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Sample records for analysis neutron activation

  1. Neutron Activation Analysis

    Energy Technology Data Exchange (ETDEWEB)

    Corliss, William R.

    1968-01-01

    In activation analysis, a sample of an unknown material is first irradiated (activated) with nuclear particles. In practice these nuclear particles are almost always neutrons. The success of activation analysis depends upon nuclear reactions which are completely independent of an atom's chemical associations. The value of activation analysis as a research tool was recognized almost immediately upon the discovery of artificial radioactivity. This book discusses activation analysis experiments, applications and technical considerations.

  2. SLOWPOKE: neutron activation analysis

    International Nuclear Information System (INIS)

    Neutron activation analysis permits the non-destructive determination of trace elements in crude oil and its derivatives at high sensitivity (up to 10-9 g/g) and good precision. This article consists of a quick survey of the method followed by an illustration based on the results of recent work at the SLOWPOKE reactor laboratory at the Ecole Polytechnique

  3. Isotopic neutron sources for neutron activation analysis

    International Nuclear Information System (INIS)

    This User's Manual is an attempt to provide for teaching and training purposes, a series of well thought out demonstrative experiments in neutron activation analysis based on the utilization of an isotopic neutron source. In some cases, these ideas can be applied to solve practical analytical problems. 19 refs, figs and tabs

  4. Neutron activation analysis of coins

    International Nuclear Information System (INIS)

    Activation analysis was applied to the study of coins using 14MeV neutrons produced by an accelerator for the determination of oxygen and neutrons emitted from a 252Cf source for the determination of the other elements (Au, Ag, Cu, As etc...). The advantages of this technique are presented

  5. Application of neutron activation analysis

    International Nuclear Information System (INIS)

    The physical basis and analytical possibilities of neutron activation analysis have been performed. The number of applications in material engineering, geology, cosmology, oncology, criminology, biology, agriculture, environment protection, archaeology, history of art and especially in chemical analysis have been presented. The place of the method among other methods of inorganic quantitative chemical analysis for trace elements determination has been discussed

  6. Neutron activation analysis in Bulgaria

    International Nuclear Information System (INIS)

    The development of instrumental neutron activation analysis (INAA) as a routine method started in 1960 with bringing into use of the experimental nuclear reactor 2 MW -IRT-2000. For the purposes of INAA the vertical channels were used. The neutron flux vary from 1 to 6x1012n/cm2s, with Cd ratio for gold of about 4,4. In one of the channels the neutron flux is additionally thermalised with grafite, in others - a pneumatic double-tube rabbit system is installed. One of the irradiation positions is equiped with 1 mm Cd shield constantly. With the pressure of the working gas (air) of 2 bar the transport time in one direction is 2,5 sec. Because of lack of special system for uniform irradiation an accuracy of 3% can be reached by use of iron monitors for long irradiations and copper monitors for use in the rabbit system. Two neutron generators are also working but the application of 14 MeV neutrons for INAA is still quite limited. The most developed are the applications of INAA in the fields of geology and paedology, medicine and biology, environment and pollution, archaeology, metallurgy, metrology and hydrology, criminology

  7. Instrumentation in neutron activation analysis

    International Nuclear Information System (INIS)

    The rise of neutron activation analysis (NAA) as a tool in geochemical research has parallelled advances in detector, multi-channel analyzer, and computer technology. Micro-computers are now being integrated into NAA systems, and gamma-ray spectrometer instrumentation is evolving towards direct-reading systems. The investigator is faced with a wide range of possibilities and choices when equipping or re-equipping a laboratory. The geoscientist is provided with an overview of the available instrumentation and what soon may be feasible. (L.L.)

  8. The Atomic Fingerprint: Neutron Activation Analysis

    Energy Technology Data Exchange (ETDEWEB)

    Keisch, Bernard [Carnegie-Mellon University

    1972-01-01

    The nuclei of atoms are stable only when they contain certain numbers of neutrons and protons. Since nuclei can absorb additional neutrons, which in many cases results in the conversion of a stable nucleus to a radioactive one, neutron activation analysis is possible.

  9. Neutron activation spectrometry and neutron activation analysis in analytical geochemistry

    International Nuclear Information System (INIS)

    The present report is to show the geochemists who are interested in neutron activation spectrometry (NAS) and neutron activation analysis (NAA) which analytical possibilities these methods offer him. As a review of these analytical possibilities, a lieterature compolation is given which is subdivided into two groups: 1) rock (basic, intermediary, acid, sediments, soils and nuds, diverse minerals, tectites, meteorites and lunar material). 2) ore (Al, Au, Be, Cr, Cu, Mn, Mo, Fe, Pb, Pt, Sn, Ti, W, Zn, Zr, U and phosphate ore, polymetallic ores, fluorite, monazite and diverse ores). The applied methods as well as the determinable elements in the given materials can be got from the tables. On the whole, the literature evaluation carried out makes it clear that neutron activation spectrometry is a very useful multi-element method for the analysis of rocks. The analysis of ores, however, is subjected to great limitations. As rock analysis is very frequently of importance in prospecting for ore deposits, the NAS proves to be extremely useful for this very field of application. (orig./LH)

  10. Activation analysis with reactor neutrons

    International Nuclear Information System (INIS)

    The potentialities of neutron as an analytical probe are indicated, pointing out the need for development of other approaches, besides the conventional activation method. Development of instrumental approach to activation and applications, carried out at Analytical Chemistry Division are outlined. The role of, and the need for, the development and application of mathematical methods in enhancing the information content, and in turn the interpretation of the analytical results, is demonstrated. (author)

  11. Instrumental neutron activation analysis - a routine method

    International Nuclear Information System (INIS)

    This thesis describes the way in which at IRI instrumental neutron activation analysis (INAA) has been developed into an automated system for routine analysis. The basis of this work are 20 publications describing the development of INAA since 1968. (Auth.)

  12. Neutron activation analysis of reference materials

    International Nuclear Information System (INIS)

    The importance is pointed out of neutron activation analysis in the preparation of reference materials, and studies are reported conducted recently by UJV. Instrumental neutron activation analysis has been used in testing homogeneity and in determining 28 elements in newly prepared reference standards of coal fly ash designated ENO, EOP and ECH. For accuracy testing, the same method was used in the analysis of NBS SRM-1633a Trace Elements in Coal Fly Ash and IAEA CRM Soil-5 and RM Soil-7. Radiochemical neutron activation analysis was used in determining Cd, Cu, Mn, Mo, and Zn in biological materials NBS SRM-1577 Bovine Liver, Bowen's Kale and in IAEA RM Milk Powder A-11 and Animal Muscle H-4. In all instances very good precision and accuracy of neutron activation analysis results were shown. (author)

  13. KFUPM fast neutron activation analysis facility

    International Nuclear Information System (INIS)

    A newly established Fast Neutron Activation Analysis facility at the Energy Research Laboratory is described. The facility mainly consists of a fast neutron irradiation station and a gamma ray counting station. Both stations are connected by a fast pneumatic sample transfer system which transports the sample from the irradiation station to the counting station in a short time of 3 s. The fast neutron activation analysis facility has been tested by measuring the 27A(n, α)24Na and 115In(n, n')115mIn cross sections at 14.8 and 2.5 MeV neutron energies, respectively. Within the experimental uncertainties, the measured cross sections for these elements agree with the published values. (orig.)

  14. Neutron activation analysis of geochemical samples

    International Nuclear Information System (INIS)

    The present paper will describe the work done at the Technical Research Centre of Finland in developing methods for the large-scale activation analysis of samples for the geochemical prospecting of metals. The geochemical prospecting for uranium started in Finland in 1974 and consequently a manually operated device for the delayed neutron activation analysis of uranium was taken into use. During 1974 9000 samples were analyzed. The small capacity of the analyzer made it necessary to develop a completely automated analyzer which was taken into use in August 1975. Since then 20000-30000 samples have been analyzed annually the annual capacity being about 60000 samples when running seven hours per day. Multielemental instrumental neutron activation analysis is used for the analysis of more than 40 elements. Using instrumental epithermal neutron activation analysis 25-27 elements can be analyzed using one irradiation and 20 min measurement. During 1982 12000 samples were analyzed for mining companies and Geological Survey of Finland. The capacity is 600 samples per week. Besides these two analytical methods the analysis of lanthanoids is an important part of the work. 11 lanthanoids have been analyzed using instrumental neutron activation analysis. Radiochemical separation methods have been developed for several elements to improve the sensitivity of the analysis

  15. Applications of neutron activation analysis in industry

    International Nuclear Information System (INIS)

    Neutron activation analysis technique is discussed in brief. This technique is used for quality control of raw materials, process materials and finished products, as well as activities in research and development for the improvement of the products and new products. The uses of this technique in several experienced industries are mentioned (author)

  16. New studies in forensic neutron activation analysis

    International Nuclear Information System (INIS)

    Three recently completed studies in forensic neutron activation analysis are reported: a study of 0.22-caliber rimfire cartridge primers, a large-scale study of shotgun pellets, and a new 5-element procedure for the analysis of bullet-lead and shotgun-pellet samples. (author) 12 refs

  17. New studies in forensic neutron activation analysis

    International Nuclear Information System (INIS)

    Earlier studies in forensic neutron activation analysis are being extended in This Laboratory. Three of these new studies are reported here: 1) a study of 0.22-caliber rimfire cartridge primers, 2) a large-scale study of shotgun pellets, and 3) a new 5-element procedure for the analysis of bullet-lead and shotgun-pellet samples. (author)

  18. Design of Neutron Activation Analysis Laboratorium Room

    International Nuclear Information System (INIS)

    Base on the planning to increase of the research and service quality in the ''Neutron activation analysis'' (APN),the design of mentioned ''Neutron activation analysis laboratories room'' has been done in the multi purpose reactor G.A. Siwabessy. By the using the designed installation, the irradiation preparation and counting sample can be done. The design doing by determination of installation lay out and maximum particle contain in the air. The design installation required a unit of 1 HP blower, a unit of 1 HP split air condition and 2 units 1200 x 800 mm HEPA filter. This paper concluded that this design is feasible to fabricated

  19. Neutron Activation Analysis with k0 Standardization

    International Nuclear Information System (INIS)

    SCK-CEN's programme on Neutron Activation Analysis with k0-standardisation aims to: (1) develop and implement k0-standardisation method for NAA; (2) to exploit the inherent qualities of NAA such as accuracy, traceability, and multi-element capability; (3) to acquire technical spin-off for nuclear measurements services. Main achievements in 1997 are reported

  20. Neutron activation analysis helps in picture attribution

    International Nuclear Information System (INIS)

    The neutron activation analysis application for obtaining the data useful for proper attribution of paintings has been presented on the base of several examples. The identification on this way of dye elements, pigments and other painting materials is an important element among the physico-chemical methods helping the attribution procedure of old painting objects

  1. Neutron Activation analysis of waste water

    International Nuclear Information System (INIS)

    An instrumental neutron activation analysis for the simultaneous determination of chlorine, bromine, sodium, manganese, cobalt, copper, chromium, zinc, nickel, antimony and iron in waste water is described. They were determined in waste water samples under normal conditions by non-destructive neutron activation simultaneously using a suitable monostandard method. Standardized water samples were used and irradiated in polyethylene ampoules at a neutron flux of 1013 cm-2 s-1 for periods of 1 minute, 1 and 10 hours. A Ge hyperpure detector was used for your activity determination, with count times of 60, 180, 300 and 600 seconds. The obtained results show than the method can be utilized for the determination of this elements without realize anything previous treatment of the samples. (Author)

  2. Neutron activation analysis of biological substances

    International Nuclear Information System (INIS)

    A Bowen cabbage sample was used as a reference material for the neutron activation studies, and the method was checked by the analysis of other biological substances (blood or serum etc.). For nondestructive measurements also some non-trace elements were determined in order to decide whether the activation analysis is a useful means for such measurements. The new activation analysis procedure was used for biomedical studies as, e.g., for trace element determination in body fluids, and for the analysis of inorganic components in air samples. (R.P.)

  3. High-capacity neutron activation analysis facility

    International Nuclear Information System (INIS)

    A high-capacity neutron activation analysis facility, the Reactor Activation Facility, was designed and built and has been in operation for about a year at one of the Savannah River Plant's production reactors. The facility determines uranium and about 19 other elements in hydrogeochemical samples collected in the National Uranium Resource Evaluation program, which is sponsored and funded by the United States Department of Energy, Grand Junction Office. The facility has a demonstrated average analysis rate of over 10,000 samples per month, and a peak rate of over 16,000 samples per month. Uranium is determined by cyclic activation and delayed neutron counting of the U-235 fission products; other elements are determined from gamma-ray spectra recorded in subsequent irradiation, decay, and counting steps. The method relies on the absolute activation technique and is highly automated for round-the-clock unattended operation

  4. Reactor neutron activation analysis of industrial materials

    International Nuclear Information System (INIS)

    The specific application of neutron activation analysis (n.a.a.) for industrial materials is demonstrated by the determination of impurities in BeO, Al, Si, Cu, Ge, GaP, GaAs, steel, and irradiated uranium. A group scheme gives an orientation about the possibilities of n.a.a. The use of different standards, methods for the measurement of low radioactivities and errors caused by recoil reaction and radiation stimulated diffusion are discussed. (author)

  5. Neutron activation analysis of geological materials

    International Nuclear Information System (INIS)

    Neutron activation analysis (NAA) is an extremely sensitive, selective and precise method, which yields a wealth of elemental information from even a small-sized sample. With the recent advances in nuclear reactors and high-efficiency and high-resolution semiconductor detectors, NAA has become a powerful method for multielemental analysis. The concentration of major, minor, and trace elements vary from 1 to 4 orders of magnitude in geological materials. By varying neutron fluxes, irradiation times, decay and counting intervals and using both instrumental and radiochemical techniques in NAA, it is possible to accurately determine about 50 elements in a sample aliquant. The practical aspects of the NAA method as applied to geological materials are discussed in detail, and are demonstrated by the analysis of the United States Geological Survey (USGS) and the International Atomic Energy Agency (IAEA) standard reference geological materials. General aspects of the elemental interpretations in terrestrial samples are also discussed. (author)

  6. Prospects for absolute neutron activation analysis

    International Nuclear Information System (INIS)

    The desirability for absolute neutron activation analysis(ANAA) is two-fold. Results by the comparitor method are only as good as the standards used, and also the method offers a chance of having the final results available within minutes of completing the analysis. In the past ANAA was not seriously considered because of the scarcity and poor qaulity of the nuclear data that were available. This situation is however steadily improving and the possible applications are being investigated. This report reviews the present status by considering the basic activation equation, calculation of parameters, the factors of importance and the size error one might expect

  7. Applications of neutron activation analysis technique

    International Nuclear Information System (INIS)

    The technique was developed as far back as 1936 by G. Hevesy and H. Levy for the analysis of Dy using an isotopic source. Approximately 40 elements can be analyzed by instrumental neutron activation analysis (INNA) technique with neutrons from a nuclear reactor. By applying radiochemical separation, the number of elements that can be analysed may be increased to almost 70. Compared with other analytical methods used in environmental and industrial research, NAA has some unique features. These are multi-element capability, rapidity, reproducibility of results, complementarity to other methods, freedom from analytical blank and independency of chemical state of elements. There are several types of neutron sources namely: nuclear reactors, accelerator-based and radioisotope-based sources, but nuclear reactors with high fluxes of neutrons from the fission of 235U give the most intense irradiation, and hence the highest available sensitivities for NAA. In this paper, the applications of NAA of socio-economic importance are discussed. The benefits of using NAA and related nuclear techniques for on-line applications in industrial process control are highlighted. A brief description of the NAA set-ups at CERT is enumerated. Finally, NAA is compared with other leading analytical techniques

  8. Quality assurance in biomedical neutron activation analysis

    International Nuclear Information System (INIS)

    The summary report represents an attempt to identify some of the possible sources of error in in vitro neutron activation analysis of trace elements applied to specimens of biomedical origin and to advise on practical means to avoid them. The report is intended as guidance for all involved in analysis, including sample collection and preparation for analysis. All these recommendations constitute part of quality assurance which is here taken to encompass the two concepts - quality control and quality assessment. Quality control is the mechanism established to control errors, while quality assessment is the mechanism used to verify that the analytical procedure is operating within acceptable limits

  9. Neutron activation analysis of Etruscan pottery

    International Nuclear Information System (INIS)

    Neutron activation analysis (NAA) has been widely used in archaeology for compositional analysis of pottery samples taken from sites of archaeological importance. Elemental profiles can determine the place of manufacture. At Cornell, samples from an Etruscan site near Siena, Italy, are being studied. The goal of this study is to compile a trace element concentration profile for a large number of samples. These profiles will be matched with an existing data bank in an attempt to understand the place of origin for these samples. The 500 kW TRIGA reactor at the Ward Laboratory is used to collect NAA data for these samples. Experiments were done to set a procedure for the neutron activation analysis with respect to sample preparation, selection of irradiation container, definition of activation and counting parameters and data reduction. Currently, we are able to analyze some 27 elements in samples of mass 500 mg with a single irradiation of 4 hours and two sequences of counting. Our sensitivity for many of the trace elements is better than 1 ppm by weight under the conditions chosen. In this talk, details of our procedure, including quality assurance as measured by NIST standard reference materials, will be discussed. In addition, preliminary results from data treatment using cluster analysis will be presented. (author)

  10. Neutron activation analysis of zirconium niobium alloys

    International Nuclear Information System (INIS)

    Full text: One of the important problems in nuclear reactor projecting is the choice of constructional materials, which meet to the requirements concerned with function, technical characteristics and expected performance of the reactor construction. Also it is necessary to take into account change of their properties under the influence of intensive neutron radiation. Zirconium and zirconium-niobium alloys are used in nuclear engineering as a fuel cladding and both matrix and impurity composition have an influence on their performance capabilities.Under intensive neutron radiation high content of undesirable trace elements in constructional materials can cause forming long-lived radionuclides with high induced activity and hence severe problems may occur at service, control of the equipment and carrying out experiments. Therefore analytical control of component and impurity composition of these materials is an important problem.Neutron activation analysis (NAA) is one of multielemental and high sensitivity methods, which widely applied for the analysis of high purity materials. Prior experiments have shown that instrumental NAA is not suitable for analysis of Zr-Nb alloys due to strong induced matrix activity. Therefore we have developed radiochemical procedure for separation of impurities from matrix elements. Study of the literature data has shown that zirconium and niobium are good extracted from hydrochloric medium by 0 75 M solution of di-2-ethylhexylphosphoric acid (DEHPA) in ortho-xylene. Also this system good extracts hafnium which being accompanying element has high content and interferes with determining impurity elements. To improve separation efficiency we have used 'DEHPA - ZM HCl' chromatography system. On the basis of the carried out researches the radiochemical NAA technique for analysis of high purity zirconium and zirconium-niobium alloys has been developed. The technique is based on extraction-chromatographic separation of matrix radionuclides

  11. Toxicological applications of neutron-activation analysis

    International Nuclear Information System (INIS)

    Thermal neutron-activation analysis is recognised as a useful tool for trace element studies in toxicology. This paper describes some recent applications of the technique to three elements when ingested by people in excess of normal intake Two of the elements (copper and chromium) are essential to life and one (bromine) is as yet unclassified. Three deaths were investiagted and trace element levels compared with normal levels from healthy subjects in the same geographical area who had died as a result of violence. (author)

  12. Neutron activation analysis of medicinal plant extracts

    International Nuclear Information System (INIS)

    Instrumental neutron activation analysis was applied to the determination of the elements Br, Ca, Cl, Cs, Fe, K, La, Mg, Mn, Na, Rb and Zn in medicinal extracts obtained from Centella asiatica, Citrus aurantium L., Achyrolcline satureoides DC, Casearia sylvestris, Solano lycocarpum, Zingiber officinale Roscoe, Solidago microglossa and Stryphnondedron barbatiman plants. The elements Hg and Se were determined using radiochemical separation by means of retention of Se in HMD inorganic exchanger and solvent extraction of Hg by bismuth diethyldithiocarbamate solution. Precision and accuracy of the results were evaluated by analyzing biological reference materials. The therapeutic action of some elements found in plant extracts analyzed is briefly discussed. (author). 15 refs., 5 tabs

  13. Support system for Neutron Activation Analysis

    International Nuclear Information System (INIS)

    In the research reactor of JAERI, the Neutron Activation Analysis (NAA) has been utilized as a major part of an irradiation usage. To utilize NAA, research participants are always required to learn necessary technique. Therefore, we started to examine a support system that will enable to carry out INAA easily even by beginners. The system is composed of irradiation device, gamma-ray spectrometer and data analyzing instruments. The element concentration is calculated by using KAYZERO/SOLCOI software with the K0 standardization method. In this paper, we review on a construction of this INAA support system in JRR-3M of JAERI. (author)

  14. Industrial applications of neutron activation analysis

    International Nuclear Information System (INIS)

    Neutron activation analysis has been widely used in the industry and over the years played a key role in the development of manufacturing process as well as monitoring of the process flow. In this context NAA has been utilized both in R and D, and in the factory as a flexible analytical tool. It has been used successfully in numerous industries including broad categories such as Chemical, Pharmaceutical, Mining, Photographic, Oil and Gas, Automobile, Defense, Semiconductor and Electronic industries. Dow Chemical owns and operates a research reactor for analytical measurements of samples generated in both R and D, and manufacturing area in its plant in Midland, Michigan. Although most industries do not have reactors on their campus but use an off site reactor regularly, and often have in-house neutron sources such as a 252Cf used primarily for NAA. In most industrial materials analysis laboratory NAA is part of a number of analytical techniques such as ICP-MS, AA, SIMS, FTIR, XRF, TXRF etc. Analysis of complex industrial samples may require data from each of these methods to provide a clear picture of the materials issues involved. With the improvement of classical analytical techniques, and the introduction of new techniques, e.g. TXRF, the role of NAA continues to be a key bench mark technique that provides accurate and reliable data. The strength of the NAA in bulk analysis is balanced by its weakness in providing surface sensitive or spatially resolved analysis as is required by many applications. (author)

  15. Neutron activation analysis applied to archaeological problems

    International Nuclear Information System (INIS)

    Among the various techniques, the main analytical methods used to characterize ceramics are undoubtedly XRF and INAA. The principles of NAA differ from those of XRF in that samples are irradiated by thermal neutrons from a nuclear reactor. During irradiation, a few neutrons are captured by the nuclei of atoms in the specimen. This process, called activation, causes some of the nuclei to become unstable. During and after neutron irradiation, these unstable nuclei emit γ rays with unique energies at rates defined by the characteristic half-lives of the radioactive nuclei. Identification of the radioactive nucleus is possible by measuring the γ ray energies. Determination of their intensities permits quantitative analysis of the elements in the sample. The use of NAA in ceramics by a combination of two or three irradiation, decay and measurement strategies allows the determination of the elements Ba, Ce, Cl, Co, Cs, Dy, Eu, Fe, Hf, K, La, Lu, Mn, Na, Nd, Rb, Sb, Sc, Sm, Sr, Ta, Tb, Th, U, Yb, Zn and Zr, if necessary by changing the irradiation, decay and measurement schemes. In general, XRF is more available, more rapid and less expensive than NAA. However, NAA offers a far greater number of elements, more sensitivity, superior precision and greater accuracy than XRF. On the other hand, NAA can be performed on extremely small samples (5-10 mg), meaning that only minor damage to valuable artefacts may be required

  16. Computer modeling for neutron activation analysis methods

    International Nuclear Information System (INIS)

    Full text: The INP AS RU develops databases for the neutron-activation analysis - ND INAA [1] and ELEMENT [2]. Based on these databases, the automated complex is under construction aimed at modeling of methods for natural and technogenic materials analysis. It is well known, that there is a variety of analysis objects with wide spectra, different composition and concentration of elements, which makes it impossible to develop universal methods applicable for every analytical research. The modelling is based on algorithm, that counts the period of time in which the sample was irradiated in nuclear reactor, providing the sample's total absorption and activity analytical peaks areas with given errors. The analytical complex was tested for low-elemental analysis (determination of Fe and Zn in vegetation samples, and Cu, Ag and Au - in technological objects). At present, the complex is applied for multielemental analysis of sediment samples. In this work, modern achievements in the analytical chemistry (measurement facilities, high-resolution detectors, IAEA and IUPAC databases) and information technology applications (Java software, database management systems (DBMS), internet technologies) are applied. Reference: 1. Tillaev T., Umaraliev A., Gurvich L.G., Yuldasheva K., Kadirova J. Specialized database for instrumental neutron activation analysis - ND INAA 1.0, The 3-rd Eurasian Conference Nuclear Science and its applications, 2004, pp.270-271.; 2. Gurvich L.G., Tillaev T., Umaraliev A. The Information-analytical database on the element contents of natural objects. The 4-th International Conference Modern problems of Nuclear Physics, Samarkand, 2003, p.337. (authors)

  17. Reactor neutron activation for multielemental analysis

    International Nuclear Information System (INIS)

    Neutron Activation Analysis using single comparator (K0 NAA method) has been used for obtaining multielemental profiles in a variety of matrices related to environment. Gold was used as the comparator. Neutron flux was characterised by determining f, the epithermal to thermal neutron flux ratio and cc, the deviation from ideal shape of the neutron spectrum. The f and a were determined in different irradiation positions in APSARA reactor, PCF position in CIRUS reactor and tray rod position in Dhruva reactor using both cadmium cut off and multi isotope detector methods. High resolution gamma ray spectrometry was used for radioactive assay of the activation products. This technique is being used for multielement analysis in a variety of matrices like lake sediments, sea nodules and crusts, minerals, leaves, cereals, pulses, leaves, water and soil. Elemental profiles of the sediments corresponding to different depths from Nainital lake were determined and used to understand the history of natural absorption/desorption pattern of the previous 160 years. Ferromanganese crusts from different locations of Indian Ocean were analysed with a view to studying the distribution of some trace elements along with Fe and Mn. Variation of Mn/Fe ratio was used to identify the nature of the crusts as hydrogenous or hydrothermal. Fe-rich and Fe-depleted nodules from Indian Ocean were analysed to understand the REE patterns and it is proposed that REE-Th associated minerals could be the potential Th contributors to the sea water and thus reached ferromanganese nodules. Dolomites (unaltered and altered), two types of serpentines and intrusive rock dolerite from the asbestos mines of Cuddapah basin were analysed for major, minor and trace elements. The elemental concentrations are used for distinguishing and characterising these minerals. From our investigations, it was concluded that both dolomite and dolerite contribute elements in the serpentinisation process. Chemical neutron

  18. Instrumental neutron activation analysis of soil sample

    International Nuclear Information System (INIS)

    This paper describes the analysis of soil samples collected from 5 different location around Sungai Lui, Kajang, Selangor, Malaysia. These sample were taken at 22-24 cm from the top of the ground and were analysed using the techniques of Instrumental Neutron Activation Analysis (INAA). The analysis on soil sample taken above 22-24 cm level were done in order to determine if there is any variation in elemental contents at different sampling levels. The results indicate a wide variation in the contents of the samples. About 30 elements have been analysed. The major ones are Na, I, Cl, Mg, Al, K, Ti, Ca and Fe. Trace elements analysed were Ba, Sc, V, Cr, Mn, Ga, As, Zn, Br, Rb, Co, Hf, Zr, Th, U, Sb, Cs, Ce, Sm, Eu, Tb, Dy, Yb, Lu and La. (author)

  19. Epithermal neutron activation analysis of food

    International Nuclear Information System (INIS)

    Food samples were irradiated with thermal and epithermal neutrons. The average ratios of thermal to epithermal activity were determined for 80Br, 49Ca, 38Cl, 60mCo, 42K, 27Mg, 56Mn, 24Na, and 86mRb. They were equal to 2.1, 26, 24, 6.6, 19, 16, 11, 23 and 1.9, respectively. Then, 57 food samples were analyzed by epithermal neutron activation analysis for Br and Rb. The concentrations (in ppm) of Br and Rb were in asparagus (2) 2.3, 11.5; beets (3) 0.5, 0.8; beef (3) 1.7, 3.6; cabbage (5) 0.5, 10.8; carrot (3) 0.2, 3.7; chicken (3) 0.6, 4.4; chocolate (7) 11.1, 18.7; egg (3) 0.9, 1.9; french bean (3) 0.3, 1.0; goose (2) 1.3, 9.3; lettuce (2) 0.9, 1.7; pork (1) 1.5, 4.4; potato (7) 1.0, 1.2; sausage (3) 4.8, 3.5; spinach (3) 3.6, 4.0; strawberry jam (3) 0.4, 1.4; tomato (1) 13.5, 14.6; turkey (3) 1.2, 4.9. respectively. The number of samples and analyzed is indicated in parentheses. (author)

  20. Selected industrial and environmental applications of neutron activation analysis

    International Nuclear Information System (INIS)

    A review of the applications of Instrumental Neutron Activation Analysis (INAA) in the industrial and environmental fields is given. Detection limits for different applications are also given. (author)

  1. Human hair neutron activation analysis: analysis on population level, mapping

    International Nuclear Information System (INIS)

    Neutron activation analysis is an outstanding analytical method having very wide applications in various fields. Analysis of human hair within last decades mostly based on neutron activation analysis is a very attractive illustration of the application of nuclear analytical techniques. Very interesting question is how the elemental composition differs in different areas or cities. In this connection the present paper gives average data and maps of various localities in the vicinity of drying-out Aral Sea and of various industrial cities in Central Asia. (author)

  2. Silicate rock and rock forming mineral neutron activation analysis

    International Nuclear Information System (INIS)

    A neutron-activation scheme for the determination of nine rare earths and other trace elements in various rock forming minerals (feldspars, ilmenite, magnetite, pyroxenes) and silicate rocks is presented. The procedure is based on three different irradiations involving three separate samples: - epithermal neutron irradiation (2 days) followed by nondestructive analysis; - thermal neutron irradiation (1 day) followed by instrumental analysis; - thermal neutron irradiation (1 week) followed by radiochemical analysis (precipitation, anion exchange separation, liquid-liquid extraction). Two USGS reference samples - granite G-2 and andesite AGV-1 - have been analysed in order to assess the accuracy of the proposed procedure. Our results agree with previous neutron-activation data. (orig.)

  3. Neutron beam characteristics of the prompt gamma neutron activation analysis system at HANARO

    International Nuclear Information System (INIS)

    Neutron beam characteristics of the Prompt Gamma Neutron Activation Analysis facility at HANARO were measured. The neutron beam of this facility is polychromatic thermal neutrons diffracted vertically by a set of pyrolytic graphite crystals at the Bragg angle of 45 .deg. from a horizontal beam line. Three conditions of thermal neutron extraction were applied by varying graphite crystal thickness and focusing geometry of diffracted beam. Thermal neutron profile, thermal neutron flux and Cd-ratio were measured at the sample position for each extraction condition. Thermal neutron flux of 6.1x107 n/cm2s and Cd-ratio of 364 are achieved finally

  4. Neutron activation analysis of urinary calculi

    International Nuclear Information System (INIS)

    Urinary calculi resulting from disorders in the urinary system are mostly composed of uric acid, urates, calcium oxalate, alkaline earth phosphates (Ca and Mg), triple phosphate (magnesium ammonium phosphate), calcium carbonate, cystine, xanthine, and traces of proteins. The determination of these macro-constituents has been carried out by different analytical procedures. No attempts however, have been reported regarding the determination of trace elements in urinary stones, apart from that of Herring et al., who investigated the consumption of strontium by urolithiasis patients. The present work is a non-destructive neutron activation analysis of urinary calculi, to search the variation in concentration of certain trace elements with the chemical composition of the calculus

  5. Neutron activation analysis of human hair

    International Nuclear Information System (INIS)

    In an attempt to study the availability and limitation of analytical data of human hair as an indicator of environmental pollution and/or of human health effect, concentrations of elements in 202 scalp hair samples collected from local population in the Tokyo Metropolitan area were determined by instrumental neutron activation analysis. The correlation coefficients between concentrations of 13 elements in each sex and in each age group were calculated and discussed. There were significant correlations between some pairs of elements, i.e. Na-K, Br-Cl, Ca-Zn and Ca-Mg, in all five age classes in both of male and female, indicating that the correlations were consistent. Ca was observed to be reversely correlated with Cl. No significant correlation was apparent between Hg and Se, when the correlation coefficient was calculated using logarithmic converted concentration data. (author)

  6. Instrumental neutron activation analysis of kidney stones

    International Nuclear Information System (INIS)

    Kidney stone samples of the types calcium oxalate, uric acid, and xanthine were analyzed for their elemental contents by neutron activation analysis to study both the elemental correlation and influence of element on stone precipitation processes. Elements, such as Al, Au, Br, Ca, Cl, Co, Cr, Fe,H, I, K, Mg, Na, Sb, Se, Sr, and Zn, were determined quantitatively. Calcium oxalate stones contained higher concentration of all the elements analyzed compared to uric acid or xanthine stones. The concentrations of Cl, Fe, K, Na, Sr, and Zn were relatively higher than Au, Co, Cr, and Sb. A positive correlation exists between Ca and Zn, whereas a negative correlation exists between Sr and Ca. Zinc may play an important role in the formation of calcium oxalate stone

  7. Large sample neutron activation analysis of a ceramic vase

    OpenAIRE

    Stamatelatos, I.E.; Tzika, F.; Vasilopoulou, T.; Koster-Ammerlaan, M.J.J.

    2010-01-01

    Large Sample Neutron Activation Analysis (LSNAA) was applied to perform non-destructive elemental analysis of a ceramic vase. Appropriate neutron self-shielding and gamma ray detection efficiency calibration factors were derived using Monte Carlo code MCNP5. The results of LSNAA were compared against Instrumental Neutron Activation Analysis (INAA) results and a satisfactory agreement between the two methods was observed. The ratio of derived concentrations between the two methods was within 0...

  8. Neutron activation analysis of human hair

    International Nuclear Information System (INIS)

    As a part of IAEA research project, ''Activation analysis of hair as an indicator of contamination of man by environmental trace element pollutants'', a survey was carried out to elucidate the levels of various trace element concentration in hair of local population in the Tokyo Metropolitan areas, by applying instrumental neutron activation analysis. A total of 202 scalp hair samples were collected from the inhabitants classified by sex and five age classes. Irradiation was made in the Rikkyo University 100 kW TRIGA MARK-II reactor. Using several combinations of irradiation time, cooling time and counting time, forty elements were determined. The relationship between several trace element contents in hair and such factors as sex, age class, hair treatment, smoking habit and dental treatment, was analyzed by using the method of multiple regression. It was shown that (1) Hair treatment had a predominant effect on the contents of bromine, magnesium and calcium in hair, (2) Aging and amoking contributed increasing mercury content in hair, and hair treatment acted reversely. (author)

  9. Development of educational program for neutron activation analysis

    International Nuclear Information System (INIS)

    This technical report is developed to apply an educational and training program for graduate student and analyst utilizing neutron activation analysis. The contents of guide book consists of five parts as follows; introduction, gamma-ray spectrometry and measurement statistics, its applications, to understand of comprehensive methodology and to utilize a relevant knowledge and information on neutron activation analysis

  10. Trace Analysis of Ancient Gold Objects Using Radiochemical Neutron Activation

    CERN Document Server

    Olariu, A; Constantinescu, O; Badica, T; Popescu, I V; Besliu, C; Leahu, D; Olariu, Agata; Constantinescu, Mioara; Leahu, Doina

    1999-01-01

    Radiochemical neutron activation analysis has been applied to investigate the microelements in gold samples with archaeological importance. Chemical separation has allowed the determination of traces of Ir, Os, Sb, Zn, Co, Fe, Ni. Instrumental neutron activation analysis has been used for the determination of Cu.

  11. Development of educational program for neutron activation analysis

    Energy Technology Data Exchange (ETDEWEB)

    Chung, Yong Sam; Moon, Jong Hwa; Kim, Sun Ha; Ryel, Sung; Kang, Young Hwan; Lee, Kil Yong; Yeon, Yeon Yel; Cho, Seung Yeon

    2000-08-01

    This technical report is developed to apply an educational and training program for graduate student and analyst utilizing neutron activation analysis. The contents of guide book consists of five parts as follows; introduction, gamma-ray spectrometry and measurement statistics, its applications, to understand of comprehensive methodology and to utilize a relevant knowledge and information on neutron activation analysis.

  12. Analysis of ayurvedic medicinal leaves by instrumental neutron activation analysis

    International Nuclear Information System (INIS)

    Concentrations of 15 elements were determined in medicinally important ayurvedic medicinal leaves. Instrumental neutron activation analysis was employed for the determination of the elements viz. Na, K, Br, Sm, Cr, Zn, Th, Rb, Sr, Fe, La, Co, Ce, Cs and Eu. The samples were neutron irradiated at 100 kW TRIGA -Mainz nuclear reactor and the induced activities were measured by gamma ray spectrometry using an efficiency calibrated high resolution high purity germanium (HPGe) detector. The concentrations of these elements in the medicinal leaves and their medicinal importance are discussed. (author)

  13. Multielemental analysis of soils by instrumental neutron activation analysis

    International Nuclear Information System (INIS)

    The results of an instrumental neutron activation analysis of some elemental concentrations in different soil samples near the industrial areas at Tirupati, India, are reported. Altogether 14 elements, Sm, La, Cr, Co, Zn, Cs, Ce, Th, Rb, Na, K, Sr, Fe and Eu were determined. The samples were irradiated with neutrons at the 100 kW Triga - Mainz research reactor and the induced activities were measured by gamma-ray spectrometry using an efficiency calibrated high resolution high purity germanium (HPGe) detector in connection with a multichannel analyzer. The results are discussed. (author)

  14. Analysis by neutron activation analysis a some ancient Dacian ceramics

    CERN Document Server

    Olariu, A

    1999-01-01

    Ancient Dacian ceramics, from three different establishments from Romanian territory have been analyzed by neutron activation analysis. A series of elements has been determined: Ba, Eu, K, La, Mn, Na, Sc, Sm. Ba is the element that could be considered to differentiate relatively the three groups of ceramics.

  15. Neutron activation analysis of arsenic in Greece

    International Nuclear Information System (INIS)

    Arsenic is considered a toxic trace element for plant, animal, and human organisms. Arsenic and certain arsenic compounds have been listed as carcinogens by the U.S. Environmental Protection Agency. Arsenic is emitted in appreciable quantities into the atmosphere by coal combustion and the production of cement. Arsenic enters the aquatic environment through industrial activities such as smelting of metallic ores, metallurgical glassware, and ceramics as well as insecticide production and use. Neutron activation analysis (NAA) is a very sensitive, precise, and accurate method for determining arsenic. This paper is a review of research studies of arsenic in the Greek environment by NAA performed at our radioanalytical laboratory. The objectives of these studies were (a) to determine levels of arsenic concentrations in environmental materials, (b) to pinpoint arsenic pollution sources and estimate the extent of arsenic pollution, and (c) to find out whether edible marine organisms from the gulfs of Greece receiving domestic, industrial, and agricultural wastes have elevated concentrations of arsenic in their tissues that could render them dangerous for human consumption

  16. Quality assurance in neutron activation analysis

    International Nuclear Information System (INIS)

    As a potential reference method, neutron activation analysis does not have to rely on other reference materials to ascertain the quality of analytical results. The fundamental characteristics of the method with the clear separation between irradiation, processing, and counting makes possible the estimation of uncertainties of individual results from a priori assumptions. Such estimates of the standard deviation from a series of independent sources of variation are compared with the a posteriori variability of replicate determinations in order to ascertain that the analytical method is in a state of statistical control. This Analysis of Precision tests the absence of unknown errors by means of a statistic T, which is closely approximated by a chi-square distribution. In this manner an evaluation is made of a commercially available computer program for peak evaluation in γ-spectrometry, as well as of other factors affecting the precision and accuracy of the counting process. An attempt is also made to determine sampling constants of one gram or less in a candidate biological reference material

  17. Epithermal neutron activation analysis in applied microbiology

    International Nuclear Information System (INIS)

    Some results from applying epithermal neutron activation analysis at FLNP JINR, Dubna, Russia, in medical biotechnology, environmental biotechnology and industrial biotechnology are reviewed. In the biomedical experiments biomass from the blue-green alga Spirulina platensis (S. platensis) has been used as a matrix for the development of pharmaceutical substances containing such essential trace elements as selenium, chromium and iodine. The feasibility of target-oriented introduction of these elements into S. platensis biocomplexes retaining its protein composition and natural beneficial properties was shown. The absorption of mercury on growth dynamics of S. platensis and other bacterial strains was observed. Detoxification of Cr and Hg by Arthrobacter globiformis 151B was demonstrated. Microbial synthesis of technologically important silver nanoparticles by the novel actinomycete strain Streptomyces glaucus 71 MD and blue-green alga S. platensis were characterized by a combined use of transmission electron microscopy, scanning electron microscopy and energy-dispersive analysis of X-rays. It was established that the tested actinomycete S. glaucus 71 MD produces silver nanoparticles extracellularly when acted upon by the silver nitrate solution, which offers a great advantage over an intracellular process of synthesis from the point of view of applications. The synthesis of silver nanoparticles by S. platensis proceeded differently under the short-term and long-term silver action. (author)

  18. Neutron-activation analysis of plant materials

    International Nuclear Information System (INIS)

    The possibilities offered by non-destructive neutron activation analysis (NAA) for simultaneously determining a large number of micro- and macro-components in plant samples of Bulgarian origin have been studied. Three groups of elements are determined: short half-life isotopes: Al, Mg, Ca, Na, Mn, Cl, Cu; medium half-life isotopes: Br, Na, K; and long half-life isotopes: Fe, Cr, Co, Sc, Pb, Zn. The samples are kept for 1 minute in a fluxes of 6x1012 n.cm2.sec-1 (first group), and of 3x1011 n.cm2.sec-1 for 18 hours (second and third groups). Use is made of a Ge/Li detector and 4000-channel analyser. To test the accuracy of the method, the results of NAA for some standard specimens have been compared with the indicators of other conventional methods tested in 18 laboratories in various countries. The data from NAA for the content of K, Mo, Ca, Mn, Fe, Zn and Cu demonstrate a high degree of coincidence with those from the other methods. Chemical composition of 23 samples of experimental and field crops is determined

  19. Neutron activation analysis of geothermal water

    International Nuclear Information System (INIS)

    Instrumental technique of determination of 16 microimpurities in geothermal water samples is worked out. Probes and standard samples with cadmium filter have been irradiated by the thermal neutron flux of 5x1013 neutr.xcm-2xc-1. Cadmium filter permitted to considerably decrease 24Na radio activity caused by its high content in geothermal water, and to measure radioactivity in several hours after irradiation. Radioactivity measurement has been carried out without probe unpacking

  20. Simultaneous speciation analysis using neutron activation

    International Nuclear Information System (INIS)

    Full text: Neutron activation analysis (NAA) is a well-established analytical technique for the simultaneous determination of multielement concentrations. Although various forms of NAA have been traditionally applied to measuring the total concentrations of elements, the scope of NAA can be further extended in conjunction with pre-irradiation chemical separations to determine the species of an element. The technique can then be called speciation NAA (SNAA). Since much of the toxicity of an element depends on its physico-chemical forms, there is an increasing interest in studying its speciation. A number of characteristic features of NAA, which other techniques normally do not possess, can be advantageously exploited in SNAA. For example, SNAA has simultaneous multielement specificity unlike AAS and AFS. The SNAA technique can be applied to the simultaneous speciation of elements which are not chemically similar such as Cd, Se and I, as well as to the elements such as Cl, Br and I which are rather difficult to determine by most other techniques. Qualitative as well as quantitative analysis of small samples can be done by SNAA with excellent precision, accuracy, sensitivity, and rapidity. Unlike many other techniques, SNAA has some enhanced quality assurance capabilities. We have developed SNAA methods for separating various inorganic and organic arsenic species in water and in sea foods. We are presently extending these methods to include simultaneous speciation of As, Sb and Se. We have also developed SNAA methods employing biochemical techniques for the characterization of metalloproteins and protein-bound trace element species of Se along with Cd, Cu, Mn, Mo and Zn in bovine kidneys. Lately, we have concentrated our efforts to develop SNAA methods in conjunction with HPLC, RPC, SEC, NMR and MS for the simultaneous separation and characterization of extractable organo chlorine, organo bromine and organo iodine species in fisheries samples. An overview of the

  1. Rapid radiochemical separations in neutron activation analysis

    International Nuclear Information System (INIS)

    Rapid radiochemical separation procedures based on the removal of metal ions by columns of C18-bonded silica gel after selective complexation are examined and the simplicity of the method demonstrated by its application to the determination of Mn, Cu and Zn in neutron-activated biological material. The method is rapid and reliable and readily adaptable in all radiochemical laboratories. An alternative separation procedure for selenium in blood plasma involving desalination and concentration of the selenium protein complex by gel filtration or ultrafiltration is briefly discussed. (author)

  2. Analysis of human enamel and dentine by neutron activation analysis

    International Nuclear Information System (INIS)

    Determination of trace elements in dental tissues has been of great interest to study the correlation between element composition and caries as well as food habits of individuals. In the present study dentine and enamel samples from healthy individuals were analysed by neutron activation analysis. The teeth were provided form dental clinics, and they were previously washed using purified water and acetone. Then they were dried at 40 deg C and ground in a agate mortar. The samples and element standards were irradiated with thermal neutrons at the IEA-R1 nuclear reactor. Long irradiations of 8 h under thermal neutron flux of 5x1012 n cm-2 s-1 were used for Ca, Na, Sr and Zn determinations. In short irradiations of 15 s and under neutron flux of 1012 n cm-2 s-1 the elements Mg, Mn, Na e Sr were determined. The induced gamma activities of the samples and standards were measured using a hyperpure Ge detector coupled to a gamma ray spectrometer. Elemental concentrations were calculated by comparative method. Results obtained showed that Ca, Mg and Na are present in both tissues at the level of percentages and the elements Mn, Sr and Zn at the μg g-1 levels. For quality control of the results the certified reference materials NIST 1400 Bone Ash and NIST 1486 Bone Meal were analysed. (author)

  3. Diagnosis of mucoviscidosis by neutron activation analysis. Part 1

    International Nuclear Information System (INIS)

    Symptoms pathology, incidence, and gravity of the inherent syndrome called mucoviscidosis, or cystic fibrosis are described in this Part I. The analytical methods used for its diagnosis, both the conventional chemical ones and by neutron activation analysis are also summarised. Finally, an analytical method to study the incidence of mucoviscidosis in Brazil is presented. This , essentially, consists in bromine determination, in fingernails, by resonance neutron activation analysis. (author)

  4. Neutron activation analysis of wheat samples

    Energy Technology Data Exchange (ETDEWEB)

    Galinha, C. [CERENA-IST, Technical University of Lisbon, Av. Rovisco Pais 1, 1049-001 Lisboa (Portugal); Instituto Tecnoclogico e Nuclear, URSN, E.N. 10, 2686-953 Sacavem (Portugal); Anawar, H.M. [Instituto Tecnoclogico e Nuclear, URSN, E.N. 10, 2686-953 Sacavem (Portugal); Freitas, M.C., E-mail: cfreitas@itn.pt [Instituto Tecnoclogico e Nuclear, URSN, E.N. 10, 2686-953 Sacavem (Portugal); Pacheco, A.M.G. [CERENA-IST, Technical University of Lisbon, Av. Rovisco Pais 1, 1049-001 Lisboa (Portugal); Almeida-Silva, M. [Instituto Tecnoclogico e Nuclear, URSN, E.N. 10, 2686-953 Sacavem (Portugal); Coutinho, J.; Macas, B.; Almeida, A.S. [INRB/INIA-Elvas, National Institute of Biological Resources, Est. Gil Vaz, 7350-228 Elvas (Portugal)

    2011-11-15

    The deficiency of essential micronutrients and excess of toxic metals in cereals, an important food items for human nutrition, can cause public health risk. Therefore, before their consumption and adoption of soil supplementation, concentrations of essential micronutrients and metals in cereals should be monitored. This study collected soil and two varieties of wheat samples-Triticum aestivum L. (Jordao/bread wheat), and Triticum durum L. (Marialva/durum wheat) from Elvas area, Portugal and analyzed concentrations of As, Cr, Co, Fe, K, Na, Rb and Zn using Instrumental Neutron Activation Analysis (INAA) to focus on the risk of adverse public health issues. The low variability and moderate concentrations of metals in soils indicated a lower significant effect of environmental input on metal concentrations in agricultural soils. The Cr and Fe concentrations in soils that ranged from 93-117 and 26,400-31,300 mg/kg, respectively, were relatively high, but Zn concentration was very low (below detection limit <22 mg/kg) indicating that soils should be supplemented with Zn during cultivation. The concentrations of metals in roots and straw of both varieties of wheat decreased in the order of K>Fe>Na>Zn>Cr>Rb>As>Co. Concentrations of As, Co and Cr in root, straw and spike of both varieties were higher than the permissible limits with exception of a few samples. The concentrations of Zn in root, straw and spike were relatively low (4-30 mg/kg) indicating the deficiency of an essential micronutrient Zn in wheat cultivated in Portugal. The elemental transfer from soil to plant decreases with increasing growth of the plant. The concentrations of various metals in different parts of wheat followed the order: Root>Straw>Spike. A few root, straw and spike samples showed enrichment of metals, but the majority of the samples showed no enrichment. Potassium is enriched in all samples of root, straw and spike for both varieties of wheat. Relatively to the seed used for cultivation

  5. Neutron activation analysis of wheat samples

    International Nuclear Information System (INIS)

    The deficiency of essential micronutrients and excess of toxic metals in cereals, an important food items for human nutrition, can cause public health risk. Therefore, before their consumption and adoption of soil supplementation, concentrations of essential micronutrients and metals in cereals should be monitored. This study collected soil and two varieties of wheat samples-Triticum aestivum L. (Jordao/bread wheat), and Triticum durum L. (Marialva/durum wheat) from Elvas area, Portugal and analyzed concentrations of As, Cr, Co, Fe, K, Na, Rb and Zn using Instrumental Neutron Activation Analysis (INAA) to focus on the risk of adverse public health issues. The low variability and moderate concentrations of metals in soils indicated a lower significant effect of environmental input on metal concentrations in agricultural soils. The Cr and Fe concentrations in soils that ranged from 93-117 and 26,400-31,300 mg/kg, respectively, were relatively high, but Zn concentration was very low (below detection limit Fe>Na>Zn>Cr>Rb>As>Co. Concentrations of As, Co and Cr in root, straw and spike of both varieties were higher than the permissible limits with exception of a few samples. The concentrations of Zn in root, straw and spike were relatively low (4-30 mg/kg) indicating the deficiency of an essential micronutrient Zn in wheat cultivated in Portugal. The elemental transfer from soil to plant decreases with increasing growth of the plant. The concentrations of various metals in different parts of wheat followed the order: Root>Straw>Spike. A few root, straw and spike samples showed enrichment of metals, but the majority of the samples showed no enrichment. Potassium is enriched in all samples of root, straw and spike for both varieties of wheat. Relatively to the seed used for cultivation, Jordao presented higher transfer coefficients than Marialva, in particular for Co, Fe, and Na. The Jordao and Marialva cultivars accumulated not statistically significant different

  6. Neutron Activation Analysis of Biological Materials by Means of Neutron Multiplicator

    International Nuclear Information System (INIS)

    We have studied the possibilities of instrumental neutron activation analysis of freeze-dried biological materials performed with neutron multiplicator of average power (subcritical assembly PS-1). Neutron flux in the vertical channel amounts to 2.3*106n/cm2sec, concentrations of Na, Al and Mn were determined in freeze-dried samples of blue-green alga Spirulina platensis (S.platensis) (author)

  7. Neutron activation analysis of ancient silver coins

    International Nuclear Information System (INIS)

    The amounts of gold and copper present as impurities in 500 Creek silver coins of the fifth century B.C. have been determined with a gamma-ray spectrometer, following neutron activation. The coinage from eight cities and kingdoms was studied; the average gold-content for different groups of coins varies between 0.02% and 0.3%, and the copper content between 0.1% and 10%. Evidence about trading connexions and of deliberate debasements of the coinage has been obtained, and several unsuspected plated coins were detected. The gold content was determined by measuring the intensity of the 0.411 MeV gamma-ray from Au198 (2.69 d); for the copper content the 0.511 MeV positron annihilation radiation from Cu64 (12.8 h) was used, and for silver the 0.884 MeV gamma-ray from Ag110m (253 d). Decay measurements were used as a check of identity. The technique of using total gamma-activity decay curves by themselves is insufficiently sensitive. For accurate work, the importance of approximate facsimile standards is stressed. (author)

  8. Fast neutron activation analysis of ancient mirror

    International Nuclear Information System (INIS)

    About fifty specimens of ancient Chinese bronze mirror from various dynasties are analysed by fast neutron radiated from neutron generator. The contents of copper, tin and lead in the mirror are listed in this paper. Experimental method and measurement equipment are described too

  9. Development of high flux thermal neutron generator for neutron activation analysis

    International Nuclear Information System (INIS)

    The new model DD110MB neutron generator from Adelphi Technology produces thermal (<0.5 eV) neutron flux that is normally achieved in a nuclear reactor or larger accelerator based systems. Thermal neutron fluxes of 3–5 · 107 n/cm2/s are measured. This flux is achieved using four ion beams arranged concentrically around a target chamber containing a compact moderator with a central sample cylinder. Fast neutron yield of ∼2 · 1010 n/s is created at the titanium surface of the target chamber. The thickness and material of the moderator is selected to maximize the thermal neutron flux at the center. The 2.5 MeV neutrons are quickly thermalized to energies below 0.5 eV and concentrated at the sample cylinder. The maximum flux of thermal neutrons at the target is achieved when approximately half of the neutrons at the sample area are thermalized. In this paper we present simulation results used to characterize performance of the neutron generator. The neutron flux can be used for neutron activation analysis (NAA) prompt gamma neutron activation analysis (PGNAA) for determining the concentrations of elements in many materials. Another envisioned use of the generator is production of radioactive isotopes. DD110MB is small enough for modest-sized laboratories and universities. Compared to nuclear reactors the DD110MB produces comparable thermal flux but provides reduced administrative and safety requirements and it can be run in pulsed mode, which is beneficial in many neutron activation techniques

  10. Neutron activation analysis for environmental sample in Thailand

    Energy Technology Data Exchange (ETDEWEB)

    Busamongkol, Arporn; Nouchpramool, Sunun; Bunprapob, Supamatthree [Office of Atomic Energy for Peace, Bangkok (Thailand); Sumitra, Tatchai [Chulalongkorn Univ., Dept. of Nuclear Technology, Bangkok (Thailand)

    2003-03-01

    Neutron Activation Analysis has been applied for the trace elements analysis in environmental samples. Thirty three samples of airborne particulate were collected every week at Ongkharak Nuclear Research Center (ONRC) during the period of June 1998 to March 1999. The Ti, I, Mg, Na, V, K, Cl, Al, Mn, Ca, As, Sm, Sb, Br, La, Ce, Th, Cr, Cs, Sc, Rb, Fe, Zn and Co were analyzed by Neutron Activation Analysis utilizing 2 MW TRIGA MARK III research reactor. The certified reference materials 1632a and 1633a from National Bureau of Standard were select as standard. (author)

  11. Neutron activation analysis of multielement in human organs

    International Nuclear Information System (INIS)

    To obtain the reference values or ranges of the elemental abundances in organs of Japanese male, neutron activation analysis was applied to nine kinds of autopsied organs, brain, heart, kidney, liver, lung, muscle, pancreas, spleen and thyroid. An applicability of multielement analysis of organs was studied prior to ordinary work. Accuracy and precision were investigated by analyzing the IAEA Certified Reference Materials, Horse Kidney, Whey Powder and Marine Sediment. The changes of count rate on various weights and the variations of the elemental abundances of five portions in organ were examined. It was found that organs were homogeneous for neutron activation analysis, except for kidney and lung. (author)

  12. Neutron activation analysis for environmental sample in Thailand

    International Nuclear Information System (INIS)

    Neutron Activation Analysis has been applied for the trace elements analysis in environmental samples. Thirty three samples of airborne particulate were collected every week at Ongkharak Nuclear Research Center (ONRC) during the period of June 1998 to March 1999. The Ti, I, Mg, Na, V, K, Cl, Al, Mn, Ca, As, Sm, Sb, Br, La, Ce, Th, Cr, Cs, Sc, Rb, Fe, Zn and Co were analyzed by Neutron Activation Analysis utilizing 2 MW TRIGA MARK III research reactor. The certified reference materials 1632a and 1633a from National Bureau of Standard were select as standard. (author)

  13. The verification of neutron activation analysis support system (cooperative research)

    International Nuclear Information System (INIS)

    Neutron activation analysis support system is the system in which even the user who has not much experience in the neutron activation analysis can conveniently and accurately carry out the multi-element analysis of the sample. In this verification test, subjects such functions, usability, precision and accuracy of the analysis and etc. of the neutron activation analysis support system were confirmed. As a method of the verification test, it was carried out using irradiation device, measuring device, automatic sample changer and analyzer equipped in the JRR-3M PN-3 facility, and analysis software KAYZERO/SOLCOI based on the k0 method. With these equipments, calibration of the germanium detector, measurement of the parameter of the irradiation field and analysis of three kinds of environmental standard sample were carried out. The k0 method adopted in this system is primarily utilized in Europe recently, and it is the analysis method, which can conveniently and accurately carried out the multi-element analysis of the sample without requiring individual comparison standard sample. By this system, total 28 elements were determined quantitatively, and 16 elements with the value guaranteed as analytical data of the NIST (National Institute of Standards and Technology) environment standard sample were analyzed in the accuracy within 15%. This report describes content and verification result of neutron activation support system. (author)

  14. Applied research of environmental monitoring using instrumental neutron activation analysis

    Energy Technology Data Exchange (ETDEWEB)

    Chung, Young Sam; Moon, Jong Hwa; Chung, Young Ju

    1997-08-01

    This technical report is written as a guide book for applied research of environmental monitoring using Instrumental Neutron Activation Analysis. The contents are as followings; sampling and sample preparation as a airborne particulate matter, analytical methodologies, data evaluation and interpretation, basic statistical methods of data analysis applied in environmental pollution studies. (author). 23 refs., 7 tabs., 9 figs.

