Sample records for analysis gas

  1. Life-cycle analysis of shale gas and natural gas.

    Energy Technology Data Exchange (ETDEWEB)

    Clark, C.E.; Han, J.; Burnham, A.; Dunn, J.B.; Wang, M. (Energy Systems); ( EVS)


    The technologies and practices that have enabled the recent boom in shale gas production have also brought attention to the environmental impacts of its use. Using the current state of knowledge of the recovery, processing, and distribution of shale gas and conventional natural gas, we have estimated up-to-date, life-cycle greenhouse gas emissions. In addition, we have developed distribution functions for key parameters in each pathway to examine uncertainty and identify data gaps - such as methane emissions from shale gas well completions and conventional natural gas liquid unloadings - that need to be addressed further. Our base case results show that shale gas life-cycle emissions are 6% lower than those of conventional natural gas. However, the range in values for shale and conventional gas overlap, so there is a statistical uncertainty regarding whether shale gas emissions are indeed lower than conventional gas emissions. This life-cycle analysis provides insight into the critical stages in the natural gas industry where emissions occur and where opportunities exist to reduce the greenhouse gas footprint of natural gas.

  2. OPIC Greenhouse Gas Emissions Analysis Details (United States)

    Overseas Private Investment Corporation — Summary project inventory with independent analysis to quantify the greenhouse gas ("GHG") emissions directly attributable to projects to which the Overseas Private...

  3. Permanent gas analysis using gas chromatography with vacuum ultraviolet detection. (United States)

    Bai, Ling; Smuts, Jonathan; Walsh, Phillip; Fan, Hui; Hildenbrand, Zacariah; Wong, Derek; Wetz, David; Schug, Kevin A


    The analysis of complex mixtures of permanent gases consisting of low molecular weight hydrocarbons, inert gases, and toxic species plays an increasingly important role in today's economy. A new gas chromatography detector based on vacuum ultraviolet (VUV) spectroscopy (GC-VUV), which simultaneously collects full scan (115-240 nm) VUV and UV absorption of eluting analytes, was applied to analyze mixtures of permanent gases. Sample mixtures ranged from off-gassing of decomposing Li-ion and Li-metal batteries to natural gas samples and water samples taken from private wells in close proximity to unconventional natural gas extraction. Gas chromatography separations were performed with a porous layer open tubular column. Components such as C1-C5 linear and branched hydrocarbons, water, oxygen, and nitrogen were separated and detected in natural gas and the headspace of natural gas-contaminated water samples. Of interest for the transport of lithium batteries were the detection of flammable and toxic gases, such as methane, ethylene, chloromethane, dimethyl ether, 1,3-butadiene, CS2, and methylproprionate, among others. Featured is the capability for deconvolution of co-eluting signals from different analytes.

  4. Analysis of K west basin canister gas

    Energy Technology Data Exchange (ETDEWEB)

    Trimble, D.J., Fluor Daniel Hanford


    Gas and Liquid samples have been collected from a selection of the approximately 3,820 spent fuel storage canisters in the K West Basin. The samples were taken to characterize the contents of the gas and water in the canisters providing source term information for two subprojects of the Spent Nuclear Fuel Project (SNFP) (Fulton 1994): the K Basins Integrated Water Treatment System Subproject (Ball 1996) and the K Basins Fuel Retrieval System Subproject (Waymire 1996). The barrels of ten canisters were sampled for gas and liquid in 1995, and 50 canisters were sampled in a second campaign in 1996. The analysis results from the first campaign have been reported (Trimble 1995a, 1995b, 1996a, 1996b). The analysis results from the second campaign liquid samples have been documented (Trimble and Welsh 1997; Trimble 1997). This report documents the results for the gas samples from the second campaign and evaluates all gas data in terms of expected releases when opening the canisters for SNFP activities. The fuel storage canisters consist of two closed and sealed barrels, each with a gas trap. The barrels are attached at a trunion to make a canister, but are otherwise independent (Figure 1). Each barrel contains up to seven N Reactor fuel element assemblies. A gas space of nitrogen was established in the top 2.2 to 2.5 inches (5.6 to 6.4 cm) of each barrel. Many of the fuel elements were damaged allowing the metallic uranium fuel to be corroded by the canister water. The corrosion releases fission products and generates hydrogen gas. The released gas mixes with the gas-space gas and excess gas passes through the gas trap into the basin water. The canister design does not allow canister water to be exchanged with basin water.

  5. Greenhouse Gas Analysis at the World Bank


    World Bank


    This report builds on reviews of available methodologies, tools, and practices for greenhouse gas (GHG) analysis, and summarizes the outcomes of pilot studies. It discusses the issues and challenges associated with GHG analysis for energy, transport and forestry projects such as setting project boundaries and accounting for indirect emissions. To do this it draws on existing United Nations...

  6. HD gas analysis with Gas Chromatography and Quadrupole Mass Spectrometer

    CERN Document Server

    Ohta, T; Didelez, J -P; Fujiwara, M; Fukuda, K; Kohri, H; Kunimatsu, T; Morisaki, C; Ono, S; Rouille, G; Tanaka, M; Ueda, K; Uraki, M; Utsuro, M; Wang, S Y; Yosoi, M


    A gas analyzer system has been developed to analyze Hydrogen-Deuteride (HD) gas for producing frozen-spin polarized HD targets, which are used for hadron photoproduction experiments at SPring-8. Small amounts of ortho-H$_{2}$ and para-D$_{2}$ gas mixtures ($\\sim$0.01%) in the purified HD gas are a key to realize a frozen-spin polarized target. In order to obtain reliable concentrations of these gas mixtures in the HD gas, we produced a new gas analyzer system combining two independent measurements with the gas chromatography and the QMS. The para-H$_{2}$, ortho-H$_{2}$, HD, and D$_{2}$ are separated using the retention time of the gas chromatography and the mass/charge. It is found that the new gas analyzer system can measure small concentrations of $\\sim$0.01% for the otho-H$_2$ and D$_2$ with good S/N ratios.

  7. Environmental analysis for pipeline gas demonstration plants

    Energy Technology Data Exchange (ETDEWEB)

    Stinton, L.H.


    The Department of Energy (DOE) has implemented programs for encouraging the development and commercialization of coal-related technologies, which include coal gasification demonstration-scale activities. In support of commercialization activities the Environmental Analysis for Pipeline Gas Demonstration Plants has been prepared as a reference document to be used in evaluating potential environmental and socioeconomic effects from construction and operation of site- and process-specific projects. Effluents and associated impacts are identified for six coal gasification processes at three contrasting settings. In general, impacts from construction of a high-Btu gas demonstration plant are similar to those caused by the construction of any chemical plant of similar size. The operation of a high-Btu gas demonstration plant, however, has several unique aspects that differentiate it from other chemical plants. Offsite development (surface mining) and disposal of large quantities of waste solids constitute important sources of potential impact. In addition, air emissions require monitoring for trace metals, polycyclic aromatic hydrocarbons, phenols, and other emissions. Potential biological impacts from long-term exposure to these emissions are unknown, and additional research and data analysis may be necessary to determine such effects. Possible effects of pollutants on vegetation and human populations are discussed. The occurrence of chemical contaminants in liquid effluents and the bioaccumulation of these contaminants in aquatic organisms may lead to adverse ecological impact. Socioeconomic impacts are similar to those from a chemical plant of equivalent size and are summarized and contrasted for the three surrogate sites.




    The GTRAN program was developed to solve transient, as well as steady state, problems for gas piping systems. GTRAN capabilities allow for the analysis of a variety of system configurations and components. These include: multiple pipe junctions; valves that change position with time; fixed restrictions (orifices, manual valves, filters, etc.); relief valves; constant pressure sources; and heat transfer for insulated piping and piping subjected to free or forced convection. In addition, boundary conditions can be incorporated to simulate specific components. The governing equations of GTRAN are the one-dimensional transient gas dynamic equations. The three equations for pressure, velocity, and density are reduced to numerical equations using an implicit Crank-Nicholson finite difference technique. Input to GTRAN includes a description of the piping network, the initial conditions, and any events (e.g. valve closings) occuring during the period of analysis. Output includes pressure, velocity, and density versus time. GTRAN is written in FORTRAN 77 for batch execution and has been implemented on a DEC VAX series computer. GTRAN was developed in 1983.

  9. Quantitative risk analysis preoperational of gas pipeline

    Energy Technology Data Exchange (ETDEWEB)

    Manfredi, Carlos; Bispo, Gustavo G.; Esteves, Alvaro [Gie S.A., Buenos Aires (Argentina)


    The purpose of this analysis is to predict how it can be affected the individual risk and the public's general security due to the operation of a gas pipeline. In case that the single or social risks are considered intolerable, compared with the international standards, to be recommended measures of mitigation of the risk associated to the operation until levels that can be considered compatible with the best practices in the industry. The quantitative risk analysis calculates the probability of occurrence of an event based on the frequency of occurrence of the same one and it requires a complex mathematical treatment. The present work has as objective to develop a calculation methodology based on the previously mentioned publication. This calculation methodology is centered in defining the frequencies of occurrence of events, according to representative database of each case in study. Besides, it settles down the consequences particularly according to the considerations of each area and the different possibilities of interferences with the gas pipeline in study. For each one of the interferences a typical curve of ignition probabilities is developed in function from the distance to the pipe. (author)

  10. Simple gas chromatographic method for furfural analysis. (United States)

    Gaspar, Elvira M S M; Lopes, João F


    A new, simple, gas chromatographic method was developed for the direct analysis of 5-hydroxymethylfurfural (5-HMF), 2-furfural (2-F) and 5-methylfurfural (5-MF) in liquid and water soluble foods, using direct immersion SPME coupled to GC-FID and/or GC-TOF-MS. The fiber (DVB/CAR/PDMS) conditions were optimized: pH effect, temperature, adsorption and desorption times. The method is simple and accurate (RSDTOF-MS: 0.3, 1.2 and 0.9 ngmL(-1) for 2-F, 5-MF and 5-HMF, respectively). It was applied to different commercial food matrices: honey, white, demerara, brown and yellow table sugars, and white and red balsamic vinegars. This one-step, sensitive and direct method for the analysis of furfurals will contribute to characterise and quantify their presence in the human diet.

  11. Analysis of trapped gas in 1E34 detonators by gas chromatography

    Energy Technology Data Exchange (ETDEWEB)

    Warner, D.K.; Back, P.S.; Barnhart, B.V.


    A method was developed to extract and then analyze gas trapped in thermally aged 1E34 detonators. This gas was extracted into an evacuated volume and injected into a gas chromatograph for separation and quantitative analysis. To effect this gas extraction, a device was designed for puncturing the detonator cup and capturing the effused gas. Limited testing of five detonators in this device shows amounts of gas ranging from about 0.5 X 10 {sup -7} to 12 X 10 {sup - 7} moles.

  12. Analysis of Flux of Gas Passing Circle Lacuna

    Institute of Scientific and Technical Information of China (English)

    ZHAO; Shi-jun; SUN; Ke-yu; YU; Xiu-ping


    The rate of flow of the gas flowing through cirque chink often needs calculation in engineering. The characters of compressibility and thermodynamics have some effect on the gas flowing, so the analysis on the flow of gas is more complex than that of liquid. But under different conditions and different requirements of precision the analysis can be simplified suitably, then make the formulae given become simple subsequently. This paper analyzes various gas flux based on basic characters and motion laws of gas and the analysis is just applied in an engineering project.


    Directory of Open Access Journals (Sweden)

    F. Abramchuk


    Full Text Available The results of comparison analysis of gas engine monospark and multispark ignition systems indices are presented. The results of these systems experimental investigation are given.

  14. Mathematical analysis of intermittent gas injection model in oil production (United States)

    Tasmi, Silvya, D. R.; Pudjo, S.; Leksono, M.; Edy, S.


    Intermittent gas injection is a method to help oil production process. Gas is injected through choke in surface and then gas into tubing. Gas forms three areas in tubing: gas column area, film area and slug area. Gas column is used to propel slug area until surface. A mathematical model of intermittent gas injection is developed in gas column area, film area and slug area. Model is expanding based on mass and momentum conservation. Using assume film thickness constant in tubing, model has been developed by Tasmi et. al. [14]. Model consists of 10 ordinary differential equations. In this paper, assumption of pressure in gas column is uniform. Model consist of 9 ordinary differential equations. Connection of several variables can be obtained from this model. Therefore, dynamics of all variables that affect to intermittent gas lift process can be seen from four equations. To study the behavior of variables can be analyzed numerically and mathematically. In this paper, simple mathematically analysis approach is used to study behavior of the variables. Variables that affect to intermittent gas injection are pressure in upstream valve and in gas column. Pressure in upstream valve will decrease when gas mass in valve greater than gas mass in choke. Dynamic of the pressure in the gas column will decrease and increase depending on pressure in upstream valve.

  15. Simulation Analysis of Indoor Gas Explosion Damage

    Institute of Scientific and Technical Information of China (English)

    钱新明; 陈林顺; 冯长根


    The influence factors and process of indoor gas explosion are studied with AutoReaGas explosion simulator. The result shows that venting pressure has great influence on the indoor gas explosion damage. The higher the venting pressure is, the more serious the hazard consequence will be. The ignition location has also evident effect on the gas explosion damage. The explosion static overpressure would not cause major injury to person and serious damage to structure in the case of low venting pressure (lower than 2 kPa). The high temperature combustion after the explosion is the major factor to person injury in indoor gas explosion accidents.

  16. Thermodynamic Analysis of Supplementary-Fired Gas Turbine Cycles

    DEFF Research Database (Denmark)

    Elmegaard, Brian; Henriksen, Ulrik Birk; Qvale, Einar Bjørn


    This paper presents an analysis of the possibilities for improving the efficiency of an indi-rectly biomass-fired gas turbine (IBFGT) by supplementary direct gas-firing. The supple-mentary firing may be based on natural gas, biogas or pyrolysis gas. Intuitively, sup-plementary firing is expected...... for the recu-perated gas turbine. Instead, other process changes may be considered in order to obtain a high marginal efficiency on natural gas. Two possibilities are discussed: Integration between an IFGT and pyrolysis of the biofuel which will result in a highly efficient utilization of the biomass...... for the indirectly fired gas turbine (IFGT) and for the supplementary-fired IFGT. These results show that the combination of external firing and internal firing have the potential of reducing or solving some problems associated with the use of biomass both in the recuperated and the indirectly fired gas turbine...

  17. Thermodynamic Analysis of Supplementary-Fired Gas Turbine Cycles

    DEFF Research Database (Denmark)

    Elmegaard, Brian; Henriksen, Ulrik Birk; Qvale, Einar Bjørn


    This paper presents an analysis of the possibilities for improving the efficiency of an indirectly biomass-fired gas turbine (IBFGT) by supplementary direct gas-firing. The supplementary firing may be based on natural gas, biogas, or pyrolysis gas. {The interest in this cycle arise from a recent......: Integration between an IFGT and pyrolysis of the biofuel which will result in a highly efficient utilization of the biomass, and integration between external biomass firing, internal biomass firing and internal natural gas firing. The marginal efficiency of the natural gas is in this case found...... for the indirectly fired gas turbine (IFGT) and for the supplementary-fired IFGT. Both results show that the combination of external firing and internal firing have the potential of reducing or solving some problems with the use of biomass both in the recuperated and the indirectly fired gas turbine: The former...

  18. Using Willie's Acid-Base Box for Blood Gas Analysis (United States)

    Dietz, John R.


    In this article, the author describes a method developed by Dr. William T. Lipscomb for teaching blood gas analysis of acid-base status and provides three examples using Willie's acid-base box. Willie's acid-base box is constructed using three of the parameters of standard arterial blood gas analysis: (1) pH; (2) bicarbonate; and (3) CO[subscript…

  19. Optical Absorption Spectroscopy for Gas Analysis in Biomass Gasification

    DEFF Research Database (Denmark)

    Grosch, Helge

    the concentration of the mentioned compounds. However, continuous measurements of different species directly in the gas (in-situ) and at the same time are scarce. In this work, the basis of optical in-situ analysis with ultraviolet and infrared spectroscopy was build to determine the concentration of the most...... important gas species of the low-temperature circulating fluidized bed gasifier. At first, a special gas cell,the hot gas flow cell (HGC), was build up and veried. In this custom-made gas cell, the optical properties, the so-called absorption cross-sections, of the most important sulfur and aromatic...

  20. Analysis of Adsorbed Natural Gas Tank Technology (United States)

    Knight, Ernest; Schultz, Conrad; Rash, Tyler; Dohnke, Elmar; Stalla, David; Gillespie, Andrew; Sweany, Mark; Seydel, Florian; Pfeifer, Peter

    With gasoline being an ever decreasing finite resource and with the desire to reduce humanity's carbon footprint, there has been an increasing focus on innovation of alternative fuel sources. Natural gas burns cleaner, is more abundant, and conforms to modern engines. However, storing compressed natural gas (CNG) requires large, heavy gas cylinders, which limits space and fuel efficiency. Adsorbed natural gas (ANG) technology allows for much greater fuel storage capacity and the ability to store the gas at a much lower pressure. Thus, ANG tanks are much more flexible in terms of their size, shape, and weight. Our ANG tank employs monolithic nanoporous activated carbon as its adsorbent material. Several different configurations of this Flat Panel Tank Assembly (FPTA) along with a Fuel Extraction System (FES) were examined to compare with the mass flow rate demands of an engine.

  1. Attachment B: URS Shale Gas Emissions Analysis (United States)

    This data was provided in response to a request by ANGA for actual current data that could be compared to EPA's assumptions used in the newly proposed Oil and Natural Gas Air Pollution Standards, Subpart quad 0

  2. Analysis of Natural Gas Vehicle Industry : none


    Li, Zhen


    A vehicle powered by natural gas is becoming a prevalent trend and direction in automobile manufacturing. The thesis is aiming at analyzing the natural gas vehicle industry from its environmental effectiveness, economic effectiveness, recent status and its development in the near future with statistical data. And also it will find out the potential problems and relevant technologies. Investigation and literature research method are mainly used to fully collect the correct information and d...

  3. Continuous Preconcentrator for Trace Gas Analysis (Preprint) (United States)


    SWNTs are removed from the suspension in such way that they are Distribution A: Approved for public release; distribution unlimited. assembled...into open-ended tubes, CNTs have become an attractive material selection for nanofluidic and nano gas dynamic applications. Molecular Dynamics

  4. Sensitivity analysis of the fission gas behavior model in BISON.

    Energy Technology Data Exchange (ETDEWEB)

    Swiler, Laura Painton; Pastore, Giovanni; Perez, Danielle; Williamson, Richard


    This report summarizes the result of a NEAMS project focused on sensitivity analysis of a new model for the fission gas behavior (release and swelling) in the BISON fuel performance code of Idaho National Laboratory. Using the new model in BISON, the sensitivity of the calculated fission gas release and swelling to the involved parameters and the associated uncertainties is investigated. The study results in a quantitative assessment of the role of intrinsic uncertainties in the analysis of fission gas behavior in nuclear fuel.

  5. Effluent metering and liquid gas ratio analysis

    Energy Technology Data Exchange (ETDEWEB)

    Conrad, L.M. [EnCana Corp., Calgary, AB (Canada); Howell, K. [Intricate Group, Calgary, AB (Canada)


    The Industry Measurement Group (IMG) launched a 2 year initiative in 2007 focused on creating technically based regulations to improve the economics on low pressure, low liquid gas plays in western Canada. The IMG is the liaison between the petroleum industry and regulatory agencies in the development of industry accepted standards for measuring activities. The Canadian Association of Petroleum Producers (CAPP) supported the IMG's initiative, which led to a joint CAPP/IMG review of effluent metering applications and the associated testing requirements for gas wells in British Columbia and Alberta. The primary objectives of the joint CAPP/IMG review were to bring all parties together to form a common framework for effluent metering application and testing expectations, based on a risk and volumetric approach; and to support an economical approach to the continued development of unconventional gas resource plays in Alberta and British Columbia, with a focus on well-site infrastructure and operational cost optimization. This paper focused primarily on the well testing requirements and discussed the benefits of creating technically based, pragmatic regulations. Existing regulations were used to help the CAPP/IMG project team to develop a new practical and pragmatic regulatory framework and policy for effluent metering and well testing. 1 ref., 2 tabs., 15 figs.

  6. Gas Turbine Design & Analysis Tool: Turbomachinery Components.


    Garcia Soto, David


    Este proyecto se centra en la creación de un programa el cual ha de ser una herramienta de ayuda en el diseño y simulación de aplicaciones de motores de turbina de gas, permitiendo al usuario realizar los cálculos necesarios para poder implementar posteriormente los resultados en sus diseños. Por ello, dicha herramienta debe ser versátil y permitir trabajar tanto con un solo módulo como con diversos acoplados según las necesidades del usuario. Además el hecho de modularizar permite acotar y r...

  7. Extended Analysis on New Generalized Chaplygin Gas

    Institute of Scientific and Technical Information of China (English)

    WANG Jun; WU Ya-Bo; WANG Di; YANG Wei-Qiang


    We extend the study of the new generalizeal Chaplygin gas (NGCG) based on [J.Cosmol.Astropart.Phys.0601 (2006) 003].Specifically,we not only discuss the change rates of the energy densities and the energy transfer of this model,but also perform the Om diagnostic to differentiate the ACDM model from the NGCG and the GCG models.Furthermore,in order to consider the influence of dark energy on structure formation,we also present the evolution of the growth index in this scenario with interaction.

  8. Analysis on using biomass lean syngas in micro gas turbines (United States)

    Mărculescu, C.; Cenuşă, V. E.; Alexe, F. N.


    The paper presents an analysis on small systems for converting biomass/wastes into power using Micro Gas Turbines (MGT) fed with gaseous bio-fuels produced by air- gasification. The MGT is designed for burning various fossil liquid and gas fuels, having catalogue data related to natural gas use. Fuel switch changes their performances. The present work is focused on adapting the MGT for burning alternative low quality gas fuel produced by biomass air gasification. The heating values of these gas fuels are 3 to 5 times lower than the methane ones, leading to different air demand for the stoichiometric burning. Validated numerical computation procedures were used to model the MGT thermodynamic process. Our purpose was to analyze the influence of fuel change on thermodynamic cycle performances.

  9. Development of a gas systems analysis model (GSAM)

    Energy Technology Data Exchange (ETDEWEB)

    Godec, M.L. [IFC Resources Inc., Fairfax, VA (United States)


    The objectives of developing a Gas Systems Analysis Model (GSAM) are to create a comprehensive, non-proprietary, PC based model of domestic gas industry activity. The system is capable of assessing the impacts of various changes in the natural gas system within North America. The individual and collective impacts due to changes in technology and economic conditions are explicitly modeled in GSAM. Major gas resources are all modeled, including conventional, tight, Devonian Shale, coalbed methane, and low-quality gas sources. The modeling system asseses all key components of the gas industry, including available resources, exploration, drilling, completion, production, and processing practices, both for now and in the future. The model similarly assesses the distribution, storage, and utilization of natural gas in a dynamic market-based analytical structure. GSAM is designed to provide METC managers with a tool to project the impacts of future research, development, and demonstration (RD&D) benefits in order to determine priorities in a rapidly changing, market-driven gas industry.

  10. The Use of Gas Chromatography for Biogas Analysis (United States)

    Andersen, Amanda; Seeley, John; Aurandt, Jennifer


    Energy from natural gas accounts for 24 percent of energy consumed in the US. Natural gas is a robust form of energy which is rich in methane content and is low in impurities. This quality suggests that it is a very clean and safe gas; it can be used in providing heat, a source for cooking, and in powering vehicles. The downside is that it is a non-renewable resource. On the contrary, methane rich gas that is produced by the breakdown of organic material in an anaerobic environment, called biogas, is a renewable energy source. This research focuses on the gas analysis portion of the creation of the anaerobic digestion and verification laboratory where content and forensic analysis of biogas is performed. Gas Chromatography is implemented as the optimal analytical tool for quantifying the components of the biogas including methane, carbon dioxide, hydrogen sulfide and siloxanes. In addition, the problems associated with the undesirable components are discussed. Anaerobic digestion of primary sludge has consistently produced about 55 percent methane; future goals of this research include studying different substrates to increase the methane yield and decrease levels of impurities in the gas.

  11. Exergy analysis of waste emissions from gas flaring

    Directory of Open Access Journals (Sweden)

    Olawale Saheed ISMAIL


    Full Text Available Gas flaring produces a stream of waste gases at high temperature and pressure which contains carbon monoxide, Hydrogen Sulphide etc. The resultant effect of which is detrimental to our planet and, consequently, to the life of both the living and the non-living things. It’s well known that gas flaring contributes in no small measure to the global warming. Exergy analysis is applied in this work to analyze waste emissions from gas flaring so as to have a model through which impact of gas flaring can be measured. The study considers both the thermo-mechanical exergy and the chemical exergy of these gases. Relevant data on gas flaring activities in the Niger-Delta region of Nigeria between the periods of fifteen (15 years was obtained from the Nigerian National Petroleum Corporation (NNPC. A computer program (Exergy Calculator was developed based on the equations generated in the Model. Exergy associated with gas flaring activities in Nigeria between the periods of 1998 through 2012 was calculated. The results show that 1 mscf (in thousand cubic feet of flared gases generate 0.000041 MWh of energy leading to a value of 440158.607 MWh of energy for the period under review.The analysis provides important conclusions and recommendations for improving oil platforms operationsin in order to safeguard the environment, health of the populace, and maximize recovered exergy from gas flaring.

  12. Engineering analysis of biomass gasifier product gas cleaning technology

    Energy Technology Data Exchange (ETDEWEB)

    Baker, E.G.; Brown, M.D.; Moore, R.H.; Mudge, L.K.; Elliott, D.C.


    For biomass gasification to make a significant contribution to the energy picture in the next decade, emphasis must be placed on the generation of clean, pollutant-free gas products. This reports attempts to quantify levels of particulated, tars, oils, and various other pollutants generated by biomass gasifiers of all types. End uses for biomass gases and appropriate gas cleaning technologies are examined. Complete systems analysis is used to predit the performance of various gasifier/gas cleanup/end use combinations. Further research needs are identified. 128 refs., 20 figs., 19 tabs.

  13. Gas phase chemical detection with an integrated chemical analysis system

    Energy Technology Data Exchange (ETDEWEB)



    Microfabrication technology has been applied to the development of a miniature, multi-channel gas phase chemical laboratory that provides fast response, small size, and enhanced versatility and chemical discrimination. Each analysis channel includes a sample preconcentrator followed by a gas chromatographic separator and a chemically selective surface acoustic wave detector array to achieve high sensitivity and selectivity. The performance of the components, individually and collectively, is described.

  14. Gas-solid coupling analysis and numerical simulation of the dynamic process of gas drainage

    Institute of Scientific and Technical Information of China (English)

    Kai WANG; Bo LI; Jian-Ping WEI; Peng LI


    Based on the basic theory of gas seepage and coal seam deformation,using the numerical simulation method,this paper established the gas-solid coupling model of gas drainage from borehole.Using multi-physical coupling analysis software,the authors studied the stress change conditions around the drainage borehole,the influence of the gas drainage effect caused by the drilling gap,and the gas drainage effect under the conditions of different borehole radius and different permeabilities.The results show that the effective drainage radius is 1.03 m during 30 days of drainage.The effect of the diameter change of the drainage borehole is limited,but the influence of coal seam permeability is much bigger.After the same drainage period,the greater the permeability of coal seam is,the bigger the drainage radius is.For a low permeability coal seam,coal miners should take pressure-relief measures and increase the permeability to improve the drainage effects before draining gas through drilling.

  15. Sensitivity Analysis of a Bioinspired Refractive Index Based Gas Sensor

    Institute of Scientific and Technical Information of China (English)

    Yang Gao; Qi Xia; Guanglan Liao; Tielin Shi


    It was found out that the change of refractive index of ambient gas can lead to obvious change of the color of Morpho butterfly's wing. Such phenomenon has been employed as a sensing principle for detecting gas. In the present study, Rigorous Coupled-Wave Analysis (RCWA) was described briefly, and the partial derivative of optical reflection efficiency with respect to the refractive index of ambient gas, i.e., sensitivity of the sensor, was derived based on RCWA. A bioinspired grating model was constructed by mimicking the nanostructure on the ground scale of Morpho didius butterfly's wing. The analytical sensitivity was verified and the effect of the grating shape on the reflection spectra and its sensitivity were discussed. The results show that by tuning shape parameters of the grating, we can obtain desired reflection spectra and sensitivity, which can be applied to the design of the bioinspired refractive index based gas sensor.

  16. Chemical gas analyzers for proximate analysis of mine atmosphere

    Energy Technology Data Exchange (ETDEWEB)

    Pochenkova, T.K.; Klassovskaya, N.A.; Zlenko, A.G.; Gus' kova, A.N. (Vsesoyuznyi Nauchno-Issledovatel' skii Institut Gornogo Dela, Donetsk (Ukraine))


    Describes a series of chemical gas analyzers developed by the VNIIGD institute for proximate analysis of mine atmosphere in coal mines. The new GKh-4, GKh-5, GKh-6, GKh CO-5 use detector tubes for carbon monoxide and dioxide, nitrogen oxides, sulfur dioxide, oxygen and hydrogen sulfide. These devices allow miners to determine gas concentrations in the mine atmosphere in less than 4 minutes with an accuracy of +/-25%. The series is now complemented by the GKh-M CH[sub 2]O-0.004 gas analyzer for measuring formaldehyde content in mine air during mine rescue operations conducted with the use of carbamide-formaldehyde resins. Key technical data on the gas analyzers are given.

  17. Performance Analysis of Producer Gas Based Diesel Engine

    Directory of Open Access Journals (Sweden)

    J. P. Yadav


    Full Text Available Producer gas is one out of the alternative fuels used in internal combustion engines. Conventionally, it is made by flowing air and steam through a thick coal or coke bed which ranges in temperature from red hot to low temperature. The oxygen in air burns the carbon to CO2. This CO2 gets reduced to CO by contacting with carbon above the combustion zone. The freed oxygen combines with carbon and steam gets dissociated which introduces hydrogen. Producer gas has a high percentage of nitrogen since air is used [1]. Thus, in the present work a gasifier is designed and developed which could gasify any form of biomass. In the present work waste wood chips, bagasse, rice husk, and eucalyptus, etc are used for gasification in a fabricated updraft gasifier to produce producer gas. The producer gas obtained from the developed gasifier is sent along with air into a diesel engine with diesel as the primary fuel and the performance characteristics ie brake thermal efficiency, exhaust gas temperature and brake specific energy consumption of the engine are studied along with economic analysis with and without aid of producer gas.

  18. Versatile in situ gas analysis apparatus for nanomaterials reactors. (United States)

    Meysami, Seyyed Shayan; Snoek, Lavina C; Grobert, Nicole


    We report a newly developed technique for the in situ real-time gas analysis of reactors commonly used for the production of nanomaterials, by showing case-study results obtained using a dedicated apparatus for measuring the gas composition in reactors operating at high temperature (nanomaterials with tailored properties. Our studies demonstrate that the composition of the precursors dynamically changes as they travel inside of the reactor, causing a nonuniform growth of nanomaterials. Moreover, mapping of the nanomaterials reactor using quantitative gas analysis revealed the actual contribution of thermocatalytic cracking and a quantification of individual precursor fragments. This information is particularly important for quality control of the produced nanomaterials and for the recycling of exhaust residues, ultimately leading toward a more cost-effective continuous production of nanomaterials in large quantities. Our case study of multiwall carbon nanotube synthesis was conducted using the probe in conjunction with chemical vapor deposition (CVD) techniques. Given the similarities of this particular CVD setup to other CVD reactors and high-temperature setups generally used for nanomaterials synthesis, the concept and methodology of in situ gas analysis presented here does also apply to other systems, making it a versatile and widely applicable method across a wide range of materials/manufacturing methods, catalysis, as well as reactor design and engineering.

  19. Geospatial Analysis of Oil and Gas Wells in California (United States)

    Riqueros, N. S.; Kang, M.; Jackson, R. B.


    California currently ranks third in oil production by U.S. state and more than 200,000 wells have been drilled in the state. Oil and gas wells provide a potential pathway for subsurface migration, leading to groundwater contamination and emissions of methane and other fluids to the atmosphere. Here we compile available public databases on oil and gas wells from the California Department of Conservation's Division of Oil, Gas, and Geothermal Resources, the U.S. Geological Survey, and other state and federal sources. We perform geospatial analysis at the county and field levels to characterize depths, producing formations, spud/completion/abandonment dates, land cover, population, and land ownership of active, idle, buried, abandoned, and plugged wells in California. The compiled database is designed to serve as a quantitative platform for developing field-based groundwater and air emission monitoring plans.

  20. Speciation analysis by gas chromatography with plasma source spectrometric detection (United States)

    Łobiński, Ryszard; Adams, Freddy C.

    State-of-the-art species-selective analysis by gas chromatography (GC) with plasma source spectrometric detection is discussed for organometal and organometalloid compounds. Various plasmas, inductively coupled plasma, microwave induced plasma, capacitatively coupled plasma, direct current plasma and alternating current plasma, are characterized and critically compared as sources of radiation for atomic emission spectrometry and sources of ions for mass spectrometry. Interfaces between gas chromatography (packed, wide-bore, capillary and multicapillary) and plasma source spectrometry are characterized. Particular emphasis is given to applications of GC with plasma source detection to real-world analytical problems, which are comprehensively reviewed. The use of plasmas for the acquisition of auxiliary molecular information such as empirical formulae and structural information is discussed. Recent developments relating to sample preparation and presentation to the hyphenated system are addressed. The most significant trends in speciation analysis are highlighted.

  1. Electronic Nose Functionality for Breath Gas Analysis during Parabolic Flight (United States)

    Dolch, Michael E.; Hummel, Thomas; Fetter, Viktor; Helwig, Andreas; Lenic, Joachim; Moukhamedieva, Lana; Tsarkow, Dimitrij; Chouker, Alexander; Schelling, Gustav


    The presence of humans in space represents a constant threat for their health and safety. Environmental factors such as living in a closed confinement, as well as exposure to microgravity and radiation, are associated with significant changes in bone metabolism, muscular atrophy, and altered immune response, which has impacts on human performance and possibly results in severe illness. Thus, maintaining and monitoring of crew health status has the highest priority to ensure whole mission success. With manned deep space missions to moon or mars appearing at the horizon where short-term repatriation back to earth is impossible the availability of appropriate diagnostic platforms for crew health status is urgently needed. In response to this need, the present experiment evaluated the functionality and practicability of a metal oxide based sensor system (eNose) together with a newly developed breath gas collecting device under the condition of altering acceleration. Parabolic flights were performed with an Airbus A300 ZeroG at Bordeaux, France. Ambient air and exhaled breath of five healthy volunteers was analyzed during steady state flight and parabolic flight maneuvres. All volunteers completed the study, the breath gas collecting device valves worked appropriately, and breathing through the collecting device was easy and did not induce discomfort. During breath gas measurements, significant changes in metal oxide sensors, mainly sensitive to aromatic and sulphur containing compounds, were observed with alternating conditions of acceleration. Similarly, metal oxide sensors showed significant changes in all sensors during ambient air measurements. The eNose as well as the newly developed breath gas collecting device, showed appropriate functionality and practicability during alternating conditions of acceleration which is a prerequisite for the intended use of the eNose aboard the International Space Station (ISS) for breath gas analysis and crew health status

  2. Availability Analysis of Gas Turbines Used in Power Plants

    Directory of Open Access Journals (Sweden)

    Gilberto Francisco Martha de Souza


    Full Text Available The availability of a complex system, such as a gas turbine, is strongly associated with its parts reliability and maintenance policy. That policy not only has influence on the parts’ repair time but also on the parts’ reliability affecting the system degradation and availability. This study presents a method for reliability and availability evaluation of gas turbines installed in an electric power station. The method is based on system reliability concepts, such as functional tree development, application of failure mode and effects analysis to identify critical components for improvement of system reliability, and reliability and maintainability evaluation based on a historical failure database. The method also proposes the application of Reliability Centered Maintenance concepts to improve complex system maintenance policies aimed at the reduction of unexpected failure occurrences in critical components. The method is applied to the analysis of two F series gas turbines, each with an output of 150 MW, installed in a 500 MW combined cycle power plant. The reliability and availability of the turbines are simulated based on a five-year failure database. The availability analysis shows different results for each turbine, one presenting 99% and the other 96% availability, indicating differences in their systems installation and operation.

  3. Well-test analysis for solution-gas-drive reservoirs. Part 2; Buildup analysis

    Energy Technology Data Exchange (ETDEWEB)

    Serra, K.V.; Peres, A.M.M. (PETROBRAS, Rio de Janeiro, RJ (Brazil)); Reynolds, A.C. (Tulsa Univ., OK (USA))


    This work presents new analysis methods for pressure-buildup data from a well completed in a solution-gas-drive reservoir. New procedures for estimating effective phase permeabilities as functions of pressure and saturation are presented.

  4. Green (as) gas. An analysis of the green gas chain; Groen (als) gas. Een analyse van de groen-gasketen

    Energy Technology Data Exchange (ETDEWEB)

    Tempelman, D.G. [Rijksuniversiteit Groningen RUG, Groningen (Netherlands)


    For over twenty years, biogas has been upgraded to natural gas quality (green gas) and fed into the natural gas grid on a small scale. This article provides an overview of the legal and technical aspects in relation to the green gas chain [Dutch] Al ruim twee decennia wordt biogas opgewaardeerd tot aardgaskwaliteit (groen gas) en op kleinschalig niveau ingevoed in het aardgasnet. Er wordt een overzicht gegeven van de juridische en technische aspecten die samenhangen met de 'groen gas keten'.

  5. Technical and financial analysis of combined cycle gas turbine

    Directory of Open Access Journals (Sweden)

    Khan Arshad Muhammad


    Full Text Available This paper presents technical and financial models which were developed in this study to predict the overall performance of combined cycle gas turbine plant in line with the needs of independent power producers in the liberalized market of power sector. Three similar sizes of combined cycle gas turbine power projects up to 200 Megawatt of independent power producers in Pakistan were selected in-order to develop and drive the basic assumptions for the inputs of the models in view of prevailing Government of Pakistan’s two components of electricity purchasing tariff that is energy purchase price and capacity purchase price at higher voltage grid station terminal from independent power producers. The levelized electricity purchasing tariff over life of plant on gaseous fuel at 60 percent plant load factor was 6.47 cent per kilowatt hour with energy purchase price and capacity purchase prices of 3.54 and 2.93 cents per kilowatt hour respectively. The outcome of technical models of gas turbine, steam turbine and combined cycle gas turbine power were found in close agreement with the projects under consideration and provides opportunity of evaluation of technical and financial aspects of combined cycle power plant in a more simplified manner with relatively accurate results. At 105 Celsius exit temperature of heat recovery steam generator flue gases the net efficiency of combined cycle gas turbine was 48.8 percent whereas at 125 Celsius exit temperature of heat recovery steam generator flue gases it was 48.0 percent. Sensitivity analysis of selected influential components of electricity tariff was also carried out.

  6. Isotopic gas analysis through Purcell cavity enhanced Raman scattering (United States)

    Petrak, B.; Cooper, J.; Konthasinghe, K.; Peiris, M.; Djeu, N.; Hopkins, A. J.; Muller, A.


    Purcell enhanced Raman scattering (PERS) by means of a doubly resonant Fabry-Perot microcavity (mode volume ≈ 100 μm3 and finesse ≈ 30 000) has been investigated as a technique for isotopic ratio gas analysis. At the pump frequency, the resonant cavity supports a buildup of circulating power while simultaneously enabling Purcell spontaneous emission rate enhancement at the resonant Stokes frequency. The three most common isotopologues of CO2 gas were quantified, and a signal was obtained from 13C16O2 down to a partial pressure of 2 Torr. Due to its small size and low pump power needed (˜10 mW) PERS lends itself to miniaturization. Furthermore, since the cavity is resonant with the emission frequency, future improvements could allow it to serve as its own spectral analyzer and no separate spectroscopic device would be needed.

  7. Gas chromatographic technologies for the analysis of essential oils. (United States)

    Marriot, P J; Shellie, R; Cornwell, C


    Essential oil analysis has basically had one technical goal: to achieve the best possible separation performance by using the most effective, available technology of the day. The result achieved from this may then be used to answer the research or industrial analysis questions which necessitated the analysis. This may be for comparative purposes, where one oil is contrasted with other(s) for quality control or investigation of adulteration, to discover new components, or to characterise the chemical classes of compounds present. Clearly, today the analyst turns to chromatography as the provider of separation and then may supplement that with mass spectrometry to aid identification. The power of GC-MS means that advances in both the separation technique, and improvements in mass spectrometry detection - along with improved data handling tools - will immediately be relevant to the essential oil area. This present review outlines the developmental nature of instrumental approaches to essential oil analysis using gas chromatography. Mass spectrometry will be included to the extent that it represents the hyphenation of choice for most analysts when analysing essential oils. Thus single-column and multi-dimensional analysis will be covered, as will sample handling or introduction techniques prior to the analysis step, where these techniques provide some measure of separation. The recent demonstration of comprehensive gas chromatography will be discussed as the potentially most powerful separation method for essential oils. This brief review is not intended to be a comprehensive dissertation on the field of essential oil analysis since that would require sufficient space to occupy a book in its own right. Rather, it will outline selected considerations and developments, to help explain where new technology has been applied to advantage in this field.

  8. Thermal/Pyrolysis Gas Flow Analysis of Carbon Phenolic Material (United States)

    Clayton, J. Louie


    Provided in this study are predicted in-depth temperature and pyrolysis gas pressure distributions for carbon phenolic materials that are externally heated with a laser source. Governing equations, numerical techniques and comparisons to measured temperature data are also presented. Surface thermochemical conditions were determined using the Aerotherm Chemical Equilibrium (ACE) program. Surface heating simulation used facility calibrated radiative and convective flux levels. Temperatures and pyrolysis gas pressures are predicted using an upgraded form of the SINDA/CMA program that was developed by NASA during the Solid Propulsion Integrity Program (SPIP). Multispecie mass balance, tracking of condensable vapors, high heat rate kinetics, real gas compressibility and reduced mixture viscosity's have been added to the algorithm. In general, surface and in-depth temperature comparisons are very good. Specie partial pressures calculations show that a saturated water-vapor mixture is the main contributor to peak in-depth total pressure. Further, for most of the cases studied, the water-vapor mixture is driven near the critical point and is believed to significantly increase the local heat capacity of the composite material. This phenomenon if not accounted for in analysis models may lead to an over prediction in temperature response in charring regions of the material.

  9. Gas-liquid chromatography in lunar organic analysis. (United States)

    Gehrke, C. W.


    Gas-liquid chromatography (GLC) is a powerful and sensitive method for the separation and detection of organic compounds at nanogram levels. The primary requirement for successful analyses is that the compounds of interest must be volatile under the chromatographic conditions employed. Nonvolatile organic compounds must be converted to volatile derivatives prior to analysis. The derivatives of choice must be both amenable to chromatographic separation and be relatively stable. The condition of volatility necessitates the development of efficient derivatization reactions for important groups of compounds as amino acids, carbohydrates, nucleosides, etc. Trimethylsilylation and trifluoroacetylation represent specific areas of recent prominence. Some relevant practical aspects of GLC are discussed.

  10. Analysis of Water Features in Gas Leakage Area

    Directory of Open Access Journals (Sweden)

    Liu Huaishan


    Full Text Available In a certain frequency range, gas is an effective absorber and scatterer of sound, which changes the compressibility of water, and then changes the speed and frequency of sound. Gas continues rising, deforming, and dissolving. The same bubble of natural gas has different radii at different depths. By analyzing these changes, the resonance frequency of gas bubble, and its impacts on sound wave, characteristics of the influences of gas at different depths on the incident sound wave can be obtained. The main sound features of gas are relevant to the gas size, gas content, velocity, attenuation, resonance frequency, the scattering cross-section, and so forth. Sound models with hydrate and free gas in the water and sediment are established. Through the practical application to actual data, the sound characteristics yielded when the gas (or gas hydrate dissociation escaped the water of seismic data are very clear.

