WorldWideScience

Sample records for anatolia chemical characterisation

  1. Genetic characterisation of 19 autosomal STR loci in a population sample from the Southeastern Anatolia Region of Turkey.

    Science.gov (United States)

    Bozman, Nazli; Gurkan, Cemal; Sevay, Huseyin; Demirdov, Damla Kanliada; Ozbas-Gerceker, Filiz

    2018-03-14

    Southeastern Anatolia is the smallest, yet the most densely populated region among the seven major geographic constituents of Turkey. Situated in the Upper Mesopotamia, Southeastern Anatolia was also the northernmost extension of the Fertile Crescent, which is often considered as the earliest cradle of civilisation. To investigate the autosomal STR polymorphisms associated with a truly representative population sample pool from Southeastern Anatolia. Samples from a total of 257 volunteers were analysed by 19-loci autosomal STRs using the commercially available COrDIS Plus Kit. Allele frequencies, statistical parameters of forensic interest and Nei's D A distances with respect to the nearby and distant populations were calculated, besides performing exact tests of population differentiation with the same populations. A combined matching probability of 1.49978 × 10 -23 and a combined power of exclusion of 0.999999961 were obtained for the novel Southeastern Anatolian autosomal STR dataset. Furthermore, the Southeastern Anatolia population was found to have close genetic affinities with the other regional populations from Turkey, along with those from an apparent genetic continuum extending from the Near East to Southeastern Europe. The novel Southeastern Anatolian dataset is expected to be useful in regional forensic genetics investigations and molecular anthropology applications.

  2. Chemical characterisation of meltwater draining from Gangotri ...

    Indian Academy of Sciences (India)

    Home; Journals; Journal of Earth System Science; Volume 121; Issue 3. Chemical characterisation of meltwater draining from Gangotri Glacier, Garhwal Himalaya, India. Virendra Bahadur Singh A L Ramanathan Jose George Pottakkal Parmanand Sharma Anurag Linda Mohd Farooq Azam C Chatterjee. Volume 121 Issue ...

  3. Chemical characterisation of meltwater draining from Gangotri ...

    Indian Academy of Sciences (India)

    Chemical characterisation of meltwater draining from Gangotri Glacier, Garhwal Himalaya, India. Virendra Bahadur Singh, AL Ramanathan. ∗. , Jose George Pottakkal,. Parmanand Sharma, Anurag Linda, Mohd Farooq Azam and C Chatterjee. School of Environmental Sciences, Jawaharlal Nehru University, New Delhi 110 ...

  4. Chemical characterisation of Hoodia gordonii extract.

    Science.gov (United States)

    Russell, P J; Swindells, C

    2012-01-01

    The chemical composition of a solvent extract of Hoodia gordonii termed 'H.gordonii extract' has been characterised by hyphenated chromatographic methods and traditional analytical techniques. The extract consists of a mixture of steroid glycosides, fatty acids, plant sterols and polar organic material. High performance liquid chromatography (HPLC) with ultra violet (UV) and mass spectrometric (MS) detection was used to quantify and confirm the identity of a number of steroid glycosides (73.7% w/w) present in the extract. Gas chromatography (GC) with MS and flame ionisation detection (FID) was applied to determine the fatty acid (3.12% w/w) sterol (0.39% w/w) and alcohol (0.03% w/w) content of a saponified sample of the extract. Polar organic material was quantified by gravimetric methodology using C(18) SPE separation and was determined to be a minimum of 3% w/w. Moisture content was measured by Karl Fischer coulometric titration (0.81% w/w). The protein content was investigated by sodium dodecyl sulphate-polyacrylamide gel electrophoresis (SDS-PAGE) with SYPRO Ruby staining and a negative result was determined with a limit of detection of <0.001%w/w of protein per band. The chemical composition of the extract remained stable for 19 months when stored in re-sealable plastic bags at ambient (21-24°C) temperature and <60% relative humidity. Copyright © 2011 Elsevier Ltd. All rights reserved.

  5. Chemical Characterisation of Printed Circuit Board Wastewater

    Energy Technology Data Exchange (ETDEWEB)

    Sobri, S; Ali, A H M, E-mail: eeza@eng.upm.edu.my [Department of Chemical and Environmental Engineering, Faculty of Engineering, Universiti Putra Malaysia, 43400 Serdang, Selangor (Malaysia)

    2011-02-15

    Manufacturing of PCBs is highly complicated and involves many processes. Recycling of PCB wastewater receives wide concerns as the recent international growth in the electronics industry has generated a drastic increase in the amount of waste PCBs with profound environmental impacts such as soil and groundwater contamination. This paper reports on the chemical characterization of PCB wastewater as the initial investigation for selective metal recovery.

  6. Microscopic characterisation of suspended graphene grown by chemical vapour deposition

    NARCIS (Netherlands)

    Bignardi, L.; Dorp, W.F. van; Gottardi, S.; Ivashenko, O.; Dudin, P.; Barinov, A.; de Hosson, J.T.M.; Stöhr, M.; Rudolf, P.

    2013-01-01

    We present a multi-technique characterisation of graphene grown by chemical vapour deposition (CVD) and thereafter transferred to and suspended on a grid for transmission electron microscopy (TEM). The properties of the electronic band structure are investigated by angle-resolved photoelectron

  7. Chemical characterisation of zircon-cadmium sulfoselenide ceramic pigments

    International Nuclear Information System (INIS)

    Gazulla Barreda, M. F.; Rodrigo Edo, M.; Blasco Roca, E.; Orduna Cordero, M.

    2013-01-01

    The present paper addresses the development of a methodology that allows the complete chemical characterisation of zircon cadmium sulfoselenide ceramic pigments including minor and major elements. To develop the methodology, five zircon-cadmium sulfoselenide pigments with different hues were selected, studying the different measurement process steps, from sample preparation to the optimisation of the measurement of the different components of the pigments by spectroscopic techniques (WD-XRF and elemental analysis by combustion and IR detection). The chemical characterisation method developed was validated with synthetic standards prepared from the mixture of certified reference materials and pure oxides because no certified referenced materials of this type of pigments were commercially available. The developed method can be used for a complete chemical characterization of zircon-cadmium sulfoselenide ceramic pigments with a very low uncertainty for all the elements analysed. (Author)

  8. Physico-chemical characterisation of material fractions in household waste

    DEFF Research Database (Denmark)

    Götze, Ramona; Boldrin, Alessio; Scheutz, Charlotte

    2016-01-01

    State-of-the-art environmental assessment of waste management systems rely on data for the physico-chemical composition of individual material fractions comprising the waste in question. To derive the necessary inventory data for different scopes and systems, literature data from different sources...... and backgrounds are consulted and combined. This study provides an overview of physico-chemical waste characterisation data for individual waste material fractions available in literature and thereby aims to support the selection of data fitting to a specific scope and the selection of uncertainty ranges related...... to the data selection from literature. Overall, 97 publications were reviewed with respect to employed characterisation method, regional origin of the waste, number of investigated parameters and material fractions and other qualitative aspects. Descriptive statistical analysis of the reported physico...

  9. Thermoluminescence characterisation of chemical vapour deposited diamond films

    CERN Document Server

    Mazzocchi, S; Bucciolini, M; Cuttone, G; Pini, S; Sabini, M G; Sciortino, S

    2002-01-01

    The thermoluminescence (TL) characteristics of a set of six chemical vapour deposited diamond films have been studied with regard to their use as off-line dosimeters in radiotherapy. The structural characterisation has been performed by means of Raman spectroscopy. Their TL responses have been tested with radiotherapy beams ( sup 6 sup 0 Co photons, photons and electrons from a linear accelerator (Linac), 26 MeV protons from a TANDEM accelerator) in the dose range 0.1-7 Gy. The dosimetric characterisation has yielded a very good reproducibility, a very low dependence of the TL response on the type of particle and independence of the radiation energy. The TL signal is not influenced by the dose rate and exhibits a very low thermal fading. Moreover, the sensitivity of the diamond samples compares favourably with that of standard TLD100 dosimeters.

  10. Contrasting melt equilibration conditions across Anatolia

    Science.gov (United States)

    Reid, Mary; Delph, Jonathan; Schleiffarth, W. Kirk; Cosca, Michael

    2017-04-01

    The widespread mafic volcanism, elevated crustal temperatures, and plateau-type topography in Central Anatolia, Turkey, could collectively be the result of lithospheric delamination, mantle upwelling, and tectonic escape in response to Arabian-Anatolian plate collision. We used the results from basalt geochemistry and a passive-source broadband seismic experiment obtained as part of an international collaborative effort (Continental Dynamics - Central Anatolia Tectonics) to investigate the crust-mantle structure and melting conditions associated with the Quaternary Hasandag Monogenic Cluster (HMC) south and west of Hasandag volcano. The HMC is unusually mafic, not only for Central Anatolia but globally, enabling meaningful comparisons between geochemical and seismic interpretations of mantle conditions. HMC basalts are characterized by orogenic signatures that could have originated (1) in mantle wedge that, after stagnating because of collision, was remobilized south and upward as a result of rollback of the African slab or, alternatively (2) by piecemeal foundering of residual mantle lithosphere into convecting upper mantle, producing small-scale convection and associated decompression melting. Melt equilibration conditions for the HMC are hot (TP ˜1335-1250˚ C, assuming 1-4 wt.% H2O) and shallow (P = 1.1 to 1.6 GPa), approaching those for MORB. Shear wave velocities are relatively constant at ˜4.1 km/s between the Moho and a depth of ˜45-50 km (˜1.4 GPa; Fig. 6), below which Vs increases with increasing depth. We infer that a melt-perfused mantle lid could be locally present between 40 and 55 km. In contrast to Central Anatolia, estimated equilibration conditions for Western Anatolia and Eastern Anatolia (east of the Inner Tauride Suture) mantle melts are hotter (by ≥60˚ C) and deeper (mostly by 0.6-1.0 GPa). They also have chemical signatures that, unlike Central Anatolia, are similar to those of intraplate basalts. These differences are likely related

  11. Using chemical shift perturbation to characterise ligand binding.

    Science.gov (United States)

    Williamson, Mike P

    2013-08-01

    Chemical shift perturbation (CSP, chemical shift mapping or complexation-induced changes in chemical shift, CIS) follows changes in the chemical shifts of a protein when a ligand is added, and uses these to determine the location of the binding site, the affinity of the ligand, and/or possibly the structure of the complex. A key factor in determining the appearance of spectra during a titration is the exchange rate between free and bound, or more specifically the off-rate koff. When koff is greater than the chemical shift difference between free and bound, which typically equates to an affinity Kd weaker than about 3μM, then exchange is fast on the chemical shift timescale. Under these circumstances, the observed shift is the population-weighted average of free and bound, which allows Kd to be determined from measurement of peak positions, provided the measurements are made appropriately. (1)H shifts are influenced to a large extent by through-space interactions, whereas (13)Cα and (13)Cβ shifts are influenced more by through-bond effects. (15)N and (13)C' shifts are influenced both by through-bond and by through-space (hydrogen bonding) interactions. For determining the location of a bound ligand on the basis of shift change, the most appropriate method is therefore usually to measure (15)N HSQC spectra, calculate the geometrical distance moved by the peak, weighting (15)N shifts by a factor of about 0.14 compared to (1)H shifts, and select those residues for which the weighted shift change is larger than the standard deviation of the shift for all residues. Other methods are discussed, in particular the measurement of (13)CH3 signals. Slow to intermediate exchange rates lead to line broadening, and make Kd values very difficult to obtain. There is no good way to distinguish changes in chemical shift due to direct binding of the ligand from changes in chemical shift due to allosteric change. Ligand binding at multiple sites can often be characterised, by

  12. Chemical bath ZnSe thin films: deposition and characterisation

    Science.gov (United States)

    Lokhande, C. D.; Patil, P. S.; Ennaoui, A.; Tributsch, H.

    1998-01-01

    The zinc selenide (ZnSe) thin films have been deposited by a simple and inexpensive chemical bath deposition (CBD) method. The selenourea was used as a selenide ion source. The ZnSe films have been characterised by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDAX), Rutherford back scattering (RBS), and optical absorption. The as-deposited ZnSe films on various substrates are found to be amorphous and contain O2 and N2 in addition to Zn and Se. The optical band gap of the film is estimated to be 2.9 eV. The films are photoactive as evidenced by time resolved microwave conductivity (TRMC).

  13. Trouble in Anatolia

    Directory of Open Access Journals (Sweden)

    Nick R Anthonisen

    2004-01-01

    Full Text Available In this issue of the Canadian Respiratory Journal, Gulmez et al (pages 287-290 review the presentation, management and outcome of malignant mesothelioma in central Anatolia, Turkey. There is nothing particularly new about the disease here; it presents with chest pain, dyspnea and pleural effusion, is diagnosed by biopsy and has a miserable outcome whatever is done for it, just like malignant mesothelioma in Canada. Mesothelioma in Anatolia is unusual in that it is very common, with an approximately equal sex distribution, and frequently occurs in relatively young people. The reasons for this are not a mystery. Anatolia is a volcanic area; there is a lot of asbestos on or near the surface, and it is widely used as construction material, in painting, and as insulation (pages 287-290! Asbestos related disease is due to environmental, not occupational exposure, and exposure is more intense and occurs at an earlier age than in Canada. Not only that, but some areas of Anatolia are rich in erionite, and people build homes in and on erionite-bearing rocks. Erionite is apparently something like asbestos but worse in terms of carcinogenicity (1, perhaps because its crystals have large surface areas, and areas with erionite have an even higher incidence of mesothelioma.

  14. Characterisation of gaharu hydrosol: Physical, chemical and microbiological properties

    International Nuclear Information System (INIS)

    Nur Humaira Lau Abdullah; Salmah Moosa

    2010-01-01

    Gaharu hydrosol is produced during the hydro distillation of resinous wood part of Aquilaria sp. This aromatic water is being considered as a by-product in the industry. There is interest to turn this aromatic by-product into aroma therapy products. The present study is carried out in order to understand the properties of gaharu hydrosol, physically, chemically and microbiologically. Gaharu hydrosol from two different extraction facilities for example at Kedaik Agar wood Sdn. Bhd. and Malaysian Nuclear Agency were characterised in this study. All the gaharu hydrosol samples displayed acidic nature, with pH in the range of 3.62 - 4.53. Four antioxidant assays were carried out to ascertain the antioxidant capabilities of two gaharu hydrosol samples through the total phenolic content assay, ABTS + radical scavenging activity, DPPH· radical scavenging activity and ferric reducing activity (FRAP). The results revealed that the samples exhibited lower antioxidant capabilities as compared to the positive control. For microbial population study, fungi was not present in the samples as there was no growth observed on the Plate Sabouraud Dextrose Agar (SDA) using membrane filtration technique. The antibacterial activity of the gaharu hydrosol against Staphylococcus aureus and Pseudomonas aeruginosa was determined using agar dilution method and disk diffusion method. The results showed that the gaharu hydrosol did not inhibit the growth of both the bacteria. The results obtained from this study will be further evaluated for the development of new products using this aromatic gaharu by-product. (author)

  15. Simplified fate modelling in respect to ecotoxicological and human toxicological characterisation of emissions of chemical compounds

    DEFF Research Database (Denmark)

    Birkved, Morten; Heijungs, Reinout

    2011-01-01

    The impact assessment of chemical compounds in Life Cycle Impact Assessment (LCIA) and Environmental Risk Assessment (ERA) requires a vast amount of data on the properties of the chemical compounds being assessed. The purpose of the present study is to explore statistical options for reduction...... the independent chemical input parameters from the minimum data set, needed for characterisation in USEtox™, according to general availability, importance and relevance for fate factor prediction.Each approach (63% and 75% of the minimum data set needed for characterisation in USEtox™) yielded 66 meta...

  16. Physico-chemical properties of manufactured nanomaterials - Characterisation and relevant methods. An outlook based on the OECD Testing Programme.

    NARCIS (Netherlands)

    Rasmussen, Kirsten; Rauscher, Hubert; Mech, Agnieszka; Riego Sintes, Juan; Gilliland, Douglas; González, Mar; Kearns, Peter; Moss, Kenneth; Visser, Maaike; Groenewold, Monique; Bleeker, Eric A J

    Identifying and characterising nanomaterials require additional information on physico-chemical properties and test methods, compared to chemicals in general. Furthermore, regulatory decisions for chemicals are usually based upon certain toxicological properties, and these effects may not be

  17. Chemical and thermal analysis for characterisation of building materials

    International Nuclear Information System (INIS)

    Kumar, S.C.; Sudersanan, M.; Ravindran, P.V.; Kalekar, B.B.; Mathur, P.K.

    2000-01-01

    Cement and other construction materials are extensively used for the construction of shielding materials for nuclear and high energy radiations. The design and optimum utilisation of such materials need an accurate analysis of their chemical composition. The moisture content and presence of bound water and other volatile materials are also important. The use of thermal analysis supplements the data obtained by chemical analysis and enables a distinction of moisture and chemically bound water. It also enables an identification of the process leading to the loss on ignition. The work carried out on the analysis of sand, cement and other aggregate materials used for the preparation of concrete is described in the paper. (author)

  18. Physico-chemical characterisation of surface modified particles for inhalation.

    Science.gov (United States)

    Stank, Katharina; Steckel, Hartwig

    2013-05-01

    Surface modification of drugs for inhalation is a possibility to influence interparticulate forces. This can be necessary to achieve a sufficient aerosolisation during powder inhalation as the cohesiveness of the micronised drug can be reduced. In addition, the interaction with propellants in pressurised metered dose inhaler can be changed. This can be used to improve the physical stability of the suspension based formulations. A dry particle coating process was used for the alteration of particle surfaces. The blending of micronised salbutamol sulphate (SBS) with different concentrations of magnesium stearate (Mgst) or glycerol monostearate (GMS) was followed by co-milling with an air jet mill. The powder properties were characterised by SEM, EDX, laser diffraction, BET and inverse gas chromatography. Physical mixtures generated by Turbula blending were compared to co-milled samples. A slight particle size reduction was determined. The Mgst deposition on SBS particles was detected by EDX measurements. The dispersive surface energy of SBS is lowered and the energy distribution is more homogenous for the co-milled samples. This study proves the application of co-milling for surface modification in the inhalation area. Copyright © 2013 Elsevier B.V. All rights reserved.

  19. Physico-chemical characterisation of material fractions in household waste

    DEFF Research Database (Denmark)

    Götze, Ramona; Boldrin, Alessio; Scheutz, Charlotte

    2016-01-01

    State-of-the-art environmental assessment of waste management systems rely on data for the physico-chemical composition of individual material fractions comprising the waste in question. To derive the necessary inventory data for different scopes and systems, literature data from different sources...

  20. Physico-chemical and Mineralogical Characterisation of Subsurface ...

    African Journals Online (AJOL)

    Studies were carried out on subsurface sediments obtained around the Gaborone landfill area Botswana, in order to characterize their mineralogy and physico-chemistry, appraise any contaminant inputs from the landfill and assess their ability to attenuate contaminants from the landfill. Physico-chemical properties ...

  1. Chemical-mineralogical characterisation of coarse recycled concrete aggregate

    International Nuclear Information System (INIS)

    Limbachiya, M.C.; Marrocchino, E.; Koulouris, A.

    2007-01-01

    The construction industry is now putting greater emphasis than ever before on increasing recycling and promoting more sustainable waste management practices. In keeping with this approach, many sectors of the industry have actively sought to encourage the use of recycled concrete aggregate (RCA) as an alternative to primary aggregates in concrete production. The results of a laboratory experimental programme aimed at establishing chemical and mineralogical characteristics of coarse RCA and its likely influence on concrete performance are reported in this paper. Commercially produced coarse RCA and natural aggregates (16-4 mm size fraction) were tested. Results of X-ray fluorescence (XRF) analyses showed that original source of RCA had a negligible effect on the major elements and a comparable chemical composition between recycled and natural aggregates. X-ray diffraction (XRD) analyses results indicated the presence of calcite, portlandite and minor peaks of muscovite/illite in recycled aggregates, although they were directly proportioned to their original composition. The influence of 30%, 50%, and 100% coarse RCA on the chemical composition of equal design strength concrete has been established, and its suitability for use in a concrete application has been assessed. In this work, coarse RCA was used as a direct replacement for natural gravel in concrete production. Test results indicated that up to 30% coarse RCA had no effect on the main three oxides (SiO 2 , Al 2 O 3 and CaO) of concrete, but thereafter there was a marginal decrease in SiO 2 and increase in Al 2 O 3 and CaO contents with increase in RCA content in the mix, reflecting the original constituent's composition

  2. Chemical-mineralogical characterisation of coarse recycled concrete aggregate.

    Science.gov (United States)

    Limbachiya, M C; Marrocchino, E; Koulouris, A

    2007-01-01

    The construction industry is now putting greater emphasis than ever before on increasing recycling and promoting more sustainable waste management practices. In keeping with this approach, many sectors of the industry have actively sought to encourage the use of recycled concrete aggregate (RCA) as an alternative to primary aggregates in concrete production. The results of a laboratory experimental programme aimed at establishing chemical and mineralogical characteristics of coarse RCA and its likely influence on concrete performance are reported in this paper. Commercially produced coarse RCA and natural aggregates (16-4 mm size fraction) were tested. Results of X-ray fluorescence (XRF) analyses showed that original source of RCA had a negligible effect on the major elements and a comparable chemical composition between recycled and natural aggregates. X-ray diffraction (XRD) analyses results indicated the presence of calcite, portlandite and minor peaks of muscovite/illite in recycled aggregates, although they were directly proportioned to their original composition. The influence of 30%, 50%, and 100% coarse RCA on the chemical composition of equal design strength concrete has been established, and its suitability for use in a concrete application has been assessed. In this work, coarse RCA was used as a direct replacement for natural gravel in concrete production. Test results indicated that up to 30% coarse RCA had no effect on the main three oxides (SiO2, Al2O3 and CaO) of concrete, but thereafter there was a marginal decrease in SiO2 and increase in Al2O3 and CaO contents with increase in RCA content in the mix, reflecting the original constituent's composition.

  3. Chemical and physicochemical characterisation of various horse feed ingredients

    DEFF Research Database (Denmark)

    Brøkner, Christine; Knudsen, Knud Erik Bach; Karaman, Ibrahim

    2012-01-01

    enzymatic-chemical methods and lignin by gravimetry. The results for total dietary fibre (DF) were compared with conventional crude fibre (CF) and neutral detergent fibre (aNDFom) methods. The physicochemical properties were quantified based on swelling and water binding capacity (WBC). Between 755 g......NDFom and CF methods. The greatest difference between the DF and aNDFom methods was found in root crops and apple pulp in which the soluble non-cellulosic polysaccharides (S-NCP) fraction made up 350–581 g/kg of total NSP. The physicochemical properties were compared to fibre content and were associated to WBC...... may be underestimated depending on the analytical method. Quantifying the soluble NCP fraction is beneficial as it has been shown to have health beneficial properties and contributes to the total energy supply. These results suggest that the DF method should be used when evaluating feeds for horses....

  4. Sampling and single particle analysis for the chemical characterisation of fine atmospheric particulates: A review.

    Science.gov (United States)

    Elmes, Michele; Gasparon, Massimo

    2017-11-01

    To better understand the potential environmental and human health impacts of fine airborne particulate matter (APM), detailed physical and chemical characterisation is required. The only means to accurately distinguish between the multiple compositions in APM is by single particle analysis. A variety of methods and instruments are available, which range from filter-based sample collection for off-line laboratory analysis to on-line instruments that detect the airborne particles and generate size distribution and chemical data in real time. There are many reasons for sampling particulates in the ambient atmosphere and as a consequence, different measurement strategies and sampling devices are used depending on the scientific objectives and subsequent analytical techniques. This review is designed as a guide to some of the techniques available for the sampling and subsequent chemical analysis of individual inorganic particles. Copyright © 2017 Elsevier Ltd. All rights reserved.

  5. Chemical and physical characterisation of biomass-based pyrolysis oils. Literature view

    Energy Technology Data Exchange (ETDEWEB)

    Fagernaes, L. [VTT Energy, Espoo (Finland). Energy Production Technologies

    1995-12-31

    Biomass-based pyrolysis oils are complex mixtures of mainly organic compounds and water. The determination of their physical and chemical properties and chemical composition is a challenge for researchers. Characterisation of biomass pyrolysis oils has been studied at many universities in North America and Europe in the 1980s and 1990s. The existing literature on the analytical methods used for these oils is reviewed in this report. For characterising the chemical composition, the bio-oils have first been mainly fractionated into different classes. Solvent extraction and adsorption chromatography are the most general methods used. In adsorption chromatography, the oils have been fractionated into different hydrocarbon and polar fractions. The fractions obtained have been analysed with various chromatographic and spectroscopic methods. Gas chromatography/mass spectrometry (GC/MS) technique is the analytical method most widely used and well adaptable for the fractions. For high-molecular-mass and highly polar compounds liquid chromatographic (LC) techniques as well as infrared (FT-IR) and nuclear magnetic resonance (1H NMR and 13C NMR) spectroscopies are more suitable due to the low volatility of pyrolysis oils. For whole pyrolysis oils, LC techniques, primarily size exclusion chromatography and FT-IR and FT-NMR spectroscopies have proved to be useful methods

  6. Physico-chemical characterisation of material fractions in household waste: Overview of data in literature.

    Science.gov (United States)

    Götze, Ramona; Boldrin, Alessio; Scheutz, Charlotte; Astrup, Thomas Fruergaard

    2016-03-01

    State-of-the-art environmental assessment of waste management systems rely on data for the physico-chemical composition of individual material fractions comprising the waste in question. To derive the necessary inventory data for different scopes and systems, literature data from different sources and backgrounds are consulted and combined. This study provides an overview of physico-chemical waste characterisation data for individual waste material fractions available in literature and thereby aims to support the selection of data fitting to a specific scope and the selection of uncertainty ranges related to the data selection from literature. Overall, 97 publications were reviewed with respect to employed characterisation method, regional origin of the waste, number of investigated parameters and material fractions and other qualitative aspects. Descriptive statistical analysis of the reported physico-chemical waste composition data was performed to derive value ranges and data distributions for element concentrations (e.g. Cd content) and physical parameters (e.g. heating value). Based on 11,886 individual data entries, median values and percentiles for 47 parameters in 11 individual waste fractions are presented. Exceptional values and publications are identified and discussed. Detailed datasets are attached to this study, allowing further analysis and new applications of the data. Copyright © 2016 Elsevier Ltd. All rights reserved.

  7. Characterisation of waste derived biochar added biocomposites: chemical and thermal modifications

    Energy Technology Data Exchange (ETDEWEB)

    Das, Oisik [Department of Civil and Environmental Engineering, University of Auckland, Auckland 1142 (New Zealand); Sarmah, Ajit K., E-mail: a.sarmah@auckland.ac.nz [Department of Civil and Environmental Engineering, University of Auckland, Auckland 1142 (New Zealand); Zujovic, Zoran [School of Chemical Sciences, University of Auckland, Auckland 1142 (New Zealand); Bhattacharyya, Debes [Centre for Advanced Composite Materials, Department of Mechanical Engineering, University of Auckland, Auckland 1142 (New Zealand)

    2016-04-15

    A step towards sustainability was taken by incorporating waste based pyrolysed biochar in wood and polypropylene biocomposites. The effect of biochar particles on the chemistry and thermal makeup of the composites was determined by characterising them through an array of characterisation techniques such as 3D optical profiling, X-ray diffraction, transmission electron microscopy, electron spin/nuclear magnetic resonance spectroscopy, and differential scanning calorimetry. It was observed that addition of biochar increased the presence of free radicals in the composite while also improving its thermal conductivity. Biochar particles did not interfere with the melting behaviour of polymer in the thermal regime. However, wood and biochar acted as nucleation agents consequently increasing the crystallisation temperature. The crystal structure of polypropylene was not disrupted by biochar inclusion in composite. Transmission electron microscopy images illustrated the aggregated nature of the biochar particles at higher loading levels. Nuclear magnetic resonance studies revealed the aromatic nature of biochar and the broadening of peak intensities of composites with increasing biochar levels due to its amorphous nature and presence of free radicals. Thus, this insight into the chemical and thermal modification of biochar added composites would allow effective engineering to optimise their properties while simultaneously utilising wastes. - Highlights: • Waste derived biochars were used to make polymer based biocomposites. • Composites were characterised by NMR, ESR, DSC, XRD, TEM etc. • Biochar increased the thermal conductivity of composites. • Biochar did not disrupt the crystal structure of polypropylene. • NMR revealed aromatic nature of biochar in composites.

  8. Characterisation of waste derived biochar added biocomposites: chemical and thermal modifications

    International Nuclear Information System (INIS)

    Das, Oisik; Sarmah, Ajit K.; Zujovic, Zoran; Bhattacharyya, Debes

    2016-01-01

    A step towards sustainability was taken by incorporating waste based pyrolysed biochar in wood and polypropylene biocomposites. The effect of biochar particles on the chemistry and thermal makeup of the composites was determined by characterising them through an array of characterisation techniques such as 3D optical profiling, X-ray diffraction, transmission electron microscopy, electron spin/nuclear magnetic resonance spectroscopy, and differential scanning calorimetry. It was observed that addition of biochar increased the presence of free radicals in the composite while also improving its thermal conductivity. Biochar particles did not interfere with the melting behaviour of polymer in the thermal regime. However, wood and biochar acted as nucleation agents consequently increasing the crystallisation temperature. The crystal structure of polypropylene was not disrupted by biochar inclusion in composite. Transmission electron microscopy images illustrated the aggregated nature of the biochar particles at higher loading levels. Nuclear magnetic resonance studies revealed the aromatic nature of biochar and the broadening of peak intensities of composites with increasing biochar levels due to its amorphous nature and presence of free radicals. Thus, this insight into the chemical and thermal modification of biochar added composites would allow effective engineering to optimise their properties while simultaneously utilising wastes. - Highlights: • Waste derived biochars were used to make polymer based biocomposites. • Composites were characterised by NMR, ESR, DSC, XRD, TEM etc. • Biochar increased the thermal conductivity of composites. • Biochar did not disrupt the crystal structure of polypropylene. • NMR revealed aromatic nature of biochar in composites.

  9. Structural, chemical and electrical characterisation of conductive graphene-polymer composite films

    Energy Technology Data Exchange (ETDEWEB)

    Brennan, Barry; Spencer, Steve J.; Belsey, Natalie A. [National Physical Laboratory, Teddington, TW11 0LW (United Kingdom); Faris, Tsegie [DZP Technologies Ltd., Future Business Centre, Cambridge, CB4 2HY (United Kingdom); Cronin, Harry [DZP Technologies Ltd., Future Business Centre, Cambridge, CB4 2HY (United Kingdom); Advanced Technology Institute (ATI), University of Surrey, Guildford, GU2 7XH (United Kingdom); Silva, S. Ravi P. [Advanced Technology Institute (ATI), University of Surrey, Guildford, GU2 7XH (United Kingdom); Sainsbury, Toby; Gilmore, Ian S. [National Physical Laboratory, Teddington, TW11 0LW (United Kingdom); Stoeva, Zlatka [DZP Technologies Ltd., Future Business Centre, Cambridge, CB4 2HY (United Kingdom); Pollard, Andrew J., E-mail: andrew.pollard@npl.co.uk [National Physical Laboratory, Teddington, TW11 0LW (United Kingdom)

    2017-05-01

    Graphical abstract: Secondary Ion Mass Spectrometry (SIMS) imaging of the dispersion of graphene within graphene-polymer composites using the Na{sup +} signal. - Highlights: • Relation of properties of graphene flakes with electrical properties of composite. • Standardised characterisation method for structural properties of graphene flakes. • Structural and chemical characterisation of commercial graphene flakes. • ToF-SIMS used to determine dispersion of graphene in polymer. - Abstract: Graphene poly-acrylic and PEDOT:PSS nanocomposite films were produced using two alternative commercial graphene powders to explore how the graphene flake dimensions and chemical composition affected the electrical performance of the film. A range of analytical techniques, including scanning electron microscopy (SEM), atomic force microscopy (AFM), Raman spectroscopy, X-ray photoelectron spectroscopy (XPS) and time-of-flight secondary ion mass spectrometry (ToF-SIMS), were employed to systematically analyse the initial graphene materials as well as the nanocomposite films. Electrical measurements indicated that the sheet resistance of the films was affected by the properties of the graphene flakes used. To further explore the composition of the films, ToF-SIMS mapping was employed and provided a direct means to elucidate the nature of the graphene dispersion in the films and to correlate this with the electrical analysis. These results reveal important implications for how the dispersion of the graphene material in films produced from printable inks can be affected by the type of graphene powder used and the corresponding effect on electrical performance of the nanocomposites. This work provides direct evidence for how accurate and comparable characterisation of the graphene material is required for real-world graphene materials to develop graphene enabled films and proposes a measurement protocol for comparing graphene materials that can be used for international

  10. Hydrophobic properties and chemical characterisation of natural water repellent materials in Australian sands

    Science.gov (United States)

    Franco, C. M. M.; Clarke, P. J.; Tate, M. E.; Oades, J. M.

    2000-05-01

    Water-repellency in non-wetting sands is due to hydrophobic waxes present on the surface of sand grains and contained in particulate organic matter present in these sands. This study investigates the physico-chemical characteristics of these natural waxes and compares them to waxes extracted from potential original source materials. Non-polar and polar hydrophobic wax extracts were obtained from whole non-wetting sand, and its individual constituents, and associated organic matter. These included the sand fraction, the intrinsic particulate organic matter, tree litter, eucalyptus leaves, bark, lucerne and lupin plants, and fungi and actinomycetes isolated from these sands. Waxes were characterised for their hydrophobic properties and composition of their chemical constituents. The hydrophobicities of the waxes were assessed by measuring the water-repellency induced after treating acid washed sand with wax extracts. Non-polar and polar wax extracts of the tree litter displayed hydrophobic properties that were similar to the corresponding waxes isolated from non-wetting sand and intrinsic particulate organic matter. Unlike these plant-derived waxes, the microbial wax extracts possessed different hydrophobic properties. Characterisation of the components of the extracted waxes by gas chromatography-mass spectroscopy (GC-MS) analysis revealed a strong similarity in the composition of waxes isolated from non-wetting sand, tree litter and other plant material. The major components found were unbranched and branched C16 to C36 fatty acids and their esters, alkanes, phytanols, phytanes, and sterols. Some of these components were not detected in the microbial waxes. Unextracted samples, as well as wax extracts of non-wetting sand, intrinsic particulate organic matter, tree litter and fresh plant material were further analysed by solution and solid state Nuclear Magnetic Resonance spectroscopy which revealed the relative content of the different chemical species present.

  11. Chemical and functional characterisation of propolis collected from East Andalusia (southern Spain).

    Science.gov (United States)

    Kumazawa, Shigenori; Bonvehí, Josep Serra; Torres, Cristina; Mok-Ryeon, Ahn; Bermejo, Francisco José Orantes

    2013-01-01

    Propolis is a complex mixture of natural sticky, gummy and resinous components produced by honeybees (Apis mellifera L.) from plant materials. However, phytochemical data of the Andalusian (southern Spain) propolis are scant. The primary objectives of this study were to chemically characterise the compounds and evaluate the anti-oxidant activity found in 28 Andalusian propolis samples. Ethanol extracts of propolis (EEP) were prepared and examined for their anti-oxidant activity by 2,2'-azinobis(3-ethylbenzothiazoline-6-sulphonic acid) and 2,2-diphenyl-1-picrylhydrazyl assays. To characterise the phenolic composition, the presence of 11 compounds was identified by HPLC analysis with photodiode array and mass spectrometric detection. All propolis samples had strong anti-oxidant activity, accompanied by high total phenolic content. The most abundant compounds were flavonoids. Concerning the phenolic compounds content, our results showed that the 75% of the samples analysed contained at least 80 mg/g of flavonoids, primarily pinobanksin 3-acetate, pinocembrin, chrysin, galangin and pinobanksin. Caffeic acid phenethyl ester was detected in almost all EEP samples but in smaller proportions (mean 12.9 ± 2.8 mg/g). The present investigation constitutes the first comprehensive report on the phenolics identified in southern Spanish propolis. The results revealed that the samples tested showed a high scavenging activity and therefore indicate the possible use of Andalusian propolis as an important source of natural anti-oxidants. Copyright © 2013 John Wiley & Sons, Ltd.

  12. Chemical characterisation of natural organic substrates for biological mitigation of acid mine drainage.

    Science.gov (United States)

    Gibert, Oriol; de Pablo, Joan; Luis Cortina, José; Ayora, Carlos

    2004-11-01

    The current approach of the biological treatment of acid mine drainage by means of a passive remediation system involves the choice of an appropriate organic substrate as electron donor for sulphate reducers. Nowadays this selection is one of the critical steps in the performance of such treatment, as this depends to a great extent on the degradability of the organic substrate. Thus, a prior characterisation of the organic substrate predicting its biodegradability would be desirable before embarking on an extensive large-scale application. The aim of this study was to correlate the chemical composition (lignin content) of four different natural organic substrates (compost, sheep and poultry manures, oak leaf) and their capacity to sustain bacterial activity in an attempt to predict biodegradation from chemical characterisation. The results showed that the lower the content of lignin in the organic substrate, the higher its biodegradability and capacity for developing bacterial activity. Of the four organic materials, sheep and poultry manures and oak leaf evolved reducing conditions and sustained active sulphidogenesis, which coupled with the decrease in sulphate concentration indicated bacterial activity. Sheep manure was clearly the most successful organic material as electron donor (sulphate removal >99%), followed by poultry manure and oak leaf (sulphate removal of 80%). Compost appeared to be too poor in carbon to promote sulphate-reducing bacteria activity by itself. Column experiments emphasised the importance of considering the residence time as a key factor in the performance of continuous systems. With a residence time of 0.73 days, sheep manure did not promote sulphidogenesis. However, extending residence time to 2.4 and 9.0 days resulted in an increase in the sulphate removal to 18% and 27%, respectively.

  13. Characterisation of chemically-modified proteins by electrospray ionisation mass spectrometry

    International Nuclear Information System (INIS)

    Bennett, K.L.

    1996-09-01

    Electrospray mass spectrometry (ESI-MS) has been used to examine a range of intact monoclonal antibodies (MAbs), antibody fragments such as F(ab') 2 , F ab and F c , chemically-modified fragments and a range of other chemically-modified peptides and proteins as part of a broader study aimed at establishing ESI-MS as a method for the characterisation of radioimmunoconjugates (radiolabelled monoclonal antibodies). For example, the addition of up to 10 biotin molecules to the 'papain-sensitive' 50 kDa F ab fragment can be easily detected in ESI mass spectra. For intact MAbs, however, it is only possible to detect average shifts in the mass of intact antibodies following modification. Successful ESI-MS analysis of complexes formed between chelators and other small molecules conjugated to synthetic peptides, hen egg-white Iysozyme (HEL) (M r 14 306) and horse heart myoglobin (M r 16 951) has been demonstrated. ESI-MS offers considerable advantages compared with existing methods for the characterisation of chemically-conjugated proteins including speed and sensitivity of analysis and the capability for obtaining specific structural information. The conditions for ESI-MS of intact MAbs and MAb fragments have been examined in detail and it was found that 150 kDa MAbs generally required lower sample concentration and higher skimmer potentials compared with the 50 kDa F ab fragment and other lower molecular weight proteins. In addition, the m/z range over which ions from MAbs were observed was higher (m/z ∼2000-4500) than for smaller proteins. ESI-MS was also found to be useful for probing the action of the protease papain, that is used to generate MAb fragments (F(ab) '2, F ab and F c ). Further, different sensitivities to papain for different MAb preparations was demonstrated. Finally, the tandem mass spectra of a range of peptides modified by iodine and biotin were examined. In the case of biotinylated peptides, a characteristic fragment ion was identified that could

  14. Chemical characterisation of the globular cluster NGC 5634 associated to the Sagittarius dwarf spheroidal galaxy

    Science.gov (United States)

    Carretta, E.; Bragaglia, A.; Lucatello, S.; D'Orazi, V.; Gratton, R. G.; Donati, P.; Sollima, A.; Sneden, C.

    2017-04-01

    As part of our on-going project on the homogeneous chemical characterisation of multiple stellar populations in globular clusters (GCs), we studied NGC 5634, associated to the Sagittarius dwarf spheroidal galaxy, using high-resolution spectroscopy of red giant stars collected with VLT/FLAMES. We present here the radial velocity distribution of the 45 observed stars, 43 of which are cluster members, the detailed chemical abundance of 22 species for the seven stars observed with UVES-FLAMES, and the abundance of six elements for stars observed with GIRAFFE. On our homogeneous UVES metallicity scale, we derived a low-metallicity [Fe/H] =-1.867 ± 0.019 ± 0.065 dex (±statistical ±systematic error) with σ = 0.050 dex (7 stars). We found the normal anticorrelations between light elements (Na and O, Mg and Al), a signature of multiple populations typical of massive and old GCs. We confirm the associations of NGC 5634 to the Sgr dSph, from which the cluster was lost a few Gyr ago, on the basis of its velocity and position, and the abundance ratios of α and neutron capture elements. Based on observations collected at ESO telescopes under programme 093.B-0583.Table 2 is only available at the CDS via anonymous ftp to http://cdsarc.u-strasbg.fr (http://130.79.128.5) or via http://cdsarc.u-strasbg.fr/viz-bin/qcat?J/A+A/600/A118

  15. A review of chemical and physical characterisation of atmospheric metallic nanoparticles

    Science.gov (United States)

    Sanderson, Paul; Delgado-Saborit, Juana Maria; Harrison, Roy M.

    2014-09-01

    Knowledge of the human health impacts associated with airborne nanoparticle exposure has led to considerable research activity aimed at better characterising these particles and understanding which particle properties are most important in the context of effects on health. Knowledge of the sources, chemical composition, physical structure and ambient concentrations of nanoparticles has improved significantly as a result. Given the known toxicity of many metals and the contribution of nanoparticles to their oxidative potential, the metallic content of the nanoparticulate burden is likely to be an important factor to consider when attempting to assess the impact of nanoparticle exposure on health. This review therefore seeks to draw together the existing knowledge of metallic nanoparticles in the atmosphere and discuss future research priorities in the field. The article opens by outlining the reasons behind the current research interest in the field, and moves on to discuss sources of nanoparticles to the atmosphere. The next section reviews ambient concentrations, covering spatial and temporal variation, mass and number size distributions, air sampling and measurement techniques. Further sections discuss the chemical and physical composition of particles. The review concludes by summing up the current state of research in the area and considering where future research should be focused.

  16. Chemical characterisation of total suspended particulate matter from a remote area in Amazonia

    Science.gov (United States)

    Gonçalves, Cátia; Figueiredo, Bernardino R.; Alves, Célia A.; Cardoso, Arnaldo A.; da Silva, Rodrigo; Kanzawa, Simone H.; Vicente, Ana Margarida

    2016-12-01

    This research had as study object the total suspended particulate matter collected in the Alenquer region, a remote area in the Pará state. The main objectives were the characterisation of the inorganic and organic chemical composition of the aerosol, looking for seasonal patterns and the identification of probable emission sources and formation processes. A set of 30 samples were collected in the rainy (April-May) and dry season (August-September) of 2014. The analytical methods included gravimetric analysis, water-soluble ions analysis by ion chromatography (IC), elemental analysis by inductively coupled plasma mass spectrometry (ICP-MS) equipped with collision cell technology, carbonaceous content determination with a thermal-optical system and organic speciation by gas chromatography-mass spectrometry (GC-MS). The average concentrations of particulate matter ranged from 14 ± 1.3 μg·m- 3 to 31 ± 7.8 μg·m- 3, in the rainy and dry season, respectively. The carbonaceous content represented, on average, approximately 27% and 21% of the particulate matter in the rainy and dry season, respectively. Na+, Cl-, SO₄2 -, and NO₃- yield the highest concentrations in both seasons. Na was the dominant element, reflecting the transport of air masses from the Atlantic. An increase in concentrations between the rainy and dry seasons was especially noted for the terrigenous elements such Mn, Fe and Al. The chromatographically resolved organics included n-alkanes, n-alkenes, PAHs, n-alkanoic acids, n-di-acids, resin acids and some phenolic compounds. The primary inputs of organic constituents to the aerosols of Alenquer based on the homologous compound series and biomarkers were: (i) natural emissions from terrestrial higher plants waxes, particularly in dry season; (ii) anthropogenic emissions from diesel fuel combustion and biomass combustion, predominating during the dry season. The chemical characterisation along with the backward trajectory cluster analysis

  17. Chemical characterisation of zircon-cadmium sulfoselenide ceramic pigments; Caracterizacion quimica de pigmentos ceramicos a base de sulfoseleniuro de cadmio

    Energy Technology Data Exchange (ETDEWEB)

    Gazulla Barreda, M. F.; Rodrigo Edo, M.; Blasco Roca, E.; Orduna Cordero, M.

    2013-07-01

    The present paper addresses the development of a methodology that allows the complete chemical characterisation of zircon cadmium sulfoselenide ceramic pigments including minor and major elements. To develop the methodology, five zircon-cadmium sulfoselenide pigments with different hues were selected, studying the different measurement process steps, from sample preparation to the optimisation of the measurement of the different components of the pigments by spectroscopic techniques (WD-XRF and elemental analysis by combustion and IR detection). The chemical characterisation method developed was validated with synthetic standards prepared from the mixture of certified reference materials and pure oxides because no certified referenced materials of this type of pigments were commercially available. The developed method can be used for a complete chemical characterization of zircon-cadmium sulfoselenide ceramic pigments with a very low uncertainty for all the elements analysed. (Author)

  18. Mechanical and chemical characterisation of demineralised human dentine after amalgam restorations.

    Science.gov (United States)

    Toledano, Manuel; Aguilera, Fátima S; Osorio, Estrella; Cabello, Inmaculada; Toledano-Osorio, Manuel; Osorio, Raquel

    2015-07-01

    The purpose of this study was to evaluate the ability of Zn-free vs Zn-containing amalgams to induce remineralisation at the dentine interface. Sound and caries-affected dentine surfaces (CAD) were subjected to both Zn-free and Zn-containing dental amalgam restorations. Dentine surfaces were studied by nano-indentation, Raman spectroscopy/cluster analysis, X-ray diffraction (XRD), field emission electron microscope (FESEM) and energy-dispersive analysis (EDX), for mechanical, morphological and chemical characterisation. Analyses were performed before and after placement amalgam restorations. Zn-containing amalgams restorations promoted an increase in the nano-mechanical properties of sound and CAD surfaces. In samples from sound or CAD restored with Zn-containing amalgams, it was evidenced: (a) new mineral calcium-phosphate deposits (intratubular and intertubular) with augmented crystallographic maturity; these crystals were identified as hydroxyl-apatite, and (b) a generalised crosslinking reduction plus an increase in those values testing nature and secondary structure of collagen. It indicates an optimal preservation, molecular organisation and orientation of collagen fibrils. Zn-containing amalgams promote remineralisation of subjacent dentine, which is more evident in caries affected dentine surfaces. Copyright © 2015 Elsevier Ltd. All rights reserved.

  19. Chemical characterisation and source identification of atmospheric aerosols in the Snowy Mountains, south-eastern Australia.

    Science.gov (United States)

    Tadros, Carol V; Crawford, Jagoda; Treble, Pauline C; Baker, Andy; Cohen, David D; Atanacio, Armand J; Hankin, Stuart; Roach, Regina

    2018-02-24

    Characterisation of atmospheric aerosols is of major importance for: climate, the hydrological cycle, human health and policymaking, biogeochemical and palaeo-climatological studies. In this study, the chemical composition and source apportionment of PM 2.5 (particulate matter with aerodynamic diameters less than 2.5μm) at Yarrangobilly, in the Snowy Mountains, SE Australia are examined and quantified. A new aerosol monitoring network was deployed in June 2013 and aerosol samples collected during the period July 2013 to July 2017 were analysed for 22 trace elements and black carbon by ion beam analysis techniques. Positive matrix factorisation and back trajectory analysis and trajectory clustering methods were employed for source apportionment and to isolate source areas and air mass travel pathways, respectively. This study identified the mean atmospheric PM 2.5 mass concentration for the study period was (3.3±2.5)μgm -3 . It is shown that automobile (44.9±0.8)%, secondary sulfate (21.4±0.9)%, smoke (12.3±0.6)%, soil (11.3±0.5)% and aged sea salt (10.1±0.4)% were the five PM 2.5 source types, each with its own distinctive trends. The automobile and smoke sources were ascribed to a significant local influence from the road network and bushfire and hazard reduction burns, respectively. Long-range transport are the dominant sources for secondary sulfate from coal-fired power stations, windblown soil from the inland saline regions of the Lake Eyre and Murray-Darling Basins, and aged sea salt from the Southern Ocean to the remote alpine study site. The impact of recent climate change was recognised, as elevated smoke and windblown soil events correlated with drought and El Niño periods. Finally, the overall implications including potential aerosol derived proxies for interpreting palaeo-archives are discussed. To our knowledge, this is the first long-term detailed temporal and spatial characterisation of PM 2.5 aerosols for the region and provides a crucial

  20. A comprehensive characterisation of Asian dust storm particles: chemical composition, reactivity to SO2, and hygroscopic property

    OpenAIRE

    H. He; J. Ma; C. Liu; Y. Liu; Q. Ma

    2010-01-01

    Mineral dust comprises of a significant fraction of the globe's aerosol loading. Yet it remains the largest uncertainty in future climate predictions due to the complexity in its components and physico-chemical properties. Multi-analysis methods, including SEM-EDX, FTIR, BET, TPD/mass, and Knudsen cell/mass, were used in the present study to characterise Asian dust storm particles. The morphology, element fraction, source distribution, true uptake coefficient of SO2 and hygroscopic behaviour ...

  1. Physical and optical characterisation of carbon-silicon layers produced by rapid thermal chemical vapour deposition

    International Nuclear Information System (INIS)

    McBride, G.M.

    1994-04-01

    The Quplas II reactor is a novel chemical vapour deposition (CVD) system, which was recently designed and built at The Queen's University of Belfast. The system was intended to produce layers of Silicon (Si) for application in advanced bipolar transistor manufacture. It became clear that the system was capable of depositing novel materials such as Silicon-Carbon (Si-C) films which could have application as the emitter material in heterojunction bipolar transistors (HBT's) formed on silicon substrates. This work focuses mainly on the development of analytical techniques to allow characterisation of the deposited layers of Si-C and permit optimisation of both the process conditions and the deposition system. The techniques that were developed to characterise the Si-C films in terms of their physical and optical properties included: Secondary Ion Mass Spectroscopy (SIMS), X-Ray Diffractometry (XRD), Transmission and Scanning Electron Microscopy (TEM and SEM), Near Infrared (NIR) and Ultraviolet/Visible/Near Infrared (UV/VIS/NIR) Spectroscopy. From assessing the data obtained from the analysis of the samples using the techniques mentioned above, it was possible to characterise the Si-C films in terms of: stoichiometry, crystallinity, degree of oxygen contamination, thickness, optical roughness of the film/air and film/substrate interfaces, and energy bandgap. In the fabrication of Si-C films it was found to be necessary to use low process pressures in order to ensure that the film deposition was slow enough to allow for a more ordered growth process. This led to the formation of polycrystalline Si-C films which had greatly reduced levels of oxygen compared to earlier amorphous films. In addition the polycrystalline Si-C films tended to have optically rough film/air and film/substrate interfaces. For most samples it was possible to obtain the thickness of their Si-C films from their SIMS profiles. Based on the method of interferometry, the thickness of the Si-C films

  2. Materials characterisation

    International Nuclear Information System (INIS)

    Azali Muhammad

    2005-01-01

    Various nuclear techniques have been developed and employed by technologies and scientists worldwide to physically and chemically characterise the material particularly those that have applications in industry. These include small angle neutron scattering (SANS), x-ray diffraction (XRD), scanning electron microscope (SEM) and transmission electron microscope (TEM) for the internal structural study of material, whereas, the x-ray fluorescence (XRF) for the chemical analysis, while the Moessbauer spectroscopy for the study on the magnetic properties and structural identity of material. Basic principle and instrumentations of the techniques are discussed in this chapter. Example of their applications in various disciplines particularly in characterisation of industrial materials also described

  3. Not so pristine – characterising the physico-chemical conditions of ...

    African Journals Online (AJOL)

    2013-08-15

    Aug 15, 2013 ... Africa (Fig.1). Its main tributary, the Goukamma River, drains ..... Horizontal and vertical salinity gradients represented during the open (a) and closed (b) .... a drainage channel. DISCUSSION. South African TOCEs are typically characterised by the dynamic fluctuation in salinity and water level in response.

  4. WOMEN’S HEADDRESSES USED IN ANATOLIA

    Directory of Open Access Journals (Sweden)

    Başak BOĞDAY SAYĞILI

    2014-07-01

    Full Text Available In history, Anatolia has long been known to have a complex composition, due to its unique geographical location and its role as host to many cultures. Clothes and accessories have been influenced by this cultural diversity. Headdresses used in harmony with clothing and thought to complement it, have been important and indispensable accessories, varying in color, shape and texture according to the clothing worn. These could differ in simplicity or grandeur, and vary according to cultural diffe rences or those in socio - economic levels. No matter their social class, women never ceased wearing th ese complementary accessories. Visual sources on Anatolian clothing culture revealed that although headdresses are accessories complementing clothing, their attributes were never studied with a scientific approach, which has been influential in the choice of the subject matter of this study. The aim of this study is to identify and classify the attributes of traditional women’s headdresses used in Anatol ia and to specify that the examples recorded and photographed are used in Anatolia. Historical and review methods were used in the research. Sources were studied with help of the observation form used as a data collection tool to examine women’s headdresse s used in Anatolia.

  5. Nature, evolution and characterisation of rhizospheric chemical exudates affecting root herbivores

    OpenAIRE

    Hiltpold Ivan; Bernklau Elisa Jo; Bjostad Louis B.; Alvarez Nadir; Miller-Struttmann Nicole E.; Lundgren Jonathan G.; Hibbard Bruce E.

    2013-01-01

    Similar to aboveground herbivores root feeding insects must locate and identify suitable resources. In the darkness of soil they mainly rely on root chemical exudations and therefore have evolved specific behaviours. Because of their impact on crop yield most of our knowledge in belowground chemical ecology is biased towards soil dwelling insect pests. Yet the increasing literature on volatile mediated interactions in the ground underpins the great importance of chemical signalling in this ec...

  6. Simplified fate modelling in respect to ecotoxicological and human toxicological characterisation of emissions of chemical compounds

    NARCIS (Netherlands)

    Birkved, Morten; Heijungs, Reinout

    Purpose: The impact assessment of chemical compounds in Life Cycle Impact Assessment (LCIA) and Environmental Risk Assessment (ERA) requires a vast amount of data on the properties of the chemical compounds being assessed. The purpose of the present study is to explore statistical options for

  7. Physical, microscopic and chemical characterisation of industrial rye and wheat brans from the Nordic countries

    DEFF Research Database (Denmark)

    Kamal-Eldin, A; Lærke, Helle Nygaard; Bach Knudsen, Knud Erik

    2009-01-01

    and chemical composition including proximal components, vitamins, minerals and bioactive compounds. Results: Rye brans were generally greener in colour and smaller in particle size than wheat brans. The rye brans varied considerably in their starch content (13.2-28.3%), which reflected variable inclusion...... variation in the chemical composition of industrially produced rye brans calls for the need of standardisation of this commodity, especially when used as a functional ingredient in foods....

  8. Effects of chemical contamination on HDPE - thermo-mechanical and characterisation properties

    International Nuclear Information System (INIS)

    Ashraf, G.

    2002-01-01

    Studying the effects of chemical contamination on HDPE is an important precursor in recycling of plastic packaging and polymer reprocessing. This research involves and discusses the results of an in-depth investigation into the effects of chemically contaminating, using various acids, commercial grade high density polyethylene (HDPE) used commonly in packaging applications. An extensive formulation study was conducted and it became obvious that in some cases degradation had occurred to HDPE when chemically contaminated with particular functional group types. The functional groups in contaminated HDPE were successfully identified. A variety of analytical techniques such as Fourier transform Infra-red spectroscopy, X-ray Florescence, x-ray photo electron spectroscopy could identify compounds such as HCl acid, HNO/sub 3/ acid and other related contaminants. Some chemical additives had effects on the mechanical and thermal properties when added in the most appropriate concentration. The results have shown lower tensile modulus and strength tensile elongation, lower modular weight, melt flow index and crystallinity. The amount of contaminant concentration, the type of chemical functional groups used and the type of test selected to affect degradation are important factors in proving the effects of chemical contamination on HDPE in the melt state. (author)

  9. Chemical characterisation and bioactive properties of Prunus avium L.: the widely studied fruits and the unexplored stems.

    Science.gov (United States)

    Bastos, Claudete; Barros, Lillian; Dueñas, Montserrat; Calhelha, Ricardo C; Queiroz, Maria João R P; Santos-Buelga, Celestino; Ferreira, Isabel C F R

    2015-04-15

    The aim of this study was to characterise sweet cherry regarding nutritional composition of the fruits, and individual phytochemicals and bioactive properties of fruits and stems. The chromatographic profiles in sugars, organic acids, fatty acids, tocopherols and phenolic compounds were established. All the preparations (extracts, infusions and decoctions) obtained using stems revealed higher antioxidant potential than the fruits extract, which is certainly related with its higher phenolic compounds (phenolic acids and flavonoids) concentration. The fruits extract was the only one showing antitumor potential, revealing selectivity against HCT-15 (colon carcinoma) (GI50∼74 μg/mL). This could be related with anthocyanins that were only found in fruits and not in stems. None of the preparations have shown hepatotoxicity against normal primary cells. Overall, this study reports innovative results regarding chemical and bioactive properties of sweet cherry stems, and confirmed the nutritional and antioxidant characteristics of their fruits. Copyright © 2014 Elsevier Ltd. All rights reserved.

  10. Structural characterisation of silicon-germanium virtual substrate- based heterostructures grown by low pressure chemical vapour deposition

    CERN Document Server

    Mihai-Dilliway, G D

    2002-01-01

    Silicon-germanium heterostructures incorporating compositionally graded virtual substrates are important for the fabrication of a variety of advanced electronic devices. Their successful application depends critically on their surface morphology and defect content. The aim of this research project is to characterise the way in which these structural properties are influenced by the growth parameters used in low pressure chemical vapour deposition (LPCVD) at the Southampton University Microelectronics Centre (SUMC). To this end, a comparative study of the surface quality and the distribution and density of misfit strain relaxation induced defects in SiGe virtual substrate-based heterostructures grown under varying conditions, was carried out. The growth parameters varied have been: growth temperature, initial and final Ge content, Ge concentration gradient, type of Ge grading profile (linear and stepwise) in the virtual substrate, and thickness and presence of a device structure in the capping layer of constan...

  11. Coupling between cracking and chemical degradation in cement based materials: characterisation and modelling

    International Nuclear Information System (INIS)

    Tognazzi, C.

    1998-01-01

    The aim of this work is to study the durability of concretes used for radioactive waste storage. It has already been shown that the concrete degradation during a storage phenomenon is due to the attack of the cement barrier by the water of the host rock, at ambient temperature. The modelling of this chemical degradation is now validated for un-cracked materials. However, a concrete preexisting crack can exist. In this work, has then been particularly studied the influence of a crack on the long term chemical degradation. The studies have been carried out on a mortar cracked mechanically (in compression or traction) and chemically degraded by leaching (reference degradation) and by accelerated degradations (with ammonium nitrate or under electric field). The diffusion properties have been measured at each step of the experiment. They have been confronted with transfer models. Results have revealed the existence of a coupling between the preexisting crack and the chemical degradation. At last, a modelling of the chemical degradation for cement materials has been proposed and validated both for pure cement and for mortars, in the cases of simple leaching and of leaching with ammonium nitrate. Its application to cracked materials by a microscopic approach (crack described in the lattice) has allowed to specify the interpretation of the experimental results. (O.M.)

  12. Physical and chemical characterisation of silica based raw materials from industrial waste

    International Nuclear Information System (INIS)

    Samayamutthirian Palaniandy; Khairul Nizar Ismail; Khairun Azizi Mohd Azizli

    2002-01-01

    Silica sand and Pulverised Fuel Ash (PFA) is considered as silica based waste materials and it have variety of usage depending on its particle size and purity. Value adding of these raw materials will enhance the exploitation of these materials in various industries, The physical and chemical properties of these materials are essential that it will determine the utilization of these materials. The phase analysis, chemical composition, particle size distribution and the morphology of the materials were determined to investigate the appropriate utilization of these raw materials in various applications. Local PFA is considered class F and has various applications as construction materials. (Author)

  13. Physico-chemical and microbiological characterisation of Italian fermented sausages in relation to their size.

    Science.gov (United States)

    Tabanelli, Giulia; Bargossi, Eleonora; Gardini, Aldo; Lanciotti, Rosalba; Magnani, Rudy; Gardini, Fausto; Montanari, Chiara

    2016-06-01

    The aim of this work was to study the physico-chemical and microbiological parameters of 10 Italian fermented sausages, produced industrially, in order to highlight the differences in relation to their size. The sausages were classified as small, medium and large and the data concerning every feature considered were analysed with some statistical explorative tools: ANOVA, principal component analysis (PCA) and linear discriminant analysis (LDA). Significant differences in relation to the sausage size were found regarding microbial populations (in particular, enterobacteria and staphylococci). The pH was higher in the small sausages, and consequently the presence of lactate and acetate was higher in the bigger one. Also the biogenic amine content (particularly tyramine, cadaverine and putrescine) was influenced by the size. In spite of the extreme variability of the sausage types at the end of ripening, this work showed that it was possible to find a strict relationship between sausages diameter and some essential physico-chemical parameters. Thus, the cross-sectional size of the product is an essential parameter, which can drive the biochemical processes during ripening, not only by affecting the kinetics of water losses, but also by influencing the microbiota enzymatic activity. © 2015 Society of Chemical Industry. © 2015 Society of Chemical Industry.

  14. Acid-Base Chemistry of White Wine: Analytical Characterisation and Chemical Modelling

    Directory of Open Access Journals (Sweden)

    Enrico Prenesti

    2012-01-01

    Full Text Available A chemical model of the acid-base properties is optimized for each white wine under study, together with the calculation of their ionic strength, taking into account the contributions of all significant ionic species (strong electrolytes and weak one sensitive to the chemical equilibria. Coupling the HPLC-IEC and HPLC-RP methods, we are able to quantify up to 12 carboxylic acids, the most relevant substances responsible of the acid-base equilibria of wine. The analytical concentration of carboxylic acids and of other acid-base active substances was used as input, with the total acidity, for the chemical modelling step of the study based on the contemporary treatment of overlapped protonation equilibria. New protonation constants were refined (L-lactic and succinic acids with respect to our previous investigation on red wines. Attention was paid for mixed solvent (ethanol-water mixture, ionic strength, and temperature to ensure a thermodynamic level to the study. Validation of the chemical model optimized is achieved by way of conductometric measurements and using a synthetic “wine” especially adapted for testing.

  15. Lifetimes of organic photovoltaics: Combining chemical and physical characterisation techniques to study degradation mechanisms

    DEFF Research Database (Denmark)

    Norrman, K.; Larsen, N.B.; Krebs, Frederik C

    2006-01-01

    Degradation mechanisms of a photovoltaic device with an Al/C-60/C-12-PSV/PEDOT:PSS/ITO/glass geometry was studied using a combination of in-plane physical and chemical analysis techniques: TOF-SIMS, AFM, SEM, interference microscopy and fluorescence microscopy. A comparison was made between...

  16. Acid-base chemistry of white wine: analytical characterisation and chemical modelling.

    Science.gov (United States)

    Prenesti, Enrico; Berto, Silvia; Toso, Simona; Daniele, Pier Giuseppe

    2012-01-01

    A chemical model of the acid-base properties is optimized for each white wine under study, together with the calculation of their ionic strength, taking into account the contributions of all significant ionic species (strong electrolytes and weak one sensitive to the chemical equilibria). Coupling the HPLC-IEC and HPLC-RP methods, we are able to quantify up to 12 carboxylic acids, the most relevant substances responsible of the acid-base equilibria of wine. The analytical concentration of carboxylic acids and of other acid-base active substances was used as input, with the total acidity, for the chemical modelling step of the study based on the contemporary treatment of overlapped protonation equilibria. New protonation constants were refined (L-lactic and succinic acids) with respect to our previous investigation on red wines. Attention was paid for mixed solvent (ethanol-water mixture), ionic strength, and temperature to ensure a thermodynamic level to the study. Validation of the chemical model optimized is achieved by way of conductometric measurements and using a synthetic "wine" especially adapted for testing.

  17. Acid-Base Chemistry of White Wine: Analytical Characterisation and Chemical Modelling

    Science.gov (United States)

    Prenesti, Enrico; Berto, Silvia; Toso, Simona; Daniele, Pier Giuseppe

    2012-01-01

    A chemical model of the acid-base properties is optimized for each white wine under study, together with the calculation of their ionic strength, taking into account the contributions of all significant ionic species (strong electrolytes and weak one sensitive to the chemical equilibria). Coupling the HPLC-IEC and HPLC-RP methods, we are able to quantify up to 12 carboxylic acids, the most relevant substances responsible of the acid-base equilibria of wine. The analytical concentration of carboxylic acids and of other acid-base active substances was used as input, with the total acidity, for the chemical modelling step of the study based on the contemporary treatment of overlapped protonation equilibria. New protonation constants were refined (L-lactic and succinic acids) with respect to our previous investigation on red wines. Attention was paid for mixed solvent (ethanol-water mixture), ionic strength, and temperature to ensure a thermodynamic level to the study. Validation of the chemical model optimized is achieved by way of conductometric measurements and using a synthetic “wine” especially adapted for testing. PMID:22566762

  18. Chromatographic analysis with different detectors in the chemical characterisation and dereplication of African propolis.

    Science.gov (United States)

    Zhang, Tong; Omar, Ruwida; Siheri, Weam; Al Mutairi, Sultan; Clements, Carol; Fearnley, James; Edrada-Ebel, RuAngelie; Watson, David

    2014-03-01

    Propolis or bee glue has very diverse composition and is potentially a source of biologically active compounds. Comprehensive chemical profiling was performed on 22 African propolis samples collected from the sub-Saharan region of Africa by using various hyphenated analytical techniques including Liquid Chromatography (LC)-UltraViolet Detection (UV)-Evaporative Light Scattering Detection (ELSD), LC-High Resolution Mass Spectrometry (HRMS), Gas Chromatography (GC)-MS and LC-Diode Array Detector (DAD)-HRMS/MS. The diversity of the composition of these African propolis samples could be observed by heat mapping the LC-UV and ELSD data. The characteristic chemical components were uncovered by applying Principal Component Analysis (PCA) to the LC-HRMS data and a preliminary dereplication was carried out by searching their accurate masses in the Dictionary of Natural Products (DNP). A further identification was achieved by comparing their GC-MS or LC-DAD-HRMS/MS spectra with previously published data. Generally no clear geographic delineation was observed in the classification of these African propolis samples. Triterpenoids were found as the major chemical components in more than half of the propolis samples analysed in this study and some others were classified as temperate and Eastern Mediterranean type of propolis. Based on the comparative chemical profiling and dereplication studies one uncommon propolis from southern Nigeria stood out from others by presenting prenylated isoflavonoids, which indicated that it was more like Brazilian red propolis, and more significantly a high abundance of stilbenoid compounds which could be novel in propolis. Copyright © 2013 Elsevier B.V. All rights reserved.

  19. Chemical synthesis, characterisation, analytical method development and control to promote exposure assessments and toxicological testing. Highlights from COMPARE

    Energy Technology Data Exchange (ETDEWEB)

    Bergman, Aa.; Malmberg, T.; Weiss, J. [Stockholm Univ. (Sweden). Dept. of Environmental Chemistry

    2004-09-15

    The issue of endocrine disruptor effects in wildlife and humans grow increasingly important during the 1990s'. As part of the focus on endocrine disruptors new contaminants and their metabolites were put forward for studies with endpoints related to hormone disruption. One such large group of chemicals and/or metabolites of neutral semi-persistent or persistent compounds was the substituted phenols, particularly the halogenated phenolic compounds (HPCs). Polychlorobiphenylols (OHPCBs) were reported to be strongly retained in human blood plasma in 1995 and this article was the first study to point out the general retention of several OH-PCBs in the plasma. The metabolic formation of OH-PCBs was well known and the specific blood retention had been reported for at least one PCB congener, 3,3',4,4'-tetrachlorobiphenyl (CB-77) in some previous studies. The identification of OH-PCBs being retained in blood and their specific binding to transthyretin (TTR) has formed much of the basis for two EU R and D programs, first RENCO and now COMPARE. The present report is aimed to highlight some of the results obtained within the COMPARE program mainly dealing with the chemical synthesis, characterisation and analytical aspects of HPCs.

  20. Characterisation of chemical components for identifying historical Chinese textile dyes by ultra high performance liquid chromatography – photodiode array – electrospray ionisation mass spectrometer

    NARCIS (Netherlands)

    Han, J.; Wanrooij, J.; van Bommel, M.; Quye, A.

    2017-01-01

    This research makes the first attempt to apply Ultra High Performance Liquid Chromatography (UHPLC) coupled to both Photodiode Array detection (PDA) and Electrospray Ionisation Mass Spectrometer (ESI–MS) to the chemical characterisation of common textile dyes in ancient China. Three different

  1. Pulsed injection metal organic chemical vapour deposition and characterisation of thin CaO films

    Energy Technology Data Exchange (ETDEWEB)

    Borges, R.P., E-mail: rpborges@fc.ul.p [Centro de Fisica da Materia Condensada, Universidade de Lisboa, Campo Grande, Ed. C8, 1749-016 Lisboa (Portugal); Ferreira, P. [Departamento de Engenharia Ceramica e do Vidro, CICECO, Universidade de Aveiro, Campus Universitario de Santiago, 3810-193 Aveiro (Portugal); Saraiva, A. [Centro de Fisica da Materia Condensada, Universidade de Lisboa, Campo Grande, Ed. C8, 1749-016 Lisboa (Portugal); Goncalves, R., E-mail: rjbarrosog@hotmail.co [Centro de Fisica da Materia Condensada, Universidade de Lisboa, Campo Grande, Ed. C8, 1749-016 Lisboa (Portugal); Rosa, M.A. [Centro de Fisica da Materia Condensada, Universidade de Lisboa, Campo Grande, Ed. C8, 1749-016 Lisboa (Portugal); Goncalves, A.P. [Centro de Fisica da Materia Condensada, Universidade de Lisboa, Campo Grande, Ed. C8, 1749-016 Lisboa (Portugal); Departamento de Quimica, Instituto Tecnologico e Nuclear, P-2686-953 Sacavem (Portugal); Silva, R.C. da [Laboratorio de Feixe de Ioes, Dep. Fisica, Instituto Tecnologico e Nuclear, Estrada Nacional 10, 2686-953 Sacavem (Portugal); Centro de Fisica Nuclear da Universidade de Lisboa, Av. Prof. Gama Pinto 2, 1649-003 Lisboa (Portugal); Magalhaes, S. [Laboratorio de Feixe de Ioes, Dep. Fisica, Instituto Tecnologico e Nuclear, Estrada Nacional 10, 2686-953 Sacavem (Portugal); Lourenco, M.J.V.; Santos, F.J.V. [Centro de Ciencias Moleculares e Materiais, Faculdade de Ciencias da Universidade de Lisboa, Campo Grande, Ed. C8, 1749-016, Lisboa (Portugal); Departamento de Quimica e Bioquimica, Faculdade de Ciencias da Universidade de Lisboa, Campo Grande, Ed. C8, 1749-016 Lisboa (Portugal); Godinho, M. [Centro de Fisica da Materia Condensada, Universidade de Lisboa, Campo Grande, Ed. C8, 1749-016 Lisboa (Portugal); Dep. de Fisica, Faculdade de Ciencias, Universidade de Lisboa, Campo Grande, Ed. C8, 1749-016 Lisboa (Portugal)

    2009-05-01

    Thin films of CaO were grown on silicon (Si) and lanthanum aluminate (LaAlO{sub 3}) substrates by pulsed injection metal-organic chemical vapour deposition in a vertical injection MOCVD system. Growth parameters were systematically varied to study their effect on film growth and quality and to determine the optimal growth conditions for this material. Film quality and growth rate were evaluated by atomic force microscopy, X-ray diffraction and Rutherford Backscattering Spectroscopy measurements. Optimised conditions allowed growing transparent, single phase films textured along the (0 0 l) direction.

