Sample records for andesites

  1. Fusion of arkosic sand by intrusive andesite (United States)

    Bailey, Roy A.


    An andesite dike in the Valles Mountains of northern New Mexico has intruded and partly fused arkosic sediments for a distance of 50 feet from its contacts. The dike is semi-circular in form, has a maximum width of about 100 feet, and is about 500 feet long. Small associated arcuate dikes are arranged in spiral fashion around the main dike, suggesting that they were intruded along shear fractures similar to those described by Burbank (1941). The fused rocks surrounding the andesite dike are of three general types: 1) partly fused arkosic sand, 2) fused clay, and 3) hybrid rocks. The fused arkosic sand consists of relict detrital grains of quartz, orthoclose, and plagioclase, imbedded in colorless glass containing microlites of tridymite, cordierite, and magnetite. The relict quartz grains are corroded and embayed by glass; the orthoclase is sanidinized and partly fused; and the plagioclase is inverted to the high temperature form and is partly fused. The fused clay, which was originally a mixture of montmorillonite and hydromica, consists primarily of cordierite but also contains needle-like crystals of sillimanite (?) or mullite (?). The hybrid rocks originated in part by intermixing of fused arkosic sediments and andesitic liquid and in part by diffusion of mafic constituents through the fused sediments. They are rich in cordierite and magnetite and also contain hypersthene, augite, and plagioclase. The composition of pigeonite in the andesite indicates that the temperature of the andesite at the time of intrusion probably did not exceed 1200?C. Samples of arkosic sand were fused in the presence of water in a Morey bomb at 1050?C. Stability relations of certain minerals in the fused sand suggest that fusion may have taken place at a lower temperature, however, and the fluxing action of volatiles from the andesite are thought to have made this possible.

  2. Genesis of Cenozoic intraplate high Mg# andesites in Northeast China (United States)

    Liu, J. Q.; Chen, L. H.; Zhong, Y.; Wang, X. J.


    High-Mg# andesites (HMAs) are usually generated in the converged plate boundary and have genetic relationships with slab subduction. However, it still remained controversial about the origin of those HMAs erupted in the intra-plate setting. Here we present major, trace element, and Sr-Nd-Pb-Hf isotopic compositions for the Cenozoic intra-plate HMAs from Northeast China to constrain their origin and formation process. Cenozoic Xunke volcanic rocks are located in the northern Lesser Khingan Range, covering an area of about 3, 000 km2. These volcanic rocks are mainly basaltic andesite and basaltic trachyandesite, with only several classified as trachyandesite and andesites. They have high SiO2 contents (54.3-57.4 wt%) and Mg# (49.6-57.8), falling into the scope of high Mg# andesites. The Xunke HMAs are enriched in large ion lithophile elements but depleted in high field strength elements, with positive Ba, K, Sr and negative Zr-Hf, and Ti anomalies. Their trace element absolute concentrations are between those of potassic basalts and Wuchagou HMAs. The Xunke HMAs have relatively enriched Sr-Nd-Hf isotopes (87Sr/86Sr = 0.705398-0.705764, ɛNd=-8.8-3.8, ɛHf=0.5-11.7), and low radiogenic Pb isotopes (206Pb/204Pb = 16.701-17.198), towards to the EM1 end-member, which indicates that they are ultimately derived from ancient, recycled crustal components. Primitive silica-rich melts were generated from higher degrees of partial melting of recycled crustal materials (relative to potassic basalts) and then interacted with the peridotite to produce the Xunke HMAs.

  3. Complex investigation of thermo-technical parameters of Ruskov andesite

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    František Krepelka


    Full Text Available The research of thermo-technical parameters of Ruskov andesite was made as a part of the complex research of its properties as well as of rock disintegration by the action of chemical flame on the rock surface, i.e. thermal spalling in particular. Thermal spalling is a process in which thermal stresses are induced in the surface layer of rock whose surface is thereby disintegrated into small parts, the so called spalls, by the brittle manner. The evaluation of thermo-technical properties of the studied rocks is necessary for the qualification and quantification of the thermal spalling process. The measured and evaluated parameters were the coefficient of linear thermal expansion, the coefficient of thermal conductivity, the specific heat capacity and the coefficient of thermal diffusivity. Andesite from the Ruskov locality was chosen as a basic experimental material for the investigation of thermal spalling upon preliminary experiments. The estimated thermo-technical parameters were analyzed regarding the application of thermal spalling for the disintegration of the Ruskov andesite. The outcome as that the values of determine thermo-technical parameters established an expectation for its successful application.

  4. Andesite Petrogenesis in Nevado de Toluca Stratovolcano, Central Mexico (United States)

    Gomez-Tuena, A.; Capra, L.; Cai, Y.; Goldstein, S. L.


    A popular model for andesite petrogenesis in continental arcs involves a hydrous parental basalt that fractionates and probably assimilates continental crust during ascent. Nevertheless, andesites erupted from polygenetic volcanoes in the Trans-Mexican Volcanic Belt are not entirely consistent with this scenario because: (1) they display a shift to higher SiO2 contents at similar Mg# than true basalts, (2) they trend to lower HREE and HFSE contents with increasing SiO2, and (3) they often show correlated isotopic compositions with proxies for slab inputs but not with fractionation indexes. Young andesites from Toluca stratovolcano (1-0.042 Ma) also display modest adakite-like features (Sr/YToluca rock-suite revealed that some other andesites (2.6-1 Ma) also exhibit very strong negative Ce (Ce/Ce~0.25) anomalies, fractionated HREE patterns (Gd/Yb~4.2), as well as low Zr/Sm (~12.6), and Sr/Y (~12) ratios. These features are not easily explained by low or even high pressure differentiation from a common primitive magma, unless enormous quantities of fractionating accessory minerals are taken into account. And yet these geochemical signals are almost identical to those observed in the pelagic sedimentary horizon of the subducted Cocos plate sampled at DSDP site 487, and thus provide strong evidence for slab-derived sediment contributions to the petrogenesis of Toluca andesites. Since sediment transfer to the Toluca source must have occurred in the form of a silicate melt, the new evidence brings further support to the slab melting hypothesis in the Mexican subduction zone. Interestingly, Ce/Pb ratios of the Toluca rocks display a linear positive correlation with Pb isotopes, that departs from the pelagic sediment values, and extends to the enriched Pb isotopic compositions of intraplate-type volcanic rocks from the Chichinautzin volcanic field. Thus the Toluca rocks likely represent discrete slab-derived melts coming from different portions of the subducted slab that

  5. Magma heating by decompression-driven crystallization beneath andesite volcanoes. (United States)

    Blundy, Jon; Cashman, Kathy; Humphreys, Madeleine


    Explosive volcanic eruptions are driven by exsolution of H2O-rich vapour from silicic magma. Eruption dynamics involve a complex interplay between nucleation and growth of vapour bubbles and crystallization, generating highly nonlinear variation in the physical properties of magma as it ascends beneath a volcano. This makes explosive volcanism difficult to model and, ultimately, to predict. A key unknown is the temperature variation in magma rising through the sub-volcanic system, as it loses gas and crystallizes en route. Thermodynamic modelling of magma that degasses, but does not crystallize, indicates that both cooling and heating are possible. Hitherto it has not been possible to evaluate such alternatives because of the difficulty of tracking temperature variations in moving magma several kilometres below the surface. Here we extend recent work on glassy melt inclusions trapped in plagioclase crystals to develop a method for tracking pressure-temperature-crystallinity paths in magma beneath two active andesite volcanoes. We use dissolved H2O in melt inclusions to constrain the pressure of H2O at the time an inclusion became sealed, incompatible trace element concentrations to calculate the corresponding magma crystallinity and plagioclase-melt geothermometry to determine the temperature. These data are allied to ilmenite-magnetite geothermometry to show that the temperature of ascending magma increases by up to 100 degrees C, owing to the release of latent heat of crystallization. This heating can account for several common textural features of andesitic magmas, which might otherwise be erroneously attributed to pre-eruptive magma mixing.

  6. Studi Potensi Sumberdaya Andesit Menggunakan Metode Geolistrik Di Daerah Kokap, Kabupaten Kulonprogo, Daerah Istimewa Yogyakarta

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    Eko Bayu Purwasatriya


    Full Text Available The study of andesite resources was carried out in Hargowilis village, Kokap sub-district, Kulonprogo regency, Daerah Istimewa Yogyakarta province using geoelectrical data with Schlumberger configuration, as much as 14 point which is spreading on 8 hectares area. Based on regional geological map of Yogyakarta area, study area include on intrusive rock lithology’s unit compose of hipersten andesite to augite-hornblende andesite and trachiandesite. Geoelectrical method is one of geophysical method that used to observed geological condition in subsurface based on rock’s electrical properties. Andesite is one type of igneous rock which have contrast electrical properties with its surrounding rock, generally sedimentary rocks, makes it suitable for geoelectrical method to identify the presence of andesite in subsurface and also estimate its thickness to calculate the resources. Geoelectrical configuration used is 1D Schlumberger configuration where this method have advantage more accurate to calculate the thickness of rock layer especially in shallow area. The result of geoelectrical survey showing that it consist 2 layer of andesite, there are shallow layer and deep layer. This result indicate that the igneous rock in study area not only intrusion type, but also lava flow type. Resources potential of andesite both shallow and deep layer are 5,072,354 tons and resources potential of shallow andesite only is 3,162,566 tons.

  7. Fracture and compaction of andesite in a volcanic edifice. (United States)

    Heap, M J; Farquharson, J I; Baud, P; Lavallée, Y; Reuschlé, T

    The failure mode of lava-dilatant or compactant-depends on the physical attributes of the lava, primarily the porosity and pore size, and the conditions under which it deforms. The failure mode for edifice host rock has attendant implications for the structural stability of the edifice and the efficiency of the sidewall outgassing of the volcanic conduit. In this contribution, we present a systematic experimental study on the failure mode of edifice-forming andesitic rocks (porosity from 7 to 25 %) from Volcán de Colima, Mexico. The experiments show that, at shallow depths (1 km), while low-porosity (explosive potential of a volcano may therefore be subject to increase over time if the progressive compaction and permeability reduction in the lower edifice cannot be offset by the formation of permeable fracture pathways in the upper edifice. The mode of failure of the edifice host rock is therefore likely to be an important factor controlling lateral outgassing and thus eruption style (effusive versus explosive) at stratovolcanoes.

  8. Environmental and energy assessment of the use of Andesite in cement

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    Hamidi Moussa


    Full Text Available The present study is a contribution to the research of new sources of supply of additions and raw materials in order to valorize local materials in the manufacture of cement. It consists in checking the environmental validity of the industrial use of andesite by evaluating the energy consumption of manufacturing andesitic cement. This evaluation was made on CEMI 52.5R type cement mortars whose basic constituent is clinker, with substitution rates of raw and calcined andesitic rock at 800 °C varying from 0-40%. and this through mechanical performance tests at several deadlines (2 days, 7 days, 28 days and 90 days. The results show that the analysis of the influence on the environment of this addition, in its raw state or calcined at 800 ° C, made it possible to say that globally the impact of andesite on the matrices seems positive to long term. The replacement of the cement by andesite systematically induces a reduction in the energy required to produce one ton of binder, due to the lower energy demand for grinding than that required for the thermal treatment of the clinker. Overall, the energy cost of andesite cement (in kWh per MPa compressive strength is lower than that of ordinary cement for low rates of clinker replacement and obtaining cements with moderate strengths.

  9. A dearth of intermediate melts at subduction zone volcanoes and the petrogenesis of arc andesites. (United States)

    Reubi, Olivier; Blundy, Jon


    Andesites represent a large proportion of the magmas erupted at continental arc volcanoes and are regarded as a major component in the formation of continental crust. Andesite petrogenesis is therefore fundamental in terms of both volcanic hazard and differentiation of the Earth. Andesites typically contain a significant proportion of crystals showing disequilibrium petrographic characteristics indicative of mixing or mingling between silicic and mafic magmas, which fuels a long-standing debate regarding the significance of these processes in andesite petrogenesis and ultimately questions the abundance of true liquids with andesitic composition. Central to this debate is the distinction between liquids (or melts) and magmas, mixtures of liquids with crystals, which may or may not be co-genetic. With this distinction comes the realization that bulk-rock chemical analyses of petrologically complex andesites can lead to a blurred picture of the fundamental processes behind arc magmatism. Here we present an alternative view of andesite petrogenesis, based on a review of quenched glassy melt inclusions trapped in phenocrysts, whole-rock chemistry, and high-pressure and high-temperature experiments. We argue that true liquids of intermediate composition (59 to 66 wt% SiO(2)) are far less common in the sub-volcanic reservoirs of arc volcanoes than is suggested by the abundance of erupted magma within this compositional range. Effective mingling within upper crustal magmatic reservoirs obscures a compositional bimodality of melts ascending from the lower crust, and masks the fundamental role of silicic melts (>/=66 wt% SiO(2)) beneath intermediate arc volcanoes. This alternative view resolves several puzzling aspects of arc volcanism and provides important clues to the integration of plutonic and volcanic records.

  10. The anatomy of an andesite volcano: A time-stratigraphic study of andesite petrogenesis and crustal evolution at Ruapehu volcano, New Zealand

    DEFF Research Database (Denmark)

    Price, R.C.; Gamble, J.A.; Smith, I.E.M.


    Ruapehu, New Zealand’s largest active andesite volcano is located at the southern tip of the Taupo Volcanic Zone (TVZ), the main locus of subduction-related volcanism in the North Island. Geophysical data indicate that crustal thickness transitions from ... Ruapehu. The volcano is built on a basement of Mesozoic metagreywacke and geophysical evidence together with xenoliths contained in lavas indicates that this is underlain by oceanic, meta-igneous lower crust. The present-day Ruapehu edifice has been constructed by a series of eruptive events that produced...... and andesite. Dacite also occurs but only one basalt flow has been identified. There have been progressive changes in the minor and trace element chemistry and isotopic composition of Ruapehu eruptives over time. In comparison with rocks from younger formations, Te Herenga eruptives have lower K2O abundances...

  11. K-Ar age and chemical composition of basalt, andesite distributed in Shimabara peninsula

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    Nakata, Setsuya; Kamata, Hirotake


    Regarding the volcanic rocks genarated by eruption of volcanos in Shimabara Penisula, historical process of change of chemical compositions were studied. For determining the chemical compositions of basalt, andesite, X-ray fluorescence analysis was applied. By this result, distribution map of potassium and other microelements contained in the basalt and andesite was completed. It was considered that magma of similar composition were continuously kept supplied to north-western Kyushu including Shimabara Penisula since later Mesozoic era, that island arc type magma was generated at least 1.4 million years ago by the action of ocean plate, and that andesites were produced by mixing magma of hot spot type with that of island arc type. (3 figs, 2 tabs, 31 refs)

  12. The genetic relationship between andesites and dacites at Tungurahua volcano, Ecuador (United States)

    Nauret, F.; Samaniego, P.; Ancellin, M.-A.; Tournigand, P.-Y.; Le Pennec, J.-L.; Vlastelic, I.; Gannoun, A.; Hidalgo, S.; Schiano, P.


    Volcanic eruptions of intermediary and silica-rich magmas (andesites, dacites and rhyolites) in convergent arc settings generate voluminous and explosive eruptions that can strongly affect human activity and have significant environmental impacts. It is therefore crucial to understand how these magmas are generated in order to anticipate their potential impact. At convergent margins, primitive magmas (primitive basalts and/or andesites) are derived from the mantle wedge and they are progressively modified by physical and chemical processes operating between the melting zone and the surface to produce silica-rich magmas. In order to elucidate the relationship between andesites and dacites, we focus on Tungurahua volcano, located in the Ecuadorian Andes. We collected a set of samples comprising such lithologies that were erupted during the last 3000 year BP. This relatively short period of time allows us to assume that the geodynamic parameters remain constant. Petrology and major-trace element compositions of these lavas have already been examined, and so we performed a complementary Pb-Sr isotope study in order to determine the nature and origin of the components involved in andesite and dacite genesis. Sr isotopes range from 0.70417 to 0.70431, and Pb isotope compositions range from 18.889 to 19.154 for 206Pb/204Pb, from 15.658 to 15.696 for 207Pb/204Pb, and from 38.752 to 38.918 for 208Pb/204Pb. Dacites display a remarkably homogeneous Pb isotopic composition, with higher 206Pb/204Pb values for a given 207-208Pb/204Pb compared to andesites. Andesites show notable 207Pb/206Pb variations for a given SiO2 content, whereas dacites have lower and homogenous 207Pb/206Pb values. Andesite and dacite altogether plot in a roughly triangular distribution, with dacitic magmas systematically plotting at the high SiO2 and 87Sr/86Sr and low 207Pb/206Pb fields. Based on our new dataset, we show that at least 3 different components are required to explain the Tungurahua

  13. The material from Lampung as coarse aggregate to substitute andesite for concrete-making (United States)

    Amin, M.; Supriyatna, Y. I.; Sumardi, S.


    Andesite stone is usually used for split stone material in the concrete making. However, its availability is decreasing. Lampung province has natural resources that can be used for coarse aggregate materials to substitute andesite stone. These natural materials include limestone, feldspar stone, basalt, granite, and slags from iron processing waste. Therefore, a research on optimizing natural materials in Lampung to substitute andesite stone for concrete making is required. This research used laboratory experiment method. The research activities included making cubical object samples of 150 x 150 x 150 mm with material composition referring to a standard of K.200 and w/c 0.61. Concrete making by using varying types of aggregates (basalt, limestone, slag) and aggregate sizes (A = 5-15 mm, B = 15-25 mm, and 25-50 mm) was followed by compressive strength test. The results showed that the obtained optimal compressive strengths for basalt were 24.47 MPa for 50-150 mm aggregate sizes, 21.2 MPa for 15-25 mm aggregate sizes, and 20.7 MPa for 25-50 mm aggregate sizes. These results of basalt compressive strength values were higher than the same result for andesite (19.69 MPa for 50-150 mm aggregate sizes), slag (22.72 MPa for 50-150 mm aggregate sizes), and limestone (19.69 Mpa for 50-150 mm aggregate sizes). These results indicated that basalt, limestone, and slag aggregates were good enough to substitute andesite as materials for concrete making. Therefore, natural resources in Lampung can be optimized as construction materials in concrete making.

  14. Eruption cycles in a basaltic andesite system: insights from numerical modeling (United States)

    Smekens, J. F.; Clarke, A. B.; De'Michieli Vitturi, M.


    Persistently active explosive volcanoes are characterized by short explosive bursts, which often occur at periodic intervals numerous times per day, spanning years to decades. Many of these systems present relatively evolved compositions (andesite to rhyolite), and their cyclic activity has been the subject of extensive work (e.g., Soufriere Hills Volcano, Montserrat). However, the same periodic behavior can also be observed at open systems of more mafic compositions, such as Semeru in Indonesia or Karymsky in Kamchatka for example. In this work, we use DOMEFLOW, a 1D transient numerical model of magma ascent, to identify the conditions that lead to and control periodic eruptions in basaltic andesite systems, where the viscosity of the liquid phase can be drastically lower. Periodic behavior occurs for a very narrow range of conditions, for which the mass balance between magma flux and open-system gas escape repeatedly generates a viscous plug, pressurizes the magma beneath the plug, and then explosively disrupts it. The characteristic timescale and magnitude of the eruptive cycles are controlled by the overall viscosity of the magmatic mixture, with higher viscosities leading to longer cycles and lower flow rates at the top of the conduit. Cyclic eruptions in basaltic andesite systems are observed for higher crystal contents, smaller conduit radii, and over a wider range of chamber pressures than the andesitic system, all of which are the direct consequence of a decrease in viscosity of the melt phase, and in turn in the intensity of the viscous forces generated by the system. Results suggest that periodicity can exist in more mafic systems with relatively lower chamber pressures than andesite and rhyolite systems, and may explain why more mafic magmas sometimes remain active for decades.

  15. Sr isotope zoning in plagioclase from andesites at Cabo De Gata, Spai

    DEFF Research Database (Denmark)

    Waight, Tod Earle; Tørnqvist, Jakob


    Plagioclase crystals in andesites from the Cabo De Gata region show generally radiogenic Sr isotope compositions and consistent core to rim increases in 87Sr/86Sr that are indicative of open system processes in the lithosphere and crustal contamination during crystallization. High-grade metamorphic...... rocks of the Alpujárride and Nevado-Filábride complexes represent the most likely crustal contaminants. The plagioclases are characterized by subtly zoned and resorbed calcic cores (An73-86). These cores also have radiogenic 87Sr/86Sr (0.7127-0.7129), although less radiogenic than plagioclase rims......, groundmass plagioclase and whole rock compositions (up to 87Sr/86Sr = 0.7135). These cores are interpreted to represent early crystallization of plagioclase from hydrous melts emplaced into the lower crust. The parental melts to these andesites must therefore have already inherited their radiogenic Sr...


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    - Munaji


    Full Text Available Telah dilakukan penelitian untuk menentukan nilai resistivitas dan kedalaman batuan andesit di Desa Polosiri. Prinsip kerja metode geolistrik adalah mempelajari aliran listrik di dalam bumi dan cara mendeteksi di permukaan bumi. Metode tahanan jenis didasari oleh hukum Ohm, untuk mengetahui jenis lapisan batuan didasarkan pada distribusi nilai resistivitas pada tiap lapisan. Variasi harga tahanan jenis akan didapatkan jika jarak masing-masing elektroda diubah, sesuai konfigurasi alat yang dipakai (konfigurasi Schlumberger. Data hasil pengukuran di lapangan berupa beda potensial dan arus yang dapat digunakan untuk menghitung resistivitas semu. Penelitian ini dilakukan sebanyak tiga lintasan. Data hasil pengukuran diolah menggunakan software IPI2Win. Berdasarkan hasil penelitian diperoleh bahwa batuan andesit di Desa Polisiri memiliki resistivitas 212 Ωm – 300 Ωm dengan kedalaman 1.3 m - 1.86 m.

  17. Strontium isotope data for recent andesites in Ecuador and North Chile

    International Nuclear Information System (INIS)

    Francis, P.W.; Thorpe, R.S.; Moorbath, S.


    New Sr isotope data are presented for andesite lavas from active volcanoes in Ecuador and North Chile. Twenty-three samples from five Ecuadorian volcanoes have 87 Sr/ 86 Sr ratios most of which are essentially within analytical error, and average 0.7044. In contrast, 16 samples from the San Pedro-San Pablo volcano complex in North Chile have 87 Sr/ 86 Sr ratios between 0.7058 and 0.7072. These samples show no correlation between 87 Sr/ 86 Sr and 87 Rb/ 86 Sr, nor between 87 Sr/ 86 Sr and other elements or ratios. The major difference in setting between the two volcanic provinces lies in the thickness of the continental crust; 40-50 km beneath Ecuador, 70 km beneath North Chile. Andesites from both areas are derived primarily from the mantle, but those from North Chile show evidence of a significant Sr isotopic contribution from the continental crust. (Auth.)

  18. Persistent growth of a young andesite lava cone: Bagana volcano, Papua New Guinea (United States)

    Wadge, G.; McCormick Kilbride, B. T.; Edmonds, M.; Johnson, R. W.


    Bagana, an andesite lava cone on Bougainville Island, Papua New Guinea, is thought to be a very young central volcano. We have tested this idea by estimating the volumes of lava extruded over different time intervals (1-, 2-, 3-, 9-, 15-, 70-years) using digital elevation models (DEMs), mainly created from satellite data. Our results show that the long-term extrusion rate at Bagana, measured over years to decades, has remained at about 1.0 m3 s-1. We present models of the total edifice volume, and show that, if our measured extrusion rates are representative, the volcano could have been built in only 300 years. It could also possibly have been built at a slower rate during a longer, earlier period of growth. Six kilometres NNW of Bagana, an andesite-dacite volcano, Billy Mitchell, had a large, caldera-forming plinian eruption 437 years ago. We consider the possibility that, as a result of this eruption, the magma supply was diverted from Billy Mitchell to Bagana. It seems that Bagana is a rare example of a very youthful, polygenetic, andesite volcano. The characteristics of such a volcano, based on the example of Bagana, are: a preponderance of lava products over pyroclastic products, a high rate of lava extrusion maintained for decades, a very high rate of SO2 emission, evidence of magma batch fractionation and location in a trans-tensional setting at the end of an arc segment above a very steeply dipping and rapidly converging subduction zone.

  19. K-Ar age of bronzite-andesite from Choshi, Chiba Prefecture, Japan

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    Tatsumi, Yoshiyuki; Ishizaka, Kyoichi


    The authors have forwarded the study on the activity period of Setouchi volcanic rocks and the research on Sanukitoid which characterizes it. It was already mentioned that the activity period of Setouchi volcanic rocks is only the middle period of Mid-cainozoic era, and that Setouchi volcanic rocks can be treated as one rock region. In this paper, the K-Ar age of bronzite-andesite in Choshi, Chiba Prefecture, is reported, which the authors think as the eastern end of Setouchi volcanic rock region. The outline of the geological features in the vicinity of Choshi is explained. The rock samples for the measurement were collected in May, 1978, in the reconstruction site of the fishing port. The rock samples were fresh, and the effects of degeneration, wathering and others were not observed. The K-Ar age of these bronzite-andesite was determined by Teledyne Isotopes Co. in commission. The determination of K and Ar was carried out on all rock samples twice respectively. The isotopic age of the bronzite-andesite in Choshi was 11.8 +- 0.6 m.y., and it was produced by the volcanic activity in the middle period of Mid-cainozoic era, same as the volcanic rocks of Setouchi. It is considered that the eastern end of Setouchi volcanic rock region is Choshi according to the results of chemical properties and isotopic age. (Kako, I.)

  20. Melting of hydrous upper mantle and possible generation of andesitic magma: an approach from synthetic systems

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    Kushiro, I


    Phase equilibria in a portion of the system forsterite--plagioclase (An/sub 50/Ab/sub 50/ by weight)--silica--H/sub 2/O have been determined at 15 kbar pressure under H/sub 2/O-saturated conditions. The composition of the liquid pertinent to the piercing point forsterite + enstatite solid solution + amphibole + liquid + vapor is similar to that of calc-alkaline andesite. The electron microprobe analysis of the glass coexisting with the above three crystalline phases is very close to that of the piercing point determined by phase assemblage observations; however, the glass near (less than 8 forsterite crystals is significantly depleted in the normative forsterite component. With the addition of 10 wt. percent KAlSi/sub 3/O/sub 8/, the composition of this piercing point becomes even closer to the compositions of calc-alkaline andesites. It is also shown that the liquid coexisting with forsterite and enstatite solid solution remains silica-rich (60 to 62 wt. percent) over a wide (approximately 100/sup 0/C) temperature range. The present experimental studies support the view that liquids similar in composition to calc-alkaline andesites can be generated by direct partial melting of hydrous upper mantle at least at or near 15 kbar.

  1. Isotopic composition of strontium in three basalt-andesite centers along the Lesser Antilles arc (United States)

    Hedge, C.E.; Lewis, J.F.


    Si87/Sr86 ratios have been determined for lavas and py lastic rocks from three basalt-andesite centers along the Lesser Antilles arc-Mt. Misery on the island of St. Kitts, Soufriere on the island of St. Vincent, and Carriacou, an island of The Grenadines. The average Si87/Sr86 content of these rocks is 0.7038 for Mt. Misery, 0.7041 for Soufriere, and 0.7053 for Carriacou. All the Sr87/Sr86 values from each center are the same within analytical uncertainty (??0.0002). The constancy of strontium isotopic data within each center supports the hypothesis that basalts and andesites for each specific center investigated are generated from the same source - in agreement with petrographic and major- and minor-element data. Strontium isotopic compositions and elemental concentrations, particularly of strontium and nickel, indicate that this source was mantle peridotite and that the relationship between the respective basalts and andesites is probably fractional crystallization. ?? 1971 Springer-Verlag.

  2. Manupulation of microstructure, phase evolution and mechanical properties by devitrification of andesite for use as proppant (United States)

    Koseski, Ryan P.

    Small, roughly spherical ceramic particles, approximately 1mm in size are used for a number of applications including casting sands, catalysts, and cement fillers. The oil and natural gas industry utilizes such materials in tonnage quantities yearly as extraction aids. Particles intended for this application are referred to as proppants. Proppants are composed of materials that differ by density, strength and cost, and are selected on a site by site basis. Recently, competing usage and depletion of reserves of one of the most popular category of proppant materials, sintered aluminosilicates (e.g. kaolinite, bauxite) have driven the need for alternative raw materials for proppant manufacturing. Andesite, a by-product of mining operations in the south-west United States was identified as an abundant, readily available, and low cost alternative proppant material that can be fused and net-shaped into a glass which when crystallized results in microstructures which may offer substantial toughening and fracture characteristics which may serve to their advantage for use as proppants that do not decrease the permeability ("blind") the particle bed. This study addressed the devitrification behavior and its role on the mechanical properties of andesite-based glass-ceramic spheres for use as proppants. Timetemperature- transformation studies were performed to evaluate the devitrification behavior of andesite glass. Crystalline phase evolution and microstructural development were evaluated using quantitative x-ray diffraction, scanning electron microscopy, differential thermal analysis, and spectrophotometry. The andesite glass devitrification commenced with the precipitation of iron oxides (magnetite) which served as seeds for the epitaxial growth of dendritic pyroxenes. Mechanical properties, such as diametral compressive strength, fracture toughness, hardness, and fracture morphology were correlated with crystalline phase evolution. Selected heat treatments resulting in the

  3. In-situ observations of bubble growth in basaltic, andesitic and rhyodacitic melts (United States)

    Masotta, M.; Ni, H.; Keppler, H.


    Bubble growth strongly affects the physical properties of degassing magmas and their eruption dynamics. Natural samples and products from quench experiments provide only a snapshot of the final state of volatile exsolution, leaving the processes occurring during its early stages unconstrained. In order to fill this gap, we present in-situ high-temperature observations of bubble growth in magmas of different compositions (basalt, andesite and rhyodacite) at 1100 to 1240 °C and 1 bar, obtained using a moissanite cell apparatus. The data show that nucleation occurs at very small degrees of supersaturaturation (bubbles occurring simultaneously with the nucleation of crystals. During the early stages of exsolution, melt degassing is the driving mechanism of bubble growth, with coalescence becoming increasingly important as exsolution progresses. Ostwald ripening occurs only at the end of the process and only in basaltic melt. The average bubble growth rate (GR) ranges from 3.4*10-6 to 5.2*10-7 mm/s, with basalt and andesite showing faster growth rates than rhyodacite. The bubble number density (NB) at nucleation ranges from 1.8*108 to 7.9*107 cm-3 and decreases exponentially over time. While the rhyodacite melt maintained a well-sorted bubble-size distribution (BSD) through time, the BSD's of basalt and andesite are much more inhomogeneous. Our experimental observations demonstrate that bubble growth cannot be ascribed to a single mechanism but is rather a combination of many processes, which depend on the physical properties of the melt. Depending on coalescence rate, annealing of bubbles following a single nucleation event can produce complex bubble size distributions. In natural samples, such BSD's may be misinterpreted as resulting from several separate nucleation events. Incipient crystallization upon cooling of a magma may allow bubble nucleation already at very small degrees of supersaturation and could therefore be an important trigger for volatile release and

  4. Elution behavior into the high pressured hot water and the organizational change of granite and andesite

    Energy Technology Data Exchange (ETDEWEB)

    Matsunaga, Isao; Miyazaki, Akira; Yamaguchi, Tsutomu; kuriyakawa, Michio


    In the development of a high temperature rock system, the interaction between the rock and hot water which occurs in a reservoir provides big effects. The decline of the strength and the increase of the permeability are caused by the elusion of the rock on the surface of the hydraulic fracture and the redeposition of the eluded material also causes to narrow or close the channel. However, studies concerning the organizational change of the rock by the hot water or the material change associated with the organizational change are small in number. In this research, Inaba granite and Honkomatsu andesite were treated in heat with an autoclave in order to investigate the organizational changes of the rocks and at the same time, the elusion behavior of the rocks into the hot water was investigated by examining chemical components which were eluded into the fluid and the components remaining on the rock surface. The decreased amount per specific surface area due to the autoclave treatment is the order of 10/sup -3/(gcm/sup -2/) for both rocks and changeable depending upon the heating temperature and the kind of rock. As a result of the analysis of the fluids in the autoclave after the heat treatment, the Si concentration of Honkomatsu andesite was higher in the same temperature and the heating time. (2 figs, 3 tabs, 6 refs)

  5. Thermal properties of andesite from Popocatepetl and Volcán de Colima, México. (United States)

    Cardenas-Sanchez, Enrique; De la Cruz-Reina, Servando; Varley, Nick


    The thermal conductivity (K), specific heat (Cp) and the coefficient of heat transfer surface (H) are the basic parameters to describe the process of cooling a volcanic rock fragment released in an explosive event. The analysis of the cooling process by conduction, convection and radiation of heat in volcanic rock fragments, has been limited to basalts, and various minerals such as olivine, pyroxene, quartz, etc. (Miao & Chen, 2014; Branlund & Hofmeister, 2012; Romine et al, 2012;. Schön, 2011; Stroberg et al, 2010;. Schatz & Simmons, 1972). There are no detailed studies on the thermal properties of the andesites, abundant in continental stratovolcanoes, and particularly susceptible from lava domes with frequent destruction processes, such as Popocatepetl and Volcan de Colima. Previously, we developed an algorithm for calculation of the grain-size distribution, degree of fragmentation, the thermal energy released and its possible correlation with Volcanic Explosive Index (VEI) from the cooling curves of fragments from vulcanian and strombolian explosions. These curves were obtained from sequences of time over incandescent deposits recorded at selected pixel thermal images of vulcanian activity in the Popocatepetl and Volcan de Colima, Mexico. However, the model was limited by the lack of thermal parameters of the andesites, forcing a first approximation using basalts data. We present a simple model for the cooling process using andesites samples from Popocatépetl and Volcan de Colima. First, the samples were subjected to a rounding process to minimize surface effects. Then, heated to 800 ° C were extracted from the muffle and cooling rate is measured. The thermal conductivity and coefficient of surface heat are determined using a thermal camera and three thermocouples embedded at various depths within the sample. An inversion method was implemented to determine the thermal properties parameters , by comparing the observed data regarding cooling model for a solid

  6. In situ observations of bubble growth in basaltic, andesitic and rhyodacitic melts (United States)

    Masotta, M.; Ni, H.; Keppler, H.


    Bubble growth strongly affects the physical properties of degassing magmas and their eruption dynamics. Natural samples and products from quench experiments provide only a snapshot of the final state of volatile exsolution, leaving the processes occurring during its early stages unconstrained. In order to fill this gap, we present in situ high-temperature observations of bubble growth in magmas of different compositions (basalt, andesite and rhyodacite) at 1,100 to 1,240 °C and 0.1 MPa (1 bar), obtained using a moissanite cell apparatus. The data show that nucleation occurs at very small degrees of supersaturaturation (bubbles occurring simultaneously with the nucleation of crystals. During the early stages of exsolution, melt degassing is the driving mechanism of bubble growth, with coalescence becoming increasingly important as exsolution progresses. Ostwald ripening occurs only at the end of the process and only in basaltic melt. The average bubble growth rate ( G R) ranges from 3.4 × 10-6 to 5.2 × 10-7 mm/s, with basalt and andesite showing faster growth rates than rhyodacite. The bubble number density ( N B) at nucleation ranges from 7.9 × 104 mm-3 to 1.8 × 105 mm-3 and decreases exponentially over time. While the rhyodacite melt maintained a well-sorted bubble size distribution (BSD) through time, the BSDs of basalt and andesite are much more inhomogeneous. Our experimental observations demonstrate that bubble growth cannot be ascribed to a single mechanism but is rather a combination of many processes, which depend on the physical properties of the melt. Depending on coalescence rate, annealing of bubbles following a single nucleation event can produce complex bubble size distributions. In natural samples, such BSDs may be misinterpreted as resulting from several separate nucleation events. Incipient crystallization upon cooling of a magma may allow bubble nucleation already at very small degrees of supersaturation and could therefore be an important

  7. The statitistical evaluation of the uniaxial compressive strength of the Ruskov andesite

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    Krepelka František


    Full Text Available The selection of a suitable model of the statistical distribution of the uniaxial compressive strength is discussed in the paper. The uniaxial compressive strength was studied on 180 specimens of the Ruskov andesite. The rate of loading was 1MPa.s-1. The experimental specimens had a prismatic form with a square base; the slightness ratio of specimens was 2:1. Three sets of specimens with a different length of the base edge were studied, namely 50, 30 and 10 mm. The result of the measurement were three sets with 60 values of the uniaxial compressive strength. The basic statistical parameters: the sample mean, the sample standard deviation, the variational interval, the minimum and maximum value, the sample obliqueness coefficient and the sharpness coefficient were evaluated for each collection. Two types of the distribution which can be joined with the real physical fundamentals of the desintegration of rocks ( the normal and the Weibull distribution were tested. The two-parametric Weibull distribution was tested. The basic characteristics of both distributions were evaluated for each set and the accordance of the model distribution with an experimental distribution was tested. The ÷2-test was used for testing. The two-parametric Weibull distribution was selected following the comparison of the test results of both model distributions as a suitable distribution model for the characterization of uniaxial compressive strength of the Ruskov andesite. The two-parametric Weibull distribution showed better results of the goodness-of-fit test. The normal distribution was suitable for two sets; one of the sets showed a negative result of the goodness-of-fit testing. At the uniaxial compressive strength of the Ruskov andesite, a scale effect was registered : the mean value of uniaxial compressive strength decreases with increasing the specimen base edge. This is another argument for using the Weibull distribution as a suitable statistical model of the

  8. Silica-enriched mantle sources of subalkaline picrite-boninite-andesite island arc magmas (United States)

    Bénard, A.; Arculus, R. J.; Nebel, O.; Ionov, D. A.; McAlpine, S. R. B.


    compositions extracted from these hybrid sources are higher in normative quartz and hypersthene (i.e., they have a more silica-saturated character) in comparison with basalts derived from prior melt-depleted asthenospheric mantle beneath ridges. These primary arc melts range from silica-rich picrite to boninite and high-Mg basaltic andesite along a residual spinel harzburgite cotectic. Silica enrichment in the mantle sources of arc-related, subalkaline picrite-boninite-andesite suites coupled with the amount of water and depth of melting, are important for the formation of medium-Fe ('calc-alkaline') andesite-dacite-rhyolite suites, key lithologies forming the continental crust.

  9. Paleoproterozoic andesitic volcanism in the southern Amazonian craton (northern Brazil); lithofacies analysis and geodynamic setting (United States)

    Roverato, Matteo; Juliani, Caetano; Capra, Lucia; Dias Fernandes, Carlos Marcelo


    Precambrian volcanism played an important role in geological evolution and formation of new crust. Most of the literature on Precambrian volcanic rocks describes settings belonging to subaqueous volcanic systems. This is likely because subaerial volcanic rocks in Proterozoic and Archean volcano-sedimentary succession are poorly preserved due to erosive/weathering processes. The late Paleoproterozoic Sobreiro Formation (SF) here described, seems to be one of the rare exceptions to the rule and deserves particular attention. SF represents the subaerial expression of an andesitic magmatism that, linked with the upper felsic Santa Rosa F., composes the Uatumã Group. Uatumã Group is an extensive magmatic event located in the Xingú region, southwestern of Pará state, Amazonian Craton (northern Brazil). The Sobreiro volcanism is thought to be related to an ocean-continent convergent margin. It is characterized by ~1880 Ma well-preserved calc-alkaline basaltic/andesitic to andesitic lava flows, pyroclastic rocks and associated reworked successions. The superb preservation of its rock-textures allowed us to describe in detail a large variety of volcaniclastic deposits. We divided them into primary and secondary, depending if they result from a direct volcanic activity (pyroclastic) or reworked processes. Our study reinforces the importance of ancient volcanic arcs and rocks contribution to the terrestrial volcaniclastic sedimentation and evolution of plate tectonics. The volcanic activity that produced pyroclastic rocks influenced the amount of detritus shed into sedimentary basins and played a major role in the control of sedimentary dispersal patterns. This study aims to provide, for the first time, an analysis of the physical volcanic processes for the subaerial SF, based in field observation, lithofacies analysis, thin section petrography and less geochemical data. The modern volcanological approach here used can serve as a model about the evolution of Precambrian

  10. Sulfur isotope fractionation between fluid and andesitic melt: An experimental study (United States)

    Fiege, Adrian; Holtz, François; Shimizu, Nobumichi; Mandeville, Charles W.; Behrens, Harald; Knipping, Jaayke L.


    Glasses produced from decompression experiments conducted by Fiege et al. (2014a) were used to investigate the fractionation of sulfur isotopes between fluid and andesitic melt upon magma degassing. Starting materials were synthetic glasses with a composition close to a Krakatau dacitic andesite. The glasses contained 4.55–7.95 wt% H2O, ∼140 to 2700 ppm sulfur (S), and 0–1000 ppm chlorine (Cl). The experiments were carried out in internally heated pressure vessels (IHPV) at 1030 °C and oxygen fugacities (fO2) ranging from QFM+0.8 log units up to QFM+4.2 log units (QFM: quartz–fayalite–magnetite buffer). The decompression experiments were conducted by releasing pressure (P) continuously from ∼400 MPa to final P of 150, 100, 70 and 30 MPa. The decompression rate (r) ranged from 0.01 to 0.17 MPa/s. The samples were annealed for 0–72 h (annealing time, tA) at the final P and quenched rapidly from 1030 °C to room temperature (T).The decompression led to the formation of a S-bearing aqueous fluid phase due to the relatively large fluid–melt partitioning coefficients of S. Secondary ion mass spectrometry (SIMS) was used to determine the isotopic composition of the glasses before and after decompression. Mass balance calculations were applied to estimate the gas–melt S isotope fractionation factor αg-m.No detectable effect of r and tA on αg-m was observed. However, SIMS data revealed a remarkable increase of αg-m from ∼0.9985 ± 0.0007 at >QFM+3 to ∼1.0042 ± 0.0042 at ∼QFM+1. Noteworthy, the isotopic fractionation at reducing conditions was about an order of magnitude larger than predicted by previous works. Based on our experimental results and on previous findings for S speciation in fluid and silicate melt a new model predicting the effect of fO2 on αg-m (or Δ34Sg–m) in andesitic systems at 1030 °C is proposed. Our experimental results as well as our modeling are of high importance for the interpretation of S isotope

  11. Sorption Behavior of Cu(II From Acidic SolutionUsing Weathered Basalt Andesite Products

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    Rajesh Singh


    Full Text Available Wastewater discharged from electroplating industry pose a serioushazard due to their heavy metal load. The objective of this work is to evaluatethe removal of Cu(II from acidic solution by sorption onto Weathered BasaltAndesite Products (WBAP. WBAP has been characterized and utilized forremoval of copper from aqueous solution over wide range of initial metal ionconcentration (25 mg/L to 500 mg/L, contact duration (0-8 h, sorbent dose(5-35 g/L, pH (1.0 to 6.0, and temperature (276 K to 333 K. The sorptionpattern of Cu ions onto WBAP followed Langmuir, Freundlich, and Dubinin-Kaganer-Radushkevich isotherms. The thermodynamic parameters (∆H0, ∆S0,and ∆G0 for Cu sorption onto WBAP were also determined.

  12. Measurements of the Activity of dissolved H2O in an Andesite Melt (United States)

    Moore, G. M.; Touran, J. P.; Pu, X.; Kelley, K. A.; Cottrell, E.; Ghiorso, M. S.


    The large effect of dissolved H2O on the physical and chemical nature of silicate melts, and its role in driving volcanism, is well known and underscores the importance of this volatile component. A complete understanding of the chemical behavior of dissolved H2O in silicate melts requires the quantification of its thermodynamic activity as a function of pressure, temperature, and melt composition, particularly at low H2O contents (i.e. at under-saturated conditions). Knowledge of the activity of H2O in silicate melts at H2O-undersaturated conditions will improve our understanding of hydrous phase equilibria, as well as our models of physical melt properties. Measurement of the activity of any silicate melt component, much less that of a volatile component such as H2O, is a difficult experimental task however. By using a modified double capsule design (Matjuschkin et al, 2015) to control oxygen fugacity in piston cylinder experiments, along with high precision X-ray absorption techniques (XANES) to measure iron oxidation state in silicate glasses (Cottrell et al, 2009), we are able to constrain the H2O activity in silicate melts at under-saturated conditions. Preliminary results on an andesite melt with low H2O content (3 wt%) have been shown (Moore et al, 2016) to match predicted H2O activity values calculated using the H2O equation of state of Duan and Zhang (1996) and the H2O solubility model of Ghiorso and Gualda (2015). More recent results on the same andesite melt containing approximately 5 wt% H2O however show a large negative deviation from the predicted values. Reversal experiments involving an oxidized starting material are ongoing, as well as further characterization of the samples to detect the presence of possible contaminants that would induce reduction of the melt beyond that related to the H2O activity (e.g. graphite contamination).

  13. The glaciovolcanic evolution of an andesitic edifice, South Crater, Tongariro volcano, New Zealand (United States)

    Cole, R. P.; White, J. D. L.; Conway, C. E.; Leonard, G. S.; Townsend, D. B.; Pure, L. R.


    Unusual deposits, mapped and logged in detail, around the summit area of Tongariro volcano, Tongariro Volcanic Centre, New Zealand indicate that the construction and evolution of a substantial portion of this andesitic stratovolcano was beneath a significant ice cap or summit glacier. As the edifice was built under and through the overlying ice, the style of volcanism evolved in a complex history of growth. Initially, a ≥ 100 m thick, widespread hyaloclastite deposit was emplaced within a subglacial, eruption-formed meltwater lake. This was followed by several phases of effusive and explosive eruptions, producing lava flows and primary volcaniclastic deposits emplaced along channels carved into the ice by heated meltwater. The clastic deposits contain quenched bombs and structural features that indicate waterlain transport and emplacement, and soft sediment deformation. Such accumulation of water on a steep-sided edifice without evidence for a subaerial crater lake, along with lava flow features indicating confinement, suggest that a substantial summit glacier was responsible for the production and retention of water, and the architecture of these deposits. Recent studies at nearby Ruapehu volcano have provided good evidence for glaciovolcanic interactions during the last glacial period. However, until now, little was known of the physical lava-ice interactions in the Centre during the last interglacial period and the earlier part of the last glacial period (110-64 ka). These new data support a reinterpretation for the volcanic evolution of the older Tongariro edifice and the emplacement mechanisms of primary volcaniclastic deposits. They also help to constrain local ice thicknesses and extents at the times of eruption. In addition, this study contributes to a sparse global catalogue of glaciovolcanic deposits of andesitic composition, particularly of primary volcaniclastics preserved at mid-latitude stratovolcanoes. The variety of deposit types indicates a

  14. a Microgravity Survey to Determine the Extent of AN Andesitic Sill that Intrudes across the Rio Grande River Basin, Rio Grande Rift Valley, Sunland Park, New Mexico (United States)

    Baker, L. A.; Shinagel, S.; Villalobos, J. I.; Avila, V.; Montana, C. J.; Kaip, G.


    In Sunland Park, NM, there is an andesite outcrop near the bank of the Rio Grande (called the River Andesite) which does not match the surrounding sedimentary deposition. Studies of the River Andesite by Garcia (1970) indicate the outcrop is petrologically similar to the Muleros Andesite of Mt. Cristo Rey located several km to the south. A limited GPR and magnetic survey conducted by UTEP students in 2008 suggested the River Andesite was part of a dike, although Garcia mapped smaller outcrops of andesite ~300 m west of the river that may be part of the same body. We have recently (June 2012) found large andesite boulders that may be the outcrops Garcia mapped, although it is uncertain whether these boulders are in-situ. We initially collected microgravity and magnetic data in a small region near the river outcrop in December 2011 to determine the extent of the outcrop. Our preliminary modeling of these data showed the river outcrop appeared to merge with a more extensive igneous body at depth. Ground conductivity data collected near the river outcrop in March 2012 suggested that the outcrop impacts groundwater flow and sediment deposition adjacent to the river. From May through July 2012 we have been collecting additional microgravity data on a grid with 100-200 m spacing extending ~ 500 m from both sides of the river outcrop to better determine the extent of the buried andesite body. We also plan to conduct GPR and magnetic surveys near the recently discovered andesite boulders to determine if these are truly in-situ and part of the same igneous body as the river outcrop. Our eventual goal is to determine how extensive the andesite unit is and how it may impact groundwater flow and flooding in this area of growing urbanization.

  15. Petrographic and Geochemical Investigation of Andesitic Arc Volcanism: Mount Kerinci, Sunda Arc, Indonesia (United States)

    Tully, M.; Saunders, K.; Troll, V. R.; Jolis, E.; Muir, D. D.; Deegan, F. M.; Budd, D. A.; Astbury, R.; Bromiley, G. D.


    Present knowledge of the chain of dominantly andesitic volcanoes, which span the Sumatran portion of the Sunda Arc is extremely limited. Previous studies have focused on Toba and Krakatau, although over 13 further volcanic edifices are known. Several recent explosive eruptions in Sumatra such as that of Mt. Sinabung, 2014, have highlighted the potential hazard that these volcanoes pose to the local and regional communities. Mount Kerinci, is one of the most active of the volcanoes in this region, yet little is known about the petrogenesis of the magma by which it is fed. Kerinci is located approximately mid-way between Toba in the North and Krakatau in the south. Along arc variations are observed in the major, minor and trace elements of whole rock analyses. However, bulk rock approaches produce an average chemical composition for a sample, potentially masking important chemical signatures. In-situ micro-analytical analysis of individual components of samples such as melt inclusions, crystals and groundmass provides chemical signatures of individual components allowing the evolution of volcanic centres to be deciphered in considerably more detail. Examination of whole rock chemistry indicates its location may be key to unravelling the petrogenesis of the arc as significant chemical changes occur between Kerinci and Kaba, 250 km to the south. Kerinci samples are dominantly porphyritic with large crystals of plagioclase, pyroxene and Fe-Ti oxides, rare olivine crystals are observed. Plagioclase and pyroxene crystals are chemically zoned and host melt inclusions. Multiple plagioclase populations are observed. A combination of in-situ micro-analysis techniques will be used to characterise the chemical composition of melt inclusions and crystals. These data can be used along with extant geothermobarometric models to help determine the magma source, storage conditions and composition of the evolving melt. Integration of the findings from this study with existing data for

  16. Petrogenesis of Mount Rainier andesite: magma flux and geologic controls on the contrasting differentiation styles at stratovolcanoes of the southern Washington Cascades (United States)

    Sisson, Thomas W.; Salters, V.J.M.; Larson, P.B.


    Quaternary Mount Rainier (Washington, USA) of the Cascades magmatic arc consists of porphyritic calc-alkaline andesites and subordinate dacites, with common evidence for mingling and mixing with less evolved magmas encompassing andesites, basaltic andesites, and rarely, basalts. Basaltic andesites and amphibole andesites (spessartites) that erupted from vents at the north foot of the volcano represent some of Mount Rainier's immediate parents and overlap in composition with regional basalts and basaltic andesites. Geochemical (major and trace elements) and isotopic (Sr, Nd, Pb, O) compositions of Mount Rainier andesites and dacites are consistent with modest assimilation (typically ≤20 wt%) of evolved sediment or sediment partial melt. Sandstones and shales of the Eocene Puget Group, derived from the continental interior, are exposed in regional anticlines flanking the volcano, and probably underlie it in the middle to lower crust, accounting for their assimilation. Mesozoic and Cenozoic igneous basement rocks are unsuitable as assimilants due to their high 143Nd/144Nd, diverse206Pb/204Pb, and generally high δ18O.

  17. Evidence for tectonic, lithologic, and thermal controls on fracture system geometries in an andesitic high-temperature geothermal field (United States)

    Massiot, Cécile; Nicol, Andrew; McNamara, David D.; Townend, John


    Analysis of fracture orientation, spacing, and thickness from acoustic borehole televiewer (BHTV) logs and cores in the andesite-hosted Rotokawa geothermal reservoir (New Zealand) highlights potential controls on the geometry of the fracture system. Cluster analysis of fracture orientations indicates four fracture sets. Probability distributions of fracture spacing and thickness measured on BHTV logs are estimated for each fracture set, using maximum likelihood estimations applied to truncated size distributions to account for sampling bias. Fracture spacing is dominantly lognormal, though two subordinate fracture sets have a power law spacing. This difference in spacing distributions may reflect the influence of the andesitic sequence stratification (lognormal) and tectonic faults (power law). Fracture thicknesses of 9-30 mm observed in BHTV logs, and 1-3 mm in cores, are interpreted to follow a power law. Fractures in thin sections (˜5 μm thick) do not fit this power law distribution, which, together with their orientation, reflect a change of controls on fracture thickness from uniform (such as thermal) controls at thin section scale to anisotropic (tectonic) at core and BHTV scales of observation. However, the ˜5% volumetric percentage of fractures within the rock at all three scales suggests a self-similar behavior in 3-D. Power law thickness distributions potentially associated with power law fluid flow rates, and increased connectivity where fracture sets intersect, may cause the large permeability variations that occur at hundred meter scales in the reservoir. The described fracture geometries can be incorporated into fracture and flow models to explore the roles of fracture connectivity, stress, and mineral precipitation/dissolution on permeability in such andesite-hosted geothermal systems.

  18. Rhyolitic calderas and centers clustered within the active andesitic belt of Ecuador's Eastern Cordillera

    Energy Technology Data Exchange (ETDEWEB)

    Mothes, Patricia A; Hall, Minard L [Instituto Geofisico, Escuela Politecnica Nacional, Quito (Ecuador)], E-mail:


    In the Ecuadorian volcanic arc a cluster of scattered rhyolitic and dacitic centers within the mainly andesitic Eastern Cordillera includes large caldera structures (Chalupas, Chacana, Cosanga) as well as smaller edifices, built upon the Paleozoic-Mesozoic metamorphic basement. At the Chacana caldera magmatism dates from 2.7 Ma to historic times. These centers erupted enormous ash flows and thick pumice lapilli falls that covered the InterAndean Valley near Quito. The role of the 50-70 km-thick crust with a notable negative gravity anomaly appears to be related to the generation of this highly silicic magmatism occurring along the crest of the Andes in the NVZ.

  19. Flowage differentiation in an andesitic dyke of the Motru Dyke Swarm (Southern Carpathians, Romania) inferred from AMS, CSD and geochemistry (United States)

    Nkono, Collin; Féménias, Olivier; Diot, Hervé; Berza, Tudor; Demaiffe, Daniel


    Two dykes of different thickness (5.5 m for TJ31 and 23 m for TJ34) from the late Pan-African calc-alkaline Motru Dyke Swarm (S. Carpathians, Romania) have been studied by electron microprobe (mineral chemistry), crystal size distribution (CSD), anisotropy of magnetic susceptibility (AMS) and whole-rock geochemistry. All the physical and chemical variations observed across the dyke's width point to concordant results and show that the variations of both modal abundance and size of the amphibole and biotite microphenocrysts inside the dykes (deduced from the classical CSD measurements) are the result of a mechanical segregation of suspended crystals during magmatic transport. Despite a pene-contemporaneous regional tectonic, the flow-induced differentiation in the thicker dyke is characterized by the concentration of pre-existing Ti-rich pargasite-tschermakite, clinopyroxene and plagioclase crystals in the core of the dyke and of the extracted differentiated liquid near the walls. This mechanical differentiation induces a chemical differentiation with a basaltic andesite composition for the core of the dyke whereas the margins are andesitic. Thus the chilled margins appear as a slightly more evolved liquid with a Newtonian behaviour when compared to the average composition of the dyke. The localization of the liquid on both sides of the dyke has certainly facilitated the ascent of the central part of the dyke that behaved as a Binghamian mush.

  20. Geological influence of andesite intrusion on diatomite. Pt. 2. Physical property changes of diatomite and self-sealing mechanism

    Energy Technology Data Exchange (ETDEWEB)

    Chigira, Masahiro; Nakata, Eiji [Central Research Inst. of Electric Power Industry, Abiko, Chiba (Japan). Abiko Research Lab.


    Diatomite alteration by andesite intrusion was studied especially on their physical property changes and the dynamic alteration processes for the diatomite of the Miocene Iwaya Formation in the Akita Prefecture, northern Japan. Diatomite is altered in different ways according to the extent of infiltration of hydrothermal solution into diatomite from dike. When the solution infiltrates into diatomite in large amount, smectite is formed in diatomite which is subsequently compacted to the most, and amorphous silica and poorly crystallized opal-CT precipitate in the compacted zone to form impermeable opaline chert. The chert zone becomes a hydraulic barrier against the infiltration of hydrothermal solution to make a closed system around the heat source, where opal-A transforms into opal-CT. When hydrothermal solution does not infiltrate into diatomite, diatomite is altered only by the heat from the andesitic dike: diatomite is compacted under higher temperatures near the dike, and consequently permeability is lowered. In both cases, diatomite is altered so as to mitigate the influence of magma intrusion. (author). 66 refs.

  1. Geological influence of andesite intrusion on diatomite. Pt. 2. Physical property changes of diatomite and self-sealing mechanism

    International Nuclear Information System (INIS)

    Chigira, Masahiro; Nakata, Eiji


    Diatomite alteration by andesite intrusion was studied especially on their physical property changes and the dynamic alteration processes for the diatomite of the Miocene Iwaya Formation in the Akita Prefecture, northern Japan. Diatomite is altered in different ways according to the extent of infiltration of hydrothermal solution into diatomite from dike. When the solution infiltrates into diatomite in large amount, smectite is formed in diatomite which is subsequently compacted to the most, and amorphous silica and poorly crystallized opal-CT precipitate in the compacted zone to form impermeable opaline chert. The chert zone becomes a hydraulic barrier against the infiltration of hydrothermal solution to make a closed system around the heat source, where opal-A transforms into opal-CT. When hydrothermal solution does not infiltrate into diatomite, diatomite is altered only by the heat from the andesitic dike: diatomite is compacted under higher temperatures near the dike, and consequently permeability is lowered. In both cases, diatomite is altered so as to mitigate the influence of magma intrusion. (author). 66 refs

  2. Sr isotope zoning in plagioclase from andesites at Cabo De Gata, Spain: Evidence for shallow and deep contamination (United States)

    Waight, Tod E.; Tørnqvist, Jakob B.


    Plagioclase crystals in andesites from the Cabo De Gata region show generally radiogenic Sr isotope compositions and consistent core to rim increases in 87Sr/86Sr that are indicative of open system processes in the lithosphere and crustal contamination during crystallization. High-grade metamorphic rocks of the Alpujárride and Nevado-Filábride complexes represent the most likely crustal contaminants. The plagioclases are characterized by subtly zoned and resorbed calcic cores (An73-86). These cores also have radiogenic 87Sr/86Sr (0.7127-0.7129), although typically less radiogenic than plagioclase rims, groundmass plagioclase and whole rock compositions (up to 87Sr/86Sr = 0.7135). These cores are interpreted to represent early crystallization of plagioclase from hydrous melts emplaced into the lower crust. The parental melts to these andesites must therefore have already inherited their radiogenic Sr isotope compositions prior to entering the lower crust and before the onset of crystallization of plagioclase, which is inconsistent with previous models suggesting that the generally radiogenic nature of Sr in these volcanics reflects large amounts of crustal contamination. Instead, the isotope systematics are consistent with models invoked significant addition of a subducted sediment component to the mantle source. The high-An% plagioclase cores are characterized by resorption textures, which are consistent with dissolution during rapid decompression and/or devolatisation during magma migration from the lower crust into upper crustal magma chambers.

  3. Analysis of noise pollution in an andesite quarry with the use of simulation studies and evaluation indices. (United States)

    Kosała, Krzysztof; Stępień, Bartłomiej


    This paper presents the verification of two partial indices proposed for the evaluation of continuous and impulse noise pollution in quarries. These indices, together with the sound power of machines index and the noise hazard index at the workstation, are components of the global index of assessment of noise hazard in the working environment of a quarry. This paper shows the results of acoustic tests carried out in an andesite quarry. Noise generated by machines and from performed blasting works was investigated. On the basis of acoustic measurements carried out in real conditions, the sound power levels of machines and the phenomenon of explosion were determined and, based on the results, three-dimensional models of acoustic noise propagation in the quarry were developed. To assess the degree of noise pollution in the area of the quarry, the continuous and impulse noise indices were used.

  4. Late Cretaceous (ca. 95 Ma) magnesian andesites in the Biluoco area, southern Qiangtang subterrane, central Tibet: Petrogenetic and tectonic implications (United States)

    He, Haiyang; Li, Yalin; Wang, Chengshan; Zhou, Aorigele; Qian, Xinyu; Zhang, Jiawei; Du, Lintao; Bi, Wenjun


    The tectonic evolutionary history of the Lhasa and Qiangtang collision zones remains hotly debated because of the lack of pivotal magmatic records in the southern Qiangtang subterrane, central Tibet. We present zircon U-Pb dating, whole-rock major and trace-element geochemical analyses, and Sr-Nd isotopic data for the newly discovered Biluoco volcanic rocks from the southern Qiangtang subterrane, central Tibet. Zircon U-Pb dating reveals that the Biluoco volcanic rocks were crystallized at ca. 95 Ma. The samples are characterized by low SiO2 (50.26-54.53 wt%), high Cr (109.7-125.92 ppm) and Ni (57.4-71.58 ppm), and a high Mg# value (39-56), which plot in the magnesian andesites field on the rock classification diagram. They display highly fractionated rare earth element patterns with light rare earth element enrichment ([La/Yb]N = 21.04-25.24), high Sr/Y (63.97-78.79) and no negative Eu anomalies (Eu/Eu* = 0.98-1.04). The Biluoco volcanic rocks are depleted in Nb, Ta and Ti and enriched in Ba, Th, U and Pb. Moreover, the eight samples of Biluoco volcanic rocks display constant (87Sr/86Sr)i ratios (0.70514-0.70527), a positive εNd(t) value (2.16-2.68) and younger Nd model ages (0.56-0.62 Ga). These geochemical signatures indicate that the Biluoco volcanic rocks were most likely derived from partial melting of the mantle wedge peridotite metasomatized by melts of subducted slab and sediment in the subducted slab, invoked by asthenospheric upwelling resulting from the slab break-off of the northward subduction of the Bangong-Nujiang oceanic lithosphere. Identification of ca. 95 Ma Biluoco magnesian andesites suggests they were a delayed response of slab break-off of the northward subduction of the Bangong-Nujiang oceanic lithosphere at ca. 100 Ma.

  5. Erratum: Correction to: Emplacement controls for the basaltic-andesitic radial dikes of Summer Coon volcano and implications for flank vents at stratovolcanoes (United States)

    Harp, A. G.; Valentine, G. A.


    In the article "Emplacement controls for the basaltic-andesitic radial dikes of Summer Coon volcano and implications for flank vents at stratovolcanoes", the vertical axis for Fig. 8 a was incorrectly labeled (i.e., the value for dikes per km2).

  6. Petrogenesis of andesites and dacites of White Island volcano, Bay of Plenty, New Zealand, in the light of new geochemical and isotopic data

    International Nuclear Information System (INIS)

    Graham, I.J.; Cole, J.W.


    White Island volcano comprises three main lava types: (1) silicic andesite, forming Western Cone and a tholoid at Troup Head, (2) dacite forming the Central Cone, and (3) mafic-silicic andesite erupted in March 1977 from the currently active crater. All lavas are calc-alkalic and medium-K orogenic types. The older andesites of Western Cone and Troup Head were probably formed from chemically dissimilar parental magmas by processes of assimilation and fractional crystallisation (AFC). Andesite blocks and bombs ejected during phreatomagmatic activity in March 1977 are geochemically primitive having high Mg-numbers, high Cr and Ni contents, and containing forsteritic olivine. They cannot be derived from magmatic compositions similar to known basaltic lavas of Taupo Volcanic Zone, and it is possible that the blocks are hybrid magmas resulting from mixing of a high Mg basalt parent and Central Cone dacite. The bombs appear to be fractionated derivatives. Central Cone dacites may also be AFC derivatives of a common parent to the 1977 lavas, in which substantial chemical diffusion has occurred. Their earlier eruption might represent unloading of a zoned magma chamber. (author). 49 refs., 8 figs., 3 tabs

  7. Long-term changes in explosive and effusive behaviour at andesitic arc volcanoes: Chronostratigraphy of the Centre Hills Volcano, Montserrat (United States)

    Coussens, Maya; Cassidy, Michael; Watt, Sebastian F. L.; Jutzeler, Martin; Talling, Peter J.; Barfod, Dan; Gernon, Thomas M.; Taylor, Rex; Hatter, Stuart J.; Palmer, Martin R.; Montserrat Volcano Observatory


    Volcanism on Montserrat (Lesser Antilles arc) has migrated southwards since the formation of the Silver Hills 2.5 Ma, and has formed three successively active volcanic centres. The Centre Hills volcano was the focus of volcanism from 1-0.4 Ma, before activity commenced at the currently active Soufrière Hills volcano. The history of activity at these two volcanoes provides an opportunity to investigate the pattern of volcano behaviour on an andesitic arc island over the lifetime of individual volcanoes. Here, we describe the pyroclastic stratigraphy of subaerial exposures around central Montserrat; identifying 11 thick (> 1 m) pumiceous units derived from sustained explosive eruptions of Centre Hills from 0.8-0.4 Ma. Over 10 other, less well- exposed pumiceous units have also been identified. The pumice-rich units are interbedded with andesite lava breccias derived from effusive, dome-forming eruptions of Centre Hills. The stratigraphy indicates that large (up to magnitude 5) explosive eruptions occurred throughout the history of Centre Hills, alongside effusive activity. This behaviour at Centre Hills contrasts with Soufrière Hills, where deposits from sustained explosive eruptions are much less common and restricted to early stages of activity at the volcano, from 175-130 ka. Subsequent eruptions at Soufriere Hills have been dominated by andesitic effusive eruptions. The bulk composition, petrography and mineral chemistry of volcanic rocks from Centre Hills and Soufrière Hills are similar throughout the history of both volcanoes, except for occasional, transient departures to different magma compositions, which mark shifts in vent location or dominant eruption style. For example, the final recorded eruption of Centre Hills, before the initiation of activity at Soufrière Hills, was more silicic than any other identified eruption on Montserrat; and the basaltic South Soufrière Hills episode marked the transition to the current stage of predominantly effusive

  8. Pyroclast textural variation as an indicator of eruption column steadiness in andesitic Plinian eruptions at Mt. Ruapehu (United States)

    Pardo, Natalia; Cronin, Shane J.; Wright, Heather M.N.; Schipper, C. Ian; Smith, Ian; Stewart, Bob


    Between 27 and 11 cal. ka BP, a transition is observed in Plinian eruptions at Mt. Ruapehu, indicating evolution from non-collapsing (steady and oscillatory) eruption columns to partially collapsing columns (both wet and dry). To determine the causes of these variations over this eruptive interval, we examined lapilli fall deposits from four eruptions representing the climactic phases of each column type. All eruptions involve andesite to basaltic andesite magmas containing plagioclase, clinopyroxene, orthopyroxene and magnetite phenocrysts. Differences occur in the dominant pumice texture, the degree of bulk chemistry and textural variability, the average microcrystallinity and the composition of groundmass glass. In order to investigate the role of ascent and degassing processes on column stability, vesicle textures were quantified by gas volume pycnometry (porosity), X-ray synchrotron and computed microtomography (μ-CT) imagery from representative clasts from each eruption. These data were linked to groundmass crystallinity and glass geochemistry. Pumice textures were classified into six types (foamy, sheared, fibrous, microvesicular, microsheared and dense) according to the vesicle content, size and shape and microlite content. Bulk porosities vary from 19 to 95 % among all textural types. Melt-referenced vesicle number density ranges between 1.8 × 102 and 8.9 × 102 mm−3, except in fibrous textures, where it spans from 0.3 × 102 to 53 × 102 mm−3. Vesicle-free magnetite number density varies within an order of magnitude from 0.4 × 102 to 4.5 × 102 mm−3 in samples with dacitic groundmass glass and between 0.0 and 2.3 × 102 mm−3 in samples with rhyolitic groundmass. The data indicate that columns that collapsed to produce pyroclastic flows contained pumice with the greatest variation in bulk composition (which overlaps with but extends to slightly more silicic compositions than other eruptive products); textures

  9. Dynamic observations of vesiculation reveal the role of silicate crystals in bubble nucleation and growth in andesitic magmas

    Energy Technology Data Exchange (ETDEWEB)

    Pleše, P.; Higgins, M. D.; Mancini, L.; Lanzafame, G.; Brun, F.; Fife, J. L.; Casselman, J.; Baker, D. R.


    Bubble nucleation and growth control the explosivity of volcanic eruptions, and the kinetics of these processes are generally determined from examinations of natural samples and quenched experimental run products. These samples, however, only provide a view of the final state, from which the initial conditions of a time-evolving magmatic system are then inferred. The interpretations that follow are inexact due to the inability of determining the exact conditions of nucleation and the potential detachment of bubbles from their nucleation sites, an uncertainty that can obscure their nucleation location – either homogeneously within the melt or heterogeneously at the interface between crystals and melts. We present results of a series of dynamic, real-time 4D X-ray tomographic microscopy experiments where we observed the development of bubbles in crystal bearing silicate magmas. Experimentally synthesized andesitic glasses with 0.25–0.5 wt% H2O and seed silicate crystals were heated at 1 atm to induce bubble nucleation and track bubble growth and movement. In contrast to previous studies on natural and experimentally produced samples, we found that bubbles readily nucleated on plagioclase and clinopyroxene crystals, that their contact angle changes during growth and that they can grow to sizes many times that of the silicate on whose surface they originated. The rapid heterogeneous nucleation of bubbles at low degrees of supersaturation in the presence of silicate crystals demonstrates that silicates can affect when vesiculation ensues, influencing subsequent permeability development and effusive vs. explosive transition in volcanic eruptions.

  10. Dynamic observations of vesiculation reveal the role of silicate crystals in bubble nucleation and growth in andesitic magmas (United States)

    Pleše, P.; Higgins, M. D.; Mancini, L.; Lanzafame, G.; Brun, F.; Fife, J. L.; Casselman, J.; Baker, D. R.


    Bubble nucleation and growth control the explosivity of volcanic eruptions, and the kinetics of these processes are generally determined from examinations of natural samples and quenched experimental run products. These samples, however, only provide a view of the final state, from which the initial conditions of a time-evolving magmatic system are then inferred. The interpretations that follow are inexact due to the inability of determining the exact conditions of nucleation and the potential detachment of bubbles from their nucleation sites, an uncertainty that can obscure their nucleation location - either homogeneously within the melt or heterogeneously at the interface between crystals and melts. We present results of a series of dynamic, real-time 4D X-ray tomographic microscopy experiments where we observed the development of bubbles in crystal bearing silicate magmas. Experimentally synthesized andesitic glasses with 0.25-0.5 wt% H2O and seed silicate crystals were heated at 1 atm to induce bubble nucleation and track bubble growth and movement. In contrast to previous studies on natural and experimentally produced samples, we found that bubbles readily nucleated on plagioclase and clinopyroxene crystals, that their contact angle changes during growth and that they can grow to sizes many times that of the silicate on whose surface they originated. The rapid heterogeneous nucleation of bubbles at low degrees of supersaturation in the presence of silicate crystals demonstrates that silicates can affect when vesiculation ensues, influencing subsequent permeability development and effusive vs. explosive transition in volcanic eruptions.

  11. A submarine andesite-rhyodacite lineage of arc affinity hosting hydrothermal mineralisation, Pual Ridge, Eastern Manus back-arc basin, Papua New Guinea

    International Nuclear Information System (INIS)

    Binns, R.A.; Waters, J.C.; Parr, J.M.; Carr, G.R.; Whitford, D.J.


    Pual Ridge, host to the PACMANUS hydrothermal field, is a composite edifice formed by recent submarine eruptions, with a continuous suite of consanguineous andesite, dacite and rhyodacite (58 to 74% SiO 2 , mg 41 to 17). The lavas are vesicular, hyaline, and aphyric to sparsely porphyritic. Dacites dominate the PACMANUS hydrothermal field at the ridge crest. The Pual Ridge volcanic suite is subalkalic, with a calcic character, bordering on calcalkaline (Fig. 1). It falls just within the medium-K field, and has geochemical characteristics (K/Rb ∼500, K/Ba∼40, mild enrichment in light rare earth elements (LREE) ((La/Sm) N ∼1.7, (La/Yb) N ∼2.1) which fall into the spectrum of modern arc volcanic rock suites on New Britain to the south. By contrast, the basalts from the central Manus back-arc spreading zone are very low-K. When major and trace element data are plotted against silica contents in Harker diagrams, gently curved trends extend from andesite to rhyodacite. The trends can be interpreted in terms of low-pressure fractionation of the observed (albeit rare) phenocryst assemblage (plagioclase, ortho- and clinopyroxene, magnetite), with progressive enrichment of incompatible elements such as K, Ba, Zr and the REE. Basaltic andesites (mg 42-45) from features adjacent to Pual Ridge exhibit Ti and P contents falling below this fractionation trend, but trend towards a possible parent magma from which Pual Ridge andesites were derived by extraction of an olivine-dominated assemblage. Moderately potassic picritic basalts (mg 56) representing the potential parent magmas also occur on edifices east of Pual Ridge. Like the Pual lavas, these have low Nb (1-2 ppm) consistent with an arc affinity

  12. Investigation of Mineral Alteration in Andesite and Dacite from Three Different Volcano Hydrothermal Systems on Dominica, Lesser Antilles (United States)

    Smith, C. I. V.; Frey, H. M.; Joseph, E. P.; Manon, M. R. F.


    The thermal discharges of Dominica are classified as steam-heated acidic-sulphate waters, produced by the mixing of shallow ground waters heated by sulphur bearing gases coming from magmatic sources. This study investigates the mineral alteration associated with three hydrothermal areas in Dominica that exhibit different temperature, pH, water composition and surface water abundance. Hydrothermal features (fumaroles, pools, springs) from Sulphur Springs ranged in temperature from 41 - 97 °C and pH from 1-3 in a predominantly gaseous environment, whereas the Valley of Desolation (69-98 °C and pH 1- 4) and the Cold Soufriere (18-32 °C and pH 1-4) have significant inputs of surface water. At each location, the host andesite-dacite rock was enveloped by a thin rind (up 2 cm) of precipitates, but the degree of alteration and rind thickness/composition varied with location. Cobbles from Sulphur Springs (SS) are grayish white in color with a thin outer rind (3-13 mm), and seemingly unaltered cores. Valley of Desolation (VoD) samples have a variety of patterns of alteration, with some clasts a uniform white-orange color, whereas others have variable thicknesses of an altered rind (1-20 mm), with relatively unaltered cores. Multiple hydrothermal minerals precipitated in the outer rinds display distinctive colors, suggestive of sulphides (dark gray), sulphates (orange and yellow), and iron oxides(?) (pink and purple). Cold Soufriere (CS) samples appear to be the most altered, often crumbling at touch. Others had rinds (2-10 mm) and pinkish gray cores that suggest more alteration compared to VoD and SS samples. Preliminary mineral identification of rind compositions was determined by XRD. Scans indicate the presence of silica polymorphs cristobalite and tridymite, as well as pyrite and sulphur. Elemental maps created using a SEM to identify any gradation caused by the elemental leaching and/or precipitation show that the boundaries between the weathering rind and the host

  13. Diffusive exchange of trace elements between basaltic-andesite and dacitic melt: Insights into potential metal fractionation during magma mixing (United States)

    Fiege, A.; Ruprecht, P.; Simon, A. C.; Holtz, F.


    Mafic magma recharge is a common process that triggers physical and chemical mixing in magmatic systems and drives their evolution, resulting in, e.g., hybridization and volcanic eruptions. Once magma-magma contact is initiated, rapid heat-flux commonly leads to the formation of a cooling-induced crystal mush on the mafic side of the interface. Here, on a local scale (µm to cm), at the magma-magma interface, melt-melt diffusive exchange is required to approach equilibrium. Significant chemical potential gradients drive a complex, multi-element mass flux between the two systems (Liang, 2010). This diffusive-equilibration often controls crystal dissolution rates within the boundary layers and, thus, the formation of interconnected melt or fluid networks. Such networks provide important pathways for the transport of volatiles and trace metals from the mafic recharge magma to the felsic host magma, where the latter may feed volcanic activities and ore deposits. While major element diffusion in silicate melts is mostly well understood, even in complex systems, the available data for many trace element metals are limited (Liang, 2010; Zhang et al., 2010). Differences in diffusivity in a dynamic, mixing environment can cause trace element fractionation, in particular during crystallization and volatile exsolution and separation. This may affect trace element signatures in phenocrysts and magmatic volatile phases that can form near a magma-magma boundary. As a result, the chemistry of volcanic gases and magmatic-hydrothermal ore deposits may be partially controlled by such mixing phenomena. We performed melt-melt diffusion-couple experiments at 150 MPa, 1100°C, FMQ, FMQ+1 and FMQ+3 (FMQ: fayalite-magnetite-quartz oxygen fugacity buffer). Hydrated, sulfur-bearing cylinders of dacite and basaltic andesite were equilibrated for up to 20 h. Major and trace element gradients were measured by using laser-ablation ICP-MS and electron microprobe analyses. The results we will

  14. Emplacement controls for the basaltic-andesitic radial dikes of Summer Coon volcano and implications for flank vents at stratovolcanoes (United States)

    Harp, A. G.; Valentine, G. A.


    Mafic flank eruptions are common events that pose a serious hazard to the communities and infrastructure often encroaching on the slopes of stratovolcanoes. Flank vent locations are dictated by the propagation path of their feeder dikes. The dikes are commonly thought to propagate either laterally from the central conduit or vertically from a deeper source. However, these interpretations are often based on indirect measurements, such as surface deformation and seismicity at active systems, and several studies at eroded volcanoes indicate the propagation paths may be more complex. We investigated the Oligocene age Summer Coon volcano (Colorado, USA), where erosion has exposed over 700 basaltic-andesitic radial dikes, to constrain the propagation directions, geometries, and spatial distributions of mafic dikes within a stratovolcano. The mean fabric angle of aligned plagioclase crystals was measured in oriented samples from the margins of 77 dikes. Of the 41 dikes with statistically significant flow fabrics, 85% had fabric angles that were inclined—plunging both inward and outward relative to the center of the volcano. After comparing fabric angles to those reported in other studies, we infer that, while most of the dikes with outward-plunging fabrics descended toward the flanks from a source within the edifice and near its axis, dikes with inward-plunging fabrics ascended through the edifice and toward the flanks from a deeper source. A possible control for the inclination of ascending dikes was the ratio between magma overpressure and the normal stress in the host rock. While higher ratios led to high-angle propagation, lower ratios resulted in inclined emplacement. Dikes crop out in higher frequencies within a zone surrounding the volcano axis at 2500 m radial distance from the center and may be the result of ascending dikes, emplaced at similar propagation angles, intersecting the current level of exposure at common distances from the volcano axis. The process

  15. Plagioclase Textures and Zoning Patterns in the Miocene Dowdy Ranch Andesite, Central California Coast Ranges: Implications for Open and Closed System Behavior in Magmatic Systems (United States)

    Bavishi, D. K.; Metzger, E. P.; Miller, J. S.


    The Miocene Dowdy Range Andesite (DRA) of the Central California Coast Ranges is part of a northwestward-younging sequence of volcanic rocks that were apparently formed by northward movement of the Mendocino triple junction, formation of a slab window, and infilling by asthenospheric mantle. The highly porphyritic andesite contains plagioclase phenocrysts with a wide array of disequilibrium textures and zoning patterns, providing an opportunity to reconstruct andesite-forming processes in a tectonic environment that evolved from subduction to transform motion. The DRA encloses metasedimentary, granulitic, and gabbroic xenoliths (described elsewhere) and displays arc-like trace element chemistry. It features glomeroporphyritic, intersertal and hyalopilitic textures with plagioclase as the dominant phase both as phenocrysts and in the groundmass. Other groundmass minerals include orthopyroxene, clinopyroxene, and ilmenite. Plagioclase exhibits normal, reverse, oscillatory and patchy zoning patterns and sieve and sponge textures, with several populations of plagioclase crystals observed on the scale of a single thin section. The presence of abundant quartz xenocrysts rimmed by augite and absence of mafic enclaves suggest that incorporation of crustal material played an important role in forming the andesite. Preliminary examination of back-scattered electron images and electron microprobe analysis of zoned plagioclase shows both concordant and discordant relationships between An and FeO, suggesting that the andesite was formed by a combination of open and closed system magmatic processes. Plagioclase cores vary from An 45-65%. Clear rims surrounding spongy zones are common and show abrupt and significant (~10-50% An and 5-20% FeO) increases in both An and FeO, as expected for magma recharge by more mafic magma. Clear rim compositions are consistent from sample to sample, suggesting that the phenocrysts experienced a common history during later stages of

  16. The 2006-2009 activity of the Ubinas volcano (Peru): Petrology of the 2006 eruptive products and insights into genesis of andesite magmas, magma recharge and plumbing system (United States)

    Rivera, Marco; Thouret, Jean-Claude; Samaniego, Pablo; Le Pennec, Jean-Luc


    Following a fumarolic episode that started six months earlier, the most recent eruptive activity of the Ubinas volcano (south Peru) began on 27 March 2006, intensified between April and October 2006 and slowly declined until December 2009. The chronology of the explosive episode and the extent and composition of the erupted material are documented with an emphasis on ballistic ejecta. A petrological study of the juvenile products allows us to infer the magmatic processes related to the 2006-2009 eruptions of the andesitic Ubinas volcano. The juvenile magma erupted during the 2006 activity shows a homogeneous bulk-rock andesitic composition (56.7-57.6 wt.% SiO2), which belongs to a medium- to high-K calc-alkaline series. The mineral assemblage of the ballistic blocks and tephra consists of plagioclase > two-pyroxenes > Fe-Ti oxide and rare olivine and amphibole set in a groundmass of the same minerals with a dacitic composition (66-67 wt.% SiO2). Thermo-barometric data, based on two-pyroxene and amphibole stability, records a magma temperature of 998 ± 14 °C and a pressure of 476 ± 36 MPa. Widespread mineralogical and textural features point to a disequilibrium process in the erupted andesite magma. These features include inversely zoned "sieve textures" in plagioclase, inversely zoned clinopyroxene, and olivine crystals with reaction and thin overgrowth rims. They indicate that the pre-eruptive magmatic processes were dominated by recharge of a hotter mafic magma into a shallow reservoir, where magma mingling occurred and triggered the eruption. Prior to 2006, a probable recharge of a mafic magma produced strong convection and partial homogenization in the reservoir, as well as a pressure increase and higher magma ascent rate after four years of fumarolic activity. Mafic magmas do not prevail in the Ubinas pre-historical lavas and tephras. However, mafic andesites have been erupted during historical times (e.g. AD 1667 and 2006-2009 vulcanian eruptions). Hence

  17. The Effect of CO2 on Partial Reactive Crystallization of MORB-Eclogite-derived Basaltic Andesite in Peridotite and Generation of Silica-Undersaturated Basalts (United States)

    Mallik, A.; Dasgupta, R.


    Recycled oceanic crust (MORB-eclogite) is considered to be the dominant heterogeneity in Earth's mantle. Because MORB-eclogite is more fusible than peridotite, siliceous partial melt derived from it must react with peridotite while the latter is still in the subsolidus state. Thus, studying such reactive process is important in understanding melting dynamics of the Earth's mantle. Reaction of MORB-eclogite-derived andesitic partial melt with peridotite can produce alkalic melts by partial reactive crystallization but these melts are not as silica-undersaturated as many natural basanites, nephelinites or melititites [1]. In this study, we constrain how dissolved CO2 in a siliceous MORB-eclogite-derived partial melt affects the reaction phase equilibria involving peridotite and can produce nephelinitic melts. Here we compare experiments on CO2-free [1] and 2.6 wt.% CO2 bearing andesitic melt+lherzolite mixtures conducted at 1375 °C and 3 GPa with added melt fraction of 8-50 wt.%. In both CO2-free and CO2-bearing experiments, melt and olivine are consumed and opx and garnet are produced, with the extent of modal change for a given melt-rock ratio being greater for the CO2-bearing experiments. While the residue evolves to a garnet websterite by adding 40% of CO2-bearing melt, the residue becomes olivine-free by adding 50% of the CO2-free melt. Opx mode increases from 12 to ~55 wt.% for 0 to 40% melt addition in CO2-bearing system and 12 to ~43 wt.% for 0 to 50% melt addition in CO2-free system. Garnet mode, for a similar range of melt-rock ratio, increases from ~10 to ~15 wt.% for CO2 bearing system and to ~11 wt.% for CO2-free system. Reacted melts from 25-33% of CO2-bearing melt-added runs contain ~39 wt.% SiO2 , ~11-13 wt.% TiO2, ~9 wt.% Al2O3, ~11 wt.% FeO*, 16 wt.% MgO, 10-11 wt.% CaO, and 3 wt.% Na2O whereas experiments with a similar melt-rock ratio in a CO2-free system yield melts with 44-45 wt.% SiO2, 6-7 wt.% TiO2, 13-14 wt.% Al2O3, 10-11 wt.% FeO*, 12-13 wt

  18. Chemical compositions and Sr, Nd isotope ratios of gabbroic xenoliths in calc-alkali andesites of Naeba and Torikabuto volcanoes, North Fossa Magna, central Japan

    International Nuclear Information System (INIS)

    Shimazu, Mitsuo; Kawano, Yoshinobu; Kaji, Kiyoshi; Igarashi, Satoshi.


