Sample records for andesites

  1. Formation of hybrid arc andesites beneath thick continental crust (United States)

    Straub, Susanne M.; Gomez-Tuena, Arturo; Stuart, Finlay M.; Zellmer, Georg F.; Espinasa-Perena, Ramon; Cai, Yue; Iizuka, Yoshiyuki


    Andesite magmatism at convergent margins is essential for the differentiation of silicate Earth, but no consensus exists as to andesite petrogenesis. Models proposing origin of primary andesite melts from mantle and/or slab materials remain in deadlock with the seemingly irrefutable petrographic and chemical evidence for andesite formation through mixing of basaltic mantle melts with silicic components from the overlying crust. Here we use 3He/4He ratios of high-Ni olivines to demonstrate the mantle origin of basaltic to andesitic arc magmas in the central Mexican Volcanic Belt (MVB) that is constructed on ~ 50 km thick continental crust. We propose that the central MVB arc magmas are hybrids of high-Mg# > 70 basaltic and dacitic initial mantle melts which were produced by melting of a peridotite subarc mantle interspersed with silica-deficient and silica-excess pyroxenite veins. These veins formed by infiltration of reactive silicic components from the subducting slab. Partial melts from pyroxenites, and minor component melts from peridotite, mix in variable proportions to produce high-Mg# basaltic, andesitic and dacitic magmas. Moderate fractional crystallization and recharge melt mixing in the overlying crust produces then the lower-Mg# magmas erupted. Our model accounts for the contrast between the arc-typical SiO2 variability at a given Mg# and the strong correlation between major element oxides SiO2, MgO and FeO which is not reproduced by mantle-crust mixing models. Our data further indicate that viscous high-silica mantle magmas may preferentially be emplaced as intrusive silicic plutonic rocks in the crust rather than erupt. Ultimately, our results imply a stronger turnover of slab and mantle materials in subduction zones with a negligible, or lesser dilution, by materials from the overlying crust.

  2. Genesis of Cenozoic intraplate high Mg# andesites in Northeast China (United States)

    Liu, J. Q.; Chen, L. H.; Zhong, Y.; Wang, X. J.


    High-Mg# andesites (HMAs) are usually generated in the converged plate boundary and have genetic relationships with slab subduction. However, it still remained controversial about the origin of those HMAs erupted in the intra-plate setting. Here we present major, trace element, and Sr-Nd-Pb-Hf isotopic compositions for the Cenozoic intra-plate HMAs from Northeast China to constrain their origin and formation process. Cenozoic Xunke volcanic rocks are located in the northern Lesser Khingan Range, covering an area of about 3, 000 km2. These volcanic rocks are mainly basaltic andesite and basaltic trachyandesite, with only several classified as trachyandesite and andesites. They have high SiO2 contents (54.3-57.4 wt%) and Mg# (49.6-57.8), falling into the scope of high Mg# andesites. The Xunke HMAs are enriched in large ion lithophile elements but depleted in high field strength elements, with positive Ba, K, Sr and negative Zr-Hf, and Ti anomalies. Their trace element absolute concentrations are between those of potassic basalts and Wuchagou HMAs. The Xunke HMAs have relatively enriched Sr-Nd-Hf isotopes (87Sr/86Sr = 0.705398-0.705764, ɛNd=-8.8-3.8, ɛHf=0.5-11.7), and low radiogenic Pb isotopes (206Pb/204Pb = 16.701-17.198), towards to the EM1 end-member, which indicates that they are ultimately derived from ancient, recycled crustal components. Primitive silica-rich melts were generated from higher degrees of partial melting of recycled crustal materials (relative to potassic basalts) and then interacted with the peridotite to produce the Xunke HMAs.

  3. Thermoelastic properties of the Rotokawa Andesite: A geothermal reservoir constraint (United States)

    Siratovich, P. A.; von Aulock, F. W.; Lavallée, Y.; Cole, J. W.; Kennedy, B. M.; Villeneuve, M. C.


    Knowledge of the thermal properties of geothermal reservoir rocks is essential to constraining important engineering concerns such as wellbore stability, reservoir forecasting and stimulation procedures. The thermo-mechanical evolution of geological material is also important to assess when considering natural processes such as magmatic dyke propagation, contact metamorphism and magma/lava emplacement and cooling effects. To better constrain these properties in the geothermal reservoir, thermal measurements were carried out on core samples from production wells drilled in the Rotokawa Andesite geothermal reservoir, located in the Taupo Volcanic Zone, New Zealand. Linear thermal expansion testing, thermogravimetric analysis, and differential scanning calorimetry were used, employing experimental heating rates of 2, 5 and 20 °C/min. Thermal property analyses can elucidate whether thermal expansion values measured under varied heating (and cooling) rates are rate dependent and if thermo-chemical reactions influence the resultant expansivity. Measured thermal expansion coefficients of the Rotokawa Andesite are shown not to be heating rate dependent. We have also found that significant thermochemical reactions occur during heating above 500 °C resulting in non-reversible changes to the thermomechanical properties. The combined thermogravimetric, calorimetric and thermomechanical analysis allows insight to the reactions occurring and how the thermomechanical properties are affected at high temperature. We incorporated results of tensile strength testing on the Rotokawa Andesite to apply our thermal property measurements to a one-dimensional thermal stress model. The developed model provides a failure criterion for the Rotokawa Andesite under thermal stress. The importance of this study is to further understand the critical heating and cooling rates at which thermal stress may cause cracking within the Rotokawa reservoir. Thermal cracking in the reservoir can be

  4. Complex investigation of thermo-technical parameters of Ruskov andesite

    Directory of Open Access Journals (Sweden)

    František Krepelka


    Full Text Available The research of thermo-technical parameters of Ruskov andesite was made as a part of the complex research of its properties as well as of rock disintegration by the action of chemical flame on the rock surface, i.e. thermal spalling in particular. Thermal spalling is a process in which thermal stresses are induced in the surface layer of rock whose surface is thereby disintegrated into small parts, the so called spalls, by the brittle manner. The evaluation of thermo-technical properties of the studied rocks is necessary for the qualification and quantification of the thermal spalling process. The measured and evaluated parameters were the coefficient of linear thermal expansion, the coefficient of thermal conductivity, the specific heat capacity and the coefficient of thermal diffusivity. Andesite from the Ruskov locality was chosen as a basic experimental material for the investigation of thermal spalling upon preliminary experiments. The estimated thermo-technical parameters were analyzed regarding the application of thermal spalling for the disintegration of the Ruskov andesite. The outcome as that the values of determine thermo-technical parameters established an expectation for its successful application.

  5. Andesite Petrogenesis in Nevado de Toluca Stratovolcano, Central Mexico (United States)

    Gomez-Tuena, A.; Capra, L.; Cai, Y.; Goldstein, S. L.


    A popular model for andesite petrogenesis in continental arcs involves a hydrous parental basalt that fractionates and probably assimilates continental crust during ascent. Nevertheless, andesites erupted from polygenetic volcanoes in the Trans-Mexican Volcanic Belt are not entirely consistent with this scenario because: (1) they display a shift to higher SiO2 contents at similar Mg# than true basalts, (2) they trend to lower HREE and HFSE contents with increasing SiO2, and (3) they often show correlated isotopic compositions with proxies for slab inputs but not with fractionation indexes. Young andesites from Toluca stratovolcano (1-0.042 Ma) also display modest adakite-like features (Sr/YToluca rock-suite revealed that some other andesites (2.6-1 Ma) also exhibit very strong negative Ce (Ce/Ce~0.25) anomalies, fractionated HREE patterns (Gd/Yb~4.2), as well as low Zr/Sm (~12.6), and Sr/Y (~12) ratios. These features are not easily explained by low or even high pressure differentiation from a common primitive magma, unless enormous quantities of fractionating accessory minerals are taken into account. And yet these geochemical signals are almost identical to those observed in the pelagic sedimentary horizon of the subducted Cocos plate sampled at DSDP site 487, and thus provide strong evidence for slab-derived sediment contributions to the petrogenesis of Toluca andesites. Since sediment transfer to the Toluca source must have occurred in the form of a silicate melt, the new evidence brings further support to the slab melting hypothesis in the Mexican subduction zone. Interestingly, Ce/Pb ratios of the Toluca rocks display a linear positive correlation with Pb isotopes, that departs from the pelagic sediment values, and extends to the enriched Pb isotopic compositions of intraplate-type volcanic rocks from the Chichinautzin volcanic field. Thus the Toluca rocks likely represent discrete slab-derived melts coming from different portions of the subducted slab that

  6. Dry Grinding Kinetics of Gölbaşı (Ankara) Andesite in Ball Mill.


    T. Agacayak; A. Aras


    Kinetic study using a laboratory steel ball mill was carried out to determine dry grinding properties of andesite sample. The Si (specific rate of breakage) values were determined by using the single sized feed fractions of - 850+600 µm, -600+425 µm and -425+300 µm. Dry grinding of single size intervals showed that andesite followed the first-order breakage law. The breakage parameters of andesite in terms of the Si, aT and α values were determined.

  7. Magma heating by decompression-driven crystallization beneath andesite volcanoes. (United States)

    Blundy, Jon; Cashman, Kathy; Humphreys, Madeleine


    Explosive volcanic eruptions are driven by exsolution of H2O-rich vapour from silicic magma. Eruption dynamics involve a complex interplay between nucleation and growth of vapour bubbles and crystallization, generating highly nonlinear variation in the physical properties of magma as it ascends beneath a volcano. This makes explosive volcanism difficult to model and, ultimately, to predict. A key unknown is the temperature variation in magma rising through the sub-volcanic system, as it loses gas and crystallizes en route. Thermodynamic modelling of magma that degasses, but does not crystallize, indicates that both cooling and heating are possible. Hitherto it has not been possible to evaluate such alternatives because of the difficulty of tracking temperature variations in moving magma several kilometres below the surface. Here we extend recent work on glassy melt inclusions trapped in plagioclase crystals to develop a method for tracking pressure-temperature-crystallinity paths in magma beneath two active andesite volcanoes. We use dissolved H2O in melt inclusions to constrain the pressure of H2O at the time an inclusion became sealed, incompatible trace element concentrations to calculate the corresponding magma crystallinity and plagioclase-melt geothermometry to determine the temperature. These data are allied to ilmenite-magnetite geothermometry to show that the temperature of ascending magma increases by up to 100 degrees C, owing to the release of latent heat of crystallization. This heating can account for several common textural features of andesitic magmas, which might otherwise be erroneously attributed to pre-eruptive magma mixing.

  8. Viscosity measurements of crystallizing andesite from Tungurahua volcano (Ecuador). (United States)

    Chevrel, Magdalena Oryaëlle; Cimarelli, Corrado; deBiasi, Lea; Hanson, Jonathan B; Lavallée, Yan; Arzilli, Fabio; Dingwell, Donald B


    Viscosity has been determined during isothermal crystallization of an andesite from Tungurahua volcano (Ecuador). Viscosity was continuously recorded using the concentric cylinder method and employing a Pt-sheathed alumina spindle at 1 bar and from 1400°C to subliquidus temperatures to track rheological changes during crystallization. The disposable spindle was not extracted from the sample but rather left in the sample during quenching thus preserving an undisturbed textural configuration of the crystals. The inspection of products quenched during the crystallization process reveals evidence for heterogeneous crystal nucleation at the spindle and near the crucible wall, as well as crystal alignment in the flow field. At the end of the crystallization, defined when viscosity is constant, plagioclase is homogeneously distributed throughout the crucible (with the single exception of experiment performed at the lowest temperature). In this experiments, the crystallization kinetics appear to be strongly affected by the stirring conditions of the viscosity determinations. A TTT (Time-Temperature-Transformation) diagram illustrating the crystallization "nose" for this andesite under stirring conditions and at ambient pressure has been constructed. We further note that at a given crystal content and distribution, the high aspect ratio of the acicular plagioclase yields a shear-thinning rheology at crystal contents as low as 13 vol %, and that the relative viscosity is higher than predicted from existing viscosity models. These viscosity experiments hold the potential for delivering insights into the relative influences of the cooling path, undercooling, and deformation on crystallization kinetics and resultant crystal morphologies, as well as their impact on magmatic viscosity.

  9. Viscosity measurements of crystallizing andesite from Tungurahua volcano (Ecuador) (United States)

    Cimarelli, Corrado; deBiasi, Lea; Hanson, Jonathan B.; Lavallée, Yan; Arzilli, Fabio; Dingwell, Donald B.


    Abstract Viscosity has been determined during isothermal crystallization of an andesite from Tungurahua volcano (Ecuador). Viscosity was continuously recorded using the concentric cylinder method and employing a Pt‐sheathed alumina spindle at 1 bar and from 1400°C to subliquidus temperatures to track rheological changes during crystallization. The disposable spindle was not extracted from the sample but rather left in the sample during quenching thus preserving an undisturbed textural configuration of the crystals. The inspection of products quenched during the crystallization process reveals evidence for heterogeneous crystal nucleation at the spindle and near the crucible wall, as well as crystal alignment in the flow field. At the end of the crystallization, defined when viscosity is constant, plagioclase is homogeneously distributed throughout the crucible (with the single exception of experiment performed at the lowest temperature). In this experiments, the crystallization kinetics appear to be strongly affected by the stirring conditions of the viscosity determinations. A TTT (Time‐Temperature‐Transformation) diagram illustrating the crystallization “nose” for this andesite under stirring conditions and at ambient pressure has been constructed. We further note that at a given crystal content and distribution, the high aspect ratio of the acicular plagioclase yields a shear‐thinning rheology at crystal contents as low as 13 vol %, and that the relative viscosity is higher than predicted from existing viscosity models. These viscosity experiments hold the potential for delivering insights into the relative influences of the cooling path, undercooling, and deformation on crystallization kinetics and resultant crystal morphologies, as well as their impact on magmatic viscosity. PMID:27656114

  10. Dry Grinding Kinetics of Gölbaşı (Ankara Andesite in Ball Mill.

    Directory of Open Access Journals (Sweden)

    T. Agacayak


    Full Text Available Kinetic study using a laboratory steel ball mill was carried out to determine dry grinding properties of andesite sample. The Si (specific rate of breakage values were determined by using the single sized feed fractions of - 850+600 µm, -600+425 µm and -425+300 µm. Dry grinding of single size intervals showed that andesite followed the first-order breakage law. The breakage parameters of andesite in terms of the Si, aT and α values were determined.

  11. Origin of the volcanic rocks erupted in the eastern Manus Basin: Basaltic andesite-andesite-dacite associations (United States)

    Ma, Yao; Zeng, Zhigang; Chen, Shuai; Yin, Xuebo; Wang, Xiaoyuan


    There has been much recent interest in the origin of intermediate lava and several hypotheses are: 1) direct melting of the mantle under water-saturated conditions, 2) partial melting of altered crust, 3) fractional crystallization of parent magma, and 4) magma mixing of mafic magmas with dacitic/rhyolitic magmas. Volcanic rocks series ranging from basaltic andesite to dacite (SiO2 ranges from 53.8 to 63.0 wt.%) from the eastern Manus Basin were detected for major and trace element compositions to understand their origin. Low H2O contents, positive correlations of La-SiO2 and Yb-SiO2, oxygen isotope data and the indistinct change of trace element concentrations in oscillatory zoning of plagioclase phenocrysts rule out the models in which silicic lava results from direct melting of hydrous mantle, partial melting of altered oceanic crust or gabbros, and magma mixing, respectively. Besides, the geochemical data of whole rock and melt inclusions indicate that fractional crystallization plays a dominant role in generating the intermediate lava with subduction features.

  12. The anatomy of an andesite volcano: A time-stratigraphic study of andesite petrogenesis and crustal evolution at Ruapehu volcano, New Zealand

    DEFF Research Database (Denmark)

    Price, R.C.; Gamble, J.A.; Smith, I.E.M.


    Ruapehu, New Zealand’s largest active andesite volcano is located at the southern tip of the Taupo Volcanic Zone (TVZ), the main locus of subduction-related volcanism in the North Island. Geophysical data indicate that crustal thickness transitions from <25 km within the TVZ to 40 km beneath Ruap...

  13. Origin of secondary sulfate minerals on active andesitic stratovolcanoes (United States)

    Zimbelman, D.R.; Rye, R.O.; Breit, G.N.


    Sulfate minerals in altered rocks on the upper flanks and summits of active andesitic stratovolcanoes result from multiple processes. The origin of these sulfates at five active volcanoes, Citlalte??petl (Mexico), and Mount Adams, Hood, Rainier, and Shasta (Cascade Range, USA), was investigated using field observations, petrography, mineralogy, chemical modeling, and stable-isotope data. The four general groups of sulfate minerals identified are: (1) alunite group, (2) jarosite group, (3) readily soluble Fe- and Al-hydroxysulfates, and (4) simple alkaline-earth sulfates such as anhydrite, gypsum, and barite. Generalized assemblages of spatially associated secondary minerals were recognized: (1) alunite+silica??pyrite??kaolinite?? gypsum??sulfur, (2) jarosite+alunite+silica; (3) jarosite+smectite+silica??pyrite, (4) Fe- and Al-hydroxysulfates+silica, and (5) simple sulfates+silica??Al-hydroxysulfates??alunite. Isotopic data verify that all sulfate and sulfide minerals and their associated alteration assemblages result largely from the introduction of sulfur-bearing magmatic gases into meteoric water in the upper levels of the volcanoes. The sulfur and oxygen isotopic data for all minerals indicate the general mixing of aqueous sulfate derived from deep (largely disproportionation of SO2 in magmatic vapor) and shallow (oxidation of pyrite or H2S) sources. The hydrogen and oxygen isotopic data of alunite indicate the mixing of magmatic and meteoric fluids. Some alunite-group minerals, along with kaolinite, formed from sulfuric acid created by the disproportionation of SO2 in a condensing magmatic vapor. Such alunite, observed only in those volcanoes whose interiors are exposed by erosion or edifice collapse, may have ??34S values that reflect equilibrium (350??50 ??C) between aqueous sulfate and H2S. Alunite with ??34S values indicating disequilibrium between parent aqueous sulfate and H2S may form from aqueous sulfate created in higher level low

  14. Soils derived from Pieniny andesite, Wdżar hill, Outer Carpathians (Poland) (United States)

    Kajdas, Bartlomiej; Zaleski, Tomasz; Mazurek, Ryszard


    Tertiary andesite occurs in only few places in Polish part of the Outer Carpatians. The biggest andesitic body is observed at the Wdżar hill (676 m a.s.l), SE from Kluszkowce village. To the beginning of the 1970s active quarry were located at the hill slope, and from the end of 1990s Wdżar is used as a ski resort. Because Wdżar is the culmination protruding over sandstones and shales of Magura Unit of Outer Carpatians, it gives opportunity to investigate soils derived directly from the andesite. Primary, unaltered andesite contain mainly plagioclase (An28-62), amphibole (hornblende group), clinopiroxene (pigeonite group) and Fe-Ti oxides (Michalik et al., 2004). Quartz in those type of rocks is absent. Andesites from Pieniny Mts. contain low amount of silica (ca. 52-55% wt. in fresh and about 62% wt. in hydrothermally altered rocks), and high amount of CaO (5,5-9,2% wt.) and MgO (0,8-5,5% wt.) (Nejbert et al., 2012). Soils cover on Wdżar hill represents different stages of soil development. Shallow, ca. 15 cm deep, Eutric Leptosols and deeper, 60 cm and over 200 cm deep, Eutric Skeleti Cambisols (Colluvic, Humic) were distinguished. There are significant differences both between the soil groups as well as inside them. Investigated soils have sandy loam, loam and silt loam texture. Surface, organic horizons show acid reaction, but cambic and parent material horizons show neutral reaction. Cation exchange capacity ranges between 526.9 and 298.2 mmol(+)ṡkg-1 in humus horizons and between 451.4 and 225.8 mmol(+)ṡkg-1in cambic and parent material horizons. The amount of exchangeable Ca2+ ranges between 386.8 and 175.8 mmol(+)ṡkg-1 and is about 6 times higher than sum of Mg2+, Na+ and K+ in the soil horizon. Despite of the high amount of Ca2+, there were no active carbonates in investigated soil. The soils, that are developed from the andesite, usualy contain high amount of clays and very low amount of primary quartz. Andesite from Wdżar reveals minor degree

  15. The genetic relationship between andesites and dacites at Tungurahua volcano, Ecuador (United States)

    Nauret, F.; Samaniego, P.; Ancellin, M.-A.; Tournigand, P.-Y.; Le Pennec, J.-L.; Vlastelic, I.; Gannoun, A.; Hidalgo, S.; Schiano, P.


    Volcanic eruptions of intermediary and silica-rich magmas (andesites, dacites and rhyolites) in convergent arc settings generate voluminous and explosive eruptions that can strongly affect human activity and have significant environmental impacts. It is therefore crucial to understand how these magmas are generated in order to anticipate their potential impact. At convergent margins, primitive magmas (primitive basalts and/or andesites) are derived from the mantle wedge and they are progressively modified by physical and chemical processes operating between the melting zone and the surface to produce silica-rich magmas. In order to elucidate the relationship between andesites and dacites, we focus on Tungurahua volcano, located in the Ecuadorian Andes. We collected a set of samples comprising such lithologies that were erupted during the last 3000 year BP. This relatively short period of time allows us to assume that the geodynamic parameters remain constant. Petrology and major-trace element compositions of these lavas have already been examined, and so we performed a complementary Pb-Sr isotope study in order to determine the nature and origin of the components involved in andesite and dacite genesis. Sr isotopes range from 0.70417 to 0.70431, and Pb isotope compositions range from 18.889 to 19.154 for 206Pb/204Pb, from 15.658 to 15.696 for 207Pb/204Pb, and from 38.752 to 38.918 for 208Pb/204Pb. Dacites display a remarkably homogeneous Pb isotopic composition, with higher 206Pb/204Pb values for a given 207-208Pb/204Pb compared to andesites. Andesites show notable 207Pb/206Pb variations for a given SiO2 content, whereas dacites have lower and homogenous 207Pb/206Pb values. Andesite and dacite altogether plot in a roughly triangular distribution, with dacitic magmas systematically plotting at the high SiO2 and 87Sr/86Sr and low 207Pb/206Pb fields. Based on our new dataset, we show that at least 3 different components are required to explain the Tungurahua

  16. The material from Lampung as coarse aggregate to substitute andesite for concrete-making (United States)

    Amin, M.; Supriyatna, Y. I.; Sumardi, S.


    Andesite stone is usually used for split stone material in the concrete making. However, its availability is decreasing. Lampung province has natural resources that can be used for coarse aggregate materials to substitute andesite stone. These natural materials include limestone, feldspar stone, basalt, granite, and slags from iron processing waste. Therefore, a research on optimizing natural materials in Lampung to substitute andesite stone for concrete making is required. This research used laboratory experiment method. The research activities included making cubical object samples of 150 x 150 x 150 mm with material composition referring to a standard of K.200 and w/c 0.61. Concrete making by using varying types of aggregates (basalt, limestone, slag) and aggregate sizes (A = 5-15 mm, B = 15-25 mm, and 25-50 mm) was followed by compressive strength test. The results showed that the obtained optimal compressive strengths for basalt were 24.47 MPa for 50-150 mm aggregate sizes, 21.2 MPa for 15-25 mm aggregate sizes, and 20.7 MPa for 25-50 mm aggregate sizes. These results of basalt compressive strength values were higher than the same result for andesite (19.69 MPa for 50-150 mm aggregate sizes), slag (22.72 MPa for 50-150 mm aggregate sizes), and limestone (19.69 Mpa for 50-150 mm aggregate sizes). These results indicated that basalt, limestone, and slag aggregates were good enough to substitute andesite as materials for concrete making. Therefore, natural resources in Lampung can be optimized as construction materials in concrete making.

  17. Textural history of recent basaltic-andesites and plutonic inclusions from Merapi volcano (United States)

    van der Zwan, Froukje M.; Chadwick, Jane P.; Troll, Valentin R.


    Mt. Merapi in Central Java is one of the most active stratovolcanoes on Earth and is underlain by a multistage plumbing system. Crystal size distribution analyses (CSD) were carried out on recent Merapi basaltic-andesites and co-eruptive magmatic and plutonic inclusions to characterise the crystallisation processes that operate during storage and ascent and to obtain information on respective time scales. The basaltic-andesites exhibit log-linear, kinked-upwards CSD curves for plagioclase and clinopyroxene that can be separated into two main textural populations. Large plagioclase phenocrysts (≥1.6 mm) make up one population, but correspond to crystals with variable geochemical composition and reflect a period of crystal growth at deep to mid-crustal levels. This population was subsequently influenced by crystal accumulation and the onset of crustal assimilation, including the incorporation of high-Ca skarn-derived xenocrysts. Textural re-equilibration is required for these crystals to form a single population in CSD. A second episode of crystal growth at shallower levels is represented by chemically homogenous plagioclase crystals <1.6 mm in size. Crustal assimilation is indicated by, for example, oxygen isotopes and based on the CSD data, crystallisation combined with contamination is likely semi-continuous in these upper crustal storage chambers. The CSD data observed in the basaltic-andesite samples are remarkably consistent and require a large-volume steady state magmatic system beneath Merapi in which late textural equilibration plays a significant role. Plagioclase CSDs of co-eruptive magmatic and plutonic inclusions may contain a third crystal population (<1 mm) not found in the lavas. This third population has probably formed from enhanced degassing of portions of basaltic-andesite magma at shallow crustal levels which resulted in increased crystallinity and basaltic-andesite mush inclusions. A suite of coarse plutonic inclusions is also present that

  18. Sr isotope zoning in plagioclase from andesites at Cabo De Gata, Spai

    DEFF Research Database (Denmark)

    Waight, Tod Earle; Tørnqvist, Jakob


    Plagioclase crystals in andesites from the Cabo De Gata region show generally radiogenic Sr isotope compositions and consistent core to rim increases in 87Sr/86Sr that are indicative of open system processes in the lithosphere and crustal contamination during crystallization. High-grade metamorphic...... rocks of the Alpujárride and Nevado-Filábride complexes represent the most likely crustal contaminants. The plagioclases are characterized by subtly zoned and resorbed calcic cores (An73-86). These cores also have radiogenic 87Sr/86Sr (0.7127-0.7129), although less radiogenic than plagioclase rims......, groundmass plagioclase and whole rock compositions (up to 87Sr/86Sr = 0.7135). These cores are interpreted to represent early crystallization of plagioclase from hydrous melts emplaced into the lower crust. The parental melts to these andesites must therefore have already inherited their radiogenic Sr...

  19. Manupulation of microstructure, phase evolution and mechanical properties by devitrification of andesite for use as proppant (United States)

    Koseski, Ryan P.

    Small, roughly spherical ceramic particles, approximately 1mm in size are used for a number of applications including casting sands, catalysts, and cement fillers. The oil and natural gas industry utilizes such materials in tonnage quantities yearly as extraction aids. Particles intended for this application are referred to as proppants. Proppants are composed of materials that differ by density, strength and cost, and are selected on a site by site basis. Recently, competing usage and depletion of reserves of one of the most popular category of proppant materials, sintered aluminosilicates (e.g. kaolinite, bauxite) have driven the need for alternative raw materials for proppant manufacturing. Andesite, a by-product of mining operations in the south-west United States was identified as an abundant, readily available, and low cost alternative proppant material that can be fused and net-shaped into a glass which when crystallized results in microstructures which may offer substantial toughening and fracture characteristics which may serve to their advantage for use as proppants that do not decrease the permeability ("blind") the particle bed. This study addressed the devitrification behavior and its role on the mechanical properties of andesite-based glass-ceramic spheres for use as proppants. Timetemperature- transformation studies were performed to evaluate the devitrification behavior of andesite glass. Crystalline phase evolution and microstructural development were evaluated using quantitative x-ray diffraction, scanning electron microscopy, differential thermal analysis, and spectrophotometry. The andesite glass devitrification commenced with the precipitation of iron oxides (magnetite) which served as seeds for the epitaxial growth of dendritic pyroxenes. Mechanical properties, such as diametral compressive strength, fracture toughness, hardness, and fracture morphology were correlated with crystalline phase evolution. Selected heat treatments resulting in the

  20. Antisana volcano: A representative andesitic volcano of the eastern cordillera of Ecuador: Petrography, chemistry, tephra and glacial stratigraphy (United States)

    Hall, Minard L.; Mothes, Patricia A.; Samaniego, Pablo; Militzer, Annemarie; Beate, Bernardo; Ramón, Patricio; Robin, Claude


    Antisana volcano is representative of many active andesitic strato-volcanoes of Pleistocene age in Ecuador's Eastern Cordillera. This study represents the first modern geological and volcanological investigation of Antisana since the late 1890's; it also summarizes the present geochemical understanding of its genesis. The volcano's development includes the formation and destruction of two older edifices (Antisana I and II) during some 400 + ka. Antisana II suffered a sector collapse about 15,000 years ago which was followed by the birth and growth of Antisana III. During its short life Antisana III has generated ≥50 eruptions of small to medium intensity, often associated with andesitic to dacitic lava flows and tephra, as well as with late Pleistocene and Holocene glacial advances. Throughout its long history Antisana's lavas have been characterized by a persistent mineral assemblage, consisting of 30-40 vol% phenocrysts of plagioclase, both clino- and orthopyroxene, and Fe-Ti oxides, with rare occurrences of olivine or amphibole, frequently in a microcrystalline to glassy matrix. This uniformity occurs despite the magma's progressive chemical evolution over ≥400 ka from early basic andesites (53-58 wt% SiO2) to intermediate and Si-rich andesites (58-62% SiO2), and recently to dacites (63-67% SiO2). Chemical diagrams suggest that crystal fractionation was the most likely magmatic process of evolution. The exception to this slowly evolving history was the short-lived emission at ∼210 ka of the Cuyuja lavas from Antisana II that generated a 73 km long andesitic lava flow. Contrasting with Antisana's general magmatic trend, Cuyuja lava (∼11 km3) is a high-Mg andesite with unusually high concentrations of incompatible elements. Antisana developed within the Chacana caldera complex, a large active siliceous center that began ∼3 Ma ago, however its lavas are chemically distinct from coeval lavas of Chacana.

  1. Thermal properties of andesite from Popocatepetl and Volcán de Colima, México. (United States)

    Cardenas-Sanchez, Enrique; De la Cruz-Reina, Servando; Varley, Nick


    The thermal conductivity (K), specific heat (Cp) and the coefficient of heat transfer surface (H) are the basic parameters to describe the process of cooling a volcanic rock fragment released in an explosive event. The analysis of the cooling process by conduction, convection and radiation of heat in volcanic rock fragments, has been limited to basalts, and various minerals such as olivine, pyroxene, quartz, etc. (Miao & Chen, 2014; Branlund & Hofmeister, 2012; Romine et al, 2012;. Schön, 2011; Stroberg et al, 2010;. Schatz & Simmons, 1972). There are no detailed studies on the thermal properties of the andesites, abundant in continental stratovolcanoes, and particularly susceptible from lava domes with frequent destruction processes, such as Popocatepetl and Volcan de Colima. Previously, we developed an algorithm for calculation of the grain-size distribution, degree of fragmentation, the thermal energy released and its possible correlation with Volcanic Explosive Index (VEI) from the cooling curves of fragments from vulcanian and strombolian explosions. These curves were obtained from sequences of time over incandescent deposits recorded at selected pixel thermal images of vulcanian activity in the Popocatepetl and Volcan de Colima, Mexico. However, the model was limited by the lack of thermal parameters of the andesites, forcing a first approximation using basalts data. We present a simple model for the cooling process using andesites samples from Popocatépetl and Volcan de Colima. First, the samples were subjected to a rounding process to minimize surface effects. Then, heated to 800 ° C were extracted from the muffle and cooling rate is measured. The thermal conductivity and coefficient of surface heat are determined using a thermal camera and three thermocouples embedded at various depths within the sample. An inversion method was implemented to determine the thermal properties parameters , by comparing the observed data regarding cooling model for a solid

  2. Sulfur isotope fractionation between fluid and andesitic melt: An experimental study (United States)

    Fiege, Adrian; Holtz, François; Shimizu, Nobumichi; Mandeville, Charles W.; Behrens, Harald; Knipping, Jaayke L.


    Glasses produced from decompression experiments conducted by Fiege et al. (2014a) were used to investigate the fractionation of sulfur isotopes between fluid and andesitic melt upon magma degassing. Starting materials were synthetic glasses with a composition close to a Krakatau dacitic andesite. The glasses contained 4.55–7.95 wt% H2O, ∼140 to 2700 ppm sulfur (S), and 0–1000 ppm chlorine (Cl). The experiments were carried out in internally heated pressure vessels (IHPV) at 1030 °C and oxygen fugacities (fO2) ranging from QFM+0.8 log units up to QFM+4.2 log units (QFM: quartz–fayalite–magnetite buffer). The decompression experiments were conducted by releasing pressure (P) continuously from ∼400 MPa to final P of 150, 100, 70 and 30 MPa. The decompression rate (r) ranged from 0.01 to 0.17 MPa/s. The samples were annealed for 0–72 h (annealing time, tA) at the final P and quenched rapidly from 1030 °C to room temperature (T).The decompression led to the formation of a S-bearing aqueous fluid phase due to the relatively large fluid–melt partitioning coefficients of S. Secondary ion mass spectrometry (SIMS) was used to determine the isotopic composition of the glasses before and after decompression. Mass balance calculations were applied to estimate the gas–melt S isotope fractionation factor αg-m.No detectable effect of r and tA on αg-m was observed. However, SIMS data revealed a remarkable increase of αg-m from ∼0.9985 ± 0.0007 at >QFM+3 to ∼1.0042 ± 0.0042 at ∼QFM+1. Noteworthy, the isotopic fractionation at reducing conditions was about an order of magnitude larger than predicted by previous works. Based on our experimental results and on previous findings for S speciation in fluid and silicate melt a new model predicting the effect of fO2 on αg-m (or Δ34Sg–m) in andesitic systems at 1030 °C is proposed. Our experimental results as well as our modeling are of high importance for the interpretation of S isotope

  3. Using mineral geochemistry to decipher slab, mantle, and crustal input in the generation of high-Mg andesites and basaltic andesites from the northern Cascade Arc (United States)

    Sas, May; DeBari, Susan; Clynne, Michael A.; Rusk, Brian G.


    To better understand the role of slab melt in the petrogenesis of North Cascades magmas, this study focuses on petrogenesis of high-Mg lavas from the two northernmost active volcanoes in Washington. High-Mg andesites (HMA) and basaltic andesites (HMBA) in the Cascade Arc have high Mg# [molar Mg/(Mg+Fe2+)] relative to their SiO2 contents, elevated Nd/Yb, and are Ni- and Cr-enriched. The rock units examined here include the Tarn Plateau HMBA (51.8–54.0 wt% SiO2, Mg# 68–70) and Glacier Creek HMA (58.3–58.7 wt% SiO2, Mg# 63–64) from the Mount Baker Volcanic Field, and the Lightning Creek HMBA (54.8–54.6 SiO2, Mg# 69–73) from Glacier Peak. This study combines major and trace element compositions of minerals and whole rocks to test several petrogenetic hypotheses and to determine which, if any, are applicable to North Cascades HMA and HMBA. In the Tarn Plateau HMBA, rare earth element (REE) equilibrium liquids calculated from clinopyroxene compositions have high Nd/Yb that positively correlates with Mg#. This correlation suggests an origin similar to that proposed for Aleutian adakites, where intermediate, high Nd/Yb slab-derived melts interact with the overlying mantle to become Mg-rich, and subsequently mix with low Nd/Yb, mantle-derived mafic magmas with lower Mg#. In the Glacier Creek HMA, elevated whole-rock MgO and SiO2 contents resulted from accumulation of xenocrystic olivine and differentiation processes, respectively, but the cause of high Nd/Yb is less clear. However, high whole-rock Sr/P (fluid mobile/fluid immobile) values indicate a mantle source that was fluxed by an enriched, hydrous slab component, likely producing the observed high Nd/Yb REE signature. The Lightning Creek HMBA is a hybridized rock unit with at least three identifiable magmatic components, but only one of which has HMA characteristics. Cr and Mg contents in Cr-spinel and olivine pairs in this HMA component suggest that its source is a strongly depleted mantle, and high

  4. The glaciovolcanic evolution of an andesitic edifice, South Crater, Tongariro volcano, New Zealand (United States)

    Cole, R. P.; White, J. D. L.; Conway, C. E.; Leonard, G. S.; Townsend, D. B.; Pure, L. R.


    Unusual deposits, mapped and logged in detail, around the summit area of Tongariro volcano, Tongariro Volcanic Centre, New Zealand indicate that the construction and evolution of a substantial portion of this andesitic stratovolcano was beneath a significant ice cap or summit glacier. As the edifice was built under and through the overlying ice, the style of volcanism evolved in a complex history of growth. Initially, a ≥ 100 m thick, widespread hyaloclastite deposit was emplaced within a subglacial, eruption-formed meltwater lake. This was followed by several phases of effusive and explosive eruptions, producing lava flows and primary volcaniclastic deposits emplaced along channels carved into the ice by heated meltwater. The clastic deposits contain quenched bombs and structural features that indicate waterlain transport and emplacement, and soft sediment deformation. Such accumulation of water on a steep-sided edifice without evidence for a subaerial crater lake, along with lava flow features indicating confinement, suggest that a substantial summit glacier was responsible for the production and retention of water, and the architecture of these deposits. Recent studies at nearby Ruapehu volcano have provided good evidence for glaciovolcanic interactions during the last glacial period. However, until now, little was known of the physical lava-ice interactions in the Centre during the last interglacial period and the earlier part of the last glacial period (110-64 ka). These new data support a reinterpretation for the volcanic evolution of the older Tongariro edifice and the emplacement mechanisms of primary volcaniclastic deposits. They also help to constrain local ice thicknesses and extents at the times of eruption. In addition, this study contributes to a sparse global catalogue of glaciovolcanic deposits of andesitic composition, particularly of primary volcaniclastics preserved at mid-latitude stratovolcanoes. The variety of deposit types indicates a

  5. Generation of new continental crust by sublithospheric silicic-magma relamination in arcs: A test of Taylor's andesite model

    NARCIS (Netherlands)

    Castro, Antonio; Vogt, Katharina|info:eu-repo/dai/nl/370618947; Gerya, Taras


    The paradox of the Earth's continental crust is that although this reservoir is generally regarded as having differentiated from the mantle, it has an andesitic bulk composition that contrasts with the intrinsic basaltic composition of mantle-derived melts. Classical models for new crust generation

  6. Subaqueous cryptodome eruption, hydrothermal activity and related seafloor morphologies on the andesitic North Su volcano (United States)

    Thal, Janis; Tivey, Maurice; Yoerger, Dana R.; Bach, Wolfgang


    North Su is a double-peaked active andesite submarine volcano located in the eastern Manus Basin of the Bismarck Sea that reaches a depth of 1154 m. It hosts a vigorous and varied hydrothermal system with black and white smoker vents along with several areas of diffuse venting and deposits of native sulfur. Geologic mapping based on ROV observations from 2006 and 2011 combined with morphologic features identified from repeated bathymetric surveys in 2002 and 2011 documents the emplacement of a volcanic cryptodome between 2006 and 2011. We use our observations and rock analyses to interpret an eruption scenario where highly viscous, crystal-rich andesitic magma erupted slowly into the water-saturated, gravel-dominated slope of North Su. An intense fragmentation process produced abundant blocky clasts of a heterogeneous magma (olivine crystals within a rhyolitic groundmass) that only rarely breached through the clastic cover onto the seafloor. Phreatic and phreatomagmatic explosions beneath the seafloor cause mixing of juvenile and pre-existing lithic clasts and produce a volcaniclastic deposit. This volcaniclastic deposit consists of blocky, non-altered clasts next, variably (1-100%) altered clasts, hydrothermal precipitates and crystal fragments. The usually applied parameters to identify juvenile subaqueous lava fragments, i.e. fluidal shape or chilled margin, were not applicable to distinguish between pre-existing non-altered clasts and juvenile clasts. This deposit is updomed during further injection of magma and mechanical disruption. Gas-propelled turbulent clast-recycling causes clasts to develop variably rounded shapes. An abundance of blocky clasts and the lack of clasts typical for the contact of liquid lava with water is interpreted to be the result of a cooled, high-viscosity, crystal-rich magma that failed as a brittle solid upon stress. The high viscosity allows the lava to form blocky and short lobes. The pervasive volcaniclastic cover on North Su is

  7. Controls on long-term low explosivity at andesitic arc volcanoes: Insights from Mount Hood, Oregon (United States)

    Koleszar, Alison M.; Kent, Adam J. R.; Wallace, Paul J.; Scott, William E.


    The factors that control the explosivity of silicic volcanoes are critical for hazard assessment, but are often poorly constrained for specific volcanic systems. Mount Hood, Oregon, is a somewhat atypical arc volcano in that it is characterized by a lack of large explosive eruptions over the entire lifetime of the current edifice (~ 500,000 years). Erupted Mount Hood lavas are also compositionally homogeneous, with ~ 95% having SiO2 contents between 58 and 66 wt.%. The last three eruptive periods in particular have produced compositionally homogeneous andesite-dacite lava domes and flows. In this paper we report major element and volatile (H2O, CO2, Cl, S, F) contents of melt inclusions and selected phenocrysts from these three most recent eruptive phases, and use these and other data to consider possible origins for the low explosivity of Mount Hood. Measured volatile concentrations of melt inclusions in plagioclase, pyroxene, and amphibole from pumice indicate that the volatile contents of Mount Hood magmas are comparable to those in more explosive silicic arc volcanoes, including Mount St. Helens, Mount Mazama, and others, suggesting that the lack of explosive activity is unlikely to result solely from low intrinsic volatile concentrations or from substantial degassing prior to magma ascent and eruption. We instead argue that an important control over explosivity is the increased temperature and decreased magma viscosity that results from mafic recharge and magma mixing prior to eruption, similar to a model recently proposed by Ruprecht and Bachmann (2010). Erupted Mount Hood magmas show extensive evidence for mixing between magmas of broadly basaltic and dacitic-rhyolitic compositions, and mineral zoning studies show that mixing occurred immediately prior to eruption. Amphibole chemistry and thermobarometry also reveal the presence of multiple amphibole populations and indicate that the mixed andesites and dacites are at least 100 °C hotter than the high-SiO2

  8. Petrogenesis of Mount Rainier andesite: magma flux and geologic controls on the contrasting differentiation styles at stratovolcanoes of the southern Washington Cascades (United States)

    Sisson, Thomas W.; Salters, V.J.M.; Larson, P.B.


    Quaternary Mount Rainier (Washington, USA) of the Cascades magmatic arc consists of porphyritic calc-alkaline andesites and subordinate dacites, with common evidence for mingling and mixing with less evolved magmas encompassing andesites, basaltic andesites, and rarely, basalts. Basaltic andesites and amphibole andesites (spessartites) that erupted from vents at the north foot of the volcano represent some of Mount Rainier's immediate parents and overlap in composition with regional basalts and basaltic andesites. Geochemical (major and trace elements) and isotopic (Sr, Nd, Pb, O) compositions of Mount Rainier andesites and dacites are consistent with modest assimilation (typically ≤20 wt%) of evolved sediment or sediment partial melt. Sandstones and shales of the Eocene Puget Group, derived from the continental interior, are exposed in regional anticlines flanking the volcano, and probably underlie it in the middle to lower crust, accounting for their assimilation. Mesozoic and Cenozoic igneous basement rocks are unsuitable as assimilants due to their high 143Nd/144Nd, diverse206Pb/204Pb, and generally high δ18O.

  9. Slab-derived melt involvement in petrogenesis of the high-Nb basalts and magnesian andesites-dacites from NE Iran (United States)

    Ahmadi, Parham; Ghorbani, Mohammad Reza; Coltorti, Massimo; Kuritani, Takeshi; Cai, Yue; Fioretti, Anna Maria; Braschi, Eleonora; Giacomoni, Pier Paolo; Babazadeh, Shahrouz; Conticelli, Sandro


    Tertiary volcanic rocks in NW Firoozeh region, also known as Meshkan triangular structural unit, represent an episode of Tertiary post-collisional magmatism in NE Iran. The volcanic suite is made of Magnesian andesites to dacites associated with some high-Nb basalts. Despite a rather restricted range of emplacement age, variable from 24.1 to 21.7 Ma obtained on the basis of 40Ar-39Ar dating. Major and trace element data show that Firoozeh volcanic rocks were derived from two distinct parental magmas. The dominant high magnesian magmatic series constitutes a wide spectrum of volcanic rocks from andesite to dacite. The magnesian andesites-dacites are subalkaline and characterized by rather high MgO, Ni, Cr and Sr/Y ratio. High Sr/Y ratio of the magnesian andesites-dacites as well as their Sr-Nd isotopic composition support the notion that the magnesian andesites were originated by interaction of slab derived melts with overlying mantle wedge. Fractional crystallization of an amphibole and plagioclase mineral assemblage is found responsible for evolutionary path form the magnesian andesite to more evolved rocks. In contrast to the sabalkaline magnesian andesites- dacites, the high Nb basalts are sodic alkaline rocks and show silica-undersaturated degree. The high-Nb basalts are enriched in Nb, and a wide range of incompatible trace elements that include LILE, LREE. Almost identical Sr-Nd isotopic composition of the magnesian andesites-dacites and high-Nb basalts imply that the two magmatic series has probably shared a common mantle source. Generation of parental magmas of the two magmatic series are attributed to the asthenospheric upwelling and subsequent partial melting of mantle metasomatized by slab-derived melts. Key words: slab melt, High-Nb basalt, 40Ar/39Ar, High-Mg andesite

  10. Antisana volcano : a representative andesitic volcano of the eastern cordillera of Ecuador : petrography, chemistry, tephra and glacial stratigraphy


    Hall, M. L.; Mothes, P. A.; Samaniego, Pablo; Militzer, A.; Beate, B.; Ramon, P.; Robin, Claude


    Antisana volcano is representative of many active andesitic strato-volcanoes of Pleistocene age in Ecuador's Eastern Cordillera. This study represents the first modern geological and volcanological investigation of Antisana since the late 1890's; it also summarizes the present geochemical understanding of its genesis. The volcano's development includes the formation and destruction of two older edifices (Antisana I and II) during some 400 + ka. Antisana II suffered a sector collapse about 15,...

  11. Geometry and structure of the andesitic volcano-detritic deposits: The Merapi case (United States)

    Selles, A.; Deffontaines, B.; Hendrayana, H.; Violette, S.


    Several geological studies have been performed on the volcano-detritic deposits but finally the global overview of the geometry of those is still poorly known. The quick alteration enhances the high heterogeneity of these formations, especially under tropical climate. Better knowledge of the structure of the volcano-sedimentary edifices is capital to understand:i) the geomorphological impacts, as landslides ii) or the hydrogeological processes. The Merapi Mount is an andesitic strato-volcano, located in Central Java and is one of the most active volcanoes in Indonesia. About 500,000 people live in the immediate vicinity of the volcano and are directly subject, not only to the volcanic eruptions but also to the landslide hazards. The East flank of the Merapi presents a complex history and has been relatively spared by the recent volcanic activity; thus, the geomorphology and the structure of the deposit have been driven by the erosion and remobilization processes under equatorial climate. This work contributes to understand the processes of construction, destruction and sedimentation of a complex active strato-volcano and shed light to its geological and geomorphological history. Based on field observations and literature, the specific deposits have been identified. The lithological facies have been described and several cross sections have been done to precise the distinct phases of building edifice, due to old eruptions. Recent field surveys allowed characterizing the dismantling steps and processes of the volcano by erosion and the local to distal sedimentation associated. The East flank has been split in four zones where each formation presents a lateral facies variation depending on the distance from the summit and the age of deposits. Based on the collected data, the size and the three dimensional extension of each deposits has been delimitated. The geological and geomorphological interpretation is proposed through a conceptual model.

  12. Thermodynamic controls on element partitioning between titanomagnetite and andesitic-dacitic silicate melts (United States)

    Sievwright, R. H.; Wilkinson, J. J.; O'Neill, H. St. C.; Berry, A. J.


    Titanomagnetite-melt partitioning of Mg, Mn, Al, Ti, Sc, V, Co, Ni, Cu, Zn, Ga, Zr, Nb, Mo, Hf and Ta was investigated experimentally as a function of oxygen fugacity ( fO2) and temperature ( T) in an andesitic-dacitic bulk-chemical compositional range. In these bulk systems, at constant T, there are strong increases in the titanomagnetite-melt partitioning of the divalent cations (Mg2+, Mn2+, Co2+, Ni2+, Zn2+) and Cu2+/Cu+ with increasing fO2 between 0.2 and 3.7 log units above the fayalite-magnetite-quartz buffer. This is attributed to a coupling between magnetite crystallisation and melt composition. Although melt structure has been invoked to explain the patterns of mineral-melt partitioning of divalent cations, a more rigorous justification of magnetite-melt partitioning can be derived from thermodynamic principles, which accounts for much of the supposed influence ascribed to melt structure. The presence of magnetite-rich spinel in equilibrium with melt over a range of fO2 implies a reciprocal relationship between a(Fe2+O) and a(Fe3+O1.5) in the melt. We show that this relationship accounts for the observed dependence of titanomagnetite-melt partitioning of divalent cations with fO2 in magnetite-rich spinel. As a result of this, titanomagnetite-melt partitioning of divalent cations is indirectly sensitive to changes in fO2 in silicic, but less so in mafic bulk systems.

  13. An experimental investigation of high-temperature interactions between seawater and rhyolite, andesite, basalt and peridotite (United States)

    Hajash, Andrew; Chandler, Gary W.


    Natural seawater was allowed to react with rhyolite, andesite, basalt, and peridotite at 200° 500° C, and 1,000 bars at water/rock mass ratios of 5 and 50 in order to investigate the effects of rock type, water/rock ratio, and temperature on solution chemistry and alteration mineralogy. The results indicate that interactions of seawater with various igneous rocks are similar in the production of a hydrous Mg-silicate and anhydrite as major alteration products. Fluids involved in the interactions lose Mg to alteration phases while leaching Fe, Mn, and Si from the rocks. The pH of the solutions is primarily controlled by Mg-OH-silicate formation and therefore varies with Mg and Si concentration of the system. Other reactions which involve Mg (such as Mg-Ca exchange) or which produce free H+, cause major differences in fluid chemistry between different seawater/ rock systems. High water/rock ratio systems (50/1) are generally more acidic and more efficient in leaching than low ratio systems (5/1), due to relatively more seawater Mg available for Mgsilicate production. The experiments show that large-scale seawater/rock interaction could exert considerable control on the chemistry of seawater, as well as producing large bodies of altered rock with associated ore-deposits. Active plate margins of convergence or divergence are suitable environments for hydrothermal systems due to the concurrence of igneous activity, tectonism, and a nearby water reservoir (seawater or connate water). The experimental data indicate that seawater interactions with igneous host rocks could generate many of the features of ore-deposits such as the Kuroko deposits of Japan, the Raul Mine of Peru, the Bleida deposit of Morocco, and deposits associated with ophiolites. Serpentinization of peridotite and alteration of igneous complexes associated with plate margins can also be explained by seawater interaction with the cooling rock. Geothermal energy production could benefit from experimental

  14. Evidence for tectonic, lithologic, and thermal controls on fracture system geometries in an andesitic high-temperature geothermal field (United States)

    Massiot, Cécile; Nicol, Andrew; McNamara, David D.; Townend, John


    Analysis of fracture orientation, spacing, and thickness from acoustic borehole televiewer (BHTV) logs and cores in the andesite-hosted Rotokawa geothermal reservoir (New Zealand) highlights potential controls on the geometry of the fracture system. Cluster analysis of fracture orientations indicates four fracture sets. Probability distributions of fracture spacing and thickness measured on BHTV logs are estimated for each fracture set, using maximum likelihood estimations applied to truncated size distributions to account for sampling bias. Fracture spacing is dominantly lognormal, though two subordinate fracture sets have a power law spacing. This difference in spacing distributions may reflect the influence of the andesitic sequence stratification (lognormal) and tectonic faults (power law). Fracture thicknesses of 9-30 mm observed in BHTV logs, and 1-3 mm in cores, are interpreted to follow a power law. Fractures in thin sections (˜5 μm thick) do not fit this power law distribution, which, together with their orientation, reflect a change of controls on fracture thickness from uniform (such as thermal) controls at thin section scale to anisotropic (tectonic) at core and BHTV scales of observation. However, the ˜5% volumetric percentage of fractures within the rock at all three scales suggests a self-similar behavior in 3-D. Power law thickness distributions potentially associated with power law fluid flow rates, and increased connectivity where fracture sets intersect, may cause the large permeability variations that occur at hundred meter scales in the reservoir. The described fracture geometries can be incorporated into fracture and flow models to explore the roles of fracture connectivity, stress, and mineral precipitation/dissolution on permeability in such andesite-hosted geothermal systems.

  15. Tephra from andesitic Shiveluch volcano, Kamchatka, NW Pacific: chronology of explosive eruptions and geochemical fingerprinting of volcanic glass (United States)

    Ponomareva, Vera; Portnyagin, Maxim; Pevzner, Maria; Blaauw, Maarten; Kyle, Philip; Derkachev, Alexander


    The ~16-ka-long record of explosive eruptions from Shiveluch volcano (Kamchatka, NW Pacific) is refined using geochemical fingerprinting of tephra and radiocarbon ages. Volcanic glass from 77 prominent Holocene tephras and four Late Glacial tephra packages was analyzed by electron microprobe. Eruption ages were estimated using 113 radiocarbon dates for proximal tephra sequence. These radiocarbon dates were combined with 76 dates for regional Kamchatka marker tephra layers into a single Bayesian framework taking into account the stratigraphic ordering within and between the sites. As a result, we report ~1,700 high-quality glass analyses from Late Glacial-Holocene Shiveluch eruptions of known ages. These define the magmatic evolution of the volcano and provide a reference for correlations with distal fall deposits. Shiveluch tephras represent two major types of magmas, which have been feeding the volcano during the Late Glacial-Holocene time: Baidarny basaltic andesites and Young Shiveluch andesites. Baidarny tephras erupted mostly during the Late Glacial time (~16-12.8 ka BP) but persisted into the Holocene as subordinate admixture to the prevailing Young Shiveluch andesitic tephras (~12.7 ka BP-present). Baidarny basaltic andesite tephras have trachyandesite and trachydacite (SiO2 SiO2 > 71.5 wt%). Strongly calc-alkaline medium-K characteristics of Shiveluch volcanic glasses along with moderate Cl, CaO and low P2O5 contents permit reliable discrimination of Shiveluch tephras from the majority of other large Holocene tephras of Kamchatka. The Young Shiveluch glasses exhibit wave-like variations in SiO2 contents through time that may reflect alternating periods of high and low frequency/volume of magma supply to deep magma reservoirs beneath the volcano. The compositional variability of Shiveluch glass allows geochemical fingerprinting of individual Shiveluch tephra layers which along with age estimates facilitates their use as a dating tool in paleovolcanological

  16. Dynamics of explosive paroxysms at open-vent andesitic systems: High-resolution mass distribution analyses of the 2006 Tungurahua fall deposit (Ecuador) (United States)

    Eychenne, Julia; Le Pennec, Jean-Luc; Ramón, Patricio; Yepes, Hugo


    Long-lasting andesitic eruptions sometimes include strong short-lived explosive events, which can pose significant hazards in populated regions. The origin and dynamics of such violent eruptions remain poorly known and may involve a combination of different factors. Tungurahua volcano, Ecuador, reawakens in 1999 and is an example of such an open-vent system that experienced a strong and deadly andesitic pyroclastic flow-forming event in August 2006. Inspection of the deposits suggested that the event could have been triggered by magma mixing (coexistence of both silicic pumices and andesitic scoria in the tephra), magma-water interaction (presence of xenolithic clasts) or deep andesitic magma reinjection (based on mineral chemistry). Here we investigate these options by performing a high-resolution mass budget analysis of the scoria fall deposit. This is achieved by analysing componentry compositions and their mass distribution pattern in the layer, which allow us to document and integrate exponential and power laws mass decay rates over wide areas. The results yield a total mass for the tephra layer of ˜2×1010 kg. The pumice mass fraction is far too small (paroxysm. Altogether our results support an explosive event fed by a deep gas-rich andesitic reinjection, which would have incorporated a pocket of older differentiated magma and eroded the upper conduit during the sub-plinian event. The high-resolution mass-based approach reveals useful to decipher the origin of the violent 2006 paroxysm and has potential to improve magnitude determinations of ancient eruption by considering componentry mass instead of volume. It is also applicable for monitoring purposes in the context of ongoing crises at andesitic volcanoes worldwide

  17. Origin of co-existing basalts, high-Mg andesites, and adakites in the SW Japan hot subduction system (United States)

    Kimura, J.; Kunikiyo, T.; Osaka, I.; Shimoshioiri, Y.; Katakuse, M.; Kakubuchi, S.; Nagao, T.; Furuyama, K.; Kamei, A.; Nakajima, J.; Stern, R. J.; Gill, J. B.


    In response to subduction of the young, hot Shikoku Basin of the Philippine Sea Plate (PSP) slab, arc magmas have been active throughout the late Cenozoic (<13 Ma) in the SW Japan arc. Extremely variable magma types occurred including oceanic island-type basalt (OIB), shoshonitc to mildly alkalic to sub-alkalic basalts with arc signatures, high-Mg andesites (HMAs), and adakitic andesites and dacites. The OIB-type basalts preceded the arc-type magmas. Therefore, the transition from OIB- to arc-types was related to opening of the Japan of Sea back-arc basin and subsequent re-initiation of PSP subduction. However, both the origin and tectonic implications of this magmatism are debated. Consequently, we analyzed the bulk rock geochemistry of 340 lava samples from seven Quaternary volcanoes and investigated their sources and melting conditions using a geochemical mass balance model, Arc Basalt Simulator version 4 (ABS4). Comparison to basement granitoids precludes adakite genesis in the lower crust. Instead, the ABS4 model suggests that the adakites are mostly slab melts plus minor interaction with mantle wedge peridotite (PERID). Increasing involvement of PERID during slab melt-fluxed mantle melting explains fairly well the geochemical variations of the shoshonites, mildly alkalic to sub-alkalic basalts, and HMAs. We propose that the generation of various magma types in the late Cenozoic SW Japan arc originated simply by "slab melt-fluxed mantle melting" with large variations in melting conditions including depth, temperature, degree of melting, and flux fractions. Such volcanism has been continuous from 13 Ma (Setouchi HMA) to the present, so that the hot subduction system, involving subduction of the Shikoku Basin spreading ridge, should be continuous since 13 Ma beneath the SW Japan arc. Our results further suggest that this atypically hot system generated diverse primary arc magmas from various degrees of flux melting even though the slab source components and sub

  18. Late Cretaceous (ca. 95 Ma) magnesian andesites in the Biluoco area, southern Qiangtang subterrane, central Tibet: Petrogenetic and tectonic implications (United States)

    He, Haiyang; Li, Yalin; Wang, Chengshan; Zhou, Aorigele; Qian, Xinyu; Zhang, Jiawei; Du, Lintao; Bi, Wenjun


    The tectonic evolutionary history of the Lhasa and Qiangtang collision zones remains hotly debated because of the lack of pivotal magmatic records in the southern Qiangtang subterrane, central Tibet. We present zircon U-Pb dating, whole-rock major and trace-element geochemical analyses, and Sr-Nd isotopic data for the newly discovered Biluoco volcanic rocks from the southern Qiangtang subterrane, central Tibet. Zircon U-Pb dating reveals that the Biluoco volcanic rocks were crystallized at ca. 95 Ma. The samples are characterized by low SiO2 (50.26-54.53 wt%), high Cr (109.7-125.92 ppm) and Ni (57.4-71.58 ppm), and a high Mg# value (39-56), which plot in the magnesian andesites field on the rock classification diagram. They display highly fractionated rare earth element patterns with light rare earth element enrichment ([La/Yb]N = 21.04-25.24), high Sr/Y (63.97-78.79) and no negative Eu anomalies (Eu/Eu* = 0.98-1.04). The Biluoco volcanic rocks are depleted in Nb, Ta and Ti and enriched in Ba, Th, U and Pb. Moreover, the eight samples of Biluoco volcanic rocks display constant (87Sr/86Sr)i ratios (0.70514-0.70527), a positive εNd(t) value (2.16-2.68) and younger Nd model ages (0.56-0.62 Ga). These geochemical signatures indicate that the Biluoco volcanic rocks were most likely derived from partial melting of the mantle wedge peridotite metasomatized by melts of subducted slab and sediment in the subducted slab, invoked by asthenospheric upwelling resulting from the slab break-off of the northward subduction of the Bangong-Nujiang oceanic lithosphere. Identification of ca. 95 Ma Biluoco magnesian andesites suggests they were a delayed response of slab break-off of the northward subduction of the Bangong-Nujiang oceanic lithosphere at ca. 100 Ma.

  19. The Origin and Evolution of a Diverse Suite of Late Pleistocene Andesitic to Dacitic Lavas From the Northern Cascade arc at Mt. Baker, Washington. (United States)

    Baggerman, T. D.; Debari, S.


    Mt. Baker, a dominantly andesitic stratovolcano, is located in the northernmost segment of the Cascade magmatic arc. The origin and evolution of andesites in the northern Cascades has thus far not been explored in any systematic way. This study highlights the geochemical diversity of andesites erupted from Mt. Baker and describes processes that are responsible for the generation of this dominant intermediate lava type. Presented here are petrographic observations, mineral chemistry, major oxide concentrations, and the largest trace and REE data set to date for three Late Pleistocene and Holocene lava flows from Mt. Baker: the basaltic andesite of Sulphur Creek (52.5-57.6 wt.% SiO2, 4.7-5.5 wt.% MgO), the andesite of Glacier Creek (59.5-63.3 wt.% SiO2, 4.7-5.0 wt.% MgO), and the andesite and dacite of Boulder Glacier (60.5-64.1 wt.% SiO2, 2.1-3.5 wt.% MgO). The data are used to characterize and asses the relationship between the three flows. The three lava flows are classified as medium K, and to a lesser degree, high K, calc-alkaline basalts through dacites. Major oxide concentrations for Sulphur Creek and Boulder Glacier lavas form curvilinear trends with increasing SiO2. The andesite of Glacier Creek has distinct major oxide chemistry, with elevated concentrations of MgO and CaO and lower concentrations of Na2O and K2O for a given wt.% SiO2 relative to the major oxide trends of the other lavas. Glacier Creek lavas also show enrichment of Ni, Cr, and Sr and depletion in La, Nb, Ta, Zr and Y. REE patterns and slopes are distinct for each flow, but are not correlated with degree of differentiation. The mafic lavas of Sulphur Creek have the highest REE abundances relative to the other lavas, with the lowest La/Yb (~4.5). The Glacier Creek andesites have the lowest REE abundances and the largest La/Yb (~6.7). The Boulder Glacier andesites and dacites have intermediate REE abundances relative to the other lavas with intermediate La/Yb (~6.4). All lavas display

  20. Petrogenesis of the Late Triassic diorites in the Hoh Xil area, northern Tibet: Insights into the origin of the high-Mg# andesitic signature of continental crust (United States)

    Wang, Jun; Gou, Guo-Ning; Wang, Qiang; Zhang, Chunfu; Dan, Wei; Wyman, Derek A.; Zhang, Xiu-Zheng


    An integrated petrologic, geochronologic, major and trace element geochemical, and Sr-Nd-Hf isotopic study of Late Triassic ( 215 Ma) diorites from the Hoh Xil area, northern Tibet, provides new constraints on the genesis of intermediate magmas and insights into the origin of the high-Mg# andesitic signature of continental crust. These dioritic rocks are characterized by high MgO contents (3.3-5.0 wt%) and Mg# values (50-57) comparable to the estimates for the bulk continental crust at the same level of SiO2 contents (61.1-64.5 wt%). They also display continental crust-like trace element distribution patterns and uniformly enriched isotope compositions ([87Sr/86Sr]i = 0.7081 to 0.7094, ɛNd[t] = - 8.0 to - 6.9, and ɛHf[t]zircon = - 10.1 to - 5.0). Combining our results with published data from crystallization experiments, we propose that they were probably produced by fractional crystallization from a primitive andesite parent, rather than a primitive basalt parent. This parental magma may be geochemically similar to the roughly contemporaneous primitive andesites in the adjacent Malanshan area of northern Tibet. Our compilation of modern arc lavas shows that progressive fractional crystallization of primitive andesites is also required to reproduce the Mg# versus SiO2 array for natural arc magmas, in addition to differentiation of mantle-derived primitive basaltic magmas and/or mixing of basaltic with felsic magmas. Therefore, we emphasize that fractional crystallization of primitive andesitic magmas is potentially a frequent occurrence in arc crust and hence may play an important role in producing the high-Mg# signature of intermediate magmas comprising the continental crust.

  1. Origin of Permian andesites from Xi Ujimqin, the Hinggan Mountains: Contributions of lower crust North China Carton (United States)

    Gao, X.


    Andesite magmas at convergent margins are enriched in silica compared to magmas erupting at mid-ocean ridges and intra-plate volcanoes. Determining the cause (s) of silica enrichment is fundamental for models of continental crust formation, arc growth rates and across-arc mass balances (Plank and Langmuir, 1993; Rudnick, 1995; White et al., 2006).The Xi-Ujimqin is located the eastern segment of the Central Asian Orogenic Belt , the CAOB is composed of mainly subduction-accretion complexes, intruded by vast plutons of mainly magmatic arc origin and covered in places by their volcanic derivatives (Sengor et al. 1993; Sengor and Natalin 1996). As the most important site for Phanerozoic crustal growth in the world, the subduction-accretion complexes added ~ 5.3 million km2of material to Asia, half of which may be of juvenile origin (Sengor et al. 1993).The andesitic lavas of Daotenuoer Fms. at Xi-Ujimqin have different trace and Sr-Nd-Pb isotopic characteristic from them, these rocks span a SiO2 range of 56.83 ~ 59.17% and MgO of range of 1.21~2.91%, characterized by obviously LREE/HREE fractionation (Ce/YbCN = 11.6 ~ 16.8), strong LILE enrichment and variable Nb-Ta and Sr depletion. They have more radiogenic Sr and less radiogenic Nd and Pb isotopic composition (87Sr/86Sr(i) = 0.7063 ~ 0.7066, eNd(t) = -10.5 ~ -6.3,TDM = 1.22 ~ 1.51Ga, 206Pb / 204Pb(i) = 17.29 ~ 17.33, D7/4 = 3.7 ~ 6.9, D 8/4 = 94 ~ 104) than the contemporaneous intermediate-felsic volcanic lavas. Zircon U-Pb dating results give an emplacement age of ~253 Ma for the these rocks by LA-ICP-MS, corresponding to the Late Permian. The features of major, trace and Sr-Nd-Pb isotope of These rocks imply its sources are of attributes of lower crust North China Carton (NCC) during Paleozoic subduction and collision related to the closure of the Chinese segment of the Paleo-Asian Ocean between the NCC and south Mongolia Block (Sengor et al., 1993).

  2. Dynamic observations of vesiculation reveal the role of silicate crystals in bubble nucleation and growth in andesitic magmas (United States)

    Pleše, P.; Higgins, M. D.; Mancini, L.; Lanzafame, G.; Brun, F.; Fife, J. L.; Casselman, J.; Baker, D. R.


    Bubble nucleation and growth control the explosivity of volcanic eruptions, and the kinetics of these processes are generally determined from examinations of natural samples and quenched experimental run products. These samples, however, only provide a view of the final state, from which the initial conditions of a time-evolving magmatic system are then inferred. The interpretations that follow are inexact due to the inability of determining the exact conditions of nucleation and the potential detachment of bubbles from their nucleation sites, an uncertainty that can obscure their nucleation location - either homogeneously within the melt or heterogeneously at the interface between crystals and melts. We present results of a series of dynamic, real-time 4D X-ray tomographic microscopy experiments where we observed the development of bubbles in crystal bearing silicate magmas. Experimentally synthesized andesitic glasses with 0.25-0.5 wt% H2O and seed silicate crystals were heated at 1 atm to induce bubble nucleation and track bubble growth and movement. In contrast to previous studies on natural and experimentally produced samples, we found that bubbles readily nucleated on plagioclase and clinopyroxene crystals, that their contact angle changes during growth and that they can grow to sizes many times that of the silicate on whose surface they originated. The rapid heterogeneous nucleation of bubbles at low degrees of supersaturation in the presence of silicate crystals demonstrates that silicates can affect when vesiculation ensues, influencing subsequent permeability development and effusive vs. explosive transition in volcanic eruptions.

  3. Dynamic observations of vesiculation reveal the role of silicate crystals in bubble nucleation and growth in andesitic magmas

    Energy Technology Data Exchange (ETDEWEB)

    Pleše, P.; Higgins, M. D.; Mancini, L.; Lanzafame, G.; Brun, F.; Fife, J. L.; Casselman, J.; Baker, D. R.


    Bubble nucleation and growth control the explosivity of volcanic eruptions, and the kinetics of these processes are generally determined from examinations of natural samples and quenched experimental run products. These samples, however, only provide a view of the final state, from which the initial conditions of a time-evolving magmatic system are then inferred. The interpretations that follow are inexact due to the inability of determining the exact conditions of nucleation and the potential detachment of bubbles from their nucleation sites, an uncertainty that can obscure their nucleation location – either homogeneously within the melt or heterogeneously at the interface between crystals and melts. We present results of a series of dynamic, real-time 4D X-ray tomographic microscopy experiments where we observed the development of bubbles in crystal bearing silicate magmas. Experimentally synthesized andesitic glasses with 0.25–0.5 wt% H2O and seed silicate crystals were heated at 1 atm to induce bubble nucleation and track bubble growth and movement. In contrast to previous studies on natural and experimentally produced samples, we found that bubbles readily nucleated on plagioclase and clinopyroxene crystals, that their contact angle changes during growth and that they can grow to sizes many times that of the silicate on whose surface they originated. The rapid heterogeneous nucleation of bubbles at low degrees of supersaturation in the presence of silicate crystals demonstrates that silicates can affect when vesiculation ensues, influencing subsequent permeability development and effusive vs. explosive transition in volcanic eruptions.

  4. Microtextural and mineral chemical analyses of andesite-dacite from Barren and Narcondam islands: Evidences for magma mixing and petrological implications (United States)

    Ray, Dwijesh; Rajan, S.; Ravindra, Rasik; Jana, Ashim


    Andesite and dacite from Barren and Narcondam volcanic islands of Andaman subduction zone are composed of plagioclase, orthopyroxene, clinopyroxene, olivine, titanomagnetite, magnesio-hornblende and rare quartz grains. In this study, we use the results of mineral chemical analyses of the calc-alkaline rock suite of rocks as proxies for magma mixing and mingling processes. Plagioclase, the most dominant mineral, shows zoning which includes oscillatory, patchy, multiple and repetitive zonation and `fritted' or `sieve' textures. Zoning patterns in plagioclase phenocrysts and abrupt fluctuations in An content record different melt conditions in a dynamic magma chamber. `Fritted' zones (An55) are frequently overgrown by thin calcic (An72) plagioclase rims over well-developed dissolution surfaces. These features have probably resulted from mixing of a more silicic magma with the host andesite. Olivine and orthopyroxene with reaction and overgrowth rims (corona) suggest magma mixing processes. We conclude that hybrid magma formed from the mixing of mafic and felsic magma by two-stage processes - initial intrusion of hotter mafic melt (andesitic) followed by cooler acidic melt at later stage.

  5. Monogenetic Arc Volcanism in the Central Andes: The "Hidden" Mafic Component in the Land of Andesite and Ignimbrite (United States)

    van Alderwerelt, B. M.; Ukstins Peate, I.; Ramos, F. C.


    Faulting in the upper crust of the Central Andes has provided passage for small volumes of mafic magma to reach the surface, providing a window into petrogenetic processes in the region's deep crust and upper mantle. Mafic lavas are rare in the Central Andean region dominated by intermediate-composition arc volcanism and massive sheets of silicic ignimbrite, and provide key data on magmatic origin, evolution, and transport. This work characterizes fault-controlled, within-arc monogenetic eruptive centers representative of the most mafic volcanism in the Altiplano-Puna region of the Andes since (at least) the Mesozoic. Olivine-phyric basaltic andesite (54 wt% SiO2, 7.3 wt% MgO) at Cerro Overo maar and associated dome, La Albóndiga Grande, and an olivine-clinopyroxene flow (53 wt% SiO2, 6.7 wt% MgO) from Cordón de Puntas Negras have been erupted at the intersection of regional structural features and the modern volcanic arc. Bulk magma chemistry, radiogenic isotopes, and microanalyses of mineral and melt inclusion composition provide insight on the composition(s) of mafic magmas being delivered to the lowermost crust and the deep crustal processes which shape central Andean magma. Bulk major and trace elements follow regional arc differentiation trends and are clearly modified by crustal magmatic processes. In contrast, microanalyses reveal a much richer history with olivine-hosted melt inclusions recording multiple distinct magmas, including potential primary melts. Single crystal olivine 87Sr/86Sr from Cerro Overo (0.7041-0.7071) define a broader range than whole rock (0.7062-0.7065), indicating preservation of juvenile melt in olivine-hosted inclusions lost at the whole rock scale. Mineral chemistry (via EMPA) P-T calculations define a petrogenetic history for these endmember lavas. Field mapping, bulk chemistry, and microanalyses outline the generation, storage, transportation, and eventual eruption of the "hidden" mafic component of the Andean arc.

  6. Dynamics of explosive paroxysms at open andesitic systems: high-resolution mass distribution analyses of 2006 tephra from Tungurahua volcano (Ecuador) (United States)

    Le Pennec, J.; Eychenne, J.; Ramon, P.; Yepes, H.


    Many andesitic volcanoes at subduction plate margins can experience in the course of their evolution periods of sub-continuous eruption during years, decades, or centuries. Such long-lived periods may embrace more or less intense outgassing events, extrusion of viscous lava flows and domes (e.g. Colima in Mexico, Merapi in Indonesia, Arenal in Costa Rica), and explosive activity of uneven intensity (e.g. Semeru in Indonesia, Sakurajima in Japan, Sangay in Ecuador). In addition, strong explosive events of short duration may occur, with potential generation of pyroclastic flows on the flanks and beyond, which can pose significant hazards in populated regions. The origin and dynamics of such violent eruptions remain poorly known and may involve a combination of different factors. Tungurahua volcano, Ecuador, reawaken in 1999 and is an example of such open-system behaviour that experienced a strong and deadly andesitic pyroclastic flow-forming event in August 2006. Inspection of the deposits suggested that the event could have been triggered by magma mixing (silicic pumices in the tephra), magma-water interaction (presence of xenolithic clasts) or deep andesitic magma reinjection (based on mineral chemistry). Here we investigate these options by performing a high-resolution mass budget analysis of the scoria fall deposit. This is achieved by analysing componentry compositions and their mass distribution pattern in the layer, which allow us to document and integrate exponential and power laws mass decay rates over wide areas. The results yield a total mass for the tephra layer of ~2 x 1010kg. The pumice mass fraction is far too small (paroxysm. Altogether our results support an explosive event fed by a deep gas-rich andesitic reinjection, which would have incorporated a pocket of older differentiated magma and eroded the upper conduit during the sub-plinian event. The high-resolution mass-based approach reveals useful to decipher the origin of the violent 2006 paroxysm

  7. Emplacement controls for the basaltic-andesitic radial dikes of Summer Coon volcano and implications for flank vents at stratovolcanoes (United States)

    Harp, A. G.; Valentine, G. A.


    Mafic flank eruptions are common events that pose a serious hazard to the communities and infrastructure often encroaching on the slopes of stratovolcanoes. Flank vent locations are dictated by the propagation path of their feeder dikes. The dikes are commonly thought to propagate either laterally from the central conduit or vertically from a deeper source. However, these interpretations are often based on indirect measurements, such as surface deformation and seismicity at active systems, and several studies at eroded volcanoes indicate the propagation paths may be more complex. We investigated the Oligocene age Summer Coon volcano (Colorado, USA), where erosion has exposed over 700 basaltic-andesitic radial dikes, to constrain the propagation directions, geometries, and spatial distributions of mafic dikes within a stratovolcano. The mean fabric angle of aligned plagioclase crystals was measured in oriented samples from the margins of 77 dikes. Of the 41 dikes with statistically significant flow fabrics, 85% had fabric angles that were inclined—plunging both inward and outward relative to the center of the volcano. After comparing fabric angles to those reported in other studies, we infer that, while most of the dikes with outward-plunging fabrics descended toward the flanks from a source within the edifice and near its axis, dikes with inward-plunging fabrics ascended through the edifice and toward the flanks from a deeper source. A possible control for the inclination of ascending dikes was the ratio between magma overpressure and the normal stress in the host rock. While higher ratios led to high-angle propagation, lower ratios resulted in inclined emplacement. Dikes crop out in higher frequencies within a zone surrounding the volcano axis at 2500 m radial distance from the center and may be the result of ascending dikes, emplaced at similar propagation angles, intersecting the current level of exposure at common distances from the volcano axis. The process

  8. Diffusive exchange of trace elements between basaltic-andesite and dacitic melt: Insights into potential metal fractionation during magma mixing (United States)

    Fiege, A.; Ruprecht, P.; Simon, A. C.; Holtz, F.


    Mafic magma recharge is a common process that triggers physical and chemical mixing in magmatic systems and drives their evolution, resulting in, e.g., hybridization and volcanic eruptions. Once magma-magma contact is initiated, rapid heat-flux commonly leads to the formation of a cooling-induced crystal mush on the mafic side of the interface. Here, on a local scale (µm to cm), at the magma-magma interface, melt-melt diffusive exchange is required to approach equilibrium. Significant chemical potential gradients drive a complex, multi-element mass flux between the two systems (Liang, 2010). This diffusive-equilibration often controls crystal dissolution rates within the boundary layers and, thus, the formation of interconnected melt or fluid networks. Such networks provide important pathways for the transport of volatiles and trace metals from the mafic recharge magma to the felsic host magma, where the latter may feed volcanic activities and ore deposits. While major element diffusion in silicate melts is mostly well understood, even in complex systems, the available data for many trace element metals are limited (Liang, 2010; Zhang et al., 2010). Differences in diffusivity in a dynamic, mixing environment can cause trace element fractionation, in particular during crystallization and volatile exsolution and separation. This may affect trace element signatures in phenocrysts and magmatic volatile phases that can form near a magma-magma boundary. As a result, the chemistry of volcanic gases and magmatic-hydrothermal ore deposits may be partially controlled by such mixing phenomena. We performed melt-melt diffusion-couple experiments at 150 MPa, 1100°C, FMQ, FMQ+1 and FMQ+3 (FMQ: fayalite-magnetite-quartz oxygen fugacity buffer). Hydrated, sulfur-bearing cylinders of dacite and basaltic andesite were equilibrated for up to 20 h. Major and trace element gradients were measured by using laser-ablation ICP-MS and electron microprobe analyses. The results we will

  9. Plagioclase Textures and Zoning Patterns in the Miocene Dowdy Ranch Andesite, Central California Coast Ranges: Implications for Open and Closed System Behavior in Magmatic Systems (United States)

    Bavishi, D. K.; Metzger, E. P.; Miller, J. S.


    The Miocene Dowdy Range Andesite (DRA) of the Central California Coast Ranges is part of a northwestward-younging sequence of volcanic rocks that were apparently formed by northward movement of the Mendocino triple junction, formation of a slab window, and infilling by asthenospheric mantle. The highly porphyritic andesite contains plagioclase phenocrysts with a wide array of disequilibrium textures and zoning patterns, providing an opportunity to reconstruct andesite-forming processes in a tectonic environment that evolved from subduction to transform motion. The DRA encloses metasedimentary, granulitic, and gabbroic xenoliths (described elsewhere) and displays arc-like trace element chemistry. It features glomeroporphyritic, intersertal and hyalopilitic textures with plagioclase as the dominant phase both as phenocrysts and in the groundmass. Other groundmass minerals include orthopyroxene, clinopyroxene, and ilmenite. Plagioclase exhibits normal, reverse, oscillatory and patchy zoning patterns and sieve and sponge textures, with several populations of plagioclase crystals observed on the scale of a single thin section. The presence of abundant quartz xenocrysts rimmed by augite and absence of mafic enclaves suggest that incorporation of crustal material played an important role in forming the andesite. Preliminary examination of back-scattered electron images and electron microprobe analysis of zoned plagioclase shows both concordant and discordant relationships between An and FeO, suggesting that the andesite was formed by a combination of open and closed system magmatic processes. Plagioclase cores vary from An 45-65%. Clear rims surrounding spongy zones are common and show abrupt and significant (~10-50% An and 5-20% FeO) increases in both An and FeO, as expected for magma recharge by more mafic magma. Clear rim compositions are consistent from sample to sample, suggesting that the phenocrysts experienced a common history during later stages of

  10. Experimental hydrothermal alteration of andesite at 325 ˚C, 300 bar: Comparison with the hydrothermal fluids in the Hatoma Knoll, southern Okinawa Trough (United States)

    Saitoh, Masafumi; Shibuya, Takazo; Nozaki, Tatsuo; Torimoto, Junji; Ueda, Hisahiro; Sato, Tomoki; Suzuki, Katsuhiko


    Formation processes and types of hydrothermal sulfide deposits are closely related to chemical compositions of subseafloor hydrothermal fluids. Subseafloor hydrothermal alteration of intermediate to felsic rocks is a major process that controls the fluid compositions in the arc/back-arc hydrothermal systems, although the chemical reaction process during water-rock interaction has not been examined in detail. We experimentally reacted a NaCl solution under high-pressure and -temperature conditions with fresh andesite collected from the Hatoma Knoll, southern Okinawa Trough. The concentrations of selected elements (e.g., K, Ca, and Si) in the fluid obtained by the experiment are inconsistent with those of the hydrothermal fluids in the Hatoma Knoll. The present results suggest that the inputs of magmatic volatiles derived from andesitic magma to the hydrothermal fluids may not be significant whereas hydrothermal reactions with felsic rocks (e.g., dacite and rhyolite) and/or sediments may contribute substantially to the fluid compositions in the Hatoma Knoll.

  11. Experimental constraints on the P/T conditions of high silica andesite storage preceding the 2006 eruption of Augustine Volcano, Alaska (United States)

    Henton, S.; Larsen, J. F.; Traxler, N.


    We present new experimental results to constrain the P/T storage conditions of the high silica andesite (HSA) prior to the 2006 eruption of Augustine Volcano, Alaska. Augustine Volcano forms a small island located in Alaska’s Cook Inlet, approximately 180 miles southwest of Anchorage. The 2006 eruption began January 11, 2006, and evolved from an initial phase of explosive activity, through continuous and effusive phases, ending approximately mid-March 2006. Lithologies erupted indicate pervasive hybridization between high- (HSA; 62.2-63.3 wt. % SiO2) and low-silica andesite (LSA; 56.6-58.7 wt% SiO2). This study focuses on experiments using the HSA as starting material to constrain magma storage conditions, based on amphibole stability. Experiments were conducted between 100-160 MPa and 800-900 °C, utilzing H2O saturated conditions and fO2 of Re-ReO. Both lightly crushed and sintered HSA were used as starting powders, seeded respectively with 5 wt. % amphibole and a mix of 5 wt. % amphibole and 20 wt. % plagioclase. Experiments with sintered starting material tended toward a bimodal distribution of experimental phenocrysts and microlites, whilst experiments of the lightly crushed material are more phenocryst rich. Preliminary results indicate that amphibole is stable at conditions of 120-140 MPa and 820-840 °C. These pressures correspond with depths of approximately 4.6-5.4 km, which are consistent with prior magma storage models for Augustine 1986 and 2006 magmas, as well as amphiboles found in other arc andesites (e.g., Redoubt and Soufriere Hills volcanoes). Experimental amphiboles are magnesio-hornblendes, which is in keeping with the natural HSA amphiboles. Experimental and natural hornblendes are similar in composition, with the main difference being a small FeO enrichment (2-3 wt%) and MgO depletion (1-2wt%) in the experimental grains. Further work will provide a more complete assessment of amphibole stability and composition, and will be applied towards

  12. Manganese mineralization in andesites of Brestovačka Banja, Serbia: evidence of sea-floor exhalations in the Timok Magmatic Complex (United States)

    Pačevski, Aleksandar; Cvetković, Vladica; Šarić, Kristina; Banješević, Miodrag; Hoefer, Heidi Eva; Kremenović, Aleksandar


    Andesites near Brestovačka Banja belong to the Late Cretaceous Timok Magmatic Complex (TMC), which hosts the world-class Bor metallogenic zone including numerous porphyry-copper and epithermal deposits. Two main volcanic phases are recognized in the TMC. The newly discovered Mn mineralization reported here is associated with the second volcanic phase of Turonian-Campanian age. Manganese mineralization containing 58 % MnO on average, occurs as black veins, lumps and nests filling cracks and cavities within an autoclastic andesite, which was deposited in a subaqueous environment. This rock also contains minor Fe mineralization, which is contemporaneous with the manganese mineralization. Manganese mineralization predominantly consists of Mn-Ca silicates (macfallite, pumpellyite-Mn, orientite, bustamite) and Mn oxides (pyrolusite, manganite). Micrometer-scale mineral intergrowths and locally preserved botryoidal and colloform textures are characteristic features of this uncommon mineral assemblage. The features could indicate that the mineralization was formed by deposition from a primary colloidal assemblage and is of sub-marine hydrothermal origin. Orientite is the only Mn mineral with grain size reaching several tenths of micrometers and showing prismatic crystal habit. Scarce to rare associated minerals are hollandite, crednerite, an unknown REE mineral, powellite, pyrite, barite and galena, in decreasing abundance. Trace element analyses of the Mn mineralization show different element contents and REE patterns compared to those of the volcanic host-rock. Manganese mineralization shows relatively high contents of Cu - 1784 ppm, Mo - 20 ppm and As - 268 ppm. These elements are commonly enriched in the Cu deposits of the Bor zone and their relatively high contents in the studied Mn crusts indicate sea-floor hydrothermal vents as a source of the metals.

  13. Chemical compositions and Sr, Nd isotope ratios of gabbroic xenoliths in calc-alkali andesites of Naeba and Torikabuto volcanoes, North Fossa Magna, central Japan

    International Nuclear Information System (INIS)

    Shimazu, Mitsuo; Kawano, Yoshinobu; Kaji, Kiyoshi; Igarashi, Satoshi.