  2. Kefir grains as a starter for whey fermentation at different temperatures: chemical and microbiological characterisation.

    Science.gov (United States)

    Londero, Alejandra; Hamet, María F; De Antoni, Graciela L; Garrote, Graciela L; Abraham, Analía G

    2012-08-01

    We report here a comparative analysis of the growth, acidification capacity, and chemical and microbiologic composition between kefir grains after 20 subcultures in whey at 20, 30, and 37°C and the original kefir grains coming from milk along with a determination of the microbiological composition of the fermented whey as compared with that of traditional fermented milk. When fermentation was carried out repeatedly at 30 or 37°C, kefir grains changed their kefir-like appearance, exhibited reduced growth rates, had a lower diversity of yeasts and water content, and a higher protein-to-polysaccharide ratio compared with the original kefir grains. In contrast, at 20°C kefir grains could remain in whey for prolonged periods without altering their acidification capacity, growth rate, macroscopic appearance or chemical and microbiologic composition-with the only difference being a reduction in certain yeast populations after 20 subcultures in whey. At this incubation temperature, the presence of Lactobacillus kefiranofaciens, Lb. kefir, Lb. parakefir, Lactococcus lactis, Kluyveromyces marxianus, Saccharomyces unisporus, and Sac. cerevisiae was detected in kefir grains and in fermented whey by denaturing-gradient-gel electrophoresis (DGGE). In whey fermented at 20°C the number of lactic-acid bacteria (LAB) was significantly lower (Pkefir grains as whey-fermentation starters.

  3. Physico-chemical characterisation of some samples of fresh milk and milk powder

    Directory of Open Access Journals (Sweden)

    Soceanu Alina

    2015-12-01

    Full Text Available Milk consumption is important in the diet of all age groups because it provides important nutrients that are essential for humans. Children are the largest consumers of milk, thus, it’s very important that milk is free of toxic compounds that can be harmful for humans. Aim of the study was to determine the physico-chemical characteristics of some samples of milk powder for different stage of baby growing and for some samples of fresh milk: raw cow’s milk, milk trade and UHT type. The following physico-chemical properties: density, pH, acidity, the presence of acetone, enzymes, antiseptics, dry substance, the ash, total fat, saponification and peroxide index, total nitrogen and protein content were determined. Comparing the values of acidity for analyzed samples it can be concluded that the powder milk acidity value is much lower than the fresh milk. The presence of antiseptics and acetone was not identified, and amylase and peroxidase were found only in raw cow's milk. The highest protein content was found for milk powder (27.22%.

  4. An Investigation of Seismicity for Western Anatolia

    International Nuclear Information System (INIS)

    Sayil, N.

    2007-01-01

    In order to determine the seismicity of western Anatolia limited with the coordinates of 36degree-40degreeN, 26degree-32degreeE, Gutenberg-Richter magnitude-frequency relation, seismic risk and recurrence period have been computed. The data belonging to both the historical period before 1900 (I0 3 6.0 corresponding to MS 3 5.0) and the instrumental period until 2005 (MS 3 4.0) have been used in the analysis. The study area has been divided into 13 sub-regions due to certain seismotectonic characteristics, plate tectonic models and geology of the region. Computations from a and b parameters and seismic risk and recurrence period for each sub-regions have showed that subregions 1 and 8 (Balikesir and Izmir-Sakiz Island), where have the lowest b values, have the highest risks and the shortest recurrence periods

  5. Chemical and physicochemical characterisation of co-products from the vegetable food and agro industries

    DEFF Research Database (Denmark)

    Serena, Anja; Bach Knudsen, Knud Erik

    2007-01-01

    Six co-products from the vegetable food and agro industres in Denmark - brewer's spent grain, pea hull, seed residue (rye grass), potato pulp, sugar beet pulp and pectin residue - were collected eight times during two seasons (four samples from each season) (n = 8; N = 48). The samples were......) and protein (61-116 g/kg DM) content and a high content of non-starch polysaccharide (430-743 g/kg DM). Exceptions, however, were seed residue and pea hull which had a DM content of 896-923 g/kg as is, and brewer's spent grain which had a EE and protein content of 117 and 215 g/kg DM, respectively. The sugar...... DF content resulting in high swelling and WBC and relatively low EDOM. The variability in chemical composition of most co-products was in the same relative range as found for barley and wheat in other national and Scandinavian studies....

  6. Fermentation kinetics and chemical characterisation of vino tostado, a traditional sweet wine from Galicia (NW Spain).

    Science.gov (United States)

    Cortés, Sandra; Salgado, José M; Rivas, Beatriz; Torrado, Ana M; Domínguez, José M

    2010-01-15

    Grapes after harvesting are air dried and pressed in order to concentrate sugars, acids and flavour compounds to produce vino tostado (toasted wine), a wine with intense aroma and flavour notes and high residual sugar concentration. In order to get a better knowledge of the difficulties involved, several fermentations were conducted at 12 and 28 degrees C using 0, 15 and 30 g hL(-1) ammonium sulfate and 0, 25 and 50 g hL(-1) exogenous commercial yeast (Saccharomyces cerevisiae var. bayanus) to study the kinetics of sugar consumption and ethanol, acetic acid and glycerol production. Fermentation kinetic parameters were calculated and metal concentrations and antioxidant activity were analysed. The spontaneous fermentation at 12 degrees C and all fermentations conducted with the commercial yeast gave vino tostado of adequate quality, while the spontaneous fermentation at 28 degrees C was sluggish. High-temperature fermentations led to sweeter wines with higher volumetric productivities, although low-temperature fermentations produced better wines in terms of higher glycerol and lower acetic acid levels. Fructose was the only sugar to be consumed during spontaneous fermentations, while both glucose and fructose were consumed during fermentations of the inoculated musts, with preference for each monosaccharide depending on temperature. Copyright (c) 2009 Society of Chemical Industry.

  7. Chemical characterisation of semi-volatile and aerosol compounds from the photooxidation of toluene and NOx

    Science.gov (United States)

    White, Stephen J.; Jamie, Ian M.; Angove, Dennys E.

    2014-02-01

    The chemical composition of a gas phase and secondary organic aerosol (SOA) mixture from toluene photooxidation in NOx was determined. Aerosol from toluene photooxidation was generated in a smog chamber and was collected onto glass fibre filters along with those gas phase compounds which adhered to the filter. The filter bound organic material was extracted, derivatised with O-2,3,4,5,6-pentafluorobenzyl hydroxylamine (PFBHA) and N,O-bistrimethylsilyl-trifluoroacetamide (BSTFA), then analysed using gas chromatography-mass spectrometry (GC-MS). Compound identification was aided by the use of isotopically-labelled toluene. The effect of humidity on product formation was investigated by raising water vapour concentration in one experiment. Sixty compounds were identified, of which twenty had not been identified from toluene photooxidation previously. Small carboxylic acids and dicarbonyls provided the highest proportion of identifiable compounds by relative response. The use of water to extract the filter samples resulted in much higher relative responses for oxocarboxylic acids, such as glyoxylic acid and pyruvic acid, than has been observed in previous studies. The formation of levulinic acid was determined to be due to the reaction of water with aromatic photooxidation products in the gas phase or particle phase of the chamber experiment. Nuclear magnetic resonance (NMR) was used to determine the functional groups of water-extracted organic material, which indicated that the water-soluble components were comprised of compounds which contain similar functional groups, primarily alcohols and carboxylic acids.

  8. Physico-chemical characterisation of the fat from red-skin rambutan (Nephellium lappaceum L.) seed.

    Science.gov (United States)

    Manaf, Yanty Noorziana Abdul; Marikkar, Jalaldeen Mohammed Nazrim; Long, Kamariah; Ghazali, Hasanah Mohd

    2013-01-01

    The seeds (6.9±0.2% by weight of fruit) of the red-skin rambutan (Nephelium lappaceum L.) contain a considerable amount of crude fat (38.0±4.36%) and thus, the aim of the study was to determine the physico-chemical properties of this fat for potential applications. The iodine and saponification values, and unsaponifiable matter and free fatty acid contents of the seed fat were 50.27 g I2/100g fat, 182.1 mg KOH/g fat, 0.8% and 2.1%, respectively. The fat is pale yellow with a Lovibond color index of 3.1Y+1.1R. The fatty acid profile indicates an almost equal proportion of saturated (49.1%) and unsaturated (50.9%) fatty acids, where oleic (42.0%) and arachidic (34.3%) acids were the most dominant fatty acids. It also contained small amounts of stearic (8.0%), palmitic (4.6%), gadoleic (5.9%), linoleic (2.2%), behenic (2.1%) palmitoleic (0.7%) myristic (0.1%) and erucic (0.1%) acids. HPLC analysis showed that the fat comprised mainly unknown triacylglycerols (TAG) with high retention times indicating they have higher carbon numbers compared with many vegetable oils. The fat has melting and cooling points of 44.2°C and -42.5°C, respectively, making it a semi-solid at room temperature. The solid content at 0°C was 53.5% and the fat melted completely at 40°C. z-Nose analysis showed that the presence of high levels of volatile compounds in red-skin rambutan seed and seed fat.

  9. Chemical characterisation of Nigerian red propolis and its biological activity against Trypanosoma Brucei.

    Science.gov (United States)

    Omar, Ruwida M K; Igoli, John; Gray, Alexander I; Ebiloma, Godwin Unekwuojo; Clements, Carol; Fearnley, James; Ebel, Ru Angeli Edrada; Zhang, Tong; De Koning, Harry P; Watson, David G

    2016-01-01

    A previous study showed the unique character of Nigerian red propolis from Rivers State, Nigeria (RSN), with regards to chemical composition and activity against Trypanosoma brucei in comparison with other African propolis. To carry out fractionation and biological testing of Nigerian propolis in order to isolate compounds with anti-trypanosomal activity. To compare the composition of the RSN propolis with the composition of Brazilian red propolis. Profiling was carried out using HPLC-UV-ELSD and HPLC-Orbitrap-FTMS on extracts of two samples collected from RSN with data extraction using MZmine software. Isolation was carried out by normal phase and reversed phase MPLC. Elucidation of the compounds with a purity > 95% was performed by 1D/2D NMR HRMS and HRLC-MS(n) . Ten phenolic compounds were isolated or in the case of liquiritigenin partially purified. Data for nine of these correlated with literature reports of known compounds i.e. one isoflavanone, calycosin (1); two flavanones, liquiritigenin (2) and pinocembrin (5); an isoflavan, vestitol (3); a pterocarpan, medicarpin (4); two prenylflavanones, 8-prenylnaringenin (7) and 6-prenylnaringenin (8); and two geranyl flavonoids, propolin D (9) and macarangin (10). The tenth was elucidated as a previously undescribed dihydrobenzofuran (6). The isolated compounds were tested against Trypanosoma brucei and displayed moderate to high activity. Some of the compounds tested had similar activity against wild type T. brucei and two strains displaying pentamidine resistance. Nigerian propolis from RSN has some similarities with Brazilian red propolis. The propolis displayed anti-trypanosomal activity at a potentially useful level. Copyright © 2015 John Wiley & Sons, Ltd.

  10. Physio-chemical, microbiological properties of tempoyak and molecular characterisation of lactic acid bacteria isolated from tempoyak.

    Science.gov (United States)

    Chuah, Li-Oon; Shamila-Syuhada, Ahamed Kamal; Liong, Min Tze; Rosma, Ahmad; Thong, Kwai Lin; Rusul, Gulam

    2016-09-01

    This study aims to determine physio-chemical properties of tempoyak, characterise the various indigenous species of lactic acid bacteria (LAB) present at different stages of fermentation and also to determine the survival of selected foodborne pathogens in tempoyak. The predominant microorganisms present in tempoyak were LAB (8.88-10.42 log CFU/g). Fructobacillus durionis and Lactobacillus plantarum were the dominant members of LAB. Other LAB species detected for the first time in tempoyak were a fructophilic strain of Lactobacillus fructivorans, Leuconostoc dextranicum, Lactobacillus collinoides and Lactobacillus paracasei. Heterofermentative Leuconostoc mesenteroides and F. durionis were predominant in the initial stage of fermentation, and as fermentation proceeded, F. durionis remained predominant, but towards the end of fermentation, homofermentative Lb. plantarum became the predominant species. Lactic, acetic and propionic acids were present in concentrations ranging from 0.30 to 9.65, 0.51 to 7.14 and 3.90 to 7.31 mg/g, respectively. Genotyping showed a high degree of diversity among F. durionis and Lb. plantarum isolates, suggesting different sources of LAB. All tested Lb. plantarum and F. durionis (except for one isolate) isolates were multidrug resistant. Salmonella spp., Listeria monocytogenes and Staphylococcus aureus were not detected. However, survival study showed that these pathogens could survive up to 8-12 days. The results aiming at improving the quality and safety of tempoyak. Copyright © 2016 Elsevier Ltd. All rights reserved.

  11. Characterisation of chemical composition and energy content of green waste and municipal solid waste from Greater Brisbane, Australia.

    Science.gov (United States)

    Hla, San Shwe; Roberts, Daniel

    2015-07-01

    The development and deployment of thermochemical waste-to-energy systems requires an understanding of the fundamental characteristics of waste streams. Despite Australia's growing interest in gasification of waste streams, no data are available on their thermochemical properties. This work presents, for the first time, a characterisation of green waste and municipal solid waste in terms of chemistry and energy content. The study took place in Brisbane, the capital city of Queensland. The municipal solid waste was hand-sorted and classified into ten groups, including non-combustibles. The chemical properties of the combustible portion of municipal solid waste were measured directly and compared with calculations made based on their weight ratios in the overall municipal solid waste. The results obtained from both methods were in good agreement. The moisture content of green waste ranged from 29% to 46%. This variability - and the tendency for soil material to contaminate the samples - was the main contributor to the variation of samples' energy content, which ranged between 7.8 and 10.7MJ/kg. The total moisture content of food wastes and garden wastes was as high as 70% and 60%, respectively, while the total moisture content of non-packaging plastics was as low as 2.2%. The overall energy content (lower heating value on a wet basis, LHVwb) of the municipal solid waste was 7.9MJ/kg, which is well above the World Bank-recommended value for utilisation in thermochemical conversion processes. Copyright © 2015 Elsevier Ltd. All rights reserved.

  12. The Geoelectrical Structure of Northwestern Anatolia, Turkey

    Science.gov (United States)

    Ulugergerli, E. U.; Seyitoğlu, G.; Başokur, A. T.; Kaya, C.; Dikmen, U.; Candansayar, M. E.

    2007-05-01

    The magnetotelluric method has been employed to generate a geoelectrical model that will reveal the rich geological pattern and dynamic character of western and northwestern Anatolia, Turkey. Magnetotelluric data were collected from 53 sites along a profile of 290 km from the Dardanelles to the Alaşehir Graben. Magnetotelluric data were in the range of 0.00055 Hz to 320 Hz. The models were obtained through 2-D joint inversion of transverse electric and transverse magnetic modes. Lateral changes in geoelectrical models are verified by using gravity and magnetic data. In addition, some of the seismological data presented here agree with proposed models that suggest a brittle-ductile structure boundary at a depth of 20 km. Generally speaking, a regional extensional regime caused reduction in the thickness of the crust and consequent uplift towards the south. The constructed model delineates the western part of the North Anatolian Fault Zone along the Biga Peninsula. The current patterns of volcanic activity on the Biga Peninsula and at Kula are related to conductive spots presented in the models. The border of the Gördes Basin, located between the Izmir - Ankara suture zone and the Menderes Massif, is also well delineated. The North Anatolian Fault Zone presents a pattern in which density and susceptibility anomalies attain relatively high values. Fillings covering most of the surface have lower density and susceptibility values than those of underlying structures.

  13. Physico-chemical analysis of industrial catalysts a practical guide to characterisation; Analyse physico-chimique des catalyseurs industriels. Manuel pratique de caracterisation

    Energy Technology Data Exchange (ETDEWEB)

    Lynch, J.

    2003-09-01

    This book describes the principal physico-chemical techniques for characterising the catalysts used in searching for new active phases, optimising the formulation and monitoring industrial production. Based on courses given at the Institut Francais du Petrole for research technicians in the fields of kinetics and catalysis, this book covers useful basic theory and provides numerous examples of industrial applications. This guide is an essential companion for technicians and chemical engineers whose work requires an understanding of the fields of application, including the capabilities and the limits of today's complex characterisation techniques. Contents: Introduction. 1. Textural characterisation of catalysts. 2. Atomic absorption spectrometry. 3. Atomic emission spectroscopy. 4. X-ray fluorescence. 5. X-ray photoelectron spectroscopy. 6. Ion impact analysis. 7. Scanning electron microscopy. 8. Elemental analysis in the electron microprobe. 9. Transmission electron microscopy. 10. X-ray diffraction and small-angle scattering. 11. Exafs. 12. Infrared absorption spectrometry. 13. Nuclear magnetic resonance. 14. Thermal analysis methods. Index.

  14. Porewater Chemistry in Compacted Re-Saturated MX-80 Bentonite: Physico-Chemical Characterisation and Geochemical Modelling

    International Nuclear Information System (INIS)

    Bradbury, M. H.; Baeyens, B.

    2002-06-01

    as =SOH, = SOH 2 and =SO - . In the report it is explained how this speciation is determined by the preparation process in the 'as received' powder. As a consequence of the high cation exchange capacity of montmorillonite, the large mass of montmorillonite in relation to the small pore water volumes in a highly compacted re-saturated bentonite, the major ion composition in the pore water will be controlled by the montmorillonite and the other solid phases present and will be very strongly buffered. The above considerations are used in conjunction with detailed physico-chemical characterisation studies on MX-80 (Appendix) to calculate initial pore water compositions in compacted bentonites. For the MX-80 material specified, the pore waters calculated for initial dry densities between 1200 and 1600 kg m -3 had relatively high ionic strengths (0.3 to 0.33 M), similar cation concentrations and a pH equal to 8.0. The pore waters changed from being Na 2 SO 4 rich at 1200 kg m -3 to a NaCI/Na 2 SO 4 type water at 1600 kg m -3 . (author)

  15. Toxic gas emissions from the Kayseri peat deposit, central Anatolia ...

    Indian Academy of Sciences (India)

    Toxic gas emissions from the Kayseri peat deposit, central Anatolia, Turkey ... The main volatile species detected are methane (CH4), hydrogen sulphide (H2S) and carbon dioxide (CO2), all of which are highly toxic. The primary means of ... Environmental Engineering Department, Nigde University, 51245 Nigde, Turkey.

  16. Late Miocene Sciuridae (Mammalia, Rodentia) from Anatolia, Turkey

    NARCIS (Netherlands)

    Bosma, A.A.; de Bruijn, H.; Wessels, W.

    Isolated cheek teeth of Sciuridae (Rodentia, Mammalia) from nine late Miocene localities in central Anatolia (Turkey) are described. The teeth represent at least 12 different species, five of which belong to the ground squirrel genus Tamias, two to the ground squirrel genus Spermophilinus, one to

  17. Hyurterianum (Asteraceae, Inuleae), a new species from NE Anatolia, Turkey

    DEFF Research Database (Denmark)

    Gemici, Y.; Tan, K.; Yidirim, H.

    2008-01-01

    Helichrysum yurterianum Y. Gemici, Kit Tan, H. Yildirim & M. Gemici (Asteraceae, Inuleae) is described and illustrated. It is a serpentine endemic restricted to the province of Erzincan in NE Anatolia, Turkey. Its affinities are with H. arenarium and H. noeanum, which both have a wider distribution...

  18. Saponaria emineana (Caryophyllaceae), a new species from inner Anatolia, Turkey

    DEFF Research Database (Denmark)

    Gemici, Yusuf; Tan, Kit; Yildirim, H.

    2011-01-01

    Saponaria emineana (Caryophyllaceae) is illustrated and described as a new species endemic to the inner part of West Anatolia, Turkey. It is related to S. pamphylica and differs from that species in having a densely tufted habit with compact and much-branched woody base, subfleshy, narrowly...

  19. Heliotropium thermophilum (Boraginaceae), a new taxon from SW Anatolia, Turkey

    DEFF Research Database (Denmark)

    Tan, Kit; Celik, Ali; Gemici, Yusuf

    2008-01-01

    Heliotropium thermophilum Kit Tan, A. Çelik & Y. Gemici (Boraginaceae), is described as a species new to science and illustrated. Its diploid chromosome number of 2n = 16 is a first report. It is restricted to the province of Aydin bordering on Denizli in SW Anatolia and is of interest on account...

  20. Verbascum lindae (Scrophulariaceae), a new species from SW Anatolia, Turkey

    DEFF Research Database (Denmark)

    Parolly, Gerald; Tan, Kit

    2007-01-01

    Verbascum lindae, a taxonomically isolated limestone chasmophyte from the vilayet of Isparta in SW Anatolia is described as a species new to science and illustrated. Its affinities with other Anatolian Verbascum species, which have either a chasmophytic habit or at least a woody base, are discussed....

  1. Lifetimes of organic photovoltaics: Using TOF-SIMS and 18O2 isotopic labelling to characterise chemical degradation mechanisms

    DEFF Research Database (Denmark)

    Norrman, K.; Krebs, Frederik C

    2006-01-01

    The lifetimes of organic photovoltaic cells based on conjugated polymer materials were studied. The device geometry was glass:ITO:PEDOT:PSS:C-12-PSV:C-60:aluminium. To characterise and elucidate the parts of the degradation mechanisms induced by molecular oxygen, 1802 isotopic labelling was emplo......The lifetimes of organic photovoltaic cells based on conjugated polymer materials were studied. The device geometry was glass:ITO:PEDOT:PSS:C-12-PSV:C-60:aluminium. To characterise and elucidate the parts of the degradation mechanisms induced by molecular oxygen, 1802 isotopic labelling...... throughout the active layer with the largest concentration towards the aluminium electrode. For devices that had been kept in the dark oxygen species were only observed at the immediate interface between the aluminium and the organic layer. The isotopic labelling allowed us to demonstrate that the oxygen...

  2. A new species of Marrubium (Lamiaceae) from Central Anatolia, Turkey

    OpenAIRE

    AYTAÇ, Zeki; AKGÜL, Gencay; EKİCİ, Murat

    2014-01-01

    Marrubium sivasense Aytaç, Akgül & Ekici sp. nova (Lamiaceae) is described and illustrated from Central Anatolia, Turkey. The new species most resembles Marrubium depauperatum, but it differs by 3-10 flowered verticillasters, crenate to crenulated leaf margins, and unequal calyx teeth. The ecology and phenology of the new species as well as its etymology, conservation status, and diagnostic features are discussed.

  3. A Sub-Microanalysis Approach in Chemical Characterisation of Gold Nanorods Formed by a Novel Polymer-Immobilised Gold Seeds Base

    Directory of Open Access Journals (Sweden)

    Majid Kazemian Abyaneh

    2017-10-01

    Full Text Available Gold nanorods (GNRs have been fabricated by a novel polymer-immobilised seed mediated method using ultraviolet (UV photoreduced gold-polymethylmethacrylate (Au–PMMA nanocomposites as a seed platform and characterised at sub-micron scale regime with synchrotron-based techniques; near-edge X-ray absorption fine structure (NEXAFS spectroscopy and X-ray fluorescence (XRF mapping. In this report, it is shown that investigating polymer nanocomposites using combination of XRF mapping and NEXAFS spectromicroscopy can help to see the growth phenomenon from different perspective than conventional characterisation techniques. XRF maps are used to explore distribution of the constituent elements and showing how polymer matrix making stripe patterns along with regions where GNRs are formed. NEXAFS carbon (C K-edge spectra have been taken at three different stages of synthesis: (1 on Au–PMMA nanocomposites before UV irradiation, (2 after gold nanoparticles formation, and (3 after GNRs formation. It reveals how polymer matrix has been degraded during GNRs formation and avoiding chemically or physically damage to polymer matrix is crucial to control the formation of GNRs.

  4. Physico-chemical characterisation of particulate heavy metals from municipal solid waste incinerator emissions and their contributions to ambient air quality. Case of Toulon MSWI (South of France)

    International Nuclear Information System (INIS)

    Le Floch, M.

    2004-07-01

    The aims of this study are the physico-chemical characterisation, the apportionment and the following of particulate heavy metals from MSWI emissions. Various methods (in situ data treatment, unmixing models and codes, UNMIX or CMB, sequential extractions and extended X-ray absorption fine structure (EXAFS) agree in the following: - identification of the MSWI source in two profiles (Zn - Ca and Ba - Cu - Fe - Zn - Pb - Ca); - estimation of its contribution of up to 25% of the total sources contribution; - showing the seasonal variability in term of profile and contribution of this source; - suggest the potential of emitted elements to enter the food chain; This EXAFS first approach on atmospheric particulate matter shows that zinc and lead are in an atomic environment with calcium, silicon and aluminum. In spite of disputable conclusions, isotopic lead ratios define a 'MSWI' end-member and confirm that the town-center of Toulon is outside the MSWI plume influence. (author)

  5. SU-8 cantilevers for bio/chemical sensing; Fabrication, characterisation and development of novel read-out methods

    DEFF Research Database (Denmark)

    Nordström, M.; Keller, Stephan Urs; Lillemose, Michael

    2008-01-01

    Here, we present the activities within our research group over the last five years with cantilevers fabricated in the polymer SU-8. We believe that SU-8 is an interesting polymer for fabrication of cantilevers for bio/chemical sensing due to its simple processing and low Young's modulus. We show...

  6. Characterisation and origin of hydrothermal waters at São Miguel (Azores) inferred by chemical and isotopic composition

    Science.gov (United States)

    Woitischek, Julia; Dietzel, Martin; Inguaggiato, Claudio; Böttcher, Michael E.; Leis, Albrecht; Cruz, J. Virgílio; Gehre, Matthias

    2017-10-01

    This study focuses on the characterisation and origin of hydrothermal waters discharging from three main active volcanoes (Furnas, Fogo and Sete Cidades) at São Miguel, where 33 water with temperatures ranging between 13 and 97 °C, and 5 precipitate samples were collected. The developed conceptual model for this active hydrothermal system reveals that all waters can be classified by Na-HCO3, Na-Cl and Na-SO4 types and are of meteoric origin. This is confirmed by the stable hydrogen and oxygen isotope data that are positioned close to the local meteoric water line (- 4.1‰ ≤ δ18OH2O ≤ 5.2‰; - 17.6‰ ≤ δDH2O ≤ 20.4‰), except for the Na-Cl type water at Ferraria (Sete Cidades area), which is characterized by admixing of seawater. The stable isotope composition of São Miguel hydrothermal solutions (δ34SSO4 range from 21.3 to - 3.7; δ18OSO4 range between 0.5 and 10.5‰; δ13CTDIC = - 4.5 ± 3.2‰) indicate that waters are individually evolved by several processes: evaporation, uptake of volcanogenic sulphur and carbon dioxide, leaching of local volcanic rocks (driven by high CO2 contents and/or elevated temperature), and biological activity. Latter hydrochemical superimposition is displayed by stromatolitic structures in the precipitates at the given site. Dissolved REE data show similar pattern as local volcanic rocks. In particular the distinct Eu anomaly hints to preferential leaching of locally occurring trachyte. The strongly acidic Na-SO4 waters sampled in boiling pools at Fogo and Furnas Lake indicate high leaching levels and LREE depletion versus HREE compared with the volcanic local rock compositions. Depletion in LREE is most likely caused by its preferential removal compared to HREE by the co-precipitation with alunite.

  7. The Dilaridae of the Balkan Peninsula and of Anatolia (Insecta, Neuropterida, Neuroptera

    Directory of Open Access Journals (Sweden)

    Ulrike Aspöck

    2015-07-01

    Full Text Available Basing upon all available information on type material of Dilar turcicus Hagen, 1858, Dilar syriacus Navás, 1909, and Dilar lineolatus Navás, 1909, together with a large number of dilarid specimens, the pleasing lacewings of Anatolia and Southeast Europe are revised. The current taxonomic concept of D. turcicus is confirmed, and a lectotype is designated. Dilar turcicus is widely distributed in the southeast of Europe (being the only representative of Dilaridae in this region, in Anatolia, and, most probably, in the Caucasus region. Dilar syriacus and D. lineolatus remain nomina dubia. Dilar syriacus might occur in Anatolia, while D. lineolatus is a species occurring in western Central Asia. Two new species, Dilar anatolicus sp. n. and Dilar fuscus sp. n. are described from Anatolia. Wings and genital segments of the three species occurring in Anatolia are illustrated, and a map documenting the known distribution of these species is provided.

  8. Chemical characterisation of iron in dust and biomass burning aerosols during AMMA-SOP0/DABEX: implication for iron solubility

    Directory of Open Access Journals (Sweden)

    R. Paris

    2010-05-01

    Full Text Available The chemical composition and the soluble fraction were determined in aerosol samples collected during flights of AMMA-SOP0/DABEX campaign, which were conducted in the West African Sahel during dry season (2006. Two aerosol types are encountered in this period: dust particles (DUST and biomass burning aerosol (BB. Chemical analysis and microscope observations showed that the iron (Fe found in BB samples mainly originates from dust particles mostly internally mixed in the biomass burning layer. Chemical analyses of samples showed that the Fe solubility is lower in African dust samples than in biomass burning aerosols. Our data provide a first idea of the variability of iron dust solubility in the source region (0.1% and 3.4%. We found a relationship between iron solubility/clay content/source which partly confirms that the variability of iron solubility in this source region is related to the character and origin of the aerosols themselves. In the biomass burning samples, no relationship were found between Fe solubility and either the concentrations of acidic species (SO42−, NO3 or oxalate or the content of carbon (TC, OC, BC. Therefore, we were unable to determine what processes are involved in this increase of iron solubility. In terms of supply of soluble Fe to oceanic ecosystems on a global scale, the higher solubility observed for Fe in biomass burning could imply an indirect source of Fe to marine ecosystems. But these aerosols are probably not significant because the Sahara is easily the dominant source of Fe to the Atlantic Ocean.

  9. Characterisation of Authentic Lignin Biorefinery Samples by Fourier Transform Infrared Spectroscopy and Determination of the Chemical Formula for Lignin

    DEFF Research Database (Denmark)

    Le, Duy Michael; Damgaard Nielsen, Anders; Sørensen, Hanne

    2017-01-01

    samples in situ with no prior purification and minimal sample preparation. Lignin chemical formulas and lignin Fourier transform infrared (FTIR) spectra were extracted from mixed spectra by filtering out signals from residual carbohydrates and minerals. From estimations of C, H and O and adjustment...... for cellulose and hemicelluloses contents, the average chemical formula of lignin was found to be C9H10.2O3.4 with slight variations depending on the biomass feedstock and processing conditions (between C9H9.5O2.8 and C9H11.1O3.6). Extracted FTIR lignin spectra showed many of the same characteristic peaks...... as organosolv and kraft lignin used as benchmark samples. Some variations in the lignin spectra of biorefinery lignin residue samples were found depending on biomass feedstock (wheat straw, corn stover or poplar) and on pretreatment severity, especially in the absorbance of bands at 1267 and 1032 cm−1 relative...

  10. Completely automated short-term genotoxicity testing for the assessment of chemicals and characterisation of contaminated soils and waste waters.

    Science.gov (United States)

    Brinkmann, Corinna; Eisentraeger, Adolf

    2008-05-01

    The umu-test was developed for the detection of effects of chemical mutagens and carcinogens in environmental samples. It is performed according to ISO 13829 with Salmonella choleraesius subsp. chol. (strain TA1535/pSK1002). By automating the entire test, large numbers of toxicants and environmental samples as well as more treatments and parallels can be tested and, additionally, only low sample volumes are needed. In this work, an automated umu-test has been set up by installing a robotic XYZ-platform and a microplate reader inside a cabin. The use of established technical equipment for the automation in combination with a performance according to ISO standards was the essential aim of the approach. After initial preparation, the test is conducted software-controlled, follows the standard and fulfils the validity criteria of the standard procedure. For the optimization of the automated test umu-tests with one concentration of methyl methanesulfonate (MMS) of 166.7 mg/L were carried out. After optimization of incubation and pipetting conditions in the automated test, dose-response curves of various chemicals and environmental samples were assessed. The results of the automated umu-test have been compared with those of the standard manual test. The aim of the study was to show the applicability of an automated test system for the assessment of the genotoxic effects of various chemicals and environmental samples. During optimization, tests with 166.7 mg/L of MMS in every well of the microplate are carried out. Chemicals with different physical, chemical and toxicological properties are applied in both test systems. Water samples from different waste water treatment plants, and water extracts of contaminated and uncontaminated soils are assessed in the umu-test. The test is performed in parallel manually according to the standard and automatically using the robotic platform. Dose-response relationships and DLI-values are recorded and compared. The umu-test is applied

  11. Role of the Western Anatolia Shear Zone (WASZ) in Neotectonics Evolution of the Western Anatolia Extended Terrain, Turkey

    Science.gov (United States)

    Cemen, I.; Gogus, O. H.; Hancer, M.

    2013-12-01

    The Neotectonics period in western Anatolia Extended Terrain, Turkey (WAET) may have initiated in late Oligocene following the Eocene Alpine collision which produced the Izmir-Ankara suture zone. The Western Anatolia Shear Zone (WASZ) bounds the WAET to the east. The shear zone contains mostly normal faults in the vicinity of the Gulf of Gokova. However, its movement is mostly oblique slip from the vicinity of Tavas towards the Lake of Acigol where it makes a northward bend and possibly joins the Eskisehir fault zone to the north of the town of Afyon. The shear zone forms the southern and eastern margins of the Kale-Tavas, Denizli and Acigol basins. The shear zone is similar in its structural/tectonics setting to the Eastern California Shear zone (ECSZ) of the Basins and Ranges of North America Extended terrain which is also composed of many normal to oblique-slip faults and separates two extended terrains with different rates of extension. Western Anatolia experienced many devastating earthquakes within the last 2000 years. Many of the ancient Greek/Roman city states, including Ephesus, Troy, and Hierapolis were destroyed by large historical earthquakes. During the second half of the 20th century, the region experienced two major large earthquake giving normal fault focal mechanism solutions. They are the 1969, M=6.9 Alasehir and the 1970, M=7.1 Gediz earthquakes. These earthquakes had caused substantial damage and loss of life in the region. Therefore, a comprehensive understanding of the kinematics of the Cenozoic extensional tectonics and earthquake potential of the WASZ in the region, is very important, especially since the fault zone is very close to the major towns in eastern part of western Turkey, such as Mugla, Denizli, Sandikli, Dinar and Afyon.

  12. The use of IRMS, (1)H NMR and chemical analysis to characterise Italian and imported Tunisian olive oils.

    Science.gov (United States)

    Camin, Federica; Pavone, Anita; Bontempo, Luana; Wehrens, Ron; Paolini, Mauro; Faberi, Angelo; Marianella, Rosa Maria; Capitani, Donatella; Vista, Silvia; Mannina, Luisa

    2016-04-01

    Isotope Ratio Mass Spectrometry (IRMS), (1)H Nuclear Magnetic Resonance ((1)H NMR), conventional chemical analysis and chemometric elaboration were used to assess quality and to define and confirm the geographical origin of 177 Italian PDO (Protected Denomination of Origin) olive oils and 86 samples imported from Tunisia. Italian olive oils were richer in squalene and unsaturated fatty acids, whereas Tunisian olive oils showed higher δ(18)O, δ(2)H, linoleic acid, saturated fatty acids β-sitosterol, sn-1 and 3 diglyceride values. Furthermore, all the Tunisian samples imported were of poor quality, with a K232 and/or acidity values above the limits established for extra virgin olive oils. By combining isotopic composition with (1)H NMR data using a multivariate statistical approach, a statistical model able to discriminate olive oil from Italy and those imported from Tunisia was obtained, with an optimal differentiation ability arriving at around 98%. Copyright © 2015 Elsevier Ltd. All rights reserved.

  13. Chemical-physical and ecological characterisation in the environmental project of a polluted coastal area: the Bagnoli case study

    Directory of Open Access Journals (Sweden)

    I. BERGAMIN

    2003-12-01

    Full Text Available The Bagnoli Bay (southern Tyrrhenian Sea, Naples, Italy has been impacted for about one century by heavy anthropogenic pollution due to an important steel plant. A multidisciplinary environmental research, aimed at the reclamation of the marine contaminated area, was planned in order to evaluate, through quantitative data, the chemical-physical and ecological characteristics of marine sediments; the latter ones are strictly related to the composition and structure of benthic foraminiferal assemblages. A comprehensive statistical approach, considering all data, was attempted in order to single out the influence of pollutants on the single species distribution. The results show strong heavy metal pollution (Fe, Mn, Pb and Zn in the vicinity of the industrial plant. Many foraminiferal species (Haynesina germanica, Miliolinella subrotunda,Quinqueloculina parvula, have a good tolerance to some trace metals while, Bulimina sublimbata, Elphidiummacellum and Miliolinella dilatata show a good tolerance to PAHs pollution.

  14. Chemical characterisation and biological activity of leaf essential oils obtained from Pistacia terebinthus growing wild in Tunisia and Sardinia Island.

    Science.gov (United States)

    Piras, Alessandra; Marzouki, Hanen; Maxia, Andrea; Marengo, Arianna; Porcedda, Silvia; Falconieri, Danilo; Gonçalves, Maria José; Cavaleiro, Carlos; Salgueiro, Ligia

    2017-11-01

    In the present work the chemical compositions, measured by GC and GC-MS, of the essential oils obtained by hydrodistillation from leaves of Pistacia terebinthus collected in Bizerte (Tunisia) and Baunei (Italy) are reported. Both essential oils possessed high content of monoterpene hydrocarbons (86.3% and 90.9%, respectively), being α-pinene (62.4 vs. 35.0)%, camphene (3.0 vs. 2.4)%, β-pinene (12.1 vs. 4.5)%, terpinolene (1.7 vs. 35.2)% and β-phellandrene (3.8 vs. 4.5)% the main components. The Tunisian essential oil exhibited higher antifungal activity than the Italian one. Cryptococcus neoformans and the majority of dermatophyte strains showed more sensitivity to the Tunisian oil, when compared to Candida strains, in particular Trichophyton rubrum, Microsporum canis and Epidermophyton floccosum, with MIC and MLC values in the range (0.16-0.32) μL/mL. The results obtained support the use of the oil from Tunisia for the treatment of dermatophytosis.

  15. Characterisation of polymers, 1

    CERN Document Server

    Crompton, Roy

    2008-01-01

    This essential guide to Polymer Characterisation is a complete compendium of methodologies that have evolved for the determination of the chemical composition of polymers. This 478-page book gives an up-to-date and thorough exposition of the state-of-the-art theories and availability of instrumentation needed to effect chemical and physical analysis of polymers. This is supported by approximately 1200 references. Volume 1 covers the methodology used for the determination of metals, non-metals and organic functional groups in polymers, and for the determination of the ratio in which different m

  16. A quantitative mechanistic description of Ni, Zn and Ca sorption on Na-Montmorillonite. Part I: Physico-chemical characterisation and titration measurements

    International Nuclear Information System (INIS)

    Baeyens, B.; Bradbury, M.H.

    1995-07-01

    The work presented in this report is primarily concerned with characterisation studies and titration measurements on conditioned Na-montmorillonite. The starting material, SWy-1 Na-montmorillonite (Crook County, Wyoming, USA), contains background metal impurities, soluble salts and sparingly soluble minerals which can influence titration and sorption measurements and thereby lead to difficulties in the interpretation of the data. A conditioning procedure is described which yielded a purified clay material in the homoionic sodium form with a particle size 4 . The reasons for choosing a batch method, coupled with back titration of the supernatant solutions, instead of a continuous procedure, are fully discussed. Chemical analyses data for the supernatant solutions are presented in detail. The influence of background impurities, not removed by the conditioning, and cation exchange processes on the form of the titration curves were investigates. Net Na-montmorillonite titration curves at two different ionic strengths were derived which are considered to reflect only the acid/base behaviour of ≡SOH type surface sites. The acid end point in the titration data was used to estimate an ≡SOH site capacity of 0.08 moles per kg conditioned Na-montmorillonite. (author) 8 figs., 19 tabs., refs

  17. Aluminium phosphate sulphate minerals (APS) associated with proterozoic unconformity-type uranium deposits: crystal-chemical characterisation and petrogenetic significance

    International Nuclear Information System (INIS)

    Gaboreau, St.

    2005-01-01

    Aluminium phosphate sulfate minerals (APS) are particularly widespread and spatially associated with hydrothermal clay alteration in both the East Alligator River Uranium Field (Northern Territory, Australia) and the Athabasca basin (Saskatchewan, Canada), in the environment of proterozoic unconformity-related uranium deposits (URUD). The purpose of this study is both: 1) to characterize the nature and the origin of the APS minerals on both sides of the middle proterozoic unconformity between the overlying sandstones and the underlying metamorphic basement rocks that host the uranium ore bodies, 2) to improve our knowledge on the suitability of these minerals to indicate the paleo-conditions (redox, pH) at which the alteration processes relative to the uranium deposition operated. The APS minerals result from the interaction of oxidising and relatively acidic fluids with aluminous host rocks enriched in monazite. Several APS-bearing clay assemblages and APS crystal-chemistry have also been distinguished as a function of the distance from the uranium ore bodies or from the structural discontinuities which drained the hydrothermal solutions during the mineralisation event. One of the main results of this study is that the index mineral assemblages, used in the recent literature to describe the alteration zones around the uranium ore bodies, can be theoretically predicted by a set of thermodynamic calculations which simulate different steps of fluid-rock interaction processes related to a downward penetrating of hyper-saline, oxidizing and acidic diagenetic fluids through the lower sandstone units of the basins and then into the metamorphic basement rocks. The above considerations and the fact that APS with different crystal-chemical compositions crystallized in a range of fO 2 and pH at which uranium can either be transported in solution or precipitated as uraninite in the host-rocks make these minerals not only good markers of the degree of alteration of the

  18. Chemical and aerosol characterisation of the troposphere over West Africa during the monsoon period as part of AMMA

    Directory of Open Access Journals (Sweden)

    C. E. Reeves

    2010-08-01

    Full Text Available During June, July and August 2006 five aircraft took part in a campaign over West Africa to observe the aerosol content and chemical composition of the troposphere and lower stratosphere as part of the African Monsoon Multidisciplinary Analysis (AMMA project. These are the first such measurements in this region during the monsoon period. In addition to providing an overview of the tropospheric composition, this paper provides a description of the measurement strategy (flights performed, instrumental payloads, wing-tip to wing-tip comparisons and points to some of the important findings discussed in more detail in other papers in this special issue.

    The ozone data exhibits an "S" shaped vertical profile which appears to result from significant losses in the lower troposphere due to rapid deposition to forested areas and photochemical destruction in the moist monsoon air, and convective uplift of ozone-poor air to the upper troposphere. This profile is disturbed, particularly in the south of the region, by the intrusions in the lower and middle troposphere of air from the southern hemisphere impacted by biomass burning. Comparisons with longer term data sets suggest the impact of these intrusions on West Africa in 2006 was greater than in other recent wet seasons. There is evidence for net photochemical production of ozone in these biomass burning plumes as well as in urban plumes, in particular that from Lagos, convective outflow in the upper troposphere and in boundary layer air affected by nitrogen oxide emissions from recently wetted soils. This latter effect, along with enhanced deposition to the forested areas, contributes to a latitudinal gradient of ozone in the lower troposphere. Biogenic volatile organic compounds are also important in defining the composition both for the boundary layer and upper tropospheric convective outflow.

    Mineral dust was found to be the most abundant and ubiquitous aerosol type in the

  19. ASSESSMENT OF IRRIGATION EFFICIENCIES UNDER CENTRAL ANATOLIA CONDITIONS

    Directory of Open Access Journals (Sweden)

    Yusuf Ersoy Yildirim

    2016-12-01

    Full Text Available Turkey is located within semi-arid climate zone and large portion of the country experience water deficits. Thus, efficient water use has become a significand issue in agricultural practices. Current global warming and climate change have aggravated such deficiencies. Konya province is located right at the center of Central Anatolia region and mostly groundwater is used in irrigations. Excessive groundwater withdrawals drop groundwaters levels and also increase energy costs. Although farmers pay quite high sums for energy, they were not using water efficiently and thus were not able to get desired benefits from the irrigations. In this study, irrigation practices of an irrigation cooperative were assessed and compared with optimum irrigation programs created through IRSIS irrigation scheduling software. It was concluded that all irrigation practices of the region were wrong and way behind the optimum ones.

  20. Neutron activation analysis of Urartian pottery from eastern Anatolia

    International Nuclear Information System (INIS)

    Speakman, R.J.; Glascock, M.D.; Stone, E.C.; Cilingiroglu, A.; Zimansky, P.; Neff, H.

    2004-01-01

    A total of 275 pottery and clay samples from Urartian period sites in eastern Anatolia were analyzed by INAA. The pottery sample originates primarily from the fortress and Outer Town at Ayanis and also includes samples from nearby sites in the Lake Van basin. A small sample of pottery from Bastam, a contemporary Urartian fortress in northwest Iran, and Kef Kalesi, a site on the north shore of Lake Van were also analyzed. Ten distinct compositional groups were identified during the course of the analysis suggesting that pottery was produced at multiple locations throughout the Urartian kingdom. In addition to identifying multiple production locales, the long-distance movement of pottery from the sites of Kef Kalesi and Bastam into the Van Basin and the movement of pottery from Ayanis to Bastam were documented. (author)

  1. Astragalus friederikeanus Kit Tan & Zeitlinger (Fabaceae), a new species from south Anatolia, Turkey

    DEFF Research Database (Denmark)

    Tan, Kit; Zeitlinger, Jörg

    2007-01-01

    A new species from south Anatolia, Turkey, Astragalus friederikeanus Kit Tan & Zeitlinger (Fabaceae), is described and illustrated. The diagnostic morphological characters separating it from other members of sect. Onobrychium Boiss. are listed.......A new species from south Anatolia, Turkey, Astragalus friederikeanus Kit Tan & Zeitlinger (Fabaceae), is described and illustrated. The diagnostic morphological characters separating it from other members of sect. Onobrychium Boiss. are listed....

  2. Long term corrosion of iron and non alloy or low alloy steels in clay soils. Physico-chemical characterisation and electrochemical study of archaeological analogues

    International Nuclear Information System (INIS)

    Pons, Emmanuelle

    2002-01-01

    Archaeological objects of Gallo-Roman and Merovingian time, and from a battlefield of World War 1, were studied to better understand long term corrosion phenomena of iron in clay soils. This study is part of the French national program about nuclear waste deep repository, conducted by the ANDRA (French national Agency for Radioactive Waste Management). Iron archaeological analogues make a valuable contribution to the specifying of containers for long lived and high level wastes (HLWs), because they provide access to the considered time scale. The experimental issue is divided into two major parts: - a physico-chemical characterisation of corrosion products, by Raman spectroscopy; - an electrochemical study of the behaviour of the different corrosion layers. Although the metallic material is different between ancient artefacts (ferrite) and 1914-1918 remains (hypo-eutectoid steels), the same stable phases are identified in their corrosion products: mainly iron oxides and oxi-hydroxides. From a macroscopic point of view, these products are staggered into two layers: an internal one, and an external one, which contains soil markers. Under the microscope, a complex composite structure appears. Goethite a-FeOOH, which was identified on each object, is frequently in contact with the metal core. The average corrosion rate in the burial environment, deduced from the layers thickness, highlights a significant slowdown of corrosion after the first burial time, about one century. The electrochemical study showed the predominant role of transport phenomena in the pores of corrosion layers. The behaviour of the metal - internal layer system is well explained by a model of porous electrode (De Levie theory). Despite its porosity, the internal layer is protective, as it leads to a significant decrease of the corrosion rate (about ten time). (author) [fr

  3. Chemical characterisation of the coarse and fine particulate matter in the environment of an underground railway system: cytotoxic effects and oxidative stress-a preliminary study.

    Science.gov (United States)

    Spagnolo, Anna Maria; Ottria, Gianluca; Perdelli, Fernanda; Cristina, Maria Luisa

    2015-04-13

    Exposure to the particulate matter produced in underground railway systems is arousing increasing scientific interest because of its health effects. The aim of our study was to evaluate the airborne concentrations of PM10 and three sub-fractions of PM2.5 in an underground railway system environment in proximity to platforms and in underground commercial areas within the system, and to compare these with the outdoor airborne concentrations. We also evaluated the metal components, the cytotoxic properties of the various fractions of particulate matter (PM) and their capacity to induce oxidative stress. We collected the coarse fraction (5-10 µm) and the fine fractions (1-2.5 µm; 0.5-1 µm; 0.25-0.5 µm). Chemical characterisation was determined by means of spectrometry. Cytotoxicity and oxidative stress were evaluated by 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide (MTT) assay and Reactive Oxygen Species (ROS) assessment. The concentrations of both PM10 and PM2.5 proved to be similar at the three sampling sites. Iron and other transition metals displayed a greater concentration at the subway platform than at the other two sites. The 2.5-10 µm and 1-2.5 µm fractions of PM from all three sampling sites determined a greater increase in ROS; the intensity of oxidative stress progressively declined as particle diameter diminished. Moreover, ROS concentrations were correlated with the concentrations of some transition metals, namely Mn, Cr, Ti, Fe, Cu, Zn, Ni and Mo. All particulate matter fractions displayed lower or similar ROS values between platform level and the outdoor air. The present study revealed that the underground railway environment at platform level, although containing higher concentrations of some particularly reactive metallic species, did not display higher cytotoxicity and oxidative stress levels than the outdoor air.

  4. Integrated approach of nutritional and molecular epidemiology, mineralogical and chemical pollutant characterisation: the protocol of a cross-sectional study in women.

    Science.gov (United States)

    Barchitta, Martina; Quattrocchi, Annalisa; Maugeri, Andrea; Barone, Germana; Mazzoleni, Paolo; Catalfo, Alfio; De Guidi, Guido; Iemmolo, Maria; Crimi, Nunzio; Agodi, Antonella

    2017-04-04

    Environmentally-related health and disease are the result of the exposome, the totality of a person's environmental exposures, from all sources and routes, across their lifespan. Epigenetic phenomena, including DNA methylation, can be potentially modified by environmental and lifestyle factors, and result in environmental reprogramming of the genome for exposed individuals and for future generations of offspring. The objective of the project is to evaluate the risk of DNA hypomethylation due to air pollution, Mediterranean diet adherence, folate intake, and demographic and socioeconomic factors, in healthy women living in the metropolitan area of Catania, Italy. Non-pregnant healthy women will be enrolled in a cross-sectional study. Sociodemographic, lifestyle and dietary intake information will be collected. LINE-1 methylation will be measured by pyrosequencing. The participants' home addresses will be geocoded and each woman will be assigned to the closest monitoring station for particulate matter (PM) exposure assessment. Mineralogical-chemical characterisation of PM and cellular model assays will be performed. An integrated approach will be designed to estimate the combined possible effect of air pollution, Mediterranean diet adherence, folate intake and other lifestyle characteristics on LINE-1 methylation levels. The project has been approved by the ethics committees of the involved institution and funded by the University of Catania (Finanziamento della Ricerca, FIR 2014). All participants will be fully informed of the purpose and procedures of the study, and signed written consents will be obtained. All the data collected will be treated confidentially and analysed in an aggregate and anonymous way. The results will be published in peer-reviewed journals and communicated to local public health agencies, in order to provide essential information for timely and effective public health action. Published by the BMJ Publishing Group Limited. For permission to

  5. Chemical Characterisation of the Coarse and Fine Particulate Matter in the Environment of an Underground Railway System: Cytotoxic Effects and Oxidative Stress—A Preliminary Study

    Directory of Open Access Journals (Sweden)

    Anna Maria Spagnolo

    2015-04-01

    Full Text Available Background: Exposure to the particulate matter produced in underground railway systems is arousing increasing scientific interest because of its health effects. The aim of our study was to evaluate the airborne concentrations of PM10 and three sub-fractions of PM2.5 in an underground railway system environment in proximity to platforms and in underground commercial areas within the system, and to compare these with the outdoor airborne concentrations. We also evaluated the metal components, the cytotoxic properties of the various fractions of particulate matter (PM and their capacity to induce oxidative stress. Method: We collected the coarse fraction (5–10 µm and the fine fractions (1–2.5 µm; 0.5–1 µm; 0.25–0.5 µm. Chemical characterisation was determined by means of spectrometry. Cytotoxicity and oxidative stress were evaluated by 3-(4,5-dimethylthiazol-2-yl-2,5-diphenyltetrazolium bromide (MTT assay and Reactive Oxygen Species (ROS assessment. Results: The concentrations of both PM10 and PM2.5 proved to be similar at the three sampling sites. Iron and other transition metals displayed a greater concentration at the subway platform than at the other two sites. The 2.5–10 µm and 1–2.5 µm fractions of PM from all three sampling sites determined a greater increase in ROS; the intensity of oxidative stress progressively declined as particle diameter diminished. Moreover, ROS concentrations were correlated with the concentrations of some transition metals, namely Mn, Cr, Ti, Fe, Cu, Zn, Ni and Mo. All particulate matter fractions displayed lower or similar ROS values between platform level and the outdoor air. Conclusions: The present study revealed that the underground railway environment at platform level, although containing higher concentrations of some particularly reactive metallic species, did not display higher cytotoxicity and oxidative stress levels than the outdoor air.

  6. Chemical Characterisation of the Coarse and Fine Particulate Matter in the Environment of an Underground Railway System: Cytotoxic Effects and Oxidative Stress—A Preliminary Study

    Science.gov (United States)

    Spagnolo, Anna Maria; Ottria, Gianluca; Perdelli, Fernanda; Cristina, Maria Luisa

    2015-01-01

    Background: Exposure to the particulate matter produced in underground railway systems is arousing increasing scientific interest because of its health effects. The aim of our study was to evaluate the airborne concentrations of PM10 and three sub-fractions of PM2.5 in an underground railway system environment in proximity to platforms and in underground commercial areas within the system, and to compare these with the outdoor airborne concentrations. We also evaluated the metal components, the cytotoxic properties of the various fractions of particulate matter (PM) and their capacity to induce oxidative stress. Method: We collected the coarse fraction (5–10 µm) and the fine fractions (1–2.5 µm; 0.5–1 µm; 0.25–0.5 µm). Chemical characterisation was determined by means of spectrometry. Cytotoxicity and oxidative stress were evaluated by 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide (MTT) assay and Reactive Oxygen Species (ROS) assessment. Results: The concentrations of both PM10 and PM2.5 proved to be similar at the three sampling sites. Iron and other transition metals displayed a greater concentration at the subway platform than at the other two sites. The 2.5–10 µm and 1–2.5 µm fractions of PM from all three sampling sites determined a greater increase in ROS; the intensity of oxidative stress progressively declined as particle diameter diminished. Moreover, ROS concentrations were correlated with the concentrations of some transition metals, namely Mn, Cr, Ti, Fe, Cu, Zn, Ni and Mo. All particulate matter fractions displayed lower or similar ROS values between platform level and the outdoor air. Conclusions: The present study revealed that the underground railway environment at platform level, although containing higher concentrations of some particularly reactive metallic species, did not display higher cytotoxicity and oxidative stress levels than the outdoor air. PMID:25872016

  7. Physico-chemical characterisation and sorption measurements of Cs, Sr, Ni, Eu, Th, Sn and Se on Opalinus clay from Mont Terri

    International Nuclear Information System (INIS)

    Lauber, Matthias; Baeyens, Bart; Bradbury, Michael H.

    2000-12-01

    Opalinus Clay is currently under investigation as a potential host rock for the disposal of high level and long-lived intermediate radioactive waste. A throughout physico-chemical characterisation was carried out on a bore core sample from the underground rock laboratory Mont Terri (Canton Jura). The results of these investigations indicate that the major characteristics (mineralogy, cation exchange capacity, cation occupancies, selectivity coefficients, chloride and sulphate inventories) were very similar to a different core sample, previously used for pore water modelling studies. It was concluded that the pore water compositions derived in the earlier studies were reliable and could be used in this work. The organic matter which dissolved from the Opalinus Clay rock was not humic or fulvic acids and the concentration remaining in the liquid phase in the sorption experiments was < 0.5 ppm C. The organic matter is therefore considered to have little or no influence on the sorption behaviour of the studied radionuclides. Redox potential measurements of the Opalinus Clay/synthetic pore water system inside the glove boxes indicated anoxic conditions. The main focus of the experimental work presented here is on the sorption behaviour of Cs (I), Sr (II), Ni (II), Eu (III), Th (IV), Sn (IV) and Se (IV) on Opalinus Clay equilibrated with synthetic pore waters at pH 6.3 and 8. Sorption isotherms were measured for Cs, Ni, Eu, Th and Se. Single point data were measured for Sr and Sn. For all radionuclides studied the sorption kinetics were measured first. The times required to complete the sorption on the Opalinus Clay varied between one day for Th and one month for Ni and Se. Within the concentration ranges under study the uptake of Cs, Ni, Eu and Se on Opalinus Clay was non-linear, whereas for Th a linear sorption behaviour was observed. For Ni, Eu and Th the sorption increased with increasing pH. For Cs a pH independent sorption behaviour was observed. The concentration

  8. Climate stability in Central Anatolia during the Messinian Salinity Crisis

    Science.gov (United States)

    Meijers, Maud J.M.; Peynircioğlu, Ahmet A; Cosca, Michael A.; Brocard, Gilles Y.; Whitney, Donna L.; Langereis, Cor G.; Mulch, Andreas

    2018-01-01

    Deposition of large amounts of evaporites and erosion of deep canyons within the Mediterranean Basin as a result of reduced basin connectivity with the Atlantic Ocean and the epicontinental Paratethys Sea characterized the Messinian Salinity Crisis (MSC, 5.97–5.33 Ma). The influence of the MSC on Mediterranean environmental conditions within the basin itself has been intensely studied from marine records, but reconstructing the impact of the MSC on circum-Mediterranean continental climate has been hampered by the absence of continuous sedimentary archives that span the duration of the event.Here, we report results of a continental record of carbon (δ13C) and oxygen (δ18O) isotopes from lake carbonates framed by new magnetostratigraphic and 40Ar/39Ar dating, as well as by existing mammal stratigraphy (Kangal Basin, central Anatolia). The sampled section records continuous fluvio-lacustrine sedimentation from ~6.6 Ma to 4.9 Ma, which spans the MSC and the Miocene-Pliocene boundary. This dataset so far represents the only continuous continental paleoenvironmental record of the MSC in the circum-Mediterranean realm.The Kangal Basin isotope record indicates a low degree of evaporation. Furthermore, covariance between δ13C and δ18O suggests a coupling between lake water balance and biologic productivity. Variations in δ13C and δ18O therefore likely reflect changes in the amount of incoming precipitation, rather than changes in δ18O values of incoming precipitation. The most prominent spike in δ13C and δ18O occurs during the acme of the MSC and is therefore interpreted to have resulted from a decrease in the amount of incoming moisture correlative to a period of vigorous erosion and sea level lowering in the Mediterranean Basin. Major sea level lowering of Mediterranean basin waters during the acme of the MSC could have therefore led to slightly dryer conditions over Anatolia, which is also suggested by modeling studies. Overall, changes in δ13C and

  9. Drought Analysis in the Tuz Lake Basin, Central Anatolia, Turkey

    Science.gov (United States)

    Ustaoglu, Beyza; Akın, Burcu

    2017-04-01

    The research area, Tuz Lake Basin is located in Central Anatolia Region in Turkey. The drought is observed in this area with the result of the meteorological data analysis, satellite imagery and field research. The aim of this study is to determine temporal and spatial characterists of the drought, frequency and extreme droughtness possibilities, drought period, amplitude of the drought and its severity which is observed in Tuz Lake within the context of climate change process effects in Turkey, by using Standart Precipitation Index (SPI) Palmer Drought Harshness Index, De Martonne and Erinç Method. Since the indexes which are used in the study have different parameters, not only meteorological results but also agricultural and hydrological drought results can be inferred. For this purpose, measurements of 12 meteorological stations in the basin between the years 1975-2015 will be studied applying the aforementioned methods in MATLAB. SRTM satellite images used in the study is provided by American Geological Survey (USGS). The findings from satellite imagery and meteorological data integrated into Geographic Information Systems Software ArcMap 10.1, then the effects of the drought to the Tuz Lake were analyzed. The findings of the analysis will be interpreted with the support of the field studies.

  10. Geoarchaeological research at Barcın Höyük: implications for the Neolithisation of northwest Anatolia

    NARCIS (Netherlands)

    Groenhuijzen, M.R.; Kluiving, S.J.; Gerritsen, F.A.; Künzel, M.

    2015-01-01

    Landscape archaeological research has been undertaken on the mound of Barcin Höyük in northwest Anatolia, Turkey. It is the oldest Neolithic site in the region, making it of particular interest in regard to the spread of farming from the regions of origin (southeast and central Anatolia) to

  11. The characterisation of precipitated magnetites

    International Nuclear Information System (INIS)

    Rush, D.F.; Segal, D.L.

    1982-06-01

    Methods are described for the preparation of magnetite by precipitation from aqueous solutions of iron(II) and iron(III) salts. The magnetites have been characterised by transmission electron microscopy, chemical analysis and X-ray diffraction. Transmission Moessbauer spectroscopy has also been used to characterise precipitated magnetites and a comparison of the spectra has been made with those obtained from nickel ferrite and hydrated ferric oxides. The hydrothermal stability of magnetite at 573 K has also been investigated. This work is relevant to corrosion processes that can occur in the water coolant circuits of nuclear reactors. (author)

  12. Hydrothermal fluids circulation and travertine deposition in an active tectonic setting: Insights from the Kamara geothermal area (western Anatolia, Turkey)

    Science.gov (United States)

    Brogi, Andrea; Alçiçek, M. Cihat; Yalçıner, Cahit Çağlar; Capezzuoli, Enrico; Liotta, Domenico; Meccheri, Marco; Rimondi, Valentina; Ruggieri, Giovanni; Gandin, Anna; Boschi, Chiara; Büyüksaraç, Aydin; Alçiçek, Hülya; Bülbül, Ali; Baykara, Mehmet Oruç; Shen, Chuan-Chou

    2016-06-01

    Coexistence of thermal springs, travertine deposits and tectonic activity is a recurring feature for most geothermal areas. Although such a certainty, their relationships are debated mainly addressing on the role of the tectonic activity in triggering and controlling fluids flow and travertine deposition. In this paper, we present the results of an integrated study carried out in a geothermal area located in western Anatolia (Turkey), nearby the well-known Pamukkale area (Denizli Basin). Our study focused on the relationships among hydrothermal fluids circulation, travertine deposition and tectonic activity, with particular emphasis on the role of faults in controlling fluids upwelling, thermal springs location and deposition of travertine masses. New field mapping and structural/kinematics analyses allowed us to recognize two main faults systems (NW- and NE-trending), framed in the Neogene-Quaternary extensional tectonic evolution of western Anatolia. A geo-radar (GPR) prospection was also provided in a key-area, permitting us to reconstruct a buried fault zone and its relationships with the development of a fissure-ridge travertine deposit (Kamara fissure-ridge). The integration among structural and geophysical studies, fluids inclusion, geochemical, isotopic data and 230 Th/238 U radiometric age determination on travertine deposits, depict the characteristics of the geothermal fluids and their pathway, up to the surface. Hydrological and seismological data have been also taken in account to investigate the relation between local seismicity and fluid upwelling. As a main conclusion we found strict relationships among tectonic activity, earthquakes occurrence, and variation of the physical/chemical features of the hydrothermal fluids, presently exploited at depth, or flowing out in thermal springs. In the same way, we underline the tectonic role in controlling the travertine deposition, making travertine (mainly banded travertine) a useful proxy to reconstruct the

  13. Diachronous demise of the Neotethys Ocean as driver for non-cylindrical orogenesis in Anatolia

    Science.gov (United States)

    Van Hinsbergen, D. J. J.; Gurer, D.

    2017-12-01

    Continent-continent collision drives crustal deformation, topographic rise, and geodynamic change. Africa-Eurasia convergence accommodated in the Eastern Mediterranean involved subduction of the Neotethyan oceanic lithosphere in Anatolia. Subduction was followed by collision of Greater Adria continental crust with Eurasia forming the Izmir-Ankara-Erzincan suture zone. Discerning the effects of this collision from pre-collisional ophiolite obduction-related orogeny of Greater Adria is notoriously difficult, and estimates from Central Anatolia based on a forearc-to-foreland basin transition along the Eurasian margin suggest a 60 Ma initial collision. Here we assess whether this age is also representative for collision in eastern Anatolia across the Cenozoic Sivas basin that straddles the Greater Adria-Europe suture by retro-deforming regional block rotations in the Pontides, Kırşehir and Taurides, building a first-order regional `block circuit' around the Sivas basin. We show that up to 700 km of convergence must have been accommodated after central Anatolian Kırşehir-Pontide collision at 65-60 Ma across the Sivas Basin - an order of magnitude more than estimated crustal shortening. We consequently infer that oceanic subduction continued much longer in eastern Anatolia, perhaps into the Oligocene or beyond, demonstrating the a recently postulated greater paleogeographic width of the Neotethys in eastern Anatolia. Prolonged oceanic subduction likely resulted from a paleogeography with a sharp kink in the former Kırşehir-Tauride passive margin. The strong non-cylindricity of the Anatolian collisional orogen is explained continued slab pull during ongoing oceanic subduction in eastern Anatolia following central Anatolian collision.

  14. Case study: Examples of Wooden Vernacular Architecture - Turkish Houses in Western Anatolia

    Directory of Open Access Journals (Sweden)

    Yilmaz Karaman Özgül

    2015-12-01

    Full Text Available Wooden material is described as the oldest construction material along with stone. In the historical process, especially for the buildings of shelter, timber construction components are seen to be used as primary and indispensable structural system components in different geographies of the world as well as Anatolia. This paper focuses on timber-frame structures of four different settlements from Western Anatolia. It is aimed to analyze the traditional techniques, in order to transmit our cultural heritage to the next generations, as well as obtaining some data on construction techniqes to be used for creating alternative solutions to the house production of today.

  15. Natural radioactivity releases from lignite power plants in Southwestern Anatolia

    International Nuclear Information System (INIS)

    Yaprak, G.; Guer, F.; Cam, F.; Candan, O.

    2006-01-01

    The Mugla basin is one of the most productive lignite basins in Southwestern Anatolia, Turkey. Mining activities started in 1979 and total reserves were estimated during exploration at 767.5 million tonnes. Total mean annual lignite production of the Mugla basin is estimated at about 10 million tonnes per year. Most of the lignite production supplies three thermal power plants (Yatagan 630 MW, Yenikoey 420 MW, Kemerkoey 630 MW) with a total capacity of 1680 MW. It is well known that the lignite contains naturally occurring primordial radionuclides arising from the uranium and thorium series as well as from 4 0K. Lignite burning is, therefore, one of the sources of technologically enhanced exposure to humans from natural radionuclides. The investigation reported here deals with the determination of the 2 26Ra, 2 32Th and 4 0K concentrations in the lignite feeding 3 thermal power plants in Mugla region and in the product ash. Samples of lignite feeding the power plants and fly and bottom ashes produced in the same power plants were collected over a period of 1 year and therefore systematic sampling allowed for the determination of mean representative values for the natural radioactivity content of above materials and also estimation of the radioactivity releases to the environment. Furthermore, grid soil sampling within 10-15 km around the power plants allowed for the mapping of the surface soil activity of natural radionuclides. Dosimetric calculations from terrestrial gamma radiation for the population living around the power plants were performed based on the guidance of UNSCEAR 2000 report

  16. Thermal structure of the crust in Inner East Anatolia from aeromagnetic and gravity data

    Science.gov (United States)

    Bektaş, Özcan

    2013-08-01

    Inner East Anatolia has many hot spring outcomes. In this study, the relationship between the thermal structure and hot spring outcomes is investigated. The residual aeromagnetic and gravity anomalies of the Inner East Anatolia, surveyed by the Mineral Research and Exploration (MTA) of Turkey, show complexities. The magnetic data were analyzed to produce Curie point depth estimates. The depth of magnetic dipole was calculated by azimuthally averaged power spectrum method for the whole area. The Curie point depth (CPD) map covering the Inner East Anatolia has been produced. The Curie point depths of the region between Sivas and Malatya vary from 16.5 to 18.7 km. Values of heat flow were calculated according to continental geotherm from the model. The heat flow values vary between 89 and 99 mW m-2. Heat flow values are incorporated with surface heat flow values. Gravity anomalies were modeled by means of a three-dimensional method. The deepest part of the basin (12-14 km), determined from the 3D model, are located below the settlement of Hafik and to the south of Zara towns. Two-dimensional cross sections produced from the basin depths, Curie values and MOHO depths. Based on the analysis of magnetic, gravity anomalies, thermal structures and geology, it seems likely that the hot springs are not related to rising asthenosphere, in the regions of shallow CPDs (∼16.5 km), and mostly hot springs are related to faulting systems in Inner East Anatolia.

  17. A new species of Hesperis (Brassicaceae) from SW Anatolia, Turkey

    DEFF Research Database (Denmark)

    Parolly, G.; Tan, Kit

    2006-01-01

    Hesperis kuerschneri, from the vilayet of Denizli in the Western Taurus is described as a species new to science and illustrated. Its affinities are with H. theophrasti, which has several infraspecific taxa in the Balkans and Anatolia. The new species occurs on steep serpentine scree slopes...... together with other serpentine plants of the Western Taurus and is rather local in distribution....

  18. Clematis austroanatolica (Ranunculaceae), an unusual new species from southern Anatolia, Turkey

    DEFF Research Database (Denmark)

    Zielinski, Jerzy; Tan, Kit

    2011-01-01

    Clematis austroanatolica (Ranunculaceae) is illustrated and described as a new species endemic to southern Anatolia, Turkey. It is related to C. vitalba and differs from the latter in having leaves with narrowly ovate, dentate-serrate leaflets, trifoliolate lowermost pinnae as well as small, pale...

  19. Helichrysum yurterianum (Asteraceae, Inuleae), a new species from NE Anatolia, Turkey

    DEFF Research Database (Denmark)

    Gemici, Yusuf; Tan, Kit; Yildirim, Hasan

    2008-01-01

    Helichrysum yurterianum Y. Gemici, Kit Tan, H. Yildirim & M. Gemici (Asteraceae, Inuleae) is described and illustrated. It is a serpentine endemic restricted to the province of Erzincan in NE Anatolia, Turkey. Its affinities are with H. arenarium and H. noeanum, which both have a wider distribution...

  20. Chaenorhinum semispeluncarum sp. nov. and C. yildirimlii sp. nov. (Scrophulariaceae) from east Anatolia, Turkey

    DEFF Research Database (Denmark)

    Yildirim, Hasan; Tan, Kit; Senol, Serdar

    2010-01-01

    Chaenorhinum semispeluncarum H. Yildirim, Kit Tan, S. Senol & A. Pirhan sp. nov. and C. yildirimlii Kit Tan, H. Yildirim, S. Senol & A. Pirhan sp. nov. (Scrophulariaceae, C. sect. Microrrhinum) from east Anatolia are described and illustrated. They are both narrow endemics related to the rare C...

