Sample records for andesites

  1. Formation of hybrid arc andesites beneath thick continental crust (United States)

    Straub, Susanne M.; Gomez-Tuena, Arturo; Stuart, Finlay M.; Zellmer, Georg F.; Espinasa-Perena, Ramon; Cai, Yue; Iizuka, Yoshiyuki


    Andesite magmatism at convergent margins is essential for the differentiation of silicate Earth, but no consensus exists as to andesite petrogenesis. Models proposing origin of primary andesite melts from mantle and/or slab materials remain in deadlock with the seemingly irrefutable petrographic and chemical evidence for andesite formation through mixing of basaltic mantle melts with silicic components from the overlying crust. Here we use 3He/4He ratios of high-Ni olivines to demonstrate the mantle origin of basaltic to andesitic arc magmas in the central Mexican Volcanic Belt (MVB) that is constructed on ~ 50 km thick continental crust. We propose that the central MVB arc magmas are hybrids of high-Mg# > 70 basaltic and dacitic initial mantle melts which were produced by melting of a peridotite subarc mantle interspersed with silica-deficient and silica-excess pyroxenite veins. These veins formed by infiltration of reactive silicic components from the subducting slab. Partial melts from pyroxenites, and minor component melts from peridotite, mix in variable proportions to produce high-Mg# basaltic, andesitic and dacitic magmas. Moderate fractional crystallization and recharge melt mixing in the overlying crust produces then the lower-Mg# magmas erupted. Our model accounts for the contrast between the arc-typical SiO2 variability at a given Mg# and the strong correlation between major element oxides SiO2, MgO and FeO which is not reproduced by mantle-crust mixing models. Our data further indicate that viscous high-silica mantle magmas may preferentially be emplaced as intrusive silicic plutonic rocks in the crust rather than erupt. Ultimately, our results imply a stronger turnover of slab and mantle materials in subduction zones with a negligible, or lesser dilution, by materials from the overlying crust.

  2. Late Tertiary andesites and basaltic andesites from Khangai, Khingan, and Vitim Plateau: geochemical similarities and differences of sources (United States)

    Rudneva, Nadezhda; Chuvashova, Irina; Rasskazov, Sergei; Yasnygina, Tatiana


    Andesite is a typical rock of island arcs and active continental margins. This kind of volcanic rocks is not characteristic for inner parts of continents. Andesites and associated rocks (basaltic andesites, trachyandesites, basaltic trachyandesites) were identified, however, in many Cenozoic volcanic fields of Inner Asia, which was never referred to the mentioned geodynamic settings. To define geodynamic meaning of andesites and related rocks, we present isotopic and geochemical systematics of their sources for three key areas: Khangai, Khingan, and Vitim Plateau. Low-K andesite and basaltic trachyandesite lavas from East Khangai erupted at about 7-6 Ma from lower crustal source with enriched isotopic signatures of Nd and Sr and were followed by high-K mantle-derived basaltic lavas at 5.5-4.8 Ma that show depleted signature in terms of Sr isotopes and enriched one in terms of Nd isotopes. This lava sequence is indicative for delamination of the lower lithosphere beneath the East Khangai orogenic province. Andesite, basaltic andesite, trachyandesite, and basalt lavas from Greater and Lesser Khingan, which are characterized by wide variations of K2O/Na2O ratios, erupted in different areas of the Greater and Lesser Khingan in the time interval from 22 to 1 Ma from heterogeneous crustal and mantle sources with enriched isotopic signatures of Nd and Sr. Unlike the crust-mantle magma-generated processes beneath East Khangai, those beneath Khingan were dispersed in time and space. Basaltic andesite lavas from Vitim Plateau, erupted at 14-13 Ma after high-Mg basanites and picrobasalts, show depleted isotopic signatures of Nd and Sr. In terms of trace-element modeling, lavas of this unit were derived through high-degree partial melting (15-20 %) in the shallow (garnet-free) mantle lithospheric source. The found geochemical grouping of rocks is considered as the basis for systematics of shallow mantle and crustal sources of Cenozoic volcanic rocks from different regions of

  3. Andesite Petrogenesis in Nevado de Toluca Stratovolcano, Central Mexico (United States)

    Gomez-Tuena, A.; Capra, L.; Cai, Y.; Goldstein, S. L.


    A popular model for andesite petrogenesis in continental arcs involves a hydrous parental basalt that fractionates and probably assimilates continental crust during ascent. Nevertheless, andesites erupted from polygenetic volcanoes in the Trans-Mexican Volcanic Belt are not entirely consistent with this scenario because: (1) they display a shift to higher SiO2 contents at similar Mg# than true basalts, (2) they trend to lower HREE and HFSE contents with increasing SiO2, and (3) they often show correlated isotopic compositions with proxies for slab inputs but not with fractionation indexes. Young andesites from Toluca stratovolcano (1-0.042 Ma) also display modest adakite-like features (Sr/YToluca rock-suite revealed that some other andesites (2.6-1 Ma) also exhibit very strong negative Ce (Ce/Ce~0.25) anomalies, fractionated HREE patterns (Gd/Yb~4.2), as well as low Zr/Sm (~12.6), and Sr/Y (~12) ratios. These features are not easily explained by low or even high pressure differentiation from a common primitive magma, unless enormous quantities of fractionating accessory minerals are taken into account. And yet these geochemical signals are almost identical to those observed in the pelagic sedimentary horizon of the subducted Cocos plate sampled at DSDP site 487, and thus provide strong evidence for slab-derived sediment contributions to the petrogenesis of Toluca andesites. Since sediment transfer to the Toluca source must have occurred in the form of a silicate melt, the new evidence brings further support to the slab melting hypothesis in the Mexican subduction zone. Interestingly, Ce/Pb ratios of the Toluca rocks display a linear positive correlation with Pb isotopes, that departs from the pelagic sediment values, and extends to the enriched Pb isotopic compositions of intraplate-type volcanic rocks from the Chichinautzin volcanic field. Thus the Toluca rocks likely represent discrete slab-derived melts coming from different portions of the subducted slab that

  4. Origin of High-Alumina Basalt, Andesite, and Dacite Magmas. (United States)

    Hamilton, W


    The typical volcanic rocks of most island arcs and eugeosynclines, and of some continental environments, are basalt, andesite, and dacite, of high alumina content. The high-alumina basalt differs from tholeiitic basalt primarily in having a greater content of the components of calcic plagioclase. Laboratory data indicate that in the upper mantle, below the level at which the basaltic component of mantle rock is transformed by pressure to eclogite or pyroxenite, the entire basaltic portion probably is melted within a narrow temperature range, but that above the level of that transformation plagioclase is melted selectively before pyroxene over a wide temperature range. The broad spectrum of high-alumina magmas may represent widely varying degrees of partial melting above the transformation level, whereas narrow-spectrum tholeiite magma may represent more complete melting beneath it.

  5. Viscosity measurements of crystallizing andesite from Tungurahua volcano (Ecuador) (United States)

    Cimarelli, Corrado; deBiasi, Lea; Hanson, Jonathan B.; Lavallée, Yan; Arzilli, Fabio; Dingwell, Donald B.


    Abstract Viscosity has been determined during isothermal crystallization of an andesite from Tungurahua volcano (Ecuador). Viscosity was continuously recorded using the concentric cylinder method and employing a Pt‐sheathed alumina spindle at 1 bar and from 1400°C to subliquidus temperatures to track rheological changes during crystallization. The disposable spindle was not extracted from the sample but rather left in the sample during quenching thus preserving an undisturbed textural configuration of the crystals. The inspection of products quenched during the crystallization process reveals evidence for heterogeneous crystal nucleation at the spindle and near the crucible wall, as well as crystal alignment in the flow field. At the end of the crystallization, defined when viscosity is constant, plagioclase is homogeneously distributed throughout the crucible (with the single exception of experiment performed at the lowest temperature). In this experiments, the crystallization kinetics appear to be strongly affected by the stirring conditions of the viscosity determinations. A TTT (Time‐Temperature‐Transformation) diagram illustrating the crystallization “nose” for this andesite under stirring conditions and at ambient pressure has been constructed. We further note that at a given crystal content and distribution, the high aspect ratio of the acicular plagioclase yields a shear‐thinning rheology at crystal contents as low as 13 vol %, and that the relative viscosity is higher than predicted from existing viscosity models. These viscosity experiments hold the potential for delivering insights into the relative influences of the cooling path, undercooling, and deformation on crystallization kinetics and resultant crystal morphologies, as well as their impact on magmatic viscosity. PMID:27656114

  6. Magma heating by decompression-driven crystallization beneath andesite volcanoes. (United States)

    Blundy, Jon; Cashman, Kathy; Humphreys, Madeleine


    Explosive volcanic eruptions are driven by exsolution of H2O-rich vapour from silicic magma. Eruption dynamics involve a complex interplay between nucleation and growth of vapour bubbles and crystallization, generating highly nonlinear variation in the physical properties of magma as it ascends beneath a volcano. This makes explosive volcanism difficult to model and, ultimately, to predict. A key unknown is the temperature variation in magma rising through the sub-volcanic system, as it loses gas and crystallizes en route. Thermodynamic modelling of magma that degasses, but does not crystallize, indicates that both cooling and heating are possible. Hitherto it has not been possible to evaluate such alternatives because of the difficulty of tracking temperature variations in moving magma several kilometres below the surface. Here we extend recent work on glassy melt inclusions trapped in plagioclase crystals to develop a method for tracking pressure-temperature-crystallinity paths in magma beneath two active andesite volcanoes. We use dissolved H2O in melt inclusions to constrain the pressure of H2O at the time an inclusion became sealed, incompatible trace element concentrations to calculate the corresponding magma crystallinity and plagioclase-melt geothermometry to determine the temperature. These data are allied to ilmenite-magnetite geothermometry to show that the temperature of ascending magma increases by up to 100 degrees C, owing to the release of latent heat of crystallization. This heating can account for several common textural features of andesitic magmas, which might otherwise be erroneously attributed to pre-eruptive magma mixing.

  7. Viscosity measurements of crystallizing andesite from Tungurahua volcano (Ecuador). (United States)

    Chevrel, Magdalena Oryaëlle; Cimarelli, Corrado; deBiasi, Lea; Hanson, Jonathan B; Lavallée, Yan; Arzilli, Fabio; Dingwell, Donald B


    Viscosity has been determined during isothermal crystallization of an andesite from Tungurahua volcano (Ecuador). Viscosity was continuously recorded using the concentric cylinder method and employing a Pt-sheathed alumina spindle at 1 bar and from 1400°C to subliquidus temperatures to track rheological changes during crystallization. The disposable spindle was not extracted from the sample but rather left in the sample during quenching thus preserving an undisturbed textural configuration of the crystals. The inspection of products quenched during the crystallization process reveals evidence for heterogeneous crystal nucleation at the spindle and near the crucible wall, as well as crystal alignment in the flow field. At the end of the crystallization, defined when viscosity is constant, plagioclase is homogeneously distributed throughout the crucible (with the single exception of experiment performed at the lowest temperature). In this experiments, the crystallization kinetics appear to be strongly affected by the stirring conditions of the viscosity determinations. A TTT (Time-Temperature-Transformation) diagram illustrating the crystallization "nose" for this andesite under stirring conditions and at ambient pressure has been constructed. We further note that at a given crystal content and distribution, the high aspect ratio of the acicular plagioclase yields a shear-thinning rheology at crystal contents as low as 13 vol %, and that the relative viscosity is higher than predicted from existing viscosity models. These viscosity experiments hold the potential for delivering insights into the relative influences of the cooling path, undercooling, and deformation on crystallization kinetics and resultant crystal morphologies, as well as their impact on magmatic viscosity.

  8. Melting the hydrous, subarc mantle: the origin of primitive andesites (United States)

    Mitchell, Alexandra L.; Grove, Timothy L.


    This experimental study is the first comprehensive investigation of the melting behavior of an olivine + orthopyroxene ± spinel—bearing fertile mantle (FM) composition as a function of variable pressure and water content. The fertile composition was enriched with a metasomatic slab component of ≤0.5 % alkalis and investigated from 1135 to 1470 °C at 1.0-2.0 GPa. A depleted lherzolite with 0.4 % alkali addition was also studied from 1225 to 1240 °C at 1.2 GPa. Melts of both compositions were water-undersaturated: fertile lherzolite melts contained 0-6.4 wt% H2O, and depleted lherzolite melts contained ~2.5 wt% H2O. H2O contents of experimental glasses are measured using electron microprobe, secondary ion mass spectrometry, and synchrotron-source reflection Fourier transform infrared spectroscopy, a novel technique for analyzing H2O in petrologic experiments. Using this new dataset in conjunction with results from previous hydrous experimental studies, a thermobarometer and a hygrometer-thermometer are presented to determine the conditions under which primitive lavas were last in equilibration with the mantle. These predictive models are functions of H2O content and pressure, respectively. A predictive melting model is also presented that calculates melt compositions in equilibrium with an olivine + orthopyroxene ± spinel residual assemblage (harzburgite). This model quantitatively predicts the following influences of H2O on mantle lherzolite melting: (1) As melting pressure increases, melt compositions become more olivine-normative, (2) as melting extent increases, melt compositions become depleted in the normative plagioclase component, and (3) as melt H2O content increases, melts become more quartz-normative. Natural high-Mg# [molar Mg/(Mg + Fe2+)], high-MgO basaltic andesite and andesite lavas—or primitive andesites (PAs)—contain high SiO2 contents at mantle-equilibrated Mg#s. Their compositional characteristics cannot be readily explained by melting

  9. Weathering Rinds and Soil Development on Basaltic Andesite, Guadeloupe (United States)

    Sak, P. B.; Murphy, M.; Ma, L.; Engel, J.; Pereyra, Y.; Gaillardet, J.; Brantley, S. L.


    An oriented clast of basaltic andesite collected from the B horizon of a soil developed in a late Quaternary volcanoclastic debris flow on the eastern, windward side of Basse Terre Island, Guadeloupe exhibits weathering patterns like that observed in many clasts from tropical settings. The sample consists of unweathered core material overlain by a ~19 mm thick weathering rind and a narrow ≤ 2mm thick indurated horizon separating the outer portion of the rind from the overlying >10mm of soil matrix material. Elemental variations are constrained by a seven point bulk ICP-AES vertical transect extending from the core, across the rind and ~15 mm into the overlying soil matix and six parallel electron microprobe transections. The porous-hydrated fraction increases from the core to the rind to the surrounding soil from 7±4% to 45±18% to 60±15%, respectively. Like the well-studied clast from the nearby Bras David watershed (Sak et al., 2010) the isovolumetric transformation from core to rind material is marked by a narrow (Ba>K≈Mn>Mg>Si>Al≈P>Fe»Ti, consistent with the relative reactivity of phases in the clast from plagioclasepyroxeneglass>apatite>ilmenite. Unlike previously studied clasts, the preservation of the rind-soil interface permits characterization of weathering reactions between the weathering clast and surrounding soil matrix. The abrupt (weathering rind suggests that weathering processes active within clasts are distinct from surrounding soil formation processes.

  10. Evolving volcanism at the tip of a propagating arc: The earliest high-Mg andesites in northern New Zealand (United States)

    Booden, Mathijs A.; Smith, Ian E. M.; Mauk, Jeffrey L.; Black, Philippa M.


    A NNW-striking string of isolated volcanic centers, the Kiwitahi chain, erupted between 15 and 5.5 Ma in northern New Zealand. Prior to 6.2 Ma, the erupted rocks were plagioclase- and hornblende-dominated andesites, which are geochemically comparable to coeval andesites erupted in the nearby, much larger Coromandel Volcanic Zone (CVZ). Compared to CVZ andesites, however, the Kiwitahi andesites show more subdued incompatible element enrichments, and they generally have relatively unradiogenic Sr isotope compositions. These features, and the small eruption volumes involved, suggest that the Kiwitahi centers formed over the edge of a magmatic system that was centered on the CVZ. The Kiwitahi centers progressively become younger towards the SSE representing the migration over the time of the edge of this magmatic system. Between 6.2 and 5.5 Ma, four centers at the southern end of the chain erupted pyroxene-dominated, high-magnesium andesites that are geochemically unlike coeval andesites in the CVZ, but similar to Quaternary high-Mg andesites erupted along the western edge of the Taupo Volcanic Zone. These are the earliest known high-Mg andesites in northern New Zealand; their appearance may mark the inception of the current configuration where high-Mg andesite eruptions precede regular andesitic volcanism at the leading edge of the arc.

  11. A dearth of intermediate melts at subduction zone volcanoes and the petrogenesis of arc andesites. (United States)

    Reubi, Olivier; Blundy, Jon


    Andesites represent a large proportion of the magmas erupted at continental arc volcanoes and are regarded as a major component in the formation of continental crust. Andesite petrogenesis is therefore fundamental in terms of both volcanic hazard and differentiation of the Earth. Andesites typically contain a significant proportion of crystals showing disequilibrium petrographic characteristics indicative of mixing or mingling between silicic and mafic magmas, which fuels a long-standing debate regarding the significance of these processes in andesite petrogenesis and ultimately questions the abundance of true liquids with andesitic composition. Central to this debate is the distinction between liquids (or melts) and magmas, mixtures of liquids with crystals, which may or may not be co-genetic. With this distinction comes the realization that bulk-rock chemical analyses of petrologically complex andesites can lead to a blurred picture of the fundamental processes behind arc magmatism. Here we present an alternative view of andesite petrogenesis, based on a review of quenched glassy melt inclusions trapped in phenocrysts, whole-rock chemistry, and high-pressure and high-temperature experiments. We argue that true liquids of intermediate composition (59 to 66 wt% SiO(2)) are far less common in the sub-volcanic reservoirs of arc volcanoes than is suggested by the abundance of erupted magma within this compositional range. Effective mingling within upper crustal magmatic reservoirs obscures a compositional bimodality of melts ascending from the lower crust, and masks the fundamental role of silicic melts (>/=66 wt% SiO(2)) beneath intermediate arc volcanoes. This alternative view resolves several puzzling aspects of arc volcanism and provides important clues to the integration of plutonic and volcanic records.

  12. Experimental Study on the Electrical Conductivity of Pyroxene Andesite at High Temperature and High Pressure (United States)

    Hui, KeShi; Dai, LiDong; Li, HePing; Hu, HaiYing; Jiang, JianJun; Sun, WenQing; Zhang, Hui


    The electrical conductivity of pyroxene andesite was in situ measured under conditions of 1.0-2.0 GPa and 673-1073 K using a YJ-3000t multi-anvil press and Solartron-1260 Impedance/Gain-phase analyzer. Experimental results indicate that the electrical conductivities of pyroxene andesite increase with increasing temperature, and the electrical conductivities decrease with the rise of pressure, and the relationship between electrical conductivity (σ) and temperature (T) conforms to an Arrhenius relation within a given pressure and temperature range. When temperature rises up to 873-923 K, the electrical conductivities of pyroxene andesite abruptly increase, and the activation enthalpy increases at this range, which demonstrates that pyroxene andesite starts to dehydrate. By the virtue of the activation enthalpy (0.35-0.42 eV) and the activation volume (-6.75 ± 1.67 cm3/mole) which characterizes the electrical properties of sample after dehydration, we consider that the conduction mechanism is the small polaron conduction before and after dehydration, and that the rise of carrier concentration is the most important reason of increased electrical conductivity.

  13. Pore-space distribution and transport properties of an andesitic intrusion (United States)

    Jamtveit, Bjørn; Krotkiewski, Marcin; Kobchenko, Maya; Renard, Francois; Angheluta, Luiza


    The pore structure of magmatic rocks records processes operating during magma solidification and cooling. It has first order effects on the petrophysical properties of the magmatic rocks, and also influences mass transfer and mineral reactions during subsequent metamorphism or weathering. Here, the pore space characteristics of an andesitic sill intrusion were determined by multiscale resolution computed X-ray microtomography (μ-CT), and the 3D structure was used for transport modeling. Unaltered andesite has a power law distribution of pore volumes over a range of five orders of magnitude. The probability distribution function (PDF) scales with the inverse square of the pore volume (V), PDF∝V-2. This scaling behavior is attributed to the coalescence of pores at crystal-melt boundaries. Large pores are concentrated on the outer margins of amphibole and plagioclase phenocrystals. Incipient weathering of the andesite is associated with preferential growth of weathering products in the largest pores. This can be explained by a model in which diffusion of external components into the porous andesite is controlled by a random network of grain boundaries and/or microfractures. This network preferentially links the larger pores to the system boundaries and it is the major fluid transport pathway, confining incipient weathering into a small fraction of the rock volume only.

  14. Spectral evidence for weathered basalt as an alternative to andesite in the northern lowlands of Mars. (United States)

    Wyatt, Michael B; McSween, Harry Y


    Mineral abundances derived from the analysis of remotely sensed thermal emission data from Mars have been interpreted to indicate that the surface is composed of basalt (Surface Type 1) and andesite (Surface Type 2). The global distribution of these rock types is divided roughly along the planetary dichotomy which separates ancient, heavily cratered crust in the southern hemisphere (basalt) from younger lowland plains in the north (andesite). But the existence of such a large volume of andesite is difficult to reconcile with our present understanding of the geological evolution of Mars. Here we reinterpret martian surface rock lithologies using mineral abundances from previous work and new mineralogies derived from a spectral end-member set representing minerals common in unaltered and low-temperature aqueously altered basalts. Our results continue to indicate the dominance of unaltered basalt in the southern highlands, but reveal that the northern lowlands can be interpreted as weathered basalt as an alternative to andesite. The coincidence between locations of such altered basalt and a suggested northern ocean basin implies that lowland plains material may be composed of basalts weathered under submarine conditions or weathered basaltic sediments transported into this depocentre.

  15. The anatomy of an andesite volcano: A time-stratigraphic study of andesite petrogenesis and crustal evolution at Ruapehu volcano, New Zealand

    DEFF Research Database (Denmark)

    Price, R.C.; Gamble, J.A.; Smith, I.E.M.;


    Ruapehu, New Zealand’s largest active andesite volcano is located at the southern tip of the Taupo Volcanic Zone (TVZ), the main locus of subduction-related volcanism in the North Island. Geophysical data indicate that crustal thickness transitions from ... Ruapehu. The volcano is built on a basement of Mesozoic metagreywacke and geophysical evidence together with xenoliths contained in lavas indicates that this is underlain by oceanic, meta-igneous lower crust. The present-day Ruapehu edifice has been constructed by a series of eruptive events that produced...

  16. Soils derived from Pieniny andesite, Wdżar hill, Outer Carpathians (Poland) (United States)

    Kajdas, Bartlomiej; Zaleski, Tomasz; Mazurek, Ryszard


    Tertiary andesite occurs in only few places in Polish part of the Outer Carpatians. The biggest andesitic body is observed at the Wdżar hill (676 m a.s.l), SE from Kluszkowce village. To the beginning of the 1970s active quarry were located at the hill slope, and from the end of 1990s Wdżar is used as a ski resort. Because Wdżar is the culmination protruding over sandstones and shales of Magura Unit of Outer Carpatians, it gives opportunity to investigate soils derived directly from the andesite. Primary, unaltered andesite contain mainly plagioclase (An28-62), amphibole (hornblende group), clinopiroxene (pigeonite group) and Fe-Ti oxides (Michalik et al., 2004). Quartz in those type of rocks is absent. Andesites from Pieniny Mts. contain low amount of silica (ca. 52-55% wt. in fresh and about 62% wt. in hydrothermally altered rocks), and high amount of CaO (5,5-9,2% wt.) and MgO (0,8-5,5% wt.) (Nejbert et al., 2012). Soils cover on Wdżar hill represents different stages of soil development. Shallow, ca. 15 cm deep, Eutric Leptosols and deeper, 60 cm and over 200 cm deep, Eutric Skeleti Cambisols (Colluvic, Humic) were distinguished. There are significant differences both between the soil groups as well as inside them. Investigated soils have sandy loam, loam and silt loam texture. Surface, organic horizons show acid reaction, but cambic and parent material horizons show neutral reaction. Cation exchange capacity ranges between 526.9 and 298.2 mmol(+)ṡkg-1 in humus horizons and between 451.4 and 225.8 mmol(+)ṡkg-1in cambic and parent material horizons. The amount of exchangeable Ca2+ ranges between 386.8 and 175.8 mmol(+)ṡkg-1 and is about 6 times higher than sum of Mg2+, Na+ and K+ in the soil horizon. Despite of the high amount of Ca2+, there were no active carbonates in investigated soil. The soils, that are developed from the andesite, usualy contain high amount of clays and very low amount of primary quartz. Andesite from Wdżar reveals minor degree

  17. Experimental study into the petrogenesis of crystal-rich basaltic to andesitic magmas at Arenal volcano (United States)

    Parat, F.; Streck, M. J.; Holtz, F.; Almeev, R.


    Arenal volcano is nearly unique among arc volcanoes with its 42 year long (1968-2010) continuous, small-scale activity erupting compositionally monotonous basaltic andesites that also dominate the entire, ~7000 year long, eruptive history. Only mineral zoning records reveal that basaltic andesites are the result of complex, open-system processes deriving minerals from a variety of crystallization environments and including the episodic injections of basalt. The condition of the mafic input as well as the generation of crystal-rich basaltic andesites of the recent, 1968-2010, and earlier eruptions were addressed by an experimental study at 200 MPa, 900-1,050 °C, oxidizing and fluid-saturated conditions with various fluid compositions [H2O/(H2O + CO2) = 0.3-1]. Phase equilibria were determined using a phenocryst-poor (~3 vol%) Arenal-like basalt (50.5-wt% SiO2) from a nearby scoria cone containing olivine (Fo92), plagioclase (An86), clinopyroxene (Mg# = 82) and magnetite (Xulvö = 0.13). Experimental melts generally reproduce observed compositional trends among Arenal samples. Small differences between experimental melts and natural rocks can be explained by open-system processes. At low pressure (200 MPa), the mineral assemblage as well as the mineral compositions of the natural basalt were reproduced at 1,000 °C and high water activity. The residual melt at these conditions is basaltic andesitic (55 wt% SiO2) with 5 wt% H2O. The evolution to more evolved magmas observed at Arenal occurred under fluid-saturated conditions but variable fluid compositions. At 1,000 °C and 200 MPa, a decrease of water content by approximately 1 wt% induces significant changes of the mineral assemblage from olivine + clinopyroxene + plagioclase (5 wt% H2O in the melt) to clinopyroxene + plagioclase + orthopyroxene (4 wt% H2O in the melt). Both assemblages are observed in crystal-rich basalt (15 vol%) and basaltic andesites. Experimental data indicate that the lack of orthopyroxene

  18. Isotopic composition of strontium in three basalt-andesite centers along the Lesser Antilles arc (United States)

    Hedge, C.E.; Lewis, J.F.


    Si87/Sr86 ratios have been determined for lavas and py lastic rocks from three basalt-andesite centers along the Lesser Antilles arc-Mt. Misery on the island of St. Kitts, Soufriere on the island of St. Vincent, and Carriacou, an island of The Grenadines. The average Si87/Sr86 content of these rocks is 0.7038 for Mt. Misery, 0.7041 for Soufriere, and 0.7053 for Carriacou. All the Sr87/Sr86 values from each center are the same within analytical uncertainty (??0.0002). The constancy of strontium isotopic data within each center supports the hypothesis that basalts and andesites for each specific center investigated are generated from the same source - in agreement with petrographic and major- and minor-element data. Strontium isotopic compositions and elemental concentrations, particularly of strontium and nickel, indicate that this source was mantle peridotite and that the relationship between the respective basalts and andesites is probably fractional crystallization. ?? 1971 Springer-Verlag.

  19. High-Mg# andesitic lavas of the Shisheisky Complex, Northern Kamchatka: implications for primitive calc-alkaline magmatism (United States)

    Bryant, J. A.; Yogodzinski, G. M.; Churikova, T. G.


    Primitive arc magmatism and mantle wedge processes are investigated through a petrologic and geochemical study of high-Mg# (Mg/Mg + Fe > 0.65) basalts, basaltic andesites and andesites from the Kurile-Kamchatka subduction system. Primitive andesitic samples are from the Shisheisky Complex, a field of Quaternary-age, monogenetic cones located in the Aleutian-Kamchatka junction, north of Shiveluch Volcano, the northernmost active composite volcano in Kamchatka. The Shisheisky lavas have Mg# of 0.66-0.73 at intermediate SiO2 (54-58 wt%) with low CaO (3.0 wt%) and K2O (>1.0 wt%). Olivine phenocryst core compositions of Fo90 appear to be in equilibrium with whole-rock `melts', consistent with the sparsely phyric nature of the lavas. Compared to the Shisheisky andesites, primitive basalts from the region (Kuriles, Tolbachik, Kharchinsky) have higher CaO (>9.9 wt%) and CaO/Al2O3 (>0.60), and lower whole-rock Na2O (andesites. The absence of plagioclase phenocrysts from the primitive andesitic lavas contrasts the plagioclase-phyric basalts, indicating relatively high pre-eruptive water contents for the primitive andesitic magmas compared to basalts. Estimated temperature and water contents for primitive basaltic andesites and andesites are 984-1,143°C and 4-7 wt% H2O. For primitive basalts they are 1,149-1,227°C and 2 wt% H2O. Petrographic and mineral compositions suggest that the primitive andesitic lavas were liquids in equilibrium with mantle peridotite and were not produced by mixing between basalts and felsic crustal melts, contamination by xenocrystic olivine, or crystal fractionation of basalt. Key geochemical features of the Shisheisky primitive lavas (high Ni/MgO, Na2O, Ni/Yb and Mg# at intermediate SiO2) combined with the location of the volcanic field above the edge of the subducting Pacific Plate support a genetic model that involves melting of eclogite or pyroxenite at or near the surface of the subducting plate, followed by interaction of that melt with

  20. Primitive, high-Mg basaltic andesites: direct melts of the shallow, hot, wet mantle (United States)

    Andrews, A.; Grove, T. L.


    Direct mantle melts are rare in subduction zone settings. Such melts are identified by Mg #s (Mg # = Mg / (Mg+Fe)) greater than ~0.73, indicating chemical equilibrium with Fo90 mantle olivine. Most of these primitive arc melts are basaltic, characterized by SiO2 contents of ~48-50 wt % and MgO contents ranging from 8-10 wt %. However, primitive basaltic andesites with mantle-equilibrated Mg #s have also been found at subduction zones worldwide. These basaltic andesites have higher SiO2 contents (53-58 wt %) than typical primitive basalts as well as high MgO (8-10 wt %). Because these rocks have high SiO2 contents and yet retain evidence for chemical equilibrium with the mantle (Mg #s), their petrogenesis has sparked intense debate as researchers have tried to discern how these samples fit into the paradigm of mantle melting at subduction zones. Through an understanding of the conditions and processes that produce the SiO2 enrichment in these rocks, we also aim to understand the role of these melts in producing the observed andesitic compositional characteristics of the continental crust. To understand the petrogenesis of primitive, high-Mg basaltic andesites, this study investigates the experimental melts of undepleted mantle peridotite plus a slab component (Na-2O + K2O) from 1,205-1,470°C at 1.0-2.0 GPa under water-undersaturated conditions (0-5 wt % H2O). At 1.0 and 1.2 GPa, the experimental melts reproduce the compositions of natural primitive, high-Mg basaltic andesites in all major elements (SiO2, TiO2, Al2O3, FeO, MnO, MgO, and Na2O+K2O) except CaO. CaO contents are higher than the range of the natural samples by ~2 wt % at the highest silica contents of the experiments (54-56 wt% SiO2). This suggests that at 1.0-1.2 GPa, a higher percent of melting (30-35 %) with 3-5 wt % H2O is required to drive the chemical compositions of the experiments toward the representative compositions of the natural rocks. The experimental melts also show that mantle-wall rock

  1. Origin of primitive andesites by melt-rock reaction in the sub-arc mantle (Invited) (United States)

    Rapp, R. P.


    The genetic relationship between primitive granitoids, including high-Mg andesites (HMAs) and bajaites, and primary granitoids, or "pristine" adakites, has been vigorously debated since Defant and Drummond (1991; henceforth D&D) first applied the term "adakite" to refer to Cenozoic arc magmas (andesites and dacites) "associated with young subducting lithosphere", with low Y and Yb, low high-field strength elements (HFSEs), high Sr, and high Sr/Y and (La/Yb)N ratios "relative to island arc andesite-dacite-rhyolite". These characteristics were attributed to an origin for adakites by partial melting of basaltic crust within the subducting slab (hence "slab melts"). That such a process can produce melts with the characteristics described by D&D has since been largely confirmed by dehydration melting experiments on hydrous metabasalt at ~1-4 GPa. Attention was also drawn to the geochemical similarities between "adakites" and large-ion lithophile element (LILE)-enriched, high-field strength element (HFSE) depleted magnesian andesites (HMAs) from Adak Island in the western Aleutians, first described by Kay (1978), implying a genetic relationship between primary granitoid (adakites) formed by partial melting of basaltic ocean crust in the subducting slab, transformed to garnet-amphibolite or eclogite, and primitive magnesian andesites (HMAs) with high Mg-numbers (Mg# = molar Mg/(Mg+Fe)x100) and high concentrations of Ni and Cr. What then is the true origin of these enigmatic arc magmas, with both crustal and mantle, derivative and primitive, geochemical signatures? Kay (1978) suggested a "hybrid" model, in which "hydrous melting of eclogite (slab melting) results in a small volume of dacitic melt ("pristine adakite"), which rises into the hotter overlying peridotite wedge and equilibrates with olivine and orthopyroxene, reacting with olivine until it becomes andesitic". In this paper, I will discuss the results of melt-rock reaction experiments modelling this peridotite

  2. Andesite petrogenesis in a hybrid arc-rift setting: the Western Trans-Mexican Volcanic Belt (United States)

    Gómez-Tuena, A.; Vázquez-Duarte, A.; Díaz-Bravo, B.; Mori, L.


    The western sector of the Mexican subduction zone is characterized by the steep subduction of one of the youngest slabs on the planet (Rivera plate), and by the existence of a continental rift at ~230 km to the north from the trench (the so-called Tepic-Zacoalco rift, TZR), under which the subducted slab is either extremely deep or even absent (>250 km). The volcanic front is located at ~170 km from the trench and contains abundant potassic-alkaline lamprophyres with strong subduction (Ba/Ta= 1600-6000) and garnet signatures (Gd/Yb= 2-8), that have been recently interpreted as influenced by deep K2O-rich slab melts or supercritical fluids (Gómez-Tuena et al., 2011, GCA). In contrast, the most mafic rocks within the TZR are high-Nb, intraplate-like basalts that appear to derive from low extents of melting of a dryer (Ba/Ta= 800-60) and shallower (Gd/Yb= 2-2.5) mantle source. Even though a simple transition from an arc environment to an extensional tectonic regime is apparent when only the most primitive volcanic rocks are taken into account, the scenario becomes more complicated since at least five stratovolcanoes have been erupting typical arc andesites within the TZR over the last million years (San Juan, Sanganguey, Tepetiltic, Ceboruco and Tequila). Surprisingly, true calc-alkaline basalts that could be parental to andesites have not been found, indicating that andesites may have a direct mantle origin. Indeed, mayor and trace element compositions of volcanic rocks from western Mexico arrange in discrete suites with linear trends that are indicative of mixing, but they form sub-parallel arrays that do not converge to a common primitive basaltic melt, and often follow diverging trends in trace element-ratio plots. Melt-crust interactions likely occurred during magma ascent, since the volcanic rocks frequently include xenoliths and disequilibrium textures, but correlations among isotopic compositions and indexes of fractionation are not clearly observed in the

  3. Mantle Origin of Silicic Calc-alkaline Basalts to Andesites in the Central Mexican Volcanic Belt (United States)

    Straub, S. M.; Zellmer, G. F.; Gómez-Tuena, A.; Stuart, F.; Espinasa-Perena, R.; Cai, Y.


    The Quaternary central Mexican Volcanic Belt, constructed on ~50 km thick continental crust, erupts a broad spectrum of basaltic to dacitic calc-alkaline magmas with the arc-typical high ratios of large-ion lithophile to high-field strength elements. In order to understand their genesis, we investigated high-Mg# olivine-phyric calc-alkaline basalts to andesites from Holocene monogenetic volcanoes Tuxtepec (50.2 wt% SiO2; 9.7 wt% MgO), Yecahuazac (53.1;8.0), Suchiooc Cone (53.2;9.2), Guespalapa (54.4-61.2;5.3-7.9) and Cuatepel (55.6-58.9;5.4-7.5), and as well as one basaltic andesite from composite volcano Popocateptl (56.7;6.9). The high 3He/4He (7.3 ± 0.3 Ra; n=16) of olivine phenocrysts that crystallize at upper crustal levels, and the limited range of Sr-Nd-Hf isotope ratios preclude any significant crustal contamination of these magmas. Moreover, small, but significant differences in Sr-Nd-Hf isotope ratios and the variations of olivine phenocrysts in the Fo-Ni space conclusively rule out that these magmas were related through fractional crystallization. Consequently, the basaltic to andesitic magmas must originate from the sub-arc mantle. Building on the high-Ni content of the olivines that by far exceed Ni abundances of olivines in partial melts of peridotite, we propose that the subarc MVB mantle contains segregations of silica-excess and silica-deficient 'reaction pyroxenites' that formed through infiltration of highly reactive silicic fluids or melts from slab. Upon melting, the pyroxenites produce dacitic and basaltic initial melts, respectively, that mix in variable proportions during ascent through mantle and crust. This genetic model links the silica enrichment of the arc magmas directly to the silica flux from slab, with no requirement for any significant melt silica increase in the overlying crust.

  4. The role of polybaric crystallization in genesis of andesitic magmas: Phase equilibria simulations of the Bezymianny volcanic subseries (United States)

    Almeev, Renat R.; Ariskin, Alexei A.; Kimura, Jun-Ichi; Barmina, Galina S.


    Using the updated COMAGMAT model, the crystallization sequences of a Bezymianny Volcano basaltic andesite (Kamchatka, Russia) are simulated in a wide range of thermodynamic conditions (P-T-fO2) as a function of H2O concentration. Comparison of the modeled liquid lines of descent with petrochemical trends of the volcanic suite indicates the parental melts contain 1.5-2 wt.% H2O stored under 490-520 MPa pressure in the magma plumbing system beneath Bezymianny Volcano. The initial magma originates as a result of the polybaric evolution of mantle-derived high-Mg basaltic magmas of the adjacent Kliuchevskoi Volcano. The subsequent evolution of derivative hydrous and alumina-rich basaltic andesite magmas may proceed under polybaric conditions with an average decompression of ~ 12 MPa per 1% of crystallization. In the course of polybaric crystallization, compositions of pyroxene-bearing andesites can be numerically reproduced and the modeled liquid compositions follow the natural liquid line of descent. However, hornblende-bearing magmas cannot be produced as a result of continued crystallization from parental basaltic andesite through the stage of pyroxene-bearing andesite formation. They require high water contents and high pressures of crystallization. In this case, liquid composition should deviate from the chemical trend defined by the whole rock compositions.

  5. Antisana volcano: A representative andesitic volcano of the eastern cordillera of Ecuador: Petrography, chemistry, tephra and glacial stratigraphy (United States)

    Hall, Minard L.; Mothes, Patricia A.; Samaniego, Pablo; Militzer, Annemarie; Beate, Bernardo; Ramón, Patricio; Robin, Claude


    Antisana volcano is representative of many active andesitic strato-volcanoes of Pleistocene age in Ecuador's Eastern Cordillera. This study represents the first modern geological and volcanological investigation of Antisana since the late 1890's; it also summarizes the present geochemical understanding of its genesis. The volcano's development includes the formation and destruction of two older edifices (Antisana I and II) during some 400 + ka. Antisana II suffered a sector collapse about 15,000 years ago which was followed by the birth and growth of Antisana III. During its short life Antisana III has generated ≥50 eruptions of small to medium intensity, often associated with andesitic to dacitic lava flows and tephra, as well as with late Pleistocene and Holocene glacial advances. Throughout its long history Antisana's lavas have been characterized by a persistent mineral assemblage, consisting of 30-40 vol% phenocrysts of plagioclase, both clino- and orthopyroxene, and Fe-Ti oxides, with rare occurrences of olivine or amphibole, frequently in a microcrystalline to glassy matrix. This uniformity occurs despite the magma's progressive chemical evolution over ≥400 ka from early basic andesites (53-58 wt% SiO2) to intermediate and Si-rich andesites (58-62% SiO2), and recently to dacites (63-67% SiO2). Chemical diagrams suggest that crystal fractionation was the most likely magmatic process of evolution. The exception to this slowly evolving history was the short-lived emission at ∼210 ka of the Cuyuja lavas from Antisana II that generated a 73 km long andesitic lava flow. Contrasting with Antisana's general magmatic trend, Cuyuja lava (∼11 km3) is a high-Mg andesite with unusually high concentrations of incompatible elements. Antisana developed within the Chacana caldera complex, a large active siliceous center that began ∼3 Ma ago, however its lavas are chemically distinct from coeval lavas of Chacana.

  6. Thermal properties of andesite from Popocatepetl and Volcán de Colima, México. (United States)

    Cardenas-Sanchez, Enrique; De la Cruz-Reina, Servando; Varley, Nick


    The thermal conductivity (K), specific heat (Cp) and the coefficient of heat transfer surface (H) are the basic parameters to describe the process of cooling a volcanic rock fragment released in an explosive event. The analysis of the cooling process by conduction, convection and radiation of heat in volcanic rock fragments, has been limited to basalts, and various minerals such as olivine, pyroxene, quartz, etc. (Miao & Chen, 2014; Branlund & Hofmeister, 2012; Romine et al, 2012;. Schön, 2011; Stroberg et al, 2010;. Schatz & Simmons, 1972). There are no detailed studies on the thermal properties of the andesites, abundant in continental stratovolcanoes, and particularly susceptible from lava domes with frequent destruction processes, such as Popocatepetl and Volcan de Colima. Previously, we developed an algorithm for calculation of the grain-size distribution, degree of fragmentation, the thermal energy released and its possible correlation with Volcanic Explosive Index (VEI) from the cooling curves of fragments from vulcanian and strombolian explosions. These curves were obtained from sequences of time over incandescent deposits recorded at selected pixel thermal images of vulcanian activity in the Popocatepetl and Volcan de Colima, Mexico. However, the model was limited by the lack of thermal parameters of the andesites, forcing a first approximation using basalts data. We present a simple model for the cooling process using andesites samples from Popocatépetl and Volcan de Colima. First, the samples were subjected to a rounding process to minimize surface effects. Then, heated to 800 ° C were extracted from the muffle and cooling rate is measured. The thermal conductivity and coefficient of surface heat are determined using a thermal camera and three thermocouples embedded at various depths within the sample. An inversion method was implemented to determine the thermal properties parameters , by comparing the observed data regarding cooling model for a solid

  7. Sulfur isotope fractionation between fluid and andesitic melt: An experimental study (United States)

    Fiege, Adrian; Holtz, François; Shimizu, Nobumichi; Mandeville, Charles W.; Behrens, Harald; Knipping, Jaayke L.


    Glasses produced from decompression experiments conducted by Fiege et al. (2014a) were used to investigate the fractionation of sulfur isotopes between fluid and andesitic melt upon magma degassing. Starting materials were synthetic glasses with a composition close to a Krakatau dacitic andesite. The glasses contained 4.55–7.95 wt% H2O, ∼140 to 2700 ppm sulfur (S), and 0–1000 ppm chlorine (Cl). The experiments were carried out in internally heated pressure vessels (IHPV) at 1030 °C and oxygen fugacities (fO2) ranging from QFM+0.8 log units up to QFM+4.2 log units (QFM: quartz–fayalite–magnetite buffer). The decompression experiments were conducted by releasing pressure (P) continuously from ∼400 MPa to final P of 150, 100, 70 and 30 MPa. The decompression rate (r) ranged from 0.01 to 0.17 MPa/s. The samples were annealed for 0–72 h (annealing time, tA) at the final P and quenched rapidly from 1030 °C to room temperature (T).The decompression led to the formation of a S-bearing aqueous fluid phase due to the relatively large fluid–melt partitioning coefficients of S. Secondary ion mass spectrometry (SIMS) was used to determine the isotopic composition of the glasses before and after decompression. Mass balance calculations were applied to estimate the gas–melt S isotope fractionation factor αg-m.No detectable effect of r and tA on αg-m was observed. However, SIMS data revealed a remarkable increase of αg-m from ∼0.9985 ± 0.0007 at >QFM+3 to ∼1.0042 ± 0.0042 at ∼QFM+1. Noteworthy, the isotopic fractionation at reducing conditions was about an order of magnitude larger than predicted by previous works. Based on our experimental results and on previous findings for S speciation in fluid and silicate melt a new model predicting the effect of fO2 on αg-m (or Δ34Sg–m) in andesitic systems at 1030 °C is proposed. Our experimental results as well as our modeling are of high importance for the interpretation of S isotope

  8. Paleoproterozoic andesitic volcanism in the southern Amazonian craton (northern Brazil); lithofacies analysis and geodynamic setting (United States)

    Roverato, Matteo; Juliani, Caetano; Capra, Lucia; Dias Fernandes, Carlos Marcelo


    Precambrian volcanism played an important role in geological evolution and formation of new crust. Most of the literature on Precambrian volcanic rocks describes settings belonging to subaqueous volcanic systems. This is likely because subaerial volcanic rocks in Proterozoic and Archean volcano-sedimentary succession are poorly preserved due to erosive/weathering processes. The late Paleoproterozoic Sobreiro Formation (SF) here described, seems to be one of the rare exceptions to the rule and deserves particular attention. SF represents the subaerial expression of an andesitic magmatism that, linked with the upper felsic Santa Rosa F., composes the Uatumã Group. Uatumã Group is an extensive magmatic event located in the Xingú region, southwestern of Pará state, Amazonian Craton (northern Brazil). The Sobreiro volcanism is thought to be related to an ocean-continent convergent margin. It is characterized by ~1880 Ma well-preserved calc-alkaline basaltic/andesitic to andesitic lava flows, pyroclastic rocks and associated reworked successions. The superb preservation of its rock-textures allowed us to describe in detail a large variety of volcaniclastic deposits. We divided them into primary and secondary, depending if they result from a direct volcanic activity (pyroclastic) or reworked processes. Our study reinforces the importance of ancient volcanic arcs and rocks contribution to the terrestrial volcaniclastic sedimentation and evolution of plate tectonics. The volcanic activity that produced pyroclastic rocks influenced the amount of detritus shed into sedimentary basins and played a major role in the control of sedimentary dispersal patterns. This study aims to provide, for the first time, an analysis of the physical volcanic processes for the subaerial SF, based in field observation, lithofacies analysis, thin section petrography and less geochemical data. The modern volcanological approach here used can serve as a model about the evolution of Precambrian

  9. Silica-enriched mantle sources of subalkaline picrite-boninite-andesite island arc magmas (United States)

    Bénard, A.; Arculus, R. J.; Nebel, O.; Ionov, D. A.; McAlpine, S. R. B.


    compositions extracted from these hybrid sources are higher in normative quartz and hypersthene (i.e., they have a more silica-saturated character) in comparison with basalts derived from prior melt-depleted asthenospheric mantle beneath ridges. These primary arc melts range from silica-rich picrite to boninite and high-Mg basaltic andesite along a residual spinel harzburgite cotectic. Silica enrichment in the mantle sources of arc-related, subalkaline picrite-boninite-andesite suites coupled with the amount of water and depth of melting, are important for the formation of medium-Fe ('calc-alkaline') andesite-dacite-rhyolite suites, key lithologies forming the continental crust.

  10. H 2O in basalt and basaltic andesite glass inclusions from four subduction-related volcanoes (United States)

    Sisson, T. W.; Layne, G. D.


    Total dissolved H 2O and major element abundances were measured in basalt and basaltic andesite glass inclusions in olivine phenocrysts from Quaternary eruptions of four subduction-related volcanoes to test the hypothesis that low-MgO high-alumina basalts contain high H 2O at depth [1] and to reveal any petrogenetically significant correlations between arc basalt compositions and H 2O contents. Total dissolved H 2O (combined molecular H 2O and OH groups) measured by ion microprobe in mafic glass inclusions from the 1974 eruption of Fuego, Guatemala, reaches 6.2 wt.%. Dissolved H 2O contents decrease in more evolved Fuego glasses. Correlations of H 2O with MgO, Na 2O, K 2O, S and Cl indicate that aqueous fluid exsolution during magma ascent forced crystallization and differentiation of residual liquids. Low-K 2O magnesian high-alumina basalt glass inclusions from the 3 ka eruption of Black Crater (Medicine Lake volcano, California) have low H 2O contents, near 0.2 wt.%, which are consistent with the MORB-like character of these and other primitive lavas of the Medicine Lake region. Basalt and basaltic andesite glass inclusions from Copco Cone and Goosenest volcano on the Cascade volcanic front north of Mt. Shasta have H 2O contents of up to 3.3 wt.%. The range of H 2O contents in Cascade mafic magmas is too large to have resulted solely from enrichment by crystallization and indicates the participation of an H 2O-rich component in magma generation or crustal-level modification. Whereas fluid-absent melting of amphibole-bearing peridotite can account for the H 2O in most mafic arc liquids, the very high H 2O/alkali ratios of the 1974 Fuego eruptives suggest that an aqueous fluid was involved in the generation of Fuego basalts.

  11. Halogen behaviours during andesitic magma degassing: from magma chamber to volcanic plume (United States)

    Balcone-Boissard, H.; Villemant, B.; Boudon, G.; Michel, A.


    Halogen (F, Cl, Br and I) behaviours during degassing of H2O-rich silicic magmas are investigated using volatile content analysis in glass (matrix glass and melt inclusions) of volcanic clasts (pumice and lava-dome fragments) in a series of plinian, vulcanian and lava dome-forming eruptions. Examples are taken from andesitic systems in subduction zones: Montagne Pelée and Soufrière Hills of Montserrat (Lesser Antilles) and Santa Maria-Santiaguito (Guatemala). Halogens behaviour during shallow degassing primarily depends on their incompatible character in melts and on H2O solubility. But variations in pre-eruptive conditions, degassing kinetics and syn-eruptive melt crystallisation, induce large variations in halogen extraction efficiency during H2O degassing, up to prevent halogen loss. In all studied systems, Cl, Br and I are not fractionated neither by differentiation nor by degassing processes: thus Cl/Br/I ratios remain well preserved in melts from reservoirs to eruption. These ratios measured in erupted clasts are characteristic of pre-eruptive magma compositions and may be used to trace deep magmatic processes. Moreover, during plinian eruptions, Cl, Br and I are extracted by H2O degassing but less efficiently than predicted by available experimental fluid-melt partition coefficients, by a factor as high as 5. F behaves as an incompatible element and, contrary to other halogens, is never significantly extracted by degassing. Degassing during lava dome-forming eruptions of andesitic magmas occurs mainly at equilibrium and is more efficient at extracting halogens and H2O than explosive degassing. The mobility of H2O and halogens depends on their speciation in both silicate melts and exsolved fluids which strongly varies with pressure. We suggest that the rapid pressure decrease during highly explosive eruptions prevents complete volatile speciation at equilibrium and consequently strongly limits halogen degassing.

  12. Generation of new continental crust by sublithospheric silicic-magma relamination in arcs: A test of Taylor's andesite model

    NARCIS (Netherlands)

    Castro, Antonio; Vogt, Katharina; Gerya, Taras


    The paradox of the Earth's continental crust is that although this reservoir is generally regarded as having differentiated from the mantle, it has an andesitic bulk composition that contrasts with the intrinsic basaltic composition of mantle-derived melts. Classical models for new crust generation

  13. Paleoproterozoic crustal evolution in the East Sarmatian Orogen: Petrology, geochemistry, Sr-Nd isotopes and zircon U-Pb geochronology of andesites from the Voronezh massif, Western Russia (United States)

    Terentiev, R. A.; Savko, K. A.; Santosh, M.


    Andesites and related plutonic rocks are major contributors to continental growth and provide insights into the interaction between the mantle and crust. Paleoproterozoic volcanic rocks are important components of the East Sarmatian Orogen (ESO) belonging to the East European Craton, although their petrogenesis and tectonic setting remain controversial. Here we present petrology, mineral chemistry, bulk chemistry, Sr-Nd isotopes, and zircon U-Pb geochronological data from andesites and related rocks in the Losevo and Vorontsovka blocks of the ESO. Clinopyroxene phenocrysts in the andesites are depleted in LREE, and enriched in HFSE (Th, Nb, Zr, Hf, Ti) and LILE (Ba, Sr). Based on the chemistry of pyroxenes and whole rocks, as well as Fe-Ti oxides, we estimate a temperature range of 1179 to 1262 °C, pressures of 11.3 to 13.0 kbar, H2O content of 1-5 wt.%, and oxygen fu gacity close to the MH buffer for the melts of the Kalach graben (KG) and the Baygora area (BA) andesites. Our zircon U-Pb geochronological data indicate new zircon growth during the middle Paleoproterozoic as displayed by weighted mean 207Pb/206Pb ages of 2047 ± 17 Ma and 2040 ± 16 Ma for andesite and dacite-porphyry of the BA, and 2050 ± 16 Ma from high-Mg basaltic andesite of the KG. The andesites and related rocks of the KG and BA are characterized by high magnesium contents (Mg # up to 0.68). All these volcanic rocks are depleted in LREE and HFSE, and display negative Nb and Ti anomalies relative to primitive mantle. The high-Mg bulk composition, and the presence of clinopyroxene phenocrysts suggests that the parent melts of the KG and BA suite were in equilibrium with the mantle rocks. The rocks show positive εNd(T) values and low initial 87Sr/86Sr, suggesting that the magmas were mostly derived from metasomatized mantle source. The geochemical differences between the two andesite types are attributed to: the predominance of fractional crystallization, and minor role of contamination in the

  14. Subaqueous cryptodome eruption, hydrothermal activity and related seafloor morphologies on the andesitic North Su volcano (United States)

    Thal, Janis; Tivey, Maurice; Yoerger, Dana R.; Bach, Wolfgang


    North Su is a double-peaked active andesite submarine volcano located in the eastern Manus Basin of the Bismarck Sea that reaches a depth of 1154 m. It hosts a vigorous and varied hydrothermal system with black and white smoker vents along with several areas of diffuse venting and deposits of native sulfur. Geologic mapping based on ROV observations from 2006 and 2011 combined with morphologic features identified from repeated bathymetric surveys in 2002 and 2011 documents the emplacement of a volcanic cryptodome between 2006 and 2011. We use our observations and rock analyses to interpret an eruption scenario where highly viscous, crystal-rich andesitic magma erupted slowly into the water-saturated, gravel-dominated slope of North Su. An intense fragmentation process produced abundant blocky clasts of a heterogeneous magma (olivine crystals within a rhyolitic groundmass) that only rarely breached through the clastic cover onto the seafloor. Phreatic and phreatomagmatic explosions beneath the seafloor cause mixing of juvenile and pre-existing lithic clasts and produce a volcaniclastic deposit. This volcaniclastic deposit consists of blocky, non-altered clasts next, variably (1-100%) altered clasts, hydrothermal precipitates and crystal fragments. The usually applied parameters to identify juvenile subaqueous lava fragments, i.e. fluidal shape or chilled margin, were not applicable to distinguish between pre-existing non-altered clasts and juvenile clasts. This deposit is updomed during further injection of magma and mechanical disruption. Gas-propelled turbulent clast-recycling causes clasts to develop variably rounded shapes. An abundance of blocky clasts and the lack of clasts typical for the contact of liquid lava with water is interpreted to be the result of a cooled, high-viscosity, crystal-rich magma that failed as a brittle solid upon stress. The high viscosity allows the lava to form blocky and short lobes. The pervasive volcaniclastic cover on North Su is

  15. Origins of Calc-Alkaline (s.l.) Andesitic Magmas - Where We Stand Today (United States)

    Sisson, T. W.


    The mainly igneous continents have intermediate mean SiO2 (~60 wt%) and Mg# (0.4-0.55 mol). Bowen championed crystallization-differentiation of basalts to silicic daughter liquids, but he encountered difficulties with conflicting evidence for iron enrichment. We now know that as dry reduced basalts crystallize, melt SiO2 begins climbing steeply at F (melt fraction): 0.25-0.35, reaching intermediate values at F: 0.1-0.2. H2O changes basalt crystallization by (1) increasing the ratio of olivine to high-Ca pyroxene, (2) delaying onset and reducing the proportion of plagioclase, (3) stabilizing calcic plagioclase, (4) destabilizing low-Ca pyroxene, (5) eventually stabilizing amphibole, and (6) destabilizing silicate minerals more than magnetite. Factors 1-5 enrich melts early in SiO2, 6 limits decline of Mg#. H2O of 2-6 wt% is sufficient for early SiO2 enrichment; fO2 modestly above Ni-NiO yields daughter liquids with high (calc-alkaline) Mg#s. These values are matched by many natural subduction zone magmas, so seemingly, the problem is solved. Yet, difficulties remain: Melt SiO2 enrichment commences at F: 0.6-0.7 in experiments on hydrous Mg basalts, reaching intermediate SiO2 at F: 0.2-0.4. Cumulates 60-80% of the basalt mass must have returned to the mantle if basalt differentiation formed the continents. Differentiation mainly near the base of the crust has geologic support, and would aid disposal of cumulates, but most experiments on hydrous basalts at such pressures yield peraluminous andesitic liquids, unlike common metaluminous andesites. A composite scenario avoiding peraluminous intermediates is crystallization-differentiation plus mixing with silicic liquids mainly residual or remelted from shortly antecedent intrusions. Even in this case, cumulates and restites exceeding the continental mass must have been lost. The Archean was different: Residual-eclogite-sourced granitoids are widespread, but experiments on hydrous eclogites at plausible temperatures

  16. Controls on long-term low explosivity at andesitic arc volcanoes: Insights from Mount Hood, Oregon (United States)

    Koleszar, Alison M.; Kent, Adam J. R.; Wallace, Paul J.; Scott, William E.


    The factors that control the explosivity of silicic volcanoes are critical for hazard assessment, but are often poorly constrained for specific volcanic systems. Mount Hood, Oregon, is a somewhat atypical arc volcano in that it is characterized by a lack of large explosive eruptions over the entire lifetime of the current edifice (~ 500,000 years). Erupted Mount Hood lavas are also compositionally homogeneous, with ~ 95% having SiO2 contents between 58 and 66 wt.%. The last three eruptive periods in particular have produced compositionally homogeneous andesite-dacite lava domes and flows. In this paper we report major element and volatile (H2O, CO2, Cl, S, F) contents of melt inclusions and selected phenocrysts from these three most recent eruptive phases, and use these and other data to consider possible origins for the low explosivity of Mount Hood. Measured volatile concentrations of melt inclusions in plagioclase, pyroxene, and amphibole from pumice indicate that the volatile contents of Mount Hood magmas are comparable to those in more explosive silicic arc volcanoes, including Mount St. Helens, Mount Mazama, and others, suggesting that the lack of explosive activity is unlikely to result solely from low intrinsic volatile concentrations or from substantial degassing prior to magma ascent and eruption. We instead argue that an important control over explosivity is the increased temperature and decreased magma viscosity that results from mafic recharge and magma mixing prior to eruption, similar to a model recently proposed by Ruprecht and Bachmann (2010). Erupted Mount Hood magmas show extensive evidence for mixing between magmas of broadly basaltic and dacitic-rhyolitic compositions, and mineral zoning studies show that mixing occurred immediately prior to eruption. Amphibole chemistry and thermobarometry also reveal the presence of multiple amphibole populations and indicate that the mixed andesites and dacites are at least 100 °C hotter than the high-SiO2

  17. Geochemistry and petrology of andesites from the north rift zone of Axial Seamount, Juan de Fuca Ridge (United States)

    Smithka, I. N.; Perfit, M. R.; Clague, D. A.; Wanless, V. D.


    In 2013, the ROV Doc Ricketts onboard R/V Western Flyer explored ~4 km of an elongate pillow ridge up to ~300 m high along the eastern edge of the north rift zone of Axial Seamount. The steep-sided volcanic ridge is constructed of large pillow lavas up to 2-3 m in diameter and smaller elongated pillow tubes. Of the 27 samples collected during dive D526, all but one are andesites making it one of the largest confirmed high-silica exposures along a mid-ocean ridge (MOR). Based on radiocarbon ages of sediment on top of flows, the mounds are at least ~1390 years old. This minimum age is much younger than the 56 Ka age calculated based on distance from the rift axis, indicating eruption off-axis through older, colder crust and supporting the hypothesis and model calculations that extensive fractional crystallization (>85%) caused the high silica content. The andesitic lavas are primarily glassy, highly vesicular, crusty, and sparsely phyric with small (~1 mm) plagioclase crystals and olivine, clinopyroxene, and Fe-Ti oxide microphenocrysts. Microprobe analyses of glasses are similar to wax-core samples previously collected from this area but are more compositionally variable. Excluding one basalt (7.7 wt% MgO) sampled between mounds, the lavas are basaltic andesites and andesites (53-59 wt% SiO2) with <3 wt% MgO and 12.8-15.7 wt% FeO concentrations. Incompatible trace element abundances are ~4-6 times more enriched than in Axial Seamount T-MORB. Primitive mantle-normalized patterns are similar to those of high-silica lavas from other MORs (southern Juan de Fuca Ridge, 9N East Pacific Rise) with significant positive U anomalies, large negative Sr anomalies, small negative Eu anomalies, and slight positive Zr-Hf anomalies. The andesites are more enriched in light rare earth elements than basalts from Axial Seamount ((La/Yb)N 1.35-1.4 vs. 0.7-1.27) and N-MORB from the southern Juan de Fuca Ridge. The andesites also have high Cl (~0.3-0.6 wt%) and H2O (~1.60-1.71 wt

  18. Experimental Insights Into the Formation of High-Mg Andesites in the Trans-Mexican Volcanic Belt (United States)

    Weber, R. M.; Wallace, P. J.; Johnston, A.


    High-Mg basaltic andesites and andesites occur in the central Trans-Mexican Volcanic Belt, primarily in the Chichinautzin Volcanic Field south of Mexico City, and their primitive chemical characteristics suggest equilibration with mantle peridotite. These lavas may represent either slab melts that re-equilibrated with peridotite during ascent or hydrous partial melts of a peridotite source. We have experimentally mapped the liquidus mineralogy for a high-Mg basaltic andesite (9.6 wt% MgO, 54.4 wt% SiO2) from the Pelagatos cinder cone as a function of temperature and water content over a range of mantle wedge pressures. We chose this primitive composition rather than a true andesite because samples from the Chichinautzin region with >55 wt% SiO2 and relatively high MgO and Mg# contain textural evidence for contamination in the form of quartz xenocrysts or reaction products. Our experimental results show that the Pelagatos composition could be in equilibrium with a harzburgite residue (with Fo90 olivine) at relatively high water contents (>7 wt%) and low temperatures (1080-1150°C) at pressures ranging from 11 to 14 kbar. These results agree well with a published thermobarometer for peridotite melting, so we use this thermobarometer to estimate equilibration conditions for other primitive magmas in the region. In contrast to the high Ni contents found in olivine phenocrysts in many high-Mg basaltic andesites and andesites produced in Chichinautzin, the olivine phenocrysts in the Pelagatos lava contain Ni contents typical of lherzolite or harzburgite melts that have subsequently fractionated a small amount of olivine after segregating from their mantle source. Because the refractory mantle source for Pelagatos may have had Fo>90 olivine, we estimate formation conditions for the composition recalculated to be in equilibrium with Fo92 olivine. This calculation shifts equilibration conditions to higher temperatures (1190-1270°C) at mantle wedge pressures (11-14 kbar

  19. Genesis of high-Mg andesites through shallow fractionation of primitive arc basalts at elevated oxygen fugacities (United States)

    Zellmer, G. F.; Shellnutt, J. G.


    The petrogenesis of high-Mg andesites has been linked to a variety of processes, including partial melting of hydrous mantle peridotite, re-equilibration of partial melts of the subducting slab with the mantle wedge, and assimilation of lower crustal cumulates into dacitic melts. Yet none of these processes can explain the recently identified association of adakitic andesites, many of which are high-Mg andesites, with regions of elevated surface heat flux that are likely related to unusually shallow magma ponding levels in the upper crust (Zellmer, 2009). Using MELTS modeling, we demonstrate here that at high oxygen fugacities (NNO+2, which based on whole-rock Fe3+/Fe2+ ratios is appropriate for the Western and Central Aleutians, the Trans-Mexican Volcanic Belt, and the Setouchi Volcanic Belt), shallow crustal pressures (0.7 kbar), and initial H2O contents between 0.5 and 4 wt%, iron-magnesium spinel will be fractionated from primitive arc basalts, producing andesitic residual melts with elevated Mg#. Subsequent assimilation of a few percent of autocrystic mafic phases makes typical high-Mg andesites with forsteritic olivines. Orthopyroxenes in equilibrium with these melts are Cr-rich due to increased uptake of Cr into orthopyroxene (Dopx/lq≥25) at lower temperatures (≤1130°C) and elevated oxygen fugacities (NNO+2). While arc magmas with high initial H2O contents will undergo early degassing induced crystallization and viscous stagnation, lower primary melt H2O contents will result in delayed crystallization and shallower magma ponding levels, accounting for elevated surface heat flux. Our findings are therefore consistent with the location of many high-Mg andesites in areas of high surface heat flux, and challenge the commonly accepted notion that these compositions are particularly hydrous primary melts generated in equilibrium with mantle peridotite. Reference: Zellmer G.F. (2009) Petrogenesis of Sr-rich adakitic rocks at volcanic arcs: insights from global

  20. The Origin of Voluminous Dacite (vs. Andesite) at Mature, Thick Continental Arcs: A Reflection of Processes in the Deep Crust (United States)

    Lange, R. A.


    An outstanding question is why some continental arc segments are characterized by voluminous eruptions of dacite (65-70 wt% SiO2), whereas others erupt more andesite (58-64 wt% SiO2) than any other magma type. An example of the former is the Altiplano-Puna region of the central Andean arc, which has erupted a predominance of dacite over all magma types 10-1 Ma (de Silva, 1989). In contrast, a 200-km arc segment of the Mexican volcanic arc (Michoacán-Guanajuato arc segment) has erupted ~75% andesite, ~26% basaltic andesite and 20%) of hornblende-rich (~40%) gabbronorite in the deep crust, driven by mantle-derived basalt intrusions at depths of 30-40 km. The absence of any dacite or rhyolite along this arc segment indicates that interstitial liquid from crystal-rich andesites never segregated to form eruptible magma. Thus, little upper-crust differentiation occurred along this arc segment. On the basis of phase-equilibrium experiments in the literature (e.g., Sisson et al., 2005), it is proposed that rhyolite and dacite did form during partial melting of the lower arc crust, but at melt fractions too low (≤15%) to permit efficient transport to the upper crust (Vigneresse and Tikoff, 1999). It is further proposed that the reason why dacite is so abundant at mature thick continental arcs (e.g., Altiplano-Puno complex) may be because mantle-derived basalts are primarily emplaced at similar depths (~30-40 km) in continental arc crustal columns. If so, in the central Andean arc, a depth of 30-40 km is within the middle dioritic crust (Graeber and Asch, 1999). Partial melts of hornblende diorite (vs. hornblende gabbro) are predicted to be dacitic (vs. andesitic) at melt fractions of 20-25%, which permits transport to the upper crust. It is therefore proposed that it is deep crustal processes that determine whether andesite or dacite is the most voluminous magma type emplaced into the upper crust and erupted at arcs.

  1. Petrogenesis of Mount Rainier andesite: magma flux and geologic controls on the contrasting differentiation styles at stratovolcanoes of the southern Washington Cascades (United States)

    Sisson, Thomas W.; Salters, V.J.M.; Larson, P.B.


    Quaternary Mount Rainier (Washington, USA) of the Cascades magmatic arc consists of porphyritic calc-alkaline andesites and subordinate dacites, with common evidence for mingling and mixing with less evolved magmas encompassing andesites, basaltic andesites, and rarely, basalts. Basaltic andesites and amphibole andesites (spessartites) that erupted from vents at the north foot of the volcano represent some of Mount Rainier's immediate parents and overlap in composition with regional basalts and basaltic andesites. Geochemical (major and trace elements) and isotopic (Sr, Nd, Pb, O) compositions of Mount Rainier andesites and dacites are consistent with modest assimilation (typically ≤20 wt%) of evolved sediment or sediment partial melt. Sandstones and shales of the Eocene Puget Group, derived from the continental interior, are exposed in regional anticlines flanking the volcano, and probably underlie it in the middle to lower crust, accounting for their assimilation. Mesozoic and Cenozoic igneous basement rocks are unsuitable as assimilants due to their high 143Nd/144Nd, diverse206Pb/204Pb, and generally high δ18O.

  2. The Cerro Bitiche Andesitic Field: petrological diversity and implications for magmatic evolution of mafic volcanic centers from the northern Puna (United States)

    Maro, Guadalupe; Caffe, Pablo J.


    The Cerro Bitiche Andesitic Field (CBAF) is one of the two largest mafic volcanic fields in northern Puna (22-24° S) and is spatially and temporally associated with ignimbrites erupted from some central Andean Altiplano-Puna Volcanic Complex calderas. The CBAF comprises seven scoria cones and widespread high-K calcalkaline lava flows that cover an area of 200 km2. Although all erupted rocks have a relatively narrow chemical range (56-62 % SiO2, 3-6 % MgO), there is a broad diversity of mineral compositions and textures. The least evolved lavas (˜58-61 % SiO2) are high-Mg andesites with scarce (andesites (˜62 wt% SiO2), on the other hand, are porphyritic rocks with plagioclase + orthopyroxene + biotite and ubiquitous phenocryst disequilibrium textures. These magmas were likely stored in crustal reservoirs, where they experienced convection caused by mafic magma underplating, magma mixing, and/or assimilation. Trace element and mineral compositions of CBAF lavas provide evidence for complex evolution of distinct magma batches.

  3. Geometry and structure of the andesitic volcano-detritic deposits: The Merapi case (United States)

    Selles, A.; Deffontaines, B.; Hendrayana, H.; Violette, S.


    Several geological studies have been performed on the volcano-detritic deposits but finally the global overview of the geometry of those is still poorly known. The quick alteration enhances the high heterogeneity of these formations, especially under tropical climate. Better knowledge of the structure of the volcano-sedimentary edifices is capital to understand:i) the geomorphological impacts, as landslides ii) or the hydrogeological processes. The Merapi Mount is an andesitic strato-volcano, located in Central Java and is one of the most active volcanoes in Indonesia. About 500,000 people live in the immediate vicinity of the volcano and are directly subject, not only to the volcanic eruptions but also to the landslide hazards. The East flank of the Merapi presents a complex history and has been relatively spared by the recent volcanic activity; thus, the geomorphology and the structure of the deposit have been driven by the erosion and remobilization processes under equatorial climate. This work contributes to understand the processes of construction, destruction and sedimentation of a complex active strato-volcano and shed light to its geological and geomorphological history. Based on field observations and literature, the specific deposits have been identified. The lithological facies have been described and several cross sections have been done to precise the distinct phases of building edifice, due to old eruptions. Recent field surveys allowed characterizing the dismantling steps and processes of the volcano by erosion and the local to distal sedimentation associated. The East flank has been split in four zones where each formation presents a lateral facies variation depending on the distance from the summit and the age of deposits. Based on the collected data, the size and the three dimensional extension of each deposits has been delimitated. The geological and geomorphological interpretation is proposed through a conceptual model.

  4. An experimental investigation of high-temperature interactions between seawater and rhyolite, andesite, basalt and peridotite (United States)

    Hajash, Andrew; Chandler, Gary W.


    Natural seawater was allowed to react with rhyolite, andesite, basalt, and peridotite at 200° 500° C, and 1,000 bars at water/rock mass ratios of 5 and 50 in order to investigate the effects of rock type, water/rock ratio, and temperature on solution chemistry and alteration mineralogy. The results indicate that interactions of seawater with various igneous rocks are similar in the production of a hydrous Mg-silicate and anhydrite as major alteration products. Fluids involved in the interactions lose Mg to alteration phases while leaching Fe, Mn, and Si from the rocks. The pH of the solutions is primarily controlled by Mg-OH-silicate formation and therefore varies with Mg and Si concentration of the system. Other reactions which involve Mg (such as Mg-Ca exchange) or which produce free H+, cause major differences in fluid chemistry between different seawater/ rock systems. High water/rock ratio systems (50/1) are generally more acidic and more efficient in leaching than low ratio systems (5/1), due to relatively more seawater Mg available for Mgsilicate production. The experiments show that large-scale seawater/rock interaction could exert considerable control on the chemistry of seawater, as well as producing large bodies of altered rock with associated ore-deposits. Active plate margins of convergence or divergence are suitable environments for hydrothermal systems due to the concurrence of igneous activity, tectonism, and a nearby water reservoir (seawater or connate water). The experimental data indicate that seawater interactions with igneous host rocks could generate many of the features of ore-deposits such as the Kuroko deposits of Japan, the Raul Mine of Peru, the Bleida deposit of Morocco, and deposits associated with ophiolites. Serpentinization of peridotite and alteration of igneous complexes associated with plate margins can also be explained by seawater interaction with the cooling rock. Geothermal energy production could benefit from experimental

  5. Controls on rind thickness on basaltic andesite clasts weathering in Guadeloupe (United States)

    Sak, P.B.; Navarre-Sitchler, A. K.; Miller, C.E.; Daniel, C.C.; Gaillardet, J.; Buss, H.L.; Lebedeva, M.I.; Brantley, S.L.


    A clast of low porosity basaltic andesite collected from the B horizon of a soil developed on a late Quaternary volcaniclastic debris flow in the Bras David watershed on Basse-Terre Island, Guadeloupe, exhibits weathering like that observed in many weathered clasts of similar composition in other tropical locations. Specifically, elemental profiles measured across the core-rind interface document that primary minerals and glass weather to Fe oxyhydroxides, gibbsite and minor kaolinite in the rind. The earliest reaction identified in the core is oxidation of Fe in pyroxene but the earliest reaction that creates significant porosity is plagioclase dissolution. Elemental loss varies in the order Ca???Na>K???Mg>Si>Al>Fe???P??Ti, consistent with the relative reactivity of phases in the clast from plagioclase???pyroxene???glass>apatite>ilmenite. The rind surrounds a core of unaltered material that is more spherical than the original clast. The distance from the core-rind boundary to a visually prominent rind layer, L, was measured as a proxy for the rind thickness at 36 locations on a slab cut vertically through the nominal center of the clast. This distance averaged 24.4??3.1mm. Maximum and minimum values for L, 35.8 and 20.6mm, were observed where curvature of the core-rind boundary is greatest (0.12mm-1) and smallest (0.018mm-1) respectively. Extrapolating from other rinds in other locations, the rate of rind formation is estimated to vary by a factor of about 2 (from ~4 to 7??10-14ms-1) from low to high curvature. The observation of a higher rate of rind formation for a higher curvature interface is consistent with a diffusion-limited model for weathering rind formation. The diffusion-limited model predicts that, like rind thickness, values of the thickness of the reaction front (h) for a given reaction, defined as the zone over which a parent mineral such as plagioclase completely weathers to rind material, should also increase with curvature. Values of h were

  6. High-Mg andesites petrogenesis by amphibole crystallization and ultramafic crust assimilation (United States)

    Tiepolo, M.; Tribuzio, R.; Langone, A.


    Mafic and ultramafic intrusives with high-Mg andesite (HMA) affinity are occasionally found in collisional settings. These amphibole-rich rocks preserve chemical and textural heterogeneities that are important records of the petrogenetic processes occurring in the deep portions of the arc crust. New insights on the origin of HMA are inferred from the Tertiary amphibole-rich ultramafic intrusives of the southern Adamello batholith (Italian Alps). These rocks consist of large amphibole grains with brown cores (Ti-pargasite) that progressively grade through brownish green (Mg-hornblende) and light green (edenite) rims. Brown amphibole has inclusions of olivine and clinopyroxene (±spinel) with irregular boundaries indicating disequilibrium with the host amphibole. Amphibole shows a marked chemical zoning. In particular, a decrease in Ti, HREE coupled to an increase in Mg, Ni, LREE, Th and U from the core to the rim is observed. Calculated equilibrium liquids for amphibole cores may be related to island arc basalts. On the other hand, liquids in equilibrium with amphibole rims share many compositional similarities to HMA (e.g. low HREE, strong LREE/HREE fractionation, high Th and U). According to the current knowledge of Amph/LD, a fractional crystallization process driven by amphibole may explain most of the observed elemental variations. However, the increase from core to rim of highly compatible elements in amphibole such as MgO and Ni contrasts with closed system fractional crystallization. The assimilation/resorption of olivine is considered the most efficient mechanism to supply or buffer MgO and Ni in the evolving system during amphibole crystallization. The textural disequilibrium of olivine with the host amphibole supports this process. In addition, clusters of olivine with triple junctions (Fo up to 85 mol%) and minor cpx were found in ultramafic rocks of the same complex. They probably represent fragments of older dunites/wehrlites dismembered by the

  7. Geochemistry of Garibaldi Lake andesites and dacites indicates crustal contamination involved in formation of Northern Cascade arc lavas (United States)

    Martindale, M.; Mullen, E.; Weis, D.


    The Cascade Arc presents a unique setting for studying the controls on andesite genesis and the implications for growth and evolution of the continental crust. It is the type-locality for a ';hot' subduction zone, where the downgoing slab is young and subduction is relatively slow. The northern segment of the Cascade arc, the Garibaldi Volcanic Belt (GVB), hosts the youngest subducting crust in Cascadia and the termination of the subducting slab. These conditions may affect magma generation processes by reducing the amount of water reaching the area of melt generation [1,2] and imparting an adakitic signature to magmas generated there if the slab edge melts [3]. We provide insights on the origin of andesites and dacites from the Garibaldi Lake area using new high-precision Pb, Sr, Nd, Hf isotope ratios and trace element data. Andesites and dacites from the Garibaldi Lake area (The Black Tusk, Mt. Price, and The Table) are calc-alkaline and show evidence for crustal contamination such as positive correlations between Ba/Nb and SiO2. Silica variation diagrams show no systematic trend for any of the volcanic centres, suggesting the presence of distinct magma batches. Garibaldi Lake andesites and dacites have among the least radiogenic Pb isotope ratios of all Cascade arc lavas, and define a linear array in Pb-isotope space. This most likely reflects mixing between MORB-source mantle (similar to Gorda and Explorer plate sources) and locally subducting sediments [4]. However, relative to GVB basalts and lavas from the rest of the Cascades (High Cascades), the andesites and dacites have higher 207Pb/204Pb (15.55-15.56) for a given 206Pb/204Pb (18.66-18.74). The Garibaldi Lake lavas also have higher 87Sr/86Sr (0.7033-0.7036) and lower ɛNd (5.8-7.9) at a given 206Pb/204Pb than GVB basalts and High Cascades lavas but among the highest ɛNd for a given SiO2 for the whole of the Cascades. ɛHf values (10.5-13.5) are higher at a given SiO2 value for Garibaldi Lake evolved

  8. Experimental insights into the formation of high-Mg basaltic andesites in the trans-Mexican volcanic belt (United States)

    Weber, Rachel M.; Wallace, Paul J.; Dana Johnston, A.


    High-Mg basaltic andesites and andesites occur in the central trans-Mexican volcanic belt, and their primitive geochemical characteristics suggest equilibration with mantle peridotite. These lavas may represent slab melts that reequilibrated with overlying peridotite or hydrous partial melts of a peridotite source. Here, we experimentally map the liquidus mineralogy for a high-Mg basaltic andesite (9.6 wt% MgO, 54.4 wt% SiO2, Mg# = 75.3) as a function of temperature and H2O content over a range of mantle wedge pressures. Our results permit equilibration of this composition with a harzburgite residue at relatively high water contents (>7 wt%) and low temperatures (1,080-1,150°C) at 11-14 kbar. However, in contrast to the high Ni contents characteristic of olivine phenocrysts in many such samples from central Mexico, those of olivine phenocrysts in our sample are more typical of mantle melts that have fractionated a small amount of olivine. To account for this and the possibility that the refractory mantle source may have had olivine more Fo-rich than Fo90, we numerically evaluated alternative equilibration conditions, using our starting bulk composition adjusted to be in equilibrium with Fo92 olivine. This shifts equilibration conditions to higher temperatures (1,180-1,250°C) at mantle wedge pressures (11-15 kbar) for H2O contents (>3 wt%) comparable to those analyzed in olivine-hosted melt inclusions from this region. Comparison with geodynamic models shows that final equilibration occurred shallower than the peak temperature of the mantle wedge, suggesting that basaltic melts from the hottest part of the wedge reequilibrated with shallower mantle as they approached the Moho.

  9. Geochemistry of the high-Mg andesites at Zhangwu, western Liaoning: Implication for delamination of newly formed lower crust

    Institute of Scientific and Technical Information of China (English)

    HUANG; Hua; GAO; Shan; HU; ZhaoChu; LIU; XiaoMing; YUAN; HongLing


    Ten volcanic samples at Zhangwu, western Liaoning Province, North China were selected for a systematic geochemical, mineralogical and geochronological study, which provides an opportunity to explore the interaction between the continental crust and mantle beneath the north margin of the North China craton. Except one basalt sample (SiO2= 50.23%), the other nine samples are andesitic with SiO2 contents ranging from 53% to 59%. They have relatively high MgO (3.4%-6.1%, Mg#=50-64) and Ni and Cr contents (Ni 27×10-6-197×10-6, Cr 51×10-6-478×10-6). Other geochemical characteristics of Zhangwu high-Mg andesites (HMAs) include strong fractionation of light rare earth elements (LREE) from heavy rare earth elements (HREE), and Sr from Y, with La/Yb greater than 15, and high Sr/Y (34-115). Zircons of andesite YX270 yield three age groups with no Precambrian age, which precludes origin of the Zhangwu HMAs from the partial melting of the Precambrian crust. The oldest age group peaking at 253 Ma is interpreted to represent the collision of the Siberia block and the North China block, resulting in formation of the Central Asian orogenic belt by closure of the Mongol-Okhotsk Ocean. The intermediate age group corresponds to the basalt underplating which caused the widespread coeval granitoids in the North China craton with a peak 206Pb/238U age of 172 Ma. The youngest age group gives a 206Pb/238U age of 126±2 Ma, which is interpreted as the eruption age of the Zhangwu HMAs. The high 87Sr/86Sri(126 Ma)>0.706 and low -Nd(t)= -6.36--13.99 of the Zhangwu HMAs are distinct from slab melts. The common presence of reversely zoned clinopyroxene phenocrysts in the Zhangwu HMAs argues against the origin of the Zhangwu HMAs either from melting of the water saturated mantle or melting of the lower crust. In light of the evidence mentioned above, the envisaged scenario for the formation of the Zhangwu HMAs is related to the basaltic underplating at the base of the crust, which led to

  10. Rhyolitic calderas and centers clustered within the active andesitic belt of Ecuador's Eastern Cordillera

    Energy Technology Data Exchange (ETDEWEB)

    Mothes, Patricia A; Hall, Minard L [Instituto Geofisico, Escuela Politecnica Nacional, Quito (Ecuador)], E-mail:


    In the Ecuadorian volcanic arc a cluster of scattered rhyolitic and dacitic centers within the mainly andesitic Eastern Cordillera includes large caldera structures (Chalupas, Chacana, Cosanga) as well as smaller edifices, built upon the Paleozoic-Mesozoic metamorphic basement. At the Chacana caldera magmatism dates from 2.7 Ma to historic times. These centers erupted enormous ash flows and thick pumice lapilli falls that covered the InterAndean Valley near Quito. The role of the 50-70 km-thick crust with a notable negative gravity anomaly appears to be related to the generation of this highly silicic magmatism occurring along the crest of the Andes in the NVZ.

  11. Contemporaneous trachyandesitic and calc-alkaline volcanism of the Huerto Andesite, San Juan Volcanic Field, Colorado, USA (United States)

    Parat, F.; Dungan, M.A.; Lipman, P.W.


    Locally, voluminous andesitic volcanism both preceded and followed large eruptions of silicic ash-flow tuff from many calderas in the San Juan volcanic field. The most voluminous post-collapse lava suite of the central San Juan caldera cluster is the 28 Ma Huerto Andesite, a diverse assemblage erupted from at least 5-6 volcanic centres that were active around the southern margins of the La Garita caldera shortly after eruption of the Fish Canyon Tuff. These andesitic centres are inferred, in part, to represent eruptions of magma that ponded and differentiated within the crust below the La Garita caldera, thereby providing the thermal energy necessary for rejuvenation and remobilization of the Fish Canyon magma body. The multiple Huerto eruptive centres produced two magmatic series that differ in phenocryst mineralogy (hydrous vs anhydrous assemblages), whole-rock major and trace element chemistry and isotopic compositions. Hornblende-bearing lavas from three volcanic centres located close to the southeastern margin of the La Garita caldera (Eagle Mountain - Fourmile Creek, West Fork of the San Juan River, Table Mountain) define a high-K calc-alkaline series (57-65 wt % SiO2) that is oxidized, hydrous and sulphur rich. Trachyandesitic lavas from widely separated centres at Baldy Mountain-Red Lake (western margin), Sugarloaf Mountain (southern margin) and Ribbon Mesa (20 km east of the La Garita caldera) are mutually indistinguishable (55-61 wt % SiO2); they are characterized by higher and more variable concentrations of alkalis and many incompatible trace elements (e.g. Zr, Nb, heavy rare earth elements), and they contain anhydrous phenocryst assemblages (including olivine). These mildly alkaline magmas were less water rich and oxidized than the hornblende-bearing calc-alkaline suite. The same distinctions characterize the voluminous precaldera andesitic lavas of the Conejos Formation, indicating that these contrasting suites are long-term manifestations of San Juan

  12. Phenocryst complexity in andesites and dacites from the Tequila volcanic field, Mexico: resolving the effects of degassing vs. magma mixing (United States)

    Frey, Holli M.; Lange, Rebecca A.