    Gabbroic, doleritic and basaltic xenoliths found in calc-alkali andesites of Naeba and Torikabuto volcanoes are geochemically divided into three groups. Gabbro A of the group 1 from Naeba is rich in MgO and Ni, poor in alkalis, and shows depleted REE pattern resembling those of Ichinomegata (Sp. No.2232) and Hakone (HKG1, HKG2) volcanoes. On the basis the REE pattern and high Al IV contents in clinopyroxenes, gabbro A is interpreted to have been cumulate from a primary magma generated by partial melting of upper mantle. From REE pattern, gabbros of the group 2 from Ichinomegata (Sp. No.2218) may have derived from low alkali tholeiite magma which have been formed by removal of material such as the group 1 gabbro at shallow depth. Doleritic and basaltic xenoliths of the group 3 from Naeba, gabbroic xenoliths from Torikabuto and Umikawa are poorer in MgO and richer in alkalis than those of the group 1 and show enriched pattern in REE resembling that of high alkali tholeiite and contain clinopyroxenes having low Al IV . Therefore, these rocks are considered to be differentiates of high alkali tholeiite magma at shallow depth. On εNd- 87 Sr/ 86 Sr diagram, isotope data of gabbro A of the group 1 plot near those of andesites from Asama and Myoko volcanoes of the North Fossa Magna. It is interpreted that these rocks have derived from the same mantle source as the Asama and Myoko volcanoes which are richer in incompatible elements than those of MORB. (author)

  14. Mesozoic high-Mg andesites from the Daohugou area, Inner Mongolia: Upper-crustal fractional crystallization of parental melt derived from metasomatized lithospheric mantle wedge (United States)

    Meng, Fanxue; Gao, Shan; Song, Zhaojun; Niu, Yaoling; Li, Xuping


    Mineral chemistry, major- and trace-element data, zircon U-Pb ages, and Sr-Nd isotopic data are presented for a suite of volcanic rocks from the Daohugou area, Ningcheng City, Inner Mongolia, on the northern margin of the North China Craton. Samples from the suite are of basaltic andesite to rhyolite in composition, with the rocks containing low εNd (t) values, moderate (87Sr/86Sr) i ratios, enrichment in LREEs relative to LILEs, and depletion in HFSEs (e.g., Nb, Ta, Ti), indicating formation through protracted fractional crystallization of a common parental magma. The unusually low CaO contents and CaO/FeO ratios of olivine phenocrysts in the HMAs suggest that the parental melt was subduction-related. The results of Rhyolite-MELTS modelling indicates that HMAs may form through upper-crustal fractional crystallization from arc basalts. Therefore, the Daohugou HMAs were most likely formed through fractional crystallization of a parental melt derived from metasomatized lithospheric mantle at crustal depths. The addition of "water" to the cratonic keel may have played a key role in the destruction of the North China Craton.

  15. The effects of thermomechanical heterogeneities in island arc crust on time-dependent preeruptive stresses and the failure of an andesitic reservoir (United States)

    Gottsmann, J.; Odbert, H.


    Using ground deformation data from Soufrière Hills volcano (SHV), we present results from numerical modeling of the temperature- and time-dependent stress evolution in a mechanically heterogeneous crust prior to reservoir failure and renewed eruptive activity. The best fit models do not allow us to discriminate between a magmatic plumbing system consisting of either a single vertically elongated reservoir or a series of stacked reservoirs. A prolate reservoir geometry with volumes between 50 and 100 km3, reservoir pressure changes between 4 and 7 MPa, and reservoir volume changes between 0.03 and 0.04 km3 with magma compressibility between 4 × 10-11 and 1 × 10-9 Pa-1 provide plausible thermomechanical model parameters to explain the deformation time series; around an order of magnitude less overpressure than is generally inferred from homogeneous, elastic crustal models. Reservoir failure is predicted to occur at the crest of the reservoir except for reservoirs with highly compressible magma (≳4×10-9 Pa) for which subhorizontal sill formation is predicted upon reservoir failure. Introducing a deep-crustal hot zone modulates the partitioning of strains into the hotter underlying crust and results in a further reduction in overpressure estimates to values of around 1-2 MPa upon reservoir failure. Deduced volume fluxes are consistent with constraints from thermal modeling of active subvolcanic systems and imply dynamic failure of a compressible magma mush column feeding eruptions at SHV. Our interpretation of the results is that the combined thermomechanical effects of a deep-crustal hot zone and hot encasing rocks around a midcrustal andesitic reservoir fundamentally alter the time-dependent subsurface stress and strain partitioning upon reservoir priming. These effects substantially influence surface strains recorded by volcano geodetic monitoring.

  16. Calbuco Volcano and minor eruptive centers distributed along the Liquiñe-Ofqui Fault Zone, Chile (41° 42° S): contrasting origin of andesitic and basaltic magma in the Southern Volcanic Zone of the Andes (United States)

    López-Escobar, L.; Parada, M. A.; Hickey-Vargas, R.; Frey, F. A.; Kempton, P. D.; Moreno, H.


    Calbuco volcano is a Late Pleistocene-Holocene composite stratovolcano located at 41°20' S, in the southern region of the Southern Volcanic Zone of the Andes (SSVZ; 37° 46° S). In contrast to basalt and basaltic andesite, which are the dominant lava types on the volcanic front from 37° to 42° S, Calbuco lavas are porphyritic andesites which contain a wide variety of crustal xenoliths. They have SiO2 contents in the 55 60% range, and have comparatively low K2O, Rb, Ba, Th and LREF abundances relative to other SSVZ centers. Incompatible element abundance ratios are similar to those of most SSVZ volcanics, but 87Sr/86Sr and 143Nd/144Nd are respectively higher and lower than those of adjacent volcanic centers. Basalts from nearby Osorno stratovolcano, 25 km to the northeast, are similar to other basaltic SSVZ volcanoes. However, basalts from several minor eruptive centers (MEC), located east of Calbuco and Osorno volcano along the Liquiñe-Ofqui fault zone (LOFZ), are enriched in Ba, Nb, Th and LREE, and have higher La/Yb and lower Ba/La, K/La and Rb/La. 87Sr/86Sr and 143Nd/144Nd in MEC basalts are respectively lower and higher than those of Osorno and Calbuco lavas. We suggest that MEC basalts were produced by lower extents of mantle melting than basalts from Osorno and other SSVZ stratovolcanoes, probably as a result of lower water content in the source of MEC basalts. Calbuco andesites formed from basaltic parents similar to Osorno basalts, by moderate pressure crystallization of a hornblende-bearing assemblage accompanied by crustal assimilation. Hornblende stability in the Calbuco andesites was promoted by the assimilation of hydrous metasedimentary crustal rocks, which are also an appropriate endmember for isotopic trends, together with magma storage at mid-crustal depths. The unique characteristics of Calbuco volcano, i.e. the stability of hornblende at andesitic SiO2 contents, low 143Nd/144Nd and high 87Sr/86Sr, and abundant crustal xenoliths, provide

  17. Birth of a bubble: sub-second 4D in-situ synchrotron tomography reveals role of silicate crystals in degassing of andesitic magmas (United States)

    Pleše, Pia; Brun, Francesco; Casselman, Jake; Fife, Julie L.; Higgins, Michael D.; Lanzafame, Gabriele N.; Mancini, Lucia; Baker, Don R.


    Bubbles in silicate magmas are one of the main controls on eruption explosivity. Previous investigations of bubble dynamics in magmatic systems were generally conducted on natural post-eruption samples or quenched experimental charges; both types of studies provide only a view of the final state of a dynamic system, with little information on how that state was achieved. One of the most important and most elusive parameters, the exact location of bubble nucleation sites, cannot yet be directly observed in natural volcanic systems. We present a 4D X-ray microscopy study of bubble behaviour using experiments that simulate natural conditions as close as is currently possible with the aim of revealing the initial nucleation dynamics and growth of water bubbles in a magma. 4D in-situ synchrotron X-ray tomography experiments were conducted on hydrous, crystal-bearing andesitic run products produced at 1 GPa to observe bubble nucleation and track bubble growth and movement. The high-pressure run products were heated at 1 atm to above the solidus and observed in 3D at a resolution of 3 µm3 every 0.5 s for a total of 50 s. We discovered that bubbles nucleated heterogeneously on plagioclase/melt interfaces and on clinopyroxene crystals. Heterogeneous nucleation on oxides and homogeneous nucleation within the melt occurred significantly after bubble nucleation on silicates. The 3D bubble-crystal contact angle was not constant but changed with time; initially the contact angle was very large and decreased with bubble growth. Bubbles grew much larger than their associated crystal, producing textures similar to some natural volcanic samples. After each experiment the bubbly samples were scanned at sub-micron spatial resolutions to confirm that bubbles nucleated at the silicate crystal/melt interface. Our results show that the presence of silicate phases in magmas must be taken into account when discussing vesiculation in natural systems. We also demonstrate the power and

  18. Paleoproterozoic arc basalt-boninite-high magnesian andesite-Nb enriched basalt association from the Malangtoli volcanic suite, Singhbhum Craton, eastern India: Geochemical record for subduction initiation to arc maturation continuum (United States)

    Rajanikanta Singh, M.; Manikyamba, C.; Ganguly, Sohini; Ray, Jyotisankar; Santosh, M.; Dhanakumar Singh, Th.; Chandan Kumar, B.


    The Singhbhum Craton of eastern India preserves distinct signatures of ultramafic-mafic-intermediate-felsic magmatism of diverse geodynamic affiliations spanning from Paleo-Mesoarchean to Proterozoic. Here we investigate the 2.25 Ga Malangtoli volcanic rocks that are predominantly clinopyroxene- and plagioclase-phyric, calc-alkaline in nature, display basalt-basaltic andesite compositions, and preserve geochemical signatures of subduction zone magmatism. Major, trace and rare earth element characteristics classify the Malangtoli volcanic rocks as arc basalts, boninites, high magnesian andesites (HMA) and Nb enriched basalts (NEB). The typical LILE enriched-HFSE depleted geochemical attributes of the arc basalts corroborate a subduction-related origin. The boninitic rocks have high Mg# (0.8), MgO (>25 wt.%), Ni and Cr contents, high Al2O3/TiO2 (>20), Zr/Hf and (La/Sm)N (>1) ratios with low (Gd/Yb)N (54 wt.%), MgO (>6 wt.%), Mg# (0.47) with elevated Cr, Co, Ni and Th contents, depleted (Nb/Th)N, (Nb/La)N, high (Th/La)N and La/Yb (Y with low Sr/Y. The NEBs have higher Nb contents (6.3-24 ppm), lower magnitude of negative Nb anomalies with high (Nb/Th)pm = 0.28-0.59 and (Nb/La)pm = 0.40-0.69 and Nb/U = 2.8-34.4 compared to normal arc basalts [Nb = generation of NEB. Thus, the arc basalt-boninite-HMA-NEB association from Malangtoli volcanic suite in Singhbhum Craton preserves the signature of a complete spectrum of Paleoproterozoic active convergent margin processes spanning from subduction initiation to arc maturation.

  19. Experimental determination of dissolved CO2 content in nominally anhydrous andesitic melts at graphite/diamond saturation - Remobilization of deeply subducted reduced carbon via partial melts of MORB-like eclogite (United States)

    Eguchi, J.; Dasgupta, R.


    Experimental phase relations of carbonated lithologies [1] and geochemistry of deep diamonds [2] suggest that deep recycling of carbon has likely been efficient for a significant portion of Earth's history. Both carbonates and organic carbon subduct into the mantle, but with gradual decrease of fO2 with depth [3] most carbon in deep mantle rocks including eclogite could be diamond/graphite [4]. Previous studies investigated the transfer of CO2 from subducted eclogite to the ambient mantle by partial melting in the presence of carbonates, i.e., by generation of carbonate-rich melts [5]. However, the transfer of carbon from subducted eclogite to the mantle can also happen, perhaps more commonly, by extraction of silicate partial melt in the presence of reduced carbon; yet, CO2 solubility in eclogite-derived andesitic melt at graphite/diamond saturation remains unconstrained. CO2content of eclogite melts is also critical as geochemistry of many ocean island basalts suggest the presence of C and eclogite in their source regions [6]. In the present study we determine CO2 concentration in a model andesitic melt [7] at graphite/diamond saturation at conditions relevant for partial melting of eclogite in the convecting upper mantle. Piston cylinder and multi anvil experiments were conducted at 1-6 GPa and 1375-1550 °C using Pt/Gr double capsules. Oxygen fugacity was monitored with Pt-Fe sensors in the starting mix. Completed experiments at 1-3 GPa show that CO2 concentration increases with increasing P, T, and fO2 up to ~0.3 wt%. Results were used to develop empirical and thermodynamic models to predict CO2 concentration in partial melts of graphite saturated eclogite. This allowed us to quantify the extent to which CO2 can mobilize from eclogitic heterogeneities at graphite/diamond saturated conditions. With estimates of eclogite contribution to erupted basaltic lavas, the models developed here allow us to put constraints on the flux of CO2 to mantle source regions

  20. Geochemistry, age and strontium isotope composition of late tertiary and quaternary basalts and andesites in western Nevada and their relation to geothermal potential. Final report, October 1, 1982-December 31, 1983

    Energy Technology Data Exchange (ETDEWEB)

    Fultz, L.A.; Bell, E.J.; Trexler, D.T.


    This research was undertaken to characterize the late Cenozoic volcanic rocks associated with active geothermal systems in west-central Nevada. Petrographic and microprobe, geochemical and isotopic analysis and age dating techniques were used to characterize these young volcanic rocks. These data were combined with the limited data previously reported in the literature on these same volcanic areas to interpret their petrogenesis. The overall characterization resulted from integrating the petrogenesis with a structural-tectonic model of the region. Potassium-argon isotopic ages ranging up to 14 million years were determined for eight localities within the Reno 1 x 2/sup 0/ study region. These ages are consistent with the morphology of the volcanic landforms, the active geothermal systems associated with them, and with other isotopic ages reported in the literature for these and similar rocks within the study region. Petrographic analysis of hand specimens and thin-sections indicated mineralogic assemblages of the respective rock types and specific mineral textures and phenocryst compositions and characteristics. These identifications were further substantiated by microprobe analysis of selected phenocrysts and groundmass phases. Classification of the respective rock types was also based on chemical composition and normative calculations using the program PETCAL. Basaltic andesites are identified and described for Steamboat Hills, Table Mountain, Silver Springs, Churchill Butte, Cleaver Peak, Desert Peak and Carson City sites.

  1. Changes of the properties of the hyperstene-augitic andesite from the Ruskov Area

    Directory of Open Access Journals (Sweden)

    Sekula Félix


    Full Text Available This paper deals with the changes of the structure and physico-chemical properties after their remelting at the temperatures over 1500°C. The following properties were analyzed: chemical composition and microscopic changes in the structure of mineral.

  2. Sulfur metabolizing microbes dominate microbial communities in Andesite-hosted shallow-sea hydrothermal systems. (United States)

    Zhang, Yao; Zhao, Zihao; Chen, Chen-Tung Arthur; Tang, Kai; Su, Jianqiang; Jiao, Nianzhi


    To determine microbial community composition, community spatial structure and possible key microbial processes in the shallow-sea hydrothermal vent systems off NE Taiwan's coast, we examined the bacterial and archaeal communities of four samples collected from the water column extending over a redoxocline gradient of a yellow and four from a white hydrothermal vent. Ribosomal tag pyrosequencing based on DNA and RNA showed statistically significant differences between the bacterial and archaeal communities of the different hydrothermal plumes. The bacterial and archaeal communities from the white hydrothermal plume were dominated by sulfur-reducing Nautilia and Thermococcus, whereas the yellow hydrothermal plume and the surface water were dominated by sulfide-oxidizing Thiomicrospira and Euryarchaeota Marine Group II, respectively. Canonical correspondence analyses indicate that methane (CH(4)) concentration was the only statistically significant variable that explains all community cluster patterns. However, the results of pyrosequencing showed an essential absence of methanogens and methanotrophs at the two vent fields, suggesting that CH(4) was less tied to microbial processes in this shallow-sea hydrothermal system. We speculated that mixing between hydrothermal fluids and the sea or meteoric water leads to distinctly different CH(4) concentrations and redox niches between the yellow and white vents, consequently influencing the distribution patterns of the free-living Bacteria and Archaea. We concluded that sulfur-reducing and sulfide-oxidizing chemolithoautotrophs accounted for most of the primary biomass synthesis and that microbial sulfur metabolism fueled microbial energy flow and element cycling in the shallow hydrothermal systems off the coast of NE Taiwan.

  3. Sulfur metabolizing microbes dominate microbial communities in Andesite-hosted shallow-sea hydrothermal systems.

    Directory of Open Access Journals (Sweden)

    Yao Zhang

    Full Text Available To determine microbial community composition, community spatial structure and possible key microbial processes in the shallow-sea hydrothermal vent systems off NE Taiwan's coast, we examined the bacterial and archaeal communities of four samples collected from the water column extending over a redoxocline gradient of a yellow and four from a white hydrothermal vent. Ribosomal tag pyrosequencing based on DNA and RNA showed statistically significant differences between the bacterial and archaeal communities of the different hydrothermal plumes. The bacterial and archaeal communities from the white hydrothermal plume were dominated by sulfur-reducing Nautilia and Thermococcus, whereas the yellow hydrothermal plume and the surface water were dominated by sulfide-oxidizing Thiomicrospira and Euryarchaeota Marine Group II, respectively. Canonical correspondence analyses indicate that methane (CH(4 concentration was the only statistically significant variable that explains all community cluster patterns. However, the results of pyrosequencing showed an essential absence of methanogens and methanotrophs at the two vent fields, suggesting that CH(4 was less tied to microbial processes in this shallow-sea hydrothermal system. We speculated that mixing between hydrothermal fluids and the sea or meteoric water leads to distinctly different CH(4 concentrations and redox niches between the yellow and white vents, consequently influencing the distribution patterns of the free-living Bacteria and Archaea. We concluded that sulfur-reducing and sulfide-oxidizing chemolithoautotrophs accounted for most of the primary biomass synthesis and that microbial sulfur metabolism fueled microbial energy flow and element cycling in the shallow hydrothermal systems off the coast of NE Taiwan.

  4. Groundwater circulations within a tropical humid andesitic volcanic watershed using the temperature as a tracer (United States)

    Selles, Adrien; Violette, Sophie; Hendrayana, Heru


    Groundwater flow within volcano-detritic environment, is of prime importance to many human needs and activities, from the supply of clean drinking water to the extraction of hydrocarbons or geothermal energy. However, the heterogeneity of the geological formations makes difficult to quantify the groundwater spatial distribution. Moreover, its temporal variation in tropical humid regions is sometimes poorly known. For instance, the surronding of the Merapi volcano, in Central Java, Indonesia, is an area of high but seasonal rainfall, and extensive crop irrigation. It has a large population and a need to increase food and potable water supplies depending upon exploiting groundwater ressources. The stress on these resources increases with the intensification of the demography, the agricultural practices and the industrial exploitations. In order to implement a sustainable management of the water resources, the description of the groundwater circulations and the quantification of the resources is needed. A mutidisciplinary approach has been performed at the watershed scale, including geology, hydrogeochemistry and long term hydrogeological monitoring. The data synthesis and constisency have been confirm with a numerical model of physical processes. Based on a geological and geomorphological study, the hydrogeological watershed on the Eastern flank of the Merapi volcano is composed by an alternation of aquitards (mainly ashes, tuffs and clay) and aquifers (sand, gravel and boulders). The deep aquifers are agenced in conduit following the burried channel of the paleo-rivers. The eastern flank of Merapi provides excellent example of a volcanic-sedimentary environment. From 20 cold springs of 3 spring zones, sampled on 2 hydrological years (2011 to 2013), the study of the transfer into the saturated zone from upstream to downstream, given the geological context and topography, allows to estimate the role of supply from high and low altitudes to the recharge processes. The water temperature has been used as a tracer to understand the pattern of groundwater flow and to determine the mean recharge elevation for springs. Inferences from standard oxygen and hydrogen isotopic measurements are compared with temperature measurements made at the springs to confirm the recharge elevation estimation and whether groundwater circulates to shallow or deeper depths. The METIS model, coupling groundwater flow and heat transport simulations in 2D steady flow regime, has been used in order to confirm the findings of the temperature and mean flow rate analysis and to characterize the regional flow of the multi-layered aquifer system. This approach provides methodological insights into characterization of the groundwater pathway within complex porous media in tropical humid regions. This study enable us to provide guidance on the required level of model complexity as well as on the amount and type of observations data required.

  5. Multiplets: Their behavior and utility at dacitic and andesitic volcanic centers (United States)

    Thelen, Weston; Malone, Steve; West, Michael


    Multiplets, or groups of earthquakes with similar waveforms, are commonly observed at volcanoes, particularly those exhibiting unrest. Using triggered seismic data from the 1980-1986 Mount St. Helens (MSH) eruption, we have constructed a catalog of multiplet occurrence. Our analysis reveals that the occurrence of multiplets is related, at least in part, to the viscosity of the magma. We also constructed catalogs of multiplet occurrence using continuous seismic data from the 2004 eruption at MSH and 2007 eruption at Bezymianny Volcano, Russia. Prior to explosions at MSH in 2004 and Bezymianny in 2007, the multiplet proportion of total seismicity (MPTS) declined, while the average amplitudes and standard deviations of the average amplitude increased. The life spans of multiplets (time between the first and last event) were also shorter prior to explosions than during passive lava extrusion. Dome-forming eruptions that include a partially solidified plug, like MSH (1983-1986 and 2004-2008), often possess multiplets with longer life spans and MPTS values exceeding 50%. Conceptually, the relatively unstable environment prior to explosions is characterized by large and variable stress gradients brought about by rapidly changing overpressures within the conduit. We infer that such complex stress fields affect the number of concurrent families, MPTS, average amplitude, and standard deviation of the amplitude of the multiplets. We also argue that multiplet detection may be an important new monitoring tool for determining the timing of explosions and in forecasting the type of eruption.

  6. Wastewater Phosphorus Removal by Two Different Types of Andesitic Volcanic Tephra (United States)

    Liesch, Amanda M.


    Phosphorus (P) is the limiting nutrient controlling productivity in most inland freshwater systems. Several materials have been proposed for use to remove excess P from wastewater treatment, including volcanic lapilli and ash (tephra). There is limited data in using tephra as a P filter. There were two objectives of this study: (1) to determine…

  7. Genesis of ultra-high-Ni olivine in high-Mg andesite lava triggered by seamount subduction. (United States)

    Nishizawa, Tatsuji; Nakamura, Hitomi; Churikova, Tatiana; Gordeychik, Boris; Ishizuka, Osamu; Haraguchi, Satoru; Miyazaki, Takashi; Vaglarov, Bogdan Stefanov; Chang, Qing; Hamada, Morihisa; Kimura, Jun-Ichi; Ueki, Kenta; Toyama, Chiaki; Nakao, Atsushi; Iwamori, Hikaru


    The Kamchatka Peninsula is a prominent and wide volcanic arc located near the northern edge of the Pacific Plate. It has highly active volcanic chains and groups, and characteristic lavas that include adakitic rocks. In the north of the peninsula adjacent to the triple junction, some additional processes such as hot asthenospheric injection around the slab edge and seamount subduction operate, which might enhance local magmatism. In the forearc area of the northeastern part of the peninsula, monogenetic volcanic cones dated at peridotite and formed a peridotite-pyroxenite source, causing the temporal evolution of local magmatism with wide compositional range.

  8. Ongeluk basaltic andesite formation in Griqualand West, South Africa: Submarine alteration in a 2222 Ma Proterozoic sea

    CSIR Research Space (South Africa)

    Cornell, DH


    Full Text Available seawater 0.7025 during submarine modem ocean-floor alteration; the Rb/Sr system also reveals a much later (similar to 1200 Ma?) phase of Ca and Rb mobility in a few samples. In contrast the submarine alteration affected Pb isotope ratios so little that a...

  9. Hf isotope evidence for variable slab input and crustal addition in basalts and andesites of the Taupo Volcanic Zone, New Zealand

    DEFF Research Database (Denmark)

    Waight, Tod Earle; Troll, Valentin R.; Gamble, J.A.


    variations likely represent variability in primary magma compositions as a result of different degrees of sediment addition at the slab-wedge interface. Coupled variations in isotopic composition, LILE/HFSE ratios (e.g. Rb/Zr and Ba/La) and SiO2 also clearly indicate that shallower level crustal interactions...... interpretations that they are derived from oceanic crust that underlies the Torlesse meta-sediments. The results indicate that interactions with sediments at both the slab-wedge interface and in the lithosphere must be considered when evaluating trace element and isotopic variations in continental arcs....

  10. The effect of kauri (Agathis australis) on grain size distribution and clay mineralogy of andesitic soils in the Waitakere Ranges, New Zealand

    NARCIS (Netherlands)

    Jongkind, A.G.; Buurman, P.


    Kauri (Agathis australis) is generally associated with intense podzolisation, but little research has been carried out to substantiate this. We studied soil profiles, grain size distribution patterns and clay mineralogy under kauri and broadleaf/tree fern vegetation in the Waitakere Ranges, North

  11. Morphological analysis of Nevado de Toluca volcano (Mexico): new insights into the structure and evolution of an andesitic to dacitic stratovolcano (United States)

    Norini, Gianluca; Groppelli, Gianluca; Capra, Lucia; De Beni, Emanuela


    We present a morphological analysis of Nevado de Toluca volcano located 80 km WSW of Mexico City based on digital elevation model study, where slope and aspect maps have been generated and analysed. Aerial photograph and satellite image observations improve the morphological analysis. The synoptic view which is offered by this analysis allowed for recognition and localization of the main volcanic and tectonic features of the area. On the basis of digital elevation model value distribution and surface textures, five morphological domains were defined. The most interesting domain, south of the crater, reflects the occurrence of an ancient complex volcano distinct from the adjacent areas. Interaction between the volcanic and volcano-tectonic evolution and the basement produced the other domains. Single volcanic edifices, like lava domes and scoria cones, and eruptive fractures were recognized. Finally, flank collapse scarps opened to the east and to the north were identified and four relevant morphostructural lineaments and their possible role in the Nevado de Toluca geological and structural evolution are discussed.

  12. Corrigendum to ;On progress and rate of the peritectic reaction Fo + SiO2 → En in natural andesitic arc magmas; [Geochim. Cosmochim. Acta 185 (2016) 383-393 (United States)

    Zellmer, Georg F.; Sakamoto, Naoya; Matsuda, Nozomi; Iizuka, Yoshiyuki; Moebis, Anja; Yurimoto, Hisayoshi


    In the original article, an olivine dissolution rate of 3-6 × 10-11 m s-1 was quoted for the tephra we have studied. However, it was not considered that the crystal dissolves on all sides, rather than just on the one edge studied, so the diameter of the crystal will reduce by twice this rate, 9 (±3) × 10-11 m s-1.

  13. Vulcanian explosions in the process of building-destruction of the lava dome of andesitic volcano: Insight from the seismic signals recorded at Volcán de Colima, México (United States)

    Zobin, Vyacheslav M.; Peral, Juan J.; Nava, Fernando; Bretón, Mauricio


    The seismic signals associated with the Vulcanian explosive events at Volcán de Colima, México during its 1998-2014 eruption were discriminated into three types according the waveforms of their initial phases. This classification includes about 85-90% of all seismic signals associated with explosive events. It was shown that the classification of the explosive seismic signals gave a useful tool for analysis of the eruption development. Analysis was performed for two 6-month stages of the eruption, the 2003 post-effusive stage culminated with large explosions and the 2007 co-effusive stage during the beginning of new lava dome growth in the crater of the volcano. The predominance (95%) of the type 1 and 3 events with low-frequency (LF) and high + low frequency (HF + LF) initial phases in the sample of the 2003 post-effusive stage explosive events identifies the termination of the lava effusion and preparation to the stage of large explosions. The high participation (37%) of the type 2 events with high-frequency (HF) initial phases in the sample of the 2007 co-effusive stage explosive events indicates the process of the lava dome growth beginning. The introduction of multi-stage conceptual model of explosive process allows the interpretation of peculiarities of the seismic signals associated with explosive activity. Analysis of the spectral content of the initial LF phases of the seismic signals associated with the explosions showed that the sources of LF initial phases, corresponding to the ascent of magma within the volcanic conduit above the fragmentation zone, were common for post-effusive and co-effusive stages. The source of events with the HF initial phases differed from the source of events with the LF first phases. The sources of explosions at explosion level were situated at different sites during post-effusive and co-effusive stages.

  14. Journal of Earth System Science | Indian Academy of Sciences

    Indian Academy of Sciences (India)

    Keywords. Andesite; dacite; Barren island; Narcondam island; magma mixing. Abstract. Andesite and dacite from Barren and Narcondam volcanic islands of Andaman subduction zone are composed of plagioclase, orthopyroxene, clinopyroxene, olivine, titanomagnetite, magnesio-hornblende and rare quartz grains.

  15. Journal of Earth System Science | Indian Academy of Sciences

    Indian Academy of Sciences (India)

    It consists of pillowed basalts, basaltic andesites, andesites (BBA) and rhyolites interlayered with ferruginous chert that were formed under submarine condition. Rhyolites were divided into type-I and II based on their REE abundances and HREE fractionation. Rb–Sr and Sm–Nd isotope studies were carried out on the rock ...

  16. Rb–Sr and Sm–Nd isotope systematics and geochemical studies on ...

    Indian Academy of Sciences (India)

    It consists of pillowed basalts, basaltic andesites, andesites (BBA) and rhyolites interlayered with ferruginous chert that were formed under submarine condition. Rhyolites were divided into type-I and II based on their REE abundances and HREE fractionation. Rb–Sr and Sm–Nd isotope studies were carried out on the rock ...

  17. Petrographic and major elements results as indicator of the geothermal potential in Java (United States)

    Indarto, S.; Setiawan, I.; Kausar, A.; Permana, dan H.


    Geothermal manifestations existed in West Java (Cilayu, Papandayan Mountain, Telagabodas, Karaha, Tampomas Mountain), Central Java (Slamet Mountain, Dieng) and East Java (Argopuro Mountain) show a difference in their mineral and geochemical compositions. The petrographic analysis of volcanic rocks from Garut (West Java) are basalt, andesite basaltic and andesite. However, based on SiO2 vs K2O value, those volcanic rocks have wide ranges of fractionated magma resulting basalt – basaltic andesite to dacitic in composition rather than those of Slamet Mountain, Dieng, and Argopuro Mountain areas which have a narrower range of fractionation magma resulting andesite basaltic and andesite in compositions. The volcanic rocks from Garut show tholeiitic affinity and calc-alkaline affinity. The geothermal potential of Java is assumed to be related to the magma fractionation level. Geothermal potential of West Java (Garut) is higher than that of Central Java (Slamet Mountain, Dieng) and East Java (Argopuro Mountain).

  18. Physical weathering and modification of a rhyolitic hyaloclastite in Iceland

    NARCIS (Netherlands)

    de Vet, S.J.; Mittelmeijer-Hazeleger, M.C.; Braakhekke, J.J.M.; Cammeraat, L.H.


    Fragmental volcanic glass or 'hyaloclastite' is a common glaciovolcanic eruption product that is formed in large abundance during basaltic, andesitic and rhyolitic sub-glacial eruptions. The physical weathering of rhyolitic hyaloclastites differs notably from basaltic hyaloclastites due to

  19. June 1991 Pinatubo, Philippines Images (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Mount Pinatubo is an andesitic island arc volcano, located on the southwestern part of the island of Luzon in the Philippines. Prior to 1991, it had been dormant for...

  20. Petrology and geochemistry of igneous inclusions in recent Merapi deposits

    DEFF Research Database (Denmark)

    Chadwick, J.P.; Troll, V.R.; Waight, Tod Earle


    basalt to andesite compositions. Results for mineral geobarometry on the inclusions suggest a crystallisation history for the plutonic inclusions and the recent and historic Merapi magmas that spans the full depth of the crust, indicating a multi-chamber magma system with high amounts of semi......Recent basaltic-andesite lavas from Merapi volcano contain abundant and varied igneous inclusions suggesting a complex sub-volcanic magmatic system for Merapi volcano. In order to better understand the processes occurring beneath Merapi, we have studied this suite of inclusions by petrography......, geochemistry and geobarometric calculations. The inclusions may be classified into four main suites: (1) highly crystalline basaltic-andesite inclusions, (2) co-magmatic enclaves, (3) plutonic crystalline inclusions and (4) amphibole megacrysts. Highly crystalline basaltic-andesite inclusions and co...

  1. The petrology and geochemistry of high cascade volcanics in southern Washington: Mount Saint Helens volcano and the Indian Heaven basalt field (United States)

    Smith, D. R.


    Mount St. Helens volcano (Washington, USA) was characterized by four eruptive periods during the last 2200 years. Eruptive products include a wide spectrum of rock types including basaltic to andesitic lavas, andesitic to dacitic pyroclastic flows and tephra, and dacite domes. The major and trace element compositions of some andesites and dacites are broadly consistent with their derivation from a basaltic andesite parental magma by fractional crystallization processes involving the observed phenocryst assemblages. However, the strontium and oxygen isotopic compositions of representative samples of the Mount St. Helens suite indicate that closed system processes cannot explain the isotopic variations. The isotopic ratios are positively correlated with one another and with bulk composition (SiO2, Mg number, etc.). The isotopic variations and trace element data support an origin of some intermediate and silicic rock types by combined processes of assimilation and fractional crystallization.

  2. MX Siting Investigation. Mineral Resources Survey, Seven Additional Valleys, Nevada/Utah Siting Area. Volume IV. (United States)


    Replacement deposits In Permian (7) limestone near alas kite stock (189). Turquoise In argillized zones in shale, and dike (233). Turquoise Veinlets, lenses...sediments ( 4 10 I Gold, silver in argillized Milltown andesite, silicified dacite (149). Silver, gold, lead NW - trending lodes along shear zones in the...Tertiary Fraction Breccia 0153). Gold, silver, copper, lead N-S fracture system in argillized , alunitized, and silicified Tertiary Milltown andesite

  3. Significance of Assimilation and Fractional Crystallization (AFC ...

    Indian Academy of Sciences (India)


    In the total alkali (Na2O+K2O) versus silica (SiO2), diagram the samples plot in the fields of basalt and basaltic andesite (Fig. 4). The SiO2 wt% of the basalts and basaltic andesites ranges from 46.7 to 53.7%. Al2O3 content shows a narrow range between 11.5 wt% to 13.2 wt%. Moderate to high variations in MgO and CaO ...

  4. Geology, mineralogy and magma evolution of Gunung Slamet Volcano, Java, Indonesia (United States)

    Vukadinovic, Danilo; Sutawidjaja, Igan

    Gunung Slamet, Central Java, is a large stratovolcano within the Sunda magmatic arc of Indonesia. The volcanic edifice includes products of two large overlapping Quaternary stratocones. Basaltic andesites and andesites, with rare basalts, dominate the western region of the complex, known as Slamet Tua (old); and basalts and basaltic andesites compose the eastern cone, called Slamet Muda (young). On the basis of stratigraphy, trace-element content, {Zr}/{Nb}, {Zr}/{K} and {87Sr}/{86Sr} ratios, Slamet lavas can be broadly categorized as relating to high abundance magma (HAM) and low abundance magma (LAM) types. The Tua and Lebaksiu sequences generally comprise the LAM group, and are older, more salic and have higher {87Sr}/{86Sr} ratios than those of HAM. LAM andesites contain some amphibole, but HAM andesites do not. Models involving randomized magma replenishment, tapping and fractionation (RTF) were developed to explain the geochemical features of both LAM and HAM rock groups. The salic lavas of the LAM suite can be generated if fractionation was dominant relative to replenishment and tapping in LAM magma chambers. Conversely, magma chambers with a high proportion of replenishment and tapping relative to fractionation can produce dominantly mafic lavas, such as those of the HAM suite. Concave-upward heavy-rare-earth element (HREE) patterns for LAM andesites are probably due to significant amphibole fractionation; HAM andesites display flat HREE patterns and do not require amphibole fractionation from parental basalts. The high TiO 2 contents of HAM basalts and basaltic andesites (relative to those of "average" arc rocks) are due to either suppressed crystallization—or minor accumulation—of Ti-magnetite, in conjunction with RTF processes.

  5. Evaluation of Resistance to Los Angeles Abrasion and Physical Factors with Grindability Properties of Some Aggregate Materials

    Directory of Open Access Journals (Sweden)

    C. Sensogut


    Full Text Available In recent years, the usage of aggregate materials has increased both in Turkey and the entire world. It can be said that the main reason of this rise is the population growth together with the demand towards the more qualitative life. Therefore, the usability of some aggregate materials was investigated in the present paper. The properties of Los Angeles abrasion resistance, freezing-thaw resistance, slake durability strength and frost resistance of basalt and andesite samples obtained from Karaman and Ankara regions were studied at the first stage. In the second order, the grindability performance of these materials was also determined from the discontinuous grinding tests and the obtained results were correlated. Whereas the Los Angeles resistance of the basalt sample was higher than the andesite sample, the mass losses after the freezing-thaw and the frost tests for the andesite sample were superior. Both of the basalt and andesite samples were classified as ‘very high’ for their slake durability strength (Id-2 values. The material percentage of the andesite sample, which is passing through the sub-size ( %90 was greater than the value obtained for the basalt sample during the same grinding time. The resistance to the crushing process was obtained to be maximum at -850+600 µm of feed size for the basalt and the andesite samples.

  6. Post-Eocene volcanics of the Abazar district, Qazvin, Iran: Mineralogical and geochemical evidence for a complex magmatic evolution (United States)

    Asiabanha, A.; Bardintzeff, J. M.; Kananian, A.; Rahimi, G.


    The style of volcanism of post-Eocene volcanism in the Alborz zone of northern Iran is different to that of Eocene volcanism (Karaj Formation). Indeed, the volcanic succession of the Abazar district, located in a narrow volcanic strip within the Alborz magmatic assemblage, is characterized by distinct mineralogical and chemical compositions linked to a complex magmatic evolution. The succession was produced by explosive eruptions followed by effusive eruptions. Two main volcanic events are recognized: (1) a thin rhyolitic ignimbritic sheet underlain by a thicker lithic breccia, and (2) lava flows including shoshonite, latite, and andesite that overlie the first event across a reddish soil horizon. Plagioclase in shoshonite (An 48-92) shows normal zoning, whereas plagioclase in latite and andesite (An 48-75) has a similar composition but shows reverse and oscillatory zoning. QUILF temperature calculations for shoshonites and andesites yield temperatures of 1035 °C and 1029 °C, respectively. The geothermometers proposed by Ridolfi et al. (2010) and Holland and Blundy (1994) yield temperatures of 960 °C and 944 °C for latitic lava, respectively. The samples of volcanic rock show a typical geochemical signature of the continental arc regime, but the andesites clearly differ from the shoshonites, the latites and the rhyolites. The mineralogical and chemical characteristics of these rocks are explained by the following petrogenesis: (1) intrusion of a hot, mantle-depth mafic (shoshonitic) magma, which differentiated in the magma chamber to produce a latitic and then a rhyolitic liquid; (2) rhyolitic ignimbritic eruptions from the top of the magma chamber, following by shoshonitic and then latitic extrusions; (3) magma mingling between the latitic and andesitic magmas, as indicated by the occurrence of andesite clasts within the latite; and (4) andesitic effusions. The youngest volcanic events in the Alborz zone show a close chemical relationship with continental arc

  7. Pliocene volcanism of the Taos Plateau, Rio Grande Rift-New constraints on eruptive cycles, compositional trends and links to rift tectonism (United States)

    Thompson, R. A.; Cosca, M. A.; Turner, K. J.; Condit, C. B.; Lee, J.; Budahn, J. R.; Drenth, B.


    The Taos Plateau volcanic field (TPVF) in the southern San Luis Basin of northern New Mexico and southern Colorado is the most voluminous of the predominantly basaltic Neogene (6-1 Ma) volcanic fields of the Rio Grande rift. Coincident with extensional tectonism, volcanic deposits of the TPVF are intercalated with alluvial deposits of the Santa Fe Group and reflect the time-integrated magmatic response to basin- and sub basin-scale structural accommodation of regional extension. New data constraining the eruptive history of mafic to intermediate composition Pliocene volcanic rocks of the Taos Plateau volcanic field are presented based on integrated geologic mapping (1:24,000 to 1:50,000 scale), 40Ar/39Ar geochronology, geochemistry and aeromagnetic data. Mapped stratigraphy and faulting is linked to new gravity model interpretations to establish the location of deeper basin and sub basin geometry relative to mapped eruptive centers. Three representative clusters of eruptive centers in the San Luis Basin (San Antonio Mtn., Ute Mtn., and Guadalupe Mtn./Red River areas) range in composition from basaltic andesite to dacite but are volumetrically dominated by high-silica andesite to dacite. Eruptive cycles for each cluster are: San Antonio Mtn. (andesite - 4.17 Ma, high silica andesite to dacite - 3.08 Ma); Ute Mtn. (andesite - 3.95 Ma, high silica andesite - 3.90 Ma); Guadalupe Mtn./Red River (Guadalupe Mtn. dacite - 5.04 Ma, Hatchery volcano basaltic andesite to andesite - 4.90 Ma) and Red River high silica andesite - 4.64 Ma). Deposits of each cluster are stratigraphically intercalated with Servilleta Basalt (5.26-3.36 Ma) but not temporally associated with these distally derived lavas. Each mapped cluster is spatially associated with mapped or inferred basin- or sub basin- bounding structures largely derived from new gravity models and interpretation of aeromagnetic data. However, few temporal constraints on pre- as well as post-eruption displacement on rift faults

  8. The Mount Edgecumbe tephra deposits, a marker horizon in southeastern Alaska near the Pleistocene-Holocene boundary (United States)

    Riehle, J.R.; Mann, D.H.; Peteet, D.M.; Engstrom, D.R.; Brew, D.A.; Meyer, C.E.


    Late Pleistocene tephra deposits found from Sitka to Juneau and Lituya Bay are assigned to a source at the Mount Edgecumbe volcanic field, based on similarity of glass compositions to nearvent deposits and on thinning away from Kruzof Island. The sequence of near-vent layers is basaltic andesite and andesite at the base, rhyolite, and mixed dacite and rhyolite on top. The only breaks in the tephra sequence are two 1-mm-thick silt partings in a lake-sediment core, indicating a depositional interval from basaltic andesite to dacite of no more than about a millennium. Tephra deposits at sites >30 km from the vent are solely dacite and rhyolite and are 10,600 to 11,400 14C yr old based on interpretation of 18 radiocarbon ages, including 5 by accelerator mass spectrometry (AMS). Basaltic andesite and andesite deposits nearer the vent are as much as 12,000 yr old. Discrepancy among radiocarbon ages of upland tephra deposits provisionally correlated as the same grainfall is resolvable within ??2 ?? of analytical uncertainty. Comparison of bulk and AMS ages in one sediment core indicates a systematic bias of +600 to +1100 yr for the bulk ages; correlation of tephra deposits among upland and lacustrine sites implies an additional discrepancy of 200-400 yr between upland (relatively too young) and lacustrine ages. In any case, the Mount Edgecumbe tephra deposits are a widespread, latest Pleistocene stratigraphic marker that serves to emphasize the uncertainty in dating biogenic material from southeastern Alaska. ?? 1992.

  9. Permian arc evolution associated with Panthalassa subduction along the eastern margin of the South China block, based on sandstone provenance and U-Pb detrital zircon ages of the Kurosegawa belt, Southwest Japan (United States)

    Hara, Hidetoshi; Hirano, Miho; Kurihara, Toshiyuki; Takahashi, Toshiro; Ueda, Hayato


    We have studied the petrography, geochemistry, and detrital zircon U-Pb ages of sandstones from shallow-marine forearc sediments, accretionary complexes (ACs), and metamorphosed accretionary complexes (Meta-ACs) within the Kurosegawa belt of Southwest Japan. Those rocks formed in a forearc region of a Permian island arc associated with subduction of the Panthalassa oceanic crust along the eastern margin of the South China block (Yangtze block). The provenance of the shallow-marine sediments was dominated by basaltic to andesitic volcanic rocks and minor granitic rocks during the late Middle to Late Permian. The ACs were derived from felsic to andesitic volcanic rocks during the Late Permian. The provenance of Meta-ACs was dominated by andesitic volcanic rocks in the Middle Permian. The provenance, source rock compositions, and zircon age distribution for the forearc sediments, ACs and Meta-ACs have allowed us to reconstruct the geological history of the Permian arc system of the Kurosegawa belt. During the Middle Permian, the ACs were accreted along the eastern margin of the South China block. The Middle Permian arc was an immature oceanic island arc consisting of andesitic volcanic rocks. During the Late Permian, the ACs formed in a mature arc, producing voluminous felsic to andesitic volcanic rocks. A forearc basin developed during the late Middle to Late Permian. Subsequently, the Middle Permian ACs and part of the Late Permian AC underwent low-grade metamorphism in the Late to Early Jurassic, presenting the Meta-ACs.

  10. Pleistocene Paleoclimatic Features at Mount Mazama Volcano and the Crater Lake Region, Oregon, Dated by Ar Geochronology (United States)

    Bacon, C. R.; Lanphere, M. A.


    Fifteen examples of the interplay between glacial ice and magma or volcanic rock in the Crater Lake region have been dated by K-Ar or 40Ar/39Ar. Ages of glacial features compare well with times of extensive ice presence implied by marine oxygen isotope stages (MIS; Bassinot et al. 1994 EPSL 126:91-108). Prior to the 7.7-ka caldera-forming eruption, the summit of Mount Mazama was 3700 m asl. Moraines of the last glacial maximum (LGM) reached as low as 1400 m. Late MIS 10 glaciation is recorded at 1900-2000 m: in the SE caldera wall, glaciated andesite (340±6, 341±8 ka; 1σ) is overlain by intracanyon dacite (306±5 ka); in the E wall, similar glaciated andesite underlies till capped by dacite (336±6 ka); on the SW lakeshore, glaciated dacite (351±12 ka) is overlain by andesite (302±10 ka). Early MIS 8 is represented 276±11-ka dacite of Munson Ridge that implies >170 m of ice at 2040 m. In late MIS 8 or in MIS 7.4, voluminous andesite of Applegate Peak (7 ages 269±12 to 211±16 ka) chilled against thick ice along the E edge of Sun Creek valley at 1850 m and higher. Andesite of Garfield Peak (224±9 ka; 2100-2400 m) flowed over andesite (269±12 ka) glaciated during MIS 8.0 or 7.4. North of Castle Creek at 1740 m dacite (216±4 ka) lies on andesite (258±7 ka) glaciated in MIS 7.4 or 8.0. Andesite of Roundtop (159±13 ka) extending 3 km NE of the caldera rim is an MIS 6 ice-bounded lava flow. At Pumice Point, polygonal jointing and breccia occur in thick andesite (117±3 ka) that rests on glaciated (1900 m) mafic andesite (122±20 ka); the andesite is overlain by subaerial dacite (116±5 ka). Although the mafic andesite could have been glaciated in MIS 6, ice-contact/meltwater chilling of the overlying andesite probably dates from MIS 5.4. Below Llao Rock, andesite (70±4 ka) caps sediments deposited on dacite (116±9 ka) during MIS 5.4-4. Andesite (87±15 ka) from a subaerial cone (base 1900 m) ESE of Mazama flowed into ice-free Scott Creek during MIS 5

  11. The Park Volcanics Group : field relations of an igneous suite emplaced in the Triassic-Jurassic Murihiku Terrane, South Island, New Zealand

    International Nuclear Information System (INIS)

    Coombs, D.S.; Cook, N.D.J.; Campbell, J.D.


    Park Volcanics Group is proposed for igneous rocks, either shallow intrusive or extrusive, emplaced in the Murihiku Terrane during Triassic-Jurassic times. The term replaces Park Intrusives of Mutch, some members of which are shown to be extrusive rather than intrusive. Formation status within the group is given to Gowan Andesite and Pinney Volcanics (new names) in western Southland, Glenham Porphyry in eastern Southland, and Barnicoat Andesite (new) in the Richmond area, Nelson. Gowan Andesite is a porphyritic feldspar two-pyroxene andesite with a glassy or microcrystalline groundmass. A suite of low-grade metavolcanic rocks which forms the main mass of Malakoff Hill and which has formerly been included in the 'Park Intrusives' is here excluded and ascribed to the Takitimu Group; representative chemical data are given. Glenham Porphyry is typically a porphyritic feldspar two-pyroxene andesite texturally similar to the Gowan Andesite but with significant geochemical differences. Two volumetrically minor members are recognised, Habukinini Trachydacite and Kenilworth Rhyolite. In the north of its outcrop area, Glenham Porphyry is emplaced on or into Late Triassic terrestrial beds; in the middle it overlies Kaihikuan (Middle Triassic) and is overlain by Otapirian (latest Triassic) marine beds; and in the southeast it is directly overlain by Ururoan (late Early to early Middle Jurassic) conglomerates and marine sandstones. Pinney Volcanics are restricted to a very few, probably one, massive conglomeratic horizon in the Oretian Stage. The commonest rock type is a two-pyroxene trachydacite, modified by very-low-grade burial metamorphism. Auto-brecciation is characteristic and rock types change over short distances. Hornblende-rich variants occur as well as more felsic varieties including rhyolite ignimbrite. These may have been erupted onto a bouldery floodplain or shallow-marine surface, but alternatively may have been mass-emplaced by debris avalanche resulting from

  12. Evidence for the Jurassic arc volcanism of the Lolotoi complex, Timor: Tectonic implications (United States)

    Park, Seung-Ik; Kwon, Sanghoon; Kim, Sung Won


    We report the first sensitive high-resolution ion microprobe (SHRIMP) U-Pb zircon ages with geochemical data from metavolcanic rocks in the Lolotoi complex, Timor. The zircon U-Pb ages of two andesitic metavolcanic rocks yield a permissible range of the Middle Jurassic extrusion from 177 Ma to 174 Ma. The geochemical data indicate that the origins of the basaltic and andesitic metavolcanic rocks are products of prolonged oceanic crust and arc magmatism, respectively. They are originated from partial melting of lherzolites, providing an insight into the tectonic evolution of the forearc basements of the Banda volcanic arc. Thus, parts of the Banda forearc basement are pieces of allochthonous oceanic basalts and Jurassic arc-related andesites accreted to the Sundaland during the closure of Mesotethys, and are incorporated later into the Great Indonesian Volcanic Arc system along the southeastern margin of the Sundaland.

  13. Mineralogy and geochemistry of Eocene Helete formation , Adiyaman, Turkey (United States)

    Choi, J.; Lee, I.; Yildirim, E.


    Helete formation is located at Adiyaman, Turkey which is in the Alpine-Himalayan orogeny belt. Helete formation is represented by andesitic, basaltic and gabbroic rocks cut by localized felsic intrusions and overlain by open-marine Nummulitic carbonate sediments. Electron microprobe analyses were conducted for 15 rocks samples of Helete formation. These rock samples are named as basalt, andesite, gabbro, diorite, dacite, and granite. Basalt and andesite samples are composed of clinopyroxene(augite), plagioclase(Ab98-96), carbonate, and hyaline. Gabbro samples have wide range of plagioclase composition from anorthite to albite(Ab92-16), and other minerals like clinopyroxene(augite) and amphibole(hornblende and actinolite). Diabase samples consist of epidote group minerals and sphene with plagioclase(Ab80), pyroxene and hornblende. Dacite samples are composed of dolomite and quartz. Granite samples are composed of quartz, chlorite, and plagioclase which range from albite to oligoclase in composition (Ab98-89).

  14. Compositional evolution of the zoned calcalkaline magma chamber of Mount Mazama, Crater Lake, Oregon (United States)

    Bacon, C.R.; Druitt, T.H.


    The climactic eruption of Mount Mazama has long been recognized as a classic example of rapid eruption of a substantial fraction of a zoned magma body. Increased knowledge of eruptive history and new chemical analyses of ???350 wholerock and glass samples of the climactic ejecta, preclimactic rhyodacite flows and their inclusions, postcaldera lavas, and lavas of nearby monogenetic vents are used here to infer processes of chemical evolution of this late Pleistocene - Holocene magmatic system. The 6845??50 BP climactic eruption vented ???50 km3 of magma to form: (1) rhyodacite fall deposit; (2) welded rhyodacite ignimbrite; and (3) lithic breccia and zoned ignimbrite, these during collapse of Crater Lake caldera. Climactic ejecta were dominantly homogeneous rhyodacite (70.4??0.3% SiO2), followed by subordinate andesite and cumulate scoriae (48-61% SiO2). The gap in wholerock composition reflects mainly a step in crystal content because glass compositions are virtually continuous. Two types of scoriae are distinguished by different LREE, Rb, Th, and Zr, but principally by a twofold contrast in Sr content: High-Sr (HSr) and low-Sr (LSr) scoriae. HSr scoriae were erupted first. Trace element abundances indicate that HSr and LSr scoriae had different calcalkaline andesite parents; basalt was parental to some mafic cumulate scoriae. Parental magma compositions reconstructed from scoria wholerock and glass data are similar to those of inclusions in preclimactic rhyodacites and of aphyric lavas of nearby monogenetic vents. Preclimactic rhyodacite flows and their magmatic inclusions give insight into evolution of the climactic chamber. Evolved rhyodacite flows containing LSr andesite inclusions were emplaced between ???30000 and ???25000 BP. At 7015??45 BP, the Llao Rock vent produced a zoned rhyodacite pumice fall, then rhyodacite lava with HSr andesite inclusions. The Cleetwood rhyodacite flow, emplaced immediately before the climactic eruption and compositionally

  15. Storage conditions of the mafic and silicic magmas at Cotopaxi, Ecuador (United States)

    Martel, Caroline; Andújar, Joan; Mothes, Patricia; Scaillet, Bruno; Pichavant, Michel; Molina, Indira


    The 2015 reactivation of the Cotopaxi volcano urges us to understand the complex eruptive dynamics of Cotopaxi for better management of a potential major crisis in the near future. Cotopaxi has commonly transitioned from andesitic eruptions of strombolian style (lava flows and scoria ballistics) or nuées ardentes (pyroclastic flows and ash falls) to highly explosive rhyolitic ignimbrites (pumiceous pyroclastic flows), which entail drastically different risks. To better interpret geophysical and geochemical signals, Cotopaxi magma storage conditions were determined via existing phase-equilibrium experiments that used starting materials chemically close to the Cotopaxi andesites and rhyolites. The results suggest that Cotopaxi's most mafic andesites (last erupted products) can be stored over a large range of depth from 7 km to ≥16 km below the summit (pressure from 200 to ≥400 MPa), 1000 °C, NNO +2, and contain 4.5-6.0±0.7 wt% H2O dissolved in the melt in equilibrium with 30-40% phenocrysts of plagioclase, two pyroxenes, and Fe-Ti oxides. These mafic andesites sometimes evolve towards more silicic andesites by cooling to 950 °C. Rhyolitic magmas are stored at 200-300 MPa (i.e. 7-11 km below the summit), 750 °C, NNO +2, and contain 6-8 wt% H2O dissolved in a nearly aphyric melt (<5% phenocrysts of plagioclase, biotite, and Fe-Ti oxides). Although the andesites produce the rhyolitic magmas by fractional crystallization, the Cotopaxi eruptive history suggests reactivation of either reservoirs at distinct times, likely reflecting flux or time fluctuations during deep magma recharge.

  16. Pre-eruptive magmatic conditions at Augustine Volcano, Alaska, 2006: Evidence from amphibole geochemistry and textures (United States)

    De Angelis, Sarah; Larsen, Jessica D; Coombs, Michelle L.


    Variations in the geochemistry and texture of amphibole phenocrysts erupted from Augustine Volcano in 2006 provide new insights into pre- and syn-eruptive magma storage and mixing. Amphiboles are rare but present in all magma compositions (low- to high-silica andesites) from the 3 month long eruption. Unzoned magnesiohornblende in the high- and low-silica andesites exhibit limited compositional variability, relatively high SiO2 (up to 49·7 wt %), and relatively low Al2O3 (temperature-dependent substitutions. Both high- and low-silica andesites represent remnant magmas that were stored in the shallow crust at 4–8 km depth, remaining distinct owing to a complex subsurface plumbing system. Intermediate-silica andesites and quenched mafic inclusions represent pre-eruptive hybrids of resident high- and low-silica andesite magmas and an intruding basalt. Amphiboles in explosive phase high-silica andesites are largely euhedral and unreacted, consistent with the high magma flux rates from depth during this phase (up to 13 800 m3 s–1). Phenocrysts from the other lithologies have reaction rims that range from 1 to >1000 μm in thickness. Reaction rim microlite sizes correlate with reaction rim thicknesses. Reaction rims 80 μm thick contain microlites 10–100 μm in length. Differentiating between heating- and decompression-induced amphibole reaction rim formation is problematic because of a lack of experimental constraints. We attempt a new approach to assessing reaction rim formation, based on a kinetic theory of crystal nucleation and growth, in which the differences in reaction rim textures represent different degrees of amphibole disequilibrium. Large crystals and low number densities suggest relatively lower levels of disequilibrium resulting in growth-dominated crystallization. Smaller crystals and larger number densities are indicative of higher nucleation rates and a high driving force.

  17. Rock Pore Structure as Main Reason of Rock Deterioration

    Directory of Open Access Journals (Sweden)

    Ondrášik Martin


    Full Text Available Crashed or dimensional rocks have been used as natural construction material, decoration stone or as material for artistic sculptures. Especially old historical towns not only in Slovakia have had experiences with use of stones for construction purposes for centuries. The whole buildings were made from dimensional stone, like sandstone, limestone or rhyolite. Pavements were made especially from basalt, andesite, rhyolite or granite. Also the most common modern construction material - concrete includes large amounts of crashed rock, especially limestone, dolostone and andesite.

  18. Global geologic context for rock types and surface alteration on Mars (United States)

    Wyatt, M.B.; McSween, H.Y.; Tanaka, K.L.; Head, J. W.


    Petrologic interpretations of thermal emission spectra from Mars orbiting spacecraft indicate the widespread occurrence of surfaces having basaltic and either andesitic or partly altered basalt compositions. Global concentration of ice-rich mantle deposits and near-surface ice at middle to high latitudes and their spatial correlation with andesitic or partly altered basalt materials favor the alteration hypothesis. We propose the formation of these units through limited chemical weathering from basalt interactions with icy mantles deposited during periods of high obliquity. Alteration of sediments in the northern lowlands depocenter may have been enhanced by temporary standing bodies of water and ice. ?? 2004 Geological Society of America.

  19. Fossilization Type of Elephas Hysudrindicus From Blora on the Basis of Petrographic and Scanning Electron Microscopic Analyses


    Herman, Danny Z


    DOI: 10.17014/ijog.v6i2.117Either fossils of the hominid or vertebrate have long been known from terraces along the Solo River in Central and East Java. Most terraces consist of andesitic sand to andesitic tuffaceous sand with either gravelpebble or conglomerate and some of them contain vertebrate fossils. It is in this place, an ancient elephant fossil named Elephas hysudrindicus was discovered in 2009. This fossil was discovered at an abandoned sand quarry of Sunggun area, Medalem Village, ...

  20. New K-Ar ages of volcanic rocks and associated mineralization in Canada Honda district, San Luis, Argentina

    International Nuclear Information System (INIS)

    Urbina, N.E.; Oggier, F.P


    New K-Ar ages in the Late Tertiary gold-bearing volcanic belt of the Sierras Pampeanas of San Luis, Argentina are presented. At Canada Honda district, an age of 8.49±0.2 Ma yielded by Cerro del Valle andesite indicates that the dome emplacement postdates the Diente Verde eruptive event. An even younger age of 7.3±0.2 Ma was obtained for illite from hydrothermal alteration at La Reynela mineralization which is hosted by Cerro del Valle andesite (au)

  1. Untitled

    Indian Academy of Sciences (India)

    mainly during the field work done in the summer of 1937 under the very aluable guidance of Prof. Raj Nath and partly alone, again in the summer. 'f 1941. The material was ... ant, nevertheless their discovery is of much interest.' Mr. D. N. Wadia (1939, p. 412-13) describes these traps as “A basic variety of augite andesite.

  2. The End of Sluiter’s Coral Reef at Krakatoa

    NARCIS (Netherlands)

    Umbgrove, J.H.F.


    It is well known that before the famous eruption of August 1883 took place, the island Krakatoa consisted of three volcanoes, the basaltic volcano Rakata and the andesitic volcanoes Danan and Perbuwatan. With the great explosion of August 28th of that year Danan, Perbuwatan and the northwestern part

  3. Geochronology and magmatic evolution of the Dieng Volcanic Complex, Central Java, Indonesia and their relationships to geothermal resources (United States)

    Harijoko, Agung; Uruma, Ryusuke; Wibowo, Haryo Edi; Setijadji, Lucas Doni; Imai, Akira; Yonezu, Kotaro; Watanabe, Koichiro


    We analyzed new radiometric dating and petrological data of DVC in an attempt to reconstruct volcanic history as groundwork to understand magmatic temporal and spatial evolution. The magma of DVC can be divided on the basis of mineral composition into three types: olivine bearing basalt-basaltic andesite, pyroxene basaltic andesite-andesite, and biotite andesite-dacite, which coincide with three volcanic episodes of DVC: pre-caldera, second, and youngest episode, respectively. The pre-caldera episode was active no later than 1 Ma, the second episode occurred between 0.3 and 0.4 Ma, and the youngest occurred after 0.27 Ma. Plots of CaO, K2O, Al2O3, and Rb/Sr against FeO*/MgO and/or MgO suggest that each volcanic episode has distinct differentiation trends, indicating the presence of multiple shallow magma chambers. The close spatial relationship between the geothermal manifestation, geophysical anomalies, geothermal production zones and volcanic edifices supports the presence of multiple shallow magma chambers beneath DVC, which act as a heat source for the existing geothermal system.

  4. Petrography, Geochemistry and Petrogenesis of Maru Amphibolite ...

    African Journals Online (AJOL)

    ... Cr and Co) which implies the origin of its protolith from partial melting of depleted or metasomatised mantle or mafic crust. Its precursor is dominantly basaltic with some basaltic trachy-andesite. The paleo-tectonic environment is volcanic arc and plate alkaline basalts. Keywords: Amphibolite, Geochemistry, Protolith, Maru ...

  5. Carbonate assimilation at Merapi volcano, Java Indonesia

    DEFF Research Database (Denmark)

    Chadwick, J.P; Troll, V.R; Ginibre,, C.


    Recent basaltic andesite lavas from Merapi volcano contain abundant, complexly zoned, plagioclase phenocrysts, analysed here for their petrographic textures, major element composition and Sr isotope composition. Anorthite (An) content in individual crystals can vary by as much as 55 mol% (An40^95...

  6. Enrichments of the mantle sources beneath the Southern Volcanic Zone (Andes) by fluids and melts derived from abraded upper continental crust

    DEFF Research Database (Denmark)

    Holm, Paul Martin; Søager, Nina; Dyhr, Charlotte Thorup


    Mafic basaltic-andesitic volcanic rocks from the Andean Southern Volcanic Zone (SVZ) exhibit a northward increase in crustal components in primitive arc magmas from the Central through the Transitional and Northern SVZ segments. New elemental and Sr–Nd-high-precision Pb isotope data from the Quat...

  7. Nanggulan Formation and Its Problem As a Basement in Kulonprogo Basin, Yogyakarta

    Directory of Open Access Journals (Sweden)

    Hill Gendoet Hartono


    Full Text Available DOI: 10.17014/ijog.4.2.71-80Nanggulan Formation consists of the oldest clastic rock sequence exposed in Kulonprogo area, Yogyakarta. This paper discusses the position of Nanggulan Formation as a basement. The method used in this research is surface and subsurface investigations based on gravity surveys. The rock assemblage is exposed and distributed partly in the east flank of Kulonprogo Mountains with weak undulated morphology. The rock sequence is composed of sand to clay grain sizes such as sandstone, quartz sandstone, calcareous sandstone, claystone, fossiliferous claystone, calcareous claystone, siltstone, and coal seam intercalations. The total thickness of the sequence is less than 200 m. Based on the fossil and palynology investigations, previous investigators concluded the age of the rock was Eocene to Middle Miocene. The geological structures developed in the rocks are the lithological stratification, fractures, folding, and faulting. The subsurface interpretation based on gravity data revealed the rock was located under the andesite breccias with 2.44 g/cc density. The density of the rock sequence was 2.63 g/cc. The gravity interpretation shows a strong indication that Nanggulan Formation underlies the andesitic breccias presumably associated with Old Andesite Formation exposed in Kulonprogo Mountains. The limited distribution, the thickness, and the closed environmental deposition of Nanggulan Formation found in the present investigation raised problems on the position of the formation as the basement of Old Andesite Formation occurring in the Kulonprogo Mountain.

  8. Geochemical constraints on the evolution of mafic and felsic rocks in ...

    Indian Academy of Sciences (India)

    Granites are emplaced later, crosscutting the volcanic sequence and are probably products of fractional crystallization of basaltic magma. The present work characterizes the geochemical characteristics of the magmatic rocks comprising of basalt, andesite, rhyolite, tuff, and granite of the area. Tholeiitic trend for basalt and ...

  9. Magma-carbonate interaction processes and associated CO2 release at Merapi volcano, Indonesia: insights from experimental petrology

    NARCIS (Netherlands)

    Deegan, F.M.; Troll, V.R.; Freda, C.; Misti, V.; Chadwick, J.P.


    There is considerable evidence for continuing, late-stage interaction between the magmatic system at Merapi volcano, Indonesia, and local crustal carbonate (limestone). Calc-silicate xenoliths within Merapi basaltic-andesite eruptive rocks display textures indicative of intense interaction between

  10. Journal of Earth System Science | Indian Academy of Sciences

    Indian Academy of Sciences (India)

    Microtextural and mineral chemical analyses of andesite–dacite from Barren and Narcondam islands: Evidences for magma mixing and petrological implications · Dwijesh Ray S Rajan Rasik Ravindra Ashim Jana · More Details Abstract Fulltext PDF. Andesite and dacite from Barren and Narcondam volcanic islands of ...

  11. Microtextural and mineral chemical analyses of andesite–dacite ...

    Indian Academy of Sciences (India)

    'Fritted' zones (An55) are frequently overgrown by thin calcic (An72) plagioclase rims over well-developed dissolution surfaces. These features have probably resulted from mixing of a more silicic magma with the host andesite. Olivine and orthopyroxene with reaction and overgrowth rims (corona) suggest magma mixing ...

  12. Archaeological Geophysics for DoD Field Use: A Guide for New and Novice Users (United States)


    top image: imported andesite cobbles are scattered about the surface in this area of Tiwanaku (Bolivia), adding clutter to the data, but careful... Rubber mallet. A mallet or hammer makes pounding in stakes easier, and one made of rubber is less likely to damage them. Rubber mallets often include some

  13. High-Ti type N-MORB parentage of basalts from the south Andaman ...

    Indian Academy of Sciences (India)

    R. Narasimhan (Krishtel eMaging) 1461 1996 Oct 15 13:05:22

    basalts as sub-alkaline basalts and alkaline basalts. A few samples show basaltic andesite, trachy- basalt, or basanitic chemical composition. High-field strength element (HFSE) geochemistry sug- gests that studied basalt samples are probably derived from similar parental magmas. Al2O3/TiO2 and CaO/TiO2 ratios classify ...

  14. Chemical trends in a perhumid soil catena on the Turrialba volcano (Costa Rica)

    NARCIS (Netherlands)

    Meijer, E.L.; Buurman, P.


    The variation in chemical composition of soil samples (XRFS data) from a soil catena of 14 soil profiles on the northern slope and foot slope of the andesitic Turrialba volcano (3300 m) has been analysed to test the two hypotheses, which underlie our interpretation that this catena is a weathering

  15. The nature of transition from adakitic to non-adakitic magmatism in a slab window setting: A synthesis from the eastern Pontides, NE Turkey

    Directory of Open Access Journals (Sweden)

    Yener Eyuboglu


    Full Text Available The eastern Pontides orogenic belt provides a window into continental arc magmatism in the Alpine–Himalayan belt. The late Mesozoic–Cenozoic geodynamic evolution of this belt remains controversial. Here we focus on the nature of the transition from the adakitic to non-adakitic magmatism in the Kale area of Gumushane region in NE Turkey where this transition is best preserved. The adakitic lithologies comprise porphyries and hyaloclastites. The porphyries are represented by biotite-rich andesites, hornblende-rich andesite and dacite. The hayaloclastites represent the final stage of adakitic activity and they were generated by eruption/intrusion of adakitic andesitic magma into soft carbonate mud. The non-adakitic lithologies include basaltic-andesitic volcanic and associated pyroclastic rocks. Both rock groups are cutting by basaltic dikes representing the final stage of the Cenozoic magmatism in the study area. We report zircon U-Pb ages of 48.71 ± 0.74 Ma for the adakitic rocks, and 44.68 ± 0.84 Ma for the non-adakitic type, suggesting that there is no significant time gap during the transition from adakitic to non-adakitic magmatism. We evaluate the origin, magma processes and tectonic setting of the magmatism in the southern part of the eastern Pontides orogenic belt. Our results have important bearing on the late Mesozoic–Cenozoic geodynamic evolution of the eastern Mediterranean region.

  16. Volcanostratigraphy and Evolution Characterization Using Morphological and Geochemical Analysis, and Field Observation for Quaternary Balerang and Rajabasa Volcanoes, Lampung-Indonesia (United States)

    Hasibuan, R. F.; Ohba, T.; Abdurrachman, M.; Sapiie, B.


    Balerang and Rajabasa are Quaternary volcanic complex with active fumaroles though no historic eruptions were recorded. These volcanoes are stratovolcanoes and located in the volcanic front of Sunda arc. Although some studies reported the geological setting of these volcanoes in these past few years, their detailed volcanostratigraphy and evolution are still unclear. Morphological analysis and field observation were used to understand the detail of volcanostratigraphy and the evolution of volcanic edifices. Morphological characteristics were analyzed by areal and linear analysis using perspective view of DEM. Sample data from Balerang and Rajabasa volcanoes were collected as well and compared each other. By analyzing the both data, it was elucidated that this volcanic complex has erupted from 4 different vents, and produced both lavas and pyroclastics. This result was strengthened by constructing a fence diagram and reconciling each of the layers. The shifting of vents was strongly influenced by active dextral Great Sumatran Fault. Geochemical study was conducted as well, and this study shows that the composition of Balerang's magma has undergone a reversal evolution from dacite to basaltic andesite. The lavas of the early product shows dacitic (%SiO2~65.76-66.24), middle stage shows andesitic (%SiO2 ~62.19), and the late stage shows basaltic andesite (%SiO2 ~55.19). On the other hand, Rajabasa magma is nearly constant between andesitic to dacitic (%SiO2 ~60.15-65.52).

  17. Fading characteristics of martian analogue materials and the applicability of a correction procedure

    DEFF Research Database (Denmark)

    Morthekai, P.; Jain, Mayank; Murray, A.S.


    The anomalous fading of trapped charge in martian analogue materials such as basalt and andesite rock samples is measured. Optically stimulated luminescence (OSL) signals show rapid fading (of between 4% and 27% per decade). Fading rates obtained using high temperature thermoluminescence signals...

  18. The distribution of radon in tunnels with different geological characteristics in China

    Energy Technology Data Exchange (ETDEWEB)

    Li Xiaoyan, E-mail: [School of Geographic and Biologic Sciences, Guizhou Normal University, GuiYang 550001 (China); Song Bo [College of Environmental Science and Engineering, Guilin University of Technology, Guilin 541004 (China); Zheng Baoshan [Institute of Geochemistry, Chinese Academy of Sciences, GuiYang 550002 (China); Wang Yan [Institute of Rock and Soil Mechanics, Chinese Academy of Sciences, Wuhan 430071 (China); Wang Xue [Institute of Geochemistry, Chinese Academy of Sciences, GuiYang 550002 (China)


    In China, as the economy is developing and the population is expanding, some underground buildings have been used as supermarkets, restaurants and entertainment places. Tunnels in mountains are one type of underground building, and the radon ({sup 222}Rn) level in tunnels is an important issue. Radon levels in different type tunnels appear to differ, and relatively higher levels of {sup 222}Rn are associated with particular types of bedrock. The {sup 222}Rn levels in tunnels in five different geological characteristics were analyzed. Those built in granite had the highest {sup 222}Rn levels with a geometric mean (GM) of 280 Bq m{sup -3}, while those built in limestone (GM: 100 Bq m{sup -3}) and andesitic porphyry (GM: 96 Bq m{sup -3}) were lower. The sequence of {sup 222}Rn concentrations was: granite > tuff > quartz sandstone > limestone > andesitic porphyry, and the {sup 222}Rn in granite was statistically significantly higher than in limestone and andesitic porphyry. Tunnels built in granite, tuff, quartz sandstone, limestone tended to have higher {sup 222}Rn concentrations in summer than in winter, while the reverse tendency was true in andesitic porphyry tunnels. Only the difference in limestone was statistically significant.

  19. Journal of Earth System Science | Indian Academy of Sciences

    Indian Academy of Sciences (India)

    Geochemical studies and modelling show that both volcanic and granitic magmas from the western part of the Johor National Park, Endau Rompin are different and probably have different sources. The geochemical plot suggests that both dacite/rhyolite and andesite probably have a common origin as in many of the ...

  20. Mass budget partitioning during explosive eruptions: insights from the 2006 paroxysm of Tungurahua volcano, Ecuador (United States)

    Bernard, Julien; Eychenne, Julia; Le Pennec, Jean-Luc; Narváez, Diego


    How and how much the mass of juvenile magma is split between vent-derived tephra, PDC deposits and lavas (i.e., mass partition) is related to eruption dynamics and style. Estimating such mass partitioning budgets may reveal important for hazard evaluation purposes. We calculated the volume of each product emplaced during the August 2006 paroxysmal eruption of Tungurahua volcano (Ecuador) and converted it into masses using high-resolution grainsize, componentry and density data. This data set is one of the first complete descriptions of mass partitioning associated with a VEI 3 andesitic event. The scoria fall deposit, near-vent agglutinate and lava flow include 28, 16 and 12 wt. % of the erupted juvenile mass, respectively. Much (44 wt. %) of the juvenile material fed Pyroclastic Density Currents (i.e., dense flows, dilute surges and co-PDC plumes), highlighting that tephra fall deposits do not depict adequately the size and fragmentation processes of moderate PDC-forming event. The main parameters controlling the mass partitioning are the type of magmatic fragmentation, conditions of magma ascent, and crater area topography. Comparisons of our data set with other PDC-forming eruptions of different style and magma composition suggest that moderate andesitic eruptions are more prone to produce PDCs, in proportions, than any other eruption type. This finding may be explained by the relatively low magmatic fragmentation efficiency of moderate andesitic eruptions. These mass partitioning data reveal important trends that may be critical for hazard assessment, notably at frequently active andesitic edifices.

  1. Significance of Assimilation and Fractional Crystallization (AFC ...

    Indian Academy of Sciences (India)


    andesites of the Chhotaudepur area plot close to a consistent mixing trend between typical mantle composition ... Deccan tholeiites and alkaline felsic rocks also exhibit a significant trend of crustal contamination. .... Keeping the rate of assimilation to fractional crystallization (r) as 0.3, the binary plotting was carried out and.

  2. Inca Volcanic Stone Provenance in the Cuzco Province, Peru

    Directory of Open Access Journals (Sweden)

    Patrick N. Hunt


    Full Text Available The use of andesite and basalt as architectual ashlars by Inca stonemasons has been widely discussed throughout the literature. Most of these archaeological or architectural studies are in agreement that that primary Inca quarrying centers in the Cuzco area are in the Rio Huatanay valley at Rumiqolqa and Huaccoto, both to the southeast of Cuzco.

  3. Depositional conditions of the coal-bearing Hirka Formation beneath ...

    Indian Academy of Sciences (India)

    This work focuses on the relationship between the coal deposition and explosive volcanism of the Miocene basin, NW central Anatolia, Turkey. The coal-bearing Hirka Formation was deposited over the Galatian Andesitic Complex and/or massive lagoonal environments during the Miocene. The investigated lignite is a high ...

  4. Geologic and preliminary reservoir data on the Los Humeros Geothermal System, Puebla, Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Ferriz, H.


    Exploratory drilling has confirmed the existence of a geothermal system in the Los Humeros volcanic center, located 180 km east of Mexico City. Volcanic activity in the area began with the eruption of andesites, followed by two major caldera-forming pyroclastic eruptions. The younger Los Potreros caldera is nested inside the older Los Humeros caldera. At later stages, basaltic andesite, dacite, and olivine basalt lavas erupted along the ring-fracture zones of both calderas. Geologic interpretation of structural, geophysical, and drilling data suggests that: (1) the water-dominated geothermal reservoir is hosted by the earliest andesitic volcanic pile, is bounded by the ring-fracture zone of the Los Potreros caldera, and is capped by the products of the oldest caldera-forming eruption; (2) permeability within the andesitic pile is provided by faults and fractures related to intracaldera uplift; (3) the geothermal system has potential for a large influx of meteoric water through portions of the ring-fracture zones of both calderas; and (4) volcanic centers with similar magmatic and structural conditions can be found in the eastern Cascades, USA.

  5. Growth of intra-caldera lava domes controlled by various modes of caldera collapse, the Štiavnica volcano-plutonic complex, Western Carpathians

    Czech Academy of Sciences Publication Activity Database

    Tomek, Filip; Žák, J.; Holub, F. V.; Chlupáčová, M.; Verner, K.


    Roč. 311, February 1 (2016), s. 183-197 ISSN 0377-0273 Institutional support: RVO:67985831 Keywords : andesite * anisotropy of magnetic susceptibility (AMS) * collapse caldera * lava dome * magma flow * stratovolcano Subject RIV: DC - Siesmology, Volcanology, Earth Structure Impact factor: 2.492, year: 2016

  6. New insights into the origin of the bimodal volcanism in the middle Okinawa Trough: not a basalt-rhyolite differentiation process (United States)

    Zhang, Yuxiang; Zeng, Zhigang; Chen, Shuai; Wang, Xiaoyuan; Yin, Xuebo


    In the middle Okinawa Trough (MOT), rhyolites have been typically considered as products of crystallization differentiation of basaltic magma as a feature of bimodal volcanism. However, the evidence is insufficient. This paper compared chemical trends of volcanic rocks from the MOT with fractional crystallization simulation models and experimental results and utilized trace element modeling combined with Rayleigh fractionation calculations to re-examine fractional crystallization processes in generating rhyolites. Both qualitative and quantitative studies indicate that andesites, rather than rhyolites, originate by fractional crystallization from basalts in the MOT. Furthermore, we established two batch-melting models for the MOT rhyolites and proposed that type 1 rhyolites are produced by remelting of andesites with amphiboles in the residue, while type 2 rhyolites are derived from remelting of andesites without residual amphiboles. It is difficult to produce melts with a SiO2 content ranging from 62% to 68% either by magmatic differentiation from basalts or by remelting of andesites, and this difficulty might help account for the compositional gap (Daly gap) for bimodal volcanism in the Okinawa Trough.

  7. Petrological constraints on the high-Mg basalts from Capo Marargiu (Sardinia, Italy): Evidence of cryptic amphibole fractionation in polybaric environments (United States)

    Tecchiato, Vanni; Gaeta, Mario; Mollo, Silvio; Scarlato, Piergiorgio; Bachmann, Olivier; Perinelli, Cristina


    This study deals with the textural and compositional characteristics of the calc-alkaline stratigraphic sequence from Capo Marargiu Volcanic District (CMVD; Sardinia island, Italy). The area is dominated by basaltic to intermediate hypabyssal (dikes and sills) and volcanic rocks (lava flows and pyroclastic deposits) emplaced during the Oligo-Miocene orogenic magmatism of Sardinia. Interestingly, a basaltic andesitic dome hosts dark-grey, crystal-rich enclaves containing up 50% of millimetre- to centimetre-sized clinopyroxene and amphibole crystals. This mineral assemblage is in equilibrium with a high-Mg basalt recognised as the parental magma of the entire stratigraphic succession at CMVD. Analogously, centimetre-sized clots of medium- and coarse-grained amphibole + plagioclase crystals are entrapped in andesitic dikes that ultimately intrude the stratigraphic sequence. Amphibole-plagioclase cosaturation occurs at equilibrium with a differentiated basaltic andesite. Major and trace element modelling indicates that the evolutionary path of magma is controlled by a two-step process driven by early olivine + clinopyroxene and late amphibole + plagioclase fractionation. In this context, enclaves represent parts of a cumulate horizon segregated at the early stage of differentiation of the precursory high-Mg basalt. This is denoted by i) resorption effects and sharp transitions between Mg-rich and Mg-poor clinopyroxenes, indicative of pervasive dissolution phenomena followed by crystal re-equilibration and overgrowth, and ii) reaction minerals found in amphibole coronas formed at the interface with more differentiated melts infiltrating within the cumulate horizon, and carrying the crystal-rich material with them upon eruption. Coherently, the mineral chemistry and phase relations of enclaves indicate crystallisation in a high-temperature, high-pressure environment under water-rich conditions. On the other hand, the upward migration and subsequent fractionation of the

  8. Park Volcanics, Murihiku Terrane, New Zealand : petrology, petrochemistry, and tectonic significance

    International Nuclear Information System (INIS)

    Coombs, D.S.; Cook, N.D.J.; Kawachi, Y.; Johnstone, R.D.; Gibson, I.L.


    The Late Triassic to Early Jurassic Park Volcanics Group comprises minor shallow intrusive and extrusive bodies emplaced during mainly marine sedimentation of the Murihiku Terrane, southern New Zealand. Gowan Andesite in western Southland and Glenham Porphyry andesites in eastern Southland are high-K andesites. Glassy examples have commonly lost K during alteration. Orthoclase contents of Or 3.6-3.7 in plagioclase phenocrysts at An 50 confirm the high-K nature of the melts at the time of phenocryst crystallisation. The Gowan andesites have higher Fe/Mg than the Glenham and related differences in minor element chemistry suggesting lower ∫O 2 during fractionation of the parent magma. Pinney Volcanics in western Southland are mostly high-K trachydacites but, like Glenham Porphyry, include minor rhyolite. Barnicoat Andesite in the Nelson area is medium-K olivine andesite, marginally tholeiitic in terms of its FeO*/MgO versus SiO 2 behaviour, but otherwise is typically calc-alkaline, as are the Gowan, Glenham, and Pinney. Analyses of pyroxenes (augites, orthopyroxenes, reaction rim and groundmass pigeonites) reveal xenocrysts recording an early stage of magma fractionation, slight iron enrichment in the andesite stage, and lowered Fe/Mg and increased Ca contents in augites of the most felsic rocks. Titanian tschermakite and titanian magnesio-tschermakite of deep-seated origin participated in fractionation leading to the Pinney Volcanics, and magnesio-hornblende, edenite, and biotite crystallised as minor late stage minerals following high-level emplacement of Gowan Andesite and siliceous Glenham Porphyry members. Low 87 Sr/ 86 Sr ratios (c. 0.7034-0.7037), REE and multi-element distribution patterns, and the mineralogical features collectively suggest fractionation of the andesites from parental basalt originating in an enriched mantle wedge above a subduction zone, with minimal contamination by continental crust. High-K andesites appear to be unknown in clearly

  9. 39Ar/40Ar Chronology and Volumes of Eruptive Products Over the Last 1 Myr in the Tequila Volcanic Field, Jalisco, Mexico (United States)

    Lewis-Kenedi, C. B.; Lange, R. A.; Hall, C. M.; Delgado-Granados, H.


    The Tequila volcanic field, located within the western Trans-Mexican arc, covers an area of 1036 km2 and includes a central, andesitic stratocone, Volc\\­_{a}n Tequila, as well as cinder cones, domes, and fissure-fed flows. Sixty-nine high precision 39Ar-40Ar dates reveal that major activity in the Tequila volcanic field began at approximately 1 Ma. From 1 Ma to 200 ka, rhyolite (> 73 wt. % SiO2) and alkali basalt (­š 51 wt. % SiO2) were the only compositions erupted in significant volumes (29 +/- 5.7 km3 and 12 +/- 1.2 km3, respectively). At approximately 200 ka, the andesite comprising Volc\\­_{a}n Tequila erupted within 30-40 kyr, producing a volume of 30 +/- 2.0 km3. Additional andesitic flows (11 +/- 1.4 km3) erupted to the northwest and southeast of the stratocone between 140 and 20 ka. The total volume of dacite that erupted at the Tequila volcanic field is small (1.3 +/- 0.03 km3) and occurred largely (88%) within the last 70 kyrs. Unlike the andesites and dacites, the basalts and rhyolites did not erupt within narrow time intervals, but extruded over the entire last 1 Myr, producing a total volume of 12.6 +/- 1.2 km3 and 32 +/- 6.1 km3, respectively. This detailed eruptive history, combined with the observed phenocryst assemblages (0-10 vol. %) in the small-volume andesite, dacite, and alkali basalt flows, suggest that they were erupted directly from the lower (or middle) crust, without prior storage in an upper crustal chamber. In contrast, the voluminous burst of andesitic volcanism that produced the phenocryst-rich (35-45 vol. %) lavas of Volc\\­_{a}n Tequila was likely fed from a short-lived (­š 40 kyrs) upper crustal chamber. This scenario is supported by the complex, disequilibrium textures seen in the phenocryst assemblage of the Volc\\­_{a}n Tequila lavas, indicative of magma mingling within an upper crustal chamber (Wallace and Carmichael, 1994). The total volume of erupted material at the Tequila volcanic field is 89 +/- 12 km3, of which

  10. Magmatic context of Bou Skour copper deposit (Eastern Anti-Atlas, Morocco): Petrogrography, geochemistry and alterations (United States)

    EL Azmi, Daoud; Aissa, M.; Ouguir, H.; Mahdoudi, M. L.; El Azmi, M.; Ouadjo, A.; Zouhair, M.