  15. Significance of neutron activation analysis in landscape geochemistry problem solution

    International Nuclear Information System (INIS)

    Employment of neutron activation analysis is of interest for solution of many theoretical and applied problems of landscape geochemistry. The role of the analysis in the study of rare and scattered element migration is quite significant. It is shown using gold, bromine, yttrium and rare earths as examples. 1 tab

  16. Neutron activation analysis of chert artifacts from a Hopewell mound

    International Nuclear Information System (INIS)

    Six artifacts from a Hopewell mound located near Mt. Vernon, Indiana, and 21 geologic specimens from three different chert sources in the Ohio River Valley were analyzed by instrumental neutron activation analysis. Principal components analysis and posterior classification of the artifacts on the basis of Mahalanobis distance calculated probabilities were used to determine the most probable source for each of the artifacts. (author)

  17. Design of a prompt gamma neutron activation analysis system and neutron beam characteristics at HANARO

    International Nuclear Information System (INIS)

    The design features and neutron beam characteristics are described for a prompt gamma neutron activation analysis(PGNAA) system at HANARO in Korea Atomic Energy Research Institute(KAERI). As a method to obtain clean beam of thermal neutrons, Bragg diffraction technique of using PG crystal is applied. The Bragg angle is set at 45 .deg. and the diffracted beam is a polychromatic one composed of neutrons from all diffraction orders n(≤n≤6). The fast neutron and gamma backgrounds will be low enough due to the use of diffracted beam and a tapered collimator. A neutron flux of 1.0x108 n/cm2sec is calculated at sample position by considering the reflectivity of PG crystal. The γ-ray detection system is comprised of a 30% n-type HPGe detector, signal electronics and a fast ADC. Construction of the beam line and setting up of the detection system is proceeding

  18. Elemental analysis of ancient potteries using instrumental neutron activation analysis

    International Nuclear Information System (INIS)

    The provenance studies of archaeological artifacts like potteries, bricks, and coins demands elemental analysis. Instrumental Neutron Activation Analysis (INAA) with high resolution gamma ray spectrometry was used due to its high sensitivity and simultaneous multielement capability. The ancient pottery samples belong to Melchittamur, collected from Department of Ancient History, Tamilnadu, were irradiated in KAMINI reactor, IGCAR, Kalpakkam and counted using PC based Aptec MCA card. The peak areas were obtained using peak-fit PHAST software. The elemental concentrations were calculated using relative method with IAEA RM SL-1 as comparator. The concentrations of elements K, Sc, Cr, Mn, Fe, Co, In, Cs, La, Ce, Sm, Eu, Hf and Th were determined. The % uncertainties are within 1-12% except for Cr, In, Cs and Th

  19. Neutron Activation Analysis for investigation of elemental composition of Amarantus

    International Nuclear Information System (INIS)

    In this work instrumental neutron activation analysis is applied for the characterization of the elemental composition of Amaranthus seeds, known in the prehistorical period, a tropical plant with promising nutritional and economic value. The characterization is enriched by the results of radiochemical neutron activation analysis for cobalt, molybdenum and uranium content. The comparison of the results, for three sorts of edible flour, commercially available: Soya Flour, Corn Bean Flour and Amaranthus Flour, is presented. The validation of the analytical methods used was carried out on the basis of participation in the interlaboratory comparison organized by the INCT (INCT-TL-1, INCT-MPH-2) and by NIST (SRM 1575a). (author)

  20. Establishment of rabbit radiation facility for neutron activation analysis

    International Nuclear Information System (INIS)

    The transfer principle and the composition of a rabbit radiation facility for neutron activation analysis in a reactor were introduced. The functions and security designs of the pneumatic transfer system and automatic control system in the irradiation device were studied. By the testing,the transfer speed of the facility is 7.0 m/s. The facility has advantages of steady transmission, simple operation, easy maintenance, etc. The facility satisfies the demand of the neutron activation analysis for short half-life nuclides. (authors)

  1. Elemental analysis of brazing alloy samples by neutron activation technique

    International Nuclear Information System (INIS)

    Two brazing alloy samples (C P2 and C P3) have been investigated by Neutron activation analysis (NAA) technique in order to identify and estimate their constituent elements. The pneumatic irradiation rabbit system (PIRS), installed at the first egyptian research reactor (ETRR-1) was used for short-time irradiation (30 s) with a thermal neutron flux of 1.6 x 1011 n/cm2/s in the reactor reflector, where the thermal to epithermal neutron flux ratio is 106. Long-time irradiation (48 hours) was performed at reactor core periphery with thermal neutron flux of 3.34 x 1012 n/cm2/s, and thermal to epithermal neutron flux ratio of 79. Activation by epithermal neutrons was taken into account for the (1/v) and resonance neutron absorption in both methods. A hyper pure germanium detection system was used for gamma-ray acquisitions. The concentration values of Al, Cr, Fe, Co, Cu, Zn, Se, Ag and Sb were estimated as percentages of the sample weight and compared with reported values. 1 tab

  2. Study on palladium determination by neutron activation analysis

    International Nuclear Information System (INIS)

    This study presents results of Pd determinations in neutron activation analysis of spiked biological tissues and CCQM-P63 automotive catalyst. Pd spiked biological tissues of bovine muscle and liver were prepared using a blender with titanium blades and Pd solutions. These materials obtained in a past form were freeze-dried and homogenized before the analysis. Thermal and epithermal neutron activation analyses were applied in these determinations. Separations of Pd from interfering elements were also carried out using solvent extraction and solid-phase extraction techniques, before the irradiations with epithermal neutrons. The irradiations were carried out at the IEA-R1 nuclear research reactor under thermal neutron flux of about 4 x 1012 n cm-2 s-1 during 4 and 16 h for thermal and epithermal irradiations, respectively. The gamma activities of 109Pd of the irradiated samples and Pd standard were measured using an HGe detector coupled to a gamma ray spectrometer. Results obtained in these analyses indicated that the epithermal irradiation presented higher sensitivity, due to the reduction of interferences. The pre-separation procedure of solid-phase extraction applied also yielded low detection limit. Comparisons made between the Pd results obtained using different procedures of neutron activation analysis indicated a good agreement. The analyses carried out in replicates also indicated a good precision with relative standard deviations varying from 1.2 to 14 %. (author)

  3. MA-1 unit for instrumental fast neutron activation analysis

    International Nuclear Information System (INIS)

    A description of the MA-1 facility intended for performing an instrumental multielement activation analysis is giveperation of facility is based on the spectrometry of samples activated with fast neutrons. The facility comprises the M-6000 control computer complex, the 10N fast neutron generator, the ARS-28G pneumatic transporter, spectrometric devices and detection units. The facility can be used to determine the contents of more than 50 elements in different combinations in compact and powdery substances. Maximum sensitivity is achieved when determining Pr, Cu, Br, Ba, Pb, Sb, Si, P, Al, O and F. The measuring equipment of the facility is universal and after proper modification can be used in activation analysis with the use of nuclear reactors, electron accelerators, a cyclotron and neutron sources

  4. Neutron activation analysis at the Californium User Facility for Neutron Science

    International Nuclear Information System (INIS)

    The Californium User Facility (CUF) for Neutron Science has been established to provide 252Cf-based neutron irradiation services and research capabilities including neutron activation analysis (NAA). A major advantage of the CUF is its accessibility and controlled experimental conditions compared with those of a reactor environment The CUF maintains the world's largest inventory of compact 252Cf neutron sources. Neutron source intensities of ≤ 1011 neutrons/s are available for irradiations within a contamination-free hot cell, capable of providing thermal and fast neutron fluxes exceeding 108 cm-2 s-1 at the sample. Total flux of ≥109 cm-2 s-1 is feasible for large-volume irradiation rabbits within the 252Cf storage pool. Neutron and gamma transport calculations have been performed using the Monte Carlo transport code MCNP to estimate irradiation fluxes available for sample activation within the hot cell and storage pool and to design and optimize a prompt gamma NAA (PGNAA) configuration for large sample volumes. Confirmatory NAA irradiations have been performed within the pool. Gamma spectroscopy capabilities including PGNAA are being established within the CUF for sample analysis

  5. Neutron activation analysis of cadmium in Jamaican soils

    International Nuclear Information System (INIS)

    A procedure for the instrumental neutron activation analysis of Cd in soils with relatively high Cd content and possible interferences is reported. Cadmium concentrations in Jamaican soils above 4 mg x kg-1 can now be reliably determined by multielemental instrumental activation analysis with an accuracy ±10% and the reasonably high throughput of 30 samples per day. Over 600 geochemical survey samples were analysed for Cd along with some 20 other long-lived elements. (author)

  6. Neutron activation analysis - an aid to forensic science

    International Nuclear Information System (INIS)

    Forensic Science is oriented towards the examination of evidence specimens, collected from a scene of crime in order to establish the link between the criminal and the crime. This science therefore has a profound role to play in criminal justice delivery system. The importance of neutron activation analysis (NAA) as a specialised technique to aid crime investigation has emerged and has been recognised

  7. Use of cyclotron-produced fast neutrons in activation analysis

    International Nuclear Information System (INIS)

    The determination of 15 elements: Pb, Sr, Ba, Ti, Ca, Sc, Cs, Zr, Rb, Cr, Se, Ni, Y, Co and Zn was investigated by fast neutron activation analysis using 80 MeV deuterons on various environmental samples. Detection limits of these elements from interference-free spectra were calculated. (author)

  8. Initial trials for in-house neutron activation analysis

    International Nuclear Information System (INIS)

    A range of elements in previously analysed rock samples have been assayed by neutron activation analysis and the practicality of performing such analyses at the Institute of Geological and Nuclear Sciences has been established. Further work is needed to fully refine the technique. A cost estimate has been made for a routine procedure. (author) 1 tab., 6 figs

  9. Neutron activation analysis of final molasses from the sugar industry

    International Nuclear Information System (INIS)

    Molasses samples from 74 factories were analyzed by neutron activation analysis. The concentration values of the 35 elements was determined. The toxicity and the influence of the presence of theses elements in sugar loss in the molasses and fermentative process is discussed

  10. Neutron activation analysis of different types of cuban sugar

    International Nuclear Information System (INIS)

    The Concentration of minor and trace elements in sugars (refined, crude and white-direct) from different Cuban mills were determined using instrumental neutron activation analysis with reactor, fourteen elements were fixed: Br, Ce, Co, Cr, Cs, Eu, Fe, La, Rb, Sc, Tb, Sr and Zn. The comparison of teh average concentration in sugar with another food samples is present

  11. Isotope identification of Langkawi black sand using neutron activation analysis

    International Nuclear Information System (INIS)

    The Langkawi black sand has been analyzed using the method of neutron activation analysis (INAA). A total of 22 elements have been detected. Elements such as Mn, Cu, Cr, U and Th occur in high concentration. Prospect for future mineralization of these elements may be of economic interest. (author) 9 refs.; 1 tab

  12. Instrumental Neutron Activation Analysis Technique using Subsecond Radionuclides

    DEFF Research Database (Denmark)

    Nielsen, H.K.; Schmidt, J.O.

    1987-01-01

    The fast irradiation facility Mach-1 installed at the Danish DR 3 reactor has been used in boron determinations by means of Instrumental Neutron Activation Analysis using12B with 20-ms half-life. The performance characteristics of the system are presented and boron determinations of NBS standard...

  13. Methodological developments and applications of neutron activation analysis

    Czech Academy of Sciences Publication Activity Database

    Kučera, Jan

    2007-01-01

    Roč. 273, č. 2 (2007), s. 273-280. ISSN 0236-5731 Institutional research plan: CEZ:AV0Z10480505 Keywords : neutron activation analysis * radiochemical separation Subject RIV: BE - Theoretical Physics Impact factor: 0.499, year: 2007

  14. Mercury mass measurement in fluorescent lamps via neutron activation analysis

    Czech Academy of Sciences Publication Activity Database

    Viererbl, L.; Vinš, M.; Lahodová, Z.; Fuksa, A.; Kučera, Jan; Koleska, M.; Voljanskij, A.

    2015-01-01

    Roč. 116, NOV (2015), s. 56-59. ISSN 0969-806X R&D Projects: GA TA ČR TA01010237; GA MŠk LM2011019 Institutional support: RVO:61389005 Keywords : fluorescent lamp * mercury measurement * neutron activation analysis * research reactor Subject RIV: BG - Nuclear, Atomic and Molecular Physics, Colliders Impact factor: 1.380, year: 2014

  15. The multielement potential of fast neutron cyclic activation analysis

    International Nuclear Information System (INIS)

    Cyclic neutron activation analysis (CNAA) has, in recent years been developed as a useful analytical tool for the assay of short-lived isotopes in single element situations. The work described in this paper investigates the potential of the technique for composite samples having a wide range of elements that produce short-lived and long-lived isotopes on neutron irradiation. Accelerator-derived neutrons with average energies of 3 MeV, 6 MeV and 14 MeV were employed in what has been dubbed 'Fast Neutron Cyclic Neutron Activation Analysis' (FNCAA). The approach to multi-element analysis entailed: determination of cycle parameters in single element samples via the reactions 27Al(n,p)27Mg(9.6 min,Eγ=840keV), and 137Ba(n,n'γ137mBa(2.3 min,Eγ137mBa(2.3 min,Eγ=662 keV), a test of the method on a composite rock sample, determination of analytical sensitivities using both powdered kale and rock standards and a comparison of analytical results with other techniques. The results obtained in all these measurements are presented and discussed. (author) 10 refs.; 3 figs.; 5 tabs

  16. Current status of neutron activation analysis in HANARO Research Reactor

    International Nuclear Information System (INIS)

    The facilities for neutron activation analysis in the HANARO (Hi-flux Advanced Neutron Application Research Reactor) are described and the main applications of NAA (Neutron Activation Analysis) are reviewed. The sample irradiation tube, automatic and manual pneumatic transfer system were installed at three irradiation holes of HANARO at the end of 1995. The performance of the NAA facility was examined to identify the characteristics of the tube transfer system, irradiation sites and custom-made polyethylene irradiation capsule. The available thermal neutron fluxes at irradiation sites are in the range of 3 x 1013 - 1 x 1014 n/cm2·s and cadmium ratios are in 15 - 250. For an automatic sample changer for gamma-ray counting, a domestic product was designed and manufactured. An integrated computer program (Labview) to analyse the content was developed. In 2001, PGNAA (Prompt Gamma Neutron Activation Analysis) facility has been installed using a diffracted neutron beam of ST1. NAA has been applied in the trace component analysis of nuclear, geological, biological, environmental and high purity materials, and various polymers for research and development. The improvement of analytical procedures and establishment of an analytical quality control and assurance system were studied. Applied research and development for the environment, industry and human health by NAA and its standardization were carried out. For the application of the KOLAS (Korea Laboratory Accreditation Scheme), evaluation of measurement uncertainty and proficiency testing of reference materials were performed. Also to verify the reliability and to validate analytical results, intercomparison studies between laboratories were carried out. (author)

  17. Current status of neutron activation analysis in HANARO Research Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Chung, Yong Sam; Moon, Jong Hwa; Sohn, Jae Min [Korea Atomic Energy Research Institute, Daejeon (Korea)

    2003-03-01

    The facilities for neutron activation analysis in the HANARO (Hi-flux Advanced Neutron Application Research Reactor) are described and the main applications of NAA (Neutron Activation Analysis) are reviewed. The sample irradiation tube, automatic and manual pneumatic transfer system were installed at three irradiation holes of HANARO at the end of 1995. The performance of the NAA facility was examined to identify the characteristics of the tube transfer system, irradiation sites and custom-made polyethylene irradiation capsule. The available thermal neutron fluxes at irradiation sites are in the range of 3 x 10{sup 13} - 1 x 10{sup 14} n/cm{sup 2}{center_dot}s and cadmium ratios are in 15 - 250. For an automatic sample changer for gamma-ray counting, a domestic product was designed and manufactured. An integrated computer program (Labview) to analyse the content was developed. In 2001, PGNAA (Prompt Gamma Neutron Activation Analysis) facility has been installed using a diffracted neutron beam of ST1. NAA has been applied in the trace component analysis of nuclear, geological, biological, environmental and high purity materials, and various polymers for research and development. The improvement of analytical procedures and establishment of an analytical quality control and assurance system were studied. Applied research and development for the environment, industry and human health by NAA and its standardization were carried out. For the application of the KOLAS (Korea Laboratory Accreditation Scheme), evaluation of measurement uncertainty and proficiency testing of reference materials were performed. Also to verify the reliability and to validate analytical results, intercomparison studies between laboratories were carried out. (author)

  18. Application of inelastic neutron scattering and prompt neutron activation analysis in coal quality assessment

    International Nuclear Information System (INIS)

    The basic principles are assessed of the determination of ash content in coal based on the measurement of values proportional to the effective proton number. Discussed is the principle of coal quality assessment using the method of inelastic neutron scattering and prompt neutron activation analysis. This is done with respect both to theoretical relations between measured values and coal quality attributes and to practical laboratory measurements of coal sample quality by the said methods. (author)

  19. Neutron activation analysis of polyethylene from neutron shield of EDELWEISS experiment

    Energy Technology Data Exchange (ETDEWEB)

    Rakhimov, Alimardon V. [Joint Institute for Nuclear Research (JINR), Dubna (Russian Federation); Uzbek Academy of Sciences (INP AS RUz), Tashkent (Uzbekistan). Inst. of Nuclear Physics; Brudanin, Viktor B.; Filosofov, Dmitry V. [Joint Institute for Nuclear Research (JINR), Dubna (Russian Federation); and others

    2015-07-01

    Instrumental neutron-activation analysis (INAA) was applied to estimate trace contaminations in polyethylene (PE) used as a neutron shield for low background setup of the EDELWEISS Dark Matter search experiment. PE samples with masses of 1-10 grams each were irradiated at the WWR-SM nuclear reactor by neutron flux of 1 x 10{sup 14}n/(cm{sup 2}s) for 5-48 h. The radioactivity was measured by high-resolution γ-ray spectrometry. In PE samples of two types, more than 30 trace elements were determined at a concentration level of 10{sup -5} to 10{sup -11} g/g.

  20. Neutron activation analysis (NAA), radioisotope production via neutron activation (PNA) and fission product gas-jet (GJA)

    Energy Technology Data Exchange (ETDEWEB)

    Gaeggeler, H.W. [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

    1996-11-01

    Three different non-diffractive applications of neutrons are outlined, neutron activation analysis, production of radionuclides, mostly for medical applications, and production of short-lived fission nuclides with a so-called gas-jet. It is shown that all three devices may be incorporated into one single insert at SINQ due to their different requests with respect to thermal neutron flux. Some applications of these three facilities are summarized. (author) 3 figs., 1 tab., 8 refs.

  1. Determination of iodine 129 in vegetables using neutron activation analysis

    International Nuclear Information System (INIS)

    The developed methodology allows the determination of iodine 129 in vegetables, using neutron activation analysis. The chemical treatment removes the interferences present in these matrixes, as well as the bromine 82 originated in the activation process. The experimental method for the determination of iodine 129 by neutron activation analysis involves five steps: 1- digestion by alkaline fusion; 2- pre-irradiation purification of iodine 129 by distillation followed by solvent extraction, and adsorption on activated charcoal by distillation; 3- neutron irradiation; 4- post-irradiation purification of iodine 130 by distillation followed by solvent extraction; 5- gamma spectrometry. A chemical recovery of 95 % is obtained in the distillations, measured using iodine 131 as tracer. The whole process recovery is within 70 % and 85 %. The detection limit is 2 mBq/kg of sample, but several factors affect this value, such as type of vegetable, natural iodine concentration, irradiation time and neutron flux. The methodology developed is applied at environmental surveillance with safeguards proposes, in the detection of undeclared reprocessing of irradiated fuel. (authors)

  2. Protein determination in soya bean by fast neutron activation analysis

    International Nuclear Information System (INIS)

    For a non-destructive determination of the protein content in soya bean samples, 14-MeV neutron activation analysis was applied. To check the method, the results obtained by X-ray fluorescence analysis and the Kjeldahl procedure were compared. For pressed pellet samples of about 1 g with 15 min irradiation and 10 min measuring times the accuracy of the protein determination was found to be 15%. (author) 7 refs.; 4 figs.; 3 tabs

  3. A dosimetry study of deuterium-deuterium neutron generator-based in vivo neutron activation analysis

    Science.gov (United States)

    Sowers, Daniel A.

    A neutron irradiation cavity for in vivo Neutron Activation Analysis (IVNAA) to detect manganese, aluminum, and other potentially toxic elements in human hand bone has been designed and its dosimetric specifications measured. The neutron source is a customized deuterium-deuterium neutron generator which produces neutrons at 2.45 MeV by the fusion reaction 2H(d, n)3He at a calculated flux of 7 x 108 +/-30% s-1. A moderator/reflector/shielding (5 cm high density polyethylene (HDPE), 5.3 cm graphite & 5.7 cm borated HDPE) assembly has been designed and built to maximize the thermal neutron flux inside the hand irradiation cavity and to reduce the extremity dose and effective dose to the human subject. Lead sheets are used to attenuate bremsstrahlung x rays and activation gammas. A Monte Carlo simulation (MCNP6) was used to model the system and calculate extremity dose. The extremity dose was measured with neutron and photon sensitive film badges and Fuji electronic pocket dosimeter (EPD). The neutron ambient dose outside the shielding was measured by Fuji NSN3, and photon dose by a Bicron MicroREM scintillator. Neutron extremity dose was calculated to be 32.3 mSv using MCNP6 simulations given a 10 min IVNAA measurement of manganese. Measurements by EPD and film badge indicate hand dose to be 31.7 +/- 0.8 mSv for neutron and 4.2 +/- 0.2 mSv for photon for 10 mins; whole body effective dose was calculated conservatively to be 0.052 mSv. Experimental values closely match values obtained from MCNP6 simulations. These are acceptable doses to apply the technology for a manganese toxicity study in a human population.

  4. Aspects of precision and accuracy in neutron activation analysis

    International Nuclear Information System (INIS)

    Analytical results without systematic errors and with accurately known random errors are normally distributed around their true values. Such results may be produced by means of neutron activation analysis both with and without radiochemical separation. When all sources of random variation are known a priori, their effect may be combined with the Poisson statistics characteristic of the counting process, and the standard deviation of a single analytical result may be estimated. The various steps of a complete neutron activation analytical procedure are therefore studied in detail with respect to determining their contribution to the overall variability of the final result. Verification of the estimated standard deviation is carried out by demonstrating the absence of significant unknown random errors through analysing, in replicate, samples covering the range of concentrations and matrices anticipated in actual use. Agreement between the estimated and the observed variability of replicate results is then tested by a simple statistic T based on the chi-square distribution. It is found that results from neutron activation analysis on biological samples can be brought into statistical control. In routine application of methods in statistical control the same statistical test may be used for quality control when some of the actual samples are analysed in duplicate. This analysis of precision serves to detect unknown or unexpected sources of variation of the analytical results, and both random and systematic errors have been discovered in practical trace element investigations in different areas of research. Particularly, at the ultratrace level of concentration where there are few or no standard reference materials for ascertaining the accuracy of results, the proposed quality control based on the analysis of precision combined with neutron activation analysis with radiochemical separation, with an a priori precision independent of the level of concentration, becomes a

  5. Activation analysis utilizing fast radiochemical separations and portable neutron generators

    International Nuclear Information System (INIS)

    Experience at the University of Michigan in adapting radiochemical procedures to short-half-lived radioisotopes and in working with neutron generators indicates that activation analysis can become a rapid routine industrial method for certain types of analysis. Portable neutron generators with thermal fluxes approaching 108 to 109 n/cm2 s, which have recently become available, offer the large analytical laboratory its own source of neutrons for activation analysis at a cost of about $ 20 000. In addition, rapid radiochemical procedures permit separation of activated products in a matter of minutes and completion of analyses for many elements in less than an hour. Rapid radiochemical separations have been devised for several elements. The sensitivities obtained from a 6-min irradiation of these elements are at least of the same order of magnitude and often better than those obtained with lengthy irradiations. Typical separation times are for vanadium 4 min and for silver 5 min. Thus it has been possible to make a complete analysis of samples ranging from meteorites to rat liver tissue, from marine biological ashes to crude petroleum, all within periods of 1/2 h to 1 h. These fast radiochemical techniques are also being applied to an evaluation of a Texas Nuclear Corporation neutron generator for use in activation analysis. This Cockcroft-Walton machine is small and compact; portable concrete shielding blocks suffice for protection. Although the present flux obtainable is less than 0.1% of the flux available in the pneumatic tube positions of the Michigan reactor, it is still sufficient to determine microgram amounts of an element such as vanadium. (author)

  6. Laboratory of neutron activation analysis at the Nuclear Physics Institute ASCR, Řež

    Czech Academy of Sciences Publication Activity Database

    Kučera, Jan

    2011-01-01

    Roč. 21, č. 1 (2011), s. 30-35. ISSN 1061-9127 Institutional research plan: CEZ:AV0Z10480505 Keywords : Instrumental neutron activation analysis * epithermal neutron activation analysis * radiochemical neutron activation analysis * applications in science and technology Subject RIV: BG - Nuclear, Atomic and Molecular Physics , Colliders

  7. The monostandard method in thermal neutron activation analysis

    International Nuclear Information System (INIS)

    A simple method is described for instrumental multielement thermal neutron activation analysis using a monostandard. For geological and air dust samples, iron is used as a comparator, while sodium has advantages for biological materials. To test the capabilities of this method, the values of the effective cross sections of the 23 elements determined were evaluated in a reactor site with an almost pure thermal neutron flux of about 9 x 1012 n x cm-2 x sec-1 and an epithermal neutron contribution of less than 0,03%. The obtained values were found to agree mostly well with the literature best values of thermal neutron cross sections. The results of an analysis by activation in the same site agree well with the relative method using multielement standard and for several standard reference materials with certified element contents. A comparison of the element contents obtained by the monostandard and relative methods together with corresponding precisions and accuracies is given. A brief survey of the monostandard method is presented. (orig.)

  8. A new microcomputer-controlled neutron activation and analysis system

    International Nuclear Information System (INIS)

    A microcomputer-controlled irradiation and measurement system and a microprocessor-controlled sample changer have been installed at the SLOWPOKE-2 Facility at the Royal Military College of Canada (RMC). These systems can provide the gamut of instrumental neutron activation analysis (INAA) techniques for the analyst. Custom software has been created for system control, data acquisition, and off-line spectral analysis using programs that incorporate Gaussian peak-fitting methods of analysis. The design and use of the equipment is discussed, and the performance is illustrated with results obtained from the analysis of marine sediment and biological reference materials

  9. Simulation for sodium-24 production using cyclic neutron activation analysis

    International Nuclear Information System (INIS)

    The cyclic neutron activation analysis is a method for elemental analysis which is preferred to use short-lived radio-nuclides. In recent years this method became a new application for radioisotope production especially in low power research reactors. In this study instrumental cyclic neutron activation analysis was used for 24Na production using 23Na (n, γ) 24Na reaction. The simplified westcott convention method is used neutron activation analysis in a research reactor. The method takes into account all corrections that can affect that yield created. In this work a model was devolving for calculations through this simplified Westcott convention method by using C++ program and selecting good parameters that can produce the expected activity. The simulation is used for the theoretical yield calculated has been validated by data from the 177Lu production used for theoretical yield which it gives the approached result had been obtained by FORTRAN 90 from literature (8). The results were achieved for expected activity at full power (1 x 10 12n cm-2 s-1) and half power (5 x 1011 cm-2 s-1) for research reactor MNSR. The activity at full power was equal to about twice the activity at half power ( 49±7, 24.9 ± MBq/g), respectively. The irradiation parameters selected were irradiation time 4 min and decay time 12 min. Sample weight was 50 mg at 12 numbers of cycles, when the K-factor was equal to 1.74. This work is considered as first step for production of 24Na which can use such parameters experimentally. It is then possible to compare the expected activity with measured activity. (Author)

  10. Applied research and development of neutron activation analysis

    Energy Technology Data Exchange (ETDEWEB)

    Chung, Yong Sam; Moon, Jong Hwa; Kim, Sun Ha; Baek, Sung Ryel; Kim, Young Gi; Jung, Hwan Sung; Park, Kwang Won; Kang, Sang Hun; Lim, Jong Myoung

    2003-05-01

    The aims of this project are to establish the quality control system of Neutron Activation Analysis(NAA) due to increase of industrial needs for standard analytical method and to prepare and identify the standard operation procedure of NAA through practical testing for different analytical items. R and D implementations of analytical quality system using neutron irradiation facility and gamma-ray measurement system and automation of NAA facility in HANARO research reactor are as following ; 1) Establishment of NAA quality control system for the maintenance of best measurement capability and the promotion of utilization of HANARO research reactor 2) Improvement of analytical sensitivity for industrial applied technologies and establishment of certified standard procedures 3) Standardization and development of Prompt Gamma-ray Activation Analysis (PGAA) technology.

  11. Applied research and development of neutron activation analysis

    International Nuclear Information System (INIS)

    The aims of this project are to establish the quality control system of Neutron Activation Analysis(NAA) due to increase of industrial needs for standard analytical method and to prepare and identify the standard operation procedure of NAA through practical testing for different analytical items. R and D implementations of analytical quality system using neutron irradiation facility and gamma-ray measurement system and automation of NAA facility in HANARO research reactor are as following ; 1) Establishment of NAA quality control system for the maintenance of best measurement capability and the promotion of utilization of HANARO research reactor 2) Improvement of analytical sensitivity for industrial applied technologies and establishment of certified standard procedures 3) Standardization and development of Prompt Gamma-ray Activation Analysis (PGAA) technology

  12. Practical aspects of operating a neutron activation analysis laboratory

    International Nuclear Information System (INIS)

    This book is intended to advise in everyday practical problems related to operating a neutron activation analysis (NAA) laboratory. It gives answers to questions like ''what to use NAA for'', ''how to find relevant research problems'', ''how to find users for the technique'', ''how to estimate the cost of the analysis and how to finance the work'', ''how to organize the work in a rational way'' and ''how to perform the quality control''. It gives advice in choosing staff, equipment, and consumables and how to design facilities and procedures according to need and available resources. Potential applications of economic or environmental importance, reactor facilities, counting and measuring equipment of the lab, cooperation with other analytical groups and competitiveness of NAA are discussed by experienced analysts. The compiled 8 tables of data useful for neutron activation analysts are a valuable asset for research labs as well as industrial quality control units. Refs, figs and tabs

  13. Nondestructive neutron activation analysis of volcanic samples: Hawaii

    International Nuclear Information System (INIS)

    Samples of volcanic emissions have been collected between and during eruptions of both Kilauea and Mauna Loa volcanoes during the last three years. Airborne particles have been collected on Teflon filters and acidic gases on base-impregnated cellulose filters. Chemically neutral gas-phase species are collected on charcoal-coated cellulose filters. The primary analytical technique used is nondestructive neutron activation analysis, which has been used to determine the quantities of up to 35 elements on the different filters. The use of neutron activation analysis makes it possible to analyze for a wide range of elements in the different matrices used for the collection and to learn about the distribution between particles and gas phases for each of the elements

  14. Analysis of medicinal plant extracts by neutron activation method

    International Nuclear Information System (INIS)

    This dissertation has presented the results from analysis of medicinal plant extracts using neutron activation method. Instrumental neutron activation analysis was applied to the determination of the elements Al, Br, Ca, Ce, Cl, Cr, Cs, Fe, K, La, Mg, Mn, Na, Rb, Sb, Sc and Zn in medicinal extracts obtained from Achyrolcline satureoides DC, Casearia sylvestris, Centella asiatica, Citrus aurantium L., Solano lycocarpum, Solidago microglossa, Stryphnondedron barbatiman and Zingiber officinale R. plants. The elements Hg and Se were determined using radiochemical separation by means of retention of Se in HMD inorganic exchanger and solvent extraction of Hg by bismuth diethyl-dithiocarbamate solution. Precision and accuracy of the results have been evaluated by analysing reference materials. The therapeutic action of some elements found in plant extracts analyzed was briefly discussed

  15. Non-destructive plant-nutrition analysis by neutron analysis by neutron activation and X-ray fluorescence techniques

    International Nuclear Information System (INIS)

    Non-destructive neutron activation and x-ray fluorescence techniques have been applied to the analysis of plant nutrients in soil. The advantages of these methods over the conventional ones have also been focussed. (author)

  16. Analysis of Some Egyptian Cosmetic Samples by Fast Neutron Activation Analysis

    CERN Document Server

    Medhat, M E; Fayez-Hassan, M

    2001-01-01

    A description of D-T neutron generator (NG) is presented. This generator can be used for fast neutron activation analysis applied to determine some selected elements, especially light elements, in different materials. In our work, the concentration of the elements Na, Mg, Al, Si, K, Cl, Ca and Fe, were determined in two domestic brands of face powder by using 14 MeV neutron activation analysis.

  17. Multielement determination in soil extracts by instrumental neutron activation analysis

    International Nuclear Information System (INIS)

    Forest Swiss soils from 39 locations, each sampled at three depths, were extracted with a buffered solution of pH 4.65 containing EDTA. Nearly 30 elements were determined by instrumental neutron activation analysis. The results obtained are discussed in terms of efficiency of the extractant, precision and accuracy. Summarized results are presented for the quantity fractions of the extracted elements. (author) 18 refs.; 4 figs.; 3 tabs

  18. Gold determination in massive samples by neutron activation analysis

    CERN Document Server

    Broglio, Eduardo

    2015-01-01

    This work presents the characteristics of the Neutron Activation Analysis (NAA) in the determination of gold in voluminous mineral samples using a linear particle accelerator (Linac) as source of irradiation. The used volumes are one or two orders of magnitude higher than the ones that can be used in nuclear research reactor, which is the source usually used to determine through the NAA. This study was encouraged by a specific legal requirement to determine the gold law in a small Patagonian gold deposit.

  19. Neutron activation analysis of copper, zinc and manganese in plants

    International Nuclear Information System (INIS)

    A fast method for simultaneous quantitative determination of microscopic quantities of copper, zinc and manganese in plant tissue through neutron activation analysis is suggested. The measurements are carried out after removal of the 24Na and 42K interference. Optimum conditions for detention of the microscopic quantities of Cu, Zn and Mn by the chelating resin Chelex-100 using the batch procedure are determined. (author)

  20. Neutron activation analysis of cheese, eggs, fish, fowl and meats

    International Nuclear Information System (INIS)

    The concentrations of Br, Ca, Cl, Cu, I, K, Mg, Na, Rb, S and Ti in 44 samples of cheese, eggs, fish, fowl and meats sold in Canada were determined with absolute instrumental neutron activation analysis. The procedure is fully computerized and incorporates one short irradiation and counting only. When an element was not detected, its detection limit was calculated. The nuclear interferences and blanks were taken into account. The nutritional significance of the results is discussed. (author)

  1. Some Applications of Fast Neutron Activation Analysis of Oxygen

    International Nuclear Information System (INIS)

    illustrated how the activated water would propagate along that pipe. C) Combustion products. In order to investigate the oxidation in combustion products (deposits), the total amount of oxygen in the deposits collected from combustion chambers of a modern gasoline engine was measured, using cyclic fast neutron activation analysis (FNAA). As a compartment, the organic compounds containing oxygen were identified using 13C solid-state nuclear magnetic resonance (NMR) spectroscopy. The results of FNAA showed that the amount of oxygen in deposits varies depending on where the deposits have been formed. 13C NMR has showed that the carbon backbone of the deposits exists as highly oxidized poly aromatics and/or graphitic structure. D) On-line fast neutron activation analysis. On-line neutron activation analysis was used to detect the amount of oxygen in bulk liquids. The method was optimised for on-line detection of oxygen in rapeseed oil. The goal was to develop a non-intrusive method for measurement of the total amount of oxygen in oil during combustion/oxidation

  2. Some Applications of Fast Neutron Activation Analysis of Oxygen

    Energy Technology Data Exchange (ETDEWEB)

    Owrang, Farshid

    2003-07-01

    illustrated how the activated water would propagate along that pipe. C) Combustion products. In order to investigate the oxidation in combustion products (deposits), the total amount of oxygen in the deposits collected from combustion chambers of a modern gasoline engine was measured, using cyclic fast neutron activation analysis (FNAA). As a compartment, the organic compounds containing oxygen were identified using {sup 13}C solid-state nuclear magnetic resonance (NMR) spectroscopy. The results of FNAA showed that the amount of oxygen in deposits varies depending on where the deposits have been formed. {sup 13}C NMR has showed that the carbon backbone of the deposits exists as highly oxidized poly aromatics and/or graphitic structure. D) On-line fast neutron activation analysis. On-line neutron activation analysis was used to detect the amount of oxygen in bulk liquids. The method was optimised for on-line detection of oxygen in rapeseed oil. The goal was to develop a non-intrusive method for measurement of the total amount of oxygen in oil during combustion/oxidation.

  3. Aerosol and air pollution study by neutron activation analysis

    International Nuclear Information System (INIS)

    Thermal neutron activation analysis technique was used in air pollution and aerosol elemental content and size distribution investigations. Air pollution samples were collected on Whatman 41 paper filters which were activated along with known quantities of standards in a flux of approximately 1013 nxcm-2xs-1. The activity of the samples was measured with a 40 cm3 Ge(Li) detector and analyzed with the computer program JANE, which identified the isotopes and found their quantities by normalization with the standard measurement results. Correlation between the various elements, in particular those belonging to dust from the desert and those considered typical urban air pollution, is investigated. (author)

  4. Provenience studies using neutron activation analysis: the role of standardization

    International Nuclear Information System (INIS)

    This paper covers the historical background of chemical analysis of archaeological artifacts which dates back to 1790 to the first application of neutron activation analysis to archaeological ceramics and goes on to elaborate on the present day status of neutron activation analysis in provenience studies, and the role of standardization. In principle, the concentrations of elements in a neutron-activated specimen can be calculated from an exact knowledge of neutron flux, its intensity, duration and spectral (energy) distribution, plus an exact gamma ray count calibrated for efficiency, corrected for branching rates, etc. However, in practice it is far easier to compare one's unknown to a standard of known or assumed composition. The practice has been for different laboratories to use different standards. With analyses being run in the thousands throughout the world, a great benefit would be derived if analyses could be exchanged among all users and/or generators of data. The emphasis of this paper is on interlaboratory comparability of ceramic data; how far are we from it, what has been proposed in the past to achieve this goal, and what is being proposed. All of this may be summarized under the general heading of Analytical Quality Control - i.e., how to achieve precise and accurate analysis. The author proposes that anyone wishing to analyze archaeological ceramics should simply use his own standard, but attempt to calibrate that standard as nearly as possible to absolute (i.e., accurate) concentration values. The relationship of Analytical Quality Control to provenience location is also examined

  5. Neutron activation analysis of ivory of African elephants

    International Nuclear Information System (INIS)

    Instrumental neutron activation analysis was applied to 61 ivory samples of which origin countries are known. 12 elements such as Br, Ca, Cl, Co, Cs, Fe, Mg, Mn, Na, Sc, Sr and Zn, were determined in all samples. The factor score of each sample was calculated for each factor by making use of principal component analysis in order to determine their origins. The results were compared with those by stable isotope analysis (13C and 15N). (author). 4 refs., 5 figs. 4 tabs

  6. Analysis by Neutron activation of the Calakmul jadeite mask

    International Nuclear Information System (INIS)

    It is very important to know the elemental composition of archaeological materials with the purpose to find relations that allow to establish their origin standards. the origin and present localization of pre hispanic archaeological pieces can lead to the determination of commercial routes and of technology transfer among different ancient cultures. In the present work it has been realized a systematic analysis using the Instrumental neutron activation analysis technique of three samples obtained from Calakmul jadeite mask, tomb I, that in addition to give a composition of constituent and trace elements detected by this technique it has leaded to establish an applicable methodology to the routine analysis of ceramics of historical interest. (Author)

  7. Neutron activation analysis applied to nutritional and foodstuff studies

    International Nuclear Information System (INIS)

    Neutron Activation Analysis, NAA, has been successfully used on a regularly basis in several areas of nutrition and foodstuffs. NAA has become an important and useful research tool due to the methodology's advantages. These include high accuracy, small quantities of samples and no chemical treatment. This technique allows the determination of important elements directly related to human health. NAA also provides data concerning essential and toxic concentrations in foodstuffs and specific diets. In this paper some studies in the area of nutrition which have been carried out at the Neutron Activation Laboratory of IPEN/CNEN-SP will be presented: a Brazilian total diet study: nutritional element dietary intakes of Sao Paulo state population; a study of trace element in maternal milk and the determination of essential trace elements in some edible mushrooms. (author)

  8. Neutron activation analysis of traces of metallic elements in water

    International Nuclear Information System (INIS)

    The application of neutron activation analysis is examined for the elements iron, nickel, chromium and cobalt which are constituents of the aqueous corrosion products of stainless steels and which are present in very low concentrations in the water used in the heat transfer systems of nuclear reactors. The best results were obtained by slow evaporation of the water sample in a quartz ampoule in an oven followed by irradiation of the dry sample in the same ampoule. The problems of blanks, of losses during concentration, and of conservation of solutions at very low concentrations were studied. Good agreement was found between the theoretical quantities and experimental results with standard samples containing 50ppb of each of the studied elements. There was also excellent agreement between neutron activation and spectrophotometric methods in the case of determinations of iron in solution

  9. Determination of sodium in pharmaceuticals by neutron activation analysis

    International Nuclear Information System (INIS)

    A simple, fast and accurate neutron activation analysis method for determination of Na in drugs concerning either active compound or total content was developed. The examined dosage forms consisted of 10 injectable ampoules and 10 bottles of oral solutions. The irradiation of samples and standards was carried out in the rotation system of the Reactor of Nuclear Research Center Democritos with maximal neutron flux of 2,9.1013 n.cm-2.sec-1. Gamma-ray spectrometry of the irradiated samples and standards was accomplished with a coaxial Ge(Li) detector series Win 15 with an efficiency of 15% connected to an Ino-Tech 1024 channel analyser (Model IT 5200). The accuracy and precision of the method are found to be very high and therefore it could be established as an official one for the determination of sodium in parmaceuticals

  10. Nondestructive multielementary analysis of human hair by neutron activation

    International Nuclear Information System (INIS)

    Various elements contained in human hair have been used for an index of environmental pollution effect of human body. Nondestructive neutron activation analysis was applied to hair samples on 61 inhabitants of a local district which was free from air pollution. At Rikkyo University hair samples were irradiated for 3 minutes or 15 hours (5 hours/day, 3 days) in a TRIGA Mark II Reactor with a neutron flux of 1.5x1012 n/cm2/sec. The activities were measured by a Ge(Li) detector. 18 elements could be determined: Al, Br, Ca, Cl, Cu, I, Mg, Mn, Na, S and V with the 3 minute irradiation method, and As, Au, Cr, K, La, Sb and Zn with the 15 hour irradiation method. Concentration-distribution histograms, and differences in distribution patterns of these elements caused by permanent wave treatment, sex or age were discussed. (auth.)

  11. Analysis of Protein in Soybean by Neutron Activation Technique

    International Nuclear Information System (INIS)

    Nitrogen content in soybean was studied by using Neutron Activation Analysis technique through fast neutron at the flux of 2.5 * 1011 n/cm2. sec in the CA-3 out-core irradiation tube of the Thai Research Reactor-1/Modification 1 (TRR-1/M1, Triga Mark 3 type). By measuring gamma ray of 511 keV from 13N of the nuclear reaction, 14N(n, 2n)13N caused by the annihilation of positron disintegrated, the semi-conductor detector (HPGe) was connected with the multi-channel analyzer (MCA) and monitor to display the spectrum range. NH4NO3 was used as the standard for the analysis. The inaccuracy of the analysis caused by other radioisotopes, i.e. potassium, phosphorus and reaction from recoiled proton scattering in soybean was corrected. The data of 27 samples analyzed by neutron activation showed no significant difference in the nitrogen content. The average nitrogen content of all the soybean samples is 7.02% equivalent to protein content of 43.88%

  12. Determination of copper in some Myanmar indigenous medicines by neutron activation analysis

    International Nuclear Information System (INIS)

    Copper was determined in two Myanmar indigenous medicines by neutron activation analysis using an Am(Be) radionuclide neutron source. The activity of 511 keV peak of the 64Cu was measured. (author) 2 refs.; 2 tabs

  13. Prompt Gamma-Ray Neutron Activation Analysis (PGNAA) for Elemental Analysis

    Energy Technology Data Exchange (ETDEWEB)

    Robin P. Gardner

    2006-04-11

    This research project was to improve the prompt gamma-ray neutron activation analysis (PGNAA) measurement approach for bulk analysis, oil well logging, and small sample thermal enutron bean applications.