  11. Practical approach on gas pipeline compression system availability analysis

    Energy Technology Data Exchange (ETDEWEB)

    Santos, Sidney Pereira dos [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil); Kurz, Rainer; Lubomirsky, Matvey [Solar Turbines, San Diego, CA (United States)


    Gas pipeline projects traditionally have been designed based on load factor and steady state flow. This approach exposes project sponsors to project sustainability risks due to potential losses of revenues and transportation contract penalties related to pipeline capacity shortage as consequence of compressor unit's unavailability. Such unavailability should previously be quantified during the design phase. This paper presents a case study and a methodology that highlights the practical benefits of applying Monte Carlo simulation for the compression system availability analysis in conjunction with quantitative risk analysis and economic feasibility study. Project economics main variables and their impacts on the project NPV (Net Present Value) are evaluated with their respective statistics distribution to quantify risk and support decision makers to adopt mitigating measures to guarantee competitiveness while protecting project sponsors from otherwise unpredictable risks. This practical approach is compared to load factor approach and the results are presented and evaluated. (author)

  12. [Quantitative analysis of butachlor, oxadiazon and simetryn by gas chromatography]. (United States)

    Liu, F; Mu, W; Wang, J


    The quantitative analysis of the ingredients in 26% B-O-S (butachlor, oxadiazon and simetryn) emulsion by gas chromatographic method was carried out with a 5% SE-30 on Chromosorb AW DMCS, 2 m x 3 mm i.d., glass column at column temperature of 210 degrees C and detector temperature of 230 degrees C. The internal standard is di-n-butyl sebacate. The retentions of simetryn, internal standard, butachlor and oxadiazon were 6.5, 8.3, 9.9 and 11.9 min respectively. This method has a recovery of 98.62%-100.77% and the coefficients of variation of this analysis of butachlor, oxadiazon and simetryn were 0.46%, 0.32% and 0.57% respectively. All coefficients of linear correlation were higher than 0.999.

  13. Semilog analysis of gas well drawdown and buildup data

    Energy Technology Data Exchange (ETDEWEB)

    Reynolds, A.C.; Bratvold, R.G.; Ding, W.


    The pseudo-pressure function is well understood and widely used for analyzing gas well drawdown and buildup data. The utility of the pseudo-time function for analyzing buildup data using drawdown type curves also has been established. Unfortunately, the pseudotime concept is often incorrectly applied when analyzing drawdown data by semilog methods. This work provides information on appropriate definitions of time which yield accurate analysis of data obtained under radial flow conditions. From the pratical viewpoint, the most important result is that there exist two Horner time ratios, one based on a normalized shut-in time and one based on shut-in pseudo-time which yield an accurate analysis of buildup data including the correct determination of average pressure using the liquid Matthews-Brons-Hazebroek functions.

  14. Semilog analysis of gas well drawdown and buildup data

    Energy Technology Data Exchange (ETDEWEB)

    Reynolds, A.C.; Bratvold, R.B.; Ding, W.


    The pseudopressure function is well understood and widely used for analyzing gas well drawdown and buildup data. The usefulness of the pseudotime function for analyzing buildup data with drawdown type curves has also been established. Unfortunately, the pseudotime concept is often incorrectly applied when drawdown data are analyzed by semilog methods. This work provides information on appropriate definitions of dimensionless time that yield accurate analysis of data obtained under radial flow conditions. From the practical viewpoint, the most important result is that two Horner time ratios exist - one based on a normalized shut-in time and one based on shut-in pseudotime - that yield an accurate analysis of buildup data, including the correct determination of average pressure using the liquid Matthews-Brons-Hazebroek (MBH) functions.

  15. Gas Analysis and Monitoring Systems for the RPC Detector of CMS at LHC

    CERN Document Server

    Abbrescia, M; Guida, R; Iaselli, G; Liuzzi, R; Loddo, F; Maggi, M; Marangelli, B; Natali, S; Nuzzo, S; Pugliese, G; Ranieri, A; Romano, F; Trentadue, R; Benussi, L; Bertani, M; Bianco, S; Caponero, M A; Colonna, D; Donisi, D; Fabbri, F L; Felli, F; Ortenzi, M G B; Pallotta, M; Paolozzi, A; Passamonti, L; Ponzio, B; Pucci, C; Polese, G S G; Segoni, I; Cavallo, N; Fabozzi, F; Paolucci, P; Piccolo, D; Belli, C S G; Grelli, A; Necchi, M; Ratti, S P; Riccardi, C; Torre, P; Vitulo, P


    The Resistive Plate Chambers (RPC) detector of the CMS experiment at the LHC proton collider (CERN, Switzerland) will employ an online gas analysis and monitoring system of the freon-based gas mixture used. We give an overview of the CMS RPC gas system, describe the project parameters and first results on gas-chromatograph analysis. Finally, we report on preliminary results for a set of monitor RPC.

  16. Thermoeconomic analysis of mixed gas-steam cycles

    Energy Technology Data Exchange (ETDEWEB)

    Traverso, A.; Massardo, A.F. [Universita di Genova (Italy). Dip. di Macchine, Sistemi Energetici e Trasporti


    In this paper the direct thermoeconomic analysis approach developed by the authors [ASME Paper 95-CTP-38; ASME Cogen Turbo Power Conference, Wien, 23/25 August, 1995] is applied to the assessment of the thermoeconomic performance of mixed gas-steam cycles such as the steam injected cycle (steam injected gas turbine, STIG), regenerated water injected (RWI) cycle, and humid air turbine (HAT) or evaporative cycle. All the simulations were carried using the thermo-economic modular program (TEMP) code developed at the University of Genoa [ASME Trans., J. Engng. Gas Turbine Power 119 (1997) 885; Thermo-economic and environmental optimisation of energy systems, Tesi di Dottorato, Universita di Genova (DIMSET),1997] and carefully tested here, mainly for the HAT cycle and saturator, using the experimental data provided by the HAT pilot-plant operating at the Lund University, Sweden [Theoretical and experimental evaluation of the EvGT-process, Thesis for Degree of Licentiate in Engineering, Lund Institute of Technology, Sweden, 1999; Evaporative cycles - in theory and in practice, Doctoral Thesis, Lund Institute of Technology, Sweden, 2000]. Three different mixed cycles (STIG, RWI, and HAT) are analysed in detail together with an additional fourth layout proposed by the authors [Thermodynamic analysis of STIG, RWI and HAT cycles with carbon dioxide (CO{sub 2}) emissions penalty, Tesi di laurea, Universita di Genova (DIMSET),2000], named HAWIT, humid air water injection turbine, that appears to be the most attractive solution. The thermoeconomic results of mixed cycles are presented here for the first time in open literature. These results are compared to the data of a conventional two-pressure level combined cycle considered as representative of the state of the art of high efficiency conversion systems. A new representation proposed by the authors [ASME Trans., J. Engng. Gas Turbine Power 122 (2000)] such as cost of electricity versus cycle efficiency or internal rate of

  17. Analysis of Halogen-Mercury Reactions in Flue Gas

    Energy Technology Data Exchange (ETDEWEB)

    Paula Buitrago; Geoffrey Silcox; Constance Senior; Brydger Van Otten


    Oxidized mercury species may be formed in combustion systems through gas-phase reactions between elemental mercury and halogens, such as chorine or bromine. This study examines how bromine species affect mercury oxidation in the gas phase and examines the effects of mixtures of bromine and chlorine on extents of oxidation. Experiments were conducted in a bench-scale, laminar flow, methane-fired (300 W), quartz-lined reactor in which gas composition (HCl, HBr, NO{sub x}, SO{sub 2}) and temperature profile were varied. In the experiments, the post-combustion gases were quenched from flame temperatures to about 350 C, and then speciated mercury was measured using a wet conditioning system and continuous emissions monitor (CEM). Supporting kinetic calculations were performed and compared with measured levels of oxidation. A significant portion of this report is devoted to sample conditioning as part of the mercury analysis system. In combustion systems with significant amounts of Br{sub 2} in the flue gas, the impinger solutions used to speciate mercury may be biased and care must be taken in interpreting mercury oxidation results. The stannous chloride solution used in the CEM conditioning system to convert all mercury to total mercury did not provide complete conversion of oxidized mercury to elemental, when bromine was added to the combustion system, resulting in a low bias for the total mercury measurement. The use of a hydroxylamine hydrochloride and sodium hydroxide solution instead of stannous chloride showed a significant improvement in the measurement of total mercury. Bromine was shown to be much more effective in the post-flame, homogeneous oxidation of mercury than chlorine, on an equivalent molar basis. Addition of NO to the flame (up to 400 ppmv) had no impact on mercury oxidation by chlorine or bromine. Addition of SO{sub 2} had no effect on mercury oxidation by chlorine at SO{sub 2} concentrations below about 400 ppmv; some increase in mercury oxidation

  18. Performance analysis for underground gas storage reservoir in depleted gas field

    Institute of Scientific and Technical Information of China (English)

    谭羽飞; 陈家新


    The construction of underground natural gas storage is one of the most reasonable and effective ways for basically surmounting city seasonal peak shaving and stabilizing peak waving. Owing to the heterogeneity of geological structure used as underground natural gas storage and different capacities of storing and transmitting fluid in reservoir, it is necessary make a reasonable proration for each member of the injection and production wells within the storage during peak shaving. In this paper, through analyzing the injection-production performance characteristics of the underground natural gas storage in depleted gas field, an accurate mathematical model of the underground gas storage of depleted gas field is set up; characteristics of the storage performance and permeating processes were studied,history processes of underground gas storage were stimulated and major influence factors were analyzed. Specific and typical examples from actural data are included to demonstrate the relevance of the method to simulation of storage operation.

  19. Hydraulic analysis of the operation of oil and gas wells

    Energy Technology Data Exchange (ETDEWEB)

    Gabor, T.; Szaharov, V.A.; Szilas, A.P.


    The results are cited of a study of the operation of operational oil and gas wells. A hydraulic system of operational wells is identified for the first time, which consists of elements of a stratum, well and surface equipment system. After a brief presentation of the rating methods which describe the operation of the elements, the methods for hydraulic analysis of the complete system are detailed. After theoretical presentation of the methods, the course of computer (EVM) programs, developed for practical purposes, is shown. These programs may be used to solve two basic problems in gusher extraction of oil: identification of the maximal flow rate of a gusher well and the operational point of a well which has a wellhead coupling.

  20. Direct analysis of ultra-trace semiconductor gas by inductively coupled plasma mass spectrometry coupled with gas to particle conversion-gas exchange technique. (United States)

    Ohata, Masaki; Sakurai, Hiromu; Nishiguchi, Kohei; Utani, Keisuke; Günther, Detlef


    An inductively coupled plasma mass spectrometry (ICPMS) coupled with gas to particle conversion-gas exchange technique was applied to the direct analysis of ultra-trace semiconductor gas in ambient air. The ultra-trace semiconductor gases such as arsine (AsH3) and phosphine (PH3) were converted to particles by reaction with ozone (O3) and ammonia (NH3) gases within a gas to particle conversion device (GPD). The converted particles were directly introduced and measured by ICPMS through a gas exchange device (GED), which could penetrate the particles as well as exchange to Ar from either non-reacted gases such as an air or remaining gases of O3 and NH3. The particle size distribution of converted particles was measured by scanning mobility particle sizer (SMPS) and the results supported the elucidation of particle agglomeration between the particle converted from semiconductor gas and the particle of ammonium nitrate (NH4NO3) which was produced as major particle in GPD. Stable time-resolved signals from AsH3 and PH3 in air were obtained by GPD-GED-ICPMS with continuous gas introduction; however, the slightly larger fluctuation, which could be due to the ionization fluctuation of particles in ICP, was observed compared to that of metal carbonyl gas in Ar introduced directly into ICPMS. The linear regression lines were obtained and the limits of detection (LODs) of 1.5 pL L(-1) and 2.4 nL L(-1) for AsH3 and PH3, respectively, were estimated. Since these LODs revealed sufficiently lower values than the measurement concentrations required from semiconductor industry such as 0.5 nL L(-1) and 30 nL L(-1) for AsH3 and PH3, respectively, the GPD-GED-ICPMS could be useful for direct and high sensitive analysis of ultra-trace semiconductor gas in air.

  1. Scenario analysis of gas crisis using the European Gas Assessment Model (EUGas)




    The European Gas Assessment model (EUGas) is a country level model of the European gas transmission pipeline network which is being developed by JRC-IET (Joint Research Centre – Institute for Energy and Transport). The model aims at supporting Directive 2008/114/EC on “the identification and designation of European Critical Infrastructure (ECI)” and Regulation 994/2010 on “measures to safeguard security of gas supply”. The hydraulic model of the European gas network is developed using a combi...

  2. Technology and Greenhouse Gas Emissions: An IntegratedScenario Analysis

    Energy Technology Data Exchange (ETDEWEB)

    Koomey, J.G.; Latiner, S.; Markel, R.J.; Marnay, C.; Richey, R.C.


    This report describes an analysis of possible technology-based scenarios for the U.S. energy system that would result in both carbon savings and net economic benefits. We use a modified version of the Energy Information Administration's National Energy Modeling System (LBNL-NEMS) to assess the potential energy, carbon, and bill savings from a portfolio of carbon saving options. This analysis is based on technology resource potentials estimated in previous bottom-up studies, but it uses the integrated LBNL-NEMS framework to assess interactions and synergies among these options. The analysis in this paper builds on previous estimates of possible "technology paths" to investigate four major components of an aggressive greenhouse gas reduction strategy: (1) the large scale implementation of demand-side efficiency, comparable in scale to that presented in two recent policy studies on this topic; (2) a variety of "alternative" electricity supply-side options, including biomass cofiring, extension of the renewable production tax credit for wind, increased industrial cogeneration, and hydropower refurbishment. (3) the economic retirement of older and less efficient existing fossil-find power plants; and (4) a permit charge of $23 per metric ton of carbon (1996 $/t),l assuming that carbon trading is implemented in the US, and that the carbon permit charge equilibrates at this level. This level of carbon permit charge, as discussed later in the report, is in the likely range for the Clinton Administration's position on this topic.

  3. An analysis of the types and distribution characteristics of natural gas reservoirs in China

    Institute of Scientific and Technical Information of China (English)

    Xu Zhangyou; Yue Dali; Wu Shenghe; Zhang Xiaoyu; Chen Ce; Ni Yuqiang


    The natural gas reservoir beds of different areas in China can be divided into three kinds,clastic natural gas reservoir bed, carbonate natural gas reservoir bed and special natural gas reservoir bed. They have different combination patterns controlled by deposition, diagenesis and tectonism. Our analysis indicates that the natural gas reservoirs are mainly distributed in the Precambrian, Palaeozoic, Mesozoic, and Tertiary-Quaternary. Craton basin, foreland basin and intracontinental rift basin which contain most of natural gas in China have special geological features and favorable accumulation conditions, and will be important exploration areas in the future.

  4. Theoretical and experimental analysis of a multiphase screw pump, handling gas-liquid mixtures with very high gas volume fractions

    Energy Technology Data Exchange (ETDEWEB)

    Raebiger, K. [LEISTRITZ Pumpen GmbH, Nuremberg (Germany); Faculty of Advanced Technology, University of Glamorgan, Pontypridd, Wales (United Kingdom); Maksoud, T.M.A.; Ward, J. [Faculty of Advanced Technology, University of Glamorgan, Pontypridd, Wales (United Kingdom); Hausmann, G. [Department of Mechanical Engineering and Building Services Engineering, University of Applied Sciences, Nuremberg (Germany)


    In the investigation of the pumping behaviour of multiphase screw pumps, handling gas-liquid mixtures with very high gas volume fractions, theoretical and experimental analyses were performed. A new theoretical screw pump model was developed, which calculates the time-dependent conditions inside the several chambers of a screw pump as well as the exchange of mass and energy between these chambers. By means of the performed experimental analysis, the screw pump model was verified, especially at very high gas volume fractions from 90% to 99%. The experiments, which were conducted with the reference fluids water and air, can be divided mainly into the determination of the steady state pumping behaviour on the one hand and into the analysis of selected transient operating conditions on the other hand, whereas the visualisation of the leakage flows through the circumferential gaps was rounded off the experimental analysis. (author)

  5. Methodology for in situ gas sampling, transport and laboratory analysis of gases from stranded cetaceans (United States)

    de Quirós, Yara Bernaldo; González-Díaz, Óscar; Saavedra, Pedro; Arbelo, Manuel; Sierra, Eva; Sacchini, Simona; Jepson, Paul D.; Mazzariol, Sandro; di Guardo, Giovanni; Fernández, Antonio


    Gas-bubble lesions were described in cetaceans stranded in spatio-temporal concordance with naval exercises using high-powered sonars. A behaviourally induced decompression sickness-like disease was proposed as a plausible causal mechanism, although these findings remain scientifically controversial. Investigations into the constituents of the gas bubbles in suspected gas embolism cases are highly desirable. We have found that vacuum tubes, insulin syringes and an aspirometer are reliable tools for in situ gas sampling, storage and transportation without appreciable loss of gas and without compromising the accuracy of the analysis. Gas analysis is conducted by gas chromatography in the laboratory. This methodology was successfully applied to a mass stranding of sperm whales, to a beaked whale stranded in spatial and temporal association with military exercises and to a cetacean chronic gas embolism case. Results from the freshest animals confirmed that bubbles were relatively free of gases associated with putrefaction and consisted predominantly of nitrogen.

  6. Technical and Feasibility Analysis of Gasoline and Natural Gas Fuelled Vehicles


    Charalambos Chasos; George Karagiorgis; Chris Christodoulou


    There is recent interest for the utilisation of natural gas for empowering the internal combustion engines (ICE) of vehicles. The production of novel natural gas ICE for vehicles, as well as the conversion of existing gasoline fuelled ICE of vehicles to natural gas fuelled ICE are new technologies which require to be analysed and assessed. The objective of the present study is to examine the adaptation of natural gas as vehicle fuel and carry out a technical analysis and an economical feasibi...

  7. Gas film disturbance characteristics analysis of high-speed and high-pressure dry gas seal (United States)

    Chen, Yuan; Jiang, Jinbo; Peng, Xudong


    The dry gas seal(DGS) has been widely used in high parameters centrifugal compressor, but the intense vibrations of shafting, especially in high-speed condition, usually result in DGS's failure. So the DGS's ability of resisting outside interference has become a determining factor of the further development of centrifugal compressor. However, the systematic researches of which about gas film disturbance characteristics of high parameters DGS are very little. In order to study gas film disturbance characteristics of high-speed and high-pressure spiral groove dry gas seal(S-DGS) with a flexibly mounted stator, rotor axial runout and misalignment are taken into consideration, and the finite difference method and analytical method are used to analyze the influence of gas film thickness disturbance on sealing performance parameters, what's more, the effects of many key factors on gas film thickness disturbance are systematically investigated. The results show that, when sealed pressure is 10.1MPa and seal face average linear velocity is 107.3 m/s, gas film thickness disturbance has a significant effect on leakage rate, but has relatively litter effect on open force; Excessively large excitation amplitude or excessively high excitation frequency can lead to severe gas film thickness disturbance; And it is beneficial to assure a smaller gas film thickness disturbance when the stator material density is between 3.1 g/cm3 to 8.4 g/cm3; Ensuring sealing performance while minimizing support axial stiffness and support axial damping can help to improve dynamic tracking property of dry gas seal. The proposed research provides the instruction to optimize dynamic tracking property of the DGS.

  8. Gas Line Pressure Fluctuation Analysis of a Gas-Liquid Reactor

    Institute of Scientific and Technical Information of China (English)

    J.J.J. CHEN; J.C. ZHAO


    To ensure efficient operation of metallurgical gas-liquid reactors, the gas bubbles must be uniformly distributed.For high temperature metallurgical reactors, it is impractical and unsafe to carry out visual observations.An air-water model was used to study the relationship between the bubble flow patterns and the pressure fluctuation signals.The fluctuation signals captured in the time domain were transformed into the frequency domain. Various parameters obtained from the transformed data were analysed for their suitability for delineating the bubble flow pqtterns observed.These parameters and the flow patterns were found to be well-correlated using the gas flow number.

  9. Analysis of carbon dioxide emission of gas fuelled cogeneration plant (United States)

    Nordin, Adzuieen; Amin, M.; Majid, A.


    Gas turbines are widely used for power generation. In cogeneration system, the gas turbine generates electricity and the exhaust heat from the gas turbine is used to generate steam or chilled water. Besides enhancing the efficiency of the system, the process assists in reducing the emission of CO2 to the environment. This study analyzes the amount of CO2 emission by Universiti Teknologi Petronas gas fuelled cogeneration system using energy balance equations. The results indicate that the cogeneration system reduces the CO2 emission to the environment by 60%. This finding could encourage the power plant owners to install heat recovery systems to their respective plants.

  10. Economics of lifecycle analysis and greenhouse gas regulations (United States)

    Rajagopal, Deepak


    Interest in alternatives to fossil fuels has risen significantly during the current decade. Although a variety of different alternative technologies have experienced rapid growth, biofuels have emerged as the main alternative transportation fuel. Energy policies in several countries envision blending biofuels with fossil fuels as the main mechanism to increase energy independence and energy security. Climate change policies in several regions are also riding on the same hope for reducing emissions from transportation. The main advantage of biofuels is that they are technically mature, cheaper to produce and more convenient to use relative to other alternative fuels. However, the impact of current biofuels on the environment and on economic welfare, is controversial. In my dissertation I focus on three topics relevant to future energy and climate policies. The first is the economics of lifecycle analysis and its application to the assessment of environmental impact of biofuel policies. The potential of biofuel for reducing greenhouse gas emissions was brought to the fore by research that relied on the methodology called lifecycle analysis (LCA). Subsequent research however showed that the traditional LCA fails to account for market-mediated effects that will arise when biofuel technologies are scaled up. These effects can increase or decrease emissions at each stage of the lifecycle. I discuss how the LCA will differ depending on the scale, a single firm versus a region and why LCA of the future should be distinguished from LCA of the past. I describe some approaches for extending the LCA methodology so that it can be applied under these different situations. The second topic is the economic impact of biofuels. Biofuels reduce the demand for oil and increase the demand for agricultural goods. To high income countries which tend to be both large importers of oil and large exporters of agricultural goods, this implies two major benefits. One of the one hand it reduces

  11. Applications of laser-photoacoustic gas analysis method

    Energy Technology Data Exchange (ETDEWEB)

    Hernberg, R.; Stenberg, J. [Tampere Univ. of Technology (Finland). Dept. of Physics


    The dynamic behavior of a circulating fluidized bed boiler (CFB) was studied using two high speed gas analysis systems during combustion of coal, peat and wood chips. Time resolved concentrations of some pollutants (SO{sub 2}, NO, NH{sub 3} and H{sub 2}S) were measured using laser induced photoacoustic spectroscopy (LIPS). A zirkonia cell based probe (lambda-probe) was used in synchronization with the LIPS-probe to measure fluctuations between reducing and oxidizing conditions. The two probes were positioned in the same measurement volume on the center-line of the combustion chamber of the CFB. The purpose of the measurements was to investigate the behavior of the LIPS in a combustion chamber containing large amounts of other unburnt hydrocarbons. The correlations between oxidizing and reducing conditions and concentrations at three locations in the combustion chamber are presented. The best correlations were found in the upper part of the CFB combustion chamber. In some cases the correlations between reducing conditions and the LIPS signal were caused by hydrocarbons. Comparison of the average values obtained by the LIPS-system for NO and SO{sub 2} with the result from a sampling probe system connected to on-line analysers was also carried out. (author)

  12. Application of parabolic reflector on Raman analysis of gas samples (United States)

    Yu, Anlan; Zuo, Duluo; Gao, Jun; Li, Bin; Wang, Xingbing


    Studies on the application of a parabolic reflector in spontaneous Raman scattering for low background Raman analysis of gas samples are reported. As an effective signal enhancing sample cell, photonic bandgap fiber (HC-PBF) or metallined capillary normally result in a strong continuous background in spectra caused by the strong Raman/fluorescence signal from the silica wall and the polymer protective film. In order to obtain enhanced signal with low background, a specially designed sample cell with double-pass and large collecting solid angle constructed by a parabolic reflector and a planar reflector was applied, of which the optical surfaces had been processed by diamond turning and coated by silver film and protective film of high-purity alumina. The influences of optical structure, polarization characteristic, collecting solid-angle and collecting efficiency of the sample cell on light propagation and signal enhancement were studied. A Raman spectrum of ambient air with signal to background ratio of 94 was acquired with an exposure time of 1 sec by an imaging spectrograph. Besides, the 3σ limits of detection (LOD) of 7 ppm for H2, 8 ppm for CO2 and 12 ppm for CO were also obtained. The sample cell mainly based on parabolic reflector will be helpful for compact and high-sensitive Raman system.

  13. Stability analysis of an encapsulated microbubble against gas diffusion. (United States)

    Katiyar, Amit; Sarkar, Kausik


    Linear stability analysis is performed for a mathematical model of diffusion of gases from an encapsulated microbubble. It is an Epstein-Plesset model modified to account for encapsulation elasticity and finite gas permeability. Although bubbles, containing gases other than air, are considered, the final stable bubble, if any, contains only air, and stability is achieved only when the surrounding medium is saturated or oversaturated with air. In absence of encapsulation elasticity, only a neutral stability is achieved for zero surface tension, the other solution being unstable. For an elastic encapsulation, different equilibrium solutions are obtained depending on the saturation level and whether the surface tension is smaller or higher than the elasticity. For an elastic encapsulation, elasticity can stabilize the bubble. However, imposing a non-negativity condition on the effective surface tension (consisting of reference surface tension and the elastic stress) leads to an equilibrium radius which is only neutrally stable. If the encapsulation can support a net compressive stress, it achieves actual stability. The linear stability results are consistent with our recent numerical findings. Physical mechanisms for the stability or instability of various equilibriums are provided.

  14. Analysis of Chinese Accounting Standards for the Oil and Gas Industry and Related Enterprises

    Institute of Scientific and Technical Information of China (English)


    Accounting standards are the tools for distribution of the revenues. Their development trend is influenced by their stakeholders. The evolution of American oil and gas accounting standards has been shaped by the profit-maximizing process of American oil and gas company shareholders, which for outside lobbying relied on their huge capital and organization. The development and perfection of Chinese new oil and gas accounting standards should consider not only the criterion of standards but also the real political fact in China oil and gas industry. The research on oil and gas accounting standards is an academic study as well as a political analysis.

  15. Gas hydrates and magnetism : comparative geological settings for diagenetic analysis

    Energy Technology Data Exchange (ETDEWEB)

    Esteban, L.; Enkin, R.J. [Natural Resources Canada, Sidney, BC (Canada). Geological Survey of Canada; Hamilton, T. [Camosun College, Victoria, BC (Canada)


    Geophysical and geochemical methods assist in locating and quantifying natural gas hydrate deposits. They are also useful in understanding these resources, their climate impacts and their potential role in geohazards. In order to understand the mechanisms of gas hydrate formation and its natural distribution in sediments, magnetic studies were conducted on cores from three different geological settings. This paper presented the results of a detailed magnetic investigation, as well as petrological observations, that were conducted on cores from a permafrost setting in the Mackenzie Delta located in the Canadian Northwest Territories Mallik region, and two marine settings, from the Cascadia margin off Vancouver Island and the Indian National Gas Hydrate Program from the Bengal Fan. The paper provided background information on the permafrost setting in Mallik region of the Mackenzie Delta as well as the Cascadia margin. The magnetic properties of gas hydrate bearing sediments were found to be a combination of the original detrital content and the diagenetic transformations of iron minerals caused by the unique environment produced by gas hydrate formation. The availability of methane to provide food for bacteria coupled with the concentration of solutes outside gas hydrate accumulation zones led to the creation of iron sulphides. These new minerals were observable using magnetic techniques, which help in delineating the gas hydrate formation mechanism and may be developed into new geophysical methods of gas hydrate exploration. 7 refs., 7 figs.

  16. Rapid analysis of urinary opiates using fast gas chromatography–mass spectrometry and hydrogen as a carrier gas

    Directory of Open Access Journals (Sweden)

    Sumandeep Rana


    Gas chromatographic–mass spectrometric analysis was performed in electron ionization mode by selective ion monitoring, using hydrogen as a carrier gas, a short narrow bore GC capillary column, and fast temperature program, allowing for a rapid analytical cycle to maximize the instrument time for high throughput laboratories. While maintaining specificity for these drugs, concentrations in human urine ranging from 50 to 5,000 ng/mL can be measured with intraday and interday imprecision, expressed as variation coefficients, of less than 2.3% for all analytes within a run time of less than 3.5 minutes.

  17. Bohai crude oil identification by gas chromatogram fingerprinting quantitative analysis coupled with cluster analysis

    Institute of Scientific and Technical Information of China (English)

    SUN Peiyan; BAO Mutai; GAO Zhenhui; LI Mei; ZHAO Yuhui; WANG Xinping; ZHOU Qing; WANG Xiulin


    By gas chromatogram, six crude oils fingerprinting distributed in four oilfields and four oil platforms were analyzed and the corresponding normal paraffin hydrocarbon (including pristane and phytane) concentration was obtained by the internal standard method. The normal paraffin hydrocarbon distribution patterns of six crude oils were built and compared. The cluster analysis on the normal paraffin hydrocarbon concentration was conducted for classification and some ratios of oils were used for oils comparison. The results indicated: there was a clear difference within different crude oils in different oil fields and a small difference between the crude oils in the same oil platform. The normal paraffin hydrocarbon distribution pattern and ratios, as well as the cluster analysis on the normal paraffin hydrocarbon concentration can have a better differentiation result for the crude oils with small difference than the original gas chromatogram.

  18. Evaluation of soil gas sampling and analysis techniques at a former petrochemical plant site. (United States)

    Hers, I; Li, L; Hannam, S


    Methods for soil gas sampling and analysis are evaluated as part of a research study on soil vapour intrusion into buildings, conducted at a former petro-chemical plant site ("Chatterton site"). The evaluation process was designed to provide information on reliability and selection of appropriate methods for soil gas sampling and analysis, and was based on a literature review of data and methods, and experiments completed as part of the research study. The broader context of this work is that soil gas characterization is increasingly being used for input into risk assessment of contaminated sites, particularly when evaluating the potential intrusion of soil vapour into buildings. There are only a limited number of research studies and protocols addressing soil gas sampling and analysis. There is significant variability in soil gas probe design and sample collection and analysis methods used by practitioners. The experimental studies conducted to evaluate soil gas methods address the permeation or leakage of gases from Tedlar bags, time-dependent sorption of volatile organic compound (VOC)-vapours onto probe surfaces and sampling devices, and analytical and quality control issues for light gas and VOC analyses. Through this work, common techniques for soil gas collection and analysis are described together with implications for data quality arising from the different methods used. Some of the potential pitfalls that can affect soil gas testing are identified, and recommendations and guidance for improved protocols are provided.

  19. Characteristic Value Method of Well Test Analysis for Horizontal Gas Well

    Directory of Open Access Journals (Sweden)

    Xiao-Ping Li


    Full Text Available This paper presents a study of characteristic value method of well test analysis for horizontal gas well. Owing to the complicated seepage flow mechanism in horizontal gas well and the difficulty in the analysis of transient pressure test data, this paper establishes the mathematical models of well test analysis for horizontal gas well with different inner and outer boundary conditions. On the basis of obtaining the solutions of the mathematical models, several type curves are plotted with Stehfest inversion algorithm. For gas reservoir with closed outer boundary in vertical direction and infinite outer boundary in horizontal direction, while considering the effect of wellbore storage and skin effect, the pseudopressure behavior of the horizontal gas well can manifest four characteristic periods: pure wellbore storage period, early vertical radial flow period, early linear flow period, and late horizontal pseudoradial flow period. For gas reservoir with closed outer boundary both in vertical and horizontal directions, the pseudopressure behavior of the horizontal gas well adds the pseudosteady state flow period which appears after the boundary response. For gas reservoir with closed outer boundary in vertical direction and constant pressure outer boundary in horizontal direction, the pseudopressure behavior of the horizontal gas well adds the steady state flow period which appears after the boundary response. According to the characteristic lines which are manifested by pseudopressure derivative curve of each flow period, formulas are developed to obtain horizontal permeability, vertical permeability, skin factor, reservoir pressure, and pore volume of the gas reservoir, and thus the characteristic value method of well test analysis for horizontal gas well is established. Finally, the example study verifies that the new method is reliable. Characteristic value method of well test analysis for horizontal gas well makes the well test analysis

  20. Gas purge microsyringe extraction for quantitative direct gas chromatographic-mass spectrometric analysis of volatile and semivolatile chemicals. (United States)

    Yang, Cui; Piao, Xiangfan; Qiu, Jinxue; Wang, Xiaoping; Ren, Chunyan; Li, Donghao


    Sample pretreatment before chromatographic analysis is the most time consuming and error prone part of analytical procedures, yet it is a key factor in the final success of the analysis. A quantitative and fast liquid phase microextraction technique termed as gas purge microsyringe extraction (GP-MSE) has been developed for simultaneous direct gas chromatography-mass spectrometry (GC-MS) analysis of volatile and semivolatile chemicals without cleanup process. Use of a gas flowing system, temperature control and a conventional microsyringe greatly increased the surface area of the liquid phase micro solvent, and led to quantitative recoveries of both volatile and semivolatile chemicals within short extraction time of only 2 min. Recoveries of polycyclic aromatic hydrocarbons (PAHs), organochlorine pesticides (OCPs) and alkylphenols (APs) determined were 85-107%, and reproducibility was between 2.8% and 8.5%. In particular, the technique shows high sensitivity for semivolatile chemicals which is difficult to achieve in other sample pretreatment techniques such as headspace-liquid phase microextraction. The variables affecting extraction efficiency such as gas flow rate, extraction time, extracting solvent type, temperature of sample and extracting solvent were investigated. Finally, the technique was evaluated to determine PAHs, APs and OCPs from plant and soil samples. The experimental results demonstrated that the technique is economic, sensitive to both volatile and semivolatile chemicals, is fast, simple to operate, and allows quantitative extraction. On-site monitoring of volatile and semivolatile chemicals is now possible using this technique due to the simplification and speed of sample treatment.

  1. Thermal Analysis of the Divertor Primary Heat Transfer System Piping During the Gas Baking Process

    Energy Technology Data Exchange (ETDEWEB)

    Yoder Jr, Graydon L [ORNL; Harvey, Karen [ORNL; Ferrada, Juan J [ORNL


    A preliminary analysis has been performed examining the temperature distribution in the Divertor Primary Heat Transfer System (PHTS) piping and the divertor itself during the gas baking process. During gas baking, it is required that the divertor reach a temperature of 350 C. Thermal losses in the piping and from the divertor itself require that the gas supply temperature be maintained above that temperature in order to ensure that all of the divertor components reach the required temperature. The analysis described in this report was conducted in order to estimate the required supply temperature from the gas heater.

  2. Gas migration through cement slurries analysis: A comparative laboratory study

    Directory of Open Access Journals (Sweden)

    Arian Velayati


    Full Text Available Cementing is an essential part of every drilling operation. Protection of the wellbore from formation fluid invasion is one of the primary tasks of a cement job. Failure in this task results in catastrophic events, such as blow outs. Hence, in order to save the well and avoid risky and operationally difficult remedial cementing, slurry must be optimized to be resistant against gas migration phenomenon. In this paper, performances of the conventional slurries facing gas invasion were reviewed and compared with modified slurry containing special gas migration additive by using fluid migration analyzer device. The results of this study reveal the importance of proper additive utilization in slurry formulations. The rate of gas flow through the slurry in neat cement is very high; by using different types of additives, we observe obvious changes in the performance of the cement system. The rate of gas flow in neat class H cement was reported as 36000 ml/hr while the optimized cement formulation with anti-gas migration and thixotropic agents showed a gas flow rate of 13.8 ml/hr.


    Energy Technology Data Exchange (ETDEWEB)

    Lee, S


    Computational fluid dynamics (CFD) methods have been used to estimate the flow patterns mainly driven by temperature gradients inside vapor space in a large-scaled Saltstone vault facility at Savannah River site (SRS). The purpose of this work is to examine the gas motions inside the vapor space under the current vault configurations by taking a three-dimensional transient momentum-energy coupled approach for the vapor space domain of the vault. The modeling calculations were based on prototypic vault geometry and expected normal operating conditions as defined by Waste Solidification Engineering. The modeling analysis was focused on the air flow patterns near the ventilated corner zones of the vapor space inside the Saltstone vault. The turbulence behavior and natural convection mechanism used in the present model were benchmarked against the literature information and theoretical results. The verified model was applied to the Saltstone vault geometry for the transient assessment of the air flow patterns inside the vapor space of the vault region using the potential operating conditions. The baseline model considered two cases for the estimations of the flow patterns within the vapor space. One is the reference nominal case. The other is for the negative temperature gradient between the roof inner and top grout surface temperatures intended for the potential bounding condition. The flow patterns of the vapor space calculated by the CFD model demonstrate that the ambient air comes into the vapor space of the vault through the lower-end ventilation hole, and it gets heated up by the Benard-cell type circulation before leaving the vault via the higher-end ventilation hole. The calculated results are consistent with the literature information. Detailed results and the cases considered in the calculations will be discussed here.

  4. Flame Stretch Analysis in Diffusion Flames with Inert Gas

    Institute of Scientific and Technical Information of China (English)

    Ay Su; Ying-Chieh Liu


    Experimental investigations of impinging flame with fuel mixed with non-reaction gas were conducted.According to the observations of combustion test and temperature measurement, the non-reaction gas might dilute the local concentration of fuel in the diffusion process. The shape of the flame was symmetrical due to the flame stretch force. Results show that the conical flame might be de-structured by the addition of inert gas in pure methane fuel. The impinging flame became shorter and bluer as nitrogen was added to the fuel. The conditions of N2/CH4 equal to 1/2 and 1/1 show a wider plane in the YZ plane. The effect of inert gas overcomes the flame stretch and destroys the symmetrical column flame as well as the cold flow. Nitrogen addition also enhances the diffusion rate and combustion efficiency.


    Institute of Scientific and Technical Information of China (English)

    Liu Zhihong


    @@ Introduction of GTL technology Processes to convert natural gas to synthetic liquid petroleum products have been under development for more than 70 years, but only in recent years are they being seen as commercially viable.

  6. On-line non-contact gas analysis

    DEFF Research Database (Denmark)

    Fateev, Alexander; Clausen, Sønnik

    Non-intrusive and fast measurements of the gas temperature, NO and other gas concentrations at elevated temperatures in boilers, engines and flames are of the great interest. The optical properties of the gases must be known in a spectral range and temperature level of interest. High-resolution I...... composition in the near-burner field with co-firing of biomass and coal, and NO measurements in a large diesel engine....

  7. Offsite Radiological Consequence Analysis for the Bounding Flammable Gas Accident

    CERN Document Server

    Carro, C A


    This document quantifies the offsite radiological consequences of the bounding flammable gas accident for comparison with the 25 rem Evaluation Guideline established in DOE-STD-3009, Appendix A. The bounding flammable gas accident is a detonation in a single-shell tank The calculation applies reasonably conservation input parameters in accordance with DOE-STD-3009, Appendix A, guidance. Revision 1 incorporates comments received from Office of River Protection.

  8. New Jersey's natural gas shortage: a policy analysis

    Energy Technology Data Exchange (ETDEWEB)

    Cecil, J.L.; Morell, D.


    The public policy problems associated with New Jersey's natural gas shortage are extremely complex and rather difficult to examine. They involve a blend of technology, politics and economics; of regulatory mandates and profit-motivated initiatives; of Federal and state interaction and conflict. To understand the state's gas shortage and to lay the basis for recommending measures to deal with it, information about the basic technology, the organization of the gas industry, the national regulatory posture, and the possible causes of the gas shortage encompasses Part I of the overall study. In Part II, the analysis turns from the national level to a direct examination of New Jersey's gas situation. In Part III, Chapter VIII, the following are considered: the state's supply of natural gas, distribution of these supply volumes within New Jersey by the four major gas utilities, and gas consumption patterns within the state as a whole and then for each major consuming sector (electric utility, industrial, commercial, and residential). This chapter concludes with an analysis of the impacts of the gas shortage to date in New Jersey, and of its probable effects in the near-term. In the final chapter, some tentative conclusions and broad suggestions are advanced for public policies to mitigate the gravity of the state's position with respect to natural gas. Analysis proceeds, in turn, through consideration of possible state actions in several areas: increasing total interstate gas supplies; increasing New Jersey's share of whatever national total exists; making greater (or more effective) use of alternate fuels; and moderating demand for gas through aggressive conservation policies. Some short-term measures to cope better with whatever level of gas shortage exists in the state at any particular time are suggested. 151 references. (MCW)

  9. Analysis of operation of the gas turbine in a poligeneration combined cycle (United States)

    Bartela, Łukasz; Kotowicz, Janusz


    In the paper the results of analysis of an integrated gasification combined cycle IGCC polygeneration system, of which the task is to produce both electricity and synthesis gas, are shown. Assuming the structure of the system and the power rating of a combined cycle, the consumption of the synthesis gas for chemical production makes it necessary to supplement the lack of synthesis gas used for electricity production with the natural gas. As a result a change of the composition of the fuel gas supplied to the gas turbine occurs. In the paper the influence of the change of gas composition on the gas turbine characteristics is shown. In the calculations of the gas turbine the own computational algorithm was used. During the study the influence of the change of composition of gaseous fuel on the characteristic quantities was examined. The calculations were realized for different cases of cooling of the gas turbine expander's blades (constant cooling air mass flow, constant cooling air index, constant temperature of blade material). Subsequently, the influence of the degree of integration of the gas turbine with the air separation unit on the main characteristics was analyzed.

  10. Differential Scanning Calorimetry and Evolved Gas Analysis at Mars Ambient Conditions Using the Thermal Evolved Gas Analyzer (TEGA) (United States)

    Musselwhite, D. S.; Boynton, W. V.; Ming, Douglas W.; Quadlander, G.; Kerry, K. E.; Bode, R. C.; Bailey, S. H.; Ward, M. G.; Pathare, A. V.; Lorenz, R. D.


    Differential Scanning Calorimetry (DSC) combined with evolved gas analysis (EGA) is a well developed technique for the analysis of a wide variety of sample types with broad application in material and soil sciences. However, the use of the technique for samples under conditions of pressure and temperature as found on other planets is one of current C development and cutting edge research. The Thermal Evolved Gas Analyzer (MGA), which was designed, built and tested at the University of Arizona's Lunar and Planetary Lab (LPL), utilizes DSC/EGA. TEGA, which was sent to Mars on the ill-fated Mars Polar Lander, was to be the first application of DSC/EGA on the surface of Mars as well as the first direct measurement of the volatile-bearing mineralogy in martian soil.

  11. Differential Scanning Calorimetry and Evolved Gas Analysis at Mars Ambient Conditions Using the Thermal Evolved Gas Analyser (TEGA) (United States)

    Musselwhite, D. S.; Boynton, W. V.; Ming, D. W.; Quadlander, G.; Kerry, K. E.; Bode, R. C.; Bailey, S. H.; Ward, M. G.; Pathare, A. V.; Lorenz, R. D.


    Differential Scanning Calorimetry (DSC) combined with evolved gas analysis (EGA) is a well developed technique for the analysis of a wide variety of sample types with broad application in material and soil sciences. However, the use of the technique for samples under conditions of pressure and temperature as found on other planets is one of current development and cutting edge research. The Thermal Evolved Gas Analyzer (TEGA), which was designed, built and tested at the University of Arizona's Lunar and Planetary Lab (LPL), utilizes DSC/EGA. TEGA, which was sent to Mars on the ill-fated Mars Polar Lander, was to be the first application of DSC/EGA on the surface of Mars as well as the first direct measurement of the volatile-bearing mineralogy in martian soil. Additional information is available in the original extended abstract.

  12. Natural gas; Gas Natural

    Energy Technology Data Exchange (ETDEWEB)

    Lopes, Carlos A.; Moraes, Claudia C.D. [Eletricidade de Sao Paulo S.A. (ELETROPAULO), Sao Paulo, SP (Brazil); Fonseca, Carlos H.F. [Centrais Eletricas de Santa Catarina S.A., Florianopolis, SC (Brazil); Silva, Clecio Fabricio da; Alves, Ricardo P. [Companhia Paranaense de Energia (COPEL), Curitiba, PR (Brazil); Sposito, Edivaldo Soares; Hulle, Lutero [Espirito Santo Centrais Eletricas S.A. (ESCELSA), Vitoria, ES (Brazil); S. Martins, Icaro da [Centrais Eletricas do Norte do Brasil S.A. (ELETRONORTE), Belem, PA (Brazil); Vilhena, Joao Luiz S. de [Companhia Energetica de Minas Gerais (CEMIG), Belo Horizonte, MG (Brazil); Fagundes, Zaluar Aquino [Companhia Estadual de Energia Eletrica do Estado do Rio Grande do Sul, Porto Alegre, RS (Brazil)


    An increase in the consumption of natural gas in Brazil is an expected fact in what concerns energetic planning. This work presents the existing situation in what concerns natural gas utilization in the main world economies, as well as an analysis of the participation of this fuel among the energy final consumption per sources. The Brazilian consumption of natural gas is also analysed as well as the international agreement between Brazil and Bolivia for natural gas commercialization. Some legal, institutional and political aspects related to natural gas commercialization are also discussed. Finally, several benefits to be brought by the utilization of natural gas are presented 10 refs., 3 tabs.