    Gabbroic, doleritic and basaltic xenoliths found in calc-alkali andesites of Naeba and Torikabuto volcanoes are geochemically divided into three groups. Gabbro A of the group 1 from Naeba is rich in MgO and Ni, poor in alkalis, and shows depleted REE pattern resembling those of Ichinomegata (Sp. No.2232) and Hakone (HKG1, HKG2) volcanoes. On the basis the REE pattern and high Al IV contents in clinopyroxenes, gabbro A is interpreted to have been cumulate from a primary magma generated by partial melting of upper mantle. From REE pattern, gabbros of the group 2 from Ichinomegata (Sp. No.2218) may have derived from low alkali tholeiite magma which have been formed by removal of material such as the group 1 gabbro at shallow depth. Doleritic and basaltic xenoliths of the group 3 from Naeba, gabbroic xenoliths from Torikabuto and Umikawa are poorer in MgO and richer in alkalis than those of the group 1 and show enriched pattern in REE resembling that of high alkali tholeiite and contain clinopyroxenes having low Al IV . Therefore, these rocks are considered to be differentiates of high alkali tholeiite magma at shallow depth. On εNd- 87 Sr/ 86 Sr diagram, isotope data of gabbro A of the group 1 plot near those of andesites from Asama and Myoko volcanoes of the North Fossa Magna. It is interpreted that these rocks have derived from the same mantle source as the Asama and Myoko volcanoes which are richer in incompatible elements than those of MORB. (author)

  19. Effect of fO2 on phase relationship in basaltic andesites during magmatic differentiation: Control of fO2 and sulphur speciation in piston cylinder experiments. (United States)

    Matjuschkin, Vladimir; Tattitch, Brian; Blundy, Jonathan D.; Skora, Susanne


    Within the mantle wedge above subduction zones, oxidation reaction take place by interaction of reduced mantle rocks with more oxidized, hydrous fluids, which can cause a local drop of the solidus, resulting in partial melting (2,6,7). The resultant melts are more oxidized that their ocean floor counterparts, which has implications for their subsequent differentiation paths, the speciation of multivalent elements and the solubility and transport of chemical compounds in magmatic systems (1,4,5). We present a series of sulphur-doped high-pressure experiments conducted to investigate the effect of oxygen fugacity on phase relationships and the behaviour of sulphur in silicate melts. Natural aphyric andesite (FM37) erupted from Laguna del Maule volcano, Chile (3) was selected as a starting composition. Experiments were carried out at 5kbar, 950-1150° C and variable oxygen fugacity conditions. New experiments buffered at Co-CoO and Ni-NiO buffer conditions have been performed using a new "MTB capsule design" developed in order to accurately control fO2 by means of a double capsule containing metal-oxide buffers and a pyrex sleeve to minimise H2 diffusion. This new design constrains oxygen fugacity to within ±0.1-0.2logfO2 units of the target value. Before conducting these experiments, the assemblage was tested multiple times at 10kbar, 1000° C over 24-48 hours and demonstrated consistent, accurate fO2 control. Analyses of the preliminary experimental run products, from a related Chilean basaltic andesite starting composition, demonstrate a clear effect of fO2 on phase relationships and the proportion of melt generated during experiments. Under oxidized conditions, as temperature decreased from 1150° C to 1050° C, the amount of melt decreased from 100% to ~80%, due to the formation of orthopyroxene, anhydrite and plagioclase. In contrast, in reduced runs the system remains nearly liquid (~5% crystals) down to 950° C due to the change in sulphur speciation and

  20. An Overview of the Dynamics of the Volcanic Paroxysmal Explosive Activity, and Related Seismicity, at Andesitic and Dacitic Volcanoes (1960–2010

    Directory of Open Access Journals (Sweden)

    Vyacheslav M. Zobin


    Full Text Available Understanding volcanic paroxysmal explosive activity requires the knowledge of many associated processes. An overview of the dynamics of paroxysmal explosive eruptions (PEEs at andesitic and dacitic volcanoes occurring between 1960 and 2010 is presented here. This overview is based mainly on a description of the pre-eruptive and eruptive events, as well as on the related seismic measurements. The selected eruptions are grouped according to their Volcanic Explosivity Index (VEI. A first group includes three eruptions of VEI 5-6 (Mount St. Helens, 1980; El Chichón, 1982; Pinatubo, 1991 and a second group includes three eruptions of VEI 3 (Usu volcano, 1977; Soufriere Hills Volcano (SHV, 1996, and Volcán de Colima, 2005. The PEEs of the first group have similarity in their developments that allows to propose a 5-stage scheme of their dynamics process. Between these stages are: long (more than 120 years period of quiescence (stage 1, preliminary volcano-tectonic (VT earthquake swarm (stage 2, period of phreatic explosions (stage 3 and then, PEE appearance (stage 4. It was shown also that the PEEs of this group during their Plinian stage “triggered” the earthquake sequences beneath the volcanic structures with the maximum magnitude of earthquakes proportional to the volume of ejecta of PEEs (stage 5. Three discussed PEEs of the second group with lower VEI developed in more individual styles, not keeping within any general scheme. Among these, one PEE (SHV may be considered as partly following in development to the PEEs of the first group, having stages 1, 3, and 4. The PEEs of Usu volcano and of Volcán de Colima had no preliminary long-term stages of quiescence. The PEE at Usu volcano came just at the end of the preceding short swarm of VT earthquakes. At Volcán de Colima, no preceding swarm of VT occurred. This absence of any regularity in development of lower VEI eruptions may refer, among other reasons, to different conditions of opening

  1. Experimental determination of dissolved CO2 content in nominally anhydrous andesitic melts at graphite/diamond saturation - Remobilization of deeply subducted reduced carbon via partial melts of MORB-like eclogite (United States)

    Eguchi, J.; Dasgupta, R.


    Experimental phase relations of carbonated lithologies [1] and geochemistry of deep diamonds [2] suggest that deep recycling of carbon has likely been efficient for a significant portion of Earth's history. Both carbonates and organic carbon subduct into the mantle, but with gradual decrease of fO2 with depth [3] most carbon in deep mantle rocks including eclogite could be diamond/graphite [4]. Previous studies investigated the transfer of CO2 from subducted eclogite to the ambient mantle by partial melting in the presence of carbonates, i.e., by generation of carbonate-rich melts [5]. However, the transfer of carbon from subducted eclogite to the mantle can also happen, perhaps more commonly, by extraction of silicate partial melt in the presence of reduced carbon; yet, CO2 solubility in eclogite-derived andesitic melt at graphite/diamond saturation remains unconstrained. CO2content of eclogite melts is also critical as geochemistry of many ocean island basalts suggest the presence of C and eclogite in their source regions [6]. In the present study we determine CO2 concentration in a model andesitic melt [7] at graphite/diamond saturation at conditions relevant for partial melting of eclogite in the convecting upper mantle. Piston cylinder and multi anvil experiments were conducted at 1-6 GPa and 1375-1550 °C using Pt/Gr double capsules. Oxygen fugacity was monitored with Pt-Fe sensors in the starting mix. Completed experiments at 1-3 GPa show that CO2 concentration increases with increasing P, T, and fO2 up to ~0.3 wt%. Results were used to develop empirical and thermodynamic models to predict CO2 concentration in partial melts of graphite saturated eclogite. This allowed us to quantify the extent to which CO2 can mobilize from eclogitic heterogeneities at graphite/diamond saturated conditions. With estimates of eclogite contribution to erupted basaltic lavas, the models developed here allow us to put constraints on the flux of CO2 to mantle source regions

  2. Geochemistry, age and strontium isotope composition of late tertiary and quaternary basalts and andesites in western Nevada and their relation to geothermal potential. Final report, October 1, 1982-December 31, 1983

    Energy Technology Data Exchange (ETDEWEB)

    Fultz, L.A.; Bell, E.J.; Trexler, D.T.


    This research was undertaken to characterize the late Cenozoic volcanic rocks associated with active geothermal systems in west-central Nevada. Petrographic and microprobe, geochemical and isotopic analysis and age dating techniques were used to characterize these young volcanic rocks. These data were combined with the limited data previously reported in the literature on these same volcanic areas to interpret their petrogenesis. The overall characterization resulted from integrating the petrogenesis with a structural-tectonic model of the region. Potassium-argon isotopic ages ranging up to 14 million years were determined for eight localities within the Reno 1 x 2/sup 0/ study region. These ages are consistent with the morphology of the volcanic landforms, the active geothermal systems associated with them, and with other isotopic ages reported in the literature for these and similar rocks within the study region. Petrographic analysis of hand specimens and thin-sections indicated mineralogic assemblages of the respective rock types and specific mineral textures and phenocryst compositions and characteristics. These identifications were further substantiated by microprobe analysis of selected phenocrysts and groundmass phases. Classification of the respective rock types was also based on chemical composition and normative calculations using the program PETCAL. Basaltic andesites are identified and described for Steamboat Hills, Table Mountain, Silver Springs, Churchill Butte, Cleaver Peak, Desert Peak and Carson City sites.

  3. An Integrative Approach for Defining Plinian and Sub-Plinian Eruptive Scenarios at Andesitic Volcanoes: Event-Lithostratigraphy, Eruptive Parameters and Pyroclast Textural Variations of the Largest Late-Holocene Eruptions of Mt. Taranaki, New Zealand. (United States)

    Torres-Orozco, R.; Cronin, S. J.; Damaschke, M.; Kosik, S.; Pardo, N.


    Three eruptive scenarios were determined based on the event-lithostratigraphic reconstruction of the largest late-Holocene eruptions of the andesitic Mt. Taranaki, New Zealand: a) sustained dome-effusion followed by sudden stepwise collapse and unroofing of gas-rich magma; b) repeated plug and burst events generated by transient open-/closed-vent conditions; and c) open-vent conditions of more mafic magmas erupting from a satellite vent. Pyroclastic density currents (PDCs) are the most frequent outcome in every scenario. They can be produced in any/every eruption phase by formation and either repetitive-partial or total gravity-driven collapse of lava domes in the summit crater (block-and-ash flows), frequently followed by sudden magma decompression and violent, highly unsteady to quasi-steady lateral expansion (blast-like PDCs); by collapse or single-pulse fall-back of unsteady eruption columns (pyroclastic flow- and surge-type currents); or during highly unsteady and explosive hydromagmatic phases (wet surges). Fall deposits are produced during the climatic phase of each eruptive scenario by the emplacement of (i) high, sustained and steady, (ii) sustained and height-oscillating, (iii) quasi-steady and pulsating, or (iv) unsteady and totally collapsing eruption columns. Volumes, column heights and mass- and volume-eruption rates indicate that these scenarios correspond to VEI 4-5 plinian and sub-plinian multi-phase and style-shifting episodes, similar or larger than the most recent 1655 AD activity, and comparable to plinian eruptions of e.g. Apoyeque, Colima, Merapi and Tarawera volcanoes. Whole-rock chemistry, textural reconstructions and density-porosity determinations suggest that the different eruptive scenarios are mainly driven by variations in the density structure of magma in the upper conduit. Assuming a simple single conduit model, the style transitions can be explained by differing proportions of alternating gas-poor/degassed and gas-rich magma.

  4. Sulfur metabolizing microbes dominate microbial communities in Andesite-hosted shallow-sea hydrothermal systems. (United States)

    Zhang, Yao; Zhao, Zihao; Chen, Chen-Tung Arthur; Tang, Kai; Su, Jianqiang; Jiao, Nianzhi


    To determine microbial community composition, community spatial structure and possible key microbial processes in the shallow-sea hydrothermal vent systems off NE Taiwan's coast, we examined the bacterial and archaeal communities of four samples collected from the water column extending over a redoxocline gradient of a yellow and four from a white hydrothermal vent. Ribosomal tag pyrosequencing based on DNA and RNA showed statistically significant differences between the bacterial and archaeal communities of the different hydrothermal plumes. The bacterial and archaeal communities from the white hydrothermal plume were dominated by sulfur-reducing Nautilia and Thermococcus, whereas the yellow hydrothermal plume and the surface water were dominated by sulfide-oxidizing Thiomicrospira and Euryarchaeota Marine Group II, respectively. Canonical correspondence analyses indicate that methane (CH(4)) concentration was the only statistically significant variable that explains all community cluster patterns. However, the results of pyrosequencing showed an essential absence of methanogens and methanotrophs at the two vent fields, suggesting that CH(4) was less tied to microbial processes in this shallow-sea hydrothermal system. We speculated that mixing between hydrothermal fluids and the sea or meteoric water leads to distinctly different CH(4) concentrations and redox niches between the yellow and white vents, consequently influencing the distribution patterns of the free-living Bacteria and Archaea. We concluded that sulfur-reducing and sulfide-oxidizing chemolithoautotrophs accounted for most of the primary biomass synthesis and that microbial sulfur metabolism fueled microbial energy flow and element cycling in the shallow hydrothermal systems off the coast of NE Taiwan.

  5. Decompression Induced Crystallization of Basaltic Andesite Magma: Constraints on the Eruption of Arenal Volcano, Costa Rica. (United States)

    Szramek, L. A.; Gardner, J. E.; Larsen, J. F.


    Arenal Volcano is a small stratovolcano located 90 km NW of San Jose, Costa Rica. In 1968 current activity began with a Plinian phase, and has continued to erupt lava flows and pyroclastic flows intermittently since. Samples from the Plinian, pyroclastic flow, strombolian, and effusive phases have been studied texturally. Little variation in crystallinity occurs amongst the different phases. Number density of crystals, both 2D and 3D are 50-70 mm-2 and 30,000-50,000 mm-3 in the Plinian sample, compared to the lesser values in other eruptive types. Characteristic crystal size also increases as explosivity decreases. Two samples, both lava flows collected while warm, overlap with the Plinian sample. This suggests that the variations seen may be a result of cooling history. Plagioclase differs between the Plinian sample, in which they are only tabular in shape, and the other eruptive types, which contain both tabular and equant crystals. To link decompression paths of the Arenal magma to possible pre-eruptive conditions, we have carried out hydrothermal experiments. The experiments were preformed in TZM pressure vessels buffered at a fugacity of Ni-NiO and water saturation. Phase equilibria results in conjunction with mineral compositions and temperature estimates by previous workers from active lava flows and two-pyroxene geothermometry, constrain the likely pre-eruptive conditions for the Arenal magma to 950-1040° C with a water pressure of 50-80 MPa. Samples that started from conditions that bracket our estimated pre-eruptive conditions were decompressed in steps of 5-30 MPa and held for various times at each step until 20 MPa was reached, approximating average decompression rates of 0.25, 0.025, 0.0013 MPa/s. Comparison of textures found in the natural samples to the experimentally produced textures suggest that the Plinian eruption likely was fed by magma ascending at 0.05-1 m/s, whereas the less explosive phases were fed by magma ascending at 0.05 m/s or less.

  6. On the conditions of magma mixing and its bearing on andesite production in the crust. (United States)

    Laumonier, Mickael; Scaillet, Bruno; Pichavant, Michel; Champallier, Rémi; Andujar, Joan; Arbaret, Laurent


    Mixing between magmas is thought to affect a variety of processes, from the growth of continental crust to the triggering of volcanic eruptions, but its thermophysical viability remains unclear. Here, by using high-pressure mixing experiments and thermal calculations, we show that hybridization during single-intrusive events requires injection of high proportions of the replenishing magma during short periods, producing magmas with 55-58 wt% SiO2 when the mafic end-member is basaltic. High strain rates and gas-rich conditions may produce more felsic hybrids. The incremental growth of crustal reservoirs limits the production of hybrids to the waning stage of pluton assembly and to small portions of it. Large-scale mixing appears to be more efficient at lower crustal conditions, but requires higher proportions of mafic melt, producing more mafic hybrids than in shallow reservoirs. Altogether, our results show that hybrid arc magmas correspond to periods of enhanced magma production at depth.

  7. Multiplets: Their behavior and utility at dacitic and andesitic volcanic centers (United States)

    Thelen, W.; Malone, S.; West, M.


    Multiplets, or groups of earthquakes with similar waveforms, are commonly observed at volcanoes, particularly those exhibiting unrest. Using triggered seismic data from the 1980-1986 Mount St. Helens (MSH) eruption, we have constructed a catalog of multiplet occurrence. Our analysis reveals that the occurrence of multiplets is related, at least in part, to the viscosity of the magma. We also constructed catalogs of multiplet occurrence using continuous seismic data from the 2004 eruption at MSH and 2007 eruption at Bezymianny Volcano, Russia. Prior to explosions at MSH in 2004 and Bezymianny in 2007, the multiplet proportion of total seismicity (MPTS) declined, while the average amplitudes and standard deviations of the average amplitude increased. The life spans of multiplets (time between the first and last event) were also shorter prior to explosions than during passive lava extrusion. Dome-forming eruptions that include a partially solidified plug, like MSH (1983-1986 and 2004-2008), often possess multiplets with longer life spans and MPTS values exceeding 50%. Conceptually, the relatively unstable environment prior to explosions is characterized by large and variable stress gradients brought about by rapidly changing overpressures within the conduit. We infer that such complex stress fields affect the number of concurrent families, MPTS, average amplitude, and standard deviation of the amplitude of the multiplets. We also argue that multiplet detection may be an important new monitoring tool for determining the timing of explosions and in forecasting the type of eruption.

  8. Sulfur metabolizing microbes dominate microbial communities in Andesite-hosted shallow-sea hydrothermal systems.

    Directory of Open Access Journals (Sweden)

    Yao Zhang

    Full Text Available To determine microbial community composition, community spatial structure and possible key microbial processes in the shallow-sea hydrothermal vent systems off NE Taiwan's coast, we examined the bacterial and archaeal communities of four samples collected from the water column extending over a redoxocline gradient of a yellow and four from a white hydrothermal vent. Ribosomal tag pyrosequencing based on DNA and RNA showed statistically significant differences between the bacterial and archaeal communities of the different hydrothermal plumes. The bacterial and archaeal communities from the white hydrothermal plume were dominated by sulfur-reducing Nautilia and Thermococcus, whereas the yellow hydrothermal plume and the surface water were dominated by sulfide-oxidizing Thiomicrospira and Euryarchaeota Marine Group II, respectively. Canonical correspondence analyses indicate that methane (CH(4 concentration was the only statistically significant variable that explains all community cluster patterns. However, the results of pyrosequencing showed an essential absence of methanogens and methanotrophs at the two vent fields, suggesting that CH(4 was less tied to microbial processes in this shallow-sea hydrothermal system. We speculated that mixing between hydrothermal fluids and the sea or meteoric water leads to distinctly different CH(4 concentrations and redox niches between the yellow and white vents, consequently influencing the distribution patterns of the free-living Bacteria and Archaea. We concluded that sulfur-reducing and sulfide-oxidizing chemolithoautotrophs accounted for most of the primary biomass synthesis and that microbial sulfur metabolism fueled microbial energy flow and element cycling in the shallow hydrothermal systems off the coast of NE Taiwan.

  9. Groundwater circulations within a tropical humid andesitic volcanic watershed using the temperature as a tracer (United States)

    Selles, Adrien; Violette, Sophie; Hendrayana, Heru


    Groundwater flow within volcano-detritic environment, is of prime importance to many human needs and activities, from the supply of clean drinking water to the extraction of hydrocarbons or geothermal energy. However, the heterogeneity of the geological formations makes difficult to quantify the groundwater spatial distribution. Moreover, its temporal variation in tropical humid regions is sometimes poorly known. For instance, the surronding of the Merapi volcano, in Central Java, Indonesia, is an area of high but seasonal rainfall, and extensive crop irrigation. It has a large population and a need to increase food and potable water supplies depending upon exploiting groundwater ressources. The stress on these resources increases with the intensification of the demography, the agricultural practices and the industrial exploitations. In order to implement a sustainable management of the water resources, the description of the groundwater circulations and the quantification of the resources is needed. A mutidisciplinary approach has been performed at the watershed scale, including geology, hydrogeochemistry and long term hydrogeological monitoring. The data synthesis and constisency have been confirm with a numerical model of physical processes. Based on a geological and geomorphological study, the hydrogeological watershed on the Eastern flank of the Merapi volcano is composed by an alternation of aquitards (mainly ashes, tuffs and clay) and aquifers (sand, gravel and boulders). The deep aquifers are agenced in conduit following the burried channel of the paleo-rivers. The eastern flank of Merapi provides excellent example of a volcanic-sedimentary environment. From 20 cold springs of 3 spring zones, sampled on 2 hydrological years (2011 to 2013), the study of the transfer into the saturated zone from upstream to downstream, given the geological context and topography, allows to estimate the role of supply from high and low altitudes to the recharge processes. The water temperature has been used as a tracer to understand the pattern of groundwater flow and to determine the mean recharge elevation for springs. Inferences from standard oxygen and hydrogen isotopic measurements are compared with temperature measurements made at the springs to confirm the recharge elevation estimation and whether groundwater circulates to shallow or deeper depths. The METIS model, coupling groundwater flow and heat transport simulations in 2D steady flow regime, has been used in order to confirm the findings of the temperature and mean flow rate analysis and to characterize the regional flow of the multi-layered aquifer system. This approach provides methodological insights into characterization of the groundwater pathway within complex porous media in tropical humid regions. This study enable us to provide guidance on the required level of model complexity as well as on the amount and type of observations data required.

  10. Experimental determination of trace-element partitioning between pargasite and a synthetic hydrous andesitic melt (United States)

    Brenan, J. M.; Shaw, H. F.; Ryerson, F. J.; Phinney, D. L.


    In order to more fully establish a basis for quantifying the role of amphibole in trace-element fractionation processes, we have measured pargasite/silicate melt partitioning of a variety of trace elements (Rb, Ba, Nb, Ta, Hf, Zr, Ce, Nd, Sm, Yb), including the first published values for U, Th and Pb. Experiments conducted at 1000°C and 1.5 GPa yielded large crystals free of compositional zoning. Partition coefficients were found to be constant at total concentrations ranging from ˜ 1 to > 100 ppm, indicating Henry's Law is oparative over this interval. Comparison of partition coefficients measured in this study with previous determinations yields good agreement for similar compositions at comparable pressure and temperature. The compatibility of U, Th and Pb in amphibole decreases in the order Pb > Th > U. Partial melting or fractional crystallization of amphibole-bearing assemblages will therefore result in the generation of excesses in 238U activity relative to 230Th, similar in magnitude to that produced by clinopyroxene. The compatibility of Pb in amphibole relative to U or Th indicates that melt generation in the presence of residual amphibole will result in the long-term enrichment in Pb relative to U or Th in the residue. This process is therefore incapable of producing the depletion in Pb relative to U or Th inferred from the Pb isotopic composition of MORB and OIB. Comparison of partition coefficients measured in this study with previous values for clinopyroxene allows some distinction to be made between expected trace-element fractionations produced during dry (cpx present) and wet (cpx + amphibole present) melting. Rb, Ba, Nb and Ta are dramatically less compatible in clinopyroxene than in amphibole, whereas Th, U, Hf and Zr have similar compatibilities in both phases. Interelement fractionations, such as DNb/DBa are also different for clinopyroxene and amphibole. Changes in certain ratios, such as Ba/Nb, Ba/Th, and Nb/Th within comagmatic suites may therefore offer a means to discern the loss of amphibole from the melting assemblage. Elastic strain theory is applied to the partitioning data after the approaches of Beattie and Blundy and Wood and is used to predict amphibole/melt partition coefficients at conditions of P, T and composition other than those employed in this study. Given values of DCa, DTi and DK from previous partitioning studies, this approach yields amphibole/melt trace-element partition coefficients that reproduce measured values from the literature to within 40-45%. This degree of reproducibility is considered reasonable given that model parameters are derived from partitioning relations involving iron- and potassium-free amphibole.

  11. Spilitization processes in the Proterozoic Ongeluk Andesite Formation in Griqualand West, South Africa

    International Nuclear Information System (INIS)

    Schuette, S.S.; Cornell, D.H.


    The Ongeluk Formation is a thick succession of lavas which crops out over a large portion of the region. The formation thickness is poorly constrained and considered to be equivalent to the Hekpoort Basalts in the Transvaal, but large facies changes in the sedimentary formations obscure the correlation. At least two alteration events can be recognized in the Ongeluk Lava: a spilitization process, and a locally restricted hydrothermal event and oxidation process which obscures the spilitization process. The Ongeluk lavas probably covered a much greater area of Griqualand West than at present and could have provided a significant source of manganese, deposited in the Kalahari Manganese Field. A connection between the volcanic origin and alteration of the Ongeluk Formation and the Kalahari Manganese-type mineralization is demonstrated by Gresens' equations. 2 figs., 1 tab

  12. Ongeluk basaltic andesite formation in Griqualand West, South Africa: Submarine alteration in a 2222 Ma Proterozoic sea

    CSIR Research Space (South Africa)

    Cornell, DH


    Full Text Available The Ongeluk lavas form part of the Palaeoproterozoic Transvaal-Griqualand West supracrustal sequence of the Archaean Kaapvaal Craton of South Africa. They form a thick shallow-marine volcanic sequence of pillow lava, massive flows and hyaloclastite...

  13. The Dynamics of an Ongoing Andesitic Eruption: What We Have Learned From Surface Deformation at Soufriere Hills Volcano, Montserrat, BWI (United States)

    Mattioli, G.; Herd, R.; Aponte, M.; Dixon, T.; Jansma, P.; Smith, A.


    The Soufriere Hills volcano (SHV) CGPS network consists of 6 dual-frequency code-phase receivers, with Dorn-Margolin choke-ring antennae, which share a common RF telemetry network. All GPS data were processed using GIPSY-OASISII to obtain free-network point positions using final orbit, clock, and earth orientation parameters from JPL. Positions were recast into ITRF97 and these positions were used to calculate component velocities. Final site velocities for each site are reported relative a fixed Caribbean reference frame (DeMets et al., 2000). By examination of the individual time series of both the campaign and continuous sites, we have been able to divide the ground deformation observations in several distinct phases, correlated with the type of eruptive behavior manifested at the surface. While the CGPS data is limited in space, and has some important and substantial gaps because of equipment failures (some of which could not be fixed due to hazardous eruptive activity), we find that the entire GPS data set can be usefully discussed in terms of three distinct periods: (1) late 1995 to the end of 1997; (2) early 1998 to late 1999; and (3) early 2000 to the present. The primary criterion used for this distinction is the vertical velocity field. During the first period (1995-1997), all stations show strong subsidence as a function of radial distance from the SH dome (Mattioli et al., 1998). Although there is a data gap between late fall 1997 and the re-establishment of the CGPS network in early 1998, all sites show inflation at about half the rate observed for the previous period of subsidence. Thus periods of significant surface outflow (1995-1997) are strongly correlated with surface subsidence, while periods of no apparent surface magma flux are strongly correlated with ground surface inflation. Although the exact timing is somewhat equivocal, subsidence resumed at all CGPS sites just prior to the emergence of the Millennium Dome in late November to Early December 1999 and continues today. Data from each of the distinct periods has been inverted using a modified, downhill simplex method for an elastic half-space. Our code explicitly includes provision for a Mogi-type source and perpendicular opening across a planer dislocation (i.e. dike). All best-fit models have two distinct sub-surface pressure sources (deep Mogi and shallow dike oriented NW) whose initial geometry and magnitude were not fixed a priori. Inferred Mogi depths range from 4.5 to 6.0 km, with changing polarity in time, and the dimensions and inferred opening displacement of the dike have decreased from an initial maximum of ~1 m in each of the three periods. Our observations demonstrate that SHV is also affected by longer-period semi-periodic behavior, similar to that reported by Voight et al. (1998) for very short-period fluctuations on the order of 6-14 hr.

  14. The effect of kauri (Agathis australis) on grain size distribution and clay mineralogy of andesitic soils in the Waitakere Ranges, New Zealand

    NARCIS (Netherlands)

    Jongkind, A.G.; Buurman, P.


    Kauri (Agathis australis) is generally associated with intense podzolisation, but little research has been carried out to substantiate this. We studied soil profiles, grain size distribution patterns and clay mineralogy under kauri and broadleaf/tree fern vegetation in the Waitakere Ranges, North

  15. Morphological analysis of Nevado de Toluca volcano (Mexico): new insights into the structure and evolution of an andesitic to dacitic stratovolcano (United States)

    Norini, Gianluca; Groppelli, Gianluca; Capra, Lucia; De Beni, Emanuela


    We present a morphological analysis of Nevado de Toluca volcano located 80 km WSW of Mexico City based on digital elevation model study, where slope and aspect maps have been generated and analysed. Aerial photograph and satellite image observations improve the morphological analysis. The synoptic view which is offered by this analysis allowed for recognition and localization of the main volcanic and tectonic features of the area. On the basis of digital elevation model value distribution and surface textures, five morphological domains were defined. The most interesting domain, south of the crater, reflects the occurrence of an ancient complex volcano distinct from the adjacent areas. Interaction between the volcanic and volcano-tectonic evolution and the basement produced the other domains. Single volcanic edifices, like lava domes and scoria cones, and eruptive fractures were recognized. Finally, flank collapse scarps opened to the east and to the north were identified and four relevant morphostructural lineaments and their possible role in the Nevado de Toluca geological and structural evolution are discussed.

  16. Chemical and isotopic composition of high-temperature gases from the new Andesitic lava dome in the Soufriere of Saint-Vincent (Lesser Antilles)

    International Nuclear Information System (INIS)

    Allard, Patrick


    High-temperature gases emitted by the new lava dome built within the crater of the Soufriere of Saint-Vincent, in 1979, were collected. Their chemical composition and a possible deep-seated origin for carbon (mean delta 13 C=-5.5 0/00 vs PDB) are discussed here [fr

  17. Chemical and isotopic composition of high-temperature gases from the new Andesitic lava dome in the Soufriere of Saint-Vincent (Lesser Antilles)

    Energy Technology Data Exchange (ETDEWEB)

    Allard, P. (Centre des Faibles radioactivites, Gif-sur-Yvette (France))


    High-temperature gases emitted by the new lava dome built within the crater of the Soufriere of Saint-Vincent, in 1979, were collected. Their chemical composition and a possible deep-seated origin for carbon (mean delta/sup 13/C=-5.5 0/00 vs PDB) are discussed here.

  18. Hf isotope evidence for variable slab input and crustal addition in basalts and andesites of the Taupo Volcanic Zone, New Zealand

    DEFF Research Database (Denmark)

    Waight, Tod Earle; Troll, Valentin R.; Gamble, J.A.


    -Nd isotopes. Here we present new Hf isotope data for a selection of volcanic rocks and crustal lithologies fromthe Taupo Volcanic Zone (TVZ), NewZealand and propose that the scatter in Hf-Nd isotopes indicates heterogeneity in the parental magmas prior to interactions with crustal lithologies. The observed......, whereas younger lavas have probably interacted more with mid- to shallow crustal meta-sedimentary greywacke-argillite lithologies of the Permian to Cretaceous composite Torlesse Terrane. Hf-Nd isotopic compositions of meta-igneous granulite xenoliths from Mt. Ruapehu are consistent with previous...

  19. Las Andesitas Estrechura del Complejo Volcánico Piroclástico del Río Chubut Medio (Paleoceno-Eoceno Medio) The Estrechura Andesites from the Middle Rio Chubut Volcanic-Pyroclastic Complex (Paleocene-Middle Eocene)


    E. Aragón; Y.E. Aguilera; V.C. Consoli; C.E. Cavarozzi; A. Ribot


    Las Andesitas Estrechura muestran una tendencia evolutiva basalto-traquita del tipo toleítico transicional. En esta secuencia la inmisciblidad líquida está presente desde los basaltos hasta las traquitas. Esto permite establecer que: los basaltos y traquibasaltos representan el magma que se está fraccionando; las traquiandesitas son la mezcla de magma basáltico enriquecido con líquido inmiscible y las traquitas son el líquido inmiscible alojado en el techo de la cámara magmática. Aunque estos...

  20. Determination of aggregate morphological properties using laser and their effects on rutting of asphalt mixes

    CSIR Research Space (South Africa)

    Anochie-Boateng, Joseph


    Full Text Available Andesite grading with andesite fines; 2Dolerite grading with andesite fines 3Chrome slag grading with slag fines FIGURE 2 Example of aggregate particles scanned for this study. Sampling for Scanning Wet sieve analysis tests were conducted... analyses. The mathematical details of the use of spherical harmonic analysis techniques to analyse laser scanning of aggregates are presented by (14). Figure 5 shows shape indices results plotted against the aggregate sieve sizes for the three...

  1. Sr–Nd isotopic compositions of Paleoproterozoic metavolcanic rocks from the southern Ashanti volcanic belt, Ghana


    Dampare, Samuel; Shibata, Tsugio; Asiedu, Daniel; Okano, Osamu; Manu, Johnson; Sakyi, Patrick


    Neodymium (Nd) and strontium (Sr) isotopic data are presented for Paleoproterozoic metavolcanic rocks in the southern part of the Ashanti volcanic belt of Ghana. The metavolcanic rocks are predominantly basalts/basaltic andesites and andesites with minor dacites. Two types of basalts/basaltic andesites (B/A), Type I and Type II, have been identified. The Type I B/A are stratigraphically overlain by the Type II B/A, followed by the andesites and the dacites. The analyzed volcanic rocks commonl...

  2. Research of mountain rocks of Georgia for using in glass materials industry

    International Nuclear Information System (INIS)

    Gabunia, L.; Gabunia, N.; Jakhva, N.; Napetvaridze, Ts.; Alibegashvili, M.


    The article presents the results of the research of mountain rocks of Georgia in various peaces of basalts, andesite, andesite-basalt porphyry and trachite deposits in order to be used in the industry of fiber, glass-crystal materials and fasade decorative tiles. The prospects of basalt and andesite-basalt porphyry use in the industry of fiber materials in the form of monocomponents has been stated. The technology of obtaining of wear resistant, chemically stable and colored glass-crystal on the basis of andesit and trachyte, has been worked out and approved in industry. (author)

  3. K-Ar age data and geochemistry of the Kiwitahi Volcanics, western Hauraki Rift, North Island, New Zealand

    Energy Technology Data Exchange (ETDEWEB)

    Black, P M [Department of Geology, Auckland University, Auckland (New Zealand); Briggs, R M [Department of Earth Sciences, Waikato University, Hamilton (New Zealand); Itaya, T [Hiruzen Research Institute, Okayama University of Science, Okayama (Japan); Dewes, E R [Department of Earth Sciences, Waikato University, Hamilton (New Zealand); Dunbar, H M [Department of Earth Sciences, Waikato University, Hamilton (New Zealand); Kawasaki, K [Hiruzen Research Institute, Okayama University of Science, Okayama (Japan); Kuschel, E [Department of Geology, Auckland University, Auckland (New Zealand); Smith, I E.M. [Department of Geology, Auckland University, Auckland (New Zealand)


    The Kiwitahi Volcanics of late Miocene age crop out in a number of localities situated along the western side of the Hauraki Rift in northern North Island, New Zealand. They extend from Waiheke Island in the north to Te Tapui in the south. From 19 new K-Ar ages presented here and geochemical data from volcanics at each locality, it is suggested that the Kiwitahi Volcanics should be informally subdivided into five groups: (1) an oldest group of agglomerates and volcanic breccias at northeastern Waiheke, containing pyroxene and hornblende andesites with an age range of 14.4-16.02 Ma; (2) a volcanic centre at Stony Batter (6.85-8.34 Ma) comprised of olivine basaltic andesites which should be assigned to the geochemically and temporally similar Ti Point Volcanics; (3) a group including the andesitic breccias at Ness Valley and the volcanic centres of Miranda (pyroxene basaltic andesite, pyroxene and hornblende andesite, hornblende dacite) and Pukekamaka (hornblende andesites), all within the age range 10.22-12.96 Ma; (4) a separate group at Tahuna (6.36-6.80 Ma) consisting of pyroxene basaltic andesites and pyroxene andesites; and (5) a southern group of Maungatapu, Ruru, Maungakawa, and Te Tapui (5.52-6.23 Ma), forming eroded cones of olivine basaltic andesites, pyroxene basaltic andesites, and pyroxene andesites. The Kiwitahi Volcanics of late Miocene age crop out in a number of localities situated along the western side of the Hauraki Rift in northern North Island, New Zealand. They extend from Waiheke Island in the north to Te Tapui in the south. From 19 new K-Ar ages presented here and geochemical data from volcanics at each locality, it is suggested that the Kiwitahi Volcanics should be informally subdivided into five groups: (1) an oldest group of agglomerates and volcanic breccias at northeastern Waiheke, containing pyroxene and hornblende andesites with an age range of 14.4-16.02 Ma; (2) a volcanic centre at Stony Batter (6.85-8.34 Ma) comprised of olivine

  4. K-Ar age data and geochemistry of the Kiwitahi Volcanics, western Hauraki Rift, North Island, New Zealand

    International Nuclear Information System (INIS)

    Black, P.M.; Briggs, R.M.; Itaya, T.; Dewes, E.R.; Dunbar, H.M.; Kawasaki, K.; Kuschel, E.; Smith, I.E.M.


    The Kiwitahi Volcanics of late Miocene age crop out in a number of localities situated along the western side of the Hauraki Rift in northern North Island, New Zealand. They extend from Waiheke Island in the north to Te Tapui in the south. From 19 new K-Ar ages presented here and geochemical data from volcanics at each locality, it is suggested that the Kiwitahi Volcanics should be informally subdivided into five groups: (1) an oldest group of agglomerates and volcanic breccias at northeastern Waiheke, containing pyroxene and hornblende andesites with an age range of 14.4-16.02 Ma; (2) a volcanic centre at Stony Batter (6.85-8.34 Ma) comprised of olivine basaltic andesites which should be assigned to the geochemically and temporally similar Ti Point Volcanics; (3) a group including the andesitic breccias at Ness Valley and the volcanic centres of Miranda (pyroxene basaltic andesite, pyroxene and hornblende andesite, hornblende dacite) and Pukekamaka (hornblende andesites), all within the age range 10.22-12.96 Ma; (4) a separate group at Tahuna (6.36-6.80 Ma) consisting of pyroxene basaltic andesites and pyroxene andesites; and (5) a southern group of Maungatapu, Ruru, Maungakawa, and Te Tapui (5.52-6.23 Ma), forming eroded cones of olivine basaltic andesites, pyroxene basaltic andesites, and pyroxene andesites. The Kiwitahi Volcanics of late Miocene age crop out in a number of localities situated along the western side of the Hauraki Rift in northern North Island, New Zealand. They extend from Waiheke Island in the north to Te Tapui in the south. From 19 new K-Ar ages presented here and geochemical data from volcanics at each locality, it is suggested that the Kiwitahi Volcanics should be informally subdivided into five groups: (1) an oldest group of agglomerates and volcanic breccias at northeastern Waiheke, containing pyroxene and hornblende andesites with an age range of 14.4-16.02 Ma; (2) a volcanic centre at Stony Batter (6.85-8.34 Ma) comprised of olivine

  5. Wynoochee Dam Foundation Report (United States)


    schists and in propylitized andesite volcanic rocks. Tests on chlorite-bearing graywackes (Lumni Island and Robe Quarry, Seattle District) and... propylitized chlorite-bearing andesites (Blue River and Lookout Point Dams, Portland District) have shown these rocks to be durable materials with only minor

  6. Magmatic controls on eruption dynamics of the 1950 yr B.P. eruption of San Antonio Volcano, Tacaná Volcanic Complex, Mexico-Guatemala (United States)

    Mora, Juan Carlos; Gardner, James Edward; Macías, José Luis; Meriggi, Lorenzo; Santo, Alba Patrizia


    San Antonio Volcano, in the Tacaná Volcanic Complex, erupted ~ 1950 yr. B.P., with a Pelean type eruption that produced andesitic pyroclastic surges and block-and-ash flows destroying part of the volcano summit and producing a horse-shoe shaped crater open to the SW. Between 1950 and 800 yr B.P. the eruption continued with effusive andesites followed by a dacite lava flow and a summit dome, all from a single magma batch. All products consist of phenocrysts and microphenocrysts of zoned plagioclase, amphibole, pyroxene, magnetite ± ilmenite, set in partially crystallized groundmass of glass and microlites of the same mineral phases, except for the lack of amphibole. Included in the andesitic blocks of the block-and-ash flow deposit are basaltic andesite enclaves with elongated and ellipsoidal forms and chilled margins. The enclaves have intersertal textures with brown glass between microphenocrysts of plagioclase, hornblende, pyroxene, and olivine, and minor proportions of phenocrysts of plagioclase, hornblende, and pyroxene. A compositional range obtained of blocks and enclaves resulted from mixing between andesite (866 °C ± 22) and basaltic andesite (enclaves, 932 °C ± 22), which may have triggered the explosive Pelean eruption. Vestiges of that mixing are preserved as complex compositional zones in plagioclase and clinopyroxene-rich reaction rims in amphibole in the andesite. Whole-rock chemistry, geothermometry, experimental petrology and modeling results suggest that after the mixing event the eruption tapped hybrid andesitic magma (≤ 900 °C) and ended with effusive dacitic magma (~ 825 °C), all of which were stored at ~ 200 MPa water pressure. A complex open-system evolution that involved crustal end-members best explains the generation of effusive dacite from the hybrid andesite. Amphibole in the dacite is rimmed by reaction products of plagioclase, orthopyroxene, and Fe-Ti oxides produced by decompression during ascent. Amphibole in the andesite

  7. Paleocene on-spreading-axis hotspot volcanism along the Ninetyeast Ridge: An interaction between the Kerguelen hotspot and the Wharton spreading center

    Digital Repository Service at National Institute of Oceanography (India)

    Krishna, K.S.; Gopala Rao, D.; SubbaRaju, L.V.; Chaubey, A.K.; Shcherbakov, V.S.; Pilipenko, A.I.; Murthy, I.V.R.

    with magnetic lineations and abondoned spreading centers of the eastern Indian Ocean and seismic structure and radiometric dates of the Ninetyeast Ridge. Furthermore, it is supported by the occurrence of oceanic andesites at Deep Sea Drilling Project (DSDP) Site...

  8. June 1991 Pinatubo, Philippines Images (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Mount Pinatubo is an andesitic island arc volcano, located on the southwestern part of the island of Luzon in the Philippines. Prior to 1991, it had been dormant for...

  9. Mineralization and geochemical studies in the Kalchouyeh occurrence, southwest of Naein


    Hengameh Hosseini Dinani; Hashem Bagheri; Reza Shamsipour Dehkordi


    Kalchouyeh area in southwest of Naein is located in the Urumieh-Dokhtar volcano-plutonic belt. Mineralization occurred mainly as disseminations and veinlets hosted by trachy-andesite and pyroxene andesites. For mineralogy, alteration, fluid inclusion and geochemical studies, the two major mineralized zones: A (larger vein) from the north-northwest and B (smaller vein) from the east-southeast of the area were sampled. Alteration studies revealed that the main alteration assemblages are silicif...

  10. Evaluation of Resistance to Los Angeles Abrasion and Physical Factors with Grindability Properties of Some Aggregate Materials

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    C. Sensogut


    Full Text Available In recent years, the usage of aggregate materials has increased both in Turkey and the entire world. It can be said that the main reason of this rise is the population growth together with the demand towards the more qualitative life. Therefore, the usability of some aggregate materials was investigated in the present paper. The properties of Los Angeles abrasion resistance, freezing-thaw resistance, slake durability strength and frost resistance of basalt and andesite samples obtained from Karaman and Ankara regions were studied at the first stage. In the second order, the grindability performance of these materials was also determined from the discontinuous grinding tests and the obtained results were correlated. Whereas the Los Angeles resistance of the basalt sample was higher than the andesite sample, the mass losses after the freezing-thaw and the frost tests for the andesite sample were superior. Both of the basalt and andesite samples were classified as ‘very high’ for their slake durability strength (Id-2 values. The material percentage of the andesite sample, which is passing through the sub-size ( %90 was greater than the value obtained for the basalt sample during the same grinding time. The resistance to the crushing process was obtained to be maximum at -850+600 µm of feed size for the basalt and the andesite samples.

  11. Clay mineralogy and geochemistry of the soils derived from metamorphic and mafic igneous parent rocks in Lahijan area

    International Nuclear Information System (INIS)

    Ramezanpour, H.; Hesami, R.; Zanjanchi, M. A.


    The mineralogical and geochemical composition of the soils of three representative pedons formed on basaltic andesite, andesitic basalt and phyllite were investigated. Results by x-ray diffraction showed that progressive weathering of rocks have been marked by gradual accumulation of Al, Fe, Ti, Mg, H 3 O + and depletion of Na, K, Ca and Si in the soil; although, predominant clay, loss and gain trend of elements was different on the various rocks. Based on x-ray diffraction analysis, minerals in basaltic andesite and andesitic basalt were similar but, the intensity of mica to smectite or vermiculite transformation for latter was relatively higher than the former. This process revealed the degradation mineral because of two reasons: (i) - smectite and vermiculite increased whereas mica decreased in surface horizons. (i i)-Irregular mixed layer of mica-smectite or vermiculite was present in deeper part (170 cm) of the soils from andesitic basalt but shallower depth (75 em) of the soils from basaltic andesite. Clay minerals in phyllite were mica and chlorite that stratified with vermiculite. However, the absence of smectite in phyllite might be attributed to more acidic condition or position of the Fe ion in the mineral lattice of chlorite (higher Fe in the interlayer hydroxide sheet)

  12. Neogene volcanism in Gutai Mts. (Eastern Carpathains: a review

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    Marinel Kovacs


    Full Text Available Two types of volcanism developed in Gutâi Mts. (inner volcanic chain of Eastern Carpathians: a felsic, extensional/“back-arc” type and an intermediate, arc type. The felsic volcanism of explosive origin, consisting of caldera-related rhyolitic ignimbrites and resedimented volcaniclastics, had taken place during Early-Middle Badenian and Early Sarmatian. The intermediate volcanism, consisting of extrusive (effusive and explosive and intrusive activity, had developed during Sarmatian and Pannonian (13.4-7.0 Ma. It is represented by typical calc-alkaline series, from basalts to rhyolites. Lava flows of basaltic andesites and andesites are predominant, often emplaced in subaqueous environment. Extrusive domes, mainly composed of dacites, are associated to the andesitic volcanic structures. The intermediate volcanism, consisting of extrusive (effusive and explosive and intrusive activity, had developed during Sarmatian and Pannonian (13.4-7.0 Ma. It is represented by typical calc-alkaline series, from basalts to rhyolites. Lava flows of basaltic andesites and andesites are predominant, often emplaced in subaqueous environment. Extrusive domes, mainly composed of dacites, are associated to the andesitic volcanic structures. The geochemical study on the volcanic rocks shows the calc-alkaline character of both felsic and intermediate volcanism and typical subduction zones geochemical signatures for the intermediate one. The felsic volcanism shows affinities with subduction-related rocks as well. The main petrogenetic process in Gutâi Mts. was crustal assimilation, strongly constrained by trace element and isotope geochemistry.

  13. Post-Eocene volcanics of the Abazar district, Qazvin, Iran: Mineralogical and geochemical evidence for a complex magmatic evolution (United States)

    Asiabanha, A.; Bardintzeff, J. M.; Kananian, A.; Rahimi, G.


    The style of volcanism of post-Eocene volcanism in the Alborz zone of northern Iran is different to that of Eocene volcanism (Karaj Formation). Indeed, the volcanic succession of the Abazar district, located in a narrow volcanic strip within the Alborz magmatic assemblage, is characterized by distinct mineralogical and chemical compositions linked to a complex magmatic evolution. The succession was produced by explosive eruptions followed by effusive eruptions. Two main volcanic events are recognized: (1) a thin rhyolitic ignimbritic sheet underlain by a thicker lithic breccia, and (2) lava flows including shoshonite, latite, and andesite that overlie the first event across a reddish soil horizon. Plagioclase in shoshonite (An 48-92) shows normal zoning, whereas plagioclase in latite and andesite (An 48-75) has a similar composition but shows reverse and oscillatory zoning. QUILF temperature calculations for shoshonites and andesites yield temperatures of 1035 °C and 1029 °C, respectively. The geothermometers proposed by Ridolfi et al. (2010) and Holland and Blundy (1994) yield temperatures of 960 °C and 944 °C for latitic lava, respectively. The samples of volcanic rock show a typical geochemical signature of the continental arc regime, but the andesites clearly differ from the shoshonites, the latites and the rhyolites. The mineralogical and chemical characteristics of these rocks are explained by the following petrogenesis: (1) intrusion of a hot, mantle-depth mafic (shoshonitic) magma, which differentiated in the magma chamber to produce a latitic and then a rhyolitic liquid; (2) rhyolitic ignimbritic eruptions from the top of the magma chamber, following by shoshonitic and then latitic extrusions; (3) magma mingling between the latitic and andesitic magmas, as indicated by the occurrence of andesite clasts within the latite; and (4) andesitic effusions. The youngest volcanic events in the Alborz zone show a close chemical relationship with continental arc

  14. Geochemical studies of abyssal lavas recovered by DSRV Alvin from Eastern Galapagos Rift, Inca Transform, and Ecuador Rift: 2. Phase chemistry and crystallization history (United States)

    Perfit, Michael R.; Fornari, Daniel J.


    A diverse suite of lavas recovered by DSRV Alvin from the eastern Galapagos rift and Inca transform includes mid-ocean ridge tholeiitic basalts (MORB), iron- and titanium-enriched basalts (FeTi basalts), and abyssal andesites. Rock types transitional in character (ferrobasalts and basaltic andesites) were also recovered. The most mafic glassy basalts contain plagioclase, augite, and olivine as near-liquidus phases, whereas in more fractionated basalts, pigeonite replaces olivine and iron-titanium oxides crystallize. Plagioclase crystallizes after pyroxenes and iron-titanium oxides in andesites, possibly due to increased water contents or cooling rates. Apatite phenocrysts are present in some andesitic glasses. Ovoid sulfide globules are also common in many lavas. Compositional variations of phenocrysts in glassy lavas reflect changes in magma chemistry, temperature of crystallization, and cooling rate. The overall chemical variations parallel the chemical evolution of the lava suite and are similar to those in other fractionated tholeiitic complexes. Elemental partitioning between plagioclase-, pyroxene-, and olivine-glass pairs suggests that equilibration occurred at low pressure in a rather restricted temperature range. Various geothermometers indicate that the most primitive MORB began to crystallize between 1150° and 1200°C with fo2 PH 2 o could have been as high as 1 kbar during andesite crystallization. Compositions of the lavas from the Galapagos rift follow the experimentally determined (1 atm-QFM) liquid line of descent. Least squares calculations for the major elements indicate that the entire suite of lavas can be produced by fractional crystallization of successive residual liquids from a MORB parent magma. FeTi basalts represent 30-65 cumulative weight percent crystallization of plagioclase, augite, and olivine. An additional 30-50% fractionation of pyroxenes, plagioclase, titanomagnetite, and possible apatite is required to generate andesite from Fe

  15. Petrographic Analysis and Geochemical Source Correlation of Pigeon Peak, Sutter Buttes, CA (United States)

    Novotny, N. M.; Hausback, B. P.


    The Sutter Buttes are a volcanic complex located in the center of the Great Valley north of Sacramento. They are comprised of numerous inter-intruding andesite and rhyolite lava domes of varying compositions surrounded by a shallow rampart of associated tephras. The Pigeon Peak block-and-ash flow sequence is located in the rampart and made up of a porphyritic Biotite bearing Hornblende Andesite. The andesite blocks demonstrate a high degree of propylization in hornblende crystals, highly zoned plagioclase, trace olivine, and display a red to gray color gradation. DAR is an andesite dome located less than one mile from Pigeon Peak. Of the 15 to 25 andesite lava domes within four miles from Pigeon Peak, only DAR displays trace olivine, red to grey color stratification, low biotite content, and propylitized hornblende. These characteristic similarities suggest that DAR may be the source for Pigeon Peak. My investigation used microprobe analysis of the DAR and Pigeon Peak feldspar crystals to identify the magmatic history of the magma body before emplacement. Correlation of the anorthite zoning within the feldspars from both locations support my hypothesis that DAR is the source of the Pigeon Peak block-and-ash flow.

  16. Geology and zircon fission track ages of volcanic rocks in the western part of Hoshino gold area, Fukuoka Prefecture, Japan

    Energy Technology Data Exchange (ETDEWEB)

    Belhadi, Ahmed; Himeno, Osamu; Watanabe, Koichiro; Izawa, Eiji [Kyushu Univ., Fukuoka (Japan). Faculty of Engineering


    The Hoshino gold area is located in the western part of the Hohi volcanic zone, northern Kyushu. Volcanic rocks in this area vary from andesitic rocks in the north to dacite and rhyolite in the South. The basement is constituted by metamorphic rocks of pre-Cretaceous age. The volcanic rocks of Pliocene age were subdivided into eight volcanic units. Seven fission track ages of zircons from five volcanic units have been determined, using the external detector method. The age data obtained, combined with some previously reported ages, show that two main volcanic activities have occurred in the area. The first volcanic activity took place around 4.3 Ma, and resulted into the deposition of the Hoshino Andesite and the Ikenoyama Conglomerate. The second main volcanism started around 3.5 Ma, and was characterized by the eruption of the Shakadake Andesite and the Reiganji Andesite at the early stage, then, by more acidic rocks of the Takeyama Andesite, the Hyugami Dacite and the Kuroki Rhyolite at the later stage. The main volcanism in the area ceased around 2.6 Ma. (author)

  17. The Mount Edgecumbe tephra deposits, a marker horizon in southeastern Alaska near the Pleistocene-Holocene boundary (United States)

    Riehle, J.R.; Mann, D.H.; Peteet, D.M.; Engstrom, D.R.; Brew, D.A.; Meyer, C.E.


    Late Pleistocene tephra deposits found from Sitka to Juneau and Lituya Bay are assigned to a source at the Mount Edgecumbe volcanic field, based on similarity of glass compositions to nearvent deposits and on thinning away from Kruzof Island. The sequence of near-vent layers is basaltic andesite and andesite at the base, rhyolite, and mixed dacite and rhyolite on top. The only breaks in the tephra sequence are two 1-mm-thick silt partings in a lake-sediment core, indicating a depositional interval from basaltic andesite to dacite of no more than about a millennium. Tephra deposits at sites >30 km from the vent are solely dacite and rhyolite and are 10,600 to 11,400 14C yr old based on interpretation of 18 radiocarbon ages, including 5 by accelerator mass spectrometry (AMS). Basaltic andesite and andesite deposits nearer the vent are as much as 12,000 yr old. Discrepancy among radiocarbon ages of upland tephra deposits provisionally correlated as the same grainfall is resolvable within ??2 ?? of analytical uncertainty. Comparison of bulk and AMS ages in one sediment core indicates a systematic bias of +600 to +1100 yr for the bulk ages; correlation of tephra deposits among upland and lacustrine sites implies an additional discrepancy of 200-400 yr between upland (relatively too young) and lacustrine ages. In any case, the Mount Edgecumbe tephra deposits are a widespread, latest Pleistocene stratigraphic marker that serves to emphasize the uncertainty in dating biogenic material from southeastern Alaska. ?? 1992.

  18. Permian arc evolution associated with Panthalassa subduction along the eastern margin of the South China block, based on sandstone provenance and U-Pb detrital zircon ages of the Kurosegawa belt, Southwest Japan (United States)

    Hara, Hidetoshi; Hirano, Miho; Kurihara, Toshiyuki; Takahashi, Toshiro; Ueda, Hayato


    We have studied the petrography, geochemistry, and detrital zircon U-Pb ages of sandstones from shallow-marine forearc sediments, accretionary complexes (ACs), and metamorphosed accretionary complexes (Meta-ACs) within the Kurosegawa belt of Southwest Japan. Those rocks formed in a forearc region of a Permian island arc associated with subduction of the Panthalassa oceanic crust along the eastern margin of the South China block (Yangtze block). The provenance of the shallow-marine sediments was dominated by basaltic to andesitic volcanic rocks and minor granitic rocks during the late Middle to Late Permian. The ACs were derived from felsic to andesitic volcanic rocks during the Late Permian. The provenance of Meta-ACs was dominated by andesitic volcanic rocks in the Middle Permian. The provenance, source rock compositions, and zircon age distribution for the forearc sediments, ACs and Meta-ACs have allowed us to reconstruct the geological history of the Permian arc system of the Kurosegawa belt. During the Middle Permian, the ACs were accreted along the eastern margin of the South China block. The Middle Permian arc was an immature oceanic island arc consisting of andesitic volcanic rocks. During the Late Permian, the ACs formed in a mature arc, producing voluminous felsic to andesitic volcanic rocks. A forearc basin developed during the late Middle to Late Permian. Subsequently, the Middle Permian ACs and part of the Late Permian AC underwent low-grade metamorphism in the Late to Early Jurassic, presenting the Meta-ACs.

  19. Tungsten abundances in some volcanic rocks

    International Nuclear Information System (INIS)

    Helsen, J.N.; Shaw, D.M.; Crocket, J.H.


    A radiochemical N.A.A. method was used to obtain new values on W distribution in some 125 volcanic rocks, mainly basalts and andesites, from different petrotectonic environments. These W data are below previously reported abundances. New median values in various types of rocks are suggested (ppm W). Basalts: ocean floor, 0.15; ocean islands subalkaline, 0.28; ocean islands alkaline, 0.60; island arc, 0.19; continental margin, 0.40; continental subalkaline, 0.30; continental alkaline, 1.35. Andesites: island arc, 0.23; continental margin, 1.05. Median values for all 91 basalts and all 20 andesites are 0.36 and 0.29 ppm respectively. (author)

  20. The Park Volcanics Group : field relations of an igneous suite emplaced in the Triassic-Jurassic Murihiku Terrane, South Island, New Zealand

    International Nuclear Information System (INIS)

    Coombs, D.S.; Cook, N.D.J.; Campbell, J.D.


    Park Volcanics Group is proposed for igneous rocks, either shallow intrusive or extrusive, emplaced in the Murihiku Terrane during Triassic-Jurassic times. The term replaces Park Intrusives of Mutch, some members of which are shown to be extrusive rather than intrusive. Formation status within the group is given to Gowan Andesite and Pinney Volcanics (new names) in western Southland, Glenham Porphyry in eastern Southland, and Barnicoat Andesite (new) in the Richmond area, Nelson. Gowan Andesite is a porphyritic feldspar two-pyroxene andesite with a glassy or microcrystalline groundmass. A suite of low-grade metavolcanic rocks which forms the main mass of Malakoff Hill and which has formerly been included in the 'Park Intrusives' is here excluded and ascribed to the Takitimu Group; representative chemical data are given. Glenham Porphyry is typically a porphyritic feldspar two-pyroxene andesite texturally similar to the Gowan Andesite but with significant geochemical differences. Two volumetrically minor members are recognised, Habukinini Trachydacite and Kenilworth Rhyolite. In the north of its outcrop area, Glenham Porphyry is emplaced on or into Late Triassic terrestrial beds; in the middle it overlies Kaihikuan (Middle Triassic) and is overlain by Otapirian (latest Triassic) marine beds; and in the southeast it is directly overlain by Ururoan (late Early to early Middle Jurassic) conglomerates and marine sandstones. Pinney Volcanics are restricted to a very few, probably one, massive conglomeratic horizon in the Oretian Stage. The commonest rock type is a two-pyroxene trachydacite, modified by very-low-grade burial metamorphism. Auto-brecciation is characteristic and rock types change over short distances. Hornblende-rich variants occur as well as more felsic varieties including rhyolite ignimbrite. These may have been erupted onto a bouldery floodplain or shallow-marine surface, but alternatively may have been mass-emplaced by debris avalanche resulting from

  1. The evolution of hydrous magmas in the Tongariro Volcanic Centre : the 10 ka Pahoka-Mangamate eruptions

    International Nuclear Information System (INIS)

    Auer, A.; Palin, J.M.; White, J.D.L.; Nakagawa, M.; Stirling, C.


    The majority of arc-type andesites in the Tongariro Volcanic Centre are highly porphyritic, hornblende-free, two-pyroxene andesites. An exception is tephras from the c. 10,000 ka Pahoka-Mangamate event. Magmas of these Plinian eruptions bypassed the extensive crustal mush columns under the central volcanoes and sequentially derived a series of almost aphyric rocks spanning a compositional range from dacite to basaltic andesite. Mineral composition, trace element and isotopic data suggest that this eruptive series tapped a mid-crustal magma reservoir, resulting in the initial eruption of an hydrous dacitic magma and several following eruptions characterised by less-evolved and less-hydrous compositions at progressively higher temperatures and substantially lower 87 Sr/ 86 Sr ratios. Systematic changes in magma chemistry are also reflected in a sequential change in phenocryst content starting with an early hornblende-plagioclase-dominated assemblage to a late olivine-plagioclase-dominated assemblage. (author).

  2. Storage conditions of the mafic and silicic magmas at Cotopaxi, Ecuador (United States)

    Martel, Caroline; Andújar, Joan; Mothes, Patricia; Scaillet, Bruno; Pichavant, Michel; Molina, Indira


    The 2015 reactivation of the Cotopaxi volcano urges us to understand the complex eruptive dynamics of Cotopaxi for better management of a potential major crisis in the near future. Cotopaxi has commonly transitioned from andesitic eruptions of strombolian style (lava flows and scoria ballistics) or nuées ardentes (pyroclastic flows and ash falls) to highly explosive rhyolitic ignimbrites (pumiceous pyroclastic flows), which entail drastically different risks. To better interpret geophysical and geochemical signals, Cotopaxi magma storage conditions were determined via existing phase-equilibrium experiments that used starting materials chemically close to the Cotopaxi andesites and rhyolites. The results suggest that Cotopaxi's most mafic andesites (last erupted products) can be stored over a large range of depth from 7 km to ≥16 km below the summit (pressure from 200 to ≥400 MPa), 1000 °C, NNO +2, and contain 4.5-6.0±0.7 wt% H2O dissolved in the melt in equilibrium with 30-40% phenocrysts of plagioclase, two pyroxenes, and Fe-Ti oxides. These mafic andesites sometimes evolve towards more silicic andesites by cooling to 950 °C. Rhyolitic magmas are stored at 200-300 MPa (i.e. 7-11 km below the summit), 750 °C, NNO +2, and contain 6-8 wt% H2O dissolved in a nearly aphyric melt (<5% phenocrysts of plagioclase, biotite, and Fe-Ti oxides). Although the andesites produce the rhyolitic magmas by fractional crystallization, the Cotopaxi eruptive history suggests reactivation of either reservoirs at distinct times, likely reflecting flux or time fluctuations during deep magma recharge.

  3. Digital data for preliminary geologic map of the Mount Hood 30- by 60-minute quadrangle, northern Cascade Range, Oregon (United States)

    Lina Ma,; Sherrod, David R.; Scott, William E.


    The Mount Hood 30- by 60-minute quadrangle covers the axis and east flank of the Cascade Range in northern Oregon. Its namesake, Mount Hood volcano, dominates the view in the northwest quarter of the quadrangle, but the entire area is underlain by Oligocene and younger volcanic and volcaniclastic rocks of the Cascade Range. Since the time of the Columbia River Basalt Group about 15 million years (m.y.) ago, the locus and composition of Cascade Range volcanism have shifted sporadically across the map area. Andesitic eruptions were predominant in the western part from about 14 to 10 m.y. ago (Salmon and Sandy Rivers area), producing the Rhododendron Formation and overlying lava flows. From about 8 to 6.5 m.y. ago, lithic pyroclastic debris of the Dalles Formation was shed by chiefly andesitic volcanoes in the north-central part of the map area (Hood River valley escarpment). Andesitic to dacitic volcanism was again predominant about 5 to 3 m.y. ago, with known eruptive centers located from Lookout Mountain westward to Lolo Pass, probably including the area now occupied by Mount Hood. A major episode of mafic volcanism-basalt and basaltic andesite-began about 3-4 m.y. ago and lasted until about 2 m.y. ago. Volcanism since about 2 m.y. ago has been concentrated along the axis of the High Cascades. North and south of Mount Hood these youngest rocks are predominantly basaltic andesite lava flows; whereas at Mount Hood itself, andesite is predominant, forming pyroclastic and debris-flow deposits and lava flows.

  4. Orientation of the eruption fissures controlled by a shallow magma chamber in Miyakejima

    Directory of Open Access Journals (Sweden)

    Nobuo Geshi


    Full Text Available Orientation of the eruption fissures and composition of the lavas of the Miyakejima volcano indicate tectonic influence of a shallow magma chamber on the distribution of eruption fissures. We examined the distributions and magmatic compositions of 23 fissures that formed within the last 2800 years, based on a field survey and a new dataset of 14C ages. The dominant orientation of the eruption fissures in the central portion of the volcano was found to be NE-SW, which is perpendicular to the direction of regional maximum horizontal compressive stress (σHmax. Magmas that show evidences of magma mixing between basaltic and andesitic magmas erupted mainly from the eruption fissures with a higher offset angle from the regional σHmax direction. The presence of a shallow dike-shaped magma chamber controls the distribution of the eruption fissures. The injection of basaltic magma into the shallow andesitic magma chamber caused the temporal rise of internal magmatic pressure in the shallow magma chamber. Dikes extending from the andesitic magma chamber intrude along the local compressive stress field which is generated by the internal excess pressure of the andesitic magma chamber. As the result, the eruption fissures trend parallel to the elongation direction of the shallow magma chamber. Injection of basaltic magma into the shallow andesitic magma chamber caused the magma mixing. Some basaltic dikes from the deep-seated magma chamber reach the ground surface without intersection with the andesitic magma chamber. The patterns of the eruption fissures can be modified in the future as was observed in the case of the destruction of the shallow magma chamber during the 2000 AD eruption.

  5. Petrography and geochemistry of lithic fragments in ignimbrites from the Mangakino Volcanic Centre : implications for the composition of the subvolcanic crust in western Taupo Volcanic Zone, New Zealand

    International Nuclear Information System (INIS)

    Krippner, S.J.P.; Briggs, R.M.; Wilson, C.J.N.; Cole, J.W.


    The Mangakino Volcanic Centre is the westernmost and oldest rhyolitic caldera volcano in the Taupo Volcanic Zone, North Island, New Zealand. The largest eruptions from Mangakino occurred in two periods of caldera-forming activity during the 1.68-1.53 Ma (Period I), and 1.21-0.95 Ma (Period IIA), producing several voluminous widespread welded and nonwelded ignimbrites and minor fall deposits. Other activity from Mangakino generated fall deposits and rhyolitic lava domes. Lithic fragments are common in all Mangakino ignimbrites (1-10 modal %), and consist of diverse lithologies including: rhyolite, dacite, andesite, and basaltic andesite lava, welded ignimbrite, tuff, volcanic breccia, biotite granite, granodiorite porphyry, siltstone, sandstone, greywacke, metagreywacke, metaconglomerate, biotite and hornblende-biotite schist. Lithic populations in Period I ignimbrites are dominated by andesite lavas, suggesting that there was a pre-existing andesite volcano in the Mangakino area, geochemically distinct from Titiraupenga and Pureora, the nearest roughly contemporaneous andesitic volcanoes. Later ignimbrites that erupted during Period IIA, contain predominantly rhyolitic lava lithics, implying that significant dome building activity occurred at Mangakino, which represented greater volumes of rhyolitic lava than previously described from the area. Petrographic, geochemical, and geophysical (density and magnetic susceptibility) data measured from the lithic fragments are used to propose a model for the shallow crust below Mangakino Volcanic Centre. This model postulates eruptions through a basement of Mesozoic biotite schists overlain by metagreywackes, a thin cover of Tertiary sandstones and siltsones, and an overlying volcanic succession of andesite, dacite and rhyolite lavas, welded ignimbrites, and lacustrine sediments. Ignimbrite eruptions incorporated comagmatic biotite granite fragments from the crystallised margins of the silicic magma chambers, and effectively

  6. New K-Ar ages of volcanic rocks and associated mineralization in Canada Honda district, San Luis, Argentina

    International Nuclear Information System (INIS)

    Urbina, N.E.; Oggier, F.P


    New K-Ar ages in the Late Tertiary gold-bearing volcanic belt of the Sierras Pampeanas of San Luis, Argentina are presented. At Canada Honda district, an age of 8.49±0.2 Ma yielded by Cerro del Valle andesite indicates that the dome emplacement postdates the Diente Verde eruptive event. An even younger age of 7.3±0.2 Ma was obtained for illite from hydrothermal alteration at La Reynela mineralization which is hosted by Cerro del Valle andesite (au)

  7. Rock Pore Structure as Main Reason of Rock Deterioration

    Directory of Open Access Journals (Sweden)

    Ondrášik Martin


    Full Text Available Crashed or dimensional rocks have been used as natural construction material, decoration stone or as material for artistic sculptures. Especially old historical towns not only in Slovakia have had experiences with use of stones for construction purposes for centuries. The whole buildings were made from dimensional stone, like sandstone, limestone or rhyolite. Pavements were made especially from basalt, andesite, rhyolite or granite. Also the most common modern construction material - concrete includes large amounts of crashed rock, especially limestone, dolostone and andesite.

  8. Inca Volcanic Stone Provenance in the Cuzco Province, Peru

    Directory of Open Access Journals (Sweden)

    Patrick N. Hunt


    Full Text Available The use of andesite and basalt as architectual ashlars by Inca stonemasons has been widely discussed throughout the literature. Most of these archaeological or architectural studies are in agreement that that primary Inca quarrying centers in the Cuzco area are in the Rio Huatanay valley at Rumiqolqa and Huaccoto, both to the southeast of Cuzco.

  9. Geological research for hot spring resources in the Kanno-kawa area, Tsukui-machi, Tanzawa mountains

    Energy Technology Data Exchange (ETDEWEB)


    The Kanno-kawa area is mainly composed of the following geological units: miocene submarine pyroclastic formation and its associated augite dolerite sheets, quartz diorite intrusive, and hornblende andesite dykes. The Miocene pyroclastic rocks mainly consist of tuff, tuff breccia, and agglomerate of basaltic, andestic, and dacitic composition intercalated with subordinate amounts of conglomerate, sandstone, and siltstone beds. These rocks were divided into two lithological facies: basaltic and andestic tuff and tuff breccia facies and a facies of dacitic pumice tuff with characteristic white or gray spots of siliceous pumice (2 to 35 mm in diameter). These pyroclastic rocks suffered metamorphism mainly related to the intrusion of quartz diorite. The metamorphic rocks can be divided into the following four zones: amphibolite, actinolite hornfels, pumpellyite-prehnite, and zeolite. Probably during the late stage of the metamorphism, hornblende andesite intruded along sheared zones running from NE or NNE toward SW or SSW. Above noted Miocene pyroclastic rocks, quartz diorite, and hornblende andesite also suffered a hydrothermal alteration by which many zeolite bearing veins or networks were formed. Mineral waters of the Tanzawa mountains are believed to be related to the intrusion of quartz diorite, hornblende andesite, and formation of zeolite veins. In this respect, mineral water of highly alkaline nature can be expected by deep drilling of 600 to 1,000 m at some places such as Choja-goya and Hikage-zawa of the Kanno-kawa area.

  10. Nanggulan Formation and Its Problem As a Basement in Kulonprogo Basin, Yogyakarta

    Directory of Open Access Journals (Sweden)

    Hill Gendoet Hartono


    Full Text Available DOI: 10.17014/ijog.4.2.71-80Nanggulan Formation consists of the oldest clastic rock sequence exposed in Kulonprogo area, Yogyakarta. This paper discusses the position of Nanggulan Formation as a basement. The method used in this research is surface and subsurface investigations based on gravity surveys. The rock assemblage is exposed and distributed partly in the east flank of Kulonprogo Mountains with weak undulated morphology. The rock sequence is composed of sand to clay grain sizes such as sandstone, quartz sandstone, calcareous sandstone, claystone, fossiliferous claystone, calcareous claystone, siltstone, and coal seam intercalations. The total thickness of the sequence is less than 200 m. Based on the fossil and palynology investigations, previous investigators concluded the age of the rock was Eocene to Middle Miocene. The geological structures developed in the rocks are the lithological stratification, fractures, folding, and faulting. The subsurface interpretation based on gravity data revealed the rock was located under the andesite breccias with 2.44 g/cc density. The density of the rock sequence was 2.63 g/cc. The gravity interpretation shows a strong indication that Nanggulan Formation underlies the andesitic breccias presumably associated with Old Andesite Formation exposed in Kulonprogo Mountains. The limited distribution, the thickness, and the closed environmental deposition of Nanggulan Formation found in the present investigation raised problems on the position of the formation as the basement of Old Andesite Formation occurring in the Kulonprogo Mountain.

  11. Chemical trends in a perhumid soil catena on the Turrialba volcano (Costa Rica)

    NARCIS (Netherlands)

    Meijer, E.L.; Buurman, P.


    The variation in chemical composition of soil samples (XRFS data) from a soil catena of 14 soil profiles on the northern slope and foot slope of the andesitic Turrialba volcano (3300 m) has been analysed to test the two hypotheses, which underlie our interpretation that this catena is a weathering

  12. Carbonate assimilation at Merapi volcano, Java Indonesia

    DEFF Research Database (Denmark)

    Chadwick, J.P; Troll, V.R; Ginibre,, C.


    Recent basaltic andesite lavas from Merapi volcano contain abundant, complexly zoned, plagioclase phenocrysts, analysed here for their petrographic textures, major element composition and Sr isotope composition. Anorthite (An) content in individual crystals can vary by as much as 55 mol% (An40^95...

  13. Petrography, mineral chemistry of tourmaline, geochemistry and tectonic setting of Tertiary igneous rocks in Shurab area(west of Khusf), Southern Khorasan

    International Nuclear Information System (INIS)

    Gholami, A. A.; Mohammadi, S. S.; Zarrinkoub, M. H.


    Tertiary igneous rocks of Shurab area in eastern part of Lut block include pyroxene andesite, andesite, trachy andesite, quartz andesite, diorite, quartz diorite and porphyric quartz monzodiorite. Plagioclase, hornblende, pyroxene, biotite and quartz are common minerals and alkali feldspar, opaque, sphene, apatite, tourmaline and zircon exists as minor minerals. Propylitization, chloritization, silisification and tourmalinization are common alterations. Based on electron micro prob analysis, tourmaline in quartz monzodiorite is characterized by weakly chemical zoning, high Mg/Fe ratio from dravite type with alkaline nature that originated from Ca-poor metapelites and metapsammites. The studied rocks have low to medium-K calk-alkaline nature and their spider diagrams display enrichment in LILE such as Cs, Rb ,K , Sr and LREE and depletion in Nb,Ti and HREE that indicate their relation to subduction zone. Geochemical characteristics such as high Sr/Y and La/Yb ratios, high SiO_2 and no Eu anomaly are comparable to high-SiO_2 adakites. Shuorab adakitic rocks are likely originated from partial melting of the crust during delamination process.

  14. The nature of transition from adakitic to non-adakitic magmatism in a slab window setting: A synthesis from the eastern Pontides, NE Turkey

    Directory of Open Access Journals (Sweden)

    Yener Eyuboglu


    Full Text Available The eastern Pontides orogenic belt provides a window into continental arc magmatism in the Alpine–Himalayan belt. The late Mesozoic–Cenozoic geodynamic evolution of this belt remains controversial. Here we focus on the nature of the transition from the adakitic to non-adakitic magmatism in the Kale area of Gumushane region in NE Turkey where this transition is best preserved. The adakitic lithologies comprise porphyries and hyaloclastites. The porphyries are represented by biotite-rich andesites, hornblende-rich andesite and dacite. The hayaloclastites represent the final stage of adakitic activity and they were generated by eruption/intrusion of adakitic andesitic magma into soft carbonate mud. The non-adakitic lithologies include basaltic-andesitic volcanic and associated pyroclastic rocks. Both rock groups are cutting by basaltic dikes representing the final stage of the Cenozoic magmatism in the study area. We report zircon U-Pb ages of 48.71 ± 0.74 Ma for the adakitic rocks, and 44.68 ± 0.84 Ma for the non-adakitic type, suggesting that there is no significant time gap during the transition from adakitic to non-adakitic magmatism. We evaluate the origin, magma processes and tectonic setting of the magmatism in the southern part of the eastern Pontides orogenic belt. Our results have important bearing on the late Mesozoic–Cenozoic geodynamic evolution of the eastern Mediterranean region.

  15. Tectonic and volcanic implications of a cratered seamount off Nicobar Island, Andaman Sea

    Digital Repository Service at National Institute of Oceanography (India)

    KameshRaju, K.A.; Ray, D.; Mudholkar, A.V.; Murty, G.P.S.; Gahalaut, V.K.; Samudrala, K.; Paropkari, A.L.; Ramachandran, R.; SuryaPrakash, L.

    seamount with well-developed crater at the summit was discovered near to the center of the Nicobar swarm. Rock samples collected by TV-guided grab from the seamount crater are dacite, rhyolite and andesite type with a veneer of ferromanganese oxide coating...

  16. Petrographic analysis of samples

    African Journals Online (AJOL)


    contents fall in the field of trachy-dacite, and those from the Kiejo volcano fall in the field of basaltic trachy-andesite .... Arrow indicates breach in Southern caldera wall. (b) Schematic structural ..... Geowissenschaften: FU Berlin: McBirney 1993 ...

  17. The rotation of Spain: Palaeomagnetic evidence from the eastern Pyrenees

    NARCIS (Netherlands)

    Dongen, P.G. van


    The results of a palaeomagnetic investigation on igneous and sedimentary Permo-Triassic rocks from the Spanish Pyrenees are presented and some conclusions are drawn. During demagnetization with a.c. magnetic fields and after correction for the dip, 41 andesitic samples revealed a characteristic

  18. Depositional conditions of the coal-bearing Hirka Formation beneath ...

    Indian Academy of Sciences (India)

    This work focuses on the relationship between the coal deposition and explosive volcanism of the Miocene basin, NW central Anatolia, Turkey. The coal-bearing Hirka Formation was deposited over the Galatian Andesitic Complex and/or massive lagoonal environments during the Miocene. The investigated lignite is a high ...

  19. Growth of intra-caldera lava domes controlled by various modes of caldera collapse, the Štiavnica volcano-plutonic complex, Western Carpathians

    Czech Academy of Sciences Publication Activity Database

    Tomek, Filip; Žák, J.; Holub, F. V.; Chlupáčová, M.; Verner, K.


    Roč. 311, February 1 (2016), s. 183-197 ISSN 0377-0273 Institutional support: RVO:67985831 Keywords : andesite * anisotropy of magnetic susceptibility (AMS) * collapse caldera * lava dome * magma flow * stratovolcano Subject RIV: DC - Siesmology, Volcanology, Earth Structure Impact factor: 2.492, year: 2016

  20. High-Ti type N-MORB parentage of basalts from the south Andaman ...

    Indian Academy of Sciences (India)

    R. Narasimhan (Krishtel eMaging) 1461 1996 Oct 15 13:05:22

    by Irvine and Baragar (1971) or MacDonald and. Katsura (1964) were not included here because of the considerable uncertainty that exists in such a classification scheme (see Sheth et al 2002 for more explanation). The Andaman ophiolite samples are mainly basalts (20 samples), with some basaltic andesites.

  1. The distribution of radon in tunnels with different geological characteristics in China

    Energy Technology Data Exchange (ETDEWEB)

    Li Xiaoyan, E-mail: [School of Geographic and Biologic Sciences, Guizhou Normal University, GuiYang 550001 (China); Song Bo [College of Environmental Science and Engineering, Guilin University of Technology, Guilin 541004 (China); Zheng Baoshan [Institute of Geochemistry, Chinese Academy of Sciences, GuiYang 550002 (China); Wang Yan [Institute of Rock and Soil Mechanics, Chinese Academy of Sciences, Wuhan 430071 (China); Wang Xue [Institute of Geochemistry, Chinese Academy of Sciences, GuiYang 550002 (China)


    In China, as the economy is developing and the population is expanding, some underground buildings have been used as supermarkets, restaurants and entertainment places. Tunnels in mountains are one type of underground building, and the radon ({sup 222}Rn) level in tunnels is an important issue. Radon levels in different type tunnels appear to differ, and relatively higher levels of {sup 222}Rn are associated with particular types of bedrock. The {sup 222}Rn levels in tunnels in five different geological characteristics were analyzed. Those built in granite had the highest {sup 222}Rn levels with a geometric mean (GM) of 280 Bq m{sup -3}, while those built in limestone (GM: 100 Bq m{sup -3}) and andesitic porphyry (GM: 96 Bq m{sup -3}) were lower. The sequence of {sup 222}Rn concentrations was: granite > tuff > quartz sandstone > limestone > andesitic porphyry, and the {sup 222}Rn in granite was statistically significantly higher than in limestone and andesitic porphyry. Tunnels built in granite, tuff, quartz sandstone, limestone tended to have higher {sup 222}Rn concentrations in summer than in winter, while the reverse tendency was true in andesitic porphyry tunnels. Only the difference in limestone was statistically significant.

  2. The distribution of radon in tunnels with different geological characteristics in China

    International Nuclear Information System (INIS)

    Li Xiaoyan; Song Bo; Zheng Baoshan; Wang Yan; Wang Xue


    In China, as the economy is developing and the population is expanding, some underground buildings have been used as supermarkets, restaurants and entertainment places. Tunnels in mountains are one type of underground building, and the radon ( 222 Rn) level in tunnels is an important issue. Radon levels in different type tunnels appear to differ, and relatively higher levels of 222 Rn are associated with particular types of bedrock. The 222 Rn levels in tunnels in five different geological characteristics were analyzed. Those built in granite had the highest 222 Rn levels with a geometric mean (GM) of 280 Bq m -3 , while those built in limestone (GM: 100 Bq m -3 ) and andesitic porphyry (GM: 96 Bq m -3 ) were lower. The sequence of 222 Rn concentrations was: granite > tuff > quartz sandstone > limestone > andesitic porphyry, and the 222 Rn in granite was statistically significantly higher than in limestone and andesitic porphyry. Tunnels built in granite, tuff, quartz sandstone, limestone tended to have higher 222 Rn concentrations in summer than in winter, while the reverse tendency was true in andesitic porphyry tunnels. Only the difference in limestone was statistically significant.

  3. Journal of Earth System Science | Indian Academy of Sciences

    Indian Academy of Sciences (India)

    Geochemical studies and modelling show that both volcanic and granitic magmas from the western part of the Johor National Park, Endau Rompin are different and probably have different sources. The geochemical plot suggests that both dacite/rhyolite and andesite probably have a common origin as in many of the ...

  4. Petrology and geochemistry of igneous inclusions in recent Merapi deposits

    DEFF Research Database (Denmark)

    Chadwick, J.P.; Troll, V.R.; Waight, Tod Earle


    Recent basaltic-andesite lavas from Merapi volcano contain abundant and varied igneous inclusions suggesting a complex sub-volcanic magmatic system for Merapi volcano. In order to better understand the processes occurring beneath Merapi, we have studied this suite of inclusions by petrography, ge...

  5. Magma crust interaction at Merapi volcano, Java Indonesia: insights from crystal isotope stratigraphy

    NARCIS (Netherlands)

    Chadwick, J.P.; Troll, V.R.; Ginibre, C.; Morgan, D.; Gertisser, R.; Waight, T.; Davidson, J.P.


    Recent basaltic andesite lavas from Merapi volcano contain abundant, complexly zoned, plagioclase phenocrysts, analysed here for their petrographic textures, major element composition and Sr isotope composition. Anorthite (An) content in individual crystals can vary by as much as 55 mol% (An

  6. Magma-carbonate interaction processes and associated CO2 release at Merapi volcano, Indonesia: insights from experimental petrology

    NARCIS (Netherlands)

    Deegan, F.M.; Troll, V.R.; Freda, C.; Misti, V.; Chadwick, J.P.


    There is considerable evidence for continuing, late-stage interaction between the magmatic system at Merapi volcano, Indonesia, and local crustal carbonate (limestone). Calc-silicate xenoliths within Merapi basaltic-andesite eruptive rocks display textures indicative of intense interaction between

  7. Penyebaran Batuan Situs Purbakala Candi Palgading di Dusun Palgading, Desa Sinduharjo, Kecamatan Ngaglik, Kabupaten Sleman, Daerah Istimewa Yogyakarta dengan Menggunakan Metode Resistivitas Dipole Dipole

    Directory of Open Access Journals (Sweden)

    Usmardin Usmardin


    Full Text Available Candi Palgading yang terletak di Desa Sinduharjo, Ngaglik, Sleman, D.I.Yogyakarta tanggal 1 Juli 2009 sampai 4 Juli 2009 dengan menggunakan alat Resistivitymeter. Pemetaan ini bertujuan untuk mengetahui penyebaran dan kedalaman batuan penyusun candi pada Situs Candi Palgading serta sebagai sumber informasi bagi usaha penemuan benda-benda purbakala yang terpendam dalam tanah. Pengambilan data dilakukan dengan menggunakan 8 lintasan ukur, dan mencakup luas daerah pengukuran ±1000 m2. Lintasan 1, 2, 3, 4, 5, 6 dan 8 mengambil jarak rentang elektroda (a = 3 m sedangkan lintasan 7 jarak rentang elektrodanya (a = 2 m. Keseluruhan lintasan menggunakan n = 1 sampai dengan n = 7. Pengolahan data menggunakan software Res2dinv dan surfer. Nilai resistivitas yang digunakan untuk menentukan batuan penyusun candi adalah nilai resistivitas batu andesit. Hasilnya menunjukkan profil nilai resistivitas batuan penyusun candi 750 Ohm-m sampai 5000 Ohm-m yang berada hingga kedalaman rata-rata 4,5 m sebagai batu andesit. Terdapat 7 lokasi yang diduga merupakan batu andesit penyusun Candi Palgading sedangkan salah satu lokasi yang lain merupakan batuan andesit bukan penyusun candi. Batuan candi pada ketujuh lokasi tersebut salah satunya telah tersingkap yakni di lokasi 4 sedangkan lokasi yang lain batuan candinya masih terpendam.

  8. Geologic and preliminary reservoir data on the Los Humeros Geothermal System, Puebla, Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Ferriz, H.