  14. Characterization of the volcanic eruption emissions using neutron activation analysis

    International Nuclear Information System (INIS)

    Characterization of the volcanic particulate material has been performed by analyzing aerosols and ashes with instrumental neutron activation analysis. Crustal enrichment factors were calculated using the elemental concentration and clustering techniques, and multivariate analysis were done. The analytical and data treatment methodologies allowed the sample differentiation from their geographical origin viewpoint, based on their chemical composition patterns, which are related to the deposit formation processes, which consist of direct deposition from the volcanic cloud, and removal by wind action after the end of the eruption, and and finally the deposition. (author). 8 refs., 5 figs

  15. Neutron activation analysis of ivory of African elephants

    International Nuclear Information System (INIS)

    Instrumental neutron activation analysis was applied to 80 samples from various African countries and 81 samples from the Kruger National Park in the Republic of South Africa. Twelve elements such as Br, Ca, Cl, Co, Cs, Fe, Mg, Mn, Na, Sc, Sr, and Zn, were determined in all samples. The factor scores of each sample were calculated from those elemental concentrations for the first and second factors to clarify the differences of samples from various African countries with those from Kruger Park. The results were compared with those by stable isotope analysis (13C and 15N). (author)

  16. Mercury determination in natural waters using neutron activation analysis

    International Nuclear Information System (INIS)

    Available as short communication only. An analytical method for quantitative determination of Mercury traces in river and sea water is proposed. The neutron activation method and radiochemical separation of Mercury by developing of C L4 Hg-2 complex, and their chromatographic separation using anionic exchange resin Dowex 1 X 8 of 400 mesh is used. The quantitative determination is done by gamma spectrometric analysis. The selection limits reached with this method showed that this is an amenable procedure in routine mercury determination in the ppb level, specially useful in the environmental contamination analysis. (author). 3 refs, 2 figs, 1 tab

  17. Teaching chemistry with neutron activation analysis at Dalhousie University

    International Nuclear Information System (INIS)

    The Dalhousie University SLOWPOKE-2 Reactor (DUSR) has been operating since July 1976 and has proven to be an invaluable tool in many teaching programs. These reactors are inherently safe and are designed to serve teaching and research needs of the universities, research centers, hospitals, etc. Since the DUSR has been, from its inception, associated with the Trace Analysis Research Centre, which is the Analytical Chemistry Division of the Department of Chemistry, the main thrust of its use continues to be in the field of nuclear analytical chemistry. Both teaching and research programs involve trace element analysis by neutron activation

  18. Speciation neutron activation analysis for arsenic in marine fish

    International Nuclear Information System (INIS)

    Neutron activation analysis (NAA) methods involving chemical separations prior to irradiations can be developed to determine the species of an element. The technique can be called speciation NAA (SNAA). We have developed SNAA methods for assaying various arsenic species, namely As(III), As(V), dimethyl arsonic acid (DMA), monomethylarsinic acid (MMA), arsenobetaine (AsB), organically bound arsenic (OBAs), and lipid-soluble arsenic (LSAs) in marine fish samples. The method involves extraction by a methanol-MIBK-water system, cation exchange chromatography, and HPLC followed by NAA. The detection limits for various arsenic species are around 20 ng g-1 of fish under the experimental conditions of 2-h irradiation in a neutron flux of 5x1011 cm-2 s-1 at the Dalhousie University SLOWPOKE-2 facility. Details of the methods and results are presented

  19. The Application of Neutron Activation Analysis in Thailand

    International Nuclear Information System (INIS)

    The technique of neutron activation analysis was introduced at the OAEP about 5 years ago. Since that time, it has become a useful technique for the determination. in particular, of certain trace inorganic elements in biological samples in this country. Scientists here have been working in close co-operation with those in other Government laboratories to meet the requirements of their studies. At present, a high resolution solid state gamma-ray detector is lacking in our laboratory. The results of the work to be described briefly were thus mainly carried out utilising our research reactor as the neutron source and multi-channel analysers together with the technique of radiochemical separation. In some cases, the non-destructive method was found feasible

  20. Neutron activation analysis of gold in teak (tectona grandis)

    International Nuclear Information System (INIS)

    The amount of gold in teak had been determined by using neutron activation technique. The neutron flux utilized was of the order of 1010n/cm2/sec. As usual the spectrum of the energy peak of gold was identified using a gamma-multichannel pulse height analyzer. The sensitivity for gold was approximately 10-7g. In teak especially Na, As, Cu, Mn and La were interfering elements in the energy region of 0.4-0.8 MeV. With the result, the non-destructive analysis only was not possible and radiochemical separation was found essential. The gold content of teak was 0.58+0.0037 ppm

  1. Activation analysis using cyclotron-produced fast neutrons

    International Nuclear Information System (INIS)

    The possibilities of activation analysis by using cyclotron-produced fast neutrons are investigated for more than 30 chemical elements. The angular distributions of fast neutrons produced by bombarding a thick beryllium target with 11.5 MeV protons, 3 and 6 MeV deuterons were obtained for five angles in the forward hemisphere. The yield's of the radionuclides produced by nuclear reactions (n,p), (n,α), (n,γ), (n,n,γ) were measured or calculated. It is showed that the yields of the majority of radionuclides are within 103-105 Bk.(μA.h.g)1. These data were used for the evaluation of the limit detection of chemical elements. The values of the LD are equal to 0.1-1 μg for some elements, whereas for majority elements they are l-100 μg

  2. Prompt gamma activation analysis using mobile reactor neutron beam

    International Nuclear Information System (INIS)

    Among the nuclear analytical methods that have proved very useful in biological and medical analyses is the in vivo prompt gamma neutron activation analysis (IVPGAA). In this work, an IVPGAA facility was assembled on a zero-power mobile nuclear reactor and has demonstrated its versatility for in vivo medical diagnosis. Absolute measurements of some environmental contaminants such as Cd, Hg, and Si in organs can be determined rapidly by partial body scan of IVPGAA, while assessment of vital constituents such as Ca, Cl, N, and P in either whole body or body part can be scanned by IVPGAA technique effectively. The in vivo clinical application using mobile reactor neutron beam are reviewed in detail. The IVPGAA scan provides unique insight into elemental concentration purpose. The IVPGAA scan can be performed on a regular basis without discomfort and radiation risk for patients. (author)

  3. Partial neutron capture cross sections of actinides using cold neutron prompt gamma activation analysis

    International Nuclear Information System (INIS)

    Nuclear waste needs to be characterized for its safe handling and storage. In particular long-lived actinides render the waste characterization challenging. The results described in this thesis demonstrate that Prompt Gamma Neutron Activation Analysis (PGAA) with cold neutrons is a reliable tool for the non-destructive analysis of actinides. Nuclear data required for an accurate identification and quantification of actinides was acquired. Therefore, a sample design suitable for accurate and precise measurements of prompt γ-ray energies and partial cross sections of long-lived actinides at existing PGAA facilities was presented. Using the developed sample design the fundamental prompt γ-ray data on 237Np, 241Am and 242Pu were measured. The data were validated by repetitive analysis of different samples at two individual irradiation and counting facilities - the BRR in Budapest and the FRM II in Garching near Munich. Employing cold neutrons, resonance neutron capture by low energetic resonances was avoided during the experiments. This is an improvement over older neutron activation based works at thermal reactor neutron energies. 152 prompt γ-rays of 237Np were identified, as well as 19 of 241Am, and 127 prompt γ-rays of 242Pu. In all cases, both high and lower energetic prompt γ-rays were identified. The most intense line of 237Np was observed at an energy of Eγ=182.82(10) keV associated with a partial capture cross section of σγ=22.06(39) b. The most intense prompt γ-ray lines of 241Am and of 242Pu were observed at Eγ=154.72(7) keV with σγ=72.80(252) b and Eγ=287.69(8) keV with σγ=7.07(12) b, respectively. The measurements described in this thesis provide the first reported quantifications on partial radiative capture cross sections for 237Np, 241Am and 242Pu measured simultaneously over the large energy range from 45 keV to 12 MeV. Detailed uncertainty assessments were performed and the validity of the given uncertainties was demonstrated. Compared

  4. The comparison of four neutron sources for Prompt Gamma Neutron Activation Analysis (PGNAA) in vivo detections of boron

    OpenAIRE

    Fantidis, J. G.; Nicolaou, G. E.; C. Potolias; N. Vordos; Bandekas, D. V.

    2011-01-01

    A Prompt Gamma Ray Neutron Activation Analysis (PGNAA) system, incorporating an isotopic neutron source has been simulated using the MCNPX Monte Carlo code. In order to improve the signal to noise ratio different collimators and a filter were placed between the neutron source and the object. The effect of the positioning of the neutron beam and the detector relative to the object has been studied. In this work the optimisation procedure is demonstrated for boron. Monte Carlo calculations were...

  5. Chemical weapons detection by fast neutron activation analysis techniques

    International Nuclear Information System (INIS)

    A neutron diagnostic experimental apparatus has been tested for nondestructive verification of sealed munitions. Designed to potentially satisfy a significant number of van-mobile requirements, this equipment is based on an easy to use industrial sealed tube neutron generator that interrogates the munitions of interest with 14 MeV neutrons. Gamma ray spectra are detected with a high purity germanium detector, especially shielded from neutrons and gamma ray background. A mobile shell holder has been used. Possible configurations allow the detection, in continuous or in pulsed modes, of gamma rays from neutron inelastic scattering, from thermal neutron capture, and from fast or thermal neutron activation. Tests on full scale sealed munitions with chemical simulants show that those with chlorine (old generation materials) are detectable in a few minutes, and those including phosphorus (new generation materials) in nearly the same time. (orig.)

  6. Mercury mass measurement in fluorescent lamps via neutron activation analysis

    Science.gov (United States)

    Viererbl, L.; Vinš, M.; Lahodová, Z.; Fuksa, A.; Kučera, J.; Koleška, M.; Voljanskij, A.

    2015-11-01

    Mercury is an essential component of fluorescent lamps. Not all fluorescent lamps are recycled, resulting in contamination of the environment with toxic mercury, making measurement of the mercury mass used in fluorescent lamps important. Mercury mass measurement of lamps via instrumental neutron activation analysis (NAA) was tested under various conditions in the LVR-15 research reactor. Fluorescent lamps were irradiated in different positions in vertical irradiation channels and a horizontal channel in neutron fields with total fluence rates from 3×108 cm-2 s-1 to 1014 cm-2 s-1. The 202Hg(n,γ)203Hg nuclear reaction was used for mercury mass evaluation. Activities of 203Hg and others induced radionuclides were measured via gamma spectrometry with an HPGe detector at various times after irradiation. Standards containing an Hg2Cl2 compound were used to determine mercury mass. Problems arise from the presence of elements with a large effective cross section in luminescent material (europium, antimony and gadolinium) and glass (boron). The paper describes optimization of the NAA procedure in the LVR-15 research reactor with particular attention to influence of neutron self-absorption in fluorescent lamps.

  7. Coincidence Prompt Gamma-Ray Neutron Activation Analysis

    Energy Technology Data Exchange (ETDEWEB)

    R.P. gandner; C.W. Mayo; W.A. Metwally; W. Zhang; W. Guo; A. Shehata

    2002-11-10

    The normal prompt gamma-ray neutron activation analysis for either bulk or small beam samples inherently has a small signal-to-noise (S/N) ratio due primarily to the neutron source being present while the sample signal is being obtained. Coincidence counting offers the possibility of greatly reducing or eliminating the noise generated by the neutron source. The present report presents our results to date on implementing the coincidence counting PGNAA approach. We conclude that coincidence PGNAA yields: (1) a larger signal-to-noise (S/N) ratio, (2) more information (and therefore better accuracy) from essentially the same experiment when sophisticated coincidence electronics are used that can yield singles and coincidences simultaneously, and (3) a reduced (one or two orders of magnitude) signal from essentially the same experiment. In future work we will concentrate on: (1) modifying the existing CEARPGS Monte Carlo code to incorporate coincidence counting, (2) obtaining coincidence schemes for 18 or 20 of the common elements in coal and cement, and (3) optimizing the design of a PGNAA coincidence system for the bulk analysis of coal.

  8. Neutron activation analysis in teaching analytical chemistry at UCI

    International Nuclear Information System (INIS)

    The undergraduate curriculum in chemistry at the University of California at Irvine has included practice with experiments in radiochemistry and activation analysis since 1968, 3 years after the campus was founded. In 1969, a TRIGA nuclear reactor was installed that operates at 250 kW steady state or can pulse to ∼10 MW of peak power. This has been the main activation source, although experiments have also been carried out by students using a 14-MeV neutron generator (Kaman Sciences, Model 711) and a small (1-μCi) 252Cf source on loan from the US Department of Energy. The majority of the experience has been within a junior/senior-level elective course in radioisotope techniques. However, experiments were also introduced by this author into the required instrumental analysis course. A very worthwhile experience was gained when students were assigned an unknown material (sometimes an inexpensive standard reference material) and asked to determine the concentration of a single trace element by two or three different techniques (atomic absorption, polarography, or derivative spectrophotometry) in addition to instrumental neutron activation analysis (INAA)

  9. Limits of detection in instrumental neutron activation analysis

    International Nuclear Information System (INIS)

    Lower limits of detection (LLODs), frequently referred to simply as limits of detection and abbreviated as LODs, often appear in the literature of analytical chemistry - for numerous different methods of elemental and/or molecular analysis. In this chapter, one particular method of quantitative elemental analysis, that of instrumental neutron activation analysis (INAA), is the subject discussed, with reference to LODs. Particularly in the literature of neutron activation analysis (NAA), many tables of 'interference-free' NAA LODs are available. Not all of these are of much use, because (1) for many the definition used for LOD is not clear, or reasonable, (2) for many, the analysis conditions used are not clearly specified, and (3) for many, the analysis conditions used are specified, but not very practicable for most laboratories. For NAA work, such tables of interference-free LODs are, in any case, only applicable to samples in which, at the time of counting, only one radionuclide is present to any significant extent in the activated sample. It is important to note that tables of INAA LODs, per se, do not exist - since the LOD for a given element, under stated analysis conditions, can vary by orders of magnitude, depending on the elemental composition of the matrix in which it is present. For any given element, its INAA LOD will always be as large as, and usually much larger than, its tabulated 'interference-free' NAA LOD - how much larger depending upon the elemental composition of the matrix in which it is present. As discussed in this chapter, however, an INAA computer program exists that can calculate realistic INAA LODs for any elements of interest, in any kind of specified sample matrix, under any given set of analysis conditions

  10. Extraction of polychromatic thermal neutrons by Bragg diffraction to use for prompt gamma neutron activation analysis

    International Nuclear Information System (INIS)

    Extraction method of thermal neutron beam by Bragg diffraction is investigated. A thermal neutron beam is used for the Prompt Gamma Neutron Activation Analysis system at HANARO, a 30 MW research reactor in the Korea Atomic Energy Research Institute. Polychromatic beam including all orders of diffraction is obtained by setting a pair of pyrolytic graphite crystals with a Bragg angle of 45 deg. on a horizontal white beam line. Diffracted neutron flux at the sample position is calculated by considering the integrated reflectivity and mosaic spread of crystals. Due to the divergence effect, the mosaic spread of crystals is optimized to give the maximum and flat flux at the sample position. An experiment has been performed to verify the reflectivities for high order diffractions from pyrolytic graphite. When the focusing technique of bending the crystals is adopted, a design value of 1.0x108 n/cm2s is expected at the sample position. Hence Bragg diffraction is a promising method of extracting thermal neutrons for PGNAA

  11. Extraction of polychromatic thermal neutrons by Bragg diffraction to use for prompt gamma neutron activation analysis

    Science.gov (United States)

    Byun, S. H.; Choi, H. D.; Jun, B. J.; Kim, M. S.

    2000-07-01

    Extraction method of thermal neutron beam by Bragg diffraction is investigated. A thermal neutron beam is used for the Prompt Gamma Neutron Activation Analysis system at HANARO, a 30 MW research reactor in the Korea Atomic Energy Research Institute. Polychromatic beam including all orders of diffraction is obtained by setting a pair of pyrolytic graphite crystals with a Bragg angle of 45° on a horizontal white beam line. Diffracted neutron flux at the sample position is calculated by considering the integrated reflectivity and mosaic spread of crystals. Due to the divergence effect, the mosaic spread of crystals is optimized to give the maximum and flat flux at the sample position. An experiment has been performed to verify the reflectivities for high order diffractions from pyrolytic graphite. When the focusing technique of bending the crystals is adopted, a design value of 1.0×108n/cm2s is expected at the sample position. Hence Bragg diffraction is a promising method of extracting thermal neutrons for PGNAA.

  12. Neutron Activation Analysis of Pre-Columbian Pottery in Venezuela

    International Nuclear Information System (INIS)

    Pre-Hispanic pottery figurines from north-central Venezuela islands and mainland were analysed by neutron activation analysis (INAA and PGAA) at the Budapest Research to establish their provenience. In order to classify the samples of figurines, characteristic molecular and atomic components were determined. Several mass ratios were calculated for significant classification of the object of two origins. Results shed light on the origin of island figurines and suggest specific areas of their production on the mainland, contributing to better understanding of late pre-Hispanic migration patterns in the southeastern Caribbean region

  13. Control of pneumatic transfer system for neutron activation analysis

    International Nuclear Information System (INIS)

    Pneumatic transfer system(PTS) is one of the facilities to be used in irradiation of target materials for neutron activation analysis(NAA) in the research reactor. There are two systems the manual and the automatic system in PTS of HANARO research reactor. The pneumatic transfer system consists of many devices, sends and loads the capsules from NAA laboratory into three holes in the reflector tank of reactor and retrieves irradiated capsules after irradiation. This report describes the part's design, control system and the operation procedures. All the algorithm described in the text will be used for maintenance and upgrading

  14. Control of pneumatic transfer system for neutron activation analysis

    Energy Technology Data Exchange (ETDEWEB)

    Jung, H. S.; Chung, Y. S.; Wu, J. S.; Kim, H. K.; Choi, Y. S.; Kim, S. H.; Moon, J. H.; Baek, S. Y

    2000-06-01

    Pneumatic transfer system(PTS) is one of the facilities to be used in irradiation of target materials for neutron activation analysis(NAA) in the research reactor. There are two systems the manual and the automatic system in PTS of HANARO research reactor. The pneumatic transfer system consists of many devices, sends and loads the capsules from NAA laboratory into three holes in the reflector tank of reactor and retrieves irradiated capsules after irradiation. This report describes the part's design, control system and the operation procedures. All the algorithm described in the text will be used for maintenance and upgrading.

  15. Multielement analysis of iliac crest bone by neutron activation

    International Nuclear Information System (INIS)

    Bone samples from iliac crest were obtained from apparently healthy female (n = 4) and male (n = 8) subjects with ages between 15-50. Cortical and trabecular parts were separated and soft tissues like fat, muscle and blood were removed. Calcium, Mg, Na, Cl, Fe, Zn, Br, Sr, and Cs were determined by instrumental neutron activation analysis and other techniques, and their relations were discussed. Fairly good agreement was obtained with literature data. These values may serve as reference values for subjects from a Turkish population. (author)

  16. Determination of mercury in dentists through Neutron activation analysis

    International Nuclear Information System (INIS)

    It was determined the mercury levels in urine through Neutron activation analysis to 25 dentists who have been exposed to mercury by several time periods, because of the routine manipulations of amalgams. The determined concentrations of mercury were less to 10 μ g Hg/l of urine. The results were founded inside the safety limits reported in the literature. The mercury levels in the dentists are associated with a wide variety of factors that contribute to their exposure as: number of years of dental practice, number of amalgams manipulated between others. (Author)

  17. Calibration of HPGe detector for flowing sample neutron activation analysis

    International Nuclear Information System (INIS)

    This work is concerned with the calibration of the HPGe detector used in flowing sample neutron activation analysis technique. The optimum counting configuration and half-life based correction factors have been estimated using Monte Carlo computer simulations. Depending on detection efficiency, sample volume and flow type around the detector, the optimum geometry was achieved using 4 mm diameter hose rolled in spiral shape around the detector. The derived results showed that the half-life based efficiency correction factors are strongly dependent on sample flow rate and the isotope half-life. (author)

  18. Neutron activation analysis of hair from breast cancer patients

    International Nuclear Information System (INIS)

    Hair samples from breast cancer patients were collected at the same time as tumour and normal tissues obtained during mastectomy, in order to determine elemental concentrations and investigate whether hair can act as an epidemiological monitor of the disease. Instrumental neutron activation analysis was used and concentrations for Na, Mg, S, Cl, Ca, Mn, Cu, Zn, Br, I, Sb, Ba, Au and Hg in the hair samples measured. No strong correlations were found between the concentrations of Cl, Cu, Zn and Br in hair and those in tumour tissues and in normal tissues. The level of Zn in the patients hair is low and that of Ca very high

  19. Elemental characterization of Brazilian beans using neutron activation analysis

    International Nuclear Information System (INIS)

    Beans are important for many developing countries as a source of protein and mineral nutrients. Here, ten commercial types of Brazilian beans, from the species Phaseolus vulgaris (common beans) and Vigna unguiculata (cowpeas), were analyzed by neutron activation analysis for the determination of Br, Ca, Co, Cs, Fe, K, Mo, Na, Rb, Sc and Zn. There were statistical differences (p/0.05) amongst the commercial types, except for Br, Rb and Sc. In general, non-essential elements showed high variability, indicating that the origin of beans had a strong influence on the mass fraction of such elements. (author)

  20. Multielemental analysis of metallurgical samples by thermal neutron activation

    International Nuclear Information System (INIS)

    Instrumental neutron activation analysis (INAA) was applied to investigate a total of 16 samples of raw materials, intermediate and final products involved in metallurgical processes in Romanian Iron and Steel Works Sidex Galatzy; iron ores and pellets from different regions of the world cast iron, slag and steels. A series of chemical elements was determined in the analyzed samples: Al, As, Ce, Co, Cr, Fe, La, Mn, Na, Sc, Sm, V, W. A qualitative discussion regarding the passing of some elements with different chemical affinity for oxygen compared to that of iron, from the raw materials to slag or to finite products is presented. (author). 11 refs., 2 tabs

  1. Neutron activation analysis for investigation of chosen food products

    International Nuclear Information System (INIS)

    In this work neutron activation analysis is applied for investigation of the elemental composition of Amaranths seeds. The characterization by multi-elemental instrumental NAA is enriched by the results of radiochemical NAA for cobalt, molybdenum and uranium content. The comparison of the results, for three sorts of edible flour, commercially available: soya Flour, Corn Bean Flour and Amaranths Flour, is presented. The validation of the analytical methods used was carried out on the basis of participation in the interlaboratory comparison organised by INCT and NIST. (author)

  2. Prompt gamma neutron activation analysis as an active interrogation technique for nuclear materials

    International Nuclear Information System (INIS)

    Prompt gamma neutron activation analysis (PGAA) is proposed as an instant, non-destructive method for the analysis of fissile materials and fission products. Measurements by PGAA were made on technetium and uranium compounds, the latter with various enrichments. Measurements were carried out in thermal and cold neutron beams at the Budapest Research Reactor. A beam chopper was used to collect the delayed decay gamma radiation from short lived nuclides separately. Accurate partial gamma ray production cross-sections were determined with internal standardization for a set of prompt and decay gamma rays following neutron capture in 235U, 238U and 99Tc and compared to those from the literature. In the case of 235U fission, prompt gamma lines were also applied.These cross-sections can be used for non-destructive analyses of uranium and technetium and also for the determination of the enrichment of uranium by prompt gamma activation analysis and neutron activation analysis. (author)

  3. Recent developments in environmental research using neutron activation analysis

    International Nuclear Information System (INIS)

    In studies of the origin and fates of trace elements, it is advantageous to be able to analyze samples for a wide spectrum of elements with a high sensitivity and accuracy. This condition is best satisfied with instrumental neutron activation analysis (INAA), since it is one of the most sensitive, selective, and reliable multielement analysis techniques available. In spite of these advantages in environmental studies, use of the technique has been generally limited to aerosol and source material analysis. Over the last few years, the trace analysis and radiochemistry group at the Massachusetts Institute of Technology's Nuclear Reactor Laboratory has applied INAA to various environmental samples for methodology development and/or to provide more information on some important environmental processes. Some examples of these studies are provided in this paper

  4. Artificial Neural Network Characteristic For Neutron Activation Analysis

    International Nuclear Information System (INIS)

    Neutron activation analysis (NAA) is one of analysis methods for identification of elements from material. Irradiated unknown material could be identified by gamma spectrum pattern analysis. The recognition process will be done easily if we have a smart system. One of the smart system choices was artificial neural network (ANN). The gamma spectrum emitted from radioactive nuclide has specific pattern, therefore smart system will try to classify the input data. Firstly, Hp-Ge detector detects gamma radiation from material, then the gamma radiations is counted by multi channel analysis instrument (MCA). The smart system based ANN system was tested to identify 50 material, in which the system has been trained by using one data only for each classifications. The result showed that the ANN appreciates 100% identification capability or has a good performance

  5. Automatization of the neutron activation analysis method in the nuclear analysis laboratory

    International Nuclear Information System (INIS)

    In the present paper the work done to automatice the Neutron Activation Analysis technic with a neutron generator is described. An interface between an IBM compatible microcomputer and the equipment in use to make this kind of measurement was developed. including the specialized software for this system

  6. RADSAT Benchmarks for Prompt Gamma Neutron Activation Analysis Measurements

    Energy Technology Data Exchange (ETDEWEB)

    Burns, Kimberly A.; Gesh, Christopher J.

    2011-07-01

    The accurate and efficient simulation of coupled neutron-photon problems is necessary for several important radiation detection applications. Examples include the detection of nuclear threats concealed in cargo containers and prompt gamma neutron activation analysis for nondestructive determination of elemental composition of unknown samples. High-resolution gamma-ray spectrometers are used in these applications to measure the spectrum of the emitted photon flux, which consists of both continuum and characteristic gamma rays with discrete energies. Monte Carlo transport is the most commonly used simulation tool for this type of problem, but computational times can be prohibitively long. This work explores the use of multi-group deterministic methods for the simulation of coupled neutron-photon problems. The main purpose of this work is to benchmark several problems modeled with RADSAT and MCNP to experimental data. Additionally, the cross section libraries for RADSAT are updated to include ENDF/B-VII cross sections. Preliminary findings show promising results when compared to MCNP and experimental data, but also areas where additional inquiry and testing are needed. The potential benefits and shortcomings of the multi-group-based approach are discussed in terms of accuracy and computational efficiency.

  7. Current studies of biological materials using instrumental and radiochemical neutron activation analysis

    International Nuclear Information System (INIS)

    Instrumental neutron activation analysis still remains the preferred option when analysing the trace element distribution in a wide rage of materials by neutron activation analysis. However, when lower limits of detection are required or major interferences reduce the effectiveness of this technique, radiochemical neutron activation analysis is applied. This paper examines the current use of both methods and the development of rapid radiochemical techniques for analysis of the biological materials, hair, cow's milk, human's milk, milk powder, blood and blood serum

  8. Fast-neutron activation analysis of light elements

    International Nuclear Information System (INIS)

    Full text: The determination of lithium, carbon, oxygen, nitrogen and other light chemical elements in various modern materials in microgram level is of importance for analytical science. As it is well-known, a thermal neutron activation of C, H, N, and O produces negligible γ-ray activity. 13C (n, γ) 14C and 2H (n, γ) 3H reactions produce very small activities of the non- γ- emitters 3H and 14C, and the 19O (n, γ)19O and 15N(n, γ)16N reactions give very short lived 19O (27 sec) and 16N (7.1 sec). All of these reactions have extremely low thermal neutron cross sections. Therefore a major advantage of the instrumental neutron activation analysis (INAA) is the determination of trace elements in biological, medical and environmental materials. For this reason the above mentioned problems are solved with use of some variants of nuclear analytical techniques based on application of charged particle accelerators. However, there are several non-traditional reactor activation analysis techniques to solve such problems which have been developed and applied in various fields of semiconductor industry, biology, geology. In recent years these techniques were named as the nuclear reactor based charged particles activation analysis (NRCPAA). We distinguished two possible applications of a nuclear reactor as charged particles source. During last years the capabilities of the NRCPAA were investigated intensively and some our results were applied to determine light elements contents [1,2]. The recoil protons are produced as the result of (n, p) elastic and inelastic scattering interaction of fast neutrons with nucleus of light elements, for example, hydrogen. These protons are applied for the development of proton activation analysis for the determination of large concentrations of Li, B and O. The non-destructive activation analysis with use of 14-MeV fast neutrons (FNAA) is the most suitable method for analysis of N, P and Si. FNAA was applied for determination of nitrogen

  9. Enhancement of research reactor utilization for neutron activation analysis

    International Nuclear Information System (INIS)

    Analytical Chemistry Division has been utilising NAA for the past 4 decades for trace analysis of a number of materials. Some of the procedures developed recently for the trace element determination of high purity hi-tech and nuclear pure materials, geological, environmental and forensic samples by radiochemical neutron activation analysis (RNAA) are discussed here. Nearly complete characterization of high purity (>4N) As and Ga is possible by the procedures developed which are simple, rapid and elegant and can be used easily for the process samples. It is to be emphasised that though the INAA is simple and being widely followed, the RNAA alone can address the problems of analysis for elements present at ultra trace levels in many matrices. (author)

  10. Quality Assurance and Control in Laboratory using Neutron Activation Analysis

    International Nuclear Information System (INIS)

    In accordance with the increment of international trade associated with the worldwide globalization, the importance of quality assurance and control for the commodity produced from one's own country has been stressed. ISO (International Organization for Standards) defines quality control as 'the operational techniques and activities that are used to fulfill the requirements for quality'. Since 1996, the HANARO research reactor in the Korea Atomic Energy Research Institute has been operated thereafter initial critical operation on April 1995. Neutron activation analysis system and applied techniques which is one of a nuclear analytical technologies using reactor neutrons has been developed for user's supporting and the establishment of the quality system for a measurement and analysis, testing and inspection was implemented successfully. On the basis of the qualified NAA system, the test and measurement of more than 1500 samples which is requested from 30 organizations including industrial companies, universities and institutes carried out in NAA laboratory annually. Moreover, as the goal of mutual recognition agreement (MRA) which can be removed a technical barrier in international trade, the objectivity and the confidence of analytical quality in NAA laboratory became established through the installation of international accreditation system by implementing analytical quality system in accordance with international standards in 2001. The aim of the report was to summarize the technical management of introduction, methods and the results for a quality control and assurance which should be performed in NAA technique using the HANARO research reactor. The report will help building up effective quality control strategy in the future

  11. High precision methods of neutron activation analysis applied to geochemistry

    International Nuclear Information System (INIS)

    Neutron activation analysis is a technique for measuring abundances of chemical elements, which differs from other methods in that it is based upon nuclear reactions instead of chemistry. This characteristic has special relevance for geochemistry because of its inherent sensitivity for trace elements which cannot be reached by other methods. 99% of the earth's crust is made up of just 8 elements, whereas the remaining 1% must accommodate 70-odd rock building trace elements of which about half can be measured by neutron activation analysis. In recent years, there has been much interest in these trace elements because they encompass diverse chemical properties. The present discussion of the technique is based upon more than 15 years of experience at the Lawrence Berkeley Laboratory and The Hebrew University of Jerusalem. This is not meant to intimate that the practices in other laboratories do not merit attention. Perhaps our approach differs from other published work in the emphasis given to sources of error and learning how to control them

  12. Neutron imaging and prompt gamma activation analysis using a monolithic capillary neutron lens

    International Nuclear Information System (INIS)

    Neutron focusing lenses have been shown to enhance the measurement capabilities of prompt gamma activation analysis (PGAA) for small samples (∼100 μm in size) using a reactor-based cold neutron beam. As reported in our earlier work, a cold neutron beam emerging from a 58Ni-coated guide, cross section 50 mm x 45 mm, is compressed to a spot size of about 0.54 mm (FWHM). In the current work, we report preliminary prompt gamma measurements performed with a monolithic capillary lens that accepts a 10 mm (hexagon flat-to-flat) size beam and focuses it to a spot size of 40. The smaller focal spot size enables better spatial resolution, but also makes sample alignment more challenging. We have added a neutron imaging technique to the sample positioning procedure that takes advantage of the converging and subsequent diverging nature of the focused beam. The measurement sensitivity for a 2.6 μg Gd sample has improved by a factor of 34. In addition to rastering samples in the lateral plane, we have also explored the possibility of profiling the inhomogeneity of the sample in the direction along the beam axis. (author)

  13. Neutron activation analysis of medieval and early modern times ceramics

    International Nuclear Information System (INIS)

    Provenience studies of medieval and early modern times ceramics from the Eastern Danube area of Austria have been performed by instrumental neutron activation analysis. All sherds examined were selected from pottery which was specially charactrized by pottery marks ('Cross Potent', 'Crossmark within a circle', 'Latin Cross', 'Cross Paty'). With respect to the chemical composition five different pottery groups could be evaluated by cluster analysis. Archaeological results: The'Cross Patent' was used by different potter's workshops whereas the 'Crossmark within a circle' was more likely restricted to one manufacture entre. The distribution of the 'Latin Cross' and The 'Cross Paty' over all five clusters indicated the usage of clay from different deposits. The assignment of the 'Cross Paty' exclusively to the area of Passau could be disproved. (Author)

  14. Study of trace impurities in heroin by neutron activation analysis

    International Nuclear Information System (INIS)

    Sixty-two heroin samples were analyzed for their contents of 15 trace elements (Au, Ba, Br, Ca, Ce, Co, Cr, Fe, La, Na, Sb, Sc, Sm, Th, and Zn) by neutron activation analysis (NAA). Large variations of elemental concentrations between samples were found to possess statistical significance. Of all the elements calcium was the most abundant element, followed by zinc and sodium. The concentrations of Au, Ce, Co, La, Sb, Sc, Sm, and Th in all the samples were below 1 μg x g-1. Classification of these heroin samples was achieved by the application of hierarchical cluster analysis. The results show that NAA can provide useful information on the origin of the illicit drugs. (author)

  15. Extraction and neutron activation analysis of humic substances

    International Nuclear Information System (INIS)

    Methods are described for the isolation of humic substances from a soil sample. The procedures are based on extractions with sodium hydroxide or sodium pyrophosphate. Four of the humic samples were dried and then analyzed by thermal neutron activation analysis. The humic samples along with three standard rocks were irradiated for 15 hours in a flux of approx. 10sup(12)nxcmsup(-2)xssup(-1). Counting was carried out using both a large volume Ge(Li) detector and a high resolution LEP detector. Quantitative analysis was based on the known element concentrations in the standard rocks. The elements determined were Sc, Cr, Fe, Co, As, Se, Br, Mo, Sb, La, Ce, Eu, Hf, Ta, Th and U. Concentrations ranged from 0.02 ppm (La) to 7900 ppm (Fe). (author)

  16. Neutron activation analysis for monitoring northern terrestrial ecosystems

    International Nuclear Information System (INIS)

    New experimental data have been obtained on heavy metal and rare-earth element concentrations in environmental objects, namely pine needles and soils, caused by atmospheric pollution in different regions of the Kola Peninsula. The investigation was performed with the use of epithermal neutron activation analysis at the IBR-2 fast pulsed reactor. The analysis of nearly 40 element distributions in pine needles and soils from the studied geographical points testifies of a strong contamination source - the nickel smelting complex in Monchegorsk. The contamination levels for Ni, Co, Cr, Se, and others are also high and may be hazardous for this region population because some of these elements are carcinogenic. 6 refs., 1 fig., 2 tabs

  17. Cyclic neutron activation analysis of fluorine concentration in Chinese teas

    International Nuclear Information System (INIS)

    Based on advantage of cyclic neutron activation of 20F(t1/2=11.03 s), cyclic neutron activation analysis (CNAA) and three traditional methods, i.e.UV-vis spectroscopy, fluorine ion selective electrode, and chromatography of ions,were used to determine fluorine concentration in standard reference materials of tea (GBW10016). Compared with the three traditional methods, CNAA is accurate, sensitive, time-saving, little sample amount,strong traceability and good anti-interference. Fluorine concentrations in 16 commercial teas of four categories were determined by using CNAA. The results showed that fluorine concentrations of brick tea, black tea, oolong tea and green tea are 60 276, 54 66, 37 59 and 34 49 mg/kg, respectively. It was also found that the fluorine concentrations in different tea categories are likely attributed to their raw materials and production process. Fluoride concentration in one tea product was 276 mg/kg, while the national standard is ≤200 mg/kg. (authors)

  18. Cosmetics chemical composition characterization by instrumental neutron activation analysis

    International Nuclear Information System (INIS)

    Brazil is in the third position in the world's cosmetics market. It is an expanding and growing market where new products and manufacturing processes are in a constant and steady expansion. Therefore, it is mandatory that the composition of the products is well known in order to guarantee safety and quality of daily used cosmetics. The Brazilian National Health Surveillance Agency (ANVISA) has issued a resolution, RDC No. 48, March 16, 2006, which defines a 'List of Substances which can not be used in personal hygiene products, cosmetics and perfumes'. In this work, samples of locally manufactured and imported cosmetics (lipsticks, eye shadows, etc.) were analyzed using the Instrumental Neutron Activation Analysis technique. The samples were irradiated in the TRIGA IPR-R1 reactor of the Centro de Desenvolvimento da Tecnologia Nuclear (CDTN/CNEN), on a 100kW thermal power, with a thermal neutron fluence rate about 8x1011ncm-2s-1. The analysis has detected the chemical elements Br, Ba, Ga, Na, K, Sc, Fe, Cr, Zn, Sm, W, La, Rb, Cs, Ta, Ge, Co, U, Ti, V, Cl, Al, Mn and Cu. The concentrations of these elements are on a range from 5 to 3000μg.g-1. Some chemical elements observed in samples (Cl, Br, Cr, U) are included at ANVISA prohibitive list. (author)

  19. Neutron activation analysis of essential elements in Multani mitti clay using miniature neutron source reactor

    International Nuclear Information System (INIS)

    Multani mitti clay was studied for 19 essential and other elements. Four different radio-assay schemes were adopted for instrumental neutron activation analysis (INAA) using miniature neutron source reactor. The estimated weekly intakes of Cr and Fe are high for men, women, pregnant and lactating women and children while intake of Co is higher in adult categories and Mn by pregnant women. Comparison of MM clay with other type of clays shows that it is a good source of essential elements. - Highlights: ► Multani mitti clay has been studied for 19 essential elements for human adequacy and safety using INAA and AAS. ► Weekly intakes for different consumer categories have been calculated and compared with DRIs. ► Comparison of MM with other type of clays depict that MM clay is a good source of essential elements.

  20. Neutron activation analysis: nuclear interference from iron in manganese

    International Nuclear Information System (INIS)

    In the present work, the contribution of iron was verified in the analysis of manganese through the reaction of interference by fast neutron. The irradiation of the samples was accomplished in the channel IC-40 of the rotary rack of the TRIGA MARK I IPR-R1 research reactor, located at Nuclear Technology Development Centre/Brazilian Commission for Nuclear Energy, CDTN/CNEN. In this irradiation device, the average thermal neutron flux is 6.69 x 1011 neutron cm-2 s-1 and fast neutron flux is 7.37 x 1010 neutron cm-2 s-1. Manganese was determined through 56Mn induced by thermal neutron flux according to the reaction 55Mn(n, γ)56Mn. In the analysis of manganese, the contribution of iron was investigated according to the reaction of interference 56Fe(n, p)56Mn produced by the fast neutron. It was verified that the contribution of 1 g of iron is 20 μg of manganese. (author)

  1. Epithermal Neutron Activation Analysis of the Asian Herbal Plants

    Science.gov (United States)

    Baljinnyam, N.; Jugder, B.; Norov, N.; Frontasyeva, M. V.; Ostrovnaya, T. M.; Pavlov, S. S.

    2011-06-01

    Asian medicinal herbs Chrysanthemum (Spiraea aquilegifolia Pall.) and Red Sandalwood (Pterocarpus Santalinus) are widely used in folk and Ayurvedic medicine for healing and preventing some diseases. The modern medical science has proved that the Chrysanthemum (Spiraea aquilegifolia Pall.) possesses the following functions: reducing blood press, dispelling cancer cell, coronary artery's expanding and bacteriostating and Red Sandalwood (Pterocarpus Santalinus) is recommended against headache, toothache, skin diseases, vomiting and sometimes it is taken for treatment of diabetes. Species of Chrysanthemums were collected in the north-eastern and central Mongolia, and the Red Sandalwood powder was imported from India. Samples of Chrysanthemums (branches, flowers and leaves) (0.5 g) and red sandalwood powder (0.5 g) were subjected to the multi-element instrumental neutron activation analysis using epithermal neutrons (ENAA) at the IBR-2 reactor, Frank Laboratory of Neutron Physics (FLNP) JINR, Dubna. A total of 41 elements (Na, Mg, Al, Cl, K, Ca, Sc, V, Cr, Mn, Fe, Co, Ni, Zn, As, Se, Br, Rb, Sr, Zr, Mo, Cd, Cs, Ba, La, Hf, Ta, W, Sb, Au, Hg, Ce, Nd, Sm, Eu, Tb, Dy, Yb, Th, U, Lu) were determined. For the first time such a large group of elements was determined in the herbal plants used in Mongolia. The quality control of the analytical results was provided by using certified reference material Bowen Cabbage. The results obtained are compared to the "Reference plant» data (B. Markert, 1992) and interpreted in terms of excess of such elements as Se, Cr, Ca, Fe, Ni, Mo, and rare earth elements.

  2. Epithermal Neutron Activation Analysis of the Asian Herbal Plants

    International Nuclear Information System (INIS)

    Asian medicinal herbs Chrysanthemum (Spiraea aquilegifolia Pall.) and Red Sandalwood (Pterocarpus Santalinus) are widely used in folk and Ayurvedic medicine for healing and preventing some diseases. The modern medical science has proved that the Chrysanthemum (Spiraea aquilegifolia Pall.) possesses the following functions: reducing blood press, dispelling cancer cell, coronary artery's expanding and bacteriostating and Red Sandalwood (Pterocarpus Santalinus) is recommended against headache, toothache, skin diseases, vomiting and sometimes it is taken for treatment of diabetes. Species of Chrysanthemums were collected in the north-eastern and central Mongolia, and the Red Sandalwood powder was imported from India. Samples of Chrysanthemums (branches, flowers and leaves)(0.5 g) and red sandalwood powder (0.5 g) were subjected to the multi-element instrumental neutron activation analysis using epithermal neutrons (ENAA) at the IBR-2 reactor, Frank Laboratory of Neutron Physics (FLNP) JINR, Dubna. A total of 41 elements (Na, Mg, Al, Cl, K, Ca, Sc, V, Cr, Mn, Fe, Co, Ni, Zn, As, Se, Br, Rb, Sr, Zr, Mo, Cd, Cs, Ba, La, Hf, Ta, W, Sb, Au, Hg, Ce, Nd, Sm, Eu, Tb, Dy, Yb, Th, U, Lu) were determined. For the first time such a large group of elements was determined in the herbal plants used in Mongolia. The quality control of the analytical results was provided by using certified reference material Bowen Cabbage. The results obtained are compared to the ''Reference plant? data (B. Markert, 1992) and interpreted in terms of excess of such elements as Se, Cr, Ca, Fe, Ni, Mo, and rare earth elements.

  3. Current status of neutron activation analysis using the Dalat Nuclear Research Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Nguyen Van Suc; Nguyen Mong Sinh [Nuclear Research Institute, Dalat (Viet Nam)

    1999-10-01

    Neutron activation analysis is one of the most sensitive, rapid, accurated methods for determination of trace elements in different materials. A review is made of the current status of the activities and the results in studying and developing NAA (Neutron Activation Analysis) at the Dalat Nuclear Research Institute and applying this method to different sectors of science and technology in Vietnam. (author)

  4. Archaeometry Applications of Cold Neutron Based Prompt Gamma Neutron Activation Analysis. Chapter 9

    International Nuclear Information System (INIS)

    Prompt gamma activation analysis (PGAA) is based on the detection of prompt gamma radiation following the capture of neutrons into the atomic nucleus. Since every atomic nucleus emits characteristic prompt gamma radiation, this method is suitable for multielemental (panorama) analysis. The PGAA method can be regarded as absolutely non-destructive, because of the relatively low intensity of the beam. The main focus of this project was on the research of ancient ceramics. Pottery production was one of the most important crafts of prehistoric communities. As the first aim of this project, pottery findings from Neolithic and later prehistoric sites in Hungary were investigated with PGAA. Compositions of local sediments, as potential raw material sources, were compared with those of pottery. As the second aim of the project, pottery fragments from the multiperiod site at Voers, in south-west Hungary, were analysed, together with clay from the surrounding areas. In a firing experiment, an attempt to reproduce the ancient production techniques was made. As a third aim of the project, PGAA was tested from a methodological point of view. The reliability of the method has been occasionally checked through parallel measurements of archaeological samples with instrumental neutron activation analysis and X ray fluorescence analysis as well. The authors took part in a proficiency test, organized by the IAEA, on a porcelain material. (author)

  5. The comparison of four neutron sources for Prompt Gamma Neutron Activation Analysis (PGNAA) in vivo detections of boron

    International Nuclear Information System (INIS)

    A Prompt Gamma Ray Neutron Activation Analysis (PGNAA) system, incorporating an isotopic neutron source has been simulated using the MCNPX Monte Carlo code. In order to improve the signal to noise ratio different collimators and a filter were placed between the neutron source and the object. The effect of the positioning of the neutron beam and the detector relative to the object has been studied. In this work the optimisation procedure is demonstrated for boron. Monte Carlo calculations were carried out to compare the performance of the proposed PGNAA system using four different neutron sources (241Am/Be, 252Cf, 241Am/B, and DT neutron generator). Among the different systems the 252Cf neutron based PGNAA system has the best performance. (author)

  6. Determination of impurities in zirconium oxide by neutron activation analysis

    International Nuclear Information System (INIS)

    The instrumental method of neutron activation analysis was applied to the determination of impurities in zirconium oxide samples produced at IPEN-CNEN/SP. The samples and the standards of the elements to be determined were irradiated in the IEA-R1 research reactor under a thermal neutron flux from 1011 to 1012 n.cm-2.s-1 for a period that varied from 3 min to 8 h and after adequate cooling time they were counted in a Ge(Li) detector coupled to a multichannel analyzer. The impurities of Al, Dy, Eu, Fe, Hf, Mn, Sc, Ta, Tb, Th and V were determined quantitatively in zirconium oxide samples. The relative standard deviations of the results for several impurities were, in general, lower than 15%. In order to investigate the accuracy obtainable with the method a standard reference material Zircaloy 2 - SRM-360a from NIST was analysed. The quantitative determination limit was also evaluated for impurities present in zirconium oxide samples. (author)

  7. Reactor neutron activation analysis on reference materials from intercomparison runs

    International Nuclear Information System (INIS)

    A review of using the Instrumental Neutron Activation Analysis (INAA) technique in our laboratory to determine major, minor and trace elements in mineral and biological samples from international intercomparison runs organised by IAEA Vienna, IAEA-MEL Monaco, 'pb-anal' Kosice, INCT Warszawa and IPNT Krakow is presented. Neutron irradiation was carried out at WWR-S reactor in Bucharest (short and long irradiation) during 1982-1997 and at TRIGA reactor in Pitesti (long irradiation) during the later period. The following type of materials were analysed: soils, marine sediments, uranium phosphate ore, water sludge, copper flue dust, whey powder, yeast, cereal flour (rye and wheat), marine animal tissue (mussel, garfish and tuna fish), as well as vegetal tissue (seaweed, cabbage, spinach, alfalfa, algae, tea leaves and herbs). The following elements could be, in general, determined: Ag, As, Au, Ba, Br, Ca, Ce, Co, Cr, Cs, Eu, Fe, Hf, Hg, K, La, Lu, Mo, Na, Nd, Ni, Rb, Sb, Sc, Se, Sm, Sr, Ta, Tb, Th, U, W, Yb and Zn of long-lived radionuclides, as well as Al, Ca, Cl, Cu, Mg, Mn, and Ti of short-lived radionuclides. Data obtained in our laboratory for various matrix samples presented and compared with the intercomparison certified values. The intercomparison exercises offer to the participating laboratories the opportunity to test the accuracy of their analytical methods as well as to acquire valuable Reference Materials/ standards for future analytical applications. (authors)

  8. Semiautomatic exchanger of samples for carry out neutron activation analysis

    International Nuclear Information System (INIS)

    In this paper the design methodology and implementation of a semiautomatic exchanger of samples for the Analysis Laboratory by Neutron Activation of the Reactor department is presented. Taking into account the antecedents, the necessities of improvement are described, as well as the equipment that previously contained the Laboratory. The project of the semiautomatic exchanger of samples was developed at Instituto Nacional de Investigaciones Nucleares, with its own technology to increase independence from commercial equipment. Each element of the semiautomatic exchanger of samples is described both in the design phase as construction. The achieved results are positive and encouraging for the fulfillment of the proposed objective that is to increase the capacity of the Laboratory. (Author)

  9. Tracking soil transport to sugarcane industry using neutron activation analysis

    International Nuclear Information System (INIS)

    Soil as mineral impurity in sugarcane loads impacts the Brazilian sugar-ethanol industry with rising production and maintenance costs as well as decreased productivity. The mechanical harvesting of sugarcane was conceived as a technology with potential to increase the raw material quality thereby has been gradually replacing manual harvesting throughout the country. Instrumental neutron activation analysis was applied for determination of soil tracers in order to compare the performance of both harvesting systems in terms of mineral impurities. There were no significant differences in the amount of soil transported to sugarcane industry despite the technological progress aggregated to mechanical harvesting. However, for both harvesting systems there were significant differences on the amount of such mineral impurity between clay and sandy soils. (author)

  10. Neutron activation analysis of phytotherapic obtained from medicinal plants

    International Nuclear Information System (INIS)

    This paper determines the inorganic constituents in phytotherapic samples for posterior study of the relationship existent among the concentrations of the found elements and the their possible therapeutical effects. The samples of phytotherapic pills (Centella asiatica, Ginkgo biloba and Ginseng) were analysed by using neutron activation analysis (NAA). The As, Br, Ca, Co, Cr, Cs, Fe, K, La, Na, Rb, Sc, Se and Zn samples were determined in the phytotherapics, The Centella asiatica presented the higher concentrations of Br, Co, Cr, Fe, K, La, Na, Rb, Sc, Se and Zn. In the sample of Ginko biloba, higher levels of As and Ca were found, while in the sample ol Ginseng the element As were not detected. The found results have shown the the NAA method is appropriated for analysing this type of materials due to his simplicity, multielemental capacity and quality of the results obtained. (author)

  11. Neutron activation analysis of snow and ice in Antarctica

    International Nuclear Information System (INIS)

    In order to minimize the possible contamination during storing and pre-treatment of such pure samples as ice and snow collected in Antarctica, trace elements in experimental tools such as bottles, beakers, tubings and filters were determined by neutron activation analysis. By using well certified tools, ice and snow samples from Antarctica and high mountains in China and in Japan were analyzed. Relative concentrations of volatile elements such as Zn, Cd, As, Sb or Ag to Al or Fe which are major components in the earth crust were found to be 10 to 1000 times higher than in the ordinary soil for the samples from Antarctica and Mt. Naimonanyi in China. (author) 5 refs.; 7 tabs

  12. Instrumental neutron activation analysis of archaeological ceramics: Progress and challenges

    International Nuclear Information System (INIS)

    Instrumental neutron activation analysis (INAA) has become a widely used technique in the characterization of archaeological ceramics. Early applications, primarily developmental in nature, have been replaced by studies that attempt to place the derived analytical data in a larger archaeological and behavioural context. If archaeology is to increasingly exploit the great potential of INAA to address a broad range of social and cultural issues involving ceramics, greater attention must be paid to the various sources of variation that contribute to the chemical composition of pottery. In addition, as all research takes place within a social context, efforts must be made to increase the communication between archaeologists and other scientists, as this will contribute to the fulfilment of the archaeological research objectives. (author)

  13. Instrumental Neutron Activation Analysis in archaeology interpretation beyond elemental abundance

    International Nuclear Information System (INIS)

    Application of instrumental neutron activation analysis to the study of archaeological ceramics involves the determination of the source or sources used to produce pottery. Groups of relatively homogeneous elemental abundances are shown to be statically distinct from one another often leading to the assesment of what was locally produced and what was imported to a site. These assesment, however are among the most preliminary interpretations. Archaeology is concerned with the reasons for artificial distributions and how and why the distribution varied through time 3 reasons that include the social and political basis of ancient economics and how these responded to other factors, such as ideology. These objectives are addressed through the increasing refinement of compositional groups leading toward greater specificity of attribution. In so doing the role of analytical precision among other considerations groves in importance. This paper illustration some of these considerations with examples from the U.S. southwest, the Maya region of southern mexico, and lower central America

  14. Neutron activation analysis of organohalogens in Chinese human hair

    International Nuclear Information System (INIS)

    To effectively extract organohalogens from human hair, two factors, the extracting time and hair length on the extraction efficiency of organohalogens were studied by neutron activation analysis (NAA) and gas chromatograph-electron capture detector (GC-ECD), respectively. Furthermore, the concentrations of extractable organohalogens (EOX) and extractable persistent organohalogens (EPOX) in hair samples from angioma and control babies were also measured by the established method. The results indicated that the optimal Soxhlet-extraction time for EOX and EPOX in hair was from 8 to 11 hours, and the extraction efficiencies for organochlorine pesticides in hair were in the order of powder >2 mm>5 mm. Also, the mean levels of EOCl and EPOCl in hair of the angioma babies were significantly higher than those in the control babies (PEOClEPOCl<0.05), which implied the possible relationship between the environmental pollution and angioma. (author)

  15. Instrumental neutron activation analysis of fly ash, aerosols and hair

    International Nuclear Information System (INIS)

    Samples of coal, slag, emissions retained on the separating devices, fly ash, aerosols and hair taken in the area of coal-fired power plant were analyzed by means of instrumental neutron activation analysis. 13 to 23 elements were determined in the samples. The data obtained for emissions and aerosols were further evaluated by calculation of enrichment factors, correlation coefficients and by the ratio matching method. The concentrations of elements determined in the hair of the exposed group were compared with data of control and so called ''out control'' groups as well as with recent data found for hair in other countries. It can be seen from the results that arsenic is the most serious pollutant in the area. (author)

  16. Instrumental neutron activation analysis of the hair of metallurgical workers

    International Nuclear Information System (INIS)

    Hair samples were collected from 20 metallurgical workers (10 males and 10 females) and from 59 control subjects (32 males and 27 females), whose jobs do not indicate a specific occupational exposure. The concentrations of ten minor and trace elements (Al, Co, Cu, Fe, Mg, Mn, Sb, Se, V and Zn) were determined by instrumental neutron activation analysis (INAA). The statistical data distributions, the sex and age influences in these elemental concentrations and the average values obtained for the control group were compared with published data. The effect of occupational exposure to the metallic elements was reflected in elemental compositon of hair by significant higher concentration levels of Al, Co, Cu, Fe, Mg, Mn, Sb, V and Zn in the hair of the exposed group, when compared with the control group. (author)

  17. Quality Assurance and Control in Laboratory using Neutron Activation Analysis

    Energy Technology Data Exchange (ETDEWEB)

    Chung, Y. S.; Moon, J. H.; Sun, G. M.; Kim, S. H.; Baek, S. Y.; Lim, J. M.; Kim, H. R

    2007-01-15

    In accordance with the increment of international trade associated with the worldwide globalization, the importance of quality assurance and control for the commodity produced from one's own country has been stressed. ISO (International Organization for Standards) defines quality control as 'the operational techniques and activities that are used to fulfill the requirements for quality'. Since 1996, the HANARO research reactor in the Korea Atomic Energy Research Institute has been operated thereafter initial critical operation on April 1995. Neutron activation analysis system and applied techniques which is one of a nuclear analytical technologies using reactor neutrons has been developed for user's supporting and the establishment of the quality system for a measurement and analysis, testing and inspection was implemented successfully. On the basis of the qualified NAA system, the test and measurement of more than 1500 samples which is requested from 30 organizations including industrial companies, universities and institutes carried out in NAA laboratory annually. Moreover, as the goal of mutual recognition agreement (MRA) which can be removed a technical barrier in international trade, the objectivity and the confidence of analytical quality in NAA laboratory became established through the installation of international accreditation system by implementing analytical quality system in accordance with international standards in 2001. The aim of the report was to summarize the technical management of introduction, methods and the results for a quality control and assurance which should be performed in NAA technique using the HANARO research reactor. The report will help building up effective quality control strategy in the future.