  13. Analysis of Turkish High School Chemistry Textbooks and Teacher-Generated Questions about Gas Laws (United States)

    Nakiboglu, Canan; Yildirir, H.


    This study presents the results of an analysis of high school chemistry textbooks and teacher-generated questions about gas laws. The materials that were analyzed consisted of 456 questions about gas laws found in seven grade 10 chemistry textbooks and 264 teacher-generated examination questions prepared by seven chemistry teachers from three…

  14. Gas chromatographic-mass spectrometric analysis of tar compounds formed during pyrolysis of rice husks

    NARCIS (Netherlands)

    Haanappel, V.A.C.; Stevens, T.W.; Hovestad, A.; Skolnik, V.; Visser, R.


    Pyrolysis of agricultural waste to produce fuel gas involves formation of tars as noxious by-products. In this paper the qualitative analysis of tars formed during pyrolysis of rice husks is presented, based on identification by gas chromatography—mass spectrometry and interpolation of retention tim

  15. Natural gas engineering and safety challenges downstream process, analysis, utilization and safety

    CERN Document Server

    Nasr, GG


    Provides a critical and extensive compilation of the downstream processes of natural gas that involve the principle of gas processing , transmission and distribution, gas flow and network analysis, instrumentation and measurement systems and its utilisation Enriches understanding of the business and management aspects of natural gas as well as highlighting some of the recent research and innovations in the field Covers the needs of practising engineers from different disciplines, who may include project managers, planning and design engineers - the book is also suitable for the demands of u

  16. Analysis of phenolic type antioxidants; Capillary gas chromatography

    Energy Technology Data Exchange (ETDEWEB)

    Chopra, S.K. (Indian Inst. of Petroleum, Dehradun (India)); Kapoor, V.B. (Indian Inst. of Petroleum, Dehradun (India)); Vishnoi, S.C. (Indian Inst. of Petroleum, Dehradun (India)); Bhagat, S.D. (Indian Inst. of Petroleum, Dehradun (India))


    A simple gas chromatographic (GC) procedure has been developed to estimate the individual alkylated phenols used as antioxidants to improve the shelf life of fuels and lubricants. Preparative gas chromatography was applied for separation and collection in sufficient quantity of the isomers of tertiary butyl, octyl and dodecyl phenols prepared by catalytic alkylation of phenol with isobutylene or its oligomers. The separated fractions were characterised by Infra-red spectrometry (IR) and paper chromatography. Out of several GC columns studies, a high resolution capillary column of 100% Methyl, Silicone gum (SE-30) as stationary phase gave best results. Data generated on various packed and capillary columns are in good agreement. (orig.)

  17. An Analysis of Policy Issues in Natural Gas Industry Restructuring

    Energy Technology Data Exchange (ETDEWEB)

    Seo, J.K. [Korea Energy Economics Institute, Euiwang (Korea)


    This report explores controversial issues and problems that could emerge in the process of implementing the government's restructuring plan for natural gas industry and aims to suggest policy directions regarding the restructuring. To begin with, it examines current conditions surrounding natural gas industry including domestic demand and supply conditions, world LNG market trend, structural changes of the industry in OECD countries, possibilities of introducing effective competition and assignment of existing import contracts. In doing so, we probe whether the direction of the natural gas industry restructuring is proper and suggest that the results be reflected when a more detailed restructuring implementation plan is formulated. Also, this report suggests possible schemes related to major institutional changes expected by the basic restructuring plan and the detailed restructuring implementation plan announced by the government. First, it presents several alternative ways to properly divide up the import/wholesales section of Korea Gas Corporation. Second, it examines critical issues such as the method of using gas supply facilities and gas balancing mechanism, and presents adoptable alternatives for each issue. These issues constitute the core of network and market operation rules which need to be in place when adopting an open access system, which in turn is a prerequisite for sales competition. Third, the report examines price systems, including gas commodity pricing and rate-making design for transportation service, by first anticipating the direction of changes in gas rate regulation. Specifically, it presents possible ways to design the service rate for each function of pipeline network and import terminals, and discusses controversial issues in determining total cost-of-service and allocating the cost-of-service to each functional service offered such as distance-related rates, interruptible service rate. Lastly, in relation to the opening of retail

  18. Optimal Control of Gas Pipelines via Infinite-Dimensional Analysis (United States)

    Durgut, Ismail; Leblebiciolu, Kemal


    A general optimal control approach employing the principles of calculus of variations has been developed to determine the best operating strategies for keeping the outlet pressure of gas transmission pipelines around a predetermined value while achieving reasonable energy consumption. The method exploits analytical tools of optimal control theory. A set of partial differential equations characterizing the dynamics of gas flow through a pipeline is directly used. The necessary conditions to minimize the specific performance index come from the infinite-dimensional model. The optimization scheme has been tested on a pipeline subject to stepwise change in demand.

  19. Analysis of engineering cycles power, refrigerating and gas liquefaction plant

    CERN Document Server

    Haywood, R W


    Extensively revised, updated and expanded, the fourth edition of this popular text provides a rigorous analytical treatment of modern energy conversion plant. Notable for both its theoretical and practical treatment of conventional and nuclear power plant, and its studies of refrigerating and gas-liquefaction plant. This fourth edition now includes material on topics of increasing concern in the fields of energy 'saving' and reduction of environmental pollution. This increased coverage deals specifically with the following areas: CHP (cogeneration) plant, studies of both gas and coal burning p

  20. Strategic analysis on establishing a natural gas trading hub in China

    Directory of Open Access Journals (Sweden)

    Xiaoguang Tong


    Full Text Available Since 2010, the LNG importing price premium in the Asia–Pacific markets has become increasingly high, generating great effects on the economic development in China. In addition, the natural gas dependence degree is expanding continuously, making it extremely urgent to establish a natural gas trading hub in China, with the aim to ensure national energy security, to gain the pricing power, and to build the regional benchmark prices. Through a comparative analysis of internal strength/weakness and external competitiveness, we concluded that with intensively-issued supporting policies on the natural gas sector, the initiation of spot and futures markets, the rapid growth of gas production and highly-improved infrastructures, as well as Shanghai's advantageous location, China has more advantages in establishing an Asian Natural Gas Trading Hub than other counties like Singapore, Japan and Malaysia. Moreover, based on the SWOT (strength, weakness, opportunity and threat and the marketization process analysis, the following strategies were presented: to impel the establishment of a natural gas trading hub depending on the gas supply condition, to follow the policies to complete the gas storage system, to form regional communities by taking comparative advantages, and to reinforce the marketization reform and regulation system establishment with foreign experiences for reference. This study rationalized the necessity and practicality of establishing a natural gas trading hub in China and will help China make a proper decision and find a periodical strategic path in this sector.

  1. Relating landfill gas emissions to atmospheric pressure using numerical modeling and state-space analysis

    DEFF Research Database (Denmark)

    Poulsen, T.G.; Christophersen, Mette; Moldrup, P.


    were applied: (I) State-space analysis was used to identify relations between gas flux and short-term (hourly) variations in atmospheric pressure. (II) A numerical gas transport model was fitted to the data and used to quantify short-term impacts of variations in atmospheric pressure, volumetric soil......-water content, soil gas permeability, soil gas diffusion coefficients, and biological CH4 degradation rate upon landfill gas concentration and fluxes in the soil. Fluxes and concentrations were found to be most sensitive to variations in volumetric soil water content, atmospheric pressure variations and gas...... permeability whereas variations in CH4 oxidation rate and molecular coefficients had less influence. Fluxes appeared to be most sensitive to atmospheric pressure at intermediate distances from the landfill edge. Also overall CH4 fluxes out of the soil over longer periods (years) were largest during periods...

  2. Economic Analysis of using Above Ground Gas Storage Devices for Compressed Air Energy Storage System

    Institute of Scientific and Technical Information of China (English)

    LIU Jinchao; ZHANG Xinjing; XU Yujie; CHEN Zongyan; CHEN Haisheng; TAN Chunqing


    Above ground gas storage devices for compressed air energy storage (CAES) have three types:air storage tanks,gas cylinders,and gas storage pipelines.A cost model of these gas storage devices is established on the basis of whole life cycle cost (LCC) analysis.The optimum parameters of the three types are determined by calculating the theoretical metallic raw material consumption of these three devices and considering the difficulties in manufacture and the influence of gas storage device number.The LCCs of the three types are comprehensively analyzed and compared.The result reveal that the cost of the gas storage pipeline type is lower than that of the other two types.This study may serve as a reference for designing large-scale CAES systems.

  3. Methods to optimize myxobacterial fermentations using off-gas analysis

    Directory of Open Access Journals (Sweden)

    Hüttel Stephan


    Full Text Available Abstract Background The influence of carbon dioxide and oxygen on microbial secondary metabolite producers and the maintenance of these two parameters at optimal levels have been studied extensively. Nevertheless, most studies have focussed on their influence on specific product formation and condition optimization of established processes. Considerably less attention has been paid to the influence of reduced or elevated carbon dioxide and oxygen levels on the overall metabolite profiles of the investigated organisms. The synergistic action of both gases has garnered even less attention. Results We show that the composition of the gas phase is highly important for the production of different metabolites and present a simple approach that enables the maintenance of defined concentrations of both O2 and CO2 during bioprocesses over broad concentration ranges with a minimal instrumental setup by using endogenously produced CO2. The metabolite profiles of a myxobacterium belonging to the genus Chondromyces grown under various concentrations of CO2 and O2 showed considerable differences. Production of two unknown, highly cytotoxic compounds and one antimicrobial substance was found to increase depending on the gas composition. In addition, the observation of CO2 and O2 in the exhaust gas allowed optimization and control of production processes. Conclusions Myxobacteria are becoming increasingly important due to their potential for bioactive secondary metabolite production. Our studies show that the influence of different gas partial pressures should not be underestimated during screening processes for novel compounds and that our described method provides a simple tool to investigate this question.

  4. Undisplayed Bicarbonate ion Concentration in Arterial Blood Gas Analysis



    Blood bicarbonate ion concentration (BcHCO3-) is a vital parameter in the management of acid base disorders. In an arterial blood gas (ABG) analyzer, the BcHCO3- is calculated from the values of pH and pCO2.

  5. Analysis of essential oils by gas chromatography and mass spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Masada, Y.


    The book is in two parts: first part Essential Oil includes compositae; labiatae; verbenaceae; oleaceae; umbelliferae; myrtaceae; euphorbiaceae; rutaceae; geraniaceae; rosaceae; lauraceae; myristicaceae; anonaceae; santalaceae; moraceae; piperaceae; zingiberaceae; araceae; gramineae; and cupressaceae written in English and Japanese. Part two includes essential oil; gas chromatography, and mass spectrometry written in Japanese. (DP)


    A procedure is presented that uses a vacuum distillation/gas chromatography/mass spectrometry system for analysis of problematic matrices of volatile organic compounds. The procedure compensates for matrix effects and provides both analytical results and confidence intervals from...

  7. Analysis of chemical signals in red fire ants by gas chromatography and pattern recognition techniques (United States)

    The combination of gas chromatography and pattern recognition (GC/PR) analysis is a powerful tool for investigating complicated biological problems. Clustering, mapping, discriminant development, etc. are necessary to analyze realistically large chromatographic data sets and to seek meaningful relat...

  8. Gas monitoring data anomaly identification based on spatio-temporal correlativity analysis

    Institute of Scientific and Technical Information of China (English)

    Shi-song ZHU; Yun-jia WANG; Lian-jiang WEI


    Based on spatio-temporal correlativity analysis method,the automatic identification techniques for data anomaly monitoring of coal mining working face gas are presented.The asynchronous correlative characteristics of gas migration in working face airflow direction are qualitatively analyzed.The calculation method of asynchronous correlation delay step and the prediction and inversion formulas of gas concentration changing with time and space after gas emission in the air return roadway are provided.By calculating one hundred and fifty groups of gas sensors data series from a coal mine which have the theoretical correlativity,the correlative coefficient values range of eight kinds of data anomaly is obtained.Then the gas monitoring data anomaly identification algorithm based on spatio-temporal correlativity analysis is accordingly presented.In order to improve the efficiency of analysis,the gas sensors code rules which can express the spatial topological relations are suggested.The experiments indicate that methods presented in this article can effectively compensate the defects of methods based on a single gas sensor monitoring data.

  9. Cost analysis of NOx control alternatives for stationary gas turbines

    Energy Technology Data Exchange (ETDEWEB)

    Bill Major


    The use of stationary gas turbines for power generation has been growing rapidly with continuing trends predicted well into the future. Factors that are contributing to this growth include advances in turbine technology, operating and siting flexibility and low capital cost. Restructuring of the electric utility industry will provide new opportunities for on-site generation. In a competitive market, it maybe more cost effective to install small distributed generation units (like gas turbines) within the grid rather than constructing large power plants in remote locations with extensive transmission and distribution systems. For the customer, on-site generation will provide added reliability and leverage over the cost of purchased power One of the key issues that is addressed in virtually every gas turbine application is emissions, particularly NO{sub x} emissions. Decades of research and development have significantly reduced the NO{sub x} levels emitted from gas turbines from uncontrolled levels. Emission control technologies are continuing to evolve with older technologies being gradually phased-out while new technologies are being developed and commercialized. The objective of this study is to determine and compare the cost of NO{sub x} control technologies for three size ranges of stationary gas turbines: 5 MW, 25 MW and 150 MW. The purpose of the comparison is to evaluate the cost effectiveness and impact of each control technology as a function of turbine size. The NO{sub x} control technologies evaluated in this study include: Lean premix combustion, also known as dry low NO{sub x} (DLN) combustion; Catalytic combustion; Water/steam injection; Selective catalytic reduction (SCR)--low temperature, conventional, high temperature; and SCONO{sub x}{trademark}.

  10. Analysis on Service Life of Hot-end Components of Gas Turbine Using Equivalent Operation

    Directory of Open Access Journals (Sweden)

    Taixing Wang


    Full Text Available The reliability of the gas turbine depends on the technical status and the maintenance level of the hot-end components in a large part.The three main factors influencing on the service life of the hot-end components of the gas turbine were analyzed first.On this basis,various common service life assessment methods for gas turbine were discussed in detail.Aiming at the features of the M701F gas-steam combined cycle unit in Huizhou LNG power plant,a gas turbine life assessment method based on equivalent operation time analysis was put forward.The calculation result of an example shows that the equivalent operation time analysis method is a simple and practical assessment method.

  11. Multi-fingerprint detection and attribution analysis of greenhouse gas, greenhouse gas-plus-aerosol and solar forced climate change

    Energy Technology Data Exchange (ETDEWEB)

    Hegerl, G.C.; Hasselmann, K.; Cubasch, U.; Roeckner, E.; Voss, R. [Max-Planck-Institut fuer Meteorologie, Hamburg (Germany); Mitchell, J.F.B. [Hadley Centre for Climate Prediction and Research, Bracknell (United Kingdom). Meteorological Office; Waszkewitz, J. [Deutsches Klimarechenzentrum (DKRZ), Hamburg (Germany)


    A multifingerprint analysis is applied to the detection and attribution of anthropogenic climate change. While a single fingerprint is optimal for the detection of climate change, further tests of the statistical consistency of the detected climate change signal with model predictions for different candidate forcing mechanisms require the simultaneous application of several fingerprints. Model-predicted climate change signals are derived from three anthropogenic global warming simulations for the period 1880 to 2049and two simulations forced by estimated changes in solar radiation from 1700 to 1992. In the first global warming simulation, the forcing is by greenhouse gas only, while in the remaining two simulations the direct influence of sulfate aerosols is also included. From the climate change signals of the greenhouse gas only and the average of the two greenhouse gas-plus-aerosol simulations, two optimized fingerprint patterns are derived by weighting the model-predicted climate change patterns towards low-noise directions. The optimized fingerprint patterns are then applied as a filter to the observed near-surface temperature trend patterns, yielding several detection variables. The space-time structure of natural climate variability needed to determine the optimal fingerprint pattern and the resultant signal-to-noise ratio of the detection variable is estimated from several multicentury control simulations with different CGCMs and from instrumental data over the last 136 y. Applying the combined greenhouse gas-plus-aerosol fingerprint in the same way as the greenhouse gas only fingerprint in a previous work, the recent 30-y trends (1966-1995) of annual mean near surface temperature are again found to represent a significant climate change at the 97.5% confidence level. (orig.) With 13 figs., 3 tabs., 63 refs.

  12. Development of gas chromatography analysis of fatty acids in marine organisms. (United States)

    Tang, Baokun; Row, Kyung Ho


    The gas chromatographic analysis of fatty acids has attracted considerable interest. In this analysis, the common derivatives of fatty acids, such as fatty acid methyl esters, can be detected using a flame ionization detector and the mass spectra can indicate the true structure of fatty acids. This paper reviews gas chromatographic methods for obtaining fatty acids from marine organisms. The stationary phase and detector for applications in gas chromatography are discussed. This article also reviews the components of fatty acids in marine animals, marine plants and marine microorganisms.

  13. Comparison of magnetic resonance imaging of inhaled SF6 with respiratory gas analysis. (United States)

    Scholz, Alexander-Wigbert; Wolf, Ursula; Fabel, Michael; Weiler, Norbert; Heussel, Claus P; Eberle, Balthasar; David, Matthias; Schreiber, Wolfgang G


    Magnetic resonance imaging of inhaled fluorinated inert gases ((19)F-MRI) such as sulfur hexafluoride (SF(6)) allows for analysis of ventilated air spaces. In this study, the possibility of using this technique to image lung function was assessed. For this, (19)F-MRI of inhaled SF(6) was compared with respiratory gas analysis, which is a global but reliable measure of alveolar gas fraction. Five anesthetized pigs underwent multiple-breath wash-in procedures with a gas mixture of 70% SF(6) and 30% oxygen. Two-dimensional (19)F-MRI and end-expiratory gas fraction analysis were performed after 4 to 24 inhaled breaths. Signal intensity of (19)F-MRI and end-expiratory SF(6) fraction were evaluated with respect to linear correlation and reproducibility. Time constants were estimated by both MRI and respiratory gas analysis data and compared for agreement. A good linear correlation between signal intensity and end-expiratory gas fraction was found (correlation coefficient 0.99+/-0.01). The data were reproducible (standard error of signal intensity 8% vs. that of gas fraction 5%) and the comparison of time constants yielded a sufficient agreement. According to the good linear correlation and the acceptable reproducibility, we suggest the (19)F-MRI to be a valuable tool for quantification of intrapulmonary SF(6) and hence lung function.

  14. Programmed automation of modulator cold jet flow for comprehensive two-dimensional gas chromatographic analysis of vacuum gas oils. (United States)

    Rathbun, Wayne


    A method is described for automating the regulation of cold jet flow of a comprehensive two-dimensional gas chromatograph (GCxGC) configured with flame ionization detection. This new capability enables the routine automated separation, identification, and quantitation of hydrocarbon types in petroleum fractions extending into the vacuum gas oil (VGO) range (IBP-540 degrees C). Chromatographic data acquisition software is programmed to precisely change the rate of flow from the cold jet of a nitrogen cooled loop modulator of a GCxGC instrument during sample analysis. This provides for the proper modulation of sample compounds across a wider boiling range. The boiling point distribution of the GCxGC separation is shown to be consistent with high temperature simulated distillation results indicating recovery of higher boiling semi-volatile VGO sample components. GCxGC configured with time-of-flight mass spectrometry is used to determine the molecular identity of individual sample components and boundaries of different molecular types.

  15. [Study of infrared spectroscopy quantitative analysis method for methane gas based on data mining]. (United States)

    Zhang, Ai-Ju


    Monitoring of methane gas is one of the important factors affecting the coal mine safety. The online real-time monitoring of the methane gas is used for the mine safety protection. To improve the accuracy of model analysis, in the present paper, the author uses the technology of infrared spectroscopy to study the gas infrared quantitative analysis algorithm. By data mining technology application in multi-component infrared spectroscopy quantitative analysis algorithm, it was found that cluster analysis partial least squares algorithm is obviously superior to simply using partial least squares algorithm in terms of accuracy. In addition, to reduce the influence of the error on the accuracy of model individual calibration samples, the clustering analysis was used for the data preprocessing, and such denoising method was found to improve the analysis accuracy.

  16. Just fracking: a distributive environmental justice analysis of unconventional gas development in Pennsylvania, USA (United States)

    Clough, Emily; Bell, Derek


    This letter presents a distributive environmental justice analysis of unconventional gas development in the area of Pennsylvania lying over the Marcellus Shale, the largest shale gas formation in play in the United States. The extraction of shale gas using unconventional wells, which are hydraulically fractured (fracking), has increased dramatically since 2005. As the number of wells has grown, so have concerns about the potential public health effects on nearby communities. These concerns make shale gas development an environmental justice issue. This letter examines whether the hazards associated with proximity to wells and the economic benefits of shale gas production are fairly distributed. We distinguish two types of distributive environmental justice: traditional and benefit sharing. We ask the traditional question: are there a disproportionate number of minority or low-income residents in areas near to unconventional wells in Pennsylvania? However, we extend this analysis in two ways: we examine income distribution and level of education; and we compare before and after shale gas development. This contributes to discussions of benefit sharing by showing how the income distribution of the population has changed. We use a binary dasymetric technique to remap the data from the 2000 US Census and the 2009-2013 American Communities Survey and combine that data with a buffer containment analysis of unconventional wells to compare the characteristics of the population living nearer to unconventional wells with those further away before and after shale gas development. Our analysis indicates that there is no evidence of traditional distributive environmental injustice: there is not a disproportionate number of minority or low-income residents in areas near to unconventional wells. However, our analysis is consistent with the claim that there is benefit sharing distributive environmental injustice: the income distribution of the population nearer to shale gas wells

  17. Gas turbine cooling modeling - Thermodynamic analysis and cycle simulations

    Energy Technology Data Exchange (ETDEWEB)

    Jordal, Kristin


    Considering that blade and vane cooling are a vital point in the studies of modern gas turbines, there are many ways to include cooling in gas turbine models. Thermodynamic methods for doing this are reviewed in this report, and, based on some of these methods, a number of model requirements are set up and a Cooled Gas Turbine Model (CGTM) for design-point calculations of cooled gas turbines is established. Thereafter, it is shown that it is possible to simulate existing gas turbines with the CGTM. Knowledge of at least one temperature in the hot part of the turbine (TET, TRIT or possibly TIT) is found to be vital for a complete heat balance over the turbine. The losses, which are caused by the mixing of coolant and main flow, are in the CGTM considered through a polytropic efficiency reduction factor S. Through the study of S, it can be demonstrated that there is more to gain from coolant reduction in a small and/or old turbine with poor aerodynamics, than there is to gain in a large, modern turbine, where the losses due to interaction between coolant and main flow are, relatively speaking, small. It is demonstrated, at the design point (TET=1360 deg C, {pi}=20) for the simple-cycle gas turbine, that heat exchanging between coolant and fuel proves to have a large positive impact on cycle efficiency, with an increase of 0.9 percentage points if all of the coolant passes through the heat exchanger. The corresponding improvement for humidified coolant is 0.8 percentage points. A design-point study for the HAT cycle shows that if all of the coolant is extracted after the humidification tower, there is a decrease in coolant requirements of 7.16 percentage points, from 19.58% to 12.52% of the compressed air, and an increase in thermal efficiency of 0.46 percentage points, from 53.46% to 53.92%. Furthermore, it is demonstrated with a TET-parameter variation, that the cooling of a simple-cycle gas turbine with humid air can have a positive effect on thermal efficiency

  18. Oxygen rich gas generator design and performance analysis (United States)

    Gloyer, P. W.; Knuth, W. H.; Crawford, R. A.


    The present oxygen-rich combustion research investigates oxygen gas generator concepts. The theoretical and modeling aspects of a selected concept are presented, together with a refined concept resulting from the findings of the study. This investigation examined a counter-flow gas generator design for O2/H2 mass ratios of 100-200, featuring a near-stoichiometric combustion zone followed by downstream mixing. The critical technologies required to develop a performance model are analyzed and include the following: (1) oxygen flow boiling; (2) two-phase oxygen flow heat transfer; (3) film-cooling in the combustion zone; (4) oxygen-rich combustion with hydrogen; and (5) mixing and dilution.

  19. Survey and Analysis of Marine Gas Turbine Control After 1975 (United States)


    the existing experimental data. Beginning in the early seventies, the U.S. Navy initiated The Gas Turbine Ship Propulsion Control Systems Research and...destroyers. Figure 1 shows a block diagram of the ship propulsion control system used. Simulations performed during the program tended to give good...Postgraduate school applied state space techniques to a linearized model of an FFG-7 ship propulsion system (5). Dynamic propulsion system equations were

  20. Inert gas analysis of ventilation-perfusion matching during hemodialysis.



    The mechanism of hypoxemia during hemodialysis was investigated by the multiple inert gas elimination technique in anesthetized, paralyzed, mechanically ventilated dogs. Profound leukopenia occurred in the first hour of a 2-h hemodialysis with a cuprophan membrane and dialysate that contained acetate. Arterial partial pressure of O2 and CO2 and oxygen consumption remained unchanged during dialysis. Pulmonary carbon dioxide elimination and lung respiratory exchange ratio decreased with the ini...

  1. Optimal energy consumption analysis of natural gas pipeline. (United States)

    Liu, Enbin; Li, Changjun; Yang, Yi


    There are many compressor stations along long-distance natural gas pipelines. Natural gas can be transported using different boot programs and import pressures, combined with temperature control parameters. Moreover, different transport methods have correspondingly different energy consumptions. At present, the operating parameters of many pipelines are determined empirically by dispatchers, resulting in high energy consumption. This practice does not abide by energy reduction policies. Therefore, based on a full understanding of the actual needs of pipeline companies, we introduce production unit consumption indicators to establish an objective function for achieving the goal of lowering energy consumption. By using a dynamic programming method for solving the model and preparing calculation software, we can ensure that the solution process is quick and efficient. Using established optimization methods, we analyzed the energy savings for the XQ gas pipeline. By optimizing the boot program, the import station pressure, and the temperature parameters, we achieved the optimal energy consumption. By comparison with the measured energy consumption, the pipeline now has the potential to reduce energy consumption by 11 to 16 percent.

  2. Analysis of hollow fibre membrane systems for multicomponent gas separation

    KAUST Repository

    Khalilpour, Rajab


    This paper analysed the performance of a membrane system over key design/operation parameters. A computation methodology is developed to solve the model of hollow fibre membrane systems for multicomponent gas feeds. The model represented by a nonlinear differential algebraic equation system is solved via a combination of backward differentiation and Gauss-Seidel methods. Natural gas sweetening problem is investigated as a case study. Model parametric analyses of variables, namely feed gas quality, pressure, area, selectivity and permeance, resulted in better understanding of operating and design optima. Particularly, high selectivities and/or permeabilities are shown not to be necessary targets for optimal operation. Rather, a medium selectivity (<60 in the given example) combined with medium permeance (∼300-500×10-10mol/sm2Pa in the given case study) is more advantageous. This model-based membrane systems engineering approach is proposed for the synthesis of efficient and cost-effective multi-stage membrane networks. © 2012 The Institution of Chemical Engineers.

  3. Performance Analysis of Neuro Genetic Algorithm Applied on Detecting Proportion of Components in Manhole Gas Mixture

    Directory of Open Access Journals (Sweden)

    Varun Kumar Ojha


    Full Text Available The article presents performance analysis of a real valued neuro genetic algorithm applied for thedetection of proportion of the gases found in manhole gas mixture. The neural network (NN trained usinggenetic algorithm (GA leads to concept of neuro genetic algorithm, which is used for implementing anintelligent sensory system for the detection of component gases present in manhole gas mixture Usually amanhole gas mixture contains several toxic gases like Hydrogen Sulfide, Ammonia, Methane, CarbonDioxide, Nitrogen Oxide, and Carbon Monoxide. A semiconductor based gas sensor array used for sensingmanhole gas components is an integral part of the proposed intelligent system. It consists of many sensorelements, where each sensor element is responsible for sensing particular gas component. Multiple sensorsof different gases used for detecting gas mixture of multiple gases, results in cross-sensitivity. The crosssensitivity is a major issue and the problem is viewed as pattern recognition problem. The objective of thisarticle is to present performance analysis of the real valued neuro genetic algorithm which is applied formultiple gas detection.

  4. Performance Analysis of Neuro Genetic Algorithm Applied on Detecting Proportion of Components in Manhole Gas Mixture

    Directory of Open Access Journals (Sweden)

    Varun Kumar Ojha


    Full Text Available The article presents performance analysis of a real valued neuro genetic algorithm applied for the detection of proportion of the gases found in manhole gas mixture. The neural network (NN trained using genetic algorithm (GA leads to concept of neuro genetic algorithm, which is used for implementing an intelligent sensory system for the detection of component gases present in manhole gas mixture Usually a manhole gas mixture contains several toxic gases like Hydrogen Sulfide, Ammonia, Methane, Carbon Dioxide, Nitrogen Oxide, and Carbon Monoxide. A semiconductor based gas sensor array used for sensing manhole gas components is an integral part of the proposed intelligent system. It consists of many sensor elements, where each sensor element is responsible for sensing particular gas component. Multiple sensors of different gases used for detecting gas mixture of multiple gases, results in cross-sensitivity. The crosssensitivity is a major issue and the problem is viewed as pattern recognition problem. The objective of this article is to present performance analysis of the real valued neuro genetic algorithm which is applied for multiple gas detection.

  5. Technical and Feasibility Analysis of Gasoline and Natural Gas Fuelled Vehicles

    Directory of Open Access Journals (Sweden)

    Charalambos Chasos


    Full Text Available There is recent interest for the utilisation of natural gas for empowering the internal combustion engines (ICE of vehicles. The production of novel natural gas ICE for vehicles, as well as the conversion of existing gasoline fuelled ICE of vehicles to natural gas fuelled ICE are new technologies which require to be analysed and assessed. The objective of the present study is to examine the adaptation of natural gas as vehicle fuel and carry out a technical analysis and an economical feasibility analysis of the two types of ICE vehicles, namely gasoline and natural gas fuelled vehicles. The technical model uses the physical properties of the two fuels and the performance factors of internal combustion engines including brake thermal efficiency. The resulting exhaust gas emissions are also estimated by the technical model using combustion calculations which provide the expected levels of exhaust gas emissions. Based on the analysis with the technical model, comparisons of the two types of engines are performed. Furthermore, the estimated performance characteristics of the two types of engines, along with local statistical data on annual fuel imports and annual fuel consumption for transportation and data on the vehicles fleet for the case study of Cyprus are used as input in the economical model. For the base year 2013, data of natural gas price is also used in the economical model. The economical model estimates the capital cost, the carbon dioxide emissions avoidance of fines, the net present value and the internal rate of return of the investment of large scale adaptation of natural gas fuelled vehicles for the case study. From the results and comparisons, conclusions are drawn and recommendations are provided for the adaptation of natural gas vehicles which can provide improved performance with reduced pollutant emissions.

  6. Severe Accident Analysis for Combustible Gas Risk Evaluation inside CFVS

    Energy Technology Data Exchange (ETDEWEB)

    Lee, NaRae; Lee, JinYong; Bang, YoungSuk; Lee, DooYong [FNC Technology Co. Ltd., Yongin (Korea, Republic of); Kim, HyeongTaek [KHNP-Central Research Institute, Daejeon (Korea, Republic of)


    The purpose of this study is to identify the composition of gases discharged into the containment filtered venting system by analyzing severe accidents. The accident scenarios which could be significant with respect to containment pressurization and hydrogen generation are derived and composition of containment atmosphere and possible discharged gas mixtures are estimated. In order to ensure the safety of the public and environment, the ventilation system should be designed properly by considering discharged gas flow rate, aerosol loads, radiation level, etc. One of considerations to be resolved is the risk due to combustible gas, especially hydrogen. Hydrogen can be generated largely by oxidation of cladding and decomposition of concrete. If the hydrogen concentration is high enough and other conditions like oxygen and steam concentration is met, the hydrogen can burn, deflagrate or detonate, which result in the damage the structural components. In particularly, after Fukushima accident, the hydrogen risk has been emphasized as an important contributor threatening the integrity of nuclear power plant during the severe accident. These results will be used to analyze the risk of hydrogen combustion inside the CFVS as boundary conditions. Severe accident simulation results are presented and discussed qualitatively with respect to hydrogen combustion. The hydrogen combustion risk inside of the CFVS has been examined qualitatively by investigating the discharge flow characteristics. Because the composition of the discharge flow to CFVS would be determined by the containment atmosphere, the severe accident progression and containment atmosphere composition have been investigated. Due to PAR operation, the hydrogen concentration in the containment would be decreased until the oxygen is depleted. After the oxygen is depleted, the hydrogen concentration would be increased. As a result, depending on the vent initiation timing (i.e. vent initiation pressure), the important

  7. Chlorine Dioxide Gas Treatment of Cantaloupe and Residue Analysis


    Kaur, Simran


    Chlorine dioxide is a selective oxidant and powerful antimicrobial agent. Previous work has shown that treatment of cantaloupe with chlorine dioxide gas at 5 mg/L for 10 minutes results in a 4.6 and 4.3 log reduction of E. coli O157:H7 and L. monocytogenes respectively. A significant reduction (p Current analytical methods for chlorine dioxide and chloroxyanions are only applicable to aqueous samples. Some of these methods have been used to determine surface residues in treated products by...

  8. Trash to Gas (TtG) Simulant Analysis (United States)

    Miles, John D., II; Hintze, Paul E.


    Space exploration in outer earths orbit is a long-term commitment, where the reuse of discarded materials is a critical component for its success. The Logistics Reduction and Repurposing (LRR) project under the NASA Advanced Exploration System Program is a project focused on technologies that reduce the amount of consumables that are needed to be sent into space, repurpose items sent to space, or convert wastes to commodities. In particular, Trash to Gas (TtG), part of the LRR project, is a novel space technology capable of converting raw elements from combustible waste including food waste and packaging, paper, wipes and towels, nitrile gloves, fecal matter, urine brine, maximum absorbency garments, and other organic wastes from human space exploration into useful gases. Trash to gas will ultimately reduce mission cost by producing a portion of important consumables in situ. This paper will discuss results of waste processing by steam reforming. Steam reforming is a thermochemical process developed as part of TtG, where waste is heated in the presence of oxygen and steam to produce carbon dioxide, carbon monoxide, hydrogen, methane and water. The aim of this experiment is to investigate the processing of different waste simulants and their gaseous products. This will lay a foundation for understating and optimizing the production of useful gases for propulsion and recovery of water for life support.

  9. Dynamic Modeling and Analysis of an Industrial Gas Suspension Absorber for Flue Gas Desulfurization

    DEFF Research Database (Denmark)

    Cignitti, Stefano; Mansouri, Seyed Soheil; Sales-Cruz, Mauricio


    another plant data set. It was verified that in spite of the simplicity of the model, very good prediction of industrial behavior was obtained. Furthermore, the dynamic analysis of the system was performed by carrying out open-loop and closed-loop simulations to verify plant dynamics. Therefore, a simple...

  10. Cold gas in cluster cores: Global stability analysis and non-linear simulations of thermal instability

    CERN Document Server

    Choudhury, Prakriti Pal


    We perform global linear stability analysis and idealized numerical simulations in global thermal balance to understand the condensation of cold gas from hot/virial atmospheres (coronae), in particular the intracluster medium (ICM). We pay particular attention to geometry (e.g., spherical versus plane-parallel) and the nature of the gravitational potential. Global linear analysis gives a similar value for the fastest growing thermal instability modes in spherical and Cartesian geometries. Simulations and observations suggest that cooling in halos critically depends on the ratio of the cooling time to the free-fall time ($t_{cool}/t_{ff}$). Extended cold gas condenses out of the ICM only if this ratio is smaller than a threshold value close to 10. Previous works highlighted the difference between the nature of cold gas condensation in spherical and plane-parallel atmospheres; namely, cold gas condensation appeared easier in spherical atmospheres. This apparent difference due to geometry arises because the prev...

  11. Adapting Human Reliability Analysis from Nuclear Power to Oil and Gas Applications

    Energy Technology Data Exchange (ETDEWEB)

    Boring, Ronald Laurids [Idaho National Laboratory


    ABSTRACT: Human reliability analysis (HRA), as currently used in risk assessments, largely derives its methods and guidance from application in the nuclear energy domain. While there are many similarities be-tween nuclear energy and other safety critical domains such as oil and gas, there remain clear differences. This paper provides an overview of HRA state of the practice in nuclear energy and then describes areas where refinements to the methods may be necessary to capture the operational context of oil and gas. Many key distinctions important to nuclear energy HRA such as Level 1 vs. Level 2 analysis may prove insignifi-cant for oil and gas applications. On the other hand, existing HRA methods may not be sensitive enough to factors like the extensive use of digital controls in oil and gas. This paper provides an overview of these con-siderations to assist in the adaptation of existing nuclear-centered HRA methods to the petroleum sector.

  12. A Driving Force Analysis and Forecast for Gas Consumption Demand in China

    Directory of Open Access Journals (Sweden)

    Qing Zhu


    Full Text Available In recent years, gas has begun to be widely used in power generation as well as in manufacturing because of the environmental advantages, lower cost, and the relative safety and reliability. Accurate prediction of future gas consumption is of great importance for energy security. In this paper, we first use path analysis to select the core factors that impact gas consumption, then use the RBF-QRNN model and BVAR model separately to predict future gas consumption, and finally discuss and compare the results from the two models. The results show that if there is a positive growth in GDP, urbanization, and population, then gas consumption is expected to increase over a comparatively long time. In detail, gas consumption is expected to remain at about 25% of all energy consumption, GDP’s contribution to gas consumption is expected to be about 53%, and the urbanization rate contribution would be about 15%. Gas consumption in China is predicted to reach around 178649.23 million cubic meters by the end of 2015 and about 264698.86 million cubic meters by 2020.

  13. An analog integrated signal processing circuit for on-chip diffusion-based gas analysis (United States)

    Sadeghi, Hesam; Ghafarinia, Vahid


    In diffusion-based gas analysis, the transient of gas diffusion process is recorded by a generic gas sensor to serve as a fingerprint for qualitative and quantitative analysis of gaseous samples. Following the acquisition of these specific signals, any standalone gas analyzer requires a pattern recognition system for pattern classification. The classic digital pattern recognition methods require computing hardware of adequate computational throughput. In this paper, we have followed a straightforward mathematical procedure to relate the signals to their associated target gases. We have shown that the procedure can be implemented by a set of analog functions. Based on the results, we have designed an analog integrated circuit, in 0.18 µm standard CMOS process, for processing the diffusion-based transient signals. The main circuit components are a low-pass filter, the differentiator, the feature extractor and an artificial neural network. The output of the circuit is a 2-bit binary code that specifies the target gas. The circuit successfully classified four alcoholic vapors by processing the experimentally obtained response patterns. The proposed signal processing circuit, the semiconductor gas sensor and the diffusion channel can all be implemented on a single substrate to fabricate an integrated micro gas analyzer.

  14. Uncertainty and sensitivity analysis of fission gas behavior in engineering-scale fuel modeling

    Energy Technology Data Exchange (ETDEWEB)

    Pastore, Giovanni, E-mail: [Fuel Modeling and Simulation, Idaho National Laboratory, P.O. Box 1625, Idaho Falls, ID 83415-3840 (United States); Swiler, L.P., E-mail: [Optimization and Uncertainty Quantification, Sandia National Laboratories, P.O. Box 5800, Albuquerque, NM 87185-1318 (United States); Hales, J.D., E-mail: [Fuel Modeling and Simulation, Idaho National Laboratory, P.O. Box 1625, Idaho Falls, ID 83415-3840 (United States); Novascone, S.R., E-mail: [Fuel Modeling and Simulation, Idaho National Laboratory, P.O. Box 1625, Idaho Falls, ID 83415-3840 (United States); Perez, D.M., E-mail: [Fuel Modeling and Simulation, Idaho National Laboratory, P.O. Box 1625, Idaho Falls, ID 83415-3840 (United States); Spencer, B.W., E-mail: [Fuel Modeling and Simulation, Idaho National Laboratory, P.O. Box 1625, Idaho Falls, ID 83415-3840 (United States); Luzzi, L., E-mail: [Politecnico di Milano, Department of Energy, Nuclear Engineering Division, via La Masa 34, I-20156 Milano (Italy); Van Uffelen, P., E-mail: [European Commission, Joint Research Centre, Institute for Transuranium Elements, Hermann-von-Helmholtz-Platz 1, D-76344 Karlsruhe (Germany); Williamson, R.L., E-mail: [Fuel Modeling and Simulation, Idaho National Laboratory, P.O. Box 1625, Idaho Falls, ID 83415-3840 (United States)


    The role of uncertainties in fission gas behavior calculations as part of engineering-scale nuclear fuel modeling is investigated using the BISON fuel performance code with a recently implemented physics-based model for fission gas release and swelling. Through the integration of BISON with the DAKOTA software, a sensitivity analysis of the results to selected model parameters is carried out based on UO{sub 2} single-pellet simulations covering different power regimes. The parameters are varied within ranges representative of the relative uncertainties and consistent with the information in the open literature. The study leads to an initial quantitative assessment of the uncertainty in fission gas behavior predictions with the parameter characterization presently available. Also, the relative importance of the single parameters is evaluated. Moreover, a sensitivity analysis is carried out based on simulations of a fuel rod irradiation experiment, pointing out a significant impact of the considered uncertainties on the calculated fission gas release and cladding diametral strain. The results of the study indicate that the commonly accepted deviation between calculated and measured fission gas release by a factor of 2 approximately corresponds to the inherent modeling uncertainty at high fission gas release. Nevertheless, significantly higher deviations may be expected for values around 10% and lower. Implications are discussed in terms of directions of research for the improved modeling of fission gas behavior for engineering purposes.

  15. Gas Analysis of Geothermal Fluid Inclusions: A New Technology For Geothermal Exploration

    Energy Technology Data Exchange (ETDEWEB)

    David I. Norman; Joseph Moore


    To increase our knowledge of gaseous species in geothermal systems by fluid inclusion analysis in order to facilitate the use of gas analysis in geothermal exploration. The knowledge of gained by this program can be applied to geothermal exploration, which may expand geothermal production. Knowledge of the gas contents in reservoir fluids can be applied to fluid inclusion gas analysis of drill chip cuttings in a similar fashion as used in the petroleum industry. Thus the results of this project may lower exploration costs both in the initial phase and lower drill hole completion costs. Commercial costs for fluid inclusion analysis done on at 20 feet intervals on chip samples for 10,000 ft oil wells is about $6,000, and the turn around time is a few weeks.

  16. The encounter and analysis of naturally occurring radionuclides in gas and oil production and processing

    Energy Technology Data Exchange (ETDEWEB)

    Hartog, F.A.; Jonkers, G.; Knaepen, W.A.I. [Shell Research and Technology Centre, Amsterdam, (Netherlands)


    As a result of oil and gas production, radioactive daughter elements from the uranium and thorium decay series can be mobilized and transported away from the reservoir. Due to changes in flow regime, temperature, pressure or chemical environment NORs (Naturally Occurring Radionuclides) may build up in products, by-products or waste streams from gas and oil production and processing facilities. Products containing NORs are commonly denoted by the acronym NORM (Naturally Occurring Radioactive Materials). Main topics of this paper are: E and P (Exploration and Production) NORM characteristics; incentives for NORM analysis; NORM analysis; interlaboratory test programme; analysis techniques; results and conclusions of the test programme. 4 figs., 2 tabs.

  17. Modelling and analysis of offshore energy systems on North Sea oil and gas platforms

    DEFF Research Database (Denmark)

    Nguyen, Tuong-Van; Elmegaard, Brian; Pierobon, Leonardo


    export, and power generation. In this paper, a generic model of a North Sea oil and gas platform is described and the most thermodynamically inefficient processes are identified by performing an exergy analysis. Models and simulations are built and run with the tools Aspen Plus R, DNA and Aspen HYSYS R....... Results reveal that the total exergy destruction of the system is particularly sensitive to the gas-to-oil ratio and amounts to 55-65 MW, while the total exergy losses amount to 15-20 MW. The gas compression train and the production manifold module are the most exergy-destructive operations of the oil...