    The Bou Skour copper deposit is located in the western part of the Saghro massif (Eastern Anti-Atlas), about 50 km East of the city of Ouarzazate. It is subdivided into several areas that are, from North to South: “Panthère”, “Chaigne”, “Anne Marie”, “Chapeau de fer” and “Patte d'Oie”. The latter is economically the most important and is the object of this study. The “Patte d'Oie” district consists mainly of extrusive and intrusive igneous rocks. The extrusive rocks are represented by andesites spatially associated with pyroclastic terms (ignimbrites and pyroclastic breccias). This volcanic unit is intruded by a pink granite pluton and a I-type granodiorite with equigranular texture (Bou Skour granodiorite) showing to the border a microgranular facies (microgranodiorite). All these magmatic formations are intersected by rhyolitic dykes (NNE-SSW) and doleritic dykes (WNW-ESE to NW-SE). The granodiorite and andesite have undergone a polyphase hydrothermal alteration: (i) potassic alteration, (ii) phyllitic alteration, (iii) silicification, (iv) argillic alteration and (v) propylitic alteration. The analysis of geochemical data of granodiorite, granite, andesite and dolerite confirmed: (i) their petrographic natures, (ii) the medium-K calc-alkaline affiliation of andesite and granodiorite, which would have been set up into an active geotectonic environment, probably of island arc or collision, during the Pan-African orogeny, (iii) The high-K calc-alkaline character of granite indicating a post-collision development during the Pan-African orogeny and (iv) The alkaline affinity of the dolerite which is linked to an extensive post-orogenic setting (post-Pan-African). The copper mineralization of “Patte d'Oie” area is hosted, exclusively, in the andesitic and granodioritic facies. It is represented, essentially, by chalcopyrite and bornite minerals and is, probably, related to a porphyry system (disseminated and stockwork mineralization

  11. Volcano-stratigraphy and Petrography of the Hasandaǧ Volcanites (Central Anatolia) (United States)

    Zeynep Çalışkanoǧlu, Ayşe; Ünal, Alp; Karadaǧ, Elif; Altunkaynak, Şafak; Görür, Naci


    The Hasandaǧ stratovolcano is one of the crucial volcanos within the Cappadocian Volcanic Complex, located in Central Anatolia, Turkey. In Quaternary, it produced various types of volcanic rocks including a variety of lava flows, domes and associated pyroclastic and volcanoclastic rocks. In this study, volcano-stratigraphy and petrography of the volcanic rocks which forms the SE flank of the Hasandaǧ stratovolcano will be presented. The early pyroclastic products associated with plinian-subplinian eruptions cover large areas with different thickness in the region. Felsic pyroclastic rocks are dominant and represented by ash, pumice and pumice-block tuffs and accretionary lapilli tuffs/breccias. Pyroclastic deposits are present as thin layers of reworked tuffs intercalated with sedimentary rocks (mudstone and marl) at the bottom of the volcanic sequence. They interfinger with pyroclastic flow deposits dominated by welded tuff and ignimbrite succession towards the upper parts of the sequence. Andesite- basaltic andesite and basaltic trachy-andesite lavas form the most common lava phase in the region and overlie the pyroclastic succession. At the upper parts of the volcanic succession, basaltic dykes and associated pyroclastic rocks are observed. The youngest member of the volcanic association is represented by andesitic-basaltic andesitic dykes which were injected into basaltic lavas and associated proclastic rocks. The areal distribution of the volcanic rocks in the SE flank of the Hasandaǧ stratovolcano indicates that they were erupted from a number of vents which set parallel to the NW-SE trending major fault systems of Central Anatolia (eg. The Salt Lake Fault). Petrographic investigations indicate that, all lava samples display several textures reflecting disequilibrium crystallization such as different stage of the plagioclase crystallization, sieve texture in plagioclases, clinopyroxene crystals mantled by hornblende (corona texture) and reaction textures

  12. Geochemistry of the 1989-1990 eruption of redoubt volcano: Part II. Evidence from mineral and glass chemistry (United States)

    Swanson, S.E.; Nye, C.J.; Miller, T.P.; Avery, V.F.


    Early stages (December 1989) of the 1989-1990 eruption of Redoubt Volcano produced two distinct lavas. Both lavas are high-silica andesites with a narrow range of bulk composition (58-64 wt.%) and similar mineralogies (phenocrysts of plagioclase, hornblende, augite, hypersthene and FeTi oxides in a groundmass of the same phases plus glass). The two lavas are distinguished by groundmass glass compositions, one is dacitic and the other rhyolitic. Sharp boundaries between the two glasses in compositionally banded pumices, lack of extensive coronas on hornblende phenocrysts, and seismic data suggest that a magma-mixing event immediately preceeded the eruption in December 1989. Textural disequilibrium in the phenocrysts suggests both magmas (dacitic and rhyolitic glasses) had a mixing history prior to their interaction and eruption in 1989. Sievey plagioclase and overgrowths of magnetite on ilmenite are textures that are at least consistent with magma mixing. The presence of two hornblende compositions (one a high-Al pargasitic hornblende and one a low-Al magnesiohornblende) in both the dacitic and rhyolitic groundmasses indicates a mixing event to yield these two amphibole populations prior to the magma mixing in December 1989. The pargasitic hornblende and the presence of Ca-rich overgrowths in the sievey zones of the plagioclase together indicate at least one component of this earlier mixing event was a mafic magma, either a basalt or a basaltic andesite. Eruptions in 1990 produced only andesite with a rhyolitic groundmass glass. Glass compositions in the 1990 andesite are identical to the rhyolitic glass in the 1989 andesite. Cognate xenoliths from the magma chamber (or conduit) are also found in the 1990 lavas. Magma mixing probably triggered the eruption in 1989. The eruption ended when this rather viscous (rhyolitic groundmass glass, magma capable of entraining sidewall xenoliths) magma stabalized within the conduit. ?? 1994.

  13. Analisis stratigrafi awal kegiatan Gunung Api Gajahdangak di daerah Bulu, Sukoharjo; Implikasinya terhadap stratigrafi batuan gunung api di Pegunungan Selatan, Jawa Tengah

    Directory of Open Access Journals (Sweden)

    Hill Gendoet Hartono


    Full Text Available, Tertiary volcanisms in the Southern Mountains, Central Jawa were started with the formation of pillow lavas having basalt to basaltic andesite in composition. This initial stage volcanism developed into a  construction period of composite volcanoes that consist of alternating basaltic to andesitic lava flows, breccias, and tuffs. The construction period could be followed by a destructive phase, producing pumice-rich pyroclastic breccias, lapillistones, and tuffs of high silica andesite to dacite, or even rhyolite in composition. A stratigraphic measuring section at Bulu area, Sukoharjo Regency, presents an alternat- ing fine-grained andesitic volcaniclastic material and some limestones, with the total thickness is 143.33 m. The thickness of bedded volcaniclastic material tends to be thickening upward from 35 m until 90 m. The grain size of the volcaniclastic material also tends to be coarsening upward from clay size through silt and fine sand to coarse sand and granules. Paleontological analysis on fossils contained in the lime- stone gives an age of Early Miocene (N7 - N9. The volcaniclastic rocks is conformably overlain by the Mandalika Formation, comprising alternating andesitic breccias, lavas, and tuffs. These data imply that the fine-grained volcaniclastic material is an initial product of the construction period of Gajahdangak Volcano in the area, that formed the Mandalika Formation. This Formation is overlain by the Semilir Formation, composed of pumice-rich pyroclastic breccias and tuffs with dacitic composition. This as- sociated volcanic rock reflects a product of a caldera explosion or a destructive phase. Based on the characteristics of lithology of volcanic products from the initial stage, to a construction and destruction period, and compiled age data, the Southern Mountains represent formal volcanic rock units that are able to be divided into many formations.  

  14. Plagioclase Crystal Populations in Lavas from Calbuco Volcano, Chile (United States)

    McKelvey, T.; Hickey-Vargas, R.


    Calbuco Volcano in Southern Chile is regionally unique in that it is predominantly andesitic, whereas surrounding volcanic centers are basaltic in composition. Lava from Calbuco is also hornblende-bearing, phenocryst-rich, and it contains crystal clots that are interpreted as cumulate minerals entrained in the magma. The phenocryst assemblage of the lava, and the mineral assemblage of the crystal clots, is: plagioclase, hornblende, orthopyroxene, clinopyroxene, olivine and oxide minerals. Three different species of plagioclase crystals are found in Calbuco andesite: zoned phenocrysts in the lava, unzoned grains in the crystal clots, and high-An megacrysts. The phenocrysts are predominantly anhedral and normally zoned with An mol% in the core ranging from An68-91, and at the rim from An58-82. Most of these crystals range in size from 50 to 700 microns, with rare grains larger, and nearly all contain melt inclusions. Plagioclase grains within the crystal clots are not zoned and have An mol% of An70-93, which overlaps the An mol% of the zoned phenocryst cores. These grains range in size from 100 to 500 microns. Megacrysts are 2000 microns and larger in size, and are unzoned, except for the rim of the grains. They have very high An mol% of An88-92 in the core. The 10-60 micron rims are normally zoned. Based on the overlapping An mol% contents of zoned plagioclase cores and the plagioclase from crystal clots, it is probable these two populations of crystals have formed as phenocrysts, crystallizing directly from the basaltic andesite to andesite magma. The origin of the megacrysts is more puzzling. Periodic replenishment by a more mafic magma and magma mixing could introduce these large An-rich plagioclase crystals, or they could be cumulate crystals that formed from a more mafic magma and were later entrained in andesitic magma. In either case, the narrow rim of normal zoning suggests a relatively short time span between entrainment and eruption.

  15. Intra-continental back-arc basin inversion and Late Carboniferous magmatism in Eastern Tianshan, NW China: Constraints from the Shaquanzi magmatic suite

    Directory of Open Access Journals (Sweden)

    Hongjun Jiang


    Full Text Available The Yamansu belt, an important tectonic component of Eastern Tianshan Mountains, of the Central Asian Orogenic Belt, NW China hosts many Fe–(Cu deposit. In this study, we present new zircon U-Pb geochronology and geochemical data of the volcanic rocks of Shaquanzi Formation and diorite intrusions in the Yamansu belt. The Shaquanzi Formation comprises mainly basalt, andesite/andesitic tuff, rhyolite and sub-volcanic diabase with local diorite intrusions. The volcanic rocks and diorites contain ca. 315–305 Ma and ca. 298 Ma zircons respectively. These rocks show calc-alkaline affinity with enrichment in large-ion lithophile elements (LILEs, light rare-earth elements (LREEs, and depletion in high field strength elements (HFSEs in primitive mantle normalized multi-element diagrams, which resemble typical back-arc basin rocks. They show depleted mantle signature with εNd(t ranging from +3.1 to +5.6 for basalt; +2.1 to +4.7 for andesite; −0.2 to +1.5 for rhyolite and the εHf(t ranges from −0.1 to +13.0 for andesites; +5.8 to +10.7 for andesitic tuffs. We suggest that the Shaquanzi Formation basalt might have originated from a depleted, metasomatized lithospheric mantle source mixed with minor (3–5% subduction-derived materials, whereas the andesite and rhyolite could be fractional crystallization products of the basaltic magma. The Shaquanzi Formation volcanic rocks could have formed in an intra-continental back-arc basin setting, probably via the southward subduction of the Kangguer Ocean beneath the Middle Tianshan Massif. The Yamansu mineralization belt might have undergone a continental arc to back-arc basin transition during the Late Carboniferous and the intra-continental back-arc basin might have closed in the Early Permian, marked by the emplacement of dioritic magma in the Shaquanzi belt.

  16. Baltazor KGRA and vicinity, Nevada: geothermal reservoir assessment case study, northern Basin and Range province. Final report, 1 October 1978-31 January 1983

    Energy Technology Data Exchange (ETDEWEB)

    Wright, T.C.


    The Baltazor KGRA and McGee/Painted Hills geothermal prospects are located in northern Humboldt County, Nevada along the northwestern margin of the Basin and Range province. Exploration work other than drilling has included groundwater sampling, a microearthquake study, a geologic literature search and photogeologic mapping, compilation of aeromagnetic and gravity mapping, soil mercury surveying, electrical resistivity and self-potential surveys and detailed hydrothermal alteration mapping. Exploration drilling included 27 shallow temperature gradient holes, four intermediate-depth gradient wells and one 3703-foot deep test, Baltazor 45-14. The deep test penetrated Miocene rhyolite, andesite, basalt and andesitic basalt flows before excessive hold deviation forced an end to drilling and completion as a deep temperature observation well. A temperature survey two weeks after completion obtained a 119.7/sup 0/C (247.4/sup 0/F) reading at survey total depth, 1110 m (3640 feet).


    Directory of Open Access Journals (Sweden)

    Jakob Pamić


    Full Text Available In the paper are presented basic geological, petrologieca1, geochemi-cal and mineral deposit data for five main magmatic-metallogenic formations of the northwestern and central Dinarides: (lThe Permo Triassic rifting related andesite-diorite formations; (2 The Jurassic-Lower Cretaceous accretionary (ophiolite formations; (3 The Upper Cretaceous-Paleogene subduction related basalt-rhyohite formations; (4 The Paleogene collisional granite formations, and (5 The Oligo-cene-Neogene postsubduction andesite formations. All these magmatic-metallogenic formations originated in different geotectonic settings during the Alpine evolution of the Dinaridic parts of thc Tethys and the postorogenic evolution of the Paratethys and the Pannonian Basin, respectively.

  18. Hydrogeology of Basins on Mars (United States)

    Arvidson, Raymond E.


    This document summarizes the work accomplished under NASA Grant NAG5-3870. Emphasis was put on the development of the FIDO rover, a prototype for the twin-Mers which will be operating on the surface of Mars in 2004, specifically the primary work was the analysis of FIDO field trials. The grantees also analyzed VIKING Lander 1 XRFS and Pathfinder APXS data. Results show that the Viking site chemistry is consistent with an andesite, and the Pathfinder site is consistent with a basaltic andesite. The grantees also worked to demonstrate the capability to simulate annealing methods to apply to the inversion of remote sensing data. They performed an initial analyses of Sojourner engineering telemetry and imaging data. They performed initial analyses of Viking Lander Stereo Images, and of Hematite deposits in Terra Meridiani. They also acquired and analyzed the New Goldstone radar data.

  19. Postglacial eruptive history, geochemistry, and recent seismicity of Aniakchak volcano, Alaska Peninsula (United States)

    Bacon, Charles R.; Neal, Christina A.; Miller, Thomas P.; McGimsey, Robert G.; Nye, Christopher J.


    Aniakchak is a Pleistocene to Holocene composite volcano of the Alaska–Aleutian arc that suffered at least one caldera-forming eruption in postglacial time and last erupted in 1931. The oldest recognized postglacial eruption, Aniakchak I, produced andesite ignimbrite ca. 9,500–7,500 14C yr B.P. Subsequently, a vent northeast of the summit issued dacite–rhyodacite magma ca. 7,000 14C yr B.P. mainly as the Black Nose Pumice falls. The ca. 3,430 14C yr B.P. Aniakchak II eruption produced rhyodacite plinian fall followed by rhyodacite and andesite ignimbrite extending ≥50 km to the Bering Sea and Pacific coasts and resulted in collapse of the 10-km-diameter caldera.

  20. Zeolitización de rocas andesíticas

    Directory of Open Access Journals (Sweden)

    Plana, F.


    Full Text Available The study of some andesites from King George Island (South Shetland Islands, Anctartica has pointed out the existence of a hydrothermal alteration process going rise to a zeolitic secondary minerals of low-temperature assemblages. Two paragenesis have been identified (Smectite-Bytownite-Mordenite, Smectite-Albite-Laumontite which reflecting different conditions durign the hydrothermal alteration of these andesitic rocksEl estudio de rocas andesíticas de la Isla King George (Archipiélago de las Shetland del Sur, Antártida pone de manifiesto la existencia de procesos de alteración hidrotermal con la formación de minerales zeolíticos secundarios pertenecientes a asociaciones de baja temperatura. Se han identificado dos paragénesis (Esmectitas-Bytownita-Mordenita, Esmectitas-AlbitaLaumontita que reflejan distintas condiciones durante la alteración hidrotermal de dichas rocas andesíticas.

  1. New Insights to the Mid Miocene Calc-alkaline Lavas of the Strawberry Volcanics, NE Oregon Surrounded by the Coeval Tholeiitic Columbia River Basalt Province (United States)

    Steiner, A. R.; Streck, M. J.


    The Strawberry Volcanics (SV) of NE Oregon were distributed over 3,400 km2 during the mid-Miocene and comprise a diverse volcanic suite, which span the range of compositions from basalt to rhyolite. The predominant composition of this volcanic suite is calc-alkaline (CA) basaltic andesite and andesite, although tholeiitic (TH) lavas of basalt to andesite occur as well. The coeval flood basalts of the Columbia River province surround the SV. Here we will discuss new ages and geochemical data, and present a new geologic map and stratigraphy of the SV. The SV are emplaced on top of pre-Tertiary accreted terranes of the Blue Mountain Province, Mesozoic plutonic rocks, and older Tertiary volcanic rocks thought to be mostly Oligocene of age. Massive rhyolites (~300 m thick) are exposed mainly along the western flank and underlie the intermediate composition lavas. In the southern portion of this study area, alkali basaltic lavas, thought to be late Miocene to early Pliocene in age, erupted and overlie the SV. In addition, several regional ignimbrites reach into the area. The 9.7 Ma Devine Canyon Tuff and the 7.1 Ma Rattlesnake Tuff also overlie the SV. The 15.9-15.4 Ma Dinner Creek Tuff is mid-Miocene, and clear stratigraphic relationships are found in areas where the tuff is intercalated between thick SV lava flows. All of the basalts of the SV are TH and are dominated by phenocryst-poor (≤2%) lithologies. These basalts have an ophitic texture dominated by plagioclase, clinopyroxene and olivine (often weathered to iddingsite). Basalts and basaltic andesites have olivine Fo #'s ranging from 44 at the rims (where weathered to iddingsite) and as high as 88 at cores. Pyroxene Mg #'s range from 65 to 85. Andesites of the SV are sub-alkaline, and like the basalts, are exceedingly phenocryst-poor (≤3%) with microphenocrysts of plagioclase and lesser pyroxene and olivine, which occasionally occur as crystal clots of ~1-3 mm instead of single crystals. In addition, minimal

  2. Geology and tectonic magmatic of emplacement of a longitudinal dyke swarm of Nico Perez(Minas) URUGUAY

    International Nuclear Information System (INIS)

    Gonzalez, P.; Poire, D.; Canalicchio, J.; Garcia Repetto, F.


    The Mina Verdun Group (Precambrian) was deposited prior to the subvolcanic emplacement of a longitudinal dyke swarm of basaltic to andesitic composition (Minas Subvolcanic Swarm of the Mina Verdun quarry - Nico Perez Terrane, Minas, Uruguay). The swarm and its country rocks predated a tectono-metamorphic event that produced fragileductile shear zones associated with very low- to low-grade dislocation metamorphism. We interpreted a K-Ar whole rock datum of 485,2 ± 12,5 Ma (andesitic dyke) as a minimum cooling age in relation with late- to post-swarm emplacement deuteric alteration stage. Another K-Ar whole rock datum of 108,5 ± 2,9 Ma on a basaltic dyke was assumed here as a degasification stage, while its geological meaning is still matter of debate. The Minas Subvolcanic Dyke Swarm was intruded at high crustal levels, suggesting that the Minas region was affected by a period of extensional tectonics [es

  3. Lithium diffusion in silicate melts (United States)

    Cunningham, G. J.; Henderson, P.; Lowry, R. K.; Nolan, J.; Reed, S. J. B.; Long, J. V. P.


    The diffusion properties of Li in an andesitic and pitchstone melt have been determined over the temperature range 1300-1400°C. The diffusion data have been fitted to an Arrhenius relationship between log D0 and 1/ T, and give relatively small activation energies of diffusion: 21.4±5.8 kcal mol -1 in the andesite and 20.1±2.8 kcal mol -1 in the pitchstone. Li +, unlike several other cations, shows similar diffusivities in these melt compositions to that in a basaltic melt. Despite the similar ionic radius of Li + to that of Co 2+, the diffusion properties of the two ions are very different from each other.

  4. Microscopic Rocks and Expansive Empires: Investigating Inca Ceramics from Cuzco, Peru

    Directory of Open Access Journals (Sweden)

    Rob Ixer


    Full Text Available High quality polychrome ceramics are an iconic aspect of Inca material culture. This ‘Cuzco Inca’ pottery appears suddenly in the archaeological record: but it draws upon technological and stylistic aspects of earlier local pottery and we discuss the specifics of how these pre-Inca traits were combined to form the distinctive new state ceramics. Using ceramic petrography, the dominant fabric of Cuzco Inca pottery is compared with those of two pre-Inca wares, Killke and Lucre. Andesite temper, identified in the Lucre and Cuzco Inca fabrics, is compared with samples of andesite from local geological outcrops. This suggests that Lucre pottery was made using similar materials to Cuzco Inca and was a technological precursor. Because these materials and technological knowledge would only have become available to the Inca after their conquest of the Lucre cultural area, this ceramic evidence has important implications for our understanding of Imperial expansion and state intervention in craft-production.

  5. Archeological Testing at at the Fairchild Site (LA 45732) Otero County, New Mexico. (United States)


    granitic, technically they are Monzonites, and contain more Plagio - clase Feldspar than Quartz. Therefore these rocks are mineralogically different...poorly developed Microperthite may be present. Rock #1 is rhyolitic and consists of anhedral Quartz and some Plagio - clase in an altered...quartzite. Rock #2 is andesitic and consists of Plagio - clase microlites with interstitial opaques. The Microperthite in this slide is heavily altered

  6. Chemical evolution, petrogenesis, and regional chemical ...

    Indian Academy of Sciences (India)

    The lava sequence of the central-western Deccan Traps (from Jalgaon towards Mumbai) is formed by basalts and basaltic andesites having a significant variation in TiO2 (from 1.2 to 3.3 wt%), Zr (from 84 to 253 ppm), Nb (from 5 to 16 ppm) and Ba (from 63 to 407 ppm), at MgO ranging from 10 to 4.2 wt%. Most of these ...

  7. International Uranium Resources Evaluation Project (IUREP) national favourability studies: Taiwan

    International Nuclear Information System (INIS)


    Taiwan is an island of 36,000 sq km located 160 km east of mainland China. Geologically, the oldest rocks are Tertiary, and the only igneous rocks on the island are Quaternary andesites and basalts. Copper, gold, and silver are the only known metallic minerals produced. Uranium occurrences and exploration efforts are unknown. The potential uranium resource of Taiwan is considered a category 1 resource. (author)

  8. Petrology and geochemistry of volcanic rocks of Cheshmeh Khuri and Shekasteh Sabz areas, Khur, northwest of Birjand

    Directory of Open Access Journals (Sweden)

    Maryam Javidi Moghaddam


    Full Text Available Khur area is located in east of Iran and northwest of Birjand. The area comprises outcrops of Eocene to Oligocene volcanics with basaltic andesite to rhyolite composition, which were intruded by subvolcanic and intrusive bodies of granodiorite to gabbro. In the present work, petrogenesis of volcanic units in Cheshmeh Khuri and Shekasteh Sabz areas was studied, which are located in Khur area and these volcanics have most widespread in them. Rhyolite, dacite, andesite, trachyandesite and basaltic andesite units in Cheshmeh Khuri and trachyandesite unit in Shekasteh Sabz were identified. The main textures of these units are porphyritic, hialoporphyritic and microlitic and plagioclase, pyroxene, K-feldspar, hornblende, biotite and quartz are the main minerals. Volcanic units of Cheshmeh Khuri have characteristic of high-K Calc-alkaline. Enrichment of LREE relative to HREE and LILE to HFSE are important evidences that magma was formed in a magmatic belt of a subduction zone. Based on the initial 87Sr/86Sr of andesite and dacite, their magma has originated from partial melting of an enriched mantle and contaminated with the crust through its differentiation. Trachyandesites of Shekaste Sabz have characteristic of shoshonitic nature. These units are characterized by high FeOt/FeOt+MgO, K2O/Na2O and Zr>360 ppm, Y>39 ppm, and Ce> 100 ppm. Also, they are enrichment in REE particularly in LREE, depletion of Eu, strong enrichment in HFSE, and depletion in Ba and Sr. Therefore, trachyandesites of Shekaste Sabz belong to post collision volcanics.

  9. Magmatic interactions as recorded in plagioclase phenocrysts of Chaos Crags, Lassen Volcanic Center, California (United States)

    Tepley, F. J.; Davidson, J.P.; Clynne, M.A.


    The silicic lava domes of Chaos Crags in Lassen Volcanic National Park contain a suite of variably quenched, hybrid basaltic andesite magmatic inclusions. The inclusions represent thorough mixing between rhyodacite and basalt recharge liquids accompanied by some mechanical disaggregation of the inclusions resulting in crystals mixing into the rhyodacite host preserved by quenching on dome emplacement. 87Sr/86Sr ratios (~0.7037-0.7038) of the inclusions are distinctly lower than those of the host rhyodacite (~0.704-0.7041), which are used to fingerprint the origin of mineral components and to monitor the mixing and mingling process. Chemical, isotopic, and textural characteristics indicate that the inclusions are hybrid magmas formed from the mixing and undercooling of recharge basaltic magma with rhyodacitic magma. All the host magma phenocrysts (biotite, plagioclase, hornblende and quartz crystals) also occur in the inclusions, where they are rimmed by reaction products. Compositional and strontium isotopic data from cores of unresorbed plagioclase crystals in the host rhyodacite, partially resorbed plagioclase crystals enclosed within basaltic andesite inclusions, and partially resorbed plagioclase crystals in the rhyodacitic host are all similar. Rim 87Sr/86Sr ratios of the partially resorbed plagioclase crystals in both inclusions and host are lower and close to those of the whole-rock hybrid basaltic andesite values. This observation indicates that some crystals originally crystallized in the silicic host, were partially resorbed and subsequently overgrown in the hybrid basaltic andesite magma, and then some of these partially resorbed plagioclase crystals were recycled back into the host rhyodacite. Textural evidence, in the form of sieve zones and major dissolution boundaries of the resorbed plagioclase crystals, indicates immersion of crystals into a hotter, more calcic magma. The occurrence of partially resorbed plagioclase together with plagioclase

  10. Volcano-hydrothermal energy research at white Island, New Zealand

    International Nuclear Information System (INIS)

    Allis, R.G.


    This paper presents the White Island (New Zealand) volcano-hydrothermal research project by the N.Z. DSIR and the Geological Survey of Japan, which is investigating the coupling between magmatic and geothermal systems. The first phase of this investigation is a geophysical survey of the crater floor of the andesite volcano, White Island during 1991/1992, to be followed by drilling from the crater floor into the hydrothermal system. (TEC). 4 figs., 8 refs

  11. Crustal-scale degassing due to magma system destabilization and magma-gas decoupling at Soufrière Hills Volcano, Montserrat


    Christopher, TE; Blundy, J; Cashman, K; Cole, P; Edmonds, M; Smith, PJ; Sparks, RSJ; Stinton, A


    © 2015. American Geophysical Union. All Rights Reserved. Activity since 1995 at Soufrière Hills Volcano (SHV), Montserrat has alternated between andesite lava extrusion and quiescence, which are well correlated with seismicity and ground deformation cycles. Large variations in SO 2 flux do not correlate with these alternations, but high and low HCl/SO 2 characterize lava dome extrusion and quiescent periods respectively. Since lava extrusion ceased (February 2010) steady SO 2 emissions have c...

  12. Short time scales of magma-mixing processes prior to the 2011 eruption of Shinmoedake volcano, Kirishima volcanic group, Japan (United States)

    Tomiya, Akihiko; Miyagi, Isoji; Saito, Genji; Geshi, Nobuo


    We estimated time scales of magma-mixing processes just prior to the 2011 sub-Plinian eruptions of Shinmoedake volcano to investigate the mechanisms of the triggering processes of these eruptions. The sequence of these eruptions serves as an ideal example to investigate eruption mechanisms because the available geophysical and petrological observations can be combined for interpretation of magmatic processes. The eruptive products were mainly phenocryst-rich (28 vol%) andesitic pumice (SiO2 57 wt%) with a small amount of more silicic pumice (SiO2 62-63 wt%) and banded pumice. These pumices were formed by mixing of low-temperature mushy silicic magma (dacite) and high-temperature mafic magma (basalt or basaltic andesite). We calculated the time scales on the basis of zoning analysis of magnetite phenocrysts and diffusion calculations, and we compared the derived time scales with those of volcanic inflation/deflation observations. The magnetite data revealed that a significant mixing process (mixing I) occurred 0.4 to 3 days before the eruptions (pre-eruptive mixing) and likely triggered the eruptions. This mixing process was not accompanied by significant crustal deformation, indicating that the process was not accompanied by a significant change in volume of the magma chamber. We propose magmatic overturn or melt accumulation within the magma chamber as a possible process. A subordinate mixing process (mixing II) also occurred only several hours before the eruptions, likely during magma ascent (syn-eruptive mixing). However, we interpret mafic injection to have begun more than several tens of days prior to mixing I, likely occurring with the beginning of the inflation (December 2009). The injection did not instantaneously cause an eruption but could have resulted in stable stratified magma layers to form a hybrid andesitic magma (mobile layer). This hybrid andesite then formed the main eruptive component of the 2011 eruptions of Shinmoedake.



    Edi Yatno; Siti Zauyah


    Soils formed from volcanic materials have a high potential for agricultural development, especially for horticultural crops, tea, and pine trees. Data on the characteristics of these soils are important for the management planning. Six representative soil profiles developed on andesitic volcanic ash and tuff in Lembang area, West Java were studied to determine the soil physical, chemical, and mineralogical properties, to study the relationship between the soil properties, and to classify the ...

  14. Properties and Management Implications of Soils Formed From Volcanic Materials in Lembang Area, West Java


    Yatno, Edi; Zauyah, Siti


    Soils formed from volcanic materials have a high potential for agricultural development, especially for horticultural crops, tea, and pine trees. Data on the characteristics of these soils are important for the management planning. Six representative soil profiles developed on andesitic volcanic ash and tuff in Lembang area, West Java were studied to determine the soil physical, chemical, and mineralogical properties, to study the relationship between the soil properties, and to classify the ...

  15. Cogenetic late Pleistocene rhyolite and cumulate diorites from Augustine Volcano revealed by SIMS 238U-230Th dating of zircon, and implications for silicic magma generation by extraction from mush (United States)

    Coombs, Michelle L.; Vazquez, Jorge A.


    Augustine Volcano, a frequently active andesitic island stratocone, erupted a late Pleistocene rhyolite pumice fall that is temporally linked through zircon geochronology to cumulate dioritic blocks brought to the surface in Augustine's 2006 eruption. Zircon from the rhyolite yield a 238U-230Th age of ∼25 ka for their unpolished rims, and their interiors yield a bimodal age populations at ∼26 ka and a minority at ∼41 ka. Zircon from dioritic blocks, ripped from Augustine's shallow magmatic plumbing system and ejected during the 2006 eruption, have interiors defining a ∼26 ka age population that is indistinguishable from that for the rhyolite; unpolished rims on the dioritic zircon are dominantly younger (≤12 ka) indicating subsequent crystallization. Zircon from rhyolite and diorite overlap in U, Hf, Ti, and REE concentrations although diorites also contain a second population of high-U, high temperature grains. Andesites that brought dioritic blocks to the surface in 2006 contain zircon with young (≤9 ka) rims and a scattering of older ages, but few zircon that crystallized during the 26 ka interval. Both the Pleistocene-age rhyolite and the 2006 dioritic inclusions plot along a whole-rock compositional trend distinct from mid-Holocene–present andesites and dacites, and the diorites, rhyolite, and two early Holocene dacites define linear unmixing trends often oblique to the main andesite array and consistent with melt (rhyolite) extraction from a mush (dacites), leaving behind a cumulate amphibole-bearing residue (diorites). Rare zircon antecrysts up to ∼300 ka from all rock types indicate that a Quaternary center has been present longer than preserved surficial deposits.

  16. The Strengthening of an ASR-Affected Water Intake Tower in a Hydro-Electric Dam by Using Post-tensioned Tendons and the Long-term Monitoring of the Tower


    Torii, Kazuyuki; Sannoh, Chikao; Kanitani, Maki


    In the Hokuriku district in Japan, large numbers of concrete structures have been suffering from damage caused by alkali silica reaction (ASR). Some huge volcanoes are located within this district, and the headwaters of main rivers prompt the outflow and spreading of volcanic rocks such as andesite, rhyolite and tuff stones, which are the main volcanic reactive stones causing the serious damage of ASR in the entire area. To solve this problem effective countermeasures such as repair and stren...

  17. Late Neoproterozoic Nuqara Dokhan Volcanics, Central Eastern Desert, Egypt: Geochemistery and petrogenesis (United States)

    Hassan, Tharwat; Asran, Asran; Amron, Taha; Natflos, Theo


    The Nuqara volcanic is one of the northernmost outcrops of the Arabian-Nubian Shield Dokhan volcanics. The origin and tectonic setting of the late Neoproterozoic Dokhan volcanics (ca. 610-560 Ma) in the Egyptian Eastern Desert is highly debated. The debate concerns the tectonic setting where they formed during transition between convergent to extensional regime or after the East- and the West-Gondwana collision (~600Ma). In order to solve this problem, lavas from Nuqara area were studied geologically and geochemically. Nuqara Dokhan volcanics comprises two main rock suites: (a) an intermediate volcanic suite, consisting of basaltic andesite, andesite and their associated pyroclastics rocks; and (b) a felsic volcanic suite composed of dacite, rhyolite and ignimbrites. The two suites display well-defined major and trace element trends and continuum in composition with wide ranges in SiO2 (52-75.73%), CaO (9.19-0.22%), MgO (5.29-0.05%), Sr (1367-7.4 ppm), Zr (688.5-172.7 ppm), Cr (207-0.4 ppm), and Ni (94.3-0.2 ppm). The Nuqara Dokhan volcanics are characterized by strong enrichment in LILE relative to HFSE and affiliated to the calc-alkaline subducted - related magmatism. Geochemical Modeling displays that the evolution of these rocks was governed by fractional crystallization of plagioclase, amphiboles, pyroxene, magnetite and apatite in the intermediate varieties and plagioclase, amphibole, magnetite, apatite and zircon in the felsic varieties. The obtained mineral chemistry of these volcanics reveals: (a) Plagioclase range in composition from An55 to An40 in basaltic andesite and from An39 to An24 in andesite. (b) Alkali feldspars have sanidine composition. (c) Clinopyroxenes have augite composition. The low Al2O3 contents (1.94-5.588 wt %) indicate that clinopyroxene crystallized at low - pressure conditions. (d) Amphiboles have magnesio- hornblende composition.

  18. Early Cretaceous Surtseyan volcanoes of the Baño Nuevo Volcanic Complex (Aysén Basin, Eastern Central Patagonian Cordillera, Chile)




    Tens of Surtseyan tuff cones are exposed in the Río Coichel valley, between Ñireguao and Estancia Baño Nuevo (Southern Chilean Andes). The Early Cretaceous products of the submarine eruptions rest on, or are interbedded with, shallow marine sandstones of the Hauterivian-early Aptian Apeleg Formation. The Early Cretaceous rocks typically contain large amphibole phenocrysts, clinopyroxene and plagioclase, and have compositions that range from relatively primitive basalts to andesites. The basal...

  19. Volcanic and Tectonic Evolution of The Gulf of California Near Mulege, Baja California Sur: Results From Baja Basins NSF-REU (Research Experience for Undergraduates) (United States)

    Hutchinson, S. J.; Allard, J.; Acuna, N.; Graettinger, A. H.; Busby, C.


    Cenozoic volcanic rocks have been studied along many parts of the Gulf of California margin of Baja California because they provide a record of its volcano-tectonic evolution, from subduction (24-12 Ma), to rifting (820 m thick red bed sequence, sourced to the east by andesitic volcanic rocks eroded from the footwall of a west-dipping normal fault. Proximal alluvial fan bajada deposits are debris-flow dominated, with angular clasts up to 1.3 m in size. Distal braided stream deposits have sandstones and cobble conglomerates, with abundant cut and fill structures and rounded clasts. Adakite trachyandesite block-and-ash-flow tuffs are interstratified with the proximal deposits, representing pyroclastic flows generated by collapse of lava domes plumbed up the basin-bounding fault to the east. (2) The redbeds were cut by a dike swarm that fed a field of lava shield volcanoes. The dikes and lava shields include calcalkaline basaltic andesite, andesite and dacite, as well as magnesian trachyandesite and basaltic andesite. (3) A N-S, subvertical fault stepped into the basin and dropped the lava shields down to the east, while they were eroded off the uplifted footwall to the west. (4) The footwall block was beveled and overlain by plateau-forming magnesian basaltic trachyandesite lavas. Basal clastic sequences in the Baja Gulf of California margin have been inferred to represent Oligocene forearc rocks, with overlying volcanic rocks recording westward sweep of the Miocene arc into the area. However, on the basis of our geochemistry, we infer that all of these rocks record post-subduction (<12 Ma) processes. 1 Acuna et al., this volume

  20. Submarine silicic volcanism: Processes and products

    Digital Repository Service at National Institute of Oceanography (India)

    Kalangutkar, N.G.; Iyer, S.D.

    and these are supported by several experimental studies (Annen et al., 2006). A silicic calc-alkalic magma can form by differentiation from a more mafic parent magma and by crustal anatexis. Several evidences show the origin of some rhyolitic and andesitic magma... to be related due to similar tectonic settings. Fractional crystallisation: This process produces a series of residual liquids of variable compositions as compared to their parental magmas and is best explained by the Bowen’s reaction principle (Bowen, 1922...

  1. Geochemical signatures of tephras from Quaternary Antarctic Peninsula volcanoes


    Kraus,Stefan; Kurbatov,Andrei; Yates,Martin


    In the northern Antarctic Peninsula area, at least 12 Late Plelstocene-Holocene volcanic centers could be potential sources of tephra layers in the region. We present unique geochemical fingerprints for ten of these volcanoes using major, trace, rare earth element, and isotope data from 95 samples of tephra and other eruption products. The volcanoes have predominantly basaltic and basaltic andesitic compositions. The Nb/Y ratio proves useful to distinguish between volcanic centers located on ...

  2. Stratigraphy and AMS radiocarbon dates of cored sediments (IrBH-2) from the Irosin caldera, the Philippines

    International Nuclear Information System (INIS)

    Mirabueno, Ma. Hannah T.; Laguerta, Eduardo P.; Delos Reyes, Perla J.; Bariso, Ericson B.; Torii, Masayuki; Fujiki, Toshiyuki; Okuno, Mitsuru; Nakamura, Toshio; Danhara, Tohru; Saito-Kokubu, Yoko; Kobayashi, Tetsuo


    Core drilling at Site IrBH-2 within the Irosin caldera in Sorsogon Province, southern Luzon reached a depth of 50 m. Systematic logging and documentation were carried out to describe and interpret the sediments. The accelerator mass spectrometer (AMS) radiocarbon dates obtained from plant fragments at 7.02-10.40-m depth were 1000 to 1800 BP. Lahars and fluvial deposits were the predominant deposits in the core sequence. The upper 12 m consisted mostly of andesitic fluvial and minor lahar deposits. These deposits may be correlated with the reworking of eruptive products from resurgent andesitic volcanism. One pyroclastic flow and 12 fallout deposits, including five possible fallout deposits, were intercalated with reworked sediments at depths of 12-50 m. The refractive index of representative samples indicated that post-caldera eruptions involved mainly andesite to dacite, with minor rhyolite magmas. The rhyolite fallout in the core had similar petrographic characteristics to the 41 cal kBP Irosin ignimbrite, suggesting that the fallout and the ignimbrite were sourced from the same magma. (author)

  3. Dating and source determination of volcanic rocks from Khunik area (South of Birjand, South Khorasan using Rb-Sr and Sm-Nd isotopes

    Directory of Open Access Journals (Sweden)

    Somayeh Samiee


    Full Text Available The Khunik area is located in the south of Birjand, Khorasan province, in the eastern margin of Lut block. Tertiary volcanic rocks have andesite to trachy-andesite composition. Dating analyzing by Rb-Sr method on plagioclase and hornblende as well as whole-rock isochron method was performed on pyroxene-hornblende andesite rock unit. On this basis the emplacement age is Upper Paleocene (58±11 Ma. These rocks have initial 87Sr/86Sr and εNd 0.7046-0.7049 and 2.16-3.12, respectively. According to isotopic data, volcanic rocks originated from depleted mantle and have the least crust contamination while it was fractionated. Geochemically, Khunik volcanic rocks have features typical of calk-alkaline to shoshonite and are metaluminous. Enrichment in LILEs and typical negative anomalies of Nb and Ti are evidences that the volcanic rocks formed in a subduction zone and active continental margin. Modeling suggests that these rocks were derived dominantly from 1–5% partial melting of a mainly spinel garnet lherzolite mantle source that is metasomatized by slab-derived fluid.

  4. Synergetic use of lignite fly ash and metallurgical converter slag in geopolymer concrete

    Directory of Open Access Journals (Sweden)

    Gábor Mucsi


    Full Text Available The application and utilization of the industrial wastes and by-products in the construction industry is a key issue from an environmental and economic point of view. The increased use of lignite has substantially increased the available quantities of lignite fired power plant fly ash, which can be mainly classified as class C fly ash. The utilization of such raw material however has some difficulties. In the present paper lignite fired power station fly ash and metallurgical converter slag were used for the production of geopolymer concrete. The fly ash was used as a geopolymer based binder material, and a converter slag as aggregate, thus created a geopolymer concrete which contains mainly industrial wastes. As preliminary test experimental series were carried out using andesite as aggregate. The optimal aggregate/binder ratio was determined. The effect of the amount of alkaline activator solution in the binder, the aggregate type on the geopolymer concretes’ compressive strength and density was investigated. Furthermore, the physical properties - freeze-thaw resistance and particle size distribution - of the applied aggregates were measured as well. As a result of the experiments it was found that physical properties of the andesite and converter slag aggregate was close. Therefore andesite can be replaced by converter slag in the concrete mixture. Additionally, geopolymer concrete with nearly 20 MPa compressive strength was produced from class C fly ash and converter slag.

  5. Mineral alteration of two different bed rocks and soil derived from them in Lahijan

    International Nuclear Information System (INIS)

    Pourmasoumi Parashkooh, M.; Ramezanpour, H.


    Microscopical studies were carried out, in addition to physico-chemical and mineralogical analysis, in order to evaluate the effect of parent material and weathering on soil genesis in forest regions of Lahijan. Two representative soil pedons in mountain landform developed on granite and andesitic basalt located about 8 km southeast of Lahijan were selected and sampling were taken from each horizon by Kubiena boxes or clod. Mineral and their weathering were studied by a polarized microscope under plain and cross light and comparison was made with total elemental analysis by X-ray fluorescence and X-ray analysis (XRD). All evidences showed that there is a close structural relationship between the host mineral and the weathering products. Microscopic observation of soils and weathered rock derived from granite showed evidence of the alteration of feldspars to sericite and chlorite under hydrothermal condition and clay minerals under soil condition. In soils and weathered rock derived from andesitic basalt, alteration of plagioclase (labradorite) and olivine to chlorite and clay minerals as well as pyroxene to amphibole were dominant process. Moreover, higher depth of soil under andesitic basalt with comparison to granite was the morphological evidence of intense weathering effects of humid condition in the study area for different minerals.

  6. Sr, Nd and Pb isotope and geochemical data from the Quaternary Nevado de Toluca volcano, a source of recent adakitic magmatism, and the Tenango Volcanic Field, Mexico (United States)

    Martínez-Serrano, Raymundo G.; Schaaf, Peter; Solís-Pichardo, Gabriela; Hernández-Bernal, Ma. del Sol; Hernández-Treviño, Teodoro; Julio Morales-Contreras, Juan; Macías, José Luis


    Volcanic activity at Nevado de Toluca (NT) volcano began 2.6 Ma ago with the emission of andesitic lavas, but over the past 40 ka, eruptions have produced mainly lava flows and pyroclastic deposits of predominantly orthopyroxene-hornblende dacitic composition. In the nearby Tenango Volcanic Field (TVF) pyroclastic products and lava flows ranging in composition from basaltic andesite to andesite were erupted at most of 40 monogenetic volcanic centers and were coeval with the last stages of NT. All volcanic rocks in the study area are characterized by a calc-alkaline affinity that is consistent with a subduction setting. Relatively high concentrations of Sr (>460 ppm) coupled with low Y (45 km) that underlies the volcanoes of the study area, the geochemical and isotopic patterns of these rocks indicate low interaction with this crust. NT volcano was constructed at the intersection of three fault systems, and it seems that the Plio-Quaternary E-W system played an important role in the ascent and storage of magmas during the recent volcanic activity in the two regions. Chemical and textural features of orthopyroxene, amphibole and Fe-Ti oxides from NT suggest that crystallization of magmas occurred at polybaric conditions, confirming the rapid upwelling of magmas.

  7. Audio-magnetotelluric (AMT) study to investigate the genesis of Mujil hill (United States)

    Rahmania, Suryanto, Wiwit


    Gunung Mujil is an isolated hill located near Pondoworejo village, Kalibawang sub-district, Kulon Progo district, and Special Province of Yogyakarta. The hill is part of the eastern Kulon Progo mountain range extended relatively in the North-South direction. The lithology of the hill consists of andesite breccia and it's similar with the Old Andesite Formation that built the Kulon Progo Mountains. There are at least two hypothesis about the genesis and the formation mechanism of this hill, (1) it was formed by debris mass from Kulon Progo Mountains, and (2) ) it was formed by an intrusion. Our study intended to determine the subsurface resistivity below the hill and to relating those results to with the scenario of the genesis of the Mujil hill. We conducted Audio-magnetotellurics (AMT) measurements along two lines survey crossing the Mujil hill consisting of 20 measurements. Since the measurements are located near the villages, most of the data has a fair to bad quality and only one station yielded an excellent data. A 1D Forward modeling was then applied to find best-fit model of the AMT data. The results shows that the Mujil hill was built by debris mass of the Old Andesite Formation from Kulon Progo mountain which is represented by a lower resistivity value under the Mujil hill.

  8. Waste disposal mapping with electrical resistivity tomography case: Leuwigajah landfill (United States)

    Aryanti, Erisha; Ardi, Ahmad Puji; Almunziri, Muaz; Xanggam, Zael Yahd; Eleazar, Adino; Widodo


    Leuwigajah landfill as administrative is located between district of Bandung and Cimahi citythat has an environmental and social problem that caused aquifer contamination due to the big amount of waste from Bandung city, Cimahi and Bandung regency. It is occupied in abandoned andesite mine site with an area of about 25 hectare. The aim of this research is to map the geology structure and to study the leachate towards aquifer layer below Leuwigajah landfill. Here, we present the study of Leuwigajah landfill subsurface using Electrical Resistivity Tomography (ERT). ERT is one of the most promising prospecting techniques mainly concerning its effective contribution to resolve several environmental problems, was applied for the geophysical modeling. ERT is a robust imaging method the theory and implementation of which are well documented in geophysical research literature. The geological setting comprises clayed weathered layer, fractured andesitic dike. Due to the above-mentioned geological singularity and in the light of the requirement for an environmentally safe construction of the landfill, an ERT survey was carried out with dipole-dipole array, 78 m of acquisition line and 6 m of electrode spacing. The model consists of 4 layers below the Leuwigajah landfill and andesitic fracture until depth of 18.7 m below the surface.

  9. K-Ar ages of the Hiruzen volcano group and the Daisen volcano

    International Nuclear Information System (INIS)

    Tsukui, Masashi; Nishido, Hirotsugu; Nagao, Keisuke.


    Seventeen volcanic rocks of the Hiruzen volcano group and the Daisen volcano, in southwest Japan, were dated by the K-Ar method to clarify the age of volcanic activity in this region and the evolution of these composite volcanoes. The eruption ages of the Hiruzen volcano group were revealed to be about 0.9 Ma to 0.5 Ma, those of the Daisen volcano to be about 1 Ma to very recent. These results are consistent with geological and paleomagnetic data of previous workers. Effusion of lavas in the area was especially vigorous at 0.5+-0.1 Ma. It was generally considered that the Hiruzen volcano group had erupted during latest Pliocene to early Quaternary and it is older than the Daisen volcano, mainly from their topographic features. However, their overlapping eruption ages and petrographical similarities of the lavas of the Hiruzen volcano group and the Daisen volcano suggest that they may be included in the Daisen volcano in a broad sense. The aphyric andesite, whose eruption age had been correlated to Wakurayama andesite (6.34+-0.19 Ma) in Matsue city and thought to be the basement of the Daisen volcano, was dated to be 0.46+-0.04 Ma. It indicates that petrographically similar aphyric andesite erupted sporadically at different time and space in the San'in district. (author)

  10. The crust role at Paramillos Altos intrusive belt: Sr and Pb isotope evidence

    International Nuclear Information System (INIS)

    Ostera, H.A.; Linares, E; Haller, M.J; Cagnoni, M.C


    Paramillos Altos Intrusive Belt (PAIB) (Ostera, 1996) is located in the thick skinned folded-thrust belt of Malargue, southwestern Mendoza, Argentina. Geochemical, geochronologic and isotopic studies were carried out in it (Ostera 1996, 1997, Ostera et al. 1999; Ostera et al. 2000) and these previous papers suggested a minor involvement of the crust in the genesis of the PAIB. According with Ostera et al. (2000) it is composed by stocks, laccoliths, dykes and sills which range in composition from diorites to granodiorites, and from andesites to rhyolites, and divided in five Members, which range in age from Middle Miocene to Early Miocene: a- Calle del Yeso Dyke Complex (CYDC), with sills and dykes of andesitic composition (age: 20±2 Ma). b- Puchenque-Atravesadas Intrusive Complex (PAIC), composed by dykes and stocks ranging from diorites to granodiorites (age: 12.5±1 Ma). c- Arroyo Serrucho Stock (SAS), an epizonal and zoned stock, with four facies, with K/Ar and Ar/Ar dates of 10±1 and 9.5±0.5 Ma. d- Portezuelo de los Cerros Bayos (PCB), that includes porphyritic rocks of rhyolitic composition, of 7.5±0.5 Ma. e- Cerro Bayo Vitrophyres (CBV), with andesitic sills and dykes (age: 4.8±0.2 Ma). We present in this paper new Sr and Pb isotopes data that constrain the evolution of the PAIB (au)

  11. Genesis of lavas of the Taupo Volcanic Zone, North Island, New Zealand (United States)

    Cole, J. W.


    The Taupo Volcanic Zone forms part of the Taupo-Hikurangi subduction system, and comprises five volcanic centres: Tongariro, Taupo, Maroa, Okataina and Rotorua. Tongariro Volcanic Centre is formed almost entirely of andesite while the other four centres contain predominantly rhyolitic volcanics and later fissure eruptions of high-Al basalt. Estimated total volume of each lava type are as follows: 2 km 3 of high-Al basalt ( 10,000 km 3 of rhyolite and ignimbrite ( > 97.4%). The location of the andesites and vent alignments suggest a source from a subduction zone underlying the area. However, the lavas differ chemically from island-arc andesites such as those of Tonga; in particular by having higher contents of the alkali elements, light REE and Sr and Pb isotopes. This suggests some crustal contamination, and it is considered that this may occur beneath the wide accretionary prism of the subduction system. Amphibolite of the subduction zone will break down between 80 and 100 km and a partial melt will rise. A multi-stage process of magma genesis is then likely to occur. High-Al basalts are thought to be derived from partial melting of a garnet-free peridotite near the top of the mantle wedge overlying the subduction zone, locations of the vents controlled largely by faults within the crust. Rhyolites and ignimbrites were probably derived from partial melting of Mesozoic greywacke and argillite under the Taupo Volcanic Zone. Initial partial melting may have been due to hydration of the base of the crust; the "water" having come from dehydration of the downgoing slab. The partial melts would rise to form granodiorite plutons and final release of the magma to form rhyolites and ignimbrites was allowed because of extension within the Taupo graben. Dacites of the Bay of Plenty probably resulted from mixing of andesitic magma with small amounts of rhyolitic magma, but those on the eastern side of the Rotorua-Taupo area were more likely formed by a higher degree of partial

  12. Sr and Nd isotopic and trace element compositions of Quaternary volcanic centers of the Southern Andes (United States)

    Futa, K.; Stern, C.R.


    Isotopic compositions of samples from six Quaternary volcanoes located in the northern and southern extremities of the Southern Volcanic Zone (SVZ, 33-46??S) of the Andes and from four centers in the Austral Volcanic Zone (AVZ, 49-54??S) range for 87Sr 86Sr from 0.70280 to 0.70591 and for 143Nd 144Nd from 0.51314 to 0.51255. The ranges are significantly greater than previously reported from the southern Andes but are different from the isotopic compositions of volcanoes in the central and northern Andes. Basalts and basaltic andesites from three centers just north of the Chile Rise-Trench triple junction have 87Sr 86Sr, 143Nd 144Nd, La Yb, Ba La, and Hf Lu that lie within the relatively restricted ranges of the basic magmas erupted from the volcanic centers as far north as 35??S in the SVZ of the Andes. The trace element and Sr and Nd isotopic characteristics of these magmas may be explained by source region contamination of subarc asthenosphere, with contaminants derived from subducted pelagic sediments and seawater-altered basalts by dehydration of subducted oceanic lithosphere. In the northern extremity of the SVZ between 33?? and 34??S, basaltic andesites and andesites have higher 87Sr 86Sr, Rb Cs, and Hf Lu, and lower 143Nd 144Nd than basalts and basaltic andesites erupted farther south in the SVZ, which suggests involvement of components derived from the continental crust. In the AVZ, the most primitive sample, high-Mg andesite from the southernmost volcanic center in the Andes (54??S) has Sr and Nd isotopic compositions and K Rb and Ba La similar to MORB. The high La Yb of this sample suggests formation by small degrees of partial melting of subducted MORB with garnet as a residue. Samples from centers farther north in the AVZ show a regionally regular northward increase in SiO2, K2O, Rb, Ba, Ba La, and 87Sr 86Sr and decrease in MgO, Sr, K Rb, Rb Cs, and 143Nd 144Nd, suggesting increasingly greater degrees of fractional crystallization and associated intra

  13. Lateral and Vertical Vent Migration at Tecuitlapa Maar, Mexico (United States)

    Ort, M. H.; Carrasco-Nunez, G.


    Tecuitlapa maar, in the Serdan-Oriental Basin, east-central Mexico, is 1.5 km diameter and 100 m deep. Reworked ash and lapilli (`toba cafe'), derived from surrounding volcanic highlands via eolian and fluvial processes, provided fluidized water-saturated sediment for fuel-coolant interactions. The eruption sequence begins with 1.5 2-m bedded tuff comprising 50% clast-supported accretionary-lapilli beds and 50% lapilli tuff of juvenile (basalt) and andesite lapilli in a mostly toba-cafe matrix. This grades into a lithic-rich breccia near the vent (east end of maar at this stage). Weakly bedded wet surge deposits complete unit I. Unit I is the finest of the sequence but has poor sorting and variable median grain size. Basaltic juvenile grains dominate (50-80%) and andesite and oxidized grains are subordinate. Unit II deposits are dune-bedded tuffs and 10-20-cm-thick basalt lapilli beds, with abundant lithic lapilli and bomb sags. Breccia beds coarsen (to 1-25 cm diam.), thicken (to 1-2 m), and become more lithic-rich (to 40%) upward, but tuff beds dominate. Matrices are mostly toba cafe ash. Average grain size of the matrix (-2 - -3 phi) coarsens in unit II and sorting improves. Andesitic and oxidized accidental lapilli increase upward, to 50%. Unit III is similar to unit II, but is less regularly bedded and is dominated by tuff breccias. 3-5-m sections alternate between more breccia-like and more tuff-like, but all are mixed in texture. 1-3-cm-thick accretionary lapilli beds are common. Unit III has the coarsest median grain size (-3 phi), slightly better sorting than lower units and components are similar to unit II. Unit IV is many 20-50-cm-thick open-framework basalt lapilli-breccia beds. The uppermost 2-3 m contain a few thin tuffs. Unit IV scoria resemble those at the cinder/spatter cones on the crater floor. Juvenile scoria dominate, but andesitic fine lapilli are 15-40% in the tuff layers. Tecuitlapa erupted from an E-W dike system. Facies analysis and

  14. New constraints on the subsurface geology of the Mexico City Basin: The San Lorenzo Tezonco deep well, on the basis of 40Ar/39Ar geochronology and whole-rock chemistry (United States)

    Arce, J. L.; Layer, P. W.; Morales-Casique, E.; Benowitz, J. A.; Rangel, E.; Escolero, O.


    The San Lorenzo Tezonco deep well, drilled in 2012 by "Sistema de Aguas de la Ciudad de México" (Water Supply System of Mexico City) in the Mexico Basin to a depth of 2008 m, offers an excellent opportunity to explore the subsurface stratigraphy and general geology of the region. Unfortunately, only chipped samples from this well were recovered, which were examined and analyzed for whole-rock chemistry, 40Ar/39Ar, and U-Pb zircon geochronology, in order to reconstruct the lithology of the well. Contrary to previous deep wells of the Mexico Basin, no basement sedimentary rocks were found in this one. While the upper 70 m are composed of lacustrine sediments associated with Lake Texcoco, volcanic rocks make up the majority of the well and range in age from more than 18 Ma to 0.25 Ma. Andesitic lavas are the most abundant products of the stratigraphic column, followed by acidic products represented by dacitic and rhyolitic lavas and ignimbrite deposits. Less abundant are basaltic andesite lavas appearing in the upper and lower parts of the column. The thickest sequence of the well is represented not only by Miocene volcanic rocks ranging from 5 to 17 Ma, suggesting a period of intense volcanic activity in this area producing mainly andesitic lavas, but also by thick rhyolitic ignimbrite deposits dated at 5 Ma. These deposits suggest the presence of a caldera structure, probably buried by subsequent volcanic products and lacustrine sediments. Trace element concentrations suggest that volcanism is likely produced in a subduction environment with typical negative anomalies of Nb, Ta, Ti, and P and positive anomalies in Pb and Cs. We correlated the well units with units outcropping in mountain ranges in the surrounding area, with the recognition of the following units or formations: Eocene Andesite, San Nicolás Basaltic Andesite, Tepoztlán Formation, Miocene Volcanism, Sierra de las Cruces, and Chichinautzin Volcanic Field products. By correlating the two closest deep

  15. The `Strawberry Volcanic Field' of Northeastern Oregon: Another Piece of the CRB Puzzle? (United States)

    Steiner, A. R.; Streck, M. J.


    The Mid to Late Miocene Strawberry Volcanics field (SVF) located along the southern margin of the John Day valley of NE Oregon, comprise a diverse group of volcanic rocks ranging from basalt to rhyolite. The main outcrop area of the SVF (3,400 km2) is bordered by units from the Columbia River Basalt Group (CRBG), with the main CRB units to the north, the Picture Gorge Basalt to the east and Steens Basalt to the south. The geographic position and age of the Strawberry Volcanics make a genetic relationship to CRB volcanism likely, yet little is known about this diverse volcanic field. This research aims at refining the stratigraphic and age relationships as well as the petrology and geochemistry of magmas associated with the SVF. Previous investigations (e.g. Robyn, 1977) found that the SVF was active between 20 to 10 Ma with the main pulse largely being coeval with the 15 Ma CRBG eruptions. Lavas and tuffs from the SVF are calc-alkaline with low FeO*/MgO (~ 2.56 wt. %), high Al2O3 (~ 16.4 wt. %), low TiO2 (~ 1.12 wt.%), and span the entire compositional range from basalt to rhyolite (47-78 wt. % SiO2) with andesite as the dominant lithology. Basaltic lavas from the SVF have compositional affinities to earlier Steens Basalt, and some trace element concentrations and ratios are indistinguishable from those of CRBG lavas (e.g. Zr, Ba, Sr, and Ce/Y). Andesites are calc-alkaline, but contrary to typical arc (orogenic) andesites, SVF andesites are exceedingly phenocryst poor (Strawberry Volcanics are largely the product of hot-spot related basaltic magmas interacting with the continental crust. The range in compositions from calc-alkaline andesite to rhyolite may be attributed to the hybridization of mantle-derived and crustal melts, with the more evolved compositions reflecting greater proportions of crustally derived material and/or higher degrees of differentiation. Furthermore, since the earliest SVF eruption is 3 Ma older than the proposed onset of the CRBG (~ 17 Ma

  16. Petrology of the zoned calcalkaline magma chamber of Mount Mazama, Crater Lake, Oregon (United States)

    Druitt, T.H.; Bacon, C.R.


    Evolution of the magma chamber at Mount Mazama involved repeated recharge by two types of andesite (high-Sr and low-Sr), crystal fractionation, crystal accumulation, assimilation, and magma mixing (Bacon and Druitt 1988). This paper addresses the modal compositions, textures, mineral chemistry and magmatic temperatures of (i) products of the 6845??50 BP climactic eruption, (ii) blocks of partially fused granitoid wallrock found in the ejecta, and (iii) preclimactic rhyodacitic lavas leaked from the chamber in late Pleistocene and early Holocene time. Immediately prior to the climactic eruption the chamber contained ??? 40 km3 of rhyodacite (10 vol% plag + opx + aug + hb + mt + ilm, ???880?? C) overlying high-Sr andesite and cumulus-crystal mush (28-51 vol% plag + hb ?? opx ?? aug + mt ?? ilm, 880?? to ???950?? C), which in turn overlay low-Sr crystal mush (50-66 vol% plag + opx + aug ?? hb ?? ol + mt + ilm, 890?? to ???950??? C). Despite the well known compositional gap in the ejecta, no thermal discontinuity existed in the chamber. Pre-eruptive water contents of pore liquids in most high-Sr and low-Sr mushes were 4-6 wt%, but on average the high-Sr mushes were slightly richer in water. Although parental magmas of the crystal mushes were andesitic, xenocrysts of bytownite and Ni-rich magnesian olivine in some scoriae record the one-time injection of basalt into the chamber. Textures in ol-bearing scoriae preserve evidence for the reactions ol + liq = opx and ol + aug + liq(+ plag?) = hb, which occurred in andesitic liquids at Mount Mazama. Strontium abundances in plagioclase phenocrysts constrain the petrogenesis of preclimactic and climactic rhyodacites. Phenocryst cores derived from high-Sr and low-Sr magmas have different Sr contents which can be resolved by microprobe. Partition coefficients for plagioclase in andesitic to rhyolitic glasses range from 2 to 7, and increase as glass %SiO2 increases. Evolved Pleistocene rhyodacites (???30-25,000 BP) and

  17. New insights into the origin of the felsic volcanic rocks in the middle Okinawa Trough (United States)

    Zhang, Y.; Zeng, Z.


    The Okinawa Trough (OT) is a nascent back arc basin developing in the eastern margin of the Eurasian Plate. The middle segment of the OT (MOT) is featured by bimodal volcanism with dominant basalts and rhyolites and scarce intermediate volcanic rocks. The MOT rhyolites are divided into two types: type 1 rhyolites have lower heavy rare earth element (HREE) contents while type 2 rhyolites feature higher HREE contents and have slightly more enriched Sr-Nd isotopic ratios than type 1 rhyolites. The MOT rhyolites share similar Sr-Nd isotopic compositions with the MOT basalts and thus they have been typically considered as products of crystallization differentiation of basaltic magma. However, the evidence is insufficient. This paper compared chemical trends of volcanic rocks from the MOT with fractional crystallization simulation models and experimental results and utilized trace element modeling (e.g., Th vs. Rb, Rb/Nd vs. Rb, Rb vs. Rb/V, 1/V vs. Rb/V) combined with quantitative calculations to re-examine the magmatic processes in generating the rhyolites. The trace element discriminant models show that the andesites indicate a fractional crystallization trend, type 1 rhyolites present a partial melting trend, and type 2 rhyolites define a mixing trend. Further, by establishing Rayleigh fractionation and batch melting models, we found that the andesites originated by fractional crystallization of basaltic magma while the rhyolites were the products of remelting of andesites. Type 2 rhyolites have higher Dy/Yb and Nb/Ta ratios than type 1 rhyolites, implying that the former might be influenced by a greater contribution of amphibole. Quantitative models suggest that type 1 rhyolites could have formed via the remelting of andesites when amphiboles remain in the source, whereas type 2 rhyolites could have formed without residual amphiboles. Quasi-linear correlations between some major oxides, trace element ratios and Sr-Nd isotopic ratios for type 2 rhyolites suggest that

  18. A Strongly Calc-alkaline Suite in the Midst of the Tholeiitic Columbia River Basalt Province: Implications for Generating the Calc-alkaline Trend Without Subduction Processes (United States)

    Steiner, A. R.; Streck, M. J.


    The mid-Miocene lavas of the Strawberry Volcanics (SV), distributed over 3,400 km2 in NE Oregon, comprise a diverse volcanic suite, which span the range of compositions from basalt to rhyolite. The volcanic suite is mainly composed of calc-alkaline (CA) basaltic andesite and andesite, yet tholeiitic (TH) lavas of basalt to andesite occur as well. The SV lies in the heart of nearly coeval flood basalts of the Columbia River province of the Pacific Northwest. The unique combination of strongly CA rocks of the SV in a non-subduction setting provide an excellent opportunity to study controls on inducing CA evolution in the midst of a TH province and independent of processes taking places at an active subduction zone. New 40Ar/39Ar ages indicate CA basaltic andesites to andesites of the SV erupted at least from 14.78±0.13 Ma to 12.44±0.12 Ma demonstrating that CA magmatism of the SV was ongoing during the eruptions of the tholeiitic Wanapum Basalt member of the Columbia River Basalt Group (CRBG). This range will likely be extended to even older ages in the future because existent age dates did not include samples from near the base of the SV. Thickness of intermediate lavas flows of the SV range from 15 m to as thin as 2 m and lavas are characterized by mostly phenocryst poor lithologies. When phenocrysts are abundant they are very small suggesting growth late during eruption. Single lava flow sections can include on the order of 30 conformable flows, testifying to a vigorous eruption history. The thickest andesitic sections are located in the glacially carved mountains of the Strawberry Mountain Wilderness (i.e. Strawberry Mountain, High Lake, and Slide Lake) where several vent complexes are exposed, which are delineated by dikes and plugs with finely interlocking plutonic textures, cross-cutting SV lava flows. Dikes generally strike NW-SE. Subtle variations in major and trace element compositions exist between TH and CA lavas of the SV. The CA lavas of the SV are

  19. Timing of Magma Mixing Prior to the 2011 Eruption of Shinmoedake, Japan: On the Relationship Between Magma Injection, Magma Mixing, and Eruption Triggering (United States)

    Tomiya, A.; Miyagi, I.; Saito, G.; Geshi, N.


    Various petrological evidences indicate magma mixing often preceded volcanic eruptions. Magma injection into the associated magma chambers also often occurs prior to eruptions as evidenced by inflation of a volcanic edifice. However, the relationship between magma injection, magma mixing, and eruption triggering is unclear because injection does not necessarily cause instantaneous mixing if the injected magma is sufficiently denser than the pre-existing magma and has formed stable stratified layers. To investigate the relationship, we estimated the timing of magma mixing prior to the 2011 sub-Plinian eruptions of Shinmoedake volcano, Kirishima volcanic group, Japan, on the basis of chemical zoning observed in magnetite phenocrysts and numerical diffusion modeling. We compared the timing with that of volcanic inflation/deflation processes. The eruptive products are comprised mainly of phenocryst-rich (28 vol%) gray pumice (SiO2 = 57 wt%) with minor amount of white pumice (SiO2 = 62 wt%). We recognized two magmatic end members, low-T dacitic magma and high-T mafic magma (basalt or basaltic andesite), and hybrid andesitic magma on the basis of our petrologic studies. Gray pumice is comprised mainly of the hybrid andesitic magma. White pumice is comprised mainly of the low-T dacitic magma with mixing of small volume of the hybrid andesitic magma. Most of the magnetite phenocrysts (type-A1) were crystallized in the hybrid andesitic magma. Their zoning profiles showed considerable increase in Mg and Al contents toward the rims of the phenocrysts, due to mixing with the high-T mafic magma. We calculated the time for diffusion to form these zoning profiles to be only 0.4 to 3 days. The short time scale suggests that the mixing of high-T magma triggered the sub-Plinian eruptions. This mixing process was not accompanied by a significant change in the volume of the magma chamber because no significant crustal deformation was observed several days prior to the eruptions (Japan

  20. The compositionally zoned eruption of 1912 in the Valley of Ten Thousand Smokes, Katmai National Park, Alaska (United States)

    Hildreth, W.


    On June 6-8, 1912, ??? 15 km3 of magma erupted from the Novarupta caldera at the head of the Valley of Ten Thousand Smokes (VTTS), producing ??? 20 km3 of air-fall tephra and 11-15 km3 of ash-flow tuff within ??? 60 hours. Three discrete periods of ash-fall at Kodiak correlate, respectively, with Plinian tephra layers designated A, CD, and FG by Curtis (1968) in the VTTS. The ash-flow sequence overlapped with but outlasted pumice fall A, terminating within 20 hours of the initial outbreak and prior to pumice fall C. Layers E and H consist mostly of vitric dust that settled during lulls, and Layer B is the feather edge of the ash flow. The fall units filled and obscured the caldera, but arcuate and radial fissures outline a 6-km2 depression. The Novarupta lava dome and its ejecta ring were emplaced later within the depression. At Mt. Katmai, 10 km east of the 1912 vent, a 600-m-deep caldera of similar area also collapsed at about this time, probably owing to hydraulic connection with the venting magma system; but all known ejecta are thought to have erupted at Novarupta. Mingling of three distinctive magmas during the eruption produced an abundance of banded pumice, and mechanical mixing of chilled ejecta resulted in deposits with a wide range of bulk composition. Pumice in the initial fall unit (A) is 100% rhyolite, but fall units atop the ash flow are > 98% dacite; black andesitic scoria is common only in the ash flows and in near-vent air-fall tephra. Pumice counts show the first half of the ash-flow deposit to be 91-98% rhyolite, but progressive increases of dacite and andesite eventually reduced the rhyolitic component to 20 km to the lowermost VTTS, and deposited 1-8 m of debris there. Rhyolitic ejecta contain only 1-2% phenocrysts but andesite and dacite have 30-45%. Quartz is present and augite absent only in the rhyolite, but all ejecta contain plagioclase, orthopyroxene, titanomagnetite, ilmenite, apatite, and pyrrhotite; rare olivine occurs in the

  1. Young Rhyolitic and Alkaline Volcanism of the Ecuadorian Arc - A Result of the Carnegie Ridge Subduction? (United States)

    Hall, M. L.; Mothes, P. A.


    The subduction of aseismic submarine ridges under continental arcs generally results in the cessation of volcanic activity (Wilson, 1989). The rapidly-subducting (6 cm/yr) Carnegie Ridge under Ecuador, however, is associated with increased and diverse volcanism. The Northern Volcanic Zone in Colombia is a single row of volcanoes, but in Ecuador it is characterized by a high density of Pleistocene and active centers distributed in four parallel bands perpendicular to the convergence axis. Here the NVZ is higher in elevation (3-6 km high) and wider (ca. 140 km) than elsewhere. Ecuador’s volcanic arc has its volcanic front in the western cordillera where it is characterized by on-going dacitic, Si-rich andesitic, and adakitic-like volcanism. Eastwards, in the InterAndean Depression the volcanoes are older and andesitic. In the adjacent eastern cordillera the active volcanoes are normal 2-pyroxene andesites. However, co-existing with this andesite chain is a province of young rhyolitic volcanism (Hall & Mothes, 2001) which ranges in age from 2.7 Ma to historic times. In addition, immediately east of the rhyolitic province in a back-arc setting occurs a small group of alkaline volcanoes with feldspathoid-bearing basanites and tephrites. The rhyolite province extends 130 km southwards from the 50 km-long Chacana caldera complex (800 km3 of flow deposits) to early Holocene pumice flows recently identified at Pisayambo. Between these extremes are found the 20 km-wide Chalupas caldera and associated Late Pleistocene silicic centers and domes. The discovery of young rhyolitic centers at the eastern foot of the Andes (Aliso) extends the province 40 km eastwards. A flare-up of rhyolitic activity began at 200 ka with the 100 km3 Chalupas pumice flow, the coeval rhyolite flows from Chacana caldera, and a 11 km3 andesitic lava flow from nearby Antisana volcano. At 170-180 ka the northern sector of Chacana witnessed rhyolitic lava flows and extensive pumice lapilli falls whose

  2. Miocene magmatism and tectonics within the Peri-Alboran orogen (western Mediterranean) (United States)

    El Azzouzi, M.; Bellon, H.; Coutelle, A.; Réhault, J.-P.


    The aim of this paper concerns Miocene igneous activity in the Alboran Sea and Peri-Alboran area (northern Morocco, western Algeria and Betic Cordilleras in Spain), considering its age and its location with regard to major tectonics structures. We have compiled previous K-Ar isotopic ages of lavas and plutonic boulders and intrusives with an error of ±1σ and completed this set by a new K-Ar isotopic age for andesitic tuffites from Alboran Island. Geochemistry of most of these samples has been considered after previous analyses completed with new data for Spain magmatism. These two sets of data allow us to place the magmatic activity within the regional stratigraphy and tectonics and their chronological framework of the three major tectonic phases of the Maghrebian orogen, at 17 Ma (Burdigalian), 15 Ma (Langhian) and 9 Ma (Tortonian). Petro-geochemical characteristics are compared through time and geographical locations. A major goal of this coupled approach is to help the elaboration of possible geodynamical processes. As an application, we present the case study of the Dellys, Djinet and Thenia region (east of Algiers) where the successive magmatic events between 19.4 ± 1 and 11.6 ± 0.5 Ma are closely related to the local tectonics and sedimentation. The Peri-Alboran igneous activity is placed in a multidisciplinary framework. Timing of activity is defined according to the ages of the neighbouring sedimentary units and the K-Ar ages of igneous rocks. In Spain, the Cabo de Gata-Carboneras magmatic province displays late Oligocene and early Miocene leucogranitic dikes, dated from 24.8 ± 1.3 to 18.1 ± 1.2 Ma; three following andesitic to rhyolitic events took place around 15.1 ± 0.8 to 14.0 ± 0.7 Ma, 11.8 ± 0.6 to 9.4 ± 0.4 Ma, 8.8 ± 0.4 to 7.9 ± 0.4 Ma; this last event displays also granitic rocks. Lamproitic magmas dated between 8.4 ± 0.4 and 6.76 ± 0.04 Ma were emplaced after the Tortonian phase. In Morocco, after the complex building of the Ras Tarf

  3. Preliminary Findings of Petrology and Geochemistry of The Aladaǧ Volcanic System and Surrounding Areas (Kars, Turkey) (United States)

    Duru, Olgun; Keskin, Mehmet


    Between the towns of Sarıkamış and Kaǧızman, NE Turkey, a medium-sized strato-volcano with satellite cones and domes on its slopes unconformably overlies the Erzurum-Kars Volcanic Plateau (EKVP) with a subhorizontal contact. It is called the Aladaǧ volcanic system (AVS). Dating results indicate that the AVS is Pliocene in age. The EKVP is known to be formed by a widespread volcanism between Middle Miocene to Pliocene. The young volcanism in E Turkey including the study area is linked to a collision between the Eurasia and Arabian continents, started almost 15 Ma ago. The EKVP lies over 2000 m above the sea level, and is deeply cut by the river Aras. On the slopes of the valley, one of the best volcano-stratigraphic transects of Eastern Anatolia, almost half a km thick, is exposed. That transect is composed of aphyric andesites-dacites, ignimbrites, tuffs, perlite and obsidian bands. Pyroclastic fall and surge-related pumice deposits are also widespread. Top of the plateau is composed of the andesitic to basaltic andesitic lavas containing plagioclase (Plg) and ortho/clino pyroxene (Opx/Cpx) phenocrysts set in glassy groundmass. In the northwest of the study area, an eroded stratovolcano, probably coeval with the plateau sequence is situated. It also consists of high-silica rhyolites and pyroclastic equivalents. The AVS is composed basically of intermediate lavas. The largest volcanic edifice of the Aladaǧ volcanic system, namely the Greater Aladaǧ stratovolcano reaches up to 3000 m height and includes a horseshoe shaped crater open to the North. Small volcanic cones and domes sit on the flanks of the Greater Aladaǧ volcano. The Aladaǧ lavas are divided into four sub-groups on the basis of their stratigraphic positions, mineral assemblages and textural properties. (1) The oldest products of the Greater Aladaǧ stratovolcano are andesitic and dasitic lavas. They directly sit on the EKVP. These are Plg and Opx/Cpx bearing lavas with porphric, vitrophyric

  4. The crustal magma storage system of Volcán Quizapu, Chile, and the effects of magma mixing on magma diversity (United States)

    Bergantz, George W.; Cooper, Kari M.; Hildreth, Edward; Ruprecht, Phillipp


    Crystal zoning as well as temperature and pressure estimates from phenocryst phase equilibria are used to constrain the architecture of the intermediate-sized magmatic system (some tens of km3) of Volcán Quizapu, Chile, and to document the textural and compositional effects of magma mixing. In contrast to most arc magma systems, where multiple episodes of open-system behavior obscure the evidence of major magma chamber events (e.g. melt extraction, magma mixing), the Quizapu magma system shows limited petrographic complexity in two large historical eruptions (1846–1847 and 1932) that have contrasting eruptive styles. Quizapu magmas and peripheral mafic magmas exhibit a simple binary mixing relationship. At the mafic end, basaltic andesite to andesite recharge magmas complement the record from peripheral cones and show the same limited range of compositions. The silicic end-member composition is almost identical in both eruptions of Quizapu. The effusive 1846–1847 eruption records significant mixing between the mafic and silicic end-members, resulting in hybridized andesites and mingled dacites. These two compositionally simple eruptions at Volcán Quizapu present a rare opportunity to isolate particular aspects of magma evolution—formation of homogeneous dacite magma and late-stage magma mixing—from other magma chamber processes. Crystal zoning, trace element compositions, and crystal-size distributions provide evidence for spatial separation of the mafic and silicic magmas. Dacite-derived plagioclase phenocrysts (i.e. An25–40) show a narrow range in composition and limited zonation, suggesting growth from a compositionally restricted melt. Dacite-derived amphibole phenocrysts show similar restricted compositions and furthermore constrain, together with more mafic amphibole phenocrysts, the architecture of the magmatic system at Volcán Quizapu to be compositionally and thermally zoned, in which an andesitic mush is overlain by a homogeneous dacitic

  5. Eruptive and Intrusive History of Mount Mazama and the Crater Lake Region Explains Growth of a Young Silicic Magma Body (United States)

    Bacon, C. R.; Lanphere, M. A.; Lowenstern, J. B.


    Crater Lake caldera (subsidence area >25 km2) collapsed into a shallow long-lived magmatic system during the ~7.7 ka climactic eruption of Mount Mazama that ejected ~50 km3 of magma dominated by homogeneous crystal-poor rhyodacite pumice. Geologic mapping, Ar and U-Th geochronology, and geochemistry provide volume-time-composition information on the growth and evolution of the Mazama system. Granodiorite and related plutonic rocks in the climactic ejecta give a window into the intrusive component of that system. We interpret the eruptive and intrusive history in terms of the competition between (1) crystallization driven by degassing and hydrothermal cooling and (2) thermal input from a regional magma flux focused at Mazama. Throughout its ~400 kyr history, the andesite-dacite volcano known as Mount Mazama, built astride an earlier silicic dome field, was accompanied by nearby basaltic to andesitic effusive volcanism representing a range of differentiation of melts of depleted mantle containing varied amounts of water and subduction-related fluid-mobile elements. Similar parent magmas appear to have differentiated to form the products of Mount Mazama. The Mazama edifice was constructed in many comparatively brief episodes, some of the more voluminous being approximately coeval with volcanic pulses in the surrounding region. Magmas as evolved as dacite erupted many times, commonly associated with or following voluminous andesite effusion. It was not until ~30 ka, after 400 kyr of preconditioning, that a shallow rhyodacite-dominated magma reservoir began to grow. Between ~30 ka and the climactic eruption, rhyodacitic magmas vented mainly north of the edifice, unaccompanied by other compositions. From ~35 ka into postglacial time unusually primitive lavas (magnesian basaltic andesite and tholeiitic basalt) erupted west of Mazama suggest increased thermal input. Reconstruction of the Mazama climactic magma chamber from preclimactic rhyodacites and their enclaves and

  6. Petrology, mineral chemistry and tectono-magmatic setting of volcanic rocks from northeast Farmahin, north of Arak

    Directory of Open Access Journals (Sweden)

    Reza Zarei Sahamieh


    Full Text Available Introduction The study area is a small part of the Urumieh-Dokhtar structural zone in the Markazi province, located in the northeastern part of the Farmahin, north of Arak (Hajian, 1970. The volcanic rocks studied from the area include andesite, dacite, rhyodacite, ignimbrite and tuff of Middle to Late Eocene age (middle Lutetian to upper Lutetian (Ameri et al., 2009. It seems that folding and faulting is caused in sedimentary basin and volcanic activities. On the other hand, except of orogeny maybe rifting had rule in eruption so that this case has seen in the other area such as Taft and Khezrabad in central Iran (Zarei Sahamieh et al., 2008. The oldest formation in the studied area is Triassic limestones. The dominant textures of these rocks are porphyritic, microlite porphyritic, microlitic and rarely sieve-texture. Sieve texture and dusty texture (dusty plagioclases indicates magma mixing. Mineralogically, they contain plagioclases, clinopyroxenes, amphiboles, quartz and biotite as the main constituents and zircon, apatite, and opaque minerals as accessories. Plagioclases in the andesitic and basaltic- andesite rocks are labradorite, bytownite and anorthite (based on electron microprobe .Moreover, plagioclases in andesitic rocks show that H2O is lesser than 2.5 precent. Amphibole is found in both plagioclases and groundmass. Materials and methods In this article are used different analyses methods such as XRF, ICP-MS and EPMA. Whole-rock major and trace element analyses were determined with ICP-MS method. The major and trace element composition of some rock was determined by electron probe micro-analysis (EPMA using a Cameca SX100 instrument in Iran Mineral Processing Research Center (IMPRC. Moreover, whole-rock major and some trace element analyses for some samples were obtained by X-ray fluorescence (XRF, using an ARL Advant-XP automated X-ray spectrometer. Results Chemical data based on electron micro probe studies of minerals indicate

  7. Compositional diversity of Late Cenozoic basalts in a transect across the southern Washington Cascades: Implications for subduction zone magmatism (United States)

    Leeman, William P.; Smith, Diane R.; Hildreth, Wes; Palacz, Zen; Rogers, Nick


    Major volcanoes of the Southern Washington Cascades (SWC) include the large Quaternary stratovolcanoes of Mount St. Helens (MSH) and Mount Adams (MA) and the Indian Heaven (IH) and Simcoe Mountain (SIM) volcanic fields. There are significant differences among these volcanic centers in terms of their composition and evolutionary history. The stratovolcanoes consist largely of andesitic to dacitic lavas and pyroclastics with minor basalt flows. IH consists dominantly of basaltic with minor andesite lavas, all erupted from monogenetic rift and cinder cone vents. SIM has a poorly exposed andesite to rhyolite core but mainly consists of basaltic lavas erupted from numerous widely dispersed vents; it has the morphology of a shield volcano. Distribution of mafic lavas across the SWC is related to north-northwest trending faults and fissure zones that indicate a significant component of east-west extension within the area. There is overlap in eruptive history for the areas studied, but it appears that peak activity was progressively older (MSH (slab-metasomatized subarc mantle. The juxtaposition of such different mantle domains within the lithospheric mantle is viewed as a consequence of (1) tectonic mixing associated with accretion of oceanic and island arc terranes along the Pacific margin of North America prior to Neogene time, and possibly (2) a seaward jump in the locus of subduction at about 40 Ma. The Cascades arc is unusual in that the subducting oceanic plate is very young and hot. We suggest that slab dehydration outboard of the volcanic front resulted in a diminished role of aqueous fluids in generating or subsequently modifying SWC magmas compared to the situation at most convergent margins. Furthermore, with low fluid flux conditions, basalt generation is presumably triggered by other processes that increase the temperature of the mantle wedge (e.g., convective mantle flow, shear heating, etc.).

  8. Geology and metallogeny of the volcanic complex of Rio Blanco Ullum. Province of San Juan. Republica Argentina

    International Nuclear Information System (INIS)

    Mendoza, N.; Weidmann, N.; Puigdomenech, H.; Weidmann, R.


    Preliminary results of a research carried out at the Complejo Rio Blanco de Ullum, San Juan. Argentina are summarized in the present paper. These studies are focused on geological and metallogenic features o f this unit. The study area is located 20 km. WNW of San Juan city with geographic coordinates of 31grades 30' South latitude and 68 grades 52' West longitude. The older rocks aotcroping in the area correspond to limestones of Ordovician San Juan Formation, the chronologic succession continues with sales and siltstones of Silurian Tambolar Formation, pelites and subgraywackes of Devonian Punta Negra Formation and finally a 1500 m thick package of piroclastics and sediments of Albarracin Formation of Tertiary age. Albarracin Formation is composed pf a Basal Member (sandstones and stilstones), a Tuffaceous Member (tuffs, tuffites and oligomictic breccia s with conglomerate interbed dings in the upper part) and a Conglomeratic Member (polimictic para conglomerates). According to piroclastics facies, relationships and spreading area of piroclastics deposits a c olapsed dome and avalanche model is proposed to be the main process for the piroclastics package outcropping in the area.Sedimentary and piroclastics rocks are intruded by five sub volcanic units as noted by Leveratto (1968) which are composed by different lithologies such as: Altered Da cite - Rhyolite, Ullum Da cite, Cerro Blanco de Zonda Andesite, Ullum Andesite and Hybrid Andesite.Detailed work on alteration assemblages and metallogenic features in the southwestern sector of the Complejo resulted in the identification of three alteration zones with characteric features of potassic, argillic and propyllitic signature. (author)

  9. Fracture permeability in the Matalibong-25 corehole, Tiwi geothermal field, Philippines

    Energy Technology Data Exchange (ETDEWEB)

    Nielson, Dennis L.; Clemente, Wilson C.; Moore, Joseph N.; Powell, Thomas S.


    The Tiwi geothermal field is located in southern Luzon on the northeast flank of Mt. Malinao, an andesitic volcano that was active 0.5 to 0.06 Ma. Matalibong-25 (Mat-25) was drilled through the Tiwi reservoir to investigate lithologic and fracture controls on reservoir permeability and to monitor reservoir pressure. Continuous core was collected from 2586.5 to 8000 feet (789 to 2439 meters) with greater than 95% recovery. The reservoir rocks observed in Mat-25 consist mainly of andesitic and basaltic lavas and volcaniclastic rocks above 6600 feet depth (2012 meters) and andesitic sediments below, with a transition from subaerial to subaqueous (marine) deposition at 5250 feet (1601 meters). The rocks in the reservoir interval are strongly altered and veined. Common secondary minerals include chlorite, illite, quartz, calcite, pyrite, epidote, anhydrite, adularia and wairakite. An 39Ar/40Ar age obtained on adularia from a quartz-adularia-cemented breccia at a depth of 6066 feet (2012 meters) indicates that the hydrothermal system has been active for at least 320,000 years. Fractures observed in the core were classified as either veins (sealed) or open fractures, with the latter assumed to represent fluid entries in the geothermal system. Since the core was not oriented, only fracture frequency and dip angle with respect to the core axis could be determined. The veins and open fractures are predominantly steeply dipping and have a measured density of up to 0.79 per foot in the vertical well. Below 6500 feet (1982 meters) there is a decrease in fracture intensity and in fluid inclusion temperatures.