  1. Cenozoic extensional tectonics of the Western Anatolia Extended Terrane, Turkey

    International Nuclear Information System (INIS)

    Cemen, I; Catlos, E J; Gogus, O; Diniz, E; Hancer, M

    2008-01-01

    The Western Anatolia Extended Terrane in Turkey is located on the eastern side of the Aegean Extended Terrane and contains one of the largest metamorphic core complexes in the world, the Menderes massif. It has experienced a series of continental collisions from the Late Cretaceous to the Eocene during the formation of the Izmir-Ankara-Erzincan suture zone. Based our field work and monazite ages, we suggest that the north-directed postcollisional Cenozoic extension in the region is the product of three consecutive stages, triggered by three different mechanisms. The first stage was initiated about 30 Ma ago, in the Oligocene by the Orogenic Collapse the thermally weakened continental crust along the north-dipping Southwest Anatolian shear zone. The shear zone was formed as an extensional simple-shear zone with listric geometry at depth and exhibits predominantly normal-slip along its southwestern end. But, it becomes a high-angle oblique-slip shear zone along its northeastern termination. Evidence for the presence of the shear zone includes (1) the dominant top to the north-northeast shear sense indicators throughout the Menderes massif, such as stretching lineations trending N10E to N30E; and (2) a series of Oligocene extensional basins located adjacent to the shear zone that contain only carbonate and ophiolitic rock fragments, but no high grade metamorphic rock fragments. During this stage, erosion and extensional unroofing brought high-grade metamorphic rocks of the Central Menderes massif to the surface by the early Miocene. The second stage of the extension was triggered by subduction roll-back and associated back-arc extension in the early Miocene and produced the north-dipping Alasehir and the south-dipping Bueyuek Menderes detachments of the central Menderes massif and the north-dipping Simav detachment of the northern Menderes massif. The detachments control the Miocene sedimentation in the Alasehir, Bueyuek Menderes, and Simav grabens, containing high

  2. Cenozoic extensional tectonics of the Western Anatolia Extended Terrane, Turkey

    Energy Technology Data Exchange (ETDEWEB)

    Cemen, I; Catlos, E J [Boone Pickens School of Geology, Oklahoma State University, 105 Noble Research Center, Stillwater OK 74078 (United States); Gogus, O [University of Toronto, Department of Geology, Earth Sciences Centre, 22 Russell St. Toronto, Ontario, M5S 3B1 (Canada); Diniz, E [Occidental Oil and Gas Corporation, PO Box 22757, Houston TX 77227 (United States); Hancer, M [Pamukkale Universitesi, Muhendislik Fakultesi, Jeoloji Muh. Bolmu, Denizli, 20070 Turkey (Turkey)], E-mail: icemen@okstate.edu

    2008-07-01

    The Western Anatolia Extended Terrane in Turkey is located on the eastern side of the Aegean Extended Terrane and contains one of the largest metamorphic core complexes in the world, the Menderes massif. It has experienced a series of continental collisions from the Late Cretaceous to the Eocene during the formation of the Izmir-Ankara-Erzincan suture zone. Based our field work and monazite ages, we suggest that the north-directed postcollisional Cenozoic extension in the region is the product of three consecutive stages, triggered by three different mechanisms. The first stage was initiated about 30 Ma ago, in the Oligocene by the Orogenic Collapse the thermally weakened continental crust along the north-dipping Southwest Anatolian shear zone. The shear zone was formed as an extensional simple-shear zone with listric geometry at depth and exhibits predominantly normal-slip along its southwestern end. But, it becomes a high-angle oblique-slip shear zone along its northeastern termination. Evidence for the presence of the shear zone includes (1) the dominant top to the north-northeast shear sense indicators throughout the Menderes massif, such as stretching lineations trending N10E to N30E; and (2) a series of Oligocene extensional basins located adjacent to the shear zone that contain only carbonate and ophiolitic rock fragments, but no high grade metamorphic rock fragments. During this stage, erosion and extensional unroofing brought high-grade metamorphic rocks of the Central Menderes massif to the surface by the early Miocene. The second stage of the extension was triggered by subduction roll-back and associated back-arc extension in the early Miocene and produced the north-dipping Alasehir and the south-dipping Bueyuek Menderes detachments of the central Menderes massif and the north-dipping Simav detachment of the northern Menderes massif. The detachments control the Miocene sedimentation in the Alasehir, Bueyuek Menderes, and Simav grabens, containing high

  3. Cenozoic extensional tectonics of the Western Anatolia Extended Terrane, Turkey

    Science.gov (United States)

    Çemen, I.; Catlos, E. J.; Gogus, O.; Diniz, E.; Hancer, M.

    2008-07-01

    The Western Anatolia Extended Terrane in Turkey is located on the eastern side of the Aegean Extended Terrane and contains one of the largest metamorphic core complexes in the world, the Menderes massif. It has experienced a series of continental collisions from the Late Cretaceous to the Eocene during the formation of the Izmir-Ankara-Erzincan suture zone. Based our field work and monazite ages, we suggest that the north-directed postcollisional Cenozoic extension in the region is the product of three consecutive stages, triggered by three different mechanisms. The first stage was initiated about 30 Ma ago, in the Oligocene by the Orogenic Collapse the thermally weakened continental crust along the north-dipping Southwest Anatolian shear zone. The shear zone was formed as an extensional simple-shear zone with listric geometry at depth and exhibits predominantly normal-slip along its southwestern end. But, it becomes a high-angle oblique-slip shear zone along its northeastern termination. Evidence for the presence of the shear zone includes (1) the dominant top to the north-northeast shear sense indicators throughout the Menderes massif, such as stretching lineations trending N10E to N30E; and (2) a series of Oligocene extensional basins located adjacent to the shear zone that contain only carbonate and ophiolitic rock fragments, but no high grade metamorphic rock fragments. During this stage, erosion and extensional unroofing brought high-grade metamorphic rocks of the Central Menderes massif to the surface by the early Miocene. The second stage of the extension was triggered by subduction roll-back and associated back-arc extension in the early Miocene and produced the north-dipping Alaşehir and the south-dipping Büyük Menderes detachments of the central Menderes massif and the north-dipping Simav detachment of the northern Menderes massif. The detachments control the Miocene sedimentation in the Alaşehir, Büyük Menderes, and Simav grabens, containing high

  4. Characterisation of nanomaterial hydrophobicity using engineered surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Desmet, Cloé; Valsesia, Andrea; Oddo, Arianna; Ceccone, Giacomo; Spampinato, Valentina; Rossi, François; Colpo, Pascal, E-mail: pascal.colpo@ec.europa.eu [Directorate Health, Consumer and Reference Materials, Consumer Products Safety Unit (Italy)

    2017-03-15

    Characterisation of engineered nanomaterials (NMs) is of outmost importance for the assessment of the potential risks arising from their extensive use. NMs display indeed a large variety of physico-chemical properties that drastically affect their interaction with biological systems. Among them, hydrophobicity is an important property that is nevertheless only slightly covered by the current physico-chemical characterisation techniques. In this work, we developed a method for the direct characterisation of NM hydrophobicity. The determination of the nanomaterial hydrophobic character is carried out by the direct measurement of the affinity of the NMs for different collectors. Each collector is an engineered surface designed in order to present specific surface charge and hydrophobicity degrees. Being thus characterised by a combination of surface energy components, the collectors enable the NM immobilisation with surface coverage in relation to their hydrophobicity. The experimental results are explained by using the extended DLVO theory, which takes into account the hydrophobic forces acting between NMs and collectors.

  5. Particle related fractionation and characterisation of municipal wastewater

    NARCIS (Netherlands)

    Nieuwenhuijzen, van A.F.; Graaf, van der J.H.J.M.; Kampschreur, M.J.; Mels, A.R.

    2004-01-01

    Several studies show that a more detailed characterisation of the particulate matter in municipal wastewater gives a better understanding and prediction of removal efficiencies of physical-chemical treatment techniques and the application of optimal chemical dosages. Such a characterisation should

  6. Analytical protocols for characterisation of sulphur-free lignin

    NARCIS (Netherlands)

    Gosselink, R.J.A.; Abächerli, A.; Semke, H.; Malherbe, R.; Käuper, P.; Nadif, A.; Dam, van J.E.G.

    2004-01-01

    Interlaboratory tests for chemical characterisation of sulphur-free lignins were performed by five laboratories to develop useful analytical protocols, which are lacking, and identify quality-related properties. Protocols have been established for reproducible determination of the chemical

  7. Neogene Uplift and Magmatism of Anatolia: New Insights from Drainage Analysis and Basalt Geochemistry

    Science.gov (United States)

    McNab, F.; Ball, P.; Hoggard, M.; White, N.

    2017-12-01

    The origin of Anatolia's high elevation and low relief plateaux has been the subject of much recent debate. Marine sedimentary rocks distributed across Central and Eastern Anatolia require significant regional uplift in Neogene times. This uplift cannot be explained by the present-day pattern of crustal deformation which, particularly across Central and Western Anatolia, is dominanted by strike-slip and extensional faulting. Positive long wavelength free-air gravity anomalies combined with slow upper mantle seismic wave speeds suggest that the sub-lithospheric mantle provides substantial topographic support. A range of geodynamic processes have been invoked, including complex slab fragmentation and lithospheric delamination. The temporal and spatial evolution of the Anatolian landscape should be recorded by drainage networks. Indeed, major catchments contain prominent knickzones with heights of hundreds of meters and length scales of several hundred kilometers. The stream power formulation for fluvial erosion permits these knickzones to be interpreted in terms of uplift history along a river's length. Here, we jointly invert an inventory of 1,844 river profiles to determine a spatial and temporal uplift rate history. When calibrated against independent observations of uplift rate, the resultant history provides significant new constraints for the evolution of Anatolian topography. In our model, the bulk of this topography appears to grow in Neogene times. Uplift initiates in Eastern Anatolia and propagates westward at uplift rates of up to 0.5 mm/yr. Coeval with this phase of uplift, abundant basaltic magmatism has occurred throughout Anatolia. We have compiled an extensive database of published geochemical analyses. Using this database, we analyse spatial and temporal patterns of basaltic compositions to discriminate between different modes of melt generation. Two independent techniques for estimating asthenospheric potential temperatures from the compositions of

  8. Elements for a Comparative Study of Textile Production and Use in Hittite Anatolia and Neighbouring Areas

    DEFF Research Database (Denmark)

    Vigo, Matteo; Bellucci, Benedetta; Baccelli, Giulia

    2014-01-01

    to confirm the information provided by philologists. Over the last fifty years, many scholars have specifically investigated the textile terminology. Their results mainly consist of single corpus terminology. Looking at the Hittite Anatolia (XIX-XIII century BC) the scientific production does not seem so...... different. There are indeed specific monographs dealing with some aspects of Assyrian trade in Anatolia during the XIX-XVIII centuries BC, through which we are inform on trade routes, ‘textile topography’ (i.e. the provenance and the final destination of particular fabrics), costs of production and selling...... not currently exist. The aim of this paper is to present several key elements for a comparative study on the Hittite textile production and consumption. Starting from the textile production we will try to join the aforementioned results of archaeological analyses with the data provided by the Hittite textual...

  9. Diversity and homogeneity among the early farming communities of Western Anatolia

    Directory of Open Access Journals (Sweden)

    Eylem Özdoğan

    2016-12-01

    Full Text Available Our knowledge of the Neolithisation of Western Anatolia has increased considerably in recent years. Being located beyond, but on the border of the formative zone of Neolithisation, the region has acted as a buffer in the dispersal of the Neolithic way of life farther to the west. Recent research in Western Anatolia has shown that Neolithic sites appeared in the second quarter of the 7th millennium BC and had become widespread by the second half of the same millennium. There is now adequate data available on both the distribution of sites and the material culture in some subregions. In this context, this article will focus not on the Neolithisation process, but on the characteristic features of the sub-regions and the interaction between them.

  10. The Oldest Medical Center of the Anatolia : Gevher Nesibe Darussifa and Medical School

    Directory of Open Access Journals (Sweden)

    Bedri Selim Benek

    2015-06-01

    Full Text Available Turks started a diverse array of reconstruction activities following their settlement in Anatolia- Asia’s extended arm towards the Europe-. Within a short period, Turks built too many types of artifacts such as; madrasahs, mosques, darüssifas. In the   Turkish-Islamic darussifas (hospitals were established between India and Spain between 8th-17th centuries, medical subjects were taught according to researches and scientific principles, and surgeons were educated at medical madrasahs as well. Medical health care service was provided in those places. The pioneering artifacts in the treatment of several diseases in the quality of today’s clinics in terms of medicine, psychiatry and architecture. Gevher Nesibe Darussifa, built in Kayseri, is one of the oldest hospital and school of medicine in Anatolia.

  11. Block-like plate movements in eastern Anatolia observed by InSAR

    KAUST Repository

    Cavalie, Olivier

    2014-01-16

    The question whether continental plates deform internally or move as rigid blocks has been debated for several decades. To further address this question, we use large-scale interferometric synthetic aperture radar (InSAR) data sets to study how eastern Anatolia and its surrounding plates deform. We find that most of the deformation is focused at the North and East Anatolian faults and little intraplate deformation takes place. Anatolia is therefore moving, at least its eastern part, as a uniform block. We estimate the slip velocity and locking depth of the North Anatolian fault at this location to be 20 mm/yr and ~14 km, respectively. High deformation gradient found near the East Anatolian fault, on the other hand, suggests that little stress is accumulating along the eastern sections of that fault.

  12. Characterisation, phase stability and surface chemical properties of photocatalytic active Zr and y co-doped anatase TiO2 nanoparticles

    Czech Academy of Sciences Publication Activity Database

    Mattsson, A.; Lejon, C.; Bakardjieva, Snejana; Štengl, Václav; Österlund, L.

    2013-01-01

    Roč. 199, March (2013), s. 212-223 ISSN 0022-4596 R&D Projects: GA MPO FI-IM5/231 Institutional support: RVO:61388980 Keywords : Catalytic properties * Chemical synthesis * Nanostructures * Phase transactions Subject RIV: CA - Inorganic Chemistry Impact factor: 2.200, year: 2013

  13. The effects of subduction termination on the continental lithosphere: Linking volcanism, deformation, surface uplift, and slab tearing in central Anatolia

    Science.gov (United States)

    Delph, Jonathan R.; Abgarmi, Bijan; Ward, Kevin M.; Beck, Susan L.; Arda Ozacar, A.; Zandt, George; Sandvol, Eric; Turkelli, Niyazi; Kalafat, Dogan

    2017-04-01

    The lithospheric evolution of Anatolia is largely defined by processes associated with the terminal stages of subduction along its southern margin. Central Anatolia represents the transition from the subduction of oceanic lithosphere at the Aegean trench in the west to the Arabian - Eurasian continental collision in the east. In the overriding plate, this complicated transition is contemporaneous with uplift along the southern margin of central Anatolia (2 km in 6 Myr), voluminous felsic-intermediate ignimbrite eruptions (>1000 km3), extension, and tectonic deformation reflected by abundant low-magnitude seismic activity. The addition of 72 seismic stations as part of the Continental Dynamics - Central Anatolian Tectonics project, along with development of a new approach to the joint inversion of receiver functions and dispersion data, enables us obtain a high-resolution 3D shear wave velocity model of central Anatolia down to 150 km. This new velocity model has important implications for the complex interactions between the downgoing, segmenting African lithosphere and the overriding Anatolian Plate. These results reveal that the lithosphere of central Anatolia and the northern Arabian Plate is thin (4.5 km/s), indicating the presence of the Cyprean slab beneath central Anatolia. Thus, uplift of the Central Taurus Mountains may be due to slab rebound after the detachment of the oceanic portion of the Cyprean slab beneath Anatolia rather than the presence of shallow asthenospheric material. These fast velocities extend to the northern margin of the Central Taurus Mountains, giving way to a NE-SW trend of very slow upper mantle shear wave velocities (interpreted to be shallow, warm asthenosphere in which melt is present. The combination of a shallow asthenosphere and lithospheric-scale weaknesses associated with relict tectonic structures formed during the assembly of Anatolia are responsible for the spatial distribution of volcanism in the Central Anatolian

  14. Characterising bias in regulatory risk and decision analysis: An analysis of heuristics applied in health technology appraisal, chemicals regulation, and climate change governance.

    Science.gov (United States)

    MacGillivray, Brian H

    2017-08-01

    In many environmental and public health domains, heuristic methods of risk and decision analysis must be relied upon, either because problem structures are ambiguous, reliable data is lacking, or decisions are urgent. This introduces an additional source of uncertainty beyond model and measurement error - uncertainty stemming from relying on inexact inference rules. Here we identify and analyse heuristics used to prioritise risk objects, to discriminate between signal and noise, to weight evidence, to construct models, to extrapolate beyond datasets, and to make policy. Some of these heuristics are based on causal generalisations, yet can misfire when these relationships are presumed rather than tested (e.g. surrogates in clinical trials). Others are conventions designed to confer stability to decision analysis, yet which may introduce serious error when applied ritualistically (e.g. significance testing). Some heuristics can be traced back to formal justifications, but only subject to strong assumptions that are often violated in practical applications. Heuristic decision rules (e.g. feasibility rules) in principle act as surrogates for utility maximisation or distributional concerns, yet in practice may neglect costs and benefits, be based on arbitrary thresholds, and be prone to gaming. We highlight the problem of rule-entrenchment, where analytical choices that are in principle contestable are arbitrarily fixed in practice, masking uncertainty and potentially introducing bias. Strategies for making risk and decision analysis more rigorous include: formalising the assumptions and scope conditions under which heuristics should be applied; testing rather than presuming their underlying empirical or theoretical justifications; using sensitivity analysis, simulations, multiple bias analysis, and deductive systems of inference (e.g. directed acyclic graphs) to characterise rule uncertainty and refine heuristics; adopting "recovery schemes" to correct for known biases

  15. Overwintered Hatchlings of Emys orbicularis from Lake Sülüklü (Western Anatolia, Turkey

    Directory of Open Access Journals (Sweden)

    Dinçer Ayaz

    2011-07-01

    Full Text Available During our monitoring survey of amphibians and Emys orbicularis in Lake Sülüklü (Western Anatolia, Turkey, we observed four overwintered hatchlings of European pond turtle on May 4 and 10, 2010. The average straightline maximum carapace length of the neonates captured was 26.48 mm and their average weight was 4.18 g. This observation is the second record for the Turkish population of Emys orbicularis.

  16. A first record of late Middle Permian actinopterygian fish from Anatolia, Turkey

    Science.gov (United States)

    Hoşgör, Izzet; Štamberg, Stanislav

    2014-06-01

    The Middle-Upper Permian of the Gomaniibrik Formation, of the Tanin Group, in south-east Anatolia, close to the Iraq border, yielded moderately preserved fish remains. Two species, Palaeoniscum freieslebeni and Pygopterus cf. nielseni, known so far only from the Upper Permian deposits of the Zechstein Basin in western Central Europe, were recognised. This late Middle Permian Anatolian record significantly widens the geographical range of these actinopterygians into the equatorial Palaeotethys Realm.

  17. Investigation on The Blood Cell Counts of Chalcides ocellatus (Sauria: Scincidae) Population in Anatolia

    OpenAIRE

    MERMER, Ahmet

    2014-01-01

    In this investigation, the blood cell counts (erythrocyts and leucocyts) of 136 Chalcides ocellatus specimens (75 females + 61 males), collected from different locations in Anatolia have been investigated from the view point of the effects of geographical distance and altitude factors. The blood cell counts are found to be highest in the population from Gaziantep-Urfa and the cause of this difference is evaluated as due to geographic variation.

  18. An Autecological Study on the Vitex agnus-castus L. (Verbenaceae) Distributed in West Anatolia

    OpenAIRE

    DOĞAN, Yunus; MERT, Hasan Hüseyin

    2014-01-01

    This study covers the investigation of the soil-plant relations of Vitex agnus-castus L. (Verbenaceae), a typical element of Mediteranean macchia vegetation. Soils collected from 38 different localitis in West Anatolia were analysed together with the V. agnus-castus plants from the same localities. This plant was observed to generally prefer loamy-textured, neutral and slightly alka-line soils, poor in calcium carbonate, containing varying amounts of organic matter, being rich or very rich...

  19. Origin and significance of tourmalinites and tourmaline-bearing rocks of Menderes Massif, western Anatolia, Turkey

    OpenAIRE

    Yucel-ozturk, Yesim; Helvaci, Cahit; Palmer, Martin R.; Ersoy, E. Yalcin; Freslon, Nicolas

    2015-01-01

    In the western central portion of Anatolia lies the Menderes Massif – a large metamorphic crystalline complex made of Neoproterozoic to Precambrian basement rocks overlain by Palaeozoic to early Tertiary metasedimentary rocks, and with a multistage metamorphic evolution developed from the late Neo-Proterozoic to Eocene. We have undertaken a study of the petrology, geochemistry and boron isotope composition of these tourmaline occurrences aiming to constrain the processes responsible for the e...

  20. Chemical and physical-hydric characterisation of a red latosol after five years of management during the summer between-crop season

    Directory of Open Access Journals (Sweden)

    José Fausto Guimarães Silva

    2014-10-01

    Full Text Available Agricultural production systems that include the production of mulch for no-tillage farming and structural improvement of the soil can be considered key measures for agricultural activity in the Cerrado region without causing environmental degradation. In this respect, our work aimed to evaluate the chemical and physical-hydric properties of a dystrophic Red Latosol (Oxisol in the municipality of Rio Verde, Goias, Brazil, under different soil management systems in the between-crop season of soybean cultivation five years after first planting. The following conditions were evaluated: Brachiaria brizantha cv. Marandu as a cover crop during the between-crop season; Second crop of maize intercropped with Brachiaria ruziziensis; Second crop of grain alone in a no-tillage system; Fallow soil after the soybean harvest; and Forest (natural vegetation located in an adjacent area. Soil samples up to a depth of 40 cm were taken and used in the assessment of chemical properties and soil structure diagnostics. The results demonstrated that the conversion of native vegetation areas into agricultural fields altered the chemical and physical-hydric properties of the soil at all the depths evaluated, especially up to 10 cm, due to the activity of root systems in the soil structure. Cultivation of B. brizantha as a cover crop during the summer between-crop season increased soil water availability, which is important for agricultural activities in the region under study.

  1. Chemical characterisation of atmospheric aerosols during a 2007 summer field campaign at Brasschaat, Belgium: sources and source processes of biogenic secondary organic aerosol

    Directory of Open Access Journals (Sweden)

    Y. Gómez-González

    2012-01-01

    Full Text Available Measurements of organic marker compounds and inorganic species were performed on PM2.5 aerosols from a Belgian forest site that is severely impacted by urban pollution ("De Inslag", Brasschaat, Belgium during a 2007 summer period within the framework of the "Formation mechanisms, marker compounds, and source apportionment for biogenic atmospheric aerosols (BIOSOL" project. The measured organic species included (i low-molecular weight (MW dicarboxylic acids (LMW DCAs, (ii methanesulfonate (MSA, (iii terpenoic acids originating from the oxidation of α-pinene, β-pinene, d-limonene and Δ3-carene, and (iv organosulfates related to secondary organic aerosol from the oxidation of isoprene and α-pinene. The organic tracers explained, on average, 5.3 % of the organic carbon (OC, of which 0.7 % was due to MSA, 3.4 % to LMW DCAs, 0.6 % to organosulfates, and 0.6 % to terpenoic acids. The highest atmospheric concentrations of most species were observed during the first five days of the campaign, which were characterised by maximum day-time temperatures >22 °C. Most of the terpenoic acids and the organosulfates peaked during day-time, consistent with their local photochemical origin. High concentrations of 3-methyl-1,2,3-butanetricarboxylic acid (MBTCA and low concentrations of cis-pinonic acid were noted during the first five days of the campaign, indicative of an aged biogenic aerosol. Several correlations between organic species were very high (r>0.85, high (0.7<r<0.85, or substantial (0.5<r<0.7, suggesting that they are generated through similar formation pathways. Substantial correlations with temperature were found for OC, water-soluble OC, MBTCA, and several other organic species. MBTCA and terebic acid were highly correlated with the temperature (r>0.7 and showed an Arrhenius-type relationship, consistent with their formation through OH radical chemistry.

  2. Bottom ash from fluidising bed boilers as filler material in district heating pipe culverts. Chemical and geotechnical characterisation; Pannsand som kringfyllnadsmaterial foer fjaerrvaermeroergravar. Kemisk och geoteknisk karaktaerisering av fluidbaeddsand

    Energy Technology Data Exchange (ETDEWEB)

    Pettersson, Roger; Rogbeck, Jan; Suer, Pascal

    2004-01-01

    Bottom ashes from fluid bed boilers have been characterised, both geotechnically and chemically, in order to investigate the possibility to use them as filler material in district heating pipe culverts. Bottom ashes from both biofuel boilers and waste boilers are represented in this project. The companies which ashes have been characterised are Sundsvall Energi AB, Sydkraft OestVaerme AB, Sydkraft MaelarVaerme AB, Eskilstuna Miljoe och Energi, Stora Enso Fors, Soederenergi and Fortum Vaerme. A total of ten ashes have been analysed where three ashes originates from Sundsvall Energi AB, two from Sydkraft OestVaerme AB and one from the each of the remaining companies. The chemical analyses have been performed both on fresh ashes and on ashes aged for three months. The geotechnical analyses performed are grain size distribution, packing abilities and permeability. Chemical analyses performed are total content, available content, leaching tests (leaching both by shaking method and column procedure) and organic analyses (PAH, EOX, TOC, dioxin and fenol). The geotechnical analyses show that the ashes fulfils the demands that are put on the filler material used in district heating pipe culverts. When using the ashes in applications, light compaction should be performed due to the risk of crushing the material which may cause an increased amount of fine material. The leachability of fine material is larger than for coarse material. The ashes are relatively insensitive to precipitation. Bio fuel based bottom ashes have a lower content of environmental affecting substances than waste fuel based ashes. This is also shown in the leaching analyses. The leaching water from fresh ashes contains a higher concentration of leachable components than aged ashes. When aged the pH in the ashes decreases due to carbon uptake and hydration and this makes metals as Pb, Cu, Cr and Zn less mobile. On the other hand, an increase in leachability of Sb, Mo and SO{sub 4} is shown when the ashes

  3. Scanning electron microscopy and X-ray microanalysis for chemical and morphological characterisation of the inorganic component of gunshot residue: selected problems.

    Science.gov (United States)

    Brożek-Mucha, Zuzanna

    2014-01-01

    Chosen aspects of examinations of inorganic gunshot particles by means of scanning electron microscopy and energy dispersive X-ray spectrometry technique are presented. The research methodology of particles was worked out, which included a precise and repeatable procedure of the automatic detection and identification of particles as well as the representation of the obtained analytical data in the form of the frequencies of occurrence of particles of certain chemical or morphological class within the whole population of particles revealed in a specimen. On this basis, there were established relationships between the chemical and morphological properties of populations of particles and factors, such as the type of ammunition, the distance from the gun muzzle to the target, the type of a substrate the particles sediment on, and the time between shooting and collecting the specimens. Each of these aspects of examinations of particles revealed a great potential of being utilised in casework, while establishing various circumstances of shooting incidents leads to the reconstruction of the course of the studied incident.

  4. Chemical and electrical characterisation of the segregation of Al from a CuAl alloy (90%:10% wt) with thermal anneal

    International Nuclear Information System (INIS)

    Byrne, C.; Brady, A.; Walsh, L.; McCoy, A.P.; Bogan, J.; McGlynn, E.; Rajani, K.V.; Hughes, G.

    2016-01-01

    A copper–aluminium (CuAl) alloy (90%:10% wt) has been investigated in relation to segregation of the alloying element Al, from the alloy bulk during vacuum anneal treatments. X-ray photoelectron spectroscopy (XPS) measurements were used to track the surface enrichment of Al segregating from the alloy bulk during in situ ultra-high vacuum anneals. Secondary ion mass spectroscopy (SIMS) indicates a build-up of Al at the surface of the annealed alloy relative to the bulk composition. Metal oxide semiconductor (MOS) CuAl/SiO 2 /Si structures show a shift in flatband voltage upon thermal anneal consistent with the segregation of the Al to the alloy/SiO 2 interface. Electrical four point probe measurements indicate that the segregation of Al from the alloy bulk following thermal annealing results in a decrease in film resistivity. X-ray diffraction data shows evidence for significant changes in crystal structure upon annealing, providing further evidence for expulsion of Al from the alloy bulk. - Highlights: • CuAl alloy (90%:Al 10% wt) deposited and vacuum annealed • XPS and SIMS data show segregation of Al from the alloy bulk. • Chemical changes seen indicate the reduction of Cu oxide and growth of Al Oxide. • Electrical measurements indicate a chemical change at the metal/SiO 2 interface. • All data consistent with Cu diffusion barrier layer formed

  5. Scanning Electron Microscopy and X-Ray Microanalysis for Chemical and Morphological Characterisation of the Inorganic Component of Gunshot Residue: Selected Problems

    Directory of Open Access Journals (Sweden)

    Zuzanna Brożek-Mucha

    2014-01-01

    Full Text Available Chosen aspects of examinations of inorganic gunshot particles by means of scanning electron microscopy and energy dispersive X-ray spectrometry technique are presented. The research methodology of particles was worked out, which included a precise and repeatable procedure of the automatic detection and identification of particles as well as the representation of the obtained analytical data in the form of the frequencies of occurrence of particles of certain chemical or morphological class within the whole population of particles revealed in a specimen. On this basis, there were established relationships between the chemical and morphological properties of populations of particles and factors, such as the type of ammunition, the distance from the gun muzzle to the target, the type of a substrate the particles sediment on, and the time between shooting and collecting the specimens. Each of these aspects of examinations of particles revealed a great potential of being utilised in casework, while establishing various circumstances of shooting incidents leads to the reconstruction of the course of the studied incident.

  6. Hydrogeochemistry of the thermal waters from the Yenice Geothermal Field (Denizli Basin, Southwestern Anatolia, Turkey)

    Science.gov (United States)

    Alçiçek, Hülya; Bülbül, Ali; Alçiçek, Mehmet Cihat

    2016-01-01

    The chemical and isotopic properties of thermal waters (Kamara and Çizmeli) and cold springs from the Yenice Geothermal Field (YGF), in southwestern Anatolia, Turkey are investigated in order to establish a conceptual hydrogeochemical-hydrogeological model. These thermal waters derive from Menderes metamorphic rocks and emerge along normal faults; they are commonly used for heating of greenhouses and bathing facilities. Discharge temperatures of thermal waters are 32 °C to 57 °C (mean 51 °C) for Kamara and 35 °C to 68 °C (mean 47 °C) for Çizmeli, whereas deep groundwaters are 15 °C to 20.1 °C (mean 17 °C) and shallow groundwaters are 12 to 16 °C (mean 15 °C). Kamara and Çizmeli thermal waters are mostly of Na-Ca-HCO3-SO4 type, whereas deep groundwaters are Ca-Mg-HCO3 and Mg-Ca-HCO3 types and shallow groundwaters are mainly Mg-Ca-SO4-HCO3 and Ca-Mg-HCO3 types. In the reservoir of the geothermal system, dissolution of host rock and ion-exchange reactions changes thermal water types. High correlation in some ionic ratios (e.g. Na vs. Cl, K vs. Cl, HCO3 vs. Cl) and high concentrations of some minor elements (e.g., As, Sr, B, Cl, F) in thermal waters likely derive from enhanced water-rock interaction. Water samples from YGF have not reached complete chemical re-equilibrium, possibly as a result mixing with groundwater during upward flow. Geothermal reservoir temperatures are calculated as 89-102 °C for Kamara and 87-102 °C for Çizmeli fields, based on the retrograde and prograde solubilities of anhydrite and chalcedony. Based on the isotope and chemical data, a conceptual hydrogeochemical-hydrogeological model of the YGF has been constructed. Very negative δ18O and δ2H isotopic ratios (Kamara: mean of - 8.43‰ and - 56.9‰, respectively and Çizmeli: mean of - 7.96‰ and - 53.7‰, respectively) and low tritium values (< 1 TU) reflect a deep circulation pathway and a meteoric origin. Subsequent heating by conduction in the high geothermal gradient

  7. Source identification and airborne chemical characterisation of aerosol pollution from long-range transport over Greenland during POLARCAT summer campaign 2008

    Science.gov (United States)

    Schmale, J.; Schneider, J.; Ancellet, G.; Quennehen, B.; Stohl, A.; Sodemann, H.; Burkhart, J. F.; Hamburger, T.; Arnold, S. R.; Schwarzenboeck, A.; Borrmann, S.; Law, K. S.

    2011-10-01

    We deployed an aerosol mass spectrometer during the POLARCAT (Polar Study using Aircraft, Remote Sensing, Surface Measurements and Models, of Climate, Chemistry, Aerosols, and Transport) summer campaign in Greenland in June/July 2008 on the research aircraft ATR-42. Online size resolved chemical composition data of submicron aerosol were collected up to 7.6 km altitude in the region 60 to 71° N and 40 to 60° W. Biomass burning (BB) and fossil fuel combustion (FF) plumes originating from North America, Asia, Siberia and Europe were sampled. Transport pathways of detected plumes included advection below 700 hPa, air mass uplifting in warm conveyor belts, and high altitude transport in the upper troposphere. By means of the Lagrangian particle dispersion model FLEXPART, trace gas analysis of O3 and CO, particle size distributions and aerosol chemical composition 48 pollution events were identified and classified into five chemically distinct categories. Aerosol from North American BB consisted of 22% particulate sulphate, while with increasing anthropogenic and Asian influence aerosol in Asian FF dominated plumes was composed of up to 37% sulphate category mean value. Overall, it was found that the organic matter fraction was larger (85%) in pollution plumes than for background conditions (71%). Despite different source regions and emission types the particle oxygen to carbon ratio of all plume classes was around 1 indicating low-volatility highly oxygenated aerosol. The volume size distribution of out-of-plume aerosol showed markedly smaller modes than all other distributions with two Aitken mode diameters of 24 and 43 nm and a geometric standard deviation σg of 1.12 and 1.22, respectively, while another very broad mode was found at 490 nm (σg = 2.35). Nearly pure BB particles from North America exhibited an Aitken mode at 66 nm (σg = 1.46) and an accumulation mode diameter of 392 nm (σg = 1.76). An aerosol lifetime, including all processes from emission to

  8. Source identification and airborne chemical characterisation of aerosol pollution from long-range transport over Greenland during POLARCAT summer campaign 2008

    Directory of Open Access Journals (Sweden)

    J. Schmale

    2011-10-01

    Full Text Available We deployed an aerosol mass spectrometer during the POLARCAT (Polar Study using Aircraft, Remote Sensing, Surface Measurements and Models, of Climate, Chemistry, Aerosols, and Transport summer campaign in Greenland in June/July 2008 on the research aircraft ATR-42. Online size resolved chemical composition data of submicron aerosol were collected up to 7.6 km altitude in the region 60 to 71° N and 40 to 60° W. Biomass burning (BB and fossil fuel combustion (FF plumes originating from North America, Asia, Siberia and Europe were sampled. Transport pathways of detected plumes included advection below 700 hPa, air mass uplifting in warm conveyor belts, and high altitude transport in the upper troposphere. By means of the Lagrangian particle dispersion model FLEXPART, trace gas analysis of O3 and CO, particle size distributions and aerosol chemical composition 48 pollution events were identified and classified into five chemically distinct categories. Aerosol from North American BB consisted of 22% particulate sulphate, while with increasing anthropogenic and Asian influence aerosol in Asian FF dominated plumes was composed of up to 37% sulphate category mean value. Overall, it was found that the organic matter fraction was larger (85% in pollution plumes than for background conditions (71%. Despite different source regions and emission types the particle oxygen to carbon ratio of all plume classes was around 1 indicating low-volatility highly oxygenated aerosol. The volume size distribution of out-of-plume aerosol showed markedly smaller modes than all other distributions with two Aitken mode diameters of 24 and 43 nm and a geometric standard deviation σg of 1.12 and 1.22, respectively, while another very broad mode was found at 490 nm (σg = 2.35. Nearly pure BB particles from North America exhibited an Aitken mode at 66 nm (σg = 1.46 and an accumulation mode diameter of 392 nm (σg = 1

  9. Characterisation of titanium nitride films obtained by metalorganic chemical vapor deposition (MOCVD); Caracterizacao de filmes de nitreto de titanio obtidos por MOCVD

    Energy Technology Data Exchange (ETDEWEB)

    Pillis, M.F., E-mail: mfpillis@ipen.b [Instituto de Pesquisas Energeticas e Nucleares (CCTM/IPEN/CNEN-SP), Sao Paulo, SP (Brazil). Centro de Ciencia e Tecnologia de Materiais; Franco, A.C. [Universidade de Sao Paulo (IF/USP), SP (Brazil). Inst. de Fisica; Araujo, E.G. de [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil); Sacilotti, M. [Universidade Federal de Pernambuco (IF/UFPE), Recife, PE (Brazil). Inst. de Fisica; Fundacao de Amparo a Ciencia e Tecnologia de Pernambuco (FACEPE), Recife, PE (Brazil)

    2009-07-01

    Ceramic coatings have been widely used as protective coating to improve the life of cutting tools, for corrosion protection and in microelectronics, optical and medical areas. Transition metals nitrides are of special interest due to its high hardness and thermal stability. In this work thin films of titanium nitride were obtained by MOCVD (metalorganic chemical vapor deposition) process. The tests were carried out for 1h at 700 deg C under 80 and 100 mbar of pressure. The characterization was made by using scanning electron microscopy coupled with dispersive energy analysis, and X-ray diffraction. Preliminary results suggested that Ti{sub 2}N phase was formed and that the growth rate varied between 4 and 13 nm/min according to the process parameter considered. (author)

  10. Characterisation of Functional Surfaces

    DEFF Research Database (Denmark)

    Lonardo, P.M.; De Chiffre, Leonardo; Bruzzone, A.A.

    2004-01-01

    Characterisation of surfaces is of fundamental importance to control the manufacturing process and the functional performance of the part. Many applications concern contact and tribology problems, which include friction, wear and lubrication. This paper presents the techniques and instruments for...

  11. Toxic gas emissions from the Kayseri peat deposit, central Anatolia ...

    Indian Academy of Sciences (India)

    In this paper, the geology, petrography and chemical variation of the Kayseri peat deposit have been studied in order to predict the public health risk from the land gases' behaviour, especially in soil gases. The main volatile .... compounds, and water vapour. Radon is a radioac- tive gas and it is rare to find in the soil.

  12. Hierarchical cluster analysis and chemical characterisation of Myrtus communis L. essential oil from Yemen region and its antimicrobial, antioxidant and anti-colorectal adenocarcinoma properties.

    Science.gov (United States)

    Anwar, Sirajudheen; Crouch, Rebecca A; Awadh Ali, Nasser A; Al-Fatimi, Mohamed A; Setzer, William N; Wessjohann, Ludger

    2017-09-01

    The hydrodistilled essential oil obtained from the dried leaves of Myrtus communis, collected in Yemen, was analysed by GC-MS. Forty-one compounds were identified, representing 96.3% of the total oil. The major constituents of essential oil were oxygenated monoterpenoids (87.1%), linalool (29.1%), 1,8-cineole (18.4%), α-terpineol (10.8%), geraniol (7.3%) and linalyl acetate (7.4%). The essential oil was assessed for its antimicrobial activity using a disc diffusion assay and resulted in moderate to potent antibacterial and antifungal activities targeting mainly Bacillus subtilis, Staphylococcus aureus and Candida albicans. The oil moderately reduced the diphenylpicrylhydrazyl radical (IC 50  = 4.2 μL/mL or 4.1 mg/mL). In vitro cytotoxicity evaluation against HT29 (human colonic adenocarcinoma cells) showed that the essential oil exhibited a moderate antitumor effect with IC 50 of 110 ± 4 μg/mL. Hierarchical cluster analysis of M. communis has been carried out based on the chemical compositions of 99 samples reported in the literature, including Yemeni sample.

  13. Chemical and biological characterisation of solvent extracts and essential oils from leaves and fruit of two Australian species of Pittosporum (Pittosporaceae) used in aboriginal medicinal practice.

    Science.gov (United States)

    Sadgrove, Nicholas John; Jones, Graham Lloyd

    2013-02-13

    antimicrobial activity whilst the other chemotype had only moderate antimicrobial activity against the three microbial species investigated here. This result may support the occurrence of geographical specificity with regard to ethnopharmacological use. Antimicrobial activity screening of the solvent extracts from Pittosporum angustifolium revealed the leaves to be superior to fruit, with water being the most suitable extraction solvent. To the best of our knowledge, this study constitutes the first time essential oils, and solvent extracts from the fruits of Pittosporum angustifolium, have been examined employing comprehensive chemical and biological analysis. The essential oil composition presented in this paper, includes components with structural similarity as chemosemiotic compounds involved in mother-infant identification, which may have significance with regard to traditional applications as a lactagogue. Copyright © 2012 Elsevier Ireland Ltd. All rights reserved.

  14. Physico-chemical characterisation data and sorption measurements of Cs, Ni, Eu, Th, U, Cl, I and Se on MX-80 bentonite

    International Nuclear Information System (INIS)

    Bradbury, M. H.; Baeyens, B.

    2011-12-01

    The Laboratory for Waste Management of the Nuclear Energy and Safety Research Department at the Paul Scherrer Institute is performing work to develop and test models as well as to acquire specific data relevant to performance assessments of Swiss radioactive waste repositories. These investigations are undertaken in close co-operation with, and with the financial support of, the National Cooperative for the Disposal of Radioactive Waste (Nagra). The present report describes the work carried out on MX-80 bentonite in support of Swiss radioactive waste performance assessment studies. With particular regard to Stage 2 of the Sectoral Plan for deep geological disposal, it was considered to be important to bring together in one document the information and results that have accrued over the years from both 'in house' studies and associated relevant literature data. The report gives a brief overview of the physico-chemical characteristics and porewater chemistry determined for MX-80 bentonite followed by the results of an extensive experimental sorption programme on the uptake of Cs(I), Ni(II), Eu(III), Th(IV), U(VI), CI(-I), I(-I) and Se(IV) on the same material. Sorption values are also given for K(I), Ca(II) and Sr(II) which were deduced from porewater chemistry modelling studies. The main aim of this work is to provide a compilation of experimental data on sorption isotherms for key radionuclides on MX-80 bentonite in the frame of the Swiss radioactive waste disposal programme. However, they also provide basic data sets to test the predictive capacity of mechanistic sorption models. In the first part of this work the mineralogy and physico-chemical characteristics of the MX-80 bentonite used in this work are presented: mineralogy, surface areas, sulphate and chloride inventories, CEC, cation occupancies, selectivity coefficients for K-Na, Mg-Na and Ca-Na exchange equilibria, amphoteric edge site capacities and protolysis constants and whole rock analyses (trace

  15. Palaeocology of coal-bearing Eocene sediments in central Anatolia (Turkey) based on quantitative palynological data

    Energy Technology Data Exchange (ETDEWEB)

    Akkiraz, M.S.; Kayseri, M.S.; Akgun, F. [Dokuz Eylul University, Izmir (Turkey). Dept. of Geological Engineering

    2008-04-15

    In this study, the lignite-bearing Yoncali formation between Yozgat and Sorgun, in central Anatolia has been palynologically examined. Based on 37 outcrop samples, quantitative palynological studies recognized 64 genera and 136 palynoflora species in the palynological assemblage, which indicated a Middle-Late Eocene age. This paper also presents a quantitative palaeovegetation and palaeoclimate reconstruction for the Middle-Upper Eocene coal occurrences of Central Anatolia on the basis of palynomorph assemblages. The diversified floral and ecological characteristics of the pollen taxa indicates that the Middle-Upper Eocene formations in central Anatolia were characterized by the presence of a complex mangrove swamp with contributions by Nypa, Pelliciera, Avicennia, Diporites tszkaszentgydrgyi and dinoflagellate cysts which reflect warm climatic conditions. Lowland-riparian and montane elements are characterized by the dominance of Myricaceae, Symplocaceae, Icacinaceae, Quercus, Pinus and Castanea. Swamp-freshwater elements are represented by Sparganjaceae, Nymphaceae, Taxodjaceae, Cupressaceae and Nyssa as well as fern spores such as Osmundaceae and Gleicheniaceae. The calculations were performed with the help of the 'Coexistence Approach' method to climatically evaluate palynoflora from the Yozgat-Sorgun area. The obtained results have been compared to data derived from the application of the Coexistence Approach to other, already published Central Anatolian palynofloras of the same age. The results of the climatic inferences suggest that the palaeoclimatic conditions were in the megathermal zone, megatherm/mesotherm intermediate zone whereas mesothermic conditions prevailed in the montane region. Likewise, the results of mean annual range of temperatures indicate the influence of the Indian ocean, which enabled the development of the mangroves.

  16. EASTERN ANATOLIA OBSERVATORY (DAG): RECENT DEVELOPMENTS AND A PROSPECTIVE OBSERVING SITE FOR ROBOTIC TELESCOPES

    OpenAIRE

    C. Yesilyaprak; S.K. Yerli; O. Keskin

    2016-01-01

    El Observatorio del Este de Anatolia (DAG) es el nuevo observatorio de Turqu ́ı a que incluye un nuevo telescopio ́optico e IR (de la clase de 4m) en un robusto emplazamiento. Este proyecto nacional consiste de 3 fases: DAG (telescopio, habit ́aculo, edificios e infraestructuras), FPI (instrumentos de plano focal y ́optica adaptativa) y MCP (planta de recubrimiento de espejos) y est ́a apoyado por el Ministerio de D esarrollo de Turqu ́ıa. La solicitudes de oferta tanto por el telescopio co...

  17. Hide and Seek. Roads, Lookouts and Directional Visibility Cones in Central Anatolia

    Directory of Open Access Journals (Sweden)

    Turchetto Jacopo

    2017-01-01

    Full Text Available In Cappadocia (central Turkey, routes that were only of a secondary importance during the Roman age acquired a new relevance starting from the end of the 7th century. In this framework, to what extent did the archaeological evidence match the picture recalled by the written sources? To address this question, the relationship between movement and visibility was considered and view shed analyses were conducted from targeted and strategic spots set along the routes considered. This allowed to better understand the role and the different functions of those axes crossing Cappadocia, and to evaluate the Byzantine/Arab military strategies in central Anatolia.

  18. Geothermometry and Geobarometry of Kepsut-Dursunbey Volcanites (NW Anatolia, Turkey): Implications for Magma Chamber Depth and Crystallization Conditions

    Science.gov (United States)

    Kamaci, O.; Altunkaynak, S.

    2012-04-01

    The Kepsut-Dursunbey volcanic field (NW Turkey) contains various products of the Neogene magmatic activity. Two distinct volcanic suites have been recognized in the study area; Kepsut volcanic suite (KVS) and the Dursunbey volcanic suite (DVS). Both KVS and DVS are Early Miocene in age and representative for the post-collisional magmatism in western Anatolia. Mainly andesites, latites, basaltic andesites and pyroclastic rocks of KVS were formed during the early stage of volcanism in the study area. Without a major interruption in the volcanism, partly contemporanously, KVS followed by felsic volcanic products of DVS. Rhyolithic domes, lavas and extensive pyroclastic units were formed during this felsic volcanic activity. Both DVS and KVS display textural and chemical evidence for interaction of mafic and silicic magmas. This is evidenced by disequilibrium textures such as existence of rounded plagioclase phenocrysts with reaction rims (regrowth), hornblend -mantled clinopyroxenes (corona texture), synneusis, sieve textured plagioclase, patchy zones and oscilatory zoning in plagioclase phenocrysts. Basic lavas of KVS also contains xenocrysts represented by biotite mantled quartz and asidic plagioclase ovoids and glomerocrysts entrained from melt zones near base of the crust. The observed disequilibrium textures in both suites are provide evidence for magma mixing or Assimilation and fractional crystallization (AFC). Calculated pressures and temperatures using the amphibole-plagioclase geothermometer and Al-in-hornblend geobarometer give values of 5.7-7.0 kbar and 927-982 °C for the KVS and 3.7-5.3 kbar and 783-787°C for the DVS, indicating crystallization in magma chambers at deep and mid crustal levels; 21 km and 12 km, respectively. A main deep magma reservoir served as a source for the intermediate to basic lavas of KVS. The existence of similar mixing-compatible (disequilibrium) textures in both KVS and DVS support the establishment and evolution of KDVF magma

  19. Infections of Ligula intestinalis on Freshwater Fish in Kars Plateau of North-Eastern Anatolia, Turkey.

    Science.gov (United States)

    Arslan, Mükremin Özkan; Yılmaz, Muhittin; Taşçı, Gencay Taşkın

    2015-09-01

    This study was conducted to determine the prevalence of Ligula intestinalis and infections caused by these on freshwater fish in rivers and streams in the Kars plateau of north-eastern Anatolia, Turkey. This research was conducted between April and July 2011. Fish samples were caught via a casting net and an electro-shocker. The samples were immediately examined to determine the prevalence of L. intestinalis plerocercoids. In this research, 310 stream fishes were studied to determine the prevalence of L. intestinalis plerocercoids. Detected fishes included 55.8% Capoeta capoeta, 24.2% Squalius cephalus, 11.0% Alburnus filippii, 5.8% Barbus plebejus lacerta, and 3.2% Alburnoides bipunctatus. L. intestinalis plerocercoids were found in 2.6% (8/310) of the examined fishes. The percentage of this parasite was found to be 38.9% (7/18) on B. plebejus lacerta and 0.6% (1/173) on C. capoeta. L. intestinalis plerocercoids were not observed on the other three fish species (S. cephalus, A. filippii, and Al. bipunctatus). In this study, L. intestinalis plerocercoids were reported for the first time in the Kars stream and its distributaries on the Kars plateau in north-eastern Anatolia, Turkey.

  20. Frequencies of the Common Mefv Gene Mutations in Adiyaman, Southeast Anatolia, Turkey

    Directory of Open Access Journals (Sweden)

    Korkmaz D. T.

    2014-12-01

    Full Text Available Familial Mediterranean fever (FMF is an autosomal recessive disorder characterized by fever and serosal inflammation. The reasons for the disorder are mutations in the Mediterranean fever (MEFV gene; the most common of which are M694V, M680I, M694I and V726A. In this study, we aimed to screen these common mutations of the MEFV gene and then determine the prevalence of FMF according to these mutations in Adıyaman, Southeast Anatolia, Turkey. Seven hundred and sixty-seven healthy individuals from the region of Adıyaman participated in the study. Polymerase chain reaction-amplification refractory mutation system (PCR-ARMS methods were used to determine the common mutations of the MEFV gene. Twenty-six (3.9% individuals had only one mutation in the MEFV gene, 25 individuals were heterozygous and one person was homozygous for the V726A mutation (0.15%. In the present study, the V726A mutation (50.0% was the most frequent, followed by M694V (38.5%, M680I (7.7% and M694I (3.8%. It was seen that the carrier rate was very low and the prevalence of FMF was 0.15%, according to the common mutations of the MEFV gene in Adıyaman, Southeast Anatolia, Turkey.

  1. Dielectric characterisation of soil

    NARCIS (Netherlands)

    Hilhorst, M.A.

    1998-01-01

    The potential of dielectric measuring techniques for soil characterisation has not been fully explored. This is attributed to the complex and incomplete theory on dielectrics, as well as to the lack of sensors suited for practical applications.

    The theory on dielectric properties of soils is

  2. Characterisation of mouse prothymocytes

    NARCIS (Netherlands)

    Boersma, W.J.A.

    1982-01-01

    In this thesis, the study of growth kinetics of thymocytes in lethally irradiated mice as a means to characterise the early T-cell progenitors is described. Normal bone marrow cells were used as the source of hemopoietic cells. The experiments show that it is possible to obtain information on T-cell

  3. Characterisation of mouse prothymocytes

    NARCIS (Netherlands)

    W.J.A. Boersma (Wim)

    1982-01-01

    textabstractIn this thesis, the study of growth kinetics of thymocytes in lethally irradiated mice as a means to characterise the early T-cell progenitors is described. Normal bone marrow cells were used as the source of hemopoietic cells. The experiments show that it is possible to obtain

  4. Surface and Interface Characterisation

    DEFF Research Database (Denmark)

    De Chiffre, Leonardo

    2006-01-01

    Surface physical analysis, i.e. topography characterisation, encompasses measurement, visualisation, and quantification. This is critical for both component form and for surface finish at macro-, micro- and nano-scales. The principal methods of surface topography measurement are stylus profilometry...

  5. Characterisation of Chemical Degradation of Polymers

    DEFF Research Database (Denmark)

    Kjellander, Carina Koch

    2008-01-01

    Arbejdet har fokuseret på kemisk især hydrolytisk nedbrydning af industrielt vigtige polymerer eksponeret i forskellige aggressive men industrielt realistiske miljøer. Hovedvægten har ligget på eksponeringer af uforstærket polyamid 66 i 10% vandig NaOH ved 60 oC og i 5% NaOCl ved 20 oC i variende...

  6. microstructural characterisation, physical and chemical properties

    African Journals Online (AJOL)

    Mrs Abiodun

    Colour. Weight per cubic meter(kg/m3). Length, Width. (mm). Aspect ratio. (l÷w). Description. Location of. Collection. Faro 58/ O.sativa. Yellowish light brown (buff) BS. 381 359. 328.4. 5.87, 2.22. 2.64. Medium grained rice,. Bold. Oke-Ogun,. Oyo State. Olomo nla/Soro/. O.glaberrima. Yellowish light brown(buff) BS. 381 359.

  7. Microstructural characterisation, physical and chemical properties of ...

    African Journals Online (AJOL)

    The Energy dispersive x ray spectroscopy (EDX) analysis of rice husk ash performed to determine percentages of silica present in the samples were graphically represented. Nine elements (Al, Si, K, Ca, Br, Fe, Mg, Na, Mn) and their corresponding oxides (Al2O3 , SiO2 , K2O, CaO, Br, Fe2O3 , MgO, Na2 O, MnO) were ...

  8. CHEMICALS

    CERN Multimedia

    Medical Service

    2002-01-01

    It is reminded that all persons who use chemicals must inform CERN's Chemistry Service (TIS-GS-GC) and the CERN Medical Service (TIS-ME). Information concerning their toxicity or other hazards as well as the necessary individual and collective protection measures will be provided by these two services. Users must be in possession of a material safety data sheet (MSDS) for each chemical used. These can be obtained by one of several means : the manufacturer of the chemical (legally obliged to supply an MSDS for each chemical delivered) ; CERN's Chemistry Service of the General Safety Group of TIS ; for chemicals and gases available in the CERN Stores the MSDS has been made available via EDH either in pdf format or else via a link to the supplier's web site. Training courses in chemical safety are available for registration via HR-TD. CERN Medical Service : TIS-ME :73186 or service.medical@cern.ch Chemistry Service : TIS-GS-GC : 78546

  9. Reconstructing Early Pleistocene (1.3 Ma) terrestrial environmental change in western Anatolia: Did it drive fluvial terrace formation?

    NARCIS (Netherlands)

    Veldkamp, A.; Candy, I.; Jongmans, A.G.; Maddy, D.; Demir, T.; Schoorl, J.M.; Schreve, D.; Stemerdink, C.; Schriek, van der T.

    2015-01-01

    A terrestrial environmental reconstruction of an Early Pleistocene landscape from western Anatolia is presented. The basis of this reconstruction is a sedimentary stack comprising fluvial and colluvial slope deposits. Contained within this stack is a sequence comprising two massive laminar calcretes

  10. Paleomagnetic evidence for an inverse rotation history of Western Anatolia during the exhumation of Menderes core complex

    NARCIS (Netherlands)

    Uzel, Bora; Langereis, Cornelis G.; Kaymakçı, Nuretdin; Sözbilir, Hasan; Özkaymak, Çağlar; Özkaptan, Murat

    2015-01-01

    Within the Aegean extensional system, the Izmir-Balikesir Transfer Zone (IBTZ) is a crucial element in the late Cenozoic evolution of western Anatolia since it accommodates the differential deformation between the Cycladic and the Menderes metamorphic core complexes. Here, we determine the

  11. Waste package characterisation

    International Nuclear Information System (INIS)

    Sannen, L.; Bruggeman, M.; Wannijn, J.P.

    1998-09-01

    Radioactive wastes originating from the hot labs of the Belgian Nuclear Research Centre SCK-CEN contain a wide variety of radiotoxic substances. The accurate characterisation of the short- and long-term radiotoxic components is extremely difficult but required in view of geological disposal. This paper describes the methodology which was developed and adopted to characterise the high- and medium-level waste packages at the SCK-CEN hot laboratories. The proposed method is based on the estimation of the fuel inventory evacuated in a particular waste package; a calculation of the relative fission product contribution on the fuel fabrication and irradiation footing; a comparison of the calculated, as expected, dose rate and the real measured dose rate of the waste package. To cope with the daily practice an appropriate fuel inventory estimation route, a user friendly computer programme for fission product and corresponding dose rate calculation, and a simple dose rate measurement method have been developed and implemented

  12. Waste package characterisation

    Energy Technology Data Exchange (ETDEWEB)

    Sannen, L.; Bruggeman, M.; Wannijn, J.P

    1998-09-01

    Radioactive wastes originating from the hot labs of the Belgian Nuclear Research Centre SCK-CEN contain a wide variety of radiotoxic substances. The accurate characterisation of the short- and long-term radiotoxic components is extremely difficult but required in view of geological disposal. This paper describes the methodology which was developed and adopted to characterise the high- and medium-level waste packages at the SCK-CEN hot laboratories. The proposed method is based on the estimation of the fuel inventory evacuated in a particular waste package; a calculation of the relative fission product contribution on the fuel fabrication and irradiation footing; a comparison of the calculated, as expected, dose rate and the real measured dose rate of the waste package. To cope with the daily practice an appropriate fuel inventory estimation route, a user friendly computer programme for fission product and corresponding dose rate calculation, and a simple dose rate measurement method have been developed and implemented.

  13. Analysis of Seismic Anisotropy Across Central Anatolia by Shear Wave Splitting

    Science.gov (United States)

    Pamir, Dilekcan; Abgarmi, Bizhan; Arda Özacar, A.

    2014-05-01

    Analysis of Seismic Anisotropy Across Central Anatolia by Shear Wave Splitting Dilekcan Pamir, Bizhan Abgarmi, A. Arda Özacar Department of Geological Engineering, Middle East Technical University (METU), Dumlupinar Bulvari 1, 06800 Ankara, Turkey Central Anatolia holds the key to connect the theories about the ongoing tectonic escape, the African Plate subduction along Cyprus Arc and the indenter-style collision of Arabian Plate along Bitlis Suture. However, the shear wave splitting measurements which are needed to characterize seismic anisotropy are very sparse in the region. Recently, seismic data recorded by national seismic networks (KOERI, ERI-DAD) with dense coverage, provided a unique opportunity to analyze the effect of present slab geometry (slab tears, slab break-off) on mantle deformation and test different models of anisotropy forming mechanisms. In this study, the anisotropic structure beneath the Central Anatolia is investigated via splitting of SKS and SKKS phases recorded at 46 broadband seismic stations. Our measurements yielded 1171 well-constrained splitting and 433 null results. Overall, the region displays NE-SW trending fast splitting directions and delay times on the order of 1 sec. On the other hand, a large number of stations which are spatially correlated with Cyprus Slab, Neogene volcanism and major tectonic structures present significant back azimuthal variations on splitting parameters that cannot be explained by one-layered anisotropy with horizontal symmetry. Thus, we have modeled anisotropy for two-layered structures using a forward approach and identified NE-SW trending fast splitting directions with delay times close to 1 sec at the lower layer and N-S, NW-SE trending fast splitting with limited time delays (0.1 - 0.3 sec) at the upper layer. Fast directions and delay times of the lower layer are similar to one-layered anisotropy and parallel or sub-parallel to the absolute plate motions which favors asthenospheric flow model

  14. Multidimensional Mantle Convection Models in Eastern Anatolia, the North Arabian Platform, and Caucasus Region

    Science.gov (United States)

    Sengul Uluocak, E.; Shahnas, H.; Pysklywec, R.; Gogus, O.; Eken, T.

    2017-12-01

    Eastern Anatolia, the North Arabian Platform, and Caucasus regions show many features of collisional tectonics with different convergence rates and shortening from south to north. The volcanism, sediment provenience, and thermochronological data suggest that the shortening and exhumation in the Greater Caucasus started during the Eocene-Oligocene synchronously with the collision between Arabia-Bitlis-Pötürge Massif in the south. Previous works indicate that the uplift (up to 2 km) in Eastern Anatolia related to upwelling mantle following the deformation of the Arabian oceanic lithosphere ( 11 Ma) during the ongoing Greater Caucasus closure is the dominant tectonic processes in the center of the region. However, there is no integrated geodynamic model that explains the deformation mechanisms of the region -and their possible interactions with each other -under the dynamic forces. In this study, we use multidimensional mantle-lithosphere convection/deformation models to quantify the geodynamic processes as constrained by the geological/geophysical observations in the region. For the models, seismic studies provide the high-resolution images of the upwelling mantle beneath Eastern Anatolia and the presence -and the locations- of the seismically fast structures associated with the relic/subducted slabs at varying depths such as the Bitlis slab in the south, and the Pontide and Kura slabs in the north. Fast polarization directions observed from splitting analyses exhibit an overall NE-SW oriented mantle anisotropy and a comparison between Pn and SKS derived fast wave azimuths indicates a crust-mantle coupling most likely implying vertically coherent deformation to the north of the study area. For the geodynamic models, we modify the mantle and lithosphere rheology as well as the thermal state. We interpret the estimated uplift and subsidence anomalies related to lithospheric variations (ranging from 54 km to 211 km) and subducting slab behavior with observed

  15. Fatty acid composition of some walnut ( Juglans regia L. cultivars from east Anatolia

    Directory of Open Access Journals (Sweden)

    Akgul, Attila

    2005-12-01

    Full Text Available In this study, the fatty acid composition of different walnut (Juglans regia L. cultivars grown in Adilcevaz in east Anatolia was determined. The total oil content of the walnuts ranged from 65.00 ± 0.06 to 70.00 ± 0.58 %. The oleic acid content of the oils ranged from 22.63 to 27.27 % of the total fatty acids while the linoleic acid and linolenic contents ranged from 49.93 to 54.41 % and 14.32 to 17.82 % respectively. The palmitic acid content of the walnuts ranged from 5.61 % to 5.82 % while there was a trace amount of miristic acid (En este estudio se ha determinado la composición en ácidos grasos de diferentes cultivos de nueces ( Juglans regia L. producidos en Adilcevaz en el Este de Anatolia. El contenido de aceite total de las nueces osciló entre 65.00 ± 0.06 y 70.00 ± 0.58 %. El contenido en ácido oleico varió desde 22.63 a 27.27 % respecto a los ácidos grasos totales mientras que los contenidos en ácido linoleico y linolénico variaron desde 49.93 hasta 54.41 % y desde 14.32 hasta 17.82 % respectivamente. El contenido en ácido palmítico de las muestras de nueces estuvo comprendido entre 5.61 y 5.82 % mientras que de ácido miristico solo se encontraron trazas ( < 0.1 %. Finalmente, los resultados de los ácidos grasos indicaron que los cultivos de nueces del Este de Anatolia son distintos en cuanto a su perfil de ácido linolenico. Estos resultados pueden ser significativos para estudios de selección en orden a identificar mejor las variedades de nueces para dietas saludables.

  16. Soil Radiological Characterisation Methodology

    International Nuclear Information System (INIS)

    Attiogbe, Julien; Aubonnet, Emilie; De Maquille, Laurence; De Moura, Patrick; Desnoyers, Yvon; Dubot, Didier; Feret, Bruno; Fichet, Pascal; Granier, Guy; Iooss, Bertrand; Nokhamzon, Jean-Guy; Ollivier Dehaye, Catherine; Pillette-Cousin, Lucien; Savary, Alain

    2014-12-01

    This report presents the general methodology and best practice approaches which combine proven existing techniques for sampling and characterisation to assess the contamination of soils prior to remediation. It is based on feedback of projects conducted by main French nuclear stakeholders involved in the field of remediation and dismantling (EDF, CEA, AREVA and IRSN). The application of this methodology will enable the project managers to obtain the elements necessary for the drawing up of files associated with remediation operations, as required by the regulatory authorities. It is applicable to each of the steps necessary for the piloting of remediation work-sites, depending on the objectives targeted (release into the public domain, re-use, etc.). The main part describes the applied statistical methodology with the exploratory analysis and variogram data, identification of singular points and their location. The results obtained permit assessment of a mapping to identify the contaminated surface and subsurface areas. It stakes the way for radiological site characterisation since the initial investigations from historical and functional analysis to check that the remediation objectives have been met. It follows an example application from the feedback of the remediation of a contaminated site on the Fontenay aux Roses facility. It is supplemented by a glossary of main terms used in the field from different publications or international standards. This technical report is a support of the ISO Standard ISO ISO/TC 85/SC 5 N 18557 'Sampling and characterisation principles for soils, buildings and infrastructures contaminated by radionuclides for remediation purposes'. (authors) [fr

  17. Emission factors and chemical characterisation of fine particulate emissions from modern and old residential biomass heating systems determined for typical load cycles; Emissionsfaktoren und chemische Charakterisierung von Feinstaubemissionen moderner und alter Biomasse-Kleinfeuerungen ueber typische Tageslastverlaeufe

    Energy Technology Data Exchange (ETDEWEB)

    Kelz, Joachim [BIOENERGY 2020+ GmbH, Graz (Austria); Brunner, Thomas; Obernberger, Ingwald [BIOENERGY 2020+ GmbH, Graz (Austria); Technische Universitaet Graz, Institut fuer Prozess- und Partikeltechnik, Graz (Austria); BIOS BIOENERGIESYSTEME GmbH, Graz (Austria)

    2012-12-15

    It is already well known that there are significant differences regarding the emissions, especially particulate matter (PM) emissions, of old and modern as well as automatically and not automatically controlled biomass based residential heating systems. This concerns their magnitude as well as their chemical composition. In order to investigate emission factors for particulate emissions and the chemical compositions of the PM emissions over typical whole day operation cycles, a project on the determination and characterisation of PM emissions from the most relevant small-scale biomass combustion systems was performed at the BIOENERGY 2020+ GmbH, Graz, Austria, in cooperation with the Institute for Process and Particle Engineering, Graz University of Technology. The project was based on test stand measurements, during which relevant operation parameters (gaseous emissions, boiler load, flue gas temperature, combustion chamber temperature etc.) as well as PM emissions have been measured and PM samples have been taken and forwarded to chemical analyses. Firstly, typical whole day operation cycles for residential biomass combustion systems were specified for the test runs. Thereby automatically fed and automatically controlled boilers, manually fed and automatically controlled boilers as well as manually fed stoves were distinguished. The results show a clear correlation between the gaseous emissions (CO and OGC) and the PM{sub 1} emissions. It is indicated that modern biomass combustion systems emit significantly less gaseous and PM emissions than older technologies (up to a factor of 100). Moreover, automatically fed systems emit much less gaseous and PM emissions than manually fed batch-combustion systems. PM emissions from modern and automatically controlled systems mainly consist of alkaline metal salts, while organic aerosols and soot dominate the composition of aerosols from old and not automatically controlled systems. As an important result comprehensive data

  18. Pollen analysis of coal-bearing Miocene sedimentary rocks from the Seyitomer basin (Kutahya), western Anatolia

    Energy Technology Data Exchange (ETDEWEB)

    Yavuz-Isik, N. [Ondokuz Mayis University, Kurupelit (Turkey). Dept. of Civil Engineering

    2007-09-15

    The late Early-Middle Miocene sequences of the Seyitomer Basin (western Anatolia) were palynologically investigated. Fifty-five taxa belonging to seven gymnospermous and 48 angiospermous pollen genera were identified in the 19 productive samples. Two pollen zones were recognised based on the changing abundance of individual tree taxa. Zone 1 is characterized by predominance of Pinus and Cedrus. Zone 2 is characterized by predominance of deciduous Quercus and evergreen Quercus and a marked reduction in representation of Taxodiaceae. The differences in the pollen spectra between Zone 1 and Zone 2 may reflect the global Middle Miocene cooling. These results are largely comparable to pollen data derived from the neighbouring areas. The vegetation of the Seyitomer Basin was dominated by trees. This palynological analysis reveals the existence of a swamp-forest developed in a subtropical to warm-temperate humid climate.

  19. Estimating the horizontal diffuse solar radiation over the Central Anatolia Region of Turkey

    International Nuclear Information System (INIS)

    Aras, Haydar; Balli, Ozgur; Hepbasli, Arif

    2006-01-01

    The main objective of the present study is to develop new hybrid models to predict the monthly average daily diffuse solar radiation on a horizontal surface over Turkey's Central Anatolia Region (CAR), which covers the 12 provinces (Afyon, Ankara, Cankiri, Corum, Eskisehir, Kayseri, Kirsehir, Konya, Nevsehir, Nigde, Sivas and Yozgat), as an example. The models proposed by many investigators to estimate the diffuse solar radiation were reviewed. Although the global solar radiation and sunshine duration have been measured by the Turkish State Meteorological Service (DMI) over all the country since 1964, the diffuse solar radiation has not been measured. The twelve new hybrid models for estimating the monthly average daily diffuse solar radiation on a horizontal surface in the CAR were validated, and thus, the most accurate model was selected for guiding future projects

  20. Eastern Anatolia Observatory (DAG): Recent developments and a prospective observing site for robotic telescopes

    Science.gov (United States)

    Yesilyaprak, C.; Yerli, S. K.; Keskin, O.

    2016-12-01

    This document (Eastern Anatolia Observatory (DAG) is the new observatory of Turkey with the optical and near-infrared largest telescope (4 m class) and its robust observing site infrastructure. This national project consists of three phases with DAG (Telescope, Enclosure, Buildings and Infrastructures), FPI (Focal Plane Instruments and Adaptive Optics) and MCP (Mirror Coating Plant) and is supported by the Ministry of Development of Turkey. The tenders of telescope and enclosure have been made and almost all the infrastructure (roads, geological and atmospherical surveys, electricity, fiber optics, cable car, water, generator, etc.) of DAG site (Erzurum/Turkey, 3,170 m altitude) have been completed. This poster is about the recent developments of DAG and about the future possible collaborations for various robotic telescopes which can be set up in DAG site.

  1. Seroprevalence of brucellosis among children in the Middle Anatolia Region of Turkey.

    Science.gov (United States)

    Gül, Serdar; Satilmiş, Ozgun Kiriş; Ozturk, Baris; Gökçe, Mehmet Ilker; Kuscu, Ferit

    2014-12-01

    Brucellosis is an important public-health problem in Turkey. Children may constitute 20 to 30% of all brucellosis cases in the world, especially in the endemic regions. Data on the seroprevalence of brucellosis in childhood are very limited. In this study, we aimed to evaluate the seroprevalence of brucellosis among a child population. One thousand one hundred and ten subjects were included in the study. Blood samples were collected and tested with Rose Bengal (RB) and standard tube agglutination test (SAT). RB test results were positive for 6 patients, and SAT was negative for all patients. Our findings suggest that seroprevalence of brucellosis is decreasing in Middle Anatolia due to a new cattle vaccination and eradication programme which was initiated in 2009.