  18. Improved thermodynamic analysis of gas reactions for compound semiconductor growth by vapor-phase epitaxy (United States)

    Inatomi, Yuya; Kangawa, Yoshihiro; Kakimoto, Koichi; Koukitu, Akinori


    An improved thermodynamic analysis method for vapor-phase epitaxy is proposed. In the conventional method, the mass-balance constraint equations are expressed in terms of variations in partial pressure. Although the conventional method is appropriate for gas–solid reactions occurring near the growth surface, it is not suitable for gas reactions that involve changes in the number of gas molecules. We reconsider the constraint equations in order to predict the effect of gas reactions on semiconductor growth processes. To demonstrate the feasibility of the improved method, the growth process of group-III nitrides by metalorganic vapor-phase epitaxy has been investigated.

  19. Scaling analysis of gas-liquid two-phase flow pattern in microgravity (United States)

    Lee, Jinho


    A scaling analysis of gas-liquid two-phase flow pattern in microgravity, based on the dominant physical mechanism, was carried out with the goal of predicting the gas-liquid two-phase flow regime in a pipe under conditions of microgravity. The results demonstrated the effect of inlet geometry on the flow regime transition. A comparison of the predictions with existing experimental data showed good agreement.

  20. Risk assessment of Kermanshah gas storage tanks by energy trace and barrier analysis (2014)


    M. Ghanbari Kakavandi; F. Rajati; H. Ashtarian; SY. Hosseini


    Background: Despite the cost and millions loss of life due to industrial accidents, often are preventable through risk assessment methods and control measures. Objective: To assess the safety of gas storage tanks in Kermanshah oil refinery by Energy Trace and Barrier Analysis (ETBA). Methods: This case-descriptive study was conducted in gas storage tanks of Kermanshah oil refinery. Energy checklist was used for identification of energy types. Energy flows were tracked and then, manageme...

  1. Analysis of homogeneity of 2D electron gas at decreasing of electron density


    Sherstobitov, A. A.; Minkov, G. M.; Germanenko, A. V.; Rut, O. E.; Soldatov, I. V.; Zvonkov, B. N.


    We investigate the gate voltage dependence of capacitance of a system gate - 2D electron gas (C-Vg). The abrupt drop of capacitance at decreasing concentration was found. The possible reasons of this drop, namely inhomogeneity of electron density distribution and serial resistance of 2D electron gas are discussed. Simultaneous analysis of gate voltage dependences of capacitance and resistance has shown that in heavily doped 2D systems the main role in the drop of capacitance at decreasing con...

  2. Gas chromatographic analysis of synthetic glycidol esters, mono-, di- and triglycerides. (United States)

    Engbersen, J A; van Stijn, F


    The gas chromatographic analysis of glycidol esters and mono-, di-,and triglycerides of palmitic-, stearic-, and oleic acid mixtures is described. The composition of the products was determined by gas chromatography on OV-17 after trimethylsilylation. Base-line separations between 1- and 2-monoglycerides and between 1,2- and 1,3-diglycerides were obtained. Isomerisation of the trimethylsilyl ethers of monoglycerides was not observed, contrary to published work.

  3. Analysis of spherical thermo-acoustic radiation in gas

    Directory of Open Access Journals (Sweden)

    Hanping Hu


    Full Text Available A general solution of the spherical thermo-acoustic (TA radiation from any solid in gas is derived by using a fully thermally-mechanically coupled TA model. Therefore, the characteristics and regularities of spherical TA emission can be studied more completely. It is shown that flat amplitude-frequency response, the most important feature for planar TA emission from technical standpoint, still exists for spherical TA emission, and changes with the radius of a sphere, thickness of TA sample, and the distance from surface. This expression agrees well with experimental and theoretical results of planer TA emission for much larger sphere and lays the foundation to calculate complex TA emission problems.

  4. Fibre-optic UV systems for gas and vapour analysis

    Energy Technology Data Exchange (ETDEWEB)

    Eckhardt, H S [University of Applied Sciences Giessen-Friedberg, Wilhelm-Leuschner-Str, 13, 61169 Friedberg (Germany); Klein, K-F [University of Applied Sciences Giessen-Friedberg, Wilhelm-Leuschner-Str, 13, 61169 Friedberg (Germany); Spangenberg, B [University of Applied Sciences Offenburg, Badstrasse 24, 77652 Offenburg (Germany); Sun, T [City University London, Northampton Square, London, EC1V 0HB (United Kingdom); Grattan, K T V [City University London, Northampton Square, London, EC1V 0HB (United Kingdom)


    The identification and quantification of compounds in the gas phase becomes of increasing interest in the context of environmental protection, as well as in the analytical field. In this respect, the high extinction coefficients of vapours and gases in the ultraviolet wavelength region allow a very sensitive measurement system. In addition, the increased performance of the components necessary for setting up a measurement system, such as fibres, light sources and detectors has been improved. In particular the light sources and detectors offer improved stability, and the deep UV performance and solarisation resistance of fused silica fibres allow have been significantly optimized in the past years. Therefore a compact and reliable detection system with high measuring accuracy is developed. Within this paper possible applications of the system under development and recent results will be discussed.

  5. Gas flow analysis during thermal vacuum test of a spacecraft. (United States)

    Scialdone, J. J.


    The pressures indicated by two tubulated ionization gages, one pointing to a spinning spacecraft undergoing thermal vacuum test and the other the walls of the chamber, have been used in a computer program to calculate important parameters of flow kinetics in the vacuum chamber. These parameters calculated as a function of time are: the self-contamination of the spacecraft (defined as the return of outgassed molecules on its critical surfaces either in orbit or while undergoing vacuum test); the spacecraft outgassing including leaks from sealed compartments; and the gas pumping performance of the vacuum chamber. The test indicated the feasibility of this type of evaluation and the improvements in instrumentations and arrangements needed for future tests.

  6. Thermal and Evolved Gas Analysis of "Nanophase" Carbonates: Implications for Thermal and Evolved Gas Analysis on Mars Missions (United States)

    Lauer, Howard V., Jr.; Archer, P. D., Jr.; Sutter, B.; Niles, P. B.; Ming, Douglas W.


    Data collected by the Mars Phoenix Lander's Thermal and Evolved Gas Analyzer (TEGA) suggested the presence of calcium-rich carbonates as indicated by a high temperature CO2 release while a low temperature (approx.400-680 C) CO2 release suggested possible Mg- and/or Fe-carbonates [1,2]. Interpretations of the data collected by Mars remote instruments is done by comparing the mission data to a database on the thermal properties of well-characterized Martian analog materials collected under reduced and Earth ambient pressures [3,4]. We are proposing that "nano-phase" carbonates may also be contributing to the low temperature CO2 release. The objectives of this paper is to (1) characterize the thermal and evolved gas proper-ties of carbonates of varying particle size, (2) evaluate the CO2 releases from CO2 treated CaO samples and (3) examine the secondary CO2 release from reheated calcite of varying particle size.

  7. A model-based analysis of the implications of shale gas developments for the European gas market

    Energy Technology Data Exchange (ETDEWEB)

    De Joode, J.; Plomp, A.J.; Ozdemir, O. [ECN Policy Studies, Petten (Netherlands)


    Shale gas in Europe could potentially be a big thing, especially in particular regions. Whereas test drillings need to confirm the technical recoverability of deposits and further research is needed on the environmental and safety aspects of shale gas production, this paper illustrates that shale gas developments may have substantial implications for regional gas balances, gas flows, and infrastructure requirements throughout Europe in the next decades.

  8. Interring Gas Dynamic Analysis of Piston in a Diesel Engine considering the Thermal Effect

    Directory of Open Access Journals (Sweden)

    Wanyou Li


    Full Text Available Understanding the interaction between ring dynamics and gas transport in ring pack systems is crucial and needs to be imperatively studied. The present work features detailed interring gas dynamics of piston ring pack behavior in internal combustion engines. The model is developed for a ring pack with four rings. The dynamics of ring pack are simulated. Due to the fact that small changes in geometry of the grooves and lands would have a significant impact on the interring gas dynamics, the thermal deformation of piston has been considered during the ring pack motion analysis in this study. In order to get the temperature distribution of piston head more quickly and accurately, an efficient method utilizing the concept of inverse heat conduction is presented. Moreover, a sensitive analysis based on the analysis of partial regression coefficients is presented to investigate the effect of groove parameters on blowby.


    Directory of Open Access Journals (Sweden)

    Nahiely Flores-Fajardo


    Full Text Available Los estudios del Gas Ionizado Difuso (DIG, hasta el momento se han hecho sin un consenso del criterio estricto para diferenciar entre el DIG y las regiones H II. En este trabajo recopilamos las mediciones de las l neas en emisi n de 29 galaxias disponibles en la literatura, creando la primera base de datos del DIG (DI- GEDA. Haciendo uso de esta base, analizamos las propiedades globales del DIG a partir de los cocientes de l neas [N II]-6583/H , [O I]-6300/H , [O III]-5007/H y [S II]-6716/H , as como la medida de emisi n de H . Este an lisis nos permiti concluir que el cociente [N II]/H es un criterio general para diferenciar si una regi n en emisi n es DIG o regi n H II, mientras que la EM(H es una cantidad til nicamente cuando consideramos galaxias por separado. Finalmente, encontramos que las regiones clasi cadas como DIG en galaxias Irr parecen tener un comportamiento m s cercano al de las regiones H II que al DIG en galaxias espirales.

  10. Manure management and greenhouse gas mitigation techniques : a comparative analysis

    Energy Technology Data Exchange (ETDEWEB)

    Langmead, C.


    Alberta is the second largest agricultural producer in Canada, ranking just behind Ontario. Approximately 62 per cent of the province's farm cash receipts are attributable to the livestock industry. Farmers today maintain large numbers of a single animal type. The drivers for more advanced manure management systems include: the trend towards confined feeding operations (CFO) is creating large, concentrated quantities of manure; public perception of CFO; implementation of provincial legislation regulating the expansion and construction of CFO; ratification of the Kyoto Protocol raised interest in the development of improved manure management systems capable of reducing greenhouse gas (GHG) emissions; and rising energy costs. The highest methane emissions factors are found with liquid manure management systems. They contribute more than 80 per cent of the total methane emissions from livestock manure in Alberta. The author identified and analyzed three manure management techniques to mitigate GHG emissions. They were: bio-digesters, gasification systems, and composting. Three recommendations were made to establish a strategy to support emissions offsets and maximize the reduction of methane emissions from the livestock industry. The implementation of bio-digesters, especially for the swine industry, was recommended. It was suggested that a gasification pilot project for poultry manure should be pursued by Climate Change Central. Public outreach programs promoting composting of cattle manure for beef feedlots and older style dairy barns should also be established. 19 refs., 11 tabs., 3 figs.

  11. Methodology for Structural Integrity Analysis of Gas Turbine Blades

    Directory of Open Access Journals (Sweden)

    Tiago de Oliveira Vale


    Full Text Available One of the major sources of stress arising in turbomachinery blades are the centrifugal loads acting at any section of the airfoil. Accounting for this phenomenon stress evaluation of the blade attachment region in the disc has to be performed in order to avoid blade failure. Turbomachinery blades are generally twisted, and the cross section area varies from the root of the blade to the tip. The blade root shape at the attachment region is of great concern. Stress concentrations are predictable at this contact region. In this paper, a finite element model has been created for the purpose of assessing stress at the joint region connecting the blade to the disc slot. Particular attention was paid to the geometric modeling of the "fir-tree" fixing, which is now used in the majority of gas turbine engines. This study has been performed using the commercial software ANSYS 13.0. The disc and blade assembly are forced to move with a certain rotational velocity. Contact connections are predicted on the common faces of the blade and on the disc at the root. Solutions can be obtained to allow the evaluation of stresses. Results can be compared with the mechanical properties of the adopted material.

  12. Saturator analysis for an evaporative gas turbine cycle

    Energy Technology Data Exchange (ETDEWEB)

    Parente, Joao O.S.; Traverso, Alberto; Massardo, Aristide F. [Universita di Genova, Thermo-Chemical Power Group (TPG), Genova (Italy)


    In this paper a thermodynamic assessment and a preliminary cost evaluation are given for an evaporative gas turbine (EvGT) cycle packed humidifier. Both background theory and simulation results are included. Two different approaches were used for the humidifier system modelling: the full integration of the mass-energy balance and mass transfer equations (called SAT model), and an atmospheric cooling tower-based model (called CT model). Both approaches were used to perform component thermodynamic analyses and to determine the humidifier packing design. Within these approaches, two simulation cases are discussed: a test case, with experimental results from the pilot-plant of the University of Lund, and a case study of the saturators for the optimised HAT (humid air turbine) cycles of a plant with a 50 MW power output. The two cases presented consider two different operating conditions for the saturator: the first being a 'non-optimised' saturator, and the second the 'optimal' configuration with reduced exergetic losses. For the case study, the saturator design and cost evaluation are also included. (Author)

  13. Analysis of Internal Cooling Geometry Variations in Gas Turbine Blades

    Institute of Scientific and Technical Information of China (English)

    M. Eifel; V. Caspary; H. H(o)nen; P. Jeschke


    The present investigation analyzes the effects of major geometrical modifications to the interior of a convection cooled gas turbine rotor blade. The main focus lies on the flow of the leading edge channels and the impact on the heat transfer. An experimental approach is performed with flow visualization via paint injection into water. Also numerical calculations are carried out in two sets, on the one hand water calculations accompanying the experi-ments and on the other hand conjugate heat transfer calculations under realistic engine conditions. The latter cal-culations are still ongoing delivering preliminary results. Five geometry configurations are investigated, three of them with differing turbulator arrangements in the leading edge channels. The operating point of the base configuration is set to Re = 50,000 at the inlet while for the modi-fied geometries the pressure ratio is held constant compared to the base. Among several investigated configurations one could be identified that leads to a heat transfer enhancement in one leading edge channel 7 % larger compared to the base.

  14. Molecular dynamics analysis of reflected gas molecules on self-assembled monolayers (United States)

    Takeuchi, Hideki


    In order to investigate the gas flow of high Knudsen number, it is necessary to specify the boundary condition for the reflected gas molecules at a solid surface. In most cases of the analysis, the diffuse reflection is generally assumed, but there are many cases for which this reflection cannot be applied. The characteristics of the reflected gas molecules depend on the state of the solid surface as well as the gas-surface interaction. The present author analyzed the scattering properties of monoatomic and diatomic gases on various solid surfaces based on the molecular dynamics (MD) method and proposed the boundary condition of reflected gas molecule (Phys. Fluids 18, 046103, 2006). Recently, self-assembled monolayers (SAMs) for the functionalization of the solid surface have been used in the development of micro/nano devices such as microarray and nanosensor. Therefore, it is interesting to study the scattering behavior of the reflected gas molecules on the SAM surface and make the scattering model of gases for the boundary condition. In this study, the angular distribution and the trapping probability for gas molecule on the SAM surface are observed by using MD simulation. The scattering probability at different incident energies is also discussed. JSPS KAKENHI Grant Number 26870813.

  15. Process analysis of syngas production by non-catalytic POX of oven gas

    Institute of Scientific and Technical Information of China (English)

    Fuchen WANG; Xinwen ZHOU; Wenyuan GUO; Zhenghua DAI; Xin GONG; Haifeng LIU; Guangsuo YU; Zunhong YU


    A non-catalytic POX of oven gas is proposed to solve the problem of secondary pollution due to solid wastes produced from the great amount of organic sulfur contained in oven gas in the traditional catalytic partial oxidation (POX) process. A study of the measurement of flow field and a thermodynamic analysis of the process characteristics were conducted. Results show that there exist a jet-flow region, a recirculation-flow region, a tube-flow region, and three corresponding reaction zones in the non-catalytic POX reformer. The combustion of oven gas occurs mainly in the jet-flow region, while the reformation of oven gas occurs mainly in the other two regions. Soot would not be formed by CH4 cracking at above 1200℃. Since there are very little C2+ hydrocarbons in oven gas, the soot produced would be very tiny, even if they underwent cracking reaction. The integrated model for entrained bed gasification process was applied to simulate a non-catalytic POX reformer. It indicated that the proper oxygen-to-oven gas ratio is 0.22-0.28 at differ-ent pressures in the oven gas reformation process.

  16. Visibility graph network analysis of natural gas price: The case of North American market (United States)

    Sun, Mei; Wang, Yaqi; Gao, Cuixia


    Fluctuations in prices of natural gas significantly affect global economy. Therefore, the research on the characteristics of natural gas price fluctuations, turning points and its influencing cycle on the subsequent price series is of great significance. Global natural gas trade concentrates on three regional markets: the North American market, the European market and the Asia-Pacific market, with North America having the most developed natural gas financial market. In addition, perfect legal supervision and coordinated regulations make the North American market more open and more competitive. This paper focuses on the North American natural gas market specifically. The Henry Hub natural gas spot price time series is converted to a visibility graph network which provides a new direction for macro analysis of time series, and several indicators are investigated: degree and degree distribution, the average shortest path length and community structure. The internal mechanisms underlying price fluctuations are explored through the indicators. The results show that the natural gas prices visibility graph network (NGP-VGN) is of small-world and scale-free properties simultaneously. After random rearrangement of original price time series, the degree distribution of network becomes exponential distribution, different from the original ones. This means that, the original price time series is of long-range negative correlation fractal characteristic. In addition, nodes with large degree correspond to significant geopolitical or economic events. Communities correspond to time cycles in visibility graph network. The cycles of time series and the impact scope of hubs can be found by community structure partition.

  17. Economic evaluation and market analysis for natural gas utilization. Topical report

    Energy Technology Data Exchange (ETDEWEB)

    Hackworth, J.H.; Koch, R.W.; Rezaiyan, A.J.


    During the past decade, the U.S. has experienced a surplus gas supply. Future prospects are brightening because of increased estimates of the potential size of undiscovered gas reserves. At the same time, U.S. oil reserves and production have steadily declined, while oil imports have steadily increased. Reducing volume growth of crude oil imports was a key objective of the Energy Policy Act of 1992. Natural gas could be an important alternative energy source to liquid products derived from crude oil to help meet market demand. The purpose of this study was to (1) analyze three energy markets to determine whether greater use could be made of natural gas or its derivatives and (2) determine whether those products could be provided on an economically competitive basis. The following three markets were targeted for possible increases in gas use: transportation fuels, power generation, and chemical feedstock. Gas-derived products that could potentially compete in these three markets were identified, and the economics of the processes for producing those products were evaluated. The processes considered covered the range from commercial to those in early stages of process development. The analysis also evaluated the use of both high-quality natural gas and lower-quality gases containing CO{sub 2} and N{sub 2} levels above normal pipeline quality standards.

  18. Sustainability Assessment of the Natural Gas Industry in China Using Principal Component Analysis

    Directory of Open Access Journals (Sweden)

    Xiucheng Dong


    Full Text Available Under pressure toward carbon emission reduction and air protection, China has accelerated energy restructuring by greatly improving the supply and consumption of natural gas in recent years. However, several issues with the sustainable development of the natural gas industry in China still need in-depth discussion. Therefore, based on the fundamental ideas of sustainable development, industrial development theories and features of the natural gas industry, a sustainable development theory is proposed in this thesis. The theory consists of five parts: resource, market, enterprise, technology and policy. The five parts, which unite for mutual connection and promotion, push the gas industry’s development forward together. Furthermore, based on the theoretical structure, the Natural Gas Industry Sustainability Index in China is established and evaluated via the Principal Component Analysis (PCA method. Finally, a conclusion is reached: that the sustainability of the natural gas industry in China kept rising from 2008 to 2013, mainly benefiting from increasing supply and demand, the enhancement of enterprise profits, technological innovation, policy support and the optimization and reformation of the gas market.

  19. Analysis of gas turbine cogeneration plants in Italy; Indagine sulla funzionalita` degli impianti di cogenerazione conturbina a gas operanti in Italia

    Energy Technology Data Exchange (ETDEWEB)

    Romani, Rino; Vignati, Sigfrido [ENEA, Centro Ricerche Casaccia, Rome (Italy). Dipt. Energia


    The purpose of this study is to improve, by random analysis, the current knowledge about functional and running data of gas turbine cogeneration plants in Italy. The analysis consider simple and combined cycle gas turbines plant with electric power less 30.000 k W per unit and involves a sample of 44 units according to a randomized model consisting of 112 gas turbines. The collected data show different plant selection criteria, energy performances, reliability and availability values as well as maintenance costs. These data support some general suggestions and recommendations for a better selection and utilization of these plants.


    Directory of Open Access Journals (Sweden)

    Ye. B. Bukreyeva


    Full Text Available Bronchopulmonary system diseases are on the first place among the causes of people's death. Most of methods for lung diseases diagnosis are invasive or not suitable for children and patients with severe disease. One of the promising methods of clinical diagnosis and disease activity monitoring of bronchopulmonary system is analyzing of human breath. Directly exhaled breath or exhaled breath condensate are using for human breaths analyzing. Analysis of human breath can apply for diagnostic, long monitoring and evaluation of efficacy of the treatment bronchopulmonary diseases. Differential diagnostic between chronic obstructive lung disease (COPD and bronchial asthma is complicated because they have differences in pathogenesis. Analysis of human breath allows to explore features of COPD and bronchial asthma and to improve differential diagnostic of these diseases. Human breaths analyzing can apply for diagnostic dangerous diseases, such as tuberculosis, lung cancer. The analysis of breath air by spectroscopy methods is new noninvasive way for diagnosis of bronchopulmonary diseases.

  1. Mixture gas component concentration analysis based on support vector machine and infrared spectrum

    Institute of Scientific and Technical Information of China (English)

    Peng Bai; Junhua Liu


    @@ A novel quantitative analysis method of multi-component mixture gas concentration based on support vector machine (SVM) and spectroscopy is proposed. Through transformation of the kernel function, the seriously overlapped and nonlinear spectrum data are transformed in high-dimensional space, but the highdimensional data can be processed in the original space. Some factors, such as kernel function, range of the wavelength, and penalty coefficient, are discussed. This method is applied to the quantitative analysis of natural gas components concentration, and the component concentration maximal deviation is 2.28%.

  2. Operation, Modeling and Analysis of the Reverse Water Gas Shift Process (United States)

    Whitlow, Jonathan E.


    The Reverse Water Gas Shift process is a candidate technology for water and oxygen production on Mars under the In-Situ Propellant Production project. This report focuses on the operation and analysis of the Reverse Water Gas Shift (RWGS) process, which has been constructed at Kennedy Space Center. A summary of results from the initial operation of the RWGS, process along with an analysis of these results is included in this report. In addition an evaluation of a material balance model developed from the work performed previously under the summer program is included along with recommendations for further experimental work.

  3. Modeling and parametric analysis of hollow fiber membrane system for carbon capture from multicomponent flue gas

    KAUST Repository

    Khalilpour, Rajab


    The modeling and optimal design/operation of gas membranes for postcombustion carbon capture (PCC) is presented. A systematic methodology is presented for analysis of membrane systems considering multicomponent flue gas with CO 2 as target component. Simplifying assumptions is avoided by namely multicomponent flue gas represented by CO 2/N 2 binary mixture or considering the co/countercurrent flow pattern of hollow-fiber membrane system as mixed flow. Optimal regions of flue gas pressures and membrane area were found within which a technoeconomical process system design could be carried out. High selectivity was found to not necessarily have notable impact on PCC membrane performance, rather, a medium selectivity combined with medium or high permeance could be more advantageous. © 2011 American Institute of Chemical Engineers (AIChE).

  4. Cross-interference correction and simultaneous multi-gas analysis based on infrared absorption

    Institute of Scientific and Technical Information of China (English)

    Sun You-Wen; Zeng Yi; Liu Wen-Qing; Xie Pin-Hua; Chan Ka-Lok; Li Xian-Xin; Wang Shi-Mei; Huang Shu-Hua


    In this paper,we present simultaneous multiple pollutant gases (CO2,CO,and NO) measurements by using the non-dispersive infrared (NDIR) technique.A cross-correlation correction method is proposed and used to correct the cross-interferences among the target gases.The calculation of calibration curves is based on least-square fittings with third-order polynomials,and the interference functions are approximated by linear curves.The pure absorbance of each gas is obtained by solving three simultaneous equations using the fitted interference functions.Through the interference correction,the signal created at each filter channel only depends on the absorption of the intended gas.Gas mixture samples with different concentrations of CO2,CO,and NO are pumped into the sample cell for analysis.The results show that the measurement error of each gas is less than 4.5%.

  5. Principal Component Analysis studies of turbulence in optically thick gas

    CERN Document Server

    Correia, Caio; Burkhart, Blakesley; Pogosyan, Dmitri; De Medeiros, José Renan


    In this work we investigate the Principal Component Analysis (PCA) sensitivity to the velocity power spectrum in high opacity regimes of the interstellar medium (ISM). For our analysis we use synthetic Position-Position-Velocity (PPV) cubes of fractional Brownian motion (fBm) and magnetohydrodynamics (MHD) simulations, post processed to include radiative transfer effects from CO. We find that PCA analysis is very different from the tools based on the traditional power spectrum of PPV data cubes. Our major finding is that PCA is also sensitive to the phase information of PPV cubes and this allows PCA to detect the changes of the underlying velocity and density spectra at high opacities, where the spectral analysis of the maps provides the universal -3 spectrum in accordance with the predictions of Lazarian \\& Pogosyan (2004) theory. This makes PCA potentially a valuable tool for studies of turbulence at high opacities provided that the proper gauging of the PCA index is made. The later, however, we found t...


    Energy Technology Data Exchange (ETDEWEB)

    Correia, C.; Medeiros, J. R. De [Departamento de Física Teórica e Experimental, Universidade Federal do Rio Grande do Norte, 59072-970, Natal (Brazil); Lazarian, A. [Astronomy Department, University of Wisconsin, Madison, 475 N. Charter St., WI 53711 (United States); Burkhart, B. [Harvard-Smithsonian Center for Astrophysics, 60 Garden St, MS-20, Cambridge, MA 02138 (United States); Pogosyan, D., E-mail: [Canadian Institute for Theoretical Astrophysics, University of Toronto, Toronto, ON (Canada)


    In this work we investigate the sensitivity of principal component analysis (PCA) to the velocity power spectrum in high-opacity regimes of the interstellar medium (ISM). For our analysis we use synthetic position–position–velocity (PPV) cubes of fractional Brownian motion and magnetohydrodynamics (MHD) simulations, post-processed to include radiative transfer effects from CO. We find that PCA analysis is very different from the tools based on the traditional power spectrum of PPV data cubes. Our major finding is that PCA is also sensitive to the phase information of PPV cubes and this allows PCA to detect the changes of the underlying velocity and density spectra at high opacities, where the spectral analysis of the maps provides the universal −3 spectrum in accordance with the predictions of the Lazarian and Pogosyan theory. This makes PCA a potentially valuable tool for studies of turbulence at high opacities, provided that proper gauging of the PCA index is made. However, we found the latter to not be easy, as the PCA results change in an irregular way for data with high sonic Mach numbers. This is in contrast to synthetic Brownian noise data used for velocity and density fields that show monotonic PCA behavior. We attribute this difference to the PCA's sensitivity to Fourier phase information.

  7. An analysis on social cost benefit of city gas safety supervision system - concentrated on estimating the intended amount paid about gas safety of households using city gas

    Energy Technology Data Exchange (ETDEWEB)

    Cho, Yong Sung [Korea Energy Economics Institute, Euiwang (Korea)


    With the increase of convenient and clean gas fuel consumption, the danger of gas safety accident is also increasing. Therefore, now is the time for requiring many thoughtful concerns and cares for the prevention of gas accident. In this study, the perception of city gas end users on use of city gas was studied and the economic value of improving gas safety was estimated by examining the intended amount paid for improving safety of city gas use. Although most of city gas end-users perceive that gas use is generally safe, they are concerned about a possibility of dander of accidents happened without any notice. On the other hand, about 97% of households using city gas know checking gas safety at a minimum, but only 60% among them are implementing self-checkup. The economic benefit of improving gas safety of city gas end-users in Korea is estimated from the lowest of 121.47 billion to the highest of 317.97 billion annually. (author). 38 refs., 5 figs., 45 tabs.

  8. Design of continuous circulation sub for gas drilling and the mechanical analysis on the sub body

    Directory of Open Access Journals (Sweden)

    Ding Feng


    Full Text Available Gas drilling, as an important part of underbalanced drilling, can increase drilling speed. But in the process of conventional gas drilling, it tends to cause cutting settlement, borehole collapse, sticking and other safety hazards because gas circulation has to be interrupted. Therefore, this paper presents a continuous circulation sub which can be installed and removed easily. With this sub, gas circulation will not be interrupted when drilling tools are connected and removed. This sub is composed of body, main valve, bypass valve and side entry sub. The structure design of its key components (i.e. main and bypass valves were fulfilled. Based on statics analysis on the sub body, its force situations under extension, torsion and internal pressure were simulated by using the ANSYS finite element analysis software. It is shown that its stress distribution trend is consistent with its elastic–plastic mechanics analysis results. Stress concentrates around the two round holes of the sub body, and the maximum deformation amount is still at the stage of elastic deformation. The analysis results are in line with the elastic–plastic mechanics analysis results, and the requirement of body strength is satisfied. This paper provides a new program to guarantee the drilling safety of extended-reach wells, underbalanced wells and narrow-density window wells.

  9. Flatography: Detection of gastrointestinal diseases by faecal gas analysis

    Institute of Scientific and Technical Information of China (English)

    Evelien; F; de; Groot; Tim; G; de; Meij; Daniel; J; Berkhout; Marc; P; van; der; Schee; Nanne; K; de; Boer


    Patients presenting with gastro-intestinal symptoms might suffer from a range of possible underlying diseases. An unmet need exists for novel cost-effective,reproducible, easy-to-perform and non-invasive tests. Hippocrates used body odours to diagnose diseases circa 460 before Christ. The art of diagnostic smelling is making a promising high-tech come-back with portable "electronic diagnostic noses". Analysis of faecal volatile organic compounds is a novel field in metabolomics with considerable potential to improve the diagnosis, phenotyping and monitoring of gastro-intestinal disease. Challenges will be to mature over the coming years by development of a standardized methodology for stool sample collection, storage, handling and analysis. Furthermore, key volatiles need to be identified to improve test accuracy and sensitivity by development of sensors tailored toward the accurate identification of disease specific volatiles. If these challenges are adequately faced, analysis of faecal volatiles has realistic potential to considerably improve screening, diagnosis and disease monitoring for gastro-intestinal diseases.

  10. Blood gas analysis in dogs with pulmonary heartworm disease. (United States)

    Kitagawa, H; Yasuda, K; Sasaki, Y


    Blood gases were analyzed in dogs with pulmonary heartworm (HW) disease. The arterial oxygen tension (PaO2) in dogs with mild signs of dirofilariasis (mildly affected group, n = 48, 85.7 +/- 8.2 mmHg) and in dogs with signs of right heart failure (severely affected group, n = 13, 76.4 +/- 11.6 mmHg) was lower (p < 0.01) than in dogs without HW infection (HW-free group, n = 19, 91.5 +/- 7.3 mmHg). Only 2 dogs in the severely affected group had a PaO2 less than 60 mmHg. The arterial carbon dioxide tension (PaCO2, p < 0.01) and mixed venous O2 (p < 0.01) and CO2 (p < 0.01) tensions were lower, and alveolar-arterial oxygen difference (AaDO2, p < 0.01) was greater in the severely affected group than in the HW-free and mildly affected groups. Arterial pH and bicarbonate (HCO3-) concentrations were lower (p < 0.01) in both affected groups than in the HW-free groups. The anion gap level was not different among the 3 groups. Serum lactic acid level in the severely affected group was higher (p < 0.01) than in the HW-free and mildly affected groups. However, a slightly higher serum lactic acid concentration was found only in 2 dogs of the severely affected group (3.84 mmol/l and 3.82 mmol/l). The PaO2 (r = -0.62) and AaDO2 (r = 0.66) correlated significantly (p < 0.01) with mean pulmonary arterial pressure. One week after HW removal, blood gases, pH and HCO3- concentration remained unchanged in the mildly affected group. In the severely affected group, blood gas values were the same, but pH and HCO3- concentration improved slightly.

  11. Sensitivity analysis of a light gas oil deep hydrodesulfurization process via catalytic distillation

    Energy Technology Data Exchange (ETDEWEB)

    Rosales-Quintero, A.; Vargas-Villamil, F.D. [Prog. de Matematicas Aplicadas y Computacion, Instituto Mexicano del Petroleo, Eje Central Lazaro Cardenas 152, Mexico, D.F. 07330 (Mexico); Arce-Medina, E. [Instituto Politecnico Nacional, ESIQIE, Ed. 8 Col. Lindavista, Mexico, D.F. 07738 (Mexico)


    In this work, a sensitivity analysis of a light gas oil deep hydrodesulfurization catalytic distillation column is presented. The aim is to evaluate the effects of various parameters and operating conditions on the organic sulfur compound elimination by using a realistic light gas oil fraction. The hydrocarbons are modeled using pseudocompounds, while the organic sulfur compounds are modeled using model compounds, i.e., dibenzothiophene (DBT) and 4,6-dimethyl dibenzothiophene (4,6-DMDBT). These are among the most refractive sulfur compounds present in the oil fractions. A sensitivity analysis is discussed for the reflux ratio, bottom flow rate, condenser temperature, hydrogen and gas oil feed stages, catalyst loading, the reactive, stripping, and rectifying stages, feed disturbances, and multiple feeds. The results give insight into the qualitative effect of some of the operating variables and disturbances on organic sulfur elimination. In addition, they show that special attention must be given to the bottom flow rate and LGO feed rate control. (author)

  12. Humidity independent mass spectrometry for gas phase chemical analysis via ambient proton transfer reaction

    Energy Technology Data Exchange (ETDEWEB)

    Zhu, Hongying; Huang, Guangming, E-mail:


    Graphical abstract: Direct and humidity independent mass spectrometry analysis of gas phase chemicals could be achieved via ambient proton transfer ionization, ion intensity was found to be stable with humidity ranged from ∼10% to ∼100%. - Highlights: • A humidity independent mass spectrometric method for gas phase samples analysis. • A universal and good sensitivity method. • The method can real time identify plant released raw chemicals. - Abstract: In this work, a humidity independent mass spectrometric method was developed for rapid analysis of gas phase chemicals. This method is based upon ambient proton transfer reaction between gas phase chemicals and charged water droplets, in a reaction chamber with nearly saturate humidity under atmospheric pressure. The humidity independent nature enables direct and rapid analysis of raw gas phase samples, avoiding time- and sample-consuming sample pretreatments in conventional mass spectrometry methods to control sample humidity. Acetone, benzene, toluene, ethylbenzene and meta-xylene were used to evaluate the analytical performance of present method. The limits of detection for benzene, toluene, ethylbenzene and meta-xylene are in the range of ∼0.1 to ∼0.3 ppbV; that of benzene is well below the present European Union permissible exposure limit for benzene vapor (5 μg m{sup −3}, ∼1.44 ppbV), with linear ranges of approximately two orders of magnitude. The majority of the homemade device contains a stainless steel tube as reaction chamber and an ultrasonic humidifier as the source of charged water droplets, which makes this cheap device easy to assemble and facile to operate. In addition, potential application of this method was illustrated by the real time identification of raw gas phase chemicals released from plants at different physiological stages.

  13. Analysis of micro vibration in gas film of aerostatic guide way based on molecule collision theory

    Directory of Open Access Journals (Sweden)

    Yang Shao Hua


    Full Text Available Micro vibration of the aerostatic guide way has a significant impact on its dynamic characteristics and stability, which limits the development of pneumatic component. High pressure gas molecules have been collided with the supporting surface and the internal surface of the throttle during the flow process. Variable impulse of the surfaces aside for the gas film are affected by the changes of impulse which formed irregular impact force in horizontal and vertical direction. Micro-vibration takes place based on the natural frequency of the system and its frequency doubling. In this paper, the vibration model was established to describe the dynamic characteristics of the gas film, and the formation mechanism of micro vibration in the film is defined. Through the simulation analysis and experimental comparison, formation mechanism of the micro vibration in the gas film is confirmed. It was proposed that the micro vibration of gas film can be produced no matter whether there is a gas chamber or not in the throttle. Under the same conditions, the micro vibration of the guide way with air chamber is greater than that without any chamber. The frequency points of the vibration peaks are almost the same, as well as the vibration pattern in the frequency domain.

  14. Thermodynamic Analysis and Experimental Study on Reaction of CO2 Gas with Hot Metal

    Institute of Scientific and Technical Information of China (English)

    Guo WEI; Zhi-tao LI; Zi-liang LI; Qiang-jian GAO; Feng-man SHEN


    The reaction of CO2 gas with hot metal was investigated based on the thermodynamic analysis and experi-mental results.It shows that both silicon and carbon in hot metal can be oxidized by CO2 gas in the temperature range of 1 300-1 500 ℃.When using graphite crucible,temperature has little influence on final mass percent of car-bon w[C] because of the carburization effect.Decarburization degree rises significantly with increasing gas inj ection rate and w[C] can be reduced to 3�2% at most when using MgO crucible.Lower temperature or higher gas inj ection rate is propitious to promote desilication reaction,but only 5%-10% of desilication ratio could be obtained in 20 min. The final mass percent of silicon w[Si] when using MgO crucible is lower than that when using graphite crucible.Ex-perimental results also demonstrate that CO2 injection has no effect on the concentration of manganese,sulfur and phosphorus in hot metal.In view of the weak oxidation ability and temperature drop of hot metal,CO2 gas is sugges-ted to be used as carrier gas in desilication process rather than oxidizing agent.

  15. Application of Gas Chromatographic analysis to RPC detectors in the ATLAS experiment at CERN-LHC

    CERN Document Server

    De Asmundis, R


    Starting from 2007 a large number (1200) Resistive Plate Chambers (RPC) detectors will be used as muon trigger detectors in the ATLAS Experiment at CERN-LHC accelerator. RPC are gaseous detector in which the quality and the stability of the gas mixture as well as the design of the gas supplying system, play a fundamental role in their functioning. RPC are foreseen to work more than ten years in the high radiation environment of ATLAS and the gas mixture acts really as a "lifeguard" for the detectors. For this reason a great attention has been devoted to the gas studies in order to optimize RPC performance, robustness and reliability in a high radiation environment. In this paper we describe the work done to decide how to supply and control in an optimal way the gas to the detectors, in order to ensure their best performance for a long time. The activity, based on Gas Chromatographic (GC) analysis, has been carried on a sample of final RPC working in radiation conditions much more intense than those foreseen f...

  16. Comprehensive two-dimensional gas chromatography for the analysis of organohalogenated micro-contaminants

    NARCIS (Netherlands)

    Korytar, P.; Haglund, P.; Boer, de J.; Brinkman, U.A.Th.


    We explain the principles of comprehensive two-dimensional gas chromatography (GC × GC), and discuss key instrumental aspects - with emphasis on column combinations and mass spectrometric detection. As the main item of interest, we review the potential of GC × GC for the analysis of organohalogenate

  17. Multi-scale symbolic time reverse analysis of gas-liquid two-phase flow structures (United States)

    Wang, Hongmei; Zhai, Lusheng; Jin, Ningde; Wang, Youchen

    Gas-liquid two-phase flows are widely encountered in production processes of petroleum and chemical industry. Understanding the dynamic characteristics of multi-scale gas-liquid two-phase flow structures is of great significance for the optimization of production process and the measurement of flow parameters. In this paper, we propose a method of multi-scale symbolic time reverse (MSTR) analysis for gas-liquid two-phase flows. First, through extracting four time reverse asymmetry measures (TRAMs), i.e. Euclidean distance, difference entropy, percentage of constant words and percentage of reversible words, the time reverse asymmetry (TRA) behaviors of typical nonlinear systems are investigated from the perspective of multi-scale analysis, and the results show that the TRAMs are sensitive to the changing of dynamic characteristics underlying the complex nonlinear systems. Then, the MSTR analysis is used to study the conductance signals from gas-liquid two-phase flows. It is found that the multi-scale TRA analysis can effectively reveal the multi-scale structure characteristics and nonlinear evolution properties of the flow structures.

  18. Carbohydrate analysis of hemicelluloses by gas chromatography-mass spectrometry of acteylated methyl glycosides

    DEFF Research Database (Denmark)

    Sárossy, Zsuzsa; Plackett, David; Egsgaard, Helge


    A method based on gas chromatography–mass spectrometry analysis of acetylated methyl glycosides was developed in order to analyze monosaccharides obtained from various hemicelluloses. The derivatives of monosaccharide standards, arabinose, glucose, and xylose were studied in detail and 13C...

  19. Analysis of Trace Hydrogen Isotopes in Fusion Fuel Cycle by High Precision Gas Chromatograph

    Institute of Scientific and Technical Information of China (English)

    YANG; Li-ling; YANG; Hong-guang; ZHAO; Wei-wei; HE; Chang-shui; LIU; Zhen-xing; ZHAN; Qin


    It is essential to analysis of hydrogen isotopes in the fuel cycle system of fusion reactors,gas chromatography(GC)was found to be an effectively analytical technique.Compared with conventional GC,the high-precision GC with a cryogenic column could achieve fairly good performance to reduce the retention time.

  20. Quantitative analysis of target components by comprehensive two-dimensional gas chromatography

    NARCIS (Netherlands)

    Mispelaar, V.G. van; Tas, A.C.; Smilde, A.K.; Schoenmakers, P.J.; Asten, A.C. van


    Quantitative analysis using comprehensive two-dimensional (2D) gas chromatography (GC) is still rarely reported. This is largely due to a lack of suitable software. The objective of the present study is to generate quantitative results from a large GC x GC data set, consisting of 32 chromatograms. I

  1. Investigation of thiol derivatized gold nanoparticle sensors for gas analysis (United States)

    Stephens, Jared S.

    Analysis of volatile organic compounds (VOCs) in air and exhaled breath by sensor array is a very useful testing technique. It can provide non-invasive, fast, inexpensive testing for many diseases. Breath analysis has been very successful in identifying cancer and other diseases by using a chemiresistor sensor or array with gold nanoparticles to detect biomarkers. Acetone is a biomarker for diabetes and having a portable testing device could help to monitor diabetic and therapeutic progress. An advantage to this testing method is it is conducted at room temperature instead of 200 degrees Celsius. 3. The objective of this research is to determine the effect of thiol derivatized gold nanoparticles based on sensor(s) detection of VOCs. The VOCs to be tested are acetone, ethanol, and a mixture of acetone and ethanol. Each chip is tested under all three VOCs and three concentration levels (0.1, 1, and 5.0 ppm). VOC samples are used to test the sensors' ability to detect and differentiate VOCs. Sensors (also referred to as a chip) are prepared using several types of thiol derivatized gold nanoparticles. The factors are: thiol compound and molar volume loading of the thiol in synthesis. The average resistance results are used to determine the VOC selectivity of the sensors tested. The results show a trend of increasing resistance as VOC concentration is increased relative to dry air; which is used as baseline for VOCs. Several sensors show a high selectivity to one or more VOCs. Overall the 57 micromoles of 4-methoxy-toluenethiol sensor shows the strongest selectivity for VOCs tested. 3. Gerfen, Kurt. 2012. Detection of Acetone in Air Using Silver Ion Exchanged ZSM-5 and Zinc Oxide Sensing Films. Master of Science thesis, University of Louisville.

  2. Fuzzy Reliability Analysis for Seabed Oil-Gas Pipeline Networks Under Earthquakes

    Institute of Scientific and Technical Information of China (English)

    刘震; 潘斌


    The seabed oil-gas pipeline network is simplified to a network w i th stochastic edge-weight by means of the fuzzy graphics theory. With the help o f network analysis, fuzzy mathematics, and stochastic theory, the problem of rel iability analysis for the seabed oil-gas pipeline network under earthquakes is t ransformed into the calculation of the transitive closure of fuzzy matrix of the stochastic fuzzy network. In classical network reliability analysis, the node i s supposed to be non-invalidated; in this paper, this premise is modified by in t roducing a disposal method which has taken the possible invalidated node into a ccount. A good result is obtained by use of the Monte Carlo simulation analysis.

  3. Gas chromatographic analysis of polyhydroxybutyrate in activated sludge: a round-robin test. (United States)

    Baetens, D; Aurola, A M; Foglia, A; Dionisi, D; van Loosdrecht, M C M


    Polyhydroxyalkanoates (PHA) and poly-beta-hydroxybutyrate (PHB) in particular have become compounds which is routinely investigated in wastewater research. The PHB analysis method has only recently been applied to activated sludge samples where PHA contents might be relatively low. This urges the need to investigate the reproducibility of the gas chromatographic method for PHB analysis. This was evaluated in a round-robin test in 5 European laboratories with samples from lab-scale and full-scale enhanced biological phosphorus removal systems. It was shown that the standard deviation of measurements in each lab and the reproducibility between the labs was very good. Experimental results obtained by different laboratories using this analysis method can be compared. Sludge samples with PHB contents varying between 0.3 and 22.5 mg PHB/mg sludge were analysed. The gas chromatographic method allows for PHV, PH2MB and PH2MV analysis as well.