  10. Hydrogeological investigation of Melendiz basin (Aksaray)

    International Nuclear Information System (INIS)

    Dogdu, M.S.


    Within the scope of this M.Sc, study entitled Hydrogeologic Investigation of Melendiz basin, the geological, hydrological, hydrogeological and hydrochemical features of a 600 km2 area have been studied and, 1/100.000 scale geological and hydrogeological maps have been prepared. Tetriary-Guaternary aged young volkanic rocks occupy nearly 80% (480 km2 ) of the area. The major aquifers are alluvium and andesite and basalt which are extensively fractured and jointed. Aquitard units comprise of ignimbirite, some of the andesites-basalts and formations that composes of limestone-sandstone-marl intercalations. The youngest geologic unit of the area, Hasandag volcanic ash formation, and also the tuffs have been indentified as aquiclude units. Mean areal precipitation, potential and real evapotranspiration rates and mean annual streamflow have been calculated on the basis of available data and, a hydrologic budget of the basin has been established. Hydrogeologic units have been classified as aquifer, aquitard and aquiclude with respect to their geohydrologic properties, field observations and the results of the pumping tests. On the other hand, hydrodynamic mechanism of the groundwater flow reaching major cold and thermal water discharges have also been explained. A hydrogeologic budget for the area covering Ciftlik township and its vicinity where extensively joint and fractured andesite-basalt and alluvial aquifers outcrop has been established. Major water points as thermal and cold springs, wells and streams have been sampled for major ion analysis. Beyond this, some water points have also been sampled for organic, trace,metal ald environmental isotropic analyses. Environmental isotope data of thermal springs point out a long-deep groundwater flow path

  11. La Purísima volcanic field, Baja California Sur (Mexico): Miocene to Quaternary volcanism related to subduction and opening of an asthenospheric window (United States)

    Bellon, Hervé; Aguillón-Robles, Alfredo; Calmus, Thierry; Maury, René C.; Bourgois, Jacques; Cotten, Joseph


    Geological mapping and geochemical analyses combined with 40K- 40Ar ages for lavas from the Late Miocene to Quaternary La Purísima volcanic field (Baja California Sur) provide evidence for five volcanic events. These, in turn, may reflect plate interactions in the region. The oldest event (event 1), prior to 11 Ma, corresponds to the emission of normal to K-rich calc-alkaline lavas, exposed as large mesas in the eastern part of the studied area and as pyroclastic breccias and volcaniclastic sediments to the west. It is associated with the end of the Comondú arc activity resulting from subduction of the Farallon and Guadalupe plates. Between 10.6 and 8.8 Ma (event 2), magnesian andesites and tholeiites were emplaced. At 5.5 Ma (event 3) and 2.5 Ma (event 4) small volumes of magnesian andesites erupted in the central and southern parts of the volcanic field. Finally, between 1.2 Ma and Holocene (event 5), numerous basaltic and magnesian andesitic fissural and central emissions resulted in the formation of strombolian cones and associated lava flows, mainly distributed within a NNW-SSE trending graben located SE of the town of La Purísima. Magmatic events 2 to 5 occurred well after the supposed end of the subduction event. Their geochemical characteristics are still typical of subduction-modified sources and possibly indicate partial melting of hot slab and formation of an asthenospheric window due to a slab rupture event which followed ridge-trench collision, prior to the continental breakup of the Gulf of California extensional province.

  12. Evolving metasomatic agent in the North Andean subduction, deduced from magma composition of the long-lived Pichincha volcanic complex (Ecuador) (United States)

    Samaniego, P.; Robin, C.; Chazot, G.; Bourdon, E. P.; Jo, C.


    Geochemical studies of long-lived volcanic complexes are crucial for the understanding of the nature and composition of the subduction component of arc magmatism. The Pichincha Volcanic Complex (Northern Andean Volcanic Zone) consists of: (1) an older, highly eroded edifice, the Rucu Pichincha, whose lavas are mostly andesites, erupted from 1100 to 150 ka; and (2) a younger, essentially dacitic, Guagua Pichincha composite edifice, with three main construction phases (Basal Guagua Pichincha, Toaza and Cristal) which formed over the last 60 ka. This structural evolution was accompanied by a progressive increase of most incompatible trace element abundances and ratios, as well as by a sharp decrease of fluid-mobile to fluid-immobile element ratios. Geochemical data indicate that fractional crystallization of an amphibole-rich cumulate could account for the evolution from the Guagua Pichincha andesites to dacites. However, in order to explain the passage from the Rucu Pichincha andesites to Guagua Pichincha dacites, the mineralogical and geochemical data indicate the predominance of magma mixing processes between a mafic, trace-element depleted, mantle-derived end-member, and a siliceous, trace-element enriched, adakitic end-member. The systematic variation of trace element abundances and ratios in primitive samples of this volcanic complex leads us to propose that the Rucu Pichincha magmas came from a hydrous-fluid metasomatized mantle wedge, whereas Guagua Pichincha magmas are related to partial melting of a siliceous-melt metasomatized mantle. This temporal evolution implies a change from dehydration to partial melting of the slab, which may be associated with an increase in the geothermal gradient along the slab due to the presence of the subducted Carnegie Ridge at the subduction system. This work emphasizes the importance of studying arc-magma systems over long periods of time (of at least 1 million of years), in order to evaluate the potential variations of the

  13. Evolving metasomatic agent in the Northern Andean subduction zone, deduced from magma composition of the long-lived Pichincha volcanic complex (Ecuador) (United States)

    Samaniego, Pablo; Robin, Claude; Chazot, Gilles; Bourdon, Erwan; Cotten, Joseph


    Geochemical studies of long-lived volcanic complexes are crucial for the understanding of the nature and composition of the subduction component of arc magmatism. The Pichincha Volcanic Complex (Northern Andean Volcanic Zone) consists of: (1) an old, highly eroded edifice, the Rucu Pichincha, whose lavas are mostly andesites, erupted from 1,100 to 150 ka; and (2) a younger, essentially dacitic, Guagua Pichincha composite edifice, with three main construction phases (Basal Guagua Pichincha, Toaza, and Cristal) which developed over the last 60 ka. This structural evolution was accompanied by a progressive increase of most incompatible trace element abundances and ratios, as well as by a sharp decrease of fluid-mobile to fluid-immobile element ratios. Geochemical data indicate that fractional crystallization of an amphibole-rich cumulate may account for the evolution from the Guagua Pichincha andesites to dacites. However, in order to explain the transition between the Rucu Pichincha andesites and Guagua Pichincha dacites, the mineralogical and geochemical data indicate the predominance of magma mixing processes between a mafic, trace-element depleted, mantle-derived end-member, and a siliceous, trace-element enriched, adakitic end-member. The systematic variation of trace element abundances and ratios in primitive samples leads us to propose that the Rucu Pichincha magmas came from a hydrous-fluid metasomatized mantle wedge, whereas Guagua Pichincha magmas are related to partial melting of a siliceous-melt metasomatized mantle. This temporal evolution implies a change from dehydration to partial melting of the slab, which may be associated with an increase in the geothermal gradient along the slab due to the presence of the subducted Carnegie Ridge at the subduction system. This work emphasizes the importance of studying arc-magma systems over long periods of time (of at least 1 million of years), in order to evaluate the potential variations of the slab contribution

  14. Origins of large-volume, compositionally zoned volcanic eruptions: New constraints from U-series isotopes and numerical thermal modeling for the 1912 Katmai-Novarupta eruption (United States)

    Turner, Simon; Sandiford, Mike; Reagan, Mark; Hawkesworth, Chris; Hildreth, Wes


    We present the results of a combined U-series isotope and numerical modeling study of the 1912 Katmai-Novarupta eruption in Alaska. A stratigraphically constrained set of samples have compositions that range from basalt through basaltic andesite, andesite, dacite, and rhyolite. The major and trace element range can be modeled by 80–90% closed-system crystal fractionation over a temperature interval from 1279°C to 719°C at 100 MPa, with an implied volume of parental basalt of ∼65 km3. Numerical models suggest, for wall rock temperatures appropriate to this depth, that 90% of this volume of magma would cool and crystallize over this temperature interval within a few tens of kiloyears. However, the range in 87Sr/86Sr, (230Th/238U), and (226Ra/230Th) requires open-system processes. Assimilation of the host sediments can replicate the range of Sr isotopes. The variation of (226Ra/230Th) ratios in the basalt to andesite compositional range requires that these were generated less than several thousand years before eruption. Residence times for dacites are close to 8000 years, whereas the rhyolites appear to be 50–200 kyr old. Thus, the magmas that erupted within only 60 h had a wide range of crustal residence times. Nevertheless, they were emplaced in the same thermal regime and evolved along similar liquid lines of descent from parental magmas with similar compositions. The system was built progressively with multiple inputs providing both mass and heat, some of which led to thawing of older silicic material that provided much of the rhyolite.

  15. Ignimbrite Analyses of Batur Caldera, Bali, based on 14C Dating

    Directory of Open Access Journals (Sweden)

    Igan S. Sutawidjaja


    Full Text Available Batur Caldera, in the northeastern part of Bali Island, is an elliptical collapse structure 13.8 by 10 km in size and another circular composite collapse structure with a diameter of 7.5 km in its centre. Two stages of the collapse were interrupted by silicic andesite lavas and domes. The first collapse was initiated by the eruption of about 84 km3 of the dacitic "Ubud Ignimbrite", about 29,300 years B.P., which caused a steep-walled depression about 1 km deep. The second ignimbrite was erupted from a large crater about the present lake, and it  produced about 19 km3 of a similar voluminous dacitic ignimbrite, called the "Gunungkawi Ignimbrite" about 20,150 years B.P. This second eruption trig- gered a second collapse, which created the central circular caldera, and formed a basin structure. Both the Ubud and Gunungkawi Ignimbrites consist of a similar dacitic composition, white to red (the most abundant nearly 90 % and dark grey to black dacitic pumice clasts. The large clasts, up to 20 cm in diameter, are in the non-welded ignimbrite, particularly in the upper part of the Gunungkawi Ignimbrite. The intracaldera ignimbrite, called the "Batur Ignimbrite" about 5 km3  in volume is a densely welded ignimbrite and generally shows typical welded features. The ignimbrite comprises at least five different flow units, separated by thin (15 - 40 cm welded pumiceous airfall deposits, with flattened pumice clasts. Another large eruption occurred about 5,500 years B.P., producing around 0.09 km3  andesitic ignimbrite. This was initiated by phreatomagmatic eruptions, indicated by thick phreatomagmatic and surge deposits, underlying the ignimbrite. The caldera and its vicinity are partly filled, and variably mantled by later eruptive products of dacitic and andesitic phreatomagmatic and airfall deposits.  

  16. Low- δ18O tephra from a compositionally zoned magma body: Fisher Caldera, Unimak Island, Aleutians (United States)

    Bindeman, Ilya N.; Fournelle, John H.; Valley, John W.


    We present the results of an oxygen isotope study of phenocrysts in pumice clasts and ash layers produced by the 9100 yr BP composite dacite-basaltic andesite climactic eruption that formed Fisher Caldera in the eastern Aleutians. Products of the eruption represent a low-δ18O magma with δ18O plagioclase (+4.79±0.24‰) and clinopyroxene (3.81±0.23‰) corresponding to equilibrium at magmatic temperatures. Dacitic and overlying basaltic-andesitic tephra of the climactic eruption, subsequent intracaldera basaltic to andesitic lavas, and a cumulate inclusion, are similarly low in δ18O. Other analyzed lavas and pyroclastics of Unimak island and the lower Alaska peninsula, as well as precaldera Fisher basalt, have normal δ18O magmatic values (>+5.5‰). We propose a model in which prior to 9100 yr BP, normal mantle-derived basaltic magma coalesced in a large shallow precaldera magma chamber during Late Wisconsin glaciation. Lowering of magmatic δ18O resulted then from long-term assimilation of ∼5-10% of syn-glacial hydrothermally-altered country rocks. Differentiation of basaltic magma was concurrent with this assimilation and produced low-δ18O Fisher dacites, cumulates, and post-caldera crystal-richer lavas. We propose the use of δ18O values of phenocrysts (especially alteration-resistant pyroxene) in tephra as a tool for tephrochronological and tephrostratigraphic correlation. Distinctly low-δ18O values are useful in identification of the Fisher ash in the eastern Aleutians and in the lower Alaska Peninsula.

  17. The Ediacaran volcanic rocks and associated mafic dykes of the Ouarzazate Group (Anti-Atlas, Morocco): Clinopyroxene composition, whole-rock geochemistry and Sr-Nd isotopes constraints from the Ouzellarh-Siroua salient (Tifnoute valley) (United States)

    Belkacim, Said; Gasquet, Dominique; Liégeois, Jean-Paul; Arai, Shoji; Gahlan, Hisham A.; Ahmed, Hassan; Ishida, Yoshito; Ikenne, Moha


    Belonging to the huge Ouarzazate volcanic Group that covered the whole Anti-Atlas during the late Ediacaran (580-545 Ma), the Tifnoute valley volcanic formations are mainly pyroclastic and show a large composition, from trachybasalt to rhyolite and are crosscut by dolerite dykes. The Tifnoute valley volcanic rocks are located within a rigid salient of the Anti-Atlas that gives them special extreme characteristics. Due to the heavy greenschist alteration that affects this volcanic group, we focused the more immobile elements, but as REE can also be affected, we used the composition of unaltered clinopyroxene crystals to determine the nature of these volcanic rocks. The clinopyroxene is an augite diopside in the basalt, an augite in the andesite and an augite-salite in the dolerite. Petrography of the Tifnoute mafic volcanic rocks and clinopyroxene compositions indicate the presence of two magmatic series: (i) older high-K calc-alkaline (alkali-calcic) andesite and basalt characterized by the early crystallization of Fe-Ti oxides and of the late fractionation of plagioclase, the modal proportion of the latter increasing from the basalt to the andesite and (ii) younger alkalic dolerite dykes. With clinopyroxene trace element compositions obtained using laser ablation ICP-MS, we calculated the composition of the melts in equilibrium with the pyroxenes. The volcanic rocks of the Tifnoute Valley have positive εNd570 (+1.7 to +5.0), low Sri (volcanic rocks emplaced in a Pan-African transtensive post-collisional environment that evolved towards the major rifting event that will give rise to the Rheic ocean, in a similar way to what occurred just after the Variscan orogeny during the Triassic period that evolved to the Tethys ocean opening.

  18. Crustal xenoliths from Calbuco Volcano, Andean Southern Volcanic Zone: implications for crustal composition and magma-crust interaction (United States)

    Hickey-Vargas, Rosemary; Abdollahi, Mohammad J.; Parada, Miguel A.; López-Escobar, Leopoldo; Frey, Fred A.


    Crustal xenoliths in the 1961 andesite flow of Calbuco Volcano, in the southern Southern Volcanic Zone (SSVZ) of the Andes, consist predominantly of pyroxene granulites and hornblende gabbronorites. The granulites contain plagioclase+pyroxene+magnetite±amphibole, and have pronounced granoblastic textures. Small amounts of relict amphibole surrounded by pyroxene-plagioclase-magnetite-glass symplectites are found in some specimens. These and similar textures in the gabbronorites are interpreted as evidence of dehydration melting. Mineral and bulk rock geochemical data indicate that the granulites are derived from an incompatible trace element depleted basaltic protolith that underwent two stages of metamorphism: a moderate pressure, high temperature stage accompanied by melting and melt extraction from some samples, followed by thermal metamorphism after entrainment in the Calbuco andesite lavas. High ɛNd T values (+4.0 to +8.6), Nd-isotope model ages of 1.7 2.0 Ga, and trace element characteristics like chondrite normalized La/YbCalbuco. Crystallization pressures for the gabbros based on total Al contents in amphibole are 6 8 kbar. These pressures point to middle to lower crustal storage of the Calbuco magma. Neither granulite nor gabbro xenoliths have the appropriate geochemical characteristics to be contaminants of Calbuco andesites, although an ancient sedimentary contaminant is indicated by the lava compositions. The presence of oceanic metabasaltic xenoliths, together with the sedimentary isotopic imprint, suggests that the lower crust beneath the volcano is analogous to the coastal metamorphic belt, which is an accretionary complex of intercalated basalts and sediments that formed along the Paleozoic Gondwanan margin. If this is the case, the geochemical composition of the lower and middle crust beneath the SSVZ is significantly different from that of most recent SSVZ volcanic rocks.

  19. Sr and O isotopes in western Aleutian seafloor lavas: Implications for the source of fluids and trace element character of arc volcanic rocks (United States)

    Yogodzinski, Gene M.; Kelemen, Peter B.; Hoernle, Kaj; Brown, Shaun T.; Bindeman, Ilya; Vervoort, Jeffrey D.; Sims, Kenneth W. W.; Portnyagin, Maxim; Werner, Reinhard


    High Mg# andesites and dacites (Mg# = molar Mg/Mg + Fe) from western Aleutian seafloor volcanoes carry high concentrations of Sr (>1000 ppm) that is unradiogenic (87Sr/86Sr 0.7030). Data patterns in plots of 87Sr/86Sr vs Y/Sr and Nd/Sr imply the existence of an eclogite-melt source component - formed by partial melting of MORB eclogite in the subducting Pacific Plate - which is most clearly expressed in the compositions of western Aleutian andesites and dacites (Nd/Sr and Y/Sr important source of Sr because mixtures of fluids from altered oceanic crust with depleted mantle and sediment produce compositions with 87Sr/86Sr higher than in common Aleutian rocks. The unradiogenic nature of Sr in the western Aleutian andesite-dacite end-member may be understood if H2O required to drive melting of the subducting oceanic crust is transported in fluids containing little Sr. Mass balance demonstrates that such fluids may be produced by dewatering of serpentinite in the mantle section of the subducting plate. If the eclogite-melt source component is present throughout the Aleutian arc, melting of the subducting plate must extend into minimally altered parts of the sheeted dike section or upper gabbros, at depths >2 km below the paleo-seafloor. Oxygen isotopes in western Aleutian seafloor lavas, which fall within a narrow range of MORB-like values (δ18 O = 5.1- 5.7), are also consistent with this model. These results indicate that the subducting Pacific lithosphere beneath the Aleutian arc is significantly hotter than indicated my most thermal models.

  20. Permo-triassic volcanism in the San Rafael Block (Mendoza province) and its uraniferous potential

    International Nuclear Information System (INIS)

    Kleiman, L.E.


    This paper describes the Permo-triassic volcanism in the San Rafael Block, Mendoza, Argentina, which forms part of the Choiyoi province and it represents by large volumes of intermediate to silicic ignimbrites with minor sub volcanic bodies of rhyolites, andesites and basandesites. Three different suites can be distinguished: the first one (Lower Section) of Early Permian age, is composed of dacites and rhyolites (SiO 2 up to 71 %) with minor andesites, the second one (Upper Section) of Late Permian-Early Triassic age is made up of rhyolites (SiO 2 up to 77 %) with some basandesites and andesites, and the third one, of Triassic age is composed of rhyolites (SiO 2 > 75 %) and basandecites. These suites are easily distinguished by means of trace element data and are believed to represent the transition between a subduction-related magmatic arc and an extensional tectonic regime. This tectonic setting is similar to the prevalent during the Cenozoic in the Sierra Occidental of Mexico and is favourable for the development of long-lived hydrothermal systems which lead to economic U concentrations (i.e. Sierra de Pena Blanca). In the San Rafael Block, the Dr. Baulies-Los Reyunos U deposit, which is hosted in volcanic sediments, is associated to the first suite (Lower Section). Although minor U concentrations are known, up to date, to be related to the second and third suites, these rocks are fertile and seen to be potential source for the formation of uranium deposits within a volcanic caldera environment. (Author)

  1. Petrographic and Geochemical Analyses of Kirana Hills Shield Rocks around Sargodha and Economic Potential

    Directory of Open Access Journals (Sweden)

    Muhammad Waseem Khan


    Full Text Available The present study deals with geochemical and petrographic analysis of the Kirana Hill shield rocks of Punjab plains from Buland, Hachi, Shaheen Abad, Shaikh and Machh hills. On basis of the current studies certain modifications have been made in the classification and nomenclature of rocks exposed in the study areas. Chemical analyses have also been carried out in order to calculate Cross Iddings, Pirsson, and Washington (CIPW norms”, to strengthen nomenclature scheme and finally rocks are classified by using “MAGMA SOFTWARE”. Rhyolites predominate over the basalts/dolerites, andesites, and phyllite/ slate. Rhyolitic rocks are light grey, greenish grey and light brown in color, aphanitic in nature. The observed microscopic textures are aphyric, phyric or porphyritic and micropoikilitc. Moreover, some rhyolitic rocks also show flow texture. They are either cryptocrystalline to microcrystalline or microcrystalline to cryptocrystalline. No glassy material has been observed in any thin section. Mafic rocks are characterized by the presence of ferromagnesian minerals with plagioclase. Andesites exhibit mainly porphyritic texture, but aphyric texture has also been observed in few samples. Hydrothermal alterations are also very common in these rocks. Other rock assemblages identified during laboratory studies from Kirana area include: tuffs i.e. (Lithic Crystal Tuff and Lithic Tuff, basaltic andesite, rhyodacite/ dacite, slate/ phyllite, ankeritic rocks/ veins and quartzofeldspathic veins. Our studies also reveal that no evidence of quartzite has been found in the samples collected from above mentioned areas of Kirana, although it has been reported in previous literature. Iron (Fe has been observed in rhyolite as well as other volcanic rocks of Kirana hills, its presence suggests magma from deep mantle instead of crustal melting / anatexis. In the present analysis some primary and secondary copper minerals including chalcopyrite, atacamite and

  2. Magnetic fabric and flow direction in the Ediacaran Imider dyke swarms (Eastern Anti-Atlas, Morocco), inferred from the Anisotropy of Magnetic Susceptibility (AMS) (United States)

    Otmane, Khadija; Errami, Ezzoura; Olivier, Philippe; Berger, Julien; Triantafyllou, Antoine; Ennih, Nasser


    Located in the Imiter Inlier (Eastern Saghro, Anti-Atlas, Morocco), Ediacaran volcanic dykes have been studied for their petrofabric using Anisotropy of Magnetic Susceptibility (AMS) technique. Four dykes, namely TF, TD, FF and FE show andesitic compositions and are considered to belong to the same dyke swarm. They are oriented respectively N25E, N40E, N50E, and N10E and have been emplaced during a first tectonic event. The dyke FW, oriented N90E displays a composition of alkali basalt and its emplacement is attributed to a subsequent tectonic event. These rocks are propylitized under greenschist facies conditions forming a secondary paragenesis constituted by calcite, chlorite, epidote and sericite. The dykes TF, TD, FF and FE are sub-volcanic calc-alkaline, typical of post-collisional basalts/andesites, belonging to plate margin andesites. The FW dyke shows a within-plate basalt signature; alkaline affinity reflecting a different petrogenetic process. The thermomagnetic analyses show a dominantly ferromagnetic behaviour in the TF dyke core carried by single domain Ti-poor magnetite, maghemite and pyrrhotite. The dominantly paramagnetic susceptibilities in TF dyke rims and TD, FE, FF and FW dykes are controlled by ilmenite, amphibole, pyroxene and chlorite. The magnetic fabrics of the Imider dykes, determined by our AMS study, allows us to reconstitute the tectonic conditions which prevailed during the emplacement of these two generations of volcanic dykes. The first tectonic event was characterized by a roughly NE-SW compression and the second tectonic event is characterized by an E-W shortening followed by a relaxation recording the end of the Pan-African orogeny in the eastern Anti-Atlas.

  3. Effect of sintering temperature and boron carbide content on the wear behavior of hot pressed diamond cutting segments


    Islak S.; Çelik H.


    The aim of this study was to investigate the effect of sintering temperature and boron carbide content on wear behavior of diamond cutting segments. For this purpose, the segments contained 2, 5 and 10 wt.% B4C were prepared by hot pressing process carried out under a pressure of 35 MPa, at 600, 650 and 700 °C for 3 minutes. The transverse rupture strength (TRS) of the segments was assessed using a three-point bending test. Ankara andesite stone was cut to ...


    Directory of Open Access Journals (Sweden)

    Sz. Fischer


    Full Text Available Purpose. Using adequate granular materials and layer structures in the railway super- and substructure is able to stabilise railway track geometry. For this purpose special behaviour of above materials has to be determined, e.g. inner shear resistance. Inner shear resistance of granular media with and without geogrid reinforcement in different depths is not known yet. Methodology. The author developed a special laboratory method to measure and define inner shear resistance of granular materials, it is called «multi-level shear box test». This method is adequate to determine inner shear resistance (pushing force vs. depth (distance from the «zero» surface. Two different granular materials: andesite railway ballast (31.5/63 mm and andesite railway protection layer material (0/56 mm, and seven different types of geogrids (GG1…GG7 were used during the tests. Findings. Values of inner shear resistance functions of andesite railway ballast without geogrid reinforcement and reinforced with different types of geogrids and andesite granular protection layer in function of the vertical distance from the geogrid plane were determined with multi-layer shear box tests when the material aggregation is uncompacted and compacted. Only the compacted sample was tested in case of the 0/56 mm protection layer. Cubic polynomial regression functions fitted on the mean values of the measurements are described graphically. Determination coefficients with values of R2>0.97 were resulted in all the cases of regression functions. Based on the polynomial regression functions fitted on the mean values of the test results, three increasing factors were determined in function of the distance measured from the geogrid. Increasing factor «A», «B» and «D». Originality. Multi-level shear box test, developed by the author, is certified unequivocally adequate for determining inner shear resistance of reinforced and unreinforced granular materials, e.g. railway ballast

  5. Update of map the volcanic hazard in the Ceboruco volcano, Nayarit, Mexico (United States)

    Suarez-Plascencia, C.; Camarena-Garcia, M. A.; Nunez-Cornu, F. J.


    The Ceboruco Volcano (21° 7.688 N, 104° 30.773 W) is located in the northwestern part of the Tepic-Zacoalco graben. Its volcanic activity can be divided in four eruptive cycles differentiated by their VEI and chemical variations as well. As a result of andesitic effusive activity, the "paleo-Ceboruco" edifice was constructed during the first cycle. The end of this cycle is defined by a plinian eruption (VEI between 3 and 4) which occurred some 1020 years ago and formed the external caldera. During the second cycle an andesitic dome built up in the interior of the caldera. The dome collapsed and formed the internal caldera. The third cycle is represented by andesitic lava flows which partially cover the northern and south-southwestern part of the edifice. The last cycle is represented by the andesitic lava flows of the nineteenth century located in the southwestern flank of the volcano. Actually, moderate fumarolic activity occurs in the upper part of the volcano showing temperatures ranging between 20° and 120°C. Some volcanic high frequency tremors have also been registered near the edifice. Shows the updating of the volcanic hazard maps published in 1998, where we identify with SPOT satellite imagery and Google Earth, change in the land use on the slope of volcano, the expansion of the agricultural frontier on the east sides of the Ceboruco volcano. The population inhabiting the area is 70,224 people in 2010, concentrated in 107 localities and growing at an annual rate of 0.37%, also the region that has shown an increased in the vulnerability for the development of economic activities, supported by highway, high road, railroad, and the construction of new highway to Puerto Vallarta, which is built in the southeast sector of the volcano and electrical infrastructure that connect the Cajon and Yesca Dams to Guadalajara city. The most important economic activity in the area is agriculture, with crops of sugar cane (Saccharum officinarum), corn, and jamaica

  6. Magma mixing in the San Francisco Volcanic Field, AZ (United States)

    Bloomfield, Anne L.; Arculus, Richard J.


    A wide variety of rock types are present in the O'Leary Peak and Strawberry Crater volcanics of the Pliocene to Recent San Francisco Volcanic Field (SFVF), AZ. The O'Leary Peak flows range from andesite to rhyolite (56 72 wt % SiO2) and the Strawberry Crater flows range from basalt to dacite (49 64 wt % SiO2). Our interpretation of the chemical data is that both magma mixing and crustal melting are important in the genesis of the intermediate composition lavas of both suites. Observed chemical variations in major and trace elements can be modeled as binary mixtures between a crustal melt similar to the O'Leary dome rhyolite and two different mafic end-members. The mafic end-member of the Strawberry suite may be a primary mantle-derived melt. Similar basalts have also been erupted from many other vents in the SFVF. In the O'Leary Peak suite, the mafic end-member is an evolved (low Mg/(Mg+ Fe)) basalt that is chemically distinct from the Strawberry Crater and other vent basalts as it is richer in total Fe, TiO2, Al2O3, MnO, Na2O, K2O, and Zr and poorer in MgO, CaO, P2O5, Ni, Sc, Cr, and V. The derivative basalt probably results from fractional crystallization of the more primitive, vent basalt type of magma. This evolved basalt occurs as xenolithic (but originally magmatic) inclusions in the O'Leary domes and andesite porphyry flow. The most mafic xenolith may represent melt that mixed with the O'Leary dome rhyolite resulting in andesite preserved as other xenoliths, a pyroclastic unit (Qoap), porphyry flow (Qoaf) and dacite (Darton Dome) magmas. Thermal constraints on the capacity of a melt to assimilate (and melt) a volume of solid material require that melt mixing and not assimilation has produced the observed intermediate lavas at both Strawberry Crater and O'Leary Peak. Textures, petrography, and mineral chemistry support the magma mixing model. Some of the inclusions have quenched rims where in contact with the host. The intermediate rocks, including the

  7. Mineralogy and fluid inclusion studies in kalchoye Copper- gold deposit, East of Esfahan

    Directory of Open Access Journals (Sweden)

    Rezvan Mehvary


    Full Text Available Kalchoye Copper-gold deposit is located about 110 kilometers east of Esfahan province and within the Eocene volcano sedimentary rocks. Sandy tuff and andesite lava are important members of this complex.The form of mineralization in area is vein and veinlet and quartz as the main gangue phase. The main ore minerals are chalcopyrite, chalcocite, galena and weathered minerals such as goethite, iron oxides, malachite and azurite. Studies in area indicate that ore mineralization Kalchoye is low sulfide, quartz type of hydrothermal ore deposits and results of thermometry studies on quartz minerals low- medium fluid with low potential mineralization is responsible for mineralization in this area.

  8. Magmatic response to early aseismic ridge subduction: the Ecuadorian margin case (South America) (United States)

    Bourdon, Erwan; Eissen, Jean-Philippe; Gutscher, Marc-André; Monzier, Michel; Hall, Minard L.; Cotten, Joseph


    A geochemical and isotopic study of lavas from Pichincha, Antisana and Sumaco volcanoes in the Northern Volcanic Zone (NVZ) in Ecuador shows their magma genesis to be strongly influenced by slab melts. Pichincha lavas (in fore arc position) display all the characteristics of adakites (or slab melts) and were found in association with magnesian andesites. In the main arc, adakite-like lavas from Antisana volcano could be produced by the destabilization of pargasite in a garnet-rich mantle. In the back arc, high-niobium basalts found at Sumaco volcano could be produced in a phlogopite-rich mantle. The strikingly homogeneous isotopic signatures of all the lavas suggest that continental crust assimilation is limited and confirm that magmas from the three volcanic centers are closely related. The following magma genesis model is proposed in the NVZ in Ecuador: in fore arc position beneath Pichincha volcano, oceanic crust is able to melt and produces adakites. En route to the surface, part of these magmas metasomatize the mantle wedge inducing the crystallization of pargasite, phlogopite and garnet. In counterpart, they are enriched in magnesium and are placed at the surface as magnesian andesites. Dragged down by convection, the modified mantle undergoes a first partial melting event by the destabilization of pargasite and produces the adakite-like lavas from Antisana volcano. Lastly, dragged down deeper beneath the Sumaco volcano, the mantle melts a second time by the destabilization of phlogopite and produces high-niobium basalts. The obvious variation in spatial distribution (and geochemical characteristics) of the volcanism in the NVZ between Colombia and Ecuador clearly indicates that the subduction of the Carnegie Ridge beneath the Ecuadorian margin strongly influences the subduction-related volcanism. It is proposed that the flattening of the subducted slab induced by the recent subduction (<5 Ma?) of the Carnegie Ridge has permitted the progressive warming of

  9. Petrological Features of The Post-Collisional Volcanics on the Izmir-Ankara-Erzincan Suture Zone at Around Almus and Yıldızeli Regions, NE Turkey. (United States)

    Göçmengil, G.; Karacik, Z.; Genç, Ş. C.


    Following the closure of the northern Neo-Tethyan ocean, post-collisional magmatism developed both on the Izmir-Ankara-Erzincan suture zone (IAESZ) and the northern (Pontides) and southern (Kırşehir block) continents. Cenozoic volcanics (particularly Middle to Upper Eocene) from the Almus and Yıldızeli regions (NE, Turkey) have poorly known and exposed along the northern and southern part of the IAESZ respectively. In this presentation; we present geological, geochemical and isotopic data of these volcanic rocks to characterize the petrological evolution and petrogenesis on the different tectonic blocks. Almus region, have a composite basement of Mesozoic metamorphic and ophiolitic rocks. Volcanic and sedimentary units of the Middle Eocene covering the basement units have a stratigraphic sequence of: a basal conglomerate; fossiliferous sandstone/shale; epiclastic rocks; auto-brecciated lavas with basalt/basaltic andesite lava flows. All these units are cut by trachyte stocks. Besides, basement of Yıldızeli region consisting of Cretaceous Kırşehir block metamorphics with IAESZ melangé and flysch units. Volcanic and sedimentary units covers the basement are trachyte-trachyandesite lavas; fossiliferous limestone; basalt/basaltic andesite lava flows; pyroclastic units with dacitic lavas. Basalt/basaltic andesites from Almus region are sub-alkaline/mildly alkaline and display middle to high-K character. REE data display relative enrichments in LILE (Sr, K, Rb, Ba, Th) together with negative anomalies of Nb, Ta and P. Trachyte stocks are shoshonitic and display LILE enrichment together with negative patters of Nb, Ta, P and Eu. Besides, trachyte-trachyandesite and basalt/basaltic andesite from Yıldızeli region are sub-alkaline/mildly alkaline with middle-K to shoshonitic character. REE patterns show enrichments in LILE and depletion of Nb, Ta, P and Ti for both rock suites. The 87Sr/86Sr and 143Nd/144Nd ratios of volcanic rocks from both regions, range from 0

  10. Petrography and geochemistry of the volcanic rocks of the Rodeio Velho Member, Ordovician of the Camaqua basin (RS-Brazil): preliminary results

    International Nuclear Information System (INIS)

    Almeida, Delia del Pilar M. de; Lopes, Ricardo da C.; Gomes, Cristiane H.; Lima, Larissa de.


    A geochemical study based in REE, minor elements and petrographic analyses from the volcanic rocks pertaining to the Rodeio Velho Member, comprising lava flows and epizonal intrusive bodies, both corresponding to andesites, subalkaline and alkaline basalts and trachyandesites; and stratified pyroclastic deposits, showed that fractional crystallization of deep source magma is the fundamental mechanism controlling the relationships among these rocks. This igneous event occurred in an alkaline intraplate environment, associated to a widespread extension tectonics, probably corresponding to a final stage of the Pan African - Brasiliano Orogeny during the Middle Ordovician. (author)

  11. Fading characteristics of martian analogue materials and the applicability of a correction procedure

    International Nuclear Information System (INIS)

    Morthekai, P.; Jain, M.; Murray, A.S.; Thomsen, K.J.; Botter-Jensen, L.


    The anomalous fading of trapped charge in martian analogue materials such as basalt and andesite rock samples is measured. Optically stimulated luminescence (OSL) signals show rapid fading (of between 4% and 27% per decade). Fading rates obtained using high temperature thermoluminescence signals are smaller. The importance of knowing whether a standard fading correction method is applicable to samples of unknown age is illustrated by application to an 'infinitely old' known-age basalt, for which both the uncorrected and fading-corrected natural signals lie within the approximately linear region of the growth curve

  12. Thermoluminescence dating in the South-West Pacific region

    International Nuclear Information System (INIS)

    Prescott, J.R.


    The archaeometry laboratory of the University of Adelaide has undertaken a variety of dating projects for archaeologists in the region. For example, a survey of Pacific Island pottery has shown that themoluminescence dating is likely to be severely limited in usefulness on islands remote from the continental shelf i.e., the andesitic island arcs and oceanic islands. On the mainland of Australia, we have dated prehistoric campsites using ovenstones from fireplaces and have compared C-14 ages with themoluminescent ages. Where there is a close stratigraphic association of the C-14 and TL materials, there is good agreement between the two methods. (author)

  13. Neutron activation analysis of ultrabasis rock by Ge(Li) γ-ray spectrometry and group separation

    International Nuclear Information System (INIS)

    Chen Baoguan; Yuan Ling; Fang Chanmeng


    The analytical procedure for determination of 21 elements in two ultrabasis rock samples with Ge(Li) gamma-ray spectrometry and group separation was described. 8 elements including Cr, Fe, Co, Sc, Mn, Na, Cl and Br have been directly determined by INAA. 13 elements including La, Ce, Nd, Sm, Gd, Eu, Tb, Ho, Tm, Yb, Lu, Zn and Cs have been determined by radiochemical separation. The samples of international standard AGV-1 (Andesite) have also been analyzed. The agreement of the results with the values proposed by F.J.Flanagan is satisfactory

  14. Crystal textures produced by magma mixing at Chokai, northern Honshu, Japan (United States)

    Ohba, T.; Hayashi, S.; Ban, M.


    Thermal equilibration during magma mingling between hot mafic magma and cold felsic magma results in rapid cooling of the mafic magma and in rapid heating of the felsic magma. In the mafic magma, minerals would quickly crystallize to grow, whereas minerals would dissolve in the felsic magma. As these suspended solid minerals are able to freely move in the liquids, they could enter the liquid which is not their original host. Every crystal would undergo complex chemical fluctuation of surrounding liquid during the dynamic mingling process, forming a wide variety of complex intracrystal textures. The complex mineralogy in a mixed lava (Saruana Lava) from Chokai, northern Honshu, Japan, is completely accounted for by crystallization and resorption induced by magma mixing. The lava is compositionally heterogeneous, as silica contents in whole rocks ranges from 54 to 60 % in the single lava flow. Regardless of the heterogeneity, these rocks exhibit similar mineralogical features, e.g. coexistence of reversely zoned pyroxene and normally zoned pyroxenes. In addition to whole rocks chemistry, extensive petrographical study with SEM-EDS revealed original mineralogy and compositions of the endmembers. The felsic endmember is the andesitic crystal mush consisting of 46% rhyolite melt, 38% plagioclase, 11% pyroxenes, 5% magnetite, and trace of hornblende. The mafic endmember is magnesian basalt magma containing small amount of magnesian olivine (Fo87), picotite, and calcic plagioclase (An90). Reversely zoned minerals consist of relatively uniform cores derived from felsic endmember and surrounding mafic margins that exhibit normal zoning imposed by fine rectilinear oscillatory zones. Innermost margin ranges mafic to intermediate in composition, depending on the thickness of the margin which broadly ranges from 1 to 100 micrometer. The cores exhibit resorption textures such as rounded shape, irregular shape, or dusty zones. Normally zoned crystals exhibit the similar

  15. Geochemistry of Archaean supracrustal belts in SW Greenland

    DEFF Research Database (Denmark)

    Szilas, Kristoffer

    geochemical mixing trends between juvenile felsic and mafic end-members. This suggests that partial melting and magma mixing by mafic underplating and slab melt metasomatism of the mantle source region were important in forming rocks of andesitic composition, which is also observed in some modern island arcs......, rather than high degrees of partial melting at elevated temperatures, as commonly proposed for such rocks. In conclusion, the main finding of this PhD-thesis is that all of the three studied areas have geochemical- and field-characteristics, which can be related to a subduction zone environment...

  16. Holocene tephrochronology of the Cold Bay area, southwest Alaska Peninsula*1 (United States)

    Carson, Eric C.; Fournelle, John H.; Miller, Thomas P.; Mickelson, David M.


    The major-element glass geochemistry of 92 tephra samples from the southwest Alaska Peninsula provides the basis for establishing a Holocene tephrochronology for the region. Electron microprobe analysis has been combined with field descriptions of samples, stratigraphic relationships between tephra samples and sample localities, and glass shard micro-morphology to correlate these sampled distal tephra units throughout the area of Cold Bay and adjacent Morzhovoi Bay. Radiocarbon dating provides age constraints on correlated horizons. Previous research had clearly delineated only one horizon in the region, the so-called 'Funk/Fisher' ash, dating to between 8425±350 and 9130±140 14C yr BP. In addition to constraining the bimodal andesitic and dacitic glass chemistry of that horizon, this study has recognized six additional tephra layers in the area. Two horizons pre-date the Funk/Fisher ash and four are younger than it. A tephra containing dacitic and andesitic components was identified in the vicinity of Morzhovoi Bay, with a minimum age of 9300±80 14C yr BP and a maximum age of 10,200±75 14C yr BP. A rhyolitic horizon composed of cm-sized, rounded pumice clasts was identified in the vicinity of Cold Bay; it has been correlated to the ca 9500 BP eruption of Roundtop volcano on Unimak Island. The four younger tephra beds date to between 6070±340 and 3600±140 14C yr BP. The oldest of the four is rhyodacitic, followed by a mixed rhyodacitic-andesitic horizon, another rhyodacitic horizon, and finally an andesitic layer. Comparison of all the correlated horizons to proximal samples collected on Unimak Island provides conclusive geochemical evidence that the ca 9100 BP Caldera-forming eruption of Fisher volcano is the source of the Funk/Fisher ash. Correlation between the rhyodacitic tephra horizons and proximal samples from Fisher volcano suggests that Fisher Caldera is the source of one of the rhyodacitic tephra horizons that post-dates the Funk/Fisher ash

  17. Holocene tephrochronology of the Cold Bay area, southwest Alaska Peninsula (United States)

    Carson, E.C.; Fournelle, J.H.; Miller, T.P.; Mickelson, D.M.


    The major-element glass geochemistry of 92 tephra samples from the southwest Alaska Peninsula provides the basis for establishing a Holocene tephrochronology for the region. Electron microprobe analysis has been combined with field descriptions of samples, stratigraphic relationships between tephra samples and sample localities, and glass shard micro-morphology to correlate these sampled distal tephra units throughout the area of Cold Bay and adjacent Morzhovoi Bay. Radiocarbon dating provides age constraints on correlated horizons. Previous research had clearly delineated only one horizon in the region, the so-called 'Funk/Fisher' ash, dating to between 8425 ± 350 and 9130 ± 140 14C yr BP. In addition to constraining the bimodal andesitic and dacitic glass chemistry of that horizon, this study has recognized six additional tephra layers in the area. Two horizons pre-date the Funk/Fisher ash and four are younger than it. A tephra containing dacitic and andesitic components was identified in the vicinity of Morzhovoi Bay, with a minimum age of 9300 ± 80 14C yr BP and a maximum age of 10,200 ± 75 14C yr BP. A rhyolitic horizon composed of cm-sized, rounded pumice clasts was identified in the vicinity of Cold Bay; it has been correlated to the ca 9500 BP eruption of Roundtop volcano on Unimak Island. The four younger tephra beds date to between 6070 ± 340 and 3600 ± 140 14C yr BP. The oldest of the four is rhyodacitic, followed by a mixed rhyodacitic-andesitic horizon, another rhyodacitic horizon, and finally an andesitic layer. Comparison of all the correlated horizons to proximal samples collected on Unimak Island provides conclusive geochemical evidence that the ca 9100 BP Caldera-forming eruption of Fisher volcano is the source of the Funk/Fisher ash. Correlation between the rhyodacitic tephra horizons and proximal samples from Fisher volcano suggests that Fisher Caldera is the source of one of the rhyodacitic tephra horizons that post-dates the Funk

  18. The seismic reassessment Mochovce NPP

    International Nuclear Information System (INIS)

    Baumeister, P.


    The design of Mochovce NPP was based on the Novo-Voronez type WWER-440/213 reactor - twin units. Seismic characteristic of this region is characterized by very low activity. Mochovce NPP site is located on the rock soil with volcanic layer (andesit). Seismic reassessment of Mochovce NPP was done in two steps: deterministic approach up to commissioning confirmed value Horizontal Peak Ground Acceleration HPGA=0.1 g and activities after commissioning as a consequence of the IAEA mission indicate higher hazard values. (author)

  19. K-Ar age for alunite-bearing rock from the Iwato gold deposit, Kagoshima Prefecture, southern Japan

    International Nuclear Information System (INIS)

    Togashi, Yukio; Shibata, Ken


    K-Ar age determination was made on a whole rock sample of the alunite-bearing silicified rock from the Iwato gold deposit, Kagoshima Prefecture, southern Japan. The sample is from one of the Nansatsu-type gold deposits, whose mineralization is characterized by the occurrence of leaching-type massive silicified rocks with gold dissemination. The result, 4.15 +- 0.78 Ma, is interpreted to be the age of the mineralization at the Iwato gold deposit. It also suggests that the Nansatsu-type deposits were formed in close association with andesitic volcanism in the early Pliocene age. (author)

  20. Petrology and geochemistry of ca. 2100-1000 a.B.P. magmas of Augustine volcano, Alaska, based on analysis of prehistoric pumiceous tephra (United States)

    Tappen, Christine M.; Webster, James D.; Mandeville, Charles W.; Roderick, David


    Geochemical and textural features of whole-rock samples, phenocrysts, matrix glasses, and silicate melt inclusions from five prehistoric pumiceous tephra units of Augustine volcano, Alaska, were investigated to interpret processes of magma storage and evolution. The bulk-rock compositions of the tephra (designated G, erupted ca. 2100 a.B.P.; I ca. 1700 a.B.P.; H ca. 1400 a.B.P.; and C1 and C2 ca. 1000 a.B.P.) are silicic andesite; they contain rhyolitic matrix glasses and silicate melt inclusions with 74-79 wt.% SiO 2. The rocks are comprised of microlite-bearing matrix glass and phenocrysts of plagioclase, orthopyroxene, clinopyroxene, magnesio-hornblende, titanomagnetite, and ilmenite ± Al-rich amphibole with minor to trace apatite and rare sulfides and quartz. The felsic melt inclusions in plagioclase, pyroxenes, and amphibole are variably enriched in volatile components and contain 1.6-8.0 wt.% H 2O, 2100-5400 ppm Cl, < 40-1330 ppm CO 2, and 30-390 ppm S. Constraints from Fe-Ti oxides imply that magma evolution occurred at 796 ± 6 °C to 896 ± 8 °C and log ƒ O2 of NNO + 2.2 to + 2.6. This is consistent with conditions recorded for 1976, 1986, and 2006 eruptive materials and implies that magmatic and eruptive processes have varied little during the past 2100 years. Prehistoric Augustine magmas represented by these silicic andesites evolved via fractional crystallization, magma mingling and mixing, and/or chemical contamination due to magma-volcanic rock interaction. The occurrence of fractional crystallization is supported by the abundance of normally zoned phenocrysts, the presence of felsic matrix glass and melt inclusions within andesitic rock samples, trace-element data, and by geochemical modeling. The modeling constrains the influence of crystal fractionation on melt differentiation and is consistent with the evolution of the melt phase from felsic andesite to rhyodacite compositions. Magma mixing, mingling, and/or contamination by magma-volcanic rock

  1. Trepça Ore Belt and Stan Terg mine – Geological overview and interpretation, Kosovo (SE Europe

    Directory of Open Access Journals (Sweden)

    Sylejman Hyseni


    Full Text Available The Trepça Belt of Pb-Zn-Ag mineralization is located within the NNW-SSE trending Vardar zone. The Beltextends for over 80 km, and supported five mines during the period 1930-2008. It contains a number of the otherPb-Zn occurrences too. The replacement and vein type mineralization is hosted primarily by Mesozoic carbonates,but also occasionally by amphibolites, and displays a clear structural control. Mineralization is spatially and geneticallyrelated to Neogene andesite-dacite extrusives and sub-volcanic intrusives. Only Stan Terg mine is presentedin this paper.

  2. Volcanologic and petrologic evolution of Antuco-Sierra Velluda, Southern Andes, Chile (United States)

    Martínez, Paola; Singer, Brad S.; Roa, Hugo Moreno; Jicha, Brian R.


    The Andean Southern Volcanic Zone comprises > 30 active arc front volcanoes that grew over periods of hundreds of thousands of years. Quantifying the rates at which these volcanoes grow is key to appreciating geological hazards, clarifying petrologic evolution, and exploring possible relationships between volcanism, ice loading, and climate. The integration of precise geochronology and geologic mapping, together with new lava compositions and volume estimates, reveal the evolution of the Antuco-Sierra Velluda volcanic complex at 37.2°S. Thirty-one new 40Ar/39Ar age determinations illuminate a punctuated eruptive history that spans at least 430 kyr. Sierra Velluda comprises 130 km3 and began to grow prior to 426.8 ka. A lacuna in the volcanic record between 343.5 and 150.4 ka coincides with glaciations associated with marine isotope stages (MIS) 10 and 8, although shallow intrusions were emplaced at 207.0 and 190.0 ka. Antuco began to grow rapidly on the northeast flank of Sierra Velluda, erupting > 60 km3 of lava during three phases: (1) an early phase that began at 150.4 ka, (2) a post-MIS 2 phase between 16.3 and 6.2 ka, and (3) a post-sector collapse phase after 6.2 ka. Volcanism has been continuous during the last 100 kyr, with an average rate of cone growth during this period of 0.46 km3/kyr that has accelerated by about 50% during the past 6 kyr. Whereas Sierra Velluda erupted basaltic andesitic to andesitic (53.5 to 58.7 wt% SiO2) lavas, during the last expansion of glaciers between 130 and 17 ka, Early Antuco erupted a wider spectrum of lavas, ranging from basaltic andesite to dacite (52.0 to 64.5 wt% SiO2). Notably, eruptions following the last glacial termination at 17 ka produced basalts and basaltic andesites (50.9-53.7% SiO2), and following the 6.2 ka cone collapse they have been exclusively olivine basalt (50.9-53.0% SiO2) with > 5 wt% MgO. Thermodynamic and trace element modeling suggests that lavas from Sierra Velluda and Early Antuco reflect

  3. Bulk rock and melt inclusion analyses indicate bimodal distribution in Calbuco volcano (Chile) (United States)

    Montalbano, Salvatrice; Bolle, Olivier; Schiano, Pierre; Cluzel, Nicolas; Vander Auwera, Jacqueline


    Calbuco is an active stratovolcano situated in the central SVZ (Southern Volcanic Zone) of the Andes at 41.2°S. The dominant rock-type is basaltic andesite containing macrocrysts of plagioclase (An57-91), olivine (Fo60-81), clinopyroxene (Mg# 74-85), orthopyroxene (Mg# 66-75) and rare amphibole (mostly pargasitic) in a micro-crystalline matrix. Orthopyroxene frequently occurs as a reaction rim surrounding olivine suggestive of a peritectic reaction. The oldest lava unit (Calbuco 1) contains basaltic andesites that are notably lower in MgO and higher in Al2O3 than the other samples. Some dacitic compositions have also been identified. Bulk rock analyses define a low-K calc-alkaline trend with however two basalts plotting in the tholeiite field in the AFM diagram. Bulk rocks display a differentiation trend of decreasing CaO, FeOt and MgO and increasing K2O and P2O5 with increasing SiO2. Typical negative anomalies in Nb, Ta and Th are shown in spiderdiagrams whereas there is no Eu anomaly in REE patterns. In variation diagrams, a clear compositional gap occurs between 61 and 65 wt. % SiO2. Investigation of melt inclusions was performed on homogenized and naturally quenched inclusions hosted in olivine and clinopyroxene crystals. Their composition mimics the differentiation trend observed in the bulk samples, including a bimodal distribution. The melt inclusions analyzed in olivine range in composition from 45 to 58 wt. % SiO2 whereas those occurring in clinopyroxene range from 70 and 76 wt. % SiO2. The compositional gap of the melt inclusions thus overlaps that of the whole rocks. The observed differentiation trend from basalt to basaltic andesite (49 to 58 wt. % SiO2) perfectly fits published experimental trends acquired on hydrous basalts at different crustal pressures, water concentrations and oxygen fugacities at subduction zones and can be accounted for by a fractional crystallization process where a bulk cumulate made of plagioclase, olivine, clinopyroxene and

  4. Assembling an ignimbrite: Compositionally defined eruptive packages in the 1912 Valley of Ten Thousand Smokes ignimbrite, Alaska (United States)

    Fierstein, J.; Wilson, C.J.N.


    The 1912 Valley of Ten Thousand Smokes (VTTS) ignimbrite was constructed from 9 compositionally distinct, sequentially emplaced packages, each with distinct proportions of rhyolite (R), dacite (D), and andesite (A) pumices that permit us to map package boundaries and flow paths from vent to distal extents. Changing pumice proportions and interbedding relationships link ignimbrite formation to coeval fall deposition during the first ???16 h (Episode I) of the eruption. Pumice compositional proportions in the ignimbrite were estimated by counts on ???100 lapilli at multiple levels in vertical sections wherever accessible and more widely over most of the ignimbrite surface in the VTTS. The initial, 100% rhyolite ignimbrite package (equivalent to regional fall Layer A and occupying ???3.5 h) was followed by packages with increasing proportions of andesite, then dacite, emplaced over ???12.5 h and equivalent to regional fall Layers B1-B3. Coeval fall deposits are locally intercalated with the ignimbrite and show parallel changes in R:D (rhyolite:dacite) proportions, but lack significant amounts of andesite. Andesite was thus dominantly a low-fountaining component in the eruption column and is preferentially represented in packages filling the VTTS north of the vent. The most extensive packages (3 and 4) occur in B1 and early B2 times where flow mobility and volume were optimized; earlier all-rhyolite flows (Package 1) were highly energetic but less voluminous, while later packages (5-9) were both less voluminous and emplaced at lower velocities. Package boundaries are expressed as one or more of the following: sharp color changes corresponding to compositional variations; persistent finer-grained basal parts of flow units; compaction swales filled by later packages; erosional channels cut by the flows that fill them; lobate accumulations of one package; and (mostly south of the vent) intercalated fall deposit layers. Clear flow-unit boundaries are best developed between

  5. Geochemical of trace elements in volcanics rocks Peninsula Fildes, Fildes Bay Rey Jorge island, south Shetland

    International Nuclear Information System (INIS)

    Masquelin, H.; Vaz Chavez, N.


    The authors present some geochemical data derived from the multielement analysis of three different types of volcanic rocks collected around Fildes Bay on King George Island, South Shetland. Volcanic rocks from Fildes Peninsula Group may be distinguished from those Marian Cove by their hydrothermal alteration. Apparently the correlation between NI ands Cr allows for the observation of the stratigraphic separation of samples of the same kind. Consequently, the correlation between Cu and As show a distinction between Marian Cove propylitised tuffites and both Brecciated Andesites and pyroclastic rock from Fildes Peninsula Group.

  6. Yield strengths of flows on the earth, Mars, and moon. [application of Bingham plastic model to lava flows (United States)

    Moore, H. J.; Arthur, D. W. G.; Schaber, G. G.


    Dimensions of flows on the earth, Mars, and moon and their topographic gradients obtained from remote measurements are used to calculate yield strengths with a view to explore the validity of the Bingham plastic model and determine whether there is a relation between yield strengths and silica contents. Other factors are considered such as the vagaries of natural phenomena that might contribute to erroneous interpretations and measurements. Comparison of yield strengths of Martian and lunar flows with terrestrial flows suggests that the Martian and lunar flows are more akin to terrestrial basalts than they are to terrestrial andesites, trachytes, and rhyolites.

  7. Geochemistry, geochronology and structural geology of the Birimian formations of the Katiola-Marabadiassa region (north-center of Ivory Coast). Magmatic evolution and geodynamical context of palaeo-Proterozoic

    International Nuclear Information System (INIS)

    Doumbia, S.


    Birimian (palaeo-Proterozoic) formations from western Africa are known from being of juvenile origin and dated of 2.1 Ga. However, few studies have been carried out so far on the nature, petrogenesis, and tectonic-metamorphic evolution of these formations, and the geodynamical evolution of the Birimian crust remains an open question. The Katiola-Marabadiassa region offers a clear litho-stratigraphy where the main units and their structural relationships can be recognized (green rocks, andesites, granitoids, sediments). Two generations of granitoids separated by the opening of a sedimentary basin are identified thanks to the petrographic, geochemical, geochronological and structural data. The first, of Archean type, is dated at 2123-2108 Ma and cuts the green rock belts in a diapiric way. The second, dated at about 2097 Ma comprises leucogranite batholites which cut the discordant overlying sedimentary formations. Thus, 3 volcanism phases can be recognized: a T-MORB type tholeiitic volcanism (the green rock belts), a rhyodacitic calc-alkaline volcanism with granitoid plutons, and an andesitic volcanism interstratified with the basin sediments. The general metamorphism is of green-schist facies. An intermediate model between the archaic Archean processes and the modern collision processes is proposed for the formation of the Birimian crust. (J.S.)

  8. Petrogenesis and tectonic implications of Late Devonian arc volcanic rocks in southern Beishan orogen, NW China: Geochemical and Nd-Sr-Hf isotopic constraints (United States)

    Guo, Qian-Qian; Chung, Sun-Lin; Xiao, Wen-Jiao; Hou, Quan-Lin; Li, Shan


    Late Devonian (ca. 370 Ma) volcanic rocks provide important information about the nature of magmatism during the tectonic transition between the Early and Late Paleozoic in the Beishan orogen, southern Central Asian Orogenic Belt. They are predominantly an andesitic-dacitic-rhyolitic assemblage, characterized by alkali contents ranging from slightly calcic to slightly alkaline. The rhyolitic rocks are generally ferroan, whereas the andesitic rocks are magnesian. These volcanic rocks exhibit similar trace element characteristics to those of continental arcs. Strongly negative εNd(t) values (- 2.8 to - 3.6) and high Sr isotopic compositions (initial 87Sr/86Sr = 0.7036-0.7108) suggest that they are mainly derived from an ancient crust. However, the positive zircon εHf(t) values (+ 1.4 to + 16.4) support the role of juvenile components in their genesis, indicating the significant input of new mantle-derived magmas. These characteristics imply a hybrid derivation, from an ancient crustal source with the addition of juvenile materials during magma genesis, or perhaps heterogeneous contamination or hybridization during magma emplacement. Combined with the regional geology, our results indicate that the Late Devonian magmatism resulted from a southward retreat of the subduction zone, which records significant continental crustal growth in a transitional arc or an accretionary arc setting. The distinct geochemical compositions, especially the Nd-Hf isotope decoupling of the Dundunshan volcanic rocks, imply a significant change in the geodynamic setting in the Late Paleozoic.

  9. High resolution CSMT method for shallow structure; Senjo ochi ni okeru kobunkaino denjiho tansa

    Energy Technology Data Exchange (ETDEWEB)

    Yamane, K.; Takasugi, S. [GERD Geothermal Energy Research and Development Co. Ltd., Tokyo (Japan); Inazaki, S. [Geological Survey of Japan, Tsukuba (Japan); Sasaki, Y.


    Electromagnetic exploration methods and seismic reflection methods are conducted for the study of applicability of geophysical exploration to shallow layer geological survey. In the study, four north-south traverse lines are set in 400mtimes200m grassland. Tensor type CSMT methods are employed, a CSMT method using 96kHz-1kHz artificial magnetic fields and an MT method using 1kHz-10kHz natural magnetic fields, for the determination of resistivity distribution in the ground. Distributed in the site are a surface layer composed of gravel-containing sand and silt, andesitic fractured lava, and massive andesite, and the exploration reaches several tens of meters below the surface. The results of CSMT measurements are found to be in agreement with reflection profiles acquired simultaneously with these CSMT measurements. It is found, furthermore, that CSMT profiles help identify reflection waveforms in a domain where reflection is obscure. It is also found that electromagnetic methods are effective in fault logging because they are very sensitive to porosity, or the amount of pore water, which is higher in a domain with subsurface cracks than in the neighborhood without cracks. 1 ref., 4 figs.

  10. The off-crust origin of granite batholiths

    Directory of Open Access Journals (Sweden)

    Antonio Castro


    Full Text Available Granitod batholiths of I-type features (mostly granodiorites and tonalites, and particularly those forming the large plutonic associations of active continental margins and intracontinental collisional belts, represent the most outstanding magmatic episodes occurred in the continental crust. The origin of magmas, however, remains controversial. The application of principles from phase equilibria is crucial to understand the problem of granitoid magma generation. An adequate comparison between rock compositions and experimental liquids has been addressed by using a projected compositional space in the plane F(Fe + Mg–Anorthite–Orthoclase. Many calc-alkaline granitoid trends can be considered cotectic liquids. Assimilation of country rocks and other not-cotectic processes are identified in the projected diagram. The identification of cotectic patterns in batholith implies high temperatures of magma segregation and fractionation (or partial melting from an intermediate (andesitic source. The comparison of batholiths with lower crust granulites, in terms of major-element geochemistry, yields that both represent liquids and solid residues respectively from a common andesitic system. This is compatible with magmas being formed by melting, and eventual reaction with the peridotite mantle, of subducted mélanges that are finally relaminated as magmas to the lower crust. Thus, the off-crust generation of granitoids batholiths constitutes a new paradigm in which important geological implications can be satisfactorily explained. Geochemical features of Cordilleran-type batholiths are totally compatible with this new conception.

  11. The Ahuachapan geothermal field, El Salvador: Reservoir analysis

    Energy Technology Data Exchange (ETDEWEB)

    Aunzo, Z.; Bodvarsson, G.S.; Laky, C.; Lippmann, M.J.; Steingrimsson, B.; Truesdell, A.H.; Witherspoon, P.A. (Lawrence Berkeley Lab., CA (USA); Icelandic National Energy Authority, Reykjavik (Iceland); Geological Survey, Menlo Park, CA (USA); Lawrence Berkeley Lab., CA (USA))


    The Earth Sciences Division of Lawrence Berkeley Laboratory (LBL) is conducting a reservoir evaluation study of the Ahuachapan geothermal field in El Salvador. This work is being performed in cooperation with the Comision Ejecutiva Hidroelectrica del Rio Lempa (CEL) and the Los Alamos National Laboratory (LANL). This report describes the work done during the first year of the study (FY 1988--89), and includes the (1) development of geological and conceptual models of the field, (2) evaluation of the initial thermodynamic and chemical conditions and their changes during exploitation, (3) evaluation of interference test data and the observed reservoir pressure decline, and (4) the development of a natural state model for the field. The geological model of the field indicates that there are seven (7) major and five (5) minor faults that control the fluid movement in the Ahuachapan area. Some of the faults act as a barrier to flow as indicated by large temperature declines towards the north and west. Other faults act as preferential pathways to flow. The Ahuachapan Andesites provide good horizontal permeability to flow and provide most of the fluids to the wells. The underlying Older Agglomerates also contribute to well production, but considerably less than the Andesites. 84 refs.

  12. Black dimensional stones: Geology, technical properties and deposit characterization of the dolerites from Uruguay (United States)

    Morales Demarco, M.; Oyhantçabal, P.; Stein, K.-J.; Siegesmund, S.


    Dimensional stones with a black color occupy a prominent place on the international market. Uruguayan dolerite dikes of andesitic and andesitic-basaltic composition are mined for commercial blocks of black dimensional stones. A total of 16 dikes of both compositions were studied and samples collected for geochemical and petrographical analysis. Color measurements were performed on different black dimensional stones in order to compare them with the Uruguayan dolerites. Samples of the two commercial varieties (Absolute Black and Moderate Black) were obtained for petrophysical analysis (e.g. density, porosity, uniaxial compressive strength, tensile strength, etc.). Detailed structural analyses were performed in several quarries. Geochemistry and petrography determines the intensity of the black color. When compared with commercial samples from China, Brazil, India and South Africa, among others, the Uruguayan dolerite Absolute Black is the darkest black dimensional stone analyzed. In addition, the petrophysical properties of the Uruguayan dolerites make them one of the highest quality black dimensional stones. Structural analyses show that five joint sets have been recognized: two sub-vertical joints, one horizontal and two diagonal. These joint sets are one of the most important factors that control the deposits, since they control the block size distribution and the amount of waste material.

  13. Volcanic sequence in Late Triassic – Jurassic siliciclastic and evaporitic rocks from Galeana, NE Mexico

    International Nuclear Information System (INIS)

    Cruz-Gómez, E.M.; Velasco-Tapia, F.; Ramírez-Fernández, J.A.; Jenchen, U.; Rodríguez-Saavedra, P.; Rodríguez-Díaz, A.A.; Iriondo, A.


    In northeastern Mexico, volcanic rocks interbedded with Late Triassic–Jurassic siliciclastic and evaporitic strata have been linked to magmatic arcs developed in the Pangea western margin during its initial phase of fragmentation. This work provides new petrographic and geochemical data for volcanism included in the El Alamar and Minas Viejas formations outcropping in the Galeana region. Andesitic dykes and sills (n= 10) in the El Alamar redbeds show SiO2= 47.5–59.1% and MgO= 1.2–4.2%, as well as a geochemical affinity to island arc magmas. This work represents the first report of this tectonic setting in the region. Geological and petrographic evidence suggest that this arc system likely developed after ~220 and before ~193Ma. Trachy-andesitic and rhyodacitic domes (n= 20) associated with the Minas Viejas gypsum-carbonates sequence show SiO2= 61.8–82.7% and MgO= 0.1–4.0% with a tectonic affinity to continental arc. A rhyodacite sample from this region has been dated by U-Pb in zircon, yielding an age of 149.4 ± 1.2Ma (n= 21), being the youngest age related to this arc. Finally, we propose a threestep model to explain the tectonic evolution from Late Triassic island arc to Jurassic continental arc system in the northeastern Mexico.

  14. Thermal Waters in Maguarichi, Chihuahua, Mexico: Influence on Volcanic Rocks Alteration (United States)

    Mascote, C. R.; Espejel-Garcia, V. V.; Villalobos-Aragon, A.


    Piedras de Lumbre, Maguarichi, is located 294 km. to the SW of Chihuahua city, in northern Mexico, in the Sierra Madre Occidental (SMO). The study area is composed of a set of igneous volcanic rocks affected by hydrothermal flows, which apparently run along a fault. Outcrops of hot springs, going out with high pressure, are active all over the year and have no seasonal flow changes. The hydrothermal flows, approximately 20, that reach the surface area at Piedras de Lumbre, are altering the volcanic rocks that surround the hot springs. The study area is highly altered, and evidenced by a variety range of colors in the rock surfaces. The rock samples collected at the region show a crystal growth due to the influence of the salts from the thermal water. The rocks closest to the water openings have a change in its mineralogy, with the mafic minerals, present in andesites, been replaced by carbonates and sulfates, leaving only the clear mineral pseudomorphs. On the crust of the rocks a white layer of material (salts), product of the thermal waters has precipitated. The alteration is perceived only about 5 m. or less around the hot springs. The water, which has high contents of arsenic and sulfates has exerted a strong alteration in rhyolitic and andesitic rocks.

  15. A New Sample Transect through the Sierra Madre Occidental Silicic Large Igneous Province in Southern Chihuahua State, Mexico: First Stratigraphic, Petrologic, and Geochemical Results (United States)

    Andrews, G. D.; Davila Harris, P.; Brown, S. R.; Anderson, L.; Moreno, N.


    We completed a field sampling transect across the northern Sierra Madre Occidental silicic large igneous province (SMO) in December 2013. Here we present the first stratigraphic, petrological, and geochemical data from the transect between Hidalgo del Parral and Guadalupe y Calvo, Chihuahua, Mexico. This is the first new transect across the SMO in 25 years and the only one between existing NE - SW transects at Chihuahua - Hermosillo and Durango - Mazatlan. The 245 km-long transect along Mexican Highway 24 crosses the boundary between the extended (Basin and Range) and non-extended (Sierra Madre Occidental plateau) parts of the SMO, and allows sampling of previously undescribed Oligocene (?) - early Miocene (?) rhyolitic ignimbrites and lavas, and occasional post-rhyolite, Miocene (?) SCORBA basaltic andesite lavas. 54 samples of rhyolitic ignimbrites (40) and lavas (7), and basaltic andesite lavas (7) were sampled along the transect, including 8 canyon sections with more than one unit. The ignimbrites are overwhelming rhyodacitic (plagioclase and hornblende or biotite phyric) or rhyolitic (quartz (+/- sanidine) in additon to plagioclase and hornblende or biotite phyric) and sparsely to highly phyric. Preliminary petrographic (phenocryst abundances) and geochemical (major and trace element) will be presented and compared to existing data from elsewhere in the SMO. Future work will include U-Pb zircon dating and whole rock and in-zircon radiogenic isotopes analyses.

  16. Geochemistry of the Bossoroca greenstone belt, Southernmost Brazil

    International Nuclear Information System (INIS)

    Koppe, J.C.; Hartmann, L.A.


    The Bossoroca greenstone belt is situated in the center of the State of Rio Grande do Sul and has a north-south extension of 18 Km and an east-west of 12 Km. It comprises two sequences. The lower Arroio Lajeadinho Sequence is made up of ultramafic schists and serpentinites, besides amphibolite, meta basalts and mafic meta-volcanoclastic rocks and banded iron-formation; some chert and graphitic rocks also occur. The upper Campestre Sequence is made up of meta volcanoclastic rocks of basaltic to rhyolitic composition with predominance of andesite. They are N A 2 O-rich (5.0 wt%), K 2 O-poor (0.8 wt%), with high Na/K ratios. The REE patterns are rather flat, with small negative Eu anomaly, similar to andesite from Archean or younger greenstone belts. The major and trace elements in samples from the Campestre Sequence were determined by X-ray fluorescence analysis and the rare earth elements by induced coupled plasma. (author)

  17. Tectonic setting of Late Cenozoic gold mineralization in the gold belt of Costa Rica

    Energy Technology Data Exchange (ETDEWEB)

    Deruyter, V.D.


    The Gold Belt of Costa Rica is a northwest-elongated zone 15 km wide by 120 km long containing numerous auriferous quartz veins and pyritic silicified patterns upon which abundant small mines are developed. Gold veins are related principally to northeast-southwest and north-south striking, steeply dipping faults. Higher grade ore and thicker veins invariably occur at intersections of these fracture orientations, indicating simultaneous opening at the time of gold introduction. Restriction of gold veins to the northwest-trending arc of Miocene Aguacate Group andesite volcanic rocks, a product of Cocos Plate subduction, suggested approximately coeval formation, but recognition by the writer of the important role played by 2-5 m.y. old altered, gold mineralized rhyolite dikes intruded along north-south gold vein structures and intimately involved with high grade ores at the Esperanza Mine and Rio Chiquito prospect, for example, suggest a much younger period of fracturing and gold introduction. The rhyolite intrusions are more brittle and stockwork mineralized than andesite host rocks and form bulk tonnage gold targets. Initiation of right-lateral movement along the north-south Panama Fracture Zone at 5 m.y.a. within the pattern of northeastward Cocos Plate subduction may have tapped rhyolites from subvolcanic magma chambers into new faults.

  18. Thermophysical properties of the Lipari lavas (Southern Tyrrhenian Sea

    Directory of Open Access Journals (Sweden)

    D. Russo


    Full Text Available Results of thermophysical investigations into the lavas of the island of Lipari (Southern Tyrrhenian Sea are presented. Samples selected for laboratory measurements belong to four main magmatic cycles, which produced basaltic-andesitic, andesitic and rhyolitic lavas. The wet-bulk density and the thermal conductivity measured on 69 specimens range from 1900 to 2760 kg m-3 and from 1.02 to 2.88 W m-1 K-1, respectively. Porosity is never negligible and its influence on density is maximum in rhyolites of the third cycle. The thermal conductivity is also influenced by the amount of glass. Rhyolitic obsidians show values lower than other rhyolites, although the latter rocks have a larger average porosity. The radioactive heat production determined on 36 specimens varies with the rock type, depending on the amount of U, Th and K. In basic lavas of the first cycle its value is 0.95°± 0.30 mW m-3, while in rhyolites of the fourth cycle it attains 6.68°±0.61 mW m-3. A comparison between results of g-ray spectrometry and X-ray fluorescence points out that the assumption of equilibrium in the decay series of the isotopic elements seems fulfilled. The information obtained is useful not only for the interpretation of geophysical surveys but also for the understanding of the geochemical characteristics of lavas.

  19. Mineralogy and geochemistry of xenoliths in the Eocene volcanic rocks from southwest of Jandaq

    Directory of Open Access Journals (Sweden)

    Samineh Rajabi


    Full Text Available The Eocene volcanic rocks from the southwest of the Jandaq (Kuh-e-Godar-e-Siah, Central-East Iran micro-continent are andesitic basalt and andesite in composition. These rocks contain xenoliths with granulitic mineralogy. Mineral assemblage of these xenoliths is plagioclase + phlogopite + corundum + sillimanite + chlorite + phengite with granublastic, poiklioblastic and foliated textures in the pick metamorphic condition. Thermometry of phlogopite in these xenoliths suggests the average temperature 782oC. The characteristics of the xenoliths are consistent with the granolitic facies metamorphism of the Al-saturated Si-undersaturated crustal sediments at the lower crust condition. Melting of these granulites forms the magma which crystallized the S-type granitoids. Differentiation and crystallization of this magma causes the S-type granite formation. Therefore, the S-type granites in the study area are probably generated from melting of the granulites parts of which brought to the surface as xenoliths by Eocene magmatism in south of the Jandaq (Kuh-e-Godar-e-Siah. S-type granites in the study area are located along the Doruneh, Chupanan and Aeirakan faults in the Aeirakan area and Jandaq ophiolite. These granites are the source of uranium, thorium and uranium ore in southwest of the Aeirakan mountain.

  20. Mineral Chemistry and Geochemistry of Volcanic Rocks in The North of Pasinler (Erzurum

    Directory of Open Access Journals (Sweden)

    Oktay KILIÇ


    Full Text Available In the north of Pasinler (Erzurum, Upper Miocene-Pliocene volcanic rocks crop out. These volcanites are composed of basaltic andesite, andesite, dacite, rhyolite lavas and rhyolitic pyroclastics. The rocks show porphyritic, microlitic porphyritic, hyalo-microlitic porphyritic, vitrophyric, glomeroporphyritic, pilotaxitic and hyalopilitic textures. The investigated volcanites contain plagioclase (An29-80, olivine (Fo65-82, clinopyroxene (augite, orthopyroxene (enstatite, amphibole (Mg#: 0.57-0.71, biotite (phlogopite: 0.44-0.47, annite: 0.33-0.37, sanidine, quartz and opaque mineral (titano-magnetite and ilmenite. The volcanic rocks are calc-alkaline in character and have medium to high-K contents. Major oxide and trace element variations point out open-system magmatic differentiation in the evolution of rocks. Geochemical data indicate an important role of fractionation of phenocryst phases in the rocks during differentiation process. However, it is considered that assimilation±magma mixing might have accompanied to the process. High LILE (K, Rb, Ba, Th and relatively low HFSE (Nb, Ta, Hf, Zr contents of the rocks indicate that these rocks derived from parental magmas carrying subduction signature.

  1. The Relationship Between Lithology and Slope Morphology in the Tucson Mountains, Arizona.

    Directory of Open Access Journals (Sweden)

    Kamel Khanchoul


    Full Text Available The relationship between lithology and slope morphology is investigated at eight sites on granitic, andesitic, andsedimentary hillslopes in the Tucson Mountains, Arizona. Several methods are used in the study. Topographic profi lesare constructed. Skewness indices, slope length, and mean slope angles of the different slope profi les are computed andcompared with each other. Debris size analysis has permitted for some profi les, the determination of hillfront/piedmontjunctions. The nature and structural characteristics of the bedrock are the ones that determine the hillslope morphologyin this semi-arid region. There are, as a matter of fact, variations in profi les on the same bedrock nature but differentlyexposed. More precise morphologic studies have been also done in comparing the different lithologic pairs. They havepermitted to show some similarities in shapes. The granitic-andesitic slopes and andesiic-sedimentary slopes are thebest comparisons which show the relationship between lithology and slope morphology. The granitic-sedimentary sloperelationship is shown in the hillfront concavities, mountain front and piedmont mean slope angles.

  2. Volcanic sequence in Late Triassic – Jurassic siliciclastic and evaporitic rocks from Galeana, NE Mexico

    Energy Technology Data Exchange (ETDEWEB)

    Cruz-Gómez, E.M.; Velasco-Tapia, F.; Ramírez-Fernández, J.A.; Jenchen, U.; Rodríguez-Saavedra, P.; Rodríguez-Díaz, A.A.; Iriondo, A.


    In northeastern Mexico, volcanic rocks interbedded with Late Triassic–Jurassic siliciclastic and evaporitic strata have been linked to magmatic arcs developed in the Pangea western margin during its initial phase of fragmentation. This work provides new petrographic and geochemical data for volcanism included in the El Alamar and Minas Viejas formations outcropping in the Galeana region. Andesitic dykes and sills (n= 10) in the El Alamar redbeds show SiO2= 47.5–59.1% and MgO= 1.2–4.2%, as well as a geochemical affinity to island arc magmas. This work represents the first report of this tectonic setting in the region. Geological and petrographic evidence suggest that this arc system likely developed after ~220 and before ~193Ma. Trachy-andesitic and rhyodacitic domes (n= 20) associated with the Minas Viejas gypsum-carbonates sequence show SiO2= 61.8–82.7% and MgO= 0.1–4.0% with a tectonic affinity to continental arc. A rhyodacite sample from this region has been dated by U-Pb in zircon, yielding an age of 149.4 ± 1.2Ma (n= 21), being the youngest age related to this arc. Finally, we propose a threestep model to explain the tectonic evolution from Late Triassic island arc to Jurassic continental arc system in the northeastern Mexico.

  3. Lead and strontium isotopic evidence for crustal interaction and compositional zonation in the source regions of Pleistocene basaltic and rhyolitic magmas of the Coso volcanic field, California (United States)

    Bacon, C.R.; Kurasawa, H.; Delevaux, M.H.; Kistler, R.W.; Doe, B.R.


    The isotopic compositions of Pb and Sr in Pleistocene basalt, high-silica rhyolite, and andesitic inclusions in rhyolite of the Coso volcanic field indicate that these rocks were derived from different levels of compositionally zoned magmatic systems. The 2 earliest rhyolites probably were tapped from short-lived silicic reservoirs, in contrast to the other 36 rhyolite domes and lava flows which the isotopic data suggest may have been leaked from the top of a single, long-lived magmatic system. Most Coso basalts show isotopic, geochemical, and mineralogic evidence of interaction with crustal rocks, but one analyzed flow has isotopic ratios that may represent mantle values (87Sr/86Sr=0.7036,206Pb/204Pb=19.05,207Pb/204Pb=15.62,208Pb/204Pb= 38.63). The (initial) isotopic composition of typical rhyolite (87Sr/86Sr=0.7053,206Pb/204Pb=19.29,207Pb/204Pb= 15.68,208Pb/204Pb=39.00) is representative of the middle or upper crust. Andesitic inclusions in the rhyolites are evidently samples of hybrid magmas from the silicic/mafic interface in vertically zoned magma reservoirs. Silicic end-member compositions inferred for these mixed magmas, however, are not those of erupted rhyolite but reflect the zonation within the silicic part of the magma reservoir. The compositional contrast at the interface between mafic and silicic parts of these systems apparently was greater for the earlier, smaller reservoirs. ?? 1984 Springer-Verlag.

  4. Les grandes étapes d'évolution d'un volcan andésitique composite: Exemple du Nevado de Toluca (Méxique) (United States)

    Cantagrel, J. M.; Robin, C.; Vincent, P.


    The Nevado de Toluca, in the middle of the Mexican volcanic belt, has been built by two very dissimilar phases. The first one that lasted more than one million years is mainly andesitic. Numerous massive and autobrecciated lava flows of this phase pass outwards into thick conglomeratic formations. The volume of this primitive volcano represents the essential part of the Nevado. After an intense periode of erosion, the second phase is of very short duration (about 100.000 years) and is dacitic in nature. Three main episode can be distinguished: 1. Eruption of important ash and pumice pyroclastic flows related to caldera collapse above a shallow magmatic reservoir. 2. Extrusions of several dacitic domes within and outside the caldera with numerous associated «nuées ardentes» surrounding the volcano. 3. Plinian eruption leading to widespread pumiceous air-fall and to the opening of the present crater inside the caldera. Extrusion of a new small dacitic dome and late phreatic explosions. This second sequence of events can be interpreted as the progressive emptying of the crustal magmatic chamber without refilling by a new magma supply. The most recent activity in the area is represented by monogenic cones and flows of basic andesites outside the central vent system of the Nevado.

  5. Multivariate Analysis, Mass Balance Techniques, and Statistical Tests as Tools in Igneous Petrology: Application to the Sierra de las Cruces Volcanic Range (Mexican Volcanic Belt) (United States)

    Velasco-Tapia, Fernando


    Magmatic processes have usually been identified and evaluated using qualitative or semiquantitative geochemical or isotopic tools based on a restricted number of variables. However, a more complete and quantitative view could be reached applying multivariate analysis, mass balance techniques, and statistical tests. As an example, in this work a statistical and quantitative scheme is applied to analyze the geochemical features for the Sierra de las Cruces (SC) volcanic range (Mexican Volcanic Belt). In this locality, the volcanic activity (3.7 to 0.5 Ma) was dominantly dacitic, but the presence of spheroidal andesitic enclaves and/or diverse disequilibrium features in majority of lavas confirms the operation of magma mixing/mingling. New discriminant-function-based multidimensional diagrams were used to discriminate tectonic setting. Statistical tests of discordancy and significance were applied to evaluate the influence of the subducting Cocos plate, which seems to be rather negligible for the SC magmas in relation to several major and trace elements. A cluster analysis following Ward's linkage rule was carried out to classify the SC volcanic rocks geochemical groups. Finally, two mass-balance schemes were applied for the quantitative evaluation of the proportion of the end-member components (dacitic and andesitic magmas) in the comingled lavas (binary mixtures). PMID:24737994

  6. Multivariate Analysis, Mass Balance Techniques, and Statistical Tests as Tools in Igneous Petrology: Application to the Sierra de las Cruces Volcanic Range (Mexican Volcanic Belt

    Directory of Open Access Journals (Sweden)

    Fernando Velasco-Tapia


    Full Text Available Magmatic processes have usually been identified and evaluated using qualitative or semiquantitative geochemical or isotopic tools based on a restricted number of variables. However, a more complete and quantitative view could be reached applying multivariate analysis, mass balance techniques, and statistical tests. As an example, in this work a statistical and quantitative scheme is applied to analyze the geochemical features for the Sierra de las Cruces (SC volcanic range (Mexican Volcanic Belt. In this locality, the volcanic activity (3.7 to 0.5 Ma was dominantly dacitic, but the presence of spheroidal andesitic enclaves and/or diverse disequilibrium features in majority of lavas confirms the operation of magma mixing/mingling. New discriminant-function-based multidimensional diagrams were used to discriminate tectonic setting. Statistical tests of discordancy and significance were applied to evaluate the influence of the subducting Cocos plate, which seems to be rather negligible for the SC magmas in relation to several major and trace elements. A cluster analysis following Ward’s linkage rule was carried out to classify the SC volcanic rocks geochemical groups. Finally, two mass-balance schemes were applied for the quantitative evaluation of the proportion of the end-member components (dacitic and andesitic magmas in the comingled lavas (binary mixtures.

  7. Preliminary geochronological data of the Morro Agudo de Goias Dike Swarm

    International Nuclear Information System (INIS)

    Tomazzoli, Edison Ramos; Nilson, Ariplinio Antonio


    The Morro Agudo Dyke Swarm consists of mafic and ultramafic dykes and ultramafic dykes and stocks that intrude Archean granite-gneiss terranes of the Goias Massif. The dyke swarm was subdivided into five rock groups: Group I-basaltic andesite in dykes; Group II-metadiabase, diabase, metagabbro and amphibolite in dykes: Group III-metadiabase associated with-meta ultramafic rocks in the same dyke; Group IV-meta ultramafic rocks in dykes; Group V-meta ultramafic rocks in stocks. Four basaltic andesite dyke samples were dated using the K-Ar whole-rock method, yielding 2,412 ± 30 Ma, 2,403 ± 48 Ma, 2,254 ± Ma and 2,006 ±45 Ma ages. A Sm-Nd isochronic diagram for Group III mafic-ultramafic dyke yielded a 2,331 ± 101 Ma age with 0.50976 initial ratio. It is believed that this age may be extensive to the other mafic-ultramafic dykes of the dyke swarm. (author)

  8. Geochemical provenance of anomalous metal concentrations in stream sediments in the Ashton 1:250,000 quadrangle, Idaho/Montana/Wyoming

    International Nuclear Information System (INIS)

    Shannon, S.S. Jr.


    Stream-sediment samples from 1500 sites in the Ashton, Idaho/Montana/Wyoming 1:250,000 quadrangle were analyzed for 45 elements. Almost all samples containing anomalous concentrations (exceeding one standard deviation above the mean value of any element) were derived from drainage basins underlain by Quaternary rhyolite, Tertiary andesite or Precambrian gneiss and schist. Aluminum, barium, calcium, cobalt, iron, nickel, magnesium, scandium, sodium, strontium, and vanadium have no andesite provenance. Most anomalous manganese, europium, hafnium, and zirconium values were derived from Precambrian rocks. All other anomalous elemental concentrations are related to Quaternary rhyolite. This study demonstrates that multielemental stream-sediment analyses can be used to infer the provenance of stream sediments. Such data are available for many parts of the country as a result of the National Uranium Resource Evaluation. This study suggests that stream-sediment samples collected in the Rocky Mountains can be used either as pathfinders or as direct indicators to select targets for mineral exploration for a host of metals

  9. Gold in primary high thermal transformations of the Au porphyry deposit Biely vrch

    International Nuclear Information System (INIS)

    Kozak, J.; Kodera, P.; Lexa, J.; Chovan, M.