  18. Development Of The Computer Code For Comparative Neutron Activation Analysis

    International Nuclear Information System (INIS)

    The qualitative and quantitative chemical analysis with Neutron Activation Analysis (NAA) is an importance utilization of a nuclear research reactor, and this should be accelerated and promoted in application and its development to raise the utilization of the reactor. The application of Comparative NAA technique in GA Siwabessy Multi Purpose Reactor (RSG-GAS) needs special (not commercially available yet) soft wares for analyzing the spectrum of multiple elements in the analysis at once. The application carried out using a single spectrum software analyzer, and comparing each result manually. This method really degrades the quality of the analysis significantly. To solve the problem, a computer code was designed and developed for comparative NAA. Spectrum analysis in the code is carried out using a non-linear fitting method. Before the spectrum analyzed, it was passed to the numerical filter which improves the signal to noise ratio to do the deconvolution operation. The software was developed using the G language and named as PASAN-K The testing result of the developed software was benchmark with the IAEA spectrum and well operated with less than 10 % deviation

  19. A package for gamma-ray spectrum analysis and routine neutron activation analysis

    Indian Academy of Sciences (India)

    M E Medhat; A Abdel-Hafiez; Z Awaad; M A Ali

    2005-08-01

    A package for gamma spectrum analysis (PGSA) was developed using object oriented Borland C++ design for MS-windows. This package consists of five programs which can be used for gamma-ray spectrum analysis and routine neutron activation analysis. The advantages of PGSA are its simple algorithms and its need for only minimum amount of input information.

  20. Diagnosis of mucoviscidosis by neutron activation analysis. Part 1; Diagnostico da mucoviscidose utilizando analise por ativacao com neutrons. Parte 1

    Energy Technology Data Exchange (ETDEWEB)

    Bellido, Luis F.; Bellido, Alfredo V

    1997-02-01

    Symptoms pathology, incidence, and gravity of the inherent syndrome called mucoviscidosis, or cystic fibrosis are described in this Part I. The analytical methods used for its diagnosis, both the conventional chemical ones and by neutron activation analysis are also summarised. Finally, an analytical method to study the incidence of mucoviscidosis in Brazil is presented. This , essentially, consists in bromine determination, in fingernails, by resonance neutron activation analysis. (author) 33 refs., 13 figs.

  1. Fusion material transmutation and activation analysis induced by fast neutrons: Anita-IEAF Activation Code Package

    International Nuclear Information System (INIS)

    This paper presents the Anita-IEAF code package for the activation characterization of materials exposed to neutrons with energies above 20 MeV. Its origins trace back to the Anita-2000 code (NEA-1638, RSICC CCC-606). Anita-IEAF is able to manage the many reaction channels for neutron energies up to 150 MeV. It computes the radioactive inventories of materials exposed to neutron irradiation, continuously or stepwise. It provides activity, isotopic nuclide density, decay heat, biological hazard, clearance index and gamma ray source spectra at shutdown and at different cooling times. The code package is provided with a complete database that includes neutron activation data library, decay, hazard and clearance data library, and gamma library. The Anita-IEAF neutron activation library was produced by processing the IEAF-2001 data activation files that have been recently released by FZK. It contains the neutron activation cross-sections for 679 nuclides in the 256 neutron energy group structure up to 150 MeV, in EAF format. That group structure includes the standard Vitamin-J 175 groups for energies below 20 MeV and 81 groups for the highest energies. The paper presents also an application of the Anita-IEAF code package to the neutron exposure characterization for the SS-316 liner and heat shield of the Test Cell area of the International Fusion Materials Irradiation Facility (IFMIF). The decay gamma source evaluation for SS-316, needed for dose rate calculations at beam-off IFMIF phase for shielding analysis, is discussed too. (authors)

  2. Using robust statistics to improve neutron activation analysis results

    Energy Technology Data Exchange (ETDEWEB)

    Zahn, Guilherme S.; Genezini, Frederico A.; Ticianelli, Regina B.; Figueiredo, Ana Maria G., E-mail: gzahn@ipen.b [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil). Centro do Reator de Pesquisas

    2011-07-01

    Neutron activation analysis (NAA) is an analytical technique where an unknown sample is submitted to a neutron flux in a nuclear reactor, and its elemental composition is calculated by measuring the induced activity produced. By using the relative NAA method, one or more well-characterized samples (usually certified reference materials - CRMs) are irradiated together with the unknown ones, and the concentration of each element is then calculated by comparing the areas of the gamma ray peaks related to that element. When two or more CRMs are used as reference, the concentration of each element can be determined by several different ways, either using more than one gamma ray peak for that element (when available), or using the results obtained in the comparison with each CRM. Therefore, determining the best estimate for the concentration of each element in the sample can be a delicate issue. In this work, samples from three CRMs were irradiated together and the elemental concentration in one of them was calculated using the other two as reference. Two sets of peaks were analyzed for each element: a smaller set containing only the literature-recommended gamma-ray peaks and a larger one containing all peaks related to that element that could be quantified in the gamma-ray spectra; the most recommended transition was also used as a benchmark. The resulting data for each element was then reduced using up to five different statistical approaches: the usual (and not robust) unweighted and weighted means, together with three robust means: the Limitation of Relative Statistical Weight, Normalized Residuals and Rajeval. The resulting concentration values were then compared to the certified value for each element, allowing for discussion on both the performance of each statistical tool and on the best choice of peaks for each element. (author)

  3. Medical application of in vivo neutron activation analysis

    Energy Technology Data Exchange (ETDEWEB)

    Cohn, S.H.; Ellis, K.J.; Vartsky, D.; Zanzi, I.; Aloia, J.F.

    1978-01-01

    The clinical usefulness of total body neutron activation analysis (TBNAA) was clearly established at an IAEA panel meeting in Vienna in 1972. It is best demonstrated by the studies involving the measurement of total-body calcium. This measurement provides data useful for the diagnosis and management of metabolic bone disorders. It should be emphasized, however, that while most of the applications to date have involved calcium and phosphorus, the measurement of sodium, chlorine and nitrogen also appear to be useful clinically. Total-body calcium measurements utilizing TBNAA have been used in studies of osteoporosis to establish absolute and relative deficits of calcium in patients with this disease in comparison to a normal contrast population. Changes in total-body calcium (skeletal mass) have also been useful for quantitating the efficacy of various therapies in osteoporosis. Serial measurements over periods of years provide long-term balance data by direct measurement with a higher precision (+- 2%) than is possible by the use of any other technique. In the renal osteodystrophy observed in patients with renal failure, disorders of both calcium and phosphorus, as well as electrolyte disturbances, have been studied. The measure of total-body levels of these elements gives the clinician useful data upon which to design dialysis therapy. The measurement of bone changes in endocrine dysfunction has been studied, particularly in patients with thyroid and parathyroid disorders. In parathyroidectomy, the measurement of total-body calcium, post-operatively, can indicate the degree of bone resorption. Skeletal metabolism and body composition in acromegaly and Cushing's disease have also been investigated by TBNAA. Levels of cadmium in liver and kidney have also been measured in-vivo by prompt-gamma neutron activation and associated with hypertension, emphysema and cigarette smoking.

  4. Medical application of in vivo neutron activation analysis

    International Nuclear Information System (INIS)

    The clinical usefulness of total body neutron activation analysis (TBNAA) was clearly established at an IAEA panel meeting in Vienna in 1972. It is best demonstrated by the studies involving the measurement of total-body calcium. This measurement provides data useful for the diagnosis and management of metabolic bone disorders. It should be emphasized, however, that while most of the applications to date have involved calcium and phosphorus, the measurement of sodium, chlorine and nitrogen also appear to be useful clinically. Total-body calcium measurements utilizing TBNAA have been used in studies of osteoporosis to establish absolute and relative deficits of calcium in patients with this disease in comparison to a normal contrast population. Changes in total-body calcium (skeletal mass) have also been useful for quantitating the efficacy of various therapies in osteoporosis. Serial measurements over periods of years provide long-term balance data by direct measurement with a higher precision (+- 2%) than is possible by the use of any other technique. In the renal osteodystrophy observed in patients with renal failure, disorders of both calcium and phosphorus, as well as electrolyte disturbances, have been studied. The measure of total-body levels of these elements gives the clinician useful data upon which to design dialysis therapy. The measurement of bone changes in endocrine dysfunction has been studied, particularly in patients with thyroid and parathyroid disorders. In parathyroidectomy, the measurement of total-body calcium, post-operatively, can indicate the degree of bone resorption. Skeletal metabolism and body composition in acromegaly and Cushing's disease have also been investigated by TBNAA. Levels of cadmium in liver and kidney have also been measured in-vivo by prompt-gamma neutron activation and associated with hypertension, emphysema and cigarette smoking

  5. Using robust statistics to improve neutron activation analysis results

    International Nuclear Information System (INIS)

    Neutron activation analysis (NAA) is an analytical technique where an unknown sample is submitted to a neutron flux in a nuclear reactor, and its elemental composition is calculated by measuring the induced activity produced. By using the relative NAA method, one or more well-characterized samples (usually certified reference materials - CRMs) are irradiated together with the unknown ones, and the concentration of each element is then calculated by comparing the areas of the gamma ray peaks related to that element. When two or more CRMs are used as reference, the concentration of each element can be determined by several different ways, either using more than one gamma ray peak for that element (when available), or using the results obtained in the comparison with each CRM. Therefore, determining the best estimate for the concentration of each element in the sample can be a delicate issue. In this work, samples from three CRMs were irradiated together and the elemental concentration in one of them was calculated using the other two as reference. Two sets of peaks were analyzed for each element: a smaller set containing only the literature-recommended gamma-ray peaks and a larger one containing all peaks related to that element that could be quantified in the gamma-ray spectra; the most recommended transition was also used as a benchmark. The resulting data for each element was then reduced using up to five different statistical approaches: the usual (and not robust) unweighted and weighted means, together with three robust means: the Limitation of Relative Statistical Weight, Normalized Residuals and Rajeval. The resulting concentration values were then compared to the certified value for each element, allowing for discussion on both the performance of each statistical tool and on the best choice of peaks for each element. (author)

  6. Study on the methods for analysis of the chemical poison in canister by neutron activity

    International Nuclear Information System (INIS)

    The method that is used to analyse the poison gases in canister by neutron activity is proposed. Through theory analysis and experimental measurement, the feasibility for analysis of the poison gases in a canister by neutron activity has been demonstrated, and it is proved that the method itself do not result in radioactive problem to use again the canister. (authors)

  7. Instrumental neutron activation analysis of carbonatites from Panda Hill and Oldoinyo-Lengai, Tanzania

    International Nuclear Information System (INIS)

    Twenty nine (major and trace) elements including nine rare earth elements (REE) in African carbonatite samples were determined by instrumental neutron activation analysis (INAA). The geochemical behavior of trace elements in carbonatites, especially REE pattern (chondrite normalized), and the efficiency of neutron activation analysis compared to other methods are discussed in this study. (author)

  8. Application of neutron activation analysis system in Xi'an pulsed reactor

    CERN Document Server

    Zhang Wen Shou; Yu Qi

    2002-01-01

    Neutron Activation Analysis System in Xi'an Pulsed Reactor is consist of rabbit fast radiation system and experiment measurement system. The functions of neutron activation analysis are introduced. Based on the radiation system. A set of automatic data handling and experiment simulating system are built. The reliability of data handling and experiment simulating system had been verified by experiment

  9. The role of neutron activation analysis in nutritional biomonitoring programs

    International Nuclear Information System (INIS)

    Nutritional biomonitoring is a multidisciplinary task and an integral part of a more general bioenvironmental surveillance. In its comprehensive form, it is a combination of biological, environmental, and nutrient monitoring activities. Nutrient monitoring evaluates the input of essential nutrients required to maintain vital bodily functions; this includes vigilance over extreme fluctuations of nutrient intake in relation to the recommended dietary allowances and estimated safe and adequate daily dietary intakes and adherence to the goals of provisional tolerance limits. Environmental monitoring assesses the external human exposure via ambient pathways, namely, air, water, soil, food, etc. Biological monitoring quantifies a toxic agent and its metabolites in representative biologic specimens of an exposed organ to identify health effects. In practice, coordinating all three components of a nutritional biomonitoring program is complex, expensive, and tedious. Experience gained from the US National Health and Nutrition Examination Surveys demonstrates the problems involved. By far the most critical challenge faced here is the question of analytical quality control, particularly when trace element determinations are involved. Yet, measures to ensure reliability of analytical data are mandatory, and there are no short-cuts to this requirement. The purpose of this presentation is to elucidate the potential of neutron activation analysis (NAA) in nutritional biomonitoring activities

  10. Prompt gamma-ray neutron activation analysis of boron using Deuterium-Deuterium (D-D) neutron generator

    International Nuclear Information System (INIS)

    Prompt gamma-ray neutron activation analysis (PGNAA) is a nuclear analytical technique for the determination of trace and other elements in solid, liquid or gaseous samples. The method consists in observing gamma rays emitted by a sample during neutron irradiation. The PGNAA system was built using a moderated and shielded deuterium-deuterium (D-D) neutron generator. This facility has been developed to determine the chemical composition of materials. The neutron generator is composed of three major components: An RF-Induction Ion Source, the Secondary Electron Shroud, and the Diode Accelerator Structure and Target. The generator produces monoenergetic neutrons (2.5 MeV) with a yield of 1010 n/s using 25-50 mA of beam current and 125 kV of acceleration voltage. Prompt γ-ray neutron activation analysis of 10B concentrations in Si and SiO2 matrices was carried out using a germanium detector (HPGe) and the results obtained are compared with a PGNAA system using a NaI detector. Neutron flux and energy distribution from D-D neutron generator at the sample position was calculated using Monte Carlo simulation. The interaction properties of neutrons in a Germanium detector have been studied. (author)

  11. Recent applications of neutron activation analysis in Korea

    International Nuclear Information System (INIS)

    There are two purposes in this research; first aim is to promote the use of neutron activation analysis (NAA) as a utilization of nuclear research reactor in the field of air pollution studies through a routine and long-term monitoring. Other is to improve NAA with an experimental simplicity, high accuracy, excellent flexibility with respect to irradiation and counting conditions. For the study on air pollution, airborne particulate matter (APM) for the fine (< 2.5 μm EAD) and coarse particle (2.5-10 μm EAD) fractions were collected using the Gent stacked filter unit low volume sampler and two types of Nuclepore polycarbonate filters. Air samples were collected at two regions (suburban and industrial site of Daejeon city in the Republic of Korea) from January to December 2002. Mass concentration and elemental black carbon of APM were measured and the concentration of 25 elements were determined by Instrumental NAA. Analytical quality control is carried out using three certified reference materials (CRM). The monitoring data were treated statistically to assess air pollution source and source apportionment. The results obtained from this project can be used to investigate source identification and apportionment and its trends, and to establish a more cost-effective method for national air quality management. Preliminary experiment for application of ko-standardization method has been carried out to determine the reactor neutron spectrum parameters, i.e.a and f-values as the main factors of irradiation quality at NAA no.1 irradiation hole on HANARO research reactor, to determine peak detection efficiency for the HP Ge(EG and G ORTEC, GEM 35185) detector for the use in the ko-experiments and to compare the measured concentration results with the certified values of some CRMs applying the experimentally determined ko-parameters. (author)

  12. Multielement Analysis of Libyan Soils by ko Instrumental Neutron Activation Analysis

    International Nuclear Information System (INIS)

    This paper concentrates on the assessment of theko-method of instrumental neutron activation in soil analysis without relying on the standard reference materials. This method has been applied in multielement analysis of soil samples. Using reactor neutron activation analysis based on ko method, numerous elements were determined in the samples in single irradiation. The samples were irradiated for 8 hours under thermal neutron flux ∼ 8.9x1012 n cm-2 s-1 in channel VCR11 of Tajura Research reactor. The accuracy of the method was ascertained by the analysis of the reference materials SL-1 and SoilL-7. The results are weighted mean with the expected/observed uncertainties (%) based on the standard deviation in the peak area. (Authors)

  13. Determination of rhenium in molybdenite by neutron-activation analysis.

    Science.gov (United States)

    Terada, K; Yoshimura, Y; Osaki, S; Kiba, T

    1967-01-01

    A neutron-activation method is described for the determination of rhenium in molybdenite. Radiochemical separation by a carrier technique was carried out very rapidly by means of successive liquid-liquid extraction processes. The recovery of rhenium, which was determined by a spectrophotometric method, was about 93%. About 10 samples could be analysed within 6 hr in parallel runs. PMID:18960067

  14. Trace elements in coloured opals using neutron activation analysis

    Energy Technology Data Exchange (ETDEWEB)

    McOrist, G.D.; Smallwood, A. [Australian Nuclear Science and Technology Organisation, Lucas Heights, NSW (Australia)

    1996-12-31

    Neutron activation analysis (NAA) is a technique particularly suited to analysing opals since it is non-destructive and the silica matrix of opals is not prone to significant activation. It was used to determine the concentration of trace elements in 50 samples of orange, yellow, green, blue and pink opals as well as 18 samples of colourless opals taken from a number of recognised fields in Australia, Peru, Mexico and USA. The results were then evaluated to determine if a relationship existed between trace element content and opal colour. The mean concentration of most of the elements found in orange, yellow and colourless opals were similar with few exceptions. This indicated that, for these samples, colour is not related to the trace elements present. However, the trace element profile of the green, pink and blue opals was found to be significantly different with each colour having a much higher concentration of certain trace elements when compared with all other opals analysed. 7 refs.

  15. Non-destructive neutron activation analysis of dental porcelain powders

    International Nuclear Information System (INIS)

    Determination of 15 elements in the dental porcelain powders (Vita VMK 68) marketed in Japan was done by means of non-destructive neutron activation analysis. The potassium and sodium contents showed less variations from powder to powder, and the uranium contents varied from a few ppm to 1090 ppm in a wide range. The high contents of uranium (345 - 1090 ppm) were detected in the powders of Enamel, Dentin, Effect, Color and Gum which were used for the superficial parts of a porcelain crown, while the low contents of uranium (1.6 - 2.7 ppm) were detected in those of Opaque and Translucent which were used for the core part and the top of the crown. Cerium and samarium were also detected in each powder in the amounts similar to those of uranium. The main radionuclides present in the porcelain powders were 238U, 235U, 234U, sup(234m)Pa, 234Th, 231Th and 40K. The activities of these nuclides were calculated and discussed. (author)

  16. Neutron activation analysis: a powerful tool in provenance investigations

    International Nuclear Information System (INIS)

    It is well known that neutron activation analysis (NAA), both instrumental and destructive, allows the simultaneous determination of a number of elements, mostly trace elements, with high levels of precision and accuracy. These peculiar properties of NAA are very useful when applied to provenance studies, i.e. to the identification of the origin of raw materials with which artifacts had been manufactured in ancient times. Data reduction by statistical procedures, especially multivariate analysis techniques, provides a statistical 'fingerprint' of investigated materials, both raw materials and archaeological artifacts, that, upon comparison, allows the identification of the provenance of prime matters used for artifact manufacturing. Thus information on quarries and flows exploitation in the antiquity, on technological raw materials processing, on trade routes and about the circulation of fakes, can be obtained. In the present paper two case studies are reported. The first one deals with the identification of the provenance of clay used to make ceramic materials, mostly bricks and tiles, recovered from the excavation of a Roman 'villa' in Lomello (Roman name Laumellum) and of Roman settlings in Casteggio (Roman name Clastidium). Both sites are located in the Province of Pavia in areas called Lomellina and Oltrepo respectively. The second one investigates the origin of the white marble used to build medieval arks, Carolingian age, located in the church of San Felice, now property of the University of Pavia. Experimental set-up, analytical results and data reduction procedures are presented and discussed. (author)

  17. Neutron activation analysis in receptor modeling in environmental chemistry

    International Nuclear Information System (INIS)

    The release of air pollutants in high enough concentrations can have adverse health effects on the general public, particularly in urban areas. To develop strategies to manage the quality of air pollution, it is necessary to understand the flow of materials through the system, the sources and sinks, transformation, and transport pathways of the species of interest. An approach that is extensively being used in our laboratories, as well as in many others, is the use of receptor modeling. These models are based on the concepts of conservation of mass and a mass balance analysis, which in turn is based on the characterization of airborne particles into their constituents. From these methods, sources contributing to air quality are identified from the perspective of the receptor or ambient sampler. Separation of the ambient particles containing trace elements into distinct size classes allows the study of various sources to be identified. Another reason for the rapid development of receptor models has been the concurrent development of a variety of analytical techniques that permit greatly improved analyses to provide the needed input data. Two of the most powerful methods are instrumental neutron activation analysis (INAA) and X-ray fluorescence (XRF), including particle-induced X-ray emission. By using these methods along with sophisticated receptor modeling and size fractionation, the authors have been able to identify specific sources of local and regional air pollution

  18. Neutron Activation Analysis of Lead Halide Pollution Aerosols

    International Nuclear Information System (INIS)

    Iodine, bromine and chlorine have been determined by neutron activation analysis in atmospheric samples of both natural and pollution origin, and a comparison of the two sources provides the basis of a technique described in this paper for determining the composition and possible source of lead halide pollution aerosols. The activation analysis procedure employed consists of reactor neutron irradiation of aqueous samples and comparators for 20 min followed by radiochemical separation of iodine, bromine and chlorine and automatic counting of beta radioactivity from solid silver halide sources. Determination of lead by anodic stripping voltammetry (inverse polarography) consists of deposition of Pb++ from the solution onto a composite paraffin- impregnated graphite and mercury electrode at -1.00 V versus the standard calomel electrode, and then stripping by increasing the potential continuously. A significant question of public health interest in the air chemistry of lead is the source of the lead. Ethyl fluid, a mixture of organic lead, bromine and chlorine compounds, burns to form inorganic lead halide particles with Cl/Pb = 0.34 and Br/Pb = 0.39 by weight. In Cambridge, Massachusetts, analyses of cascade impactor aerosols were compared with similarly collected samples from the unpolluted air of Hawaii. The pollution bromine component ranged from 0.4 to 0.1 or less of the lead concentration, indicating in most cases either automotive lead with a bromine deficiency or a mixture of lead from automotive and other sources. In Fairbanks, Alaska, during winter, atmospheric conditions favour high local concentrations of air pollutants. Aerosols collected by Millipore filters show that pollution chlorine averages very nearly the value predicted from the observed lead and the known composition of ethyl fluid, and the automotive source for both chlorine and lead is strongly indicated. Pollution bromine, however, was less than predicted, and the bromine deficiency was about

  19. Status Report on the Neutron Activation Analysis Activities in the Philippines

    International Nuclear Information System (INIS)

    The Philippines has a one megawatt open-pool type nuclear research reactor which is presently utilized in the conduct of nuclear research and development activities. The reactor is operated by the Philippine Atomic Research Center, the research arm of the Philippine Atomic Energy Commission. The reactor is presently utilized in the production of some radioisotopes, nuclear physics experiments and neutron activation analysis. For activation analysis the facilities available include the two 2 inch pneumatic tubes and a 2-inch central core dry-pipe. Although the reactor has been operative since 1963 it was only in the latter part of 1966 that a neutron activation analysis group was organized and almost immediately the training of personnel and setting up of a radiochemical laboratory and nucleonic counting assembly were initiated. Today, the counting system include a 100 channel analyzer with a 3 x 3 inch Nal(Tl) crystal

  20. Elemental analysis of some West Malaysian limestones using neutron activation, delayed neutron and electron microprobe analysis

    International Nuclear Information System (INIS)

    Limestone stratigraphy in Malaysia has been and is dependent almost entirely in palaeontology. However fossil localities are sporadic and as such a new fossil discovery mean the necessity for a complete re-appraisal of the stratigraphy. The almost complete dependence upon palaeontology results from the difficulties of stratigraphy correlation of isolated outcrops, from the cover of tropical vegetation and from the often complex folding and faulting which has been imposed on the geosyn-clinical rocks by the Indonesian-Thai-Malayan orogeny. So by studying the elemental composition of limestones accurately, we would be able to correlate outcrops and other stratigraphic samples independent of fossil finds. The use of delayed neutron analysis would also determine the concentration of uranium and thorium accurately. This study, in conjunction with thermoluminescence and fission track studies, would able us to date the age of the limestones

  1. Multielement analysis of archaic Chinese bronze and antique coins by fast neutron activation analysis

    International Nuclear Information System (INIS)

    Samples of archaic bronze have been investigated by fast neutron activation analysis using both the absolute and relative method. The components Cu, Zn, Sn and Pb have been determined quantitatively. For the detection of lead via the short-lived isomeric state 207mPb, cyclic activation and measurement technique was used with pneumatic sample transfer between detector and central irradiation position of the neutron tube. For non-destructive analysis of antique Chinese coins the samples had to be irradiated outside the neutron generator KORONA. The activation reactions, the evaluation of the elemental concentrations and the accuracy of the results are discussed. The data were corrected for γ-ray self-absorption in the samples and summing of coincident γ-rays in the detector. According to reported typical compositions of Chinese bronze from different dynasties, the age of the samples has been derived from the results obtained. (orig.)

  2. Multielement analysis of archaic Chinese bronze and antique coins by fast neutron activation analysis

    Energy Technology Data Exchange (ETDEWEB)

    Tian, Y.H. (Academia Sinica, Lanzhou, Gansu (China). Inst. of Modern Physics); Pepelnik, R.; Fanger, H.U. (GKSS-Forschungszentrum Geesthacht GmbH, Geesthacht-Tesperhude (Germany, F.R.). Inst. fuer Physik)

    1990-01-01

    Samples of archaic bronze have been investigated by fast neutron activation analysis using both the absolute and relative method. The components Cu, Zn, Sn and Pb have been determined quantitatively. For the detection of lead via the short-lived isomeric state {sup 207m}Pb, cyclic activation and measurement technique was used with pneumatic sample transfer between detector and central irradiation position of the neutron tube. For non-destructive analysis of antique Chinese coins the samples had to be irradiated outside the neutron generator KORONA. The activation reactions, the evaluation of the elemental concentrations and the accuracy of the results are discussed. The data were corrected for {gamma}-ray self-absorption in the samples and summing of coincident {gamma}-rays in the detector. According to reported typical compositions of Chinese bronze from different dynasties, the age of the samples has been derived from the results obtained. (orig.).

  3. Fast-neutron activation analysis of manganese nodules

    International Nuclear Information System (INIS)

    The present paper describes the development of a new nuclear method that allows rapid determinations of the most relevant metals Ni and Cu without sample treatment, thus being particularly suited for quasi-continuous elemental analyses in mining and processing. The measurement is based on fast-neutron activation using Cockcroft-Walton generators, sealed neutron tubes or, possibly, (α,n)-type natural sources. Fast-neutron activation of manganese nodules is dominated by the (n,p)-reactions on Si, Al, Fe; the (n,α)-reaction on Mn and the (n,2n)-reaction on Cu. By choosing appropriate irradiation and cooling periods gamma-ray activities with comparatively simple spectral distributions are induced. From these spectra the Mn/Fe ratio in the nodules can be determined without the elaborate procedures usually required in absolute methods for eliminating systematic errors from fluctuations in sample and/or irradiation parameters. It is connected with the absolute Ni and Cu contents via well-known geochemical correlations which according to a lot of statistical data apply to quite different deposits and nodule types in the Pacific. Using these correlations the determination of the most important metals reduces to the evaluation of a peak area ratio. Measurements of the neutron flux distribution and the apparent sample density are unnecessary. The simple structure of the spectra allows the application of detectors with modest energy resolution, e.g. scintillation counters which can be manufactured as ruggedized crystal assemblies with great resistance to thermal and mechanical shock. The method is described in detail and possible interference, in particular from thermal and epithermal neutrons, are discussed. (orig.)

  4. Elemental analysis of airborne particulate by using thermal and epithermal neutron activation

    International Nuclear Information System (INIS)

    Thermal neutron activation analysis was used to determine Al, Br, Ca, Cl, Mn, Na, V, and Ti concentrations, whereas epithermal neutron activation analysis was used to determine Cu, I and Si concentrations. Counting by Compton suppression both in thermal neutron activation and epithermal neutron activation analysis showed the significantly different on detection limit of element compare with normal counting system. It revealed counting by Compton suppression gave better result. The enrichment factor of elements indicated that V and Mn were enriched in several fine particulate samples. Ca, Si and Na were not enriched, whereas Br, I and Cl were enriched in fine airborne particulate or in coarse one. It was found that Cl and Na did not have correlation, while Br and I showed the same enrichment the same enrichment trend and high correlation (0,9). It means that Br and I were from the same pollutant source. It could concluded that the thermal neutron and epithermal neutron activations analysis combined with counting by Compton suppression could enhance sensitivity of analysis of elemental air bone particulate that was very useful in air pollution study. Key words : activation analysis, thermal neutron, epithermal neutron, Compton

  5. Present status of neutron activation analysis in environmental research

    International Nuclear Information System (INIS)

    Neutron activation analysis, in spite of its many advantageous features, is less widely used than some alternative trace element techniques, and has been losing ground during the last decade. In the environmental field however there are still many problems which can be solved in a better way by the contribution of NAA. The combination of multi-element capability and high accuracy is of great importance in many studies related to atmospheric trace elements. Also in aquatic studies NAA still has a significant role to play. Applications to soils, sediments, and plant material have so far been limited, but there is a place for further development. The scope of NAA in environmental research may be extended by further use of pre-irradiation separations. NAA is particularly important in the certification of analytical reference materials in the environmental field. In future applications of NAA an appropriate combination with other analytical techniques will often be a requisite for success. The general future of NAA is dependent on the availability of nuclear reactors, radiochemical laboratoties and appropriate competence. 21 references

  6. Intrinsic quality assurance aspects of neutron activation analysis

    International Nuclear Information System (INIS)

    Full text: Neutron activation analysis (NAA) is an extremely valuable tool for the certification of Certified Reference Materials (CRMs) for a number of reasons. First, the method itself has characteristics that inherently provide few sources of error compared to many other analytical techniques. In addition, the intrinsic quality assurance characteristics of the method often allow the analytical values to be internally evaluated and cross checked. For example, most spectroscopic techniques separate the signals of the different excited species (analytes and interferences) by a single parameter, i.e. energy, mass, wavelength, time, etc. NAA can separate the signals of excited species (radionuclides) via two different parameters, energy and time (half-life). The ability to perform gamma ray spectrometry on the same sample after different decay times often provides the capability of verifying the absence of many sources of error such as interferences, incorrect pileup corrections, incorrect dead-time corrections, use of an erroneous half-life, etc. In addition, quantification using multiple gamma rays of the same isotope, and in some cases entirely different isotopes of the same element, can provide a powerful tool to minimize the possibility of errors due to interferences. Finally, counting both samples and standards at multiple geometries can provide insight into the importance of counting geometry effects. This presentation will describe ways to take advantage of some of the unique QA characteristics of Naca to observe and eliminate a number of potential sources of error. (author)

  7. Instrumental neutron activation analysis. A valuable link in chemical metrology

    International Nuclear Information System (INIS)

    A systematic experimental approach to the demonstration of viability of instrumental neutron activation analysis (INAA) in chemical metrology is provided. The practical approach was derived from a complete survey of uncertainty components that affect the INAA measurement process. These uncertainty components were classified by their magnitude and origin and subsequently minimized by appropriate steps in the INAA process. The process was tested with the INAA determination of Cr in SRM 1152A stainless steel; the Cr value is certified at 17.76% with an estimated uncertainty of 0.04% (0.23% relative). The INAA results from this procedure are in agreement with these specifications. Similar procedures have been applied to INAA multi-element determinations in a high temperature alloy. Agreement with available consensus values was demonstrated in the alloy. The guidelines on the determination of uncertainty were fully met, providing through INAA a valuable independent non-destructive tool in chemical measurements of metrological value such as required in the CCQM key comparisons. (author)

  8. Essential trace elements in edible mushrooms by Neutron Activation Analysis

    Energy Technology Data Exchange (ETDEWEB)

    Moura, Patricia L.C.; Maihara, Vera A.; Castro, Lilian P. de [Instituto de Pesquisa e Energetica e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)]. E-mail: patricialandim@ig.com.br; vmaihara@ipen.br; lilian.Pavanelli@terra.com.br; Figueira, Rubens C.L. [Universidade Cruzeiro do Sul, Sao Paulo, SP (Brazil)]. E-mail: figueiraru@yahoo.com.br

    2007-07-01

    Mushrooms are excellent nutritional sources since they provide proteins, fibers and mineral, such as K, P, Fe. They have also been the focus of medical research. In Brazil mushrooms are not consumed in large quantities by the general population since people know little about the nutritional and medicinal benefits that mushrooms offer. Hence, this study intends to contribute to a better understanding of the essential element content in edible mushrooms, which are currently commercialized in Sao Paulo state. Br Fe, K, Na and Zn concentrations were determined by Instrumental Neutron Activation Analysis in the following mushroom species: Shitake (Lentinus edodes), Shimeji (Pleurotus ssp), Paris Champignon (Agaricus bisporus), Hiratake ( Pleurotus ssp) and Eringue (Pleurotus Eryngu. The mushroom samples were acquired from commercial establishments in the city of Sao Paulo and directly from the producers. Essential element contents in mushrooms varied between Br 0.03 to 4.1 mg/kg; Fe 20 to 267 mg/kg; K 1.2 to 5.3 g/kg, Na 10 to 582 mg/kg and Zn 60 to 120 mg/kg. The results confirm that mushrooms can be considered a good source of K, Fe and Zn. The low Na level is a good nutritional benefit for the consumer. (author)

  9. Study of nutritional supplements using neutron activation analysis

    International Nuclear Information System (INIS)

    The increasing consumption of nutritional supplements among the people mainly aiming at the replacement of nutrients and minerals in the organism has led the commercialization of a great number of brands of these products. Consequently the quality control of these products is of great interest to verify if their element contents agree the values presented in labels or in the instructions for their uses. In this study the elements Ca, Co, Cr, Cu, Fe, K, Na, Se and Zn were analyzed in multimineral supplements and vitamins samples using neutron activation analysis method. The results obtained compared with the values of the labels of nutritional supplements presented good agreement. For quality control of the analytical data, certified reference materials NIST 1400 Bone Ash and NIST 1633b Coal Fly Ash provided by National Institute of Standards and Technology were analysed. Accuracy and precision of the results were evaluated and Z score values obtained were lower than 2 indicating that the data found are within the certified values at 95% of significance level. (author)

  10. Neutron activation analysis and provenance study of Tupiguarani Tradition pottery

    International Nuclear Information System (INIS)

    Archaeology can fill the gap between ancient population and modern society elucidating the evidences found in archaeological sites. The fingerprint identified, that is the chemical composition of the ceramics, can help understanding this connection between the past and the present. The Tupiguarani Tradition vestiges found by archaeologists will be a way to know about the last two millennia of the Brazilian prehistory. This archaeological site is located along the coast of the Brazilian State of Espirito Santo, where the main evidence is a pretty ceramic with the occurrence of plastic and painted decoration. When the Portuguese settlers arrived in this region, in sixteenth century, several Missoes Jesuiticas (Jesuitical Missions) were built along the Brazilian coast. In spite of living within the Mission and been catechized, the Indians kept on producing traditional handicraft, as the decorated ceramic, however, they introduced European elements to the decoration. During the research expeditions made to the archaeological site of the Tupiguarani Tradition, many sherds were found. The identification and classification of ceramics through a multielemental chemistry analysis will be used to determine if they have the same origin. This paper shows the first elemental concentration results of the sherds collected from archaeological site determined at CDTN/CNEN, Belo Horizonte, Minas Gerais, using the TRIGA Mark I IPR-R1 nuclear reactor, applying the neutron activation technique, k0-method. (author)

  11. Residual Chromium in Leather by Instrumental Neutron Activation Analysis

    Directory of Open Access Journals (Sweden)

    S. Okoh

    2012-01-01

    Full Text Available Problem statement: Most tanning processes employ the use of chromium sulphate. For chromium tanned leather, finished products may contain high amount of residual chromium. This may pose some health hazards, since chromium is known to be toxic at elevated concentration. This justifies the need for the study. Approach: Various samples of leather were collected from a tannery, a leather crafts market, a leather dump site and from local tanners all in Kano, Nigeria in 2009. The samples were irradiated for 6 h in the inner site of the Nigerian Research Reactor (NIRR-1 at a flux of 5×1011 ncm-2 sec-1. Results: After evaluating the spectrum, the mean results for chromium in the samples were determined as 2.33±0.3, 2.23±0.3 and 2.93±0.4% for samples from the tannery, leather crafts market and leather dump sites respectively. Chromium concentration in samples collected from local tanners who use tannins from Acacia nilotica as tanning agent was below the detection limit of Instrumental Neutron Activation Analysis (INAA technique used in the study. Conclusion: Although, the concentrations of chromium in the analysed samples were not much higher than what were obtained in literature, they may be enough to sensitize the population that is allergic to chromium.

  12. Instrumental neutron activation analysis of prehistoric and ancient bone remains

    International Nuclear Information System (INIS)

    Instrumental neutron activation analysis (INAA) was used to study the element contents in bones of prehistoric dinosaurs and bones of an ancient bear and an archantrop (ancient person), which were found on the territory of Uzbekistan. Concentrations of more than 25 elements were in the range of 0.043-3600 mg/kg. Multielement analyses of bone and soil samples were carried out by INAA using the WWR-SM research nuclear reactor. Results of measurements have shown that in the dinosaurs bones the concentration of the rare earth elements (REEs) were within 280-3200 mg/kg; the uranium content reached a very high value, up to 180 mg/kg, while in soils coating the dinosaurs bones this content was 4.2 mg/kg; in the bones of the archantrop it was 1.53 mg/kg and in the bones of a standard person its amount is less than 0.016 mg/kg. (author)

  13. Neutron activation analysis and provenance study of Tupiguarani Tradition pottery

    Energy Technology Data Exchange (ETDEWEB)

    Faria, Gleikam Lopes de Oliveira [Centro de Desenvolvimento da Tecnologia Nuclear (CDTN/ CNEN-MG), Belo Horizonte, MG (Brazil). Curso de Mestrado em Ciencia e Tecnologia das Radiacoes, Minerais e Materiais], e-mail: gleikam@yahoo.com.br; Menezes, Maria Angela de B.C. [Centro de Desenvolvimento da Tecnologia Nuclear (CDTN/ CNEN-MG), Belo Horizonte, MG (Brazil). Servico de Reator e Tecnicas Analiticas. Lab. de Ativacao Neutronica], e-mail: menezes@cdtn.br; Ribeiro, Loredana; Jacome, Camila [Cooperativa dos Empreendedores em Acoes Culturais - COOP. CULTURA, Belo Horizonte, MG (Brazil). Lab. de Arqueologia], e-mail: loredana.ribeiro@gmail.com

    2009-07-01

    Archaeology can fill the gap between ancient population and modern society elucidating the evidences found in archaeological sites. The fingerprint identified, that is the chemical composition of the ceramics, can help understanding this connection between the past and the present. The Tupiguarani Tradition vestiges found by archaeologists will be a way to know about the last two millennia of the Brazilian prehistory. This archaeological site is located along the coast of the Brazilian State of Espirito Santo, where the main evidence is a pretty ceramic with the occurrence of plastic and painted decoration. When the Portuguese settlers arrived in this region, in sixteenth century, several Missoes Jesuiticas (Jesuitical Missions) were built along the Brazilian coast. In spite of living within the Mission and been catechized, the Indians kept on producing traditional handicraft, as the decorated ceramic, however, they introduced European elements to the decoration. During the research expeditions made to the archaeological site of the Tupiguarani Tradition, many sherds were found. The identification and classification of ceramics through a multielemental chemistry analysis will be used to determine if they have the same origin. This paper shows the first elemental concentration results of the sherds collected from archaeological site determined at CDTN/CNEN, Belo Horizonte, Minas Gerais, using the TRIGA Mark I IPR-R1 nuclear reactor, applying the neutron activation technique, k{sub 0}-method. (author)

  14. Inorganic constituents in herbal medicine by neutron activation analysis

    International Nuclear Information System (INIS)

    The demand for herbal medicines is growing worldwide. The expansion of interest has required the standardization of the sector with implementation and constant review of technical standards for production and marketing of these medicines in order to ensure the safe use, therapeutic efficacy and quality of the products. According to data from the World Health Organization, approximately 80% of world population has resorted to the benefits of certain herbs with therapeutic action popularly recognized. Despite the vast flora and the extensive use of medicinal plants by the population, it is a consensus that scientific studies on the subject are insufficiency. Therefore, it is necessary to stimulate such studies in view of the importance of the results of both individual and social field. The determination of major, minor and trace elements and the research of metabolic processes and their impacts on human health are of great importance due to the growth of environmental pollution that directly affects the plants and therefore the phytotherapics. Therefore, the objective of this work was to determine the content of inorganic constituents in herbal medicine: moisture, total ash and the elements As, Ba, Br, Ca, Cs, Co, Cr, Fe, Hf, K, Na, Rb, Sb, Sc, Se, Ta, Th, U, Zn and Zr by neutron activation analysis in order to verify the quality of the products. It was observed that the elemental concentrations varied in a wide range from plant to plant and elements with higher concentrations were Ba, Fe, Cr and Zn. (author)

  15. Elementary concentration of Peruibe black mud by neutron activation analysis

    International Nuclear Information System (INIS)

    The Peruibe Black Mud is used in therapies such as psoriasis, peripheral dermatitis, acne, seborrehea, myalgia arthritis and rheumatic non-articular processes. This material is characterized by is fine organic matter particles, sulphate reducing bacteria and a high content of potential reduction ions. Although this material is particles, sulphate reducing bacteria and a high content of potential reduction ions. Although this material is considered natural, it may not be free of possible adverse health effects, like toxic chemical elements, when used for therapeutic purposes. In the therapeutic treatments involving clays, clays are used in mud form also called peloids, obtained by maturation process. Five in natura and three maturated Black Mud samples were collected in Peruibe city, Sao Paulo State, Brazil. To investigate the distribution of major, trace and rare earth elements in the in natura and maturated clays that constitute the Peruibe Black Mud, neutron activation analysis (NAA) was used. A comparison between in natura and maturated mud shows that major, trace and rare earth elements follow the same order in both types. Generally, the concentrations in the maturated mud are slightly lower than in natura mud. Enrichment on the upper continental crust could be observed for the elements As, Br, Sb and Se, in these types of mud. (author)

  16. Essential trace elements in edible mushrooms by Neutron Activation Analysis

    International Nuclear Information System (INIS)

    Mushrooms are excellent nutritional sources since they provide proteins, fibers and mineral, such as K, P, Fe. They have also been the focus of medical research. In Brazil mushrooms are not consumed in large quantities by the general population since people know little about the nutritional and medicinal benefits that mushrooms offer. Hence, this study intends to contribute to a better understanding of the essential element content in edible mushrooms, which are currently commercialized in Sao Paulo state. Br Fe, K, Na and Zn concentrations were determined by Instrumental Neutron Activation Analysis in the following mushroom species: Shitake (Lentinus edodes), Shimeji (Pleurotus ssp), Paris Champignon (Agaricus bisporus), Hiratake ( Pleurotus ssp) and Eringue (Pleurotus Eryngu. The mushroom samples were acquired from commercial establishments in the city of Sao Paulo and directly from the producers. Essential element contents in mushrooms varied between Br 0.03 to 4.1 mg/kg; Fe 20 to 267 mg/kg; K 1.2 to 5.3 g/kg, Na 10 to 582 mg/kg and Zn 60 to 120 mg/kg. The results confirm that mushrooms can be considered a good source of K, Fe and Zn. The low Na level is a good nutritional benefit for the consumer. (author)

  17. Neutron activation analysis of lipsticks using gamma-ray spectrometry

    International Nuclear Information System (INIS)

    Neutron activation analysis with gamma-ray spectrometry was used to measure the concentrations of various elements in lipsticks of popular Indian and foreign brands. The aim of the present work was to study the possibility of existence of trace elements in samples of lipsticks (the ingredients of which are mostly organic in nature) and to see whether trace elements could distinguish lipsticks of different Indian and foreign brands from the forensic point of view apart from their inter-se differentiation. In the different samples of lipsticks that were analysed the following elements were detected: Au, Ba, Br, Ca, Cs, Fe, Na, Ru, Sb, Sc, Ta, Yb, Zn, Rb and Se. It was found that inter-se differentiation of lipsticks was possible on the basis of concentrations of trace elements and their profile. Concentration of bromine in samples of lipsticks identified lipsticks of different Indian brands. Samples of lipsticks of Indian and foreign brands could be differentiated on the basis of concentrations of cesium, antimony and scandium which were found to be higher in foreign brands as compared to those in Indian brands. (authors)

  18. Elementary concentration of Peruibe black mud by neutron activation analysis

    Energy Technology Data Exchange (ETDEWEB)

    Torrecilha, Jefferson K.; Ponciano, Ricardo; Silva, Paulo S.C da, E-mail: jeffkoy@ipen.br [Instituto de Pesquisas Energeticas e Nucleares (IPEN-CNEN/SP), Sao Paulo, SP (Brazil)

    2013-07-01

    The Peruibe Black Mud is used in therapies such as psoriasis, peripheral dermatitis, acne, seborrehea, myalgia arthritis and rheumatic non-articular processes. This material is characterized by is fine organic matter particles, sulphate reducing bacteria and a high content of potential reduction ions. Although this material is particles, sulphate reducing bacteria and a high content of potential reduction ions. Although this material is considered natural, it may not be free of possible adverse health effects, like toxic chemical elements, when used for therapeutic purposes. In the therapeutic treatments involving clays, clays are used in mud form also called peloids, obtained by maturation process. Five in natura and three maturated Black Mud samples were collected in Peruibe city, Sao Paulo State, Brazil. To investigate the distribution of major, trace and rare earth elements in the in natura and maturated clays that constitute the Peruibe Black Mud, neutron activation analysis (NAA) was used. A comparison between in natura and maturated mud shows that major, trace and rare earth elements follow the same order in both types. Generally, the concentrations in the maturated mud are slightly lower than in natura mud. Enrichment on the upper continental crust could be observed for the elements As, Br, Sb and Se, in these types of mud. (author)

  19. Neutron activation analysis: A primary method of measurement

    Science.gov (United States)

    Greenberg, Robert R.; Bode, Peter; De Nadai Fernandes, Elisabete A.

    2011-03-01

    Neutron activation analysis (NAA), based on the comparator method, has the potential to fulfill the requirements of a primary ratio method as defined in 1998 by the Comité Consultatif pour la Quantité de Matière — Métrologie en Chimie (CCQM, Consultative Committee on Amount of Substance — Metrology in Chemistry). This thesis is evidenced in this paper in three chapters by: demonstration that the method is fully physically and chemically understood; that a measurement equation can be written down in which the values of all parameters have dimensions in SI units and thus having the potential for metrological traceability to these units; that all contributions to uncertainty of measurement can be quantitatively evaluated, underpinning the metrological traceability; and that the performance of NAA in CCQM key-comparisons of trace elements in complex matrices between 2000 and 2007 is similar to the performance of Isotope Dilution Mass Spectrometry (IDMS), which had been formerly designated by the CCQM as a primary ratio method.