  2. Active optics system for the 4m telescope of the Eastern Anatolia Observatory (DAG)

    Science.gov (United States)

    Lousberg, Gregory P.; Mudry, Emeric; Bastin, Christian; Schumacher, Jean-Marc; Gabriel, Eric; Pirnay, Olivier; Flebus, Carlo

    2016-07-01

    An active optics system is being developed by AMOS for the new 4m-class telescope for the Turkish Eastern Anatolia Observatory (DAG). It consists in (a) an adjustable support for the primary mirror and (b) two hexapods supporting M2 and M3. The M1 axial support consists of 66 pneumatic actuators (for mirror shape corrections) associated with 9 hydraulic actuators that are arranged in three independent circuits so as to fix the axial position of the mirror. Both M1 support and the hexapods are actively controlled during regular telescope operations, either with look-up tables (openloop control) or using optical feedback from a wavefront sensor (closed-loop control).

  3. Study of attenuation structure for central Anatolia region, Turkey based on Keskin seismic array data

    Science.gov (United States)

    Semin, K. U.; Ozel, N. M.

    2011-12-01

    Central Anatolia is bounded in the north by the well-known north Anatolian fault system (NAFS) and on the south-southwest is bounded by the east Anatolian fault system (EAFS). The central area does not have major faults and acts as a single block moving westward. This region is not considered as seismically active as the NAFS or EAFS but the recent moderate-size Bala earthquakes (Ml=5.7, Ml= 5.5) on 20 and 27 December 2007 near the Tuz golu fault may be an indication of future seismic activity. In order to get a better picture of the crustal structure of this region we applied Coda Normalization method for the measurement of Qs-1 as a function of frequency for the frequencies 1.5, 3, 6, 8 Hz. 20 and 27 December 2007 Bala earthquakes (Ml magnitude 5.6 an 5.5) and their aftershocks recorded by the Keskin seismic array (International Monitoring System code BRTR) is analyzed in this study. Keskin seismic array has a small aperture circular design with 6 vertical short period and 1 broadband borehole seismometers. In addition, Multiple Lapse Time Window Analysis (MLTWA) method was applied to the data for the separation of intrinsic and scattering attenuation inm the region at the same frequencies. MLTWA method allowed a separation between the intrinsic attenuation and scattering attenuation. Preliminary results show a relatively low attenuation compared to western and eastern anatolia regions. This might be explained by the less seismicity in the region. A study of the regional and site attenuation of seismic waves of earthquakes in this area will contribute in predicting earthquake generated ground-motion and becomes vital in making decisions for earthquake regulations, building codes and to monitoring nuclear explosions.

  4. Sedimentary lipid biomarkers in the magnesium rich and highly alkaline Lake Salda (south-western Anatolia

    Directory of Open Access Journals (Sweden)

    Jérôme Kaiser

    2016-06-01

    Full Text Available Lake Salda located in south-western Anatolia is characterized by the presence of living stromatolites and by a low diversity of both phytoplankton and zooplankton due to high pH and magnesium concentration. The most abundant, free sedimentary lipids of the uppermost centimetres of the lake sediments were studied as potential environmental biomarkers, and proxies based on glycerol dialkyl glycerol tetraethers (GDGT were tested in this extreme environment. Dinosterol and tetrahymanol are potentially relevant biomarkers for the dinoflagellate Peridinium cinctum and ciliates, respectively. C20:1 and C25:2 highly branched isoprenoid (HBI alkenes, and n-C17 alkane and n-C17:1 alkene are considered as representing, respectively, diatoms and Cyanobacteria involved in the formation of the stromatolites. Isoprenoid GDGT-0 is assumed to be derived mainly from Euryarchaeota (methanogens, and crenarchaeol from Thaumarchaeota. Allochthonous organic material is represented by long-chain n-alkanes and n-alkanols derived from land plant leaf waxes, as well as branched GDGTs produced by soil bacteria. While pH and temperature proxies based on branched GDGTs are likely not applicable in Lake Salda, TEX86 (tetraether index of tetraethers consisting of 86 carbons, a proxy based on isoprenoid GDGTs, potentially allows estimating mean annual lake surface temperature. Interestingly, C23 and C25 1,2 diols, which have a yet unknown origin, were found for the first time in lake sediments. This study represents the first investigation of sedimentary lipid distribution in an alkaline and magnesium-rich lake in Anatolia, and provides a basis for future biomarker-based paleoenvironmental reconstruction of Lake Salda.

  5. Volcano-stratigraphy and Petrography of the Hasandaǧ Volcanites (Central Anatolia)

    Science.gov (United States)

    Zeynep Çalışkanoǧlu, Ayşe; Ünal, Alp; Karadaǧ, Elif; Altunkaynak, Şafak; Görür, Naci

    2016-04-01

    The Hasandaǧ stratovolcano is one of the crucial volcanos within the Cappadocian Volcanic Complex, located in Central Anatolia, Turkey. In Quaternary, it produced various types of volcanic rocks including a variety of lava flows, domes and associated pyroclastic and volcanoclastic rocks. In this study, volcano-stratigraphy and petrography of the volcanic rocks which forms the SE flank of the Hasandaǧ stratovolcano will be presented. The early pyroclastic products associated with plinian-subplinian eruptions cover large areas with different thickness in the region. Felsic pyroclastic rocks are dominant and represented by ash, pumice and pumice-block tuffs and accretionary lapilli tuffs/breccias. Pyroclastic deposits are present as thin layers of reworked tuffs intercalated with sedimentary rocks (mudstone and marl) at the bottom of the volcanic sequence. They interfinger with pyroclastic flow deposits dominated by welded tuff and ignimbrite succession towards the upper parts of the sequence. Andesite- basaltic andesite and basaltic trachy-andesite lavas form the most common lava phase in the region and overlie the pyroclastic succession. At the upper parts of the volcanic succession, basaltic dykes and associated pyroclastic rocks are observed. The youngest member of the volcanic association is represented by andesitic-basaltic andesitic dykes which were injected into basaltic lavas and associated proclastic rocks. The areal distribution of the volcanic rocks in the SE flank of the Hasandaǧ stratovolcano indicates that they were erupted from a number of vents which set parallel to the NW-SE trending major fault systems of Central Anatolia (eg. The Salt Lake Fault). Petrographic investigations indicate that, all lava samples display several textures reflecting disequilibrium crystallization such as different stage of the plagioclase crystallization, sieve texture in plagioclases, clinopyroxene crystals mantled by hornblende (corona texture) and reaction textures

  6. Seismotectonics of the southern boundary of Anatolia, Eastern Mediterranean region: subduction, collision, and arc jumping

    Energy Technology Data Exchange (ETDEWEB)

    Rotstein, Y.; Kafka, A.L.

    1982-09-10

    The pattern of seismicity and fault plane solutions of earthquakes are used to outline the tectonic features of the southern boundary of Anatolia in the eastern Mediterranean and southeastern Turkey. The results of this study show that this boundary is composed of two distinct parts. One, in southeastern Turkey and Syria, is a wide and complex zone of continental collision. The other, in the Levantine basin of the eastern Mediterranean, is a zone of oceanic subduction. In the region of continental collision three zones of seismicity are observed. Most of the seismic activity in this region follows the Bitlis zone and is associated with a zone of thrusting and mountain building. This appears to be the zone of most active deformation and plate consumption in the plate boundary region between Arabia and Turkey. A less active zone of seismicity to the north of the Bitlis zone is interpreted to have been more active in the past whereas another active zone of seismicity to the south is interpreted to be a zone which may be more active in the future as the main zone of plate consumption jumps to the south. In the subduction zone of the eastern Mediterranean the depth of the subducted slab and the rate of seismicity generally increease from east to west. The zone of present-day convergence between Africa and Turkey in the Levantine basin can be best outlined by the northern edge of the Mediterranean ridge. Deep seismic activity near the Gulf of Antalya is associated with a detached subducted slab north of the Anaximander Mountains that is distinctly different from the seismic trend which is associated with present-day active subduction. Most of the focal mechanisms of the earthquakes along the entire southern boundary of Anatolia indicate that N to NNW thrusting is the dominant mode of seismic deformation.

  7. Post-Paleogene Deformation in central Anatolia, South of Ankara (Turkey)

    Science.gov (United States)

    Rojay, Bora

    2014-05-01

    The closure of the northern Neo-Tethys took place between Eurasia in the north and northern edge of Afro- Arabian plate in the south since the Early Cretaceous is documented in central Anatolia. It is mated by Cretaceous ophiolitic mélanges thrusted over southwards on to the upper Cretaceous-Paleogene fore-arc and foreland sequences along the northern margins of Haymana and Tuzgölü basins, respectively. Two main deformation episodes are recognized in the region. These include post-Cretaceous-pre Miocene compressional regime and Miocene to mid-Pliocene transcurrent regime dominated extensional deformation. The first regime is characterize by NW-SE directed compressional and contractional deformation dominated by south vergent, large wave length, asymmetric to overturned folds and associated thrust/reverse faults. Some of these reverse faults were reactivated as strike-slip faults with reverse components as evidenced by cross-cutting relationships and overprinting slickensides observed extensively in the field. Along these reactivated faults, echelon calcite veins, fault parallel meter thick silica walls with repeated phases of deformation are very common. Following the Miocene, the region is affected by a NNE-SSW to NE-SW directed extension, possibly resulted from the interaction of Tuzgölü Fault with the northwards convex splays of dextral North Anatolian Fault extending into the region. As a conclusion, the Paleogene sequences with ophiolitic mélanges are deformed under NNE-SSW directed compression related to the development of dextral strike slip tectonics during post-Paleogene-pre-Miocene period. Keywords:fault plane slip data, transcurrent regime, post-Paleogene, central Anatolia.

  8. ONKALO. Underground characterisation and research programme (UCRP)

    International Nuclear Information System (INIS)

    2003-09-01

    impacts of ONKALO's construction and operation. Basically all geoscientific disciplines, geology, hydrogeology, geochemistry and rock mechanics follow the same workflow. Integration between modelling in different disciplines is essential and an integrated modelling task force will be formed. Posiva will also use ONKALO for tests and experiments, in which the site-specific conditions at Olkiluoto have to be taken into account. The detailed programme for such testing will be developed once the tunnel progresses further. Already at present specific tests are planned related to construction and characterisation issues. These involve exploration of the mechanical and chemical impact on the rock and the impact of grouting. (orig.)

  9. Characterisation of humic material for inter-laboratory comparison

    International Nuclear Information System (INIS)

    Peachy, D.; Bradley, A.D.; Davis, A.E.; Stuart, M.E.; Tait, B.A.R.; Vickers, B.P.; Williams, G.M.

    1988-01-01

    The characterisation and interlaboratory comparison of common humic materials by members of the European Commission's COCO group (set up to study complexes and colloids), forms part of a study of the effects of natural organic compounds in groundwater on the complexation and mobility of radionuclides. Three samples have been characterised: a sodium salt and a protonated form of the commercially available humic acid from Aldrich Chemicals; and a protonated humic acid from the Gorleben research site in Germany. Characterisation undertaken by BGS includes moisture content, elemental analysis, metal content, functional group analysis, infra-red spectroscopy, ultra-violet absorbance (E 4 /E 6 ratios), and ultra-filtration. (author)

  10. Precipitation and characterisation of lignin obtained from South African kraft mill black liquor

    CSIR Research Space (South Africa)

    Namane, M

    2014-07-01

    Full Text Available International Conference on Chemical Thermodynamics and South African Institution of Chemical Engineering Conference, Durban, South Africa, 27 July - 1 August 2014 Precipitation and characterisation of lignin obtained from South African kraft mill black...

  11. Synthesis, structure, and characterisation of a new phenolato-bridged manganese complex [Mn2(mL)2]2+: chemical and electrochemical access to a new mono-mu-oxo dimanganese core unit.

    Science.gov (United States)

    Hureau, Christelle; Sabater, Laurent; Anxolabéhère-Mallart, Elodie; Nierlich, Martine; Charlot, Marie-France; Gonnet, Florence; Rivière, Eric; Blondin, Geneviève

    2004-04-19

    The dinuclear phenolato-bridged complex [(mL)Mn(II)Mn(II)(mL)](ClO(4))(2) (1(ClO(4))(2)) has been obtained with the new [N(4)O] pentadentate ligand mL(-) (mLH=N,N'-bis-(2-pyridylmethyl)-N-(2-hydroxybenzyl)-N'-methyl-ethane-1,2-diamine) and has been characterised by X-ray crystallography. X- and Q-band EPR spectra were recorded and their variation with temperature was examined. All spectra exhibit features extending over 0-800 mT at the X band and over 100-1450 mT at the Q band, features that are usually observed for dinuclear Mn(II) complexes. Cyclic voltammetry of 1 exhibits two irreversible oxidation waves at E(1)(p)=0.89 V and E(2)(p)=1.02 V, accompanied on the reverse scan by an ill-defined cathodic wave at E(1')(p)=0.56 V (all measured versus the saturated calomel electrode (SCE)). Upon chemical oxidation with tBuOOH (10 equiv) at 20 degrees C, 1 is transformed into the mono-mu-oxo species [(mL)Mn(III)-(mu-O)-Mn(III)(mL)](2+) (2), which eventually partially evolves into the di-mu-oxo species [(mL)Mn(III)-(mu-O)(2)-Mn(IV)(mL)](n+) (3) in which one of the aromatic rings of the ligand is decoordinated. The UV/Vis spectrum of 2 displays a large absorption band at 507 nm, which is attributed to a phenolate-->Mn(III) charge-transfer transition. The cyclovoltammogram of 2 exhibits two reversible oxidation waves, at 0.65 and 1.16 V versus the SCE, corresponding to the Mn(III)Mn(III)/Mn(III)Mn(IV) and Mn(III)Mn(IV)/Mn(IV)Mn(IV) oxidation processes, respectively. The one-electron electrochemical oxidation of 2 leads to the mono-mu-oxo mixed-valent species [(mL)Mn(III)-(mu-O)-Mn(IV)(mL)](3+) (2 ox). The UV/Vis spectrum of 2 ox exhibits one large band at 643 nm, which is attributed to the phenolate-->Mn(IV) charge-transfer transition. 2 ox can also be obtained by the direct electrochemical oxidation of 1 in the presence of an external base. The 2 ox and 3 species exhibit a 16-line EPR signal with first peak to last trough widths of 125 and 111 mT, respectively. Both

  12. Full vector archaeomagnetic records from Anatolia between 2400 and 1350 BCE: Implications for geomagnetic field models and the dating of fires in antiquity

    Science.gov (United States)

    Ertepinar, P.; Langereis, C. G.; Biggin, A. J.; de Groot, L. V.; Kulakoğlu, F.; Omura, S.; Süel, A.

    2016-01-01

    Anatolia, as one of the busiest crossroads of ancient civilizations, provides an ideal platform for archaeomagnetic studies. Previous results from the Middle East have suggested the occurrence of a strong peak in geomagnetic intensity at ∼1000 BCE associated with dramatic field strength variations that could require a radical rethinking of geodynamo theory. The behavior of the field in the centuries preceding this peak remains poorly constrained, however. Here we present the results of full-vector archaeomagnetic experiments performed on 18 sets of samples from three archaeological sites belonging to Assyrian Trade Colony and Hittite periods. Associated rock magnetic analyses showed that the major magnetic carrier is magnetite chemically stable up to 700 °C and the magnetic mineral assemblage is composed mostly of non-interacting PSD grains. The directional results are compared with existing data and with the most recent global geomagnetic field models pfm9k.1b and SHA.DIF.14k. The directions are in remarkably good agreement with SHA.DIF.14k which is based on archaeomagnetic and lava flow data. Together with our earlier results from Anatolia, we triple the existing database of directions for the 700 year long period 2200-1500 BCE, over a large region from Greece to Azerbaijan, and from Moldavia/Ukraine to Egypt. Three archaeointensity methods: thermal IZZI-Thellier, microwave Thellier and the multi-specimen protocol (MSP) produced virtual axial dipole moment estimates (9.0- 10.9 ×1022 Am2) that are somewhat higher than contemporaneous (regional and global) data and model predictions suggesting that the field was already substantially stronger than today more than 800 years prior to the reported peak. In addition to constraining geomagnetic variability, our data also allow us to assign relative dates to inferred fire events in the Assyrian Trade Colony Period sites. This allows us to conclude that the fire events at the largest site, Kültepe, were not all

  13. Origin, evolution and geothermometry of the thermal waters in the Gölemezli Geothermal Field, Denizli Basin (SW Anatolia, Turkey)

    Science.gov (United States)

    Alçiçek, Hülya; Bülbül, Ali; Brogi, Andrea; Liotta, Domenico; Ruggieri, Giovanni; Capezzuoli, Enrico; Meccheri, Marco; Yavuzer, İbrahim; Alçiçek, Mehmet Cihat

    2018-01-01

    The Gölemezli Geothermal Field (GGF) is one of the best known geothermal fields in western Anatolia (Turkey). The exploited fluids are of meteoric origin, mixed with deep magmatic fluids, which interacted with the metamorphic rocks of the Menderes Massif. The geothermal fluids are channeled along Quaternary faults belonging to the main normal faults system delimiting the northern side of the Denizli Basin and their associated transfer zones. In this study, hydrochemical and isotopic analyses of the thermal and cold waters allow us to determine water-rock interactions, fluid paths and mixing processes. Two groups of thermal waters have been distinguished: (i) Group 1A, comprising Na-SO4 type and Ca-SO4 type and (ii) Group 1B, only consisting Ca-HCO3 type waters. Differently, two groups were recognized in the cold waters: (i) Group 2A, corresponding to Ca-HCO3 type and (ii) Group 2B, including Mg-HCO3 type. Their geochemical characteristics indicate interactions with the Paleozoic metamorphic rocks of the Menderes Massif and with the Neogene lacustrine sedimentary rocks. Dissolution of host rock and ion-exchange reactions modify thermal water composition in the reservoir of the GGF. High correlation in some ionic ratios and high concentrations of some minor elements suggest an enhanced water-rock interaction. None of the thermal waters has been reached a complete chemical re-equilibrium, possibly as a result of mixing with cold water during their pathways. Geothermal reservoir temperatures are calculated in the range of 130-210°C for the Gölemezli field. Very negative δ18O and δ2H isotopic ratios are respectively between -8.37 and -8.13‰ and -61.09 and -59.34‰ for the SO4-rich thermal waters, and ca. - 8.40 and -8.32‰ and - 57.80 and -57.41‰ for the HCO3-rich thermal waters. Low tritium (rock volumes. Volatile ascent from deep magmatic sources through crustal structures can explain the occurrence of mantle volatiles at shallow depth in the Denizli Basin

  14. IAEA Perspectives on Radiological Characterisation

    International Nuclear Information System (INIS)

    O'Sullivan, Patrick; Ljubenov, Vladan

    2012-01-01

    Requirements for characterization of radiological and other hazards in nuclear facilities are reflected in the IAEA Safety Standards. WS-R-5, Safety Requirements for Decommissioning of Facilities using Radioactive Material, includes a requirement that 'During the preparation of the final decommissioning plan, the extent and type of radioactive material (irradiated and contaminated structures and components) at the facility shall be determined by means of a detailed characterization survey and on the basis of records collected during the operational period'. The subsidiary Safety Guide WS-G-2.1, Decommissioning of Nuclear Power Plants and Research Reactors, further elaborates that 'A survey of radiological and non-radiological hazards provides an important input for the safety assessment and for implementing a safe approach during the work'. Although the characterisation requirements addressed in the Safety Standards relate primarily to the detailed survey activities undertaken following the shutdown of the facility, it is evident that radiological characterization is of relevance to all major phases of the lifetime of a nuclear facility, including: - the siting phase - baseline surveys are undertaken to determine background radiation levels; - the construction phase - construction materials are retained to support future calculations of radioactivity distributions; - the operational phase - surveys are done regularly, with additional surveys being required following incidents involving plant contamination; - the transition phase - detailed radiological surveys are required to support the development of the final decommissioning plan; and - the closure phase - a final survey of the site and any remaining structures will be needed to support an application for release of the site from regulatory control. In the case of facilities that are already shut down, the main purpose of radiological characterisation is to provide a reliable database of information on the

  15. Tectono-stratigraphy of the Orhaniye Basin, Turkey: Implications for collision chronology and Paleogene biogeography of central Anatolia

    Science.gov (United States)

    Licht, A.; Coster, P.; Ocakoğlu, F.; Campbell, C.; Métais, G.; Mulch, A.; Taylor, M.; Kappelman, John; Beard, K. Christopher

    2017-08-01

    Located along the İzmir-Ankara-Erzincan Suture (IAES), the Maastrichtian - Paleogene Orhaniye Basin has yielded a highly enigmatic -yet poorly dated- Paleogene mammal fauna, the endemic character of which has suggested high faunal provincialism associated with paleogeographic isolation of the Anatolian landmass during the early Cenozoic. Despite its biogeographic significance, the tectono-stratigraphic history of the Orhaniye Basin has been poorly documented. Here, we combine sedimentary, magnetostratigraphic, and geochronological data to infer the chronology and depositional history of the Orhaniye Basin. We then assess how our new data and interpretations for the Orhaniye Basin impact (1) the timing and mechanisms of seaway closure along the IAES and (2) the biogeographic evolution of Anatolia. Our results show that the Orhaniye Basin initially developed as a forearc basin during the Maastrichtian, before shifting to a retroarc foreland basin setting sometime between the early Paleocene and 44 Ma. This chronology supports a two-step scenario for the assemblage of the central Anatolian landmass, with incipient collision during the Paleocene - Early Eocene and final seaway retreat along the IAES during the earliest Late Eocene after the last marine incursion into the foreland basin. Our dating for the Orhaniye mammal fauna (44-43 Ma) indicates the persistence of faunal endemism in northern Anatolia until at least the late Lutetian despite the advanced stage of IAES closure. The tectonic evolution of dispersal corridors linking northern Anatolia with adjacent parts of Eurasia was not directly associated with IAES closure and consecutive uplifts, but rather with the build-up of continental bridges on the margins of Anatolia, in the Alpine and Tibetan-Himalayan orogens.

  16. The Upper Cretaceous to Palaeogene Sedimentary History and Tectonic Evolution of the Bala Basin, Central Anatolia, Turkey

    OpenAIRE

    Emre, Mehmet Fahrettin

    1985-01-01

    The study area is situated on the northern extension of the Tuzgolu basin, (Central Anatolia) and contains Upper Cretaceous--Tertiary volcanic, clastic, and carbonate rocks with evaporites deposited on an ophiolitic melange basement, the Ankara Melange. The present structure of the area is the result of tectonism during late Alpine movements. The movements controlled the timing and conditions of sediment accumulation. The Bala basin evolved on the northern continental margin of the Kirsehi...

  17. Measures Taken by the Ottoman State against Shah İsmail's Attempts to Convert Anatolia to Shia

    Directory of Open Access Journals (Sweden)

    Yusuf Küçükdağ

    2008-06-01

    Full Text Available Shah Ismail, when he was sheikh of Safevi sect established by Sheikh Safiyuddin, Ismail’s grandfather, established Safevi State in Azerbaijan taking Tebriz as the center at the beginning of XVI th.century. The followers of Safevi Sect were Turcomen originated from Anatolia. They helped Shah Ismail to establish state. Shah Ismail depending on Turcomen followers attempted to annex Anotolia which was under Otoman domination in his new state’s territory. He sent his caliphs to Anatolia to propagandize his sect. They tried to convince Anatolion people about Safevi sect. Ottoman state which understand that the main purpose of Shah Ismail was not the speading of Safevi sect took military, political, economical and cultural measures. In the war between two states, Shah Ismail was defeated by Ottoman army in Caldıran (1514 The relationship of Safevi’s followers with Iran was prevented. In order to prevent economical growth of Safevi State, economical embargo was put. By helping the organization of Halvetiyye which has Safevi sect orijin but accept’ s ottoman state outhority the spread of Safevism was prevented. Turcomen in Anatolia become hopeless when Sheikh Ismail was defeated by I. Selim. Ottoman State does not extinct Safevism

  18. The Status of Woman in Family and Society in 19th Century Anatolia (A Case Study in Ayntab

    Directory of Open Access Journals (Sweden)

    Bülent Çukurova

    2007-12-01

    Full Text Available Since the ancient times, in states that have been established in Anatolia (Asia Minor women have had a special place in the family and in the society. Until the acceptance of Islamic traditions by the Anatolian people, women were considered to be equal to men in terms of legal and social standing. Even in the administration of governmental affairs women used to have a say equal to that of men or the khan. Islamic traditions have been shaped by Arab and Iranians more than any other people or culture. Both cultures have had a strong influence on Anatolian people after the acceptance of Islamic traditions. To understand how such influences of Arabic and Iranian cultures are reflected on Anatolia today, one needs to examine the role of women in the family and in the society. In general, when we observe Anatolia in terms of women’s right to inherited property and marital decisions and affairs as well as other socioeconomic rights we see different traditions and rules applied depending on location of living whether women living in rural or urban areas of the country. We also observe differences in terms of society’s treatment of women based on the ethnicity or religious affinity

  19. Seismotectonics of the southern boundary of Anatolia, eastern Mediterranean region: Subduction, collision, and arc jumping

    Science.gov (United States)

    Rotstein, Yair; Kafka, Alan L.

    1982-09-01

    The pattern of seismicity and fault plane solutions of earthquakes are used to outline the tectonic features of the southern boundary of Anatolia in the eastern Mediterranean and southeastern Turkey. The results of this study show that this boundary is composed of two distinct parts. One, in southeastern Turkey and Syria, is a wide and complex zone of continental collision. The other, in the Levantine basin of the eastern Mediterranean, is a zone of oceanic subduction. In the region of continental collision three zones of seismicity are observed. Most of the seismic activity in this region follows the Bitlis zone and is associated with a zone of thrusting and mountain building. This appears to be the zone of most active deformation and plate consumption in the plate boundary region between Arabia and Turkey. A less active zone of seismicity to the north of the Bitlis zone is interpreted to have been more active in the past whereas another active zone of seismicity to the south is interpreted to be a zone which may be more active in the future as the main zone of plate consumption jumps to the south. In the subduction zone of the eastern Mediterranean the depth of the subducted slab and the rate of seismicity generally increase from east to west. The zone of present-day convergence between Africa and Turkey in the Levantine basin can be best outlined by the northern edge of the Mediterranean ridge. The subduction zone in this area sequentially jumps to the south as small continental fragments collide with existing zones of subduction. Deep seismic activity near the Gulf of Antalya is associated with a detached subducted slab north of the Anaximander Mountains that is distinctly different from the seismic trend which is associated with present-day active subduction. The plate boundary between Africa and Turkey at the center of the Levantine basin appears to have shifted to the south of the Anaximander Mountains and Florence rise. Most of the focal mechanisms of the

  20. 500,000 Years of Environmental History in Eastern Anatolia: The PALEOVAN Drilling Project

    Directory of Open Access Journals (Sweden)

    Clemens Glombitza, and Jens Kallmeyer

    2012-09-01

    Full Text Available International Continental Scientific Drilling Program (ICDP drilled a complete succession of the lacustrine sediment sequence deposited during the last ~500,000 years in Lake Van, Eastern Anatolia (Turkey. Based on a detailed seismic site survey, two sites at a water depth of up to 360 m were drilled in summer 2010, and cores were retrieved from sub-lake-floor depths of 140 m (Northern Basin and 220 m (Ahlat Ridge. To obtain a complete sedimentary section, the two sites were multiple-cored in order to investigate the paleoclimate history of a sensitive semi-arid region between theBlack, Caspian, and Mediterranean seas. Further scientific goals of the PALEOVAN project are the reconstruction of earthquake activity, as well as the temporal, spatial, and compositional evolution of volcanism as reflected in the deposition of tephra layers. The sediments host organic matter from different sources and hence composition, which will be unravelled using biomarkers. Pathways for migration of continental and mantle-derived noble gases will be analyzed in pore waters. Preliminary 40Ar/39Ar single crystal dating of tephra layers and pollen analyses suggest that the AhlatRidge record encompasses more than half a million years of paleoclimate and volcanic/geodynamic history, providing the longest continental record in the entire Near East to date.

  1. Lithospheric flexural strength and effective elastic thicknesses of the Eastern Anatolia (Turkey) and surrounding region

    Science.gov (United States)

    Oruç, Bülent; Gomez-Ortiz, David; Petit, Carole

    2017-12-01

    The Lithospheric structure of Eastern Anatolia and the surrounding region, including the northern part of the Arabian platform is investigated via the analysis and modeling of Bouguer anomalies from the Earth Gravitational Model EGM08. The effective elastic thickness of the lithosphere (EET) that corresponds to the mechanical cores of the crust and lithospheric mantle is determined from the spectral coherence between Bouguer anomalies and surface elevation data. Its average value is 18.7 km. From the logarithmic amplitude spectra of Bouguer anomalies, average depths of the lithosphere-asthenosphere boundary (LAB), Moho, Conrad and basement in the study area are constrained at 84 km, 39 km, 16 km and 7 km, respectively. The geometries of the LAB and Moho are then estimated using the Parker-Oldenburg inversion algorithm. We also present a lithospheric strength map obtained from the spatial variations of EET determined by Yield Stress Envelopes (YSE). The EET varies in the range of 12-23 km, which is in good agreement with the average value obtained from spectral analysis. Low EET values are interpreted as resulting from thermal and flexural lithospheric weakening. According to the lithospheric strength of the Eastern Anatolian region, the rheology model consists of a strong but brittle upper crust, a weak and ductile lower crust, and a weak lower part of the lithosphere. On the other hand, lithosphere strength corresponds to weak and ductile lower crust, a strong upper crust and a strong uppermost lithospheric mantle for the northern part of the Arabian platform.

  2. 500,000 Years of Environmental History in Eastern Anatolia: The PALEOVAN Drilling Project

    Science.gov (United States)

    Litt, T.; Anselmetti, F. S.; Baumgarten, H.; Beer, J.; Cagatay, N.; Cukur, D.; Damci, E.; Glombitza, C.; Haug, G.; Heumann, G.; Kallmeyer, H.; Kipfer, R.; Krastel, S.; Kwiecien, O.; Meydan, A. F.; Orcen, S.; Pickarski, N.; Randlett, M.-E.; Schmincke, H.-U.; Schubert, C. J.; Sturm, M.; Sumita, M.; Stockhecke, M.; Tomonaga, Y.; Vigliotti, L.; Wonik, T.; Paleovan Scientific Team

    2012-09-01

    International Continental Scientific Drilling Program (ICDP) drilled a complete succession of the lacustrine sediment sequence deposited during the last ~500,000 years in Lake Van, Eastern Anatolia (Turkey). Based on a detailed seismic site survey, two sites at a water depth of up to 360 m were drilled in summer 2010, and cores were retrieved from sub-lake-floor depths of 140 m (Northern Basin) and 220 m (Ahlat Ridge). To obtain a complete sedimentary section, the two sites were multiple-cored in order to investigate the paleoclimate history of a sensitive semi-arid region between the Black, Caspian, and Mediterranean seas. Further scientific goals of the PALEOVAN project are the reconstruction of earthquake activity, as well as the temporal, spatial, and compositional evolution of volcanism as reflected in the deposition of tephra layers. The sediments host organic matter from different sources and hence composition, which will be unravelled using biomarkers. Pathways for migration of continental and mantle-derived noble gases will be analyzed in pore waters. Preliminary 40Ar/39Ar single crystal dating of tephra layers and pollen analyses suggest that the Ahlat Ridge record encompasses more than half a million years of paleoclimate and volcanic/geodynamic history, providing the longest continental record in the entire Near East to date. doi:10.2204/iodp.sd.14.02.2012

  3. Determination of Selenium and Nickel in Asphaltite from Milli (Sirnak) Deposit in SE Anatolia of Turkey

    Science.gov (United States)

    Aydin, Isil; Fidan, Celal; Kavak, Orhan; Erek, Figen; Aydin, Firat

    2017-12-01

    Asphaltite is one of the naturally occurring black, solid bitumen’s, which are soluble at heating in carbon disulphide band fuse. Asphaltite is also a solidified hydro carbon compound derived from petroleum [1]. According to the World Energy Council, Turkish National Committee (1998), the total reserve of the asphaltic substances that are found in south eastern Turkey is about 82 million tons, with Silopi and Sirnak reserves to get her comprising the major part of the Asphaltite deposits. Selenium and Nickel are very important elements both environmental and health. Selenium plays an important role in the formation of the enzyme antioxidant effect in the cell. The need for Selenium increases in situations such as pregnancy, menopause, grow than development, air pollution. Nickel is used for preventing iron-poor blood, increasing iron absorption, and treating weak bones. In this study, asphaltites were taken from Milli vein from Sirnak deposit in SE Anatolia of Turkey. A total of 6.500.000 tons of Asphaltite reserves have been identified as asphaltites in Milli (Sirnak). The sample preparation method was developed in Asphaltite by spectroanalytical techniques, wet acid digestion. MW-AD followed by ICP-OES were used for the determination of Selenium and Nickel in Asphaltite. Proximate analysis of Asphaltite fly ash samples was made. It also, Selenium and Nickel element analysis in Asphaltite were made.

  4. Mineralogy, geochemistry and expansion testing of an alkali-reactive basalt from western Anatolia, Turkey

    International Nuclear Information System (INIS)

    Copuroglu, Oguzhan; Andic-Cakir, Ozge; Broekmans, Maarten A.T.M.; Kuehnel, Radko

    2009-01-01

    In this paper, the alkali-silica reaction performance of a basalt rock from western Anatolia, Turkey is reported. It is observed that the rock causes severe gel formation in the concrete microbar test. It appears that the main source of expansion is the reactive glassy phase of the basalt matrix having approximately 70% of SiO 2 . The study presents the microstructural characteristics of unreacted and reacted basalt aggregate by optical and electron microscopy and discusses the possible reaction mechanism. Microstructural analysis revealed that the dissolution of silica is overwhelming in the matrix of the basalt and it eventually generates four consequences: (1) Formation of alkali-silica reaction gel at the aggregate perimeter, (2) increased porosity and permeability of the basalt matrix, (3) reduction of mechanical properties of the aggregate and (4) additional gel formation within the aggregate. It is concluded that the basalt rock is highly prone to alkali-silica reaction. As an aggregate, this rock is not suitable for concrete production.

  5. Urological recommedations of Hadji Pasha’s, a Turkish aged doctor in Anatolia

    Directory of Open Access Journals (Sweden)

    Mehmet Yıldırım

    2016-08-01

    Full Text Available Objective: Urinary tract conditions have been an important part of diseases from antiquity until today. Historically, many plants and herbs have been used for the treatment of urinary disorders. Methods: Celâlüddîn Hızır bin Ali el-Konevi (Hadji Pasha is one of the most famous physician who lived in Anatolia between 13th and 14th centuries. He has written one of the most important medical books of that era, "Müntehab-ıŞifa" (solution of wellness in Turkish. General medical information about the diseases in this book, focus on diagnosis and treatment. Results: The herbal solutions for urological disorders such as, urinary incontinence, urinary stones or erection problems are told in this section.   Conclusion: Many of the herbal medicines addressed in this book are being widely used in current medicine, but the usage of these herbals in daily urology practice is limited. In this study, we aimed to share the advices for the urological diseases and therelated herbal medicines that are named in Hadji Pasha’s book, " Müntehab-ıŞifa ", with today's physicians.

  6. Distribution of inhalant allergies in pediatric patients presenting with allergic complaints in the Eastern Anatolia Region.

    Science.gov (United States)

    Kilic, Mehmet; Taskin, Erdal

    2016-08-01

    The objective of this study was to define the distribution of inhalant allergens in pediatric patients in whom sensitization was diagnosed with a skin prick test (SPT) who had presented with allergic complaints. In addition, the correlation between the inhalant allergens detected on the SPT and the patients' demographic features, diagnosis, and laboratory findings was defined. A total of 1415 children among the 4056 patients who presented at a clinic in the Eastern Anatolia region with allergic complaints and who had undergone an SPT were included in this study. On the SPT, sensitization to grass pollens was found in 60.1%, cereals pollens in 57.2%, and Dermatophagoides farinae in 21.8% of the patients. Furthermore, on the SPT, incidence of asthma development was 3.96 times higher (odds ratio 3.96, 95% CI: 1.77-6.83; P=0.001) in patients who were allergic to Dermatophagoides farinae. In our study, differences were found in the study region compared to data from around the world and other regions in Turkey in terms of the distribution of allergies and variations in allergens in patients diagnosed due to variations in climate and plants.

  7. Anatomical, morphological and palynological studies of some onosma l. (boraginaceae) taxa endemic to anatolia

    International Nuclear Information System (INIS)

    Teke, H.I.; Binzet, R.

    2017-01-01

    In this study, the morphological, anatomical and palynological characters of Onosma discedens Hausskn. ex. Bornm., O. nana DC. and O. sorgerae var. subglabriflora Teppner were investigated. All the examined species are endemic to Anatolia, Turkey. The root cortex of examined species is multilayered. The raphide crystals are observed in epidermal cells and basal hair cells on both side of epidermis in O. sorgerae var. subglabriflora. Leaves are isobilateral (=equifacial) in O. nana and O. sorgerae var. subglabriflora, whereas leaves are dorsiventral(=bifacial) in O. discedens. Stomatas are observed on both surfaces (=amfistomatic) in all examined species. Stomata index is 9.25 of upper epidermis and 10.71 of lower epidermis in O. discedens, 9.61 of upper epidermis and 10 of lower epidermis in O. nana and 9.67 of upper epidermis and 13.63 of lower epidermis in O. sorgerae var. subglabriflora. The pollen grains are heteropolar, trisyncolporatae and sphaeroidal shape. In O. discedens, sphaeroidal (P/E: 1.13 W) and subprolate in Acetolysis and in O. nana, subprolate in shape and in O. sorgerae var. subglabriflora. Amb is three angular in all examined Onosma species. Sculpture is scabrate-rugulate in all species. Nutlet ornamentation is rugose. (author)

  8. Spatial Prediction of Air Temperature in East Central Anatolia of Turkey

    Science.gov (United States)

    Bilgili, B. C.; Erşahin, S.; Özyavuz, M.

    2017-11-01

    Air temperature is an essential component of the factors used in landscape planning. At similar topographic conditions, vegetation may show considerable differences depending on air temperature and precipitation. In large areas, measuring temperature is a cost and time-consuming work. Therefore, prediction of climate variables at unmeasured sites at an acceptable accuracy is very important in regional resource planning. In addition, use a more proper prediction method is crucial since many different prediction techniques yield different performance in different landscape and geographical conditions. We compared inverse distance weighted (IDW), ordinary kriging (OK), and ordinary cokriging (OCK) to predict air temperature at unmeasured sites in Malatya region (East Central Anatolia) of Turkey. Malatya region is the most important apricot production area of Turkey and air temperature is the most important factor determining the apricot growing zones in this region. We used mean monthly temperatures from 1975 to 2010 measured at 28 sites in the study area and predicted temperature with IDW, OC, and OCK techniques, mapped temperature in the region, and tested the reliability of these maps. The OCK with elevation as an auxiliary variable occurred the best procedure to predict temperature against the criteria of model efficiency and relative root mean squared error.

  9. SPATIAL PREDICTION OF AIR TEMPERATURE IN EAST CENTRAL ANATOLIA OF TURKEY

    Directory of Open Access Journals (Sweden)

    B. C. Bilgili

    2017-11-01

    Full Text Available Air temperature is an essential component of the factors used in landscape planning. At similar topographic conditions, vegetation may show considerable differences depending on air temperature and precipitation. In large areas, measuring temperature is a cost and time-consuming work. Therefore, prediction of climate variables at unmeasured sites at an acceptable accuracy is very important in regional resource planning. In addition, use a more proper prediction method is crucial since many different prediction techniques yield different performance in different landscape and geographical conditions. We compared inverse distance weighted (IDW, ordinary kriging (OK, and ordinary cokriging (OCK to predict air temperature at unmeasured sites in Malatya region (East Central Anatolia of Turkey. Malatya region is the most important apricot production area of Turkey and air temperature is the most important factor determining the apricot growing zones in this region. We used mean monthly temperatures from 1975 to 2010 measured at 28 sites in the study area and predicted temperature with IDW, OC, and OCK techniques, mapped temperature in the region, and tested the reliability of these maps. The OCK with elevation as an auxiliary variable occurred the best procedure to predict temperature against the criteria of model efficiency and relative root mean squared error.

  10. Anisotropy of Magnetic Susceptibility Studies in Lava Flows of the Eastern Anatolia Region, Turkey

    Science.gov (United States)

    Ucar, Hakan; Cengiz Cinku, Mualla

    2017-04-01

    Eastern Anatolia comprises one of the high plateaus of the Alpine-Himalaya mountain belt with an average elevation of 2 km above the sea level. Available geochronologic data indicate that the volcanism started in the south of the region around the north of Lake Van and continued towards the norths in a age interval of 15.0 Ma to 0.4 Ma. The products are exposed as stratovolcanoes like Agri, Tendurek, Suphan and Girekol with the eruption of andesitic to rhyolitic lavas, ignimbrites and basaltic lava flows. In this study, anisotropy of magnetic susceptibility measurements were carried out on different lava flows (Tendurek, Girekol and Suphan) to determine the flow direction of lavas. It has been shown that the direction of maximum susceptibility is associated with magma flow direction in the vertical direction, while a horizontal flow direction is predicted for the volcano structure of Suphan. Anisotropy of magnetic measurements show a trend of lineation towards the center of the projection and shallow-dipping foliations which are largely scattered.

  11. The prevalence of Behçet's disease in a city in Central Anatolia in Turkey.

    Science.gov (United States)

    Çölgeçen, Emine; Özyurt, Kemal; Ferahbaş, Ayten; Borlu, Murat; Kulluk, Pınar; Öztürk, Ahmet; Öner, Ayşe Öztürk; Gün, İskender; Aşçıoğlu, Özcan

    2015-03-01

    The prevalence of Behçet's disease (BD) is much higher in countries along the ancient Silk Route, extending from Japan to Mediterranean countries including Turkey, than in northern Europe and the USA. The present study aimed to investigate the prevalence of BD in Kayseri, a city in Central Anatolia in Turkey. This study investigated cross-sectional prevalences of BD in individuals aged >10 years in Kayseri, Turkey, in two stages. The first stage aimed to identify individuals with recurrent oral ulcers (ROUs) through home visits, and the second stage aimed to further examine those with ROUs for the presence of other BD-related manifestations under hospital conditions. The study was conducted using the criteria defined by the International Study Group for Behçet's Disease. The sample size was determined to be 4697 with an expected sampling error of 5.5 per 10,000, with a 95% confidence interval. A standard questionnaire was administered to a total of 5218 individuals. A history of ROU was recorded in 470 (9.0%) of the 5218 residents, and a previous diagnosis of BD was recorded in nine individuals. The prevalence rate of BD was estimated as 17 cases per 10,000 population in Kayseri, Turkey. The present study contributes towards estimations of prevalences of BD in Turkey and towards raising public awareness about the disease. It also supports previous studies that have reported the world's highest prevalences of BD in Turkey. © 2014 The International Society of Dermatology.

  12. Early Miocene depositional environments in the northern margin of the Mediterranean, southwestern Anatolia

    Energy Technology Data Exchange (ETDEWEB)

    Yavuz, H.H.; Oercen, S.

    1988-08-01

    The continental and shallow marine clastics and carbonates exposed around the towns of Kale and Acipayam in southwestern Anatolia were investigated to interpret the depositional environments in the northern margin of the Mediterranean in terms of lithofacies and biozones. These deposits include Miogypsina intermedia and M. irregularis, indicating Burdigalian age when correlated with the same species in the different parts of the Tethys Sea and Indian-Pacific Oceans. The clastic lower part of the succession is characterized by sheet flow and braided-stream deposits of an alluvial-fan/fan-delta complex. Marine carbonates overlie these deposits, but in some places a transgressive lag deposit lies between the unconformity surface and the carbonates. The lag deposit unit corresponds to the Gastropoda biozone, including Ostrea, Terebralia, and Pecten. Four carbonate facies are recognized: (1) Clayey limestones with ahermatypic corals, ostracods, macrofossils, and foraminifers. This facies corresponds to the Textularia-Rotalia biozone. (2) Packstones and grainstones with abundant nearshore and some offshore foraminifers, corresponding to the Miliolidae biozone. (3) Packstones and wackestones with offshore foraminifers. This facies includes the Miogypsina irregularis-Miogypsina intermedia biozone. (4) Boundstones and very poorly sorted reef-talus conglomerates including hermatypic corals, foraminifers, and binding foraminifers. This facies is the coral biozone. These sediments define the northern extent of the Tethys Sea in the investigated area during the Burdigalian. They were deposited in a shallow carbonate platform at the southern margin of the Anatolian mainland, which had a steep coast characterized by an alluvial-fan/fan-delta complex.

  13. Characterising Super-Earths

    Directory of Open Access Journals (Sweden)

    Valencia D.

    2011-02-01

    Full Text Available The era of Super-Earths has formally begun with the detection of transiting low-mass exoplanets CoRoT-7b and GJ 1214b. In the path of characterising super-Earths, the first step is to infer their composition. While the discovery data for CoRoT-7b, in combination with the high atmospheric mass loss rate inferred from the high insolation, suggested that it was a rocky planet, the new proposed mass values have widened the possibilities. The combined mass range 1−10 M⊕ allows for a volatile-rich (and requires it if the mass is less than 4 M⊕ , an Earth-like or a super-Mercury-like composition. In contrast, the radius of GJ 1214b is too large to admit a solid composition, thus it necessarily to have a substantial gas layer. Some evidence suggests that within this gas layer H/He is a small but non-negligible component. These two planets are the first of many transiting low-mass exoplanets expected to be detected and they exemplify the limitations faced when inferring composition, which come from the degenerate character of the problem and the large error bars in the data.

  14. Calcite veining and feeding conduits in a hydrothermal system: Insights from a natural section across the Pleistocene Gölemezli travertine depositional system (western Anatolia, Turkey)

    Science.gov (United States)

    Capezzuoli, Enrico; Ruggieri, Giovanni; Rimondi, Valentina; Brogi, Andrea; Liotta, Domenico; Alçiçek, Mehmet Cihat; Alçiçek, Hülya; Bülbül, Ali; Gandin, Anna; Meccheri, Marco; Shen, Chuan-Chou; Baykara, Mehmet Oruç

    2018-02-01

    Linking the architecture of structural conduits with the hydrothermal fluids migrating from the reservoir up to the surface is a key-factor in geothermal research. A contribution to this achievement derives from the study of spring-related travertine deposits, but although travertine depositional systems occur widely, their feeding conduits are only rarely exposed. The integrated study carried out in the geothermal Gölemezli area, nearby the well-known Pamukkale area (Denizli Basin, western Anatolia, Turkey), focused on onyx-like calcite veins (banded travertine) and bedded travertine well exposed in a natural cross-section allowing the reconstruction of the shallower part of a geothermal system. The onyx-like veins represent the thickest vein network (> 150 m) so far known. New field mapping and structural/kinematic analyses allowed to document a partially dismantled travertine complex (bedded travertine) formed by proximal fissure ridges and distal terraced/pools depositional systems. The banded calcite veins, WNW-trending and up to 12 m thick, developed within a > 200 m thick damaged rock volume produced by parallel fault zones. Th/U dating indicates a long lasting (middle-late Pleistocene) fluids circulation in a palaeo-geothermal system that, due to its location and chemical characteristics, can be considered the analogue of the nearby, still active, Pamukkale system. The isotopic characteristics of the calcite veins together with data from fluid inclusions analyses, allow the reconstruction of some properties (i.e. temperature, salinity and isotopic composition) and processes (i.e. temperature variation and intensity of degassing) that characterized the parent fluids and the relation between degassing intensity and specific microfabric of calcite crystals (elongated/microsparite-micrite bands), controlled by changes/fluctuations of the physico-chemical fluid characteristics.

  15. Paper 1: Wastewater characterisation

    African Journals Online (AJOL)

    drinie

    unbiodegradable soluble chemical oxygen demand. VFA. = volatile fatty acid. VFA-COD. = equivalent COD for VFA. WCW. = water care works. Introduction. The presence of appropriate proportions of the macro-nutrients C,. N and P in municipal wastewater is important for the efficient performance of a BNRAS process ...

  16. Characterisation of areal surface texture

    CERN Document Server

    Leach, Richard

    2014-01-01

    This book presents the areal framework that is being adopted by the international community, concentrating on characterisation methods, and presenting case studies highlighting use of areal methods in applications from automobile manufacturing to archaeology.

  17. In-line rheological characterisation of wastewater sludges using non ...

    African Journals Online (AJOL)

    In-line process control based on accurate rheological characterisation for treated wastewater sludge could lead to significant savings in chemicals and will optimise dewatering processes producing drier sludges. In this work, a wastewater sludge at three concentrations was tested in order to investigate the capabilities of the ...

  18. Towards a complete characterisation of guaiacwood oil.

    Science.gov (United States)

    Tissandié, Loïc; Viciana, Stéphane; Brevard, Hugues; Meierhenrich, Uwe J; Filippi, Jean-Jacques

    2018-05-01

    Guaiacwood oil is a common perfume ingredient used in modern compositions for its suave woody-rosy scent. This essential oil is a byproduct of the timber industry obtained by hydrodistillation of the heartwood of Bulnesia sarmientoi, a tree native from Latin America. Despite being widely used in perfumery, guaiacwood oil has been poorly described in the past. This study aims at giving an in-depth characterisation of its chemical composition as well as disclosing the odorant compounds responsible for its characteristic fragrance. Our methodology was based on a combination of fractionation and analytical techniques, including comprehensive two-dimensional gas chromatography coupled to mass spectrometry and preparative capillary-gas chromatography. The entire analytical work led to the isolation of 20 constituents among which 14 have never been reported so far in natural extracts. Each isolated compound was fully characterised by spectroscopic methods. Finally, the accurate knowledge of the chemical composition permitted the identification of the odour-active constituents by gas chromatography-olfactometry. Copyright © 2018 Elsevier Ltd. All rights reserved.

  19. Mantle to Surface Dynamics Across Subduction-Collision Transitions in Space and Time: Results from the CD-CAT Project in Anatolia

    Science.gov (United States)

    Whitney, D. L.; Abgarmi, B.; Beck, S. L.; Brocard, G. Y.; Cosca, M. A.; Darin, M. H.; Delph, J. R.; Hui, H.; Kahraman, M.; Kaymakci, N.; Kuscu, G.; Meijers, M. J.; Mulch, A.; Özacar, A.; Portner, D. E.; Reid, M. R.; Rey, P. F.; Rojay, B.; Schlieffarth, W. K.; Sandvol, E. A.; Schoenbohm, L. M.; Tank, B.; Teoman, U.; Teyssier, C. P.; Thomson, S. N.; Turkelli, N.; Umhoefer, P. J.; Uslular, G.; Willenbring, J. K.

    2017-12-01

    From west to east, the southern plate boundary of Anatolia varies from subduction to continental collision; plate dynamics are influenced by the interaction of back-arc extension in the west (Aegean) and convergence in the east (Arabia-Eurasia). Prior to 40 Ma, the entire margin was a subduction zone. The NSF project "Continental Dynamics-Central Anatolian Tectonics (CD-CAT)" has contributed to understanding how the mantle, crust, and surface evolve in subduction-to-collision transitions in time and space. Differences are seen in changes in deformation style as collision proceeded; e.g. from distributed across a broad zone to highly localized on a series of oblique-slip faults, and from transpression to transtension (W of the Central Anatolian fault zone, CAFZ) or strike-slip (E of the CAFZ); age, composition, and sources of magmatism, including a magmatic lull from 40-20 Ma, followed by expansion of magmatism SE-ward in central Anatolia; properties and architecture of the lithosphere and sub-lithospheric mantle (e.g. significant and locally abrupt crustal thickness variations, including thick crust under the Tauride Mts; thin to absent lithospheric mantle; and a torn and disaggregating slab that varies from shallow to steep below central Anatolia); and a topographic gradient from a high eastern plateau (> 2 km) to a central plateau (1-1.5 km) bounded to the N and S by mountain ranges that rose > 2 km from the sea between 11-5 Ma, producing a rain shadow in the Anatolian interior. Thermochronologic and structural studies of exhumed mid-crust and associated basins and fault zones as well as geophysical data for Anatolia today show the extent to which inherited features (suture zones, faults) have affected the tectonic evolution of Anatolia, particularly in the vicinity of the CAFZ/East Anatolian Fault, and mantle properties. Results also show that the Miocene was a dynamic time in the thermal and mechanical evolution of the region, as early Miocene rollback

  20. Using a source-receptor approach to characterise VOC behaviour in a French urban area influenced by industrial emissions. Part II: source contribution assessment using the Chemical Mass Balance (CMB) model.

    Science.gov (United States)

    Badol, Caroline; Locoge, Nadine; Galloo, Jean-Claude

    2008-01-25

    In Part I of this study (Badol C, Locoge N, Leonardis T, Gallo JC. Using a source-receptor approach to characterise VOC behaviour in a French urban area influenced by industrial emissions, Part I: Study area description, data set acquisition and qualitative data analysis of the data set. Sci Total Environ 2007; submitted as companion manuscript.) the study area, acquisition of the one-year data set and qualitative analysis of the data set have been described. In Part II a source profile has been established for each activity present in the study area: 6 profiles (urban heating, solvent use, natural gas leakage, biogenic emissions, gasoline evaporation and vehicle exhaust) have been extracted from literature to characterise urban sources, 7 industrial profiles have been established via canister sampling around industrial plants (hydrocarbon cracking, oil refinery, hydrocarbon storage, lubricant storage, lubricant refinery, surface treatment and metallurgy). The CMB model is briefly described and its implementation is discussed through the selection of source profiles and fitting species. Main results of CMB modellings for the Dunkerque area are presented. (1) The daily evolution of source contributions for the urban wind sector shows that the vehicle exhaust source contribution varies between 40 and 55% and its relative increase at traffic rush hours is hardly perceptible. (2) The relative contribution of vehicle exhaust varies from 55% in winter down to 30% in summer. This decrease is due to the increase of the relative contribution of hydrocarbon storage source reaching up to 20% in summer. (3) The evolution of source contributions with wind directions has confirmed that in urban wind sectors the contribution of vehicle exhaust dominate with around 45-55%. For the other wind sectors that include some industrial plants, the contribution of industrial sources is around 60% and could reach 80% for the sector 280-310 degrees , which corresponds to the most dense

  1. Effect of the Syrian Civil War on Prevalence of Cutaneous Leishmaniasis in Southeastern Anatolia, Turkey.

    Science.gov (United States)

    Inci, Rahime; Ozturk, Perihan; Mulayim, Mehmet Kamil; Ozyurt, Kemal; Alatas, Emine Tugba; Inci, Mehmet Fatih

    2015-07-20

    Cutaneous leishmaniasis (CL) is a vector-mediated skin disease, characterized by chronic wounds on the skin and caused by macrophages in protozoan parasites. It is an endemic disease in the southern and southeastern Anatolia region and is still an important public health problem in Turkey. Because of the civil war in Syria, immigrants to this region in the last 3 years have begun to more frequently present with this disease. The aim of this study was to draw attention to the dramatic increase in new cases with CL after the beginning of the civil war in Syria. In this retrospective study, we evaluated demographic, epidemiological, and clinical features of 110 patients diagnosed with cutaneous leishmaniasis who were admitted to the Department of Dermatology at Kahramanmaras Sutcu Imam University Faculty of Medicine between January 2011 and June 2014. A total of 110 patients included in the study; 50 (45%) were males, and 60 (55%) were females. The age range of the study group was 1-78 years, and the infection was more prevalent in the 0-20 year age group. Of these patients, 76 (69%) were Syrian refugees living in tent camps and 34 (31%) were Turkish citizens. The majority of the cases were diagnosed between October and December. Immigrations to endemic regions of Turkey from neighbouring countries where CL incidence is higher may lead to large increases in case numbers. In order to decrease the risk of exposure, housing conditions of the refugees must be improved, routine health controls must be performed, effective measures must be set in place for vector control, and infected individuals must be diagnosed and treated to prevent spread of the infection.

  2. Hyphenated analytical techniques for materials characterisation

    Science.gov (United States)

    Armstrong, Gordon; Kailas, Lekshmi

    2017-09-01

    This topical review will provide a survey of the current state of the art in ‘hyphenated’ techniques for characterisation of bulk materials, surface, and interfaces, whereby two or more analytical methods investigating different properties are applied simultaneously to the same sample to better characterise the sample than can be achieved by conducting separate analyses in series using different instruments. It is intended for final year undergraduates and recent graduates, who may have some background knowledge of standard analytical techniques, but are not familiar with ‘hyphenated’ techniques or hybrid instrumentation. The review will begin by defining ‘complementary’, ‘hybrid’ and ‘hyphenated’ techniques, as there is not a broad consensus among analytical scientists as to what each term means. The motivating factors driving increased development of hyphenated analytical methods will also be discussed. This introduction will conclude with a brief discussion of gas chromatography-mass spectroscopy and energy dispersive x-ray analysis in electron microscopy as two examples, in the context that combining complementary techniques for chemical analysis were among the earliest examples of hyphenated characterisation methods. The emphasis of the main review will be on techniques which are sufficiently well-established that the instrumentation is commercially available, to examine physical properties including physical, mechanical, electrical and thermal, in addition to variations in composition, rather than methods solely to identify and quantify chemical species. Therefore, the proposed topical review will address three broad categories of techniques that the reader may expect to encounter in a well-equipped materials characterisation laboratory: microscopy based techniques, scanning probe-based techniques, and thermal analysis based techniques. Examples drawn from recent literature, and a concluding case study, will be used to explain the

  3. The Use of Herbal Drugs in Organic Animal Production: The Case of Ethnoveterinary Medicine in Central Anatolia Region

    Directory of Open Access Journals (Sweden)

    Çağrı Çağlar Sinmez

    2017-12-01

    Full Text Available Organic animal production is a natural breeding system in which animal health is protected by giving priority to alternative medicines and treatment as needed by applying appropriate management and feeding methods based on the physiological requirements of animals. Increasing numbers of strains resistant to antibiotics and antiparasitic drugs used in animal breeding have brought about the search for alternative herbal remedies that lead to drug residues in animal products and lead to important health problems in people consuming these products. In this study, it was aimed to evaluate the therapeutic and protective effects of herbal drugs used in organic animal production in ethnoveterinary medicine in the Central Anatolia Region. The material of the study collected as written and declared facts as well as visual data were obtained from animal breeders in the Central Anatolia Region. The results indicated that 30 herbal drugs were used for the treatment of internal diseases, surgical diseases, obstetric and gynecological problems and parasitic diseases in cattle, sheep, horse, poultry, bee, and dog species. Based on the evaluation of the facts that the use of all kinds of synthetic drugs, especially antibiotics, is prohibited or restricted in organic livestock, it can be said that natural herbal drugs instead of artificial substances will provide positive contributions in the protection and treatment of herd health.

  4. Native of the marble in ancient city, Nysa on the Meander of Hellenistic and Roman Period, Aydin- Western Anatolia - Turkey

    Energy Technology Data Exchange (ETDEWEB)

    Kadioglu, M [Ankara University Faculty of Letters Archeological Department Ankara (Turkey); Kadioglu, Y K [Ankara University Engineering Faculty Geol. Eng. Department Ankara (Turkey)], E-mail: kadioglu@humanity.ankara.edu.tr, E-mail: kadi@eng.ankara.edu.tr

    2008-07-01

    Nysa, one of the most important cities of Caria in Hellenistic and Roman period, is located on the highway connecting Aydin (ancient name Tralleis) and Denizli, at about three kilometres northwest of Sultanhisar in western Anatolia of Turkey. The archaeological remains of Nysa are located on the slopes on the side of the stream called Tekkecik. The buildings, streets and public squares of the ancient city were supported by vaulted substructures adapted to the topographic conditions. As to the foundation of the city, Strabo relates that three brothers named Athymbros, Athymbrados, and Hydrelos came from Lakedaimon to Caria, and founded there three cities named after themselves. The small rock samples from the building of theatre, stadium, basement of agora and tomb were collected and determined under polarized microscope and confocal Raman spectroscopy to find out the native of these rock sources. The results of these studies reveal that the main rocks of these structures are composed from white colour marble. These marbles have granoblastic texture and are composed of mainly pressure twinned calcite as coarse grain size. The confocal Raman specroscopical studies of reveal that the marble building stone of Nysa city are mainly obtained from Jurassic Cretaceous of Western Anatolia marble.

  5. Phenotypes of individuals affected by airborne chemicals in the general population

    DEFF Research Database (Denmark)

    Berg, Nikolaj Drimer; Linneberg, A.; Dirksen, Asger

    2009-01-01

    OBJECTIVE: To characterise the chemical exposures and symptoms affecting individuals with subsequent adjustments of social life or occupational conditions, and further characterise these severely affected individuals. METHODS: All individuals (n = 1,134) who reported symptoms from airborne chemic...

  6. REACH. Analytical characterisation of petroleum UVCB substances

    Energy Technology Data Exchange (ETDEWEB)

    De Graaff, R.; Forbes, S.; Gennart, J.P.; Gimeno Cortes, M.J.; Hovius, H.; King, D.; Kleise, H.; Martinez Martin, C.; Montanari, L.; Pinzuti, M.; Pollack, H.; Ruggieri, P.; Thomas, M.; Walton, A.; Dmytrasz, B.

    2012-10-15

    The purpose of this report is to summarise the findings of the scientific and technical work undertaken by CONCAWE to assess the feasibility and potential benefit of characterising petroleum UVCB substances (Substances of Unknown or Variable Composition, Complex reaction products or Biological Materials) beyond the recommendations issued by CONCAWE for the substance identification of petroleum substances under REACH. REACH is the European Community Regulation on chemicals and their safe use (EC 1907/2006). It deals with the Registration, Evaluation, Authorisation and Restriction of Chemical substances. The report is based on Member Company experience of the chemical analysis of petroleum UVCB substances, including analysis in support of REACH registrations undertaken in 2010. This report is structured into four main sections, namely: Section 1 which provides an introduction to the subject of petroleum UVCB substance identification including the purpose of the report, regulatory requirements, the nature of petroleum UVCB substances, and CONCAWE's guidance to Member Companies and other potential registrants. Section 2 provides a description of the capabilities of each of the analytical techniques described in the REACH Regulation. This section also includes details on the type of analytical information obtained by each technique and an evaluation of what each technique can provide for the characterisation of petroleum UVCB substances. Section 3 provides a series of case studies for six petroleum substance categories (low boiling point naphthas, kerosene, heavy fuel oils, other lubricant base oils, residual aromatic extracts and bitumens) to illustrate the value of the information derived from each analytical procedure, and provide an explanation for why some techniques are not scientifically necessary. Section 4 provides a summary of the conclusions reached from the technical investigations undertaken by CONCAWE Member Companies, and summarising the

  7. Radiological characterisation - Know your objective

    International Nuclear Information System (INIS)

    Lindow, Veronica; Moeller, Jennifer

    2012-01-01

    When developing a programme for mapping the radiological characteristics of a facility to be decommissioned it is important to take into account the objectives of the programme. Will the results be used to plan for radiological control and selection of appropriate decontamination and dismantling techniques? Will the radiological inventory be used for dimensioning of future waste repositories? These are two examples of the applications for such studies, which could require that a radiological characterisation programme be adapted to provide the data appropriate to the intended use. The level of detail and scope needed for a radiological characterisation will also vary depending on how the data will be used. An application to free-release a facility requires a comprehensive survey and well documented analysis in order to ensure that no radioactive contamination above prescribed levels is present. A bounding calculation to determine the maximum anticipated volumes and activity of radioactive waste requires a different approach. During the past few years, older decommissioning studies for the Swedish nuclear power plants have been updated (or are in the process of being updated). The decommissioning study's main purpose is to estimate the cost for decommissioning. The cost estimation is based on material and activity inventories, which in turn is based on previous and, in some cases, updated radiological characterisations of the facilities. The radiological inventory is an important part of the study as it affects the cost of decommissioning but also the uncertainties and accuracy of the cost estimation. The presentation will discuss the challenges in specifying a radiological characterisation programme with multiple objectives, together with insights on how data delivered can be applied to yield results suitable for the intended purpose, without introducing excessive conservatism. The intent of the presentation is to define issues that can be of use in various aspects

  8. Palaeomagnetic and geochronological evidence for a major middle miocene unconformity in Söke Basin (western Anatolia) and its tectonic implications for the Aegean region

    NARCIS (Netherlands)

    Uzel, Bora; Sümer, Ökmen; Özkaptan, Murat; Özkaymak, Çağlar; Kuiper, Klaudia; Sözbilir, Hasan; Kaymakci, Nuretdin; İnci, Uğur; Langereis, Cornelis G.

    2017-01-01

    Cenozoic convergence between the Eurasian and African plates and concurrent slab roll-back processes have produced a progressive extension in back-arc areas, such as the Aegean region andwestern Anatolia. There is still a long-standing controversy as to whether this was a continuous or stepwise

  9. A long-lived Late Cretaceous-early Eocene extensional province in Anatolia? Structural evidence from the Ivriz Detachment, southern central Turkey

    Science.gov (United States)

    Gürer, Derya; Plunder, Alexis; Kirst, Frederik; Corfu, Fernando; Schmid, Stefan M.; van Hinsbergen, Douwe J. J.

    2018-01-01

    Central Anatolia exposes previously buried and metamorphosed, continent-derived rocks - the Kırşehir and Afyon zones - now covering an area of ∼300 × 400 km. So far, the exhumation history of these rocks has been poorly constrained. We show for the first time that the major, >120 km long, top-NE 'Ivriz' Detachment controlled the exhumation of the HP/LT metamorphic Afyon Zone in southern Central Anatolia. We date its activity at between the latest Cretaceous and early Eocene times. Combined with previously documented isolated extensional detachments found in the Kırşehir Block, our results suggest that a major province governed by extensional exhumation was active throughout Central Anatolia between ∼80 and ∼48 Ma. Although similar in dimension to the Aegean extensional province to the east, the Central Anatolian extensional province is considerably older and was controlled by a different extension direction. From this, we infer that the African slab(s) that subducted below Anatolia must have rolled back relative to the Aegean slab since at least the latest Cretaceous, suggesting that these regions were underlain by a segmented slab. Whether or not these early segments already corresponded to the modern Aegean, Antalya, and Cyprus slab segments remains open for debate, but slab segmentation must have occurred much earlier than previously thought.

  10. characterisation of silica surfaces iii: characterisation of aerosil ...

    African Journals Online (AJOL)

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    ABSTRACT. ABSTRACT. Aerosil samples, heat treated and then silylated with various silanes at various temperatures have been characterised by adsorption of ethanol at 293 K. Adsorption isotherms were plotted and the BET specific surface areas were determined. Contact angles were measured by the captive bubble ...

  11. Isotopic implications for the origin and the geodynamic nature of the Miocene granitic rocks in the northwest Anatolia (Turkey): comparison with the central Aegean magmatism

    Science.gov (United States)

    Hasözbek, Altug; Satir, Muharrem; Erdogan, Burhan; Siebel, Wolfgang; Akay, Erhan; Deniz Dogan, Güllü

    2010-05-01

    Central Aegean magmatic belt including the northwestern Anatolia is interpreted in the literature as formed along magmatic arc which has migrated southwardly to its present position. During and after the closure of the Neo-Tethyan Ocean and progressive collision of the Tauride-Anatolide Platform with the Sakarya Continent, widespread magmatism occurred in NW Anatolia. These magmatic associations form a NW trending belt. In NW Anatolia, mostly Miocene I-type, shallow seated Egrigöz, Koyunoba, Alacam plutons expose along the suture zone called İzmir-Ankara Zone. These granitoid rocks intruded into the basement rocks of the region which are from bottom to top consist of Menderes Massif, Afyon Zone and Bornova Flysch Zone. Due to the complex geodynamic evolution, the exact emplacement mode of the Miocene granitoids is still a subject for debate. New results give rise to re-consider the general mode of the Miocene magmatic activity and address the question if the magmatism was triggered by compression or extensional tectonic processes. The new data are also compared to those of the central Aegean granitoids. Initial isotopic signatures of these shallow seated granitoids of NW Anatolian are 87Sr/86Sr(I) = 0.70800-0.70975, ENd(I) = -4.9 to -7.3, δ18O = 9.4-10.6, 206Pb/204Pb = 18.85-18.918. These characteristics indicate an assimilation-dominated crystallization and most probably origin of a metaluminous older meta-sedimentary protolith which is also common in most of the central Aegean magmatic suites. However, the geodynamic scenario for the mode of emplacement of the Miocene granitoids along the NW Anatolia implies remarkable differences when comparing to the central Aegean granitoid suites. These differences can be summarized as: an extension related granitoid emplacement in the central Aegean occurred between 15 Ma to 10 Ma. However, in NW Anatolia, the granitoids emplaced after Eocene collision and continue till 20-22 Ma. Isotopic patterns with suggested mixing

  12. Geochemistry and petrogenesis of basaltic rocks from the Develidağ volcanic complex, Central Anatolia, Turkey

    Science.gov (United States)

    Kürkcüoglu, Biltan

    2010-01-01

    The Develidağ volcanic zone (DVZ) is a part of the Middle Miocene-Quaternary Cappadocian Volcanic Province (CVP) in central Anatolia. The DVZ is located at the eastern side of the Plio-Quaternary Sultansazlığı pull-apart basin, that opened along the Ecemiş left-lateral strike-slip fault. Towards the south, the volcanic rocks of the DVZ overlie the Paleozoic metamorphic rocks of the Taurus range. Regional stratigraphic studies indicate that volcanic rocks of the DVZ crop out in a ˜N-S trending rectangular-shaped exposure in the middle of which Middle Miocene andesitic rocks are found surrounded by Upper Miocene basaltic rocks. The purpose of this paper is to present basic geochemical data for the DVZ rocks and discuss possible processes of magma generation. The Develidağ basalts are characterized by low LILE (Rb, K, Ba, Th) and high HFSE (Nb,Zr,Hf,Y) contents, whereas the andesites generally have high LILE and HFSE values except for Nb and Zr. Variable abundances of Pb (3.11-12.09 ppm) and U (0.36-2.64 ppm) are associated with high Ba content within the rock suites. Although low Nb/La (0.6-0.7) and relatively high Ba/Nb ratios indicate crustal involvement for the basalts, high Zr/Ba (0.5), Zr/Hf (42-47) and Th/U (3.13-4.69) values imply contributions from an asthenospheric source component. Furthermore, the high Zr/Hf values (>36) are the diagnostic feature of metasomatized mantle (Dupuy et al., 1992; Rudnick et al., 1993). Moreover, multi-element patterns show that Develidağ basalts have similar trace element signatures to those of the US Cascades tholeiites. The ratios of Zr/Hf, Zr/Ba, Nb/Th and Sr/Ce indicate that basaltic rocks are derived from a MORB-like mantle, and calculated melting model reflects generation from a spinel peridotite source (3-4% melting), but the combined effects of melting and assimilation and fractional crystallization (AFC) processes seem to be partially responsible for the relatively evolved rocks. Typical tholeiitic

  13. [A water-borne tularemia outbreak caused by Francisella tularensis subspecies holarctica in Central Anatolia region].