    Porphyry gold deposit Biely vrch is situated in northern part of the Javorie stratovolcano in eastern part of Central Slovakia Volcanic Field. Intrusion of diorite to andesite porphyry with andesites is affected by hydrothermal alterations with dominant intermediate argillic alteration. Accumulations of gold are spatially associated with stockwork, formed by different types of quartz veinlets. Gold grains occur in altered rocks in the vicinity of quartz veinlets and rarely also as inclusions in vein. Analysed gold grains are chemically very homogenous and have fineness between 87 to 99.50 wt % Au while silver is the only significant element in addition to gold. In deeper parts of the deposit gold also occurs associated with K and Ca-Na silicate alteration which confirms precipitation of gold already in early stages of the hydrothermal system from high salinity Fe-K rich salt melt based on analyses of corresponding fluid inclusions. Difference in the fineness of gold is not significant between primary and secondary hydrothermal alterations. The highest fineness of gold (more than 99 wt %) in advanced argillic alteration is probably caused by remobilisation by acidic hydrothermal fluids. (authors)

  10. The Chahnaly low sulfidation epithermal gold deposit, western Makran volcanic arc, southeastern Iran (United States)

    Sholeh, Ali; Rastad, Ebrahim; Huston, David L.; Gemmell, J. Bruce; Taylor, Ryan D.


    The Chahnaly low-sulfidation epithermal Au deposit and nearby Au prospects are located northwest of the intermittently active Bazman stratovolcano on the western end of the Makran volcanic arc, which formed as the result of subduction of the remnant Neo-Tethyan oceanic crust beneath the Lut block. The arc hosts the Siah Jangal epithermal and Kharestan porphyry prospects, near Taftan volcano, as well as the Saindak Cu-Au porphyry deposit and world-class Reko Diq Cu-Au porphyry deposit, near Koh-i-Sultan volcano to the east-northeast in Pakistan. The host rocks for the Chahnaly deposit include early Miocene andesite and andesitic volcaniclastic rocks that are intruded by younger dacitic domes. Unaltered late Miocene dacitic ignimbrites overlie these rocks. Laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS) U-Pb zircon geochronology data yield ages between 21.8 and 9.9 Ma for the acidic-intermediate regional volcanism. The most recent volcanic activity of the Bazman stratovolcano involved extrusion of an olivine basalt during Pliocene to Quaternary times. Interpretation of geochemical data indicate that the volcanic rocks are synsubduction and calc-alkaline to subalkaline. The lack of a significant negative Eu anomaly, a listric-shaped rare earth element pattern, and moderate La/Yb ratios of host suites indicate a high water content of the source magma.

  11. Late Palaeogene emplacement and late Neogene–Quaternary exhumation of the Kuril island-arc root (Kunashir island constrained by multi-method thermochronometry

    Directory of Open Access Journals (Sweden)

    J. De Grave


    Full Text Available The Kuril islands constitute a volcanic island arc-trench system, stretching from eastern Hokkaido (Japan to Kamchatka (Russia along the northwestern Pacific subduction system. The current arc consists of several volcanic islands mainly with Neogene basement and capped by several, predominantly andesitic, active subduction stratovolcanoes. Kunashir Island is the southwestern-most island of the arc, just off the Hokkaido coast and represents the study area in this paper. The island is composed of a Lower Complex of mainly late Miocene to Pliocene volcanic rocks, covered by an Upper Complex of younger (basaltic andesitic lava flows and tuffs on which currently four active volcanic edifices are built. In the Lower Complex sub-volcanic and deeper-seated intrusives of the so-called Prasolov and Dokuchaev magmatic complexes are found. More differentiated, tonalitic–granodioritic rocks were collected from these small intrusive bodies. An early Oligocene zircon LA-ICP-MS U/Pb age of 31 Ma for the Prasolov Complex was obtained, showing that the basement of Kunashir Island is older than previously thought. Thermochronometry (apatite fission-track and U-Th-Sm/He and zircon U-Th/He analyses further shows that the magmatic basement of the island was rapidly exhumed in the Pleistocene to present levels in a differential pattern, with He-ages ranging from 1.9 to 0.8 Ma. It is shown that the northern section of the island was hereby exhumed more intensely.

  12. Characterization and zircon SHRIMP U-Pb geochronology of the subvolcanic rocks from Yarumalito Porphyry System, Marmato District, Colombia; Caracterizacao e geocronologia SHRIMP U-Pb em zircao das rochas subvulcanicas do sistema porfiro Yarumalito, Distrito de Marmato, Colombia

    Energy Technology Data Exchange (ETDEWEB)

    Henrichs, Isadora A.; Frantz, Jose Carlos; Marques, Juliana C.; Castoldi, Marco S., E-mail:, E-mail:, E-mail: [Universidade Federal do Rio Grande do Sul (UFRS), Porto Alegre, RS (Brazil). Instituto de Geociencias; Ordonez-Carmona, Oswaldo, E-mail: [Universidad Nacional de Colombia, Medellin (Colombia). Facultad de Minas; Sato, Kei, E-mail: [Universidade de Sao Paulo (USP), Sao Paulo, SP (Brazil). Centro de Pesquisas Geocronologicas


    The mining District of Marmato, located in the Central Cordillera, is considered one of the oldest gold districts in Colombia and its exploration dates back to the Inca’s times, being exploited regularly for more than a thousand years. Inserted in this context lies the Yarumalito porphyry system (YPS), characterized to concentrate ore in structure related veins and stockworks. The YPS is related to the Miocene magmatism of the Combia Formation. In this paper, the subvolcanic rocks directly associated with the mineralized zones were described in order to obtain U-Pb ages in zircon to the intrusions. Selected samples from two fertile intrusions, one andesitic (more abundant in the area) and other dioritic (more restricted), were carefully described and dated by SHRIMP. The results points to a very restricted interval for the ages, with weighted average {sup 206}Pb/{sup 238}U varying from 7,00 ± 0,15 Ma for the andesitic porphyry and 6.95 ± 0.16 Ma for the dioritic porphyry. These results constrain the Yarumalito system to the final stages of the Combia magmatism and suggest a brief period for the crystallization of the mineralized subvolcanic rocks in the area and in the Marmato District. (author)

  13. Eruptive parameters and dynamics of the April 2015 sub-Plinian eruptions of Calbuco volcano (southern Chile) (United States)

    Castruccio, Angelo; Clavero, Jorge; Segura, Andrea; Samaniego, Pablo; Roche, Olivier; Le Pennec, Jean-Luc; Droguett, Bárbara


    We conducted geological and petrological analyses of the tephra fallout and pyroclastic density current (PDC) products of the 22-23 April 2015 Calbuco eruptions. The eruptive cycle consisted of two sub-Plinian phases that generated > 15 km height columns and PDCs that travelled up to 6 km from the vent. The erupted volume is estimated at 0.38 km3 (non-DRE), with approximately 90% corresponding to tephra fall deposits and the other 10% to PDC deposits. The erupted products are basaltic-andesite, 54-55 wt.% SiO2, with minor amounts of andesite (58 wt.% SiO2). Despite the uniform composition of the products, there are at least four types of textures in juvenile clasts, with different degrees of vesicularity and types and content of crystals. We propose that the eruption triggering mechanism was either exsolution of volatiles due to crystallization, or a small intrusion into the base of the magma chamber, without significant magma mixing or with a magma compositionally similar to that of the residing magma. In either case the triggering mechanism generated convection and sufficient overpressure to promote the first eruptive phase. The start of the eruption decompressed the chamber, promoting intense vesiculation of the remaining magma and an increase in eruption rate towards the end of the eruption.

  14. Geochemical and Sr-Nd-Pb isotope characteristics of the Miocene to Pliocene volcanic rocks from the Kandilli (Erzurum) area, Eastern Anatolia (Turkey): Implications for magma evolution in extension-related origin (United States)

    Kaygusuz, Abdullah; Aslan, Zafer; Aydınçakır, Emre; Yücel, Cem; Gücer, Mehmet Ali; Şen, Cüneyt


    This paper presents Sr-Nd-Pb isotopic and whole-rock geochemical data of Miocene to Pliocene volcanic rocks in the Eastern Anatolia (Turkey) aiming to unravel their sources and evolutionary history. The wide compositional range of lavas and pyroclastics includes basaltic andesite, basaltic trachyandesite, trachyandesite, andesite and trachydacite. These calc-alkaline volcanics are enriched in large ion lithophile elements and light rare earth elements and depleted in the high field strength elements. Sr-Nd isotope data indicate low values for 87Sr/86Sr(i) (0.70432-0.70464) and high values for 143Nd/144Nd(i) (0.51272-0.51282). Further, these data are within the mantle array of the isotope ratio diagram. The lead (Pb) isotopic compositions (206Pb/204Pb(i) = 18.33 to 18.62, 207Pb/204Pb(i) = 15.51 to 15.60, 208Pb/204Pb(i) = 38.10 to 38.45) reveals the presence of an enriched source. The main petrological processes involved fractional crystallization and the mixing of at least two fractionated magmas having same source characteristics. All evidence supports the findings that the Kandilli volcanic rocks were derived from a partial melting of the both spinel and garnet bearing subcontinental lithospheric mantle, which had been previously metasomatized by mostly fluids derived from subducted slab during the collisional and post-collisional extension-related geodynamic setting in the Eastern Anatolia region of Turkey.

  15. Conditions of formation of the Mavrokoryfi high-sulfidation epithermal Cu-Ag-Au-Te mineralization (Petrota Graben, NE Greece) (United States)

    Voudouris, Panagiotis Christos


    The Mavrokoryfi Cu-Ag-Au-Te prospect, northeastern Greece, consists of atypical, high-sulfidation mineralization where precious metals were introduced contemporaneously with advanced argillic alteration from magmatic vapors. It occurs as veins of massive sulfides in zones of silicic and advanced argillic alteration spatially associated with an andesitic lava dome and hyaloclastites. Mineralogical data demonstrate an unusual ore and gangue mineralogy that is compatible with formation under very oxidizing conditions (log fO2 values of >-31.8) at temperatures of 200°C to 250°C. Oxidizing conditions favored the formation of hypogene lead sulfates (anglesite and barian celestite) instead of galena. Selenian acanthite, cadmian freibergite, and argentian goldfieldite are the main carriers of silver in the deposit and are reported in Greece for the first time. They were deposited at log fS2 of -9 to -7 and log fTe2 values of -9 to -12.5 (250°C). Ag-poor goldfieldite at Mavrokoryfi has up to 3.7 apfu Te and is the most Te-rich goldfieldite yet reported. The mineralization is accompanied by aluminum-phosphate-sulfate minerals of magmatic-hydrothermal origin and an unusual Pb-enrichment. Ore-forming components were likely derived from andesite porphyries.

  16. U-Pb and K-Ar geochronology from the Cerro Empexa Formation, 1st and 2nd Regions, Precordillera, northern Chile

    International Nuclear Information System (INIS)

    Tomlinson, A.J; Martin, M.W; Blanco, N.; Perez de Arce, C


    The Cerro Empexa Formation (Galli, 1957) is a regionally distributed andesitic volcanic and continental sedimentary unit exposed in the Precordillera of the 1st and 2nd Regions of northern Chile. The formation has generally been considered to lie within the Lower or 'mid' Cretaceous, however, this assignment is based on scant, unreliable geochronologic data. Furthermore, there are conflicting interpretations as to whether the unit predates or postdates the first major Mesozoic shortening event affecting northern Chile. Because of the formation's presumed mid-Cretaceous age and its stratigraphic position over older back-arc sedimentary successions, the unit has been interpreted to represent products of the first eastward jump in the Andean magmatic arc from the arc's initial position in the Cordillera de la Costa (Scheuber and Reutter, 1992). In this paper we present the results of mapping and field observations that indicate exposures previously assigned to the Cerro Empexa Formation include two andesitic volcanic units separated by a major unconformity. The Cerro Empexa Formation proper lies above this unconformity. We also present U-Pb zircon and K-Ar geochronology that indicate the Cerro Empexa Formation is latest Cretaceous in its lower levels, and integrate our data with previously reported 40 Ar/ 39 Ar and fission-track data in the Cerros de Montecristo area (Maksaev, 1990; Maksaev and Zentilli, 1999) to show that 1800±600 m of rocks were deposited within ca. 2.5 m.y (au)


    Directory of Open Access Journals (Sweden)

    Anisa Maulina


    Full Text Available Abstract. Mining material of kind C include igneous rocks, sedimentary rocks and metamorphic rocks. These minerals are often used as industrial raw material. Geologically these minerals are to be found in Banjar Regency. Mining material of kind C can increase regional income. Concerning this, mapping of Mining material of kind C distribution is necessary. Method used for this is interpretation of Geological Map of Banjar Regency and stratigraphic analysis. Based on interpretation of geological map, Mining material of kind C found in Banjar Regency include sand, clay, quartz sandstone, quartzite, andesite, granite and serpentinit. Andesite distribution is found in Pitanak and Pauu formation with distributional area of 421 km². Granite distribution is found in Granite Formation with distributional area of 101 km². Quartz sandstone distribution is found in Tanjung Formation with distributional area of 81 km². Serpentinite distribution is found in Manunggul and Ultramafic rocks distribution with distributional area of 941 km². Quartzite distribution is found in Metamorphic Rocks with distributional area of 123 km². Sand and clay are found in Alluvium with distributional area of 1.430 km².   Keywords: Banjar Regency, group C minerals, GIS

  18. Lithostratigraphy of the Grao Para Group, Serra dos Carajas, Brazil

    Energy Technology Data Exchange (ETDEWEB)

    Gibbs, A.K.; Wirth, K.R.


    The Grao para Group (GPG) is the low-grade metavolcanic portion of the largest metasupracrustal fold belt of the eastern Guapore Shield. It hosts the enormous Serra dos Carajas banded iron formations and was considered to be Early Proterozoic in age. Roughly 4-6 km of metavolcanic rocks underlie 300-400 m thick BIF, and more mafic volcanics overlie them. Subalkaline basalts, basaltic andesites and shoshonites predominate. The basalts and andesites have higher K/sub 2/O (1.5-3.0%) than is typical of Archean greenstone belts, and have LREE-enriched patterns. Spilitic alteration, yielding extreme K/Na ratios, is only locally apparent. The chemical compositions of the volcanics, their bimodal character, and isotopic signatures are consistent with their eruption through continental or transitional crust. The surrounding region contains rocks that may comprise an older, more typical Archean greenstone-granite gneiss terrane. Stratigraphic relations with the overlying sandstones, conglomerates, shales, cherts and carbonates require further work. In areal extent and apparent supracontinental setting, the Carajas iron deposits are like Lake Superior and Hamersley deposits; in age and direct association with volcanic rocks they are like Algoma-type sequences. The GPG has analogies with some Proterozoic belts in SW USA, and with younger continental rift deposits. It is also similar to some of the youngest shoshonite-bearing sequences in the Superior Province, but other Archean examples are rare.

  19. The crustal magma storage system of Volcán Quizapu, Chile, and the effects of magma mixing on magma diversity (United States)

    Bergantz, George W.; Cooper, Kari M.; Hildreth, Edward; Ruprecht, Phillipp


    Crystal zoning as well as temperature and pressure estimates from phenocryst phase equilibria are used to constrain the architecture of the intermediate-sized magmatic system (some tens of km3) of Volcán Quizapu, Chile, and to document the textural and compositional effects of magma mixing. In contrast to most arc magma systems, where multiple episodes of open-system behavior obscure the evidence of major magma chamber events (e.g. melt extraction, magma mixing), the Quizapu magma system shows limited petrographic complexity in two large historical eruptions (1846–1847 and 1932) that have contrasting eruptive styles. Quizapu magmas and peripheral mafic magmas exhibit a simple binary mixing relationship. At the mafic end, basaltic andesite to andesite recharge magmas complement the record from peripheral cones and show the same limited range of compositions. The silicic end-member composition is almost identical in both eruptions of Quizapu. The effusive 1846–1847 eruption records significant mixing between the mafic and silicic end-members, resulting in hybridized andesites and mingled dacites. These two compositionally simple eruptions at Volcán Quizapu present a rare opportunity to isolate particular aspects of magma evolution—formation of homogeneous dacite magma and late-stage magma mixing—from other magma chamber processes. Crystal zoning, trace element compositions, and crystal-size distributions provide evidence for spatial separation of the mafic and silicic magmas. Dacite-derived plagioclase phenocrysts (i.e. An25–40) show a narrow range in composition and limited zonation, suggesting growth from a compositionally restricted melt. Dacite-derived amphibole phenocrysts show similar restricted compositions and furthermore constrain, together with more mafic amphibole phenocrysts, the architecture of the magmatic system at Volcán Quizapu to be compositionally and thermally zoned, in which an andesitic mush is overlain by a homogeneous dacitic

  20. Stratigraphy and geochronology of the Comondú Group near Loreto, Baja California sur, Mexico (United States)

    Umhoefer, Paul J.; Dorsey, Rebecca J.; Willsey, Shawn; Mayer, Larry; Renne, Paul


    Upper Oligocene to Middle Miocene volcanic and sedimentary rocks in the Loreto region, Baja California Sur, are widely exposed and make up the Comondú Group as redefined here following McFall. The Comondú Group is part of a volcanic arc and forearc basin that formed along the northwestern margin of Mexico. Regional to detailed scale mapping, stratigraphic analysis, and geochronology in a 10-20-km-wide and 70-km-long belt from the gulf escarpment to the coast near Loreto reveal three main units in the Comondú Group and a composite thickness of ∼1.5-2 km. (1) The lower clastic unit (∼30-19 Ma) contains 200-300 m of fluvial sandstone and conglomerate with probable local eolian deposits and numerous felsic tuffs and basalt flows that accumulated in a forearc basin. (2) The middle breccia and lava flow unit (∼19-15 Ma) is up to 750 m thick and consists of massive andesite breccia that was deposited as proximal debris flows interbedded with minor andesite lava flows. (3) The upper lava flow and breccia unit (∼15-12 Ma) consists almost entirely of up to ∼600 meters of andesite lava flows a few kilometers west of Loreto that are part of a composite volcano. North and south of Loreto for up to 25 km, the unit is composed of andesite lava flows and massive andesite breccia that formed from thick debris flows near that and other volcanic centers. The three units of the Comondú Group in the Loreto area correlated with the Salto, Pelones, and Ricasón formations of the Bahı´a Concepción area. The lower clastic unit of this study is time equivalent to the marine San Gregorio, El Cien, and Isidro formations on the western and southern Baja California peninsula. The middle and upper units of the Loreto area are the proximal equivalent to the type section of the Comondú Group near the village of Comondú. During deposition of the lower part of the Comondú Group, the arc lay to the east on mainland Mexico in the Sierra Madre Occidental, and then migrated to the

  1. Petrological Features and evolution of Post-Collision Volcanism of the Central Part of the Caucasus Segment (within Georgia) (United States)

    Tutberidze, Bezhan


    The study area is located in the central part of the Caucasus - Asia Minor segment of the Alpine folded belt. The subduction geodynamic situation in the Caucasus segment changed to a collision 11 Ma ago in conditions of convergence of the Africa -Arabian and Eurasian continental lithospheric plates, followed by the closure of the Mesezoic ocean Thetys with its oceanic type crust. The first powerful paroxysm of collision subareal volcanism in the central part of the Caucasus segment occured in the volcanic area of South Georgia at the end of the Miocene. The initial stage of its volcanic activity begins with the eruption of pyroclastic material and ends with the eruptions of lava material. The products range in composition from basalts to ryolite. Andesites and dacites are predominant. The second cycle of volcanic paroxysm begins in the Late Pliocene, starting with the eruption of thick areal doleritebasaltic lavas on the Javakheti Plateau - the volcanic area of South Georgia ends with the eruption of lavas of andesitic composition and their pyroclasts. The volcanic processes in the South Georgian volcanic area end in the Middle Pleistocene by the formation of dolerite-basaltic and andesitic lava flows. Volcanic activity in the folded system of the Lesser Caucasus started in the Late Pliocene with the eruption of basalts, andesitebasalts, andesites and their pyroclastic equivalents. Andesites are predominant. Late Miocene volcanism is manifested mainly in the Transcaucasian intermontane area. All volcanic products of the cited area correspond to subalkaline (rarely alkaline) basalts, being represented by short lava flows and their pyroclastic equivalents. The subalkaline basalts of the Transcaucasian intermontane area are close to continental lithospheric intraplate basalts. Volcanism in the folded system of the Greater Caucasus is confined to two enormous regions including the Kazbegi and Keli plateau provinces. The magmatism occurred in 5 episodes at: Late

  2. New U-Pb ages from dykes cross-cutting the Demirci metamorphics, NW Turkey: Implications for multiple orogenic events (United States)

    Sen, Fatih; Koral, Hayrettin; Peytcheva, Irena


    A high-grade metamorphic sequence in the Sünnice Mountains, Bolu, NW Turkey, is represented by migmatitic quartzo-feldspathic gneisses in amphibolite facies called the Demirci metamorphics/paragneisses, and a sequence of low-grade meta-volcanics containing meta-andesites with minor meta-rhyolites and meta-sedimentary rocks called the Yellice meta-volcanics. They are intruded by the Dirgine granite with an age of Upper Ediacaran (576-565 Ma) and are considered a part of the İstanbul-Zonguldak Tectonic Unit. The Demirci paragneisses are also intruded by a number of dykes in various directions, traditionally considered without radiometric dating to have been emplaced in a single magmatic phase in the Eocene related to post-collision regime of the Anatolide-Tauride platform. Mafic-intermediate-felsic dykes cross-cutting the Demirci paragneisses have been investigated in maps of 1/1000 scale, and their U-Pb zircon age, major-trace element and kinematic data have been obtained. The mafics dykes cross-cutting the Yellice meta-volcanics, equivalents of those in the Demirci paragneisses, occur in N400-500E orientations and have calc-alkaline basalt compositions with a subduction signature. The intermediate dykes occur in N650W, N800W orientations and have calc-alkaline basaltic andesite to andesitic compositions with a subduction signature. Some felsics occur in N150W and N800E orientations and have calc-alkaline dacitic compositions with a collisional tectonic setting. Other calc-alkaline granitic dykes occur in N750E orientation and calc-alkaline granitic compositions with a subduction signature. U-Pb LA-ICP-MS dating of zircons yield ages from 485.7±3.6 Ma (i.e. Cambro-Ordovician) for N800E trending dacite dykes; 443.0±5.4 Ma (i.e. Ordovician-Silurian) for N150W trending dacite dykes; 301.0±1.6 Ma (i.e. Upper Pennsylvanian-Carboniferous) for N650W trending basaltic andesite dykes; 268.2±2.4 Ma (i.e. Guadalupian-Permian) for N40-500E trending basalt dykes; 262.9±3

  3. Postglacial eruptive history and geochemistry of Semisopochnoi volcano, western Aleutian Islands, Alaska (United States)

    Coombs, Michelle L.; Larsen, Jessica F.; Neal, Christina A.


    Semisopochnoi Island, located in the Rat Islands group of the western Aleutian Islands and Aleutian volcanic arc, is a roughly circular island composed of scattered volcanic vents, the prominent caldera of Semisopochnoi volcano, and older, ancestral volcanic rocks. The oldest rocks on the island are gently radially dipping lavas that are the remnants of a shield volcano and of Ragged Top, which is an eroded stratocone southeast of the current caldera. None of these oldest rocks have been dated, but they all are likely Pleistocene in age. Anvil Peak, to the caldera’s north, has the morphology of a young stratocone and is latest Pleistocene to early Holocene in age. The oldest recognized Holocene deposits are those of the caldera-forming eruption, which produced the 7- by 6-km caldera in the center of the island, left nonwelded ignimbrite in valleys below the edifice, and left welded ignimbrite high on its flanks. The caldera-forming eruption produced rocks showing a range of intermediate whole-rock compositions throughout the eruption sequence, although a majority of clasts analyzed form a fairly tight cluster on SiO2-variation diagrams at 62.9 to 63.4 weight percent SiO2. This clustering of compositions at about 63 weight percent SiO2 includes black, dense, obsidian-like clasts, as well as tan, variably oxidized, highly inflated pumice clasts. The best estimate for the timing of the eruption is from a soil dated at 6,920±60 14C years before present underlying a thin facies of the ignimbrite deposit on the island’s north coast. Shortly after the caldera-forming eruption, two scoria cones on the northwest flank of the volcano outside the caldera, Ringworm crater and Threequarter Cone, simultaneously erupted small volumes of andesite.The oldest intracaldera lavas, on the floor of the caldera, are andesitic to dacitic, but are mostly covered by younger lavas and tephras. These intracaldera lavas include the basaltic andesites of small Windy cone, as well as the

  4. Eruptive history of Mount Mazama and Crater Lake Caldera, Cascade Range, U.S.A. (United States)

    Bacon, C.R.


    New investigations of the geology of Crater Lake National Park necessitate a reinterpretation of the eruptive history of Mount Mazama and of the formation of Crater Lake caldera. Mount Mazama consisted of a glaciated complex of overlapping shields and stratovolcanoes, each of which was probably active for a comparatively short interval. All the Mazama magmas apparently evolved within thermally and compositionally zoned crustal magma reservoirs, which reached their maximum volume and degree of differentiation in the climactic magma chamber ??? 7000 yr B.P. The history displayed in the caldera walls begins with construction of the andesitic Phantom Cone ??? 400,000 yr B.P. Subsequently, at least 6 major centers erupted combinations of mafic andesite, andesite, or dacite before initiation of the Wisconsin Glaciation ??? 75,000 yr B.P. Eruption of andesitic and dacitic lavas from 5 or more discrete centers, as well as an episode of dacitic pyroclastic activity, occurred until ??? 50,000 yr B.P.; by that time, intermediate lava had been erupted at several short-lived vents. Concurrently, and probably during much of the Pleistocene, basaltic to mafic andesitic monogenetic vents built cinder cones and erupted local lava flows low on the flanks of Mount Mazama. Basaltic magma from one of these vents, Forgotten Crater, intercepted the margin of the zoned intermediate to silicic magmatic system and caused eruption of commingled andesitic and dacitic lava along a radial trend sometime between ??? 22,000 and ??? 30,000 yr B.P. Dacitic deposits between 22,000 and 50,000 yr old appear to record emplacement of domes high on the south slope. A line of silicic domes that may be between 22,000 and 30,000 yr old, northeast of and radial to the caldera, and a single dome on the north wall were probably fed by the same developing magma chamber as the dacitic lavas of the Forgotten Crater complex. The dacitic Palisade flow on the northeast wall is ??? 25,000 yr old. These relatively

  5. Petrography, geochemistry and tectonic setting of Salmabad Tertiary volcanic rocks, southeast of Sarbisheh, eastern Iran

    Directory of Open Access Journals (Sweden)

    Masoumeh Goodarzi


    Full Text Available Introduction The area reviewed and studied in this paper is located 5 km southeast of Sarbisheh city at eastern border of the Lut block (Jung et al., 1983; Karimpour et al., 2011; Richards et al., 2012 in eastern Iran between 59° 47′ and 59° 53′ E longitude and 32°30′ and 32°34′ N latitude. The magmatic activity in the Lut block began in middle Jurassic (165-162 Ma and reached its peak in Tertiary (Jung et al., 1983. Volcanic and subvolcanic rocks of Tertiary age cover over half of Lut block with up to 2000 m thickness and formed due to subduction prior to the collision of the Arabian and Asian plates (Camp and Griffis, 1982; Tirrul et al., 1983; Berberianet et al., 1982. Most of magmatic activity in the Lut block formed in middle Eocene (Karimpour et al., 2011 The andesitic volcanics were erupted together with the dacites and rhyodacites during a time interval of some 50 Ma from early Cretaceous to early Neogene. It can be assumed that the intensity of the volcanic activity was varying significantly during this time span (Jung et al., 1983.Tertiary volcanic rocks (Eocene-Oligocene to Pliocene with intermediate composition associated with pyroclastic rocks cropped out in eastern parts of Salmabad village, southeast of Sarbisheh. The main purpose of this paper is better understand the tectono-magmatic setting of the Tertiary volcanic rocks in southeast of Sarbisheh, eastern Iran based on geochemical characteristics. Materials and methods Eleven samples were analyzed for major elements by inductively coupled plasma (ICP technologies and trace elements were analyzed using inductively coupled plasma mass spectrometry (ICP-MS, following a lithium metaborate/tetraborate fusion and nitric acid total digestion, at the SGS Laboratories, Toronto, Canada. Results In the Salmabad area, Tertiary volcanic rocks with mainly intermediate (andesitic composition are exposed associated with pyroclastic deposits such as tuff, breccia and agglomerate

  6. Paleoproterozoic volcanism in the southern Amazon Craton (Brazil): insight into its origin and deposit textures (United States)

    Roverato, Matteo; Juliani, Caetano


    The Brazilian Amazon craton hosts a primitive volcanic activity that took place in a region completely stable since 1.87 Ga. The current geotectonic context is very different from what caused the huge volcanism that we are presenting in this work. Volcanic rocks in several portions of the Amazon craton were grouped in the proterozoic Uatumã supergroup, a well-preserved magmatic region that covers an area with more than 1,200,000 km2. In this work one specific region is considered, the southwestern Tapajos Gold province (TGP) that is part of the Tapajós-Parina tectonic province (Tassinari and Macambri, 1999). TGP consists of metamorphic, igneous and sedimentary sequences resulted from a ca. 2.10-1.87 Ga ocean-continent orogeny. High-K andesites to felsic volcanic sequences and plutonic bodies, andesitic/rhyolitic epiclastic volcanic rocks and A-type granitic intrusions form part of this volcanism/plutonism. In this work we focus particularly our attention on welded, reomorphic and lava-like rhyolitic ignimbrites and co-ignimbrite brecchas. Fiamme texture of different welding intensity, stretched obsidian fragments, "glassy folds", relict pumices, lithics, rotated crystals of feldspars, bipiramidal quarz, and devetrification spherulites are the common features represented by our samples. Microscopical images are provided to characterize the deposits analyzed during this preliminary research. The lack of continuum outcrops in the field made more difficult the stratigraphic reconstruction, but the superb preservation of the deposits, apparently without any metamorphic evidences (not even low-grade), permits a clearly description of the textures and a differentiation between deposits. A detailed exploration of this ancient andesitic and rhyolitic volcanic activity could contribute greatly to the knowledge of the Amazon territory and in particular for the recognition of the various units that form the supergroup Uatumã, especially in relation to different eruptive

  7. Seismological studies of the plumbing system beneath the Klyuchevskoy volcanic group in Kamchataka, Russia (United States)

    Koulakov, I.; Shapiro, N.; Abkadyirov, I.; Gordeev, E.; Jakovlev, A.; Kugaenko, Y.; Droznin, D.; Droznina, S.; Senyukov, S.; Novgorodova, A.; Kulakov, R.; Deev, E.


    The Klyuchevskoy volcanic group (KVG) is one of largest and most active clusters of subduction-related volcanoes in the World. Within an area of 70 km size, there are 13 closely located stratovolcanoes, of which Klyuchevskoy, Bezymianny, and Tolbachik produced numerous strong eruptions during recent decades. The Klyuchevskoy and Tolbachik recent eruptions produced lavas of basaltic to basaltic-andesitic composition while Bezimyanny is an explosive andesitic volcano. We present a seismological study of the KVG plumbing system. The first part of our study is the tomographic imaging based on data of permanent and temporary seismic stations operated in vicinity of the KVG. Beneath the Klyuchevskoy volcano at depths between 28 and 35 km, we observe an anomaly with very high Vp/Vs ratio collocated with a large cluster of long-period volcanic earthquakes. We propose that this feature represents the top of the mantle magmatic reservoir feeding the KVG. A narrow seismicity cluster beneath the Klyuchevskoy volcano marks a straight vertical conduit bringing basic magma from the deep reservoir at 30 km to the surface. For the Bezymianny volcano, we observe a middle-crust reservoir at 15 km depth, where the light andesitic magma is fractioned and separated. For the Tolbachik volcano, linearly clustered seismicity and seismic anomalies indicate two distinct pathways of magma ascending. In summary, the new seismic model has revealed three different types of plumbing systems explaining the variability of eruption styles in Klyuchevskoy, Bezymyanny and Tolbachik volcanoes. In the second part we study the occurrence of long-period (LP) seismic events occurring within KVG during two years preceding the large eruption of Tolbachik started at the end of 2012. We find two distinct groups of LP sources: events that occurred just below the edifices of the active volcanoes, and events at depths of 30 km in the vicinity of a deep magmatic reservoir. The time histories of these deep and

  8. Vulnerability of Karangkates dams area by means of zero crossing analysis of data magnetic

    Energy Technology Data Exchange (ETDEWEB)

    Sunaryo,, E-mail:, E-mail:; Susilo, Adi [Geophysics Program Study, Physics Dept., Sciences Faculty, University of Brawijaya, Malang (Indonesia)


    Study with entitled Vulnerability Karangkates Dam Area By Means of Zero Crossing Analysis of Data Magnetic has been done. The study was aimed to obtain information on the vulnerability of two parts area of Karangkates dams, i.e. Lahor dam which was inaugurated in 1977 and Sutami dam inaugurated in 1981. Three important things reasons for this study are: 1). The dam age was 36 years old for Lahor dam and 32 years old for Sutami dam, 2). Geologically, the location of the dams are closed together to the Pohgajih local shear fault, Selorejo local fault, and Selorejo limestone-andesite rocks contact plane, and 3). Karangkates dams is one of the important Hydro Power Plant PLTA with the generating power of about 400 million KWH per year from a total of about 29.373MW installed in Indonesia. Geographically, the magnetic data acquisition was conducted at coordinates (112.4149oE;-8.2028oS) to (112.4839oE;-8.0989oS) by using Proton Precession Magnetometer G-856. Magnetic Data acquisition was conducted in the radial direction from the dams with diameter of about 10 km and the distance between the measurements about 500m. The magnetic data acquisition obtained the distribution of total magnetic field value in the range of 45800 nT to 44450 nT. Residual anomalies obtained by doing some corrections, including diurnal correction, International Geomagnetic Reference Field (IGRF) correction, and reductions so carried out the distribution of the total magnetic field value in the range of -650 nT to 700 nT. Based on the residual anomalies, indicate the presence of 2 zones of closed closures dipole pairs at located in the west of the Sutami dam and the northwest of the Lahor dam from 5 total zones. Overlapping on the local geological map indicated the lineament of zero crossing patterns in the contour of residual anomaly contour with the Pohgajih shear fault where located at about 4 km to the west of the Sutami dam approximately and andesite-limestone rocks contact where located

  9. Flank Collapse Assessment At Kick-'em-Jenny Submarine Volcano (Lesser Antilles): A Combined Approach Using Modelling and Experiments (United States)

    Dondin, F. J. Y.; Heap, M. J.; Robertson, R. E. A.; Dorville, J. F. M.; Carey, S.


    In the Lesser Antilles over 52 volcanic landslide episodes have been identified. These episodes serve as a testament to the hazard posed by volcanic landslides to a region composed of many islands that are small independent countries with vulnerable local economies. This study presents a relative slope stability analysis (RIA) to investigate the stability condition of the only active submarine volcano of the Lesser Antilles Arc: Kick-'em-Jenny Submarine Volcano (KeJ). Thus we hope to provide better constraint on the landslide source geometry to help mitigate volcanic landslide hazards at a KeJ. KeJ is located ca. 8 km north of Grenada island. KeJ lies within a collapse scar from a prehistorical flank collapse. This collapse was associated with a voluminous landslide deposit of about 4.4km3 with a 14 km runout. Numerial simulations showed that this event could generate a regional tsunami. We aim to quantify potential initial volumes of collapsed material using a RIA. The RIA evaluates the critical potential failure surface associated with factor of safety (Fs) inferior to unity and compares them to areas of deficit/surplus of mass/volume obtained from the comparison of an high resolution digital elevation model of the edifice with an ideal 3D surface. We use freeware programs VolcanoFit 2.0 and SSAP 4.7. and produce a 3D representation of the stability map. We report, for the first time, results of a Limit Equilibrium Method performed using geomechanical parameters retrieved from rock mechanics tests performed on two rock basaltic-andesite rock samples collected from within the crater of the volcano during the 1-18 November 2013 NA039 E/V Nautilus cruise. We performed triaxial and uniaxial deformation tests to obtain values of strength at the top and bottom of the edifice. We further characterized the permeability and P-wave velocity of the samples collected. The chosen internal structure for the model is composed of three bodies: (i) a body composed of basaltic-andesite

  10. Northernmost Known Outcrop in North America of Lower Cretaceous Porphyritic Ocoite Facies (Ocoa, Chile) at Western Mexico: the Talpa Ocoite (United States)

    Zárate-del Valle, P. F.; Demant, A.


    At Talpa de Allende region in Western Mexico is located the northernmost known outcrop of ocoite facies (andesite): the Talpa ocoite (TO). The ocoite facies consists of an calk-alkaline andesitic rock rich in K and characterized by the presence of megacrysts of plagioclase (An48-65). TO belongs to the so-called Guerrero Terrane composed of plutono-volcanic and volcano-sedimentary sequences of the Alisitos-Teloloapan arc that was accreted to the North American craton at the end of the early Cretaceous (Lapierre et al., 1992, Can. J. Earth Sci. 29. 2478--2489). Geodynamically TO belongs to lithological sequence number IV or "Tecoman" of Tardy et al. (1994, Tectonophysics 230, 49--73). TO in hand-sample shows typical megacrysts (>1 cm) of plagioclase and clinopyroxene in a dark green aphanitic matrix. This andesitic lava has a shoshonitic character as evidenced by chemical composition: SiO_2 TiO_2 Al_2O_3 Fe_2O_3 MnO MgO CaO Na_2O K_2O P_2O_5 LOI % Ba Sr (ppm) 55.64 0.73 16.61 8.39 0.13 3.59 6.40 3.55 2.85 0.36 1.84% 1093 880 Under microscope TO is characterized by a porphyritic texture made of large labradorite phenocrysts (up to 3 cm) and clinopyroxene with a matrix made of plagioclase microlites; TO has been affected by a low grade metamorphism process belonging to the prehnite-pumpellite facies as it happens in Chile (Levi, 1969, Contr. Mineral. and Petrol. 24-1, p. 30--49). Electron microprobe analysis shows that plagioclase (An55-57) is partly transformed into albite (An7-9); clinopyroxene shows a variation in composition from Wo33En41Fs17 to Wo40En44Fs24 and it is transformed towards the margin first into amphibole and then into biotite. TO outcrops located at East of Talpa river are affected by a deep rubefaction process. TO is not characterized by the presence of bitumen as it occurs in Northern Chile (Nova-Muñoz et al., 2001, EUG XI Meeting, OS09 Supo09 PO, 606); TO is related in time with albian-cenomanian volcanogenic massive sulphides of Western Mexico

  11. The onset of the volcanism in the Ciomadul Volcanic Dome Complex (Eastern Carpathians): Eruption chronology and magma type variation (United States)

    Molnár, Kata; Harangi, Szabolcs; Lukács, Réka; Dunkl, István; Schmitt, Axel K.; Kiss, Balázs; Garamhegyi, Tamás; Seghedi, Ioan


    Combined zircon U-Th-Pb and (U-Th)/He dating was applied to refine the eruption chronology of the last 2 Myr for the andesitic and dacitic Pilişca volcano and Ciomadul Volcanic Dome Complex (CVDC), the youngest volcanic area of the Carpathian-Pannonian region, located in the southernmost Harghita, eastern-central Europe. The proposed eruption ages, which are supported also by the youngest zircon crystallization ages, are much younger than the previously determined K/Ar ages. By dating every known eruption center in the CVDC, repose times between eruptive events were also accurately determined. Eruption of the andesite at Murgul Mare (1865 ± 87 ka) and dacite of the Pilişca volcanic complex (1640 ± 37 ka) terminated an earlier pulse of volcanic activity within the southernmost Harghita region, west of the Olt valley. This was followed by the onset of the volcanism in the CVDC, which occurred after several 100s kyr of eruptive quiescence. At ca. 1 Ma a significant change in the composition of erupted magma occurred from medium-K calc-alkaline compositions to high-K dacitic (Baba-Laposa dome at 942 ± 65 ka) and shoshonitic magmas (Malnaş and Bixad domes; 964 ± 46 ka and 907 ± 66 ka, respectively). Noteworthy, eruptions of magmas with distinct chemical compositions occurred within a restricted area, a few km from one another. These oldest lava domes of the CVDC form a NNE-SSW striking tectonic lineament along the Olt valley. Following a brief (ca. 100 kyr) hiatus, extrusion of high-K andesitic magma continued at Dealul Mare (842 ± 53 ka). After another ca. 200 kyr period of quiescence two high-K dacitic lava domes extruded (Puturosul: 642 ± 44 ka and Balvanyos: 583 ± 30 ka). The Turnul Apor lava extrusion occurred after a ca. 200 kyr repose time (at 344 ± 33 ka), whereas formation of the Haramul Mic lava dome (154 ± 16 ka) represents the onset of the development of the prominent Ciomadul volcano. The accurate determination of eruption dates shows that the

  12. Detection of morphological changes in cliff face surrounding a waterfall using terrestrial laser scanning and unmanned aerial system (United States)

    Hayakawa, Yuichi S.; Obanawa, Hiroyuki


    Waterfall or bedrock knickpoint appears as an erosional front in bedrock rivers forming deep v-shaped valley downstream. Following the rapid fluvial erosion of waterfall, rockfalls and gravita-tional collapses often occur in surrounding steep cliffs. Although morphological changes of such steep cliffs are sometimes visually observed, quantitative and precise measurements of their spatio-temporal distribution have been limited due to the difficulties in direct access to such cliffs if with classical measurement methods. However, for the clarification of geomorphological processes oc-curring in the cliffs, multi-temporal mapping of the cliff face at a high resolution is necessary. Re-mote sensing approaches are therefore suitable for the topographic measurements and detection of changes in such inaccessible cliffs. To achieve accurate topographic mapping of cliffs around a wa-terfall, here we perform multi-temporal terrestrial laser scanning (TLS), as well as structure-from-motion multi-view stereo (SfM-MVS) photogrammetry based on unmanned aerial system (UAS). The study site is Kegon Falls in central Japan, having a vertical drop of surface water from top of its overhanging cliff, as well as groundwater outflows from its lower portions. The bedrock is composed of alternate layers of andesite lava and conglomerates. Minor rockfalls in the cliffs are often ob-served by local people. The latest major rockfall occurred in 1986, causing ca. 8-m upstream propa-gation of the waterfall lip. This provides a good opportunity to examine the changes in the surround-ing cliffs following the waterfall recession. Multi-time point clouds were obtained by TLS measure-ment over years, and the three-dimensional changes of the rock surface were detected, uncovering the locus of small rockfalls and gully developments. Erosion seems particularly frequent in relatively weak the conglomerates layer, whereas small rockfalls seems to have occurred in the andesite layers. Also, shadows in the

  13. The timing of compositionally-zoned magma reservoirs and mafic 'priming' weeks before the 1912 Novarupta-Katmai rhyolite eruption (United States)

    Singer, Brad S.; Costa, Fidel; Herrin, Jason S.; Hildreth, Wes; Fierstein, Judy


    The June, 6, 1912 eruption of more than 13 km3 of dense rock equivalent (DRE) magma at Novarupta vent, Alaska was the largest of the 20th century. It ejected >7 km3 of rhyolite, ∼1.3 km3 of andesite and ∼4.6 km3 of dacite. Early ideas about the origin of pyroclastic flows and magmatic differentiation (e.g., compositional zonation of reservoirs) were shaped by this eruption. Despite being well studied, the timing of events that led to the chemically and mineralogically zoned magma reservoir remain poorly known. Here we provide new insights using the textures and chemical compositions of plagioclase and orthopyroxene crystals and by reevaluating previous U-Th isotope data. Compositional zoning of the magma reservoir likely developed a few thousand years before the eruption by several additions of mafic magma below an extant silicic reservoir. Melt compositions calculated from Sr contents in plagioclase fill the compositional gap between 68 and 76% SiO2 in whole pumice clasts, consistent with uninterrupted crystal growth from a continuum of liquids. Thus, our findings support a general model in which large volumes of crystal-poor rhyolite are related to intermediate magmas through gradual separation of melt from crystal-rich mush. The rhyolite is incubated by, but not mixed with, episodic recharge pulses of mafic magma that interact thermochemically with the mush and intermediate magmas. Hot, Mg-, Ca-, and Al-rich mafic magma intruded into, and mixed with, deeper parts of the reservoir (andesite and dacite) multiple times. Modeling the relaxation of the Fe-Mg concentrations in orthopyroxene and Mg in plagioclase rims indicates that the final recharge event occurred just weeks prior to the eruption. Rapid addition of mass, volatiles, and heat from the recharge magma, perhaps aided by partial melting of cumulate mush below the andesite and dacite, pressurized the reservoir and likely propelled a ∼10 km lateral dike that allowed the overlying rhyolite to reach the

  14. Deposits, petrology and mechanism of the 2010-2013 eruption of Kizimen volcano in Kamchatka, Russia (United States)

    Auer, A.; Belousov, A.; Belousova, M.


    Kizimen volcano in Kamchatka is well known as a source of highly heterogeneous poorly mingled magmas ranging from dacites to basaltic andesites. In 2010-2013, the volcano produced its first historical magmatic eruption with the deposition of 0.27 km3 of block and ash pyroclastic flows accompanied by slow extrusion of a 200-m-thick, highly viscous (1010-1011 Pa s) block lava flow with a volume of 0.3 km3. The total volume of erupted magma comprised approximately 0.4 km3 DRE. We provide description of the eruption chronology, as well as the lithology and petrology of eruptive products. The erupted material is represented by banded dacite and high-silica andesite. The dacitic magma was formed during a long dormancy after the previous magmatic eruption several hundred years ago with mineral compositions indicating average pre-eruptive temperatures of 810 °C, fO2 of 0.9-1.6 log units above the nickel-nickel oxide (NNO) buffer and shallow crustal storage conditions at 123 MPa. The silica-rich andesite represents a hybrid magma, which shows signs of recent thermal and compositional disequilibrium. We suggest that the hybrid magma started to form in 1963 when a swarm of deep earthquakes indicated an input of mafic magma from depth into the 6-11-km-deep silicic magma chamber. It took the following 46 years until the magma filling the chamber reached an eruptible state. Poor mingling of the two melts is attributed to its unusually high viscosity that could be associated with the pre-eruptive long-term leakage of volatiles from the chamber through a regional tectonic fault. Our investigations have shown that shallow magma chambers of dormant volcanoes demonstrating strong persistent fumarolic activity can contain highly viscous, degassed magma of evolved composition. Reactivation of such magma chambers by injection of basic magma takes a long time (several decades). Thus, eruption forecasts at such volcanoes should include a possibility of long time lag between a swarm of

  15. Subaqueous early eruptive phase of the late Aptian Rajmahal volcanism, India: Evidence from volcaniclastic rocks, bentonite, black shales, and oolite

    Directory of Open Access Journals (Sweden)

    Naresh C. Ghose


    Full Text Available The late Aptian (118–115 Ma continental flood basalts of the Rajmahal Volcanic Province (RVP are part of the Kerguelen Large Igneous Province, and constitute the uppermost part of the Gondwana Supergroup on the eastern Indian shield margin. The lower one-third of the Rajmahal volcanic succession contains thin layers of plant fossil-rich inter-trappean sedimentary rocks with pyroclasts, bentonite, grey and black shale/mudstone and oolite, whereas the upper two-thirds consist of sub-aerial fine-grained aphyric basalts with no inter-trappean material. At the eastern margin and the north-central sector of the RVP, the volcanics in the lower part include rhyolites and dacites overlain by enstatite-bearing basalts and enstatite-andesites. The pyroclastic rocks are largely felsic in composition, and comprise ignimbrite as well as coarse-grained tuff with lithic clasts, and tuff breccia with bombs, lapilli and ash that indicate explosive eruption of viscous rhyolitic magma. The rhyolites/dacites (>68 wt.% are separated from the andesites (<60 wt.% by a gap in silica content indicating their formation through upper crustal anatexis with only heat supplied by the basaltic magma. On the other hand, partially melted siltstone xenoliths in enstatite-bearing basalts suggest that the enstatite-andesites originated through mixing of the upper crust with basaltic magma, crystallizing orthopyroxene at a pressure-temperature of ∼3 kb/1150 °C. In contrast, the northwestern sector of the RVP is devoid of felsic-intermediate rocks, and the volcaniclastic rocks are predominantly mafic (basaltic in composition. Here, the presence of fine-grained tuffs, tuff breccia containing sideromelane shards and quenched texture, welded tuff breccia, peperite, shale/mudstone and oolite substantiates a subaqueous environment. Based on these observations, we conclude that the early phase of Rajmahal volcanism occurred under predominantly subaqueous conditions. The presence

  16. 6 ka anoxic condition in the Sibuyan Sea Basin, Philippines - possible link with an explosive eruption event? (United States)

    Catane, S. G.; Fernando, A.; Peleo-Alampay, A.; Tejada, M. G.


    Marine tephra layers in Philippine inland seas were studied to evaluate the history of explosive volcanism in the region and their impact on the marine environment. Two discrete andesitic (SiO*blc*2*elc* = 55-63 wt%) tephra layers were found at depths 446.5-448.4 cm and 454.9-455.8 cm in the gravity core MD 3057 recovered during the Marion Dufresne Marco Polo 2 cruise in 2006. The 7m-long core was retrieved from the northern portion of the Sibuyan Sea Basin at 1660 m below sea level. A C-14 age of 6 ka was obtained for the lower tephra using benthic foraminifera collected immediately below the tephra layer. The tephra layers have similar major element compositions and follow the same fractionation trend on the basis of glass geochemistry. Compositions are distinct from the nearby active andesitic volcanoes, Taal and Mayon. Microprobe imaging showed the occurrence of authigenic pyrite within the lower andesitic tephra layer. Pyrite occurs as euhedral crystals or granular masses (framboids), which are isolated particles or foraminiferal infillings. Framboidal pyrite is associated with anoxic environments where anaerobic bacteria reduces SO*blc*4*elc* dissolved in sea water, initiating the formation of H*blc*2*elc*S. H2S reacts with iron in sediments to form pyrite. Anoxic conditions occur in ocean basins with restricted water exchange due to a physical barrier (sill), density stratification or where input of organic material is high. Alternatively, anoxic conditions may have been caused by the death of benthic organisms due to tephra deposition by depriving the organisms of their food supply. The effect of this apparent anoxic event on benthic foraminifera will be analyzed in detail. It is postulated that these anoxic conditions may cause a decline in the benthic foraminifera occurrence. The extent and duration of anoxic condition of the northern part of the Sibuyan Sea Basin 6 ka needs to be clarified because present-day water condition in the basin is normal. If

  17. Geology and radiometric dating of Quaternary monogenetic volcanism in the western Zacapu lacustrine basin (Michoacán, México): implications for archeology and future hazard evaluations (United States)

    Reyes-Guzmán, Nanci; Siebe, Claus; Chevrel, Magdalena Oryaëlle; Guilbaud, Marie-Noëlle; Salinas, Sergio; Layer, Paul


    The Zacapu lacustrine basin is located in the north-central part of the Michoacán-Guanajuato volcanic field (MGVF), which constitutes the west-central segment of the Trans-Mexican Volcanic Belt. Geological mapping of a 395 km2 quadrangle encompassing the western margin of the basin, 40Ar/39Ar and 14C radiometric dating, whole-rock chemical and petrographic analyses of volcanic products provide information on the stratigraphy, erupted volumes, age, and composition of the volcanoes. Although volcanism in the MGVF initiated since at least 5 Ma ago, rocks in the western Zacapu lacustrine basin are all younger than 2.1 Ma. A total of 47 volcanoes were identified and include 19 viscous lava flows ( 40 vol.%), 17 scoria cones with associated lava flows ( 36 vol.%), seven lava shields ( 15 vol.%), three domes ( 6 vol.%), and one maar ( 2 vol.%). Erupted products are dominantly andesites with 42 km3 ( 86 vol.%) followed by 4 km3 of dacite ( 8 vol.%), 1.4 km3 of basaltic trachy-andesite ( 3 vol.%), 1 km3 of basaltic andesite ( 2 vol.%), and 0.14 km3 of rhyolite ( 0.3 vol.%). Eruptive centers are commonly aligned ENE-WSW following the direction of the regional Cuitzeo Fault System. Over time, the high frequency of eruptions and consequent accumulation of lavas and pyroclastic materials pushed the lake's shore stepwise toward the southeast. Eruptions appear to have clustered through time. One cluster occurred during the Late Pleistocene between 27,000 and 21,300 BC when four volcanoes erupted. A second cluster formed during the Late Holocene, between 1500 BC and AD 900, when four closely spaced monogenetic vents erupted forming thick viscous `a'a to blocky flows on the margin of the lacustrine flats. For still poorly understood reasons, these apparently inhospitable lava flows were attractive to human settlement and eventually became one of the most densely populated heartlands of the pre-Hispanic Tarascan civilization. With an average eruption recurrence interval of 900

  18. Sedimentology and geochemistry of surface sediments, outer continental shelf, southern Bering Sea (United States)

    Gardner, J.V.; Dean, W.E.; Vallier, T.L.


    Present-day sediment dynamics, combined with lowerings of sea level during the Pleistocene, have created a mixture of sediments on the outer continental shelf of the southern Bering Sea that was derived from the Alaskan Mainland, the Aleutian Islands, and the Pribilof ridge. Concentrations of finer-grained, higher-organic sediments in the region of the St. George basin have further modified regional distribution patterns of sediment composition. Q-mode factor analysis of 58 variables related to sediment size and composition - including content of major, minor, and trace elements, heavy and light minerals, and clay minerals - reveals three dominant associations of sediment: 1. (1) The most significant contribution, forming a coarse-grained sediment scattered over most of the shelf consists of felsic sediment derived from the generally quartz-rich rocks of the Alaskan mainland. This sediment contains relatively high concentrations of Si, Ba, Rb, quartz, garnet, epidote, metamorphic rock fragments, potassium feldspar, and illite. 2. (2) The next most important group, superimposed on the felsic group consists of andesitic sediment derived from the Aleutian Islands. This more mafic sediment contains relatively high concentrations of Na, Ca, Ti, Sr, V, Mn, Cu, Fe, Al, Co, Zn, Y, Yb, Ga, volcanic rock fragments, glass, clinopyroxene, smectite, and vermiculite. 3. (3) A local group of basaltic sediment, derived from rocks of the Pribilof Islands, is a subgroup of the Aleutian andesite group. Accumulation of fine-grained sediment in St. George basin has created a sediment group containing relatively high concentrations of C, S, U, Li, B, Zr, Ga, Hg, silt, and clay. Sediment of the Aleutian andesite group exhibits a strong gradient, or "plume", with concentrations decreasing away from Unimak Pass and toward St. George basin. The absence of present-day currents sufficient to move even clay-size material as well as the presence of Bering submarine canyon between the Aleutian

  19. The onset and evolution of slab flattening in the central Trans-Mexican volcanic belt (United States)

    Orozco-Esquivel, T.; Ferrari, L.; Manea, V.; Manea, M.


    One of the most intriguing features of the Middle America subduction zone is the horizontal subduction of a segment of the Cocos plate, flanked by slab segments with normal subduction angles of 45°. The flat slab segment extends for about 300 km inland at ~50 km depth, and then sinks into the asthenosphere at a steep angle beneath the present volcanic front of the central Trans-Mexican volcanic belt (TMVB). In Central Mexico, flat subduction is not associated with upper plate shortening because the continental crust is decoupled from the flat slab by a E-W oriented arc, at ca. 270 km from the trench, dominated by basaltic andesitic to andesitic central volcanoes and domes. During the following 10 m.y., the volcanic front of this early TMVB migrated away from the trench, and more siliceous volcanics (andesite to dacite) became dominant. The migration of the arc culminated at ca. 480 km from the trench, and since ca. 8 Ma the volcanic front has migrated backward until its present position at 250 km from the trench. Geochemical data indicate that the contribution of subduction components (fluids, sediment melts) to the magmas decreased as the arc migrated farther from the trench. This behavior abruptly changed at 12 - 9 Ma with the emplacement of adakitic volcanoes and domes at the farthest distance to the trench. The adakitic volcanics signal the onset of slab melting at the end of the arc migration. The rapid migration of the volcanic front farther from the trench and the emplacement of adakitic lavas at the end of this period are consistent with flattening of the subducted slab from the early to the late Miocene. The onset of slab flattening in central Mexico may have been promoted by (1) the rapid increase in Pacific-Cocos spreading rate from ~4 cm/yr to ~12 cm/yr in the early to middle Miocene; (2) the active overriding of the North America plate over the Cocos plate, leading to trench roll back at 0.5-1 cm/yr; (3) the relatively young age of the subducted slab

  20. Magma Diversity in the Trans-Mexican Volcanic Belt: the role of Mantle Heterogeneities, Slab-derived Fluxes and Crustal Contamination. (United States)

    Schaaf, P.; Valdez, G.; Siebe, C.; Carrasco, G.


    The Plio-Quaternary Trans-Mexican Volcanic Belt (TMVB) is related to subduction of the Cocos and Rivera plates underneath the North American plate. Non-parallelism of the magmatic arc with respect to the trench can be explained by oblique subduction and changes of dip angle. In this contribution we compare geochemical and Sr-Nd-Pb isotope data of five TMVB stratovolcanoes (from east to west: Colima Volcano, Nevado de Toluca, Popocatepetl, La Malinche, and Pico de Orizaba) and associated cinder cones. Volcanic products range in stratovolcanoes from andesites (e.g. Colima, Popocatepetl) to rhyolites (e.g. Pico de Orizaba), and from basalts to andesites in the monogenetic cones. Concentrations of incompatible elements correlate positively with Sr-Nd-Pb isotope ratios from east to west along the arc. 87Sr/86Sr, eNd, and 206Pb/204Pb range from 0.7034-0.7050, +6.9 to minus 1.8, and 18.57-18.78, respectively, displaying considerable differences. In the central TMVB, REE patterns of closely spaced high-Mg basaltic andesites differ substantially. This cannot be explained by fractional crystallization processes or differential partial melting of a homogeneous mantle source. Instead, it points towards small-scale mantle heterogeneities. LILE (e.g. Cs, Rb, Ba, Pb) and HFSE (e.g. Ta, Nb, Zr) display variations of orders in magnitude at different segments along the arc. These variations might correlate with amounts of slab-derived aqueous fluids and intensity of metasomatic reactions between the subducting lithosphere and the overlying mantle wedge. Isotopic ratios of mid-lower crustal xenoliths found in nearly all stratovolcano products reflect the nature of the underlying crust beneath the TMVB. Tertiary-Cretaceous plagiogranites (Colima), Cretaceous limestones (Popocatepetl), and Grenvillian quartzites (Pico de Orizaba)and their increasing radiogenic isotope ratios match well with the observed isotopic signatures of the stratovolcanoes. Moreover, elevated CO2 amounts in

  1. Genesis and gold (Copper) Potential in Darestan-Baghu mining area (South of Damghan)

    International Nuclear Information System (INIS)

    Tajeddin, H. A.; Rashid Nezhad Omran, N.; Babakhani, A. R.


    Darestan-Baghu gold mining area is exposed at about 100 km south of Damghan. The area is a part of Torud-Chahshirin volcano-plutonic belt that crops out as a ho rst with a N E-S W trend in the northern limit Dasht-e-Kavir. The outcrops in the area are Middle-Eocene volcano-pyroclastics with andesite to da cite in composition, which are intruded by a number of intrusive s including granite to granodiorite bodies. Mineralization in Darestan gold occurrence consists of a copper (gold)-bearing silicic vein with 400 meter length occurring within a N-S trending normal fault in andesitic to dacitic- andesitic massive breccia tuff associated with silicic, argillic and propylitic alterations. Mineralization in the vein includes quartz, chalcopyrite, pyrite, gold, specularite, malachite, and iron-hydroxides. Gold mineralization in Baghu vein (at about 3 km N E of Darestan gold occurrence) is as a silicic vein with 700 meter length occurring within a granodiorite-granite sub volcanic with argillic alteration. Mineralization in Baghu vein consists of quartz, pyrite, chalcopyrite, gold, iron oxides and iron-hydroxides, malachite, chalcocite, covellite and tourmaline. Field observations indicate that considerable contents of gold in Darestan area mainly related to sulfide-bearing silicic veins are intruded within N-S normal faults that are generally associated with hydrothermal alteration of argillic, silicic and chloritic (± epi dote) zones. investigation on other mineralized zones of Darestan and Baghu areas suggests a clear genetic relationship between Darestan copper (gold) occurrence and gold-bearing silicic vein of Baghu. Field observations and laboratory studies show a close relationship between the copper (gold) mineralization and late-stage silicic solutions induced from sub volcanic intrusive s with acidic to intermediate composition in Darestan and Baghu districts. Some of the most important lines of evidence are spatial relationship between ore-bearing silicic veins

  2. Electron Microscopy Observation of Biomineralization within Wood Tissues of Kurogaki

    Directory of Open Access Journals (Sweden)

    Kazue Tazaki


    Full Text Available Interactions between minerals and microorganisms play a crucial role in living wood tissues. However, living wood tissues have never been studied in the field. Fortunately, we found several kurogaki (black persimmon; Diospyros kaki trees at Tawara in Kanazawa, Ishikawa, Japan. Here, we report the characterization of kurogaki based on scanning electron microscopy equipped with energy-dispersive spectroscopy (SEM-EDS and transmission electron microscopy (TEM, associated with inductively coupled plasma-mass spectrometry (ICP-MS analyses, X-ray fluorescence analyses (XRF and X-ray powder diffraction (XRD analyses. This study aims to illustrate the ability of various microorganisms associated with biominerals within wood tissues of kurogaki, as shown by SEM-EDS elemental content maps and TEM images. Kurogaki grows very slowly and has extremely hard wood, known for its striking black and beige coloration, referred to as a “peacock pattern”. However, the scientific data for kurogaki are very limited. The black “peacock pattern” of the wood mainly comprises cellulose and high levels of crystal cristobalite. As per the XRD results, the black taproot contains mineralized 7 Å clays (kaolinite, cellulose, apatite and cristobalite associated with many microorganisms. The chemical compositions of the black and beige portions of the black persimmon tree were obtained by ICP-MS analyses. Particular elements such as abundant Ca, Mg, K, P, Mn, Ba, S, Cl, Fe, Na, and Al were concentrated in the black region, associated with Pb and Sr elements. SEM-EDS semi-qualitative analyses of kurogaki indicated an abundance of P and Ca in microorganisms in the black region, associated with Pb, Sr, S, Mn, and Mg elements. On the other hand, XRF and XRD mineralogical data showed that fresh andesite, weathered andesite, and the soils around the roots of kurogaki correlate with biomineralization of the black region in kurogaki roots, showing clay minerals (kaolinite and

  3. Soil organic carbon and nitrogen pools drive soil C-CO2 emissions from selected soils in Maritime Antarctica. (United States)

    Pires, C V; Schaefer, C E R G; Hashigushi, A K; Thomazini, A; Filho, E I F; Mendonça, E S


    The ongoing trend of increasing air temperatures will potentially affect soil organic matter (SOM) turnover and soil C-CO 2 emissions in terrestrial ecosystems of Maritime Antarctica. The effects of SOM quality on this process remain little explored. We evaluated (i) the quantity and quality of soil organic matter and (ii) the potential of C release through CO 2 emissions in lab conditions in different soil types from Maritime Antarctica. Soil samples (0-10 and 10-20cm) were collected in Keller Peninsula and the vicinity of Arctowski station, to determine the quantity and quality of organic matter and the potential to emit CO 2 under different temperature scenarios (2, 5, 8 and 11°C) in lab. Soil organic matter mineralization is low, especially in soils with low organic C and N contents. Recalcitrant C form is predominant, especially in the passive pool, which is correlated with humic substances. Ornithogenic soils had greater C and N contents (reaching to 43.15gkg -1 and 5.22gkg -1 for total organic carbon and nitrogen, respectively). C and N were more present in the humic acid fraction. Lowest C mineralization was recorded from shallow soils on basaltic/andesites. C mineralization rates at 2°C were significant lower than at higher temperatures. Ornithogenic soils presented the lowest values of C-CO 2 mineralized by g of C. On the other hand, shallow soils on basaltic/andesites were the most sensitive sites to emit C-CO 2 by g of C. With permafrost degradation, soils on basaltic/andesites and sulfates are expected to release more C-CO 2 than ornithogenic soils. With greater clay contents, more protection was afforded to soil organic matter, with lower microbial activity and mineralization. The trend of soil temperature increases will favor C-CO 2 emissions, especially in the reduced pool of C stored and protected on permafrost, or in occasional Histosols. Copyright © 2016 Elsevier B.V. All rights reserved.

  4. Geochemistry and Geochronology of the Early Paleoproterozoic Volcanism of the Karelian Craton: Petrogenetic and Geodynamic Implications (United States)

    Bogina, M. M.; Zlobin, V. L.


    The Early Paleoproterozoic time is characterized worldwide by large-scale magmatic, especially volcanic activity, which was related to the onset of global rifting at the Archean-Proterozoic boundary. At the Karelian craton, its volcanic products compose giant nearly submeridional belts several hundreds kilometer long. The Early Paleoproterozoic volcanosedimentary sequences (2-3 km thick) from the bottom upward are made up of coarse-grade mature sediments, predominant pillow-textured and massive lavas, tuffs, and tuffobreccia of basaltic andesites and andesites, which through felsic tuffs grade into quartz porphyries. Two types of basaltic andesites are distinguished. The Type I show MORB-like flat to slightly LREE-depleted or insignificantly LREE-enriched patterns with (La/Sm)N = 0.7-1.5, and (La/Yb)N = 0.35-1.3, and minor negative or absent Eu, Nb, and Ti anomalies. The type II rocks show LREE enrichment relative to HREE, (La/Sm)N = 1.5-3.84 and (La/Yb)N=6.5-11.67, with minor negative to non-existent Eu anomalies (Eu/Eu) = 0.99-1.15, prominent negative Nb and Sr anomalies, and subtle Ti anomaly. Trace element patterns show that the rocks are enriched in LILE relative to HFSE and in LREE relative to HREE. Negative Nb and Ti anomalies could be inherited from a previous subduction event or result from crustal contamination. Nb-Ta-Th systematics can serve in support of the former interpretation, indicating that the rocks exibit "island arc" affinity with low to moderate (Nb/La)N ratio and extremely low (Nb/Th)N ratio. HREE patterns are weakly fractionated, and show no significant depletion, indicating that garnet was absent from the source rocks during generation of the primary magma. The relatively low Ni and Cr contents suggest that the rocks undergone significant fractional crystallization from mantle-derived melts. The upper age limit of the mafic rocks is constrained by the U-Pb SHIRMP zircon age of cross-cutting felsic dike at 2416

  5. Waduk Parangjoho dan Songputri: Alternatif Sumber Erupsi Formasi Semilir di daerah Eromoko, Kabupaten Wonogiri, Jawa Tengah

    Directory of Open Access Journals (Sweden)

    Sutikno Bronto


    Full Text Available Semilir Formation was typically originated from products of a very explosive volcanic activity, i.e. breccias, lapillistones, and tuffs containing abundant pumice. It has a light grey to white colour and high silica andesite to dacite in composition, mainly rich in volcanic glass and quartz. Sedimentary structures of these volcanic rocks are massive, grading, planar bedding, and cross-bedding to antidunes, with grain size varies from ash (≤ 2 mm to lapilli (2 – 64 mm to bomb and block (> 64 mm. The formation is widely distributed from the west side (Pleret and Piyungan areas, Bantul Regency, Special Province of Yogyakarta until Eromoko area in the east (Wonogiri Regency, Jawa Tengah Province. Stratigraphically, the Semilir Formation underlies the Nglanggeran Formation, and overlies the Mandalika Formation in the eastern part and Kebo-Butak Formation in the western part. Geomorphological- and lithological analyses of the Semilir Formation in areas of Parangjoho and Song- putri Dams, Eromoko Sub-regency, Wonogiri Regency indicate that the two depressions were alternatively volcanic sources of the Semilir Formation in the Eromoko area. This is proved by the presence of co-ignimbrite breccias(co-ignimbrite lag fall deposits, that descriptively they are polymict breccias. This rock is characterized by a mixing of pumice and various hard rock fragments that primarily are juvenile materials (volcanic blocks, bombs, accessory-, and accidental rock fragments set in pumice-rich volcanic ash and lapilli sizes. The accessory materials came from older volcanic rocks, whereas the accidental ones were originated from basement rocks. During a caldera forming event or a destruction period of an older composite volcanic cone(s, all older rocks resting above the magma chamber were ejected to the surface by a very high magmatic pressure. Since they were heavier than the juvenile material, most accessory and

  6. From rock to magma and back again: The evolution of temperature and deformation mechanism in conduit margin zones (United States)

    Heap, Michael J.; Violay, Marie; Wadsworth, Fabian B.; Vasseur, Jérémie


    Explosive silicic volcanism is driven by gas overpressure in systems that are inefficient at outgassing. The zone at the margin of a volcanic conduit-thought to play an important role in the outgassing of magma and therefore pore pressure changes and explosivity-is the boundary through which heat is exchanged from the hot magma to the colder country rock. Using a simple heat transfer model, we first show that the isotherm for the glass transition temperature (whereat the glass within the groundmass transitions from a glass to an undercooled liquid) moves into the country rock when the magma within the conduit can stay hot, or into the conduit when the magma is quasi-stagnant and cools (on the centimetric scale over days to months). We then explore the influence of a migrating viscous boundary on compactive deformation micromechanisms in the conduit margin zone using high-pressure (effective pressure of 40 MPa), high-temperature (up to 800 °C) triaxial deformation experiments on porous andesite. Our experiments show that the micromechanism facilitating compaction in andesite is localised cataclastic pore collapse at all temperatures below the glass transition of the amorphous groundmass glass Tg (i.e., rock). In this regime, porosity is only reduced within the bands of crushed pores; the porosity outside the bands remains unchanged. Further, the strength of andesite is a positive function of temperature below the threshold Tg due to thermal expansion driven microcrack closure. The micromechanism driving compaction above Tg (i.e., magma) is the distributed viscous flow of the melt phase. In this regime, porosity loss is distributed and is accommodated by the widespread flattening and closure of pores. We find that viscous flow is much more efficient at reducing porosity than cataclastic pore collapse, and that it requires stresses much lower than those required to form bands of crushed pores. Our study therefore highlights that temperature excursions can result in a

  7. Post-collisional magmatism in the Late Miocene Rodna-Bârgău district (East Carpathians, Romania): Geochemical constraints and petrogenetic models (United States)

    Fedele, Lorenzo; Seghedi, Ioan; Chung, Sun-Lin; Laiena, Fabio; Lin, Te-Hsien; Morra, Vincenzo; Lustrino, Michele


    Post-collisional magmatism in the Late Miocene Rodna-Bârgău subvolcanic district (East Carpathians) gave rise to a wide variety of rock compositions, allowing recognition of four groups of calcalkaline rocks with distinctive petrography, mineral chemistry, whole-rock geochemistry and Sr-Nd-Hf isotope features. New U-Pb zircon datings, together with literature data, indicate that the emplacement of the four rock groups was basically contemporaneous in the 11.5-8 Ma time span. The low potassium group (LKG) includes the most abundant lithotypes of the area, ranging from basaltic andesite to dacite, characterized by K-poor tschermakitic amphibole, weak enrichment in LILE and LREE, relatively low 87Sr/86Sr, coupled with relatively high 143Nd/144Nd and 176Hf/177Hf. The high potassium group (HKG) includes amphibole-bearing microgabbro, amphibole andesite and amphibole- and biotite dacite, with K-richer magnesio-hastingsite to hastingsite amphibole, more marked enrichments in incompatible elements, higher 87Sr/86Sr and lower 143Nd/144Nd and 176Hf/177Hf. These two main rock groups seem to have originated from similar juxtaposed mantle sources, with the HKG possibly related to slightly more enriched domains (with higher H2O reflected by the higher modal amphibole) with respect to LKG (with higher plagioclase/amphibole ratios). The evolution of the two rock series involved also open-system processes, taking place mainly in the upper crust for the HKG, in the lower crust for LKG magmas. In addition, limited occurrences of generally younger strongly evolved peraluminous rhyolites and microgranites (Acid group) and sialic-dominated "leucocratic" andesites and dacites (LAD group) were also recognized to the opposite outermost areas of the district. These two latter rock groups were generated by the melting of a basic metamorphic crustal source (respectively in hydrous and anhydrous conditions), favored by the heat released by mantle melts from the adjoining central area. The

  8. Geochemical characterization of mid-distal Nisyros tephra on Datça peninsula (southwestern Anatolia) (United States)

    Gençalioğlu-Kuşcu, Gonca; Uslular, Göksu


    We present new distal records of tephra deposits that overly the Kos ignimbrite in seven locations of Datça peninsula. Tephra in one of these locations were previously associated with Nisyros Kyra sub-unit based only on the field characteristics. We use different proxies such as field observations, petrography, mineral, glass, and whole-rock chemistry in order to characterize and correlate the previously and recently identified pumice fall deposits on Datça. The total thickness of the fall deposit reaches to 3.5 m. The size of the pumice clasts is generally within the range of lapilli, and they have vitrophyric texture consisting mainly of plagioclase (andesine to labradorite) with scarce clinopyroxene (diopside to augite), olivine (Fo48-50), amphibole (magnesio-hastingsite), and biotite crystals. Amphibole is a ubiquitous phenocryst in all Datça tephra units and used as a criterion for the correlation. Glass major element analyses by EMPA reveal two different groups with andesitic and dacitic compositions. Difference in silica content (up to ca. 4 wt%) detected in the same specimen also designates the heterogeneity in pumice glass. This heterogeneity in glass composition is also supported by the frequent occurrence of banded pumice clasts in Datça tephra. Whole-rock composition of the pumice is mainly andesitic with calc-alkaline affinity. Multi-element patterns on primitive-mantle normalized diagram display typical arc-magmatism signature (i.e. depletion in Nb, Ta, Ti, and P). In order to check and eliminate the potential alternatives, we compared the distal deposits on Datça not only with Kyra, but also with other Nisyros tephra units. Yet, Kyra is the only unit that has comparable depositional characteristics, calcic amphibole crystals, andesitic-dacitic glass and whole-rock chemistry, and distal tephra deposits on neighboring islands (Tilos and Chalki). Therefore, we associate Datça tephra deposits with some proximal Kyra subunits of intermediate

  9. Did the massive magnetite "lava flows" of El Laco (Chile) form by magmatic or hydrothermal processes? New constraints from magnetite composition by LA-ICP-MS (United States)

    Dare, Sarah A. S.; Barnes, Sarah-Jane; Beaudoin, Georges


    The El Laco magnetite deposits consist of more than 98 % magnetite but show field textures remarkably similar to mafic lava flows. Therefore, it has long been suggested that they represent a rare example of an effusive Fe oxide liquid. Field and petrographic evidence, however, suggest that the magnetite deposits represent replacement of andesite flows and that the textures are pseudomorphs. We determined the trace element content of magnetite by laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) from various settings at El Laco and compared them with magnetite from both igneous and hydrothermal environments. This new technique allows us to place constraints on the conditions under which magnetite in these supposed magnetite "lava flows" formed. The trace element content of magnetite from the massive magnetite samples is different to any known magmatic magnetite, including primary magnetite phenocrysts from the unaltered andesite host rocks at El Laco. Instead, the El Laco magnetite is most similar in composition to hydrothermal magnetite from high-temperature environments (>500 °C), such as iron oxide-copper-gold (IOCG) and porphyry-Cu deposits. The magnetite trace elements from massive magnetite are characterised by (1) depletion in elements considered relatively immobile in hydrothermal fluids (e.g. Ti, Al, Cr, Zr, Hf and Sc); (2) enrichment in elements that are highly incompatible with magmatic magnetite (rare earth elements (REE), Si, Ca, Na and P) and normally present in very low abundance in magmatic magnetite; (3) high Ni/Cr ratios which are typical of magnetite from hydrothermal environments; and (4) oscillatory zoning of Si, Ca, Mg, REE and most high field strength elements, and zoning truncations indicating dissolution, similar to that formed in hydrothermal Fe skarn deposits. In addition, secondary magnetite in altered, brecciated host rock, forming disseminations and veins, has the same composition as magnetite from the massive

  10. Late Holocene Peléan-style eruption at Tacaná volcano, Mexico and Guatemala: past, present, and future hazards (United States)

    Macías, J. L.; Espíndola, J. M.; Garcia-Palomo, A.; Scott, K.M.; Hughes, S.; Mora, J C.


    Tacaná volcano, located on the border between Mexico and Guatemala, marks the northern extent of the Central American volcanic chain. Composed of three volcanic structures, it is a volcanic complex that has had periodic explosive eruptions for at least the past 40 k.y. The most recent major eruption occurred at the San Antonio volcano, the youngest volcanic edifice forming the complex, about 1950 yr ago. The Peléan style eruption, issued from the southwest part of the dome, and swept a 30° sector with a hot block and ash flow that traveled about 14 km along the Cahoacán ravine. Deposits from this event are well exposed around the town of Mixcun and were therefore given the name of that town, the Mixcun flow deposit. The Mixcun flow deposit is, in the channel facies, a light gray, massive, thick (>10 m), matrix-supported unit with dispersed lithic clasts of gravel to boulder size, divisible in some sections into a variable number of flow units. The overbank facies is represented by a thin (2 and has a minimum estimated volume of 0.12 km3. Basaltic-andesite inclusions (54% SiO2) and various signs of disequilibrium in the mineral assemblage of the two-pyroxene andesitic products (60%–63% SiO2) suggest that magma mixing may have triggered the eruption. Following deposition of the Mixcun flow deposit andesitic to dacitic (62%–64% SiO2) lava flows were extruded and a dacitic dome (64.4% SiO2) at the San Antonio summit formed. Syn-eruptive and posteruptive lahars flooded the main drainages of the Cahoacán and Izapa-Mixcun valleys in the area of the present city of Tapachula (population 250000) and the pre-Hispanic center of Izapa. Three radiocarbon ages date this event between A.D. 25 and 72 (range ±1σ, 38 B.C.–A.D. 216), which correlates with a halt in construction at Izapa (Hato phase of ca. 50 B.C.–A.D. 100), probably due to temporary abandonment of the city caused by lahars. Another similar event would produce extensive damage to the towns (population

  11. Soil mineral assemblage influences on microbial communities and carbon cycling under fresh organic matter input (United States)

    Finley, B. K.; Schwartz, E.; Koch, B.; Dijkstra, P.; Hungate, B. A.


    The interactions between soil mineral assemblages and microbial communities are important drivers of soil organic carbon (SOC) cycling and storage, although the mechanisms driving these interactions remain unclear. There is increasing evidence supporting the importance of associations with poorly crystalline, short-range order (SRO) minerals in protection of SOC from microbial utilization. However, how the microbial processing of SRO-associated SOC may be influenced by fresh organic matter inputs (priming) remains poorly understood. The influence on SRO minerals on soil microbial community dynamics is uncertain as well. Therefore, we conducted a priming incubation by adding either a simulated root exudate mixture or conifer needle litter to three soils from a mixed-conifer ecosystem. The parent material of the soils were andesite, basalt, and granite and decreased in SRO mineral content, respectively. We also conducted a parallel quantitative stable isotope probing incubation by adding 18O-labelled water to the soils to isotopically label microbial DNA in situ. This allowed us to characterize and identify the active bacterial and archaeal community and taxon-specific growth under fresh organic matter input. While the granite soil (lowest SRO content), had the largest total mineralization, the least priming occurred. The andesite and basalt soils (greater SRO content) had lower total respiration, but greater priming. Across all treatments, the granite soil, while having the lowest species richness of the entire community (249 taxa, both active and inactive), had a larger active community (90%) in response to new SOC input. The andesite and basalt soils, while having greater total species richness of the entire community at 333 and 325 taxa, respectively, had fewer active taxa in response to new C compared to the granite soil (30% and 49% taxa, respectively). These findings suggest that the soil mineral assemblage is an important driver on SOC cycling under fresh

  12. Shear thinning behaviors in magmas (United States)

    Vetere, F. P.; Cassetta, M.; Perugini, D.


    Studies on magma rheology are of fundamental importance to understanding magmatic processes from depth to surface. Since viscosity is one of the most important parameter controlling eruption mechanisms, as well as lava flow emplacement, a comprehensive knowledge on the evolution of magma viscosities during crystallization is required. We present new viscosity data on partly crystalized basalt, andesite and analogue lavas comparable to those erupted on Mercury's northern volcanic plains. High-temperature viscosity measurements were performed using a rotational Anton Paar RheolabQC viscometer head at the PVRG labs, in Perugia (Italy) ( The relative proportion of phases in each experimental run were determined by image analysis on BS-SEM images at different magnifications; phases are glasses, clinopyroxene, spinel, plagioclase for the basalt, plagioclase and spinel for the andesite and pure enstatite and clinopyroxenes, for the analogue Mercury's composition. Glass and crystalline fractions determined by image analysis well correlate with compositions of residual melts. In order to constrain the viscosity (η) variations as a function of crystallinity, shear rate (γ) was varied from 0.1 to 5 s-1. Viscosity vs. time at constant temperature shows a typical S-shape curve. In particular, for basaltic composition η vary from 3.1-3.8 Pa s [log η] at 1493 K and crystallinity of 19 area % as γ vary from 1.0 to 0.1 s-1; the andesite viscosity evolution is 3.2 and 3.7 Pa s [log η] as γ varies from 1 to 0.1 at 1493 K and crystal content of 17 area %; finally, Mercury's analogue composition was investigated at different temperature ranging from 1533 to 1502 K (Vetere et al., 2017). Results, for γ = 0.1, 1.0 and 5.0 s-1, show viscosity variation between 2.7-4.0, 2.5-3.4 and 2.0-3.0 [log η inPa s] respectively while crystallinity vary from 9 to 27 (area %). As viscosity decreases as shear rate increases, these data points to a shear thinning behaviour

  13. Minor and trace element geochemistry of volcanic rocks dredged from the Galapagos spreading center: role of crystal fractionation and mantle heterogeneity. (United States)

    Clague, D.A.; Frey, F.A.; Thompson, G.; Rindge, S.


    A wide range of rock types (abyssal tholeiite, Fe-Ti-rich basalt, andesite, and rhyodacite) were dredged from near 95oW and 85oW on the Galapagos spreading center. Computer modeling of major element compositions has shown that these rocks could be derived from common parental magmas by successive degrees of fractional crystallization. However, the P2O5/K2O ratio implies distinct mantle source compositions for the two areas. These source regions also have different rare earth element (REE) abundance patterns. The sequence of fractionated lavas differs for the two areas and indicates earlier fractionation of apatite and titanomagnetite in the lavas from 95oW. The mantle source regions for these two areas are interpreted to be depleted in incompatible (and volatile?) elements, although the source region beneath 95oW is less severely depleted in La and K. -Authors

  14. Análisis e interpretación de los materiales volcánicos del Cerro de los Frailes (Cabo de Gata. Almería

    Directory of Open Access Journals (Sweden)

    Fernández Soler, J. M.


    Full Text Available The formation of Los Frailes volcano had two stages, which produced amphibole andesites (Frailes-I and two-pyroxene andesites (Frailes-II respectively, Iying on the extension of the dacites and andesites of the southernmost Cabo de Gata volcanoes (Revancha-Sabinal. The FRAILES-I stage is discontinuous, and has mainly produced domes and autoclastic breccias, in addition to an intermediate level of pumice-and-ash flow; this unit has some intercalated sedimentary levels. To the NE it is covered by a formation of sedimentary and hydroclastic rocks. The Frailes-II stage is continuous, and has formed some lava flows, the two summit domes, and sorne pyroclastic rocks of scarcely explosive origin. Other volcanic features are some domes and dikes of biotite-amphibole dacites, which affect to the Frailes-I-group; these are the southern continuation of the dacitic volcanic group of Rodalquilar-Rellana-Garbanzal. The generally accepted idea of a succesion in Cabo de Gata of cycles which started very explosively and ended with subvolcanic extrussions (domes does not seem to be very realistic at least in the building of Los Frailes. A review of geochronological data, and the field disposition of the described materials does not discard the hypothesis that the pyroxene andesites of FrailesI-I might have been formed simultaneously or even than later the ignimbritic dacites of the Rodalquilar group.La formación del volcán de Los Frailes se produjo en dos ciclos, de composiciones andesítica anfibólica (Frailes-I y andesitica de dos piroxenos (Frailes-II, apoyadas sobre la prolongación hacia el este de las andesitas y dacitas del extremo sur de Cabo de Gata (edificio de Revancha-Sabinal-Cabo de Gata. El ciclo Frailes-I es discontínuo y ha formado domos y brechas autoclásticas principalmente, mas un nivel intermedio de colada piroclástica pumítica; este ciclo contiene niveles sedimentarios intercalados. Al NE es cubierto por una formación de rocas

  15. Melting Temperature and Partial Melt Chemistry of H2O-Saturated Mantle Peridotite to 11 Gigapascals (United States)

    Kawamoto; Holloway


    The H2O-saturated solidus of a model mantle composition (Kilborne Hole peridotite nodule, KLB-1) was determined to be just above 1000°C from 5 to 11 gigapascals. Given reasonable H2O abundances in Earth's mantle, an H2O-rich fluid could exist only in a region defined by the wet solidus and thermal stability limits of hydrous minerals, at depths between 90 and 330 kilometers. The experimental partial melts monotonously became more mafic with increasing pressure from andesitic composition at 1 gigapascal to more mafic than the starting peridotite at 10 gigapascals. Because the chemistry of the experimental partial melts is similar to that of kimberlites, it is suggested that kimberlites may be derived by low-temperature melting of an H2O-rich mantle at depths of 150 to 300 kilometers.

  16. The Loma Seca tuff and the Calabozos caldera: a major ash-flow and caldera complex in the southern Andes of central Chile. (United States)

    Hildreth, W.; Grunder, A.L.; Drake, Robert E.


    A composite ring-structure caldera of Late Pleistocene age, 26 X 14km in size, has been discovered and mapped near the Andean crest in central Chile (35o 30'S). Rhyolitic to dacitic zoned ashflow sheets, each representing 150-300 km3 of magma, were erupted 0.8, 0.3 and 0.15 m.y. ago; the youngest of the associated collapses was closely followed by resurgent doming of the caldera floor and the development of a longitudinal graben. Post-caldera eruption of dacite and andesite have persisted into Holocene time and active hot springs are abundant along caldera-marginal and resurgent fault systems, suggesting a significant geothermal energy resource. The ash-flow magmatism has been no less important in this segment of the glaciated S Andes than in the arid central Andes and may well be accounted for by the existence of thicker crust in both regions.- L.H.