  20. Neutron activation analysis of human hair and health

    International Nuclear Information System (INIS)

    Full text: Periodically increasing and decreasing enthusiasm has accompanied the studies of medical significance of human hair elemental composition for at least two decades. In this field, nuclear analytical methods play an extremely important role, especially the instrumental neutron activation analysis (INAA). This paper tries to add some new knowledge to this problem. There were collected and analyzed hair samples from 2 500 practically healthy inhabitants of Uzbekistan. This allowed to estimate average concentrations of elements and intervals of concentration for normal population. Average data for 11 regions of Uzbekistan were compared with medical statistics data for these regions. There were found significant correlations for some diseases. In addition were found correlations in world wide scale. These data and previously obtained data in clinical conditions allowed to elaborate algorithm of estimation of health status according to human hair elemental composition. Reliability for many cases was very high. This allows to focus for more detailed diagnostic procedures and measures for the body elemental status correction

  1. Determination of gold in some Myanmar indigenous medicines by neutron activation analysis

    International Nuclear Information System (INIS)

    Gold has been determined in two Myanmar indigenous medicines TMF 14 (Devaauthada), TMF 15 (Shwe Thwe Say) by neutron activation analysis using an Am(Be) radionuclide neutron source. The activity of 411 keV of the 198Au has been measured. (author). 2 refs., 1 fig., 1 tab

  2. Use of a 14 MeV neutron generator for activation analysis

    International Nuclear Information System (INIS)

    An overview of applications of the IPEN 14 MeV neutron generator is given. The generator was in active use, for neutron activation analysis, until middle of 1991 when a major breakdown caused serious damage to the vacuum system. (author)

  3. Neutron activation analysis as analytical tool of environmental issue

    International Nuclear Information System (INIS)

    Neutron activation analysis (NAA) ia applicable to the sample of wide range of research fields, such as material science, biology, geochemistry and so on. However, respecting the advantages of NAA, a sample with small amounts or a precious sample is the most suitable samples for NAA, because NAA is capable of trace analysis and non-destructive determination. In this paper, among these fields, NAA of atmospheric particulate matter (PM) sample is discussed emphasizing on the use of obtained data as an analytical tool of environmental issue. Concentration of PM in air is usually very low, and it is not easy to get vast amount of sample even using a high volume air sampling devise. Therefore, high sensitive NAA is suitable to determine elements in PM samples. Main components of PM is crust oriented silicate, and so on in rural/remote area, and carbonic materials and heavy metals are concentrated in PM in urban area, because of automobile exhaust and other anthropogenic emission source. Elemental pattern of PM reflects a condition of air around the monitoring site. Trends of air pollution can be traced by periodical monitoring of PM by NAA method. Elemental concentrations in air change by season. For example, crustal elements increase in dry season, and sea salts components increase their concentration when wind direction from sea is dominant. Elements that emitted from anthropogenic sources are mainly contained in fine portion of PM, and increase their concentration during winter season, when emission from heating system is high and air is stable. For further analysis and understanding of environmental issues, indicator elements for various emission sources, and elemental concentration ratios of some environmental samples and source portion assignment techniques are useful. (author)

  4. Instrumental neutron-activation analysis of geological samples for rare earths using internal standard method

    International Nuclear Information System (INIS)

    Full text: Instrumental neutron-activation analysis os one of a few modern analytical techniques, being applied to solve difficult analytical tasks, such as mineral resources analysis for rare earth element content. No other analytical technique can be used with the latter end in view, since Instrumental neutron-activation analysis is possessed of the highest precision among them. In order to check experimentally the stated approach to REE content calculation by the internal standard method, relative bias values of this approach should be estimated. This approach will be verified further with a number of different rock samples simultaneously analyzed by an instrumental neutron-activation analysis certified analytical technique

  5. First research coordination meeting on reference database for neutron activation analysis. Summary report

    International Nuclear Information System (INIS)

    Potential problems associated with nuclear data for neutron activation analysis were identified, the scope of the work to be undertaken was defined together with its priorities, and tasks were assigned to participants. Data testing and measurements refer to gamma spectrum peak evaluations, detector efficiency calibration, neutron spectrum characteristics and reference materials analysis. (author)

  6. Neutron activation analysis challenges. Problems and applications in biomedical and other areas

    International Nuclear Information System (INIS)

    Developments in neutron activation analysis in its various modes for trace element determination are described with reference to reactor and other neutron sources, competing methods, tomography and detection systems. A selected number of areas of application are highlighted which provide challenges into the next millennium and to which a useful and in some cases a unique contribution can be made. The role that neutron activation analysis can play in decommissioning, landmine detection, boron neutron capture therapy, Alzheimer's disease, diabetes mellitus, the complex mechanisms of initiation and termination of feeding and obesity as well as in scar formation and the requirements for artificial skin are presented. (author)

  7. Neutron activation analysis challenges: Problems and applications in biomedical and other areas

    International Nuclear Information System (INIS)

    Developments in neutron activation analysis in its various modes for trace element determination are described with reference to reactor and other neutron sources, competing methods, tomography and detection systems. A selected number of areas of applications are highlighted which provide challenges into the next millennium and to which a useful and in some cases a unique contribution can be made. The role that neutron activation analysis can play in decommissioning, land mine detection, born neutron capture therapy, Alzheimer disease, diabetes mellitus, the complex mechanisms of initiation and termination of feeding and obesity as well as in scar formation and the requirements for artificial skin are presented. (author)

  8. Neutron activation analysis in the investigation of pseudomonas to mercury

    International Nuclear Information System (INIS)

    The aim of this work was to investigate the resistance to mercury in Pseudomonas. The measurements were performed by using neutron activation technique. The TRIGA MARK 1-IPE-R1 reactor was used as the irradiation facility, and the nuclide Hg202 as target element. The experimental results showed that cultures of Pseudomonas during the logarithmic growing phase, have a significant volatilization of the Hg, while during the stationary phase, they absorb and retain this metal. (author)

  9. The use of neutron activation analysis in environmental pollution studies

    International Nuclear Information System (INIS)

    Environmental samples and localized species from a marine environment, water samples for public drinking, sediment core samples from a polluted marine environment, soil samples from tin-tailing dump sites, air particulate matter and leachates from landfills were analyzed for their trace, toxic elemental contents, chemical species and natural radioactivity in an attempt to assess the safety levels of these pollutants in these matrices by means of instrumental neutron activation analysis (INAA) and other related nuclear techniques. Complementary techniques such as the graphite furnace atomic absorption spectrometry (GFAAS), ICP-MS, ion chromatography and pre-concentration steps particularly in the speciation studies were also incorporated in these studies for specific elemental determinations prior to irradiation in a neutron flux of about 5.1 x 108 n.m-2.s-1 from a TRIGA Mk.II reactor. Pre-concentration of the chemical species of As and Se was done using a mixture of ammonium pyrrolidinethiocarbamatechloroform (APDTC-CHCl3) while activated carbon derived from agricultural wastes was used in the iodine speciation. Some of the specific chemical species have to be separated prior to the final quantitative determination to reduce interference and enhance the sensitivity of the INAA technique. These include arsenic, selenium and iodine species present in various matrices. The more toxic inorganic arsenic, selenium, iodine and a host of other trace elements were detected in these samples by quantifying their respective γ-rays emitted from the radioisotopes. The amounts of As(III) present vary from about 1.8 ng/g to 15.5 ng/g in localized marine species, 0.1 ng/g to more than 5.0 ng/g in treated public drinking water while the more toxic inorganic Se (IV) is present in the range of 1.5 μg/L to about 4.5 μg/L. The distribution patterns of pollutants were presented on maps and deductions were made from these patterns to address pollution issues. Results obtained from the

  10. A software architectural framework specification for neutron activation analysis

    International Nuclear Information System (INIS)

    Neutron Activation Analysis (NAA) is a sensitive multi-element nuclear analytical technique that has been routinely applied by research reactor (RR) facilities to environmental, nutritional, health related, geological and geochemical studies. As RR facilities face calls to increase their research output and impact, with existing or reducing budgets, automation of NAA offers a possible solution. However, automation has many challenges, not the least of which is a lack of system architecture standards to establish acceptable mechanisms for the various hardware/software and software/software interactions among data acquisition systems, specialised hardware such as sample changers, sample loaders, and data processing modules. This lack of standardization often results in automation hardware and software being incompatible with existing system components, in a facility looking to automate its NAA operations. This limits the availability of automation to a few RR facilities with adequate budgets or in-house engineering resources. What is needed is a modern open system architecture for NAA, that provides the required set of functionalities. This paper describes such an 'architectural framework' (OpenNAA), and portions of a reference implementation. As an example of the benefits, calculations indicate that applying this architecture to the compilation and QA steps associated with the analysis of 35 elements in 140 samples, with 14 SRM's, can reduce the time required by over 80 %. The adoption of open standards in the nuclear industry has been very successful over the years in promoting interchangeability and maximising the lifetime and output of nuclear measurement systems. OpenNAA will provide similar benefits within the NAA application space, safeguarding user investments in their current system, while providing a solid path for development into the future. (author)

  11. Instrumental neutron activation analysis, a valuable link in chemical metrology

    International Nuclear Information System (INIS)

    Instrumental neutron activation analysis (INAA) is sufficiently versatile to establish a direct link to the amount of substance determined. The inherent quality parameters of INAA, such as being virtually free of blank, having fully accountable effects of matrix and physical form, and operating over a huge range of amounts, allows the comparison of a mole (or its fraction) of a pure element with the amount of substance in the sample analyzed with the same direct relationship as a beam balance provides. Indeed, varieties of this approach are in common use in INAA in the comparator methods of quantitation. To eliminate possible perturbations of the traceability chain as they may occur in common INAA practice, experimental measurements have been set up that only involve the fraction of a mole of the element(s) of interest in form of the pure element, compound or certified standard and the unknown sample. This principle has been used in INAA measurements for certification value assignment of high temperature alloy SRMs. To further demonstrate the performance parameters of INAA, we selected the determination of chromium in SRM 1152a Stainless Steel by direct non-destructive comparison with the pure metal in form of crystalline chromium. The measurements were validated with weighed aliquots of SRM 3112a dried on filter paper pellets. The experimental results do not show deviations beyond the uncertainties of the SRMs (≤ 0.2 % relative), and the assessment of the uncertainty budget indicates that expanded uncertainties of ≤ 0.3 % are achievable. The measurements demonstrate that INAA can meet the CCQM definition of a primary ratio method of analysis

  12. Characterization of hydrogen in concrete by cold neutron prompt gamma-ray activation analysis and neutron incoherent scattering

    Energy Technology Data Exchange (ETDEWEB)

    Paul, R.L.; Chen-Mayer, H.H.; Lindstrom, R.M.; Blaauw, M.

    2000-07-01

    A combination of cold neutron prompt gamma-ray activation analysis (PGAA) and neutron incoherent scattering (NIS) has been used for nondestructive characterization of hydrogen as a function of position in slabs of wet concrete of different composition. Hydrogen was determined by PGAA by scanning each sample across of 5 mm diameter neutron beam in 10 mm increments, and measuring the 2223 keV prompt gamma ray. NIS measurements were performed by scanning the samples across a 5 mm diameter neutron beam at 5 mm increments and detecting scattered neutrons. The measurements demonstrate the feasibility of the techniques for 2D compositional mapping of hydrogen and other elements in materials, and indicate the potential of these methods for monitoring the uniformity of drying concrete.

  13. The influence of an additional filter in epithermal neutron activation analysis

    International Nuclear Information System (INIS)

    Additional filters of tungsten and sodium in different thicknesses have been used in the epithermal neutron activation analysis of geological samples to reduce the interferences caused by resonance neutron capture in these two elements. The results show that a selective reduction of the interfering activities in favor of the activities sought can be obtained. Improvements in terms of detection sensitivity and precision in the γ-spectrometric determinations of Sc, Fe, Co, La, Sm, Eu, Gd, Tb, Yb, Lu, Th and W have been calculated. The possible applications of the filtered epithermal neutron activation analysis (FENA) method to different kinds of samples are also briefly discussed. (author)

  14. Determination of oxygen content in steel using activation analysis with 14 MeV neutron

    International Nuclear Information System (INIS)

    In the quantitative analysis of oxygen in steel by fast neutron activation analysis the oxygen content is evaluated from the measured activity of 16N produced. Steel s mples are irradiated in 14 MeV neutron flux. After irradiation the samples are pneumatically transfered to the counting terminal where activity is measured. Oxygen concentrations, are obtained by comparison with standards of specified oxygen content

  15. Evaluation of new pharmaceuticals using in vivo neutron inelastic scattering and neutron activation analysis

    International Nuclear Information System (INIS)

    Nutritional status of patients can be evaluated by monitoring changes in body composition, including depletion of protein and muscle, adipose tissue distribution and changes in hydration status, bone or cell mass. Fast neutron activation (for N and P) and neutron inelastic scattering (for C and O) are used to assess in vivo elements characteristic of specific body compartments. The fast neutrons are produced with a sealed deuterium-tritium (D-T) neutron generator. This method provides the most direct assessment of body composition. Non-bone phosphorus for muscle is measured by the 31P(n,α)28Al reaction, and nitrogen for protein via the (n,2n) fast neutron reaction. Inelastic neutron scattering is used for the measurement of total body carbon and oxygen. Carbon is used to derive body fat, after subtracting carbon contributions due to protein, bone and glycogen. Carbon-to-oxygen (C/O) ratio is used to measure distribution of fat and lean tissue in the body and to monitor small changes of lean mass and its quality. In addition to evaluating the efficacy of new treatments, the system is used to study the mechanisms of lean tissue depletion with aging and to investigate methods for preserving function and quality of life in the elderly. (author)

  16. Simultaneous multielement speciation analysis in food using neutron activation

    International Nuclear Information System (INIS)

    Complete text of publication follows. We develop various forms of neutron activation analysis (NAA) methods for the simultaneous determination of multielement concentrations in biological and environmental materials. Although NAA has traditionally been applied to measuring the total concentrations of elements, the scope of NAA can be further extended in conjunction with chemical separations prior to irradiations to determine the species of an element. This technique is then called simultaneous speciation NAA (SSNAA). Almost all speciation techniques consist of two steps. The first step involves the separation of species from the sample followed by the second step of element-specific detection. A number of characteristic features of NAA, which other techniques normally do not possess, can be advantageously exploited in SSNAA. For example, SSNAA can be used for: (i) simultaneous multielement speciation with high specificity, (ii) speciation of elements which are not chemically similar such as Cd, Mn and Se, (iii) speciation of elements such as Cl, Br and I which are rather difficult to determine by most other techniques, etc. The SSNAA technique has some unique quality assurance features. We have developed SNAA methods for assaying various arsenic species in water and in foods of marine origin, and then SSNAA to include simultaneous speciation of As, Sb and Se. We have developed SSNAA methods for the characterization of organohalogen species in fish and milk samples. We have also developed SSNAA methods employing biochemical techniques for the simultaneous separation, preconcentration and characterization of metalloproteins and protein-bound trace element species of As, Br, Cd, Cu, Mn, Se and Zn. An overview of the SSNAA methods being developed in our laboratory will be presented.

  17. Analysis of elements present in beers and brewing waters by neutron activation analysis

    International Nuclear Information System (INIS)

    Neutron activation analysis (NAA) was used for determination of Si, Na, K, Ca, Sc, V, Cr, Mn, Fe, Co, Zn, Rb, Cs, and La in Czech beers and brewing waters. The Si concentration in beer determined by the reaction 29Si(n,p)29Al with fast neutrons confirmed that beer is an important Si source in human diet. Determination of other trace elements by NAA with the whole spectrum of reactor neutrons aimed at the feasibility of identification of Gambrinus beers brewed in various breweries. The elements Ca and V appeared to be the best candidates for this purpose. The concentrations of elements determined by NAA were also compared with the recommended daily element intake for humans. The accuracy of the method was proved by analysis of reference materials, specifically NIST SRM 2704 Buffalo River Sediment, NIST SRM 1633b Coal Fly Ash, and NIST SRM 1515 Apple Leaves. (author)

  18. Applications of neutron activation analysis in chemistry and pollution fields

    International Nuclear Information System (INIS)

    Some examples of applications of activation analysis are given such as: chemical analysis of precious metals, nuclear graphite and hydrocarbons; control of pollution of water and seawater, analysis of food and seafood, atmospheric, dust and hair for determination of impurities

  19. Nitrogen determination in wheat by neutron activation analysis using fast neutron flux from a thermal nuclear reactor

    International Nuclear Information System (INIS)

    This is a study of the technique for the determination of nitrogen and other elements in wheat flour through activation analysis with fast neutrons from a thermal nuclear reactor. The study begins with an introduction about the basis of the analytical methods, the equipment used in activation analysis and a brief description of the neutrons source. In the study are included the experiments carried out in order to determine the flux form in the site of irradiation, the N-13 half life and the interference due to the sample composition. (author)

  20. Elemental analysis of rain- and fresh water by neutron activation analysis

    International Nuclear Information System (INIS)

    Analysis of rain-and fresh water for trace constituents is a mandatory part of environmental monitoring. This text gives a survey of neutron activation analysis (NAA) within the framework of current environmental water research programmes, based on the practice developed in co-operation with the Dutch Energy Research Centre at Petten (ECN). While the procedures reported in literature cover about thirty five elements, The routine procedures of instrumental neutron activation analysis (INAA) is limited to ten to fifteen elements. The use of some dedicated radiochemical separations (RNAA) adds another six, some of which are speciated as well. Current contributions of NAA to water analysis center on determination and speciation of anionic trace elements, notably Br, I, As and Se on the assay of some ultra traces like Ag, Au and Hg and on validation

  1. Determination of zinc by substoichiometric thermal neutron activation analysis (Paper No. RA-23)

    International Nuclear Information System (INIS)

    Trace amount of Zn in complex matrices has been determined by substoichiometric thermal neutron activation analysis. The method involves radiochemical separation of 65Zn from neutron irradiated samples employing substoichiometric extraction of Zn(II) with 1,2,3-benzotriazole (1,2,3-BT) into n-heptanol. (author). 1 tab

  2. Possibilities of Controlling Nutritious Wheat Flour by the Method of Neutron Activation Analysis

    International Nuclear Information System (INIS)

    Possibilities of controlling nutritious wheat flour by the method of neutron activation analysis are studied. It is established, that detection of contents of As, Cd, Hg, Cu and Zn in wheat flour is possible using this method and a neutron multiplier. The results of measurements were worked out by polycomparative method. (author)

  3. Neutron activation analysis of toxic elements in meat and farinaceous food of Argentina

    International Nuclear Information System (INIS)

    Quantitative information about the concentration of toxic elements in foodstuffs for human consumption is important for the study of human health and diseases. Our project is to analyze, by neutron activation, toxic elements im meat and farinaceous food of Argentina by means of: a) Radiochemical neutron activation analysis with development of an adequate technique for the determination of As, Se, Sb and Hg in farinaceous food and manufactured meat (sausages and hamburgers); b) Instrumental neutron activation analysis of Rb, Se, Br, Fe, Co and Zn in farinaceous food and manufactured meat; c) Preliminary studies of the daily intake of the determined elements. 5 refs, 3 figs, 17 tabs

  4. Activities of the neutron activation analysis laboratory of the radiochemistry division of IPEN - CNEN/SP

    International Nuclear Information System (INIS)

    Neutron activation analysis (NAA) is one of the relevant applications of nuclear research reactors. Due to the high neutron fluxes available in these reactors, an excellent sensitivity of analysis is attained for many elements. NAA is one of the most sensitive, precise and accurate analytical methods for trace element determination. NAA has been one of the main activities of the Radiochemistry Division of IPEN, since the beginning of the operation of the nuclear reactor IEA-R1. Most of the effort was devoted to research work, aimed to improvements in the method as well as to its applications to several kinds of matrixes (geological, biological, metallic, environmental, forensic). Besides, analytical services were also offered, to the CNEN, to industries, universities, mining companies and research institutes. In the present paper, a review is made of the research work being developed presently at the Radiochesmitry Division of IPEN. A discussion is also made of the planned expansion of the analytical services offered

  5. The role of neutron activation analysis technique Ex Industrial applications using the egyptian research reactor facilities

    International Nuclear Information System (INIS)

    This report covers several papers which deal with the industrial applications of the Neutron Activation Analysis Technique (NAAT) in Egypt. The applications include: exploration, mining, industrial environment and multielemental analysis of different materials, just for quality control, optimization, safety uses and help in improving the efficiency and economic evaluation. The technique principles, instrumentation, neutron irradiation facilities and experience of analysis are reviewed. Also, the current research activities using the ET-RR-1 facilities as well as a proposal for cold neutron applications in this field on the ET-RR-2 are given

  6. Archaeometry Applications of Cold Neutron Based Prompt Gamma Neutron Activation Analysis

    International Nuclear Information System (INIS)

    Prompt Gamma Activation Analysis (PGAA) is based on the detection of prompt gamma radiation following the capture of the neutrons into the atomic nucleus. Since every atomic nucleus emits characteristic prompt gamma radiation, this method is suitable for multielemental (panorama) analysis. The PGAA method can be regarded absolutely non-destructive, because of the relatively low intensity of the beam. In this project, we mainly focus on the research of ancient ceramics. Pottery production is one of the most important crafts of prehistoric communities. In the first task, pottery findings from Neolithic later prehistoric sites in Hungary were investigated with PGAA. Compositions of local sediments, as potential raw material sources were compared with those of pottery. In the second task, pottery fragments from the multiperiodical site of Voers, SW-Hungary were analyzed together with clay from the surrounding areas. In a firing experiment, an attempt to reproduce the ancient production techniques was done. As a third task of the project, PGAA was tested from methodological point of view. The reliability of the method has been occasionally checked through parallel measurements of archaeological samples with INAA and XRF as well. We took part in a proficiency test on a porcelane material, organized by IAEA. (author)

  7. Applications of neutron activation analysis in agriculture of Uzbekistan

    International Nuclear Information System (INIS)

    Full text: Soil is one of the main components of biosphere, which is subject to Man's economic activity from year to year. Unfortunately, during last 50-60years it became an object of the chemization (the treatment of crop by poison chemicals and the usage of mineral fertilizers).Thus, definite pre-conditions are created to migrate to substances applied along the soil horizon. These substances fall into organism of Man and animals through soil-contacting media: plants, air, water. In this respect the instrumental neutron-activation techniques which allows determination of about 40 chemical elements in soils and other objects of environment, with detection limit equal to 0.001-10.0mg/kg and not more than 30% uncertainty, are provided with the Ge -detector (the Canberra firm). The report discusses some metrological points of INAA concerning the objects of environment, in particular, the influence of space-time non-uniformity of chemical element distributions on the reliability of analysis results. The elaborated techniques make it possible to: - establish the elemental composition of soils, cotton, natural waters, mineral fertilizers, aerosol dust of near land layer of various climatic zones of Uzbekistan, including the airs around the Aral sea. - study of the interrelation between the soil elemental composition and the chemism in the evolution of pathological processes - find the correlation between the cotton returns and Mn contents in soils and to elaborate on this base a new way to value the presown grain quality - choose the wall material of ancient monuments of a region, which were not strongly subjected to ecological impact, as standards to monitor the background of chemical elements in soils - value the ecologically agrochemical conditions of soils for main cotton-sawing zones of Uzbekistan - perform a large scale mapping of soils to find the Mn contents and to elaborate the technology of introduction of Mn - containing microfertilizers - estimate the

  8. Use of research reactors for neutron activation analysis. Report of an advisory group meeting

    International Nuclear Information System (INIS)

    Neutron activation analysis (NAA) is an analytical technique based on the measurement of characteristic radiation from radionuclides formed directly or indirectly by neutron irradiation of the material of interest. In the last three decades, neutron activation analysis has been found to be extremely useful in the determination of trace and minor elements in many disciplines. These include environmental analysis applications, nutritional and health related studies, geological as well as material sciences. The most suitable source of neutrons for NAA is a research reactor. There are several application fields in which NAA has a superior position compared to other analytical methods, and there are good prospects in developing countries for long term growth. Therefore, the IAEA is making concerted efforts to promote neutron activation analysis and at the same time to assist developing Member States in better utilization of their research reactors. The purpose of the meeting was to discuss the benefits and the role of NAA in applications and research areas that may contribute towards improving utilization of research reactors. The participants focused on five specific topics: (1) Current trends in NAA; (2) The role of NAA compared to other methods of chemical analysis; (3) How to increase the number of NAA users through interaction with industries, research institutes, universities and medical institutions; (4) How to reduce costs and to maintain quality and reliability; (5) NAA using low power research reactors. Neutron activation analysis in its various forms is still active and there are good prospects in developing countries for long-term growth. This can be achieved by a more effective use of existing irradiation and counting facilities, a better end-user focus, and perhaps marginal improvements in equipment and techniques. Therefore, it is recommended that the Member States provide financial and other assistance to enhance the effectiveness of their laboratories

  9. Analysis of large samples by neutron activation analysis. Quality assurance aspects

    International Nuclear Information System (INIS)

    The need for quality assurance in large sample instrumental neutron activation analysis (INAA) requires the development of unconventional methods of quality control. Certified reference materials are not available at the 1-5 kg scale; moreover, inhomogeneities which might affect the accuracy of the real sample analysis would not be reflected in the analysis of a reference material or in-house control sample even when available. Model studies indicate that inhomogeneities with strong gamma ray absorbing properties have the largest effect on the accuracy of the concentrations. The occurrence of these inhomogeneities may be derived from gamma spectrum analysis. Other opportunities for quality assurance are with the calculated estimates of the parameters describing neutron and gamma ray self-attenuation, and eventually through direct assessment after homogenization of the large sample, subsampling and conventional analysis. (author)

  10. Determination of cadmium in water samples by co-precipitation and neutron activation analysis

    International Nuclear Information System (INIS)

    For the determination of cadmium in sea water, a neutron activation analysis method involving a preconcentration step has been developed. Preconcentration is achieved by co-precipitation of cadmium dibenzyldithiocarbamate with phenolphthalein. The precipitate is collected on 0.45 μm membrane filters and cadmium is determined by instrumental neutron activation analysis. A 115mCd radio tracer was used to establish optimum conditions and to evaluate the chemical yield. (author) 14 refs.; 1 fig. ; 2 tabs

  11. Neutron activation analysis and atomic absorption spectrophotometry for the analysis of fresh, pasteurised and powder milk

    Energy Technology Data Exchange (ETDEWEB)

    Wasim, M.; Rehman, S.; Arif, M.; Fatima, I.; Zaidi, J.H. [Pakistan Inst. of Nuclear Science and Technology, Islamabad (Pakistan). Chemistry Div.

    2012-07-01

    This study shows the application of semi-absolute k{sub 0} instrumental neutron activation analysis (k{sub 0}-INAA), epithermal neutron activation analysis (ENAA) and atomic absorption spectrophotometry (AAS) for the determination of 21 elements (Br, Ca, Cl, Co, Cr, Cs, Cu, Fe, Hf, I, K, Mg, Mn, Na, Ni, P, Pb, Rb, Sc Sr, and Zn) in different types of milk samples. The ENAA was required for the determination of iodine, AAS for Cu, Ni and Pb and the rest of the elements were measured by k{sub 0}-INAA. Thirteen elements (Br, Ca, Cl, Cs, Cu, Fe, K, Mg, Na, P, Rb, Sr and Zn) were identified in all milk samples. Ni was detected in eleven and Pb in two samples. Concentrations of most of the elements were within the ranges of the world reported data. The data was further explored by principal component analysis to find relationships between samples and elements. (orig.)

  12. Quantitative analysis of silicates by instrumental epithermal neutron activation using (n,p) reactions

    International Nuclear Information System (INIS)

    Instrumental epithermal neutron activation (IENA) involves the use of a neutron filter to screen out the thermal portion of the reactor neutron energy spectrum. Both Cd and B are efficient neutron filters. The principal advantage of epithermal over conventional thermal neutron activation for elemental analysis of geological materials is that the most common rock forming elements, which activate strongly with thermal neutrons (Na, Al, P, K, Fe, and Sc), have their activities suppressed, relative to elements which have cross-sectional resonances in the epithermal energy region. One-gram samples of various silicate standard reference materials were encapsulated in polyethylene vials and irradiated in the Los Alamos Omega West Reactor epithermal facility. Only six elements (F, Si, Na, Fe, Ni, and Ti) were successfully determined in geological matrices via (n,p) reactions. The single standard deviations among the measurements were less than 10% in all cases. The production ratio of (n,p) to (n,γ) and (n,p) to (n,α) interfering reactions are included for silicate materials having Mason's average crustal abundance of elements. Epithermal activation via (n,p) reactions provides an alternative method for the determination of Fe, Al, Na, Ni, and F. The preferred techniques are probably thermal neutron activation for the first three elements, atomic absorption for Ni, and ion selective electrode for F.Titanium and Si can be measured much more sensitively using the (n,p) reaction than by thermal neutron activation. 4 tables

  13. Optimization in Activation Analysis by Means of Epithermal Neutrons. Determination of Molybdenum in Steel

    International Nuclear Information System (INIS)

    Optimization in activation analysis by means of selective activation with epithermal neutrons is discussed. This method was applied to the determination of molybdenum in a steel alloy without recourse to radiochemical separations. The sensitivity for this determination is estimated to be 10 ppm. With the common form of activation by means of thermal neutrons, the sensitivity would be about one-tenth of this. The sensitivity estimations are based on evaluation of the photo peak ratios of Mo-99/Fe-59

  14. Analysis of some egyptian cosmetic samples by using fast neutron activation analysis

    International Nuclear Information System (INIS)

    A description of our neutron generator (NG) facility for neutron activation analysis is presented. As an example, the concentration of Na, Mg, Al, Si, K, Cl, Ca and Fe elements were determined in two domestic brands of face powder by using a beam of 14 MeV neutrons. An empirical expression for detector efficiency in terms of incident gamma ray energy and the source-detector distance has been obtained for a hyper pure germanium detector (HPGe) using different standard point sources. The comparison of the calculated efficiencies and the measured values in the energy range from 59.5 to 1332.2 keV and for source-to-detector distances of 5-30 cm show the agreement between the calculated values and the measured experimental values

  15. Utilization and facility of neutron activation analysis in HANARO research reactor

    International Nuclear Information System (INIS)

    The facilities of neutron activation analysis within a multi-purpose research reactor (HANARO) are described and the main applications of Neutron activation analysis (NAA) in Korea are reviewed. The sample irradiation tube, automatic and manual pneumatic transfer system, are installed at three irradiation holes. One irradiation hole is lined with a cadmium tube for epithermal-nal NAA. The performance of the NAA facility was examined to identify the characteristics of tube transfer system, irradiation sites and polyethylene irradiation capsule. The available thermal neutron flux with each irradiation site are in the range of 3.9x1013-1.6x1014 n/cm2·s and cadmium ratios are 15-250. Neutron activation analysis has been applied in the trace component analysis of nuclear, geological, biological, environmental and high purity materials and various polymers for research and development. Analytical services and the latest analytical results are summarized. (author)

  16. Characterization of the TRIGA Mark III reactor for k0 neutron activation analysis

    International Nuclear Information System (INIS)

    The k0 standardization for instrumental neutron activation analysis is a relatively new nuclear analytical technique. It is extended i n more than 20 countries of the world with reactor facilities, including some from Latin America. The great advantages of this technique (low uncertainties, fast and massive analysis, no standard necessity) with respect to relative, absolute and radiochemical activation analysis, are the reason of it fast introduction in Geology, Medicine, Agriculture and other fields of applications. But for the k0 instrumental neutron activation analysis implementation, the good knowledge of some reactor neutron flux and isotopes characteristics is necessary. The non ideality of the epithermal neutron flux temperature (Tn) and the k0 factors for more than 20 isotopes were determinate in the 3 typical irradiation positions of the TRIGA Mark III reactor of the National Nuclear Research Institute, Salazar, Mexico, using different experimental methods with conventional and non-conventional monitors

  17. Multielement analysis of foods by neutron capture prompt γ-ray activation analysis

    International Nuclear Information System (INIS)

    A method is described for the determination of H, B, Cl, K, Na, S, Ca, and Cd in foods using in-beam neutron capture prompt γ-ray activation analysis. Special calibration procedures were necessary because of matrix-related thermal neutron scattering-induced sensitivity and background enhancements. Detection limits and sensitivities are presented for best-case and worst-case irradiation conditions. The method was applied to multielement analysis of 41 foods and to B, Cl, and K analysis of 13 orange juice products in conjunction with analysis by inductively coupled plasma atomic emission spectrometry. The purpose of the latter application was to study B losses during acid digestion. (author) 9 refs.; 3 figs.; 2 tabs

  18. Total body neutron activation analysis of calcium: calibration and normalisation

    International Nuclear Information System (INIS)

    An irradiation system has been designed, using a neutron beam from a cyclotron, which optimises the uniformity of activation of calcium. Induced activity is measured in a scanning, shadow-shield whole-body counter. Calibration has been effected and reproducibility assessed with three different types of phantom. Corrections were derived for variations in body height, depth and fat thickness. The coefficient of variation for repeated measurements of an anthropomorphic phantom was 1.8% for an absorbed dose equivalent of 13 mSv (1.3 rem). Measurements of total body calcium in 40 normal adults were used to derive normalisation factors which predict the normal calcium in a subject of given size and age. The coefficient of variation of normalised calcium was 6.2% in men and 6.6% in women, with the demonstration of an annual loss of 1.5% after the menopause. The narrow range should make single measurements useful for diagnostic purposes. (author)

  19. Conventional radiometric methods of analysis including neutron activation

    International Nuclear Information System (INIS)

    The chapter aims primarily to provide a reference with which the various mass spectrometric methods may be compared. The fundamental problems created by low specific activity in the measurement of very long-lived radionuclides using radiometric techniques are noted and discussed in terms of the different types of decay, background count rates, source weight and spectral interferences. An attempt is made to identify typical detection limits for the radiometric determination of the various long-lived radionuclides. The use of neutron activation as a means of enhancing sensitivity or convenience of measurement for long-lived radionuclides is described with appropriate illustrations. Mass spectrometry and radiometry are seen as complementary, not competitive techniques for the measurement of radioactive materials, each with its own advantages and disadvantages. (author). 21 refs, 2 figs, 6 tabs

  20. Establishment and application of the cyclic neutron activation analysis method on mini-reactor

    International Nuclear Information System (INIS)

    Background: Instrument neutron activation analysis is a nondestructive analytic method. Some elements after irradiation produce short half-life radio-nuclides (<60 s), and others produce both long-lived and short-lived nuclides. For these short-lived nuclides, the single measurement has big error. Purpose: In order to reduce the error, cyclic neutron activation analysis can be used to improve the sensitivity. Methods: A device was designed to be connected to the sample transporter, detector and irradiation pipeline in the reactor, which can automatically control the irradiation time and counting time. According to the nuclear parameters of certain elements, irradiation time and counting time and cycle times were determined by experiment. Cyclic activation analysis method was established at the mini-reactor. Results: This paper studied cyclic activation analysis conditions of 17 kinds of element, and applied to the determination of actual samples. Cyclic epithermal neutron activation analysis (CENAA) method was discussed too. By the analysis of national standard reference materials, the reliability of this method was confirmed. Conclusion: Cyclic neutron activation analysis (CNAA) is an effective analytic method for only short life nuclide elements. For both short and long lived nuclides of elements, the cyclic activation analysis method can make the analytical cycle shorten, from a few days or several weeks to within a few minutes. Cyclic activation analysis has the advantages of high sensitivity, and its precision and accuracy are better than single short irradiation activation analysis. (authors)

  1. Survey on Neutron Activation Analysis Activities at the Dalat Nuclear Research Centre

    International Nuclear Information System (INIS)

    The Dalat Nuclear Research Centre (D.N.R.C.) during the past few years has been involved in conducting an activation analysis service. Work has been carried out in collaboration with other organizations. However, no rigid research programme of our own has been established and thus the Radiochemistry Division of the D.N.R.C. has no personnel and special facilities permanently engaged in this field. The equipment and facilities used are shared with other activities within the Division and the whole Centre. The activities in neutron activation analysis at the D.N.R.C. are sporadically revived by requests for analysis. Up to now, such analyses have been performed free of charge. Most of the work was carried out on biological materials such as vegetables, raw natural rubber (RES smoked sheets of different qualities, crepes and dried rubber films obtained from concentrated natural latex) from hevea tree leaves from various clones

  2. A study of environmental analysis of Havana Bay sediments using neutron activation analysis

    International Nuclear Information System (INIS)

    Surface sediments from the Havana Bay (Cuba) were analyzed by instrumental neutron activation analysis (INAA). Concentrations of 23 heavy and trace elements in the sediments were reported, including for the first time, an important group of REE (La, Ce, Nd, Sm, Eu, Tb, Yb and Lu). The normalization of the results for a reference metal shows that an anthropogenic Sb, Ba, As, Cr and Zn inputs are due to discharges of sewage and industrial effluent. (author)

  3. Analysis by neutron activation analysis a some ancient ceramics from Romanian territories

    CERN Document Server

    Olariu, A

    1999-01-01

    In this paper we have analyzed samples of Neolithic ceramics from Cucuteni-Scanteia - Vaslui county and Neolithic and Dacian ceramics from Magurele - Bucharest, by the method of neutron activation analysis. The following elements have been observed: Fe, K, La, Mn, Na, Sc and Sm. It has been noticed a relative and a slight clusterization of the analyzed items on the ratios of concentrations Na/Mn, La/Sc and La/Sm.

  4. Neutron activation analysis as applied to instrumental analysis of trace elements from seawater

    International Nuclear Information System (INIS)

    Particulate matter collected from the coastal area delimited by the mouth of the river Volturno and the Sabaudia lake has been analyzed by instrumental neutron activation analysis for its content of twenty-two trace elements. The results for surface water and bottom water are reported separately, thus evidencing the effect of sampling depth on the concentration of many elements. The necessity of accurately 'cleaning' the filters before use is stressed

  5. Neutron activation analysis of stable elements in marine algae

    International Nuclear Information System (INIS)

    The nuclear industry has grown during the last decades and continuing growth is predicted. Although considerable efforts are being made to minimize the release of the increasing amounts of radioactive wastes into marine environment, it is evident that the potential for radioactive contamination will continue to grow. The purposes of marine environment monitoring around nuclear facilities are to verify that they are functioning as it was designed and to detect the unplanned releases of radioactive contaminants. To provide a sufficient assessment with biological indicators of 60Co and 137Cs, most significant radionuclides in waste effluents released with nuclear power station, the concentration of stable elements in the Sargassum and other algae were surveyed with thermal neutron activation method. The results were followed: 1) The concentration of Mn, As, Zn, and Co were seem to be higher in the sargassum than in other algae. 2) The concentration of Co and Cs were higher in S. thunbergit than in other Sargassum. (author)

  6. Clinical applications of in vivo neutron-activation analysis

    International Nuclear Information System (INIS)

    In vivo neutron activation has opened a new era of both clinical diagnosis and therapy evaluation, and investigation into and modelling of body composition. The techniques are new, but it is already clear that considerable strides can be made in increasing accuracy and precision, increasing the number of elements susceptible to measurement, enhancing uniformity, and reducing the dose required for the measurement. The work presently underway will yield significant data on a variety of environmental contaminants such as Cd. Compositional studies are determining the level of vital constituents such as nitrogen and potassium in both normal subjects and in patients with a variety of metabolic disorders. Therapeutic programs can be assessed while in progress

  7. Human hair identification by instrumental neutron activation analysis

    International Nuclear Information System (INIS)

    Nondestructive neutron activation technique was used to analyze 17 elements (Al, As, Au, Ba, Br, Cl, Cu, Hg, I, K, Mg, Mn, Na, Sb, Sr, V and Zn) in 75 human hair samples in 5 different locations, respectively, from 15 glassware workers. The analytical results were treated further statistically to find the elemental distribution among different human hairs and to identify the individual's hair. The identifying probability of one's hair by the comparison of elemental concentrations is found to be 104-106 times higher from the same person's than from any other person's. The standard deviation of the elemental concentrations of samples taken from 5 different locations of one person is about 5 time smaller than the standard deviation for individual's hair. These data support the possibility of using NAA of hair for human hair identification. (author)

  8. Clinical applications of in vivo neutron-activation analysis

    Energy Technology Data Exchange (ETDEWEB)

    Cohn, S.H.

    1982-01-01

    In vivo neutron activation has opened a new era of both clinical diagnosis and therapy evaluation, and investigation into and modelling of body composition. The techniques are new, but it is already clear that considerable strides can be made in increasing accuracy and precision, increasing the number of elements susceptible to measurement, enhancing uniformity, and reducing the dose required for the measurement. The work presently underway will yield significant data on a variety of environmental contaminants such as Cd. Compositional studies are determining the level of vital constituents such as nitrogen and potassium in both normal subjects and in patients with a variety of metabolic disorders. Therapeutic programs can be assessed while in progress.

  9. Applied research and development of neutron activation analysis

    International Nuclear Information System (INIS)

    This report is written for results of research and development as follows : improvement of neutron irradiation facilities, counting system and development of automation system and capsules for NAA in HANARO ; improvement of analytical procedures and establishment of analytical quality control and assurance system; applied research and development of environment, industry and human health and its standardization. For identification and standardization of analytical method, environmental biological samples and polymer are analyzed and uncertainity of measurement are estimated. Also data intercomparison and proficency test were performed. Using airborne particulate matter chosen as a environmental indicators, trace elemental concentrations of sample collected at urban and rural site are determined and then the calculation of statistics and the factor analysis are carried out for investigation of emission source. International cooperation research project was carried out for utilization of nuclear techniques

  10. Applied research and development of neutron activation analysis

    Energy Technology Data Exchange (ETDEWEB)

    Chung, Yong Sam; Moon, Jong Hwa; Kim, Sun Ha; Bak, Sung Ryel; Park, Yong Chul; Kim, Young Ki; Chung, Hwan Sung; Park, Kwang Won; Kang, Sang Hun

    2000-05-01

    This report is written for results of research and development as follows : improvement of neutron irradiation facilities, counting system and development of automation system and capsules for NAA in HANARO ; improvement of analytical procedures and establishment of analytical quality control and assurance system; applied research and development of environment, industry and human health and its standardization. For identification and standardization of analytical method, environmental biological samples and polymer are analyzed and uncertainity of measurement are estimated. Also data intercomparison and proficency test were performed. Using airborne particulate matter chosen as a environmental indicators, trace elemental concentrations of sample collected at urban and rural site are determined and then the calculation of statistics and the factor analysis are carried out for investigation of emission source. International cooperation research project was carried out for utilization of nuclear techniques.

  11. Multielement analysis of archaic Chinese bronze and antique coins by fast neutron activation analysis

    International Nuclear Information System (INIS)

    Samples of archaic bronze were investigated by fast neutron activation analysis using both the absolute and relative method. The components Cu, Zn, Sn and Pb were determined quantitatively. For nondestructive analysis of antique Chinese coins the samples had to be irradiated. The activation reactions, the evaluation of the elemental concentrations and the accuracy of the results are discussed. The data were corrected for γ-ray self-absorption in the samples and summing of coincident γ-rays in the detector. According to reported typical compositions of Chinese bronze from different dynasties, the age of the samples has been derived from the results obtained. (author) 18 refs.; 3 figs.; 7 tabs

  12. Application of active neutronic interrogation method to the line analysis in reprocessing plant

    International Nuclear Information System (INIS)

    In a reprocessing plant of irradiated spent fuels, the knowledge in real time (line analysis) of uranium and plutonium quantities present in solutions is an extremely important parameter to control the proceeding and for the apparatus safety. The active neutronic analysis give a nondestructive non intrusive and quick measure to know the concentrations. This method consists in inducing fissions in nuclides with a neutron source and then to detect the particles which come from

  13. Nondestructive neutron activation analysis of mineral materials. III

    International Nuclear Information System (INIS)

    A description is presented of sampling, calibration standards, the method of activation and measurement, activation product identification, the respective nuclear reactions, interfering admixtures, and pre-activation operations. The analysis is described of sulphides, halogenides, oxides, sulphates, carbonates, phosphates, silicates, aluminosilicates, composite minerals containing lanthanides, rocks, tektites, meteors, and plant materials. The method allows determining mainly F, Mg, Al, Ti, V, Nb, Rh, and I which cannot be determined by long-term activation (LTA). It is more sensitive than LTA in determining Ca, Cu, In, and Dy. The analysis takes less time, irradiation and measurement are less costly. The main mineral components are quickly found. (M.K.)

  14. Studies on thermal neutron perturbation factor needed for bulk sample activation analysis

    CERN Document Server

    Csikai, J; Sanami, T; Michikawa, T

    2002-01-01

    The spatial distribution of thermal neutrons produced by an Am-Be source in a graphite pile was measured via the activation foil method. The results obtained agree well with calculated data using the MCNP-4B code. A previous method used for the determination of the average neutron flux within thin absorbing samples has been improved and extended for a graphite moderator. A procedure developed for the determination of the flux perturbation factor renders the thermal neutron activation analysis of bulky samples of unknown composition possible both in hydrogenous and graphite moderators.

  15. Modern Trends in Neutron Activation Analysis. Applications to some African Environmental Samples

    International Nuclear Information System (INIS)

    This review covers the results of several published articles which deal with the modern trends in neutron activation analysis techniques using some of African research reactors for some environmental samples. The samples used have been collected from different areas in Egypt, South Africa, Ghana, Morocco, Nigeria, and Algeria. The neutron irradiation facilities and the advanced detection systems in each country are outlined. The prompt and delayed gamma-rays emitted due to neutron capture have been applied for investigation of the elemental constituents of such samples. Covered applications include exploration, mining, industrial environment, pollution of air, foodstuffs, soils and irrigation water samples. Some of the developed software programmes as well as the modern methods of data analysis are presented. The thermal and epithermal neutron activation analysis techniques have been applied for estimation of major, minor and trace elements in each material. Some of these data are presented with several comments.

  16. Gamma and Neutron Flux of a Prompt Gamma Neutron Activation Analysis Collimator at the PUSPATI TRIGA Reactor

    International Nuclear Information System (INIS)

    A Prompt Gamma Neutron Activation Analysis (PGNAA) facility is being studied for installation at PUSPATI TRIGA Reactor (RTP) under the Thorium Flagship programme. This work presents the preliminary design of a PGNAA collimator at the RTP. The result of calculations for gamma and neutron flux at various positions of the PGNAA collimator in the RTP beam port 1 by using the computer code MCNPX are presented and discussed. The results indicate the technical feasibility of the installation of PGNAA facility at the RTP and the possibility of enhancing the utilization of the RTP. (author)

  17. Determination of hydrogen in niobium by cold neutron prompt gamma ray activation analysis and neutron incoherent scattering

    Energy Technology Data Exchange (ETDEWEB)

    R.L. Paul; H.H. Cheu-Maya; G.R. Myneni

    2002-11-01

    The presence of trace amounts of hydrogen in niobium is believed to have a detrimental effect on the mechanical and superconducting properties. Unfortunately, few techniques are capable of measuring hydrogen at these levels. We have developed two techniques for measuring hydrogen in materials. Cold neutron prompt gamma-ray activation analysis (PGAA) has proven useful for the determination of hydrogen and other elements in a wide variety of materials. Neutron incoherent scattering (NIS), a complementary tool to PGAA, has been used to measure trace hydrogen in titanium. Both techniques were used to study the effects of vacuum heating and chemical polishing on the hydrogen content of superconducting niobium.

  18. Matrix effects in compositional analysis of bulk materials by PGNAA (prompt gamma/neutron activation analysis). Final report

    Energy Technology Data Exchange (ETDEWEB)

    Rogers, V.C.; Sandquist, G.M.; Merrell, G.B.; Gozani, T.

    1984-08-01

    This feasibility study has identified and evaluated the influence of important matrix effects which arise in the commercial application of prompt gamma/neutron activation analysis (PGNAA) methods to bulk-coal analysis as follows: neutron moderation and absorption changes; gamma-ray attenuation in the sample; sample density and volume changes. The neutron-induced capture gamma spectra were found to vary in a similar, predictable manner for all neutron absorbers found in coal such as hydrogen, boron, nitrogen, chlorine, and sulfur. Three different models have been proposed from this study to analyze coal by PGNAA methods and account for the significant matrix effects arising from hydrogen variation and other system perturbations.

  19. Matrix effects in compositional analysis of bulk materials by PGNAA (prompt gamma/neutron activation analysis). Final report

    International Nuclear Information System (INIS)

    This feasibility study has identified and evaluated the influence of important matrix effects which arise in the commercial application of prompt gamma/neutron activation analysis (PGNAA) methods to bulk-coal analysis as follows: neutron moderation and absorption changes; gamma-ray attenuation in the sample; sample density and volume changes. The neutron-induced capture gamma spectra were found to vary in a similar, predictable manner for all neutron absorbers found in coal such as hydrogen, boron, nitrogen, chlorine, and sulfur. Three different models have been proposed from this study to analyze coal by PGNAA methods and account for the significant matrix effects arising from hydrogen variation and other system perturbations

  20. Impurities analysis of polycrystalline silicon substrates: Neutronic Activation Analysis (NAA) and Secondary Ion Mass Spectrometry (SIMS)

    Science.gov (United States)

    Lounis, A.; Lenouar, K.; Gritly, Y.; Abbad, B.; Azzaz, M.; Taïbi, K.

    2010-01-01

    In this study we have determined the concentration of some impurities such as carbon, iron, copper, titanium, nickel of the flat product (polycrystalline silicon). These impurities generate a yield decrease in the photovoltaic components. The material (polycrystalline silicon) used in this work is manufactured by the Unit of Silicon Technology Development (UDTS Algiers, Algeria). The 80 kg ingot has been cutted into 16 briquettes in order to have plates (flat product) of 100 mm×100 mm dimensions. Each briquette is divided into three parts top (T), middle (M) and bottom (B). For this purpose, the following instrumental analysis techniques have been employed: neutronic analysis (neutronic activation analysis) and secondary ion mass spectrometry (SIMS). Masses of 80 mg are sampled and form of discs 18 mm in diameter, then exposed to a flux of neutron of 2.1012neutron cm-2 s-1 during 15 min. The energetic profile of incidental flux is constituted of fast neutrons (ΦR = 3.1012n.cm-2 s-1; E = 2 Mev), thermal neutrons (ΦTH = 1013n.cm-2 s-1; E = 0.025 ev) and epithermal neutrons (Φepi = 7.1011 n cm-2 s-1; E>4.9 ev), irradiation time 15 mn, after 20 mn of decrement, acquisitions of 300 s are carried out. The results are expressed by disintegration per second which does not exceed the 9000 Bq, 500 Bq and 2600 Bq, respectively for copper, titanium and nickel. It is observed that the impurities concentrations in the medium are higher. The impurities in the bottom of the ingots originate from the crucible. The impurities in the top originate from impurities dissolved in the liquid silicon, which have segregated to the top layer of the ingot and after solidification diffuse. Silicon corresponds to a mixture of three isotopes 28Si, 29Si and 30Si. These elements clearly appear on the mass spectrum (SIMS). The presence of iron and the one of nickel has been noticed.