    Science.gov (United States)

    Ulu Kılıç, Ayşegül; Kılıç, Selçuk; Sencan, Irfan; Ciçek Şentürk, Gönül; Gürbüz, Yunus; Tütüncü, Emin Ediz; Celebi, Bekir; Kıcıman, Özlem; Ergönül, Önder

    2011-04-01

    In this study, we investigated a waterborne tularemia outbreak occured in Kadiozu, a village of Cerkes county of Cankiri province (located in North-west part of central Anatolia, Turkey) between 18 November 2009-24 December 2009. Active surveillance was conducted to determine clinical characteristics and risk factors of cases after two patients from the same village had been diagnosed as oropharyngeal tularemia. All villagers were examined, and clinical specimens from cases and water samples which may be the source of outbreak in the field investigations were taken. Cases were in the form of oropharyngeal, glandular and pneumonic. Polymerase chain reaction (PCR) and cultures were conducted from lymph node aspirates, throat swabs taken from cases and samples from water sources of epidemic zone. All serum samples taken from the villagers were screened for F.tularensis antibodies with microagglutination test (MAT). Oropharyngeal tularemia was diagnosed in 11 patients, glandular form in 3 patients and pneumonic form in one patient according to clinical and laboratory results. Age of the patients ranged between 6-75 years old (mean age: 52.5 years) and thirty one of them (54.7%) were female. MAT titers ranged between 1/160 and 1/5120 in cases of tularemia. Causative agent was grown in the cultures of two patients (including a throat swab and a lymph node aspirate). F.tularensis DNA was shown by PCR in a throat swab and four lymph node aspirates. F.tularensis was also detected by PCR in the water sample obtained from one of the spring water commonly used by villagers. Only one of the lymph node samples obtained from two different patients, was positive by direct fluorescent antibody method. Causative agent was defined as F.tularensis subsp. holarctica by conventional and also molecular methods. Patients were treated with aminoglycoside (streptomycin, gentamicin, amikacin) or quinolone (ciprofloxacin, levofloxacin) antibiotics. Treatment failure was observed in five

  14. Physical and microbiological properties of alluvial calcareous Çumra province soils (Central Anatolia, Turkey

    Directory of Open Access Journals (Sweden)

    Ahmet Sami Erol

    2015-04-01

    Full Text Available Alluvial calcareous soils in Central Anatolia (Konya province, Çumra district has a heavy granulometric composition (average clay, low organic carbon content (less than 1%, but stable pore space structure and favorable agrophysical properties. Studies of the water regime in drip irrigation confirm favorable hydrological properties of these soils. It is assumed that the favorable structure of the pore space due to vigorous activity a large and diverse soil biota. Four phyla dominate in soil biota, among which predominate Actinobacteria. The higher (Streptomyces, and lower (three species Rhodococcus actinobacteria are predominant in large amounts as a part of this phyla. Large biodiversity at a sufficiently high bacteria richness formed the structure of the microbial community that contribute to the balanced production of specific metabolites, including gases (CO2, N2, which allows the soil to function actively, preventing compaction of the pore space and maintaining optimal density, porosity, hydrologic properties of the studied silty clay soils. m the uppermost soil horizons. Analyses of heavy mineral fraction show presence of metamorphic and igneous minerals which indicate participation of weathering products from other rock types in the nearby area. The types of heavy minerals in soils depend more on composition of parent rocks and geomorphic position than on climate type. Soils from Nova Lovcha show similar composition, but the quantity of goethite and hematite significantly increase in soil from plain. Typical high-metamorphic minerals as andalusite, kyanite and sillimanite present only in Nova Lovcha, while garnet dominates in Petrovo and opaque minerals - in Dobrostan. Red soils, formed on slopes, where erosion prevails over accumulation, contain more illite, smectite and vermiculite-smectite, and very few or no kaolinite, whereas the kaolinite is dominant in soils formed on plain. The mineralogical composition of clays in different

  15. Mineral and whole-rock geochemistry of the Topuk Granitoid (Bursa, Western Anatolia, Turkey)

    Science.gov (United States)

    Orhan, Ayşe; Demirbilek, Mehmet; Mutlu, Halim

    2014-05-01

    by the interaction of post-collisional, calc-alkaline, metaluminous and I-type coeval felsic and mafic magmas at shallow depths under similar physicochemical conditions. Keywords: Turkey, Western Anatolia, Topuk Granitoid, geochemistry. Acknowledgement: This study is supported by the Scientific and Technical Research Council of Turkey (TÜBİTAK; YDABAG-111Y289).

  16. The Gediz River fluvial archive: A benchmark for Quaternary research in Western Anatolia

    Science.gov (United States)

    Maddy, D.; Veldkamp, A.; Demir, T.; van Gorp, W.; Wijbrans, J. R.; van Hinsbergen, D. J. J.; Dekkers, M. J.; Schreve, D.; Schoorl, J. M.; Scaife, R.; Stemerdink, C.; van der Schriek, T.; Bridgland, D. R.; Aytaç, A. S.

    2017-06-01

    The Gediz River, one of the principal rivers of Western Anatolia, has an extensive Pleistocene fluvial archive that potentially offers a unique window into fluvial system behaviour on the western margins of Asia during the Quaternary. In this paper we review our work on the Quaternary Gediz River Project (2001-2010) and present new data which leads to a revised stratigraphical model for the Early Pleistocene development of this fluvial system. In previous work we confirmed the preservation of eleven buried Early Pleistocene fluvial terraces of the Gediz River (designated GT11, the oldest and highest, to GT1, the youngest and lowest) which lie beneath the basalt-covered plateaux of the Kula Volcanic Province. Deciphering the information locked in this fluvial archive requires the construction of a robust geochronology. Fortunately, the Gediz archive provides ample opportunity for age-constraint based upon age estimates derived from basaltic lava flows that repeatedly entered the palaeo-Gediz valley floors. In this paper we present, for the first time, our complete dataset of 40Ar/39Ar age estimates and associated palaeomagnetic measurements. These data, which can be directly related to the underlying fluvial deposits, provide age constraints critical to our understanding of this sequence. The new chronology establishes the onset of Quaternary volcanism at ∼1320ka (MIS42). This volcanism, which is associated with GT6, confirms a pre-MIS42 age for terraces GT11-GT7. Evidence from the colluvial sequences directly overlying these early terraces suggests that they formed in response to hydrological and sediment budget changes forced by climate-driven vegetation change. The cyclic formation of terraces and their timing suggests they represent the obliquity-driven climate changes of the Early Pleistocene. By way of contrast the GT5-GT1 terrace sequence, constrained by a lava flow with an age estimate of ∼1247ka, span the time-interval MIS42 - MIS38 and therefore do not

  17. Magnetotelluric Imaging of Hasandaǧ-Karacadaǧ Monogenetic Cluster, Central Anatolia, Turkey

    Science.gov (United States)

    Uslular, Göksu; Bülent Tank, Sabri; Özaydın, Sinan; Karaş, Mustafa; Gençalioǧlu-Kuşcu, Gonca; Sandvol, Eric

    2017-04-01

    Hasandaǧ stratovolcano is one of the most devastating volcanic edifices in the Central Anatolia, Turkey. The volcano has been studied for decades but there is still no consensus on its origin. To provide new insight on Hasandaǧ, there is also a need for geophysical explorations (e.g. seismology, magnetotelluric-MT) within the region. As a part of collaborative multidisciplinary project (CD-CAT: Continental Dynamics/Central Anatolian Tectonics) funded by NSF, we conducted 25 MT (360 Hz - 0.0002 Hz) measurements to reveal the electrical conductivity structure of the volcanic region between Hasandaǧ and Karacadaǧ stratovolcanoes. By means of two- and three-dimensional numerical modelling attempts based on several state-of-the-art algorithms, the MT data were utilized to create SW-NE trending profiles that visualize to a depth of 50-km of the subsurface structure. Prior to two-dimensional modelling, dimensionality analyses (i.e. geo-electric strike angle determination following Groom and Bailey decomposition for single-site and multi-site cases, phase tensors and induction vectors) were performed. Preliminary findings lead us to suggest that (i) there is a highly conductive body from 20 km to 40 km depth beneath the monogenetic field (i.e. Eǧrikuyu) between Hasandaǧ and Karacadaǧ. This may correspond to the possible depth at which widespread mildly-alkaline basalts are formed due to the decompression melting of heterogeneous mantle (mixing of mostly subduction-modified lithospheric and partially upwelling asthenospheric). (ii) Relatively low conductive body at shallow depth possibly due to the presence of buried ignimbrite. (iii) One of the maar with a deep source (diatreme-like) may still store hot fluids that result from highly conductive body, and here would be a suitable prospect area for geothermal exploration. (iv) low to high conductivity boundary underneath the Tuz Gölü fault appear as a barrier for fluid flow.

  18. Kinematics of SW Anatolia implications on crustal deformation above slab tear

    Science.gov (United States)

    Özkaptan, Murat; Koç, Ayten; Lefebvre, Côme; Gülyüz, Erhan; Uzel, Bora; Kaymakci, Nuretdin; Langereis, Cornelis G.; Özacar, Arda A.; Sözbilir, Hasan

    2014-05-01

    SW Anatolian tectonics are dominated mainly by emplacement of Lycian Nappes from north to south over the Beydaǧları platform during the early to middle Miocene, which followed by the development of the so called Fethiye Burdur Fault Zone (FBFZ). This fault zone is supposed to be a sinistral strike-slip fault zone that accommodated more than 100 km displacement between the Menderes Massif and the Beydaǧları platform during the exhumation of the Menderes Massif, mainly during the late Miocene. In addition, the FBFZ is collinear with the on-land NE continuation of the Pliny Trench along which the north subducting African slab is thought to be torn apart and retreated from somewhere around the apex of Isparta Angle to its present configuration as a STEP fault. In order to test already proposed evolutionary scenarios, and the feasibility of a STEP fault scenario and tectonic evolution of the region, we have conducted a rigorous paleomagnetic and kinematic study in the region containing more than 3000 paleomagnetic samples collected from 88 locations distributed evenly all over SW Anatolia and more than 2000 fault slip data measured mainly along the FBFZ. According to our preliminary results, except for some local insignificant clockwise rotations - the region underwent counter-clockwise rotation during the early to Late Miocene. The rotation senses and amounts are almost the same everywhere implying that rotation took place uniformly everywhere, as a rigid body rotation or the region underwent no internal rotational deformation. Likewise, rotations in the west and the east of FBFZ are similar for the post-late Miocene implying no internal rotational deformation. In addition to paleomagnetic data, the slickenside pitches and constructed paleostress configurations mainly along the FBFZ indicated that the faults within the FBFZ are mainly normal in character although minor lateral components are observed at the fault terminations or intersections. These fault slip

  19. Geodynamic Evolution of Subduction to Collision to Escape in Central Anatolia From Surface to Mantle - Results From the CD-CAT Project

    Science.gov (United States)

    Darin, Michael

    2017-04-01

    Despite significant progress toward understanding the kinematics of modern tectonic escape in Anatolia, considerable uncertainty remains regarding the dynamics of the transition from collision to escape. Because of the relatively small size of the Anatolia microplate, regional-scale studies spanning the plate margins and interior are well-suited to investigate the driving forces and space-time evolution of this unique tectonic transition in collisional orogens. CD-CAT (Continental Dynamics-Central Anatolia Tectonics) is a five-year (2011-2016) project funded by the National Science Foundation (USA) designed to explore the surface-to-mantle dynamics of Anatolia during the Cenozoic subduction-collision-escape transition in central Anatolia. Our approach integrates results from a diversity of methods including: structural, stratigraphic, and geomorphic analyses; magnetostratigraphy; low-temperature thermochronometry; Ar/Ar geochronology; geochemistry; passive seismic experiments (71 stations over two years); magnetotellurics; and numerical modeling. The principal results from this project include: recognition of a margin-wide magmatic lull from 40-20 Ma, followed by a southwestward migration of the initiation of magmatism toward and within the Central Anatolia Volcanic Province (CAVP); an early Miocene switch from contraction/transpression to extension/transtension in the Kırşehir and Niǧde Massifs, while contraction changed to late Miocene strike-slip deformation east of the Central Anatolian fault zone (CAFZ); rain shadow development due to uplift of the central Taurides 11-5 Ma; thin to absent lithospheric mantle beneath central Anatolia; the lack of an Arabia slab shallower than 800 km depth; and a change in the Cyprus slab from horizontal beneath the central Taurides and apparently fragmented beneath the CAVP, to very steeply dipping beneath the eastern Isparta Angle. The CAFZ lies along part of the Inner Tauride Suture (ITS) and represents a fundamental

  20. Characterisation of a uranium fire aerosol

    International Nuclear Information System (INIS)

    Leuscher, A.H.

    1976-01-01

    Uranium swarf, which can burn spontaneously in air, creates an aerosol which is chemically toxic and radiotoxic. The uptake of uranium oxide in the respiratory system is determined to a large extent by the characteristics of the aerosol. A study has been made of the methods by which aerosols can be characterised. The different measured and defined characteristics of particles are given. The normal and lognormal particle size distributions are discussed. Shape factors interrelating characteristics are explained. Experimental techniques for the characterisation of an aerosol are discussed, as well as the instruments that have been used in this study; namely the Andersen impactor, point-to-plane electrostatic precipitator and the Pollak counter. Uranium swarf was made to burn with a heated filament, and the resulting aerosol was measured. Optical and electron microscopy have been used for the determination of the projected area diameters, and the aerodynamic diameters have been determined with the impactor. The uranium fire aerosol can be represented by a bimodal, or monomodal, lognormal particle size distribution depending on the way in which the swarf burns. The determined activity median aerodynamic diameter of the two peaks were 0,49μm and 6,0μm respectively [af

  1. Post-Paleogene (post-Middle Eocene-pre-Miocene) Geodynamic evolution of the Upper Cretaceous-Paleogene Basins in Central Anatolia, Turkey

    Science.gov (United States)

    Rojay, Bora

    2017-04-01

    Central Anatolia is one of the key areas on the evolution of Cretaceous-Paleogene Tethys where stratigraphy of the region is well studied. However not well linked with tectonics. The so-called "Ankara Mélange" belt (AOM) and the basins on top are important elements in the understanding of the İzmir-Ankara-Erzincan suture belt (İAES) evolution in Anatolia (Turkey) and in the evolution of Tethys in minor Asia (Turkey). Some of the basins are directly situated on top of the tectonic slices of the accretionary prism (IAES). However, some are not tectonically well explained as in the case of Haymana basin. The southern continental fragments (eg. Kütahya-Bolkardaǧ and Kırşehir blocks from Gondwana) are approaching to northern continents (Pontides of Lauriasia) where basins like Haymana, Alçı, Kırıkkale and Orhaniye extensional basins are evolved in between the closing margins of two continents. Haymana basin is an extensional basin developed under contractional regime on top of both northward subducting oceanic fragments and an approaching fragments of southern continents. Paleogene (end of Eocene) is the time where the Seas were retreated to S-SE Anatolia leaving a continental setting in Anatolia during Oligocene-Miocene. The slip data gathered from the faults cross-cutting the Paleogene Units and the fabric from Cretaceous mélanges depicts a NNW-SSE to NNE-SSW compressional stress regime operated during post-Eocene-pre-Miocene period. Lately the slip surfaces were overprinted by post-Pliocene normal faulting. Key words: fault slip data, Paleogene, NNW-SSE compression, Anatolia.

  2. Quantitative Characterisation of Surface Texture

    DEFF Research Database (Denmark)

    De Chiffre, Leonardo; Lonardo, P.M.; Trumpold, H.

    2000-01-01

    This paper reviews the different methods used to give a quantitative characterisation of surface texture. The paper contains a review of conventional 2D as well as 3D roughness parameters, with particular emphasis on recent international standards and developments. It presents new texture...

  3. Characterising performance of environmental models

    NARCIS (Netherlands)

    Bennett, N.D.; Croke, B.F.W.; Guariso, G.; Guillaume, J.H.A.; Hamilton, S.H.; Jakeman, A.J.; Marsili-Libelli, S.; Newham, L.T.H.; Norton, J.; Perrin, C.; Pierce, S.; Robson, B.; Seppelt, R.; Voinov, A.; Fath, B.D.; Andreassian, V.

    2013-01-01

    In order to use environmental models effectively for management and decision-making, it is vital to establish an appropriate level of confidence in their performance. This paper reviews techniques available across various fields for characterising the performance of environmental models with focus

  4. Characterising agrammatism in Standard Indonesian

    NARCIS (Netherlands)

    Anjarningsih, Harwintha Yuhria; Haryadi-Soebadi, Ratna D.; Gofir, Abdul; Bastiaanse, Roelien

    2012-01-01

    Background: The spontaneous speech of speakers of Standard Indonesian (SI) with agrammatic Broca's aphasia has not yet been characterised, although there are features of SI that are relevant for the discussion of agrammatic speech. Aims: The purpose of this study was to find the characteristic

  5. Manufacturing Methods and Characterisation of Titanium Beryllides

    International Nuclear Information System (INIS)

    Kurinskiy, P.; Klimiankou, M.; Moeslang, A.; Goraieb, A.A.; Harsch, H.

    2006-01-01

    Beryllium pebbles of about 1 mm diameter are presently the reference neutron multiplier in helium cooled pebble bed (HCPB) blanket designs, both in Japan and Europe. However, some concern exists with Be pebbles, mostly because of the uncertainty of T-release properties during DEMO reactor operation conditions. Since the recent past, beryllides like Be12Ti are considered to be one of the most promising materials for advanced neutron multipliers due to their relatively high melting point, good chemical and corrosion stability and much better tritium release behaviour compared to pure Be. Development of scaleable manufacturing methods bypassing the intrinsic brittleness of beryllides is considered to be the most challenging. In this work, we present a detailed study of two different routes of titanium beryllide fabrication, including characterisation of obtained specimens by means of Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM), X-Ray Analysis and impurity analysis performed by Plasma Emission Spectrometer. (author)

  6. O, Sr and Nd isotopic constraints on Cenozoic granitoids of Northwestern Anatolia, Turkey: Enrichment by subduction zone fluids

    Science.gov (United States)

    Yücel-Öztürk, Yeşim

    2016-05-01

    The oxygen and strontium isotope compositions of Cenozoic granitoids cropping out in the İzmir-Ankara-Erzincan suture zone help constrain the petrological evolution of magmatism in northwest Anatolia. The magmatism was mostly widespread between late Eocene (∼37 Ma) and the middle Miocene (∼14-15 Ma), and is represented by volcanic and plutonic rocks of orogenic affinity, of which Ezine, Eğrigöz, Çataldağ and Kozak are the largest Tertiary granitic plutons exposed in northwest Anatolia. They vary from granite to granodiorite, and are subalkaline, belonging to the high-K calc-alkaline I-type granite series. All these characteristics, combined with major, trace element geochemical data as well as mineralogical and textural evidence, reveal that the Oligocene-Miocene granitoids of NW Anatolia are comparable with volcanic arc granites, formed in a transitional oceanic to continental collisional tectonic setting, from a hybrid source, having crustal and mantle components that underwent further interaction with the upper crust. These plutons have initial 87Sr/86Sr ratios of 0.7072-0.7094, and εNd(t) values ranging from -3.48 to -1.20. These characteristics also indicate that a crustal component played an important role in the petrogenesis of NW Anatolian Oligocene-Miocene granitoids. The moderately evolved Ezine, Eğrigöz, Çataldağ and Kozak granitoids, have δ18O values that are consistent with those of normal I-type granites (6-10‰), but the δ18O relationships among minerals of samples collected from the intrusive contacts which are closest to mineralized zones, indicate a major influence of hydrothermal processes under subsolidus conditions. The oxygen isotope systematics of the samples from these plutons result from the activity of high-δ18O fluids (magmatic water), with major involvement of low-δ18O fluids (meteoric water) evident, near the edge zone of these plutons. This is most evident in δ18O quartz-feldspar pairs from these granitoids, which

  7. Using Multicriteria Decision Making Techniques in Free Zone for Facility Location Selection: An Example for Eastern Anatolia Region

    Directory of Open Access Journals (Sweden)

    Gökhan Ağaç

    2015-06-01

    Full Text Available Free Zones contribute to the prosperity of the region by increasing employment, attracting foreign capital, allowing technology transfer and increasing exports. In this study, an application of location selection was performed for a possible Free Zone established in provinces of Eastern Anatolia Region. For application of the study, AHP, TOPSIS, VIKOR and ELECTRE, which are multi criteria decision making techniques, were used. AHP was used for determine weights of the criteria that influence the Free Zone location selection while TOPSIS, VIKOR and ELECTRE methods were used to rank alternatives. Accordingly; the three most important criteria for the Free Zone location selection were proximity countries, quantity of exports and government incentives while first three provinces were respectively, Iğdır, Hakkâri and Van for Free Zone will be established.

  8. 3-D crustal structure along the North Anatolian Fault Zone in north-central Anatolia revealed by local earthquake tomography

    Science.gov (United States)

    Yolsal-Ćevikbilen, Seda; Biryol, C. Berk; Beck, Susan; Zandt, George; Taymaz, Tuncay; Adıyaman, Hande E.; Özacar, A. Arda

    2012-03-01

    3-D P-wave velocity structure and Vp/Vs variations in the crust along the North Anatolian Fault Zone (NAFZ) in north-central Anatolia were investigated by the inversion of local P- and S-wave traveltimes, to gain a better understanding of the seismological characteristics of the region. The 3-D local earthquake tomography inversions included 5444 P- and 3200 S-wave readings obtained from 168 well-located earthquakes between 2006 January and 2008 May. Dense ray coverage yields good resolution, particularly in the central part of the study area. The 3-D Vp and Vp/Vs tomographic images reveal clear correlations with both the surface geology and significant tectonic units in the region. We observed the lower limit of the seismogenic zone for north-central Anatolia at 15 km depth. Final earthquake locations display a distributed pattern throughout the study area, with most of the earthquakes occurring on the major splays of the NAFZ, rather than its master strand. We identify three major high-velocity blocks in the mid-crust separated by the İzmir-Ankara-Erzincan Suture and interpret these blocks to be continental basement fragments that were accreted onto the margin following the closure of Neo-Tethyan Ocean. These basement blocks may have in part influenced the rupture propagations of the historical 1939, 1942 and 1943 earthquakes. In addition, large variations in the Vp/Vs ratio in the mid-crust were observed and have been correlated with the varying fluid contents of the existing lithologies and related tectonic structures.

  9. A 6-year investigation into types of dental trauma treated in a paediatric dentistry clinic in Eastern Anatolia region, Turkey.

    Science.gov (United States)

    Eyuboglu, Ozge; Yilmaz, Yucel; Zehir, Cigdem; Sahin, Hakan

    2009-02-01

    The purpose of this study was to assess the frequency, the effective factors and the applied treatments for dental trauma among children aged 1-15 years from Eastern Anatolia in a 6-year period. The total frequency of trauma in this study was calculated as 4.9% during a 6-year period. The males were found to have more traumatic injury than females (P < 0.05). Also, the permanent teeth were more vulnerable to dental trauma than the primary teeth (P < 0.05). The highest frequency of traumas in the primary teeth was observed at the age of 5, whereas the rate for the permanent teeth was at the age of 10. The teeth mostly influenced by the traumas were the upper central incisors in both primary and permanent teeth. It was in October that traumas were mostly seen for the permanent teeth and in June for the primary teeth. The most frequent source of trauma in both genders and in both primary and permanent teeth were falls. The most common type of trauma in the primary teeth was lateral luxation, while it was enamel-dentin crown fracture in the permanent ones. Soft tissue injuries were observed in 143 of 653 dental traumatized children. The most common method of treatment was examination and follow up for the primary teeth, and only direct restoration for the permanent teeth without any endodontic treatment. 15% of the patients applied for treatment 1 year after injury event. Therefore, it was concluded that the patients, parents and teachers living in Eastern Anatolia should be informed about the necessity of early treatment of dental traumas and the consequence of a delay.

  10. Extensional and compressional regime driven left-lateral shear in southwestern Anatolia (eastern Mediterranean): The Burdur-Fethiye Shear Zone

    Science.gov (United States)

    Elitez, İrem; Yaltırak, Cenk; Aktuğ, Bahadır

    2016-10-01

    The tectonic framework of the eastern Mediterranean presented in this paper is based on an active subduction and small underwater hills/mountains on the oceanic crust moving toward the north. The Hellenic Arc, the Anaximander Mountains, the Rhodes and Finike basins, the compressional southern regions of the Western Taurides, and the extensional western Anatolian graben are the main interrelated tectonic structures that are shaped by the complex tectonic regimes. There are still heated debates regarding the structural properties and tectonic evolution of the southwestern Anatolia. GPS velocities and focal mechanisms of earthquakes demonstrate the absence of a single transform fault across the Burdur-Fethiye region; however, hundreds of small faults showing normal and left-lateral oblique slip indicate the presence of a regionally extensive shear zone in southwestern Turkey, which plays an important role in the eastern Mediterranean tectonics. The 300-km-long, 75-90-km-wide NE-SW-trending Burdur-Fethiye Shear Zone developed during the formation of Aegean back-arc extensional system and the thrusting of Western Taurides. Today, the left-lateral differential motion across the Burdur-Fethiye Shear Zone varies from 3 to 4 mm/yr in the north to 8-10 mm/yr in the south. This finding could be attributed to the fact that while the subduction of the African Plate is relatively fast beneath the western Anatolia at the Hellenic Trench, it is slow or locked beneath the Western Taurides. Therefore, the GPS vectors and their distributions on land indicate remarkable velocity differences and enable us to determine the left-lateral shear zone located between the extensional and compressional blocks. Furthermore, this active tectonic regime creates differences in topography. This study also demonstrates how deep structures, such as the continuation of the subduction transform edge propagator (STEP) fault between the Hellenic and Cyprus arcs in the continental area, can come into play

  11. Geology and Tectonic Evolution of the Kazdaǧ Massif (NW Anatolia)

    Science.gov (United States)

    Erdoğan, B.; Akay, E.; Hasözbek, A.; Satır, M.; Siebel, W.

    2009-04-01

    In the northwestern part of Anatolia along the Izmir-Ankara Suture Zone, the Kazdağ and Uludağ metamorphic massifs form an E-W trending belt between the Sakarya Continent in the north and the Menderes Massif in the south. Internal succession of these two massifs have been described as metamorphic complexes consisting of various kinds of micaschists, quartz mica schist, gneisses, amphibolites and marbles. In the Kazdağ metamorphics, metaophiolites have been described additionally (Okay et al., 1991; Yaltırak and Okay, 1994; Okay et al., 1996; Duru et al., 2004). These metamorphic complexes were considered to form the basement of the Sakarya Continent tectonically overlain by the Early Permian (Topuz et al., 2004) to Late Triassic (Okay and Monie, 1997; Okay et al., 2002) Karakaya Complex. This old basement and the Karakaya Complex were suggested to be unconformably overlain by Liassic and younger platform limestones and detritals (Altıner et al., 1991). In the literature, it has also been suggested that the Kazdağ Massif had experienced polyphase metamorphism, first during Carboniferous time, second during Early Triassic and third during Tertiary (Bingöl, 1971; Okay et al., 1996; Okay and Satır, 2000). In this study we mapped the Kazdağ Massif on 1/25000 scale, studied its internal stratigraphy and structures and performed some petrologic analyses and radiogenic age determinations. Stratigraphically in the lower part of the Kazdağ metamorphic sequence, there is a part of an oceanic crust represented by metaultramafic rocks and gabbroic metacumulates. Geochemistry of these banded metagabbros show a mid-oceanic affinity. This oceanic crust is overlain, along an unconformity, by a platform type marble succession. At the base of the marbles, there is a basal conglomerate, clasts of which derived from the underlying ultramafic sequence. Thick white marble sequence is overlain along a gradational boundary with a metadetrital succession consisting of quartz mica

  12. A characterisation of algebraic exactness

    OpenAIRE

    Garner, Richard

    2011-01-01

    An algebraically exact category in one that admits all of the limits and colimits which every variety of algebras possesses and every forgetful functor between varieties preserves, and which verifies the same interactions between these limits and colimits as hold in any variety. Such categories were studied by Ad\\'amek, Lawvere and Rosick\\'y: they characterised them as the categories with small limits and sifted colimits for which the functor taking sifted colimits is continuous. They conject...

  13. Characterisation of Silicon Pad Diodes

    CERN Document Server

    Hodson, Thomas Connor

    2017-01-01

    Silicon pad sensors are used in high luminosity particle detectors because of their excellent timing resolution, radiation tolerance and possible high granularity. The effect of different design decisions on detector performance can be investigated nondestructively through electronic characterisation of the sensor diodes. Methods for making accurate measurements of leakage current and cell capacitance are described using both a standard approach with tungsten needles and an automated approach with a custom multiplexer and probing setup.

  14. Cold-pressed pumpkin seed (Cucurbita pepo L. oils from the central Anatolia region of Turkey: Characterization of phytosterols, squalene, tocols, phenolic acids, carotenoids and fatty acid bioactive compounds

    Directory of Open Access Journals (Sweden)

    G. Akin

    2018-03-01

    Full Text Available There is a growing interest in cold-pressed oils because they present high contents of bioactive compounds. These oils have the characteristic properties of seeds and are specific products of their regions. The aim of this study was to determine the compositions and contents of fatty acids, phytosterols, squalene, tocols, phenolic acids, carotenoids and phenolic bioactives, and the free radical scavenging as well as antioxidant activities of cold-pressed pumpkin (Cucurbita pepo L. seed oils. Oil samples from raw pumpkin seeds cultivated in four different central Anatolia regions of Turkey were prepared using a laboratory screw-pressing machine. The results indicate that cold-pressed pumpkin seed oils (PSO have excellent quality with high contents of polyunsaturated fatty acids (%ΣPUFAs (53.60 ±0.06-53.73 ±0.05, total phytosterols (782.1±9.7–805.2 ±11.3 mg/100 g oil, squalene (591.3±10.6–632.5±11.4 mg/100 g oil, tocols (97.79 ±0.76?94.29 ±0.34 mg/100 g oil, phenolic acids (22.73 ±0.41–23.98 ±0.46 mg/100 g oil, carotenoids (6.95 ±0.03–7.60 ±0.03 mg/100 g oil, total phenolics (3.96 ±0.13 –5.82±0.15 mg GAE/100 g, free radical-scavenging activity (5.70 ±0.13?7.35 ±0.15 mg GAE/100 g and total antioxidant activity (26.67±0.97-38.89±1.41 mg GAE/100 g values. Thus, this study demonstrates that the cold- pressed PSOs from the central Anatolia regions of Turkey are an excellent source of natural bioactive compounds, free of chemical contaminants and nutritious.

  15. Characterisation and Airborne Deployment of a New Counterflow Virtual Impactor Inlet

    Science.gov (United States)

    2012-06-06

    properties. Essential to understanding these interactions are properties including particle size distribu- tion, chemical composition and hygroscopicity ...detection limit issues (e.g., Berg et al., 2009); for example, a particle- into- liquid sampler (PILS) typically requires approximately 12–15 l min−1 of...Laboratory characterisation CVI characterisation experiments were performed using the BMI wind tunnel following methods described in Anderson et al. (1993). A

  16. The plasters of the Sacro Monte of Varallo Sesia. From the characterisation to the proposition of a restorative mix

    Directory of Open Access Journals (Sweden)

    Alessandra Formia

    2014-01-01

    The plasters characterisation realised in laboratory for in situ integration is also presented. These plasters should meet functional and aesthetical requirements and must satisfy the compatibility issues not only related to the physical-chemical aspects.

  17. Preparation and characterisation of glass surfaces for experimental purposes

    International Nuclear Information System (INIS)

    Serruys, Y.

    1986-01-01

    Experimental investigation of glasses, applied especially to the prevision of the behaviour of vitrified nuclear wastes, requires the preparation of well-defined and reproducibles surfaces, in order to separate the investigated phenomena from artifacts due to surface anomalies and to allow a valuable comparison between results obtained in different laboratories. The aim of the present report is to determine which characters, both physical and chemical, of glass surfaces, have to be controlled, because of their influence upon the investigated phenomena or the experimental processes employed in the investigation. A method is then presented for a surface preparation giving good guaranties of quality and reproducibility. The physical and chemical aspects of surface characterisation are successively considered. The relevant characters and their importance are described, then the corresponding techniques of characterisation are reviewed and it has been attempted to propose a set of techniques allowing a characterisation as complete as possible for laboratory purposes. A preparation method for experimental sample, aiming to satisfy all the previously defined criteria, is then proposed, and present results obtained with this method are described [fr

  18. Record of high-pressure overprint in metamorphic soles of the Tavşanli zone, Western Anatolia

    Science.gov (United States)

    Plunder, Alexis; Agard, Philippe; Chopin, Christian; Okay, Aral

    2013-04-01

    Large obducted ophiolites correspond to the emplacement of dense oceanic lithosphere on top of a continent and thereby provide insights into rheological and thermal coupling between plates or fluid budgets. Obducted ophiolites thrust onto the continental margin of the Anatolide-Tauride block (Western Anatolia, south of the Izmir-Ankara suture zone) are dated through their metamorphic sole at ca. 90-95Ma and derive from the same intra-oceanic Neotethyan subduction. We herein focus on the metamorphic soles of the Tavşanlı zone, which show a variable high-pressure low-temperature (HP-LT) overprint of the initial amphibolitic metamorphic conditions (Önen & Hall, 1993; Dilek & Whitney, 1997; Okay et al, 1998). Systematic sampling was done in both the already studied areas as well as new locations. PT conditions were estimated at 8 kbar and 700°C for the amphibolitic stage with the assemblage hornblende + plagioclase ± garnet ± epidote. The HP-LT metamorphic overprint reached incipient blueschist to blueschist facies PT conditions. Development of the characteristic assemblage glaucophane + lawsonite yields PT estimates of >6-7 kbar and 300°C. The high-pressure stage is similar to the one observed for the underlying accretionary-complex unit of the Tavşanlı zone (Plunder et al, this meeting). This HP overprint was not observed in other obduction contexts such as Oman or New Caledonia but was documented in Fransciscan Complex amphibolites (Wakayabashi, 1990). The record of two metamorphic events can be understood as: (1) rapid cooling of the subduction zone after initiation and the exhumation of the metamorphic sole; (2) reburial after or during exhumation of the amphibolite initially welded at the base of the ophiolite. Several observations (i.e., lack of tectonic contact between the ophiolitic body and the metamorphic sole, PT estimates,...) point to cooling as the most likely hypothesis. Metamorphic soles allow to highlight: (1) the dynamics of obducted

  19. Old stories and lost pieces of the Eastern Mediterranean puzzle: a new approach to the tectonic evolution of the Western Anatolia and the Aegean Sea

    Science.gov (United States)

    Yaltırak, Cenk; Engin Aksu, Ali; Hall, Jeremy; Elitez, İrem

    2015-04-01

    During the last 20 or so years, the tectonic evolution of Aegean Sea and Western Anatolia has been dominantly explained by back-arc extension and escape tectonics along the North Anatolian Fault. Various datasets have been considered in the construction of general tectonic models, including the geometry of fault patterns, paleomagnetic data, extensional directions of the core complexes, characteristic changes in magmatism and volcanism, the different sense of Miocene rotation between the opposite sides of the Aegean Sea, and the stratigraphy and position of the Miocene and Pliocene-Quaternary basins. In these models, the roles of the Burdur-Fethiye Shear Zone, the Trakya-Eskişehir Fault Zone, the Anaximander Mountains and Isparta Angle have almost never been taken into consideration. The holistic evaluation of numerous land and marine researches in the Aegean Sea and western Anatolia suggest the following evolutionary stages: 1. during the early Miocene, Greece and western Anatolia were deformed under the NE-SW extensional tectonics associated with the back-arc extension, when core complexes and supra-detachment basins developed, 2. following the collision of the Anaximander Mountains and western Anatolia in early Miocene , the Isparta Angle locked this side of the western arc by generating a triangle-shaped compressional structure, 3. while the Isparta Angle penetrated into the Anatolia, the NE-striking Burdur-Fethiye Shear Zone in the west and NW-striking Trakya-Eskişehir Fault Zone in the north developed along the paleo-tectonic zones , 4. the formation of these two tectonic structures allowed the counterclockwise rotation of the western Anatolia in the middle Miocene and this rotation removed the effect of the back-arc extension on the western Anatolian Block, 5. the counterclockwise rotation developed with the early westward escape of the Western Anatolian reached up to 35-40o and Trakya-Eskişehir Fault Zone created a total dextral displacement of about 200

  20. Characterisation of wood combustion ashes

    DEFF Research Database (Denmark)

    Maresca, Alberto

    The combustion of wood chips and wood pellets for the production of renewable energy in Denmark increased from 5.7 PJ to 16 PJ during the period 2000-2015, and further increases are expected to occur within the coming years. In 2012, about 22,300 tonnes of wood ashes were generated in Denmark....... Currently, these ashes are mainly landfilled, despite Danish legislation allowing their application onto forest and agricultural soils for fertilising and/or liming purposes. During this PhD work, 16 wood ash samples generated at ten different Danish combustion plants were collected and characterised...... for their composition and leaching properties. Despite the relatively large variations in the contents of nutrients and trace metals, the overall levels were comparable to typical ranges reported in the literature for other wood combustion ashes, as well as with regards to leaching. In general, the composition...

  1. Characterisation of TRISO fuel particles

    International Nuclear Information System (INIS)

    Lopez H, E.; Yang, D.

    2012-10-01

    The TRISO (tri structural isotropic) coated fuel particle is a key component contributing to the inherent safety of the High Temperature Reactor. A uranium kernel is coated with three layers of pyrolytic carbon and one of silicon carbide. The purpose of these coatings is to work as a miniature fission product containment vessel capable of enclosing all important radio nuclei under normal and off-normal reactor operating conditions. Due to the importance of these coatings, is of great interest to establish characterisation techniques capable of providing a detailed description of their microstructure and physical properties. Here we describe the use of Raman spectroscopy and two modulator generalised ellipsometry to study the anisotropy and thermal conductivity of pyrolytic carbon coatings, as well as the stoichiometry of the silicon carbide coatings and fibres. (Author)

  2. The Konya earthquakes of 10–11 September 2009 and soil conditions in Konya, Central Anatolia, Turkey

    Directory of Open Access Journals (Sweden)

    R. Aksoy

    2012-02-01

    Full Text Available Earthquakes registering magnitudes Md = 4.5 and 4.7 struck the city of Konya, Central Anatolia, on 10–11 September 2009, causing very slight damages. The earthquake epicenters were located at the east of Sille District along the Konya Fault Zone, a dip-slip fault. The nature and seismicity of the fault zone indicates that it is capable of producing earthquakes of moderate magnitudes. This paper summarizes the geologic data along the fault zone and documents groundwater conditions and analyzes borehole and geotechnical data of the Konya city. The residential area of the city covers an area of approximately 1150 square kilometers and consists almost entirely of flat land except for a small part of rugged land in the southwestern corner. Groundwater and geotechnical data were collected and analyzed to evaluate the liquefaction potential of deposits under the Konya city. This preliminary investigation indicates that areas for liquefaction are generally limited to the eastern and east central parts of the city.

  3. Naturally occurring arsenic in terrestrial geothermal systems of western Anatolia, Turkey: potential role in contamination of freshwater resources.

    Science.gov (United States)

    Bundschuh, Jochen; Maity, Jyoti Prakash; Nath, Bibhash; Baba, Alper; Gunduz, Orhan; Kulp, Thomas R; Jean, Jiin-Shuh; Kar, Sandeep; Yang, Huai-Jen; Tseng, Yu-Jung; Bhattacharya, Prosun; Chen, Chien-Yen

    2013-11-15

    Arsenic (As) contamination in terrestrial geothermal systems has been identified in many countries worldwide. Concentrations higher than 0.01 mg/L are detrimental to human health. We examined potential consequences for As contamination of freshwater resources based on hydrogeochemical investigations of geothermal waters in deep wells and hot springs collected from western Anatolia, Turkey. We analyzed samples for major ions and trace element concentrations. Temperature of geothermal waters in deep wells showed extreme ranges (40 and 230 °C), while, temperature of hot spring fluids was up to 90 °C. The Piper plot illustrated two dominant water types: Na-HCO3(-) type for geothermal waters in deep wells and Ca-HCO3(-) type for hot spring fluids. Arsenic concentration ranged from 0.03 to 1.5mg/L. Dominance of reduced As species, i.e., As(III), was observed in our samples. The Eh value ranged between -250 and 119 mV, which suggests diverse geochemical conditions. Some of the measured trace elements were found above the World Health Organization guidelines and Turkish national safe drinking water limits. The variation in pH (range: 6.4-9.3) and As in geothermal waters suggest mixing with groundwater. Mixing of geothermal waters is primarily responsible for contamination of freshwater resources and making them unsuitable for drinking or irrigation. Copyright © 2013 Elsevier B.V. All rights reserved.

  4. Complementary techniques for solid oxide electrolysis cell characterisation at the micro- and nano-scale

    DEFF Research Database (Denmark)

    Wiedenmann, D.; Hauch, Anne; Grobety, B.

    2010-01-01

    ), material degradation and evaporation can occur, e.g., from the cell-sealing material, leading to poisoning effects and aging mechanisms that decrease the cell efficiency and long-term durability. To investigate such cell degradation processes, thorough examination of SOCs often requires a chemical...... approach for the structural and chemical characterisation of changes in aged cathode-supported electrolysis cells produced at Risø DTU, Denmark. Additionally, we present results from the characterisation of impurities at the electrolyte/hydrogen interface caused by evaporation of sealing material....

  5. Characterisation of Tmmmian Local Sorghmn Varieties

    African Journals Online (AJOL)

    Many local varieties of sorghum grown in Tanzania have not been characterised in terms of their end uses. This study was conducted to characterise 14 such varieties. Three improved varieties commonly grown in this country were includedfor comparison. Physical analyses that included 100-grain weight, percent dehulling ...

  6. Characterisation of wastewater for modelling of wastewater ...

    African Journals Online (AJOL)

    Bio-process modelling is increasingly used in design, modification and troubleshooting of wastewater treatment plants (WWTPs). Characterisation of the influent wastewater to a WWTP is an important part of developing such a model. The characterisation required for modelling is more detailed than that routinely employed ...

  7. Characterisation of wastewater for modelling of wastewater ...

    African Journals Online (AJOL)

    Bio-process modelling is increasingly used in design, modification and troubleshooting of wastewater treatment plants. (WWTPs). Characterisation of the influent wastewater to a WWTP is an important part of developing such a model. The characterisation required for modelling is more detailed than that routinely employed ...

  8. Physico-chemical characterisation and antioxidant activity of some ...

    African Journals Online (AJOL)

    Ojarikre

    mg AAE/100 g). However, betacyanin and total betalains contents were obtained in red juicy pulp. Following this rich composition in antioxidants, the four varieties studied showed performances in reducing ... functional ingredients for the soft drink market, including ... all aspects concerning this fruit in Algeria, current study.

  9. Chemical characterisation of unrefined rock salt deposits of pakistan

    International Nuclear Information System (INIS)

    Hassan, A.U.; Din, A.N.U.; Muhsen, S.; Ali, S.

    2016-01-01

    Different salt samples from mining sites of Bahadur Khel, Warcha and Jatta salt mines were collected during a survey to evaluate their parameters of purity like water insoluble matter, calcium, magnesium, sulphate and potassium contents.Trace elements such as iron, zinc, copper, mangansese, chromium, lead and cadmium were determined by using Atomic absorption Spectrophotometer.Obtained results have shown that of all the three salt deposits, Bahadur Khel salt deposits have a of low purity of 97% set by codex alimentarius commission. Trace element contents of all the salt deposits were within the legal limits of human consumption and RDA specification. (author)

  10. Characterisation of microbiological and physico-chemical properties ...

    African Journals Online (AJOL)

    The most prevalent bacteria isolated were Escherichia coli, Streptococcus faecalis, Pseudomonas aeruginosa, Vibrio parahaemolyticus, and Clostridium perfringens with Penicillium digitatum as the only prevalent mould. The mean temperature ranges from 28.40 to 29.10 0C, pH from 7.80 to 9.03 and salinity level from 1.06 ...

  11. Physiochemical characterisation of mangafodipir trisodium

    International Nuclear Information System (INIS)

    Tirkkonen, B.; Grace, D.; Haile, Y.; Holm, K.M.; Hope, H.; Larsen, Aa.; Lunde, H.S.; Sjoegren, C.E.

    1997-01-01

    Purpose: To determine the structure and various physicochemical properties of mangafodipir (MnDPDP) trisodium, the active ingredient of Teslascan, a new organ-specific contrast medium for MR imaging. Material and Methods: The structure of MnDPDP trisodium crystals was determined by X-ray crystallography. The possible existence of polymorphism in MnDPDI trisodium was evaluated by powder X-ray diffraction, optical microscopy, thermal analysis and IR spectroscopy. In addition, various spectroscopic techniques and phyicochemical measurements were used for characterisation of MnDPDP trisodium. Results: The crystallogrpahic data obtained for MnDPDP trisodium show that the general core structure of the MnDPDP anion is similar to that seen in related substances. The metal coordination geometry is a distorted octahedron defined by 2 phenolate oxygens, 2 carboxylate oxygens and 2 amine nitrogens. The unit cell contains 2 MnDPDP anions, 6 sodium ions and 50 water molecules. The various spectroscopic data are consistent with the structure determined by X-ray crystallography. The product (Teslascan) has low viscosity, is isotonic with blood and has a physiological pH. (orig./AJ)

  12. Characterisation: Challenges and Opportunities - A UK Perspective

    International Nuclear Information System (INIS)

    Emptage, Matthew; Loudon, David; Mcleod, Richard; Milburn, Helen

    2016-01-01

    Characterisation plays a very important role in the nuclear industry supporting: the development and implementation of decommissioning strategies/plans (and the optimisation of associated costs through reduction in technical risks); regulatory compliance demonstration; waste prevention/minimisation; evaluation and optimisation of worker radiation doses; and maintaining public confidence. Recognising these important drivers, the UK regulators are working with the UK Nuclear Decommissioning Authority (NDA) to undertake a review of characterisation practice in the UK nuclear (decommissioning) industry. The objective of the characterisation review is to understand the current characterisation challenges and to determine strategic and tactical opportunities (including sharing of standards and guidance, capabilities, learning from experience, good practice, research and development, training, quality assurance) to optimise characterisation practice. The work is being undertaken through review of nuclear operator's characterisation practice, with input from the NDA, the UK regulators, nuclear operators and representatives from the supply chain, and through consideration of good practice case studies. To support this, a catalogue of relevant national/international guidance documents is also be compiled. Finally a workshop with representatives from all parties has taken place to consider the findings and establish a common understanding of challenges and opportunities and to start to consider how they can be addressed. The review is establishing a collective (UK regulator's, NDA; nuclear operator's and supply chain) understanding of opportunities to improve characterisation practice in the UK. The characterisation review process is described and early results are presented and discussed. Subsequent work in 2016 will be required to prioritise the opportunities and to build a consensus to facilitate development and implementation of an improvement plan. The aim

  13. A comparison of Y-chromosome variation in Sardinia and Anatolia is more consistent with cultural rather than demic diffusion of agriculture.

    Directory of Open Access Journals (Sweden)

    Laura Morelli

    Full Text Available Two alternative models have been proposed to explain the spread of agriculture in Europe during the Neolithic period. The demic diffusion model postulates the spreading of farmers from the Middle East along a Southeast to Northeast axis. Conversely, the cultural diffusion model assumes transmission of agricultural techniques without substantial movements of people. Support for the demic model derives largely from the observation of frequency gradients among some genetic variants, in particular haplogroups defined by single nucleotide polymorphisms (SNPs in the Y-chromosome. A recent network analysis of the R-M269 Y chromosome lineage has purportedly corroborated Neolithic expansion from Anatolia, the site of diffusion of agriculture. However, the data are still controversial and the analyses so far performed are prone to a number of biases. In the present study we show that the addition of a single marker, DYSA7.2, dramatically changes the shape of the R-M269 network into a topology showing a clear Western-Eastern dichotomy not consistent with a radial diffusion of people from the Middle East. We have also assessed other Y-chromosome haplogroups proposed to be markers of the Neolithic diffusion of farmers and compared their intra-lineage variation--defined by short tandem repeats (STRs--in Anatolia and in Sardinia, the only Western population where these lineages are present at appreciable frequencies and where there is substantial archaeological and genetic evidence of pre-Neolithic human occupation. The data indicate that Sardinia does not contain a subset of the variability present in Anatolia and that the shared variability between these populations is best explained by an earlier, pre-Neolithic dispersal of haplogroups from a common ancestral gene pool. Overall, these results are consistent with the cultural diffusion and do not support the demic model of agriculture diffusion.

  14. Thermal Characterisation of Brake Pads

    DEFF Research Database (Denmark)

    Ramousse, Séverine; Høj, Jakob Weiland; Sørensen, O. T.

    2001-01-01

    The chemical-physical decomposition processes that occur in a brake pad heated to 1000degreesC have been studied. This temperature can be reached when a brake pad is applied. Thermogravimetry and differential thermal analysis were used in combination with evolved gas analysis, and image analysis...... using a scanning electron microscope.A brake pad is essentially a mixture of iron, carbon and binder. Combined techniques have been used, because of chemical reaction overlap, to determine how and at what temperature the binder decomposes, the coal and graphite combust and the iron oxidises.This work...... enables the development of brake pads that are stable at high temperature....

  15. Physico-chemical characterisation of particulate heavy metals from municipal solid waste incinerator emissions and their contributions to ambient air quality. Case of Toulon MSWI (South of France); Caracterisation physico-chimique et tracage des emissions particulaires metalliques d'une usine d'incineration d'ordures menageres dans l'air ambiant. Exemple de l'UIOM de Toulon (Var, France)

    Energy Technology Data Exchange (ETDEWEB)

    Le Floch, M

    2004-07-15

    The aims of this study are the physico-chemical characterisation, the apportionment and the following of particulate heavy metals from MSWI emissions. Various methods (in situ data treatment, unmixing models and codes, UNMIX or CMB, sequential extractions and extended X-ray absorption fine structure (EXAFS) agree in the following: - identification of the MSWI source in two profiles (Zn - Ca and Ba - Cu - Fe - Zn - Pb - Ca); - estimation of its contribution of up to 25% of the total sources contribution; - showing the seasonal variability in term of profile and contribution of this source; - suggest the potential of emitted elements to enter the food chain; This EXAFS first approach on atmospheric particulate matter shows that zinc and lead are in an atomic environment with calcium, silicon and aluminum. In spite of disputable conclusions, isotopic lead ratios define a 'MSWI' end-member and confirm that the town-center of Toulon is outside the MSWI plume influence. (author)

  16. Bronze Age Archaeointensity data from the Levant and Anatolia: Constraining the Temporal and Geographic Extent of Archaeomagnetic Jerks

    Science.gov (United States)

    Thomas, Megan; Hill, Mimi; Biggin, Andy; Greaves, Alan; Ertepinar, Pinar

    2014-05-01

    In order to understand the behaviour of the Earth's magnetic field on decadal to millennial timescales and to produce reliable field models, globally distributed archaeointensity data are required. Such well constrained models will also enable us to test hypotheses of geomagnetic-climate coupling during the Holocene. Here, we will present new high quality archaeointensity data spanning the age range 2200 BC to 700 BC from Turkey. Additionally we will present the first archaeointensity data for Cyprus from 2400 BC to 2000 BC. The intensity results and associated rock magnetic data were obtained from unoriented pottery samples and oriented burnt mud bricks from two Bronze Age archaeological sites in Southern Turkey: Tell Atchana and Kilise Tepe and from two Bronze Age sites in Central and Northern Cyprus: Marki Alonia and Bellapais Vounous. Strict criteria were applied to the results of archaeointensity measurements made using microwave and thermal techniques. Archaeointensity experiments followed both the Coe and IZZI Thellier-type protocols. A success rate of 32% from a total of 174 samples was recorded. The results were corrected for cooling rate and the anisotropy of the samples shaped the experiment design. The age of the samples were constrained by site stratigraphy, carbon dating of suitable related material, and pottery typology. For each archaeological context/ age group studied a variety of pottery types were analysed to improve the robustness of the results. In addition, a burnt in situ mud brick wall was analysed. The geographic location of these sites within the Levant and Anatolia enables comparison with the archaeointensity results presented by previous authors who measured exceptionally high ancient fields over the time period presented here. Some of these previous studies have correlated periods of high intensity (so called "archaeomagnetic jerks") with periods of cooling in the North Atlantic and fluctuations in the length of Swiss glaciers. The

  17. Identifying the volcanic eruption depicted in a neolithic painting at Çatalhöyük, Central Anatolia, Turkey.

    Directory of Open Access Journals (Sweden)

    Axel K Schmitt

    Full Text Available A mural excavated at the Neolithic Çatalhöyük site (Central Anatolia, Turkey has been interpreted as the oldest known map. Dating to ∼6600 BCE, it putatively depicts an explosive summit eruption of the Hasan Dağı twin-peaks volcano located ∼130 km northeast of Çatalhöyük, and a birds-eye view of a town plan in the foreground. This interpretation, however, has remained controversial not least because independent evidence for a contemporaneous explosive volcanic eruption of Hasan Dağı has been lacking. Here, we document the presence of andesitic pumice veneer on the summit of Hasan Dağı, which we dated using (U-Th/He zircon geochronology. The (U-Th/He zircon eruption age of 8.97±0.64 ka (or 6960±640 BCE; uncertainties 2σ overlaps closely with (14C ages for cultural strata at Çatalhöyük, including level VII containing the "map" mural. A second pumice sample from a surficial deposit near the base of Hasan Dağı records an older explosive eruption at 28.9±1.5 ka. U-Th zircon crystallization ages in both samples range from near-eruption to secular equilibrium (>380 ka. Collectively, our results reveal protracted intrusive activity at Hasan Dağı punctuated by explosive venting, and provide the first radiometric ages for a Holocene explosive eruption which was most likely witnessed by humans in the area. Geologic and geochronologic lines of evidence thus support previous interpretations that residents of Çatalhöyük artistically represented an explosive eruption of Hasan Dağı volcano. The magmatic longevity recorded by quasi-continuous zircon crystallization coupled with new evidence for late-Pleistocene and Holocene explosive eruptions implicates Hasan Dağı as a potential volcanic hazard.

  18. Seismicity and Seismotectonic Properties of The Sultandağı Fault Zone (Afyonkarahisar-Konya): Western Anatolia,Turkey

    Science.gov (United States)

    Kalafat, D.; Gunes, Y.; Kekovali, K.; Kara, M.; Gorgun, E.

    2017-12-01

    n this study we investigated seismicity and source characteristics of the Sultandağı Fault Zone (SFZ). As known Western Anatolia is one of the most important seismically active region in Turkey. The relative movement of the African-Arabian plates, it causes the Anatolian Plate to movement to the west-Southwest direction 2.5 cm per year and this result provides N-S direction with extensional regime in the recent tectonic. In this study, especially with the assessment of seismic activity occurring in Afyon and around between 200-2002 years, we have been evaluated to date with seismic activity as well as fault mechanism solution. We analyzed recent seismicity and distribution of earthquakes in this region. In the last century, 3 important earthquakes occurred in the Sultandağı Fault zone (Afyon-Akşehir Graben), this result shown it was seismic active and broken fault segments caused stress balance in the region and it caused to occur with short intervals of earthquakes in 2000 and 2002, triggering each other. The scope of this tudy, we installed new BB stations in the region and we have been done of the fault plane solutions for important earthquakes. The focal mechanisms clearly exhibit the activation of a NE-SW trending normal faulting system along the SFZ region. The results of stress analysis showed that the effective current tectonic evolution of normal faulting in this region. This study is supported by Bogazici University Research Projects Commission under SRP/BAP project No. 12280. Key Words: Sultandağı fault zone, normal faulting, seismicity, fault mechanism

  19. Geology and U-Pb Zircon ages of the Kavacik Leucogranite in the Bornova Flysch Zone (Western Anatolia, Turkey)

    Science.gov (United States)

    Güngör, Talip; Hasözbek, Altuǧ; Akal, Cüneyt; Mertz-Kraus, Regina; Peştemalci Üregel, Reyhan

    2016-04-01

    The Bornova Flysch Zone comprises an olistostrome-melange situated NE-SW direction between the Izmir Ankara Suture Zone and the Menderes Massif. The Bornova Flysch Zone is mainly composed of slightly deformed Late Cretaceous to Paleocene sandstone and shale with Mesozoic limestone and oceanic crustal associations. These large-scale blocks in the matrix of the Bornova Flysch Zone are mostly defined as limestone, basalt, serpentinite and radiolarian cherts. In this study, granitic bodies, situated in the Bornova Flysch Zone, named as Kavacik leucogranite is examined for the first time, in terms its geological features and its U-Pb zircon crystallization ages. Kavacik leucogranite displays a typical granitic texture and its composition indicates ranging between granitic to granodioritic in composition with lack of mafic minerals. The geochemical features of the granite indicate the I-type and subalkaline nature of the granitic body. The geochemical signatures of the Kavacik granite points out Volcanic Arc Granitoids as similarly seen in Karaburun granite. U-Pb zircon LA ages were also obtained from the Kavacik granite ranging between 224.5 ± 2.0 Ma and 230.0 ± 2.8 Ma. Early Triassic zircon ages are also previously observed in the Karaburun Peninsula (Karaburun Granite) and the Menderes Massif (Odemis-Kiraz Submassif). The initial geological boundary relation of the Kavacik Leucogranite is not clear in the field and likely displays tectonic boundary features in the matrix of the Bornova Flysch Zone. Overall, the geochemical features of the Kavacik leucogranite and similar leucomagmatic bodies in the Western Anatolia points out the subduction-related tectonic setting is favorable during the Triassic time.

  20. Planktonic and benthic foraminiferal biostratigraphy of the Middle Eocene–Lower Miocene successions from the Sivas Basin (Central Anatolia, Turkey

    Directory of Open Access Journals (Sweden)

    Hakyemez Aynur

    2016-02-01

    Full Text Available Planktonic and benthic foraminifera are described from the Middle Eocene-Lower Miocene successions in the Sivas Basin, Central Anatolia. An integrated foraminiferal zonation provides new age assignments in terms of a great number of taxa for the studied sections. Four biostratigraphical intervals are first recorded based on the concurrent ranges of sporadically occurring but well preserved planktonic foraminiferal assemblages. The first interval characterized by the co-occurrences of Acarinina bullbrooki, Truncorotaloides topilensis and Turborotalia cerroazulensis is referable to the E11 Zone of late Lutetian–early Bartonian. An assemblage yielding Paragloborotalia opima accompanied by Globigerinella obesa forms a basis for the late Chattian O5 Zone. The successive interval corresponds to the late Chattian O6 Zone indicated by the presence of Globigerina ciperoensis and Globigerinoides primordius along with the absence of Paragloborotalia opima. The early Aquitanian M1 Zone can be tentatively defined based mainly on the assemblage of Globigerina, Globigerinella, Globoturborotalita and Tenuitella. The biostratigraphical data obtained from the benthic foraminifera assign the studied sections to the SBZ 21–22, SBZ 23 and SBZ 24 ranging in age from Rupelian to Aquitanian. The SBZ 23 and 24 are well constrained biozones by the occurrences of Miogypsinella complanata and Miogypsina gunteri, respectively, whereas the SBZ 21–22 defined by nummulitids and lepidocylinids in the Tethyan Shallow Benthic Zonation is characterized dominantly by peneroplids, soritids and miliolids in the studied sections. Benthic foraminiferal assemblages suggest different paleoenvironments covering lagoon, algal reef and shallow open marine whereas planktonic foraminifera provides evidence for relatively deep marine settings on the basis of assemblages characterized by a mixture of small-sized simple and more complex morphogroups indicative for intermediate depths of

  1. Identifying the Volcanic Eruption Depicted in a Neolithic Painting at Çatalhöyük, Central Anatolia, Turkey

    Science.gov (United States)

    Schmitt, Axel K.; Danišík, Martin; Aydar, Erkan; Şen, Erdal; Ulusoy, İnan; Lovera, Oscar M.

    2014-01-01

    A mural excavated at the Neolithic Çatalhöyük site (Central Anatolia, Turkey) has been interpreted as the oldest known map. Dating to ∼6600 BCE, it putatively depicts an explosive summit eruption of the Hasan Dağı twin-peaks volcano located ∼130 km northeast of Çatalhöyük, and a birds-eye view of a town plan in the foreground. This interpretation, however, has remained controversial not least because independent evidence for a contemporaneous explosive volcanic eruption of Hasan Dağı has been lacking. Here, we document the presence of andesitic pumice veneer on the summit of Hasan Dağı, which we dated using (U-Th)/He zircon geochronology. The (U-Th)/He zircon eruption age of 8.97±0.64 ka (or 6960±640 BCE; uncertainties 2σ) overlaps closely with 14C ages for cultural strata at Çatalhöyük, including level VII containing the “map” mural. A second pumice sample from a surficial deposit near the base of Hasan Dağı records an older explosive eruption at 28.9±1.5 ka. U-Th zircon crystallization ages in both samples range from near-eruption to secular equilibrium (>380 ka). Collectively, our results reveal protracted intrusive activity at Hasan Dağı punctuated by explosive venting, and provide the first radiometric ages for a Holocene explosive eruption which was most likely witnessed by humans in the area. Geologic and geochronologic lines of evidence thus support previous interpretations that residents of Çatalhöyük artistically represented an explosive eruption of Hasan Dağı volcano. The magmatic longevity recorded by quasi-continuous zircon crystallization coupled with new evidence for late-Pleistocene and Holocene explosive eruptions implicates Hasan Dağı as a potential volcanic hazard. PMID:24416270

  2. The Cooking Effect on Two Edible Mushrooms in Anatolia: Fatty Acid Composition, Total Bioactive Compounds, Antioxidant and Anticholinesterase Activities

    Directory of Open Access Journals (Sweden)

    Mehmet Öztürk

    2014-03-01

    Full Text Available The effects of baking practices on the fatty acid and bioactivity of edible mushrooms; namely, Lactarius delicious and Ramaria flava, naturally growing in Anatolia were investigated. Each mushroom species was divided into two parts and one of the parts was baked. Both baked and unbaked materials were extracted with hexane and methanol, successively. The fatty acid contents of baked and unbaked extracts of both species were carried out by GC and GC-MS analytical techniques. In the unbaked extracts palmitic acid (9.7-14.43%, stearic acid (41.41-6.68%, oleic acid (25.94-47.12% and linoleic acid (22.85-9.78% were identified as major fatty acids, respectively. In the baked extracts, however, palmitic acid (7.92-19.12%, stearic acid (49.94-6.23%, oleic acid (18.07-45.13% and linoleic acid (23.36-9.25% were identified as major fatty acids, as well. The antioxidative effect of the extracts of baked and unbaked mushroom species was also determined by using four complimentary assays. In addition, the extracts and the major fatty acids were also evaluated for anticholinesterase activity against acetylcholinesterase (AChE and butyrylcholinesterase (BChE which are the chief enzymes of Alzheimer’s disease. The baked methanol extract of R. flava showed the highest activity in DPPH scavenging, ABTS scavenging and BChE assays, while the unbaked hexane extract of R. flava exhibited the best lipid peroxidation inhibition activity. In conclusion, baking proved to have influence in nutritional values and bioactivity properties of L. delicious and R. flava. The nutrient concentration and bioactivities of L. delicious were decreased when baked; however, baked R. flava proved to have higher nutrient concentrations and higher bioactivities than unbaked samples.

  3. Hydrogeological, Hydrogeochemical and Isotope Geochemical Features of the Geothermal Waters in Seferihisar and Environs, Western Anatolia, Turkey

    Science.gov (United States)

    Özgür, Nevzat; Aras Pala, Ebru; Degirmenci, Saliha

    2017-12-01

    The study area of Seferihisar is located within the Izmir-Ankara suture in the NW of the Menderes Massif in western Anatolia, Turkey. The Paleozoic metamorphic rocks of the Menderes Massif form the basement rocks in the area which are overlain by 760 m thick Izmir-flysch series consisting of metamorphic rocks, limestones and ultrabasic rocks tectonically. The Pliocene Bahçecik formation which consists of an alternation of conglomerates, sandstones, claystones, lignite and limestones and shows a thickness of 300 m overlies the (İzmir) flysch series discordantly. This is overlain by 430 m thick Yeniköy formation composed of conglomerates, sandstones, claystones and clayey limestones discordantly. The Miocene volcanic rocks of Cumaovası overlie the Yeniköy formation concordantly which are overlain by alluvium and travertine deposits. Geothermal waters which are observed in the localities of Tuzla, Cumalı, Doğanbey and Karakoç are associated with NE-SW trending faults in the area. The geothermal waters in the area are considered as Na-Cl or Na-Cl-HCO3 type waters. The geothermal waters of Seferihisar and environs are identified to be Na+K>Ca>Mg dominant cations and Cl>HCO3>SO4 dominant anions. According to the diagram of Na/100-K/100-√Mg, a certainly part of the thermal waters can be considered as equilibrated thermal waters during some waters are of immature waters. According to the results of geochemical thermometers, the reservoir temperatures of thermal waters range from 150 to 240°C. The δ2H values of thermal waters are between -13,3 to -31,9, while δ18O values range from -2,55 to -5,70. The tritium contents of thermal waters are between 13 to 64±10 TU.

  4. Molecular characterisation of radish cultivars

    Directory of Open Access Journals (Sweden)

    Sara Michelly Cruz

    Full Text Available The radish has been gaining importance in the Brazilian market due to its use as a green manure and cover crop, and also due to its potential for the production of biodiesel, however there are only two registered cultivars, which are morphologically very similar. Determination of genetic purity is a prerequisite in marketing seeds as it ensures uniformity of the crop and is important in breeding programs. The aim of this work therefore was to evaluate the similarity and genotype patterns which permit differentiation of the commercial radish cultivars IPR 116 and CATI AL-1000. In order to do this, isoenzyme electrophoretic patterns were analysed in dry seeds, soaked seeds, seedling leaves and young leaves; the isoenzymes used being: superoxide dismutase, catalase, esterase, glutamate-oxalocetate, malate dehydrogenase and isocitrate lyase. Thirty-seven RAPD primers and 10 ISSR primers in leaves of the CATI AL-1000 and IPR-116 cultivars were analysed. Among the isoenzymes under study, the most polymorphic were glutamate oxalocetate, malate dehydrogenase, esterase and superoxide dismutase, with the superoxide dismutase system giving the best characterisation for all stages of development. The catalase isoenzyme system did not make it possible to differentiate between cultivars at any stage of development, and isocitrate lyase was not revealed by the protocol used. In analysis of the markers, 27 RAPD primers and eight ISSR primers showed polymorphism. The results indicate that it is possible to determine reliable descriptors based on isoenzymes at different stages of development of the radish and with the use of RAPD and ISSR primers.

  5. Biochemical and immunohistochemical characterisation of mucins in ...

    African Journals Online (AJOL)

    Biochemical and immunohistochemical characterisation of mucins in 8 cases of colonic disease - a pilot study. N Chirwa, A Mall, M Tyler, B Kavin, P Goldberg, JEJ Krige, Z Lotz, D Khan, D Govender, A Hunter ...

  6. Molecular weight characterisation of synthetic polymers

    CERN Document Server

    Holding, Steve R

    1995-01-01

    The report comprises a state-of-the-art overview of the subject of molecular weight characterisation, supported by an extensive, indexed bibliography. The bibliography contains over 400 references and abstracts, compiled from the Polymer Library.

  7. Characterisation and quantification of liposome-type nanoparticles in a beverage matrix using hydrodynamic chromatography and MALDI–TOF mass spectrometry

    NARCIS (Netherlands)

    Helsper, J.P.F.G.; Peters, R.J.B.; Brouwer, L.; Weigel, S.

    2013-01-01

    This paper describes the characterisation of liposome-type nanoparticles (NPs) dispersed in a beverage matrix. Characterisation is based on a two-step procedure: first, liposomes are separated on the basis of size in the nanometre range by use of hydrodynamic chromatography (HDC); second, chemical

  8. The UNEP/SETAC recommended characterisation factors for human health and aquatic ecotoxicity: results and future

    DEFF Research Database (Denmark)

    Rosenbaum, Ralph K.; Hauschild, Michael Zwicky; Bachmann, Till M.

    , called USEtox, to serve as a repository for recommended practice. USEtox is a parsimonious and transparent tool that currently provides human-health characterisation factors (CFs) for some 1000 chemicals and aquatic ecotoxicity CFs for more than 2000 substances. The accuracy of these factors relative...

  9. Detection and characterisation of radicals using electron paramagnetic resonance (EPR) spin trapping and related methods

    DEFF Research Database (Denmark)

    Davies, Michael Jonathan

    2016-01-01

    Electron paramagnetic resonance (EPR) spectroscopy (also known as electron spin resonance, ESR, or electron magnetic resonance, EMR, spectroscopy) is often described as the “gold standard” for the detection and characterisation of radicals in chemical, biological and medical systems. The article...

  10. Synthesis and characterisation of Cu (II), Ni (II), Mn (II), Zn (II) and ...

    Indian Academy of Sciences (India)

    Home; Journals; Journal of Chemical Sciences; Volume 113; Issue 3. Synthesis and characterisation of Cu(II), Ni(II), Mn(II), Zn(II) and VO(II) Schiff base complexes derived from o-phenylenediamine and acetoacetanilide. N Raman Y Pitchaikani Raja A Kulandaisamy. Inorganic Volume 113 Issue 3 June 2001 pp 183-189 ...

  11. Tectonic evolution of the Cretaceous Ankara Ophiolitic Mélange during the Late Cretaceous to pre-Miocene interval in Central Anatolia, Turkey

    Science.gov (United States)

    Rojay, Bora

    2013-04-01

    The chaotic tectonic belt, which is distinguished in northern Anatolia, is called the - Ankara Accretionary Complex - in the Ankara region, central Anatolia. The belt is differentiated into three imbricated tectonic subbelts, namely, pre-Triassic metamorphics, Mélange with calcareous blocks and Cretaceous mélange with ophiolitic blocks (Ankara Ophiolitic Mélange). The Ankara Ophiolitic Mélange (AOM) is a chaotic tectono-sedimentary mixture made up of detached blocks of Mesozoic ultramafic rocks, Cretaceous pillow basalts, Cretaceous radiolarites, Upper Jurassic-Cretaceous limestones and closely associated Upper Cretaceous basinal sequences. The detached and dismembered blocks lie within a highly sheared and brecciated ophiolitic detrital matrix or a block-on-block to sheared sedimentary matrix that varies along the mélange belt. Cenomanian-Turonian and Turonian-Santonian trench-linked basin deposits onlap the Cenomanian sedimentary and Cretaceous ophiolitic mélanges. The elements of the ophiolitic mélange were comixed as a result of tectonic recycling in the accretionary wedge. The belt is unconformably overlain by Campanian-Maastrichtian to Paleogene accretionary fore-arc basin deposits. The AOM developed in an accretionary wedge setting in which oceanic leading edge of the Anatolide-Tauride platform subducted toward north during the post-Barremian-pre-Campanian period. The AOM emplaced episodically and progressively as a result of in thrust tectonics with vergence ranging from SSW to SE during the post-Turonian to pre-Miocene in the Ankara terrain.

  12. The evolution of the Cappadocia Geothermal Province, Anatolia (Turkey): geochemical and geochronological evidence

    Science.gov (United States)

    Şener, M. Furkan; Şener, Mehmet; Uysal, I. Tonguç

    2017-12-01

    Cappadocia Geothermal Province (CGP), central Turkey, consists of nine individual geothermal regions controlled by active regional fault systems. This paper examines the age dating of alteration minerals and the geochemistry (trace elements and isotopes) of the alteration minerals and geothermal waters, to assess the evolution of CGP in relation to regional tectonics. Ar-Ar age data of jarosite and alunite show that the host rocks were exposed to oxidizing conditions near the Earth's surface at about 5.30 Ma. Based on the δ18O-δD relationhip, water samples had a high altitude meteoric origin. The δ34S values of jarosite and alunite indicate that water samples from the southern part of the study area reached the surface after circulation through volcanic rocks, while northern samples had traveled to the surface after interacting with evaporates at greater depths. REY (rare earth elements and yttrium) diagrams of alteration minerals (especially illite, jarosite and alunite) from rock samples, taken from the same locations as the water samples, display a similar REY pattern to water samples. This suggests that thermal fluids, which reached the surface along a fault zone and caused the mineral alteration in the past, had similar chemical composition to the current geothermal water. The geothermal conceptual model, which defines a volcanically heated reservoir and cap rocks, suggests there are no structural drawbacks to the use of the CGP geothermal system as a resource. However, fluid is insufficient to drive the geothermal system as a result of scanty supply of meteoric water due to evaporation significantly exceeding rainfall.