    The petrology of five phenocryst-poor (2-5%) andesites and dacites, all of which were erupted from different short-lived, monogenetic vents, is compared to that of phenocryst-rich (10-25%) andesites erupted from the adjacent stratovolcano, Volcán Tequila, in the Mexican arc. Despite differences in phenocryst abundances, these magmas have comparable phase assemblages (plagioclase + orthopyroxene + titanomagnetite + ilmenite + apatite ± augite ± hornblende), and similarly wide variations in phenocryst compositions, coupled to complex zoning patterns. For the phenocryst-poor lavas, equilibrium pairs of two Fe-Ti oxides lead to a narrow range of calculated temperatures for each sample that range from 934 (±24) to 1,073 (±6)°C and oxygen fugacities that range from +0.1 to +0.7 log units relative to the Ni-NiO buffer. Application of the plagioclase-liquid hygrometer to each sample at these calculated temperatures leads to maximum melt water concentrations of 4.6-3.1 wt% during plagioclase crystallization, indicating that the magmas were fluid saturated at depths ≥6.4-4.5 km. There is a wide, continuous range in the composition of plagioclase (≤44 mol% An) and orthopyroxene (≤16% Mg#) phenocrysts in each sample, which is consistent with a loss of dissolved water (≤2.8 wt%) from the melt phase during degassing as the magmas ascended rapidly to the surface. Evidence is presented that shows the effect of dissolved water is to reduce the activity of MgO relative to FeO in the melt phase, which indicates that degassing will also affect the Mg# of pyroxene phenocrysts, with higher melt water concentrations favoring Fe-rich pyroxene. Both plagioclase and orthopyroxene commonly display diffusion-limited growth textures (e.g., skeletal and hopper crystals, large interior melt hollows, and swallow tails), which are consistent with large undercoolings produced by degassing-induced crystallization. Therefore, degassing is proposed as a possible cause for the phenocryst

  13. Soluble iron inputs to the Southern Ocean through recent andesitic to rhyolitic volcanic ash eruptions from the Patagonian Andes (United States)

    Simonella, L. E.; Palomeque, M. E.; Croot, P. L.; Stein, A.; Kupczewski, M.; Rosales, A.; Montes, M. L.; Colombo, F.; García, M. G.; Villarosa, G.; Gaiero, D. M.


    Patagonia, due to its geographic position and the dominance of westerly winds, is a key area that contributes to the supply of nutrients to the Southern Ocean, both through mineral dust and through the periodic deposits of volcanic ash. Here we evaluate the characteristics of Fe dissolved (into soluble and colloidal species) from volcanic ash for three recent southern Andes volcanic eruptions having contrasting features and chemical compositions. Contact between cloud waters (wet deposition) and end-members of andesitic (Hudson volcano) and rhyolitic (Chaitén volcano) materials was simulated. Results indicate higher Fe release and faster liberation rates in the andesitic material. Fe release during particle-seawater interaction (dry deposition) has higher rates in rhyolitic-type ashes. Rhyolitic ashes under acidic conditions release Fe in higher amounts and at a slower rate, while in those samples containing mostly glass shards, Fe release was lower and faster. The 2011 Puyehue eruption was observed by a dust monitoring station. Puyehue-type eruptions can contribute soluble Fe to the ocean via dry or wet deposition, nearly reaching the limit required for phytoplankton growth. In contrast, the input of Fe after processing by an acidic eruption plume could raise the amount of dissolved Fe in surface ocean waters several times, above the threshold required to initiate phytoplankton blooms. A single eruption like the Puyehue one represents more than half of the yearly Fe flux contributed by dust.

  14. Morpho-tectonics and mechanism of emplacement of the andesitic ring in Givshad, east of Iran (United States)

    Khatib, M. M.; Zarrinkoub, M. H.


    matter of debate for a considerable period of time. However, the mechanism for is emplacement still remains an enigma. A large quantity of geological information, maps, field data have become available over the last 30 years. The Eocene Givshad volcanism intruded into the Paleocene flysch type sediments. These flysch sediments are deposited over an ophiolite mélange sequence in south of Birjand, east of Iran. This ophiolite mélange is introduced as cretaceous sequence. A transperssional tectonic regime case emplacement the oceanic lithosphere segments over continental margin by in upper cretaceous-early tertiary. Some local shear zones with E-W general trends have occurred during emplacement period. Shear zones reactivation happen after Paleocene flysch type sedimentation. These processes have created three different types of deep open spaces. Rhomboid, lensoidal and wedge shape spaces made deep conduits in crustal shear zones. Two large-size ring-like structures were investigated in Givshad area. The size of ring-like structures are variable and ranges from 1×1.5 km to 0.9 × 1.2 Km. Based on the field structural data, vertical cross section of maps and morphotectonic evidences these structure aren't ring sill or dykes. They should be collapsed structure of andesitic dome ascending and it looks as a caldera. The formations of these calderas are classically ascribed to the vertical collapse of the overlying roof during emptying of a shallow magma chamber. This vertical collapse occurs along a ring fault system and leaves a vast, circular and flat-lying depression limited by sub-vertical cliffs that can reach several ten meters high. The walls of ring-like structure have been affected by systematic shear joints. Crossed joints prepare a background for wethering and alteration inside the ring. Key words: ring-like structures, collapse, Givshad area, morphotectonic, transperssional

  15. Analysis of noise pollution in an andesite quarry with the use of simulation studies and evaluation indices. (United States)

    Kosała, Krzysztof; Stępień, Bartłomiej


    This paper presents the verification of two partial indices proposed for the evaluation of continuous and impulse noise pollution in quarries. These indices, together with the sound power of machines index and the noise hazard index at the workstation, are components of the global index of assessment of noise hazard in the working environment of a quarry. This paper shows the results of acoustic tests carried out in an andesite quarry. Noise generated by machines and from performed blasting works was investigated. On the basis of acoustic measurements carried out in real conditions, the sound power levels of machines and the phenomenon of explosion were determined and, based on the results, three-dimensional models of acoustic noise propagation in the quarry were developed. To assess the degree of noise pollution in the area of the quarry, the continuous and impulse noise indices were used.

  16. Crystallization of oxidized, moderately hydrous arc basalt at mid- to lower-crustal pressures: Implications for andesite genesis (United States)

    Blatter, Dawnika L.; Sisson, Thomas W.; Hankins, W. Ben


    This study focuses on the production of convergent margin calc-alkaline andesites by crystallization–differentiation of basaltic magmas in the lower to middle crust. Previous experimental studies show that dry, reduced, subalkaline basalts differentiate to tholeiitic (high Fe/Mg) daughter liquids, but the influences of H2O and oxidation on differentiation are less well established. Accordingly, we performed crystallization experiments at controlled oxidized fO2 (Re–ReO2 ≈ ΔNi–NiO + 2) on a relatively magnesian basalt (8.7 wt% MgO) typical of mafic magmas erupted in the Cascades near Mount Rainier, Washington. The basalt was synthesized with 2 wt% H2O and run at 900, 700, and 400 MPa and 1,200 to 950 °C. A broadly clinopyroxenitic crystallization interval dominates near the liquidus at 900 and 700 MPa, consisting of augite + olivine + orthopyroxene + Cr-spinel (in decreasing abundance). With decreasing temperature, plagioclase crystallizes, Fe–Ti-oxide replaces spinel, olivine dissolves, and finally amphibole appears, producing gabbroic and then amphibole gabbroic crystallization stages. Enhanced plagioclase stability at lower pressure narrows the clinopyroxenitic interval and brings the gabbroic interval toward the liquidus. Liquids at 900 MPa track along Miyashiro’s (Am J Sci 274(4):321–355, 1974) tholeiitic versus calc-alkaline boundary, whereas those at 700 and 400 MPa become calc-alkaline at silica contents ≥56 wt%. This difference is chiefly due to higher temperature appearance of magnetite (versus spinel) at lower pressures. Although the evolved liquids are similar in many respects to common calc-alkaline andesites, the 900 and 700 MPa liquids differ in having low CaO concentrations due to early and abundant crystallization of augite, with the result that those liquids become peraluminous (ASI: molar Al/(Na + K + 2Ca) > 1) at ≥61 wt% SiO2, similar to liquids reported in other studies of the high-pressure crystallization of hydrous basalts

  17. A chilled margin of komatiite and Mg-rich basaltic andesite in the western Bushveld Complex, South Africa (United States)

    Maier, W. D.; Barnes, S.-J.; Karykowski, B. T.


    A chill sequence at the base of the Lower Zone of the western Bushveld Complex at Union Section, South Africa, contains aphanitic Mg-rich basaltic andesite and spinifex-textured komatiite. The basaltic andesite has an average composition of 15.2 % MgO, 52.8 % SiO2, 1205 ppm Cr, and 361 ppm Ni, whereas the komatiite has 18.7 % MgO, 1515 ppm Cr, and 410 ppm Ni. Both rock types have very low concentrations of immobile incompatible elements (0.14-0.72 ppm Nb, 7-31 ppm Zr, 0.34-0.69 ppm Th, 0.23-0.27 wt% TiO2), but high PGE contents (19-23 ppb Pt, 15-16 ppb Pd) and Pt/Pd ratios (Pt/Pd 1.4). Strontium and S isotopes show enriched signatures relative to most other Lower Zone rocks. The rocks could represent a ~20 % partial melt of subcontinental lithospheric mantle. This would match the PGE content of the rocks. However, this model is inconsistent with the high SiO2, Fe, and Na2O contents and, in particular, the low K2O, Zr, Hf, Nb, Ta, Th, LREE, Rb, and Ba contents of the rocks. Alternatively, the chills could represent a komatiitic magma derived from the asthenosphere that underwent assimilation of the quartzitic floor accompanied by crystallization of olivine and chromite. This model is consistent with the lithophile elements and the elevated Sr and S isotopic signatures of the rocks. However, in order to account for the high Pt and Pd contents of the magma, the mantle must have been twice as rich in PGE as the current estimate for PUM, possibly due to a component of incompletely equilibrated late veneer.

  18. Origin of co-existing basalts, high-Mg andesites, and adakites in the SW Japan hot subduction system (United States)

    Kimura, J.; Kunikiyo, T.; Osaka, I.; Shimoshioiri, Y.; Katakuse, M.; Kakubuchi, S.; Nagao, T.; Furuyama, K.; Kamei, A.; Nakajima, J.; Stern, R. J.; Gill, J. B.


    In response to subduction of the young, hot Shikoku Basin of the Philippine Sea Plate (PSP) slab, arc magmas have been active throughout the late Cenozoic (high-Mg andesites (HMAs), and adakitic andesites and dacites. The OIB-type basalts preceded the arc-type magmas. Therefore, the transition from OIB- to arc-types was related to opening of the Japan of Sea back-arc basin and subsequent re-initiation of PSP subduction. However, both the origin and tectonic implications of this magmatism are debated. Consequently, we analyzed the bulk rock geochemistry of 340 lava samples from seven Quaternary volcanoes and investigated their sources and melting conditions using a geochemical mass balance model, Arc Basalt Simulator version 4 (ABS4). Comparison to basement granitoids precludes adakite genesis in the lower crust. Instead, the ABS4 model suggests that the adakites are mostly slab melts plus minor interaction with mantle wedge peridotite (PERID). Increasing involvement of PERID during slab melt-fluxed mantle melting explains fairly well the geochemical variations of the shoshonites, mildly alkalic to sub-alkalic basalts, and HMAs. We propose that the generation of various magma types in the late Cenozoic SW Japan arc originated simply by "slab melt-fluxed mantle melting" with large variations in melting conditions including depth, temperature, degree of melting, and flux fractions. Such volcanism has been continuous from 13 Ma (Setouchi HMA) to the present, so that the hot subduction system, involving subduction of the Shikoku Basin spreading ridge, should be continuous since 13 Ma beneath the SW Japan arc. Our results further suggest that this atypically hot system generated diverse primary arc magmas from various degrees of flux melting even though the slab source components and sub-arc mantle are fairly homogeneous.

  19. Origin of Permian andesites from Xi Ujimqin, the Hinggan Mountains: Contributions of lower crust North China Carton (United States)

    Gao, X.


    Andesite magmas at convergent margins are enriched in silica compared to magmas erupting at mid-ocean ridges and intra-plate volcanoes. Determining the cause (s) of silica enrichment is fundamental for models of continental crust formation, arc growth rates and across-arc mass balances (Plank and Langmuir, 1993; Rudnick, 1995; White et al., 2006).The Xi-Ujimqin is located the eastern segment of the Central Asian Orogenic Belt , the CAOB is composed of mainly subduction-accretion complexes, intruded by vast plutons of mainly magmatic arc origin and covered in places by their volcanic derivatives (Sengor et al. 1993; Sengor and Natalin 1996). As the most important site for Phanerozoic crustal growth in the world, the subduction-accretion complexes added ~ 5.3 million km2of material to Asia, half of which may be of juvenile origin (Sengor et al. 1993).The andesitic lavas of Daotenuoer Fms. at Xi-Ujimqin have different trace and Sr-Nd-Pb isotopic characteristic from them, these rocks span a SiO2 range of 56.83 ~ 59.17% and MgO of range of 1.21~2.91%, characterized by obviously LREE/HREE fractionation (Ce/YbCN = 11.6 ~ 16.8), strong LILE enrichment and variable Nb-Ta and Sr depletion. They have more radiogenic Sr and less radiogenic Nd and Pb isotopic composition (87Sr/86Sr(i) = 0.7063 ~ 0.7066, eNd(t) = -10.5 ~ -6.3,TDM = 1.22 ~ 1.51Ga, 206Pb / 204Pb(i) = 17.29 ~ 17.33, D7/4 = 3.7 ~ 6.9, D 8/4 = 94 ~ 104) than the contemporaneous intermediate-felsic volcanic lavas. Zircon U-Pb dating results give an emplacement age of ~253 Ma for the these rocks by LA-ICP-MS, corresponding to the Late Permian. The features of major, trace and Sr-Nd-Pb isotope of These rocks imply its sources are of attributes of lower crust North China Carton (NCC) during Paleozoic subduction and collision related to the closure of the Chinese segment of the Paleo-Asian Ocean between the NCC and south Mongolia Block (Sengor et al., 1993).

  20. The partitioning of sulfur and chlorine between andesite melts and magmatic volatiles and the exchange coefficients of major cations (United States)

    Zajacz, Zoltán; Candela, Philip A.; Piccoli, Philip M.; Sanchez-Valle, Carmen


    Andesite melts were equilibrated with an H-O-S-bearing volatile phase to determine the partition coefficients for S and Cl as a function of melt composition and oxygen fugacity. The experiments were conducted in rapid-quench MHC vessel assemblies at 200 MPa and 1000 °C, and over a range of imposed fO2 between NNO-1.2 and NNO+1.8. High fluid/melt mass ratios (∼15) were employed, allowing precise and accurate partition coefficients to be obtained by mass balance calculations. Chlorine exhibits Henrian behavior at ClO-0.5 activities typical for arc magmas, with D Cl volatile/melt = 1.36 ± 0.06 (1σ) below 0.2 wt.% Cl in the melt; at higher ClO-0.5 activities, D Cl volatile/melt increases linearly to 2.11 ± 0.02 at 1 wt.% Cl in the melt. In the volatile phase: FeCl2 ∼ NaCl > KCl ∼ HCl. The determination of cation exchange coefficients for major cations yielded: K K,Na volatile/melt = 1.23 ± 0.10 (1σ) and ∗K Fe,Na volatile/melt = D Fe volatile/melt / D Na volatile/melt = 1.08 ± 0.16 (1σ). Under these conditions, the concentration of HCl in the vapor is negatively correlated with the (Na + K)/(Al + Fe3+) ratio in the melt. Reduced sulfur (S2-) appears to obey Henry's law in andesite melt-volatile system at fH2S below pyrrhotite saturation. The partition coefficient for S at fO2 = NNO-0.5 correlates negatively with the FeO concentration in the melt, changing from 254 ± 25 at 4.0 wt.% FeO to 88 ± 6 at 7.5 wt.% FeO. Pyrrhotite saturation is reached when approximately 3.2 mol% S is present in the volatile phase at fO2 = NNO-0.5. At the sulfide/sulfate transition, the partition coefficient of S drops from 171 ± 23 to 21 ± 1 at a constant FeO content of ∼6 wt.% in the melt. At fO2 = NNO+1.8, anhydrite saturation is reached at ∼3.3 mol% S present in the volatile phase. Aqueous volatiles exsolving from intermediate to mafic magmas can efficiently extract S, and effect its transfer to sites of magmatic-hydrothermal ore deposit formation.

  1. Peninsular terrane basement ages recorded by Paleozoic and Paleoproterozoic zircon in gabbro xenoliths and andesite from Redoubt volcano, Alaska (United States)

    Bacon, Charles R.; Vazquez, Jorge A.; Wooden, Joseph L.


    Historically Sactive Redoubt volcano is an Aleutian arc basalt-to-dacite cone constructed upon the Jurassic–Early Tertiary Alaska–Aleutian Range batholith. The batholith intrudes the Peninsular tectonostratigraphic terrane, which is considered to have developed on oceanic basement and to have accreted to North America, possibly in Late Jurassic time. Xenoliths in Redoubt magmas have been thought to be modern cumulate gabbros and fragments of the batholith. However, new sensitive high-resolution ion microprobe (SHRIMP) U-Pb ages for zircon from gabbro xenoliths from a late Pleistocene pyroclastic deposit are dominated by much older, ca. 310 Ma Pennsylvanian and ca. 1865 Ma Paleoproterozoic grains. Zircon age distributions and trace-element concentrations indicate that the ca. 310 Ma zircons date gabbroic intrusive rocks, and the ca. 1865 Ma zircons also are likely from igneous rocks in or beneath Peninsular terrane basement. The trace-element data imply that four of five Cretaceous–Paleocene zircons, and Pennsylvanian low-U, low-Th zircons in one sample, grew from metamorphic or hydrothermal fluids. Textural evidence of xenocrysts and a dominant population of ca. 1865 Ma zircon in juvenile crystal-rich andesite from the same pyroclastic deposit show that this basement has been assimilated by Redoubt magma. Equilibration temperatures and oxygen fugacities indicated by Fe-Ti–oxide minerals in the gabbros and crystal-rich andesite suggest sources near the margins of the Redoubt magmatic system, most likely in the magma accumulation and storage region currently outlined by seismicity and magma petrology at ∼4–10 km below sea level. Additionally, a partially melted gabbro from the 1990 eruption contains zircon with U-Pb ages between ca. 620 Ma and ca. 1705 Ma, as well as one zircon with a U-Th disequilibrium model age of 0 ka. The zircon ages demonstrate that Pennsylvanian, and probably Paleoproterozoic, igneous rocks exist in, or possibly beneath, Peninsular

  2. Geochemical constraints on the origin of Late Mesozoic andesites from the Ningwu basin in the Middle-Lower Yangtze Valley, South China (United States)

    Chen, Long; Zheng, Yong-Fei; Zhao, Zi-Fu


    An integrated study of zircon U-Pb ages, Hf-O isotopes, whole-rock major-trace elements and Sr-Nd-Hf isotopes was carried out for Mesozoic andesites from the Ningwu basin in the Middle-Lower Yangtze Valley, South China. The results not only provide insights into the origin of anorogenic magmatism in the Middle-Lower Yangtze Valley but also shed light on the petrogenesis of continental arc andesites in general. The Ningwu andesites are mainly composed of trachyandesite and trachyte, with subordinate of basaltic trachy-andesites. They exhibit variable and low MgO contents of 0.1-3.7 wt.% and low Mg# values of 1.6-51.2, high K2O contents of 2.0-9.9 wt.%. They are characterized by arc-like trace element distribution patterns, with significant enrichment in LILE and LREE but depletion in HFSE. Furthermore, these rocks exhibit relatively enriched whole-rock Sr-Nd-Hf-Pb isotope compositions, with initial 87Sr/86Sr ratios of 0.7050-0.7082, negative εNd(t) values of - 8.1 to - 1.8, and negative εHf(t) values of - 6.7 to 0.4. Zircon U-Pb dating yields consistent ages of 128 ± 2 to 133 ± 2 Ma for magma emplacement through volcanic eruption. The zircon exhibits slightly high δ18O values of 5.7-7.8‰ and variable εHf(t) values of - 5.8 to 0.7. All andesites can be categorized into two groups in view of their distinct geochemical compositions, an integrated interpretation of which allows deciphering of their petrogenesis. Group I andesite was produced by a relatively larger extent of partial melting of a more fertile and enriched mantle source that contains a greater amount of phlogopite, whereas Group II andesite was generated by a relatively smaller extent of partial melting of a less fertile and enriched mantle source that contains a less amount of phlogopite. In either case, these two mantle sources are less ultramafic in lithochemistry than normal mantle peridotite due to its reaction with metasediment-derived hydrous felsic melts. This metasomatism would take place

  3. Origin of Miocene andesite and dacite in the Goldfield-Superstition volcanic province, central Arizona: Hybrids of mafic and silicic magma mixing (United States)

    Fodor, R. V.; Johnson, Kelly G.


    The Miocene Goldfield-Superstition volcanic province (G-SVP), ∼8000 km2 in central Arizona, is composed largely of silicic pyroclastic rocks and lavas, and smaller volumes of alkalic basalt and intermediate-composition lavas. Volcanism began ∼20.5 Ma as sparse rhyolitic and mainly basaltic lavas followed by intermediate lavas, lasting until ∼19 Ma. At that time, ∼1 m.y. of silicic eruptions began, creating most of the G-SVP. Petrologic studies are available for basalts and some for silicic rocks, but petrologic/geochemical information is sparse for intermediate-composition lavas. These latter, andesites and dacites, are the focus of this study, in which we present the processes and sources responsible for their origins. Goldfield-Superstition andesites and dacites have SiO2 ∼56-70 wt.% and Na2O + K2O that qualifies some as trachy-andesite and -dacite. A prominent petrographic feature is plagioclase-phyric texture (∼11-30 vol% plagioclase), where oligoclase-andesine phenocrysts have cores surrounded by corroded, or reacted, zones, mantled by higher An% plagioclase. Where corroded zones are absent, margins are etched, curved, or embayed. Groundmass plagioclase is labradorite, also more calcic than the phenocrysts. Other minerals are quartz (subrounded; embayed), clinopyroxene, amphibole, biotite, and rare titanite and zircon. A salient compositional characteristic that provides insight to andesite-dacite origins with respect to other G-SVP rocks is revealed when using SiO2 as an index. Namely, abundances of many incompatible elements, mainly HFSE and REE, decrease over the low to high SiO2 range (i.e., abundances are lower in dacites than in co-eruptive andesites and underlying alkalic basalts). As examples: G-SVP basalts have ∼50-70 ppm La, and andesites-dacites have ∼59-22 ppm La; for Zr, basalts have ∼225-170 ppm, but most andesites-dacites have ∼180-50; for Y, basalts >20 ppm, andesites-dacites ∼18-9 ppm. To understand these trends of lower

  4. Genesis of high-Mg andesites (HMA) through shallow fractionation of primitive arc basalts at elevated oxygen fugacities (and low initial water contents) (United States)

    Zellmer, Georg; Shellnutt, Gregory


    The petrogenesis of high-Mg andesites has been linked to a variety of processes, including partial melting of hydrous mantle peridotite, re-equilibration of partial melts of the subducting slab with the mantle wedge, and assimilation of lower crustal cumulates into dacitic melts. Yet none of these processes can explain the recently identified association of adakitic andesites, many of which are high-Mg andesites, with regions of elevated surface heat flux that are related to unusually shallow magma ponding levels in the upper crust (Zellmer, 2009). Using MELTS modeling, we demonstrate here that at elevated oxygen fugacities (NNO+2, which based on whole-rock Fe3+/Fe2+ ratios is appropriate for the Western and Central Aleutians, the Trans-Mexican Volcanic Belt, and the Setouchi Volcanic Belt), shallow crustal pressures (0.7 kbar), and initial H2O contents between 0.5 and 4 wt%, iron-magnesium spinel will be fractionated from primitive arc basalts, producing andesitic residual melts with elevated Mg#. Subsequent assimilation of a few percent of autocrystic mafic phases makes typical high-Mg andesites with forsteritic olivines. Orthopyroxenes in equilibrium with these melts are Cr-rich due to increased uptake of Cr into orthopyroxene (Dopx-lq ≥25) at lower temperatures (≤1130° C) and elevated oxygen fugacities (NNO+2). While arc magmas with high initial H2O contents will undergo early degassing induced crystallization and viscous stagnation, lower primary melt H2O contents will result in delayed crystallization and shallower magma ponding levels, accounting for elevated surface heat flux. Our findings are therefore consistent with the location of many high-Mg andesites in areas of high surface heat flux, and challenge the commonly accepted notion that these compositions are particularly hydrous primary melts generated in equilibrium with mantle peridotite. Reference: Zellmer G.F. (2009) Petrogenesis of Sr-rich adakitic rocks at volcanic arcs: insights from global

  5. The Link between Hi - Magnesium Andesite Distribution in Baja California Peninsula and the Undetached Fragments of the Farallon Plate (United States)

    Wang, Y.; Forsyth, D. W.; Savage, B.


    About 12 Ma, the Guadalupe and Magdalena microplates ceased subducting beneath the North American continent, leaving behind plate fragments that became incorporated into the Pacific plate as spreading ceased. Spreading directions changed dramatically on Magdalena spreading centers, suggesting that the Farallon slab detached from the microplate fragments before or during the cessation of spreading. Although the sinking Farallon plate must have detached from those two microplates, it is not known where the detachments occurred and how much of the young slab was left behind still attached to the unsubducted surface microplates. We delineate the undetached Farallon fragments by looking for associated seismic velocity anomalies using teleseismic Rayleigh wave tomography and the stations of the USArray, NARS-Baja and RESBAN arrays. The lateral extent of the remanent plate fragments is indicated by a high (positive) velocity anomaly at 100 km depth (Figure 1). This landward edge of this anomaly coincides with the distribution of post-subduction high-Mg andesites (Bajaites, black region in Figure 1), which are inferred to involve fluid fluxed melting in overlying asthenospheric wedge and melting of the subducted oceanic crust. Shear velocity anomaly at 100 km

  6. Halogens behaviours in Magma Degassing: Insights into Eruptive Dynamics, Hydrothermal Systems and Atmospheric Impact of Andesitic Volcanism (United States)

    Villemant, B.; Balcone, H.; Mouatt, J.; Michel, A.; Komorowski, J.; Boudon, G.


    Shallow degassing of H2O in andesitic magmas determines the eruptive styles of volcanic eruptions and contributes to the hydrothermal systems developed around active volcanoes. Halogens behaviour during magma degassing primarily depends on their incompatible behaviour in the melts and on water solubility. Thus, residual contents of halogens in volcanic juvenile vitric clasts may be used as tracers of H2O degassing processes during explosive and effusive eruptions. Because of the large range of water-melt partition coefficients of halogens and their relatively low diffusion coefficients, a comparison of F, Cl, Br and I contents in volcanic clasts in function of their vesicularity and micro-cristallinity allows to precisely model the main degassing processes and to establish constraints on pre-eruptive conditions. Halogens acids (HCl, HBr and HI) extracted in the vapour phase have much more complex behaviours because of their high solubility in low temperature thermal waters, their variable condensation temperatures and their very high reactivity when mixed with low temperature and oxidizing atmospheric gases. A comparison of model compositions of high temperature gases with the composition of thermal waters, and gases from fumaroles or plumes of active volcanoes allows to characterise the shallow volcanic system and its evolutionary states. Variable halogen behaviours are discussed for a variety of eruption types (plinian, vulcanian and dome-forming) and active volcanic systems from the Lesser Antilles (Montagne Pelee, Soufrière of Guadeloupe, Soufriere Hills of Montserrat).

  7. Potential reactivity of the andesitic rocks from Cabo de Gata (SE Spain); Reactividad potencial de las rocas andesiticas de Cabo de Gata (SE de Espana)

    Energy Technology Data Exchange (ETDEWEB)

    Soriano, J.; Iglesia, A. la; Garcia Calleja, M. A.; Lopez-Ruiz, J.


    Andesitic rocks produce an alkali-silica reaction with the components of the interstitial phase of concrete. This reaction can be considered as belonging to the slow-kinetic type, since the incongruent dissolution of the rock-forming minerals leads to the late formation of siliceous calc-alkaline gel. As a conquence, the conventional mortar-bar method does not detect such reaction until 90 days later. (Author) 9 refs.

  8. Dynamics of explosive paroxysms at open andesitic systems: high-resolution mass distribution analyses of 2006 tephra from Tungurahua volcano (Ecuador) (United States)

    Le Pennec, J.; Eychenne, J.; Ramon, P.; Yepes, H.


    Many andesitic volcanoes at subduction plate margins can experience in the course of their evolution periods of sub-continuous eruption during years, decades, or centuries. Such long-lived periods may embrace more or less intense outgassing events, extrusion of viscous lava flows and domes (e.g. Colima in Mexico, Merapi in Indonesia, Arenal in Costa Rica), and explosive activity of uneven intensity (e.g. Semeru in Indonesia, Sakurajima in Japan, Sangay in Ecuador). In addition, strong explosive events of short duration may occur, with potential generation of pyroclastic flows on the flanks and beyond, which can pose significant hazards in populated regions. The origin and dynamics of such violent eruptions remain poorly known and may involve a combination of different factors. Tungurahua volcano, Ecuador, reawaken in 1999 and is an example of such open-system behaviour that experienced a strong and deadly andesitic pyroclastic flow-forming event in August 2006. Inspection of the deposits suggested that the event could have been triggered by magma mixing (silicic pumices in the tephra), magma-water interaction (presence of xenolithic clasts) or deep andesitic magma reinjection (based on mineral chemistry). Here we investigate these options by performing a high-resolution mass budget analysis of the scoria fall deposit. This is achieved by analysing componentry compositions and their mass distribution pattern in the layer, which allow us to document and integrate exponential and power laws mass decay rates over wide areas. The results yield a total mass for the tephra layer of ~2 x 1010kg. The pumice mass fraction is far too small (< 0.4 %) to account for the high explosivity of the 2006 event. Similarly, the xenoclastic mass fraction is small (0.2%) and suggests limited magma-water interaction. Instead, we interpret these xenoclasts as a result of upper conduit erosion at a rate of ~30 cm/hour during the paroxysm. Altogether our results support an explosive event

  9. Late Triassic high-Mg andesite/dacite suites from northern Hohxil, North Tibet: Geochronology, geochemical characteristics, petrogenetic processes and tectonic implications (United States)

    Wang, Qiang; Li, Zheng-Xiang; Chung, Sun-Lin; Wyman, Derek A.; Sun, Ya-Li; Zhao, Zhen-Hua; Zhu, Yin-Tang; Qiu, Hua-Ning


    This study reports age, petrologic and geochemical data for andesites and dacites from the Late Triassic sedimentary strata of northern Hohxil, in the Hohxil-Songpan-Ganzi Block (northern Tibet), which constitutes the most voluminous Triassic strata on Earth. LA-ICP-MS zircon U-Pb analysis of dacite (210.4 ± 1.9 Ma) and whole rock 40Ar- 39Ar analyses for both the andesites and dacites (211 ± 2 Ma and 210.9 ± 1.6 Ma) show that the rocks were almost contemporaneous. Both rock types are sodium-rich and calc-alkaline. The andesites, characterized by high MgO (up to 10 wt.%) or Mg # (~ 70), TiO 2, Al 2O 3, Cr, Ni, La/Yb and Th/La, but low Nb/Ta ratios, are geochemically similar to sanukitoids in southeastern Japan. The dacites are strongly peraluminous, and have high Al 2O 3 and La/Yb, low Y and Yb, coupled with negligible to positive Eu and Sr anomalies, comparable to slab-derived adakites in the circum Pacific arc system. Both rocks exhibit strongly fractionated platinum group element patterns, with Pt/Pt* (Pt anomaly), (Pt/Ir) N and Re/Os ratios higher than those of the primitive mantle. They have uniformly low ɛNd(t) values (- 7.57--9.59) and high ( 86Sr/ 87Sr) i ratios (0.7086-0.7106) that imply a continental rather than oceanic type magma source. We suggest that the northern Hohxil dacites were produced by partial melting of subducted sediments on the northward-subducting Songpan-Ganzi oceanic slab, and the high-Mg andesites were formed by subsequent interaction between the sediment-derived melts and mantle wedge peridotites. Taking into account the Triassic magmatic record from nearby regions, we suggest that the Late Triassic high-Mg andesite/dacite suites of northern Hohxil were generated in a forearc setting, and propose that double-sided subduction eventually closed the Songpan-Ganzi ocean during the Late Triassic.

  10. Mechanics and Timescales of Magma Mixing Inferred by Texture and Petrology of Basalt Inclusions and Host Andesite From the 2006 Eruption of Augustine Volcano, Alaska (United States)

    Vitale, M. L.; Browne, B. L.


    This study characterizes the texture, mineralogy and phenocryst disequilibrium textures in basaltic inclusions and host andesite lavas and scoria to advance our understanding of the mechanics and timescales of open system magma processes driving the 2006 eruption at Augustine Volcano, Alaska. Inclusions account for approximately 1 volume percent in all andesite lithologies emplaced during the explosive, continuous, and effusive eruption phases. In outcrop, quenched basaltic to andesite inclusions (51.3 to 57.3 weight percent SiO2) hosted by andesite lavas (59.1-62.6 weight percent SiO2) range in diameter from 1 cm to over 9 cm, are dark black and characterized by vesicular interiors, quenched and cuspate margins, and porphyritic texture. Inclusion mineralogy is dominated by phenocryst-sized plagioclase with lesser amounts of hornblende, clinopyroxene and olivine, as well as, microphenocrysts-sized plagioclase, hornblende, clinopryoxene, olivine, magnetite, ilmenite and apatite in a glassy, vesicular and acicular groundmass. Intrusion of a hotter, basaltic magma into a cooler silicic magma followed by inclusion formation through mingling processes is evidenced by (1) plagioclase crystal textures displaying (a) oscillatory zoned interiors surrounded by a dusty sieved layer and enclosed by clear, euhedral overgrowth rims, (b) coarsely-sieved interiors characterized by 0.01 mm -0.02 mm diameter melt inclusions and/or similarly sized inclusions of clinopyroxene, orthopryoxene, or hornblende, (2) Anorthite concentration profiles of engulfed host plagioclase crystals displaying contact with a basaltic magma, (3)Fe-Ti oxides from inclusions and low-silica andesite host recording core to rim temperatures ranging from 908°C to 1100°C, indicative of pre- and post- mixing temperatures, respectively, with oxygen fugacity approximately 2 log units above the nickel-nickel oxide buffer. The closest approximation of the basaltic end-member magma composition involved in magma

  11. Trace element geochemistry and petrogenesis of the granitoids and high-K andesite hosting gold mineralisation in the Archean Musoma-Mara Greenstone Belt, Tanzania (United States)

    Kazimoto, Emmanuel Owden; Ikingura, Justinian R.


    Modern and ancient active continental margins are well known for their potential for hosting important gold deposits. The Neoarchean Musoma-Mara Greenstone Belt of the Tanzania Craton is also known for hosting several important gold deposits. Previous geochemical studies of the belt demonstrated that the rocks formed along Neoarchean convergent margins. The host rocks of the three important deposits in this belt had not yet been geochemically investigated. Therefore, we studied the host rocks of the Gokona, Nyabigena and Nyabirama gold deposits in the Neoarchean Musoma-Mara Greenstone Belt of the Tanzania Craton to determine the tectonic setting of their formation and constrain their petrogenesis. The host rocks of the Gokona and Nyabigena deposits are classified as high-K andesite, whereas the host rocks of the Nyabirama deposit are classified primarily as trondhjemite and granite and minor granodiorite (TGG). The high-K andesite and TGG were formed in an active continental margin similar to that of other Neoarchean volcanic rocks found in the Musoma-Mara Greenstone Belt. The host rocks contain low Ni and Cr concentrations and are characterised by negative Eu anomalies (Eu/Eu* = 0.67-0.72 and 0.17-0.6). The chondrite-normalised rare earth element (REE) patterns of the rocks display strong enrichment in light REEs over heavy REEs (high-K andesite (La/Yb)N = 21.7-35.6, and TGG (La/Yb)N = 2.4-94.4). Moreover, the primitive normalised diagrams show enrichment in large-ion lithophile elements (Ba, Rb, Th and K), negative Nb and Ta anomalies and depletion in heavy rare earth elements and high field-strength elements (Y and Ti). The high-K andesite has a Nb/Ta value close to that of depleted mantle (mean = 15.0), lower Zr/Sm values (19.4-30.6) and higher concentrations of REEs, large ion lithophile elements, Sr (607 ppm) and Y than in the TGG. The TGG has a low mean Nb/Ta value (13.2) and Sr concentration (283 ppm) and a lower amount of HREEs and higher values of Zr

  12. On progress and rate of the peritectic reaction Fo + SiO2 → En in natural andesitic arc magmas (United States)

    Zellmer, Georg F.; Sakamoto, Naoya; Matsuda, Nozomi; Iizuka, Yoshiyuki; Moebis, Anja; Yurimoto, Hisayoshi


    Using a high resolution ion microprobe with SCAPS imaging, the peritectic reaction of forsterite + silica to enstatite was studied down to submicron level in a natural andesitic tephra from the Central Plateau of North Island, New Zealand. The fayalitic component of natural olivines is stable in high-silica melts, and therefore the reaction is in fact a two-step progress: 1. Dissolution of Mg-rich olivine, rate-limited by Fe-Mg interdiffusion at the crystal rim, results in enrichment of Fe in the crystal rim and of Mg in the c. 1 μm wide melt boundary layer around the crystal. 2. Magnesian pyroxenes preferentially but not exclusively nucleate in the melt boundary layer and grow; as soon as these microlites touch the rim of the dissolving olivine, they shield the crystals from the silica-rich melt, thereby preventing further olivine dissolution. At this point, Fe-Mg interdiffusion begins to destroy the Fe-enrichment of the olivine rim. The reaction is completed when the dissolving olivine crystal is completely mantled by magnesian pyroxene microlites. Thick pyroxene mantles are likely the result of pyroxene overgrowth rather than due to peritectic transformation. The morphology of the olivine rim preserves information about the reaction history of the grain. Modeling of Fe-Mg interdiffusion in the olivine rim following its shielding from the melt by pyroxene overgrowth may yield the rates of olivine dissolution and the rates of pyroxene growth if temperature is known. For the tephra we have studied, microlite thermometry yields a temperature of 1137 (±41) °C, indicating an olivine dissolution rate of 3-6 × 10-11 ms-1 and an initially volumetric pyroxene growth rate of 2.2-5.6 × 10-21 m3 s-1. This points to timescales between olivine crystal uptake into the SiO2-rich melt and explosive eruption at the surface of a few hours to at most a day.

  13. The influence of critical zone processes on the Mg isotope budget in a tropical, highly weathered andesitic catchment (United States)

    Chapela Lara, María; Buss, Heather L.; Pogge von Strandmann, Philip A. E.; Schuessler, Jan A.; Moore, Oliver W.


    In order to assess the effects of critical zone processes on Mg concentrations and isotopic signatures of tropical streams, we studied a well constrained, highly weathered andesitic volcaniclastic catchment in the Luquillo Critical Zone Observatory, Puerto Rico. Our results indicate that dissolved Mg concentrations and isotope ratios in the regolith pore water are mainly controlled by rain input, with weathering inputs being more important at sites with thinner regolith (2.7-0.9 m deep) and at depth (>8 m) on a thick ridgetop regolith (∼10 m). In addition to mixing of precipitation and weathering-sourced Mg, an isotopic fractionation process is taking place between dissolved Mg and the regolith, likely during dissolution or recrystallisation of Fe(III)-(hydro)oxides under alternating redox conditions. Bulk regolith is isotopically heavier than both the bedrock and the exchangeable fraction (δ26Mgregolith-bedrock = +0.03 to +0.47‰), consistent with the preferential incorporation of heavy 26Mg into secondary minerals with some exchange of sorbed Mg with isotopically lighter pore water. Magnesium concentrations in the stream show a typical dilution behaviour during a storm event, but the [Mg] - δ26Mg pattern cannot be explained by mixing of rain and pore water; the data are best explained by a steady-state fractionation model with α = 1.00115. During baseflow the stream has δ26Mg = +0.01‰, higher than any of the water samples or the bedrock. In-situ analysis of the Mg isotopic composition of bedrock minerals points at the dissolution of Mg-rich chlorite (δ26Mg = +0.19‰) as the most likely source of this isotopically heavy Mg, with mass balance calculations indicating chlorite dissolution is also the main source of Mg to the stream. Overall, our study highlights the importance of atmospheric input of nutrients to the vegetation in tropical areas covered by thick, highly leached regolith, whereas the Mg flux and Mg isotopic signature of watershed exports

  14. Melt inclusions are not reliable proxies for magmatic liquid composition: evidence from crystal-poor andesites and dacites in the Tequila volcanic field, Mexico (United States)

    Frey, H. M.; Lange, R. A.


    A compositional study of >200 melt inclusions in plagioclase and orthopyroxene phenocrysts from six crystal-poor (2-5 vol%) andesite and dacite lavas (60-68 wt% SiO2) from the Tequila volcanic field in the Mexico arc is used to evaluate whether melt inclusions in phenocrysts accurately record magmatic liquid compositions. The crystal-poor andesites and dacites were erupted contemporaneously with crystal-poor rhyolites, and there is a continuum in the SiO2 concentration of the erupted magmas. The liquid line of descent defined by the whole-rock compositions ranges from andesite to rhyolite (60-77 wt% SiO2), as illustrated on Harker diagrams. The crystal-poor andesites and dacites are multiply saturated with five to seven mineral phases (plagioclase + orthopyroxene + titanomagnetite + ilmenite + apatite ± augite ± hornblende), most of which crystallized via degassing during magma ascent (Frey and Lange, 2009). By comparison with phase equilibrium experiments from the literature, it is shown that the vast majority of crystals are phenocrysts and not xenocrysts. Textural evidence of rapid crystal growth includes skeletal, hopper, and swallow-tail morphologies and abundant melt inclusions. The inclusions range in size from a few microns to > 50 μm and occur as isolated pockets and extensive channels that mimic the crystal morphology. Inclusions are typically brown glass, with occasional microphenocrysts of titanomagnetite and/or apatite within or adjacent to the melt inclusions. The compositions of the melt inclusions in the plagioclase and orthopyroxene phenocrysts, when plotted on Harker diagrams, vary systematically from one another and from the liquid line of descent defined by the whole rock compositions of erupted magmas. For example, melt inclusions in plagioclase are systematically depleted in Al2O3 relative to the whole rock samples, whereas those in coexisting orthopyroxenes are systematically enriched in Al2O3. The opposite trend is found for FeO, where it


    Langone, A.; Tiepolo, M.; Morishita, T.; Tribuzio, R.


    High-Mg andesites (HMA) are a group of arc products, usually rich in amphibole, whose origin is still debated. High-Mg diorites (HMD) are intrusive counterparts of HMA and are locally found in exhumed arc sections. In places, HMD are closely associated with ultramafic amphibole-rich rocks and may provide further constrains on the role of amphibole in the origin of HMA and in the petrogenesis of arc related-magmas. Small bodies of Cretaceous amph-rich mafic and ultramafic intrusives with similar petrographic features and HMA affinity (e.g. Kamei et al., 2004) are exhumed together with granitoid rocks along the Japan arc. These rocks, originated during the Cretaceous subduction of the Pacific plate under Asia, give the opportunity to investigate modifications in the composition of melts with HMA affinity as a function of the along-margin position and time. Mafic and ultramafic intrusives were sampled in different localities of the Honshu (NE Japan arc) and Kyushu Island (SW Japan arc). In situ U-Pb zircon geochronology by laser ablation ICPMS was carried out to constrain the time relationships among the different intrusive bodies. U-Pb concordia ages show that the HMD were mostly emplaced from ca. 100 Ma up to 118 Ma. In only one case (Honshu Island) U-Pb concordia ages as young as 70 Ma were obtained. High modal proportions of amphibole (40-60 vol%) with pargasite cores (mg# = 0.66-0.77) characterize all studied samples. In ultramafic rocks (Ol-hornblendites and Cpx-hornblendites), pargasitic amphibole is poikilitic on sub-rounded clinopyroxene (mg# up to 88) and olivine (Fo61-78). In mafic rocks (amph-gabbros and amph-diorites), large amphibole grains are dispersed in a fine-grained matrix defining a porphyritic texture. The matrix consists mainly of Mg-hornblende, plagioclase and clinopyroxene. The cores of pargasitic amphibole from mafic rocks have clinopyroxene inclusions with mg# up to 88, similar to what found in ultramafic rocks. Independently from the age

  16. Microgranular enclaves in island-arc andesites: A possible link between known epithermal Au and potential porphyry Cu-Au deposits in the Tulasu ore cluster, western Tianshan, Xinjiang, China (United States)

    Zhao, Xiaobo; Xue, Chunji; Symons, David T. A.; Zhang, Zhaochong; Wang, Honggang


    The successful exploration for porphyry copper deposit in western Tianshan, Xinjiang, faces great challenge. Tulasu basin is an important epithermal gold ore cluster in western Tianshan, which was formed in a southwest-Pacific-type island-arc setting during the late Paleozoic by the southward subduction of the North Tianshan ocean beneath the Yili plate. Porphyry Cu-Au deposits are possibly to be found at depth or adjacent to these epithermal gold deposits. Some sulfide-mineralized microgranular enclaves of monzonite porphyry and microdiorite were found in andesites of the Tawuerbieke gold district, Tulasu basin. The enclaves are randomly distributed, with generally round or subangular shape and commonly clearly defined within their host andesite, and have a chilled surrounding margin of andesite. The monzonite porphyry enclaves (MPE) exhibit porphyritic texture with the phenocrysts of plagioclase and K-feldspar. The microdiorite enclaves (MDE) are mainly composed of plagioclase and hornblende with an aplitic texture and massive structure. The host andesites show porphyritic texture, with the phenocrysts major of plagioclase, minor of hornblende and clinopyroxene. The groundmass consists of short-column plagioclase and minor clinopyroxene with a hyalopilitic texture. Zircon grains from a MPE sample yield a weighted 206Pb/238U age of 356.2 ± 4.3 Ma (n = 13, MSWD = 1.11), which is effectively coincident with the 360.5 ± 3.4 Ma (n = 20, MSWD = 0.61) of an andesite sample within analytical error, indicating that they were coeval. In addition, the MPE, MDE and the andesite samples share similar normalized incompatible element and rare earth element patterns that are characterized by a pronounced enrichment of large ion lithophile elements and a deficit of high field strength elements. Moreover, the samples show similar Nd isotope compositions to the contemporary andesites and basaltic andesites. Detailed petrology, geochronology and geochemistry studies suggest that

  17. NanoSIMS mapping and LA-ICP-MS chemical and U-Th-Pb data in monazite from a xenolith enclosed in andesite (Central Slovakia Volcanic Field) (United States)

    Didier, A.; Bosse, V.; Bouloton, J.; Mostefaoui, S.; Viala, M.; Paquette, J. L.; Devidal, J. L.; Duhamel, R.


    In this study, we use NanoSIMS element and isotope ratio mapping and LA-ICP-MS trace element measurements to elucidate the origins of monazites from a restitic xenolith enclosed in a 13.5 ± 0.3 Ma andesitic lava (Slovakia). The xenolith/lava interaction is mainly characterized by the growth of a plagioclase-bearing corona around the xenolith and magmatic garnet overgrowths on primary metamorphic garnets within the xenolith. NanoSIMS images (89Y, 139La, 208Pb, 232Th and 238U) and trace element analyses indicate that variations of HREE, Y and Eu contents in the monazite are correlated with the resorption and the following overgrowth of garnet and plagioclase in the xenolith. Three domains are distinguished in the monazite grains: the inherited Variscan core at ca. 310 Ma (M1 domain) characterized by low Y and HREE contents and a weak negative Eu anomaly; the inner rim (M2 domain) crystallized during the growth of the plagioclase magmatic corona (large negative Eu anomaly) and the resorption of metamorphic garnet (high HREE and Y contents); and the external rim (M3 domain) crystallized during the growth of the plagioclase corona (large negative Eu anomaly) and during the crystallization of magmatic garnet (low Y, HREE contents) at ~13 Ma, i.e. the age of the andesitic lava. The age and chemical zonation of the monazites attest to the preservation of primary monazite in the xenolith despite the interaction with the andesite lava. NanoSIMS imaging provides high-quality sub-µm scale images of the monazite that reveals chemical domains that were not distinguishable on WDS X-ray maps, especially for depleted elements such as U and Pb. Owing to its small size, the M2 domain could not be accurately dated by the LA-ICP-MS method. However, NanoSIMS isotopic maps reveal that the M2 domain has similar 208Pb/232Th isotope ratios to the M3 domain and thus similar ages. These results support the hypothesis that melt-assisted partial dissolution-precipitation in monazite

  18. Experimental constraints on the P/T conditions of high silica andesite storage preceding the 2006 eruption of Augustine Volcano, Alaska (United States)

    Henton, S.; Larsen, J. F.; Traxler, N.


    We present new experimental results to constrain the P/T storage conditions of the high silica andesite (HSA) prior to the 2006 eruption of Augustine Volcano, Alaska. Augustine Volcano forms a small island located in Alaska’s Cook Inlet, approximately 180 miles southwest of Anchorage. The 2006 eruption began January 11, 2006, and evolved from an initial phase of explosive activity, through continuous and effusive phases, ending approximately mid-March 2006. Lithologies erupted indicate pervasive hybridization between high- (HSA; 62.2-63.3 wt. % SiO2) and low-silica andesite (LSA; 56.6-58.7 wt% SiO2). This study focuses on experiments using the HSA as starting material to constrain magma storage conditions, based on amphibole stability. Experiments were conducted between 100-160 MPa and 800-900 °C, utilzing H2O saturated conditions and fO2 of Re-ReO. Both lightly crushed and sintered HSA were used as starting powders, seeded respectively with 5 wt. % amphibole and a mix of 5 wt. % amphibole and 20 wt. % plagioclase. Experiments with sintered starting material tended toward a bimodal distribution of experimental phenocrysts and microlites, whilst experiments of the lightly crushed material are more phenocryst rich. Preliminary results indicate that amphibole is stable at conditions of 120-140 MPa and 820-840 °C. These pressures correspond with depths of approximately 4.6-5.4 km, which are consistent with prior magma storage models for Augustine 1986 and 2006 magmas, as well as amphiboles found in other arc andesites (e.g., Redoubt and Soufriere Hills volcanoes). Experimental amphiboles are magnesio-hornblendes, which is in keeping with the natural HSA amphiboles. Experimental and natural hornblendes are similar in composition, with the main difference being a small FeO enrichment (2-3 wt%) and MgO depletion (1-2wt%) in the experimental grains. Further work will provide a more complete assessment of amphibole stability and composition, and will be applied towards

  19. Geochemistry of high-Mg andesites from the early Cretaceous Yixian Formation, western Liaoning: Implications for lower crustal delamination and Sr/Y variations

    Institute of Scientific and Technical Information of China (English)

    WANG; Xiaorui; GAO; Shan; LIU; Xiaoming; YUAN; Honglin; HU; Zhaochu; ZHANG; Hong; WANG; Xuance


    85 volcanic rocks of the Yixian Formation from the Sihetun type section were collected and analyzed for geochemical and isotopic compositions. Major element compositions indicate that the Sihetun volcanic rocks are high magnesium andesites with some basalts occurring at the bottom of section. The Sihetun high magnesium andesites (SiO2 = 52.82-59.31wt%, Al2O3 = 14.15-16.35wt%)show many characteristics of adakites such as depletion in heavy rare-earth elements (HREE; Yb =1.03-1.88 μg/g) and Y(12-20 μg/g) and high Sr (620-1323 μg/g) and Sr/Y(32-88), with high LaN/YbN ratio (10-25). They share similar major and trace element characteristics to volcanic rocks from the Xinglonggou Formation except their lower Nd isotope ratios (143Nd/144Nd (130Ma) =0.5118-0.5119, εNd (130Ma) = -11.6--13.8, 87Sr/86Sr (130 Ma) = 0.7058-0.7064. They were interpreted in a way that eclogite that formed at the base of thickened Archean lower crust of the North China craton foundered into the convecting mantle and subsequently melted and interacted with peridotite. However, compared to the Xinglonggou volcanic rocks, the source of the Sihetun magma contained more ancient continental crustal material in order to explain its evolved Nd isotopes. The age of the Sihetun Formation was 120 to 130 Ma, and this indicates that delamination lasted to the early Cretaceous period. The Sr contents and Sr/Y ratios of the Sihetun high-Mg andesites show significant negative correlations with SiO2 for samples with SiO2 > 56%. These suggest that the Sr and Sr/Y values were reduced due to fractional crystallization of plagioclase. Accordingly, the effect of crystallization on volcanic Sr and Sr/Y ratio has to be taken into account.

  20. First U-Pb isotopic data on zircon from andesite of the Saf'yanovka Cu-bearing massive sulfide deposit (Middle Urals) (United States)

    Ronkin, Yu. L.; Pritchin, M. E.; Soroka, E. I.; Gerdes, A.; Puchkov, V. N.; Busharina, S. V.


    New results of U-Pb LA ICP-MS dating of zircon from andesite samples cropping out on the western wall of the Saf'yanovka quarry (57°22'58.88″ N, 61°31'50.85″ E) in the synonymous Cu-Zn-bearing massive sulfide deposit of the Urals type are considered. The position of data points of the U-Pb systematics in the 207Pb/235U-206Pb/238U plot determines a cluster practically corresponding to the concordant U-Pb age: 422.8 ± 2.0 Ma. This date indicates for the first time the presence of Pridolian volcanogenic rocks in the East Urals megazone of the Middle Urals.

  1. Manganese mineralization in andesites of Brestovačka Banja, Serbia: evidence of sea-floor exhalations in the Timok Magmatic Complex (United States)

    Pačevski, Aleksandar; Cvetković, Vladica; Šarić, Kristina; Banješević, Miodrag; Hoefer, Heidi Eva; Kremenović, Aleksandar


    Andesites near Brestovačka Banja belong to the Late Cretaceous Timok Magmatic Complex (TMC), which hosts the world-class Bor metallogenic zone including numerous porphyry-copper and epithermal deposits. Two main volcanic phases are recognized in the TMC. The newly discovered Mn mineralization reported here is associated with the second volcanic phase of Turonian-Campanian age. Manganese mineralization containing 58 % MnO on average, occurs as black veins, lumps and nests filling cracks and cavities within an autoclastic andesite, which was deposited in a subaqueous environment. This rock also contains minor Fe mineralization, which is contemporaneous with the manganese mineralization. Manganese mineralization predominantly consists of Mn-Ca silicates (macfallite, pumpellyite-Mn, orientite, bustamite) and Mn oxides (pyrolusite, manganite). Micrometer-scale mineral intergrowths and locally preserved botryoidal and colloform textures are characteristic features of this uncommon mineral assemblage. The features could indicate that the mineralization was formed by deposition from a primary colloidal assemblage and is of sub-marine hydrothermal origin. Orientite is the only Mn mineral with grain size reaching several tenths of micrometers and showing prismatic crystal habit. Scarce to rare associated minerals are hollandite, crednerite, an unknown REE mineral, powellite, pyrite, barite and galena, in decreasing abundance. Trace element analyses of the Mn mineralization show different element contents and REE patterns compared to those of the volcanic host-rock. Manganese mineralization shows relatively high contents of Cu - 1784 ppm, Mo - 20 ppm and As - 268 ppm. These elements are commonly enriched in the Cu deposits of the Bor zone and their relatively high contents in the studied Mn crusts indicate sea-floor hydrothermal vents as a source of the metals.

  2. Mixing and mingling in the evolution of andesite dacite magmas; evidence from co-magmatic plutonic enclaves, Taupo Volcanic Zone, New Zealand (United States)

    Cole, J. W.; Gamble, J. A.; Burt, R. M.; Carroll, L. D.; Shelley, D.


    The southeastern side of the Taupo Volcanic Zone, New Zealand is marked by a line of andesite/dacite/low-silica rhyolite complexes. Co-magmatic plutonic enclaves occur within the lavas of the four youngest complexes: White Island, Motuhora (Whale Island), Edgecumbe and Tauhara. The enclaves range from coarse-grained gabbros, diorites, granodiorites and a syenite to finer-grained dolerites and microdiorites. The more mafic types are generally porphyritic with large phenocrysts of plagioclase, usually with extensive sieve textures in the cores and corroded margins. Most of these enclaves, including the coarser-grained plutonic examples, contain glass and many are miarolitic. Diorites and microdiorites/dolerites predominate at White Island, Motuhora and Edgecumbe; many are porphyritic. Enclaves at Tauhara are more variable; those collected from Hipaua Dome include a range from microdiorites to quartz microdiorites and those from Rubbish Tip Dome include microdiorites, a granodiorite, and a syenite. Most enclaves show textural evidence for disequilibrium with multiple populations of plagioclase and pyroxene. They also show considerable textural variation, even within a thin section, with coarse-grained gabbros/diorites intimately mixed with finer-grained dolerites/microdiorites. Geochemically and isotopically, most enclaves have a similar composition with their host lavas, although some have lower silica contents. Enclaves at Motuhora and Tauhara are isotopically more variable, indicating multiple sources and a more complex petrogenesis. Most diorite/microdiorite enclaves are interpreted to represent parts of a crystal mush formed during fractionation of andesite/dacite magma, and entrained during later rise of magma to the surface. The granodiorite from Rubbish Tip Dome, Tauhara, probably represents part of a silicic magma chamber within the crust that fed the host low-silica rhyolite lava dome. Variability within the enclaves indicates the complexity likely to occur

  3. Chemical and isotopic fractionation of wet andesite in a temperature gradient: Experiments and models suggesting a new mechanism of magma differentiation (United States)

    Huang, F.; Lundstrom, C. C.; Glessner, J.; Ianno, A.; Boudreau, A.; Li, J.; Ferré, E. C.; Marshak, S.; DeFrates, J.


    Piston-cylinder experiments were conducted to investigate the behavior of partially molten wet andesite held within an imposed temperature gradient at 0.5 GPa. In one experiment, homogenous andesite powder (USGS rock standard AGV-1) with 4 wt.% H 2O was sealed in a double capsule assembly for 66 days. The temperature at one end of this charge was held at 950 °C, and the temperature at the other end was kept at 350 °C. During the experiment, thermal migration (i.e., diffusion in a thermal gradient) took place, and the andesite underwent compositional and mineralogical differentiation. The run product can be broadly divided into three portions: (1) the top third, at the hot end, contained 100% melt; (2) the middle-third contained crystalline phases plus progressively less melt; and (3) the bottom third, at the cold end, consisted of a fine-grained, almost entirely crystalline solid of granitic composition. Bulk major- and trace-element compositions change down temperature gradient, reflecting the systematic change in modal mineralogy. These changes mimic differentiation trends produced by fractional crystallization. The change in composition throughout the run product indicates that a fully connected hydrous silicate melt existed throughout the charge, even in the crystalline, cold bottom region. Electron Backscatter Diffraction analysis of the run product indicates that no preferred crystallographic orientation of minerals developed in the run product. However, a significant anisotropy of magnetic susceptibility was observed, suggesting that new crystals of magnetite were elongated in the direction of the thermal gradient. Further, petrographic observation reveals alignment of hornblende parallel to the thermal gradient. Finally, the upper half of the run product shows large systematic variations in Fe-Mg isotopic composition reflecting thermal diffusion, with the hot end systematically enriched in light isotopes. The overall δ 56Fe IRMM-14 and δ 26Mg DSM-3

  4. Revisiting the compositions and volatile contents of olivine-hosted melt inclusions from the Mount Shasta region: implications for the formation of high-Mg andesites (United States)

    Ruscitto, D. M.; Wallace, P. J.; Kent, A. J. R.


    Primitive chemical characteristics of high-Mg andesites (HMA) suggest equilibration with mantle wedge peridotite, and they may form through either shallow, wet partial melting of the mantle or re-equilibration of slab melts migrating through the wedge. We have re-examined a well-studied example of HMA from near Mt. Shasta, CA, because petrographic evidence for magma mixing has stimulated a recent debate over whether HMA magmas have a mantle origin. We examined naturally quenched, glassy, olivine-hosted (Fo87-94) melt inclusions from this locality and analyzed the samples by FTIR, LA-ICPMS, and electron probe. Compositions (uncorrected for post-entrapment modification) are highly variable and can be divided into high-CaO (>10 wt%) melts only found in Fo > 91 olivines and low-CaO ( 90 olivines. Restored low-CaO melt inclusions are HMAs (57-61 wt% SiO2; 4.9-10.9 wt% MgO), whereas high-CaO inclusions are primitive basaltic andesites (PBA) (51-56 wt% SiO2; 9.8-15.1 wt% MgO). HMA and PBA inclusions have distinct trace element characteristics. Importantly, both types of inclusions are volatile-rich, with maximum values in HMA and PBA melt inclusions of 3.5 and 5.6 wt% H2O, 830 and 2,900 ppm S, 1,590 and 2,580 ppm Cl, and 500 and 820 ppm CO2, respectively. PBA melts are comparable to experimental hydrous melts in equilibrium with harzburgite. Two-component mixing between PBA and dacitic magma (59:41) is able to produce a primitive HMA composition, but the predicted mixture shows some small but significant major and trace element discrepancies from published whole-rock analyses from the Shasta locality. An alternative model that involves incorporation of xenocrysts (high-Mg olivine from PBA and pyroxenes from dacite) into a primary (mantle-derived) HMA magma can explain the phenocryst and melt inclusion compositions but is difficult to evaluate quantitatively because of the complex crystal populations. Our results suggest that a spectrum of mantle-derived melts, including

  5. Effect of Bulk Water Concentration on Mantle Wedge Hybridization by Rhyolitic Sediment Melt - Implications for Generation of K-rich Basalts to Andesites in Subduction Zones (United States)

    Mallik, A.; Dasgupta, R.; Nelson, J. M.; Tsuno, K.


    Similarities in trace element geochemistry between ocean-floor sediments and arc lavas suggest the involvement of subducted sediments in the mantle source of arc volcanoes. Siliciclastic sediments produce rhyo-dacitic, hydrous partial melts at sub-arc depths, which must react with wedge peridotite during their ascent. In addition to fluids, these sediment melts can be a major carrier of water to the arc source. Here we investigate the effects of bulk water concentration on the phase equilibria of reaction between sediment partial melt and peridotite. Piston-cylinder experiments were performed using Au-Pd capsules, at 2 and 3 GPa, 1050 - 1350 °C with mixtures of 25% rhyolite + 75% lherzolite, bearing bulk water content of 2 (low-water) and 4 wt.% (high-water). Melting degree is higher in high-water experiments at both 2 and 3 GPa with a sharp increase in melt mode from 31 to 53 wt.% at 1250-1300 °C, 2 GPa and 21 to 49 wt.% at 1225-1250 °C, 3 GPa. This sharp increase in melt mode is accompanied by a corresponding abrupt increase in residual olivine to opx ratio at both pressures (0.11 to 0.53 at 1250-1300 °C, 2 GPa and 0 to 0.71 at 1225-1250 °C, 3 GPa). The stability field of phlogopite, clinopyroxene, and garnet are reduced in high-water experiments due to higher degrees of partial melting. Low-water experiments produce basalts with SiO2, on a volatile-free basis, increasing from 49 to 51 wt.% at 2 GPa and 46 to 48 wt.% at 3 GPa. For high-water experiments, melt SiO2 contents at 2 GPa are slightly higher than those in low-water experiments for a given temperature, varying from 51 to 52 wt.%, and, at 3 GPa, the melts trend towards andesitic compositions with SiO2 ~54 wt.%. These compositional characteristics of the melts can be attributed to the effect of increased olivine to opx ratios in the residue as a function of increasing bulk water concentration. Our study shows that a spectrum of ultra-potassic, high-Mg arc lavas (MgO varying from 10-16 wt.%) from

  6. Using mineral geochemistry to decipher slab, mantle, and crustal inputs to the generation of high-Mg andesites from Mount Baker and Glacier Peak, northern Cascade arc (United States)

    Sas, M.; DeBari, S. M.; Clynne, M. A.; Rusk, B. G.


    A fundamental question in geology is whether subducting plates get hot enough to generate melt that contributes to magmatic output in volcanic arcs. Because the subducting plate beneath the Cascade arc is relatively young and hot, slab melt generation is considered possible. To better understand the role of slab melt in north Cascades magmas, this study focused on petrogenesis of high-Mg andesites (HMA) and basaltic andesites (HMBA) from Mt. Baker and Glacier Peak, Washington. HMA have unusually high Mg# relative to their SiO2 contents, as well as elevated La/Yb and Dy/Yb ratios that are interpreted to result from separation of melt from a garnet-bearing residuum. Debate centers on the garnet's origin as it could be present in mineral assemblages from the subducting slab, deep mantle, thick lower crust, or basalt fractionated at high pressure. Whole rock analyses were combined with major, minor, and trace element analyses to understand the origin of these HMA. In the Tarn Plateau (Mt. Baker) flow unit (51.8-54.0 wt.% SiO2, Mg# 68-70) Mg#s correlate positively with high La/Yb in clinopyroxene equilibrium liquids, suggesting an origin similar to that of Aleutian adakites, where slab-derived melts interact with the overlying mantle to become Mg-rich and subsequently mix with mantle-derived basalts. The source for high La/Yb in the Glacier Creek (Mt. Baker) flow unit (58.3-58.7 wt.% SiO2, Mg# 63-64) is more ambiguous. High whole rock Sr/P imply origin from a mantle that was hydrated by an enriched slab component (fluid ± melt). In the Lightning Creek (Glacier Peak) flow unit (54.8-57.9 SiO2, Mg# 69-72) Cr and Mg contents in Cr-spinel and olivine pairs suggest a depleted mantle source, and high whole rock Sr/P indicate hydration-induced mantle melting. Hence Lightning Creek is interpreted have originated from a refractory mantle source that interacted with a hydrous slab component (fluid ± melt). Our results indicate that in addition to slab-derived fluids, slab

  7. Repeated magmatism at 34 Ma and 23-20 Ma producing high magnesian adakitic andesites and transitional basalts on southern Okushiri Island, NE Japan arc (United States)

    Sato, Makoto; Shuto, Kenji; Nohara-Imanaka, Rikako; Takazawa, Eiichi; Osanai, Yasuhito; Nakano, Nobuhiko


    The southern part of Okushiri Island in the present-day back-arc margin of the NE Japan arc is one of the rare convergent plate boundaries where similar magma types (high-magnesian adakitic andesite (HMAA) and high-TiO2 basalt (HTB)) have been erupted concurrently at more than one time. Oligocene HMAA can be divided into two types: HMAA-I is characterized by high Sr/Y and low Y, and HMAA-II by relatively low Sr/Y and high Y. HMAA-I is primitive in terms of MgO (8.5 wt.%), Mg# (67), Ni (232 ppm) and Cr (613 ppm) contents, and the most Mg-rich olivine phenocrysts plot within the mantle olivine array in terms of Fo and NiO. The similar Cr versus Ni relations of types I and II HMAA indicate some interaction of slab-derived adakitic melts with mantle peridotite, whereas Ni contents are higher than those of most boninites derived by partial melting of mantle peridotite at a given Cr content. Types I and II HMAA have more enriched Sr and Nd isotopic compositions than N-MORB. The petrography and geochemistry of these rocks, combined with published results on the genesis of high-magnesian andesite (HMA) indicate that types I and II HMAA could be produced by interaction of slab (N-MORB and sediment)-derived adakitic melts with mantle peridotite. The comagmatism of HMAA and HTB is ascribed to the following model. A cool, less hydrous, adakite magma (spherical diapir) would rise from the subducting slab (Pacific Plate) and become more hydrous as a result of its interaction with overlying hydrous peridotite. This hydrated adakitic diapir further ascends and is heated on entering the overlying mantle wedge. Subsequently, the temperature and H2O gradients in the ascending adakitic diapir and surrounding mantle peridotite would have been established. The HTB magma segregated from the surrounding mantle peridotite region (high temperature and low H2O content) at a depth of 60 km or more, whereas the adakitic diapir (low temperature and high H2O content) continued to rise, with its

  8. Intermediate composition magma production in an intracontinental setting: Unusual andesites and dacites of the mid-Miocene Santa Rosa-Calico volcanic field, Northern Nevada (United States)

    Brueseke, Matthew E.; Hart, William K.


    The mid-Miocene Santa Rosa-Calico volcanic field (SC) of northern Nevada provides an outstanding example of the role open-system magmatic processes play in producing calc-alkaline and tholeiitic andesite-dacite magmas in an intracontinental setting. SC volcanism commenced at ˜ 16.7 Ma and is associated with the initial manifestations of the Yellowstone hotspot, the Columbia River-Steens flood basalt event(s), and the formation of the Northern Nevada rift. Locally a diverse package of magmatic products ranging from tholeiitic basalt to high-Si rhyolite was produced during an ˜ 2 myr duration. Within this package are the products of at least four distinct intermediate composition magmatic systems that may represent as much as 40% of the SC volcanic pile. These help differentiate the SC from contemporaneous Oregon Plateau volcanic fields (e.g. McDermitt, Lake Owyhee, Northwest Nevada) that are dominated by bimodal basalt-rhyolite assemblages. All SC intermediate units are characterized by textural and mineralogic complexities including xenoliths and xenocrysts of local crust and crystal clots of plagioclase ± clinopyroxene ± orthopyroxene ± oxide. SC intermediate units are dominantly tholeiitic, but include lava flows with transitional to calc-alkaline affinities. Relative to locally erupted Steens Basalt, SC intermediate lava flows have similar elemental enrichments and depletions, but dissimilar Sr and Nd isotopic compositions. These isotopic differences, coupled with the abundant disequilibrium features and variable incompatible element ratios, indicate that open system magmatic processes played a major role in the genesis of the intermediate units. SC silicic magmas were produced primarily via upper crustal melting of chemically and isotopically heterogeneous Cretaceous granitoid. Interaction between fractionating mafic Steens flood basalt magmas and the more evolved crustal melts ± assimilation of local upper crust provides a general template for the

  9. Genesis of andesitic boninitic magmas at mid-ocean ridges by melting of hydrated peridotites: Geochemical evidence from DSDP Site 334 gabbronorites (United States)

    Nonnotte, Philippe; Ceuleneer, Georges; Benoit, Mathieu


    account for part of the variability in the Sr isotopic signature of oceanic basalts, among other to the short wavelength isotopic "noise" superimposed on regional trends. We conclude that seawater introduction into residual peridotite at shallow depth beneath mid-ocean ridges can lead mantle rocks and their melts to follow complex P-T-f H2O paths that mimic petrogenetic contexts classically attributed to subduction zone environments, like the production of boninitic-andesitic magmas.

  10. High-K andesite petrogenesis and crustal evolution: Evidence from mafic and ultramafic xenoliths, Egmont Volcano (Mt. Taranaki) and comparisons with Ruapehu Volcano, North Island, New Zealand (United States)

    Price, Richard C.; Smith, Ian E. M.; Stewart, Robert B.; Gamble, John A.; Gruender, Kerstin; Maas, Roland


    This study uses the geochemistry and petrology of xenoliths to constrain the evolutionary pathways of host magmas at two adjacent andesitic volcanoes in New Zealand's North Island. Egmont (Mt. Taranaki) is located on the west coast of the North Island and Ruapehu lies 140 km to the east at the southern end of the Taupo Volcanic Zone, the principal locus of subduction-related magmatism in New Zealand. Xenoliths are common in the eruptives of both volcanoes but the xenoliths suites are petrographically and geochemically different. Ruapehu xenoliths are predominantly pyroxene-plagioclase granulites derived from Mesozoic meta-greywacke basement and the underlying oceanic crust. The xenolith population of Egmont Volcano is more complex. It includes sedimentary, metamorphic and plutonic rocks from the underlying basement but is dominated by coarse grained, mafic and ultramafic igneous rocks. Gabbroic xenoliths (Group 1) are composed of plagioclase, clinopyroxene and amphibole whereas ultramafic xenoliths are dominated by amphibole (Group 2) or pyroxene (Group 3) or, in very rare cases, olivine (Group 4). In Group 1 xenoliths plagioclase and clinopyroxene and in some cases amphibole show cumulate textures. Amphibole also occurs as intercumulate poikilitic crystals or as blebs or laminae replacing pyroxene. Some Group 2 xenoliths have cumulate textures but near monomineralic amphibole xenoliths are coarse grained with bladed or comb textures. Pyroxene in Group 3 xenoliths has a polygonal granoblastic texture that is commonly overprinted by veining and amphibole replacement. Group 1 and most Group 2 xenoliths have major, trace element and Sr, Nd and Pb isotope compositions indicating affinity with the host volcanic rocks. Geochemical variation can be modelled by assimilation fractional crystallisation (AFC) and fractional crystallisation (FC) of basaltic parents assuming an assimilant with the composition of average crystalline basement and Group 1 xenoliths have

  11. 大兴安岭敖包查干地区安山岩年代学、地球化学研究%Age and Geochemistry of Andesites in the Qagan Obo Area, Da Hinggan Mountains

    Institute of Scientific and Technical Information of China (English)

    程银行; 杨俊泉; 刘永顺; 滕学建; 李艳锋; 彭丽娜; 李影; 刘洋


    在大兴安岭敖包查干地区首次识别出中三叠世安山质岩石,主要岩性为玄武质安山岩、粗面安山岩,应用锆石U—DbLA—ICPM—AS法定年,结果表明安山岩形成于234.8±3.2Ma~231.4±1.2Ma,属中三叠世。地球化学特征显示,研究区安山岩具高SiO2(54.19%~62.30%)、A12O3(15.78%~17.30%)、K20(1.77%~3.92%)、Na2O(2.95%~5.66%)、Na2O+K20(5.4~8.99)的特征和低MgO(1.23%~3.66%,Mg^#=27.89~50.48)含量,并与SiO2含量呈负相关关系。岩石富Na20(Na2O/K2O=1.01~2.86),铝指数A/CNK=0.81~1.21,属准铝质一弱过铝质钙碱性系列岩石。富集大离子亲石元素(LILE)K、Rb、Th和轻稀土元素,亏损高场强元素(HFSE)№、Ta、P、Ti,轻重稀土元素分馏明显[(LaMb)N=3.31~10.33].无Eu异常(δEu=0.80~1.03),显示弧火山岩的特征,但所研究样品的Zr、Hf呈弱正异常、Rb弱负异常却不同于正常岛弧安山岩,Zr/Y—Zr图解以及高钾特征显示出板内伸展构造环境的特征。综合研究表明敖包查干地区中三叠世钙碱性安山岩可能为古亚洲洋残余俯冲洋壳部分熔融的产物,与底侵作用有关,形成于大陆内部伸展构造环境。%Middle Triassic andesite rocks, which composed of basaltic andesite and trachyandesite, are fristly identified in Qagan Obo, Da Hinggan Mountains. The LA-MC-ICP-MS zircon U-Pb dating show that the crystal- lization ages of the andesites between 234.8±3.2Ma and 231.4±1.2Ma, which belong to Middle Triassic. Geo- chemical researches indicate that the andesites is high in silica (SiO2 = 54.19% - 62.3%), A1203(15.78%-17.30%), K20(1.77%-3.92%), alkali (K20 + Na20 = 9.59% - 9.90%) and low in MgO(1.23%-3.66%, Mg^#=27.89-50.48). Andesites is rich in Na20(Na20/K20=1.01-2.86), which is a typical high-K calc-alkaline series with the character

  12. CO2 content of andesitic melts at graphite-saturated upper mantle conditions with implications for redox state of oceanic basalt source regions and remobilization of reduced carbon from subducted eclogite (United States)

    Eguchi, James; Dasgupta, Rajdeep


    We have performed experiments to determine the effects of pressure, temperature and oxygen fugacity on the CO2 contents in nominally anhydrous andesitic melts at graphite saturation. The andesite composition was specifically chosen to match a low-degree partial melt composition that is generated from MORB-like eclogite in the convective, oceanic upper mantle. Experiments were performed at 1-3 GPa, 1375-1550 °C, and fO2 of FMQ -3.2 to FMQ -2.3 and the resulting experimental glasses were analyzed for CO2 and H2O contents using FTIR and SIMS. Experimental results were used to develop a thermodynamic model to predict CO2 content of nominally anhydrous andesitic melts at graphite saturation. Fitting of experimental data returned thermodynamic parameters for dissolution of CO2 as molecular CO2: ln( K 0) = -21.79 ± 0.04, Δ V 0 = 32.91 ± 0.65 cm3mol-1, Δ H 0 = 107 ± 21 kJ mol-1, and dissolution of CO2 as CO3 2-: ln (K 0 ) = -21.38 ± 0.08, Δ V 0 = 30.66 ± 1.33 cm3 mol-1, Δ H 0 = 42 ± 37 kJ mol-1, where K 0 is the equilibrium constant at some reference pressure and temperature, Δ V 0 is the volume change of reaction, and Δ H 0 is the enthalpy change of reaction. The thermodynamic model was used along with trace element partition coefficients to calculate the CO2 contents and CO2/Nb ratios resulting from the mixing of a depleted MORB and the partial melt of a graphite-saturated eclogite. Comparison with natural MORB and OIB data suggests that the CO2 contents and CO2/Nb ratios of CO2-enriched oceanic basalts cannot be produced by mixing with partial melts of graphite-saturated eclogite. Instead, they must be produced by melting of a source containing carbonate. This result places a lower bound on the oxygen fugacity for the source region of these CO2-enriched basalts, and suggests that fO2 measurements made on cratonic xenoliths may not be applicable to the convecting upper mantle. CO2-depleted basalts, on the other hand, are consistent with mixing between

  13. Etude de l’activité pouzzolanique d’une roche andésitique en Algérie Study of the pozzolanic activity of an andesitic rock in Algeria

    Directory of Open Access Journals (Sweden)

    Clastres P.


    Full Text Available Ce travail s’inscrit dans le cadre de l’accord programme Tassili N° 09 MDU 773 entre le Laboratoire de Physicochimie des Matériaux, USTO-Oran et le Laboratoire des Matériaux et Durabilité des Constructions (LMDC, INSA-UPS-Toulouse, France. La présente étude est une contribution aux travaux de la recherche de nouvelles sources d’approvisionnement en ajouts et en matières premières et la valorisation des matériaux naturels locaux utilisés dans la fabrication du ciment. Cette étude porte sur l’activité pouzzolanique des roches volcaniques, elle a pour but de comparer les caractéristiques physiques et mécaniques d’un mortier témoin à ciment de type CEMI 52,5R fourni par la firme Lafarge et d’un mortier à ciment du même type avec ajout dont les taux de substitution de la roche Andésitique est de 0- 40%. Dans notre travail, nous avons utilisé des roches volcaniques appartenant à la famille des Andésites, provenant de la région de Tipaza, Nord Ouest Algérois. L’étude des caractéristiques mécaniques et de l’indice de pouzzolanicité ont montré que les ciments fabriqués sont capables de remplacer certains ciments Portland pour une éventuelle utilisation dans le domaine de construction. This work is a part of the agreement programs Tassili N° 09 MDU 773 between Laboratory of Physic-chemistry Materials, USTO-Oran and Laboratory of Materials and Durability of Constructions (LMDC, INSA-UPS-Toulouse, France. The present study is an attempt to the research of new supply sources in admixtures and raw materials and the evaluation of local natural materials used in the manufacture of cement. It deals with the pozzolanic activity of the volcanic rocks and aims to compare the physical and mechanical characteristics of a mortar control made with cement CEMI 52,5R provided by Lafarge firm and of a mortar made with the same cement incorporated by different replacement rate of andesitic rock in a range of 0 – 40

  14. Mid infrared throughput with 5 mu m aperture for H sub 2 O determination of an andesitic glass. Comparison of synchrotron radiation source at SPring-8 with conventional light sources

    CERN Document Server

    Kawamoto, T; Kagi, H; Handa, T; Yamashita, S; Ikemoto, Y; Moriwaki, T; Kimura, H


    Mid infrared throughput using 5 mu m apertures was investigate using micro-FTIR spectrometers with conventional light sources at two laboratories and the synchrotron radiation infrared (SR-IR) light source at SPring-8. With both the light sources micro-FTIR microscopy can analyze the fundamental O-H vibration in andesitic glass with 1 weight % H sub 2 O through 5 mu m apertures. Spectra obtained at SPring-8 show better relative standard deviations due to the brighter and more highly collimated nature of SR-IR compared to conventional light sources. The spectra with 100 and 1000 scans at SPring-8 have similar relative standard deviations to those with 1000 and 10200 scans, respectively, at laboratories. The successful analysis with 5 mu m apertures using both light sources shows the potential for an improvement in the spatial resolution of micro-FTIR analyses. (author)

  15. Late Permian high-Mg andesite and basalt association from northern Liaoning, North China: Insights into the final closure of the Paleo-Asian ocean and the orogen-craton boundary (United States)

    Yuan, Lingling; Zhang, Xiaohui; Xue, Fuhong; Lu, Yinghuai; Zong, Keqing


    High-Mg andesites (HMAs) and related basalts constitute a volumetrically minor, but genetically important occurrence along most convergent plate margins of various ages on Earth. The details of their petrogenesis can contain critical information for resolving essential geodynamic and crustal evolutionary issues. This zircon U-Pb dating and geochemical study documents the late Permian metamorphosed high-Mg basaltic to andesitic suite from Kaiyuan of northern Liaoning, North China. These rocks feature SiO2 contents ranging from 48.7 to 63.2 wt.%, high Mg# values of 63-75, an enrichment in large-ion lithophile elements (LILE), and depletion in high field strength elements (HFSE). They possess whole-rock initial 87Sr/86Sr ratios of 0.70417-0.70457, εNd(t) values from - 0.4 to 5.0, and εHf(t) values from 5.1 to 11, as well as zircon εHf(t) values from - 9.4 to 0.4. These features indicate that their petrogenesis most likely involved precursory metasomatism of mantle peridotites by melts from subduction-related sediments, and subsequent partial melting. With a depleted mantle source and possible tectonic link to post-subduction slab break-off, the Kaiyuan suite could present a spatial reference not only for defining the demarcation line between the North China craton (NCC) and the Central Asian Orogenic belt (CAOB) in the region, but also for tracing the final location of the cryptic suturing zone of the Paleo-Asian Ocean. Synthesizing the suite with coeval igneous episodes as well as concomitant metamorphic events along the Solonker-Xra Moron-Changchun zone leads to the characterization of the eventual closure of the Paleo-Asian Ocean within a double-sided subduction system during late Permian-Early Triassic.

  16. High-resolution solid-state NMR study of the effect of composition on network connectivity and structural disorder in multi-component glasses in the diopside and jadeite join: Implications for structure of andesitic melts (United States)

    Park, Sun Young; Lee, Sung Keun


    The structural evolution of andesitic melts with varying compositions remains one of the unsolved questions in high-temperature geochemistry and petrology. In this article, we report the structural details of model andesitic glasses [CaO-MgO-Na2O-Al2O3-SiO2 (CMNAS)] in the diopside (CaMgSi2O6) and jadeite (NaAlSi2O6) join using high-resolution, multi-nuclear, solid-state nuclear magnetic resonance (NMR). The 27Al NMR spectra of CMNAS glasses confirm that [4]Al is dominant. While a minor fraction of [5]Al is observed, its presence is only prevalent in the glasses with higher Ca-Mg content. Topological disorder in the glass network also tends to increase with Ca-Mg content as evidenced by the increase in the quadrupolar coupling constant (Cq) of [4]Al for glasses with increasing diopside contents (XDiopside). Despite the complex nature of the glasses studied here (with five oxide components), the 17O 3QMAS NMR spectra resolve diverse bridging oxygens (BOs) and non-bridging oxygens (NBOs), from which the degree of Al avoidance among framework cations (Si and Al) and preferential proximity among non-network cations (Ca2+, Mg2+, and Na+) and each oxygen site can be estimated: presence of Al-O-Al in jadeite glass implies a violation of the Al-avoidance rule in the glasses and the decrease in the fraction of NBOs with increasing XDiopside is consistent with a decrease in their viscosity. Analysis of the peak position of {Ca, Mg}-mixed NBOs, along with the absence of Na-NBO peak, and the peak shape of Si-O-Al reveals preferential partitioning of Ca2+ and Mg2 into NBOs and the proximity of Na+ to BOs. The fraction of highly coordinated Al has been linked to thermodynamic and transport properties of the melts. Considering all the experimental Al coordination environments available in the literature, together with the current experimental studies, we attempt to establish the relationship between the fractions of highly coordinated Al and composition, particularly average

  17. Post-collisional volcanism in a sinking slab setting—crustal anatectic origin of pyroxene-andesite magma, Caldear Volcanic Group, Neogene Alborán volcanic province, southeastern Spain (United States)

    Zeck, H. P.; Kristensen, A. B.; Williams, I. S.


    Caldear Volcanic Group (CVG), a stratigraphically well defined, calc-alkaline rock complex within S a de Gata in the eastern part of the Alpine Betic mountain chain, S Spain, consists of three distinct formations: Hernández pyroxene andesites, Bujo hornblende-bearing pyroxene andesites and Viuda hornblende-bearing pyroxene dacites-rhyolites. The letter rock formation may have developed through crystal fractionation of mainly plagioclase and pyroxenes, however there is no direct relation between two formations. CVG has a domainal structure with a northeastern domain where Hernández formation is overlain by Bujo formation while Viuda formation is absent, and a southwestern domain where Viuda formation forms the only fractionate after Hernández formation. Hernández parent magma is thought generated through crustal anatexis by dehydration melting of a predominantly amphibolitic source rock complex which was formed by metamorphism from c. 500 Ma volcano-sedimentary parent material. The domainal structure of CVG is explained by compositional variation within this protogenetic complex. Single crystal U-Pb ages of c. 500 Ma to 1800 Ma for inherited zircon support the presence of clastic material of Proterozoic derivation within the original volcano-sedimentary complex. Regional study of syn-collisional rock formations (Alpine nappe complexes) indicate that the collisional tectonic stage in the Betic-Rif orogenic belt took place rather early (25-30 Ma?) and was followed by a stage of rapid regional rock uplift, fast cooling (c. 500°C/my) and extensional tectonics in the period 22-17 Ma. This later tectonic stage was set into motion by slab break-off which set the stage for a high temperature regime in the overlying lithosphere, providing the framework for the crustal melting and magma production responsible for the calc-alkaline rocks of Alborán volcanic province. Miocene zircon with ages ranging from c. 17 to 11 Ma indicate a rather protracted magmatic development

  18. Paleoproterozoic arc basalt-boninite-high magnesian andesite-Nb enriched basalt association from the Malangtoli volcanic suite, Singhbhum Craton, eastern India: Geochemical record for subduction initiation to arc maturation continuum (United States)

    Rajanikanta Singh, M.; Manikyamba, C.; Ganguly, Sohini; Ray, Jyotisankar; Santosh, M.; Dhanakumar Singh, Th.; Chandan Kumar, B.