  1. Impurities analysis of polycrystalline silicon substrates : Neutronic Activation Analysis (NAA) and Secondary Ion Mass Spectrometry (SIMS)

    International Nuclear Information System (INIS)

    Full text: In this study we have determined the concentration of some impurities such as carbon, iron, copper, titanium, nickel of the flat product (polycrystalline silicon). These impurities generate a yield decrease in the photovoltaic components. The material (polycrystalline silicon) used in this work is manufactured by the Unit of Silicon Technology Development (UDTS Algiers, Algeria). The 80 kg ingot has been cutted into 16 briquettes in order to have plates (flat product) of 100 mm x 100 mm dimensions. Each briquette is divided into three parts top (T), middle (M) and bottom (B). For this purpose, the following instrumental analysis techniques have been employed: neutronic analysis ( neutronic activation analysis) and secondary ion mass spectrometry (SIMS). Masses of 80 mg are sampled and form of discs 18 mm in diameter, then exposed to a flux of neutron of 2.1012 neutron cm-2 s-1 during 15 min . The R= 3.1012 energetic profile of incidental flux is constituted of fast neutrons ( TH = 1013 ncm-2 s-1; E = 0.025 eV) ncm-2 s-1; E = 2 MeV), thermal neutrons ( epi = 7.1011 n cm-2 s-1; E and epithermal neutrons (> 4.9 eV), irradiation time 15 mn, after 20 mn of decrement, acquisitions of 300 s are carried out, the results are expressed by disintegration per second which does not exceed the 9000, 500 and 2600 Bq, respectively for copper, titanium and nickel. It is observed that the impurities concentrations in the medium are higher. The impurities in the bottom of the ingots originate from the crucible. The impurities in the top originate from impurities dissolved in the liquid silicon, which have segregated to the top layer of the ingot and after solidification diffuse. Silicon corresponds to a mixture of three isotopes 28Si, 29Si and 30Si. These elements clearly appear on the mass spectrum (SIMS).The presence of iron and the one of nickel has been noticed. (author)

  2. Correction for neutron self-shielding in large-sample prompt-gamma neutron activation analysis. Determination of macroscopic neutron cross sections

    International Nuclear Information System (INIS)

    When a sample is analysed with neutron activation analysis (NAA) neutron self-shielding and gamma self-absorption affect the accuracy. Both effects become even more important when the mass of a sample analysed is changed from small (say, 1 g) to large (say 30 kg). Therefore, corrections have to be carried out. Correction method for neutron self-shielding is considered for a thermal neutron beam irradiating large homogeneous samples for prompt-gamma NAA (PGNAA). The correction method depends on the macroscopic scattering and absorption cross sections of the sample. To avoid doing experiments with samples with different macroscopic scattering and absorption cross sections, the Monte Carlo model MCNP is applied in the development of the correction method. The computational development of the method to determine these cross sections through flux monitoring outside the sample is described. (author)

  3. Toenail elemental analysis of Korean young adults by instrumental neutron activation analysis

    International Nuclear Information System (INIS)

    The element contents in toenail clippings of healthy Korean young adults were measured using an instrumental neutron activation analysis. The average contents of elements such as Na, K, Cl, Ca, Fe, Se, and Zn are 449, 474, 1024, 1677, 66, 0.7 and 94 mg/kg in men, whereas those contents in women respectively 332, 476, 836, 1097, 66, 0.8 and 104 mg/kg. The correlation analysis of toenail elements with chronic disease risks showed positive associations between Na and serum HDL-cholesterol, blood pressure, and negative associations between Se and Hs-CRP, between Zn and hemoglobin level. (author)

  4. Elemental compositional analysis of meteorites by Prompt Gamma-ray Neutron Activation Analysis (PGNAA)

    International Nuclear Information System (INIS)

    Prompt Gamma ray neutron activation analysis method (PGNAA) is an isotope specific non distractive nuclear analytical method for complete compositional analysis of materials. This technique is being used for determination of various elements such as H,B,Cd,Hg rare earths, alkali metals transition metals in various samples of antiques, geological, biological and meteorites. In this work PGNAA has been used to study three original meteorite samples Dhofar 020 (OMAN), Sikhote Alin (RUSSIA) and North West Africa 2909 (Africa) at Budapest, Hungary and the results are presented in this paper. (author)

  5. Multi-element analysis of emeralds and associated rocks by k(o) neutron activation analysis

    Science.gov (United States)

    Acharya; Mondal; Burte; Nair; Reddy; Reddy; Reddy; Manohar

    2000-12-01

    Multi-element analysis was carried out in natural emeralds, their associated rocks and one sample of beryl obtained from Rajasthan, India. The concentrations of 21 elements were assayed by Instrumental Neutron Activation Analysis using the k0 method (k0 INAA method) and high-resolution gamma ray spectrometry. The data reveal the segregation of some elements from associated (trapped and host) rocks to the mineral beryl forming the gemstones. A reference rock standard of the US Geological Survey (USGS BCR-1) was also analysed as a control of the method. PMID:11077961

  6. Utilization of recycled neutron source to teach prompt gamma analysis activation-PGNA

    Science.gov (United States)

    Delgado-Correal, Camilo; Munera, Hector

    2008-03-01

    Neutron activation analysis based on prompt gamma ray emission has significantly developed during the past twenty years. The technique is particularly suited for the identification of low atomic number elements, as nitrogen that is a main component of drugs and explosives. Identification of these substances is important in the context of humanitarian demining, and in the control of illicit traffic of drugs and explosives. As a good example of recycling of radioactive sources, a ^241Am-Be neutron source emitting 10^7neutron/s, that was not longer in use for other purposes at Ingeominas, was used to build a neutron irradiator that can be used to teach prompt gamma ray analysis, and other nuclear techniques. We irradiated individual samples, each about 4 gram, of three different elements: nitrogen in urea, silicon in milled rock, and cadmium in cadmium oxide. The prompt gamma rays emitted in the nuclear reactions ^112Cd (neutron,gamma) ^113Cd, ^28Si (neutron,gamma) ^29Si and ^14N (neutron,gamma) ^15N were identified using a well-type NaI (Tl) detector, connected to a multi-channel analyzer.

  7. Thick activation detectors for neutron spectrometry using different unfolding methods: sensitivity analysis and dose calculation

    International Nuclear Information System (INIS)

    This paper discusses the use of threshold detectors of extended sizes for low intensity neutron fields' characterization. The detectors were tested by the measurement of the neutron spectrum of an 241Am–Be source. Integral quantities characterizing the neutron field, required for radiological protection, have been derived by unfolding the measured data. A good agreement is achieved between the obtained results and those deduced using Bonner spheres. In addition, a sensitivity analysis of the results to the deconvolution procedure is given. - Highlights: ► Low intensity neutron fields' characterization using thick threshold detectors. ► Low activity 241Am–Be neutron source spectrum measurement. ► Integral quantities required for radiological protection have been derived. ► The results are in good agreement with those deduced using Bonner spheres. ► The results are not very sensitive to the chosen deconvolution procedure.

  8. Current states for developing the prompt gamma neutron activation analysis system at HANARO

    International Nuclear Information System (INIS)

    Fabrication and performance test of major components used for the Prompt Gamma Neutron Activation Analysis system at HANARO have been completed. Thermal neutron extraction device consists of pyrolytic graphite crystals and a manual type two-axis goniometer. To focus neutron at the sample position graphite crystals can be tilted to concave mirror type. The tilting angle corresponding to the focusing condition was determined by reflecting parallel light. Collimator is composed of alternating layers of borated plastic, lead and polyethylene. As a shield surrounding collimator, heavy concrete mixed with B4C power was fabricated and neutron and gamma-ray shields for diffracted beam line have been completed. Presently, measurements of diffracted beam characteristics and neutron focusing effect are on the way with graphite crystals, collimator and surrounding shield installed

  9. Applications of short-lived activation products in neutron activation analysis of bio-environmental specimens

    International Nuclear Information System (INIS)

    This report discusses the advantages and disadvantages, special techniques, and actual and potential applications of neutron activation analysis (NAA) utilizing short-lived neutron-induced products, with special reference to the analysis of samples of biological and environmental origin. Attention is devoted mainly to products having half-lives in roughly the range of 10 milliseconds to 60 seconds, but with some discussion of the usefulness of even shorter-lived species, and ones with half-lives as long as a few minutes. Important aspects of the analytical methodology include sample preparation, irradiation/transfer systems, activity measurements, data processing and analytical quality assurance. It is concluded that several trace elements can be determined in bio-environmental samples (as well as in samples of industrial, geochemical and other origin). In particular, this method provides analytical possibilities for several elements (e.g. B, F, Li and V) that are difficult to determine in some matrices at trace levels by any other technique. These conclusions are illustrated in an annex by results of calculations in which the applicability of the techniques to the analysis of several biological and environmental reference materials is evaluated by means of an advance computer prediction program. The report concludes with an annotated bibliography of relevant publications (including abstracts, where available) taken from the INIS database. (author)

  10. Determination of rare earth elements in zircons by neutron activation analysis and their geochemical significance

    International Nuclear Information System (INIS)

    The concentrations of rare earth elements (REE) have been determined in zircon samples from different geological environments by radiochemical neutron activation analysis (RNAA) procedure, which is described. Prior to the REE determination, the uranium content of the zircon is obtained by the delayed neutron activation analysis technique (DNAA). In the determination of light rare earth elements from the activity of (n,γ) products, corrections were applied for the contributions from fission products nuclide (which are identical with the (n,γ) products). The REE patterns thus obtained seem to be characteristic of the evolution of their parent magma and could be used to trace their petrogenetic history. (author)

  11. Study of the origin of Mexican Indian potshards by means of neutron activation analysis

    International Nuclear Information System (INIS)

    This investigation is devoted to study similarities between various samples of Mexican potteries. Neutron activation analysis can provide a clue about the concentration of various elements in the clay sample. It constitutes a most accurate method for provenance studies. The availability of nuclear reactors and large lithium-drifted germanium detectors have made analysis of the pottery easier. Studies on the origin of Mexican Indian potshards by means of neutron activation analysis may clarify the relationship between tempered and untempered pottery made from the same clay and may facilitate a solution to many archaeological problems

  12. Determination of selenium in BCR single cell protein via destructive neutron activation analysis

    International Nuclear Information System (INIS)

    The amount of selenium in single cell protein (SCP), a product of BP Research Centre at Sunbury-at-Thames, England, was determined by neutron activation analysis. The SCP-samples were irradiated in the reactor of the Interuniversity Reactor Institute at Delft, in a neutron flux of 1.0 x 1013 n/cm2s for 24 hours. After chemical destruction of the samples the amount of selenium was determined by measuring the γ-peaks of selenium-75

  13. Study of the elemental composition of Chenopodium Quinoa Willd by fast neutron activation analysis and X ray fluorescence analysis

    International Nuclear Information System (INIS)

    By means of x-ray fluorescence and fast neutron activation analysis the nitrogen content has been determined in samples of roots, stems, leaf, flowers and grains from Quinua (Chenopodium Quinoa Willd), which was previously treated with fertilizer

  14. Neutronics and activation analysis of a SS316 based experimental D-T fusion power reactor

    International Nuclear Information System (INIS)

    Neutronics and activation analysis for a SS316 based experimental tokamak fusion power reactor was completed using a two-dimensional neutronics model because of its practical features. Operating and decay power densities in all reactor components were obtained. The significant increase of neutron fluxes in the vacuum duct region was revealed. Maintenance and waste management aspects of the reactor components were investigated. Impacts on these aspects due to important minor alloying elements and impurities such as Mn, Co, Mo, and Nb were addressed

  15. Multielement analysis of rice flour-unpolished reference material by instrumental neutron activation analysis

    International Nuclear Information System (INIS)

    Trace elements in NIES certified reference material No. 10-a∼10-c Rice Flour-Unpolished, prepared by the National Institute for Environmental Studies of Japan (NIES), were determined by instrumental neutron activation analysis (INAA). A set of three samples with different Cd concentration levels was subjected to analyses. Portions of each sample (ca. 200∼1000 mg) were irradiated, either with thermal neutrons without cadmium filter or with epithermal neutrons with cadmium filter, in the Musashi Institute of Technology Research Reactor (MITRR). The activated samples were analyzed by the three methods; conventional γ-ray spectrometry using a coaxial Ge detector, anticoincidence counting spectrometry, and coincidence counting spectrometry using a coaxial Ge detector and a well type NaI(Tl) detector. Concentrations of 26∼28 elements were determined by these methods. The values obtained for many elements, except for Mg and K, were in good agreement with those of the NIES certified and reference. Concentrations of 10 elements (S, Sc, V, Ag, Sb, Cs, Ba, La, Sm, Th), whose certified or reference values are not available from NIES, were also determined in this work. (author)

  16. Simultaneous Determination of Arsenic, Manganese, and Selenium in Biological Materials by Neutron-Activation Analysis

    DEFF Research Database (Denmark)

    Heydorn, Kaj; Damsgaard, Else

    1973-01-01

    A new method was developed for the simultaneous determination of arsenic, manganese, and selenium in biological material by thermal-neutron activation analysis. The use of 81 mSe as indicator for selenium permitted a reduction of activation time to 1 hr for a 1 g sample, and the possibility of loss...... the ppM level in samples of biological tissue....

  17. Analysis of impurities at trace levels in metallic niobium by instrumental neutron activation analysis

    International Nuclear Information System (INIS)

    The interest in obtaining niobium of high purity has increased due to the recent applications of this material in both vacuum and high temperature technologies and to its potential uses in the aeronautic and aerospacial industries and in the nuclear energy field. In the present work, a procedure of analysis of impurities in the parts per million level, in eletrolitic and non-eletrolitic niobium samples has been established. The method of neutron activation analysis followed by high resolution gamma ray spectrometry has been used. The elements Al, Na, Mn, Cl and In, in ppm level and Y, in the percentage level, were determined after irradiation from 1 to 20 minutes, under a thermal neutron flux of 1011 n.cm-2.s-1 at the IEA-Rl reactor of the IPEN-CNEN/SP. The γ-rays from the radioactive products were measured with a Ge(Li) detector coupled to a 4096 channel analyzer. The elements Ta, Cr and W, in the parts per million level, were determined with irradiation of 8 hours under a thermal neutron flux of 1012 n.cm-2.s-1. (autor)

  18. Neutron activation analysis with k0-standardisation : general formalism and procedure

    International Nuclear Information System (INIS)

    Instrumental neutron activation analysis (INAA) with k0-standardisation is a powerful tool for multi-element analysis at a broad range of trace element concentrations. An overview is given of the basic principles, fundamental equations, and general procedure of this method. Different aspects of the description of the neutron activation reaction rate are discussed, applying the Hogdahl convention. A general activation-decay formula is derived and its application to INAA is demonstrated. Relevant k0-definitions for different activation decay schemes are summarised and upgraded to cases of extremely high fluxes. The main standardisation techniques for INAA are discussed, emphasizing the k0-standardisation. Some general aspects of the basic equipment and its calibration are discussed, such as the characterisation of the neutron field and the tuning of the spectrometry part. A method for the prediction and optimisation of the analytical performance of INAA is presented

  19. Neutron Activation Analysis of Soil Samples from Different Parts of Edirne in Turkey*

    Science.gov (United States)

    Zaim, N.; Dogan, C.; Camtakan, Z.

    2016-05-01

    The concentrations of constituent elements were determined in soil samples collected from different parts of the Maritza Basin, Edirne, Turkey. Neutron activation analysis, an extremely accurate technique, and the comparator method (using a standard) were applied for the first time in this region. After preparing the soil samples for neutron activation analysis, they were activated with thermal neutrons in a nuclear reactor, TRIGA-MARK II, at Istanbul Technical University. The activated samples were analyzed using a high-efficiency high-purity germanium detector, and gamma spectrometry was employed to determine the elemental concentration in the samples. Eight elements (chromium, manganese, cobalt, zinc, arsenic, molybdenum, cadmium, and barium) were qualitatively and quantitatively identified in 36 samples. The concentrations of some elements in the soil samples were high compared with values reported in the literature.

  20. Neutron activation analysis with k{sub 0}-standardisation : general formalism and procedure

    Energy Technology Data Exchange (ETDEWEB)

    Pomme, S.; Hardeman, F. [Centre de l`Etude de l`Energie Nucleaire, Mol (Belgium); Robouch, P.; Etxebarria, N.; Arana, G. [European Commission, Joint Research Centre, Institute for Reference Materials and Measurements, Geel (Belgium)

    1997-09-01

    Instrumental neutron activation analysis (INAA) with k{sub 0}-standardisation is a powerful tool for multi-element analysis at a broad range of trace element concentrations. An overview is given of the basic principles, fundamental equations, and general procedure of this method. Different aspects of the description of the neutron activation reaction rate are discussed, applying the Hogdahl convention. A general activation-decay formula is derived and its application to INAA is demonstrated. Relevant k{sub 0}-definitions for different activation decay schemes are summarised and upgraded to cases of extremely high fluxes. The main standardisation techniques for INAA are discussed, emphasizing the k{sub 0}-standardisation. Some general aspects of the basic equipment and its calibration are discussed, such as the characterisation of the neutron field and the tuning of the spectrometry part. A method for the prediction and optimisation of the analytical performance of INAA is presented.

  1. Neutron activation analysis of rare earths and some other elements in material of geochemical interest

    International Nuclear Information System (INIS)

    ngle-element methods for the determination by neutron activation analysis of antimony, chromium, phosphorus, selenium and silver in international geochemical standard rocks, and the determination of rare earth elements i in standard rocks and apatites are described and discussed in twelve previously published papers, and in an eighteen page summary. Chemical separationtechniques are also discussed and the results are compared with previously obtained results with the same standard rocks. The accuracy of neutron activation analysis is discussed in comparison with isotope dilution mass spectroscopy, atomic absorption, gas chromatography and spark source mass spectrometry. (JIW)

  2. Twenty Five Years of Neutron Activation Analysis: A Personal Perspective on Utilization of the Techniques

    International Nuclear Information System (INIS)

    Since the late 1970's there have been enormous changes in the methods, techniques and applications of neutron activation analysis. Having been a research scientist at the National Research Council of Canada and the McMaster Nuclear Reactor, as well as a professor for ten years at the University of Illinois and 15 years at the University of Texas, I have a unique perspective on the research performed by my many MS, PhD and even undergraduate students. Below is a personal perspective on the utilization of the neutron activation analysis. (author)

  3. Elemental analysis of soil and hair sample by instrumental neutron activation analysis

    Energy Technology Data Exchange (ETDEWEB)

    Chung, Yong Sam; Quraishi, Shamshad Begum; Moon, Jong Hwa; Kim, Sun Ha; Baek, Sung Yeoil; Kang, Sang Hoon; Lim, Jong Myoung; Cho, Hyun Je; Kim, Young Jin

    2004-03-01

    Myanmar soil sample was analyzed by using the instrumental neutron activation analysis. The elemental concentrations in the sample, altogether 34 elements, Al As, Ba, Ce, Co, Cr, Cs, Eu, Fe, Ga, Gd, Hf, Ir, K, La, Lu, Mn, Na, Nd, Rb, Sb, Sc, Se, Sm, Th, Ti, V, Yb, Zn and Zr were determined. The concentration of 17 elements (Al, Au, Br, Ca, Cl, Cr, Cu, Co, Fe, Hg, K, Na, Mn, Mg, Sb, Se, Zn) in human hair samples were determined by INAA For quality control of analytical method, certified reference material was used.

  4. Elemental analysis of soil and hair sample by instrumental neutron activation analysis

    International Nuclear Information System (INIS)

    Myanmar soil sample was analyzed by using the instrumental neutron activation analysis. The elemental concentrations in the sample, altogether 34 elements, Al As, Ba, Ce, Co, Cr, Cs, Eu, Fe, Ga, Gd, Hf, Ir, K, La, Lu, Mn, Na, Nd, Rb, Sb, Sc, Se, Sm, Th, Ti, V, Yb, Zn and Zr were determined. The concentration of 17 elements (Al, Au, Br, Ca, Cl, Cr, Cu, Co, Fe, Hg, K, Na, Mn, Mg, Sb, Se, Zn) in human hair samples were determined by INAA For quality control of analytical method, certified reference material was used

  5. Multielement analysis of Nigerian chewing sticks by instrumental neutron activation analysis

    International Nuclear Information System (INIS)

    In Nigeria, various parts of various species of native plants have long been used for dental hygiene, with reportedly considerable effectiveness. These materials are known as 'chewing sticks'. This study was an effort to ascertain whether any unusual trace element concentrations might be present in Nigerian chewing sticks. Results are presented for 17 elements (Na, Mg, Al, Cl, K, Ca, Sc, V, Mn, Fe, Co, Zn, Br, Cs, La, Sm, Au) detected and measured in 12 species of such plants, via instrumental thermal-neutron activation analysis. (author)

  6. Analysis of essential elements in medicinal plants and their respective soils by neutron activation analysis

    International Nuclear Information System (INIS)

    In this study, the essential elements for humans in selected medicinal plants and their respective growing soils are measured by Neutron Activation Analysis. The concentrations of Na, K, Fe, Br, Al, Mn, Cl, Ca and Mg were analyzed using 20 kW KAMINI Reactor, Indira Gandhi Centre for Atomic Research (IGCAR), Kalpakkam. Results show that justification for the usage of these medicinal plants in the treatment of various diseases. Moreover, these results can be useful for preparing dosage of the herbal formulations. (author)

  7. Analysis of consumed fish species by neutron activation analysis in six Asian countries

    International Nuclear Information System (INIS)

    Fish were selected as a common target sample for a collaborative study of FNCA (Forum for Nuclear Cooperation in Asia)-NAA (neutron activation analysis) project in 2011. Six Asian countries took part in this work. Fish samples were purchased from commercial markets and prepared by following an agreed protocol. Toxic and essential elements in the prepared samples were determined by NAA. The concentration levels of As, Hg in many fish samples have higher values than the regulation ones. The fish contamination by heavy metals should be monitored continuously for human health. (author)

  8. Coal stream composition analysis for process control using prompt neutron activation analysis

    International Nuclear Information System (INIS)

    In this paper we describe early results of a series of laboratory experiments and computer modeling studies designed to provide realistic accuracy limits for the determination of the elemental concentration in coal using prompt neutron activation analysis. The results provide guidance for optimizing the technique for monitoring the quality of coal which is being input to an electric power generating plant. The reported work was performed as the initial phase of an ongoing program to develop a prototype on-line coal analyzer based on the PNAA technique for power plant application

  9. Analysis of gold and silver concentration on gold mining tailings by neutron activation analysis

    International Nuclear Information System (INIS)

    Full text: Instrumental neutron-activation analysis without radiochemical separation is one of most applicable and often used methods to analyze the concentration of gold, silver and other rare and noble metals in gold ores. This method is not suitable for analyzing low concentration of gold and silver in gold mining tailings due to rather high concentration of some elements. Samples are dissolved by boiling in a mixture of concentrated hydrochloric and nitric acids to extract gold and silver into the solution. Chemical yield of gold and silver after dissolution of the sample and further chromatographic separation is between 92 and 95 percent respectively

  10. Application of polyacrylamide gel electrophoresis/neutron activation analysis for protein quantification

    International Nuclear Information System (INIS)

    A combination of two methods, polyacrylamide gel electrophoresis (PAGE) and neutron activation analysis (NAA), has been applied to solutions containing phosphoproteins for the purpose of protein quantification. The proteins were separated by molecular weight using PAGE, and then the whole gel was activated by neutron bombardment. Densitometric measurements of the developed bands from 32P, taken from autoradiographs of the activated gels, resulted in quantification of the phosphorus, and then the related protein. This PAGE/NAA method was applied to several phosphoprotein-containing materials, including commercial milk products and reference materials, i.e., IAEA A-11, milk powder, and SRM 1845, Cholesterol in Egg Powder

  11. A simple and fast method for the determination of active ingredient in antiperspirant cosmetics by neutron activation analysis

    International Nuclear Information System (INIS)

    Antiperspirant cosmetics are tested for their active ingredient (aluminium chlorohydroxide) by conventional analytical techniques. Aluminium has been determined by instrumental neutron activation analysis in all antiperspirant products and package forms available in the Greek market in order to develop a simple and fast method for quantization. The results show that neutron activation analysis could be established as an official method for the determination of active ingredient in antiperspirant cosmetics. The proposed method is compared with the existing official methods and an alternative sampling method for aerosol package is presented. (author)

  12. Neutron activation analysis of the MIBI, MAG-3 and sodium fitate active principles

    International Nuclear Information System (INIS)

    Neutron activation analysis (NAA) both instrumental (INAA) and radiochemical (RNAA) are extensively applied for determination of minor and trace elements in samples of quite different origin and composition. Particularly, the application of INAA is well recognized for analysis of microquantitis of heavy metals as well as toxic elements in biological samples. In this work the possibility of the determination of MIBI, MAG-3 and sodium fitate elemental composition by INAA was investigated Analytical information about the concentration and/or detection limits of some toxic elements (Hg, Cd, As, Se, Sb) and other trace elements of interest (Fe, Cr, Co, Zn, Br) was obtained. The samples were irradiated in the CAb Ra-6 nuclear research reactor

  13. The study of the trace element in organisms by neutron analysis. I. Multielement instrumental neutron activation analysis of cannabis

    International Nuclear Information System (INIS)

    Examinations were made on optimal experimental conditions for instrumental determination of various elements in cannabis by neutron activation analysis, without any radiochemical separation, and the following conditions were found to be useful. Irradiation samples to be used are about 300 mg of the leaves or stem bark, and about 100 mg of the root. For soil sample, about 50 mg is used for the determination of short half-life nuclides and about 300 mg for long half-life nuclides. For short half-life nuclides, the samples are irradiated for 1 min, activity is measured for 200 sec after a decay of 3 min, and for 400 sec after a decay of 10 min. For long half-life nuclides, the samples are irradiated for 60 min and the activities are measured for 4 K sec after 1 week and for 10 K sec after 1 month. Use of supersonic waves is also convenient for cleansing of the samples. Thirty-five kinds of interesting elements were determined by this method from cannabis cultivated in Maizuru area. (Author)

  14. An evaluation of Compton suppression neutron activation analysis for determination of trace elements in some geological samples

    International Nuclear Information System (INIS)

    Compton suppressed neutron activation analysis has been used for a variety of applications, but never has a detailed discussion of its use in far more complex matrices, such as geological samples, been fully addressed. This investigation seeks to serve as a qualitative evaluation of Compton suppression neutron activation analysis (CSNAA) and to illustrate the benefits of using Compton suppression with thermal and epithermal neutrons for the analysis of several geological specimens.

  15. An evaluation of Compton suppression neutron activation analysis for determination of trace elements in some geological samples.

    Science.gov (United States)

    Landsberger, S; Kapsimalis, R

    2009-12-01

    Compton suppressed neutron activation analysis has been used for a variety of applications, but never has a detailed discussion of its use in far more complex matrices, such as geological samples, been fully addressed. This investigation seeks to serve as a qualitative evaluation of Compton suppression neutron activation analysis (CSNAA) and to illustrate the benefits of using Compton suppression with thermal and epithermal neutrons for the analysis of several geological specimens. PMID:19577479

  16. Taking into account neutron self-shielding and gamma quantum self-absorption in a sample during neutron activation analysis

    International Nuclear Information System (INIS)

    The neutron activation analysis errors caused by the effects of self-shielding of the neutron fluence and gamma quantum self-absorption are considered. These errors depend on the analyzed sample material, radiation parameters, radiation geometry and conditions of induced activity recording. The proper experiment is carried out at samples of different density (straw, grass, corn). All measurements were performed in the same geometry. The deltasub(n, γ) (L) effect of self-shielding and self-absorption in a sample of the L length was estimated by the following expression deltasub(n, γ)(L)=(Asub(0)sup(n, γ)(L)-Asub(sample)sup(n, γ)(L))/sub(0)sup(n, γ)(L) where Asub(0)sup(n, γ)(L) and Asub(sample)sup(n, γ)(L) are the induced gamma radiation fluences integrated along the L capsule length in the capsule with and without filler. The deltasub(n, γ)(L) effect was theoretically estimated. The dependence of this effect on the sample mass experimentally measured and theoretically calculated is given. Taking into account of the given effects with introduction of the proper correction during calculation permits to increase the accuracy of the neutron activation analysis by 5%

  17. Analysis of umayyad islamic silver coins (Dirhams) by using instrumental neutron activation analysis

    Institute of Scientific and Technical Information of China (English)

    1999-01-01

    Islamic silver coins (Dirhams) running the period between 107 to 126 Hijri (726-743AD), which belong to the Umayyad Empire period, 41-132 hijri (661-750AD), were selected for analysis by using instrumentalneutron activation analysis techniques.During this period (105-126H),(724-743AD), the Caliph Hisham Eben Abdlemalek ruled the Umayyad Empire.Dirhams were irradiated in a reactor neutron activation facility.Levels of various elements viz.Cu, Ag and Au were estimated.It was found that the average silver concentration, the baseconstituent of the Dirham, was about 88wt%.Correlation between thecomposition of Dirhams and the historical implications was discussed.

  18. Use of particles other than neutrons in activation analysis

    International Nuclear Information System (INIS)

    Nuclear reactions obtained by irradiation in γ Bremsstrahlung, α particles and protons are particularly suitable for dosing very small traces of light elements. We consider the possibilities presented by activation in γ radiation of 28 MeV maximum energy, mainly for the measurement of C, F, N, O, P and S. Non-destructive methods of analysis for beryllium are described. Under certain conditions they may also be used for other elements such as B, Ca, Li and Na. We give also the results of our first experiments carried out in an attempt to find a method for dosing carbon and oxygen by irradiation in α particles and protons. For each type of activation the possible types of interference with other nuclear refections are considered. (author)

  19. Determination of Lithium by Instrumental Neutron Activation Analysis

    DEFF Research Database (Denmark)

    Heydorn, Kaj; Skanborg, Preben Zacho; Gwozdz, R.;

    1977-01-01

    The fast transfer system in the DR 2 reactor for irradiation at a thermal neutron flux density of 1013 n·cm−2·sec−1 was used for the determination of lithium by the7Li(n, γ)8Li reaction. β-counting with a large perspex Cerenkov detector begun at 0.3 s after the end of irradiation, and multi...

  20. Overall measurement uncertainty of k0-based neutron activation analysis

    International Nuclear Information System (INIS)

    Special aspects of the uncertainty quantification in k0-NAA are discussed and applied in accordance with the Guide to the Expression of Uncertainty in Measurement (GUM), on a model case. The uncertainty budget is calculated highlighting the contribution and the importance of the different parameters to be taken into account. The importance of the nuclide-specific and neutron fluence-specific approach in estimating individual uncertainty contributions is emphasized and demonstrated by examples of Au, Cr, Rb, and Sb determinations. (author)

  1. Neutron activation analysis for the determination of contaminants in food contact materials

    International Nuclear Information System (INIS)

    A neutron activation method has been developed for the analysis of high density polyethylene, low density polyethylene,polypropylene, polyethylene terephthalate and polystyrene. Samples weighing 2-5 g were irradiated in a thermal neutron flux of 1016 neutrons m-2 s-1 and measured with gamma ray spectrometry for 64 elements. With the method developed here over 50 elements can be detected at concentrations below 1 mg/kg. Correction factors were applied for neutron flux variation and counting geometry. The method was validated using reference material citrus leaves (NIST) for Na, Mg, Al, K, Ca, Mn, Cu, Sr and I, and a suite of 'in house' standards doped with Al, Cr, Co, Mg, Zn and Sb confirmed repeatability of the method was used to measure inorganic contaminants in the raw polymers and retail samples of plastic packaging used in contact with food. (author). 3 refs., 6 tabs

  2. Software for neutron activation analysis at reactor IBR-2, FLNP, JINR

    CERN Document Server

    Zlokazov, V B

    2004-01-01

    A Delphi program suite, developed for processing gamma-spectra of induced activity of nuclei, obtained from the neutron activation measurements at the reactor IBR-2, FLNF, JINR, is reported. This suite contains components, intended for carrying out all the operations of the analysis cycle, starling with a data acquisition program for gamma -spectrometers Gamma (written in C++ Builder) and including Delphi programs for steps of the analysis. (6 refs).

  3. Implementation of neutron activation analysis in the neutron multiplier CS-ISCTN (first part)

    International Nuclear Information System (INIS)

    The detection limit of 32 elements are determined after experimental evaluation of the neutron flux components in the irradiation position of the neutron multiplier CS-ISCTN. The control of the thermal flux was carry up, comparing the experimental results obtained through three convention used determination of the reaction rate, with the theoretical obtained before

  4. Self-shielding coefficient and thermal flux depression factor of voluminous sample in neutron activation analysis

    International Nuclear Information System (INIS)

    Full text: One of the major problems encountered during the irradiation of large inhomogeneous samples in performing activation analysis using neutron is the perturbation of the neutron field due to absorption and scattering of neutron within the sample as well as along the neutron guide in the case of prompt gamma activation analysis. The magnitude of this perturbation shown by self-shielding coefficient and flux depression depend on several factors including the average neutron energy, the size and shape of the sample, as well as the macroscopic absorption cross section of the sample. In this study, we use Monte Carlo N-Particle codes to simulate the variation of neutron self-shielding coefficient and thermal flux depression factor as a function of the macroscopic thermal absorption cross section. The simulation works was carried out using the high performance computing facility available at UTM while the experimental work was performed at the tangential beam port of Reactor TRIGA PUSPATI, Malaysia Nuclear Agency. The neutron flux measured along the beam port is found to be in good agreement with the simulated data. Our simulation results also reveal that total flux perturbation factor decreases as the value of absorption increases. This factor is close to unity for low absorbing sample and tends towards zero for strong absorber. In addition, sample with long mean chord length produces smaller flux perturbation than the shorter mean chord length. When comparing both the graphs of self-shielding factor and total disturbance, we can conclude that the total disturbance of the thermal neutron flux on the large samples is dominated by the self-shielding effect. (Author)

  5. A method of neutron activation analysis to determine the concentration of alloy elements in steels

    International Nuclear Information System (INIS)

    The determination of the concentration of V, Mn and W in several types of steels was carried out through neutron activation analysis with an isotopic neutron source. Induced activities were detected with a NaI(Tl) gamma spectrometer coupled to a single channel pulse height analyser. Highly significant correlations have been found between specific count rates for each radionuclide and the concentration of the corresponding element (r > = .999 for each element); concentration ranges comprised a number of steel types. The comparison between the results of the application of the method and the ones obtained through conventional chemical analyses showed discrepancies no higher than 10%. (Author)

  6. Fast neutron activation analysis and radioisotope X-ray fluorescence study on KALEWA and NAMMA coal

    International Nuclear Information System (INIS)

    Kalewa coal was studied with Fast Neutron Activation Analysis (FNAA) technique, employing KAMAN A-710 neutron generator and HP(Ge) detector coupled to ''Canberra'' series 30 MCA. Sequential irradiation and dual aluminium foil monitoring method was employed. Simultaneous multielement analysis was carried out. Namma Coal was studied with radioisotope X-ray Fluorescence (XRF) technique, employing Co-57 exciter source and HP(Ge) detector coupled to ''Canberra'' series 40 MCA. In both FNAA and XRF study, the results obtained were compared to that obtained with Atomic Absorption Spectrophotometry (AAS) technique. Finally, the results were reviewed together with those obtained from similar work on coal with FNAA and XRF techniques. (author)

  7. Workbook on reactor neutron activation analysis (NAA) of airborne particulate matter (APM)

    International Nuclear Information System (INIS)

    This publication presents general aspects of reactor neutron activation analysis (NAA) applied to measurement of elemental composition of airborne particulate matter. It presents an introduction to the NAA, its' basic principles and brief history of the method and discusses its' advantages and disadvantages. This publication also presents experimental procedures of NAA including sampling and sample preparation; preparation of calibration standard samples; reactor neutron irradiation; gamma-spectroscopy of the irradiated samples; quantification and presentation of analytical results. The publication pays attention to the quality assurance and quality control procedures including internal quality control, analysis of certified reference materials, and interlaboratory and multi-method comparison studies, control charts

  8. Multi elementary analysis in medicinal plants through the neutron activation method

    International Nuclear Information System (INIS)

    A instrumental method by neutron activation in multielementary analysis was applied. Samples of Centelha asiatica (Cairucu) and Paulinia cupana (Guarana) were used. The elements Al, Br, Ca, Cl, Fe, K, Mn, Na, Rb, Sc, and Zn were determined. The results like precision and exactitude were analysed. (L.M.J.)

  9. Neutron activation analysis of stable isotopic tracers for studies of mineral bioavailability

    International Nuclear Information System (INIS)

    With increased recognition of the importance of trace minerals in nutrition it is necessary to investigate factors affecting their absorption. Enriched stable isotopic tracers with determination by neutron activation analysis or mass spectroscopy have been used to investigate the absorption of minerals by term and pre-term babies and to compare their absorption from infant formulae, without any radiological risk. (UK)

  10. Multi-element neutron activation analysis of sediment using a californium-252 source

    International Nuclear Information System (INIS)

    The application of a 252Cf source to the neutron activation analysis of several elements in small (approximately 1.5 in. in dia) cores was studied using high-resolution gamma ray spectroscopy and manual data reduction. (U.S.)

  11. Neutron-Activation Analysis of Biological Material with High Radiation Levels

    International Nuclear Information System (INIS)

    A method has been developed for the chemical separation and subsequent gamma-spectrometric analysis of the alkali metals, the alkaline earths, the rare earths, chromium, hafnium, lanthanum, manganese, phosphorus, scandium and silver in neutron-activated biological material. The separation steps, being fully automatic, are based on a combination of ion-exchange and partition chromatography and require 40 min

  12. Air pollution studies in Tianjing city using neutron activation analysis techniques

    International Nuclear Information System (INIS)

    Two sites of airborne sampling from industrial and residential areas were made in Tianjing city during February and June using PM-10 sampler and analyzed by NAA techniques; Comparison of air pollution between urban and rural area in Tianjing city was made using neutron activation analysis techniques and some other data analyzing techniques. (author)

  13. Neutron activation analysis for chemical characterization of Brazilian oxo-biodegradable plastics

    International Nuclear Information System (INIS)

    The chemical characterization of oxo-biodegradable plastic bags was performed by neutron activation analysis. The presence of several chemical elements (As, Br, Ca, Co, Cr, Fe, Hf, K, La, Na, Sb, Sc, Ta and Zn) with large variability of mass fractions amongst samples indicates that these plastics receive additives and may have been contaminated during manufacturing process thereby becoming potential environmental pollutants. (author)

  14. Determination of arsenic in some Myanmar indigenous medicines by neutron activation analysis

    International Nuclear Information System (INIS)

    Am(Be) neutron source was used for activation of samples and 76As radioactivity measured by both β- and γ-counting techniques. The samples analyzed were raw materials traditionally used in formulating Myanmar indigenous medicines. The results were compared with those obtained by volumetric analysis and those reported in the literature. (author) 4 refs.; 5 tabs

  15. Neutron activation analysis of zinc in forages used in intensive dairy cattle production systems

    International Nuclear Information System (INIS)

    Instrumental neutron activation analysis (INAA) was applied for the determination of Zn concentration in the main tropical grass forages used in intensive dairy cattle production systems, in Brazil. Smaller Zn concentration could be verified in the rainy period. Comparison of results obtained in these analyses of forages dry matter with daily requirements pointed towards deficiency of Zn in the forages. (author)

  16. New method in the criminalistics: neutron-activation analysis of the human hair

    International Nuclear Information System (INIS)

    The application of the neutron activation analysis for the examination of human hair for criminological purposes is discussed. Earlier Nal scintillation detector and 256-channels analyzer were used and only form trace elements could be detected in the hair. Recently using Ge/Li detector and a 1024-channels analyzer 11 trace elements were detected in the human hair. (H.E.)

  17. 14 MeV fast neutron activation analysis in the year 2000

    International Nuclear Information System (INIS)

    In recent years there is a decided upswing in interest in the application of fast neutron activation analysis methodologies to certain problems, i.e., detection of contraband substances, use of steady-state and pulsing instruments of body compositions etc. The value of a method which can characterize major and minor elements in large samples is again recognized. (author)

  18. Automatic activation analysis of fertilizers and plant samples by fast neutrons

    International Nuclear Information System (INIS)

    Instrumental neutron activation methods are suggested in order to carry out automatic analysis of fertilizers and plant samples for N, P, K and Si allowing for the investigation of more than 40 samples per 8 hours. The experimental errors do not exceed +-3% for N, +-6% for P, +-5% for K and +-15% for Si. (author)

  19. Rapid assay of organic halides in environmental samples by neutron activation analysis

    International Nuclear Information System (INIS)

    A method of searching for halogenated organic compounds (RCl, RBr and RI) in environmental samples (soils) is presented. The method involves extraction with hexane and detection of halogens by neutron activation analysis. Detection limits are about 1 microgram per gram of soil (1 ppm) for chlorine and about 0.1 ppm for bromine and iodine. (author)

  20. Development of the k0-based cyclic neutron activation analysis for short-lived radionuclides

    NARCIS (Netherlands)

    Dung, H.M.; Blaauw, M.; Beasley, D.; Freitas, M.D.C.

    2011-01-01

    The k0-based cyclic neutron activation analysis (k0-CNAA) technique has been studied to explore the applicability at the Portuguese research reactor (RPI). In particular, for the determination of elements which form short-lived radionuclides, particularly fluorine (20F, 11.16 s half-life) and seleni

  1. Handbook of nuclear data for neutron activation analysis. Vol. I

    International Nuclear Information System (INIS)

    The first part of a two-volume book which is meant for experimentalists working in instrumental activation analysis and related fields, such as nuclear metrology, materials testing and environmental studies. The volume describes the basic processes of gamma-ray interaction with matter as well as the important phenomena affecting gamma-ray spectra formation in semiconductor spectrometers. A brief account is also given of computation methods commonly employed for spectra evaluation. The results rather than detailed derivations are stressed. A great deal of material si divided into five chapters and nine appendices. The inclusion of many tables of significant spectroscopic data should make the text a useful handbook for those dealing with multi-channel gamma-ray spectra. (author) 26 figs., 82 tabs., 334 refs

  2. Verification of the viability of virions detection using neutron activation analysis

    International Nuclear Information System (INIS)

    The use of nuclear techniques, as Neutron Activation Analysis, can be an alternative way for the microbiological diagnosis, bringing a significant profit in the analysis time, for not needing pre cultivated samples in appropriate way. In this technique, the samples are collected and submitted to a thermal neutron beam. The interaction of these neutrons with the samples generates gamma rays whose energy spectre is a characteristic of the elemental composition of these samples. Of this done one, a virus presence can be detected in the sample through the distinction of its respective elemental compositions allowing, also, carrying through the analysis in real time. In this work, computational simulations had been become fulfilled using the radiation transport code based on the Monte Carlo Method, MCNP4B, to verify the viability of the application of this system for the virus particle detection in its natural collection environment. (author)

  3. Evaluation of the capability of neutron activation analysis at P2TRR-BATAN

    International Nuclear Information System (INIS)

    The capability of the neutron activation analysis comparative method and used equipment at P2TRR-BATAN performed by analysis reference standard materials of NIST-SRM 1648 and NIES-CRM 8. The analysis results shown the method and equipment have a good precision and accuracy, and also have a high sensitivity results. In these experiments, few elements could analyze, namely: As, Mg, Sc, Cr, Co, and Zn. The standard deviation each element values obtained with 2 - 13%

  4. Beam characteristics of polychromatic diffracted neutrons used for prompt gamma activation analysis

    International Nuclear Information System (INIS)

    The neutron beam is fully characterized for the prompt gamma activation analysis facility at Hanaro in the Korea Atomic Energy Research Institute(KAERI). The facility uses thermal neutrons which are diffracted vertically from a horizontal beam port by a set of pyrolytic graphite(PG) crystals positioned at the Bragg angle of 45 .deg.. Neutron spectra, neutron flux and Cd-ratio are determined for the three extraction modes of diffracted beam by means of the theoretical and experimental efforts. To obtain theoretical result, the reflectivity of pyrolytic graphite is calculated in the diffraction model for mosaic crystal and the angular divergence after diffraction by mosaic crystal is estimated from Monte Carlo simulation. The time-of-flight spectrometer and gold activation wire are used for measuring the neutron spectra. Both the calculated and measured spectra have proven that the unique feature of polychromatic beam obtained by PG crystals are useful for PGAA. The thermal neutron flux of 7.9 x 107 n/cm2s and the Cd-ratio of 266 for gold have been achieved at the sample position while the reactor operates at 24MW. The uniformity of beam flux is 12% in the central 1 x 1 cm2 area. Finally, the beam is briefly characterized by the effective velocity and temperature which are determined by measuring the prompt γ-ray spectra for thin and thick boron samples

  5. Prompt gamma neutron activation analysis in borehole logging and industrial process control

    International Nuclear Information System (INIS)

    Elemental analysis by prompt neutron activation analysis can be made by measuring the energy and intensity of prompt gamma-rays (PGNAA) emitted by an element upon capture of either a thermal or an epithermal neutron. Both prompt gamma-ray methods have a significant potential in bulk analysis because both neutrons and gamma-ray radiation are not significantly attenuated by the sample. The lack of absorption minimizes matrix effects and a large statistically meaningful sample is involved in the analysis. To accomplish the prompt neutron activation analysis in the laboratory it is relatively easy to design and control the entire process. The geometry of measurements is always constant and neutron flux at the sample can be measured. There is practically no restriction on size of detector or neutron source. However, in the narrow confines of a borehole there are a number of restrictions which must be considered. On-line analyses, although not restricted by space, have special problems in biological shielding, timing of detector pulses, need for rapid analysis and sensitivity for a given element. The purpose of this report is to discuss the different features which have to be taken into account when designing a PGNAA analyzer for a borehole logging tool or nuclear process control instrument. The performance characteristics of existing instruments, the special problems, possible solutions and the direction of the current thinking for future research are discussed. In addition, some appropriate applications where these instruments can be beneficially used to solve on-going problems are outlined. Refs, figs, tabs

  6. Analysis for toxic elements in food and drinking water in Thailand by neutron activation analysis

    International Nuclear Information System (INIS)

    This paper presents the results of a research aimed at the determination of several trace elements in foodstuffs and water in Thailand. The project included the development of adequate analytical procedures for the determination of As, Cd, Cu and Zn by ion exchange chromatography; Hg and Se by a direct combustion technique; Br, Co, Fe and Mn by instrumental neutron activation analysis (INAA); Pb by flame atomic absorption spectrophotometry; and As, Co, Mn, Sb, U, V, Zn, and Cr in water samples by pre-concentration on activated carbon followed by INAA. The samples analyzed comprised various kinds of vegetables, meat, poultry, beans and peas, various species of rice, fish, shellfish and other marine products. Natural and tap water samples were collected at several locations in twenty-nice provinces in Southern, Northern, North-Eastern and Central parts of Thailand. (author). 16 refs, 1 fig., 49 tabs

  7. Non-destructive analysis of ancient Egyptian vitreous materials by neutron activation analysis

    International Nuclear Information System (INIS)

    Chemical compositions of ancient Egyptian glass are one of the key information for identifying the location of the original material for production. The ordinary chemical analysis is however restricted because variable remains can not be destroyed. Thus sensitive analytical method in non-destructive manner is required. The neutron activation analysis was used in this research and the content of Ca, Cl, Al and Mn were found in ancient Egyptian glass and peak area of them were compared with those in the sand samples taken from several areas around Egypt because sand was thought as the raw material of such glasses. As a result, we found three different patterns in chemical compositions in the surrounding sand samples and we expect this pattern might be a good indicator of location of raw sand material. (author)

  8. Elemental analysis and plant samples at el-Manzala lake by neutron activation analysis technique

    International Nuclear Information System (INIS)

    A soil and a plant samples were taken from two locations, Bahr el-Bakar and Bahr Kados at the Manzala lake, where a high pollution is expected. The samples were especially treated and prepared for investigation by thermal neutron activation analysis (NAA). The irradiation facilities of the first egyptian research reactor (ET-R R-1) and the hyper pure germanium (HPGe) detection system were used for such a type of analysis. Among the 34 identified elements Fe, Co, As, Ru, Cd, Te, La, Sm, Eu, Tb, Hg, Th, and U are of a special significance because of their toxic deleterious impact to organisms. This work is a part of a research project concerning pollution studies on the river nile and some lakes of egypt. The data obtained in the present work stand as a reference basic record for any future follow up of the contamination level. 1 tab

  9. Application of an instrumental neutron activation analysis procedure to analysis of food

    International Nuclear Information System (INIS)

    The capabilities of a relatively simple instrumental neutron activation analysis procedure were demonstrated by performing multielement analyses of 240 Food and Drug Administration Total Diet Studies food composites. The analytical results provide a comprehensive database for a wide range of food types. The procedure incorporates only two irradiations and counts, polyethylene packaging and no sample transfer after irradiation. Concentrations were determined for 19 elements, 16 of which were found in most composites. Detection limits were calculated for all food groups and are given for the 22 elements included in the quantitative analysis scheme. In a qualitative search for 18 additional elements for which no standards were run, none were detected in any of the composites. Specific factors such as interferences from the blank are discussed in regard to their effects on the uncertainties associated with the experimental data and the detection limits. Modifications to the procedure are also suggested for lowering the detection limits for specific elements. (Auth.)

  10. Study on arsenic metabolism in animals by neutron activation analysis

    International Nuclear Information System (INIS)

    Male rats fed a diet of 5% Hijiki or 5% cellulose for 2 weeks, were administered large doses of sodium arsenate (Na2HAsO4) during two days. After 24 to 48 hours of the last arsenic administration, respective organs were isolated and dried. Potions of these were irradiated with thermal neutrons in a research reactor of Research Reactor Institute, Kyoto University, KUR. Arsenic concentrations were determined as gamma radiation from 76As. The Hijiki diet enhanced higher concentrations of arsenic in the blood cells than did the cellulose diet. These results suggested that the Hijiki diet has some effects on arsenic metabolism concerning arsenic distribution in body and its excretion. (author)

  11. The determination of chromium in water samples by neutron activation analysis after preconcentration on activated carbon

    International Nuclear Information System (INIS)

    A method is presented for the determination of chromium in sea- and fresh water. Chromium is concentrated on activated carbon from a neutral solution after a previous reduction of chromate with sodium sulfite at pH 1.5. The adsorption conditions, acidity, concentrations, amount of carbon, stirring-time, sample-volume, salinity, the influence of storage on the ratio of tervalent to hexavalent chromium, were investigated. The final determination of the total chromium content is performed by instrumental neutron-activation analysis. By preconcentration on activated carbon, a differentiation between tervalent and hexavalent chromium is possible. A separate determination of both species is not yet feasible due to the high carbon blank and to the necessity of measuring the adsorption percentage on carbon. The lower limit of determination, which depends on the value of the carbon blank, is 0.05 μg Cr/l with a precision of 20%. The determination is hampered by the considerable blank from the carbon. The use of activated carbon prepared from recrystallized sugar will probably improve the lower limit of determination and possibly allow the determination of chromate. (T.G.)

  12. Manganese determination om minerals by activation analysis, using the californium-252 as a neutron source

    International Nuclear Information System (INIS)

    Neutron Activation Analysis, using a Californium-252 neutron source, has been applied for the determination of manganese in ores such as pyrolusite, rodonite (manganese silicate)' and blending used in dry-batteries The favorable nuclear properties of manganese, such as high thermal neutron cross-section for the reaction 55Mn (n.gamma)56 Mn, high concentration of manganese in the matrix and short half - life of 56Mn, are an ideal combination for non-destructive analysis of manganese in ores. Samples and standards of manganese dioxide were irradiated for about 20 minutes, followed by a 4 to 15 minutes decay and counted in a single channel pulse-height discrimination using a NaI(Tl) scintillation detector. Counting time was equal to 10 minutes. The interference of nuclear reactions 56Fe(n,p)56Mn and 59 Co (n, α)56 were studied, as well as problems in connection with neutron shadowing during irradiation, gamma-rays attenuation during counting and influence of granulometry of samples. One sample,was also analysed by wet-chemical method (sodium bismuthate) in order to compare results. As a whole, i t was shown that the analytical method of neutron activation for manganese in ores and blending, is a method simple, rapid and with good precision and accuracy. (author)

  13. Determination of trace elements in NIES environmental reference materials by instrumental neutron activation analysis

    International Nuclear Information System (INIS)

    Concentrations of trace elements in environmental reference materials prepared by the National Institute for Environmental Studies of Japan (NIES) were determined by instrumental neutron activation analysis (INAA). Mussel, Human Hair, Tea Leaves and Sargasso reference material samples (ca. 150∼1200 mg) were irradiated by thermal neutron without cadmium filter and epithermal neutron with cadmium filter at Musashi Institute of Technology Research Reactor (MITRR). The activated samples were measured by three methods; conventional γ-ray spectrometry using a coaxial Ge detector, anticoincidence counting spectrometry and coincidence counting spectrometry. The γ-ray spectrometric system (GAMA system) was developed by the authors. As a result, they could determined about 30 - 50 elements by the combination of these irradiation and counting methods. The analyzed values were in good agreement with NIES certified values

  14. Determination of total nitrogen in rice by 14-MeV neutron activation analysis

    International Nuclear Information System (INIS)

    The determination of nitrogen in rice was accomplished by fast neutron activation analysis. The method is based in the irradiation of the grain/straw samples by 14-MeV neutron, giving 14N(n, 2n) 13N reaction. The neutron generator was operated at 140-145 kV with a beam current of 600-800 μA, giving a relative flux of about 108 n. cm-2sec-1. The activity of the annihilation radiation was counted with the Ge (Li) detector which was coupled to a multi-channel analyzer. Ammonium nitrate was used as standard. Correction for n-γ attenuation difference between the samples and the standard, for the interfering activites induced by other elements commonly found in rice, such as potassium and phosphorus, and for recoil protons were done. Results indicate that the method is in good agreement with the Kjeldahl determination

  15. Bulk - Samples gamma-rays activation analysis (PGNAA) with Isotopic Neutron Sources

    International Nuclear Information System (INIS)

    An overview is given on research towards the Prompt Gamma-ray Neutron Activation Analysis (PGNAA) of bulk-samples. Some aspects in bulk-sample PGNAA are discussed, where irradiation by isotopic neutron sources is used mostly for in-situ or on-line analysis. The research was carried out in a comparative and/or qualitative way or by using a prior knowledge about the sample material. Sometimes we need to use the assumption that the mass fractions of all determined elements add up to 1. The sensitivity curves are also used for some elements in such complex samples, just to estimate the exact percentage concentration values. The uses of 252Cf, 241Arn/Be and 239Pu/Be isotopic neutron sources for elemental investigation of: hematite, ilmenite, coal, petroleum, edible oils, phosphates and pollutant lake water samples have been mentioned.