    Exploratory drilling has confirmed the existence of a geothermal system in the Los Humeros volcanic center, located 180 km east of Mexico City. Volcanic activity in the area began with the eruption of andesites, followed by two major caldera-forming pyroclastic eruptions. The younger Los Potreros caldera is nested inside the older Los Humeros caldera. At later stages, basaltic andesite, dacite, and olivine basalt lavas erupted along the ring-fracture zones of both calderas. Geologic interpretation of structural, geophysical, and drilling data suggests that: (1) the water-dominated geothermal reservoir is hosted by the earliest andesitic volcanic pile, is bounded by the ring-fracture zone of the Los Potreros caldera, and is capped by the products of the oldest caldera-forming eruption; (2) permeability within the andesitic pile is provided by faults and fractures related to intracaldera uplift; (3) the geothermal system has potential for a large influx of meteoric water through portions of the ring-fracture zones of both calderas; and (4) volcanic centers with similar magmatic and structural conditions can be found in the eastern Cascades, USA.

  9. New insights into the origin of the bimodal volcanism in the middle Okinawa Trough: not a basalt-rhyolite differentiation process (United States)

    Zhang, Yuxiang; Zeng, Zhigang; Chen, Shuai; Wang, Xiaoyuan; Yin, Xuebo


    In the middle Okinawa Trough (MOT), rhyolites have been typically considered as products of crystallization differentiation of basaltic magma as a feature of bimodal volcanism. However, the evidence is insufficient. This paper compared chemical trends of volcanic rocks from the MOT with fractional crystallization simulation models and experimental results and utilized trace element modeling combined with Rayleigh fractionation calculations to re-examine fractional crystallization processes in generating rhyolites. Both qualitative and quantitative studies indicate that andesites, rather than rhyolites, originate by fractional crystallization from basalts in the MOT. Furthermore, we established two batch-melting models for the MOT rhyolites and proposed that type 1 rhyolites are produced by remelting of andesites with amphiboles in the residue, while type 2 rhyolites are derived from remelting of andesites without residual amphiboles. It is difficult to produce melts with a SiO2 content ranging from 62% to 68% either by magmatic differentiation from basalts or by remelting of andesites, and this difficulty might help account for the compositional gap (Daly gap) for bimodal volcanism in the Okinawa Trough.

  10. Amphiboles as indicators of mantle source contamination: Combined evaluation of stable H and O isotope compositions and trace element ratios

    NARCIS (Netherlands)

    Demény, A.; Harangi, S.; Vennemann, T.W.; Casillas, R.; Horváth, P.; Milton, A.J.; Mason, P.R.D.; Ulianov, A.


    Stable isotope and trace element compositions of igneous amphiboles from different tectonic settings (ocean island basalts, intraplate alkaline basalts, subduction-related andesitic complexes) were compiled to help understand the role of fluids and melts in subduction-related mantle metasomatism

  11. Petrological constraints on the high-Mg basalts from Capo Marargiu (Sardinia, Italy): Evidence of cryptic amphibole fractionation in polybaric environments (United States)

    Tecchiato, Vanni; Gaeta, Mario; Mollo, Silvio; Scarlato, Piergiorgio; Bachmann, Olivier; Perinelli, Cristina


    This study deals with the textural and compositional characteristics of the calc-alkaline stratigraphic sequence from Capo Marargiu Volcanic District (CMVD; Sardinia island, Italy). The area is dominated by basaltic to intermediate hypabyssal (dikes and sills) and volcanic rocks (lava flows and pyroclastic deposits) emplaced during the Oligo-Miocene orogenic magmatism of Sardinia. Interestingly, a basaltic andesitic dome hosts dark-grey, crystal-rich enclaves containing up 50% of millimetre- to centimetre-sized clinopyroxene and amphibole crystals. This mineral assemblage is in equilibrium with a high-Mg basalt recognised as the parental magma of the entire stratigraphic succession at CMVD. Analogously, centimetre-sized clots of medium- and coarse-grained amphibole + plagioclase crystals are entrapped in andesitic dikes that ultimately intrude the stratigraphic sequence. Amphibole-plagioclase cosaturation occurs at equilibrium with a differentiated basaltic andesite. Major and trace element modelling indicates that the evolutionary path of magma is controlled by a two-step process driven by early olivine + clinopyroxene and late amphibole + plagioclase fractionation. In this context, enclaves represent parts of a cumulate horizon segregated at the early stage of differentiation of the precursory high-Mg basalt. This is denoted by i) resorption effects and sharp transitions between Mg-rich and Mg-poor clinopyroxenes, indicative of pervasive dissolution phenomena followed by crystal re-equilibration and overgrowth, and ii) reaction minerals found in amphibole coronas formed at the interface with more differentiated melts infiltrating within the cumulate horizon, and carrying the crystal-rich material with them upon eruption. Coherently, the mineral chemistry and phase relations of enclaves indicate crystallisation in a high-temperature, high-pressure environment under water-rich conditions. On the other hand, the upward migration and subsequent fractionation of the

  12. Park Volcanics, Murihiku Terrane, New Zealand : petrology, petrochemistry, and tectonic significance

    International Nuclear Information System (INIS)

    Coombs, D.S.; Cook, N.D.J.; Kawachi, Y.; Johnstone, R.D.; Gibson, I.L.


    The Late Triassic to Early Jurassic Park Volcanics Group comprises minor shallow intrusive and extrusive bodies emplaced during mainly marine sedimentation of the Murihiku Terrane, southern New Zealand. Gowan Andesite in western Southland and Glenham Porphyry andesites in eastern Southland are high-K andesites. Glassy examples have commonly lost K during alteration. Orthoclase contents of Or 3.6-3.7 in plagioclase phenocrysts at An 50 confirm the high-K nature of the melts at the time of phenocryst crystallisation. The Gowan andesites have higher Fe/Mg than the Glenham and related differences in minor element chemistry suggesting lower ∫O 2 during fractionation of the parent magma. Pinney Volcanics in western Southland are mostly high-K trachydacites but, like Glenham Porphyry, include minor rhyolite. Barnicoat Andesite in the Nelson area is medium-K olivine andesite, marginally tholeiitic in terms of its FeO*/MgO versus SiO 2 behaviour, but otherwise is typically calc-alkaline, as are the Gowan, Glenham, and Pinney. Analyses of pyroxenes (augites, orthopyroxenes, reaction rim and groundmass pigeonites) reveal xenocrysts recording an early stage of magma fractionation, slight iron enrichment in the andesite stage, and lowered Fe/Mg and increased Ca contents in augites of the most felsic rocks. Titanian tschermakite and titanian magnesio-tschermakite of deep-seated origin participated in fractionation leading to the Pinney Volcanics, and magnesio-hornblende, edenite, and biotite crystallised as minor late stage minerals following high-level emplacement of Gowan Andesite and siliceous Glenham Porphyry members. Low 87 Sr/ 86 Sr ratios (c. 0.7034-0.7037), REE and multi-element distribution patterns, and the mineralogical features collectively suggest fractionation of the andesites from parental basalt originating in an enriched mantle wedge above a subduction zone, with minimal contamination by continental crust. High-K andesites appear to be unknown in clearly

  13. Miocene volcanism in the Oaş-Gutâi Volcanic Zone, Eastern Carpathians, Romania: Relationship to geodynamic processes in the Transcarpathian Basin (United States)

    Kovacs, Marinel; Seghedi, Ioan; Yamamoto, Masatsugu; Fülöp, Alexandrina; Pécskay, Zoltán; Jurje, Maria


    We present the first comprehensive study of Miocene volcanic rocks of the Oaş-Gutâi Volcanic Zone (OGVZ), Romania, which are exposed in the eastern Transcarpathian Basin (TB), within the Eastern Alpine-Western Carpathian-Northern Pannonian (ALCAPA) block. Collision between the ALCAPA block and Europe at 18-16 Ma produced the Carpathian fold-and-thrust belt. This was followed by clockwise rotation and an extensional regime forming core complexes of the separated TB fragment. Based on petrographic and geochemical data, including Srsbnd Nd isotopic compositions and Ksbnd Ar ages, we distinguish three types of volcanic activity in the OGVZ: (1) early Miocene felsic volcanism that produced caldera-related ignimbrites in the Gutâi Mountains (15.4-14.8 Ma); (2) widespread middle-late Miocene intermediate/andesitic volcanism (13.4-7.0 Ma); and (3) minor late Miocene andesitic/rhyolitic volcanism comprising the Oraşu Nou rhyolitic volcano and several andesitic-dacitic domes in the Oaş Mountains (11.3-9.5 Ma). We show that magma evolution in the OGVZ was controlled by assimilation-fractional crystallization and magma-mixing processes within an interconnected multi-level crustal magmatic reservoir. The evolution of volcanic activity within the OGVZ was controlled by the geodynamics of the Transcarpathian Basin. The early felsic and late intermediate Miocene magmas were emplaced in a post-collisional setting and were derived from a mantle source region that was modified by subduction components (dominantly sediment melts) and lower crust. The style of volcanism within the eastern TB system exhibits spatial variations, with andesitic composite volcanoes (Gutâi Mountains) observed at the margins, and isolated andesitic-rhyolitic monogenetic volcanoes (Oaş Mountains) in the center of the basin.

  14. Magmatic context of Bou Skour copper deposit (Eastern Anti-Atlas, Morocco): Petrogrography, geochemistry and alterations (United States)

    EL Azmi, Daoud; Aissa, M.; Ouguir, H.; Mahdoudi, M. L.; El Azmi, M.; Ouadjo, A.; Zouhair, M.


    The Bou Skour copper deposit is located in the western part of the Saghro massif (Eastern Anti-Atlas), about 50 km East of the city of Ouarzazate. It is subdivided into several areas that are, from North to South: “Panthère”, “Chaigne”, “Anne Marie”, “Chapeau de fer” and “Patte d'Oie”. The latter is economically the most important and is the object of this study. The “Patte d'Oie” district consists mainly of extrusive and intrusive igneous rocks. The extrusive rocks are represented by andesites spatially associated with pyroclastic terms (ignimbrites and pyroclastic breccias). This volcanic unit is intruded by a pink granite pluton and a I-type granodiorite with equigranular texture (Bou Skour granodiorite) showing to the border a microgranular facies (microgranodiorite). All these magmatic formations are intersected by rhyolitic dykes (NNE-SSW) and doleritic dykes (WNW-ESE to NW-SE). The granodiorite and andesite have undergone a polyphase hydrothermal alteration: (i) potassic alteration, (ii) phyllitic alteration, (iii) silicification, (iv) argillic alteration and (v) propylitic alteration. The analysis of geochemical data of granodiorite, granite, andesite and dolerite confirmed: (i) their petrographic natures, (ii) the medium-K calc-alkaline affiliation of andesite and granodiorite, which would have been set up into an active geotectonic environment, probably of island arc or collision, during the Pan-African orogeny, (iii) The high-K calc-alkaline character of granite indicating a post-collision development during the Pan-African orogeny and (iv) The alkaline affinity of the dolerite which is linked to an extensive post-orogenic setting (post-Pan-African). The copper mineralization of “Patte d'Oie” area is hosted, exclusively, in the andesitic and granodioritic facies. It is represented, essentially, by chalcopyrite and bornite minerals and is, probably, related to a porphyry system (disseminated and stockwork mineralization

  15. Analisis stratigrafi awal kegiatan Gunung Api Gajahdangak di daerah Bulu, Sukoharjo; Implikasinya terhadap stratigrafi batuan gunung api di Pegunungan Selatan, Jawa Tengah

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    Hill Gendoet Hartono


    Full Text Available, Tertiary volcanisms in the Southern Mountains, Central Jawa were started with the formation of pillow lavas having basalt to basaltic andesite in composition. This initial stage volcanism developed into a  construction period of composite volcanoes that consist of alternating basaltic to andesitic lava flows, breccias, and tuffs. The construction period could be followed by a destructive phase, producing pumice-rich pyroclastic breccias, lapillistones, and tuffs of high silica andesite to dacite, or even rhyolite in composition. A stratigraphic measuring section at Bulu area, Sukoharjo Regency, presents an alternat- ing fine-grained andesitic volcaniclastic material and some limestones, with the total thickness is 143.33 m. The thickness of bedded volcaniclastic material tends to be thickening upward from 35 m until 90 m. The grain size of the volcaniclastic material also tends to be coarsening upward from clay size through silt and fine sand to coarse sand and granules. Paleontological analysis on fossils contained in the lime- stone gives an age of Early Miocene (N7 - N9. The volcaniclastic rocks is conformably overlain by the Mandalika Formation, comprising alternating andesitic breccias, lavas, and tuffs. These data imply that the fine-grained volcaniclastic material is an initial product of the construction period of Gajahdangak Volcano in the area, that formed the Mandalika Formation. This Formation is overlain by the Semilir Formation, composed of pumice-rich pyroclastic breccias and tuffs with dacitic composition. This as- sociated volcanic rock reflects a product of a caldera explosion or a destructive phase. Based on the characteristics of lithology of volcanic products from the initial stage, to a construction and destruction period, and compiled age data, the Southern Mountains represent formal volcanic rock units that are able to be divided into many formations.  

  16. Upper Carboniferous retroarc volcanism with submarine and subaerial facies at the western Gondwana margin of Argentina (United States)

    Koukharsky, M.; Kleiman, L.; Etcheverría, M.; Quenardelle, S.; Bercowski, F.


    During Late Carboniferous times a continental magmatic arc developed at the western margin of Gondwana in South America, as several marine sedimentary basins were formed at the same time in the retroarc region. North of 33°S, at Cordón Agua del Jagüel, Precordillera of Mendoza, Argentina, a volcanic sequence crops out which was emplaced in a submarine environment with some subaerial exposures, and it is intercalated in marine sediments of Agua del Jagüel Formation, which fills of one of these retroarc basins. This paper presents, for the first time, a facies analyses together with geochemical and isotopic data of this volcanic suite, suggesting its deposition in an ensialic retroarc marine basin. The volcanic succession comprises debris flows with either sedimentary or volcanic fragments, base surge, resedimented massive and laminated dacitic-andesitic hyaloclastite, pillow lava, basic hyaloclastite and dacitic-andesitic lavas and hyaloclastite facies. Its composition is bimodal, either basaltic or dacitic-andesitic. The geochemistry data indicate a subalkaline, low K calk-alkaline and metaluminous affinity. The geochemistry of the basalts points to an origin of the magmas from a depleted mantle source with some crustal contamination. Conversely, the geochemistry of the dacites-andesites shows an important participation of both crustal components and subduction related fluids. A different magmatic source for the basalts than for the dacites-andesites is also supported by Sr and Nd isotopic initial ratios and Nd model ages. The characteristics of this magmatic suite suggest its emplacement in an extensional setting probably associated with the presence of a steepened subduction zone at this latitude during Upper Carboniferous times.

  17. Integrated inversion of airborne geophysics over a structural geological unit: A case study for delineation of a porphyry copper zone in Iran (United States)

    Abedi, Maysam; Fournier, Dominique; Devriese, Sarah G. R.; Oldenburg, Douglas W.


    This work presents the application of an integrated geophysical survey of magnetometry and frequency-domain electromagetic data (FDEM) to image a geological unit located in the Kalat-e-Reshm prospect area in Iran which has good potential for ore mineralization. The aim of this study is to concentrate on a 3D arc-shaped andesite unit, where it has been concealed by a sedimentary cover. This unit consists of two segments; the top one is a porphyritic andesite having potential for ore mineralization, especially copper, whereas the lower segment corresponds to an unaltered andesite rock. Airborne electromagnetic data were used to delineate the top segment as a resistive unit embedded in a sediment column of alluvial fan, while the lower andesite unit was detected by magnetic field data. In our research, the FDEM data were first inverted by a laterally-constrained 1D program to provide three pieces of information that facilitate full 3D inversion of EM data: (1) noise levels associated with the FDEM observations, (2) an estimate of the general conductivity structure in the prospect area, and (3) the location of the sought target. Then EM data inversion was extended to 3D using a parallelized OcTree-based code to better determine the boundaries of the porphyry unit, where a transition exists from surface sediment to the upper segment. Moreover, a mixed-norm inversion approach was taken into account for magnetic data to construct a compact and sharp susceptible andesite unit at depth, beneath the top resistive and non-susceptible segment. The blind geological unit was eventually interpreted based on a combined model of conductivity and magnetic susceptibility acquired from individually inverting these geophysical surveys, which were collected simultaneously.

  18. Magma evolution in the Pliocene Pleistocene succession of Kos, South Aegean arc (Greece) (United States)

    Pe-Piper, Georgia; Moulton, Ben


    This study investigates the petrogenesis of Pliocene-Quaternary andesites, dacites and rhyolites of the island of Kos. These volcanic rocks differ from other volcanic centres in the South Aegean arc in the narrow range of Pliocene volcanic products, the abundance of high-silica rhyolite, the lower ɛNd for a given Sr isotope composition, and greater depth to the subducting slab. Pliocene and early Pleistocene dacite stocks and rhyolite domes are succeeded by younger tuffs, notably the 0.16 Ma Kos Plateau Tuff derived from a super-eruption of an andesite stratocone now subsided beneath the sea south of Kos. Volcanic products in tuffs have been sampled from lithic clasts. Andesite, dacite and rhyolite all have ɛNd ˜+ 1.5 to -1.5 and 86Sr/ 87Sr ˜ 0.7042; this unusual composition is argued to be the result of subduction of sediments derived from the River Nile. All rock types show structures indicative of widespread magma mixing, including complexly zoned plagioclase, clinopyroxene and amphibole containing glass inclusions of trachyte and rhyolite compositions. The observed rocks result from fractionation and mixing of three principal magma types: (a) calc-alkaline high-Al basalt that fractionated to andesite at the base of crust; (b) partially melted metabasaltic amphibolite underplated at the base of crust, that fractionated to produce high-SiO 2 rhyolite; and (c) a minor component of trachytic magma from partial melting of enriched subcontinental lithospheric mantle. The complexly zoned phenocrysts with glass inclusions provide specific evidence for mixing of these three components. Specifically, it was the emplacement of the andesite into a voluminous rhyolite magma in a mid-crustal magma chamber that led to the explosive Kos Plateau Tuff super-eruption.

  19. Late Neoproterozoic adakitic lavas in the Arabian-Nubian shield, Sinai Peninsula, Egypt (United States)

    Abdelfadil, Khaled M.; Obeid, Mohamed A.; Azer, Mokhles K.; Asimow, Paul D.


    The Sahiya and Khashabi volcano-sedimentary successions are exposed near the southern tip of the Sinai Peninsula, the northernmost segment of the Arabian-Nubian Shield (ANS). These Neoproterozoic successions include a series of intermediate to acidic lavas and associated pyroclastic deposits. Field observations and geochemical data reveal two distinct eruptive phases. The lavas representing each phase are intercalated with volcaniclastic greywackes and siltstones. The first eruptive phase, well exposed at Wadi Sahiya, includes basaltic andesite, andesite and dacite with minor rhyolite. The rocks of this sequence are at most weakly deformed and slightly metamorphosed. The second eruptive phase, well exposed at Wadi Khashabi, includes only undeformed and unmetamorphosed dacite and rhyolite. The two volcano-sedimentary successions were separated and dismembered during intrusion of post-collisional calc-alkaline and alkaline granites. Geochemical compositions of the Sahiya and Khashabi volcanic rocks confirm the field data indicating discrete phases of magmatism, however all the compositions observed might plausibly be derived from a common source and be related to one another dominantly through fractional crystallization. The low and variable Mg# values (55-33) measured in the basaltic andesites and andesites preclude their equilibration with a mantle source. Rather, even the most primitive observed lavas are already the products of significant fractional crystallization, dominated by removal of amphibole and plagioclase. Continued fractionation eventually produced dacite and rhyolite marked by significant depletion in Y and HREE. The gradual appearance of negative Nb-Ta anomalies with increasing SiO2 through both suites suggests at least some component of progressive crustal contamination. The medium- to high-K calc-alkaline character of the Sahiya and Khashabi volcanics could be explained either by their formation at an active continental margin or by a two

  20. From source to surface: Tracking magmatic boron and chlorine input into the geothermal systems of the Taupo Volcanic Zone, New Zealand (United States)

    Bégué, Florence; Deering, Chad D.; Gravley, Darren M.; Chambefort, Isabelle; Kennedy, Ben M.


    The magmatic contribution into geothermal fluids in the central Taupo Volcanic Zone (TVZ), New Zealand, has been attributed to either andesitic, 'arc-type' fluids, or rhyolitic, 'rift-type' fluids to explain the compositional diversity of discharge waters. However, this model relies on outdated assumptions related to geochemical trends associated with the magma at depth of typical arc to back-arc settings. Current tectonic models have shown that the TVZ is situated within a rifting arc and hosts magmatic systems dominated by distinct rhyolite types, that are likely to have evolved under different conditions than the subordinate andesites. Therefore, a new appraisal of the existing models is required to further understand the origin of the spatial compositional diversity observed in the geothermal fluids and its relationship to the structural setting. Here, we use volatile concentrations (i.e. H2O, Cl, B) from rhyolitic and andesitic mineral-hosted melt inclusions to evaluate the magmatic contribution to the TVZ geothermal systems. The andesite and two different types of rhyolites (R1 and R2) are each distinct in Cl/H2O and B/Cl, which will affect volatile solubility and phase separation (vapor vs. hydrosaline liquid) of the exsolved volatile phase. Ultimately, these key differences in the magmatic volatile constituents will play a significant role in governing the concentration of Cl discharged into geothermal systems. We estimate bulk fluid compositions (B and Cl) in equilibrium with the different melt types to show the potential contribution of 'parent' fluids to the geothermal systems throughout the TVZ. The results of this analysis show that the variability in fluid compositions partly reflects degassing from previously unaccounted for distinct magma source compositions. We suggest the geothermal systems that appear to have an 'arc-type' andesitic fluid contribution are actually derived from a rhyolite melt in equilibrium with a highly crystalline andesite

  1. Microscopic Rocks and Expansive Empires: Investigating Inca Ceramics from Cuzco, Peru

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    Rob Ixer


    Full Text Available High quality polychrome ceramics are an iconic aspect of Inca material culture. This ‘Cuzco Inca’ pottery appears suddenly in the archaeological record: but it draws upon technological and stylistic aspects of earlier local pottery and we discuss the specifics of how these pre-Inca traits were combined to form the distinctive new state ceramics. Using ceramic petrography, the dominant fabric of Cuzco Inca pottery is compared with those of two pre-Inca wares, Killke and Lucre. Andesite temper, identified in the Lucre and Cuzco Inca fabrics, is compared with samples of andesite from local geological outcrops. This suggests that Lucre pottery was made using similar materials to Cuzco Inca and was a technological precursor. Because these materials and technological knowledge would only have become available to the Inca after their conquest of the Lucre cultural area, this ceramic evidence has important implications for our understanding of Imperial expansion and state intervention in craft-production.

  2. Petrologic and geochemical characterization and mineralization of the metavolcanic rocks of the Heib Formation, Kid Metamorphic Complex, Sinai, Egypt

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    Ibrahim H. Khalifa


    Full Text Available Metavolcanic rocks hosting base metal sulphide mineralization, and belonging to the Kid Metamorphic Complex, are exposed in the Samra-Tarr area, Southern Sinai. The rocks consist of slightly metamorphosed varicolored porphyritic lavas of rhyolite-to-andesite composition, and their equivalent pyroclastics. Geochemically, these metavolcanics are classified as high-K calc-alkaline, metaluminous andesites, trachyandesites, dacites, and rhyolites. The geochemical characteristics of these metavolcanics strongly point to their derivation from continental crust in an active continental margin. The sulphide mineralization in these metavolcanics occurs in two major ore zones, and is represented by four distinct styles of mineralization. The mineralization occurs either as low-grade disseminations or as small massive pockets. The associated hydrothermal alterations include carbonatization, silicification, sericitization and argillic alterations. The base metal sulphide mineralization is epigenetic and was formed by hydrothermal solutions associated with subduction-related volcanic activity.

  3. Genesis of hydrothermal alterations using stable isotope geochemistry in Takestan area (Tarom zone

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    Batool Taghipou


    Full Text Available Hydrothermal alteration processes are extensively took place on volcanic and pyroclstics of Takestan area. Existence of abundant, deep fracturing and subvolcanic intrusions are enhanced extend hydrothermal alteration zones. The following alteration zones are determined: propylitic, argillic, advanced argillic and sillicic. There are outcropped and widespread in different size and limit. Formation of siliceous sinter, silicified tuffs with preserved primary sedimentary layering including pure mineralized alunite patches are most outstanding. Quartz, sussoritic plagioclase, chlorite, sericite and alunite are main mineral constituents in the volcanics. On the basis of geochemical data volcanic rocks are rhyolite, dacite, andesite, andesitic-basalt and basalt in composition. Acid-sulfate zone is the type of alteration in Tarom area and alunite is an index mineral of this zone. Results of 18O, D and 34S stable isotope geochemistry on altered minerals (muscovite, kaolinite and alunite, revealed that alteration fluids are magmatic in origin.

  4. Hydrogeology of Basins on Mars (United States)

    Arvidson, Raymond E.


    This document summarizes the work accomplished under NASA Grant NAG5-3870. Emphasis was put on the development of the FIDO rover, a prototype for the twin-Mers which will be operating on the surface of Mars in 2004, specifically the primary work was the analysis of FIDO field trials. The grantees also analyzed VIKING Lander 1 XRFS and Pathfinder APXS data. Results show that the Viking site chemistry is consistent with an andesite, and the Pathfinder site is consistent with a basaltic andesite. The grantees also worked to demonstrate the capability to simulate annealing methods to apply to the inversion of remote sensing data. They performed an initial analyses of Sojourner engineering telemetry and imaging data. They performed initial analyses of Viking Lander Stereo Images, and of Hematite deposits in Terra Meridiani. They also acquired and analyzed the New Goldstone radar data.

  5. Geology and tectonic magmatic of emplacement of a longitudinal dyke swarm of Nico Perez(Minas) URUGUAY

    International Nuclear Information System (INIS)

    Gonzalez, P.; Poire, D.; Canalicchio, J.; Garcia Repetto, F.


    The Mina Verdun Group (Precambrian) was deposited prior to the subvolcanic emplacement of a longitudinal dyke swarm of basaltic to andesitic composition (Minas Subvolcanic Swarm of the Mina Verdun quarry - Nico Perez Terrane, Minas, Uruguay). The swarm and its country rocks predated a tectono-metamorphic event that produced fragileductile shear zones associated with very low- to low-grade dislocation metamorphism. We interpreted a K-Ar whole rock datum of 485,2 ± 12,5 Ma (andesitic dyke) as a minimum cooling age in relation with late- to post-swarm emplacement deuteric alteration stage. Another K-Ar whole rock datum of 108,5 ± 2,9 Ma on a basaltic dyke was assumed here as a degasification stage, while its geological meaning is still matter of debate. The Minas Subvolcanic Dyke Swarm was intruded at high crustal levels, suggesting that the Minas region was affected by a period of extensional tectonics [es

  6. Chemical and biological characterisation of biofilms formed on different substrata in Tisza river (Hungary)

    International Nuclear Information System (INIS)

    Kroepfl, Krisztina; Vladar, Peter; Szabo, Katalin; Acs, Eva; Borsodi, Andrea K.; Szikora, Szilvia; Caroli, Sergio; Zaray, Gyula


    Natural biofilms were simultaneously grown on granite, polished granite, andesite, polycarbonate and Plexi-glass substrata for six weeks in the Tisza River. Biofilm production and abundance of algae were influenced by the substratum. Magnitude of the substratum effect was andesite < polished granite < Plexi-glass < granite < polycarbonate. The benthic diatom community on polycarbonate had a high population of Achnantes helvetica. Bacterial activity was similar among substrates for 95 different carbon sources. The concentrations of essential elements and heavy metal pollutants (Zn, Ni, Pb and Cu) were highest in biofilms on polished granite or granite. On basis of algological, bacteriological and chemical investigations, as well as literature data, the Plexi-glass substratum is recommended for biomonitoring of river benthic microbiota. - The Plexi-glass substrate is recommended for monitoring river benthic microbiota

  7. Chemical and biological characterisation of biofilms formed on different substrata in Tisza river (Hungary)

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    Kroepfl, Krisztina [Research Group of Environmental Chemistry, Hungarian Academy of Sciences, H-1518, Budapest, P.O. Box 32 (Hungary); Vladar, Peter [Research Group of Environmental Chemistry, Hungarian Academy of Sciences, H-1518, Budapest, P.O. Box 32 (Hungary); Szabo, Katalin [Department of Microbiology, Eoetvoes University, H-1518, Budapest, P.O. Box 32 (Hungary); Acs, Eva [Danube Research Station of Hungarian Academy of Sciences, H-2131 Goed (Hungary); Borsodi, Andrea K. [Department of Microbiology, Eoetvoes University, H-1518, Budapest, P.O. Box 32 (Hungary); Szikora, Szilvia [Department of Inorganic and Analytical Chemistry, Eoetvoes University, H-1518, Budapest, P.O. Box 32 (Hungary); Caroli, Sergio [Istituto Superiore di Sanita, 00161 Roma, Viale Regina Elena, 299 (Italy); Zaray, Gyula [Research Group of Environmental Chemistry, Hungarian Academy of Sciences, H-1518, Budapest, P.O. Box 32 (Hungary) and Department of Inorganic and Analytical Chemistry, Eoetvoes University, H-1518, Budapest, P.O. Box 32 (Hungary)]. E-mail:


    Natural biofilms were simultaneously grown on granite, polished granite, andesite, polycarbonate and Plexi-glass substrata for six weeks in the Tisza River. Biofilm production and abundance of algae were influenced by the substratum. Magnitude of the substratum effect was andesite < polished granite < Plexi-glass < granite < polycarbonate. The benthic diatom community on polycarbonate had a high population of Achnantes helvetica. Bacterial activity was similar among substrates for 95 different carbon sources. The concentrations of essential elements and heavy metal pollutants (Zn, Ni, Pb and Cu) were highest in biofilms on polished granite or granite. On basis of algological, bacteriological and chemical investigations, as well as literature data, the Plexi-glass substratum is recommended for biomonitoring of river benthic microbiota. - The Plexi-glass substrate is recommended for monitoring river benthic microbiota.


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    Şükrü KOÇ


    Full Text Available Dutluca volcanics, which are known as Hallaçlar Formation in regional scale in the study area (Kurshens- ky, 1976, are composed of hydrothermally altered andesite and basaltic andesite. In these rocks, sulfidic minerals such as pyrite, enargite and chalcosine, and oxide and hydroxide minerals such as magnetite, hematite and goethite were detected as opaque minerals. The presence of enargite in opaque mineral para- genesis, and the changes observed in structures and textures of opaque and silicate minerals indicate that examined volcanics have been altered by highly sulfidic hydrothermal solutions. During the hydrothermal alteration process, which indicates at least in two phases, a diffuse pyritization rich in H S in reducing conditions and enargite mineral, which is known as pathfinder minerals in such processes, formed in the first phase. Later on; the extensive martitization developed in oxidizing conditions.

  9. New Insights to the Mid Miocene Calc-alkaline Lavas of the Strawberry Volcanics, NE Oregon Surrounded by the Coeval Tholeiitic Columbia River Basalt Province (United States)

    Steiner, A. R.; Streck, M. J.


    The Strawberry Volcanics (SV) of NE Oregon were distributed over 3,400 km2 during the mid-Miocene and comprise a diverse volcanic suite, which span the range of compositions from basalt to rhyolite. The predominant composition of this volcanic suite is calc-alkaline (CA) basaltic andesite and andesite, although tholeiitic (TH) lavas of basalt to andesite occur as well. The coeval flood basalts of the Columbia River province surround the SV. Here we will discuss new ages and geochemical data, and present a new geologic map and stratigraphy of the SV. The SV are emplaced on top of pre-Tertiary accreted terranes of the Blue Mountain Province, Mesozoic plutonic rocks, and older Tertiary volcanic rocks thought to be mostly Oligocene of age. Massive rhyolites (~300 m thick) are exposed mainly along the western flank and underlie the intermediate composition lavas. In the southern portion of this study area, alkali basaltic lavas, thought to be late Miocene to early Pliocene in age, erupted and overlie the SV. In addition, several regional ignimbrites reach into the area. The 9.7 Ma Devine Canyon Tuff and the 7.1 Ma Rattlesnake Tuff also overlie the SV. The 15.9-15.4 Ma Dinner Creek Tuff is mid-Miocene, and clear stratigraphic relationships are found in areas where the tuff is intercalated between thick SV lava flows. All of the basalts of the SV are TH and are dominated by phenocryst-poor (≤2%) lithologies. These basalts have an ophitic texture dominated by plagioclase, clinopyroxene and olivine (often weathered to iddingsite). Basalts and basaltic andesites have olivine Fo #'s ranging from 44 at the rims (where weathered to iddingsite) and as high as 88 at cores. Pyroxene Mg #'s range from 65 to 85. Andesites of the SV are sub-alkaline, and like the basalts, are exceedingly phenocryst-poor (≤3%) with microphenocrysts of plagioclase and lesser pyroxene and olivine, which occasionally occur as crystal clots of ~1-3 mm instead of single crystals. In addition, minimal


    Directory of Open Access Journals (Sweden)

    Jakob Pamić


    Full Text Available In the paper are presented basic geological, petrologieca1, geochemi-cal and mineral deposit data for five main magmatic-metallogenic formations of the northwestern and central Dinarides: (lThe Permo Triassic rifting related andesite-diorite formations; (2 The Jurassic-Lower Cretaceous accretionary (ophiolite formations; (3 The Upper Cretaceous-Paleogene subduction related basalt-rhyohite formations; (4 The Paleogene collisional granite formations, and (5 The Oligo-cene-Neogene postsubduction andesite formations. All these magmatic-metallogenic formations originated in different geotectonic settings during the Alpine evolution of the Dinaridic parts of thc Tethys and the postorogenic evolution of the Paratethys and the Pannonian Basin, respectively.

  11. Ejection age of volcano rocks and trend of volcanic activity

    Energy Technology Data Exchange (ETDEWEB)

    Sakaguchi, Keiichi


    This report is II-7 of an interim report on research and development of the Sunshine Project for 1986. This report considers on the trend of volcanic activities in the South of Kyushu area. K-Ar age measurement was newly made and reported. Age values obtained were 1.09 plus minus 0.21 Ma for Nagaoyama andesite, 1.33 plus minus 0.18 Ma for Nozato andesite, and 0.3 plus minus 0.1 Ma for Imuta volcanos. Including these age values, from the age values and their distribution of the volcanic rocks in the South Kyushu district, the following three districts were selected to represent the volcanic activities since the Pliocene Epoch. As these districts are mutually overwrapped, verification at these overwrapped districts are necessary. (4 figs, 1 tab, 12 refs)

  12. Enrichments of the mantle sources beneath the Southern Volcanic Zone (Andes) by fluids and melts derived from abraded upper continental crust

    DEFF Research Database (Denmark)

    Holm, Paul Martin; Søager, Nina; Dyhr, Charlotte Thorup


    Mafic basaltic-andesitic volcanic rocks from the Andean Southern Volcanic Zone (SVZ) exhibit a northward increase in crustal components in primitive arc magmas from the Central through the Transitional and Northern SVZ segments. New elemental and Sr–Nd-high-precision Pb isotope data from the Quat......Mafic basaltic-andesitic volcanic rocks from the Andean Southern Volcanic Zone (SVZ) exhibit a northward increase in crustal components in primitive arc magmas from the Central through the Transitional and Northern SVZ segments. New elemental and Sr–Nd-high-precision Pb isotope data from...... mantle by means of subduction erosion in response to the northward increasingly strong coupling of the converging plates. Both types of enrichment had the same Pb isotope composition in the TSVZ with no significant component derived from the subducting oceanic crust. Pb–Sr–Nd isotopes indicate a major...

  13. Volcano-hydrothermal energy research at white Island, New Zealand

    International Nuclear Information System (INIS)

    Allis, R.G.


    This paper presents the White Island (New Zealand) volcano-hydrothermal research project by the N.Z. DSIR and the Geological Survey of Japan, which is investigating the coupling between magmatic and geothermal systems. The first phase of this investigation is a geophysical survey of the crater floor of the andesite volcano, White Island during 1991/1992, to be followed by drilling from the crater floor into the hydrothermal system. (TEC). 4 figs., 8 refs

  14. Stratigraphy and eruption age of the volcanic rocks in the west of Miyanoharu area, Kumamoto Prefecture

    International Nuclear Information System (INIS)

    Kamata, Hiroki


    The detailed stratigraphic survey, K-Ar age determinations and NRM measurements of the volcanic rocks in the west of Miyanoharu area revealed the volcanic history as follows: Hornblende andesite lava with plagioclase megacryst (Yoshinomoto lava) erupted during 2.8 - 2.5 Ma (Gauss normal epoch), accompanied by small amount of pyroclastic materials. After this eruption, Kamitarumizu hypersthene-augite andesite lava (1.7 - 1.3 Ma; reversed), Yabakei pyroclastic flow (0.99 Ma; Jaramillo normal event), Yamakogawa biotite rhyolite lava (0.9 Ma; reversed) and Daikanbo hypersthene-augite andesite lava (0.8 Ma; normal) erupted successively prior to the Aso-1 pyroclastic flow (0.3 - 0.4 Ma). Both the K-Ar ages and NRM data are consistent with the stratigraphic sequence (Fig. 2), which suggests that the activity of andesite and rhyolite is intercalated with each other during Pleistocene in the studied area. The compiled radiometric age data in the central-north Kyushu show that the age of volcanic activity that has previously been inferred as middle Miocene is of Pliocene, and its distribution is limited within the quadrilateral (60 km x 40 km) where the pre-Tertiary basement rocks are absent. The distribution of volcanic rocks is historically zonated such that the rocks of older age up to 5 Ma develop toward the outer rim of the quadrilateral, which coincides with the 0 mgal contour bordering the large low Bouguer anomaly. These facts suggest that the volcanic activity is remarkably relevant to the subsidence of this area, where the volcano-tectonic depression has been formed after 5 Ma to the present, and filled with lavas and pyroclastic materials with scarce sedimentary rocks in the tension stress field during Plio-Pleistocene age. (Kubozono, M.)

  15. Fracturing Fluid Leak-off for Deep Volcanic Rock in Zhungeer Basin: Mechanism and Control Method


    Huang Bo; Cheng Hao; He Yidong; Fu Yanming


    The deep volcanic reservoir in Zhungeer Basin is buried in over 4000m depth, which is characterized by complex lithology (breccia, andesite, basalt, etc.), high elastic modulus and massive natural fractures. During hydraulic fracturing, hydraulic fracture will propagate and natural fractures will be triggered by the increasing net pressure. However, the extension of fractures, especially natural fractures, would aggravate the leak-off effect of fracturing fluid, and consequently decrease the ...

  16. Elemental Mass Balance of the Hydrothermal Alteration Associated with the Baturappe Epithermal Silver-Base Metal Prospect, South Sulawesi, Indonesia


    Nur, Irzal; Idrus, Arifudin; Pramumijoyo, Subagyo; Harijoko, Agung; Watanabe, Koichiro; Imai, Akira; Jaya, Asri; Irfan, Ulva Ria; Sufriadin


    Abstract The Baturappe prospect situated in southernmost part of Sulawesi island, Indonesia, is a hydrothermal mineralization district which is characterized by occurrences of epithermal silver-base metal mineralizations. The mineralizations hosted in basaltic-andesitic volcanic rocks of the late Middle-Miocene Baturappe Volcanics. This paper discusses a recent study of relationships between alteration mineralogy and whole-rock geochemistry, which focused on elemental mass balance calculat...

  17. Comparison between the chemistry of igneous and hydrothermal biotite in the igneous rocks of Sakhtehesar mountain


    Farima Ayati; Sayide Mahdevari


    Sakhtehesar mountain is located in Urumieh-Dokhtar magmatic belt and is composed of volcanic and subvolcanic rocks (Pliocene andesite to dacite) which intruded the volcanics and pyroclastics of Paleocene age. Three alteration zones including potassic, phyllic and propylitic are recognized in the area. In this paper, the mineral chemistry of magmatic and primary biotite and the mineral chemistry of biotite in potassic and phyllic alteration zones have been studied. Investigations show that pri...

  18. Petrology and geochemistry of volcanic rocks of Cheshmeh Khuri and Shekasteh Sabz areas, Khur, northwest of Birjand

    Directory of Open Access Journals (Sweden)

    Maryam Javidi Moghaddam


    Full Text Available Khur area is located in east of Iran and northwest of Birjand. The area comprises outcrops of Eocene to Oligocene volcanics with basaltic andesite to rhyolite composition, which were intruded by subvolcanic and intrusive bodies of granodiorite to gabbro. In the present work, petrogenesis of volcanic units in Cheshmeh Khuri and Shekasteh Sabz areas was studied, which are located in Khur area and these volcanics have most widespread in them. Rhyolite, dacite, andesite, trachyandesite and basaltic andesite units in Cheshmeh Khuri and trachyandesite unit in Shekasteh Sabz were identified. The main textures of these units are porphyritic, hialoporphyritic and microlitic and plagioclase, pyroxene, K-feldspar, hornblende, biotite and quartz are the main minerals. Volcanic units of Cheshmeh Khuri have characteristic of high-K Calc-alkaline. Enrichment of LREE relative to HREE and LILE to HFSE are important evidences that magma was formed in a magmatic belt of a subduction zone. Based on the initial 87Sr/86Sr of andesite and dacite, their magma has originated from partial melting of an enriched mantle and contaminated with the crust through its differentiation. Trachyandesites of Shekaste Sabz have characteristic of shoshonitic nature. These units are characterized by high FeOt/FeOt+MgO, K2O/Na2O and Zr>360 ppm, Y>39 ppm, and Ce> 100 ppm. Also, they are enrichment in REE particularly in LREE, depletion of Eu, strong enrichment in HFSE, and depletion in Ba and Sr. Therefore, trachyandesites of Shekaste Sabz belong to post collision volcanics.

  19. Geochemical signatures of tephras from Quaternary Antarctic Peninsula volcanoes


    Kraus,Stefan; Kurbatov,Andrei; Yates,Martin


    In the northern Antarctic Peninsula area, at least 12 Late Plelstocene-Holocene volcanic centers could be potential sources of tephra layers in the region. We present unique geochemical fingerprints for ten of these volcanoes using major, trace, rare earth element, and isotope data from 95 samples of tephra and other eruption products. The volcanoes have predominantly basaltic and basaltic andesitic compositions. The Nb/Y ratio proves useful to distinguish between volcanic centers located on ...

  20. Tephra from the 1979 soufriere explosive eruption. (United States)

    Sigurdsson, H


    The explosive phase of the 1979 Soufriere eruption produced 37.5 x 10(6) cubic meters (dense-rock equivalent) of tephra, consisting of about 40 percent juvenile basaltic andesite and 60 percent of a nonjuvenile component derived from the fragmentation of the 1971-1972 lava island during phreatomagmatic explosions. The unusually fine grain size, poor sorting, and bimodality of the land deposit are attributed to particle aggregation and the formation of accretionary lapilli in a wet eruption column.

  1. Journal of Earth System Science | Indian Academy of Sciences

    Indian Academy of Sciences (India)

    The lava sequence of the central-western Deccan Traps (from Jalgaon towards Mumbai) is formed by basalts and basaltic andesites having a significant variation in TiO2 (from 1.2 to 3.3 wt%), Zr (from 84 to 253 ppm), Nb (from 5 to 16 ppm) and Ba (from 63 to 407 ppm), at MgO ranging from 10 to 4.2 wt%. Most of these ...

  2. International Uranium Resources Evaluation Project (IUREP) national favourability studies: Taiwan

    International Nuclear Information System (INIS)


    Taiwan is an island of 36,000 sq km located 160 km east of mainland China. Geologically, the oldest rocks are Tertiary, and the only igneous rocks on the island are Quaternary andesites and basalts. Copper, gold, and silver are the only known metallic minerals produced. Uranium occurrences and exploration efforts are unknown. The potential uranium resource of Taiwan is considered a category 1 resource. (author)

  3. Bulk rock composition and geochemistry of olivine-hosted melt inclusions in the Grey Porri Tuff and selected lavas of the Monte dei Porri volcano, Salina, Aeolian Islands, southern Italy (United States)

    Doherty, Angela L.; Bodnar, Robert J.; De Vivo, Benedetto; Bohrson, Wendy A.; Belkin, Harvey E.; Messina, Antonia; Tracy, Robert J.


    The Aeolian Islands are an arcuate chain of submarine seamounts and volcanic islands, lying just north of Sicily in southern Italy. The second largest of the islands, Salina, exhibits a wide range of compositional variation in its erupted products, from basaltic lavas to rhyolitic pumice. The Monte dei Porri eruptions occurred between 60 ka and 30 ka, following a period of approximately 60,000 years of repose. The bulk rock composition of the Monte dei Porri products range from basaltic-andesite scoria to andesitic pumice in the Grey Porri Tuff (GPT), with the Monte dei Porri lavas having basaltic-andesite compositions. The typical mineral assemblage of the GPT is calcic plagioclase, clinopyroxene (augite), olivine (Fo72−84) and orthopyroxene (enstatite) ± amphibole and Ti-Fe oxides. The lava units show a similar mineral assemblage, but contain lower Fo olivines (Fo57−78). The lava units also contain numerous glomerocrysts, including an unusual variety that contains quartz, K-feldspar and mica. Melt inclusions (MI) are ubiquitous in all mineral phases from all units of the Monte dei Porri eruptions; however, only data from olivine-hosted MI in the GPT are reported here. Compositions of MI in the GPT are typically basaltic (average SiO2 of 49.8 wt %) in the pumices and basaltic-andesite (average SiO2 of 55.6 wt %) in the scoriae and show a bimodal distribution in most compositional discrimination plots. The compositions of most of the MI in the scoriae overlap with bulk rock compositions of the lavas. Petrological and geochemical evidence suggest that mixing of one or more magmas and/or crustal assimilation played a role in the evolution of the Monte dei Porri magmatic system, especially the GPT. Analyses of the more evolved mineral phases are required to better constrain the evolution of the magma.

  4. Airborne dust transport to the eastern Pacific Ocean off southern California: Evidence from San Clemente Island (United States)

    Muhs, D.R.; Budahn, J.; Reheis, M.; Beann, J.; Skipp, G.; Fisher, E.


    Islands are natural dust traps, and San Clemente Island, California, is a good example. Soils on marine terraces cut into Miocene andesite on this island are clay-rich Vertisols or Alfisols with vertic properties. These soils are overlain by silt-rich mantles, 5-20 cm thick, that contrast sharply with the underlying clay-rich subsoils. The silt mantles have a mineralogy that is distinct from the island bedrock. Silt mantles are rich in quartz, which is rare in the island andesite. The clay fraction of the silt mantles is dominated by mica, also absent from local andesite, and contrasts with the subsoils, dominated by smectite. Ternary plots of immobile trace elements (Sc-Th-La and Ta-Nd-Cr) show that the island andesite has a composition intermediate between average upper continental crust and average oceanic crust. In contrast, the silt and, to a lesser extent, clay fractions of the silt mantles have compositions closer to average upper continental crust. The silt mantles have particle size distributions similar to loess and Mojave Desert dust, but are coarser than long-range-transported Asian dust. We infer from these observations that the silt mantles are derived from airborne dust from the North American mainland, probably river valleys in the coastal mountains of southern California and/or the Mojave Desert. Although average winds are from the northwest in coastal California, easterly winds occur numerous times of the year when "Santa Ana" conditions prevail, caused by a high-pressure cell centered over the Great Basin. Examination of satellite imagery shows that easterly Santa Ana winds carry abundant dust to the eastern Pacific Ocean and the California Channel Islands. Airborne dust from mainland North America may be an important component of the offshore sediment budget in the easternmost Pacific Ocean, a finding of potential biogeochemical and climatic significance.

  5. Final Environmental Assessment and Finding of No Significant Impact (EA/FONSI) for 2012-14 Capital Improvements Program (CIP) at Davis-Monthan Air Force Base, Tucson, Arizona (United States)


    million years ago. Isolated outcrops of granite more than 1 billion years old are evident throughout the province, but most of the andesite and basaltic ...billion years ago (U.S. Geological Survey 2003). Some basaltic flows occurred as early as 4 million years ago and as late as 65 million years ago...hazardous fibers released into the air. Buildings to be demolished or renovated should be evaluated for the presence of ACMs or other hazardous

  6. Cost Effective, Ultra Sensitive Groundwater Monitoring for Site Remediation and Management (United States)


    evaporites, sandstone, gravel, conglomerate, and andesitic basalt . Closed basin; playa, alluvial fan, fluvial 600 to 10,000+ Unconfined, leaky...confined Lower unit Breccia, conglomerate, sandstone, siltstone, and local basaltic to rhyolitic flows and pyroclastic rocks. Alluvial fan, fluvial...with large volumes of groundwater. Three of the cartridges additionally protected by glass fiber filters (Acrodisc AP-4523; Pall GmbH, Dreieich, GE

  7. Stratigraphy and AMS radiocarbon dates of cored sediments (IrBH-2) from the Irosin caldera, the Philippines

    International Nuclear Information System (INIS)

    Mirabueno, Ma. Hannah T.; Laguerta, Eduardo P.; Delos Reyes, Perla J.; Bariso, Ericson B.; Torii, Masayuki; Fujiki, Toshiyuki; Okuno, Mitsuru; Nakamura, Toshio; Danhara, Tohru; Saito-Kokubu, Yoko; Kobayashi, Tetsuo


    Core drilling at Site IrBH-2 within the Irosin caldera in Sorsogon Province, southern Luzon reached a depth of 50 m. Systematic logging and documentation were carried out to describe and interpret the sediments. The accelerator mass spectrometer (AMS) radiocarbon dates obtained from plant fragments at 7.02-10.40-m depth were 1000 to 1800 BP. Lahars and fluvial deposits were the predominant deposits in the core sequence. The upper 12 m consisted mostly of andesitic fluvial and minor lahar deposits. These deposits may be correlated with the reworking of eruptive products from resurgent andesitic volcanism. One pyroclastic flow and 12 fallout deposits, including five possible fallout deposits, were intercalated with reworked sediments at depths of 12-50 m. The refractive index of representative samples indicated that post-caldera eruptions involved mainly andesite to dacite, with minor rhyolite magmas. The rhyolite fallout in the core had similar petrographic characteristics to the 41 cal kBP Irosin ignimbrite, suggesting that the fallout and the ignimbrite were sourced from the same magma. (author)

  8. Mutnovsky and Gorely Volcanoes, Kamchatka as Planetary Analogue Sites (United States)

    Evdokimova, N.; Izbekov, P. E.; Krupskaya, V.; Muratov, A.


    Recent advances in Mars studies suggest that volcanic rocks, which dominated Martian surface in the past, have been exposed to alteration processes in a water-bearing environment during Noachian, before 3.7 Gy. Active volcanoes on Earth are natural laboratories, where volcanic processes and their associated products can be studied directly. This is particularly important for studying of alteration of juvenile volcanic products in aqueous environment because of the transient nature of some of the alteration products, as well as the environment itself. Terrestrial analogues help us to better understand processes on Mars; they are particularly useful as a test sites for preparation to future Mars missions. In this presentation we describe planetary analogue sites at Mutnovsky and Gorely Volcanoes in Kamchatka, which might be helpful for comparative studies and preparation to future Mars missions. Mutnovsky and Gorely Volcanoes are located 75 km south of Petropavlovsk-Kamchatsky, in the southern part of the Kamchatka Peninsula, Russia. The modern volcanic landscape in the area was shaped in Holocene (recent 10,000 years) through intermittent eruption of magmas ranging in composition from basalts to dacites and rhyodacites, with basaltic andesite lavas dominating in the modern relief. Two localities could be of a particular interest: (1) Mutnovsky NW thermal field featuring processes of active hydrothermal alteration of lavas of basaltic andesite and (2) dry lake at the bottom of Gorely caldera featuring products of mechanical disintegration of basaltic andesite lavas by eolian processes with short seasonal sedimentation in aqueous environment.

  9. The crust role at Paramillos Altos intrusive belt: Sr and Pb isotope evidence

    International Nuclear Information System (INIS)

    Ostera, H.A.; Linares, E; Haller, M.J; Cagnoni, M.C


    Paramillos Altos Intrusive Belt (PAIB) (Ostera, 1996) is located in the thick skinned folded-thrust belt of Malargue, southwestern Mendoza, Argentina. Geochemical, geochronologic and isotopic studies were carried out in it (Ostera 1996, 1997, Ostera et al. 1999; Ostera et al. 2000) and these previous papers suggested a minor involvement of the crust in the genesis of the PAIB. According with Ostera et al. (2000) it is composed by stocks, laccoliths, dykes and sills which range in composition from diorites to granodiorites, and from andesites to rhyolites, and divided in five Members, which range in age from Middle Miocene to Early Miocene: a- Calle del Yeso Dyke Complex (CYDC), with sills and dykes of andesitic composition (age: 20±2 Ma). b- Puchenque-Atravesadas Intrusive Complex (PAIC), composed by dykes and stocks ranging from diorites to granodiorites (age: 12.5±1 Ma). c- Arroyo Serrucho Stock (SAS), an epizonal and zoned stock, with four facies, with K/Ar and Ar/Ar dates of 10±1 and 9.5±0.5 Ma. d- Portezuelo de los Cerros Bayos (PCB), that includes porphyritic rocks of rhyolitic composition, of 7.5±0.5 Ma. e- Cerro Bayo Vitrophyres (CBV), with andesitic sills and dykes (age: 4.8±0.2 Ma). We present in this paper new Sr and Pb isotopes data that constrain the evolution of the PAIB (au)

  10. Mineralization model for Chahar Gonbad copper-gold deposit (Sirjan, using mineralogical, alteration and geochemical data and multivariate statistical methods

    Directory of Open Access Journals (Sweden)

    Seayed Jaber Yousefi


    Full Text Available The study area is located in southeastern Iran, about 110 km southwest of Kerman. Geologically, the area is composed of ophiolitic rocks, volcanic rocks, intrusive bodies and sedimentary rocks. Vein mineralization within andesite, andesitic basalt, andesitic tuffs occurred along the Chahar Gonbad fault. Sulfide mineralization in the ore deposit has taken place as dissemination, veins and veinlets in which pyrite and chalcopyrite are the most important ores. In this area, argillic, phyllic and propylitic alteration types are observed. Such elements as Au, Bi, Cu, S and Se are more enriched than others and the enrichment factors for these elements in comparison with background concentration are 321, 503, 393, 703 and 208, and with respect to Clark concentration are 401, 222, 532, 101 and 156, respectively. According to multivariate analysis, three major mineralization phases are recognized in the deposit. During the first phase, hydrothermal calcite veins are enriched in As, Cd, Pb, Zn and Ca, the second phase is manifested by the enrichment of sulfide veins in Cu, Au, Ag, Bi, Fe and S and the third phase mineralization includes Ni, Mn, Se and Sb as an intermediate level between the two previous phases.

  11. Synergetic use of lignite fly ash and metallurgical converter slag in geopolymer concrete

    Directory of Open Access Journals (Sweden)

    Gábor Mucsi


    Full Text Available The application and utilization of the industrial wastes and by-products in the construction industry is a key issue from an environmental and economic point of view. The increased use of lignite has substantially increased the available quantities of lignite fired power plant fly ash, which can be mainly classified as class C fly ash. The utilization of such raw material however has some difficulties. In the present paper lignite fired power station fly ash and metallurgical converter slag were used for the production of geopolymer concrete. The fly ash was used as a geopolymer based binder material, and a converter slag as aggregate, thus created a geopolymer concrete which contains mainly industrial wastes. As preliminary test experimental series were carried out using andesite as aggregate. The optimal aggregate/binder ratio was determined. The effect of the amount of alkaline activator solution in the binder, the aggregate type on the geopolymer concretes’ compressive strength and density was investigated. Furthermore, the physical properties - freeze-thaw resistance and particle size distribution - of the applied aggregates were measured as well. As a result of the experiments it was found that physical properties of the andesite and converter slag aggregate was close. Therefore andesite can be replaced by converter slag in the concrete mixture. Additionally, geopolymer concrete with nearly 20 MPa compressive strength was produced from class C fly ash and converter slag.

  12. Audio-magnetotelluric (AMT) study to investigate the genesis of Mujil hill (United States)

    Rahmania, Suryanto, Wiwit


    Gunung Mujil is an isolated hill located near Pondoworejo village, Kalibawang sub-district, Kulon Progo district, and Special Province of Yogyakarta. The hill is part of the eastern Kulon Progo mountain range extended relatively in the North-South direction. The lithology of the hill consists of andesite breccia and it's similar with the Old Andesite Formation that built the Kulon Progo Mountains. There are at least two hypothesis about the genesis and the formation mechanism of this hill, (1) it was formed by debris mass from Kulon Progo Mountains, and (2) ) it was formed by an intrusion. Our study intended to determine the subsurface resistivity below the hill and to relating those results to with the scenario of the genesis of the Mujil hill. We conducted Audio-magnetotellurics (AMT) measurements along two lines survey crossing the Mujil hill consisting of 20 measurements. Since the measurements are located near the villages, most of the data has a fair to bad quality and only one station yielded an excellent data. A 1D Forward modeling was then applied to find best-fit model of the AMT data. The results shows that the Mujil hill was built by debris mass of the Old Andesite Formation from Kulon Progo mountain which is represented by a lower resistivity value under the Mujil hill.

  13. Fluid and rock interaction in permeable volcanic rock

    International Nuclear Information System (INIS)

    Lindley, J.I.


    Four types of interrelated changes -geochemical, mineralogic, isotopic, and physical - occur in Oligocene volcanic units of the Mogollon-Datil volcanic field, New Mexico. These changes resulted from the operation of a geothermal system that, through fluid-rock interaction, affected 5 rhyolite ash-flow tuffs and an intercalated basaltic andesite lava flow causing a potassium metasomatism type of alteration. (1) Previous studies have shown enrichment of rocks in K 2 O as much as 130% of their original values at the expense of Na 2 O and CaO with an accompanying increase in Rb and decreases in MgO and Sr. (2) X-ray diffraction results of this study show that phenocrystic plagioclase and groundmass feldspar have been replaced with pure potassium feldspar and quartz in altered rock. Phenocrystic potassium feldspar, biotite, and quartz are unaffected. Pyroxene in basaltic andesite is replaced by iron oxide. (3) delta 18 O increases for rhyolitic units from values of 8-10 permil, typical of unaltered rock, to 13-15 permil, typical of altered rock. Basaltic andesite, however, shows opposite behavior with a delta 18 of 9 permil in unaltered rock and 6 permit in altered. (4) Alteration results in a density decrease. SEM revealed that replacement of plagioclase by fine-grained quartz and potassium feldspar is not a volume for volume replacement. Secondary porosity is created in the volcanics by the chaotic arrangement of secondary crystals

  14. Sr, Nd and Pb isotope and geochemical data from the Quaternary Nevado de Toluca volcano, a source of recent adakitic magmatism, and the Tenango Volcanic Field, Mexico (United States)

    Martínez-Serrano, Raymundo G.; Schaaf, Peter; Solís-Pichardo, Gabriela; Hernández-Bernal, Ma. del Sol; Hernández-Treviño, Teodoro; Julio Morales-Contreras, Juan; Macías, José Luis


    Volcanic activity at Nevado de Toluca (NT) volcano began 2.6 Ma ago with the emission of andesitic lavas, but over the past 40 ka, eruptions have produced mainly lava flows and pyroclastic deposits of predominantly orthopyroxene-hornblende dacitic composition. In the nearby Tenango Volcanic Field (TVF) pyroclastic products and lava flows ranging in composition from basaltic andesite to andesite were erupted at most of 40 monogenetic volcanic centers and were coeval with the last stages of NT. All volcanic rocks in the study area are characterized by a calc-alkaline affinity that is consistent with a subduction setting. Relatively high concentrations of Sr (>460 ppm) coupled with low Y (45 km) that underlies the volcanoes of the study area, the geochemical and isotopic patterns of these rocks indicate low interaction with this crust. NT volcano was constructed at the intersection of three fault systems, and it seems that the Plio-Quaternary E-W system played an important role in the ascent and storage of magmas during the recent volcanic activity in the two regions. Chemical and textural features of orthopyroxene, amphibole and Fe-Ti oxides from NT suggest that crystallization of magmas occurred at polybaric conditions, confirming the rapid upwelling of magmas.

  15. Relationships between mineralization and silicic volcanism in the central Andes (United States)

    Francis, P. W.; Halls, C.; Baker, M. C. W.


    Existing models for the genesis of porphyry copper deposits indicate that they formed in granodioritic stocks located in the infrastructure of andesitic stratovolcanoes. It is noted that sites of porphyry-type subvolcanic tin mineralization in the Eastern Cordillera of Bolivia are distinguished by the absence of such andesitic structures. The surface expression of a typical subvolcanic porphyry tin deposit is thought to be an extrusive dome of quartz latite porphyry, sometimes related to a larger caldera structure. Evidence from the El Salvador porphyry copper deposit in the Eocene magmatic belt in Chile indicates that it too may be more closely related to a silicic volcanic structure than to an andesitic stratovolcano. The dome of La Soufriere, Guadeloupe is offered as a modern analog for the surface expression of subvolcanic mineralization processes, with the phreatic eruptions there indicating the formation of hydrothermal breccia bodies in depths. It is pointed out that the occurrence of mineralized porphyries, millions of years after caldera formation, does not necessarily indicate that tin intrusions and mineralization are not genetically related to the subcaldera pluton, but may be a consequence of the long thermal histories (1-10 million years) of the lowermost parts of large plutons.

  16. Evolution of the East Philippine Arc: experimental constraints on magmatic phase relations and adakitic melt formation (United States)

    Coldwell, B.; Adam, J.; Rushmer, T.; MacPherson, C. G.


    Piston-cylinder experiments on a Pleistocene adakite from Mindanao in the Philippines have been used to establish near-liquidus and sub-liquidus phase relationships relevant to conditions in the East Philippines subduction zone. The experimental starting material belongs to a consanguineous suite of adakitic andesites. Experiments were conducted at pressures from 0.5 to 2 GPa and temperatures from 950 to 1,150°C. With 5 wt. % of dissolved H2O in the starting mix, garnet, clinopyroxene and orthopyroxene are liquidus phases at pressures above 1.5 GPa, whereas clinopyroxene and orthopyroxene are liquidus (or near-liquidus) phases at pressures 1.5 GPa) and subsequently involved the lower pressure fractionation of amphibole, plagioclase and subordinate clinopyroxene. Thus, the distinctive Y and HREE depletions of the andesitic adakites (which distinguish them from associated non-adakitic andesites) must be established relatively early in the fractionation process. Our experiments show that this early fractionation must have occurred at pressures >1.5 GPa and, thus, deeper than the Mindanao Moho. Published thermal models of the Philippine Sea Plate preclude a direct origin by melting of the subducting ocean crust. Thus, our results favour a model whereby basaltic arc melt underwent high-pressure crystal fractionation while stalled beneath immature arc lithosphere. This produced residual magma of adakitic character which underwent further fractionation at relatively low (i.e. crustal) pressures before being erupted.

  17. Dating and source determination of volcanic rocks from Khunik area (South of Birjand, South Khorasan using Rb-Sr and Sm-Nd isotopes

    Directory of Open Access Journals (Sweden)

    Somayeh Samiee


    Full Text Available The Khunik area is located in the south of Birjand, Khorasan province, in the eastern margin of Lut block. Tertiary volcanic rocks have andesite to trachy-andesite composition. Dating analyzing by Rb-Sr method on plagioclase and hornblende as well as whole-rock isochron method was performed on pyroxene-hornblende andesite rock unit. On this basis the emplacement age is Upper Paleocene (58±11 Ma. These rocks have initial 87Sr/86Sr and εNd 0.7046-0.7049 and 2.16-3.12, respectively. According to isotopic data, volcanic rocks originated from depleted mantle and have the least crust contamination while it was fractionated. Geochemically, Khunik volcanic rocks have features typical of calk-alkaline to shoshonite and are metaluminous. Enrichment in LILEs and typical negative anomalies of Nb and Ti are evidences that the volcanic rocks formed in a subduction zone and active continental margin. Modeling suggests that these rocks were derived dominantly from 1–5% partial melting of a mainly spinel garnet lherzolite mantle source that is metasomatized by slab-derived fluid.

  18. K-Ar ages of the Hiruzen volcano group and the Daisen volcano

    International Nuclear Information System (INIS)

    Tsukui, Masashi; Nishido, Hirotsugu; Nagao, Keisuke.


    Seventeen volcanic rocks of the Hiruzen volcano group and the Daisen volcano, in southwest Japan, were dated by the K-Ar method to clarify the age of volcanic activity in this region and the evolution of these composite volcanoes. The eruption ages of the Hiruzen volcano group were revealed to be about 0.9 Ma to 0.5 Ma, those of the Daisen volcano to be about 1 Ma to very recent. These results are consistent with geological and paleomagnetic data of previous workers. Effusion of lavas in the area was especially vigorous at 0.5+-0.1 Ma. It was generally considered that the Hiruzen volcano group had erupted during latest Pliocene to early Quaternary and it is older than the Daisen volcano, mainly from their topographic features. However, their overlapping eruption ages and petrographical similarities of the lavas of the Hiruzen volcano group and the Daisen volcano suggest that they may be included in the Daisen volcano in a broad sense. The aphyric andesite, whose eruption age had been correlated to Wakurayama andesite (6.34+-0.19 Ma) in Matsue city and thought to be the basement of the Daisen volcano, was dated to be 0.46+-0.04 Ma. It indicates that petrographically similar aphyric andesite erupted sporadically at different time and space in the San'in district. (author)

  19. Magma evolution at Copahue volcano (Chile/Argentina border): insights from melt inclusions (United States)

    Cannatelli, C.; Aracena, C.; Leisen, M.; Moncada, D.; Roulleau, E.; Vinet, N.; Petrelli, M.; Paolillo, A.; Barra, F.; Morata, D.


    Copahue volcano is an active stratovolcano in the Andean Southern Volcanic Zone (SVZ), straddling at the border between Central Chile and Argentina. The volcano's eruptive style during its history has changed from mainly effusive in the Pleistocene to explosive in the Holocene. The prehistoric eruptions can be divided into pre-glacial (PG), syn-glacial (SG) and post-glacial (PM) stages, with products ranging from basaltic andesites to andesites. In order to investigate the evolution of the magma source and volatiles through time, we have focused our study on the eruptive products from the SG to the 2014 eruption (SUM2014). Sampled rocks are glomero-porphyritic, with a paragenetic mineral sequence of feldspars, ortho- and clinopyroxene, and olivine in order of abundance. All samples present a variable number of vesicles, with SUM2014 samples containing the biggest amount. Feldspar composition varies from Na-rich (andesine) in SG to Ca-rich (labradorite) in SUM2014. Two pyroxene types are present in SG and PM samples (augite and enstatite), while SUM2014 presents augite, pigeonite and enstatite. Thermobarometric estimation, based on mineral chemistry, show a bimodal distribution for SG and SUM2014 (P=10-12 kbars and 5-8 kbars) and only one interval for PM (P=7-8 kbars). Melt Inclusions Assemblages (MIAs) are found in all mineral phases, mostly re-crystallized, with one or more bubbles and daughter oxide minerals. Compositions vary from trachy-andesitic to dacitic for SG, andesitic to trachydacitic for PM, and basaltic andesitic to trachydacitic for SUM2014. Major elements systematics show the existence of a bimodal distribution of pyroxene and feldspar hosted-MIA in SUM2014, which together with the co-presence of pigeonite (low-Ca pyroxene) and augite and the bimodal distribution of P, can be interpreted as evidence of mixing of two types of magmas, evolving at different depths. Trace elements systematics for MIA in SG, PM and SUM2014 show a negative anomaly for Nb

  20. Tectonic implications of a paleomagnetic direction obtained from a Miocene dike swarm in central Honshu, Japan (United States)

    Hoshi, H.; Sugisaki, Y.


    Central Honshu of Japan is an ideal field for the study of crustal deformation related to arc-arc collision. In this study we obtained rock magnetic and paleomagnetic results from early Miocene igneous rocks in central Honshu in order to examine rotational deformation caused by the collision of the Izu-Bonin-Mariana (IBM) arc with central Honshu. In Takane of the Hida region, gabbro intrusions and older sedimentary rocks are intruded by numerous andesitic dikes that comprise a parallel dike swarm. The dikes formed under two different normal-faulting paleostress conditions, which were suggested using a method of clustering dike orientations. Cross-cutting relationships indicate that the two paleostress conditions existed during the same period. More than 240 oriented cores were taken at 38 sites in two localities for magnetic study. The andesites and gabbros generally have magnetite, and some andesites also contain pyrrhotite. The magnetite records easterly deflected remanent magnetization directions of dual polarities that pass the reversals test. Positive baked contact tests at two sites demonstrate that the easterly deflected direction is a thermoremanent magnetization acquired at the time of intrusion. The overall in situ (i.e., in geographic coordinates) mean direction for andesitic dikes is judged to be highly reliable, although there are two possible scenarios for explaining the easterly deflection: (1) clockwise rotation and (2) tilting to the northwest. We prefer the former scenario and conclude that 45° clockwise rotation occurred in Takane with respect to the North China Block of the Asian continent. This rotation must represent the clockwise rotation of entire Southwest Japan during the opening period of the Japan Sea. Very little difference is observed between the amount of the easterly deflection in Takane and those in the Tokai and Hokuriku regions, indicating no significant relative rotation. Thus, the crust beneath Takane has not suffered rotation

  1. Sr and Nd isotopic and trace element compositions of Quaternary volcanic centers of the Southern Andes (United States)

    Futa, K.; Stern, C.R.


    Isotopic compositions of samples from six Quaternary volcanoes located in the northern and southern extremities of the Southern Volcanic Zone (SVZ, 33-46??S) of the Andes and from four centers in the Austral Volcanic Zone (AVZ, 49-54??S) range for 87Sr 86Sr from 0.70280 to 0.70591 and for 143Nd 144Nd from 0.51314 to 0.51255. The ranges are significantly greater than previously reported from the southern Andes but are different from the isotopic compositions of volcanoes in the central and northern Andes. Basalts and basaltic andesites from three centers just north of the Chile Rise-Trench triple junction have 87Sr 86Sr, 143Nd 144Nd, La Yb, Ba La, and Hf Lu that lie within the relatively restricted ranges of the basic magmas erupted from the volcanic centers as far north as 35??S in the SVZ of the Andes. The trace element and Sr and Nd isotopic characteristics of these magmas may be explained by source region contamination of subarc asthenosphere, with contaminants derived from subducted pelagic sediments and seawater-altered basalts by dehydration of subducted oceanic lithosphere. In the northern extremity of the SVZ between 33?? and 34??S, basaltic andesites and andesites have higher 87Sr 86Sr, Rb Cs, and Hf Lu, and lower 143Nd 144Nd than basalts and basaltic andesites erupted farther south in the SVZ, which suggests involvement of components derived from the continental crust. In the AVZ, the most primitive sample, high-Mg andesite from the southernmost volcanic center in the Andes (54??S) has Sr and Nd isotopic compositions and K Rb and Ba La similar to MORB. The high La Yb of this sample suggests formation by small degrees of partial melting of subducted MORB with garnet as a residue. Samples from centers farther north in the AVZ show a regionally regular northward increase in SiO2, K2O, Rb, Ba, Ba La, and 87Sr 86Sr and decrease in MgO, Sr, K Rb, Rb Cs, and 143Nd 144Nd, suggesting increasingly greater degrees of fractional crystallization and associated intra

  2. Eruptive history of South Sister, Oregon Cascades (United States)

    Fierstein, J.; Hildreth, W.; Calvert, A.T.


    South Sister is southernmost and highest of the Three Sisters, three geologically dissimilar stratovolcanoes that together form a spectacular 20km reach along the Cascade crest in Oregon. North Sister is a monotonously mafic edifice as old as middle Pleistocene, Middle Sister a basalt-andesite-dacite cone built between 48 and 14ka, and South Sister is a basalt-free edifice that alternated rhyolitic and intermediate modes from 50ka to 2ka (largely contemporaneous with Middle Sister). Detailed mapping, 330 chemical analyses, and 42 radioisotopic ages show that the oldest exposed South Sister lavas were initially rhyolitic ~50ka. By ~37ka, rhyolitic lava flows and domes (72-74% SiO2) began alternating with radially emplaced dacite (63-68% SiO2) and andesite (59-63% SiO2) lava flows. Construction of a broad cone of silicic andesite-dacite (61-64% SiO2) culminated ~30ka in a dominantly explosive sequence that began with crater-forming andesitic eruptions that left fragmental deposits at least 200m thick. This was followed at ~27ka by growth of a steeply dipping summit cone of agglutinate-dominated andesite (56-60.5% SiO2) and formation of a summit crater ~800m wide. This crater was soon filled and overtopped by a thick dacite lava flow and then by >150m of dacitic pyroclastic ejecta. Small-volume dacite lavas (63-67% SiO2) locally cap the pyroclastic pile. A final sheet of mafic agglutinate (54-56% SiO2) - the most mafic product of South Sister - erupted from and drapes the small (300-m-wide) present-day summit crater, ending a summit-building sequence that lasted until ~22ka. A 20kyr-long-hiatus was broken by rhyolite eruptions that produced (1) the Rock Mesa coulee, tephra, and satellite domelets (73.5% SiO2) and (2) the Devils Chain of ~20 domes and short coulees (72.3-72.8% SiO2) from N-S vent alignments on South Sister's flanks. The compositional reversal from mafic summit agglutinate to recent rhyolites epitomizes the frequently changing compositional modes of the

  3. The compositionally zoned eruption of 1912 in the Valley of Ten Thousand Smokes, Katmai National Park, Alaska (United States)

    Hildreth, W.


    On June 6-8, 1912, ??? 15 km3 of magma erupted from the Novarupta caldera at the head of the Valley of Ten Thousand Smokes (VTTS), producing ??? 20 km3 of air-fall tephra and 11-15 km3 of ash-flow tuff within ??? 60 hours. Three discrete periods of ash-fall at Kodiak correlate, respectively, with Plinian tephra layers designated A, CD, and FG by Curtis (1968) in the VTTS. The ash-flow sequence overlapped with but outlasted pumice fall A, terminating within 20 hours of the initial outbreak and prior to pumice fall C. Layers E and H consist mostly of vitric dust that settled during lulls, and Layer B is the feather edge of the ash flow. The fall units filled and obscured the caldera, but arcuate and radial fissures outline a 6-km2 depression. The Novarupta lava dome and its ejecta ring were emplaced later within the depression. At Mt. Katmai, 10 km east of the 1912 vent, a 600-m-deep caldera of similar area also collapsed at about this time, probably owing to hydraulic connection with the venting magma system; but all known ejecta are thought to have erupted at Novarupta. Mingling of three distinctive magmas during the eruption produced an abundance of banded pumice, and mechanical mixing of chilled ejecta resulted in deposits with a wide range of bulk composition. Pumice in the initial fall unit (A) is 100% rhyolite, but fall units atop the ash flow are > 98% dacite; black andesitic scoria is common only in the ash flows and in near-vent air-fall tephra. Pumice counts show the first half of the ash-flow deposit to be 91-98% rhyolite, but progressive increases of dacite and andesite eventually reduced the rhyolitic component to 20 km to the lowermost VTTS, and deposited 1-8 m of debris there. Rhyolitic ejecta contain only 1-2% phenocrysts but andesite and dacite have 30-45%. Quartz is present and augite absent only in the rhyolite, but all ejecta contain plagioclase, orthopyroxene, titanomagnetite, ilmenite, apatite, and pyrrhotite; rare olivine occurs in the

  4. Reconstructing multiple arc-basin systems in the Altai-Junggar area (NW China): Implications for the architecture and evolution of the western Central Asian Orogenic Belt (United States)

    Li, Di; He, Dengfa; Tang, Yong


    The Altai-Junggar area in northwestern China is a critical region to gain insights on the tectonic framework and geological evolution of the western Central Asian Orogenic Belt (CAOB). In this study, we report results from integrated geological, geochemical and geophysical investigations on the Wulungu Depression of the Junggar Basin to determine the basement nature of the basin and understand its amalgamation history with the Chinese Altai, within the broad tectonic evolution of the Altai-Junggar area. Based on borehole and seismic data, the Wulungu Depression is subdivided into two NW-trending tectonic units (Suosuoquan Sag and Hongyan High) by southward-vergent thrust faults. The Suosuoquan Sag consists of the Middle-Late Devonian basaltic andesite, andesite, dacite, tuff, tuffaceous sandstone and tuffite, and the overlying Early Carboniferous volcano-sedimentary sequence with lava flows and shallow marine sediments from a proximal juvenile provenance (zircon εHf(t) = 6.0-14.9), compared to the Late Carboniferous andesite and rhyolite in the Hongyan High. Zircon SIMS U-Pb ages for dacites and andesites indicate that these volcanics in the Suosuoquan Sag and Hongyan High erupted at 376.3 Ma and 313.4 Ma, respectively. The Middle-Late Devonian basaltic andesites from well LC1 are calc-alkaline and exhibit primitive magma-like MgO contents (7.9-8.6%) and Mg# values (66-68), with low initial 87Sr/86Sr (0.703269-0.704808) and positive εNd(t) values (6.6-7.6), and relatively high Zr abundance (98.2-116.0 ppm) and Zr/Y ratios (5.1-5.4), enrichment in LREEs and LILEs (e.g., Th and U) and depletion in Nb, Ta and Ti, suggesting that they were probably derived from a metasomatized depleted mantle in a retro-arc extensional setting. The well LC1 andesitic tuffs, well L8 dacites, well WL1 dacitic tuffs and well L5 andesites belong to calc-alkaline and metaluminous to peraluminous (A/CNK = 0.8-1.7) series, and display low Mg# values (35-46) and variably positive εNd(t) (4

  5. Miocene magmatism and tectonics within the Peri-Alboran orogen (western Mediterranean) (United States)

    El Azzouzi, M.; Bellon, H.; Coutelle, A.; Réhault, J.-P.


    The aim of this paper concerns Miocene igneous activity in the Alboran Sea and Peri-Alboran area (northern Morocco, western Algeria and Betic Cordilleras in Spain), considering its age and its location with regard to major tectonics structures. We have compiled previous K-Ar isotopic ages of lavas and plutonic boulders and intrusives with an error of ±1σ and completed this set by a new K-Ar isotopic age for andesitic tuffites from Alboran Island. Geochemistry of most of these samples has been considered after previous analyses completed with new data for Spain magmatism. These two sets of data allow us to place the magmatic activity within the regional stratigraphy and tectonics and their chronological framework of the three major tectonic phases of the Maghrebian orogen, at 17 Ma (Burdigalian), 15 Ma (Langhian) and 9 Ma (Tortonian). Petro-geochemical characteristics are compared through time and geographical locations. A major goal of this coupled approach is to help the elaboration of possible geodynamical processes. As an application, we present the case study of the Dellys, Djinet and Thenia region (east of Algiers) where the successive magmatic events between 19.4 ± 1 and 11.6 ± 0.5 Ma are closely related to the local tectonics and sedimentation. The Peri-Alboran igneous activity is placed in a multidisciplinary framework. Timing of activity is defined according to the ages of the neighbouring sedimentary units and the K-Ar ages of igneous rocks. In Spain, the Cabo de Gata-Carboneras magmatic province displays late Oligocene and early Miocene leucogranitic dikes, dated from 24.8 ± 1.3 to 18.1 ± 1.2 Ma; three following andesitic to rhyolitic events took place around 15.1 ± 0.8 to 14.0 ± 0.7 Ma, 11.8 ± 0.6 to 9.4 ± 0.4 Ma, 8.8 ± 0.4 to 7.9 ± 0.4 Ma; this last event displays also granitic rocks. Lamproitic magmas dated between 8.4 ± 0.4 and 6.76 ± 0.04 Ma were emplaced after the Tortonian phase. In Morocco, after the complex building of the Ras Tarf

  6. The crustal magma storage system of Volcán Quizapu, Chile, and the effects of magma mixing on magma diversity (United States)

    Bergantz, George W.; Cooper, Kari M.; Hildreth, Edward; Ruprecht, Phillipp


    Crystal zoning as well as temperature and pressure estimates from phenocryst phase equilibria are used to constrain the architecture of the intermediate-sized magmatic system (some tens of km3) of Volcán Quizapu, Chile, and to document the textural and compositional effects of magma mixing. In contrast to most arc magma systems, where multiple episodes of open-system behavior obscure the evidence of major magma chamber events (e.g. melt extraction, magma mixing), the Quizapu magma system shows limited petrographic complexity in two large historical eruptions (1846–1847 and 1932) that have contrasting eruptive styles. Quizapu magmas and peripheral mafic magmas exhibit a simple binary mixing relationship. At the mafic end, basaltic andesite to andesite recharge magmas complement the record from peripheral cones and show the same limited range of compositions. The silicic end-member composition is almost identical in both eruptions of Quizapu. The effusive 1846–1847 eruption records significant mixing between the mafic and silicic end-members, resulting in hybridized andesites and mingled dacites. These two compositionally simple eruptions at Volcán Quizapu present a rare opportunity to isolate particular aspects of magma evolution—formation of homogeneous dacite magma and late-stage magma mixing—from other magma chamber processes. Crystal zoning, trace element compositions, and crystal-size distributions provide evidence for spatial separation of the mafic and silicic magmas. Dacite-derived plagioclase phenocrysts (i.e. An25–40) show a narrow range in composition and limited zonation, suggesting growth from a compositionally restricted melt. Dacite-derived amphibole phenocrysts show similar restricted compositions and furthermore constrain, together with more mafic amphibole phenocrysts, the architecture of the magmatic system at Volcán Quizapu to be compositionally and thermally zoned, in which an andesitic mush is overlain by a homogeneous dacitic

  7. An overview of the 2009 eruption of Redoubt Volcano, Alaska (United States)

    Bull, Katharine F.; Buurman, Helena


    In March 2009, Redoubt Volcano, Alaska erupted for the first time since 1990. Explosions ejected plumes that disrupted international and domestic airspace, sent lahars more than 35 km down the Drift River to the coast, and resulted in tephra fall on communities over 100 km away. Geodetic data suggest that magma began to ascend slowly from deep in the crust and reached mid- to shallow-crustal levels as early as May, 2008. Heat flux at the volcano during the precursory phase melted ~ 4% of the Drift glacier atop Redoubt's summit. Petrologic data indicate the deeply sourced magma, low-silica andesite, temporarily arrested at 9-11 km and/or at 4-6 km depth, where it encountered and mixed with segregated stored high-silica andesite bodies. The two magma compositions mixed to form intermediate-silica andesite, and all three magma types erupted during the earliest 2009 events. Only intermediate- and high-silica andesites were produced throughout the explosive and effusive phases of the eruption. The explosive phase began with a phreatic explosion followed by a seismic swarm, which signaled the start of lava effusion on March 22, shortly prior to the first magmatic explosion early on March 23, 2009 (UTC). More than 19 explosions (or “Events”) were produced over 13 days from a single vent immediately south of the 1989-90 lava domes. During that period multiple small pyroclastic density currents flowed primarily to the north and into glacial ravines, three major lahars flooded the Drift River Terminal over 35 km down-river on the coast, tephra fall deposited on all aspects of the edifice and on several communities north and east of the volcano, and at least two, and possibly three lava domes were emplaced. Lightning accompanied almost all the explosions. A shift in the eruptive character took place following Event 9 on March 27 in terms of infrasound signal onsets, the character of repeating earthquakes, and the nature of tephra ejecta. More than nine additional

  8. Eruptive history and geochronology of Mount Mazama and the Crater Lake region, Oregon (United States)

    Bacon, Charles R.; Lanphere, Marvin A.