  13. Materials Characterisation of Glass/epoxy Composites - Focusing on Process Conditions

    DEFF Research Database (Denmark)

    Jakobsen, Johnny; Lyckegaard, Anders; Jensen, Erik Appel

    2013-01-01

    Predicting the behaviour of fibre reinforced polymer composites taking the process conditions into account involves advanced modelling techniques and an extensive materials characterisation. The materials characterisation of a chopped strand mat glass/epoxy composite has been the focus...... of this paper. The resin gelation has been investigated with two different experimental setups and the measurements are compared. A thermo-chemical material model for the in-plane Young’s modulus has been developed based on multiple DMA experiments and further presented in a modulus......-temperature-transformation diagram. The viscoelastic behaviour for the fully cured composite materials was investigated and a master curve of the relaxation modulus was established....

  14. Preparation and characterisation of ammonium plutonium (III) sulphate tetrahydrate NH4Pu(SO4)2.4H2O (Preprint No. AL.05)

    International Nuclear Information System (INIS)

    Iyer, P.N.; Natarajan, P.R.

    1989-01-01

    Ammonium plutonium (III) sulphate tetrahydrate has been prepared and characterised by chemical and thermal analysis. X-ray powder diffraction studies showed the compound to be isostructural to ammonium samarium sulphate tetrahydrate. (author)

  15. Kinematics of Post-Collisional Extensional Tectonics and Exhumation of the Menderes Massif in the Western Anatolia Extended Terrane, Turkey

    Science.gov (United States)

    Cemen, I.; Catlos, E. J.; Diniz, E.; Gogus, O.; Ozerdem, C.; Baker, C.; Kohn, M. J.; Goncuoglu, C.; Hancer, M.

    2006-12-01

    The Western Anatolia Extended Terrane in Turkey is one of the best-developed examples of post-collisional extended terranes and contains one of the largest metamorphic core complexes in the world, the Menderes massif. It has experienced a series of continental collisions from the Late Cretaceous to the Eocene as the Neotethys Ocean closed and the Izmir-Ankara-Erzincan suture zone was formed. Based our field work and monazite ages, we suggest that the north-directed postcollisional Cenozoic extension in the region is the product of three consecutive, uninterrupted stages, triggered by three different mechanisms. The first stage was initiated about 30 Ma ago, in the Oligocene by the Orogenic Collapse the thermally weakened continental crust along the north-dipping Southwest Anatolian shear zone. The shear zone was formed as an extensional simple-shear zone with listric geometry at depth and exhibits predominantly normal- slip along its southwestern end. But, it becomes a high-angle oblique-slip shear zone along its northeastern termination. Evidence for the presence of the shear zone includes (1) the dominant top to the north-northeast shear sense indicators throughout the Menderes massif, such as stretching lineations trending N10E to N30E; and (2) a series of Oligocene extensional basins located adjacent to the shear zone that contain only carbonate and ophiolitic rock fragments, but no high grade metamorphic rock fragments. During this stage, erosion and extensional unroofing brought high-grade metamorphic rocks of the central Menderes massif to the surface by the early Miocene. The second stage of the extension was triggered by subduction roll-back and associated back-arc extension in the early Miocene and produced the north-dipping Alasehir and the south-dipping Buyuk Menderes detachments of the central Menderes massif and the north-dipping Simav detachment of the northern Menderes massif. The detachments control the Miocene sedimentation in the Alasehir, Buyuk

  16. Jurassic-Paleogene intra-oceanic magmatic evolution of the Ankara Mélange, North-Central Anatolia, Turkey

    Science.gov (United States)

    Sarifakioglu, E.; Dilek, Y.; Sevin, M.

    2013-11-01

    Oceanic rocks in the Ankara Mélange along the Izmir-Ankara-Erzincan suture zone (IAESZ) in North-Central Anatolia include locally coherent ophiolite complexes (~179 Ma and ~80 Ma), seamount or oceanic plateau volcanic units with pelagic and reefal limestones (96.6 ± 1.8 Ma), metamorphic rocks with ages of 187.4 ± 3.7 Ma, 158.4 ± 4.2 Ma, and 83.5 ± 1.2 Ma, and subalkaline to alkaline volcanic and plutonic rocks of an island arc origin (~67-63 Ma). All but the arc rocks occur in a shaly-graywacke and/or serpentinite matrix, and are deformed by south-vergent thrust faults and folds that developed in the Middle to Late Eocene due to continental collisions in the region. Ophiolitic volcanic rocks have mid-ocean ridge (MORB) and island arc tholeiite (IAT) affinities showing moderate to significant LILE enrichment and depletion in Nb, Hf, Ti, Y and Yb, which indicate the influence of subduction-derived fluids in their melt evolution. Seamount/oceanic plateau basalts show ocean island basalt (OIB) affinities. The arc-related volcanic rocks, lamprophyric dikes and syeno-dioritic plutons exhibit high-K shoshonitic to medium-to high-K calc-alkaline compositions with strong enrichment in LILE, REE and Pb, and initial ϵNd values between +1.3 and +1.7. Subalkaline arc volcanic units occur in the northern part of the mélange, whereas the younger alkaline volcanic rocks and intrusions (lamprophyre dikes and syeno-dioritic plutons) in the southern part. The Early to Late Jurassic and Late Cretaceous epidote-actinolite, epidote-chlorite and epidote-glaucophane schists represent the metamorphic units formed in a subduction channel in the Northern Neotethys. The Middle to Upper Triassic neritic limestones spatially associated with the seamount volcanic rocks indicate that the Northern Neotethys was an open ocean with its MORB-type oceanic lithosphere by the Early Triassic. The Latest Cretaceous-Early Paleocene island arc volcanic, dike and plutonic rocks with

  17. Jurassic-Paleogene intraoceanic magmatic evolution of the Ankara Mélange, north-central Anatolia, Turkey

    Science.gov (United States)

    Sarifakioglu, E.; Dilek, Y.; Sevin, M.

    2014-02-01

    Oceanic rocks in the Ankara Mélange along the Izmir-Ankara-Erzincan suture zone (IAESZ) in north-central Anatolia include locally coherent ophiolite complexes (∼ 179 Ma and ∼ 80 Ma), seamount or oceanic plateau volcanic units with pelagic and reefal limestones (96.6 ± 1.8 Ma), metamorphic rocks with ages of 256.9 ± 8.0 Ma, 187.4 ± 3.7 Ma, 158.4 ± 4.2 Ma, and 83.5 ± 1.2 Ma indicating northern Tethys during the late Paleozoic through Cretaceous, and subalkaline to alkaline volcanic and plutonic rocks of an island arc origin (∼ 67-63 Ma). All but the arc rocks occur in a shale-graywacke and/or serpentinite matrix, and are deformed by south-vergent thrust faults and folds that developed in the middle to late Eocene due to continental collisions in the region. Ophiolitic volcanic rocks have mid-ocean ridge (MORB) and island arc tholeiite (IAT) affinities showing moderate to significant large ion lithophile elements (LILE) enrichment and depletion in Nb, Hf, Ti, Y and Yb, which indicate the influence of subduction-derived fluids in their melt evolution. Seamount/oceanic plateau basalts show ocean island basalt (OIB) affinities. The arc-related volcanic rocks, lamprophyric dikes and syenodioritic plutons exhibit high-K shoshonitic to medium- to high-K calc-alkaline compositions with strong enrichment in LILE, rare earth elements (REE) and Pb, and initial ɛNd values between +1.3 and +1.7. Subalkaline arc volcanic units occur in the northern part of the mélange, whereas the younger alkaline volcanic rocks and intrusions (lamprophyre dikes and syenodioritic plutons) in the southern part. The late Permian, Early to Late Jurassic, and Late Cretaceous amphibole-epidote schist, epidote-actinolite, epidote-chlorite and epidote-glaucophane schists represent the metamorphic units formed in a subduction channel in the northern Neotethys. The Middle to Upper Triassic neritic limestones spatially associated with the seamount volcanic rocks indicate that the northern

  18. The structural elements and tectonics of the Lake Van basin (Eastern Anatolia) from multi-channel seismic reflection profiles

    Science.gov (United States)

    Toker, Mustafa; Sengor, A. M. Celal; Demirel Schluter, Filiz; Demirbag, Emin; Cukur, Deniz; Imren, Caner; Niessen, Frank; PaleoVan-Working Group

    2017-05-01

    This study analyzed multi-channel seismic reflection data from Lake Van, Eastern Anatolia, to provide key information on the structural elements, deformational patterns and overall tectonic structure of the Lake Van basin. The seismic data reveal three subbasins (the Tatvan, northern and Ahlat subbasins) separated by structural ridges (the northern and Ahlat ridges). The Tatvan basin is a tilted wedge-block in the west, it is a relatively undeformed and flat-lying deep basin, forming a typical example of strike-slip sedimentation. Seismic sections reveal that the deeper sedimentary sections of the Tatvan basin are locally folded, gently in the south and more intensely further north, suggesting a probable gravitational "wedge-block" instability, oblique to the northern margin. The northern subbasin, bounded by normal oblique faults, forms a basin-margin graben structure that is elongated in a northeast-southwest direction. The east-west trending Ahlat ridge forms a fault-wedged sedimentary ridge and appears to offset by reverse oblique faults forming as a push-up rhomb horst structure. The Ahlat subbasin is a fault-wedged trough fill that is elongated in the west-east direction and appears as a horst-foot graben formed by the normal oblique faults. The northeast-southwest directed northern ridge is a faulted crestal terrace of a sublacustrine basement block. Its step-like morphology, in response to the downfaulting of the Tatvan basin, as well as its backthrusted appearance, indicates the normal oblique nature of the bounding faults. The lacustrine shelf and slope show distinctive stratigraphic features; progradational deltas, submerged fluvial channels, distorted and collapsed beddings and soft sediment deformation structures, characterizing a highly unstable nature of shelf caused by strong oblique faulting and related earthquakes. The faulting caused uplift of the Çarpanak spur zone, together with the northeastern Erek delta, deformation of deltaic structures

  19. Characterising exposure to PM aerosols for an epidemiological study

    Science.gov (United States)

    Viana, M.; Querol, X.; Alastuey, A.; Ballester, F.; Llop, S.; Esplugues, A.; Fernández-Patier, R.; García dos Santos, S.; Herce, M. D.

    Recent health studies evidence that epidemiological studies must be combined with accurate analyses of the physico-chemical properties of the particles, and vice versa, in order to determine the effects of atmospheric PM on human health. The present study focuses on the chemical characterisation of PM 10 and PM 2.5 aerosols, with the aim to characterise the exposure to this pollutant of the pregnant women in a cohort study in Valencia, Spain. PM sampling was carried out during five campaigns (1 month by trimester) between 2004 and 2005, when the women in the study were pregnant. Four sites were selected, representing a gradient of urban, metropolitan, suburban and rural environments. The study includes the determination of PM levels, major and trace elements, and 15 polycyclic aromatic hydrocarbons (PAHs). The results evidenced a marked gradient regarding PM levels from urban to rural sites, which was also observed for anthropogenic PM components (OM+EC, NO 3-, Fe, SO 42-, NO 3-, NH 4+) but not for elements of mineral origin (Al 2O 3, Ca, K, Mg). PAH levels were similar or slightly higher that those reported for other Spanish sites but lower than in Europe. Findings show that the relationship between exposure to PM and adverse health effects cannot be determined only by the study of PM levels; other parameters such as chemical and physical properties of the aerosols must also be taken into account. Results also allow evaluating the adequacy of central monitor measurements as proxies for actual exposure to local emissions (e.g., vehicular emissions), which are known to vary considerably with distance to the source. The sampling strategy used in this study, devised jointly by PM monitoring and epidemiology specialists could be considered a guideline for the design of air quality monitoring studies aimed at epidemiological analysis.

  20. Subduction Zone Configuration of Central and Eastern Anatolia since the Late Cretaceous: Insights from Sedimentary Basins in the Neotethyan Suture Zone

    Science.gov (United States)

    Gürer, D.; Van Hinsbergen, D. J. J.; Matenco, L.; Corfu, F.; Langereis, C. G.; Ozkaptan, M.

    2015-12-01

    Subduction and accretion of continental and Neotethyan oceanic crustal fragments during Africa-Europe convergence since the Mesozoic formed the Anatolian fold-and-thrust belt. Sedimentary basins overlying key locations of the resulting fold-thrust belt that was metamorphosed to varying grades, may help to quantitatively kinematically restore the subduction evolution, and to identify timing, directions and amounts of post-accretionary extension, shortening and strike-slip faulting. The Upper Cretaceous - Oligocene Ulukışla basin straddles ophiolites, underlain by the HT-LP metamorphic Kırşehir Block (KB) to its north, and the HP-LT Bolkardağ/Afyon zone (BA) to its south. At its southern margin a series of small-offset faults consistent with latest Cretaceous-Paleocene N-S extension, was contemporaneous with (presumably extensional) exhumation of BA. Close to the contact with KB, a series of large-offset listric normal faults compatible with E-W extension offsets sediments and the base of newly dated Paleocene volcanics, showing E-W extension simultaneous with N-S extension in the south, prevailing until at least 56 Ma. Subsequently, N-S directed contraction led to E-W striking folds and thrusts and back-thrusting of the BA over the Ulukisla basin, probably in Oligocene time, and coeval left lateral strike-slip motion along the Ecemiş fault (EF) at the eastern basin margin. We explain the interplay between two Late Cretaceous-Paleocene extension directions to result from interplay between N-S and E-W striking subduction segments in central and eastern Anatolia, respectively. The latter can be followed farther east towards the Bitlis. In addition, absence of a Kirsehir block in eastern Anatolia led to a much longer duration of subduction below the Pontides, throughout the Paleogene and perhaps until as young as the Middle Miocene, with a suture below the Sivas basin that covers the contact between the KB, the Pontides and the Taurides. We restore an amount of

  1. Production, characterisation and flocculation mechanism of ...

    African Journals Online (AJOL)

    Bioflocculant from marine Bacillus pumilus JX860616 was characterised and its flocculation mechanism determined. The bacterium was identified by 16S rRNA and the bioflocculant was obtained through solvent extraction after optimum medium composition and culture conditions were established. The physicochemical ...

  2. Agromorphological characterisation of Gboma eggplant, an ...

    African Journals Online (AJOL)

    Gboma (Solanum macrocarpon L.) is an important leafy and fruit vegetable in Ghana. Despite its nutritional and medicinal properties, and consumption by many ethnic groups in the country, the crop is underdeveloped. The objective of this study was to characterise diversity among local landraces of Solanum macrocarpon ...

  3. Evaluation and characterisation of sugar cane germplasm ...

    African Journals Online (AJOL)

    Thirty local sugar cane (Saccharum spp.) accessions were evaluated and characterised for smut (Ustilago scitammeaSyd.) resistance during four years under field conditions. The results showed that nine accessions, BD-07, KN-08, LS-01, OG-07, 0Y10, 0Y11, OY-16, OY-22 and OY-26, were resistant and had high brix ...

  4. Characterisation of fracture network and groundwater preferential ...

    African Journals Online (AJOL)

    Characterisation of fractured rocks and evaluation of fracture connectivity are essential for the study of subsurface flow and transport in fractured rock aquifers. In this study, we use a new method to present fracture networks and analyse the connectivity of the fractures, based on the technique of randomly-generated ...

  5. Characterisation of fracture network and groundwater preferential ...

    African Journals Online (AJOL)

    2014-03-18

    Mar 18, 2014 ... Characterisation of fractured rocks and evaluation of fracture connectivity are essential for the study of subsurface flow and transport in fractured rock aquifers. In this study, we use a new method to present fracture networks and analyse the connectivity of the fractures, based on the technique of ...

  6. Identification and Characterisation of Major Hydrocarbons in ...

    African Journals Online (AJOL)

    Identification and Characterisation of Major Hydrocarbons in Thermally Degraded Low Density Polyethylene Films. ... There were alkanes, alkenes, halogenated alkanes, and very few aromatics in the liquid product and, the hydrocarbons were observed to range between C10 - C27. The FTIR and GC-MS results show the ...

  7. Dynamic and Acoustic Characterisation of Automotive Wheels

    Directory of Open Access Journals (Sweden)

    Francesca Curà

    2004-01-01

    Full Text Available The subject of this paper is the dynamic and acoustic characterisation of an automotive wheel. In particular, an experimental research activity previously performed by the authors about the dynamic behaviour of automotive wheels has been extended to the acoustic field.

  8. Synthesis and characterisation of quinoline functionalised ...

    African Journals Online (AJOL)

    A series of quinoline based imidazolium salts were prepared and characterised as nucleophilic heterocyclic carbene (NHC) ligand precursors. The symmetrically saturated imidazolium salt prepared by ring closure of achiral tetradentate diquinolyl-diamine with triethyl orthoformate is a tridentate ligand and can function as ...

  9. Source Specific Quantification, Characterisation and Management of ...

    African Journals Online (AJOL)

    The most important aspect of solid waste management is the quantity and characteristics of waste to be managed. Lapai town lacks data on quantity of waste generated and their characteristics for efficient and sustainable waste management. This study is the quantification, characterisation and management of solid waste ...

  10. Characterisation and concentration profile of aluminium during ...

    African Journals Online (AJOL)

    An aluminium(Al) characterisation study was conducted at a surface water treatment plant (Buffalo Pound Water Treatment Plant (BPWTP) in Moose Jaw, Saskatchewan, Canada) to understand better the effect of alum coagulant on various Al fractions. The raw water source for BPWTP is Buffalo Pound Lake water. The Al ...

  11. Modelling and characterisation of transistors | Akande | Global ...

    African Journals Online (AJOL)

    Models and characterisation of active devices that control the flow of energy operating within and outside the active region of the operating domain are presented. Specifically, the incremental charge carrier and Ebers Moll models of the bipolar junction transistor are presented and the parameters of electrical behaviour of ...

  12. Characterisation of potential aquaculture pond effluents, and ...

    African Journals Online (AJOL)

    Conventional treatment of effluents from these small-scale, low-volume operations, which discharge relatively dilute effluents infrequently, might not be cost-effective. Keywords: aquaculture–environment interaction, earthen ponds, effluent characterisation, K-means clustering, t ilapia, water quality. African Journal of Aquatic ...

  13. isolation and characterisation of cryptococcus neoformans

    African Journals Online (AJOL)

    2014-08-01

    Aug 1, 2014 ... 91 No. 8 August 2014. ISOLATION AND CHARACTERISATION OF CRYPTOCOCCUS NEOFORMANS AND CRYPTOCOCCUS GATTII. FROM ENVIRONMENTAL .... parts and a single colony was seeded onto each part, it was covered with sterile .... cryptococcosis in Thailand. Yeast. 2004;21:809-12.

  14. Phenotypic characterisation and molecular polymorphism of ...

    African Journals Online (AJOL)

    The study of the phenotypic characterisation and molecular polymorphism of local chicken populations was carried out in Benin on 326 chickens of the Forest ecological area and 316 of the Savannah ecological area, all were 7 months old at least. The collection of blood for the molecular typing was achieved on 121 ...

  15. Characterisation of interfaces in nanocrystalline palladium

    Indian Academy of Sciences (India)

    R. Narasimhan (Krishtel eMaging) 1461 1996 Oct 15 13:05:22

    Characterisation of interfaces in nanocrystalline palladium. 49. Interface structures in nanocrystalline materials have been the subject of research from the very beginning. The first indication that the structure of grain boundaries in nanocrystalline materials was different was from the X-ray diffraction (XRD) studies of Zhu et al ...

  16. Characterisations of Intersection Graphs by Vertex Orderings

    OpenAIRE

    Wood, David R.

    2004-01-01

    Characterisations of interval graphs, comparability graphs, co-comparability graphs, permutation graphs, and split graphs in terms of linear orderings of the vertex set are presented. As an application, it is proved that interval graphs, co-comparability graphs, AT-free graphs, and split graphs have bandwidth bounded by their maximum degree.

  17. Characterising and modelling extended conducted electromagnetic emission

    CSIR Research Space (South Africa)

    Grobler, Inus

    2013-06-01

    Full Text Available to reduce conducted EMI, such as phase dithering, were also analysed. Circuit layout high frequency effects as well as high frequency impedances of the power components were characterised. At first, a trapezoidal noise source and lumped element noise path...

  18. Phenotypic characterisation and molecular polymorphism of ...

    African Journals Online (AJOL)

    PRECIOUS

    2010-01-18

    Jan 18, 2010 ... The study of the phenotypic characterisation and molecular polymorphism of local chicken populations was carried out in Benin on 326 chickens of the Forest ecological area and 316 of the Savannah ecological area, all were 7 months old at least. The collection of blood for the molecular typing was.

  19. Characterisation of childhood and adolescence accidental fatalities ...

    African Journals Online (AJOL)

    Background: Accidental death in childhood and adolescence is posing a public health problem in Nigeria, as most of these deaths were not caused by the victims. There is need to research into the pattern and circumstances surrounding the death. Aim: To characterise and study accidental deaths in childhood and ...

  20. Synthesis, characterisation, nuclease and cytotoxic activity of ...

    Indian Academy of Sciences (India)

    GULZAR A BHAT

    2018-02-07

    Feb 7, 2018 ... Synthesis, characterisation, nuclease and cytotoxic activity of phosphate-free and phosphate-containing copper. 4 -(N-methylpyridinium)-2,2 :6 ,2 terpyridine complexes. GULZAR A BHATa, RAIHANA MAQBOOLb and RAMASWAMY MURUGAVELa,∗. aDepartment of Chemistry, Indian Institute of ...

  1. An experimental investigation to characterise soil macroporosity ...

    Indian Academy of Sciences (India)

    An experimental investigation to characterise soil macroporosity under different land use and land covers of northeast India. Sangeeta Shougrakpam1, Rupak Sarkar2 and Subashisa Dutta. 1,∗. 1. Department of Civil Engineering, Indian Institute of Technology Guwahati,. North Guwahati, Assam 781 039, India. 2. Faculty of ...

  2. Characterising Castrate Tolerant Prostate Cancer Cells

    OpenAIRE

    ASHLEE KATE CLARK

    2017-01-01

    Prostate cancer is a prevalent disease in aging males. This thesis explores prostate cancer cells that escape current therapy and give rise to end-stage disease. Using sophisticated experimental approaches, this important cancer cell population was identified and characterised in human prostate cancer tissues.  Our discoveries will eventually lead to improved cancer treatments for men with prostate cancer.

  3. Detection and identification of cutaneous leishmaniasis isolates by culture, Polymerase chain reaction and sequence analyses in Syrian and Central Anatolia patients.

    Science.gov (United States)

    Beyhan, Yunus E; Karakus, Mehmet; Karagoz, Alper; Mungan, Mesut; Ozkan, Aysegul T; Hokelek, Murat

    2017-09-01

    To characterize the cutaneous leishmaniasis (CL) isolates of Syrian and Central Anatolia patients at species levels. Methods: Skin scrapings of 3 patients (2 Syrian, 1 Turkish) were taken and examined by direct examination, culture in Novy-MacNeal-Nicole (NNN) medium, internal transcribed spacer polymerase chain reaction and sequence analysis (PCR). Results:According to microscopic examination, culture and PCR methods, 3 samples were detected positive. The sequencing results of all isolates in the study were identified as Leishmania tropica. The same genotypes were detected in the 3 isolates and nucleotide sequence submitted into GenBank with the accession number: KP689599. Conclusion: This finding could give information about the transmission of CL between Turkey and Syria. Because of the Syrian civil war, most of the Syrian citizens circulating in Turkey and different part of Europe, this can be increase the risk of spreading the disease. So, prevention measurements must be taken urgently.

  4. Impact of the ATATÜRK DAM Lake on Agro-Meteorological Aspects of the Southeastern Anatolia Region Using Remote Sensing and GIS Analysis

    Science.gov (United States)

    Ozcan, O.; Bookhagen, B.; Musaoglu, N.

    2012-07-01

    The Atatürk Dam is the fourth largest clay-cored rock fill dam in the world. It was constructed on the Euphrates River located in semi-arid Southeastern Turkey in the 1980s as the central component of a large-scale regional development project for the Southeastern Anatolia region (referred to as GAP). The construction began in 1983 and was completed in 1990. The dam and the hydroelectric power plant, which went into service after filling up the reservoir was accomplished in 1992. The Atatürk Dam, which has a height of 169 m, a total storage capacity of 48.7 million m3, and a surface area of about 817 km2 plays an important role in the development of Turkey's energy and agriculture sectors. In this study, the spatial and temporal impacts of the Atatürk Dam on agro-meteorological aspects of the Southeastern Anatolia region have been investigated. Change detection and environmental impacts due to water-reserve changes in Atatürk Dam Lake have been determined and evaluated using multi-temporal Landsat satellite imageries and meteorological datasets within a period of 1984 to 2011. These time series have been evaluated for three time periods. Dam construction period constitutes the first part of the study. Land cover/use changes especially on agricultural fields under the Atatürk Dam Lake and its vicinity have been identified between the periods of 1984 to 1992. The second period comprises the 10-year period after the completion of filling up the reservoir in 1992. At this period, Landsat and meteorological time-series analyses are examined to assess the impact of the Atatürk Dam Lake on selected irrigated agricultural areas. For the last 9-year period from 2002 to 2011, the relationships between seasonal water-reserve changes and irrigated plains under changing climatic factors primarily driving vegetation activity (monthly, seasonal, and annual fluctuations of rainfall rate, air temperature, humidity) on the watershed have been investigated using a 30-year

  5. IMPACT OF THE ATATÜRK DAM LAKE ON AGRO-METEOROLOGICAL ASPECTS OF THE SOUTHEASTERN ANATOLIA REGION USING REMOTE SENSING AND GIS ANALYSIS

    Directory of Open Access Journals (Sweden)

    O. Ozcan

    2012-07-01

    Full Text Available The Atatürk Dam is the fourth largest clay-cored rock fill dam in the world. It was constructed on the Euphrates River located in semi-arid Southeastern Turkey in the 1980s as the central component of a large-scale regional development project for the Southeastern Anatolia region (referred to as GAP. The construction began in 1983 and was completed in 1990. The dam and the hydroelectric power plant, which went into service after filling up the reservoir was accomplished in 1992. The Atatürk Dam, which has a height of 169 m, a total storage capacity of 48.7 million m3, and a surface area of about 817 km2 plays an important role in the development of Turkey's energy and agriculture sectors. In this study, the spatial and temporal impacts of the Atatürk Dam on agro-meteorological aspects of the Southeastern Anatolia region have been investigated. Change detection and environmental impacts due to water-reserve changes in Atatürk Dam Lake have been determined and evaluated using multi-temporal Landsat satellite imageries and meteorological datasets within a period of 1984 to 2011. These time series have been evaluated for three time periods. Dam construction period constitutes the first part of the study. Land cover/use changes especially on agricultural fields under the Atatürk Dam Lake and its vicinity have been identified between the periods of 1984 to 1992. The second period comprises the 10-year period after the completion of filling up the reservoir in 1992. At this period, Landsat and meteorological time-series analyses are examined to assess the impact of the Atatürk Dam Lake on selected irrigated agricultural areas. For the last 9-year period from 2002 to 2011, the relationships between seasonal water-reserve changes and irrigated plains under changing climatic factors primarily driving vegetation activity (monthly, seasonal, and annual fluctuations of rainfall rate, air temperature, humidity on the watershed have been investigated

  6. Detection and identification of cutaneous leishmaniasis isolates by culture, Polymerase chain reaction and sequence analyses in Syrian and Central Anatolia patients

    Directory of Open Access Journals (Sweden)

    Yunus E. Beyhan

    2017-09-01

    Full Text Available Objectives: To characterize the cutaneous leishmaniasis (CL isolates of Syrian and Central Anatolia patients at species levels. Methods: Skin scrapings of 3 patients (2 Syrian, 1 Turkish were taken and examined by direct examination, culture in Novy-MacNeal-Nicole (NNN medium, internal transcribed spacer polymerase chain reaction and sequence analysis (PCR. Results:According to microscopic examination, culture and PCR methods, 3 samples were detected positive. The sequencing results of all isolates in the study were identified as Leishmania tropica. The same genotypes were detected in the 3 isolates and nucleotide sequence submitted into GenBank with the accession number: KP689599. Conclusion: This finding could give information about the transmission of CL between Turkey and Syria. Because of the Syrian civil war, most of the Syrian citizens circulating in Turkey and different part of Europe, this can be increase the risk of spreading the disease. So, prevention measurements must be taken urgently.

  7. THE HELPS WHICH WERE MADE BY THE RED CRESCENT IN ANATOLIA AND GREECE TO THE TURKS AND GREEK PRISONERS IN THE PERIOD OF THE NATIONAL STRUGGLE / MILLI MÜCADELE DÖNEMINDE HILAL-I AHMER CEMIYETI’NIN ANADOLU VE YUNANISTAN’DAKI TÜRK VE YUNAN ESIRLERINE YAPTIĞI YARDIMLAR

    Directory of Open Access Journals (Sweden)

    Dr. Erol KAYA

    2008-05-01

    Full Text Available It became mutually the prisoners of war to the Grek and Turkishunions fighting in Anatolia during the First World War. It was helped in thedifferent was both The Grek prisoners in Anatolia and The Turkish prisonersin Greece by The Red Crescent. These helpings were rather important fromthe point of view of improvement of the positions of The Turkish prisoners inGrece especially.

  8. Characterisation of carbon nanotubes in the context of toxicity studies

    Science.gov (United States)

    Berhanu, D.; Dybowska, A.; Misra, S.K.; Stanley, C.J.; Ruenraroengsak, P.; Boccaccini, A.R.; Tetley, T.D.; Luoma, S.N.; Plant, J.A.; Valsami-Jones, E.

    2009-01-01

    Nanotechnology has the potential to revolutionise our futures, but has also prompted concerns about the possibility that nanomaterials may harm humans or the biosphere. The unique properties of nanoparticles, that give them novel size dependent functionalities, may also have the potential to cause harm. Discrepancies in existing human health and environmental studies have shown the importance of good quality, well-characterized reference nanomaterials for toxicological studies. Here we make a case for the importance of the detailed characterization of nanoparticles, using several methods, particularly to allow the recognition of impurities and the presence of chemically identical but structurally distinct phases. Methods to characterise fully, commercially available multi-wall carbon nanotubes at different scales, are presented. ?? 2009 Berhanu et al; licensee BioMed Central Ltd.

  9. Ion beam induced luminescence characterisation of CVD diamond films

    Energy Technology Data Exchange (ETDEWEB)

    Bettiol, A.A.; Gonon, P.; Jamieson, D.N. [Melbourne Univ., Parkville, VIC (Australia). School of Physics

    1996-12-31

    The characterisation of the band structure properties of materials and devices by ion microprobe techniques has been made possible at the Melbourne MeV ion microprobe facility with the development of Ion Beam Induced Luminescence (IBIL). A number of diamond films grown by Microwave Plasma Chemical Vapour Deposition (MPCVD) on silicon substrates are analysed. A preliminary study of the luminescence properties of these samples has revealed information not previously obtainable via traditional microprobe techniques. The optical effects of incorporating dopants during the deposition process is determined using IBIL. The presence of trace element impurities introduced during growth is examined by Particle Induced X-ray Emission (PIXE), and a measurement of the film thickness is made using Rutherford Backscattering Spectrometry (RBS). 7 refs., 2 figs.

  10. Jurassic–Paleogene intraoceanic magmatic evolution of the Ankara Mélange, north-central Anatolia, Turkey

    Directory of Open Access Journals (Sweden)

    E. Sarifakioglu

    2014-02-01

    Full Text Available Oceanic rocks in the Ankara Mélange along the Izmir–Ankara–Erzincan suture zone (IAESZ in north-central Anatolia include locally coherent ophiolite complexes (~ 179 Ma and ~ 80 Ma, seamount or oceanic plateau volcanic units with pelagic and reefal limestones (96.6 ± 1.8 Ma, metamorphic rocks with ages of 256.9 ± 8.0 Ma, 187.4 ± 3.7 Ma, 158.4 ± 4.2 Ma, and 83.5 ± 1.2 Ma indicating northern Tethys during the late Paleozoic through Cretaceous, and subalkaline to alkaline volcanic and plutonic rocks of an island arc origin (~ 67–63 Ma. All but the arc rocks occur in a shale–graywacke and/or serpentinite matrix, and are deformed by south-vergent thrust faults and folds that developed in the middle to late Eocene due to continental collisions in the region. Ophiolitic volcanic rocks have mid-ocean ridge (MORB and island arc tholeiite (IAT affinities showing moderate to significant large ion lithophile elements (LILE enrichment and depletion in Nb, Hf, Ti, Y and Yb, which indicate the influence of subduction-derived fluids in their melt evolution. Seamount/oceanic plateau basalts show ocean island basalt (OIB affinities. The arc-related volcanic rocks, lamprophyric dikes and syenodioritic plutons exhibit high-K shoshonitic to medium- to high-K calc-alkaline compositions with strong enrichment in LILE, rare earth elements (REE and Pb, and initial εNd values between +1.3 and +1.7. Subalkaline arc volcanic units occur in the northern part of the mélange, whereas the younger alkaline volcanic rocks and intrusions (lamprophyre dikes and syenodioritic plutons in the southern part. The late Permian, Early to Late Jurassic, and Late Cretaceous amphibole-epidote schist, epidote-actinolite, epidote-chlorite and epidote-glaucophane schists represent the metamorphic units formed in a subduction channel in the northern Neotethys. The Middle to Upper Triassic neritic limestones spatially associated with the

  11. Oxygen and sulfur isotope geochemistry revealing a significant crustal signature in the genesis of the post-collisional granitoids in central Anatolia, Turkey

    Science.gov (United States)

    Boztuğ, Durmuş; Arehart, Greg B.

    2007-04-01

    Late Cretaceous granitoid rocks from central Anatolia comprise S-I-A-type plutons derived from the collisional stages of the Neo-Tethyan convergence system in central Turkey. These granitoids intrude the tectonic imbrication zone consisting of blocks of supra-subduction zone-type (SSZ-type) central Anatolian ophiolite and crustal metasediments which are present in the İzmir-Ankara-Erzincan suture zone. The plutons are overlain by Late Palaeocene-Early Eocene or younger detrital sediments. Granitoid formation is thought to be related to magma generation processes occurring in a post-collisional lithospheric detachment-related geodynamic setting that resulted from slab break-off or lithospheric delamination. Whole-rock S and quartz/feldspar O isotope data from these plutons yields a broad range of values, and both parameters indicate a nearly exclusively supracrustal origin for the S-type granites, as well as a significant crustal contribution in the genesis of the hybrid I-type and A-type granitoids. The more mafic I-type and A-type granitoid rocks of any given suite have lower S and O values, indicative of their larger degree of mantle component. The combined stable isotope geochemical compositions, when coupled with major, trace and REE geochemistry and regional geology, provide evidence that the significant crustal contribution originated from a metasomatized mantle layer which was affected by earlier SSZ-derived fluids, and then accreted into the subcontinental lithosphere as collision occurred. The partial melting of such a metasomatized mantle layer in a post-collisional extensional geodynamic setting, supplied either by the slab break-off or lithospheric delamination mechanisms, provided the significant crustal signature in the hybrid magmas of the Late Cretaceous I-type and A-type granitoids in central Anatolia, Turkey.

  12. Aksaray and Ecemis faults - Diapiric salt relationships: relevance to the hydrocarbon exploration in the Tuz Golu (Salt Lake) Basin, Central Anatolia, Turkey

    Energy Technology Data Exchange (ETDEWEB)

    Coskun, Bulent [Ankara Univ., Dept. of Geology, Tandogan (Turkey)

    2004-09-15

    Due to activity of the Aksaray and Ecemis Faults, volcanic intrusion and westward movement of the Anatolian plate, diapiric salt structures were occurred in the Tuz Golu (Salt Lake) basin in central Anatolia, Turkey. With the collisions of the Arabian and Anatolian plates during the late Cretaceous and Miocene times, prominent ophiolitic obduction occurred in the Pontides and Taurides along the North Anatolian Fault (NAF) and East Anatolian Fault (EAF). The NAF and EAF intersect each other in the Karliova region, in eastern Turkey. At this point, due to the northward movement of the Arabian plate in SE Turkey, the Anatolian plate shifted toward the west and south along the fault zones. The same geological tectonic model is proposed at the intersection point of the Aksaray Fault (AF) and Ecemis Fault (EF) in central Anatolia. The westward movement of the Anatolian plate between these two faults resulted in the formation of the diapiric salt structures, volcanic intrusions and overpressure zones in the study area. Paleogeological reconstructions of the Tuz Golu basin indicate that the salient positive structures in the basin were formed during late Eocene-Oligocene times. These structures, like the Yeniceoba-Bezirci and Karapinar-Kochisar trends, are oriented in a NW-SE or N-S directions between the Kirsehir and Sivrihisar-Bozdag massifs. The subsidence rate and Paleogeographic evolutions in the basin show that the southeastern sector of the Tuz Golu basin remained shallower relative to the central and northwestern regions. Based on the paleostructural, subsidence and geothermal reconstructions, it has been concluded that the oil generation and migration zones and geothermal trends are oriented in a NW-SE direction in the Tuz Golu basin. (Author)

  13. Dynamic characterisation of the specific surface area for fracture networks

    Science.gov (United States)

    Cvetkovic, V.

    2017-12-01

    One important application of chemical transport is geological disposal of high-level nuclear waste for which crystalline rock is a prime candidate for instance in Scandinavia. Interconnected heterogeneous fractures of sparsely fractured rock such as granite, act as conduits for transport of dissolved tracers. Fluid flow is known to be highly channelized in such rocks. Channels imply narrow flow paths, adjacent to essentially stagnant water in the fracture and/or the rock matrix. Tracers are transported along channelised flow paths and retained by minerals and/or stagnant water, depending on their sorption properties; this mechanism is critical for rocks to act as a barrier and ultimately provide safety for a geological repository. The sorbing tracers are retained by diffusion and sorption on mineral surfaces, whereas non-sorbing tracers can be retained only by diffusion into stagnant water of fractures. The retention and transport properties of a sparsely fractured rock will primarily depend on the specific surface area (SSA) of the fracture network which is determined by the heterogeneous structure and flow. The main challenge when characterising SSA on the field-scale is its dependence on the flow dynamics. We first define SSA as a physical quantity and clarify its importance for chemical transport. A methodology for dynamic characterisation of SSA in fracture networks is proposed that relies on three sets of data: i) Flow rate data as obtained by a flow logging procedure; ii) transmissivity data as obtained by pumping tests; iii) fracture network data as obtained from outcrop and geophysical observations. The proposed methodology utilises these data directly as well as indirectly through flow and particle tracking simulations in three-dimensional discrete fracture networks. The methodology is exemplified using specific data from the Swedish site Laxemar. The potential impact of uncertainties is of particular significance and is illustrated for radionuclide

  14. Fertiliser characterisation: Major, trace and rare earth elements

    International Nuclear Information System (INIS)

    Otero, N.; Vitoria, L.; Soler, A.; Canals, A.

    2005-01-01

    In recent years, there has been increasing concern regarding the chemical impact of agricultural activities on the environment so it is necessary to identify contaminants, and/or characterise the sources of contamination. In this study, a comprehensive chemical characterisation of 27 fertilisers of different types used in Spain has been conducted; major, minor and trace elements were determined, including rare earth elements. Results show that compound fertilisers used for fertigation or foliar application have low content of heavy metals, whereas fertilisers used for basal and top dressing have the highest content of both REE and other heavy metals. REE patterns of fertilisers have been determined in order for them to be used as tracers of fertilisers in future environmental studies. Furthermore in this work REE patterns of fertilisers are used as tracers of the source of phosphate in compound fertilisers, distinguishing between phosphorite and carbonatite derived fertilisers. Fertilisers from carbonatites have higher contents of REE, Sr, Ba and Th whereas fertilisers from phosphorites have higher contents of metals of environmental concern, such as Cd, U and As; and the sum of the heavy metals is higher. Some of the analysed fertilisers have Cd concentrations that exceed maximum values established in some countries and can be expected to produce long-term soil accumulation. Furthermore, other elements such as U, As and Cr are 10-50 times higher in concentration than those of Cd, but there is no legislation regarding them, therefore it is necessary to regulate fertiliser compositions in order to achieve environmental protection of soils and waters

  15. Modelling, fabrication and characterisation of THz fractal meta-materials

    DEFF Research Database (Denmark)

    Xiao, S.; Zhou, L.; Malureanu, Radu

    2011-01-01

    We present theoretical predictions, fabrication procedure and characterisation results of fractal metamaterials for the THz frequency range. The characterisation results match well the predicted response thus validating both the fabrication procedure as well as the simulation one. Such systems show...

  16. Material characterisation of nanowires with intrinsic stress

    Science.gov (United States)

    Mills, S.; Sader, J. E.; Boland, J. J.

    2017-09-01

    When fabricating nanowires (NWs) in a doubly-clamped beam configuration it is possible for a residual axial stress to be generated. Here, we show that material characterisation of metal and semiconductor NWs subjected to residual axial stress can be problematic. Benchmark measurements of the Young’s modulus of NWs are performed by sectioning a doubly-clamped NW into two cantilevered wires, eliminating residual axial stress. Use of models for doubly-clamped beams that incorporate the effects of residual stress are found to lead to ambiguity in the extracted Young’s modulus as a function of displacement fit range, even for NWs with no residual stress. This is due to coupling of bending and axial stress effects at small displacements, and the limited displacement range of force curves prior to fracture or plastic deformation. This study highlights the importance of fabricating metal and semiconductor NWs that exhibit little or no residual axial stress for materials characterisation.

  17. Preparation and characterisation of nevirapine oral nanosuspensions.

    Science.gov (United States)

    Raju, Anju; Reddy, A Jagdeesh; Satheesh, J; Jithan, A V

    2014-01-01

    The objective of this study was to prepare and characterise nevirapine nanosuspensions so as to improve the dissolution rate of nevirapine. Nevirapine is a nonnucleoside reverse transcriptase inhibitor of immunodeficiency virus type-1 and it is poorly water-soluble antiretroviral drug. The low solubility of nevirapine can lead to decreased and variable oral bioavailability. Nanosuspension can overcome the oral bioavailability problem of nevirapine. Nevirapine nanosuspensions were prepared using nanoedge method. The suspensions were stabilised using surfactants Lutrol F 127 or Poloxamer 407 and hydroxypropyl methyl cellulose. The nanosuspension was characterised for particle size, polydispersibility index, crystalline state, particle morphology, in vitro drug release and pharmacokinetics in rats after oral administration. The results support the claim for the preparation of nanosuspensions with enhanced solubility and bioavailability.

  18. Negative affect is associated with development and persistence of chemical intolerance

    DEFF Research Database (Denmark)

    Skovbjerg, Sine; Christensen, Karl Bang; Ebstrup, Jeanette Frost

    2015-01-01

    OBJECTIVE: Chemical intolerance (CI) is characterised by negative health effects attributed to a heightened responsiveness to common airborne chemicals. This longitudinal study explored the hypothesised role of negative affect in the development and persistence of CI in a general population...

  19. Immunoassays: biological tools for high throughput screening and characterisation of combinatorial libraries.

    Science.gov (United States)

    Taipa, M Angela

    2008-05-01

    In the demanding field of proteomics, there is an urgent need for affinity-catcher molecules to implement effective and high throughput methods for analysing the human proteome or parts of it. Antibodies have an essential role in this endeavour, and selection, isolation and characterisation of specific antibodies represent a key issue to meet success. Alternatively, it is expected that new, well-characterised affinity reagents generated in rapid and cost-effective manners will also be used to facilitate the deciphering of the function, location and interactions of the high number of encoded protein products. Combinatorial approaches combined with high throughput screening (HTS) technologies have become essential for the generation and identification of robust affinity reagents from biological combinatorial libraries and the lead discovery of active/mimic molecules in large chemical libraries. Phage and yeast display provide the means for engineering a multitude of antibody-like molecules against any desired antigen. The construction of peptide libraries is commonly used for the identification and characterisation of ligand-receptor specific interactions, and the search for novel ligands for protein purification. Further improvement of chemical and biological resistance of affinity ligands encouraged the "intelligent" design and synthesis of chemical libraries of low-molecular-weight bio-inspired mimic compounds. No matter what the ligand source, selection and characterisation of leads is a most relevant task. Immunological assays, in microtiter plates, biosensors or microarrays, are a biological tool of inestimable value for the iterative screening of combinatorial ligand libraries for tailored specificities, and improved affinities. Particularly, enzyme-linked immunosorbent assays are frequently the method of choice in a large number of screening strategies, for both biological and chemical libraries.

  20. Characterisation and surface reactions of iron oxides and fluorapatite in aqueous suspensions

    OpenAIRE

    Jarlbring, Mathias

    2004-01-01

    The final objective of this study is to produce chemical models of flotation- like systems, including oxidation products of magnetite (maghemite and hematite) together with apatite. This is started by investigating the acid base properties, surface complexation and surface characteristics of the systems hematite-H+ and maghemite-H+ (paper I), fluorapatite-OH- (paper II) and a mixed system of maghemite-fluorapatite-OH- (paper III). Synthetic minerals were prepared and characterised with BET, S...

  1. Characterisation of hydrogen and erbium in carbon layers fabricated by PACVD for optical applications

    Science.gov (United States)

    Macková, A.; Peřina, V.; Hnatowicz, V.; Nekvindová, P.; Prajzler, V.; Hüttel, I.; Špirková, J.

    2002-04-01

    Carbon films prepared by plasma assisted chemical vapor deposition were doped by laser active ion Er 3+. The characterisation of the layers was performed using Rutherford backscattering spectrometry and elastic recoil detection analysis. Optical properties of the waveguides were measured at 660 nm wave length using standard prism spectroscopy. The correlation between the layer composition and the content of incorporated erbium and layer optical properties shows very interesting aspects [SPIE 4281, San Jose (2001) 13].

  2. Evaluation of the radioactive waste characterisation at the Olkiluoto nuclear power plant

    International Nuclear Information System (INIS)

    Kekki, T.; Titta, A.

    2000-03-01

    The aim of this study is to evaluate the physical, chemical and radiological characterisation, handling and documentation of the radioactive waste packages to be disposed of in the VLJ-repository at the Olkiluoto NPP. A comparison with the current practices in Europe, based on information from Sweden, Spain and Czech Republic, is made. The report presents recommendations for STUK to harmonise the LILW waste management practises in Finland with those in Europe. (orig.)

  3. An elementary characterisation of sifted weights

    OpenAIRE

    Dostál, Matěj; Velebil, Jiří

    2014-01-01

    Sifted colimits (those that commute with finite products in sets) play a major role in categorical universal algebra. For example, varieties of (many-sorted) algebras are precisely the free cocompletions under sifted colimits of (many-sorted) Lawvere theories. Such a characterisation does not depend on the existence of finite products in algebraic theories, but on the above fact that these products commute with sifted colimits and another condition: finite products form a sound class of limit...

  4. Radiological characterisation experience with Magnox reactors

    International Nuclear Information System (INIS)

    Westall, Bill A.; Towton, Barbara

    2012-01-01

    At the end of generation, power reactors will be decommissioned. Whether decommissioning is prompt or deferred, knowledge of the radioactive inventory of plant and structures is needed to develop and underpin the decommissioning strategy. As decommissioning progresses the level of detail required for the radioactive inventory increases as more specific and detailed questions need answering. Failure to adequately characterise will result in increased costs and project overruns due to missing optimal solutions, over pessimistic assumptions or unforeseen problems and regulatory issues. Radiological characterisation for decommissioning of Magnox power stations in the UK has been in progress for over a quarter of a century. Firstly measurements and calculations were carried out to develop a strategy. These have been followed by measurements to determine radioactive inventories of waste streams and packages or to allow decontamination of structures and most recently for partial de-licensing of sites. Some examples of the work carried out for the Magnox stations will be given, ranging from the neutron activation calculations to estimate the radioactive inventory within a bio-shield and measurements to validate them. Various plant and structures where the radioactive inventory is due to contamination have been characterised by measurements and examples for boilers and cooling ponds will be discussed. Various routine and ad-hoc measurements and shielding assessments have been performed on waste forms to help satisfy conditions for acceptance for disposal or exemption, which will be reviewed. Finally the measurements for de-licensing and the successful application of Data Quality Objectives will be addressed. (authors)

  5. Characterisation of contamination migration in the workplace

    International Nuclear Information System (INIS)

    Boulaud, D.; Laborde, J.C.; Pourprix, M.

    1994-01-01

    The Institute for Nuclear Safety and Protection (IPSN) has developed a procedure for characterising airborne contamination between processes and the workplace in nuclear facilities. It was initially intended to use this process to validate operator choices concerning the monitoring of indoor air contamination (personnel monitoring, and environmental detection at fixed locations), but also to optimise the fundamental parameters which have a more or less direct influence on potential exposure of staff in the workplace (at the same time optimising the contamination source, close confinement, process ventilation and general ventilation). In practice, the methods used to obtain these expert appraisals were usually based on experiments carried out in situ: (i) characterisation of aerosol contamination by accurate measurement of the nature, concentration and particle size distribution at various locations; (ii) characterisation of the migration of contamination by precise measurement involving gas and/or particle tracing techniques. In parallel with these experiments, a considerable effort was made to develop and qualify computer codes capable of predicting or estimating the migration of contamination through complex ventilated areas, by means of both fluid mechanics and aerosol science. (Author)

  6. Characterisation of the ecotoxicity of hospital effluents: A review

    International Nuclear Information System (INIS)

    Orias, Frédéric; Perrodin, Yves

    2013-01-01

    The multiple activities that take place in hospitals (surgery, drug treatments, radiology, cleaning of premises and linen, chemical and biological analysis laboratories, etc.), are a major source of pollutant emissions into the environment (disinfectants, detergents, drug residues, etc.). Most of these pollutants can be found in hospital effluents (HWW), then in urban sewer networks and WWTP (weakly adapted for their treatment) and finally in aquatic environments. In view to evaluating the impact of these pollutants on aquatic ecosystems, it is necessary to characterise their ecotoxicity. Several reviews have focused on the quantitative and qualitative characterisation of pollutants present in HWW. However, none have focused specifically on the characterisation of their experimental ecotoxicity. We have evaluated this according to two complementary approaches: (i) a “substance” approach based on the identification of the experimental data in the literature for different substances found in hospital effluents, and on the calculation of their PNEC (Predicted Non Effect Concentration), (ii) a “matrix” approach for which we have synthesised ecotoxicity data obtained from the hospital effluents directly. This work first highlights the diversity of the substances present within hospital effluents, and the very high ecotoxicity of some of them (minimum PNEC observed close to 0,01 pg/L). We also observed that the consumption of drugs in hospitals was a predominant factor chosen by authors to prioritise the compounds to be sought. Other criteria such as biodegradability, excretion rate and the bioaccumulability of pollutants are considered, though more rarely. Studies of the ecotoxicity of the particulate phase of effluents must also be taken into account. It is also necessary to monitor the effluents of each of the specialised departments of the hospital studied. These steps is necessary to define realistic environmental management policies for hospitals

  7. Characterisation of the ecotoxicity of hospital effluents: A review

    Energy Technology Data Exchange (ETDEWEB)

    Orias, Frédéric; Perrodin, Yves

    2013-06-01

    The multiple activities that take place in hospitals (surgery, drug treatments, radiology, cleaning of premises and linen, chemical and biological analysis laboratories, etc.), are a major source of pollutant emissions into the environment (disinfectants, detergents, drug residues, etc.). Most of these pollutants can be found in hospital effluents (HWW), then in urban sewer networks and WWTP (weakly adapted for their treatment) and finally in aquatic environments. In view to evaluating the impact of these pollutants on aquatic ecosystems, it is necessary to characterise their ecotoxicity. Several reviews have focused on the quantitative and qualitative characterisation of pollutants present in HWW. However, none have focused specifically on the characterisation of their experimental ecotoxicity. We have evaluated this according to two complementary approaches: (i) a “substance” approach based on the identification of the experimental data in the literature for different substances found in hospital effluents, and on the calculation of their PNEC (Predicted Non Effect Concentration), (ii) a “matrix” approach for which we have synthesised ecotoxicity data obtained from the hospital effluents directly. This work first highlights the diversity of the substances present within hospital effluents, and the very high ecotoxicity of some of them (minimum PNEC observed close to 0,01 pg/L). We also observed that the consumption of drugs in hospitals was a predominant factor chosen by authors to prioritise the compounds to be sought. Other criteria such as biodegradability, excretion rate and the bioaccumulability of pollutants are considered, though more rarely. Studies of the ecotoxicity of the particulate phase of effluents must also be taken into account. It is also necessary to monitor the effluents of each of the specialised departments of the hospital studied. These steps is necessary to define realistic environmental management policies for hospitals

  8. Metals Characterisation by Facility Characterisation in support of Site Remediation and Decommissioning Projects

    International Nuclear Information System (INIS)

    Laurie, Gemma; Carroll, Megan

    2014-01-01

    Facility Characterisation (FC) is a technical organisation within Site Remediation and Decommissioning Projects (SR and DP). The department is focused on the delivery of characterisation projects across the entire Sellafield Site. A programme of characterisation has been executed by the Sellafield Ltd Facility Characterisation team to support the demolition and optimised waste routing of metal from projects across the Sellafield Site. Characterisation aims to maximise the quantity of metal for unrestricted release from the site in line with the fundamental principles of the waste hierarchy. Projects that this work has supported include: - Characterisation of Site Electrical Transformers A total of 10 electrical transformers from various locations across the Sellafield site were assessed against the Environmental Permitting Regulations (EPR) 2011 criteria and have been classified as Exempt (Out of scope of EPR), based on sampling and analysis Approximately 576 te of metal was classified as exempt (out of scope of EPR). This material will be processed via the metals team to a suitable scrap metal dealer. Classification as exempt, avoided sentencing of the metal via 'Segregated Services'. The metals types classified as part of these projects included 411 te of mild steel, 4 te of stainless steel and 161 te copper. Key challenges with these projects include the characterisation of the transformer internals based on sampling of the associated oil rather than sampling the metalwork. Also the external paint layers were found to be contaminated to greater than exemption limits. However bulk assessment of the metal with firmly adhered paint demonstrated exemption against RP89 to support smelting. - FHP Crane Wires - 3000 metres of stainless steel crane wire that was used as part of crane operations within the Fuel Handling Plant was classified as Exempt (Out of Scope of EPR) based on sampling and analysis. Justification to support the sentencing of future steel

  9. Radiographic evaluation of third-molar development in relation to the chronological age of Turkish children in the southwest Eastern Anatolia region.

    Science.gov (United States)

    Karataş, Orhan H; Öztürk, Fırat; Dedeoğlu, Numan; Çolak, Cemil; Altun, Oğuzhan

    2013-10-10

    To study the chronological age of third-molar mineralisation of Turkish children from the southwest Eastern Anatolia region, the Demirjian staging method was used to determine the stage of the mineralisation of four third molars (18, 28, 38 and 48) and to compare third-molar development by sex and age with the results of previous studies. The study comprised 832 Turkish children from the southwest Eastern Anatolia region aged 6-16 years based on radiological evidence from digital orthopantomograms. The mean age of the 832 patients was 11.03±1.98 years, with 424 males (mean age, 10.97±1.97) and 408 females (mean age, 11.09±2.00). The orthopantomograms were scored by two observers. The Wilcoxon matched-pairs signed-rank test used to assess intra- and inter-observer assessment revealed strong agreement between both observers' measurements. Statistical analysis of the association between sex and age was performed with the Mann-Whitney U-test and the Wilcoxon test. Regression analysis was performed to obtain regression formulae for calculating the dental and the chronological age. The statistical analysis showed a strong correlation between age and third-molar development in males (R(2)=0.61) and females (R(2)=0.63). New equations (age=7.49+0.69, development stage (DS) 38+0.70, DS18) were derived for estimation of the chronological age. The results showed that there was no significant difference in mineralisation between 18 and 28 and 38 and 48 in males or females. For both sexes, the dental age was lower than the chronological age. Males reached the developmental stages earlier than females. In the whole population, the boys' and the girls' dental ages were 0.84 years and 0.16 years earlier, respectively, than their chronological ages. The use of third-molar teeth as a developmental marker is suitable, particularly when comparing the obtained standard deviation with other skeletal-age calculation techniques. Copyright © 2013 Elsevier Ireland Ltd. All rights

  10. Geoarchaeological research of the mid-age Ilyas Bey complex buildings with ground penetrating radar in Miletus, Aydin, Western Anatolia, Turkey

    Energy Technology Data Exchange (ETDEWEB)

    Kadioglu, S [Ankara University, Eng. Fac. Geophysical Engineering Department, 06100 Ankara (Turkey); Kadioglu, Y K [Ankara University, Eng. Fac. Geological Engineering Department, 06100 Ankara (Turkey); Akyol, A A [Ankara University, Baskent Vac. High Sch. Prog. of Restoration and Cons., Ankara (Turkey)], E-mail: kadioglu@eng.ankara.edu.tr, E-mail: kadi@eng.ankara.edu.tr, E-mail: akyol@ankara.edu.tr

    2008-07-01

    ) studies reveal that the main bulding rock units of Ilyas Bey Mosque are mainly composed of 4 main units these are marble, metalimestone, mica gneiss and granodiorite. The marble, metalimestone with the mica gneiss were obtained from Menderes Massif in Western Anatolia. The granodiorite columns might be obtained from Kozak Pluton in the north of Bergama-Izmir line of western Anatolia.

  11. Chemical carcinogenesis

    Directory of Open Access Journals (Sweden)

    Paula A. Oliveira

    2007-12-01

    Full Text Available The use of chemical compounds benefits society in a number of ways. Pesticides, for instance, enable foodstuffs to be produced in sufficient quantities to satisfy the needs of millions of people, a condition that has led to an increase in levels of life expectancy. Yet, at times, these benefits are offset by certain disadvantages, notably the toxic side effects of the chemical compounds used. Exposure to these compounds can have varying effects, ranging from instant death to a gradual process of chemical carcinogenesis. There are three stages involved in chemical carcinogenesis. These are defined as initiation, promotion and progression. Each of these stages is characterised by morphological and biochemical modifications and result from genetic and/or epigenetic alterations. These genetic modifications include: mutations in genes that control cell proliferation, cell death and DNA repair - i.e. mutations in proto-oncogenes and tumour suppressing genes. The epigenetic factors, also considered as being non-genetic in character, can also contribute to carcinogenesis via epigenetic mechanisms which silence gene expression. The control of responses to carcinogenesis through the application of several chemical, biochemical and biological techniques facilitates the identification of those basic mechanisms involved in neoplasic development. Experimental assays with laboratory animals, epidemiological studies and quick tests enable the identification of carcinogenic compounds, the dissection of many aspects of carcinogenesis, and the establishment of effective strategies to prevent the cancer which results from exposure to chemicals.A sociedade obtém numerosos benefícios da utilização de compostos químicos. A aplicação dos pesticidas, por exemplo, permitiu obter alimento em quantidade suficiente para satisfazer as necessidades alimentares de milhões de pessoas, condição relacionada com o aumento da esperança de vida. Os benefícios estão, por

  12. Geological exploration strategies and site characterisation methodologies

    International Nuclear Information System (INIS)

    Sprecher, C.

    1997-01-01

    Starting with a short overview of the Swiss HLW disposal programme the paper addresses the more general issue of how site characterisation programmes can better be matched to the acknowledged data requirements of safety analysts and repository designers. Swiss experience suggests that measures to promote mutual understanding between geologistsand quantitative modelers and advance planning of the GEO-data-synthesis can help to bridge the gap separating performance assessment input parameters and field measurements. This represents a step towards more effective and cost efficient field investigations. (author). 4 figs

  13. The Wigner distribution function in modal characterisation

    CSIR Research Space (South Africa)

    Mredlana, Prince

    2016-07-01

    Full Text Available function in modal characterisation P. MREDLANA1, D. NAIDOO1, C MAFUSIRE2, T. KRUGER2, A. DUDLEY1,3, A. FORBES1,3 1CSIR National Laser Centre, PO BOX 395, Pretoria 0001, South Africa. 2Department of Physics, Faculty of Natural and Agricultural... these modal weights is the main aim of the decomposition, the coefficients yield information about the amplitude and phase of the orthogonal modes. Using this, we can reconstruct the entire field. Let 𝑓 𝑥 be a field function in the spatial domain...

  14. X-ray characterisation of nanostructured materials

    DEFF Research Database (Denmark)

    Oddershede, Jette

    X-ray powder di®raction (XRPD) is an excellent tool for characterising the bulk structure of crystalline materials. Along with the growing interest in exploiting materials with decreasing particle sizes and increasing number of defects, factors that complicate the traditional interpretation...... of the experi- mental XRPD patterns, the need for new interpretation methods has arisen. The method described in the present thesis is by no means new, in fact it was developed by Debye in 1915. However, the Debye method it is rather computationally heavy, so in practise it is only applicable to the X-ray char...

  15. Impedimetric method for physiologically characterisation of fungi

    DEFF Research Database (Denmark)

    Nielsen, Per Væggemose; Petersen, Karina

    1998-01-01

    Fungi are playing an important role in the food and pharmaceutical industry today, both as starter cultures, fermentation organisms, and as contaminants. Characterisation of fungal growth is normally time consuming as it includes measurements and study on a wide range of media at different...... time) on the Bactometer and agar plates were obtained. The two methods present two phases of the growth of fungi; exponential growth observed after growth on the Bactometer (first 2-3 days) and a linear growth observed after growth on agar plates (after 2-3 days). It was also found that growth depends...

  16. Identification and Characterisation of a Proteasome -

    DEFF Research Database (Denmark)

    Andersen, Katrine Mølgaard

    is responsible for the degradation of most intracellular proteins. To sustain its function, the proteasome is supported by a still increasing number of interacting proteins or co-factors. In the work presented here, two new proteasome interacting proteins are identified and characterised in humans...... this domain. A txl1 yeast knockout mutant displays a synthetic growth defect with a cut8 knockout, whereas the txc1 knockout does not. In fission yeast, Cut8 is a nuclear protein that tethers the 26S proteasome to the nuclear membrane. In both wild type cells and in a cut8 null mutant Txl1 co-localises...

  17. Radiological characterisation and decommissioning in Denmark

    International Nuclear Information System (INIS)

    Nellemenn, Thomas

    2012-01-01

    Danish Decommissioning (DD) is currently decommissioning the last Danish research reactor (DR3) and the Hot Cell facility. The DR3 project will soon finish dismantling of the external parts of the reactor (January 2012). The approval for dismantling of neutron activated and tritium contaminated heavy water pumps and tubing was granted in December 2011. DD will begin the work on the inner parts as the tendering process for equipment will start in 2012. Hereafter the dismantling of the top of the reactor will begin using the obtained remote controlled equipment. The Hot Cell facility consists of 6 contaminated cells. The first cell have been opened and cleaned. Currently the work progresses by removing parts and hot spots from the other cells with the use of robotic equipment. Challenges, lack of conventional and radiological documentation, dose rates and contamination higher than expected and the confined space in the cells have delayed the project. No final repository exists in Denmark. Therefore no official Waste Acceptance Criteria (WAC) have been formulated. However the Danish authority (SIS) does require a description of the waste in the interim storage facility (Inventory). Furthermore radiological characterisation of key nuclides is needed during decommissioning and dismantling. The information gained from the characterisation helps in the planning phase prior to the dismantling and for inventory calculations for later use. DD performs the radiological characterisation via both non-destructive and destructive analysis on samples. The samples are measured with gamma spectroscopy using mathematical and geometrical analysis. Scaling factors are used for neutron activated waste (DR3) to determine the difficult-to-measure isotopes and pure beta emitters. The primary scaling isotope is Co-60. Waste from the Hot Cell facility is alpha contaminated and scaling procedures for determination of alpha contamination are currently used in the planning process. Scaling of

  18. Mechanically induced residual stresses: Modelling and characterisation

    Science.gov (United States)

    Stranart, Jean-Claude E.

    Accurate characterisation of residual stress represents a major challenge to the engineering community. This is because it is difficult to validate the measurement and the accuracy is doubtful. It is with this in mind that the current research program concerning the characterisation of mechanically induced residual stresses was undertaken. Specifically, the cold expansion of fastener holes and the shot peening treatment of aerospace alloys, aluminium 7075 and titanium Ti-6Al-4V, are considered. The objective of this study is to characterise residual stresses resulting from cold working using three powerful techniques. These are: (i) theoretical using three dimensional non-linear finite element modelling, (ii) semi-destructive using a modified incremental hole drilling technique and (iii) nondestructive using a newly developed guided wave method supplemented by traditional C-scan measurements. The three dimensional finite element results of both simultaneous and sequential cold expansion of two fastener holes revealed the importance of the separation distance, the expansion level and the loading history upon the development and growth of the plastic zone and unloading residual stresses. It further showed that the commonly adopted two dimensional finite element models are inaccurate and incapable of predicting these residual stresses. Similarly, the dynamic elasto-plastic finite element studies of shot peening showed that the depth of the compressed layer, surface and sub-surface residual stresses are significantly influenced by the shot characteristics. Furthermore, the results reveal that the separation distance between two simultaneously impacting shots governs the plastic zone development and its growth. In the semi-destructive incremental hole drilling technique, the accuracy of the newly developed calibration coefficients and measurement techniques were verified with a known stress field and the method was used to measure peening residual stresses. Unlike

  19. High-Rate Characterisation of Hexanitrostilbene

    Science.gov (United States)

    Claridge, Robert; Parker, Adam; Proud, William

    2007-06-01

    Hexanitrostilbene (HNS) is a nitro-aromatic insensitive secondary explosive currently used in a number of insensitive munitions (IM) applications and under consideration for several others. The physical behavior of HNS is therefore important for the development of safe and reliable weapons systems. As part of a comprehensive suite of shock characterisation experiments, one-dimensional plate impact experiments have been performed on HNS IV at two different densities. The unreacted Hugoniot curve was established at each density and the results compared to those reported in the literature. The data obtained from these experiments will assist in the modelling of ignition and growth within HNS based explosives systems.

  20. Tablet surface characterisation by various imaging techniques

    DEFF Research Database (Denmark)

    Seitavuopio, Paulus; Rantanen, Jukka; Yliruusi, Jouko

    2003-01-01

    The aim of this study was to characterise tablet surfaces using different imaging and roughness analytical techniques including optical microscopy, scanning electron microscopy (SEM), laser profilometry and atomic force microscopy (AFM). The test materials compressed were potassium chloride (KCl......) and sodium chloride (NaCl). It was found that all methods used suggested that the KCl tablets were smoother than the NaCl tablets and higher compression pressure made the tablets smoother. Imaging methods like optical microscopy and SEM can give useful information about the roughness of the sample surface...

  1. Material characterisation with methods of nonlinear optics

    Science.gov (United States)

    Prylepa, A.; Reitböck, C.; Cobet, M.; Jesacher, A.; Jin, X.; Adelung, R.; Schatzl-Linder, M.; Luckeneder, G.; Stellnberger, K.-H.; Steck, T.; Faderl, J.; Stehrer, T.; Stifter, D.

    2018-01-01

    In this review, we present nonlinear optical methods, based on the second and third order nonlinear polarization, especially in the context of material characterization tasks outside the area of life sciences—for which these techniques are mostly designed. An overview of application studies reported to date is given, together with a discussion on the advantages and limits of the individual methods. Furthermore, new ways of experimentally combining different optical concepts are introduced, and their potential for characterisation and inspection tasks is evaluated in the context of various case studies, including the investigation of semiconductor surfaces, metals and related corrosion products, as well as of organic materials.

  2. A rock characterisation facility consultative document

    International Nuclear Information System (INIS)

    1992-10-01

    This U.K. Nirex Ltd., consultative document describes a proposed underground rock characterisation facility, east of Sellafield, for conducting geophysical surveys as a basis for refining long-term safety analysis of an underground repository for intermediate-level and low-level radioactive wastes. Planning application will be submitted in 1993. The construction of shafts and galleries is described and the site's geologic, topographical, climatic and archaeological features discussed. The effects to the local environment and on local populations and other socio-economic factors are discussed. (UK)

  3. THE ILICA BRANCH OF THE SOUTHEASTERN ESKIŞEHIR FAULT ZONE: AN ACTIVE RIGHT LATERAL STRIKE-SLIP STRUCTURE IN CENTRAL ANATOLIA, TURKEY

    Directory of Open Access Journals (Sweden)

    Korhan ESAT

    2016-12-01

    Full Text Available The Eskişehir Fault Zone is one of the prominent neotectonic structures of Turkey. It separates the west  Anatolian extensional province and the strike-slip induced northwest central Anatolian contractional area in the Anatolian Block. Its southeastern part is generally divided into three branches, namely the Ilıca, Yeniceoba, and Cihanbeyli from north to south, respectively. The right lateral strike-slip Ilıca branch (IB is an approximately 100-km-long fault and it is composed of several segments in a northwest-southeast direction. The slickensides, subsidiary fractures, cataclastic zone, fracture-controlled drainage pattern, right lateral stream deflections, deformation in the Quaternary unit observing in the seismic reflection sections, and seismicity of the region all indicate that the IB is an active right lateral strike-slip fault. The IB has also a regional tectonic importance as a boundary fault between the contractional and the extensional regions in central Anatolia considering that it is the southern limit of the contraction-related structures in the west-southwest of Ankara.

  4. sandflyDST: a dynamic web-based decision support tool for the morphological identification of sandflies present in Anatolia and mainland Europe, and user study.

    Science.gov (United States)

    Karakülah, G; Karakuş, M; Suner, A; Demir, S; Arserim, S K; Töz, S; Özbel, Y

    2016-09-01

    Species identification of sandflies is mainly performed according to morphological characters using classical written identification keys. This study introduces a new web-based decision support tool (sandflyDST) for guiding the morphological identification of sandfly species present in Anatolia and mainland Europe and classified in the Phlebotomus and Sergentomyia genera (both: Diptera: Psychodidae). The current version of the tool consists of 111 questions and 36 drawings obtained from classical written keys, and 107 photographs for the quick and easy identification of 26 species of the genus Phlebotomus and four species of the genus Sergentomyia. The tool guides users through a decision tree using yes/no questions about the morphological characters of the specimen. The tool was applied by 30 individuals, who then completed study questionnaires. The results of subsequent analyses indicated that the usability (x‾SUSScore=75.4) and users' level of appreciation (86.6%) of the tool were quite high; almost all of the participants considered recommending the tool to others. The tool may also be useful in training new entomologists and maintaining their level of expertise. This is a dynamic tool and can be improved or upgraded according to feedback. The tool is now available online at http://parasitology.ege.edu.tr/sandflyDST/index.php. © 2016 The Royal Entomological Society.