  16. Neutron activation analysis of bulk samples from Chinese ancient porcelain to provenance research

    International Nuclear Information System (INIS)

    Neutron activation analysis (NAA) is an important technique to determine the provenance of ancient ceramics. The most common technique used for preparing ancient samples for NAA is to grind them into a powder and then encapsulate them before neutron irradiation. Unfortunately, ceramic materials are typically very hard making it a challenge to grind them into a powder. In this study we utilize bulk porcelain samples cut from ancient shards. The bulk samples are irradiated by neutrons alongside samples that have been conventionally ground into a powder. The NAA for both the bulk samples and powders are compared and shown to provide equivalent information regarding their chemical composition. Also, the multivariate statistical have been employed to the analysis data for check the consistency. The findings suggest that NAA results are less dependent on the state of the porcelain sample, and thus bulk samples cut from shards may be used to effectively determine their provenance. (author)

  17. Neutron activation analysis of several elements in the unicellular alga Cyanidium caldarium irradiated by α particles from neutron captured boron

    International Nuclear Information System (INIS)

    The TRIGA MARK 2 atomic reactor was used not only for instrumental neutron activation analysis (INAA) but also as the irradiation source of α particles derived from the 10B(n, α)7Li reaction for biological samples. The acidophilic and thermophilic unicellular alga (Cyanidium caldarium Geitler) was incubated for 20 hours after irradiation and then its elemental concentrations were analysed by INAA. An increase in the quantities of 56Mn, 28Al and 38Cl, and a decrease of 27Mg and 42K were detected in the irradiated cells in contrast to non-irradiated cells. (author)

  18. Application of instrumental neutron activation analysis to study ceramic fragments from Damascus Castle site, Syria

    International Nuclear Information System (INIS)

    Thirty-three archaeological ceramic fragment samples from Damascus Castle archaeological site, Damascus city, Syria, were analyzed using instrumental neutron activation analysis (INAA). 36 elements were determined. These elemental concentrations have been processed using two multivariate statistical methods, cluster and factor analysis in order to determine similarities and correlation between the various samples. Factor analysis confirms that 84.8% of the ceramics samples classified by cluster analysis are correctly classified by cluster analysis. The results provided persuasive evidence that Castle pottery used at least four different clay sources. Moreover, by means of systematic local analysis it will be clear whether these sources are local or not. (author)

  19. Chemical composition of lateritic ores and its industrial processing products by neutron activation analysis

    International Nuclear Information System (INIS)

    Several techniques of neutron activation analysis for the determination of chemical composition of lateritic ores and in its industrial processing products has been assayed. Instrumental neutron activation analysis with thermal neutrons from reactor combined with short irradiations, allowed the determination of a group of elements, but it was practically not applicable with long irradiations due to the strongly interferences of Co-60, Cr-51, Sc-46 and Fe-59. Reactor epithermal neutron activation analysis (ENAA), significantly reduced such interferences and at least 20 elements had been determined by this technique. An improvement of practical detection limits (10-6%) had been achieved combining the ENAA with one step radiochemical separation by using either the ion exchange in samples of ores and tails or the cobalt liquid extraction in the elaborated products. Nearly 30 elements had been determined by this combination, that also gives a valuable information concerning the distribution of some ''dispersed'' (Se, Ir, Au, etc.) and rare earths elements (La, Sm, Yb, Lu, etc.) during the industrial treatment of lateritic ores in Cuba. 21 refs

  20. In vivo neutron activation analysis of sodium and chlorine in tumor tissue after fast neutron therapy.

    Science.gov (United States)

    Auberger, T; Koester, L; Knopf, K; Weissfloch, L

    1996-01-01

    In 12 patients with recurrences and metastases of different primaries (head and neck cancer, breast cancer, malignant melanoma, and osteosarcoma) who were treated with reactor fission neutrons the photon emission of irradiated tissue was measured after each radiotherapy fraction. Spectral analyses of the decay rates resulted in data for the exchange of sodium (Na) and chlorine (Cl) between the irradiated tissue and the body. About 60% of Na and Cl exchanged rapidly with a turnover half-life of 13 +/- 2 min. New defined mass exchange rates for Na and Cl amount to an average of 0.8 mval/min/kg of soft tissue. At the beginning of radiotherapy the turnover of the electrolytes in tissues with large tumor volumes was about twice that in tissues with small tumor volumes. Depending on the dose, neutron therapy led in all cases to variation in the metabolism. A maximum of Cl exchange and a minimum of Na exchange occurred after 10 Gy of neutrons (group of six previously untreated patients) or after 85 Gy (photon equivalent dose) of combined photon-neutron therapy. A significant increase in non-exchangeable fraction of Na from about 40 to 80% was observed in three tumors after a neutron dose of 10 Gy administered in five fractions correlated with a rapid reduction of tissue within 4 weeks after end of therapy. These results demonstrate for the first time the local response of the electrolyte metabolism to radiotherapy. PMID:8949749

  1. Neutrons flux distribution in a 252Cf irradiation cell for neutron activation analysis

    International Nuclear Information System (INIS)

    A 100 microgram Californium-252 (252Cf) neutron source was embedded in a pure paraffin moderator surrounded by neutron and gamma ray shields to be used as an irradiation cell facility for NAA experiments. The cell is provided with a direct horizontal channel and a Vertical Tangential Irradiation Channel (VTIC) that are parallel to the source axis. The cadmium difference method was used in determining the thermal and epithermal neutron flux distributions along the axis of the (VTIC). For this purpose, 10 pairs of bare and cadmium covered pure gold foils were irradiated at the same positions along the axis of the (VTIC) in two separate runs. The absolute efficiency of the HPGe detector at the gamma ray energy 411.8 keV of 198 Au, was found to be 0.0318 ± 0.0025.The obtained distributions of thermal and epithermal neutron fluxes were tabulated and graphically presented. An evidence for contributions from 252Cf fission by epithermal neutrons was noticed. As an application on this facility the concentration of gold in an ore sample from gold - bearing ivory vein of wady Allaqui (at south west of eastern desert) was determined. It was found to be 612 ± 6 ppm

  2. Target preparation and neutron activation analysis a successful story at IRMM

    CERN Document Server

    Robouch, P; Eguskiza, M; Maguregui, M I; Pommé, S; Ingelbrecht, C

    2002-01-01

    The main task of a target producer is to make well characterized and homogeneous deposits on specific supports. Alpha and/or gamma spectrometry are traditionally used to monitor the quality of actinide deposits. With the increasing demand for enriched stable isotope targets, other analytical techniques, such as ICP-MS and NAA, are needed. This paper presents the application of neutron activation analysis to quality control of 'thin' targets, 'thicker' neutron dosimeters and 'thick' bronze disks prepared by the Reference Materials Unit at the Institute of Reference Materials and Measurements.

  3. Utilization of the Dalat Research Reactor for Radioisotope Production, Neutron Activation Analysis, Research and Training

    International Nuclear Information System (INIS)

    The Dalat Nuclear Research Reactor (DNRR) is a 500 kW pool type reactor loaded with a mixed core of HEU (36% enrichment) and LEU (19.75% enrichment) fuel assemblies. The reactor is used as a neutron source for the purposes of radioisotopes production, neutron activation analysis, basic and applied research and training. The reactor is operated mainly in continuous runs of 108 hours for cycles of 3–4 weeks for the above mentioned purposes. The current status of safety, operation and utilization of the reactor is given and some aspects for improvement of commercial products and services of the DNRR are also discussed in this paper. (author)

  4. Neutron activation analysis of trace metals in the livers of Japanese sika deer (cervus Nippon)

    International Nuclear Information System (INIS)

    Neutron activation analysis facilities at the JMTR reactor was used to determine the levels of trace metals in the livers of nine Japanese sika deer. The samples were cut into pieces, pulverized in liquid nitrogen, freeze-dried, and finally fractionated through a stainless steel sieve of 200 mesh. Then the samples were irradiated for 6 or 24 hours by a neutron flux of 1.0x1014 n·cm-2·sec-1. In the present work, we analysed the concentrations of six elements (Ag, Co, Fe, Rb, Se, and Zn) in the livers of nine deer. (author)

  5. Determination of aluminium contents in selected food samples by instrumental neutron activation analysis

    International Nuclear Information System (INIS)

    Food and food products are the main sources of Aluminium entering the human body. In order to know aluminium contents in food and food products, selected 26 samples from local market were analyzed by instrumental neutron activation analysis (INAA) using reactor neutrons and high resolution gamma-ray spectrometry. INAA using 1,779 keV γ-ray of 28Al (2.24 min) was used for aluminium concentrations in the range of 33-529 mg kg-1. Two NIST standard reference materials (SRMs) and two IAEA reference materials (RMs) were analyzed by INAA for quantification of aluminium as a part of method validation. (author)

  6. Application of neutron activation analysis to micro gram scale of solid samples

    International Nuclear Information System (INIS)

    An instrumental neutron activation analysis (INAA) procedure for analyzing extremely small samples was developed and applied to two kinds of extraterrestrial samples. A few mg of the Allende meteorite as well as the JB-1 basalt can work well as a reference sample for a relative method. To evaluate the applicability of this INAA procedure, detection limits are presented and compared with the elemental contents in a potential sample to be analyzed. The possibility of reuse of neutron-irradiated samples for mass spectrometry was noted by indicating degree of increase in isotopic abundance for noble gas and long-lived radioactive nuclides. (author)

  7. Simultaneous determination of nitrogen and phosphorus in cereals using 14 MeV Neutron Activation Analysis

    International Nuclear Information System (INIS)

    A method using 14 MeV neutron activation analysis was developed form non-destructive simultaneous determination of N and P in cereals. The samples were irradiated 5 min. after 0,5 min. decay time. The induced activities were measured using gamma spectrometry with Nal(Tl) well type detector. The accuracy, precision and detection limits obtained are discussed as well as the analytical results for different types of cereals. (Author) 10 refs., 8 tab., 1 fig

  8. Neutron activation analysis studies of selected portions of the Mahoning River system using 252Cf

    International Nuclear Information System (INIS)

    A neutron activation analysis study was conducted on portions of the Mahoning River located in eastern Ohio and western Pennsylvania. This river occurs in a highly populated area and is used extensively by numerous industries, including four steel mills, located in the area. Detailed analysis of water and sediment samples indicates the presence of ten different elements. These are sodium, chlorine, bromine, copper, manganese, magnesium, calcium, vanadium, potassium and aluminum. (U.S.)

  9. Principles and methods of neutron activation analysis (NAA) in improved water resources development

    International Nuclear Information System (INIS)

    The methods of neutron activation analysis (NAA) as it applies to water resources exploration, exploitation and management has been reviewed and its capabilities demonstrated. NAA has been found to be superior and offer higher sensitivity to many other analytical techniques in analysis of water. The implications of chemical and element concentrations (water pollution and quality) determined in water on environmental impact assessment to aquatic life and human health are briefly highlighted

  10. Risk assessment of inhalation exposure for airborne toxic metals using instrumental neutron activation analysis

    International Nuclear Information System (INIS)

    In order to study the effects of air pollution, about 1,300 samples of airborne particulate matter (APM) were collected at suburban and industrial sites, in Daejeon, Korea from 1998 to 2006. The concentrations of carcinogenic (As and Cr) and non-carcinogenic metals (Al, Mn, and Zn) were determined by using instrumental neutron activation analysis (INAA). These long-term metal concentration data were applied to a risk assessment of inhalation exposure using Monte Carlo analysis (MCA). (author)

  11. Determination of fluoride in human nails via cyclic instrumental neutron activation analysis

    International Nuclear Information System (INIS)

    The role of fluorine in human health has become somewhat controversial. It is widely accepted as protective against dental caries, may be protective against osteoporosis, and has been very conservatively implicated with osteosarcoma in male rats. The develepment of a neutron activation analysis method and its application to the analysis of human nails is reported. It has been found that toenails collected in population-based epidemiology studies apparently reflect fluoride intake. (author) 11 refs.; 2 tabs

  12. 'Edomite', 'Negbite' and 'Midianite' pottery from the Negev Desert and Jordan: instrumental neutron activation analysis results

    International Nuclear Information System (INIS)

    Edomite, Negbite and Midianite pottery from the Negev desert, Jordan, was subjected to neutron activation analysis to establish the origin of these pottery styles and to shed light on inter-regional contact between different peoples and tribes of the area for the 12th to 6th centuries BC. The pottery is listed with reference to chronological period and style and there are tables giving data on multi-element analysis of the pottery. (UK)

  13. Activation spectrometry: evidently neutrons provide the clues to non-destructive multielement analysis

    International Nuclear Information System (INIS)

    Activation spectrometry is the combination of neutron activation and gamma ray spectrometry, the most practical and widely applicable method in activation analysis. In simple terms a sample is bombarded with neutrons to activate stable isotopes of the elements to produce radionuclides. The activity of these radionuclides is measured using gamma ray spectrometry and used to deduce the original mass of the element. It is possible to identify and evaluate the peaks from hundreds of gamma rays using the high resolution detectors and so a material containing several elements can be analysed for the activity of all their radionuclides simultaneously. Since most elements can be activated with thermal neutrons, activation spectrometry is a multielemental technique capable of determining over 60 elements at trace concentrations in a wide range of materials. The main advantage it has over other multielemental techniques, such as inductively coupled plasma-atomic emission spectrometry or inductively coupled plasma-mass spectrometry, is that the sample requires no prior treatment and remains intact after analysis. The only change that takes place in the sample is the conversion of an insignificant number of stable nuclei to a new radioactive form of the element, or for those nuclei which have decayed, production of a new element. The method is therefore considered to be non-destructive since the sample can be analysed over and over again without deterioration. (Author)

  14. IPR-RI TRIGA MARK I reactor and the neutron activation analysis at CDTN/CNEN

    International Nuclear Information System (INIS)

    The IPR-R1 TRIGA Mark I research reactor started up in 1960. It is located at Centro de Desenvolvimento da Tecnologia Nuclear (Nuclear Technology Development Centre) / Comissao Nacional de Energia Nuclear (Brazilian Commission for Nuclear Energy), CDTN/CNEN. Join to the reactor, the Laboratory for Neutron Activation Analysis has been developing its activities since 1960. The activities of the Laboratory comprise the delayed fission neutron activation analysis, instrumental (comparative and parametric methods) and radiochemical / chemical methods. These methods are responsible for relevant percentage of CDTN's analysis demand, meeting the clients' analytical needs and researches developed by the Laboratory, by CDTN and by other institutions. Over the years the work has been linked to the goals of the country and the institutions. Nowadays several elements - Ag, Al, Au, As, Ba, Br, Ca, Cd, Ce, Cl, Co, Cr, Cs, Cu, Dy, Eu, Fe, Ga, Hf, Hg, Ho, K, La, Mg, Mn, Mo, Na, Nd, Rb, Sb, Sc, Se, Sm, Sr, Ta, Tb, Th, Ti, U, V, W, Yb, Zn and Zr - are determined in several matrices and range of concentrations. In Brazil, CDTN is the only Institute that fully masters the instrumental neutron activation analysis k0-method determining short, medium and long half-life radionuclides using its own nuclear reactor. The good performance of the reactor is pointed out in a table with experimental and certified values for Certified Reference Materials. (authors)

  15. Multi-element analysis of the obese subject by in vivo neutron activation analysis

    International Nuclear Information System (INIS)

    The Leeds facility for in vivo neutron activation analysis has been modified and calibrated for the simultaneous measurement of nitrogen, potassium, sodium, chlorine, phosphorus and calcium in obese patients weighing up to 210 kg. The effects of body size and shape were incorporated into the calibration by measuring 14 anthropomorphic phantoms of known composition representing individual patients being treated for obesity. The phantoms were constructed from tissue substitutes representing lean skeletal and adipose tissues, arranged to simulate the distributions of the corresponding tissues within the patients, as visualised by CT scanning. The precision of the method, determined by measuring a single phantom ten times over a period of ten weeks, is between two and three per cent for all elements except calcium, for which it is 11.3%. Accuracy is estimated to be similar to precision. The procedure has been used to study changes in body composition of patients undergoing therapeutic starvation. (author)

  16. The path of obsidian at the Tajin region. Origin analysis through Neutron Activation Analysis

    International Nuclear Information System (INIS)

    The task of contemporary archaeology is extended every day; new techniques and new instruments have been incorporating to those tools which the archaeologist has in order to achieve a better approach to his study object. The archaeology had been exploring in the physical chemical sciences with the purpose to obtain information beyond the traditional methodologies and so obtaining more and best data. The sudden advance in the knowledge of the basic particles which make up the matter can be applied to these archaeological studies too. Archaeology takes part of the new possibilities which nuclear physics offers in the study of materials such as ceramics, clays, metal alloys, native metals and practically some lithological source. In Latin America the neutron activation analysis was used first for the characterization and determination of the ceramics origin. Some regions have been better studied from the point of view of obsidian exploitation and consumption, such is the case of El Tajin and Oaxaca region in Mexico. (Author)

  17. Analysis of sewage sludge and cover soil by neutron activation analysis

    International Nuclear Information System (INIS)

    The Korean government reported that in 2005, 4395 tons/day of sewage sludge were generated from sewage disposal facilities in Korea and only 11.03% of it was reused. In addition, as a direct landfill of sewage sludge was forbidden from June 2003, research for a relevant disposal technique has been increasing. In this study, the aims were to analyze the collected sewage sludge samples and to evaluate the possibility for their reuse by a comparison of the elemental contents from a sewage sludge and a cover soil. Sludge samples were collected from a sewage disposal plant in Daejeon city and the cover soil was produced by a dilution of a sewage sludge with quicklime. Instrumental neutron activation analysis was employed to determine the elemental contents in the samples. Twenty seven elements were analyzed and their concentrations were compared. (author)

  18. Multielement analysis of environmental reference materials by instrumental neutron activation analysis

    International Nuclear Information System (INIS)

    Concentrations of trace elements in environmental reference materials prepared by the National Institute for Environmental Studies, Japan (NIES) and by the National Institute of Standards and Technology, USA (NIST) were determined by instrumental neutron activation analysis (INAA). NIES CRM No. 5 Human Hair, No. 6 Mussel, No. 7 Tea Leaves, No. 8 Vehicle Exhaust Particulates, No. 9 Sargasso and No. 10 Rice Flour-unpolished samples (ca. 150 - 1200 mg) and NIST SRM 1632a Bituminous Coal, SRM 1635 Sub-bituminous Coal and SRM 1633a Coal Fly Ash samples (ca. 10 - 150 mg) were irradiated at the Musashi Institute of Technology Research Reactor (MITRR). Concentrations of 28 - 52 elements in these NIES and NIST environmental reference materials were determined by two irradiation methods and four γ-ray counting methods. The determined values were in good agreement with the NIES and NIST certified values. (author)

  19. The role of neutron activation analysis for trace elements characterization, analysis and certification in atmospheric particulates

    International Nuclear Information System (INIS)

    The Neutron Activation Analysis (NAA) owns these requirements and is universally accepted as one of the most reliable analytical tools for trace and ultratrace elements determination. Its use in trace elements atmospheric pollution related studies has been and is still extensive as can be demonstrate by several specific works and detailed reviews. In this work, the application of this nuclear technique, in solving a series of different analytical problems related to trace elements in air pollution processes is reported. Examples and results are given on the following topics: characterization of urban and rural airborne particulate samples; particles size distribution in the different inhalable and respirable fractions (PM10 and PM 2.5); certification of related Standard Reference Materials for data quality assurance. (author)

  20. Analysis of sediment samples by reactor neutron activation analysis using Ko method

    International Nuclear Information System (INIS)

    The study on the determination of elemental concentration in sediments from lakes and other water bodies is of prime importance for geological as well as environmental studies. The profile of different elements with prior knowledge of sedimentation rates might provide clues to knowledge of their possible origin. The results on the determination of elemental concentration in sediments from Nanital lake at different depths are presented using single comparator neutron activation analysis (KoNAA) method. Irradiations of samples along with gold as comparator were carried out in Apsara reactor at Bhabha Atomic Research Centre. The concentrations of Na, K, Mn, Cu, Ba, As, Sr, Sc, La, Sm, Eu and Dy were determined. Variations in concentration of different elements in the sediment samples as a function of depth and the derived correlations are presented in this paper. (author). 5 refs., 1 fig., 1 tab

  1. Specialized database for instrumental neutron activation analysis-ND INAA 1.0

    International Nuclear Information System (INIS)

    Full text: In order to conduct nuclear and physical elemental analysis of materials content, in particular, activation analysis it is necessary to attract a large number of various nuclear data. The network of nuclear data centers (NNDC) under supervision of IAEA is dealing with accumulation, evaluation and systematization of nuclear data. The authors of the work have developed a software and information medium consisting specialized database, a package of calculation as well as requests and results visualization software. Based on evaluated nuclear data and original works a specialized database for need of neutron-activation analysis - ND INAA 1.0 was developed. The database presents a relatively frequently encountered isotopes of elements, thermal and resonance neutrons rapping cross-sections, decay types, radionuclides half-life, gamma- and alpha-radiation energies and intensities, maximal energies and intensities of beta-radiation, gamma-constants, and absolute yields of KX-radiation of radioactive nuclides, radioactive chains. The report contains examples of use of ND INAA 1.0 database along with the database on elemental content of natural objects - ELEMENT [1]: calculation of macro-cross-sections of elemental activation and calculation of activity of produced isotope on thermal and resonance neutrons in investigated objects, with taking into account of saturation and decay factors, geochemical spectra and others. Necessary calculations are conducted both for single radionuclide and for natural object as a whole. Separate part is dedicated to automation of K-Ar geological objects dating method. The give database is a part of developed by authors the system of automatization of instrumental neutron activation analysis - INAA. The developed apparatus allows one to use the given software production for another modifications of activation analysis. This work is performed on the project P-20-48 CST RUz

  2. Proceedings of DAE-BRNS discussion meet on current trends and future perspectives of neutron activation analysis

    International Nuclear Information System (INIS)

    The theme of the meet includes: Development of Neutron Activation Analysis (Naca) methods : ko-based NAA, Chemical NAA, Short-lived NAA, Prompt Gamma ray NAA (PGNAA), Fast neutron NAA using reactor and 14 MeV neutrons, Applications of NAA methods in various fields, Gamma ray spectrometry, An in-sight to data analysis in NAA, Position of NAA in comparison to other Nuclear Analytical Techniques (NATs) and Future perspectives in a panel discussion. Papers relevant to INIS are indexed separately

  3. Determination of Substances Content of Soil Surface Using Fast Neutron Activation Analysis

    International Nuclear Information System (INIS)

    Determination of substances content of soil surface using neutron activation analysis has been performed. The aim of this research is to determine whether there are any dangerous, hazardous and toxic substances that released from The Research and Development Center for Advanced Technology (RDCAT) as a government institution has possibility in releasing that substances to the environment by surface water, sewage or rain water that give any dangerous the environmental. The fast neutron activation analysis was used to analyze the type and concentration of substances qualitative and quantitatively. The quantitative analysis was performed using relative method. Samples were counted using NaI(TI) detector. The result showed that there are several substances such as Mn-55, Fe-56, P-31, Al-27. Zn,65 and Mg-24. And there are found any hazardous, dangerous and toxic substances in the samples that causing any danger to human and environment. (author)

  4. The use of the TRIGA Mark II reactor, Ljubljana, Yugoslavia in the k0 method of neutron activation analysis

    International Nuclear Information System (INIS)

    The k0 standardisation method is suitable for routine multi-element determinations in various materials by reactor neutron activation. A 21 - element synthetic standard for biological material was analysed in this work by neutron activation analysis and the results obtained, as well as our experience with the method itself, are discussed. (author)

  5. Determination of the specific activity of carrier-free 125I preparations by neutron activation analysis

    DEFF Research Database (Denmark)

    Heydorn, Kaj

    Chemical methods are unsuitable for the determination of the specific activity of commerical125I preparations because of the unknown chemical state of the iodine in solutions more than a few weeks old.125I and127I were determined in samples from seven different manufacturers by instrumental neutron...

  6. Application of thermal and epithermal neutron activation analysis to rocks and sediment samples

    International Nuclear Information System (INIS)

    Neutron activation analysis (NAA) has been applied to the determination of several trace elements in rocks and in marine sediments. Epithermal neutron activation analysis (ENAA) has been shown to be useful in the analysis of rocks, because some strong activities limiting the instrumental determination of many elements are reduced. Some USGS geological reference materials have been activated by both thermal and epithermal neutrons, evaluating the experimental advantage factors of ENAA and comparing the obtained concentrations and the detection limits for both methods. ENAA is particularly useful to determine several elements, among which some of the rare earth elements (REE), whose importance in petrogenetic studies is well known. In the case of marine sediments, the REE are considered particularly important for simulating the chemical behaviour of the actinides in the environment. For this purpose, REE have been determined after a group separation from the matrix, in order reduce the complexity of the activation gamma-ray spectra. This separation step improves detection limits for all REE, allowing the determination of some of them not easily detected without a separation, like Nd, Gd, Tb, and Tm

  7. Progress report on neutron activation analysis at Dalat Nuclear Research Reactor

    Energy Technology Data Exchange (ETDEWEB)

    Tuan, Nguyen Ngoc [Nuclear Research Institute, Dalat (Viet Nam)

    2003-03-01

    Neutron Activation Analysis (NAA) is one of most powerful techniques for the simultaneous multi-elements analysis. This technique has been studied and applied to analyze major, minor and trace elements in Geological, Biological and Environmental samples at Dalat Nuclear Research Reactor. At the sixth Workshop, February 8-11, 1999, Yojakarta, Indonesia we had a report on Current Status of Neutron Activation Analysis using Dalat Nuclear Research Reactor. Another report on Neutron Activation Analysis at the Dalat Nuclear Research Reactor also was presented at the seventh Workshop in Taejon, Korea from November 20-24, 2000. So in this report, we would like to present the results obtained of the application of NAA at NRI for one year as follows: (1) Determination of the concentrations of noble, rare earth, uranium, thorium and other elements in Geological samples according to requirement of clients particularly the geologists, who want to find out the mineral resources. (2) The analysis of concentration of radionuclides and nutrient elements in foodstuffs to attend the program on Asian Reference Man. (3) The evaluation of the contents of trace elements in crude oil and basement rock samples to determine original source of the oil. (4) Determination of the elemental composition of airborne particle in the Ho Chi Minh City for studying air pollution. The analytical data of standard reference material, toxic elements and natural radionuclides in seawater are also presented. (author)

  8. Progress report on neutron activation analysis at Dalat Nuclear Research Reactor

    International Nuclear Information System (INIS)

    Neutron Activation Analysis (NAA) is one of most powerful techniques for the simultaneous multi-elements analysis. This technique has been studied and applied to analyze major, minor and trace elements in Geological, Biological and Environmental samples at Dalat Nuclear Research Reactor. At the sixth Workshop, February 8-11, 1999, Yojakarta, Indonesia we had a report on Current Status of Neutron Activation Analysis using Dalat Nuclear Research Reactor. Another report on Neutron Activation Analysis at the Dalat Nuclear Research Reactor also was presented at the seventh Workshop in Taejon, Korea from November 20-24, 2000. So in this report, we would like to present the results obtained of the application of NAA at NRI for one year as follows: (1) Determination of the concentrations of noble, rare earth, uranium, thorium and other elements in Geological samples according to requirement of clients particularly the geologists, who want to find out the mineral resources. (2) The analysis of concentration of radionuclides and nutrient elements in foodstuffs to attend the program on Asian Reference Man. (3) The evaluation of the contents of trace elements in crude oil and basement rock samples to determine original source of the oil. (4) Determination of the elemental composition of airborne particle in the Ho Chi Minh City for studying air pollution. The analytical data of standard reference material, toxic elements and natural radionuclides in seawater are also presented. (author)

  9. Determination of Iron and Nickel in Geological Samples by Activation Analysis with Reactor Fast Neutrons

    International Nuclear Information System (INIS)

    Threshold reactions induced by reactor fast neutrons are well recognized. The concentration of Fe and Ni were determined in nine geological samples by activation analysis with reactor fast neutrons using the threshold reactions 54Fe( n,p)54Mn and 58Ni ( n, p )'58Co respectively. The fast neutron flux was determined using the reactions 92Mo(n, 2n)92mNb and 95Mo(n,p)95Nb. The determined concentration of Fe and Ni in the samples were checked by determining them in the GSJ JB-1 reference material using the same , ( p, n) reactions. There are a good agreement between the measured and recommended values. The concentrations of Fe were also determined by the ) , ( n, γ) capture reactions in the geological samples and the JB-1 reference material using the Kθ- NAA method. There are good agreements between the determined concentrations from the ) , ( p, n) and the ( γ, n) reactions.

  10. Nuclear data and the effects of its inconsistency on instrumental neutron activation analysis

    International Nuclear Information System (INIS)

    In this study, we examine the role of nuclear data in Instrumental Neutron Activation Analysis (INAA) particularly as it affects determination of reactor flux parameters and application of comparator methods. The work reviewed the available sources of nuclear data, the variations that exist from one source to the other and the effects of such variations on INAA. Measurement of Neutron flux parameters in inner and outer irradiation channel of a miniature neutron source reactor was carried out using two independent nuclear data sources to investigate the effects of inconsistency of nuclear data on the precision of analytical result. The result obtained shows a slight variation of flux parameters with nuclear data source. It was also observed that modification of the earlier compiled basic nuclear data lead to inconsistencies in the secondary data that applies it. (author)

  11. Establishment of prompt gamma neutron activation analysis facility at PARR-1

    International Nuclear Information System (INIS)

    Prompt gamma neutron activation analysis facility at through tube of upgraded PARR-1 reactor has been established. The salient features of the facility have been described. The in-pile as well as external collimators, beam shutter, target assembly and beam catcher were designed and fabricated indigenously. The flux at target position is 1.8x10/sup 10/ neutrons/cm/sup 2/sec and the cadmium ratio is about 10 Anti-Compton/pair spectrometer has been installed at 90 deg. to the incident beam. The measurements of the prompt gamma rays from thermal neutron capture in chlorine, nitrogen and chromium were carried out to calibrate HPGe detector up to 10 MeV. The set-up will be used in the determination of non-metals that form the elements of geological and biological materials or other trace elements with high thermal capture cross sections with improved peak/compton ratio of the spectrometer. (author)

  12. Elemental analysis of granite by instrumental neutron activation analysis (INAA) and X-ray fluorescence analysis (XRF)

    Energy Technology Data Exchange (ETDEWEB)

    El-Taher, A., E-mail: Atef_Eltaher@hotmail.com [Physics Department, Faculty of Science, Al-Azher University, Assuit 71452 (Egypt); Physics Department, Faculty of Science, Qassium University, Buraydah 51452 (Saudi Arabia)

    2012-01-15

    The instrumental neutron activation analysis technique (INAA) was used for qualitative and quantitative analysis of granite samples collected from four locations in the Aswan area in South Egypt. The samples were prepared together with their standards and simultaneously irradiated in a neutron flux of 7 Multiplication-Sign 10{sup 11} n/cm{sup 2} s in the TRIGA Mainz research reactor. Gamma-ray spectra from an hyper-pure germanium detector were analyzed. The present study provides the basic data of elemental concentrations of granite rocks. The following elements have been determined Na, Mg, K, Fe, Mn, Sc, Cr, Ti, Co, Zn, Ga, Rb, Zr, Nb, Sn, Ba, Cs, La, Ce, Nd, Sm, Eu, Yb, Lu, Hf, Ta, Th and U. The X-ray fluorescence (XRF) was used for comparison and to detect elements, which can be detected only by XRF such as F, S, Cl, Co, Cu, Mo, Ni, Pb, Se and V. The data presented here are our contribution to understanding the elemental composition of the granite rocks. Because there are no existing databases for the elemental analysis of granite, our results are a start to establishing a database for the Egyptian granite. It is hoped that the data presented here will be useful to those dealing with geochemistry, granite chemistry and related fields. - Highlights: Black-Right-Pointing-Pointer Instrumental neutron activation analysis technique (INAA) was used for qualitative and quantitative analysis of granite. Black-Right-Pointing-Pointer The samples were prepared together with their standards and simultaneously irradiated in a neutron flux of 7 Multiplication-Sign 10{sup 11} n/cm{sup 2} s in the TRIGA Mainz research reactor. Black-Right-Pointing-Pointer Following elements have been determined Na, Mg, K, Fe, Mn, Sc, Cr, Ti, Co, Zn, Ga, Rb, Zr, Nb, Sn, Ba, Cs, La, Ce, Nd, Sm, Eu, Yb, Lu, Hf, Ta, Th and U.

  13. Neutron activation analysis of soils and its application in ecological studies

    International Nuclear Information System (INIS)

    The multi-element instrumental neutron-activation analysis of soil is carried out with the purpose of establishing the reproduction and correctness of the analysis of separate elements, the content whereof changes from 5 up to 10-6 mass % . The probe irradiation was accomplished in the neutron fuel with the flux density of 5 x 1013 s-1 · cm-2. The study on the metrological parameters of the soil neutron activation analysis and distribution functions of above 20 chemical elements showed, that the sum of squares of reproducibility and deviations of the analysis characterizes the analytical dispersion (the laboratory error) for each element. The summary distribution dispersion of separate elements is close to and in the majority of cases significantly above the analytical one in the low-content area. The distribution histogram form for 20 chemical elements depends on the limit of identification and metrological parameters of the applies analysis methodologies. All the metrological parameters in the area of 10-6 - 5 mass % including the reproduction and correctness of the analysis, are the functions of the element average content are the functions of the element average content

  14. Instrumental neutron activation analysis of roots and juice of carrot

    International Nuclear Information System (INIS)

    The results are presented of the determination of the contents of Na, Br, Ca, Ba, Fe, Zn, Co, Cr, Sb and Ni. The results of the analysis are in agreement with the usually given concentrations of the elements determined in identical or similar materials. The amount of monitored elements passing from the raw materials into juices was calculated. (J.B.)

  15. Neutron activation analysis for the archaeometric study of Catamarca pottery

    International Nuclear Information System (INIS)

    Samples of pottery and raw materials from the Puna and the mesothermal valleys regions were irradiated in the RA-3 reactor for 5 hours and 22 elements (As, Ba, Ce, Co, Cr, Cs, Eu, Fe, Gd, Hf, La, Lu, Nd, Rb, Sb, Sc, Sm, Ta, Tb, Th, U and Yb) were determined by instrumental analysis, 37 days after the irradiation. The results allow drawing conclusions on the production and distribution of the pottery in the region. (authors)

  16. Validation of the MCNP Computational Model for Neutron Flux Distribution with the Neutron Activation Analysis Measurement

    International Nuclear Information System (INIS)

    The objective of this work is to demonstrate the method for validating the predication of the calculation methods for neutron flux distribution in the irradiation tubes of TRIGA research reactor (TRR-1/M1) using MCNP computer code model. The reaction rate using in the experiment including 27Al(n, α)24Na and 197Au(n, γ)198Au reactions. Aluminum (99.9 wt%) and gold (0.1 wt%) foils and the gold foils covered with Cd were irradiated in 9 locations in the core referring as CT, C8, C12, F3, F12, F22, F29, G5, and G33. The experimental results were compared to the calculations performed using MCNP which consisted of the detailed geometrical model of the reactor core. The results from the experimental and calculated normalized reaction rates in the reactor core are in good agreement for both reactions showing that the material and geometrical properties of the reactor core are modeled very well. The results indicated that the difference between the experimental measurements and the calculation of the reactor core using MCNP geometrical model was below 10%. In conclusion MCNP computational model which was used to calculate the neutron flux and reaction rate distribution in the reactor core can be used for others reactor core parameters including neutron spectra calculation, dose rate calculation, power peaking factors calculation and optimization of research reactor utilization in the future with the confidence in the accuracy and reliability of the calculation.

  17. Multi-element characterization of silicon nitride powders by instrumental and radiochemical neutron activation analysis

    Energy Technology Data Exchange (ETDEWEB)

    Franek, M.; Krivan, V. (Ulm Univ. (Germany). Sektion Analytik und Hoechstreinigung)

    1992-07-15

    An optimized instrumental neutron activation analysis method was applied to the comprehensive trace characterization of good- and high- purity silicon nitride powders of different origins. Experimental modes are given for 55 elements leading to limits of detection below 1 ng g[sup -] [sup 1] for 28 elements, between 1 and 100 ng g[sup -1] for 19 elements and higher than 100 ng g[sup -1] for 8 elements. For the removal of the radionuclides [sup 140]La, [sup 182]Ta and [sup 187]W, which cause the major activity in certain types of materials, radiochemical procedures based in cation exchange from 2 M HCl and anion exchange from 2 M HF were developed. [sup 64]Cu was selectively extracted with dithizone from 10 M HF for counting the 511-keV line. By radiochemical neutron activation analysis, the limits of detection were improved by up to three orders of magnitude. Comparison with results obtained by inductively coupled plasma (ICP) atomic emission spectrometry and ICP mass spectrometry shows satisfactory agreement and demonstrates the advantages of neutron activation analysis especially when low elements contents are to be determined. (author). 30 refs.; 2 figs.; 6 tabs.

  18. Comparing performance of K-zero neutron activation. Fresh and freeze-dried animal tissue analysis

    International Nuclear Information System (INIS)

    The success attainable in K-zero neutron activation analysis using a Triga Mark-1 reactor, IPR-R1 CDTN/CNEN, Belo Horizonte - Brazil, operating at 100 MW and thermal neutron flux of 6.6 1011 neutron.cm-2.s-1 - is to a large degree dependent on the sample composition and the upper limit of each element considered. In practice, carrying out investigations on essential and non-essential elements in fresh cattle muscle tissues, only concentrations of major elements which often dominate the gamma-ray spectrum are obtained by virtue of their relative high values. In order to evidence additional elements when their concentrations have values under the upper limits, the pre-concentration of biological matrices before applying K-zero neutron activation analysis will probably be an appropriate alternative. For this purpose, a nondestructive freeze-drying process - lyophilization was carried out in this study due to small losses of chemical elements as reviewed in previous studies. (orig.)

  19. Development of a prompt gamma activation analysis facility using diffracted polychromatic neutron beam

    CERN Document Server

    Byun, S H; Choi, H D

    2002-01-01

    A prompt gamma activation analysis facility has recently been developed at Hanaro, the 24 MW research reactor in the Korea Atomic Energy Research Institute. Polychromatic thermal neutrons are extracted by setting pyrolytic graphite crystals at a Bragg angle of 45 deg. . The detection system comprises a large single n-type HPGe detector, signal electronics and a fast ADC. Neutron beam characterization was performed both theoretically and experimentally. The neutron flux was measured to be 7.9x10 sup 7 n/cm sup 2 s in a 1x1 cm sup 2 beam area at the sample position with a uniformity of 12%. The corresponding Cd-ratio for gold was found to be 266. The beam quality was compared with other representative thermal neutron prompt gamma activation analysis. The detection efficiency was calibrated up to 11 MeV using a set of radionuclides and the (n,gamma) reactions of N and Cl. Finally, the sensitivities and the detection limits were obtained for several elements.

  20. Development of a prompt gamma activation analysis facility using diffracted polychromatic neutron beam

    International Nuclear Information System (INIS)

    A prompt gamma activation analysis facility has recently been developed at Hanaro, the 24 MW research reactor in the Korea Atomic Energy Research Institute. Polychromatic thermal neutrons are extracted by setting pyrolytic graphite crystals at a Bragg angle of 45 deg. . The detection system comprises a large single n-type HPGe detector, signal electronics and a fast ADC. Neutron beam characterization was performed both theoretically and experimentally. The neutron flux was measured to be 7.9x107 n/cm2 s in a 1x1 cm2 beam area at the sample position with a uniformity of 12%. The corresponding Cd-ratio for gold was found to be 266. The beam quality was compared with other representative thermal neutron prompt gamma activation analysis. The detection efficiency was calibrated up to 11 MeV using a set of radionuclides and the (n,γ) reactions of N and Cl. Finally, the sensitivities and the detection limits were obtained for several elements

  1. Development of a prompt gamma activation analysis facility using diffracted polychromatic neutron beam

    Science.gov (United States)

    Byun, S. H.; Sun, G. M.; Choi, H. D.

    2002-07-01

    A prompt gamma activation analysis facility has recently been developed at Hanaro, the 24 MW research reactor in the Korea Atomic Energy Research Institute. Polychromatic thermal neutrons are extracted by setting pyrolytic graphite crystals at a Bragg angle of 45°. The detection system comprises a large single n-type HPGe detector, signal electronics and a fast ADC. Neutron beam characterization was performed both theoretically and experimentally. The neutron flux was measured to be 7.9×10 7 n/cm 2 s in a 1×1 cm 2 beam area at the sample position with a uniformity of 12%. The corresponding Cd-ratio for gold was found to be 266. The beam quality was compared with other representative thermal neutron prompt gamma activation analysis. The detection efficiency was calibrated up to 11 MeV using a set of radionuclides and the (n,γ) reactions of N and Cl. Finally, the sensitivities and the detection limits were obtained for several elements.

  2. VISPECT program evaluation in gamma-ray spectra analysis of neutron-activated geological samples

    International Nuclear Information System (INIS)

    A comparative evaluation of gamma-ray analysis software VISPECT in relation to two commercial gamma-ray analysis software packages OMNIGAM (EG and GORTEC) and SAMPO 90 (CANBERRA) was performed. For this evaluation, artificial gamma-ray spectra were created, presenting peaks of different intensities and located at different regions of the spectrum. Multiplet peaks with equal and different intensities, but with different channel separations were also created. Neutron activation analysis of the reference material GS-N (IWG-GIT) was also performed, aiming the evaluation of the program VISPECT in the analysis of a geological sample. (author)

  3. Determination of carrier yields for neutron activation analysis using energy dispersive X-ray spectrometry

    Science.gov (United States)

    Johnson, R.G.; Wandless, G.A.

    1984-01-01

    A new method is described for determining carrier yield in the radiochemical neutron activation analysis of rare-earth elements in silicate rocks by group separation. The method involves the determination of the rare-earth elements present in the carrier by means of energy-dispersive X-ray fluorescence analysis, eliminating the need to re-irradiate samples in a nuclear reactor after the gamma ray analysis is complete. Results from the analysis of USGS standards AGV-1 and BCR-1 compare favorably with those obtained using the conventional method. ?? 1984 Akade??miai Kiado??.

  4. Neutron activation analysis of final molasses from cuban sugar industry

    International Nuclear Information System (INIS)

    Thermal and epithermal non-destructive activation analyses have been performed on samples of final molasses from 14 different sugar factories , covering the most important regions in Cuba. From the first measurement after irradiation at the Triga Mark reactor (VTT), the concentration of more than 15 elements is reported. The almost constant elemental composition shows that they can be used equally for different purposes as animal foodstuff and for the manufacture of biotechnological products. This work is part of a research project developed in order to establish a complete characterization of Cuban sugar molasses. (author). 7 refs., 2 tabs

  5. Design of a prompt gamma neutron activation analysis system at HANARO

    International Nuclear Information System (INIS)

    The design feature is described for a prompt gamma neutron activation analysis (PGAA) system at HANARO, the 30 MW research reactor in Korea Atomic Energy Research Institute (KAERI). The primary purpose of this system is to analyze boron concentration in biological samples for research of neutron capture therapy. By considering the performance, available space and cost of setup, the PGAA system will use a thermal neutron beam diffracted by pyrolytic graphite (PG) in the existing ST1 horizontal beam line. The energy of monochromatic neutrons is 12.4 meV by setting the Bragg angle of 22.5 deg. The backgrounds will be low due to the use of diffracted beam and be further reduced through a Bi filter and a couple of LiF collimators. A neutron flux of 107 n/cm2sec is expected at sample position. The feature of low backgrounds will permit a closer detector position less than 10 cm from sample while the actual location will be decided upon test measurement. Capture γ-rays of 478 keV from 10B(n,α)7Li reaction will be detected by a 30% n-type HPGe detector and processed by a fast ADC. The goal of detection sensitivity for natural boron is 2,500 cps/mg. By completing the facility, efforts to improve the system performance will be further implemented in parallel with widening application of PGAA to other elements. (author)

  6. Thick activation detectors for neutron spectrometry using different unfolding methods: sensitivity analysis and dose calculation

    Energy Technology Data Exchange (ETDEWEB)

    Medkour Ishak-Boushaki, Ghania, E-mail: gmedkour@yahoo.com [Laboratoire SNIRM-Faculte de Physique, Universite des Sciences et de la Technologie Houari Boumediene, BP 32 El-Alia BabEzzouar, Algiers (Algeria); Boukeffoussa, Khelifa [Laboratoire SNIRM-Faculte de Physique, Universite des Sciences et de la Technologie Houari Boumediene, BP 32 El-Alia BabEzzouar, Algiers (Algeria); Idiri, Zahir [Centre de Recherche Nucleaire d' Alger, 02 Boulevard Frantz-Fanon, BP 399, Algiers (Algeria); Allab, Malika [Laboratoire SNIRM-Faculte de Physique, Universite des Sciences et de la Technologie Houari Boumediene, BP 32 El-Alia BabEzzouar, Algiers (Algeria)

    2012-03-15

    This paper discusses the use of threshold detectors of extended sizes for low intensity neutron fields' characterization. The detectors were tested by the measurement of the neutron spectrum of an {sup 241}Am-Be source. Integral quantities characterizing the neutron field, required for radiological protection, have been derived by unfolding the measured data. A good agreement is achieved between the obtained results and those deduced using Bonner spheres. In addition, a sensitivity analysis of the results to the deconvolution procedure is given. - Highlights: Black-Right-Pointing-Pointer Low intensity neutron fields' characterization using thick threshold detectors. Black-Right-Pointing-Pointer Low activity {sup 241}Am-Be neutron source spectrum measurement. Black-Right-Pointing-Pointer Integral quantities required for radiological protection have been derived. Black-Right-Pointing-Pointer The results are in good agreement with those deduced using Bonner spheres. Black-Right-Pointing-Pointer The results are not very sensitive to the chosen deconvolution procedure.