    Geologic mapping, K-Ar, and 40Ar/39Ar age determinations, supplemented by paleomagnetic measurements and geochemical data, are used to quantify the Quaternary volcanic history of the Crater Lake region in order to define processes and conditions that led to voluminous explosive eruptions. The Cascade arc volcano known as Mount Mazama collapsed during its climactic eruption of ∼50 km3 of mainly rhyodacitic magma ∼7700 yr ago to form Crater Lake caldera. The Mazama edifice was constructed on a Pleistocene silicic lava field, amidst monogenetic and shield volcanoes ranging from basalt to andesite similar to parental magmas for Mount Mazama. Between 420 ka and 35 ka, Mazama produced medium-K andesite and dacite in 2:1 proportion. The edifice was built in many episodes; some of the more voluminous occurred approximately coeval with volcanic pulses in the surrounding region, and some were possibly related to deglaciation following marine oxygen isotope stages (MIS) 12, 10, 8, 6, 5.2, and 2. Magmas as evolved as dacite erupted many times, commonly associated with or following voluminous andesite effusion. Establishment of the climactic magma chamber was under way when the first preclimactic rhyodacites vented ca. 27 ka. The silicic melt volume then grew incrementally at an average rate of 2.5 km3 k.y.−1 for nearly 20 k.y. The climactic eruption exhausted the rhyodacitic magma and brought up crystal-rich andesitic magma, mafic cumulate mush, and wall-rock granodiorite. Postcaldera volcanism produced 4 km3 of andesite during the first 200–500 yr after collapse, followed at ca. 4800 yr B.P. by 0.07 km3 of rhyodacite. The average eruption rate for all Mazama products was ∼0.4 km3 k.y.−1, but major edifice construction episodes had rates of ∼0.8 km3 k.y.−1. The long-term eruption rate for regional monogenetic and shield volcanoes was d∼0.07 km3 k.y.−1, but only ∼0.02 km3 k.y.−1 when the two major shields are excluded. Plutonic xenoliths and evidence for

  9. Magnetic fabric and flow direction in the Ediacaran Imider dyke swarms (Eastern Anti-Atlas, Morocco), inferred from the Anisotropy of Magnetic Susceptibility (AMS) (United States)

    Otmane, Khadija; Errami, Ezzoura; Olivier, Philippe; Berger, Julien; Triantafyllou, Antoine; Ennih, Nasser


    Located in the Imiter Inlier (Eastern Saghro, Anti-Atlas, Morocco), Ediacaran volcanic dykes have been studied for their petrofabric using Anisotropy of Magnetic Susceptibility (AMS) technique. Four dykes, namely TF, TD, FF and FE show andesitic compositions and are considered to belong to the same dyke swarm. They are oriented respectively N25E, N40E, N50E, and N10E and have been emplaced during a first tectonic event. The dyke FW, oriented N90E displays a composition of alkali basalt and its emplacement is attributed to a subsequent tectonic event. These rocks are propylitized under greenschist facies conditions forming a secondary paragenesis constituted by calcite, chlorite, epidote and sericite. The dykes TF, TD, FF and FE are sub-volcanic calc-alkaline, typical of post-collisional basalts/andesites, belonging to plate margin andesites. The FW dyke shows a within-plate basalt signature; alkaline affinity reflecting a different petrogenetic process. The thermomagnetic analyses show a dominantly ferromagnetic behaviour in the TF dyke core carried by single domain Ti-poor magnetite, maghemite and pyrrhotite. The dominantly paramagnetic susceptibilities in TF dyke rims and TD, FE, FF and FW dykes are controlled by ilmenite, amphibole, pyroxene and chlorite. The magnetic fabrics of the Imider dykes, determined by our AMS study, allows us to reconstitute the tectonic conditions which prevailed during the emplacement of these two generations of volcanic dykes. The first tectonic event was characterized by a roughly NE-SW compression and the second tectonic event is characterized by an E-W shortening followed by a relaxation recording the end of the Pan-African orogeny in the eastern Anti-Atlas.

  10. Structural control on arc volcanism: The Caviahue Copahue complex, Central to Patagonian Andes transition (38°S) (United States)

    Melnick, Daniel; Folguera, Andrés; Ramos, Victor A.


    This paper describes the volcanostratigraphy, structure, and tectonic implications of an arc volcanic complex in an oblique subduction setting: the Caviahue caldera Copahue volcano (CAC) of the Andean margin. The CAC is located in a first-order morphotectonic transitional zone, between the low and narrow Patagonian and the high and broad Central Andes. The evolution of the CAC started at approximately 4-3 Ma with the opening of the 20 × 15 km Caviahue pull-apart caldera; Las Mellizas volcano formed inside the caldera and collapsed at approximately 2.6 Ma; and the Copahue volcano evolved in three stages: (1) 1.2-0.7 Ma formed the approximately 1 km thick andesitic edifice, (2) 0.7-0.01 Ma erupted andesitic-dacitic subglacial pillow lavas, and (3) 0.01-0 Ma erupted basaltic-andesites and pyroclastic flows from fissures, aligned cones, and summit craters. Magma ascent has occurred along planes perpendicular to the least principal horizontal stress, whereas hydrothermal activity and hot springs also occur along parallel planes. At a regional scale, Quaternary volcanism concentrates along the NE-trending, 90 km long Callaqui-Copahue-Mandolegüe lineament, the longest of the southern volcanic zone, which is here interpreted as an inherited crustal-scale transfer zone from a Miocene rift basin. At a local scale within the CAC, effusions are controlled by local structures that formed at the intersection of regional fault systems. The Central to Patagonian Andes transition occurs at the Callaqui-Copahue-Mandolegüe lineament, which decouples active deformation from the intra-arc strike-slip Liquiñe-Ofqui fault zone to the south and the backarc Copahue-Antiñir thrust system.

  11. Magmatic record of Late Devonian arc-continent collision in the northern Qiangtang, Tibet: Implications for the early evolution of East Paleo-Tethys Ocean (United States)

    Dan, Wei; Wang, Qiang; Zhang, Xiu-Zheng; Zhang, Chunfu; Tang, Gong-Jian; Wang, Jun; Ou, Quan; Hao, Lu-Lu; Qi, Yue


    Recognizing the early-developed intra-oceanic arc is important in revealing the early evolution of East Paleo-Tethys Ocean. In this study, new SIMS zircon U-Pb dating, O-Hf isotopes, and whole-rock geochemical data are reported for the newly-discovered Late Devonian-Early Carboniferous arc in Qiangtang, central Tibet. New dating results reveal that the eastern Riwanchaka volcanic rocks were formed at 370-365 Ma and were intruded by the 360 Ma Gangma Co alkali feldspar granites. The volcanic rocks consist of basalts, andesites, dacites, and rhyodacites, whose geochemistry is similar to that typical of subduction-related volcanism. The basalts and andesites were generated by partial melting of the fluid and sediment-melt metasomatized mantle, respectively. The rhyodacites and dacites were probably derived from the fractional crystallization of andesites and from partial melting of the juvenile underplated mafic rocks, respectively. The Gangma Co alkali feldspar granites are A-type granites, and were possibly derived by partial melting of juvenile underplated mafic rocks in a post-collisional setting. The 370-365 Ma volcanic arc was characterized by basalts with oceanic arc-like Ce/Yb ratios and by rhyodacites with mantle-like or slightly higher zircon δ18O values, and it was associated with the contemporary ophiolites. Thus, we propose that it is the earliest intra-oceanic arc in the East Paleo-Tethys Ocean, and was accreted to the Northern Qiangtang Terrane during 365-360 Ma.

  12. Permo-triassic volcanism in the San Rafael Block (Mendoza province) and its uraniferous potential

    International Nuclear Information System (INIS)

    Kleiman, L.E.


    This paper describes the Permo-triassic volcanism in the San Rafael Block, Mendoza, Argentina, which forms part of the Choiyoi province and it represents by large volumes of intermediate to silicic ignimbrites with minor sub volcanic bodies of rhyolites, andesites and basandesites. Three different suites can be distinguished: the first one (Lower Section) of Early Permian age, is composed of dacites and rhyolites (SiO 2 up to 71 %) with minor andesites, the second one (Upper Section) of Late Permian-Early Triassic age is made up of rhyolites (SiO 2 up to 77 %) with some basandesites and andesites, and the third one, of Triassic age is composed of rhyolites (SiO 2 > 75 %) and basandecites. These suites are easily distinguished by means of trace element data and are believed to represent the transition between a subduction-related magmatic arc and an extensional tectonic regime. This tectonic setting is similar to the prevalent during the Cenozoic in the Sierra Occidental of Mexico and is favourable for the development of long-lived hydrothermal systems which lead to economic U concentrations (i.e. Sierra de Pena Blanca). In the San Rafael Block, the Dr. Baulies-Los Reyunos U deposit, which is hosted in volcanic sediments, is associated to the first suite (Lower Section). Although minor U concentrations are known, up to date, to be related to the second and third suites, these rocks are fertile and seen to be potential source for the formation of uranium deposits within a volcanic caldera environment. (Author)

  13. Microbiology of Low Temperature Seafloor Deposits Along a Geochemical Gradient in Lau Basin (United States)

    sylvan, J. B.; Sia, T. Y.; Haddad, A.; Briscoe, L. J.; Girguis, P. R.; Edwards, K. J.


    The East Lau Spreading Center (ELSC) and Valu Fa Ridge comprise a ridge segment in the southwest Pacific Ocean where rapid transitions in the underlying mantle lenses manifest themselves by gradients in seafloor rock geochemistry. At the spreading center in the north, basaltic host rock extrudes while the influence of subduction in the south creates mainly basaltic andesite host rock. A contuous gradient between these two end members exists along the spreading center. We studied the geology and microbial diversity of three silicate rock samples and three inactive sulfide chimney samples collected along the ELSC and Valu Fa Ridge by X-ray diffraction, elemental analysis, thin section analysis and construction of bacterial 16S rRNA clone libraries. Here, we discuss the geological and biological differences between the collected rocks. We found that the bacterial community composition changed as the host rock mineralogy and chemistry changed from north to south. Also, the bacterial community composition on the silicates is distinct from those on the inactive chimneys, and the interior conduit of an inactive chimney hosts a very different community from the exterior. Basalt from the northern end of the ELSC had high proportions of Alphaproteobacteria and Bacteroidetes. These proportions decreased on the silicates collected further south. Epsilonproteobacteria were also present on the basalt, decreased further south and were absent on the basaltic andesite. Conversely, basaltic andesite rocks from the southern end had high proportions of Chloroflexi, which decreased further north and were absent on basalt. The exterior of inactive sulfide structures were dominated by lineages of sulfur oxidizing Gammaproteobacteria and Epsilonproteobacteria and were less diverse than those on the silicates. The interior of one chimney was dominated by sulfate-reducing Deltaproteobacteria and was the least diverse of all samples. These results support the Mantle to Microbe hypothesis in

  14. Petrographic and Geochemical Analyses of Kirana Hills Shield Rocks around Sargodha and Economic Potential

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    Muhammad Waseem Khan


    Full Text Available The present study deals with geochemical and petrographic analysis of the Kirana Hill shield rocks of Punjab plains from Buland, Hachi, Shaheen Abad, Shaikh and Machh hills. On basis of the current studies certain modifications have been made in the classification and nomenclature of rocks exposed in the study areas. Chemical analyses have also been carried out in order to calculate Cross Iddings, Pirsson, and Washington (CIPW norms”, to strengthen nomenclature scheme and finally rocks are classified by using “MAGMA SOFTWARE”. Rhyolites predominate over the basalts/dolerites, andesites, and phyllite/ slate. Rhyolitic rocks are light grey, greenish grey and light brown in color, aphanitic in nature. The observed microscopic textures are aphyric, phyric or porphyritic and micropoikilitc. Moreover, some rhyolitic rocks also show flow texture. They are either cryptocrystalline to microcrystalline or microcrystalline to cryptocrystalline. No glassy material has been observed in any thin section. Mafic rocks are characterized by the presence of ferromagnesian minerals with plagioclase. Andesites exhibit mainly porphyritic texture, but aphyric texture has also been observed in few samples. Hydrothermal alterations are also very common in these rocks. Other rock assemblages identified during laboratory studies from Kirana area include: tuffs i.e. (Lithic Crystal Tuff and Lithic Tuff, basaltic andesite, rhyodacite/ dacite, slate/ phyllite, ankeritic rocks/ veins and quartzofeldspathic veins. Our studies also reveal that no evidence of quartzite has been found in the samples collected from above mentioned areas of Kirana, although it has been reported in previous literature. Iron (Fe has been observed in rhyolite as well as other volcanic rocks of Kirana hills, its presence suggests magma from deep mantle instead of crustal melting / anatexis. In the present analysis some primary and secondary copper minerals including chalcopyrite, atacamite and

  15. The Relationship between Mechanical Properties and Gradual Deterioration of Microstructures of Rock Mass Subject to Freeze-thaw Cycles

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    Haibo Jiang


    Full Text Available Under freeze-thaw cycles, the relationship between rock microstructure deterioration and its macroscopic mechanical characteristics has drawn extensive attention from engineers. With the objective to incorporate freeze-thaw cycle experiment into headrace tunnel engineering, in the present study two groups of andesite rock samples in different states are tested under the conditions of the lowest freezing temperature of –40 ℃ and the thawing temperature of 20 ℃. Damage detection was performed by magnetic resonance imaging for the interior microstructure of rock samples subject to different freeze-thaw cycles, and the relationship between the sample mechanical properties and gradual deterioration of rock microstructures was discussed. The results demonstrate evident influence of freeze-thaw cycle on the damage and deterioration of internal pore structure in andesite, and the rock uniaxial compressive strength and elasticity modulus exhibit a decreasing trend with the increase of freeze-thaw cycles. After 40 cycles, the strength of naturally saturated rock samples decreases by 39.4% (equivalent to 69.4 MPa and the elasticity modulus drops by 47.46% (equivalent to 3.27 GPa. For rock samples saturated by vacuum, 40 freeze-thaw cycles lead to a decrease of 36.86% (equivalent to 58.2 MPa in rock strength and a drop of 44.85% (equivalent to 2.83 GPa in elasticity modulus. Therefore, the test results quantitatively elucidate the substantial influence of freeze-thaw cycle on the damage and deterioration of internal structure in andesite.

  16. The Ediacaran volcanic rocks and associated mafic dykes of the Ouarzazate Group (Anti-Atlas, Morocco): Clinopyroxene composition, whole-rock geochemistry and Sr-Nd isotopes constraints from the Ouzellarh-Siroua salient (Tifnoute valley) (United States)

    Belkacim, Said; Gasquet, Dominique; Liégeois, Jean-Paul; Arai, Shoji; Gahlan, Hisham A.; Ahmed, Hassan; Ishida, Yoshito; Ikenne, Moha


    Belonging to the huge Ouarzazate volcanic Group that covered the whole Anti-Atlas during the late Ediacaran (580-545 Ma), the Tifnoute valley volcanic formations are mainly pyroclastic and show a large composition, from trachybasalt to rhyolite and are crosscut by dolerite dykes. The Tifnoute valley volcanic rocks are located within a rigid salient of the Anti-Atlas that gives them special extreme characteristics. Due to the heavy greenschist alteration that affects this volcanic group, we focused the more immobile elements, but as REE can also be affected, we used the composition of unaltered clinopyroxene crystals to determine the nature of these volcanic rocks. The clinopyroxene is an augite diopside in the basalt, an augite in the andesite and an augite-salite in the dolerite. Petrography of the Tifnoute mafic volcanic rocks and clinopyroxene compositions indicate the presence of two magmatic series: (i) older high-K calc-alkaline (alkali-calcic) andesite and basalt characterized by the early crystallization of Fe-Ti oxides and of the late fractionation of plagioclase, the modal proportion of the latter increasing from the basalt to the andesite and (ii) younger alkalic dolerite dykes. With clinopyroxene trace element compositions obtained using laser ablation ICP-MS, we calculated the composition of the melts in equilibrium with the pyroxenes. The volcanic rocks of the Tifnoute Valley have positive εNd570 (+1.7 to +5.0), low Sri (volcanic rocks emplaced in a Pan-African transtensive post-collisional environment that evolved towards the major rifting event that will give rise to the Rheic ocean, in a similar way to what occurred just after the Variscan orogeny during the Triassic period that evolved to the Tethys ocean opening.

  17. The timing of compositionally-zoned magma reservoirs and mafic 'priming' weeks before the 1912 Novarupta-Katmai rhyolite eruption (United States)

    Singer, Brad S.; Costa, Fidel; Herrin, Jason S.; Hildreth, Wes; Fierstein, Judith


    The June 6, 1912 eruption of more than 13 km3 of dense rock equivalent (DRE) magma at Novarupta vent, Alaska was the largest of the 20th century. It ejected >7 km3 of rhyolite, ~1.3 km3 of andesite and ~4.6 km3 of dacite. Early ideas about the origin of pyroclastic flows and magmatic differentiation (e.g., compositional zonation of reservoirs) were shaped by this eruption. Despite being well studied, the timing of events that led to the chemically and mineralogically zoned magma reservoir remain poorly known. Here we provide new insights using the textures and chemical compositions of plagioclase and orthopyroxene crystals and by reevaluating previous U-Th isotope data. Compositional zoning of the magma reservoir likely developed a few thousand years before the eruption by several additions of mafic magma below an extant silicic reservoir. Melt compositions calculated from Sr contents in plagioclase fill the compositional gap between 68 and 76% SiO2 in whole pumice clasts, consistent with uninterrupted crystal growth from a continuum of liquids. Thus, our findings support a general model in which large volumes of crystal-poor rhyolite are related to intermediate magmas through gradual separation of melt from crystal-rich mush. The rhyolite is incubated by, but not mixed with, episodic recharge pulses of mafic magma that interact thermochemically with the mush and intermediate magmas. Hot, Mg-, Ca-, and Al-rich mafic magma intruded into, and mixed with, deeper parts of the reservoir (andesite and dacite) multiple times. Modeling the relaxation of the Fe-Mg concentrations in orthopyroxene and Mg in plagioclase rims indicates that the final recharge event occurred just weeks prior to the eruption. Rapid addition of mass, volatiles, and heat from the recharge magma, perhaps aided by partial melting of cumulate mush below the andesite and dacite, pressurized the reservoir and likely propelled a ~10 km lateral dike that allowed the overlying rhyolite to reach the surface.

  18. Hydrogeological investigation of Melendiz basin (Aksaray)

    International Nuclear Information System (INIS)

    Dogdu, M.S.


    Within the scope of this M.Sc, study entitled Hydrogeologic Investigation of Melendiz basin, the geological, hydrological, hydrogeological and hydrochemical features of a 600 km2 area have been studied and, 1/100.000 scale geological and hydrogeological maps have been prepared. Tetriary-Guaternary aged young volkanic rocks occupy nearly 80% (480 km2 ) of the area. The major aquifers are alluvium and andesite and basalt which are extensively fractured and jointed. Aquitard units comprise of ignimbirite, some of the andesites-basalts and formations that composes of limestone-sandstone-marl intercalations. The youngest geologic unit of the area, Hasandag volcanic ash formation, and also the tuffs have been indentified as aquiclude units. Mean areal precipitation, potential and real evapotranspiration rates and mean annual streamflow have been calculated on the basis of available data and, a hydrologic budget of the basin has been established. Hydrogeologic units have been classified as aquifer, aquitard and aquiclude with respect to their geohydrologic properties, field observations and the results of the pumping tests. On the other hand, hydrodynamic mechanism of the groundwater flow reaching major cold and thermal water discharges have also been explained. A hydrogeologic budget for the area covering Ciftlik township and its vicinity where extensively joint and fractured andesite-basalt and alluvial aquifers outcrop has been established. Major water points as thermal and cold springs, wells and streams have been sampled for major ion analysis. Beyond this, some water points have also been sampled for organic, trace,metal ald environmental isotropic analyses. Environmental isotope data of thermal springs point out a long-deep groundwater flow path

  19. Geology and metallogeny of the volcanic complex of Rio Blanco Ullum. Province of San Juan. Republica Argentina

    International Nuclear Information System (INIS)

    Mendoza, N.; Weidmann, N.; Puigdomenech, H.; Weidmann, R.


    Preliminary results of a research carried out at the Complejo Rio Blanco de Ullum, San Juan. Argentina are summarized in the present paper. These studies are focused on geological and metallogenic features o f this unit. The study area is located 20 km. WNW of San Juan city with geographic coordinates of 31grades 30' South latitude and 68 grades 52' West longitude. The older rocks aotcroping in the area correspond to limestones of Ordovician San Juan Formation, the chronologic succession continues with sales and siltstones of Silurian Tambolar Formation, pelites and subgraywackes of Devonian Punta Negra Formation and finally a 1500 m thick package of piroclastics and sediments of Albarracin Formation of Tertiary age. Albarracin Formation is composed pf a Basal Member (sandstones and stilstones), a Tuffaceous Member (tuffs, tuffites and oligomictic breccia s with conglomerate interbed dings in the upper part) and a Conglomeratic Member (polimictic para conglomerates). According to piroclastics facies, relationships and spreading area of piroclastics deposits a c olapsed dome and avalanche model is proposed to be the main process for the piroclastics package outcropping in the area.Sedimentary and piroclastics rocks are intruded by five sub volcanic units as noted by Leveratto (1968) which are composed by different lithologies such as: Altered Da cite - Rhyolite, Ullum Da cite, Cerro Blanco de Zonda Andesite, Ullum Andesite and Hybrid Andesite.Detailed work on alteration assemblages and metallogenic features in the southwestern sector of the Complejo resulted in the identification of three alteration zones with characteric features of potassic, argillic and propyllitic signature. (author)

  20. Ignimbrite Analyses of Batur Caldera, Bali, based on 14C Dating

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    Igan S. Sutawidjaja


    Full Text Available Batur Caldera, in the northeastern part of Bali Island, is an elliptical collapse structure 13.8 by 10 km in size and another circular composite collapse structure with a diameter of 7.5 km in its centre. Two stages of the collapse were interrupted by silicic andesite lavas and domes. The first collapse was initiated by the eruption of about 84 km3 of the dacitic "Ubud Ignimbrite", about 29,300 years B.P., which caused a steep-walled depression about 1 km deep. The second ignimbrite was erupted from a large crater about the present lake, and it  produced about 19 km3 of a similar voluminous dacitic ignimbrite, called the "Gunungkawi Ignimbrite" about 20,150 years B.P. This second eruption trig- gered a second collapse, which created the central circular caldera, and formed a basin structure. Both the Ubud and Gunungkawi Ignimbrites consist of a similar dacitic composition, white to red (the most abundant nearly 90 % and dark grey to black dacitic pumice clasts. The large clasts, up to 20 cm in diameter, are in the non-welded ignimbrite, particularly in the upper part of the Gunungkawi Ignimbrite. The intracaldera ignimbrite, called the "Batur Ignimbrite" about 5 km3  in volume is a densely welded ignimbrite and generally shows typical welded features. The ignimbrite comprises at least five different flow units, separated by thin (15 - 40 cm welded pumiceous airfall deposits, with flattened pumice clasts. Another large eruption occurred about 5,500 years B.P., producing around 0.09 km3  andesitic ignimbrite. This was initiated by phreatomagmatic eruptions, indicated by thick phreatomagmatic and surge deposits, underlying the ignimbrite. The caldera and its vicinity are partly filled, and variably mantled by later eruptive products of dacitic and andesitic phreatomagmatic and airfall deposits.  

  1. Metamorphism and plutonism around the middle and south forks of the Feather River, California (United States)

    Hietanen, Anna Martta


    The area around the Middle and South Forks of the Feather River provides information on metamorphic and igneous processes that bear on the origin of andesitic and granitic magmas in general and on the variation of their potassium content in particular. In the north, the area joins the Pulga and Bucks Lake quadrangles studied previously. Tectonically, this area is situated in the southern part of an arcuate segment of the Nevadan orogenic belt in the northwestern Sierra Nevada. The oldest rocks are metamorphosed calcalkaline island-arc-type andesite, dacite, and sodarhyolite with interbedded tuff layers (the Franklin Canyon Formation), all probably correlative with Devonian rocks in the Klamath Mountains. Younger rocks form a sequence of volcanic, volcaniclastic, and sedimentary rocks including some limestone (The Horseshoe Bend Formation), probably Permian in age. All the volcanic and sedimentary rocks were folded and recrystallized to the greenschist facies during the Nevadan (Jurassic) orogeny and were invaded by monzotonalitic magmas shortly thereafter. A second lineation and metamorphism to the epidote-amphibolite facies developed in a narrow zone around the plutons. In light of the concept of plate tectonics, it is suggested that the early (Devonian?) island-arc-type andesite, dacite, and sodarhyolite (the Franklin Canyon Formation) were derived from the mantle above a Benioff zone by partial melting of peridotite in hydrous conditions. The water was probably derived from an oceanic plate descending to the mantle. Later (Permian?) magmas were mainly basaltic; some discontinuous layers of potassium-rich rhyolite indicate a change into anhydrous conditions and a deeper level of magma generation. The plutonic magmas that invaded the metamorphic rocks at the end of the Jurassic may contain material from the mantle, the subducted oceanic lithosphere, and the downfolded metamorphic rocks. The ratio of partial melts from these three sources may have changed with time

  2. Chemical, multispectral, and textural constraints on the composition and origin of rocks at the Mars Pathfinder landing site (United States)

    McSween, H.Y.; Murchie, S.L.; Crisp, J.A.; Bridges, N.T.; Anderson, R.C.; Bell, J.F.; Britt, D.T.; Brückner, J.; Dreibus, G.; Economou, T.; Ghosh, A.; Golombek, M.P.; Greenwood, J.P.; Johnson, J. R.; Moore, H.J.; Morris, R.V.; Parker, T.J.; Rieder, R.; Singer, R.; Wänke, H.


    Rocks at the Mars Pathfinder site are probably locally derived. Textures on rock surfaces may indicate volcanic, sedimentary, or impact-generated rocks, but aeolian abration and dust coatings prevent unambiguous interpretation. Multispectral imaging has resolved four spectral classes of rocks: gray and red, which occur on different surfaces of the same rocks; pink, which is probably soil crusts; and maroon, which occurs as large boulders, mostly in the far field. Rocks are assigned to two spectral trends based on the position of peak reflectance: the primary spectral trend contains gray, red, and pink rocks; maroon rocks constitute the secondary spectral trend. The spatial pattern of spectral variations observed is oriented along the prevailing wind direction. The primary spectral trend arises from thin ferric coatings of aeolian dust on darker rocks. The secondary spectral trend is apparently due to coating by a different mineral, probably maghemite or ferrihydrite. A chronology based on rock spectra suggests that rounded maroon boulders constitute the oldest petrologic unit (a flood deposit), succeeded by smaller cobbles possibly deposited by impact, and followed by aeolian erosion and deposition. Nearly linear chemical trends in alpha proton X-ray spectrometer rock compositions are interpreted as mixing lines between rock and adhering dust, a conclusion supported by a correlation between sulfur abundance and red/blue spectral ratio. Extrapolations of regression lines to zero sulfur give the composition of a presumed igneous rock. The chemistry and normative mineralogy of the sulfur-free rock resemble common terrestrial volcanic rocks, and its classification corresponds to andesite. Igneous rocks of this composition may occur with clastic sedimentary rocks or impact melts and breccias. However, the spectral mottling expected on conglomerates or breccias is not observed in any APXS-analyzed rocks. Interpretation of the rocks as andesites is complicated by absence

  3. Petrography and geochemistry of the volcanic rocks of the Rodeio Velho Member, Ordovician of the Camaqua basin (RS-Brazil): preliminary results

    International Nuclear Information System (INIS)

    Almeida, Delia del Pilar M. de; Lopes, Ricardo da C.; Gomes, Cristiane H.; Lima, Larissa de.


    A geochemical study based in REE, minor elements and petrographic analyses from the volcanic rocks pertaining to the Rodeio Velho Member, comprising lava flows and epizonal intrusive bodies, both corresponding to andesites, subalkaline and alkaline basalts and trachyandesites; and stratified pyroclastic deposits, showed that fractional crystallization of deep source magma is the fundamental mechanism controlling the relationships among these rocks. This igneous event occurred in an alkaline intraplate environment, associated to a widespread extension tectonics, probably corresponding to a final stage of the Pan African - Brasiliano Orogeny during the Middle Ordovician. (author)

  4. Multi-elemental characterization of volcanic and vulcano-sedimentary rocks from Pina petroleum ore, central Cuba

    International Nuclear Information System (INIS)

    Montero-Cabrera, M.E.; Herrera-Peraza, E.; Betancourt-Tanda, L.; Campa-Menendez, R.; Diaz-Rizo, O.; Rodriguez-Martinez, N.; Segura-Soto, R.; Hernandez-Lopez, B.; Valdes-Lopez, S.


    Concentrations of 32 elements in 22 clay, limestone, tuff and volcanic rock samples from the Pina ore have been obtained by neutron activation and X-ray fluorescence analyses. Several LILE (large ion lithofile elements) and REE (rare earth element) concentration diagrams showed the calc-alkaline character of the volcanic rocks corresponding to the Greater Antilles Island, Arc. The basaltic andesite behavior of the rocks studied was confirmed by comparing the average concentrations obtained from tuffs and volcanic rocks with proper mean values of rock elemental compositions of the earth's crust. (Author)

  5. Stratigraphy and Petrology of the Grande Soufriere Hills Volcano, Dominica, Lesser Antilles (United States)

    Daly, G.; Smith, A. L.; Garcia, R.; Killingsworth, N.


    The Grande Soufriere Hills volcanic center is located on the south east coast of the island of Dominica in the Lesser Antilles. Although the volcano is deeply dissected, a distinct circular crater that opens to the east can be observed. Within the crater is a lava dome and unconsolidated pyroclastic deposits mantle the southeast flanks of the volcano. These pyroclastic deposits are almost entirely matrix-supported block and ash flows and surges suggesting that Pelean-style eruptions have dominated its most recent activity. Within this sequence is a relatively thin (30-50 cm) clast-supported deposit that has been interpreted as a possible blast deposit. Two age dates from these younger deposits suggest that much of this activity occurred between l0,000 and 12,000 years ago. On the southeastern coast at Pointe Mulâtre and extending approximately 4 km north and at a maximum 2 km west, is a megabreccia of large (up to 3 m) flow-banded andesite clasts set in a semi-lithified medium grained ash matrix. At Pointe Mulâtre this megabreccia is overlain by unconsolidated block and ash flow deposits. To the north of the megabreccia, exposures in the sea cliffs reveal a consolidated sequence of well-bedded alternating coarse and fine deposits suggesting deltaic foreset beds; which in turn appears to be overlain by a yellow- colored relatively coarse flow deposit with an irregular upper surface. The uppermost deposits in the sea cliffs are a sequence of unconsolidated block and ash flow deposits and interbedded fluviatile conglomerates equivalent to the younger flow deposits logged inland. Volcanic rocks from the Grande Soufriere Hills are all porphyritic andesites often containing hypabyssal inclusions. Dominant phenocrysts are plagioclase often with inclusion-rich cores and well developed zoning. Mafic phenocrysts include hornblende, augite and hypersthene. Geochemically these andesites range from 58- 63% SiO2 and show trends of decreasing values for Al2O3, FeO, MgO, CaO, Ti

  6. Comparison between the chemistry of igneous and hydrothermal biotite in the igneous rocks of Sakhtehesar mountain

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    Farima Ayati


    Full Text Available Sakhtehesar mountain is located in Urumieh-Dokhtar magmatic belt and is composed of volcanic and subvolcanic rocks (Pliocene andesite to dacite which intruded the volcanics and pyroclastics of Paleocene age. Three alteration zones including potassic, phyllic and propylitic are recognized in the area. In this paper, the mineral chemistry of magmatic and primary biotite and the mineral chemistry of biotite in potassic and phyllic alteration zones have been studied. Investigations show that primary and secondary biotites are different from each other and hydrothermal fluids associated with the potassic alteration are distinctively different from the fluids associated with the phyllic alteration zone in the area.


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    Arief Mustofa Nur


    Full Text Available Diabas Parang hill is one of location which conservated in area conservation of geological Karangsambung.Now, it is threatened, because there are many mines at surrounding it. Activities of mining not care science andenvironmental conservation.Impact of mining so cause change of topography/morphology, slope become more steep, and mining locationbecome potentially accure rock fall and landslide. Pursuant to result of laboratory analysis, engineeringproperties diabas Parang hill strongless than andesit so it is only fulfil for trotoir.For diabas conservation which is protected so need affort to stop activity of mining. The effort can do seekingaltenative location for mine and/or to change mine activities.

  8. K-Ar age for alunite-bearing rock from the Iwato gold deposit, Kagoshima Prefecture, southern Japan

    International Nuclear Information System (INIS)

    Togashi, Yukio; Shibata, Ken


    K-Ar age determination was made on a whole rock sample of the alunite-bearing silicified rock from the Iwato gold deposit, Kagoshima Prefecture, southern Japan. The sample is from one of the Nansatsu-type gold deposits, whose mineralization is characterized by the occurrence of leaching-type massive silicified rocks with gold dissemination. The result, 4.15 +- 0.78 Ma, is interpreted to be the age of the mineralization at the Iwato gold deposit. It also suggests that the Nansatsu-type deposits were formed in close association with andesitic volcanism in the early Pliocene age. (author)

  9. Geology and stratigraphy of the San Lorenzo Tezonco deep well and its correlation to surrounding ranges, Mexico Basin (United States)

    Arce, J. L.; Layer, P. W.; Morales-Casique, E.; Benowitz, J.


    The San Lorenzo Tezonco deep well stratigraphy records intense episodic volcanic activity in the Mexico Basin and surroundings during the past 20 Ma. The 2008-m deep lithological column is dominated by volcanic material, either as lava flows or pyroclastic deposits (97%), and only the upper most 70 m are composed of lacustrine deposits (3%). Based on geochronology and geochemistry, the lower part of the drill core is represented by rocks correlating to the Tepoztlán Formation (876-2008 m deep) that vary in composition from basaltic-andesite to rhyolite, and ages ranging from 13 to 21.2 Ma. On the surface this formation outcrops near the towns of Malinalco and Tepoztlán, ~43 km south of the deep well. Between depths of 581 and 875 m, volcanic rocks were recovered and are interpreted as lavas from the Sierra de las Cruces that vary in composition from andesite to dacite and range in age from 0.9 Ma to 5 Ma. Additionally, we documented rocks belonging to the Xochitepec Formation, outcropping around Xochimilco, in the Mexico City, with ages ranging from 1.2 and 1.7 Ma, in contrast with the Oligocene age proposed in previous works for these rocks. These new ages plus the chemical composition data, allow us to correlate the Xochitepec rocks with Sierra de las Cruces. Upward in the drill core (510-580 m) there are andesitic rocks that correlate with the 0.25 Ma Cerro de la Estrella volcanic center. The last volcanic package found in the well is correlated to the Santa Catarina basaltic andesites (70-120 m) that are younger than 0.25 Ma, and probably Holocene. Lacustrine deposits crown the stratigraphic column of the drill core with ages probably younger than 34 ka. The San Lorenzo Tezonco well is in a graben-like structure that was filled with more than 1900 m of volcanic products, suggesting that volcanism were intense in the Miocene to the Recent, and the south drainage of the Mexico Basin was closed probably in the early Pleistocene.

  10. Cíge¾ - new field of chloropal and common opal

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    Barok Maroš


    Full Text Available In the open pits in surroudings of village Cígeľ in Prievidza district a new occurance of chloropal and common opal was found. The opal postvulkanic mineralization is related to the vulkanic komplex of the mountain range Vtáčnik. The locality is composed of vulcanic rock and their pyroklastic, represented by particularly by andesite and rhyolit brekcia. The quality of the opals is variable. The resouces of the opals were calculated on the order of hundrens ( XOO kg of available materials. Local opals have also another utilization mostly for the individual jewel.

  11. Neutron activation analysis of ultrabasis rock by Ge(Li) γ-ray spectrometry and group separation

    International Nuclear Information System (INIS)

    Chen Baoguan; Yuan Ling; Fang Chanmeng


    The analytical procedure for determination of 21 elements in two ultrabasis rock samples with Ge(Li) gamma-ray spectrometry and group separation was described. 8 elements including Cr, Fe, Co, Sc, Mn, Na, Cl and Br have been directly determined by INAA. 13 elements including La, Ce, Nd, Sm, Gd, Eu, Tb, Ho, Tm, Yb, Lu, Zn and Cs have been determined by radiochemical separation. The samples of international standard AGV-1 (Andesite) have also been analyzed. The agreement of the results with the values proposed by F.J.Flanagan is satisfactory

  12. Mineralogy and fluid inclusion studies in kalchoye Copper- gold deposit, East of Esfahan

    Directory of Open Access Journals (Sweden)

    Rezvan Mehvary


    Full Text Available Kalchoye Copper-gold deposit is located about 110 kilometers east of Esfahan province and within the Eocene volcano sedimentary rocks. Sandy tuff and andesite lava are important members of this complex.The form of mineralization in area is vein and veinlet and quartz as the main gangue phase. The main ore minerals are chalcopyrite, chalcocite, galena and weathered minerals such as goethite, iron oxides, malachite and azurite. Studies in area indicate that ore mineralization Kalchoye is low sulfide, quartz type of hydrothermal ore deposits and results of thermometry studies on quartz minerals low- medium fluid with low potential mineralization is responsible for mineralization in this area.

  13. Physical volcanology of the mafic segment of the subaqueous New Senator caldera, Abitibi greenstone belt, Quebec, Canada

    International Nuclear Information System (INIS)

    Moore, Lyndsay N; Mueller, Wulf U


    Archean calderas provide valuable insight into internal geometries of subaqueous calderas. The New Senator caldera, Abitibi greenstone belt, Canada, is an Archean example of a subaqueous nested caldera with a basal stratigraphy dominated by gabbro-diorite dykes and sills, ponded magmas and basalt and andesite lava flows. The aim of our study is to focus on the use of physical volcanology to differentiate between the various mafic units found at the base of the New Senator caldera. Differentiation between these various mafic units is important from an exploration point of view because in modern subaqueous summit calders (e.g. Axial Seamount) margins of ponded magmas are often sites of VMS formation.

  14. Dynamic behavior of the Bering Glacier-Bagley icefield system during a surge, and other measurements of Alaskan glaciers with ERS SAR imagery (United States)

    Lingle, Craig S.; Fatland, Dennis R.; Voronina, Vera A.; Ahlnaes, Kristina; Troshina, Elena N.


    ERS-1 synthetic aperture radar (SAR) imagery was employed for the measurement of the dynamics of the Bagley icefield during a major surge in 1993-1994, the measurement of ice velocities on the Malaspina piedmont glacier during a quiescent phase between surges, and for mapping the snow lines and the position of the terminus of Nabesna glacier on Mount Wrangell (a 4317 m andesitic shield volcano) in the heavily glacierized Saint Elias and Wrangell Mountains of Alaska. An overview and summary of results is given. The methods used include interferometry, cross-correlation of sequential images, and digitization of boundaries using terrain-corrected SAR imagery.


    Directory of Open Access Journals (Sweden)

    Hananto Kurnio


    Full Text Available Mineable iron sand deposits in Cilacap – southern coastal area of Central Java have certain coastal characteristics that need to be studied in order to understand its depositional environment. With the knowledge of such environment, it can be applied to look for other places prospective of iron sand deposits that have the same characteristics especially recently when Cilacap’s deposits were almost depleted. Coastal characteristics of iron sand deposit in Cilacap is shown by successive sandy beach ridges separated by marshy valleys typical of prograded coasts and by dunes of sand elongated parallel to the shore line with elevation varies from 0 m to 15 m above sea level. The iron sand deposit was derived from denudation of andesite and “Old Andesite Formation” enriched in magnetite and ilmenite minerals in the steep elevated and deeply weathered rock hinterlands of Cilacap. High sediment loads of Serayu Basin in the hinterland (3,500-4,500 ton/km2/year; Citarum River basin only 800-1,200 ton/km2/year was causing extensive deposition of iron sand in the coastal zone. Key words: coast, characteristic, iron sand, Cilacap Endapan pasir besi yang dapat ditambang di Cilacap – pesisir selatan Jawa Tengah memiliki karakteristik pantai tertentu yang perlu dikaji agar dapat dipahami lingkungan pengendapannya. Dengan pengetahuan tentang lingkungan pengendapan tersebut, dapat diterapkan untuk mencari daerah-daerah lain prospek endapan pasir besi yang memiliki karakteristik yang sama terutama pada akhir-akhir ini ketika endapan Cilacap akan habis. Karakteristik pantai endapan pasir besi di Cilacap dicirikan oleh urutan pematang pantai berpasir yang dipisahkan oleh lembah-lembah berawa khas pantai maju dan oleh gumuk-gumuk pasir memanjang sejajar dengan garis pantai dengan ketinggian bervariasi dari 0 m hingga 15 m dari muka laut. Endapan pasir besi di daerah ini berasal dari proses denudasi andesit dan “Formasi Andesit

  16. Cristobalite in volcanic ash of the soufriere hills volcano, montserrat, british west indies (United States)

    Baxter; Bonadonna; Dupree; Hards; Kohn; Murphy; Nichols; Nicholson; Norton; Searl; Sparks; Vickers


    Crystalline silica (mostly cristobalite) was produced by vapor-phase crystallization and devitrification in the andesite lava dome of the Soufriere Hills volcano, Montserrat. The sub-10-micrometer fraction of ash generated by pyroclastic flows formed by lava dome collapse contains 10 to 24 weight percent crystalline silica, an enrichment of 2 to 5 relative to the magma caused by selective crushing of the groundmass. The sub-10-micrometer fraction of ash generated by explosive eruptions has much lower contents (3 to 6 percent) of crystalline silica. High levels of cristobalite in respirable ash raise concerns about adverse health effects of long-term human exposure to ash from lava dome eruptions.

  17. Eruption of soufriere volcano on st. Vincent island, 1971-1972. (United States)

    Aspinall, W P; Sigurdsson, H; Shepherd, J B


    The Soufrière volcano in St. Vincent erupted from October 1971 to March 1972, as 80 x 10(6) m(3) of basaltic andesite lava was quietly extruded inside the mile-wide crater. The eruption was largely subaqueous, taking place in the 180-m-deep crater lake, and resulted in the emergence of a steep-sided island. The mild character of the eruption and the absence of seismic activity stand in direct contrast to the highly explosive character of the eruption of 1902 to 1903.

  18. Physical volcanology of the mafic segment of the subaqueous New Senator caldera, Abitibi greenstone belt, Quebec, Canada

    Energy Technology Data Exchange (ETDEWEB)

    Moore, Lyndsay N; Mueller, Wulf U [Universite du Quebec a Chicoutimi, 555 boul. du l' Universite, Chicoutimi, Quebec, G7H2B1 (Canada)], E-mail:


    Archean calderas provide valuable insight into internal geometries of subaqueous calderas. The New Senator caldera, Abitibi greenstone belt, Canada, is an Archean example of a subaqueous nested caldera with a basal stratigraphy dominated by gabbro-diorite dykes and sills, ponded magmas and basalt and andesite lava flows. The aim of our study is to focus on the use of physical volcanology to differentiate between the various mafic units found at the base of the New Senator caldera. Differentiation between these various mafic units is important from an exploration point of view because in modern subaqueous summit calders (e.g. Axial Seamount) margins of ponded magmas are often sites of VMS formation.


    Directory of Open Access Journals (Sweden)

    Sz. Fischer


    Full Text Available Purpose. Using adequate granular materials and layer structures in the railway super- and substructure is able to stabilise railway track geometry. For this purpose special behaviour of above materials has to be determined, e.g. inner shear resistance. Inner shear resistance of granular media with and without geogrid reinforcement in different depths is not known yet. Methodology. The author developed a special laboratory method to measure and define inner shear resistance of granular materials, it is called «multi-level shear box test». This method is adequate to determine inner shear resistance (pushing force vs. depth (distance from the «zero» surface. Two different granular materials: andesite railway ballast (31.5/63 mm and andesite railway protection layer material (0/56 mm, and seven different types of geogrids (GG1…GG7 were used during the tests. Findings. Values of inner shear resistance functions of andesite railway ballast without geogrid reinforcement and reinforced with different types of geogrids and andesite granular protection layer in function of the vertical distance from the geogrid plane were determined with multi-layer shear box tests when the material aggregation is uncompacted and compacted. Only the compacted sample was tested in case of the 0/56 mm protection layer. Cubic polynomial regression functions fitted on the mean values of the measurements are described graphically. Determination coefficients with values of R2>0.97 were resulted in all the cases of regression functions. Based on the polynomial regression functions fitted on the mean values of the test results, three increasing factors were determined in function of the distance measured from the geogrid. Increasing factor «A», «B» and «D». Originality. Multi-level shear box test, developed by the author, is certified unequivocally adequate for determining inner shear resistance of reinforced and unreinforced granular materials, e.g. railway ballast

  20. Geochemical of trace elements in volcanics rocks Peninsula Fildes, Fildes Bay Rey Jorge island, south Shetland

    International Nuclear Information System (INIS)

    Masquelin, H.; Vaz Chavez, N.


    The authors present some geochemical data derived from the multielement analysis of three different types of volcanic rocks collected around Fildes Bay on King George Island, South Shetland. Volcanic rocks from Fildes Peninsula Group may be distinguished from those Marian Cove by their hydrothermal alteration. Apparently the correlation between NI ands Cr allows for the observation of the stratigraphic separation of samples of the same kind. Consequently, the correlation between Cu and As show a distinction between Marian Cove propylitised tuffites and both Brecciated Andesites and pyroclastic rock from Fildes Peninsula Group.

  1. Assembling an ignimbrite: Compositionally defined eruptive packages in the 1912 Valley of Ten Thousand Smokes ignimbrite, Alaska (United States)

    Fierstein, J.; Wilson, C.J.N.


    The 1912 Valley of Ten Thousand Smokes (VTTS) ignimbrite was constructed from 9 compositionally distinct, sequentially emplaced packages, each with distinct proportions of rhyolite (R), dacite (D), and andesite (A) pumices that permit us to map package boundaries and flow paths from vent to distal extents. Changing pumice proportions and interbedding relationships link ignimbrite formation to coeval fall deposition during the first ???16 h (Episode I) of the eruption. Pumice compositional proportions in the ignimbrite were estimated by counts on ???100 lapilli at multiple levels in vertical sections wherever accessible and more widely over most of the ignimbrite surface in the VTTS. The initial, 100% rhyolite ignimbrite package (equivalent to regional fall Layer A and occupying ???3.5 h) was followed by packages with increasing proportions of andesite, then dacite, emplaced over ???12.5 h and equivalent to regional fall Layers B1-B3. Coeval fall deposits are locally intercalated with the ignimbrite and show parallel changes in R:D (rhyolite:dacite) proportions, but lack significant amounts of andesite. Andesite was thus dominantly a low-fountaining component in the eruption column and is preferentially represented in packages filling the VTTS north of the vent. The most extensive packages (3 and 4) occur in B1 and early B2 times where flow mobility and volume were optimized; earlier all-rhyolite flows (Package 1) were highly energetic but less voluminous, while later packages (5-9) were both less voluminous and emplaced at lower velocities. Package boundaries are expressed as one or more of the following: sharp color changes corresponding to compositional variations; persistent finer-grained basal parts of flow units; compaction swales filled by later packages; erosional channels cut by the flows that fill them; lobate accumulations of one package; and (mostly south of the vent) intercalated fall deposit layers. Clear flow-unit boundaries are best developed between

  2. Thermoluminescence dating in the South-West Pacific region

    International Nuclear Information System (INIS)

    Prescott, J.R.


    The archaeometry laboratory of the University of Adelaide has undertaken a variety of dating projects for archaeologists in the region. For example, a survey of Pacific Island pottery has shown that themoluminescence dating is likely to be severely limited in usefulness on islands remote from the continental shelf i.e., the andesitic island arcs and oceanic islands. On the mainland of Australia, we have dated prehistoric campsites using ovenstones from fireplaces and have compared C-14 ages with themoluminescent ages. Where there is a close stratigraphic association of the C-14 and TL materials, there is good agreement between the two methods. (author)

  3. The seismic reassessment Mochovce NPP

    International Nuclear Information System (INIS)

    Baumeister, P.


    The design of Mochovce NPP was based on the Novo-Voronez type WWER-440/213 reactor - twin units. Seismic characteristic of this region is characterized by very low activity. Mochovce NPP site is located on the rock soil with volcanic layer (andesit). Seismic reassessment of Mochovce NPP was done in two steps: deterministic approach up to commissioning confirmed value Horizontal Peak Ground Acceleration HPGA=0.1 g and activities after commissioning as a consequence of the IAEA mission indicate higher hazard values. (author)

  4. Update of map the volcanic hazard in the Ceboruco volcano, Nayarit, Mexico (United States)

    Suarez-Plascencia, C.; Camarena-Garcia, M. A.; Nunez-Cornu, F. J.


    The Ceboruco Volcano (21° 7.688 N, 104° 30.773 W) is located in the northwestern part of the Tepic-Zacoalco graben. Its volcanic activity can be divided in four eruptive cycles differentiated by their VEI and chemical variations as well. As a result of andesitic effusive activity, the "paleo-Ceboruco" edifice was constructed during the first cycle. The end of this cycle is defined by a plinian eruption (VEI between 3 and 4) which occurred some 1020 years ago and formed the external caldera. During the second cycle an andesitic dome built up in the interior of the caldera. The dome collapsed and formed the internal caldera. The third cycle is represented by andesitic lava flows which partially cover the northern and south-southwestern part of the edifice. The last cycle is represented by the andesitic lava flows of the nineteenth century located in the southwestern flank of the volcano. Actually, moderate fumarolic activity occurs in the upper part of the volcano showing temperatures ranging between 20° and 120°C. Some volcanic high frequency tremors have also been registered near the edifice. Shows the updating of the volcanic hazard maps published in 1998, where we identify with SPOT satellite imagery and Google Earth, change in the land use on the slope of volcano, the expansion of the agricultural frontier on the east sides of the Ceboruco volcano. The population inhabiting the area is 70,224 people in 2010, concentrated in 107 localities and growing at an annual rate of 0.37%, also the region that has shown an increased in the vulnerability for the development of economic activities, supported by highway, high road, railroad, and the construction of new highway to Puerto Vallarta, which is built in the southeast sector of the volcano and electrical infrastructure that connect the Cajon and Yesca Dams to Guadalajara city. The most important economic activity in the area is agriculture, with crops of sugar cane (Saccharum officinarum), corn, and jamaica

  5. Petrology, mineral chemistry and tectono-magmatic setting of volcanic rocks from northeast Farmahin, north of Arak

    Directory of Open Access Journals (Sweden)

    Reza Zarei Sahamieh


    Full Text Available Introduction The study area is a small part of the Urumieh-Dokhtar structural zone in the Markazi province, located in the northeastern part of the Farmahin, north of Arak (Hajian, 1970. The volcanic rocks studied from the area include andesite, dacite, rhyodacite, ignimbrite and tuff of Middle to Late Eocene age (middle Lutetian to upper Lutetian (Ameri et al., 2009. It seems that folding and faulting is caused in sedimentary basin and volcanic activities. On the other hand, except of orogeny maybe rifting had rule in eruption so that this case has seen in the other area such as Taft and Khezrabad in central Iran (Zarei Sahamieh et al., 2008. The oldest formation in the studied area is Triassic limestones. The dominant textures of these rocks are porphyritic, microlite porphyritic, microlitic and rarely sieve-texture. Sieve texture and dusty texture (dusty plagioclases indicates magma mixing. Mineralogically, they contain plagioclases, clinopyroxenes, amphiboles, quartz and biotite as the main constituents and zircon, apatite, and opaque minerals as accessories. Plagioclases in the andesitic and basaltic- andesite rocks are labradorite, bytownite and anorthite (based on electron microprobe .Moreover, plagioclases in andesitic rocks show that H2O is lesser than 2.5 precent. Amphibole is found in both plagioclases and groundmass. Materials and methods In this article are used different analyses methods such as XRF, ICP-MS and EPMA. Whole-rock major and trace element analyses were determined with ICP-MS method. The major and trace element composition of some rock was determined by electron probe micro-analysis (EPMA using a Cameca SX100 instrument in Iran Mineral Processing Research Center (IMPRC. Moreover, whole-rock major and some trace element analyses for some samples were obtained by X-ray fluorescence (XRF, using an ARL Advant-XP automated X-ray spectrometer. Results Chemical data based on electron micro probe studies of minerals indicate

  6. Yield strengths of flows on the earth, Mars, and moon. [application of Bingham plastic model to lava flows (United States)

    Moore, H. J.; Arthur, D. W. G.; Schaber, G. G.


    Dimensions of flows on the earth, Mars, and moon and their topographic gradients obtained from remote measurements are used to calculate yield strengths with a view to explore the validity of the Bingham plastic model and determine whether there is a relation between yield strengths and silica contents. Other factors are considered such as the vagaries of natural phenomena that might contribute to erroneous interpretations and measurements. Comparison of yield strengths of Martian and lunar flows with terrestrial flows suggests that the Martian and lunar flows are more akin to terrestrial basalts than they are to terrestrial andesites, trachytes, and rhyolites.

  7. Multi-elemental characterization of volcanic and vulcano-sedimentary rocks from Pina petroleum ore, central Cuba

    Energy Technology Data Exchange (ETDEWEB)

    Montero-Cabrera, M.E.; Herrera-Peraza, E.; Betancourt-Tanda, L.; Campa-Menendez, R.; Diaz-Rizo, O. (Instituto Superior de Ciencia y Tecnologia Nuclear (ISCTN), La Habana (Cuba)); Rodriguez-Martinez, N.; Segura-Soto, R.; Hernandez-Lopez, B.; Valdes-Lopez, S. (Centro de Investigaciones y Desarrollo del Petroleo, La Habana (Cuba))


    Concentrations of 32 elements in 22 clay, limestone, tuff and volcanic rock samples from the Pina ore have been obtained by neutron activation and X-ray fluorescence analyses. Several LILE (large ion lithofile elements) and REE (rare earth element) concentration diagrams showed the calc-alkaline character of the volcanic rocks corresponding to the Greater Antilles Island, Arc. The basaltic andesite behavior of the rocks studied was confirmed by comparing the average concentrations obtained from tuffs and volcanic rocks with proper mean values of rock elemental compositions of the earth's crust. (Author).

  8. Final Environmental Assessment for 2012-14 Capital Improvements Program (CIP) for Davis-Monthan Air Force Base (AFB), Tucson, Arizona (United States)


    but most of the andesite and basaltic flows were fo1med in the last 50 million years. The oldest rocks in the Tucson Basin ru·e the metavolcanic...Pinal Schist, fo1med approximately 1.7 billion years ago (U.S. Geological Smvey 2003). Some basaltic flows occmTed as early as 4 million years ago and...pe1mits. ACMs are a pruticulru· concem for demolition projects because of potential exposme of workers to hazardous fibers released into the air

  9. Geochemical and geochronological constrains on the Chiang Khong volcanic rocks (northwestern Thailand) and its tectonic implications (United States)

    Qian, Xin; Feng, Qinglai; Chonglakmani, Chongpan; Monjai, Denchok


    Volcanic rocks in northwestern Thailand exposed dominantly in the Chiang Khong area, are commonly considered to be genetically linked to the tectonic evolution of the Paleo-Tethyan Ocean. The volcanic rocks consist mainly of andesitic to rhyolitic rocks and are traditionally mapped as Permian-Triassic sequences. Our zircon U-Pb geochronological results show that two andesitic samples (TL-1-B and TL-31-B), are representative of the Doi Yao volcanic zone, and give a mean weighted age of 241.2±4.6 Ma and 241.7±2.9 Ma, respectively. The rhyolitic sample (TL-32-B1) from the Doi Khun Ta Khuan volcanic zone erupted at 238.3±3.8 Ma. Such ages indicate that Chiang Khong volcanic rocks erputed during the early Middle Triassic period. Seven samples from the Doi Yao and Doi Khun Ta Khuan zones exhibit an affinity to arc volcanics. Three rhyolitic samples from the Chiang Khong area have a geochemical affinity to both arc and syn-collisional volcanic rocks. The Chiang Khong arc volcanic rocks can be geochemically compared with those in the Lampang area in northern Thailand, also consistent with those in Jinghong area of southwestern Yunnan. This indicates that the Chiang Rai arc-volcanic zone might northwardly link to the Lancangjiang volcanic zone in southwestern China.

  10. Inventory of uranium resources potency at Kawat area, upper Mahakam, East Kalimantan detailed prospecting stage

    International Nuclear Information System (INIS)

    Ngadenin; I Gde Sukadana; Adi Gunawan Muhammad; Suripto


    Result of the general prospecting in East Kalimantan has found several radioactivity outcrop anomalies at upper Mahakam in the acid volcanic rock area which is approximately 25 km 2 in wide. The objective of the research is to know detailed geological information and characteristic of uranium mineralization. Method of this research are detailed geological, radiometric and geochemical mapping 1:10.000 on scale. The lithology of Kawat area is composed of seven units of rock. They are black clay unit, feldspatic sandstone unit, Nyaan rhyolite unit, lower andesite unit, Kawat rhyolite unit, upper andesite unit and tuffaceous sandstone unit. Evolving fault is dextral fault and normal fault. The trending of dextral fault is west-east and southwest-northeast, meanwhile the trending of normal faults is west-east and southwest northeast. There are two period of uranium mineralization occurrences in the area, the first is connected with the eruption of Nyaan rhyolite magma and the second is connected with the eruption of Kawat rhyolite magma. Uranium mineralization occurred in the stage of hydrothermal process and including in the pneumatogenic class of volcanogenic uranium deposits. This investigation has yielded two sites of potential uranium sector are the Nyaan sector with an area of about 6 km 2 and Kawat sector with an area of about 10 km 2 . (author)

  11. Earth's early O2 cycle suppressed by primitive continents (United States)

    Smit, Matthijs A.; Mezger, Klaus


    Free oxygen began to accumulate in Earth's surface environments between 3.0 and 2.4 billion years ago. Links between oxygenation and changes in the composition of continental crust during this time are suspected, but have been difficult to demonstrate. Here we constrain the average composition of the exposed continental crust since 3.7 billion years ago by compiling records of the Cr/U ratio of terrigenous sediments. The resulting record is consistent with a predominantly mafic crust prior to 3.0 billion years ago, followed by a 500- to 700-million-year transition to a crust of modern andesitic composition. Olivine and other Mg-rich minerals in the mafic Archaean crust formed serpentine minerals upon hydration, continuously releasing O2-scavenging agents such as dihydrogen, hydrogen sulfide and methane to the environment. Temporally, the decline in mafic crust capable of such process coincides with the first accumulation of O2 in the oceans, and subsequently the atmosphere. We therefore suggest that Earth's early O2 cycle was ultimately limited by the composition of the exposed upper crust, and remained underdeveloped until modern andesitic continents emerged.

  12. {sup 40}K-{sup 40}Ar dating of the Late Miocene transition from calc-alkaline to alkali basalt series, Northwestern Algeria; Datation {sup 40}K-{sup 40}Ar de la transition du volcanisme calco-alcalin au volcanisme alcalin en Oranie au Miocene superieur

    Energy Technology Data Exchange (ETDEWEB)

    Louni-Hacini, A; Megartsi, M; Semroud, B [Algiers Univ. (Algeria). Faculte des Sciences; Bellon, H; Maury, R C; Cotten, J; Coutelle, A [Brest Univ., 29 (France); Coulon, C [Aix-Marseille-3 Univ., 13 - Marseille (France)


    Neogene volcanic rocks from the northwestern coast of Algeria include calc-alkaline to shoshonitic andesites and dacites (Sahel of Oran and M`Sirda areas) and alkali basalts (Tafna valley). Seventeen new {sup 40}K-{sup 40}Ar ages indicate that these volcanics were emplaced during two distinct periods, from 11.7 to 7.2 Ma and ca. 4 Ma, respectively. All the andesites and dacites were emplaced during the first period, and their trace element characteristics are typical of subduction -and/or collision- related magmas. They are enriched in large-ion lithophile elements and display negative Nb anomalies. The associated alkali basalts are chemically heterogeneous, and contain variable amounts of TiO{sub 2} and P{sub 2}O{sub 5}. Their multielement plots show either positive or slightly negative Nb anomalies. These features suggest that the Neogene volcanics studied derive from two different types of mantle sources, i.e. an enriched sub-continental mantle and an upper mantle carrying a subduction-related geochemical imprint. The latter component may have inherited its specific signature from an earlier subduction event. This ``orogenic`` imprint tends to disappear through time as the contribution of the sub-continental mantle increases. (authors). 12 refs., 4 figs., 2 tabs.

  13. Petrogenesis and tectonic implications of Late Devonian arc volcanic rocks in southern Beishan orogen, NW China: Geochemical and Nd-Sr-Hf isotopic constraints (United States)

    Guo, Qian-Qian; Chung, Sun-Lin; Xiao, Wen-Jiao; Hou, Quan-Lin; Li, Shan


    Late Devonian (ca. 370 Ma) volcanic rocks provide important information about the nature of magmatism during the tectonic transition between the Early and Late Paleozoic in the Beishan orogen, southern Central Asian Orogenic Belt. They are predominantly an andesitic-dacitic-rhyolitic assemblage, characterized by alkali contents ranging from slightly calcic to slightly alkaline. The rhyolitic rocks are generally ferroan, whereas the andesitic rocks are magnesian. These volcanic rocks exhibit similar trace element characteristics to those of continental arcs. Strongly negative εNd(t) values (- 2.8 to - 3.6) and high Sr isotopic compositions (initial 87Sr/86Sr = 0.7036-0.7108) suggest that they are mainly derived from an ancient crust. However, the positive zircon εHf(t) values (+ 1.4 to + 16.4) support the role of juvenile components in their genesis, indicating the significant input of new mantle-derived magmas. These characteristics imply a hybrid derivation, from an ancient crustal source with the addition of juvenile materials during magma genesis, or perhaps heterogeneous contamination or hybridization during magma emplacement. Combined with the regional geology, our results indicate that the Late Devonian magmatism resulted from a southward retreat of the subduction zone, which records significant continental crustal growth in a transitional arc or an accretionary arc setting. The distinct geochemical compositions, especially the Nd-Hf isotope decoupling of the Dundunshan volcanic rocks, imply a significant change in the geodynamic setting in the Late Paleozoic.

  14. Volcanic sequence in Late Triassic – Jurassic siliciclastic and evaporitic rocks from Galeana, NE Mexico

    International Nuclear Information System (INIS)

    Cruz-Gómez, E.M.; Velasco-Tapia, F.; Ramírez-Fernández, J.A.; Jenchen, U.; Rodríguez-Saavedra, P.; Rodríguez-Díaz, A.A.; Iriondo, A.


    In northeastern Mexico, volcanic rocks interbedded with Late Triassic–Jurassic siliciclastic and evaporitic strata have been linked to magmatic arcs developed in the Pangea western margin during its initial phase of fragmentation. This work provides new petrographic and geochemical data for volcanism included in the El Alamar and Minas Viejas formations outcropping in the Galeana region. Andesitic dykes and sills (n= 10) in the El Alamar redbeds show SiO2= 47.5–59.1% and MgO= 1.2–4.2%, as well as a geochemical affinity to island arc magmas. This work represents the first report of this tectonic setting in the region. Geological and petrographic evidence suggest that this arc system likely developed after ~220 and before ~193Ma. Trachy-andesitic and rhyodacitic domes (n= 20) associated with the Minas Viejas gypsum-carbonates sequence show SiO2= 61.8–82.7% and MgO= 0.1–4.0% with a tectonic affinity to continental arc. A rhyodacite sample from this region has been dated by U-Pb in zircon, yielding an age of 149.4 ± 1.2Ma (n= 21), being the youngest age related to this arc. Finally, we propose a threestep model to explain the tectonic evolution from Late Triassic island arc to Jurassic continental arc system in the northeastern Mexico.

  15. Volcanic sequence in Late Triassic – Jurassic siliciclastic and evaporitic rocks from Galeana, NE Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Cruz-Gómez, E.M.; Velasco-Tapia, F.; Ramírez-Fernández, J.A.; Jenchen, U.; Rodríguez-Saavedra, P.; Rodríguez-Díaz, A.A.; Iriondo, A.


    In northeastern Mexico, volcanic rocks interbedded with Late Triassic–Jurassic siliciclastic and evaporitic strata have been linked to magmatic arcs developed in the Pangea western margin during its initial phase of fragmentation. This work provides new petrographic and geochemical data for volcanism included in the El Alamar and Minas Viejas formations outcropping in the Galeana region. Andesitic dykes and sills (n= 10) in the El Alamar redbeds show SiO2= 47.5–59.1% and MgO= 1.2–4.2%, as well as a geochemical affinity to island arc magmas. This work represents the first report of this tectonic setting in the region. Geological and petrographic evidence suggest that this arc system likely developed after ~220 and before ~193Ma. Trachy-andesitic and rhyodacitic domes (n= 20) associated with the Minas Viejas gypsum-carbonates sequence show SiO2= 61.8–82.7% and MgO= 0.1–4.0% with a tectonic affinity to continental arc. A rhyodacite sample from this region has been dated by U-Pb in zircon, yielding an age of 149.4 ± 1.2Ma (n= 21), being the youngest age related to this arc. Finally, we propose a threestep model to explain the tectonic evolution from Late Triassic island arc to Jurassic continental arc system in the northeastern Mexico.

  16. Mineralization and geochemical studies in the Kalchouyeh occurrence, southwest of Naein

    Directory of Open Access Journals (Sweden)

    Hengameh Hosseini Dinani


    Full Text Available Kalchouyeh area in southwest of Naein is located in the Urumieh-Dokhtar volcano-plutonic belt. Mineralization occurred mainly as disseminations and veinlets hosted by trachy-andesite and pyroxene andesites. For mineralogy, alteration, fluid inclusion and geochemical studies, the two major mineralized zones: A (larger vein from the north-northwest and B (smaller vein from the east-southeast of the area were sampled. Alteration studies revealed that the main alteration assemblages are silicification and propylitic. The ore minerals are chalcopyrite, galena, pyrite, bornite, chalcocite, covellite, goethite, malachite, azurite, cerussite and cuprite with quartz, calcite and barite as the main gangues. Fluid inclusion studies demonstrated that salinity and homogenization temperatures were 0.38-4.23 and 0.166-9.188 wt% NaCl and 175-252°C and 250-324°C at the A and B veins, respectively. Rare Earth Element (REE plots show negative slopes that is one of the features for calc-alkaline magmas. La/Y is higher than 1 showing that mineralizing fluids were neutral to basic. According to the data, direction of ore-bearing fluids movement was determined to be from east-southeast toward north-northwest (from B to A veins(, approximate site of mineralization center is located adjacent to smaller vein and the mineralization is epithermal in type.

  17. Geochemical provenance of anomalous metal concentrations in stream sediments in the Ashton 1:250,000 quadrangle, Idaho/Montana/Wyoming

    International Nuclear Information System (INIS)

    Shannon, S.S. Jr.


    Stream-sediment samples from 1500 sites in the Ashton, Idaho/Montana/Wyoming 1:250,000 quadrangle were analyzed for 45 elements. Almost all samples containing anomalous concentrations (exceeding one standard deviation above the mean value of any element) were derived from drainage basins underlain by Quaternary rhyolite, Tertiary andesite or Precambrian gneiss and schist. Aluminum, barium, calcium, cobalt, iron, nickel, magnesium, scandium, sodium, strontium, and vanadium have no andesite provenance. Most anomalous manganese, europium, hafnium, and zirconium values were derived from Precambrian rocks. All other anomalous elemental concentrations are related to Quaternary rhyolite. This study demonstrates that multielemental stream-sediment analyses can be used to infer the provenance of stream sediments. Such data are available for many parts of the country as a result of the National Uranium Resource Evaluation. This study suggests that stream-sediment samples collected in the Rocky Mountains can be used either as pathfinders or as direct indicators to select targets for mineral exploration for a host of metals

  18. The Relationship Between Lithology and Slope Morphology in the Tucson Mountains, Arizona.

    Directory of Open Access Journals (Sweden)

    Kamel Khanchoul


    Full Text Available The relationship between lithology and slope morphology is investigated at eight sites on granitic, andesitic, andsedimentary hillslopes in the Tucson Mountains, Arizona. Several methods are used in the study. Topographic profi lesare constructed. Skewness indices, slope length, and mean slope angles of the different slope profi les are computed andcompared with each other. Debris size analysis has permitted for some profi les, the determination of hillfront/piedmontjunctions. The nature and structural characteristics of the bedrock are the ones that determine the hillslope morphologyin this semi-arid region. There are, as a matter of fact, variations in profi les on the same bedrock nature but differentlyexposed. More precise morphologic studies have been also done in comparing the different lithologic pairs. They havepermitted to show some similarities in shapes. The granitic-andesitic slopes and andesiic-sedimentary slopes are thebest comparisons which show the relationship between lithology and slope morphology. The granitic-sedimentary sloperelationship is shown in the hillfront concavities, mountain front and piedmont mean slope angles.

  19. Trace Elements and Minerals in Fumarolic Sulfur: The Case of Ebeko Volcano, Kuriles

    Directory of Open Access Journals (Sweden)

    E. P. Shevko


    Full Text Available Native sulfur deposits on fumarolic fields at Ebeko volcano (Northern Kuriles, Russia are enriched in chalcophile elements (As-Sb-Se-Te-Hg-Cu and contain rare heavy metal sulfides (Ag2S, HgS, and CuS, native metal alloys (Au2Pd, and some other low-solubility minerals (CaWO4, BaSO4. Sulfur incrustations are impregnated with numerous particles of fresh and altered andesite groundmass and phenocrysts (pyroxene, magnetite as well as secondary minerals, such as opal, alunite, and abundant octahedral pyrite crystals. The comparison of elemental abundances in sulfur and unaltered rocks (andesite demonstrated that rock-forming elements (Ca, K, Fe, Mn, and Ti and other lithophile and chalcophile elements are mainly transported by fumarolic gas as aerosol particles, whereas semimetals (As, Sb, Se, and Te, halogens (Br and I, and Hg are likely transported as volatile species, even at temperatures slightly above 100°C. The presence of rare sulfides (Ag2S, CuS, and HgS together with abundant FeS2 in low-temperature fumarolic environments can be explained by the hydrochloric leaching of rock particles followed by the precipitation of low-solubility sulfides induced by the reaction of acid solutions with H2S at ambient temperatures. The elemental composition of native sulfur can be used to qualitatively estimate elemental abundances in low-temperature fumarolic gases.

  20. Lead and strontium isotopic evidence for crustal interaction and compositional zonation in the source regions of Pleistocene basaltic and rhyolitic magmas of the Coso volcanic field, California (United States)

    Bacon, C.R.; Kurasawa, H.; Delevaux, M.H.; Kistler, R.W.; Doe, B.R.


    The isotopic compositions of Pb and Sr in Pleistocene basalt, high-silica rhyolite, and andesitic inclusions in rhyolite of the Coso volcanic field indicate that these rocks were derived from different levels of compositionally zoned magmatic systems. The 2 earliest rhyolites probably were tapped from short-lived silicic reservoirs, in contrast to the other 36 rhyolite domes and lava flows which the isotopic data suggest may have been leaked from the top of a single, long-lived magmatic system. Most Coso basalts show isotopic, geochemical, and mineralogic evidence of interaction with crustal rocks, but one analyzed flow has isotopic ratios that may represent mantle values (87Sr/86Sr=0.7036,206Pb/204Pb=19.05,207Pb/204Pb=15.62,208Pb/204Pb= 38.63). The (initial) isotopic composition of typical rhyolite (87Sr/86Sr=0.7053,206Pb/204Pb=19.29,207Pb/204Pb= 15.68,208Pb/204Pb=39.00) is representative of the middle or upper crust. Andesitic inclusions in the rhyolites are evidently samples of hybrid magmas from the silicic/mafic interface in vertically zoned magma reservoirs. Silicic end-member compositions inferred for these mixed magmas, however, are not those of erupted rhyolite but reflect the zonation within the silicic part of the magma reservoir. The compositional contrast at the interface between mafic and silicic parts of these systems apparently was greater for the earlier, smaller reservoirs. ?? 1984 Springer-Verlag.

  1. High resolution CSMT method for shallow structure; Senjo ochi ni okeru kobunkaino denjiho tansa

    Energy Technology Data Exchange (ETDEWEB)

    Yamane, K; Takasugi, S [GERD Geothermal Energy Research and Development Co. Ltd., Tokyo (Japan); Inazaki, S [Geological Survey of Japan, Tsukuba (Japan); Sasaki, Y


    Electromagnetic exploration methods and seismic reflection methods are conducted for the study of applicability of geophysical exploration to shallow layer geological survey. In the study, four north-south traverse lines are set in 400mtimes200m grassland. Tensor type CSMT methods are employed, a CSMT method using 96kHz-1kHz artificial magnetic fields and an MT method using 1kHz-10kHz natural magnetic fields, for the determination of resistivity distribution in the ground. Distributed in the site are a surface layer composed of gravel-containing sand and silt, andesitic fractured lava, and massive andesite, and the exploration reaches several tens of meters below the surface. The results of CSMT measurements are found to be in agreement with reflection profiles acquired simultaneously with these CSMT measurements. It is found, furthermore, that CSMT profiles help identify reflection waveforms in a domain where reflection is obscure. It is also found that electromagnetic methods are effective in fault logging because they are very sensitive to porosity, or the amount of pore water, which is higher in a domain with subsurface cracks than in the neighborhood without cracks. 1 ref., 4 figs.

  2. Gold in primary high thermal transformations of the Au porphyry deposit Biely vrch

    International Nuclear Information System (INIS)

    Kozak, J.; Kodera, P.; Lexa, J.; Chovan, M.


    Porphyry gold deposit Biely vrch is situated in northern part of the Javorie stratovolcano in eastern part of Central Slovakia Volcanic Field. Intrusion of diorite to andesite porphyry with andesites is affected by hydrothermal alterations with dominant intermediate argillic alteration. Accumulations of gold are spatially associated with stockwork, formed by different types of quartz veinlets. Gold grains occur in altered rocks in the vicinity of quartz veinlets and rarely also as inclusions in vein. Analysed gold grains are chemically very homogenous and have fineness between 87 to 99.50 wt % Au while silver is the only significant element in addition to gold. In deeper parts of the deposit gold also occurs associated with K and Ca-Na silicate alteration which confirms precipitation of gold already in early stages of the hydrothermal system from high salinity Fe-K rich salt melt based on analyses of corresponding fluid inclusions. Difference in the fineness of gold is not significant between primary and secondary hydrothermal alterations. The highest fineness of gold (more than 99 wt %) in advanced argillic alteration is probably caused by remobilisation by acidic hydrothermal fluids. (authors)

  3. Geochemistry of the Bossoroca greenstone belt, Southernmost Brazil

    International Nuclear Information System (INIS)

    Koppe, J.C.; Hartmann, L.A.


    The Bossoroca greenstone belt is situated in the center of the State of Rio Grande do Sul and has a north-south extension of 18 Km and an east-west of 12 Km. It comprises two sequences. The lower Arroio Lajeadinho Sequence is made up of ultramafic schists and serpentinites, besides amphibolite, meta basalts and mafic meta-volcanoclastic rocks and banded iron-formation; some chert and graphitic rocks also occur. The upper Campestre Sequence is made up of meta volcanoclastic rocks of basaltic to rhyolitic composition with predominance of andesite. They are N A 2 O-rich (5.0 wt%), K 2 O-poor (0.8 wt%), with high Na/K ratios. The REE patterns are rather flat, with small negative Eu anomaly, similar to andesite from Archean or younger greenstone belts. The major and trace elements in samples from the Campestre Sequence were determined by X-ray fluorescence analysis and the rare earth elements by induced coupled plasma. (author)

  4. Paleogene volcanism in Central Afghanistan: Possible far-field effect of the India-Eurasia collision (United States)

    Motuza, Gediminas; Šliaupa, Saulius


    A volcanic-sedimentary succession of Paleogene age is exposed in isolated patches at the southern margin of the Tajik block in the Ghor province of Central Afghanistan. The volcanic rocks range from basalts and andesites to dacites, including adakites. They are intercalated with sedimentary rocks deposited in shallow marine environments, dated biostratigraphically as Paleocene-Eocene. This age corresponds to the age of the Asyābēd andesites located in the western Ghor province estimated by the 40Ar/39Ar method as 54 Ma. The magmatism post-dates the Cimmerian collision between the Tajik block (including the Band-e-Bayan block) and the Farah Rod block located to the south. While the investigated volcanic rocks apparently bear geochemical signatures typical to an active continental margin environment, it is presumed that the magmatism was related to rifting processes most likely initiated by far-field tectonics caused by the terminal collision of the Indian plate with Eurasia (Najman et al., 2017). This event led to the dextral movement of the Farah Rod block, particularly along Hari Rod (Herat) fault system, resulting in the development of a transtensional regime in the proximal southern margin of the Tajik block and giving rise to a rift basin where marine sediments were interbedded with pillow lavas intruded by sheeted dyke series.

  5. Archean crustal evolution in the central Minto block, northern Quebec

    Energy Technology Data Exchange (ETDEWEB)

    Skulski, T; Percival, J A; Stern, R A [Geological Survey of Canada, Ottawa, ON (Canada)


    The central Minto block contains three volcano-sedimentary successions. Near Lake Qalluviartuuq, an isotopically primitive ({sup 2.83} {sup Ga}{epsilon}{sub Nd} +3.8 to +2.3) 2.83 Ga volcano-plutonic sequence comprises depleted tholeiitic basalts, anorthositic gabbro, and diorite-granodiorite that is unconformably overlain by <2.77 Ga conglomerates. Overlying the conglomerate is a more evolved ({sup 2.76} {sup Ga}{epsilon}{sub Nd} +1.8) calc-alkaline sequence of pillow basalts, andesites, and peridotite cut by 2.73 Ga diorite. To the west, and in inferred tectonic contact, the sediment-dominated Kogaluc sequence includes both isotopically evolved calc-alkaline rocks ({sup 2.76} {sup Ga}{epsilon}{sub Nd} +1.6 to -0.1) including <2.76 Ga rhyolitic tuff, pillowed andesites, and 2.76 Ga quartz-feldspar porphyry, and less abundant, depleted tholeiitic basalts (2.76 GaF-Nd +2.4). These are interlain with sedimentary rocks including banded iron-formation, quartzite, and metagreywacke. Calc-alkaline batholiths include 2.78 Ga pyroxene-bearing intermediate and felsic plutons ({sup 2.78Ga}{epsilon}{sub Nd} <+2.7) and younger, peraluminous tonalites ({epsilon}{sub Nd} <+1.3). Late, 2.73 Ga peraluminous granitoids are isotopically evolved ({sup 2.725Ga}{epsilon}{sub Nd} - 1. 6). (author). 19 refs., 4 tabs., 5 figs.

  6. Magnetostratigraphy of the Ahuachapan-Chipilapa geothermal field, El Salvador

    Energy Technology Data Exchange (ETDEWEB)

    Fucugauchi, Jaime Urrutia [Universidad Nacional Autonoma de Mexico, Lab. de Paleomagnetismo y Geofisica Nuclear, Coyoacan (Mexico); Rodriguez, Vicente Torres; Partida, Eduardo Gonzalez [Instituto de Investigaciones Electricas, Dept. de Geotermia, Cuernavaca, Morelos (Mexico)


    The volcanic stratigraphy for the Ahuachapan-Chipilapa geothermal field is defined on the basis of the magnetostratigraphic results on 156 oriented samples from 33 sites. The magnetostratigraphic sequence shows that the major volcanism associated with the Concepcion de Ataco caldera and the Cuyanausul volcano took place during the middle Brunhes chron (Quaternary). Pre-caldera activity of small centers such as Empalizada and Apaneca in the southern sector of the field occurred during the early Brunhes (0.77{+-}0.07 Ma). Basaltic-andesitic activity associated with the Cuyanausul volcano took place earlier, i.e. during the Matuyama chron, possibly around 1.3{+-}0.15 and 1.7{+-}0.3 Ma. The local igneous basement is composed of Late Miocene-Pliocene andesites, ignimbrites and volcano-sedimentary deposits. Normal polarities and a K-Ar date of 7.37{+-}0.73 Ma indicate that the volcanic activity in the study area extends beyond the Gauss chron. The polarity of some of the units in the post-caldera sequence and in the Concepcion de Ataco and Cuyanausul sequences suggest that they may have recorded short polarity sub-chrons. (Author)

  7. The Ahuachapan geothermal field, El Salvador: Reservoir analysis

    Energy Technology Data Exchange (ETDEWEB)

    Aunzo, Z.; Bodvarsson, G.S.; Laky, C.; Lippmann, M.J.; Steingrimsson, B.; Truesdell, A.H.; Witherspoon, P.A. (Lawrence Berkeley Lab., CA (USA); Icelandic National Energy Authority, Reykjavik (Iceland); Geological Survey, Menlo Park, CA (USA); Lawrence Berkeley Lab., CA (USA))


    The Earth Sciences Division of Lawrence Berkeley Laboratory (LBL) is conducting a reservoir evaluation study of the Ahuachapan geothermal field in El Salvador. This work is being performed in cooperation with the Comision Ejecutiva Hidroelectrica del Rio Lempa (CEL) and the Los Alamos National Laboratory (LANL). This report describes the work done during the first year of the study (FY 1988--89), and includes the (1) development of geological and conceptual models of the field, (2) evaluation of the initial thermodynamic and chemical conditions and their changes during exploitation, (3) evaluation of interference test data and the observed reservoir pressure decline, and (4) the development of a natural state model for the field. The geological model of the field indicates that there are seven (7) major and five (5) minor faults that control the fluid movement in the Ahuachapan area. Some of the faults act as a barrier to flow as indicated by large temperature declines towards the north and west. Other faults act as preferential pathways to flow. The Ahuachapan Andesites provide good horizontal permeability to flow and provide most of the fluids to the wells. The underlying Older Agglomerates also contribute to well production, but considerably less than the Andesites. 84 refs.

  8. Les grandes étapes d'évolution d'un volcan andésitique composite: Exemple du Nevado de Toluca (Méxique) (United States)

    Cantagrel, J. M.; Robin, C.; Vincent, P.


    The Nevado de Toluca, in the middle of the Mexican volcanic belt, has been built by two very dissimilar phases. The first one that lasted more than one million years is mainly andesitic. Numerous massive and autobrecciated lava flows of this phase pass outwards into thick conglomeratic formations. The volume of this primitive volcano represents the essential part of the Nevado. After an intense periode of erosion, the second phase is of very short duration (about 100.000 years) and is dacitic in nature. Three main episode can be distinguished: 1. Eruption of important ash and pumice pyroclastic flows related to caldera collapse above a shallow magmatic reservoir. 2. Extrusions of several dacitic domes within and outside the caldera with numerous associated «nuées ardentes» surrounding the volcano. 3. Plinian eruption leading to widespread pumiceous air-fall and to the opening of the present crater inside the caldera. Extrusion of a new small dacitic dome and late phreatic explosions. This second sequence of events can be interpreted as the progressive emptying of the crustal magmatic chamber without refilling by a new magma supply. The most recent activity in the area is represented by monogenic cones and flows of basic andesites outside the central vent system of the Nevado.

  9. Thermophysical properties of the Lipari lavas (Southern Tyrrhenian Sea

    Directory of Open Access Journals (Sweden)

    D. Russo


    Full Text Available Results of thermophysical investigations into the lavas of the island of Lipari (Southern Tyrrhenian Sea are presented. Samples selected for laboratory measurements belong to four main magmatic cycles, which produced basaltic-andesitic, andesitic and rhyolitic lavas. The wet-bulk density and the thermal conductivity measured on 69 specimens range from 1900 to 2760 kg m-3 and from 1.02 to 2.88 W m-1 K-1, respectively. Porosity is never negligible and its influence on density is maximum in rhyolites of the third cycle. The thermal conductivity is also influenced by the amount of glass. Rhyolitic obsidians show values lower than other rhyolites, although the latter rocks have a larger average porosity. The radioactive heat production determined on 36 specimens varies with the rock type, depending on the amount of U, Th and K. In basic lavas of the first cycle its value is 0.95°± 0.30 mW m-3, while in rhyolites of the fourth cycle it attains 6.68°±0.61 mW m-3. A comparison between results of g-ray spectrometry and X-ray fluorescence points out that the assumption of equilibrium in the decay series of the isotopic elements seems fulfilled. The information obtained is useful not only for the interpretation of geophysical surveys but also for the understanding of the geochemical characteristics of lavas.

  10. Multivariate Analysis, Mass Balance Techniques, and Statistical Tests as Tools in Igneous Petrology: Application to the Sierra de las Cruces Volcanic Range (Mexican Volcanic Belt) (United States)

    Velasco-Tapia, Fernando


    Magmatic processes have usually been identified and evaluated using qualitative or semiquantitative geochemical or isotopic tools based on a restricted number of variables. However, a more complete and quantitative view could be reached applying multivariate analysis, mass balance techniques, and statistical tests. As an example, in this work a statistical and quantitative scheme is applied to analyze the geochemical features for the Sierra de las Cruces (SC) volcanic range (Mexican Volcanic Belt). In this locality, the volcanic activity (3.7 to 0.5 Ma) was dominantly dacitic, but the presence of spheroidal andesitic enclaves and/or diverse disequilibrium features in majority of lavas confirms the operation of magma mixing/mingling. New discriminant-function-based multidimensional diagrams were used to discriminate tectonic setting. Statistical tests of discordancy and significance were applied to evaluate the influence of the subducting Cocos plate, which seems to be rather negligible for the SC magmas in relation to several major and trace elements. A cluster analysis following Ward's linkage rule was carried out to classify the SC volcanic rocks geochemical groups. Finally, two mass-balance schemes were applied for the quantitative evaluation of the proportion of the end-member components (dacitic and andesitic magmas) in the comingled lavas (binary mixtures). PMID:24737994

  11. Derivation of intermediate to silicic magma from the basalt analyzed at the Vega 2 landing site, Venus. (United States)

    Shellnutt, J Gregory


    Geochemical modeling using the basalt composition analyzed at the Vega 2 landing site indicates that intermediate to silicic liquids can be generated by fractional crystallization and equilibrium partial melting. Fractional crystallization modeling using variable pressures (0.01 GPa to 0.5 GPa) and relative oxidation states (FMQ 0 and FMQ -1) of either a wet (H2O = 0.5 wt%) or dry (H2O = 0 wt%) parental magma can yield silicic (SiO2 > 60 wt%) compositions that are similar to terrestrial ferroan rhyolite. Hydrous (H2O = 0.5 wt%) partial melting can yield intermediate (trachyandesite to andesite) to silicic (trachydacite) compositions at all pressures but requires relatively high temperatures (≥ 950°C) to generate the initial melt at intermediate to low pressure whereas at high pressure (0.5 GPa) the first melts will be generated at much lower temperatures (< 800°C). Anhydrous partial melt modeling yielded mafic (basaltic andesite) and alkaline compositions (trachybasalt) but the temperature required to produce the first liquid is very high (≥ 1130°C). Consequently, anhydrous partial melting is an unlikely process to generate derivative liquids. The modeling results indicate that, under certain conditions, the Vega 2 composition can generate silicic liquids that produce granitic and rhyolitic rocks. The implication is that silicic igneous rocks may form a small but important component of the northeast Aphrodite Terra.