  17. Volcanic Eruption Forecasts From Accelerating Rates of Drumbeat Long-Period Earthquakes (United States)

    Bell, Andrew F.; Naylor, Mark; Hernandez, Stephen; Main, Ian G.; Gaunt, H. Elizabeth; Mothes, Patricia; Ruiz, Mario


    Accelerating rates of quasiperiodic "drumbeat" long-period earthquakes (LPs) are commonly reported before eruptions at andesite and dacite volcanoes, and promise insights into the nature of fundamental preeruptive processes and improved eruption forecasts. Here we apply a new Bayesian Markov chain Monte Carlo gamma point process methodology to investigate an exceptionally well-developed sequence of drumbeat LPs preceding a recent large vulcanian explosion at Tungurahua volcano, Ecuador. For more than 24 hr, LP rates increased according to the inverse power law trend predicted by material failure theory, and with a retrospectively forecast failure time that agrees with the eruption onset within error. LPs resulted from repeated activation of a single characteristic source driven by accelerating loading, rather than a distributed failure process, showing that similar precursory trends can emerge from quite different underlying physics. Nevertheless, such sequences have clear potential for improving forecasts of eruptions at Tungurahua and analogous volcanoes.

  18. Major, trace element and isotope geochemistry of historic (1945-1996) eruptions from Ruapehu volcano, New Zealand with implications for open system magmatic processes in arc volcanoes

    Energy Technology Data Exchange (ETDEWEB)

    Gamble, J. [Victoria University of Wellington, (New Zealand). Department of Geology and RSES; Wood, P.; Nakagawa, M. [Taupo Volcano Observatory, Wairakei, (New Zealand). Institute of Geological and Nuclear Sciences; Price, R. [La Trobe University and VIEPS, Bundoora, VIC (Australia). Department of Geology; Smith, I. [University of Auckland, Auckland, (New Zealand). Department of Geology


    Detailed evaluation of the isotope data ({sup 87}Sr/{sup 86}Sr vs {sup 143}Nd/{sup 144}Nd) reveals the 1945 sample as the most radiogenic, with samples from the 1995-96 eruptions overlapping the range of all intervening eruptives. It is suggested that the observed chemical and petrographic variations are best explained by injection of a fresh batch of andesitic magma into the volcano superstructure. This magma batch interacts and mixes with stagnated magma batches from previous events, and leads to abrupt chemical zonation (including reverse zoning) in the phenocryst assemblages. The 1995 - 96 eruptives appear to represent a new cycle of activity, suggesting that there should be no complacency on the monitoring front. Extended abstract. 4 refs., 2 figs.

  19. Rb-Sr and Ar-Ar systematics of Malani volcanic rocks of southwest Rajasthan: evidence for a younger post-crystallization thermal event

    International Nuclear Information System (INIS)

    Rathore, S.S.; Srivastava, R.K.


    A new Rb-Sr age of 779 ± 10 Ma has been obtained for a suite of andesite-dacite-rhyolite from the Malani igneous province of southwestern Rajasthan, dated earlier at 745 ± 10 Ma by Crawford and Compston (1970). The associated basalts may be slightly younger than the felsic volcanics and have a mantle source. The felsic volcanics on the other hand were most probably derived by fractional crystallization of a crustal magma. 40 Ar- 39 Ar systematics of three samples viz., a basalt, a dacite and a rhyolite show disturbed age spectra indicating a thermal event around 500-550 Ma ago. This secondary thermal event is quite wide-spread and possibly related to the Pan-African thermo-tectonic episode observed in the Himalayas and south India. (author). 38 refs., 5 figs., 2 tabs

  20. Age of the Karakoram fault activation: 40Ar-39Ar geochronological study of Shyok suture zone in northern Ladakh, India

    International Nuclear Information System (INIS)

    Bhutani, Rajneesh; Pande, Kanchan; Desai, Nikhil


    Shyok volcanics, from the Shyok suture zone in northern Ladakh, ranging from basalts to andesites are analysed for 40 Ar- 30 Ar isotopic systematics by step heating experiment. All samples, collected along the Nubra river, in the vicinity of Karakoram fault zone, yielded disturbed age spectra, reflecting subsequent tectono-thermal events. However, consistency in the pattern of the age spectra, particularly at the low temperature steps, indicate a strong tectono-thermal event between ∼ 10 to ∼ 20 Ma ago. Mica-segregate from segregate from a sheared granite of Karakoram fault zone near village Murgi has yielded an excellent plateau age of 13.9 ± 0.1 Ma. This age of Karakoram fault activation explains the consistent but disturbed age spectra of Shyok volcanics within the vicinity of the fault zone. The Karakoram fault activation in Shyok suture zone is therefore synchronous with the extensional tectonic regime within the Tibetan plateau. (author)


    Directory of Open Access Journals (Sweden)

    Asmoro Widagdo


    Full Text Available Lawa Cave in Purbalingga Regency is a special type of cave as it formed not at calcareous rocks like at the usual cave. It is formed by lava flow processes. So, it is made of an igneous rock and it has an andesit basaltic rock type. Lawa Cave formed due to lava flow of the volcanic eruption of the Old Slamet Volcano. The rocks composition of Lawa Cave consists of primary minerals that are plagioclase and volcanic glass and some secondary mineral like calcite and ferri oxide which is fill the previous gas pores. Generally, rock fractures in Lawa Cave is formed as primary joint when the lava flow was cooling down, tectonic joints is found very limited. Lawa Cave’s direction is controlled by the flow direction of the melting lava. It’s direction indicate the paleomorphology of the volcano.

  2. A dynamical analysis of the seismic activity of Villarrica volcano (Chile) during September-October 2000

    Energy Technology Data Exchange (ETDEWEB)

    Tarraga, Marta [Departamento de Volcanologia. Museo Nacional de Ciencias Naturales, CSIC, Madrid (Spain)], E-mail:; Carniel, Roberto [Dipartimento di Georisorse e Territorio, Universita di Udine, Via Cotonificio 114, 33100 Udine (Italy)], E-mail:; Ortiz, Ramon; Garcia, Alicia [Departamento de Volcanologia. Museo Nacional de Ciencias Naturales, CSIC, Madrid (Spain); Moreno, Hugo [Observatorio Volcanologico de los Andes del Sur (OVDAS), Servicio Nacional de Geologia y Mineria de Chile (SERNAGEOMIN), Temuco, IX Region (Chile)


    Although Villarrica volcano in Chile is one of the most active in the southern Andes, the literature studying its seismic activity is relatively scarce. An interesting problem recently tackled is the possibility for a regional tectonic event to trigger a change in the volcanic activity of this basaltic to basaltic-andesitic volcano, which is in turn reflected in the time evolution of the properly volcanic seismicity, especially in the form of a continuous volcanic tremor. In this work, we conduct a spectral, dynamical and statistical analysis of the tremor recorded during September and October 2000, in order to characterize the anomalous behaviour of the volcano following a tectonic event recorded on 20th September 2000. The observed dynamical transitions are compared with remote sensing and visual observations describing the changes in the eruptive style of the volcano.

  3. Waning Miocene subduction and arc volcanism in Baja California: the San Luis Gonzaga volcanic field (United States)

    Martín, Arturo; Fletcher, John M.; López-Martínez, Margarita; Mendoza-Borunda, Ramón


    Subduction of the Guadalupe-Magdalena microplate beneath Baja California ended in the middle Miocene, and the last volcanic events in the frontal arc extinguished along the present-day eastern margin of the Baja California peninsula. The San Luis Gonzaga area in the north-central Gulf coast contains one of the younger arc-related volcanic centers in northern Baja California. The volcanic succession contains three sequences. The basal sequence (Group 1) is composed of stratified pyroclastic deposits, up to 500 m thick, and subordinate lava flows. The near-vent facies crop out in tilted fault blocks along the present shoreline, whereas the distal facies are exposed across ˜12 km toward the west and includes epiclastic deposits and at least three ash flow tuffs. This sequence is internally concordant and overlies smooth paleosurface developed on granitic basement, and pinches out across the Gulf escarpment. The Potrero Andesite (Group 2) is a series of dacite to basaltic-andesite lava flows from a shield volcano located ˜15 km west of today's coastline; similar source vents also occurs further south of the San Luis Gonzaga area. A sequence of dacite domes (Group 3) intrudes the near-vent facies of Group 1 and contains subordinate volcanic breccia and minor lava flows that overlie Group 1 sequence. Cross-cutting relationships and the abundance of volcanic breccia associated with the domes suggest that these domes were emplaced as semi-rigid intrusions (spines) with low explosive activity. The San Luis Gonzaga volcanic suite ranges in composition from basaltic andesite to dacite with predominant plagioclase and pyroxene and variable amounts of hornblende. Trace-element patterns indicate calc-alkaline to mildly alkaline magmas with high Ba and low Nb contents. Incompatible-element ratios and mineralogical characteristics suggest different magma batches and/or different amount of crustal assimilation for the three sequences that produced contrasting eruptive styles. A

  4. Age of forming of Laplandian franulites granite-migmatite domes and Pechenga-Imandra-Varzuga greenstone belt (Kola peninsula)

    International Nuclear Information System (INIS)

    Mints, M.V.; Ts'on', O.V.; Sobotovich, Eh.V.


    The stage-by-stage nature of the geological evolution of the green-stone belt of the Pechenga-Imandra-Varzuga and interconnected structures of framework is characterized. U-Pb-, Pb-Sr and Pb-Pb-datings of tectonic events are given. The first rifting stage is 2.8-2.4 billiard years. The second stage is 2.2-1.9 billiard years, compression perio (the formation of tectonic covers of Laplandian granulites and andesite eruption within the belt) is 2.0-1.9 billiard years. The formation of granite migratite cupolas in the Southern and rheomorphism of Archean granitoids in the nothern framework of the Pechenga structure is 2.1-1.95 billiard years. The formation of sulfide copper-nickel ores is 2.1-2.0 billiard years. The competence of possible variants of paleogeodynamic reconstructions is estimated

  5. The post-Laramide clastic deposits of the Sierra de Guanajuato: Compositional implications on the tectono-sedimentary and paleographic evolution

    Directory of Open Access Journals (Sweden)

    R. Miranda-Avilés


    Full Text Available This article presents the results of the study on sedimentation, sedimentary environments, tectono-sedimentary and paleogeographic evolution of post-Laramide clastic deposits and pre-volcanism of the Sierra Madre Occidental in the Sierra de Guanajuato, central Mexico. The Eocene Duarte Conglomerate and Guanajuato Conglomerate were deposited in the middle and distal parts of alluvial fans. The studied rocks are composed of limestone clasts, granite, andesite, metasediments, diorite, and pyroxenite, indicating the erosion of uplifted blocks of the basal complex of the Sierra de Guanajuato (Arperos basin. The petrographic and compositional analysis of limestone shows a textural variation from basin limestones and shallow platform limestones. The shallow platform limestone contain bivalves, brachiopods, gastropods, echinoderms and benthic foraminifera from the Berriasian-Valanginian. The shallow-water limestone corresponds to the boundary of the Arperos basin whose original outcrops currently not outcrop in the Sierra de Guanajuato.

  6. Rock Magnetic and Paleointensity Study of Eastern California's ~83 Ma Golden Bear and Coso Dikes (United States)

    Feldman, M.; Raub, T. D.


    Extraordinary intermediate-composition (Kspar +/- quartz andesite porphyry) dikes are coincident with the end of Sierra Nevada magmatism and crop out on both the east and the west sides of Owens Valley, but offset dextrally by >60 km. If this offset represents ancient (possibly Cretaceous) strike-slip partitioning of Pacific-North America plate boundary strain, then at least one of the south- and east-sited Coso dikes might be expected to be paleomagnetically "identical" to its presumed paleo-contiguous, north- and west-sited Golden Bear partner. Accompanying a directional study by Pluhar and colleagues at CSU-Fresno, we are characterizing magnetic mineralogy, fabric, and thermal lability of Coso dikes and the Golden Bear dike. We are also applying the pTRM difference multi-specimen paleointensity technique to these samples, testing for across-Owens Valley correlation.

  7. Net Acid Production, Acid Neutralizing Capacity, and Associated Mineralogical and Geochemical Characteristics of Animas River Watershed Igneous Rocks Near Silverton, Colorado (United States)

    Yager, Douglas B.; Choate, LaDonna; Stanton, Mark R.


    This report presents results from laboratory and field studies involving the net acid production (NAP), acid neutralizing capacity (ANC), and magnetic mineralogy of 27 samples collected in altered volcanic terrain in the upper Animas River watershed near Silverton, Colo., during the summer of 2005. Sampling focused mainly on the volumetrically important, Tertiary-age volcanic and plutonic rocks that host base- and precious-metal mineralization in the study area. These rocks were analyzed to determine their potential for neutralization of acid-rock drainage. Rocks in the study area have been subjected to a regional propylitic alteration event, which introduced calcite, chlorite (clinochlore), and epidote that have varying amounts and rates of acid neutralizing capacity (ANC). Locally, hydrothermal alteration has consumed any ANC and introduced minerals, mainly pyrite, that have a high net acid production (NAP). Laboratory studies included hydrogen pyroxide (H2O2) acid digestion and subsequent sodium hydroxide (NaOH) titration to determine NAP, and sulfuric acid (H2SO4) acid titration experiments to determine ANC. In addition to these environmental rock-property determinations, mineralogical, chemical, and petrographic characteristics of each sample were determined through semiquantitative X-ray diffractometry (Rietveld method), optical mineralogy, wavelength dispersive X-ray fluorescence, total carbon-carbonate, and inductively coupled plasma?mass spectrometric analysis. An ANC ranking was assigned to rock samples based on calculated ANC quantity in kilograms/ton (kg/t) calcium carbonate equivalent and ratios of ANC to NAP. Results show that talus near the southeast Silverton caldera margin, composed of andesite clasts of the Burns Member of the Silverton Volcanics, has the highest ANC (>100 kg/t calcium carbonate equivalent) with little to no NAP. The other units found to have moderate to high ANC include (a) andesite lavas and volcaniclastic rocks of the San Juan

  8. Upper Paleozoic mafic and intermediate volcanic rocks of the Mount Pleasant caldera associated with the Sn-W deposit in southwestern New Brunswick (Canada): Petrogenesis and metallogenic implications (United States)

    Dostal, Jaroslav; Jutras, Pierre


    Upper Paleozoic ( 365 Ma) mafic and intermediate volcanic rocks of the Piskahegan Group constitute a subordinate part of the Mount Pleasant caldera, which is associated with a significant polymetallic deposit (tungsten-molybdenum-bismuth zones 33 Mt ore with 0.21% W, 0.1% Mo and 0.08% Bi and tin-indium zones 4.8 Mt with 0.82% Sn and 129 g/t In) in southwestern New Brunswick (Canada). The epicontinental caldera complex formed during the opening of the late Paleozoic Maritimes Basin in the northern Appalachians. The mafic and intermediate rocks make up two compositionally distinct associations. The first association includes evolved rift-related continental tholeiitic basalts, and the second association comprises calc-alkaline andesites, although both associations were emplaced penecontemporaneously. The basalts have low Mg# 0.34-0.40, smooth chondrite-normalized REE patterns with (La/Yb)n 5-6, primitive mantle-normalized trace element patterns without noticeable negative Nb-Ta anomalies, and their ɛNd(T) ranges from + 2.5 to + 2.2. The basalts were generated by partial melting of a transition zone between spinel and garnet mantle peridotite at a depth of 70-90 km. The calc-alkaline andesites of the second association have chondrite-normalized REE patterns that are more fractionated, with (La/Yb)n 7-8.5, but without significant negative Eu anomalies. Compared to the basaltic rocks, they have lower ɛNd(T) values, ranging from + 0.5 to + 1.9, and their mantle-normalized trace element plots show negative Nb-Ta anomalies. The ɛNd(T) values display negative correlations with indicators of crustal contamination, such as Th/La, Th/Nb and SiO2. The andesitic rocks are interpreted to have formed by assimilation-fractional crystallization processes, which resulted in the contamination of a precursor basaltic magma with crustal material. The parent basaltic magma for both suites underwent a different evolution. The tholeiitic basalts experienced shallow-seated fractional

  9. Achieving Mixtures of Ultra-High Performance Concrete

    Directory of Open Access Journals (Sweden)

    Mircea POPA


    Full Text Available Ultra-High Performance Concrete (UHPC is a relatively new concrete. According to [11] UHPC is that concrete which features compressive strength over C100/115 class. Up to this point standards for this type of concrete were not adopted, although its characteristic strength exceeds those specified in [33]. Its main property is high compressive strength. This provides the possibility of reducing the section of elements (beams or columns made of this type of concrete, while the load capacity remains high. The study consists in blending mixtures of UHPC made of varying proportions of materials. The authors have obtained strengths of up to 160 MPa. The materials used are: Portland cement, silica fume, quartz powder, steel fibers, superplasticiser, sand and crushed aggregate for concrete - andesite.


    Directory of Open Access Journals (Sweden)

    Ioan Bâca


    Full Text Available Igneous intrusive structures from Bârgău Mountains belong to the group of central Neogene volcanic chain of the Eastern Carpathians of Romania. The evolution of the relief developed on these structures are three main stages: the stage of injection of structures (Pannonian, the stage of uncovering of igneous intrusive bodies from Oligo-Miocene sedimentary cover (Pliocene, and the stage of subaerial modeling of magmatic bodies (Pliocene-current.In those circumstances, the geodiversity of intrusive magmatic structures from Bârgău Mountains is represented by several types of landforms such as: polycyclic landforms (erosional levels, structural landforms (the configuration of igneous intrusive structures, petrographic landforms (andesites, lithological contact, fluvial landforms (valleys, slopes, ridges, periglacial landforms (cryogenic and crionival landforms, biogenic and anthropogenic landforms. This study highlights certain features of the landforms modeled on igneous intrusive bodies with the aim of developing some strategy for tourism recovery by local and county authorities.

  11. Laser cutting of concretes with various ballasts

    International Nuclear Information System (INIS)

    Hamasaki, Masanobu; Katsumura, Munehide; Utsumi, Hiroaki


    The biological shield concrete and the radiation shield concrete which construct a part of the atomic reactor must be demolished with the decommissioning of the atomic reactor plants. In a case, the demolition using a laser is expected as one of excellent method for the decommissioning of these radioactive concretes. The fundamental cuttings of a mortar, the concretes with andesite, lime stone and gray wacke as ballast and a concrete reinforced with mild steel rods were therefore carried out using a 5 kW output CO 2 laser. As the results of experiment, it was cleared that cutting results varied with ballasts, 100 mm thick reinforced concrete could be cut, safety was high because few dross and few fume were produced. (author)

  12. Evaluation of the high concentrations of nitrate in the spring The Freedom and their relationship with the field of wells The Valencia, Sacred Domingo of Heredia Costa Rica

    International Nuclear Information System (INIS)

    Agudelo Arango, C. L.


    At general level in the study area one can observe a sequence of layers of lavas belonging to different laundries of andesitic composition of variable character (dense to breachess), being often presented strongly fractured, conforming the different aquifer levels (Inferior Colima, Superior Colima and The Freedom). These lavic layers are found interstratified with layers of low permeability, composed by ashy tufas and ignimbrites that conform the units grieves, they possess a secondary hydraulic conductivity that possibly favors the drainage for graveness, allowing: 1) the step of the rain through the Tiribi grieve toward the aquifer The Freedom, and 2) a hydraulic connection among the different aquifer levels. The study area is characterized in three areas of same hidrogeochemical and isotopic behavior [es

  13. Archean crustal evolution in the central Minto block, northern Quebec

    International Nuclear Information System (INIS)

    Skulski, T.; Percival, J.A.; Stern, R.A.


    The central Minto block contains three volcano-sedimentary successions. Near Lake Qalluviartuuq, an isotopically primitive ( 2.83 Ga ε Nd +3.8 to +2.3) 2.83 Ga volcano-plutonic sequence comprises depleted tholeiitic basalts, anorthositic gabbro, and diorite-granodiorite that is unconformably overlain by 2.76 Ga ε Nd +1.8) calc-alkaline sequence of pillow basalts, andesites, and peridotite cut by 2.73 Ga diorite. To the west, and in inferred tectonic contact, the sediment-dominated Kogaluc sequence includes both isotopically evolved calc-alkaline rocks ( 2.76 Ga ε Nd +1.6 to -0.1) including 2.78Ga ε Nd Nd 2.725Ga ε Nd - 1. 6). (author). 19 refs., 4 tabs., 5 figs

  14. Constraining the origin of La Poruña scoria cone, Central Volcanic Zone, northern Chile (United States)

    González-Maurel, O. P.; Godoy, B.; Rodriguez, I.; Menzies, A.; le Roux, P. J.; Bertin, D.; Marin, C.


    The magmatic arc in the Andean Central Volcanic Zone has evolved over a 70 km thick continental crust. Accordingly, true basalts are scarce, with basaltic-andesite being the least evolved volcanic product. In the active arc of northern Chile, this mafic volcanism is found as isolated lava flows and pyroclastic material. La Poruña (21°53'S; 68°30'W) is a 180 m high scoria cone constituted of pyroclastic material and extensive lava flows that are up to 8 km in length. La Poruña lavas show a range of 40Ar/39Ar ages in whole-rock and groundmass from 110 to 54 ka (Bertin and Amigo, in prep.) and its origin has been related to the evolution of San Pedro, a stratovolcano located 13 km to the east (O'Callaghan and Francis, 1986). Microscopic petrography and automated mineralogy analyses by QEMSCAN show that volcanic products from La Poruña have plagioclase and olivine, with subordinated ortho- and clino- pyroxene phenocrysts. Lavas and pyroclastic flows from the San Pedro volcano are predominantly plagioclase and orthopyroxene phenocrysts, with minor olivine and clinopyroxene. Geochemically, La Poruña samples show basaltic-andesite to andesite compositions (56.0-59.6 wt% SiO2; 482-654 ppm Sr), whilst 87Sr/86Sr and 143Nd/144Nd isotopic ratios vary between 0.7062 to 0.7066, and 0.51239 to 0.51245, respectively. Samples from San Pedro with similar ages as those from La Poruña (140 to 60 ka, 40Ar/39Ar; Bertin and Amigo, in prep.), have mainly andesitic compositions (55.9-63.8 wt% SiO2; 412-639 ppm Sr) with 87Sr/86Sr ratios (0.7064-0.7067) and 143Nd/144Nd ratios (0.51236-0.51243), overlapping those from La Poruña. Although the presented data is similar, there are observable differences on geochemical and isotopic characteristics of flows from La Poruña cone and San Pedro volcano. When related to SiO2 (wt. %) and Sr (ppm) concentrations, the Sr-isotope ratios from La Poruña show a well-defined cluster that has lower values than contemporaneous lavas from San Pedro

  15. Sulfate Saturated Hydrous Magmas Associated with Hydrothermal Gold Ores (United States)

    Chambefort, I.; Dilles, J. H.; Kent, A. J.


    Hydrothermal ore deposits associated with arc magmatism represent important sulfur anomalies. During degassing of magmatic systems the volatile may transport metals and sulfur and produce deposits. The ultimate origin of the magma-derived sulfur is still uncertain. The Yanacocha high-sulfidation epithermal Au deposit, Peru, is hosted by a Miocene volcanic succession (ca. 16 to 8 Ma). Magmatic rocks are highly oxidized >NNO+2 and show a range of composition from andesite to dacite. Two populations of amphibole occur in the Yanacocha dacitic ignimbrite deposits (~7 and 12 wt% Al2O3). Low Al amphiboles crystallized at ~ 1.5-2 kbar and 800°C (Plag-Hb thermobarometry) in equilibrium with plagioclase and pyroxene. High Al amphiboles only contain inclusions of anhydrite associated with apatite (up to 1.2 wt% SO3), and have a higher Cr2O3 content (up to 1000 ppm). We estimate these amphiboles form near the magma's liquidus at P(H2O)> 3kbar and 950 to 1000°C of a basaltic, basaltic andesite ascending magma. Low Al amphibole presents an REE pattern with negative anomalies in Sr, Ti and Eu, characteristic of plagioclase and titanite fractionation in the magma. High Al amphiboles are less enriched in REE and have no Sr, Ti, or Eu anomaly. Rare crystals of high Al amphibole display a low Al rim marked by higher REE contents compared to the core and a negative Eu anomaly. Magmatic sulfate occurrences have been discovered through the 8 m.y. volcanic sequence. Rounded anhydrite crystals are found included within clinopyroxene and both high and low Al amphibole. The rare high Al amphiboles (from the sample RC6) contain up to ~10 vol.%, ~5-80 micrometer-long anhydrite as irregularly shaped (amoeboid) blebs that do not show crystallographic forms and do not follow host cleavages. Extremely rare sulfide inclusions are found in plagioclase (Brennecka, 2006). The major and trace element contents of Yanacocha magmatic anhydrite have been analyzed by electron microprobe and LA

  16. Cerro Amarillo rhyolites, advanced AFC in the northern SVZ, Chile

    International Nuclear Information System (INIS)

    Godoy, E; Hildreth, W


    Cerro Amarillo is a Quaternary medium size (500m high, 2 km 2 ) rhyolite dome complex located close to the Chile-Argentina border, reaching a height of 4162 m, between the headwaters of the Rio Colina and the Nieves Negras Pass. It overlies a broad anticline of thick Middle Jurassic pelites (Alvarez et al., 1997). Thiele (1980) includes this complex in his 'Unidad Volcanica Antigua', a Pleistocene composite map unit made up of andesites and trachyandesites. Ramos et al. (1997), while recognizing its rhyolitic character, assigned a Tertiary age to the lava domes, most likely based on the late Pliocene age of silicic dikes outcropping eastward, in Argentina. Both the lack of younger overlying units and freshness of its components, together with preservation of the unconsolidated, easily eroded pyroclastic deposits at its base, suggest, however, that it is not older than Pleistocene (au)

  17. Geological research on rare earth elements, results and outlook

    International Nuclear Information System (INIS)

    Fortin, H


    This is a report of the geological investigation of rare earth elements carried out by CCHEN and ENAMI (Empresa Nacional de Mineria) over 70,000 square kilometers in Chile's northern coastal mountain range. Twenty areas were identified with sphena, davidite, ilmenite, pyroxene, anatase and magnetite minerals containing 0.3 kg/t to 6.0 kg/t of rare earth elements. Additional research on Cerro Carmen Prospect, located near Diego de Almagro, define it as a metasomatic deposit, hosted in metamorphic contact rocks, between andesites (Pliensbachian to early Jurassic) and intrusive monzonitic rocks. This information increases knowledge about the metallogenesis of Chile's copper - iron - rare earth - uranium deposits and the application of this geological model of ore deposits as defined in Australia's Olympic Dam

  18. K-Ar Geochronology and isotopic composition of the late oligocene- early miocene Ancud volcanic complex, Chiloe

    International Nuclear Information System (INIS)

    Munoz B, Jorge; Duhart O, Paul; Farmer, G. Lang; Stern, Charles R


    The Ancud Volcanic Complex (Gally and Sanchez , 1960) forms a portion of the Mid-Tertiary Coastal Magmatic Belt which outcrops in the area of northern Chiloe island. Main exposures occur at Ancud, Punta Polocue, Punihuil, Pumillahue, Tetas de Teguaco and Bahia Cocotue. The Ancud Volcanic Complex consists of basaltic to basaltic andesites lava flows and volcanic necks and rhyolitic pyroclastic flows and vitric domes. Previous studies indicate a Late Oligocene-Early Miocene age (Garcia et al., 1988; Stern and Vergara, 1992; Munoz et al., 2000). The Ancud Volcanic Complex covers and intrudes Palaeozoic-Triassic metamorphic rocks and is partially covered by an early to middle Miocene marine sedimentary sequence known as Lacui Formation (Valenzuela, 1982) and by Pleistocene glacial deposits (Heusser, 1990). At Punihuil locality, lava flows are interbedded with the lower part of the marine sedimentary sequence, which includes significant amounts of redeposited pyroclastic components. Locally, the presence of hyaloclastic breccias suggests interaction of magma with marine water (au)

  19. Lithospheric convective removal related post-collisional middle Eocene magmatism along the Izmir-Ankara-Erzincan suture zone (NE Turkey). (United States)

    Göçmengil, Gönenç; Karacık, Zekiye; Genç, Ş. Can


    Obliteration of the Mesozoic Neo-Tethyan Ocean and succeeding collision of the micro plates along the northern part of Turkey lead the development of the İzmir-Ankara-Erzincan suture zone (IAESZ). The suturing and collision stages terminate with the amalgamation of the three different crustal blocks (Pontides, Central Anatolian Crystalline Complex and Anatolide-Tauride Block) in the Paleocene-Early Eocene period. After the collisional stage; a new phase of extension and magmatism concomitantly developed at the both sides and as well as along the IAESZ during the Middle Eocene period. However, the origin, mechanism and driving force of the post-collisional magmatism is still enigmatic. To understand and better constrain the syn-to post collisional evolutionary stages, we have carried out volcano-stratigraphy and geochemistry based study on the middle Eocene magmatic associations along a transect ( 100 km) from Pontides to the Central Anatolian Crystalline Complex (CACC) at the NE part of the Turkey. Middle Eocene magmatic activity in the region has been represented by calc-alkaline, alkaline, shoshonitic volcanic and granitic rocks together with scarce gabbroic intrusions. We particularly focused on middle Eocene volcano-sedimentary successions (MEVSS) to constrain the tectono-magmatic evolution of the abovementioned transect. The volcano-sedimentary succsessions are coevally developed and cover the crustal blocks (Pontides and CACC) and the IAESZ with a region wide unconformity. We have differentiated three lava series (V1-V2-V3) and their sub-groups (V1a-V1b; V2a-V2b) in MEVSS. Generally, all lava series have middle-K to shoshonitic composition with distinct subduction characteristics. V1 series is marked by presence of hydrous phenocrysts such as amphibole+biotite. V1a sub-group constitute the first volcanic product and characterized by the high Mg# (42-69); alkaline basaltic andesite, and hawaiites. V1b sub-group is represented by calc-alkaline, low Mg# (24

  20. New data on the geological structure of the southwestern Mendeleev Rise, Arctic Ocean (United States)

    Skolotnev, S. G.; Fedonkin, M. A.; Korniychuk, A. V.


    This communication considers the ideas about the geological structure of the southwestern Mendeleev Rise belonging to the East Arctic rises of the Arctic Ocean. These ideas have resulted from analyzing the data obtained from bathymetric surveys, visual observations, and bottom coring using the technical tools of a research submarine. We distinguished the lower sequence of quartzite sandstones and dolomites, which has a visible thickness of about 230 m and occurs in the lowermost visible section, at depths between 1500 and 1270 m. This sequence is superimposed with stratigraphic and angular unconformity by the upper sequence of limestones and sandstones having a visible thickness of 40 m. The lower sequence is pierced by subvolcanic rocks of basaltic to andesitic composition, and in the lowermost part of the slope, a tuffaceous sequence having a visible thickness of 50 m adjoins it.

  1. The Laramide Mesa formation and the Ojo de Agua caldera, southeast of the Cananea copper mining district, Sonora, Mexico (United States)

    Cox, Dennis P.; Miller, Robert J.; Woodbourne, Keith L.


    The Mesa Formation extends from Cananea, Mexico, southeast to the Sonora River and is the main host rock of Laramide porphyry copper deposits in the Cananea District and at the Alacran porphyry prospect to the east. The Mesa consists of two members-a lower andesite and an upper dacite. The lowest part of the dacite member is a crystal tuff about 100 m thick. This tuff is the outfall of a caldera centered near the village of Ojo de Agua, dated by 40Ar/39Ar at 65.8 Ma ?0.4. The Ojo de Agua Caldera is about 9 km in diameter and is filled by a light gray biotite dacite tuff with abundant flattened pumice fragments. The volume of the caldera is estimated to be 24 km3.

  2. Origin of phenocrysts and compositional diversity in pre-Mazama rhyodacite lavas, Crater Lake, Oregon (United States)

    Nakada, S.; Bacon, C.R.; Gartner, A.E.


    Phenocrysts in porphyritic volcanic rocks may originate in a variety of ways in addition to nucleation and growth in the matrix in which they are found. Porphyritic rhyodacite lavas that underlie the eastern half of Mount Mazama, the High Cascade andesite/dacite volcano that contains Crater Lake caldera, contain evidence that bears on the general problem of phenocryst origin. Phenocrysts in these lavas apparently formed by crystallization near the margins of a magma chamber and were admixed into convecting magma before eruption. About 20 km3 of pre-Mazama rhyodacite magma erupted during a relatively short period between ~400 and 500 ka; exposed pre-Mazama dacites are older and less voluminous. The rhyodacites formed as many as 40 lava domes and flows that can be assigned to three eruptive groups on the basis of composition and phenocryst content. -from Authors

  3. Geologic map of Mount Mazama, Crater Lake, Oregon (United States)

    Bacon, Charles


    Crater Lake caldera collapsed about 6,850 yr B.P. during the climactic eruption of Mount Mazama, a High Cascade basaltic andesitic to dacitic volcanic center that was constructed during a period of about 400,000 yr. The caldera and the products of the climactic eruption are clear evidence for the presence of a shallow magma body that must have supported a hydrothermal system in the recent past. The geology of Mount Mazama has been mapped at a scale of 1:24,000 based on detailed study of the walls of Crater Lake caldera and mapping of the flanks of the volcano. The map shows lavas and fragmental deposits of Mount Mazama, lavas of nearby monogenetic volcanoes, pre-Mazama silicic volcanic rocks, products of the climactic eruption, and glacial deposits. Related topical studies of the volcanology, geochronology, petrology, and geochemistry of the Crater Lake area depend on field relations established by geologic mapping.

  4. Stable isotope and mineralogical investigation of the genesis of amethyst geodes in the Los Catalanes gemological district, Uruguay, southernmost Paraná volcanic province (United States)

    Duarte, Lauren C.; Hartmann, Leo A.; Ronchi, Luiz H.; Berner, Zsolt; Theye, Thomas; Massonne, Hans J.


    Stable isotopes (C, O, S) and mineralogical studies of the world-class amethyst-geode deposits of the Los Catalanes gemological district, Uruguay, constrain processes operative during mineral deposition. The mineralized basaltic andesites from the Cretaceous Paraná volcanic province are intensely altered to zeolites (clinoptilolite) and clay minerals. Variations in the δ18O values of silica minerals in geodes (chalcedony, quartz, and amethyst) are much larger and the values generally somewhat lower (21.2-31.5‰) in the Uruguayan deposits than in the Ametista do Sul area of southern Brazil. The range of δ34S values (-15.0 to -0.3‰) of altered basaltic rocks requires (in addition to sulfur of magmatic origin) the involvement of 34S-depleted sedimentary sulfur from bacterial sulfate reduction. The results delimit the mineralizing processes to a post-eruption environment characterized by low temperature and strong interaction of the lava flows with meteoric water.

  5. Stratigraphy of Reforma Caldera, Baja California Sur, Mexico (United States)

    García Sánchez, L.; Macias, J. L.; Osorio, L. S.; Pola, A.; Avellán, D. R.; Arce, J. L.; Saucedo, R.; Sánchez, J. M.; García-Tenorio, F.; Cisneros, G.; Reyes-Agustín, G.; Cardona, S.; Jimenez, A.


    The Reforma caldera is located at ~35 km to the northwest of Santa Rosalía in the central part of the Baja California peninsula. It has 10 km in diameter and a maximum height of 1200 masl in the center and between 100 and 500 masl in its slopes. Reforma is within a tectonic zone affected by two fault systems: A NW-SE normal fault system linked to the opening of the Gulf of California, and a NNW-SSE and NW-SE strike-slip fault system associated with an active Riedel system. Reforma was built upon Cretaceous granites that outcrop at the caldera center, Miocene to Pliocene volcano-sedimentary rocks of the Comondú group, and Miocene marine sediments of the Santa Rosalía basin. On top of these rocks outcrop at least four submarine to subaerial ignimbrites interbedded with marine fossiliferous beds and the lower Pleistocene deposits associated to the Reforma caldera. These deposits are formed by a ignimbrite that shifts to different lithofacies that change gradually their welding, here dubbed basal, transitional, intermediate, and upper (all of then enriched in black fiammes), followed by a pumice-rich, white fiammes, and vitrophyre lithofacies, which are distributed around the 9 km wide caldera and have been associated to the caldera formation episode. Deposits related to post-caldera volcanism are andesite-basaltic lava flows erupted along the caldera rim through localized feeding dikes and andesitic and rhyolitic domes, and scoria cinder cones exposed inside and outside the caldera. On top of these deposits rest the middle Pleistocene Aguajito caldera deposits.

  6. Geochemistry and tectonic setting of the Golabad granitoid complex (SW Nain, Iran) (United States)

    Mansouri Esfahani, Mahin; Khalili, Mahmoud; Alaminia, Zahra


    The Oligo-Miocene Golabad granitoid complex intrusive into the Eocene volcanic rocks occurs in the Urumieh-Dokhtar Magmatic Arc (UDMA) in Iran. According to microscopic and chemical studies, the granitoid complex consists of three different rock types: 1) plutonic rocks comprising diorite, quartz diorite, granodiorite and granite; 2) volcanic rocks composed of basalt, andesite basalt, ± pyroxene bearing andesite and rhyolite, and 3) pyroclastic rocks. The main mineral constituents of these rocks are mostly plagioclase (oligoclase and andesine), quartz, K-feldspar, amphibole (magnesio-hornblende and actinolite-hornblende) and Mg-biotite. In addition, apatite, titanite, zircon, and opaque minerals are common accessory minerals. The studied enclaves are classified as mafic micro-granular enclaves (MME) with monzodiorite compositions. Geochemically, the rocks in this study represent medium to high-K calc-alkaline series, metaluminous and I-type nature. Plotting, the chemical composition of plagioclase on the An-Ab-Or ternary diagram, the temperature of crystallization is estimated to range from 700 to 900 °C at a pressure of 4.5 Kbar. High TiO2 values of biotites from the Golabad granitoid complex suggest magmatic origin and the crystallization temperature is estimated to range from 700 to 750 °C. The amphiboles according to their chemical analysis, are classified as igneous amphiboles generated in high oxygen fugacity conditions. The chemical data of the amphiboles and biotites pointed out to the I- type nature of the Golabad granitoid complex emplaced in an active continental margin subduction setting. The amphibole crystallization pressure was estimated by Al in amphibole varies from 1.09 to 2.28 Kbar. Using the calculated pressure the depth of the formation of the Golabad granitoid complex estimated from 4 to 9 Km.

  7. Seismogenic frictional melting in the magmatic column as the driving force of stick-slip motion (United States)

    Kendrick, J. E.; Lavallee, Y.; Hirose, T.; Di Toro, G.; Hornby, A.; De Angelis, S.; Henton De Angelis, S.; Ferk, A.; Hess, K.; Leonhardt, R.; Dingwell, D. B.


    Lava dome eruptions subjected to high extrusion rates commonly evolve from endogenous to exogenous growth and limits to their structural stability hold catastrophic potential as explosive eruption triggers. In the conduit strain localisation in magma, accompanied by seismogenic failure, marks the onset of brittle magma ascent dynamics. The rock record of exogenous dome structures preserves vestiges of cataclastic processes and of thermal anomalies, key to unravelling subsurface processes. A combined structural, thermal and magnetic investigation of shear bands from Mount St. Helens (MSH) and Soufrière Hills volcano (SHV) reveal evidence of faulting and frictional melting within the magmatic column. High velocity rotary shear (HVR) experiments demonstrate the propensity for melting of andesitic and dacitic material (from SHV and MSH respectively) at upper conduit stress conditions. Such melting events may be linked to the step-wise extrusion of magma accompanied by repetitive long-period (LP) seismicity. Using a source duration calculated from the waveforms at seismic stations around SHV, and slip distance per drumbeat calculated from extrusion rate, frictional melting of SHV andesite in a high velocity rotary shear apparatus can be achieved at small slip distances (HVR experiments which mimic rapid velocity fluctuations in stick-slip behavior demonstrate velocity-weakening behavior of melt, with a tendency for unstable slip. We postulate that pseudotachylyte generation could be the underlying cause of stick-slip motion and associated seismic 'drumbeats', which are so commonly observed at dome-building volcanoes, allowing for a fixed spatial locus and the occurrence of 'families' of similar seismic events. We conclude that, given the ease with which melting is achieved in volcanic rocks, and considering the high ambient temperatures in volcanic conduits, frictional melting is a highly probable consequence of viscous magma ascent.

  8. Mineral chemistry and petrogenesis of the Gurgur Mount volcanic rocks (Northeast Takab

    Directory of Open Access Journals (Sweden)

    Dariush Esmaeily


    Full Text Available Andesitic and andesitic-basaltic lavas are widespread over most of the ground surface of the Gurgur area altered mostly by the hydrothermal solutions. The main rock forming minerals in these rocks are plagioclase, pyroxene and olivine affected by the hydrothermal solutions. The altered rocks do contain minerals including calcite, sericite and chlorite. Given the results obtained and the mineral chemistry studies, the clinopyroxenes formed in the area are, chemically, calkalkaline and of diopside-augite type formed in subvolcanic to near surface levels contemporaneous with magma ascending. Plagioclase minerals show zoning textures and lie within the two andesine and albite-oligoclase fields. These units, in terms of total rock chemistry, are classified as the calk-alkaline volcanic rocks formed in the continental arcs. On the other hand, on the trace elements chondrite-normalized diagrams and enriched mantle-normalized multi- element diagrams, the LREE enrichment relative to the HREE is observed. The LILE (i.e. Rb, K and Th and the LREE (e.g. La, Ce and Nd show an enrichment in comparison to the HFSE (Zr, Hf, Nb, Yb, Y and Sm. Given the Nd/Th (1.42-1.15, Zr/Nb (12.27-21.22, Ba/La (18.64-29.77 as well as LILE enrichment associated with depletion in Nb, Ta and Ti, an environment related to the subduction zones can be proposed for the area under study. Moreover, the similarity between the REE distribution pattern and the incompatible elements point to the genetic relationship between these rocks. Finally, on the base of the obtained data, it can be concluded that the volcanic rocks in the Gurgur Mountain were likely formed during the extended magmatism of the Urumieh-Dokhtar in the Cenozoic.

  9. Petrogenesis of Rinjani Post-1257-Caldera-Forming-Eruption Lava Flows

    Directory of Open Access Journals (Sweden)

    Heryadi Rachmat


    Full Text Available DOI:10.17014/ijog.3.2.107-126After the catastrophic 1257 caldera-forming eruption, a new chapter of Old Rinjani volcanic activity beganwith the appearance of Rombongan and Barujari Volcanoes within the caldera. However, no published petrogeneticstudy focuses mainly on these products. The Rombongan eruption in 1944 and Barujari eruptions in pre-1944, 1966,1994, 2004, and 2009 produced basaltic andesite pyroclastic materials and lava flows. A total of thirty-one sampleswere analyzed, including six samples for each period of eruption except from 2004 (only one sample. The sampleswere used for petrography, whole-rock geochemistry, and trace and rare earth element analyses. The Rombonganand Barujari lavas are composed of calc-alkaline and high K calc-alkaline porphyritic basaltic andesite. The magmashows narrow variation of SiO2 content that implies small changes during its generation. The magma that formedRombongan and Barujari lavas is island-arc alkaline basalt. Generally, data show that the rocks are enriched in LargeIon Lithophile Elements (LILE: K, Rb, Ba, Sr, and Ba and depleted in High Field Strength Elements (HFSE: Y, Ti,and Nb which are typically a suite from a subduction zone. The pattern shows a medium enrichment in Light REEand relatively depleted in Heavy REE. The processes are dominantly controlled by fractional crystallization andmagma mixing. All of the Barujari and Rombongan lavas would have been produced by the same source of magmawith little variation in composition caused by host rock filter process. New flux of magma would likely have occurredfrom pre-1944 until 2009 period that indicates slightly decrease and increase of SiO2 content. The Rombongan andBarujari lava generations show an arc magma differentiation trend.

  10. The intra-oceanic Cretaceous (~ 108 Ma) Kata-Rash arc fragment in the Kurdistan segment of Iraqi Zagros suture zone: Implications for Neotethys evolution and closure (United States)

    Ali, Sarmad A.; Ismail, Sabah A.; Nutman, Allen P.; Bennett, Vickie C.; Jones, Brian G.; Buckman, Solomon


    The Kata-Rash arc fragment is an allochthonous thrust-bound body situated near Penjween, 100 km northeast of Sulymannia city, Kurdistan Region, within the Iraqi portion of the Zagros suture zone. It forms part of the suprasubduction zone 'Upper Allochthon' terranes (designated as the Gimo-Qandil Group), which is dominated by calc-alkaline andesite and basaltic-andesite, rhyodacite to rhyolite, crosscut by granitic, granodioritic, and dioritic dykes. Previously, rocks of the Kata-Rash arc fragment were interpreted as a part of the Eocene Walash volcanic group. However, SHRIMP zircon U-Pb dates on them of 108.1 ± 2.9 Ma (Harbar volcanic rocks) and 107.7 ± 1.9 Ma (Aulan intrusion) indicate an Albian-Cenomanian age, which is interpreted as the time of igneous crystallisation. The Aulan intrusion zircons have initial εHf values of + 8.6 ± 0.2. On a Nb/Yb-Th/Yb diagram, all Kata-Rash samples fall within the compositional field of arc-related rocks, i.e. above the mid-ocean-ridge basalt (MORB)-ocean island basalt (OIB) mantle array. Primitive-mantle-normalised trace-element patterns for the Kata-Rash samples show enrichment in the large ion lithophile elements and depletion in the high-field-strength elements supporting their subduction-related character. Low Ba/La coupled with low La/Yb and Hf/Hf* 3000 km continuity of Cretaceous arc activity (Oman to Cyprus), that consumed Neotethyian oceanic crust between Eurasia and the Gondwanan fragment Arabia.

  11. Geochemical and Petrological Studies of Peralkaline Rocks from Laborcita de San Javier, Chihuahua, Mexico (United States)

    Lozano, J. E.; Espejel-Garcia, V. V.; Villalobos-Aragon, A.


    Peralkaline igneous rocks are characterized by a lower total aluminum content in comparison to the total alkalis content (Na + K), and are important to determine the tectonic environment in which they formed. The majority of the volcanic activity in Chihuahua State, northern Mexico, is mostly related to the formation of the Sierra Madre Occidental (SMO), product of the subduction of the Farallon plate. Volcanic activity of Paleogene age (late Oligocene) to the SW of Chihuahua city, specifically in the towns of Laborcita de San Javier and Cusihuiriachic, includes 27.5 M.a. peralkaline tuffs, capping the older rhyolites and andesites of the SMO. This sequence becomes thicker and more prominent towards the west. A volcanic section of more than 1,000 m thick is exposed in the Laborcita area, which ranges in age from 27 to 35 Ma. The oldest (bottom) unit is a calc-alkaline felsic ash-flow tuff and rhyolitic lavas interbedded with flows of mafic to intermediate composition. Overlying this unit, there is a basaltic andesite with an age of 30 to 33 Ma. Right at the top of this sequence, there is the widespread peralkaline ash-flow tuff (27.5 M.a.), focus of this study. Geochemical analyses performed to rhyolitic tuffs by Mauger and Dayvault (1983), have a peralkalinity index ranging from 0.94 to 1.20, while analyses prepared for this project only reach an index of 0.60. The appearance of peralkaline rocks in the Chihuahua State indicates the change of tectonic regime from compression (Farallon plate subduction) to distension (Basin and Range and/or Rio Grande Rift), about 27 M.a. ago.

  12. Forearc oceanic crust in the Izu-Bonin arc - new insights from active-source seismic survey - (United States)

    Kodaira, S.; Noguchi, N.; Takahashi, N.; Ishizuka, O.; Kaneda, Y.


    Petrological studies have suggested that oceanic crust is formed in forearc areas during the initial stage of subduction. However, there is little geophysical evidence for the formation of oceanic crust in those regions. In order to examine crustal formation process associated with a subduction initiation process, we conducted an active-source seismic survey at a forearc region in the Izu-Bonin intra-oceanic arc. The resultant seismic image shows a remarkably thin crust (less than 10 km) at the northern half of the Bonin ridge (at the north of the Chichi-jima) and abrupt thickening the crust (~ 20 km thick) toward the south (at the Haha-jima). Comparison of velocity-depth profiles of the thin forearc crust of the Bonin ridge with those of typical oceanic crusts showed them to be seismologically identical. The observed structural variation also well corresponds to magmatic activities along the forearc. Boninitic magmatism is evident in the area of thin crust and tholeiitic-calcalkaline andesitic volcanism in the area of thick crust. Based on high precision dating studies of those volcanic rocks, we interpreted that the oceanic-type thin crust associated with boninitic volcanism has been created soon after the initiation of subduction (45-48 Ma) and and that the nonoceanic thick crust was created by tholeiitic-calcalkaline andesitic magmatism after the boninitic magmatism was ceased. The above seismological evidences strongly support the idea of forearc oceanic crust (or phiolite) created by forearc spreading in the initial stage of subduction along the intra-oceanic arc.

  13. Geology, Petrography, Geochemistry and Radioactivity Studies on The Dyke Swarms of Gabal Al Aglab area, North Eastern Desert, Egypt

    International Nuclear Information System (INIS)

    Eldabe, M.M.M.


    Gabal Al Aglab area is located in the North Eastern Desert of Egypt bounded by lat. 27° 14'-27° 19' N and long. 33° 00'-33° 05' E. It is covered by pan African basement rocks. The present study concern with the geology, petrography, geochemistry and radioactivity of various types of the dyke swarms in Gabal Al Aglab area. The field studies revealed that the area comprises the following litho-tectonic units ; Dokhan volcanic (oldest) and Hamammat sedimentary rocks and younger granites are represented by both Gabal Um Twier and Gabal Al Aglab syenogranites (youngest). Many dykes of acidic, intermediate and basic composition have a large extension and dissect all the mentioned rock units. The dyke swarms intruding Gabal Al Aglab area include the acidic (felsite and granite porphyry) dykes, while the intermediate comprise andesite and andesite porphyry and the basic dykes show basalt and dolerites. The chronologic relations of these dykes indicate the following sequence of emplacement beginning with the oldest acidic, followed by intermediate and then basic ones. The geochemical studies indicate that the acidic dykes were derived from a highly differentiated calc- alkaline magma, while the basic and intermediate dykes were developed from magma of subalkaline nature. The dykes were derived from separate magmas and not by magmatic differentiation of single mother magma. The radioactivity of the studied dyke rocks revealed that the high levels of radioactivity mainly linked to the acidity, differentiation and alkalinity characters. Radioactive granitic spot was observed along the contact with some basic dykes due to their thermal effect during its emplacement on the granite, at the northern part of the studied area. This radioactive spot display anomalies with higher values in U and Th contents, than the normal background value of the younger granite.

  14. The effect of offset on fracture permeability of rocks from the Southern Andes Volcanic Zone, Chile (United States)

    Pérez-Flores, P.; Wang, G.; Mitchell, T. M.; Meredith, P. G.; Nara, Y.; Sarkar, V.; Cembrano, J.


    The Southern Andes Volcanic Zone (SVZ) represents one of the largest undeveloped geothermal provinces in the world. Development of the geothermal potential requires a detailed understanding of fluid transport properties of its main lithologies. The permeability of SVZ rocks is altered by the presence of fracture damage zones produced by the Liquiñe-Ofqui Fault System (LOFS) and the Andean Transverse Faults (ATF). We have therefore measured the permeability of four representative lithologies from the volcanic basement in this area: crystalline tuff, andesitic dike, altered andesite and granodiorite. For comparative purposes, we have also measured the permeability of samples of Seljadalur basalt, an Icelandic rock with widely studied and reported hydraulic properties. Specifically, we present the results of a systematic study of the effect of fractures and fracture offsets on permeability as a function of increasing effective pressure. Baseline measurements on intact samples of SVZ rocks show that the granodiorite has a permeability (10-18 m2), two orders of magnitude higher than that of the volcanic rocks (10-20 m2). The presence of throughgoing mated macro-fractures increases permeability by between four and six orders of magnitude, with the highest permeability recorded for the crystalline tuff. Increasing fracture offset to produce unmated fractures results in large increases in permeability up to some characteristic value of offset, beyond which permeability changes only marginally. The increase in permeability with offset appears to depend on fracture roughness and aperture, and these are different for each lithology. Overall, fractured SVZ rocks with finite offsets record permeability values consistent with those commonly found in geothermal reservoirs (>10-16 m2), which potentially allow convective/advective flow to develop. Hence, our results demonstrate that the fracture damage zones developed within the SVZ produce permeable regions, especially within the

  15. Emplacement of the final lava dome of the 2009 eruption of Redoubt Volcano, Alaska (United States)

    Bull, Katharine F.; Anderson, Steven W.; Diefenbach, Angela K.; Wessels, Rick L.; Henton, Sarah M.


    After more than 8 months of precursory activity and over 20 explosions in 12 days, Redoubt Volcano, Alaska began to extrude the fourth and final lava dome of the 2009 eruption on April 4. By July 1 the dome had filled the pre-2009 summit crater and ceased to grow. By means of analysis and annotations of time-lapse webcam imagery, oblique-image photogrammetry techniques and capture and analysis of forward-looking infrared (FLIR) images, we tracked the volume, textural, effusive-style and temperature changes in near-real time over the entire growth period of the dome. The first month of growth (April 4–May 4) produced blocky intermediate- to high-silica andesite lava (59–62.3 wt.% SiO2) that initially formed a round dome, expanding by endogenous growth, breaking the surface crust in radial fractures and annealing them with warmer, fresh lava. On or around May 1, more finely fragmented and scoriaceous andesite lava (59.8–62.2 wt.% SiO2) began to appear at the top of the dome coincident with increased seismicity and gas emissions. The more scoriaceous lava spread radially over the dome surface, while the dome continued to expand from endogenous growth and blocky lava was exposed on the margins and south side of the dome. By mid-June the upper scoriaceous lava had covered 36% of the dome surface area. Vesicularity of the upper scoriaceous lava range from 55 to 66%, some of the highest vesicularity measurements recorded from a lava dome.We suggest that the stability of the final lava dome primarily resulted from sufficient fracturing and clearing of the conduit by preceding explosions that allowed efficient degassing of the magma during effusion. The dome was thus able to grow until it was large enough to exceed the magmastatic pressure in the chamber, effectively shutting off the eruption.

  16. Deep magmatic degassing versus scrubbing: Elevated CO2 emissions and C/S in the lead-up to the 2009 eruption of Redoubt Volcano, Alaska (United States)

    Werner, Cynthia A.; Evans, William C.; Kelly, Peter; McGimsey, Robert G.; Pfeffer, Melissa; Doukas, Michael P.; Neal, Christina


    We report CO2, SO2, and H2S emission rates and C/S ratios during the five months leading up to the 2009 eruption of Redoubt Volcano, Alaska. CO2emission rates up to 9018 t/d and C/S ratios ≥30 measured in the months prior to the eruption were critical for fully informed forecasting efforts. Observations of ice-melt rates, meltwater discharge, and water chemistry suggest that surface waters represented drainage from surficial, perched reservoirs of condensed magmatic steam and glacial meltwater. These fluids scrubbed only a few hundred tonnes/day of SO2, not the >2100 t/d SO2expected from degassing of magma in the mid- to upper crust (3–6.5 km), where petrologic analysis shows the final magmatic equilibration occurred. All data are consistent with upflow of a CO2-rich magmatic gas for at least 5 months prior to eruption, and minimal scrubbing of SO2by near-surface groundwater. The high C/S ratios observed could reflect bulk degassing of mid-crustal magma followed by nearly complete loss of SO2in a deep magmatic-hydrothermal system. Alternatively, high C/S ratios could be attributed to decompressional degassing of low silica andesitic magma that intruded into the mid-crust in the 5 months prior to eruption, thereby mobilizing the pre-existing high silica andesite magma or mush in this region. The latter scenario is supported by several lines of evidence, including deep long-period earthquakes (−28 to −32 km) prior to and during the eruption, and far-field deformation following the onset of eruptive activity.

  17. The rise and fall of periodic 'drumbeat' seismicity at Tungurahua volcano, Ecuador (United States)

    Bell, Andrew F.; Hernandez, Stephen; Gaunt, H. Elizabeth; Mothes, Patricia; Ruiz, Mario; Sierra, Daniel; Aguaiza, Santiago


    Highly periodic 'drumbeat' long period (LP) earthquakes have been described from several andesitic and dacitic volcanoes, commonly accompanying incremental ascent and effusion of viscous magma. However, the processes controlling the occurrence and characteristics of drumbeat, and LP earthquakes more generally, remain contested. Here we use new quantitative tools to describe the emergence, evolution, and degradation of drumbeat LP seismicity at the andesitic Tungurahua volcano, Ecuador, in April 2015. The signals were recorded during an episode of minor explosive activity and ash emission, without lava effusion, and are the first to be reported at Tungurahua during the ongoing 17 yrs of eruption. Following four days of high levels of continuous and 'pulsed' tremor, highly-periodic LP earthquakes first appear on 10 April. Over the next four days, inter-event times and event amplitudes evolve through a series of step-wise transitions between stable behaviors, each involving a decrease in the degree of periodicity. Families of similar waveforms persist before, during, and after drumbeat activity, but the activity levels of different families change coincidentally with transitions in event rate, amplitude, and periodicity. A complex micro-seismicity 'initiation' sequence shows pulse-like and stepwise changes in inter-event times and amplitudes in the hours preceding the onset of drumbeat activity that indicate a partial de-coupling between event size and rate. The observations increase the phenomenology of drumbeat LP earthquakes, and suggest that at Tungurahua they result from gas flux and rapid depressurization controlled by shear failure of the margins of the ascending magma column.

  18. Magmatic and tectonic evolution of the Ladakh Block from field studies (United States)

    Raz, U.; Honegger, K.


    The Ladakh Block is in an intermediate position between the Indian plate in the south and the Karakorum-Tibetan plate in the north. To the west it is separated from the Kohistan Arc by the Nanga Parbat Syntaxis, to the east it is cut off from the Lhasa Block by the Gartok-Nubra Fault. Present data, together with previously published results, show, that the Ladakh Block consists of an island arc in the south and a calc-alkaline batholith in the north with remnants of a continental crust. Migmatitic gneisses and metasedimentary sequences, such as quartzites and metapelites, interbedded with basaltic volcanics and overlain by thick platform carbonates were found as evidence of a continental crust. Remnants of megafossils ( Megalodon and Lithiotis) within the high-grade metamorphic marbles indicate a probable age of Late Triassic to Early Jurassic. These sediments were intruded by a faintly layered hornblende-gabbro, which preceded the calc-alkaline magmatic episode. Gabbro and gabbronorites are found as roof pendants and large inclusions within diorites and granodiorites. The major part of the batholith consists of granodiorite and biotite-granite plutons, ranging from Late Cretaceous to Tertiary. Associated with the intrusives are volcanic rocks with trachyandesite to alkalibasalt and basalt-andesite to rhyolite compositions. Garnet-bearing leucogranites succeeded the emplacement of the major plutons. The magmatic stage ended, finally, by intense fracturing and injections of NE-SW striking andesitic dykes. The southernmost unit of the Ladakh Block is formed by oceanic crust with serpentinized peridotite and hornblende-gabbro and is covered by volcanics of an island-arc type (Dras volcanics). These units are intruded by gabbronorite, as well as Middle and Upper Cretaceous granodiorite and coarse-grained biotite-granite. In a plate tectonic view the Ladakh Block represents a transitional sector between the pure island arc of Kohistan in the west and the Andean type

  19. Mesozoic and cenozoic volcanic rocks from central and southern Tibet: 39Ar-40Ar dating, petrological characteristics and geodynamical significance

    International Nuclear Information System (INIS)

    Coulon, C.; Bollinger, C.; Wang, S.


    Field relations, radiometric ages and mineralogical and chemical characteristics of the orogenic volcanic rocks from the Lhasa block (Tibet) are studied. Volcanic activity started before the deposition of the Albian-Aptian sedimentary units (Takena Formation and Xigaze Group). Volcanism is volumetrically limited in the northern part of the Lhasa block: basalts, andesites and dacites are present while ignimbrites are scarce. Radiometric ages of these rocks range between 110 and 80 Ma. Conversely, in the southern part of the Lhasa block, volcanism is largely developed (Gangdese belt). There, paroxysmal activity occurred later than in the north, between 60 and 50 Ma (Lingzizong Formation). This volcanism is mainly represented by andesites and ignimbrites. A younger episode at about 15-10 Ma took place in this southern region. The mineralogical and geochemical characteristics indicate that, as a whole, the volcanic rocks from the Lhasa block belong to a calc-alkaline continental-margin series, enriched in K 2 O and other incompatible elements. Subordinate potassic alkaline lavas are present in the northern margin of the Gangdese belt; some basalts exhibit a tholeiitic affinity (Daquin area, southern region). The geodynamic significance of these Cenozoic volcanic rocks lies in the relative motion of India and the Lhasa block, after accretion of the latter to the northern Qantang block. A geodynamic model based on changes of the type of subduction of the Indian oceanic crust beneath the Lhasa block, for the period 120-40 Ma, is proposed to account for the abundance, age, and magmatic affinity of the volcanic products. (orig.)

  20. Behaviour of major, minor and trace elements (including REEs during kaolinization processes at Zonouz deposit, northeast of Marand, East Azarbaidjan province

    Directory of Open Access Journals (Sweden)

    Vahideh Alipour


    Full Text Available The Zonouz kaolin deposit is located ~15 km northeast of Marand, East-Azarbaidjan province. Based on physical features in field investigations, such as color, five distinct kaolin types including (1 white, (2 lemon, (3 gray, (4 brown, and (5 yellow are distinguished in the deposit. Field evidence and petrographic studies indicate that the deposit is genetically close to trachy-andesite rocks. According to mineralogical data, the deposit contains quartz, kaolinite, montmorillonite, calcite, pyrophyllite, chlorite, muscovite-illite, dolomite, hematite, and anatase minerals. Geochemical data indicate that function of alteration processes on trachy-andesite rocks during development of Zonouz ore deposit was accompanied by leaching of elements such as Al, Na, K, Rb, Ba, V, Hf, Cu, Zr, Tm, Yb, and Lu, enrichment of elements such as U, Nb, and Ta, and leaching-fixation of elements such as Si, Fe, Ca, Mg, Ti, Mn, P, Cs, Sr, Th, Co, Cr, Ni, Y, Ga, LREE, Tb, Dy, Ho, and Er. Incorporation of obtained results from mineralogical and geochemical studies show that physico-chemical conditions of alteration environment, the relative stability of primary minerals, surface adsorption, preferential sorption by metallic oxides, existing of organic matters, scavenging and concentration processes, and fixation in neomorphic mineralogical phases played important role in distribution of elements in the deposit. Geochemical studies show that development of the deposit is relative to two types of processes, (1 hypogene and (2 supergene. The distribution pattern of REEs indicates that differentiation degree of LREEs from HREEs in supergene kaolins is more than hypogene kaolins. Geochemical studies indicate that minerals such as Mn-oxides, zircon, anatase, hematite, cerianite, and secondary phosphates (monazite, rhabdophane, churchite, and zenotime are the potential hosts for rare earth elements in this deposit.

  1. Magmatic inclusions in rhyolites, contaminated basalts, and compositional zonation beneath the Coso volcanic field, California (United States)

    Bacon, C.R.; Metz, J.


    Basaltic lava flows and high-silica rhyolite domes form the Pleistocene part of the Coso volcanic field in southeastern California. The distribution of vents maps the areal zonation inferred for the upper parts of the Coso magmatic system. Subalkalic basalts (Coso volcanic field contain sparse andesitic inclusions (55-61% SiO2). Pillow-like forms, intricate commingling and local diffusive mixing of andesite and rhyolite at contacts, concentric vesicle distribution, and crystal morphologies indicative of undercooling show that inclusions were incorporated in their rhyolitic hosts as blobs of magma. Inclusions were probably dispersed throughout small volumes of rhyolitic magma by convective (mechanical) mixing. Inclusion magma was formed by mixing (hybridization) at the interface between basaltic and rhyolitic magmas that coexisted in vertically zoned igneous systems. Relict phenocrysts and the bulk compositions of inclusions suggest that silicic endmembers were less differentiated than erupted high-silica rhyolite. Changes in inferred endmembers of magma mixtures with time suggest that the steepness of chemical gradients near the silicic/mafic interface in the zoned reservoir may have decreased as the system matured, although a high-silica rhyolitic cap persisted. The Coso example is an extreme case of large thermal and compositional contrast between inclusion and host magmas; lesser differences between intermediate composition magmas and inclusions lead to undercooling phenomena that suggest smaller ??T. Vertical compositional zonation in magma chambers has been documented through study of products of voluminous pyroclastic eruptions. Magmatic inclusions in volcanic rocks provide evidence for compositional zonation and mixing processes in igneous systems when only lava is erupted. ?? 1984 Springer-Verlag.

  2. The Valle de Bravo Volcanic Field. A monogenetic field in the central front of the Mexican Volcanic Belt (United States)

    Aguirre-Diaz, G. J.; Jaimes-Viera, M. D.; Nieto-Obreg¢n, J.; Lozano-Santacruz, R.


    The Valle de Bravo volcanic field, VBVF, is located in the central-southern front of the Mexican Volcanic Belt just to the southwest of Nevado de Toluca volcano. The VBVF covers 3,703 square Km and includes at least 122 cinder cones, 1 shield volcano, several domes, and the 2 volcanic complexes of Zitacuaro and Villa de Allende. Morphometric parameters calibrated with isotopic ages of the volcanic products indicate four groups or units for the VBVF, Pliocene domes and lava flows, undifferentiated Pleistocene lava flows,> 40 Ka cones and lavas, 40 to 25 Ka cones and lavas, 25 to 10 Ka cones and lavas, and < 10 Ka cones and lavas. Whole-rock chemistry shows that all products of the VBVF range from basaltic andesites to dacites. No basalts were found, in spite of many units are olivine-rich and large some with large weight percent contents of MgO, 1 to 9. There is the possibility that some or all of the olivines in some samples could be xenocrysts. Some andesites are high in Sr, 1000 to 1800 ppm, that correlates with relatively high values of Ba, Cr, Ni, Cu, CaO and MgO. Y and Nb have the typical low values for orogenic rocks. The only shield volcano of the VBVF has a base of 9 Km, and its composition is practically the average composition of the whole field. Stratigraphycally, it is one of the earlier events of the VBVF. Compared with other volcanic fields of the Mexican Volcanic Belt, it lacks basalts and alkalic rocks. All volcanism of this field is calcalkaline

  3. The Quaternary history of effusive volcanism of the Nevado de Toluca area, Central Mexico (United States)

    Torres-Orozco, R.; Arce, J. L.; Layer, P. W.; Benowitz, J. A.


    Andesite and dacite lava flows and domes, and intermediate-mafic cones from the Nevado de Toluca area were classified into five groups using field data and 40Ar/39Ar geochronology constraints. Thirty-four lava units of diverse mineralogy and whole-rock major-element geochemistry, distributed between the groups, were identified. These effusive products were produced between ∼1.5 and ∼0.05 Ma, indicating a mid-Pleistocene older-age for Nevado de Toluca volcano, coexisting with explosive products that suggest a complex history for this volcano. A ∼0.96 Ma pyroclastic deposit attests for the co-existence of effusive and explosive episodes in the mid-Pleistocene history. Nevado de Toluca initiated as a composite volcano with multiple vents until ∼1.0 Ma, when the activity began to centralize in an area close to the present-day crater. The modern main edifice reached its maximum height at ca. 50 ka after bulky, spiny domes erupted in the current summit of the crater. Distribution and geochemical behavior in major elements of lavas indicate a co-magmatic relationship between different andesite and dacite domes and flows, although unrelated to the magmatism of the monogenetic volcanism. Mafic-intermediate magma likely replenished the system at Nevado de Toluca since ca. ∼1.0 Ma and contributed to the eruption of new domes, cones, as well as effusive-explosive activity. Altogether, field and laboratory data suggest that a large volume of magma was ejected around 1 Ma in and around the Nevado de Toluca.

  4. Geochemical Characterization of Late Pleistocene and Holocene Tephra Layers from the Basin of Mexico, Central Mexico (United States)

    Ortega-Guerrero, Beatriz; Newton, Anthony J.


    In order to aid palaeoenvironmental research of Late Pleistocene and Holocene deposits of central Mexico, tephra layers collected from the sediments of the Texcoco and Chalco sub-basins, in the southern part of the Basin of Mexico, are geochemically characterized and used as stratigraphic markers. The tephra layers range in composition from basaltic andesites to rhyolites and are calc-alkaline. The tephras range in age from >34,000 to ca. 2600 14C yr B.P. New names are used informally to designate correlated tephras. The Tlahuac tephra is present in Chalco, at a depth of 18 m; in the southeastern part of Texcoco, at a depth of around 10 m; and at the Tlapacoya archaeological site, where it had been mistakenly described as basaltic. This basalt-andesite tephra is dated to at least 34,000 14C yr B.P. The Tlapacoya 1 tephra is dated to between 15,020 ± 450 and 14,430 ± 190 yr B.P. and is present in all Chalco sections. The Tlapacoya 2 tephra corresponds to the previously described "pomez gruesa con fragmentos de andesita" (ca. 14,400 yr B.P.) and is present in all Chalco and Texcoco sections. The likely source of these three tephras is the volcano Popocatepetl. Tephra II at Chalco dates to 12,520 ± 135 yr B.P. and correlates with the Upper Toluca Pumice from Nevado de Toluca volcano. These represent the first geochemical glass-shard analysis of tephras from the Basin of Mexico, and so further research is necessary before a reliable tephrochronology can be established.

  5. Geological study of Ujungwatu area as support for NPP planning in Muria Central Java

    International Nuclear Information System (INIS)



    In accordance with growth of life in Java, the need for electricity is also growing accordingly. Efforts to provide electricity such as planning to build nuclear power plant (NPP) has been in the debate for a while. There are many factors to be considered in this planning, such as its environmental condition. Geological factor is one of the important one to be considered. Surface geological conditions around NPP area at Ujungwatu needed include stratigraphy, geological structure, geomorphology, and environmental geology. Geology in Ujungwatu at radius 5 km is quite interesting. This area is part of Genuk volcano group which is laid at south and Ujungwatu coast at north. Genuk mountain group is divided into mountain slope, mountain back, and mountain skeleton. Coastal area is composed of coast sand. Sand up to broken rock was present along river gullies. Others were volcanic rocks which was composed of lapili tuff, trachite, pyroxene andesite, tuff breccia, tephrite-andesitic tuff breccia, and basaltic tuff breccia. Volcanic structure is well reflected by morphological feature as lineaments and half circular form in mount Genuk. This structure was predominantly in NW-SE direction, and less dominant in NE-SW direction. Ujungwatu, from environmental view, is deserved to be developed because of its underground potency. Iron sand, fluvial tuff, kaolin, mud, riverstone, volcanic rock, tuff and marble were easily found underground. Those could be benefited to the people in the area so that it could change socio-economical condition of the people which in turn electricity is becoming a necessity. Last but not least, Portuguese fort as potential touristic object is also situated at Kartini beach near Ujungwatu. (author). 15 refs, 3 tabs, 5 figs

  6. Using noble gases and 87Sr/86Sr to constrain heat sources and fluid evolution at the Los Azufres Geothermal Field, Mexico (United States)

    Wen, T.; Pinti, D. L.; Castro, M. C.; Lopez Hernandez, A.; Hall, C. M.; Shouakar-Stash, O.; Sandoval-Medina, F.


    Geothermal wells and hot springs were sampled for noble gases' volume fraction and isotopic measurements and 87Sr/86Sr in the Los Azufres Geothermal Field (LAGF), Mexico, to understand the evolution of fluid circulation following three decades of exploitation and re-injection of used brines. The LAGF, divided into the Southern Production Zone (SPZ) and the Northern Production Zone (NPZ), is hosted in a Miocene to Pliocene andesitic volcanic complex covered by Quaternary rhyolitic-dacitic units. Air contamination corrected 3He/4He ratios (Rc) normalized to the atmospheric ratio (Ra=1.384 x 10-6), show a median value of 6.58 indicating a dominant mantle helium component. Contributions of crustal helium up to 53% and 18% are observed in NPZ and SPZ, respectively. Observations based on Rc/Ra and 87Sr/86Sr ratios points to the mixing of three magmatic sources supplying mantle helium to the LAGF: (1) a pure mantle He (Rc/Ra = 8) and Sr (87Sr/86Sr = 0.7035) source; (2) a pure mantle helium (Rc/Ra = 8) with some radiogenic Sr (87Sr/86Sr = 0.7049) source possibly resulting from Quaternary rhyolitic volcanism; and (3) a fossil mantle He component (Rc/Ra = 3.8) with some radiogenic Sr (87Sr/86Sr = 0.7038), corresponding possibly to the Miocene andesite reservoir. Intrusions within the last 50 kyrs from sources (1) and (2) are likely responsible for the addition of mantle volatiles and heat to the hydrothermal system of Los Azufres. He and Ar isotopes indicate that heat flow is transported by both convection and conduction. Atmospheric noble gas elemental ratios suggest that geothermal wells located closer to the western re-injection zone are beginning to be dominated by re-injection of used brines (injectate). The area affected by boiling in LAGF has further extended to the north and west since the last noble gas sampling campaign in 2009.

  7. Geothermometry and Geobarometry of Kepsut-Dursunbey Volcanites (NW Anatolia, Turkey): Implications for Magma Chamber Depth and Crystallization Conditions (United States)

    Kamaci, O.; Altunkaynak, S.


    The Kepsut-Dursunbey volcanic field (NW Turkey) contains various products of the Neogene magmatic activity. Two distinct volcanic suites have been recognized in the study area; Kepsut volcanic suite (KVS) and the Dursunbey volcanic suite (DVS). Both KVS and DVS are Early Miocene in age and representative for the post-collisional magmatism in western Anatolia. Mainly andesites, latites, basaltic andesites and pyroclastic rocks of KVS were formed during the early stage of volcanism in the study area. Without a major interruption in the volcanism, partly contemporanously, KVS followed by felsic volcanic products of DVS. Rhyolithic domes, lavas and extensive pyroclastic units were formed during this felsic volcanic activity. Both DVS and KVS display textural and chemical evidence for interaction of mafic and silicic magmas. This is evidenced by disequilibrium textures such as existence of rounded plagioclase phenocrysts with reaction rims (regrowth), hornblend -mantled clinopyroxenes (corona texture), synneusis, sieve textured plagioclase, patchy zones and oscilatory zoning in plagioclase phenocrysts. Basic lavas of KVS also contains xenocrysts represented by biotite mantled quartz and asidic plagioclase ovoids and glomerocrysts entrained from melt zones near base of the crust. The observed disequilibrium textures in both suites are provide evidence for magma mixing or Assimilation and fractional crystallization (AFC). Calculated pressures and temperatures using the amphibole-plagioclase geothermometer and Al-in-hornblend geobarometer give values of 5.7-7.0 kbar and 927-982 °C for the KVS and 3.7-5.3 kbar and 783-787°C for the DVS, indicating crystallization in magma chambers at deep and mid crustal levels; 21 km and 12 km, respectively. A main deep magma reservoir served as a source for the intermediate to basic lavas of KVS. The existence of similar mixing-compatible (disequilibrium) textures in both KVS and DVS support the establishment and evolution of KDVF magma

  8. Ciclos tectónicos, volcánicos y sedimentarios del Cenozoico del sur de Mendoza-Argentina (35°-37°S y 69°30'W Cenozoic tectonic, volcanic and sedimentary cycles in southern Mendoza Province, Argentina (35°-37°S y 69°30'W

    Directory of Open Access Journals (Sweden)

    Ana María Combina


    Full Text Available En este trabajo se describe la estratigrafía sedimentaria y volcánica asociada a los procesos de deformación de las unidades con edades del Cretácico Tardío al Plioceno Tardío aflorantes en el sur de Mendoza, Argentina, entre los ríos Atuel y Barrancas en el ámbito de la Cordillera Principal. Se proponen tres ciclos tectovolcano-sedimentarios, limitados por discordancias regionales generadas por la acción de las Fases Incaica, Quechua, Pehuenche y Diaguita. El primer ciclo comprende las unidades volcánicas y sedimentarias del Cretácico Superior hasta el Oligoceno Superior (Formaciones Roca y Pircala-Coihueco y el Ciclo Eruptivo Molle. El segundo abarca desde el Oligoceno Tardío al Mioceno Tardío (Formación Agua de la Piedra y las Andesitas Huincán. Por último, el tercer ciclo comprende desde el Mioceno Tardío al Plioceno (Formaciones Butaló, Pincheiras, Loma Fiera, Río Diamante y las Andesitas La Brea.This article describes the volcanic and sedimentary stratigraphy and their associated proces-ses with the Andean deformation during the Late Cretaceous to Late Pliocene. The studied área is located between the Atuel and Barrancas rivers and the Main Cordillera, in southern Mendoza, Argentina. Three tectovolcano-sedimentary cycles limited by regional discordances (Inca, Quechua, Pehuenche and Diaguita are proposed. The first comprises Upper Oligocene to Upper Miocene volcanic and sedimentary units (Roca and Pircala-Coihueco formations and the Volcanic Cycle Molle. The second extends from the Late Oligocene to Late Miocene (Agua de la Piedra Formation and the Huincán Andesites volcanic cycle. Finally, the third cycle ranges from the Late Miocene to Pliocene (Butaló, Pincheiras, Loma Fiera and Rio Diamante formations and La Brea Andesites.

  9. The Early Mesozoic volcanic arc of western North America in northeastern Mexico (United States)

    Barboza-Gudiño, José Rafael; Orozco-Esquivel, María Teresa; Gómez-Anguiano, Martín; Zavala-Monsiváis, Aurora


    Volcanic successions underlying clastic and carbonate marine rocks of the Oxfordian-Kimmeridgian Zuloaga Group in northeastern Mexico have been attributed to magmatic arcs of Permo-Triassic and Early Jurassic ages. This work provides stratigraphic, petrographic geochronological, and geochemical data to characterize pre-Oxfordian volcanic rocks outcropping in seven localities in northeastern Mexico. Field observations show that the volcanic units overlie Paleozoic metamorphic rocks (Granjeno schist) or Triassic marine strata (Zacatecas Formation) and intrude Triassic redbeds or are partly interbedded with Lower Jurassic redbeds (Huizachal Group). The volcanic rocks include rhyolitic and rhyodacitic domes and dikes, basaltic to andesitic lava flows and breccias, and andesitic to rhyolitic pyroclastic rocks, including breccias, lapilli, and ashflow tuffs that range from welded to unwelded. Lower-Middle Jurassic ages (U/Pb in zircon) have been reported from only two studied localities (Huizachal Valley, Sierra de Catorce), and other reported ages (Ar/Ar and K-Ar in whole-rock or feldspar) are often reset. This work reports a new U/Pb age in zircon that confirms a Lower Jurassic (193 Ma) age for volcanic rocks exposed in the Aramberri area. The major and trace element contents of samples from the seven localities are typical of calc-alkaline, subduction-related rocks. The new geochronological and geochemical data, coupled with the lithological features and stratigraphic positions, indicate volcanic rocks are part of a continental arc, similar to that represented by the Lower-Middle Jurassic Nazas Formation of Durango and northern Zacatecas. On that basis, the studied volcanic sequences are assigned to the Early Jurassic volcanic arc of western North America.

  10. The Wyoming gold deposits: volcanic-hosted lode-type gold mineralisation in the eastern Lachlan Orogen, Australia (United States)

    Chalmers, D. Ian; Ransted, Terry W.; Kairaitis, Rimas A.; Meates, David G.


    The eastern Lachlan Orogen in southeastern Australia is noted for its major porphyry-epithermal-skarn copper-gold deposits of late Ordovician age. Whilst many small quartz vein-hosted or orogenic lode-type gold deposits are known in the region, the discovery of the Wyoming gold deposits has demonstrated the potential for significant lode-type mineralisation hosted within the same Ordovician volcanic stratigraphy. Outcrop in the Wyoming area is limited, with the Ordovician sequence largely obscured by clay-rich cover of probable Quaternary to Cretaceous age with depths up to 50 m. Regional aeromagnetic data define a north-south trending linear belt interpreted to represent the Ordovician andesitic volcanic rock sequence within probable Ordo-Silurian pelitic metasedimentary rocks. Drilling through the cover sequence in 2001 to follow up the trend of historically reported mineralisation discovered extensive alteration and gold mineralisation within an andesitic feldspar porphyry intrusion and adjacent volcaniclastic sandstones and siltstones. Subsequent detailed resource definition drilling has identified a substantial mineralised body associated with sericite-carbonate-albite-quartz-(±chlorite ± pyrite ± arsenopyrite) alteration. The Wyoming deposits appear to have formed as the result of a rheological contrast between the porphyry host and the surrounding volcaniclastic rocks, with the porphyry showing brittle fracture and the metasedimentary rocks ductile deformation. The mineralisation at Wyoming bears many petrological and structural similarities to orogenic lode-style gold deposits. Although the timing of alteration and mineralisation in the Wyoming deposits remain problematic, a relationship with possible early to middle Devonian deformation is considered likely.

  11. Late Pleistocene flank collapse of Zempoala volcano (Central Mexico) and the role of fault reactivation (United States)

    Arce, José Luis; Macías, Rodolfo; García Palomo, Armando; Capra, Lucia; Macías, José Luis; Layer, Paul; Rueda, Hernando


    Zempoala is an extinct Pleistocene (˜ 0.7-0.8 Ma) stratovolcano that together with La Corona volcano (˜ 0.9 Ma) forms the southern end of the Sierra de las Cruces volcanic range, Central Mexico. The volcano consists of andesitic and dacitic lava flows and domes, as well as pyroclastic and epiclastic sequences, and has had a complex history with several flank collapses. One of these collapses occurred during the late Pleistocene on the S-SE flank of the volcano and produced the Zempoala debris avalanche deposit. This collapse could have been triggered by the reactivation of two normal fault systems (E-W and NE-SW), although magmatic activity cannot be absolutely excluded. The debris avalanche traveled 60 km to the south, covers an area of 600 km 2 and has a total volume of 6 km 3, with a calculated Heim coefficient (H/L) of 0.03. Based on the textural characteristics of the deposit we recognized three zones: proximal, axial, and lateral distal zone. The proximal zone consists of debris avalanche blocks that develop a hummocky topography; the axial zone corresponds with the main debris avalanche deposit made of large clasts set in a sandy matrix, which transformed to a debris flow in the lateral distal portion. The deposit is heterolithologic in composition, with dacitic and andesitic fragments from the old edifice that decrease in volume as bulking of exotic clasts from the substratum increase. Several cities (Cuernavaca, Jojutla de Juárez, Alpuyeca) with associated industrial, agricultural, and tourism activities have been built on the deposit, which pose in evidence the possible impact in case of a new event with such characteristics, since the area is still tectonically active.

  12. The isotopic and chemical evolution of Mount St. Helens (United States)

    Halliday, A.N.; Fallick, A.E.; Dickin, A.P.; Mackenzie, A.B.; Stephens, W.E.; Hildreth, W.


    Isotopic and major and trace element analysis of nine samples of eruptive products spanning the history of the Mt. St. Helens volcano suggest three different episodes; (1) 40,000-2500 years ago: eruptions of dacite with ??{lunate}Nd = +5, ??{lunate}Sr = -10, variable ??18O, 206Pb/204Pb ??? 18.76, Ca/Sr ??? 60, Rb/Ba ??? 0.1, La/Yb ??? 18, (2) 2500-1000 years ago: eruptions of basalt, andesite and dacite with ??{lunate}Nd = +4 to +8, ??{lunate}Sr = -7 to -22, variable ??18O (thought to represent melting of differing mantle-crust reservoirs), 206Pb/204Pb = 18.81-18.87, variable Ca/Sr, Rb/Ba, La/Yb and high Zr, (3) 1000 years ago to present day: eruptions of andesite and dacite with ??{lunate}Nd = +6, ??{lunate}Sr = -13, ??18O ???6???, variable 206Pb/204Pb, Ca/Sr ??? 77, Rb/Ba = 0.1, La/Yb ??? 11. None of the products exhibit Eu anomalies and all are LREE enriched. There is a strong correlation between 87Sr/86Sr and differentiation indices. These data are interpreted in terms of a mantle heat source melting young crust bearing zircon and garnet, but not feldspar, followed by intrusion of this crustal reservoir by mantle-derived magma which caused further crustal melting and contaminated the crustal magma system with mafic components. Since 1000 years ago all the eruptions have been from the same reservoir which has displayed a much more gradual re-equilibration of Pb isotopic compositions than other components suggesting that Pb is being transported via a fluid phase. The Nd and Sr isotopic compositions lie along the mantle array and suggest that the mantle underneath Mt. St. Helens is not as depleted as MORB sources. There is no indication of seawater involvement in the source region. ?? 1983.

  13. Geochronology and geochemistry of Early Cretaceous igneous units from the central Sulu orogenic belt: Evidence for crustal delamination during a shift in the regional tectonic regime (United States)

    Wang, Jun; Chang, Su-Chin; Wang, Kuo-Lung; Lu, Hong-Bo; Zhang, Hai-Chun


    Widespread Late Mesozoic igneous events in northern China have been intensively investigated over the past decades and provide evidence for regional lithospheric thinning. The underlying mechanism causing lithospheric thinning remains unclear however. This study reports U-Pb zircon ages, geochemical data and isotopic ratios for Cretaceous igneous units from the central Sulu orogenic belt as it occurs in the Shandong Peninsula. LA-ICP-MS U-Pb analyses of magmatic zircons identified a relatively restricted population of ages ranging from 123 ± 2 Ma to 120 ± 2 Ma from four representative samples of igneous units in the study area. Geochemical analysis of the samples revealed LREE and LILE enrichment, HREE depletion, high initial 87Sr/86Sr values ranging from 0.7040 to 0.7096, and low negative εNd(t) values from -22.0 to -12.2. The data suggest lamprophyres derived separately from heterogeneous mantle inputs, which experienced crust-mantle interaction, andesitic porphyrites and syenogranites derived from enriched lithospheric mantle and rhyolites derived from partial melting of an ancient crustal component. Assimilation and fractionation processes did not contribute to lamprophyre formation, but did play an important role in generating andesitic porphyrites, syenogranites and rhyolites. The petrogenetic history of these rocks indicates intensive lithospheric thinning of the upper mantle and lower crust beneath the Sulu orogenic belt at 123-120 Ma. Given the timing and regional tectonic framework in which these units formed, thinning was likely caused by an abrupt change in the direction of the subducting Pacific plate.