  7. Prompt gamma ray activation analysis using neutron beam from THOR facility

    International Nuclear Information System (INIS)

    A reactor-based facility for neutron-capture prompt gamma-ray spectrometry for activation analysis has been installed at the one megawatt Tsing Hua Open-pool Reactor. The system consists a neutron beam port with collimators, irradiation stand, external beam tube, neutron beam dump, and counting system. The counting system consists of a 25 % n-type high purity germanium main gamma-ray detector, a 9'' x 10'' NaI(T1) anti-Compton detector shield, and Compton-suppressed electronics coupled to the CANBERRA S-88 Multi-parameter analyzer. Although the neutron beam at the sample irradiation station has an intensity of only 1,300,000 n/cm2s with a cadmium ratio of 26 : 1, the background levels of the on-line measurement in the mixed neutron/gamma field are sufficiently low, resulting a satisfactory detection of many elemental composition in samples. The lower limits of detection of 35 elements in sample matrix of the present system and the current applications are discussed. (author)

  8. Determination of neodymium and gadolinium in geologic samples by neutron activation analysis

    International Nuclear Information System (INIS)

    The determination of Nd and Gd present in rocks by neutron activation analysis is aimed at. A separation procedure for the rare earth group of elements is presented. The method is based on the retention of 233Pa, 182Ta and 46Sc by hydrated antimony pentoxide (HAP) in a 6M HClO4 medium. Those radioisotopes are interferences in the gamma-ray spectrum of 153Gd and 147Nd. The reliability of the method was tested by means of the geological standards BCR-1 and G-2 from the U.S. Geological Survey. The limitations of the instrumental neutron activation analysis and the advantages of the chemical separation are discussed for the special case of the Nd and Gd determinations. (Author)

  9. Determination of mercury contents in head hair of dentists by instrumental neutron activation analysis

    International Nuclear Information System (INIS)

    Mercury contents in head hair of 32 dentists and 30 controls were determined by instrumental neutron activation analysis. The precision and accuracy of the analytical results were checked by independent analytical techniques comprising cold vapour atomic absorption spectrometry and neutron activation analysis combined with lead diethyldithiocarbamate as a preconcentrating agent. The normal range was from 1.91 to 5.44 ppm with an arithmetic mean of 3.90+-1.01 ppm, and the geometric mean of 3.76x:1.33 ppm. The range, arithmetic and geometric means of the values for dentists were 4.32-24.14 ppm, 11.68+-4.70 ppm, and 10.77x:4.04 ppm, resp. The mercury contents in the hair of the dentists are significantly higher than those of the controls. It indicates that dentists in Taiwan do not practice good mercury hygiene. However, the mercury contents are considerably below the toxicity level. (author)

  10. Application of neutron activation analysis to the study of diabetes

    International Nuclear Information System (INIS)

    INAA was a very convenient method for hair analysis. The preliminary results of our clinical study of elemental composition of hair from patients with insulin - requiring diabetes have proved again that scalp hair is a significant health status indicator. We found statistically significant changes of the concentrations of some essential and non-essential elements in the hair of diabetic patients, which may be related with the metabolic disorders specific for the disease. Future studies will need to provide more information on the possible role of some elements in diabetes. Also we intend to broaden the scope of the investigation to many elements and to other types of diabetes, in order to validate the results and the conclusions. (author)

  11. Neutron activation analysis of Urartian pottery from eastern Anatolia

    International Nuclear Information System (INIS)

    A total of 275 pottery and clay samples from Urartian period sites in eastern Anatolia were analyzed by INAA. The pottery sample originates primarily from the fortress and Outer Town at Ayanis and also includes samples from nearby sites in the Lake Van basin. A small sample of pottery from Bastam, a contemporary Urartian fortress in northwest Iran, and Kef Kalesi, a site on the north shore of Lake Van were also analyzed. Ten distinct compositional groups were identified during the course of the analysis suggesting that pottery was produced at multiple locations throughout the Urartian kingdom. In addition to identifying multiple production locales, the long-distance movement of pottery from the sites of Kef Kalesi and Bastam into the Van Basin and the movement of pottery from Ayanis to Bastam were documented. (author)

  12. Neutron activation analysis of amphorae of Roman Gaul. Proving of trade exports at the empire frontiers

    International Nuclear Information System (INIS)

    A bunch of 24 amphorae found in Switzerland and Germany, with types encountered in South-Gaul workshops, has been analyzed with neutron activation. Comparison with the reference groups of the 13 workshops characterized for the moment allowed us to classify 70% of the sampling, either in a workshop precisely, or in an area more or less extended. Cluster analysis is used as a first approach, and a detailed control is then operated taking in account elements mobility and surface of geological outcrops

  13. Monitoring of I-129 in the vicinity of a nuclear power plant by neutron activation analysis

    Czech Academy of Sciences Publication Activity Database

    Kučera, Jan; Světlík, Ivo; Krausová, Ivana

    Universita of Sao Paulo : Nuclear Energy Centre for Agriculture, 2005 - (De Nadai, E.; Sileno, F.), s. 127-127 [International Conference on Nuclear Analytical Methods in the Life Sciences (NAMLS-8). Rio de Janeiro (BR), 17.04.2005-22.04.2005] R&D Projects: GA AV ČR IAA4048301 Institutional research plan: CEZ:AV0Z10480505 Keywords : Iodine-129 * neutron activation analysis * iodine-129/iodine-127 ratio * environment Subject RIV: CB - Analytical Chemistry, Separation

  14. The use of neutron activation analysis in environmental and biomedical research

    Czech Academy of Sciences Publication Activity Database

    Kučera, Jan

    Melville : AMER INST PHYSICS, 2007 - (Granja, C.; Leroy, C.; Štekl, I.), s. 28-32 ISBN 978-0-7354-0472-4. ISSN 0094-243X. - (AIP Conference Proceedings. 958). [4th International Summer School on Nuclear Physics Methods and Accelerators in Biology and Medicine . Praha (CZ), 08.07.2007-19.07.2007] Institutional research plan: CEZ:AV0Z10480505 Keywords : neutron activation analysis * environmental pollutants * Vanadium exposure Subject RIV: CB - Analytical Chemistry, Separation

  15. Determination of trace elements of Egyptian crops by neutron activation analysis Pt. 2

    International Nuclear Information System (INIS)

    Neutron activation analysis, NAA, a high resolution Ge(Li) gamma ray spectrometer was used to determine the concentration of Al, As, Au, Br, Ca, Cd, Co, Cr, Cu, Fe, La, Mn, Mo, Sb, Se, W, and Zn in Cumin, coriander, carrots, and Daucus carota (Umbelliferae Family), alfalfa, Kidney bean, Phaseolus sativus, Phaseolus vulgaris, bean, lentil, and fenugreek (Legumirosae Family). Multielement determination technique on destructive and nondestructive samples was followed. This method is simple, precise and sensitive to 17 trace elements. (author)

  16. Possible use of neutron activation analysis in studying trace elements in senile cataracts

    International Nuclear Information System (INIS)

    The effect of certain life parameters (age, sex, place of residence) on the occurrence of trace elements in turpid human lens (senile cataract) was studied using instrumental neutron activation analysis. The results obtained suggest the dependence of some trace elements deposition in cataracts on age, sex and residence. The work was motivated by the aim to search for possible correlation between the environment and trace elements deposition in eye cataracts. (author)

  17. Monitoring Australian foodstuffs for toxic and essential trace elements using neutron activation analysis

    International Nuclear Information System (INIS)

    A total of nine toxic elements are listed in current Australian legislation for maximum permitted levels in foodstuffs. In addition, the National Health and Medical Research Council (NH and MRC) have published date for the recommended dietary intake of seven essential elements. The use of neutron activation analysis to monitor the levels of these toxic and essential elements in 350 food samples gathered around Australia as a part of the NH and MRC's Market Basket Survey is reviewed. 4 refs

  18. Multielemental analysis by neutron activation of sediments in the Ana Maria Gulf, Cuba

    International Nuclear Information System (INIS)

    In this paper general samples of marine sediments taken from six control stations of the Ana Maria Gulf (Cuba) were analyzed. For this purpose the thermal neutron activation analysis method was used. 18 elements were determinated. They are: Al, Ce, Co, Cs, Cr, Eu, Fe, Hf, La, Lu, Mo, Mn, Rb, Sc, Ta, Th, Yb and Zn. The accuracy varied between 5 and 30% for all elements. 10 refs

  19. Third research coordination meeting on reference database for neutron activation analysis. Summary report

    International Nuclear Information System (INIS)

    The third meeting of the Co-ordinated Research Project on 'Reference Database for Neutron Activation Analysis' was held at the IAEA, Vienna from 17-19 November 2008. A summary of presentations made by participants is given, reports on specific tasks and subsequent discussions. With the aim of finalising the work of this CRP and in order to meet initial objectives, outputs were discussed and detailed task assignments agreed upon. (author)

  20. Characterization of the rhyolitic rocks from the Lela ore body using neutron activation analysis

    International Nuclear Information System (INIS)

    Instrumental neutron activation analysis (INAA) is a well-known analytical method for nondestructive, sensitive and accurate determination of elemental composition of geological samples. In the present work twenty-two elements were determined by INAA in nine rhyolitic geological samples from a wolframium ore body Lela, located in the territory of Isla de la Juventud, Cuba. The obtained results are important for the preliminary geochemical evaluation of the studied rocks. (author)

  1. Instrumental neutron activation analysis of human hair and related radiotracer experiments on washing and leaching

    International Nuclear Information System (INIS)

    The work done under the IAEA-contract 2440/RB is summarized. The aim was to develop a fast and reliable system for the determination of tracer elements in human head hair by instrumental neutron activation analysis (INAA) and radiotracer washing experiments. The standardized procedure for INAA was applied to hair samples collected by the Coronel Laboratory of the University of Amsterdam. The correlation between trace element contents is considered

  2. Determination of trace elements in tobacco using different techniques of neutron activation analysis

    International Nuclear Information System (INIS)

    Quantitative data on trace elements in two tobacco leaf (candidate) reference materials OTL-1 and VTL-2 prepared by the Polish Academy of Sciences and the Institute of Nuclear Chemistry and Technology, Warsaw, Poland, are presented and compared to recommended values, where available. By instrumental neutron activation analysis (INAA), as well as by radiochemical technique (RNAA) 30 elements were quantitatively determined and fair agreement was found between the results and recommended values for the first material. (author) 18 refs.; 5 tabs

  3. Elementary composition in sewer silt and vermicomposting by instrumental neutron activation analysis

    International Nuclear Information System (INIS)

    The purpose of this study is to demonstrate elementary composition in sewer silt and vermicomposting method produced by oligoquetas for the application of the technique of instrumental neutron activation analysis. As the gotten results, were possible according to inquire that the texts found in the samples are very below of the acceptable maximum values, North American norm 40 CRF Prat 503, elaborated for the Agency of Ambient Protection of the United States and used as reference in Brazil. (author)

  4. Characterization of inorganic compounds in nutritional supplements by the instrumental neutron activation analysis

    International Nuclear Information System (INIS)

    In this work instrumental neutron activation analysis was applied in the analyses of samples of nutritional supplements in order to evaluate the composition of their essential inorganic components. Results obtained in these analyses presented, in general, a good agreement with the label values. Precision and accuracy of the results were also evaluated by analyzing NIST 2704 Buffalo River Sediment and NIST 1400 Bone Ash reference materials. (author)

  5. Determination of Inorganic Elements in White Rice by Neutron Activation Analysis

    Energy Technology Data Exchange (ETDEWEB)

    Moon, J. H.; Kim, S. H.; Lim, J. M.; Lee, Y. N.; Chung, Y. S. [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2011-05-15

    Rice is a staple food and provides an important information of mineral supplement as well as a large portion of calorie for Korean. As scientists have focused their researches on health impacts caused by mineral nutrient deficiency and hazardous elements, public concerns about mineral intake by dietary food is rising. The objectives of this study were to determine inorganic elemental contents in white rice by neutron activation analysis(NAA) and to assist the evaluation of nutritional and harmful status for Korean people

  6. Elemental concentration determination in certain medicinal leaves by K0 instrumental neutron activation analysis

    International Nuclear Information System (INIS)

    Elemental concentrations of two types of medicinal leaves (neem and eucalyptus) are determined by neutron activation analysis using single comparator (K0 NAA) method. Data obtained on one of the varieties studied (neem), collected from two different places, have also been used to see the effect of soil condition. The method was validated by analysing the SRM-1571 and it was found that the measured elemental concentrations in SRM-1571 are within ±9% of the reported values. (author)

  7. Identification of the provenience of Majolica from sites in the Caribbean using neutron activation analysis

    Energy Technology Data Exchange (ETDEWEB)

    Olin, J.S.; Sayre, E.V.

    1975-01-01

    Tin-enamelled earthenware pottery from five early Spanish Colonial sites in the Dominican Republic and Venezuela were sampled and analyzed by neutron activation analysis in an attempt to determine whether these sherds had a common source. The tentative conclusion was that although several sources were indicated for the specimens analyzed the overall similarity in composition indicated that these sources were probably closely related. (JSR)

  8. Application of the k0 parametric neutron activation technique in the industrial reforestation soil analysis

    International Nuclear Information System (INIS)

    This work identifies and establishes the concentration of some minerals nutrients in Mata Atlantica and Vale do Aco Eucalyptus (Minas Gerais State, Brazil) soils. The k0 method of analysis with neutron activation and X-ray fluorescence were used. Reference material were used to check the accuracy of the analytical results. The k0 method is being introduced in CDTN using the CDTN/CNEN-B H IPR-R1 TRIGA Mark I reactor. (author). 5 refs., 2 tabs

  9. The preparation of synthetic standards for use in instrumental neutron-activation analysis

    International Nuclear Information System (INIS)

    An account is given of the formulation and preparation of synthetic standards suitable for the routine analysis of minerals, ores, and ore concentrates by instrumental neutron activation. Fifteen standards were prepared, each containing from one to seven elements. The standards contain forty-four elements that produce isotopes with half-lives longer than 12 hours. An evaluation of the accuracy and precision of the method of preparation is given

  10. Instrumental neutron activation analysis of Malaysian off-shore carbonate samples irradiated in a nuclear reactor

    International Nuclear Information System (INIS)

    The elemental abudances of the USGS standard rock AGV-1 and two Malaysian off-shore drill core carbonate samples (off Sarawak) are studied by the method of Neutron Activation Analysis. One major element (Fe) and 23 trace elements (Sc, Cr, Co, Rb, Sr, Zr, Sb, Cs, Ba, La, Ce, Nd, Sm, Eu, Tb, Ho, Yb, Lu, Hf, Ta, Au, Th and U) have been determined using reactor irradiations and high-resolution gamma-ray spectrometry. (author)

  11. Trace element analysis of human head hair by neutron activation technique

    International Nuclear Information System (INIS)

    28 elements in reference hair sample (HH-1) and 44 hair samples of Seoul, Korea have been analyzed by instrumental neutron activation analysis. The analytical results of reference sample agreed well with those of the IAEA report within 10% deviation except those of some elements. For the 44 hair samples of Seoul, the range of content of each element is fallen in +-3σ from his mean value if rejecting one or two of the highest data. (author)

  12. Determination of trace elements in a cigarette paper by neutron activation analysis

    International Nuclear Information System (INIS)

    The concentration of 19 trace elements in a cigarette paper (Zig-Zag Paper Company, France) which is used in making different brands of Iranian cigarettes, has been measured by neutron activation analysis, employing a high-resolution Ge(Li) detector. They include Na, K, Ca, Sc, Cr, Mn, Fe, Co, Zn, Br, Sr, Sb, Ba, Ce, Eu, Gd, Au, Hg, and Th. (author)

  13. Neutron activation analysis of the rat thyroid: Determination of the concentration ratio I/Br

    Czech Academy of Sciences Publication Activity Database

    Pavelka, Stanislav

    Brno: Masarykova univerzita, 2008. s. 89-89. ISBN 978-80-210-4526-2. [Pracovní setkání biochemiků a molekulárních biologů /12./. 05.02.2008-06.02.2008, Brno] Grant ostatní: GA AV ČR(CZ) KJB401630701 Institutional research plan: CEZ:AV0Z50110509 Keywords : spo2 * neutron activation analysis * iodine Subject RIV: BO - Biophysics

  14. Determination of trace elements in chewing gum by neutron activation analysis

    International Nuclear Information System (INIS)

    Six trace elements of nutritional or toxicological interest (Al, Ca, Cl, Mn, Na and Sr) were determined in three different brands of chewing gum by instrumental neutron activation analysis. For the particular brands of gum examined, none of the detected elements was found to be present at a level representing a substantial contribution to the total dietary intake of the element for an American adult. (author) 11 refs.; 3 tabs

  15. Study of arsenic and molybdenum retention in organism during hydrotherapy by neutron activation analysis

    International Nuclear Information System (INIS)

    At La Bourboule (France), arsenic and molybdenum are contained in high concentrations in the spring water used for hydrotherapy. Thermal neutron activation analysis was applied to determine arsenic and molybdenum penetration into the organism for the first time. The results obtained with children, men and rabbits are similar. The chronology of the absorption of arsenic and molybdenum in blood and urine during the treatment is in good accordance with the medical therapeutic observations. (author) 10 refs.; 10 figs.; 10 tabs

  16. Calculation of corrections in the neutron activation analysis of oxygen in powdered and granulated materials

    International Nuclear Information System (INIS)

    Presented is a formula for the correction calculation at the analysis of oxygen in materials by the neutron activation method. A nomogram is plotted for the calculation of corrections taking into account the oxygen of capsule material and of air being in the internal volume of the capsule due to its incomplete filling. The accuracy of corrections according to nomogram is 2-3x10-4 mass %

  17. Determination of pollutants in dwellings by neutron activation analysis and x-ray fluorescence

    International Nuclear Information System (INIS)

    Metallic pollutants were measured in dwellings in Mexico city by instrumental neutron activation analysis (INAA) and x-ray fluorescence techniques. Monitoring was performed in the west side of the city and in the winter season. In general the average concentration of contaminants collected, when compared with average concentrations reported in a previous paper, have increased with time and in the particular case of lead and mercury some samples are above the indicative WHO maximum levels. (author)

  18. Characterization of obsidian devices come from San Miguel Ixtapan, Estado de Mexico by Neutron Activation Analysis

    International Nuclear Information System (INIS)

    The Neutron Activation Analysis (NAA) is an efficient multielemental technique for determination of elements in low concentration (ppm), what has been result useful in the study of origin of archaeological material. In this work that technique was used for characterizing obsidian devices coming from the San Miguel Ixtapan site, Estado de Mexico and it was found that these come from three important beds which are: Sierra de Pachuca, Hidalgo, Zinapecuaro and Zinaparo-Varal in the Michoacan state. (Author)

  19. Elemental comparison in sound and carious human teeth by instrumental neutron activation analysis

    International Nuclear Information System (INIS)

    Instrumental neutron activation analysis (INAA) was applied to determine Ca, Cl, Mg, Mn, Na, Sr and Zn in human dentin and enamel tissues from carious and sound teeth. Comparisons were made between the results obtained in carious and sound dental tissues for dentin and enamel. The findings obtained were also compared with the published data. Accuracy and precision of the results were evaluated by analyzing certified reference material. (author)

  20. Neutron activation analysis of airborne thorium liberated during welding operations

    Energy Technology Data Exchange (ETDEWEB)

    Glasgow, D.C.; Robinson, L.; Janjovic, J.T.

    1996-02-01

    Typically, reactive metals such as aluminum are welded using a thoriated tungsten welding electrode which is attached to a source of argon gas such that the local atmosphere around the weld is inert. The metal is heated by the arc formed between the electrode and the grounded component to be welded. During this process, some of the electrode is vaporized in the arc and is potentially liberated to the surrounding air. This situation may result in a hazardous airborne thorium level. Because the electrode is consumed during welding, the electrode tip must be repeatedly dressed by grinding the tip to a fine point so that the optimal welding conditions are maintained. These grinding activities may also release thorium to the air. Data generated in the 1950s suggested that these electrodes posed no significant health hazard and seemed to justify their exemption from licensing requirements for source material. Since that time, other studies have been performed and present conflicting results as to the level of risk. Values both above and below the health protection limit in use in the United States, have been reported in the literature recently. This study is being undertaken to provide additional data which may be useful in evaluating both the chemical toxicity risk and radiological dose assessment criteria associated with thoriated tungsten welding operations.

  1. The affect of industrial activities on zinc in alluvial Egyptian soil determined using neutron activation analysis

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    Thirty-two surface (0-20 cm) soil samples were collected from different locations in Egypt representing non-polluted,moderately and highly polluted soils.The aim of this study was to evaluate total Zn content in alluvial soils of Nile Delta in Egypt by using the delayed neutron activation analysis technique (DNAA),in the irradiation facilities of the first Egyptian research reactor (ET-RR-1).The gamma-ray spectra were recorded with a hyper pure germanium detection system.The well resolved gamma-ray peak at 1116.0 kev was efficiently used for 65Zn content determination.Zn content in non-polluted soil samples ranged between 74.1 and 103.8 ppm with an average of 98.5 + 5.1 ppm.Zn content in moderately polluted soils ranged between 136.0 and 232.5 ppm with an average of 180.1 + 32.6 ppm.The highest Zn levels ranging from 240.0 and 733.0 ppm with an average of 410.3 + 54.4 ppm,were observed in soil samples collected from,either highly polluted agricultural soils exposed to prolonged irrigation with industrial wastewater or surface soil samples from industrial sites.

  2. Second Research Coordination Meeting on Reference Database for Neutron Activation Analysis. Summary Report

    International Nuclear Information System (INIS)

    The second meeting of the Co-ordinated Research Project on 'Reference Database for Neutron Activation Analysis'; was held at the IAEA, Vienna from 7-9 May, 2007. A summary of the presentations made by participants is given, along with reports on specifically assigned tasks and subsequent discussions. In order to meet the overall objectives of this CRP, the outputs have been reiterated and new task assignments made. The aims of the Co-ordinated Research Project (CRP) on 'Reference Database for Neutron Activation Analysis' are to improve the status of the database of nuclear constants for k0-NAA, to contribute to the quantification of nuclear structure and decay data, and to remove or reduce some of the discrepancies that exist between the integral constants and values derived from differential data. This CRP originated following the support of the International Nuclear Data Committee (INDC) which advises the Nuclear Data Section (NDS) on nuclear data issues. The INDC recommended in the Summary Report of their meeting of May 2002, INDC/P(02)-23, that a CRP on 'Reference Database for Neutron Activation Analysis' be initiated in 2005

  3. Determination of arsenic in food and dietary supplement standard reference materials by neutron activation analysis

    International Nuclear Information System (INIS)

    Arsenic was measured in food and dietary supplement standard reference materials by neutron activation analysis for the purpose of assigning certified or reference As mass fractions and to assess material homogeneity. Instrumental neutron activation analysis was used to value assign As in candidate SRM 3532 Calcium Dietary Supplement and candidate SRM 3262 Hypericum perforatum (St. John's Wort) Aerial Parts down to about 100 μg/kg. Values were also determined for two additional candidate St. John's Wort SRMs with As mass fractions 24Na and 82Br limited the reproducibility of the method below 100 μg/kg. For measurement of lower As mass fractions, a radiochemical neutron activation analysis method with extraction of As3+ into diethyl-dithiocarbamate in chloroform and detection limits down to 0.1 μg/kg. As was used to value-assign As mass fractions for SRM 3280 Multivitamin/Multielement Tablets and for candidate SRM 3233 Fortified Breakfast Cereal, and at <10 μg/kg in candidate SRM 1845a Whole Egg Powder. (author)

  4. Study on the simultaneous measurement of fluorine and calcium in human teeth by neutron activation analysis

    International Nuclear Information System (INIS)

    This study was undertaken to examine the potential of neutron activation analysis in the simultaneous measurement of F and Ca concentrations responsible for the occurence of dental caries. The contents of F and Ca were found to be 556±43.6 ppm and 26.3±1.5%, respectively, in the dental powder samples. These results were in good accordance with those with other routine chemical analysis. The neutron activation method allowed F and Ca contents to be measured simultaneously; F and Ca contents in the upper central incisor was 298±38 ppm and 23.0±3.5%, respectively, on the left side and 261±40 ppm and 24.9±4.7%, respectively, on the right side. For the upper cuspid , F and Ca contents were 312±34 ppm and 24.4±1.1%, respectively; the corresponding figures were 276±52 ppm and 21.8±1.8% for the upper first molar. Regarding F and Ca contents, there was no significant difference between these teeth. In conclusion, neutron activation analysis is very useful for measuring F and Ca contents in teeth because of its high sensitivity, non-destructivivity and simultaneous measurement of multiple elements. (N.K.)

  5. Multi trace element analysis of dry biological materials by neutron activation analysis including a chemical group separation

    International Nuclear Information System (INIS)

    Multi-element analysis of dry biological material by neutron activation analysis has to include radiochemical separation. The evaporation process is described in terms of the half-volume. The pretreatment of the samples and the development of the destruction-evaporation apparatus are described. The successive adsorption steps with active charcoal, Al2O3 and coprecipitation with Fe(OH)3 are described. Results obtained for standard reference materials are summarized. (G.T.H.)

  6. Analysis of Canoparmelia texana lichens collected in Brazil by neutron activation analysis

    International Nuclear Information System (INIS)

    The accumulation of elements by lichens is well known. Therefore analyses of lichen samples have been carried out in order to use this kind of material in environmental studies. In this work, the epiphytic lichen Canoparmelia texana collected from the bark of trees was analyzed by instrumental neutron activation analysis. The preparation of samples consisted of cleaning, washing with water, lyophilization and grinding. Elements Al, As, Br, Ca, Cd, Ce, Cl, Co, Cr, Cs, Cu, Eu, Fe, K, La, Lu, Mg, Mn, Mo, Na, Rb, Sb, Sc, Se, Sm, Tb, Th, Ti, U, V, Yb, and Zn were determined quantitatively by using short and long irradiations carried out under a thermal neutron flux from 1011 to 1013 n cm-2 s-1 in the IEA-R1 nuclear reactor. Radioactivity measurements were performed by using a hyperpure Ge detector. Results obtained by analyzing a sample of Canoparmelia texana species in replicates revealed a good precision with relative standard deviations varying from 0.5 to 15%. Also the precision and the accuracy of the method were evaluated by analyzing reference materials IAEA 336 Lichen, NIST 1575 Pine Needles and 1572 Citrus Leaves. In order to study the influence of age of the lichen, in the collection, the center and outer fraction of each sample were collected separately. For some elements the center of the lichen sample presented slightly higher concentrations than the outer fraction, indicating that the accumulation of the elements increases with the lichen age or with the length of exposure. Results obtained for lichens collected from different trees from the same sampling area showed relative standard deviations varying from 20 to about 60%. (author)

  7. Trace analysis measurements in high-purity aluminium by means of radiochemical neutron and proton activation analysis

    International Nuclear Information System (INIS)

    The aim of the study consisted in the development of efficient radiochemical composite processes and activation methods for the multi-element determination of traces within the lower ng range in high-purity aluminium. More than 50 elements were determined with the help of activation with reactor neutrons; the selective separation of matrix activity (adsorption with hydrated antimony pentoxide) led to a noticeable improvement of detectability, as compared with instrumental neutron activation analysis. Further improvements were achieved with the help of radiochemical group separations in ion exchangers or with the help of the selective separation of the pure beta-emitting elements. Over 20 elements up to high atomic numbers were determined by means of activating 13 MeV protons and 23 Me protons. In this connection, improvements of the detection limit by as a factor of 10 were achieved with radiochemical separation techniques, as compared with pure instrumental proton activation analysis. (RB)

  8. Determination of Magnesium in Needle Biopsy Samples of Muscle Tissue by Means of Neutron Activation Analysis

    International Nuclear Information System (INIS)

    Magnesium has been determined by means of neutron-activation analysis in needle biopsy samples of the order of magnitude 1 mg dry weight. The procedure applied was to extract the Mg-27 activity from irradiated muscle tissue with concentrated hydrochloric acid followed by a fast hydroxide precipitation and gamma-spectrometric measurements. The Mg activity was recovered in the muscle tissue samples to (97 ± 2) per cent. The sensitivity for the magnesium determination is estimated as 0.3 μg

  9. In vivo measurement of calcium by prompt-gamma neutron activation analysis

    International Nuclear Information System (INIS)

    This paper describes phantom experiments to assess the feasibility of measuring both part- and total-body calcium by the prompt - as opposed to the more usual delayed - neutron activation technique. The results indicate that a 30 min irradiation of a 20 cm length of the lumbar spine with a collimated beam of 252Cf neutrons, would yield approximately 2500 counts in the 6.420 MeV main and escape peaks, with a statistical precision of less than 5%, for a dose equivalent of 20 mSv. The proposed detection system, consisting of two 20% efficient germanium detectors positioned above the subject, i.e. on the side opposite the incident neutron beam, would provide improved uniformity of measurement compared with the usual situation where activation and counting are performed from the same side. The on-line technique also enables the subject to be scanned across the neutron beam to provide a measure of total-body calcium. In this case it would be possible to make an analysis to the same degree of precision for an average whole-body dose equivalent of only 1 to 1.3 mSv. 10 references, 3 figures, 1 table

  10. Use of neutron activation analysis at the IBR-2 reactor for atmospheric monitoring

    International Nuclear Information System (INIS)

    The object of this work was the study of the possibilities of neutron activation analysis (NAA) for determination of elemental content of atmospheric aerosol. On examples of three Siberian regions it was shown that methodics of analysis allow to estimate the average level of suburban background (ALSB), scale of its regional, season and annual changes. Analysis of enrichment factors allows one to convince in presence of increased content of a row of heavy metals in atmospheric air of background regions what is the consequence of a global growing of technogenic impact

  11. Rare earth element determination in silicate rocks using neutron activation analysis and mass spectrometry

    International Nuclear Information System (INIS)

    A pre-irradiation group separation procedure for the quantification of 11 to 13 rare earth elements (REE) in geological materials by neutron activation analysis, with yield determination by mass spectrometry isotope dilution analysis of Sm and Nd, is described. Utilization of the shorter-lived isotopes of the REE allow sufficient data for most geochemical studies to be obtained within one day of irradiation, although where necessary, additional information may be obtained following a decay period of three to four weeks. Analysis of selected USGS rock standards shows the method to be both accurate and precise. (author)

  12. A comparison of neutron activation analysis and inductively coupled plasma mass spectrometry for trace element analysis of biological materials

    International Nuclear Information System (INIS)

    Fifty individual food types were analysed by instrumental and radiochemical neutron activation analysis as well as inductively coupled plasma mass spectrometry after testing all techniques by analysing IAEA mixed human diet, H-9. The performance of these trace element techniques and their limitations were evaluated under normal, routine, multielement surveys of a large range of solid biological materials. (author) 18 refs.; 2 tabs

  13. Analysis of Essential Elements for Plants Growth Using Instrumental Neutron Activation Analysis

    Directory of Open Access Journals (Sweden)

    R. L. Njinga

    2013-01-01

    Full Text Available In this study, a total of ten essential elements for plants growth in the Guinea savanna region of Niger State in Northern Nigeria have been identified in the soils using instrumental neutron activation analysis. The experimental results show good agreement with certified or literature values within the agreed percentage range of ±2.35% to ±8.69%. However, the concentration distributions of the ten identified elements in the soil samples within the studied area for plants growth revealed the following: Fe (123.4 ppm, Mn (2100.7 ppm, K (5544.3 ppm, Al (54752.4 ppm, Ti (3082.9 ppm, Ca (4635 ppm, V (54.3 ppm, Na (857.5 ppm, Mg (13924.1 ppm, and Dy (12.1 ppm. A further analysis of the two fundamental soil physical parameters for healthy growth of some common crops like egusimelon, groundnut, rice, yams, soybeans, cassava, and potato analyzed in this work revealed a pH range of 4.0 pH–8.0 pH and a temperature range of 28.0°C to 29.3°C, which are optimal for plant nutrients availability in the soils within the study area.

  14. Active neutron instrumentation

    International Nuclear Information System (INIS)

    An introduction to neutron interactions in tissue and a discussion of pertinent nuetron cross-sections will be given. A brief description of the statistics of energy deposition due to interactions of neutron secondaries in tissue equivalent media is presented. Present and past techniques for measurement of neutron radiation fields are given with advantages and disadvantages in the light of legal limits and proposed changes in those requirements. Neutron dose measuring devices, such as the tissue equivalent proportional counter (TEPC) developed by Rossi, are discussed with emphasis on their response in varying neutron energy spectra. Techniques for determining neutron quality factors from TEPC response functions are discussed along with implications of possible new definitions of quality factor. A brief description of high-resolution spectrometry systems, which use hydrogen, methane and He-3 fill gases, is given with discussion of their limitations. Low resolution systems, such as multisphere spectrometers and activation foils, are also presented

  15. Air pollution assessment in two Moroccan cities using instrumental neutron activation analysis on bio-accumulators

    International Nuclear Information System (INIS)

    Full text: Biomonitoring is an appropriate tool for the air pollution assessment studies. In this work, lichens and barks have been used as bio-accumulators in several sites in two Moroccan cities (Rabat and Mohammadia). The specific ability of absorbing and accumulating heavy metals and toxic element from the air, their longevity and resistance to the environmental stresses, make those bioindicators suitable for this kind of studies. The Instrumental Neutron Activation Analysis (INAA) is universally accepted as one of the most reliable analytical tools for trace and ultra-trace elements determination. Its use in trace elements atmospheric pollution related studies has been and is still extensive as can be demonstrated by several specific works and detailed reviews. In this work, a preliminary investigation employing lichens, barks and instrumental neutron activation analysis (INAA) was carried out to evaluate the trace elements distribution in six different areas of Rabat and Mohammadia cities characterised by the presence of many industries and heavy traffic. Samples were irradiated with thermal neutrons in a nuclear reactor and the induced activity was counted using high-resolution Germanium-Lithium detectors. More than 30 elements were determined using two modes : short irradiation (1 minute) and long irradiation (17 hours). Accuracy and quality control were assessed using the reference standard material IAEA-336. This was less than 1% for major and about 5 to 10% for traces.

  16. Neutron activation analysis determination of trace amounts of mercury in selected foodstuffs

    International Nuclear Information System (INIS)

    Neutron activation analysis was used for the determination of trace amounts of mercury in powdered milk, flour, coffee, rice and tea. The results of the determination were compared with the photometric determination of mercury using dithizone. Four wet mineralization procedures were also assessed with regard to mercury release during sample destruction. Following thermal neutron irradiation and the addition of a carrier the samples were mineralized with a mixture of H2SO4+HClO4+HNO3; the mineralization product was diluted and extracted by a substoichiometric amount of dithizone-chloroform solution. The activity of 197Hg in the organic phase was measured with a NaI(Tl) crystal. The determination threshold was found to be 0.003 μg Hg at a mean error of 15%. (B.S.)

  17. Activation analysis of pit-coal ash content with the use of isotopic fast neutron source

    International Nuclear Information System (INIS)

    The neutron activation techniques of coal ash determination are briefly reviewed and a new version of activation analysis using fast neutrons from 239Pu-Be source and basing on the reactions 28Si(n,p)28Al and 27Al(n,p)27Mg is proposed. 72 samples of pit-coals with ash content ranging from 3 to 40% were measured. The linear calibration function between ash content and both, 1.78 MeV and 0.84 MeV, γ-ray counts was obtained. The precision (0.94% ash for 17% ash content) and accuracy (1.4%ash for the whole range) were evaluated. Comparison of the results with those of fluorescent-scattering methods is made. (author)

  18. Determination of 2,4-D in aqueous solution by neutron activation analysis

    International Nuclear Information System (INIS)

    A method based on neutron activation analysis was developed for the determination of fractions of milligrams of 2,4-D (2,4-dichlorophenoxy acetic acid) in aqueous solution in laboratory tests. The indirect determination of 2,4-D was based on the quantification of chlorine, 38Cl, produced by neutron activation. The range of application was 0.01 - 100 mg x l-1. No loss of 38Cl by chemical effects of the nuclear reaction was found. The advantages of the proposed method include high precision and sensitivity of determination. Results were compared with those obtained by UV-Vis spectrophotometry, where concentrations less than 1 mg x l-1 were not detected. (author)

  19. Determination of radioactive trace elements in ultra low background detectors by means of neutron activation analysis

    International Nuclear Information System (INIS)

    In this paper new analytical methods for the determination of naturally occurring radionuclides are being presented. They combine neutron activation, radiochemical separation and coincidence counting techniques. For complex matrices such as organic liquids and silicon we have obtained detection limits lower than 10-14 g/g for Th, U, La and lower than 10-12 g/g for Cd, In, K, Lu, and Rb with radiochemical separation methods geared to the nuclides investigated. The β-γ coincidence counting techniques used for the determination of U, Th and Lu in the ultra trace region are discussed in detail, with recorded spectra and applied selection criteria for the evaluation of decay events. Impacts of the results on low level experiments in the field of astro and particle physics are being discussed as well as the advantage of neutron activation analysis which is sensitive to most naturally occurring radionuclides. (author)

  20. Development of a gamma ray spectrometry software for neutron activation analysis using the open source concept

    International Nuclear Information System (INIS)

    This study developed a specific software for gamma ray spectra analysis for researchers of the Neutron Activation Laboratory (LAN), which was named SAANI (Instrumental Neutron Activation Analysis Software). The LAN laboratory of the Institute for Research and Nuclear Energy (IPEN-CNEN/SP), uses a multielemental analytical technique, based on irradiation of a sample by a flux of neutrons from a nuclear reactor, which induces radioactivity. The sample is then placed in a gamma-ray spectrometer, to obtain the spectrum. With free software philosophy in mind, this software will replace the existing software VISPECT / VERSION 2. The new software's main features are: a friendlier interface; easier standardization procedure carried out by LAN staff and researchers; adapted to the use of plug technology; multi platform and code free. The software was developed using the programming Python language, the library Trolltech Qt graphics and some of their scientific extensions. Preliminary results using the SANNI software were compared to those obtained with the existing software and were considered good. There were some errors in accuracy during the implementation of the software. The SAANI software has been installed in selected computers to be used for routine analysis in order to verify its strength, accuracy and usability. (author)

  1. Instrumental neutron activation analysis of iron and zinc in compact cosmetic products

    International Nuclear Information System (INIS)

    An instrumental neutron activation analysis method is described for the determination of iron and zinc in compact eye shadow, compact face powder and compact rouge make-up cosmetic products. The steps of the procedure are: Irradiation of samples with thermal neutrons, counting of gamma-radioactivity of the radioisotopes of iron and zinc produced by this irradiation and calculation of the concentration of these elements from the gamma-ray spectra of samples and standards. Analysis of the I.A.E.A. standard reference material by this procedure give results in close agreement with certified values. The limit of quantitation is 45 μg for iron and 0.35 μg for zinc. The developed procedure could possibly be established as an official method for the simultaneous determination of iron and zinc in compact cosmetic products. (orig.)

  2. Self-sustainability of a research reactor facility with neutron activation analysis

    International Nuclear Information System (INIS)

    Long-term self-sustainability of a small reactor facility is possible because there is a large demand for non-destructive chemical analysis of bulk materials that can only be achieved with neutron activation analysis (NAA). The Ecole Polytechnique Montreal SLOWPOKE Reactor Facility has achieved self-sustainability for over twenty years, benefiting from the extreme reliability, ease of use and stable neutron flux of the SLOWPOKE reactor. The industrial clientele developed slowly over the years, mainly because of research users of the facility. A reliable NAA service with flexibility, high accuracy and fast turn-around time was achieved by developing an efficient NAA system, using a combination of the relative and k0 standardisation methods. The techniques were optimized to meet the specific needs of the client, such as low detection limit or high accuracy at high concentration. New marketing strategies are presented, which aim at a more rapid expansion. (author)

  3. Determination of short-lived trace elements in environmental samples by neutron activation analysis

    International Nuclear Information System (INIS)

    Concentration of a short-lived trace elements in environmental samples were determined by neutron activation analysis, a counting loss often occur due to the high counting rate. A Pile-Up Rejecter (PUR) electric circuit was installed in counting a short-lived trace elements by a γ-ray spectrometer in order to correct a counting loss. The samples were irradiated for 30∼60 seconds at neutron flux of 3.5 x 1012n.cm-2.s-1, then the samples cooled for 120 second and counted for 180 second using this system. The nuclides concentration in the varieties environmental samples have a difference analysis result, was more accurate and precise, which the measured result would be 30 % more higher by PUR system than the result would be counted using a conventional γ-ray spectrometry method

  4. Forensic and environmental aspects of neutron activation analysis of single human hairs

    International Nuclear Information System (INIS)

    A new analytical procedure consisting of special washing step, irradiation in a thermal neutron flux of 1014n cm-2s-1, and Ge(Li) spectrometry enabled to determine as many as 14 elements in a 3 cm segment of a single human hair by neutron activation analysis. The criminalistic aspects of hair analysis were studied using a new statistical criterion for elimination/identification and an appropriate computer program was constructed. Hair dimensions as measured microscopically were used as additional individualizing attributes. It was shown that despite the dif--ficulties originating from from a relatively large intrinsic variation of the trace element concentration over one head, elimination of most or nearly all of the ''suspects'' could be achieved in simulated cases. Distincly elevated levels of Au as well as Cu and Ag were found in hair of some groups of persons working under specific conditions thus confirming the importance of the environmental factor related to some kinds of occupation. (author)

  5. The simultaneous determination of 235U and 239Pu using delayed neutron activation analysis

    International Nuclear Information System (INIS)

    Delayed neutron activation analysis (DNAA) remains one of the most sensitive methods of nondestructively determining fissile materials in a variety of sample matrices, provided that the samples contain only a single fissile component. This has historically been the limiting factor in many applications of DNAA, and often chemically destructive methods of analysis have needed to be utilized for many real-world samples. This work seeks to develop a method that will allow for DNAA to be utilized on samples containing multiple fissile components. Initial efforts, presented here, show that using a multivariate linear regression model to describe the delayed neutron emission profile of an irradiated sample allows for the concurrent determination of fissile nuclides in samples containing both 235U and 239Pu, without chemical separations and using only a single counting step. (author)

  6. Multi-element determination of sandstone rock by instrumental neutron activation analysis

    International Nuclear Information System (INIS)

    The instrumental neutron activation analysis technique (INAA) was used in the qualitative and quantitative analysis of sandstone samples from Aswan area in South Egypt. The samples were properly prepared together with their standards and simultaneously irradiated in a neutron flux of 7 x 1011 n/cm2.s in the TRIGA Mainz research reactor facilities. Gamma spectra from hyper pure germanium HPGe detector were analysed. The present study provides the basic data of elemental concentrations of sandstone rock. The following elements constituents have been determined: Na, K, Fe, Sc, Cr, Co, Zr, Ce, La, Nd, Sm, Eu, Yb, Lu, Hf, Ta, Th and U. The x-ray fluorescence (XRF) was used for comparison and to detect elements which can be detected only by XRF. (author)

  7. Studies on application of radiation and radioisotopes -Studies on application of neutron activation analysis-

    International Nuclear Information System (INIS)

    To apply Neutron activation analysis to routine analysis of environmental samples utilizing the research reactor (TRIGA MK-III), improving effects of analytical sensitivity have been investigated using both of thermal and epithermal neutron irradiating technique. Identification and development of analytical procedure was carried out using three kinds of standard reference materials (urban particulate matter, coal fly ash, soil). In addition, the confidence of this method was established by participation in collaborative research for the training and apply of international credit of analytical procedure. Practical studies on air dust samples have also been carried out regionally and seasonally. For the investigation on emission source of special element, enrichment factor was calculated in urban and rural area. Besides, a suitable process of biological sample (pine needle) analyses has been established by carrying out identification of uncertainty using standard reference material. The concentration of elements in practical samples were also determined regionally and seasonally. 14 figs, 26 tabs, 67 refs. (Author)

  8. Determination of x mercury trace amounts in selected foodstuffs by neutron activation analysis

    International Nuclear Information System (INIS)

    Neutron activation analysis was used for the analysis of dehydrated milk, flour, coffee, tea and rice. The results were compared with those obtained by the photometric determination of mercury by dithizone. Four types of sample distribution by wet ashing were evaluated with regard to mercury volatilization in sample destruction. The samples were irradiated with thermal neutrons, a carrier was added and the samples were dissolved in the mixture of H2SO4+HClO4+HNO3. After dilution mercury was extracted using a substoichiometric amount of dithizone dissolved in chloroform. In the extract the radioactivity of 197Hg was measured by NaI(Tl). At the average 15% accuracy of determination the lower limit of determination is 0.003 μg Hg. (M.K.)

  9. Determination of phosphorus in kiwicha using analysis for activation with fast neutrons

    International Nuclear Information System (INIS)

    In this study it has been used the technique of activation analysis with fast neutrons for nondestructive of Phosphorus in Kiwicha (amaranthus caudatus l.), as an alternative to the conventionally used technique of spectrophotometry. The samples are irradiated during five minutes in the IPEN's neutron generator under a fast flow of around 109n/cm2.s after 30 seconds of the irradiation end, and are counted for 10 minutes in a NaI(Tl) detector type well jointed to a multichannel analyzer. The testing of method exactness was carried out analyzing the IAEA's H5 and H8 reference materials, obtaining a good correspondence with the certified values. The reproducibility of the method was carried out analyzing by repetition a pure standard sample of phosphorus. In the analysis of 8 samples of kiwicha it was found that the phosphorus content is in the rank of 0.3% to 0.5%. (author). 31 refs., 12 tabs., 19 figs

  10. Contributions to the prompt neutron activation analysis of industrially used coals and zinc roasting products

    International Nuclear Information System (INIS)

    The construction of an irradiation plant for calibration measurement by means of prompt neutron activation analysis is described. A 5.84 μg and 16.3 μg Cf-252 source serve as neutron sources. Tests have shown an inner centred arrangement to offer the best solution for sources of this strength. The use of the PNAA method for determining sulphur, iron and chloride content in brown coal was tested and calibration curves drawn. The sulphur content of the coal briquettes tested was found to be 0.27% S, the iron content amounting to 0.21% Fe and chloride to 0.06%. These values correlate closely with values obtained from wet chemical industrial analysis. (WI)

  11. Uncertainty Estimation of Neutron Activation Analysis in Zinc Elemental Determination in Food Samples

    International Nuclear Information System (INIS)

    Beside to complished the requirements of international standard of ISO/IEC 17025:2005, uncertainty estimation should be done to increase quality and confidence of analysis results and also to establish traceability of the analysis results to SI unit. Neutron activation analysis is a major technique used by Radiometry technique analysis laboratory and is included as scope of accreditation under ISO/IEC 17025:2005, therefore uncertainty estimation of neutron activation analysis is needed to be carried out. Sample and standard preparation as well as, irradiation and measurement using gamma spectrometry were the main activities which could give contribution to uncertainty. The components of uncertainty sources were specifically explained. The result of expanded uncertainty was 4,0 mg/kg with level of confidence 95% (coverage factor=2) and Zn concentration was 25,1 mg/kg. Counting statistic of cuplikan and standard were the major contribution of combined uncertainty. The uncertainty estimation was expected to increase the quality of the analysis results and could be applied further to other kind of samples. (author)

  12. Epithermal Neutron Activation Analysis at the IBR-2 reactor of the Frank Laboratory of Neutron Physics at the Joint Institute for Nuclear Research (Dubna)

    Science.gov (United States)

    Frontasyeva, M. V.

    2008-10-01

    Experience of the Neutron Activation Analysis (NAA) Department in employing epithermal activation in life sciences and materials science is summarized. The potential of a combination of epithermal activation and the suppression of Compton scattering and contributions from cascade-photon-emitting elements for raising NAA-based analytical studies up to a new level are discussed.

  13. Non destructive multi elemental analysis using prompt gamma neutron activation analysis techniques: Preliminary results for concrete sample

    International Nuclear Information System (INIS)

    In this study, principle of prompt gamma neutron activation analysis has been used as a technique to determine the elements in the sample. The system consists of collimated isotopic neutron source, Cf-252 with HPGe detector and Multichannel Analysis (MCA). Concrete with size of 10×10×10 cm3 and 15×15×15 cm3 were analysed as sample. When neutrons enter and interact with elements in the concrete, the neutron capture reaction will occur and produce characteristic prompt gamma ray of the elements. The preliminary result of this study demonstrate the major element in the concrete was determined such as Si, Mg, Ca, Al, Fe and H as well as others element, such as Cl by analysis the gamma ray lines respectively. The results obtained were compared with NAA and XRF techniques as a part of reference and validation. The potential and the capability of neutron induced prompt gamma as tool for multi elemental analysis qualitatively to identify the elements present in the concrete sample discussed

  14. Neutron activation analysis of phytotherapic obtained from medicinal plants; Analise por ativacao com neutrons de fitoterapicos obtidos de plantas medicinais

    Energy Technology Data Exchange (ETDEWEB)

    Moreira, Henrique S. [Universidade de Sao Paulo (USP), Ribeirao Preto, SP (Brazil). Faculdade de Ciencias Farmaceuticas]. E-mail: hs_moreira@hotmail.com; Saiki, Mitiko; Vasconcellos, Marina B.A. [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)]. E-mails: mitiko@ipen.br; mbvascon@ipen.br

    2007-07-01

    This paper determines the inorganic constituents in phytotherapic samples for posterior study of the relationship existent among the concentrations of the found elements and the their possible therapeutical effects. The samples of phytotherapic pills (Centella asiatica, Ginkgo biloba and Ginseng) were analysed by using neutron activation analysis (NAA). The As, Br, Ca, Co, Cr, Cs, Fe, K, La, Na, Rb, Sc, Se and Zn samples were determined in the phytotherapics, The Centella asiatica presented the higher concentrations of Br, Co, Cr, Fe, K, La, Na, Rb, Sc, Se and Zn. In the sample of Ginko biloba, higher levels of As and Ca were found, while in the sample ol Ginseng the element As were not detected. The found results have shown the the NAA method is appropriated for analysing this type of materials due to his simplicity, multielemental capacity and quality of the results obtained. (author)

  15. Study on bioavailability of zinc for children's diet by using activable isotopic tracer 70Zn and neutron activation analysis techniques

    International Nuclear Information System (INIS)

    Bioavailability of zinc for three groups (low amount of diet zinc, balance amount of diet zinc and high amount of diet zinc) of children's diet is studied by using activable isotopic tracer 70Zn and neutron activation analysis techniques. The results indicate that the fractional absorption of zinc from balance diet zinc group is the highest, up to 33.9%. A procedure of pre-irradiation concentration zinc for fecal samples using anion exchanger is developed, and the enriched 70Zn with isotopic abundance of 18.3% is used for tracer. The mass ratios between 70Zn and 68Zn or 64Zn and their contents between natural zinc and enriched zinc are used to calculate the bioavailability of zinc. Instrumental neutron activation analysis of 64Zn of each original fecal samples and pre-irradiation concentrated zinc samples are used to normalize the chemical yield in order to reduce the uncertainty during the chemical separation procedure

  16. Possible applications of neutron activation analysis at the RB reactor for the environmental monitoring

    International Nuclear Information System (INIS)

    This paper presents the possibilities of performing neutron activation analysis in Yugoslavia for the purpose of environmental pollution monitoring. Neutron activation analysis (NAA) is an established method for the determination of trace elements in a broad range of samples. It is non-destructive method used in a routine manner with gamma-ray spectrometry for various applications in biology, environmental toxicology, radiation assessment, mineral exploration, trace elements monitoring regarding human health studies. As a complex, powerful analytical tool, it might give results even when other analytical methods fail. NAA has been performed at the Nuclear Engineering Laboratory (NET), the VINCA Institute of Nuclear Sciences, for various applications in the reactor physics research. The samples are irradiated in the RB research reactor, which is the zero-power, bear, heavy water critical facility utilising three fuel element types. The reactor system is very flexible and allows for different core configurations, resulting in various neutron fields, with energy spectra ranging from thermal to fast (in the coupled fast-thermal system HERBE). There are several vertical and horizontal experimental channels available for sample's irradiation. The achievable thermal neutron flux is approximately 1 0 7 n/(cm 2 s) per 1 W of fission power. We believe the RB reactor could be successfully used for neutron activation analysis of trace elements in the environmental samples, comprising short-lived isotopes. Although the flux level and restricted irradiation time pose a certain limitation to NAA applications at the RB reactor, it can be compensated by the specific methodology advancement. That involves overcoming the main sources of error in the instrumental NAA evaluation methodology which utilises generally valid k0, and Q0 factors. In particular, the computational accuracy of required nuclear parameters (e.g. neutron flux distribution, effective nuclear cross sections) can be

  17. Trace Element Analysis of Human Lung Tissue by Neutron Activation and Instrumental Analysis

    International Nuclear Information System (INIS)

    The measurement of trace elements in tissues in the ppm to pp109 range requires very careful and specialized techniques both in the sample acquisition and in subsequent analysis. Many of the trace elements which are present in human tissues are at lower concentrations than those in super-pure chemical reagents; also, an acid rinse of typical laboratory glassware may contain as much of some trace elements as the tissue sample being studied. An analytical technique based on neutron activation for the measurement of trace elements in tissues has been developed which requires a minimum of pre-irradiation handling followed by the direct measurement of the activation products on a multidimensional or a solid-state gammaray spectrometer. This technique has been applied to a study of trace elements in human lung tissue. Lung tissue contains not only the tissue-bound elements but also those which have been deposited in the cells of the pulmonary alveoli through inhalation. The method permits the direct measurement of 15 trace elements. The analysis of lung tissues thus provides information on the integrated trace element deposition resulting during the life of an individual. The concentrations of several of these including Fe, Br, P, Se, Ag, Zn, Cs, Co, Sc, U and Sb have been measured in several autopsy and biopsy samples of both normal and diseased tissues from several subjects with known case histories. The variations in the observed trace element compositions are presented and considered in terms of the occupational and medical history of the subject. (author)

  18. Transitions, cross sections and neutron binding energy in 186Re by Prompt Gamma Activation Analysis

    Science.gov (United States)

    Lerch, A. G.; Hurst, A. M.; Firestone, R. B.; Revay, Zs.; Szentmiklosi, L.; McHale, S. R.; McClory, J. W.; Detwiler, B.; Carroll, J. J.

    2014-03-01

    The nuclide 186Re possesses an isomer with 200,000 year half-life while its ground state has a half-life of 3.718 days. It is also odd-odd and well-deformed nucleus, so should exhibit a variety of other interesting nuclear-structure phenomena. However, the available nuclear data is rather sparse; for example, the energy of the isomer is only known to within + 7 keV and, with the exception of the J?=1- ground state, every proposed level is tentative in the ENSDF. Previously, Prompt Gamma Activation Analysis (PGAA) was utilized to study natRe with 186,188Re being produced via thermal neutron capture. Recently, an enriched 185Re target was irradiated by thermal neutrons at the Budapest Research Reactor to build on those results. Prompt (primary and secondary) and delayed gamma-ray transitions were measured with a large-volume, Compton-suppressed HPGe detector. Absolute cross sections for each gamma transition were deduced and corrected for self attenuation within the sample. Fifty-two primary gamma-ray transitions were newly identified and used to determine a revised value of the neutron binding energy. DICEBOX was used to simulate the decay scheme and the total radiative thermal neutron capture cross section was found to be 97+/-3 b Supported by DTRA (Detwiler) through HDTRA1-08-1-0014.

  19. An in-beam Compton-suppressed Ge spectrometer for nondestructive neutron activation analysis

    International Nuclear Information System (INIS)

    A high-efficiency compton background suppressed gamma-ray spectrometer by anti-coincidence counting with a NaI(Tl)-shield around a central HPGe-detector for in-beam prompt gamma-ray neutron activation analysis (AC-PGNAA) using a Cf-252 neutron source has been designed and built to provide simultaneous anti-coincidence spectrometry of natural, industrial and environmental samples. The spectrometer consists of a high-purity germanium detector as the main detector and a large volume cylindrical NaI(Tl) detector as a guard detector. The assembly has the ability to measure instantaneously, simultaneously and nondestructively bulk samples up to about 50 cm3. Major constituent elements in several rocks and minerals such as H, B, N, Na, Mg, Al, Si, Cl, K, Ca, P, S, Ti, Fe, Sm, Nd, Mn and Gd can be determined, while oxygen cannot be measured due to its small capture cross section (0.27 mb). Several important minor and trace elements such as B, Cd and Hg beside the low residual activity, rare earths and short-lived isotopes could be detected. The sensitivity of the AC-PGNAA technique is limited by the available neutron flux at the target matrix and the neutron absorption cross section of the elements of interest. PGNAA has the advantage to estimate the constituent elements which are difficult to be measured through the delayed gamm-ray measurements such as B, Bi, C, H, P, Tl, Be, Cl and S in industrial and reference materials and those elements which are transformed into other stable isotopes when undergoing neutron capture. The design of the spectrometer assembly, its properties and performance are described

  20. Metrological role of reactor neutron activation analysis in contemporary inorganic trace analysis

    International Nuclear Information System (INIS)

    In this paper, the inherent characteristics of relative instrumental neutron activation analysis (INAA) as a primary ratio method of measurement, the unique functions of parametric INAA as an ideal back-up method of the relative INAA, and the valuable role of INAA in characterization of sampling behavior of individual elements in certified reference materials (CRMs) will be discussed. In the second of this series, traceability and uncertainty of measurement results by k0-INAA will be described. The role of k0-INAA as a back-up to relative INAA will be discussed. In the final series, minimum sample size, usually 100 mg or larger, is often the only information given in certificates of the existing certified reference materials (CRMs) to describe sampling behavior. This value is not only too large to cope with the quality control (QC) requirements of microanalysis, but also too general to reflect the strong element-specific nature of sampling behavior of solid materials. The need for CRMs with sampling behavior characterized for individual elements is explained, and the unique role INAA can play in this aspect is described. (J.P.N.)