  4. Analysis of a reheat gas turbine cycle with chemical recuperation using Aspen

    Energy Technology Data Exchange (ETDEWEB)

    Harvey, S.; Kane, N`Diaye [ISITEM - Lab. d`Energetique, Nantes (France)


    Present-day high performance gas turbine based cycles use the combined cycle concept in which the heat in the hot turbine exhaust stream is used to raise steam which can be used to generate electricity using a steam turbine. Recent attention has focused in particular on the chemical heat recovery concept.The potential benefits of such cycles include high conversion efficiency, ultra-low NO{sub x} emission levels (less than 1 ppm) and high power density per unit of land. The low thermal NO{sub X} emissions result from the presence of hydrogen in the reformed fuel gas, which enables combustion at lower flame temperatures. Thus, a CRGT (Chemically Recuperated Gas Turbine) cycle can meet the strictest NO{sub x} limits in operation today without the need for selective catalytic reduction. Such environmental characteristics are the primary reason fuelling current interest in CRGT cycles. For design reasons, reheat combustors cannot be easily adapted to stationary gas turbines, and until recently the CRGT cycle seemed to be limited to aeroderivative gas turbine applications. However, ABB recently unveiled its new GT26 series stationary gas turbines using staged expansion with reheat combustion, allowing high thermal efficiencies with relatively low turbine inlet temperatures. This type of turbine appears particularly well-suited for chemical heat recovery. In this paper, we present a CRGT cycle based on a reheat gas turbine with key design features similar to those of ABB`s GT26 machine. The cycle analysis is performed using ASPEN+ process simulation software. The report includes a detailed first and second law analysis of the cycle. The results confirm that the energy conversion efficiencies of CRGT cycles cannot rival with the efficiencies achieved by state-of-the-art combined cycles. 12 refs, 3 figs, 5 tabs

  5. Parametric Analysis of a Two-Shaft Aeroderivate Gas Turbine of 11.86 MW

    Directory of Open Access Journals (Sweden)

    R. Lugo-Leyte


    Full Text Available The aeroderivate gas turbines are widely used for power generation in the oil and gas industry. In offshore marine platforms, the aeroderivative gas turbines provide the energy required to drive mechanically compressors, pumps and electric generators. Therefore, the study of the performance of aeroderivate gas turbines based on a parametric analysis is relevant to carry out a diagnostic of the engine, which can lead to operational as well as predictive and/or corrective maintenance actions. This work presents a methodology based on the exergetic analysis to estimate the irrevesibilities and exergetic efficiencies of the main components of a two-shaft aeroderivate gas turbine. The studied engine is the Solar Turbine Mars 100, which is rated to provide 11.86 MW. In this engine, the air is compressed in an axial compressor achieving a pressure ratio of 17.7 relative to ambient conditions and a high pressure turbine inlet temperature of 1220 °C. Even if the thermal efficiency associated to the pressure ratio of 17.7 is 1% lower than the maximum thermal efficiency, the irreversibilities related to this pressure ratio decrease approximately 1 GW with respect to irreversibilities of the optimal pressure ratio for the thermal efficiency. In addition, this paper contributes to develop a mathematical model to estimate the high turbine inlet temperature as well as the pressure ratio of the low and high pressure turbines.

  6. Analysis of fission gas release in LWR fuel using the BISON code

    Energy Technology Data Exchange (ETDEWEB)

    G. Pastore; J.D. Hales; S.R. Novascone; D.M. Perez; B.W. Spencer; R.L. Williamson


    Recent advances in the development of the finite-element based, multidimensional fuel performance code BISON of Idaho National Laboratory are presented. Specifically, the development, implementation and testing of a new model for the analysis of fission gas behavior in LWR-UO2 fuel during irradiation are summarized. While retaining a physics-based description of the relevant mechanisms, the model is characterized by a level of complexity suitable for application to engineering-scale nuclear fuel analysis and consistent with the uncertainties pertaining to some parameters. The treatment includes the fundamental features of fission gas behavior, among which are gas diffusion and precipitation in fuel grains, growth and coalescence of gas bubbles at grain faces, grain growth and grain boundary sweeping effects, thermal, athermal, and transient gas release. The BISON code incorporating the new model is applied to the simulation of irradiation experiments from the OECD/NEA International Fuel Performance Experiments database, also included in the IAEA coordinated research projects FUMEX-II and FUMEX-III. The comparison of the results with the available experimental data at moderate burn-up is presented, pointing out an encouraging predictive accuracy, without any fitting applied to the model parameters.

  7. Techno-economic analysis for the evaluation of three UCG synthesis gas end use approaches (United States)

    Nakaten, Natalie; Kempka, Thomas; Burchart-Korol, Dorota; Krawczyk, Piotr; Kapusta, Krzysztof; Stańczyk, Krzysztof


    Underground coal gasification (UCG) enables the utilization of coal reserves that are economically not exploitable because of complex geological boundary conditions. In the present study we investigate UCG as a potential economic approach for conversion of deep-seated coals into a synthesis gas and its application within three different utilization options. Related to geological boundary conditions and the chosen gasification agent, UCG synthesis gas composes of varying methane, hydrogen, nitrogen, carbon monoxide and carbon dioxide amounts. In accordance to its calorific value, the processed UCG synthesis gas can be utilized in different manners, as for electricity generation in a combined cycle power plant or for feedstock production making use of its various chemical components. In the present study we analyze UCG synthesis gas utilization economics in the context of clean electricity generation with an integrated carbon capture and storage process (CCS) as well as synthetic fuel and fertilizer production (Kempka et al., 2010) based on a gas composition achieved during an in situ UCG trial in the Wieczorek Mine. Hereby, we also consider chemical feedstock production in order to mitigate CO2 emissions. Within a sensitivity analysis of UCG synthesis gas calorific value variations, we produce a range of capital and operational expenditure bandwidths that allow for an economic assessment of different synthesis gas end use approaches. To carry out the integrated techno-economic assessment of the coupled systems and the sensitivity analysis, we adapted the techno-economic UCG-CCS model developed by Nakaten et al. (2014). Our techno-economic modeling results demonstrate that the calorific value has a high impact on the economics of UCG synthesis gas utilization. In the underlying study, the synthesis gas is not suitable for an economic competitive electricity generation, due to the relatively low calorific value of 4.5 MJ/Nm³. To be a profitable option for electricity

  8. Value of arterial blood gas analysis in patients with acute dyspnea: an observational study



    Introduction The diagnostic and prognostic value of arterial blood gas analysis (ABGA) parameters in unselected patients presenting with acute dyspnea to the Emergency Department (ED) is largely unknown. Methods We performed a post-hoc analysis of two different prospective studies to investigate the diagnostic and prognostic value of ABGA parameters in patients presenting to the ED with acute dyspnea. Results We enrolled 530 patients (median age 74 years). ABGA parameters were neither useful ...

  9. Parallel Hybrid Gas-Electric Geared Turbofan Engine Conceptual Design and Benefits Analysis (United States)

    Lents, Charles; Hardin, Larry; Rheaume, Jonathan; Kohlman, Lee


    The conceptual design of a parallel gas-electric hybrid propulsion system for a conventional single aisle twin engine tube and wing vehicle has been developed. The study baseline vehicle and engine technology are discussed, followed by results of the hybrid propulsion system sizing and performance analysis. The weights analysis for the electric energy storage & conversion system and thermal management system is described. Finally, the potential system benefits are assessed.

  10. Intelligent Fault Diagnosis in Power Transformer with Using Dissolved Gas Analysis in different Standards by Fuzzy Logic

    Directory of Open Access Journals (Sweden)

    Rahmat Houshmand


    Full Text Available The power electric transformer fault diagnosis is based on dissolved gas-in-oil analysis (DGA. the conventional fault diagnosis methods, i.e. the ratio methods (Rogers, Dornenburg and IEC and the key gas method, have limitations such as the “no decision” problem. Various artificial intelligence techniques may help solve the problems and present a better solution. In this paper present a fuzzy systems to fault diagnosis in power electric transformer by dissolved we gas analysis.

  11. Comparative analysis of monetizing technologies for the use of offshore natural gas; Analise comparativa das tecnologias embarcadas de aproveitamento de gas natural

    Energy Technology Data Exchange (ETDEWEB)

    Biruel Junior, Jose


    The growing world need for natural gas, the issue of offshore oil and associated gas exploration in regions constantly farther from the consumer market, and the law restrictions due to greenhouses gases emissions have stimulated the development of technologies intended to monetizing stranded gas reserves. In order to compare these technologies, a Multi Criteria Decision Analysis Methodology, based on fuzzy parameters, has been developed. The Methodology enables specialists to define analysis dimensions and criteria as well as to assign weight and ratings by means of linguistic variables, resulting in a general performance index for each technology. The Methodology has been applied in a case study to compare the floating technologies FCNG (Floating Compressed Natural Gas), FLNG (Floating Liquefied Natural Gas), FGTL (Floating Gas-to-Liquid) and FGTW (Floating Gas-to- Wire). The efficacy of the Methodology depends on the comprehensiveness and quality of the information provided. Therefore, this dissertation presents a study of these technologies, placing strong emphasis on the Technological Dimension. The Methodology allows for the identification of the drawbacks of each technology so as to especially conduct R and D efforts to improve their competitiveness. (author)

  12. Exergy analysis of offshore processes on North Sea oil and gas platforms

    DEFF Research Database (Denmark)

    Nguyen, Tuong-Van; Pierobon, Leonardo; Elmegaard, Brian


    generation. In this paper, the most thermodynamically inefficient processes are identified by performing an exergy analysis, based on models built with the simulation tools Aspen Plus®, DNA and Aspen HYSYS®. Results reveal that the total exergy destruction of the system amounts to 69.4 MW, while the total...... exergy losses amount to 22.3 MW. The gas lifting train and the production-separation module are the most exergy-destructive operations of the oil and gas processing system, consuming 8.83 MW and 8.17 MW respectively, while the power generation system alone is responsible for 46.7 MW. The exergetic...

  13. Analysis of spectrum characteristics of optical scintillation in stack gas flow

    Institute of Scientific and Technical Information of China (English)

    Liu Wen-Qing; Liu He-Lai; Zeng Zong-Yong; Jiang Yu


    Based on the analysis of spectrum characteristics of intensity fluctuations while light beams pass through stack gas flow in an industrial setting, this paper puts emphasis upon discussing the spectrum of optical intensity fluctuations by the variety of particle concentration in stack gas flow. This paper also gives the primary theoretical explanation of the measurement results in the stack of coal-fired utility boilers. Meanwhile, the cross-correlation formula is given as the theoretical basis of velocity measurement by using particle concentration scintillation.

  14. Motion analysis of waste rock in gas-solids fluidized bed in coal dry beneficiation

    Institute of Scientific and Technical Information of China (English)

    郭迎福; 陈安华; 张永忠; 邓志鹏; 毛树楷


    Through the analysis of forces acting on the waste rock in the gas-solid fluidized bed, the waste rock velocity equations and displacement equations in the gas-solids fluidized bed were achieved and the influential factors of the waste rock motion in the fluidized bed were studied in this paper. The conclusions show that the primary factors influencing the waste rock motion are the waste rock grain size and the scraper velocity according to the computer simulation. This has provided the theoretical foundation both for improving the separating effect and ascertaining the length of the separating cell.

  15. Glass bottle sampling solid phase microextraction gas chromatography mass spectrometry for breath analysis of drug metabolites. (United States)

    Lu, Yan; Niu, Wenqi; Zou, Xue; Shen, Chengyin; Xia, Lei; Huang, Chaoqun; Wang, Hongzhi; Jiang, Haihe; Chu, Yannan


    Breath analysis is a non-invasive approach which may be applied to disease diagnosis and pharmacokinetic study. In the case of offline analysis, the exhaled gas needs to be collected and the sampling bag is often used as the storage vessel. However, the sampling bag usually releases some extra compounds, which may interfere with the result of the breath test. In this study, a novel breath sampling glass bottle was developed with a syringe needle sampling port for solid phase microextraction (SPME). Such a glass bottle scarcely liberates compounds and can be used to collect exhaled gas for ensuing analysis by gas chromatography-mass spectrometry (GC-MS). The glass bottle sampling SPME-GC-MS analysis was carried out to investigate the breath metabolites of myrtol, a multicompound drug normally used in the treatment of bronchitis and sinusitis. Four compounds, α-pinene, 2,3-dehydro-1,8-cineole, d-limonene and 1,8-cineole were found in the exhaled breath of all eight volunteers who had taken the myrtol. While for other ten subjects who had not used the myrtol, these compounds were undetectable. In the SPME-GC-MS analysis of the headspace of myrtol, three compounds were detected including α-pinene, d-limonene and 1,8-cineole. Comparing the results of breath and headspace analysis, it indicates that 2,3-dehydro-1,8-cineole in the breath is the metabolite of 1,8-cineole. It is the first time that this metabolite was identified in human breath. The study demonstrates that the glass bottle sampling SPME-GC-MS method is applicable to exhaled gas analysis including breath metabolites investigation of drugs like myrtol.

  16. Fuzzy Bayesian Network-Bow-Tie Analysis of Gas Leakage during Biomass Gasification.

    Directory of Open Access Journals (Sweden)

    Fang Yan

    Full Text Available Biomass gasification technology has been rapidly developed recently. But fire and poisoning accidents caused by gas leakage restrict the development and promotion of biomass gasification. Therefore, probabilistic safety assessment (PSA is necessary for biomass gasification system. Subsequently, Bayesian network-bow-tie (BN-bow-tie analysis was proposed by mapping bow-tie analysis into Bayesian network (BN. Causes of gas leakage and the accidents triggered by gas leakage can be obtained by bow-tie analysis, and BN was used to confirm the critical nodes of accidents by introducing corresponding three importance measures. Meanwhile, certain occurrence probability of failure was needed in PSA. In view of the insufficient failure data of biomass gasification, the occurrence probability of failure which cannot be obtained from standard reliability data sources was confirmed by fuzzy methods based on expert judgment. An improved approach considered expert weighting to aggregate fuzzy numbers included triangular and trapezoidal numbers was proposed, and the occurrence probability of failure was obtained. Finally, safety measures were indicated based on the obtained critical nodes. The theoretical occurrence probabilities in one year of gas leakage and the accidents caused by it were reduced to 1/10.3 of the original values by these safety measures.

  17. In situ analysis of gas composition by electron energy-loss spectroscopy for environmental transmission electron microscopy

    Energy Technology Data Exchange (ETDEWEB)

    Crozier, Peter A., E-mail: [School for Engineering of Matter, Transport and Energy, Arizona State University Tempe, AZ 85287-6106 (United States); Chenna, Santhosh [School for Engineering of Matter, Transport and Energy, Arizona State University Tempe, AZ 85287-6106 (United States)


    We have developed methods for using in situ electron energy-loss spectroscopy (EELS) to perform quantitative analysis of gas in an environmental transmission electron microscope. Inner-shell EELS was able to successfully determine the composition of gas mixtures with an accuracy of about 15% or better provided that some precautions are taken during the acquisition to account for the extended gas path lengths associated with the reaction cell. The unique valence-loss spectrum associated with many gases allowed simple methodologies to be developed to determine gas composition from the low-loss region of the spectrum from a gas mixture. The advantage of the valence loss approach is that it allows hydrogen to be detected and quantified. EELS allows real-time analysis of the volume of gas inside the reaction cell and can be performed rapidly with typical acquisition times of a few seconds or less. This in situ gas analysis can also be useful for revealing mass transport issues associated with the differential gas diffusion through the system. -- Research Highlights: {yields} In situ electron energy-loss spectroscopy for gas analysis in ETEM. {yields} Compositional accuracy of about 15% or better. {yields} Can use core-loss or valence loss spectroscopy. {yields} Can detect mass transport property of gas handling system.


    Directory of Open Access Journals (Sweden)

    Demyanenko DV


    Full Text Available The purpose of this work was to make qualitative and quantitative analysis of phenolic biologically active substances (BAS in the extracts produced from lime flowers with condensed gases, using method of high-performance liquid chromatography (HPLC. Materials and methods: materials for this study were the extracts obtained by consequent processing of the herbal drug and marcs thereof with various condensed gases: difluorochloromethane (Freon R22, difluoromethane (Freon R32, azeotropic mixture of difluoromethane with pentafluoroethane (Freon 410A and freon-ammonium mixture. Extracts obtained with the latter were subjected to further fractionation by liquidliquid separation into hexane, chloroform, ethyl acetate and aqueous-alcohol phases. Besides, the supercritical СО2 extract, obtained from the herbal drug under rather strong conditions (at temperature 60°С and pressure 400 bar, was studied in our previous research. Presence of phenolic BAS and their quantity in the researched samples were determined by method of HPLC with UVspectrometric detection. Results and discussion: It has been found that Freon R22 extracted trace amounts of rutin from lime flowers – its content was only 0.08% of the total extract weight. On the other hand, Freons R32 and R410А showed good selectivity to moderately polar BAS of lime flowers (derivatives of flavonoids and hydroxycinnamic acids: in particular, the extract obtained with freon R32 contained about 1.3% of the total phenolic substances, and it was the only one of the investigated condensed gases used by us which took the basic flavonoid of lime flowers tiliroside – its content was 0.42% of extract weight. Also Freons R32 and R410А were able to withdraw another compound dominating among phenolic substances in the yielded extracts. Its quantity was rather noticeable – up to 0.87% of extract weight. This substance was not identified by existing database, but its UV-spectrum was similar to those of

  19. [Intermediate experiment and mechanism analysis of flue gas desulfurization technology by circulating fluidized bed]. (United States)

    Zhao, Xudong; Wu, Shaohua; Ma, Chunyuan; Qin, Yukun


    A new Circulating Fluidized Bed was designed for intermediate experiment of flue gas desulphurization, in which the flue gas flow rate was 3500 m3/h. By using it, the basic experiments were carried out to study the influence of Ca/S and supersaturated temperature on desulphurization efficiency and the effect of the recycling solid particle in the sulfur removal column on desulphurization performance. The results showed when Ca/S = 1.2, the desulphurization efficiency was increased by 15% through the recycle of solid particle; the gas velocity inside the bed could be designed higher. The mechanism analysis were also studied and the method to increase effective resident time was introduced.

  20. Numerical Simulation and Analysis of Migration Law of Gas Mixture Using Carbon Dioxide as Cushion Gas in Underground Gas Storage Reservoir

    Institute of Scientific and Technical Information of China (English)

    ChuanKai Niu; YuFei Tan


    One of the major technical challenges in using carbon dioxide ( CO2 ) as part of the cushion gas of the underground gas storage reservoir ( UGSR) is the mixture of CO2 and natural gas. To decrease the mixing extent and manage the migration of the mixed zone, an understanding of the mechanism of CO2 and natural gas mixing and the diffusion of the mixed gas in aquifer is necessary. In this paper, a numerical model based on the three dimensional gas-water two-phase flow theory and gas diffusion theory is developed to understand this mechanism. This model is validated by the actual operational data in Dazhangtuo UGSR in Tianjin City, China. Using the validated model, the mixed characteristic of CO2 and natural gas and the migration mechanism of the mixed zone in an underground porous reservoir is further studied. Particularly, the impacts of the following factors on the migration mechanism are studied:the ratio of CO2 injection, the reservoir porosity and the initial operating pressure. Based on the results, the optimal CO2 injection ratio and an optimal control strategy to manage the migration of the mixed zone are obtained. These results provide technical guides for using CO2 as cushion gas for UGSR in real projects.

  1. Analysis of Critical Permeabilty, Capillary Pressure and Electrical Properties for Mesaverde Tight Gas Sandstones from Western U.S. Basins

    Energy Technology Data Exchange (ETDEWEB)

    Alan Byrnes; Robert Cluff; John Webb; John Victorine; Ken Stalder; Daniel Osburn; Andrew Knoderer; Owen Metheny; Troy Hommertzheim; Joshua Byrnes; Daniel Krygowski; Stefani Whittaker


    Although prediction of future natural gas supply is complicated by uncertainty in such variables as demand, liquefied natural gas supply price and availability, coalbed methane and gas shale development rate, and pipeline availability, all U.S. Energy Information Administration gas supply estimates to date have predicted that Unconventional gas sources will be the dominant source of U.S. natural gas supply for at least the next two decades (Fig. 1.1; the period of estimation). Among the Unconventional gas supply sources, Tight Gas Sandstones (TGS) will represent 50-70% of the Unconventional gas supply in this time period (Fig. 1.2). Rocky Mountain TGS are estimated to be approximately 70% of the total TGS resource base (USEIA, 2005) and the Mesaverde Group (Mesaverde) sandstones represent the principal gas productive sandstone unit in the largest Western U.S. TGS basins including the basins that are the focus of this study (Washakie, Uinta, Piceance, northern Greater Green River, Wind River, Powder River). Industry assessment of the regional gas resource, projection of future gas supply, and exploration programs require an understanding of reservoir properties and accurate tools for formation evaluation. The goal of this study is to provide petrophysical formation evaluation tools related to relative permeability, capillary pressure, electrical properties and algorithms for wireline log analysis. Detailed and accurate moveable gas-in-place resource assessment is most critical in marginal gas plays and there is need for quantitative tools for definition of limits on gas producibility due to technology and rock physics and for defining water saturation. The results of this study address fundamental questions concerning: (1) gas storage; (2) gas flow; (3) capillary pressure; (4) electrical properties; (5) facies and upscaling issues; (6) wireline log interpretation algorithms; and (7) providing a web-accessible database of advanced rock properties. The following text

  2. Numerical Analysis of Turbulent Combustion in a Model Swirl Gas Turbine Combustor

    Directory of Open Access Journals (Sweden)

    Ali Cemal Benim


    Full Text Available Turbulent reacting flows in a generic swirl gas turbine combustor are investigated numerically. Turbulence is modelled by a URANS formulation in combination with the SST turbulence model, as the basic modelling approach. For comparison, URANS is applied also in combination with the RSM turbulence model to one of the investigated cases. For this case, LES is also used for turbulence modelling. For modelling turbulence-chemistry interaction, a laminar flamelet model is used, which is based on the mixture fraction and the reaction progress variable. This model is implemented in the open source CFD code OpenFOAM, which has been used as the basis for the present investigation. For validation purposes, predictions are compared with the measurements for a natural gas flame with external flue gas recirculation. A good agreement with the experimental data is observed. Subsequently, the numerical study is extended to syngas, for comparing its combustion behavior with that of natural gas. Here, the analysis is carried out for cases without external flue gas recirculation. The computational model is observed to provide a fair prediction of the experimental data and predict the increased flashback propensity of syngas.

  3. Wavelength modulation spectroscopy--digital detection of gas absorption harmonics based on Fourier analysis. (United States)

    Mei, Liang; Svanberg, Sune


    This work presents a detailed study of the theoretical aspects of the Fourier analysis method, which has been utilized for gas absorption harmonic detection in wavelength modulation spectroscopy (WMS). The lock-in detection of the harmonic signal is accomplished by studying the phase term of the inverse Fourier transform of the Fourier spectrum that corresponds to the harmonic signal. The mathematics and the corresponding simulation results are given for each procedure when applying the Fourier analysis method. The present work provides a detailed view of the WMS technique when applying the Fourier analysis method.

  4. Humidity independent mass spectrometry for gas phase chemical analysis via ambient proton transfer reaction. (United States)

    Zhu, Hongying; Huang, Guangming


    In this work, a humidity independent mass spectrometric method was developed for rapid analysis of gas phase chemicals. This method is based upon ambient proton transfer reaction between gas phase chemicals and charged water droplets, in a reaction chamber with nearly saturate humidity under atmospheric pressure. The humidity independent nature enables direct and rapid analysis of raw gas phase samples, avoiding time- and sample-consuming sample pretreatments in conventional mass spectrometry methods to control sample humidity. Acetone, benzene, toluene, ethylbenzene and meta-xylene were used to evaluate the analytical performance of present method. The limits of detection for benzene, toluene, ethylbenzene and meta-xylene are in the range of ∼0.1 to ∼0.3 ppbV; that of benzene is well below the present European Union permissible exposure limit for benzene vapor (5 μg m(-3), ∼1.44 ppbV), with linear ranges of approximately two orders of magnitude. The majority of the homemade device contains a stainless steel tube as reaction chamber and an ultrasonic humidifier as the source of charged water droplets, which makes this cheap device easy to assemble and facile to operate. In addition, potential application of this method was illustrated by the real time identification of raw gas phase chemicals released from plants at different physiological stages.

  5. Spectrum analysis of national greenhouse gas emission: a case study of Germany

    Energy Technology Data Exchange (ETDEWEB)

    Su, Meirong [Dongguan University of Technology, School of Chemistry and Environmental Engineering, Dongguan, Guangdong Province (China); Beijing Normal University, State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Beijing (China); Technical University of Munich, Strategic Landscape Planning and Management, Freising (Germany); Pauleit, Stephan; Xu, Chao [Technical University of Munich, Strategic Landscape Planning and Management, Freising (Germany)


    It is essential to abstract the key information from accounting results of greenhouse gas (GHG) emissions because it can provide a highly generalized and clear picture of GHG emissions, which is especially helpful for the public and policy makers. To clearly display the composition of GHG emissions, the concept of spectrum analysis is introduced and defined in this paper. Next, a multilayer analysis framework for national GHG emissions was proposed, which is represented by a pyramid of three layers: total emissions (first layer), emissions decomposed by gas type or sector (second layer), and emissions decomposed by both gas type and sector (third layer). Based on the analysis results from the first to third layers, the main compositional information of national GHG emissions was gradually summarized and analyzed until a spectrum of GHG emissions was acquired. The spectrum of GHG emissions displays the compositional structure of national GHG emissions in the different layers, which is helpful in identifying priorities for emissions reduction. A case study of Germany's GHG emissions during 1990-2012 was conducted, which indicated that CO{sub 2} and the energy sector were the biggest contributors to the total GHG emissions. Some suggestions for reducing GHG emissions are offered based on the obtained results. And the potential development of spectrum analysis for GHG emissions is also expected from aspects of both research and technology. (orig.)

  6. Application of dynamic set-pair analysis in coal and gas outburst prediction

    Institute of Scientific and Technical Information of China (English)

    CAO Qing-kui; LI Li-jie; YU Bing


    Analyzed the factors which affected the coal and gas outburst, then established the corresponding indicator system. Built a dynamic set-pair analysis prediction model which combined of Markov model and set-pair analysis model, and then it applied to coal and gas outburst prediction. Finally, compared the prediction results with the actual results.As provided a reference to the coalmine in safety decision-making. The research results indicate that there are four districts in high dangerous level, two districts in middle level and one district in low level, which consistent with the actual situation; the dynamic set-pair analysis model has a good effect in predicting coal and gas outburst. Especially in the continuous time intervals, according to the data of mined exploration and the connec-tion degree analysis, we can deduce the dangerous levels of unexplored districts from the historical data. In different districts, the relevant indicators can be adjusted accordingly, so as to enhance the accuracy of the prediction.

  7. Transient analysis importance for gas wells flow; A importancia da analise transiente no escoamento de pocos de gas

    Energy Technology Data Exchange (ETDEWEB)

    Lopes, Marcelo; Lorensini, Rodrigo V.; Lopes, Jansen M.; Sales, Antonio E.S. [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil)


    With the increase of Brazil's natural gas demand a program was instituted aiming to anticipate the national gas production. In this context, gas field development projects have been prioritized. Natural gas production in deep and ultra-deep water has the challenge to flow the production without the risk of hydrate formation and to ensure equipment and flow lines integrity. Flowing simulations indicate that temperatures in gas wells production systems may reach very low values, depending on the adopted initial conditions. This is a critical condition, since equipment and materials applied to the production system have temperature restrictions and provides a thermodynamic condition to hydrate formation. This paper shows the importance of unsteady-state studies and analyzes to predict unfavorable conditions, still during basic project phase, contributing to an appropriate definition of materials and equipment that attain the required conditions, and assisting in the elaboration of operational procedures that mitigate the problems identified during the simulations. (author)

  8. CFD Analysis of Gas Distributor in Packed Column--Prediction of Gas Flow and Effect of Tower Internals Geometry Structure

    Institute of Scientific and Technical Information of China (English)

    张吕鸿; 周海鹰; 李鑫钢; 杜玉萍


    Computational fluid dynamics (CFD) simulations were carried out on the gas flow patterns of twin-tangential annular deflector gas distributor in the absence of liquid flow in a packed column (6.4 m in diameter), and the gas flow field in the column was presented close to reality on the whole. Furthermore, after ame-lioration of this gas distributor frame, turbulence energy and turbulence energy dissipation rate were both decreased greatly.Simulation results showed that the flow pattern and the distribution of gas flow were strongly affected by the column bottom frame; the proper column bottom frame could decrease the flow pressure drop greatly. Multifold factors, such as the column bottom geometry structure and distributor structure which affects the distribution capacity, must be considered.

  9. Performance Analysis of Joule-Thomson Cooler Supplied with Gas Mixtures (United States)

    Piotrowska, A.; Chorowski, M.; Dorosz, P.


    Joule-Thomson (J-T) cryo-coolers working in closed cycles and supplied with gas mixtures are the subject of intensive research in different laboratories. The replacement of pure nitrogen by nitrogen-hydrocarbon mixtures allows to improve both thermodynamic parameters and economy of the refrigerators. It is possible to avoid high pressures in the heat exchanger and to use standard refrigeration compressor instead of gas bottles or high-pressure oil free compressor. Closed cycle and mixture filled Joule-Thomson cryogenic refrigerator providing 10-20 W of cooling power at temperature range 90-100 K has been designed and manufactured. Thermodynamic analysis including the optimization of the cryo-cooler mixture has been performed with ASPEN HYSYS software. The paper describes the design of the cryo-cooler and provides thermodynamic analysis of the system. The test results are presented and discussed.

  10. Kinetic analysis of photocatalytic oxidation of gas-phase formaldehyde over titanium dioxide. (United States)

    Liu, Hongmin; Lian, Zhiwei; Ye, Xiaojiang; Shangguan, Wenfeng


    Degradation of formaldehyde with different initial concentration over titanium dioxide was carried out in a photocatalytic reactor. Photocatalytic rates were well described by the simplified Langmuir-Hinshelwood model. The kinetic analysis shows that the apparent first-order reaction coefficient is lower and half-life of photocatalysis is longer for low concentration than for high concentration formaldehyde. A network formation model of the photocatalytic products was established. Experimental results and analysis demonstrate that carbon dioxide concentration and carbon monoxide concentration in gas phase vary exponentially with the illumination time and may be even higher than gas-phase formaldehyde concentration if there is much pre-adsorbed formaldehyde in adsorption equilibrium on catalysts before illumination. Carbon monoxide is found to be one of the by-products during formaldehyde photooxidation.

  11. Analysis of Mechanical Seals for High-Speed Centrifugal Gas Compressors

    Directory of Open Access Journals (Sweden)

    K.N. Nwaigwe


    Full Text Available A study aimed at seal selection efficiency for centrifugal pumps in the oil and gas industry is presented. A detailed analysis of mechanical seals in use in exploration and production activities of the oil and gas sector was undertaken. The approach of analysis was using seal design equations as mathematical models for simulating the performance of the mechanical seal. The results showed a mechanical seal with balance value of 0.5, an increased surface area between mating surfaces; provided with a flush system to enhance cooling and with seal face gap of 50 mm or less between the mating surfaces for minimal or zero leakage. The obtained results can aid the industries in seal selection and seal manufacturers in seal specifications.

  12. Life Cycle Greenhouse Gas Emissions from Electricity Generation: A Comparative Analysis of Australian Energy Sources

    Directory of Open Access Journals (Sweden)

    Robert G. Hynes


    Full Text Available Electricity generation is one of the major contributors to global greenhouse gas emissions. Transitioning the World’s energy economy to a lower carbon future will require significant investment in a variety of cleaner technologies, including renewables and nuclear power. In the short term, improving the efficiency of fossil fuel combustion in energy generation can provide an important contribution. Availability of life cycle GHG intensity data will allow decision-makers to move away from overly simplistic assertions about the relative merits of certain fuels, and focus on the complete picture, especially the critical roles of technology selection and application of best practice. This analysis compares the life-cycle greenhouse gas (GHG intensities per megawatt-hour (MWh of electricity produced for a range of Australian and other energy sources, including coal, conventional liquefied natural gas (LNG, coal seam gas LNG, nuclear and renewables, for the Australian export market. When Australian fossil fuels are exported to China, life cycle greenhouse gas emission intensity in electricity production depends to a significant degree on the technology used in combustion. LNG in general is less GHG intensive than black coal, but the gap is smaller for gas combusted in open cycle gas turbine plant (OCGT and for LNG derived from coal seam gas (CSG. On average, conventional LNG burned in a conventional OCGT plant is approximately 38% less GHG intensive over its life cycle than black coal burned in a sub-critical plant, per MWh of electricity produced. However, if OCGT LNG combustion is compared to the most efficient new ultra-supercritical coal power, the GHG intensity gap narrows considerably. Coal seam gas LNG is approximately 13–20% more GHG intensive across its life cycle, on a like-for like basis, than conventional LNG. Upstream fugitive emissions from CSG (assuming best practice gas extraction techniques do not materially alter the life cycle


    Directory of Open Access Journals (Sweden)

    R. INGWE


    Full Text Available The Nigerian Gas Master-Plan, Investment Opportunities, Challenges, Issues Affecting Power Sector: an Analysis. The objective of this article is to contribute towards understanding of the Nigerian Gas Master Plan (NGMP/Plan and its bifurcations with key socio-economic development factors. I applied the method of discourse to bring to being some points that have hitherto been unknown about the Master-plan and its inter-relationships and bifurcations. Elaborated here are the spectacular gains that have accrued to the Latin American country, Trinidad and Tobago, from its recent development of natural gas resources. This was considered suitable and significant here for highlighting that if such spectacular achievements could be realized from Trinidad and Tobago’s relatively smaller gas deposit (15.3 tcf, probable reserves (8.4 tcf, possible reserves (6.2 tcf would be by far greater considering Nigeria’s larger natural gas reserves (184 tcf wealth as earlier stated. I show that the Plan is well designed relevant to addressing Nigeria’s current development needs generally. It presents potentials for stimulating Nigeria’s economic growth by harnessing the country’s abundant natural gas reserves. The Plan enumerates/ elaborates huge investment opportunities. Some challenges likely to be faced in the implementation/management of the Plan are already being surmounted as recent reports show that some of its key investments have been realized and the required infrastructure are being provided. Regarding the issues in the Master-plan that are likely to affect and are affecting Nigeria’s power sector development, I reckon that they are mostly positive factors due to the way the plan promises to stimulate electricity generation in our country.

  14. Differentiation of Bacillus anthracis from Bacillus cereus by gas chromatographic whole-cell fatty acid analysis.


    Lawrence, D.; Heitefuss, S; Seifert, H S


    Three strains of Bacillus anthracis and seven strains of Bacillus cereus were grown on complex medium and on synthetic medium. Gas chromatographic analysis of whole-cell fatty acids of strains grown on complex medium gave nearly identical fatty acid patterns. Fatty acid patterns of strains grown on synthetic medium showed a high content of branched-chain fatty acids. Significant differences between the fatty acid patterns of the two species were found. Odd iso/anteiso fatty acid ratios were a...

  15. Influence of ripening stages of tomatoes in the analysis of pesticides by gas chromatography


    Sousa,Flaviane A. de; Neves,Antônio A.; Maria Eliana L. R. Queiroz; Heleno,Fernanda F.; Teófilo, Reinaldo F.; Pinho,Gevany P.


    Some parameters of tomato fruits ripening such as color, pH, ºBrix, acidity and lycopene and β-carotene content were evaluated during the ripening of fruits. Five pesticides were quantified in organic extracts derived from tomatoes at different stages of maturation. The solid-liquid extraction technique with partition at low temperature (SLE-PLT) was used to obtain these organic extracts. The matrix effect of tomato was calculated from the results of analysis by gas chromatography with e...

  16. Nanoelectromechanical Resonator Arrays for Ultrafast, Gas-Phase Chromatographic Chemical Analysis


    Li, Mo; Myers, E. B.; Tang, H. X.; Aldridge, S. J.; McCaig, H. C.; Whiting, J. J.; Simonson, R. J.; Lewis, N. S.; Roukes, M. L.


    Miniaturized gas chromatography (GC) systems can provide fast, quantitative analysis of chemical vapors in an ultrasmall package. We describe a chemical sensor technology based on resonant nanoelectromechanical systems (NEMS) mass detectors that provides the speed, sensitivity, specificity, and size required by the microscale GC paradigm. Such NEMS sensors have demonstrated detection of subparts per billion (ppb) concentrations of a phosphonate analyte. By combining two channels of NEMS detec...

  17. H2S Analysis in Biological Samples Using Gas Chromatography with Sulfur Chemiluminescence Detection


    Vitvitsky, Victor; Banerjee, Ruma


    Hydrogen sulfide (H2S) is a metabolite and signaling molecule in biological tissues that regulates many physiological processes. Reliable and sensitive methods for H2S analysis are necessary for a better understanding of H2S biology and for the pharmacological modulation of H2S levels in vivo. In this chapter, we describe the use of gas chromatography coupled to sulfur chemiluminescence detection to measure the rates of H2S production and degradation by tissue homogenates at physiologically r...

  18. Analysis of 23 polycyclic aromatic hydrocarbons in smokeless tobacco by gas chromatography-mass spectrometry


    Stepanov, Irina; Villalta, Peter W.; Knezevich, Aleksandar; Jensen, Joni; Hatsukami, Dorothy; Hecht, Stephen S.


    Smokeless tobacco contains 28 known carcinogens and causes precancerous oral lesions and oral and pancreatic cancer. A recent study conducted by our research team identified 8 different polycyclic aromatic hydrocarbons (PAH) in U.S. moist snuff, encouraging further investigations of this group of toxicants and carcinogens in smokeless tobacco products. In this study, we developed a gas chromatography-mass spectrometry method that allows simultaneous analysis of 23 various PAH in smokeless tob...

  19. Preliminary Failure Modes and Effects Analysis of the US Massive Gas Injection Disruption Mitigation System Design

    Energy Technology Data Exchange (ETDEWEB)

    Lee C. Cadwallader


    This report presents the results of a preliminary failure modes and effects analysis (FMEA) of a candidate design for the ITER Disruption Mitigation System. This candidate is the Massive Gas Injection System that provides machine protection in a plasma disruption event. The FMEA was quantified with “generic” component failure rate data as well as some data calculated from operating facilities, and the failure events were ranked for their criticality to system operation.

  20. Time and Frequency Domain Identification and Analysis of a Gas Turbine Engine


    Boaghe, O.M.; S. A. Billings; L. M. Li; Fleming, P J; Liu, J


    The NARMAX (Nonlinear Auto Regressive Moving Average model with eXogenous inputs) approach has been used to analyse the dynamics of a gas turbine engine. The fuel flow-shaft speed relationship is analysed by identifying both time and frequency domain models of the system. The frequency domain analysis is studied by mapping the discrete-time NARMAX models into the Generalised Frequency Response Functions (GFRF's) to reveal the nonlinear coupling between the various input spectral components an...

  1. Analysis of Indirectly Fired Gas Turbine for Wet Biomass Fuels Based on commercial micro gas turbine data

    DEFF Research Database (Denmark)

    Elmegaard, Brian; Qvale, Einar Bjørn


    fueled by dry biomass assuming negligible pressure loss in the heat exchanger and the combustion chamber, the IFGT fueled with wet biomass (Wet IFGT) assuming no pressure losses, and finally both the Simple and the Wet IFGT incorporating typical data for pressure losses of commercially available micro......The results of a study of a novel gas turbine configuration is being presented. In this power plant, an Indirectly Fired Gas Turbine (IFGT), is being fueled with very wet biomass. The exhaust gas is being used to dry the biomass, but instead of striving to recover as much as possible of the thermal...

  2. An analysis of flaring and venting activity in the Alberta upstream oil and gas industry. (United States)

    Johnson, Matthew R; Coderre, Adam R


    Alberta, Canada, is an important global producer of petroleum resources. In association with this production, large amounts of gas (1.14 billion m3 in 2008) are flared or vented. Although the amount of flaring and venting has been measurably reduced since 2002, data from 2005 reveal sharp increases in venting, which have important implications in terms of resource conservation and greenhouse gas emissions (which exceeded 8 million tonnes of carbon dioxide equivalent in 2008). With use of extensive monthly production data for 18,203 active batteries spanning the years 2002-2008 obtained in close cooperation with the Alberta Energy Resources Conservation Board, a detailed analysis has been completed to examine activity patterns of flaring and venting and reasons behind these trends in the Alberta upstream oil and gas industry. In any given year, approximately 6000 batteries reported flaring and/or venting, but the distribution of volumes flared and vented at individual sites was highly skewed, such that small numbers of sites handled large fractions of the total gas flaring and venting in the Province. Examination of month-to-month volume variability at individual sites, cast in terms of a nominal turndown ratio that would be required for a compressor to capture that gas and direct it into a pipeline, further revealed that volumes at a majority of sites were reasonably stable and there was no evidence that larger or more stable sites had been preferentially reduced, leaving potential barriers to future mitigation. Through linking of geospatial data with production data coupled with additional statistical analysis, the 31.2% increase in venting volumes since 2005 was revealed to be predominantly associated with increased production of heavier oils and bitumen in the Lloydminster region of the Province. Overall, the data suggest that quite significant reductions in flaring and venting could be realized by seeking mitigation solutions for only the largest batteries in

  3. Techno-economic Analysis of Distributed Hydrogen Production from Natural Gas

    Institute of Scientific and Technical Information of China (English)

    LUK Ho Ting; LEI Ho Man; NG Wai Yee; JU Yihan; LAM Koon Fung


    It is well established that hydrogen has the potential to make a significant contribution to the world energy production. In U.S., majority of hydrogen production plants implement steam methane reforming (SMR) for centralized hydrogen production. However, there is a wide lack of agreement on the nascent stage of using hydro- gen as fuel in vehicles industry because of the difficulty in delivery and storage. By performing technological and economic analysis, this work aims to establish the most feasible hydrogen production pathway for automotives in near future. From the evaluation, processes such as thermal cracking of ammonia and centralized hydrogen production followed by bulk delivery are eliminated while on-site steam reforming of methanol and natural gas are the most technologically feasible options. These two processes are further evaluated by comprehensive economic analysis. The results showed that the steam reforming (SR) of natural gas has a shorter payback time and a higher return on investment (ROI) and internal rate of return (IRR). Sensitivity analysis has also been constructed to evaluate the impact of variables like NG feedstock price, capital of investment and operating capacity factor on the overall production cost of hydrogen. Based on this study, natural gas is prompted to be the most economically and technologically available raw material for short-term hydrogen production before the transition to renewable energy source such as solar energy, biomass and wind power.

  4. Time series analysis applied to construct US natural gas price functions for groups of states

    Energy Technology Data Exchange (ETDEWEB)

    Kalashnikov, V.V. [Departamento de Ingenieria Industrial y de Sistemas, Tecnologico de Monterrey, Av. Eugenio Garza Sada 2501 Sur, Col. Tecnologico, Monterrey, Nuevo Leon, 64849 (Mexico); Matis, T.I. [Deparment of Industrial Engineering, Texas Tech University, 2500 Broadway, Lubbock, TX 79409 (United States); Perez-Valdes, G.A. [Departamento de Ingenieria Industrial y de Sistemas, Tecnologico de Monterrey, Av. Eugenio Garza Sada 2501 Sur, Col. Tecnologico, Monterrey, Nuevo Leon, 64849 (Mexico); Deparment of Industrial Engineering, Texas Tech University, 2500 Broadway, Lubbock, TX 79409 (United States)


    The study of natural gas markets took a considerably new direction after the liberalization of the natural gas markets during the early 1990s. As a result, several problems and research opportunities arose for those studying the natural gas supply chain, particularly the marketing operations. Consequently, various studies have been undertaken about the econometrics of natural gas. Several models have been developed and used for different purposes, from descriptive analysis to practical applications such as price and consumption forecasting. In this work, we address the problem of finding a pooled regression formula relating the monthly figures of price and consumption volumes for each state of the United States during the last twenty years. The model thus obtained is used as the basis for the development of two methods aimed at classifying the states into groups sharing a similar price/consumption relationship: a dendrogram application, and an heuristic algorithm. The details and further applications of these grouping techniques are discussed, along with the ultimate purpose of using this pooled regression model to validate data employed in the stochastic optimization problem studied by the authors. (author)

  5. Sensitivity Analysis of Gas Production from Class 2 and Class 3 Hydrate Deposits

    Energy Technology Data Exchange (ETDEWEB)

    Reagan, Matthew; Moridis, George; Zhang, Keni


    Gas hydrates are solid crystalline compounds in which gas molecules are lodged within the lattices of an ice-like crystalline solid. The vast quantities of hydrocarbon gases trapped in hydrate formations in the permafrost and in deep ocean sediments may constitute a new and promising energy source. Class 2 hydrate deposits are characterized by a Hydrate-Bearing Layer (HBL) that is underlain by a saturated zone of mobile water. Class 3 hydrate deposits are characterized by an isolated Hydrate-Bearing Layer (HBL) that is not in contact with any hydrate-free zone of mobile fluids. Both classes of deposits have been shown to be good candidates for exploitation in earlier studies of gas production via vertical well designs - in this study we extend the analysis to include systems with varying porosity, anisotropy, well spacing, and the presence of permeable boundaries. For Class 2 deposits, the results show that production rate and efficiency depend strongly on formation porosity, have a mild dependence on formation anisotropy, and that tighter well spacing produces gas at higher rates over shorter time periods. For Class 3 deposits, production rates and efficiency also depend significantly on formation porosity, are impacted negatively by anisotropy, and production rates may be larger, over longer times, for well configurations that use a greater well spacing. Finally, we performed preliminary calculations to assess a worst-case scenario for permeable system boundaries, and found that the efficiency of depressurization-based production strategies are compromised by migration of fluids from outside the system.