  12. Mineral Chemistry and Geochemistry of Volcanic Rocks in The North of Pasinler (Erzurum

    Directory of Open Access Journals (Sweden)

    Oktay KILIÇ


    Full Text Available In the north of Pasinler (Erzurum, Upper Miocene-Pliocene volcanic rocks crop out. These volcanites are composed of basaltic andesite, andesite, dacite, rhyolite lavas and rhyolitic pyroclastics. The rocks show porphyritic, microlitic porphyritic, hyalo-microlitic porphyritic, vitrophyric, glomeroporphyritic, pilotaxitic and hyalopilitic textures. The investigated volcanites contain plagioclase (An29-80, olivine (Fo65-82, clinopyroxene (augite, orthopyroxene (enstatite, amphibole (Mg#: 0.57-0.71, biotite (phlogopite: 0.44-0.47, annite: 0.33-0.37, sanidine, quartz and opaque mineral (titano-magnetite and ilmenite. The volcanic rocks are calc-alkaline in character and have medium to high-K contents. Major oxide and trace element variations point out open-system magmatic differentiation in the evolution of rocks. Geochemical data indicate an important role of fractionation of phenocryst phases in the rocks during differentiation process. However, it is considered that assimilation±magma mixing might have accompanied to the process. High LILE (K, Rb, Ba, Th and relatively low HFSE (Nb, Ta, Hf, Zr contents of the rocks indicate that these rocks derived from parental magmas carrying subduction signature.

  13. U-Pb and K-Ar geochronology from the Cerro Empexa Formation, 1st and 2nd Regions, Precordillera, northern Chile

    International Nuclear Information System (INIS)

    Tomlinson, A.J; Martin, M.W; Blanco, N.; Perez de Arce, C


    The Cerro Empexa Formation (Galli, 1957) is a regionally distributed andesitic volcanic and continental sedimentary unit exposed in the Precordillera of the 1st and 2nd Regions of northern Chile. The formation has generally been considered to lie within the Lower or 'mid' Cretaceous, however, this assignment is based on scant, unreliable geochronologic data. Furthermore, there are conflicting interpretations as to whether the unit predates or postdates the first major Mesozoic shortening event affecting northern Chile. Because of the formation's presumed mid-Cretaceous age and its stratigraphic position over older back-arc sedimentary successions, the unit has been interpreted to represent products of the first eastward jump in the Andean magmatic arc from the arc's initial position in the Cordillera de la Costa (Scheuber and Reutter, 1992). In this paper we present the results of mapping and field observations that indicate exposures previously assigned to the Cerro Empexa Formation include two andesitic volcanic units separated by a major unconformity. The Cerro Empexa Formation proper lies above this unconformity. We also present U-Pb zircon and K-Ar geochronology that indicate the Cerro Empexa Formation is latest Cretaceous in its lower levels, and integrate our data with previously reported 40 Ar/ 39 Ar and fission-track data in the Cerros de Montecristo area (Maksaev, 1990; Maksaev and Zentilli, 1999) to show that 1800±600 m of rocks were deposited within ca. 2.5 m.y (au)

  14. Comparative features of volcanoes on Solar system bodies (United States)

    Vidmachenko, A. P.


    The bark of many cosmic bodies is in motion because of the displacement of tectonic plates on magma. Pouring molten magma through cracks in the cortex is called a volcanic eruption. There are two main types of volcanoes: basaltic, appearing where a new material of tectonic plates is formed, and andesitic, which located in the places of destruction of these plates.The third type of volcanoes is cryovolcanoes, or ice volcanoes. This type of volcano ejects matter in the form of ice volcanic melts or steam from water, ammonia, methane. After the eruption, the cryomagma at a low temperature condenses to a solid phase. Cryovolcanoes can be formed on such objects as Pluto, Ceres, Titan, Enceladus, Europe, Triton, etc. Potential sources of energy for melting ice in the production of cryovolcanoes are tidal friction and/or radioactive decay. Semi-transparent deposits of frozen materials that can create a subsurface greenhouse effect, with the possibility of accumulating the required heat with subsequent explosive eruption, are another way to start the cryovolcano action. This type of eruption is observed on Mars and Triton. The first and second types of eruptions (basaltic and andesitic) are characteristic of terrestrial planets (Mercury, Venus, Mars) and for some satellites of the planets of the Solar system.

  15. Sr isotope geochemistry of voluminous acidic pyroclastics erupted at 1-3 Ma in Northeast Japan

    International Nuclear Information System (INIS)

    Shirahase, Teruo; Tamanyu, Shiro; Togashi, Shigeko


    Sr isotope ratios are analyzed for voluminous acidic pyroclastics erupted at 1 - 3 Ma in five areas on the volcanic front of Northeast Japan. The initial values of 87 Sr/ 86 Sr ratios range from 0.7040 to 0.7055. There is no significant difference in ratios between 1 - 3 Ma acidic pyroclastics and 0 - 1 Ma andesitic volcanics in each area in spite of differences in age and in mean SiO 2 content. On the other hand, the ratios in both of 1 - 3 Ma and 0 - 1 Ma volcanics vary along arc in the same manner. The changes of Sr and Rb contents in each area are consistent with systematic changes by fractional crystallization. The low 87 Sr/ 86 Sr ratios and chemistry suggest that 1 - 3 Ma acidic pyroclastics of Northeast Japan formed by a high degree of fractional crystallization from basic magma which is common in genesis with young andesitic volcanism. The mechanisms of the formation of the basic magma and the character of mantle source in each area have not changed for the past 3 Ma. Degrees of fractional crystallization changed with changes of the tectonic condition of shallow magma chamber from a weak horizontal compression stress field to a strong one. (author)

  16. Paleomagnetic investigations at Mahd adh Dhahab, Kingdom of Saudi Arabia (United States)

    Gettings, M.E.


    Paleomagnetic studies of 25 oriented bedrock specimens from Jabal Mahd adh Dhahab, located 160 km southeast of Al Madinah, Kingdom of Saudi Arabia, have yielded important structural information relating to the geologic history of this base and precious metal deposit. Samples were collected along one traverse away from the mineralized zones, across the northeast-plunging antiform that constitutes the dominant regional structure of the area, and along another traverse down the axis of the mineralized zones. Lithologies range from andesite flows through andesitic to rhyodacitic tuffs, lapilli tuffs, and volcaniclastic sediments. Measurements of remanent magnetization direction and intensity before and after stepwise alternating-field demagnetization ranging from 25 Oersted (Oe) to 1000 Oe were carried out on all samples. Three classes of demagnetization behavior were observed: A very stable class with little change in direction and intensity of magnetization; a class in which rapid changes were observed at first but which then settled on a high coercivity stable component of magnetization; and a class in which the magnetization was composed of a spectrum of low coervicity components, and continuous variation of direction and intensity of magnetization occurred.

  17. The Chahnaly low sulfidation epithermal gold deposit, western Makran volcanic arc, southeastern Iran (United States)

    Sholeh, Ali; Rastad, Ebrahim; Huston, David L.; Gemmell, J. Bruce; Taylor, Ryan D.


    The Chahnaly low-sulfidation epithermal Au deposit and nearby Au prospects are located northwest of the intermittently active Bazman stratovolcano on the western end of the Makran volcanic arc, which formed as the result of subduction of the remnant Neo-Tethyan oceanic crust beneath the Lut block. The arc hosts the Siah Jangal epithermal and Kharestan porphyry prospects, near Taftan volcano, as well as the Saindak Cu-Au porphyry deposit and world-class Reko Diq Cu-Au porphyry deposit, near Koh-i-Sultan volcano to the east-northeast in Pakistan. The host rocks for the Chahnaly deposit include early Miocene andesite and andesitic volcaniclastic rocks that are intruded by younger dacitic domes. Unaltered late Miocene dacitic ignimbrites overlie these rocks. Laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) U-Pb zircon geochronology data yield ages between 21.8 and 9.9 Ma for the acidic-intermediate regional volcanism. The most recent volcanic activity of the Bazman stratovolcano involved extrusion of an olivine basalt during Pliocene to Quaternary times. Interpretation of geochemical data indicate that the volcanic rocks are synsubduction and calc-alkaline to subalkaline. The lack of a significant negative Eu anomaly, a listric-shaped rare earth element pattern, and moderate La/Yb ratios of host suites indicate a high water content of the source magma.

  18. CO2 bubble generation and migration during magma-carbonate interaction (United States)

    Blythe, L. S.; Deegan, F. M.; Freda, C.; Jolis, E. M.; Masotta, M.; Misiti, V.; Taddeucci, J.; Troll, V. R.


    We conducted quantitative textural analysis of vesicles in high temperature and pressure carbonate assimilation experiments (1200 °C, 0.5 GPa) to investigate CO2 generation and subsequent bubble migration from carbonate into magma. We employed Mt. Merapi (Indonesia) and Mt. Vesuvius (Italy) compositions as magmatic starting materials and present three experimental series using (1) a dry basaltic-andesite, (2) a hydrous basaltic-andesite (2 wt% H2O), and (3) a hydrous shoshonite (2 wt% H2O). The duration of the experiments was varied from 0 to 300 s, and carbonate assimilation produced a CO2-rich fluid and CaO-enriched melts in all cases. The rate of carbonate assimilation, however, changed as a function of melt viscosity, which affected the 2D vesicle number, vesicle volume, and vesicle size distribution within each experiment. Relatively low-viscosity melts (i.e. Vesuvius experiments) facilitated efficient removal of bubbles from the reaction site. This allowed carbonate assimilation to continue unhindered and large volumes of CO2 to be liberated, a scenario thought to fuel sustained CO2-driven eruptions at the surface. Conversely, at higher viscosity (i.e. Merapi experiments), bubble migration became progressively inhibited and bubble concentration at the reaction site caused localised volatile over-pressure that can eventually trigger short-lived explosive outbursts. Melt viscosity therefore exerts a fundamental control on carbonate assimilation rates and, by consequence, the style of CO2-fuelled eruptions.

  19. Multivariate Analysis, Mass Balance Techniques, and Statistical Tests as Tools in Igneous Petrology: Application to the Sierra de las Cruces Volcanic Range (Mexican Volcanic Belt

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    Fernando Velasco-Tapia


    Full Text Available Magmatic processes have usually been identified and evaluated using qualitative or semiquantitative geochemical or isotopic tools based on a restricted number of variables. However, a more complete and quantitative view could be reached applying multivariate analysis, mass balance techniques, and statistical tests. As an example, in this work a statistical and quantitative scheme is applied to analyze the geochemical features for the Sierra de las Cruces (SC volcanic range (Mexican Volcanic Belt. In this locality, the volcanic activity (3.7 to 0.5 Ma was dominantly dacitic, but the presence of spheroidal andesitic enclaves and/or diverse disequilibrium features in majority of lavas confirms the operation of magma mixing/mingling. New discriminant-function-based multidimensional diagrams were used to discriminate tectonic setting. Statistical tests of discordancy and significance were applied to evaluate the influence of the subducting Cocos plate, which seems to be rather negligible for the SC magmas in relation to several major and trace elements. A cluster analysis following Ward’s linkage rule was carried out to classify the SC volcanic rocks geochemical groups. Finally, two mass-balance schemes were applied for the quantitative evaluation of the proportion of the end-member components (dacitic and andesitic magmas in the comingled lavas (binary mixtures.

  20. Change with time in extrusion and chemical composition of volcanic rock in geothermal areas in central Kyushu

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    Kamata, Hiroki


    Changes with time in extrusion and chemical composition of volcanic rocks in central Kyushu are studied to provide basic data required for evaluation of geothermal resources. Distribution of volcanic rocks in successive 1Ma (10/sup 6/ year) periods and the average thickness of volcanic rock layers in each period are determined, from which the volume of volcanic rocks in each 1Ma period is calculated. Results indicate that volcanos in central Kyushu extruded about 3,000 km/sup 3//Ma of volcanic rocks during the early periods (about 5Ma), followed by a series of declining periods up to the present. Comparison of volcanic extrusive rocks of each 1Ma period shows that lava of hornblende andesite and pyroxenic andesite has been extruded in great quantities in every period. Chemical composition is studied based on diagrams showing changes in SiO/sub 2/ content. The K/sub 2/O content is relatively high in most volcanos younger than 1.6Ma, compared to those older than 1.6Ma. the K/sub 2/O content in extruded rocks has been high during the latest 0.4Ma in the Aso volcanic area, unlike other island arc conjunction areas. (4 figs, 5 tabs, 28 refs)

  1. The geology of Mount Taftan stratovolcano, southeast of Iran

    International Nuclear Information System (INIS)

    Biabangard, H.; Moradian, A.


    Mount Taftan is a double-peaked stratovolcano, located in southeast of Iran. This volcano constructed a number of calderas among which one of the most important is Anjerk. The magmas erupted from this multi-caldera complex range from andesi-basalt to dacite, but are dominated by andesite and dacite. Two terminal cones, Narkuh and Matherkuh, culminate at 4100 m and 3950 m, respectively. There are three evolutionary stages in the history of the volcanic complex (stage 1: Palaevolcanism, 6.95±0.72Ma, stage 2: Mesovolcanism, 6.01±0.15Ma and stage 3: Neo volcanism, 0.71± 0.03Ma). The eruptive products consist of lava flows, iguimbrites and pyroclastic rocks. The later include tuffs, nuees ardents, breccias and sometimes reworked as lahars. Textural and mineralogical data suggest that both magma mixing and fractional crystallization were involved in the generation of the andesites and dacites. The magmas erupted from this volcano show a calc-alkaline trend. The corresponding lavas are calk-alkaline with a potasic tendency.

  2. Expressway construction in landslide areas. ; Construction work between Fujioka interchange and Saku interchange of Joshin'etsu expressway. Ugoku yama wo tsuranuku. ; Joshin'etsu Jidoshado Fujioka IC/Saku IC kan kensetsu koji

    Energy Technology Data Exchange (ETDEWEB)

    Togo, Y [Japan Highway Public Corp., Tokyo (Japan)


    The Joshin'etsu motorway is a 204km expressway. Various technological studies have been made for the remediation work for the 69.5km section which is opened to traffic this spring, because not only a series of tunnels, bridges, long cut and fill soil particular to mountain roads are included but also the section has many landslide areas. The length of the Higureyama tunnel is 2,314m. Although strong andesite is prevailing as the nature of the soil, the central area of the tunnel is consisted of brittle mudstone and self-crushing andesite with faults because the tunnel runs through the lower portion of a landslide zone. The mudstone is a squeezing ground, and buckling of H supporting, breakage of lock bolts, and damage of sprayed concrete occurred in many places. 2 years and 10 months are required for the construction of the tunnel. The average monthly drilling is only 10m/month which is an unprecedented case in tunnel excavation. Even limited to large-scale landslides, 13 occurrences are experienced. 10 figs., 1 tab.

  3. Precursory activity of the 161 ka Kos Plateau Tuff eruption, Aegean Sea (Greece) (United States)

    Piper, David J. W.; Pe-Piper, Georgia; Lefort, Darren


    The Kos Plateau Tuff (KPT) eruption of 161 ka was the largest explosive Quaternary eruption in the eastern Mediterranean. We have discovered an uplifted beach deposit of abraded pumice cobbles, directly overlain by the KPT. The pumice cobbles resemble pumice from the KPT in petrography and composition and differ from Plio-Pleistocene rhyolites on the nearby Kefalos Peninsula. The pumice contains enclaves of basaltic andesite showing chilled lobate margins, suggesting co-existence of two magmas. The deposit provides evidence that the precursory phase of the KPT eruption produced pumice rafts, and defines the paleoshoreline for the KPT, which elsewhere was deposited on land. The beach deposit has been uplifted about 120 m since the KPT eruption, whereas the present marine area south of Kos has subsided several hundred metres, as a result of regional neotectonics. The basaltic andesite is more primitive than other mafic rocks known from the Kos-Nisyros volcanic centre and contains phenocrysts of Fo89 olivine, bytownite, enstatite and diopside. Groundmass amphibole suggests availability of water in the final stages of magma evolution. Geochemical and mineralogical variation in the mafic products of the KPT eruption indicate that fractionation of basaltic magma in a base-of-crust magma chamber was followed by mixing with rhyolitic magma during eruption. Low eruption rates during the precursory activity may have minimised the extent of mixing and preserved the end-member magma types.

  4. Characterization and zircon SHRIMP U-Pb geochronology of the subvolcanic rocks from Yarumalito Porphyry System, Marmato District, Colombia; Caracterizacao e geocronologia SHRIMP U-Pb em zircao das rochas subvulcanicas do sistema porfiro Yarumalito, Distrito de Marmato, Colombia

    Energy Technology Data Exchange (ETDEWEB)

    Henrichs, Isadora A.; Frantz, Jose Carlos; Marques, Juliana C.; Castoldi, Marco S., E-mail:, E-mail:, E-mail: [Universidade Federal do Rio Grande do Sul (UFRS), Porto Alegre, RS (Brazil). Instituto de Geociencias; Ordonez-Carmona, Oswaldo, E-mail: [Universidad Nacional de Colombia, Medellin (Colombia). Facultad de Minas; Sato, Kei, E-mail: [Universidade de Sao Paulo (USP), Sao Paulo, SP (Brazil). Centro de Pesquisas Geocronologicas


    The mining District of Marmato, located in the Central Cordillera, is considered one of the oldest gold districts in Colombia and its exploration dates back to the Inca’s times, being exploited regularly for more than a thousand years. Inserted in this context lies the Yarumalito porphyry system (YPS), characterized to concentrate ore in structure related veins and stockworks. The YPS is related to the Miocene magmatism of the Combia Formation. In this paper, the subvolcanic rocks directly associated with the mineralized zones were described in order to obtain U-Pb ages in zircon to the intrusions. Selected samples from two fertile intrusions, one andesitic (more abundant in the area) and other dioritic (more restricted), were carefully described and dated by SHRIMP. The results points to a very restricted interval for the ages, with weighted average {sup 206}Pb/{sup 238}U varying from 7,00 ± 0,15 Ma for the andesitic porphyry and 6.95 ± 0.16 Ma for the dioritic porphyry. These results constrain the Yarumalito system to the final stages of the Combia magmatism and suggest a brief period for the crystallization of the mineralized subvolcanic rocks in the area and in the Marmato District. (author)

  5. Remote sensing data of SP Mountain and SP Lava flow in North-Central Arizona (United States)

    Schaber, G.G.; Elachi, C.; Farr, T.G.


    Multifrequency airborne radar image data of SP Mountain [Official name of feature (U.S. Geological Survey, 1970)] and SP flow (and vicinity) in north-central Arizona were obtained in diverse viewing directions and direct and cross-polarization, then compared with surface and aerial photography, LANDSAT multispectral scanner data, airborne thermal infrared imagery, surface geology, and surface roughness statistics. The extremely blocky, basaltic andesite of SP flow is significantly brighter on direct-polarization K-band (0.9-cm wavelength) images than on cross-polarized images taken simultaneously. Conversely, for the longer wavelength (25 cm) L-band radar images, the cross-polarization image returns from SP flow are brighter than the direct-polarized image. This effect is explained by multiple scattering and the strong wavelength dependence of polarization effects caused by the rectilinear basaltic andesite scatters. Two distinct types of surface relief on SP flow, one extremely blocky, the other subdued, are found to be clearly discriminated on the visible and thermal wavelength images but are separable only on the longer wavelength L-band radar image data. The inability of the K- and X- (3-cm wavelength) band radars to portray the differences in roughness between the two SP flow surface units is attributed to the radar frequency dependence of the surface-relief scale, which, described as the Rayleigh criterion, represents the transition between quasispecular and primarily diffuse backscatter. ?? 1980.

  6. 40Ar/39Ar geochronology and geochemical reconnaissance of the Eocene Lowland Creek volcanic field, west-central Montana (United States)

    Dudas, F.O.; Ispolatov, V.O.; Harlan, S.S.; Snee, L.W.


    We report geochronological and geochemical data for the calc-alkalic Lowland Creek volcanic field (LCVF) in westcentral Montana. 40Ar/ 39Ar age determinations show that the LCVF was active from 52.9 to 48.6 Ma, with tuff-forming eruptions at 52.9 ?? 0.14 and 51.8 ?? 0.14 Ma. These dates span the age range of vigorous Eocene igneous activity in the Kamloops-Absaroka-Challis belt. The LCVF evolved upward from basal rhyolites (SiO 2>71 wt%) to dacites and andesites (SiO 2 > 62 wt%). Compositional change parallels a transition from early explosive volcanism to late effusive activity. Four geochemical components can be detected in the rocks. A component with 206Pb/204Pb 18.3 and epsilon;Nd>-9 contain a third component; and an andesite with low Nd content and epsilon;Nd near-9 probably contains a fourth component. The first three components probably derive from the lower and middle crust, whereas the fourth is probably from the lithospheric mantle. ?? 2010 by The University of Chicago.

  7. Black dimensional stones: Geology, technical properties and deposit characterization of the dolerites from Uruguay (United States)

    Morales Demarco, M.; Oyhantçabal, P.; Stein, K.-J.; Siegesmund, S.


    Dimensional stones with a black color occupy a prominent place on the international market. Uruguayan dolerite dikes of andesitic and andesitic-basaltic composition are mined for commercial blocks of black dimensional stones. A total of 16 dikes of both compositions were studied and samples collected for geochemical and petrographical analysis. Color measurements were performed on different black dimensional stones in order to compare them with the Uruguayan dolerites. Samples of the two commercial varieties (Absolute Black and Moderate Black) were obtained for petrophysical analysis (e.g. density, porosity, uniaxial compressive strength, tensile strength, etc.). Detailed structural analyses were performed in several quarries. Geochemistry and petrography determines the intensity of the black color. When compared with commercial samples from China, Brazil, India and South Africa, among others, the Uruguayan dolerite Absolute Black is the darkest black dimensional stone analyzed. In addition, the petrophysical properties of the Uruguayan dolerites make them one of the highest quality black dimensional stones. Structural analyses show that five joint sets have been recognized: two sub-vertical joints, one horizontal and two diagonal. These joint sets are one of the most important factors that control the deposits, since they control the block size distribution and the amount of waste material.

  8. Timing the evolution of a monogenetic volcanic field: Sierra Chichinautzin, Central Mexico (United States)

    Jaimes-Viera, M. C.; Martin Del Pozzo, A. L.; Layer, P. W.; Benowitz, J. A.; Nieto-Torres, A.


    The unique nature of monogenetic volcanism has always raised questions about its origin, longevity and spatial distribution. Detailed temporal and spatial boundaries resulted from a morphometric study, mapping, relative dating, twenty-four new 40Ar/39Ar dates, and chemical analyses for the Sierra Chichinautzin, Central Mexico. Based on these results the monogenetic cones were divided into four groups: (1) Peñón Monogenetic Volcanic Group (PMVG); (2) Older Chichinautzin Monogenetic Volcanic Group (Older CMVG); (3) Younger Chichinautzin Monogenetic Volcanic Group (Younger CMVG) and (4) Sierra Santa Catarina Monogenetic Volcanic Group (SSC). The PMVG cover the largest area and marks the northern and southern boundaries of this field. The oldest monogenetic volcanism (PMVG; 1294 ± 36 to 765 ± 30 ka) started in the northern part of the area and the last eruption of this group occurred in the south. These basaltic-andesite cones are widely spaced and are aligned NE-SW (N60°E). After this activity, monogenetic volcanism stopped for 527 ka. Monogenetic volcanism was reactivated with the birth of the Tezoyuca 1 Volcano, marking the beginning of the second volcanic group (Older CMVG; 238 ± 51 to 95 ± 12 ka) in the southern part of the area. These andesitic to basaltic andesite cones plot into two groups, one with high MgO and Nb, and the other with low MgO and Nb, suggesting diverse magma sources. The eruption of the Older CMVG ended with the eruption of Malacatepec volcano and then monogenetic volcanism stopped again for 60 ka. At 35 ka, monogenetic volcanism started again, this time in the eastern part of the area, close to Popocatépetl volcano, forming the Younger CMVG (<35 ± 4 ka). These cones are aligned in an E-W direction. Geochemical composition of eruptive products of measured samples varies from basalts to dacites with low and high MgO. The Younger CMVG is considered still active since the last eruptions took place <2 ka. The SSC (132 ± 70 to 2 ± 56 ka

  9. Suprasubduction volcanic rocks of the Char ophiolite belt, East Kazakhstan: new geochemical and first geochronological data (United States)

    Safonova, Inna; Simonov, Vladimir; Seltmann, Reimar; Yamamoto, Shinji; Xiao, Wenjiao


    The Char ophiolite belt is located in the western Central Asian Orogenic Belt, a world largest accretionary orogen, which has evolved during more than 800 Ma. The Char belt formed during Kazakhstan - Siberia collision. It has been known for hosting fragments of Late Devonian-Early Carboniferous oceanic crust, MORB, OPB and OIB, of the Paleo-Asian Ocean (Safonova et al., 2012). The Char is surrounded by two Paleozoic island-arc terranes: Zharma-Saur in the west and Rudny Altai in the east, however, until recent times, no island-arc units have been found within it. We were the first to find island-arc units as tectonic sheets occurring adjacent to those consisting of oceanic rocks. In places, island-arc andesites cut oceanic basalts. The Char volcanic and subvolcanic rocks of a probable suprasubduction origin are basalt, microgabbro, dolerite, andesite, tonalite and dacite. The mafic to andesitic volcanics possessing low TiO2 (0.85 wt.%av.) and show MgO vs. major elements crystallization trends suggesting two magma series: tholeiitic and calc-alkaline. The tholeiitic varieties are less enriched in incompatible elements then the calc-alkaline ones. Two samples are high-Mg and low-Ti andesibasalts similar to boninites. The rocks possess moderately LREE enriched rare-earth element patterns and are characterized by negative Nb anomalies present on the multi-element spectra (Nb/Lapm = 0.14-0.47; Nb/Thpm = 0.7-1.6).The distribution of rare-earth elements (La/Smn = 0.8-2.3, Gd/Ybn = 0.7-1.9) and the results of geochemical modeling in the Nb-Yb system suggest high degrees of melting of a depleted harzburgite-bearing mantle source at spinel facies depths. Fractional crystallization of clinopyroxene, plagioclase and opaque minerals also affected the final composition of the volcanic rocks. Clinopyroxene monomineral thermometry indicates crystallization of melts at 1020-1180°C. Melt inclusion composition based numerical calculations show that primary melts were derived at 1350

  10. Postglacial eruptive history and geochemistry of Semisopochnoi volcano, western Aleutian Islands, Alaska (United States)

    Coombs, Michelle L.; Larsen, Jessica F.; Neal, Christina A.


    Semisopochnoi Island, located in the Rat Islands group of the western Aleutian Islands and Aleutian volcanic arc, is a roughly circular island composed of scattered volcanic vents, the prominent caldera of Semisopochnoi volcano, and older, ancestral volcanic rocks. The oldest rocks on the island are gently radially dipping lavas that are the remnants of a shield volcano and of Ragged Top, which is an eroded stratocone southeast of the current caldera. None of these oldest rocks have been dated, but they all are likely Pleistocene in age. Anvil Peak, to the caldera’s north, has the morphology of a young stratocone and is latest Pleistocene to early Holocene in age. The oldest recognized Holocene deposits are those of the caldera-forming eruption, which produced the 7- by 6-km caldera in the center of the island, left nonwelded ignimbrite in valleys below the edifice, and left welded ignimbrite high on its flanks. The caldera-forming eruption produced rocks showing a range of intermediate whole-rock compositions throughout the eruption sequence, although a majority of clasts analyzed form a fairly tight cluster on SiO2-variation diagrams at 62.9 to 63.4 weight percent SiO2. This clustering of compositions at about 63 weight percent SiO2 includes black, dense, obsidian-like clasts, as well as tan, variably oxidized, highly inflated pumice clasts. The best estimate for the timing of the eruption is from a soil dated at 6,920±60 14C years before present underlying a thin facies of the ignimbrite deposit on the island’s north coast. Shortly after the caldera-forming eruption, two scoria cones on the northwest flank of the volcano outside the caldera, Ringworm crater and Threequarter Cone, simultaneously erupted small volumes of andesite.The oldest intracaldera lavas, on the floor of the caldera, are andesitic to dacitic, but are mostly covered by younger lavas and tephras. These intracaldera lavas include the basaltic andesites of small Windy cone, as well as the

  11. Petrography, geochemistry and tectonic setting of Salmabad Tertiary volcanic rocks, southeast of Sarbisheh, eastern Iran

    Directory of Open Access Journals (Sweden)

    Masoumeh Goodarzi


    Full Text Available Introduction The area reviewed and studied in this paper is located 5 km southeast of Sarbisheh city at eastern border of the Lut block (Jung et al., 1983; Karimpour et al., 2011; Richards et al., 2012 in eastern Iran between 59° 47′ and 59° 53′ E longitude and 32°30′ and 32°34′ N latitude. The magmatic activity in the Lut block began in middle Jurassic (165-162 Ma and reached its peak in Tertiary (Jung et al., 1983. Volcanic and subvolcanic rocks of Tertiary age cover over half of Lut block with up to 2000 m thickness and formed due to subduction prior to the collision of the Arabian and Asian plates (Camp and Griffis, 1982; Tirrul et al., 1983; Berberianet et al., 1982. Most of magmatic activity in the Lut block formed in middle Eocene (Karimpour et al., 2011 The andesitic volcanics were erupted together with the dacites and rhyodacites during a time interval of some 50 Ma from early Cretaceous to early Neogene. It can be assumed that the intensity of the volcanic activity was varying significantly during this time span (Jung et al., 1983.Tertiary volcanic rocks (Eocene-Oligocene to Pliocene with intermediate composition associated with pyroclastic rocks cropped out in eastern parts of Salmabad village, southeast of Sarbisheh. The main purpose of this paper is better understand the tectono-magmatic setting of the Tertiary volcanic rocks in southeast of Sarbisheh, eastern Iran based on geochemical characteristics. Materials and methods Eleven samples were analyzed for major elements by inductively coupled plasma (ICP technologies and trace elements were analyzed using inductively coupled plasma mass spectrometry (ICP-MS, following a lithium metaborate/tetraborate fusion and nitric acid total digestion, at the SGS Laboratories, Toronto, Canada. Results In the Salmabad area, Tertiary volcanic rocks with mainly intermediate (andesitic composition are exposed associated with pyroclastic deposits such as tuff, breccia and agglomerate

  12. Detection of morphological changes in cliff face surrounding a waterfall using terrestrial laser scanning and unmanned aerial system (United States)

    Hayakawa, Yuichi S.; Obanawa, Hiroyuki


    Waterfall or bedrock knickpoint appears as an erosional front in bedrock rivers forming deep v-shaped valley downstream. Following the rapid fluvial erosion of waterfall, rockfalls and gravita-tional collapses often occur in surrounding steep cliffs. Although morphological changes of such steep cliffs are sometimes visually observed, quantitative and precise measurements of their spatio-temporal distribution have been limited due to the difficulties in direct access to such cliffs if with classical measurement methods. However, for the clarification of geomorphological processes oc-curring in the cliffs, multi-temporal mapping of the cliff face at a high resolution is necessary. Re-mote sensing approaches are therefore suitable for the topographic measurements and detection of changes in such inaccessible cliffs. To achieve accurate topographic mapping of cliffs around a wa-terfall, here we perform multi-temporal terrestrial laser scanning (TLS), as well as structure-from-motion multi-view stereo (SfM-MVS) photogrammetry based on unmanned aerial system (UAS). The study site is Kegon Falls in central Japan, having a vertical drop of surface water from top of its overhanging cliff, as well as groundwater outflows from its lower portions. The bedrock is composed of alternate layers of andesite lava and conglomerates. Minor rockfalls in the cliffs are often ob-served by local people. The latest major rockfall occurred in 1986, causing ca. 8-m upstream propa-gation of the waterfall lip. This provides a good opportunity to examine the changes in the surround-ing cliffs following the waterfall recession. Multi-time point clouds were obtained by TLS measure-ment over years, and the three-dimensional changes of the rock surface were detected, uncovering the locus of small rockfalls and gully developments. Erosion seems particularly frequent in relatively weak the conglomerates layer, whereas small rockfalls seems to have occurred in the andesite layers. Also, shadows in the

  13. Frictional property of rocks in the Izu-Bonin-Mariana Forearc under high temperature and pressure conditions (United States)

    Hyodo, G.; Takahashi, M.; Saito, S.; Hirose, T.


    The Kanto region in central Japan lies atop of three tectonic plates: the North American Plate, the Pacific Plate, and the Philippine Sea Plate. The collision and subduction of the Izu-Bonin-Mariana (IBM) arc on the Philippine Sea Plate into the Kanto region results in occurring the different type of earthquakes, including seismic slip (e.g., the Kanto earthquake) and aseismic creep (i.e., slow earthquakes around the Boso peninsula). The seismic and aseismic slip seems to generate side by side at almost same depth (probably nearly same P-T conditions). This study focus on frictional property of incoming materials to be subducted into the Kanto region, in order to examine a hypothesis that the different types of slips arise from different input materials. Thus, we have performed friction experiments on rocks that constitute the IBM forearc using a high P-T gas medium apparatus at AIST. We sampled five rocks (marl, boninite, andesite, sheared serpentinite and serpentinized dunite) recovered from the IBM forearc by Leg 125, Ocean Drilling Program (ODP Site 784, 786). The rocks were crushed and sieved into 10˜50 µm in grain size. Experiments were conducted at temperature of 300○C, confining pressure of 156 MPa, pore pressure of 60 MPa and axial displacement rates of 0.1 and 1 µm/s. For marl, andesite and boninite, a periodic stick-slip behavior appears at 1 µm/s. Rise time of the stick-slip behaviors are quite long (3.1, 9.9 and 14.2 sec, for marl, andesite and boninite, respectively). We called such events as a "slow stick-slip". Similar slow stick-slip behaviors were observed in previous studies (Noda and Shimamoto, 2010; Okazaki, 2013; Kaproth and Marone, 2013), but this is first time to recognize this characteristic slip behavior in sedimentary and igneous rocks. Although it is difficult to discuss the diverse slip behaviors observed at the Kanto region based on our limited experimental results, we will examine the conditions where the transition between

  14. Flank Collapse Assessment At Kick-'em-Jenny Submarine Volcano (Lesser Antilles): A Combined Approach Using Modelling and Experiments (United States)

    Dondin, F. J. Y.; Heap, M. J.; Robertson, R. E. A.; Dorville, J. F. M.; Carey, S.


    In the Lesser Antilles over 52 volcanic landslide episodes have been identified. These episodes serve as a testament to the hazard posed by volcanic landslides to a region composed of many islands that are small independent countries with vulnerable local economies. This study presents a relative slope stability analysis (RIA) to investigate the stability condition of the only active submarine volcano of the Lesser Antilles Arc: Kick-'em-Jenny Submarine Volcano (KeJ). Thus we hope to provide better constraint on the landslide source geometry to help mitigate volcanic landslide hazards at a KeJ. KeJ is located ca. 8 km north of Grenada island. KeJ lies within a collapse scar from a prehistorical flank collapse. This collapse was associated with a voluminous landslide deposit of about 4.4km3 with a 14 km runout. Numerial simulations showed that this event could generate a regional tsunami. We aim to quantify potential initial volumes of collapsed material using a RIA. The RIA evaluates the critical potential failure surface associated with factor of safety (Fs) inferior to unity and compares them to areas of deficit/surplus of mass/volume obtained from the comparison of an high resolution digital elevation model of the edifice with an ideal 3D surface. We use freeware programs VolcanoFit 2.0 and SSAP 4.7. and produce a 3D representation of the stability map. We report, for the first time, results of a Limit Equilibrium Method performed using geomechanical parameters retrieved from rock mechanics tests performed on two rock basaltic-andesite rock samples collected from within the crater of the volcano during the 1-18 November 2013 NA039 E/V Nautilus cruise. We performed triaxial and uniaxial deformation tests to obtain values of strength at the top and bottom of the edifice. We further characterized the permeability and P-wave velocity of the samples collected. The chosen internal structure for the model is composed of three bodies: (i) a body composed of basaltic-andesite

  15. Deposits, petrology and mechanism of the 2010-2013 eruption of Kizimen volcano in Kamchatka, Russia (United States)

    Auer, A.; Belousov, A.; Belousova, M.


    Kizimen volcano in Kamchatka is well known as a source of highly heterogeneous poorly mingled magmas ranging from dacites to basaltic andesites. In 2010-2013, the volcano produced its first historical magmatic eruption with the deposition of 0.27 km3 of block and ash pyroclastic flows accompanied by slow extrusion of a 200-m-thick, highly viscous (1010-1011 Pa s) block lava flow with a volume of 0.3 km3. The total volume of erupted magma comprised approximately 0.4 km3 DRE. We provide description of the eruption chronology, as well as the lithology and petrology of eruptive products. The erupted material is represented by banded dacite and high-silica andesite. The dacitic magma was formed during a long dormancy after the previous magmatic eruption several hundred years ago with mineral compositions indicating average pre-eruptive temperatures of 810 °C, fO2 of 0.9-1.6 log units above the nickel-nickel oxide (NNO) buffer and shallow crustal storage conditions at 123 MPa. The silica-rich andesite represents a hybrid magma, which shows signs of recent thermal and compositional disequilibrium. We suggest that the hybrid magma started to form in 1963 when a swarm of deep earthquakes indicated an input of mafic magma from depth into the 6-11-km-deep silicic magma chamber. It took the following 46 years until the magma filling the chamber reached an eruptible state. Poor mingling of the two melts is attributed to its unusually high viscosity that could be associated with the pre-eruptive long-term leakage of volatiles from the chamber through a regional tectonic fault. Our investigations have shown that shallow magma chambers of dormant volcanoes demonstrating strong persistent fumarolic activity can contain highly viscous, degassed magma of evolved composition. Reactivation of such magma chambers by injection of basic magma takes a long time (several decades). Thus, eruption forecasts at such volcanoes should include a possibility of long time lag between a swarm of

  16. Petrologic evolution of Miocene-Pliocene mafic volcanism in the Kangal and Gürün basins (Sivas-Malatya), central east Anatolia: Evidence for Miocene anorogenic magmas contaminated by continental crust (United States)

    Kocaarslan, Ayça; Ersoy, E. Yalçın


    This study discusses the geochemical features of the Early-Middle Miocene and Pliocene basaltic (SiO2 = 46-52; MgO = 6-10 wt%) to andesitic (SiO2 = 59; MgO = 4 wt%) rocks exposed in the Gürün and Kangal basins (Sivas, eastern part of central Anatolia), respectively. The basaltic rocks are characterized by alkaline to tholeiitic affinities, while the more evolved andesitic samples show calc-alkaline affinity. Trace element variations reveal that they can be evaluated in three sub-groups, each represented by different contents of trace elements for given Nb contents. Primary magmas of each groups were likely produced by different degrees of partial melting ( 1-2, 2-3, 7-10% respectively) from a common mantle source, subsequently underwent different degrees of fractionation and crustal contamination. Derivation from a common mantle source of the primitive magmas of each group is supported by similar Sr, Nd and Pb isotopic ratios. Increasing degrees of partial melting seem to be responsible for the alkaline to tholeiitic variation among the basaltic samples, while higher degrees of crustal contamination (AFC) resulted in calc-alkaline affinity of the more evolved samples. Most primitive Pliocene samples show intra-plate (anorogenic) geochemical features, while the more evolved Miocene calc-alkaline samples resemble geochemically subduction-related (orogenic) magmatic rocks. However, on the basis of detailed geochemical models, we propose that the calc-alkaline affinity among the Miocene samples can also be gained by crustal contamination of their primary magmas which were also anorogenic in character. If this is true, overall, the Miocene and Pliocene basaltic to andesitic rocks in the Gürün and Kangal basins appear to may have formed by variable degrees of partial melting of a common anorogenic mantle that had not been subject to subduction-related metasomatism. This is an alternative approach to the general view assuming the Early-Middle Miocene magmatic activity

  17. Sedimentology and geochemistry of surface sediments, outer continental shelf, southern Bering Sea (United States)

    Gardner, J.V.; Dean, W.E.; Vallier, T.L.


    Present-day sediment dynamics, combined with lowerings of sea level during the Pleistocene, have created a mixture of sediments on the outer continental shelf of the southern Bering Sea that was derived from the Alaskan Mainland, the Aleutian Islands, and the Pribilof ridge. Concentrations of finer-grained, higher-organic sediments in the region of the St. George basin have further modified regional distribution patterns of sediment composition. Q-mode factor analysis of 58 variables related to sediment size and composition - including content of major, minor, and trace elements, heavy and light minerals, and clay minerals - reveals three dominant associations of sediment: 1. (1) The most significant contribution, forming a coarse-grained sediment scattered over most of the shelf consists of felsic sediment derived from the generally quartz-rich rocks of the Alaskan mainland. This sediment contains relatively high concentrations of Si, Ba, Rb, quartz, garnet, epidote, metamorphic rock fragments, potassium feldspar, and illite. 2. (2) The next most important group, superimposed on the felsic group consists of andesitic sediment derived from the Aleutian Islands. This more mafic sediment contains relatively high concentrations of Na, Ca, Ti, Sr, V, Mn, Cu, Fe, Al, Co, Zn, Y, Yb, Ga, volcanic rock fragments, glass, clinopyroxene, smectite, and vermiculite. 3. (3) A local group of basaltic sediment, derived from rocks of the Pribilof Islands, is a subgroup of the Aleutian andesite group. Accumulation of fine-grained sediment in St. George basin has created a sediment group containing relatively high concentrations of C, S, U, Li, B, Zr, Ga, Hg, silt, and clay. Sediment of the Aleutian andesite group exhibits a strong gradient, or "plume", with concentrations decreasing away from Unimak Pass and toward St. George basin. The absence of present-day currents sufficient to move even clay-size material as well as the presence of Bering submarine canyon between the Aleutian

  18. Mineralogy of Copper-Gold Deposit, Masjid Daghi Area, Jolfa, IRAN (United States)

    Zenoozi, Roya


    The Copper-Gold deposit of Masjid Daghi area is located in the Jolfa quadrangle (scale 1:100,000), East Azerbaijan Province, north-west Iran. The deposit, hosting by sub-volcanic bodies comprise of quartz monzonite composition whose intruded the Tertiary volcanic and volcanic-sedimentary rocks and turbidities. The Tertiary volcanic rocks consist of andesite, trachy andesite and quartz andesite. These mineral-bearing bodies related to Late Eocene sub-volcanic activities which intrudded the Eocene volcanic rocks. Mineralography, XRD and SEM studies showed that the variations in mineralization of the area. The main agent of mineralization is the intrusion of Late Eocene sub volcanic bodies inside the Tertiary volcanic units. The mineralography studies revealed two main groups of mineralization as oxides and sulfides. The sulfide minerals formed as veins, vein lets and stock work.The economic minerals comprise of native gold, copper sulfides. The native gold occurring in siliceous veins and almost as inclusions inside the sulfides minerals such as chalcopyrite. The copper sulfides, contain pyrite, chalcopyrite and chalco-pyrrhoyite. Pyrite is main sulfide in the area and formed as disseminations, cavity filling and colloform. The amount of pyrite, chalcopyrite and chalco-pyrrhoyite increases with depth. Supergene alteration produced digenite, covellite, bornite, and malachite. The alteration occurred as potassic, phyllic, argillic and propylitic minerals. Furthermore, selective sercitic, sericitic-chloritic and alunitic alterations are seen around the mineralized veins. The mineralography studies indicate that pyrite is main mineral phase and native gold occurred in silicious vein almost as inclusions inside the sulfide mineral. Most of economic mineral formed as veins, vein lets, disseminated, cavity filling and colloform which related to intrusions of Late Eocene quartz monzonite bodies into the Eocene volcanic rocks and turbiditse. Some types of alterations such as

  19. An overview of the Awibengkok geothermal system, Indonesia

    Energy Technology Data Exchange (ETDEWEB)

    Stimac, James; Nordquist, Gregg; Suminar, Aquardi; Sirad-Azwar, Lutfhie [Chevron Geothermal Salak, Ltd., 11th Floor Sentral Senayan I, Jl. Asia Afrika No. 8, Jakarta 10270 (Indonesia)


    The Awibengkok (Salak) geothermal system is a liquid-dominated, fracture-controlled reservoir with benign chemistry and low-to-moderate non-condensable gas content. The geothermal system is hosted mainly by andesitic-to-rhyodacitic rocks, and floored by Miocene marine sedimentary rocks cut by igneous intrusions. The volcanic sequence is capped by an 8400-year-old phreatic explosion breccia, rhyolite fallout tuff (>8400 years and <40,000 years), rhyolite lavas, domes and related tuffs ({>=}40-120 ka), and dacite-to-rhyodate lavas and domes (185-280 ka) that were erupted across the eastern part of the field from NNE-trending vents controlled by a major fault. More regionally extensive basaltic-andesite to andesite volcanic centers are mostly between 180 and 1610 ka old. Surface and subsurface fault patterns, formation image logs and tracer studies indicate strongly anisotropic permeability aligned with the dominant N to NE fracture trend, dividing the field into a number of subcompartments that are locally connected by fractured aquifers and NW- and E-W-trending fractures. Shallow argillic alteration gives way with increasing depth and temperature to argillic-phyllic and propylitic zones, with the latter accounting for the bulk of the fluid produced from the geothermal system. The commercial Awibengkok reservoir is a moderate-to-high temperature (240-312 C) geothermal resource with high fracture permeability, moderate porosity (mean = 10.6%) and moderate-to-low matrix permeability (geometric mean = 0.026 md). The principal deep upflow zone, with fluid temperatures in the 275-312 C range, is located in the western part of the field. The ascending fluids move up along N- or NNE-trending structures that breach low-permeability tuff layers in the central and east-central parts of the field. Fluids in the central part of the reservoir are uniform in composition and temperature, representing the mixing of upflow and convective reflux. Fluids ascend and flow laterally to

  20. Petrogenesis of volcanic rocks that host the world-class Agsbnd Pb Navidad District, North Patagonian Massif: Comparison with the Jurassic Chon Aike Volcanic Province of Patagonia, Argentina (United States)

    Bouhier, Verónica E.; Franchini, Marta B.; Caffe, Pablo J.; Maydagán, Laura; Rapela, Carlos W.; Paolini, Marcelo


    We present the first study of the volcanic rocks of the Cañadón Asfalto Formation that host the Navidad world-class Ag + Pb epithermal district located in the North Patagonian Massif, Patagonia, Argentina. These volcanic and sedimentary rocks were deposited in a lacustrine environment during an extensional tectonic regime associated with the breakup of Gondwana and represent the mafic to intermediate counterparts of the mainly silicic Jurassic Chon Aike Volcanic Province. Lava flows surrounded by autobrecciated carapace were extruded in subaerial conditions, whereas hyaloclastite and peperite facies suggest contemporaneous subaqueous volcanism and sedimentation. LA-ICPMS Usbnd Pb ages of zircon crystals from the volcanic units yielded Middle Jurassic ages of 173.9 ± 1.9 Ma and 170.8 ± 3 Ma. In the Navidad district, volcanic rocks of the Cañadón Asfalto Formation show arc-like signatures including high-K basaltic-andesite to high-K dacite compositions, Rb, Ba and Th enrichment relative to the less mobile HFS elements (Nb, Ta), enrichment in light rare earth elements (LREE), Ysbnd Ti depletion, and high Zr contents. These characteristics could be explained by assimilation of crustal rocks in the Jurassic magmas, which is also supported by the presence of zircon xenocrysts with Permian and Middle-Upper Triassic ages (281.3 Ma, 246.5, 218.1, and 201.3 Ma) and quartz xenocrysts recognized in these volcanic units. Furthermore, Sr and Nd isotope compositions suggest a contribution of crustal components in these Middle Jurassic magmas. High-K basaltic andesite has initial 87Sr/86Sr ratios of 0.70416-0.70658 and ξNd(t) values of -5.3 and -4. High-K dacite and andesite have initial 87Sr/86Sr compositions of 0.70584-0.70601 and ξNd(t) values of -4,1 and -3,2. The range of Pb isotope values (206Pb/204Pb = 18.28-18.37, 207Pb/204Pb = 15.61-15.62, and 208Pb/204Pb = 38.26-38.43) of Navidad volcanic rocks and ore minerals suggest mixing Pb sources with contributions of

  1. Depleted arc volcanism in the Alboran Sea and shoshonitic volcanism in Morocco: geochemical and isotopic constraints on Neogene tectonic processes (United States)

    Gill, R. C. O.; Aparicio, A.; El Azzouzi, M.; Hernandez, J.; Thirlwall, M. F.; Bourgois, J.; Marriner, G. F.


    Samples of volcanic rocks from Alborán Island, the Alboran Sea floor and from the Gourougou volcanic centre in northern Morocco have been analyzed for major and trace elements and Sr-Nd isotopes to test current theories on the tectonic geodynamic evolution of the Alboran Sea. The Alborán Island samples are low-K tholeiitic basaltic andesites whose depleted contents of HFS elements (˜0.5×N-MORB), especially Nb (˜0.2×N-MORB), show marked geochemical parallels with volcanics from immature intra-oceanic arcs and back-arc basins. Several of the submarine samples have similar compositions, one showing low-Ca boninite affinity. 143Nd/ 144Nd ratios fall in the same range as many island-arc and back-arc basin samples, whereas 87Sr/ 86Sr ratios (on leached samples) are somewhat more radiogenic. Our data point to active subduction taking place beneath the Alboran region in Miocene times, and imply the presence of an associated back-arc spreading centre. Our sea floor suite includes a few more evolved dacite and rhyolite samples with ( 87Sr/ 86Sr) 0 up to 0.717 that probably represent varying degrees of crustal melting. The shoshonite and high-K basaltic andesite lavas from Gourougou have comparable normalized incompatible-element enrichment diagrams and Ce/Y ratios to shoshonitic volcanics from oceanic island arcs, though they have less pronounced Nb deficits. They are much less LIL- and LREE-enriched than continental arc analogues and post-collisional shoshonites from Tibet. The magmas probably originated by melting in subcontinental lithospheric mantle that had experienced negligible subduction input. Sr-Nd isotope compositions point to significant crustal contamination which appears to account for the small Nb anomalies. The unmistakable supra-subduction zone (SSZ) signature shown by our Alboran basalts and basaltic andesite samples refutes geodynamic models that attribute all Neogene volcanism in the Alboran domain to decompression melting of upwelling asthenosphere

  2. Waduk Parangjoho dan Songputri: Alternatif Sumber Erupsi Formasi Semilir di daerah Eromoko, Kabupaten Wonogiri, Jawa Tengah

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    Sutikno Bronto


    Full Text Available Semilir Formation was typically originated from products of a very explosive volcanic activity, i.e. breccias, lapillistones, and tuffs containing abundant pumice. It has a light grey to white colour and high silica andesite to dacite in composition, mainly rich in volcanic glass and quartz. Sedimentary structures of these volcanic rocks are massive, grading, planar bedding, and cross-bedding to antidunes, with grain size varies from ash (≤ 2 mm to lapilli (2 – 64 mm to bomb and block (> 64 mm. The formation is widely distributed from the west side (Pleret and Piyungan areas, Bantul Regency, Special Province of Yogyakarta until Eromoko area in the east (Wonogiri Regency, Jawa Tengah Province. Stratigraphically, the Semilir Formation underlies the Nglanggeran Formation, and overlies the Mandalika Formation in the eastern part and Kebo-Butak Formation in the western part. Geomorphological- and lithological analyses of the Semilir Formation in areas of Parangjoho and Song- putri Dams, Eromoko Sub-regency, Wonogiri Regency indicate that the two depressions were alternatively volcanic sources of the Semilir Formation in the Eromoko area. This is proved by the presence of co-ignimbrite breccias(co-ignimbrite lag fall deposits, that descriptively they are polymict breccias. This rock is characterized by a mixing of pumice and various hard rock fragments that primarily are juvenile materials (volcanic blocks, bombs, accessory-, and accidental rock fragments set in pumice-rich volcanic ash and lapilli sizes. The accessory materials came from older volcanic rocks, whereas the accidental ones were originated from basement rocks. During a caldera forming event or a destruction period of an older composite volcanic cone(s, all older rocks resting above the magma chamber were ejected to the surface by a very high magmatic pressure. Since they were heavier than the juvenile material, most accessory and

  3. Electron Microscopy Observation of Biomineralization within Wood Tissues of Kurogaki

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    Kazue Tazaki


    Full Text Available Interactions between minerals and microorganisms play a crucial role in living wood tissues. However, living wood tissues have never been studied in the field. Fortunately, we found several kurogaki (black persimmon; Diospyros kaki trees at Tawara in Kanazawa, Ishikawa, Japan. Here, we report the characterization of kurogaki based on scanning electron microscopy equipped with energy-dispersive spectroscopy (SEM-EDS and transmission electron microscopy (TEM, associated with inductively coupled plasma-mass spectrometry (ICP-MS analyses, X-ray fluorescence analyses (XRF and X-ray powder diffraction (XRD analyses. This study aims to illustrate the ability of various microorganisms associated with biominerals within wood tissues of kurogaki, as shown by SEM-EDS elemental content maps and TEM images. Kurogaki grows very slowly and has extremely hard wood, known for its striking black and beige coloration, referred to as a “peacock pattern”. However, the scientific data for kurogaki are very limited. The black “peacock pattern” of the wood mainly comprises cellulose and high levels of crystal cristobalite. As per the XRD results, the black taproot contains mineralized 7 Å clays (kaolinite, cellulose, apatite and cristobalite associated with many microorganisms. The chemical compositions of the black and beige portions of the black persimmon tree were obtained by ICP-MS analyses. Particular elements such as abundant Ca, Mg, K, P, Mn, Ba, S, Cl, Fe, Na, and Al were concentrated in the black region, associated with Pb and Sr elements. SEM-EDS semi-qualitative analyses of kurogaki indicated an abundance of P and Ca in microorganisms in the black region, associated with Pb, Sr, S, Mn, and Mg elements. On the other hand, XRF and XRD mineralogical data showed that fresh andesite, weathered andesite, and the soils around the roots of kurogaki correlate with biomineralization of the black region in kurogaki roots, showing clay minerals (kaolinite and

  4. Genesis and gold (Copper) Potential in Darestan-Baghu mining area (South of Damghan)

    International Nuclear Information System (INIS)

    Tajeddin, H. A.; Rashid Nezhad Omran, N.; Babakhani, A. R.


    Darestan-Baghu gold mining area is exposed at about 100 km south of Damghan. The area is a part of Torud-Chahshirin volcano-plutonic belt that crops out as a ho rst with a N E-S W trend in the northern limit Dasht-e-Kavir. The outcrops in the area are Middle-Eocene volcano-pyroclastics with andesite to da cite in composition, which are intruded by a number of intrusive s including granite to granodiorite bodies. Mineralization in Darestan gold occurrence consists of a copper (gold)-bearing silicic vein with 400 meter length occurring within a N-S trending normal fault in andesitic to dacitic- andesitic massive breccia tuff associated with silicic, argillic and propylitic alterations. Mineralization in the vein includes quartz, chalcopyrite, pyrite, gold, specularite, malachite, and iron-hydroxides. Gold mineralization in Baghu vein (at about 3 km N E of Darestan gold occurrence) is as a silicic vein with 700 meter length occurring within a granodiorite-granite sub volcanic with argillic alteration. Mineralization in Baghu vein consists of quartz, pyrite, chalcopyrite, gold, iron oxides and iron-hydroxides, malachite, chalcocite, covellite and tourmaline. Field observations indicate that considerable contents of gold in Darestan area mainly related to sulfide-bearing silicic veins are intruded within N-S normal faults that are generally associated with hydrothermal alteration of argillic, silicic and chloritic (± epi dote) zones. investigation on other mineralized zones of Darestan and Baghu areas suggests a clear genetic relationship between Darestan copper (gold) occurrence and gold-bearing silicic vein of Baghu. Field observations and laboratory studies show a close relationship between the copper (gold) mineralization and late-stage silicic solutions induced from sub volcanic intrusive s with acidic to intermediate composition in Darestan and Baghu districts. Some of the most important lines of evidence are spatial relationship between ore-bearing silicic veins

  5. Diverse lavas from closely spaced volcanoes drawing from a common parent: Emmons Lake Volcanic Center, Eastern Aleutian Arc (United States)

    Mangan, M.; Miller, T.; Waythomas, C.; Trusdell, F.; Calvert, A.; Layer, P.


    Emmons Lake Volcanic Center (ELVC) on the lower Alaskan Peninsula is one of the largest and most diverse volcanic centers in the Aleutian Arc. Since the Middle Pleistocene, eruption of ~ 350 km3 of basalt through rhyolite has produced a 30 km, arc front chain of nested calderas and overlapping stratovolcanoes. ELVC has experienced as many as five major caldera-forming eruptions, the most recent, at ~ 27 ka, produced ~ 50 km3 of rhyolitic ignimbrite and ash fall. These violent silicic events were interspersed with less energetic, but prodigious, outpourings of basalt through dacite. Holocene eruptions are mostly basaltic andesite to andesite and historically recorded activity includes over 40 eruptions within the last 200 yr, all from Pavlof volcano, the most active site in the Aleutian Arc. Geochemical and geophysical observations suggest that although all ELVC eruptions derive from a common clinopyroxene + spinel + plagioclase fractionating high-aluminum basalt parent in the lower crust, magma follows one of two closely spaced, but distinct paths to the surface. Under the eastern end of the chain, magma moves rapidly and cleanly through a relatively young (~ 28 ka), hydraulically connected dike plexus. Steady supply, short magma residence times, and limited interaction with crustal rocks preserve the geochemistry of deep crustal processes. Below the western part of the chain, magma moves haltingly through a long-lived (~ 500 ka) and complex intrusive column in which many generations of basaltic to andesitic melts have mingled and fractionated. Buoyant, silicic melts periodically separate from the lower parts of the column to feed voluminous eruptions of dacite and rhyolite. Mafic lavas record a complicated passage through cumulate zones and hydrous silicic residues as manifested by disequilibrium phenocryst textures, incompatible element enrichments, and decoupling of REEs and HFSEs ratios. Such features are absent in mafic lavas from the younger part of the chain

  6. Paleoproterozoic volcanism in the southern Amazon Craton (Brazil): insight into its origin and deposit textures (United States)

    Roverato, Matteo; Juliani, Caetano


    The Brazilian Amazon craton hosts a primitive volcanic activity that took place in a region completely stable since 1.87 Ga. The current geotectonic context is very different from what caused the huge volcanism that we are presenting in this work. Volcanic rocks in several portions of the Amazon craton were grouped in the proterozoic Uatumã supergroup, a well-preserved magmatic region that covers an area with more than 1,200,000 km2. In this work one specific region is considered, the southwestern Tapajos Gold province (TGP) that is part of the Tapajós-Parina tectonic province (Tassinari and Macambri, 1999). TGP consists of metamorphic, igneous and sedimentary sequences resulted from a ca. 2.10-1.87 Ga ocean-continent orogeny. High-K andesites to felsic volcanic sequences and plutonic bodies, andesitic/rhyolitic epiclastic volcanic rocks and A-type granitic intrusions form part of this volcanism/plutonism. In this work we focus particularly our attention on welded, reomorphic and lava-like rhyolitic ignimbrites and co-ignimbrite brecchas. Fiamme texture of different welding intensity, stretched obsidian fragments, "glassy folds", relict pumices, lithics, rotated crystals of feldspars, bipiramidal quarz, and devetrification spherulites are the common features represented by our samples. Microscopical images are provided to characterize the deposits analyzed during this preliminary research. The lack of continuum outcrops in the field made more difficult the stratigraphic reconstruction, but the superb preservation of the deposits, apparently without any metamorphic evidences (not even low-grade), permits a clearly description of the textures and a differentiation between deposits. A detailed exploration of this ancient andesitic and rhyolitic volcanic activity could contribute greatly to the knowledge of the Amazon territory and in particular for the recognition of the various units that form the supergroup Uatumã, especially in relation to different eruptive

  7. Subaqueous early eruptive phase of the late Aptian Rajmahal volcanism, India: Evidence from volcaniclastic rocks, bentonite, black shales, and oolite

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    Naresh C. Ghose


    Full Text Available The late Aptian (118–115 Ma continental flood basalts of the Rajmahal Volcanic Province (RVP are part of the Kerguelen Large Igneous Province, and constitute the uppermost part of the Gondwana Supergroup on the eastern Indian shield margin. The lower one-third of the Rajmahal volcanic succession contains thin layers of plant fossil-rich inter-trappean sedimentary rocks with pyroclasts, bentonite, grey and black shale/mudstone and oolite, whereas the upper two-thirds consist of sub-aerial fine-grained aphyric basalts with no inter-trappean material. At the eastern margin and the north-central sector of the RVP, the volcanics in the lower part include rhyolites and dacites overlain by enstatite-bearing basalts and enstatite-andesites. The pyroclastic rocks are largely felsic in composition, and comprise ignimbrite as well as coarse-grained tuff with lithic clasts, and tuff breccia with bombs, lapilli and ash that indicate explosive eruption of viscous rhyolitic magma. The rhyolites/dacites (>68 wt.% are separated from the andesites (<60 wt.% by a gap in silica content indicating their formation through upper crustal anatexis with only heat supplied by the basaltic magma. On the other hand, partially melted siltstone xenoliths in enstatite-bearing basalts suggest that the enstatite-andesites originated through mixing of the upper crust with basaltic magma, crystallizing orthopyroxene at a pressure-temperature of ∼3 kb/1150 °C. In contrast, the northwestern sector of the RVP is devoid of felsic-intermediate rocks, and the volcaniclastic rocks are predominantly mafic (basaltic in composition. Here, the presence of fine-grained tuffs, tuff breccia containing sideromelane shards and quenched texture, welded tuff breccia, peperite, shale/mudstone and oolite substantiates a subaqueous environment. Based on these observations, we conclude that the early phase of Rajmahal volcanism occurred under predominantly subaqueous conditions. The presence

  8. Shear thinning behaviors in magmas (United States)

    Vetere, F. P.; Cassetta, M.; Perugini, D.


    Studies on magma rheology are of fundamental importance to understanding magmatic processes from depth to surface. Since viscosity is one of the most important parameter controlling eruption mechanisms, as well as lava flow emplacement, a comprehensive knowledge on the evolution of magma viscosities during crystallization is required. We present new viscosity data on partly crystalized basalt, andesite and analogue lavas comparable to those erupted on Mercury's northern volcanic plains. High-temperature viscosity measurements were performed using a rotational Anton Paar RheolabQC viscometer head at the PVRG labs, in Perugia (Italy) ( The relative proportion of phases in each experimental run were determined by image analysis on BS-SEM images at different magnifications; phases are glasses, clinopyroxene, spinel, plagioclase for the basalt, plagioclase and spinel for the andesite and pure enstatite and clinopyroxenes, for the analogue Mercury's composition. Glass and crystalline fractions determined by image analysis well correlate with compositions of residual melts. In order to constrain the viscosity (η) variations as a function of crystallinity, shear rate (γ) was varied from 0.1 to 5 s-1. Viscosity vs. time at constant temperature shows a typical S-shape curve. In particular, for basaltic composition η vary from 3.1-3.8 Pa s [log η] at 1493 K and crystallinity of 19 area % as γ vary from 1.0 to 0.1 s-1; the andesite viscosity evolution is 3.2 and 3.7 Pa s [log η] as γ varies from 1 to 0.1 at 1493 K and crystal content of 17 area %; finally, Mercury's analogue composition was investigated at different temperature ranging from 1533 to 1502 K (Vetere et al., 2017). Results, for γ = 0.1, 1.0 and 5.0 s-1, show viscosity variation between 2.7-4.0, 2.5-3.4 and 2.0-3.0 [log η inPa s] respectively while crystallinity vary from 9 to 27 (area %). As viscosity decreases as shear rate increases, these data points to a shear thinning behaviour

  9. Soil organic carbon and nitrogen pools drive soil C-CO2 emissions from selected soils in Maritime Antarctica. (United States)

    Pires, C V; Schaefer, C E R G; Hashigushi, A K; Thomazini, A; Filho, E I F; Mendonça, E S


    The ongoing trend of increasing air temperatures will potentially affect soil organic matter (SOM) turnover and soil C-CO 2 emissions in terrestrial ecosystems of Maritime Antarctica. The effects of SOM quality on this process remain little explored. We evaluated (i) the quantity and quality of soil organic matter and (ii) the potential of C release through CO 2 emissions in lab conditions in different soil types from Maritime Antarctica. Soil samples (0-10 and 10-20cm) were collected in Keller Peninsula and the vicinity of Arctowski station, to determine the quantity and quality of organic matter and the potential to emit CO 2 under different temperature scenarios (2, 5, 8 and 11°C) in lab. Soil organic matter mineralization is low, especially in soils with low organic C and N contents. Recalcitrant C form is predominant, especially in the passive pool, which is correlated with humic substances. Ornithogenic soils had greater C and N contents (reaching to 43.15gkg -1 and 5.22gkg -1 for total organic carbon and nitrogen, respectively). C and N were more present in the humic acid fraction. Lowest C mineralization was recorded from shallow soils on basaltic/andesites. C mineralization rates at 2°C were significant lower than at higher temperatures. Ornithogenic soils presented the lowest values of C-CO 2 mineralized by g of C. On the other hand, shallow soils on basaltic/andesites were the most sensitive sites to emit C-CO 2 by g of C. With permafrost degradation, soils on basaltic/andesites and sulfates are expected to release more C-CO 2 than ornithogenic soils. With greater clay contents, more protection was afforded to soil organic matter, with lower microbial activity and mineralization. The trend of soil temperature increases will favor C-CO 2 emissions, especially in the reduced pool of C stored and protected on permafrost, or in occasional Histosols. Copyright © 2016 Elsevier B.V. All rights reserved.

  10. Magma Diversity in the Trans-Mexican Volcanic Belt: the role of Mantle Heterogeneities, Slab-derived Fluxes and Crustal Contamination. (United States)

    Schaaf, P.; Valdez, G.; Siebe, C.; Carrasco, G.


    The Plio-Quaternary Trans-Mexican Volcanic Belt (TMVB) is related to subduction of the Cocos and Rivera plates underneath the North American plate. Non-parallelism of the magmatic arc with respect to the trench can be explained by oblique subduction and changes of dip angle. In this contribution we compare geochemical and Sr-Nd-Pb isotope data of five TMVB stratovolcanoes (from east to west: Colima Volcano, Nevado de Toluca, Popocatepetl, La Malinche, and Pico de Orizaba) and associated cinder cones. Volcanic products range in stratovolcanoes from andesites (e.g. Colima, Popocatepetl) to rhyolites (e.g. Pico de Orizaba), and from basalts to andesites in the monogenetic cones. Concentrations of incompatible elements correlate positively with Sr-Nd-Pb isotope ratios from east to west along the arc. 87Sr/86Sr, eNd, and 206Pb/204Pb range from 0.7034-0.7050, +6.9 to minus 1.8, and 18.57-18.78, respectively, displaying considerable differences. In the central TMVB, REE patterns of closely spaced high-Mg basaltic andesites differ substantially. This cannot be explained by fractional crystallization processes or differential partial melting of a homogeneous mantle source. Instead, it points towards small-scale mantle heterogeneities. LILE (e.g. Cs, Rb, Ba, Pb) and HFSE (e.g. Ta, Nb, Zr) display variations of orders in magnitude at different segments along the arc. These variations might correlate with amounts of slab-derived aqueous fluids and intensity of metasomatic reactions between the subducting lithosphere and the overlying mantle wedge. Isotopic ratios of mid-lower crustal xenoliths found in nearly all stratovolcano products reflect the nature of the underlying crust beneath the TMVB. Tertiary-Cretaceous plagiogranites (Colima), Cretaceous limestones (Popocatepetl), and Grenvillian quartzites (Pico de Orizaba)and their increasing radiogenic isotope ratios match well with the observed isotopic signatures of the stratovolcanoes. Moreover, elevated CO2 amounts in

  11. High-Mg basalts as a Signal of Magma System Replenishment at Lopevi Island, Vanuatu (United States)

    Stewart, R. B.; Smith, I. E.; Turner, M. B.; Cronin, S. J.


    Lopevi is is a basalt to basaltic andesite island stratovolcano in central Vanuatu and is part of a long-lived, mature Island Arc chain. Central Vanuatu is tectonically influenced by the subduction of the D'Entrecasteaux zone. Primitive rock types that have been identified from the arc include picrites, ankaramites and high MgO basalts. High MgO rocks are generally considered to be a relatively rare component of arc-type magma suites but as detailed sequence sampling of individual volcanoes occurs, they have been identified more often. Here we report on the occurrence of high-Mg basalts in a sequence of lavas erupted in the last 100 years from Lopevi volcano. Activity at Lopevi is characteristically intermittent with eruptive sequences occurring over a c. 6 year period, separated by longer periods of repose. A major eruptive episode in 1939 caused evacuation of the island and the next eruptive episode in the 1960's also led to evacuation. The 1960's cycle of activity ended in 1982. The most recent phase of activity commenced in 1998 with a return to eruption of more siliceous, high alumina basaltic andesite. Geochemical data show that the 1960's lavas were different from those erupted earlier and later. They are olivine basalts with up to 9 wt percent MgO, 70 ppm Ni and 300 ppm Cr; Al2O3 content is about 12 wt percent. The 2003 lavas and pre-1960's lavas, in contrast, are basaltic andesites with c. 4 wt percent MgO, less than 25 ppm Ni, less than 100 ppm Cr and c. 20 wt percent Al2O3. The 1960's Lopevi sequence of eruptions represents an injection of a more primitive, high MgO magma at the end of a 21 year quiescent period after the major eruptions of 1939. Injection of small batches of more primitive magmas over decadal time periods at Lopevi marks the initiation of a new magmatic cycle. The occurrence of high MgO magmas as part of a cycle that includes typically low MgO arc type rocks demonstrates a consanguineous relationship and shows that high MgO arc type

  12. A possible connection between post-subduction arc magmatism and adakite-NEB rock association in Baja California, Mexico (United States)

    Castillo, P. R.


    Late Miocene to Recent arc-related magmatism occurs in Baja California, Mexico despite the cessation of plate subduction along its western margin at ~12.5 Ma. It includes calcalkaline and K-rich andesites, tholeiitic basalts and basaltic andesites, alkalic basalts similar to many ocean island basalts (OIB), magnesian and basaltic andesites with adakitic affinity (bajaiites), adakites, and Nb-enriched basalts (NEB). A popular model for the close spatial and temporal association of adakite (plus bajaiite) and NEB in Baja California is these are due to melting of the subducted Farallon/Cocos plate, which in turn is caused by the influx of hot asthenospheric mantle through a window created in the subducted slab directly beneath the Baja California peninsula [e.g., Benoit, M. et. al. (2002) J. Geol. 110, 627-648; Calmus, T. et al. (2003) Lithos 66, 77-105]. Here I propose an alternative model for the cause of post-subduction magmatism in Baja California in particular and origin of adakite-NEB rock association in general. The complicated tectonic configuration of the subducting Farallon/Cocos plate and westward motion of the North American continent caused western Mexico to override the hot, upwelling Pacific mantle that was decoupled from the spreading centers abandoned west of Baja California. The upwelling asthenosphere is best manifested east of the peninsula, beneath the Gulf of California, and is most probably due to a tear or window in the subducted slab there. The upwelling asthenosphere is compositionally heterogeneous and sends materials westward into the mantle wedge beneath the peninsula. These materials provide sources for post-subduction tholeiitic and alkalic magmas. Portions of tholeiitic magmas directly erupted at the surface produce tholeiitic lavas, but some get ponded beneath the crust. Re-melting and/or high-pressure fractional crystallization of the ponded tholeiitic magmas generate adakitic rocks. Alkalic magmas directly erupted at the surface

  13. Stratigraphy, distribution, and evidence for mafic triggering of the ca. 8.5 ka Driftwood Pumice eruption, Makushin Volcano, Alaska, U.S.A (United States)

    Lerner, Allan H.; Crowley, Peter D.; Nicolaysen, Kirsten P.; Hazlett, Richard W.


    Makushin Volcano on Unalaska Island, Alaska, threatens the Aleutian's largest population centers (Unalaska and Dutch Harbor), yet its eruption mechanisms are poorly known. This study presents a detailed stratigraphic and geochemical investigation of Makushin's most recent highly explosive event: the ca. 8.5 ka Driftwood Pumice eruption. The Driftwood Pumice has measured thicknesses of over 2.5 m, and isopach reconstructions estimate a total deposit volume of 0.3 to 1.6 km3, indicating a VEI 4-5 eruption. Proximal deposits consist of normally-graded, tan, dacitic to andesitic pumice, capped by a thinner dark layer of lower-silica andesitic scoria mixed with abundant lithic fragments. This stratigraphy is interpreted as an initial vent-clearing eruption that strengthened into a climactic ejection of pumice and ash and concluded with vent destabilization and the eruption of somewhat more mafic, gas-poor magma. Within the pumice, geochemical trends, disequilibrium mineral populations, and mineral zonation patterns show evidence of magma mixing between a bulk silicic magma and a mafic melt. Euhedral high-Ca plagioclase (An68-91) and high-Mg olivine (Fo69-77) phenocrysts are in disequilibrium with trachydacitic glass (65-68 wt% SiO2) and more abundant sodic plagioclase (An34-55), indicating the former originally crystallized in a more mafic melt. Tephra whole rock compositions become more mafic upwards through the deposit, ranging from a basal low-silica dacite to an andesite (total range: 60.8-63.3 wt% SiO2). Collectively, these compositional variations suggest magma mixing in the Driftwood Pumice (DWP) magma reservoir, with a systematic increase in the amount of a mafic component (up to 25%) upward through the deposit. Olivine-liquid and liquid-only thermometry indicate the mafic magma intruded at temperatures 140-200 °C hotter than the silicic magma. Diffusion rates calculated for 5-7 μm thick, lower-Mg rims on the olivine phenocrysts (Fo60 rim vs Fo76 bulk) suggest

  14. Vulnerability of Karangkates dams area by means of zero crossing analysis of data magnetic

    Energy Technology Data Exchange (ETDEWEB)

    Sunaryo,, E-mail:, E-mail:; Susilo, Adi [Geophysics Program Study, Physics Dept., Sciences Faculty, University of Brawijaya, Malang (Indonesia)


    Study with entitled Vulnerability Karangkates Dam Area By Means of Zero Crossing Analysis of Data Magnetic has been done. The study was aimed to obtain information on the vulnerability of two parts area of Karangkates dams, i.e. Lahor dam which was inaugurated in 1977 and Sutami dam inaugurated in 1981. Three important things reasons for this study are: 1). The dam age was 36 years old for Lahor dam and 32 years old for Sutami dam, 2). Geologically, the location of the dams are closed together to the Pohgajih local shear fault, Selorejo local fault, and Selorejo limestone-andesite rocks contact plane, and 3). Karangkates dams is one of the important Hydro Power Plant PLTA with the generating power of about 400 million KWH per year from a total of about 29.373MW installed in Indonesia. Geographically, the magnetic data acquisition was conducted at coordinates (112.4149oE;-8.2028oS) to (112.4839oE;-8.0989oS) by using Proton Precession Magnetometer G-856. Magnetic Data acquisition was conducted in the radial direction from the dams with diameter of about 10 km and the distance between the measurements about 500m. The magnetic data acquisition obtained the distribution of total magnetic field value in the range of 45800 nT to 44450 nT. Residual anomalies obtained by doing some corrections, including diurnal correction, International Geomagnetic Reference Field (IGRF) correction, and reductions so carried out the distribution of the total magnetic field value in the range of -650 nT to 700 nT. Based on the residual anomalies, indicate the presence of 2 zones of closed closures dipole pairs at located in the west of the Sutami dam and the northwest of the Lahor dam from 5 total zones. Overlapping on the local geological map indicated the lineament of zero crossing patterns in the contour of residual anomaly contour with the Pohgajih shear fault where located at about 4 km to the west of the Sutami dam approximately and andesite-limestone rocks contact where located

  15. Viscosity controlled magma-carbonate interaction: a comparison of Mt. Vesuvius (Italy) and Mt. Merapi (Indonesia). (United States)

    Blythe, L. S.; Misiti, V.; Masotta, M.; Taddeucci, J.; Freda, C.; Troll, V. R.; Deegan, F. M.; Jolis, E. M.


    Magma-carbonate interaction is increasingly seen as a viable and extremely important cause of magma contamination, and the generation of a crustally sourced CO2 phase (Goff et al., 2001; Freda et al., 2010). Even though the process is well recognized at certain volcanoes e.g. Popocatépetl, (Mexico); Merapi, (Indonesia); and Colli Albani, (Italy) (Goff et al., 2001; Deegan et al., 2010; Freda et al., 2010), neither the kinetics of carbonate assimilation nor its consequences for controlling the explosivity of eruptions have been constrained. Here we show the results of magma-carbonate interaction experiments conducted at 1200 °C and 0.5 GPa for varying durations (0 s, 60 s, 90 s and 300 s) for the Mt. Merapi (Indonesia) and Mt. Vesuvius (Italy) volcanic systems. We performed experiments using glassy starting materials specific to each volcano (shoshonite for Mt. Vesuvius, basaltic-andesite for Mt. Merapi) with different degrees of hydration (anhydrous vs hydration with ~ 2 wt % water) and using carbonate fragments of local origin; see Deegan et al., (2010) and Jolis et al., (2011). Experimental products include a gas phase (CO2-rich) and two melt phases, one pristine (Ca-normal) and one contaminated (Ca-rich) separated by a 'contamination front' which propagates outwards from the carbonate clast. Vesicles appear to nucleate in the contaminated glass and then migrate into the pristine one. Both contamination front propagation and bubble migration away from the carbonate are slower in anhydrous basaltic-andesite (Merapi anhydrous series) than in hydrated basaltic-andesite and shoshonite (Merapi and Vesuvius hydrated series), suggesting that assimilation speed is strongly controlled by the degree of hydration and the SiO2 content, both of which influence melt viscosity and hence diffusivity. As the carbonate dissolution proceeds in our experiments, initially dissolved and eventually exsolved CO2 builds up in the contaminated Ca-rich melt phase. Once melt volatile

  16. The Origin of Silicic Arc Crust - Insights from the Northern Pacific Volcanic Arcs through Space and Time (United States)

    Straub, S. M.; Kelemen, P. B.


    The remarkable compositional similarities of andesitic crust at modern convergent margins and the continental crust has long evoked the hypothesis of similar origins. Key to understanding either genesis is understanding the mode of silica enrichment. Silicic crust cannot be directly extracted from the upper mantle. Hence, in modern arcs, numerous studies - observant of the pervasive and irrefutable evidence of melt mixing - proposed that arc andesites formed by mixing of mantle-derived basaltic melts and fusible silicic material from the overlying crust. Mass balance requires the amount of silicic crust in such hybrid andesites to be on the order to tens of percent, implying that their composition to be perceptibly influenced by the various crustal basements. In order to test this hypothesis, major and trace element compositions of mafic and silicic arc magmas with arc-typical low Ce/PbMexico) were combined with Pb isotope ratios. Pb isotope ratios are considered highly sensitive to crustal contamination, and hence should reflect the variable composition of the oceanic and continental basement on which these arcs are constructed. In particular, in thick-crust continental arcs where the basement is isotopically different from the mantle and crustal assimilation thought to be most prevalent, silicic magmas must be expected to be distinct from those of the associated mafic melts. However, in a given arc, the Pb isotope ratios are constant with increasing melt silica regardless of the nature of the basement. This observation argues against a melt origin of silicic melts from the crustal basement and suggest them to be controlled by the same slab flux as their co-eval mafic counterparts. This inference is validated by the spatial and temporal pattern of arc Pb isotope ratios along the Northern Pacific margins and throughout the 50 million years of Cenozoic evolution of the Izu Bonin Mariana arc/trench system that are can be related to with systematic, `real

  17. The onset of the volcanism in the Ciomadul Volcanic Dome Complex (Eastern Carpathians): Eruption chronology and magma type variation (United States)

    Molnár, Kata; Harangi, Szabolcs; Lukács, Réka; Dunkl, István; Schmitt, Axel K.; Kiss, Balázs; Garamhegyi, Tamás; Seghedi, Ioan


    Combined zircon U-Th-Pb and (U-Th)/He dating was applied to refine the eruption chronology of the last 2 Myr for the andesitic and dacitic Pilişca volcano and Ciomadul Volcanic Dome Complex (CVDC), the youngest volcanic area of the Carpathian-Pannonian region, located in the southernmost Harghita, eastern-central Europe. The proposed eruption ages, which are supported also by the youngest zircon crystallization ages, are much younger than the previously determined K/Ar ages. By dating every known eruption center in the CVDC, repose times between eruptive events were also accurately determined. Eruption of the andesite at Murgul Mare (1865 ± 87 ka) and dacite of the Pilişca volcanic complex (1640 ± 37 ka) terminated an earlier pulse of volcanic activity within the southernmost Harghita region, west of the Olt valley. This was followed by the onset of the volcanism in the CVDC, which occurred after several 100s kyr of eruptive quiescence. At ca. 1 Ma a significant change in the composition of erupted magma occurred from medium-K calc-alkaline compositions to high-K dacitic (Baba-Laposa dome at 942 ± 65 ka) and shoshonitic magmas (Malnaş and Bixad domes; 964 ± 46 ka and 907 ± 66 ka, respectively). Noteworthy, eruptions of magmas with distinct chemical compositions occurred within a restricted area, a few km from one another. These oldest lava domes of the CVDC form a NNE-SSW striking tectonic lineament along the Olt valley. Following a brief (ca. 100 kyr) hiatus, extrusion of high-K andesitic magma continued at Dealul Mare (842 ± 53 ka). After another ca. 200 kyr period of quiescence two high-K dacitic lava domes extruded (Puturosul: 642 ± 44 ka and Balvanyos: 583 ± 30 ka). The Turnul Apor lava extrusion occurred after a ca. 200 kyr repose time (at 344 ± 33 ka), whereas formation of the Haramul Mic lava dome (154 ± 16 ka) represents the onset of the development of the prominent Ciomadul volcano. The accurate determination of eruption dates shows that the

  18. Geochemical characterization of mid-distal Nisyros tephra on Datça peninsula (southwestern Anatolia) (United States)

    Gençalioğlu-Kuşcu, Gonca; Uslular, Göksu


    We present new distal records of tephra deposits that overly the Kos ignimbrite in seven locations of Datça peninsula. Tephra in one of these locations were previously associated with Nisyros Kyra sub-unit based only on the field characteristics. We use different proxies such as field observations, petrography, mineral, glass, and whole-rock chemistry in order to characterize and correlate the previously and recently identified pumice fall deposits on Datça. The total thickness of the fall deposit reaches to 3.5 m. The size of the pumice clasts is generally within the range of lapilli, and they have vitrophyric texture consisting mainly of plagioclase (andesine to labradorite) with scarce clinopyroxene (diopside to augite), olivine (Fo48-50), amphibole (magnesio-hastingsite), and biotite crystals. Amphibole is a ubiquitous phenocryst in all Datça tephra units and used as a criterion for the correlation. Glass major element analyses by EMPA reveal two different groups with andesitic and dacitic compositions. Difference in silica content (up to ca. 4 wt%) detected in the same specimen also designates the heterogeneity in pumice glass. This heterogeneity in glass composition is also supported by the frequent occurrence of banded pumice clasts in Datça tephra. Whole-rock composition of the pumice is mainly andesitic with calc-alkaline affinity. Multi-element patterns on primitive-mantle normalized diagram display typical arc-magmatism signature (i.e. depletion in Nb, Ta, Ti, and P). In order to check and eliminate the potential alternatives, we compared the distal deposits on Datça not only with Kyra, but also with other Nisyros tephra units. Yet, Kyra is the only unit that has comparable depositional characteristics, calcic amphibole crystals, andesitic-dacitic glass and whole-rock chemistry, and distal tephra deposits on neighboring islands (Tilos and Chalki). Therefore, we associate Datça tephra deposits with some proximal Kyra subunits of intermediate

  19. The Late Jurassic Panjeh submarine volcano in the northern Sanandaj-Sirjan Zone, northwest Iran: Mantle plume or active margin? (United States)

    Azizi, Hossein; Lucci, Federico; Stern, Robert J.; Hasannejad, Shima; Asahara, Yoshihiro


    The tectonic setting in which Jurassic igneous rocks of the Sanandaj-Sirjan Zone (SaSZ) of Iran formed is controversial. SaSZ igneous rocks are mainly intrusive granodiorite to gabbroic bodies, which intrude Early to Middle Jurassic metamorphic basement; Jurassic volcanic rocks are rare. Here, we report the age and petrology of volcanic rocks from the Panjeh basaltic-andesitic rocks complex in the northern SaSZ, southwest of Ghorveh city. The Panjeh magmatic complex consists of pillowed and massive basalts, andesites and microdioritic dykes and is associated with intrusive gabbros; the overall sequence and relations with surrounding sediments indicate that this is an unusually well preserved submarine volcanic complex. Igneous rocks belong to a metaluminous sub-alkaline, medium-K to high-K calc-alkaline mafic suite characterized by moderate Al2O3 (13.7-17.6 wt%) and variable Fe2O3 (6.0-12.6 wt%) and MgO (0.9-11.1 wt%) contents. Zircon U-Pb ages (145-149 Ma) define a Late Jurassic (Tithonian) age for magma crystallization and emplacement. Whole rock compositions are enriched in Th, U and light rare earth elements (LREEs) and are slightly depleted in Nb, Ta and Ti. The initial ratios of 87Sr/86Sr (0.7039-0.7076) and εNd(t) values (-1.8 to +4.3) lie along the mantle array in the field of ocean island basalts and subcontinental metasomatized mantle. Immobile trace element (Ti, V, Zr, Y, Nb, Yb, Th and Co) behavior suggests that the mantle source was enriched by fluids released from a subducting slab (i.e. deep-crustal recycling) with some contribution from continental crust for andesitic rocks. Based the chemical composition of Panjeh mafic and intermediate rocks in combination with data for other gabbroic to dioritic bodies in the Ghorveh area we offer two interpretations for these (and other Jurassic igneous rocks of the SaSZ) as reflecting melts from a) subduction-modified OIB-type source above a Neo-Tethys subduction zone or b) plume or rift tectonics involving

  20. Soil mineral assemblage influences on microbial communities and carbon cycling under fresh organic matter input (United States)

    Finley, B. K.; Schwartz, E.; Koch, B.; Dijkstra, P.; Hungate, B. A.