  14. Eruptions with short run-up times: review of controlling factors inspired by the unexpected eruption of Calbuco volcano, April 2015, (Southern Andes) (United States)

    Lara, L.; Esperger, S.


    Signs of unrest are usually detected in active volcanoes before the onset of eruptions. However, a few eruptions start suddenly without evident precursory activity or very short run-up time. The latter poses a challenge to volcano observatories regarding the capability to issue early warnings. Calbuco (42°S, Southern Andes) explosive event in April 2015 is a recent case where clear signs of unrest were detected shortly before the eruption of an andesitic magma (57% SiO2). In fact, although isolated low magnitude VT events were recorded 2 months before, the base level was only disturbed 3 hours before by an emergent seismic swarm of MCalbuco erupted after 54 years of quiescence and no ground deformation was detected by InSAR or ground-based methods before the eruption. This short precursory activity is comparable to run-up times observed in basaltic to andesitic volcanoes. Previous authors have proposed a relationship between repose and run-up times. Repose time seems to be related with dynamics of plumbing systems (recharge and storage) and thus depends on the magma viscosity and hence magma composition. Others have shown that correlation between repose and run-up times is dependent of volcano typology. Here we expand the catalog and consider other factors as the crustal thickness, physical properties of the country rocks, depth of magma chambers and tectonic regime for all the reported eruptions with existing information. Our findings show that eruptions preceded by an extremely short unrest period occur mostly under conditions of favorable (tectonically-controlled) magma pathways unclamping, even in high-silica systems with large repose times.

  15. Sr and Nd isotope geochemistry and tectonics during subduction and rifting in Sierra Santa Ursula, Sonora, Northwestern Mexico

    International Nuclear Information System (INIS)

    Mora-Klepeis, G.


    The western margin of North America was affected by a convergent plate boundary from the Cretaceous through the Early Tertiary. Volcanic rocks produced by subduction-related arc magmatism in northwestern Mexico are concentrated in two northwest-trending belts subparallel to the continental margin. One of these is the Sierra Madre Occidental, where mid-Tertiary magmatism consisted mostly of calc-alkaline rhyolitic ignimbrite and minor andesite produced between ∼ 46 and 28 Ma (McDowell et al., 1990). The second (younger) northwest-trending belt is located along the eastern margin of the Baja California Peninsula and in the Gulf of California region of mainland Mexico. This belt is composed mostly of andesite, but includes some basalt and dacite whose ages range from about 24 to 11 Ma (Hausback, 1984). A transition to rifting began after a mid-Tertiary cessation of subduction, eventually creating the Gulf of California extensional province. Four markedly different magma types comprising mainly tholeiitic and alkalic rocks and minor calc-alkaline and peralkaline rocks were erupted throughout the last 13 Ma and record the history of rifting of the Gulf of California (Sawlan, 1991). The aim of the present paper is to distinguish the nature of the 24-8.5 Ma magmatism emplaced on the eastern side of the Gulf of California in the state of Sonora, by the use of stratigraphic, geochemical and isotopic data. Preliminary Sr and Nd results show that three groups of magmas are present in the area suggesting a heterogeneous source. This can be interpreted as the result of magmas being erupted at different stages of subduction and rifting during the tectonic evolution of this part on North America

  16. Evolution by Replenishment Fractional Crystallization (RFC) of Midproterozoic Magmatic Enclaves in Granites of the Eastern Llano Uplift, central Texas, U.S.A (United States)

    Smith, R. K.; Gray, W.


    The Llano Uplift is a gentle structural dome exposing both island-arc and continental margin blocks emplaced along the southern margin of Laurentia during the Grenville orogeny (locally the Llano orogeny). These ~1370 to 1230 Ma metaigneous and metasedimentary rocks were subsequently intruded by a number of ~1119 to 1070 Ma post-to syntectonic granitic plutons collectively known as the Town Mountain Granite. The eastern most of these plutons (Lone Grove, Kingsland, and Marble Falls plutons) contain sparse microgranular magmatic enclaves of intermediate composition (56-68 wt.% SiO2). The enclaves display sharp borders in contact with the host granite suggesting magma quenching with little or no physical exchange between host granite and enclave magma. The origin of the enclave magma(s) is uncertain, as no synchronous mafic to intermediate rocks are exposed in the Uplift. New major- and trace-element analyses are providing clues as to the possible origins and evolution of the enclave magmas. Numerical modeling reveals that neither fractional crystallization nor simple mixing can explain the trace-element trends. However, assuming source magmas similar to primitive continental arc andesites, the trends can be adequately replicated by a replenishment fractional crystallization(RFC) model. The model assumes that replenishment/hybridization events are accompanied by 20%-30% fractionation of plagioclase + clinopyroxene + magnetite. Modeling further reveals that results are relatively insensitive to the number of replenishment events (from 50 to 1000), as well as perturbations in the mineral percentages, suggesting that RFC is a very plausible and robust explanation for the chemical evolution of the enclaves. As suggested by Weibe et al. (1997), RFC and lack of magma exchange may be indicative of enclave magma ponding and hybridization at the base of the host granite magma chamber, followed by occasional dispersment into the host granite. Origin from a primitive

  17. Geomorphology and petrography of the Angeles lava flow and the Monte de la Cruz cinder cone, Barva Volcano, Costa Rica

    International Nuclear Information System (INIS)

    Rojas, Vanessa; Barahona, Dione; Alvarado, Guillermo E


    A geomorphological and pretrographic study was carried out at the lava flow Angeles and the Monte de la Cruz cone in the foothills of the Volcan Barva in Costa Rica. The 1967 aerial photographs at scale 1: 17,000 and 1: 13,000, 1992 at scale 1: 60,000 and TERRA 1997 at scale 1: 40,000 were used for the photogeological study, supplemented with the analysis of the eastern sector of the Hoja Topografica Barva (1: 50 000) of the Instituto Geografico Nacional (IGN) and other topographic maps at different scales (1: 25 000 and 1: 10 000), in addition to the digital elevation models developed through Sistemas de Informacion Geografica (SIG). The information extracted from the wells of the Sistema Nacional de Aguas Subterraneas, Riego y Avenamiento (SENARA) for underground control was reinterpreted. In the field work thicknesses were measured and an estimation of the volumes, dimensions of the cast and other associated geoforms was made. Likewise, 9 samples of rock were selected for the elaboration of thin sections and for their respective petrographic analysis, which allowed to define the main lava flow units and their possible flows. As a result of the volcanic activity of the cone, two flow units of the Angeles wash were identified, the Lower Angels unit and the Superior Angels unit. Petrographically, Angeles Inferior was reciprocated with an andesitic vesical basaltic lava with a porphyritic to slightly glomeroporphyric hypocrystalline texture, with plagioclase, clinopyroxene, orthopyroxene, olivine and opaque phenocrysts. On the other hand, Superior Angeles has been vesicular andesitic with a hypocrystalline texture, glomeroporfiritica to serial glomeroporfiritica, with plagioclase, clinopyroxene, orthopyroxene, olivine and opaque phenocrysts. Morphologically, kipukas and levees were observed. Regionally, it was observed that the Monte de la Cruz cone, along with other smaller satellite cones, are aligned N19 O W along 8.5 km, evidencing an origin associated with a

  18. Petrologic evaluation of Pliocene basaltic volcanism in Eastern Anatolian region, Turkey: Evidence for mixing of melts derived from both shallow and deep mantle sources (United States)

    Oyan, Vural; Özdemir, Yavuz; Keskin, Mehmet; Güleç, Nilgün


    Collision-related Neogene volcanism in the Eastern Anatolia region (EAR) began after the continent-continent collision between the Arabia and the Eurasia plates, and spreads in a wide zone from the Erzurum-Kars Plateau in the northeast to the Karacadaǧ in the south. Volcanic activity in the EAR started 15 Ma ago (Middle Miocene) in the south of the region. Voluminous basaltic lavas from local eruption centers formed basaltic lava plateaus and volcanic cones as a result of high production level of volcanism during the Pliocene time interval. Our dating results (Ar-Ar and K-Ar) indicate that age of this Late Miocene-Pliocene magmatic activity range between 6 and 3.5 Ma. Volcanic products contain alkaline and subalkaline lavas, ranging in composition from basalts to andesites and trachyandesites. Our EC-AFC and AFC modeling, based on trace element and Sr, Nd, Pb isotopic compositions, suggests about 2-7 % crustal contamination in the evolved andesites and trachyandesites. MORB and primitive mantle normalized patterns of the lavas and isotopic compositions imply that alkaline and subalkaline basalts erupted in Pliocene time interval in the EAR could have been derived from a mantle source that had previously been enriched by a clear subduction component. A partial melting model was conducted to evaluate partial melting processes in the mantle source of the Pliocene basalts. Our melting model calculations suggest that basaltic melts in the EAR could have been produced by melting of mantle sources containing spinel, garnet and amphibole with melting degree in the range of 0.7-7%. The products of mixing of these derivative melts are the Pliocene basaltic lavas of the Eastern Anatolian Region.

  19. Chemical and Mineralogical Features of Smectite from the Morron de Mateo Bentonite Deposit (Cabo de Gata, Almeria) in Relation to the Parent Rocks and the Alteration Processes Occurred After the Bentonite Formation: Analogies and Implications for the Engineered Clayey Barrier of a Deep Geological Rad waste Repository; Naturaleza de las Esmectitas del Yacimiento de Morron de Mateo (Cabo de Gata, Almeria) en Relacion con la Roca Madre y con los Procesos Posteriores a la Bentonitizacion: Implicaciones Analogicas para la Barrera de Ingenieria de un Almacenamiento Geologico de Residuos Radiactivos

    Energy Technology Data Exchange (ETDEWEB)

    Pelayo, M.; Labajo, M. A.; Garcia Romero, L.; Perez del Villar, L.


    The Morron de Mateo bentonite deposit is being studied as a natural analogue of the thermal and geochemical effects on the clayey barrier of a Deep Geological Rad waste Repository (DGRR) after its closure, in relation to the radioactive decay of the fission products and the container corrosion. This bentonite deposit and their host rocks were intruded by a rhyodacitic volcanic dome that induced a hydrothermal metasomatic process affecting the bioclastic calcarenite beds close to the dome. Bentonite from the NE sector of the deposit have been chemically and mineralogically characterized. Pyroclastic rocks (white tuffs), epyclastic rocks (mass flow) and andesitic breccia all of them hydrothermally altered, have been studied at the site. Samples are composed of feldspars, quartz and amphybols, as inherited minerals, and phyllosilicates, zeolites, crystoballite and calcite, as new formed minerals. White tuffs have the highest phyllosilicate contents, mainly dioctahedral smectite of montmorillonite type. Epyclastic rocks and andesitic breccia have a highest proportion of inherited minerals, the new formed phillosilicates being di octahedral smectite of beidellite type and an ordered interlayer chlorite/smectite mineral, of corrensite type. Smectite from the epyclastic rocks have higher Fe and Mg contents and chemical variability, as a consequence of nature of their parent rocks. The presence of corrensite in the epyclastic rocks suggests that in the Morron de Mateo area a propilitic alteration process occurred after bentonite formation, which transformed Fe-Mg-rich smectite into corrensite. This transformation was probably favoured by the sub volcanic intrusion, which also produced a temperature increase in the geological media and a supply of Fe-Mg-rich solutions, which also were the responsible for the metasomatic transformations observed in the calcarenite beds. (Author) 57 refs.

  20. Variations in eruption style during the 1931 A.D. eruption of Aniakchak volcano, Alaska (United States)

    Nicholson, Robert S.; Gardner, James E.; Neal, Christina A.


    The 1931 A.D. eruption of Aniakchak volcano, Alaska, progressed from subplinian to effusive eruptive style and from trachydacite to basaltic andesite composition from multiple vent locations. Eyewitness accounts and new studies of deposit stratigraphy provide a combined narrative of eruptive events. Additional field, compositional, grain size, componentry, density, and grain morphology data document the influences on changing eruptive style as the eruption progressed. The eruption began on 1 May 1931 A.D. when a large subplinian eruption column produced vesicular juvenile-rich tephra. Subsequent activity was more intermittent, as magma interacted with groundwater and phreatomagmatic ash and lithic-rich tephra was dispersed up to 600 km downwind. Final erupted products were more mafic in composition and the eruption became more strombolian in style. Stratigraphic evidence suggests that two trachydacitic lava flows were erupted from separate but adjacent vents before the phreatomagmatic phase concluded and that basaltic andesite lava from a third vent began to effuse near the end of explosive activity. The estimated total bulk volume of the eruption is 0.9 km3, which corresponds to approximately 0.3 km3 of magma. Eruption style changes are interpreted as follows: (1) a decrease in magma supply rate caused the change from subplinian to phreatomagmatic eruption; (2) a subsequent change in magma composition caused the transition from phreatomagmatic to strombolian eruption style. Additionally, the explosion and effusion of a similar magma composition from three separate vents indicates how the pre-existing caldera structure controlled the pathway of shallow magma ascent, thus influencing eruption style.

  1. Late Triassic porphyritic intrusions and associated volcanic rocks from the Shangri-La region, Yidun terrane, Eastern Tibetan Plateau: Adakitic magmatism and porphyry copper mineralization (United States)

    Wang, Bai-Qiu; Zhou, Mei-Fu; Li, Jian-Wei; Yan, Dan-Ping


    Early Mesozoic porphyritic intrusions in the Shangri-La region, southern Yidun terrane, SW China, are spatially associated with andesites and dacites. These intrusions are composed of diorite and quartz diorite, and are closely related to copper mineralization. LA-ICP-MS zircon U-Pb ages of the intrusions range from 230 to 215 Ma. The associated andesites and dacites are interlayered with slates and sandstones and have ages of around 220 Ma. All of the intrusive and extrusive rocks have similar, highly fractionated REE patterns and high La/Yb (13-49) ratios with no prominent Eu anomalies. They display pronounced negative Nb-Ta and Ti anomalies on primitive mantle-normalized spidergrams. Their SiO2 contents range from 56.6 to 67.1 wt.%, Al2O3 from 14.2 to 17.4 wt.% and MgO from1.9 to 4.2 wt.%. All the rocks have high Sr (258-1980 ppm), and low Y (13-21 ppm) with high Sr/Y ratios (29-102). These features suggest that both the volcanic rocks and porphyritic intrusions were derived from adakitic magmas. They have similar initial 87Sr/86Sr ratios (0.7058 to 0.7077) and εNd (- 1.88 to - 4.93) values, but belong to high silica (HSA) and low silica adakitic rocks (LSA). The HSA represent an early stage of magmatism (230 to 215 Ma) and were derived from oceanic slab melts with limited interaction with the overlying mantle wedge during ascent. At 215 Ma, more extensive interaction produced the LSA. We propose that the early adakitic magmas (HSA) formed by flat subduction leading to melting of oceanic slab, whereas subsequent slab break-off caused the significant interaction between slab melts and the mantle wedge and thus the generation of the later adakitic magmas (LSA).

  2. Environmental effect and genetic influence: a regional cancer predisposition survey in the Zonguldak region of Northwest Turkey (United States)

    Kadir, Selahattin; Önen-Hall, A. Piril; Aydin, S. Nihal; Yakicier, Cengiz; Akarsu, Nurten; Tuncer, Murat


    The Cretaceous-Eocene volcano-sedimentary units of the Zonguldak region of the western Black Sea consist of subalkaline andesite and tuff, and sandstone dominated by smectite, kaolinite, accessory chlorite, illite, mordenite, and analcime associated with feldspar, quartz, opal-CT, amphibole, and calcite. Kaolinization, chloritization, sericitization, albitization, Fe-Ti-oxidation, and the presence of zeolite, epidote, and illite in andesitic rocks and tuffaceous materials developed as a result of the degradation of a glass shards matrix, enclosed feldspar, and clinopyroxene-type phenocrysts, due to alteration processes. The association of feldspar and glass with smectite and kaolinite, and the suborientation of feldspar-edged, subparallel kaolinite plates to fracture axes may exhibit an authigenic smectite or kaolinite. Increased alteration degree upward in which Al, Fe, and Ti are gained, and Si, Na, K, and Ca are depleted, is due to the alteration following possible diagenesis and hydrothermal activities. Micromorphologically, fibrous mordenite in the altered units and the presence of needle-type chrysotile in the residential buildings in which cancer cases lived were detected. In addition, the segregation pattern of cancer susceptibility in the region strongly suggested an environmental effect and a genetic influence on the increased cancer incidence in the region. The most likely diagnosis was Li-Fraumeni syndrome, which is one of the hereditary cancer predisposition syndromes; however, no mutations were observed in the p53 gene, which is the major cause of Li-Fraumeni syndrome. The micromorphology observed in the altered units in which cancer cases were detected may have a role in the expression of an unidentified gene, but does not explain alone the occurrence of cancer as a primary cause in the region.

  3. Hydrogen in rocks: an energy source for deep microbial communities (United States)

    Freund, Friedemann; Dickinson, J. Thomas; Cash, Michele


    To survive in deep subsurface environments, lithotrophic microbial communities require a sustainable energy source such as hydrogen. Though H2 can be produced when water reacts with fresh mineral surfaces and oxidizes ferrous iron, this reaction is unreliable since it depends upon the exposure of fresh rock surfaces via the episodic opening of cracks and fissures. A more reliable and potentially more voluminous H2 source exists in nominally anhydrous minerals of igneous and metamorphic rocks. Our experimental results indicate that H2 molecules can be derived from small amounts of H2O dissolved in minerals in the form of hydroxyl, OH- or O3Si-OH, whenever such minerals crystallized in an H2O-laden environment. Two types of experiments were conducted. Single crystal fracture experiments indicated that hydroxyl pairs undergo an in situ redox conversion to H2 molecules plus peroxy links, O3Si/OO\\SiO3. While the peroxy links become part of the mineral structure, the H2 molecules diffused out of the freshly fractured mineral surfaces. If such a mechanism occurred in natural settings, the entire rock column would become a volume source of H2. Crushing experiments to facilitate the outdiffusion of H2 were conducted with common crustal igneous rocks such as granite, andesite, and labradorite. At least 70 nmol of H2/g diffused out of coarsely crushed andesite, equivalent at standard pressure and temperature to 5,000 cm3 of H2/m3 of rock. In the water-saturated, biologically relevant upper portion of the rock column, the diffusion of H2 out of the minerals will be buffered by H2 saturation of the intergranular water film.

  4. Petrophysical Properties of Twenty Drill Cores from the Los Azufres, Mexico, Geothermal Field

    Energy Technology Data Exchange (ETDEWEB)

    Iglesias, E.R.; Contreras L., E.; Garcia G., A.; Dominquez A., Bernardo


    For this study we selected 20 drill cores covering a wide range of depths (400-3000 m), from 15 wells, that provide a reasonable coverage of the field. Only andesite, the largely predominant rock type in the field, was included in this sample. We measured bulk density, grain (solids) density, effective porosity and (matrix) permeability on a considerable number of specimens taken from the cores; and inferred the corresponding total porosity and fraction of interconnected total porosity. We characterized the statistical distributions of the measured and inferred variables. The distributions of bulk density and grain density resulted approximately normal; the distributions of effective porosity, total porosity and fraction of total porosity turned out to be bimodal; the permeability distribution resulted highly skewed towards very small (1 mdarcy) values, though values as high as 400 mdarcies were measured. We also characterized the internal inhomogeneity of the cores by means of the ratio (standard deviation/mean) corresponding to the bulk density in each core (in average there are 9 specimens per core). The cores were found to present clearly discernible inhomogeneity; this quantitative characterization will help design new experimental work and interpret currently available and forthcoming results. We also found statistically significant linear correlations between total density and density of solids, effective porosity and total density, total porosity and total density, fraction of interconnected total porosity and the inverse of the effective porosity, total porosity and effective porosity; bulk density and total porosity also correlate with elevation. These results provide the first sizable and statistically detailed database available on petrophysical properties of the Los Azufres andesites. 1 tab., 16 figs., 4 refs.

  5. Orthopyroxene-enrichment in the lherzolite-websterite xenolith suite from Paleogene alkali basalts of the Poiana Ruscă Mountains (Romania

    Directory of Open Access Journals (Sweden)

    Nédli Zsuzsanna


    Full Text Available In this paper we present the petrography and geochemistry of a recently collected lherzolite-websterite xenolith series and of clinopyroxene xenocrysts, hosted in Upper Cretaceous–Paleogene basanites of Poiana Ruscă (Romania, whose xenoliths show notable orthopyroxene-enrichment. In the series a slightly deformed porphyroclastic-equigranular textured series could represent the early mantle characteristics, and in many cases notable orthopyroxene growth and poikilitic texture formation was observed. The most abundant mantle lithology, Type A xenoliths have high Al and Na-contents but low mg# of the pyroxenes and low cr# of spinel suggesting a low degree (< 10 % of mafic melt removal. They are also generally poor in overall REE-s (rare earth elements and have flat REY (rare earth elements+ Y patterns with slight LREE-depletion. The geochemistry of the Type A xenoliths and calculated melt composition in equilibrium with the xenolith clinopyroxenes suggests that the percolating melt causing the poikilitization can be linked to a mafic, Al-Na-rich, volatile-poor melt and show similarity with the Late Cretaceous–Paleogene (66–72 Ma subduction-related andesitic magmatism of Poiana Ruscă. Type B xenoliths, with their slightly different chemistry, suggest that, after the ancient depletion, the mantle went through a slight metasomatic event. A subsequent passage of mafic melts in the mantle, with similar compositions to the older andesitic magmatism of Poiana Ruscă, is recorded in the pyroxenites (Fe-rich xenoliths, whereas the megacrysts seem to be cogenetic with the host basanite. The Poiana Ruscă xenoliths differ from the orthopyroxene-enriched mantle xenoliths described previously from the Carpathian-Pannonian Region and from the Dacia block.

  6. U–Pb geochronology and geochemistry of late Palaeozoic volcanism in Sardinia (southern Variscides

    Directory of Open Access Journals (Sweden)

    L. Gaggero


    Full Text Available The latest Carboniferous to lower Permian volcanism of the southern Variscides in Sardinia developed in a regional continental transpressive and subsequent transtensile tectonic regime. Volcanism produced a wide range of intermediate–silicic magmas including medium- to high-K calc-alkaline andesites, dacites, and rhyolites. A thick late Palaeozoic succession is well exposed in the four most representative Sardinian continental basins (Nurra, Perdasdefogu, Escalaplano, and Seui–Seulo, and contains substantial stratigraphic, geochemical, and geochronological evidence of the area's complex geological evolution from the latest Carboniferous to the beginning of the Triassic. Based on major and trace element data and LA-ICP-MS U–Pb zircon dating, it is possible to reconstruct the timing of post-Variscan volcanism. This volcanism records active tectonism between the latest Carboniferous and Permian, and post-dates the unroofing and erosion of nappes in this segment of the southern Variscides. In particular, igneous zircon grains from calc-alkaline silicic volcanic rocks yielded ages between 299 ± 1 and 288 ± 3 Ma, thereby constraining the development of continental strike-slip faulting from south (Escalaplano Basin to north (Nurra Basin. Notably, andesites emplaced in medium-grade metamorphic basement (Mt. Cobingius, Ogliastra show a cluster of older ages at 332 ± 12 Ma. Despite the large uncertainty, this age constrains the onset of igneous activity in the mid-crust. These new radiometric ages constitute: (1 a consistent dataset for different volcanic events; (2 a precise chronostratigraphic constraint which fits well with the biostratigraphic data and (3 insights into the plate reorganization between Laurussia and Gondwana during the late Palaeozoic evolution of the Variscan chain.

  7. Chemical and Mineralogical Features of Smectite from the Morron de Mateo Bentonite Deposit (Cabo de Gata, Almeria) in Relation to the Parent Rocks and the Alteration Processes Occurred After the Bentonite Formation: Analogies and Implications for the Engineered Clayey Barrier of a Deep Geological Rad waste Repository

    International Nuclear Information System (INIS)

    Pelayo, M.; Labajo, M. A.; Garcia Romero, L.; Perez del Villar, L.


    The Morron de Mateo bentonite deposit is being studied as a natural analogue of the thermal and geochemical effects on the clayey barrier of a Deep Geological Rad waste Repository (DGRR) after its closure, in relation to the radioactive decay of the fission products and the container corrosion. This bentonite deposit and their host rocks were intruded by a rhyodacitic volcanic dome that induced a hydrothermal metasomatic process affecting the bioclastic calcarenite beds close to the dome. Bentonite from the NE sector of the deposit have been chemically and mineralogically characterized. Pyroclastic rocks (white tuffs), epyclastic rocks (mass flow) and andesitic breccia all of them hydrothermally altered, have been studied at the site. Samples are composed of feldspars, quartz and amphybols, as inherited minerals, and phyllosilicates, zeolites, crystoballite and calcite, as new formed minerals. White tuffs have the highest phyllosilicate contents, mainly dioctahedral smectite of montmorillonite type. Epyclastic rocks and andesitic breccia have a highest proportion of inherited minerals, the new formed phillosilicates being di octahedral smectite of beidellite type and an ordered interlayer chlorite/smectite mineral, of corrensite type. Smectite from the epyclastic rocks have higher Fe and Mg contents and chemical variability, as a consequence of nature of their parent rocks. The presence of corrensite in the epyclastic rocks suggests that in the Morron de Mateo area a propilitic alteration process occurred after bentonite formation, which transformed Fe-Mg-rich smectite into corrensite. This transformation was probably favoured by the sub volcanic intrusion, which also produced a temperature increase in the geological media and a supply of Fe-Mg-rich solutions, which also were the responsible for the metasomatic transformations observed in the calcarenite beds. (Author) 57 refs

  8. Geochemical studies of rocks, water, and gases at Mt. Hood, Oregon

    Energy Technology Data Exchange (ETDEWEB)

    Wollenberg, H.A.; Bowen, R.E.; Bowman, H.R.; Strisower, B.


    Mr. Hood, a composite andesitic volcano, located near Portland, Oregon, is one of several large eruptive centers which dominate the Cascade Mountains of the western United States. As part of a program of geologic, geophysical and geochemical studies to examine Mt. Hood's geothermal resource potential, samples of warm-and cold-spring water, water from a geothermal test well in Old Maid Flat, fumarolic gases, and rocks were collected and analyzed for major chemical constituents and trace elements. The only warm-spring area on Mt. Hood is Swim Springs, located on the south flank. Orifices at Swim were sampled repeatedly with little overall change noted in water chemistry between summer and winter. Oxygen and hydrogen isotope data and mixing calculations based on analyses of Swim Springs and numerous cold springs, indicate that a large component of the warm water at Swim is from near-surface runoff. Chemical geothermometry suggests that temperatures at depth in the Swim Springs system are within the range 104 to 170/sup 0/C; the temperature of unmixed hot water may exceed 200/sup 0/C. Higher-than-background chloride contents and specific conductances of cold springs on the south flank of the mountain suggest that there is a small component of thermal water in these sources. A geothermal model of Mt. Hood is proposed wherein snow- and glacier-melt water near the summit comes in close promimity to the hot central neck of the mountain, manifested by the summit-crater fumaroles.Iridium was detected in warm and cold spring waters and in a sample of altered andesite.

  9. Geology, mineralization and geochemistry of the Aqkand Cu occurrence (north of Zanjan, Tarom-Hashtjin zone

    Directory of Open Access Journals (Sweden)

    Maryam Feyzi


    Full Text Available Introduction The Aqkand Cu occurrence, 48 km north of Zanjan, is located in the Tarom subzone of the Western Alborz-Azerbaijan structural zone. Apart from small scale geological maps of the area, i.e., 1:250,000 geological maps of Bandar-e-Anzali (Davies, 1977 and 1:100,000 geological maps of Hashtjin (Faridi and Anvari, 2000 and a number of unpublished perlite exploration reports, prior to this research no work has been done on Cu mineralization at Aqkand. The present paper provides an overview of the geological framework, the mineralization characteristics, and the results of geochemistry study of the Aqkand Cu occurrence with an application to the ore genesis. Identification of these characteristics can be used as a model for exploration of this type of copper mineralization in the Tarom area and elsewhere. Materials and methods Detailed field work has been carried out at different scales in the Aqkand area. About 35 polished thin and thin sections from host rocks and mineralized and altered zones were studied by conventional petrographic and mineralogic methods at the University of Zanjan. In addition, a total of 6 samples from ore zones at the Aqkand occurrence were analyzed by ICP-MS for trace elements and REE compositions at Kimia Pazhuh Alborz Co., Isfahan, Iran. Results and Discussion The oldest units exposed in the Aqkand area are Eocene volcanic rocks which are overlain unconformably by Oligocene acidic rocks. The Eocene units consist of lithic and vitric tuff with intercalations of andesitic basalt lavas (equal to Karaj Formation, Hirayama et al., 1966. The andesitic basalt lavas show porphyritic texture consisting of plagioclase and altered ferromagnesian minerals set in a fine-grained groundmass. The Oligocene acidic rocks consist of rhyolite-rhyodacite, perlite, pitchstone and ignimbrite. These rocks are exposed as domes and lava flows. The rhyolite-rhyodacite lavas usually show onion-skin weathering and locally display flow bands

  10. Determination of Mineralization Zones Using Interpretation of IP and RS Data in The GarmabCopper Deposit (South Khorasan province

    Directory of Open Access Journals (Sweden)

    Mansour Adelpour


    Full Text Available Introduction The Garmab copper deposit is located northeast of Qaen (South Khorasan province in the1:100,000 scale map of Abiz in the eastern tectonic zone of Iran. It is hosted by Late Paleocene-Eocene lava flows consisting mainly of andesite, trachy¬andesite, andesite-basalt and basalt lavas, as well as pyroclastic rocks, including tuffs and ignimbrites. The Lut Block has undergone intense magmatic activitywith a variety of geochemical characteristics due to changing tectonic conditions (e.g., compression during subduction followed by tensional conditions; Karimpour et al., 2012; Zarrinkoub et al., 2012. The Lut Block has a great potential for the discovery of new mineral deposits, like the Mahrabad and Khonik porphyry copper-gold deposits (Malekzadeh shafarodi, 2009, the Dehsalam porphyry copper deposit (Arjmandzadeh, 2011, high sulfidation epithermal gold deposits such as Chah Shalghami (Karimpour, 2005 and IOCG deposits such as Kuh-E-Zar and Qaleh Zari (Mazlomi et al., 2008. Materials and methods After field studies of the Garmab area, 32 thin sections and 21 polished sections were prepared for petrological and mineralogical studies.In addition, 10 least-altered and fractured samples of volcanic rocks were selected for geochemical studies. Major oxides were determined using XRF analyses at the Zarazma laboratory. Induced polarization and resistivity geophysical data were collected and correlated with geological and alteration maps. The geophysical datawere collectedfrom 420 individual points, using a dipole-dipole arrangement along five profiles separated 60m apart.This covered the study area entirely. After a change in the mineralization trend was observed,additional profileswere designed, twoon bearings of 25º and three on 75º. Results The Garmab volcanic rocks exhibit typical geochemical characteristics of subduction zone magmas including strong enrichment in LILE and depletion in HFSE. Based on the discrimination plot of Irvine and

  11. Geology and ground-water resources of the islands of Lanai and Kahoolawe, Hawaii (United States)

    Stearns, Harold T.; Macdonald, Gordon Andrew; Swartz, Joel Howard


    basal water, although potable, is fairly high in salt. Several sites are recommended for developing and conserving ground water.Kahoolawe Island is 11 miles long, 6 miles wide, 1,491 feet high, covers 45 square miles, and lies 94 miles southeast of Honolulu and 6 3/4 miles southwest of Maui. It is a shield-shaped extinct volcano composed chiefly of thin flows of primitive basalt poured in rapid succession from three rift zones and a vent at their intersection. At one stage the volcano was indented with a caldera about 3 miles across which was later completely filled. A graben led southwestward from it. The rocks are divided into Late Tertiary (?) or early Pleistocene(?) pre-caldera basalts, caldera-filling basalts and basaltic andesites, post-caldera basalts and andesites, and Recent post erosional basalts. A few thin vitric tuff beds and cinder cones were found. Marine erosion has cut cliffs as high as 800 feet along the east and south shores and exposed a cross section of the caldera. Only shallow ephemeral gulches exist. The entire summit has been eroded to a hard-pan surface by the wind as a result of the vegetation being destroyed by livestock. The island is semi-arid and well water is needed for stook: "The stook is now supplied entirely from storage of rain and flood waters. During droughts water is hauled by boat from the island of Maui. All the wells dug so far yield water that is too brackish for stock except at the fairly inaccessible south side of Kanapou Bay. The resistivity survey indicates a water table 1.5 feet or less above sea level for 2.25 miles inland. A few sites for wells are recommended in the dike complex where small supplies of water suitable for stock might be found. Petrographic studies by Gordon A. Macdonald indicate that the pre-caldera and caldera-filling lavas are largely normal olivine basalt of the type which forms the bulk of all Hawaiian volcanoes thus far investigated. It represents the undifferentiated magma of the Hawaiian

  12. Mineralogical indicators of intrachamber magma degassing and oxidation in Shiveluch (Kamchatka) (United States)

    Salova, T.; Simakin, A.


    Processes of the intrachamber magma degassing precede degassing in the conduit on the final stages of eruption and may be of no less importance. Appearance of the free fluid phase at the depth can be responsible for intrachamber elements transport, pressure buildup and local magma oxidation. We interpret phenocrysts zonality in Shiveluch andesites in terms of such degassing based on our experimental data. High magnesium andesite of Shiveluch volcano (Kamchatka) was studied at PH2O=2 kbar. Bulk hydrous glass was prepared in the series of operations including hydrothermal reducing of the initially melted oxidized rock powder under hydrothermal conditions and remelting. The Fe2+/Fe3+ ratio in the final hydrous glass was estimated with Mossbauer spectroscopy. It corresponds to fO2 = NNO - NNO+2 in the andesite melt at the experimental PT parameters. Short experiments yield crystals grown from the melt with Fe2+/Fe3+ ratio close to the initial value. Liquidus temperature of amphibole was found to be 970oC. The analysis of composition of amphiboles grown at T=950oC demonstrates that the sum Fe3+ +Ti (in M1+M2) is inversely correlated with alumina content in the octahedral coordination: Al_VI= 0.601-0.330(Fe3+ + Ti). The Al_VI content rises with melt reduction (Simakin et al., 2009). Liquidus temperatures of plagioclase have been found at PH2O=1 kbar (1000оС) and 2 kbar (960оС). They are in excellent correspondence with values predicted with model by Putirka (2005): 1006оС and 956оС correspondingly. While using this model we analyse composition of plagioclase at the variation of the water content in the wide range (1-6 wt.%) while changing melt temperature to keep plagioclase on the liquidus. It appears that dependence of the anorthite content in plagioclase on the water content has minimum. It means that degassing coupled with magma heating may result in both direct and inverse zonality in plagioclase. The examples of zonality pattern of magmatic minerals that

  13. Late Cenozoic Samtskhe-Javakheti Volcanic Highland, Georgia:The Result of Mantle Plumes Activity (United States)

    Okrostsvaridze, Avtandil


    Late Cenozoic Samtskhe-Javakheti continental volcanic highland (1500-2500 m a.s.l) is located in the SW part of the Lesser Caucasus. In Georgia the highland occupies more than 4500 km2, however its large part spreads towards the South over the territories of Turkey and Armenia. One can point out three stages of magmatic activity in this volcanic highland: 1. Early Pliocene activity (5.2-2.8 Ma; zircons U-Pb age) - when a large part of the highland was built up. It is formed from volcanic lava-breccias of andesite-dacitic composition, pyroclastic rocks and andesite-basalt lava flow. The evidences of this structure are: a large volume of volcanic material (>1500 km3); big thickness (700-1100 m in average), large-scale of lava flows (length 35 km, width 2.5-3.5 km, thickness 30-80 m), big thickness of volcanic ash horizons (300 cm at some places) and big size of volcanic breccias (diameter >1 m). Based on this data we assume that a source of this structure was a supervolcano (Okrostsvaridze et al., 2016); 2. Early Pleistocene activity (2.4 -1.6 Ma; zircons U-Pb age) - when continental flood basalts of 100-300 m thickness were formed. The flow is fully crystalline, coarse-grained, which mainly consist of olivine and basic labradorite. There 143Nd/144Nd parameter varies in the range of +0.41703 - +0.52304, and 87Sr/88Sr - from 0.7034 to 0.7039; 3. Late Pleistocene activity (0.35-0.021 Ma; zircons U-Pb age) - when intraplate Abul-Samsari linear volcanic ridge of andesite composition was formed stretching to the S-N direction for 40 km with the 8-12 km width and contains more than 20 volcanic edifices. To the South of the Abul-Samsari ridge the oldest (0.35-0.30 Ma; zircons U-Pb age) volcano Didi Abuli (3305 m a.s.l.) is located. To the North ages of volcano edifices gradually increase. Farther North the youngest volcano Tavkvetili (0.021-0. 030 Ma) is located (2583 m a.s.l.). One can see from this description that the Abul-Samsari ridge has all signs characterizing

  14. Transition of magma genesis estimated by change of chemical composition of Izu-bonin arc volcanism associated with spreading of Shikoku Basin (United States)

    Haraguchi, S.; Ishii, T.


    Arc volcanism in the Izu-Ogasawara arc is separated into first and latter term at the separate of Shikoku Basin. Middle to late Eocene early arc volcanism formed a vast terrane of boninites and island arc tholeiites that is unlike active arc systems. A following modern-style arc volcanism was active during the Oligocene, along which intense tholeiitic and calc-alkaline volcanism continued until 29Ma, before spreading of the back- arc basin. The recent arc volcanism in the Izu-Ogasawara arc have started in the middle Miocene, and it is assumed that arc volcanism were decline during spreading of back-arc basin. In the northern Kyushu-Palau Ridge, submarine bottom materials were dredged during the KT95-9 and KT97-8 cruise by the R/V Tansei-maru, Ocean Research Institute, university of Tokyo, and basaltic to andesitic volcanic rocks were recovered during both cruise except for Komahashi-Daini Seamount where recovered acidic plutonic rocks. Komahashi-Daini Seamount tonalite show 37.5Ma of K-Ar dating, and this age indicates early stage of normal arc volcanism. These volcanic rocks are mainly cpx basalt to andesite. Two pyroxene basalt and andesite are only found from Miyazaki Seamount, northern end of the Kyushu-Palau Ridge. Volcanic rocks show different characteristics from first term volcanism in the Izu-Ogasawara forearc rise and recent arc volcanism. The most characteristic is high content of incompatible elements, that is, these volcanics show two to three times content of incompatible elements to Komahashi-Daini Seamount tonalite and former normal arc volcanism in the Izu outer arc (ODP Leg126), and higher content than recent Izu arc volcanism. This characteristic is similar to some volcanics at the ODP Leg59 Site448 in the central Kyushu- Palau Ridge. Site448 volcanic rocks show 32-33Ma of Ar-Ar ages, which considered beginning of activity of Parece Vela Basin. It is considered that the dredged volcanic rocks are uppermost part of volcanism before spreading of

  15. Geochemistry of the Palaeoproterozoic volcanic and associated potassic granitic rocks of the Ngualla area of the Ubendian Belt, SW Tanzania (United States)

    Tulibonywa, Tulibako; Manya, Shukrani; Torssander, Peter; Maboko, Makenya A. H.


    The Ngualla area of the Lupa terrane in the Ubendian Belt of SW Tanzania is underlain by well-preserved greenschist facies calc-alkaline volcanic rocks which have been intruded by low-Sr, peraluminous K-rich granites. The Ngualla volcanic rocks are subdivided into four groups: the basaltic andesites-trachyandesites, Group I porphyritic dacites-trachytes, Group II porphyritic dacites-trachytes, and rhyolites. The basaltic andesites-trachyandesites were emplaced at ∼1943 Ma and their most primitive members are characterized by MgO contents of up to 7.43 wt % at a SiO2 content of 54.0 wt %, Ni contents of up to 170 ppm and Mg# of up to 62. They show fractionated REE patterns (La/YbCN = 11.5-36.5), sub-chondritic Zr/Hf (37.8-43.9) and Nb/Ta (7.14-20.0) ratios, εNd (1943 Ma) values of -3.33 to -6.24 and TDM ages of 2521-2883 Ma. These geochemical features are consistent with derivation of the basaltic andesites-trachyandesites by at least 0.1% partial melting of garnet peridotite mantle, followed by 50-80% fractional crystallization involving the removal of 61% clinopyroxene, 20% hornblende, 4% plagioclase and 15% orthopyroxene. The magmas were contaminated by Neoarchaean crustal materials incorporated in the Ubendian Belt during their ascent to the surface. The evolution of these magmas led to the formation of Group I porphyritic dacites-trachytes and rhyolites in a Palaeoproterozoic continental arc setting. The Group II porphyritic dacites-trachytes (1871 ± 5 Ma) were coevally emplaced with the low-Sr, peraluminous K-granites (1878 ± 15 Ma) forming a felsic plutonic-volcanic suite. Despite some differences, these rocks share geochemical features including negative Eu anomalies (mean Eu/Eu* = 0.19 for the dacites and 0.5 for the granites) and εNd (1871 Ma) values of -5.72 for the dacites and εNd (1878 Ma) values of -6.00 to -11.2 for the granites. These geochemical features are consistent with the generation of the ∼1.87 Ga Ngualla felsic plutonic

  16. Temporal and spatial constraints on the evolution of a Rio Grande rift sub-basin, Guadalupe Mountain area, northern New Mexico (United States)

    Thompson, R. A.; Turner, K. J.; Cosca, M. A.; Drenth, B.; Hudson, M. R.; Lee, J.


    .27-4.8 Ma), (2) lower Servilleta basalt lavas (olivine tholeiite ~5.26-4.92 Ma), (3) Hatchery volcano lavas (basaltic andesite to andesite ~4.93 Ma), (4) Red River lavas (high silica andesite ~4.93 Ma), (5) UCEM lavas (dacite ~4.85 Ma), and (6) upper Servilleta basalt lavas (olivine tholeiite ~3.84-3.45 Ma). Mapped eruptive centers are interpreted to reflect discrete pulses of volcanic activity characterized by limited compositional range and short eruption cycles. Four major, northwest-trending, dip-slip faults cut the volcanic fill. From west to east these are: (1) down-to-east Red River fault zone (post 3.84 Ma displacement), (2) down-to-east Fish Hatchery fault zone including fault splays of opposite displacement (pre- upper Servilleta displacement Guadalupe Mtn. fault zone, both down-to-west and down-to-east components (post ~5 Ma displacement), and (4) Tailings Pond fault zone, down-to-east (post ~5 Ma displacement). The Red River and Tailings Pond fault zones appear to have the largest cumulative displacements and may reflect eastward migration of the western sub-basin margin. This may reflect coupled partitioning of extensional strain reflected as local expressions of sub-basin development and contemporaneous volcanism.

  17. Stratigraphy, geochemistry and tectonic significance of the Oligocene magmatic rocks of western Oaxaca, southern Mexico (United States)

    Martiny, Barbara; Martínez-Serrano, Raymundo G.; Morán-Zenteno, Dante J.; Macías-Romo, Consuelo; Ayuso, Robert A.


    In western Oaxaca, Tertiary magmatic activity is represented by extensive plutons along the continental margin and volcanic sequences in the inland region. K-Ar age determinations reported previously and in the present work indicate that these rocks correspond to a relatively broad arc in this region that was active mainly during the Oligocene (˜35 to ˜25 Ma). In the northern sector of western Oaxaca (Huajuapan-Monte Verde-Yanhuitlán), the volcanic suite comprises principally basaltic andesite to andesitic lavas, overlying minor silicic to intermediate volcaniclastic rocks (epiclastic deposits, ash fall tuffs, ignimbrites) that were deposited in a lacustrine-fluvial environment. The southern sector of the volcanic zone includes the Tlaxiaco-Laguna de Guadalupe region and consists of intermediate to silicic pyroclastic and epiclastic deposits, with silicic ash fall tuffs and ignimbrites. In both sectors, numerous andesitic to dacitic hypabyssal intrusions (stocks and dikes) are emplaced at different levels of the sequence. The granitoids of the coastal plutonic belt are generally more differentiated than the volcanic rocks that predominate in the northern sector and vary in composition from granite to granodiorite. The studied rocks show large-ion lithophile element (LILE) enrichment (K, Rb, Ba, Th) relative to high-field-strength (HFS) elements (Nb, Ti, Zr) that is characteristic of subduction-related magmatic rocks. On chondrite-normalized rare earth element diagrams, these samples display light rare earth element enrichment (LREE) and a flat pattern for the heavy rare earth elements (HREE). In spite of the contrasting degree of differentiation between the coastal plutons and inland volcanic rocks, there is a relatively small variation in the isotopic composition of these two suites. Initial 87Sr/ 86Sr ratios obtained and reported previously for Tertiary plutonic rocks of western Oaxaca range from 0.7042 to 0.7054 and ɛNd values, from -3.0 to +2.4, and for the

  18. Metallogeny of the Gold Quadrilateral: style and characteristics of epithermal - subvolcanic mineralized structures, South Apuseni Mts., Romania

    Directory of Open Access Journals (Sweden)

    S̡erban-Nicolae Vlad


    Full Text Available The Romanian territory contains numerous ore deposits mined since pre-Roman times. An assessment of historical gold production of the Gold Quadri-lateral (GQ yielded a total estimate of 55.7 Moz of gold throughout an area of 2400 km2. Interpreted in terms of mineralization density this is 23,208 oz of gold/ km2. The geological setting of the GQ is represented mainly by Tertiary (14.7 My to 7.4 My calc-alkaline volcano-plutonic complexes of intermediate character in sedimentary basins of molasse type. These basins are tectonically controlled by NW-SE lineation across early Alpine magmatic products, i.e. subduction related Jurassic-Lower Cretaceous igneous association (island arc ophiolites and granitoids and Upper Cretaceous igneous association (banatites. The Tertiary magmatism is associated with extensional tectonics caused by NE escape of the Pannonian region during Upper Oligocene-Lower Miocene times. As a result of tectono-magmatic and mineralization-alteration characteristics, two metallogenetical types were separated in the GQ, i.e. calc-alkaline andesitic (CAM and sub-alkaline rhyodacitic (SRM. Both develop almost entirely low-sulfidation type of Au epithermal mineralization. However, two subtypes, -rich in sulfide (2-7% and -poor in sulfide (7-20% were delineated and correlated with CAM type and SRM type respectively. Furthermore, CAM is connected at deeper levels with Cu-Au+/-Mo porphyry systems in contrast with SRM, which is a non-porphyry environment. The Brad-Săcărâmb district contains mainly CAM type andesitic structures. It is a porphyry environment with epithermal low-sulfidation-rich sulfide vein halo (Barza, Troiţa-Bolcana deposits. However, a few SRM type patterns, such as Măgura Ţebii, Băiţa-Crăciuneşti and Săcărâmb, deposits exhibit Au-Ag-Te low-sulfidation-poor sulfide epithermal vein halo. The Zlatna-Stănija district exhibits similar characteristics, with Au-Ag+/-Pb, Zn veins in Cu-Au subvolcanic

  19. Slab Contributions to Cascades Magmas: Constraints from Central Oregon and Northern California (United States)

    Ruscitto, D. M.; Wallace, P. J.


    The Cascades arc is the global end member, warm-slab subduction zone (slab thermal parameter ~200 km) resulting from the slow subduction of young oceanic crust beneath North America. Significant slab dehydration is predicted to occur beneath the forearc (e., H2O, S, Cl) beneath the forearc should result in reduced slab contributions to the mantle wedge, consistent with muted subduction-related signatures in calc-alkaline magmas and low magmatic volatile flux estimates from Oregon and Washington compared to other arcs (e.g., Marianas, Kamchatka, Central America). Despite reduced slab-derived inputs, olivine-hosted melt inclusions in the Central Oregon Cascades display elevated volatile contents in melts erupted along the volcanic front compared to those erupted towards the back-arc. In contrast to Oregon and Southern Washington, primitive magmas from the southern part of the arc (e.g., Mt. Shasta) contain some of the highest H2O contents reported. We used olivine-hosted melt inclusion data from Central Oregon and Northern California to estimate the input of volatiles and trace elements from the slab to the mantle wedge beneath the Cascades. Inclusions from near Mt. Shasta in Northern California represent two types of hydrous primitive melts that have equilibrated with a refractory mantle: high-Mg andesite (HMA) and primitive basaltic andesite (PBA) with 3.3 and 5.6 wt.% H2Omax, respectively. Three distinct primitive melt compositions were calculated using inclusions from Central Oregon: calc-alkaline basalt, Sr-rich basalt, and depleted basaltic andesite (1.6, 2.3, and 3.0 wt.% H2Omax, respectively). We calculated extents of mantle melting for each primitive magma composition using Ti, Y, Gd, Dy, Er, and Yb contents (i.e., assuming negligible contributions from the slab). Based on these calculations, we infer Central Oregon and Shasta magmas to represent 8-15% and 14-20% partial melts (respectively) of variably depleted sources. Major elements in preliminary slab

  20. Quaternary volcanism near the Valley of Mexico: implications for subduction zone magmatism and the effects of crustal thickness variations on primitive magma compositions (United States)

    Wallace, Paul J.; Carmichael, Ian S. E.

    The Valley of Mexico and surrounding regions of Mexico and Morelos states in central Mexico contain more than 250 Quaternary eruptive vents in addition to the large, composite volcanoes of Popocatépetl, Iztaccíhuatl, and Nevado de Toluca. The eruptive vents include cinder and lava cones, shield volcanoes, and isolated andesitic and dacitic lava flows, and are most numerous in the Sierra Chichináutzin that forms the southern terminus of the Valley of Mexico. The Chichináutzin volcanic field (CVF) is part of the E-W-trending Mexican Volcanic Belt (MVB), a subduction-related volcanic arc that extends across Mexico. The crustal thickness beneath the CVF ( 50km) is the greatest of any region in the MVB and one of the greatest found in any arc worldwide. Lavas and scoriae erupted from vents in the CVF include alkaline basalts and calc-alkaline basaltic andesites, andesites, and dacites. Both alkaline and calc-alkaline groups contain primitive varieties that have whole rock Mg#, MgO, and Ni contents, and liquidus olivine compositions (<=Fo90) that are close to those expected of partial melts from mantle peridotite. Primitive varieties also show a wide range of incompatible trace element abundances (e.g. Ba 210-1080ppm Ce 25-100ppm Zr 130-280ppm). Data for primitive calc-alkaline rocks from both the CVF and other regions of the MVB to the west are consistent with magma generation in an underlying mantle wedge that is depleted in Ti, Zr, and Nb and enriched in large ion lithophile (K, Ba, Rb) and light rare earth (La, Ce) elements. Extents of partial melting estimated from Ti and Zr data are lower for primitive calc-alkaline magmas in the CVF than for those from the regions of the MVB to the west where the crust is thinner. The distinctive major element compositions (low CaO and Al2O3, high SiO2) of the primitive calc-alkaline magmas in the CVF indicate a more refractory mantle source beneath this region of thick crust. In contrast, primitive alkaline magmas from the

  1. 3D geophysical insights into the Ciomadu volcano (United States)

    Besutiu, Lucian; Zlagnean, Luminita


    RATIONALE Located at the south easternmost end of the Neogene to Quaternary volcanic chain of East Carpathians, the Ciomadu volcano (last erupted approx 30 ka ago) seems to represent the latest volcanic manifestation within the Carpatho-Pannonian region. Based on the interpretation of some large-scale electromagnetic and seismological surveys, the hypothesis of the in depth (8 -15 km) existence of a magma reservoir raises the volcanic hazard in the region. The close neighbourhood of the Vrancea active geodynamic zone, where intermediate-depth seismicity occurs within full intra-continental environment makes the study of the Ciomadu volcano of higher interest. METHOD During the time numerous geological investigations have been conducted in the area, but except for the previously mentioned large-scale electromagnetic and seismological approaches geophysical tools have been less employed. Relatively recent, within the frame of the INSTEC project, funded through a CNCS-UEFISCDI (Romanian Science Foundation) grant, the area has been subject to an integrated gravity and geomagnetic survey accompanied by outcrops sampling and lab determinations on rock physics. Field data have been highly processed and models of their sources have been constructed through 3D inversion techniques. RESULTS Overall, the potential fields have revealed a large gravity low covering the whole volcano area associating a residual geomagnetic anomaly with local effects mainly bordering the gravity anomaly. 3D inversion of the gravity data provided an intriguing image on the mass distribution within the volcanic structure, with underground densities much bellow the figures provided by the lab determinations on rock samples collected at the surface. The geometry of the revealed gravity source clearly suggests an andesitic/dacitic intrusion acceding to the surface along a deep fault that seems to belong to the alpine overthrust system of East Carpathians. Attempts to interpret the low value densities

  2. Straddling the tholeiitic/calc-alkaline transition: the effects of modest amounts of water on magmatic differentiation at Newberry Volcano, Oregon (United States)

    Mandler, Ben E.; Donnelly-Nolan, Julie M.; Grove, Timothy L.


    Melting experiments have been performed at 1 bar (anhydrous) and 1- and 2-kbar H2O-saturated conditions to study the effect of water on the differentiation of a basaltic andesite. The starting material was a mafic pumice from the compositionally zoned tuff deposited during the ~75 ka caldera-forming eruption of Newberry Volcano, a rear-arc volcanic center in the central Oregon Cascades. Pumices in the tuff of Newberry caldera (TNC) span a continuous silica range from 53 to 74 wt% and feature an unusually high-Na2O content of 6.5 wt% at 67 wt% SiO2. This wide range of magmatic compositions erupted in a single event makes the TNC an excellent natural laboratory in which to study the conditions of magmatic differentiation. Our experimental results and mineral–melt hygrometers/thermometers yield similar estimates of pre-eruptive H2O contents and temperatures of the TNC liquids. The most primitive (mafic) basaltic andesites record a pre-eruptive H2O content of 1.5 wt% and a liquidus temperature of 1,060–1,070 °C at upper crustal pressure. This modest H2O content produces a distinctive fractionation trend that is much more enriched in Na, Fe, and Ti than the calc-alkaline trend typical of wetter arc magmas, but slightly less enriched in Fe and Ti than the tholeiitic trend of dry magmas. Modest H2O contents might be expected at Newberry Volcano given its location in the Cascade rear arc, and the same fractionation trend is also observed in the rim andesites of the rear-arc Medicine Lake volcano in the southern Cascades. However, the Na–Fe–Ti enrichment characteristic of modest H2O (1–2 wt%) is also observed to the west of Newberry in magmas erupted from the arc axis, such as the Shevlin Park Tuff and several lava flows from the Three Sisters. This shows that modest-H2O magmas are being generated directly beneath the arc axis as well as in the rear arc. Because liquid lines of descent are particularly sensitive to water content in the range of 0–3 wt% H

  3. Phanerozoic Rifting Phases And Mineral Deposits (United States)

    Hassaan, Mahmoud


    In North Africa occur Mediterranean and Red Sea metallogenic provinces. In each province distribute 47 iron- manganese- barite and lead-zinc deposits with tectonic-structural control. The author presents in this paper aspects of position of these deposits in the two provinces with Phanerozoic rifting . The Mediterranean Province belongs to two epochs, Hercynian and Alpine. The Hercynian Epoch manganese deposits in only Moroccoa- Algeria belong to Paleozoic tectonic zones and Proterozoic volcanics. The Alpine Epoch iron-manganese deposits are of post-orogenic exhalative-sedimentary origin. Manganese deposits in southern Morocco occur in Kabil-Rief quartz-chalcedony veins controlled by faults in andesitic sheets and in bedded pelitic tuffs, strata-form lenses and ore veins, in Precambrian schist and in Triassic and Cretaceous dolomites. Disseminated manganese with quartz and barite and effusive hydrothermal veins are hosted in Paleocene volcanics. Manganese deposits in Algeria are limited and unrecorded in Tunisia. Strata-form iron deposits in Atlas Heights are widespread in sub-rift zone among Jurassic sediments inter-bedding volcanic rocks. In Algeria, Group Beni-Saf iron deposits are localized along the Mediterranean coast in terrigenous and carbonate rocks of Jurassic, Cretaceous and Eocene age within faults and bedding planes. In Morocco strata-form hydrothermal lead-zinc deposits occur in contact zone of Tertiary andesite inter-bedding Cambrian shale, Lias dolomites and Eocene andesite. In both Algeria and Tunisia metasomatic Pb-Zn veins occur in Campanian - Maastrichtian carbonates, Triassic breccia, Jurassic limestone, Paleocene sandstones and limestone and Neogene conglomerates and sandstones. The Red Sea metallogenic province belongs to the Late Tertiary-Miocene times. In Wadi Araba hydrothermal iron-manganese deposits occur in Cretaceous sediments within 320°and 310 NW faults related to Tertiary basalt. Um-Bogma iron-manganese deposits are closely

  4. Structural observations from the Canavese Fault west of Valle d'Ossola (Piemonte) and some time constraints (United States)

    Pleuger, Jan; Mancktelow, Neil


    The Canavese Fault (CF) is the SW part of the most important fault system in the Alps, the Periadriatic Fault. The CF has a complex kinematic history involving an older stage of NW-side-up faulting and a younger stage of SE-side-up plus dextral faulting in the area of Valle d'Ossola (Schmid et al. 1987). There, shearing occurred under greenschist-facies conditions and the fault is a c. 1 km thick mylonite zone. Toward SW, faulting took place under progressively lower temperatures and the volume of rocks affected by S-side-up plus dextral shearing becomes larger at the expense of the N-side-up mylonites. S of Valle Sesia, brittle fault rocks dominate over mylonites. Still further SW, close to the Serra d'Ivrea, the CF splits into two branches, the Internal Canavese Fault (ICF) and the External Canavese Fault (ECF). S-side-up plus dextral faulting is localised along the ICF while the observed displacement senses at the ECF are mostly, though not always, N-side-up and sinistral. Age constraints for faulting along the CF are mostly derived from absolute ages of magmatic rocks exposed alongside or within the fault. In the section around Biella, NW-side-up faulting cannot have lasted longer than until 31±2 Ma (Scheuring et al. 1974) because this is the age of andesites overlying the basement of the Penninic Sesia Zone. However, some additional uplift of the Sesia Zone with respect to the South Alpine Ivrea Zone was accommodated by down-to-the-SE tilting of the Sesia zone around a roughly NNE-SSW-trending subhorizontal axis which is evidenced by palaeomagnetic data (Lanza 1977). As a result of that, the Early Oligocene Biella Pluton (c. 31 Ma, Romer et al. 1996) today occupies a similar altitude level as the andesites of the same age. Post-31-Ma uplift of the Ivrea Zone with respect to the andesites is evidenced by the Early Oligocene (29-33 Ma, Carraro & Ferrara 1968) Miagliano Pluton which is hosted by the Ivrea Zone rocks and exposed at the present topographic surface

  5. Geologic Map of Lassen Volcanic National Park and Vicinity, California (United States)

    Clynne, Michael A.; Muffler, L.J. Patrick


    modified for inclusion here. Figure 2 (sheet 3) shows the mapping credit for previous work; figure 3 (sheet 3) shows locations discussed throughout the text. A CD-ROM entitled Database for the Geologic Map of Lassen Volcanic National Park and Vicinity, California accompanies the printed map (Muffler and others, 2010). The CD-ROM contains ESRI compatible geographic information system data files used to create the 1:50,000-scale geologic map, both geologic and topographic data and their associated metadata files, and printable versions of the geologic map and pamphlet as PDF formatted files. The 1:50,000-scale geologic map was compiled from 1:24,000-scale geologic maps of individual quadrangles that are also included in the CD-ROM. It also contains ancillary data that support the map including locations of rock samples selected for chemical analysis (Clynne and others, 2008) and radiometric dating, photographs of geologic features, and links to related data or web sites. Data contained in the CD-ROM are also available on this Web site. The southernmost Cascade Range consists of a regional platform of basalt and basaltic andesite, with subordinate andesite and sparse dacite. Nested within these regional rocks are 'volcanic centers', defined as large, long-lived, composite, calc-alkaline edifices erupting the full range of compositions from basalt to rhyolite, but dominated by andesite and dacite. Volcanic centers are produced by the focusing of basaltic flux from the mantle and resultant enhanced interaction of mafic magma with the crust. Collectively, volcanic centers mark the axis of the southernmost Cascade Range. The map area includes the entire Lassen Volcanic Center, parts of three older volcanic centers (Maidu, Dittmar, and Latour), and the products of regional volcanism (fig. 4, sheet 3). Terminology used for subdivision of the Lassen Volcanic Center has been modified from Clynne (1984, 1990).

  6. Magma reservoir conditions beneath Tsurumi volcano, SW Japan: Evidence from amphibole thermobarometry and seismicity (United States)

    Nagasaki, Shiho; Ishibashi, Hidemi; Suwa, Yukiko; Yasuda, Atsushi; Hokanishi, Natsumi; Ohkura, Takahiro; Takemura, Keiji


    Calcic amphibole phenocrysts in the Tsurumidake summit (TS) lava, which was produced during the most recent eruption at Tsurumi Volcano (SW Japan) at around 7.5-10.5 ka, have been analyzed to determine the pre-eruptive conditions, such as temperature (T), pressure (P), oxygen fugacity (fO2), SiO2 content (SiO2melt), and FeO*/MgO ratio (FeO*/MgOmelt), of coexisting silicate melts in the magma reservoir beneath the volcano. Although most of the amphibole phenocrysts have been completely decomposed to a fine-grained opaque symplectite, 6% of the grains remain intact. The degree of amphibole breakdown (DAB), defined as the ratio of the area of symplectite to the area of symplectite plus relict amphibole in each phenocryst, varies from 20% to 100%. Compositional zoning was not observed in the amphibole grains, however, two distinct groups of amphibole phenocrysts have been identified based on their chemical compositions: group-I amphiboles, which are relatively Si-poor, and [6]Al-rich, and have a relatively high Mg# [100Mg/(Mg + Fe2 +)]; and group-II amphiboles, which are Si-rich, and [6]Al-poor, and have a relatively low Mg#. Empirical equations for geothermobarometry, oxygen barometry and chemometry that exclusively rely on the amphibole composition were applied to estimate the T-P-fO2-SiO2melt-FeO*/MgOmelt conditions of the silicate melts with which the amphibole crystals equilibrated. The results show that group-I and group-II amphiboles equilibrated with andesitic melts (group-I melts) and dacitic-rhyolitic melts (group-II melts), respectively. The T-P-fO2 conditions of group-I melts were estimated as 374-483 MPa ( 13.9-17.9 km depth), 950 °C, and NNO + 1.3, respectively, and those of group-II melts were 93-242 MPa ( 3.4-9.0 km depth), 824-913 °C, and NNO + 0.6-1.7, respectively. The estimated T-P-fO2-SiO2melt-FeO*/MgOmelt conditions were almost constant for group-I melts, whereas the T, ΔNNO, and FeO*/MgOmelt values of group-II melts decreased with increasing

  7. New perspectives on the eruption of 1912 in the valley of ten thousand smokes, Katmai National Park, Alaska (United States)

    Hildreth, W.


    New data extend our understanding of the 1912 eruption, its backfilled vent complex at Novarupta, and magma-storage systems beneath adjacent stratovolcanoes. Initial Plinian rhyolite fallout is confined to a narrow downwind sector, and its maximum thickness may occur as far as 13 km from source. In contrast, the partly contemporaneous rhyolite-rich ash flows underwent relatively low-energy emplacement, their generation evidently being decoupled from the high column. Flow veneers 1-13 m thick on near-vent ridge crests exhibit a general rhyolite-to-andesite sequence like that of the much thicker valley-confined ignimbrite into which they merge downslope. Lithics in both the initial Plinian and the ignimbrite are predominantly fragments of the Jurassic Naknek Formation, which extends from the surface to a depth of ca. 1500 m. Absence of lithics from the underlying sedimentary section limits to 100 m thick near source and 10 m thick 3 km away, which dip back into an inner vent <0.5 km wide, nested inside the earlier vent funnel of the ignimbrite. The dacite fallout is poor in Naknek lithics but contains abundant fragments of vitrophyre, most of which was vent-filling, densely welded tuff reejected during later phases of the 3-day eruption. Adjacent to the inner vent, a 225-m-high asymmetrical accumulation of coarse near-vent ejecta is stratigraphically continuous with the regional dacite fallout. Distensional faulting of its crest may reflect spreading related to compaction and welding. Nearby andesite-dacite stratovolcanoes, i.e., Martin, Mageik, Trident, and Katmai, display at least 12 vents that define a linear volcanic front trending N65??E. The 1912 vent and adjacent dacite domes are disposed parallel to the front and ca. 4 km behind it. Mount Griggs, 10 km behind the front, is more potassic than other centers, taps isotopically more depleted source materials, and reflects a wholly independent magmatic plumbing system. Geochemical differences among the

  8. Eruptive history of the youngest Mexican Shield and Mexico's most voluminous Holocene eruption: Cerro El Metate (United States)

    Oryaëlle Chevrel, Magdalena; Guilbaud, Marie-Noelle; Siebe, Claus


    Small to medium-sized shield volcanoes are an important component of many volcanic fields on Earth. The Trans-Mexican Volcanic Belt, one of the most complex and active continental arcs worldwide, displays a large number of such medium-sized volcanoes. In particular the Michoacán-Guanajuato Volcanic Field (MGVF) situated in central Mexico, is the largest monogenetic volcanic field in the world and includes more than 1000 scoria cones and about four hundred medium-sized volcanoes, also known as Mexican shields. The Mexican shields nevertheless represent nearly 70% of the total volume erupted since 1 Ma and hence played a considerable role in the formation of the MGVF. However, the source, storage, and transport as well as the physical properties (density, viscosity, volatile content, etc.) of the magmas involved in these eruptions remain poorly constrained. Here, we focus on Cerro El Metate, the youngest monogenetic andesite shield volcano of the field. New C14 dates for the eruption yield a young age (~AD 1250), which briefly precedes the initial rise of the Tarascan Empire (AD 1350-1521) in this region. This volcano has a minimum volume of ~9.2 km3 DRE, and its viscous lava flows were emplaced during a single eruption over a period of ~35 years covering an area of 103 km2. By volume, this is certainly the largest eruption during the Holocene in Mexico, and it is the largest andesitic effusive eruption known worldwide for this period. Such a large volume of lava erupted in a relatively short time had a significant impact on the environment (modification of the hydrological network, forest fires, etc.), and hence, nearby human populations probably had to migrate. Its eruptive history was reconstructed through detailed mapping, and geochemical and rheological analyses of its thick hornblende-bearing andesitic flows. Early and late flows have distinct morphologies, chemical and mineralogical compositions, and isotopic signatures which show that these lavas were fed by

  9. Cathodoluminescence (CL) features of the Anatolian agates, hydrothermally deposited in different volcanic hosts from Turkey

    International Nuclear Information System (INIS)

    Hatipoglu, Murat; Ajo, David; Sezai Kirikoglu, M.


    Two different types of multi-colored gem-quality agate samples were investigated. They are both found in the same area in the Cubuk-Ankara region of Turkey although the first group is morphologically and geologically distinct from the second, being nodular-shaped agates occurring in cavity-spaces of a rhyolite host rock with an acidic character. They generally do not have any macroscopic inclusions, but the second group of rather block-shaped agates occurs in the fracture-spaces of an andesite host rock with a more neutral character, i.e. of lower free silica content, and they may display pseudomorphic bar-like macroscopic inclusions. Cathodoluminescence results at room temperature were obtained using measurements with alternating current (AC) (at energies of 14 and 24 keV) as well as direct current (DC) (at 14 keV energy), and they display remarkably different patterns between the two types of agates. It reveals a relation between the CL emissions and the presence of some transition metal elements. It is obvious that all trace elements do not play a direct role. Gaussian fitting of the cathodoluminescence AC experimental data at 14 keV energy obtained from the agates of rhyolite host indicates that there are three major spectral emissions, the dominant one being in the longer-visible wavelength region (red region) at about 690 nm. Additionally, two lesser emission lines occur in the middle-visible wavelength region (yellow region) at about 590 nm, and in the smaller-visible wavelength region (blue region) at about 430 nm. In spite of these, the same data from the agates of andesite host indicate that there is only one remarkable spectral emission which is in the in the middle-visible wavelength region (yellow region) at about 590 nm. On the other hand, Gaussian fitting of the cathodoluminescence AC experimental data at 24 keV energy obtained from the agates of rhyolite host indicates that these initial spectral emissions shift from the red and yellow regions to

  10. Petrogenesis of meta-volcanic rocks from the Maimón Formation (Dominican Republic): Geochemical record of the nascent Greater Antilles paleo-arc (United States)

    Torró, Lisard; Proenza, Joaquín A.; Marchesi, Claudio; Garcia-Casco, Antonio; Lewis, John F.


    Metamorphosed basalts, basaltic andesites, andesites and plagiorhyolites of the Early Cretaceous, probably pre-Albian, Maimón Formation, located in the Cordillera Central of the Dominican Republic, are some of the earliest products of the Greater Antilles arc magmatism. In this article, new whole-rock element and Nd-Pb radiogenic isotope data are used to give new insights into the petrogenesis of the Maimón meta-volcanic rocks and constrain the early evolution of the Greater Antilles paleo-arc system. Three different groups of mafic volcanic rocks are recognized on the basis of their immobile element contents. Group 1 comprises basalts with compositions similar to low-Ti island arc tholeiites (IAT), which are depleted in light rare earth elements (LREE) and resemble the forearc basalts (FAB) and transitional FAB-boninitic basalts of the Izu-Bonin-Mariana forearc. Group 2 rocks have boninite-like compositions relatively rich in Cr and poor in TiO2. Group 3 comprises low-Ti island arc tholeiitic basalts with near-flat chondrite-normalized REE patterns. Plagiorhyolites and rare andesites present near-flat to subtly LREE-depleted chondrite normalized patterns typical of tholeiitic affinity. Nd and Pb isotopic ratios of plagiorhyolites, which are similar to those of Groups 1 and 3 basalts, support that these felsic lavas formed by anatexis of the arc lower crust. Geochemical modelling points that the parental basic magmas of the Maimón meta-volcanic rocks formed by hydrous melting of a heterogeneous spinel-facies mantle source, similar to depleted MORB mantle (DMM) or depleted DMM (D-DMM), fluxed by fluids from subducted oceanic crust and Atlantic Cretaceous pelagic sediments. Variations of subduction-sensitive element concentrations and ratios from Group 1 to the younger rocks of Groups 2 and 3 generally match the geochemical progression from FAB-like to boninite and IAT lavas described in subduction-initiation ophiolites. Group 1 basalts likely formed at magmatic

  11. Hydrogeological Modelling of Some Geothermal Waters of Ivrindi, Havran and Gönen in the Province Capital of Balikesir, Western Anatolia, Turkey (United States)

    Özgür, Nevzat; Ugurlu, Zehra; Memis, Ümit; Aydemir, Eda


    In this study, hydrogeological, hydrogeochemical and isotope geochemical features of Havran, Gönen and Ivrindi within the province capital of Balıkesir, Turkey were investigated in detail. The Early Triassic Karakaya formation in the study area of Havran forms the oldest rocks consisting of spilitic basalts, diabases, gabbros, mudstones, cherts and radiolarites. There are limestone blocks in this formation with intercalations with sandstones and with feldspar contents, quartzite, conglomerates and siltstones. Oligocene to Miocene granodiorite intrusions were generated in association with intensively volcanic events in the area. Between Upper Oligocene and Early Miocene, andesitic and dacitic pyroclastic rocks cropped out due to intensively volcanism. Later, conglomerates, sandstones, claystones, marls and limestones as lacustrine sediments formed from Middle to Upper Miocene in the study area. In the study area of Gönen, the Lower Triassic Karakaya formation consists of basalts, diabases, gabbros, mudstones, cherts and radiolarites and forms the basement rocks overlain by Upper Jurassic to Lower Cretaceous sandy limestones. Upper and Middle Miocene volcanics which can be considered intensive Biga Peninsula volcanos outcrop in the area. These andesitic lava flows are of black, gray and red color with intensive fissures. Neogene lacustrine sediments consist of conglomerates, sandstones, marl, claystone and clayey limestones. Upper Miocene to Pliocene rhyolitic pyroclastics and dacitic lava flows are the volcanic rocks which are overlain by Pliocene conglomerates, sandstones and claystones. In the study area of Ivrindi, the Çaldağ limestones are the oldest formation in Permian age. Çavdartepe metamorphic rocks are of Lower Triassic in which can be observed marbles sporadically. The Kınık formation consisting of conglomerates, sandstones, siltstones and limestones are of Lower Triassic age and display a lateral Stratigraphic progress with volcanic rocks. Upper

  12. Stratigraphy, geochemistry and tectonic significance of the Oligocene magmatic rocks of western Oaxaca, southern Mexico (United States)

    Martiny, B.; Martinez-Serrano, R. G.; Moran-Zenteno, D. J.; MacIas-Romo, C.; Ayuso, R.A.


    In Western Oaxaca, Tertiary magmatic activity is represented by extensive plutons along the continental margin and volcanic sequences in the inland region. K-Ar age determinations reported previously and in the present work indicate that these rocks correspond to a relatively broad arc in this region that was active mainly during the Oligocene (~ 35 to ~ 25 Ma). In the northern sector of western Oaxaca (Huajuapan-Monte Verde-Yanhuitlan), the volcanic suite comprises principally basaltic andesite to andesitic lavas, overlying minor silicic to intermediate volcaniclastic rocks (epiclastic deposits, ash fall tuffs, ignimbrites) that were deposited in the lacustrine-fluvial environment. The southern sector of the volcanic zone includes the Tlaxiaco-Laguna de Guadalupe region and consists of intermediate to silicic pyroclastic and epiclastic deposits, with silicic ash fall tuffs and ignimbrites. In both sectors, numerous andesitic to dacitic hypabyssal intrusions (stocks and dikes) were emplaced at different levels of the sequence. The granitoids of the coastal plutonic belt are generally more differentiated than the volcanic rocks that predominate in the northern sector and vary in composition from granite to granodiorite. The studied rocks show large-ion lithophile element (LILE) enrichment (K, Rb, Ba, Th) relative to high-field-strength (HFS) elements (Nb, Ti, Zr) that is characteristic of subduction-related magmatic rocks. On chondrite-normalized rare earth element diagrams, these samples display light rare earth element enrichment (LREE) and a flat pattern for the heavy rare earth elements (HREE). In spite of the contrasting degree of differentiation between the coastal plutons and inland volcanic rocks, there is a relatively small variation in the isotopic composition of these two suites. Initial 87Sr/86Sr ratios obtained and reported previously for Tertiary plutonic rocks of western Oaxaca range from 0.7042 to 0.7054 and ??Nd values, from -3.0 to +2.4, and for

  13. Fine-scale ignimbrite morphology revealed in LiDAR at Crater Lake, OR (United States)

    Robinson, J. E.; Bacon, C. R.; Wright, H. M.


    Mount Mazama erupted ~7,700 years ago resulting in the collapse of Crater Lake caldera, ash fall across the Pacific Northwest, and emplacement of compositionally zoned ignimbrite. Early climactic ignimbrite contains uniform rhyodacitic pumice and traveled far from the vent, whereas late, less mobile ignimbrite is dominated by crystal-rich andesitic scoria and mafic crystal mush. Funded by the USGS, NPS, and FHWA, the DOGAMI-led Oregon LiDAR Consortium contracted with Watershed Services to collect ~800 km2 of LiDAR over Crater Lake National Park from Aug 2010 to Sept 2010. Ground laser returns have an average density of 1.63 returns/m2 over the heavily forested area of interest. The data have a lateral RMSE and vertical accuracy of 0.05 m. A bare earth terrain model allows a virtual removal of the forest, revealing fine-scale surface morphology, notably in the climactic ignimbrite. Secondary pyroclastic flows, explosion craters, erosion by water, and compaction-related deformation modified the originally smooth ignimbrite surface. Distinct pyroclastic flow fronts are evident in the LiDAR in Annie Creek valley. Leveed flows stand approximately 5 m above the lower ignimbrite surface, and individual toes are about 1-2 m high. Preliminary field checking indicates that rhyodacitic pumice dominates the lower ignimbrite surface, but the leveed flows are a subequal mix of locally oxidized rhyodacitic pumice and andesitic scoria. We hypothesize that these deposits were secondary pyroclastic flows formed by gravitational failure of late ignimbrite. In the Castle Creek valley, is a 2-meter collapse scarp that may have spawned a small secondary pyroclastic flow; several such headwall scarps are present in Sand Creek valley. Differential compaction features are common in many thick ignimbrites. We suggest this caused the deformation of the ignimbrite apparent in the LiDAR. In Annie Creek valley are a series of flow parallel asymmetric ridges, with shallower slopes toward the

  14. Characterization of geothermal paleosystem in the Lesser Antilles volcanic arc: structural, petrographic, thermodynamic and petrophysics analysis of Terre-de-Haut (Les Saintes archipelago, Lesser Antilles) (United States)

    Favier, Alexiane; Navelot, Vivien; Verati, Chrystèle; Lardeaux, Jean-Marc; Corsini, Michel; Diraison, Marc; Géraud, Yves; Mercier de Lépinay, Jeanne; Munschy, Marc


    This survey takes part in the GEOTREF project (high enthalpy geothermal energy in fractured reservoirs), supported by the French government program "Investments for the future". The program focuses on the exploration of geothermal resource in the Lesser Antilles volcanic arc. An exclusive license has been issued in the Vieux-Habitants area (Basse-Terre, Guadeloupe) to carry on the development of high-temperature geothermal energy in this active volcanic region. The deep geothermal reservoir on the Basse-Terre island could be characterized in exhumed paleosystems. The reference paleosystem in the Guadeloupe archipelago is located in Terre-de-Haut. Four major fault directions have been highlighted N000-N020, N050-N070, N090-N110 and N130-N140. Field observations emphasize three major cleavage directions overlaying the fault systems: N035-N060, N080-N110, N145-N165. Volcanic rocks affected by cleavage display several metamorphic transformation grades. The more transformed calc-alkaline rocks are located at the intersection of several cleavage directions. Mineralogical transformations due to metamorphism and surimposed fractures are also responsible for strong changes of petrophysical properties. In comparison with the reference protolith of andesitic lava flows outcropping in Vieux-Habitants, which have porosity and permeability lower than 5 % and 10-15 m2, andesites of Terre-de-Haut have better reservoir properties with connected porosity and permeability higher than 15 % and 10-14-10-15 m2 respectively. Thermodynamic modelling based on petrography and chemical composition of the most transformed rocks highlights a steady state mineral assemblage between 0.25 - 1.5 kbar and 350 - 450 ˚ C. It corresponds to a geothermal gradient higher than 120 to 150˚ C/km. This is consistent with temperatures measured in Bouillante wells. However, this geothermal gradient is notably higher to a usual volcanic arc conductive gradient estimated to 70-100˚ C/km. It can be explained

  15. Impact of Magmatism on the Geodynamic Evolution of Southern Georgia on the Example of the Lesser Caucasus Artvin-Bolnisi Block. (United States)

    Sadradze, Nino; Adamia, Shota; Zakariadze, Guram; Beridze, Tamara; Khutsishvili, Sophio


    The Georgian region occupies the central part of the collisional zone between the Eurasian and Africa-Arabian continents and is actually a collage of lithospheric fragments of the Tethyan Ocean and its northern and southern continental margins. Magmatic evolution is an important event in the formation and development of the geological structure of Southern Georgia, where several reliably dated volcanogenic and volcanogenic-sedimentary formations are established. The region represents a modern analogue of continental collision zone, where subduction-related volcanic activity lasted from Paleozoic to the end of Paleogene. After the period of dormancy in the Early-Middle Miocene starting from the Late Miocene and as far as the end of the Pleistocene, primarily subaerial volcanic eruptions followed by formation of volcanic highlands and plateaus occurred in the reigon. The Upper Miocene to Holocene volcanic rocks are related to the transverse Van-Transcaucasian uplift and belong to post-collisional calc- alkaline basalt-andesite-dacite-rhyolite series. A system of island arc and intra-arc rift basins (Artvin-Bolnisi and Achara-Trialeti) have been interpreted as characteristic of the pre-collisional stage of the region development, while syn- post-collisional geodynamic events have been attributed to intracontinental stage. Outcrops of the postcollisional magmatic rocks are exposed along the boundaries of the major tectonic units of the region. The Artvin-Bolnisi unit forms the northwestern part of the Lesser Caucasus and represents an island arc domain of so called the Somkheto-Karabakh Island Arc or Baiburt-Garabagh-Kapan belt. It was formed mainly during the Jurassic-Eocene time interval on the southern margin of the Eurasian plate by nort-dipping subduction of the Neotethys Ocean and subsequent collision to the Anatolia-Iranian continental plate. The Artvin-Bolnisi unit, including the Bolnisi district, was developing as a relatively uplifted island arc-type unit

  16. Cumulate xenoliths from St. Vincent, Lesser Antilles Island Arc: a window into upper crustal differentiation of mantle-derived basalts (United States)

    Tollan, P. M. E.; Bindeman, I.; Blundy, J. D.


    In order to shed light on upper crustal differentiation of mantle-derived basaltic magmas in a subduction zone setting, we have determined the mineral chemistry and oxygen and hydrogen isotope composition of individual cumulus minerals in plutonic blocks from St. Vincent, Lesser Antilles. Plutonic rock types display great variation in mineralogy, from olivine-gabbros to troctolites and hornblendites, with a corresponding variety of cumulate textures. Mineral compositions differ from those in erupted basaltic lavas from St. Vincent and in published high-pressure (4-10 kb) experimental run products of a St. Vincent high-Mg basalt in having higher An plagioclase coexisting with lower Fo olivine. The oxygen isotope compositions (δ18O) of cumulus olivine (4.89-5.18‰), plagioclase (5.84-6.28‰), clinopyroxene (5.17-5.47‰) and hornblende (5.48-5.61‰) and hydrogen isotope composition of hornblende (δD = -35.5 to -49.9‰) are all consistent with closed system magmatic differentiation of a mantle-derived basaltic melt. We employed a number of modelling exercises to constrain the origin of the chemical and isotopic compositions reported. δ18OOlivine is up to 0.2‰ higher than modelled values for closed system fractional crystallisation of a primary melt. We attribute this to isotopic disequilibria between cumulus minerals crystallising at different temperatures, with equilibration retarded by slow oxygen diffusion in olivine during prolonged crustal storage. We used melt inclusion and plagioclase compositions to determine parental magmatic water contents (water saturated, 4.6 ± 0.5 wt% H2O) and crystallisation pressures (173 ± 50 MPa). Applying these values to previously reported basaltic and basaltic andesite lava compositions, we can reproduce the cumulus plagioclase and olivine compositions and their associated trend. We conclude that differentiation of primitive hydrous basalts on St. Vincent involves crystallisation of olivine and Cr-rich spinel at depth

  17. Geology, lithogeochemistry and paleotectonic setting of the host sequence to the Kangasjärvi Zn-Cu deposit, central Finland: implications for volcanogenic massive sulphide exploration in the Vihanti-Pyhäsalmi district

    Directory of Open Access Journals (Sweden)

    Michael D. Roberts


    Full Text Available The Kangasjärvi Zn-Cu deposit is a highly deformed and metamorphosed Paleoproterozoic volcanogenic massive sulphide (VMS deposit located in the Vihanti-Pyhäsalmi base metal mining district of central Finland. The host sequence to the deposit, referred to as the Inner Volcanic Sequence (IVS, is comprised of a bimodal suite of metavolcanic rocks and a regionally extensive tonalite-trondhjemite gneiss (sub-volcanic intrusions?. A separate and perhaps younger sequence of mafic volcanic rocks, with irregular intervals of undifferentiated intermediate to felsic schists and metalimestones, referred to as the Outer Volcanic Sequence (OVS, are separated from the IVS sequence by intervals of metagreywacke and U-P-bearing graphitic schists. A stratigraphic scheme for rocks within the IVS is proposed based on outcrop observations, locally preserved volcanic textures, aspects of seafloor-related hydrothermal alteration and lithogeochemistry. In this scheme, rare andesites form the lowermostvolcanic stratigraphy and are overlain by typical island-arc basalts that were erupted in a subaqueous setting. Tonalite-trondhjemite subvolcanic intrusions were locally emplaced within andesites and coeval rhyolites were extruded on the basaltic substrate. The extrusion of rhyolites, including high-silica rhyolites, was coeval with regional-scale, pre-metamorphic seafloor hydrothermal alteration and local sulphide mineralization. Extensively altered rhyolites envelope massive sulphides and are underlain by altered basalts. The latter rocks are now characterized by a variety of low-variance metamorphic mineral assemblages (e.g. orthoamphibole-cordierite rocks and define a domain of intense pre-metamorphic chlorite ± sericite alteration in the stratigraphic footwall of the deposit. The altered nature of these rocks is attributed to reaction with seawater-related hydrothermal fluids within a zone of upflow at or near the seafloor. The fundamental controls on convective

  18. Reconnaissance geology of the Sabkhat Muraysis quadrangle, Kingdom of Saudi Arabia (United States)

    Overstreet, William C.; Whitlow, Jesse William; Ankayr, Abdullah O.


    The Sabkhat Muraysis quadrangle .covers an area of 2843 sq km in the central part of the Kingdom of Saudi Arabia. In the northwestern quarter of the area Precambrian rocks are exposed. They are overlain toward the .south and east by sedimentary formations of Permian and younger age. Four main units of Precambrian .rocks were identified in this area. From oldest to youngest they are: hornblende-biotite granite gneiss; amphibolite and rhyolite of the Halaban Group; graywacke and chlorite-sericite schist of the Bi'r Khountina Group; and biotite-hornblende granite, The hornblende-biotite granite gneiss unit and the biotite-hornblende granite .unit are both poorly exposed and largely covered by veneers of sand, Owing to these factors the boundaries between the granitic, rocks are obscure, Much of what is shown as hornblende-biotite granite gneiss may actually be biotite-hornblende granite. The Halaban Group is represented by an older amphibolite unit called the Umm Mushraha Formation and by a younger rhyolite unit., called the Wadi al Jifr Formation. Layered and msslve components in the Umm Mushraha Formation represent metamorphosed .andesite and graywacke, ,and metamorphosed diorite., gabbro, and pyroxenite. The Wadi al Jifr Formation consists of virtually unmetamorphosed to strongly sheared and metamorphosed rhyolite, rhyolite porphyry, and rhyolite tuff which at many places has been metamorphosed to quartz-sericite schist and biotite-muscovite schist. These schists retain porphyroclasts of blue quartz which also form conspicuous phenocrysts in the unsheared rhyolite. Locally, the sheared rhyolite ha s been hydrothermally altered resulting in the formation of quartz-chlorite-ankerite veins and a sparse impregnation of pyrite. The Bi'r Khountina Group consists of a unit of graywacke and argillite with interbedded andesite that is metamorphosed to chlorite-sericite schist near the contacts of intrusive biottte-hornblende granite. This .unit is-called the Abu Sawarir

  19. Volcaniclastic stratigraphy of Gede Volcano, West Java, Indonesia: How it erupted and when (United States)

    Belousov, A.; Belousova, M.; Krimer, D.; Costa, F.; Prambada, O.; Zaennudin, A.