  6. Nanoelectromechanical resonator arrays for ultrafast, gas-phase chromatographic chemical analysis. (United States)

    Li, Mo; Myers, E B; Tang, H X; Aldridge, S J; McCaig, H C; Whiting, J J; Simonson, R J; Lewis, N S; Roukes, M L


    Miniaturized gas chromatography (GC) systems can provide fast, quantitative analysis of chemical vapors in an ultrasmall package. We describe a chemical sensor technology based on resonant nanoelectromechanical systems (NEMS) mass detectors that provides the speed, sensitivity, specificity, and size required by the microscale GC paradigm. Such NEMS sensors have demonstrated detection of subparts per billion (ppb) concentrations of a phosphonate analyte. By combining two channels of NEMS detection with an ultrafast GC front-end, chromatographic analysis of 13 chemicals was performed within a 5 s time window.

  7. Blade loss transient dynamics analysis, volume 1. Task 1: Survey and perspective. [aircraft gas turbine engines (United States)

    Gallardo, V. C.; Gaffney, E. F.; Bach, L. J.; Stallone, M. J.


    An analytical technique was developed to predict the behavior of a rotor system subjected to sudden unbalance. The technique is implemented in the Turbine Engine Transient Rotor Analysis (TETRA) computer program using the component element method. The analysis was particularly aimed toward blade-loss phenomena in gas turbine engines. A dual-rotor, casing, and pylon structure can be modeled by the computer program. Blade tip rubs, Coriolis forces, and mechanical clearances are included. The analytical system was verified by modeling and simulating actual test conditions for a rig test as well as a full-engine, blade-release demonstration.

  8. Pseudo-absolute quantitative analysis using gas chromatography - Vacuum ultraviolet spectroscopy - A tutorial. (United States)

    Bai, Ling; Smuts, Jonathan; Walsh, Phillip; Qiu, Changling; McNair, Harold M; Schug, Kevin A


    The vacuum ultraviolet detector (VUV) is a new non-destructive mass sensitive detector for gas chromatography that continuously and rapidly collects full wavelength range absorption between 120 and 240 nm. In addition to conventional methods of quantification (internal and external standard), gas chromatography - vacuum ultraviolet spectroscopy has the potential for pseudo-absolute quantification of analytes based on pre-recorded cross sections (well-defined absorptivity across the 120-240 nm wavelength range recorded by the detector) without the need for traditional calibration. The pseudo-absolute method was used in this research to experimentally evaluate the sources of sample loss and gain associated with sample introduction into a typical gas chromatograph. Standard samples of benzene and natural gas were used to assess precision and accuracy for the analysis of liquid and gaseous samples, respectively, based on the amount of analyte loaded on-column. Results indicate that injection volume, split ratio, and sampling times for splitless analysis can all contribute to inaccurate, yet precise sample introduction. For instance, an autosampler can very reproducibly inject a designated volume, but there are significant systematic errors (here, a consistently larger volume than that designated) in the actual volume introduced. The pseudo-absolute quantification capability of the vacuum ultraviolet detector provides a new means for carrying out system performance checks and potentially for solving challenging quantitative analytical problems. For practical purposes, an internal standardized approach to normalize systematic errors can be used to perform quantitative analysis with the pseudo-absolute method.

  9. Analysis and quantitation of volatile organic compounds emitted from plastics used in museum construction by evolved gas analysis-gas chromatography-mass spectrometry. (United States)

    Samide, Michael J; Smith, Gregory D


    Construction materials used in museums for the display, storage, and transportation of artwork must be assessed for their tendency to emit harmful pollution that could potentially damage cultural treasures. Traditionally, a subjective metals corrosion test known as the Oddy test has been widely utilized in museums for this purpose. To augment the Oddy test, an instrumental sampling approach based on evolved gas analysis (EGA) coupled to gas chromatography (GC) with mass spectral (MS) detection has been implemented for the first time to qualitatively identify off-gassed pollutants under specific conditions. This approach is compared to other instrumental methods reported in the literature. This novel application of the EGA sampling technique yields several benefits over traditional testing, including rapidity, high sensitivity, and broad detectability of volatile organic compounds (VOCs). Furthermore, unlike other reported instrumental approaches, the EGA method was used to determine quantitatively the amount of VOCs emitted by acetate resins and polyurethane foams under specific conditions using both an external calibration method as well as surrogate response factors. EGA was successfully employed to rapidly characterize emissions from 12 types of common plastics. This analysis is advocated as a rapid pre-screening method to rule out poorly performing materials prior to investing time and energy in Oddy testing. The approach is also useful for rapid, routine testing of construction materials previously vetted by traditional testing, but which may experience detrimental formulation changes over time. As an example, a case study on batch re-orders of rigid expanded poly(vinyl chloride) board stock is presented.

  10. Evaluation of three gas chromatography and two direct mass spectrometry techniques for aroma analysis of dried red bell peppers

    NARCIS (Netherlands)

    Ruth, van S.M.; Boscaini, E.; Mayr, D.; Pugh, J.; Posthumus, M.A.


    Three gas chromatography methods and two direct mass spectrometry techniques were compared for the analysis of the aroma of rehydrated diced red bell peppers. Gas chromatography methods included systems with olfactometry detection (GC-O), flame ionisation detection (GC-FID) and mass spectrometry (GC

  11. Use of hydrogen as a carrier gas for the analysis of steroids with anabolic activity by gas chromatography-mass spectrometry. (United States)

    Muñoz-Guerra, J A; Prado, P; García-Tenorio, S Vargas


    Due to the impact in the media and the requirements of sensitivity and robustness, the detection of the misuse of forbidden substances in sports is a really challenging area for analytical chemistry, where any study focused on enhancing the performance of the analytical methods will be of great interest. The aim of the present study was to evaluate the usefulness of using hydrogen instead of helium as a carrier gas for the analysis of anabolic steroids by gas chromatography-mass spectrometry with electron ionization. There are several drawbacks related with the use of helium as a carrier gas: it is expensive, is a non-renewable resource, and has limited availability in many parts of the world. In contrast, hydrogen is readily available using a hydrogen generator or high-pressure bottled gas, and allows a faster analysis without loss of efficiency; nevertheless it should not be forgotten that due to its explosiveness hydrogen must be handled with caution. Throughout the study the impact of the change of the carrier gas will be evaluated in terms of: performance of the chromatographic system, saving of time and money, impact on the high vacuum in the analyzer, changes in the fragmentation behaviour of the analytes, and finally consequences for the limits of detection achieved with the method.

  12. Propagation of uncertainty and sensitivity analysis in an integral oil-gas plume model

    KAUST Repository

    Wang, Shitao


    Polynomial Chaos expansions are used to analyze uncertainties in an integral oil-gas plume model simulating the Deepwater Horizon oil spill. The study focuses on six uncertain input parameters—two entrainment parameters, the gas to oil ratio, two parameters associated with the droplet-size distribution, and the flow rate—that impact the model\\'s estimates of the plume\\'s trap and peel heights, and of its various gas fluxes. The ranges of the uncertain inputs were determined by experimental data. Ensemble calculations were performed to construct polynomial chaos-based surrogates that describe the variations in the outputs due to variations in the uncertain inputs. The surrogates were then used to estimate reliably the statistics of the model outputs, and to perform an analysis of variance. Two experiments were performed to study the impacts of high and low flow rate uncertainties. The analysis shows that in the former case the flow rate is the largest contributor to output uncertainties, whereas in the latter case, with the uncertainty range constrained by aposteriori analyses, the flow rate\\'s contribution becomes negligible. The trap and peel heights uncertainties are then mainly due to uncertainties in the 95% percentile of the droplet size and in the entrainment parameters.

  13. Analysis of an activated-carbon sorption compressor operating with gas mixtures (United States)

    Tzabar, N.; Grossman, G.


    Sorption compressors elevate the pressure of gases and can provide a more or less continuous mass flow. Unlike mechanical compressors, sorption compressors have no moving parts, and therefore do not emit vibrations and are highly reliable. There exist different sorption compressors for different operating conditions and various gases. However, there are no published reports of sorption compressors for mixed gases. Such compressors, among other applications, may drive mixed-refrigerant Joule-Thomson cryocoolers. The adsorption of mixed gases is usually investigated under steady conditions, mainly for storage and separation processes. However, the sorption process in a compressor goes through varying states and mass changes; therefore, it differs from the common mixed gases adsorption applications. In this research a numerical analysis for mixed gas sorption compressors is developed, based on pure gas adsorption characteristics and the ideal adsorbed solution theory. Two pure gas adsorption models are used for calculating the conditions of the adsorbed phase: Langmuir and Sips; and the Peng-Robinson equation of state is used to calculate the conditions of the vapor phase. Two mixtures are investigated; nitrogen-methane and nitrogen-ethane. Finally, the analysis is verified against experimental results. This research provides initiatory observation for mixed gases sorption compressor in which each component is differently adsorbed.

  14. Optimal q-homotopy analysis method for time-space fractional gas dynamics equation (United States)

    Saad, K. M.; AL-Shareef, E. H.; Mohamed, Mohamed S.; Yang, Xiao-Jun


    It is well known that the homotopy analysis method is one of the most efficient methods for obtaining analytical or approximate semi-analytical solutions of both linear and non-linear partial differential equations. A more general form of HAM is introduced in this paper, which is called Optimal q-Homotopy Analysis Method (Oq-HAM). It has better convergence properties as compared with the usual HAM, due to the presence of fraction factor associated with the solution. The convergence of q-HAM is studied in details elsewhere (M.A. El-Tawil, Int. J. Contemp. Math. Sci. 8, 481 (2013)). Oq-HAM is applied to the non-linear homogeneous and non-homogeneous time and space fractional gas dynamics equations with initial condition. An optimal convergence region is determined through the residual error. By minimizing the square residual error, the optimal convergence control parameters can be obtained. The accuracy and efficiency of the proposed method are verified by comparison with the exact solution of the fractional gas dynamics equation. Also, it is shown that the Oq-HAM for the fractional gas dynamics equation is equivalent to the exact solution. We obtain graphical representations of the solutions using MATHEMATICA.

  15. Gas chromatography-vacuum ultraviolet spectroscopy for analysis of fatty acid methyl esters. (United States)

    Fan, Hui; Smuts, Jonathan; Bai, Ling; Walsh, Phillip; Armstrong, Daniel W; Schug, Kevin A


    A new vacuum ultraviolet (VUV) detector for gas chromatography was recently developed and applied to fatty acid methyl ester (FAME) analysis. VUV detection features full spectral acquisition in a wavelength range of 115-240nm, where virtually all chemical species absorb. VUV absorption spectra of 37 FAMEs, including saturated, monounsaturated, and polyunsaturated types were recorded. Unsaturated FAMEs show significantly different gas phase absorption profiles than saturated ones, and these classes can be easily distinguished with the VUV detector. Another advantage includes differentiating cis/trans-isomeric FAMEs (e.g. oleic acid methyl ester and linoleic acid methyl ester isomers) and the ability to use VUV data analysis software for deconvolution of co-eluting signals. As a universal detector, VUV also provides high specificity, sensitivity, and a fast data acquisition rate, making it a powerful tool for fatty acid screening when combined with gas chromatography. The fatty acid profile of several food oil samples (olive, canola, vegetable, corn, sunflower and peanut oils) were analyzed in this study to demonstrate applicability to real world samples.

  16. Propagation of uncertainty and sensitivity analysis in an integral oil-gas plume model (United States)

    Wang, Shitao; Iskandarani, Mohamed; Srinivasan, Ashwanth; Thacker, W. Carlisle; Winokur, Justin; Knio, Omar M.


    Polynomial Chaos expansions are used to analyze uncertainties in an integral oil-gas plume model simulating the Deepwater Horizon oil spill. The study focuses on six uncertain input parameters—two entrainment parameters, the gas to oil ratio, two parameters associated with the droplet-size distribution, and the flow rate—that impact the model's estimates of the plume's trap and peel heights, and of its various gas fluxes. The ranges of the uncertain inputs were determined by experimental data. Ensemble calculations were performed to construct polynomial chaos-based surrogates that describe the variations in the outputs due to variations in the uncertain inputs. The surrogates were then used to estimate reliably the statistics of the model outputs, and to perform an analysis of variance. Two experiments were performed to study the impacts of high and low flow rate uncertainties. The analysis shows that in the former case the flow rate is the largest contributor to output uncertainties, whereas in the latter case, with the uncertainty range constrained by aposteriori analyses, the flow rate's contribution becomes negligible. The trap and peel heights uncertainties are then mainly due to uncertainties in the 95% percentile of the droplet size and in the entrainment parameters.

  17. Wavelet analysis of pressure fluctuation signals in a gas-solid fluidized bed

    Institute of Scientific and Technical Information of China (English)

    甄玲; 王晓萍; 黄海; 陈伯川; 黄春燕


    It has been shown that much dynamic information is hidden in the pressure fluctuation signals of a gas-solid fluidized bed. Unfortunately, due to the random and capricious nature of this signal, it is hard to realize reliable analysis using traditional signal processing methods such as statistical analysis or spectral analysis, which is done in Fourier domain. Information in different frequency band can be extracted by using wavelet analysis. On the evidence of the composition of the pressure fluctuation signals, energy of low frequency (ELF) is proposed to show the transition of fluidized regimes from bubbling fluidization to turbulent fluidization. Plots are presented to describe the fluidized bed's evolution to help identify the state of different flow regimes and provide a characteristic curve to identify the fluidized status effectively and reliably.

  18. Discrimination of honeys using colorimetric sensor arrays, sensory analysis and gas chromatography techniques. (United States)

    Tahir, Haroon Elrasheid; Xiaobo, Zou; Xiaowei, Huang; Jiyong, Shi; Mariod, Abdalbasit Adam


    Aroma profiles of six honey varieties of different botanical origins were investigated using colorimetric sensor array, gas chromatography-mass spectrometry (GC-MS) and descriptive sensory analysis. Fifty-eight aroma compounds were identified, including 2 norisoprenoids, 5 hydrocarbons, 4 terpenes, 6 phenols, 7 ketones, 9 acids, 12 aldehydes and 13 alcohols. Twenty abundant or active compounds were chosen as key compounds to characterize honey aroma. Discrimination of the honeys was subsequently implemented using multivariate analysis, including hierarchical clustering analysis (HCA) and principal component analysis (PCA). Honeys of the same botanical origin were grouped together in the PCA score plot and HCA dendrogram. SPME-GC/MS and colorimetric sensor array were able to discriminate the honeys effectively with the advantages of being rapid, simple and low-cost. Moreover, partial least squares regression (PLSR) was applied to indicate the relationship between sensory descriptors and aroma compounds.

  19. Numerical analysis of excimer laser-induced breakdown of Kr gas (United States)

    Hamam, Kholoud A.; Elsayed, Khaled A.; Gamal, Yosr E. E.


    The present paper displays a numerical study on the role of electron dynamics in relation to the dependence of the threshold intensity on the pressure in the breakdown of gases by laser radiation. The analysis aimed to find out the origin of the steep slope observed in the measurements of threshold intensity against gas pressure in the breakdown of Kr induced by an excimer laser source (Opt. Commun. 13:66-68, 1). The experiment was carried out using wavelength 248 nm and pulse width of 18 ns for a gas pressure range 4.5-300 torr. The investigation centered on an adaptation of our previously developed electron cascade model given in Evans and Gamal (J. Phys. D Appl. Phys. 13:1447-1458, 2). This model solves numerically a time-dependent energy equation simultaneously with a set of rate equations that describe the change of the population of the formed excited states. The modifications introduced into the model the realistic structure of the krypton gas atom as well as electron diffusion as a loss process to inspect the experimentally tested low-pressure regime. A computer program is undertaken to determine the breakdown threshold intensity as a function of gas pressure. Reasonable agreement is obtained between the calculated thresholds and measured ones, corresponding to the examined pressure range. This agreement validates the applicability of the model. The relationship between the role of the physical mechanisms and gas pressure is studied by analyzing the EEDF and its parameters at selected pressure values that cover the experimentally tested range. The result of this study clarified that electron diffusion out of the focal region is responsible for the steep slope of the threshold intensities for pressures values showed non-Maxwellian distribution as well as determined the time and energy region at which breakdown is formed.

  20. Numeric Design and Performance Analysis of Solid Oxide Fuel Cell -- Gas Turbine Hybrids on Aircraft (United States)

    Hovakimyan, Gevorg

    The aircraft industry benefits greatly from small improvements in aircraft component design. One possible area of improvement is in the Auxiliary Power Unit (APU). Modern aircraft APUs are gas turbines located in the tail section of the aircraft that generate additional power when needed. Unfortunately the efficiency of modern aircraft APUs is low. Solid Oxide Fuel Cell/Gas Turbine (SOFC/GT) hybrids are one possible alternative for replacing modern gas turbine APUs. This thesis investigates the feasibility of replacing conventional gas turbine APUs with SOFC/GT APUs on aircraft. An SOFC/GT design algorithm was created in order to determine the specifications of an SOFC/GT APU. The design algorithm is comprised of several integrated modules which together model the characteristics of each component of the SOFC/GT system. Given certain overall inputs, through numerical analysis, the algorithm produces an SOFC/GT APU, optimized for specific power and efficiency, capable of performing to the required specifications. The SOFC/GT design is then input into a previously developed quasi-dynamic SOFC/GT model to determine its load following capabilities over an aircraft flight cycle. Finally an aircraft range study is conducted to determine the feasibility of the SOFC/GT APU as a replacement for the conventional gas turbine APU. The design results show that SOFC/GT APUs have lower specific power than GT systems, but have much higher efficiencies. Moreover, the dynamic simulation results show that SOFC/GT APUs are capable of following modern flight loads. Finally, the range study determined that SOFC/GT APUs are more attractive over conventional APUs for longer range aircraft.

  1. Thermoeconomic and exegetic analysis of a cogeneration proposal by using natural gas in breweries; Analise termoeconomica e exergetica de uma proposta de cogeracao usando gas natural em cervejarias

    Energy Technology Data Exchange (ETDEWEB)

    Gallego, Antonio Garrido; Martins, Gilberto [Universidade Metodista de Piracicaba (UNIMEP), Santa Barbara do Oeste, SP (Brazil). Faculdade de Engenharia Mecanica e de Producao]. E-mail:;; Nebra, Silvia Azucena [Universidade Estadual de Campinas, SP (Brazil). Faculdade de Engenharia Mecanica]. E-mail:


    In this work the thermo economic method is used for analysis of the cost distribution in a cogeneration power plant proposed for a brewery in the Campinas - state of Sao Paulo, Brazil. The thermal process energy demands were considered for beer production in 1997. The proposed cogeneration system consists of two gas turbines with recovering boiler and ammonium compression cooling system. The present power generation configuration and the cogeneration proposed performance were simulated in a monthly basis, considering the month steam and refrigeration requests. The gas turbines were simulated considering the nominal load and the energy surplus sold to the concessionaire.

  2. Ion beam analysis of gas turbine blades: evaluation of refurbishment quality

    Indian Academy of Sciences (India)

    O Kakuee; V Fathollahi; P Oliaiy; D Agha-Aligol; M Lamehi-Rachti


    Refurbishment of hot components of gas turbines damaged in the harsh working environments is necessary to increase their lifetime. Scanning proton microscopy was employed to evaluate the quality of refurbishment process of gas turbine blades. Distribution patterns of different elements were observed in the polished cross-sections of turbine blade samples by proton microbeam. In the cross-sections of refurbished and used samples, distinct regions were identified corresponding to the base superalloy, original protection layer and applied coating for refurbishment. The elemental composition of each of these regions was measured by Micro-PIXE analysis. Inhomogeneous and high content of Si as well as undesired light elements were observed in the cross-sections of refurbished samples, indicating imperfections in the refurbishment process.

  3. Numerical analysis of experiments with gas injection into liquid metal coolant (United States)

    Usov, E. V.; Lobanov, P. D.; Pribaturin, N. A.; Mosunova, N. A.; Chuhno, V. I.; Kutlimetov, A. E.


    Presented paper contains results of a numerical analysis of experiments with gas injection in water and liquid metal which have been performed at the Institute of Thermophysics Russian Academy of Science (IT RAS). Obtained experimental data are very important to predict processes that take place in the BREST-type reactor during the hypothetical accident with damage of the steam generator tubes, and may be used as a benchmark to validate thermo-hydraulic codes. Detailed description of models to simulate transport of gas phase in a vertical liquid column is presented in a current paper. Two-fluid model with closing relation for wall friction and interface friction coefficients was used to simulate processes which take place in a liquid during injection of gaseous phase. It has being shown that proposed models allow obtaining a good agreement between experimental data and calculation results.

  4. An analysis of seasonality fluctuations in the oil and gas stock returns

    Directory of Open Access Journals (Sweden)

    Muhammad Surajo Sanusi


    Full Text Available This paper investigates the existence of seasonality anomalies in the stock returns of the oil and gas companies on the London Stock Exchange. It employs F-test, Kruskal–Wallis and Tukey tests to examine days-of-the-week effect. Generalised autoregressive conditional heteroscedasticity specification was also employed to investigate both the days-of-the-week and months-of-the-year effects. The analysis had been extended to some key FTSE indices. Our results showed no evidence of any regularity or seasonal fluctuation in the oil and gas stock returns despite the seasonal changes of demand in the companies’ products. However, January effect has been observed in FTSE All Share and FTSE 100 indices.

  5. Upgrades to the Radiochemistry Analysis of Gas Samples (RAGS) diagnostic at the National Ignition Facility (United States)

    Jedlovec, Donald; Christensen, Kim; Velsko, Carol; Cassata, Bill; Stoeffl, Wolfgang; Shaughnessy, Dawn; Lugten, John; Golod, Tony; Massey, Warren


    The Radiochemical Analysis of Gaseous Samples (RAGS) diagnostic apparatus operates at the National Ignition Facility (NIF). At the NIF, xenon is injected into the target chamber as a tracer, used as an analyte in the NIF targets, and generated as a fission product from 14 MeV neutron fission of depleted uranium contained in the NIF hohlraum. Following a NIF shot, the RAGS apparatus used to collect the gas from the NIF target chamber and then to cryogenically fractionate xenon gas. Radio-xenon and other activation products are collected and counted via gamma spectrometry, with the results used to determine critical physics parameters including: capsule areal density, fuel-ablator mix, and nuclear cross sections.

  6. Selective chlorine dioxide determination using gas-diffusion flow injection analysis with chemiluminescent detection

    Energy Technology Data Exchange (ETDEWEB)

    Hollowell, D.A.; Gord, J.R.; Gordon, G.; Pacey, G.E.


    An automated chemiluminescent technique has been developed utilizing the advantages of gas-diffusion flow injection analysis. A gas-diffusion membrane separates the donor (sampling) stream from the acceptor (detecting) stream and removes ionic interferences. A novel chemiluminescence flow-through detector cell is used to measure the concentration of chlorine dioxide as a function of the intensity of the chemiluminescence produced from its reaction with luminol. The chemiluminescent reagent merges with the analyte directly in front of the photomultiplier tube in order to maximize the sensitivity of the system. The detection limit for chlorine dioxide is approximately 5 ppb. The method is over 1500 times more selective for chlorine dioxide than for chlorine on a mole basis. This method eliminates interference from iron and manganese compounds, as well as other oxychlorinated compounds such as chlorite ion and chlorate ion.

  7. Selective determination of chlorine dioxide using gas diffusion flow injection analysis

    Energy Technology Data Exchange (ETDEWEB)

    Hollowell, D.A.; Pacey, G.E.; Gordon, G.


    An automated absorbance technique for the determination of aqueous chlorine dioxide has been developed by utilizing gas diffusion flow injection analysis. A gas diffusion membrane is used to separate the donor (sampling) stream from the acceptor (detecting) stream. The absorbance of chlorine dioxide is monitored at 359 nm. The first method uses distilled water as the acceptor stream and gives a detection limit of 0.25 mg/L chlorine dioxide. This system is over 550 times more selective for chlorine dioxide than chlorine. To further minimize chlorine interference, oxalic acid is used in the acceptor stream. The detection limit for this system is 0.45 mg/L chlorine dioxide. This second system is over 5400 times more selective for chlorine dioxide than chlorine. Both methods show excellent selectivity for chlorine dioxide over iron and manganese compounds, as well as other oxychlorinated compounds such as chlorite and perchlorate ions. 18 references, 7 figures, 3 tables.

  8. Decision analysis for the exploration of gas reserves: merging todim and thor

    Directory of Open Access Journals (Sweden)

    Carlos Francisco Simões Gomes


    Full Text Available This article approaches the problem of selecting the non-dominated alternative for the destination of the natural gas reserves in the Mexilhão field in the Santos Basin, Brazil. Major aims of the case study reported here were to create a mechanism for assisting in the process of analyzing and selecting the best options for the destination of natural gas, and to enable the decision agent to choose the investment options best aligned to the expectations and objectives observed in the company strategies. The decision analysis employed in the study made use of the TODIM method and the THOR multicriteria decision support system. The application of both demonstrated that a decision analytic framework can be extremely useful when recommending options for upstream projects, owing to the fact that it can clearly identify the most important alternatives in the face of the scenarios tested and in relation to the criteria expressed.


    Institute of Scientific and Technical Information of China (English)

    J.H. Liu; J. Y. Zhang; S.K. Wei


    The present paper presents the structure, features and functions of a computerized system on kinetic analysis and evaluation of gas/solid reactions, KinPreGSR. KinPreGSR is a menu driven system, can be operated with MS Windows as workbench in a PC computer. It has been developed using visual C++ with FoxPro hybrid coding technique.KinPreGSR combines the characteristics of gas/solid reactions with the kinetic models as well as mass and heat transfer equations. The database files were established for the apparent activation energies of some reduction and decomposition reactions to allow the prediction of the reaction kinetics to some extents. Outputs can be displayed using graphical or numerical forms. Examples regarding the oxide reduction and carbonate decomposition under isothermal conditions are given to show those functions.

  10. Method 349.0 Determination of Ammonia in Estuarine and Coastal Waters by Gas Segmented Continuous Flow Colorimetric Analysis (United States)

    This method provides a procedure for the determination of ammonia in estuarine and coastal waters. The method is based upon the indophenol reaction,1-5 here adapted to automated gas-segmented continuous flow analysis.

  11. Thermo-economic comparative analysis of gas turbine GT10 integrated with air and steam bottoming cycle (United States)

    Czaja, Daniel; Chmielnak, Tadeusz; Lepszy, Sebastian


    A thermodynamic and economic analysis of a GT10 gas turbine integrated with the air bottoming cycle is presented. The results are compared to commercially available combined cycle power plants based on the same gas turbine. The systems under analysis have a better chance of competing with steam bottoming cycle configurations in a small range of the power output capacity. The aim of the calculations is to determine the final cost of electricity generated by the gas turbine air bottoming cycle based on a 25 MW GT10 gas turbine with the exhaust gas mass flow rate of about 80 kg/s. The article shows the results of thermodynamic optimization of the selection of the technological structure of gas turbine air bottoming cycle and of a comparative economic analysis. Quantities are determined that have a decisive impact on the considered units profitability and competitiveness compared to the popular technology based on the steam bottoming cycle. The ultimate quantity that can be compared in the calculations is the cost of 1 MWh of electricity. It should be noted that the systems analyzed herein are power plants where electricity is the only generated product. The performed calculations do not take account of any other (potential) revenues from the sale of energy origin certificates. Keywords: Gas turbine air bottoming cycle, Air bottoming cycle, Gas turbine, GT10

  12. Permeability in Rotliegend gas sandstones to gas and brine as predicted from NMR, mercury injection and image analysis

    DEFF Research Database (Denmark)

    Rosenbrand, Esther; Fabricius, Ida Lykke; Fisher, Quentin


    Permeability characterisation of low permeability, clay-rich gas sandstones is part of production forecasting and reservoir management. The physically based Kozeny (1927) equation linking permeability with porosity and pore size is derived for a porous medium with a homogeneous pore size, whereas...... and mercury injection data. To estimate which pores control permeability to gas, gas permeability was calculated for each pore size increment by using the Kozeny equation. Permeability to brine is modelled by assuming a bound water layer on the mineral pore interface. The measured brine permeabilities...... are lower than predicted based on bound water alone for these illite rich samples. Based on the fibrous textures of illite as visible in electron microscopy we speculate that these may contribute to a lower brine permeability....

  13. Multivariate analysis of progressive thermal desorption coupled gas chromatography-mass spectrometry.

    Energy Technology Data Exchange (ETDEWEB)

    Van Benthem, Mark Hilary; Mowry, Curtis Dale; Kotula, Paul Gabriel; Borek, Theodore Thaddeus, III


    Thermal decomposition of poly dimethyl siloxane compounds, Sylgard{reg_sign} 184 and 186, were examined using thermal desorption coupled gas chromatography-mass spectrometry (TD/GC-MS) and multivariate analysis. This work describes a method of producing multiway data using a stepped thermal desorption. The technique involves sequentially heating a sample of the material of interest with subsequent analysis in a commercial GC/MS system. The decomposition chromatograms were analyzed using multivariate analysis tools including principal component analysis (PCA), factor rotation employing the varimax criterion, and multivariate curve resolution. The results of the analysis show seven components related to offgassing of various fractions of siloxanes that vary as a function of temperature. Thermal desorption coupled with gas chromatography-mass spectrometry (TD/GC-MS) is a powerful analytical technique for analyzing chemical mixtures. It has great potential in numerous analytic areas including materials analysis, sports medicine, in the detection of designer drugs; and biological research for metabolomics. Data analysis is complicated, far from automated and can result in high false positive or false negative rates. We have demonstrated a step-wise TD/GC-MS technique that removes more volatile compounds from a sample before extracting the less volatile compounds. This creates an additional dimension of separation before the GC column, while simultaneously generating three-way data. Sandia's proven multivariate analysis methods, when applied to these data, have several advantages over current commercial options. It also has demonstrated potential for success in finding and enabling identification of trace compounds. Several challenges remain, however, including understanding the sources of noise in the data, outlier detection, improving the data pretreatment and analysis methods, developing a software tool for ease of use by the chemist, and demonstrating our belief

  14. Analysis of transient fission gas behaviour in oxide fuel using BISON and TRANSURANUS (United States)

    Barani, T.; Bruschi, E.; Pizzocri, D.; Pastore, G.; Van Uffelen, P.; Williamson, R. L.; Luzzi, L.


    The modelling of fission gas behaviour is a crucial aspect of nuclear fuel performance analysis in view of the related effects on the thermo-mechanical performance of the fuel rod, which can be particularly significant during transients. In particular, experimental observations indicate that substantial fission gas release (FGR) can occur on a small time scale during transients (burst release). To accurately reproduce the rapid kinetics of the burst release process in fuel performance calculations, a model that accounts for non-diffusional mechanisms such as fuel micro-cracking is needed. In this work, we present and assess a model for transient fission gas behaviour in oxide fuel, which is applied as an extension of conventional diffusion-based models to introduce the burst release effect. The concept and governing equations of the model are presented, and the sensitivity of results to the newly introduced parameters is evaluated through an analytic sensitivity analysis. The model is assessed for application to integral fuel rod analysis by implementation in two structurally different fuel performance codes: BISON (multi-dimensional finite element code) and TRANSURANUS (1.5D code). Model assessment is based on the analysis of 19 light water reactor fuel rod irradiation experiments from the OECD/NEA IFPE (International Fuel Performance Experiments) database, all of which are simulated with both codes. The results point out an improvement in both the quantitative predictions of integral fuel rod FGR and the qualitative representation of the FGR kinetics with the transient model relative to the canonical, purely diffusion-based models of the codes. The overall quantitative improvement of the integral FGR predictions in the two codes is comparable. Moreover, calculated radial profiles of xenon concentration after irradiation are investigated and compared to experimental data, illustrating the underlying representation of the physical mechanisms of burst release.

  15. Rapid analysis of urinary opiates using fast gas chromatography–mass spectrometry and hydrogen as a carrier gas


    Sumandeep Rana; Rakesh K. Garg; Anu Singla


    A sensitive and specific fast gas chromatography–mass spectrometry (FGC–MS) analytical method using hydrogen as a carrier gas is developed for the rapid simultaneous determination of morphine, codeine, hydrocodone and hydromorphone in human urine. Urine samples were spiked with deuterated internal standards, morphine-d3, codeine-d3, hydrocodone-d3 and hydro-morphone-d3, subjected to acid hydrolysis, treated with hydroxylamine to convert the keto-opiates to oximes and then extracted using a po...

  16. Identification of Gas Components in Lighter by Gas Chromatography: An Experiment for the Undergraduate Instrumental Analysis Laboratory Which Can Be Used With Distance Learning Applications

    Directory of Open Access Journals (Sweden)

    Inci MORGIL


    Full Text Available In the applications of instrumental analysis lessons, advanced instruments with the needed experiments are needed. During the lessons it is a fact that the more experiments are performed, the more learning will be. For this reason, experiments that do not last long and should be performed with more simple instruments and that increase students’ attention with current events should be developed. It is thought that there is only propane gas in lighters used in daily life. However, in fact, in certain ratios, there are also other gases having similar structure besides propane gas. For these reasons, the identification of gas components in lighter has been thought. To enlighten this situation a simple experiment design has been planned.

  17. Gulf of Mexico Gas Hydrate Joint Industry Project Leg II logging-while-drilling data acquisition and analysis (United States)

    Collett, Timothy S.; Lee, Wyung W.; Zyrianova, Margarita V.; Mrozewski, Stefan A.; Guerin, Gilles; Cook, Ann E.; Goldberg, Dave S.


    One of the objectives of the Gulf of Mexico Gas Hydrate Joint Industry Project Leg II (GOM JIP Leg II) was the collection of a comprehensive suite of logging-while-drilling (LWD) data within gas-hydrate-bearing sand reservoirs in order to make accurate estimates of the concentration of gas hydrates under various geologic conditions and to understand the geologic controls on the occurrence of gas hydrate at each of the sites drilled during this expedition. The LWD sensors just above the drill bit provided important information on the nature of the sediments and the occurrence of gas hydrate. There has been significant advancements in the use of downhole well-logging tools to acquire detailed information on the occurrence of gas hydrate in nature: From using electrical resistivity and acoustic logs to identify gas hydrate occurrences in wells to where wireline and advanced logging-while-drilling tools are routinely used to examine the petrophysical nature of gas hydrate reservoirs and the distribution and concentration of gas hydrates within various complex reservoir systems. Recent integrated sediment coring and well-log studies have confirmed that electrical resistivity and acoustic velocity data can yield accurate gas hydrate saturations in sediment grain supported (isotropic) systems such as sand reservoirs, but more advanced log analysis models are required to characterize gas hydrate in fractured (anisotropic) reservoir systems. In support of the GOM JIP Leg II effort, well-log data montages have been compiled and presented in this report which includes downhole logs obtained from all seven wells drilled during this expedition with a focus on identifying and characterizing the potential gas-hydrate-bearing sedimentary section in each of the wells. Also presented and reviewed in this report are the gas-hydrate saturation and sediment porosity logs for each of the wells as calculated from available downhole well logs.

  18. Agricultural green gas demonstration projects in the Netherlands. A stakeholder analysis

    NARCIS (Netherlands)

    Hoppe, Thomas; Sanders, M.P.T.


    In the Netherlands green gas is seen as a sustainable alternative to natural gas. However, green gas is still not competitive to natural gas in terms of pricing, and production volumes are remarkably low. Currently, there is a lot of attention to green gas which stems from upgraded biogas, which is

  19. Generic Analysis Methods for Gas Turbine Engine Performance: The development of the gas turbine simulation program GSP

    NARCIS (Netherlands)

    Visser, W.P.J.


    Numerical modelling and simulation have played a critical role in the research and development towards today’s powerful and efficient gas turbine engines for both aviation and power generation. The simultaneous progress in modelling methods, numerical methods, software development tools and methods,

  20. "Second order" exploratory data analysis of the large scale gas injection test (lasgit) dataset, focused around known gas migration events

    NARCIS (Netherlands)

    Bennett, D.; Cuss, R.; Vardon, P.J.; Harrington, J.; Sedighi, M.; Shaw, R.; Thomas, H.


    Within large-scale experimental datasets a wealth of small scale information can typically be found. An example of such an experiment is the Large Scale Gas Injection Test (Lasgit). A toolkit has been developed to facilitate the investigation of the small scale or ‘second order’ detail contained wit

  1. Elemental speciation analysis by multicapillary gas chromatography with microwave-induced plasma atomic spectrometric detection. (United States)

    Rodriguez Pereiro, I; Schmitt, V O; Lobiński, R


    Multicapillary column gas chromatography (MC-GC)/microwave-induced plasma atomic emission spectrometry (MIP AES) was developed for fast speciation analysis of organotin compounds in the environment. Ethylated butyltin compounds could be separated isothermally within less than 30 s (instead of ∼5-10 min) without sacrificing either the resolution or the sample capacity of conventional capillary GC with oven temperature gradient programming. Careful optimization of the pressure and temperature GC program allowed a comprehensive organotin speciation analysis including phenyltin compounds within less than 2.5 min, increasing the sample throughput 6-fold. Compatibility of MC-GC with an MIP atomic emission detector (MIP-AED) was discussed. MC-GC/MIP-AES was validated for the analysis of sediment (PACS-1 and BCR 462) and biological (NIES11) certified reference materials.

  2. Thermal analysis and its application in evaluation of fluorinated polyimide membranes for gas separation

    KAUST Repository

    Qiu, Wulin


    Seven polyimides based on (4,4′-hexafluoroisopropylidene) diphthalic anhydride, 6FDA, with different chemical structures were synthesized in a single pot two-step procedure by first producing a high molecular weight polyamic acid (PAA), followed by reaction with acetic anhydride to produce polyimide (PI). The resulting polymers were characterized using thermal analysis techniques including TGA, derivative weight analysis, TGA-MS, and DSC. The decarboxylation-induced thermal cross-linking, ester cross-linking through a diol, and ion-exchange reactions of selected polyimide membranes were investigated. Cross-linking of polymer membranes was confirmed by solubility tests and CO 2 permeability measurements. The thermal analysis provides simple and timesaving opportunities to characterize the polymer properties, the ability to optimize polymer cross-linking conditions, and to monitor polymer functionalization to develop high performance polymeric membranes for gas separations. © 2011 Elsevier Ltd. All rights reserved.

  3. Gas chromatography (United States)

    Guiochon, Georges; Guillemin, Claude L.


    Gas chromatography is a powerful separation technique for gas and vapor mixtures. Combining separation and on-line detection permits accurate quantitative analysis of complex mixtures, including traces of compounds down to parts per trillions in some particular cases. The importance of gas chromatography in quality control and process control in the chemical and drug industry, in environmental pollution investigations and in clinical analysis is critical. The principles of the technique are discussed, the main components of a gas chromatograph are described and some idea of the importance of the applications is given.

  4. Arterial blood gas analysis and electrolyte determination in neonates with asphyxia

    Institute of Scientific and Technical Information of China (English)

    Zi-Mei Sun


    Objective:To explore the value of arterial blood gas analysis and electrolyte determination in the diagnosis of neonatal asphyxia.Methods: A total of 100 neonates with asphyxia who were admitted in our department from March, 2013 to March, 2014 were included in the study and divided into the mild asphyxia group and the severe asphyxia group according to Apgar scoring. Moreover, 50 normal neonates were served as the control group and used for comparative analysis. AVL blood-gas analyzer was used to detect the levels of pH, PaO2, HCO3-, BE, PaCO2, K+, Na+, Cl-, and Ca2+.Results:The concentrations of pH, PaO2, HCO3-, and BE in the severe asphyxia group were significantly lower than those in the mild asphyxia group and the control group, while PaCO2 level was significantly higher than that in the mild asphyxia group and the control group. The comparison of the various indicators between the control group and the mild asphyxia group was not statistically significant. The comparison of serum K+, Na+,and Cl- levels among the control group, the mild asphyxia group, and the severe asphyxia group was not statistically significant. The serum Ca2+ level in the severe asphyxia group was significantly lower than that in the mild asphyxia group and the control group, while the comparison between the mild asphyxia group and the control group was also statistically significant.Conclusions:Blood gas analysis and electrolyte determination to the arterial blood in neonates can compensate for the insufficiency of Apgar scoring and provide an objective evidence for the diagnosis of neonatal asphyxia and the estimation of severity degree. Clinical combination with Apgar scoring is of great significance in enhancing the diagnosis of neonatal asphyxia and the accuracy of severity evaluation.

  5. Cost-benefit analysis of using natural gas in vehicles of the Mexico City metropolitan area

    Energy Technology Data Exchange (ETDEWEB)

    Barrera-Roldan, A.; Trinidad-Garcia, H.G.; Diaz, L.; Perdomo, V.; Castillo, H.; Schifter, I. [Istituto Mexicano del Petroleo, Eje Central Lazaro Cardenas (Mexico)


    According to the Mexico City Metropolitan Area (MCMA) authorities the transport sector causes 75% of total pollutant emissions to the atmosphere, that is why to mitigate pollution several programs focus on reducing emissions from mobile sources, one of these programs promotes the use of Natural Gas (NG) in vehicles of the MCMA instead of gasoline or diesel. This work shows the cost-benefit analysis results of this program. The analysis considered the period 1999-2014. Projections for the MCMA vehicular fleet, and for the type and number of vehicles that would switch from gasoline or diesel to NG were made. To obtain the change in exhaust emissions, measurements were performed using the U. S. Federal Test Procedure 75 in vehicles consuming gasoline and NG Vehicle conversion, conversion shops, and gas station costs were considered in the analysis The estimated benefits stemmed from fuel price and efficiency differential, vehicle taxes, maintenance costs, and pollutant emission reductions. The Benefit/Cost ratio found was 3.79, and the vehicles suggested for conversion were those of intensive use circulating exclusively in the MCMA. Even though ozone formation simulations were done using the CIT trajectory model, the changes in ozone concentrations observed were smaller than the model resolution, mainly because the change in ozone precursors due to the fuel change in some of the MCMA vehicles, was less than 1% of total emissions. (authors)

  6. Estimating Depth and Producing Formations of Abandoned Oil and Gas Wells Using Geospatial Analysis (United States)

    Christian, S.; Kang, M.; Celia, M. A.; Maloof, A. C.; Mauzerall, D. L.


    More than three million abandoned oil and gas wells exist in the U.S., and information on many of these wells are lost. Recent measurements of 93 abandoned wells in Pennsylvania show that they may be a significant source of methane emissions to the atmosphere. Data such as depth and producing formation of 98% of these measured wells are unavailable. Information on the likely depth of the well and the formation, from which the well likely produced from, is important when evaluating the wells' potential to emit methane and/or to contaminate overlying aquifers, and when developing mitigation strategies. We use geospatial analysis that combines available public databases from the Pennsylvania Department of Environmental Protection and historic documents to determine the likely depth and formation from which the measured abandoned wells produced. We develop a framework to systematically evaluate the nearest well, pool, and field attributes and assign depth and producing formation to the measured wells based on how well these attributes match. We then use this information to perform a cost analysis for plugging based on well depth for Pennsylvania. The geospatial analysis framework presented here for determining abandoned well properties can be valuable for future field measurement designs, upscaling methane emissions, and mitigating abandoned wells in Pennsylvania but also the many other states with a long history of oil and gas production.