    The Singhbhum Craton of eastern India preserves distinct signatures of ultramafic-mafic-intermediate-felsic magmatism of diverse geodynamic affiliations spanning from Paleo-Mesoarchean to Proterozoic. Here we investigate the 2.25 Ga Malangtoli volcanic rocks that are predominantly clinopyroxene- and plagioclase-phyric, calc-alkaline in nature, display basalt-basaltic andesite compositions, and preserve geochemical signatures of subduction zone magmatism. Major, trace and rare earth element characteristics classify the Malangtoli volcanic rocks as arc basalts, boninites, high magnesian andesites (HMA) and Nb enriched basalts (NEB). The typical LILE enriched-HFSE depleted geochemical attributes of the arc basalts corroborate a subduction-related origin. The boninitic rocks have high Mg# (0.8), MgO (>25 wt.%), Ni and Cr contents, high Al2O3/TiO2 (>20), Zr/Hf and (La/Sm)N (>1) ratios with low (Gd/Yb)N (54 wt.%), MgO (>6 wt.%), Mg# (0.47) with elevated Cr, Co, Ni and Th contents, depleted (Nb/Th)N, (Nb/La)N, high (Th/La)N and La/Yb (<9) ratio, moderate depletion in HREE and Y with low Sr/Y. The NEBs have higher Nb contents (6.3-24 ppm), lower magnitude of negative Nb anomalies with high (Nb/Th)pm = 0.28-0.59 and (Nb/La)pm = 0.40-0.69 and Nb/U = 2.8-34.4 compared to normal arc basalts [Nb = <2 ppm; (Nb/Th)pm = 0.10-1.19; (Nb/La)pm 0.17-0.99 and Nb/U = 2.2-44 respectively] and HMA. Arc basalts and boninites are interpreted to be the products of juvenile subduction processes involving shallow level partial melting of mantle wedge under hydrous conditions triggered by slab-dehydrated fluid flux. The HMA resulted through partial melting of mantle wedge metasomatized by slab-dehydrated fluids and sediments during the intermediate stage of subduction. Slab-melting and mantle wedge hybridization processes at matured stages of subduction account for the generation of NEB. Thus, the arc basalt-boninite-HMA-NEB association from Malangtoli volcanic suite in Singhbhum Craton

  19. Geochemistry, age and strontium isotope composition of late tertiary and quaternary basalts and andesites in western Nevada and their relation to geothermal potential. Final report, October 1, 1982-December 31, 1983

    Energy Technology Data Exchange (ETDEWEB)

    Fultz, L.A.; Bell, E.J.; Trexler, D.T.


    This research was undertaken to characterize the late Cenozoic volcanic rocks associated with active geothermal systems in west-central Nevada. Petrographic and microprobe, geochemical and isotopic analysis and age dating techniques were used to characterize these young volcanic rocks. These data were combined with the limited data previously reported in the literature on these same volcanic areas to interpret their petrogenesis. The overall characterization resulted from integrating the petrogenesis with a structural-tectonic model of the region. Potassium-argon isotopic ages ranging up to 14 million years were determined for eight localities within the Reno 1 x 2/sup 0/ study region. These ages are consistent with the morphology of the volcanic landforms, the active geothermal systems associated with them, and with other isotopic ages reported in the literature for these and similar rocks within the study region. Petrographic analysis of hand specimens and thin-sections indicated mineralogic assemblages of the respective rock types and specific mineral textures and phenocryst compositions and characteristics. These identifications were further substantiated by microprobe analysis of selected phenocrysts and groundmass phases. Classification of the respective rock types was also based on chemical composition and normative calculations using the program PETCAL. Basaltic andesites are identified and described for Steamboat Hills, Table Mountain, Silver Springs, Churchill Butte, Cleaver Peak, Desert Peak and Carson City sites.

  20. Composition, volatile components, and trace elements in andesitic melts of the Kurile-Kamchatka region%俄罗斯Kurile-Kamchatka地区安山质熔体的成分、挥发分组成和微量元素

    Institute of Scientific and Technical Information of China (English)

    M.L.Tolstykh; V.B.Naumov; A.D.Babansky


    Melt inclusions in minerals from some volcanoes of the Kurile-Kamchatka region were examined. The studied basaltic andesites and andesites were sampled from volcanoes of the Central Kamchatka depression ( Shiveluch and Bezymyannyi), Eastern Kamchatka volcanic belt (Avachinskii and Karymskii), and Iturup Island, Southern Kuriles (Kudryavyi). Basalts of the 1996 eruption of the Karymskii volcanic center and dacites of Dikii Greben' volcano, Southern Kamchatka were also studied. More than 260 melt inclusions from 31 rock samples were homogenized, and quenched glasses were analyzed using electron and ion microprobes. The compositions of melt inclusions in andesitic phenocrysts vary in silica contents from 56 to 80wt%. Al2O3 , FeO, MgO, CaO decrease and Na2O and K2O increase with increasing SiO2. Many inclusions ( about 80% ) are dacitic or rhyolitic. However, the compositions of silicic glasses ( >65wt% SiO2 ) in andesites significantly differ in TiO2 , FeO, MgO, CaO, and K2O contents from those in dacites and rhyolites. High-potassium melts (K2O 3.8 ~6.8wt% ) with various SiO2 from 51.4 to 77.2wt% were found in minerals of all volcanoes studied. This indicates a contribution of a component selectively enriched in potassium to magmas of the whole region. A great compositional diversity of melt inclusions in plagioclase phenocrysts from the Bezymyannyi andesites suggests a complex history of plagioclase crystallization and magma evolution in the andesite formation. Melts from different volcanoes strongly vary in volatile contents. The highest H2O contents are found in the melts from Shiveluch (3.0 ~7.2wt%, 4.7wt% on average) and Avachinskii (4.7 ~4.8wt% ); while those are lower in melts of Kudryavyi (0.1 ~ 2.6wt% ), Dikii Greben' (0.4 ~ 1.8wt% ), and Bezymyannyi ( < 1wt% ). Chlorine contents are also variable. The lowest values are found in the Bezymyannyi melts (0.09wt% on average), the highest Cl contents are typical of melt inclusions in minerals from

  1. Las Andesitas Estrechura del Complejo Volcánico Piroclástico del Río Chubut Medio (Paleoceno-Eoceno Medio The Estrechura Andesites from the Middle Rio Chubut Volcanic-Pyroclastic Complex (Paleocene-Middle Eocene

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    E. Aragón


    Full Text Available Las Andesitas Estrechura muestran una tendencia evolutiva basalto-traquita del tipo toleítico transicional. En esta secuencia la inmisciblidad líquida está presente desde los basaltos hasta las traquitas. Esto permite establecer que: los basaltos y traquibasaltos representan el magma que se está fraccionando; las traquiandesitas son la mezcla de magma basáltico enriquecido con líquido inmiscible y las traquitas son el líquido inmiscible alojado en el techo de la cámara magmática. Aunque estos basaltos toleíticos transicionales sean pobres en agua, el enriquecimiento en volátiles por fraccionamiento en una de las fases inmiscibles permite la extrusión esporádica de ignimbritas que arrastran restos de magma sin vesicular y perliticos en los núcleos de los pómez. La profundidad de emplazamiento de la cámara magmática se estima próxima a los 4,5 kilómetros.The Estrechura Andesites show a basalt-trachyte tholeiitic transitional trend. Liquid immiscibility is present from basalts to trachytes. Thus, basalts and trachybasalts are interpreted as the fractionating magmas; the trachyandesites are the enriched (mix residual magma - immiscible liquid; and the trachytes are the segregated immiscible liquid at the magma chamber top. Even though it is a water poor system, the concentration of volatile in one of the immiscible liquids enables few ignimbrite extrusions that carry non-vesiculated perlitic magma blebs in pumice core. The depth of the magma chamber emplacement is estimated to be close to the 4,5 kilometers.

  2. High temperature uniaxial deformation experiment of bubble-free highly crystalline magmas; a case study for the high-Mg andesite from Goshiki-dai lava plateau, southwest Japan (Invited) (United States)

    Ishibashi, H.


    Rheological property of magma is a key factor for understanding various volcanic processes. Natural magmas commonly have crystals of various volume fraction and such suspended crystals strongly affect on magma rheology. For dilute to intermediately crystalline magmas, previous studies (e.g., Ishibashi, 2009JVGR; Vona et al. 2011ChemGeol) experimentally investigated the effects of suspended crystals on apparent viscosities and the model predicting the effects of crystals is proposed by Mader et al. (2013JVGR). However, for highly crystalline magmas, our knowledge on their complex rheological behaviors is still not enough even for bubble-free system whereas several experimental studies have been done (e.g., Carrichi et al., 2007EPSL; Picard et al., 2013JGR). Understanding rheological property in the crystal-melt two phase system is important for considering magma dynamics in deep magma chambers and dykes and also for investigating the property in bubble-crystal-melt three phase system. In this study, uniaxial compression deformation experiments were done for bubble-free, highly crystalline natural lava under high temperature, 1atm pressure conditions to investigate the effects of suspended crystals on rheology of bubble-free magma. The high-Mg andesite erupted at ca. 15 Ma from Goshiki-dai lava plateau, southwest Japan, was used for starting materials. The lava is aphyric, bubble-free, and composed of fine-grained elongated plagioclase, pyroxenes, and magnetite crystals and unaltered silicate glass. Crystal volume fraction is ca. 0.65. Samples were cut into rectangular with 15mm length, 15mm width, and 30 mm high from massive portion of lava without any visible fracture. The samples were deformed by using the high temperature uniaxial compression apparatus, installed at Earthquake Research Institute, the University of Tokyo, under conditions of temperature from 1292 to 1133 K, log strain rate from -5.5 to -2.5, and 1 atm pressure. Total strains of the samples are

  3. 西藏北部拉萨地块那曲地区约113Ma安山岩岩石成因与意义%Petrogenesis and implication of the andesites at ~ 113Ma in the Nagqu region in the northern Lhasa subterrane

    Institute of Scientific and Technical Information of China (English)

    黄玉; 朱弟成; 赵志丹; 张亮亮; Don DEPAOLO; 胡兆初; 袁洪林; 莫宣学


    The nature of magma source region and petrogenesis of the Early Cretaceous igneous rocks, which are widely distributed in the northern Lhasa subterrane, are not well constrained so far largely due to the limitation of high quality geochronological and geochemical data. This paper reports the petrologinal, zircon U-Pb dating, whole-rock geochemical and zircon Hf isotopic data of the andesites from Nagqu area, northern Lhasa subterrane. The andesites have been dated to be 112.7±0. 7Ma by zircon U-Pb dating method. These rocks are high-K calc-alkaline, enriched in large-ion lithophile elements (LILEs), Th, U, and light rare earth elements (LREEs), and depleted in high field strength elements (e. g. , Nb, Ta, P, and Ti; HFSEs). The andesites show high (87S/86Sr), values (0.7100-0.7126), negative eNd(t) values ( -10. 5 ~ -7.8), and negative zircon eHf(l) values ( -9.9~ -4. 7), yielding ancient two-stage Nd model ages of 1.5 ~ 1. 8Ga and zircon Hf isotope mantle model ages of 1. 0 ~ 1.6Ga. The data reported here, combined with regional geological background of the northern Lhasa subterrane, we propose that the Nagqu andesites can be considered as the products of partial melting of ancient lithospheric mantle of the Amdo microcontinent that was modified by fluids or/and melts of the sediments, and subsequendy experienced varying degrees of fractional crystallization. This magma event is most likely resulted from the slab break-off of the southward subduction of the Bangong-Nujiang Ocean seafloor.%西藏北部拉萨地块广泛分布着早白垩世岩浆岩,由于缺少高质量的年代学和地球化学数据,其岩浆源区和岩石成因迄今未能很好约束.本文报道了北部拉萨地块那曲地区安山岩的锆石U-Pb定年、地球化学和Sr-Nd-Hf同位素数据.那曲安山岩锆石U-Pb年龄为112.7±0.7Ma.岩石为高钾钙碱性系列,富集大离子亲石元素、Th、U和轻稀土元素[(La/Yb)N=6.62~11.68],亏损Nb、Ta、P和Ti等高

  4. The Late Jurassic high-Mg andesites in the Daru Tso area, Tibet:Evidence for the subduction of the Bangong Co-Nujiang River oceanic lithosphere%西藏达如错地区晚侏罗世高镁安山岩--班公湖-怒江洋壳俯冲消减的证据

    Institute of Scientific and Technical Information of China (English)

    李小波; 王保弟; 刘函; 王立全; 陈莉


    对出露于拉萨地块北部的达如错接奴群安山岩进行了年代学、元素地球化学和锆石原位Hf同位素研究。用LA-ICP-MS技术测得的安山岩锆石206Pb/238U年龄为163.3±1.7Ma,即火山活动时限为晚侏罗世早期。安山岩地球化学研究结果表明,其具有典型高镁安山岩的地球化学特征,所有样品均具有较高的MgO、Mg#值,低的TFeO/MgO值(小于1.5);所有样品都显示轻稀土元素富集,具有Eu负异常,富集大离子亲石元素、亏损高场强元素的特征;锆石εHf(t)值为较均一的负值(εHf(t)=-8.5~-6.7)。研究表明,达如错高镁安山岩很可能是班公湖—怒江洋壳在俯冲消减背景下,由俯冲沉积物熔融产生的熔体与地幔橄榄岩发生交代作用的产物,形成于与班公湖—怒江洋壳俯冲消减有关的活动大陆边缘(安第斯型)的构造环境。由此认为,晚侏罗世接奴群火山岩是班公湖—怒江洋壳俯冲消减的产物,从而为班公湖—怒江洋壳的俯冲消减提供了直接的火山岩证据。%This paper reports zircon U-Pb and Hf isotopic data of major and trace elements for the andesites of Jienu Group from the Daru Tso area in the northern Lhasa block. LA-ICP-MS U-Pb zircon analyses suggest that the andesite were formed at 163.3 ± 1.7Ma, and that the volcanic rocks were formed in early Late Jurassic period. Geochemical studies show Daru Tso andesites have typi⁃cal geochemical characteristics similar to the high-Mg andesite (HMA). They are characterized by high MgO content, Mg # values, and low TFeO/MgO ratios. They are enriched in LREE in the chondrite-normalized REE patterns with negative Eu anomalies, and are enriched in large ion lithophile elements (LILEs) and depleted in high field strength elements (HFSEs). Zircon εHf(t) values are from-8.5 to-6.7. Geochemical features of the Daru Tso high-Mg andesites are considered to have been generated by the subduc

  5. 赣东北蛇绿岩带新元古代(~800 Ma)高镁安山岩的发现及其意义%Recognition and Significance of Neoproterozoic (ca.800 Ma) High-Mg Andesites in the NE Jiangxi Ophiolite Belt

    Institute of Scientific and Technical Information of China (English)

    王存智; 余明刚; 黄志忠; 洪文涛; 赵希林; 姜杨; 周效华; 段政; 邢光福


    The newly discovered Neoproterozoic high-Mg andesites are located at Zhangshudun of the NE Jiangxi ophiolite belt and are dated at a zircon U-Pb age of 794.8 ±6.0 Ma.They have variable SiO2(54.90%~58.45%),CaO (2.46%~6.73%),relatively consistent Al2O3 (15.31%~16.77%,mostly less than 16%) and FeOT/MgO values (0.87~1.20),and show relatively high MgO contents (6.22~8.47%),high Mg#(64~7 1 ),which clearly exhibits the diagnostic features of typical high-Mg andesites.The study samples are enriched in LREE and have slightly negative Eu anomalies.In spider diagram,they show enrichment of LILE (eg.Rb,Ba) while depleted in Nb and Sr elements.These andesites have relatively low Sr abundance and Sr/Y ratios (4.1 1 ~7.29),similar to Sanukitoids of the Setouchi volcanic belt in Japan.The zircon Hf isotopes show positive initial epsilon Hf values ranging from +10.3 to +17.8.These geochemical data indicate Zhangshudun high-Mg andesites should derived from the deplted mantle wedge metasomatized by fluids released from the subducted slab,within an oceanic arc setting.Therefore,it is inferred that the Shuangxiwu arc was away from the southeastern margin of the Yangtze Block,and the Yangtze and Cathaysia blocks had not collided at least at ca.800Ma.%在赣东北蛇绿岩带中的樟树墩地区新发现新元古代高镁安山岩,其LA-ICP-MS锆石U-Pb法年龄为794.8±6.0 Ma。它们的 SiO2介于54.90%~58.45%,Al2O3介于15.31%~16.77%(平均小于16%);CaO 为2.46%~6.73%,FeOT/MgO变化于0.87~1.20,具有高MgO(6.39%~8.76%)、高Mg#(64~71)特点;富集轻稀土元素且具弱负Eu异常,明显富集LILE而亏损HFSE,Sr含量(普遍<200×10-6)和Sr/Y比值(4.11~7.29)均较低,具有典型高镁安山岩的地球化学特征,类似于日本Setouchi火山带的Sanukitoids。锆石εHf(t)值介于10.23~17.79之间,反映它们起源于亏损地幔。主、微量及同位素特征均表明,本区

  6. 内蒙古林西早中生代O型高镁埃达克质安山岩的发现及其意义%Early Mesozoic O-type High-Mg Adakitic Andesites from Linxi Area, Inner Mongolia and Its Implication

    Institute of Scientific and Technical Information of China (English)

    王冬兵; 刘勇胜; 宗克清; 高长贵; 徐娟


    对内蒙古林西地区火山岩样品的地球化学研究表明,其具有大洋型(O型)高镁埃达克质安山岩的地球化学特征[w(SiO_2)=57.89%~63.97%、w(Al_2O_3)=15.39%~16.17%、w(Na_2O)/w(K_2O)=1.5~2.2(除一个为0.9)、A/CNK=0.83~0.97、Mg~#=49~64、w(Cr)=91~209 μg/g、w(Ni)=52.2~111.4 μg/g、w(Sr)=551~1 018 μg/g、w(Yb)=1.18~1.71 μg/g、w(Y)=12.6~17.7 μg/g、δ(Eu)=0.86~0.94]. 利用LA-ICP-MS对其锆石进行了U-Pb定年,得到~(206)Pb/~(238)U加权平均年龄为(244±2)Ma(MSWD=0.36).此时,区域内古亚洲洋已闭合,综合地球化学特征和区域地质环境说明,林西高镁埃达克质安山岩是由残余洋壳部分熔融并随后与地幔橄榄岩相互作用形成的.内蒙古林西早中生代高镁埃达克质安山岩的产出表明,洋壳来源的埃达克岩(O型埃达克岩)不仅可以随俯冲同时产生,而且也可以在非俯冲环境下由保存在古俯冲带地幔中的残余洋壳部分熔融产生.%This paper studies geochemical compositions of volcanic samples from Linxi area, Inner Mongolia. The results show that these samples have similar geochemical characteristics of ocean-type (O-type) high-Mg adakitic andesites[SiO~2 = 57.89%~63.97%,A1_2O_3= 15.39%~16.17%,Na_2O/K_2O=l.5~2.2 (except one of 0.9), A/CNK =0.83~0.97, Mg~#=49~64、Cr=91~209 μg/g, Ni = 52.2~111.4 μg/g, Sr=551~1 018 μg/g, Yb=l.18~1.71 μg/g, Y=12.6~17.7 μg/g, and δ(Eu)=0.86~0.94]. LA-ICP-MS zircon U-Pb dating results for the Linxi high-Mg adakitic andesites yield a weighted mean ~(206)Pb/~(238)U age of (244±2)Ma (MSWD=0.36), when the Paleo-Asian ocean was closed. The combination of geolog-ical setting and geochemical characteristics of the Linxi high-Mg adakitic andesites suggests that the Linxi high-Mg adakitic rocks were most probably derived from partial melting of the remnant of Paleo-Asian oce-anic crust and subsequently hybridized by mantle peridotite. Generation of the Linxi early

  7. 粤北仁化白垩纪安山玢岩锆石年代学、地球化学和岩石成因研究%Geochronology, Geochemistry and Petrogenesis of Cretaceous Andesitic Porphyrite from Renhua Area, Northern Guangdong, SE China

    Institute of Scientific and Technical Information of China (English)

    蒋英; 梁新权; 梁细荣; 周云; 温淑女; 付建刚; 王策


    The Renhua andesitic porphyrite is exposed in the Danxia volcanic basin in the northern Guangdong, southeast of the Hunan-Guangxi Diwa series in South China. Volcanic rocks from Shibei and Miaochansi in the Renhua area have been dated to be 104.3±0.8 Ma and 105.0±0.7 Ma, respectively, using the method of LA-ICP-MS zircon U-Pb, which suggests that the Renhua andesitic porphyrites were formed in Early Cretaceous. The Shibei and Miaochansi andesitic porphyrites are of porphyritic texture, within which the phenocrysts are dominated by plagioclase and amphibole or pyroxene. They have K2O of 3.07%~3.81% and Mg# values of 49~61, with compositions similar to those of high-K calc-alkaline volcanic rocks. The rocks are enriched in large ion lithophile elements (LILEs, Rb, K, Th, U) and light rare earth elements (LREEs), and depleted in high field strength elements (HFSEs, Nb, Ta, Ti). The ratios of Zr/Y (6.56~9.10), Th/U (3.72~4.31), La/Nb (>3), Nb/La (10) of the rocks indicate that they are probably derived from intraplate mafic magma with the contamination of crust materials. Combined with the previous studies in this area, we conclude that the andesitic porphyrites in the Renhua area may have formed by partial melting of the lithospheric mantle in an intraplate extensional tectonic setting and subsequently experienced crystallization differentiation and crust contamination during the magma ascent and emplacement. Formation of the volcanic rocks was triggered by the subduction of the Pacific plate under the Eurasian plate during the late Early Cretaceous.%仁化安山玢岩分布在华南湘桂地洼系南东侧,位于广东韶关丹霞火山盆地中。来自仁化妙禅寺和石背两地的安山玢岩 LA-ICP-MS 锆石 U-Pb 测年结果分别为105.0±0.7 Ma 和104.3±0.8 Ma,表明其形成于中生代构造活化期最强烈的早白垩世晚期。妙禅寺和石背安山玢岩均具斑状结构,块状构造。斑晶主要为斜长石和角闪石或辉石,基质组

  8. Andesita Cerro Bola: Nueva unidad vinculada al magmatismo mioceno de la Cordillera de Olivares, San Juan, Argentina (30°35´S; 69°30´O Cerro Bola Andesite: New unit linked to the Miocene magmatism of the Olivares Cordillera, San Juan (30°35' S ; 68°30' W

    Directory of Open Access Journals (Sweden)

    A.F. Wetten


    properly in the regional stratigraphic context. The main outcrops were recognized in the Bola Hill and surroundings, where they are irregularly distributed, covering an area greater than 5 km². Dome and lava flow structures are present with the light gray andesite - phenoandesite rock. These outcrops can be correlated with the Pircas volcanic unit (Miocene, to the west, and could be further related to other porphyry bodies of different composition, situated both in Chita Creek and in Divisadero Hill. The extension of the area, lithological uniformity, the low alteration and a K/Ar radiometric age were considered, in order to propose these subvolcanic and volcanic bodies as a new lithostratigraphic unit, Upper Miocene in age, denominated "Cerro Bola Andesite".

  9. 江南中段慈化地区新元古代高镁安山岩的厘定及其构造意义%Geochronology and Geochemistry of Cihua Neoproterozoic High-Mg Andesites in Jiangnan Orogen and Their Tectonic Implications

    Institute of Scientific and Technical Information of China (English)

    张玉芝; 王岳军; 郭小飞; 甘成势; 邢晓婉; 宋菁菁


    江南造山带被普遍认为是扬子与华夏陆块在新元古代的拼合带,其拼合机制及精细时代却一直备受争议.在江南造山带中段湘赣交界慈化地区识别出新元古代火山岩,并对其进行了锆石 U-Pb 年代学及主微量地球化学研究.该火山岩发育于冷家溪群地层中,其锆石 LA-ICP-MS 年代学测试得到了832±12 Ma 的206 Pb/238 U 加权平均年龄(n=16,MSWD=0.12),代表其喷发年龄.主量元素结果显示,SiO2和 MgO 含量分别为57.67%~61.33%和3.51%~4.29%,Mg#为52~57,高于正常弧火山岩,属高镁安山岩.微量元素富集轻稀土元素和大离子亲石元素,亏损高场强元素,其 Nb-Ta、Ti 亏损,具“弧型”地球化学特征,可能来源于受板片熔体/流体或者俯冲再循环沉积物交代的难熔地幔源区.上述资料表明,慈化高镁安山岩是江南造山带中段楔形地幔源区受消减组分交代作用的产物,暗示此时江南造山带中段仍在消减,扬子和华夏陆块尚未完全拼合.结合前人研究成果,江南造山带不同区段的闭合时间可能存在差异.%It is generally accepted that the Jiangnan orogenic belt led to the amalgamation of the Yangtze with Cathaysia blocks during the Neoproterozoic period.However,its tectonic evolution and amalgamation timing are still in debate.This paper pres-ents a set of new geochronological and geochemical data for the newly-identified Neoproterozoic high-Mg volcanics from Cihua (Jiangxi).LA-ICP-MS zircon U-Pb dating of the representative sample yields a weighted mean age of 832±12 Ma (n=16, MSWD=0.12),representing the eruption age of the andesite.Geochemical results indicate that they can be classified as high-Mg andesites with SiO2 ranging from 57.67% to 61.33%,MgO from 3.51% to 4.29% and Mg-number from 52 to 57.Their chondrite-normalized REE patterns exhibit a left-sloping pattern with enriched LREEs

  10. Sulfur metabolizing microbes dominate microbial communities in Andesite-hosted shallow-sea hydrothermal systems.

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    Yao Zhang

    Full Text Available To determine microbial community composition, community spatial structure and possible key microbial processes in the shallow-sea hydrothermal vent systems off NE Taiwan's coast, we examined the bacterial and archaeal communities of four samples collected from the water column extending over a redoxocline gradient of a yellow and four from a white hydrothermal vent. Ribosomal tag pyrosequencing based on DNA and RNA showed statistically significant differences between the bacterial and archaeal communities of the different hydrothermal plumes. The bacterial and archaeal communities from the white hydrothermal plume were dominated by sulfur-reducing Nautilia and Thermococcus, whereas the yellow hydrothermal plume and the surface water were dominated by sulfide-oxidizing Thiomicrospira and Euryarchaeota Marine Group II, respectively. Canonical correspondence analyses indicate that methane (CH(4 concentration was the only statistically significant variable that explains all community cluster patterns. However, the results of pyrosequencing showed an essential absence of methanogens and methanotrophs at the two vent fields, suggesting that CH(4 was less tied to microbial processes in this shallow-sea hydrothermal system. We speculated that mixing between hydrothermal fluids and the sea or meteoric water leads to distinctly different CH(4 concentrations and redox niches between the yellow and white vents, consequently influencing the distribution patterns of the free-living Bacteria and Archaea. We concluded that sulfur-reducing and sulfide-oxidizing chemolithoautotrophs accounted for most of the primary biomass synthesis and that microbial sulfur metabolism fueled microbial energy flow and element cycling in the shallow hydrothermal systems off the coast of NE Taiwan.

  11. Wastewater Phosphorus Removal by Two Different Types of Andesitic Volcanic Tephra (United States)

    Liesch, Amanda M.


    Phosphorus (P) is the limiting nutrient controlling productivity in most inland freshwater systems. Several materials have been proposed for use to remove excess P from wastewater treatment, including volcanic lapilli and ash (tephra). There is limited data in using tephra as a P filter. There were two objectives of this study: (1) to determine…

  12. The Petrographic Distinction between Basalt and Andesite Based upon the Arrested Fractionation of Plagioclase Phenocrysts. (United States)

    Garlick, G. Donald; Garlick, Benjamin J.


    Discusses the need to take into account the effects of arrested fractional crystallization in the petrographic classification of volcanic rocks containing plagioclase phenocrysts. Describes the development and use of a computer program to accomplish this task graphically. (TW)

  13. On the conditions of magma mixing and its bearing on andesite production in the crust. (United States)

    Laumonier, Mickael; Scaillet, Bruno; Pichavant, Michel; Champallier, Rémi; Andujar, Joan; Arbaret, Laurent


    Mixing between magmas is thought to affect a variety of processes, from the growth of continental crust to the triggering of volcanic eruptions, but its thermophysical viability remains unclear. Here, by using high-pressure mixing experiments and thermal calculations, we show that hybridization during single-intrusive events requires injection of high proportions of the replenishing magma during short periods, producing magmas with 55-58 wt% SiO2 when the mafic end-member is basaltic. High strain rates and gas-rich conditions may produce more felsic hybrids. The incremental growth of crustal reservoirs limits the production of hybrids to the waning stage of pluton assembly and to small portions of it. Large-scale mixing appears to be more efficient at lower crustal conditions, but requires higher proportions of mafic melt, producing more mafic hybrids than in shallow reservoirs. Altogether, our results show that hybrid arc magmas correspond to periods of enhanced magma production at depth.

  14. Posteruptive impacts of pyroclastic deposits from basaltic andesite stratovolcanoes on surface water composition (United States)

    Genareau, K.; Cronin, S. J.; Stewart, C.; Bhattacharyya, S.; Donahoe, R.


    Volcanic ash deposition following explosive eruptions can pose significant hazards for water quality, human health, agriculture, and infrastructure functionality. Many studies have examined how fresh ash deposition may lower the pH of, and introduce a range of potentially toxic elements into, exposed surface waters. However, no study has yet determined the effects on water composition as a result of mechanical pyroclast disaggregation and production of new fresh particle surfaces and increasingly fine grained particles. Such disaggregation could result from natural posteruptive processes such as debris avalanches, lahars, or fluvial/aeolian transport and human activities such as cleanup efforts or mining of pyroclastic deposits. The posteruption time scales of pyroclast disaggregation may vary from months in moist tropical or temperate environments to years or decades in arid settings. Here we show, for the first time in experimental studies, that mechanical milling of pyroclasts will introduce a range of elements into exposed waters, including Al, which can be toxic at elevated levels, and Na, which increases the electrical conductivity of solutions. The pH of leaching solutions also increases by several log units. Such dramatic changes on the experimental scale may have implications for surface water composition in posteruptive settings, necessitating longer-term risk assessments for ecosystem health and consideration of the role of pyroclastic deposits in element cycling in volcanically active regions.

  15. Anhydrite-bearing andesite and dacite as a source for sulfur in magmatic-hydrothermal mineral deposits (United States)

    Chambefort, Isabelle; Dilles, John H.; Kent, Adam J. R.


    Magmaticanhydritefromandesitesanddacitesoccursasinclusionsinhigh-andlow-aluminumamphibole and pyroxene and indicates that sulfate-saturatedmagmas spanned a period of six million years at Yanacocha, Peru.Magmatic anhydrite from Yanacocha and other sites is characterizedby light rare earth element-enriched patterns and elevatedstrontium contents distinct from magmatic-hydrothermal anhydrite.Petrologic arguments suggest that the hydrous and oxidized Yanacochamagmas contained more than ~1000 ppm sulfur both dissolved inthe melt and as a separate sulfate phase, which is sufficientto provide all the sulfur for the genetically related giantsulfur-rich Yanacocha epithermal gold deposits. High-aluminumamphiboles contain unusual anhydrite with wormy and amoeboidaltextures, which are tentatively interpreted to represent trappingof an immiscible CaSO4-water melt together with sulfur-richapatite at a temperature of ~950 °C and a water pressure>3 kbar. Such unusually sulfate-rich magmas may be requiredto produce sulfur-rich magmatic-hydrothermal mineral deposits.

  16. New insights into the evolution of the magmatic system of a composite andesite volcano revealed by clasts from distal mass-flow deposits: Ruapehu volcano, New Zealand (United States)

    Tost, M.; Price, R. C.; Cronin, S. J.; Smith, I. E. M.


    Stratovolcanoes characteristically build large composite edifices over long periods with stacked lavas intercalated with pyroclastic deposits. In most cases, only the most recent volcanic products are exposed on the flanks of the volcano, and consequently the search for deposits recording an older eruptive and magmatic history is typically focussed far from the cone, within distal tephra deposits. Clasts within lahar and debris avalanche deposits may also provide unique insights into the earliest eruptive and magmatic history of long-lived volcanoes, especially when widespread fallout is absent. Careful sampling and subsequent petrological and geochemical analyses of lava and pumice clasts from six distal mass-flow deposit sequences (hyperconcentrated flow, debris flows and debris avalanche deposits) from Mt. Ruapehu (New Zealand), combined with detailed stratigraphic studies and radiometric age dating, give new perspectives on the pre-50 ka magmatic system of this complex volcano. A conglomerate emplaced between 340 and 310 ka contains evidence for the oldest episode of Mt. Ruapehu volcanism, and unusually for the composite cone, pumice clasts from this unit contain amphibole-bearing xenoliths. Chemical and petrological data for these oldest Ruapehu clasts indicate that a deep (˜40 km) crustal storage system had already developed under Mt. Ruapehu before ˜340 ka. From the very earliest stages, evolution was largely controlled by magma mixing, along with decoupled assimilation and fractional crystallization within numerous isolated small-scale magma batches stored throughout the crust. From around 340 to 160 ka, there was a progressive shift towards more primitive compositions, suggesting that during this period large-scale replenishment events involving mantle-derived basaltic magmas occurred within the mid- to upper crustal storage system. Subsequent magmas became progressively more evolved due to decoupled fractional crystallization and assimilation processes accompanied by magma recharge events, which triggered major phases of eruptive activity.

  17. The effect of kauri (Agathis australis) on grain size distribution and clay mineralogy of andesitic soils in the Waitakere Ranges, New Zealand

    NARCIS (Netherlands)

    Jongkind, A.G.; Buurman, P.


    Kauri (Agathis australis) is generally associated with intense podzolisation, but little research has been carried out to substantiate this. We studied soil profiles, grain size distribution patterns and clay mineralogy under kauri and broadleaf/tree fern vegetation in the Waitakere Ranges, North Is

  18. Morphological analysis of Nevado de Toluca volcano (Mexico): new insights into the structure and evolution of an andesitic to dacitic stratovolcano (United States)

    Norini, Gianluca; Groppelli, Gianluca; Capra, Lucia; De Beni, Emanuela


    We present a morphological analysis of Nevado de Toluca volcano located 80 km WSW of Mexico City based on digital elevation model study, where slope and aspect maps have been generated and analysed. Aerial photograph and satellite image observations improve the morphological analysis. The synoptic view which is offered by this analysis allowed for recognition and localization of the main volcanic and tectonic features of the area. On the basis of digital elevation model value distribution and surface textures, five morphological domains were defined. The most interesting domain, south of the crater, reflects the occurrence of an ancient complex volcano distinct from the adjacent areas. Interaction between the volcanic and volcano-tectonic evolution and the basement produced the other domains. Single volcanic edifices, like lava domes and scoria cones, and eruptive fractures were recognized. Finally, flank collapse scarps opened to the east and to the north were identified and four relevant morphostructural lineaments and their possible role in the Nevado de Toluca geological and structural evolution are discussed.

  19. High-Mg andesites and their geodynamic implications%高镁安山岩及其地球动力学意义

    Institute of Scientific and Technical Information of China (English)

    唐功建; 王强



  20. Geochemical discrimination of the geotectonic environment of basaltic-andesitic volcanic rocks associated with the Laochang polymetallic ore deposit at Lancang, Yunnan

    Institute of Scientific and Technical Information of China (English)

    GAO Jianguo


    The Laochang polymetallic ore deposit at Lancang is one of the well known ancient ore deposits associated with volcanic rocks in the Sanjiang (Tri-river) region of Southwest China. Volcanic rocks are dominated by alkali basalt and trachyte basalt. There has long been a controversy on the environment of formation of basalts. Some scholars hold that the basalts were formed in a continental environment, some thought they were formed in an oceanic environment and others considered that the basalts were emplaced in a back-arc basin. This study focuses on the geochemical characteristics of the basalts on the basis of their major elements, REEs and trace elements. At the same time, strongly incompatible elements such as Ta, Th and Hf and their ratios were used to differentiate the geotectonic settings of basalts. The results showed that the basalts in the region studied were formed in a continental rift environment.

  1. Chronological record of the Early Mesozoic underplating in the northern margin of North China-U-Pb chronometry of zircons in the Late Mesozoic andesite from Western Liaoning

    Institute of Scientific and Technical Information of China (English)


    Cathodoluminescence spectroscopic analysis of zircons in the uppermost sanukites of the early Cretaceous Yixian Formation in Western Liaoning reveals zoning structures of the zircons in the volcanic rocks. LA-ICP-MS chronometry shows that the central part of the zircons is remnant zircon with a U-Pb dating of 254 Ma, which is consistent with the age of the Early Mesozoic underplating granulites, and that the periphery is zircon crystallizing out of the host magma with a U-Pb dating of 116 Ma, which is highly consistent with the Ar-Ar dating of the host volcanic rocks. Compositions of the clinopyroxenes xenocrystals in the sanukites are similar to those of the clinopyroxenes in the underplating granulites, indicating that the granulites accreted to the lower crust in the Early Mesozoic have been reformed and disrupted by the upwelling diapers of the asthenosphere and taken part in formation of the sanukites in the Late Mesozoic.

  2. Discovery of the basaltic andesite-high-K basaltic andesite-trachyandesite association in the Yuximolegai Daban,West Tianshan and its geological significance%西天山玉希莫勒盖达坂玄武安山岩-高钾玄武安山岩-粗安岩组合的发现及其地质意义

    Institute of Scientific and Technical Information of China (English)

    罗勇; 牛贺才; 单强; 张兵; 周昌平; 杨武斌; 于学元


    在阿吾拉勒东段玉希莫勒盖达坂地区大哈拉军山组主要是一套以安山质(粗安质)-英安质(粗面质-粗面英安质)火山熔岩和火山碎屑岩为主的火山岩建造.根据岩石地球化学特征,本文在大哈拉军山组火山岩的上部厘定出了钙碱性玄武安山岩-高钾钙碱性玄武安山岩-粗安岩(橄榄安粗岩系)组合.微量元素地球化学特征显示,三类岩石形成于岛弧环境,钙碱性玄武安山岩的形成与板片俯冲作用有关,而高钾钙碱性玄武安山岩和粗安岩的形成则与俯冲板片断裂诱发的软流圈上涌作用有关.钙碱性玄武安山岩-高钾钙碱性玄武安山岩-粗安岩组合的存在说明阿吾拉勒东段在晚石炭世由于俯冲板片的断裂,构造体制由挤压转变为伸展.玉希莫勒盖达坂大哈拉军山组上部的火山岩组合与世界许多著名铜-金矿集区(如Papua New Guinea)的火山岩组合相似,显示该地区晚石炭世具有良好的铜、金成矿条件.

  3. Magnesian andesites from White Island, New Zealand : Mineralogical evidence for mixing of high-magnesian basalt and dacite magmas : Mineralogical evidence for mixing of high-magnesian basalt and dacite magmas(MEMORIAL VOLUME TO THE LATE PROFESSOR TERUHIKO SAMESHIMA)



    ホワイト島火山から1977年の噴火で放出された火山岩塊は, 化学組成では, 瀬戸内火山岩のカンラン石, 単斜輝石, 斜方輝石の順に, Mg#が連続的に減少する単斜輝石高マグネシア安山岩に似る.しかし鉱物化学組成はまったく異なり, ホワイト島高マグネシア安山岩は, 著しくMgに富み(Fo_), 正規累帯をなすカンラン石と, 対照的にMgに比較的乏しく(Mg#=84-73), 逆累帯を示す単斜および斜方輝石をもつ.特に, 単斜輝石の核部はMg#が79-75とカンラン石に比べ低く, カンラン石を晶出させたと同一のマグマに由来するとは考え難い.ホワイト島高マグネシア安山岩は高マグネシア玄武岩質マグマとデイサイト質マグマの混合によって生じた。...

  4. Geochemistry and petrology of the most recent deposits from Cotopaxi volcano, Northern Volcanic Zone, Ecuador.



    Cotopaxi volcano is located in the Northern Volcanic Zone of the South American Andes. Pyroclastic deposits and lava flows from Cotopaxi comprise basaltic andesites, andesites and rhyolites that have erupted since 13 200 years BP. Nine rhyolite eruptions were produced in at least five separate events, punctuated by intermittent andesite eruptions. High La/Yb (>5) and 230Th excesses in the andesites are consistent with equilibration of magma with garnet-bearing lower crust or mantle, and numer...

  5. 右江盆地晚侏罗世钾玄质高镁安山岩的厘定及其构造意义%The identification and implications of the Late Jurassic shoshonitic high-Mg andesite from the Youjiang basin

    Institute of Scientific and Technical Information of China (English)

    甘成势; 王岳军; 张玉芝; 刘汇川; 张立敏


    右江盆地在大地构造上处于特提斯和滨太平洋构造域的结合部位.本文报道了该盆地东部杨屯安山岩的岩相学、年代学和地球化学特征.杨屯安山岩具斑状结构和气孔状构造,斑晶主要为辉石,基质以针状斜长石微晶为主,含少量辉石.LA-ICP-MS锆石U-Pb定年结果表明杨屯安山岩的喷发时代为159.3±2.8Ma,即晚侏罗世.样品的SiO2含量为53.13%~55.71%,具高MgO(6.74%~8.85%)、Mg#值(63~72)、Cr(416×10-6~565×10-6)和Ni (207×10-6~246×10-6),低FeOT/MgO (0.83~1.23)等特征,与典型高镁安山岩的特征相似.所有样品具高K2O (3.39%~4.77%)和K2O/Na2O(1.31~2.33),同时也具钾玄质岩石的地球化学特征.样品强烈富集大离子亲石元素和轻稀土元素,而亏损高场强元素,具较高的Rb/Sr (0.20~0.46)和较低的Ba/Rb (7.17 ~9.30),富集的Sr-Nd同位素组成((87Sr/86 Sr)i=0.70738~0.70739,εNd (t)=-3.6~-3.4).元素和同位素特征表明杨屯钾玄质高镁安山岩是含金云母的富集岩石圈地幔部分熔融的产物,形成于板内伸展环境而不是岛弧环境.晚侏罗世杨屯钾玄质高镁安山岩的厘定,反映了该时期右江地区处于岩石圈伸展-减薄阶段.

  6. Early Paleozoic subduction of the Paleo-Asian Ocean: Zircon U-Pb geochronological and geochemical evidence from the Kalatag high-Mg andesites, East Tianshan%早古生代古亚洲洋俯冲记录:来自东天山卡拉塔格高镁安山岩的年代学、地球化学证据

    Institute of Scientific and Technical Information of China (English)

    李玮; 陈隽璐; 董云鹏; 徐学义; 李智佩; 柳小明; 何登峰


    吐哈盆地南缘荒草坡群大柳沟组火山岩出露于大草滩断裂以北的彩霞山、土屋铜矿北和卡拉塔格地区.该组火山岩主要为基性、中酸性熔岩及火山碎屑岩组合.LA-ICP MS锆石U-Pb分析获得安山岩和英安岩的年龄分别为434.8±3.8Ma和438.4 ±4.9Ma,表明大柳沟组火山岩形成于早志留世.安山岩SiO2含量为54.35%~60.70%;Al2O3含量为11.8%~16.3%,MgO含量为4.94%~8.27%,TiO2含量为0.38% ~0.52%,Na2O和K2O的含量分别为0.50%~3.83%和0.08%~1.26%,铝饱和指数(A/CNK)为0.77 ~ 1.37,低∑REE(43×10-6 ~70×10-6),为具有亏损源区特征的高镁安山岩.英安岩较安山岩SiO2含量高(63.74% ~75.35%),具有相似的Al2O3(12.3% ~ 16.0%%)和TiO2(0.32% ~0.52%)含量;Na2O和K2O含量分别为2.01% ~5.53%和0.16% ~2.19%,∑REE含量较安山岩略高(61×10-6 ~84×10-6),铝饱和指数(A/CNK)为0.77 ~5.74.安山岩和英安岩均轻重稀土分异明显,具有中等的Eu负异常;富集大离子亲石元素(LILE),亏损高场强元素(HFSE),具有明显的Nb-Ta-Ti负异常.相似的岩石地球化学特征表明安山岩和英安岩可能为同源岩浆,英安岩是安山质岩浆经过角闪石等矿物结晶分异作用形成的,安山岩的母岩岩浆很可能来自亏损大洋岩石圈地幔.基于该组岩石组合、地球化学特征和区域地质资料,推测研究区高镁安山岩可能形成于洋内弧环境,这表明东天山吐哈盆地南缘卡拉塔格地区在早古生代已经存在古亚洲洋的俯冲.

  7. Zircon SHRIMP geochronology and geochemistry of Late Permian high-Mg andesites in Seluohe area, Jilin province, China%吉林色洛河晚二叠世高镁安山岩SHRIMP锆石年代学及其地球化学特征

    Institute of Scientific and Technical Information of China (English)

    李承东; 张福勤; 苗来成; 颉航强; 许雅雯


    吉林色洛河地区发育高镁安山岩类,SHRIMP锆石U-Pb定年结果表明它们形成于晚二叠世(252±5Ma).色洛河高镁安山岩类(SiO259.08%~65.67%)具有富MgO(3.68%~5.30%),高Mg#值(0.62~0.68,平均0.66),高Cr(203.17×10-6~379.70×10-6,平均258.79×10-6)、Ni(98.13×10-6~249.35×10-6,平均137.00×10-6)含量;富集大离子亲石元素(如Cs、K、Pb、Rb和Ba),亏损高场强元素(如Ta、Ti、Nb、P);富集LREE(Ce39.14×10-6~48.74×10-6),强烈亏损HREE(Yb 0.95×10-6~1.27×10-6,Y 10.80×10-6~13.13×10-6,(La/Yb)N13.27~16.66);但它们含有较低的Sr(158.62×10-6~369.77×10-6,平均258.52×10-6).它们属于中钾、钙碱性系列,具有明显的结晶分异和同化混染特征.上述地球化学特征表明它可能与消减沉积物流体交代形成富集地幔的部分熔融有关,其后又经历了分异和混染作用.这揭示它们形成于活动陆缘的构造背景,表明晚古生代末期古亚洲洋板块仍在消减,华北地块和佳木斯-兴凯地块(中亚造山带)最终的拼合时间可能在二叠纪之后.

  8. Reaction experiments between tonalitic melt and mantle olivine and their implications for genesis of high-Mg andesites within cratons%英云闪长质熔体与地幔橄榄石反应的实验研究——对克拉通内部高镁安山岩成因的约束

    Institute of Scientific and Technical Information of China (English)

    王明梁; 唐红峰


    产于克拉通内部的高镁(Mg#>45)安山岩受到地学界的高度关注,目前对于高镁安山岩的成因仍然存在明显的争议.为了对已有基于岩石学和地球化学研究推断的克拉通内部高镁安山岩成因认识进行检验并提供直接的证据,我们在六面顶压机上开展了1250~1400℃,2.0~5.0 GPa条件下英云闪长质熔体与地幔橄榄石反应的高温高压实验,模拟研究拆沉到地幔的榴辉岩化下地壳部分熔融产生的熔体与地幔橄榄岩的反应.实验结果显示,反应后熔体的化学组成与华北克拉通内部高镁安山岩有很相似的变化.因此,榴辉岩化下地壳部分熔融产生的英云闪长质熔体与地幔橄榄岩的反应可能是形成克拉通内部高镁安山岩的重要机制之一.

  9. Geochemical Characterization of Endmember Mantle Components (United States)


    Scholl, Along-strike variation in the Aleutian island arc: Genesis of high Mg # andesite and implications for continental crust, in Inside the...G.M. Yogodzinski and D.W. Scholl, Along-strike variation in lavas of the Aleutian island arc: Implications for the genesis of high Mg # andesite and...genesis of high Mg # andesite and the continental crust, In: Inside the Subduction Factory, Ed. J. Eiler, AGU Monograph 138, 2003b. Kelley, K.A., T

  10. Carboniferous adakite-high-Mg andesite-Nb-enriched basaltic rock suites in the Northern Tianshan area: Implications for Phanerozoic crustal growth in the Central Asia Orogenic Belt and Cu-Au mineralization%天山北部石炭纪埃达克岩-高镁安山岩-富Nb岛弧玄武质岩:对中亚造山带显生宙地壳增生与铜金成矿的意义

    Institute of Scientific and Technical Information of China (English)

    王强; 赵振华; 许继峰; Derek; A.WYMAN; 熊小林; 资峰; 白正华



  11. Research on isotope geology: Isotopes ages of volcanic rocks from Ryeongnam Massif, Korea

    Energy Technology Data Exchange (ETDEWEB)

    Shin, Seong Cheon; Chi, Se Jung; Kim, Yoo Sook [Korea Institute of Geology Mining and Materials, Taejon (Korea, Republic of)


    Chronostratigraphy of most volcanic rocks in the Ryeongnam Massif have been undefined or mis-classified in different geological maps due to total absence of reported isotope ages. Twenty-four new isotope ages are given for age-undefined volcanic units and some related igneous bodies. Most of volcanic rocks show high [La/Yb]n ratios and LREE enrichments which are characteristics of subduction-related high-K calc-alkali volcanic rocks occurred in the active continental margin. Preliminary results on carbon and oxygen stable isotope ratios({delta}{sup 13}C=-1.7{approx}-6.2 per mil; {delta}{sup 18} O=-21.6{approx}-24.7 per mil) of druse- or phenocryst-calcite from andesitic and basaltic rocks in the southern coastal region indicate a magmatic origin. Based on new K-Ar whole-rock ages, chronological guidelines are established as follows: 1) Gayasan andesite (78{+-}4Ma) - Gurye andesitic tuff (81{+-}4Ma); 2) Gurye andesite (68{+-}4Ma) - Suncheon andesitic tuff (67{+-}3Ma) - Yeosu basaltic andesite (67{+-}3Ma) - Narodo andesite (70{+-}3Ma); 3) Taebaeg Baegbyeongsan basaltic andesite (62{+-}3Ma) - Gurye Obongsan andesite (64{+-}3Ma) - Yeosu dacite (63{+-}3Ma) - Dolsando andesite (62{+-}3Ma) - Jangheung Buyongsan andesite (65{+-}3Ma); 4) Suncheon Joryedong andesite (55{+-}2Ma) - Goheung andesite (56{+-}3Ma); 5) Taebaeg Baegbyeonsan basaltic andesite (48{+-}2Ma) - Yeosu basalt (51{+-}3Ma). Resetted age (49{+-}2Ma) of an intrusive rhyolite implies the timing of thermal alteration in the Wondong Fe-Mine of the Taebaegsan Mineralized Belt. K-Ar hornblende ages of two hornblendite stocks in the southern Jangsu suggests apparent emplacement-ages of late Triassic (210{+-}9Ma) and early Permian (274{+-}10Ma), independently. K-Ar hornblende age (1023{+-}37Ma) of the Ogbang amphibolite implies a reduction of original age due to later thermal effect probably attributed to either later intrusion or regional metamorphism. (author). 56 refs., 19 tabs., 14 figs.

  12. Geochemistry of the 1989-1990 eruption of redoubt volcano: Part I. Whole-rock major- and trace-element chemistry (United States)

    Nye, C.J.; Swanson, S.E.; Avery, V.F.; Miller, T.P.


    The 1989-1990 eruption of Redoubt Volcano produced medium-K calc-alkaline andesite and dacite of limited compositional range (58.2-63.4% SiO2) and entrained quenched andesitic inclusions (55% SiO2) which bear chemical similarities to the rest of the ejecta. The earliest (December 15) magmas are pumiceous, often compositionally banded, and the majority is relatively mafic ( 60 wt.%). They have Mg, Cr, Ni, Sc, and V contents higher than the andesites, but lower than Redoubt basalts and basaltic andesites. Thus, they may be crystallization products of andesites, but do not represent the cumulate residue of basalt fractionation. The xenoliths were probably derived from a shallow or intermediate crustal chamber. ?? 1994.

  13. Does subduction zone magmatism produce average continental crust (United States)

    Ellam, R. M.; Hawkesworth, C. J.


    The question of whether present day subduction zone magmatism produces material of average continental crust composition, which perhaps most would agree is andesitic, is addressed. It was argued that modern andesitic to dacitic rocks in Andean-type settings are produced by plagioclase fractionation of mantle derived basalts, leaving a complementary residue with low Rb/Sr and a positive Eu anomaly. This residue must be removed, for example by delamination, if the average crust produced in these settings is andesitic. The author argued against this, pointing out the absence of evidence for such a signature in the mantle. Either the average crust is not andesitic, a conclusion the author was not entirely comfortable with, or other crust forming processes must be sought. One possibility is that during the Archean, direct slab melting of basaltic or eclogitic oceanic crust produced felsic melts, which together with about 65 percent mafic material, yielded an average crust of andesitic composition.

  14. Magmatic controls on eruption dynamics of the 1950 yr B.P. eruption of San Antonio Volcano, Tacaná Volcanic Complex, Mexico-Guatemala (United States)

    Mora, Juan Carlos; Gardner, James Edward; Macías, José Luis; Meriggi, Lorenzo; Santo, Alba Patrizia


    San Antonio Volcano, in the Tacaná Volcanic Complex, erupted ~ 1950 yr. B.P., with a Pelean type eruption that produced andesitic pyroclastic surges and block-and-ash flows destroying part of the volcano summit and producing a horse-shoe shaped crater open to the SW. Between 1950 and 800 yr B.P. the eruption continued with effusive andesites followed by a dacite lava flow and a summit dome, all from a single magma batch. All products consist of phenocrysts and microphenocrysts of zoned plagioclase, amphibole, pyroxene, magnetite ± ilmenite, set in partially crystallized groundmass of glass and microlites of the same mineral phases, except for the lack of amphibole. Included in the andesitic blocks of the block-and-ash flow deposit are basaltic andesite enclaves with elongated and ellipsoidal forms and chilled margins. The enclaves have intersertal textures with brown glass between microphenocrysts of plagioclase, hornblende, pyroxene, and olivine, and minor proportions of phenocrysts of plagioclase, hornblende, and pyroxene. A compositional range obtained of blocks and enclaves resulted from mixing between andesite (866 °C ± 22) and basaltic andesite (enclaves, 932 °C ± 22), which may have triggered the explosive Pelean eruption. Vestiges of that mixing are preserved as complex compositional zones in plagioclase and clinopyroxene-rich reaction rims in amphibole in the andesite. Whole-rock chemistry, geothermometry, experimental petrology and modeling results suggest that after the mixing event the eruption tapped hybrid andesitic magma (≤ 900 °C) and ended with effusive dacitic magma (~ 825 °C), all of which were stored at ~ 200 MPa water pressure. A complex open-system evolution that involved crustal end-members best explains the generation of effusive dacite from the hybrid andesite. Amphibole in the dacite is rimmed by reaction products of plagioclase, orthopyroxene, and Fe-Ti oxides produced by decompression during ascent. Amphibole in the andesite

  15. Magmatic processes under Quizapu volcano, Chile, identified from geochemical and textural studies (United States)

    Higgins, Michael D.; Voos, Stéphanie; Vander Auwera, Jacqueline


    Quizapu is part of a linear system of active volcanos in central Chile. The volcanic petrology and geology have been used to infer the plumbing system beneath the volcano. The 1846-1847 eruption (~5 km3) started with small flows of dacite, then changed to a range of andesite-dacite compositions and finally terminated with large flows of dacite. Andesitic enclaves (feed the system—first mixed magmas, then back to dacites. The eruption then terminated until 1932 when renewed injection of andesite into the system created a conduit that tapped an undegassed dacite chamber and resulted in a strong explosive eruption. The whole story is one of continual andesite magmatism, modulated by storage, degassing and mixing.

  16. Mount Pinatubo, Philippines: June 1991 Eruptions (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Mount Pinatubo is an andesitic island arc volcano, located on the southern Luzon Island, Philippines. Prior to 1991 it had been dormant for more than 635 years. On...

  17. Physical weathering and modification of a rhyolitic hyaloclastite in Iceland

    NARCIS (Netherlands)

    de Vet, S.J.; Mittelmeijer-Hazeleger, M.C.; Braakhekke, J.J.M.; Cammeraat, L.H.


    Fragmental volcanic glass or 'hyaloclastite' is a common glaciovolcanic eruption product that is formed in large abundance during basaltic, andesitic and rhyolitic sub-glacial eruptions. The physical weathering of rhyolitic hyaloclastites differs notably from basaltic hyaloclastites due to differenc

  18. 1991 Pinatubo, Philippines Images (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Mount Pinatubo is an andesitic island arc volcano, located on the southwestern part of the island of Luzon in the Philippines. Prior to 1991, it had been dormant for...

  19. The petrology, geochronology and geochemistry of Hauhungatahi volcano, S.W. Taupo Volcanic Zone (United States)

    Cameron, Errol; Gamble, John; Price, Richard; Smith, Ian; McIntosh, William; Gardner, Mairi


    Hauhungatahi volcano is an eroded andesitic edifice 10 km west of Ruapehu volcano constructed on an upfaulted block of Mesozoic marine sediments. Hauhungatahi andesites are distinctively clinopyroxene-phyric with high ratios of clinopyroxene:plagioclase. This contrasts with the plagioclase-phyric dominated assemblages in the stratovolcanoes such as Ruapehu and Tongariro. Hauhungatahi andesites show high MgO (> 8.0% wt), Sr (> 400 ppm), Ni (> 100 ppm) and Cr (> 400 ppm) and low Si, Rb, Ba and Zr relative to andesites from Ruapehu volcano, with fractionated LREE (Ce/Sm) n ~ 2 and flat HREE (Dy/Yb) n ~ 1. Sr-isotope ratios are lower at equivalent Nd isotope ratios than Ruapehu andesites of the (oldest) Te Herenga Formation. 40Ar/ 39Ar step-heating experiments of groundmass concentrates of 4 samples have yielded ages between 881 ± 83 ka and 961 ± 59 ka, with a weighted mean age of 933 ± 46 ka, indicating that Hauhungatahi is significantly older than Ruapehu Volcano where volcanism commenced ~ 250-300 ka. Hauhungatahi is therefore similar in age to the older andesitic edifices that are marginal to the TVZ (eg Titiraupenga, Pureora and Rolles Peak). We suggest that these high-Mg andesites hold clues to the early conditioning of the lithosphere beneath TVZ, prior to the establishment of the large andesite stratovolcanoes that presently dominate the skyline at the southern end of TVZ. The relatively low abundance of plagioclase in the phenocryst assemblages hints at high P H 2O and possible involvement of amphibole in the source.

  20. Stratabound and vein-type Pb-Zn mineralization at Las Canas, Chanarcillo Group, northern Chile; fluid inclusion microthermometry, and sulfur and lead isotope constraints


    Lieben, François Claude Serge; Moritz, Robert; Fontboté, Lluis; Chiaradia, Massimo


    The Las Canas stratabound Pb-Zn deposit, in northern Chile, is hosted by the Lower Cretaceous back-arc marine carbonate and subordinate andesitic volcanic and volcaniclastic rocks of the Chanarcillo Group, one hundred meters above a thick pile of magmatic arc-related basaltic to andesitic lavas of the Bandurrias Formation. The deposit is not obviously related to local intrusive rocks, which include an Upper Cretaceous granodiorite batholith and dacite dikes emplaced along normal faults. Strat...

  1. Geologic and chemical evolution of volcan tepetiltic, Nayarit, Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Deremer, L.A.; Nelson, S.A.


    Volcan Tepetiltic is located in the northwestern segment of the Mexican Volcanic Belt, about 40 km SW of the city of Tepic. The structure is a calc-alkaline stratovolcano composed primarily of andesite and dacite lava flows topped by an elliptical caldera measuring approximately 5 by 2.5 km. At least two cycles of andesite volcanism followed by rapid differentiation into volumetrically subordinate dacite flows and dikes built the majority of the complex. The second pulse of andesitic lavas were more basic than the first and appear to have been the result of reinjection of mafic magma into the shallow andesitic magma chamber. This was closely followed by the emplacement of two rhyolite domes and associated ash deposits on the eastern flank of the volcano. Finally, two small hornblende andesite domes were erupted on the floor of the caldera, and a lake formed in the northeastern corner of the caldera. Cinder cones on the flanks of the volcano have erupted alkaline lavas of mugearitic affinity. These are chemically unrelated to the calc-alkaline lavas erupted from Tepetiltic itself. The latest activity of Tepetiltic was the emplacement of a crystal rich rhyolite domes on the southern flank, which has blocked stream drainages to form a coulee lake. This last event has occurred within the last several thousand years. The rocks erupted from Tepetiltic form a chemically continuous suite which could have been derived through crystal fractionation of andesitic magma. No basic parental magmas, however, have erupted throughout the area.

  2. Neogene volcanism in Gutai Mts. (Eastern Carpathains: a review

    Directory of Open Access Journals (Sweden)

    Marinel Kovacs


    Full Text Available Two types of volcanism developed in Gutâi Mts. (inner volcanic chain of Eastern Carpathians: a felsic, extensional/“back-arc” type and an intermediate, arc type. The felsic volcanism of explosive origin, consisting of caldera-related rhyolitic ignimbrites and resedimented volcaniclastics, had taken place during Early-Middle Badenian and Early Sarmatian. The intermediate volcanism, consisting of extrusive (effusive and explosive and intrusive activity, had developed during Sarmatian and Pannonian (13.4-7.0 Ma. It is represented by typical calc-alkaline series, from basalts to rhyolites. Lava flows of basaltic andesites and andesites are predominant, often emplaced in subaqueous environment. Extrusive domes, mainly composed of dacites, are associated to the andesitic volcanic structures. The intermediate volcanism, consisting of extrusive (effusive and explosive and intrusive activity, had developed during Sarmatian and Pannonian (13.4-7.0 Ma. It is represented by typical calc-alkaline series, from basalts to rhyolites. Lava flows of basaltic andesites and andesites are predominant, often emplaced in subaqueous environment. Extrusive domes, mainly composed of dacites, are associated to the andesitic volcanic structures. The geochemical study on the volcanic rocks shows the calc-alkaline character of both felsic and intermediate volcanism and typical subduction zones geochemical signatures for the intermediate one. The felsic volcanism shows affinities with subduction-related rocks as well. The main petrogenetic process in Gutâi Mts. was crustal assimilation, strongly constrained by trace element and isotope geochemistry.

  3. Petrogenesis of Indosinian volcanic rocks in Songpan-Garze fold belt of the northeastern Tibetan Plateau:New evidence for lithospheric delamination

    Institute of Scientific and Technical Information of China (English)


    In the Songpan-Garze fold belt of the northeastern Tibetan Plateau, an Indosinian lithospheric delamination model has been proposed, based on previous investigation of widespread granitoids. However, this model lacks comparable information from volcanism in the area. During the Indosinian delamination in the Songpan-Garze fold belt, whether partial melting of litho- spheric mantle taken place is debated. This paper reports U-Pb zircon LA-ICP-MS ages, geochemical and Sr-Nd-Hf isotopic compositions from the Aba and Wasai calc-alkaline volcanic rocks in the central Songpan-Garze fold belt. Obtained magma crystallization ages are 210±3 Ma for the Aba andesite and 205±1 Ma for the Wasai andesite. These are consistent with magma crystallization ages of the late Indosinian granitoids in the Songpan-Garze fold belt that formed in a post-collisional tectonic setting. The Aba and Wasai andesites have distinct geochemical singnatures. The former has higher Al2O3, K2O, Rb but lower Na2O, Ba and Sr contents, suggesting differences in their magmatic evolution. The Aba andesites have ISr values of 0.7070-0.7076 and εNd(t) values of -3.9 to -5.3, and the Wasai andesites have ISr values of 0.7075-0.7077 and εNd(t) values of -3.6 to -3.9. Zircons show εHf(t) values of -3.7 to 0.3 for the Aba andesites and -2.7 to 5.5 for the Wasai andesites. Geochemical and Sr-Nd-Hf isotopic compositions indicate that fractional crystallization and crustal assimilation processes are not key roles for their magma evolution, implying that their chemical compositions are those of primary melts. We suggest that the magma of the Aba andesites originated predominantly from a crustal source, with a minor mantle-derived component. The source region of the magma was likely at the crust-mantle boundary. The magma of the Wasai andesites resulted from partial melting of lithospheric mantle, which was probably metasomatized by fluids so that it was amphibole bearing. The petrogenesis of the Aba and Wasai

  4. The generation of a diverse suite of Late Pleistocene and Holocene basalt through dacite lavas from the northern Cascade arc at Mount Baker, Washington (United States)

    Baggerman, Troy David; Debari, S. M.


    Mt. Baker is a dominantly andesitic stratovolcano in the northern Cascade arc. In this study, we show that the andesites are not all derived from similar sources, and that open-system processes were dominant during their petrogenesis. To this end, we discuss petrographic observations, mineral chemistry, and whole rock major and trace element chemistry for three of Mt. Baker's late Pleistocene to Holocene lava flow units. These include the basalt and basaltic andesite of Sulphur Creek (SC) (51.4-55.8 wt% SiO2, Mg# 57-58), the Mg-rich andesite of Glacier Creek (GC) (58.3-58.7 wt% SiO2, Mg# 63-64), and the andesite and dacite of Boulder Glacier (BG) (60.2-64.2 wt% SiO2, Mg# 50-57). Phenocryst populations in all units display varying degrees of reaction and disequilibrium textures along with complicated zoning patterns indicative of open-system processes. All lavas are medium-K and calc-alkaline, but each unit displays distinctive trace element and REE characteristics that do not correlate with the average SiO2 content of the unit. The mafic lavas of SC have relatively elevated REE abundances with the lowest (La/Yb)N (~4.5). The intermediate GC andesites (Mg- and Ni-rich) have the lowest REE abundances and the highest (La/Yb)N (~6.7) with strongly depleted HREE. The more felsic BG lavas have intermediate REE abundances and (La/Yb)N (~6.4). The high-Mg character of the GC andesites can be explained by addition of 4% of a xenocrystic olivine component. However, their depleted REE patterns are similar to other high-Mg andesites reported from Mt. Baker and require a distinct mantle source. The two dominantly andesitic units (GC and BG) are different enough from each other that they could not have been derived from the same parent basalt. Nor could either of them have been derived from the SC basalt by crystal fractionation processes. Crystal fractionation also cannot explain the compositional diversity within each unit. Compositional diversity within the SC unit (basalt to

  5. Experimental and textural constraints on mafic enclave formation in volcanic rocks (United States)

    Coombs, M.L.; Eichelberger, J.C.; Rutherford, M.J.


    We have used experiments and textural analysis to investigate the process of enclave formation during magma mixing at Southwest Trident volcano, Alaska. Andesite enclaves are present throughout the four dacite lava flows produced by the eruption, and resemble mafic enclaves commonly found in other volcanic rocks. Our experiments replicate the pressure-temperature-time path taken by enclave-forming andesite magma as it is engulfed in dacite during magma mixing. Pressure and temperature information for the andesite and dacite are from [Coombs et al., Contrib. Mineral. Petrol. 140 (2000) 99-118]. The andesite was annealed at 1000??C, and then cooled to 890??C at rates of 110??C h1, 10??C h1 and 2??C h1. Once cooled to 890??C, andesite was held at this lower temperature from times ranging from 1 to 40 h. The andesite that was cooled at the slower rates of 2??C h1 and 10??C h1 most resembles enclave groundmass texturally and compositionally. Based on simple thermal calculations, these rates are more consistent with cooling of the andesite groundmass below an andesite-dacite interface than with cooling of enclave-sized spheres. If enclaves do crystallize as spheres, post-crystallization disaggregation must occur. Calculations using the MELTS algorithm [Ghiorso and Sack, Contrib. Mineral. Petrol. 119 (1995) 197-212] show that for incoming andesite to become less dense than the dacite to become less dense ???34 volume % of its groundmass must crystallize to undergo~18 volume % vesiculation; these values are similar to those determined for Southwest Trident enclaves. Thus such crystallization may lead to 'flotation' of enclaves and be a viable mechanism for enclave formation and dispersal. The residual melt in the cooling experiments did not evolve to rhyolitic compositions such as seen in natural enclaves due to a lack of a decompression step in the experiments. Decompression experiments on Southwest Trident dacite suggest an average ascent rate for the eruption of ???2

  6. Post-Eocene volcanics of the Abazar district, Qazvin, Iran: Mineralogical and geochemical evidence for a complex magmatic evolution (United States)

    Asiabanha, A.; Bardintzeff, J. M.; Kananian, A.; Rahimi, G.


    The style of volcanism of post-Eocene volcanism in the Alborz zone of northern Iran is different to that of Eocene volcanism (Karaj Formation). Indeed, the volcanic succession of the Abazar district, located in a narrow volcanic strip within the Alborz magmatic assemblage, is characterized by distinct mineralogical and chemical compositions linked to a complex magmatic evolution. The succession was produced by explosive eruptions followed by effusive eruptions. Two main volcanic events are recognized: (1) a thin rhyolitic ignimbritic sheet underlain by a thicker lithic breccia, and (2) lava flows including shoshonite, latite, and andesite that overlie the first event across a reddish soil horizon. Plagioclase in shoshonite (An 48-92) shows normal zoning, whereas plagioclase in latite and andesite (An 48-75) has a similar composition but shows reverse and oscillatory zoning. QUILF temperature calculations for shoshonites and andesites yield temperatures of 1035 °C and 1029 °C, respectively. The geothermometers proposed by Ridolfi et al. (2010) and Holland and Blundy (1994) yield temperatures of 960 °C and 944 °C for latitic lava, respectively. The samples of volcanic rock show a typical geochemical signature of the continental arc regime, but the andesites clearly differ from the shoshonites, the latites and the rhyolites. The mineralogical and chemical characteristics of these rocks are explained by the following petrogenesis: (1) intrusion of a hot, mantle-depth mafic (shoshonitic) magma, which differentiated in the magma chamber to produce a latitic and then a rhyolitic liquid; (2) rhyolitic ignimbritic eruptions from the top of the magma chamber, following by shoshonitic and then latitic extrusions; (3) magma mingling between the latitic and andesitic magmas, as indicated by the occurrence of andesite clasts within the latite; and (4) andesitic effusions. The youngest volcanic events in the Alborz zone show a close chemical relationship with continental arc

  7. Extreme high field strength element (HFSE) depletion and near-chondritic Nb/Ta ratios in Central Andean adakite-like lavas (~ 28°S, ~ 68°W) (United States)

    Goss, A. R.; Kay, S. M.


    The eruption of andesites with steep REE patterns and high Sr concentrations (adakite-like) in the northernmost Chilean flatslab region of the Central Andes spatially and temporally corresponds with the appearance of a marked HFSE (high field strength element) depletion in these lavas (La/Ta up to 95). Known as the Dos Hermanos and Pircas Negras andesites, these lavas erupted at the beginning (˜ 8 Ma), during (7-3 Ma), and immediately following (3-2 Ma) a period of tectonic instability characterized by eastward migration of the frontal volcanic arc. ICP-MS analyses of the HFSE reveal a range of chondritic (20-18) to subchondritic (18-11) Nb/Ta ratios in these lavas. Evident temporal trace element trends support a change from a rutile-bearing to an amphibole-bearing eclogitic residual assemblage in equilibrium with the mafic precursor magmas of these andesites. This change in residual mineralogy is contemporaneous with the onset of frontal arc migration in the region. Potential eclogitic sources for the Dos Hermanos and Pircas Negras adakitic andesites include mafic Andean lower crust and an additional flux of forearc crust transported to the sub-arc mantle via subduction erosion during the height of arc migration and Pircas Negras magmatism. Batch melting models of rutile- or amphibole-bearing eclogitic arc basalt in tandem with magma mixing calculations generate the observed adakitic signatures and near-chondritic Nb/Ta ratios of these Central Andean andesites.

  8. Advent of Continents: A New Hypothesis (United States)

    Tamura, Yoshihiko; Sato, Takeshi; Fujiwara, Toshiya; Kodaira, Shuichi; Nichols, Alexander


    The straightforward but unexpected relationship presented here relates crustal thickness to magma type in the Izu-Ogasawara (Bonin) and Aleutian oceanic arcs. Volcanoes along the southern segment of the Izu-Ogasawara arc and the western Aleutian arc (west of Adak) are underlain by thin crust (10-20 km). In contrast those along the northern segment of the Izu-Ogasawara arc and eastern Aleutian arc are underlain by crust ~35 km thick. Interestingly, andesite magmas dominate eruptive products from the former volcanoes and mostly basaltic lavas erupt from the latter. According to the hypothesis presented here, rising mantle diapirs stall near the base of the oceanic crust at depths controlled by the thickness of the overlying crust. Where the crust is thin, melting occurs at relatively low pressures in the mantle wedge producing andesitic magmas. Where the crust is thick, melting pressures are higher and only basaltic magmas tend to be produced. The implications of this hypothesis are: (1) the rate of continental crust accumulation, which is andesitic in composition, would have been greatest soon after subduction initiated on Earth, when most crust was thin; and (2) most andesite magmas erupted on continental crust could be recycled from “primary” andesite originally produced in oceanic arcs.

  9. Petrology and geochemistry of igneous inclusions in recent Merapi deposits

    DEFF Research Database (Denmark)

    Chadwick, J.P.; Troll, V.R.; Waight, Tod Earle;


    with compositions of minerals in recent and historic basaltic-andesites and the enclaves they contain, indicating a cognate or ‘antelithic’ nature for most of the plutonic inclusions. Many of the plutonic inclusions plot together with the host basaltic andesites along fractional crystallisation trends from parental...... basalt to andesite compositions. Results for mineral geobarometry on the inclusions suggest a crystallisation history for the plutonic inclusions and the recent and historic Merapi magmas that spans the full depth of the crust, indicating a multi-chamber magma system with high amounts of semi......-molten crystalline mush. There, crystallisation, crystal accumulation, magma mixing and mafic recharge take place. Comparison of the barometric results with whole rock Sr, Nd, and Pb isotope data for the inclusions suggests input of crustal material as magma ascends from depth, with a significant late addition...

  10. Composition of plagioclases in volcanic rocks of King George Island, Antarctica with reference to the petrogenetic significance

    Institute of Scientific and Technical Information of China (English)


    Plagioclases occur mainly as phenocrysts in volcanic rocks of King George Island, South Shetland Islands, West Antarctica. In basaltic andesites and andesites of Keller Peninsula and Ullman Spur (Admiralty Bay), they are high structure state labradorite-andesines; and in high-A1 basalts and basaltic andesites of Barton and Weaver peninsulas (Maxwell Bay), they are high structure state bytownite-anorthites.∑REE, La/Yb ratios and δEu values of plagioclases from Admiralty Bay are higher than those from Maxwell Bay. All plagioclases have rather identical chondritenormalized transitional element distribution patterns, probably reflecting that crystal structure rather than composition of plagioclase controls their diversity. Compositions of plagioclases depend chiefly on those of their host rocks, compositional differences of plagioclases reveal that basaltic magmas in the Admiralty Bay area are more evolved than in the Maxwell Bay area.

  11. Deducing the magma chamber processes of middle Eocene volcanics, Sivas and Tokat regions; NE Turkey: Insights from clinopyroxene chemistry (United States)

    Göçmengil, Gönenç; Karacık, Zekiye; Genç, Ş. Can; Prelevic, Dejan


    Middle Eocene Tokat and Sivas volcanic successions occur within the İzmir-Ankara-Erzincan suture zone. Different models are suggested for the development of the middle Eocene volcanism such as post-collisional, delamination and slab-breakoff models as well as the arc magmatism. In both areas, volcanic units cover all the basement units with a regional disconformity and comprise lavas spanning a compositional range from mainly basalt-basaltic andesite to a lesser amount trachyte. Here, we report mineral chemistry of different basaltic lavas through transect from northern continent (Tokat region, Pontides) to southern continent (Sivas region, Kırşehir block) to deduce the characteristics of the magma chamber processes which are active during the middle Eocene. Basaltic lavas include olivine bearing basalts (Ol-basalt: ± olivine + clinopyroxene + plagioclase); amphibole bearing basaltic andesite (Amp-basaltic andesite: amphibole + clinopyroxene + plagioclase ± biotite) and pyroxene bearing basaltic andesite (Px-basaltic andesite: clinopyroxene + plagioclase). Microlitic, glomeroporphyric and pilotaxitic texture are common. Clinopyroxene phenocrystals (macro ≥ 750 μm and micro ≤300 μm) are common in all three lava series which are investigated by transecting core to rim compositional profiles. They are generally augite and diopside; euhedral to subhedral in shape with oscillatory, normal and reverse zoning patterns. Also, all clinopyroxene phenocrystals are marked by moderately high Mg# (for Ol-basalt: 67-91; avg. 80; Amp-basaltic andesite: 76-83, avg: 80; Px -basaltic andesite 68-95, avg: 81). In Ol-basalt, clinopyroxene phenocrystals show normal zonation (high Mg# cores and low Mg# rims). In Amp-basaltic andesite, clinopyroxenes are generally homogenous in composition with minor variation of Mg# towards the rims. On the contrary, in Px-basaltic andesite, clinopyroxene macro phenocrystals show reverse zonation with the core with low Mg# and the rims with

  12. Reconnaissance geology of the Al Ba'ayith quadrangle, sheet 26/41 D, Kingdom of Saudi Arabia (United States)

    Williams, P.L.; Simonds, F.W.; Turner, J.D.


    The Al Ba'ayith quadrangle, located in the northeastern part of the Arabian Shield, is underlain by upper Proterozoic intrusive rocks and volcanogenic layered sequences bounded by unconformities. The oldest rocks are silicic volcanic rocks of the Banana formation that is tentatively assigned to the Hulayfah group. Successively younger layered rocks are the Maraghan formation of the Murdama group, consisting of lithic graywacke, siltstone, and shale; the Hibshi formation, coarse-grained lithic sandstone and conglomerate; the Sufran formation, dacitic and andesitic lava flows and ash-flow tuffs; the Jurdhawiyah formation, andesitic flows and agglomerate, and conglomeratic sandstone; and the Hadn formation, rhyolite flows and ash-flow tuffs, conglomerate, sandstone, and andesite flows.

  13. Late Holocene hydrous mafic magmatism at the Paint Pot Crater and Callahan flows, Medicine Lake Volcano, N. California and the influence of H2O in the generation of silicic magmas (United States)

    Kinzler, R.J.; Donnelly-Nolan, J. M.; Grove, T.L.


    This paper characterizes late Holocene basalts and basaltic andesites at Medicine Lake volcano that contain high pre-eruptive H2O contents inherited from a subduction related hydrous component in the mantle. The basaltic andesite of Paint Pot Crater and the compositionally zoned basaltic to andesitic lavas of the Callahan flow erupted approximately 1000 14C years Before Present (14C years B.P.). Petrologic, geochemical and isotopic evidence indicates that this late Holocene mafic magmatism was characterized by H2O contents of 3 to 6 wt% H2O and elevated abundances of large ion lithophile elements (LILE). These hydrous mafic inputs contrast with the preceding episodes of mafic magmatism (from 10,600 to ~3000 14C years B.P.) that was characterized by the eruption of primitive high alumina olivine tholeiite (HAOT) with low H2O (Mg silicates and the suppression of plagioclase as an early crystallizing phase. In addition, H2O lowers the saturation temperature of Fe and Mg silicates, and brings the temperature of oxide crystallization closer to the liquidus. These combined effects generate SiO2-enrichment that leads to rhyodacitic differentiated lavas. In contrast, low H2O HAOT magmas at Medicine Lake differentiate to iron-rich basaltic liquids. When these Fe-enriched basalts mix with melted granitic crust, the result is an andesitic magma. Since mid-Holocene time, mafic volcanism has been dominated primarily by hydrous basaltic andesite and andesite at Medicine Lake Volcano. However, during the late Holocene, H2O-poor mafic magmas continued to be erupted along with hydrous mafic magmas, although in significantly smaller volumes.

  14. ニュージーランド北島, オハクネ火口産高マグネシア質安山岩と同質デイサイト(鮫島輝彦先生追悼論文集)



    The Ohakune crater is one of the parasitic vents around Ruapehu volcano. Olivine andesite and bronzite dacite occur in and around the crater, the eruption of which took place explosively on the flat laharic plain surrounding Ruapehu volcano. The Ohakune crater rocks ' contain some phenocrysts of Mg-rich olivine (Fo88) or orthopyroxene (En89) , indicating their derivation from the mantle peridotite. The olivine andesites have high contents of MgO (7.3-6.6%) and SiO_2 (55.5-57.4%), similar to m...

  15. The Origin of ‘OIB-Type’ Magmas in the Central Mexican Volcanic Belt (United States)

    Straub, S. M.; Gomez-Tuena, A.; Zellmer, G. F.; Cai, Y.; Stuart, F. M.; Espinasa-Perena, R.; Langmuir, C. H.; Goldstein, S. L.


    Many models consider a primary mantle origin of high-Mg andesites, but the subarc mantle of arcs producing high-Mg andesites remains poorly defined. In the monogenetic volcanic field of Sierra Chichinautzin (central Mexican Volcanic Belt), high-Mg andesites are spatially and temporally intimately associated with mildly alkaline basalts and basaltic andesites, variously referred to as ‘OIB-type’, ‘intraplate’ or ‘high-Nb arc basalts’ (Wallace and Carmichael 1999, Contrib Mineral Petrol; Schaaf et al. 2005, J Petrol). ‘OIB-type’ magmas and high-Mg andesites have erupted within a few hundreds to thousands of years from vents only a few kilometers apart, or may even have erupted jointly from single vents. It has been suggested that these ‘OIB-type’ magmas were melts from subarc mantle yet unmodified by subduction fluxes while high-Mg andesites were produced from mantle sources residual to the ‘OIB-type’ magmas. In order to test this model, we investigated ‘OIB-type’ magmas erupting from three young and closely spaced monogenetic volcanoes in the Sierra Chichinautzin Volcanic Field (V. Chichinautzin, V. Suchiooc, Cuescomates vent). The primitive olivine-phyric alkaline basalts and basaltic andesites (SiO2 = 49.6-53.5 wt%; Mg#=62-68 and MgO= 6.5-8.3 wt%) have high Ni (97-179 ppm), Nb (18-34 ppm), Nb/La (0.9-1.2) and 3He/4He ratios (R/Ra = 7.3-8.0) typical of near-primary mantle magmas unaffected by the passage through the ~47 km thick continental crust. However, all ‘OIB-type’ magmas contain high-Ni olivines that are indicative of siliceous slab melts infiltrating and reacting with peridotite mantle (Straub et al., 2008, G-cubed; Wang & Gaetani 2008, Contrib Mineral Petrol). Significant slab additions to the mantle source of the ‘OIB-type’ magmas are further confirmed by Sr-Nd-Pb systematics. We suggest that ‘OIB-type’ arc magmas reflect fertilization of a pre-existing MORB-type subarc mantle by enriched, little fractionated slab

  16. Magma mixing during the 2010 Eyjafjallajökull eruption (United States)

    Portnyagin, M.; Borisova, A. Y.; Plechov, P.; Shkurski, B.; Stefansson, A.


    We performed detailed study of matrix glasses, olivines and melt inclusions in 6 samples of tephras of the 2010 Eyjafjallajökull eruption. Tephras erupted during the early basaltic stage (March 20 - April 13) are very homogeneous with respect to matrix glass compositions and host assemblage of primitive phenocrysts (olivine Fo75-87, Cr-spinel Cr# = 0.14 - 0.55). The olivines have normal or rhythmic zoning which suggests multiple episodes of mixing with more primitive magmas and crystallization before eruption. Glasses of the initial andesitic stage (April 14 - 30) fall into three groups: basaltic (group 2a, andesitic (group 2b, >80% ) and dacitic (group 2c, andesitic stage (May 1 - 22, group 3) have exclusively andesitic composition, slightly more primitive than on the early stage. The compositions of olivine cores and Cr-spinel inclusions in olivine in the late stage andesites are identical to those in basalts and suggest injection of basaltic magma into silicic magma shortly before eruption of andesite. The composition of shallow magma reservoir before the 2010 eruption could have composition similar to the group 2c glasses. A remarkable peculiarity of silicic Eyjafjallajökull glasses is high Cl (0.2-0.45 wt%) and high Cl/K2O (0.07-0.13) which are higher compared to basaltic glasses and primitive inclusions in olivine (Cl=0.02-0.09 wt%, Cl/K2O=0.04-0.09). The Cl enrichment in silicic Eyjafjallajökull melts may be an indicator of assimilation of crustal rocks altered via interaction with Cl-rich surface or oceanic waters. To estimate the residence time of basaltic xenocrysts in andesitic magma erupted on May 11, we measured compositional profiles in olivine xenocrysts and calculated the time required to form such a zoning via Fe-Mg diffusion. Orientation of the studied olivine sections has been determined with universal table and verified by comparing the facet angles with the ideal olivine crystal shape. Our modeling indicates that the high-Mg olivine


    Directory of Open Access Journals (Sweden)

    Dragomir Jovičić


    Full Text Available Andesite agregate, due to its suitable physical-mechanical properties, is known on market primarily of asphalt mixtures production for wear covers of roads, regardles to traffic intensity and impedance. The economic importance of the andesite Fužinski Benkovac (Gorski kotar is presented on the basis of the geological, genetic, technical-exploitable, technological, regional, marketing, and social-economic factors. Petrographic structure and tectonic fabric of the deposit have been separately elaborated. On the basis of these researches, quality, hydro-geological characteristics, natural and factors of evaluation, the deposit is economically evaluated as prosperous (the paper is published in Croatian.

  18. Melting of a subduction-modified mantle source: A case study from the Archean Marda Volcanic Complex, central Yilgarn Craton, Western Australia (United States)

    Morris, P. A.; Kirkland, C. L.


    Subduction processes on early earth are controversial, with some suggestions that tectonics did not operate until the earth cooled to a sufficient point around the Archean-Proterozoic boundary. One way of addressing this issue is to examine well-preserved successions of Archean supracrustal rocks. Here we discuss petrography, whole-rock chemical and isotopic data combined with zircon Hf isotopes from andesites, high-magnesium andesites (HMA), dacites, high-magnesium dacites (HMD), rhyolites and coeval felsic intrusive rocks of the c. 2730 Ma Marda Volcanic Complex (MVC) in the central Yilgarn Craton of Western Australia. We demonstrate that these rocks result from melting of a metasomatized mantle source, followed by fractional crystallization in a crustal magma chamber. Contamination of komatiite by Archean crust, to produce the Marda Volcanic Complex andesites, is not feasible, as most of these crustal sources are too radiogenic to act as viable contaminants. The ɛNd(2730) of MVC andesites can be produced by mixing 10% Narryer semi-pelite with komatiite, consistent with modelling using Hf isotopes, but to achieve the required trace element concentrations, the mixture needs to be melted by about 25%. The most likely scenario is the modification of a mantle wedge above a subducting plate, coeval with partial melting, producing volcanic rocks with subduction signatures and variable Mg, Cr and Ni contents. Subsequent fractionation of cognate phases can account for the chemistry of dacites and rhyolites.