  5. An analysis of the murder of women in a 10-year period in Eskişehir Province located in western Anatolia in Turkey.

    Science.gov (United States)

    Karbeyaz, Kenan; Akkaya, Harun; Balci, Yasemin

    2013-08-01

    Murder of women generally occurs as a result of violence by their husbands and relatives. We evaluated the female victims of murder in Eskişehir, located in western Anatolia, where the education level is high in this study. Our aim was to assess and discuss data related to the victims and murderers. A total of 141 women's murder cases were analysed in the study. After a legal process and the results of the autopsies during 2002-2011 in Eskişehir, 715 subjects found to have died as a result of murder were chosen. Cases were evaluated in terms of their age, marital status, education level, relationship to the murderer, reasons for violence, type of action and reasons for death. It was determined that 48.2% (n = 68) of the victims had been killed by the husband and 7.8% (n = 11) by the ex-husband. Murderers generally stated that the reason of murder was the woman's request for divorce or breaking up (n = 40, 28.4%). In compliance with the literature, the women were most commonly killed by their husbands in our study. Enhancing women's status and preventing violence against women will decrease such murders. Published by Elsevier Ltd.

  6. TORCH seroprevalence among patients attending Obstetric Care Clinic of Haydarpasa Training and Research Hospital affiliated to Association of Istanbul Northern Anatolia Public Hospitals.

    Science.gov (United States)

    Numan, Onur; Vural, Fisun; Aka, Nurettin; Alpay, Murat; Coskun, Ayse Deniz Erturk

    2015-01-01

    Toxoplasma gondii, Rubella, Cytomegalovirus and Herpes simplex viruses are microorganisms that cause congenital infections and they are called briefly as TORCH. There is an ongoing argument for the screening of reproductive age women due to the high cost of tests. For a test to be used in screening, prevalence of disease in this population should be known. The aim of this study was to investigate TORCH seroprevalence among women attending a teaching hospital in Istanbul. A total of 1101 patients attending outpatient clinic of Obstetric Care Clinic of Haydarpasa Training and Research Hospital affiliated to Association of Istanbul Northern Anatolia Public Hospitals between September 2013 to January 2015 and their laboratory data were evaluated retrospectively. We investigated Ig G and M seropositivity rates against TORCH. The age of the patients ranged between 17-47 years with a mean age of 30.3±5.8 years. Pregnant population had 99.5% anti-CMV Ig G (+), 94.2% anti-Rubella Ig G (+), 31% anti-Toxoplasma Ig G (+). Seroprevalence for Anti IgM was 0.5% for CMV, 0.2% for rubella. The screening for Toxoplasma gondii may be suggested since the prevalence is not high in our population. The screening of CMV is not meaningful, due to high seroprevalence. Although seroprevalence of rubella is also high, it may be suggested for preconception vaccination especially in women above 20 years of age born prior to National Vaccination Programme.

  7. Thermo-resistant green microalgae for effective biodiesel production: isolation and characterization of unialgal species from geothermal flora of Central Anatolia.

    Science.gov (United States)

    Onay, Melih; Sonmez, Cagla; Oktem, Huseyin Avni; Yucel, Ayse Meral

    2014-10-01

    Oil content and composition, biomass productivity and adaptability to different growth conditions are important parameters in selecting a suitable microalgal strain for biodiesel production. Here, we describe isolation and characterization of three green microalgal species from geothermal flora of Central Anatolia. All three isolates, namely, Scenedesmus sp. METUNERGY1402 (Scenedesmus sp. ME02), Hindakia tetrachotoma METUNERGY1403 (H. tetrachotoma ME03) and Micractinium sp. METUNERGY1405 (Micractinium sp. ME05) are adaptable to growth at a wide temperature range (25-50 °C). Micractinium sp. ME05, particularly has superior properties for biodiesel production. Biomass productivity, lipid content and lipid productivity of this isolate are 0.17 g L(-1) d(-1), 22.7% and 0.04 g L(-1) d(-1), respectively. In addition, Micractinium sp. ME05 and Scenedesmus sp. ME03 mainly contain desirable fatty acid methyl esters (i.e. 16:0, 16:1, 18:0 and 18:1) for biodiesel production. All isolates can further be improved via genetic and metabolic engineering strategies. Copyright © 2014 Elsevier Ltd. All rights reserved.

  8. Pathogenic and molecular characterisation of Pythium spp. inducing ...

    African Journals Online (AJOL)

    Pathogenic and molecular characterisation of Pythium spp. inducing root rot symptoms in other crops intercropped with beans in Southwestern Uganda. Virginia Gichuru, Robin Buruchara, Patrick Okori ...

  9. Characterisation of metal combustion with DUST code

    Energy Technology Data Exchange (ETDEWEB)

    García-Cascales, José R., E-mail: jr.garcia@upct.es [DITF, ETSII, Universidad Politécnica de Cartagena, Dr Fleming s/n, 30202 Murcia (Spain); Velasco, F.J.S. [Centro Universitario de la Defensa de San Javier, MDE-UPCT, C/Coronel Lopez Peña s/n, 30730 Murcia (Spain); Otón-Martínez, Ramón A.; Espín-Tolosa, S. [DITF, ETSII, Universidad Politécnica de Cartagena, Dr Fleming s/n, 30202 Murcia (Spain); Bentaib, Ahmed; Meynet, Nicolas; Bleyer, Alexandre [Institut de Radioprotection et Sûreté Nucléaire, BP 17, 92260 Fontenay-aux-Roses (France)

    2015-10-15

    Highlights: • This paper is part of the work carried out by researchers of the Technical University of Cartagena, Spain and the Institute of Radioprotection and Nuclear Security of France. • We have developed a code for the study of mobilisation and combustion that we have called DUST by using CAST3M, a multipurpose software for studying many different problems of Mechanical Engineering. • In this paper, we present the model implemented in the code to characterise metal combustion which describes the combustion model, the kinetic reaction rates adopted and includes a first comparison between experimental data and calculated ones. • The results are quite promising although suggest that improvement must be made on the kinetic of the reaction taking place. - Abstract: The code DUST is a CFD code developed by the Technical University of Cartagena, Spain and the Institute of Radioprotection and Nuclear Security, France (IRSN) with the objective to assess the dust explosion hazard in the vacuum vessel of ITER. Thus, DUST code permits the analysis of dust spatial distribution, remobilisation and entrainment, explosion, and combustion. Some assumptions such as particle incompressibility and negligible effect of pressure on the solid phase make the model quite appealing from the mathematical point of view, as the systems of equations that characterise the behaviour of the solid and gaseous phases are decoupled. The objective of this work is to present the model implemented in the code to characterise metal combustion. In order to evaluate its ability analysing reactive mixtures of multicomponent gases and multicomponent solids, two combustion problems are studied, namely H{sub 2}/N{sub 2}/O{sub 2}/C and H{sub 2}/N{sub 2}/O{sub 2}/W mixtures. The system of equations considered and finite volume approach are briefly presented. The closure relationships used are commented and special attention is paid to the reaction rate correlations used in the model. The numerical

  10. Complementary techniques for solid oxide cell characterisation on micro- and nano-scale

    International Nuclear Information System (INIS)

    Wiedenmann, D.; Hauch, A.; Grobety, B.; Mogensen, M.; Vogt, U.

    2009-01-01

    High temperature steam electrolysis by solid oxide electrolysis cells (SOEC) is a way with great potential to transform clean and renewable energy from non-fossil sources to synthetic fuels such as hydrogen, methane or dimethyl ether, which have been identified as promising alternative energy carriers. Also, as SOEC can operate in the reverse mode as solid oxide fuel cells (SOFC), during high peak hours e.g. hydrogen can be used in a very efficient way to reconvert chemically stored energy into electrical energy. As solid oxide cells (SOC) are working at high temperatures (700-900 o C), material degradation and evaporation can occur e.g. from the cell sealing material, leading to poisoning effects and aging mechanisms which are decreasing the cell efficiency and long-term durability. In order to investigate such cell degradation processes, thorough examination on SOC often requires the chemical and structural characterisation on the microscopic and the nanoscopic level. The combination of different microscope techniques like conventional scanning electron microscopy (SEM), electron-probe microanalysis (EPMA) and the focused ion-beam (FIB) preparation technique for transmission electron microscopy (TEM) allows performing post mortem analysis on a multi scale level of cells after testing. These complementary techniques can be used to characterize structural and chemical changes over a large and representative sample area (micro-scale) on the one hand, and also on the nano-scale level for selected sample details on the other hand. This article presents a methodical approach for the structural and chemical characterisation of changes in aged cathode-supported electrolysis cells produced at Riso DTU, Denmark. Also, results from the characterisation of impurities at the electrolyte/hydrogen interface caused by evaporation from sealing material are discussed. (author)

  11. Recent Progresses in Characterising Information Inequalities

    Directory of Open Access Journals (Sweden)

    Terence Chan

    2011-01-01

    Full Text Available In this paper, we present a revision on some of the recent progresses made in characterising and understanding information inequalities, which are the fundamental physical laws in communications and compression. We will begin with the introduction of a geometric framework for information inequalities, followed by the first non-Shannon inequality proved by Zhang et al. in 1998 [1]. The discovery of this non-Shannon inequality is a breakthrough in the area and has led to the subsequent discovery of many more non-Shannon inequalities. We will also review the close relations between information inequalities and other research areas such as Kolmogorov complexity, determinantal inequalities, and group-theoretic inequalities. These relations have led to non-traditional techniques in proving information inequalities and at the same time made impacts back onthose related areas by the introduction of information-theoretic tools.

  12. Particle methods of characterising catalysts Part 1

    International Nuclear Information System (INIS)

    Wright, C.J.

    1980-01-01

    It is the intention of this chapter to explain and illustrate the areas in catalysis research where advantages will accrue from using neutron techniques to illuminate a particular problem. The introduction will include an outline of the different classes of neutron experiment and a description of how the neutron nucleus interaction expressed through the cross-sections leads to many of the individual applications. After this the technique will be described area by area, with examples chosen from the literature to underscore points of importance. The areas are: small angle scattering, where information on the textural properties of materials such as pore structure and particle size can be determined; diffraction, for structure analysis; quasi-elastic scattering, for characterising the spatial and temporal aspects of atomic and molecular diffusion; and inelastic scattering, for studying vibrational transitions of atoms and molecules. (author)

  13. Synthesis and characterisation of new laser dyes

    International Nuclear Information System (INIS)

    Scala-Valero, Claudine

    1997-01-01

    Rhodamines are very efficient laser dyes for the red part of the visible spectrum: their fluorescence quantum efficiencies are about hundred per cent. However, their conversion efficiencies in dye amplifier are about fifty per cent, due to the presence of S n electronic level which is responsible of the re-absorption of a part of photons. In this research thesis, the author aims at trying to move this S n level out of the stimulated emission bandwidth. Models have been developed to propose new structures derived from rhodamines and theoretically possessing the desired properties. The so-recommended molecules have then been synthesised and characterised in terms of absorption and fluorescence spectra, of quantum efficiency, and of fluorescence lifetime. Two modifications are proposed for the rhodamine 6G structure, either by grafting methyl substitutes, or by grafting variously substituted amines. The searched result is obtained with the second modification [fr

  14. Tablet surface characterisation by various imaging techniques

    DEFF Research Database (Denmark)

    Seitavuopio, Paulus; Rantanen, Jukka; Yliruusi, Jouko

    2003-01-01

    The aim of this study was to characterise tablet surfaces using different imaging and roughness analytical techniques including optical microscopy, scanning electron microscopy (SEM), laser profilometry and atomic force microscopy (AFM). The test materials compressed were potassium chloride (KCl......) and sodium chloride (NaCl). It was found that all methods used suggested that the KCl tablets were smoother than the NaCl tablets and higher compression pressure made the tablets smoother. Imaging methods like optical microscopy and SEM can give useful information about the roughness of the sample surface......, but they do not provide quantitative information about surface roughness. Laser profilometry and AFM on the other hand provide quantitative roughness data from two different scales, laser profilometer from 1 mm and atomic force microscope from 90 microm scale. AFM is a powerful technique but other imaging...

  15. Analytical characterisation of homoeopathic mother tinctures.

    Science.gov (United States)

    Biber, A; Franck-Karl, G; Waimer, F; Riegert, U; Wiget, R

    2009-03-01

    Quality of homoeopathic mother tinctures is assured by the definition of the starting material, the manufacturing process and the analytical characteristics described in the monograph. Traditionally analytical characterisation of the mother tincture comprises appearance, odour, identity, density and dry residue. According to annex I of directive 2001/83/EC an assay is only performed in case of a health hazard due to toxic compounds. The concept of marker substances as usually used in phytotherapy cannot be transferred to mother tinctures without research effort. For example the marker substances echinacoside, apigenin-7-glucoside and rosmarinic acid found in dried underground parts of Echinacea pallida Nutt., dried flower heads of Matricaria recutita L. and dried herb of Pulmonaria officinalis L. cannot be found in homoeopathic mother tinctures prepared from fresh material thereof.

  16. Characterisation of multifunctional surfaces with robust filters

    DEFF Research Database (Denmark)

    Friis, Kasper Storgaard; Godi, Alessandro; De Chiffre, Leonardo

    2011-01-01

    Research has shown that engineered surfaces containing lubrication pockets and directional surface texture can decrease wear and friction in sliding or rolling contacts. A new generation of multifunctional (MUFU) surfaces is achieved by hard machining followed by robot assisted polishing (RAP......). The novel production method allows for a large degree of freedom in specifying surface characteristics such as frequency, depth and volume of the lubricant retention valleys, as well as the amount of load bearing area and the surface roughness. The surfaces cannot readily be characterized by means...... of conventional roughness parameters due to the multi-process production method involved. A series of MUFU surfaces were characterized by using the ISO 13565 standard for stratified surfaces and it is shown that the standard in some cases is inadequate for characterisation of a MUFU surface. To improve...

  17. Characterising shock propagation through inert beds

    Science.gov (United States)

    Edgeley, James; Braithwaite, Christopher

    2017-06-01

    Optical velocimetry methods have been used extensively to measure the detonation wave velocity in explosives. The reaction zone length can subsequently be inferred using one of several methods, most involving transmitting the shock into an acceptor component made of another material and observing the wave's attenuation. The ultimate aim of this investigation is to develop a method optimised for characterising the reaction zone in low density PETN. The initial procedure involves a shock imparted by a gas gun into an inert bed in otherwise similar conditions. The design of the acceptor component is varied, and in each case an appropriate calculation is done to determine the size and profile of the shock. Laser interferometry is used to take velocity measurements where necessary. The results are compared against the input shock from the gun to assess the suitability of the apparatus.

  18. Extraction and characterisation of cellulose nanocrystals from pineapple peel

    Directory of Open Access Journals (Sweden)

    Ana Raquel Madureira

    2018-04-01

    Full Text Available The potential of pineapple peel as a source of cellulose nanocrystals was evaluated. Peels skin from fresh-cut fruit was used as raw material. These residues were purified to remove pigments, lipids and hemicellulose, and a bleaching process for delignification was carried out for 4-6 h. All resulting products were characterised for their lignin, hemicellulose, cellulose and ash contents using standard techniques. Dry matter at the end was low (ca. 50% compared with the raw material (ca. 90%. The process applied resulted in ca. 20% (m/m of purified cellulose (ca. 80% purity, with ineligible levels of lignin and hemicellulose present, especially when using 6h of bleaching. The purified cellulose was subject to acid hydrolysis for nanocrystal extraction with two testing times, 30 and 60 minutes. These cellulose nanocrystals had small sizes (< 1000 nm, with high variability and negative zeta potential values. The time of extraction did not affect the nanocrystals’ chemical and physical properties. The use of 6 h of bleaching treatment during purification was shown to be more effective than 4 h. Pineapple peel was demonstrated to be a good source of cellulose for the production of cellulose nanocrystals.

  19. Characterisation of thin films by phase modulated spectroscopic ellipsometry

    International Nuclear Information System (INIS)

    Bhattacharyya, D.; Das, N.C.

    1998-07-01

    A wide variety of thin film coatings, deposited by different techniques and with potential applications in various important areas, have been characterised by the Phase Modulated Spectroscopic Ellipsometer, installed recently in the Spectroscopy Division, B.A.R.C. The Phase Modulated technique provides a faster and more accurate data acquisition process than the conventional ellipsometry. The measured Ellipsometry spectra are fitted with theoretical spectra generated assuming an appropriate model regarding the sample. The fittings have been done objectively by minimising the squared difference (χ 2 ) between the measured and calculated values of the ellipsometric parameters and thus accurate information have been derived regarding the thickness and optical constants (viz, the refractive index and extinction coefficient) of the different layers, the surface roughness and the inhomogeneities present in the layers. Measurements have been done on (i) ion-implanted Si-wafers to investigate the formation of SiC layers, (ii) phenyl- silane coating on glass to investigate the surface modifications achieved for better adsorption of rhodamine dye on glass, (iii) GaN films on quartz to investigate the formation of high quality GaN layers by sputtering of GaAs targets, (iv) Diamond-like-coating (DLC) samples prepared by Chemical Vapour Deposition (CVD) to investigate the optical properties which would ultimately lead to an accurate estimation of the ratio of sp 3 and sp 2 bonded carbon atoms in the films and (v) SS 304 under different surface treatments to investigate the growth of different passive films. (author)

  20. Characterising antimicrobial protein-membrane complexes

    International Nuclear Information System (INIS)

    Xun, Gloria; Dingley, Andrew; Tremouilhac, Pierre

    2009-01-01

    Full text: Antimicrobial proteins (AMPs) are host defence molecules that protect organisms from microbial infection. A number of hypotheses for AMP activity have been proposed which involve protein membrane interactions. However, there is a paucity of information describing AMP-membrane complexes in detail. The aim of this project is to characterise the interactions of amoebapore-A (APA-1) with membrane models using primarily solution-state NMR spectroscopy. APA-1 is an AMP which is regulated by a pH-dependent dimerisation event. Based on the atomic resolution solution structure of monomeric APA-1, it is proposed that this dimerisation is a prerequisite for ring-like hexameric pore formation. Due to the cytotoxicity of APA-1, we have developed a cell-free system to produce this protein. To facilitate our studies, we have adapted the cell-free system to isotope label APA-1. 13 C /15 N -enriched APA-1 sample was achieved and we have begun characterising APA-1 dimerisation and membrane interactions using NMR spectroscopy and other biochemical/biophysical methods. Neutron reflectometry is a surface-sensitive technique and therefore represents an ideal technique to probe how APA-1 interacts with membranes at the molecular level under different physiological conditions. Using Platypus, the pH-induced APA-1-membrane interactions should be detectable as an increase of the amount of protein adsorbed at the membrane surface and changes in the membrane properties. Specifically, detailed information of the structure and dimensions of the protein-membrane complex, the position and amount of the protein in the membrane, and the perturbation of the membrane phospholipids on protein incorporation can be extracted from the neutron reflectometry measurement. Such information will enable critical assessment of current proposed mechanisms of AMP activity in bacterial membranes and complement our NMR studies

  1. Rheological characterisation of gluten from triticale (x Triticosecale Wittmack).

    Science.gov (United States)

    Pruska-Kędzior, Anna; Makowska, Agnieszka; Kędzior, Zenon; Salmanowicz, Bolesław P

    2017-11-01

    Triticale gluten still remains very poorly characterised rheologically. In this study the mechanical spectra of gluten isolated from four triticale cultivars were registered and fitted with Cole-Cole functions yielding the visco-elastic plateau parameters. Master spectra were calculated. A retardation test was performed and used to calculate the composite mechanical spectra and the width of visco-elastic plateau l. Protein fractional composition of triticale flour and gluten was studied using capillary zone electrophoresis. Differentiated HMW-GS/SS compositions were identified in the triticale cultivars studied. The rheological parameters reached the following values: J N 0 1.05·10 -3 to 2.69·10 -3 Pa -1 , G N 0 372 to 956 Pa, ω 0 0.003 to 0.06 rad s -1 , l 169 to 3121, J e 0 1.57·10 -3 to 5.03·10 -3 Pa -1 , G e 0 199 to 637 Pa and η 0 1.06·10 7 to 3.93·10 7 Pa s. Visco-elastic properties of triticale gluten correspond to the lower end of medium visco-elasticity shown by common wheat gluten. Master spectra and the composite mechanical spectra prove that four triticale glutens exhibit practically an identical type of visco-elastic behaviour of a biopolymeric visco-elastic liquid similar to wheat gluten. The visco-elastic plateau parameters G N 0 , J N 0 , ω 0 and l appeared significantly correlated with the contents of prolamins and secaloglutenins in triticale flours and glutens. © 2017 Society of Chemical Industry. © 2017 Society of Chemical Industry.

  2. A review of characterisation requirements for in-line prefermenters ...

    African Journals Online (AJOL)

    A review of characterisation requirements for in-line prefermenters : Paper 2 : Process characterisation. ... Abstract. The operational factors having a significant effect on in-line prefermentation efficiency include the sludge recycle rate and the subsequent sludge elutriation rate, solids concentrations and retention times.

  3. Structural characterisation of human proteinosis surfactant protein A

    DEFF Research Database (Denmark)

    Berg, T.; Leth-Larsen, R.; Holmskov, U.

    2000-01-01

    Human surfactant protein-A (SP-A) has been purified from a proteinosis patient and characterised by a combination of automated Edman degradation and mass spectrometry. The complete protein sequence was characterised. The major part of SP-A was shown to consist of SP-A2 gene product, and only...

  4. Molecular tools for the characterisation of antibiotic-resistant bacteria

    NARCIS (Netherlands)

    Aarts, H.J.M.; Boumedine, K.S.; Nesme, X.; Cloeckaert, A.

    2001-01-01

    This review will discuss a number of molecular tools which are currently used as well as some innovative approaches for the characterisation of antibiotic-resistant bacterial strains. Various methods involved in the detection and characterisation of genes and mutations associated with antibiotic

  5. Chemical characterization of atmospheric particles

    International Nuclear Information System (INIS)

    Adams, F.

    2002-01-01

    In the characterisation of complex environmental materials such as atmospheric particulate matter, analytical specificity is required to account for the many dimensions of information present in the sample. These dimensions include size, morphology, elemental composition, inorganic and organic chemical speciation, all to be performed on either single particles or on the population (or bulk sample) basis. Various techniques were developed for such measurements, including a number of bulk analysis procedures, methodologies for microscopical analysis of individual particles, and a variety of procedures for organic/inorganic chemical speciation. (author)

  6. Growth and characterisation of lead iodide single crystals

    International Nuclear Information System (INIS)

    Tonn, Justus

    2012-01-01

    The work in hand deals with the growth and characterisation of lead iodide (PbI 2 ) single crystals. PbI 2 is regarded as a promising candidate for low-noise X- and gamma ray detection at room temperature. Its benefits if compared to conventional materials like HgI 2 , CdTe, Si, or GaAs lie in a band gap energy of 2.32 eV, an excellent ability to absorb radiation, and a high electrical resistivity. For an application of PbI 2 as detector material the growth and characterisation of crystals with high chemical and structural quality is extremely challenging. In light of this, the effectiveness of zone purification of the PbI 2 used for crystal growth was confirmed by spectroscopic analysis. Furthermore, technological aspects during processing of purified PbI 2 were investigated. With the help of thermal analysis, a correlation was found between the degree of exposing the source material to oxygen from the air and the structural quality of the resulting crystals. A hydrogen treatment was applied to PbI 2 as an effective method for the removal of oxidic pollutions, which resulted in a significant reduction of structural defects like polytypic growth and stress-induced cracking. The growth of PbI 2 single crystals was, among others, carried out by the Bridgman-Stockbarger method. In this context, much effort was put on the investigation of influences resulting from the design and preparation of ampoules. For the first time, crystal growth of PbI 2 was also carried out by the Czochralski method. If compared to the Bridgman-Stockbarger method, the Czochralski technique allowed a significantly faster growth of nearly crack-free crystals with a reproducible predetermination of crystallographic orientation. By an optimised sample preparation of PbI 2 , surface orientations perpendicular to the usually cleaved (0001) plane were realised. It is now possible to determine the material properties along directions which were so far not accessible. Thus, for example, the ratio of

  7. Chemical Emergencies

    Science.gov (United States)

    When a hazardous chemical has been released, it may harm people's health. Chemical releases can be unintentional, as in the case of an ... the case of a terrorist attack with a chemical weapon. Some hazardous chemicals have been developed by ...

  8. A new look at the collision-related volcanism in Eastern Anatolia, Turkey: Volcanic history of the Northern-Van neovolcanic province

    Science.gov (United States)

    Keskin, Mehmet; Lebedev, Vladimir; Sharkov, Evgenii; Oyan, Vural; Ünal, Esin

    2010-05-01

    The region including the Eastern Anatolian - Northern Iranian High Plateau and Greater and Lesser Caucasus mountain ranges is one of the best examples of an active continental collision zone in the world, which is thought to have been formed by the closure of the northern branch of the Neotethyan Ocean. It comprises one of the high plateaus of the Alpine-Himalaya mountain belt (i.e. the Eastern Anatolia High Plateau) with an average elevation of ~2 km above the sea level. The volcanic activity initiated immediately after the block uplift of the region (at around 15 Ma as our new isotope-geochronological database indicates) and produced great volumes of volcanic material in a number of countries including Turkey, Russia, Georgia, Azerbaijan, Armenia and Iran. At present, the volcanic province extends from Eastern Anatolia (Turkey) into Caucasus of Southern Russia, spanning a distance of some 1000 km. Perhaps the most striking aspect of the Eastern Anatolian - N Iranian High Plateau and Caucasus is the volume and compositional variability of collision-related volcanic products erupted in a time interval from Neogene to Quaternary. Only in E Turkey, the collision-related volcanic units cover over half of the region (i.e.˜43,000 km2). In order to better understand the spatial and temporal compositional variations in volcanic rocks and their implications on magma genesis and geodynamic evolution of the region, we conducted joint research on this spectacular volcanic province. One of the largest Cenozoic volcanic areas on the EAHP is located in the north of Lake Van as we named "the Northern-Van neovolcanic province". It covers an area of about 6000 km2 starting from the northern cost of Lake Van. It is composed of a series of volcanic edifices (e.g. Girekol, Meydandag and Etrusk volcanoes). Remarkably, these volcanoes sit almost on the culmination of a regional domal structure called "Lake Van dome" in the vertex of the eastern Turkish high plateau. We intentionally

  9. Bandidaje y piratería en la Anatolia meridional. Definición y circunstancias en el marco de las guerras mitridáticas

    Directory of Open Access Journals (Sweden)

    Isaías ARRAYÁS MORALES

    2011-03-01

    Full Text Available El presente trabajo trata sobre el fenómeno pirático en el mundo greco-romano. Su estudio resulta muy complejo, teniendo en cuenta que el vocabulario y la mentalidad de los autores antiguos interfieren de tal manera que es extremadamente complicado ir más allá y precisar el germen de los procesos históricos que fomentan las actividades piráticas, así como el tipo y la naturaleza de las diferentes acciones descritas. En este sentido, resulta casi imposible diferenciar a los piratas, de corsarios, de mercenarios o incluso de simples mercaderes armados, algo habitual considerando el primigenio vínculo entre piratería y comercio. Tan sólo el análisis del contexto histórico nos va a permitir una aproximación a la realidad descrita y, en muchos casos, maquillada, que nos presentan las fuentes literarias antiguas. En nuestro cometido, la evidencia arqueológica apenas puede ayudarnos, pues las trazas dejadas por una banda de piratas no se diferencian de las generadas por un destacamento de soldados o de mercenarios, revestidos de la oficialidad que los diferencia de los bandidos. Con el objetivo de ahondar en la problemática, abordamos las causas del auge del fenómeno pirático en los territorios de la Anatolia meridional en la primera mitad del s. I a. C., calibrando el impacto que tuvieron las guerras mitridáticas en el proceso.

  10. Thermal Investigation in the Cappadocia Region, Central Anatolia-Turkey, Analyzing Curie Point Depth, Geothermal Gradient, and Heat-Flow Maps from the Aeromagnetic Data

    Science.gov (United States)

    Bilim, Funda; Kosaroglu, Sinan; Aydemir, Attila; Buyuksarac, Aydin

    2017-12-01

    In this study, curie point depth (CPD), heat flow, geothermal gradient, and radiogenic heat production maps of the Cappadocian region in central Anatolia are presented to reveal the thermal structure from the aeromagnetic data. The large, circular pattern in these maps matches with previously determined shallow (2 km in average) depression. Estimated CPDs in this depression filled with loose volcano-clastics and ignimbrite sheets of continental Neogene units vary from 7 to 12 km, while the geothermal gradient increases from 50 to 68 °C/km. Heat flows were calculated using two different conductivity coefficients of 2.3 and 2.7 Wm-1 K-1. The radiogenic heat production was also obtained between 0.45 and 0.70 μW m-3 in this area. Heat-flow maps were compared with the previous, regional heat-flow map of Turkey and significant differences were observed. In contrast to linear heat-flow increment through the northeast in the previous map in the literature, produced maps in this study include a large, caldera-like circular depression between Nevsehir, Aksaray, Nigde, and Yesilhisar cities indicating high geothermal gradient and higher heat-flow values. In addition, active deformation is evident with young magmatism in the Neogene and Quaternary times and a large volcanic cover on the surface. Boundaries of volcanic eruption centers and buried large intrusions are surrounded with the maxspots of the horizontal gradients of magnetic anomalies. Analytic signal (AS) map pointing-out exact locations of causative bodies is also presented in this study. Circular region in the combined map of AS and maxspots apparently indicates a possible caldera.

  11. Characterisation of varnishes used in violins by pyrolysis-gas chromatography/mass spectrometry.

    Science.gov (United States)

    Chiavari, Giuseppe; Montalbani, Simona; Otero, Vanessa

    2008-12-01

    The correct characterisation and a detailed knowledge of the materials originally used in violin varnishes, like natural resins, is crucial for the conservation in museums and for a suitable restoration technique. The study presented here reports on the potential of pyrolysis (Py) coupled with gas chromatography (GC) and mass spectrometry (MS) for the identification of chemical markers of each resin; this technique is very sensitive and selective, it needs a small quantity of sample and does not require chemical treatments. To improve the chromatographic behaviour of polar compounds the derivatising agent tetramethylammonium hydroxide (TMAH) in combination with pyrolysis has been used, in the so-called TMAH thermochemolysis or thermally assisted hydrolysis and methylation (THM), or more simply pyrolysis-methylation. The natural resins studied were colophony, sandarac, manila copal, elemi, amber and benzoin, mainly composed of terpenic compounds, with the exception of the latter, composed of aromatic compounds. Many compounds were identified; in particular, methyl esters of resinous acids that, individually or in a group, can be used as chemical markers. However, through this technique it was not possible to distinguish between the sandarac and manila copal resins because their chromatographic behaviour is very similar. Finally, the procedure applied has been employed in the characterisation of original varnish samples.

  12. Characterisation of metals in the electronic waste of complex mixtures of end-of-life ICT products for development of cleaner recovery technology

    Energy Technology Data Exchange (ETDEWEB)

    Sun, Z.H.I. [Department of Materials Science and Engineering, TU Delft, 2628 CD Delft (Netherlands); Xiao, Y. [Ironmaking Department, R and D, Tata Steel, 1970 CA IJmuiden (Netherlands); Sietsma, J. [Department of Materials Science and Engineering, TU Delft, 2628 CD Delft (Netherlands); Agterhuis, H.; Visser, G. [Business Development, Van Gansewinkel Groep BV, 5657 DH Eindhoven (Netherlands); Yang, Y. [Department of Materials Science and Engineering, TU Delft, 2628 CD Delft (Netherlands)

    2015-01-15

    Highlights: • New characterisation methodology has been established to understand an industrially processed ICT waste. • Particle size distribution, composition, thermal–chemical behaviour and occurrence of metals were considered. • The characterisation provides direct guidelines for values recovery from the waste. - Abstract: Recycling of valuable metals from electronic waste, especially complex mixtures of end-of-life information and communication technology (ICT) products, is of great difficulty due to their complexity and heterogeneity. One of the important reasons is the lack of comprehensive characterisation on such materials, i.e. accurate compositions, physical/chemical properties. In the present research, we focus on developing methodologies for the characterisation of metals in an industrially processed ICT waste. The morphology, particle size distribution, compositional distribution, occurrence, liberation as well as the thermo-chemical properties of the ICT waste were investigated with various characterisation techniques, including X-ray Fluorescence Spectrometry (XRF), differential scanning calorimetry (DSC) and scanning electron microscopy (SEM) with energy dispersed spectroscopy (EDS). Due to the high heterogeneity of the material, special sample preparation procedures were introduced to minimise the discrepancies during compositional analyses. As a result, a clearer overview of the ICT waste has been reached. This research provides better understanding of the extractability of each metal and improves the awareness of potential obstacles for extraction. It will lead to smarter decisions during further development of a clean and effective recovery process.

  13. Characterisation of metals in the electronic waste of complex mixtures of end-of-life ICT products for development of cleaner recovery technology

    International Nuclear Information System (INIS)

    Sun, Z.H.I.; Xiao, Y.; Sietsma, J.; Agterhuis, H.; Visser, G.; Yang, Y.

    2015-01-01

    Highlights: • New characterisation methodology has been established to understand an industrially processed ICT waste. • Particle size distribution, composition, thermal–chemical behaviour and occurrence of metals were considered. • The characterisation provides direct guidelines for values recovery from the waste. - Abstract: Recycling of valuable metals from electronic waste, especially complex mixtures of end-of-life information and communication technology (ICT) products, is of great difficulty due to their complexity and heterogeneity. One of the important reasons is the lack of comprehensive characterisation on such materials, i.e. accurate compositions, physical/chemical properties. In the present research, we focus on developing methodologies for the characterisation of metals in an industrially processed ICT waste. The morphology, particle size distribution, compositional distribution, occurrence, liberation as well as the thermo-chemical properties of the ICT waste were investigated with various characterisation techniques, including X-ray Fluorescence Spectrometry (XRF), differential scanning calorimetry (DSC) and scanning electron microscopy (SEM) with energy dispersed spectroscopy (EDS). Due to the high heterogeneity of the material, special sample preparation procedures were introduced to minimise the discrepancies during compositional analyses. As a result, a clearer overview of the ICT waste has been reached. This research provides better understanding of the extractability of each metal and improves the awareness of potential obstacles for extraction. It will lead to smarter decisions during further development of a clean and effective recovery process

  14. Representing chemicals using OWL, description graphs and rules

    CSIR Research Space (South Africa)

    Hastings, J

    2010-06-01

    Full Text Available of structured objects whose parts are related in complex ways. Classes of chemical entities such as molecules, ions and groups (parts of molecules) are often characterised by the way in which the constituent atoms of their instances are connected via chemical...

  15. Journal of Chemical Sciences | Indian Academy of Sciences

    Indian Academy of Sciences (India)

    Home; Journals; Journal of Chemical Sciences. N Raman. Articles written in Journal of Chemical Sciences. Volume 112 Issue 5 October 2000 pp 515-521 Inorganic and Analytical. Copper(II) complex of 3-cinnamalideneacetylacetone: Synthesis and characterisation · A Veeraraj P Sami N Raman · More Details Abstract ...

  16. Journal of Chemical Sciences | Indian Academy of Sciences

    Indian Academy of Sciences (India)

    Home; Journals; Journal of Chemical Sciences. A Kulandaisamy. Articles written in Journal of Chemical Sciences. Volume 113 Issue 3 June 2001 pp 183-189 Inorganic. Synthesis and characterisation of Cu(II), Ni(II), Mn(II), Zn(II) and VO(II) Schiff base complexes derived from o-phenylenediamine and acetoacetanilide.

  17. Manufacture, characterisation and properties of novel fluorcanasite glass-ceramics.

    Science.gov (United States)

    Pollington, Sarah; van Noort, Richard

    2012-11-01

    The aim of this study was to investigate the manufacture and characterisation of different compositions of fluorcanasite glass-ceramics with reduced fluorine content and to assess their mechanical and physical properties. Three compositional variations (S80, S81 and S82) of a fluorcanasite glass were investigated. Differential thermal analysis (DTA) and X-ray diffraction (XRD) identified crystallisation temperatures and phases. X-ray fluorescence (XRF) determined the element composition in the glass-ceramics. Different heat treatments [2 h nucleation and either 2 or 4 h crystallisation] were used for the glasses. Scanning electron microscopy (SEM) examined the microstructure of the cerammed glass. The chemical solubility, biaxial flexural strength, fracture toughness, hardness and brittleness index of S81 and S82 fluorcanasite were investigated with lithium disilicate (e.max CAD, Ivoclar Vivadent) as a commercial comparison. Statistical analysis was performed using one-way ANOVA with Tukey's multiple comparison tests (Pglasses. XRD analysis confirmed fluorcanasite formation with the S81 and S82 compositions, with the S82 (2+2h) showing the most prominent crystal structure. The chemical solubility of the glass-ceramics was significantly different, varying from 2565 ± 507 μg/cm(2) for the S81 (2+2 h) to 722 ± 177 μg/cm(2) for the S82 (2+2 h) to 37.4 ± 25.2 μg/cm(2) for the lithium disilicate. BFS values were highest for the S82 (2+2 h) composition (250 ± 26 MPa) and lithium disilicate (266 ± 37 MPa) glass-ceramics. The fracture toughness was higher for the S82 compositions, with the S82 (2+2h) attaining the highest value of 4.2 ± 0.3 MPa m(1/2)(P=0.01). The S82 (2+2 h) fluorcanasite glass-ceramic had the lowest brittleness index. The S82 (2+2 h) fluorcanasite glass-ceramic has acceptable chemical solubility, high biaxial flexural strength, fracture toughness and hardness. A novel glass-ceramic has been developed with potential as a restorative material. The

  18. Characterisation of commercial and natural Torulaspora delbrueckii wine yeast strains.

    Science.gov (United States)

    van Breda, Valmary; Jolly, Neil; van Wyk, Jessy

    2013-05-15

    Forty-three South African Torulaspora delbrueckii yeast isolates from the ARC Infruitec-Nietvoorbij yeast culture collection, the T. delbrueckii type strain (CBS 1146), one reference T. delbrueckii strain (CBS 4663), two T. delbrueckii strains isolated from commercial yeast blends (Viniflora® Harmony.nsac and Viniflora® Melody.nsac), and a commercial Saccharomyces cerevisiae yeast (VIN 13) had their identities confirmed and were characterised using conventional and molecular microbiological techniques. These included a selection of growth media as well as CHEF electrophoretic karyotyping and PCR-RFLP analyses. Based on the biochemical and physiological results the strains were divided into 13 groups. The performances of the yeasts were also monitored by means of laboratory-scale fermentations in grape must at 15 °C and 22 °C. The fermentation kinetic data showed that at 22 °C, the yeasts were divided into two distinct groups, a faster and a slower fermenting group. The fermentation curves of the laboratory-scale study at 15 °C showed that, at this lower temperature, the yeasts also fermented at different speeds, but the fermentation curves showed greater separation. The biochemical and physiological grouping did not coincide with the fermentation abilities and good fermenters could be found in more than one group. Chemical analyses of the resultant wines (alcohol, volatile acidity, glycerol, total SO2, residual sugar) were used in Principle Component Analyses. The yeasts that grouped close to the S. cerevisiae reference strain (VIN 13) showed more acceptable wine chemical profiles, while those further away displayed less acceptable profiles. Three locally isolated strains and one commercial T. delbrueckii yeast strain, Viniflora® Harmony.nsac. produced wines with acceptable chemical profiles at both temperatures. These strains also had comparable fermentation kinetics to the S. cerevisiae reference. Therefore, depending on the fermentation temperature

  19. Characterisation of fume from hyperbaric welding operations

    Energy Technology Data Exchange (ETDEWEB)

    Ross, John A S; Semple, Sean [Environmental and Occupational Medicine, University of Aberdeen (United Kingdom); Duffin, Rodger [ELEGI Colt Laboratory, University of Edinburgh (United Kingdom); Kelly, Frank [Lung Biology Group, Kings College, University of London (United Kingdom); Seldmann, Joerg; Raab, Andrea, E-mail: j.a.ross@abdn.ac.u [Trace Element Speciation Laboratory, University of Aberdeen (United Kingdom)

    2009-02-01

    We report preliminary work characterising dust from hyperbaric welding trials carried out at increased pressure in a helium and oxygen atmosphere. Particle size and concentration were measured during welding. Samples for quartz and metal analysis and toxicity assessment were taken from a filter in the local fume extraction system. The residue of dust after metal extraction by nitric acid in hydrogen peroxide predominantly a non-metallic white powder assumed to be dust from welding rod coatings and thermal insulation material. Metallic analysis showed predominantly calcium, from the welding rod coating, and period 4 transition metals such as iron, manganese, magnesium and titanium (inductively coupled mass spectrometry, Agilent 7500c). The presence of zirconium indicated a contribution from grinding. The fume was nanoparticulate in nature with a mean particle diameter of 20-30 nm (MSI Inc WPS 1000XP). It showed an intermediate level of oxidative potential regarding the low-molecular weight respiratory tract lining fluid antioxidants ascorbate and glutathione and caused release of the inflammatory marker IL-8 in a human lung A 549 epithelial cell culture with no indication of cytotoxicity. The study findings have strong implications for the measurement techniques needed to assess fume exposure in hyperbaric welding and the provision of respiratory protection.

  20. Characterising dye-sensitized solar cells

    Science.gov (United States)

    Tobin, Laura L.; O'Reilly, Thomas; Zerulla, Dominic; Sheridan, John T.

    2009-08-01

    With growing energy and environmental concerns due to fossil fuel depletion and global warming there is an increasing attention being attracted by alternative and/or renewable sources of power such as biomass, hydropower, geothermal, wind and solar energy. In today's society there is a vast and in many cases not fully appreciated dependence on electrical power for everyday life and therefore devices such as PV cells are of enormous importance. The more widely used and commercially available silicon (semiconductor) based cells currently have the greatest efficiencies, however the manufacturing of these cells is complex and costly due to the cost and difficulty of producing and processing pure silicon. One new direction being explored is the development of dye-sensitised solar cells (DSSC). The SFI Strategic Research Centre for Solar Energy Conversion is a new research cluster based in Ireland, formed with the express intention of bringing together industry and academia to produce renewable energy solutions. Our specific area of research is in biomimetic dye sensitised solar cells and their electrical properties. We are currently working to develop test equipment, and optoelectronic models describing the performance and behaviors of dye-sensitised solar cells (Grätzel Cells). In this paper we describe some of the background to our work and also some of our initial experimental results. Based on these results we intend to characterise the opto-electrical properties and bulk characteristics of simple dye-sensitised solar cells and then to proceed to test new cell compositions.

  1. Formulation and characterisation of valsartan proniosomes

    Directory of Open Access Journals (Sweden)

    Rao Rekha

    2011-04-01

    Full Text Available Non-ionic surfactant vesicles of valsartan, an angiotensin II inhibitor, were prepared by coacervation phase separation method. The prepared systems were characterised for encapsulation efficiency, shape, size and in vitro drug release. Stability study was carried out to investigate the leaching of drug from the proniosomal system during storage. The results showed that valsartan in all the formulations was successfully entrapped and a substantial change in release rate and an alteration in the encapsulation efficiency of valsartan from proniosomes were observed upon varying the type of surfactant and cholesterol content. The encapsulation efficiency of proniosomes prepared with Span 60 was superior to that prepared with Span 40. A preparation with 9:2:9 ratio of Span 60, cholesterol and lecithin gave maximum encapsulation efficiency (71.50% and release results (Q24h= 75% as compared to other compositions. Proniosomal formulations showed fairly high retention of valsartan inside the vesicles at refrigerated temperature (4-8oC up to 1 month.

  2. Characterisation of Supra- and Infratentorial ICP Profiles.

    Science.gov (United States)

    Moyse, Emmanuel; Ros, Maxime; Marhar, Fouad; Swider, Pascal; Schmidt, Eric Albert

    2016-01-01

    In pathophysiology and clinical practice, the intracranial pressure (ICP) profiles in the supratentorial and infratentorial compartments are unclear. We know that the pressure within the skull is unevenly distributed, with demonstrated ICP gradients. We recorded and characterised the supra- and infratentorial ICP patterns to understand what drives the transtentorial ICP gradient.A 70-year-old man was operated on for acute cerebellar infarction. One supratentorial probe and one cerebellar probe were implanted. Both signals were recorded concurrently and analysed off-line. We calculated mean ICP, ICP pulse amplitude, respiratory waves, slow waves and the RAP index of supra- and infratentorial ICP signals. Then, we measured transtentorial difference and performed correlation analysis for every index.Supratentorial ICP mean was 8.5 mmHg lower than infratentorial ICP, but the difference lessens for higher values. Both signals across the tentorium showed close correlation. Supra- and infratentorial pulse amplitude, respiratory waves and slow waves also showed a high degree of correlation. The compensatory reserve (RAP) showed good correlation. In this case report, we demonstrate that the mean value of ICP is higher in the posterior fossa, with a strong correlation across the tentorium. All other ICP-derived parameters display a symmetrical profile.

  3. CHARACTERISATION OF SOLID AND LIQUID PINEAPPLE WASTE

    Directory of Open Access Journals (Sweden)

    Abdullah Abdullah

    2011-07-01

    Full Text Available The pineapple waste is contain high concentration of biodegradable organic material and suspended solid. As a result it has a high BOD and extremes of pH conditions. The pineapple wastes juice contains mainly sucrose, glucose, fructose and other nutrients. The characterisation this waste is needed to reduce it by  recycling to get raw material or  for  conversion into useful product of higher value added products such as organic acid, methane , ethanol, SCP and enzyme. Analysis of sugar indicates that liquid waste contains mainly sucrose, glucose and fructose.  The dominant sugar was fructose, glucose and sucrose.  The fructose and glucose levels were similar to each other, with fructose usually slightly higher than glucose. The total sugar and citric acid content were 73.76 and 2.18 g/l. The sugar content in solid waste is glucose and fructose was 8.24 and 12.17 %, no sucrose on this waste

  4. Characterisation of aerosols produced by laser cutting

    International Nuclear Information System (INIS)

    Fauvel, S.; Pilot, G.; Dinechin, G. de; Gosse, X.; Arnaud, P.

    2007-01-01

    Powerful lasers represent a promising alternative solution to traditional cutting processes used in dismantling nuclear equipments. The use of optical fibers has an unquestionable advantage when dealing with airtight workshops. A study funded by COGEMA Marcoule was undertaken by IRSN/SERAC in collaboration with GIP/GERAILP in order to characterise the aerosols emitted by the cutting of evaporators elements with a 4 kW continuous wave Nd:YAG laser. For this study, laser cutting has been carried out in a tight room of 35 m 3 connected to a particle sampling pipe. Iso-kinetic samplers allowed the measurement of the aerosol concentration. A diffusional and inertial spectrometer (SDI 2001) - an Andersen impinger coupled to a diffusion battery - provided the size distribution. An electrostatic filter used upstream a HEPA filter, itself placed before the extractor fan, collected the majority of the emitted aerosol. Its efficiency was measured and controlled throughout the experiments. The results show the influence of the cutting conditions on the characteristics of the aerosol, and allow a comparison with other cutting tools. (authors)

  5. Characterisation of Ferrosilicon Dense Medium Separation Material

    International Nuclear Information System (INIS)

    Waanders, F. B.; Mans, A.

    2003-01-01

    Ferrosilicon is used in the dense medium separation of iron ore at Kumba resources, Sishen, South Africa. Due to high cost and losses that occur during use, maximum recovery by means of magnetic separation is aimed for. The purpose of this project was to determine the characteristics of the unused Fe-Si and then to characterise the changes that occur during storage and use thereof. Scanning electron microscopy was used to determine the composition of each sample, whilst Moessbauer spectroscopy yielded a two-sextet spectrum with hyperfine magnetic field strengths of 20 and 31 T, respectively, for the fresh samples. Additional hematite oxide peaks appeared in the Moessbauer spectra after use of the Fe-Si over a length of time, but this did not result in a dramatic degradation of the medium. No definite changes occurred during correct storage methods. It was, however, found that the biggest loss of Fe-Si was due to the abrasion of the particles, which resulted in the formation of an oxihydroxide froth, during the process.

  6. 3D characterisation of RCF crack networks

    Directory of Open Access Journals (Sweden)

    Ahlström Johan

    2014-06-01

    Full Text Available Rolling contact fatigue (RCF damage is becoming more frequent with increased traffic and loading conditions in the railway industry. Defects which are characterized by a two-lobe darkened surface and a V-shaped surface-breaking crack are often so-called squats. The origination and propagation of squats in railway rails is the topic of many recent studies; the associated crack networks develop with complicated geometry near the surface of rails that is difficult to characterise using most non-destructive methods. The cracks can be examined with repeated metallographic sectioning, but the process is time-consuming and destructive. In order to reduce time, as well as information and material loss, high-resolution and high-energy X-ray imaging of railway rails was done in the current study. Combining the exposures from a range of angles using image analysis, a 3D representation of the complex crack network is achieved. The latter was complemented with metallographic sectioning to determine the accuracy of prediction of the geometrical reconstruction.

  7. Commercial Charcoal Characterisation For Water Purification

    International Nuclear Information System (INIS)

    Saryati; Sumardjo; Sutisna; Handayani, Ari; Suprapti, Siti

    2001-01-01

    In order to provide a drinking water purification substance, has been studied the charcoal characterisation that based on a porous profile and an adsorption properties of the charcoal. There were using the commercial charcoal like wood charcoals, coconut shell charcoals and activated charcoals. The porous profile was studied by using an electron microscope SEM-EDX and the adsorption properties was studied by using the water sample simulation that contains several metal ions. The concentration of all ions was ten times greater that the maximum ions concentration that permissible in the drinking water. From the grain surface microscopic analysis was shown that the pore structure of the wood charcoal was more regular than the coconut shell charcoal. Mean while the activated charcoal has pore more than wood and coconut shell charcoal. Grains size was not an adsorption parameter. The absorptivitas charcoal was affected by pH solution, but this effect was not linear proportion. There are no significant deference in the adsorptivitas among the tree charcoals that has been studied for Al 3 + , Cr 3+ , Ag 1 +, and Pb 2+ ions the adsorption was large enough (> 60%), for Mn 2+ , Fe 3+ , Se 4+ , Cd 2+ and Ba 2+ ions was 20%-60% dan for Mg 2+ , Na 1+ , Ca 2+ , and Zn 2+ ions was less than 20 %. Generally the wood and coconut shell charcoal absorptivity in the pH 4 solutions was lower than in the pH 5-7 solutions

  8. Characterisation and stability evaluation of bixin nanocapsules.

    Science.gov (United States)

    Lobato, Kleidson Brito de Sousa; Paese, Karina; Forgearini, Joana Casanova; Guterres, Silvia Stanisçuaski; Jablonski, André; Rios, Alessandro de Oliveira

    2013-12-15

    The aim of this study was to produce bixin nanocapsules by the interfacial deposition of preformed poly-ε-caprolactone (PCL). PCL (250 mg), capric/caprylic triglyceride (400 μL), sorbitan monostearate (95 mg) and bixin were dissolved in a mixture of acetone (60 mL) and ethanol (7.5 mL) under stirring (40 °C). This organic solution was added to the aqueous solution (130 mL) containing Tween 80 (195 mg). The size distributions in the formulations with bixin concentration from 11 to 100 μg/mL were evaluated periodically during 3 weeks of storage at ambient temperature. The optimal formulation (bixin concentration of 16.92±0.16 μg/mL) was characterised in terms of particle size distribution, zeta potential, bixin content and encapsulation efficiency, and showed a volume-weighted mean diameter (D4,3) of 195±27 nm, around 100% of encapsulation efficiency and the nanocapsules were considered physically stable during 119 days of storage at ambient temperature. Copyright © 2013 Elsevier Ltd. All rights reserved.

  9. Characterising risk - aggregated metrics: radiation and noise

    International Nuclear Information System (INIS)

    Passchier, W.

    1998-01-01

    The characterisation of risk is an important phase in the risk assessment - risk management process. From the multitude of risk attributes a few have to be selected to obtain a risk characteristic or profile that is useful for risk management decisions and implementation of protective measures. One way to reduce the number of attributes is aggregation. In the field of radiation protection such an aggregated metric is firmly established: effective dose. For protection against environmental noise the Health Council of the Netherlands recently proposed a set of aggregated metrics for noise annoyance and sleep disturbance. The presentation will discuss similarities and differences between these two metrics and practical limitations. The effective dose has proven its usefulness in designing radiation protection measures, which are related to the level of risk associated with the radiation practice in question, given that implicit judgements on radiation induced health effects are accepted. However, as the metric does not take into account the nature of radiation practice, it is less useful in policy discussions on the benefits and harm of radiation practices. With respect to the noise exposure metric, only one effect is targeted (annoyance), and the differences between sources are explicitly taken into account. This should make the metric useful in policy discussions with respect to physical planning and siting problems. The metric proposed has only significance on a population level, and can not be used as a predictor for individual risk. (author)

  10. New Device for Characterisation of Thermoforming and Blow Moulding Materials by Membrane Inflation

    DEFF Research Database (Denmark)

    Kjær, Erik Michael; Lauridsen, Carsten Linding

    1998-01-01

    New Device for Characterisation of Thermoforming and Blow Moulding Materials by Membrane Inflation......New Device for Characterisation of Thermoforming and Blow Moulding Materials by Membrane Inflation...

  11. Geochemical and Sr-Nd-Pb isotope characteristics of the Miocene to Pliocene volcanic rocks from the Kandilli (Erzurum) area, Eastern Anatolia (Turkey): Implications for magma evolution in extension-related origin

    Science.gov (United States)

    Kaygusuz, Abdullah; Aslan, Zafer; Aydınçakır, Emre; Yücel, Cem; Gücer, Mehmet Ali; Şen, Cüneyt

    2018-01-01

    This paper presents Sr-Nd-Pb isotopic and whole-rock geochemical data of Miocene to Pliocene volcanic rocks in the Eastern Anatolia (Turkey) aiming to unravel their sources and evolutionary history. The wide compositional range of lavas and pyroclastics includes basaltic andesite, basaltic trachyandesite, trachyandesite, andesite and trachydacite. These calc-alkaline volcanics are enriched in large ion lithophile elements and light rare earth elements and depleted in the high field strength elements. Sr-Nd isotope data indicate low values for 87Sr/86Sr(i) (0.70432-0.70464) and high values for 143Nd/144Nd(i) (0.51272-0.51282). Further, these data are within the mantle array of the isotope ratio diagram. The lead (Pb) isotopic compositions (206Pb/204Pb(i) = 18.33 to 18.62, 207Pb/204Pb(i) = 15.51 to 15.60, 208Pb/204Pb(i) = 38.10 to 38.45) reveals the presence of an enriched source. The main petrological processes involved fractional crystallization and the mixing of at least two fractionated magmas having same source characteristics. All evidence supports the findings that the Kandilli volcanic rocks were derived from a partial melting of the both spinel and garnet bearing subcontinental lithospheric mantle, which had been previously metasomatized by mostly fluids derived from subducted slab during the collisional and post-collisional extension-related geodynamic setting in the Eastern Anatolia region of Turkey.

  12. Geoelectrical and hydrogeochemical characterisation of the ...

    African Journals Online (AJOL)

    All the analysed chemical elements had concentrations that were within the WHO permissible levels with the exception of very few boreholes showing relatively high nitrate and total iron concentrations. The study concluded that the study area was characterized by both the weathered layer and partly weathered/fractured ...

  13. Phosphogypsum surface characterisation using scanning electron microscopy

    Directory of Open Access Journals (Sweden)

    Rajković Miloš B.

    2003-01-01

    Full Text Available This paper presents the results of application of Scanning Electron Microscopy (SEM to examinations of the samples of natural gypsum and phosphogypsum. Phosphogypsum has a well developed crystalline structure, and appear in two polymorphous forms, of rombic and hexagonal shape crystals. Natural gypsum has a poorly crystalline structure. The differences in crystalline structure influence the chemical behavior of these row materials.

  14. Characterisation and applications of synthesised cation exchanger ...

    African Journals Online (AJOL)

    The chemically modified guar gum sulphonic acid (GSA) resin was used for removal and pre-concentration of Zn2+, Cd2+, Fe2+, Pb2+ and Cu2+ ions in aqueous solutions and steel industry effluent from Jodhpur, India. This type of ion exchange resin represents a new class of hybrid ion exchangers with higher stability, ...

  15. Preparation and characterisation of activated carbon

    International Nuclear Information System (INIS)

    Badri bin Muhammad; Karen binti Badri; Mohd Zobir bin Hussein; Zulkarnain bin Zainal; W.M. Daud bin W Yunus; Ramli bin Ibrahim

    1994-01-01

    Activated carbon was prepared from Agricultural wastes, such as coconut shell, Palm oil Shell and mangrove trunk by destructive distillation under vakuum. Chemical and Physical properties of the activated carbon were studied and some potentially useful application in the fields of chemistry was also carried out

  16. Magnetooptical garnet films: preparation, characterisation, application

    International Nuclear Information System (INIS)

    Goernert, P.; Lorenz, A.; Lindner, M.; Richert, H.

    2007-01-01

    Full text: In contemporary magnetooptics both Kerr effect and Faraday effect are applied. The Kerr effect of metals and alloys - such as Fe, Ni, Co, FePt, CoPt, MnBi, PtMnSb - with thicknesses 300 μm are established as commercial isolators in optical systems and for developments of waveguide applications. Bi-REIG is prepared mostly by conventional liquid phase epitaxy (LPE) in PbO-B 2 O 3 -Bi 2 O 3 based solvents and sometimes by laser ablation and as nanocrystalline powders. In each case high Faraday rotation and low optical absorption is necessary. Additionally, magnetooptical sensors should possess high sensitivity and a large dynamic range. All these demands can be fulfilled with (REBi) 3 (FeGaAl) 5 O 12 LPE layers. Here we discuss some new results concerning preparation, characterisation, and application of Bi-TmIG and Bi-DyIG LPE layers on high-quality gadolinium gallium garnet (GGG) or lattice matched Ca-, Mg-, Zr-substituted GGG substrates. Optimization of flux melt composition and under cooling result in sensor films with a Faraday rotation of e.g. -1.2 0 /μm at a wavelength of l=590 nm and saturation induction of Bs=70 mT. Such films are already applied for forensic investigations. However, the responsivity of the garnet films is restricted by their coercivity Hc. Surface defects are found to give rise to pinned magnetic domains correlated with typical hysteresis. Obviously, Hc and the formation of pits are due to misfit stress and substrate surface quality. Besides, it is shown that an increase of working temperature leads to smaller coercivities. (authors)

  17. Fast quantitative characterisation of differential mobility responses.

    Science.gov (United States)

    Veasey, Catherine A; Thomas, C L P

    2004-03-01

    A chromatography-based method for producing mass flux-response surfaces for differential mobility spectrometers is described as a replacement for exponential dilution and mixing approaches. An exponential dilution or mixing experiment typically takes 150 min; while the exponential function in the Gaussian elution profile obtained from linear chromatography may be exploited in approximately 10 s. The approach was demonstrated with a gas chromatograph-mass spectrometer and the correlation of the calibration results to nominal on-column masses was within experimental error for 19 separate analyses. The method was then applied to a gas chromatographic (10.6 eV UV) differential mobility spectrometer. Mass fluxes in the range 10 pg s(-1) to 250 ng s(-1) were generated over the 5 s to 10 s associated with the elution of a chromatographic peak. The characterisations were repeated for a range of electrical field strengths from 10 kV cm(-1) to 30 kV cm(-1). Triplicate runs indicated that the approach was reproducible and that response surfaces could be generated rapidly from chromatographic data. The effects of trace impurities associated with the chromatographic eluent on the relationship between compensation voltage and electrical field strength was observed. This emphasised the importance of managing this aspect of the operation if reliable estimates of alpha functions for the compounds under study were to be obtained. Application of this approach to other detection systems with an 85% reduction in the analytical operations required to produce a reliable calibration function was also noted.

  18. Sources, isolation, characterisation and evaluation of probiotics.

    Science.gov (United States)

    Fontana, Luis; Bermudez-Brito, Miriam; Plaza-Diaz, Julio; Muñoz-Quezada, Sergio; Gil, Angel

    2013-01-01

    According to the FAO and the WHO, probiotics are 'live microorganisms which, when administered in adequate amounts, confer a health benefit on the host'. The strains most frequently used as probiotics include lactic acid bacteria and bifidobacteria, which are isolated from traditional fermented products and the gut, faeces and breast milk of human subjects. The identification of microorganisms is the first step in the selection of potential probiotics. The present techniques, including genetic fingerprinting, gene sequencing, oligonucleotide probes and specific primer selection, discriminate closely related bacteria with varying degrees of success. Additional molecular methods, such as denaturing gradient gel electrophoresis/temperature gradient gel electrophoresis and fluorescence in situ hybridisation, are employed to identify and characterise probiotics. The ability to examine fully sequenced genomes has accelerated the application of genetic approaches to the elucidation of the functional roles of probiotics. One of the best-demonstrated clinical benefits of probiotics is the prevention and treatment of acute and antibiotic-associated diarrhoea;however, there is mounting evidence for a potential role for probiotics in the treatment of allergies and intestinal, liver and metabolic diseases. There are various mechanisms by which probiotics exert their beneficial effects: regulation of intestinal permeability, normalisation of host intestinal microbiota, improvement of gut immune barrier function, and adjustment between pro- and anti-inflammatory cytokines. The number of studies carried out to test the effects of probiotics in vitro and in animals is enormous. However, the most reliable method of assessing the therapeutic benefits of any probiotic strain is the use of randomised, placebo-controlled trials, which are reviewed in this article [corrected].

  19. Characterisation and outcomes of upper extremity amputations.

    Science.gov (United States)

    Tennent, David J; Wenke, Joseph C; Rivera, Jessica C; Krueger, Chad A

    2014-06-01

    The purpose of this study is to characterise the injuries, outcomes, and disabling conditions of the isolated, combat-related upper extremity amputees in comparison to the isolated lower extremity amputees and the general amputee population. A retrospective study of all major extremity amputations sustained by the US military service members from 1 October 2001 to 30 July 2011 was conducted. Data from the Department of Defense Trauma Registry, the Armed Forces Health Longitudinal Technology Application, and the Physical Evaluation Board Liaison Offices were queried in order to obtain injury characteristics, demographic information, treatment characteristics, and disability outcome data. A total of 1315 service members who sustained 1631 amputations were identified; of these, 173 service members were identified as sustaining an isolated upper extremity amputation. Isolated upper extremity and isolated lower extremity amputees had similar Injury Severity Scores (21 vs. 20). There were significantly more non-battle-related upper extremity amputees than the analysed general amputation population (39% vs. 14%). Isolated upper extremity amputees had significantly greater combined disability rating (82.9% vs. 62.3%) and were more likely to receive a disability rating >80% (69% vs. 53%). No upper extremity amputees were found fit for duty; only 12 (8.3%) were allowed continuation on active duty; and significantly more upper extremity amputees were permanently retired than lower extremity amputees (82% vs. 74%). The most common non-upper extremity amputation-related disabling condition was post-traumatic stress disorder (PTSD) (17%). Upper extremity amputees were significantly more likely to have disability from PTSD, 13% vs. 8%, and loss of nerve function, 11% vs. 6%, than the general amputee population. Upper extremity amputees account for 14% of all amputees during the Operation Enduring Freedom and Operation Iraqi Freedom conflicts. These amputees have significant

  20. Electronic cigarettes: product characterisation and design considerations.

    Science.gov (United States)

    Brown, Christopher J; Cheng, James M

    2014-05-01

    To review the available evidence regarding electronic cigarette (e-cigarette) product characterisation and design features in order to understand their potential impact on individual users and on public health. Systematic literature searches in 10 reference databases were conducted through October 2013. A total of 14 articles and documents and 16 patents were included in this analysis. Numerous disposable and reusable e-cigarette product options exist, representing wide variation in product configuration and component functionality. Common e-cigarette components include an aerosol generator, a flow sensor, a battery and a nicotine-containing solution storage area. e-cigarettes currently include many interchangeable parts, enabling users to modify the character of the delivered aerosol and, therefore, the product's 'effectiveness' as a nicotine delivery product. Materials in e-cigarettes may include metals, rubber and ceramics. Some materials may be aerosolised and have adverse health effects. Several studies have described significant performance variability across and within e-cigarette brands. Patent applications include novel product features designed to influence aerosol properties and e-cigarette efficiency at delivering nicotine. Although e-cigarettes share a basic design, engineering variations and user modifications result in differences in nicotine delivery and potential product risks. e-cigarette aerosols may include harmful and potentially harmful constituents. Battery explosions and the risks of exposure to the e-liquid (especially for children) are also concerns. Additional research will enhance the current understanding of basic e-cigarette design and operation, aerosol production and processing, and functionality. A standardised e-cigarette testing regime should be developed to allow product comparisons.

  1. Gas flare characterisation with Sentinel-3

    Science.gov (United States)

    Caseiro, Alexandre; Kaiser, Johannes W.; Ruecker, Gernot; Tiemann, Joachim; Leimbach, David

    2017-04-01

    Gas Flaring (GF) is the process of burning waste gases at the tip of a stack. It is widely used in the upstream oil and gas industry. It is a contributor to the imbalance of the greenhouse gases (GHG) concentration in the earth's atmosphere, which prompts global warming. Besides GHG, GF also emits black carbon (BC), a known carcinogen and climate active species. At higher latitudes, GF has been estimated as the main input of atmospheric BC, alongside vegetation fires. The consideration of GF as a source to global budgets has been hindered by technical difficulties of in-situ measurements and the inexistence of a systematic reporting system. Remote sensing offers the possibility of a continuous, global and systematic monitoring of GF over extended periods. Being a high temperature process, GF can be detected from space using measurements at appropriate wavelengths. Considering 1800K as a typical GF temperature and Wien's displacement law, the peak emission will be in the short-wave infrared region. This spectral region is observed by two channels (S5 and S6) of the SLSTR instrument aboard ESA's newly launched Sentinel-3 satellite. Because of solar contamination, only night-time observations are used. In order to characterise the identified gas flares in terms of temperature and area, two Planck curves are fitted to SLSTR radiance observations in five spectral channels (S5 through S9, with F1 and F2). In this work, we present the methodology in detail as well as results for known flaring regions around the world. A comparison with VIIRS on Suomi-NPP and with HSRS on TET-1 over known GF locations is also considered.

  2. [Characterisation of Suicide in Colombia, 2000 2010].

    Science.gov (United States)

    Cardona Arango, Doris; Medina-Pérez, Óscar Adolfo; Cardona Duque, Deisy Viviana

    2016-01-01

    Suicide is a serious public health problem worldwide, affecting all population groups, regardless of age, gender, or area of residence. The aim of this investigation was to characterise the recorded suicides in Colombia, between the years 2000 and 2010, according to the variables of the person, time and place. Descriptive quantitative study with information from secondary sources, from the death certificates of deceased people by suicide registered with the National Bureau of Statistics. The behaviour of the deaths and mortality, were determined using the denominator population projections of Colombia and the Amazon, Andean, Atlantic Coast, Eastern Plains and Pacific regions. Descriptive measurements and mortality rates were calculated using these. A total of 24,882 suicides were recorded in the eleven years studied, with a mean of 6.2 people per day, which increased to 8.0 during holidays The mean age of death was 34.5 years (men 36.4, women 27.7), with male deaths (78.1%) and urban areas (66%) predominating. The greatest risk of dying from this cause was recorded in the Eastern Plains, in young adults and seniors, and residents in rural areas. Suicide rates in Colombia show a downward trend, with a mean of 5.3/100,000 inhabitants, and with an increased risk in men (3.7 times the risk in women, in young adults (9/100,000). A higher death rate was recorded in single people in the months of December and January, and at weekends. Copyright © 2015 Asociación Colombiana de Psiquiatría. Publicado por Elsevier España. All rights reserved.

  3. Forsmark site characterisation - Borehole KFM22 and KFM23: Derivation of porewater data by diffusion experiments

    Energy Technology Data Exchange (ETDEWEB)

    Waber, H. N. [Rock Water Interaction, University of Bern, Bern (Switzerland); Smellie, J. A. T. [Conterra AB, Partille (Sweden)

    2012-04-15

    Within the Detum Project (Detailed Investigations in Forsmark) a 'Methodology comparison for porewater extraction and characterisation techniques' was initiated. This has centred on two shallow boreholes drilled at Soederviken within the northern part of the Forsmark characterisation site. The comparison includes different methodologies to characterise the chemical and isotopic composition of porewater residing in the connected pore space of the rock matrix. The present report describes the chemical and isotopic information of the porewater obtained by out-diffusion experiments and the diffusive isotope equilibration technique applied to originally water saturated drillcore samples. In addition, petrophysical data and solute transport properties of the rock matrix, all necessary for porewater characterisation, have also been elaborated. Specially conditioned drillcore samples were obtained from depths of less than 100 m from boreholes KFM22 and KFM23. Porewater has been extracted successfully from seven samples by laboratory out-diffusion and diffusive isotope exchange methods. The methodology to extract and analyse the porewater is outlined and the analytical data are tabulated. The data are critically reviewed for potential experimental artefacts and their significance with respect to in situ conditions. The connected pore space in the core material representing borehole KFM22 and KFM23 was measured on different types of originally saturated drillcore samples using gravimetric and isotope mass balance methods. Out-diffusion experiments were performed on kg-sized drillcore samples to derive the in situ concentration of the chemically conservative compounds chloride and bromide. The attainment of equilibrium conditions in the out-diffusion experiments was monitored by the concentration change of chloride and bromide as a function of time. The water isotope composition of porewater was determined by the diffusive isotope equilibration technique and by

  4. History of radiological characterisation in Studsvik - History of radiological characterisation in decommissioning projects in Studsvik

    International Nuclear Information System (INIS)

    Hedvall, Robert

    2012-01-01

    AB SVAFO is a nuclear waste technology and decommissioning company based in Sweden in the scenic surroundings of Studsvik on the Baltic coast. SVAFO is owned by the Swedish nuclear power industry. The company was created in 1992 by Sydsvenska Vaermekraft AB, Vattenfall AB, Forsmarks Kraftgrupp AB and Oskarshamns Kraftgrupp AB as a consequence of the Act on the Financing of the Management of Certain Radioactive Waste etc, from 1988. AB SVAFO's main business is to take care of formerly state-owned spent nuclear waste at the site, including small amounts of nuclear fuel. Buildings are also included, mainly nuclear waste storage buildings and a research reactor. Some buildings have already been decommissioned and all the fuel is treated. In the past 30 years, various decommissioning projects have been carried out, encompassing areas such as an underground research reactor, a Van de Graaff accelerator, 15,000 m 2 of nuclear laboratories, two 150 m 3 underground concrete sludge silos and several waste-storage buildings. Up till now only one or two persons did a simple characterisation before the project started to get the level of contamination. With the start of the decommissioning of the former uranium mine in Ranstad and the R2-reactor, more efforts have been put for the characterisation. The change in methods will be described. (author)

  5. Characterisation of high dose aerosols from dry powder inhalers

    NARCIS (Netherlands)

    Grasmeijer, Floris; Hagedoorn, Paul; Frijlink, Henderik W; de Boer, Anne H

    2012-01-01

    Developments in high dose dry powder aerosol delivery will increasingly challenge the applicability of currently used aerosol characterisation techniques. With cascade impaction analysis bounce effects can negatively influence stage collection efficiency, especially with increasing impactor loads.

  6. Scanning Anode Field Emission Characterisation of Carbon Nanotube emitter arrays

    NARCIS (Netherlands)

    Berhanu, S.; Gröning, O.; Chen, Z.; Merikhi, J.; Bachmann, P.K.

    2011-01-01

    Scanning anode field emission microscopy (SAFEM) was used to characterise carbon nanotube (CNT) emitter arrays produced within Philips CediX-Technotubes' activities. Four different samples were investigated and compared. The field enhancement distributions were determined and the local field

  7. A continuum mechanics analysis of shear characterisation methods

    NARCIS (Netherlands)

    Akkerman, Remko

    2018-01-01

    The shear response of fabrics and fabric reinforced materials is primarily characterised by means of Picture Frame and Bias Extension experiments. Normalisation methods have been proposed earlier to enable comparison between different measurement results. Here, a continuum mechanics based analysis

  8. Characterisation of Staphylococcus aureus bacteraemia at Tygerberg hospital

    NARCIS (Netherlands)

    Orth, H.; Dreyer, Z.S.; Makgotlho, E.; Oosthuysen, W.; Sinha, B.; Wasserman, E.