  7. A Complete 2D Stability Analysis of Fast MHD Shocks in an Ideal Gas (United States)

    Trakhinin, Yuri

    An algorithm of numerical testing of the uniform Lopatinski condition for linearized stability problems for 1-shocks is suggested. The algorithm is used for finding the domains of uniform stability, neutral stability, and instability of planar fast MHD shocks. A complete stability analysis of fast MHD shock waves is first carried out in two space dimensions for the case of an ideal gas. Main results are given for the adiabatic constant γ=5/3 (mono-atomic gas), that is most natural for the MHD model. The cases γ=7/5 (two-atomic gas) and γ>5/3 are briefly discussed. Not only the domains of instability and linear (in the usual sense) stability, but also the domains of uniform stability, for which a corresponding linearized stability problem satisfies the uniform Lopatinski condition, are numerically found for different given angles of inclination of the magnetic field behind the shock to the planar shock front. As is known, uniform linearized stability implies the nonlinear stability, that is local existence of discontinuous shock front solutions of a quasilinear system of hyperbolic conservation laws.

  8. Analysis of CO2 Separation from Flue Gas, Pipeline Transportation, and Sequestration in Coal

    Energy Technology Data Exchange (ETDEWEB)

    Eric P. Robertson


    This report was written to satisfy a milestone of the Enhanced Coal Bed Methane Recovery and CO2 Sequestration task of the Big Sky Carbon Sequestration project. The report begins to assess the costs associated with separating the CO2 from flue gas and then injecting it into an unminable coal seam. The technical challenges and costs associated with CO2 separation from flue gas and transportation of the separated CO2 from the point source to an appropriate sequestration target was analyzed. The report includes the selection of a specific coal-fired power plant for the application of CO2 separation technology. An appropriate CO2 separation technology was identified from existing commercial technologies. The report also includes a process design for the chosen technology tailored to the selected power plant that used to obtain accurate costs of separating the CO2 from the flue gas. In addition, an analysis of the costs for compression and transportation of the CO2 from the point-source to an appropriate coal bed sequestration site was included in the report.

  9. Life-cycle analysis of greenhouse gas emission and energy efficiency of hydrogen fuel cell scooters

    Energy Technology Data Exchange (ETDEWEB)

    Hwang, Jenn Jiang [Department of Greenergy, National University of Taiwan, Tainan (China); Chang, Wei Ru [Department of Landscape Architecture, FuJen Catholic University, Taipei (China)


    The well-to-wheels (WTW) analysis of energy conservation and greenhouse gas emission of advanced scooters associated with new transportation fuels is studied in the present work. Focus is placed on fuel cell scooter technologies, while the gasoline-powered scooter equipped with an internal combustion engine (ICE) serves as a reference technology. The effect of various pathways of hydrogen production on the well-to-tank (WTT) efficiency for energy is examined. Both near-term and long-term hydrogen production options are explored, such as purification of coke oven gas (COG), steam reforming of natural gas, water electrolysis by generation mix and renewable electricity, and gasification of herbaceous biomass. Then, the WTW efficiency of fuel cell scooters for various hydrogen production options is compared with that of the conventional ICE scooters and electric scooters. Results showed that the fuel cell scooters fueled with COG-based hydrogen could achieve the highest reduction benefits in energy consumption and GHG emission. Finally, the potential for hydrogen production from COG resulting from the coking process in steelworks is evaluated, which is anticipated as a near-term hydrogen production for helping transition to a hydrogen energy economy in Taiwan. (author)

  10. Improved machine learning method for analysis of gas phase chemistry of peptides

    Directory of Open Access Journals (Sweden)

    Ahn Natalie


    Full Text Available Abstract Background Accurate peptide identification is important to high-throughput proteomics analyses that use mass spectrometry. Search programs compare fragmentation spectra (MS/MS of peptides from complex digests with theoretically derived spectra from a database of protein sequences. Improved discrimination is achieved with theoretical spectra that are based on simulating gas phase chemistry of the peptides, but the limited understanding of those processes affects the accuracy of predictions from theoretical spectra. Results We employed a robust data mining strategy using new feature annotation functions of MAE software, which revealed under-prediction of the frequency of occurrence in fragmentation of the second peptide bond. We applied methods of exploratory data analysis to pre-process the information in the MS/MS spectra, including data normalization and attribute selection, to reduce the attributes to a smaller, less correlated set for machine learning studies. We then compared our rule building machine learning program, DataSqueezer, with commonly used association rules and decision tree algorithms. All used machine learning algorithms produced similar results that were consistent with expected properties for a second gas phase mechanism at the second peptide bond. Conclusion The results provide compelling evidence that we have identified underlying chemical properties in the data that suggest the existence of an additional gas phase mechanism for the second peptide bond. Thus, the methods described in this study provide a valuable approach for analyses of this kind in the future.

  11. Thermodynamic analysis of fuels in gas phase: ethanol, gasoline and ethanol - gasoline predicted by DFT method. (United States)

    Neto, A F G; Lopes, F S; Carvalho, E V; Huda, M N; Neto, A M J C; Machado, N T


    This paper presents a theoretical study using density functional theory to calculate thermodynamics properties of major molecules compounds at gas phase of fuels like gasoline, ethanol, and gasoline-ethanol mixture in thermal equilibrium on temperature range up to 1500 K. We simulated a composition of gasoline mixture with ethanol for a thorough study of thermal energy, enthalpy, Gibbs free energy, entropy, heat capacity at constant pressure with respect to temperature in order to study the influence caused by ethanol as an additive to gasoline. We used semi-empirical computational methods as well in order to know the efficiency of other methods to simulate fuels through this methodology. In addition, the ethanol influence through the changes in percentage fractions of chemical energy released in combustion reaction and the variations on thermal properties for autoignition temperatures of fuels was analyzed. We verified how ethanol reduces the chemical energy released by gasoline combustion and how at low temperatures the gas phase fuels in thermal equilibrium have similar thermodynamic behavior. Theoretical results were compared with experimental data, when available, and showed agreement. Graphical Abstract Thermodynamic analysis of fuels in gas phase.

  12. Hydrogen Energy Storage (HES) and Power-to-Gas Economic Analysis; NREL (National Renewable Energy Laboratory)

    Energy Technology Data Exchange (ETDEWEB)

    Eichman, Joshua


    This presentation summarizes opportunities for hydrogen energy storage and power-to-gas and presents the results of a market analysis performed by the National Renewable Energy Laboratory to quantify the value of energy storage. Hydrogen energy storage and power-to-gas systems have the ability to integrate multiple energy sectors including electricity, transportation, and industrial. On account of the flexibility of hydrogen systems, there are a variety of potential system configurations. Each configuration will provide different value to the owner, customers and grid system operator. This presentation provides an economic comparison of hydrogen storage, power-to-gas and conventional storage systems. The total cost is compared to the revenue with participation in a variety of markets to assess the economic competitiveness. It is found that the sale of hydrogen for transportation or industrial use greatly increases competitiveness. Electrolyzers operating as demand response devices (i.e., selling hydrogen and grid services) are economically competitive, while hydrogen storage that inputs electricity and outputs only electricity have an unfavorable business case. Additionally, tighter integration with the grid provides greater revenue (e.g., energy, ancillary service and capacity markets are explored). Lastly, additional hours of storage capacity is not necessarily more competitive in current energy and ancillary service markets and electricity markets will require new mechanisms to appropriately compensate long duration storage devices.

  13. Value analysis of district heating system with gas-fired peak load boiler in secondary network

    Institute of Scientific and Technical Information of China (English)

    郑雪晶; 穆振英


    In district heating(DH) system with gas-fired peak load regulating boiler in the secondary network,by prolonging run time of base load plants under rated condition,the mean energy efficiency could be increased. The fuels of the system,including coal and gas,would cause different environmental impacts. Meanwhile,the reliability of the heating networks would be changed because the peak load regulating boiler could work as a standby heat source. A model for assessment of heating system was established by value analysis to optimize this kind of system. Energy consumption,greenhouse gas emission,pollution emission and system reliability were selected as functional assessment indexes in the model. Weights of each function were determined by analytical hierarchy process (AHP) and experts consultation. Life cycle cost was used as the cost in the model. A real case as an example was discussed to obtain the optimal base load ratio. The result shows that the optimal base load ratio of the case is 0.77.

  14. Dynamic Analysis of Pig through Two and Three Dimensional Gas Pipeline

    Directory of Open Access Journals (Sweden)

    Malihe Mirshamsi


    Full Text Available This paper deals with the dynamic analysis and simulation of Pipeline Inspection Gage (PIG through the two and three dimensional gas pipelines. Continuity, momentum and the state equations are employed to achieve the gas flow parameters like density, velocity and pressure along the pipeline since the dynamic behavior of the pig depends on the flow field characteristics. Also, a differential equation which governs the dynamic behavior of the pig is derived. The pig is assumed to be a small rigid body with a bypass hole in its body. The variation of the diameter of the bypass port, which is controlled by a valve, is considered in this research. The path of the pig or geometry of the pipeline is assumed to be 2D and 3D curve. 2D and 3D simulations of the pig motion are performed individually using Rung- Kutta method and a case has been solved and discussed for each of them. The simulation results show that the derived equations are valid and effective for online estimating of the position, velocity and forces acting on the pig in gas pipelines at any time of the motion.

  15. Design and Analysis of Gas Turbine Blade by Potential Flow Approach

    Directory of Open Access Journals (Sweden)

    V. Vijaya Kumar,


    Full Text Available The design features of the turbine segment of the gas turbine have been taken from the “preliminary design of a power turbine for maximization of an existing turbojet engine”. It was observed that in the above design, after the rotor blades being designed they were analyzed only for the mechanical stresses. As the temperature has a significant effect on the overall stress in the rotor blades, a detailed study is carried out on the temperature effects to have a clear understanding of the combined mechanical and the thermal stresses. The first stage rotor blade of the gas turbine is analyzed for the mechanical axial and centrifugal forces. Knowing the fluid conditions at exit of the gas turbines, a value of static pressure was assumed at the turbine outlet. From this the corresponding enthalpy drop required in the power turbine is calculated. The peripheral speed of rotor and flows velocities is kept in the reasonable range so to minimize losses. In which the base profiles available and is analyzed later for flow conditions through any of the theoretical flow analysis methods such as “Potential flow Approach”

  16. Facile synthesis of porous ZnO microbelts and analysis of their gas-sensing property

    Energy Technology Data Exchange (ETDEWEB)

    Huang, Jiarui, E-mail:; Shi, Chengcheng; Fu, Guijun; Sun, Pingping; Wang, Xinyue; Gu, Cuiping, E-mail:


    Porous ZnO microbelts were achieved using a facile chemical solution method combined with subsequent calcination. The micro-nanostructures were characterized through X-ray diffraction, field emission scanning electron microscopy, thermogravimetric-differential thermal analysis, and Brunauer–Emmett–Teller N{sub 2} adsorption-desorption analyses, among others. The BET surface area of the porous ZnO microbelts was calculated at 23.0 m² g{sup −1}. Furthermore, the gas sensing properties of the as-prepared porous ZnO microbelts were investigated using volatile organic compounds. Compared with ZnO microflowers, the porous ZnO microbelts exhibited higher response with certain organic vapors, such as formaldehyde, acetone, and ethanol. The responses to 100 ppm formaldehyde, acetone, and ethanol were 45.7, 40.6, and 38.4, respectively, at a working temperature of 300 °C. The results showed that the porous ZnO microbelts are highly promising candidates for gas sensing applications. - Highlights: • Zinc glycinate monohydrate microwires were obtained by a chemical solution method. • Porous ZnO microbelts were achieved after calcinations. • The porous ZnO microbelts exhibit superior gas-sensing property.

  17. Technical and economic analysis of implementation of small scale GTL (Gas-to-Liquids) technology to monetize associated stranded natural gas offshore in Brazil

    Energy Technology Data Exchange (ETDEWEB)

    Castelo Branco, David; Szklo, Alexandre; Schaeffer, Roberto [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Coordenacao dos Programas de Pos-graduacao de Engenharia (COPPE). Programa de Planejamento Energetico


    The volume of global stranded natural gas reserves is impressive totalling more than a third of the world's proven natural gas reserves. In Brazil, recent discoveries operated by PETROBRAS with the share of other companies indicate the tendency of incorporating stranded gas reserves (associated or not) to the country's total reserves. The objective of this study is to perform a technical and economic analysis of the implementation of small-scale GTL technology for the exploitation of stranded associated natural gas offshore in Brazil. Thus, the study initially held a survey of the processes of gasification and the manufacturers of technologies and projects based on these processes, specifically for offshore applications. Then, the offshore environment conditions were examined. After the confrontation of the available technologies and the operational conditions, one technology was chosen to be assessed by the economic analysis. The results show that GTL offshore option becomes feasible for the minimum oil price of approximately $50.00 per barrel. This price is greater than the value of robustness adopted by PETROBRAS, however there is still the possibility of cost reductions for the feasibility of new technologies. (author)

  18. Isolation and gas chromatographic analysis of lupenone and lupeol from sorbus cortex

    Energy Technology Data Exchange (ETDEWEB)

    Lee, S.M. [Chungnam National University, Taejon (Korea, Republic of); Lee, C.G. [Chongju University, Congju (Korea, Republic of)


    Lupenone and lupeol, the triterpenoids of sorbus cortex, were isolated with silica gel column chromatography and used as the standard substances for the quantitative analysis. The compounds were identified with IR, NMR, EI-MS. They were separated on VA-5MS [(5%-phenyl)methlypolysiloxane, 30m*0.25mm, 0.25 {mu}m] column by gas-chromatograph. The contents of lupeone and lupeol in three different samples of Sorbus Cortex were in the range of 0.050{approx}0.056% and 0.772{approx}0.834%, respectively. 15 refs., 6 figs., 2 tabs.

  19. Analysis of the citric acid cycle intermediates using gas chromatography-mass spectrometry. (United States)

    Kombu, Rajan S; Brunengraber, Henri; Puchowicz, Michelle A


    Researchers view analysis of the citric acid cycle (CAC) intermediates as a metabolomic approach to identifying unexpected correlations between apparently related and unrelated pathways of metabolism. Relationships of the CAC intermediates, as measured by their concentrations and relative ratios, offer useful information to understanding interrelationships between the CAC and metabolic pathways under various physiological and pathological conditions. This chapter presents a relatively simple method that is sensitive for simultaneously measuring concentrations of CAC intermediates (relative and absolute) and other related intermediates of energy metabolism using gas chromatography-mass spectrometry.

  20. Rapid X-ray crystal structure analysis in few second measurements using microstrip gas chamber

    CERN Document Server

    Ochi, A; Tanimori, T; Ohashi, Y; Toyokawa, H; Nishi, Y; Nishi, Y; Nagayoshi, T; Koishi, S


    X-ray crystal structure analysis using microstrip gas chamber was successfully carried out in a measurement time within a few seconds. The continuous rotation photograph method, in which most of the diffraction peaks can be obtained within one continuous rotation of the sample crystal (without stopping or oscillation), was applied for this measurement. As an example, the structure of a single crystal of ammonium bitartrate (r=1 mm, spherical) was measured. Diffraction spots from the sample, which were sufficient to obtain crystal structure, were successfully obtained by taking only 2 s measurements with a commercially available laboratory X-ray source.

  1. Simple, specific analysis of organophosphorus and carbamate pesticides in sediments using column extraction and gas chromatography (United States)

    Belisle, A.A.; Swineford, D.M.


    A simple, specific procedure was developed for the analysis of organophosphorus and carbamate pesticides in sediment. The wet soil was mixed with anhydrous sodium sulfate to bind water and the residues were column extracted in acetone:methylene chloride (1:l,v/v). Coextracted water was removed by additional sodium sulfate packed below the sample mixture. The eluate was concentrated and analyzed directly by capillary gas chromatography using phosphorus and nitrogen specific detectors. Recoveries averaged 93 % for sediments extracted shortly after spiking, but decreased significantly as the samples aged.

  2. Direct analysis of fluoxetine and norfluoxetine in plasma by gas chromatography with nitrogen-phosphorus detection. (United States)

    Fontanille, P; Jourdil, N; Villier, C; Bessard, G


    A quantitative method for the simultaneous GC resolution and detection of fluoxetine and his metabolite norfluoxetine in human plasma was developed. The procedure required 1.0 ml of plasma, extraction with a mixed organic solvent and injection into a capillary gas chromatograph with an OV-1 fused-silica column coupled to a nitrogen-phosphorus detector. The calibration curves were linear over the range 5-3000 ng/ml. The detection limits were 0.3 and 2 ng/ml for fluoxetine and norfluoxetine, respectively. The assay is suitable for routine analysis.

  3. Multi-Scale Morphological Analysis of Conductance Signals in Vertical Upward Gas-Liquid Two-Phase Flow (United States)

    Lian, Enyang; Ren, Yingyu; Han, Yunfeng; Liu, Weixin; Jin, Ningde; Zhao, Junying


    The multi-scale analysis is an important method for detecting nonlinear systems. In this study, we carry out experiments and measure the fluctuation signals from a rotating electric field conductance sensor with eight electrodes. We first use a recurrence plot to recognise flow patterns in vertical upward gas-liquid two-phase pipe flow from measured signals. Then we apply a multi-scale morphological analysis based on the first-order difference scatter plot to investigate the signals captured from the vertical upward gas-liquid two-phase flow loop test. We find that the invariant scaling exponent extracted from the multi-scale first-order difference scatter plot with the bisector of the second-fourth quadrant as the reference line is sensitive to the inhomogeneous distribution characteristics of the flow structure, and the variation trend of the exponent is helpful to understand the process of breakup and coalescence of the gas phase. In addition, we explore the dynamic mechanism influencing the inhomogeneous distribution of the gas phase in terms of adaptive optimal kernel time-frequency representation. The research indicates that the system energy is a factor influencing the distribution of the gas phase and the multi-scale morphological analysis based on the first-order difference scatter plot is an effective method for indicating the inhomogeneous distribution of the gas phase in gas-liquid two-phase flow.

  4. Roadmap for Development of Natural Gas Vehicle Fueling Infrastructructure and Analysis of Vehicular Natural Gas Consumption by Niche Sector

    Energy Technology Data Exchange (ETDEWEB)

    Stephen C. Yborra


    Vehicular natural gas consumption is on the rise, totaling nearly 200 million GGEs in 2005, despite declines in total NGV inventory in recent years. This may be attributed to greater deployment of higher fuel use medium- and heavy-duty NGVs as compared to the low fuel use of the natural gas-powered LDVs that exited the market through attrition, many of which were bi-fuel. Natural gas station counts are down to about 1100 from their peak of about 1300. Many of the stations that closed were under-utilized or not used at all while most new stations were developed with greater attention to critical business fundamentals such as site selection, projected customer counts, peak and off-peak fueling capacity needs and total station throughput. Essentially, the nation's NGV fueling infrastructure has been--and will continue--going through a 'market correction'. While current economic fundamentals have shortened payback and improved life-cycle savings for investment in NGVs and fueling infrastructure, a combination of grants and other financial incentives will still be needed to overcome general fleet market inertia to maintain status quo. Also imperative to the market's adoption of NGVs and other alternative fueled vehicle and fueling technologies is a clear statement of long-term federal government commitment to diversifying our nation's transportation fuel use portfolio and, more specifically, the role of natural gas in that policy. Based on the current NGV market there, and the continued promulgation of clean air and transportation policies, the Western Region is--and will continue to be--the dominant region for vehicular natural gas use and growth. In other regions, especially the Northeast, Mid-Atlantic states and Texas, increased awareness and attention to air quality and energy security concerns by the public and - more important, elected officials--are spurring policies and programs that facilitate deployment of NGVs and fueling

  5. Integrated cost-effectiveness analysis of greenhouse gas emission abatement. The case of Finland

    Energy Technology Data Exchange (ETDEWEB)

    Lehtilae, A.; Tuhkanen, S. [VTT Energy, Espoo (Finland). Energy Systems


    In Finland greenhouse gas emissions are expected to increase during the next decades due to economic growth, particularly in the energy intensive industrial sectors. The role of these industries is very central in the national economy. The emission control according to the Kyoto Protocol will therefore be quite difficult and costly. The study analyses the cost-effectiveness of different technical options for reducing the emissions of carbon dioxide, methane, and nitrous oxide in Finland. The analysis is performed with the help of a comprehensive energy system model for Finland, which has been extended to cover all major sources of methane and nitrous oxide emissions in the energy sector, industry, waste management and agriculture. The focus being on technical options, no consideration is given to possible policy measures, emission trading or joint implementation in the study. Under the boundary conditions given for the development of the Finnish energy economy, cost-effective technical measures in the energy system include increases in the use of wood biomass, natural gas and wind energy, increases in the contribution of CHP to the power supply, and intensified energy conservation in all end-use sectors. Additional cost-effective measures are landfill gas recovery, utilisation of the combustible fraction of waste and catalytic conversion of N{sub 2}O in nitric acid production. With baseline assumptions, the direct annual costs of emission abatement are calculated to be about 2000 MFIM (330 M{epsilon}) in 2010. The marginal costs are estimated to be about 230 FIM (40 {epsilon}) per tonne of CO{sub 2}-equivalent in 2010. The cost curie derived from the analysis could be used in further analyses concerning emissions trading. (orig.) 109 refs. SIHTI Research Programme

  6. Analysis of a gas stratification break-up by a vertical jet using the GOTHIC code

    Energy Technology Data Exchange (ETDEWEB)

    Fernández-Cosials, Mikel Kevin; Jimenez, Gonzalo, E-mail:; Lopez-Alonso, Emma


    Highlights: • Study of a light gas distribution with the GOTHIC code based on the OECD/NEA IBE-3. • Sensitivity analysis on turbulence model, discretization scheme and heat transfer. • The jet erosion phenomena is captured properly with a relatively coarse mesh. • Development of a tool to evaluate the influence of each parameter on the simulation. • Several recommendation on modeling a stratification break-up are included. - Abstract: During a severe accident in light water reactor (LWR), hydrogen concentration can overpass the flammability limits locally, so the correct simulation of its behavior during a release is critical. The capability assessment of computational fluid dynamics tools to calculate the hydrogen distribution under different conditions has been the focus of intense research worldwide. In this context, the OECD/NEA conducted an international benchmark exercise (IBE-3), which was focused on the break-up of a stratified layer of a light gas by a vertical jet. The participants performed their simulations before the experiment data was released. When the data was released, it was noticed that a combination of several parameters like the mesh, turbulence model or solver controls were responsible for the broad differences between the participants’ results. To obtain information about how each parameter affects the simulation, a post-test sensitivity analysis has been done by the UPM. In this paper, the IBE-3 experiment simulation with GOTHIC 8.0 is presented along with extensive sensitivity analyses of the relevant parameters. The first objective of the work is to test the capability of GOTHIC 8.0 to simulate properly a gas stratification break-up by a vertical jet with a relatively coarse mesh. The second objective of the paper is to relate each sensitivity parameter with each other and with the experiment through the Parameter Influence Chart, a helpful tool specially designed for this purpose.

  7. Dynamical mechanism in aero-engine gas path system using minimum spanning tree and detrended cross-correlation analysis (United States)

    Dong, Keqiang; Zhang, Hong; Gao, You


    Identifying the mutual interaction in aero-engine gas path system is a crucial problem that facilitates the understanding of emerging structures in complex system. By employing the multiscale multifractal detrended cross-correlation analysis method to aero-engine gas path system, the cross-correlation characteristics between gas path system parameters are established. Further, we apply multiscale multifractal detrended cross-correlation distance matrix and minimum spanning tree to investigate the mutual interactions of gas path variables. The results can infer that the low-spool rotor speed (N1) and engine pressure ratio (EPR) are main gas path parameters. The application of proposed method contributes to promote our understanding of the internal mechanisms and structures of aero-engine dynamics.

  8. Steady-state analysis of the integrated natural gas and electric power system with bi-directional energy conversion

    DEFF Research Database (Denmark)

    Zeng, Qing; Fang, Jiakun; Li, Jinghua


    Nowadays, the electric power system and natural gas network are becoming increasingly coupled and interdependent. A harmonized integration of natural gas and electricity network with bi-directional energy conversion is expected to accommodate high penetration levels of renewables in terms of system...... flexibility. This work focuses on the steady-state analysis of the integrated natural gas and electric power system with bi-directional energy conversion. A unified energy flow formulation is developed to describe the nodal balance and branch flow in both systems and it is solved with the Newton...... series of wind power and power load are used to investigate the mitigation effect of the integrated energy system. At last, the effect of wind power and power demand on the output of Power to Gas (P2G) and gas-fired power generation (GPG) has also been investigated....

  9. Tipping points for carbon dioxide and air pollution benefits: an energy systems analysis of natural gas verses electric technologies in the U.S. buildings sector (United States)

    Our analysis examines emission trade-offs between electricity and natural gas use in the buildings sector at the system level, including upstream emissions from the electric sector and natural gas mining emissions.

  10. Greenhouse gas mitigation options in the forestry sector of The Gambia: Analysis based on COMAP model

    Energy Technology Data Exchange (ETDEWEB)

    Jallow, B.P.


    Results of the 1993 Greenhouse Gas Emissions Inventory of The Gambia showed net CO{sub 2} emissions of over (1.66 x 10{sup 6} tons) and 1% was due to uptake by plantations (0.01 x 10{sup 6} tons). This is a clear indication that there is need to identify changes in the land-use policy, law and tenure that discourages forest clearing at the same time significantly influencing the sustainable distribution of land among forestry, rangeland and livestock, and agriculture. About 11% of the total area of The Gambia is either fallow or barren flats that once supported vegetation and hence is still capable of supporting vegetation. The US Country Study Programme has provided the Government of The Gambia through the National Climate Committee funds to conduct Assessment of Mitigation Options to Reduce Greenhouse Gas Emissions. The Forestry Sector is one area for which assessment is being conducted. The assessment is expected to end in September 1996. The Comprehensive Mitigation Analysis Process (COMAP) is one of the Models supplied to the National Climate Committee by the Lawrence Berkeley Laboratory, on behalf of the US Country Study Programme, and is being used to conduct the analysis in The Gambia.

  11. Dual-Section DFB-QCLs for Multi-Species Trace Gas Analysis

    Directory of Open Access Journals (Sweden)

    Martin J. Süess


    Full Text Available We report on the dynamic behavior of dual-wavelength distributed feedback (DFB quantum cascade lasers (QCLs in continuous wave and intermittent continuous wave operation. We investigate inherent etaloning effects based on spectrally resolved light-current-voltage (LIV characterization and perform time-resolved spectral analysis of thermal chirping during long (>5 µs current pulses. The theoretical aspects of the observed behavior are discussed using a combination of finite element method simulations and transfer matrix method calculations of dual-section DFB structures. Based on these results, we demonstrate how the internal etaloning can be minimized using anti-reflective (AR coatings. Finally, the potential and benefits of these devices for high precision trace gas analysis are demonstrated using a laser absorption spectroscopic setup. Thereby, the atmospherically highly relevant compounds CO2 (including its major isotopologues, CO and N2O are simultaneously determined with a precision of 0.16 ppm, 0.22 ppb and 0.26 ppb, respectively, using a 1-s integration time and an optical path-length of 36 m. This creates exciting new opportunities in the development of compact, multi-species trace gas analyzers.

  12. A computable general equilibrium analysis of greenhouse gas reduction paths and scenarios

    Energy Technology Data Exchange (ETDEWEB)

    Iorwerth, A.A.; Bagnoli, P.; Dissou, Y.; Peluso, T.; Rudin, J. [Department of Finance, Ottawa, ON (Canada)


    Finance Canada conducted an analysis on behalf of the federal-provincial Climate Change Analysis and Modelling Group regarding policy options to reduce greenhouse gas (GHG) emissions. The Canadian sectoral general equilibrium model (CaSGEM) was used to simulate the Canadian economy using representative consumers and producers. The model describes the complete economy comprised of 51 sectors producing 59 goods and services. The model does not describe the transition costs of the path taken in adjusting to the new policy environment. Instead, it focuses on the Canadian economy after the impacts of new policies have been in place long enough to work themselves through the economy. It was suggested that at least some producers, particularly in electricity production, could easily replace GHG-intensive inputs with those which are less polluting. A table was included which showed the reduction in emissions from coal and natural gas predicted by the model for the electricity sector. The reduction in fuel use was also reported. It was concluded that there would be a long-run economic cost to implement the Kyoto agreement, but the cost is neither inconsequential nor enormous if the agreement is implemented in a cost-effective way. It was determined that the use of sector-specific emissions targets would add to the overall cost of implementing the Kyoto agreement without reducing the variation in economic impact across sectors. It was noted that technical assumptions have a significant bearing on the general impact and its distribution across sectors and provinces. tabs.

  13. Method of sensitivity improving in the non-dispersive infrared gas analysis system

    Institute of Scientific and Technical Information of China (English)

    Youwen Sun; Wenqing Liu; Shimei Wang; Shuhua Huang; Xiaoman Yu


    @@ A method of interference correction for improving the sensitivity of non-dispersive infrared (NDIR) gas analysis system is demonstrated.Based on the proposed method, the interference due to water vapor and carbon dioxide in the NDIR NO analyzer is corrected.After interference correction, the absorbance signal at the NO filter channel is only controlled by the absorption of NO, and the sensitivity of the analyzer is improved greatly.In the field experiment for pollution source emission monitoring, the concentration trend of NO monitored by NDIR analyzer is in good agreement with the differential optical absorption spectroscopy NO analyzer.Small variations of NO concentration can also be resolved, and the measuring correlation coefficient of the two analyzers is 94.28%.%A method of interference correction for improving the sensitivity of non-dispersive infrared (NDIR) gas analysis system is demonstrated. Based on the proposed method, the interference due to water vapor and carbon dioxide in the NDIR NO analyzer is corrected. After interference correction, the absorbance signal at the NO filter channel is only controlled by the absorption of NO, and the sensitivity of the analyzer is improved greatly. In the field experiment for pollution source emission monitoring, the concentration trend of NO monitored by NDIR analyzer is in good agreement with the differential optical absorption spectroscopy NO analyzer. Small variations of NO concentration can also be resolved, and the measuring correlation coefficient of the two analyzers is 94.28%.

  14. Exergy analysis in hydrogen production from auto thermal reforming of natural gas

    Energy Technology Data Exchange (ETDEWEB)

    Alves, Lourenco Gobira [SENAI, Salvador, BA (Brazil). Centro Integrado de Manufatura e Tecnologia - CIMATEC; Nebra, Silvia Azucena de [Universidade Estadual de Campinas (UNICAMP), SP (Brazil). Faculdade de Engenharia Mecanica. Dept. de Energia


    This work makes an exergetic analysis in the production of hydrogen by Autothermal Reforming of Methane, ATR. ATR is combination between Steam Methane Reforming, SMR, and partial reforming. In the ATR, the reforming reaction can be endothermic, exothermic or neutral depending on the relation CH{sub 4}-H{sub 2}O-O{sub 2}. The first step of ATR is the reforming where synthesis gas, containing H{sub 2}, H{sub 2}O, CO{sub 2}, CO and residual CH{sub 4} is formed. Thermodynamic chemical equilibrium is assumed in all reactions of process. After reforming, Shift reactions produce more H{sub 2} reacting CO and H{sub 2}O. After Shift Reactions the synthesis gas is purified by absorption and adsorption. The absorption is made in Diethanolamine, DEA, and produce CO{sub 2} as by product. The adsorption is made in fixed beds of molecular sieves. This procedure can produce H{sub 2} highly pure (99,999 %, wt) proper to fuel cells. The exergetic analysis identifies the sources of irreversibility of the process. It was employed the Fuel-Product concept where the Control Volumes, CV, may present as product the total, physical or chemical exergies. The desegregation of the exergy into physical and chemical is essential to evaluate the perform of CV's. The results show that the main source of irreversibility is the Reformer. (author)

  15. Modeling and Analysis of the Reverse Water Gas Shift Process for In-Situ Propellant Production (United States)

    Whitlow, Jonathan E.


    This report focuses on the development of mathematical models and simulation tools developed for the Reverse Water Gas Shift (RWGS) process. This process is a candidate technology for oxygen production on Mars under the In-Situ Propellant Production (ISPP) project. An analysis of the RWGS process was performed using a material balance for the system. The material balance is very complex due to the downstream separations and subsequent recycle inherent with the process. A numerical simulation was developed for the RWGS process to provide a tool for analysis and optimization of experimental hardware, which will be constructed later this year at Kennedy Space Center (KSC). Attempts to solve the material balance for the system, which can be defined by 27 nonlinear equations, initially failed. A convergence scheme was developed which led to successful solution of the material balance, however the simplified equations used for the gas separation membrane were found insufficient. Additional more rigorous models were successfully developed and solved for the membrane separation. Sample results from these models are included in this report, with recommendations for experimental work needed for model validation.

  16. Variance Analysis of Wind and Natural Gas Generation under Different Market Structures: Some Observations

    Energy Technology Data Exchange (ETDEWEB)

    Bush, B.; Jenkin, T.; Lipowicz, D.; Arent, D. J.; Cooke, R.


    Does large scale penetration of renewable generation such as wind and solar power pose economic and operational burdens on the electricity system? A number of studies have pointed to the potential benefits of renewable generation as a hedge against the volatility and potential escalation of fossil fuel prices. Research also suggests that the lack of correlation of renewable energy costs with fossil fuel prices means that adding large amounts of wind or solar generation may also reduce the volatility of system-wide electricity costs. Such variance reduction of system costs may be of significant value to consumers due to risk aversion. The analysis in this report recognizes that the potential value of risk mitigation associated with wind generation and natural gas generation may depend on whether one considers the consumer's perspective or the investor's perspective and whether the market is regulated or deregulated. We analyze the risk and return trade-offs for wind and natural gas generation for deregulated markets based on hourly prices and load over a 10-year period using historical data in the PJM Interconnection (PJM) from 1999 to 2008. Similar analysis is then simulated and evaluated for regulated markets under certain assumptions.

  17. A cluster analysis study based on profitability and financial indicators in the Italian gas retail market

    Energy Technology Data Exchange (ETDEWEB)

    Capece, Guendalina; Di Pillo, Francesca; Levialdi, Nathan [Dipartimento di Ingegneria dell' Impresa, Universita di Roma ' Tor Vergata' , Via del Politecnico 1, 00133 Roma (Italy); Cricelli, Livio [Dipartimento di Meccanica, Strutture, Ambiente e Territorio, Universita di Cassino, Via G. Di Biasio 43, 03043 Cassino (Italy)


    In the European Union, the natural gas market is increasingly being liberalized. The liberalization process is aimed at leading to lower prices and higher volumes, and hence higher consumer welfare. This paper focuses on the changes in performance in the natural gas retail market by analyzing the profit and financial position of the companies concerned over the first three years following the market liberalization. The balance sheets of 105 Italian companies in this sector are analyzed, after which a cluster analysis is performed employing the most significant performance indexes. The companies are then analyzed within each cluster with respect to age, size, geographical location and business diversification. The results of our analysis show that the majority of companies attained a high level of performance, although this positive outcome was mitigated by the gradual decrease of the average values of performance indicators during the period concerned. The companies that achieve the best performances belong to longstanding business groups, are medium-large sized and are located in the north of the country. Regarding business diversification, in the first two years, the specialised companies outperformed the diversified companies. (author)

  18. In situ search for organics by gas chromatography analysis: new derivatization / thermochemolysis approach (United States)

    Geffroy, Claude; Buch, Arnaud; David, Marc; Aissat, Lyes; El Mufleh, Amel; Papot, S.; Sternberg, Robert

    Many organic molecules are present in interstellar clouds and might be carried to the early Earth by comets and meteorites during the heavy bombardment phase in the first few hundred million years of the solar system. It has been suggested that extraterrestrial organic material may well represent an important part of the organic material available for the origin of life. Until samples, brought by future space missions, are available on Earth, in situ measurements are one of the way to get unaltered and non-contaminated samples for analysis. The analytical technique has to be robust, sensitive and non-specific due to the large scope of targets molecules. The only currently flight qualified technique of analysis of organic molecules in space is gas chromatography (Viking, Cassini-Huygens, SAM-MSL, COSAC-Rosetta). The main objective of this work is to present a new approach with multi step analysis using derivatisation and thermochemolysis reagents for a one pot in situ analysis of volatile and refractory organics in surface or sub-surface samples (Mars, comets).Indeed, no single technology enables to identify all organic compounds because naturally occurring molecules have different polarities, molecular weights, being extractible or recalcitrant, bonded trapped or adsorbed on minerals. Thus, we propose to wider the scope of chemical reagent already validated for in situ wet chemistry such as MTBSTFA (Rodier et al. 2001, 2002), DMF-DMA (Rodier et al. 2002), or TMAH (Rodier et al, 2005, Geffroy-Rodier et al; 2009) to analyze enantiomers of amino acids, carbohydrates and lipids in a one pot several steps sub system using a multi reagent and multi step approach. Thus using a new derivatizing agent, we successfully identified twenty one amino acids including twelve of the twenty proteinic amino acids without inhibiting following multi step thermochemolysis. *Geffroy-Rodier C, Grasset L, Sternberg R. Buch A. Amblès A. (2009) Thermochemolysis in search for organics in

  19. Analysis of markets for biofuels - Theme: Vehicle gas market; Analys av marknaderna foer biodrivmedel - Tema: Fordonsgasmarknaden

    Energy Technology Data Exchange (ETDEWEB)



    In 2011 the Energy Agency was given an annual mission, which involved analyzing the current and future markets for ethanol and bio diesel. The mission resulted in a report that did a thorough analysis of price and market mechanisms in the Swedish and international market. This year's report aims to provide a situation analysis of the markets for ethanol and bio diesel, both first and second generation, with additional focus on certain market issues. This time, the Agency has also been asked to consider the market for vehicle gas, something that was not part of the original mandate from 2011. Regarding ethanol and bio diesel so have indentations made primarily on European protection duties.

  20. Numerical Analysis of Silicon Micromachined Gas Pendulum Tilt Sense Organ Temperature Field

    Institute of Scientific and Technical Information of China (English)

    Linhua Piao; Bin Zhang; Yaojie Lv; Fuxue Zhang


    An analysis of the sensitive mechanism of silicon micromachined gas pendulum tilt sense organ is made. Adopting the method of FEA (finite element analysis), the temperature field at two points heat source, when the two-dimensional enclosure was inclined, was obtained by application of the program ANSYS-FLOTRAN CFD and a series of procedures, such as modeling, meshing, loading and equation solving. The numerical results show that in the level state, the temperatures at two points heat source are two points in the same isotherm; however, the temperatures are not the same when the enclosure is inclined. The difference of the temperatures will increase with the augment of the tilt angle, and contrarily it will decrease. That is the characteristic used to sense the transformation of obliquity.

  1. Species-selective analysis by microcolumn multicapillary gas chromatography with inductively coupled plasma mass spectrometric detection. (United States)

    Rodriguez, I; Mounicou, S; Lobiński, R; Sidelnikov, V; Patrushev, Y; Yamanaka, M


    A glass rod (5-20 cm long, 2 mm o.d.) containing more than 1200 parallel microchannels ( 100 theoretical plates cm-1) GC column by coating the inside of each channel in a way that compensated for the dispersion of the channel inner diameter. The columns were evaluated for the separation of mixtures of several organometallic (Hg, Sn, Pb) compounds prior to on-line sensitive metalselective detection by ICPMS. Chromatographic separation conditions were optimized to enable a rapid (within a maximum 30 s) multielemental speciation analysis. Absolute detection limits were 0.1 pg for Hg, 0.05 pg for Sn, and 0.03 pg for Pb using the carrier gas flows of approximately 200 mL min-1. The microcolumn multicapillary GC/ICPMS developed was applied to the analysis of a number of environmental samples. The results were validated with certified reference materials for tin (BCR477, PACS-2) and mercury (DORM-1, TORT-1).

  2. Thermal Analysis in Gas Insulated Transmission Lines Using an Improved Finite-Element Model

    Directory of Open Access Journals (Sweden)

    Ling LI


    Full Text Available  In this paper, an improved finite element (FE model is proposed to investigate the temperature distribution in gas insulated transmission lines (GILs. The solution of joule losses in eddy current field analysis is indirectly coupled into fluid and thermal fields. As is different from the traditional methods, the surrounding air of the GIL is involved in the model to avoid constant convective heat transfer coefficient, thus multiple species transport technique is employed to deal with the problem of two fluid types in a single model. In addition, the temperature dependent electrical and thermal properties of the materials are considered. The steady-state and transient thermal analysis of the GIL are performed separately with the improved model. The corresponding temperature distributions are compared with experimental results reported in the literature.

  3. Gas Classification Using Combined Features Based on a Discriminant Analysis for an Electronic Nose

    Directory of Open Access Journals (Sweden)

    Sang-Il Choi


    Full Text Available This paper proposes a gas classification method for an electronic nose (e-nose system, for which combined features that have been configured through discriminant analysis are used. First, each global feature is extracted from the entire measurement section of the data samples, while the same process is applied to the local features of the section that corresponds to the stabilization, exposure, and purge stages. The discriminative information amounts in the individual features are then measured based on the discriminant analysis, and the combined features are subsequently composed by selecting the features that have a large amount of discriminative information. Regarding a variety of volatile organic compound data, the results of the experiment show that, in a noisy environment, the proposed method exhibits classification performance that is relatively excellent compared to the other feature types.

  4. Gas chromatographic analysis of methyl formate and application in methanol poisoning cases

    Energy Technology Data Exchange (ETDEWEB)

    Fraser, A.D.; MacNeil, W. (Dalhousie Univ., Halifax, Nova Scotia (Canada))

    A modified headspace gas chromatographic method for analysis of formate in biological fluids is described. Serum or whole blood specimens were methylated in the presence of concentrated sulfuric acid and sodium propionate (internal standard) dissolved in methanol. Derivatization was performed at 35{degree}C for 30 min before injection (0.5 mL headspace) onto a Hallcomid-Carbowax packed GLC column. Using serum or aqueous standards, the method was linear from 5 to 100 mg/dL. The limit of detection was 2.5 mg/dL. Day-to-day precision was less than 5% (CV) at 54 mg/dL formate. Formate and methanol were analyzed in 3 methanol poisonings, two of which were fatal. Formate analysis is considered important in any patient with suspected methanol poisoning who presents for medical assistance with metabolic acidosis. The extent of ocular toxicity correlates better with formate concentration than with methanol concentration.

  5. Controllability analysis and decentralized control of a wet limestone flue gas desulfurization plant

    Energy Technology Data Exchange (ETDEWEB)

    Perales, A.L.V.; Ortiz, F.J.G.; Ollero, P.; Gil, F.M. [University of Seville, Seville (Spain)


    Presently, decentralized feedback control is the only control strategy used in wet limestone flue gas desulfurization (WLFGD) plants. Proper tuning of this control strategy is becoming an important issue in WLFGD plants because more stringent SO{sub 2} regulations have come into force recently. Controllability analysis is a highly valuable tool for proper design of control systems, but it has not been applied to WLFGD plants so far. In this paper a decentralized control strategy is designed and applied to a WLFGD pilot plant taking into account the conclusions of a controllability analysis. The results reveal that good SO{sub 2} control in WLFGD plants can be achieved mainly because the main disturbance of the process is well-aligned with the plant and interactions between control loops are beneficial to SO{sub 2} control.


    Directory of Open Access Journals (Sweden)

    Branko Lalić


    Full Text Available This paper explores the problem of exhaust emissions of the marine two-stroke slow-speed diesel engines. After establishing marine diesel engine regulations and defining the parameters influencing exhaust emissions, the simulation model of the marine two-stroke slow-speed diesel engine has been developed. Furthermore, the comparison of numerical and experimentally obtained data has been performed, resulting in achieving the model validity at 100% load, which represents a requirement for further exhaust gas analysis. Deviations obtained at the real engine and the model range from 2% to 7%. An analysis of the influential parameters such as compression ratio, exhaust valve timing and fuel injection timing has been performed. The obtained results have been compared and conclusions have been drawn.