  19. Nematodes from rocky grassland in Börzsöny Mountains, Hungary


    Kiss, M


    This paper reports on investigations carried out on soil inhabiting nematodes living in andesitic rock regions ofBörzsöny Mountains. Seventeen species are listed. Heterodorus arcuatus (Thorne, 1939), new to the fauna of Hungary, isdescribed and illustrated in detail.

  20. Nematodes from rocky grassland in Börzsöny Mountains, Hungary

    Directory of Open Access Journals (Sweden)

    Kiss, M.


    Full Text Available This paper reports on investigations carried out on soil inhabiting nematodes living in andesitic rock regions ofBörzsöny Mountains. Seventeen species are listed. Heterodorus arcuatus (Thorne, 1939, new to the fauna of Hungary, isdescribed and illustrated in detail.

  1. Mass budget partitioning during explosive eruptions: insights from the 2006 paroxysm of Tungurahua volcano, Ecuador (United States)

    Bernard, Julien; Eychenne, Julia; Le Pennec, Jean-Luc; Narváez, Diego


    How and how much the mass of juvenile magma is split between vent-derived tephra, PDC deposits and lavas (i.e., mass partition) is related to eruption dynamics and style. Estimating such mass partitioning budgets may reveal important for hazard evaluation purposes. We calculated the volume of each product emplaced during the August 2006 paroxysmal eruption of Tungurahua volcano (Ecuador) and converted it into masses using high-resolution grainsize, componentry and density data. This data set is one of the first complete descriptions of mass partitioning associated with a VEI 3 andesitic event. The scoria fall deposit, near-vent agglutinate and lava flow include 28, 16 and 12 wt. % of the erupted juvenile mass, respectively. Much (44 wt. %) of the juvenile material fed Pyroclastic Density Currents (i.e., dense flows, dilute surges and co-PDC plumes), highlighting that tephra fall deposits do not depict adequately the size and fragmentation processes of moderate PDC-forming event. The main parameters controlling the mass partitioning are the type of magmatic fragmentation, conditions of magma ascent, and crater area topography. Comparisons of our data set with other PDC-forming eruptions of different style and magma composition suggest that moderate andesitic eruptions are more prone to produce PDCs, in proportions, than any other eruption type. This finding may be explained by the relatively low magmatic fragmentation efficiency of moderate andesitic eruptions. These mass partitioning data reveal important trends that may be critical for hazard assessment, notably at frequently active andesitic edifices.

  2. Carbonate assimilation at Merapi volcano, Java Indonesia

    DEFF Research Database (Denmark)

    Chadwick, J.P; Troll, V.R; Ginibre,, C.


    Recent basaltic andesite lavas from Merapi volcano contain abundant, complexly zoned, plagioclase phenocrysts, analysed here for their petrographic textures, major element composition and Sr isotope composition. Anorthite (An) content in individual crystals can vary by as much as 55 mol% (An40^95...

  3. Preliminary Assessment/Site Inspection Work Plan for Granite Mountain Radio Relay System (United States)


    Installation Restoration Program IRPIMS Installation Restoration Program Information Management System Jacobs Jacobs Engineering Group Inc. mg ...station; * water supply building; * two 30-foot high disk antennas; * four 60-foot high tropospheric antennas; * two fuel oil storage tanks; and...a predominant surface feature around the peak of Granite Mountain. This pluton is surrounded by an andesitic volcanic unit of early Cretaceous age

  4. The rotation of Spain: Palaeomagnetic evidence from the Spanish meseta

    NARCIS (Netherlands)

    Voo, R. van der


    The magnetic properties of 39 oriented samples of Triassic siltstones and of 43 oriented samples of Silurian andesites and basalts from the Spanish Meseta were investigated. After a.c. magnetic field demagnetization up to 3,000 Oe, peak value, and after correction for the dip of the geological stra

  5. Eruption of a major Holocene pyroclastic flow at Citlaltépetl volcano (Pico de Orizaba), México, 8.5 9.0 ka (United States)

    Carrasco-Núñez, Gerardo; Rose, William I.


    Multiple volcanic eruptions occurred between 8500 and 9000 yr. B.P. from the central crater of Citlaltépetl Volcano generating a series of pyroclastic flows that formed a deposit with a total volume of about 0.26 km 3 (D.R.E.). The flows descended in all directions around the crater, but they were mostly controlled by topography and deposited in valleys or local topographic depressions up to about 30 km from vent. Although the flows were apparently emplaced without much violence, some features of the deposits reveal local turbulent conditions and an expanded fluidization that can be related to moderate flow velocities. The deposit has two members: the lower one consists of multiple flow units, and the upper one includes a single flow unit and a thin basal pumice-fall. Both members are lithologically similar and dominated by dense, andesitic scoriae with minor amounts of different pumice types (andesitic, dacitic, and banded), and lithics in a silty matrix. The eruption probably had a low-pressure 'boiling-over' mechanism and was possibly triggered by mixing of dacitic and andesitic magmas. Juvenile material in the pyroclastic-flow deposit is compositionally similar to that of Holocene lava flows at Citlaltépetl, which have apparently resulted from magma homogenization of mafic and silicic end members. Because the system is continuously injected with new basaltic-andesitic magma, a recurrence of explosive activity is possible in future eruptions.

  6. Stratigraphy, petrology, and geochemistry of the Spurr Volcanic Complex, eastern Aleutian Arc, Alaska. [(Appendix for geothermal fluid chemistry)

    Energy Technology Data Exchange (ETDEWEB)

    Nye, C.J.


    The Spurr Volcanic Complex (SVC) is a calcalkaline, medium-K, sequence of andesites erupted over the last quarter of a million years by the easternmost currently active volcanic center in the Aleutian Arc. The ancestral Mt. Spurr was built mostly of andesites of uniform composition (58 to 60% SiO/sub 2/), although andesite production was episodically interrupted by the introduction of new batches of more mafic magma. Near the end of the Pleistocene the ancestral Mt. Spurr underwent Bezyianny-type avalanche caldera formation, resulting in the production of a volcanic debris avalanche with overlying ashflows. Immediately afterward, a large dome (the present Mt. Spurr) was emplaced in the caldera. Both the ashflows and dome are made of acid andesite more silicic than any analyzed lavas from the ancestral Mt. Spurr (60 to 63% SiO/sub 2/), yet contain olivine and amphibole xenocrysts derived from more mafic magma. The mafic magma (53 to 57% SiO/sub 2/) erupted during and after dome emplacement, forming proto-Crater Peak and Crater Peak. Hybrid pyroclastic flows and lavas were also produced. Proto-Crater Peak underwent glacial dissection prior to the formation of Crater Peak in approximately the same location. Appendices II through VIII contain a summary of mineral compositions; Appendix I contains geochemical data. Appendix IX by R.J. Motyka and C.J. Nye describes the chemistry of geothermal fluids. 78 refs., 16 figs., 3 tabs.

  7. The Odivelas gabbro complex (Alentejo, Portugal): a Hercynian synorogenic layered intrusion

    NARCIS (Netherlands)

    Soares de Andrade, A.A.; Vieira, Conceição L.


    The ultramafic-mafic zone of the Hercynian Beja Massif includes 1) the Quintos amphibolite-diorite-serpentinite Complex, 2) the Odivelas layered gabbro Complex, and 3) the Peroguarda (meta) basalt-andesite Complex. The rhythmic and cryptic zoning of the Odivelas Complex is described, as well as its

  8. Geologic and preliminary reservoir data on the Los Humeros Geothermal System, Puebla, Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Ferriz, H.


    Exploratory drilling has confirmed the existence of a geothermal system in the Los Humeros volcanic center, located 180 km east of Mexico City. Volcanic activity in the area began with the eruption of andesites, followed by two major caldera-forming pyroclastic eruptions. The younger Los Potreros caldera is nested inside the older Los Humeros caldera. At later stages, basaltic andesite, dacite, and olivine basalt lavas erupted along the ring-fracture zones of both calderas. Geologic interpretation of structural, geophysical, and drilling data suggests that: (1) the water-dominated geothermal reservoir is hosted by the earliest andesitic volcanic pile, is bounded by the ring-fracture zone of the Los Potreros caldera, and is capped by the products of the oldest caldera-forming eruption; (2) permeability within the andesitic pile is provided by faults and fractures related to intracaldera uplift; (3) the geothermal system has potential for a large influx of meteoric water through portions of the ring-fracture zones of both calderas; and (4) volcanic centers with similar magmatic and structural conditions can be found in the eastern Cascades, USA.

  9. Groundwater Treatment Study for South Plants and Basin a Neck, Task 26 (United States)


    andesites and volcaniclastic sediments may be volcanic sources from as far away as Salida (Epis & others, 1976). Alternatively, volcanic flows may have... California , 1981). However, heavy metals and other wastes high in inorganics are unlikely to be destroyed. Frequently, these incinerators require

  10. Origin of lead in andean calc-alkaline lavas, southern peru. (United States)

    Tilton, G R; Barreiro, B A


    Lead isotope data from Quaternary andesitic lavas of the Arequipa and Barroso groups of southern Peru and from regional Precambrian granulitic gneisses reveal a lead component in the lavas from the gneisses. The lava leads can be accounted for by two-component mixtures of lead from mantle and lower crustal sources, although the mixing process need not have occurred in the lower crust.

  11. 76 FR 30060 - Proposed Establishment of the Naches Heights Viticultural Area (2009R-107P) (United States)


    ... that of the Naches Heights. Soils After the volcanic flow of andesite cooled and hardened to form the... water table close to the surface of the soil, according to NRCS data. In addition, the valley vines have shallow rooting depths that can reach the water table and be frozen during extreme cold weather....

  12. 76 FR 77696 - Establishment of the Naches Heights Viticultural Area (United States)


    ... vineyards on the Naches Heights. Soils After the volcanic flow of andesite cooled and hardened to form the..., including the Weirman, Wenas, and Kittitas series, are subject to seasonal flooding and a water table close... rooting depths that can reach the water table and be frozen during extreme cold weather. Further,...

  13. The End of Sluiter’s Coral Reef at Krakatoa

    NARCIS (Netherlands)

    Umbgrove, J.H.F.


    It is well known that before the famous eruption of August 1883 took place, the island Krakatoa consisted of three volcanoes, the basaltic volcano Rakata and the andesitic volcanoes Danan and Perbuwatan. With the great explosion of August 28th of that year Danan, Perbuwatan and the northwestern part

  14. Geochronology and magmatic evolution of the Dieng Volcanic Complex, Central Java, Indonesia and their relationships to geothermal resources (United States)

    Harijoko, Agung; Uruma, Ryusuke; Wibowo, Haryo Edi; Setijadji, Lucas Doni; Imai, Akira; Yonezu, Kotaro; Watanabe, Koichiro


    We analyzed new radiometric dating and petrological data of DVC in an attempt to reconstruct volcanic history as groundwork to understand magmatic temporal and spatial evolution. The magma of DVC can be divided on the basis of mineral composition into three types: olivine bearing basalt-basaltic andesite, pyroxene basaltic andesite-andesite, and biotite andesite-dacite, which coincide with three volcanic episodes of DVC: pre-caldera, second, and youngest episode, respectively. The pre-caldera episode was active no later than 1 Ma, the second episode occurred between 0.3 and 0.4 Ma, and the youngest occurred after 0.27 Ma. Plots of CaO, K2O, Al2O3, and Rb/Sr against FeO*/MgO and/or MgO suggest that each volcanic episode has distinct differentiation trends, indicating the presence of multiple shallow magma chambers. The close spatial relationship between the geothermal manifestation, geophysical anomalies, geothermal production zones and volcanic edifices supports the presence of multiple shallow magma chambers beneath DVC, which act as a heat source for the existing geothermal system.

  15. Geology and stratigraphy of the Challis Volcanic Group and related rocks, Little Wood River area, south-central Idaho (United States)

    Sandford, Richard F.; Snee, Lawrence W.


    The southwestern part of the Challis volcanic field occupies the valley of the Little Wood River and its tributaries in the Hailey and Idaho Falls 1??2? quadrangles of south-central Idaho. The Little Wood River area is a structurally controlled topographic basin that is partly filled by Eocene Challis Volcanic Group and younger rocks. Rock types in the Challis Volcanic Group of the Little Wood River area include, in order of decreasing abundance, andesite lava flows and tuff breccia, dacite lava flows and flow breccia, volcaniclastic sedimentary rocks, lithic tuff, nonvolcanic conglomerate, and rhyolite dikes. A basal nonvolcanic conglomerate, that locally rests on upper Paleozoic sedimentary rocks at a regional unconformity, was deposited prior to eruption of volcanic rocks. Andesite was the first volcanic rock erupted and is a voluminous sequence as thick as 3,000 ft (1,000 m). Locally thick volcaniclastic sedimentary rocks accumulated in topographic lows. A sharp transition marks the beginning of dacite eruption from fissures and flow-dome complexes. Dacite flows and breccias are as thick as 2,000 ft (600 m). An upper volcaniclastic unit was deposited in paleotopographic lows following emplacement of the main dacite unit. Next, a widespread, distinctive, lithic rich ash flow tuff, correlated with the tuff of Stoddard Gulch, was deposited over much of the area. Deposition of the tuff was followed by eruption of thin andesite and dacite lava flows and deposition of conglomeratic sedimentary rocks. The entire sequence was then intruded by a dacite flow-dome complex composed of at least three separate intrusions. The Challis Volcanic Group in the study area is calcalkaline. Andesitic rocks are typically high potassium basaltic andesite, high potassium andesite, shoshonite, and banakite (latite). Dacitic rocks are high potassium dacite and trachyte. Tuffs and vitrophyres range in composition from basaltic andesite to trachyte. The paleotopographic basin in which the

  16. Petrogenesis of gold-mineralized magmatic rocks of the Taerbieke area, northwestern Tianshan (western China): Constraints from geochronology, geochemistry and Sr-Nd-Pb-Hf isotopic compositions (United States)

    Tang, Gong-Jian; Wang, Qiang; Wyman, Derek A.; Sun, Min; Zhao, Zhen-Hua; Jiang, Zi-Qi


    Many Late Paleozoic Cu-Au-Mo deposits occur in the Central Asian Orogenic Belt (CAOB). However, their tectonic settings and associated geodynamic processes have been disputed. This study provides age, petrologic and geochemical data for andesites and granitic porphyries of the Taerbieke gold deposit from the Tulasu Basin, in the northwestern Tianshan Orogenic Belt (western China). LA-ICP-MS zircon U-Pb dating indicates that the granitic porphyries have an Early Carboniferous crystallization age (349 ± 2 Ma) that is broadly contemporaneous with the eruption age (347 ± 2 Ma) of the andesites. The andesites have a restricted range of SiO2 (58.94-63.85 wt.%) contents, but relatively high Al2O3 (15.39-16.65 wt.%) and MgO (2.51-6.59 wt.%) contents, coupled with high Mg# (57-69) values. Geochemically, they are comparable to Cenozoic sanukites in the Setouchi Volcanic Belt, SW Japan. Compared with the andesites, the granitic porphyries have relatively high SiO2 (72.68-75.32 wt.%) contents, but lower Al2O3 (12.94-13.84 wt.%) and MgO (0.10-0.33 wt.%) contents, coupled with lower Mg# (9-21) values. The andesites and granitic porphyries are enriched in both large ion lithophile and light rare earth elements, but depleted in high field strength elements, similar to those of typical arc magmatic rocks. They also have similar Nd-Hf-Pb isotope compositions: ɛNd(t) (+0.48 to +4.06 and -0.27 to +2.97) and zircons ɛHf(t) (+3.4 to +8.0 and -1.7 to +8.2) values and high (206Pb/204Pb)i (18.066-18.158 and 17.998-18.055). We suggest that the Taerbieke high-Mg andesitic magmas were generated by the interaction between mantle wedge peridotites and subducted oceanic sediment-derived melts with minor basaltic oceanic crust-derived melts, and that the magmas then fractionated to produce the more felsic members (i.e., the Taerbieke granitic porphyries) during late-stage evolution. Taking into account the Carboniferous magmatic record from the western Tianshan Orogenic Belt, we suggest that

  17. Formation of redox gradients during magma-magma mixing (United States)

    Ruprecht, P.; Fiege, A.; Simon, A. C.


    Magma-mixing is a key process that controls mass transfer in magmatic systems. The variations in melt compositions near the magma-magma interface potentially change the Fe oxidation state [1] and, thus, affect the solubility and transport of metals. To test this hypothesis, diffusion-couple experiments were performed at 1000 °C, 150 MPa and QFM+4. Synthesized crystal-bearing cylinders of hydrous dacite and hydrous basaltic andesite were equilibrated for up to 80 h. The run products show that mafic components (Fe, Mg, etc.) were transported from the andesite into the dacite, while Si, Na and K diffused from the dacite into the andesite. A crystal dissolution sequence in the order of cpx, opx, plag, and spl/il was observed for the andesite. We combined μ-XANES spectroscopy at Fe K-edge [2] with two-oxide oxybarometry [3] to measure redox profiles within our experiments. Here, fO2 decreased towards the interface within the dacite and increased towards the interface within the andesite. This discontinuous fO2 evolution, with a sharp redox gradient of ~1.8 log fO2 units at the interface was maintained throughout the time-series despite the externally imposed fO2 of the vessel. We propose a combination of two mechanisms that create and sustain this redox gradient: 1) The dissolution of cpx and opx in the andesite mainly introduced Fe2+ into the melt, which diffused towards the dacite, lowering Fe3+/SFe near the interface. 2) Charge balance calculations in the melt during diffusive exchange suggest net positive charge excess in the andesite near the interface (i.e., oxidation) and net negative charge excess in the dacite near the interface (i.e., reduction). We suggest that this (metastable) redox layer can help to explain the contrasting Au/Cu ratios observed for arc-related porphyry-type ore deposits. [1] Moretti (2005), Ann. Geophys. 48, 583-608. [2] Cottrell et al. (2009), Chem. Geol. 268, 167-179. [3] Ghiorso and Evans (2008), Am. J. Sci. 308, 957-1039.

  18. New insights into the initiation and venting of the Bronze-Age eruption of Santorini (Greece), from component analysis (United States)

    Druitt, T. H.


    The late-seventeenth century BC Minoan eruption of Santorini discharged 30-60 km3 of magma, and caldera collapse deepened and widened the existing 22 ka caldera. A study of juvenile, cognate, and accidental components in the eruption products provides new constraints on vent development during the five eruptive phases, and on the processes that initiated the eruption. The eruption began with subplinian (phase 0) and plinian (phase 1) phases from a vent on a NE-SW fault line that bisects the volcanic field. During phase 1, the magma fragmentation level dropped from the surface to the level of subvolcanic basement and magmatic intrusions. The fragmentation level shallowed again, and the vent migrated northwards (during phase 2) into the flooded 22 ka caldera. The eruption then became strongly phreatomagmatic and discharged low-temperature ignimbrite containing abundant fragments of post-22 ka, pre-Minoan intracaldera lavas (phase 3). Phase 4 discharged hot, fluidized pyroclastic flows from subaerial vents and constructed three main ignimbrite fans (northwestern, eastern, and southern) around the volcano. The first phase-4 flows were discharged from a vent, or vents, in the northern half of the volcanic field, and laid down lithic-block-rich ignimbrite and lag breccias across much of the NW fan. About a tenth of the lithic debris in these flows was subvolcanic basement. New subaerial vents then opened up, probably across much of the volcanic field, and finer-grained ignimbrite was discharged to form the E and S fans. If major caldera collapse took place during the eruption, it probably occurred during phase 4. Three juvenile components were discharged during the eruption—a volumetrically dominant rhyodacitic pumice and two andesitic components: microphenocryst-rich andesitic pumices and quenched andesitic enclaves. The microphenocryst-rich pumices form a textural, mineralogical, chemical, and thermal continuum with co-erupted hornblende diorite nodules, and together

  19. Miocene and early Pliocene epithermal gold-silver deposits in the northern Great Basin, western United States: Characteristics, distribution, and relationship to Magmatism (United States)

    John, D.A.


    Numerous important Miocene and early Pliocene epithermal Au-Ag deposits are present in the northern Great Basin. Most deposits are spatially and temporally related to two magmatic assemblages: bimodal basalt-rhyolite and western andesite. These magmatic assemblages are petrogenetic suites that reflect variations in tectonic environment of magma generation. The bimodal assemblage is a K-rich tholeiitic series formed during continental rifting. Rocks in the bimodal assemblage consist mostly of basalt to andesite and rhyolite compositions that generally contain anhydrous and reduced mineral assemblages (e.g., quartz + fayalite rhyolites). Eruptive forms include mafic lava flows, dikes, cinder and/or spatter cones, shield volcanoes, silicic flows, domes, and ash-flow calderas. Fe-Ti oxide barometry indicates oxygen fugacities between the magnetite-wustite and fayalite-magnetite-quartz oxygen buffers for this magmatic assemblage. The western andesite assemblage is a high K calc-alkaline series that formed a continental-margin are related to subduction of oceanic crust beneath the western coast of North America. In the northern Great Basin, most of the western andesite assemblage was erupted in the Walker Lane belt, a zone of transtension and strike-slip faulting. The western andesite assemblage consists of stratovolcanoes, dome fields, and subvolcanic plutons, mostly of andesite and dacite composition. Biotite and hornblende phenocrysts are abundant in these rocks. Oxygen fugacities of the western andesite assemblage magmas were between the nickel-nickel oxide and hematite-magnetite buffers, about two to four orders of magnitude greater than magmas of the bimodal assemblage. Numerous low-sulfidation Au-Ag deposits in the bimodal assemblage include deposits in the Midas (Ken Snyder), Sleeper, DeLamar, Mule Canyon, Buckhorn, National, Hog Ranch, Ivanhoe, and Jarbidge districts; high-sulfidation gold and porphyry copper-gold deposits are absent. Both high- and low

  20. 39Ar/40Ar Chronology and Volumes of Eruptive Products Over the Last 1 Myr in the Tequila Volcanic Field, Jalisco, Mexico (United States)

    Lewis-Kenedi, C. B.; Lange, R. A.; Hall, C. M.; Delgado-Granados, H.


    The Tequila volcanic field, located within the western Trans-Mexican arc, covers an area of 1036 km2 and includes a central, andesitic stratocone, Volc\\­_{a}n Tequila, as well as cinder cones, domes, and fissure-fed flows. Sixty-nine high precision 39Ar-40Ar dates reveal that major activity in the Tequila volcanic field began at approximately 1 Ma. From 1 Ma to 200 ka, rhyolite (> 73 wt. % SiO2) and alkali basalt (­š 51 wt. % SiO2) were the only compositions erupted in significant volumes (29 +/- 5.7 km3 and 12 +/- 1.2 km3, respectively). At approximately 200 ka, the andesite comprising Volc\\­_{a}n Tequila erupted within 30-40 kyr, producing a volume of 30 +/- 2.0 km3. Additional andesitic flows (11 +/- 1.4 km3) erupted to the northwest and southeast of the stratocone between 140 and 20 ka. The total volume of dacite that erupted at the Tequila volcanic field is small (1.3 +/- 0.03 km3) and occurred largely (88%) within the last 70 kyrs. Unlike the andesites and dacites, the basalts and rhyolites did not erupt within narrow time intervals, but extruded over the entire last 1 Myr, producing a total volume of 12.6 +/- 1.2 km3 and 32 +/- 6.1 km3, respectively. This detailed eruptive history, combined with the observed phenocryst assemblages (0-10 vol. %) in the small-volume andesite, dacite, and alkali basalt flows, suggest that they were erupted directly from the lower (or middle) crust, without prior storage in an upper crustal chamber. In contrast, the voluminous burst of andesitic volcanism that produced the phenocryst-rich (35-45 vol. %) lavas of Volc\\­_{a}n Tequila was likely fed from a short-lived (­š 40 kyrs) upper crustal chamber. This scenario is supported by the complex, disequilibrium textures seen in the phenocryst assemblage of the Volc\\­_{a}n Tequila lavas, indicative of magma mingling within an upper crustal chamber (Wallace and Carmichael, 1994). The total volume of erupted material at the Tequila volcanic field is 89 +/- 12 km3, of which

  1. Effects of water-saturation on strength and ductility of three igneous rocks at effective pressures to 50 MPA and temperatures to partial melting

    Energy Technology Data Exchange (ETDEWEB)

    Bauer, S.J.; Friedman, M.; Handin, J.


    The short-term failure strengths and strains at failure of room-dry and water-saturated, cylindrical specimens (2 by 4 cm) of Charcoal Granodiorite (CG), Mt. Hood Andesite (MHA), and Cuerbio Basalt (CB) at a strain rate of 10/sup -4/s/sup -1/, at effective confining pressures of 0, 50, and 100 MPa and at temperatures to partial melting were investigated. Data from water-saturated specimens of the granodiorite and andesite, compared to room-dry counterparts, indicate (1) the pore pressures are essentially communicated throughout each test specimen so that they are fully effective; (2) at P/sub e/ = 0 and 50 MPa the granodiorite does not water-weaken; (3) at these same effective pressures the more porous and finer-grained andesite begins to exhibit water-weakening at about 600/sup 0/C; (4) at P/sub e/ = 0 and 870 to 900/sup 0/C the andesite's strength averages 20 MPa while the strength of dry specimens at the same P and T exhibit a strength of 100 MPa; (5) at P/sub e/ = 50 MPa compared to 160 MPa dry; (6) the basalt at P/sub e/ = 0, appears to be water-weakened at 800/sup 0/C; (7) water saturated specimens deformed at temperatures less than that of melting exhibit ultimate strengths at less than 2% shortening and then work-soften along faults; (8) again as do the dry counterparts, the wet specimens deform primarily by microscopic fracturing that coalesces into one or more macroscopic faults; and (9) the temperature for incipient melting of the andesite is decreased >150/sup 0/C in the water-saturated tests.

  2. Use of Ekibastuzsk coal ash as a filler for acid resistant plaster

    Energy Technology Data Exchange (ETDEWEB)

    Korsakov, F.F.; Isichenko, I.I.; Kabanov, G.A.


    Acid resistant plasters are used extensively at thermal power plants for protection of gas conduits, ash traps with spouts and hydraulic valves, and the internal surfaces of smoke pump housings. The surface being protected is preliminarily cleaned and a No. 16-20 steel grid attached to the surface by electrial welding. In producing the acid resistant plaster, 14-17 parts by weight of sodium silicofluoride are added to 100 parts by weight of sodium water glass; the remainder consists of andesite or diabase meal to the required consistency. The water glass fulfills the role of a binder; the sodium silicofluoride accelerates solidification of the water glass and the andesite and diabase meal serve as fillers. We found, tested in the laboratory and used successfully (under experimental-industrial conditions) a substitute for andesite and diabase meal. This substitute was ash of Ekibastuzsk coal, which was not only comparable to the meal in regard to quality of the acid resistant plaster, but even exceeded andesite and diabase meal in regard to several qualitative indicators. At the present time, a formula is being developed for an acid resistant plaster produced on the basis of water glass, sodium silicofluoride and ash of Ekibastuzsk coal. In order to verify the possibility of using other ashes instead of andesite and diabase meal, we also tested, under laboratory conditions, acid resistant plasters using ash from thermal power plants (TPP's) also burning Karagandinsk, Kuuchekinsk, Kuznetsk and Kansko-Achinsk coals. In compositions produced with polymer binders, Kansko-Achinsk coal ash was one of the best fillers, providing the most favorable physico-mechanical properties of the composition.

  3. Analisis stratigrafi awal kegiatan Gunung Api Gajahdangak di daerah Bulu, Sukoharjo; Implikasinya terhadap stratigrafi batuan gunung api di Pegunungan Selatan, Jawa Tengah

    Directory of Open Access Journals (Sweden)

    Hill Gendoet Hartono


    Full Text Available, Tertiary volcanisms in the Southern Mountains, Central Jawa were started with the formation of pillow lavas having basalt to basaltic andesite in composition. This initial stage volcanism developed into a  construction period of composite volcanoes that consist of alternating basaltic to andesitic lava flows, breccias, and tuffs. The construction period could be followed by a destructive phase, producing pumice-rich pyroclastic breccias, lapillistones, and tuffs of high silica andesite to dacite, or even rhyolite in composition. A stratigraphic measuring section at Bulu area, Sukoharjo Regency, presents an alternat- ing fine-grained andesitic volcaniclastic material and some limestones, with the total thickness is 143.33 m. The thickness of bedded volcaniclastic material tends to be thickening upward from 35 m until 90 m. The grain size of the volcaniclastic material also tends to be coarsening upward from clay size through silt and fine sand to coarse sand and granules. Paleontological analysis on fossils contained in the lime- stone gives an age of Early Miocene (N7 - N9. The volcaniclastic rocks is conformably overlain by the Mandalika Formation, comprising alternating andesitic breccias, lavas, and tuffs. These data imply that the fine-grained volcaniclastic material is an initial product of the construction period of Gajahdangak Volcano in the area, that formed the Mandalika Formation. This Formation is overlain by the Semilir Formation, composed of pumice-rich pyroclastic breccias and tuffs with dacitic composition. This as- sociated volcanic rock reflects a product of a caldera explosion or a destructive phase. Based on the characteristics of lithology of volcanic products from the initial stage, to a construction and destruction period, and compiled age data, the Southern Mountains represent formal volcanic rock units that are able to be divided into many formations.  

  4. Reverse Polarity Magnetized Melt Rocks from the Cretaceous/Tertiary Chicxulub Structure, Yucatan Peninsula, Mexico (United States)

    Urrutia-Fucugauchi, J.; Marin, Luis; Sharpton, Virgil L.


    We report paleomagnetic results for core samples of the breccia and andesitic rocks recovered from the Yucatan-6 Petrolcos Mexicanos exploratory well within the Chicxulub structure (about 60 km SSW from its center), northern Yucatan, Mexico. A previous study has shown that the rocks studied contain high iridium levels and shocked breccia clasts and an Ar/Ar date of 65.2 +/- 0.4 Ma. Andesitic rocks are characterized by stable single-component magnetizations with a mean inclination of -42.6 deg +/- 2.4 deg. Breccias present a complex paleomagnetic record characterized by multivectorial magnetizations with widely different initial NRM inclinations. However, after alternating field demagnetization, well defined characteristic components with upward inclinations are defined. IRM acquisition experiments, comparison of IRM and NRM coercivity spectra and the single component magnetization of the andesitic rocks indicate the occurrence of iron-rich titanomagnetites of single or pseudo-single domain states as the dominant magnetic carriers. Mean inclinations from the andesitic rocks and most of the breccia samples give a mean inclination of about -40 deg to -45 deg, indicating a reverse polarity for the characteristic magnetization that is consistent with geomagnetic chron 29R, which spans the Cretaceous/Tertiary (K/T) boundary. The inclination is also consistent with the expected value (and corresponding paleolatitude) for the site estimated from the reference polar wander curve for North America. We suggest that the characteristic magnetizations for the andesitic and breccia rocks are the result of shock heating at the time of formation of the impact structure and that the age, polarity and pateolatitude are consistent with a time at the K/T boundary.

  5. Geochemistry of the 1989-1990 eruption of redoubt volcano: Part II. Evidence from mineral and glass chemistry (United States)

    Swanson, S.E.; Nye, C.J.; Miller, T.P.; Avery, V.F.


    Early stages (December 1989) of the 1989-1990 eruption of Redoubt Volcano produced two distinct lavas. Both lavas are high-silica andesites with a narrow range of bulk composition (58-64 wt.%) and similar mineralogies (phenocrysts of plagioclase, hornblende, augite, hypersthene and FeTi oxides in a groundmass of the same phases plus glass). The two lavas are distinguished by groundmass glass compositions, one is dacitic and the other rhyolitic. Sharp boundaries between the two glasses in compositionally banded pumices, lack of extensive coronas on hornblende phenocrysts, and seismic data suggest that a magma-mixing event immediately preceeded the eruption in December 1989. Textural disequilibrium in the phenocrysts suggests both magmas (dacitic and rhyolitic glasses) had a mixing history prior to their interaction and eruption in 1989. Sievey plagioclase and overgrowths of magnetite on ilmenite are textures that are at least consistent with magma mixing. The presence of two hornblende compositions (one a high-Al pargasitic hornblende and one a low-Al magnesiohornblende) in both the dacitic and rhyolitic groundmasses indicates a mixing event to yield these two amphibole populations prior to the magma mixing in December 1989. The pargasitic hornblende and the presence of Ca-rich overgrowths in the sievey zones of the plagioclase together indicate at least one component of this earlier mixing event was a mafic magma, either a basalt or a basaltic andesite. Eruptions in 1990 produced only andesite with a rhyolitic groundmass glass. Glass compositions in the 1990 andesite are identical to the rhyolitic glass in the 1989 andesite. Cognate xenoliths from the magma chamber (or conduit) are also found in the 1990 lavas. Magma mixing probably triggered the eruption in 1989. The eruption ended when this rather viscous (rhyolitic groundmass glass, magma capable of entraining sidewall xenoliths) magma stabalized within the conduit. ?? 1994.

  6. Contrasting geochemistry of the Cretaceous volcanic suites in Shandong province and its implications for the Mesozoic lower crust delamination in the eastern North China craton (United States)

    Ling, Wen-Li; Duan, Rui-Chun; Xie, Xian-Jun; Zhang, Yong-Qing; Zhang, Jun-Bo; Cheng, Jian-Ping; Liu, Xiao-Ming; Yang, Hong-Mei


    The Qingshan volcanic sequences occur in the Mengyin and Jiaozhou basins, west and east of the Tan-Lu fault zone, respectively, were formed at 128 ± 2 and 106 - 98 Ma. Lithologically the Mengyin succession comprises unimodal andesite (53 - 65 wt.% SiO 2), whereas the Jiaozhou succession consists of bimodal andesite (56-59 wt.% SiO 2) and rhyolite (69-77 wt.% SiO 2). High-Mg (Mg# >60) and low-Mg (Mg# andesitic suites are recognized in the Mengyin volcanic rocks. They show tholeiitic and calc-alkaline trends, respectively. Though the two suites share common trace element features of LILE enrichment and HFSE depletion, higher incompatible element contents in the high-Mg andesite relative to the low-Mg andesite rule out their genetic connection by magmatic differentiation. Similarly, the Jiaozhou andesites also possess higher incompatible element contents compared to their interbedded rhyolites, suggesting their distinct source rocks. The Qingshan mafic volcanic suites are characterized by radiogenic Sr and unradiogenic Nd isotopic compositions, of which the Mengyin high-Mg andesitic rocks display the lowest ɛ Nd(t) and highest initial Sr ratio. By contrast, the Jiaozhou rhyolites possess a positive correlation between Sr-Nd isotopes and relatively unradiogenic Sr isotopic ratios. The Qingshan mafic rocks exhibit geochemical characteristics distinct from those of mantle peridotite- or pyroxenite-derived melt as well as from Fangcheng basalts, the only basalts documented in the Cretaceous volcanic suites in Shandong province. They are inferred to be crust-derived melts. However, a clear decreasing trend in ACNK with Mg# increasing and the elevated MgO, Cr and Ni contents relative to basalt-derived melts indicate assimilation with mantle peridotite during their pristine magmatic evolution. Such a two-step process can be best explained by the Archean lower crust delamination of the North China craton with a ~35% partial melting followed by a variable extent of

  7. Main peculiarities of N-Q magmatism of the Greater Caucasus (United States)

    Dokuchaev, A.; Bubnov, S.; Bogatikov, O.; Goltsman, Yu.


    Three stages are recognized in young magmatic activity of the Greater Caucasus: Late Miocene, Pliocene, and Quaternary. Products of Late Miocene stage are confined to the northern and southern margins of the Greater Caucasus, respectively: laccoliths of Caucasian Mineral Waters (CMW) (~8 Ma) and magmatic complexes of Central Georgian neovolcanic area (6.4-6.1 Ma) (Lebedev at al., 2006). CMW granitoids are represented by high-Mg# granosyenites, granites, and leucogranites with high alkalinity. They show Mo-Sn±Au-W and base metal ore-geochemical signature. Lavas of Central Georgian area correspond to K-Na subalkali and alkali basalts with high Mg# (0.56-0.67) and elevated Sr, Ba, Nb. Their ore-geochemical specialization has not been defined yet. Pliocene stage was responsible for the formation of Chegem volcanic center (~2.8 Ma), several plutonic complexes (Eldzhurta, Dzhimara, Sangutidon, Kyrtyk) (3.75-1.6 Ma), felsic ignimbrites, rhyolites, rhyodacites of NE and W Elbrus area (3.0-1.6 Ma), as well as dacites and rhyodacites of dikes and stocks of Tyrnyauz area (2.5-2.1 Ma) (Chernyshev et al., 2011). Rocks of Chegem center were formed during three main phases: (1) basaltic andesites of Surkh and Krandukh volcanoes; (2) pyroclastic sequences of Upper and Lower Chegem volcanic highlands and Dzhungusu intrusive massif (dacites, rhyolites, trachyrhyolites, granodiorite porphyries); (3) andesites of Kumtyube and Kyugenkaya stratovolcanoes. Initial and final stages represented by calc-alkaline rocks, whereas second stage was marked by K-Na subalkaline and calc-alkaline rocks. Chegem volcanic center have Pb-Zn±Mo ore-geochemical signatures. Eldzhurta Massif is made up of K-Na granites and leucogranites, while Dzhimara, Tepli, and Sangutidon massifs consist mainly of calc-alkaline diorites and granodiorites with high Ti and Mg contents. Granitoids of Eldzhurta Massif bear W-Mo-Sn-Cu-base-metal signatures, while the Tepli and Sangutidon massifs are characterized by Cu

  8. Evidencia textural y geoquímica de mezcla de magmas en el volcán Chimpa, Puna Salteña Textural and geochemical evidence for magma mixing in the Chimpa Volcano, Puna Salteña

    Directory of Open Access Journals (Sweden)

    Marcelo Arnosio


    Full Text Available La historia eruptiva del volcán Chimpa (24º00´S-66º08´O comprende un ciclo explosivo que eruptó ignimbritas y depósitos de flujos de bloques y ceniza de composición andesítica, y un ciclo efusivo, representado por lavas andesíticas y andesíticas basálticas. Los primeros materiales emitidos durante el ciclo explosivo corresponden a ignimbritas, las cuales no poseen evidencias de interacción con magmas básicos. Por el contrario, en los depósitos de flujos de bloques y ceniza quedó registrada la interacción con un magma básico (mingling representado por inclusiones máficas y el desarrollo de texturas de desequilibrio en plagioclasa y biotita. Sin embargo, la composición del magma andesítico no se modificó durante la mezcla. En el ciclo efusivo se generó un nuevo magma, por mezcla y homogeneización (magma mixing entre el magma andesítico y un magma más básico. Este magma híbrido posee una asociación mineral en desequilibrio, que incluye olivino y cuarzo con corona de clinopiroxeno, hornblenda y biotita con coronas formadas por plagioclasa + ortopiroxeno + magnetita, así como ortopiroxeno con coronas de clinopiroxeno. Estas fases en desequilibrio coexisten junto a otros cristales de las mismas fases, pero en aparente equilibrio. En diagramas geoquímicos, las lavas híbridas ocupan una posición intermedia en la tendencia lineal definida por el extremo andesítico y andesítico basáltico. La proporción del magma básico involucrado en la mezcla es de 44%. Los datos petrográficos y geoquímicos indican un proceso creciente de interacción de magmas básicos con el magma andesítico residente en la cámara magmática a lo largo del tiempo.The eruptive history of the Chimpa volcano (24º00´S-66º08´O comprises an explosive cycle that erupted andesitic ignimbrites and blocks and ash flow deposits, and an effusive cycle, represented by the discharge of andesitic and basaltic andesite lava flows. The first material

  9. Late Cenozoic volcanism in the western Woodlark Basin area, SW Pacific: the sources of marine volcanic ash layers based on their elemental and Sr-Nd isotope compositions (United States)

    Lackschewitz, K. S.; Mertz, D. F.; Devey, C. W.; Garbe-Schönberg, C.-D.


    Tephra fallout layers and volcaniclastic deposits, derived from volcanic sources around and on the Papuan Peninsula, form a substantial part of the Woodlark Basin marine sedimentary succession. Sampling by the Ocean Drilling Program Leg 180 in the western Woodlark Basin provides the opportunity to document the distribution of the volcanically-derived components as well as to evaluate their chronology, chemistry, and isotope compositions in order to gain information on the volcanic sources and original magmatic systems. Glass shards selected from 57 volcanogenic layers within the sampled Pliocene-Pleistocene sedimentary sequence show predominantly rhyolitic compositions, with subordinate basaltic andesites, basaltic trachy-andesites, andesites, trachy-andesites, dacites, and phonolites. It was possible to correlate only a few of the volcanogenic layers between sites using geochemical and age information apparently because of the formation of strongly compartmentalised sedimentary realms on this actively rifting margin. In many cases it was possible to correlate Leg 180 volcanic components with their eruption source areas based on chemical and isotope compositions. Likely sources for a considerable number of the volcanogenic deposits are Moresby and Dawson Strait volcanoes (D'Entrecasteaux Islands region) for high-K calc-alkaline glasses. The Dawson Strait volcanoes appear to represent the source for five peralkaline tephra layers. One basaltic andesitic volcaniclastic layer shows affinities to basaltic andesites from the Woodlark spreading tip and Cheshire Seamount. For other layers, a clear identification of the sources proved impossible, although their isotope and chemical signatures suggest similarities to south-west Pacific subduction volcanism, e.g. New Britain and Tonga-Kermadec island arcs. Volcanic islands in the Trobriand Arc (for example, Woodlark Island Amphlett Islands and/or Egum Atoll) are probable sources for several volcaniclastic layers with ages

  10. The Global Array of Primitve Arc Melts (United States)

    Schmidt, M. W.; Jagoutz, O. E.


    A longstanding question concerns the nature of the melts forming in the subarc mantle and giving rise to arc magmatism. The global array of primitive arc melts (1180 volcanic rocks in 25 arcs extracted from the georoc database, calculated to be in equilibrium with mantle olivine) yields five principal melt types: calc-alkaline basalts and high-Mg andesites, tholeiitic basalts and high-Mg andesites, and shoshonitic or alkaline arc melts; many arcs have more than one type. Primitive calc-alkaline basalts occur in 11 arcs but most strikingly, 8 continental arcs (incl. Aleutians, Cascades, Japan, Mexico, Kamtschatka) have a continuous range of calc-alkaline basalts to high-Mg andesites with mostly 48-58 wt% SiO2. In each arc, these are spatially congruent, trace element patterns overlap, and major elements form a continuum. Their Ca-Mg-Si systematics suggests saturation in olivine+opx+cpx. We hence interpret the large majority of high-Mg andesites as derived from primitive calc-alkaline basalts through fractionation and reaction in the shallower mantle. Removal of anhydrous mantle phases at lower pressures increases SiO2 and H2O-contents while Mg# and Ni remain buffered to mantle values. Primitive tholeiitic basalts (Cascades, Kermadec, Marianas, Izu-Bonin, Japan, Palau, Sunda) have a much lesser subduction signal (e.g. in LILE) than the calc-alkaline suite. These tholeiites have been interpreted to form through decompression melting, but also characterize young intraoceanic arcs. In the two continental arcs with both tholeiitic and calc-alkaline primitive basalts (clearly distinct in trace patterns), there is no clear spatial segregation (Casacades, Japan). Three intraoceanic arcs (Marianas, Izu-Bonin, Tonga) have primitive tholeiitic, highly depleted high-Mg andesites (boninites) with HFSE and HREE slightly above primitive mantle values. These deviate in majors from the array formed by the basalts and calc-alkaline andesites suggesting that only these formed from a

  11. Volcanic structure and composition of Old Shiveluch volcano, Kamchatka (United States)

    Gorbach, Natalia; Portnyagin, Maxim; Tembrel, Igor


    This paper reports results of a new comprehensive geological mapping of the Late Pleistocene Old Shiveluch volcano. The mapping results and geochemical data on major and trace element composition of the volcanic rocks are used to characterize spatial distribution, eruptive sequence and volumetric relationships between different rock types of the volcano. Old Shiveluch volcano had been constructed during two main stages: initial explosive and subsequent effusive ones. Pyroclastic deposits of the initial stage are represented by agglomerate and psephytic tuffs with very few lava flows and form at least 60% of volume of the Old Shiveluch edifice. The deposits of the second stage are dominantly lava flows erupted from four vents: Central, Western, Baidarny and Southern, reconstructed from the field relationships of their lava flows. About 75% of the Old Shiveluch edifice, both pyroclastic deposits and lava, are composed of magnesian andesites (SiO2 = 57.3-63.8 wt.%, Mg# = 0.53-0.57). The most abundant andesitic lavas were coevally erupted from the Central and Western vents in the central part of the edifice. Less voluminous high-Al basaltic andesites (SiO2 = 53.5-55.7 wt.%, Mg# = 0.52-0.56) were produced by the Western, Baidarny and Southern vents situated in the south-western sector. Small volume high-Mg basaltic andesites (SiO2 = 53.9-55.0 wt.%, Mg# = 0.59-0.64) occur in the upper part of the pyroclastic deposits. Andesites of Old and Young Shiveluch Volcanoes have similar compositions, whereas Old Shiveluch basaltic andesites are compositionally distinctive from those of the Young Shiveluch by having lower Mg#, SiO2, Cr and Ni, and higher Al2O3, FeOT, CaO, TiO2, and V contents at given MgO. Geochemical modeling suggests that the compositions of the intermediate Old Shiveluch magmas can be reasonably explained by simple fractional crystallization of olivine, clinopyroxene, plagioclase and magnetite (± hornblende) from water-bearing (~ 3 wt.% H2O) high-Mg# basaltic

  12. The composition of the foundered complement to the continental crust and a re-evaluation of fluxes in arcs (United States)

    Jagoutz, O.; Schmidt, M. W.


    Most primitive arc melts are basaltic in composition, yet the bulk continental crust, thought to be generated in arcs, is andesitic. In order to produce an andesitic crust from primitive arc basalts, rocks complementary to the andesitic crust have to be fractionated and subsequently removed, most likely through density sorting in the lower arc crust. The Kohistan Arc in northern Pakistan offers a unique opportunity to constrain the composition and volume of material fluxes involved in this process. In a lower crustal section >10 km cumulates (dunites, wehrlites, websterites, clinopyroxene-bearing garnetites and hornblendites, and garnet-gabbros) are exposed that are 0.1-0.3 g/cm3 denser than the underlying mantle. The cumulates combine with the andesitic bulk Kohistan Arc crust to reproduce the major and trace element composition of primitive basaltic arc melts. Our petrochemical analysis suggests that fractionation and subsequent foundering of wehrlites+ultramafic hornblende-garnet-clinopyroxene cumulates+garnet-gabbros is a viable mechanism for producing andesitic crust from a calc-alkaline/tholeiitic primitive high-Mg basalt. The mass of the foundered material is approximately twice that of the arc crust generated. For an overall andesitic arc composition, we estimate a magma flux into the arc (11-15 km3/yr) about three times the rate of arc crust production itself. Foundering fluxes of cumulates (6.4-8.1 km3/yr) are one third to half those of the globally subducted oceanic crust (~19 km3/yr). Hence, the delaminate forms a volumetrically significant, albeit refractory and depleted geochemical reservoir in the mantle. Owing to its low U/Pb and high Lu/Hf the foundered material evolves with time to a reservoir characterized by unradiogenic Pb and highly radiogenic Hf isotopes, unlike any of the common mantle endmembers defined by OIB chemistry. The unradiogenic Pb of the foundered arc cumulates could counterbalance the radiogenic Pb composition of the depleted

  13. Origin of rhyolite by crustal melting and the nature of parental magmas in the Oligocene Conejos Formation, San Juan Mountains, Colorado, USA (United States)

    Parker, D. F.; Ghosh, A.; Price, C. W.; Rinard, B. D.; Cullers, R. L.; Ren, M.


    Four closely spaced volcanoes (Summer Coon; Twin Mountains; Del Norte; Carnero Creek) form the east-central cluster of Conejos volcanic centers. These Conejos rocks range from high-K basaltic andesite to rhyolite, with andesite volumetrically the most abundant. Summer Coon and Twin Mountains are composite volcanoes. The Del Norte and Carnero Creek volcanoes are deeply eroded dacite shields. Rhyolite (10% of our Conejos analyses but a much smaller percentage by volume) is only known from Summer Coon and Twin Mountains volcanoes, although high-SiO 2 dacite occurs in the Del Norte volcano. The younger Hinsdale Formation contains a related series ranging from transitional basalt to high-K andesite; we use Hinsdale Formation analyses to represent Conejos parental magmas. Conejos and Hinsdale magmas evolved through AFC processes: Basalt, after interacting with lower crust, assimilated low K/Rb crust, similar in some ways to Taylor and McLennan (Taylor, S.R., and McLennan, S.M., 1985, The continental crust: its composition and evolution. Oxford, Blackwell Scientific.) model upper crust; main series basaltic andesite fractionated to high-K andesite; rhyolite was produced by melting of high K/Ba upper crustal rocks similar to granite gneiss known from inclusions and basement outcrops. Some rhyolite may have been back-mixed into fractionating andesite and dacite. Field evidence for assimilation includes sanidinite-facies, partially melted, gneiss blocks up to 1 m in diameter. Temperature estimates (1100-900 ° C) from two-pyroxene equilibria are consistent with this interpretation, as are the sparsely porphyritic nature of the most-evolved rhyolites and the absence of phenocrystic alkali feldspar. Our study supports the conclusions of previous workers on AFC processes in similar, but generally more mafic, Conejos magmas of the southeastern San Juan Mountains. Our results, however, emphasize the importance of crustal melting in the generation of Conejos rhyolite. We further

  14. Petrogenesis and tectonic implications of Early Jurassic volcanic rocks of the Raohe accretionary complex, NE China (United States)

    Wang, Zhi-Hui; Ge, Wen-Chun; Yang, Hao; Bi, Jun-Hui; Ji, Zheng; Dong, Yu; Xu, Wen-Liang


    The Raohe accretionary complex, located at the border between the Russian Far East and Northeastern China, is a significant part of the western Pacific Oceanic tectonic regime. Due to lack of precise age and geochemical constraints, the tectonic setting and petrogenesis of the magmatic rocks in this area remain undefined, resulting in debate about crustal growth mechanisms and subduction-related accretionary processes in Northeastern China. Here, we report whole-rock major and trace element and Sr-Nd isotope data, together with zircon U-Pb ages and in situ zircon Hf isotope data for calc-alkaline andesites, dacites, rhyolites, rhyolitic crystal tuffs, Nb-enriched andesites and basaltic andesites, and high-Mg andesites of the Raohe accretionary complex in NE China. Samples were collected from Late Triassic to Early Jurassic strata. However, geochronological results in this study indicated that the studied magmatism occurred in the Early Jurassic (187-174 Ma). The calc-alkaline volcanic rocks possess geochemical characteristics typical of arc magmas that form at active continental margins, such as moderate enrichments in large ion lithophile elements (LILEs) and light rare earth elements (LREEs), and depletions in high field strength elements (HFSEs). They have positive εHf(t) values of +3.4 to +10.6 and relatively high (87Sr/86Sr)i values of 0.7047-0.7102. While the Nb-enriched andesites and basaltic andesites have higher TiO2, Hf, Nb, and Zr contents and higher Nb/Ta (24.0-87.6), Nb/U (11.9-75.9), (Nb/Th)PM (0.67-2.70), and (Nb/La)PM (1.95-5.00) ratios than typical arc basalts. They have negative εNd(t) values (-5.5 to -6.0) and relatively variable (87Sr/86Sr)i values of 0.7047-0.7114, suggesting an origin via the partial melting of mantle wedge peridotite that had been metasomatized by slab-derived melt. The high-Mg volcanic rocks, characterized by high MgO and Mg#, TiO2, Al2O3, Cr, Ni, (La/Yb)N and (La/Sm)N, but low Ba/Th ratios, are geochemically similar to

  15. Isparta' da Çıkarılan Andezit Ve Bazalt Kayaçlarının Radyasyon Soğurma Özelliklerinin İncelenmesi

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    Kadir GÜNOĞLU


    Full Text Available Natural stones are generally igneous, metamorphic and sedimentary are divided into 3 classes including. A region of Isparta volcanic magmatic origin andesite and basalt stones which are classified as an area where there are plenty of rocks. These rocks are used as coating materials, especially in buildings. Therefore it is important to determine stones radiation absorbing properties. In this study, in Isparta andesite and basalt rocks extracted 137Cs and 60Co radiation absorbing properties obtained from the radioactive source 662, 1173, and 1332 keV gamma energy was measured for. Gamma Spectroscopy Laboratory measurements of Suleyman Demirel University, located in the 3 "x3" size NaI (Tl detector containing gamma spectroscopy was performed using the system

  16. Repetitive mixing events and Holocene pyroclastic activity at Pico de Orizaba and Popocatepetl, Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Cantagrel, J.M.; Gourgaud, A.; Robin, C.


    The Holocene volcanic activity which built up the present terminal cones of Pico de Orizaba and Popocatepetl in eastern Mexico, was characterized by repeated pyroclastic Saint-Vincent type eruptions. Radiocarbon data show that these paroxysmal events occurred at more or less regular intervals, and were followed by moderate activity producing ash and pumice falls and andesitic lava flows from the summit craters. Typical ash and scoria pyroclastic flows exhibit a heterogeneous composition given by the interaction of a dacitic component with a more basic andesitic one. Scoria bombs are characterized by banded to emulsified textures, mineralogical disequilibrium assemblages and linear chemical variations on element-element plots as exemplified by the Loma Grande flow at Pico. Periodic replenishments of the magmatic reservoir could be the major phenomenon that started mixing and consequently triggered the pyroclastic eruptions. 22 references.

  17. New Insights to the Mid Miocene Calc-alkaline Lavas of the Strawberry Volcanics, NE Oregon Surrounded by the Coeval Tholeiitic Columbia River Basalt Province (United States)

    Steiner, A. R.; Streck, M. J.


    The Strawberry Volcanics (SV) of NE Oregon were distributed over 3,400 km2 during the mid-Miocene and comprise a diverse volcanic suite, which span the range of compositions from basalt to rhyolite. The predominant composition of this volcanic suite is calc-alkaline (CA) basaltic andesite and andesite, although tholeiitic (TH) lavas of basalt to andesite occur as well. The coeval flood basalts of the Columbia River province surround the SV. Here we will discuss new ages and geochemical data, and present a new geologic map and stratigraphy of the SV. The SV are emplaced on top of pre-Tertiary accreted terranes of the Blue Mountain Province, Mesozoic plutonic rocks, and older Tertiary volcanic rocks thought to be mostly Oligocene of age. Massive rhyolites (~300 m thick) are exposed mainly along the western flank and underlie the intermediate composition lavas. In the southern portion of this study area, alkali basaltic lavas, thought to be late Miocene to early Pliocene in age, erupted and overlie the SV. In addition, several regional ignimbrites reach into the area. The 9.7 Ma Devine Canyon Tuff and the 7.1 Ma Rattlesnake Tuff also overlie the SV. The 15.9-15.4 Ma Dinner Creek Tuff is mid-Miocene, and clear stratigraphic relationships are found in areas where the tuff is intercalated between thick SV lava flows. All of the basalts of the SV are TH and are dominated by phenocryst-poor (≤2%) lithologies. These basalts have an ophitic texture dominated by plagioclase, clinopyroxene and olivine (often weathered to iddingsite). Basalts and basaltic andesites have olivine Fo #'s ranging from 44 at the rims (where weathered to iddingsite) and as high as 88 at cores. Pyroxene Mg #'s range from 65 to 85. Andesites of the SV are sub-alkaline, and like the basalts, are exceedingly phenocryst-poor (≤3%) with microphenocrysts of plagioclase and lesser pyroxene and olivine, which occasionally occur as crystal clots of ~1-3 mm instead of single crystals. In addition, minimal

  18. Eruptive history and petrology of Mount Drum volcano, Wrangell Mountains, Alaska (United States)

    Richter, D.H.; Moll-Stalcup, E. J.; Miller, T.P.; Lanphere, M.A.; Dalrymple, G.B.; Smith, R.L.


    Mount Drum is one of the youngest volcanoes in the subduction-related Wrangell volcanic field (80x200 km) of southcentral Alaska. It lies at the northwest end of a series of large, andesite-dominated shield volcanoes that show a northwesterly progression of age from 26 Ma near the Alaska-Yukon border to about 0.2 Ma at Mount Drum. The volcano was constructed between 750 and 250 ka during at least two cycles of cone building and ring-dome emplacement and was partially destroyed by violent explosive activity probably after 250 ka. Cone lavas range from basaltic andesite to dacite in composition; ring-domes are dacite to rhyolite. The last constructional activity occured in the vicinity of Snider Peak, on the south flank of the volcano, where extensive dacite flows and a dacite dome erupted at about 250 ka. The climactic explosive eruption, that destroyed the top and a part of the south flank of the volcano, produced more than 7 km3 of proximal hot and cold avalanche deposits and distal mudflows. The Mount Drum rocks have medium-K, calc-alkaline affinities and are generally plagioclase phyric. Silica contents range from 55.8 to 74.0 wt%, with a compositional gap between 66.8 and 72.8 wt%. All the rocks are enriched in alkali elements and depleted in Ta relative to the LREE, typical of volcanic arc rocks, but have higher MgO contents at a given SiO2, than typical orogenic medium-K andesites. Strontium-isotope ratios vary from 0.70292 to 0.70353. The compositional range of Mount Drum lavas is best explained by a combination of diverse parental magmas, magma mixing, and fractionation. The small, but significant, range in 87Sr/86Sr ratios in the basaltic andesites and the wide range of incompatible-element ratios exhibited by the basaltic andesites and andesites suggests the presence of compositionally diverse parent magmas. The lavas show abundant petrographic evidence of magma mixing, such as bimodal phenocryst size, resorbed phenocrysts, reaction rims, and

  19. Zeolitización de rocas andesíticas

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    Plana, F.


    Full Text Available The study of some andesites from King George Island (South Shetland Islands, Anctartica has pointed out the existence of a hydrothermal alteration process going rise to a zeolitic secondary minerals of low-temperature assemblages. Two paragenesis have been identified (Smectite-Bytownite-Mordenite, Smectite-Albite-Laumontite which reflecting different conditions durign the hydrothermal alteration of these andesitic rocksEl estudio de rocas andesíticas de la Isla King George (Archipiélago de las Shetland del Sur, Antártida pone de manifiesto la existencia de procesos de alteración hidrotermal con la formación de minerales zeolíticos secundarios pertenecientes a asociaciones de baja temperatura. Se han identificado dos paragénesis (Esmectitas-Bytownita-Mordenita, Esmectitas-AlbitaLaumontita que reflejan distintas condiciones durante la alteración hidrotermal de dichas rocas andesíticas.

  20. Genesis of hydrothermal alterations using stable isotope geochemistry in Takestan area (Tarom zone

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    Batool Taghipou


    Full Text Available Hydrothermal alteration processes are extensively took place on volcanic and pyroclstics of Takestan area. Existence of abundant, deep fracturing and subvolcanic intrusions are enhanced extend hydrothermal alteration zones. The following alteration zones are determined: propylitic, argillic, advanced argillic and sillicic. There are outcropped and widespread in different size and limit. Formation of siliceous sinter, silicified tuffs with preserved primary sedimentary layering including pure mineralized alunite patches are most outstanding. Quartz, sussoritic plagioclase, chlorite, sericite and alunite are main mineral constituents in the volcanics. On the basis of geochemical data volcanic rocks are rhyolite, dacite, andesite, andesitic-basalt and basalt in composition. Acid-sulfate zone is the type of alteration in Tarom area and alunite is an index mineral of this zone. Results of 18O, D and 34S stable isotope geochemistry on altered minerals (muscovite, kaolinite and alunite, revealed that alteration fluids are magmatic in origin.


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    Jakob Pamić


    Full Text Available In the paper are presented basic geological, petrologieca1, geochemi-cal and mineral deposit data for five main magmatic-metallogenic formations of the northwestern and central Dinarides: (lThe Permo Triassic rifting related andesite-diorite formations; (2 The Jurassic-Lower Cretaceous accretionary (ophiolite formations; (3 The Upper Cretaceous-Paleogene subduction related basalt-rhyohite formations; (4 The Paleogene collisional granite formations, and (5 The Oligo-cene-Neogene postsubduction andesite formations. All these magmatic-metallogenic formations originated in different geotectonic settings during the Alpine evolution of the Dinaridic parts of thc Tethys and the postorogenic evolution of the Paratethys and the Pannonian Basin, respectively.

  2. Repetitive mixing events and holocene pyroclastic activity at Pico de Orizaba and Popocatepetl (Mexico) (United States)

    Cantagrel, J. M.; Gourgaud, A.; Robin, C.


    The Holocene volcanic activity which built up the present terminal cones of Pico de Orizaba and Popocatepetl in eastern Mexico, was characterized by repeated pyroclastic Saint-Vincent type eruptions. Radiocarbon data show that these paroxysmal events occurred at more or less regular intervals, and were followed by moderate activity producing ash and pumice falls and andesitic lava flows from the summit craters. Typical ash and scoria pyroclastic flows exhibit a heterogeneous composition given by the interaction of a dacitic component with a more basic andesitic one. Scoria bombs are characterized by banded to emulsified textures, mineralogical desequilibrium assemblages and linear chemical variations on element-element plots as exemplified by the Loma Grande flow at Pico. Periodic replenishments of the magmatic reservoir could be the major phenomenon that started mixing and consequently triggered the pyroclastic eruptions.

  3. Postglacial eruptive history, geochemistry, and recent seismicity of Aniakchak volcano, Alaska Peninsula (United States)

    Bacon, Charles R.; Neal, Christina A.; Miller, Thomas P.; McGimsey, Robert G.; Nye, Christopher J.


    Aniakchak is a Pleistocene to Holocene composite volcano of the Alaska–Aleutian arc that suffered at least one caldera-forming eruption in postglacial time and last erupted in 1931. The oldest recognized postglacial eruption, Aniakchak I, produced andesite ignimbrite ca. 9,500–7,500 14C yr B.P. Subsequently, a vent northeast of the summit issued dacite–rhyodacite magma ca. 7,000 14C yr B.P. mainly as the Black Nose Pumice falls. The ca. 3,430 14C yr B.P. Aniakchak II eruption produced rhyodacite plinian fall followed by rhyodacite and andesite ignimbrite extending ≥50 km to the Bering Sea and Pacific coasts and resulted in collapse of the 10-km-diameter caldera.

  4. Petrologic and geochemical characterization and mineralization of the metavolcanic rocks of the Heib Formation, Kid Metamorphic Complex, Sinai, Egypt

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    Ibrahim H. Khalifa


    Full Text Available Metavolcanic rocks hosting base metal sulphide mineralization, and belonging to the Kid Metamorphic Complex, are exposed in the Samra-Tarr area, Southern Sinai. The rocks consist of slightly metamorphosed varicolored porphyritic lavas of rhyolite-to-andesite composition, and their equivalent pyroclastics. Geochemically, these metavolcanics are classified as high-K calc-alkaline, metaluminous andesites, trachyandesites, dacites, and rhyolites. The geochemical characteristics of these metavolcanics strongly point to their derivation from continental crust in an active continental margin. The sulphide mineralization in these metavolcanics occurs in two major ore zones, and is represented by four distinct styles of mineralization. The mineralization occurs either as low-grade disseminations or as small massive pockets. The associated hydrothermal alterations include carbonatization, silicification, sericitization and argillic alterations. The base metal sulphide mineralization is epigenetic and was formed by hydrothermal solutions associated with subduction-related volcanic activity.

  5. Experiments and Spectral Studies of Martian Volcanic Rocks: Implications for the Origin of Pathfinder Rocks and Soils (United States)

    Rutherford, Malcolm J.; Mustard, Jack; Weitz, Catherine


    The composition and spectral properties of the Mars Pathfinder rocks and soils together with the identification of basaltic and andesitic Mars terrains based on Thermal Emission Spectrometer (TES) data raised interesting questions regarding the nature and origin of Mars surface rocks. We have investigated the following questions: (1) are the Pathfinder rocks igneous and is it possible these rocks could have formed by known igneous processes, such as equilibrium or fractional crystallization, operating within SNC magmas known to exist on Mars? If it is possible, what P (depth) and PH2O conditions are required? (2) whether TES-based interpretations of plagioclase-rich basalt and andesitic terrains in the south and north regions of Mars respectively are unique. Are the surface compositions of these regions plagioclase-rich, possibly indicating the presence of old AI-rich crust of Mars, or are the spectra being affected by something like surface weathering processes that might determine the spectral pyroxene to plagioclase ratio?

  6. Submarine silicic volcanism: Processes and products

    Digital Repository Service at National Institute of Oceanography (India)

    Kalangutkar, N.G.; Iyer, S.D.

    and these are supported by several experimental studies (Annen et al., 2006). A silicic calc-alkalic magma can form by differentiation from a more mafic parent magma and by crustal anatexis. Several evidences show the origin of some rhyolitic and andesitic magma... to be related due to similar tectonic settings. Fractional crystallisation: This process produces a series of residual liquids of variable compositions as compared to their parental magmas and is best explained by the Bowen’s reaction principle (Bowen, 1922...

  7. Geochemical constraints on the evolution of mafic and felsic rocks in the Bathani volcanic and volcano-sedimentary sequence of Chotanagpur Granite Gneiss Complex

    Indian Academy of Sciences (India)

    Ashima Saikia; Bibhuti Gogoi; Mansoor Ahmad; Talat Ahmad


    The Bathani volcanic and volcano-sedimentary (BVS) sequence is a volcanic and volcano-sedimentary sequence, best exposed near Bathani village in Gaya district of Bihar. It is located in the northern fringe of the Chotanagpur Granite Gneiss Complex (CGGC). The volcano-sedimentary unit comprises of garnet-mica schist, rhyolite, tuff, banded iron formation (BIF) and chert bands with carbonate rocks as enclaves within the rhyolite and the differentiated volcanic sequence comprises of rhyolite, andesite, pillow basalt, massive basalt, tuff and mafic pyroclasts. Emplacement of diverse felsic and mafic rocks together testifies for a multi-stage and multi-source magmatism for the area. The presence of pillow basalt marks the eruption of these rocks in a subaqueous environment. Intermittent eruption of mafic and felsic magmas resulted in the formation of rhyolite, mafic pyroclasts, and tuff. Mixing and mingling of the felsic and mafic magmas resulted in the hybrid rock andesite. Granites are emplaced later, crosscutting the volcanic sequence and are probably products of fractional crystallization of basaltic magma. The present work characterizes the geochemical characteristics of the magmatic rocks comprising of basalt, andesite, rhyolite, tuff, and granite of the area. Tholeiitic trend for basalt and calc-alkaline affinities of andesite, rhyolite and granite is consistent with their generation in an island arc, subduction related setting. The rocks of the BVS sequence probably mark the collision of the northern and southern Indian blocks during Proterozoic period. The explosive submarine volcanism may be related to culmination of the collision of the aforementioned blocks during the Neoproterozoic (1.0 Ga) as the Grenvillian metamorphism is well established in various parts of CGGC.

  8. Dacitic glassy lava flow from Trlično at Rogatec, Eastern Slovenia

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    Polona Kralj


    Full Text Available Glassy lava from Trlično is dacitic in composition and developed by incomplete mixing of two magmas of similar composition but different degree of groundmass crystallinity.By laminar lava flow banded texture developed consisting of bands with different magma types. Abundance of major and trace elements is within the variation range for dacites. Comparison with the Smrekovec andesites in Northern Slovenia indicates that the rocks do not originate from the same volcanic complex, displaced by tectonic activity.

  9. Disseminated, veinlet and vein Pb-Zn, Cu and Sb polymetallic mineralization in the GaleChah-Shurab mining district, Iranian East Magmatic Assemblage (IEMA)


    Behzad Mehrabi; Ebrahim Tale Fazel; Ali Nokhbatolfoghahai


    The Iranian East Magmatic Assemblage (IEMA) in the Central Lut region, hosted porphyry and vein-type polymetallic mineralization. The GaleChah-Shurab mining district is located in NW of the IEMA. Volcanic and subvolcanic bodies in the area are composed of calc-alkaline porphyry quartz-latite, porphyry dacite and rhyodacite and hornblende-biotite andesite, equivalent to I-type granite. They emplaced in Tertiary and intruded the Jurassic shale, siltstone and limestone basement (Shemshak Fm). Th...

  10. Archeological Testing at at the Fairchild Site (LA 45732) Otero County, New Mexico. (United States)


    granitic, technically they are Monzonites, and contain more Plagio - clase Feldspar than Quartz. Therefore these rocks are mineralogically different...poorly developed Microperthite may be present. Rock #1 is rhyolitic and consists of anhedral Quartz and some Plagio - clase in an altered...quartzite. Rock #2 is andesitic and consists of Plagio - clase microlites with interstitial opaques. The Microperthite in this slide is heavily altered

  11. The delicate balance between soil production and erosion, and its role on landscape evolution


    Dosseto, Anthony; Buss, Heather L; Suresh, P O


    The diversity in landscapes at the Earth’s surface is the result, amongst other things, of the balance (or imbalance) between soil production and erosion. While erosion rates are well constrained, it is only recently that we have been able to quantify rates of soil production. Uranium-series isotopes have been useful to provide such estimates independently of erosion rates. In this study, new U-series isotope are presented data from weathering profiles developed over andesitic parent rock in ...

  12. Bulk rock composition and geochemistry of olivine-hosted melt inclusions in the Grey Porri Tuff and selected lavas of the Monte dei Porri volcano, Salina, Aeolian Islands, southern Italy (United States)

    Doherty, Angela L.; Bodnar, Robert J.; De Vivo, Benedetto; Bohrson, Wendy A.; Belkin, Harvey E.; Messina, Antonia; Tracy, Robert J.


    The Aeolian Islands are an arcuate chain of submarine seamounts and volcanic islands, lying just north of Sicily in southern Italy. The second largest of the islands, Salina, exhibits a wide range of compositional variation in its erupted products, from basaltic lavas to rhyolitic pumice. The Monte dei Porri eruptions occurred between 60 ka and 30 ka, following a period of approximately 60,000 years of repose. The bulk rock composition of the Monte dei Porri products range from basaltic-andesite scoria to andesitic pumice in the Grey Porri Tuff (GPT), with the Monte dei Porri lavas having basaltic-andesite compositions. The typical mineral assemblage of the GPT is calcic plagioclase, clinopyroxene (augite), olivine (Fo72−84) and orthopyroxene (enstatite) ± amphibole and Ti-Fe oxides. The lava units show a similar mineral assemblage, but contain lower Fo olivines (Fo57−78). The lava units also contain numerous glomerocrysts, including an unusual variety that contains quartz, K-feldspar and mica. Melt inclusions (MI) are ubiquitous in all mineral phases from all units of the Monte dei Porri eruptions; however, only data from olivine-hosted MI in the GPT are reported here. Compositions of MI in the GPT are typically basaltic (average SiO2 of 49.8 wt %) in the pumices and basaltic-andesite (average SiO2 of 55.6 wt %) in the scoriae and show a bimodal distribution in most compositional discrimination plots. The compositions of most of the MI in the scoriae overlap with bulk rock compositions of the lavas. Petrological and geochemical evidence suggest that mixing of one or more magmas and/or crustal assimilation played a role in the evolution of the Monte dei Porri magmatic system, especially the GPT. Analyses of the more evolved mineral phases are required to better constrain the evolution of the magma.

  13. The Influence of Ridge Geometry at the Ultraslow-Spreading Southwest Indiean Ridge (9 deg - 25 deg E): Basalt Composition Sensitivity to Variations in Source and Process (United States)


    Along-strike variation in lavas of the Aleutian island arc: implications for the genesis of high Mg # andesite and the continental crust, in Inside the...entire Atlantis II FZ peridotite suite. Harzburgites (red triangles) generally have low Cr # and high Mg #, which is indicative of low degrees of melting...and high Mg #, suggesting a lower degree of compositions (Figures 4 and 6). Upon first glance, melting and thus a less depleted residual peridotite

  14. JPRS Report, Science & Technology, USSR: Earth Sciences (United States)


    formation waters with dissolved fuel gasses are closely spati- ally associated with those having high mineralization, bromine (100s mg /1) and iodine...formations associated with both the ophiolites of the oceanic crust and with an island arc complex of magmatic rocks of the calc-alkali (" andesite ...had maxima near lO^c/min, with high coherence at that frequency with a vertical separation of up to 50-60 m. Outside this band of frequencies

  15. A Preliminary Study of Seismicity at Ceboruco, Volcano, Nayarit, Mexico (United States)

    Sanchez, J. J.; Nunez-Cornu, F. J.; Suarez-Plascencia, C.; Trejo-Gomez, E.


    Ceboruco Volcano is located northwestern of Tepic-Zacoalco graben (Jalisco, Mexico). Its volcanic activity can be divided in four eruptive cycles differentiated by their volcano explosivity index (VEI) and chemical variations as well. As a result of andesitic effusive activity, during the first cycle the "paleo-Ceboruco" edifice was constructed. The end of this cycle is defined by a plinian eruption (VEI is estimated between 3 and 4) which occurred some 1020 years ago and formed the external caldera. During the second cycle an andesitic dome extruded in the interior of the caldera. The dome, called Dos Equis, collapsed and formed the internal caldera. The third cycle is represented by andesitic lava flows which partially cover the northern and south-southwestern part of the edifice. The last cycle is represented by historic andesitic lava flows located in the southwestern flank of the volcano. In February 2003 as part of an agreement with Nayarit Civil Defense a seismic station was installed in the SW flank of the volcano. The station is equipped with a Marslite (lennartz) digitizer with a 3DLe 1Hz. seismic sensor. Detection system is based on a STA/LTA recording algorithm. More than 2000 small earthquakes have been attributed to various local sources, and some of this earthquakes are possibly located beneath Ceboruco volcano. A preliminary classification separates high frequency and low frequency seismic events. The sources of high frequency earthquakes appear to be distributed as evidenced from waveforms variety and changing S-P arrivals separations. The low frequency seismic events also show varying signatures and some of them exhibit extended coda, including some monochromatic character.

  16. 山形県白鷹火山カルデラの構造と岩屑なだれ堆積物


    笹谷, 晋吾; 横田, 修一郎


    Structures of the Quaternary Shirataka volcanic calderas and the occurrences of debris avalanches have been studied on the basis of field mapping data,borehole core,and paleomagnetism measurements.The debris avalanche deposits distributed in and adjacent to the calderas are determined to be 50 to 60 meters in thickness,and it extensively cover rhyolitic pyroclastic flow deposits and thick andesite lava.Although the northern and eastern walls of the calderas are not recognized,borehole data in...

  17. Tree-mould caves in Slovakia.

    Directory of Open Access Journals (Sweden)

    Gaal Ludovit


    Full Text Available Four tube-shaped caves are described in this work, which origined in consequence of weathering the trees. Their length ranges from 5.8 to 17 m. All of them occur in neovolcanic rocks of Middle Slovakia, in epiclastic andesite conglomerates, breccias or in the tuffs. Some other caverns are close to the entrance of this caves, however they are inaccessible for a man. Thin rim of silicates (opal or chalcedony occurs in some of them.

  18. Geomorphology and sedimentary features, and temporal component-change of lahar deposits at the northern foot of Chokai volcano, NE Japan (United States)

    Minami, Y.; Ohba, T.; Kataoka, K.; Hayashi, S.


    Chokai volcano is an andesitic stratovolcano that collapsed to the north ca.2500 years ago. The post-collapse fan deposits are distributed in the northern foot of the volcano, and to reveal their depositional process in terms of modern sedimentology, we carried out the geological study includung digging survey, as well as geomorphological analysis, mineralogy, and 14C chronology. Consequently, the geological study revealed that the fan deposits consist of more than 16 units, which are debris flow, hyperconcentrated flow and streamflow deposits. We give hare general name lahar deposits for these deposits. The lahar deposits have a total thickness of 30 m, and overlie the 2.5-ka Kisakata debris avalanche deposit. The lahar deposits form a part of volcanic fan and volcaniclastic apron of Chokai volcano. In proximal areas (steep or moderate sloped areas), the lahar flowed down as debris flows, and in the distal area (horizontal area) the lahars transformed into hyperconcentrated flow or stream flows but partly arrived the area as debris flow. The hyperconcentrated flows or stream flows reached the horizontal area at least four times, supposed by AMS dating (the ages of some lahar deposits are 2200, 1500-1600, 1000-1200, and 100-200 yBP). The lahar deposits contain clasts of altered andesite, fresh andesite, mudstone and sandstone. Proportions of altered andesite clasts to total clasts decrease upwards in stratigraphic sequence. Matrices of the lower eight units are composed of grayish-blue clay, and are different from those of the upper eight units, composed of brownish yellow volcanic sand. The stratigraphic variation in matrix component is consistent with the change in matrix mineral assemblage, possibly reflecting changes in the source materials from Chokai volcano.

  19. Deciphering petrogenic processes using Pb isotope ratios from time-series samples at Bezymianny and Klyuchevskoy volcanoes, Central Kamchatka Depression (United States)

    Kayzar, Theresa M.; Nelson, Bruce K.; Bachmann, Olivier; Bauer, Ann M.; Izbekov, Pavel E.


    The Klyuchevskoy group of volcanoes in the Kamchatka arc erupts compositionally diverse magmas (high-Mg basalts to dacites) over small spatial scales. New high-precision Pb isotope data from modern juvenile (1956-present) erupted products and hosted enclaves and xenoliths from Bezymianny volcano reveal that Bezymianny and Klyuchevskoy volcanoes, separated by only 9 km, undergo varying degrees of crustal processing through independent crustal columns. Lead isotope compositions of Klyuchevskoy basalts-basaltic andesites are more radiogenic than Bezymianny andesites (208Pb/204Pb = 37.850-37.903, 207Pb/204Pb = 15.468-15.480, and 206Pb/204Pb = 18.249-18.278 at Bezymianny; 208Pb/204Pb = 37.907-37.949, 207Pb/204Pb = 15.478-15.487, and 206Pb/204Pb = 18.289-18.305 at Klyuchevskoy). A mid-crustal xenolith with a crystallization pressure of 5.2 ± 0.6 kbars inferred from two-pyroxene geobarometry and basaltic andesite enclaves from Bezymianny record less radiogenic Pb isotope compositions than their host magmas. Hence, assimilation of such lithologies in the middle or lower crust can explain the Pb isotope data in Bezymianny andesites, although a component of magma mixing with less radiogenic mafic recharge magmas and possible mantle heterogeneity cannot be excluded. Lead isotope compositions for the Klyuchevskoy Group are less radiogenic than other arc segments (Karymsky—Eastern Volcanic Zone; Shiveluch—Northern Central Kamchatka Depression), which indicate increased lower-crustal assimilation beneath the Klyuchevskoy Group. Decadal timescale Pb isotope variations at Klyuchevskoy demonstrate rapid changes in the magnitude of assimilation at a volcanic center. Lead isotope data coupled with trace element data reflect the influence of crustal processes on magma compositions even in thin mafic volcanic arcs.

  20. Magmatism in the Asunción-Sapucai-Villarrica Graben (Eastern Paraguay) Revisited: Petrological, Geophysical, Geochemical, and Geodynamic Inferences


    Piero Comin-Chiaramonti; Angelo De Min; Aldo Cundari; Girardi,Vicente A. V.; Marcia Ernesto; GOMES,CELSO B.; Claudio Riccomini


    The Asunción-Sapucai-Villarrica graben (ASV) in Eastern Paraguay at the westernmost part of the Paraná Basin was the site of intense magmatic activity in Mesozoic and Tertiary times. Geological, petrological, mineralogical, and geochemical results indicate that the following magmatic events are dominant in the area: (1) tholeiitic basalt and basaltic andesites, flows and sills of low- and high-titanium types; (2) K-alkaline magmatism, where two suites are distinguished, that is, basanite to p...

  1. Imperial porphyry from Gebel Abu Dokhan, the Red Sea Mountains, Egypt

    DEFF Research Database (Denmark)

    Makovicky, Emil; Frei, Robert; Karup-Møller, Sven;


    -K calc-alkaline andesites and dacites with a traceelement spectrum typical of volcanic rocks from an Andean subduction-zone setting. Four rock samples yielded an errorchron with an age of 560 ± 42 Ma and an initial 87Sr/86Sr ratio of 0.70283 ± 0.00011. Using Nd isotope data, values of TDM from 0.84 to 0...

  2. Formation and Significance of Magmatic Enclaves in From the 2006 Eruption of Augustine Volcano, Alaska (United States)

    Browne, B. L.; Vitale, M. L.


    Deposits from the 2006 eruption of Augustine Volcano, Alaska, record a complicated history of open system magmatic processes that produced a suite of intermediate (56.5 to 63.3% SiO2) lithologies containing rare and variably quenched basaltic to basaltic-andesite enclaves (49.5-57.3% SiO2). The eruption transitioned from an explosive phase (Jan 11-28) to a continuous phase (Jan 28-Feb 10) before ending following a month-long effusive phase in March. Whereas the explosive phase is dominated by a low-silica andesite (LSAS, 56.5-58.7% SiO2) lithology, high-silica andesite (HSA, 62.2-63.3% SiO2) is more common during the continuous phase and dense low-silica andesite (DLSA, 56.4-59.3% SiO2) occurs mostly during the effusive phase. Enclaves occur in all lithologies, although most commonly in DLSA and LSAS. Point-counting of enclaves in outcrop reveals an average abundance of Augustine Volcano record a complex and multi-step mixing and mingling scenario between intruding basalt and resident silicic mush, and possibly gabbroic cumulates/wall rock, that is inconsistent with any single currently employed mingling model (e.g., buoyant lift-off of vesiculated and undercooled basalt, prolonged undercooling of intruded basalt punctuated by subsequent intrusions, enclave dissagregation and ripening, or violent intrusion of bubbly basaltic plumes) that has been used to explain magmatic enclave formation at other arc systems characterized by lower magma temperature, higher crystallinity, and larger eruptive volumes (e.g., Unzen Volcano, Mt. Lassen, Soufriere Hills).

  3. Cogenetic late Pleistocene rhyolite and cumulate diorites from Augustine Volcano revealed by SIMS 238U-230Th dating of zircon, and implications for silicic magma generation by extraction from mush (United States)

    Coombs, Michelle L.; Vazquez, Jorge A.


    Volcano, a frequently active andesitic island stratocone, erupted a late Pleistocene rhyolite pumice fall that is temporally linked through zircon geochronology to cumulate dioritic blocks brought to the surface in Augustine's 2006 eruption. Zircon from the rhyolite yield a 238U-230Th age of ˜25 ka for their unpolished rims, and their interiors yield a bimodal age populations at ˜26 ka and a minority at ˜41 ka. Zircon from dioritic blocks, ripped from Augustine's shallow magmatic plumbing system and ejected during the 2006 eruption, have interiors defining a ˜26 ka age population that is indistinguishable from that for the rhyolite; unpolished rims on the dioritic zircon are dominantly younger (≤12 ka) indicating subsequent crystallization. Zircon from rhyolite and diorite overlap in U, Hf, Ti, and REE concentrations although diorites also contain a second population of high-U, high temperature grains. Andesites that brought dioritic blocks to the surface in 2006 contain zircon with young (≤9 ka) rims and a scattering of older ages, but few zircon that crystallized during the 26 ka interval. Both the Pleistocene-age rhyolite and the 2006 dioritic inclusions plot along a whole-rock compositional trend distinct from mid-Holocene-present andesites and dacites, and the diorites, rhyolite, and two early Holocene dacites define linear unmixing trends often oblique to the main andesite array and consistent with melt (rhyolite) extraction from a mush (dacites), leaving behind a cumulate amphibole-bearing residue (diorites). Rare zircon antecrysts up to ˜300 ka from all rock types indicate that a Quaternary center has been present longer than preserved surficial deposits.

  4. Giant magmatic water reservoir beneath Uturuncu volcano and Altiplano-Puna region (Central Andes) (United States)

    Laumonier, Mickael; Gaillard, Fabrice; Muir, Duncan; Blundy, Jon; Unsworth, Martyn


    Volcanism at continental arcs is the surface manifestation of long-lived crustal magmatic processes whereby mantle-derived hydrous basalt magma differentiates to more silica-rich magmas by a combination of crystallization and crustal melting. What erupts is just a fraction of the total volume of magma produced by these processes; the unerupted, plutonic residues solidify and are inaccessible to direct study until millions of years of uplift and erosion bring them to the surface. In contrast, geophysical surveys, using electromagnetic and seismic waves, can provide real-time images of subduction zone magmatic systems. Several such studies have revealed that arc volcanoes are underlain by large partially molten regions at depths of >10 km, the largest known example being the Altiplano-Puna magma body (APMB) in central Andes. Interpreting such geophysical images in terms of amount, composition and distribution of partial melts is limited by our lack of knowledge of the physical properties of silicate melts at elevated pressures and temperatures. Here we present high-pressure, in situ experimental data showing that the electrical conductivity of andesitic melts is primarily controlled by their dissolved water contents. Linking our new measurements to petrological constraints from andesites erupted on the Altiplano, we show that the APMB is composed of 10-20% of an andesitic melt containing 8-10 wt% dissolved water. This implies that the APMB is a giant water anomaly in the global subduction system, with a total mass of dissolved magmatic water about half of the water contained within the Adriatic Sea. In addition to the controls on the physical properties of the melts, the abundance of dissolved water governs the structural levels of magma ponding, equivalent to the depth of water saturation, where degassing and crystallisation promote partial melting and weakening of the upper crust. Unexpectedly, very high concentrations of water in andesite magmas shall impede their

  5. The Patricia Zn–Pb–Ag epithermal ore deposit: An uncommon type of mineralization in northeastern Chile


    Chinchilla, Darío; Ortega, L.; Piña, Rubén; Merinero, R.; Moncada, D.; Bodnar, Robert J.; Quesada, Cecilio; Valverde, Antonio; Lunar, Rosario


    The Patricia ore deposit represents an unusual example of economic Zn–Pb–Ag mineralization at the northernmost end of the Late Eocene–Oligocene metallogenic belt in Chile. It is hosted by volcano-sedimentary units, which are typically tuffaceous and andesitic breccias. The ore body consists of a set of subvertical E-W vein systems developed under a sinistral strike-slip regime that included transtensive domains with generalized extensional structures where the ores were deposited. The deposit...