    The interactions between soil mineral assemblages and microbial communities are important drivers of soil organic carbon (SOC) cycling and storage, although the mechanisms driving these interactions remain unclear. There is increasing evidence supporting the importance of associations with poorly crystalline, short-range order (SRO) minerals in protection of SOC from microbial utilization. However, how the microbial processing of SRO-associated SOC may be influenced by fresh organic matter inputs (priming) remains poorly understood. The influence on SRO minerals on soil microbial community dynamics is uncertain as well. Therefore, we conducted a priming incubation by adding either a simulated root exudate mixture or conifer needle litter to three soils from a mixed-conifer ecosystem. The parent material of the soils were andesite, basalt, and granite and decreased in SRO mineral content, respectively. We also conducted a parallel quantitative stable isotope probing incubation by adding 18O-labelled water to the soils to isotopically label microbial DNA in situ. This allowed us to characterize and identify the active bacterial and archaeal community and taxon-specific growth under fresh organic matter input. While the granite soil (lowest SRO content), had the largest total mineralization, the least priming occurred. The andesite and basalt soils (greater SRO content) had lower total respiration, but greater priming. Across all treatments, the granite soil, while having the lowest species richness of the entire community (249 taxa, both active and inactive), had a larger active community (90%) in response to new SOC input. The andesite and basalt soils, while having greater total species richness of the entire community at 333 and 325 taxa, respectively, had fewer active taxa in response to new C compared to the granite soil (30% and 49% taxa, respectively). These findings suggest that the soil mineral assemblage is an important driver on SOC cycling under fresh

  1. Rb-Sr and Ar-Ar systematics of Malani volcanic rocks of southwest Rajasthan: evidence for a younger post-crystallization thermal event

    International Nuclear Information System (INIS)

    Rathore, S.S.; Srivastava, R.K.


    A new Rb-Sr age of 779 ± 10 Ma has been obtained for a suite of andesite-dacite-rhyolite from the Malani igneous province of southwestern Rajasthan, dated earlier at 745 ± 10 Ma by Crawford and Compston (1970). The associated basalts may be slightly younger than the felsic volcanics and have a mantle source. The felsic volcanics on the other hand were most probably derived by fractional crystallization of a crustal magma. 40 Ar- 39 Ar systematics of three samples viz., a basalt, a dacite and a rhyolite show disturbed age spectra indicating a thermal event around 500-550 Ma ago. This secondary thermal event is quite wide-spread and possibly related to the Pan-African thermo-tectonic episode observed in the Himalayas and south India. (author). 38 refs., 5 figs., 2 tabs

  2. Laser cutting of concretes with various ballasts

    International Nuclear Information System (INIS)

    Hamasaki, Masanobu; Katsumura, Munehide; Utsumi, Hiroaki


    The biological shield concrete and the radiation shield concrete which construct a part of the atomic reactor must be demolished with the decommissioning of the atomic reactor plants. In a case, the demolition using a laser is expected as one of excellent method for the decommissioning of these radioactive concretes. The fundamental cuttings of a mortar, the concretes with andesite, lime stone and gray wacke as ballast and a concrete reinforced with mild steel rods were therefore carried out using a 5 kW output CO 2 laser. As the results of experiment, it was cleared that cutting results varied with ballasts, 100 mm thick reinforced concrete could be cut, safety was high because few dross and few fume were produced. (author)

  3. A dynamical analysis of the seismic activity of Villarrica volcano (Chile) during September-October 2000

    Energy Technology Data Exchange (ETDEWEB)

    Tarraga, Marta [Departamento de Volcanologia. Museo Nacional de Ciencias Naturales, CSIC, Madrid (Spain)], E-mail:; Carniel, Roberto [Dipartimento di Georisorse e Territorio, Universita di Udine, Via Cotonificio 114, 33100 Udine (Italy)], E-mail:; Ortiz, Ramon; Garcia, Alicia [Departamento de Volcanologia. Museo Nacional de Ciencias Naturales, CSIC, Madrid (Spain); Moreno, Hugo [Observatorio Volcanologico de los Andes del Sur (OVDAS), Servicio Nacional de Geologia y Mineria de Chile (SERNAGEOMIN), Temuco, IX Region (Chile)


    Although Villarrica volcano in Chile is one of the most active in the southern Andes, the literature studying its seismic activity is relatively scarce. An interesting problem recently tackled is the possibility for a regional tectonic event to trigger a change in the volcanic activity of this basaltic to basaltic-andesitic volcano, which is in turn reflected in the time evolution of the properly volcanic seismicity, especially in the form of a continuous volcanic tremor. In this work, we conduct a spectral, dynamical and statistical analysis of the tremor recorded during September and October 2000, in order to characterize the anomalous behaviour of the volcano following a tectonic event recorded on 20th September 2000. The observed dynamical transitions are compared with remote sensing and visual observations describing the changes in the eruptive style of the volcano.

  4. Achieving Mixtures of Ultra-High Performance Concrete

    Directory of Open Access Journals (Sweden)

    Mircea POPA


    Full Text Available Ultra-High Performance Concrete (UHPC is a relatively new concrete. According to [11] UHPC is that concrete which features compressive strength over C100/115 class. Up to this point standards for this type of concrete were not adopted, although its characteristic strength exceeds those specified in [33]. Its main property is high compressive strength. This provides the possibility of reducing the section of elements (beams or columns made of this type of concrete, while the load capacity remains high. The study consists in blending mixtures of UHPC made of varying proportions of materials. The authors have obtained strengths of up to 160 MPa. The materials used are: Portland cement, silica fume, quartz powder, steel fibers, superplasticiser, sand and crushed aggregate for concrete - andesite.

  5. Zircon U-Pb and molybdenite Re-Os geochronology and Sr-Nd-Pb-Hf isotopic constraints on the genesis of the Xuejiping porphyry copper deposit in Zhongdian, Northwest Yunnan, China (United States)

    Leng, Cheng-Biao; Zhang, Xing-Chun; Hu, Rui-Zhong; Wang, Shou-Xu; Zhong, Hong; Wang, Wai-Quan; Bi, Xian-Wu


    The Xuejiping porphyry copper deposit is located in northwestern Yunnan Province, China. Tectonically, it lies in the southern part of the Triassic Yidun island arc. The copper mineralization is mainly hosted in quartz-dioritic and quartz-monzonitic porphyries which intruded into clastic-volcanic rocks of the Late Triassic Tumugou Formation. There are several alteration zones including potassic, strong silicific and phyllic, argillic, and propylitic alteration zones from inner to outer of the mineralized porphyry bodies. The ages of ore-bearing quartz-monzonitic porphyry and its host andesite are obtained by using the zircon SIMS U-Pb dating method, with results of 218.3 ± 1.6 Ma (MSWD = 0.31, N = 15) and 218.5 ± 1.6 Ma (MSWD = 0.91, N = 16), respectively. Meanwhile, the molybdenite Re-Os dating yields a Re-Os isochronal age of 221.4 ± 2.3 Ma (MSWD = 0.54, N = 5) and a weighted mean age of 219.9 ± 0.7 Ma (MSWD = 0.88). They are quite in accordance with the zircon U-Pb ages within errors. Furthermore, all of them are contemporary with the timing of the Garzê-Litang oceanic crust subduction in the Yidun arc. Therefore, the Xuejiping deposit could be formed in a continental margin setting. There are negative ɛNd(t) values ranging from -3.8 to -2.1 and relatively high initial 87Sr/86Sr ratios from 0.7051 to 0.7059 for the Xuejiping porphyries and host andesites. The (206Pb/204Pb)t, (207Pb/204Pb)t and (208Pb/204Pb)t values of the Xuejiping porphyries and host andesites vary from 17.899 to 18.654, from 15.529 to 15.626, and from 37.864 to 38.52, respectively, indicative of high radiogenic Pb isotopic features. In situ Hf isotopic analyses on zircons by using LA-MC-ICP-MS exhibit that there are quite uniform and slightly positive ɛHf(t) values ranging from -0.2 to +3.2 (mostly between 0 and +2), corresponding to relatively young single-stage Hf model ages from 735 Ma to 871 Ma. These isotopic features suggest that the primary magmas of the Xuejiping porphyries and

  6. Thermal characteristics of rocks for high-level waste repository

    International Nuclear Information System (INIS)

    Shimooka, Kenji; Ishizaki, Kanjiro; Okamoto, Masamichi; Kumata, Masahiro; Araki, Kunio; Amano, Hiroshi


    Heat released by the radioactive decay of high-level waste in an underground repository causes a long term thermal disturbance in the surrounding rock mass. Several rocks constituting geological formations in Japan were gathered and specific heat, thermal conductivity, thermal expansion coefficient and compressive strength were measured. Thermal analysis and chemical analysis were also carried out. It was found that volcanic rocks, i.e. Andesite and Basalt had the most favorable thermal characteristics up to around 1000 0 C and plutonic rock, i.e. Granite had also favorable characteristics under 573 0 C, transition temperature of quartz. Other igneous rocks, i.e. Rhyolite and Propylite had a problem of decomposition at around 500 0 C. Sedimentary rocks, i.e. Zeolite, Tuff, Sandstone and Diatomite were less favorable because of their decomposition, low thermal conductivity and large thermal expansion coefficient. (author)

  7. Net Acid Production, Acid Neutralizing Capacity, and Associated Mineralogical and Geochemical Characteristics of Animas River Watershed Igneous Rocks Near Silverton, Colorado (United States)

    Yager, Douglas B.; Choate, LaDonna; Stanton, Mark R.


    This report presents results from laboratory and field studies involving the net acid production (NAP), acid neutralizing capacity (ANC), and magnetic mineralogy of 27 samples collected in altered volcanic terrain in the upper Animas River watershed near Silverton, Colo., during the summer of 2005. Sampling focused mainly on the volumetrically important, Tertiary-age volcanic and plutonic rocks that host base- and precious-metal mineralization in the study area. These rocks were analyzed to determine their potential for neutralization of acid-rock drainage. Rocks in the study area have been subjected to a regional propylitic alteration event, which introduced calcite, chlorite (clinochlore), and epidote that have varying amounts and rates of acid neutralizing capacity (ANC). Locally, hydrothermal alteration has consumed any ANC and introduced minerals, mainly pyrite, that have a high net acid production (NAP). Laboratory studies included hydrogen pyroxide (H2O2) acid digestion and subsequent sodium hydroxide (NaOH) titration to determine NAP, and sulfuric acid (H2SO4) acid titration experiments to determine ANC. In addition to these environmental rock-property determinations, mineralogical, chemical, and petrographic characteristics of each sample were determined through semiquantitative X-ray diffractometry (Rietveld method), optical mineralogy, wavelength dispersive X-ray fluorescence, total carbon-carbonate, and inductively coupled plasma?mass spectrometric analysis. An ANC ranking was assigned to rock samples based on calculated ANC quantity in kilograms/ton (kg/t) calcium carbonate equivalent and ratios of ANC to NAP. Results show that talus near the southeast Silverton caldera margin, composed of andesite clasts of the Burns Member of the Silverton Volcanics, has the highest ANC (>100 kg/t calcium carbonate equivalent) with little to no NAP. The other units found to have moderate to high ANC include (a) andesite lavas and volcaniclastic rocks of the San Juan

  8. Evidence for crustal recycling during the Archean: the parental magmas of the stillwater complex

    International Nuclear Information System (INIS)

    McCallum, I.S.


    The petrology and geochemistry of the Stillwater Complex, an Archean (2.7 Ga) layered mafic intrusion in the Beartooth Mountains of Montana, is discussed. Efforts to reconstruct the compositions of possible parental magmas and thereby place some constraints on the composition and history of their mantle source regions was studied. A high-Mg andesite or boninite magma best matches the crystallization sequences and mineral compositions of Stillwater cumulates, and represents either a primary magma composition or a secondary magma formed, for example, by assimilation of crustal material by a very Mg-rich melt such as komatiite. Isotopic data do not support the extensive amounts of assimilation required by the komatiite parent hypothesis, and it is argued that the Stillwater magma was generated from a mantle source that had been enriched by recycling and homogenization of older crustal material over a large area

  9. Archean crustal evolution in the central Minto block, northern Quebec

    International Nuclear Information System (INIS)

    Skulski, T.; Percival, J.A.; Stern, R.A.


    The central Minto block contains three volcano-sedimentary successions. Near Lake Qalluviartuuq, an isotopically primitive ( 2.83 Ga ε Nd +3.8 to +2.3) 2.83 Ga volcano-plutonic sequence comprises depleted tholeiitic basalts, anorthositic gabbro, and diorite-granodiorite that is unconformably overlain by 2.76 Ga ε Nd +1.8) calc-alkaline sequence of pillow basalts, andesites, and peridotite cut by 2.73 Ga diorite. To the west, and in inferred tectonic contact, the sediment-dominated Kogaluc sequence includes both isotopically evolved calc-alkaline rocks ( 2.76 Ga ε Nd +1.6 to -0.1) including 2.78Ga ε Nd Nd 2.725Ga ε Nd - 1. 6). (author). 19 refs., 4 tabs., 5 figs

  10. Geochronology of the Sleeper deposit, Humboldt County, Nevada: epithermal gold-silver mineralization following emplacement of a silicic flow-dome complex (United States)

    Conrad, J.E.; McKee, E.H.; Rytuba, J.J.; Nash, J.T.; Utterback, W.C.


    The high-grade gold-silver deposits at the Sleeper mine are low sulfidation, quartz-adularia-type epithermal deposits, formed during the final stages of igneous hydrothermal activity of a small middle Miocene silicic flow-dome complex in north-central Nevada. There were multiple pulses of alteration and mineralization but all occurred within a period of less than 2 m.y. Later supergene alteration formed opal and alunite about 5.4 Ma but produced no Au or Ag mineralization other than some remobilization to produce locally rich pockets of secondary Au and Ag enrichment and is unrelated to the older magmatic hydrothermal system. The Sleeper deposit in the northern part of the Great Basin is genetically related to bimodal volcanism that followed a long period of arc-related andesitic volcanism in the same general region. -from Authors

  11. Temporal evolution of the Western and Central volcanism of the Aeolian Island Arc (Italy, southern Tyrhhenian Sea) (United States)

    Leocat, E.; Gillot, P.-Y.; Peccerillo, A.


    The Aeolian Archipelago is a volcanic arc in the Southern Tyrrhenian Sea located on the continental margin of the Calabro-Peloritan basement. The Aeolian volcanism occurs in a very complex geodynamic setting linked to the convergence of the European and African plates. For that reason, it is strongly related to regional tectonic lineaments, such as the NW-SE trending Tindari-Letojani (TL) fault. The archipelago consists of seven main islands and several seamounts, which extend around the Marsili Basin, forming a ring-like shape, typical for an island arc. While the seamounts began their activities around 1 Ma , the emerged part is active since about 400 ka. The magmatic products of the whole arc range from typical island arc calc-alkaline (CA) and shoshonitic series, to slightly silica undersaturated potassic alkaline series that are typical of post-collisional settings. Furthermore, the TL fault, along which the Lipari and Vulcano islands are developed, separates a calc-alkaline western sector (Alicudi, Filicudi and Salina islands) from the calc-alkaline to potassic eastern system (Panarea and Stromboli islands) (Peccerillo,1999). This makes of the Aeolian Islands a complex volcanism, with a still controversial origin. In this context, the aim of this work is to constrain the sources and spatio-temporal evolution of this magmatism. We present here new K-Ar ages based on the accurate Cassignol-Gillot technique devoted to the dating of very young rocks (Gillot et Cornette, 1986). These geochronological data were used together with new geochemical data on the same samples. In this study, we attempt to understand the origin of those magmatic events and the relationship between the deep processes and the shallow structures. Our results allow us to define specific periods of very quick geomechemical changes. In the case of Filicudi island, the first rocks range in composition from CA basalts to andesites. This period ended with the edification of the Mte Guardia at 189

  12. Self-sealing of rock fractures. A possibility around the repositories of high-level radioactive wastes

    International Nuclear Information System (INIS)

    Chigira, Masahiro; Nakata, Eiji


    To the goal of the safe geological disposal of high-level radioactive wastes (HLW), we must provide long-term confidence for the isolation of HLW in various ways. In particular, groundwater flow, the most likely transport media of radioactive nuclides from HLW, must be restricted around a repository for long time. For that purpose, grouting techniques using cement, bentonite, or other materials have been studied in many countries. In this paper we report the results of a series of experiments on silica precipitation behavior in a flow path with negative temperature gradients in granite and also describe a natural example of hydrothermal alteration of diatomite intruded by andesite. Based on these, we will discuss the possibility of self-sealing around HLW repository. (J.P.N.)

  13. Oxygen and hydrogen isotope studies of gold mineralization in the southern Apuseni Mountains, Romania: interpretation and problems

    International Nuclear Information System (INIS)

    Alderton, David H.M.


    Precious and base metal mineralization in the southern Apuseni Mountains of western Romania occurs in several steeply-dipping veins which are hosted by Miocene andesitic rocks. Fluid inclusion evidence suggests that the majority of the mineralization was caused by low salinity fluids at temperatures between 200 and 300 o C. Although subject to several uncertainties, the oxygen and hydrogen isotope data support a model in which main stage mineralization was formed when a metal-bearing magmatic fluid was exsolved from the crystallizing melt. In contrast to many other 'epithermal' precious metal deposits, the incorporation into the hydrothermal system of local meteoric groundwaters was minor, and mostly restricted to the latest, barren, low temperature stage of mineralization. (Author)

  14. Mermer Ve Yapıtaşı Olarak Kullanılan Farklı Jeolojik Kökenli Kayaçların Porozite, P-Dalga Hızı Ve Basınç Dayanımı İlişkisinin İncelenmesi

    Directory of Open Access Journals (Sweden)

    Mustafa KUŞCU


    Full Text Available In this study, the relationships between the apparent porosity, porosity and uniaxial compressive strength and P-wave velocity of geologically different origins some natural stones that used as marble and building stone were investigated. For this purposes, 58 samples of diabase, andesite, trachyandesite, limestone and travertine were collected from the marble-quarries and potential industrial usable fields. According to results of the evaluation of the data while the porosity values in the igneous and sedimentary rocks decreases, which results increases in the P-wave velocity values and the highest value is observed in the hard, fossiliferous, calcite veined Balkırı Beige Limestone. The relation between uniaxial compressive strength and P-wave velocity was reveals that this relation not only depends on the porosity of the rocks, but also depends on the mineralogical, textural, alteration and structural characteristics of the rock types

  15. Paleomagnetic contributions to the Klamath Mountains terrane puzzle-a new piece from the Ironside Mountain batholith, northern California (United States)

    Mankinen, Edward A.; Gromme, C. Sherman; Irwin, W. Porter


    We obtained paleomagnetic samples from six sites within the Middle Jurassic Ironside Mountain batholith (~170 Ma), which constitutes the structurally lowest part of the Western Hayfork terrane, in the Klamath Mountains province of northern California and southern Oregon. Structural attitudes measured in the coeval Hayfork Bally Meta-andesite were used to correct paleomagnetic data from the batholith. Comparing the corrected paleomagnetic pole with a 170-Ma reference pole for North America indicates 73.5° ± 10.6° of clockwise rotation relative to the craton. Nearly one-half of this rotation may have occurred before the terrane accreted to the composite Klamath province at ~168 Ma. No latitudinal displacement of the batholith was detected.

  16. Lithogeochemistry and fluid flow in the epithermal Veta Rublo base metal-silver deposit, Chonta Mine (Huancavelica, Perú)


    Castroviejo Bolibar, Ricardo; Yparraguirre, José Andrés; Chacón, E.


    The Chonta Mine (75º00’30” W & 13º04’30”S, 4495 to 5000 m absl), owned by Compañía Minera Caudalosa, operates a polymetallic Zn-Pb-Cu-Ag vein system of the low sulphidation epithermal type, hosted by cenozoic volcanics of dacitic to andesitic composition (Domos de Lava Formation). Veta Rublo, one of the main veins of the system, is worked underground to nearly 300 m. It strikes 60-80º NE and dips 60-70º SE; its width varies between 0.30 and 2.20m, and it crops out along 1 km, but is continued...

  17. Age of the Karakoram fault activation: 40Ar-39Ar geochronological study of Shyok suture zone in northern Ladakh, India

    International Nuclear Information System (INIS)

    Bhutani, Rajneesh; Pande, Kanchan; Desai, Nikhil


    Shyok volcanics, from the Shyok suture zone in northern Ladakh, ranging from basalts to andesites are analysed for 40 Ar- 30 Ar isotopic systematics by step heating experiment. All samples, collected along the Nubra river, in the vicinity of Karakoram fault zone, yielded disturbed age spectra, reflecting subsequent tectono-thermal events. However, consistency in the pattern of the age spectra, particularly at the low temperature steps, indicate a strong tectono-thermal event between ∼ 10 to ∼ 20 Ma ago. Mica-segregate from segregate from a sheared granite of Karakoram fault zone near village Murgi has yielded an excellent plateau age of 13.9 ± 0.1 Ma. This age of Karakoram fault activation explains the consistent but disturbed age spectra of Shyok volcanics within the vicinity of the fault zone. The Karakoram fault activation in Shyok suture zone is therefore synchronous with the extensional tectonic regime within the Tibetan plateau. (author)

  18. Volcanic Ash fall Impact on Vegetation, Colima 2005 (United States)

    Garcia, M. G.; Martin, A.; Fonseca, R.; Nieto, A.; Radillo, R.; Armienta, M.


    An ash sampling network was established arround Colima Volcano in 2005. Ash fall was sampled on the North, Northeast, East, Southeast, South, Southwest and West of the volcano. Samples were analyzed for ash components, geochemistry and leachates. Ash fall ocurred on April (12), May (10, 23), June (2, 6, 9, 10, 12, 14), July (27), September (27), October (23) and November (24). Most of the ash is made of andesitic dome-lithics but shows diferences in crystal, juvenile material and lithic content. In May, some samples contained grey and dark pumice (scoria). Texture varies from phi >4 to phi 0. Leachate concentration were low: SO4 (7.33-54.19) Cl- (2.29-4.97) and F- (0.16-0.37). During 2005, Colima Volcano's ash fall rotted some of the guava and peach fruits and had a drying effect on spearment and epazote plants. Even these small ash amounts could have hindered sugar cane and agave growth.

  19. Upper Paleozoic mafic and intermediate volcanic rocks of the Mount Pleasant caldera associated with the Sn-W deposit in southwestern New Brunswick (Canada): Petrogenesis and metallogenic implications (United States)

    Dostal, Jaroslav; Jutras, Pierre


    Upper Paleozoic ( 365 Ma) mafic and intermediate volcanic rocks of the Piskahegan Group constitute a subordinate part of the Mount Pleasant caldera, which is associated with a significant polymetallic deposit (tungsten-molybdenum-bismuth zones 33 Mt ore with 0.21% W, 0.1% Mo and 0.08% Bi and tin-indium zones 4.8 Mt with 0.82% Sn and 129 g/t In) in southwestern New Brunswick (Canada). The epicontinental caldera complex formed during the opening of the late Paleozoic Maritimes Basin in the northern Appalachians. The mafic and intermediate rocks make up two compositionally distinct associations. The first association includes evolved rift-related continental tholeiitic basalts, and the second association comprises calc-alkaline andesites, although both associations were emplaced penecontemporaneously. The basalts have low Mg# 0.34-0.40, smooth chondrite-normalized REE patterns with (La/Yb)n 5-6, primitive mantle-normalized trace element patterns without noticeable negative Nb-Ta anomalies, and their ɛNd(T) ranges from + 2.5 to + 2.2. The basalts were generated by partial melting of a transition zone between spinel and garnet mantle peridotite at a depth of 70-90 km. The calc-alkaline andesites of the second association have chondrite-normalized REE patterns that are more fractionated, with (La/Yb)n 7-8.5, but without significant negative Eu anomalies. Compared to the basaltic rocks, they have lower ɛNd(T) values, ranging from + 0.5 to + 1.9, and their mantle-normalized trace element plots show negative Nb-Ta anomalies. The ɛNd(T) values display negative correlations with indicators of crustal contamination, such as Th/La, Th/Nb and SiO2. The andesitic rocks are interpreted to have formed by assimilation-fractional crystallization processes, which resulted in the contamination of a precursor basaltic magma with crustal material. The parent basaltic magma for both suites underwent a different evolution. The tholeiitic basalts experienced shallow-seated fractional

  20. A dynamical analysis of the seismic activity of Villarrica volcano (Chile) during September-October 2000

    International Nuclear Information System (INIS)

    Tarraga, Marta; Carniel, Roberto; Ortiz, Ramon; Garcia, Alicia; Moreno, Hugo


    Although Villarrica volcano in Chile is one of the most active in the southern Andes, the literature studying its seismic activity is relatively scarce. An interesting problem recently tackled is the possibility for a regional tectonic event to trigger a change in the volcanic activity of this basaltic to basaltic-andesitic volcano, which is in turn reflected in the time evolution of the properly volcanic seismicity, especially in the form of a continuous volcanic tremor. In this work, we conduct a spectral, dynamical and statistical analysis of the tremor recorded during September and October 2000, in order to characterize the anomalous behaviour of the volcano following a tectonic event recorded on 20th September 2000. The observed dynamical transitions are compared with remote sensing and visual observations describing the changes in the eruptive style of the volcano


    Directory of Open Access Journals (Sweden)

    Asmoro Widagdo


    Full Text Available Lawa Cave in Purbalingga Regency is a special type of cave as it formed not at calcareous rocks like at the usual cave. It is formed by lava flow processes. So, it is made of an igneous rock and it has an andesit basaltic rock type. Lawa Cave formed due to lava flow of the volcanic eruption of the Old Slamet Volcano. The rocks composition of Lawa Cave consists of primary minerals that are plagioclase and volcanic glass and some secondary mineral like calcite and ferri oxide which is fill the previous gas pores. Generally, rock fractures in Lawa Cave is formed as primary joint when the lava flow was cooling down, tectonic joints is found very limited. Lawa Cave’s direction is controlled by the flow direction of the melting lava. It’s direction indicate the paleomorphology of the volcano.

  2. Volcanic Eruption Forecasts From Accelerating Rates of Drumbeat Long-Period Earthquakes (United States)

    Bell, Andrew F.; Naylor, Mark; Hernandez, Stephen; Main, Ian G.; Gaunt, H. Elizabeth; Mothes, Patricia; Ruiz, Mario


    Accelerating rates of quasiperiodic "drumbeat" long-period earthquakes (LPs) are commonly reported before eruptions at andesite and dacite volcanoes, and promise insights into the nature of fundamental preeruptive processes and improved eruption forecasts. Here we apply a new Bayesian Markov chain Monte Carlo gamma point process methodology to investigate an exceptionally well-developed sequence of drumbeat LPs preceding a recent large vulcanian explosion at Tungurahua volcano, Ecuador. For more than 24 hr, LP rates increased according to the inverse power law trend predicted by material failure theory, and with a retrospectively forecast failure time that agrees with the eruption onset within error. LPs resulted from repeated activation of a single characteristic source driven by accelerating loading, rather than a distributed failure process, showing that similar precursory trends can emerge from quite different underlying physics. Nevertheless, such sequences have clear potential for improving forecasts of eruptions at Tungurahua and analogous volcanoes.

  3. Interpreting compositional zonation of the Zaragoza ignimbrite from Los Humeros caldera, Central Mexico

    International Nuclear Information System (INIS)

    Carrasco-Nunez, Gerardo; McCurry, Michael; Branney, Michael J


    Compositional zonation in ignimbrites is relatively common, and is often inferred to record gradual withdrawal by an eruption of a density-stratified magma chamber (with silicic magma towards the top and more dense, mafic magma at the bottom). We show that this model does not match observations at the ca. 0.1 Ma Zaragoza ignimbrite from Los Humeros caldera in central Mexico. Detailed petrologic studies reveal a more complex scenario: the ignimbrite exhibits a 'double' vertical zonation based on the compositions of pumice lapilli. We present evidence for mingling and limited mixing occurred during or immediately before the caldera-forming eruption. One possibility to explain the observations is that the ignimbrite eruption occurred in response to intrusion of a hybridized andesitic magma into a rhyodacitic magma chamber.

  4. Geological research on rare earth elements, results and outlook

    International Nuclear Information System (INIS)

    Fortin, H


    This is a report of the geological investigation of rare earth elements carried out by CCHEN and ENAMI (Empresa Nacional de Mineria) over 70,000 square kilometers in Chile's northern coastal mountain range. Twenty areas were identified with sphena, davidite, ilmenite, pyroxene, anatase and magnetite minerals containing 0.3 kg/t to 6.0 kg/t of rare earth elements. Additional research on Cerro Carmen Prospect, located near Diego de Almagro, define it as a metasomatic deposit, hosted in metamorphic contact rocks, between andesites (Pliensbachian to early Jurassic) and intrusive monzonitic rocks. This information increases knowledge about the metallogenesis of Chile's copper - iron - rare earth - uranium deposits and the application of this geological model of ore deposits as defined in Australia's Olympic Dam

  5. Cerro Amarillo rhyolites, advanced AFC in the northern SVZ, Chile

    International Nuclear Information System (INIS)

    Godoy, E; Hildreth, W


    Cerro Amarillo is a Quaternary medium size (500m high, 2 km 2 ) rhyolite dome complex located close to the Chile-Argentina border, reaching a height of 4162 m, between the headwaters of the Rio Colina and the Nieves Negras Pass. It overlies a broad anticline of thick Middle Jurassic pelites (Alvarez et al., 1997). Thiele (1980) includes this complex in his 'Unidad Volcanica Antigua', a Pleistocene composite map unit made up of andesites and trachyandesites. Ramos et al. (1997), while recognizing its rhyolitic character, assigned a Tertiary age to the lava domes, most likely based on the late Pliocene age of silicic dikes outcropping eastward, in Argentina. Both the lack of younger overlying units and freshness of its components, together with preservation of the unconsolidated, easily eroded pyroclastic deposits at its base, suggest, however, that it is not older than Pleistocene (au)

  6. Fluid inclusions study in thermal gradient wells, Nevado del Ruiz Volcano

    International Nuclear Information System (INIS)

    Uruena Suarez, Cindy L; Zuluaga, Carlos A; Molano, Juan Carlos


    A fluid inclusions study in the Nevado del Ruiz volcano hydrothermal system allowed to characterize fluids involved in the evolution of the geothermal system. Fluid inclusions hosted in quartz, plagioclase and carbonate from samples of the deepest parts of three thermal gradient wells were analyzed to understand fluid-rock interaction. Fluid inclusions hosted in carbonate veins with coloform microestructure represent hydrothermal fluids with temperatures higher than 250 Celsius degrade. This interpretation is supported by microprobe and cathodoluminescence analysis that also indicate a hydrothermal origin for the veins. Fluid inclusions hosted in quartz (mylonite) were originated by metamorphic fluids and fluid inclusions hosted in plagioclase (andesitic lavas) are considered to be originated from magmatic fluids (H 2 O + CO 2 system).

  7. The Laramide Mesa formation and the Ojo de Agua caldera, southeast of the Cananea copper mining district, Sonora, Mexico (United States)

    Cox, Dennis P.; Miller, Robert J.; Woodbourne, Keith L.


    The Mesa Formation extends from Cananea, Mexico, southeast to the Sonora River and is the main host rock of Laramide porphyry copper deposits in the Cananea District and at the Alacran porphyry prospect to the east. The Mesa consists of two members-a lower andesite and an upper dacite. The lowest part of the dacite member is a crystal tuff about 100 m thick. This tuff is the outfall of a caldera centered near the village of Ojo de Agua, dated by 40Ar/39Ar at 65.8 Ma ?0.4. The Ojo de Agua Caldera is about 9 km in diameter and is filled by a light gray biotite dacite tuff with abundant flattened pumice fragments. The volume of the caldera is estimated to be 24 km3.

  8. Groundwater drilling location determination in Girirejo Village, Tempuran Sub-District, Magelang

    International Nuclear Information System (INIS)

    FD Indrastomo; I Gde Sukadana


    Girirejo Village is one of the villages in Tempuran Sub-district, Magelang Regency which have fresh water difficulty. Determination of groundwater drilling location conducted with phases of activity include desk study stage, topographic data collection, geology and hydrogeology mapping, geo electrical surveys, and integrated analysis. Based on the results of field geological mapping, it is found that the area is composed of three rock units, namely andesite, breccia tuff and sandy tuff. Results of rock resistivity measurements show the value of resistivity 16 - 32 ohm-m are interpreted as sandy tuff with wet conditions, and the value of resistivity 60 - 80 ohm-m is interpreted as a breccia. Location TMG-14 at depths of 1.6 - 29.1 m by 27.5 m thick aquifer is a potential point which next recommended as potential sites of groundwater drilling. (author)

  9. Greated era of volcanic front in Middle Kyushu and Western Chugoku districts

    Energy Technology Data Exchange (ETDEWEB)

    Kamata, Hirotake; Hoshizumi, Hideo; Koyaguchi, Takehiro


    Purpose of this study was to determine the era when the creation of the volcanos commenced which were extending from north-east to south west, by using the K-Ar age of volcanic rocks which were continuously distributed from middle Kyushu to San-in district and which were mainly composed of amphibole andesite. By comparing with geological map, relation with the stratigraphic order of layers at Yabakei, Himejima and Aono were considered. It was concluded that, in every place, the vocanic activities commenced much later era than creation of basement rock. It was also recognized that, by studying the relation with Phillipine Plate, deep earthquake was related with the volcanic front of south west Japan arc. (8 figs, 2 tabs, 14 refs)

  10. 238U-230Th-226Ra radioactive disequilibria in the products from 1707 eruption of Fuji volcano, Japan

    International Nuclear Information System (INIS)

    Kurihara, Yuichi; Takahashi, Masaomi; Sato, Jun


    Time scale of magmatic processes in the 1707 eruptive activity of Fuji volcano, Japan, was estimated by the 238 U- 230 Th- 226 Ra disequilibria observed in the 1707 volcanic products. The activity ratios of 226 Ra/ 230 Th in the products were larger than unity, being enriched in 226 Ra relative to 230 Th. The decay-corrected 226 Ra/ 230 Th activity ratio to the time of the eruption versus 238 U/ 230 Th activity ratio diagram for the 1707 volcanic products showed a positive correlation, suggesting that the 238 U/ 230 Th- 226 Ra disequilibria occurred during the magma genesis of Fuji volcano. The 230 Th- 226 Ra disequilibria in the 1707 volcanic products suggested that the time scale from the magma genesis to the eruption, including the melting of the mantle wedge, magma storage and magmatic differentiation from basalt to andesite, was less than 8000 years. (author)

  11. Petrology and oxygen isotope geochemistry of the Pucon ignimbrite - Southern Andean volcanic zone, Chile: Implications for genesis of mafic ignimbrites

    International Nuclear Information System (INIS)

    McCurry, Michael; Schmidt, Keegan


    Although mafic components of dominantly intermediate to silicic ignimbrites are rather common, voluminous, dominantly mafic ignimbrites are rare (e.g., Smith, 1979; cf. Freundt and Schmincke, 1995). Volcan Villarrica, the most active composite volcano in South America, located in the Southern Andean Volcanic Zone (SAVZ, Lopez-Escobar and Moreno, 1994a), has produced two such ignimbrites, respectively the Lican and Pucon Ignimbrites, in the last 14,000 years (Clavero, 1996). The two ignimbrites are low-Si andesite and basaltic-andesite to low-Si andesite, respectively, the former about twice as voluminous as the later (10 and 5 km 3 ). Eruption of the ignimbrites produced calderas respectively 5 and 2 km in diameter (Moreno, 1995; Clavero, 1996). In addition to its mafic bulk composition, the Pucon Ignimbrite (PI) is also distinguished by numerous xenolithic fragments among and also within magmatic pyroclasts. Many of these are fragments of granitoid rocks. Volcan Villarrica has also produced numerous smaller mafic ignimbrites and pyroclastic surge deposits, as well as dominantly basaltic fallout and lava flows (Lopez-Escobar and Moreno, 1994; Moreno, 1995; Clavero, 1996; Hickey-Vargas et al., 1989; Tormey et al., 1991). Reasons for the unusual style of mafic explosive activity at Volcan Villarrica are unclear. Clavero (1996), based upon an exemplary thesis-study of the physical volcanology and petrology of the PI, suggests it formed in response to a sequence of events beginning with injection of a shallow basaltic andesite magma chamber by hotter basaltic magma. In his model mixing and heat transfer between the two magmas initiated a violent Strombolian eruption that destabilized the chamber causing infiltration of large amounts of meteoric-water saturated country rocks. The Pucon Ignimbrite formed in response to subsequent phreatomagmatic interactions. In contrast, Lopez-Escobar and Moreno (1994) infer on geochemical grounds that volatiles leading to the explosive

  12. K-Ar Geochronology and isotopic composition of the late oligocene- early miocene Ancud volcanic complex, Chiloe

    International Nuclear Information System (INIS)

    Munoz B, Jorge; Duhart O, Paul; Farmer, G. Lang; Stern, Charles R


    The Ancud Volcanic Complex (Gally and Sanchez , 1960) forms a portion of the Mid-Tertiary Coastal Magmatic Belt which outcrops in the area of northern Chiloe island. Main exposures occur at Ancud, Punta Polocue, Punihuil, Pumillahue, Tetas de Teguaco and Bahia Cocotue. The Ancud Volcanic Complex consists of basaltic to basaltic andesites lava flows and volcanic necks and rhyolitic pyroclastic flows and vitric domes. Previous studies indicate a Late Oligocene-Early Miocene age (Garcia et al., 1988; Stern and Vergara, 1992; Munoz et al., 2000). The Ancud Volcanic Complex covers and intrudes Palaeozoic-Triassic metamorphic rocks and is partially covered by an early to middle Miocene marine sedimentary sequence known as Lacui Formation (Valenzuela, 1982) and by Pleistocene glacial deposits (Heusser, 1990). At Punihuil locality, lava flows are interbedded with the lower part of the marine sedimentary sequence, which includes significant amounts of redeposited pyroclastic components. Locally, the presence of hyaloclastic breccias suggests interaction of magma with marine water (au)

  13. Evaluation of the high concentrations of nitrate in the spring The Freedom and their relationship with the field of wells The Valencia, Sacred Domingo of Heredia Costa Rica

    International Nuclear Information System (INIS)

    Agudelo Arango, C. L.


    At general level in the study area one can observe a sequence of layers of lavas belonging to different laundries of andesitic composition of variable character (dense to breachess), being often presented strongly fractured, conforming the different aquifer levels (Inferior Colima, Superior Colima and The Freedom). These lavic layers are found interstratified with layers of low permeability, composed by ashy tufas and ignimbrites that conform the units grieves, they possess a secondary hydraulic conductivity that possibly favors the drainage for graveness, allowing: 1) the step of the rain through the Tiribi grieve toward the aquifer The Freedom, and 2) a hydraulic connection among the different aquifer levels. The study area is characterized in three areas of same hidrogeochemical and isotopic behavior [es

  14. Multidisciplinary exploratory study of a geothermal resource in the active volcanic arc of Basse-Terre (Guadeloupe, Lesser Antilles) (United States)

    Navelot, Vivien; Favier, Alexiane; Géraud, Yves; Diraison, Marc; Corsini, Michel; Verati, Chrystèle; Lardeaux, Jean-Marc; Mercier de Lépinay, Jeanne; Munschy, Marc


    The GEOTREF project (high enthalpy geothermal energy in fractured reservoirs), supported by the French government program, "Investissements d'avenir" develops a sustainable geothermal resource in the Vieux Habitants area, 8-km south of the currently exploited Bouillante geothermal field. The Basse Terre Island is a recent volcanic arc (meta-andesite. This metamorphism forms cleavage plans thanks to a pressure-solution mechanism. Mineralogical transformations associated with these cleavage planes have an impact on petrophysical properties. The solid phase density and porosity decrease. An anisotropy of permeability develops due to cleavage plans. Thermodynamics modelling based on the rock chemical composition and petrography observations emphasizes a steady-state mineral assemblage between 1.5 - 2 kbar and 280 - 320˚ C. This is consistent with an in situ measured volcanic arc conductive geothermal gradient of 70 ˚ C/km.

  15. Mechanical properties of rock at high temperatures

    International Nuclear Information System (INIS)

    Kinoshita, Naoto; Abe, Tohru; Wakabayashi, Naruki; Ishida, Tsuyoshi.


    The laboratory tests have been performed in order to investigate the effects of temperature up to 300degC and pressure up to 30 MPa on the mechanical properties of three types of rocks, Inada granite, Sanjoume andesite and Oya tuff. The experimental results indicated that the significant differences in temperature dependence of mechanical properties exist between the three rocks, because of the difference of the factors which determine the mechanical properties of the rocks. The effect of temperature on the mechanical properties for the rocks is lower than that of pressure and water content. Temperature dependence of the mechanical properties is reduced by increase in pressure in the range of pressure and temperature investigated in this paper. (author)

  16. The post-Laramide clastic deposits of the Sierra de Guanajuato: Compositional implications on the tectono-sedimentary and paleographic evolution

    Energy Technology Data Exchange (ETDEWEB)

    Miranda-Aviles, R.; Puy-Alquiza, M.J.; OmaNa, L.; Loza-Aguirre, I.


    This article presents the results of the study on sedimentation, sedimentary environments, tectono-sedimentary and paleogeographic evolution of post-Laramide clastic deposits and pre-volcanism of the Sierra Madre Occidental in the Sierra de Guanajuato, central Mexico. The Eocene Duarte Conglomerate and Guanajuato Conglomerate were deposited in the middle and distal parts of alluvial fans. The studied rocks are composed of limestone clasts, granite, andesite, metasediments, diorite, and pyroxenite, indicating the erosion of uplifted blocks of the basal complex of the Sierra de Guanajuato (Arperos basin). The petrographic and compositional analysis of limestone shows a textural variation from basin limestones and shallow platform limestones. The shallow platform limestone contain bivalves, brachiopods, gastropods, echinoderms and benthic foraminifera from the Berriasian-Valanginian. The shallow-water limestone corresponds to the boundary of the Arperos basin whose original outcrops currently not outcrop in the Sierra de Guanajuato. (Author)


    Directory of Open Access Journals (Sweden)

    Ioan Bâca


    Full Text Available Igneous intrusive structures from Bârgău Mountains belong to the group of central Neogene volcanic chain of the Eastern Carpathians of Romania. The evolution of the relief developed on these structures are three main stages: the stage of injection of structures (Pannonian, the stage of uncovering of igneous intrusive bodies from Oligo-Miocene sedimentary cover (Pliocene, and the stage of subaerial modeling of magmatic bodies (Pliocene-current.In those circumstances, the geodiversity of intrusive magmatic structures from Bârgău Mountains is represented by several types of landforms such as: polycyclic landforms (erosional levels, structural landforms (the configuration of igneous intrusive structures, petrographic landforms (andesites, lithological contact, fluvial landforms (valleys, slopes, ridges, periglacial landforms (cryogenic and crionival landforms, biogenic and anthropogenic landforms. This study highlights certain features of the landforms modeled on igneous intrusive bodies with the aim of developing some strategy for tourism recovery by local and county authorities.

  18. Overview of Qatecalovo-Kulaming uranium metallogenic region

    International Nuclear Information System (INIS)

    Zhao Fengmin


    Qatecalovo-Kulaming uranium metallogenic region is the earliest discovered volcanic-type uranium metallogenic region in the world, which which is located in the Kulaming uplift of Middle Tianshan Variscan orogenic belt. Ten deposits have been discovered in the mine area, over 20000 t metallic uranium has been mined out. Uranium deposits mainly occurred in Late Palaeozoic volcanic depression, and the volcanic rocks are characterized by the great lithologic change from andesite to rhyolite. Mineralization age is from 260 to 270 Ma. The tectonic unit in which the metallogenic region is located can extend eastward into China. Therefore, the ore-forming condition study on this tectonic unit can be used to guide the prospection for Palaeozoic volcanics uranium deposit in northwestern China. (author)

  19. Interpreting compositional zonation of the Zaragoza ignimbrite from Los Humeros caldera, Central Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Carrasco-Nunez, Gerardo [Centro de Geociencias, UNAM, Campus Juriquilla, Queretaro, Qro. (Mexico); McCurry, Michael [Department of Geology, Idaho State University, Pocatello, ID (United States); Branney, Michael J [Department of Geology, University of Leicester, Leicester (United Kingdom)


    Compositional zonation in ignimbrites is relatively common, and is often inferred to record gradual withdrawal by an eruption of a density-stratified magma chamber (with silicic magma towards the top and more dense, mafic magma at the bottom). We show that this model does not match observations at the ca. 0.1 Ma Zaragoza ignimbrite from Los Humeros caldera in central Mexico. Detailed petrologic studies reveal a more complex scenario: the ignimbrite exhibits a 'double' vertical zonation based on the compositions of pumice lapilli. We present evidence for mingling and limited mixing occurred during or immediately before the caldera-forming eruption. One possibility to explain the observations is that the ignimbrite eruption occurred in response to intrusion of a hybridized andesitic magma into a rhyodacitic magma chamber.

  20. Quaternary basaltic volcanism in the Payenia volcanic province, Argentina

    DEFF Research Database (Denmark)

    Søager, Nina

    primitive basalts and trachybasalts but also more evolved samples from the retroarc region and the larger volcanoes Payún Matrú and Payún Liso are presented. The samples cover a broad range of compositions from intraplate lavas similar to ocean island basalts to arc andesites. A common feature found...... are isotopically similar to the Andean Southern Volcanic Zone arc rocks and their mantle source possibly resembled the source of South Atlantic N-MORB prior to addition of fluids and melts from the subduction channel. However, it must have been more enriched than the estimates of depleted upper mantle from...... the lithosphere is thinnest and possibly in areas of elevated mantle temperatures. The pyroxenite melts formed at deeper levels react with the surrounding peridotite and thereby changes composition leading to eruption of melts which experienced variable degrees of melt-peridotite interaction. This can presumably...

  1. Chemical and Mineralogical Features of Smectite from the Morron de Mateo Bentonite Deposit (Cabo de Gata, Almeria) in Relation to the Parent Rocks and the Alteration Processes Occurred After the Bentonite Formation: Analogies and Implications for the Engineered Clayey Barrier of a Deep Geological Rad waste Repository; Naturaleza de las Esmectitas del Yacimiento de Morron de Mateo (Cabo de Gata, Almeria) en Relacion con la Roca Madre y con los Procesos Posteriores a la Bentonitizacion: Implicaciones Analogicas para la Barrera de Ingenieria de un Almacenamiento Geologico de Residuos Radiactivos

    Energy Technology Data Exchange (ETDEWEB)

    Pelayo, M; Labajo, M A; Garcia Romero, L; Perez del Villar, L


    The Morron de Mateo bentonite deposit is being studied as a natural analogue of the thermal and geochemical effects on the clayey barrier of a Deep Geological Rad waste Repository (DGRR) after its closure, in relation to the radioactive decay of the fission products and the container corrosion. This bentonite deposit and their host rocks were intruded by a rhyodacitic volcanic dome that induced a hydrothermal metasomatic process affecting the bioclastic calcarenite beds close to the dome. Bentonite from the NE sector of the deposit have been chemically and mineralogically characterized. Pyroclastic rocks (white tuffs), epyclastic rocks (mass flow) and andesitic breccia all of them hydrothermally altered, have been studied at the site. Samples are composed of feldspars, quartz and amphybols, as inherited minerals, and phyllosilicates, zeolites, crystoballite and calcite, as new formed minerals. White tuffs have the highest phyllosilicate contents, mainly dioctahedral smectite of montmorillonite type. Epyclastic rocks and andesitic breccia have a highest proportion of inherited minerals, the new formed phillosilicates being di octahedral smectite of beidellite type and an ordered interlayer chlorite/smectite mineral, of corrensite type. Smectite from the epyclastic rocks have higher Fe and Mg contents and chemical variability, as a consequence of nature of their parent rocks. The presence of corrensite in the epyclastic rocks suggests that in the Morron de Mateo area a propilitic alteration process occurred after bentonite formation, which transformed Fe-Mg-rich smectite into corrensite. This transformation was probably favoured by the sub volcanic intrusion, which also produced a temperature increase in the geological media and a supply of Fe-Mg-rich solutions, which also were the responsible for the metasomatic transformations observed in the calcarenite beds. (Author) 57 refs.

  2. Chemical and Mineralogical Features of Smectite from the Morron de Mateo Bentonite Deposit (Cabo de Gata, Almeria) in Relation to the Parent Rocks and the Alteration Processes Occurred After the Bentonite Formation: Analogies and Implications for the Engineered Clayey Barrier of a Deep Geological Rad waste Repository

    International Nuclear Information System (INIS)

    Pelayo, M.; Labajo, M. A.; Garcia Romero, L.; Perez del Villar, L.


    The Morron de Mateo bentonite deposit is being studied as a natural analogue of the thermal and geochemical effects on the clayey barrier of a Deep Geological Rad waste Repository (DGRR) after its closure, in relation to the radioactive decay of the fission products and the container corrosion. This bentonite deposit and their host rocks were intruded by a rhyodacitic volcanic dome that induced a hydrothermal metasomatic process affecting the bioclastic calcarenite beds close to the dome. Bentonite from the NE sector of the deposit have been chemically and mineralogically characterized. Pyroclastic rocks (white tuffs), epyclastic rocks (mass flow) and andesitic breccia all of them hydrothermally altered, have been studied at the site. Samples are composed of feldspars, quartz and amphybols, as inherited minerals, and phyllosilicates, zeolites, crystoballite and calcite, as new formed minerals. White tuffs have the highest phyllosilicate contents, mainly dioctahedral smectite of montmorillonite type. Epyclastic rocks and andesitic breccia have a highest proportion of inherited minerals, the new formed phillosilicates being di octahedral smectite of beidellite type and an ordered interlayer chlorite/smectite mineral, of corrensite type. Smectite from the epyclastic rocks have higher Fe and Mg contents and chemical variability, as a consequence of nature of their parent rocks. The presence of corrensite in the epyclastic rocks suggests that in the Morron de Mateo area a propilitic alteration process occurred after bentonite formation, which transformed Fe-Mg-rich smectite into corrensite. This transformation was probably favoured by the sub volcanic intrusion, which also produced a temperature increase in the geological media and a supply of Fe-Mg-rich solutions, which also were the responsible for the metasomatic transformations observed in the calcarenite beds. (Author) 57 refs

  3. Mapping erosion susceptibility by a multivariate statistical method: A case study from the Ayvalık region, NW Turkey (United States)

    Akgün, Aykut; Türk, Necdet


    Erosion is one of the most important natural hazard phenomena in the world, and it poses a significant threat to Turkey in terms of land degredation and desertification. To cope with this problem, we must determine which areas are erosion-prone. Many studies have been carried out and different models and methods have been used to this end. In this study, we used a logistic regression to prepare an erosion susceptibility map for the Ayvalık region in Balıkesir (NW Turkey). The following were our assessment parameters: weathering grades of rocks, slope gradient, structural lineament density, drainage density, land cover, stream power index (SPI) and profile curvature. These were processed by Idrisi Kilimanjaro GIS software. We used logistic regression analysis to relate predictor variables to the occurrence or non-occurrence of gully erosion sites within geographic cells, and then we used this relationship to produce a probability map for future erosion sites. The results indicate that lineament density, weathering grades of rocks and drainage density are the most important variables governing erosion susceptibility. Other variables, such as land cover and slope gradient, were revealed as secondary important variables. Highly weathered basalt, andesite, basaltic andesite and lacustrine sediments were the units most susceptible to erosion. In order to calculate the prediction accuracy of the erosion susceptibility map generated, we compared it with the map showing the gully erosion areas. On the basis of this comparison, the area under curvature (AUC) value was found to be 0.81. This result suggests that the erosion susceptibility map we generated is accurate.

  4. The intra-oceanic Cretaceous (~ 108 Ma) Kata-Rash arc fragment in the Kurdistan segment of Iraqi Zagros suture zone: Implications for Neotethys evolution and closure (United States)

    Ali, Sarmad A.; Ismail, Sabah A.; Nutman, Allen P.; Bennett, Vickie C.; Jones, Brian G.; Buckman, Solomon


    The Kata-Rash arc fragment is an allochthonous thrust-bound body situated near Penjween, 100 km northeast of Sulymannia city, Kurdistan Region, within the Iraqi portion of the Zagros suture zone. It forms part of the suprasubduction zone 'Upper Allochthon' terranes (designated as the Gimo-Qandil Group), which is dominated by calc-alkaline andesite and basaltic-andesite, rhyodacite to rhyolite, crosscut by granitic, granodioritic, and dioritic dykes. Previously, rocks of the Kata-Rash arc fragment were interpreted as a part of the Eocene Walash volcanic group. However, SHRIMP zircon U-Pb dates on them of 108.1 ± 2.9 Ma (Harbar volcanic rocks) and 107.7 ± 1.9 Ma (Aulan intrusion) indicate an Albian-Cenomanian age, which is interpreted as the time of igneous crystallisation. The Aulan intrusion zircons have initial εHf values of + 8.6 ± 0.2. On a Nb/Yb-Th/Yb diagram, all Kata-Rash samples fall within the compositional field of arc-related rocks, i.e. above the mid-ocean-ridge basalt (MORB)-ocean island basalt (OIB) mantle array. Primitive-mantle-normalised trace-element patterns for the Kata-Rash samples show enrichment in the large ion lithophile elements and depletion in the high-field-strength elements supporting their subduction-related character. Low Ba/La coupled with low La/Yb and Hf/Hf* 3000 km continuity of Cretaceous arc activity (Oman to Cyprus), that consumed Neotethyian oceanic crust between Eurasia and the Gondwanan fragment Arabia.

  5. Amphibole Fractional Crystallization and Delamination in Arc Roots: Implications for the `Missing' Nb Reservoir in the Earth (United States)

    Galster, F.; Chatterjee, R. N.; Stockli, D. F.


    Most geologic processes should not fractionate Nb from Ta but Earth's major silicate reservoirs have subchondritic Nb/Ta values. Nb/Ta of >10000 basalts and basaltic andesites from different tectonic settings (GEOROC) cluster around 16, indistinguishable from upper mantle values. In contrast, Nb/Ta in more evolved arc volcanics have progressively lower values, reaching continental crust estimates, and correlate negatively with SiO2 (see figure) and positively with TiO2 and MgO. This global trend suggests that differentiation processes in magmatic arcs could explain bulk crustal Nb/Ta estimates. Understanding processes that govern fractionation of Nb from Ta in arcs can provide key insights on continental crust formation and help identify Earth's `missing' Nb reservoir. Ti-rich phases (rutile, titanite and ilmenite) have DNb/DTa values in the evolved liquid. Lack of correlation between Nb/Ta and K2O in global volcanic rocks implies that biotite plays a minor role in fractionating Nb from Ta during differentiation. Experimental petrology and evidence from exposed arc sections indicate that amphibole fractionation and delamination of island arc roots can explain the andesitic composition of bulk continental crust. Experimental studies have shown that amphibole Mg# correlate with DNb/DTa and amphibole could effectively fractionate Nb from Ta. Preliminary data from lower to middle crustal amphiboles from preserved arcs show sub- to super-chondritic Nb/Ta up to >60. This suggests that delamination of amphibole-rich cumulates can be a viable mechanism for the preferential removal of Nb from the continental crust. Future examination of Nb/Ta ratios in lower crustal amphiboles from various preserved arcs will provide improved constraints on the Nb-Ta paradox of the silicate Earth.

  6. The isotopic and chemical evolution of Mount St. Helens (United States)

    Halliday, A.N.; Fallick, A.E.; Dickin, A.P.; Mackenzie, A.B.; Stephens, W.E.; Hildreth, W.


    Isotopic and major and trace element analysis of nine samples of eruptive products spanning the history of the Mt. St. Helens volcano suggest three different episodes; (1) 40,000-2500 years ago: eruptions of dacite with ??{lunate}Nd = +5, ??{lunate}Sr = -10, variable ??18O, 206Pb/204Pb ??? 18.76, Ca/Sr ??? 60, Rb/Ba ??? 0.1, La/Yb ??? 18, (2) 2500-1000 years ago: eruptions of basalt, andesite and dacite with ??{lunate}Nd = +4 to +8, ??{lunate}Sr = -7 to -22, variable ??18O (thought to represent melting of differing mantle-crust reservoirs), 206Pb/204Pb = 18.81-18.87, variable Ca/Sr, Rb/Ba, La/Yb and high Zr, (3) 1000 years ago to present day: eruptions of andesite and dacite with ??{lunate}Nd = +6, ??{lunate}Sr = -13, ??18O ???6???, variable 206Pb/204Pb, Ca/Sr ??? 77, Rb/Ba = 0.1, La/Yb ??? 11. None of the products exhibit Eu anomalies and all are LREE enriched. There is a strong correlation between 87Sr/86Sr and differentiation indices. These data are interpreted in terms of a mantle heat source melting young crust bearing zircon and garnet, but not feldspar, followed by intrusion of this crustal reservoir by mantle-derived magma which caused further crustal melting and contaminated the crustal magma system with mafic components. Since 1000 years ago all the eruptions have been from the same reservoir which has displayed a much more gradual re-equilibration of Pb isotopic compositions than other components suggesting that Pb is being transported via a fluid phase. The Nd and Sr isotopic compositions lie along the mantle array and suggest that the mantle underneath Mt. St. Helens is not as depleted as MORB sources. There is no indication of seawater involvement in the source region. ?? 1983.

  7. Behaviour of major, minor and trace elements (including REEs during kaolinization processes at Zonouz deposit, northeast of Marand, East Azarbaidjan province

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    Vahideh Alipour


    Full Text Available The Zonouz kaolin deposit is located ~15 km northeast of Marand, East-Azarbaidjan province. Based on physical features in field investigations, such as color, five distinct kaolin types including (1 white, (2 lemon, (3 gray, (4 brown, and (5 yellow are distinguished in the deposit. Field evidence and petrographic studies indicate that the deposit is genetically close to trachy-andesite rocks. According to mineralogical data, the deposit contains quartz, kaolinite, montmorillonite, calcite, pyrophyllite, chlorite, muscovite-illite, dolomite, hematite, and anatase minerals. Geochemical data indicate that function of alteration processes on trachy-andesite rocks during development of Zonouz ore deposit was accompanied by leaching of elements such as Al, Na, K, Rb, Ba, V, Hf, Cu, Zr, Tm, Yb, and Lu, enrichment of elements such as U, Nb, and Ta, and leaching-fixation of elements such as Si, Fe, Ca, Mg, Ti, Mn, P, Cs, Sr, Th, Co, Cr, Ni, Y, Ga, LREE, Tb, Dy, Ho, and Er. Incorporation of obtained results from mineralogical and geochemical studies show that physico-chemical conditions of alteration environment, the relative stability of primary minerals, surface adsorption, preferential sorption by metallic oxides, existing of organic matters, scavenging and concentration processes, and fixation in neomorphic mineralogical phases played important role in distribution of elements in the deposit. Geochemical studies show that development of the deposit is relative to two types of processes, (1 hypogene and (2 supergene. The distribution pattern of REEs indicates that differentiation degree of LREEs from HREEs in supergene kaolins is more than hypogene kaolins. Geochemical studies indicate that minerals such as Mn-oxides, zircon, anatase, hematite, cerianite, and secondary phosphates (monazite, rhabdophane, churchite, and zenotime are the potential hosts for rare earth elements in this deposit.

  8. The final pulse of the Early Cenozoic adakitic activity in the Eastern Pontides Orogenic Belt (NE Turkey): An integrated study on the nature of transition from adakitic to non-adakitic magmatism in a slab window setting (United States)

    Eyuboglu, Yener; Dudas, Francis O.; Santosh, M.; Eroğlu-Gümrük, Tuğba; Akbulut, Kübra; Yi, Keewook; Chatterjee, Nilanjan


    The Eastern Pontides Orogenic Belt, one of the best examples of a fossil continental arc in the Alpine-Himalayan system, is characterized by adakitic magmatism during the Early Cenozoic. Popular models correlate the adakitic magmatism to syn- or post-collisional processes occurring after the collision between the Eastern Pontides Orogenic Belt and the Tauride Platform at the end of Late Mesozoic and/or beginning of the Cenozoic. We present new geological, petrological and chronological data from andesites and felsic tuffs exposed in the Bayburt area, in the southern part of the Eastern Pontides Orogenic Belt, and discuss the nature of the transition from adakitic to non-adakitic activities in a continental arc. Major, trace and rare earth element concentrations of both andesites and felsic tuffs clearly suggest that they are related to arc magmatism in a continental arc with adakitic composition. The isotopic compositions are permissive of mixing between a component similar to depleted mantle and a second component that is either mafic lower crust or subducted oceanic crust. 39Ar/40Ar hornblende and U/Pb zircon dating indicate that this adakitic magmatism in the Bayburt area ended by about 47 Ma, and transformed into non-adakitic, granitoid arc magmatism in the area immediately north of Bayburt in the Lutetian (∼46 Ma). Based on our new results in conjunction with available data, we propose that the beginning of northward rollback of a south-directed subducting slab, and simultaneous opening of a slab window related to ridge subduction, triggered both adakitic magmatism for approximately a 10 Myr period between 57.6 and 47 Ma and arc-parallel extension that caused the opening of the Early Cenozoic sedimentary basins. We also suggest that the shallow marine environment, in which Nummulite-bearing sandy limestones accumulated in the Early Cenozoic, was transformed into a saline-lake environment during the pyroclastic activity that produced the studied felsic tuffs

  9. Ciclos tectónicos, volcánicos y sedimentarios del Cenozoico del sur de Mendoza-Argentina (35°-37°S y 69°30'W Cenozoic tectonic, volcanic and sedimentary cycles in southern Mendoza Province, Argentina (35°-37°S y 69°30'W

    Directory of Open Access Journals (Sweden)

    Ana María Combina


    Full Text Available En este trabajo se describe la estratigrafía sedimentaria y volcánica asociada a los procesos de deformación de las unidades con edades del Cretácico Tardío al Plioceno Tardío aflorantes en el sur de Mendoza, Argentina, entre los ríos Atuel y Barrancas en el ámbito de la Cordillera Principal. Se proponen tres ciclos tectovolcano-sedimentarios, limitados por discordancias regionales generadas por la acción de las Fases Incaica, Quechua, Pehuenche y Diaguita. El primer ciclo comprende las unidades volcánicas y sedimentarias del Cretácico Superior hasta el Oligoceno Superior (Formaciones Roca y Pircala-Coihueco y el Ciclo Eruptivo Molle. El segundo abarca desde el Oligoceno Tardío al Mioceno Tardío (Formación Agua de la Piedra y las Andesitas Huincán. Por último, el tercer ciclo comprende desde el Mioceno Tardío al Plioceno (Formaciones Butaló, Pincheiras, Loma Fiera, Río Diamante y las Andesitas La Brea.This article describes the volcanic and sedimentary stratigraphy and their associated proces-ses with the Andean deformation during the Late Cretaceous to Late Pliocene. The studied área is located between the Atuel and Barrancas rivers and the Main Cordillera, in southern Mendoza, Argentina. Three tectovolcano-sedimentary cycles limited by regional discordances (Inca, Quechua, Pehuenche and Diaguita are proposed. The first comprises Upper Oligocene to Upper Miocene volcanic and sedimentary units (Roca and Pircala-Coihueco formations and the Volcanic Cycle Molle. The second extends from the Late Oligocene to Late Miocene (Agua de la Piedra Formation and the Huincán Andesites volcanic cycle. Finally, the third cycle ranges from the Late Miocene to Pliocene (Butaló, Pincheiras, Loma Fiera and Rio Diamante formations and La Brea Andesites.

  10. The study of hydrothermal alteration zones in Kahang exploration area (north eastern of Isfahan, central of Iran) using microscopy studies and TM and Aster satellite data (United States)

    Zahra Afshooni, Seyedeh; Esmaeily, Dariush


    Kahang ore deposit located in 73 km to the northeast of Isfahan city and 10 km to the east of Zefreh town, covering an area about 18.6 km2. This ore deposit is a part of Uromieh-Dokhtar volcanopolotonic belt. The rocks of the area included Andesite, Porphyritic Andesite, Dacite, Porphyritic, Rhyodacite, Diorite, Quartz Monzonite and Porphyry Micro Granite. In plutons, there is a trend from basic to acid features along with decreasing of age from margin to center of massive. Kahang region is an alteration and breccia zone. The occurrence of alteration zones and iron oxides were confirmed by satellite images processing. Generally, more than 90% of rocks of this region have been affected by hydrothermal fluids. Remote sensing refers to detection and measurement from a distance. For the first time, this exploration area was studied using satellite images processing (TM) and primary results showed that is suitable place for resources of Copper (Cu) and Molybdenum (Mo). Hydrothermal alteration commonly occurs in geothermal areas in association with ore deposits producing alteration assemblages typically dominated by silicates, sulfides, sulfates and carbonates. In the alteration zones studies the subject discussed is the study of existing minerals in such zones and study of chemical specifications of altering fluids. Four alteration zones Based on observations derived from the study of thin sections, XRD analysis and deep remote sensing using TM and Aster satellite images studies could be identified in this area: propylitic alteration zone with chlorite, epidot, calcite; argillic alteration zone with clay minerals; phyllic (qartz-sericite) alteration zone with quartz, sericite and pyrite and silicic alteration zone with abundant quartz.

  11. Karakteristik mineralisasi epitermal di Daerah Taran, Hulu Kahayan, Kalimantan Tengah berdasarkan studi mikroskopis, X-Ray Diffraction (XRD, dan inklusi fluida

    Directory of Open Access Journals (Sweden)

    Danny Zulkifli Herman


    Full Text Available area is occupied predominantly by piroclastic rocks and locally intercalations of lenticular claystones and sandstones. The pyroclastic rocks are intruded by diorite, dacite and andesite, leading alteration and mineralization within the host rocks. Mineralization occurs as a vein type and is associated with a number of pervasive alteration types named respectively: quartz-illite- montmorillonite-kaolinite ± pyrite, quartz-illite ± pyrite, quartz-illite-chlorite ± pyrite and quartz- kaolinite-illite ± pyrite. On the other hand, a propylitic alteration also occurs within the andesite intrusion composed of calcite-epidote-chlorite-sericite-quartz ± pyrite. The mineralization is characterized by several zones of quartz stockwork containing gold and associated ore minerals of chalcopyrite, sphalerite, galena, pyrite and argentite. The quartz veins occurs as fi llings of structural openings in the form of milky quartz and amethyst with textures of sugary, comb, and dogteeth. Evaluation work on results of microscopic (petrography and mineragraphy, X-Ray Diffraction (XRD, and fl uid inclusion studies, and chemical analysis of entirely altered rock/quartz vein samples shows that the alteration and mineralization process were closely related to a change of hydrothermal fl uids, from near neutral into acid conditions at a temperature range of >290o – 100oC. The appearances of quartz variation indicate a relationship with repeated episodes of boiling in an epithermal system, as ground water mixed with hot vapor originated from a remained post-magmatic solution. Corresponding to a salinity of average 1,388 equiv.wt.% NaCl, it indicates that the ore minerals bearing quartz veins were deposited at a depth range of 640 – 1020 m beneath paleosurface.  

  12. The graphite deposit at Borrowdale (UK): A catastrophic mineralizing event associated with Ordovician magmatism (United States)

    Ortega, L.; Millward, D.; Luque, F. J.; Barrenechea, J. F.; Beyssac, O.; Huizenga, J.-M.; Rodas, M.; Clarke, S. M.


    The volcanic-hosted graphite deposit at Borrowdale in Cumbria, UK, was formed through precipitation from C-O-H fluids. The δ 13C data indicate that carbon was incorporated into the mineralizing fluids by assimilation of carbonaceous metapelites of the Skiddaw Group by andesite magmas of the Borrowdale Volcanic Group. The graphite mineralization occurred as the fluids migrated upwards through normal conjugate fractures forming the main subvertical pipe-like bodies. The mineralizing fluids evolved from CO 2-CH 4-H 2O mixtures (XCO 2 = 0.6-0.8) to CH 4-H 2O mixtures. Coevally with graphite deposition, the andesite and dioritic wall rocks adjacent to the veins were intensely hydrothermally altered to a propylitic assemblage. The initial graphite precipitation was probably triggered by the earliest hydration reactions in the volcanic host rocks. During the main mineralization stage, graphite precipitated along the pipe-like bodies due to CO 2 → C + O 2. This agrees with the isotopic data which indicate that the first graphite morphologies crystallizing from the fluid (cryptocrystalline aggregates) are isotopically lighter than those crystallizing later (flakes). Late chlorite-graphite veins were formed from CH 4-enriched fluids following the reaction CH 4 + O 2 → C + 2H 2O, producing the successive precipitation of isotopically lighter graphite morphologies. Thus, as mineralization proceeded, water-generating reactions were involved in graphite precipitation, further favouring the propylitic alteration. The structural features of the pipe-like mineralized bodies as well as the isotopic homogeneity of graphite suggest that the mineralization occurred in a very short period of time.

  13. Geology, alteration, mineralization and geochemical study in Kalateh Taimour area, NE Iran

    Directory of Open Access Journals (Sweden)

    Zahra Alaminia


    Full Text Available The area is located 20 km northwest of Kashmar and about 4 km of Kalateh Taimour in Khorasan Razavi province. The study area is part of Tertiary volcanic-plutonic belt north of Daruneh fault and its situation in tectonic inliers between two important active faults, Doruneh and Taknar. Volcanic rocks are mainly intermediate to acid pyroclastic type. They formed during early Tertiary. The volcanic rocks of the Kalateh Taimour area are predominantly andesitic basalt, andesite, latite, trachyte, dacite and rhyodacite and are observed as lava, tuff, lapilli tuff and agglomerate. Field evidences and study show several subvolcanic bodies including quartz hornblende biotite monzodiorite porphyry, quartz biotite monzodiorite porphyry, quartz diorite porphyry and microdiorite which are intruded sometime in mid-Tertiary. In this belt, new methods of image processing were used for enhancing the alteration zones to help near infra red and short wavelength infrared and bands example band ratios and principle component method. Propylitic, sericitic and argillic are the main alteration types. Minor silicification is found in some areas. Alteration is extent but mineralization is limited. Mineralization is mainly controlled by fault system. Several mineralized faults are being discovered. Open space filling features are abundant. In the study area, disseminate and stock work mineralization are abundant. The amount of sulfide minerals is very small. Ancient mining is present in the area. Stream sediment geochemical study shows a very broad and high level of gold anomaly. Rock geochemical study show very high levels of Au, Ag, Cu, Pb, Zn and Au value is correlative to Cu, Pb, Zn and Ag values. Due to alteration modeling, non uniformity in mineralization and low abundance of sulfide mineralization suggest study in low sulphidation Au-Cu deposit.

  14. The rise and fall of periodic 'drumbeat' seismicity at Tungurahua volcano, Ecuador (United States)

    Bell, Andrew F.; Hernandez, Stephen; Gaunt, H. Elizabeth; Mothes, Patricia; Ruiz, Mario; Sierra, Daniel; Aguaiza, Santiago


    Highly periodic 'drumbeat' long period (LP) earthquakes have been described from several andesitic and dacitic volcanoes, commonly accompanying incremental ascent and effusion of viscous magma. However, the processes controlling the occurrence and characteristics of drumbeat, and LP earthquakes more generally, remain contested. Here we use new quantitative tools to describe the emergence, evolution, and degradation of drumbeat LP seismicity at the andesitic Tungurahua volcano, Ecuador, in April 2015. The signals were recorded during an episode of minor explosive activity and ash emission, without lava effusion, and are the first to be reported at Tungurahua during the ongoing 17 yrs of eruption. Following four days of high levels of continuous and 'pulsed' tremor, highly-periodic LP earthquakes first appear on 10 April. Over the next four days, inter-event times and event amplitudes evolve through a series of step-wise transitions between stable behaviors, each involving a decrease in the degree of periodicity. Families of similar waveforms persist before, during, and after drumbeat activity, but the activity levels of different families change coincidentally with transitions in event rate, amplitude, and periodicity. A complex micro-seismicity 'initiation' sequence shows pulse-like and stepwise changes in inter-event times and amplitudes in the hours preceding the onset of drumbeat activity that indicate a partial de-coupling between event size and rate. The observations increase the phenomenology of drumbeat LP earthquakes, and suggest that at Tungurahua they result from gas flux and rapid depressurization controlled by shear failure of the margins of the ascending magma column.

  15. Study on weathering index for improving the reliability of terrace correlation and chronology. Part 2. Understanding weathering condition of terrace gravel and induction of application requirement for correlation index

    International Nuclear Information System (INIS)

    Hamada, Takaomi


    Geomorphographic survey of fluvial terraces, geological exploration, borehole drilling and investigation, and analysis of weathering condition of terrace gravels were carried out in Chuetsu area, Niigata prefecture, where a great deal of geomorphostratigraphic and tephrostratigraphic data are available. The results of these surveys and investigations indicate that weathering degree of terrace gravels can be considered as an index of the terrace age, and also provide points to remember for sampling and method of sampling and observation. The effective porosity and the thickness of weathering rind of gravels, which are indexes for weathering degree evaluation, in boring core, increase above the depth of about 5m from the top of the hole. Weathering doesn't reach the deep portion, therefore, investigation and evaluation for the weathering degree of terrace gravels must be carried out on the upper portion. Weathering rind thickness and effective porosity of the gravels are dispersive. Dispersion of the weathering rind thickness can be reduced by confining to andesite, and dispersion of the effective porosity can be reduced by limiting range of gravel size. Reducing dispersion, increase trend with age becomes clear in change of the weathering rind thickness and the effective porosity in many of the studied area. It shows that weathering rind thickness and effective porosity are effective for terrace correlation. Dispersion of data in an outcrop isn't small, but data from neighboring terraces with the same age are not different each other. It indicates that weathering rind thickness and effective porosity can be quantitative indexes for terrace age evaluation. In area where weathering rind is effective for terrace correlation, the rate of the weathering rind formation of andesite gravels is about 0.04mm/1000 years. Therefore, MIS6 terraces and MIS8 terraces can be distinguished each other by means of thickness of the weathering rind. This formation rate falls inside the

  16. Late Triassic porphyritic intrusions and associated volcanic rocks from the Shangri-La region, Yidun terrane, Eastern Tibetan Plateau: Adakitic magmatism and porphyry copper mineralization (United States)

    Wang, Bai-Qiu; Zhou, Mei-Fu; Li, Jian-Wei; Yan, Dan-Ping


    Early Mesozoic porphyritic intrusions in the Shangri-La region, southern Yidun terrane, SW China, are spatially associated with andesites and dacites. These intrusions are composed of diorite and quartz diorite, and are closely related to copper mineralization. LA-ICP-MS zircon U-Pb ages of the intrusions range from 230 to 215 Ma. The associated andesites and dacites are interlayered with slates and sandstones and have ages of around 220 Ma. All of the intrusive and extrusive rocks have similar, highly fractionated REE patterns and high La/Yb (13-49) ratios with no prominent Eu anomalies. They display pronounced negative Nb-Ta and Ti anomalies on primitive mantle-normalized spidergrams. Their SiO2 contents range from 56.6 to 67.1 wt.%, Al2O3 from 14.2 to 17.4 wt.% and MgO from1.9 to 4.2 wt.%. All the rocks have high Sr (258-1980 ppm), and low Y (13-21 ppm) with high Sr/Y ratios (29-102). These features suggest that both the volcanic rocks and porphyritic intrusions were derived from adakitic magmas. They have similar initial 87Sr/86Sr ratios (0.7058 to 0.7077) and εNd (- 1.88 to - 4.93) values, but belong to high silica (HSA) and low silica adakitic rocks (LSA). The HSA represent an early stage of magmatism (230 to 215 Ma) and were derived from oceanic slab melts with limited interaction with the overlying mantle wedge during ascent. At 215 Ma, more extensive interaction produced the LSA. We propose that the early adakitic magmas (HSA) formed by flat subduction leading to melting of oceanic slab, whereas subsequent slab break-off caused the significant interaction between slab melts and the mantle wedge and thus the generation of the later adakitic magmas (LSA).

  17. The plinian eruptions of 1912 at Novarupta, Katmai National Park, Alaska (United States)

    Fierstein, J.; Hildreth, W.


    The three-day eruption at Novarupta in 1912 consisted of three discrete episodes. Episode I began with plinian dispersal of rhyolitic fallout (Layer A) and contemporaneous emplacement of rhyolitic ignimbrites and associated proximal veneers. The plinian column was sustained throughout most of the interval of ash flow generation, in spite of progressive increases in the proportions of dacitic and andesitic ejecta at the expense of rhyolite. Accordingly, plinian Layer B, which fell in unbroken continuity with purely rhyolitic Layer A, is zoned from >99% to ???15% rhyolite and accumulated synchronously with emplacement of the correspondingly zoned ash flow sequence in Mageik Creek and the Valley of Ten Thousand Smokes (VTTS). Only the andesiterichest flow units that cap the flow sequence lack a widespread fallout equivalent, indicating that ignimbrite emplacement barely outlasted the plinian phase. On near-vent ridges, the passing ash flows left proximal ignimbrite veneers that share the compositional zonation of their valley-filling equivalents but exhibit evidence for turbulent deposition and recurrent scour. Episode II began after a break of a few hours and was dominated by plinian dispersal of dacitic Layers C and D, punctuated by minor proximal intraplinian flows and surges. After another break, dacitic Layers F and G resulted from a third plinian episode (III); intercalated with these proximally are thin intraplinian ignimbrites and several andesite-rich fall/flow layers. Both CD and FG were ejected from an inner vent much as 0.4 km3 of rhyolitic glass shards from eruptive Episode I fell with CDE and 1.1 km3 with FGH. Most of the rhyolitic ash in the dacitic fallout layers fell far downwind (SE of the vent); near the rhyolite-dominated ignimbrite, however, nearly all of Layers E and H are dacitic, showing that the downwind rhyolitic ash is of 'co-plinian' rather than co-ignimbrite origin. ?? 1992 Springer-Verlag.

  18. Interpretasi Vulkanostratigrafi Daerah Mamuju Berdasarkan Analisis Citra Landsat-8

    Directory of Open Access Journals (Sweden)

    Frederikus Dian Indrastomo


    Full Text Available Mamuju and its surrounding area are constructed mainly by volcanic rocks. Volcanoclastic sedimentary rocks and limestones are laid above the volcanic rocks. Volcanic activities create some unique morphologies such as craters, lava domes, and pyroclastic flow paths as their volcanic products. These products are identified from their circular features characters on Landsat-8 imagery. After geometric and atmospheric corrections had been done, a visual interpretation on Landsat-8 imagery was conducted to identify structure, geomorphology, and geological condition of the area. Regional geological structures show trend to southeast – northwest direction which is affects the formation of Adang volcano. Geomorphology of the area are classified into 16 geomorphology units based on their genetic aspects, i.e Sumare fault block ridge, Mamuju cuesta ridge, Adang eruption crater, Labuhan Ranau eruption crater, Sumare eruption crater, Ampalas volcanic cone, Adang lava dome, Labuhan Ranau intrusion hill, Adang pyroclastic flow ridge, Sumare pyroclastic flow ridge, Adang volcanic remnant hills, Malunda volcanic remnant hills, Talaya volcanic remnant hills, Tapalang karst hills, Mamuju alluvium plains, and Karampuang reef terrace plains. Based on the Landsat-8 imagery interpretation result and field confirmation, the geology of Mamuju area is divided into volcanic rocks and sedimentary rocks. There are two groups of volcanic rocks; Talaya complex and Mamuju complex. The Talaya complex consists of Mambi, Malunda, and Kalukku volcanic rocks with andesitic composition, while Mamuju complex consist of Botteng, Ahu, Tapalang, Adang, Ampalas, Sumare, danLabuhanRanau volcanic rocks with andesite to leucitic basalt composition. The volcanostratigraphy of Mamuju area was constructed based on its structure, geomorphology and lithology distribution analysis. Volcanostratigraphy of Mamuju area is classified into Khuluk Talaya and Khuluk Mamuju. The Khuluk Talaya consists

  19. Sr and Nd isotope geochemistry and tectonics during subduction and rifting in Sierra Santa Ursula, Sonora, Northwestern Mexico

    International Nuclear Information System (INIS)

    Mora-Klepeis, G.


    The western margin of North America was affected by a convergent plate boundary from the Cretaceous through the Early Tertiary. Volcanic rocks produced by subduction-related arc magmatism in northwestern Mexico are concentrated in two northwest-trending belts subparallel to the continental margin. One of these is the Sierra Madre Occidental, where mid-Tertiary magmatism consisted mostly of calc-alkaline rhyolitic ignimbrite and minor andesite produced between ∼ 46 and 28 Ma (McDowell et al., 1990). The second (younger) northwest-trending belt is located along the eastern margin of the Baja California Peninsula and in the Gulf of California region of mainland Mexico. This belt is composed mostly of andesite, but includes some basalt and dacite whose ages range from about 24 to 11 Ma (Hausback, 1984). A transition to rifting began after a mid-Tertiary cessation of subduction, eventually creating the Gulf of California extensional province. Four markedly different magma types comprising mainly tholeiitic and alkalic rocks and minor calc-alkaline and peralkaline rocks were erupted throughout the last 13 Ma and record the history of rifting of the Gulf of California (Sawlan, 1991). The aim of the present paper is to distinguish the nature of the 24-8.5 Ma magmatism emplaced on the eastern side of the Gulf of California in the state of Sonora, by the use of stratigraphic, geochemical and isotopic data. Preliminary Sr and Nd results show that three groups of magmas are present in the area suggesting a heterogeneous source. This can be interpreted as the result of magmas being erupted at different stages of subduction and rifting during the tectonic evolution of this part on North America

  20. The Quaternary history of effusive volcanism of the Nevado de Toluca area, Central Mexico (United States)

    Torres-Orozco, R.; Arce, J. L.; Layer, P. W.; Benowitz, J. A.


    Andesite and dacite lava flows and domes, and intermediate-mafic cones from the Nevado de Toluca area were classified into five groups using field data and 40Ar/39Ar geochronology constraints. Thirty-four lava units of diverse mineralogy and whole-rock major-element geochemistry, distributed between the groups, were identified. These effusive products were produced between ∼1.5 and ∼0.05 Ma, indicating a mid-Pleistocene older-age for Nevado de Toluca volcano, coexisting with explosive products that suggest a complex history for this volcano. A ∼0.96 Ma pyroclastic deposit attests for the co-existence of effusive and explosive episodes in the mid-Pleistocene history. Nevado de Toluca initiated as a composite volcano with multiple vents until ∼1.0 Ma, when the activity began to centralize in an area close to the present-day crater. The modern main edifice reached its maximum height at ca. 50 ka after bulky, spiny domes erupted in the current summit of the crater. Distribution and geochemical behavior in major elements of lavas indicate a co-magmatic relationship between different andesite and dacite domes and flows, although unrelated to the magmatism of the monogenetic volcanism. Mafic-intermediate magma likely replenished the system at Nevado de Toluca since ca. ∼1.0 Ma and contributed to the eruption of new domes, cones, as well as effusive-explosive activity. Altogether, field and laboratory data suggest that a large volume of magma was ejected around 1 Ma in and around the Nevado de Toluca.

  1. Using noble gases and 87Sr/86Sr to constrain heat sources and fluid evolution at the Los Azufres Geothermal Field, Mexico (United States)

    Wen, T.; Pinti, D. L.; Castro, M. C.; Lopez Hernandez, A.; Hall, C. M.; Shouakar-Stash, O.; Sandoval-Medina, F.


    Geothermal wells and hot springs were sampled for noble gases' volume fraction and isotopic measurements and 87Sr/86Sr in the Los Azufres Geothermal Field (LAGF), Mexico, to understand the evolution of fluid circulation following three decades of exploitation and re-injection of used brines. The LAGF, divided into the Southern Production Zone (SPZ) and the Northern Production Zone (NPZ), is hosted in a Miocene to Pliocene andesitic volcanic complex covered by Quaternary rhyolitic-dacitic units. Air contamination corrected 3He/4He ratios (Rc) normalized to the atmospheric ratio (Ra=1.384 x 10-6), show a median value of 6.58 indicating a dominant mantle helium component. Contributions of crustal helium up to 53% and 18% are observed in NPZ and SPZ, respectively. Observations based on Rc/Ra and 87Sr/86Sr ratios points to the mixing of three magmatic sources supplying mantle helium to the LAGF: (1) a pure mantle He (Rc/Ra = 8) and Sr (87Sr/86Sr = 0.7035) source; (2) a pure mantle helium (Rc/Ra = 8) with some radiogenic Sr (87Sr/86Sr = 0.7049) source possibly resulting from Quaternary rhyolitic volcanism; and (3) a fossil mantle He component (Rc/Ra = 3.8) with some radiogenic Sr (87Sr/86Sr = 0.7038), corresponding possibly to the Miocene andesite reservoir. Intrusions within the last 50 kyrs from sources (1) and (2) are likely responsible for the addition of mantle volatiles and heat to the hydrothermal system of Los Azufres. He and Ar isotopes indicate that heat flow is transported by both convection and conduction. Atmospheric noble gas elemental ratios suggest that geothermal wells located closer to the western re-injection zone are beginning to be dominated by re-injection of used brines (injectate). The area affected by boiling in LAGF has further extended to the north and west since the last noble gas sampling campaign in 2009.