    Gede Volcano, West Java (Indonesia), is located 60 km south of Jakarta within one of the regions with highest population density in the world. Therefore, knowledge of its eruption history is necessary for hazard evaluation, because even a small eruption would have major societal and economic consequences. Here we report the results of the investigation of the stratigraphy of Gede (with the focus on its volcaniclastic deposits of Holocene age) and include 23 new radiocarbon dates. We have found that a major part of the volcanic edifice was formed in the Pleistocene when effusions of lavas of high-silica basalt dominated. During this period the volcano experienced large-scale lateral gravitational failure followed by complete reconstruction of the edifice, formation of the summit subsidence caldera and its partial refilling. After a repose period of > 30,000 years the volcanic activity resumed at the Pleistocene/Holocene boundary. In the Holocene the eruptions were dominantly explosive with magma compositions ranging from basaltic andesite to rhyodacite; many deposits show heterogeneity at the macroscopic hand specimen scale and also in the minerals, which indicates interactions between mafic (basaltic andesite) and silicic (rhyodacite) magmas. Significant eruptions of the volcano were relatively rare and of moderate violence (the highest VEI was 3-4; the largest volume of erupted pyroclasts 0.15 km3). There were 4 major Holocene eruptive episodes ca. 10,000, 4000, 1200, and 1000 yr BP. The volcanic plumes of these eruptions were not buoyant and most of the erupted products were transported in the form of highly concentrated valley-channelized pyroclastic flows. Voluminous lahars were common in the periods between the eruptions. The recent eruptive period of the volcano started approximately 800 years ago. It is characterized by frequent and weak VEI 1-2 explosive eruptions of Vulcanian type and rare small-volume extrusions of viscous lava. We estimate that during

  20. Carboniferous-Permian tectonic transition envisaged in two magmatic episodes at the Kuruer Cu-Au deposit, Western Tianshan (NW China) (United States)

    Yu, Jie; Li, Nuo; Qi, Nan; Guo, Jian-Ping; Chen, Yan-Jing


    The Western Tianshan in NW China is one of the most important gold provinces in the Central Asian Orogenic Belt (CAOB). The recently discovered Kuruer Cu-Au deposit has been interpreted to represent a transition from high-sulfidation epithermal to porphyry mineralization system. In this study, we present new LA-ICP-MS zircon U-Pb ages for the many magmatic rock types at Kuruer, including the Dahalajunshan Formation andesitic tuff (333.2 ± 1.6 Ma), diorite porphyry (269.7 ± 2.0 Ma), slightly-altered (264.4 ± 2.6 Ma) and intensively-altered (270.5 ± 2.5 Ma) albite porphyry. These ages reveal two distinct magmatic episodes: The Early Carboniferous Dahalajunshan Formation (wall rocks) andesitic tuff samples contain narrow ranges of SiO2 (60.29-61.28 wt.%), TiO2 (0.96-0.98 wt.%), Al2O3 (16.55-16.57 wt.%) and Fe2O3T (5.36-5.57 wt.%). The tuff is characterized by LREE enrichment and HFSE depletion, as well as LREE/HREE enrichment ((La/Yb)N = 8.31-8.76) and negative Eu anomalies (δEu = 0.64-0.76). Zircon εHf (t) values are 5.4-8.2, and two-stage Hf model ages (TDM2) are 821-1016 Ma, indicating partial melting of a moderately depleted mantle wedge with Precambrian continental crustal input. The ore-forming Middle Permian diorite porphyry and (quartz) albite porphyry have variable major oxide compositions (e.g., SiO2 = 53.09-53.12 wt.% for the diorite porphyry, 70.84-78.03 wt.% for the albite porphyry, and 74.07-75.03 wt.% for the quartz albite porphyry) but similar chondrite-normalized REE and primitive mantle-normalized multi-element patterns. These porphyries display LREE enrichment and HFSE depletion, as well as elevated LREE/HREE enrichment and negative Eu anomalies. The positive zircon εHf(t) values (11.7-15.9 for the diorite porphyry, 8.9-14.9 for the albite porphyry) and young two-stage Hf model ages (TDM2) (282-542 Ma for the diorite porphyry, 337-717 Ma for the albite porphyry) indicate a major juvenile continental crustal involvement. We propose that the

  1. Geochemistry and petrogenesis of basaltic rocks from the Develidağ volcanic complex, Central Anatolia, Turkey (United States)

    Kürkcüoglu, Biltan


    The Develidağ volcanic zone (DVZ) is a part of the Middle Miocene-Quaternary Cappadocian Volcanic Province (CVP) in central Anatolia. The DVZ is located at the eastern side of the Plio-Quaternary Sultansazlığı pull-apart basin, that opened along the Ecemiş left-lateral strike-slip fault. Towards the south, the volcanic rocks of the DVZ overlie the Paleozoic metamorphic rocks of the Taurus range. Regional stratigraphic studies indicate that volcanic rocks of the DVZ crop out in a ˜N-S trending rectangular-shaped exposure in the middle of which Middle Miocene andesitic rocks are found surrounded by Upper Miocene basaltic rocks. The purpose of this paper is to present basic geochemical data for the DVZ rocks and discuss possible processes of magma generation. The Develidağ basalts are characterized by low LILE (Rb, K, Ba, Th) and high HFSE (Nb,Zr,Hf,Y) contents, whereas the andesites generally have high LILE and HFSE values except for Nb and Zr. Variable abundances of Pb (3.11-12.09 ppm) and U (0.36-2.64 ppm) are associated with high Ba content within the rock suites. Although low Nb/La (0.6-0.7) and relatively high Ba/Nb ratios indicate crustal involvement for the basalts, high Zr/Ba (0.5), Zr/Hf (42-47) and Th/U (3.13-4.69) values imply contributions from an asthenospheric source component. Furthermore, the high Zr/Hf values (>36) are the diagnostic feature of metasomatized mantle (Dupuy et al., 1992; Rudnick et al., 1993). Moreover, multi-element patterns show that Develidağ basalts have similar trace element signatures to those of the US Cascades tholeiites. The ratios of Zr/Hf, Zr/Ba, Nb/Th and Sr/Ce indicate that basaltic rocks are derived from a MORB-like mantle, and calculated melting model reflects generation from a spinel peridotite source (3-4% melting), but the combined effects of melting and assimilation and fractional crystallization (AFC) processes seem to be partially responsible for the relatively evolved rocks. Typical tholeiitic

  2. Development of Waterfall Cliff Face: An Implication from Multitemporal High-definition Topographic Data (United States)

    Hayakawa, Y. S.; Obanawa, H.


    Bedrock knickpoints (waterfalls) often act as erosional front in bedrock rivers, whose geomorphological processes are various. In waterfalls with vertical cliffs, both fluvial erosion and mass movement are feasible to form the landscape. Although morphological changes of such steep cliffs are sometimes visually observed, quantitative and precise measurements of their spatiotemporal distribution have been limited due to poor accessibility to such cliffs. For the clarification of geomorphological processes in such cliffs, multi-temporal mapping of the cliff face at a high resolution can be advantaged by short-range remote sensing approaches. Here we carry out multi-temporal terrestrial laser scanning (TLS), as well as structure-from-motion multi-view stereo (SfM-MVS) photogrammetry based on unmanned aerial system (UAS) for accurate topographic mapping of cliffs around a waterfall. The study site is Kegon Falls in central Japan, having a vertical drop of surface water from top of its overhanging cliff and groundwater outflows from its lower portions. The bedrock consists of alternate layers of jointed andesite lava and conglomerates. The latest major rockfall in 1986 caused approximately 8-m recession of the waterfall lip. Three-dimensional changes of the rock surface were detected by multi-temporal measurements by TLS over years, showing the portions of small rockfalls and surface lowering in the bedrock. Erosion was frequently observed in relatively weak the conglomerates layer, whereas small rockfalls were often found in the andesite layers. Wider areas of the waterfall and cliff were also measured by UAS-based SfM-MVS photogrammetry, improving the mapping quality of the cliff morphology. Point clouds are also projected on a vertical plane to generate a digital elevation model (DEM), and cross-sectional profiles extracted from the DEM indicate the presence of a distinct, 5-10-m deep depression in the cliff face. This appears to have been formed by freeze-thaw and

  3. Late Miocene Debris-Avalanche Deposit At The Gutai Shield Volcano, NW Romania. Re- Evaluation Of Geological Mapping And Mineral Deposits (United States)

    Seghedi, I.; Fülöp, A.


    The recent identification of debris avalanche deposits (DADs) originating from the southern edge of the Ignis peak (1306m, highest of the Gutai Mts.) has important implications for understanding its genesis in the geological context of the broader area, rich in hydrothermal intrusive-related base metal and gold-silver deposits closely connected to the Dragos Voda - Bogdan Voda strike-slip fault system. Pyroxene andesite lavas are exposed below the Ignis peak followed by hornblende and pyroxene andesites the only ones found in the DAD. The flank failure event has left an E-W-oriented horseshoe shaped scar with an estimated volume of material removed of at least 0.35 km3 and an estimated area covered by DADs of 4,345 km2 as a minimum. The deposit is a mega breccia with a variable amount of coarse matrix with jigsaw-fractured blocks, large boulders, and several southward-elongated hummocks up to 1.8 km distance from the scar. Between 720-850 m altitude the DADs contain megablocks of 5-12 m thick and up to 100 m long of layered fine-grained poorly consolidated pyroclastic materials of interlayered ash and lapillistone of fallout origin, and clay beds rich in vegetation remnants(known as the 'Chiuzbaia flora' of similar age as the surrounding lava flows, i.e. ca. 10-7 Ma) and diatoms. These megablocks found in various positions, suggest a lithological discontinuity likely representing the detachment surface of the gravity-driven instability phenomenon and the deep excavation of the volcano flank by the sector collapse event. The clayey material of these blocks acted probably as an efficient barrier to water infiltration and helped destabilization of the overlying rock mass. Since no explosive products have been observed to follow the DAD, it is possible that the sliding was triggered by pressure release of hydrothermal system along an E-W fault parallel to the Dragos Voda-Bogdan Voda fault system, with related high-grade ore deposits. This suggests the possible presence

  4. The Punta del Cobre Formation, Punta del Cobre Candelaria area, northern Chile (United States)

    Marschik, Robert; Fontboté, Lluís.


    The Punta del Cobre Formation hosts the iron oxide-rich Cu-Au(-Zn-Ag) deposits of the Punta del Cobre belt, Chile. Hydrothermal alteration associated with mineralization and/or contact metamorphism caused by the Coastal Batholith exposed in the west resulted in new mineral assemblages and significant changes in the geochemical composition of its rocks. This paper presents a redefinition of the Punta del Cobre Formation and discusses its geologic context. The Punta del Cobre Formation is subdivided, from bottom to top, into: (1) the 'Geraldo-Negro Member', composed mainly of massive andesitic volcanic rocks (>300 m) and locally dacitic rocks (up to 200 m) that overlie the latter, and (2) the 'Algarrobos Member' (up to >800 m) comprising mainly volcaniclastic rocks, basalt andesitic and basaltic flows, and volcanic breccias. The Punta del Cobre Formation is overlain by the Chañarcillo Group, the lowest part of which is represented by alternating carbonate and volcaniclastic beds of the Abundancia Formation, which pass vertically and laterally into limestones of the Nantoco Formation. The contact between the Punta del Cobre Formation and the overlying Abundancia Formation is transitional and defined by the first continuous bed of massive limestone or its metamorphosed equivalent. A pre-upper Valanginian age for the Punta del Cobre Formation is suggested by ammonites of Berriasian age found in the upper part of the Algarrobos Member and Late Valanginian-Early Hauterivian fauna in the overlying Abundancia Formation. Despite the intense alteration, immobile element compositions of the volcanic rocks of the Punta del Cobre Formation enable the recognition of a calc-alkaline suite with a trend to more primitive, less differentiated magmas towards the top of the stratigraphic sequence, reflecting initial stages of basin development. The transgressive nature of the sedimentary part of the Punta del Cobre Formation marks the onset of increased subsidence that eventually

  5. Stable isotope (δ18O and δ2H) data for precipitation, stream water, and groundwater in Puerto Rico (United States)

    Scholl, Martha A.; Torres-Sanchez, Angel; Rosario-Torres, Manuel


    Puerto Rico is located in the northeastern Caribbean Sea (18.2 °N, 66.3 °W), with the Atlantic Ocean on its northern coast. The U.S. Geological Survey’s Water, Energy, and Biogeochemical Budgets (WEBB) program study area in which most of these data were collected comprises the El Yunque National Forest and surrounding area of eastern Puerto Rico. Samples were collected in two forested watersheds, the Rio Mameyes and the Rio Icacos/Rio Blanco, on opposite sides of a ridge in the Luquillo Mountains on the eastern end of the island (fig. 1). Elevation in both watersheds ranges from sea level to approximately 1,000 meters (m). Near sea level, land use is mixed pasture, moist forest, and residential, grading to completely forested within the boundaries of El Yunque National Forest. Forest type changes with elevation from tabonuco to palo colorado to sierra palm to cloud forest above approximately 950 m (Murphy and others, 2012). The Rio Mameyes watershed is oriented north-northeast, and the basin is underlain by volcaniclastic bedrock (basaltic to andesitic volcanic sandstone/mudstone/conglomerate/breccia). The Rio Icacos/Rio Blanco watershed is oriented south-southeast. The Rio Icacos is one of the headwaters of the Rio Blanco and is underlain by quartz diorite. The lower Rio Blanco basin is underlain by andesitic volcaniclastic bedrock. This report also contains a long-term rain isotope dataset from the San Agustin site, in north-central Puerto Rico (fig. 1). Puerto Rico has a tropical climate dominated by easterly trade winds, and seasonal climate patterns affect the hydrology of the study area. The summer wet season is characterized by convective precipitation from tropical easterly waves, troughs, and cyclonic low-pressure systems, including tropical storms and hurricanes; in contrast, the drier winter season is characterized by trade-wind showers and frontal systems. The highest single-event rainfall totals tend to be associated with tropical storms

  6. Amphibole stability using new thermobarometric formulations on calc-alkaline magmas of Volcán Doña Inés, Chile (United States)

    Hines, R. A.; Walker, J. A.


    Location and delineation of subvolcanic magma chambers have heavily relied on geophysical, particularly seismic, data. However, new and improved thermobarometric formulations can yield equally important constraints on the depths and conditions of magmatic storage and movement. The objective of this study was to utilize the single phase thermobarometric algorithms of Ridolfi et al. (2010) to determine the conditions of amphibole stability in the volcanic system beneath Volcán Doña Inés, a large stratovolcano from the Mid-Late Miocene magmatic arc in the Central Volcanic Zone of the Andes, Chile. According to Moulds (1989), Doña Inés had three main eruptive vents: the main central vent; a second vent low on its flanks, called Loma Doña Inés; and a sister cone, called Gemelas. The barometric, thermometric, hygrometric, and oxygen fugacity formulations of Ridolfi et al. (2010) are based on the total aluminum (AlT) content, the silicon index (Si*), the octahedral aluminum index ([6]Al*), and the magnesium index (Mg*) of the amphibole grains, respectively. For this study, 120 amphiboles from 20 andesite-dacite samples from Doña Inés were analyzed approximately 30 times per grain with an electron microprobe. Amphibole compositions range from tschermakitic pargasite, to magnesiohornblende, to magnesiohastingsite, with the central vent crystals exhibiting the widest variability. Preliminary results from the thermobarometer indicate that amphibole crystallization beneath the central vent occurred between 213-928 ± 102 MPa and 872-1016 ± 22 *C, with magmatic water contents of approximately 5.2-9.9 ± 1.5 wt%. Conditions of formation of amphibole at Loma Doña Inés were between 230-405 ± 37 MPa and 901-980 ± 22 *C, with approximately 5.4-6.2 ± 0.9 wt% magmatic H2O and were similar at the sister cone Gemelas: 259-309 ± 34 MPa, 902-952 ± 22 *C, and 5.1-6.2 ± 0.9 wt% magmatic H2O. Temperatures obtained from amphibole stability agree well with the previous from

  7. The 1994-2001 eruptive period at Rabaul, Papua New Guinea: Petrological and geochemical evidence for basalt injections into a shallow dacite magma reservoir, and significant SO2 flux (United States)

    Patia, H.; Eggins, S. M.; Arculus, R. J.; McKee, C. O.; Johnson, R. W.; Bradney, A.


    The eruptions that began at Rabaul Caldera on 19 September 1994 had two focal points, the vents Tavurvur and Vulcan, located 6 km apart on opposing sides of the caldera. Vulcan eruptives define a tight cluster of dacite compositions, whereas Tavurvur eruptives span an array from equivalent dacite compositions to mafic andesites. The eruption of geochemically and mineralogically identical dacites from both vents indicates sourcing from the same magma reservoir. This, together with previously reported H2O-CO2 volatile contents of dacite melt inclusions, a caldera-wide seismic low-velocity zone, and a seismically active caldera ring fault structure are consistent with the presence at 3-6 km depth of an extensive, tabular dacitic magma body having volume of about 15-150 km3. The Tavurvur andesites form a linear compositional array and have strongly bimodal phenocryst assemblages that reflect dacite hybridisation with a mafic basalt. The moderately large volume SO2 flux documented in the Tavurvur volcanic plume (and negligible SO2 flux in the Vulcan plume) combined with high dissolved S contents of basaltic melt inclusions trapped in olivine of Tavurvur eruptives, indicate that the amount of degassed basaltic magma was 0.1 km3 and suggest that the injection of this magma was confined to the Tavurvur-side (eastern to northeastern sector) of the caldera. Circumstantial evidence suggests that the eruption was triggered and evolved in response to a series of basaltic magma injections that may have commenced in 1971 and continued up until at least the start of the 1994 eruptions. The presence of zoned plagioclase phenocrysts reflecting older basalt-dacite interaction events (i.e. anorthite cores overgrown with thick andesine rims), evaluation of limited available data for the products of previous eruptions in 1878 and 1937-1943, and the episodic occurrence of major intra-caldera seismo-deformational events indicates that the shallow magma system at Rabaul Caldera is

  8. Geologic field-trip guide to Mount Shasta Volcano, northern California (United States)

    Christiansen, Robert L.; Calvert, Andrew T.; Grove, Timothy L.


    The southern part of the Cascades Arc formed in two distinct, extended periods of activity: “High Cascades” volcanoes erupted during about the past 6 million years and were built on a wider platform of Tertiary volcanoes and shallow plutons as old as about 30 Ma, generally called the “Western Cascades.” For the most part, the Shasta segment (for example, Hildreth, 2007; segment 4 of Guffanti and Weaver, 1988) of the arc forms a distinct, fairly narrow axis of short-lived small- to moderate-sized High Cascades volcanoes that erupted lavas, mainly of basaltic-andesite or low-silica-andesite compositions. Western Cascades rocks crop out only sparsely in the Shasta segment; almost all of the following descriptions are of High Cascades features except for a few unusual localities where older, Western Cascades rocks are exposed to view along the route of the field trip.The High Cascades arc axis in this segment of the arc is mainly a relatively narrow band of either monogenetic or short-lived shield volcanoes. The belt generally averages about 15 km wide and traverses the length of the Shasta segment, roughly 100 km between about the Klamath River drainage on the north, near the Oregon-California border, and the McCloud River drainage on the south (fig. 1). Superposed across this axis are two major long-lived stratovolcanoes and the large rear-arc Medicine Lake volcano. One of the stratovolcanoes, the Rainbow Mountain volcano of about 1.5–0.8 Ma, straddles the arc near the midpoint of the Shasta segment. The other, Mount Shasta itself, which ranges from about 700 ka to 0 ka, lies distinctly west of the High Cascades axis. It is notable that Mount Shasta and Medicine Lake volcanoes, although volcanologically and petrologically quite different, span about the same range of ages and bracket the High Cascades axis on the west and east, respectively.The field trip begins near the southern end of the Shasta segment, where the Lassen Volcanic Center field trip leaves

  9. Performance and safety assessment of the co-location of the near surface radioactive waste disposal facilities and borehole disposal concept in the Philippines

    Energy Technology Data Exchange (ETDEWEB)

    Vargas, Edmundo; Reyes, Rolando [Atomic Research Division, Philippine Nuclear Research Institute, Quezon City (Philippines); Palattao, Maria Visitacion; Nohay, Carl; Singayan, Alfonso [Nuclear Regulatory Division, Philippine Nuclear Research Institute, Quezon City (Philippines); Aurelio, Mario [National Institute of Geological Sciences, University of the Philippines, Quezon City (Philippines); Gedeon, Matej [Belgian Nuclear Research Centre SCK-CEN, Mol (Belgium); Luna, Roy Anthony C. [AMH Philippines, Inc., Quezon City (Philippines)


    The Philippine Nuclear Research Institute (PNRI) in collaboration with the interagency technical committee on radioactive waste has been undertaking a national project to find a final solution to the country's low to intermediate level radioactive waste. The strategy adopted was to co-locate 2 disposal concepts that will address the types of radioactive waste generated from the use of radioactive materials. This strategy is expected to compensate for the small volumes of waste generated in the Philippines as compared to countries with big nuclear energy programs. It will also take advantage of the benefits of a shared infrastructure and R and D work that accompany such project. The preferred site selected from previous site selection and investigations is underlain by highly fractured 'andesitic volcaniclastics' mantled by residual clayey soil which act as the aquifer or water bearing layer. Results of investigation show that the groundwater in the area is relatively dilute and acidic. Springs at the lower elevations of the footprint also indicate acidic waters. The relatively acidic water is attributed to the formation of sulfuric acid by the oxidation of the pyrite in the andesite. A preliminary post closure safety assessment was carried out using the GMS MODFLOW and HYDRUS softwares purchased through the International Atomic Energy Agency (IAEA) technical assistance. Results from MODFLOW modeling show that the radionuclide transport follows the natural gradient from the top of the hill down to the natural discharge zones. The vault dispersion model shows a circular direction from the vaults towards the faults and eventually to the creeks. The contaminant transport from borehole shows at least one confined plume from the borehole towards the creek designated as Repo1 and eventually follows downstream. The influx of surface water and rainfall to the disposal vault was modeled using the HYDRUS software. The pressure head and water content at the base

  10. Contributions to the petrography, geochemistry and geochronology (U-Pb and Sm-Nd) of the Paleoproterozoic effusive rocks from Iricoume Group, Amazonian Craton, Brazil

    Energy Technology Data Exchange (ETDEWEB)

    Marques, Suelen Nonata de Souza; Nascimento, Rielva Solimairy Campelo do, E-mail:, E-mail: [Universidade Federal do Amazonas (UFAM), Manaus, AM (Brazil). Inst. de Geociencias; Souza, Valmir da Silva; Dantas, Elton Luiz, E-mail:, E-mail: [Universidade de Brasilia (UnB), DF (Brazil). Inst. de Geociencias; Valerio, Cristovao da Silva, E-mail: [Universidade Federal de Roraima (UFRR), Boa Vista, RR (Brazil). Inst. de Geociencias


    The southernmost region of the Guyana shield, Amazonian craton, hosts large record of Paleoproterozoic effusive rocks of the Iricoume Group. They present remarkably well-preserved igneous textures and structures. The SiO{sub 2} contents reveal a bimodal association marked by a compositional gap between acid (SiO{sub 2} > 67 wt%) and intermediate (SiO{sub 2} < 57.7 wt%) rocks. The acid effusive rocks are rhyolites to rhyodacites with high SiO{sub 2}, alkali, Rb, Zr, Nb + Ta, La + Ce and 104 Ga/Al content and low Fe{sub 2}O{sub 3tot}, TiO{sub 2}, CaO, Sr and Co content. They exhibit subalkaline, metaluminous-to-peraluminous compositions, and geochemically compatible to A-type magmatism emplaced in post-collisional to within-plate tectonic settings. The intermediate rocks are andesitic/basalt to andesite relatively high contents of TiO{sub 2}, Al{sub 2}O{sub 3}, Fe{sub 2}O{sub 3total}, MgO, CaO, Sr and Co; low SiO{sub 2}, K{sub 2}O, Rb, Zr, Nb + Ta, La + Ce. They have subalkaline and metaluminous geochemical composition and plot on within-plate basalt field. The acid rocks crystallized at 1882 ± 11 Ma in U-Pb analyses for LA-MC-ICPMS zircon data. The Sm-Nd isotopic data on all rocks reveal a Nd TDM model ages between 2.59 and 2.16 Ga and ε{sub Nd}(t) values between -5.78 and 0.03, indicate that the magmatic evolution was related to the reworking of older Paleoproterozoic at the Rhyacian-Siderian period, continental crust (Transamazonian crust-forming event) with some mixing with a limited amount mantle-derived magmas or with contamination by Archean crust. The petrographic, geochemical and geochronological data presented in this paper suggest a within-plate to post-collisional tectonic setting for the Iricoume volcanism, involving lower crust uplift and generation of basalt magma in an extensional regime. (author)

  11. Across-arc variation of Magma Composition in Central Sunda Arc, Indonesia: A test of slab influence to mantle source (United States)

    Wibowo, H.; Hasenaka, T.; Handini, E.; Harijoko, A.


    Sunda arc, a part of Pacific ring of fire, extends from West Java to Flores. The arc developed since Tertiary period at a convergent tectonic plate margin, where India-Australian plate is subducted northward beneath Eurasian plate. Central Sunda Arc (CSA) is represented by a series of Quartenary volcanoes from the fore arc toward the back arc including Merapi, Merbabu, Telomoyo, Ungaran and Muria. Estimated depth of Wadati-Benioff zone beneath CSA ranges from 190 km for Merapi to 350 km for Muria. Field works have been conducted for brief geologic observation and rock sample collection from Merbabu, Telomoyo, Muria, including Genuk on the north and Patiayam on the south of Muria. Data from Merapi is compiled from previous studies. X-Ray Fluorescence, Prompt Gamma Ray and Instrumental Neutron Activation Analyses were used to obtain whole rock compositions. Previously reported trace element of Altered Oceanic Crust (AOC) and Indian Ocean sediment are employed to estimate the derived fluid composition, by considering mobility of the elements and assuming 1.5% weight fraction of hydrous fluid extracted from them. By applying subduction component elements, we tried to estimate the slab influence to mantle source in magma genesis of CSA. High Al2O3 (~18 wt%), low Cr (~29 ppm) and Ni (~27 ppm) of the volcanic rocks characterize CSA. K2O content increases gradually with the depth of Benioff zone from each volcano. Most samples from Merapi, Merbabu, Telomoyo and Ungaran are classified as subalkaline, whereas Muria samples fall on both alkaline and subalkaline fields. In detail, Merapi samples could be divided into medium-K and high-K, Merbabu medium-K, Telomoyo and Ungaran high-K, and Muria samples range from high-K to shosonitic. We only selected unfractionated lavas to avoid assimilation, including basalt, basaltic andesite, basanite, and trachy basaltic andesite. We also exclude samples with hornblende, micas, and K-feldspar to avoid boron fractionation and assimilation

  12. Modelling of Magma Density and Viscocity Changes and Their Influences towards the Characteristic of Kelud Volcano Eruption

    Directory of Open Access Journals (Sweden)

    Hanik Humaida


    Full Text Available DOI: 10.17014/ijog.v6i4.129The effusive eruption of Kelud Volcano in 2007 was different from the previous ones, which in general were more explosive. Among others, density and viscosity are factors that determine the type of eruption. Therefore, the study on the difference of the recent eruption style based on the density and viscosity of magma was carried out. The method used in this study was based on geochemical analysis of the rock and then a modeling was established by using the above parameter. The study on the explosive eruption was emphasized on the data of 1990 eruption, whereas the effusive eruption was based on the data of 2007 eruption. The result shows that the magma viscosity of Kelud Volcano depend on the H O concentration as one of the volatile compound in magma, and temperature which gives the exponential equation. The higher the increase of H O content the smaller the value of its viscosity as well as the higher the temperature. The H O content in silica fluid can break the polymer bond of the silica fluid, because a shorter polymer will produce a lower viscosity. The density of the silica content of Kelud Volcano ranges between andesitic and basaltic types, but andesite is more likely. The fluid density of the material of 1990 eruption is different from 2007 eruption. Compared to the 2007, the 1990 eruption material gave a lower density value in its silica fluid than that of the 2007 one. The low density value of the silica fluid of the 1990 eruption material was reflecting a more acid magma. The level of density value of silica fluid depends on its temperature. At the temperature of 1073 K the density of the 1990 Kelud magma is 2810 kg/m3 and the 2007 magma is 2818 kg/m3, whereas at a temperature of 1673 K, the density is 2672 kg/m3 and 2682 kg/m3 of the 1990 and 2007 eruptions respectively. A modeling by using an ideal gas law of Henry’s Law illustrated that the ascent of Kelud’s magma to the surface may cause changes

  13. The delicate balance between soil production and erosion, and its role on landscape evolution

    Energy Technology Data Exchange (ETDEWEB)

    Dosseto, A., E-mail: [GeoQuEST Research Centre, School of Earth and Environmental Sciences, University of Wollongong. Wollongong, NSW (Australia); Buss, Heather [US Geological Survey. Menlo Park, CA (United States); Suresh, P.O. [Department of Environment and Geography, Macquarie University. North Ryde, NSW (Australia)


    Highlights: > The uranium-series isotope composition of regolith material can be used to determine the soil residence time. > Soil residence times up to 30 and 90 kyr are calculated for Frogs Hollow and Bisley, respectively. > Production rates are relatively similar for granitic and shale lithologies, but much higher over volcanic parent rock. > Soil production matches erosion in soil-mantled landscapes, demonstrating quantitatively that this type of landscape results from a balance between these two processes > Soil production is up to two orders of magnitude slower than erosion in cultivated areas. - Abstract: The diversity in landscapes at the Earth's surface is the result, amongst other things, of the balance (or imbalance) between soil production and erosion. While erosion rates are well constrained, it is only recently that we have been able to quantify rates of soil production. Uranium-series isotopes have been useful to provide such estimates independently of erosion rates. In this study, new U-series isotope are presented data from weathering profiles developed over andesitic parent rock in Puerto Rico, and granitic bedrock in southeastern Australia. The site in Australia is located on a highland plateau, neighbouring a retreating escarpment where soil production rates between 10 and 50 mm/kyr have been determined. The results show that production rates are invariant in these two regions of Australia with values between 15 and 25 mm/kyr for the new site. Andesitic soils show much faster rates, about 200 mm/kyr. Overall, soil production rates determined with U-series isotopes range between 10 and 200 mm/kyr. This is comparable to erosion rates in soil-mantled landscapes, but faster than erosion in cratonic areas and slower than in alpine regions and cultivated areas. This suggests that soil-mantled landscapes maintain soil because they can: there is a balance between production and erosion. Similarly, thick weathering profiles develop in cratonic areas

  14. Reservoir characteristics and control factors of Carboniferous volcanic gas reservoirs in the Dixi area of Junggar Basin, China

    Directory of Open Access Journals (Sweden)

    Ji'an Shi


    Full Text Available Field outcrop observation, drilling core description, thin-section analysis, SEM analysis, and geochemistry, indicate that Dixi area of Carboniferous volcanic rock gas reservoir belongs to the volcanic rock oil reservoir of the authigenic gas reservoir. The source rocks make contact with volcanic rock reservoir directly or by fault, and having the characteristics of near source accumulation. The volcanic rock reservoir rocks mainly consist of acidic rhyolite and dacite, intermediate andesite, basic basalt and volcanic breccia: (1 Acidic rhyolite and dacite reservoirs are developed in the middle-lower part of the structure, have suffered strong denudation effect, and the secondary pores have formed in the weathering and tectonic burial stages, but primary pores are not developed within the early diagenesis stage. Average porosity is only at 8%, and the maximum porosity is at 13.5%, with oil and gas accumulation showing poor performance. (2 Intermediate andesite and basic basalt reservoirs are mainly distributed near the crater, which resembles the size of and suggests a volcanic eruption. Primary pores are formed in the early diagenetic stage, secondary pores developed in weathering and erosion transformation stage, and secondary fractures formed in the tectonic burial stage. The average porosity is at 9.2%, and the maximum porosity is at 21.9%: it is of the high-quality reservoir types in Dixi area. (3 The volcanic breccia reservoir has the same diagenetic features with sedimentary rocks, but also has the same mineral composition with volcanic rock; rigid components can keep the primary porosity without being affected by compaction during the burial process. At the same time, the brittleness of volcanic breccia reservoir makes it easily fracture under the stress; internal fracture was developmental. Volcanic breccia developed in the structural high part and suffered a long-term leaching effect. The original pore-fracture combination also made

  15. Alberca De Guadalupe Maar Crater, Zacapu Basin : A Rare Type of Volcano within the Michoacán-Guanajuato Volcanic Field, México (United States)

    Kshirsagar, P. V.; Siebe, C.; Guilbaud, M. N.; Salinas, S.


    Phreato-magmatic vents (esp. maar craters) are rare in the ~40,000 Km2 Plio-Quaternary monogenetic Michoacán-Guanajuato Volcanic Field (MGVF) located in the central part of the Mexican Volcanic Belt. In contrast to >1000 scoria cones, only 2 dozen phreato-magmatic monogenetic vents (e.g. tuff cones, tuff rings, and maars) have been identified. About half of these form a cluster near Valle de Santiago in the Lerma river valley at the northern margin of the MGVF, while the others occur in a rather scattered fashion. Here we discuss the origin of Alberca de Guadalupe maar crater, one of the three phreato-magmatic vents (in addition to El Caracol and Alberca de Los Espinos) that occur within the boundaries of the inter-montane lacustrine Zacapu basin, a tectonic graben bound by an ENE-WSW normal fault system. The maar crater came into existence between 20,000 and 23,000 y BP, forming a 140 m deep hole in the otherwise planar surrounding ground of theearly Pleistocene lava flows of Cerro Pelón.The maar crater has a diameter of ~1 Km and bears a 9 m deep lake. Eruptive products include typical surge deposits that are best exposed around the rim and inner crater walls. They are poorly sorted (Mdø= -1.56 to -3.75, ø= 1.43 to 3.23), rich in accidental lithics (angular andesitic lava and ignimbrite clasts) constituting 51-88% of the deposit with few juveniles (basaltic andesite with phenocrysts of plagioclase, olivine, and pyroxene in a quenched glassy matrix; SiO2=54-58 wt. %). Dry surge units are friable and clast-supported, in contrast the wet surge units are fairly indurated and bear accretionary lapilli. Bedding is frequently distorted by ballistic impact-sag structures. The entire construct is disrupted by an E-W trending regional fault, downthrowing the northern part by ~30 m.The unusual formation of this maar crater in the semi-arid highlands of Zacapu was favored by the local hydrological and topographical conditions. Such conditions still prevail in several

  16. Late Pleistocene Alberca de Guadalupe maar volcano (Zacapu basin, Michoacán): Stratigraphy, tectonic setting, and paleo-hydrogeological environment (United States)

    Kshirsagar, Pooja; Siebe, Claus; Guilbaud, Marie Noëlle; Salinas, Sergio; Layer, Paul W.


    The Late Pleistocene ( 21,000 yr BP) Alberca de Guadalupe maar is one of the few phreatomagmatic volcanoes occurring within the scoria-cone dominated Plio-Quaternary Michoacán-Guanajuato Volcanic Field. The scarcity of this type of volcano implies that conditions favoring their formation are rarely met in this region. We identify these factors by implementing current methods of investigation with emphasis on hydrogeological conditions. We present the stratigraphy (including a set of 40Ar/39Ar and 14C dates) of the SE margin of the Zacapu intermontane tectonic basin, where the maar just forms a hole ( 1 km in diameter, 150 m deep, bearing a 9 m deep lake) in the otherwise planar topography of the underlying early Pleistocene lava flows of the Cerro Pelón scoria cone. The maar is composed of typical phreatomagmatic surge deposits that are poorly sorted and rich in accidental lithics (> 60 wt.% of the deposit) with few juveniles (basaltic andesite, SiO2 = 54-58 wt.%). The entire structure is cut by an ENE-WSW trending normal fault and is underlain by andesite lavas and silicic ignimbrites (partly inferred from xenoliths encountered in the maar deposits) that are Miocene to Early Pleistocene in age. The crater is at the center of a N-S elongated drainage basin surrounded by topographic highlands that channel water with high hydraulic pressure from most directions towards the location of the maar. This geometric configuration was already in existence at the time of the maar-forming eruption, but the climate was different. Colder and more humid conditions during the Last Glacial Maximum (Cw2-climate type, annual precipitation of > 1000 mm) favored the saturation of the fractured shallow aquifer system (hydraulic conductivity of 10- 8 to 10- 7 m/s) that supplied sufficient groundwater at a high flow rate directed towards the center of the basin. Upon contact near surface ( 150 m deep crater with steep inner walls and an underlying shallow diatreme (< 300 m). Since then

  17. The origin of high-Mg magmas in Mt Shasta and Medicine Lake volcanoes, Cascade Arc (California): higher and lower than mantle oxygen isotope signatures attributed to current and past subduction (United States)

    Martin, E.; Bindeman, I.; Grove, T. L.


    We report the oxygen isotope composition of olivine and orthopyroxene phenocrysts in lavas from the main magma types at Mt Shasta and Medicine Lake Volcanoes: primitive high-alumina olivine tholeiite (HAOT), basaltic andesites (BA), primitive magnesian andesites (PMA), and dacites. The most primitive HAOT (MgO > 9 wt%) from Mt. Shasta has olivine δ18O (δ18OOl) values of 5.9-6.1‰, which are about 1‰ higher than those observed in olivine from normal mantle-derived magmas. In contrast, HAOT lavas from Medicine Lake have δ18OOl values ranging from 4.7 to 5.5‰, which are similar to or lower than values for olivine in equilibrium with mantle-derived magmas. Other magma types from both volcanoes show intermediate δ18OOl values. The oxygen isotope composition of the most magnesian lavas cannot be explained by crustal contamination and the trace element composition of olivine phenocrysts precludes a pyroxenitic mantle source. Therefore, the high and variable δ18OOl signature of the most magnesian samples studied (HAOT and BA) comes from the peridotitic mantle wedge itself. As HAOT magma is generated by anhydrous adiabatic partial melting of the shallow mantle, its 1.4‰ range in δ18OOl reflects a heterogeneous composition of the shallow mantle source that has been influenced by subduction fluids and/or melts sometime in the past. Magmas generated in the mantle wedge by flux melting due to modern subduction fluids, as exemplified by BA and probably PMA, display more homogeneous composition with only 0.5‰ variation. The high-δ18O values observed in magnesian lavas, and principally in the HAOT, are difficult to explain by a single-stage flux-melting process in the mantle wedge above the modern subduction zone and require a mantle source enriched in 18O. It is here explained by flow of older, pre-enriched portions of the mantle through the slab window beneath the South Cascades.

  18. The application of near-infared spectral data in studying the chloritized rocks (United States)

    Yang, Min; Yang, Junlu; Ren, Guangli; Li, Jianqiang; Gao, Ting; Yi, Huan; Han, Haihui; Zhang, Zhuan; Nan, Liang


    Chlorite minerals present in altered rocks could characterised by field portable near-infrared spectroscopy. It is a kind of low-temperature altered mineral that cristal at between 100 to 400 degree centigrade. Six kinds of major alteration rocks, andesite, dacite, sillite, granite, sandstone and phyllite are shown the spectruml characteristic of chlorite. The characteristic absorption bands of chlorite are always due to OH stretch absorption and metal-OH bend absorption, but different lithology behaves different wavelengths of the absorption bands espetially for basic rocks, intermediate rocks and acid rocks. This behavior could help geologists to study the lithology and diagenetic environment. The diagnostic absorption bands of chlorite are appear at wavelengths between 2249nm and 2260nm, it dues to Fe-OH absorption and called Fe-OH band; and another important absorption band between 2335nm to 2355nm, it is caused by Mg-OH absorption and named Mg-OH band. Fe-OH band and Mg-OH band are always existence proof of chlorite. Basic rocks such as andesite and sillite, their Fe-OH bands are occured at wavelength between 2256nm and 2260nm; Mg-OH bands are located at wavelength between 2338nm to 2339nm. Intermediate rocks such as dacite and sandstone, their Fe-OH bands are appeared at wavelength between 2253nm and 2256nm; Mg-OH bands are shown at between 2237nm and 2251nm. Acid rocks such as granite and phyllite, their Fe-OH bands are shown at wavelength between 2249nm and 2252nm; Mg-OH bands are occurred at wavelength between 2340nm and 2351nm. Contrast with X-Ray Fluorescence Spectrometer measurement, the wavelength of the Fe-OH band correlates positively with the (FeO+Fe2O3) values. It varies from Mg-rich to Fe-rich varieties, and it can help us to analysis the diagenetic environment, and it could also distinguish basic rocks, intermediate rocks and acid rocks that be rich in chlorite.

  19. The eruptive history and volcanic hazards of Savo, Solomon Islands (United States)

    Petterson, M. G.; Cronin, S. J.; Taylor, P. W.; Tolia, D.; Papabatu, A.; Toba, T.; Qopoto, C.


    Savo Island is the 6-km-diameter emergent summit of an andesitic-dacitic stratovolcano, rising from the Iron Bottom Sound, 35 km NW of Honiara, Solomon Islands. Savo has erupted at least three times within recorded history and the 3,000 inhabitants maintain extensive oral traditions of past events. Through description and interpretation of the volcaniclastic sequences on the island, in conjunction with historical accounts and oral traditions, we reconstruct the eruptive processes on Savo. Block-and-ash flow (BAF) deposits are volumetrically dominant on the island within three main depositional environments: near-vent sequences, thick medial channel sequences and distal fan sequences. The deposits comprise universally non-vesicular and highly porphyritic (40-70% phenocrysts), high-silica andesite and dacite clasts. These appear to have been derived from collapsing lava domes during an 1560-1570 A.D. eruption. However, eyewitness descriptions and crater morphology suggest that similar deposits formed from dome explosions or collapses of eruption columns during later eruptions (1830-1840 A.D.). The high-sodium magmas (ca. 5-7 wt% Na2O) apparently crystallised and strongly degassed prior to eruption. Shallow explosions were possibly caused by entrapment of magmatic gases beneath a dome or conduit plug of highly crystalline, near solid magma. Repeated sealing of the vent may have been due to inward collapse of the highly altered rocks of the surrounding hydrothermal system; these rocks probably were saturated due to contemporaneous high intensity rainfall events. BAFs were hot enough to char vegetation and attain aligned clast TRM (thermal remnant magnetism) up to 3 km from the vent, many being accompanied by ash-cloud surges. Changes with distance in the BAF deposits appear mostly dependent on flow confinement and are limited to an overall decrease in thickness and maximum clast size, and an increased definition of weak planar fabrics. In distal fan sequences, there is

  20. Geology of the south-central part of the New River Mesa Quadrangle, Cave Creek area, Maricopa County, Arizona (United States)

    Gomez, Ernest


    A small area north of Cave Creek, Arizona, contains key stratigraphic and structural information bearing on the Cenozoic development of the mountain and desert regions of Arizona. The area contains elements of the two physiographic regions. The northern and western parts are high mesas containing flat lying interbedded Tertiary volcanic and sedimentary strata. These deposits can be traced southward across the physiographic boundary where they are tilted and down faulted into the desert region. Seven bedrock units were revealed by geologic mapping at 1:12,000 scale. They are, in ascending stratigraphic order: (1) a basement of Precambrian schist, granitic rock, and diabase (300 meters exposed), (2) fanglomerate derived from the crystalline rocks, of probable early and middle Oligocene age (0-152 m thick), (3) andesite of possible middle Oligocene age (225 m thick), (4) interbedded sediments and volcanics of Oligocene and Miocene age (30-320 m thick), and (5) resistant cliff forming basalt flows of middle Miocene age (125-180 m thick) that cap the high mesas. Regional uplift of an exposed Precambrian terrane occurred ~38-30 m.y. ago, accompanied by erosion of the basement and deposition of fanglomerate. Regional volcanism began ~30 m.y. ago, apparently with the extrusion of andesite, followed by deposition of alkali basaltic flows, tuff, lake beds, and alluvium in one or more irregularly closed basins, formed as a result of faulting and volcanism. A transition from calcalkali and alkali volcanism to olivine basalt volcanism of the Hickey Formation occurred approximately IS m.y. ago. The interval 14.5-11 m.y. saw the deposition of olivine basalt flows of the New River Mesa formation, which cap the high mesas and correlate with basalt of the Hickey Formation. Topographic development of the mountain-desert region boundary occurred with collapse of the basalts of the New River Mesa formation into the desert region. This may have occurred at the time of initial subsidence

  1. Tectonic evolution of the central-eastern sector of Trans Mexican Volcanic Belt and its influence on the eruptive history of the Nevado de Toluca volcano (Mexico) (United States)

    Bellotti, F.; Capra, L.; Groppelli, G.; Norini, G.


    The Nevado de Toluca is an andesitic to dacitic stratovolcano of Late Pliocene-Holocene age located within the central and eastern sectors of the Trans Mexican Volcanic Belt. Morphostructural analysis, aerial photograph and satellite image interpretation, structural analysis and geological fieldwork were methods used to investigate the relationship between the evolution of the volcano and the tectonic framework of its basement. The study revealed that the area of Nevado de Toluca is affected by three main fault systems that intersect close to the volcanic edifice. These are from oldest to youngest, the Taxco-Querétaro, San Antonio and Tenango fault systems. The NNW-SSE Taxco-Querétaro fault system was active in the area since Early Miocene, and is characterized by right-lateral transtensive movement. Its reactivation during Early to Middle Pleistocene was responsible for the emplacement of andesitic to dacitic lava flows and domes of La Cieneguilla Supersynthem. The NE-SW San Antonio fault system was active during Late Pliocene, before the reactivation of the Taxco-Querétaro fault system, and is characterized by extensional left-lateral oblique-slip kinematics. The youngest is the E-W Tenango fault system that has been active since Late Pleistocene. This fault system is characterized by transtensive left-lateral strike-slip movement, and partly coeval with the youngest eruptive phase, the Nevado Supersynthem, which formed the present summit cone of the Nevado de Toluca volcano. The stress re-orientation from the Taxco-Querétaro to the Tenango fault system during Late Pleistocene is responsible for the ˜ 1 Ma hiatus in the magmatic activity between 1.15 Ma and 42 ka. After this period of repose, the eruptive style drastically changed from effusive to explosive with the emission of dacitic products. The methodology presented here furnish new data that can be used to better assess the complex structural evolution of this sector of the Trans Mexican Volcanic Belt

  2. El Estribo Volcanic Complex: Evolution from a shield volcano to a cinder cone, Pátzcuaro Lake, Michoacán, México (United States)

    Pola, A.; Macías, J. L.; Osorio-Ocampo, S.; Sosa-Ceballos, G.; Garduño-Monroy, V. H.; Martínez-Martínez, J.


    El Estribo Volcanic Complex (EVC) is located in the northern part of the Michoacán-Guanajuato Volcanic Field within the Trans-Mexican Volcanic Belt (TMVB). El Estribo is located at the southern edge of the E-W Pátzcuaro fault that belongs to the Pátzcuaro-Jarácuaro graben, a western extension of the E-W Morelia-Acambay fault system. Stratigraphy, geochronology, chemistry, and mineral assemblages suggest that the volcanic complex was constructed in two periods separated by a ~ 100 ka volcanic hiatus: a) emission of lava flows that constructed a shield volcano between 126 ka, and b) mixed phreatomagmatic to Strombolian activity that formed a cinder cone ~ 28 ka. The magmas that fed these monogenetic volcanoes were able to use the same feeding system. The cinder cone itself was constructed by Strombolian fallouts and remobilized scoria beds, followed by an erosion period, and by a mixed phreatomagmatic to magmatic phase (Strombolian fallouts ending with lava flows). Soft-sedimentary deformation of beds and impact sags, cross-bedding, as well as pitting and hydrothermal cracks found in particles support the phreatomagmatic phase. The erupted magmas through time ejected basaltic andesitic lava flows (56.21-58.88% SiO2) that built the shield volcano and then basaltic andesitic scoria (57.65-59.05% SiO2) that constructed the cinder cone. Although they used the same feeding system, the geochemical data and the mineral chemistry of the magmas indicate that the shield volcano and the cinder cone were fed by different magma batches erupted thousands of years apart. Therefore, the location of El Estribo Volcanic Complex along an E-W fault that has generated two sector collapses of the shield volcano to the north may be directly linked to this complex redistribution of the magmatic paths to the surface. Our findings show that magmatic feeding systems within monogenetic volcanic fields could be long lived, questioning the classic view of the monogenetic nature of their

  3. Physical volcanology, geochemistry and basin evolution of the Ediacaran volcano-sedimentary succession in the Bas Draâ inlier (Ouarzazate Supergroup, Western Anti-Atlas, Morocco) (United States)

    Karaoui, Brahim; Breitkreuz, Christoph; Mahmoudi, Abdelkader; Youbi, Nasrrddine


    New geologic mapping, lithofacies and granulometric analysis, and geochemistry from the volcano-sedimentary successions of the central part of the Bas Draâ inlier, Western Anti-Atlas, constrain the Ediacaran Ouarzazate Supergroup evolution during the post-collisional stage of the Pan-African orogeny. Volcanosedimentary facies analysis is the key aspect of the present contribution. We distinguished sixteen terrestrial volcanosedimentary lithofacies in the Bas Draâ succession (BDS), which reaches a total thickness of 2000 m. BDS evolution can be grouped into four units (Aouinet Aït Oussa I to IV, AO I-AO IV). The earliest volcanic activity produced rhyolitic ignimbrite sheets (AO I), which had been considered as lava flows by previous workers, and which were presumably related to caldera system(s). During AO II, a complex of high-silica andesitic and rhyolitic lavas formed, punctuated by the explosive eruption of a high-temperature silica-rich magma leading to the formation of parataxitic ignimbrite. AO III consists of basalt and andesite lava fields and small explosive, in parts phreatomagmatic volcanic vents. It is dissected by fluvial systems depositing external non-volcanic and local volcanic debris. BDS evolution terminated with the formation of a large SiO2-rich lava dome complex (AO IV), accompanied by small basalt effusive event. Volcanosedimentary facies analysis infers that the BDS evolved in a continental extensional setting developing in a low topography under humid paleoclimatic conditions. Alteration textures are dominated by a piemontite-calcite-albite-quartz (+ iron oxides) assemblage. Chemical analysis of BDS volcanic and subvolcanic rocks belongs to high-k calc-alkaline and alkali-calcic to alkaline magmatic trend typical for a post-collision setting. Trace elements spidergrams show a pattern typical for subduction-related suites of orogenic belts. REE patterns show moderate enrichment in LREE relative to flat HREE, with strong negative Eu

  4. Origin Of Black Shale (Marl) Formation Aided By Continuous Volcanism For 10Ma Including Oceanic Anoxic Event, OAE2 (93-93.5 Ma) In The Eagle Ford Formation In South Texas (United States)

    Chakrabarty, P.; Basu, A. R.


    We report LA-ICPMS U-Pb ages and Hf isotopes of zircons, petrography, major and trace elements and X-ray diffraction (XRD) analyses of whole rock black shales(marls) from volcanic subsurface as well as surface exposure ash beds of the Eagle Ford and Boquillas Formations in South Texas. Zircons from the middle part of the 300ft long Eagle Ford cores yield ages of 93.2±1.66 Ma, 94.13±1.25 Ma and 93.7±1.9 Ma. These ages are consistent with the Cenomanian-Turonian (C-T) age of deposition in three contiguous cores with spatial separation of 140 miles. An approximate 10Ma duration of deposition of volcanic ash and marl, at a rate of 28ft/Ma for the Eagle Ford is suggested from the 85.76 to 95.5 Ma ages. These ages are from the Eagle Ford ash beds, below the Austin Chalk and above the Buda Limestone and cover the Oceanic Anoxic Event 2 at the C-T boundary. Zircons from 7 ash beds in the surface exposures of the Boquillas Formation near Del Rio, yield ages between 84.63 Ma - 90.91 Ma, implying younger than C-T boundary ages for these samples. The mineralogy, major and trace elements of the ash beds suggest their source from nearby arc-derived calc-alkaline volcanism. The ɛHf(T) of the analyzed ash bed zircons yield values between 0 - +8 averaging at +3.5, clearly indicating a mantle component in the host magmas of the zircons. This initial range of ɛHf(T) is similar to arc-volcanism signatures such as the Quaternary andesitic volcanism in Central Mexico. Petrographic analyses of marls away from the visible tuff layer contain phenocrysts of biotite, alkali feldspar and andesitic rock fragments. The whole rock marl with high concentration of some transition metals (V, Zn, Ni, Pb, Mo) and relatively higher MgO and TiO2 contents indicate contemporaneous arc volcanic activity at the time of marl deposition. XRD of subsurface Eagle Ford bulk marl samples from different depths in 4 cores, show volcanogenic clays, such as montmorillonite, vermiculite, dickite and halloysite

  5. Intrusive hyaloclastite and peperitic breccias associated to sill and cryptodome emplacement on an Early Paleocene polymagmatic compound cone-dome volcanic complex from El Guanaco mine, Northern Chile (United States)

    Páez, G. N.; Permuy Vidal, C.; Galina, M.; López, L.; Jovic, S. M.; Guido, D. M.


    This work explores the textural characteristics, morphology and facies architecture of well-preserved Paleocene hyaloclastic and peperitic breccias associated with subvolcanic intrusions at El Guanaco gold mine (Northern Chile). The El Guanaco mine volcanic sequence is part of a polymagmatic compound cone-dome volcanic complex grouping several dacitic domes and maar-diatremes, and subordinated subvolcanic intrusions of basaltic, andesitic and dacitic compositions. The Soledad-Peñafiel Fault System is a first order regional structure controlling the location and style of the volcanism in the region. Three different intrusive bodies (Basaltic sills, Dacitic cryptodomes and Andesitic cryptodomes) were found to intrude into a wet and poorly consolidated pyroclastic sequence representing the upper portions of a maar-diatreme. Consequently, extensive quench fragmentation and fluidization along their contacts occurred, leading to the formation of widespread breccia bodies enclosing a coherent nucleus. Differences in matrix composition allows to define two main breccias types: 1) poorly-sorted monomictic breccias (intrusive hyaloclastites) and 2) poorly-sorted tuff-matrix breccias (peperites). The observed facies architecture is interpreted as the result of the interplay of several factors, including: 1) magma viscosity, 2) the geometry of the intrusives, and 3) variations on the consolidation degree of the host rocks. Additionally, the overall geometry of each intrusive is interpreted to be controlled by the effective viscosity of the magmas along with the available magma volume at the time of the intrusions. The presence of three compositionally different subvolcanic bodies with intrusive hyaloclastite and peperite envelopes indicate, not only that all these intrusions occurred in a short period of time (probably less than 2-3 Ma), but also that the volcaniciclastic pile suffer little or none compaction nor consolidation during that time. The presence of three

  6. Performance and safety assessment of the co-location of the near surface radioactive waste disposal facilities and borehole disposal concept in the Philippines

    International Nuclear Information System (INIS)

    Vargas, Edmundo; Reyes, Rolando; Palattao, Maria Visitacion; Nohay, Carl; Singayan, Alfonso; Aurelio, Mario; Gedeon, Matej; Luna, Roy Anthony C.


    The Philippine Nuclear Research Institute (PNRI) in collaboration with the interagency technical committee on radioactive waste has been undertaking a national project to find a final solution to the country's low to intermediate level radioactive waste. The strategy adopted was to co-locate 2 disposal concepts that will address the types of radioactive waste generated from the use of radioactive materials. This strategy is expected to compensate for the small volumes of waste generated in the Philippines as compared to countries with big nuclear energy programs. It will also take advantage of the benefits of a shared infrastructure and R and D work that accompany such project. The preferred site selected from previous site selection and investigations is underlain by highly fractured 'andesitic volcaniclastics' mantled by residual clayey soil which act as the aquifer or water bearing layer. Results of investigation show that the groundwater in the area is relatively dilute and acidic. Springs at the lower elevations of the footprint also indicate acidic waters. The relatively acidic water is attributed to the formation of sulfuric acid by the oxidation of the pyrite in the andesite. A preliminary post closure safety assessment was carried out using the GMS MODFLOW and HYDRUS softwares purchased through the International Atomic Energy Agency (IAEA) technical assistance. Results from MODFLOW modeling show that the radionuclide transport follows the natural gradient from the top of the hill down to the natural discharge zones. The vault dispersion model shows a circular direction from the vaults towards the faults and eventually to the creeks. The contaminant transport from borehole shows at least one confined plume from the borehole towards the creek designated as Repo1 and eventually follows downstream. The influx of surface water and rainfall to the disposal vault was modeled using the HYDRUS software. The pressure head and water content at the base

  7. Paleomagnetism of Late Paleozoic and Mesozoic volcanic rocks of Southern Siberia (United States)

    Fedyukin, I.; Shatsillo, A.


    The main objects of the present study are late Permian and Mesozoic volcanic rocks from Selengin-Vitim volcano-plutonic belt (South Siberia). The belt was formed in the back area of Siberian continent active margin. Volcanic rocks are presented by contrastive volcanites more than 5 km thick. The deposits are subdivided into three suits: Ungurkuy (basalts and andesites), Chernoyar (basalts, andesites and tuffs) and Hilok (basalts, pyroclastic flows and tuffs). The age of Ungurkuy suite is deemed to be between Late Carboniferous and Late Permian. The age of Chernoyar suite is Middle-late Triassic. The age og Hilok suite is Late Jurassic. Volcanic deposits of the three suits were studied to create APWP for the Siberian craton. 250 oriented samples from 40 sites were collected from the Chikoy river valley within South Siberia. All samples were characterized by interpretable paleomagnetic signal. The Ungurkuy suite has different dip and strike: from subhorizontal to 40 degrees inclination and NE course. Chernoyar rocks were collected from monoclinal structure with the dip and strike around NW declination and 5-10 degrees inclination. Hilok suite represents large subhorizontal eruptive bodies. Volcanic rocks of Ungurkuy suite show mostly monopolar (normal polarity) magnetization direction between Early Permian and Permian-Triassic Siberian poles, which indicates its Late Permian age. The normal polarity of the deposits indicates its formation in the period between Kiama superchron, characterized by reversal polarity, and Illavara hyperchron with mixed polarity - 265 Ma. Direction from Chernoyar suite is well-correlated with Late Triassic APWP of Europe, directions of magnetization are bipolar. From Hilok suite several sites show direction of magnetization similar to directions revealed from Early Cretaceous volcanites from nearby area. The magnetization is metachronous. In the other sites the directions of magnetization well-correlated with Late Jurassic APWP of Europe

  8. Gabbroic and Peridotitic Enclaves from the 2008 Kasatochi Eruption, Aleutian Islands, Alaska (United States)

    Kentner, A.; Nadin, E. S.; Izbekov, P. E.; Nye, C. J.; Neill, O. K.


    Kasatochi volcano of the Andreanof Islands in the western Aleutian Arc violently erupted over a two day period from August 7-8, 2008. The eruption involved multiple explosive events generating pyroclastic flows, which included abundant mafic and ultramafic enclaves that have since weathered out and accumulated in talus along the coast. These and other mafic enclaves sampled by modern island arc lavas provide insight into subduction magmatism because they emerge from a section of the subduction system that is less likely than shallower zones to be modified by magmatic processes such as mixing, assimilation, or fractionation. We present new whole rock, clinopyroxene, amphibole, plagioclase, and melt compositions from Kasatochi enclaves of the 2008 eruption. The highly crystalline (~40 vol. % phenocryst content), medium-K basaltic andesite host rock contains ~52-55 wt. % SiO2 and 0.6-0.9 wt. % K2O, and is composed of plagioclase, ortho- and clinopyroxene, amphibole, and Ti-magnetite in a microlite-rich groundmass. Upon eruption, this magma sampled two distinct enclave populations: gabbro and peridotite. The gabbro has abundant amphibole (mostly magnesio-hastingsite) and plagioclase with minor clinopyroxene, olivine, and magnetite, while the peridotite is composed of olivine with minor amounts of clinopyroxene and orthopyroxene. There is little textural variation amongst the peridotitic samples collected, but the gabbroic samples vary from layered to massive and cover a range in grain size from fine-grained to pegmatitic. The layered gabbros display centimeter-scale bands of alternating plagioclase- and amphibole-rich layers, with a strong preferential alignment of the amphibole grains. The coarser-grained samples are very friable, with ~10% pore space; disaggregation of these upon host-magma ascent likely formed the amphibole and plagioclase xenocrysts in the andesitic host. Based on the textural and compositional differences, we divide the enclaves into four groups

  9. The A.D. 1835 eruption of Volcán Cosigüina, Nicaragua: A guide for assessing local volcanic hazards (United States)

    Scott, William E.; Gardner, Cynthia A.; Devoli, Graziella; Alvarez, Antonio


    The January 1835 eruption of Volcán Cosigüina in northwestern Nicaragua was one of the largest and most explosive in Central America since Spanish colonization. We report on the results of reconnaissance stratigraphic studies and laboratory work aimed at better defining the distribution and character of deposits emplaced by the eruption as a means of developing a preliminary hazards assessment for future eruptions. On the lower flanks of the volcano, a basal tephra-fall deposit comprises either ash and fine lithic lapilli or, locally, dacitic pumice. An overlying tephra-fall deposit forms an extensive blanket of brown to gray andesitic scoria that is 35–60 cm thick at 5–10 km from the summit-caldera rim, except southwest of the volcano, where it is considerably thinner. The scoria fall produced the most voluminous deposit of the eruption and underlies pyroclastic-surge and -flow deposits that chiefly comprise gray andesitic scoria. In northern and southeastern sectors of the volcano, these flowage deposits form broad fans and valley fills that locally reach the Gulf of Fonseca. An arcuate ridge 2 km west of the caldera rim and a low ridge east of the caldera deflected pyroclastic flows northward and southeastward. Pyroclastic flows did not reach the lower west and southwest flanks, which instead received thick, fine-grained, accretionary-lapilli–rich ashfall deposits that probably derived chiefly from ash clouds elutriated from pyroclastic flows. We estimate the total bulk volume of erupted deposits to be ∼6 km3. Following the eruption, lahars inundated large portions of the lower flanks, and erosion of deposits and creation of new channels triggered rapid alluviation. Pre-1835 eruptions are poorly dated; however, scoria-fall, pyroclastic-flow, and lahar deposits record a penultimate eruption of smaller magnitude than that of 1835. It occurred a few centuries earlier—perhaps in the fifteenth century. An undated sequence of thick tephra-fall deposits on

  10. Incipient boninitic arc crust built on denudated mantle: the Khantaishir ophiolite (western Mongolia) (United States)

    Gianola, Omar; Schmidt, Max W.; Jagoutz, Oliver; Sambuu, Oyungerel


    The 570 Ma old Khantaishir ophiolite is built by up to 4 km harzburgitic mantle with abundant pyroxenites and dunites followed by 2 km of hornblende-gabbros and gabbronorites and by a 2.5 km thick volcanic unit composed of a dyke + sill complex capped by pillow lavas and some volcanoclastics. The volcanics are mainly basaltic andesites and andesites (or boninites) with an average of 58.2 ± 1.0 wt% SiO2, X Mg = 0.61 ± 0.03 ( X Mg = molar MgO/(MgO + FeOtot), TiO2 = 0.4 ± 0.1 wt% and CaO = 7.5 ± 0.6 wt% (errors as 2 σ). Normalized trace element patterns show positive anomalies for Pb and Sr, a negative Nb-anomaly, large ion lithophile elements (LILE) concentrations between N- and E-MORB and distinctly depleted HREE. These characteristics indicate that the Khantaishir volcanics were derived from a refractory mantle source modified by a moderate slab-component, similar to boninites erupted along the Izu-Bonin-Mariana subduction system and to the Troodos and Betts Cove ophiolites. Most strikingly and despite almost complete outcrops over 260 km2, there is no remnant of any pre-existing MORB crust, suggesting that the magmatic suite of this ophiolite formed on completely denudated mantle, most likely upon subduction initiation. The architecture of this 4-5 km thick early arc crust resembles oceanic crust formed at mid ocean ridges, but lacks a sheeted dyke complex; volcanic edifices are not observed. Nevertheless, low melting pressures combined with moderate H2O-contents resulted in high-Si primitive melts, in abundant hornblende-gabbros and in a fast enrichment in bulk SiO2. Fractional crystallization modeling starting from the observed primitive melts (56.6 wt% SiO2) suggests that 25 wt% pyroxene + plagioclase fractionation is sufficient to form the average Khantaishir volcanic crust. Most of the fractionation happened in the mantle, the observed pyroxenite lenses and layers in and at the top of the harzburgites account for the required cumulate volumes. Finally

  11. Geology, petrology and geochemistry of the dome complex of Huequi volcano, southern Chile Geología, petrología y geoquímica de los domos volcánicos del volcán Huequi, Chile meridional

    Directory of Open Access Journals (Sweden)

    Sebastian F.L Watt


    Full Text Available Huequi, a little-known volcano in the southern part of the Andean southern volcanic zone (SSVZ, shows a regionally unusual eruption style, mineralogy and geochemistry. The volcano comprises multiple highly-eroded lava domes. Past eruptions were accompanied by relatively minor explosive activity, most recently from 1890-1920. The rocks erupted by Huequi range from basaltic andesite to dacite, and are highly distinctive when compared to other volcanoes of the SSVZ, being K-poor and Al-rich, and containing euhedral hornblende phenocrysts. Overall compositions suggest a notably water-rich magma source, evolving through high levels of fractionation and subsequent degassing to produce highly porphyritic dome-forming andesites. The ultimate causes of water-rich magmas at this point in the arc remain unclear.El volcán Huequi es poco conocido, que se ubica en la provincia sur de la zona Volcánica Sur de los Andes (ZVSS. Sus tipos de erupción y características mineralógicas y geoquímicas son poco comunes a nivel regional. El volcán presenta múltiples domos poco erosionados. Las erupciones estuvieron acompañadas por una actividad explosiva secundaria, siendo las más recientes las ocurridas entre los años 1890 y 1920. Los magmas del Huequi son de composición andesítico-basáltica a dacítica. Si se las compara con rocas eruptadas por otros centros volcánicos de la ZVSS de los Andes, las del Huequi se caracterizan por ser pobres en K, ricas en Al y por presentar fenocristales euhedrales de anfíbola. Las composiciones totales sugieren una fuente magmática rica en H2O, que se desarrolla a través de niveles de cristalización fraccionada y desgasificación subsecuente, que producen domos volcánicos andesíticos altamente porfíricos. Sin embargo, la causa última que genera magmas ricos en H2O, en esta parte de los Andes, sigue aún sin explicación.

  12. Morphometric study of pillow-size spectrum among pillow lavas (United States)

    Walker, George P. L.


    Measurements of H and V (dimensions in the horizontal and vertical directions of pillows exposed in vertical cross-section) were made on 19 pillow lavas from the Azores, Cyprus, Iceland, New Zealand, Tasmania, the western USA and Wales. The median values of H and V plot on a straight line that defines a spectrum of pillow sizes, having linear dimensions five times greater at one end than at the other, basaltic toward the small-size end and andesitic toward the large-size end. The pillow median size is interpreted to reflect a control exercised by lava viscosity. Pillows erupted on a steep flow-foot slope in lava deltas can, however, have a significantly smaller size than pillows in tabular pillowed flows (inferred to have been erupted on a small depositonal slope), indicating that the slope angle also exercised a control. Pipe vesicles, generally abundant in the tabular pillowed flows and absent from the flow-foot pillows, have potential as a paleoslope indicator. Pillows toward the small-size end of the spectrum are smooth-surfaced and grew mainly by stretching of their skin, whereas disruption of the skin and spreading were important toward the large-size end. Disruption involved increasing skin thicknesses with increasing pillow size, and pillows toward the large-size end are more analogous with toothpaste lava than with pahoehoe and are inferred from their thick multiple selvages to have taken hours to grow. Pseudo-pillow structure is also locally developed. An example of endogenous pillow-lava growth, that formed intrusive pillows between ‘normal’ pillows, is described from Sicily. Isolated pillow-like bodies in certain andesitic breccias described from Iceland were previously interpreted to be pillows but have anomalously small sizes for their compositions; it is now proposed that they may lack an essential attribute of pillows, namely, the development of bulbous forms by the inflation of a chilled skin, and are hence not true pillows. Para-pillow lava is

  13. Origin of the ca. 50 Ma Linzizong shoshonitic volcanic rocks in the eastern Gangdese arc, southern Tibet (United States)

    Liu, An-Lin; Wang, Qing; Zhu, Di-Cheng; Zhao, Zhi-Dan; Liu, Sheng-Ao; Wang, Rui; Dai, Jin-Gen; Zheng, Yuan-Chuan; Zhang, Liang-Liang


    The origin of the Eocene shoshonitic rocks within the upper part of the extensive Linzizong volcanic succession (i.e., the Pana Formation) in the Gangdese arc, southern Tibet remains unclear, inhibiting the detailed investigations on the crust-mantle interaction and mantle dynamics that operate the generation of the coeval magmatic flare-up in the arc. We report mineral composition, zircon U-Pb age and zircon Hf isotope, whole-rock element and Sr-Nd-Hf isotope data for the Pana Formation volcanic rocks from Pangduo, eastern Gangdese arc in southern Tibet. The Pana volcanic rocks from Pangduo include basalts, basaltic andesites, and dacites. SIMS and LA-ICPMS zircon U-Pb dating indicates that the Pangduo dacites were erupted at 50 ± 1 Ma, representing the volcanic equivalent of the coeval Gangdese Batholith that define a magmatic flare-up at 51 ± 1 Ma. The Pangduo volcanic rocks are exclusively shoshonitic, differing from typical subduction-related calc-alkaline volcanic rocks. The basalts have positive whole-rock ƐNd(t) (+1.7) and ƐHf(t) (+3.8) with high Zr abundances (121-169 ppm) and Zr/Y ratios (4.3-5.2), most likely derived from the partial melting of an enriched garnet-bearing lithospheric mantle that was metasomatized by subduction-related components with input from asthenosphere. Compared to the basalts, similar trace elemental patterns and decreased whole-rock ƐNd(t) (-3.5 to -3.3) and ƐHf(t) (-2.5 to -1.6) of the basaltic andesites can be attributed to the input of the ancient basement-derived material of the central Lhasa subterrane into the basaltic magmas. The coherent whole-rock Sr-Nd-Hf isotopic compositions ((87Sr/86Sr)i = 0.7064-0.7069, ƐNd(t) = -6.0 to -5.2, ƐHf(t) = -5.6 to -5.0) and varying zircon ƐHf(t) (-6.0 to +4.1) of the dacites can be interpreted by the partial melting of a hybrid lower crust source (juvenile and ancient lower crust) with incorporation of basement-derived components. Calculations of zircon-Ti temperature and whole

  14. Eruption History and Geochemical Evolution of Servilleta Basalt Along the Rio Grande Gorge, Colorado and New Mexico (United States)

    Cosca, M. A.; Thompson, R. A.; Turner, K. J.; Morgan, L. E.


    Subalkaline basalt to basaltic andesite lava flows formally known as Servilleta Basalt (SB) are the most voluminous rock type forming the Pliocene Taos Plateau volcanic field. Pleistocene incision by the Rio Grande into the bedrock-floored plateau has resulted in spectacular exposures of occasionally thick ( 240 m) accumulations of SB within the Rio Grande gorge. Incremental CO2 laser heating of individual rock fragments, the SB within and along the length of the Rio Grande gorge has been precisely dated by 40Ar/39Ar geochronology to between 5.3 Ma and 3.3 Ma. SB older than 4 Ma is restricted to some lava flows exposed between La Junta point, at the confluence of the Red River and Rio Grande, and the Gorge Bridge crossing northwest of Taos, NM. Vertical sampling through thick SB flow sequences within the gorge yields precise emplacement histories and also reveals small but systematic major and minor element concentration variations (including Si, Rb, Sr, Cu and Zn). 40Ar/39Ar data show that these trends developed over short (0-250 ka) timescales, and probably relate to partial assimilation of crust, possibly at multiple depths. Combined field, geochemical, and 40Ar/39Ar data consequently record short-lived changes in tholeiitic melt compositions in response to regional extension and development of the Rio Grande rift. The age, lateral extent, and thickness of exposed SB partially reflect the paleotopographic surface of the southern San Luis Basin prior to onset of Pliocene Taos Plateau volcanic field magmatism; paleotopographic highs diverted some flows while topographic lows were areas of infilling and accumulation. Heterogeneous basin paleotopography developed during contemporaneous or precursory andesitic to dacitic volcanism, extensional faulting and subsidence of sub-basins within the San Luis Basin, and deposition of prograding alluvial fans that originated in the Sangre de Cristo and Picuris Mountains. SB flowed into the southern San Luis Valley beginning 5

  15. Venus surface peeking through the atmosphere - gaining a global perspective on the surface composition through near infrared observations (United States)

    Helbert, J.; Dyar, M. D.; Maturilli, A.; D'Amore, M.; Ferrari, S.; Mueller, N. T.; Smrekar, S. E.


    Venus is the most Earth-like of the terrestrial planets, though very little is known about its surface composition. Thanks to recent advances in laboratory spectroscopy and spectral analysis techniques, this is about to change. Although the atmosphere prohibits observations of the surface with traditional imaging techniques over much of the EM spectral range, five transparent windows between 0.86 µm and 1.18 µm occur in the atmosphere's CO2 spectrum. New high temperature laboratory spectra from the Planetary Spectroscopy Laboratory at DLR show that spectra in these windows are highly diagnostic for surface mineralogy [1]. The Venus Emissivity Mapper (VEM) [2] builds on these recent advances. It is proposed for NASA's Venus Origins Explorer where a radar will provided the needed high-resolution altimetry and ESA's EnVision would provide stereo topography instead. VEM is the first flight instrument specially designed to focus solely on mapping Venus' surface using the windows around 1 µm. Operating in situ from Venus orbit, VEM will provide a global map of composition as well as redox state of the surface, enabling a comprehensive picture of surface-atmosphere interaction on Venus. VEM will return a complex data set containing surface, atmospheric, cloud, and scattering information. Total planned data volume for a typical mission scenario exceeds 1TB. Classical analysis techniques have been successfully used for VIRTIS on Venus Express [3-5] and could be employed with the VEM data. However, application of machine learning approaches to this rich dataset is vastly more efficient, as has already been confirmed with laboratory data. Binary classifiers [6] demonstrate that at current best estimate errors, basalt spectra are confidently discriminated from basaltic andesites, andesites, and rhyolite/granite. Applying the approach of self-organizing maps to the increasingly large set of laboratory measurements allows searching for additional mineralogical indicators

  16. High-silica Rocks from Oceans, Arcs and Ophiolites: What Can They Tell Us About Ophiolite Origins? (United States)

    Perfit, M. R.; Lundstrom, C.; Wanless, V. D.


    Although the volumes of high-silica rocks in submarine oceanic and supra-subduction zone environments are not well constrained, their common occurrence, field relations and compositions have led to various hypotheses suggesting that silicic intrusions (plagiogranites) in ophiolites formed by similar processes to high-silica volcanic rocks at mid-ocean ridge (MOR) or island arc environments. Geochemical attributes of andesite-rhyolite suites from MOR (East Pacific Rise, Juan de Fuca Ridge, Galapagos Spreading Center, Pacific-Antarctic Rise) and back-arc basins (Manus Basin, Lau Basin, East Scotia Ridge) show both similarities and differences to plagiogranitic suites (qtz. diorite-tonalite-trondhjemite) from ophiolites (Troodos and Semail). Both suites are commonly attributed to: extreme (>90%) fractional crystallization of basaltic melts; fractional crystallization coupled with assimilation of hydrated oceanic crust (AFC); or partial melting of preexisting crust. Normalized incompatible trace element patterns show either highly elevated, relatively flat patterns with negative Eu and Sr anomalies similar to high silica volcanics or have complimentary patterns with low abundance, more depleted patterns with positive Eu and Sr anomalies. None of the mechanisms, however, provide a consistent explanation for the compositional and isotopic variations that are observed among plagiogranites. In fact, ophiolitic plagiogranites can have at least two petrogenetic signatures - one indicative of a MORB parent and another that has been related to later, off-axis formation associated with supra-subduction zone magmatism. Based on thermal gradient experiments, the systematic changes in Fe and Si stable isotope ratios with differentiation observed in ophiolite and MOR high-silica suites may result from melt-mineral reactions within a temperature gradient near the boundaries of MOR magma lenses. Comparative major element, trace element and isotopic data will be presented from MOR

  17. Structural controls and mechanisms of diffusion in natural silicate melts (United States)

    Henderson, P.; Nolan, J.; Cunningham, G. C.; Lowry, R. K.


    The diffusion properties of Na, Cs, Ba, Fe and Eu ions have been determined experimentally for a pantellerite melt and of these ions plus Li, Mn and Co in pitchstone melt, using the radiotracer residual-activity method, and narrow platinum capillaries, over the temperature range 1,200 1,400° C. In addition, Eu diffusion in a basaltic and an andesitic melt was determined. Diffusion of all cations follows an Arrhenius relationship, activation energy values being high for diffusion in the pantellerite melt (e.g. Eu: 100 kcal mol-1) except in the case of Na (24.3 kcal mol-1). Activation energies of diffusion in the pitchstone melt are similar to values recorded earlier for andesitic and basaltic melts. The new data are used, along with previously published data for diffusion in other composition melts, to examine the compositional and structural controls on diffusion. The range of diffusivities shows a marked change with melt composition; over two orders of magnitude for a basaltic melt, and nearly four orders for a pantellerite melt (both at 1,300° C). Diffusivity of all cations (except Li and Na) correlates positively with the proportion of network modifying cations. In the case of Li and Na the correlation is negative but the diffusivity of these ions correlates positively with the proportion of Na or of Na + K ions in the bulk melt. Diffusion behaviour in the pantellerite melt departs from the relationships shown by the data for other melt compositions, which could be partly explained by trivalent ions (such as Fe) occupying network forming positions. The diffusivity of alkali metal ions is strongly dependent on ionic radius, but this is not the case with the divalent and trivalent ions; diffusivity of these ions remains relatively constant with change in radius but decreases with increase in ionic charge. A compensation diagram shows four distinct but parallel trends for the majority of the cations in four melt types but the data for Li and Na plot on a separate

  18. Fossilization Type of Elephas hysudrindicus from Blora on the Basis of Petrographic and Scanning Electron Microscopic Analyses

    Directory of Open Access Journals (Sweden)

    Danny Z. Herman


    Full Text Available DOI: 10.17014/ijog.v6i2.117Either fossils of the hominid or vertebrate have long been known from terraces along the Solo River in Central and East Java. Most terraces consist of andesitic sand to andesitic tuffaceous sand with either gravelpebble or conglomerate and some of them contain vertebrate fossils. It is in this place, an ancient elephant fossil named Elephas hysudrindicus was discovered in 2009. This fossil was discovered at an abandoned sand quarry of Sunggun area, Medalem Village, Kradenan Subregency, Blora Regency which and can be mentioned as a great event for the Geological Museum. It was said as a phenomenal discovery, because the fossil was found within the terrace with condition of nearly complete skeleton of an individual elephant. Some bone fragments of Elephas hysudrindicus fossil is treated as rock specimens because a number of minerals fill in either pore spaces or cavities or cracks within bones, and such infilling minerals can be observed in cut sections of the bones. Main goals of the study are to determine the distribution and type of minerals within the bones, interpret environment of deposition, and identify fossilization type. The methodology used in this study consists of petrographic and Scanning Electron Microscopic (SEM analyses. Based on the petrographical observation, some bone specimens of Elephas hysudrindicus fossil are characterized by fibrous and porous feature with cracks occuring locally. Whilst, examination with SEM shows that the bone specimens are apparently composed of collophane or massive cryptocrystalline variety of apatite as the principal component of fossil bone, having physical characteristic of spheroidal structure and cavities of 100 to 1500 micron (μ in diameter. Most cavities and pore spaces are predominantly filled in by either authigenic crystals of rhombohedral calcite and lesser pseudohexagonal kaolinite with either slightly minerals of manganese oxide or iron oxide or ilmenite

  19. The 1976 1982 Strombolian and phreatomagmatic eruptions of White Island, New Zealand: eruptive and depositional mechanisms at a `wet' volcano (United States)

    Houghton, B. F.; Nairn, I. A.


    White Island is an active andesitic-dacitic composite volcano surrounded by sea, yet isolated from sea water by chemically sealed zones that confine a long-lived acidic hydrothermal system, within a thick sequence of fine-grained volcaniclastic sediment and ash. The rise of at least 106 m3 of basic andesite magma to shallow levels and its interaction with the hydrothermal system resulted in the longest historical eruption sequence at White Island in 1976 1982. About 107 m3 of mixed lithic and juvenile ejecta was erupted, accompanied by collapse to form two coalescing maar-like craters. Vent position within the craters changed 5 times during the eruption, but the vents were repeatedly re-established along a line linking pre-1976 vents. The eruption sequence consisted of seven alternating phases of phreatomagmatic and Strombolian volcanism. Strombolian eruptions were preceded and followed by mildly explosive degassing and production of incandescent, blocky juvenile ash from the margins of the magma body. Phreatomagmatic phases contained two styles of activity: (a) near-continuous emission of gas and ash and (b) discrete explosions followed by prolonged quiescence. The near-continuous activity reculted from streaming of magmatic volatiles and phreatic steam through open conduits, frittering juvennile shards from the margins of the magma and eroding loose lithic particles from the unconsolidated wall rock. The larger discrete explosions produced ballistic block aprons, downwind lobes of fall tephra, and cohesive ‘wet’ surge deposits confined to the main crater. The key features of the larger explosions were their shallow focus, random occurrence and lack of precursors, and the thermal heterogeneity of the ejecta. This White Island eruption was unusual because of the low discharge rate of magma over an extended time period and because of the influence of a unique physical and hydrological setting. The low rate of magma rise led to very effective separation of

  20. Geochemical and Sr-Nd isotopic characteristics of Upper Cretaceous (calc-alkaline) and Miocene (alkaline) volcanic rocks: Elazığ, Eastern Taurides, Turkey (United States)

    Kürüm, Sevcan; Tanyıldızı, Özge


    The massive volcanic suite of Upper Cretaceous Elazığ Magmatic Complex, and Miocene basic volcanic rocks of crop out to the southern vicinity of Elazığ. The petrographical studies indicated that the massive volcanic suite of Upper Cretaceous are of basalt, spilitic basalt, basaltic andesite, andesite, trachite, dacite/ryolithe and dolerite in composition, and the Miocene volcanic rocks are basalt in composition. According to the geochemical data, which are conformable with the petrographical ones, Upper Cretaceous volcanic rocks are of low and medium-K contaning types and calc-alkalin in general, and enriched with respect to LILE and HREE contents. They also contain low Ti, have negative Nb and Ta anomaly and low 143Nd/147Nd and high 87Sr/86Sr ratios. Geochemical and isotopic data for the massive volcanic suite point out that these volcanic rocks were originated from an upper mantle source (lithospheric) which undergone fractional crystallisation and crustal contamination and enriched by these processes and metasomatized within a subduction zone. Miocene volcanic rocks are of high-K alkaline type, alkali basalt/basanite in composition and products of intraplate volcanism. These rocks are richer in some major oxide contents such as Na2O, K2O, MgO and trace element contents such as Nb, Sr, Zr compared to the massive volcanic rocks of Upper Cretaceous, and they are also enriched with respect to their LILE and HREE contents. The remarkable decrease from LREE towards HREE in the REE/Chondrite-normalized variation diagram indicates a magmatic differentiation process. The MgO and Ni ratios of Miocene volcanic rocks are not conformable with those of primitive basalt composition. However, all the chemical and isotopic (low 87Sr/86Sr ratio and positive (+) εNd values) data indicate that the source magma of these volcanic rocks was derived from a depleted garnet free magma (astenospheric mantle) and was modified once again by the post collosional geodynamical events and

  1. Dacite petrogenesis on mid-ocean ridges: Evidence for oceanic crustal melting and assimilation (United States)

    Wanless, V.D.; Perfit, M.R.; Ridley, W.I.; Klein, E.


    Whereas the majority of eruptions at oceanic spreading centers produce lavas with relatively homogeneous mid-ocean ridge basalt (MORB) compositions, the formation of tholeiitic andesites and dacites at mid-ocean ridges (MORs) is a petrological enigma. Eruptions of MOR high-silica lavas are typically associated with ridge discontinuities and have produced regionally significant volumes of lava. Andesites and dacites have been observed and sampled at several locations along the global MOR system; these include propagating ridge tips at ridge-transform intersections on the Juan de Fuca Ridge and eastern Gal??pagos spreading center, and at the 9??N overlapping spreading center on the East Pacific Rise. Despite the formation of these lavas at various ridges, MOR dacites show remarkably similar major element trends and incompatible trace element enrichments, suggesting that similar processes are controlling their chemistry. Although most geochemical variability in MOR basalts is consistent with low-pressure fractional crystallization of various mantle-derived parental melts, our geochemical data for MOR dacitic glasses suggest that contamination from a seawater-altered component is important in their petrogenesis. MOR dacites are characterized by elevated U, Th, Zr, and Hf, low Nb and Ta concentrations relative to rare earth elements (REE), and Al2O3, K2O, and Cl concentrations that are higher than expected from low-pressure fractional crystallization alone. Petrological modeling of MOR dacites suggests that partial melting and assimilation are both integral to their petrogenesis. Extensive fractional crystallization of a MORB parent combined with partial melting and assimilation of amphibole-bearing altered crust produces a magma with a geochemical signature similar to a MOR dacite. This supports the hypothesis that crustal assimilation is an important process in the formation of highly evolved MOR lavas and may be significant in the generation of evolved MORB in

  2. Mafic enclaves in dacitic domes and their relation with La Poruña scoria cone, Central Andes, northern Chile (United States)

    González-Maurel, O. P.; Gallmeyer, G.; Godoy, B.; Menzies, A.; le Roux, P. J.; Harris, C.


    Chao Dacite, Chillahui