  6. Significado de fábricas magnéticas en rocas volcánicas cuaternarias de la Isla Decepción (Shetland del Sur, Antártida)


    Gil Imaz, Andrés; Gil Peña, Inmaculada; Galindo Zaldívar, Jesús; Rey Salgado, Jorge; Maestro González, Adolfo; Pueyo Anchuela, Óscar; Soto Marín, Ruth; Oliva Urcia, Belén; López Martínez, Jerónimo


    This work deals with the magnetic fabric (AMS technique) of different lithotypes related to quaternary volcanism of Deception Island (South Shetland Islands). The studied rocks include lava flows from basaltic to basaltic-andesitic composition, mafic dykes and several types of pyroclastic deposits. By combining the analysis of parametric aspects of the magnetic ellipsoids and their directional pattern, four types of magnetic fabrics have been recognized. Type I fabrics are related...

  7. Geochemical constraints on the evolution of mafic and felsic rocks in the Bathani volcanic and volcano-sedimentary sequence of Chotanagpur Granite Gneiss Complex (United States)

    Saikia, Ashima; Gogoi, Bibhuti; Ahmad, Mansoor; Ahmad, Talat


    The Bathani volcanic and volcano-sedimentary (BVS) sequence is a volcanic and volcano-sedimentary sequence, best exposed near Bathani village in Gaya district of Bihar. It is located in the northern fringe of the Chotanagpur Granite Gneiss Complex (CGGC). The volcano-sedimentary unit comprises of garnet-mica schist, rhyolite, tuff, banded iron formation (BIF) and chert bands with carbonate rocks as enclaves within the rhyolite and the differentiated volcanic sequence comprises of rhyolite, andesite, pillow basalt, massive basalt, tuff and mafic pyroclasts. Emplacement of diverse felsic and mafic rocks together testifies for a multi-stage and multi-source magmatism for the area. The presence of pillow basalt marks the eruption of these rocks in a subaqueous environment. Intermittent eruption of mafic and felsic magmas resulted in the formation of rhyolite, mafic pyroclasts, and tuff. Mixing and mingling of the felsic and mafic magmas resulted in the hybrid rock andesite. Granites are emplaced later, cross-cutting the volcanic sequence and are probably products of fractional crystallization of basaltic magma. The present work characterizes the geochemical characteristics of the magmatic rocks comprising of basalt, andesite, rhyolite, tuff, and granite of the area. Tholeiitic trend for basalt and calc-alkaline affinities of andesite, rhyolite and granite is consistent with their generation in an island arc, subduction related setting. The rocks of the BVS sequence probably mark the collision of the northern and southern Indian blocks during Proterozoic period. The explosive submarine volcanism may be related to culmination of the collision of the aforementioned blocks during the Neoproterozoic (1.0 Ga) as the Grenvillian metamorphism is well established in various parts of CGGC.

  8. Effect of melt composition on crustal carbonate assimilation: Implications for the transition from calcite consumption to skarnification and associated CO2 degassing (United States)

    Carter, Laura B.; Dasgupta, Rajdeep


    Skarns are residue of relatively low-temperature magma-induced decarbonation in the crust largely associated with silicic plutons. Mafic magmatic intrusions are also capable of releasing excess CO2 due to carbonate assimilation. However, the effect of mafic to silicic melt evolution on the decarbonation processes, in addition to temperature controls on carbonate-intrusive magmatic systems, particularly at continental arcs, remains unclear. In this study, experiments performed in a piston cylinder apparatus at midcrustal depth (0.5 GPa) at supersolidus temperatures (900-1200°C) document calcite interaction with andesite and dacite melts at equilibrium under closed-system conditions at calcite saturation in a 1:1 melt-calcite ratio by weight. With increasing silica content in the starting melt, at similar melt fractions and identical pressure, assimilation decreases drastically (≤65% andesite-calcite to ≤18% dacite-calcite). In conjunction, the CaO/SiO2 ratio in melts resulting from calcite assimilation in andesitic starting material is >1, but ≤0.3 in those formed from dacite-calcite interaction. With increasing silica-content in the starting melt skarn mineralogy, particularly wollastonite, increases in modal abundance while diopsidic clinopyroxene decreases slightly. More CO2 is released with andesite-calcite reaction (≤2.9 × 1011 g/y) than with more skarn-like dacite-calcite interaction (≤8.1 × 1010 g/y, at one volcano assuming respective calcite-free-superliquidus conditions and a magma flux of 1012 g/y). Our experimental results thus suggest that calcite assimilation in more mafic magmas may have first degassed a significant amount of crustal carbon before the melt evolves to more silicic compositions, producing skarn. Crustal decarbonation in long-lived magmatic systems may hence deliver significant albeit diminishing amounts of carbon to the atmosphere and contribute to long-term climate change.

  9. The age and constitution of Cerro Campanario, a mafic stratovolcano in the Andes of central Chile (United States)

    Hildreth, W.; Singer, B.; Godoy, E.; Munizaga, F.


    Cerro Campanario, a towering landmark on the continental divide near Paso Pehuenche, is a glacially eroded remnant of a mafic stratovolcano that is much younger than previously supposed. Consisting of fairly uniform basaltic andesite, rich in olivine and plagioclase, the 10-15 km3 edifice grew rapidly near the end of the middle Pleistocene, about 150-160 ka, as indicated by 40Ar/39Ar and unspiked K-Ar analyses of its lavas.

  10. Multiple plagioclase crystal populations identified by crystal size distribution and in situ chemical data: Implications for timescales of magma chamber processes associated with the 1915 eruption of Lassen Peak, CA (United States)

    Salisbury, M.J.; Bohrson, W.A.; Clynne, M.A.; Ramos, F.C.; Hoskin, P.


    Products of the 1915 Lassen Peak eruption reveal evidence for a magma recharge-magma mixing event that may have catalyzed the eruption and from which four compositional members were identified: light dacite, black dacite, andesitic inclusion, and dark andesite. Crystal size distribution, textural, and in situ chemical (major and trace element and Sr isotope) data for plagioclase from these compositional products define three crystal populations that have distinct origins: phenocrysts (long axis > 0??5 mm) that typically have core An contents between 34 and 36 mol %, microphenocrysts (long axis between 0??1 and 0??5 mm) that have core An contents of 66-69, and microlites (long axis crystal growth rates and acicular and swallowtail crystal habits. Some plagioclase phenocrysts from the dacitic chamber were incorporated into the hybrid layer and underwent dissolution-precipitation, seen in both crystal textures and rim compositions. Average microphenocryst residence times are of the order of months. Microlites may have formed in response to decompression and/ or syn-eruptive degassing as magma ascended from the chamber through the volcanic conduit. Chemical distinctions in plagioclase microlite An contents reveal that melt of the dark andesite was more mafic than the melt of the other three compositions. We suggest that mixing of an intruding basaltic andesite and reservoir dacite before magma began ascending in the conduit allowed formation of a compositionally distinct microlite population. Melt in the other three products was more evolved because it had undergone differentiation during the months following initial mixing; as a consequence, melt and microlites among these three products have similar compositions. The results of this study highlight the integrated use of crystal size distribution, textural, and in situ chemical data in identifying distinct crystal populations and linking these populations to the thermal and chemical characteristics of complex magma

  11. Summary of the geology of the northern part of the Sierra Cuchillo, Socorroand Sierra Counties, southwestern New Mexico (United States)

    Maldonado, Florian; Edited by Lucas, Spencer G.; McLemore, Virginia T.; Lueth, Virgil W.; Spielmann, Justin A.; Krainer, Karl


    The northern part of the Sierra Cuchillo is located within the northeastern part of the Mogollon-Datil volcanic field west of the Rio Grande rift in the Basin and Range Province, approximately 50 km northwest of Truth or Consequences in south-central New Mexico. The Sierra Cuchillo is a north-south, elongated horst block composed of Tertiary volcanic and intrusive rocks, sparse outcrops of Lower Permian and Upper Cretaceous rocks, and sediments of the Tertiary-Quaternary Santa Fe Group. The horst is composed mainly of a basal volcanic rock sequence of andesite-latite lava flows and mud-flow breccias with a 40Ar/39Ar isotopic age of about 38 Ma. The sequence is locally intruded by numerous dikes and plugs that range in composition from basaltic andesite through rhyolite and granite. The andesite-latite sequence is overlain by ash-flow tuffs and a complex of rhyolitic lava flows and domes. Some of these units are locally derived and some are outflow sheets derived from calderas in the San Mateo Mountains, northeast of the study area. These locally derived units and outflow sheets range in age from 28 to 24 Ma.

  12. Sr, Nd and Pb isotope and geochemical data from the Quaternary Nevado de Toluca volcano, a source of recent adakitic magmatism, and the Tenango Volcanic Field, Mexico (United States)

    Martínez-Serrano, Raymundo G.; Schaaf, Peter; Solís-Pichardo, Gabriela; Hernández-Bernal, Ma. del Sol; Hernández-Treviño, Teodoro; Julio Morales-Contreras, Juan; Macías, José Luis


    Volcanic activity at Nevado de Toluca (NT) volcano began 2.6 Ma ago with the emission of andesitic lavas, but over the past 40 ka, eruptions have produced mainly lava flows and pyroclastic deposits of predominantly orthopyroxene-hornblende dacitic composition. In the nearby Tenango Volcanic Field (TVF) pyroclastic products and lava flows ranging in composition from basaltic andesite to andesite were erupted at most of 40 monogenetic volcanic centers and were coeval with the last stages of NT. All volcanic rocks in the study area are characterized by a calc-alkaline affinity that is consistent with a subduction setting. Relatively high concentrations of Sr (>460 ppm) coupled with low Y (45 km) that underlies the volcanoes of the study area, the geochemical and isotopic patterns of these rocks indicate low interaction with this crust. NT volcano was constructed at the intersection of three fault systems, and it seems that the Plio-Quaternary E-W system played an important role in the ascent and storage of magmas during the recent volcanic activity in the two regions. Chemical and textural features of orthopyroxene, amphibole and Fe-Ti oxides from NT suggest that crystallization of magmas occurred at polybaric conditions, confirming the rapid upwelling of magmas.


    Directory of Open Access Journals (Sweden)

    Lazar Kricak


    Full Text Available The blasting process remains a potential source of numerous environmental and safety accidents. The majority of these accidents were contributed to the flyrock and lack of blast area security. A field-scale investigation related to flyrock accident was conducted in an andesite quarry where rocks up to 50 cm in diameter were propelled almost 300 m from the center of blasting field causing extensive damages to the surrounding objects. The study revealed that accident occurred due to the existence of andesite alteration in one section of the blast field. The existence of this alteration caused a sliding of rock masses along the subsistent joint planes and thereby reduced burden for the second row of blastholes. Alterations involved small area of andesite masses that were not detected by previous geological exploration or visually observed prior to initiation of blastholes. The result of this filed investigation should have a positive impact on hazard awareness, prevention and safe blasting practices in mining and construction industries."

  14. Subaqueous environment and volcanic evolution of the Late Cretaceous Chelopech Au-Cu epithermal deposit, Bulgaria (United States)

    Chambefort, Isabelle; Moritz, Robert


    A detailed field and petrographic study constrains the volcanic evolution and environment setting of the volcano-sedimentary-hosted Chelopech Cu-Au epithermal deposit, Bulgaria. Magmatic activity and associated high-sulfidation epithermal mineralization occurred at about 91 Ma in the Panagyurishte ore district of the Eastern European Banat-Timok-Srednogorie metallogenic belt. Volcanic and hydrothermal activity took place in a complex subaqueous setting, resulting in the intercalation of quartz sandstone with andesitic volcanic and volcaniclastic breccia. There are also hypabyssal andesite intrusion, phreatomagmatic breccia and interbeds of pyroclastic, oolithic and bioclastic rocks. The presence of altered cerebroid ooid-bearing sedimentary units characteristic of salty environment is in accordance with a lagoon environment predating the mineralization at Chelopech. Four principal stages of evolution for the Chelopech district are proposed based on field and petrographic observations. Initial volcanism occurred in a lake or in a coastal, shallow lagoon environment above crystalline basement. The Chelopech "phreatomagmatic" breccia and subsurface andesites were emplaced at this time. Subsequent hydrothermal activity produced the different hydrothermal breccia types, advanced argillic and quartz-phyllic alteration, and Au-Cu vein and replacement mineralization. The end of volcanism and hydrothermal activity was associated with opening of a pull-apart basin that covered the Chelopech environment with a sedimentary flysch. Tertiary compression faulting juxtaposed various rocks and tilted the ore deposit during the Alpine orogeny.

  15. Clast formation in cinder cone vents: Negro Rock, Malheur County, Oregon

    Energy Technology Data Exchange (ETDEWEB)

    Atkinson, M.G. (California State Univ., Sacramento, CA (United States). Geology Dept.); Pasek, T.A. (Springfield High School, OR (United States)); Cummings, M.L. (Portland State Univ., OR (United States). Geology Dept.)


    Negro Rock is an andesitic vent complex within the middle to late Miocene Grassy Mountain Formation. Negro Rock complex includes two central vents that intrude palagonitic tephra formed during an earlier episode of hydrovolcanic-dominated volcanism. In the southwestern vent, Negro Rock, progressive fragmentation from a chilled wall to open textured scoria is preserved. Chilled, vesicle-free andesite against contact metamorphosed palagonitic tephra forms the outer wall of the vent. Inward, strongly vertically stretched vesicles occur in crudely flow banded andesite. The stretch textures give way to isolated patches of small vesicles in a non-vesiculated, non-stretched matrix. The size and abundance of vesicles patches increases inward. The non-vesiculated portion steadily decreases to a dense rim around vesiculated incipient clasts. As clast forms become more prominent the color changes from dark gray to purple. Liberated scoria clasts are red and occur with an assortment of blocks and fusiform bombs within the vent. Clast formation is due to magmatic degassing within the base of the cinder cone. The northeastern, higher vent shows incipient clast formation near the summit.

  16. SHRIMP zircon U-Pb dating for volcanic rocks of the Dasi Formation in southeast Hubei Province, middle-lower reaches of the Yangtze River and its implications

    Institute of Scientific and Technical Information of China (English)

    XIE Guiqing; MAO Jingwen; LI Ruiling; ZHOU Shaodong; YE Huishou; YAN Quanren; ZHANG Zusong


    The Jinniu Basin in southeast Hubei,located at the westernmost part of middle-lower valley of the Yangtze River, is one of the important volcanic basins in East China. Volcanic rocks in the Jinniu Basin are distributed mainly in the Majiashan Formation, the Lingxiang Formation and the Dasi Formation, consisting of rhyolite, basalt and basaltic andesite, (trachy)-basalt and basaltic trachy-andesite and (trachy)-andesite and (trachy)-dacite and rhyolite respectively, in which the Dasi volcanism is volumetrically dominant and widespread. The Dasi volcanic rocks were selected for SHRIMP zircon U-Pb dating to confirm the timing of volcanism. The results indicate that there exist a large amount of magmatic zircons characterized by high U and Th contents in the volcanic rocks. The concordia ages for 13 points are 128±1Ma (MSWD = 3.0). On account of the shape of zircons and Th/U ratios, this age is considered to represent the crystallization time of the Dasi volcanism. The volcanic rocks in the Dasi, Majiashan and Lingxiang Formations share similar trace element and REE partition patterns as well as Sr-Nd isotopic compositions. In combination with the regional geology, it is proposed that the southeast Hubei volcanic rocks were formed mainly during the Early Cretaceous, just like other volcanic basins in middle-lower Yangtze valley. A lithospheric extension is also suggested for tectonic regime in this region in the Cretaceous Period.

  17. Timing and geochemical characters of the Sanchazi magmatic arc in Mianlüe tectonic zone, South Qinling

    Institute of Scientific and Technical Information of China (English)


    The Sanchazi mafic-ultramafic complex in Mianlue tectonic zone, South Qinling can be subdivided into two blocks, i.e. Sanchazi paleo-magmatic arc and Zhuangkegou paleo-oceanic crust fragment (ophiolite). The Sanchazi paleo-magmatic arc is mainly composed of andesite, basaltic and basalt-andesitic gabbro (or diorite), andesitic dyke, plagiogranite and minor ultramafic rocks, which have typical geochemical features of island arc volcanic rocks, such as high field strength element (e.g. Nb, Ti) depletions and lower Cr, Ni contents. The Light rare earth element (LREE) and K enrichments of these rocks and zircon xenocrystals of 900 Ma from plagiogranite suggest that this magmatic arc was developed on the South active continental margin of the South Qinling micro-continent. The U-Pb age of (300 ± 61)Ma for zircons from plagiogranite indicates that the Mianlue paleo-oceanic crust was probably subducted underneath the South Qinling micro-continent in Carboniferous. This is consistent with the formation time (309Ma) of the Huwan eclogite originating from oceanic subduction in Dabie Mountains, suggesting that the Mianlue paleo-ocean probably extended eastward to the Dabie Mountains in Carboniferous. The high-Mg adakitic rocks in Sanchazi paleo-magmatic arc suggest that the subducted oceanic crust was relatively young (<25Ma) and hot.

  18. Discovery of the boninite series volcanic rocks in the Bangong Lake ophiolite mélange,western Tibet,and its tectonic implications

    Institute of Scientific and Technical Information of China (English)

    SHI Rendeng; YANG Jingsui; XU Zhiqin; QI Xuexiang


    The boninite series volcanic rocks, mainly composed of basaltic andesite, andesitic lava breccia and andesite porphyrite, were recognized for the first time in the Bangong Lake ophiolite mé1ange, western Tibet. These rocks have a strong boninitic affinity, with high SiO2 (55.61%-59.23%,weight percent), MgO (6.63%-13.08%, 9.13% on average (weight percent)), A1203/1iO2 ratios (36-54), Mg# (0.61-0.74), Ni (116 ppm on average) and Cr (354 ppm on average)low TiO2 (0.23%-0.39%, weight percent), and strong LILEs enrichment relative to the depleted HFSEs. C1-chondrite normalized (La/Gd)N and (Gd/Yb)N ratios of about 1.70 and 0.83, respectively, produce prominent“U-shaped” normalized REE (rare earth element) patterns. Such a close compositional affinity to boninite indicates that these volcanic rocks were formed in a forearc setting produced by the intra-oceanic subduction.

  19. Microtextural and mineral chemical analyses of andesite–dacite from Barren and Narcondam islands: Evidences for magma mixing and petrological implications

    Indian Academy of Sciences (India)

    Dwijesh Ray; S Rajan; Rasik Ravindra; Ashim Jana


    Andesite and dacite from Barren and Narcondam volcanic islands of Andaman subduction zone are composed of plagioclase, orthopyroxene, clinopyroxene, olivine, titanomagnetite, magnesio-hornblende and rare quartz grains. In this study, we use the results of mineral chemical analyses of the calc-alkaline rock suite of rocks as proxies for magma mixing and mingling processes. Plagioclase, the most dominant mineral, shows zoning which includes oscillatory, patchy, multiple and repetitive zonation and ‘fritted’ or ‘sieve’ textures. Zoning patterns in plagioclase phenocrysts and abrupt fluctuations in An content record different melt conditions in a dynamic magma chamber. ‘Fritted’ zones (An55) are frequently overgrown by thin calcic (An72) plagioclase rims over well-developed dissolution surfaces. These features have probably resulted from mixing of a more silicic magma with the host andesite. Olivine and orthopyroxene with reaction and overgrowth rims (corona) suggest magma mixing processes. We conclude that hybrid magma formed from the mixing of mafic and felsic magma by two-stage processes initial intrusion of hotter mafic melt (andesitic) followed by cooler acidic melt at later stage.

  20. Upper cretaceous magmatic suites of the Timok magmatic complex

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    Banješević Miodrag


    Full Text Available The Upper Cretaceous Timok Magmatic Complex (TMC developed on a continental crust composed of different types of Proterozoic to Lower Cretaceous rocks. The TMC consists of the magmatic suites: Timok andesite (AT - Turonian-Santonian, Metovnica epiclastite (EM - Coniacian-Campanian, Osnić basaltic andesite (AO and Ježevica andesite (AJ - Santonian-Campanian, Valja Strž plutonite (PVS - Campanian and Boljevac latite (LB. The sedimentary processes and volcanic activity of the TMC lasted nearly continuously throughout nearly the whole Late Cretaceous. The sedimentation lasted from the Albian to the Maastrichtian and the magmatism lasted for 10 million years, from the Upper Turonian to the Upper Campanian. The volcanic front migrated from East to West. The volcanic processes were characterized by the domination of extrusive volcanic facies, a great amount of volcanic material, a change in the depositional environment during the volcanic cycle, sharp facial transitions and a huge deposition of syn- and post-eruptive resedimented volcaniclastics.

  1. Synergetic use of lignite fly ash and metallurgical converter slag in geopolymer concrete

    Directory of Open Access Journals (Sweden)

    Gábor Mucsi


    Full Text Available The application and utilization of the industrial wastes and by-products in the construction industry is a key issue from an environmental and economic point of view. The increased use of lignite has substantially increased the available quantities of lignite fired power plant fly ash, which can be mainly classified as class C fly ash. The utilization of such raw material however has some difficulties. In the present paper lignite fired power station fly ash and metallurgical converter slag were used for the production of geopolymer concrete. The fly ash was used as a geopolymer based binder material, and a converter slag as aggregate, thus created a geopolymer concrete which contains mainly industrial wastes. As preliminary test experimental series were carried out using andesite as aggregate. The optimal aggregate/binder ratio was determined. The effect of the amount of alkaline activator solution in the binder, the aggregate type on the geopolymer concretes’ compressive strength and density was investigated. Furthermore, the physical properties - freeze-thaw resistance and particle size distribution - of the applied aggregates were measured as well. As a result of the experiments it was found that physical properties of the andesite and converter slag aggregate was close. Therefore andesite can be replaced by converter slag in the concrete mixture. Additionally, geopolymer concrete with nearly 20 MPa compressive strength was produced from class C fly ash and converter slag.

  2. Geology, geochronology, and tectonic setting of the Jorullo Volcano region, Michoacán, México (United States)

    Guilbaud, Marie-Noëlle; Siebe, Claus; Layer, Paul; Salinas, Sergio; Castro-Govea, Renato; Garduño-Monroy, Victor Hugo; Le Corvec, Nicolas


    The Jorullo monogenetic volcano erupted 250 years ago at the southern border of the Trans-Mexican Volcanic Belt (TMVB), an area that records a long history of magmatic and tectonic activity. The oldest rocks that crop out in the area are early-Oligocene (32.7 ± 0.2 Ma) dioritic to granitic (60-72 wt.% SiO 2) plutons intruded by younger to contemporaneous (30.3 ± 0.1 and 33.3 ± 0.7 Ma) aplitic (76-78 wt.% SiO 2) dikes and mineralized veins. Volcanic rocks related to these intrusives form a thick sequence exposed in cliffs, from the base of which an altered andesite (58 wt.% SiO 2) was collected. The nearby epithermal Cu-mineralization of the Inguarán mining area to the southeast is also related to this Tertiary volcanic episode. The oldest expression of the TMVB in this area is represented by Pliocene (3.2-2.4 Ma) basaltic andesite to andesite (53-63 wt.% SiO 2) lavas (with pyroxene ± olivine) forming extensive mesas, eroded mounds, and thick elongate flows, that were unconformably deposited on top of the Oligocene rocks. Their emplacement was followed by erosion approximating a rate of 100 m/Ma over the past 3 Ma. This led to the formation of an inverted topography reflecting the higher resistance to erosion of these lavas that were originally deposited in valleys and today constitute prominent mesas. During the last 1 Ma, at least twenty-six monogenetic scoria cones formed in the study area, erupting about 10.2 km 3 of lava and pyroclastics dominantly composed of olivine and pyroxene-bearing andesites (61 vol.% DRE), lesser basaltic andesites (30 vol.% DRE), and a minority of olivine-rich basalts (10 vol.% DRE). These eruptive products include the K-rich basaltic trachyandesites of Cerro La Pilita, a scoria and lava cone located close to Jorullo. The ≤ 27 ka San Hilario and Esmeralda lavas, which are located 13 km southeast of Jorullo, are the southernmost eruptive products of the TMVB and also the youngest volcanoes after Jorullo in this area. Mapping of

  3. The `Strawberry Volcanic Field' of Northeastern Oregon: Another Piece of the CRB Puzzle? (United States)

    Steiner, A. R.; Streck, M. J.


    The Mid to Late Miocene Strawberry Volcanics field (SVF) located along the southern margin of the John Day valley of NE Oregon, comprise a diverse group of volcanic rocks ranging from basalt to rhyolite. The main outcrop area of the SVF (3,400 km2) is bordered by units from the Columbia River Basalt Group (CRBG), with the main CRB units to the north, the Picture Gorge Basalt to the east and Steens Basalt to the south. The geographic position and age of the Strawberry Volcanics make a genetic relationship to CRB volcanism likely, yet little is known about this diverse volcanic field. This research aims at refining the stratigraphic and age relationships as well as the petrology and geochemistry of magmas associated with the SVF. Previous investigations (e.g. Robyn, 1977) found that the SVF was active between 20 to 10 Ma with the main pulse largely being coeval with the 15 Ma CRBG eruptions. Lavas and tuffs from the SVF are calc-alkaline with low FeO*/MgO (~ 2.56 wt. %), high Al2O3 (~ 16.4 wt. %), low TiO2 (~ 1.12 wt.%), and span the entire compositional range from basalt to rhyolite (47-78 wt. % SiO2) with andesite as the dominant lithology. Basaltic lavas from the SVF have compositional affinities to earlier Steens Basalt, and some trace element concentrations and ratios are indistinguishable from those of CRBG lavas (e.g. Zr, Ba, Sr, and Ce/Y). Andesites are calc-alkaline, but contrary to typical arc (orogenic) andesites, SVF andesites are exceedingly phenocryst poor (Strawberry Volcanics are largely the product of hot-spot related basaltic magmas interacting with the continental crust. The range in compositions from calc-alkaline andesite to rhyolite may be attributed to the hybridization of mantle-derived and crustal melts, with the more evolved compositions reflecting greater proportions of crustally derived material and/or higher degrees of differentiation. Furthermore, since the earliest SVF eruption is 3 Ma older than the proposed onset of the CRBG (~ 17 Ma

  4. Experimental evidence of bulk chemistry constraint on SiO2 solubility in clinopyroxene at high-pressure conditions (United States)

    Kawasaki, Toshisuke; Osanai, Yasuhito


    We have experimentally confirmed that the solubility of SiO2 in clinopyroxene at ultrahigh-pressure metamorphic conditions is buffered by coesite and kyanite. The present findings were derived from high-pressure experiments on metapelite glass, powdered andesite and eclogite glass under anhydrous conditions. The metapelite glass and powdered andesite were recrystallised in boron nitride capsules at 8 GPa and 1100-1500 °C. The eclogite glass was heated in an AuPd capsule, both ends of which were welded, at 3 GPa and 1000 °C. Clinopyroxene nucleated from metapelite glass, the bulk composition of which is saturated in both SiO2 and Al2SiO5 components plotting within the Jd (Na,K)(Al,Cr)(Si,Ti)2O6-Qtz (Si,Ti)O2-Grt M3(Al,Cr)2(Si,Ti)3O12-Als (Al,Cr)2(Si,Ti)O5 tetrahedron (M = Fe, Mn, Mg, Ni, Zn, Ca), coexists with garnet, coesite and kyanite. The average excess silica content of the clinopyroxene ranges from 23.4 to 35.4 mol%. In contrast, an andesite experiment saturated in SiO2 but undersaturated in Al2SiO5 within the Jd-Qtz-Aug M(Si,Ti)O3-Grt tetrahedron produced clinopyroxene, garnet and coesite but no kyanite. The average excess silica in the clinopyroxene was 9.7-15.5 mol%, which is comparable to previous experimental data. Experiment on the eclogite glass with similar composition to andesite yielded clinopyroxene, garnet and coesite. An average excess silica content in clinopyroxene counts 6.4 mol%, which is much lower than that obtained from the andesite. The SiO2 content of clinopyroxene coexisting with garnet, coesite and kyanite is much higher than that of clinopyroxene coexisting with garnet and coesite without kyanite. Although the temperature dependence is unclear, the SiO2 solubility increases with pressure and Fe/(Fe+Mg). Clinopyroxene forms the solid solution series Jd-Es □0.5M0.5Al(Si,Ti)2O6 and Aug-Es, rather than Jd-Ts MAl2(Si,Ti)O6 and Es-Ts joins. Our experimental data suggest the probable existence of octahedral Si which may accompany the M2

  5. Origin of the ca. 90 Ma magnesia-rich volcanic rocks in SE Nyima, central Tibet: Products of lithospheric delamination beneath the Lhasa-Qiangtang collision zone (United States)

    Wang, Qing; Zhu, Di-Cheng; Zhao, Zhi-Dan; Liu, Sheng-Ao; Chung, Sun-Lin; Li, Shi-Min; Liu, Dong; Dai, Jin-Gen; Wang, Li-Quan; Mo, Xuan-Xue


    Bulk-rock major and trace element, Sr-Nd-Hf isotope, zircon U-Pb age, and zircon Hf isotopic data of the Late Cretaceous Zhuogapu volcanic rocks in the northern Lhasa subterrane provide a new insight into tectonic processes following the collision of the terrane with the Qiangtang zone. SHRIMP zircon U-Pb dating reveals that the Zhuogapu volcanic rocks crystallized at ca. 91 Ma, postdating the development of a regional angular unconformity between the Upper Cretaceous and the underlying strata in the Lhasa-Qiangtang collision zone. Compared to the Andean arc-type andesites and dacites, the Zhuogapu volcanic rocks are characterized by higher MgO of 2.78-5.86 wt.% and Mg# of 54-64 for andesites and MgO of 2.30-2.61 wt.% and Mg# of 55-58 for dacites. Eight andesite samples have whole-rock (87Sr/86Sr)i of 0.7054-0.7065, εNd(t) of - 3.2 to - 1.7, and εHf(t) of + 3.8-+ 6.4, similar to those of the three dacite samples with (87Sr/86Sr)i = 0.7056-0.7060, εNd(t) of - 2.7 to - 2.2, and εHf(t) of + 5.6-+ 7.0. Thirteen analyses from a dacite sample give positive zircon εHf(t) of + 5.6 to + 8.7. These signatures indicate that the Zhuogapu Mg-rich andesites were most likely derived from partial melting of a delaminated mafic lower crust (including the lowermost crust straddling the northern and central Lhasa subterranes) that led to the generation of the Zhuogapu primary melts with adakitic signatures and small negative εNd(t). Such melts subsequently experienced interaction of melt-asthenospheric mantle peridotite followed by the modification of highly fractionated magmas in shallow crustal magma chamber. Hornblende-controlled fractionation results in the change of geochemical composition from Mg-rich andesitic to Mg-rich dacitic magmas. Field observations, together with geochronological and geochemical data, indicate that the Zhuogapu Mg-rich volcanic rocks and coeval magmatism in the northern Lhasa subterrane may be the result of thickened lithospheric delamination

  6. The geology and petrology of Volcán San Juan (Nayarit, México) and the compositionally zoned Tepic Pumice (United States)

    Luhr, James F.


    Volcán San Juan is the westernmost Quaternary composite volcano in the Mexican Volcanic Belt. Its activity is divided into three stages of decreasing eruptive volume. During stage-1 activity, the main cone of San Juan and the adjacent Cerro Alto grew to a combined volume of ˜60 km 3 through eruption of hornblende-bearing andesites, dacites, and rhyodacites. Stage 1 included explosive eruptions of hornblende-dacite and an andesite dated at 33,750 a (years ago) and 23,010 a. Stage-2 activity involved a major Plinian eruption 14,770 a that produced the hypersthene-hornblende-bearing, compositionally zoned, rhyodacitic-andesitic Tepic Pumice and led to formation of an oval-shaped caldera 4×1 km in diameter. Tepic, the capital city of Nayarit State, with a population of ˜250,000, lies at the NE foot of Volcán San Juan. This location was buried under 2-9 m of rhyodacitic pumice-fall deposits from the Tepic Pumice eruption. Erosion has since removed virtually all exposures of Tepic Pumice >15 km from the caldera. The estimated volume of erupted tephra is 5.6 km 3, equivalent to 1.2 km 3 of magma. Modeling of the eruption dynamics indicates that as the eruption evolved the column height increased from ˜15 km to ˜24 km and maximum mass discharge rate increased from ˜3×10 6 kg/s to ˜6×10 7 kg/s. During stage-3 activity, a hornblende-andesitic lava dome partially filled the caldera and sent block lava flows down the north slope of the cone; total erupted volume was ˜0.55 km 3. Compared to other composite volcanoes of the western Mexican Volcanic Belt, the products from San Juan have the highest Sr contents and the lowest Rb, Y, Yb, and Lu contents, resulting in high La/Yb and Sr/Y, with low Rb/Sr. These observations indicate a strong slab-melt component at San Juan, consistent with its proximity to the Middle America Trench where young, hot lithosphere is subducting. The San Juan andesites, dacites, and rhyodacites also have relatively high 87Sr/ 86Sr, 206Pb/ 204

  7. Sr and Nd isotopic and trace element compositions of Quaternary volcanic centers of the southern Andes

    Energy Technology Data Exchange (ETDEWEB)

    Futa, Kiyoto; Stern, C.R.


    Isotopic compositions of samples from six Quaternary volcanoes located in the northern and southern extremities of the Southern Volcanic Zone (SVZ, 33-46/sup 0/S) of the Andes and from four centers in the Austral Volcanic Zone (AVZ, 49-54/sup 0/S) range for /sup 87/Sr//sup 86/Sr from 0.70280 to 0.70591 and for /sup 143/Nd//sup 144/Nd from 0.51314 to 0.51255. Basalts and basaltic andesites from three centers just north of the Chile Rise-Trench triple junction have /sup 87/Sr//sup 86/Sr, /sup 143/Nd//sup 144/Nd, La/Yb, Ba/La and Hf/Lu that lie within the relatively restricted ranges of the basic magmas erupted from the volcanic centers as far north as 35/sup 0/S in the SVZ of the Andes. The trace element and Sr and Nd isotopic characteristics of these magmas may be explained by source region contamination of subarc asthenosphere, with contaminants derived from subducted pelagic sediments and seawater-altered basalts by dehydration of subducted oceanic lithosphere. In the northern extremity of the SVZ between 33/sup 0/ and 34/sup 0/S, basaltic andesites and andesites have higher /sup 87/Sr//sup 86/Sr, Rb/Cs, and Hf/Lu, and lower /sup 143/Nd//sup 144/Nd than basalts and basaltic andesites erupted farther south in the SVZ, which suggests involvement of components derived from the continental crust. In the AVZ, the most primitive sample, high-Mg andesite from the southernmost volcanic center in the Andes (54/sup 0/S) has Sr and Nd isotopic compositions and K/Rb and Ba/La similar to MORB. The high La/Yb of this sample suggests formation by small degrees of partial melting of subducted MORB with garnet as a residue. Samples from centers farther north in the AVZ show a regionally regular northward increase in SiO/sub 2/, K/sub 2/O, Rb, Ba, Ba/La, and /sup 87/Sr//sup 86/Sr and decrease in MgO, Sr, K/Rb, Rb/Cs, and /sup 143/Nd//sup 144/Nd, suggesting increasingly greater degrees of fractional crystallization and associated intra-crustal contamination. (orig./SHOE).

  8. Sr and Nd isotopic and trace element compositions of Quaternary volcanic centers of the Southern Andes (United States)

    Futa, K.; Stern, C.R.


    Isotopic compositions of samples from six Quaternary volcanoes located in the northern and southern extremities of the Southern Volcanic Zone (SVZ, 33-46??S) of the Andes and from four centers in the Austral Volcanic Zone (AVZ, 49-54??S) range for 87Sr 86Sr from 0.70280 to 0.70591 and for 143Nd 144Nd from 0.51314 to 0.51255. The ranges are significantly greater than previously reported from the southern Andes but are different from the isotopic compositions of volcanoes in the central and northern Andes. Basalts and basaltic andesites from three centers just north of the Chile Rise-Trench triple junction have 87Sr 86Sr, 143Nd 144Nd, La Yb, Ba La, and Hf Lu that lie within the relatively restricted ranges of the basic magmas erupted from the volcanic centers as far north as 35??S in the SVZ of the Andes. The trace element and Sr and Nd isotopic characteristics of these magmas may be explained by source region contamination of subarc asthenosphere, with contaminants derived from subducted pelagic sediments and seawater-altered basalts by dehydration of subducted oceanic lithosphere. In the northern extremity of the SVZ between 33?? and 34??S, basaltic andesites and andesites have higher 87Sr 86Sr, Rb Cs, and Hf Lu, and lower 143Nd 144Nd than basalts and basaltic andesites erupted farther south in the SVZ, which suggests involvement of components derived from the continental crust. In the AVZ, the most primitive sample, high-Mg andesite from the southernmost volcanic center in the Andes (54??S) has Sr and Nd isotopic compositions and K Rb and Ba La similar to MORB. The high La Yb of this sample suggests formation by small degrees of partial melting of subducted MORB with garnet as a residue. Samples from centers farther north in the AVZ show a regionally regular northward increase in SiO2, K2O, Rb, Ba, Ba La, and 87Sr 86Sr and decrease in MgO, Sr, K Rb, Rb Cs, and 143Nd 144Nd, suggesting increasingly greater degrees of fractional crystallization and associated intra

  9. New constraints on the subsurface geology of the Mexico City Basin: The San Lorenzo Tezonco deep well, on the basis of 40Ar/39Ar geochronology and whole-rock chemistry (United States)

    Arce, J. L.; Layer, P. W.; Morales-Casique, E.; Benowitz, J. A.; Rangel, E.; Escolero, O.


    The San Lorenzo Tezonco deep well, drilled in 2012 by "Sistema de Aguas de la Ciudad de México" (Water Supply System of Mexico City) in the Mexico Basin to a depth of 2008 m, offers an excellent opportunity to explore the subsurface stratigraphy and general geology of the region. Unfortunately, only chipped samples from this well were recovered, which were examined and analyzed for whole-rock chemistry, 40Ar/39Ar, and U-Pb zircon geochronology, in order to reconstruct the lithology of the well. Contrary to previous deep wells of the Mexico Basin, no basement sedimentary rocks were found in this one. While the upper 70 m are composed of lacustrine sediments associated with Lake Texcoco, volcanic rocks make up the majority of the well and range in age from more than 18 Ma to 0.25 Ma. Andesitic lavas are the most abundant products of the stratigraphic column, followed by acidic products represented by dacitic and rhyolitic lavas and ignimbrite deposits. Less abundant are basaltic andesite lavas appearing in the upper and lower parts of the column. The thickest sequence of the well is represented not only by Miocene volcanic rocks ranging from 5 to 17 Ma, suggesting a period of intense volcanic activity in this area producing mainly andesitic lavas, but also by thick rhyolitic ignimbrite deposits dated at 5 Ma. These deposits suggest the presence of a caldera structure, probably buried by subsequent volcanic products and lacustrine sediments. Trace element concentrations suggest that volcanism is likely produced in a subduction environment with typical negative anomalies of Nb, Ta, Ti, and P and positive anomalies in Pb and Cs. We correlated the well units with units outcropping in mountain ranges in the surrounding area, with the recognition of the following units or formations: Eocene Andesite, San Nicolás Basaltic Andesite, Tepoztlán Formation, Miocene Volcanism, Sierra de las Cruces, and Chichinautzin Volcanic Field products. By correlating the two closest deep

  10. Petrology of the zoned calcalkaline magma chamber of Mount Mazama, Crater Lake, Oregon (United States)

    Druitt, T.H.; Bacon, C.R.


    Evolution of the magma chamber at Mount Mazama involved repeated recharge by two types of andesite (high-Sr and low-Sr), crystal fractionation, crystal accumulation, assimilation, and magma mixing (Bacon and Druitt 1988). This paper addresses the modal compositions, textures, mineral chemistry and magmatic temperatures of (i) products of the 6845??50 BP climactic eruption, (ii) blocks of partially fused granitoid wallrock found in the ejecta, and (iii) preclimactic rhyodacitic lavas leaked from the chamber in late Pleistocene and early Holocene time. Immediately prior to the climactic eruption the chamber contained ??? 40 km3 of rhyodacite (10 vol% plag + opx + aug + hb + mt + ilm, ???880?? C) overlying high-Sr andesite and cumulus-crystal mush (28-51 vol% plag + hb ?? opx ?? aug + mt ?? ilm, 880?? to ???950?? C), which in turn overlay low-Sr crystal mush (50-66 vol% plag + opx + aug ?? hb ?? ol + mt + ilm, 890?? to ???950??? C). Despite the well known compositional gap in the ejecta, no thermal discontinuity existed in the chamber. Pre-eruptive water contents of pore liquids in most high-Sr and low-Sr mushes were 4-6 wt%, but on average the high-Sr mushes were slightly richer in water. Although parental magmas of the crystal mushes were andesitic, xenocrysts of bytownite and Ni-rich magnesian olivine in some scoriae record the one-time injection of basalt into the chamber. Textures in ol-bearing scoriae preserve evidence for the reactions ol + liq = opx and ol + aug + liq(+ plag?) = hb, which occurred in andesitic liquids at Mount Mazama. Strontium abundances in plagioclase phenocrysts constrain the petrogenesis of preclimactic and climactic rhyodacites. Phenocryst cores derived from high-Sr and low-Sr magmas have different Sr contents which can be resolved by microprobe. Partition coefficients for plagioclase in andesitic to rhyolitic glasses range from 2 to 7, and increase as glass %SiO2 increases. Evolved Pleistocene rhyodacites (???30-25,000 BP) and

  11. Eruptive History of Volcán Tepetiltic, Mexico: Evidence for Remelting of Silicic Ashflows Revealed by 40Ar/39Ar Geochronology (United States)

    Frey, H. M.; Lange, R. A.; Hall, C. M.; Nelson, S. A.; Granados, H. D.


    Volcán Tepetiltic (VT) is located in the northwestern part of the Trans-Mexican Volcanic Belt and features an elliptical caldera (5 x 2.5 km). Previous detailed 40Ar/39Ar geochronology studies at V. Tequila and V. Ceboruco, showed that cone-building events occur within narrow time intervals (200 kyr between cone building episodes along the southern flank of the volcano. Following construction of the main stratocone (dominated by andesitic effusive activity), there was a clustering of rhyolite eruptions, including the caldera forming event which produced rhyolitic ashflow and airfall deposits. The age of the eruption is constrained by stratigraphic and cross-cutting relations. The eruption must be younger than 231 ± 36 kyr, based on the uppermost andesite dated from the caldera rim. The minimum age of the eruption is constrained by the occurrence of airfall from VT found underneath lava flows from the Amado Nervo shield volcano (220 ± 30 ka). Given these results, the Plinian eruption likely occurred ˜225 ± 40 kyrs ago. The two rhyolite obsidian domes on the eastern flanks of VT were dated at 307 ± 34 ka and 274 ± 52 ka and are thus similar in age or slightly older than the Plinian eruption. The >200 kyr hiatus between the construction of the andesite/dacite stratocone and the rhyolitic activity argues against crystal fractionation of the andesite to form the rhyolite. The upper crustal magma chamber feeding the main edifice ˜524 kyrs ago was likely short-lived (tens of kyrs), and may have crystallized to a granitoid. We suggest that the rhyolites formed ˜230 kyrs ago by partial melting of older shallow basement rhyolitic ashflows prevalent in the area. Evidence for this process is found in an unconsolidated pyroclastic flow from VT with pumiceous rhyolitic blocks and andesitic lithic fragments. Anorthoclase crystals in this deposit yield ages of 4.5 ± 0.34 Ma and 25.9 ± 0.24 Ma. Thus the rhyolites were likely produced by refusing of 4-5 Ma silicic

  12. Reconstructing multiple arc-basin systems in the Altai-Junggar area (NW China): Implications for the architecture and evolution of the western Central Asian Orogenic Belt (United States)

    Li, Di; He, Dengfa; Tang, Yong


    The Altai-Junggar area in northwestern China is a critical region to gain insights on the tectonic framework and geological evolution of the western Central Asian Orogenic Belt (CAOB). In this study, we report results from integrated geological, geochemical and geophysical investigations on the Wulungu Depression of the Junggar Basin to determine the basement nature of the basin and understand its amalgamation history with the Chinese Altai, within the broad tectonic evolution of the Altai-Junggar area. Based on borehole and seismic data, the Wulungu Depression is subdivided into two NW-trending tectonic units (Suosuoquan Sag and Hongyan High) by southward-vergent thrust faults. The Suosuoquan Sag consists of the Middle-Late Devonian basaltic andesite, andesite, dacite, tuff, tuffaceous sandstone and tuffite, and the overlying Early Carboniferous volcano-sedimentary sequence with lava flows and shallow marine sediments from a proximal juvenile provenance (zircon εHf(t) = 6.0-14.9), compared to the Late Carboniferous andesite and rhyolite in the Hongyan High. Zircon SIMS U-Pb ages for dacites and andesites indicate that these volcanics in the Suosuoquan Sag and Hongyan High erupted at 376.3 Ma and 313.4 Ma, respectively. The Middle-Late Devonian basaltic andesites from well LC1 are calc-alkaline and exhibit primitive magma-like MgO contents (7.9-8.6%) and Mg# values (66-68), with low initial 87Sr/86Sr (0.703269-0.704808) and positive εNd(t) values (6.6-7.6), and relatively high Zr abundance (98.2-116.0 ppm) and Zr/Y ratios (5.1-5.4), enrichment in LREEs and LILEs (e.g., Th and U) and depletion in Nb, Ta and Ti, suggesting that they were probably derived from a metasomatized depleted mantle in a retro-arc extensional setting. The well LC1 andesitic tuffs, well L8 dacites, well WL1 dacitic tuffs and well L5 andesites belong to calc-alkaline and metaluminous to peraluminous (A/CNK = 0.8-1.7) series, and display low Mg# values (35-46) and variably positive εNd(t) (4

  13. Mixing, Assimilation, Storage and Homogenization, Aeolian Islands, Italy: Evidence from In situ Plagioclase Data from Alicudi Island (United States)

    Hunt, R.; Bohrson, W. A.; Mayfield, A. M.; Creamer, J. B.


    In situ plagioclase data can provide time-transgressive information about petrogenetic processes that contribute to compositional diversity, thereby improving our ability to predict eruption style and to manage associated hazards. Alicudi, Aeolian Island Arc, Italy has a compositional range separated into 3 eruptive stages: stage 1 basalts; stage 2 basaltic andesites; stage 3 andesites (Peccerillo et al., 2004). Plagioclase from 10 samples that span this compositional and temporal range have been analyzed to elucidate magma chamber processes at this arc volcano. Through Nomarski Differential Interference Contrast imaging, 4 textural types were defined for each sample: simple oscillatory; complex oscillatory; sieved/patchy intermediate zone; sieve/patchy core. Andesitic plagioclase commonly exhibits patchy/sieve textures, whereas basaltic plagioclase commonly shows simple or complex oscillatory textures. Locations of core to rim major element analyses are based on textural boundaries. Microprobe results reveal ranges of An50-An88 in basalts, An42-An93 in basaltic andesites, and An45-An88 in andesites. Stage 1 and 2 cores and rims have a wide range in An. Stage 3 cores also have a wide range in An, but are dominated by lower values. In most samples, increasing An content of ≥10% is noted rimward of dissolution rims or within sieved/patchy zones, consistent with possible recharge events. Results of Tukey's Test (analysis of variance) suggest plagioclase crystals are related for stages 1 and 2. Stage 3 cores are unrelated to stage 1 and 2 cores. Laser Ablation Sr isotope data confirm variable 87Sr/86Sr for distinct textural types, and where possible, core and rim 87Sr/86Sr. Basalt plagioclase has the highest and most variable 87Sr/86Sr (0.70327-0.70375), whereas andesite plagioclase has the lowest and least variable (0.70284-0.70353). Whole rock 87Sr/86Sr (0.70316-0.70392) are consistent with in situ 87Sr/86Sr. Collectively, the data suggest mixing, assimilation

  14. Eruptive Productivity of the Ceboruco-San Pedro Volcanic Field, Nayarit, Mexico (United States)

    Frey, H. M.; Lange, R. A.; Hall, C. M.; Delgado-Granados, H.


    High-precision 40Ar/39Ar geochronology coupled with GIS spatial analysis provides constraints on magma eruption rates over the past 1 Myr of the Ceboruco-San Pedro volcanic field (1870 km2), located in the Tepic-Zacoalco rift in western Mexico. The volcanic field is part of the Trans Mexican Volcanic arc and is dominated by the andesitic-dacitic stratocone of Volcan Ceboruco and includes peripheral fissure-fed flows, domes, and monogenetic cinder cones. The ages of these volcanic features were determined using 40Ar/39Ar laser step-heating techniques on groundmass or mineral separates, with 78% of the 52 analyses yielding plateau ages with a 2 sigma error < 50 kyrs. The volumes were determined using high resolution (1:50,000) digital elevation models, orthophotos, and GIS software, which allowed for the delineation of individual volcanic features, reconstruction of the pre-eruptive topography, and volume calculations by linear interpolation. The relative proportions of the 80 km3 erupted over the past 1 Myr are 14.5% basaltic andesite, 64.5% andesite, 20% dacite, and 1% rhyolite, demonstrating the dominance of intermediate magma types (in terms of silica content). Overall, there appears to be no systematic progression in the eruption of different magma types (e.g., basalt, andesite, dacite, etc.) with time. However, more than 75% of the total volume of lava within the Ceboruco-San Pedro volcanic field erupted in the last 100 kyrs. This reflects the youthfulness of Volcan Ceboruco, which was constructed during the last 50 kyrs and has a present day volume of 50 +/- 2.5 km3, accounting for 81% of the andesite and 50% of the dacite within the volcanic field. Eleven cinder cones, ranging from the Holocene to 0.37 Ma, display a narrow compositional range, with 52-58 wt% SiO2, 3-5.5 wt% MgO, and relatively high TiO2 concentrations (0.9-1.8 wt%). The total volume of the cinder cones is 0.83 km3. No lavas with < 51 wt% SiO2 have erupted in the past 1 Myr. Peripheral

  15. Evolution and genesis of volcanic rocks from Mutnovsky Volcano, Kamchatka (United States)

    Simon, A.; Yogodzinski, G. M.; Robertson, K.; Smith, E.; Selyangin, O.; Kiryukhin, A.; Mulcahy, S. R.; Walker, J. D.


    This study presents new geochemical data for Mutnovsky Volcano, located on the volcanic front of the southern portion of the Kamchatka arc. Field relationships show that Mutnovsky Volcano is comprised of four distinct stratocones, which have grown over that past 80 ka. The youngest center, Mutnovsky IV, has produced basalts and basaltic andesites only. The three older centers (Mutnovsky I, II, III) are dominated by basalt and basaltic andesite (60-80% by volume), but each has also produced small volumes of andesite and dacite. Across centers of all ages, Mutnovsky lavas define a tholeiitic igneous series, from 48-70% SiO2. Basalts and basaltic andesites have relatively low K2O and Na2O, and high FeO* and Al2O3 compared to volcanic rocks throughout Kamchatka. The mafic lavas are also depleted in the light rare earth elements (REEs), with chondrite-normalized La/Sm arc volcanic rocks worldwide. Radiogenic isotope ratios (Sr, Nd, Pb, Hf) are similar for samples from all four eruptive centers, and indicate that all samples were produced by melting of a similar source mixture. No clear age-progressive changes are evident in the compositions of Mutnovsky lavas. Mass balance and assimilation-fractional crystallization (AFC) modeling of major and rare earth elements (REEs) indicate that basaltic andesites were produced by FC of plagioclase, clinopyroxene and olivine from a parental basalt, combined with assimilation of a melt composition similar to dacite lavas present at Mutnovsky. This modeling also indicates that andesites were produced by FC of plagioclase from basaltic andesite, combined with assimilation of dacite. Dacites erupted from Mutnovsky I and II have low abundances of REEs, and do not appear to be related to mafic magmas by FC or AFC processes. These dacites are modeled as the products of dehydration partial melting at mid-crustal levels of a garnet-free, amphibole-bearing basaltic rock, which itself formed in the mid-crust by emplacement of magma that

  16. Bimodal magmatism of the Tucumã area, Carajás province: U-Pb geochronology, classification and processes (United States)

    Silva, Fernando Fernandes da; Oliveira, Davis Carvalho de; Antonio, Paul Y. J.; D'Agrella Filho, Manoel S.; Lamarão, Claudio Nery


    Geological mapping of the Tucumã area has enabled the identification of dike swarms intruded into an Archean basement. The disposition of these dikes is consistent with the well-defined NW-SE trending regional faults, and they can reach up to 20 km in length. They were divided into three main groups: (i) felsic dikes (70% of the dikes), composed exclusively of porphyritic rhyolite with euhedral phenocrysts of quartz and feldspars immersed in an aphyric felsite matrix; (ii) mafic dikes, with restricted occurrence, composed of basaltic andesite and subordinate basalt, with a mineralogical assembly consisting dominantly of plagioclase, clinopyroxene, orthopyroxene and olivine; and (iii) intermediate rocks, represented by andesite and dacite. Dacites are found in outcrops associated with felsic dikes, representing different degrees of hybridization or mixture of mafic and felsic magmas. This is evidenced by a large number of mafic enclaves in the felsic dikes and the frequent presence of embayment textures. SHRIMP U-Pb zircon dating of felsic dikes yielded an age of 1880.9 ± 3.3 Ma. The felsic dikes are peraluminous to slightly metaluminous and akin to A2, ferroan and reduced granites. The intermediate and mafic dikes are metaluminous and belong to the tholeiitic series. Geochemical modeling showed that mafic rocks evolved by pyroxene and plagioclase crystallization, while K-feldspar and biotite are the fractionate phases in felsic magma. A simple binary mixture model was used to determine the origin of intermediate rocks. It indicated that mixing 60% of rhyolite and 40% basaltic andesite melts could have generated the dacitic composition, while the andesite liquid could be produced by mixing of 60% and 40% basaltic andesite and rhyolite melts, respectively. The mixing of basaltic and andesitic magmas probably occurred during ascent and storage in the crust, where andesite dikes are likely produced by a more homogeneous mixture at high depths in the continental crust

  17. Petrogenesis of Neoarchean metavolcanic rocks in Changyukou, Northwestern Hebei: Implications for the transition stage from a compressional to an extensional regime for the North China Craton (United States)

    Liou, Peng; Shan, Houxiang; Liu, Fu; Guo, Jinghui


    The 2.5 Ga metavolcanic rocks in Changyukou, Northwestern Hebei, can be classified into three groups based on major and trace elements: high-Mg basalts, tholeiitic basalts, and the calc-alkaline series (basaltic andesites-andesites and dacites-rhyolites). Both high-Mg basalts and tholeiitic basalts have negative anomalies of Nb, Zr, Ti and Heavy Rare Earth Elements (HREE) as well as enrichments of Sr, K, Pb, Ba and Light Rare Earth Elements (LREE) and show typical subduction zone affinities. The petrogenesis of high-Mg basalts can be ascribed to high-degree partial melting of an enriched mantle source in the spinel stability field that was previously enriched in Large Ion Lithophile Elements (LILE) and LREE by slab-derived hydrous fluids/melts/supercritical fluids, as well as the subsequent magma mixing processes of different sources at different source depths, with little or no influence of polybaric fractional crystallization. The flat HREE of tholeiitic basalts indicates they may also originate from the spinel stability field, but from obviously shallower depths than the source of high-Mg basalts. They may form at a later stage of the subduction process when rapid slab rollback leads to extension and seafloor spreading in the upper plate. We obtain the compositions of the Archean lower crust of the North China Craton based on the Archean Wutai-Jining section by compiling the average tonalite-trondhjemite-granodiorite (TTG) components, average mafic granulite components, and average sedimentary rock components. The modeling results show that the generation of high-Al basalts, basaltic andesites and andesites can be attributed to assimilation by high-Mg basalts (primary basalts) of relatively high-Al2O3 thickened lower crust and the subsequent crystallization of prevailing mafic mineral phases, while Al2O3-rich plagioclase crystallization is suppressed under high-pressure and nearly water-saturated conditions. Dacites and rhyolites may be the result of further

  18. Katmai volcanic cluster and the great eruption of 1912 (United States)

    Hildreth, W.; Fierstein, J.


    In June 1912, the world's largest twentieth century eruption broke out through flat-lying sedimentary rocks of Jurassic age near the base of Trident volcano on the Alaska Peninsula. The 60 h ash-flow and Plinian eruptive sequence excavated and subsequently backfilled with ejecta a flaring funnel-shaped vent since called Novarupta. The vent is adjacent to a cluster of late Quaternary stratocones and domes that have released about 140 km3 of magma in the past 150 k.y. Although the 1912 vent is closest to the Trident group and is also close to Mageik and Griggs volcanoes, it was the summit of Mount Katmai, 10 km east of Novarupta, that collapsed during the eruption to form a 5.5 km3 caldera. Many earthquakes, including 14 in the range M 6-7, took place during and after the eruption, releasing 250 times more seismic energy than the 1991 caldera-forming eruption of the Philippine volcano, Pinatubo. The contrast in seismic behavior may reflect the absence of older caldera faults at Mount Katmai, lack of upward (subsidence opposing) magma flow owing to lateral magma withdrawal in 1912, and the horizontally stratified structure of the thick shale-rich Mesozoic basement. The Katmai caldera compensates for only 40% of the 13 km3 of 1912 magma erupted, which included 7-8 km3 of slightly zoned high-silica rhyolite and 4.5 km3 of crystal-rich dacite that grades continuously into 1 km3 of crystal-rich andesite. We have now mapped, sampled, and studied the products of all 20 components of the Katmai volcanic cluster. Pyroxene dacite and silicic andesite predominate at all of them, and olivine andesite is also common at Griggs, Katmai, and Trident volcanoes, but basalt and rhyodacite have erupted only at Mount Katmai. Rhyolite erupted only in 1912 and is otherwise absent among Quaternary products of the cluster. Pleistocene products of Mageik and Trident and all products of Griggs are compositionally distinguishable from those of 1912 at Novarupta. Holocene products of Mount

  19. Le Pico de Orizaba (Mexique): Structure et evolution d'un grand volcan andesitique complexe (United States)

    Robin, C.; Cantagrel, J. M.


    Volcan Pico de Orizaba, which marks the eastern end of the Trans-Mexican Volcanic Belt, is one of the largest andesitic composite volcanoes in America. It is located above a series of crustal distensive faults making the boundary of the Coast Plains of the Gulf of Mexico from the Altiplano. For this reason, the volcano shows an asymmetry: from the west, its elevation is about 3,000 m whereas on the eastern side it reaches 4,000 to 4,500 m from its base. The Pico de Orizaba is composed of a primitive stratovolcano raised by a recent summit cone. It has been built by three very distinct volcanic and magmatic phases. 1. The first one, probably discontinuous effusive activity, lasted more than one million years. It is mainly composed of two pyroxenes-andesites with scarce associated basaltic and dacitic lava-flows. Amphibole is an accessory mineral in most differentiated lavas. On the eastern flank, numerous massive and autobrecciated lava-flows pass outward into thick conglomeratic formations. This effusive phase has built a primitive central volcano and a parasitic cone: the Sierra Negra. 2. The second phase is of short duration — about 100,000 years or less — in comparison with the first period. It seems that this period began with the formation of a caldera followed by the extrusion of amphibole dacite domes and the overflow of viscous silica-rich (andesite to dacite) lava flows on the northern flank. An intense explosive activity develops: pelean nuées ardentes are associated with extrusion of the domes; numerous plinian eruptions leading to widespread dacitic pumiceous air-falls are produced by both the central and the adventive volcanoes. This sequence of events is interpreted as the progressive emptying of a superficial chamber containing differenciated magma. A rhyolite flow erupted during this phase. 3. The age of the recent phase is better defined. It started 13,000 years B.P. with the eruption of a dacitic ash-flow containing pumice and scoria

  20. Magma genesis of the acidic volcanism in the intra-arc rift zone of the Izu volcanic arc, Japan (United States)

    Haraguchi, S.; Tokuyama, H.; Ishii, T.


    The Izu volcanic arc extends over 550 km from the Izu Peninsula, Japan, to the Nishinoshima Trough or Sofugan tectonic line. It is the northernmost segment of the Izu-Bonin-Mariana arc system, which is located at the eastern side of the Philippine Sea Plate. The recent magmatism of the Izu arc is bimodal and characterized by basalt and rhyolite (e.g. Tamura and Tatsumi 2002). In the southern Izu arc, volcanic front from the Aogashima to the Torishima islands is characterized by submarine calderas and acidic volcanisms. The intra-arc rifting, characterized by back-arc depressions, small volcanic knolls and ridges, is active in this region. Volcanic rocks were obtained in 1995 during a research cruise of the R/V MOANA WAVE (Hawaii University, cruise MW9507). Geochemical variation of volcanic rocks and magma genesis was studied by Hochstaedter et al. (2000, 2001), Machida et al (2008), etc. These studies focused magma and mantle dynamics of basaltic volcanism in the wedge mantle. Acidic volcanic rocks were also dredged during the curies MW9507. However, studies of these acidic volcanics were rare. Herein, we present petrographical and chemical analyses of these acidic rocks, and compare these results with those of other acidic rocks in the Izu arc and lab experiments, and propose a model of magma genesis in a context of acidic volcanism. Dredge sites by the cruise MW9507 are 120, and about 50 sites are in the rift zone. Recovered rocks are dominated by the bimodal assemblage of basalt-basaltic andesite and dacite-rhyolite. The most abundant phase is olivine basalt, less than 50 wt% SiO2. Andesites are minor in volume and compositional gap from 56 to 65 wt% SiO2 exists. The across-arc variation of the HFSE contents and ratios, such as Zr/Y and Nb/Zr of rhyolites exhibit depleted in the volcanic front side and enriched in reararc side. This characteristic is similar to basaltic volcanism pointed out by Hochstaedter et al (2000). The petrographical features of rhyolites

  1. An experimental study of permeability development as a function of crystal-free melt viscosity (United States)

    Lindoo, A.; Larsen, J. F.; Cashman, K. V.; Dunn, A. L.; Neill, O. K.


    Permeability development in magmas controls gas escape and, as a consequence, modulates eruptive activity. To date, there are few experimental controls on bubble growth and permeability development, particularly in low viscosity melts. To address this knowledge gap, we have run controlled decompression experiments on crystal-free rhyolite (76 wt.% SiO2), rhyodacite (70 wt.% SiO2), K-phonolite (55 wt.% SiO2) and basaltic andesite (54 wt.% SiO2) melts. This suite of experiments allows us to examine controls on the critical porosity at which vesiculating melts become permeable. As starting materials we used both fine powders and solid slabs of pumice, obsidian and annealed starting materials with viscosities of ˜102 to ˜106 Pas. We saturated the experiments with water at 900° (rhyolite, rhyodacite, and phonolite) and 1025 °C (basaltic andesite) at 150 MPa for 2-72 hrs and decompressed samples isothermally to final pressures of 125 to 10 MPa at rates of 0.25-4.11 MPa/s. Sample porosity was calculated from reflected light images of polished charges and permeability was measured using a bench-top gas permeameter and application of the Forchheimer equation to estimate both viscous (k1) and inertial (k2) permeabilities. Degassing conditions were assessed by measuring dissolved water contents using micro-Fourier-Transform Infrared (μ-FTIR) techniques. All experiment charges are impermeable below a critical porosity (ϕc) that varies among melt compositions. For experiments decompressed at 0.25 MPa/s, we find the percolation threshold for rhyolite is 68.3 ± 2.2 vol.%; for rhyodacite is 77.3 ± 3.8 vol.%; and for K-phonolite is 75.6 ± 1.9 vol.%. Rhyolite decompressed at 3-4 MPa/s has a percolation threshold of 74 ± 1.8 vol.%. These results are similar to previous experiments on silicic melts and to high permeability thresholds inferred for silicic pumice. All basaltic andesite melts decompressed at 0.25 MPa/s, in contrast, have permeabilities below the detection limit

  2. Igneous Petrogenesis of Tequila Volcano, Western Mexico (United States)

    Vázquez-Duarte, A.; Gómez-Tuena, A.; Díaz-Bravo, B.


    Tequila volcano belongs to a Quaternary volcanic chain that runs in parallel to the Middle American Trench, but that have been constructed within the so-called Tepic-Zacoalco rift: an extensional tectonic structure that has been active for the past 3.5 Ma. This unusual tectonic setting, and the existence of a high-resolution stratigraphy for the Tequila Volcanic Field (Lewis-Kenedi, 2005, Bull Volcanol), provide an excellent opportunity to study andesite petrogenesis. New comprehensive geochemical data allow the recognition of at least four different magmatic series around Tequila: 1) The Santa Rosa intraplate basalts (1.0 - 0.2 Ma), a volcanic plateau constructed along the Santiago River Fault north of Tequila volcano. These Na-alkaline basalts are olivine-phyric, have negligible subduction signatures (Ba/Nb= 11.75 - 49.36), and display Sr-Nd-Pb isotopic compositions that correlate with fractionation indexes, probably indicating melt-crust interactions. 2) A group of vitreous domes and flows of dacitic to rhyolitic compositions, mostly contemporaneous to the Santa Rosa basalts, that were emplaced on the periphery of Tequila volcano. These rocks can have very low Sr and Eu contents but their isotopic compositions are remarkably constant and similar to the Santa Rosa basalts, probably indicating a genetic link through low pressure fractionation in the stability field of plagioclase. 3) The main edifice of Tequila volcano (~0.2 Ma) is made of two pyroxene andesites and dacites with strong subduction signatures (Ba/Nb= 53-112), that inversely correlate with MgO contents, but that follow a diverging evolutionary trend as the rest of the sequences. The isotopic compositions of Tequila main edifice can extend to slightly more enriched values, but do not correlate with fractionation indexes, thus indicating provenance from a different source. 4) The youngest activity on Tequila volcano (~0.09 Ma) is represented by amphibole bearing andesites that erupted through the

  3. An overview of the 2009 eruption of Redoubt Volcano, Alaska (United States)

    Bull, Katharine F.; Buurman, Helena


    In March 2009, Redoubt Volcano, Alaska erupted for the first time since 1990. Explosions ejected plumes that disrupted international and domestic airspace, sent lahars more than 35 km down the Drift River to the coast, and resulted in tephra fall on communities over 100 km away. Geodetic data suggest that magma began to ascend slowly from deep in the crust and reached mid- to shallow-crustal levels as early as May, 2008. Heat flux at the volcano during the precursory phase melted ~ 4% of the Drift glacier atop Redoubt's summit. Petrologic data indicate the deeply sourced magma, low-silica andesite, temporarily arrested at 9-11 km and/or at 4-6 km depth, where it encountered and mixed with segregated stored high-silica andesite bodies. The two magma compositions mixed to form intermediate-silica andesite, and all three magma types erupted during the earliest 2009 events. Only intermediate- and high-silica andesites were produced throughout the explosive and effusive phases of the eruption. The explosive phase began with a phreatic explosion followed by a seismic swarm, which signaled the start of lava effusion on March 22, shortly prior to the first magmatic explosion early on March 23, 2009 (UTC). More than 19 explosions (or “Events”) were produced over 13 days from a single vent immediately south of the 1989-90 lava domes. During that period multiple small pyroclastic density currents flowed primarily to the north and into glacial ravines, three major lahars flooded the Drift River Terminal over 35 km down-river on the coast, tephra fall deposited on all aspects of the edifice and on several communities north and east of the volcano, and at least two, and possibly three lava domes were emplaced. Lightning accompanied almost all the explosions. A shift in the eruptive character took place following Event 9 on March 27 in terms of infrasound signal onsets, the character of repeating earthquakes, and the nature of tephra ejecta. More than nine additional

  4. The Ediacaran volcanic rocks and associated mafic dykes of the Ouarzazate Group (Anti-Atlas, Morocco): Clinopyroxene composition, whole-rock geochemistry and Sr-Nd isotopes constraints from the Ouzellarh-Siroua salient (Tifnoute valley) (United States)

    Belkacim, Said; Gasquet, Dominique; Liégeois, Jean-Paul; Arai, Shoji; Gahlan, Hisham A.; Ahmed, Hassan; Ishida, Yoshito; Ikenne, Moha


    Belonging to the huge Ouarzazate volcanic Group that covered the whole Anti-Atlas during the late Ediacaran (580-545 Ma), the Tifnoute valley volcanic formations are mainly pyroclastic and show a large composition, from trachybasalt to rhyolite and are crosscut by dolerite dykes. The Tifnoute valley volcanic rocks are located within a rigid salient of the Anti-Atlas that gives them special extreme characteristics. Due to the heavy greenschist alteration that affects this volcanic group, we focused the more immobile elements, but as REE can also be affected, we used the composition of unaltered clinopyroxene crystals to determine the nature of these volcanic rocks. The clinopyroxene is an augite diopside in the basalt, an augite in the andesite and an augite-salite in the dolerite. Petrography of the Tifnoute mafic volcanic rocks and clinopyroxene compositions indicate the presence of two magmatic series: (i) older high-K calc-alkaline (alkali-calcic) andesite and basalt characterized by the early crystallization of Fe-Ti oxides and of the late fractionation of plagioclase, the modal proportion of the latter increasing from the basalt to the andesite and (ii) younger alkalic dolerite dykes. With clinopyroxene trace element compositions obtained using laser ablation ICP-MS, we calculated the composition of the melts in equilibrium with the pyroxenes. The volcanic rocks of the Tifnoute Valley have positive εNd570 (+1.7 to +5.0), low Sri (volcanic rocks emplaced in a Pan-African transtensive post-collisional environment that evolved towards the major rifting event that will give rise to the Rheic ocean, in a similar way to what occurred just after the Variscan orogeny during the Triassic period that evolved to the Tethys ocean opening.

  5. Zircon U-Pb Age Determination of Volcanic Eruptions in Lutao and Lanyu in the Northern Luzon Magmatic Arc

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    Wen-Yu Shao


    Full Text Available This paper reports for the first time zircon U-Pb ages of volcanic rocks and sands from Lutao and Lanyu, two islets off SE Taiwan in the north Luzon arc. The samples include (1 seven andesites from four volcanic units and three river/beach sands from Lutao and (2 five basaltic andesites from four volcanic units and two river/beach sands from Lanyu. The Lutao andesites contain abundant magmatic zircons, aging from ~1.54 to ~1.24 Ma for individual sample, which yielded an overall mean 206Pb/238U age of 1.31 ±± 0.03 Ma (n = 190, MSWD = 2.6. This is slightly older than, or broadly coincident with, a mean 206Pb/238U age of 1.23 ±± 0.03 Ma (n = 103, MSWD = 1.9 given by detrital zircons from the three sands. The Lanyu volcanics appear to have less abundant magmatic zircons, aging from ~2.72 to ~2.35 Ma for individual sample, which yielded an overall mean 206Pb/238U age of 2.61 ±± 0.13 Ma (n = 11, MSWD = 1.8. This accords with a mean 206Pb/238U age of 2.69 ±± 0.11 Ma (n = 34, MSWD = 4.7 obtained by detrital zircons from the two sands. The age data suggest that in Lutao and Lanyu the major volcanic eruptions occurred at ~1.3 and ~2.6 Ma, respectively. Moreover, volcanic samples from both islets contain various amounts of older inherited zircons, ~11% in Lutao and up to ~82% in Lanyu, which together with detrital zircons from the sands show main age peaks at ~150 Ma and ~1.9 and ~2.5 Ga, consistent with the notion for a _ continental crust involved in the genesis of the northern Luzon magmatic arc.

  6. Mantle temperature control on composition of arc magmas along the Central Kamchatka Depression (United States)

    Portnyagin, Maxim; Constantin Manea, Vlad


    Abundant volcanism in the Central Kamchatka Depression (CKD)adjacent to the Kamchatka-Aleutian Arc junction occurswhere the Pacific slab edge is subducting beneath Kamchatka.Here we summarize published data on CKD rocks and demonstratea systematic south-to-north change of their compositions frommoderately fractionated basalt-andesite tholeiitic series tohighly fractionated basalt-rhyolite calc-alkaline series includinghigh-magnesian andesites near the slab edge. Localized slabmelting at the slab edge cannot explain these regional geochemicalvariations. Instead, we propose that the thermal state of themantle wedge can be the key factor governing the compositionof CKD magmas. We integrate the results from petrology and numericmodeling to demonstrate the northward decrease of the mantlewedge temperatures beneath CKD volcanoes, which correlates withdecreasing slab dip, length of mantle columns, and magma flux.We envision two petrogenetic models, which relate the compositionof erupted magmas to the subduction parameters beneath the CKD.The first model suggests that mantle temperature governs melt-peridotiteequilibria and favors generation of andesitic primary meltsin cold mantle regions above the shallowly subducting Pacificslab edge. Alternatively, mantle temperature may control magmaticproductivity along the CKD, which decreases sharply toward theslab edge and thus allows more extensive magma fractionationdeeper in the crust and mixing of highly evolved and mantle-derivedmagmas to generate Si-rich "primitive" magmas. These resultspoint to a possible casual link between deep mantle and shallowcrustal magmatic processes. Similar effects of mantle temperatureon the composition and productivity of arc magmatism are expectedelsewhere, particularly in volcanic regions associated withsignificant slab dip variation along the arc.

  7. Comparison of element and isotope diffusion of K and Ca in multicomponent silicate melts (United States)

    van der Laan, Sieger; Zhang, Youxue; Kennedy, Allen K.; Wyllie, Peter J.


    Recent experimental work has shown that the homogenization of elemental concentrations can be much slower than that of isotopic ratios when there are strong concentration gradients in SiO 2 and Al 2O 3. The ramifications of this result for magma homogenization and other petrological problems related to diffusion are significant. We report here a comparison of experimental profiles of elemental concentrations and isotopic fractions of K and Ca in rhyolite-andesite (large concentration gradients) and rhyolite-rhyolite (small concentration gradients) melt couples. When the concentration profile and the isotopic profile of the same element in a single couple are compared, the former is much shorter than the latter in the rhyolite-andesite couple, consistent with other recent studies. However, the lengths of both concentration and isotopic profiles are similar in the rhyolite-rhyolite couple. Therefore, diffusion of an element or oxide may be decoupled from or coupled with isotopic 'diffusion', depending on whether large concentration gradients of major components are present. When the two couples are compared, the intrinsic effective binary diffusivities obtained from isotopic profiles are similar for each element in the two couples, whereas the effective binary diffusivity of K obtained from the concentration profile in the rhyolite-rhyolite couple is 37 times that in the rhyolite-andesite couple. Therefore, isotopic homogenization is roughly independent of elemental homogenization and the presence of SiO 2, Al 2O 3, and other concentration gradients, whereas elemental homogenization is strongly affected by concentration gradients. Our experimental data (isotopic and concentration profiles including uphill diffusion profiles) can be modeled quantitatively to a good approximation using a modified effective binary diffusion model in which the flux of a component is assumed to be proportional to its activity gradient instead of its concentration gradient. Therefore, the

  8. Water-rich and volatile-undersaturated magmas at Hekla volcano, Iceland (United States)

    Lucic, Gregor; Berg, Anne-Sophie; Stix, John


    Olivine-hosted melt inclusions from four eruptions at Hekla volcano in Iceland were analyzed for their dissolved H2O, CO2, S, and Cl contents. A positive correlation among the repose interval, magmatic evolution, and volatile contents of magmas is revealed. H2O is the dominant volatile species; it behaves as an incompatible component, increasing in concentration over time as a result of fractional crystallization in the magma. The full suite of H2O contents ranges from a low of 0.80 wt % in basaltic andesites to a maximum of 5.67 wt % in rhyolites. Decreasing H2O/K2O at fixed major element compositions suggests that syneruptive degassing reduces H2O contents significantly. Hekla magmas are CO2 poor, with very low concentrations present only in the most evolved compositions (˜20-30 ppm or less). The decrease in S content from basaltic andesite to rhyolite demonstrates that sulfide saturation is attained when the melt composition reaches basaltic andesite, resulting in the precipitation of pyrrhotite. Low CO2/Nb ratios suggest that vapor saturation is most likely reached during an early period of cooling and solidification in the crust. Fresh injections of mafic magma interact with previously solidified intrusives, producing new melts that are volatile undersaturated. Vapor saturation pressures obtained using the most volatile-rich melt inclusions suggest the presence of a magma chamber at a minimum depth of ˜7 km. This is in agreement with geophysical observations from recent small-volume eruptions, but given the possibility of volatile-undersaturated melts, some of the magmas may reside at greater depths.

  9. Dynamics and pre-eruptive conditions of catastrophic, ignimbrite-producing eruptions from the Yenkahe Caldera, Vanuatu (United States)

    Firth, Chris W.; Cronin, Shane J.; Turner, Simon P.; Handley, Heather K.; Gaildry, Clement; Smith, Ian


    A combined stratigraphic and geochemical examination of ~ 43 kyr of volcanic activity is presented for the Yenkahe Caldera, a mafic-intermediate volcanic system on the island of Tanna, in the Vanuatu Arc. Through this period two catastrophic ignimbrite-producing eruptions have occurred: the Siwi eruption and the older, Old Tanna Ignimbrite eruption. The latter was previously linked with a different edifice to the north-east, however re-examination has shown it was derived from the Yenkahe Caldera. Radiocarbon dating of this ignimbrite gives an age of ~ 43 kyr B.P. Both eruptions produced voluminous ignimbrite sheets, however differences in deposit sequences show that the eruptions followed distinct courses. Deposits from the more recent Siwi eruption display greater evidence for phreatomagmatic phases during eruption onset. Both ignimbrites are distributed asymmetrically about the caldera, indicating partial collapse in each case. The early stages of the Siwi eruption produced directed pyroclastic surges and spatter fountains. Between these two major eruptions, volcanic activity was maintained through the formation of small, discrete volcanic cones, such as Yasur, which is active today. Whole rock major and trace element data show that intra-caldera activity between cataclysmic eruptions produced magmas of uniform basaltic-trachy-andesitic composition (SiO2 ~ 56 wt.%). Minerals within these lavas appear to be in equilibrium with their host. The Siwi eruption produced the most evolved, trachy-andesitic magma (SiO2 > 58 wt.%), while the Old Tanna eruption is associated with less evolved, basaltic-andesite magma (SiO2 ~ 53 wt.%). Juvenile clasts from both ignimbrites display diverse mineral chemistry and mineral disequilibrium textures. From these variations in geochemistry and petrology we suggest that a crystal mush or resident magma remained following low-magnitude, intra-caldera activity. MELTS modelling suggest that this was stored at shallow depths, equivalent

  10. Production of hybrid granitic magma at the advancing front of basaltic underplating: Inferences from the Sesia Magmatic System (south-western Alps, Italy) (United States)

    Sinigoi, Silvano; Quick, James E.; Demarchi, Gabriella; Klötzli, Urs S.


    The Permian Sesia Magmatic System of the southwestern Alps displays the plumbing system beneath a Permian caldera, including a deep crustal gabbroic complex, upper crustal granite plutons and a bimodal volcanic field dominated by rhyolitic tuff filling the caldera. Isotopic compositions of the deep crustal gabbro overlap those of coeval andesitic basalts, whereas granites define a distinct, more radiogenic cluster (Sri ≈ 0.708 and 0.710, respectively). AFC computations starting from the best mafic candidate for a starting melt show that Nd and Sr isotopic compositions and trace elements of andesitic basalts may be modeled by reactive bulk assimilation of ≈ 30% of partially depleted crust and ≈ 15%-30% gabbro fractionation. Trace elements of the deep crustal gabbro cumulates require a further ≈ 60% fractionation of the andesitic basalt and loss of ≈ 40% of silica-rich residual melt. The composition of the granite plutons is consistent with a mixture of relatively constant proportions of residual melt delivered from the gabbro and anatectic melt. Chemical and field evidence leads to a conceptual model which links the production of the two granitic components to the evolution of the Mafic Complex. During the growth of the Mafic Complex, progressive incorporation of packages of crustal rocks resulted in a roughly steady state rate of assimilation. Anatectic granite originates in the hot zone of melting crust located above the advancing mafic intrusion. Upward segregation of anatectic melts facilitates the assimilation of the partially depleted restite by stoping. At each cycle of mafic intrusion and incorporation, residual and anatectic melts are produced in roughly constant proportions, because the amount of anatectic melt produced at the roof is a function of volume and latent heat of crystallization of the underplated mafic melt which in turn produces proportional amounts of hybrid gabbro cumulates and residual melt. Such a process can explain the

  11. Subduction-related oceanic crust in the Khantaishir ophiolite (western Mongolia). (United States)

    Gianola, O.; Schmidt, M. W.; Jagoutz, O. E.


    Most of the oceanic crust is generated at mid oceanic ridges and only a minor portion results from magmatism related to subduction zones (i.e. back-arc basins or in incipient arcs). However it has been observed that several ophiolites preserve an oceanic crust displaying a subduction zone signature. Such a signature is also found in the Khantaishir ophiolite located in western Mongolia. This ~570 m.y. old ophiolite is ~480 km2 in size and displays a complete sequence, tectonically slightly dismembered during the emplacement process. The ophiolite exposes ~130 km2 of highly refractory harzburgitic mantle with local dunite channels and lenses. Towards its top the mantle is replaced by sub-horizontal km-wide discrete zones of pyroxenites situated either in the mantle or forming a crust-mantle transition zone overlain by gabbros. The crust is then composed of various gabbros and minor gabbronorite (both in part replaced by pyroxenites and/or cut by intermediate dykes), by a dyke/sill-complex and by pillow lavas. The entire ophiolite is re-equilibrated at lower greenschist facies conditions. Major and trace elements of the crustal rocks of the Khantaishir ophiolite show trends similar to those observed for the Izu-Bonin-Mariana subduction system. Mafic dykes/sills and pillow lavas of the Khantaishir ophiolite have overall basaltic-andesite compositions, resembling high-Mg andesites with an average SiO2 of 57 wt%. Their low TiO2 (high-Mg andesites and boninites from modern island arcs. This evidence suggests that the Kantaishir crust might represent the submarine initial stage of an incipient arc, probably when the preexisting oceanic crust is spread and incipient island arc crust is formed.

  12. Slab Contributions to Cascades Magmas: Constraints from Central Oregon and Northern California (United States)

    Ruscitto, D. M.; Wallace, P. J.


    The Cascades arc is the global end member, warm-slab subduction zone (slab thermal parameter ~200 km) resulting from the slow subduction of young oceanic crust beneath North America. Significant slab dehydration is predicted to occur beneath the forearc (high-Mg andesite (HMA) and primitive basaltic andesite (PBA) with 3.3 and 5.6 wt.% H2Omax, respectively. Three distinct primitive melt compositions were calculated using inclusions from Central Oregon: calc-alkaline basalt, Sr-rich basalt, and depleted basaltic andesite (1.6, 2.3, and 3.0 wt.% H2Omax, respectively). We calculated extents of mantle melting for each primitive magma composition using Ti, Y, Gd, Dy, Er, and Yb contents (i.e., assuming negligible contributions from the slab). Based on these calculations, we infer Central Oregon and Shasta magmas to represent 8-15% and 14-20% partial melts (respectively) of variably depleted sources. Major elements in preliminary slab components from Central Oregon are H2O (~39-45 wt.%), Na2O (~36-47 wt.%), K2O (~8-15 wt.%), and Cl (~1.0-3.8 wt.%) and similar to the slab component calculated for Shasta HMA. The slab component calculated for Shasta PBA is more volatile-rich with ~62 wt.% H2O, ~28 wt.% Na2O, ~5.3 wt.% K2O, and 4.6 wt.% Cl. Calculated slab components are similar to previously published estimates from the Shasta region and experimental high temperature (>800 °C) fluids/melts derived from altered oceanic crust and/or sediments. Compositional proxies for slab surface temperatures (H2O/K2O and H2O/Ce) are at the high temperature range of the global arc spectrum, corresponding to temperatures of 850-950 °C, and are consistent with a young, hot incoming plate.

  13. Shallow electrical resistivity imaging of the Limón fault, Chagres River Watershed, Panama Canal (United States)

    Mojica, Alexis; Pérez, Tatiana; Toral, Jaime; Miranda, Roberto; Franceschi, Pastora; Calderón, Carlos; Vergara, Fidedigna


    The aim of this study was the use of electrical resistivity imaging to investigate the geometry of the southwest portion of one of the most important geologic fault zones of the Panama Canal Watershed: the Limón fault. This fault is characterized by its juxtaposition of pre-Tertiary andesitic basalt (Playa Venado Formation) against late Oligocene Tertiary sediments (Caimito Formation). In this zone, four 2D electrical resistivity tomography profiles were conducted perpendicular to the fault trace: T-1, T-2, T-3 and T-4. The T-1, T-3, and T-4 profiles were long profiles (235 m for the first two and 215 m for the last one), with a goal of determining the depth of the geologic boundary between the sedimentary and andesitic deposits. The T-2 profile was a short profile (23.5 m), with the objective of calibrating the results with data provided by the paleoseismic trenching previously developed in the area of interest. For these tests, two electrode arrays of types Wenner-Schlumberger and Dipole-Dipole, were used. For the inversion routine, two regularized least-squares methods were used: the smoothness-constrained method and robust inversion. The long electrical resistivity tomography profiles were able to identify a set of electrical anomalies associated with the andesitic basalt and the Tertiary sediments and with that, the contact geometry between these formations. In these profiles, fault angle measurements ranged from 60° to 80° with respect to the ground surface. In the T-2 profile, the electrical anomalies showed a good association with the results of the paleoseismic study. This allowed identification of the colluvium and alluvium covering the gravel and sand debris that mark the gradual transition to the soils of the Caimito Formation. Finally, a set of 2D synthetic models was developed for each of the T-1, T-3, and T-4 profiles with the objective of optimizing interpretation of the field results.