    2013-01-01

    To elucidate the local epidemiology of Staphylococcus aureus bacteraemia, we characterised blood culture isolates using molecular methods and prospectively collected clinical data to determine the occurrence of community-acquired, methicillinresistant S. aureus (MRSA). Consecutive S. aureus blood

  9. Sulfate reduction controlled by organic matter availability in deep sediment cores from the saline, alkaline Lake Van (Eastern Anatolia, Turkey

    Directory of Open Access Journals (Sweden)

    Clemens eGlombitza

    2013-07-01

    Full Text Available As part of the International Continental Drilling Program (ICDP deep lake drilling project PaleoVan, we investigated sulfate reduction (SR in deep sediment cores of the saline, alkaline (salinity 21.4 ‰, alkalinity 155 m mEq-1, pH 9.81 Lake Van, Turkey. The cores were retrieved in the Northern Basin (NB and at Ahlat Ridge (AR and reached a maximum depth of 220 m. Additionally, 65-75 cm long gravity cores were taken at both sites. Sulfate reduction rates (SRR were low (≤ 22 nmol cm-3 d-1 compared to lakes with higher salinity and alkalinity, indicating that salinity and alkalinity are not limiting SR in Lake Van. Both sites differ significantly in rates and depth distribution of SR. In NB, SRR are up to 10 times higher than at AR. Sulfate reduction (SR could be detected down to 19 meters below lake floor (mblf at NB and down to 13 mblf at AR. Although SRR were lower at AR than at NB, organic matter (OM concentrations were higher. In contrast, dissolved OM in the pore water at AR contained more macromolecular OM and less low molecular weight OM. We thus suggest, that OM content alone cannot be used to infer microbial activity at Lake Van but that quality of OM has an important impact as well. These differences suggest that biogeochemical processes in lacustrine sediments are reacting very sensitively to small variations in geological, physical or chemical parameters over relatively short distances. 

  10. Elaboration and characterisation of plutonium waste reference materials

    International Nuclear Information System (INIS)

    Perolat, J.P.

    1990-01-01

    The Analysis Methods Establishment Commission (CETAMA) has set up a program for the elaboration and characterisation of plutonium waste reference materials. The object of this program is to give laboratories the possibility to test and calibrate apparatus used in non-destructive methods for the analysis of plutonium waste. The different parameters of this program are presented: - characterisation of plutonium, - type and number of containers, - plutonium distribution inside the different containers, - description of the matrix

  11. Characterisation of COPD heterogeneity in the ECLIPSE cohort

    DEFF Research Database (Denmark)

    Agusti, Alvar; Calverley, Peter M A; Celli, Bartolome

    2010-01-01

    Chronic obstructive pulmonary disease (COPD) is a complex condition with pulmonary and extra-pulmonary manifestations. This study describes the heterogeneity of COPD in a large and well characterised and controlled COPD cohort (ECLIPSE).......Chronic obstructive pulmonary disease (COPD) is a complex condition with pulmonary and extra-pulmonary manifestations. This study describes the heterogeneity of COPD in a large and well characterised and controlled COPD cohort (ECLIPSE)....

  12. The characterisation of vapour-phase alkali metal-tellurium-oxygen species

    International Nuclear Information System (INIS)

    Gomme, R.A.; Ogden, J.S.; Bowsher, B.R.

    1986-10-01

    Detailed assessments of hypothetical severe accidents in light water reactors require the identification of the chemical forms of the radionuclides in order to determine their transport characteristics. Caesium and tellurium are important volatile fission products in accident scenarios. This report describes detailed studies to characterise the chemical species that vaporise from heated mixtures of various alkali metal-tellurium-oxygen systems. The molecular species were characterised by a combination of quadrupole mass spectrometry and matrix isolation-infrared spectroscopy undertaken in conjunction with experiments involving oxygen-18 substitution. The resulting spectra were interpreted in terms of a vapour-phase molecule with the stoichiometry M 2 TeO 3 (M = K,Rb,Cs) for M/Te molecular ratios of ∼ 2, and polymeric species for ratios < 2. This work has demonstrated the stability of caesium tellurite. The formation of this relatively low-volatility, water-soluble species could significantly modify the transport and release of caesium and tellurium. The data presented in this report should allow more comprehensive thermodynamic calculations to be undertaken that assist in the quantification of fission product behaviour during severe reactor accidents. (author)

  13. Age and duration of intra-oceanic arc volcanism built on a suprasubduction zone type oceanic crust in southern Neotethys, SE Anatolia

    Directory of Open Access Journals (Sweden)

    Fatih Karaoğlan

    2013-07-01

    Full Text Available The southeastern Anatolia comprises numbers of tectono-magmatic/stratigraphic units such as the metamorphic massifs, the ophiolites, the volcanic arc units and the granitoid rocks. All of them play important role for the late Cretaceous evolution of the southern Neotethys. The spatial and temporal relations of these units suggest the progressive development of coeval magmatism and thrusting during the late Cretaceous northward subduction/accretion. Our new U-Pb zircon data from the rhyolitic rocks of the wide-spread volcanic arc unit show ages of (83.1 ± 2.2–(74.6 ± 4.4 Ma. Comparison of the ophiolites, the volcanic arc units and the granitoids suggest following late Cretaceous geological evolution. The ophiolites formed in a suprasubduction zone (SSZ setting as a result of northward intra-oceanic subduction. A wide-spread island-arc tholeiitic volcanic unit developed on the top of the SSZ-type crust during 83–75 Ma. Related to regional plate convergence, northward under-thrusting of SSZ-type ophiolites and volcanic arc units was initiated beneath the Tauride platform (Malatya-Keban and followed by the intrusion of I-type calc-alkaline volcanic arc granitoids during 84–82 Ma. New U-Pb ages from the arc-related volcanic-sedimentary unit and granitoids indicate that under-thrusting of ophiolites together with the arc-related units beneath the Malatya-Keban platform took place soon after the initiation of the volcanic arc on the top of the SSZ-type crust. Then the arc-related volcanic-sedimentary unit continued its development and lasted at ∼75 Ma until the deposition of the late Campanian–Maastrichtian shallow marine limestone. The subduction trench eventually collided with the Bitlis-Pütürge massif giving rise to HP-LT metamorphism of the Bitlis massif. Although the development of the volcanic arc units and the granitoids were coeval at the initial stage of the subduction/accretion both tectono-magmatic units were

  14. Superimposed basin formation during Neogene-Quaternary extensional tectonics in SW-Anatolia (Turkey): Insights from the kinematics of the Dinar Fault Zone

    Science.gov (United States)

    Alçiçek, M. Cihat; Brogi, Andrea; Capezzuoli, Enrico; Liotta, Domenico; Meccheri, Marco

    2013-11-01

    In the extensional province of SW-Anatolia, the cross-cutting relationship between the NW- and NE-oriented Neogene and Quaternary basins is an ongoing debate in the understanding of the tectonic evolution of this area. In order to contribute to this issue, we carried out a structural and kinematic study along the seismogenic NW-trending Dinar Fault Zone (DFZ). This structure was initially controlled by the sedimentary and tectonic evolution of the NE-oriented Neogene Baklan, Acıgöl and Burdur basins and, later, by the NW-oriented Quaternary Dinar Basin. On the basis of > 1000 structural and kinematic data, in conjunction with basin stratigraphy, the DFZ can be divided into three almost parallel and continuous bands, that are: (a) the Hangingwall where Quaternary sediments are deformed by normal faults with mechanical striations; (b) the Inner Zone, corresponding to the present Dinar fault scarp, where NW-trending normal faults with mechanical striations are dominant, and (c) the Outer Zone, located in the footwall of the structure comprising the area between the fault scarp and undeformed bedrock, where faults exhibit variable orientation and kinematics, from strike-slip to normal dip-slip. These kinematics are mainly indicated by calcite shear veins and superimposed mechanical striations, respectively. This suggests that the DFZ changed kinematics over time, i.e., the DFZ initiated as dominant dextral strike-slip to oblique-slip fault system and continued with a dominant normal movement. Therefore, we hypothesize that the NW-trending DFZ was initially a transfer zone during the late Miocene-Pliocene, coeval to the sedimentary and structural evolution of the NE-trending Baklan, Acigöl and Burdur basins. During the Quaternary the DFZ, representing an already weakened crustal sector, played the role of a normal fault system providing the accommodation space for the Quaternary Dinar Basin. Hydrothermal circulation and volcanism at NE-/NW-trending faults

  15. Characterisation of the volatile profile of coconut water from five varieties using an optimised HS-SPME-GC analysis.

    Science.gov (United States)

    Prades, Alexia; Assa, Rebecca Rachel Ablan; Dornier, Manuel; Pain, Jean-Pierre; Boulanger, Renaud

    2012-09-01

    Coconut (Cocos nucifera L.) water is a refreshing tropical drink whose international market has recently been growing. However, little is yet known about its physicochemical composition, particularly its aroma. This study set out to characterise the volatile profile of water from five coconut varieties. Aroma compounds were characterised by headspace solid phase microextraction gas chromatography (HS-SPME-GC) analysis. An experimental design was established to optimise SPME conditions, leading to an equilibration time of 10 min followed by an extraction time of 60 min at 50 °C. Accordingly, immature coconut water from WAT (West African Tall), PB121 (MYD × WAT Hybrid), MYD (Malayan Yellow Dwarf), EGD (Equatorial Guinea Green Dwarf) and THD (Thailand Aromatic Green Dwarf) palms was analysed and described. Ketones were mainly present in the Tall and Hybrid varieties, whereas aldehydes were most abundant in the Dwarf palms. Tall coconut water was characterised by a high lactone content. THD exhibited a high ethyl octanoate level. The cluster analysis of the volatile fraction from the five coconut cultivars was found to be related to their genetic classification. The volatile compounds of immature coconut water from five varieties were characterised for the first time. Volatile profile analysis could be a useful tool for the selection of Dwarf coconut varieties, which are mainly consumed as a beverage. Copyright © 2012 Society of Chemical Industry.

  16. Characterisation of the Redox Sensitive NMDA Receptor

    KAUST Repository

    Alzahrani, Ohood

    2016-05-01

    Glucose entry into the brain and its subsequent metabolism to L-lactate, regulated by astrocytes, plays a major role in synaptic plasticity and memory formation. A recent study has shown that L-lactate produced by the brain upon stimulation of glycolysis, and glycogen-derived L-lactate from astrocytes and its transport into neurons, is crucial for memory formation. A recent study revealed the molecular mechanisms that underlie the role of L-lactate in neuronal plasticity and long-term memory formation. L-lactate was shown to induce a cascade of molecular events via modulation of redox-sensitive N-Methyl-D-aspartate (NMDA) receptor activity that was mimicked by nicotinamide adenine dinucleotide hydride (NADH) co-enzyme. This indicated that changes in cellular redox state, following L-lactate transport inside the cells and its subsequent metabolism, production of NADH, and favouring a reduced state are the key effects of L-lactate. Therefore, we are investigating the role of L-lactate in modulating NMDA receptor function via redox modulatory sites. Accordingly, crucial redox-sensitive cysteine residues, Cys320 and Cys87, of the NR2A NMDA receptor subunit are mutated using site-directed mutation, transfected, and expressed in HEK293 cells. This cellular system will then be used to characterise and monitor its activity upon Llactate stimulation, compared to the wild type. This will be achieved by calcium imaging, using fluorescent microscopy. Our data shows that L-lactate potentiated NMDA receptor activity and increased intracellular calcium influx in NR1/NR2A wild type compared to the control condition (WT NR1/NR2A perfused with (1μM) glutamate and (1μM) glycine agonist only), showing faster response initiation and slower decay rate of the calcium signal to the baseline. Additionally, stimulating with L-lactate associated with greater numbers of cells having high fluorescent intensity (peak amplitude) compared to the control. Furthermore, L-lactate rescued the

  17. Non-allergic cutaneous reactions in airborne chemical sensitivity--a population based study

    DEFF Research Database (Denmark)

    Berg, Nikolaj Drimer; Linneberg, Allan; Thyssen, Jacob Pontoppidan

    2011-01-01

    Multiple chemical sensitivity (MCS) is characterised by adverse effects due to exposure to low levels of chemical substances. The aetiology is unknown, but chemical related respiratory symptoms have been found associated with positive patch test. The purpose of this study was to investigate the r...

  18. Transmission electron microscopy characterisation of 0-D nanomaterials

    Science.gov (United States)

    Turner, Stuart Matthew

    When materials are scaled down to the nanometre level, a change in physical behaviour is frequently observed. In so-called 0-D nanomaterials (nanoparticles), these unique nanoscale properties are most abundant and are usually linked to either a change in (electronic) structure of the material or to the dominating influence of the particle surface at the nanometre scale. In this doctoral work the nanoscale properties of several nanoparticle systems have been studied using advanced transmission electron microscopy (TEM). Every material that was studied required for its solution a unique approach and a host of transmission electron microscopy techniques. The title of this doctoral work can be freely translated as "retrieving quantitatively the maximal and most accurate chemical, structural and morphological information from nanoparticles by advanced transmission electron microscopy, to uncover and explain their unique properties". Chapter 1 gives a brief general introduction to the world of nanomaterials and nanotechnology in general and more specifically to 0-D nanomaterials (nanoparticles). The unique properties and potential applications of these materials are described. The production of 0-D nanomaterials is not covered in this chapter, as this is an extremely broad field to cover in only a few pages. Instead, the production method for each of the materials is left to the detailed chapters that follow. In Chapter 2 the main transmission electron microscopy techniques used to characterise the materials in the further chapters are described together with the microscopes used to perform these techniques and their parameters of operation. Again, the sample-specific setups are listed in the detailed chapters that follow. Chapter 3 covers all work carried out on luminescent detonation nanodiamond powder for drug delivery and bio-medical imaging applications. Specific attention is paid to the morphology, surface chemistry and nitrogen incorporation of detonation

  19. Nanostructural characterisation of catalysts by SANS

    International Nuclear Information System (INIS)

    De Stefanis, A.; Tomlinson, A.A.G.; Steriotis, Th.A.; Stefanopoulos, K.L.; Keiderling, U.

    2004-01-01

    A series of restructured clays used as catalysts in small- and large-scale chemical reactions, have been studied by small-angle neutron scattering (SANS). Analysis of the spectra provides detailed information both on the nanopore structure and the surface texture of these materials. Additionally, pillared inter-layered clays (PILCs) have a great potential for industrial utilisation in catalysis, sorption and separations. PILCs have been studied with contrast-matching SANS in order to independently resolve the structure of each phase since by matching the neutron scattering length density of the clay or the pillars, the scattering curve results only from the non-contrast matched phase

  20. Nanostructural characterisation of catalysts by SANS

    Science.gov (United States)

    Stefanis, A. De; Tomlinson, A. A. G.; Steriotis, Th. A.; Stefanopoulos, K. L.; Keiderling, U.

    2004-07-01

    A series of restructured clays used as catalysts in small- and large-scale chemical reactions, have been studied by small-angle neutron scattering (SANS). Analysis of the spectra provides detailed information both on the nanopore structure and the surface texture of these materials. Additionally, pillared inter-layered clays (PILCs) have a great potential for industrial utilisation in catalysis, sorption and separations. PILCs have been studied with contrast-matching SANS in order to independently resolve the structure of each phase since by matching the neutron scattering length density of the clay or the pillars, the scattering curve results only from the non-contrast matched phase.

  1. Thresholds in chemical respiratory sensitisation.

    Science.gov (United States)

    Cochrane, Stella A; Arts, Josje H E; Ehnes, Colin; Hindle, Stuart; Hollnagel, Heli M; Poole, Alan; Suto, Hidenori; Kimber, Ian

    2015-07-03

    There is a continuing interest in determining whether it is possible to identify thresholds for chemical allergy. Here allergic sensitisation of the respiratory tract by chemicals is considered in this context. This is an important occupational health problem, being associated with rhinitis and asthma, and in addition provides toxicologists and risk assessors with a number of challenges. In common with all forms of allergic disease chemical respiratory allergy develops in two phases. In the first (induction) phase exposure to a chemical allergen (by an appropriate route of exposure) causes immunological priming and sensitisation of the respiratory tract. The second (elicitation) phase is triggered if a sensitised subject is exposed subsequently to the same chemical allergen via inhalation. A secondary immune response will be provoked in the respiratory tract resulting in inflammation and the signs and symptoms of a respiratory hypersensitivity reaction. In this article attention has focused on the identification of threshold values during the acquisition of sensitisation. Current mechanistic understanding of allergy is such that it can be assumed that the development of sensitisation (and also the elicitation of an allergic reaction) is a threshold phenomenon; there will be levels of exposure below which sensitisation will not be acquired. That is, all immune responses, including allergic sensitisation, have threshold requirement for the availability of antigen/allergen, below which a response will fail to develop. The issue addressed here is whether there are methods available or clinical/epidemiological data that permit the identification of such thresholds. This document reviews briefly relevant human studies of occupational asthma, and experimental models that have been developed (or are being developed) for the identification and characterisation of chemical respiratory allergens. The main conclusion drawn is that although there is evidence that the

  2. Fast characterisation of cell-derived extracellular vesicles by nanoparticles tracking analysis, cryo-electron microscopy, and Raman tweezers microspectroscopy

    Directory of Open Access Journals (Sweden)

    Irène Tatischeff

    2012-11-01

    Full Text Available The joint use of 3 complementary techniques, namely, nanoparticle tracking analysis (NTA, cryo-electron microscopy (Cryo-EM and Raman tweezers microspectroscopy (RTM, is proposed for a rapid characterisation of extracellular vesicles (EVs of various origins. NTA is valuable for studying the size distribution and concentration, Cryo-EM is outstanding for the morphological characterisation, including observation of vesicle heterogeneity, while RTM provides the global chemical composition without using any exogenous label. The capabilities of this approach are evaluated on the example of cell-derived vesicles of Dictyostelium discoideum, a convenient general model for eukaryotic EVs. At least 2 separate species differing in chemical composition (relative amounts of DNA, lipids and proteins, presence of carotenoids were found for each of the 2 physiological states of this non-pathogenic microorganism, that is, cell growth and starvation-induced aggregation. These findings demonstrate the specific potency of RTM. In addition, the first Raman spectra of human urinary exosomes are reported, presumably constituting the primary step towards Raman characterisation of EVs for the purpose of human diseases diagnoses.

  3. Characterisation of focal liver lesions with contrast enhanced ultrasonography

    Energy Technology Data Exchange (ETDEWEB)

    Dietrich, Christoph F. E-mail: christoph.dietrich@ckbm.de

    2004-06-01

    Ultrasound contrast agents (USCA) have improved the detection rate of liver tumours in recent years. Conventional ultrasound has been reported to be relatively unreliable in the characterisation of liver tumours. SonoVue{sup [reg]} (Bracco Imaging Spa) has been shown to be particularly advantageous in the differentiation of benign and malignant liver tumours and, therefore, possibly represents a new cost-effective competitive alternative to other liver imaging modalities (e.g. computed tomography and magnetic resonance imaging), thus allowing these important technologies to be available for other indications (e.g. brain, thorax). More detailed and specific liver tumour characterisation is possible in about 80% of liver tumours due to typical vascularity and perfusion patterns. The role of USCA for better characterisation, which is possible through the analysis of flow characteristics in real time, places a particular emphasis on agent use. Contrast enhanced real-time imaging techniques with SonoVue{sup [reg]} allow real-time analysis of tumour perfusion in patients with liver lesions. Liver tumours known to be hyperperfused in the arterial phase (e.g. focal nodular hyperplasia, hepatocellular adenoma and carcinoma, and hyperperfused metastases) can be better detected and characterised. Hypoperfused tumours (e.g. liver metastases of the gastrointestinal tract) can be recognised in the portal venous phase as less perfused 'black spots'. In this article we discuss liver tumour characterisation by contrast enhanced ultrasonography.

  4. SiteChar. Characterisation of European CO2 storage. Deliverable D8.1. Qualitative and quantitative social site characterisations

    Energy Technology Data Exchange (ETDEWEB)

    Brunsting, S.; Pol, M.; Paukovic, M. [ECN Policy Studies, Energy research Centre of the Netherlands ECN, Amsterdam (Netherlands); Kaiser, M.; Zimmer, R. [Unabhaengiges Institut fuer Umweltfragen UfU, Berlin (Germany); Shackley, S.; Mabon, L. [Scottish Carbon Capture and Storage SCCS, Edinburg, Scotland (United Kingdom); Hepplewhite, F.; Loveridge, R. [Energy Markets Unit, Scottish Government, Edinburg, Scotland (United Kingdom); Mazurowski, M.; Polak-Osiniak, D. [Polish Oil and Gas Company PGNiG, Warszawa (Poland); Rybicki, C. [AGH University of Science and Technology, Krakow (Poland)

    2012-10-15

    At local level, public support has proven crucial to the implementation of CO2 capture and storage (CCS) demonstration projects. Whereas no method exists to guarantee public acceptability of any project, a constructive stakeholder engagement process does increase the likelihood thereof. Social site characterisation can be used as an instrument to explore, plan and evaluate a process of active and constructive local stakeholder engagement in a prospective CCS project as a parallel activity to technical site characterisation. It roughly consists of a formative research phase to get acquainted with the area followed by a series of public information and engagement activities. This deliverable presents results from the first phase for the social site characterisations of a prospective CCS site in Poland (onshore) and the UK (offshore), using qualitative as well as quantitative research methods, as a first step to planning of local public engagement activities and evaluation of these activities that will be undertaken by this consortium at both sites in the near future. Although the term social site characterisation actually refers to the entire process of formative research and subsequent public outreach, and hence to the complete package of awareness work undertaken as part of SiteChar, in the present deliverable the term only refers to the formative research activities as undertaken up to now and as described in this deliverable. The qualitative part of the social site characterisation consisted of (1) a description of relevant social site characteristics such as local history; (2) interviews with relevant local stakeholders; (3) a media analysis of local newspapers. The quantitative part of the social site characterisation consisted of surveys using representative samples to characterise the local population in terms of awareness, knowledge and perceptions of CCS, felt involvement in decision making, extent of local activism, level of trust in representatives and

  5. Characterisation and management of concrete grinding residuals.

    Science.gov (United States)

    Kluge, Matt; Gupta, Nautasha; Watts, Ben; Chadik, Paul A; Ferraro, Christopher; Townsend, Timothy G

    2018-02-01

    Concrete grinding residue is the waste product resulting from the grinding, cutting, and resurfacing of concrete pavement. Potential beneficial applications for concrete grinding residue include use as a soil amendment and as a construction material, including as an additive to Portland cement concrete. Concrete grinding residue exhibits a high pH, and though not hazardous, it is sufficiently elevated that precautions need to be taken around aquatic ecosystems. Best management practices and state regulations focus on reducing the impact on such aquatic environment. Heavy metals are present in concrete grinding residue, but concentrations are of the same magnitude as typically recycled concrete residuals. The chemical composition of concrete grinding residue makes it a useful product for some soil amendment purposes at appropriate land application rates. The presence of unreacted concrete in concrete grinding residue was examined for potential use as partial replacement of cement in new concrete. Testing of Florida concrete grinding residue revealed no dramatic reactivity or improvement in mortar strength.

  6. Aluminium phosphate sulphate minerals (APS) associated with proterozoic unconformity-type uranium deposits: crystal-chemical characterisation and petrogenetic significance; Les sulfates phosphates d'aluminium hydrates (APS) dans l'environnement des gisements d'uranium associes a une discordance proterozoique: caracterisation cristallochimique et signification petrogenetique

    Energy Technology Data Exchange (ETDEWEB)

    Gaboreau, St

    2005-07-01

    Aluminium phosphate sulfate minerals (APS) are particularly widespread and spatially associated with hydrothermal clay alteration in both the East Alligator River Uranium Field (Northern Territory, Australia) and the Athabasca basin (Saskatchewan, Canada), in the environment of proterozoic unconformity-related uranium deposits (URUD). The purpose of this study is both: 1) to characterize the nature and the origin of the APS minerals on both sides of the middle proterozoic unconformity between the overlying sandstones and the underlying metamorphic basement rocks that host the uranium ore bodies, 2) to improve our knowledge on the suitability of these minerals to indicate the paleo-conditions (redox, pH) at which the alteration processes relative to the uranium deposition operated. The APS minerals result from the interaction of oxidising and relatively acidic fluids with aluminous host rocks enriched in monazite. Several APS-bearing clay assemblages and APS crystal-chemistry have also been distinguished as a function of the distance from the uranium ore bodies or from the structural discontinuities which drained the hydrothermal solutions during the mineralisation event. One of the main results of this study is that the index mineral assemblages, used in the recent literature to describe the alteration zones around the uranium ore bodies, can be theoretically predicted by a set of thermodynamic calculations which simulate different steps of fluid-rock interaction processes related to a downward penetrating of hyper-saline, oxidizing and acidic diagenetic fluids through the lower sandstone units of the basins and then into the metamorphic basement rocks. The above considerations and the fact that APS with different crystal-chemical compositions crystallized in a range of fO{sub 2} and pH at which uranium can either be transported in solution or precipitated as uraninite in the host-rocks make these minerals not only good markers of the degree of alteration of the

  7. Geochemical Parameters Required from the SKB Site Characterisation Programme

    International Nuclear Information System (INIS)

    Bath, Adrian

    2002-01-01

    SKB has described its approach to site characterisation in a number of Technical Reports. One of the scientific topics in which specific information requirements and priorities are set out is geochemistry. This report for SKI examines critically whether the geochemical parameters identified in the SKB programme documents will be adequate for safety and regulatory requirements. It also examines some of the details of parameter requirements and interpretation tools that will be necessary to convert site investigation data into knowledge about chemical conditions and groundwater movements. The SKB strategy for geochemical data focuses on a small number of 'suitability indicators', primarily dissolved oxygen, pH and salinity. Their parameter requirements aim to assess those primary characteristics, as well as to acquire a wider range of data that will support those assessments and provide a broader understanding of candidate areas. An initial observation in this review that, though it is a primary suitability indicator, dissolved oxygen apparently will not be measured and instead will be inferred from other redox indicators. This raises a number of issues about sampling and monitoring measures, analytical data reliability and sensitivity, and the degree of confidence in geochemical understanding. A geochemical programme involves reconnaissance by desk study and acquisition of new data at levels of details that are appropriate to the stage of site investigations. As early as possible, a conceptual model of a candidate area should help to define the objectives of geochemical measurements on both rock and groundwater samples. It is recommended that parameters requirements should be defined and considered not only in terms of isolated measurements but more in terms of addressing broader objectives that relate to safety and also to geoscientific understanding. The safety priorities remain (e.g. dissolved oxygen) but will then be supported by an understanding of processes

  8. Multidisciplinary characterisation of raw materials used for 'ghiara

    Science.gov (United States)

    Barca, Donatella; Belfiore, Cristina M.; La Russa, Mauro F.; Pelle, Teresa; Pezzino, Antonio; Scarciglia, Fabio; Viccaro, Marco

    2010-05-01

    This work deals with new data on the raw materials used for the production of typical ghiara mortars, widely employed in historical buildings of Catania downtown (Eastern Sicily, Southern Italy). Ghiara aggregates are interpreted as the product of thermal transformation of soils rich in organic matter as a consequence of heating induced by the flowing lavas of Mt. Etna volcano on them. This process changes the original brown colour of the soil to reddish nuances. Aim of this study is a multidisciplinary investigation of such raw materials by comparing various ghiara samples from different ancient quarries located in areas covered by historic lava flows (both in the historic centre and the periphery of Catania) with a still-preserved, unburied and unburnt, volcanic soil profile presumably correlated with those affected by transformation. Relevant information about the compositional, physical, petrographic and mineralogical features is provided, mainly on the weathering degree, the patterns that affect the primary components and the newly-formed phases. This allows the acquisition of new elements on the ghiara genesis and its physical-chemical formation conditions. Several analytical techniques were used to characterise both the ghiara and soil samples from the same profile. Major and trace element patterns of ghiara and soil samples are very similar, supporting the hypothesis that the studied soil really represents the parent material of ghiara unaffected by the lava flow-induced transformation. Plagioclase, pyroxene and quartz grains of ghiara samples exhibit important corrosion features, often coupled with Si-Al and Si amorphous phases as well as Fe-oxides/hydroxides. Conversely, primary minerals are fairly fresh within the soil. The clay mineralogy of soil horizons consists of illite and kaolinite phyllosilicates (along with halloysite-7Å in one sample), whereas ghiara includes illite and hematite and/or goethite. Organic matter occurs in significant amounts

  9. Grey water characterisation and pollutant loads in an urban slum

    International Nuclear Information System (INIS)

    Katukiza, A. Y.; Ronteltap, M.; Niwagaba, C. B.; Kansiime, F.; Lens, P. N. L.

    2015-01-01

    On-site sanitation provisions in urban slums rarely prioritise grey water management, yet it forms the largest fraction of wastewater. This study was carried out to characterise grey water and quantify its pollutant loads in Bwaise III (Uganda) and to provide data for grey water management in urban slums of developing countries. Samples were collected for analysis from ten representative households as well as from four tertiary drains and the main drainage channel for 7 months in two dry seasons. Grey water production was found to comprise 85 % of the domestic water consumption. The chemical oxygen demand concentration in the grey water generated by laundry, in the kitchen and in the bathroom was 9,225 ± 1,200 mg L-1, 71,250 ± 1,011 mg L-1 and 4,675 ± 750 mg L-1, while the BOD5 (biochemical oxygen demand) to COD ratio was 0.24 ± 0.05, 0.33 ± 0.08 and 0.31 ± 0.07, respectively. The maximum concentration of Escherichia coli and total coliforms was 2.05 9 107 cfu (100 mL)-1 and 1.75 9 108 cfu (100 mL)-1, respectively, in grey water from the bathroom, while that of Salmonella spp. was 7.32 9 106 cfu (100 mL)-1 from laundry. Analysis of variance (ANOVA) showed a significant difference in the concentration of COD, total suspended solids, total organic carbon, dissolved organic carbon, total phosphorus, sodium adsorption ratio, oil and grease, and Salmonella spp. in grey water from laundry, bathroom and kitchen (p/0.05). The high loads of COD ([500 kg day-1), total suspended solids ([200 kg day-1), nutrients (8.3 kg TKN day-1 and 1.4 kg total phosphorus day-1) and microorganisms (106 to 109 cfu c-1 day-1) originating from grey water in Bwaise III show that grey water poses a threat to the environment and a risk to human health in urban slums. Therefore, there is a need to prioritise grey water treatment in urban slums of developing countries to achieve adequate sanitation.

  10. Geochemical Parameters Required from the SKB Site Characterisation Programme

    Energy Technology Data Exchange (ETDEWEB)

    Bath, Adrian [Intellisci Ltd., Loughborough (United Kingdom)

    2002-01-01

    SKB has described its approach to site characterisation in a number of Technical Reports. One of the scientific topics in which specific information requirements and priorities are set out is geochemistry. This report for SKI examines critically whether the geochemical parameters identified in the SKB programme documents will be adequate for safety and regulatory requirements. It also examines some of the details of parameter requirements and interpretation tools that will be necessary to convert site investigation data into knowledge about chemical conditions and groundwater movements. The SKB strategy for geochemical data focuses on a small number of 'suitability indicators', primarily dissolved oxygen, pH and salinity. Their parameter requirements aim to assess those primary characteristics, as well as to acquire a wider range of data that will support those assessments and provide a broader understanding of candidate areas. An initial observation in this review that, though it is a primary suitability indicator, dissolved oxygen apparently will not be measured and instead will be inferred from other redox indicators. This raises a number of issues about sampling and monitoring measures, analytical data reliability and sensitivity, and the degree of confidence in geochemical understanding. A geochemical programme involves reconnaissance by desk study and acquisition of new data at levels of details that are appropriate to the stage of site investigations. As early as possible, a conceptual model of a candidate area should help to define the objectives of geochemical measurements on both rock and groundwater samples. It is recommended that parameters requirements should be defined and considered not only in terms of isolated measurements but more in terms of addressing broader objectives that relate to safety and also to geoscientific understanding. The safety priorities remain (e.g. dissolved oxygen) but will then be supported by an understanding of

  11. Ferrite nanoparticles: Synthesis, characterisation and applications in electronic device

    International Nuclear Information System (INIS)

    Kefeni, Kebede K.; Msagati, Titus A.M.; Mamba, Bhekie B.

    2017-01-01

    Highlights: • Available synthesis methods of ferrite nanoparticles (FNPs) are briefly reviewed. • Summary of the advantage and limitation of FNPs synthesis techniques are presented. • The existing most common FNPs characterisation techniques are briefly reviewed. • Major application areas of FNPs in electronic materials are reviewed. - Abstract: Ferrite nanoparticles (FNPs) have attracted a great interest due to their wide applications in several areas such as biomedical, wastewater treatment, catalyst and electronic device. This review focuses on the synthesis, characterisation and application of FNPs in electronic device with more emphasis on the recently published works. The most commonly used synthesis techniques along with their advantages and limitations are discussed. The available characterisation techniques and their application in electronic materials such as sensors and biosensors, energy storage, microwave device, electromagnetic interference shielding and high-density recording media are briefly reviewed.

  12. Ferrite nanoparticles: Synthesis, characterisation and applications in electronic device

    Energy Technology Data Exchange (ETDEWEB)

    Kefeni, Kebede K., E-mail: kkefeni@gmail.com; Msagati, Titus A.M.; Mamba, Bhekie B.

    2017-01-15

    Highlights: • Available synthesis methods of ferrite nanoparticles (FNPs) are briefly reviewed. • Summary of the advantage and limitation of FNPs synthesis techniques are presented. • The existing most common FNPs characterisation techniques are briefly reviewed. • Major application areas of FNPs in electronic materials are reviewed. - Abstract: Ferrite nanoparticles (FNPs) have attracted a great interest due to their wide applications in several areas such as biomedical, wastewater treatment, catalyst and electronic device. This review focuses on the synthesis, characterisation and application of FNPs in electronic device with more emphasis on the recently published works. The most commonly used synthesis techniques along with their advantages and limitations are discussed. The available characterisation techniques and their application in electronic materials such as sensors and biosensors, energy storage, microwave device, electromagnetic interference shielding and high-density recording media are briefly reviewed.

  13. Major leaching processes of combustion residues - Characterisation, modelling and experimental investigation

    Energy Technology Data Exchange (ETDEWEB)

    Yan Jinying

    1998-12-31

    Characterising leaching behaviour provides ample evidence to identify the major leaching processes of combustion residues. Neutralisation and chemical weathering govern the leaching reactions and control the release of elements from combustion residues, and are thus considered to be the major leaching processes. According to experimental investigations and geochemical simulations, the leaching kinetics of buffering materials are key issues for the understanding of the neutralizing processes. The acid neutralizing capacity at different pH levels depends mainly on the mineralogy of the combustion residues. In combustion residues, the dissolution of glass phases is expected to play an important role in a long-term neutralizing process. The neutralizing process in a flow system is significantly different from that in a batch system. The neutralizing ability of a combustion residue may be strongly affected by solute transport and carbonation reactions in a natural leaching environment. The chemical weathering mainly involves the matrix of combustion residues consisting mostly of glass phases. The dissolution kinetics of waste glass and other possible processes involved in the chemical weathering have been investigated and incorporated into a kinetic reactive transport model. Most important processes in the chemical weathering can be simulated simultaneously using this model. The results show that there is a complicated relationship between the factors controlling the long-term chemical weathering. The environmental impact of the glass dissolution cannot be neglected. Although the glass dissolution provides considerable buffering capacity in long-term weathering, the carbonate is usually a dominant buffering mineral in actual weathering processes. The transformation of carbonate should be considered as an important process in the chemical weathering. The formation of secondary minerals may considerably alter the mineralogy of the waste, and thus change the leaching

  14. Chemical Peels

    Science.gov (United States)

    ... for Every Season How to Choose the Best Skin Care Products In This Section Dermatologic Surgery What is dermatologic ... for Every Season How to Choose the Best Skin Care Products Chemical Peels Uses for Chemical Peels Learn more ...

  15. Chemical Reactors.

    Science.gov (United States)

    Kenney, C. N.

    1980-01-01

    Describes a course, including content, reading list, and presentation on chemical reactors at Cambridge University, England. A brief comparison of chemical engineering education between the United States and England is also given. (JN)

  16. Tectono-metamorphic evolution of the Tavşanli zone, Western Anatolia: implications for mechanical coupling during subduction/obduction processes

    Science.gov (United States)

    Plunder, Alexis; Agard, Philippe; Chopin, Christian; Okay, Aral

    2013-04-01

    Obduction (i.e., emplacement of a dense oceanic lithosphere on top of a continent) and associated continental subduction provide insights into the rheology of the lithosphere and inter-plate mechanical coupling that usefully complements those inferred from normal oceanic subduction beneath continents. Structural and petrological data from the Tavşanlı zone are herein used to highlight processes occurring along the subduction interface from initial obduction stages (i.e., initiation of intra-oceanic subduction witnessed by metamorphic soles) to continental subduction (represented by high-pressure low-temperature, HP-LT rocks). The Tavşanlı zone (Western Anatolia) belongs to the İzmir-Ankara suture zone, which separates the Pontides and Anatolide-Tauride block. It represents a very well preserved late Cretaceous subduction interface, thanks to only mild, later collision. The Tavşanlı zone is divided in three main tectonic units related to (either continental or oceanic) subduction and obduction, respectively, which are from bottom to top: (i) the distal cover of the subducted north facing continental margin of the Anatolide-Tauride block (Orhaneli unit), which yields one of the lowest thermal gradients on earth (i.e., 5°C/km, with peak T and P of 430°C/22-24 kbar); (ii) an accretionary complex made of low-grade, subducted ocean-derived metamorphic rocks; (iii) the non-metamorphic obducted ophiolite, underlain by a thin metamorphic sole, which is found as klippen south of the İzmir-Ankara suture zone. Systematic sampling and structural work allow us to reappraise the nature, internal structure and P-T conditions of the accretionary complex sandwiched between the lower continental and upper oceanic plates. Two major tectonic units (termed complex 1 and 2) are recognised based on metamorphic grade and structural position with respect to the continental margin. Metamorphic conditions range from incipient HP-LT metamorphism (complex 1) to blueschist facies

  17. Biomarker geochemistry of bituminous shale sequence and crude oil in the Ereǧli-Bor Basin (Konya-Niǧde), Central Anatolia, Turkey

    Science.gov (United States)

    Kara-Gulbay, Reyhan; Erdogan, Mert; Korkmaz, Sadettin; Kadinkiz, Gökhan

    2016-04-01

    In the Ereǧli-Bor Basin (Konya-Niǧde), Central Anatolia, bituminous shale sequence with thickness ranging between 72 and 160 m occurs in lacustrine deposits of Upper Miocene-Pliocene age. The live oil has also been observed in this bituminous shale sequence. Rock-Eval/TOC, GC and GC-MS analyses were conducted on selected bituminous shale samples from four borehole (key-12/1, key-12/2, key-12/3 key-12/4) and one crude oil sample from a borehole (key-12/2) in the basin. In this study, organic matter type, maturity and depositional environment of bituminous shale are evaluated and the origin of crude oil is determined by the bituminous shale-crude oil correlation. The total organic carbon (TOC) values of the bituminous shale samples range from 1.21-13.98 wt% with an average TOC value of 4.75wt%. The bituminous shale sequence is characterized by high HI (127-662 mg HC/g TOC) and low OI (7-50 mgCO2/TOC). Tmax varies from 332-419ᵒC. Very low Pr/Ph ratios of bituminous shale (0.09-0.22) are indicative of anoxic depositional conditions. C27 is dominate sterane for bituminous shale and crude oil samples with C27>C29>C28. Normal steranes are more dominant compare to iso- and diasteranes. Ouite high sterane/hopane ratios (1.14-2.70) indicate dominant algal organic matter input for bituminous shale and source rock of crude oil. C31R/hopane ratio for bituminous shale and crude oil samples are very low (0.09-0.13) and these ratio show a lacustrine depositional envirronment for bituminous shale and source rock of crude oil. Sterane and terpane distributions of bituminous shale and crude oil are very similar. A very good correlation in terms of biomarker between bituminous shale and crude oil samples indicate that source rock of crude oil is bituminous shale. The 22S/(22R + 22S) C32 homohopane ratios of bituminous shale and crude oil samples are found to be 0.56 and 0.61, indicating that homohopane isomerization has attained equilibrium and bituminous shale and crude oil are

  18. Hydrogeological Modelling of the Geothermal Waters of Alaşehir in the Continental Rift Zone of the Gediz, Western Anatolia, Turkey

    Science.gov (United States)

    Ӧzgür, Nevzat; Bostancı, Yesim; Anilır Yürük, Ezgi

    2017-12-01

    In western Anatolia, Turkey, the continental rift zones of the Büyük Menderes, Küçük Menderes and Gediz were formed by extensional tectonic features striking E-W generally and representing a great number of active geothermal systems, epithermal mineralizations and volcanic rocks from Middle Miocene to recent. The geothermal waters are associated with the faults which strike preferentially NW-SE and NE-SW and locate diagonal to general strike of the rift zones of the Menderes Massif. These NW-SE and NE-SW striking faults were probably generated by compressional tectonic regimes which leads to the deformation of uplift between two extensional rift zones in the Menderes Massif. The one of these rift zones is Gediz which is distinguished by a great number of geothermal waters such as Alaşehir, Kurşunlu, Çamurlu, Pamukkale and Urganlı. The geothermal waters of Alaşehir form the biggest potential in the rift zone of Gediz with a capacity of about 100 to 200 MWe. Geologically, the gneisses from the basement rocks in the study area which are overlain by an Paleozoic to Mesozoic intercalation of mica schists, quartzites and marbles, a Miocene intercalation of conglomerates, sandstones and clay stones and Plio-Quaternary intercalation of conglomerates, sandstones and clay stones discordantly. In the study area, Paleozoic to Mesozoic quartzites and marbles form the reservoir rocks hydrogeologically. The geothermal waters anions with Na+K>Ca>Mg dominant cations and HCO3>Cl> dominant anions are of Na-HCO3 type and can be considered as partial equilibrated waters. According to the results of geochemical thermometers, the reservoir temperatures area of about 185°C in accordance with measured reservoir temperatures. Stabile isotopes of δ18O versus δ2H of geothermal waters of Alaşehir deviate from the meteoric water line showing an intensive water-rock interaction under high temperature conditions. These data are well correlated with the results of the

  19. Characterisation of crude oil components, asphaltene aggregation and emulsion stability by means of near infrared spectroscopy and multivariate analysis

    Energy Technology Data Exchange (ETDEWEB)

    Aske, Narve

    2002-06-01

    Effective separation of water-in-crude oil emulsions is a central challenge for the oil industry on the Norwegian Continental Shelf, especially with the future increase in subsea and even down-hole processing of well fluids. The mechanisms and properties governing emulsion stability are far from fully understood but the indigenous surface active crude oil components are believed to play a major role. In this work a thorough physico-chemical characterisation of a set of crude oils originating from a variety of production fields has been performed. Crude oil properties responsible for emulsion stability were identified by use of multivariate analysis techniques like partial least squares regression (PLS) and principal component analysis (PCA). Interfacial elasticity along with both asphaltene content and asphaltene aggregation state were found to be main contributors to emulsion stability. Information on a crude oils ability to form elastic crude oil-water interfaces was found to be especially crucial when discussing emulsion stability. However, measured values of interfacial elasticity were highly dependent on asphaltene aggregation state. Several experimental techniques was utilised and partly developed for the crude oil characterisation. A high-pressure liquid chromatography (HPLC) scheme was developed for SARA-fractionation of crude oils and an oscillating pendant drop tensiometer was used for characterisation of interfacial rheological properties. For emulsion stability a cell for determining the stability as a function of applied electric fields was used. In addition, near infrared spectroscopy (NIR) was used throughout the work both for chemical and physical characterisation of crude oils and model systems. High pressure NIR was used to study the aggregation of asphaltenes by pressure depletion. A new technique for detection of asphaltene aggregation onset pressures based on NIR combined with PCA was developed. It was also found that asphaltene aggregation is

  20. Implications of Late Cretaceous U-Pb zircon ages of granitic intrusions cutting ophiolitic and volcanogenic rocks for the assembly of the Tauride allochthon in SE Anatolia (Helete area, Kahramanmaraş Region, SE Turkey)

    Science.gov (United States)

    Nurlu, Nusret; Parlak, Osman; Robertson, Alastair; von Quadt, Albrecht

    2016-01-01

    An assemblage of NE-SW-trending, imbricate thrust slices (c. 26 km E-W long × 6.3 km N-S) of granitic rocks, basic-felsic volcanogenic rocks (Helete volcanics), ophiolitic rocks (Meydan ophiolite) and melange (Meydan melange) is exposed near the Tauride thrust front in SE Anatolia. The volcanogenic rocks were previously assumed to be Eocene because of associated Nummulitic limestones. However, ion probe U-Pb dating of zircons extracted from the intrusive granitic rocks yielded ages of 92.9 ± 2.2-83.1 ± 1.5 Ma (Cenomanian-Campanian). The Helete volcanic unit and the overlying Meydan ophiolitic rocks both are intruded by granitic rocks of similar age and composition. Structurally underlying ophiolite-related melange includes similar-aged, but fragmented granitic intrusions. Major, trace element and rare earth element analyses coupled with electron microprobe analysis of the granitic rocks show that they are metaluminus to peraluminus and calc-alkaline in composition. A magmatic arc setting is inferred from a combination of tectonomagmatic discrimination, ocean ridge granite-normalized multi-element patterns and biotite geochemistry. Sr-Nd-Pb isotope data further suggest that the granitoid rocks were derived from variably mixed mantle and crustal sources. Granitic rocks cutting the intrusive rocks are inferred to have crystallized at ~5-16 km depth. The volcanogenic rocks and granitic rocks originated in a supra-subduction zone setting that was widely developed throughout SE Anatolia. Initial tectonic assembly took place during the Late Cretaceous probably related to northward subduction and accretion beneath the Tauride continent (Keban and Malatya platforms). Initial tectonic assembly was followed by exhumation and then transgression by shelf-depth Nummulitic limestones during Mid-Eocene, as documented in several key outcrops. Final emplacement onto the Arabian continental margin took place during the Early Miocene.

  1. Characterising power quality disturbances resulting from current limiting fuse operation

    Directory of Open Access Journals (Sweden)

    N. Ortiz S.

    2011-06-01

    Full Text Available This article presents novel and easily implemented tools for characterising electrical disturbances originated by fuse operations. A methodology is described that (with the use of some descriptors led to identifying electrical disturbances of this kind. The algorithm’s decision thresholds were estimated using machine learning techniques. This work was aimed at providing new tools for assessing power quality, characterising and extracting information from voltage and current records obtained from monitoring distribution systems. MATLAB was used for validating this methodology, receiving voltage and current records of simulated events in ATP-EMTP and also real events as input.

  2. Characterisation of triacetone triperoxide (TATP) conformers using LC-NMR.

    Science.gov (United States)

    Haroune, Nicolas; Crowson, Andrew; Campbell, Bill

    2011-06-01

    Previous studies [1,2] have reported the existence of two conformers of TATP. This study demonstrates the ability of LC-NMR to separate and characterise the individual conformers. The NMR data is consistent with the proposed structures for the two conformers. Re-equilibration can be followed by NMR and the kinetics of the process studied. Over the past decade the use of the explosive TATP in terrorist devices has increased. Therefore, the ability to analyse and characterise this material has assumed greater importance. Copyright © 2010 Forensic Science Society. All rights reserved.

  3. Characterisation of ferroelectric bulk materials and thin films

    CERN Document Server

    Cain, Markys G

    2014-01-01

    This book presents a comprehensive review of the most important methods used in the characterisation of piezoelectric, ferroelectric and pyroelectric materials. It covers techniques for the analysis of bulk materials and thick and thin film materials and devices. There is a growing demand by industry to adapt and integrate piezoelectric materials into ever smaller devices and structures. Such applications development requires the joint development of reliable, robust, accurate and - most importantly - relevant and applicable measurement and characterisation methods and models. In the past f

  4. Ion beam characterisation of nanometre structures

    International Nuclear Information System (INIS)

    Persson, Leif.

    1995-08-01

    Ion beam analysis methods have been applied to the study of technologically important issues in III-V nanometre structure science. In the first application, the incorporation of hydrogen in GaAs during electron cyclotron resonance etching was studied using the 1 H( 15 N,αγ) 12 C reaction analysis method. The major part of the work was carried out using mass and energy dispersive Recoil Spectrometry (RS). RS was used to study reactions of thin metal films InP reactions. The metals investigated include Cr, Ti, Ni, Pd and Pt and the reactions as a function of temperature were studied to elucidate suitable compounds for contacts and metallization. Using 127 I in the 0.5A to 0.7A MeV region as the projectile, the depth profiles for the different elements were obtained. Complementary measurements with X-ray diffraction to obtain chemical phase information as well as scanning electron microscopy to study the surface morphology were also carried out. 59 refs, 15 figs

  5. Hydraulic and hydrochemical characterisation of argillaceous rocks

    International Nuclear Information System (INIS)

    1995-01-01

    Throughout the OECD member countries many national programmes on radioactive waste management are considering geological disposal in argillaceous media. In order to determine their suitability for waste disposal, evaluations and understanding of basic physical and chemical processes that govern radionuclides transport through these formations are required. Clay-rich media have a very marked capacity to retard the movement of radionuclides by sorption, filtration and other mechanisms. However, a complicating factor to make quantitative predictions of the performance of clay barriers is our incomplete knowledge of the mechanisms of groundwater and solute transport in compact clays. Application of hydraulic testing and groundwater sampling methods to low and very low permeability rocks, and in particular to argillaceous media, requires modifications in equipment, testing procedures, and interpretation methods. In this context, the NEA Coordinating Group on Site Evaluation and Design of Experiments for Radioactive Waste Disposal (SEDE) established the NEA Working Group on Measurement and Physical Understanding of Groundwater Flow through Argillaceous Media (the Clay Club) to address the many issues associated with this subject. The workshop on hydraulic and hydrochemical characteristics of argillaceous media was hosted by the British Geological Survey in Keyworth, United Kingdom, on 7-9 June 1994

  6. Characterisation of contaminated metals using an advanced statistical toolbox - Geostatistical characterisation of contaminated metals: methodology and illustrations

    International Nuclear Information System (INIS)

    Larsson, Arne; Lidar, Per; Desnoyers, Yvon

    2014-01-01

    Radiological characterisation plays an important role in the process to recycle contaminated or potentially contaminated metals. It is a platform for planning, identification of the extent and nature of contamination, assessing potential risk impacts, cost estimation, radiation protection, management of material arising from decommissioning as well as for the release of the materials as well as the disposal of the generated secondary waste as radioactive waste. Key issues in radiological characterisation are identification of objectives, development of a measurement and sampling strategy (probabilistic, judgmental or a combination thereof), knowledge management, traceability, recording and processing of obtained information. By applying advanced combination of statistical and geostatistical in the concept better performance can be achieved at a lower cost. This paper will describe the benefits with the usage of the available methods in the different stages of the characterisation, treatment and clearance processes aiming for reliable results in line with the data quality objectives. (authors)

  7. Characterisation of long-term climate change by dimension estimates of multivariate palaeoclimatic proxy data

    Directory of Open Access Journals (Sweden)

    R. Donner

    2006-01-01

    Full Text Available The problem of extracting climatically relevant information from multivariate geological records is tackled by characterising the eigenvalues of the temporarily varying correlation matrix. From these eigenvalues, a quantitative measure, the linear variance decay (LVD dimension density, is derived. The LVD dimension density is shown to serve as a suitable estimate of the fractal dimension density. Its performance is evaluated by testing it for (i systems with independent components and for (ii subsystems of spatially extended linearly correlated systems. The LVD dimension density is applied to characterise two geological records which contain information about climate variability during the Oligocene and Miocene. These records consist of (a abundances of different chemical trace elements and (b grain-size distributions obtained from sediment cores offshore the East Antarctic coast. The presented analysis provides evidence that the major climate change associated with the Oligocene-Miocene transition is reflected in significant changes of the LVD dimension density. This is interpreted as a change of the interrelationships between different trace elements in the sediment and to a change of the provenance area of the deposited sediment.

  8. Characterisation and removal of recalcitrants in reverse osmosis concentrates from water reclamation plants.

    Science.gov (United States)

    Bagastyo, Arseto Y; Keller, Jurg; Poussade, Yvan; Batstone, Damien J

    2011-03-01

    Water reclamation plants frequently utilise reverse osmosis (RO), generating a concentrated reject stream as a by-product. The concentrate stream contains salts, and dissolved organic compounds, which are recalcitrant to biological treatment, and may have an environmental impact due to colour and embedded nitrogen. In this study, we characterise organic compounds in RO concentrates (ROC) and treated ROC (by coagulation, adsorption, and advanced oxidation) from two full-scale plants, assessing the diversity and treatability of colour and organic compounds containing nitrogen. One of the plants was from a coastal catchment, while the other was inland. Stirred cell membrane fractionation was applied to fractionate the treated ROC, and untreated ROC along with chemical analysis (DOC, DON, COD), colour, and fluorescence excitation-emission matrix (EEM) scans to characterise changes within each fraction. In both streams, the largest fraction contained 10 kDa molecules, with 17-34% of organic compounds as COD. Iron coagulation affected a wider size range, with better removal of organics (41-49% as COD) at the same molar dosage. As with iron, adsorption reduced organics of a broader size range, including organic nitrogen (26-47%). Advanced oxidation (UV/H2O2) was superior for complete decolourisation and provided superior organics removal (50-55% as COD). Copyright © 2011 Elsevier Ltd. All rights reserved.

  9. Propolis volatiles characterisation from acaricide-treated and -untreated beehives maintained at Algarve (Portugal).

    Science.gov (United States)

    Miguel, Maria G; Nunes, Susana; Cruz, Cláudia; Duarte, João; Antunes, Maria D; Cavaco, Ana M; Mendes, Marta D; Lima, A Sofia; Pedro, Luis G; Barroso, José G; Figueiredo, A Cristina

    2013-04-01

    The variability of the volatile profile of 70 propolis samples from acaricide-treated and -untreated beehives maintained at Algarve (Portugal) was evaluated. Propolis samples were collected in three regions of Algarve at three different periods. Cluster analysis based on the propolis volatiles' chemical composition defined two main clusters, not related to the time of year, collection site, altitude, temperature or humidity ranges, and was based mainly on the relative amounts of viridiflorol, n-tricosane and n-nonadecane for cluster I. Cluster II was mainly characterised by the high thymol content, followed by viridiflorol, n-tricosane and n-nonadecane. The presence of higher thymol levels in propolis samples from cluster II may reflect the long use of an acaricide with thymol as main active ingredient. All samples showed an intense rock-rose aroma supported by the presence of characteristic Cistus and labdanum oil volatile components. Given the nowadays frequent propolis household use, volatiles thorough characterisation may assist in its quality assessment.

  10. Characterisation of baroque tin amalgam mirrors of the historical Green Vault in Dresden

    Science.gov (United States)

    Zywitzki, O.; Nedon, W.; Kopte, T.; Modes, T.

    2008-07-01

    The historical Green Vault, one of Europe’s most sumptuous treasure chambers, has reopened in September 2006 in the Dresden Royal Palace. For the baroque presentation of the artworks the special properties of tin amalgam mirrors are of great importance. A comprehensive analytic characterisation was necessary for restoration and reconstruction. The different original casting glasses were analysed in respect of chemical composition, roughness, waviness and optical properties like chromaticity coordinates and transmittance. The microstructure of the tin amalgam layers were investigated on metallographic cross-sections and by X-ray diffraction. The investigations reveal that the tin amalgam layers are composed of γ-HgSn6-10 phase with a grain size between 5 and 50 μm surrounded by a thin mercury phase with about 2 wt. % tin. However the most important property of the baroque tin amalgam mirrors is a relative low reflectivity of about 59% which is drastically lower than for silver mirrors with a reflectivity of about 96%. According to the characterisation results a suitable glass for reconstruction was selected. The mirror layers were produced by historical tin amalgam technology for the rooms not destroyed by bombarding of Dresden in February 1945. For the completely destroyed Jewel Room pure tin layers were deposited by magnetron sputtering. The results show that this new technology enables an adequate substitute for the original tin amalgam layers.

  11. Characterisation of the Fish Producing and Fish Processing Sectors ...

    African Journals Online (AJOL)

    Since a few years, there is a focus on the expansion of the fish industry in Mauritius in view of its contribution in boosting the economic situation of the country. This study was undertaken to characterise the two main sub-sectors of this industry namely the fish producing and fish processing sectors. A survey was carried out in ...

  12. Nutrition economics - Characterising the economic and health impact of nutrition

    NARCIS (Netherlands)

    I. Lenoir-Wijnkoop (Irene); M. Dapoigny; D. Dubois; E. Ganse (Éric); I. Gutiérrez-Ibarluzea (Iñaki); J. Hutton; P. Jones; T. Mittendorf (Thomas); M.J. Poley (Marten); S. Salminen (Seppo); M.J.C. Nuijten (Mark)

    2011-01-01

    textabstractThere is a new merging of health economics and nutrition disciplines to assess the impact of diet on health and disease prevention and to characterise the health and economic aspects of specific changes in nutritional behaviour and nutrition recommendations. A rationale exists for

  13. CO2 Storage Feasibility: A Workflow for Site Characterisation

    Directory of Open Access Journals (Sweden)

    Nepveu Manuel

    2015-04-01

    Full Text Available In this paper, we present an overview of the SiteChar workflow model for site characterisation and assessment for CO2 storage. Site characterisation and assessment is required when permits are requested from the legal authorities in the process of starting a CO2 storage process at a given site. The goal is to assess whether a proposed CO2 storage site can indeed be used for permanent storage while meeting the safety requirements demanded by the European Commission (EC Storage Directive (9, Storage Directive 2009/31/EC. Many issues have to be scrutinised, and the workflow presented here is put forward to help efficiently organise this complex task. Three issues are highlighted: communication within the working team and with the authorities; interdependencies in the workflow and feedback loops; and the risk-based character of the workflow. A general overview (helicopter view of the workflow is given; the issues involved in communication and the risk assessment process are described in more detail. The workflow as described has been tested within the SiteChar project on five potential storage sites throughout Europe. This resulted in a list of key aspects of site characterisation which can help prepare and focus new site characterisation studies.

  14. Molecular approaches for the identification and characterisation of ...

    African Journals Online (AJOL)

    Molecular approaches for the identification and characterisation of oenological lactic acid bacteria. ... Frequently Asked Questions about PDFs. Alternatively, you can download the PDF file directly to your computer, from where it can be opened using a PDF reader. To download the PDF, click the Download link above.

  15. Characterisation of bacterial brown spot pathogen from dry bean ...

    African Journals Online (AJOL)

    Pseudomonas syringae pv. syringae (Pss) causes bacterial brown spot (BBS) of beans (Phaseolus vulgaris L.), with yield losses of up to 55% in South Africa. Pss has a wide host range and for many of these, the pathogen has been biochemically and genetically characterised. However, few studies have been conducted on ...

  16. Methodology for characterisation of glass fibre composite architecture

    DEFF Research Database (Denmark)

    Hansen, Jens Zangenberg; Larsen, J.B.; Østergaard, R.C.

    2012-01-01

    of the fibres. The information is used for different analyses to investigate and characterise the fibre architecture. As an example, the methodology is applied to glass fibre reinforced composites with varying fibre contents. The different fibre volume fractions (FVFs) affect the number of contact points per...... fibre architecture and composite properties....

  17. Spatial distribution and habitat characterisation of mosquito species ...

    African Journals Online (AJOL)

    Background: Infections with mosquito-borne parasites are common in human populations inhabiting tropical regions of the world. Malaria is endemic along Kenyan Lake Victoria basin and its vectors are fresh water breeders. However, much less is known about the current spatial distribution and habitat characterisation of ...

  18. Characterisation of a CMOS charge transfer device for TDI imaging

    International Nuclear Information System (INIS)

    Rushton, J.; Holland, A.; Stefanov, K.; Mayer, F.

    2015-01-01

    The performance of a prototype true charge transfer imaging sensor in CMOS is investigated. The finished device is destined for use in TDI applications, especially Earth-observation, and to this end radiation tolerance must be investigated. Before this, complete characterisation is required. This work starts by looking at charge transfer inefficiency and then investigates responsivity using mean-variance techniques

  19. Characterisation of Oyster Shell for Neutralisation of Bio-leached ...

    African Journals Online (AJOL)

    Characterisation studies of Oyster Shell (Mercenera mercenera) collected from coastal towns of Ghana and its neutralising effect on bio-leached effluent has been studied using XRF, XRD, Zeta Meter, BET and SEM/EDX. The study confirmed that OS contains high calcium equivalent to about 54% CaO. The OS consists ...

  20. Characterisation and Next-generation Sequencing Analysis of Unknown Arboviruses

    Science.gov (United States)

    2012-09-01

    incapacitating illness, lack of adequate control measures, and the ease of production of large quantities of virus. Characterisation by sequencing is...ability to induce a fatal or seriously incapacitating illness, the lack of adequate control measures, and the ease of production of large...Location Family Neutralising antibody detected Culex annulirostris (mosquito) DPP1163 1987 Darwin, NT Rhabdoviridae Cattle, buffalo

  1. Characterisation of cholera toxin by liquid chromatography - Electrospray mass spectrometry

    NARCIS (Netherlands)

    Baar, B.L.M. van; Hulst, A.G.; Wils, E.R.J.

    1999-01-01

    Cholera toxin, one of the toxins that may be generated by various strains of the bacterium Vibrio cholerae, can be considered as a substance possibly used in biological warfare. The possibilities of characterising the toxin by liquid chromatography electrospray mass spectrometry (LC-ES-MS) were

  2. Characterisation of Oil-Gas Mixtures by Raman Spectroscopy

    DEFF Research Database (Denmark)

    Hansen, Susanne Brunsgaard; Berg, Rolf W.; Stenby, Erling Halfdan

    2004-01-01

    . The present project deals with development of a technique for quick analysis of oil-gas mixtures. The main emphasis is laid on characterisation of gas phases in equilibrium with oil at high pressures and high temperatures by Raman spectroscopy. The Raman technique has a great potential of being useful, due...

  3. Location and characterisation of pollution sites by principal ...

    African Journals Online (AJOL)

    Location and characterisation of pollution sites by principal component analysis of trace contaminants in a slightly polluted seasonal river: a case study of the Arenales River (Salta, Argentina) ... Keywords: trace element contamination, water quality, principal component analysis, Arenales River, Salta, Argentina ...

  4. Characterisation and biological treatability of "Izmit industrial and ...

    African Journals Online (AJOL)

    We investigated the conventional characterisation and biological treatability of wastewaters of the "Izmit Industrial and Domestic Wastewater Treatment Plant". Respirometric procedures were carried out for the experimental assessment of organic contents of wastewater. The mean value of total COD was 1201 mg.l-1 and ...

  5. Waste characterisation, determining the energy potential of waste

    CSIR Research Space (South Africa)

    Oelofse, Suzanna HH

    2015-11-01

    Full Text Available • Waste characterisation studies provide evidence • Comprehensive studies are costly • Spending money upfront will save money in long run • Calorific value of MSW is low compared to coal • WtE is a by-product of integrated waste management...

  6. Characterising atmospheric optical turbulence using stereo-SCIDAR

    Science.gov (United States)

    Osborn, James; Butterley, Tim; Föhring, Dora; Wilson, Richard

    2015-04-01

    Stereo-SCIDAR (SCIntillation Detection and Ranging) is a development to the well known SCIDAR method for characterisation of the Earth's atmospheric optical turbulence. Here we present some interesting capabilities, comparisons and results from a recent campaign on the 2.5 m Isaac Newton Telescope on La Palma.

  7. ORIGINAL ARTICLE CASE SERIES Fetal MRI for characterising a ...

    African Journals Online (AJOL)

    Introduction. Prenatal ultrasound (US) is the investigation of choice when screening for fetal abnormalities. When an intracranial abnormality is detected on US specifically within the posterior fossa, a fetal MRI is the next investigation of choice, to accurately characterise and diagnose the abnormality. In the developing world ...

  8. Characterisation of random DFB Raman laser amplifier for WDM transmission.

    Science.gov (United States)

    Rosa, Paweł; Rizzelli, Giuseppe; Tan, Mingming; Harper, Paul; Ania-Castañόn, Juan Diego

    2015-11-02

    We perform a full numerical characterisation of half-open cavity random DFB Raman fibre laser amplifier schemes for WDM transmission in terms of signal power variation, noise and nonlinear impairments, showcasing the excellent potential of this scheme to provide amplification for DWDM transmission with very low gain variation.

  9. Aircraft wind tunnel characterisation using modern design of experiments

    CSIR Research Space (South Africa)

    Dias, JF

    2013-04-01

    Full Text Available 2013-1502, 54th AIAA/ASME/ASCE/AHS/ASC Structures, Structural Dynamics and Materials Conference, Boston, Massachusetts, 8-11 April 2013 Aircraft wind tunnel characterisation using modern design of experiments J. F. Dias1 IDMEC - Instituto...

  10. Characterising and comparing the spawning habitats of anchovy ...

    African Journals Online (AJOL)

    The spawning habitats of anchovy Engraulis encrasicolus and sardine Sardinops sagax in the southern Benguela upwelling ecosystem were characterised by comparing their egg abundances with environmental variables measured concomitantly during two different survey programmes: the South African Sardine and ...

  11. Biological characterisation of Haliclona (?gellius) sp.: sponge and associated microorganisms.

    NARCIS (Netherlands)

    Sipkema, D.; Holmes, B.; Nichols, S.A.; Blanch, H.W.

    2009-01-01

    We have characterised the northern Pacific undescribed sponge Haliclona (?gellius) sp. based on rDNA of the sponge and its associated microorganisms. The sponge is closely related to Amphimedon queenslandica from the Great Barrier Reef as the near-complete 18S rDNA sequences of both sponges were

  12. Superficially located enlarged lymphoid follicles characterise nodular gastritis.

    Science.gov (United States)

    Okamura, Takuma; Sakai, Yasuhiro; Hoshino, Hitomi; Iwaya, Yugo; Tanaka, Eiji; Kobayashi, Motohiro

    2015-01-01

    Nodular gastritis is a form of chronic Helicobacter pylori gastritis affecting the gastric antrum and characterised endoscopically by the presence of small nodular lesions resembling gooseflesh. It is generally accepted that hyperplasia of lymphoid follicles histologically characterises nodular gastritis; however, quantitative analysis in support of this hypothesis has not been reported. Our goal was to determine whether nodular gastritis is characterised by lymphoid follicle hyperplasia.The number, size, and location of lymphoid follicles in nodular gastritis were determined and those properties compared to samples of atrophic gastritis. The percentages of high endothelial venule (HEV)-like vessels were also evaluated.The number of lymphoid follicles was comparable between nodular and atrophic gastritis; however, follicle size in nodular gastritis was significantly greater than that seen in atrophic gastritis. Moreover, lymphoid follicles in nodular gastritis were positioned more superficially than were those in atrophic gastritis. The percentage of MECA-79 HEV-like vessels was greater in areas with gooseflesh-like lesions in nodular versus atrophic gastritis.Superficially located hyperplastic lymphoid follicles characterise nodular gastritis, and these follicles correspond to gooseflesh-like nodular lesions observed endoscopically. These observations suggest that MECA-79 HEV-like vessels could play at least a partial role in the pathogenesis of nodular gastritis.

  13. Characterisation of tectonic lineaments in the Central Equatorial ...

    African Journals Online (AJOL)

    Characterisation of tectonic lineaments in the Central Equatorial Atlantic region of Africa using Bouguer anomaly gravity data. ... Ife Journal of Science ... 3-D standard Euler deconvolution analysis was carried out on Bouguer anomaly gravity data for configuration definition and approximate depth estimate of tectonic ...

  14. Synthesis, characterisation and non-isothermal degradation kinetics ...

    Indian Academy of Sciences (India)

    between MEGDMA and aromatic primary amine leads to. AMA polymerisation. The slope value declared that, 0.31 mol of monomer is required to form 1 mol of the co-polymer. 3.2 UV–visible reflectance study. The above-synthesised polymer was characterised by UV– visible reflectance study. The co-polymer contains both.

  15. Analytical Characterisation of Nanoscale Zero-Valent Iron: A ...

    Science.gov (United States)

    Zero-valent iron nanoparticles (nZVI) have been widely tested as they are showing significant promise for environmental remediation. However, many recent studies have demonstrated that their mobility and reactivity in subsurface environments are significantly affected by their tendency to aggregate. Both the mobility and reactivity of nZVI mainly depends on properties such as particle size, surface chemistry and bulk composition. In order to ensure efficient remediation, it is crucial to accurately assess and understand the implications of these properties before deploying these materials into contaminated environments. Many analytical techniques are now available to determine these parameters and this paper provides a critical review of their usefulness and limitations for nZVI characterisation. These analytical techniques include microscopy and light scattering techniques for the determination of particle size, size distribution and aggregation state, and X-ray techniques for the characterisation of surface chemistry and bulk composition. Example characterisation data derived from commercial nZVI materials is used to further illustrate method strengths and limitations. Finally, some important challenges with respect to the characterisation of nZVI in groundwater samples are discussed. In recent years, manufactured nanoparticles (MNPs) have attracted increasing interest for their potential applications in the treatment of contaminated soil and water. In compar

  16. The spatial and temporal characterisation of flooding within the ...

    African Journals Online (AJOL)

    The inundated area of a wetland is characterised by annual and interannual variability. This paper presents remotely-sensed imagery in order to better understand the spatial and temporal patterns of flooding within the floodplain wetland of the Nyl River, Limpopo Province. A detailed understanding of the hydrological ...

  17. Characterisation of the inorganic chemistry of surface waters in ...

    African Journals Online (AJOL)

    The main purpose of this study was to determine a simple inorganic chemistry index that can be used for all surface waters in South Africa, in order to characterise the inorganic chemistry of surface waters. Water quality data collected up until 1999 from all sample monitoring stations (2 068 monitoring stations, 364 659 ...

  18. The characterisation of the Colonial British and the Voortrekkers in ...

    African Journals Online (AJOL)

    Fictional and non-fi ctional reconstructions of the Great Trek have been a signifi cant dimension of South African cultural history since the late nineteenth century. The majority of novels about ... conventional ethnic stereotypes of heroes and villains featured by some theories of colonial discourse. The ethnic characterisation ...

  19. Synthesis and characterisation of doxorubicin-loaded functionalised ...

    African Journals Online (AJOL)

    Synthesis and characterisation of doxorubicin-loaded functionalised cobalt ferrite nanoparticles and their in vitro anti-tumour activity under an AC-magnetic field. ... morphology of the uncoated and XG-coated CFNPs was established using scanning electron microscopy (SEM), atomic force microscopy (AFM) and dynamic ...

  20. Characterisation of a novel Mannheimia sp from Australian feedlot cattle

    DEFF Research Database (Denmark)

    Blackall, P.J.; Angen, Øystein; Fegan, N.

    2001-01-01

    glucosida, M granulomatis, M ruminalis and M varigena - using a range of phenotypic and genotypic methods. Results Phenotypic characterisation indicated that the isolates belonged to the trehalose-negative [Pasteurella] haemolytica complex. This complex has recently been reorganised into five species within...