  2. Geomorphology and petrography of the Angeles lava flow and the Monte de la Cruz cinder cone, Barva Volcano, Costa Rica

    International Nuclear Information System (INIS)

    Rojas, Vanessa; Barahona, Dione; Alvarado, Guillermo E


    A geomorphological and pretrographic study was carried out at the lava flow Angeles and the Monte de la Cruz cone in the foothills of the Volcan Barva in Costa Rica. The 1967 aerial photographs at scale 1: 17,000 and 1: 13,000, 1992 at scale 1: 60,000 and TERRA 1997 at scale 1: 40,000 were used for the photogeological study, supplemented with the analysis of the eastern sector of the Hoja Topografica Barva (1: 50 000) of the Instituto Geografico Nacional (IGN) and other topographic maps at different scales (1: 25 000 and 1: 10 000), in addition to the digital elevation models developed through Sistemas de Informacion Geografica (SIG). The information extracted from the wells of the Sistema Nacional de Aguas Subterraneas, Riego y Avenamiento (SENARA) for underground control was reinterpreted. In the field work thicknesses were measured and an estimation of the volumes, dimensions of the cast and other associated geoforms was made. Likewise, 9 samples of rock were selected for the elaboration of thin sections and for their respective petrographic analysis, which allowed to define the main lava flow units and their possible flows. As a result of the volcanic activity of the cone, two flow units of the Angeles wash were identified, the Lower Angels unit and the Superior Angels unit. Petrographically, Angeles Inferior was reciprocated with an andesitic vesical basaltic lava with a porphyritic to slightly glomeroporphyric hypocrystalline texture, with plagioclase, clinopyroxene, orthopyroxene, olivine and opaque phenocrysts. On the other hand, Superior Angeles has been vesicular andesitic with a hypocrystalline texture, glomeroporfiritica to serial glomeroporfiritica, with plagioclase, clinopyroxene, orthopyroxene, olivine and opaque phenocrysts. Morphologically, kipukas and levees were observed. Regionally, it was observed that the Monte de la Cruz cone, along with other smaller satellite cones, are aligned N19 O W along 8.5 km, evidencing an origin associated with a

  3. Seismogenic frictional melting in the magmatic column as the driving force of stick-slip motion (United States)

    Kendrick, J. E.; Lavallee, Y.; Hirose, T.; Di Toro, G.; Hornby, A.; De Angelis, S.; Henton De Angelis, S.; Ferk, A.; Hess, K.; Leonhardt, R.; Dingwell, D. B.


    Lava dome eruptions subjected to high extrusion rates commonly evolve from endogenous to exogenous growth and limits to their structural stability hold catastrophic potential as explosive eruption triggers. In the conduit strain localisation in magma, accompanied by seismogenic failure, marks the onset of brittle magma ascent dynamics. The rock record of exogenous dome structures preserves vestiges of cataclastic processes and of thermal anomalies, key to unravelling subsurface processes. A combined structural, thermal and magnetic investigation of shear bands from Mount St. Helens (MSH) and Soufrière Hills volcano (SHV) reveal evidence of faulting and frictional melting within the magmatic column. High velocity rotary shear (HVR) experiments demonstrate the propensity for melting of andesitic and dacitic material (from SHV and MSH respectively) at upper conduit stress conditions. Such melting events may be linked to the step-wise extrusion of magma accompanied by repetitive long-period (LP) seismicity. Using a source duration calculated from the waveforms at seismic stations around SHV, and slip distance per drumbeat calculated from extrusion rate, frictional melting of SHV andesite in a high velocity rotary shear apparatus can be achieved at small slip distances (HVR experiments which mimic rapid velocity fluctuations in stick-slip behavior demonstrate velocity-weakening behavior of melt, with a tendency for unstable slip. We postulate that pseudotachylyte generation could be the underlying cause of stick-slip motion and associated seismic 'drumbeats', which are so commonly observed at dome-building volcanoes, allowing for a fixed spatial locus and the occurrence of 'families' of similar seismic events. We conclude that, given the ease with which melting is achieved in volcanic rocks, and considering the high ambient temperatures in volcanic conduits, frictional melting is a highly probable consequence of viscous magma ascent.

  4. Origin of silicic magmas along the Central American volcanic front: Genetic relationship to mafic melts (United States)

    Vogel, Thomas A.; Patino, Lina C.; Eaton, Jonathon K.; Valley, John W.; Rose, William I.; Alvarado, Guillermo E.; Viray, Ela L.


    Silicic pyroclastic flows and related deposits are abundant along the Central American volcanic front. These silicic magmas erupted through both the non-continental Chorotega block to the southeast and the Paleozoic continental Chortis block to the northwest. The along-arc variations of the silicic deposits with respect to diagnostic trace element ratios (Ba/La, U/Th, Ce/Pb), oxygen isotopes, Nd and Sr isotope ratios mimic the along-arc variation in the basaltic and andesitic lavas. This variation in the lavas has been interpreted to indicate relative contributions from the slab and asthenosphere to the basaltic magmas [Carr, M.J., Feigenson, M.D., Bennett, E.A., 1990. Incompatible element and isotopic evidence for tectonic control of source mixing and melt extraction along the Central American arc. Contributions to Mineralogy and Petrology, 105, 369-380.; Patino, L.C., Carr, M.J. and Feigenson, M.D., 2000. Local and regional variations in Central American arc lavas controlled by variations in subducted sediment input. Contributions to Mineralogy and Petrology, 138 (3), 265-283.]. With respect to along-arc trends in basaltic lavas the largest contribution of slab fluids is in Nicaragua and the smallest input from the slab is in central Costa Rica — similar trends are observed in the silicic pyroclastic deposits. Data from melting experiments of primitive basalts and basaltic andesites demonstrate that it is difficult to produce high K 2O/Na 2O silicic magmas by fractional crystallization or partial melting of low-K 2O/Na 2O sources. However fractional crystallization or partial melting of medium- to high-K basalts can produce these silicic magmas. We interpret that the high-silica magmas associated Central America volcanic front are partial melts of penecontemporaneous, mantle-derived, evolved magmas that have ponded and crystallized in the mid-crust — or are melts extracted from these nearly completely crystallized magmas.

  5. The Valle de Bravo Volcanic Field. A monogenetic field in the central front of the Mexican Volcanic Belt (United States)

    Aguirre-Diaz, G. J.; Jaimes-Viera, M. D.; Nieto-Obreg¢n, J.; Lozano-Santacruz, R.


    The Valle de Bravo volcanic field, VBVF, is located in the central-southern front of the Mexican Volcanic Belt just to the southwest of Nevado de Toluca volcano. The VBVF covers 3,703 square Km and includes at least 122 cinder cones, 1 shield volcano, several domes, and the 2 volcanic complexes of Zitacuaro and Villa de Allende. Morphometric parameters calibrated with isotopic ages of the volcanic products indicate four groups or units for the VBVF, Pliocene domes and lava flows, undifferentiated Pleistocene lava flows,> 40 Ka cones and lavas, 40 to 25 Ka cones and lavas, 25 to 10 Ka cones and lavas, and < 10 Ka cones and lavas. Whole-rock chemistry shows that all products of the VBVF range from basaltic andesites to dacites. No basalts were found, in spite of many units are olivine-rich and large some with large weight percent contents of MgO, 1 to 9. There is the possibility that some or all of the olivines in some samples could be xenocrysts. Some andesites are high in Sr, 1000 to 1800 ppm, that correlates with relatively high values of Ba, Cr, Ni, Cu, CaO and MgO. Y and Nb have the typical low values for orogenic rocks. The only shield volcano of the VBVF has a base of 9 Km, and its composition is practically the average composition of the whole field. Stratigraphycally, it is one of the earlier events of the VBVF. Compared with other volcanic fields of the Mexican Volcanic Belt, it lacks basalts and alkalic rocks. All volcanism of this field is calcalkaline

  6. Geochemical Characterization of Late Pleistocene and Holocene Tephra Layers from the Basin of Mexico, Central Mexico (United States)

    Ortega-Guerrero, Beatriz; Newton, Anthony J.


    In order to aid palaeoenvironmental research of Late Pleistocene and Holocene deposits of central Mexico, tephra layers collected from the sediments of the Texcoco and Chalco sub-basins, in the southern part of the Basin of Mexico, are geochemically characterized and used as stratigraphic markers. The tephra layers range in composition from basaltic andesites to rhyolites and are calc-alkaline. The tephras range in age from >34,000 to ca. 2600 14C yr B.P. New names are used informally to designate correlated tephras. The Tlahuac tephra is present in Chalco, at a depth of 18 m; in the southeastern part of Texcoco, at a depth of around 10 m; and at the Tlapacoya archaeological site, where it had been mistakenly described as basaltic. This basalt-andesite tephra is dated to at least 34,000 14C yr B.P. The Tlapacoya 1 tephra is dated to between 15,020 ± 450 and 14,430 ± 190 yr B.P. and is present in all Chalco sections. The Tlapacoya 2 tephra corresponds to the previously described "pomez gruesa con fragmentos de andesita" (ca. 14,400 yr B.P.) and is present in all Chalco and Texcoco sections. The likely source of these three tephras is the volcano Popocatepetl. Tephra II at Chalco dates to 12,520 ± 135 yr B.P. and correlates with the Upper Toluca Pumice from Nevado de Toluca volcano. These represent the first geochemical glass-shard analysis of tephras from the Basin of Mexico, and so further research is necessary before a reliable tephrochronology can be established.

  7. Orthopyroxene-enrichment in the lherzolite-websterite xenolith suite from Paleogene alkali basalts of the Poiana Ruscă Mountains (Romania

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    Nédli Zsuzsanna


    Full Text Available In this paper we present the petrography and geochemistry of a recently collected lherzolite-websterite xenolith series and of clinopyroxene xenocrysts, hosted in Upper Cretaceous–Paleogene basanites of Poiana Ruscă (Romania, whose xenoliths show notable orthopyroxene-enrichment. In the series a slightly deformed porphyroclastic-equigranular textured series could represent the early mantle characteristics, and in many cases notable orthopyroxene growth and poikilitic texture formation was observed. The most abundant mantle lithology, Type A xenoliths have high Al and Na-contents but low mg# of the pyroxenes and low cr# of spinel suggesting a low degree (< 10 % of mafic melt removal. They are also generally poor in overall REE-s (rare earth elements and have flat REY (rare earth elements+ Y patterns with slight LREE-depletion. The geochemistry of the Type A xenoliths and calculated melt composition in equilibrium with the xenolith clinopyroxenes suggests that the percolating melt causing the poikilitization can be linked to a mafic, Al-Na-rich, volatile-poor melt and show similarity with the Late Cretaceous–Paleogene (66–72 Ma subduction-related andesitic magmatism of Poiana Ruscă. Type B xenoliths, with their slightly different chemistry, suggest that, after the ancient depletion, the mantle went through a slight metasomatic event. A subsequent passage of mafic melts in the mantle, with similar compositions to the older andesitic magmatism of Poiana Ruscă, is recorded in the pyroxenites (Fe-rich xenoliths, whereas the megacrysts seem to be cogenetic with the host basanite. The Poiana Ruscă xenoliths differ from the orthopyroxene-enriched mantle xenoliths described previously from the Carpathian-Pannonian Region and from the Dacia block.

  8. Volcano stratigraphy interpretation of Mamuju area based on Landsat-8 imagery analysis

    International Nuclear Information System (INIS)

    Frederikus Dian Indrastomo; I Gde Sukadana; Dhatu Kamajati; Asep Saepuloh; Agus Handoyo Harsolumakso


    Mamuju and its surrounding area are constructed mainly by volcanic rocks. Volcanoclastic sedimentary rocks and limestones are laid above the volcanic rocks. Volcanic activities create some unique morphologies such as craters, lava domes, and pyroclastic flow paths as their volcanic products. These products are identified from their circular features characters on Landsat-8 imagery. Geometric and atmospheric corrections had been done, a visual interpretation on Landsat-8 imagery was conducted to identify structure, geomorphology, and geological condition of the area. Regional geological structures show trend to southeast – northwest direction which is affects the formation of Adang volcano. Geomorphology of the area are classified into 16 geomorphology units based on their genetic aspects, i.e Sumare fault block ridge, Mamuju cuesta ridge, Adang eruption crater, Labuhan Ranau eruption crater, Sumare eruption crater, Ampalas volcanic cone, Adang lava dome, Labuhan Ranau intrusion hill, Adang pyroclastic flow ridge, Sumare pyroclastic flow ridge, Adang volcanic remnant hills, Malunda volcanic remnant hills, Talaya volcanic remnant hills, Tapalang karst hills, Mamuju alluvium plains, and Karampuang reef terrace plains. Based on the Landsat-8 imagery interpretation result and field confirmation, the geology of Mamuju area is divided into volcanic rocks and sedimentary rocks. There are two groups of volcanic rocks; Talaya complex and Mamuju complex. The Talaya complex consists of Mambi, Malunda, and Kalukku volcanic rocks with andesitic composition, while Mamuju complex consist of Botteng, Ahu, Tapalang, Adang, Ampalas, Sumare, and Labuhan Ranau volcanic rocks with andesite to leucitic basalt composition. The volcano stratigraphy of Mamuju area was constructed based on its structure, geomorphology and lithology distribution analysis. Volcano stratigraphy of Mamuju area is classified into Khuluk Talaya and Khuluk Mamuju. The Khuluk Talaya consists of Gumuk Mambi, Gumuk

  9. Forearc oceanic crust in the Izu-Bonin arc - new insights from active-source seismic survey - (United States)

    Kodaira, S.; Noguchi, N.; Takahashi, N.; Ishizuka, O.; Kaneda, Y.


    Petrological studies have suggested that oceanic crust is formed in forearc areas during the initial stage of subduction. However, there is little geophysical evidence for the formation of oceanic crust in those regions. In order to examine crustal formation process associated with a subduction initiation process, we conducted an active-source seismic survey at a forearc region in the Izu-Bonin intra-oceanic arc. The resultant seismic image shows a remarkably thin crust (less than 10 km) at the northern half of the Bonin ridge (at the north of the Chichi-jima) and abrupt thickening the crust (~ 20 km thick) toward the south (at the Haha-jima). Comparison of velocity-depth profiles of the thin forearc crust of the Bonin ridge with those of typical oceanic crusts showed them to be seismologically identical. The observed structural variation also well corresponds to magmatic activities along the forearc. Boninitic magmatism is evident in the area of thin crust and tholeiitic-calcalkaline andesitic volcanism in the area of thick crust. Based on high precision dating studies of those volcanic rocks, we interpreted that the oceanic-type thin crust associated with boninitic volcanism has been created soon after the initiation of subduction (45-48 Ma) and and that the nonoceanic thick crust was created by tholeiitic-calcalkaline andesitic magmatism after the boninitic magmatism was ceased. The above seismological evidences strongly support the idea of forearc oceanic crust (or phiolite) created by forearc spreading in the initial stage of subduction along the intra-oceanic arc.

  10. The 2003 phreatomagmatic eruptions of Anatahan volcano - Textural and petrologic features of deposits at an emergent island volcano (United States)

    Pallister, J.S.; Trusdell, F.A.; Brownfield, I.K.; Siems, D.F.; Budahn, J.R.; Sutley, S.F.


    Stratigraphic and field data are used in conjunction with textural and chemical evidence (including data from scanning electron microscope, electron microprobe, X-ray fluorescence, X-ray diffraction, and instrumental neutron activation analysis) to establish that the 2003 eruption of Anatahan volcano was mainly phreatomagmatic, dominated by explosive interaction of homogeneous composition low-viscosity crystal-poor andesite magma with water. The hydromagmatic mode of eruption contributed to the significant height of initial eruptive columns and to the excavation and eruption of altered rock debris from the sub-volcanic hydrothermal system. Volatile contents of glass inclusions in equilibrium phenocrysts less abundances of these constituents in matrix glass times the estimated mass of juvenile magma indicate minimum emissions of 19 kt SO2 and 13 kt Cl. This petrologic estimate of SO2 emission is an order-of-magnitude less than an estimate from TOMS. Similarly, inferred magma volumes from the petrologic data are an order of magnitude greater than those modeled from deformation data. Both discrepancies indicate additional sources of volatiles, likely derived from a separate fluid phase in the magma. The paucity of near-source volcanic-tectonic earthquakes preceding the eruption, and the dominance of sustained long-period tremor are attributed to the ease of ascent of the hot low-viscosity andesite, followed by a shallow phreatomagmatic mode of eruption. Phreatomagmatic eruptions are probably more common at emergent tropical island volcanoes, where shallow fresh-water lenses occur at near-sea-level vents. These relations suggest that phreatomagmatic explosions contributed to the formation of many of the near-sea-level craters and possibly even to the small calderas at the other Mariana islands.

  11. Geology, Petrography, Geochemistry and Radioactivity Studies on The Dyke Swarms of Gabal Al Aglab area, North Eastern Desert, Egypt

    International Nuclear Information System (INIS)

    Eldabe, M.M.M.


    Gabal Al Aglab area is located in the North Eastern Desert of Egypt bounded by lat. 27° 14'-27° 19' N and long. 33° 00'-33° 05' E. It is covered by pan African basement rocks. The present study concern with the geology, petrography, geochemistry and radioactivity of various types of the dyke swarms in Gabal Al Aglab area. The field studies revealed that the area comprises the following litho-tectonic units ; Dokhan volcanic (oldest) and Hamammat sedimentary rocks and younger granites are represented by both Gabal Um Twier and Gabal Al Aglab syenogranites (youngest). Many dykes of acidic, intermediate and basic composition have a large extension and dissect all the mentioned rock units. The dyke swarms intruding Gabal Al Aglab area include the acidic (felsite and granite porphyry) dykes, while the intermediate comprise andesite and andesite porphyry and the basic dykes show basalt and dolerites. The chronologic relations of these dykes indicate the following sequence of emplacement beginning with the oldest acidic, followed by intermediate and then basic ones. The geochemical studies indicate that the acidic dykes were derived from a highly differentiated calc- alkaline magma, while the basic and intermediate dykes were developed from magma of subalkaline nature. The dykes were derived from separate magmas and not by magmatic differentiation of single mother magma. The radioactivity of the studied dyke rocks revealed that the high levels of radioactivity mainly linked to the acidity, differentiation and alkalinity characters. Radioactive granitic spot was observed along the contact with some basic dykes due to their thermal effect during its emplacement on the granite, at the northern part of the studied area. This radioactive spot display anomalies with higher values in U and Th contents, than the normal background value of the younger granite.

  12. High water contents in basaltic melt inclusions from Arenal volcano, Costa Rica (United States)

    Wade, J. A.; Plank, T.; Hauri, E. H.; Melson, W. G.; Soto, G. J.


    Despite the importance of water to arc magma genesis, fractionation and eruption, few quantitative constraints exist on the water content of Arenal magmas. Early estimates, by electron microprobe sum deficit, suggested up to 4 wt% H2O in olivine-hosted basaltic andesite melt inclusions (MI) from pre-historic ET-6 tephra (Melson, 1982), and up to 7 wt% H2O in plagioclase and orthopyroxene-hosted dacitic MI from 1968 lapilli (Anderson, 1979). These high water contents are consistent with abundant hornblende phenocrysts in Arenal volcanics, but inconsistent with geochemical tracers such as 10Be and Ba/La that suggest a low flux of recycled material (and presumably water) from the subduction zone. In order to test these ideas, and provide the first direct measurements of water in mafic Arenal magmas, we have studied olivine-hosted MI from the prehistoric (900 yBP; Soto et al., 1998) ET3 tephra layer. MI range from andesitic (> 58% SiO2) to basaltic compositions ( 4 wt%) found here for Arenal basaltic MI support the semi-quantitative data from earlier studies, but are somewhat unexpected given predictions from slab tracers. Arenal water contents (4%) approach those of the 1995 eruption of Cerro Negro in Nicaragua (4-5 wt% in basaltic MI; Roggensack et al., 1997), despite the fact that the latter has Ba/La of > 100, while Arenal has Ba/La Journal of Geology; Melson, William G. (1982) Boletin de Volcanologia; Roggensack et al. (1997) Science; Soto et al. (1998) OSIVAM; Williams-Jones et al. (2001) Journal of Volc. and Geoth. Res.

  13. Petrology and geochemistry of Granitoids at Khanchay-Aliabad region, Tarom sub-zone, East of Zanjan

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    Arefeh Saiedi


    Full Text Available Khanchay-Aliabad area as a part of Tarom magmatic belt contains some shallow depth intrusions which are intruded the Eocene volcanic- sedimentary rocks and have very close association with Cu mineralization. The Eocene volcanic- sedimentary rocks include alternation of basalt, basaltic andesite and andesite, various kinds of tuff, tuffaceous sandstone, sandstone, siltstone and occasionally shale. Petrographical studies demonstrate that intrusions are pyroxene quartz monzonite and olivine gabbro in composition. The Khanchay pyroxene quartz monzonite have porphyritic to porphyroidic, hetero-granular to sereitic, ophitic and sub- ophitic textures and composed of plagioclase, clinopyroxene, hornblende, quartz, K-feldspar and biotite. The Aliabad pyroxene quartz monzonite shows porphyritic to porphyroidic textures composing of plagioclase, clinopyroxene and hornblende in the quartz- feldspatic matrix. The Khanchay olivine gabbro is characterized by the presence of coarse grained granular, ophitic and sub- ophitic textures as well as the occurrence of plagioclase, clinopyroxene and olivine. Geochemical studies indicate that the Khanchay- Aliabad pyroxene quartz monzonitic intrusions have SiO2 content varying from 59.58 to 61.34 %. These intrusions have high- K calc- alkaline nature and are classified as I-type metaluminous granitoids. Their similar patterns on spider diagrams are indication of genetic relation of these intrusions. On these diagrams LILEs (Ba, K, Th and Pb enrichment along with negative anomalies of HFSEs (Nb and Ti are observed. Moreover, the Chondrite normalized REE patterns demonstrate LREE enrichment with high ratio of LREE/HREE and Lan/Ybn ratio ranging from 3.08 to 3.72. The overall  field investigation, petrological and geochemical studies as well as  tectonic setting discrimination diagrams confirm that the Khanchay- Aliabad high-K intrusions were formed from a subduction related metasomatized lithospheric mantle in a post

  14. U–Pb geochronology and geochemistry of late Palaeozoic volcanism in Sardinia (southern Variscides

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    L. Gaggero


    Full Text Available The latest Carboniferous to lower Permian volcanism of the southern Variscides in Sardinia developed in a regional continental transpressive and subsequent transtensile tectonic regime. Volcanism produced a wide range of intermediate–silicic magmas including medium- to high-K calc-alkaline andesites, dacites, and rhyolites. A thick late Palaeozoic succession is well exposed in the four most representative Sardinian continental basins (Nurra, Perdasdefogu, Escalaplano, and Seui–Seulo, and contains substantial stratigraphic, geochemical, and geochronological evidence of the area's complex geological evolution from the latest Carboniferous to the beginning of the Triassic. Based on major and trace element data and LA-ICP-MS U–Pb zircon dating, it is possible to reconstruct the timing of post-Variscan volcanism. This volcanism records active tectonism between the latest Carboniferous and Permian, and post-dates the unroofing and erosion of nappes in this segment of the southern Variscides. In particular, igneous zircon grains from calc-alkaline silicic volcanic rocks yielded ages between 299 ± 1 and 288 ± 3 Ma, thereby constraining the development of continental strike-slip faulting from south (Escalaplano Basin to north (Nurra Basin. Notably, andesites emplaced in medium-grade metamorphic basement (Mt. Cobingius, Ogliastra show a cluster of older ages at 332 ± 12 Ma. Despite the large uncertainty, this age constrains the onset of igneous activity in the mid-crust. These new radiometric ages constitute: (1 a consistent dataset for different volcanic events; (2 a precise chronostratigraphic constraint which fits well with the biostratigraphic data and (3 insights into the plate reorganization between Laurussia and Gondwana during the late Palaeozoic evolution of the Variscan chain.

  15. Radioactive equilibria and disequilibria of U-series nuclides in the products from Izu arc volcanoes, Japan

    Energy Technology Data Exchange (ETDEWEB)

    Kurihara, Y.; Sato, J. [Meiji Univ., Kawasaki, Kanagawa (Japan). Dept. of Applied Chemistry; Takahashi, M. [Central Research Institute of Electric Power Industry, Tokyo (Japan). Radiation Safety Research Center


    Activity ratios among {sup 238}U-{sup 230}Th-{sup 226}Ra in the products from Izu arc volcanoes, Japan, were observed in order to estimate the time scale of magmatic processes and the magma generation for Izu arc volcanism. Activity ratios of {sup 238}U/{sup 230}Th and {sup 226}Ra/{sup 230}Th in the basaltic and andesitic products from Izu arc volcanoes were greater than unity, being enriched in {sup 238}U and {sup 226}Ra relative to {sup 230}Th. The {sup 226}Ra/{sup 230}Th activity ratio versus {sup 238}U/{sup 230}Th activity ratio diagram for these products showed positive correlation, suggesting that the {sup 238}U-{sup 230}Th-{sup 226}Ra disequilibria occurred during the magma genesis by the additions of U- and Ra-rich fluids derived from the subducting slab by dehydration to the mantle wedge. The {sup 230}Th-{sup 226226}Ra radioactive disequilibria observed in the basaltic and andesitic products imply a short period of time (<8000 years) between the magma genesis and the eruption. The majority of rhyolitic products was considered to be almost in equilibrium of {sup 238}U={sup 230}Th={sup 226}Ra. The observation that {sup 238}U-{sup 230}Th-{sup 226}Ra for the rhyolite are in radioactive equilibrium suggested that the rhyolitic magma from Izu arc was generated in the partial melting of the earth crust heated by the basaltic magma of high temperature. (orig.)

  16. Petrogenesis of Rinjani Post-1257-Caldera-Forming-Eruption Lava Flows

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    Heryadi Rachmat


    Full Text Available DOI:10.17014/ijog.3.2.107-126After the catastrophic 1257 caldera-forming eruption, a new chapter of Old Rinjani volcanic activity beganwith the appearance of Rombongan and Barujari Volcanoes within the caldera. However, no published petrogeneticstudy focuses mainly on these products. The Rombongan eruption in 1944 and Barujari eruptions in pre-1944, 1966,1994, 2004, and 2009 produced basaltic andesite pyroclastic materials and lava flows. A total of thirty-one sampleswere analyzed, including six samples for each period of eruption except from 2004 (only one sample. The sampleswere used for petrography, whole-rock geochemistry, and trace and rare earth element analyses. The Rombonganand Barujari lavas are composed of calc-alkaline and high K calc-alkaline porphyritic basaltic andesite. The magmashows narrow variation of SiO2 content that implies small changes during its generation. The magma that formedRombongan and Barujari lavas is island-arc alkaline basalt. Generally, data show that the rocks are enriched in LargeIon Lithophile Elements (LILE: K, Rb, Ba, Sr, and Ba and depleted in High Field Strength Elements (HFSE: Y, Ti,and Nb which are typically a suite from a subduction zone. The pattern shows a medium enrichment in Light REEand relatively depleted in Heavy REE. The processes are dominantly controlled by fractional crystallization andmagma mixing. All of the Barujari and Rombongan lavas would have been produced by the same source of magmawith little variation in composition caused by host rock filter process. New flux of magma would likely have occurredfrom pre-1944 until 2009 period that indicates slightly decrease and increase of SiO2 content. The Rombongan andBarujari lava generations show an arc magma differentiation trend.

  17. On the time-scales of magmatism at island-arc volcanoes. (United States)

    Turner, S P


    Precise information on time-scales and rates of change is fundamental to an understanding of natural processes and the development of quantitative physical models in the Earth sciences. U-series isotope studies are revolutionizing this field by providing time information in the range 10(2)-10(4) years, which is similar to that of many modern Earth processes. I review how the application of U-series isotopes has been used to constrain the time-scales of magma formation, ascent and storage beneath island-arc volcanoes. Different elements are distilled-off the subducting plate at different times and in different places. Contributions from subducted sediments to island-arc lava sources appear to occur some 350 kyr to 4 Myr prior to eruption. Fluid release from the subducting oceanic crust into the mantle wedge may be a multi-stage process and occurs over a period ranging from a few hundred kyr to less than one kyr prior to eruption. This implies that dehydration commences prior to the initiation of partial melting within the mantle wedge, which is consistent with recent evidence that the onset of melting is controlled by an isotherm and thus the thermal structure within the wedge. U-Pa disequilibria appear to require a component of decompression melting, possibly due to the development of gravitational instabilities. The preservation of large (226)Ra disequilibria permits only a short period of time between fluid addition and eruption. This requires rapid melt segregation, magma ascent by channelled flow and minimal residence time within the lithosphere. The evolution from basalt to basaltic andesite probably occurs rapidly during ascent or in magma reservoirs inferred from some geophysical data to lie within the lithospheric mantle. The flux across the Moho is broadly andesitic, and some magmas subsequently stall in more shallow crustal-level magma chambers, where they evolve to more differentiated compositions on time-scales of a few thousand years or less.

  18. Late Pleistocene flank collapse of Zempoala volcano (Central Mexico) and the role of fault reactivation (United States)

    Arce, José Luis; Macías, Rodolfo; García Palomo, Armando; Capra, Lucia; Macías, José Luis; Layer, Paul; Rueda, Hernando


    Zempoala is an extinct Pleistocene (˜ 0.7-0.8 Ma) stratovolcano that together with La Corona volcano (˜ 0.9 Ma) forms the southern end of the Sierra de las Cruces volcanic range, Central Mexico. The volcano consists of andesitic and dacitic lava flows and domes, as well as pyroclastic and epiclastic sequences, and has had a complex history with several flank collapses. One of these collapses occurred during the late Pleistocene on the S-SE flank of the volcano and produced the Zempoala debris avalanche deposit. This collapse could have been triggered by the reactivation of two normal fault systems (E-W and NE-SW), although magmatic activity cannot be absolutely excluded. The debris avalanche traveled 60 km to the south, covers an area of 600 km 2 and has a total volume of 6 km 3, with a calculated Heim coefficient (H/L) of 0.03. Based on the textural characteristics of the deposit we recognized three zones: proximal, axial, and lateral distal zone. The proximal zone consists of debris avalanche blocks that develop a hummocky topography; the axial zone corresponds with the main debris avalanche deposit made of large clasts set in a sandy matrix, which transformed to a debris flow in the lateral distal portion. The deposit is heterolithologic in composition, with dacitic and andesitic fragments from the old edifice that decrease in volume as bulking of exotic clasts from the substratum increase. Several cities (Cuernavaca, Jojutla de Juárez, Alpuyeca) with associated industrial, agricultural, and tourism activities have been built on the deposit, which pose in evidence the possible impact in case of a new event with such characteristics, since the area is still tectonically active.

  19. Crustal Viscosity Structure Estimated from Multi-Phase Mixing Theory (United States)

    Shinevar, W. J.; Behn, M. D.; Hirth, G.


    Estimates of lower crustal viscosity are typically constrained by analyses of isostatic rebound, post seismic creep, and laboratory-derived flow laws for crustal rocks and minerals. Here we follow a new approach for calculating the viscosity structure of the lower continental crust. We use Perple_X to calculate mineral assemblages for different crustal compositions. Effective viscosity is then calculated using the rheologic mixing model of Huet et al. (2014) incorporating flow laws for each mineral phase. Calculations are performed along geotherms appropriate for the Basin and Range, Tibetan Plateau, Colorado Plateau, and the San Andreas Fault. To assess the role of crustal composition on viscosity, we examined two compositional gradients extending from an upper crust with ~67 wt% SiO2 to a lower crust that is either: (i) basaltic with ~53 wt% SiO2 (Rudnick and Gao, 2003), or (ii) andesitic with ~64% SiO2 (Hacker et al., 2011). In all cases, the middle continental crust has a viscosity that is 2-3 orders of magnitude greater than that inferred for wet quartz, a common proxy for mid-crustal viscosities. An andesitic lower crust results in viscosities of 1020-1021 Pa-s and 1021-1022 Pa-s for hotter and colder crustal geotherms, respectively. A mafic lower crust predicts viscosities that are an order of magnitude higher for the same geotherm. In all cases, the viscosity calculated from the mixing model decreases less with depth compared to single-phase estimates. Lastly, for anhydrous conditions in which alpha quartz is stable, we find that there is a strong correlation between Vp/Vs and bulk viscosity; in contrast, little to no correlation exists for hydrous conditions.

  20. The effect of offset on fracture permeability of rocks from the Southern Andes Volcanic Zone, Chile (United States)

    Pérez-Flores, P.; Wang, G.; Mitchell, T. M.; Meredith, P. G.; Nara, Y.; Sarkar, V.; Cembrano, J.


    The Southern Andes Volcanic Zone (SVZ) represents one of the largest undeveloped geothermal provinces in the world. Development of the geothermal potential requires a detailed understanding of fluid transport properties of its main lithologies. The permeability of SVZ rocks is altered by the presence of fracture damage zones produced by the Liquiñe-Ofqui Fault System (LOFS) and the Andean Transverse Faults (ATF). We have therefore measured the permeability of four representative lithologies from the volcanic basement in this area: crystalline tuff, andesitic dike, altered andesite and granodiorite. For comparative purposes, we have also measured the permeability of samples of Seljadalur basalt, an Icelandic rock with widely studied and reported hydraulic properties. Specifically, we present the results of a systematic study of the effect of fractures and fracture offsets on permeability as a function of increasing effective pressure. Baseline measurements on intact samples of SVZ rocks show that the granodiorite has a permeability (10-18 m2), two orders of magnitude higher than that of the volcanic rocks (10-20 m2). The presence of throughgoing mated macro-fractures increases permeability by between four and six orders of magnitude, with the highest permeability recorded for the crystalline tuff. Increasing fracture offset to produce unmated fractures results in large increases in permeability up to some characteristic value of offset, beyond which permeability changes only marginally. The increase in permeability with offset appears to depend on fracture roughness and aperture, and these are different for each lithology. Overall, fractured SVZ rocks with finite offsets record permeability values consistent with those commonly found in geothermal reservoirs (>10-16 m2), which potentially allow convective/advective flow to develop. Hence, our results demonstrate that the fracture damage zones developed within the SVZ produce permeable regions, especially within the

  1. Geological study of Ujungwatu area as support for NPP planning in Muria Central Java

    International Nuclear Information System (INIS)



    In accordance with growth of life in Java, the need for electricity is also growing accordingly. Efforts to provide electricity such as planning to build nuclear power plant (NPP) has been in the debate for a while. There are many factors to be considered in this planning, such as its environmental condition. Geological factor is one of the important one to be considered. Surface geological conditions around NPP area at Ujungwatu needed include stratigraphy, geological structure, geomorphology, and environmental geology. Geology in Ujungwatu at radius 5 km is quite interesting. This area is part of Genuk volcano group which is laid at south and Ujungwatu coast at north. Genuk mountain group is divided into mountain slope, mountain back, and mountain skeleton. Coastal area is composed of coast sand. Sand up to broken rock was present along river gullies. Others were volcanic rocks which was composed of lapili tuff, trachite, pyroxene andesite, tuff breccia, tephrite-andesitic tuff breccia, and basaltic tuff breccia. Volcanic structure is well reflected by morphological feature as lineaments and half circular form in mount Genuk. This structure was predominantly in NW-SE direction, and less dominant in NE-SW direction. Ujungwatu, from environmental view, is deserved to be developed because of its underground potency. Iron sand, fluvial tuff, kaolin, mud, riverstone, volcanic rock, tuff and marble were easily found underground. Those could be benefited to the people in the area so that it could change socio-economical condition of the people which in turn electricity is becoming a necessity. Last but not least, Portuguese fort as potential touristic object is also situated at Kartini beach near Ujungwatu. (author). 15 refs, 3 tabs, 5 figs

  2. Complex conductivity of volcanic rocks and the geophysical mapping of alteration in volcanoes (United States)

    Ghorbani, A.; Revil, A.; Coperey, A.; Soueid Ahmed, A.; Roque, S.; Heap, M. J.; Grandis, H.; Viveiros, F.


    Induced polarization measurements can be used to image alteration at the scale of volcanic edifices to a depth of few kilometers. Such a goal cannot be achieved with electrical conductivity alone, because too many textural and environmental parameters influence the electrical conductivity of volcanic rocks. We investigate the spectral induced polarization measurements (complex conductivity) in the frequency band 10 mHz-45 kHz of 85 core samples from five volcanoes: Merapi and Papandayan in Indonesia (32 samples), Furnas in Portugal (5 samples), Yellowstone in the USA (26 samples), and Whakaari (White Island) in New Zealand (22 samples). This collection of samples covers not only different rock compositions (basaltic andesite, andesite, trachyte and rhyolite), but also various degrees of alteration. The specific surface area is found to be correlated to the cation exchange capacity (CEC) of the samples measured by the cobalthexamine method, both serving as rough proxies of the hydrothermal alteration experienced by these materials. The in-phase (real) conductivity of the samples is the sum of a bulk contribution associated with conduction in the pore network and a surface conductivity that increases with alteration. The quadrature conductivity and the normalized chargeability are two parameters related to the polarization of the electrical double layer coating the minerals of the volcanic rocks. Both parameters increase with the degree of alteration. The surface conductivity, the quadrature conductivity, and the normalized chargeability (defined as the difference between the in-phase conductivity at high and low frequencies) are linearly correlated to the CEC normalized by the bulk tortuosity of the pore space. The effects of temperature and pyrite-content are also investigated and can be understood in terms of a physics-based model. Finally, we performed a numerical study of the use of induced polarization to image the normalized chargeability of a volcanic edifice

  3. Mineral chemistry and petrogenesis of the Gurgur Mount volcanic rocks (Northeast Takab

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    Dariush Esmaeily


    Full Text Available Andesitic and andesitic-basaltic lavas are widespread over most of the ground surface of the Gurgur area altered mostly by the hydrothermal solutions. The main rock forming minerals in these rocks are plagioclase, pyroxene and olivine affected by the hydrothermal solutions. The altered rocks do contain minerals including calcite, sericite and chlorite. Given the results obtained and the mineral chemistry studies, the clinopyroxenes formed in the area are, chemically, calkalkaline and of diopside-augite type formed in subvolcanic to near surface levels contemporaneous with magma ascending. Plagioclase minerals show zoning textures and lie within the two andesine and albite-oligoclase fields. These units, in terms of total rock chemistry, are classified as the calk-alkaline volcanic rocks formed in the continental arcs. On the other hand, on the trace elements chondrite-normalized diagrams and enriched mantle-normalized multi- element diagrams, the LREE enrichment relative to the HREE is observed. The LILE (i.e. Rb, K and Th and the LREE (e.g. La, Ce and Nd show an enrichment in comparison to the HFSE (Zr, Hf, Nb, Yb, Y and Sm. Given the Nd/Th (1.42-1.15, Zr/Nb (12.27-21.22, Ba/La (18.64-29.77 as well as LILE enrichment associated with depletion in Nb, Ta and Ti, an environment related to the subduction zones can be proposed for the area under study. Moreover, the similarity between the REE distribution pattern and the incompatible elements point to the genetic relationship between these rocks. Finally, on the base of the obtained data, it can be concluded that the volcanic rocks in the Gurgur Mountain were likely formed during the extended magmatism of the Urumieh-Dokhtar in the Cenozoic.

  4. Petrography, Geochemistry and Petrogenesis of Volcanic Rocks, NW Ghonabad, Iran

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    Sedigheh Zirjanizadeh


    Full Text Available Introduction The study area is located in NW Gonabad, Razavi Khorasan Province, northern Lut block and eastern Iran north of the Lut Block. Magmatism in NW Gonabad produced plutonic and volcanic rock associations with varying geochemical compositions. These rocks are related to the Cenozoic magmatic rocks in Iran and belong to the Lut Block volcanic–plutonic belt. In this study, petrogenesis of volcanic units in northwest Gonabad was investigated. The volcanic rocks are andesites/trachyandesites, rhyolites, dacites/ rhyodacites and pyroclastics.These rocks show porphyritic, trachytic and embayed textures in phenocrysts with plagioclase, sanidine and quartz (most notably in dacite and rhyolite, hornblende and rare biotite. The most important alteration zones are propylitic, silicification and argillic.Four kaolinite- bearing clay deposits have been located in areas affectedby hydrothermal alteration of Eocene rhyolite, dacite and rhyodacite. Analytical techniques Five samples were analyzed for major elements by wavelength dispersive X-ray fluorescence (XRF and six samples were analyzed for trace elements using inductively coupled plasma-mass spectrometry (ICP-MS in the Acme Laboratories, Vancouver (Canada.Sr and Nd isotopic compositions were determined for four whole-rock samples at the Laboratório de GeologiaIsotópica da Universidade de Aveiro, Portugal. Results Petrography. The rocks in this area are consist of trachyte, andesite/ trachyandesite, dacite/ rhyodacite, principally as ignimbrites and soft tuff. The textures of phenocrysts are mainly porphyritic, glomerophyric, trachytic and embayed textures in plagioclase, hornblende and biotite. The groundmasses consist of plagioclase and fine-grainedcrystals of hornblende. Plagioclase phenocrysts and microlitesare by far the most abundant textures in andesite - trachyandesites (>25% and in size from 0.01 to 0.1mm. Euhedral to subhedral hornblende phenocrysts areabundant (3-5%and 0.1 to 0

  5. Post-Hercynian subvolcanic magmatism in the Serre Massif (Central-Southern Calabria, Italy) (United States)

    Romano, V.; Cirrincione, R.; Fiannacca, P.; Mazzoleni, P.; Tranchina, A.


    In the Serre Massif (Central-Southern Calabria, Italy) dykes and subvolcanic bodies intrude diffusively both Hercynian metamorphic rocks and late-Hercynian granitoids. They range in composition from basaltic andesites to dacite-rhyodacites and can be ascribed to the extensive magmatic activity that affects the entire Hercynian orogenic belt in late Paleozoic - early Mesozoic time. The geodinamic framework of the magmatic activity is still matter of debate, nevertheless most authors agree in correlating magmatism both to the late-orogenic collapse of the Hercynian belt and to the lithosphere thinning responsible for the subsequent continental rifting. In this work, we propose a petrogenetic model for acidic to basic hypabissal bodies from southern Calabria in order to define the nature of sources, discriminate magmatic processes and supply a contribution in the geodynamic reconstruction of the Late Palaeozoic in the Calabria-Peloritani Orogen. In relation to their geochemical affinity, studied dykes have been divided in two groups: a medium- to high-K calc-alkaline and a tholeiitic one. Dykes belonging to the former group, andesitic and dacitic-rhyodacitic in composition, show typical features of subduction-related magmatism, such as LILE and LREE enrichments, depletions in HFSE, peaks in Rb, Th and Ce, accentuated troughs in Ba, Nb-Ta, P and Ti (White and Dupré, 1986; McCulloch and Gamble, 1991), contrasting with the late Hercynian collisional context. On the other side, features typical of intra-plate magmatic activity, such as a moderate enrichment in Ta, Nb, Ce, P, Zr, Hf and Sm relative to MORB composition are also present in studied rocks (Shimizu & Arculus, 1975; Pearce, 1982). REE-patterns are strongly to weakly fractionated for the andesitic rocks (Lan/Ybn = 10.03-13.98) and the dacitic-rhyodacitic ones (Lan/Ybn = 6.00 to 2.82), respectively. The latter rocks exhibit a very slight negative Eu anomaly, whereas no Eu anomaly is recognizable in the andesite

  6. Petrology, Geochemistry and Tectonomagmatic Setting of Farmahin Volcanic Rocks (North of Arak

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    Reza Zarei Sahamieh


    Full Text Available Introduction The study area includes Alam Baghi, Vashaghan, Sar Band and Ghermez Cheshmeh and is located in the northeast of Farmahin and the southwest of Tafresh. Based on the structural subdivisions of Iran, the mentioned area is a part of Central Iran and the Urumieh-Dokhtar magmatic belt (Hajian, 1970. The studied volcanic rocks consist of trachybasalt, trachyandesite, basaltic andesite, andesite, dacite, rhyodacite, rhyolite, ignimbrite, tuff and tuffit in composition and in terms of age they belong to the middle and upper Eocene. It seems that the volcanic activities are related to folding and faulting in the studied area. On the other hand, in addition to causing orogenic activity, at the middle and upper Eocene (Ghasemi and Talbot, 2006, locally extensional regime has played a main role in volcanic eruption. Similar to this scenario happened in other areas such as Taft and Khizrabad in Central Iran (Zarei Sahamieh et al., 2008. Porphyritic, microlite porphyritic and microlitic are the main textures in these rocks. Mineralogically, they contain plagioclase, clinopyroxene, amphibole, quartz and biotite as the main minerals and zircon, apatite, and opaque minerals as accessories. Materials and methods The major and trace elements of mineral composition are determined by electron probe micro-analysis (EPMA using a Cameca SX100 instrument in the Iran Mineral Processing Research Center (IMPRC. Moreover, the whole-rock major and some trace elements analyses for a few samples were obtained by X-ray fluorescence (XRF, using an ARL Advant-XP automated X-ray spectrometer. Results Based on EPMA analyses, plagioclase mineral in basaltic andesite and trachybasalt samples range from labradorite to bytownite in andesite and trachyandesite has oligoclase- andesine and in dacite, rhyodacite, rhyolite has an albite-oligoclase composition. In the Wo-En-Fs diagram, all clinopyroxenes show augitic and a lessor amount of clinoenstatite composition and in the Q

  7. Geology, mineralization and geochemistry of the Aqkand Cu occurrence (north of Zanjan, Tarom-Hashtjin zone

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    Maryam Feyzi


    Full Text Available Introduction The Aqkand Cu occurrence, 48 km north of Zanjan, is located in the Tarom subzone of the Western Alborz-Azerbaijan structural zone. Apart from small scale geological maps of the area, i.e., 1:250,000 geological maps of Bandar-e-Anzali (Davies, 1977 and 1:100,000 geological maps of Hashtjin (Faridi and Anvari, 2000 and a number of unpublished perlite exploration reports, prior to this research no work has been done on Cu mineralization at Aqkand. The present paper provides an overview of the geological framework, the mineralization characteristics, and the results of geochemistry study of the Aqkand Cu occurrence with an application to the ore genesis. Identification of these characteristics can be used as a model for exploration of this type of copper mineralization in the Tarom area and elsewhere. Materials and methods Detailed field work has been carried out at different scales in the Aqkand area. About 35 polished thin and thin sections from host rocks and mineralized and altered zones were studied by conventional petrographic and mineralogic methods at the University of Zanjan. In addition, a total of 6 samples from ore zones at the Aqkand occurrence were analyzed by ICP-MS for trace elements and REE compositions at Kimia Pazhuh Alborz Co., Isfahan, Iran. Results and Discussion The oldest units exposed in the Aqkand area are Eocene volcanic rocks which are overlain unconformably by Oligocene acidic rocks. The Eocene units consist of lithic and vitric tuff with intercalations of andesitic basalt lavas (equal to Karaj Formation, Hirayama et al., 1966. The andesitic basalt lavas show porphyritic texture consisting of plagioclase and altered ferromagnesian minerals set in a fine-grained groundmass. The Oligocene acidic rocks consist of rhyolite-rhyodacite, perlite, pitchstone and ignimbrite. These rocks are exposed as domes and lava flows. The rhyolite-rhyodacite lavas usually show onion-skin weathering and locally display flow bands

  8. Determination of Mineralization Zones Using Interpretation of IP and RS Data in The GarmabCopper Deposit (South Khorasan province

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    Mansour Adelpour


    Full Text Available Introduction The Garmab copper deposit is located northeast of Qaen (South Khorasan province in the1:100,000 scale map of Abiz in the eastern tectonic zone of Iran. It is hosted by Late Paleocene-Eocene lava flows consisting mainly of andesite, trachy¬andesite, andesite-basalt and basalt lavas, as well as pyroclastic rocks, including tuffs and ignimbrites. The Lut Block has undergone intense magmatic activitywith a variety of geochemical characteristics due to changing tectonic conditions (e.g., compression during subduction followed by tensional conditions; Karimpour et al., 2012; Zarrinkoub et al., 2012. The Lut Block has a great potential for the discovery of new mineral deposits, like the Mahrabad and Khonik porphyry copper-gold deposits (Malekzadeh shafarodi, 2009, the Dehsalam porphyry copper deposit (Arjmandzadeh, 2011, high sulfidation epithermal gold deposits such as Chah Shalghami (Karimpour, 2005 and IOCG deposits such as Kuh-E-Zar and Qaleh Zari (Mazlomi et al., 2008. Materials and methods After field studies of the Garmab area, 32 thin sections and 21 polished sections were prepared for petrological and mineralogical studies.In addition, 10 least-altered and fractured samples of volcanic rocks were selected for geochemical studies. Major oxides were determined using XRF analyses at the Zarazma laboratory. Induced polarization and resistivity geophysical data were collected and correlated with geological and alteration maps. The geophysical datawere collectedfrom 420 individual points, using a dipole-dipole arrangement along five profiles separated 60m apart.This covered the study area entirely. After a change in the mineralization trend was observed,additional profileswere designed, twoon bearings of 25º and three on 75º. Results The Garmab volcanic rocks exhibit typical geochemical characteristics of subduction zone magmas including strong enrichment in LILE and depletion in HFSE. Based on the discrimination plot of Irvine and

  9. Partial reactive crystallization of variable CO2-bearing siliceous MORB-eclogite-derived melt in fertile peridotite and genesis of alkalic basalts with signatures of crustal recycling (United States)

    Mallik, A.; Dasgupta, R.


    The presence of heterogeneity in the form of recycled altered oceanic crust (MORB-eclogite) has been proposed in the source of HIMU ocean island basalts (OIBs) [1]. Partial melts of recycled oceanic crust, however, are siliceous and Mg-poor and thus do not resemble the major element compositions of alkalic OIBs that are silica-poor and Mg-rich. In an upwelling heterogenous mantle, MORB-eclogite undergoes melting deeper than volatile-free peridotite, hence, andesitic partial melt derived from eclogite will react with subsolidus peridotite. We have examined the effect of such a melt-rock reaction under volatile-free conditions at 1375 °C, 3 GPa by varying the melt-rock ratio from 8 to 50 wt.% [2]. We concluded that the reacted melts reproduce certain major element characteristics of oceanic basanites, but not nephelinites. Also, the melt-rock reaction produces olivine and garnet-bearing websteritic residue. Because presence of CO2 has been invoked in the source of many HIMU ocean islands, the effect of CO2 on such a melt-rock reaction needs to be evaluated. Accordingly, we performed reaction experiments on mixtures of 25% and 33% CO2-bearing andesitic partial melt and peridotite at 1375 °C, 3 GPa by varying the dissolved CO2 content of the reacting melts from 1 to 5 wt.% (bulk CO2 from 0.25 to 1.6 wt.%) [3, this study]. Owing to melt-rock reaction, with increasing CO2 in the bulk mixture, (a) modes of olivine and cpx decrease while melt, opx and garnet increase, (b) reacted melts evolve to greater degree of Si-undersaturation (from andesite through basanite to nephelinite), (c) enhanced crystallization of garnet take place with higher CO2 in the melt, reducing alumina content of the reacted melts, and (d) CaO and MgO content of the reacted melts increase, without affecting FeO* and Na2O contents (indicating greater propensity of Ca2+ and Mg2+ over Fe2+ and Na+ to enter silicate melt as carbonate). For a given melt-MgO, the CO2-bearing reacted melts are a better

  10. Late Carboniferous to Early Permian magmatic pulses in the Uliastai continental margin linked to slab rollback: Implications for evolution of the Central Asian Orogenic Belt (United States)

    Chai, Hui; Wang, Qingfei; Tao, Jixiong; Santosh, M.; Ma, Tengfei; Zhao, Rui


    The Paleo Asian Ocean underwent a protracted closure history during Late Paleozoic. Here we investigate the magmatic evolution during this process based on a detailed study in the Baiyinwula region along the Uliastai continental margin. The major rock types in this area are Late Carboniferous-Early Permian volcanic sequences and coeval intrusions. We identified four stages of magmatic evolution based on the diverse assemblages and their precise isotopic ages. The first stage is represented by andesites with a zircon 206Pb/238U age of ca. 326 ± 12 Ma. These rocks are metaluminous to weakly peraluminous, high-K calc-alkaline, and possess high Na2O/K2O ratios in the range of 1.23 to 2.45. They also display enrichment of large ion lithophile elements (LILE) and depletion of high field strength elements (HFSE), with markedly positive zircon εHf (t) varying from 8.1 to 15.6.The geochemical features of these andesites are similar to those of typical arc volcanic rocks. The second stage includes granodiorites emplaced at 318.6 + 1.8 Ma. The rocks are high-K calc-alkaline with A/CNK values ranging from 0.95 to 1.06, and show enrichment in LILE and depletion in HFSE. They show geochemical affinities to adakites, with high Sr and low Y and Yb contents, indicating magma derivation from thickened lower crust. Zircon grains from these rocks display positive initial εHf (t) values ranging from 11.1 to 14.6 with corresponding two-stage Hf model ages (TDM2) of 394-622 Ma. The third stage consists of syenogranite together with a volcanic suite ranging in composition from rhyolite todacite, which formed during 303.4 ± 1.2 to 285.1 ± 2.2 Ma. They possess elevated silica and alkali contents, high FeOt/MgO and Ga/Al ratios, low Al2O3, MgO and CaO contents, and high Rb, Y, Nb, Ce, Zr, Y, and Ga contents, strong negative Ba, Sr and Eu anomalies, showing I- to A-type granitic affinities. Zircons in these rocks show elevated Hf isotopic compositions (εHf (t) = 9.9 to 14.6) with TDM2

  11. Permian to recent volcanism in northern sumatra, indonesia: a preliminary study of its distribution, chemistry, and peculiarities (United States)

    Rock, N. M. S.; Syah, H. H.; Davis, A. E.; Hutchison, D.; Styles, M. T.; Lena, Rahayu


    Sumatra has been a ‘volcanic arc’, above an NE-dipping subduction zone, since at least the Late Permian. The principal volcanic episodes in Sumatra N of the Equator have been in the Late Permian, Late Mesozoic, Palaeogene, Miocene and Quaternary. Late Permian volcanic rocks, of limited extent, are altered porphyritic basic lavas interstratified with limestones and phyllites. Late Mesozoic volcanic rocks, widely distributed along and W of the major transcurrent. Sumatra Fault System (SFS), which axially bisects Sumatra, include ophiolite-related spilites, andesites and basalts. Possible Palaeogene volcanic rocks include an altered basalt pile with associated dyke-swarm in the extreme NW, intruded by an Early Miocene (19 my) dioritic stock; and variable pyroxene rich basic lavas and agglomerates ranging from alkali basaltic to absarokitic in the extreme SW. Miocene volcanic rocks, widely distributed (especially W of the SFS), and cropping out extensively along the W coast, include calc-alkaline to high-K calc-alkaline basalts, andesites and dacites. Quaternary volcanoes (3 active, 14 dormant or extinct) are irregularly distributed both along and across the arc; thus they lie fore-arc of the SFS near the Equator but well back-arc farther north. The largest concentration of centres, around Lake Toba, includes the >2000 km3 Pleistocene rhyolitic Toba Tuffs. Quaternary volcanics are mainly calc-alkaline andesites, dacites and rhyolites with few basalts; they seem less variable, but on the whole more acid, than the Tertiary. The Quaternary volcanism is anomalous in relation to both southern Sumatra and adjacent Java/Bali: in southern Sumatra, volcanoes are regularly spaced along and successively less active away from the SFS, but neither rule holds in northern Sumatra. Depths to the subduction zone below major calc-alkaline volcanoes in Java/Bali are 160-210 km, but little over 100 km in northern Sumatra, which also lacks the regular K2O-depth correlations seen in

  12. Metallogeny of the Gold Quadrilateral: style and characteristics of epithermal - subvolcanic mineralized structures, South Apuseni Mts., Romania

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    S̡erban-Nicolae Vlad


    Full Text Available The Romanian territory contains numerous ore deposits mined since pre-Roman times. An assessment of historical gold production of the Gold Quadri-lateral (GQ yielded a total estimate of 55.7 Moz of gold throughout an area of 2400 km2. Interpreted in terms of mineralization density this is 23,208 oz of gold/ km2. The geological setting of the GQ is represented mainly by Tertiary (14.7 My to 7.4 My calc-alkaline volcano-plutonic complexes of intermediate character in sedimentary basins of molasse type. These basins are tectonically controlled by NW-SE lineation across early Alpine magmatic products, i.e. subduction related Jurassic-Lower Cretaceous igneous association (island arc ophiolites and granitoids and Upper Cretaceous igneous association (banatites. The Tertiary magmatism is associated with extensional tectonics caused by NE escape of the Pannonian region during Upper Oligocene-Lower Miocene times. As a result of tectono-magmatic and mineralization-alteration characteristics, two metallogenetical types were separated in the GQ, i.e. calc-alkaline andesitic (CAM and sub-alkaline rhyodacitic (SRM. Both develop almost entirely low-sulfidation type of Au epithermal mineralization. However, two subtypes, -rich in sulfide (2-7% and -poor in sulfide (7-20% were delineated and correlated with CAM type and SRM type respectively. Furthermore, CAM is connected at deeper levels with Cu-Au+/-Mo porphyry systems in contrast with SRM, which is a non-porphyry environment. The Brad-Săcărâmb district contains mainly CAM type andesitic structures. It is a porphyry environment with epithermal low-sulfidation-rich sulfide vein halo (Barza, Troiţa-Bolcana deposits. However, a few SRM type patterns, such as Măgura Ţebii, Băiţa-Crăciuneşti and Săcărâmb, deposits exhibit Au-Ag-Te low-sulfidation-poor sulfide epithermal vein halo. The Zlatna-Stănija district exhibits similar characteristics, with Au-Ag+/-Pb, Zn veins in Cu-Au subvolcanic

  13. 3D geophysical insights into the Ciomadu volcano (United States)

    Besutiu, Lucian; Zlagnean, Luminita


    RATIONALE Located at the south easternmost end of the Neogene to Quaternary volcanic chain of East Carpathians, the Ciomadu volcano (last erupted approx 30 ka ago) seems to represent the latest volcanic manifestation within the Carpatho-Pannonian region. Based on the interpretation of some large-scale electromagnetic and seismological surveys, the hypothesis of the in depth (8 -15 km) existence of a magma reservoir raises the volcanic hazard in the region. The close neighbourhood of the Vrancea active geodynamic zone, where intermediate-depth seismicity occurs within full intra-continental environment makes the study of the Ciomadu volcano of higher interest. METHOD During the time numerous geological investigations have been conducted in the area, but except for the previously mentioned large-scale electromagnetic and seismological approaches geophysical tools have been less employed. Relatively recent, within the frame of the INSTEC project, funded through a CNCS-UEFISCDI (Romanian Science Foundation) grant, the area has been subject to an integrated gravity and geomagnetic survey accompanied by outcrops sampling and lab determinations on rock physics. Field data have been highly processed and models of their sources have been constructed through 3D inversion techniques. RESULTS Overall, the potential fields have revealed a large gravity low covering the whole volcano area associating a residual geomagnetic anomaly with local effects mainly bordering the gravity anomaly. 3D inversion of the gravity data provided an intriguing image on the mass distribution within the volcanic structure, with underground densities much bellow the figures provided by the lab determinations on rock samples collected at the surface. The geometry of the revealed gravity source clearly suggests an andesitic/dacitic intrusion acceding to the surface along a deep fault that seems to belong to the alpine overthrust system of East Carpathians. Attempts to interpret the low value densities

  14. Late Cenozoic Samtskhe-Javakheti Volcanic Highland, Georgia:The Result of Mantle Plumes Activity (United States)

    Okrostsvaridze, Avtandil


    Late Cenozoic Samtskhe-Javakheti continental volcanic highland (1500-2500 m a.s.l) is located in the SW part of the Lesser Caucasus. In Georgia the highland occupies more than 4500 km2, however its large part spreads towards the South over the territories of Turkey and Armenia. One can point out three stages of magmatic activity in this volcanic highland: 1. Early Pliocene activity (5.2-2.8 Ma; zircons U-Pb age) - when a large part of the highland was built up. It is formed from volcanic lava-breccias of andesite-dacitic composition, pyroclastic rocks and andesite-basalt lava flow. The evidences of this structure are: a large volume of volcanic material (>1500 km3); big thickness (700-1100 m in average), large-scale of lava flows (length 35 km, width 2.5-3.5 km, thickness 30-80 m), big thickness of volcanic ash horizons (300 cm at some places) and big size of volcanic breccias (diameter >1 m). Based on this data we assume that a source of this structure was a supervolcano (Okrostsvaridze et al., 2016); 2. Early Pleistocene activity (2.4 -1.6 Ma; zircons U-Pb age) - when continental flood basalts of 100-300 m thickness were formed. The flow is fully crystalline, coarse-grained, which mainly consist of olivine and basic labradorite. There 143Nd/144Nd parameter varies in the range of +0.41703 - +0.52304, and 87Sr/88Sr - from 0.7034 to 0.7039; 3. Late Pleistocene activity (0.35-0.021 Ma; zircons U-Pb age) - when intraplate Abul-Samsari linear volcanic ridge of andesite composition was formed stretching to the S-N direction for 40 km with the 8-12 km width and contains more than 20 volcanic edifices. To the South of the Abul-Samsari ridge the oldest (0.35-0.30 Ma; zircons U-Pb age) volcano Didi Abuli (3305 m a.s.l.) is located. To the North ages of volcano edifices gradually increase. Farther North the youngest volcano Tavkvetili (0.021-0. 030 Ma) is located (2583 m a.s.l.). One can see from this description that the Abul-Samsari ridge has all signs characterizing

  15. Geology of the region of Guadalajara, Mexico, and its relationships with processes of subsidence (United States)

    Suarez-Plascencia, C.; Delgado-Argote, L. A.; Nuñez-Cornu, F. J.; Sanchez, J. J.


    The city of Guadalajara, Mexico, began an accelerated urban growth in early 1950. During a span of 25 years a large number of gullies were artificially filled, with the aim of incorporating new areas for urbanization, particularly in the areas north and west of the city. These gullies originally formed a complex dendritic-type system, whose evolution may be associated with faults or fracture zones whose current identification are only possible based on escarpments along the Canyon of the Rio Grande de Santiago (CRGS), north of Guadalajara. Reports of affectations documented in the 80's described subsidence in buildings and infrastructure, a process that has been continued during 2008. We present the results of work done in the CRGS, which is a tectonic erosive-depression with an average depth of 500 m and exhibits a sequence of volcanic and sedimentary deposits with rapid lateral facies changes. The stratigraphic column spans a 15 km-long section along the Matatlán-Arcediano road, and, from top to bottom contains: 1) Unconsolidated pumice and tuffs with an average thickness of 12 m; 2) basaltic lavas with average thickness of 60 m; 3) the San Gaspar ignimbrite; 4) fluvial- sedimentary deposits with a thickness of approximately 20 meters that include both sub-rounded and angular volcanic clasts, with sizes up to 0.15 m; 5) a thick sequence of ignimbrites and dacitic lavas. At a depth of 1200 m.a.s.l. in the town of Arcediano, the basal sequence is composed of dacites and andesites with interbedded pumice-rich ignimbrites with 10-20 m thickness. The Rio Grande de Santiago talweg to 1018 m.a.s.l. (apparently the base of the sequence) is formed by andesite lava. In the area of San Gaspar we identified oblique-normal left-lateral faults in lavas, with a strike 191° and a dip 89°. In the Colimilla dam, 1297 m.a.s.l., we observed normal faulting (strike 267° and dip 81°), with 20-30 m jumps with reference to a unit of tephra of 3-10 m thickness. The lavas in this

  16. Quaternary volcanism near the Valley of Mexico: implications for subduction zone magmatism and the effects of crustal thickness variations on primitive magma compositions (United States)

    Wallace, Paul J.; Carmichael, Ian S. E.

    The Valley of Mexico and surrounding regions of Mexico and Morelos states in central Mexico contain more than 250 Quaternary eruptive vents in addition to the large, composite volcanoes of Popocatépetl, Iztaccíhuatl, and Nevado de Toluca. The eruptive vents include cinder and lava cones, shield volcanoes, and isolated andesitic and dacitic lava flows, and are most numerous in the Sierra Chichináutzin that forms the southern terminus of the Valley of Mexico. The Chichináutzin volcanic field (CVF) is part of the E-W-trending Mexican Volcanic Belt (MVB), a subduction-related volcanic arc that extends across Mexico. The crustal thickness beneath the CVF ( 50km) is the greatest of any region in the MVB and one of the greatest found in any arc worldwide. Lavas and scoriae erupted from vents in the CVF include alkaline basalts and calc-alkaline basaltic andesites, andesites, and dacites. Both alkaline and calc-alkaline groups contain primitive varieties that have whole rock Mg#, MgO, and Ni contents, and liquidus olivine compositions (<=Fo90) that are close to those expected of partial melts from mantle peridotite. Primitive varieties also show a wide range of incompatible trace element abundances (e.g. Ba 210-1080ppm Ce 25-100ppm Zr 130-280ppm). Data for primitive calc-alkaline rocks from both the CVF and other regions of the MVB to the west are consistent with magma generation in an underlying mantle wedge that is depleted in Ti, Zr, and Nb and enriched in large ion lithophile (K, Ba, Rb) and light rare earth (La, Ce) elements. Extents of partial melting estimated from Ti and Zr data are lower for primitive calc-alkaline magmas in the CVF than for those from the regions of the MVB to the west where the crust is thinner. The distinctive major element compositions (low CaO and Al2O3, high SiO2) of the primitive calc-alkaline magmas in the CVF indicate a more refractory mantle source beneath this region of thick crust. In contrast, primitive alkaline magmas from the

  17. Phanerozoic Rifting Phases And Mineral Deposits (United States)

    Hassaan, Mahmoud


    In North Africa occur Mediterranean and Red Sea metallogenic provinces. In each province distribute 47 iron- manganese- barite and lead-zinc deposits with tectonic-structural control. The author presents in this paper aspects of position of these deposits in the two provinces with Phanerozoic rifting . The Mediterranean Province belongs to two epochs, Hercynian and Alpine. The Hercynian Epoch manganese deposits in only Moroccoa- Algeria belong to Paleozoic tectonic zones and Proterozoic volcanics. The Alpine Epoch iron-manganese deposits are of post-orogenic exhalative-sedimentary origin. Manganese deposits in southern Morocco occur in Kabil-Rief quartz-chalcedony veins controlled by faults in andesitic sheets and in bedded pelitic tuffs, strata-form lenses and ore veins, in Precambrian schist and in Triassic and Cretaceous dolomites. Disseminated manganese with quartz and barite and effusive hydrothermal veins are hosted in Paleocene volcanics. Manganese deposits in Algeria are limited and unrecorded in Tunisia. Strata-form iron deposits in Atlas Heights are widespread in sub-rift zone among Jurassic sediments inter-bedding volcanic rocks. In Algeria, Group Beni-Saf iron deposits are localized along the Mediterranean coast in terrigenous and carbonate rocks of Jurassic, Cretaceous and Eocene age within faults and bedding planes. In Morocco strata-form hydrothermal lead-zinc deposits occur in contact zone of Tertiary andesite inter-bedding Cambrian shale, Lias dolomites and Eocene andesite. In both Algeria and Tunisia metasomatic Pb-Zn veins occur in Campanian - Maastrichtian carbonates, Triassic breccia, Jurassic limestone, Paleocene sandstones and limestone and Neogene conglomerates and sandstones. The Red Sea metallogenic province belongs to the Late Tertiary-Miocene times. In Wadi Araba hydrothermal iron-manganese deposits occur in Cretaceous sediments within 320°and 310 NW faults related to Tertiary basalt. Um-Bogma iron-manganese deposits are closely

  18. Structural observations from the Canavese Fault west of Valle d'Ossola (Piemonte) and some time constraints (United States)

    Pleuger, Jan; Mancktelow, Neil


    The Canavese Fault (CF) is the SW part of the most important fault system in the Alps, the Periadriatic Fault. The CF has a complex kinematic history involving an older stage of NW-side-up faulting and a younger stage of SE-side-up plus dextral faulting in the area of Valle d'Ossola (Schmid et al. 1987). There, shearing occurred under greenschist-facies conditions and the fault is a c. 1 km thick mylonite zone. Toward SW, faulting took place under progressively lower temperatures and the volume of rocks affected by S-side-up plus dextral shearing becomes larger at the expense of the N-side-up mylonites. S of Valle Sesia, brittle fault rocks dominate over mylonites. Still further SW, close to the Serra d'Ivrea, the CF splits into two branches, the Internal Canavese Fault (ICF) and the External Canavese Fault (ECF). S-side-up plus dextral faulting is localised along the ICF while the observed displacement senses at the ECF are mostly, though not always, N-side-up and sinistral. Age constraints for faulting along the CF are mostly derived from absolute ages of magmatic rocks exposed alongside or within the fault. In the section around Biella, NW-side-up faulting cannot have lasted longer than until 31±2 Ma (Scheuring et al. 1974) because this is the age of andesites overlying the basement of the Penninic Sesia Zone. However, some additional uplift of the Sesia Zone with respect to the South Alpine Ivrea Zone was accommodated by down-to-the-SE tilting of the Sesia zone around a roughly NNE-SSW-trending subhorizontal axis which is evidenced by palaeomagnetic data (Lanza 1977). As a result of that, the Early Oligocene Biella Pluton (c. 31 Ma, Romer et al. 1996) today occupies a similar altitude level as the andesites of the same age. Post-31-Ma uplift of the Ivrea Zone with respect to the andesites is evidenced by the Early Oligocene (29-33 Ma, Carraro & Ferrara 1968) Miagliano Pluton which is hosted by the Ivrea Zone rocks and exposed at the present topographic surface

  19. Transition of magma genesis estimated by change of chemical composition of Izu-bonin arc volcanism associated with spreading of Shikoku Basin (United States)

    Haraguchi, S.; Ishii, T.


    Arc volcanism in the Izu-Ogasawara arc is separated into first and latter term at the separate of Shikoku Basin. Middle to late Eocene early arc volcanism formed a vast terrane of boninites and island arc tholeiites that is unlike active arc systems. A following modern-style arc volcanism was active during the Oligocene, along which intense tholeiitic and calc-alkaline volcanism continued until 29Ma, before spreading of the back- arc basin. The recent arc volcanism in the Izu-Ogasawara arc have started in the middle Miocene, and it is assumed that arc volcanism were decline during spreading of back-arc basin. In the northern Kyushu-Palau Ridge, submarine bottom materials were dredged during the KT95-9 and KT97-8 cruise by the R/V Tansei-maru, Ocean Research Institute, university of Tokyo, and basaltic to andesitic volcanic rocks were recovered during both cruise except for Komahashi-Daini Seamount where recovered acidic plutonic rocks. Komahashi-Daini Seamount tonalite show 37.5Ma of K-Ar dating, and this age indicates early stage of normal arc volcanism. These volcanic rocks are mainly cpx basalt to andesite. Two pyroxene basalt and andesite are only found from Miyazaki Seamount, northern end of the Kyushu-Palau Ridge. Volcanic rocks show different characteristics from first term volcanism in the Izu-Ogasawara forearc rise and recent arc volcanism. The most characteristic is high content of incompatible elements, that is, these volcanics show two to three times content of incompatible elements to Komahashi-Daini Seamount tonalite and former normal arc volcanism in the Izu outer arc (ODP Leg126), and higher content than recent Izu arc volcanism. This characteristic is similar to some volcanics at the ODP Leg59 Site448 in the central Kyushu- Palau Ridge. Site448 volcanic rocks show 32-33Ma of Ar-Ar ages, which considered beginning of activity of Parece Vela Basin. It is considered that the dredged volcanic rocks are uppermost part of volcanism before spreading of

  20. Cathodoluminescence (CL) features of the Anatolian agates, hydrothermally deposited in different volcanic hosts from Turkey

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    Hatipoglu, Murat, E-mail: [Dokuz Eylul University, IMYO, Izmir Multidisciplinary Vocational School, Gemmology and Jewellery Programme, TR-35380 Buca-Izmir (Turkey); Ajo, David [Institute of Inorganic Chemistry and Surfaces, CNR, Corso Stati Uniti 4, I-35127 Padova (Italy); SMATCH (Scientific Methodologies Applied to Cultural Heritage), Largo Ugo Bartolomei 5, I-00136 Rome (Italy); Sezai Kirikoglu, M. [Istanbul Technical University, Faculty of Mine, Department of Geological Engineering, TR-34469 Maslak-Istanbul (Turkey)


    Two different types of multi-colored gem-quality agate samples were investigated. They are both found in the same area in the Cubuk-Ankara region of Turkey although the first group is morphologically and geologically distinct from the second, being nodular-shaped agates occurring in cavity-spaces of a rhyolite host rock with an acidic character. They generally do not have any macroscopic inclusions, but the second group of rather block-shaped agates occurs in the fracture-spaces of an andesite host rock with a more neutral character, i.e. of lower free silica content, and they may display pseudomorphic bar-like macroscopic inclusions. Cathodoluminescence results at room temperature were obtained using measurements with alternating current (AC) (at energies of 14 and 24 keV) as well as direct current (DC) (at 14 keV energy), and they display remarkably different patterns between the two types of agates. It reveals a relation between the CL emissions and the presence of some transition metal elements. It is obvious that all trace elements do not play a direct role. Gaussian fitting of the cathodoluminescence AC experimental data at 14 keV energy obtained from the agates of rhyolite host indicates that there are three major spectral emissions, the dominant one being in the longer-visible wavelength region (red region) at about 690 nm. Additionally, two lesser emission lines occur in the middle-visible wavelength region (yellow region) at about 590 nm, and in the smaller-visible wavelength region (blue region) at about 430 nm. In spite of these, the same data from the agates of andesite host indicate that there is only one remarkable spectral emission which is in the in the middle-visible wavelength region (yellow region) at about 590 nm. On the other hand, Gaussian fitting of the cathodoluminescence AC experimental data at 24 keV energy obtained from the agates of rhyolite host indicates that these initial spectral emissions shift from the red and yellow regions to

  1. Hydrogeological Modelling of Some Geothermal Waters of Ivrindi, Havran and Gönen in the Province Capital of Balikesir, Western Anatolia, Turkey (United States)

    Özgür, Nevzat; Ugurlu, Zehra; Memis, Ümit; Aydemir, Eda


    In this study, hydrogeological, hydrogeochemical and isotope geochemical features of Havran, Gönen and Ivrindi within the province capital of Balıkesir, Turkey were investigated in detail. The Early Triassic Karakaya formation in the study area of Havran forms the oldest rocks consisting of spilitic basalts, diabases, gabbros, mudstones, cherts and radiolarites. There are limestone blocks in this formation with intercalations with sandstones and with feldspar contents, quartzite, conglomerates and siltstones. Oligocene to Miocene granodiorite intrusions were generated in association with intensively volcanic events in the area. Between Upper Oligocene and Early Miocene, andesitic and dacitic pyroclastic rocks cropped out due to intensively volcanism. Later, conglomerates, sandstones, claystones, marls and limestones as lacustrine sediments formed from Middle to Upper Miocene in the study area. In the study area of Gönen, the Lower Triassic Karakaya formation consists of basalts, diabases, gabbros, mudstones, cherts and radiolarites and forms the basement rocks overlain by Upper Jurassic to Lower Cretaceous sandy limestones. Upper and Middle Miocene volcanics which can be considered intensive Biga Peninsula volcanos outcrop in the area. These andesitic lava flows are of black, gray and red color with intensive fissures. Neogene lacustrine sediments consist of conglomerates, sandstones, marl, claystone and clayey limestones. Upper Miocene to Pliocene rhyolitic pyroclastics and dacitic lava flows are the volcanic rocks which are overlain by Pliocene conglomerates, sandstones and claystones. In the study area of Ivrindi, the Çaldağ limestones are the oldest formation in Permian age. Çavdartepe metamorphic rocks are of Lower Triassic in which can be observed marbles sporadically. The Kınık formation consisting of conglomerates, sandstones, siltstones and limestones are of Lower Triassic age and display a lateral Stratigraphic progress with volcanic rocks. Upper

  2. New perspectives on the eruption of 1912 in the valley of ten thousand smokes, Katmai National Park, Alaska (United States)

    Hildreth, W.


    New data extend our understanding of the 1912 eruption, its backfilled vent complex at Novarupta, and magma-storage systems beneath adjacent stratovolcanoes. Initial Plinian rhyolite fallout is confined to a narrow downwind sector, and its maximum thickness may occur as far as 13 km from source. In contrast, the partly contemporaneous rhyolite-rich ash flows underwent relatively low-energy emplacement, their generation evidently being decoupled from the high column. Flow veneers 1-13 m thick on near-vent ridge crests exhibit a general rhyolite-to-andesite sequence like that of the much thicker valley-confined ignimbrite into which they merge downslope. Lithics in both the initial Plinian and the ignimbrite are predominantly fragments of the Jurassic Naknek Formation, which extends from the surface to a depth of ca. 1500 m. Absence of lithics from the underlying sedimentary section limits to 100 m thick near source and 10 m thick 3 km away, which dip back into an inner vent <0.5 km wide, nested inside the earlier vent funnel of the ignimbrite. The dacite fallout is poor in Naknek lithics but contains abundant fragments of vitrophyre, most of which was vent-filling, densely welded tuff reejected during later phases of the 3-day eruption. Adjacent to the inner vent, a 225-m-high asymmetrical accumulation of coarse near-vent ejecta is stratigraphically continuous with the regional dacite fallout. Distensional faulting of its crest may reflect spreading related to compaction and welding. Nearby andesite-dacite stratovolcanoes, i.e., Martin, Mageik, Trident, and Katmai, display at least 12 vents that define a linear volcanic front trending N65??E. The 1912 vent and adjacent dacite domes are disposed parallel to the front and ca. 4 km behind it. Mount Griggs, 10 km behind the front, is more potassic than other centers, taps isotopically more depleted source materials, and reflects a wholly independent magmatic plumbing system. Geochemical differences among the

  3. Glacial alteration of volcanic terrains: A chemical investigation of the Three Sisters, Oregon, USA. (United States)

    Rutledge, Alicia; Horgan, Briony; Havig, Jeff


    Glacial silica cycling is more efficient than previously reported, and in some settings, particularly glaciated mafic volcanics, can be the dominant weathering process. Based on field work at glaciated volcanic sites, we hypothesize that this is due to a combination of high rates of silica dissolution from mafic bedrock and reprecipitation of silica in the form of opaline silica coatings and other poorly crystalline silicate alteration phases. The high rate of bedrock comminution in subglacial environments results in high rates of both chemical and physical weathering, due to the increased reactive mineral surface area formed through glacial grinding. In most bedrock types, carbonate weathering is enhanced and silica fluxes are depressed in glacial outwash compared with global average riverine catchment runoff due to low temperatures and short residence times. However, in mafic systems, higher dissolved SiO2 concentrations have been observed. The major difference between observed glacial alteration of volcanic bedrock and more typical continental terrains is the absence of significant dissolved carbonate in the former. In the absence of carbonate minerals which normally dominate dissolution processes at glacier beds, carbonation of feldspar can become the dominant weathering process, which can result in a high proportion of dissolved silica fluxes in glacial outwash waters compared to the total cation flux. Mafic volcanic rocks are particularly susceptible to silica mobility, due to the high concentration of soluble minerals (i.e. plagioclase) as compared to the high concentration of insoluble quartz found in felsic rocks. To investigate melt-driven chemical weathering of mafic volcanics, water and rock samples were collected during July 2016 from glaciated volcanic bedrock in the Three Sisters Wilderness, Oregon, U.S.A. (44°9'N, 121°46'W): Collier Glacier (basaltic andesite, andesite), Hayden Glacier (andesite, dacite), and Diller Glacier (basalt). Here we

  4. Oxygen isotope geochemistry of the lassen volcanic center, California: Resolving crustal and mantle contributions to continental Arc magmatism (United States)

    Feeley, T.C.; Clynne, M.A.; Winer, G.S.; Grice, W.C.


    This study reports oxygen isotope ratios determined by laser fluorination of mineral separates (mainly plagioclase) from basaltic andesitic to rhyolitic composition volcanic rocks erupted from the Lassen Volcanic Center (LVC), northern California. Plagioclase separates from nearly all rocks have ??18O values (6.1-8.4%) higher than expected for production of the magmas by partial melting of little evolved basaltic lavas erupted in the arc front and back-arc regions of the southernmost Cascades during the late Cenozoic. Most LVC magmas must therefore contain high 18O crustal material. In this regard, the ??18O values of the volcanic rocks show strong spatial patterns, particularly for young rhyodacitic rocks that best represent unmodified partial melts of the continental crust. Rhyodacitic magmas erupted from vents located within 3.5 km of the inferred center of the LVC have consistently lower ??18 O values (average 6.3% ?? 0.1%) at given SiO2 contents relative to rocks erupted from distal vents (>7.0 km; average 7.1% ?? 0.1%). Further, magmas erupted from vents situated at transitional distances have intermediate values and span a larger range (average 6.8% ?? 0.2%). Basaltic andesitic to andesitic composition rocks show similar spatial variations, although as a group the ??18O values of these rocks are more variable and extend to higher values than the rhyodacitic rocks. These features are interpreted to reflect assimilation of heterogeneous lower continental crust by mafic magmas, followed by mixing or mingling with silicic magmas formed by partial melting of initially high 18O continental crust (??? 9.0%) increasingly hybridized by lower ??18O (???6.0%) mantle-derived basaltic magmas toward the center of the system. Mixing calculations using estimated endmember source ??18O values imply that LVC magmas contain on a molar oxygen basis approximately 42 to 4% isotopically heavy continental crust, with proportions declining in a broadly regular fashion toward the

  5. Geologic Reconnaissance of the Antelope-Ashwood Area, North-Central Oregon: With Emphasis on the John Day Formation of Late Oligocene and Early Miocene Age (United States)

    Peck, Dallas L.


    This report briefly describes the geology of an area of about 750 square miles in Jefferson, Wasco, Crook, and Wheeler Counties, Oregon. About 16,000 feet of strata that range in age from pre-Tertiary to Quaternary are exposed. These include the following units: pre-Tertiary slate, graywacke, conglomerate, and meta-andesite; Clarno Formation of Eocene age - lava flows, volcanic breccia, tuff, and tuffaceous mudstone, chiefly of andesitic composition; John Day Formation of late Oligocene and early Miocene age - pyroclastic rocks, flows, and domes, chiefly of rhyolitic composition; Columbia River Basalt of middle Miocene age - thick, columnar jointed flows of very fine grained dense dark-gray basalt; Dalles Formation of Pliocene age - bedded tuffaceous sandstone, siltstone, and conglomerate; basalt of Pliocene or Pleistocene age - lava flows of porous-textured olivine basalt; and Quaternary loess, landslide debris, and alluvium. Unconformities separate pre-Tertiary rocks and Clarno Formation, Clarno and John Day Formations, John Day Formation and Columbia River Basalt, and Columbia River Basalt and Dalles Formation. The John Day Formation, the only unit studied in detail, consists of about 4,000 feet of tuff, lapilli tuff, strongly to weakly welded rhyolite ash flows, and less abundant trachyandesite flows and rhyolite flows and domes. The formation was divided into nine mappable members in part of the area, primarily on the basis of distinctive ledge-forming welded ash-flow sheets. Most of the sheets are composed of stony rhyolite containing abundant lithophysae and sparse phenocrysts. One sheet contains 10 to 20 percent phenocrysts, mostly cryptoperthitic soda sanidine, but including less abundant quartz, myrmekitic intergrowths of quartz and sanidine, and oligoclase. The rhyolitic ash flows and lava flows were extruded from nearby vents, in contrast to some of the interbedded air-fall tuff and lapilli tuff of dacitic and andesitic composition that may have been

  6. Development of Waterfall Cliff Face: An Implication from Multitemporal High-definition Topographic Data (United States)

    Hayakawa, Y. S.; Obanawa, H.


    Bedrock knickpoints (waterfalls) often act as erosional front in bedrock rivers, whose geomorphological processes are various. In waterfalls with vertical cliffs, both fluvial erosion and mass movement are feasible to form the landscape. Although morphological changes of such steep cliffs are sometimes visually observed, quantitative and precise measurements of their spatiotemporal distribution have been limited due to poor accessibility to such cliffs. For the clarification of geomorphological processes in such cliffs, multi-temporal mapping of the cliff face at a high resolution can be advantaged by short-range remote sensing approaches. Here we carry out multi-temporal terrestrial laser scanning (TLS), as well as structure-from-motion multi-view stereo (SfM-MVS) photogrammetry based on unmanned aerial system (UAS) for accurate topographic mapping of cliffs around a waterfall. The study site is Kegon Falls in central Japan, having a vertical drop of surface water from top of its overhanging cliff and groundwater outflows from its lower portions. The bedrock consists of alternate layers of jointed andesite lava and conglomerates. The latest major rockfall in 1986 caused approximately 8-m recession of the waterfall lip. Three-dimensional changes of the rock surface were detected by multi-temporal measurements by TLS over years, showing the portions of small rockfalls and surface lowering in the bedrock. Erosion was frequently observed in relatively weak the conglomerates layer, whereas small rockfalls were often found in the andesite layers. Wider areas of the waterfall and cliff were also measured by UAS-based SfM-MVS photogrammetry, improving the mapping quality of the cliff morphology. Point clouds are also projected on a vertical plane to generate a digital elevation model (DEM), and cross-sectional profiles extracted from the DEM indicate the presence of a distinct, 5-10-m deep depression in the cliff face. This appears to have been formed by freeze-thaw and

  7. Mafic enclaves in dacitic domes and their relation with La Poruña scoria cone, Central Andes, northern Chile (United States)

    González-Maurel, O. P.; Gallmeyer, G.; Godoy, B.; Menzies, A.; le Roux, P. J.; Harris, C.