  14. Petrology, mineral chemistry and tectono-magmatic setting of volcanic rocks from northeast Farmahin, north of Arak

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    Reza Zarei Sahamieh


    Full Text Available Introduction The study area is a small part of the Urumieh-Dokhtar structural zone in the Markazi province, located in the northeastern part of the Farmahin, north of Arak (Hajian, 1970. The volcanic rocks studied from the area include andesite, dacite, rhyodacite, ignimbrite and tuff of Middle to Late Eocene age (middle Lutetian to upper Lutetian (Ameri et al., 2009. It seems that folding and faulting is caused in sedimentary basin and volcanic activities. On the other hand, except of orogeny maybe rifting had rule in eruption so that this case has seen in the other area such as Taft and Khezrabad in central Iran (Zarei Sahamieh et al., 2008. The oldest formation in the studied area is Triassic limestones. The dominant textures of these rocks are porphyritic, microlite porphyritic, microlitic and rarely sieve-texture. Sieve texture and dusty texture (dusty plagioclases indicates magma mixing. Mineralogically, they contain plagioclases, clinopyroxenes, amphiboles, quartz and biotite as the main constituents and zircon, apatite, and opaque minerals as accessories. Plagioclases in the andesitic and basaltic- andesite rocks are labradorite, bytownite and anorthite (based on electron microprobe .Moreover, plagioclases in andesitic rocks show that H2O is lesser than 2.5 precent. Amphibole is found in both plagioclases and groundmass. Materials and methods In this article are used different analyses methods such as XRF, ICP-MS and EPMA. Whole-rock major and trace element analyses were determined with ICP-MS method. The major and trace element composition of some rock was determined by electron probe micro-analysis (EPMA using a Cameca SX100 instrument in Iran Mineral Processing Research Center (IMPRC. Moreover, whole-rock major and some trace element analyses for some samples were obtained by X-ray fluorescence (XRF, using an ARL Advant-XP automated X-ray spectrometer. Results Chemical data based on electron micro probe studies of minerals indicate

  15. Chronology and Geochemistry of Volcanic Rocks in the Cretaceous Suifenhe Formation in Eastern Heilongjiang, China

    Institute of Scientific and Technical Information of China (English)

    JI Weiqiang; XU Wenliang; YANG Debin; PEI Fuping; JIN Ke; LIU Xiaoming


    Zircon U-Pb ages and geochemical data of volcanic rocks in the Suifenhe Formation in eastern Heilongjiang Province are reported, and their petrogenesis is discussed in this paper. The Suifenhe Formation mainly consists of basalt, andesite, and dacite. Zircon from andesite and dacite are euhedral in shape and show typical oscillatory zoning with high Th/U ratios (0.18-0.57), implying its magmatic origin. Zircon U-Pb dating results by laser ablation inductively coupled plasma mass spectrometer (LA-ICP-MS) indicate that the 206Pb/238U ages of zircons from andesite range within 105-106 Ma, yielding a weighted mean age of 105.5±0.8 Ma (n=14), and that 206Pb/238U ages of zircons from dacite are between 90-96 Ma, yielding a weighted mean age of 93.2±1.3 Ma (n =13). The volcanic rocks from the Suifenhe Formation are subalkaline series and show a calc-alkaline evolutionary trend with SiO2 content of 47.69%-65.47%, MgO contents of 1.42%-6.80% (Mg#= 45-53), and Na2O/K2O ratios of 1.83-3.63. They are characterized by enrichment in large ion lithophile elements (LILE) and lightrare-earth elements (LREE), depletion in heavy rare earth elements (HREE) and high field strength elements (HFSE) (e.g., Nb, Ta, Ti), and low initial 87Sr/86Sr ratios (0.7041-0.7057) and positive εNd(t)values (0.39-4.08), implying that they could be derived from a depleted magma source. Taken together,these results suggest that the primary magma of the volcanic rocks might originate from partial melting of the mantle wedge metasomatized by fluids derived from subducted slab under a tectonic setting of active continental margin.

  16. Účinok tektoniky mladších štvrtohôr na pokles riečneho koryta medzi Rajkou a Budapešťou v Maďarsku


    Czigány, Sz.; Gyenizse, P.; Lovász, G.


    Results of the effect of subsidence of the Little Hungarian Plain on vertical movement of the riverbed and the downstream riverbed slope changes of the regulated flowchannel of Danube are presented. Subsidence of the flowchannel is also affected by the tectonic movements. The subsidence rate is attenuated by the andesitic Börzsöny and Visegrád Mountains since they function as natural barriers for the river. In the eastern vicinity of the Börzsöny and the Mátra, where the river flows in loose,...


    Directory of Open Access Journals (Sweden)

    Arief Mustofa Nur


    Full Text Available Diabas Parang hill is one of location which conservated in area conservation of geological Karangsambung.Now, it is threatened, because there are many mines at surrounding it. Activities of mining not care science andenvironmental conservation.Impact of mining so cause change of topography/morphology, slope become more steep, and mining locationbecome potentially accure rock fall and landslide. Pursuant to result of laboratory analysis, engineeringproperties diabas Parang hill strongless than andesit so it is only fulfil for trotoir.For diabas conservation which is protected so need affort to stop activity of mining. The effort can do seekingaltenative location for mine and/or to change mine activities.

  18. Archaeomagnetic Investigation at Chapultepec, Mexico City: Case Study of Classical Settlers (United States)

    Lopez, V.; Romero, E.; Soler-Arechalde, A. M.; Espinosa, G.


    During the restoration campaign at the Chapultepec Park in Mexico City downtown, a teotihuacan settlement was found at the south flank of Chapultepec Hill. Samples represent a kind of irregular home kilns with a hole in their central part bounded by andesite rocks. Alternating field demagnetization had been employed. Rock magnetic measurements which included: Hysteresis, continuous susceptibility and isothermal remanence experiments revealed that some spinels, most probably magnetite or Ti-poor Titanomagnetites are responsible for the remanence. An archeomagnetic date obtained here is of 525 AD which is in good agreement with other evidences of the Teotihuacan Classic Metepec period (450-600 AD).

  19. Zeolites replacing plant fossils in the Denver formation, Lakewood, Colorado. (United States)

    Modreski, P.J.; Verbeek, E.R.; Grout, M.A.


    Well-developed crystals of heulandite and stilbite, within fossil wood, occur in sedimentary rocks in Lakewood, Jefferson County. The rocks belong to the Denver formation, a locally fossiliferous deposit of fluvial claystone, siltstone, sandstone and conglomerate, containing some volcanic mudflows (andesitic) of late Cretaceous to Palaeocene age. Altered volcanic glass released Na and Ca into the ground-water and subsequently zeolites were crystallized in the open spaces between grains and within fossil plant structures. Minor pyrite, quartz (jasper), calcite and apatite also occur as replacements of fossil wood. Similar zeolite occurrences in other areas are reviewed.-R.S.M.

  20. Modeling of micrometeoric streams under the action of the high-power laser pulse on multicomponent polycrystal rocks (United States)

    Timofeev, I. S.; Burdonskiy, I. N.; Goltsov, A. Yu; Leonov, A. G.; Makarov, K. N.; Yufa, V. N.


    The paper presents the analysis of interaction of the high-power laser pulse with multicomponent polycrystal rocks. Experiments were completed on a laser facility “Saturn” with intensity of 1010-1013 W/cm2. Structural analysis of the materials from the spall crater and from the plasma flame show significant differences. The article demonstrates experimental results of the spall formation moment depending on the thickness of the radiated target. The scale of damage to aluminium 6 pm thick foil at the rare side of the target is illustrated when it is hit by the andesite fragments from a spall crater.

  1. Emanation Study of Gas Radon on the Ancient Cuexcomate Geyser in Puebla City, Mexico

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    J. A. Monarca Serrano


    Full Text Available Radon measurements were collected over a period of nine months in the area of the ancient Cuexcomate geyser, in Puebla City. For measuring radon, the passive method of nuclear tracks in solids was used, using polycarbonate CR-39 as radiation sensitive material. Radon concentrations varied in strong anti-correlation with the rainfall intensity. And are lower compared to other locations, in concordance with the stratigraphic composition, as travertine and deposits of volcanic origin, corresponding to the geyser chemical composition and the active environment in the north part of the Trans-Mexican Volcanic Belt with an andesitic and basalt composition.

  2. A/E/C CAD Standard, Release 5.0 (United States)


    Steel reinforcing, welded wire fabric 0 0.70 5 1 X X X X X X X X X X S-REIN-TEND-HORZ Horizontal Tendons 0 0.50 181 185 X X X S-REIN-TEND-VERT Vertical...Intercom ........................... D1-13 INTRLK – Interlock Steel Members ... D1-13 IWASTE – Industrial Waste ................ D1-13 LADDER – Cable...D2-3 ALUMIN – Aluminum .......................... D2-3 ANDES – Andesite ............................... D2-3 ASHLER – Stone Ashler

  3. Update of map the volcanic hazard in the Ceboruco volcano, Nayarit, Mexico (United States)

    Suarez-Plascencia, C.; Camarena-Garcia, M. A.; Nunez-Cornu, F. J.


    The Ceboruco Volcano (21° 7.688 N, 104° 30.773 W) is located in the northwestern part of the Tepic-Zacoalco graben. Its volcanic activity can be divided in four eruptive cycles differentiated by their VEI and chemical variations as well. As a result of andesitic effusive activity, the "paleo-Ceboruco" edifice was constructed during the first cycle. The end of this cycle is defined by a plinian eruption (VEI between 3 and 4) which occurred some 1020 years ago and formed the external caldera. During the second cycle an andesitic dome built up in the interior of the caldera. The dome collapsed and formed the internal caldera. The third cycle is represented by andesitic lava flows which partially cover the northern and south-southwestern part of the edifice. The last cycle is represented by the andesitic lava flows of the nineteenth century located in the southwestern flank of the volcano. Actually, moderate fumarolic activity occurs in the upper part of the volcano showing temperatures ranging between 20° and 120°C. Some volcanic high frequency tremors have also been registered near the edifice. Shows the updating of the volcanic hazard maps published in 1998, where we identify with SPOT satellite imagery and Google Earth, change in the land use on the slope of volcano, the expansion of the agricultural frontier on the east sides of the Ceboruco volcano. The population inhabiting the area is 70,224 people in 2010, concentrated in 107 localities and growing at an annual rate of 0.37%, also the region that has shown an increased in the vulnerability for the development of economic activities, supported by highway, high road, railroad, and the construction of new highway to Puerto Vallarta, which is built in the southeast sector of the volcano and electrical infrastructure that connect the Cajon and Yesca Dams to Guadalajara city. The most important economic activity in the area is agriculture, with crops of sugar cane (Saccharum officinarum), corn, and jamaica

  4. Major, Trace, and Rare Earth Element Abudances in Boninitic Lavas from the Ogasawara Forearc



    Dredged andesites and dacites from the Ogasawara forearc contain high abundances of MgO at high SiO2, high K2O, low rare earth element abundances and flat patterns, and very low TiO2 contents. The chemical character and geologic setting support the interpretation that these lavas are evolved members of the boninite series formed by high degrees of partial melting of a previously depleted arc source, followed by enrichment in K, Th, and large-ion lithophile elements, and finally differentiated...

  5. MX Siting Investigation. Geotechnical Evaluation. Aggregate Resources Study, Whirlwind Valley, Utah. (United States)


    andesitic flows (Vb) within and east of the Little Drum Mountains in the north and south of Delta along the eastern boundary. I The useability of any of...accomo- date accuracy of data and map scale and may contain deposits which could supply significant quantities of high quality materials. A conversion...12 -12 --12 COARSE AGGREGATE SOUNDNESS, MR SO4 - 8 ’-16 - 18 PERCENT LOSS’ Na SO4 - 10 ’.10 ’.10 FINE AGGREGATE Mg SO4 ciS ’.15 - 15 INNOCUOUS TO

  6. <研究報告>長崎県西彼杵半島南部の高Mg安山岩と玄武岩



    The late Cenozoic volcanic rocks in the southern Nishisonogi Peninsula, which are characterized by dominance of undifferentiated, primitive rocks, show a large variation in chemical composition ranging from high-Mg andesite (HMA) through tholeiitic basalt to alkali basalt and from high-Mg basalt to rhyolite. Most HMA is cpx-HMA crystallized clinopyroxene with the highest Mg# and Cr_2O_3 of 87.4 and 1.24%, respectively, following olivine with the highest Fo of 92.1 and NiO of 0.48%. An orthopy...

  7. Bi-directional subduction of the South Tianshan Ocean during the Late Silurian: Magmatic records from both the southern Central Tianshan Block and northern Tarim Craton (United States)

    Wang, Meng; Zhang, Jinjiang; Zhang, Bo; Liu, Kai; Ge, Maohui


    The subduction polarity of the South Tianshan Ocean (STO) is a matter of debate, primarily in that the Paleozoic structures of Tianshan orogenic belt have been strongly overprinted by the Cenozoic intra-continental deformation. Indentifying the arc-related magmatic rocks may provide a convincible clue for understanding the closure process of the STO. In this study, whole-rock geochemistry, zircon U-Pb dating and Hf isotope were presented on the andesite and monzonite from the Bayanbulak area of the southern Central Tianshan Block (CTB) and on the quartz diorite from the Ouxidaban area of the northern Tarim Craton. Geochemically, all the samples are Na-rich, enriched in light rare earth elements and large ion lithophile elements (Rb, Ba, U, K and Pb), and depleted in high strength field elements (Nb, Ta and Ti), like most arc-type igneous rocks. The Bayanbulak andesite samples display high MgO, Fe2O3T, TiO2 and Mg# values, and positive εHf(t) values, indicating magma source from the wedge mantle. But the existence of xenocrystic zircons implies that continental crust material were involved during magma ascend, suggesting a continental arc setting for the Bayanbulak andesite. The Bayanbulak monzonite and the Ouxidaban quartz diorite samples display relatively higher SiO2 contents, and lower MgO, Fe2O3T and TiO2 concentrations, indicating crustal sources. But the Mg# values of the Bayanbulak monzonite and the Ouxidaban quartz diorite are 48.76-51.85 and 50.31-53.73, and the εHf(t) values are -2.5 to 8.7 and -1.7 to 4.1, indicating that their magma sources were also mixed by mantle-derived components. LA-ICP-MS zircon U-Pb dating results reveal that the Bayanbulak andesite, the Bayanbulak monzonite and the Ouxidaban quartz diorite were formed at 423, 424 Ma, and 421 Ma, respectively. The age and geochemical data indicate that both the southern CTB and northern Tarim Craton were active continental margins during the Late Silurian, favoring a bi-directional subduction

  8. Temporal source evolution and crustal contamination at Lopevi Volcano, Vanuatu Island Arc



    Here we present a new geochemical study of Lopevi volcano, one the most active volcanoes in the Vanuatu island arc. We focus on the temporally well-defined sequence of lava flows emitted since 1960, and for the first time, on pre-1960 volcanic products, including high-MgO basalts and felsic andesites, the most evolved lavas sampled so far on this island. This work reports the first Pb and Hf isotopic study of lavas from Lopevi island. These lavas display correlations between differentiation i...

  9. Physical volcanology of the mafic segment of the subaqueous New Senator caldera, Abitibi greenstone belt, Quebec, Canada

    Energy Technology Data Exchange (ETDEWEB)

    Moore, Lyndsay N; Mueller, Wulf U [Universite du Quebec a Chicoutimi, 555 boul. du l' Universite, Chicoutimi, Quebec, G7H2B1 (Canada)], E-mail:


    Archean calderas provide valuable insight into internal geometries of subaqueous calderas. The New Senator caldera, Abitibi greenstone belt, Canada, is an Archean example of a subaqueous nested caldera with a basal stratigraphy dominated by gabbro-diorite dykes and sills, ponded magmas and basalt and andesite lava flows. The aim of our study is to focus on the use of physical volcanology to differentiate between the various mafic units found at the base of the New Senator caldera. Differentiation between these various mafic units is important from an exploration point of view because in modern subaqueous summit calders (e.g. Axial Seamount) margins of ponded magmas are often sites of VMS formation.

  10. Volatile Abundances and Magma Geochemistry of Recent (2006) Through Ancient Eruptions (Less Than 2100 aBP) of Augustine Volcano, Alaska (United States)

    Webster, J. D.; Mandeville, C. W.; Gerard, T.; Goldoff, B.; Coombs, M. L.


    Augustine Volcano, Cook Inlet, Alaska, is a subduction-related Aleutian arc volcano located approximately 275 km southwest of Anchorage. During the past 200 years, Augustine volcano has shown explosive eruptive behavior seven times, with the most recent activity occurring in January through March 2006. Its ash and pumice eruptions pose a threat to commercial air traffic, the local fishing industry, and the inhabitants of the region. Following prior investigations on volatile abundances and processes of evolution for magmas associated with the 1976 (Johnston, 1978) and 1986 (Roman et al., 2005) eruptions of Augustine, we have analyzed phenocrysts, matrix glasses, and silicate melt inclusions in andesites formed during 5 pre-historic eruptions (ranging from 2100 to 1000 years in age) as well as the 1986 and recent 2006 eruptions. Outcrops of basaltic units on Augustine are rare, and basaltic melt inclusions are as well, so most melt inclusions studied range from andesitic to rhyolitic compositions. Comparison of the volatile abundances in felsic melt inclusion glasses shows few differences in H2O, CO2, S, and Cl, respectively, between eruptive materials of the pre- historic, 1976 (Johnston, 1978), and 1986 (Roman et al., 2005; our data) events. The magmas associated with these eruptions contained 1.6 to 8.0 wt.% H2O with 0.21 to 0.84 wt.% Cl, 100 to 1800 ppm CO2, and 100 to 400 ppm S. In contrast, preliminary research on rhyodacitic to rhyolitic melt inclusions in a single 2006 andesite sample collected from a lahar deposit indicates they contain somewhat lower H2O contents and higher Cl and S abundances than felsic melt inclusions from prior eruptions, and they exhibit geochemical trends consonant with magma mixing. Relationships involving H2O, CO2, S, and Cl in prehistoric through 1986 melt inclusions are consistent with fluid-saturated magma evolution of andesitic to rhyolitic melt compositions during closed-system ascent. The various batches of magma rose through

  11. Subsurface geology of Los Humeros geothermal field, Puebla, Mexico; Geologia del subsuelo del campo geotermico de Los Humeros, Puebla, Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Cedillo Rodriguez, Fidel [Comision federal de Electricidad, Perote, Veracruz, Mexico(Mexico)


    In the 1980s, most geologists correlated subsurface geology at Los Humeros geothermal field using penetrated by faults, as interpreted by photogeology. These were structural objectives for geothermal drilling programs. Recent petrology reinterpretation of data from well cutting lets us identify nine lithologic units, with the Toba Vitrea Humeros as the index horizon. The study of the subsurface geology allows us to demonstrate- based on the distribution, depth, and thickness of the lithologic units- that the augite andesites, the Toba Vitrea Humeros, the hornblende andesites, the basalt, and the metamorphosed limestone are affected by system of hidden faults (with no surface evidence) replaced by major fracture zones able to contain steam. Thus these hidden faults are the structural objectives controlling design and sitting of new wells. We conclude that the lithologic unit of augite andesites forms the upper geothermal reservoir, and the hornblende andesites and basalt comprise the lower reservoir- separated from each other by the Toba Vitrea Humeros lithologic unit. Based on the subsurface geologic model, we propose drilling 40 new wells, a long and parallel the north-south faults system. [Spanish] En la decada de los 80s se agrupo la geologia del subsuelo de Los Humeros en cuatro unidades litologicas afectadas por fallas interpretadas por fotogeologia. Estas fallas eran el objetivo estructural para programar la perforacion de pozos geotermicos. La reinterpretacion de los datos de petrologia de las muestras de canal permite identificar nueve unidades litologicas, de las cuales la unidad Toba Vietrea Humeros se comporta como horizonte indice. El estudio de la geologia del subsuelo permite demostrar, con base en la distribucion, profundidades y espesores de las unidades litologicas, que las andesitas de augita, la Toba Vitrea Humeros, las andesitas de hornblenda, los basaltos, y las calizasmetamorfizadas estan afectadas por sistemas de fallas ocultas (sin

  12. The Records of the Tectonic Evolution From the Volcanics in Qiangtang Basin, Tibet

    Institute of Scientific and Technical Information of China (English)

    He Zhonghua; Yang Deming; Li Cai; Pu Zhongyu


    The volcanism in Qiangtang Basin is very frequent due to the divergence and subduction of the various plates. The study indicates that these volcanics are formed in different tectonic settings: 1 )Hercynian volcanics are mainly basalts and are formed in the intraplate and intercontinental rift. 2 ) Indosinian volcanics markedly vary in the distribution and composition and reflect transitional MORB and island are environments respectively. 3) Yanshanian volcanics consist predominantly of basalts, andesites, dacites and rhyolites and are characterized by calc- alkaline volcanic suite, indicating island arc setting. 4)Himalayan volcanics are complicated and associated with intraplate orogency. The volcanism provides important tectonic information for recognizing the evolution of Qiangtang Basin.

  13. Mineralogy and fluid inclusion studies in kalchoye Copper- gold deposit, East of Esfahan

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    Rezvan Mehvary


    Full Text Available Kalchoye Copper-gold deposit is located about 110 kilometers east of Esfahan province and within the Eocene volcano sedimentary rocks. Sandy tuff and andesite lava are important members of this complex.The form of mineralization in area is vein and veinlet and quartz as the main gangue phase. The main ore minerals are chalcopyrite, chalcocite, galena and weathered minerals such as goethite, iron oxides, malachite and azurite. Studies in area indicate that ore mineralization Kalchoye is low sulfide, quartz type of hydrothermal ore deposits and results of thermometry studies on quartz minerals low- medium fluid with low potential mineralization is responsible for mineralization in this area.

  14. Tectono-metamorphic evolution of high-P/T and low-P/T metamorphic rocks in the Tia Complex, southern New England Fold Belt, eastern Australia: Insights from K-Ar chronology (United States)

    Fukui, Shiro; Tsujimori, Tatsuki; Watanabe, Teruo; Itaya, Tetsumaru


    The Tia Complex in the southern New England Fold Belt is a poly-metamorphosed Late Paleozoic accretionary complex. It consists mainly of high-P/low-T type pumpellyite-actinolite facies (rare blueschist facies) schists, phyllite and serpentinite (T = 300 °C and P = 5 kbar), and low-P/high-T type amphibolite facies schist and gneiss (T = 600 °C and P high-Mg andesite and adakite might explain formation of S-type granitoids (Hillgrove suite) and coeval low-P/high-T type metamorphism in the Tia Complex.

  15. Mineral chemistry of some agates from Gurasada (Mures Valley, Romania

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    Ovidiu Iancu


    Full Text Available The paper presents the study of some agates from the Gurasada area (Mures Valley, West Romania and their igneous host rocks. Agates occur in the vesicles of strongly altered pyroclastic rocks (“banatites”, such as basaltic andesites, trachyandesites, trachytes and dacites or in the alluvial sediments along the Gurasada valley. The age of host-rocks is Late Cretaceous-Early Paleogene. Agates consist mainly of various types of α-quartz such as: chalcedony, quartzine and microquartz, associated with moganite. The genesis of agates is related with the hydrothermal solutions which altered the host-rocks.


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    Ika Yulia Sulistyarini, Irjan


    Hasil penelitian menunjukkan lapisan penyusun bawah permukaan pada lintasan B dan C tidak kontinu dan didominasi oleh lapisan yang tidak memiliki sifat pembawa air panas yang berupa batuan lava dan campuran batuan lava dengan andesit yang menunjukkan kemas tertutup dan porositas batuan jelek. Potensi air panas masih kecil dan diduga air panas yang muncul ke permukaan berasal dari aliran air panas dari arah songgoriti-cangar. Air panas tersebut muncul ke permukaan diduga karena adanya rekahan batuan di bawah permukaan. Kata Kunci : Air Panas (Hidrothermal, Geolistrik Resistivitas Konfigurasi Wenner, Potensi air panas.

  17. U-series Disequilibria in Continental Arcs: NE Japan Case (United States)

    Tepley, F. J.; Gill, J. B.; Williams, R. W.


    Basalts and andesites from continental arcs typically are close to equilibrium between (238U) and (230Th), and have subdued excesses of 226Ra compared to oceanic arcs (Turner et al., 2003). There is ambiguity whether these and other geochemical features derive from subducted sediment, subcontinental lithosphere, or the crust. We report new 238U-234U-230Th-226Ra data for 20 historical to Holocene samples from Asama in the south of NE Japan to Tarumai in the north. Most straddle the equiline with 4.

  18. U.S. Geological Survey silicate rock standards (United States)

    Flanagan, F.J.


    The U.S. Geological Survey has processed six silicate rocks to provide new reference samples to supplement G-1 and W-1. Complete conventional, rapid rock, and spectrochemical analyses by the U.S. Geological Survey are reported for a granite (replacement for G-1), a granodiorite, an andesite, a peridotite, a dunite, and a basalt. Analyses of variance for nickel, chromium, copper, and zirconium in each rock sample showed that for these elements, the rocks can be considered homogeneous. Spectrochemical estimates are given for the nickel, chromium, copper, and zirconium contents of the samples. The petrography of five of the six rocks is described and CIPW norms are presented. ?? 1967.

  19. Geology and stratigraphy of the San Lorenzo Tezonco deep well and its correlation to surrounding ranges, Mexico Basin (United States)

    Arce, J. L.; Layer, P. W.; Morales-Casique, E.; Benowitz, J.


    The San Lorenzo Tezonco deep well stratigraphy records intense episodic volcanic activity in the Mexico Basin and surroundings during the past 20 Ma. The 2008-m deep lithological column is dominated by volcanic material, either as lava flows or pyroclastic deposits (97%), and only the upper most 70 m are composed of lacustrine deposits (3%). Based on geochronology and geochemistry, the lower part of the drill core is represented by rocks correlating to the Tepoztlán Formation (876-2008 m deep) that vary in composition from basaltic-andesite to rhyolite, and ages ranging from 13 to 21.2 Ma. On the surface this formation outcrops near the towns of Malinalco and Tepoztlán, ~43 km south of the deep well. Between depths of 581 and 875 m, volcanic rocks were recovered and are interpreted as lavas from the Sierra de las Cruces that vary in composition from andesite to dacite and range in age from 0.9 Ma to 5 Ma. Additionally, we documented rocks belonging to the Xochitepec Formation, outcropping around Xochimilco, in the Mexico City, with ages ranging from 1.2 and 1.7 Ma, in contrast with the Oligocene age proposed in previous works for these rocks. These new ages plus the chemical composition data, allow us to correlate the Xochitepec rocks with Sierra de las Cruces. Upward in the drill core (510-580 m) there are andesitic rocks that correlate with the 0.25 Ma Cerro de la Estrella volcanic center. The last volcanic package found in the well is correlated to the Santa Catarina basaltic andesites (70-120 m) that are younger than 0.25 Ma, and probably Holocene. Lacustrine deposits crown the stratigraphic column of the drill core with ages probably younger than 34 ka. The San Lorenzo Tezonco well is in a graben-like structure that was filled with more than 1900 m of volcanic products, suggesting that volcanism were intense in the Miocene to the Recent, and the south drainage of the Mexico Basin was closed probably in the early Pleistocene.

  20. Geochemistry and tectonic setting of the Paleoproterozoic metavolcanic rocks from the Chirano Gold District, Sefwi belt, Ghana (United States)

    Senyah, Gloria A.; Dampare, Samuel B.; Asiedu, Daniel K.


    Major and trace elements, including rare earth elements (REEs) data are presented for metavolcanic rocks of the Paleoproterozoic Birimian Sefwi belt to determine the geochemical characteristics as well as the possible tectonic setting of emplacement of these rocks. In order to accomplish the aim of the study, the petrographical characteristics of the rocks were examined coupled with analysis of the rocks for their whole-rock major and trace elements contents by ICP-AES and ICP-MS methods respectively. The rocks have been classified as basalt/basaltic andesites and dolerites based on their textural and mineralogical compositions. It is observed that the rocks have suffered various degrees of alteration evident in the overprinting of primary minerals such as pyroxenes and plagioclase by chlorite, epidote, sericite and others. Generally, the rocks are moderately deformed and may have experienced at least greenschist metamorphism. The basalt/basaltic andesites are derivative magmas [Mg# (20-51), Cr (10-220 ppm) and Ni (5-137 ppm)], and show flat REE to fractionated REE patterns with (La/Sm)N = 1.36-3.90, (La/Yb)N = 1.17-5.32 and strong negative to non-existent Eu anomalies (Eu/Eu* = 0.51-1.03). N-MORB-normalised multi-element diagrams show that the rocks have geochemical patterns characterised by enrichment in LILE relative to HFSE and in LREE relative to HREE. The basalt/basaltic andesites exhibit characteristics of subduction zone-related magmas, such as pronounced negative Nb-Ta anomalies, slightly negative Hf and variable negative Ti anomalies. The dolerites do not vary much from the basalts and basaltic andesites. The MgO and Fe2O3 values of the dolerite range from 2.97 to 6.93 and 5.98 to 14.35 wt.% respectively, corresponding to Mg#s of 38-62. LREEs enrichment over HREEs with (La/Sm)N ranging from 0.61 to 4.61 and (Gd/Yb)N ranging from 0.99 to 2.91 is also typical of these rocks. The dolerites also exhibit quite invariable Eu anomalies (Eu/Eu* = 0.81-1.00) and


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    Rayo Lorena


    Full Text Available The contact between the unit Porphyry Andesite and the Cajamarca Group is observed in the "Túnel de la Linea" section. The integration of petrographic, geochemical and textural (crystal size distribution, CSD analysis allows description of physical and chemical processes that took place in the contact zone in order to propose a model for the intrusion. Material assimilation produced quartz enrichment towards pluton's boundaries associated to a simple process of melt injection. The difference between host rock and hot melt rheologies causedshear stress that produced crystal breaking, folding and foliation rotation.


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    Sz. Fischer


    Full Text Available Purpose. Using adequate granular materials and layer structures in the railway super- and substructure is able to stabilise railway track geometry. For this purpose special behaviour of above materials has to be determined, e.g. inner shear resistance. Inner shear resistance of granular media with and without geogrid reinforcement in different depths is not known yet. Methodology. The author developed a special laboratory method to measure and define inner shear resistance of granular materials, it is called «multi-level shear box test». This method is adequate to determine inner shear resistance (pushing force vs. depth (distance from the «zero» surface. Two different granular materials: andesite railway ballast (31.5/63 mm and andesite railway protection layer material (0/56 mm, and seven different types of geogrids (GG1…GG7 were used during the tests. Findings. Values of inner shear resistance functions of andesite railway ballast without geogrid reinforcement and reinforced with different types of geogrids and andesite granular protection layer in function of the vertical distance from the geogrid plane were determined with multi-layer shear box tests when the material aggregation is uncompacted and compacted. Only the compacted sample was tested in case of the 0/56 mm protection layer. Cubic polynomial regression functions fitted on the mean values of the measurements are described graphically. Determination coefficients with values of R2>0.97 were resulted in all the cases of regression functions. Based on the polynomial regression functions fitted on the mean values of the test results, three increasing factors were determined in function of the distance measured from the geogrid. Increasing factor «A», «B» and «D». Originality. Multi-level shear box test, developed by the author, is certified unequivocally adequate for determining inner shear resistance of reinforced and unreinforced granular materials, e.g. railway ballast

  3. Structure and petrology of newly discovered volcanic centers in the northern Kermadec-southern Tofua arc, South Pacific Ocean (United States)

    Graham, Ian J.; Reyes, Agnes G.; Wright, Ian C.; Peckett, Kimberley M.; Smith, Ian E. M.; Arculus, Richard J.


    The NZAPLUME III expedition of September-October 2004 to the northern Kermadec-southern Tofua (NKST) arc, between 28°52'S and 25°07'S, resulted in the discovery of at least seven new submarine volcanic centers and a substantial caldera complex adjacent to the previously known Monowai Seamount. The volcanic centers form a sublinear chain that coincides with the Kermadec Ridge crest in the south (Hinetapeka) and diverges ˜45 km westward of the ridge crest in the north ("V") just to the south of where the Louisville Ridge intersects with the arc. All of the centers contain calderas or caldera-like structures, as well as multiple cones, domes, fissure ridges, and vent fields. All show signs of recent eruptive and current hydrothermal activity. There are strong structural controls on edifice location, with cones and fissure ridges typically associated with faulting parallel to the regional ˜12° strike of the arc front. Several of the calderas are ellipsoidal, orientated northwest-southeast in the general direction of least compressive stress. Sampled volcanic rocks, representing the most recently erupted lavas, are all low-K tholeiites. Two of the centers, Gamble and Rakahore, yielded only high-silica dacite to rhyolite (69-74 wt% silica), whereas two others, Monowai and "V," yielded only basalt to andesite (48-63 wt% silica). Mineral assemblages are plagioclase-pyroxene dominated, with accessory Fe-Ti oxides, apatite, olivine, and quartz/tridymite/cristobalite, typical of dry volcanic arc systems. Hornblende occurs only in a felsitic rhyolite from Hinepuia volcanic center, and zircon is absent. Glass contents range to 57% in basalts-andesites (mean 20%), and 97% in andesites-rhyolites (mean 59%) and other quench textures, including swallow-tailed, plumose, or dendritic crystal forms and crystallites, are common. Most lavas are highly vesicular (≤63%; mean 28%) and have low volatile contents (mostly cristobalite, indicates explosive eruption and rapid cooling

  4. Dynamic behavior of the Bering Glacier-Bagley icefield system during a surge, and other measurements of Alaskan glaciers with ERS SAR imagery (United States)

    Lingle, Craig S.; Fatland, Dennis R.; Voronina, Vera A.; Ahlnaes, Kristina; Troshina, Elena N.


    ERS-1 synthetic aperture radar (SAR) imagery was employed for the measurement of the dynamics of the Bagley icefield during a major surge in 1993-1994, the measurement of ice velocities on the Malaspina piedmont glacier during a quiescent phase between surges, and for mapping the snow lines and the position of the terminus of Nabesna glacier on Mount Wrangell (a 4317 m andesitic shield volcano) in the heavily glacierized Saint Elias and Wrangell Mountains of Alaska. An overview and summary of results is given. The methods used include interferometry, cross-correlation of sequential images, and digitization of boundaries using terrain-corrected SAR imagery.

  5. Volatile contents of mafic-to-intermediate magmas at San Cristóbal volcano in Nicaragua (United States)

    Robidoux, P.; Aiuppa, A.; Rotolo, S. G.; Rizzo, A. L.; Hauri, E. H.; Frezzotti, M. L.


    San Cristóbal volcano in northwest Nicaragua is one of the most active basaltic-andesitic stratovolcanoes of the Central American Volcanic Arc (CAVA). Here we provide novel constraints on the volcano's magmatic plumbing system, by presenting the first direct measurements of major volatile contents in mafic-to-intermediate glass inclusions from Holocene and historic-present volcanic activity. Olivine-hosted (forsterite [Fo] 1500 μg/g) found in Nicaragua at Cerro Negro, Nejapa, and Granada. Models of H2O and CO2 solubilities constrain the degassing pathway of magmas up to 425 MPa ( 16 km depth), which includes a deep CO2 degassing step (only partially preserved in the MI record), followed by coupled degassing of H2O and S plus crystal fractionation at magma volatile saturation pressures from ∼ 195 to < 10 MPa. The variation in volatile contents from San Cristóbal MI is interpreted to reflect (1) Holocene eruptive cycles characterized by the rapid emplacement of basaltic magma batches, saturated in volatiles, at depths of 3.8-7.4 km, and (2) the ascent of more-differentiated and cogenetic volatile-poor basaltic andesites during historic-present eruptions, having longer residence times in the shallowest (< 3.4 km) and hence coolest regions of the magmatic plumbing system. We also report the first measurements of the compositions of noble-gas isotopes (He, Ne, and Ar) in fluid inclusions in olivine and pyroxene crystals. While the measured 40Ar/36Ar ratios (300-304) and 4He/20Ne ratios (9-373) indicate some degree of air contamination, the 3He/4He ratios (7.01-7.20 Ra) support a common mantle source for Holocene basalts and historic-present basaltic andesites. The magmatic source is interpreted as generated by a primitive MORB-like mantle, that is influenced to variable extents by distinct slab fluid components for basalts (Ba/La 76 and U/Th 0.8) and basaltic andesites (Ba/La 86 and U/Th 1.0) in addition to effects of magma differentiation. These values for the

  6. 米国New Mexico州の火山地域の地形とその分類


    守屋, 以智雄


    Geomorphology and evolution of the volcanic fields in New Mexico have been studied. Thirteen volcanic fields being active in the late Tertiary-Quaternary are classified into 4 - A, B, C, and D types. A-type volcanic fields are simple lava fields, composed of basaltic lava flows, scoria cones, tuff rings, tuff cones, and small shields. B-type volcanic fields are lava fields on which small to medium-scale andesitic stratovolcanoes and dacitic to rhyolitic lava domes stand. C-type volcanic field...

  7. Long-Period seismic events at Ubinas Volcano (Peru): their implications and potentiality as monitoring tool (United States)

    Zandomeneghi, D.; Inza, A.; Metaxian, J.-P.; Macedo, O.


    Ubinas volcano (Southern Peru) is an active andesitic stratovolcano, located 75 km East of Arequipa City, with an average occurrence of 6-7 eruptions per century and persistent fumarolic and phreatic activity. The most recent eruption, accompanied by explosions and by the extrusion of a lava dome, started on March 2006 with an increase of seismicity and observed fumarole occurrence followed in April by more intense explosions, recorded until May 2009. To monitor the volcanic activity, the Geophysical Institute of Peru and the Institut de Recherche pour le Développment (France), built up a seismic network around the volcano, installing 4 permanent stations and deploying 8 supplementary temporary broadband seismometers. In addition, in the period May to July 2009, a seismic experiment was carried out on the volcano flanks with 2 cross-shaped dense antennas with broadband seismometers. As the seismic activity was characterized by recurring low-frequency waveforms, we identify their pattern of occurrence through waveform cross-correlation technique, with respect to major eruptive phases and other observations (as volcano ground deformation from tiltmeters, volcanic product composition, etc). Once established their likely association with the eruptive sequence, we utilize both local network and dense-array data and analyze their location, changes in location, spectral content variations and possible physical explanation. The final aim is to introduce this kind of analysis as quantitative tool to understand ongoing eruptive phases at andesitic volcanoes and possibly to forecast magma/fluid significant movements.

  8. Characterization and zircon SHRIMP U-Pb geochronology of the subvolcanic rocks from Yarumalito Porphyry System, Marmato District, Colombia; Caracterizacao e geocronologia SHRIMP U-Pb em zircao das rochas subvulcanicas do sistema porfiro Yarumalito, Distrito de Marmato, Colombia

    Energy Technology Data Exchange (ETDEWEB)

    Henrichs, Isadora A.; Frantz, Jose Carlos; Marques, Juliana C.; Castoldi, Marco S., E-mail:, E-mail:, E-mail: [Universidade Federal do Rio Grande do Sul (UFRS), Porto Alegre, RS (Brazil). Instituto de Geociencias; Ordonez-Carmona, Oswaldo, E-mail: [Universidad Nacional de Colombia, Medellin (Colombia). Facultad de Minas; Sato, Kei, E-mail: [Universidade de Sao Paulo (USP), Sao Paulo, SP (Brazil). Centro de Pesquisas Geocronologicas


    The mining District of Marmato, located in the Central Cordillera, is considered one of the oldest gold districts in Colombia and its exploration dates back to the Inca’s times, being exploited regularly for more than a thousand years. Inserted in this context lies the Yarumalito porphyry system (YPS), characterized to concentrate ore in structure related veins and stockworks. The YPS is related to the Miocene magmatism of the Combia Formation. In this paper, the subvolcanic rocks directly associated with the mineralized zones were described in order to obtain U-Pb ages in zircon to the intrusions. Selected samples from two fertile intrusions, one andesitic (more abundant in the area) and other dioritic (more restricted), were carefully described and dated by SHRIMP. The results points to a very restricted interval for the ages, with weighted average {sup 206}Pb/{sup 238}U varying from 7,00 ± 0,15 Ma for the andesitic porphyry and 6.95 ± 0.16 Ma for the dioritic porphyry. These results constrain the Yarumalito system to the final stages of the Combia magmatism and suggest a brief period for the crystallization of the mineralized subvolcanic rocks in the area and in the Marmato District. (author)

  9. Multivariate analysis, mass balance techniques, and statistical tests as tools in igneous petrology: application to the Sierra de las Cruces volcanic range (Mexican Volcanic Belt). (United States)

    Velasco-Tapia, Fernando


    Magmatic processes have usually been identified and evaluated using qualitative or semiquantitative geochemical or isotopic tools based on a restricted number of variables. However, a more complete and quantitative view could be reached applying multivariate analysis, mass balance techniques, and statistical tests. As an example, in this work a statistical and quantitative scheme is applied to analyze the geochemical features for the Sierra de las Cruces (SC) volcanic range (Mexican Volcanic Belt). In this locality, the volcanic activity (3.7 to 0.5 Ma) was dominantly dacitic, but the presence of spheroidal andesitic enclaves and/or diverse disequilibrium features in majority of lavas confirms the operation of magma mixing/mingling. New discriminant-function-based multidimensional diagrams were used to discriminate tectonic setting. Statistical tests of discordancy and significance were applied to evaluate the influence of the subducting Cocos plate, which seems to be rather negligible for the SC magmas in relation to several major and trace elements. A cluster analysis following Ward's linkage rule was carried out to classify the SC volcanic rocks geochemical groups. Finally, two mass-balance schemes were applied for the quantitative evaluation of the proportion of the end-member components (dacitic and andesitic magmas) in the comingled lavas (binary mixtures).

  10. Petrologi - geokimia batuan Gunung Api Tampomas dan sekitarnya

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    Mesker H. Dirk


    Full Text Available rocks of Mount Tampomas and its surroundings belong to low–K, calc–alkaline, and high–K series of basalt, basaltic andesite, and andesite suites containing 48.59 – 60.49 wt% of SiO and 0.31-1.67 wt% of K O. The rocks are typically formed in an island arc environment characterized by the high content of Al O (16.47 – 21.76 wt%, low to moderate content of MgO (2.37 – 8.84 wt%, low content of both titanium TiO (< 1 wt% and high field strength elements (HFSEs, negative anomaly of Nb relative to K and La. The light rare earth elements (LREEs enrichment but low abundances of heavy rare earth elements (HREEs indicate fractionation process. The parent magma was an extensive removal of olivine and clino-pyroxene, plagioclase, apatite, and titanoferrousmagnetite from a basalt olivine magma of N-MORB character that was firstly enriched by LILEs such as Ba, Rb, Th, K, and LREE (La. The differentiation lasted, and the magma became water undersaturated at the crystallization phase of hornblende. The high content of incompatible elements such as Ba, Th, La, Ce, may indicate contamination by liquid derived from the subducted slab.   

  11. Radiogenic Heat Production in the Gölcük Caldera and Direkli, Isparta Angle (Southwest Anatolia) (United States)

    Ayten Uyanık, Nurten; Öncü, Ziya; Akkurt, İskender


    The radiogenic heat is one of the important parameter due to the radioactivity has existed since beginning of universe as prediction of Big-Bang theory. In this study the radiogenic heat production of the Gölcük caldera and Direkli fields of the Isparta-Turkey, has been investigated. Total of 1390 data were obtained in the study area. The study area is included of the Gölcük volcanism and its around that is located in Isparta province of Turkey's Mediterranean region. The Gölcük volcanism is a young volcanism. Around this volcanism the andesite, trachy andesite, tuff, pumice and such a geological units is available. The data were collected using in-situ measurements with gamm-ray spectrometer. These measurements were covered natural radioactive elements (Uranium U, Thorium Th and Potassium K). Radiogenic heat production values were calculated using the literature relationships and in-situ measurement values of these radioactive elements. Radiogenic heat map of study area were obtained using radiogenic heat production values. In the map the red zone areas shows highest heat values while green zones areas of the map presents lowest heat values. Key words: Radioactive elements, radiogenic heat, map, Gölcük-Direkli(Isparta), Turkey

  12. Accumulation of 'anti-continent' at the base of the mantle and its recycling in mantle plumes (United States)

    Tatsumi, Yoshiyuki; Suzuki, Toshihiro; Ozawa, Haruka; Hirose, Kei; Hanyu, Takeshi; Ohishi, Yasuo


    The continental crust is a unique reservoir of light elements in the solid Earth; it possesses an intermediate composition and is believed to have been created principally along volcanic arcs, which are major sites of terrestrial andesitic magmatism. Mantle-derived arc magmas are, however, generally mafic or basaltic. A simple mechanism to overcome this apparent dilemma and generate andesitic melts in such a setting is through the partial remelting of an initial mafic arc crust by heat supplied from underplating basaltic magmas. An antithesis to the formation of continental crust in this way should be the production of refractory melting residue, here referred to as 'anti-continent'. This anti-continent is likely to detach from arc crust as a result of a density inversion and descend into the upper mantle. High-pressure experiments demonstrate that sinking anti-continent is, in contrast to the subducting oceanic crust, always denser than the surrounding mantle, suggesting that it penetrates through the upper-lower mantle boundary, without stagnation, and accumulates at the base of the mantle to form a 200-400 km thick mass known as the D″ layer. Geochemical modeling provides further evidence that this accumulating anti-continent contributes to a deep-seated hotspot source. Therefore, through complementary processes, Earth creates buoyant continents and dense anti-continents at the top and the base of the mantle, respectively, and has recycled portions of anti-continent in mantle plumes.

  13. Geochemistry of the subduction-related magmatic rocks in the Dahong Mountains, northern Hubei Province--Constraint on the existence and subduction of the eastern Mianlüe oceanic basin

    Institute of Scientific and Technical Information of China (English)

    DONG Yunpeng; ZHANG Guowei; ZHAO Xia; YAO Anping; LIU Xiaoming


    The existence and subduction of the eastern Mianlue oceanic basin in the south Qinling belt are keys to understand the Qinling orogen. Based on geological mapping, several volcanic slices have been identified in Tumen, Zhoujiawan, Xiaofu and Yuantan areas, which distribute in the northern margin of the Dahong Mountains (DHM), and thrust into the Sanligang-Sanyang fault. These slices consist mainly of diabases, basaltic-andesitic lavas, pyroclastic rocks and a minor tuff. The geochemistry of the basalts, andesites, and diabases is characterized by depleting in Nb and Ta, enriching in Th and LILE (e.g.K, Rb, Ba), and undifferentiating in HFSE. These geochemical characteristics suggest that the original magma of these rocks was derived from a mantle wedge above a subduction zone, and formed in an island-arc setting in Carboniferous-early Triassic. Comparing with the ophiolites and island-arc volcanic rocks in Mianxian-Lueyang area to the west, it is reasonable to consider that there had been an oceanic basin connecting with the Mianlue ancient ocean to the westward, distributing along the south edge of the Tongbai-Dabie block. In view of the ophiolite in Huashan area and these island-arc volcanic rocks along the north of the Dahong Mountains, it is suggested that there had been a plate tectonic evolutionary history with oceanic basin rifting and subduction in this region.

  14. Geochemical Characteristics and Metallogenesis of Volcanic Rocks as Exemplified by Volcanic Rocks in Ertix,Xinjiang

    Institute of Scientific and Technical Information of China (English)

    刘铁庚; 叶霖


    Volcanic rocks in Ertix,Xinjiang,occurring in the collision zone between the Siberia Plate and the Junggar Plate,are distributed along the Eritix River Valley in northern Xinjiang.The volcanic rocks were dated at Late Paleozoic and can be divided into the spilite-keratophyre series and the basalt-andesite series.The spilite-keratophyre series volcanic rocks occur in the Altay orogenic belt at the southwest margin of the Siberia Plate.In addition to sodic volcanic rocks.There are also associated potassic-sodic volcanic rocks and potassic volcanic rocks.The potassic-sodic volcanic rocks occur at the bottom of the eruption cycle and control the distribution of Pb and Zn deposits.The potassic volcanic rocks occur at the top of the eruption cycle and are associated with Au and Cu mineralizations.The sodic volcanic rocks occur in the middle stage of eruption cycle and control the occurrence of Cu(Zn) deposits.The basalt-andesite series volcanic rocks distributed in the North Junggar orogenic belt at the north margin of the Junggar-Kazakstan Plate belong to the potassic sodic volcain rocks.The volcanic rocks distributed along the Ulungur fault are relatively rich in sodium and poor in potassium and are predominated by Cu mineralization and associated with Au mineralization.Those volcanic rocks distributed along the Ertix fault are relatively rich in K and poor in Na,with Au mineralization being dominant.

  15. Continental crust generated in oceanic arcs (United States)

    Gazel, Esteban; Hayes, Jorden L.; Hoernle, Kaj; Kelemen, Peter; Everson, Erik; Holbrook, W. Steven; Hauff, Folkmar; van den Bogaard, Paul; Vance, Eric A.; Chu, Shuyu; Calvert, Andrew J.; Carr, Michael J.; Yogodzinski, Gene M.


    Thin oceanic crust is formed by decompression melting of the upper mantle at mid-ocean ridges, but the origin of the thick and buoyant continental crust is enigmatic. Juvenile continental crust may form from magmas erupted above intra-oceanic subduction zones, where oceanic lithosphere subducts beneath other oceanic lithosphere. However, it is unclear why the subduction of dominantly basaltic oceanic crust would result in the formation of andesitic continental crust at the surface. Here we use geochemical and geophysical data to reconstruct the evolution of the Central American land bridge, which formed above an intra-oceanic subduction system over the past 70 Myr. We find that the geochemical signature of erupted lavas evolved from basaltic to andesitic about 10 Myr ago--coincident with the onset of subduction of more oceanic crust that originally formed above the Galápagos mantle plume. We also find that seismic P-waves travel through the crust at velocities intermediate between those typically observed for oceanic and continental crust. We develop a continentality index to quantitatively correlate geochemical composition with the average P-wave velocity of arc crust globally. We conclude that although the formation and evolution of continents may involve many processes, melting enriched oceanic crust within a subduction zone--a process probably more common in the Archaean--can produce juvenile continental crust.

  16. New ages and chemical analysis on Lower Jurassic volcanism close to the dorsal de Huincul, Neuquén

    Directory of Open Access Journals (Sweden)

    Mario SCHIUMA


    Full Text Available New single zircon ages from hydrocarbon well cores in the A-1 Norte de la Dorsal and Anticlinal Campamento area of the Neuquén basin indicate that 199.0 ± 1.5 Ma andesite lava flow and 203.75 ± 0.26 Ma dacite breccia overlie a 286.5 ± 2.3 Ma granodiorite and 284.0 ± 1.3 Ma andesite dike. The Lower Jurassic volcanics were deposited on a regional erosion surface affecting the Permian rocks. In the studied area there is no record of Middle to Upper Triassic volcanics as in other areas of the basin. Exotic zircon crystals gave ages of Mesoproterozoic, Middle Cambian, Early Devonian and Early Carboniferous, suggesting a poliphasic basement. Chemical analyses of three selected samples show a calc-alkaline signature, supporting the existence of a volcanic arc at the Early Jurassic as it has been proposed for the center of the basin.

  17. Magma storage and plumbing of adakite-type post-ophiolite intrusions in the Sabzevar ophiolitic zone, northeast Iran (United States)

    Jamshidi, K.; Ghasemi, H.; Troll, V. R.; Sadeghian, M.; Dahren, B.


    Subduction-related adakite-type intrusive rocks emplaced into the late Cretaceous-Paleocene Sabzevar ophiolite zone, northeast Iran, range from Mg-andesite to rhyodacite in composition. Here we investigate the magma supply system to these subvolcanic intrusive rocks by applying thermobarometric mineral and mineral-melt equilibrium models, including amphibole thermobarometry, plagioclase-melt thermobarometry and clinopyroxene-melt barometry. Based on the results of these thermobarometric models, plagioclase crystallized dominantly at pressures of ~350 (130 to 468) MPa, while amphiboles record both low pressures (~300 MPa) and very high pressures (>700 MPa) of crystallization. The latter is supported by the calculated pressures for clinopyroxene crystallization (550 to 730 MPa). The association of amphibole with clinopyroxene and no plagioclase in the most primitive samples (Mg-andesites) is consistent with amphibole fractionation from very hydrous magmas at deep crustal levels of the plumbing system, which may have been a key process in intensifying adakite-type affinities in this rock suite. Barometry, combined with frequent disequilibrium features such as oscillatory-zoned and sieve-textured plagioclase crystals with An-rich overgrowths in more evolved samples, implies that final magma differentiation occurred in an open upper crustal magma system that developed progressively stronger compositional modifications during high-level magma storage.

  18. Magma storage and plumbing of adakite-type post-ophiolite intrusions in the Sabzevar ophiolitic zone, NE Iran (United States)

    Jamshidi, K.; Ghasemi, H.; Troll, V. R.; Sadeghian, M.; Dahren, B.


    Subduction-related adakite-type intrusive rocks emplaced into the late Cretaceous-Paleocene Sabzevar ophiolite zone, NE Iran, range from Mg-andesite to rhyodacite in composition. Here we investigate the magma supply system to these subvolcanic intrusive rocks by applying thermobarometric mineral and mineral-melt equilibrium models, including amphibole thermobarometry, plagioclase-melt thermobarometry and clinopyroxene-melt barometry. Based on the results of these thermobarometric models, plagioclase crystallized dominantly at pressures of ~ 350 (468-130) MPa, while amphiboles record both low pressures (~ 300 MPa) and very high pressures (> 700 MPa) of crystallization. The latter is supported by the calculated pressures for clinopyroxene crystallization (550 to 730 MPa). The association of amphibole with clinopyroxene and no plagioclase in the most primitive samples (Mg-andesites) is consistent with amphibole fractionation from very hydrous magmas at deep crustal levels of the plumbing system, which may have been a key process to intensify adakite-type affinities in this rock suite. Barometry, combined with frequent disequilibrium features, such as oscillatory-zoned and sieve-textured plagioclase crystals with An-rich overgrowths in more evolved samples, imply final magma differentiation occurred in an open upper crustal magma system that developed progressively stronger compositional modifications during high-level magma storage.

  19. The Chahnaly low sulfidation epithermal gold deposit, western Makran volcanic arc, southeastern Iran (United States)

    Sholeh, Ali; Rastad, Ebrahim; Huston, David L.; Gemmell, J. Bruce; Taylor, Ryan D.


    The Chahnaly low-sulfidation epithermal Au deposit and nearby Au prospects are located northwest of the intermittently active Bazman stratovolcano on the western end of the Makran volcanic arc, which formed as the result of subduction of the remnant Neo-Tethyan oceanic crust beneath the Lut block. The arc hosts the Siah Jangal epithermal and Kharestan porphyry prospects, near Taftan volcano, as well as the Saindak Cu-Au porphyry deposit and world-class Reko Diq Cu-Au porphyry deposit, near Koh-i-Sultan volcano to the east-northeast in Pakistan. The host rocks for the Chahnaly deposit include early Miocene andesite and andesitic volcaniclastic rocks that are intruded by younger dacitic domes. Unaltered late Miocene dacitic ignimbrites overlie these rocks. Laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) U-Pb zircon geochronology data yield ages between 21.8 and 9.9 Ma for the acidic-intermediate regional volcanism. The most recent volcanic activity of the Bazman stratovolcano involved extrusion of an olivine basalt during Pliocene to Quaternary times. Interpretation of geochemical data indicate that the volcanic rocks are synsubduction and calc-alkaline to subalkaline. The lack of a significant negative Eu anomaly, a listric-shaped rare earth element pattern, and moderate La/Yb ratios of host suites indicate a high water content of the source magma.

  20. Orthopyroxene-enrichment in the lherzolite-websterite xenolith suite from Paleogene alkali basalts of the Poiana Ruscă Mountains (Romania) (United States)

    Nédli, Zsuzsanna; Szabó, Csaba; Dégi, Júlia


    In this paper we present the petrography and geochemistry of a recently collected lherzolite-websterite xenolith series and of clinopyroxene xenocrysts, hosted in Upper Cretaceous-Paleogene basanites of Poiana Ruscă (Romania), whose xenoliths show notable orthopyroxene-enrichment. In the series a slightly deformed porphyroclastic-equigranular textured series could represent the early mantle characteristics, and in many cases notable orthopyroxene growth and poikilitic texture formation was observed. The most abundant mantle lithology, Type A xenoliths have high Al and Na-contents but low mg# of the pyroxenes and low cr# of spinel suggesting a low degree (andesitic magmatism of Poiana Ruscă. Type B xenoliths, with their slightly different chemistry, suggest that, after the ancient depletion, the mantle went through a slight metasomatic event. A subsequent passage of mafic melts in the mantle, with similar compositions to the older andesitic magmatism of Poiana Ruscă, is recorded in the pyroxenites (Fe-rich xenoliths), whereas the megacrysts seem to be cogenetic with the host basanite. The Poiana Ruscă xenoliths differ from the orthopyroxene-enriched mantle xenoliths described previously from the Carpathian-Pannonian Region and from the Dacia block.

  1. Rb–Sr and Sm–Nd isotope systematics and geochemical studies on metavolcanic rocks from Peddavura greenstone belt: Evidence for presence of Mesoarchean continental crust in easternmost part of Dharwar Craton, India

    Indian Academy of Sciences (India)

    M Rajamanickam; S Balakrishnan; R Bhutani


    Linear, north–south trending Peddavura greenstone belt occurs in easternmost part of the Dharwar Craton. It consists of pillowed basalts, basaltic andesites, andesites (BBA) and rhyolites interlayered with ferruginous chert that were formed under submarine condition. Rhyolites were divided into type-I and II based on their REE abundances and HREE fractionation. Rb–Sr and Sm–Nd isotope studies were carried out on the rock types to understand the evolution of the Dharwar Craton. Due to source heterogeneity Sm–Nd isotope system has not yielded any precise age. Rb–Sr whole-rock isochron age of 2551 ± 19 (MSWD = 1.16) Ma for BBA group could represent time of seafloor metamorphism after the formation of basaltic rocks. Magmas representing BBA group of samples do not show evidence for crustal contamination while magmas representing type-II rhyolites had undergone variable extents of assimilation of Mesoarchean continental crust (< 3.3 Ga) as evident from their initial Nd isotope values. Trace element and Nd isotope characteristics of type I rhyolites are consistent with model of generation of their magmas by partial melting of mixed sources consisting of basalt and oceanic sediments with continental crustal components. Thus this study shows evidence for presence of Mesoarchean continental crust in Peddavura area in eastern part of Dharwar Craton.

  2. Gabbroic xenoliths in alkaline lavas in the region of Sanganguey Volcano, Nayarit, Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Giosa, T.A.; Nelson, S.A.


    Gabbroic xenoliths occur in alkaline cinder cones and lava flows erupted from vents along five parallel lines trending through the calc-alkaline volcano, Sanganguey in the northwestern portion of the Mexican Volcanic Belt. The xenoliths consist of varying proportions of olivine, clinopyroxene, orthopyroxene, and plagioclase. The complete lack of hydrous phases indicates that the gabbros crystallized under conditions of low PH/sub 2/O. Many xenoliths show textures indicative of a cumulate origin and others exhibit recrystallization indicative of subsolidus reactions prior to incorporation in the host liquids. Reaction between xenolithic minerals and host liquids are also observed. The range of Mg numbers calculated for liquids that would have been in equilibrium with olivines in the xenoliths suggests that these olivines crystallized from magmas such as those represented by either calc-alkaline basaltic andesites and andesites or the more evolved alkalic rocks which occur throughout the area. Crystal fractionation models show that the xenoliths may be related to such magmas. The fact that xenoliths occur most commonly in the alkaline rocks suggests that alkaline magmas rise to the surface more rapidly than the more chemically evolved calc-alkaline and alkaline magmas. Alternatively the lack of xenoliths in the more evolved magmas produced by high level crystal fractionation may indicate that the xenoliths are derived from zones below that from which the differentiated magmas begin their final ascent to the surface.

  3. Multivariate Analysis, Mass Balance Techniques, and Statistical Tests as Tools in Igneous Petrology: Application to the Sierra de las Cruces Volcanic Range (Mexican Volcanic Belt

    Directory of Open Access Journals (Sweden)

    Fernando Velasco-Tapia


    Full Text Available Magmatic processes have usually been identified and evaluated using qualitative or semiquantitative geochemical or isotopic tools based on a restricted number of variables. However, a more complete and quantitative view could be reached applying multivariate analysis, mass balance techniques, and statistical tests. As an example, in this work a statistical and quantitative scheme is applied to analyze the geochemical features for the Sierra de las Cruces (SC volcanic range (Mexican Volcanic Belt. In this locality, the volcanic activity (3.7 to 0.5 Ma was dominantly dacitic, but the presence of spheroidal andesitic enclaves and/or diverse disequilibrium features in majority of lavas confirms the operation of magma mixing/mingling. New discriminant-function-based multidimensional diagrams were used to discriminate tectonic setting. Statistical tests of discordancy and significance were applied to evaluate the influence of the subducting Cocos plate, which seems to be rather negligible for the SC magmas in relation to several major and trace elements. A cluster analysis following Ward’s linkage rule was carried out to classify the SC volcanic rocks geochemical groups. Finally, two mass-balance schemes were applied for the quantitative evaluation of the proportion of the end-member components (dacitic and andesitic magmas in the comingled lavas (binary mixtures.

  4. Geochemistry and geochronology of late Mesozoic volcanic rocks in the northern part of the Eastern Pontide Orogenic Belt (NE Turkey): Implications for the closure of the Neo-Tethys Ocean (United States)

    Özdamar, Şenel


    This paper presents 40Ar/39Ar and U-Pb age data, Sr-Nd isotopes, whole-rock and mineral compositions of Upper Cretaceous volcanic rocks from the Ordu area of the Eastern Pontide Orogenic Belt (EPOB) in northeastern Turkey. The volcanic rocks exhibit a wide compositional range: basalt, basaltic-andesites, andesites and a rhyodacite suite; they are characterized by subparallel light rare earth element (LREE)-enrichment, relatively flat heavy rare earth element (HREE) patterns with Eu anomalies and moderate fractionation [average (La/Yb)N = 8.55]. The geochemical results show that the volcanic rocks have calc-alkaline affinity consistent with arc volcanic rocks erupted in an active continental margin. Initial 87Sr/86Sr values vary between 0.70569 and 0.70606, while initial 143Nd/144Nd values lie between 0.51244 and 0.51249. Crustal contamination affected the mantle-originated primary magma, as indicated by increased 87Sr/86Sr and decreased 143Nd/144Nd ratios with increasing SiO2. New precise laser ablation inductively coupled plasma mass spectrometer (LA-ICP-MS) 206Pb-238U age analyses of zircon and 40Ar/39Ar age data of plagioclase from the volcanics enable a more precise reconstruction of the EBOP. The ages provide insight into the timing of arc formation in this region, constrain the volcanic activity between 86 My (Coniacian) and 75 My (Campanian) and constrain the timing of closure of the Neo-Tethys.

  5. Mineral Chemistry and Geochemistry of Volcanic Rocks in The North of Pasinler (Erzurum

    Directory of Open Access Journals (Sweden)

    Oktay KILIÇ


    Full Text Available In the north of Pasinler (Erzurum, Upper Miocene-Pliocene volcanic rocks crop out. These volcanites are composed of basaltic andesite, andesite, dacite, rhyolite lavas and rhyolitic pyroclastics. The rocks show porphyritic, microlitic porphyritic, hyalo-microlitic porphyritic, vitrophyric, glomeroporphyritic, pilotaxitic and hyalopilitic textures. The investigated volcanites contain plagioclase (An29-80, olivine (Fo65-82, clinopyroxene (augite, orthopyroxene (enstatite, amphibole (Mg#: 0.57-0.71, biotite (phlogopite: 0.44-0.47, annite: 0.33-0.37, sanidine, quartz and opaque mineral (titano-magnetite and ilmenite. The volcanic rocks are calc-alkaline in character and have medium to high-K contents. Major oxide and trace element variations point out open-system magmatic differentiation in the evolution of rocks. Geochemical data indicate an important role of fractionation of phenocryst phases in the rocks during differentiation process. However, it is considered that assimilation±magma mixing might have accompanied to the process. High LILE (K, Rb, Ba, Th and relatively low HFSE (Nb, Ta, Hf, Zr contents of the rocks indicate that these rocks derived from parental magmas carrying subduction signature.

  6. Tectonic setting of Late Cenozoic gold mineralization in the gold belt of Costa Rica

    Energy Technology Data Exchange (ETDEWEB)

    Deruyter, V.D.


    The Gold Belt of Costa Rica is a northwest-elongated zone 15 km wide by 120 km long containing numerous auriferous quartz veins and pyritic silicified patterns upon which abundant small mines are developed. Gold veins are related principally to northeast-southwest and north-south striking, steeply dipping faults. Higher grade ore and thicker veins invariably occur at intersections of these fracture orientations, indicating simultaneous opening at the time of gold introduction. Restriction of gold veins to the northwest-trending arc of Miocene Aguacate Group andesite volcanic rocks, a product of Cocos Plate subduction, suggested approximately coeval formation, but recognition by the writer of the important role played by 2-5 m.y. old altered, gold mineralized rhyolite dikes intruded along north-south gold vein structures and intimately involved with high grade ores at the Esperanza Mine and Rio Chiquito prospect, for example, suggest a much younger period of fracturing and gold introduction. The rhyolite intrusions are more brittle and stockwork mineralized than andesite host rocks and form bulk tonnage gold targets. Initiation of right-lateral movement along the north-south Panama Fracture Zone at 5 m.y.a. within the pattern of northeastward Cocos Plate subduction may have tapped rhyolites from subvolcanic magma chambers into new faults.

  7. Some aspects of the volcanology and geochemistry of the Tengger Caldera, Java, Indonesia: eruption of a K-rich tholeiitic series (United States)

    van Gerven, M.; Pichler, H.

    The Tengger Caldera together with the active Mount Bromo is situated in Java, Indonesia. Though activity of Mt Bromo has been recorded since 1804, little modern petrographic and geochemical data is available. In this study we provide a detailed petrographic and stratigraphic description of the two major caldera units, i.e. the "pre-caldera formation" and the "post-caldera formation". A zonal arrangement of the alkali content of the Sunda arc volcanoes, i.e. an increase of the alkali content in the lavas across the arc from the trench to the backarc basin, has been noticed for many years. In contrast to the common classification of the geochemistry and magmatic affinity of the Javanese volcanoes related to the depth of the Benioff zone (100-150 km for tholeiitic rocks and 150-250 km for calc-alkaline rocks), we found a tholeiitic trend expressed by increasing FeO∗/MgO with increasing SiO 2 and an average {Zr}/{Y} ratio of 4.9 for the Tengger Caldera volcanics (Benioff zone depth ca 200 km), despite high alkali contents (K 2O > 2 wt%). These features characterize the Tengger Caldera volcanics as medium to high-K tholeiitic andesites and basaltic andesites.

  8. Eclogite-melt/peridotite reaction: Experimental constrains on the destruction mechanism of the North China Craton

    Institute of Scientific and Technical Information of China (English)


    To study the mechanism of melt-peridotite reaction pertinent to the destruction of the North China Craton (NCC) lithosphere, a series of experiments were performed at a pressure of 2.0 GPa and temperatures from 1250 to 1400°C using Bixiling eclogite and Damaping peridotite as starting materials. The experimental results show that the reaction between eclogite melt and peridotite causes dissolution of olivine and orthopyroxene and precipitation of clinopyroxene in the melt. The experimental run products, characterized by a lherzolite/pyroxenite/garnet-pyroxenite sequence, are consistent with the mantle xenoliths in the Neogene Hannuoba basalt of the NCC found by Liu et al. (2005). It suggests that the mafic lower continental crust was probably recycled into the mantle during the Mesozoic Era. In the experiments conducted at 1300 and 1350°C, the resulting melts have a high Mg# andesite signature, indicating that the melt-peridotite reaction may have played a major role in the generation of high Mg# andesite. Our experimental results support the hypothesis that melts derived from foundered eclogite in the asthenosphere will consume the lithospheric peridotites. Therefore, melt-peridotite reaction is an important mechanism for the destruction/thinning of the lithosphere.

  9. 印度与欧亚板块东部碰撞边界——腾冲火山岩的Nd-Sr同位素与微量元素研究

    Institute of Scientific and Technical Information of China (English)

    朱炳泉; 毛存孝


    The Tengchong volcanies in western Yunnan Province, China, are located in the eastern part of the collision margin between Indian and Eurasian Plates. Alternating extention and compression controlled the eruption, from late Tertiary to Holeeno, of at least 5 groups of volcanics consisting of a Major series of hlgh-Al basalts (3 groups), a high-K andesite-dacite group and a high-Mg basalt group. The Major series has a range of GNd from +0.7 to-6.7 and Sr87/Sr86 from 0.70595 to 0.70881, exhibiting good linear correlations between Zr/Ni and Zr as well as between Nd. and both Sm/Nd and 1/Nd and similar chondrite-normalized incompatible element patterns. This suggests an ecologitic source metasomatized with fluids derived from parts of thesubducted Indian plate.The high-K andesite-dacite group shows a more extreme isotopic composition of GNd=-12.3, Sr87/Sr66=0.71124. It is chemically comparable to the calc-alkaline lavas in Xizang and could be resulted from mixing between shallow mantle zones and lower crust. The high-Mg basalt group has Sr87/Sr86-0.708 and slightly negative GNd (-2). They are similar, in chemical composition and possibly also in source, to the intraplate basalts in east China. A partial melting model of isotopic tmequilibrium system has been proposed to explain the isotope and trace element correlations of Tengchong volcanics.

  10. Making continental crust: The sanukitoid connection

    Institute of Scientific and Technical Information of China (English)

    Yoshiyuki TATSUMI


    The average continental crust possesses intermediate compositions that typify arc magmatism and as a result it is believed to have been created at ancient convergent plate boundaries. One possible mechanism for intermediate continental crust formation is the direct production of andesitic melts in the upper mantle. Sanukitoids, which characterize the Setouchi volcanic belt, SW Japan, include unusually high-Mg andesites (HMA). They were generated by slab melting and subsequent melt-mantle interactions under unusual tectonic settings such as where warm lithosphere subducts into hot upper mantle. Such conditions would have existed in the Archean. Hydrous HMA magmas are likely to have solidified within the crust to form HMA plutons, which were then remelted to produce differentiated sanukitoids. At present, generation and differentiation of HMA magmas may be taking place in the Izu-Bonin-Mariana arc-trench system (IBM), because (1) HMA magmatism characterizes the initial stages of the iBM evolution and (2) the IBM middle crust exhibits Vp identical to that of the bulk continental crust. Vp estimates for plutonic rocks with HMA compositions support this. However tonalitic composition for middle-crust-forming rocks cannot be ruled out, suggesting an alternative possibility that the continental crust has been created by differentiation of mantle-derived basaltic magmas.

  11. Geochemistry and petrogenesis of Early Cretaceous volcanic rocks from Mengyin basin%蒙阴盆地早白垩世火山岩地球化学特征及其岩石成因

    Institute of Scientific and Technical Information of China (English)

    牛漫兰; 傅朋远; 吴齐; 朱光; 夏文静


    蒙阴盆地早白垩世火山岩主要出露于青山群八亩地组和方戈庄组中.火山岩SiO2含量为53.71% ~ 69.08%,主要为安山质岩石和流纹岩,以钙碱性系列为主(σ平均3.42);富集Rb、Ba等大离子亲石元素和轻稀土元素,相对亏损Nb、Ta、P、Ti等高场强元素和重稀土元素;具有富集的Sr-Nd-Pb同位素组成(87Sr/86Sr(t)=0.7051~ 0.7110,εNd(t)=-5.16~-16.4).根据MgO含量和Mg#值,可将安山质火山岩划分为高镁(Mg #>60)和低镁(Mg#<60)两个系列.高镁安山质岩石的MgO、Cr、Ni及不相容元素的含量明显高于低镁安山质岩石,且具有相对高的87Sr/86Sr(t)和较低的εNd(t)值,Sr-Nd同位素组成趋向于EMⅡ型富集地慢端元.低镁安山质岩石地球化学特征类似于埃达克岩,其同位素组成介于EM Ⅰ型富集地幔端元与华北麻粒岩相下地壳之间.流纹岩具有较低的MgO、Cr、Ni含量和明显的负Eu、Sr异常,同位素组成类似于扬子中、上地壳.研究表明,蒙阴盆地高镁安山质岩石由曾遭受俯冲扬子陆壳熔体改造的华北岩石圈地幔部分熔融形成,且岩浆在上升过程中经历了华北下地壳物质一定程度的混染或混合作用;低镁安山质岩石主要由华北下地壳部分熔融形成;流纹岩为岩石圈伸展减薄背景下仰冲至华北克拉通之上的扬子中、上地壳部分熔融的产物.地质现象显示,郯庐断裂带的伸展活动控制着蒙阴断陷盆地的发育,与蒙阴盆地早白垩世火山岩的成因有着密切的联系,在华北克拉通破坏中可能起到了重要的作用.%Early Cretaceous volcanic rocks in Mengyin basin are exposed in Bamudi and Fanggezhuang formations. These rocks are mainly andesitic rocks and rhyolites with SiO2 contents varied between 53.71% ~69. 08% , belong to calc-alkaline to alkaline series ( with a average of σ = 3. 42). These volcanic rocks are characterized by large ion lithophile element ( LILE) , light

  12. Newly developed evidence for the original Tethysan island-arc volcanic rocks in the southern segment of the South Lancangjiang Belt

    Institute of Scientific and Technical Information of China (English)


    This paper re-describes the characteristics of pre-Ordovician (Pt3) metamorphic volcanic rocks in the Huimin-Manlai region of Yunnan Province from the aspects of petrographic characteristics, rock assemblage, petrochemistry, REE, trace elements, lead isotopes and geotectonic setting. The metamorphic volcanic rocks maintain blasto-intergranular and blasto-andesitic textures; the volcanic rocks are characterized by a basalt-andesite-dacite assemblage; the volcanic rocks are basic-intermediate-intermediate-acid in chemical composition, belonging to semi-alkaline rocks, with calc-alkaline series and tholeiite series coexisting, and they are characterized by low TiO2 contents; their REE distribution patterns are of the LREE-enrichment right-inclined type; the volcanic rocks are enriched in large cation elements and commonly enriched in Th and partly depleted in Ti, Cr and P, belonging to the Gondwana type as viewed from their Pb isotopic composition; petrochemically the data points fall mostly within the field of island-arc volcanic rocks. All these characteristics provided new evidence for the existence of original Tethysan island-arc volcanic rocks in the region studied.

  13. The off-crust origin of granite batholiths

    Institute of Scientific and Technical Information of China (English)

    Antonio Castro


    Granitod batholiths of I-type features (mostly granodiorites and tonalites), and particularly those forming the large plutonic associations of active continental margins and intracontinental collisional belts, represent the most outstanding magmatic episodes occurred in the continental crust. The origin of magmas, however, remains controversial. The application of principles from phase equilibria is crucial to understand the problem of granitoid magma generation. An adequate comparison between rock com-positions and experimental liquids has been addressed by using a projected compositional space in the plane F(Fe þ Mg)eAnorthiteeOrthoclase. Many calc-alkaline granitoid trends can be considered cotectic liquids. Assimilation of country rocks and other not-cotectic processes are identified in the projected diagram. The identification of cotectic patterns in batholith implies high temperatures of magma segregation and fractionation (or partial melting) from an intermediate (andesitic) source. The com-parison of batholiths with lower crust granulites, in terms of major-element geochemistry, yields that both represent liquids and solid residues respectively from a common andesitic system. This is compatible with magmas being formed by melting, and eventual reaction with the peridotite mantle, of subducted mélanges that are finally relaminated as magmas to the lower crust. Thus, the off-crust generation of granitoids batholiths constitutes a new paradigm in which important geological implica-tions can be satisfactorily explained. Geochemical features of Cordilleran-type batholiths are totally compatible with this new conception.

  14. Magma storage and plumbing of adakite-type post-ophiolite intrusions in the Sabzevar ophiolitic zone, NE Iran

    Directory of Open Access Journals (Sweden)

    K. Jamshidi


    Full Text Available Subduction-related adakite-type intrusive rocks emplaced into the late Cretaceous-Paleocene Sabzevar ophiolite zone, NE Iran, range from Mg-andesite to rhyodacite in composition. Here we investigate the magma supply system to these subvolcanic intrusive rocks by applying thermobarometric mineral and mineral-melt equilibrium models, including amphibole thermobarometry, plagioclase-melt thermobarometry and clinopyroxene-melt barometry. Based on the results of these thermobarometric models, plagioclase crystallized dominantly at pressures of ~ 350 (468–130 MPa, while amphiboles record both low pressures (~ 300 MPa and very high pressures (> 700 MPa of crystallization. The latter is supported by the calculated pressures for clinopyroxene crystallization (550 to 730 MPa. The association of amphibole with clinopyroxene and no plagioclase in the most primitive samples (Mg-andesites is consistent with amphibole fractionation from very hydrous magmas at deep crustal levels of the plumbing system, which may have been a key process to intensify adakite-type affinities in this rock suite. Barometry, combined with frequent disequilibrium features, such as oscillatory-zoned and sieve-textured plagioclase crystals with An-rich overgrowths in more evolved samples, imply final magma differentiation occurred in an open upper crustal magma system that developed progressively stronger compositional modifications during high-level magma storage.

  15. Formation of cordierite-bearing lavas during anatexis in the lower crust beneath Lipari Island (Aeolian arc, Italy) (United States)

    di Martino, Corrado; Forni, Francesca; Frezzotti, Maria Luce; Palmeri, Rosaria; Webster, James D.; Ayuso, Robert A.; Lucchi, Federico; Tranne, Claudio A.


    Cordierite-bearing lavas (CBL;~105 ka) erupted from the Mt. S. Angelo volcano at Lipari (Aeolian arc, Italy) are high-K andesites, displaying a range in the geochemical and isotopic compositions that reflect heterogeneity in the source and/or processes. CBL consist of megacrysts of Ca-plagioclase and clinopyroxene, euhedral crystals of cordierite and garnet, microphenocrysts of orthopyroxene and plagioclase, set in a heterogeneous rhyodacitic-rhyolitic groundmass containing abundant metamorphic and gabbroic xenoliths. New petrographic, chemical and isotopic data indicate formation of CBL by mixing of basaltic-andesitic magmas and high-K peraluminous rhyolitic magmas of anatectic origin and characterize partial melting processes in the lower continental crust of Lipari. Crustal anatectic melts generated through two main dehydration-melting peritectic reactions of metasedimentary rocks: (1) Biotite + Aluminosilicate + Quartz + Albite = Garnet + Cordierite + K-feldspar + Melt; (2) Biotite + Garnet + Quartz = Orthopyroxene + Cordierite + K-feldspar + Melt. Their position into the petrogenetic grid suggests that heating and consequent melting of metasedimentary rocks occurred at temperatures of 725 Lipari was induced by protracted emplacement of basic magmas in the lower crust (~130 Ky). Crustal melting of the lower crust at 105 ka affected the volcano evolution, impeding frequent mafic-magma eruptions, and promoting magma stagnation and fractional crystallization processes.


    di Martino, C.; Frezzotti, M.; Lucchi, F.; Peccerillo, A.; Tranne, C. A.; Diamond, L.


    Fluid inclusion study, together with structural, volcanological and petrochemical data, allow reconstruction of the magma feeding system of basaltic-andesitic to andesitic volcanoes during the oldest and intermediate stages of development of Lipari Island (223-81 ka). A major magma storage zone is active during the overall investigated time span at depths of ~22 km close to the crust-mantle Moho transition, at which mantle-derived mafic magmas tend to accumulate due to neutral buoyancy conditions. A shallow magma reservoir is found at depths of 5.5-3.5 km in correspondence of a major lithological discontinuity within the upper crust beneath central-type volcanoes (M. Mazzacaruso, M. S.Angelo, M. Chirica-Costa d'Agosto). It is the place where magmas shortly rest (day-week time scale) before the eruption. For fissural-type volcanoes (Timpone Ospedale, Monterosa, M. Chirica), tectonic structures are suggested to intercept magma batches at different crustal depths (~14 km), thus provoking CO2-degassing and rapid magma uprising with no substantial ponding at shallow levels. Partial crustal melting processes at roof of the deep magma reservoirs are invoked to explain conditions of fluids trapping at depths of volcanoes, active during the intermediate stages of development of Lipari (105-81 ka). These melting processes determine the generation of felsic melts which may act as a density-barrier and prevent the uprising of mantle-derived magmas, with an influence on the subsequent evolution of the magma feeding system of Lipari.

  17. Magma storage and ascent at Lipari Island (Aeolian archipelago, Southern Italy) at 223-81 ka: the role of crustal processes and tectonic influence (United States)

    di Martino, Corrado; Frezzotti, Maria Luce; Lucchi, Federico; Peccerillo, Angelo; Tranne, Claudio A.; Diamond, Larryn W.


    Fluid inclusion studies together with volcanological and petrochemical data allow reconstruction of the magma feeding system of basaltic-andesitic to andesitic activity during the oldest and intermediate stages of development of Lipari Island (223-81 ka). A major magma storage zone is active during the overall investigated time span at depths of 22 km, close to the crust-mantle Moho transition, at which mantle-derived mafic magmas tend to accumulate due to neutral buoyancy conditions. Beneath central-type volcanoes (M. Mazzacaruso, M. S.Angelo, M. Chirica-Costa d’Agosto), a shallower magma reservoir is located within the upper crust at 5.5-3.5 km, associated with a major lithological discontinuity. For fissural-type volcanoes (Timpone Ospedale, Monterosa, M. Chirica), tectonic structures are suggested to influence further magma ascent and storage at mid-crustal depths (˜14 km), with no ponding at shallower levels. Partial crustal melting processes at the roofs of the deep magma reservoirs (˜17 km) are invoked to explain the origin of cordierite-bearing lavas beneath M. S.Angelo and M. Chirica-Costa d’Agosto volcanoes, which were active during the intermediate stages of development of Lipari (105-81 ka). The generation of felsic anatectic melts in the lower crust could have created density and rheologic barriers to impede the passage of mafic melts and promote their ponding, with influence on the subsequent evolution of Lipari volcano.

  18. Unmasking Sinkings Zones Caused by Subsidence-Creep Processes in Morelia, MICHOACÁN, Using Insar and GIS (United States)

    Alejandro, Avila-Olivera Jorge; Paolo, Farina; Hugo, Garduño-Monroy Victor


    In Morelia City since the beginning of the 1980s, problems of differential sinkings, crackings and superficial faults affecting natural and anthropogenic structures have been observed. At the present time the city is being affected by nine faults, eight of which are related to Subsidence-Creep-Fault Processes (SCFP) and display a preferential direction ENE-WSW, identical to the Tula-Chapala regional faulting system. As part of the SCFP studies, GDPS and InSAR monitoring have been carried out; both showed that the maximum sinkings (3. 5 cm/year, summer 2003-summer 2007) are located in the NW part of the city, considered stable (in the past) due to the coverage of Pleistocene-Holocene basaltic-andesitic materials of Quinceo volcano. In order to resolve the enigma, all the available information related to the SCFP in the city have been integrated in a GIS; as well as two analysis of lithology columns were carried out to obtain a surface of the spatial distribution of the thickness of compressible materials in the city. The first analysis just increased the doubts, but the second one showed that the subsoil in the NW portion of Morelia consists of an interleave between basaltic-andesitic products of Quinceo volcano and lacustrine and/or fluviolacustrine sediments able to suffer deformations induced by groundwater withdrawal, which have been masked by the superficial volcanic products, that in addition are responsible of accelerating the process of land subsidence (sinkings) in function of weight these represent.

  19. Eruptive parameters and dynamics of the April 2015 sub-Plinian eruptions of Calbuco volcano (southern Chile) (United States)

    Castruccio, Angelo; Clavero, Jorge; Segura, Andrea; Samaniego, Pablo; Roche, Olivier; Le Pennec, Jean-Luc; Droguett, Bárbara


    We conducted geological and petrological analyses of the tephra fallout and pyroclastic density current (PDC) products of the 22-23 April 2015 Calbuco eruptions. The eruptive cycle consisted of two sub-Plinian phases that generated > 15 km height columns and PDCs that travelled up to 6 km from the vent. The erupted volume is estimated at 0.38 km3 (non-DRE), with approximately 90% corresponding to tephra fall deposits and the other 10% to PDC deposits. The erupted products are basaltic-andesite, 54-55 wt.% SiO2, with minor amounts of andesite (58 wt.% SiO2). Despite the uniform composition of the products, there are at least four types of textures in juvenile clasts, with different degrees of vesicularity and types and content of crystals. We propose that the eruption triggering mechanism was either exsolution of volatiles due to crystallization, or a small intrusion into the base of the magma chamber, without significant magma mixing or with a magma compositionally similar to that of the residing magma. In either case the triggering mechanism generated convection and sufficient overpressure to promote the first eruptive phase. The start of the eruption decompressed the chamber, promoting intense vesiculation of the remaining magma and an increase in eruption rate towards the end of the eruption.

  20. Geology, geochemistry, geochronology, and economic potential of Neogene volcanic rocks in the Laguna Pedernal and Salar de Aguas Calientes segments of the Archibarca lineament, northwest Argentina (United States)

    Richards, J. P.; Jourdan, F.; Creaser, R. A.; Maldonado, G.; DuFrane, S. A.


    This study presents new geochemical, geochronological, isotopic, and mineralogical data, combined with new geological mapping for a 2400 km2 area of Neogene volcanic rocks in northwestern Argentina near the border with Chile, between 25°10‧S and 25°45‧S. The area covers the zone of intersection between the main axis of the Cordillera Occidental and a set of NW-SE-trending structures that form part of the transverse Archibarca lineament. This lineament has localized major ore deposits in Chile (e.g., the late Eocene La Escondida porphyry Cu deposit) and large volcanic centers such as the active Llullaillaco and Lastarría volcanoes on the border between Chile and Argentina, and the Neogene Archibarca, Antofalla, and Cerro Galán volcanoes in Argentina. Neogene volcanic rocks in the Laguna Pedernal and Salar de Aguas Calientes areas are mostly high-K calc-alkaline in composition, and range from basaltic andesites, through andesites and dacites, to rhyolites. Magmatic temperatures and oxidation states, estimated from mineral compositions, range from ~ 1000 °C and ∆FMQ ≈ 1.0-1.5 in andesites, to ~ 850 °C and ∆FMQ ≈ 1.5-2.0 in dacites and rhyolites. The oldest rocks consist of early-middle Miocene andesite-dacite plagioclase-pyroxene-phyric lava flows and ignimbrites, with 40Ar/39Ar ages ranging from 17.14 ± 0.10 Ma to 11.76 ± 0.27 Ma. Their major and trace element compositions are typical of the Andean Central Volcanic Zone, and show strong crustal contamination trends for highly incompatible elements such as Cs, Rb, Th, and U. These rocks are geochemically grouped as sub-suite 1. This widespread intermediate composition volcanism was followed in the middle-late Miocene by a period of more focused rhyodacitic flow-dome complex formation. These felsic rocks are characterized by less extreme enrichments in highly incompatible elements, and increasing depletion of heavy rare earth elements. These rocks are geochemically grouped as sub-suite 2. The

  1. Mineralogy and geochemistry of xenoliths in the Eocene volcanic rocks from southwest of Jandaq

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    Samineh Rajabi


    Full Text Available The Eocene volcanic rocks from the southwest of the Jandaq (Kuh-e-Godar-e-Siah, Central-East Iran micro-continent are andesitic basalt and andesite in composition. These rocks contain xenoliths with granulitic mineralogy. Mineral assemblage of these xenoliths is plagioclase + phlogopite + corundum + sillimanite + chlorite + phengite with granublastic, poiklioblastic and foliated textures in the pick metamorphic condition. Thermometry of phlogopite in these xenoliths suggests the average temperature 782oC. The characteristics of the xenoliths are consistent with the granolitic facies metamorphism of the Al-saturated Si-undersaturated crustal sediments at the lower crust condition. Melting of these granulites forms the magma which crystallized the S-type granitoids. Differentiation and crystallization of this magma causes the S-type granite formation. Therefore, the S-type granites in the study area are probably generated from melting of the granulites parts of which brought to the surface as xenoliths by Eocene magmatism in south of the Jandaq (Kuh-e-Godar-e-Siah. S-type granites in the study area are located along the Doruneh, Chupanan and Aeirakan faults in the Aeirakan area and Jandaq ophiolite. These granites are the source of uranium, thorium and uranium ore in southwest of the Aeirakan mountain.