    Chao Dacite, Chillahuita, Cerro Pabellón, Chanka, Chac-Inca, and Cerro La Torta (or Tocorpuri) are dacitic domes of late Pleistocene age (30 to 140 ka; Renzulli et al., 2006; Tierney et al., 2016) located in Northern Chilean Central Andean province (NCCA; 17°20'S - 27°40'S). While, La Poruña is a 180 m high basaltic-andesite scoria cone erupted ca. 100 ka (Wörner et al., 2000). This scoria cone is also located at the NCCA, 26 km to the SW of Chanka and 45 km to the NW of Chao Dacite. The dacitic domes are generally porphyritic and highly crystalline lavas (30 - 50 vol % phenocrysts, plagioclase > biotite > amphibole > quartz ≥ accessory), with hyalopilitic or intersertal groundmass. These domes contain mafic enclaves, mostly andesite in composition, with plagioclase > amphibole > biotite ≥ clinopyroxene ≥ olivine ≥ accessory phenocryst (10 - 20 vol %) in a lightly oxidized groundmass with intersertal or intergranular textures. In contrast, La Poruña rocks are mostly aphanitic (75 - 85 vol % groundmass) and highly vesicular, with plagioclase > olivine ≥ clinopyroxene ≥ orthopyroxene phenocrysts in an intersertal or hyalopilitic groundmass. Although petrographically different, the composition (57 wt % SiO2; 580 ppm Sr, 87Sr/86Sr = 0.7066) of mafic enclaves from Cerro Pabellón dome are similar to the lava flows and pyroclastic blocks of La Poruña scoria cone (55 - 59 wt % SiO2; 560 - 610 ppm Sr; 0.7062 - 0.7066 87Sr/86Sr). Based on this data and the eruption ages of these volcanic structures, we suggest that the mafic enclaves and La Poruña magmas are co-genetic. Thus, we propose that the genesis of these mafic enclaves is associated with the origin of less evolved parental magmas erupted in the NCCA, such as those from La Poruña. In this case, the mafic enclaves would represent batches of less evolved magmas that ascended from deeper sources and probably contributed in the eruption of the dacitic domes. Renzulli et al., 2006. In XI Congreso Geol

  8. Contributions to the petrography, geochemistry and geochronology (U-Pb and Sm-Nd) of the Paleoproterozoic effusive rocks from Iricoume Group, Amazonian Craton, Brazil

    Energy Technology Data Exchange (ETDEWEB)

    Marques, Suelen Nonata de Souza; Nascimento, Rielva Solimairy Campelo do, E-mail:, E-mail: [Universidade Federal do Amazonas (UFAM), Manaus, AM (Brazil). Inst. de Geociencias; Souza, Valmir da Silva; Dantas, Elton Luiz, E-mail:, E-mail: [Universidade de Brasilia (UnB), DF (Brazil). Inst. de Geociencias; Valerio, Cristovao da Silva, E-mail: [Universidade Federal de Roraima (UFRR), Boa Vista, RR (Brazil). Inst. de Geociencias


    The southernmost region of the Guyana shield, Amazonian craton, hosts large record of Paleoproterozoic effusive rocks of the Iricoume Group. They present remarkably well-preserved igneous textures and structures. The SiO{sub 2} contents reveal a bimodal association marked by a compositional gap between acid (SiO{sub 2} > 67 wt%) and intermediate (SiO{sub 2} < 57.7 wt%) rocks. The acid effusive rocks are rhyolites to rhyodacites with high SiO{sub 2}, alkali, Rb, Zr, Nb + Ta, La + Ce and 104 Ga/Al content and low Fe{sub 2}O{sub 3tot}, TiO{sub 2}, CaO, Sr and Co content. They exhibit subalkaline, metaluminous-to-peraluminous compositions, and geochemically compatible to A-type magmatism emplaced in post-collisional to within-plate tectonic settings. The intermediate rocks are andesitic/basalt to andesite relatively high contents of TiO{sub 2}, Al{sub 2}O{sub 3}, Fe{sub 2}O{sub 3total}, MgO, CaO, Sr and Co; low SiO{sub 2}, K{sub 2}O, Rb, Zr, Nb + Ta, La + Ce. They have subalkaline and metaluminous geochemical composition and plot on within-plate basalt field. The acid rocks crystallized at 1882 ± 11 Ma in U-Pb analyses for LA-MC-ICPMS zircon data. The Sm-Nd isotopic data on all rocks reveal a Nd TDM model ages between 2.59 and 2.16 Ga and ε{sub Nd}(t) values between -5.78 and 0.03, indicate that the magmatic evolution was related to the reworking of older Paleoproterozoic at the Rhyacian-Siderian period, continental crust (Transamazonian crust-forming event) with some mixing with a limited amount mantle-derived magmas or with contamination by Archean crust. The petrographic, geochemical and geochronological data presented in this paper suggest a within-plate to post-collisional tectonic setting for the Iricoume volcanism, involving lower crust uplift and generation of basalt magma in an extensional regime. (author)

  9. Late Miocene Debris-Avalanche Deposit At The Gutai Shield Volcano, NW Romania. Re- Evaluation Of Geological Mapping And Mineral Deposits (United States)

    Seghedi, I.; Fülöp, A.


    The recent identification of debris avalanche deposits (DADs) originating from the southern edge of the Ignis peak (1306m, highest of the Gutai Mts.) has important implications for understanding its genesis in the geological context of the broader area, rich in hydrothermal intrusive-related base metal and gold-silver deposits closely connected to the Dragos Voda - Bogdan Voda strike-slip fault system. Pyroxene andesite lavas are exposed below the Ignis peak followed by hornblende and pyroxene andesites the only ones found in the DAD. The flank failure event has left an E-W-oriented horseshoe shaped scar with an estimated volume of material removed of at least 0.35 km3 and an estimated area covered by DADs of 4,345 km2 as a minimum. The deposit is a mega breccia with a variable amount of coarse matrix with jigsaw-fractured blocks, large boulders, and several southward-elongated hummocks up to 1.8 km distance from the scar. Between 720-850 m altitude the DADs contain megablocks of 5-12 m thick and up to 100 m long of layered fine-grained poorly consolidated pyroclastic materials of interlayered ash and lapillistone of fallout origin, and clay beds rich in vegetation remnants(known as the 'Chiuzbaia flora' of similar age as the surrounding lava flows, i.e. ca. 10-7 Ma) and diatoms. These megablocks found in various positions, suggest a lithological discontinuity likely representing the detachment surface of the gravity-driven instability phenomenon and the deep excavation of the volcano flank by the sector collapse event. The clayey material of these blocks acted probably as an efficient barrier to water infiltration and helped destabilization of the overlying rock mass. Since no explosive products have been observed to follow the DAD, it is possible that the sliding was triggered by pressure release of hydrothermal system along an E-W fault parallel to the Dragos Voda-Bogdan Voda fault system, with related high-grade ore deposits. This suggests the possible presence

  10. Hydroxyl and molecular H2O diffusivity in a haploandesitic melt (United States)

    Ni, Huaiwei; Xu, Zhengjiu; Zhang, Youxue


    H2O diffusion in a haploandesitic melt (a high-silica and Fe-free andesitic melt, NBO/T = 0.173) has been investigated at 1 GPa in a piston-cylinder apparatus. We adopted a double diffusion couple technique, in which one couple was composed of a nominally anhydrous glass with 0.01 wt.% H2O and a hydrous glass with 5.7 wt.% H2O, and the other contained the same nominally anhydrous glass and a hydrous glass with 3.3 wt.% H2O. Both couples were annealed in a single experimental run and hence experienced exactly the same P-T history, which is crucial for constraining the dependence of H2O diffusivity on water content. H2O concentration profiles were measured by both Fourier transform infrared (FTIR) microspectroscopy and confocal Raman microspectroscopy. Nearly identical profiles were obtained from Raman and FTIR methods for profile length >1 mm (produced at 1619-1842 K). By contrast, for profile lengths <100 μm (produced at 668-768 K), FTIR profiles show marked convolution effects compared to Raman profiles. A comparison between the short FTIR and Raman profiles indicates that the real spatial resolution (FWHM) of FTIR analyses is about 28 μm for a 7 μm wide aperture on ˜200 μm thick glasses. While the short profiles are not reliable for quantitative modeling, the long diffusion profiles at superliquidus temperatures can be fit reasonably well by a diffusivity model previously developed for felsic melts, in which molecular H2O (H2Om) is the only diffusive species and its diffusivity (D) increases exponentially with the content of total water (H2Ot). However, there is noticeable misfit of the data at low H2Ot concentrations, suggesting that OH diffusivity (DOH) cannot be neglected in this andesitic melt at high temperatures and low water contents. We hence develop a new fitting procedure that simultaneously fits both diffusion profiles from a single experimental run and accounts for the roles of both OH and H2Om diffusion. With this procedure, DOH/D is constrained

  11. Localities With Elevated Radiation Background in the High Karst Zone of Montenegro

    International Nuclear Information System (INIS)

    Vukotic, P.; Svrkota, R.; Andjelic, T.; Zekic, R.; Antovic, N.


    Research aimed to find localities in Montenegro with an elevated terrestrial gamma background was conducted during the period 2008-2009. For this purpose, 138 localities which have geological formations known to contain minerals with potentially high concentrations of U, Th and K, were selected throughout the country for a dosimetric survey. There are four distinctive geotectonic units in Montenegro: the Adriatic-Ionian Zone (JZ), the Budva-Cukali Zone (BZ), the High Karst Zone (VK), and the Durmitor Tectonic Unit (DTJ). The central and southern parts of Montenegro belong to the VK zone, whose geological structure is predominated by Mesozoic carbonate sediments, with occurrences of red and white bauxite formations, Triassic volcanic rocks, Paleogene flysch sediments and Quaternary sediments. In total, 38 localities belonging to the VK zone were selected for field investigations of terrestrial radiation. Knowing from earlier investigations that in Montenegro the average absorbed dose-rate in the air, 1 m above the ground, is 55 nGy/h, it was arbitrarily adopted that only localities with absorbed doses at least 50 % above this average value would be considered as having a relatively elevated radiation background. Field measurements have shown that 12 of the surveyed localities in the VK zone have such elevated dose values, five of them being with the highest dose rates in Montenegro. Among these five sites, the highest dose rate (192 nGy/h) was found at a locality which lies on andesite volcanic rock, while the other four localities (131 - 149 nGy/h) lie on bauxite deposits. Compared to the other areas in the world known to have a high natural radiation background, all of these localities in Montenegro have a moderately elevated radiation level. From the 12 localities with a relatively elevated radiation background, soil samples have been collected and analyzed by gamma spectrometry to determine activity concentrations of 40K, 232Th, 235U, 238U, 226Ra and 137Cs

  12. Carboniferous volcanic rocks associated with back-arc extension in the western Chinese Tianshan, NW China: Insight from temporal-spatial character, petrogenesis and tectonic significance (United States)

    Su, Wenbo; Cai, Keda; Sun, Min; Wan, Bo; Wang, Xiangsong; Bao, Zihe; Xiao, Wenjiao


    The Yili-Central Tianshan Block, as a Late Paleozoic major continental silver of the Central Asian Orogenic Belt, holds a massive volume of Carboniferous volcanic rocks, occurring as subparallel magmatic belts. However, the petrogenesis and tectonic implications of these volcanic rocks remain enigmatic. This study compiled isotopic age data for mapping their temporal-spatial character, and conducted petrogenetic study of these magmatic belts, aiming to understand their tectonic implications. Our compiled dataset reveals four magmatic belts in the Yili-Central Tianshan Block, including the Keguqinshan-Tulasu belt and the Awulale belt in the north, and the Wusun Mountain belt and the Haerk-Nalati belt in the south. In addition, our new zircon U-Pb dating results define two significant Early Carboniferous eruptive events (ca. 355-350 Ma and 325 Ma) in the Wusun Mountain belt. Volcanic rocks of the early significant eruptive event (ca. 355-350 Ma) in the Wusun Mountain comprise basalt, trachy-andesite, andesite, dacite and rhyolite, which are similar to the typical rock assemblage of a continental arc. Their positive εNd(t) values (+0.3 to +1.5) and relatively high Th/Yb and Nb/Yb ratios suggest the derivation from a mantle source with additions of slab-derived components. The gabbroic dykes and rhyolites of the late volcanic event (ca. 325 Ma) form a bimodal rock association, and they show alkaline features, with relatively low Th/Yb and Th/Nb ratios, and higher positive εNd(t) values (εNd(t) = +3.3-+5.0). It is interpreted that the gabbroic dykes and rhyolites may have been derived from mantle and juvenile crustal sources, respectively. The isotopic and trace elemental variations with time elapse of the Wusun Mountain magmatic belt show an important clue for strengthening depletion of the magma sources. Considering the distinctive temporal-spatial character of the Carboniferous volcanic rocks, two separate subduction systems in the southern and northern margins of

  13. The Massive Compound Cofre de Perote Shield Volcano: a Volcanological Oddity in the Eastern Mexican Volcanic Belt (United States)

    Siebert, L.; Carrasco-Nunez, G.; Diaz-Castellon, R.; Rodriguez, J. L.


    Cofre de Perote volcano anchors the northern end of the easternmost of several volcanic chains orthogonal to the E-W trend of the Mexican Volcanic Belt (MVB). Its structure, geochemistry, and volcanic history diverge significantly from that of the large dominantly andesitic stratovolcanoes that have been the major focus of research efforts in the MVB. Andesitic-trachyandesitic to dacitic-trachydacitic effusive activity has predominated at Cofre de Perote, forming a massive low-angle compound shield volcano that dwarfs the more typical smaller shield volcanoes of the central and western MVB. The 4282-m-high volcano overlooking Xalapa, the capital city of the State of Veracruz, has a diameter of about 30 km and rises more than 3000 m above the coastal plain to the east. Repeated edifice collapse has left massive horseshoe-shaped scarps that truncate the eastern side of the edifice. Five major evolutionary stages characterize the growth of this compound volcano: 1) emplacement of a multiple-vent dome complex forming the basal structure of Cofre de Perote around 1.9-1.3 Ma; 2) construction of the basal part of the compound shield volcano from at least two main upper-edifice vents at about 400 ka; 3) effusion of the summit dome-like lavas through multiple vents at ca. 240 ka; 4) eruption of a large number of geochemically diverse, alkaline and calc-alkaline Pleistocene-to-Holocene monogenetic cones (likely related to regional volcanism) through the flanks of the Cofre de Perote edifice; 5) late-stage, large-volume edifice collapse on at least two occasions (ca. 40 ka and ca. 10 ka), producing long-runout debris avalanches that traveled to the east. An undated tephra layer from Cofre de Perote overlies deposits likely of the youngest collapse. Cofre de Perote is one of several volcanoes in the roughly N-S-trending chain that has undergone major edifice collapse. As with Citlaltepetl (Pico de Orizaba) and Las Cumbres volcanoes, Cofre de Perote was constructed at the

  14. Miocene shoshonite volcanism in Sardinia: Implications for magma sources and geodynamic evolution of the central-western Mediterranean (United States)

    Beccaluva, Luigi; Bianchini, Gianluca; Mameli, Paola; Natali, Claudio


    In this paper we document the existence of a Miocene shoshonite (SHO) volcanism in Northern Sardinia (Anglona). This occurrence completes the spectrum of orogenic magmas related to the subduction process which developed from the Eocene along the Palaeo-European continental margin, in concert with the opening of the Ligurian-Balearic back-arc basin and southeastward drift/rotation of the Sardinia-Corsica continental block. K-Ar ages show that the oldest volcanics of the area are calcalkaline (CA) basalts and andesites (~ 21 Ma), overlain by 19.7-18.4 Ma-old more potassic products such as high-potassium calcalkaline (HK-CA) and SHO lavas. CA, HK-CA and SHO suites include basalts and differentiated lavas of andesite and latite composition, respectively, that (according to the PELE software modelling) represent ~ 40-45% residual liquid fraction after shallow fractional crystallization. Application of the "Arc Magma Simulator" software suggests that the generation of primary melts of the distinct suites may occur at similar degrees of partial melting (5-8%) and melting pressures (2-2.2 GPa, ~ 60-70 km depth) in the mantle wedge. By contrast, the potassic character of parental melts of CA, HK-CA and SHO suites is controlled by 1) the amount of subducted continental components (possibly terrigenous sediments) and 2) the pressure (depth) at which these metasomatic agents are released from the slab. Results suggest that the slab depth beneath the volcanic district increased from ~ 80-100 to 100-120 km for CA and SHO magmas, respectively. Accordingly, the evolution from CA to SHO magmatism in the same plumbing system could be related to slab deepening and increase of the subduction angle of ~ 5-10° in the time span of 2-3 Ma. This tectono-magmatic scenario conforms to the major anticlockwise rotation (~ 30°) event of the Sardinia block (between 20.5 and 18 Ma). This geodynamic evolution preludes the development of the volcanism in the Apennine-Tyrrhenian domains, where the

  15. Amphibole stability using new thermobarometric formulations on calc-alkaline magmas of Volcán Doña Inés, Chile (United States)

    Hines, R. A.; Walker, J. A.


    Location and delineation of subvolcanic magma chambers have heavily relied on geophysical, particularly seismic, data. However, new and improved thermobarometric formulations can yield equally important constraints on the depths and conditions of magmatic storage and movement. The objective of this study was to utilize the single phase thermobarometric algorithms of Ridolfi et al. (2010) to determine the conditions of amphibole stability in the volcanic system beneath Volcán Doña Inés, a large stratovolcano from the Mid-Late Miocene magmatic arc in the Central Volcanic Zone of the Andes, Chile. According to Moulds (1989), Doña Inés had three main eruptive vents: the main central vent; a second vent low on its flanks, called Loma Doña Inés; and a sister cone, called Gemelas. The barometric, thermometric, hygrometric, and oxygen fugacity formulations of Ridolfi et al. (2010) are based on the total aluminum (AlT) content, the silicon index (Si*), the octahedral aluminum index ([6]Al*), and the magnesium index (Mg*) of the amphibole grains, respectively. For this study, 120 amphiboles from 20 andesite-dacite samples from Doña Inés were analyzed approximately 30 times per grain with an electron microprobe. Amphibole compositions range from tschermakitic pargasite, to magnesiohornblende, to magnesiohastingsite, with the central vent crystals exhibiting the widest variability. Preliminary results from the thermobarometer indicate that amphibole crystallization beneath the central vent occurred between 213-928 ± 102 MPa and 872-1016 ± 22 *C, with magmatic water contents of approximately 5.2-9.9 ± 1.5 wt%. Conditions of formation of amphibole at Loma Doña Inés were between 230-405 ± 37 MPa and 901-980 ± 22 *C, with approximately 5.4-6.2 ± 0.9 wt% magmatic H2O and were similar at the sister cone Gemelas: 259-309 ± 34 MPa, 902-952 ± 22 *C, and 5.1-6.2 ± 0.9 wt% magmatic H2O. Temperatures obtained from amphibole stability agree well with the previous from

  16. The Riscos Bayos Ignimbrites of the Caviahue-Copahue volcanic caldera complex, southern Andes, Argentina (United States)

    Colvin, A.; Merrill, M.; Demoor, M.; Goss, A.; Varekamp, J. C.


    The Caviahue-Copahue volcanic complex (38 S, 70 W) is located on the eastern margin of the active arc in the southern Andes, Argentina. Volcán Copahue, an active stratovolcano which hosts an active hydrothermal system, sits on the southwestern rim of the elliptical Caviahue megacaldera (17 x 15 km). The caldera wall sequences are up to 0.6 km thick and consist of lavas with 51 -69 percent SiO2 and 0.2 - 5 percent MgO as well as breccias, dikes, sills, domes and minor ignimbrites. Andesitic lava flows also occur within the caldera, and are overlain by a chaotic complex of silicic lava and intracaldera pyroclastic flow deposits. The eastern wall sequence is capped by several extracaldera ignimbrites (Riscos Bayos formation) of about 50 m maximum thickness which extend 30 km east-southeast of the caldera. Young back-arc alkali basalt scoria cones occur east of the Caviahue-Copahue volcanic complex. The eruption of the Riscos Bayos formation at about 1.1 Ma (12 km cubed) may be related to the Caviahue caldera formation, though the Riscos Bayos account for only about 7 percent of the caldera volume. The Riscos Bayos consists of three lithic-bearing flow units: a grey basal flow, a tan middle flow and a bright-white, highly indurated uppermost flow. The basal unit consists of white and grey pumice fragments, black scoria clasts, black obsidian clasts (which give it the grey color), and accidental volcanic lithics set in a matrix of ash and crystals. The middle unit is composed of large mauve pumice fragments and accidental lithics set in a fine tan ash groundmass. The uppermost unit is composed of small pink and white pumice fragments set in a matrix of fine white ash. These pumices carry quartz and biotite crystals, whereas the lower two units are orthopyroxene-bearing trachy-dacites. The Caviahue-Copahue magmas all bear arc signatures, but possibly some magma mixing between the andesitic arc magmas and basaltic back-arc magmas may have occurred. The evolved top layer

  17. U-series in zircon and 40Ar/39Ar geochronology reveal the most recent stage of a supervolcanic cycle in the Altiplano-Puna Volcanic Complex, Central Andes (United States)

    Tierney, C.; de Silva, S. L.; Schmitt, A. K.; Jicha, B.; Singer, B. S.


    peaks in zircon crystallization ages could result from periodic injections of andesitic magma that reinvigorated crystallization. However, the ubiquity of likely antecrystic zircon interiors suggests that the associated temperature rise was insufficient to cause complete resorbtion of the antecrysts. A shared peak of zircon crystallization just prior to eruptions, as well as co-eruption of andesitic lava connotes recharge as the eruption trigger.

  18. Carboniferous-Permian tectonic transition envisaged in two magmatic episodes at the Kuruer Cu-Au deposit, Western Tianshan (NW China) (United States)

    Yu, Jie; Li, Nuo; Qi, Nan; Guo, Jian-Ping; Chen, Yan-Jing


    The Western Tianshan in NW China is one of the most important gold provinces in the Central Asian Orogenic Belt (CAOB). The recently discovered Kuruer Cu-Au deposit has been interpreted to represent a transition from high-sulfidation epithermal to porphyry mineralization system. In this study, we present new LA-ICP-MS zircon U-Pb ages for the many magmatic rock types at Kuruer, including the Dahalajunshan Formation andesitic tuff (333.2 ± 1.6 Ma), diorite porphyry (269.7 ± 2.0 Ma), slightly-altered (264.4 ± 2.6 Ma) and intensively-altered (270.5 ± 2.5 Ma) albite porphyry. These ages reveal two distinct magmatic episodes: The Early Carboniferous Dahalajunshan Formation (wall rocks) andesitic tuff samples contain narrow ranges of SiO2 (60.29-61.28 wt.%), TiO2 (0.96-0.98 wt.%), Al2O3 (16.55-16.57 wt.%) and Fe2O3T (5.36-5.57 wt.%). The tuff is characterized by LREE enrichment and HFSE depletion, as well as LREE/HREE enrichment ((La/Yb)N = 8.31-8.76) and negative Eu anomalies (δEu = 0.64-0.76). Zircon εHf (t) values are 5.4-8.2, and two-stage Hf model ages (TDM2) are 821-1016 Ma, indicating partial melting of a moderately depleted mantle wedge with Precambrian continental crustal input. The ore-forming Middle Permian diorite porphyry and (quartz) albite porphyry have variable major oxide compositions (e.g., SiO2 = 53.09-53.12 wt.% for the diorite porphyry, 70.84-78.03 wt.% for the albite porphyry, and 74.07-75.03 wt.% for the quartz albite porphyry) but similar chondrite-normalized REE and primitive mantle-normalized multi-element patterns. These porphyries display LREE enrichment and HFSE depletion, as well as elevated LREE/HREE enrichment and negative Eu anomalies. The positive zircon εHf(t) values (11.7-15.9 for the diorite porphyry, 8.9-14.9 for the albite porphyry) and young two-stage Hf model ages (TDM2) (282-542 Ma for the diorite porphyry, 337-717 Ma for the albite porphyry) indicate a major juvenile continental crustal involvement. We propose that the

  19. The newly-discovered Late Cretaceous igneous rocks in the Nuocang district: Products of ancient crust melting trigged by Neo-Tethyan slab rollback in the western Gangdese (United States)

    Jiang, Jun-Sheng; Zheng, You-Ye; Gao, Shun-Bao; Zhang, Yong-Chao; Huang, Jian; Liu, Jun; Wu, Song; Xu, Jing; Huang, Liang-Liang


    The newly discovered polymetallic Nuocang Pb-Zn skarn deposit is located in the southern Lhasa subterrane, western Gangdese, Tibet. The orebodies occur primarily at the contact zone between the Angjie Formation and the Linzizong volcanic rocks of Dianzhong Formation (LDF) that are dominated by basaltic andesitic tuff and rhyolite. Zircon U-Pb dating for two granite porphyries yield ages of 72.4 ± 0.2 Ma and 73.4 ± 0.9 Ma, which are different from the ages ( 69-60 Ma) of the LDF in the eastern Gangdese. The basaltic andesite tuff at Nuocang exhibits enrichment of MgO, TiO2, LILE, and LREE, with a relative depletion of SiO2, K2O, HFSE, and HREE, low Sr/Y ratios (32.9-38.0), and weak negative Eu anomalies (mean 0.86). They have 87Sr/86Sr(i) from 0.70695 to 0.70807 and εNd(t) values between -4.3 and -5.9. These features are similar to the Linzizong volcanic rocks of Dianzhong Formation in the Linzhou basin, indicating that they were associated with partial melting of mantle wedge mixing with 25-35% ancient Lhasa terrane basement. The rhyolite and granite porphyry show high SiO2 and K2O, and low Sr/Y ratio (1.2-9.9), enrichment of LILE and LREE and strong depletion of the HFSEs. They have pronounced negative Eu anomalies (mean 0.46), and εHf (t) values of the granite porphyry zircons range from -22.0 to -6.0. All these features suggest that they are the product of anatexis of ancient crustal materials heated by mantle-derived magma, the latter derived from Neo-Tethyan slab dehydration mechanisms. Combined with the previous geochronological and geochemical data, we proposed that the Nuocang district of western Gangdese in the southern Lhasa subterrane contains an ancient block, and the igneous rocks here were triggered by the Neo-Tethyan slab rollback starting at 82 Ma. The western Gangdese contains more ancient continental crustal materials and Late Cretaceous-Eocene Linzizong volcanic rocks and coeval intrusions than in the eastern Gangdese. Thus the western

  20. A holistic model for the role of the axial melt lens at fast-spreading mid-ocean ridges (United States)

    MacLeod, C. J.; Loocke, M. P.; Lissenberg, J. C. J.


    Axial melt lenses (AML) are melt or crystal mush1 bodies located at the dyke-gabbro transition beneath intermediate- and fast-spreading mid-ocean ridges (MORs)2,3. Although it is generally thought that AMLs play a major role in the storage and differentiation of mid-ocean ridge basalts (MORB)1, the melt compositions within the AML and its role in the accretion of the lower crust are heavily debated4-6. Here we present the first comprehensive study of the AML horizon at a fast-spreading MOR (Hess Deep, equatorial Pacific Ocean). We show that plagioclase and pyroxene within the AML are much too evolved to be in equilibrium with MORB, with mean An (54.85) and Mg# (65.01) consistent with derivation from basaltic andesite to andesite melts (Mg# 43-26). We propose that, in between decadal eruptions, the AML is predominantly crystal mush and is fed by small volumes of evolved interstitial melts. Short-lived, focused injection of primitive melt leads to mixing of primitive melts with the extant highly fractionated melt, and triggers eruptions. This model reconciles the paradoxical compositional mismatch between the volcanic and plutonic records with the geophysical characteristics of the AML, the short residence times of Pacific MORB phenocrysts, and the incompatible trace element over-enrichments in MORB. 1Marjanović, M. et al., 2015. Distribution of melt along the East Pacific Rise from 9°30' to 10°N from an amplitude variation with angle of incidence (AVA) technique. Geophys. J. Int. 203. 2Detrick, R. S. et al., 1987. Multi-channel seismic imaging of a crustal magma chamber along the EPR. Nature 326. 3Sinton, J. M. & Detrick, R. S., 1992. Mid-ocean ridge magma chambers. J. Geophys. Res. 97. 4Coogan, L. A., Thompson, G. & MacLeod, C. J., 2002. A textural and geochemical investigation of high level gabbros from the Oman ophiolite: implications for the role of the axial magma chamber at fast-spreading ridges. Lithos 63. 5Pan, Y. & Batiza, R., 2002. Mid-ocean ridge magma

  1. Revised preliminary geologic map of the Rifle Quadrangle, Garfield County, Colorado (United States)

    Shroba, R.R.; Scott, R.B.


    andesitic conglomerate clasts abundant in the upper part of the Atwell Gulch Member was Late Cretaceous-Early Tertiary andesitic igneous rocks, remnants of which are present southeast of the Piceance Basin (Tweto, 1979). Thinning of the Atwell Gulch and Molina Members to the northwest also suggests a southeastern source of sediments, ruling out a northeastern source related to earlier deformation of the Upper Cretaceous Mesa Verde Group.

  2. Philippine Sea Plate inception, evolution, and consumption with special emphasis on the early stages of Izu-Bonin-Mariana subduction (United States)

    Lallemand, Serge


    We compiled the most relevant data acquired throughout the Philippine Sea Plate (PSP) from the early expeditions to the most recent. We also analyzed the various explanatory models in light of this updated dataset. The following main conclusions are discussed in this study. (1) The Izanagi slab detachment beneath the East Asia margin around 60-55 Ma likely triggered the Oki-Daito plume occurrence, Mesozoic proto-PSP splitting, shortening and then failure across the paleo-transform boundary between the proto-PSP and the Pacific Plate, Izu-Bonin-Mariana subduction initiation and ultimately PSP inception. (2) The initial splitting phase of the composite proto-PSP under the plume influence at ˜54-48 Ma led to the formation of the long-lived West Philippine Basin and short-lived oceanic basins, part of whose crust has been ambiguously called "fore-arc basalts" (FABs). (3) Shortening across the paleo-transform boundary evolved into thrusting within the Pacific Plate at ˜52-50 Ma, allowing it to subduct beneath the newly formed PSP, which was composed of an alternance of thick Mesozoic terranes and thin oceanic lithosphere. (4) The first magmas rising from the shallow mantle corner, after being hydrated by the subducting Pacific crust beneath the young oceanic crust near the upper plate spreading centers at ˜49-48 Ma were boninites. Both the so-called FABs and the boninites formed at a significant distance from the incipient trench, not in a fore-arc position as previously claimed. The magmas erupted for 15 m.y. in some places, probably near the intersections between back-arc spreading centers and the arc. (5) As the Pacific crust reached greater depths and the oceanic basins cooled and thickened at ˜44-45 Ma, the composition of the lavas evolved into high-Mg andesites and then arc tholeiites and calc-alkaline andesites. (6) Tectonic erosion processes removed about 150-200 km of frontal margin during the Neogene, consuming most or all of the Pacific ophiolite

  3. The isotopic and chemical evolution of Mount St. Helens

    International Nuclear Information System (INIS)

    Halliday, A.N.; Fallick, A.E.; Dickin, A.P.; Mackenzie, A.B.; Stephens, W.E.


    Isotopic and major and trace element analysis of nine samples of eruptive products spanning the history of the Mt. St. Helens volcano suggest three different episodes; (1) 40,000-2500 years ago: eruptions of dacite with epsilonsub(Nd) = +5, epsilonsub(Sr) = -10, variable delta 18 O, 206 Pb/ 204 Pb approx.= 18.76, Ca/Sr approx.= 60, Rb/Ba- approx.= 0.1, La/Yb approx.= 18, (2) 2500-1000 years ago: eruptions of basalt, andesite and dacite with epsilonsub(Nd) = +4 to + 8, epsilonsub(Sr) = -7 to -22, variable delta 18 O (thought to represent melting of differing mantle-crust reservoirs), 206 Pb/ 204 Pb = 18.81-18.87, variable Ca/Sr, Rb/Ba, La/Yb and high Zr, (3) 1000 years ago to present day: eruptions of andesite and dacite with epsilonsub(Nd) = + 6, epsilonsub(Sr) = -13, delta 18 O approx.= 6per mille, variable 206 Pb/ 204 Pb, Ca/Sr approx.= 77, Rb/Ba = 0.1, La/Yb approx.= 11. None of the products exhibit Eu anomalies and all are LREE enriched. There is a strong correlation between 87 Sr/ 86 Sr and differentiation indices. These data are interpreted in terms of a mantle heat source melting young crust bearing zircon and garnet, but not feldspar, followed by intrusion of this crustal reservoir by mantle-derived magma which caused further crustal melting and contaminated the crustal magma system with mafic components. Since 1000 years ago all the eruptions have been from the same reservoir which has displayed a much more gradual re-equilibration of Pb isotopic compositions than other components suggesting that Pb is being transported via a fluid phase. The Nd and Sr isotopic compositions lie along the mantle array and suggest that the mantle underneath Mt. St. Helens is not as depleted as MORB sources. There is no indication of seawater involvement in the source region. (orig.)

  4. The origin of high-Mg magmas in Mt Shasta and Medicine Lake volcanoes, Cascade Arc (California): higher and lower than mantle oxygen isotope signatures attributed to current and past subduction (United States)

    Martin, E.; Bindeman, I.; Grove, T. L.


    We report the oxygen isotope composition of olivine and orthopyroxene phenocrysts in lavas from the main magma types at Mt Shasta and Medicine Lake Volcanoes: primitive high-alumina olivine tholeiite (HAOT), basaltic andesites (BA), primitive magnesian andesites (PMA), and dacites. The most primitive HAOT (MgO > 9 wt%) from Mt. Shasta has olivine δ18O (δ18OOl) values of 5.9-6.1‰, which are about 1‰ higher than those observed in olivine from normal mantle-derived magmas. In contrast, HAOT lavas from Medicine Lake have δ18OOl values ranging from 4.7 to 5.5‰, which are similar to or lower than values for olivine in equilibrium with mantle-derived magmas. Other magma types from both volcanoes show intermediate δ18OOl values. The oxygen isotope composition of the most magnesian lavas cannot be explained by crustal contamination and the trace element composition of olivine phenocrysts precludes a pyroxenitic mantle source. Therefore, the high and variable δ18OOl signature of the most magnesian samples studied (HAOT and BA) comes from the peridotitic mantle wedge itself. As HAOT magma is generated by anhydrous adiabatic partial melting of the shallow mantle, its 1.4‰ range in δ18OOl reflects a heterogeneous composition of the shallow mantle source that has been influenced by subduction fluids and/or melts sometime in the past. Magmas generated in the mantle wedge by flux melting due to modern subduction fluids, as exemplified by BA and probably PMA, display more homogeneous composition with only 0.5‰ variation. The high-δ18O values observed in magnesian lavas, and principally in the HAOT, are difficult to explain by a single-stage flux-melting process in the mantle wedge above the modern subduction zone and require a mantle source enriched in 18O. It is here explained by flow of older, pre-enriched portions of the mantle through the slab window beneath the South Cascades.

  5. Reservoir characteristics and control factors of Carboniferous volcanic gas reservoirs in the Dixi area of Junggar Basin, China

    Directory of Open Access Journals (Sweden)

    Ji'an Shi


    Full Text Available Field outcrop observation, drilling core description, thin-section analysis, SEM analysis, and geochemistry, indicate that Dixi area of Carboniferous volcanic rock gas reservoir belongs to the volcanic rock oil reservoir of the authigenic gas reservoir. The source rocks make contact with volcanic rock reservoir directly or by fault, and having the characteristics of near source accumulation. The volcanic rock reservoir rocks mainly consist of acidic rhyolite and dacite, intermediate andesite, basic basalt and volcanic breccia: (1 Acidic rhyolite and dacite reservoirs are developed in the middle-lower part of the structure, have suffered strong denudation effect, and the secondary pores have formed in the weathering and tectonic burial stages, but primary pores are not developed within the early diagenesis stage. Average porosity is only at 8%, and the maximum porosity is at 13.5%, with oil and gas accumulation showing poor performance. (2 Intermediate andesite and basic basalt reservoirs are mainly distributed near the crater, which resembles the size of and suggests a volcanic eruption. Primary pores are formed in the early diagenetic stage, secondary pores developed in weathering and erosion transformation stage, and secondary fractures formed in the tectonic burial stage. The average porosity is at 9.2%, and the maximum porosity is at 21.9%: it is of the high-quality reservoir types in Dixi area. (3 The volcanic breccia reservoir has the same diagenetic features with sedimentary rocks, but also has the same mineral composition with volcanic rock; rigid components can keep the primary porosity without being affected by compaction during the burial process. At the same time, the brittleness of volcanic breccia reservoir makes it easily fracture under the stress; internal fracture was developmental. Volcanic breccia developed in the structural high part and suffered a long-term leaching effect. The original pore-fracture combination also made

  6. Stratigraphic, Granulometric and Geochemical Studies of a Major Plinian Eruption on Dominica, Lesser Antilles (United States)

    Smith, A. L.; Daly, G.; Killingsworth, N.; Deuerling, K.; Schneider, S.; Fryxell, J. E.


    The island of Dominica, located in the center of the Lesser Antilles island arc has witnessed, probably within the last 100,000 years, three large volume Plinian eruptions. One of these, associated with the Morne Diablotins center, forms the Grande Savane pyroclastic flow fan, that extends off shore as a distinctive submarine feature for a distance of at least 14 km. Stratigraphical studies of road cuts and well-exposed sea cliffs indicate the fan is composed of an older unit composed of reworked deposits at the base followed by at least four sequences, based on the presence of paleosols, of block and ash flow deposits. The upper unit of block and ash flows is overlain, with no evidence of an intervening paleosol, by a sequence of ignimbrites and pumiceous surges (representing the Plinian eruption). There is no evidence of an initial Plinian fall deposit, so the lowest bed in the succession is an ignimbrite with a highly irregular base that cuts into the underlying block and ash flow deposits, the upper parts of which are colored red due to thermal effects. This lowest ignimbrite is welded (minimum porosity of 15%) throughout its thickness (maximum thickness of greater than 21 m), although a few outcrops near the margins show a thin (20-30 cm) non-welded but lithified zone beneath the welded zone. The remainder of the sequence is composed of lithified ignimbrite that can be subdivided into three units separated by pumiceous surge layers. The ignimbrite succession is overlain, with no obvious break, by a thin fall deposit containing accretionary lapilli and gas cavities, followed by three pumiceous surge deposits (lower and upper show planar stratification and the middle surge shows massive bedding); towards the north the upper two surge deposits are separated by thin pumiceous lapilli fall and ash fall deposits. This surge sequence extends laterally outside of the main area of ignimbrite deposition. The pumice clasts from the ignimbrites are andesitic in

  7. Geophysical image of the hydrothermal system of Merapi volcano (United States)

    Byrdina, S.; Friedel, S.; Vandemeulebrouck, J.; Budi-Santoso, A.; Suhari; Suryanto, W.; Rizal, M. H.; Winata, E.; Kusdaryanto


    We present an image of the hydrothermal system of Merapi volcano based on results from electrical resistivity tomography (ERT), self-potential, and CO2 flux mappings. The ERT models identify two distinct low-resistivity bodies interpreted as two parts of a probably interconnected hydrothermal system: at the base of the south flank and in the summit area. In the summit area, a sharp resistivity contrast at ancient crater rim Pasar-Bubar separates a conductive hydrothermal system (20-50 Ω m) from the resistive andesite lava flows and pyroclastic deposits (2000-50,000 Ω m). The existence of preferential fluid circulation along this ancient crater rim is also evidenced by self-potential data. The significative diffuse CO2 degassing (with a median value of 400 g m-2 d-1) is observed in a narrow vicinity of the active crater rim and close to the ancient rim of Pasar-Bubar. The total CO2 degassing across the accessible summital area with a surface of 1.4 ṡ 105 m2 is around 20 t d-1. Before the 2010 eruption, Toutain et al. (2009) estimated a higher value of the total diffuse degassing from the summit area (about 200-230 t d-1). This drop in the diffuse degassing from the summit area can be related to the decrease in the magmatic activity, to the change of the summit morphology, to the approximations used by Toutain et al. (2009), or, more likely, to a combination of these factors. On the south flank of Merapi, the resistivity model shows spectacular stratification. While surficial recent andesite lava flows are characterized by resistivity exceeding 100,000 Ω m, resistivity as low as 10 Ω m has been encountered at a depth of 200 m at the base of the south flank and was interpreted as a presence of the hydrothermal system. No evidence of the hydrothermal system is found on the basis of the north flank at the same depth. This asymmetry might be caused by the asymmetry of the heat supply source of Merapi whose activity is moving south or/and to the asymmetry in

  8. Lithium, boron and chloride in volcanics and greywackes in Northland, Auckland and the Taupo Volcanic Zone

    International Nuclear Information System (INIS)

    Reyes, A.G.; Trompetter, W.J.


    During magmatic differentiation processes B preferentially partitions into the glassy mesostasis of rhyolite and andesite. The behaviour of Li, on the other hand, varies with the silica content of the rock. Lithium, B, Cl and water contents increase proportionally with the silica concentration of the volcanic rocks. Their relative proportions in andesites of the Taupo Volcanic Zone (TVZ) appear to reflect the nature of the underlying crust, the dip of the subducting slab and hence the depth and temperature of magma generation. The B/Li ratios of rhyolites associated with the northern Rotorua and Okataina eruptive centres yield lower B/Li ratios than those from Maroa and Taupo centres in the south, where the slab subducts at a shallower angle. Apparently, volcanics associated with a younger subduction event as in the TVZ, contain and retain more Cl, yielding lower Li/Cl ratios for the TVZ than Northland-Auckland basalts. The B/Li ratio of greywackes from the Torlesse terrane ( 1.4). In geothermal wells in Ngawha, hydrothermal alteration yields higher B/Li ratios of >2.8 for Waipapa terrane sedimentary rocks. The Li/Cl ratios for average South and North Island greywackes are similar and may reflect similar degrees of metamorphism. In general, the relative Li, B and Cl contents in greywackes are dictated by the composition of the detrital fragments, the clay fraction, the type of clays and the metamorphic grade. During hydrothermal alteration of rhyolite in the TVZ, Cl always partitions into solution while Li and B have an affinity for the rock. However, more Li remains in the rock than B at any given temperature. The distribution coefficients of Li and B between water and rock increase with increasing temperature. The partitioning of Li between rock and solution in TVZ hydrothermal systems is mainly dictated by temperature, whereas the mass distribution coefficient for B is related to the tectonic setting. An increase in relative Li of the rock is associated with the

  9. Alberca De Guadalupe Maar Crater, Zacapu Basin : A Rare Type of Volcano within the Michoacán-Guanajuato Volcanic Field, México (United States)

    Kshirsagar, P. V.; Siebe, C.; Guilbaud, M. N.; Salinas, S.


    Phreato-magmatic vents (esp. maar craters) are rare in the ~40,000 Km2 Plio-Quaternary monogenetic Michoacán-Guanajuato Volcanic Field (MGVF) located in the central part of the Mexican Volcanic Belt. In contrast to >1000 scoria cones, only 2 dozen phreato-magmatic monogenetic vents (e.g. tuff cones, tuff rings, and maars) have been identified. About half of these form a cluster near Valle de Santiago in the Lerma river valley at the northern margin of the MGVF, while the others occur in a rather scattered fashion. Here we discuss the origin of Alberca de Guadalupe maar crater, one of the three phreato-magmatic vents (in addition to El Caracol and Alberca de Los Espinos) that occur within the boundaries of the inter-montane lacustrine Zacapu basin, a tectonic graben bound by an ENE-WSW normal fault system. The maar crater came into existence between 20,000 and 23,000 y BP, forming a 140 m deep hole in the otherwise planar surrounding ground of theearly Pleistocene lava flows of Cerro Pelón.The maar crater has a diameter of ~1 Km and bears a 9 m deep lake. Eruptive products include typical surge deposits that are best exposed around the rim and inner crater walls. They are poorly sorted (Mdø= -1.56 to -3.75, ø= 1.43 to 3.23), rich in accidental lithics (angular andesitic lava and ignimbrite clasts) constituting 51-88% of the deposit with few juveniles (basaltic andesite with phenocrysts of plagioclase, olivine, and pyroxene in a quenched glassy matrix; SiO2=54-58 wt. %). Dry surge units are friable and clast-supported, in contrast the wet surge units are fairly indurated and bear accretionary lapilli. Bedding is frequently distorted by ballistic impact-sag structures. The entire construct is disrupted by an E-W trending regional fault, downthrowing the northern part by ~30 m.The unusual formation of this maar crater in the semi-arid highlands of Zacapu was favored by the local hydrological and topographical conditions. Such conditions still prevail in several

  10. Stable isotope (δ18O and δ2H) data for precipitation, stream water, and groundwater in Puerto Rico (United States)

    Scholl, Martha A.; Torres-Sanchez, Angel; Rosario-Torres, Manuel


    Puerto Rico is located in the northeastern Caribbean Sea (18.2 °N, 66.3 °W), with the Atlantic Ocean on its northern coast. The U.S. Geological Survey’s Water, Energy, and Biogeochemical Budgets (WEBB) program study area in which most of these data were collected comprises the El Yunque National Forest and surrounding area of eastern Puerto Rico. Samples were collected in two forested watersheds, the Rio Mameyes and the Rio Icacos/Rio Blanco, on opposite sides of a ridge in the Luquillo Mountains on the eastern end of the island (fig. 1). Elevation in both watersheds ranges from sea level to approximately 1,000 meters (m). Near sea level, land use is mixed pasture, moist forest, and residential, grading to completely forested within the boundaries of El Yunque National Forest. Forest type changes with elevation from tabonuco to palo colorado to sierra palm to cloud forest above approximately 950 m (Murphy and others, 2012). The Rio Mameyes watershed is oriented north-northeast, and the basin is underlain by volcaniclastic bedrock (basaltic to andesitic volcanic sandstone/mudstone/conglomerate/breccia). The Rio Icacos/Rio Blanco watershed is oriented south-southeast. The Rio Icacos is one of the headwaters of the Rio Blanco and is underlain by quartz diorite. The lower Rio Blanco basin is underlain by andesitic volcaniclastic bedrock. This report also contains a long-term rain isotope dataset from the San Agustin site, in north-central Puerto Rico (fig. 1). Puerto Rico has a tropical climate dominated by easterly trade winds, and seasonal climate patterns affect the hydrology of the study area. The summer wet season is characterized by convective precipitation from tropical easterly waves, troughs, and cyclonic low-pressure systems, including tropical storms and hurricanes; in contrast, the drier winter season is characterized by trade-wind showers and frontal systems. The highest single-event rainfall totals tend to be associated with tropical storms

  11. Cumulate xenoliths from St. Vincent, Lesser Antilles Island Arc: a window into upper crustal differentiation of mantle-derived basalts (United States)

    Tollan, P. M. E.; Bindeman, I.; Blundy, J. D.


    In order to shed light on upper crustal differentiation of mantle-derived basaltic magmas in a subduction zone setting, we have determined the mineral chemistry and oxygen and hydrogen isotope composition of individual cumulus minerals in plutonic blocks from St. Vincent, Lesser Antilles. Plutonic rock types display great variation in mineralogy, from olivine-gabbros to troctolites and hornblendites, with a corresponding variety of cumulate textures. Mineral compositions differ from those in erupted basaltic lavas from St. Vincent and in published high-pressure (4-10 kb) experimental run products of a St. Vincent high-Mg basalt in having higher An plagioclase coexisting with lower Fo olivine. The oxygen isotope compositions (δ18O) of cumulus olivine (4.89-5.18‰), plagioclase (5.84-6.28‰), clinopyroxene (5.17-5.47‰) and hornblende (5.48-5.61‰) and hydrogen isotope composition of hornblende (δD = -35.5 to -49.9‰) are all consistent with closed system magmatic differentiation of a mantle-derived basaltic melt. We employed a number of modelling exercises to constrain the origin of the chemical and isotopic compositions reported. δ18OOlivine is up to 0.2‰ higher than modelled values for closed system fractional crystallisation of a primary melt. We attribute this to isotopic disequilibria between cumulus minerals crystallising at different temperatures, with equilibration retarded by slow oxygen diffusion in olivine during prolonged crustal storage. We used melt inclusion and plagioclase compositions to determine parental magmatic water contents (water saturated, 4.6 ± 0.5 wt% H2O) and crystallisation pressures (173 ± 50 MPa). Applying these values to previously reported basaltic and basaltic andesite lava compositions, we can reproduce the cumulus plagioclase and olivine compositions and their associated trend. We conclude that differentiation of primitive hydrous basalts on St. Vincent involves crystallisation of olivine and Cr-rich spinel at depth

  12. Morphometric study of pillow-size spectrum among pillow lavas (United States)

    Walker, George P. L.


    Measurements of H and V (dimensions in the horizontal and vertical directions of pillows exposed in vertical cross-section) were made on 19 pillow lavas from the Azores, Cyprus, Iceland, New Zealand, Tasmania, the western USA and Wales. The median values of H and V plot on a straight line that defines a spectrum of pillow sizes, having linear dimensions five times greater at one end than at the other, basaltic toward the small-size end and andesitic toward the large-size end. The pillow median size is interpreted to reflect a control exercised by lava viscosity. Pillows erupted on a steep flow-foot slope in lava deltas can, however, have a significantly smaller size than pillows in tabular pillowed flows (inferred to have been erupted on a small depositonal slope), indicating that the slope angle also exercised a control. Pipe vesicles, generally abundant in the tabular pillowed flows and absent from the flow-foot pillows, have potential as a paleoslope indicator. Pillows toward the small-size end of the spectrum are smooth-surfaced and grew mainly by stretching of their skin, whereas disruption of the skin and spreading were important toward the large-size end. Disruption involved increasing skin thicknesses with increasing pillow size, and pillows toward the large-size end are more analogous with toothpaste lava than with pahoehoe and are inferred from their thick multiple selvages to have taken hours to grow. Pseudo-pillow structure is also locally developed. An example of endogenous pillow-lava growth, that formed intrusive pillows between ‘normal’ pillows, is described from Sicily. Isolated pillow-like bodies in certain andesitic breccias described from Iceland were previously interpreted to be pillows but have anomalously small sizes for their compositions; it is now proposed that they may lack an essential attribute of pillows, namely, the development of bulbous forms by the inflation of a chilled skin, and are hence not true pillows. Para-pillow lava is

  13. The 1994-2001 eruptive period at Rabaul, Papua New Guinea: Petrological and geochemical evidence for basalt injections into a shallow dacite magma reservoir, and significant SO2 flux (United States)

    Patia, H.; Eggins, S. M.; Arculus, R. J.; McKee, C. O.; Johnson, R. W.; Bradney, A.


    The eruptions that began at Rabaul Caldera on 19 September 1994 had two focal points, the vents Tavurvur and Vulcan, located 6 km apart on opposing sides of the caldera. Vulcan eruptives define a tight cluster of dacite compositions, whereas Tavurvur eruptives span an array from equivalent dacite compositions to mafic andesites. The eruption of geochemically and mineralogically identical dacites from both vents indicates sourcing from the same magma reservoir. This, together with previously reported H2O-CO2 volatile contents of dacite melt inclusions, a caldera-wide seismic low-velocity zone, and a seismically active caldera ring fault structure are consistent with the presence at 3-6 km depth of an extensive, tabular dacitic magma body having volume of about 15-150 km3. The Tavurvur andesites form a linear compositional array and have strongly bimodal phenocryst assemblages that reflect dacite hybridisation with a mafic basalt. The moderately large volume SO2 flux documented in the Tavurvur volcanic plume (and negligible SO2 flux in the Vulcan plume) combined with high dissolved S contents of basaltic melt inclusions trapped in olivine of Tavurvur eruptives, indicate that the amount of degassed basaltic magma was 0.1 km3 and suggest that the injection of this magma was confined to the Tavurvur-side (eastern to northeastern sector) of the caldera. Circumstantial evidence suggests that the eruption was triggered and evolved in response to a series of basaltic magma injections that may have commenced in 1971 and continued up until at least the start of the 1994 eruptions. The presence of zoned plagioclase phenocrysts reflecting older basalt-dacite interaction events (i.e. anorthite cores overgrown with thick andesine rims), evaluation of limited available data for the products of previous eruptions in 1878 and 1937-1943, and the episodic occurrence of major intra-caldera seismo-deformational events indicates that the shallow magma system at Rabaul Caldera is

  14. Long-Term Volumetric Eruption Rates and Magma Budgets

    Energy Technology Data Exchange (ETDEWEB)

    Scott M. White Dept. Geological Sciences University of South Carolina Columbia, SC 29208; Joy A. Crisp Jet Propulsion Laboratory, California Institute of Technology Pasadena, CA 91109; Frank J. Spera Dept. Earth Science University of California, Santa Barbara Santa Barbara, CA 93106


    A global compilation of 170 time-averaged volumetric volcanic output rates (Qe) is evaluated in terms of composition and petrotectonic setting to advance the understanding of long-term rates of magma generation and eruption on Earth. Repose periods between successive eruptions at a given site and intrusive:extrusive ratios were compiled for selected volcanic centers where long-term (>104 years) data were available. More silicic compositions, rhyolites and andesites, have a more limited range of eruption rates than basalts. Even when high Qe values contributed by flood basalts (9 ± 2 Å~ 10-1 km3/yr) are removed, there is a trend in decreasing average Qe with lava composition from basaltic eruptions (2.6 ± 1.0 Å~ 10-2 km3/yr) to andesites (2.3 ± 0.8 Å~ 10-3 km3/yr) and rhyolites (4.0 ± 1.4 Å~ 10-3 km3/yr). This trend is also seen in the difference between oceanic and continental settings, as eruptions on oceanic crust tend to be predominately basaltic. All of the volcanoes occurring in oceanic settings fail to have statistically different mean Qe and have an overall average of 2.8 ± 0.4 Å~ 10-2 km3/yr, excluding flood basalts. Likewise, all of the volcanoes on continental crust also fail to have statistically different mean Qe and have an overall average of 4.4 ± 0.8 Å~ 10-3 km3/yr. Flood basalts also form a distinctive class with an average Qe nearly two orders of magnitude higher than any other class. However, we have found no systematic evidence linking increased intrusive:extrusive ratios with lower volcanic rates. A simple heat balance analysis suggests that the preponderance of volcanic systems must be open magmatic systems with respect to heat and matter transport in order to maintain eruptible magma at shallow depth throughout the observed lifetime of the volcano. The empirical upper limit of Å`10-2 km3/yr for magma eruption rate in systems with relatively high intrusive:extrusive ratios may be a consequence of the fundamental parameters

  15. Incipient boninitic arc crust built on denudated mantle: the Khantaishir ophiolite (western Mongolia) (United States)

    Gianola, Omar; Schmidt, Max W.; Jagoutz, Oliver; Sambuu, Oyungerel


    The 570 Ma old Khantaishir ophiolite is built by up to 4 km harzburgitic mantle with abundant pyroxenites and dunites followed by 2 km of hornblende-gabbros and gabbronorites and by a 2.5 km thick volcanic unit composed of a dyke + sill complex capped by pillow lavas and some volcanoclastics. The volcanics are mainly basaltic andesites and andesites (or boninites) with an average of 58.2 ± 1.0 wt% SiO2, X Mg = 0.61 ± 0.03 ( X Mg = molar MgO/(MgO + FeOtot), TiO2 = 0.4 ± 0.1 wt% and CaO = 7.5 ± 0.6 wt% (errors as 2 σ). Normalized trace element patterns show positive anomalies for Pb and Sr, a negative Nb-anomaly, large ion lithophile elements (LILE) concentrations between N- and E-MORB and distinctly depleted HREE. These characteristics indicate that the Khantaishir volcanics were derived from a refractory mantle source modified by a moderate slab-component, similar to boninites erupted along the Izu-Bonin-Mariana subduction system and to the Troodos and Betts Cove ophiolites. Most strikingly and despite almost complete outcrops over 260 km2, there is no remnant of any pre-existing MORB crust, suggesting that the magmatic suite of this ophiolite formed on completely denudated mantle, most likely upon subduction initiation. The architecture of this 4-5 km thick early arc crust resembles oceanic crust formed at mid ocean ridges, but lacks a sheeted dyke complex; volcanic edifices are not observed. Nevertheless, low melting pressures combined with moderate H2O-contents resulted in high-Si primitive melts, in abundant hornblende-gabbros and in a fast enrichment in bulk SiO2. Fractional crystallization modeling starting from the observed primitive melts (56.6 wt% SiO2) suggests that 25 wt% pyroxene + plagioclase fractionation is sufficient to form the average Khantaishir volcanic crust. Most of the fractionation happened in the mantle, the observed pyroxenite lenses and layers in and at the top of the harzburgites account for the required cumulate volumes. Finally

  16. Late Triassic Porphyritic Intrusions And Associated Volcanic Rocks From The Shangri-La Region, Yidun Terrane, Eastern Tibetan Plateau: Implications For Adakitic Magmatism And Porphyry Copper Mineralization (United States)

    Wang, B.; Zhou, M.; Li, J.; Yan, D.


    The Yidun terrane, located on the eastern margin of the Tibetan plateau, has been commonly considered to be a Triassic volcanic arc produced by subduction of the Ganzi-Litang oceanic lithosphere. The Yidun terrane is characterized by numerous arc-affinity granitic intrusions located along a 500-km-long, north-south-trending belt. Among these granitic bodies, several small porphyritic intrusions in the southern segment of the terrane (Shangri-La region) are associated with large porphyry copper deposits. These porphyritc intrusions are composed of diorite and quartz diorite, and spatially associated with andesites and dacites. LA-ICP-MS zircon U-Pb ages of the intrusions range from 230 to 215 Ma. The andesites and dacites are intercalated with slates and sandstones and have ages of around 220 Ma. The intrusive and volcanic rocks have SiO2 contents from 56.6 to 67.1 wt.%, Al2O3 from 14.2 to 17.4 wt.% and MgO from 1.9 to 4.2 wt.%. They show significant negative Nb-Ta anomalies on primitive mantle-normalized spidergrams. They have high La/Yb (13-49) ratios with no prominent Eu anomalies. All the rocks have high Sr (258-1980 ppm), and low Y (13-21 ppm) with high Sr/Y ratios (29-102). The geochemical features indicate that both the volcanic rocks and porphyritic intrusions were derived from adakitic magmas. They have similar initial 87Sr/86Sr ratios (0.7058 to 0.7077) and ɛNd (-1.88 to -4.93) values, but can be further divided into two groups: high silica (HSA) and low silica adakitic rocks (LSA). The HSA, representing an early stage of magmatism (230 to 215 Ma), were derived from oceanic slab melts with limited interaction with the overlying mantle wedge. At 215 Ma, more extensive interaction resulted in the formation of LSA. We propose that HSA were produced by flat subduction leading to melting of oceanic slab, whereas subsequent slab break-off caused the significant interaction between slab melts and the mantle wedge and thus the generation of the LSA. Compared with

  17. General geology and ground-water resources of the island of Maui, Hawaii (United States)

    Stearns, Harold T.; Macdonald, Gordon Andrew


    level. Covering this dome are the Kula volcanics, extruded probably in early and middle Pleistocene time, and characterized by andesites, andesitic basalts, and picritic basalts. They are 2.000 feet thick on the summit and 50 to 200 feet thick at the periphery. They contain a sufficient number of interbedded soils, thin vitric tuff beds, and lava-filled valleys in their upper part to give rise to valuable perched springs in wet areas. The Kula lavas accumulated during a waning volcanic phase which was followed by a quiescence long enough for the erosion of deep amphitheater-headed valleys in the east or wet half of the mountain. Volcanic activity was renewed in middle (?) to late Pleistocene time and continued until Recent time, during which the Hana volcanic series was laid down. The last lava flow was erupted about 1750. The Hana lavas comprise andesitic, picritic, and olivine basalts. They veneered large areas of the east and south slopes, partly filled the deep amphitheater-headed valleys, and deeply buried the smaller valleys in the eastern half of the mountain. The Hana rocks are exceedingly permeable and much rain sinks into them.The oldest rocks on West Maui are the very permeable primitive Wailuku basalts, which were extruded probably in Pliocene and early Pleistocene time from two rifts and from many radial fissures. The basalts form a dome about 5,600 feet high and extend an unknown distance below sea level. Iao Valley is the eroded caldera of this dome. Forming an incomplete veneer over the dome are the Honolua soda trachytes and oligoclase andesites. They were extruded in late Pliocene (?) or early Pleistocene time, chiefly from bulbous domes. The clinker beds carry some water but the rocks are generally too dense to be good aquifers. During early (?) Pleistocene the West Maui volcano was cut by deep amphitheater-headed valleys and then all of Maui was deeply submerged. Four scattered eruptions occurred on West Maui in middle (?) and late Pleistocene time

  18. Geologic field-trip guide to Mount Shasta Volcano, northern California (United States)

    Christiansen, Robert L.; Calvert, Andrew T.; Grove, Timothy L.


    The southern part of the Cascades Arc formed in two distinct, extended periods of activity: “High Cascades” volcanoes erupted during about the past 6 million years and were built on a wider platform of Tertiary volcanoes and shallow plutons as old as about 30 Ma, generally called the “Western Cascades.” For the most part, the Shasta segment (for example, Hildreth, 2007; segment 4 of Guffanti and Weaver, 1988) of the arc forms a distinct, fairly narrow axis of short-lived small- to moderate-sized High Cascades volcanoes that erupted lavas, mainly of basaltic-andesite or low-silica-andesite compositions. Western Cascades rocks crop out only sparsely in the Shasta segment; almost all of the following descriptions are of High Cascades features except for a few unusual localities where older, Western Cascades rocks are exposed to view along the route of the field trip.The High Cascades arc axis in this segment of the arc is mainly a relatively narrow band of either monogenetic or short-lived shield volcanoes. The belt generally averages about 15 km wide and traverses the length of the Shasta segment, roughly 100 km between about the Klamath River drainage on the north, near the Oregon-California border, and the McCloud River drainage on the south (fig. 1). Superposed across this axis are two major long-lived stratovolcanoes and the large rear-arc Medicine Lake volcano. One of the stratovolcanoes, the Rainbow Mountain volcano of about 1.5–0.8 Ma, straddles the arc near the midpoint of the Shasta segment. The other, Mount Shasta itself, which ranges from about 700 ka to 0 ka, lies distinctly west of the High Cascades axis. It is notable that Mount Shasta and Medicine Lake volcanoes, although volcanologically and petrologically quite different, span about the same range of ages and bracket the High Cascades axis on the west and east, respectively.The field trip begins near the southern end of the Shasta segment, where the Lassen Volcanic Center field trip leaves

  19. Geology of El Chichon volcano, Chiapas, Mexico (United States)

    Duffield, Wendell A.; Tilling, Robert I.; Canul, Rene


    The (pre-1982) 850-m-high andesitic stratovolcano El Chichón, active during Pleistocene and Holocene time, is located in rugged, densely forested terrain in northcentral Chiapas, México. The nearest neighboring Holocene volcanoes are 275 km and 200 km to the southeast and northwest, respectively. El Chichón is built on Tertiary siltstone and sandstone, underlain by Cretaceous dolomitic limestone; a 4-km-deep bore hole near the east base of the volcano penetrated this limestone and continued 770 m into a sequence of Jurassic or Cretaceous evaporitic anhydrite and halite. The basement rocks are folded into generally northwest-trending anticlines and synclines. El Chichón is built over a small dome-like structure superposed on a syncline, and this structure may reflect cumulative deformation related to growth of a crustal magma reservoir beneath the volcano. The cone of El Chichón consists almost entirely of pyroclastic rocks. The pre-1982 cone is marked by a 1200-m-diameter (explosion?) crater on the southwest flank and a 1600-m-diameter crater apparently of similar origin at the summit, a lava dome partly fills each crater. The timing of cone and dome growth is poorly known. Field evidence indicates that the flank dome is older than the summit dome, and K-Ar ages from samples high on the cone suggest that the flank dome is older than about 276,000 years. At least three pyroclastic eruptions have occurred during the past 1250 radiocarbon years. Nearly all of the pyroclastic and dome rocks are moderately to highly porphyritic andesite, with plagioclase, hornblende and clinopyroxene the most common phenocrysts. Geologists who mapped El Chichón in 1980 and 1981 warned that the volcano posed a substantial hazard to the surrounding region. This warning was proven to be prophetic by violent eruptions that occurred in March and April of 1982. These eruptions blasted away nearly all of the summit dome, blanketed the surrounding region with tephra, and sent pyroclastic

  20. Re-Os dating on pyrite and metal sources tracing in porphyry-type and neutral epithermal deposits: example of the Bolcana, Troita and Magura deposits, Apuseni Mountains, Romania

    International Nuclear Information System (INIS)

    Cardon, Olivier


    Many porphyry-type (Cu-Au) and neutral epithermal (Pb-Zn and Au ± Ag) ore deposits are encountered in the region of the Apuseni Mountains, located at the foot of the Carpathian chain in the Western Romania. These deposits are related to a Neogene andesitic volcanism. In order to demonstrate possible genetic relationships between the porphyry-type and neutral epithermal deposits, the Bolcana porphyry has been investigated since it is surrounded by a number of epithermal low-sulfidation veins with a Pb-Zn ± Au mineralisation. These veins are currently mined at the Troita and Magura sites. A structural analysis and a 3D modelling pf these deposits indicate that the geometry and orientation of fractures and mineralized vein are consistent both with direction of regional extension and with a NW-SE progression of the different andesitic intrusions. In order to establish precisely the temporal relationship between the different ore deposits, a Re-Os dating method has been developed and applied on pyrite which is ubiquitous in all of the deposits. This method enabled us to assign an age of 10.9 ± 1.9 Ma for the porphyry-hosted mineralization. The ages obtained for the epithermal systems are somewhat approximative as perturbations of the Re-Os system are observed for these environments. A fractionation of rhenium responsible for a significant enrichment in this element for the apical zone of the porphyry has been demonstrated. This enrichment is most probably related to a maximum boiling event, which may also explain a similar enrichment in arsenic for the pyrite in the same zone. The sources for the metals have been characterized at the district scale by combining two isotopic systems (Re-Os and Pb-Pb) on both pyrite and galena. The osmium data indicate that the Troita deposit has composition which is similar to that of the Bolcana porphyry. In contrast the results obtained for the Magura deposits indicate the Re-OS system has in this case been perturbed due to a

  1. Are U-Series Disequilibria Transparent to Crustal Processing of Magma? A Case Study at Bezymianny and Klyuchevskoy Volcanoes, Kamchatka, Russia (United States)

    Kayzar, T. M.; Nelson, B. K.; Bachmann, O.; Portnyagin, M.; Ponomareva, V.


    Disequilibria in the short-lived uranium-series isotopic system can provide timescales of magma production, modification and transport in all tectonic settings. In volcanic arcs, the field has converged on the concept that (238U/230Th) and (226Ra/230Th) activities greater than one are a result of fluid fluxing from the slab to mantle wedge, and that the preservation of (226Ra/230Th) disequilibria requires rapid transport of melts from the mantle wedge to the surface (226Ra returns to equilibrium with 230Th in ~8000 years). The need for rapid transport coupled with the incompatibility of U-series elements suggest that U-series fractionation is not measurably affected by crustal processes. However, some well-studied arc systems, including the very productive Central Kamchatka Depression (CKD) of the Kamchatkan volcanic arc, show U-series data that are in conflict with this commonly accepted model. Our study focuses on two neighboring volcanic systems, Bezymianny and Klyuchevskoy volcanoes in the CKD. Separated by ~10km, these two systems are thought to share the same mantle source. Klyuchevskoy has primitive compositions (51-56 wt%) while Bezymianny erupts more differentiated andesites (57-63 wt% SiO2); therefore, by examining the U-series signals in these two systems it is possible to decouple a primary signal from one having undergone crustal processing. We record whole rock (238U/230Th) values for Bezymianny ranging from 0.94 to 0.96 in modern eruptive products, while (226Ra/230Th) are >1. We also observe a similar signal in older (212-6791BP) tephra deposits from Klyuchevskoy, measuring (238U/230Th) of 0.92-0.99 (unpublished data, collaborative research with the KALMAR project). (238U/230Th) local bulk rock or partial melts to fractionate U, Th, and Ra from one another. In particular, we focus on minor mineral phases, such as apatite and magnetite, which are present during early stages of differentiation (andesites) and may fractionate U from Th. We measure U and

  2. The eruptive chronology of the Ampato-Sabancaya volcanic complex (Southern Peru) (United States)

    Samaniego, Pablo; Rivera, Marco; Mariño, Jersy; Guillou, Hervé; Liorzou, Céline; Zerathe, Swann; Delgado, Rosmery; Valderrama, Patricio; Scao, Vincent


    We have reconstructed the eruptive chronology of the Ampato-Sabancaya volcanic complex (Southern Peru) on the basis of extensive fieldwork, and a large dataset of geochronological (40K-40Ar, 14C and 3He) and geochemical (major and trace element) data. This volcanic complex is composed of two successive edifices that have experienced discontinuous volcanic activity from Middle Pleistocene to Holocene times. The Ampato compound volcano consists of a basal edifice constructed over at least two cone-building stages dated at 450-400 ka and 230-200 ka. After a period of quiescence, the Ampato Upper edifice was constructed firstly during an effusive stage (80-70 ka), and then by the formation of three successive peaks: the Northern, Southern (40-20 ka) and Central cones (20-10 ka). The Southern peak, which is the biggest, experienced large explosive phases, resulting in deposits such as the Corinta plinian fallout. During the Holocene, eruptive activity migrated to the NE and constructed the mostly effusive Sabancaya edifice. This cone comprised many andesitic and dacitic blocky lava flows and a young terminal cone, mostly composed of pyroclastic material. Most samples from the Ampato-Sabancaya define a broad high-K magmatic trend composed of andesites and dacites with a mineral assemblage of plagioclase, amphibole, biotite, ortho- and clino-pyroxene, and Fe-Ti oxides. A secondary trend also exists, corresponding to rare dacitic explosive eruptions (i.e. Corinta fallout and flow deposits). Both magmatic trends are derived by fractional crystallisation involving an amphibole-rich cumulate with variable amounts of upper crustal assimilation. A marked change in the overall eruptive rate has been identified between Ampato ( 0.1 km3/ka) and Sabancaya (0.6-1.7 km3/ka). This abrupt change demonstrates that eruptive rates have not been homogeneous throughout the volcano's history. Based on tephrochronologic studies, the Late Holocene Sabancaya activity is characterised by strong

  3. Seismic and Gas Analyses Imply Magmatic Intrusion at Iliamna Volcano, Alaska in 2012 (United States)

    Prejean, S. G.; Werner, C. A.; Buurman, H.; Doukas, M. P.; Kelly, P. J.; Kern, C.; Ketner, D.; Stihler, S.; Thurber, C. H.; West, M. E.


    In early 2012, Iliamna Volcano, an ice-covered andesitic stratovolcano located in the Cook Inlet region of Alaska, had a vigorous earthquake swarm that included both brittle-failure earthquakes (Mvolume has otherwise been seismically quiet except during a possible magmatic intrusion at Iliamna in 1996, when it sustained a similar swarm (Roman et al., 2004, J. Volc. Geotherm. Res., v. 130, p. 265-284). Analysis of the relative amplitudes between the small low-frequency and located brittle failure events indicates that their sources are geographically separate, with the low-frequency events sourced closer to the fumarolically active summit region, ~4 km north of the brittle failure events. Airborne gas-emission measurements on March 17 revealed emission rates of up to 2000 and 580 tonnes per day (t/d) of CO2 and SO2, respectively, and a molar C/S ratio of 5. Visual observations from the flight revealed unusually vigorous fumarole activity near the summit. Subsequent measurements on June 20 and 22 showed continued high emissions of up to 1190 and 440 t/d of CO2 and SO2, respectively, with a C/S ratio of 4. These emission measurements are similar to those measured during the height of the 1996 unrest episode and are significantly above background measurements between 1998 and August 2011, which were typically below 100 and 60 t/d of CO2 and SO2. Taken together, gas and seismic data suggest that the earthquake swarm was driven by magmatic intrusion. Gas flux rates are consistent with those measured for degassing andesitic magmas in the shallow crust at other Cook Inlet volcanoes. Increased heat and degassing likely caused small low-frequency events in the shallow hydrothermal system near the volcano's summit, and/or may have destabilized the glacier, triggering shallow low-frequency glacial events. This unrest episode demonstrates how magmatic intrusions can cause spatially disparate earthquake swarms in hydrothermal systems and on pre-existing crustal structures.

  4. Poás volcano in Costa Rica as a hydrothermal analog for Mars (United States)

    Elmaarry, M. R.; Hynek, B. M.


    Mars has experienced intensive volcanic and impact activity early in its history, coinciding with a similarly extensive hydrologic activity on a global scale. These activities constitute the main ingredients of hydrothermal activity. Data acquired from the study of Martian meteorites, remote sensing spectral observations, and robotic rovers has shown the surface of Mars to be mineralogically diverse including mineral assemblages that resemble those of analogous hydrothermal systems on Earth. In particular, evidence for extensive acid-sulfate weathering has been observed by the MERs at Gusev and Meridiani, as well as by MSL at Gale crater. Furthermore, there is growing evidence for silicic volcanism on Mars as indicated by the detection of silica-rich mudstone at Gale containing tridymite and cristobalite coupled with spectral observations indicative of felsic rocks in geographically disparate locations on Mars. For that, the Poás volcano in Costa Rica offers a geologic setting that can be analogous to similar environments on Mars. The Poás volcano is a basaltic andesite stratovolcano in central Costa Rica. Its caldera houses a highly acidic lake inside the caldera 130 m below the crater rim. The volcano has been active in recent historical times, and is currently displaying intensive activity since Apr 2017. Unaltered andesitic basalts collected from the 1953-1955 magmatic activity are mainly composed of plagioclase and minor amounts of orthopyroxene and olivine. We collected samples during our fieldwork in March 2017 (few weeks before its eruption) from fumaroles inside the caldera. The fumaroles were emitting gases at 92°C, and the acidic lake minor abundances of hematite, anatase, and amorphous silica. Most of these minerals have been observed on Mars under potentially similar settings. We plan to continue our investigation by carrying out additional analyses and compare to samples collected from earlier campaigns to gain a better understanding of how the

  5. Impact of Magmatism on the Geodynamic Evolution of Southern Georgia on the Example of the Lesser Caucasus Artvin-Bolnisi Block. (United States)

    Sadradze, Nino; Adamia, Shota; Zakariadze, Guram; Beridze, Tamara; Khutsishvili, Sophio


    The Georgian region occupies the central part of the collisional zone between the Eurasian and Africa-Arabian continents and is actually a collage of lithospheric fragments of the Tethyan Ocean and its northern and southern continental margins. Magmatic evolution is an important event in the formation and development of the geological structure of Southern Georgia, where several reliably dated volcanogenic and volcanogenic-sedimentary formations are established. The region represents a modern analogue of continental collision zone, where subduction-related volcanic activity lasted from Paleozoic to the end of Paleogene. After the period of dormancy in the Early-Middle Miocene starting from the Late Miocene and as far as the end of the Pleistocene, primarily subaerial volcanic eruptions followed by formation of volcanic highlands and plateaus occurred in the reigon. The Upper Miocene to Holocene volcanic rocks are related to the transverse Van-Transcaucasian uplift and belong to post-collisional calc- alkaline basalt-andesite-dacite-rhyolite series. A system of island arc and intra-arc rift basins (Artvin-Bolnisi and Achara-Trialeti) have been interpreted as characteristic of the pre-collisional stage of the region development, while syn- post-collisional geodynamic events have been attributed to intracontinental stage. Outcrops of the postcollisional magmatic rocks are exposed along the boundaries of the major tectonic units of the region. The Artvin-Bolnisi unit forms the northwestern part of the Lesser Caucasus and represents an island arc domain of so called the Somkheto-Karabakh Island Arc or Baiburt-Garabagh-Kapan belt. It was formed mainly during the Jurassic-Eocene time interval on the southern margin of the Eurasian plate by nort-dipping subduction of the Neotethys Ocean and subsequent collision to the Anatolia-Iranian continental plate. The Artvin-Bolnisi unit, including the Bolnisi district, was developing as a relatively uplifted island arc-type unit

  6. Geology, lithogeochemistry and paleotectonic setting of the host sequence to the Kangasjärvi Zn-Cu deposit, central Finland: implications for volcanogenic massive sulphide exploration in the Vihanti-Pyhäsalmi district

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    Michael D. Roberts


    Full Text Available The Kangasjärvi Zn-Cu deposit is a highly deformed and metamorphosed Paleoproterozoic volcanogenic massive sulphide (VMS deposit located in the Vihanti-Pyhäsalmi base metal mining district of central Finland. The host sequence to the deposit, referred to as the Inner Volcanic Sequence (IVS, is comprised of a bimodal suite of metavolcanic rocks and a regionally extensive tonalite-trondhjemite gneiss (sub-volcanic intrusions?. A separate and perhaps younger sequence of mafic volcanic rocks, with irregular intervals of undifferentiated intermediate to felsic schists and metalimestones, referred to as the Outer Volcanic Sequence (OVS, are separated from the IVS sequence by intervals of metagreywacke and U-P-bearing graphitic schists. A stratigraphic scheme for rocks within the IVS is proposed based on outcrop observations, locally preserved volcanic textures, aspects of seafloor-related hydrothermal alteration and lithogeochemistry. In this scheme, rare andesites form the lowermostvolcanic stratigraphy and are overlain by typical island-arc basalts that were erupted in a subaqueous setting. Tonalite-trondhjemite subvolcanic intrusions were locally emplaced within andesites and coeval rhyolites were extruded on the basaltic substrate. The extrusion of rhyolites, including high-silica rhyolites, was coeval with regional-scale, pre-metamorphic seafloor hydrothermal alteration and local sulphide mineralization. Extensively altered rhyolites envelope massive sulphides and are underlain by altered basalts. The latter rocks are now characterized by a variety of low-variance metamorphic mineral assemblages (e.g. orthoamphibole-cordierite rocks and define a domain of intense pre-metamorphic chlorite ± sericite alteration in the stratigraphic footwall of the deposit. The altered nature of these rocks is attributed to reaction with seawater-related hydrothermal fluids within a zone of upflow at or near the seafloor. The fundamental controls on convective

  7. Morphology, volcanism, and mass wasting in Crater Lake, Oregon (United States)

    Bacon, C.R.; Gardner, J.V.; Mayer, L.A.; Buktenica, M.W.; Dartnell, P.; Ramsey, D.W.; Robinson, J.E.


    Crater Lake was surveyed nearly to its shoreline by high-resolution multibeam echo sounding in order to define its geologic history and provide an accurate base map for research and monitoring surveys. The bathymetry and acoustic backscatter reveal the character of landforms and lead to a chronology for the concurrent filling of the lake and volcanism within the ca. 7700 calibrated yr B.P. caldera. The andesitic Wizard Island and central-plattform volcanoes are composed of sequences of lava deltas that record former lake levels and demonstrate simultaneous activity at the two vents. Wizard Island eruptions ceased when the lake was ~80 m lower than at present. Lava streams from prominent channels on the surface of the central platform descended to feed extensive subaqueous flow fields on the caldera floor. The Wizard Island and central-platform volcanoes, andesitic Merriam Cone, and a newly discovered probable lava flow on the eastern floor of the lake apparently date from within a few hundred years of caldera collapse, whereas a small rhydacite dome was emplaced on the flank of Wizard Island at ca. 4800 cal. yr B.P. Bedrock outcrops on the submerged caldera walls are shown in detail and, in some cases, can be correlated with exposed geologic units of Mount Mazama. Fragmental debris making up the walls elsewhere consists of narrow talus cones forming a dendritic pattern that leads to fewer, wider ridges downslope. Hummocky topography and scattered blocks up to ~280 m long below many of the embayments in the caldera wall mark debris-avalanche deposits that probably formed in single events and commonly are affected by secondary failures. The flat-floored, deep basins contain relatively fine-grained sediment transported from the debris aprons by sheet-flow turbidity currents. Crater Lake apparently filled rapidly (ca. 400-750 yr) until reaching a permeable layer above glaciated lava identified by the new survey in the northeast caldera wall at ~1845 m elevation

  8. Origin of the ca. 50 Ma Linzizong shoshonitic volcanic rocks in the eastern Gangdese arc, southern Tibet (United States)

    Liu, An-Lin; Wang, Qing; Zhu, Di-Cheng; Zhao, Zhi-Dan; Liu, Sheng-Ao; Wang, Rui; Dai, Jin-Gen; Zheng, Yuan-Chuan; Zhang, Liang-Liang


    The origin of the Eocene shoshonitic rocks within the upper part of the extensive Linzizong volcanic succession (i.e., the Pana Formation) in the Gangdese arc, southern Tibet remains unclear, inhibiting the detailed investigations on the crust-mantle interaction and mantle dynamics that operate the generation of the coeval magmatic flare-up in the arc. We report mineral composition, zircon U-Pb age and zircon Hf isotope, whole-rock element and Sr-Nd-Hf isotope data for the Pana Formation volcanic rocks from Pangduo, eastern Gangdese arc in southern Tibet. The Pana volcanic rocks from Pangduo include basalts, basaltic andesites, and dacites. SIMS and LA-ICPMS zircon U-Pb dating indicates that the Pangduo dacites were erupted at 50 ± 1 Ma, representing the volcanic equivalent of the coeval Gangdese Batholith that define a magmatic flare-up at 51 ± 1 Ma. The Pangduo volcanic rocks are exclusively shoshonitic, differing from typical subduction-related calc-alkaline volcanic rocks. The basalts have positive whole-rock ƐNd(t) (+1.7) and ƐHf(t) (+3.8) with high Zr abundances (121-169 ppm) and Zr/Y ratios (4.3-5.2), most likely derived from the partial melting of an enriched garnet-bearing lithospheric mantle that was metasomatized by subduction-related components with input from asthenosphere. Compared to the basalts, similar trace elemental patterns and decreased whole-rock ƐNd(t) (-3.5 to -3.3) and ƐHf(t) (-2.5 to -1.6) of the basaltic andesites can be attributed to the input of the ancient basement-derived material of the central Lhasa subterrane into the basaltic magmas. The coherent whole-rock Sr-Nd-Hf isotopic compositions ((87Sr/86Sr)i = 0.7064-0.7069, ƐNd(t) = -6.0 to -5.2, ƐHf(t) = -5.6 to -5.0) and varying zircon ƐHf(t) (-6.0 to +4.1) of the dacites can be interpreted by the partial melting of a hybrid lower crust source (juvenile and ancient lower crust) with incorporation of basement-derived components. Calculations of zircon-Ti temperature and whole

  9. Tectonic evolution of the central-eastern sector of Trans Mexican Volcanic Belt and its influence on the eruptive history of the Nevado de Toluca volcano (Mexico) (United States)

    Bellotti, F.; Capra, L.; Groppelli, G.; Norini, G.


    The Nevado de Toluca is an andesitic to dacitic stratovolcano of Late Pliocene-Holocene age located within the central and eastern sectors of the Trans Mexican Volcanic Belt. Morphostructural analysis, aerial photograph and satellite image interpretation, structural analysis and geological fieldwork were methods used to investigate the relationship between the evolution of the volcano and the tectonic framework of its basement. The study revealed that the area of Nevado de Toluca is affected by three main fault systems that intersect close to the volcanic edifice. These are from oldest to youngest, the Taxco-Querétaro, San Antonio and Tenango fault systems. The NNW-SSE Taxco-Querétaro fault system was active in the area since Early Miocene, and is characterized by right-lateral transtensive movement. Its reactivation during Early to Middle Pleistocene was responsible for the emplacement of andesitic to dacitic lava flows and domes of La Cieneguilla Supersynthem. The NE-SW San Antonio fault system was active during Late Pliocene, before the reactivation of the Taxco-Querétaro fault system, and is characterized by extensional left-lateral oblique-slip kinematics. The youngest is the E-W Tenango fault system that has been active since Late Pleistocene. This fault system is characterized by transtensive left-lateral strike-slip movement, and partly coeval with the youngest eruptive phase, the Nevado Supersynthem, which formed the present summit cone of the Nevado de Toluca volcano. The stress re-orientation from the Taxco-Querétaro to the Tenango fault system during Late Pleistocene is responsible for the ˜ 1 Ma hiatus in the magmatic activity between 1.15 Ma and 42 ka. After this period of repose, the eruptive style drastically changed from effusive to explosive with the emission of dacitic products. The methodology presented here furnish new data that can be used to better assess the complex structural evolution of this sector of the Trans Mexican Volcanic Belt

  10. Modelling of Magma Density and Viscocity Changes and Their Influences towards the Characteristic of Kelud Volcano Eruption

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    Hanik Humaida


    Full Text Available DOI: 10.17014/ijog.v6i4.129The effusive eruption of Kelud Volcano in 2007 was different from the previous ones, which in general were more explosive. Among others, density and viscosity are factors that determine the type of eruption. Therefore, the study on the difference of the recent eruption style based on the density and viscosity of magma was carried out. The method used in this study was based on geochemical analysis of the rock and then a modeling was established by using the above parameter. The study on the explosive eruption was emphasized on the data of 1990 eruption, whereas the effusive eruption was based on the data of 2007 eruption. The result shows that the magma viscosity of Kelud Volcano depend on the H O concentration as one of the volatile compound in magma, and temperature which gives the exponential equation. The higher the increase of H O content the smaller the value of its viscosity as well as the higher the temperature. The H O content in silica fluid can break the polymer bond of the silica fluid, because a shorter polymer will produce a lower viscosity. The density of the silica content of Kelud Volcano ranges between andesitic and basaltic types, but andesite is more likely. The fluid density of the material of 1990 eruption is different