  2. The Ahuachapan geothermal field, El Salvador: Reservoir analysis

    Energy Technology Data Exchange (ETDEWEB)

    Aunzo, Z.; Bodvarsson, G.S.; Laky, C.; Lippmann, M.J.; Steingrimsson, B.; Truesdell, A.H.; Witherspoon, P.A. (Lawrence Berkeley Lab., CA (USA); Icelandic National Energy Authority, Reykjavik (Iceland); Geological Survey, Menlo Park, CA (USA); Lawrence Berkeley Lab., CA (USA))


    The Earth Sciences Division of Lawrence Berkeley Laboratory (LBL) is conducting a reservoir evaluation study of the Ahuachapan geothermal field in El Salvador. This work is being performed in cooperation with the Comision Ejecutiva Hidroelectrica del Rio Lempa (CEL) and the Los Alamos National Laboratory (LANL). This report describes the work done during the first year of the study (FY 1988--89), and includes the (1) development of geological and conceptual models of the field, (2) evaluation of the initial thermodynamic and chemical conditions and their changes during exploitation, (3) evaluation of interference test data and the observed reservoir pressure decline, and (4) the development of a natural state model for the field. The geological model of the field indicates that there are seven (7) major and five (5) minor faults that control the fluid movement in the Ahuachapan area. Some of the faults act as a barrier to flow as indicated by large temperature declines towards the north and west. Other faults act as preferential pathways to flow. The Ahuachapan Andesites provide good horizontal permeability to flow and provide most of the fluids to the wells. The underlying Older Agglomerates also contribute to well production, but considerably less than the Andesites. 84 refs.

  3. Lead and strontium isotopic evidence for crustal interaction and compositional zonation in the source regions of Pleistocene basaltic and rhyolitic magmas of the Coso volcanic field, California (United States)

    Bacon, C.R.; Kurasawa, H.; Delevaux, M.H.; Kistler, R.W.; Doe, B.R.


    The isotopic compositions of Pb and Sr in Pleistocene basalt, high-silica rhyolite, and andesitic inclusions in rhyolite of the Coso volcanic field indicate that these rocks were derived from different levels of compositionally zoned magmatic systems. The 2 earliest rhyolites probably were tapped from short-lived silicic reservoirs, in contrast to the other 36 rhyolite domes and lava flows which the isotopic data suggest may have been leaked from the top of a single, long-lived magmatic system. Most Coso basalts show isotopic, geochemical, and mineralogic evidence of interaction with crustal rocks, but one analyzed flow has isotopic ratios that may represent mantle values (87Sr/86Sr=0.7036,206Pb/204Pb=19.05,207Pb/204Pb=15.62,208Pb/204Pb= 38.63). The (initial) isotopic composition of typical rhyolite (87Sr/86Sr=0.7053,206Pb/204Pb=19.29,207Pb/204Pb= 15.68,208Pb/204Pb=39.00) is representative of the middle or upper crust. Andesitic inclusions in the rhyolites are evidently samples of hybrid magmas from the silicic/mafic interface in vertically zoned magma reservoirs. Silicic end-member compositions inferred for these mixed magmas, however, are not those of erupted rhyolite but reflect the zonation within the silicic part of the magma reservoir. The compositional contrast at the interface between mafic and silicic parts of these systems apparently was greater for the earlier, smaller reservoirs. ?? 1984 Springer-Verlag.

  4. Textural analysis of magmatic enclaves from the Kameni Islands, Santorini, Greece (United States)

    Martin, Victoria M.; Holness, Marian B.; Pyle, David M.


    The Kameni Islands have been the focus of historic volcanic activity on Santorini, Greece. The islands comprise a series of dacite lavas, the erupted compositions of which have remained approximately constant for the last ˜2200 years. The dacite lava flows of Nea Kameni contain a variety of mafic enclaves, distinguished by differences in texture, composition and mechanical behaviour. The mafic enclaves represent chilled fragments of mafic magma that crystallised rapidly on contact with the cooler, more silicic host magma. The absence of chilled margins on the enclaves suggests that the replenishing magma initially formed a dense layer at the base of the chamber. Groundmass textures are interpreted as an indication of the degree of undercooling between the enclaves and the host. Groundmass textural information obtained from the enclaves has been used to determine the relative volumes of replenishing magmas injected into the host magma before eruption, which indicates that the volume of erupted magma is directly proportional to the volume of replenishing magma emplaced in the chamber prior to eruption, which thus may act as a potential eruption trigger. The variety of replenishing magmas implies the existence of a complex conduit and chamber system beneath Santorini volcano. Andesitic enclaves with linear crystal size distributions are thought to have originated as an aphyric andesitic melt expelled from a crystal mush by filter-pressing. Disequilibrium phenocryst assemblages in the lavas and phenocryst-bearing enclaves provide evidence for the entrainment and recycling of older phenocryst populations.

  5. Imaging a 3D geological structure from HEM, airborne magnetic and ground ERT data in Kalat-e-Reshm area, Iran (United States)

    Shirzaditabar, Farzad; Bastani, Mehrdad; Oskooi, Behrooz


    A set of geophysical data collected in an area in Iran are analyzed to check the validity of a geological map that was prepared in connection to a mineral prospecting project and also to image the spatial electrical resistivity distribution. The data set includes helicopter electromagnetic (HEM), airborne magnetic and ground electrical resistivity measurement. Occam approach was used to invert the HEM data to model the resistivity using a layered earth model with fixed thicknesses. The algorithm is based on a nonlinear inverse problem in a least-squares sense. The algorithm was tested on a part of an HEM dataset acquired with a DIGHEM helicopter EM system at Kalat-e-Reshm, Semnan in Iran. The area contains a resistive porphyry andesite that is covered by Eocene sedimentary units. The results are shown as resistivity sections and maps confirming the existence of an arc like resistive structure in the survey area. The resistive andesite seems to be thicker than it is indicated in the geological maps. The results are compared with the reduced to the pole (RTP) airborne magnetic anomaly field data as well as with two ground resistivity profiles. We found reasonable correlations between the HEM 1D resistivity models and 2D models from electrical resistivity tomography (ERT) inversions. A 3D visualization of the 1D models along all flight lines provided a useful tool for the study of spatial variations of the resistivity structure in the investigation area.

  6. The Relationship Between Lithology and Slope Morphology in the Tucson Mountains, Arizona.

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    Kamel Khanchoul


    Full Text Available The relationship between lithology and slope morphology is investigated at eight sites on granitic, andesitic, andsedimentary hillslopes in the Tucson Mountains, Arizona. Several methods are used in the study. Topographic profi lesare constructed. Skewness indices, slope length, and mean slope angles of the different slope profi les are computed andcompared with each other. Debris size analysis has permitted for some profi les, the determination of hillfront/piedmontjunctions. The nature and structural characteristics of the bedrock are the ones that determine the hillslope morphologyin this semi-arid region. There are, as a matter of fact, variations in profi les on the same bedrock nature but differentlyexposed. More precise morphologic studies have been also done in comparing the different lithologic pairs. They havepermitted to show some similarities in shapes. The granitic-andesitic slopes and andesiic-sedimentary slopes are thebest comparisons which show the relationship between lithology and slope morphology. The granitic-sedimentary sloperelationship is shown in the hillfront concavities, mountain front and piedmont mean slope angles.

  7. A New Sample Transect through the Sierra Madre Occidental Silicic Large Igneous Province in Southern Chihuahua State, Mexico: First Stratigraphic, Petrologic, and Geochemical Results (United States)

    Andrews, G. D.; Davila Harris, P.; Brown, S. R.; Anderson, L.; Moreno, N.


    We completed a field sampling transect across the northern Sierra Madre Occidental silicic large igneous province (SMO) in December 2013. Here we present the first stratigraphic, petrological, and geochemical data from the transect between Hidalgo del Parral and Guadalupe y Calvo, Chihuahua, Mexico. This is the first new transect across the SMO in 25 years and the only one between existing NE - SW transects at Chihuahua - Hermosillo and Durango - Mazatlan. The 245 km-long transect along Mexican Highway 24 crosses the boundary between the extended (Basin and Range) and non-extended (Sierra Madre Occidental plateau) parts of the SMO, and allows sampling of previously undescribed Oligocene (?) - early Miocene (?) rhyolitic ignimbrites and lavas, and occasional post-rhyolite, Miocene (?) SCORBA basaltic andesite lavas. 54 samples of rhyolitic ignimbrites (40) and lavas (7), and basaltic andesite lavas (7) were sampled along the transect, including 8 canyon sections with more than one unit. The ignimbrites are overwhelming rhyodacitic (plagioclase and hornblende or biotite phyric) or rhyolitic (quartz (+/- sanidine) in additon to plagioclase and hornblende or biotite phyric) and sparsely to highly phyric. Preliminary petrographic (phenocryst abundances) and geochemical (major and trace element) will be presented and compared to existing data from elsewhere in the SMO. Future work will include U-Pb zircon dating and whole rock and in-zircon radiogenic isotopes analyses.

  8. Thermal Waters in Maguarichi, Chihuahua, Mexico: Influence on Volcanic Rocks Alteration (United States)

    Mascote, C. R.; Espejel-Garcia, V. V.; Villalobos-Aragon, A.


    Piedras de Lumbre, Maguarichi, is located 294 km. to the SW of Chihuahua city, in northern Mexico, in the Sierra Madre Occidental (SMO). The study area is composed of a set of igneous volcanic rocks affected by hydrothermal flows, which apparently run along a fault. Outcrops of hot springs, going out with high pressure, are active all over the year and have no seasonal flow changes. The hydrothermal flows, approximately 20, that reach the surface area at Piedras de Lumbre, are altering the volcanic rocks that surround the hot springs. The study area is highly altered, and evidenced by a variety range of colors in the rock surfaces. The rock samples collected at the region show a crystal growth due to the influence of the salts from the thermal water. The rocks closest to the water openings have a change in its mineralogy, with the mafic minerals, present in andesites, been replaced by carbonates and sulfates, leaving only the clear mineral pseudomorphs. On the crust of the rocks a white layer of material (salts), product of the thermal waters has precipitated. The alteration is perceived only about 5 m. or less around the hot springs. The water, which has high contents of arsenic and sulfates has exerted a strong alteration in rhyolitic and andesitic rocks.

  9. Formation of cordierite-bearing lavas during anatexis in the lower crust beneath Lipari Island (Aeolian arc, Italy) (United States)

    Di, Martino C.; Forni, F.; Frezzotti, M.L.; Palmeri, R.; Webster, J.D.; Ayuso, R.A.; Lucchi, F.; Tranne, C.A.


    Cordierite-bearing lavas (CBL;~105 ka) erupted from the Mt. S. Angelo volcano at Lipari (Aeolian arc, Italy) are high-K andesites, displaying a range in the geochemical and isotopic compositions that reflect heterogeneity in the source and/or processes. CBL consist of megacrysts of Ca-plagioclase and clinopyroxene, euhedral crystals of cordierite and garnet, microphenocrysts of orthopyroxene and plagioclase, set in a heterogeneous rhyodacitic-rhyolitic groundmass containing abundant metamorphic and gabbroic xenoliths. New petrographic, chemical and isotopic data indicate formation of CBL by mixing of basaltic-andesitic magmas and high-K peraluminous rhyolitic magmas of anatectic origin and characterize partial melting processes in the lower continental crust of Lipari. Crustal anatectic melts generated through two main dehydration-melting peritectic reactions of metasedimentary rocks: (1) Biotite + Aluminosilicate + Quartz + Albite = Garnet + Cordierite + K-feldspar + Melt; (2) Biotite + Garnet + Quartz = Orthopyroxene + Cordierite + K-feldspar + Melt. Their position into the petrogenetic grid suggests that heating and consequent melting of metasedimentary rocks occurred at temperatures of 725 crust of Lipari was induced by protracted emplacement of basic magmas in the lower crust (~130 Ky). Crustal melting of the lower crust at 105 ka affected the volcano evolution, impeding frequent maficmagma eruptions, and promoting magma stagnation and fractional crystallization processes. ?? 2011 Springer-Verlag.

  10. Early formation of evolved asteroidal crust. (United States)

    Day, James M D; Ash, Richard D; Liu, Yang; Bellucci, Jeremy J; Rumble, Douglas; McDonough, William F; Walker, Richard J; Taylor, Lawrence A


    Mechanisms for the formation of crust on planetary bodies remain poorly understood. It is generally accepted that Earth's andesitic continental crust is the product of plate tectonics, whereas the Moon acquired its feldspar-rich crust by way of plagioclase flotation in a magma ocean. Basaltic meteorites provide evidence that, like the terrestrial planets, some asteroids generated crust and underwent large-scale differentiation processes. Until now, however, no evolved felsic asteroidal crust has been sampled or observed. Here we report age and compositional data for the newly discovered, paired and differentiated meteorites Graves Nunatak (GRA) 06128 and GRA 06129. These meteorites are feldspar-rich, with andesite bulk compositions. Their age of 4.52 +/- 0.06 Gyr demonstrates formation early in Solar System history. The isotopic and elemental compositions, degree of metamorphic re-equilibration and sulphide-rich nature of the meteorites are most consistent with an origin as partial melts from a volatile-rich, oxidized asteroid. GRA 06128 and 06129 are the result of a newly recognized style of evolved crust formation, bearing witness to incomplete differentiation of their parent asteroid and to previously unrecognized diversity of early-formed materials in the Solar System.

  11. The off-crust origin of granite batholiths

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    Antonio Castro


    Full Text Available Granitod batholiths of I-type features (mostly granodiorites and tonalites, and particularly those forming the large plutonic associations of active continental margins and intracontinental collisional belts, represent the most outstanding magmatic episodes occurred in the continental crust. The origin of magmas, however, remains controversial. The application of principles from phase equilibria is crucial to understand the problem of granitoid magma generation. An adequate comparison between rock compositions and experimental liquids has been addressed by using a projected compositional space in the plane F(Fe + Mg–Anorthite–Orthoclase. Many calc-alkaline granitoid trends can be considered cotectic liquids. Assimilation of country rocks and other not-cotectic processes are identified in the projected diagram. The identification of cotectic patterns in batholith implies high temperatures of magma segregation and fractionation (or partial melting from an intermediate (andesitic source. The comparison of batholiths with lower crust granulites, in terms of major-element geochemistry, yields that both represent liquids and solid residues respectively from a common andesitic system. This is compatible with magmas being formed by melting, and eventual reaction with the peridotite mantle, of subducted mélanges that are finally relaminated as magmas to the lower crust. Thus, the off-crust generation of granitoids batholiths constitutes a new paradigm in which important geological implications can be satisfactorily explained. Geochemical features of Cordilleran-type batholiths are totally compatible with this new conception.

  12. Probe Drilling Ahead of Two TBMs in Difficult Ground Conditions in Turkey (United States)

    Bilgin, Nuh; Ates, Ugur


    This paper summarizes the results of probe drilling carried out ahead of TBMs in two difficult tunneling projects in Turkey. The tunnels have completely different geological characteristics which necessitated two different methods of data analysis. Melen Water Tunnel was excavated under Istanbul Bosphorus within sedimentary rocks which are cut frequently by andesitic dykes, fracturing the surrounding rocks and creating a potential risk for water ingress into the tunnel. At the beginning of Melen Project, pioneering probe drillings with petrographic analysis and strength tests were performed on samples collected from TBM muck. This analysis allowed identifying some critical normalized probe drilling rate values for predicting potential weak zones created by andesitic dykes. These studies gave a sound basis for further interpretation of TBM and geologic data for the same tunnel. The second set of probe drilling analysis was from Kargi Tunnel. The North Anatolian Fault highly affected the tunnel excavation by fractured rock formations. Although the change in normalized probe drilling data was a good indicator of fractured zones, the diversity of rock formations made it difficult to interpret the data.

  13. Analysis of fractures along a borehole axis at a geothermal well. Preliminary study for interpretation of 3D stress field using logging data. Chinetsusei ni okeru koseijiku ni sou fracture no kaiseki. Kenso data wo riyoshita 3 jigen oryokuba kaiseki no yobiteki hyoka

    Energy Technology Data Exchange (ETDEWEB)

    Okabe, T.; Shinohara, N.; Takasugi, S. (GERD Geothermal Energy Research and Development Co. Ltd., Tokyo (Japan)); Hayashi, K. (Tohoku University, Sendai (Japan). Institute of Fluid Science)


    Logging and analysis by BHTV and FMI were made in order to detect and evaluate the fracture before and after the hydraulic crushing of geothermal well. As a result of BHTV logging, the number of fractures detected increased before and after its hydraulic crushing. Though artificially generated, new open cracks were not confirmed at approximate depths of mud water leakage. That leakage which was generated by the hydraulic crushing was judged attributable to the opening of originally existing natural cracks. The FMI logging which electrically surveys the borehole wall can easily give information about the stratification planes. Many fractures were detected due to stratification planes which traveled west-northwestward with a southwestward dip of 20[degree] at the depth of 950 to 1100m. It was judged that some fractures leaking the mud water had largely depended upon the intrusive orientation of andesite and natural cracks during the hydraulic crushing, and lay on an intrusive boundary of andesite. The conclusion from the foregoing was that the evaluation of fracture, through logging by BHTV and FMI in advance, in the borehole is important for the hydraulic crushing. 3 refs., 7 figs.

  14. Stratigraphy and geochronology of the Comondú Group near Loreto, Baja California sur, Mexico (United States)

    Umhoefer, Paul J.; Dorsey, Rebecca J.; Willsey, Shawn; Mayer, Larry; Renne, Paul


    Upper Oligocene to Middle Miocene volcanic and sedimentary rocks in the Loreto region, Baja California Sur, are widely exposed and make up the Comondú Group as redefined here following McFall. The Comondú Group is part of a volcanic arc and forearc basin that formed along the northwestern margin of Mexico. Regional to detailed scale mapping, stratigraphic analysis, and geochronology in a 10-20-km-wide and 70-km-long belt from the gulf escarpment to the coast near Loreto reveal three main units in the Comondú Group and a composite thickness of ˜1.5-2 km. (1) The lower clastic unit (˜30-19 Ma) contains 200-300 m of fluvial sandstone and conglomerate with probable local eolian deposits and numerous felsic tuffs and basalt flows that accumulated in a forearc basin. (2) The middle breccia and lava flow unit (˜19-15 Ma) is up to 750 m thick and consists of massive andesite breccia that was deposited as proximal debris flows interbedded with minor andesite lava flows. (3) The upper lava flow and breccia unit (˜15-12 Ma) consists almost entirely of up to ˜600 meters of andesite lava flows a few kilometers west of Loreto that are part of a composite volcano. North and south of Loreto for up to 25 km, the unit is composed of andesite lava flows and massive andesite breccia that formed from thick debris flows near that and other volcanic centers. The three units of the Comondú Group in the Loreto area correlated with the Salto, Pelones, and Ricasón formations of the Bahı´a Concepción area. The lower clastic unit of this study is time equivalent to the marine San Gregorio, El Cien, and Isidro formations on the western and southern Baja California peninsula. The middle and upper units of the Loreto area are the proximal equivalent to the type section of the Comondú Group near the village of Comondú. During deposition of the lower part of the Comondú Group, the arc lay to the east on mainland Mexico in the Sierra Madre Occidental, and then migrated to the

  15. New U-Pb ages from dykes cross-cutting the Demirci metamorphics, NW Turkey: Implications for multiple orogenic events (United States)

    Sen, Fatih; Koral, Hayrettin; Peytcheva, Irena


    A high-grade metamorphic sequence in the Sünnice Mountains, Bolu, NW Turkey, is represented by migmatitic quartzo-feldspathic gneisses in amphibolite facies called the Demirci metamorphics/paragneisses, and a sequence of low-grade meta-volcanics containing meta-andesites with minor meta-rhyolites and meta-sedimentary rocks called the Yellice meta-volcanics. They are intruded by the Dirgine granite with an age of Upper Ediacaran (576-565 Ma) and are considered a part of the İstanbul-Zonguldak Tectonic Unit. The Demirci paragneisses are also intruded by a number of dykes in various directions, traditionally considered without radiometric dating to have been emplaced in a single magmatic phase in the Eocene related to post-collision regime of the Anatolide-Tauride platform. Mafic-intermediate-felsic dykes cross-cutting the Demirci paragneisses have been investigated in maps of 1/1000 scale, and their U-Pb zircon age, major-trace element and kinematic data have been obtained. The mafics dykes cross-cutting the Yellice meta-volcanics, equivalents of those in the Demirci paragneisses, occur in N400-500E orientations and have calc-alkaline basalt compositions with a subduction signature. The intermediate dykes occur in N650W, N800W orientations and have calc-alkaline basaltic andesite to andesitic compositions with a subduction signature. Some felsics occur in N150W and N800E orientations and have calc-alkaline dacitic compositions with a collisional tectonic setting. Other calc-alkaline granitic dykes occur in N750E orientation and calc-alkaline granitic compositions with a subduction signature. U-Pb LA-ICP-MS dating of zircons yield ages from 485.7±3.6 Ma (i.e. Cambro-Ordovician) for N800E trending dacite dykes; 443.0±5.4 Ma (i.e. Ordovician-Silurian) for N150W trending dacite dykes; 301.0±1.6 Ma (i.e. Upper Pennsylvanian-Carboniferous) for N650W trending basaltic andesite dykes; 268.2±2.4 Ma (i.e. Guadalupian-Permian) for N40-500E trending basalt dykes; 262.9±3

  16. Petrology, geochemistry and U-Pb geochronology of magmatic rocks from the high-sulfidation epithermal Au-Cu Chelopech deposit, Srednogorie zone, Bulgaria (United States)

    Chambefort, Isabelle; Moritz, Robert; von Quadt, Albrecht


    The Chelopech deposit is one of the largest European gold deposits and is located 60 km east of Sofia, within the northern part of the Panagyurishte mineral district. It lies within the Banat-Srednegorie metallogenic belt, which extends from Romania through Serbia to Bulgaria. The magmatic rocks define a typical calc-alkaline suite. The magmatic rocks surrounding the Chelopech deposit have been affected by propylitic, quartz-sericite, and advanced argillic alteration, but the igneous textures have been preserved. Alteration processes have resulted in leaching of Na2O, CaO, P2O5, and Sr and enrichment in K2O and Rb. Trace element variation diagrams are typical of subduction-related volcanism, with negative anomalies in high field strength elements (HFSE) and light element, lithophile elements. HFSE and rare earth elements were relatively immobile during the hydrothermal alteration related to ore formation. Based on immobile element classification diagrams, the magmatic rocks are andesitic to dacitic in compositions. Single zircon grains, from three different magmatic rocks spanning the time of the Chelopech magmatism, were dated by high-precision U-Pb geochronology. Zircons of an altered andesitic body, which has been thrust over the deposit, yield a concordant 206Pb/238U age of 92.21 ± 0.21 Ma. This age is interpreted as the crystallization age and the maximum age for magmatism at Chelopech. Zircon analyses of a dacitic dome-like body, which crops out to the north of the Chelopech deposit, give a mean 206Pb/238U age of 91.95 ± 0.28 Ma. Zircons of the andesitic hypabyssal body hosting the high-sulfidation mineralization and overprinted by hydrothermal alteration give a concordant 206Pb/238U age of 91.45 ± 0.15 Ma. This age is interpreted as the intrusion age of the andesite and as the maximum age of the Chelopech epithermal high-sulfidation deposit. 176Hf/177Hf isotope ratios of zircons from the Chelopech magmatic rocks, together with published data on the

  17. Suprasubduction volcanic rocks of the Char ophiolite belt, East Kazakhstan: new geochemical and first geochronological data (United States)

    Safonova, Inna; Simonov, Vladimir; Seltmann, Reimar; Yamamoto, Shinji; Xiao, Wenjiao


    The Char ophiolite belt is located in the western Central Asian Orogenic Belt, a world largest accretionary orogen, which has evolved during more than 800 Ma. The Char belt formed during Kazakhstan - Siberia collision. It has been known for hosting fragments of Late Devonian-Early Carboniferous oceanic crust, MORB, OPB and OIB, of the Paleo-Asian Ocean (Safonova et al., 2012). The Char is surrounded by two Paleozoic island-arc terranes: Zharma-Saur in the west and Rudny Altai in the east, however, until recent times, no island-arc units have been found within it. We were the first to find island-arc units as tectonic sheets occurring adjacent to those consisting of oceanic rocks. In places, island-arc andesites cut oceanic basalts. The Char volcanic and subvolcanic rocks of a probable suprasubduction origin are basalt, microgabbro, dolerite, andesite, tonalite and dacite. The mafic to andesitic volcanics possessing low TiO2 (0.85 wt.%av.) and show MgO vs. major elements crystallization trends suggesting two magma series: tholeiitic and calc-alkaline. The tholeiitic varieties are less enriched in incompatible elements then the calc-alkaline ones. Two samples are high-Mg and low-Ti andesibasalts similar to boninites. The rocks possess moderately LREE enriched rare-earth element patterns and are characterized by negative Nb anomalies present on the multi-element spectra (Nb/Lapm = 0.14-0.47; Nb/Thpm = 0.7-1.6).The distribution of rare-earth elements (La/Smn = 0.8-2.3, Gd/Ybn = 0.7-1.9) and the results of geochemical modeling in the Nb-Yb system suggest high degrees of melting of a depleted harzburgite-bearing mantle source at spinel facies depths. Fractional crystallization of clinopyroxene, plagioclase and opaque minerals also affected the final composition of the volcanic rocks. Clinopyroxene monomineral thermometry indicates crystallization of melts at 1020-1180°C. Melt inclusion composition based numerical calculations show that primary melts were derived at 1350

  18. Episodic growth of Mt. Shasta, CA, documented by argon geochronology (United States)

    Calvert, A. T.; Christiansen, R. L.


    Mt. Shasta is the largest stratovolcano along the high Cascade arc, surpassed in volume only by the rear-arc Medicine Lake and Newberry volcanoes. Currently >4300 m high and >350 km3 in volume, it grew episodically from overlapping vents and was partially destroyed by a major debris avalanche >300 ka. The area has been a long-lived eruptive focus; prior to 700 ka a similar-sized andesite stratocone sat 15-25 km E along the arc axis, but is now deeply eroded. Approximately 700 ka, the center moved ~20 km to its current location west of the arc axis. Good preservation and minor northward migration (3-5 km) of Mount Shasta's eruptive focus enables access to the older portions of the edifice. Lavas throughout Shasta's history have been dominantly intermediate in composition, typically having 60-64%wt. SiO2, though more mafic (basaltic andesite, 53-54%wt. SiO2) and more silicic (dacite, 64-69% wt. SiO2) lavas are also present. Most units erupted from central vents, but a N-S trend of domes and lava vents bisects the summit. No flank vents lie east of that N-S line, but they are numerous to the west. The oldest (~700-600 ka) Mt. Shasta eruptive focus is partly preserved on the SW flank up to 2,000 m elevation (Sand Flat) and as blocks in the massive (~45 km3) debris avalanche deposit in Shasta Valley. The avalanche is bracketed as younger than a 696 ± 3 ka included block and older than an overlapping 318 ± 29 ka lava. Several domes erupted 475-350 ka, but don't provide age constraints on the debris avalanche. Between 300 ka and 100 ka voluminous lavas issued from an eruptive focus (Sargents Ridge cone) ~2 km south of the present summit in at least six episodes spaced 10-30 kyr apart. The core of this eruptive focus has been removed by stream and glacial erosion in and above Mud Creek. High-Mg basaltic andesites erupted high on the S flank at 131 ka and low on the NW flank at 84 ka. No lavas have been identified as erupting from the summit area between 100-50 ka. The

  19. Augustine Volcano's late Pleistocene rhyolite eruption and its modern-day residuum (United States)

    Coombs, M. L.; Vazquez, J. A.


    The pre-Holocene eruptive history of Augustine Volcano, the most active volcano in the populated Cook Inlet region of Alaska, is poorly known due to the effects of glaciation and voluminous products of Holocene eruptions that cover the majority of this island volcano. Among its oldest known deposits, thought to be latest Pleistocene in age, are a basalt-rhyolite hyaloclastite, which is interbedded with an overlying pumiceous rhyolite tephra fall, that crop out on the south side of the island (Waitt and Beget, 2009). Dense and pumiceous rhyolite clasts from the deposits are compositionally similar (71-74 wt. % SiO2; Larsen et al., 2010) and contain phenocrysts of plagioclase, quartz, amphibole, and Fe-Ti oxides. These basalt-rhyolite deposits are the most compositionally extreme products of the volcano; Holocene eruptions, including historical eruptions in 1976, 1986, and 2006, produced andesites and dacites. In 2006, one such eruption produced gabbro inclusions (54.4-60.2 wt% SiO2) that consist of plagioclase, amphibole, pyroxenes, Fe-Ti oxides, and small amounts of interstitial glass, suggesting a cumulate origin. Both the Pleistocene-age rhyolite and the 2006 gabbro inclusions fall along a whole-rock compositional trend depleted in incompatible elements relative to mid-Holocene-present andesites and dacites. To investigate differentiation and the timing of rhyolite magma generation at Augustine, we have determined high-spatial resolution 238U-230Th ages of zircon crystallization for the rhyolite as well as for the gabbros and high-silica andesites erupted in 2006. Sensitive high-resolution ion microprobe (SHRIMP-RG) analyses of indium-mounted, unpolished zircon rims from the rhyolite yield a single 238U-230Th isochron age of ca. 27 ka, which we interpret to reflect the final interval of crystallization immediately prior to eruption. Sectioned core ages for rhyolite zircon, however, fall into two populations: one at ca. 27 ka, and a second, smaller population that

  20. A high-resolution 40Ar/39Ar lava chronology and edifice construction history for Ruapehu volcano, New Zealand (United States)

    Conway, Chris E.; Leonard, Graham S.; Townsend, Dougal B.; Calvert, Andrew T.; Wilson, Colin J. N.; Gamble, John A.; Eaves, Shaun R.


    Ruapehu is an active 150 km3 andesite-dacite composite volcano located at the southern end of the Taupo Volcanic Zone, New Zealand. The growth of the present-day edifice has occurred throughout coeval eruptive and glacial histories since 200 ka. We present high-precision 40Ar/39Ar eruption ages for 46 samples and whole-rock major element geochemical data for 238 samples from lava flows. These new and existing data are interpreted in the context of geomorphologic and geologic mapping, volcano-ice interaction processes and glacier reconstructions to present an improved chronostratigraphic framework and new edifice evolution history for Ruapehu. Sub-glacial to ice-marginal effusive eruption of medium-K basaltic-andesites and andesites constructed the northern portion of the exposed edifice between 200 and 150 ka, and a wide southeast planèze as well as parts of the northern, eastern and western flanks between 160 and 80 ka. None of the dated lava flows have ages in the range of 80-50 ka, which may reflect an eruptive hiatus. Alternatively the lack of ages may be the result of erosion and burial of lavas and syn-eruptive glacial conveyance of lava flows to the ring-plain during glacial advance at 70-60 ka. From 50-15 ka edifice growth occurred via effusive eruptions onto the glaciated flanks of the volcano, resulting in construction of ice-bounded planèzes and ridges. The distribution of dated ice-marginal lavas indicates a general decrease in glacier thicknesses over this time, except for a short-lived period centred at 31 ka when peak ice cover was reached. The compositional ranges of medium- to high-K andesite and dacite lava flows within 50-35 ka eruptive packages define broadly bimodal high- and low-MgO trends. Lavas erupted at 35-22 ka have compositions that fill a transitional geochemical field between older dacites and younger andesites. Large-scale retreat of flank glaciers since 15 ka has resulted in intra-valley lava flow emplacement at elevations below

  1. 新疆北天山沙湾地区晚石炭世火山岩地球化学特征及地质意义%Geochemical characteristics of Late Carboniferous volcanic rocks in northern Tianshan, Xinjiang, and their geological significance

    Institute of Scientific and Technical Information of China (English)

    刘飞; 杨经绥; 李天福; 陈松永; 徐向珍; 李金阳; 贾毅


    天山北部沙湾地区火山岩由火山碎屑岩和火山熔岩组成,主要包括安山质(岩屑)晶屑凝灰岩、英安质熔结凝灰岩、玄武安山岩和流纹岩,为钙碱性系列.玄武安山岩和流纹岩主量元素平均含量分别为:SiO2=51.03%、77.33%,TiO2=0.76%、0.16%,CaO=10.30%、0.43%,MgO=5.19%、0.89%,Na2O=2.10%、1.27%,K2O= 1.28%、2.54%;稀土元素特征分别为:∑REE=369.1 ×10-6、729.0× 10-6,(La/Yb)N=5.0、3.5,(La/Sm)N=2.7、2.4,δ Eu=0.82、0.54;Sr、Nd、Pb同位素特征分别为:(87Sr/86Sr)t=0.70680和0.70476,(143Nd/144Nd)t=0.52224和0.51225,ε Nd (t)=0.2和0.1,(206Pb/204Pb)t=17.775和17.720,(207Pb/204Pb)t=15.790和15.826,(28pb/204Pb)t=38.240和38.876.火山熔岩亏损Nb、Ta、Ti和P,富集K、Rb、U、Th、Zr和Hf,玄武安山岩的Zr为117×10-6~121×10-6,Zr/Y比值为5.63~5.82.流纹岩是玄武安山质岩浆结晶分异的产物,流纹岩LA-ICPMS锆石的U-Pb年龄为(310±2) Ma.本区火山岩原始岩浆产出于大陆板内拉张环境,是源自软流圈地幔的大陆玄武岩浆受到岩石圈地幔和大陆上、下地壳混染的结果.玄武安山岩中辉石斑晶的结晶温度和压力分别为1176.4C,4.13 kpa,相当于16.7 km的深度,反映了混染的大陆玄武岩浆在中、上地壳缓慢结晶形成单斜辉石斑晶后,因陆壳的拉张、快速上升至地表的过程.%Anjihai volcanic rocks in northern Tianshan are composed of pyroclastic rocks and lavas, which include andesite crystal tuff, andesite detritus crystal tuff, dacite welded tuff, basaltic andesite and rhyolite, thus being of calc- alkaline series. Major and rare earth element compositions of basaltic andesite and rhyolite are as follows; SiO2=51.03%,77.33%, TiO2=0.76%,0.16%, CaO=10.30%,0.43%, MgO=5.19%,0.89%, Na2O=2.10%,1.27%, K2O= 1.28%,2.54%,∑REE=369.1ppm,729.0ppm, (La/Yb)N=5.0,3.5, (La/Sm)N=2.7,2.4 and 5 Eu =0.82,0.54. The primitive mantle normalized spider

  2. Petrography, geochemistry and tectonic setting of Salmabad Tertiary volcanic rocks, southeast of Sarbisheh, eastern Iran

    Directory of Open Access Journals (Sweden)

    Masoumeh Goodarzi


    Full Text Available Introduction The area reviewed and studied in this paper is located 5 km southeast of Sarbisheh city at eastern border of the Lut block (Jung et al., 1983; Karimpour et al., 2011; Richards et al., 2012 in eastern Iran between 59° 47′ and 59° 53′ E longitude and 32°30′ and 32°34′ N latitude. The magmatic activity in the Lut block began in middle Jurassic (165-162 Ma and reached its peak in Tertiary (Jung et al., 1983. Volcanic and subvolcanic rocks of Tertiary age cover over half of Lut block with up to 2000 m thickness and formed due to subduction prior to the collision of the Arabian and Asian plates (Camp and Griffis, 1982; Tirrul et al., 1983; Berberianet et al., 1982. Most of magmatic activity in the Lut block formed in middle Eocene (Karimpour et al., 2011 The andesitic volcanics were erupted together with the dacites and rhyodacites during a time interval of some 50 Ma from early Cretaceous to early Neogene. It can be assumed that the intensity of the volcanic activity was varying significantly during this time span (Jung et al., 1983.Tertiary volcanic rocks (Eocene-Oligocene to Pliocene with intermediate composition associated with pyroclastic rocks cropped out in eastern parts of Salmabad village, southeast of Sarbisheh. The main purpose of this paper is better understand the tectono-magmatic setting of the Tertiary volcanic rocks in southeast of Sarbisheh, eastern Iran based on geochemical characteristics. Materials and methods Eleven samples were analyzed for major elements by inductively coupled plasma (ICP technologies and trace elements were analyzed using inductively coupled plasma mass spectrometry (ICP-MS, following a lithium metaborate/tetraborate fusion and nitric acid total digestion, at the SGS Laboratories, Toronto, Canada. Results In the Salmabad area, Tertiary volcanic rocks with mainly intermediate (andesitic composition are exposed associated with pyroclastic deposits such as tuff, breccia and agglomerate

  3. The role of petrology in defining volcanic hazards and designing monitoring systems (United States)

    Smith, I. E.; Turner, M. B.; Price, R. C.; Cronin, S. J.


    Petrology is the study of magmatic systems; physical volcanology investigates processes of eruption. Physical volcanology provides the pre-eminent underpinning of the practical business of defining hazard scenarios, planning mitigation and designing monitoring strategies. Recent research in a variety of volcanic settings has demonstrated an important link between the petrologic processes that at a fundamental level drive the behavior of volcanoes and the processes that determine the eruptive style of a volcano. Together these define the hazards that arise from volcanic eruptions. Petrological studies of volcanoes are typically based on a study of lava because coherent rock is less vulnerable to weathering and alteration and is more durable in the geological record. Pyroclastic materials are commonly friable and glassy, are more easily eroded, and are more difficult to use in the analytical techniques that have become the staple basis of petrological studies. However, pyroclastic materials represent a complementary but different part of the magmatic story and it is only by integrating both effusive and explosive components of an eruption sequence that a complete picture of the behavior of the system feeding a volcano can be gained. Andesitic strato-cones are made up of a cone-building facies consisting mainly of primary magmatic products and usually dominated by lava flows because pyroclastic material is easily eroded from the slopes of a steep cone. The surrounding ring plain facies includes primary pyroclastic deposits but is typically dominated by redistributed material in the form of debris flow and lahar deposits together with reworked fluvial material. The deposits of each of these two facies are assembled on different time scales and they contain different aspects of the record of the evolution of the magmatic system that gave rise to them. An important practical consequence of this is that different parts of the geochemical record of the system can occur in

  4. Geologic Map of Lassen Volcanic National Park and Vicinity, California (United States)

    Clynne, Michael A.; Muffler, L.J. Patrick


    The geologic map of Lassen Volcanic National Park (LVNP) and vicinity encompasses 1,905 km2 at the south end of the Cascade Range in Shasta, Lassen, Tehama, and Plumas Counties, northeastern California (fig. 1, sheet 3). The park includes 430 km2 of scenic volcanic features, glacially sculpted terrain, and the most spectacular array of thermal features in the Cascade Range. Interest in preserving the scenic wonders of the Lassen area as a national park arose in the early 1900s to protect it from commercial development and led to the establishment in 1907 of two small national monuments centered on Lassen Peak and Cinder Cone. The eruptions of Lassen Peak in 1914-15 were the first in the Cascade Range since widespread settling of the West in the late 1800s. Through the printed media, the eruptions aroused considerable public interest and inspired renewed efforts, which had languished since 1907, to establish a national park. In 1916, Lassen Volcanic National Park was established by combining the areas of the previously established national monuments and adjacent lands. The southernmost Cascade Range is bounded on the west by the Sacramento Valley and the Klamath Mountains, on the south by the Sierra Nevada, and on the east by the Basin and Range geologic provinces. Most of the map area is underlain by middle to late Pleistocene volcanic rocks; Holocene, early Pleistocene, and late Pliocene volcanic rocks (radiometric dating, photographs of geologic features, and links to related data or web sites. Data contained in the CD-ROM are also available on this Web site. The southernmost Cascade Range consists of a regional platform of basalt and basaltic andesite, with subordinate andesite and sparse dacite. Nested within these regional rocks are 'volcanic centers', defined as large, long-lived, composite, calc-alkaline edifices erupting the full range of compositions from basalt to rhyolite, but dominated by andesite and dacite. Volcanic centers are produced by the

  5. Rock size distributions on lava flow surfaces: New results from a range of compositions (United States)

    Burke, M. P.; Anderson, S. W.; Bulmer, M. H.


    We measured block sizes along 15-25m orthogonal transects on 12 lava flows of compositions ranging from basalt to rhyolite. At each site, we stretched a line across the flow surface then measured the length of each block cut by this line that were greater than 3-12cm (depending on composition). The measurements from each site were reduced to cumulative size frequency distribution plots, with block size (D) plotted against the fraction of the line f(D) composed of blocks greater than or equal to that size, and fitted with an exponential curve of the form f(D) = k exp(-qD) where k is the intercept and q is the decay parameter. Average block size and geometric mean were also determined for each site. Our data show no clear trends linking average or mean block size to composition, although there does seem to be relationship between block size and the decay parameter. Block size corresponds with the decay parameter at each site except for the basaltic andesite flow at Paint Pot Crater (CA). Many sites at this flow were covered with secondary spatter deposits. Largest blocks and smallest decay parameters were found for the andesite flows at Sabancaya (Peru), while the basalt flows at Cima (CA) exhibited the smallest blocks and largest decay parameters. The second largest block sizes occurred at the four Inyo domes composed of both crystal-rich and glassy rhyolite, and these domes also showed the second smallest decay parameters. All four of the Inyo domes were emplaced along the same feeder dike trend, and the average and mean sizes and decay parameters at these domes are nearly identical, suggesting that composition, extrusion rate, or eruption history controls the block size distributions. However, values for the two andesitic flows, Mt. Shasta (CA) and Sabancaya, were very different, suggesting that extrusion rate and/or eruption history exert a stronger control over the block size distributions than does composition. LIDAR data sets are capable of detecting sub

  6. Probing permeability and microstructure: Unravelling the role of a low-permeability dome on the explosivity of Merapi (Indonesia) (United States)

    Kushnir, Alexandra R. L.; Martel, Caroline; Bourdier, Jean-Louis; Heap, Michael J.; Reuschlé, Thierry; Erdmann, Saskia; Komorowski, Jean-Christophe; Cholik, Noer


    Low permeability dome rocks may contribute to conduit overpressure development in volcanic systems, indirectly abetting explosive activity. The permeability of dome-forming rocks is primarily controlled by the volume, type (vesicles and/or microcracks), and connectivity of the void space present. Here we investigate the permeability-porosity relationship of dome-forming rocks and pumice clasts from Merapi's 1888 to 2013 eruptions and assess their possible role in eruptive processes, with particular emphasis on the 2010 paroxysmal eruption. Rocks are divided into three simple field classifications common to all eruptions: Type 1 samples have low bulk density and are pumiceous in texture; Type 2 samples, ubiquitous to the 2010 eruption, are dark grey to black in hand sample and vary greatly in vesicularity; and Type 3 samples are weakly vesicular, light grey in hand sample, and are the only samples that contain cristobalite. Type 2 and Type 3 rocks are present in all eruptions and their permeability and porosity data define similar power law relationships, whereas data for Type 1 samples are clearly discontinuous from these trends. A compilation of permeability and porosity data for andesites and basaltic andesites with published values highlights two microstructural transitions that exert control on permeability, confirmed by modified Bayesian Information Criterion (BIC) analysis. Permeability is microcrack- and diktytaxitic-controlled at connected porosities, φc, 31 vol.%. Type 3 basaltic andesites, the least permeable of the measured samples and therefore the most likely to have originated in the uppermost low-permeability dome, are identified as relicts of terminal domes (the last dome extruded prior to quiescence). Cristobalite commonly found in the voids of Type 3 blocks may not contribute significantly to the reduction of the permeability of these samples, mainly because it is associated with an extensive microporous, diktytaxitic texture. Indeed, the low

  7. Complex variations during a caldera-forming Plinian eruption, including precursor deposits, thick pumice fallout, co-ignimbrite breccias and climactic lag breccias: The 184 ka Lower Pumice 1 eruption sequence, Santorini, Greece (United States)

    Simmons, J. M.; Cas, R. A. F.; Druitt, T. H.; Folkes, C. B.


    The 184 ka Lower Pumice 1 eruption sequence records a complex history of eruption behaviours denoted by two significant eruptive phases: (1) a minor precursor (LP1-Pc) and (2) a major Plinian phase (LP1-A, B, C). The precursor phase produced 13 small-volume pyroclastic fallout, surge and flow deposits, which record the transition from a dominantly magmatic to a phreatomagmatic eruptive style, and exhibit a normal (dacite to andesitic-dacite) to reverse (andesitic-dacite to dacite) compositional zonation of juvenile pyroclasts in the stratigraphy. Incipient bioturbation and variability in unit thickness and lithology reflect multiple time breaks and highlight the episodic nature of volcanism prior to the main Plinian eruption phase. The Plinian magmatic eruption phase is defined by three major stratigraphic divisions, including a basal pumice fallout deposit (LP1-A), an overlying valley-confined ignimbrite (LP1-B) and a compositionally zoned (rhyodacite to basaltic andesite) lithic-rich lag breccia (LP1-C), which caps the sequence. This sequence records the initial development of a buoyant convective eruption column and the transition to eruption column and catastrophic late-stage caldera collapse events. Similarities in pyroclast properties (i.e., chemistry, density), between the Plinian fallout (LP1-A) and pyroclastic flow (LP1-B) deposits, indicate that changes in magma properties exerted no influence on the dynamics and temporal evolution of the LP1 eruption. Conversely, lithic breccias at the base of the LP1-B ignimbrite suggest that the transition from a buoyant convective column to column collapse was facilitated by mechanical erosion of the conduit system and/or the initiation of caldera collapse, leading to vent widening, an increase in magma discharge rate and the increased incorporation of lithics into the eruption column, causing mass overload. Lithic-rich lag breccia deposits (LP1-C), which cap the eruption sequence, record incremental, high

  8. Volatile Evolution and Anhydrite-Bearing Dacite, Yanacocha Gold Deposit, Cajamarca, Peru: Relevance for the Sulfur Budget (United States)

    Chambefort, I. S.; Dilles, J. H.


    Magmatic water, sulfur and chlorine evolved during volcanic eruptions have important climactic effects, but during passive degassing these volatiles may transport metals and produce hydrothermal ore deposits. At the Yanacocha Mine, we are examining the volatile evolution of the Miocene andesitic to dacitic volcanic rocks (ca 20 to 8 Ma). High sulfidation epithermal deposits contain >50 Moz of gold in oxides with additional deeper sulfide resources containing >5 Mt of copper. Large volumes (>10 km3) of rock are hydrothermally altered by sulfate-rich and low pH fluid to quartz, quartz-alunite, quartz-pyrophyllite, illite. Pyrite (1-5 vol.%), native sulfur, covellite, enargite and chalcopyrite constitute reduced S-species. In total, at least 500 M tonnes of sulfur were added during alteration. The San Jose ignimbrite (SJI) erupted 30 km3 magma in two cooling units at 11.50 and 11.28 Ma, and immediately predates the bulk of gold mineralization at about 10.80 Ma (Longo, 2005). This hornblende- plagioclase dacitic magma is highly oxidized with fO2 ≍ 2 NNO. Low-Al2O3 (~7 wt.%), and high- Al2O3 (~12 wt.%) amphiboles coexist in most of the samples. Plag-hbl thermobarometry on low-Al content amphibole yields ca. 1.5-2 kb and 800°C. High-Al pargasitic hornblende forms sparse crystals up to 1 cm long that often show resorption or oxide rims associated with oxyhornblende breakdown. Apatite is an inclusion but generally not plagioclase or oxide. These petrographic relations suggest that the high-Al hornblende is the liquidus phase (at 950 to 1000°C, PH2O > 3 kb) in an andesitic or basaltic magma. The high-Al amphibole in two samples contains anhydrite inclusions, one with >5 vol.% anhydrite associated with apatite having up to 1.2 wt.% SO3. Comparison of these data with experimental sulfate solubilities at NNO+2 suggests the andesitic or basaltic melt dissolved at least 1000 ppm S. One low-Al amphibole contains anhydrite, demonstrating that the cooler dacite magma was also

  9. Petrogenesis of Late Cretaceous lava flows from a Ceno-Tethyan island arc: The Raskoh arc, Balochistan, Pakistan (United States)

    Siddiqui, Rehanul Haq; Qasim Jan, M.; Asif Khan, M.


    The Raskoh arc is about 250 km long, 40 km wide and trends in an ENE direction. The oldest rock unit in the Raskoh arc is an accretionary complex (Early to Late Jurassic), which is followed in age by Kuchakki Volcanic Group, the most wide spread unit of the Raskoh arc. The Volcanic Group is mainly composed of basaltic to andesitic lava flows and volcaniclastics, including agglomerate, volcanic conglomerate, breccia and tuff, with subordinate shale, sandstone, limestone and chert. The flows generally form 3-15 m thick lenticular bodies but rarely reach up to 300 m. They are mainly basaltic-andesites with minor basalts and andesites. The main textures exhibited by these rocks are hypocrystalline porphyritic, subcumulophyric and intergranular. The phenocrysts comprise mainly plagioclase (An30-54 in Nok Chah and An56-64 in Bunap). They are embedded in a micro-cryptocrystalline groundmass having the same minerals. Apatite, magnetite, titanomagnetite and hematite occur as accessory minerals. Major, trace and rare earth elements suggest that the volcanics are oceanic island arc tholeiites. Their low Mg # (42-56) and higher FeO (total)/MgO (1.24-2.67) ratios indicate that the parent magma of these rocks was not directly derived from a mantle source but fractionated in an upper level magma chamber. The trace element patterns show enrichment in LILE and depletion in HFSE relative to N-MORB. Their primordial mantle-normalized trace element patterns show marked negative Nb anomalies with positive spikes on K, Ba and Sr which confirm their island arc signatures. Slightly depleted LREE to flat chondrite normalized REE patterns further support this interpretation. The Zr versus Zr/Y and Cr versus Y studies show that their parent magma was generated by 20-30% melting of a depleted mantle source. The trace elements ratios including Zr/Y (1.73-3.10), Ti/Zr (81.59-101.83), Ti/V (12.39-30.34), La/YbN (0.74-2.69), Ta/Yb (0.02-0.05) and Th/Yb (0.11-0.75) of the volcanics are more

  10. From rock to magma and back again: The evolution of temperature and deformation mechanism in conduit margin zones (United States)

    Heap, Michael J.; Violay, Marie; Wadsworth, Fabian B.; Vasseur, Jérémie


    Explosive silicic volcanism is driven by gas overpressure in systems that are inefficient at outgassing. The zone at the margin of a volcanic conduit-thought to play an important role in the outgassing of magma and therefore pore pressure changes and explosivity-is the boundary through which heat is exchanged from the hot magma to the colder country rock. Using a simple heat transfer model, we first show that the isotherm for the glass transition temperature (whereat the glass within the groundmass transitions from a glass to an undercooled liquid) moves into the country rock when the magma within the conduit can stay hot, or into the conduit when the magma is quasi-stagnant and cools (on the centimetric scale over days to months). We then explore the influence of a migrating viscous boundary on compactive deformation micromechanisms in the conduit margin zone using high-pressure (effective pressure of 40 MPa), high-temperature (up to 800 °C) triaxial deformation experiments on porous andesite. Our experiments show that the micromechanism facilitating compaction in andesite is localised cataclastic pore collapse at all temperatures below the glass transition of the amorphous groundmass glass Tg (i.e., rock). In this regime, porosity is only reduced within the bands of crushed pores; the porosity outside the bands remains unchanged. Further, the strength of andesite is a positive function of temperature below the threshold Tg due to thermal expansion driven microcrack closure. The micromechanism driving compaction above Tg (i.e., magma) is the distributed viscous flow of the melt phase. In this regime, porosity loss is distributed and is accommodated by the widespread flattening and closure of pores. We find that viscous flow is much more efficient at reducing porosity than cataclastic pore collapse, and that it requires stresses much lower than those required to form bands of crushed pores. Our study therefore highlights that temperature excursions can result in a

  11. Vulnerability of Karangkates dams area by means of zero crossing analysis of data magnetic

    Energy Technology Data Exchange (ETDEWEB)

    Sunaryo,, E-mail:, E-mail:; Susilo, Adi [Geophysics Program Study, Physics Dept., Sciences Faculty, University of Brawijaya, Malang (Indonesia)


    Study with entitled Vulnerability Karangkates Dam Area By Means of Zero Crossing Analysis of Data Magnetic has been done. The study was aimed to obtain information on the vulnerability of two parts area of Karangkates dams, i.e. Lahor dam which was inaugurated in 1977 and Sutami dam inaugurated in 1981. Three important things reasons for this study are: 1). The dam age was 36 years old for Lahor dam and 32 years old for Sutami dam, 2). Geologically, the location of the dams are closed together to the Pohgajih local shear fault, Selorejo local fault, and Selorejo limestone-andesite rocks contact plane, and 3). Karangkates dams is one of the important Hydro Power Plant PLTA with the generating power of about 400 million KWH per year from a total of about 29.373MW installed in Indonesia. Geographically, the magnetic data acquisition was conducted at coordinates (112.4149oE;-8.2028oS) to (112.4839oE;-8.0989oS) by using Proton Precession Magnetometer G-856. Magnetic Data acquisition was conducted in the radial direction from the dams with diameter of about 10 km and the distance between the measurements about 500m. The magnetic data acquisition obtained the distribution of total magnetic field value in the range of 45800 nT to 44450 nT. Residual anomalies obtained by doing some corrections, including diurnal correction, International Geomagnetic Reference Field (IGRF) correction, and reductions so carried out the distribution of the total magnetic field value in the range of -650 nT to 700 nT. Based on the residual anomalies, indicate the presence of 2 zones of closed closures dipole pairs at located in the west of the Sutami dam and the northwest of the Lahor dam from 5 total zones. Overlapping on the local geological map indicated the lineament of zero crossing patterns in the contour of residual anomaly contour with the Pohgajih shear fault where located at about 4 km to the west of the Sutami dam approximately and andesite-limestone rocks contact where located

  12. Complejo Caldera Diamante-volcán Maipo (34°10'S, 69º50'O: Evolución volcanológica y geoquímica e implicancias en su peligrosidad Volcanological and geochemical evolution and hazard assessment of the Diamante Caldera-Maipo Volcano Complex (34°10'S, 69º50'W

    Directory of Open Access Journals (Sweden)

    Patricia Sruoga


    Full Text Available El Complejo Caldera Diamante-Volcán Maipo (34°10' S, 69º50' O se halla situado en el extremo norte de la Zona Volcánica Sur. Su actividad se remonta a 450/150 ka, posee un registro histórico incierto y carece de manifestaciones fumarólicas o hidrotermales. Su evolución abarca dos etapas: 1 Diamante, con la formación de una caldera de colapso (20x16 km y el emplazamiento de ignimbritas de gran volumen y 2 Maipo, con la construcción de un estratovolcán, domo anular y conos adventicios asociados. Esta etapa comprende siete eventos eruptivos principales (cuatro preglaciales: 86 ± 10 ka / 88 ± 7 ka, 75 ± 16 ka, 45 ± 14 ka y 28 ± 17 ka y tres postglaciales: The Caldera Diamante-Maipo volcanic complex (34°10' S, 69º50' W is located at the northern end of the South Volcanic Zone. The eruptive activity started 450/150 ka ago and its historic record remains uncertain. At present, neither fumarolic activity nor hydrothermal manifestations are detected. Two main stages are distinguished in the evolution of the volcanic complex: 1 "Diamante stage" corresponds to the emplacement of large-volume ignimbrites associated to a 20 by 16 km in diameter collapse caldera and 2 the "Maipo stage" represents andesite-dacite stratocone-building lavas and pyroclastics, a ring-fault dome and parasitic cones emplaced during the last 100 ka of the complex lifetime (4 pre-glacial events: 86 ± 10 ka / 88 ± 7 ka, 75 ± 16 ka, 45 ± 14 ka, 28 ± 17 ka and 3 post-glacial events <14 ka. Scoria flows and fall deposits near the summit are assigned to the recent explosive record. The last eruption tentatively occurred in 1912. The volcanics define a high-K, calc-alkaline suite ranging in silica from 54% to 74%. The Maipo series encompasses two pyroxene with minor olivine andesites and two pyroxene and hornblende dacites. Magmatic differentiation is strongly controlled by fractional crystallization. However, periodic magma mixing and crustal assimilation should have

  13. Did the massive magnetite "lava flows" of El Laco (Chile) form by magmatic or hydrothermal processes? New constraints from magnetite composition by LA-ICP-MS (United States)

    Dare, Sarah A. S.; Barnes, Sarah-Jane; Beaudoin, Georges


    The El Laco magnetite deposits consist of more than 98 % magnetite but show field textures remarkably similar to mafic lava flows. Therefore, it has long been suggested that they represent a rare example of an effusive Fe oxide liquid. Field and petrographic evidence, however, suggest that the magnetite deposits represent replacement of andesite flows and that the textures are pseudomorphs. We determined the trace element content of magnetite by laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) from various settings at El Laco and compared them with magnetite from both igneous and hydrothermal environments. This new technique allows us to place constraints on the conditions under which magnetite in these supposed magnetite "lava flows" formed. The trace element content of magnetite from the massive magnetite samples is different to any known magmatic magnetite, including primary magnetite phenocrysts from the unaltered andesite host rocks at El Laco. Instead, the El Laco magnetite is most similar in composition to hydrothermal magnetite from high-temperature environments (>500 °C), such as iron oxide-copper-gold (IOCG) and porphyry-Cu deposits. The magnetite trace elements from massive magnetite are characterised by (1) depletion in elements considered relatively immobile in hydrothermal fluids (e.g. Ti, Al, Cr, Zr, Hf and Sc); (2) enrichment in elements that are highly incompatible with magmatic magnetite (rare earth elements (REE), Si, Ca, Na and P) and normally present in very low abundance in magmatic magnetite; (3) high Ni/Cr ratios which are typical of magnetite from hydrothermal environments; and (4) oscillatory zoning of Si, Ca, Mg, REE and most high field strength elements, and zoning truncations indicating dissolution, similar to that formed in hydrothermal Fe skarn deposits. In addition, secondary magnetite in altered, brecciated host rock, forming disseminations and veins, has the same composition as magnetite from the massive

  14. Waduk Parangjoho dan Songputri: Alternatif Sumber Erupsi Formasi Semilir di daerah Eromoko, Kabupaten Wonogiri, Jawa Tengah

    Directory of Open Access Journals (Sweden)

    Sutikno Bronto


    Full Text Available Semilir Formation was typically originated from products of a very explosive volcanic activity, i.e. breccias, lapillistones, and tuffs containing abundant pumice. It has a light grey to white colour and high silica andesite to dacite in composition, mainly rich in volcanic glass and quartz. Sedimentary structures of these volcanic rocks are massive, grading, planar bedding, and cross-bedding to antidunes, with grain size varies from ash (≤ 2 mm to lapilli (2 – 64 mm to bomb and block (> 64 mm. The formation is widely distributed from the west side (Pleret and Piyungan areas, Bantul Regency, Special Province of Yogyakarta until Eromoko area in the east (Wonogiri Regency, Jawa Tengah Province. Stratigraphically, the Semilir Formation underlies the Nglanggeran Formation, and overlies the Mandalika Formation in the eastern part and Kebo-Butak Formation in the western part. Geomorphological- and lithological analyses of the Semilir Formation in areas of Parangjoho and Song- putri Dams, Eromoko Sub-regency, Wonogiri Regency indicate that the two depressions were alternatively volcanic sources of the Semilir Formation in the Eromoko area. This is proved by the presence of co-ignimbrite breccias(co-ignimbrite lag fall deposits, that descriptively they are polymict breccias. This rock is characterized by a mixing of pumice and various hard rock fragments that primarily are juvenile materials (volcanic blocks, bombs, accessory-, and accidental rock fragments set in pumice-rich volcanic ash and lapilli sizes. The accessory materials came from older volcanic rocks, whereas the accidental ones were originated from basement rocks. During a caldera forming event or a destruction period of an older composite volcanic cone(s, all older rocks resting above the magma chamber were ejected to the surface by a very high magmatic pressure. Since they were heavier than the juvenile material, most accessory and

  15. Northernmost Known Outcrop in North America of Lower Cretaceous Porphyritic Ocoite Facies (Ocoa, Chile) at Western Mexico: the Talpa Ocoite (United States)

    Zárate-del Valle, P. F.; Demant, A.


    At Talpa de Allende region in Western Mexico is located the northernmost known outcrop of ocoite facies (andesite): the Talpa ocoite (TO). The ocoite facies consists of an calk-alkaline andesitic rock rich in K and characterized by the presence of megacrysts of plagioclase (An48-65). TO belongs to the so-called Guerrero Terrane composed of plutono-volcanic and volcano-sedimentary sequences of the Alisitos-Teloloapan arc that was accreted to the North American craton at the end of the early Cretaceous (Lapierre et al., 1992, Can. J. Earth Sci. 29. 2478--2489). Geodynamically TO belongs to lithological sequence number IV or "Tecoman" of Tardy et al. (1994, Tectonophysics 230, 49--73). TO in hand-sample shows typical megacrysts (>1 cm) of plagioclase and clinopyroxene in a dark green aphanitic matrix. This andesitic lava has a shoshonitic character as evidenced by chemical composition: SiO_2 TiO_2 Al_2O_3 Fe_2O_3 MnO MgO CaO Na_2O K_2O P_2O_5 LOI % Ba Sr (ppm) 55.64 0.73 16.61 8.39 0.13 3.59 6.40 3.55 2.85 0.36 1.84% 1093 880 Under microscope TO is characterized by a porphyritic texture made of large labradorite phenocrysts (up to 3 cm) and clinopyroxene with a matrix made of plagioclase microlites; TO has been affected by a low grade metamorphism process belonging to the prehnite-pumpellite facies as it happens in Chile (Levi, 1969, Contr. Mineral. and Petrol. 24-1, p. 30--49). Electron microprobe analysis shows that plagioclase (An55-57) is partly transformed into albite (An7-9); clinopyroxene shows a variation in composition from Wo33En41Fs17 to Wo40En44Fs24 and it is transformed towards the margin first into amphibole and then into biotite. TO outcrops located at East of Talpa river are affected by a deep rubefaction process. TO is not characterized by the presence of bitumen as it occurs in Northern Chile (Nova-Muñoz et al., 2001, EUG XI Meeting, OS09 Supo09 PO, 606); TO is related in time with albian-cenomanian volcanogenic massive sulphides of Western Mexico

  16. Petrogenesis of the Miocene volcanism along the İzmir-Balıkesir Transfer Zone in western Anatolia, Turkey: Implications for origin and evolution of potassic volcanism in post-collisional areas (United States)

    Ersoy, Yalçın E.; Helvacı, Cahit; Uysal, İbrahim; Karaoğlu, Özgür; Palmer, Martin R.; Dindi, Fulya


    The Miocene volcanic rocks along the İzmir-Balıkesir Transfer Zone along the western margin of the Menderes Core Complex (MCC) in western Anatolian Volcanic Province (WAVP), where strike-slip deformation is dominant, comprise: (Group 1) early-middle Miocene high-K to shoshonitic rocks with high-Mg# and relatively low SiO2, (Group 2) middle Miocene phonolitic rocks with low-Mg# and intermediate SiO2, (Group 3) early-middle Miocene medium- to high-K series from andesites to rhyolites, (Group 4) middle Miocene rhyolites with distinct trace element compositions; and (Group 5) late Miocene high-MgO basalts, K-trachybasalts and (Group 6) late Miocene high-MgO basaltic andesites. The geochemical features of these rocks are comparable with the other Oligocene to Miocene volcanic rocks, but differ from the Eocene volcanic rocks in WAVP. The geochemical features of the most primitive early-middle Miocene Group 1 rocks indicate that they were derived from an anomalously metasomatized lithospheric mantle. The mineralogical and geochemical properties of garnet-amphibole peridotite from the Ulten Zone (UZP), Eastern Alps, which is thought to represent a fossil metasomatic mantle wedge contaminated by continental subduction, is similar to the model mantle composition previously proposed for the genesis of the mafic rocks. Together with the presence of Eocene to early Miocene continental subduction beneath the Aegean-west Anatolia region, this strongly suggests that continental subduction was an important factor in the genesis of the high-MgO shoshonitic to ultrapotassic volcanism in this post-collisional area. The origin of the Group 3 andesitic to rhyolitic rocks includes; (1) lower crustal melting, (2) mixing between lower crustally-derived and mantle-derived melts, and (3) FC-AFC processes. The late Miocene Group 5 and 6 rocks, however, derived from a more depleted mantle source, indicating that the mantle became depleted over time. The rhyolites of Group 4 are most probably

  17. 31+/-17 ka 40Ar/39Ar Plateau Age on the Very Low-Potassium Hat Creek Basalt Fits Stratigraphic and Geochronologic Constraints of Contiguous Units (United States)

    Clynne, M. A.; Turrin, B. D.; Champion, D. E.; Muffler, L. P.


    The Hat Creek Basalt is a late Pleistocene low-K olivine tholeiite that floors much of the Hat Creek Valley, north of the Lassen volcanic highland in NE California. The flow erupted from a fissure trending N 10° W located 0.5 to 4.0 km SSE of Old Station and flowed north nearly 30 km, mainly through lava tubes. Paleomagnetic data indicate that the Hat Creek Basalt is a single eruptive unit with an inclination of 64.3° and a declination of 1.0° . The Hat Creek Basalt is overlain by gravel related to the last major glaciation, which ended about 15 to 17 ky ago. The Hat Creek Basalt overlies numerous andesite and basaltic andesite lava flows that are closely related geographically, stratigraphically, petrographically and geochemically and probably represent the same eruptive episode (although not necessarily the same year or century). Three of these flows have been dated by the 40Ar/39Ar method and yield concordant plateau, integrated (total fusion), and isochron ages: Little Potato Butte (1.42% K2O; 67+/-4 ka), Sugarloaf (1.85% K2O; 55+/-7 ka), and Big Potato Butte (1.62% K2O; 73+/-14 ka). The Hat Creek Basalt also overlies the basaltic andesite of Cinder Butte (1.65% K2O) with a 40Ar/39Ar plateau age of 38+/-7 ka. Given that the age of the Hat Creek Basalt is thus firmly bracketed between ˜15 ka and 38+/-7 ka, we attempted to date this low-potassium tholeiitic basalt directly. One sample produced 40Ar/39Ar data that cannot be interpreted, but a second sample (0.17% K2O) yielded concordant plateau, integrated (total fusion), and isochron ages of 31+/-17 ka, 30+/-20 ka, and 24+/-6 ka; within the time bracket determined by stratigraphic relations. These data indicate that samples of latest Pleistocene tholeiitic basalt with very low K2O can give useful 40Ar/39Ar ages. As with all isotopically determined ages, the confidence of the results are significantly enhanced when additional constraints imposed by other isotopic ages within a stratigraphic context are taken

  18. Characterizing Lava Flows With LiDAR (United States)

    Deligne, N. I.; Cashman, K. V.; Deardorff, N.; Dietterich, H. R.; House, P. K.; Soule, S.


    Digital elevation models (DEMs) have been used in volcanology in predictive modeling of lava flow paths, both for assessment of potential hazards and specific predictions of lava flow paths. Topographic analysis of a lava flow is potentially useful for mapping and quantifying flow surface morphologies, which in turn can be used to determine flow emplacement conditions, such as effusion rate, steadiness of flow, and interactions with pre-existing topography and surface water. However, this has been limited in application because of the coarse resolution of most DEMs. In recent years, use of Light Detection and Ranging (LiDAR) airborne laser altimetry, capable of producing high resolution (≤ 1 meter) DEMs, has become increasingly common in the geomorphic and mapping community. However, volcanologists have made little use of airborne LiDAR. Here we compare information obtained using field observations and standard (10 meter) DEMs against LiDAR high resolution DEMs to assess the usefulness, capabilities, and limitations of LiDAR as applicable to lava flows. We compare morphologic characteristics of five lava flows of different compositions, tectonic settings, flow extents, slopes, and eruption duration: (1) 1984 Mauna Loa lava flow, Hawaii; (2) December 1974 Kilauea lava flow, Hawaii; (3) c. 1600 ybp Collier Cone lava flow, central Oregon Cascades; (4) Holocene lava flows from the Sand Mountain volcanic chain, central Oregon Cascades; and (5) Pleistocene lava flows along the Owyhee River, eastern Oregon basin and range. These lava flows range in composition from basalt to andesite, and have eruption durations ranging from 6 hours (observed) to years (inferred). We measure channel width, levee and flow front heights, compression ridge amplitude, wavelength and tumuli dimensions, and surface roughness. For all but the smallest scale features, LiDAR is easily used to quantify these features, which often is impossible or technically challenging to do in the field, while

  19. Vulnerability of Karangkates dams area by means of zero crossing analysis of data magnetic (United States)

    Sunaryo, Susilo, Adi


    Study with entitled Vulnerability Karangkates Dam Area By Means of Zero Crossing Analysis of Data Magnetic has been done. The study was aimed to obtain information on the vulnerability of two parts area of Karangkates dams, i.e. Lahor dam which was inaugurated in 1977 and Sutami dam inaugurated in 1981. Three important things reasons for this study are: 1). The dam age was 36 years old for Lahor dam and 32 years old for Sutami dam, 2). Geologically, the location of the dams are closed together to the Pohgajih local shear fault, Selorejo local fault, and Selorejo limestone-andesite rocks contact plane, and 3). Karangkates dams is one of the important Hydro Power Plant PLTA with the generating power of about 400 million KWH per year from a total of about 29.373MW installed in Indonesia. Geographically, the magnetic data acquisition was conducted at coordinates (112.4149oE;-8.2028oS) to (112.4839oE;-8.0989oS) by using Proton Precession Magnetometer G-856. Magnetic Data acquisition was conducted in the radial direction from the dams with diameter of about 10 km and the distance between the measurements about 500m. The magnetic data acquisition obtained the distribution of total magnetic field value in the range of 45800 nT to 44450 nT. Residual anomalies obtained by doing some corrections, including diurnal correction, International Geomagnetic Reference Field (IGRF) correction, and reductions so carried out the distribution of the total magnetic field value in the range of -650 nT to 700 nT. Based on the residual anomalies, indicate the presence of 2 zones of closed closures dipole pairs at located in the west of the Sutami dam and the northwest of the Lahor dam from 5 total zones. Overlapping on the local geological map indicated the lineament of zero crossing patterns in the contour of residual anomaly contour with the Pohgajih shear fault where located at about 4 km to the west of the Sutami dam approximately and andesite-limestone rocks contact where located at

  20. Magma Diversity in the Trans-Mexican Volcanic Belt: the role of Mantle Heterogeneities, Slab-derived Fluxes and Crustal Contamination. (United States)

    Schaaf, P.; Valdez, G.; Siebe, C.; Carrasco, G.


    The Plio-Quaternary Trans-Mexican Volcanic Belt (TMVB) is related to subduction of the Cocos and Rivera plates underneath the North American plate. Non-parallelism of the magmatic arc with respect to the trench can be explained by oblique subduction and changes of dip angle. In this contribution we compare geochemical and Sr-Nd-Pb isotope data of five TMVB stratovolcanoes (from east to west: Colima Volcano, Nevado de Toluca, Popocatepetl, La Malinche, and Pico de Orizaba) and associated cinder cones. Volcanic products range in stratovolcanoes from andesites (e.g. Colima, Popocatepetl) to rhyolites (e.g. Pico de Orizaba), and from basalts to andesites in the monogenetic cones. Concentrations of incompatible elements correlate positively with Sr-Nd-Pb isotope ratios from east to west along the arc. 87Sr/86Sr, eNd, and 206Pb/204Pb range from 0.7034-0.7050, +6.9 to minus 1.8, and 18.57-18.78, respectively, displaying considerable differences. In the central TMVB, REE patterns of closely spaced high-Mg basaltic andesites differ substantially. This cannot be explained by fractional crystallization processes or differential partial melting of a homogeneous mantle source. Instead, it points towards small-scale mantle heterogeneities. LILE (e.g. Cs, Rb, Ba, Pb) and HFSE (e.g. Ta, Nb, Zr) display variations of orders in magnitude at different segments along the arc. These variations might correlate with amounts of slab-derived aqueous fluids and intensity of metasomatic reactions between the subducting lithosphere and the overlying mantle wedge. Isotopic ratios of mid-lower crustal xenoliths found in nearly all stratovolcano products reflect the nature of the underlying crust beneath the TMVB. Tertiary-Cretaceous plagiogranites (Colima), Cretaceous limestones (Popocatepetl), and Grenvillian quartzites (Pico de Orizaba)and their increasing radiogenic isotope ratios match well with the observed isotopic signatures of the stratovolcanoes. Moreover, elevated CO2 amounts in

  1. Geochemistry and petrogenesis of early Cretaceous sub-alkaline mafic dykes from Swangkre-Rongmil, East Garo Hills, Shillong plateau, northeast India

    Indian Academy of Sciences (India)

    Rajesh K Srivastava; Anup K Sinha


    Numerous early Cretaceous mafic and alkaline dykes, mostly trending in N-S direction, are emplaced in the Archaean gneissic complex of the Shillong plateau, northeastern India. These dykes are spatially associated with the N-S trending deep-seated Nongchram fault and well exposed around the Swangkre-Rongmil region. The petrological and geochemical characteristics of mafic dykes from this area are presented. These mafic dykes show very sharp contact with the host rocks and do not show any signature of assimilation with them. Petrographically these mafic dykes vary from fine-grained basalt (samples from the dyke margin) to medium-grained dolerite (samples from the middle of the dyke) having very similar chemical compositions, which may be classified as basaltic-andesite/andesite. The geochemical characteristics of these mafic dykes suggest that these are genetically related to each other and probably derived from the same parental magma. Although, the high-field strength element (+rare-earth elements) compositions disallow the possibility of any crustal involvement in the genesis of these rocks, but Nb/La, La/Ta, and Ba/Ta ratios, and similarities of geochemical characteristics of present samples with the Elan Bank basalts and Rajmahal (Group II) mafic dyke samples, suggest minor contamination by assimilation with a small amount of upper crustal material. Chemistry, particularly REE, hints at an alkaline basaltic nature of melt. Trace element modelling suggests that the melt responsible for these mafic dykes had undergone extreme differentiation (∼50%) before its emplacement. The basaltic-andesite nature of these rocks may be attributed to this differentiation. Chemistry of these rocks also indicates ∼10–15% melting of the mantle source. The mafic dyke samples of the present investigation show very close geochemical similarities with the mafic rocks derived from the Kerguelen mantle plume. Perhaps the Swangkre-Rongmil mafic dykes are also derived

  2. Precaldera lavas of the southeast San Juan Volcanic Field: Parent magmas and crustal interactions (United States)

    Colucci, M. T.; Dungan, M. A.; Ferguson, K. M.; Lipman, P. W.; Moorbath, S.


    Early intermediate composition volcanic rocks of the Oligocene (circa 34-29 Ma) southeast San Juan volcanic field, southern Colorado, comprise the Conejos Formation. Conejos lavas include both high-K calc-alkaline and alkaline magma series (54-69% SiO2) ranging in composition from basaltic andesite (basaltic trachyandesite) to dacite (trachydacite). The subsequent Platoro caldera complex (29-27 Ma) was superimposed on a cluster of broadly precursory Conejos stratocones. Precaldera volcanism occurred in three pulses corresponding to three time-stratigraphic members: (1) the Horseshoe Mountain member, (2) the Rock Creek member, and (3) the Willow Mountain member. Each member exhibits distinctive phenocryst modes and incompatible trace element contents. Horseshoe Mountain lavas (hornblende-phyric) have relatively low alkali and incompatible element abundances, Rock Creek lavas (anhydrous phenocrysts) and ash-flow tuffs have the highest abundances, and Willow Mountain lavas (diverse mineralogy) are intermediate. All Conejos lavas exhibit low ratios of lead (206Pb/204Pb = 17.5 to 18.2) and neodymium (ɛNd = -8 to -4) isotopes and high 87Sr/86Sr (0.7045 to 0.7056) compared to depleted asthenospheric mantle. These values lie between those of likely mantle compositions and the isotopic composition of Proterozoic crust of the southern Rocky Mountains. Mafic lavas of the Horseshoe Mountain member have the lowest Pb and Nd isotope ratios among Conejos members but trend toward higher isotopic values with increasing degrees of differentiation. Compositions within the Rock Creek series trend toward higher Pb and lower Nd isotope ratios with increasing SiO2. Willow mountain volcanic sequences define diverse chemical-isotopic correlations. We interpret the chemical and isotopic differences observed between mafic lavas of each member to reflect derivation from compositionally distinct mantle derived parent magmas that have experienced extensive deep level crustal contamination

  3. Post-collisional magmatism in the Late Miocene Rodna-Bârgău district (East Carpathians, Romania): Geochemical constraints and petrogenetic models (United States)

    Fedele, Lorenzo; Seghedi, Ioan; Chung, Sun-Lin; Laiena, Fabio; Lin, Te-Hsien; Morra, Vincenzo; Lustrino, Michele


    Post-collisional magmatism in the Late Miocene Rodna-Bârgău subvolcanic district (East Carpathians) gave rise to a wide variety of rock compositions, allowing recognition of four groups of calcalkaline rocks with distinctive petrography, mineral chemistry, whole-rock geochemistry and Sr-Nd-Hf isotope features. New U-Pb zircon datings, together with literature data, indicate that the emplacement of the four rock groups was basically contemporaneous in the 11.5-8 Ma time span. The low potassium group (LKG) includes the most abundant lithotypes of the area, ranging from basaltic andesite to dacite, characterized by K-poor tschermakitic amphibole, weak enrichment in LILE and LREE, relatively low 87Sr/86Sr, coupled with relatively high 143Nd/144Nd and 176Hf/177Hf. The high potassium group (HKG) includes amphibole-bearing microgabbro, amphibole andesite and amphibole- and biotite dacite, with K-richer magnesio-hastingsite to hastingsite amphibole, more marked enrichments in incompatible elements, higher 87Sr/86Sr and lower 143Nd/144Nd and 176Hf/177Hf. These two main rock groups seem to have originated from similar juxtaposed mantle sources, with the HKG possibly related to slightly more enriched domains (with higher H2O reflected by the higher modal amphibole) with respect to LKG (with higher plagioclase/amphibole ratios). The evolution of the two rock series involved also open-system processes, taking place mainly in the upper crust for the HKG, in the lower crust for LKG magmas. In addition, limited occurrences of generally younger strongly evolved peraluminous rhyolites and microgranites (Acid group) and sialic-dominated "leucocratic" andesites and dacites (LAD group) were also recognized to the opposite outermost areas of the district. These two latter rock groups were generated by the melting of a basic metamorphic crustal source (respectively in hydrous and anhydrous conditions), favored by the heat released by mantle melts from the adjoining central area. The

  4. Detection of morphological changes in cliff face surrounding a waterfall using terrestrial laser scanning and unmanned aerial system (United States)

    Hayakawa, Yuichi S.; Obanawa, Hiroyuki


    Waterfall or bedrock knickpoint appears as an erosional front in bedrock rivers forming deep v-shaped valley downstream. Following the rapid fluvial erosion of waterfall, rockfalls and gravita-tional collapses often occur in surrounding steep cliffs. Although morphological changes of such steep cliffs are sometimes visually observed, quantitative and precise measurements of their spatio-temporal distribution have been limited due to the difficulties in direct access to such cliffs if with classical measurement methods. However, for the clarification of geomorphological processes oc-curring in the cliffs, multi-temporal mapping of the cliff face at a high resolution is necessary. Re-mote sensing approaches are therefore suitable for the topographic measurements and detection of changes in such inaccessible cliffs. To achieve accurate topographic mapping of cliffs around a wa-terfall, here we perform multi-temporal terrestrial laser scanning (TLS), as well as structure-from-motion multi-view stereo (SfM-MVS) photogrammetry based on unmanned aerial system (UAS). The study site is Kegon Falls in central Japan, having a vertical drop of surface water from top of its overhanging cliff, as well as groundwater outflows from its lower portions. The bedrock is composed of alternate layers of andesite lava and conglomerates. Minor rockfalls in the cliffs are often ob-served by local people. The latest major rockfall occurred in 1986, causing ca. 8-m upstream propa-gation of the waterfall lip. This provides a good opportunity to examine the changes in the surround-ing cliffs following the waterfall recession. Multi-time point clouds were obtained by TLS measure-ment over years, and the three-dimensional changes of the rock surface were detected, uncovering the locus of small rockfalls and gully developments. Erosion seems particularly frequent in relatively weak the conglomerates layer, whereas small rockfalls seems to have occurred in the andesite layers. Also, shadows in the

  5. Bimodal volcanism in a tectonic transfer zone: Evidence for tectonically controlled magmatism in the southern Central Andes, NW Argentina (United States)

    Petrinovic, I. A.; Riller, U.; Brod, J. A.; Alvarado, G.; Arnosio, M.


    This field-based and analytical laboratory study focuses on the genetic relationship between bimodal volcanic centres and fault types of an important tectonic transfer zone in the southern Central Andes, the NW-SE striking Calama-Olacapato-Toro (COT) volcanic belt. More specifically, tectono-magmatic relationships are examined for the 0.55 Ma Tocomar, the 0.78 Ma San Jerónimo and the 0.45 Ma Negro de Chorrillos volcanic centres in the Tocomar area (66°30 W-24°15 S). Structures of the COT volcanic belt, notably NW-SE striking strike-slip faults and NE-SW trending normal faults, accommodated differential shortening between major N-S striking thrust faults on the Puna Plateau. We present evidence that bimodal volcanism was contemporaneous with activity of these fault types in the COT volcanic belt, whereby eruption and composition of the volcanic rocks in the Tocomar and San Jerónimo-Negro de Chorrillos areas appear to have been controlled by the kinematics of individual faults. More specifically, rhyolitic centres such as the Tocomar are associated with normal faults, whereas shoshonitic-andesitic monogenetic volcanoes, e.g., the San Jerónimo and Negro de Chorrillos centres, formed at strike-slip dominated faults. Thus, the eruption of higher viscous rhyolite magmas appears to have been facilitated in tectonic settings characterized by horizontal dilation whereas ascent and effusive volcanic activity of less viscous and hot basaltic andesites to shoshonites were controlled by subvertical strike-slip faults. While the Tocomar rhyolites are interpreted to be derived from an anatectic crustal source, geochemical characteristics of the San Jerónimo and Negro de Chorrillos shoshonitic andesites are in agreement with a deeper source. This suggests that the composition of erupted volcanic rocks as well as their spatial distribution in the Tocomar area is controlled by the activity of specific fault types. Such volcano-tectonic relationships are also evident from older

  6. Petrology of Volcán Tequila, Jalisco, Mexico: disequilibrium phenocryst assemblages and evolution of the subvolcanic magma system (United States)

    Wallace, Paul J.; Carmichael, Ian S. E.


    Volcán Tequila is an extinct stratovolcano in the western Mexican Volcanic Belt that has erupted lavas ranging from andesite to rhyolite during the last 0.9 Ma. Following an early period of rhyolitic volcanism, the main edifice of the volcano was constructed by central vent eruptions that produced ˜ 25 km3 of pyroxene-andesite. At about 0.2 Ma central activity ceased and numerous flows of hornblende-bearing andesite, dacite, and rhyodacite erupted from vents located around the flanks of the volcano. Bimodal plagioclase phenocryst rim compositions in lavas from both the main edifice and the flanks indicate that magma mixing commonly occurred shortly prior to or during eruption. Compositions of endmember magmas involved in mixing, as constrained by whole-rock major and trace element abundances, phenocryst compositions, and mineral-melt exchange equilibria, are similar to those of some lavas erupted from the central vent and on the flanks of the volcano. Estimated pre-eruptive temperatures for hornblende-bearing lavas (970° 830°C) are systematically lower than for lavas that lack hornblende (1045° 970°C), whereas magmatic H2O contents are systematically higher for hornblende-bearing lavas. In addition to stabilizing hornblende, high magmatic water contents promoted crystallization of calcic plagioclase (An70 82). Frequent injections of magma into the base of the subvolcanic plumbing system followed by eruption of mixed magma probably prevented formation of large volumes of silicic magma, which have caused paroxysmal, caldera-forming eruptions at other stratovolcanoes in western Mexico. The later stages of volcanic activity, represented by the flank lavas, indicate a change from a large magma storage reservoir to numerous small ones that developed along a NW-trending zone parallel to regional fault trends. Sr and Nd isotopic data for lavas from the Tequila region and other volcanoes in western Mexico demonstrate that differentiated calc-alkaline magmas are formed

  7. The timing of compositionally-zoned magma reservoirs and mafic 'priming' weeks before the 1912 Novarupta-Katmai rhyolite eruption (United States)

    Singer, Brad S.; Costa, Fidel; Herrin, Jason S.; Hildreth, Wes; Fierstein, Judy


    The June, 6, 1912 eruption of more than 13 km3 of dense rock equivalent (DRE) magma at Novarupta vent, Alaska was the largest of the 20th century. It ejected >7 km3 of rhyolite, ∼1.3 km3 of andesite and ∼4.6 km3 of dacite. Early ideas about the origin of pyroclastic flows and magmatic differentiation (e.g., compositional zonation of reservoirs) were shaped by this eruption. Despite being well studied, the timing of events that led to the chemically and mineralogically zoned magma reservoir remain poorly known. Here we provide new insights using the textures and chemical compositions of plagioclase and orthopyroxene crystals and by reevaluating previous U-Th isotope data. Compositional zoning of the magma reservoir likely developed a few thousand years before the eruption by several additions of mafic magma below an extant silicic reservoir. Melt compositions calculated from Sr contents in plagioclase fill the compositional gap between 68 and 76% SiO2 in whole pumice clasts, consistent with uninterrupted crystal growth from a continuum of liquids. Thus, our findings support a general model in which large volumes of crystal-poor rhyolite are related to intermediate magmas through gradual separation of melt from crystal-rich mush. The rhyolite is incubated by, but not mixed with, episodic recharge pulses of mafic magma that interact thermochemically with the mush and intermediate magmas. Hot, Mg-, Ca-, and Al-rich mafic magma intruded into, and mixed with, deeper parts of the reservoir (andesite and dacite) multiple times. Modeling the relaxation of the Fe-Mg concentrations in orthopyroxene and Mg in plagioclase rims indicates that the final recharge event occurred just weeks prior to the eruption. Rapid addition of mass, volatiles, and heat from the recharge magma, perhaps aided by partial melting of cumulate mush below the andesite and dacite, pressurized the reservoir and likely propelled a ∼10 km lateral dike that allowed the overlying rhyolite to reach the

  8. Rock property measurements guide interpretation of electromagnetic, magnetic and gravity models at Mts. Adams, Baker, Rainier and St. Helens (Invited) (United States)

    Finn, C.; Bedrosian, P. A.; Horton, R.; Polster, S.


    Hydrothermally altered rocks, particularly if water saturated, can weaken volcanoes, thereby increasing the potential for catastrophic sector collapses that can lead to far-traveled, destructive debris flows. Such alteration significantly reduces the electrical resistivity, magnetization and density of volcanic rocks, resulting in a clear distinction between altered and unaltered rock in geophysical survey measurements. We measured electrical resistivity, susceptibility and density of rock samples to help constrain models of the three-dimensional distribution of water saturated, hydrothermally altered sections of several Cascade Volcanoes, Washington, critical for understanding volcanic landslide hazards. Samples ranged from fresh, massive andesite and dacite to completely altered powders composed of opal, alunite, kaolinite, and montmorillonite. The resistivity of each sample was measured over 11 frequencies ranging from 100 to 100,000 Hz for dry and wet samples. Almost all dry sample resistivities typically exceed 5000 ohm-m. Water saturation levels vary from 2 to 33 wt% in the rocks samples and surpass 50% for the powders. Fresh andesite resistivity values exceed 1500 ohm-m, even when saturated. Resistivities of saturated, moderately altered samples and an intensely altered, low-porosity (~5%) opal and alunite sample are greater than 450 ohm m. Values less than 100 ohm-m are associated with saturated (>50%), intensely altered opal + alunite powders. Magnetic susceptibilities for the fresh volcanic rocks range from 4-25 x 10-3 SI while those of altered andesites range from 0 to 0.35 x 10-3 SI. Densities for the fresh rocks range from about 2200 - 2600 kg/m3 and 1300-1900 kg/m3 for the altered rocks. The combination of the rock property measurements, geophysical data and geological mapping, indicates the presence of appreciable thicknesses (>500 m) of altered rock west of the modern summit of Mt. Rainier in the Sunset Amphitheater region and in the central core of

  9. Chronology and Geochemistry of Mesozoic Volcanic Rocks in the Linjiang Area, Jilin Province and their Tectonic Implications

    Institute of Scientific and Technical Information of China (English)

    YU Yang; XU Wenliang; PEI Fuping; YANG Debin; ZHAO Quanguo


    Zircon U-Pb ages and geochemical analytical results are presented for the volcanic rocks of the Naozhigou, Ergulazi, and Sidaogou Formations in the Linjiang area, southeastern Jilin Province to constrain the nature of magma source and their tectonic settings. The Naozhigou Formation is composed mainly of andesite and rhyolite and its weighted mean 206Pb/238U age for 13 zircon grains is 2224±1 Ma. The Ergulazi Formation consists of basaltic andesite, basaltic trachyandesite, and andesite, and six grains give a weighted mean 206Pb/238U age of 131±4 Ma. The Sidaogou Formation consists mainly of trachyandesite and rhyolite, and six zircon grains yield a weighted mean 206Pb/238U age of113±4 Ma. The volcanic rocks have SiO2=60.24%-77.46%, MgO=0.36%-1.29% (Mg#=0.32-0.40) for the Naozhigou Formation, SiO2=51.60%-59.32 %, MgO=3.70 %-5.54% (Mg#=0.50-0.60) for the Ergulazi Formation, and SiO2=58.28%-76.32%, MgO=0.07%-1.20% (Mg#=0.14-0.46) for the Sidaogou Formation. The trace element analytical results indicate that these volcanic rocks are characterized by enrichment in light rare earth elements (LREEs) and large ion lithophile elements (LILEs), relative depletion in heavy rare earth elements (HREEs) and high field strength elements (HFSEs, Nb, Ta, and Ti), and negative Eu anomalies. Compared with the primitive mantle, the Mesozoic volcanic rocks in the Linjiang area have relatively high initial 87Sr/86Sr ratios (0.7053-0.7083) and low eNd(t) values (-8.38 to -2.43), and display an EMII trend. The late Triassic magma for the Naozhigou Formation could be derived from partial melting of a newly accretional crust with the minor involvement of the North China Craton basement and formed under an extensional environment after the collision of the Yangtze Craton and the North China Craton. The Early Cretaceous volcanic rocks for the Ergulazi and Sidaogou Formations could be formed under the tectonic setting of an active continental margin related to the westward snbduction of

  10. The Montesbelos mass-flow (southern Amazonian craton, Brazil): a Paleoproterozoic volcanic debris avalanche deposit? (United States)

    Roverato, M.


    The present contribution documents the extremely well-preserved Paleoproterozoic architecture of the Montesbelos breccia (named here for the first time), which is interpreted as a rare example of a subaerial paleoproterozoic (>1.85 Ga) granular-dominated mass-flow deposit, few of which are recorded in the literature. Montesbelos deposit is part of the andesitic Sobreiro Formation located in the São Felix do Xingu region, southern Amazonian craton, northern Brazil. The large volume, high variability of textural features, presence of broken clasts, angular low sphericity fragments, mono- to heterolithic character, and the size of the outcrops point to a volcanic debris avalanche flow. Fluviatile sandy material and debris flows are associated with the deposit as a result of post-depositional reworking processes.

  11. Development Techniques of Zaoyuan Oilfield

    Institute of Scientific and Technical Information of China (English)

    Yang Tianji


    @@ Situation of the Oilfield Zaoyuan Oilfield located in Cangxian County of Hebei Province is a main production oilfield of Dagang Petroleum Administration Bureau. Its structure location is in the center of Kongdian Uplift and at two sides of Kongxi Fault. The main oil-bearing sequences of the oil field are No. 1 and 2 formations of Tertiary Period and andesite formation of Mesozoic with buried depth of 1 700- 3 050 m, composed of Zilaitun,Fenghuadian and Shenjiapu oil-bearing structures (Fig. 1). The industrial oil flow was firstly obtained from Kong well No. 17 in Zaobei area in 1971,which was put into development in 1978. By the end of 1992,the proven oil-bearing area was 48. 1 km2,original oil in place 147 million tons ,developed producing oil-bearing area 21.6 km2,and proven producing reserves in place 60 460 000 tons.


    Directory of Open Access Journals (Sweden)

    Ioan Bâca


    Full Text Available Igneous intrusive structures from Bârgău Mountains belong to the group of central Neogene volcanic chain of the Eastern Carpathians of Romania. The evolution of the relief developed on these structures are three main stages: the stage of injection of structures (Pannonian, the stage of uncovering of igneous intrusive bodies from Oligo-Miocene sedimentary cover (Pliocene, and the stage of subaerial modeling of magmatic bodies (Pliocene-current.In those circumstances, the geodiversity of intrusive magmatic structures from Bârgău Mountains is represented by several types of landforms such as: polycyclic landforms (erosional levels, structural landforms (the configuration of igneous intrusive structures, petrographic landforms (andesites, lithological contact, fluvial landforms (valleys, slopes, ridges, periglacial landforms (cryogenic and crionival landforms, biogenic and anthropogenic landforms. This study highlights certain features of the landforms modeled on igneous intrusive bodies with the aim of developing some strategy for tourism recovery by local and county authorities.

  13. Geochemical characteristics of Huanggou gold deposit in western Henan%豫西黄沟金矿床地质地球化学特征

    Institute of Scientific and Technical Information of China (English)



    This paper studied geochemical characteristics of Huanggou gold deposit and elaborated on the effect of Taihua formation on mineralization of gold deposits in this area.The result suggested that(1 )the protolith of gneiss was igneous and fell in high-k calc-alkaline series,and gold ores were pervasively charac-terized by Na-poorness and K-Ca-richness and high grade of SiO 2 content,while the grade of Au was positive-ly correlated to content of SiO 2 ;(2)the trace element characteristics suggested sever edepletion of elements like Rb,Ta,Ti,Ba,Sm and Y in the ore samples,and the similar normalized pattern with gneiss of Taihua Group and andesite of Xiong'er Group suggested that Au mineralization was possibly associated with gneiss and andesite in terms of genesis;(3)the rare earth element characteristics suggested slight depletion of light rare earth and slight enrichment of heavy rare earth in most of the gold ores.Weak negative Eu anomaly was quite different from the normalized pattern of various out cropped rocks and rare earth elements in this area (right declined),yet was derived from deep part.The normalized pattern of some gold ore was to some ex-tent similar with gneiss or (and)andesite and had the right declined weak negative Eu anomaly pattern,and it suggested that the genesis of Taihua Group and (or)andesite of Xiong’er Group contributed some ore-form-ing substances to the mineralization.%通过研究黄沟金矿床中岩石地球化学特征,从而探讨太华群地层对于该区金矿床成矿的作用。研究表明(1)本区的片麻岩原岩主要为火成岩,属高钾钙碱性系列,且金矿石一般都明显贫钠而富钾、富钙,SiO 2含量普遍较高,Au 品位随 SiO 2的含量增高而呈正相关变化;(2)微量元素特征表明矿石样品以Rb、Ta、Ti 等元素强烈亏损,Ba、Sm 和 Y 元素强烈亏损为特征,与太华群片麻岩和熊耳群安山岩的标准化分布曲线型式接近,说明金矿化可能与太华群片麻

  14. An oxygen isotope and geochemical study of meteoric-hydrothermal systems at Pilot Mountain and selected other localities, Carolina slate belt (United States)

    Klein, T.L.; Criss, R.E.


    Several epigenetic mineral deposits in the Carolina slate belt are intimately related to meteoric-hydrothermal systems of late Precambrian and early Paleozoic age. At Pilot Mountain, low 18O rocks correlate well with zones of strong silicic alteration and alkali leaching accompanied by high alumina minerals (sericite, pyrophyllite, andalusite ?? topaz) and anomalous concentrations of Cu, Mo, Sn, B, and Au. A magmatic source for much of the sulfur and metal is likely, and a subordinate magmatic water component in the fluid of the central zone is possible. This central zone is surrounded by a >30 km2 peripheral zone of low 18O sericite schists, chlorite-sericite schists, and andesitic volcanic rocks. Reconnaissance studies of other alteration zones in the Carolina slate belt have so far disclosed the involvement of meteoric-hydrothermal fluids at the Snow Camp pyrophyllite deposit, at the Hoover Hill and Sawyer Au mines, and probably at the Haile and Brewer Au mines. -from Authors

  15. Sulfate Saturated Hydrous Magmas Associated with Hydrothermal Gold Ores (United States)

    Chambefort, I.; Dilles, J. H.; Kent, A. J.


    Hydrothermal ore deposits associated with arc magmatism represent important sulfur anomalies. During degassing of magmatic systems the volatile may transport metals and sulfur and produce deposits. The ultimate origin of the magma-derived sulfur is still uncertain. The Yanacocha high-sulfidation epithermal Au deposit, Peru, is hosted by a Miocene volcanic succession (ca. 16 to 8 Ma). Magmatic rocks are highly oxidized >NNO+2 and show a range of composition from andesite to dacite. Two populations of amphibole occur in the Yanacocha dacitic ignimbrite deposits (~7 and 12 wt% Al2O3). Low Al amphiboles crystallized at ~ 1.5-2 kbar and 800°C (Plag-Hb thermobarometry) in equilibrium with plagioclase and pyroxene. High Al amphiboles only contain inclusions of anhydrite associated with apatite (up to 1.2 wt% SO3), and have a higher Cr2O3 content (up to 1000 ppm). We estimate these amphiboles form near the magma's liquidus at P(H2O)> 3kbar and 950 to 1000°C of a basaltic, basaltic andesite ascending magma. Low Al amphibole presents an REE pattern with negative anomalies in Sr, Ti and Eu, characteristic of plagioclase and titanite fractionation in the magma. High Al amphiboles are less enriched in REE and have no Sr, Ti, or Eu anomaly. Rare crystals of high Al amphibole display a low Al rim marked by higher REE contents compared to the core and a negative Eu anomaly. Magmatic sulfate occurrences have been discovered through the 8 m.y. volcanic sequence. Rounded anhydrite crystals are found included within clinopyroxene and both high and low Al amphibole. The rare high Al amphiboles (from the sample RC6) contain up to ~10 vol.%, ~5-80 micrometer-long anhydrite as irregularly shaped (amoeboid) blebs that do not show crystallographic forms and do not follow host cleavages. Extremely rare sulfide inclusions are found in plagioclase (Brennecka, 2006). The major and trace element contents of Yanacocha magmatic anhydrite have been analyzed by electron microprobe and LA

  16. Análisis e interpretación de los materiales volcánicos del Cerro de los Frailes (Cabo de Gata. Almería

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    Fernández Soler, J. M.


    Full Text Available The formation of Los Frailes volcano had two stages, which produced amphibole andesites (Frailes-I and two-pyroxene andesites (Frailes-II respectively, Iying on the extension of the dacites and andesites of the southernmost Cabo de Gata volcanoes (Revancha-Sabinal. The FRAILES-I stage is discontinuous, and has mainly produced domes and autoclastic breccias, in addition to an intermediate level of pumice-and-ash flow; this unit has some intercalated sedimentary levels. To the NE it is covered by a formation of sedimentary and hydroclastic rocks. The Frailes-II stage is continuous, and has formed some lava flows, the two summit domes, and sorne pyroclastic rocks of scarcely explosive origin. Other volcanic features are some domes and dikes of biotite-amphibole dacites, which affect to the Frailes-I-group; these are the southern continuation of the dacitic volcanic group of Rodalquilar-Rellana-Garbanzal. The generally accepted idea of a succesion in Cabo de Gata of cycles which started very explosively and ended with subvolcanic extrussions (domes does not seem to be very realistic at least in the building of Los Frailes. A review of geochronological data, and the field disposition of the described materials does not discard the hypothesis that the pyroxene andesites of FrailesI-I might have been formed simultaneously or even than later the ignimbritic dacites of the Rodalquilar group.La formación del volcán de Los Frailes se produjo en dos ciclos, de composiciones andesítica anfibólica (Frailes-I y andesitica de dos piroxenos (Frailes-II, apoyadas sobre la prolongación hacia el este de las andesitas y dacitas del extremo sur de Cabo de Gata (edificio de Revancha-Sabinal-Cabo de Gata. El ciclo Frailes-I es discontínuo y ha formado domos y brechas autoclásticas principalmente, mas un nivel intermedio de colada piroclástica pumítica; este ciclo contiene niveles sedimentarios intercalados. Al NE es cubierto por una formación de rocas

  17. Petrography and geochemistry of metamafic rocks intercalated in gneisses from Goiás Magmatic Arc, region of Indiara (GO

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    Guillermo Rafael Beltran Navarro


    Full Text Available In Indiara region (GO, dozens of metamafic rocks lenses of various dimensions (metric to kilometric occur, intercalated in gneisses of the Goiás Magmatic Arc and oriented according to the direction of the main foliation (Sn. These lenses consist of amphibolite (amphibole schists and amphibolites, have chemical compositions of sub-alkaline basalts to andesitic basalts and sub-alkaline tholeiitic affinity. The distribution of major and trace elements, as well as rare earth elements (REE, suggests that these rocks are derived from a source with similar geochemical signature. The analyzed rocks are enriched in large ion litophile elements (Cs, Rb, Ba, K, Th and U in relation to elements of high field strength (Nb, Ta, Zr, Hf and Y and in relation to REE, Sr, P and Ti, showing weak to medium negative anomalies of Nb, Ta and P and suggesting that these rocks were generated in a magmatic arc environment.

  18. An Early Cretaceous volcanic arc/marginal basin transition zone, Peninsula hardy, southernmost Chile (United States)

    Miller, Christopher A.; Barton, Michael; Hanson, Richard E.; Fleming, Thomas H.


    The Hardy Formation represents a latest Jurassic-Early Cretaceous volcanic arc that was located along the Pacific margin of southern South America. It was separated from the continent by a marginal basin floored by portions of an ophiolite sequence (the Rocas Verdes ophiolites). The transition between the arc and marginal basin occurs on Peninsula Hardy, southernmost Chile, where there is a lateral facies transition from arc deposits of the Hardy Formation into proximal marginal basin fill of the Yahgan Formation. Interfingering of arc and marginal basin sequences demonstrates that subduction-related arc magmatism was concurrent with marginal basin formation. The lateral facies transition is reflected in the geochemistry of volcanic rocks from the Hardy and Yahgan formations. Basalts, andesites and dacites of the arc sequence follow a calc-alkaline differentiation trend whereas basalts from the marginal basin follow a tholeiitic differentiation trend. Estimates of temperature and oxygen fugacity for crystallization of the arc andesites are similar to values reported for other calc-alkaline andesites. It is suggested that water activity influenced the early or late crystallization of Ti-magnetite and this controlled the style of differentiation of the magmas erupted on Peninsula Hardy. Magmas with high water contents evolved along the calc-alkaline differentiation trend whereas those with low water contents evolved along the tholeiitic differentiation trend. Some rhyolites are differentiated from the calc-alkaline andesites and dacites, but most appear to be the products of crustal anatexis on the basis of trace-element evidence. The arc basalts and some marginal basin basalts show relative enrichment in LILE, relative depletion in HFSE, and enrichment in LREE. Other marginal basin basalts are LREE depleted and show small relative depletions in HFSE. Basalts with both calc-alkaline and tholeiitic affinities can also be recognized in the Rocas Verdes ophiolites


    Institute of Scientific and Technical Information of China (English)


    <正>20091749 Cai Hou’an(College of Energy Geology,China University of Geosciences,Beijing 100083,China);Xu Debin SHRIMP U-Pb Isotope Age of Volcanic Rocks Distributed in the Badaohao Area,Liaoning Province and Its Significance(Coal Geology & Exploration,ISSN1001-1986,CN61-1155/P,36(4),2008,p.17-20,2 illus.,1 table,16 refs.)Key words:coal measures,volcanic rocks,U-Pb dating,LiaoningA set of andesite volcanic rocks distributes in the Badaohao area in Heishan County,Liaoning Province.It’s geological age and stratigraphy sequence relationship between the Lower Cretaceous Badaohao Formation and the volcanic rocks can not make sure till now and is influencing the further prospect for coals.Zircon

  20. Facies-controlled volcanic reservoirs of northern Songliao Basin, NE China

    Institute of Scientific and Technical Information of China (English)


    Volcanic rocks of the late Mesozoic are very important reservoirs for the commercial natural gases including hydrocarbon, carbon dioxide and rare gases in the northern Songliao Basin. The reservoir volcanic rocks include rhyolite,andesite, trachyte, basalt and tuff. Facies of the volcanic rocks can be classified into 5 categories and 15 special types.Porosity and permeability of the volcanic reservoirs are facies-controlled. Commercial reservoirs were commonly found among the following volcanic subfacies: volcanic neck (Ⅰ1), underground-explosive breccia (Ⅰ3), pyroclastic-bearing lava flow (Ⅱ3), upper effusive (Ⅲ3) and inner extrusive ones (Ⅳ1). The best volcanic reservoirs are generally evolved in the interbedded explosive and effusive volcanics. Rhyolites show in general better reservoir features than other types of rocks do.

  1. Geochemistry of Archaean supracrustal belts in SW Greenland

    DEFF Research Database (Denmark)

    Szilas, Kristoffer

    . (3) The Nunatak 1390 area contains ultramafic rocks with geochemical characteristics similar to high-Ti komatiites, but they show geochemical signs of a juvenile slab melt contribution. Their high MgO contents may thus reflect flux-melting of a refractory mantle source, as is the case for boninites......This PhD-thesis investigates the geological formation environment of c. 3200-3000 million-year-old volcanic rocks from SW Greenland, using whole-rock geochemical data in combination with U-Pb, Sm-Nd and Lu-Hf isotope data. The following three supracrustal areas were studied: (1) The Tartoq Group...... geochemical mixing trends between juvenile felsic and mafic end-members. This suggests that partial melting and magma mixing by mafic underplating and slab melt metasomatism of the mantle source region were important in forming rocks of andesitic composition, which is also observed in some modern island arcs...

  2. Nd—Sr Isotope Geological Study on the Age of Armantai Ophiolite,Xinjiang,China

    Institute of Scientific and Technical Information of China (English)

    黄萱; 金成伟; 等


    Sm-Nd and Rb-Sr whole-rock isochron dating of the samples of cumulated gabbro,diabase and andesitic porphyrite from the Armantai ophiolite,Xinjiang,yielded the ages of 561±41(Ma(εNd(t)=6.1)and 392±17Ma(87Sr/86Sr)i=0.7041],which stand for the ages of creation and later metamorphism of the ophiolites,respectively,The creation environment of the Armantai ophiolites seems to a back-arc basin caused by the southward subduction of the the Armantai ophiloites seems to a back-arc basin caused by the southward subduction of the palaeo-Asia Ocean.

  3. Evidence for crustal recycling during the Archean: The parental magmas of the stillwater complex (United States)

    Mccallum, I. S.


    The petrology and geochemistry of the Stillwater Complex, an Archean (2.7 Ga) layered mafic intrusion in the Beartooth Mountains of Montana is discussed. Efforts to reconstruct the compositions of possible parental magmas and thereby place some constraints on the composition and history of their mantle source regions was studied. A high-Mg andesite or boninite magma best matches the crystallization sequences and mineral compositions of Stillwater cumulates, and represents either a primary magma composition or a secondary magma formed, for example, by assimilation of crustal material by a very Mg-rich melt such as komatiite. Isotopic data do not support the extensive amounts of assimilation required by the komatiite parent hypothesis, and it is argued that the Stillwater magma was generated from a mantle source that had been enriched by recycling and homogenization of older crustal material over a large area.

  4. Early Paleozoic ridge subduction in the Chinese Altai: Insight from the abrupt change in zircon Hf isotopic compositions

    Institute of Scientific and Technical Information of China (English)


    Zircons were separated from granitoids, gneisses, and sedimentary rocks of the Chinese Altai. Those with igneous characteristics yielded U-Pb ages of 280-2800 Ma, recording a long history of magmatic activity in the region. Zircon Hf isotopic compositions show an abrupt change at ~420 Ma, indicating that prior to that time the magmas came from both ancient and juvenile sources, whereas younger magmas were derived mainly from juvenile material. This may imply that the lithosphere was signifi- cantly modified in composition by a rapid addition of melt from the mantle. We suggest that this dramatic change was due to the onset of ridge subduction, which can account not only for the formation of voluminous granitoids, mafic rocks with complex compositions, and the association of adakite + high-Mg andesite + boninite + Nb-enriched basalt, but also for the coeval high-T, low-P metamorphism.

  5. Contrasting compositional trends of rocks and olivine-hosted melt inclusions from Cerro Negro volcano (Central America): implications for decompression-driven fractionation of hydrous magmas (United States)

    Portnyagin, Maxim V.; Hoernle, Kaj; Mironov, Nikita L.


    Melt inclusions in olivine Fo83-72 from tephras of 1867, 1971 and 1992 eruptions of Cerro Negro volcano represent a series of basaltic to andesitic melts of narrow range of MgO (5.6-8 wt %) formed by ~46 wt % fractional crystallization of olivine (~6 wt %), plagioclase (~27 wt %), pyroxene (~13 wt %) and magnetite (high-Mg basalts reflects the process of phenocryst re-distribution in progressively evolving melt. The crystallization scenario is anticipated to operate everywhere in dykes feeding basaltic volcanoes and can explain the predominance of plagioclase-rich high-Al basalts in island arc as well as typical compositional variations of magmas during single eruptions.

  6. Experimental Evidence for Polybaric Intracrustal Differentiation of Primitive Arc Basalt beneath St. Vincent, Lesser Antilles (United States)

    Blundy, Jon; Melekhova, Lena; Robertson, Richard


    We present experimental phase equilibria for a primitive, high-Mg basalt from St. Vincent, Lesser Antilles. Experimental details were presented in Melekhova et al (Nature Geosci, 2013); the objective here is to compare experimental phase compositions to those of erupted lavas and cumulates from St. Vincent. Starting material with 4.5 wt% H2O is multiply-saturated with a lherzolite assemblage at 1.3 GPa and 1180 ° C, consistent with mantle wedge derivation. Experimental glasses from our study, in addition to those of Pichavant et al (GCA, 2002) and Pichavant & Macdonald (CMP 2007) on a similar high-Mg basalt, encompass a compositional range from high-magnesian basalt to dacite, with a systematic dependence on H2O content, temperature and pressure. We are able to match the glasses from individual experiments to different lava types, so as to constrain the differentiation depths at which these magmas could be generated from a high-Mg parent, as follows: Composition wt% H2OP (GPa) T (° C) High-Mg basalt 3.9-4.8 1.45-1.751180-1200 Low-Mg basalt 2.3-4.5 1.0-1.3 1065-1150 High alumina basalt 3.0-4.5 0.4 1050-1080 Basaltic andesite 0.6-4.5 0.7-1.0 1050-1130 Andesite 0.6 1.0 1060-1080 The fact that St. Vincent andesites (and some basaltic andesites) appear to derive from a low-H2O (0.6 wt%) parent suggest that they are products of partial melting of older, high-Mg gabbroic rocks, as 0.6 wt% H2O is approximately the amount that can be stored in amphibole-bearing gabbros. The higher H2O contents of parents for the other lava compositions is consistent with derivation by crystallization of basalts with H2O contents that accord with those of olivine-hosted melt inclusions from St. Vincent (Bouvier et al, J Petrol, 2008). The generation of evolved melts both by basalt crystallization and gabbro melting is consistent with the hot zone concept of Annen et al (J Petrol, 2006) wherein repeated intrusion of mantle-derived basalt simultaneously crystallize by cooling and melt

  7. Early Paleozoic ridge subduction in the Chinese Altai:Insight from the abrupt change in zircon Hf isotopic compositions

    Institute of Scientific and Technical Information of China (English)

    SUN Min; LONG XiaoPing; CAI KeDa; JIANG YingDe; WANG BuYun; YUAN Chao; ZHAO GuoChun; XIAO WenJiao; WU FuYuan


    Zircons were separated from granitoids,gneisses,and sedimentary rocks of the Chinese Altai.Those with igneous characteristics yielded U-Pb ages of 280-2800 Ma,recording a long history of magmatic activity in the region.Zircon Hf isotopic compositions show an abrupt change at ~420 Ma,indicating that prior to that time the magmas came from both ancient and juvenile sources,whereas younger magmas were derived mainly from juvenile material.This may imply that the lithosphere was significantly modified in composition by a rapid addition of melt from the mantle.We suggest that this dramatic change was due to the onset of ridge subduction,which can account not only for the formation of voluminous granitoids,mafic rocks with complex compositions,and the association of adakite + high-Mg andesite+boninite + Nb-enriched basalt,but also for the coeval high-T,Iow-P metamorphism.

  8. Early Devonian suprasubduction ophiolites of the southern Urals (United States)

    Belova, A. A.; Ryazantsev, A. V.; Razumovsky, A. A.; Degtyarev, K. E.


    The composition of ophiolites widespread in the southern Urals shows that they were formed in a suprasubduction setting. Low-Ti and high-Mg sheeted dikes and volcanic rocks vary from basalt to andesite, and many varieties belong to boninite series. The rocks of this type extend as a 600-km tract. The volcanic rocks contain chert interbeds with Emsian conodonts. Plagiogranites localized at the level of the sheeted dike complex and related to this complex genetically are dated at 400 Ma. The ophiolites make up a base of thick islandarc volcanic sequence. The composition of the igneous rocks and the parameters of their metamorphism indicate that subduction and ascent of a mantle plume participated in their formation. The nonstationary subduction at the intraoceanic convergent plate boundary developed, at least, from the Middle Ordovician.


    Schaber, Gerald C.; Kozak, R.C.; Burns, Barbara A.; Bartels, K.I.


    The objective of this poster paper is to present a site-specific atlas showing a wide variety of remote sensing data sets collected for the area of S. P. Mountain and lava flow (basaltic-andesite) in north-central Arizona. The data set to be displayed includes a number of radar images, representing three wavelength regions (1-, 3- and 25-cm), multiple incidence angles, look directions, and polarization combinations, in addition to thermal infrared scanner imagery, multispectral scanner imagery, aerial and ground photography, micro- and macro topography, and four-frequency, multipolarization radar scatterometer spectra. The expression of different surface units on the S. P. lava flow are effectively displayed on the ERIM four-channel images by the registration and combination of the four bands. Multi-color imagery of band combinations demonstrate the information content of multi-channel SAR imagery as well as the suitability of extending data manipulation methods developed for Landsat data to SAR data.

  10. The Laramide Mesa formation and the Ojo de Agua caldera, southeast of the Cananea copper mining district, Sonora, Mexico (United States)

    Cox, Dennis P.; Miller, Robert J.; Woodbourne, Keith L.


    The Mesa Formation extends from Cananea, Mexico, southeast to the Sonora River and is the main host rock of Laramide porphyry copper deposits in the Cananea District and at the Alacran porphyry prospect to the east. The Mesa consists of two members-a lower andesite and an upper dacite. The lowest part of the dacite member is a crystal tuff about 100 m thick. This tuff is the outfall of a caldera centered near the village of Ojo de Agua, dated by 40Ar/39Ar at 65.8 Ma ?0.4. The Ojo de Agua Caldera is about 9 km in diameter and is filled by a light gray biotite dacite tuff with abundant flattened pumice fragments. The volume of the caldera is estimated to be 24 km3.

  11. Zircon U-Pb and molybdenite Re-Os geochronology and Sr-Nd-Pb-Hf isotopic constraints on the genesis of the Xuejiping porphyry copper deposit in Zhongdian, Northwest Yunnan, China (United States)

    Leng, Cheng-Biao; Zhang, Xing-Chun; Hu, Rui-Zhong; Wang, Shou-Xu; Zhong, Hong; Wang, Wai-Quan; Bi, Xian-Wu


    The Xuejiping porphyry copper deposit is located in northwestern Yunnan Province, China. Tectonically, it lies in the southern part of the Triassic Yidun island arc. The copper mineralization is mainly hosted in quartz-dioritic and quartz-monzonitic porphyries which intruded into clastic-volcanic rocks of the Late Triassic Tumugou Formation. There are several alteration zones including potassic, strong silicific and phyllic, argillic, and propylitic alteration zones from inner to outer of the mineralized porphyry bodies. The ages of ore-bearing quartz-monzonitic porphyry and its host andesite are obtained by using the zircon SIMS U-Pb dating method, with results of 218.3 ± 1.6 Ma (MSWD = 0.31, N = 15) and 218.5 ± 1.6 Ma (MSWD = 0.91, N = 16), respectively. Meanwhile, the molybdenite Re-Os dating yields a Re-Os isochronal age of 221.4 ± 2.3 Ma (MSWD = 0.54, N = 5) and a weighted mean age of 219.9 ± 0.7 Ma (MSWD = 0.88). They are quite in accordance with the zircon U-Pb ages within errors. Furthermore, all of them are contemporary with the timing of the Garzê-Litang oceanic crust subduction in the Yidun arc. Therefore, the Xuejiping deposit could be formed in a continental margin setting. There are negative ɛNd(t) values ranging from -3.8 to -2.1 and relatively high initial 87Sr/86Sr ratios from 0.7051 to 0.7059 for the Xuejiping porphyries and host andesites. The (206Pb/204Pb)t, (207Pb/204Pb)t and (208Pb/204Pb)t values of the Xuejiping porphyries and host andesites vary from 17.899 to 18.654, from 15.529 to 15.626, and from 37.864 to 38.52, respectively, indicative of high radiogenic Pb isotopic features. In situ Hf isotopic analyses on zircons by using LA-MC-ICP-MS exhibit that there are quite uniform and slightly positive ɛHf(t) values ranging from -0.2 to +3.2 (mostly between 0 and +2), corresponding to relatively young single-stage Hf model ages from 735 Ma to 871 Ma. These isotopic features suggest that the primary magmas of the Xuejiping porphyries and

  12. Triassic rift-related sedimentary basins in northern Chile (24° 29°S) (United States)

    Suarez, M.; Bell, C. M.


    Triassic rocks in northern Chile (latitude 24°-29°S) include marine and continental rift-related sedimentary deposits, associated with basaltic, andesitic, and silicic volcanic rocks. Five main successions include the deposits of two marine basins (Profeta and San Félix) separated by three continental basins (Cifuncho, La Ternera, and La Coipa). The marine strata include turbidites and debris flow deposits interpreted as coarse-grained fan-delta sediments. The continental sediments include lacustrine fan delta, open lake, braided river, alluvial fan, and sabkha deposits. The widespread fan-delta systems (both marine and lacustrine), together with abrupt lateral and vertical facies discontinuities and large-scale depositional cycles, are indicative of rift-controlled sedimentation. The associated magmatic activity indicates that this rifting was the product of subduction-related extension or strike-slip movement on the active plate margin. Triassic rifting was followed in Late Triassic to Early Jurassic times by widespread thermotectonic subsidence.

  13. Petrology and petrogenesis of the Eocene Volcanic rocks in Yildizeli area (Sivas), Central Anatolia, Turkey (United States)

    Doğa Topbay, C.; Karacık, Zekiye; Genç, S. Can; Göçmengil, Gönenç


    Yıldızeli region to the south of İzmir Ankara Erzincan suture zone is situated on the large Sivas Tertiary sedimentary basin. After the northern branch of the Neotethyan Ocean was northerly consumed beneath the Sakarya Continent, a continent - continent collision occurred between the Anatolide- Tauride platform and Pontides and followed a severe intermediate magmatism during the Late Cretaceous- Tertiary period. This created an east-west trending volcanic belt along the whole Pontide range. In the previous studies different models are suggested for the Eocene volcanic succession such as post-collisional, delamination and slab-breakoff models as well as the arc model for its westernmost parts. We will present our field and geochemical data obtained from the Yıldızeli and its surroundings for its petrogenesis, and will discuss the tectonic model(s) on the basis of their geochemical/petrological aspects. Cenozoic volcanic sequences of Yıldızeli region which is the main subject of this study, overlie Pre-Mesozoic crustal meta-sedimentary group of Kırşehir Massif, Ophiolitic mélange and Cretaceous- Paleocene? flysch-like sequences. In the northern part of Yıldızeli region, north vergent thrust fault trending E-W seperates the ophiolitic mélange complex from the Upper Cretaceous-Paleocene and Tertiary formations. Volcano-sedimentary units, Eocene in age, of the Yıldızeli (Sivas-Turkey) which are intercalated with sedimentary deposits related to the collision of Anatolide-Tauride and a simultaneous volcanic activity (i.e. the Yıldızeli volcanics), exposed throughout a wide zone along E-W orientation. Yıldızeli volcanics consist of basalts, basaltic-andesites and andesitic lavas intercalated flow breccias and epiclastic, pyroclastic deposits. Basaltic andesite lavas contain Ca-rich plagioclase + clinopyroxene ± olivine with minor amounts of opaque minerals in a matrix comprised of microlites and glass; andesitic lavas are generally contain Ca

  14. Achieving Mixtures of Ultra-High Performance Concrete

    Directory of Open Access Journals (Sweden)

    Mircea POPA


    Full Text Available Ultra-High Performance Concrete (UHPC is a relatively new concrete. According to [11] UHPC is that concrete which features compressive strength over C100/115 class. Up to this point standards for this type of concrete were not adopted, although its characteristic strength exceeds those specified in [33]. Its main property is high compressive strength. This provides the possibility of reducing the section of elements (beams or columns made of this type of concrete, while the load capacity remains high. The study consists in blending mixtures of UHPC made of varying proportions of materials. The authors have obtained strengths of up to 160 MPa. The materials used are: Portland cement, silica fume, quartz powder, steel fibers, superplasticiser, sand and crushed aggregate for concrete - andesite.

  15. A dynamical analysis of the seismic activity of Villarrica volcano (Chile) during September-October 2000

    Energy Technology Data Exchange (ETDEWEB)

    Tarraga, Marta [Departamento de Volcanologia. Museo Nacional de Ciencias Naturales, CSIC, Madrid (Spain)], E-mail:; Carniel, Roberto [Dipartimento di Georisorse e Territorio, Universita di Udine, Via Cotonificio 114, 33100 Udine (Italy)], E-mail:; Ortiz, Ramon; Garcia, Alicia [Departamento de Volcanologia. Museo Nacional de Ciencias Naturales, CSIC, Madrid (Spain); Moreno, Hugo [Observatorio Volcanologico de los Andes del Sur (OVDAS), Servicio Nacional de Geologia y Mineria de Chile (SERNAGEOMIN), Temuco, IX Region (Chile)


    Although Villarrica volcano in Chile is one of the most active in the southern Andes, the literature studying its seismic activity is relatively scarce. An interesting problem recently tackled is the possibility for a regional tectonic event to trigger a change in the volcanic activity of this basaltic to basaltic-andesitic volcano, which is in turn reflected in the time evolution of the properly volcanic seismicity, especially in the form of a continuous volcanic tremor. In this work, we conduct a spectral, dynamical and statistical analysis of the tremor recorded during September and October 2000, in order to characterize the anomalous behaviour of the volcano following a tectonic event recorded on 20th September 2000. The observed dynamical transitions are compared with remote sensing and visual observations describing the changes in the eruptive style of the volcano.

  16. The post-Laramide clastic deposits of the Sierra de Guanajuato: Compositional implications on the tectono-sedimentary and paleographic evolution

    Directory of Open Access Journals (Sweden)

    R. Miranda-Avilés


    Full Text Available This article presents the results of the study on sedimentation, sedimentary environments, tectono-sedimentary and paleogeographic evolution of post-Laramide clastic deposits and pre-volcanism of the Sierra Madre Occidental in the Sierra de Guanajuato, central Mexico. The Eocene Duarte Conglomerate and Guanajuato Conglomerate were deposited in the middle and distal parts of alluvial fans. The studied rocks are composed of limestone clasts, granite, andesite, metasediments, diorite, and pyroxenite, indicating the erosion of uplifted blocks of the basal complex of the Sierra de Guanajuato (Arperos basin. The petrographic and compositional analysis of limestone shows a textural variation from basin limestones and shallow platform limestones. The shallow platform limestone contain bivalves, brachiopods, gastropods, echinoderms and benthic foraminifera from the Berriasian-Valanginian. The shallow-water limestone corresponds to the boundary of the Arperos basin whose original outcrops currently not outcrop in the Sierra de Guanajuato.

  17. Net Acid Production, Acid Neutralizing Capacity, and Associated Mineralogical and Geochemical Characteristics of Animas River Watershed Igneous Rocks Near Silverton, Colorado (United States)

    Yager, Douglas B.; Choate, LaDonna; Stanton, Mark R.


    This report presents results from laboratory and field studies involving the net acid production (NAP), acid neutralizing capacity (ANC), and magnetic mineralogy of 27 samples collected in altered volcanic terrain in the upper Animas River watershed near Silverton, Colo., during the summer of 2005. Sampling focused mainly on the volumetrically important, Tertiary-age volcanic and plutonic rocks that host base- and precious-metal mineralization in the study area. These rocks were analyzed to determine their potential for neutralization of acid-rock drainage. Rocks in the study area have been subjected to a regional propylitic alteration event, which introduced calcite, chlorite (clinochlore), and epidote that have varying amounts and rates of acid neutralizing capacity (ANC). Locally, hydrothermal alteration has consumed any ANC and introduced minerals, mainly pyrite, that have a high net acid production (NAP). Laboratory studies included hydrogen pyroxide (H2O2) acid digestion and subsequent sodium hydroxide (NaOH) titration to determine NAP, and sulfuric acid (H2SO4) acid titration experiments to determine ANC. In addition to these environmental rock-property determinations, mineralogical, chemical, and petrographic characteristics of each sample were determined through semiquantitative X-ray diffractometry (Rietveld method), optical mineralogy, wavelength dispersive X-ray fluorescence, total carbon-carbonate, and inductively coupled plasma?mass spectrometric analysis. An ANC ranking was assigned to rock samples based on calculated ANC quantity in kilograms/ton (kg/t) calcium carbonate equivalent and ratios of ANC to NAP. Results show that talus near the southeast Silverton caldera margin, composed of andesite clasts of the Burns Member of the Silverton Volcanics, has the highest ANC (>100 kg/t calcium carbonate equivalent) with little to no NAP. The other units found to have moderate to high ANC include (a) andesite lavas and volcaniclastic rocks of the San Juan

  18. Petrographic and geochemical characterization of the Triassic and Jurassic magmatic and volcanic rocks of southeastern Ecuador (United States)

    Villares, Fabián; Eguez, Arturo; Yanez, Ernesto


    Formely, the subandean zone in the southeastern Ecuador involved large volcanic and magmatic rocks included in the Misahualli Formation and Zamora batholith, both as expression of the Jurassic cal-alcaline volcanic arc. The aim of the project carried out by the INIGEMM (Instituto Nacional de Investigación Geológico Minero Metalúrgico) was discriminate the volcanic products including a continuous set going from basalts to ryolithes and volcanoclastic rocks. Geochemical characterization was done using representative 16 whole - rock chemical analysis. The oldest rocks of the investigated area called Pachicutza Unit, include greenish to black, massive basalts and basaltic andesites, locally showing pillows structures. The texture is aphanitic to microporphyritic with slight crystal growth of plagioclase and pyroxenes. The Unit include also local pyroclastic breccias and tuffs showing variable skarnification related to the intrusion of the jurassic Zamora Batholith. Two samples of basalts show tholeiitic affinity, corresponding to an N- MORB, probably representing an early stage in opening of a regional Triassic rift reported since Colombia to Peru in the Andes. These geochemical characteristics are similar to the amphibolites of Monte Olivo Unit in the Real Cordillera. The Jurassic large volcanic assembly of the Misahualli Formation was also differenciated. Basal volcanics include green, subporphyritic andesites and volcanic breccias possibly generated at an early stage of the volcanic arc, caused by a change of extensive to compressive regime. Continental volcano sedimentary and sedimentary rock were discriminate as Nueva Esperanza and Suarez Units, respectively. The volcanosedimentary sequence include massive to laminate tuffs and tuffites of intermediate composition. The sediments of the Suarez Unit include dominant conglomerats and sandstones of fluvial domain. The regional volcanic sequence is completed by the Las Peñas Unit that includes aphanitic to

  19. New Insights Into Volcanic Hazards in Western Mexico: Multiple Cone-Building Episodes at Arc Stratovolcanoes Revealed by 40Ar/39Ar Geochronology (United States)

    Frey, H. M.; Lewis-Kenedi, K.; Lange, R. A.; Hall, C. M.; Delgado-Granados, H.


    The detailed eruptive histories of two andesitic stratocones, Volcáns Ceboruco and Tequila, in the western Mexican arc have been documented using 40Ar/39Ar geochronology. The volumes of these volcanoes were obtained with mapping, airphotos, and digital elevation models. The age and volume data constrain the rate and duration of major cone-building events, which bears on the longevity of the underlying upper-crustal magma chambers that fed the eruptions. The results indicate that at each stratovolcano there were two discrete cone-building events, separated by a hiatus. At V. Tequila, six samples from the edifice yielded dates (196 +/- 8, 196 +/- 19, 178 +/- 8, 191 +/- 13, 216 +/- 11, and 198 +/- 11 ka; errors are 1 sigma) with a mean eruption age of 196 +/- 12 ka. Thus the bulk of the main edifice ( ˜31 km3) erupted within 24 kyrs (at the 2 sigma level), leading to a cone-building rate of > 1.3 km3/kyr. After a hiatus of ˜110 kyrs, ˜14 km3 of andesite erupted along the NW and SE flanks of V. Tequila at 90 +/- 19 ka. The last activity at V. Tequila produced a ˜2 km3 parasitic cone at ˜60 ka. Since an eruption has not occurred in the last 60 kyrs, V. Tequila is often considered an extinct volcano. This may be the view held by the > 75,000 inhabitants of the town of Tequila located on the northern flanks. A similar history of two discrete cone-building events is found at V. Ceboruco, ˜75 km to the NW. Seven samples taken from various parts of the edifice, including the inner caldera wall, indicate an initial cone-building event at ˜45 ka in which ˜37 km3 of andesite erupted. After a hiatus of nearly 44 kyrs, a second eruptive period began ˜1000 years ago. The first eruption to occur after the hiatus was Plinian and released 3-4 km3 of dacite. In the last 1 kyr, 9.5 km3 of andesite and dacite erupted effusively, culminating in the historic 1870 flow. The sobering conclusion, in terms of volcanic hazards assessment, is that the only Plinian eruption to occur

  20. A Late Proterozoic Early Paleozoic magmatic cycle in Sierra de la Ventana, Argentina (United States)

    Gregori, D. A.; López, V. L.; Grecco, L. E.


    Late Proterozoic-Early Paleozoic intrusive and volcanic rocks of Sierra de la Ventana can be grouped into two magmatic assemblages: the Meyer and Cochenleufú suites. The older (700-570 Ma) is composed of S-type quartz-monzodiorites, synogranites, and monzogranites associated with andesites and rhyolites and related to volcanic-arc and postcollisional settings. The younger (540-470 Ma) corresponds to highly fractionated homogeneous A-type monzogranites, linked to final plutonic events during postorogenic extension in collisional belts. Strong similarities between Sierra de la Ventana magmatic rocks and the S- and A-type granites of the Cape granite suite in South Africa allow positive correlation. In both areas, primitive volcanic arcs or collisional orogens are recognized. Continuous transpressional shearing between the Swartland and Tygerberg terranes in the Saldania belt may have triggered the generation and emplacement of both suites.

  1. Age and composition of granulite xenoliths from Paso de Indios, Chubut province, Argentina (United States)

    Castro, Antonio; Aragón, Eugenio; Díaz-Alvarado, Juan; Blanco, Idael; García-Casco, Antonio; Vogt, Katharina; Liu, D.-Y.


    Granulite xenoliths enclosed in Paleogene alkali basalts from the locality of Paso de Indios in The Argentinean Patagonia, have been studied for petrology, geochemistry and U-Pb SHRIMP zircon geochronology. These are lower crust xenoliths composed of pyroxene and plagioclase dominantly. Symplectitic overgrowths with olivine and new pyroxene-plagioclase formation around the large pyroxene crystals are common. The study of phase equilibrium yields a decompression path from pressure 0.9 GPa at temperatures of about 1000 °C. The major element composition does not correspond with any known basaltic or andesitic magmas. They have SiO 2 residual origin of the granulites. In situ age determination with SHRIMP yields a Concordia age of 175.9 ± 4.9 Ma with MSWD = 1.4. This age represent the time of complex lithosphere evolution in relation with the formation of this residual crust.

  2. A Neoarchean subduction recorded by the Eastern Hebei Precambrian basement, North China Craton: Geochemical fingerprints from metavolcanic rocks of the Saheqiao-Shangying-Qinglong supracrustal belt (United States)

    Guo, Rongrong; Liu, Shuwen; Bai, Xiang; Wang, Wei


    The Saheqiao-Shangying-Qinglong supracrustal belt (SSQB) in the northern Eastern Hebei Precambrian basement (EHPB) is located in the northern margin of the Eastern Block (EB) of the North China Craton (NCC). The Shangying terrane constitutes the middle segment of the SSQB and contains primarily metamorphic volcanics and plutonic tonalitic gneisses. The metamorphic volcanics mainly consist of pyroxene plagioclase amphibolites, garnet plagioclase amphibolites, biotite plagioclase amphibole gneisses, and amphibole plagioclase gneisses. Zircon U-Pb-Lu-Hf isotopic analyses reveal that the metavolcanic rocks from the Shangying terrane crystallized at ∼2506-2613 Ma with TDM (Hf) values of ∼2541-2944 Ma. These metamorphic volcanic rocks are subdivided into four groups based on their lithological and chemical features. Group I consists chiefly of tholeiites that are characterized by slightly light rare earth element (LREE) depleted patterns and flat multi-element spider diagrams, which are similar to back-arc basin basalt (BABB)-like rocks and were derived from the partial melting of the depleted mantle. The tholeiites in Group II have slightly fractionated rare earth element (REE) patterns without Nb anomalies, exhibit an affinity to Nb-enriched basalt (NEB)-like rocks, and were produced by the partial melting of HFSE-enriched mantle peridotites. Group III is composed of slightly LREE-enriched tholeiites with negative Nb-Ta anomalies that resemble island arc tholeiites. Group IV comprises calc-alkaline basalts and andesites with highly enriched LREEs and evident Nb, Ta and Ti depletions that are geochemically similar to the products of island arcs. The island arc tholeiites and calc-alkaline basalt-andesites originated from the partial melting of sub-arc mantle peridotites that were previously metasomatized by slab-derived fluids/melts with the fractional crystallization of ferromagnesian minerals. Collectively, the BABB-like rocks, the NEBs, arc tholeiites and calc

  3. Petrogenesis and its significance to continental dynamics of the Neogene high-potassium calc-alkaline volcanic rock association from north Qiangtang, Tibetan Plateau

    Institute of Scientific and Technical Information of China (English)

    赖绍聪; 刘池阳; S.Y.O’Reilly


    Detailed studies indicate that the main rock type of the Neogene high-potassium calc-alkaline volcanic rock association from north Qiangtang is andesite, dacite and rhyolite. They belong to typical crust-generation magmatic system and originate from the special thickened crust of the Tibetan Plateau by dehydration melting. This group of rocks exhibits LREE enrichment but no remarkable Eu anomaly that shows their source region should be a thickened deep crust consisting of eclogitic mass group, implying that the crust had been thickened and an eclogitic deep crust had been formed during the Neogene period in Qiangtang area. This understanding is important and significant to making further discussion on the uplift mechanism and continental dynamics of the Tibetan Plateau.

  4. Volcanic Ash fall Impact on Vegetation, Colima 2005 (United States)

    Garcia, M. G.; Martin, A.; Fonseca, R.; Nieto, A.; Radillo, R.; Armienta, M.


    An ash sampling network was established arround Colima Volcano in 2005. Ash fall was sampled on the North, Northeast, East, Southeast, South, Southwest and West of the volcano. Samples were analyzed for ash components, geochemistry and leachates. Ash fall ocurred on April (12), May (10, 23), June (2, 6, 9, 10, 12, 14), July (27), September (27), October (23) and November (24). Most of the ash is made of andesitic dome-lithics but shows diferences in crystal, juvenile material and lithic content. In May, some samples contained grey and dark pumice (scoria). Texture varies from phi >4 to phi 0. Leachate concentration were low: SO4 (7.33-54.19) Cl- (2.29-4.97) and F- (0.16-0.37). During 2005, Colima Volcano's ash fall rotted some of the guava and peach fruits and had a drying effect on spearment and epazote plants. Even these small ash amounts could have hindered sugar cane and agave growth.

  5. Petrologic, tectonic, and metallogenic evolution of the Ancestral Cascades magmatic arc, Washington, Oregon, and northern California (United States)

    du Bray, Edward A.; John, David A.


    Present-day High Cascades arc magmatism was preceded by ~40 m.y. of nearly cospatial magmatism represented by the ancestral Cascades arc in Washington, Oregon, and northernmost California (United States). Time-space-composition relations for the ancestral Cascades arc have been synthesized from a recent compilation of more than 4000 geochemical analyses and associated age data. Neither the composition nor distribution of ancestral Cascades magmatism was uniform along the length of the ancestral arc through time. Initial (>40 to 36 Ma) ancestral Cascades magmatism (mostly basalt and basaltic andesite) was focused at the north end of the arc between the present-day locations of Mount Rainier and the Columbia River. From 35 to 18 Ma, initial basaltic andesite and andesite magmatism evolved to include dacite and rhyolite; magmatic activity became more voluminous and extended along most of the arc. Between 17 and 8 Ma, magmatism was focused along the part of the arc coincident with the northern two-thirds of Oregon and returned to more mafic compositions. Subsequent ancestral Cascades magmatism was dominated by basaltic andesite to basalt prior to the post–4 Ma onset of High Cascades magmatism. Transitional tholeiitic to calc-alkaline compositions dominated early (before 40 to ca. 25 Ma) ancestral Cascades eruptive products, whereas the majority of the younger arc rocks have a calc-alkaline affinity. Tholeiitic compositions characteristic of the oldest ancestral arc magmas suggest development associated with thin, immature crust and slab window processes, whereas the younger, calc-alkaline magmas suggest interaction with thicker, more evolved crust and more conventional subduction-related magmatic processes. Presumed changes in subducted slab dip through time also correlate with fundamental magma composition variation. The predominance of mafic compositions during latest ancestral arc magmatism and throughout the history of modern High Cascades magmatism probably

  6. Upper Paleozoic mafic and intermediate volcanic rocks of the Mount Pleasant caldera associated with the Sn-W deposit in southwestern New Brunswick (Canada): Petrogenesis and metallogenic implications (United States)

    Dostal, Jaroslav; Jutras, Pierre


    Upper Paleozoic ( 365 Ma) mafic and intermediate volcanic rocks of the Piskahegan Group constitute a subordinate part of the Mount Pleasant caldera, which is associated with a significant polymetallic deposit (tungsten-molybdenum-bismuth zones 33 Mt ore with 0.21% W, 0.1% Mo and 0.08% Bi and tin-indium zones 4.8 Mt with 0.82% Sn and 129 g/t In) in southwestern New Brunswick (Canada). The epicontinental caldera complex formed during the opening of the late Paleozoic Maritimes Basin in the northern Appalachians. The mafic and intermediate rocks make up two compositionally distinct associations. The first association includes evolved rift-related continental tholeiitic basalts, and the second association comprises calc-alkaline andesites, although both associations were emplaced penecontemporaneously. The basalts have low Mg# 0.34-0.40, smooth chondrite-normalized REE patterns with (La/Yb)n 5-6, primitive mantle-normalized trace element patterns without noticeable negative Nb-Ta anomalies, and their ɛNd(T) ranges from + 2.5 to + 2.2. The basalts were generated by partial melting of a transition zone between spinel and garnet mantle peridotite at a depth of 70-90 km. The calc-alkaline andesites of the second association have chondrite-normalized REE patterns that are more fractionated, with (La/Yb)n 7-8.5, but without significant negative Eu anomalies. Compared to the basaltic rocks, they have lower ɛNd(T) values, ranging from + 0.5 to + 1.9, and their mantle-normalized trace element plots show negative Nb-Ta anomalies. The ɛNd(T) values display negative correlations with indicators of crustal contamination, such as Th/La, Th/Nb and SiO2. The andesitic rocks are interpreted to have formed by assimilation-fractional crystallization processes, which resulted in the contamination of a precursor basaltic magma with crustal material. The parent basaltic magma for both suites underwent a different evolution. The tholeiitic basalts experienced shallow-seated fractional

  7. Ultramafic rocks in the Namurian C series in the Zebrzydowice area (Rybnik coal region)

    Energy Technology Data Exchange (ETDEWEB)

    Jochemczyk, L.


    The chemical and physical properties as well as origin of ultramafic rock samples from the Zebrzydowice area in the Rybnik coal region are evaluated. The ultramafic rocks detected by drilling were situated at depths of 1035 m in the top of dacite-andesite system and thermally alterated claystones. Chemical analyses and X-ray examination show that the ultramafic rock consists of secondarily alterated peridotite. The peridotite consists of chlorite-serpentite, phlogopite, bastite, nepheline and opaque minerals. Its chemical composition is characterized by reduced content of silica and a high content of ferric oxide. The ultramafic rock in the Zebrzydowice area differs from mineral and chemical composition of igneous rocks which occur in Carboniferous strata in the west and the southwest of the Upper Silesia basin. Rock of this type has been recorded in the Upper Silesia basin for the first time. 12 references.

  8. Stratigraphic implications of Sinian-Early Cambrian volcanic ash beds on the Yangtze Platform

    Institute of Scientific and Technical Information of China (English)

    ZHANG Junming; ZHU Maoyan; YANG Aihua; LI Guoxiang; YANG Jinghong; Christoph HEUBECK


    Volcanic ash beds from shallow- to deep-water facies strata of the Sinian-Early Cambrian (Meishucunian) on the Yangtze Platform consist of bentonites and tuffites which are readily recognized in the field by their physical features and confirmed by geochemical analyses.Geochemistry suggests that the volcanic ash beds in Meishucunian time are rhyolite and rhyodacite while those in the Qiongzhusian and Sinian are andesite and trachyandesite.The ash beds in the time-equivalent strata, even in different areas display rather similar geochemical features, whereas the ash beds in different strata even in the same areas show large chemical difference.The results suggest that these ash beds can be used for intra- and extra-basinal correlations of the Sinian-Early Cambrian interval on the Yangtze Platform.Additionally, these ash beds suggest high potentials for further U-Pb dating strategies.

  9. Petrogenesis of Volcanic Rocks in the Khabr-Marvast Tectonized Ophiolite: Evidence for Subduction Processes in the South-Western Margin of Central Iranian Microcontinent

    Institute of Scientific and Technical Information of China (English)



    The Late Cretaceous Khabr-Marvast tectonized ophiolite is located in the middle part of the Nain-Baft ophiolite belt, at the south-western edge of the central Iranian microcontinent. Although all the volcanic rocks in the study area indicate subduction-related magmatism (e.g. high LILE (large ion lithophile elements)/ HFSE (high field strenght elements) ratios and negative anomalies in Nb and Ta), geological and geochemical data clearly distinguish two distinct groups of volcanic rocks in the tectonized association: (1) group 1 is comprised of hyaloclustic breccias, basaltic pillow iavas, and andesite sheet flows. These rocks represent the Nain-Baft oceanic crust; and (2) group 2 is alkaline iavas from the top section of the ophiolite suite. These lavas show shoshonite affinity, but do not support the propensity of ophiolite.

  10. The cervantes lava flow geomorfology, irazú volcano (costa rica): description of the central america`s greater lava flow field


    Guillermo E. Alvarado; Vega, Ana E.


    The Cervantes lava flow field, on the southeastern flank of Irazú volcano, is the most recent and large effusive event dated at this volcano. The Cervantes lava flow actually consists of two different bi-modal lava flow fields. The Western composite lava field (10.85 km2, 0.18 ± 0.1 km3) has a basaltic (SiO2: 50.71-52.06%; MgO: 8.13- 9.50%) and basaltic andesite composition due to magma mixing (SiO2: 52.90-53.42%; MgO: 6.71-7.12%) and is older in age (57 ka ± 13 ka years B.P.). The Eastern co...

  11. Robust 24 ± 6 ka 40Ar/39Ar age of a low-potassium tholeiitic basalt in the Lassen region of NE California (United States)

    Turrin, Brent D.; Muffler, L. J. Patrick; Clynne, Michael A.; Champion, Duane E.


    40Ar/39Ar ages on the Hat Creek Basalt (HCB) and stratigraphically related lava flows show that latest Pleistocene tholeiitic basalt with very low K2O can be dated reliably. The HCB underlies ∼ 15 ka glacial gravel and overlies four andesite and basaltic andesite lava flows that yield 40Ar/39Ar ages of 38 ± 7 ka (Cinder Butte; 1.65% K2O), 46 ± 7 ka (Sugarloaf Peak; 1.85% K2O), 67 ± 4 ka (Little Potato Butte; 1.42% K2O) and 77 ± 11 ka (Potato Butte; 1.62% K2O). Given these firm age brackets, we then dated the HCB directly. One sample (0.19% K2O) clearly failed the criteria for plateau-age interpretation, but the inverse isochron age of 26 ± 6 ka is seductively appealing. A second sample (0.17% K2O) yielded concordant plateau, integrated (total fusion), and inverse isochron ages of 26 ± 18, 30 ± 20 and 24 ± 6 ka, all within the time bracket determined by stratigraphic relations; the inverse isochron age of 24 ± 6 ka is preferred. As with all isotopically determined ages, confidence in the results is significantly enhanced when additional constraints imposed by other isotopic ages within a stratigraphic context are taken into account.

  12. Geochemical studies of rocks, water, and gases at Mt. Hood, Oregon

    Energy Technology Data Exchange (ETDEWEB)

    Wollenberg, H.A.; Bowen, R.E.; Bowman, H.R.; Strisower, B.


    Mr. Hood, a composite andesitic volcano, located near Portland, Oregon, is one of several large eruptive centers which dominate the Cascade Mountains of the western United States. As part of a program of geologic, geophysical and geochemical studies to examine Mt. Hood's geothermal resource potential, samples of warm-and cold-spring water, water from a geothermal test well in Old Maid Flat, fumarolic gases, and rocks were collected and analyzed for major chemical constituents and trace elements. The only warm-spring area on Mt. Hood is Swim Springs, located on the south flank. Orifices at Swim were sampled repeatedly with little overall change noted in water chemistry between summer and winter. Oxygen and hydrogen isotope data and mixing calculations based on analyses of Swim Springs and numerous cold springs, indicate that a large component of the warm water at Swim is from near-surface runoff. Chemical geothermometry suggests that temperatures at depth in the Swim Springs system are within the range 104 to 170/sup 0/C; the temperature of unmixed hot water may exceed 200/sup 0/C. Higher-than-background chloride contents and specific conductances of cold springs on the south flank of the mountain suggest that there is a small component of thermal water in these sources. A geothermal model of Mt. Hood is proposed wherein snow- and glacier-melt water near the summit comes in close promimity to the hot central neck of the mountain, manifested by the summit-crater fumaroles.Iridium was detected in warm and cold spring waters and in a sample of altered andesite.

  13. Igneous rocks identification on well-log data; Classificacao de rochas igneas em perfis eletricos

    Energy Technology Data Exchange (ETDEWEB)

    Souza-Lima, Wagner [PETROBRAS S.A., Salvador, BA (Brazil). Unidade de Negocio de Exploracao e Producao de Sergipe e Alagoas. Ativo de Exploracao], E-mail:; Pinho, Gustavo de Carvalho; Silva, Patricia Martins; Paraizo, Paulo Lopes Brandao


    An attempt to discriminate and characterise igneous rocks on well-log data is made in a well drilled on the Cabo Sub-basin (JG-1 well, Sergipe- Alagoas Basin), situated on the northeastern coast of Brazil. Log data from the twelve drilled igneous intervals were analysed on RHOBxPHIN and DTxGRxResistivity cross plots. Similar diagrams were constructed for igneous data from the 1-CPE-1-PE well, drilled on the same basin, and with igneous data from other Brazilian basins. At the RHOBxPHIN cross plot, twelve lithologic fields were discriminated, and their characteristics verified against petrographic data. Two trends are perceptible: the basic rocks set (olivine-basalt, andesite, basaltic pumice and basaltic andesite) distributed along the dolomite line, and the acid rocks set (trachyandesite/quartz-latite, trachyandesite, trachyte, olivine-trachyandesite and acid pumice) coincident with the calcite line. At the DTxGRxResistivity cross plot, the basic set occurs around low-GR field, and the acid set is distributed around high-GR field. The JG-1 well's log data were submitted to discriminant analysis, and the results were checked against the CPE-1 well's curves, for validation. For the first well, the hits ranged from 82 and 100%. For the second well, a perfect lithologic identification was obtained, except for those cases where the lithotypes does not exist in the JG-1 well. One of the main applications for this technique is the stratigraphic correlation for the volcanic successions from sedimentary basins, mainly in the absence of good biostratigraphic markers. (author)

  14. Orthopyroxene-enrichment in the lherzolite-websterite xenolith suite from Paleogene alkali basalts of the Poiana Ruscă Mountains (Romania

    Directory of Open Access Journals (Sweden)

    Nédli Zsuzsanna


    Full Text Available In this paper we present the petrography and geochemistry of a recently collected lherzolite-websterite xenolith series and of clinopyroxene xenocrysts, hosted in Upper Cretaceous–Paleogene basanites of Poiana Ruscă (Romania, whose xenoliths show notable orthopyroxene-enrichment. In the series a slightly deformed porphyroclastic-equigranular textured series could represent the early mantle characteristics, and in many cases notable orthopyroxene growth and poikilitic texture formation was observed. The most abundant mantle lithology, Type A xenoliths have high Al and Na-contents but low mg# of the pyroxenes and low cr# of spinel suggesting a low degree (< 10 % of mafic melt removal. They are also generally poor in overall REE-s (rare earth elements and have flat REY (rare earth elements+ Y patterns with slight LREE-depletion. The geochemistry of the Type A xenoliths and calculated melt composition in equilibrium with the xenolith clinopyroxenes suggests that the percolating melt causing the poikilitization can be linked to a mafic, Al-Na-rich, volatile-poor melt and show similarity with the Late Cretaceous–Paleogene (66–72 Ma subduction-related andesitic magmatism of Poiana Ruscă. Type B xenoliths, with their slightly different chemistry, suggest that, after the ancient depletion, the mantle went through a slight metasomatic event. A subsequent passage of mafic melts in the mantle, with similar compositions to the older andesitic magmatism of Poiana Ruscă, is recorded in the pyroxenites (Fe-rich xenoliths, whereas the megacrysts seem to be cogenetic with the host basanite. The Poiana Ruscă xenoliths differ from the orthopyroxene-enriched mantle xenoliths described previously from the Carpathian-Pannonian Region and from the Dacia block.

  15. Stratigraphy of Reforma Caldera, Baja California Sur, Mexico (United States)

    García Sánchez, L.; Macias, J. L.; Osorio, L. S.; Pola, A.; Avellán, D. R.; Arce, J. L.; Saucedo, R.; Sánchez, J. M.; García-Tenorio, F.; Cisneros, G.; Reyes-Agustín, G.; Cardona, S.; Jimenez, A.


    The Reforma caldera is located at ~35 km to the northwest of Santa Rosalía in the central part of the Baja California peninsula. It has 10 km in diameter and a maximum height of 1200 masl in the center and between 100 and 500 masl in its slopes. Reforma is within a tectonic zone affected by two fault systems: A NW-SE normal fault system linked to the opening of the Gulf of California, and a NNW-SSE and NW-SE strike-slip fault system associated with an active Riedel system. Reforma was built upon Cretaceous granites that outcrop at the caldera center, Miocene to Pliocene volcano-sedimentary rocks of the Comondú group, and Miocene marine sediments of the Santa Rosalía basin. On top of these rocks outcrop at least four submarine to subaerial ignimbrites interbedded with marine fossiliferous beds and the lower Pleistocene deposits associated to the Reforma caldera. These deposits are formed by a ignimbrite that shifts to different lithofacies that change gradually their welding, here dubbed basal, transitional, intermediate, and upper (all of then enriched in black fiammes), followed by a pumice-rich, white fiammes, and vitrophyre lithofacies, which are distributed around the 9 km wide caldera and have been associated to the caldera formation episode. Deposits related to post-caldera volcanism are andesite-basaltic lava flows erupted along the caldera rim through localized feeding dikes and andesitic and rhyolitic domes, and scoria cinder cones exposed inside and outside the caldera. On top of these deposits rest the middle Pleistocene Aguajito caldera deposits.

  16. Early Cretaceous bimodal volcanic rocks in the southern Lhasa terrane, south Tibet: Age, petrogenesis and tectonic implications (United States)

    Wang, Chao; Ding, Lin; Liu, Zhi-Chao; Zhang, Li-Yun; Yue, Ya-Hui


    Limited geochronological and geochemical data from Early Cretaceous igneous rocks of the Gangdese Belt have resulted in a dispute regarding the subduction history of Neo-Tethyan Ocean. To approach this issue, we performed detailed in-situ zircon U-Pb and Hf isotopic, whole-rock elemental and Sr-Nd isotopic analyses on Late Mesozoic volcanic rocks exposed in the Liqiongda area, southern Lhasa terrane. These volcanic rocks are calc-alkaline series, dominated by basalts, basaltic andesites, and subordinate rhyolites, with a bimodal suite. The LA-ICPMS zircon U-Pb dating results of the basaltic andesites and rhyolites indicate that these volcanic rocks erupted during the Early Cretaceous (137-130 Ma). The basaltic rocks are high-alumina (average > 17 wt.%), enriched in large ion lithophile elements (LILEs) and light rare earth elements (LREEs), and depleted in high field strength elements (HFSEs), showing subduction-related characteristics. They display highly positive zircon εHf(t) values (+ 10.0 to + 16.3) and whole-rock εNd(t) values (+ 5.38 to + 7.47). The silicic suite is characterized by low Al2O3 (extracted from a source metasomatized by slab-derived components for the petrogenesis of mafic rocks, whereas the subsequent mafic magma underplating triggered partial melting of the juvenile crust to generate acidic magma. Our results confirm the presence of Early Cretaceous volcanism in the southern Lhasa terrane. Combined with the distribution of the contemporary magmatism, deformation style, and sedimentary characteristics in the Lhasa terrane, we favor the suggestion that the Neo-Tethyan oceanic lithosphere was flat-lying beneath the Lhasa terrane during the Early Cretaceous.

  17. Mineral chemistry of paleoproterozoic volcano-plutonism from the São Félix do Xingu (PA region, Amazonian Craton

    Directory of Open Access Journals (Sweden)

    Raquel Souza da Cruz


    Full Text Available The Sobreiro and Santa Rosa formations are result of large paleoproterozoic volcanic activities in the São Félix do Xingu (PA region, SE of Amazonian Craton. The Sobreiro Formation is composed of andesitic lava flow facies, with subordinate dacite and rhyodacite, and autoclastic volcaniclastic facies characterized by tuff, lapilli-tuff, and massive polymictic breccia. These rocks exhibit clinopyroxene, amphibole, and plagioclase phenocrysts in a microlytic or trachytic groundmass. The clinopyroxene is augite with subordinate diopside, and reveals chemical variations typical of minerals generated by arc-related magmatism. The amphibole is magnesiohastingsite, has oscillatory oxidizing conditions, and reveals breakdown rim textures linked to degassing during magma ascent. The Santa Rosa Formation has polyphase evolution controlled by large NE-SW crustal fissures, materialized by rhyolitic and dacitic lava flow facies. Volcaniclastic facies of ignimbrites, lapilli-tuffs, felsic crystal tuffs, and massive polymict breccias represents an explosive cycle in this unit. Metric dikes and stocks of granitic porphyries and equigranular granitoids complete this suite. K-feldspar, plagioclase, and quartz phenocrysts surrounded by quartz and K-feldspar integrowth occur in these rocks. Electron microprobe pressure and temperature estimates in clinopyroxene phenocrysts reveal formation depth between 58 and 17.5 km (17.5 – 4.5 kbar at temperatures between 1,249 and 1,082 ºC; and between 28 and 15 km (7.8 – 4.1 kbar for amphibole grains of the Sobreiro Formation, suggesting polybaric evolution. A model with generation of hydrated basaltic magma from partial melting of mantle wedge and accumulation in a hot zone of the lower crust, from which the andesitic and dacitic magmas are formed by the assimilation of continental crust and following fractional crystallization is proposed.

  18. Petrogenesis of Middle-Late Triassic volcanic rocks from the Gangdese belt, southern Lhasa terrane: Implications for early subduction of Neo-Tethyan oceanic lithosphere (United States)

    Wang, Chao; Ding, Lin; Zhang, Li-Yun; Kapp, Paul; Pullen, Alex; Yue, Ya-Hui


    The Gangdese belt is dominantly composed of igneous rocks that formed during the northward subduction of Neo-Tethyan oceanic lithosphere beneath the Lhasa terrane and has played a crucial role in understanding the pre-collisional evolution of southern Tibet. This paper presents new geochronological and geochemical (whole-rock major and trace element and Sr-Nd and zircon Hf isotope) data for recently identified volcanic rocks exposed in Changguo area, southernmost part of the Lhasa terrane. Zircon U-Pb dating from six samples yields consistent ages of 237.1 ± 1.1 Ma to 211.7 ± 1.5 Ma for magma emplacement through volcanic eruption, showing the Middle-Late Triassic magmatic activity in the southernmost Gangdese Belt. The Changguo volcanic rocks are mainly composed of basaltic and andesitic rocks and exhibit LILE enrichment and HFSE depletion. They also exhibit relatively uniform Nd-Hf isotopic compositions (εNd(t) = + 5.20 to + 7.74 and εHf(t)zircon = + 10.2 to + 15.9). The basaltic magmas were likely sourced from partial melting of sub-arc mantle wedge that was metasomatized by not only the aqueous fluid derived from subducting altered oceanic crust but also hydrous melt derived from subducting seafloor sediments, and subsequently experienced fractional crystallization and juvenile crustal contamination during ascent. The andesitic magmas were generated by partial melting of mafic-ultramafic metasomes through melt/fluid-peridotite reaction at slab-mantle interface. Taking into account the temporal and spatial distribution of the Early Mesozoic magmatic rocks and regional detrital zircon data, we further propose that the northward subduction of Neo-Tethyan oceanic lithosphere beneath the Lhasa terrane commenced by Middle Triassic.

  19. Behaviour of major, minor and trace elements (including REEs during kaolinization processes at Zonouz deposit, northeast of Marand, East Azarbaidjan province

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    Vahideh Alipour


    Full Text Available The Zonouz kaolin deposit is located ~15 km northeast of Marand, East-Azarbaidjan province. Based on physical features in field investigations, such as color, five distinct kaolin types including (1 white, (2 lemon, (3 gray, (4 brown, and (5 yellow are distinguished in the deposit. Field evidence and petrographic studies indicate that the deposit is genetically close to trachy-andesite rocks. According to mineralogical data, the deposit contains quartz, kaolinite, montmorillonite, calcite, pyrophyllite, chlorite, muscovite-illite, dolomite, hematite, and anatase minerals. Geochemical data indicate that function of alteration processes on trachy-andesite rocks during development of Zonouz ore deposit was accompanied by leaching of elements such as Al, Na, K, Rb, Ba, V, Hf, Cu, Zr, Tm, Yb, and Lu, enrichment of elements such as U, Nb, and Ta, and leaching-fixation of elements such as Si, Fe, Ca, Mg, Ti, Mn, P, Cs, Sr, Th, Co, Cr, Ni, Y, Ga, LREE, Tb, Dy, Ho, and Er. Incorporation of obtained results from mineralogical and geochemical studies show that physico-chemical conditions of alteration environment, the relative stability of primary minerals, surface adsorption, preferential sorption by metallic oxides, existing of organic matters, scavenging and concentration processes, and fixation in neomorphic mineralogical phases played important role in distribution of elements in the deposit. Geochemical studies show that development of the deposit is relative to two types of processes, (1 hypogene and (2 supergene. The distribution pattern of REEs indicates that differentiation degree of LREEs from HREEs in supergene kaolins is more than hypogene kaolins. Geochemical studies indicate that minerals such as Mn-oxides, zircon, anatase, hematite, cerianite, and secondary phosphates (monazite, rhabdophane, churchite, and zenotime are the potential hosts for rare earth elements in this deposit.

  20. Geology and petrology of Tertiary volcanic rocks of Sarbisheh perlite mine area (eastern Iran and industrial applications

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    Seayad Sayid Mohammadi


    Full Text Available The study area is located at northwest of Sarbisheh in South Khorasan province and eastern border of Lut block. In this area, Tertiary (Eocene-Oligocene to Pliocene volcanic rocks consisting of basaltic andesite, dacite, rhyodacite, vitreous rhyolite (perlitic in some parts, tuff and ignimbrite are exposed. In the Daghar Mountain, A, B and C perlite layers with thicknesses of 102, 7 and 58 meters respectively, occur alternatively with volcanic-pyroclastic rocks. Zoning, sieve texture and embayment of plagioclase and roundness of minerals in the lavas indicate disequilibrium conditions during magma crystallization. Chemically, these are meta-aluminous, medium to high-K calc-alkaline, enriched in LILE and negative anomaly for Nb and Ti. Chondrite-normalized Rare Earth Elements (REE plots indicate enrichment of light REE in comparison with heavy REE, (La/YbN of 9.14-12.64, low negative anomaly for Eu in basaltic andesite (Eu/Eu*=0.91 and dacite (Eu/Eu*=0.78-0.87 and strong negative anomaly for Eu in the rhyolites (Eu/Eu*=0.18-0.35. Negative anomaly for Eu indicates calc-alkaline nature for these rocks. On the basis of chemical characteristics and magnetic susceptibility, these are I-type. Tectonically, the rocks belong to subduction zone and active continental margin and their parental magma originated from partial melting of enriched mantle and then crustal contamination during differentiation process. Dacites have an initial 87Sr/86Sr between 0.7048 and 0.7050 (average 0.7049 that confirm mantle source for the magma. Volcanic glasses of rhyolitic composition altered by hydration (likely meteoric water and formed perlite. Physical tests and chemical analyses show that perlite of Sarbisheh is suitable as raw material for production of expanded perlite.

  1. Cenozoic volcanic geology and probable age of inception of basin-range faulting in the southeasternmost Chocolate Mountains, California

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    Crowe, B.M.


    A complex sequence of Oligocene-age volcanic and volcaniclastic rocks form a major volcanic center in the Picacho area of the southeasternmost Chocolate Mountains, Imperial County, California. Basal-volcanic rocks consist of lava flows and flow breccia of trachybasalt, pyroxene rhyodacite, and pyroxene dacite (32 My old). These volcanic rocks locally overlie fanglomerate and rest unconformably on pre-Cenozoic basement rocks. South and southeast of a prominent arcuate fault zone in the central part of the area, the rhyolite ignimbrite (26 My old) forms a major ash-flow sheet. In the southwestern part of the Picacho area the rhyolite ignimbrite interfingers with and is overlain by dacite flows and laharic breccia. The rhyolite ignimbrite and the dacite of Picacho Peak are overlapped by lava flows and breccia of pyroxene andesite (25 My old) that locally rest on pre-Cenozoic basement rocks. The volcanic rocks of the Picacho area form a slightly bimodal volcanic suite consisting chiefly of silicic volcanic rocks with subordinate andesite. Late Miocene augite-olivine basalt is most similar in major-element abundances to transitional alkali-olivine basalt of the Basin and Range province. Normal separation faults in the Picacho area trend northwest and north parallel to major linear mountain ranges in the region. The areal distribution of the 26-My-old rhyolite ignimbrite and the local presence of megabreccia and fanglomerate flanking probable paleohighs suggest that the ignimbrite was erupted over irregular topography controlled by northwest- and north-trending probable basin-range faults. These relations date the inception of faulting in southeasternmost California at pre-26 and probably pre-32 My ago. A transition of basaltic volcanism in the area is dated at 13 My ago. 9 figures, 2 tables.

  2. Magmatic and tectonic evolution of the Ladakh Block from field studies (United States)

    Raz, U.; Honegger, K.


    The Ladakh Block is in an intermediate position between the Indian plate in the south and the Karakorum-Tibetan plate in the north. To the west it is separated from the Kohistan Arc by the Nanga Parbat Syntaxis, to the east it is cut off from the Lhasa Block by the Gartok-Nubra Fault. Present data, together with previously published results, show, that the Ladakh Block consists of an island arc in the south and a calc-alkaline batholith in the north with remnants of a continental crust. Migmatitic gneisses and metasedimentary sequences, such as quartzites and metapelites, interbedded with basaltic volcanics and overlain by thick platform carbonates were found as evidence of a continental crust. Remnants of megafossils ( Megalodon and Lithiotis) within the high-grade metamorphic marbles indicate a probable age of Late Triassic to Early Jurassic. These sediments were intruded by a faintly layered hornblende-gabbro, which preceded the calc-alkaline magmatic episode. Gabbro and gabbronorites are found as roof pendants and large inclusions within diorites and granodiorites. The major part of the batholith consists of granodiorite and biotite-granite plutons, ranging from Late Cretaceous to Tertiary. Associated with the intrusives are volcanic rocks with trachyandesite to alkalibasalt and basalt-andesite to rhyolite compositions. Garnet-bearing leucogranites succeeded the emplacement of the major plutons. The magmatic stage ended, finally, by intense fracturing and injections of NE-SW striking andesitic dykes. The southernmost unit of the Ladakh Block is formed by oceanic crust with serpentinized peridotite and hornblende-gabbro and is covered by volcanics of an island-arc type (Dras volcanics). These units are intruded by gabbronorite, as well as Middle and Upper Cretaceous granodiorite and coarse-grained biotite-granite. In a plate tectonic view the Ladakh Block represents a transitional sector between the pure island arc of Kohistan in the west and the Andean type

  3. Pan-African adakitic rocks of the north Arabian-Nubian Shield: petrological and geochemical constraints on the evolution of the Dokhan volcanics in the north Eastern Desert of Egypt (United States)

    Obeid, Mohamed A.; Azer, Mokhles K.


    The Precambrian basement of Egypt is part of the Red Sea Mountains and represents the north-western part of the Arabian-Nubian Shield (ANS). Five volcanic sections are exposed in the Egyptian basement complex, namely El Kharaza, Monqul, Abu Had, Mellaha and Abu Marwa. They are located in the north Eastern Desert (ED) of Egypt and were selected for petrological and geochemical studies as they represent the Dokhan volcanics. The volcanics divide into two main pulses, and each pulse was frequently accompanied by deposition of immature molasse type sediments, which represent a thick sequence of the Hammamat group in the north ED. Compositionally, the rocks form a continuum from basaltic andesite, andesite, dacite (lower succession) to rhyodacite and rhyolite (upper succession), with no apparent compositional gaps. These high-K calc-alkaline rocks have strong affinities to subduction-related rocks with enriched LILEs (Rb, Ba, K, Th, Ce) relative to high field strength elements (Nb, Zr, P, Ti) and negative Nb anomalies relative to NMORB. The lower succession displays geochemical characteristics of adakitic rocks with SiO2 >53 wt%, Al2O3 >15 wt%, MgO >2.5 wt%, Mg# >49, Sr >650 ppm, Y 25 ppm, Cr >50 ppm and Sr/Y >42.4. They also have low Nb, Rb and Zr compared to the coexisting calc-alkaline rhyodacites and rhyolites. The highly fractionated rhyolitic rocks have strong negative Eu anomalies and possess the geochemical characteristics of A-type suites. Trace element geochemical signatures indicate a magma source consistent with post-collisional suites that retain destructive plate signatures associated with subduction zones. The adakitic rocks in the northern ANS are generated through partial melting of delaminated mafic lower crust interacting with overlying mantle-derived magma. The Dokhan volcanics were likely generated by a combination of processes, including partial melting, crystal fractionation and assimilation.

  4. Late Cretaceous lithospheric extension in SE China: Constraints from volcanic rocks in Hainan Island (United States)

    Zhou, Yun; Liang, Xinquan; Kröner, Alfred; Cai, Yongfeng; Shao, Tongbin; Wen, Shunv; Jiang, Ying; Fu, Jiangang; Wang, Ce; Dong, Chaoge


    Petrological, geochemical and in-situ zircon U-Pb dating and Hf-isotope analyses have been carried out on a suite of basalt-andesite-rhyolite volcanic rocks exposed in the Liuluocun area, Hainan Island, SE China. Zircon analyses show that these volcanic rocks crystallized in the Early Cretaceous (ca. 102 Ma). The basalts are characterized by low MgO contents and mg-numbers but high rare earth element, high field strength element and large ion lithophile element contents and Nb-Ta negative anomalies. They have relatively uniform Sr-Nd isotope compositions with εNd(t) values of - 4.09 to - 3.63. The andesites show enrichment of high field strength element and rare earth element with negligible Eu anomalies. They have εNd(t) values of - 2.35 to - 3.88 and εHf(t) values of - 9.73 to - 1.13. The rhyolites have high K2O and SiO2 contents. They are characterized by prominent Eu, P and Ti negative anomalies and enrichment in large ion lithophile element, and show εHf(t) values of - 7.51 to + 0.47 and εNd(t) values of - 2.49 to - 2.69. Petrogenetic analysis indicates that the Liuluocun volcanic rocks were produced by incomplete reaction of the mantle wedge peridotite with felsic melts derived from partial melting of subducted sediment. All these characteristics, combined with geological observations, suggest that their formation was related to regional lithospheric extension in the South China Craton during the Early Cretaceous, which may have been caused by subduction of the Paleo-Pacific plate beneath the continental plate of China.

  5. Rare earth elements geochemistry in springs from Taftan geothermal area SE Iran (United States)

    Shakeri, Ata; Ghoreyshinia, Sayedkazem; Mehrabi, Behzad; Delavari, Morteza


    Concentrations of rare earth elements (REEs) were determined in springs and andesitic-dacitic rocks of Taftan geothermal field. Hydrochemical results of major ions indicate that thermal springs are Na-SO4-Cl and Ca-SO4-Cl types. Concentrations of REEs are in ranges of 10- 4 to 1.2 and 49 to ~ 62 times of chondrite for springwater and rock samples, respectively. The thermal (STS and TTS) and the cold (APS) springs with low pH values exhibit a very high REE contents (0.64 to 3.15 mg/l). Saturation index indicates that Fe and Al phases can control dissolved REE concentration in FTS and PF cold springs. The speciation of REE complexes indicates dominant presence of LnSO4+ and free ion in the Taftan thermal springs. In APS cold spring with pH ~ 4, fluoride complexes are dominate over the free ion and sulfate species, while in PF and FTS cold springs with pH 6.4 and 7, respectively, carbonate complexes (LnCO3+) are predominant species. Chondrite-normalized pattern for the low-pH waters show very distinctive gull-wing patterns, characteristic feature of acid-sulfate geothermal systems, and are similar to those of the host rocks. Chemical characteristics of rare earth elements in spring and volcanic rock samples indicate that REEs are originated from the andesitic-dacitic host rocks. Whole-rock-normalized REE patterns and petrographic evidences show that rare earth elements leached mainly from marginal alteration of minerals and matrix decomposition in volcanic rocks. In chondrite-normalized REE patterns, significant negative Eu anomaly in the cold springs compare to the thermal and acidic springs indicates that alteration of plagioclase is more intense in the later, corresponding to increasing in temperature and acidic state of reactant water.

  6. Geology of