  7. Bifurcation and chaos analysis of nonlinear rotor system with axial-grooved gas-lubricated journal bearing support (United States)

    Zhang, Yongfang; Hei, Di; Lü, Yanjun; Wang, Quandai; Müller, Norbert


    Axial-grooved gas-lubricated journal bearings have been widely applied to precision instrument due to their high accuracy, low friction, low noise and high stability. The rotor system with axial-grooved gas-lubricated journal bearing support is a typical nonlinear dynamic system. The nonlinear analysis measures have to be adopted to analyze the behaviors of the axial-grooved gas-lubricated journal bearing-rotor nonlinear system as the linear analysis measures fail. The bifurcation and chaos of nonlinear rotor system with three axial-grooved gas-lubricated journal bearing support are investigated by nonlinear dynamics theory. A time-dependent mathematical model is established to describe the pressure distribution in the axial-grooved compressible gas-lubricated journal bearing. The time-dependent compressible gas-lubricated Reynolds equation is solved by the differential transformation method. The gyroscopic effect of the rotor supported by gas-lubricated journal bearing with three axial grooves is taken into consideration in the model of the system, and the dynamic equation of motion is calculated by the modified Wilson- θ-based method. To analyze the unbalanced responses of the rotor system supported by finite length gas-lubricated journal bearings, such as bifurcation and chaos, the bifurcation diagram, the orbit diagram, the Poincaré map, the time series and the frequency spectrum are employed. The numerical results reveal that the nonlinear gas film forces have a significant influence on the stability of rotor system and there are the rich nonlinear phenomena, such as the periodic, period-doubling, quasi-periodic, period-4 and chaotic motion, and so on. The proposed models and numerical results can provide a theoretical direction to the design of axial-grooved gas-lubricated journal bearing-rotor system.


    Directory of Open Access Journals (Sweden)

    Tukiran Surbakti


    Full Text Available Abstract NEUTRONICS ANALYSIS ON MINI TEST FUEL IN THE RSG-GAS CORE. Research of UMo fuel for research reactor has been developing  right now. The fuel of  research reactor used is uranium low enrichment with high density. For supporting the development of fuel, an assessment of mini fuel in the RSG-GAS core was performed. The mini fuel are U7Mo-Al and U6Zr-Al with densitis of 7.0gU/cc and 5.2 gU/cc, respectively. The size of both fuel are the same namely 630x70.75x1.30 mm were inserted to the 3 plates of dummy fuel. Before being irradiated in the core, a calculation for safety analysis  from neutronics and thermohydrolics aspects were required. However, in this paper will discuss safety analysis of the U7Mo-Al and U6Zr-Al mini fuels from neutronic point of view.  The calculation was done using WIMSD-5B and Batan-3DIFF code. The result showed that both of the mini fuels could be irradiated in the RSG-GAS core with burn up less than 70 % within 12 cycles of operation without over limiting the safety margin. Power density of U7Mo-Al mini fuel bigger than U6Zr-Al fuel.   Key words: mini fuel, neutronics analysis, reactor core, safety analysis   Abstrak ANALISIS NEUTRONIK ELEMEN BAKAR UJI MINI DI TERAS RSG-GAS. Penelitian tentang bahan bakar UMo untuk reaktor riset terus berkembang saat ini. Bahan bakar reaktor riset yang digunakan adalah uranium pengkayaan rendah namun densitas tinggi.  Untuk mendukung pengembangan bahan bakar dilakukan uji elemen bakar mini di teras reakror RSG-GAS dengan tujuan menentukan jumlah siklus di dalam teras sehingga tercapai fraksi bakar maksimum. Bahan bakar yang diuji adalah U7Mo-Al dengan densitas 7,0 gU/cc dan U6Zr-Al densitas 5,2 gU/cc. Ukuran kedua bahan bakar uji tersebut adalah sama 630x70,75x1,30 mm dimasukkan masing masing kedalam 3 pelat dummy bahan bakar. Sebelum diiradiasi ke dalam teras reaktor maka perlu dilakukan perhitungan keselamatan baik secara neutronik maupun termohidrolik. Dalam makalah ini

  9. Application of gas chromatography analysis to quality control of residual organic solvents in clopidogrel bisulphate

    Directory of Open Access Journals (Sweden)

    Pavlović Aleksandar D.


    Full Text Available A direct-injection, split-mode capillary gas chromatographic procedure with a flame ionization detection is developed for the analysis of eight solvents used in the synthesis and purification of an anti-thrombotic drug clopidogrel bisulphate. The solvents analyzed were methanol, acetone, dichloromethane (DCM, 2-butanol, cyclohexane, toluene, acetic acid and N, N-dimethyl formamide (DMF. In addition, as a result of dehydration of 2-butanol during drying process, in clopidogrel bisulphate samples, significant amounts of 2-butanol dehydration products (1-butene, cis and trans isomers of 2-butene, 2,2'-oxydibutane and 1-(1-methylpropoxybutane may be detected. The content of each of these volatile products can be evaluated using the same gas-chromatographic method, with quantification based on the response factor established for the chromatographic peak of 2-butanol. For each solvent used in the process of clopidogrel bisulphate preparation, the procedure is validated for selectivity, linearity, recovery, precision, robustness, quantitation limit, and detection limit. All eight solvents plus five 2-butanol degradation products are fully separated. System suitability test is validated, and requirements are set. Based on a large number of result sets, retrospectively, from many different batches analyzed, conclusions were made about process variations and reliability and a lack of consistency was identified in the quality of the active substance from a particular producer source. Multivariate analysis was used as statistical technique to classify samples. From the analyzed set of 11 solvents, 6 of them were preselected based upon their occurrence in the samples and both Principal Component Analysis (PCA and Hierarchical Cluster Analysis (HCA were performed.

  10. Gas-well liquid-loading-field-data analysis and multiphase-flow modeling

    NARCIS (Netherlands)

    Veeken, C.A.M.; Hu, B.; Schiferli, W.


    Gas-well liquid loading occurs when gas production becomes insufficient to lift the associated liquids to surface. When that happens, gas production becomes intermittent and eventually stops. In depleting gas reservoirs, the technical abandonment pressure and ultimate recovery are typically governed

  11. A risk analysis for gas transport network planning expansion under regulatory uncertainty in Western Europe

    NARCIS (Netherlands)

    Pelletier, 27736; Wortmann, J.C.; Noteboom, H.J.


    The natural gas industry in Western Europe went through drastic changes induced by the unbundling of the national companies, followed by the liberalization of gas trade and the regulation of gas transmission. Natural gas transmission is operated through a network of interconnected grids, and is capa

  12. Roadmap for Development of Natural Gas Vehicle Fueling Infrastructructure and Analysis of Vehicular Natural Gas Consumption by Niche Sector

    Energy Technology Data Exchange (ETDEWEB)

    Stephen C. Yborra


    Vehicular natural gas consumption is on the rise, totaling nearly 200 million GGEs in 2005, despite declines in total NGV inventory in recent years. This may be attributed to greater deployment of higher fuel use medium- and heavy-duty NGVs as compared to the low fuel use of the natural gas-powered LDVs that exited the market through attrition, many of which were bi-fuel. Natural gas station counts are down to about 1100 from their peak of about 1300. Many of the stations that closed were under-utilized or not used at all while most new stations were developed with greater attention to critical business fundamentals such as site selection, projected customer counts, peak and off-peak fueling capacity needs and total station throughput. Essentially, the nation's NGV fueling infrastructure has been--and will continue--going through a 'market correction'. While current economic fundamentals have shortened payback and improved life-cycle savings for investment in NGVs and fueling infrastructure, a combination of grants and other financial incentives will still be needed to overcome general fleet market inertia to maintain status quo. Also imperative to the market's adoption of NGVs and other alternative fueled vehicle and fueling technologies is a clear statement of long-term federal government commitment to diversifying our nation's transportation fuel use portfolio and, more specifically, the role of natural gas in that policy. Based on the current NGV market there, and the continued promulgation of clean air and transportation policies, the Western Region is--and will continue to be--the dominant region for vehicular natural gas use and growth. In other regions, especially the Northeast, Mid-Atlantic states and Texas, increased awareness and attention to air quality and energy security concerns by the public and - more important, elected officials--are spurring policies and programs that facilitate deployment of NGVs and fueling

  13. Gasbuggy, New Mexico, Natural Gas and Produced Water Sampling and Analysis Results for 2011

    Energy Technology Data Exchange (ETDEWEB)



    The U.S. Department of Energy (DOE) Office of Legacy Management conducted natural gas sampling for the Gasbuggy, New Mexico, site on June 7 and 8, 2011. Natural gas sampling consists of collecting both gas samples and samples of produced water from gas production wells. Water samples from gas production wells were analyzed for gamma-emitting radionuclides, gross alpha, gross beta, and tritium. Natural gas samples were analyzed for tritium and carbon-14. ALS Laboratory Group in Fort Collins, Colorado, analyzed water samples. Isotech Laboratories in Champaign, Illinois, analyzed natural gas samples.

  14. Meta-Analysis of Microarray Data Identifies GAS6 Expression as an Independent Predictor of Poor Survival in Ovarian Cancer

    Directory of Open Access Journals (Sweden)

    Michelle Buehler


    Full Text Available Seeking new biomarkers for epithelial ovarian cancer, the fifth most common cause of death from all cancers in women and the leading cause of death from gynaecological malignancies, we performed a meta-analysis of three independent studies and compared the results in regard to clinicopathological parameters. This analysis revealed that GAS6 was highly expressed in ovarian cancer and therefore was selected as our candidate of choice. GAS6 encodes a secreted protein involved in physiological processes including cell proliferation, chemotaxis, and cell survival. We performed immunohistochemistry on various ovarian cancer tissues and found that GAS6 expression was elevated in tumour tissue samples compared to healthy control samples (. In addition, GAS6 expression was also higher in tumours from patients with residual disease compared to those without. Our data propose GAS6 as an independent predictor of poor survival, suggesting GAS6, both on the mRNA and on the protein level, as a potential biomarker for ovarian cancer. In clinical practice, the staining of a tumour biopsy for GAS6 may be useful to assess cancer prognosis and/or to monitor disease progression.

  15. A novel benzene quantitative analysis method using miniaturized metal ionization gas sensor and non-linear bistable dynamic system. (United States)

    Tang, Xuxiang; Liu, Fuqi


    In this paper, a novel benzene quantitative analysis method utilizing miniaturized metal ionization gas sensor and non-linear bistable dynamic system was investigated. Al plate anodic gas-ionization sensor was installed for electrical current-voltage data measurement. Measurement data was analyzed by non-linear bistable dynamics system. Results demonstrated that this method realized benzene concentration quantitative determination. This method is promising in laboratory safety management in benzene leak detection.

  16. Development and optimization of the procedure of gas- chromatographic elemental analysis of high-carbon solid fossil fuels

    Energy Technology Data Exchange (ETDEWEB)

    Platonov, V.V.; Shvykin, A.Y.; Proskuryakov, V.A.; Podshibyakin, S.I.; Chilachava, K.B.; Khmarin, E.M.; Solov' ev, A.S. [Tolstoy Tula State Pedagogical University, Tula (Russian Federation)


    A procedure was developed for gas-chromatographic elemental analysis of coals. The conditions of exhaustive oxidation of weighed microportions of the coals were optimized. The procedure of calculating the results of analysis was modified with the aim to improve its reproducibility.

  17. Comparative QRA (Quantitative Risk Analysis) of natural gas distribution pipelines in urban areas; Analise comparativa dos riscos da operacao de linhas de gas natural em areas urbanas

    Energy Technology Data Exchange (ETDEWEB)

    Oliveira, Luiz Fernando S. de [Energy Solutions South America (Brazil); Cardoso, Cassia de O.; Storch, Rafael [Det Norske Veritas (DNV) (Brazil)


    The natural gas pipeline network grows around the world, but its operation inherently imposes a risk to the people living next to pipelines. Due to this, it is necessary to conduct a risk analysis during the environmental licensing in Brazil. Despite the risk analysis methodology is well established, some points of its application for the distribution pipelines are still under discussion. This paper presents a methodology that examines the influences of major projects and operating parameters on the risk calculation of a distribution pipeline accident in urban areas as well as the possible accident scenarios assessment complexity. The impact of some scenarios has been evaluated using a Computational Fluid Dynamics tool. The results indicate that, under certain conditions, the risks from the pipeline operation under operating pressures of 20 bar may be acceptable in location class 3 or even in class 4. These results play a very important role if management decisions on the growth of the distribution of natural gas network in densely populated areas as well as in the improvement of laws to control the activity of distribution of natural gas. (author)

  18. High-temperature two-dimensional gas chromatography of hydrocarbons up to nC60 for analysis of vacuum gas oils. (United States)

    Dutriez, Thomas; Courtiade, Marion; Thiébaut, Didier; Dulot, Hugues; Bertoncini, Fabrice; Vial, Jérôme; Hennion, Marie-Claire


    In a tense energetic context, the characterization of heavy petroleum fractions becomes essential. Conventional comprehensive two-dimensional gas chromatography (2D-GC or GCxGC) is widely used for middle distillates analysis, but only a few applications are devoted to these heavier fractions. In this paper, it is shown how the optimization of GCxGC separation allowed the determination of suitable high-temperature (HT) conditions, adjusting column properties and operating conditions. 2D separations were evaluated using 2D separation criteria and a new concept of 2D asymmetry (As(2D)). New HT conditions allowed the extension of GCxGC range of applications to heavier hydrocarbons, up to nC(60). A first application of high-temperature two-dimensional gas chromatography (HT-2D-GC) to a full vacuum gas oil (VGO) feed stock is described. Comparisons with other standardized methods illustrate the high potential of HT-2D-GC for heavy fractions analysis.

  19. Applications of laser-photoacoustic gas analysis method; Fotoakustisen kaasuanalyysin sovelluksia. Fotoakustiset mittaukset paineistetussa poelyvirtausreaktorissa

    Energy Technology Data Exchange (ETDEWEB)

    Hernberg, R.; Stenberg, J. [Tampere Univ. of Technology (Finland). Lab. of Plasma Technology


    Laser induced photoacoustic spectroscopy has been developed in LIEKKI and LIEKKI 2 research programs. The method is intended for In-Situ analysis of gaseous components in hot and reactive environments such as combustion conditions. The method and the instrumentation developed in this project have been calibrated for SO{sub 2}, NO, NO{sub 2}, NH{sub 3}, N{sub 2}O, and H{sub 2}S between 20 and 860 deg C at atmospheric pressure. Calibrations at elevated pressures have been performed for NO{sub 2}, NO, SO{sub 2}, NH{sub 3} and N{sub 2}O. Calibration for OH radical has also been performed. A known concentration of OH was generated by thermally decomposing H{sub 2}O at temperatures between 900 and 1050 deg C. The photoacoustic method has earlier been applied to the chemical analysis of burning CH{sub 4}/HCN/O{sub 2}/N{sub 2} flame at pressures between 1 and 6 bar. The formation of NO and NH{sub 3} measured in post-flame conditions. The relative concentration of OH in the reactive zone of the flame was measured between 1 and 6 bar pressures. The method was also applied to measurements in circulating fluidized bed (CFB). Time resolved gas concentrations were measured at three different heights above the air distributor with a specialized probe. In this project the photoacoustic method is applied in studies regarding the effect of chlorine (Cl) on combustion chemistry. The second goal of this project is to make In-Situ measurements of the formation of NO{sub 2} in combustion. The formation of NO{sub 2} increases strongly at elevated pressures. Due to the instability of NO{sub 2} the analysis is prone to errors with conventional gas sampling probes

  20. A rapid analysis of plasma/serum ethylene and propylene glycol by headspace gas chromatography. (United States)

    Ehlers, Alexandra; Morris, Cory; Krasowski, Matthew D


    A rapid headspace-gas chromatography (HS-GC) method was developed for the analysis of ethylene glycol and propylene glycol in plasma and serum specimens using 1,3-propanediol as the internal standard. The method employed a single-step derivitization using phenylboronic acid, was linear to 200 mg/dL and had a lower limit of quantitation of 1 mg/dL suitable for clinical analyses. The analytical method described allows for laboratories with HS-GC instrumentation to analyze ethanol, methanol, isopropanol, ethylene glycol, and propylene glycol on a single instrument with rapid switch-over from alcohols to glycols analysis. In addition to the novel HS-GC method, a retrospective analysis of patient specimens containing ethylene glycol and propylene glycol was also described. A total of 36 patients ingested ethylene glycol, including 3 patients who presented with two separate admissions for ethylene glycol toxicity. Laboratory studies on presentation to hospital for these patients showed both osmolal and anion gap in 13 patients, osmolal but not anion gap in 13 patients, anion but not osmolal gap in 8 patients, and 1 patient with neither an osmolal nor anion gap. Acidosis on arterial blood gas was present in 13 cases. Only one fatality was seen; this was a patient with initial serum ethylene glycol concentration of 1282 mg/dL who died on third day of hospitalization. Propylene glycol was common in patients being managed for toxic ingestions, and was often attributed to iatrogenic administration of propylene glycol-containing medications such as activated charcoal and intravenous lorazepam. In six patients, propylene glycol contributed to an abnormally high osmolal gap. The common presence of propylene glycol in hospitalized patients emphasizes the importance of being able to identify both ethylene glycol and propylene glycol by chromatographic methods.

  1. Double pulse spectrochemical analysis using orthogonal geometry with very low ablation energy and He ambient gas

    Energy Technology Data Exchange (ETDEWEB)

    Suliyanti, Maria Margaretha; Hidayah, Affi Nur; Pardede, Marincan; Jobiliong, Eric; Abdulmadjid, Syahrun Nur; Idris, Nasrullah; Ramli, Muliadi; Lie, Tjung Jie; Hedwig, Rinda; Tjia, May On [Research Center of Maju Makmur Mandiri Foundation, 40/80 Srengseng Raya, Kembangan, Jakarta Barat 11630 (Indonesia); Kurniawan, Koo Hendrik, E-mail: [Research Center of Maju Makmur Mandiri Foundation, 40/80 Srengseng Raya, Kembangan, Jakarta Barat 11630 (Indonesia); Lie, Zener Sukra; Niki, Hideaki [Program of Nuclear Power and Energy Safety Engineering, Graduate School of Engineering, University of Fukui, Fukui 910-8507 (Japan); Kagawa, Kichiro [Research Institute of Nuclear Engineering, University of Fukui, Fukui 910-8507 (Japan)


    An experimental study of double pulse LIBS is performed for the development of highly sensitive and quantitative analysis of Cl and Ca for the strength evaluation of concrete. The two lasers employed are arranged in orthogonal geometry and operated for delayed ablation with delay time of 10 {mu}s, using He ambient gas at atmospheric pressure. The very large intensity enhancement is obtained over those detected with single pulse operation without generating the He plasma. It is most remarkable that the same sharpness and intensity enhancement observed in the previous double pulse experiment with 37 mJ laser ablation energy is achieved in the present experiment with much lower ablation energy of merely 2.5 mJ, resulting in average crater size of about 10 {mu}m in diameter. Further, a linear relation is obtained between the Cl concentration and its emission intensity in alumina samples, while an estimated limit of detection of 80 ppm is obtained by using concrete sample, which is adequate for highly sensitive quantitative Cl analysis in concrete. - Highlights: Black-Right-Pointing-Pointer Double pulse LIBS is used for sensitive and quantitative analysis of Cl and Ca. Black-Right-Pointing-Pointer The 2 lasers employed in orthogonal geometry and with delay of 10 {mu}s for ablation. Black-Right-Pointing-Pointer He ambient gas was used at atmospheric pressure. Black-Right-Pointing-Pointer Strong Ca and Cl emissions were detected at 2.5 mJ laser energy with small crater. Black-Right-Pointing-Pointer Linear calibration for Cl was obtained with detection limit of 80 ppm.

  2. Validation of Eulerian modeling of gas-solid fluidized beds using nonlinear analysis (United States)

    Norouzi, Y.; Norouzi, H. R.; Zarghami, R.


    In the present work, the new advanced method has been used for validation of two-fluid method (TFM) for modeling of the hydrodynamics of gas-solid fluidized beds. While many investigations were addressed validation of the CFD codes, less effort has been made to validate the nonlinear dynamics of fluidized beds with nonlinear methods. In this work new advanced nonlinear methods of recurrence plot (RP) and recurrence quantification analysis (RQA) have been used to validate the hydrodynamics modeling of the gas-solid fluidized beds. Pressure fluctuations of inside the bed were selected for comparing the nonlinear dynamics of fluidized bed in experiments and simulations. Pressure fluctuations were measured in a rectangle fluidized bed containing Geldart's group B particles with sampling frequency 400 Hz. Simulations were done with the same operating condition and pressure fluctuations were recorded with the same sampling frequency. The superficial air velocity range was 0.25-0.73 m/s (bubbling regime) and two aspect ratios 1 and 1.5 were used. The results of experiments and simulations were analyzed by RP and RQA. The values of laminarity, determinism, and recurrence rate for both experiments and simulations are close to each other. The experimental and simulation results showed high values for determinism and laminarity which show predictable and periodic behaviors of both systems. High values of determinism and laminarity are one of the most important characteristics of bubbling regime in which bubbles are periodically produced and move in the bed. In the entire gas velocity, the values of determinism and laminarity were not changed significantly that shows that no regime change occurred in the bed.

  3. Contributions to the neutronic analysis of a gas-cooled fast reactor

    Energy Technology Data Exchange (ETDEWEB)

    Martin-del-Campo, Cecilia, E-mail: [Departamento de Sistemas Energeticos, Facultad de Ingenieria, Universidad Nacional Autonoma de Mexico, Paseo Cuauhnahuac 8532. Jiutepec, Morelos (Mexico); Reyes-Ramirez, Ricardo, E-mail: [Departamento de Sistemas Energeticos, Facultad de Ingenieria, Universidad Nacional Autonoma de Mexico, Paseo Cuauhnahuac 8532. Jiutepec, Morelos (Mexico); Francois, Juan-Luis, E-mail: [Departamento de Sistemas Energeticos, Facultad de Ingenieria, Universidad Nacional Autonoma de Mexico, Paseo Cuauhnahuac 8532. Jiutepec, Morelos (Mexico); Reinking-Cejudo, Arturo G., E-mail: [Departamento de Sistemas Energeticos, Facultad de Ingenieria, Universidad Nacional Autonoma de Mexico, Paseo Cuauhnahuac 8532. Jiutepec, Morelos (Mexico)


    Highlights: > Differences on reactivity with MCNPX and TRIPOLI-4 are negligible. > Fuel lattice and core criticality calculations were done. > A higher Doppler coefficient than coolant density coefficient. > Zirconium carbide is a better reflector than silicon carbide. > Adequate active height, radial size and reflector thickness were obtained. - Abstract: In this work the Monte Carlo codes MCNPX and TRIPOLI-4 were used to perform the criticality calculations of the fuel assembly and the core configuration of a gas-cooled fast reactor (GFR) concept, currently in development. The objective is to make contributions to the neutronic analysis of a gas-cooled fast reactor. In this study the fuel assembly is based on a hexagonal lattice of fuel-pins. The materials used are uranium and plutonium carbide as fuel, silicon carbide as cladding, and helium gas as coolant. Criticality calculations were done for a fuel assembly where the axial reflector thickness was varied in order to find the optimal thickness. In order to determine the best material to be used as a reflector, in the reactor core with neutrons of high energy spectrum, criticality calculations were done for three reflector materials: zirconium carbide, silicon carbide and natural uranium. It was found that the zirconium carbide provides the best neutron reflection. Criticality calculations using different active heights were done to determine the optimal height, and the reflector thickness was adjusted. Core criticality calculations were performed with different radius sizes to determine the active radial dimension of the core. A negative temperature coefficient of reactivity was verified for the fuel. The effect on reactivity produced by changes in the coolant density was also evaluated. We present the main neutronic characteristics of a preliminary fuel and core designs for the GFR concept. ENDF-VI cross-sections libraries were used in both the MCNPX and TRIPOLI-4 codes, and we verified that the obtained

  4. Statistical Analysis of Partial Discharges in SF6 Gas via Optical Detection in Various Spectral Ranges

    Directory of Open Access Journals (Sweden)

    Ming Ren


    Full Text Available Partial discharge (PD detection is essential to the operation of high-voltage systems. In this context, we investigate the basic characteristics of light emission during PDs in SF6 gas from the perspective of insulation diagnosis. A synchronous system is constructed using three optical photoelectric instruments with separate wavelength responses in the ultraviolet (UV, 189–352 nm, visible (VIS, 381–675 nm, and near-infrared (NIR, 737–920 nm spectral ranges and a wide-band PD current pulse detector with a response of 1 pC. The results indicate that light emission depends upon the type of insulation defect and discharge energy. An increase in PD charge gives rise to more components in the spectral range from UV to VIS, and the presence of an insulator surface in discharges yields a more complex VIS-to-NIR spectrum. The phase-resolved partial discharge pattern (PRPD of UV light pulses can reasonably reflect the electroluminescence process in the presence of the insulator surface and weak corona at negative voltage points. The PRPD of VIS light describes the features of the actual PD pattern in most cases. In comparison with the other two spectral ranges, light intensity in the VIS range is more sensitive to changes in gas-pressure-normalized voltage (Vrms/p. The linear fitting analysis of the relationships between the light intensity and PD charge shows that UV light detection has a greater sensitivity to the PD charge and that UV detection exhibits a greater degree of linearity. NIR detection is applicable only to severe PDs. We believe that our findings can significantly aid in application of optical PD diagnosis in SF6 gas insulated systems.

  5. Authentication of beeswax (Apis mellifera) by high-temperature gas chromatography and chemometric analysis. (United States)

    Maia, Miguel; Nunes, Fernando M


    Chemical characterization and authentication of beeswax of Apis mellifera was performed by high temperature capillary gas chromatography coupled to electron impact mass spectrometry or to flame ionisation detection and chemometric analysis. Many major components (>50) of beeswax, odd and even hydrocarbons, oleofin, palmitate, oleate and hydroxypalmitate monoesters were detected, and for the first time palmitate and oleate monoesters esterified with 1-octadecanol and 1-eicosanol are reported to be present in beeswax. Unsupervised pattern recognition procedures, cluster analysis and principal component analysis, were used to find data patterns and successfully differentiate authentic and paraffin adulterated beeswax based on the chemical profile obtained. Independent assessment of beeswax quality and performance of the unsupervised classification methods were performed using classical analytical parameters. The discrimination power of the chemometric unsupervised methods for detection of paraffin adulterated beeswax was superior to the discriminating power of classical analytical parameters. Using linear discriminant analysis, classification rules for authentic and paraffin adulterated beeswax samples were developed. The model was validated by leave-one-out cross validation and showed good recognition and prediction abilities, 100% and 99%, respectively.

  6. Application of energy and exergy analysis to increase efficiency of a hot water gas fired boiler

    Directory of Open Access Journals (Sweden)

    Todorović Milena N.


    Full Text Available In engineering practice exergy can be used for technical and economic optimization of energy conversion processes. The problem of increasing energy consumption suggests that heating plants, i.e. hot water boilers, as energy suppliers for household heating should be subjected to exergy and energy analysis. Heating plants are typically designed to meet energy demands, without the distinguished difference between quality and quantity of the produced heat. In this paper, the energy and exergy analysis of a gas fired hot water boiler is conducted. Energy analysis gives only quantitative results, while exergy analysis provides an insight into the actually available useful energy with respect to the system environment. In this paper, a hot water boiler was decomposed into control volumes with respect to its functional components. Energy and exergy of the created physical model of the hot water boiler is performed and destruction of exergy and energy loss in each of the components is calculated. The paper describes the current state of energy and exergy efficiency of the hot water boiler. The obtained results are analyzed and used to investigate possibilities for improvement of availability and reliability of the boiler. A comparison between the actual and the proposed more reliable solution is made.

  7. Financial Risk Factor Analysis for Facility Gas Leakages of H2 and NG

    Directory of Open Access Journals (Sweden)

    In-Bok Lee


    Full Text Available Fuel cells may be the key to a more environmentally-friendly future because they emit low carbon dioxide per unit of energy supplied. However, little work has investigated the potential financial risks pertaining to fuel cell systems. Often used in the analysis of the safety of systems involving flammable or hazardous materials, risk factor analysis has recently been used to analyze the potential financial losses that may occur from industrial hazards. Therefore, this work undertakes a financial risk factor analysis to determine the costs of leakages of hydrogen and natural gas, which are used in fuel cell systems. Total leakage was calculated from an analysis of several leakage rates and modes. The impact of applying appropriate detection and prevention systems was also investigated. The findings were then used to analyze the consequences for various sections of the system and to calculate the overall cost based on facility outage or damage, and the cost of taking safety precautions. This provides a basis for comparison among proposed potential reactionary measures.

  8. Nonstandard Analysis and Shock Wave Jump Conditions in a One-Dimensional Compressible Gas

    Energy Technology Data Exchange (ETDEWEB)

    Roy S. Baty, F. Farassat, John A. Hargreaves


    Nonstandard analysis is a relatively new area of mathematics in which infinitesimal numbers can be defined and manipulated rigorously like real numbers. This report presents a fairly comprehensive tutorial on nonstandard analysis for physicists and engineers with many examples applicable to generalized functions. To demonstrate the power of the subject, the problem of shock wave jump conditions is studied for a one-dimensional compressible gas. It is assumed that the shock thickness occurs on an infinitesimal interval and the jump functions in the thermodynamic and fluid dynamic parameters occur smoothly across this interval. To use conservations laws, smooth pre-distributions of the Dirac delta measure are applied whose supports are contained within the shock thickness. Furthermore, smooth pre-distributions of the Heaviside function are applied which vary from zero to one across the shock wave. It is shown that if the equations of motion are expressed in nonconservative form then the relationships between the jump functions for the flow parameters may be found unambiguously. The analysis yields the classical Rankine-Hugoniot jump conditions for an inviscid shock wave. Moreover, non-monotonic entropy jump conditions are obtained for both inviscid and viscous flows. The report shows that products of generalized functions may be defined consistently using nonstandard analysis; however, physically meaningful products of generalized functions must be determined from the physics of the problem and not the mathematical form of the governing equations.

  9. Design Optimization And Thermal Analysis Of Multipurpose Refrigerant Gas Recovery Machine: An Innovative Approach (United States)

    Jirapure, Sagar C.


    Today on the global scene, world will see a definite impact of global temperatures, coupled with burgeoning population, will make society more vulnerable to climatic disorder, drought, famines, and flood longer heat waves spreading to newer areas. Tropical islands and low-lying coastal areas will face the treat of being submerged. Hence, it is important to reduce refrigerant emission and the approaching and with approaching phase out date for CFC elimination. It is important to recover as much of refrigerant as possible. Likewise, HFCs should also be recovered as they have high GWP. For such recovery of refrigerant, a recovery & recycling machine is required. The machine is usually comprising a hermetic compressor, air-cooled condenser, distilator, Oil separator, filters and Electric motor. The refrigerant from the appliances is drown through the filters by compressor and then discharged into recovery cylinder. The recovery cylinder should just be used for recovered refrigerant. This is because oil will usually be covered with refrigerant and this will contaminate the cylinder. It is therefore very important to treat the recovery of refrigerant at most accuracy, which require close optimization of design and further analysis of gas behavior in the system. This project aims to provide optimum solution as regards to thermal analysis of gas recovery machine. For getting insight the parameters like Specific heat of vapor at constant pressure, Density of saturated vapor, Latent heat of vaporization at boiling point, Thermal conductivity of vapor, Surface tension, etc. will require critical approach. To impart the thermal analysis, ANSYS software is proposed. It in turn provides the details of temperatures through out the piping of machine, pressure and velocity of at various locations of different components as well as the thermal zones near to high pressure and temperatures in the machine, which gives better approach for design of future gas recovery machines. It is

  10. Design and Analysis of SAW Based MEMS Gas Sensor for the Detection of Volatile Organic Gases

    Directory of Open Access Journals (Sweden)

    Staline Johnson


    Full Text Available This paper portrays the design and analysis of SAW based MEMS gas sensor for the detection of volatile organic gases. The gas sensor consists of interdigitated transducers modeled on a piezoelectric substrate and covered by a thin film of polyisobutylene (PIB which acts as the sensing layer. The piezoelectric substrate material used is YZ cut Lithium Niobate (LiNbO3 and electrodes used are made of Aluminium (Al. Mass loading effect on the sensing layer is used for the detection of volatile organic gases. The design and simultions were carried out by using comsol multiphysics software based on Finite Element Method (FEM for analytical simulations. The resonant frequency of the SAW device was determined and simulations are carried out by exposing the sensor to 100 ppm of various volatile organic gases and corresponding shift in resonant frequency for various gases are determined. The reduction in the resonant frequency is used for the detection of volatile organic gases such as chloromethane, dichloromethane, trichloromethane, tetrachloroethene, carbon tetrachloride and trichloroethylene.

  11. Thermochemical Analysis of Gas-Cooled Reactor Fuels Containing Am and Pu Oxides

    Energy Technology Data Exchange (ETDEWEB)

    Lindemer, T.B.


    Literature values and estimated data for the thermodynamics of the actinide oxides and fission products are applied to explain the chemical behavior in gas-cooled-reactor fuels. Emphasis is placed on the Am-O-C and Pu-O-C systems and the data are used to plot the oxygen chemical potential versus temperature of solid-solid and solid-gas equilibria. These results help explain observations of vaporization in Am oxides, nitrides, and carbides and provide guidance for the ceramic processing of the fuels. The thermodynamic analysis is then extended to the fission product systems and the Si-C-O system. Existing data on oxygen release (primarily as CO) as a function of burnup in the thoria-urania fuel system is reviewed and compared to values calculated from thermodynamic data. The calculations of oxygen release are then extended to the plutonia and americia fuels. Use of ZrC not only as a particle coating that may be more resistant to corrosion by Pd and other noble-metal fission products, but also as a means to getter oxygen released by fission is discussed.

  12. On the exergy disaggregation for thermoeconomic analysis of a gas turbine cogeneration system

    Energy Technology Data Exchange (ETDEWEB)

    Santos, Jose Joaquim Conceicao Soares [Federal University of Espirito Santo - UFES/DEM, Goiabeiras, Vitoria, ES (Brazil); Silva, Julio Augusto Mendes da [University of Sao Paulo, Sao Paulo, SP (Brazil)], e-mail:; Palacio, Jose Carlos Escobar [Federal University of Itajuba, Itajuba, MG (Brazil); Moreira, Hugo Lima [Federal Rural University of Amazonia, Belem, PA (Brazil)


    Most analysts agree that exergy, instead of enthalpy only, is the most adequate thermodynamic quantity to associate with cost. Therefore, all thermoeconomic methodologies use the exergy to define productive structure. Sometimes, under a thermoeconomic analysis point of view, it is necessary to consider a mass or an energy flow rate consisting of several exergy components, for example thermal, mechanical and chemical components. Most analysts agree that by considering separate exergy forms the accuracy of the results is improved in thermoeconomics. However, these analysts recognize that the disaggregation of physical exergy might not be always reasonably because of the increase in the computational efforts. Thus, the main questions are: Is this improvement often marginal? Is exergy disaggregation necessary for extracting the main conclusions? This paper aims at answering these questions for the case of external fuel (natural gas) exergy allocation to the two final products (heat and power) of a gas turbine cogeneration system, by applying four different productive structures based on different kind and level of physical exergy disaggregation. The paper also shown that the model that uses enthalpy together with sintropy presents the closest result in relation to the total disaggregated model, showing the rationality of this methodology that intrinsically allocate the residues to the components of the cycle using the entropy variation in each component as a weighting factor. (author)

  13. A thermodynamic analysis of gas adsorption on microporous materials: evaluation of energy heterogeneity. (United States)

    Llorens, Joan; Pera-Titus, Marc


    This paper presents a thermodynamic isotherm derived from solution thermodynamics principles to describe gas adsorption on microporous materials. This isotherm relies on a potential relationship between the integral free energy of adsorption relative to saturation, Psi/RT, expressed by the Kiselev equation, and the variable Z = 1/-Ln(Pi), being Pi the relative pressure. A mathematical analysis reveals that the adsorption energy heterogeneity in the micropores is collected in a characteristic parameter of the isotherm, m, that can be related to the alpha parameter of the Dubinin-Astakhov isotherm in a simple way (m = alpha + 1). The isotherm also predicts a plateau in Psi/RT at extremely low pressures (Pi < 10(-7)). Neimark's thermodynamic equation accounting for gas adsorption on mesoporous solids is found to be a particular case of the isotherm presented in this study. The Langmuir isotherm only shows consistency with the thermodynamic isotherm for a reduced combination of values of the relevant parameters, not usually found in common adsorbents. The suitability of the thermodynamic isotherm is experimentally assessed by testing a collection of microporous materials, including activated carbons, carbon nanotubes, and zeolites.

  14. Risk assessment of Kermanshah gas storage tanks by energy trace and barrier analysis (2014

    Directory of Open Access Journals (Sweden)

    M. Ghanbari Kakavandi


    Full Text Available Background: Despite the cost and millions loss of life due to industrial accidents, often are preventable through risk assessment methods and control measures. Objective: To assess the safety of gas storage tanks in Kermanshah oil refinery by Energy Trace and Barrier Analysis (ETBA. Methods: This case-descriptive study was conducted in gas storage tanks of Kermanshah oil refinery. Energy checklist was used for identification of energy types. Energy flows were tracked and then, management and administrative procedures, and personal protective equipment were considered as safeguard. Exposed and vulnerable targets are also specified. Preliminary levels of risks were determined by combination of severity and likelihood. After suggestion of corrective action for unacceptable risks, risk assessment took place again. Identified risks were expressed using descriptive statistics such as frequency and percentage. Findings: Overall, 74 risks and 121 dangerous energies were identified. Of these, 25 risks were unacceptable, 46 were low risk, and 3 were acceptable risk with revised. Frequency of risks related to electric power was 20, and followed by risk of displacement- pressure-volume, potential and chemical energies, with frequencies of 13, 12 and 9, respectively. Conclusion: Given the environmental and protection conditions of the tanks, in addition, the high percentage of some of the damaging risks in this industry, use of appropriate control measures to prevention the event of future disasters will be inevitable.

  15. Analysis of carrier gas flow rate effect on hydroxyapatite particle formation in ultrasonic spray pyrolysis (United States)

    Widiyastuti, W.; Setiawan, Adhi; Nurtono, Tantular; Winardi, Sugeng


    Ultrasonic spray pyrolysis has been well-known process for producing fine particles from single and multicomponent materials. Here, the effect of carrier gas flow rate in ultrasonic spray pyrolysis process was studied in the particle formation of hydroxyapatite using solution precursor of Ca(CH3COO)2 and (NH4)2HPO4 with Ca/P ratio of 1.67. The experimental analysis was accompanied with computational fluid dynamics (CFD) simulation for comparison. In the simulation, the evaporation of the solvent in the droplets, a second evaporation due to crust formation, the decomposition reaction of the precursor involving the transfer of heat and mass transfer from droplet to surrounding were considered. By maintaining temperature at 900 °C, the residence time increased with decreasing the carrier gas flow rate led to the increasing the evaporation rate and the reacted fraction of the precursor. The predicted and experimental results of average particles size were agreed well with discrepancy 6.3%.

  16. Well-to-Wheels Analysis of Compressed Natural Gas and Ethanol from Municipal Solid Waste

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Uisung [Argonne National Lab. (ANL), Argonne, IL (United States). Energy Systems Division; Han, Jeongwoo [Argonne National Lab. (ANL), Argonne, IL (United States). Energy Systems Division; Wang, Michael [Argonne National Lab. (ANL), Argonne, IL (United States). Energy Systems Division


    The amount of municipal solid waste (MSW) generated in the United States was estimated at 254 million wet tons in 2013, and around half of that generated waste was landfilled. There is a huge potential in recovering energy from that waste, since around 60% of landfilled material is biomass-derived waste that has high energy content. In addition, diverting waste for fuel production avoids huge fugitive emissions from landfills, especially uncontrolled CH4 emissions, which are the third largest anthropogenic CH4 source in the United States. Lifecycle analysis (LCA) is typically used to evaluate the environmental impact of alternative fuel production pathways. LCA of transportation fuels is called well-to-wheels (WTW) and covers all stages of the fuel production pathways, from feedstock recovery (well) to vehicle operation (wheels). In this study, the Greenhouse Gases, Regulated Emissions, and Energy Use in Transportation (GREET®) model developed by Argonne National Laboratory is used to evaluate WTW greenhouse gas (GHG) emissions and fossil fuel consumption of waste-derived fuels. Two waste-to-energy (WTE) pathways have been evaluated – one for compressed natural gas (CNG) production using food waste via anaerobic digestion, and the other for ethanol production from yard trimmings via fermentation processes. Because the fuel production pathways displace current waste management practices (i.e., landfilling waste), we use a marginal approach that considers only the differences in emissions between the counterfactual case and the alternative fuel production case.

  17. Theoretical Analysis of Thermodynamic Measurements near a Liquid-Gas Critical Point (United States)

    Barmatz, M.; Zhong, Fang; Hahn, Inseob


    Over the years, many ground-based studies have been performed near liquid-gas critical points to elucidate the expected divergences in thermodynamic quantities. The unambiguous interpretation of these studies very near the critical point is hindered by a gravity-induced density stratification. However, these ground-based measurements can give insight into the crossover behavior between the asymptotic critical region near the transition and the mean field region farther away. We have completed a detailed analysis of heat capacity, susceptibility and coexistence curve measurements near the He-3 liquid-gas critical point using the minimal-subtraction renormalization (MSR) scheme within the phi(exp 4) model. This MSR scheme, using only two adjustable parameters, provides a reasonable global fit to all of these experimental measurements in the gravity-free region out to a reduced temperature of |t| approx. 2x10(exp -2). Recently this approach has also been applied to the earlier microgravity measurements of Haupt and Straub in SF(sub 6) with surprising results. The conclusions drawn from the MSR analyses will be presented. Measurements in the gravity-affected region closer to the He-3 critical point have also been analyzed using the recent crossover parametric model (CPM) of the equation-of-state. The results of fitting heat capacity measurements to the CPM model along the He-3 critical isochore in the gravity-affected region will also be presented.

  18. Thermoeconomic analysis of Biomass Integrated Gasification Gas Turbine Combined Cycle (BIG GT CC) cogeneration plant

    Energy Technology Data Exchange (ETDEWEB)

    Arrieta, Felipe Raul Ponce; Lora, Electo Silva [Escola Federal de Engenharia de Itajuba, MG (Brazil). Nucleo de Estudos de Sistemas Termicos]. E-mails:;; Perez, Silvia Azucena Nebra de [Universidade Estadual de Campinas, SP (Brazil). Faculdade de Engenharia Mecanica. Dept. de Energia]. E-mail: sanebra@fem.


    Using thermoeconomics as a tool to identify the location and magnitude of the real thermodynamic losses (energy waste, or exergy destruction and exergy losses) it is possible to assess the production costs of each product (electric power and heat) and the exergetic and exergoeconomic cost of each flow in a cogeneration plant to assist in decision-marketing procedures concerning to plant design, investment, operation and allocations of research funds. Thermo economic analysis of Biomass Integrated Gasification Gas Turbine Combined Cycle (BIG GT CC) cogeneration plant for its applications in sugar cane mills brings the following results: the global exergetic efficiency is low; the highest irreversibilities occur in the following equipment, by order: scrubber (38%), gas turbine (16%), dryer (12%), gasifier and HRSG (6%); due to the adopted cost distribution methodology, the unit exergetic cost of the heat (4,11) is lower than electricity (4,71); the lower market price of biomass is one of the most sensible parameter in the possible implementation of BIG-GT technology in sugar cane industry; the production costs are 31 US$/MWh and 32 US$/MWh for electricity and heat, respectively. The electricity cost is, after all, competitive with the actual market price. The electricity and heat costs are lower or almost equal than other values reported for actual Rankine cycle cogeneration plants. (author)

  19. Thermal hydrodynamic analysis of a countercurrent gas centrifuge; Analise termo hidrodinamica de uma centrifuga a contracorrente

    Energy Technology Data Exchange (ETDEWEB)

    Andrade, Delvonei Alves de


    The influence of the thermal countercurrent on the separative performance of countercurrent centrifuges is treated in this work. The methodology used consists in modeling the gas flow inside the rotor under thermal boundary conditions supplied by the structural thermal model. The gas flow model, also called hydrodynamical model, is based on the Finite Volume Method for cylindrical geometry with azimuthal symmetry. The structural thermal model is based on the Nodal Method and take into account simultaneously, the conduction convection and radiation phenomena. The procedure adopted for this study consisted in the definition of the operational and geometric conditions of a centrifuge which was used as a pattern to the accomplished analysis. This configuration, called 'Standard Centrifuge', was used for the accomplishment of several simulations where the importance of the realistic boundary thermal conditions for the numerical evaluation of the centrifuge separative capacity was evidenced. A selective alteration for the optical properties based on simple engineering procedures was proposed. An improvement of 5% was obtained with this alteration. (author)

  20. Pressure Transient Analysis of Multi-Fractured Horizontal Well in Tight Gas Reservoirs

    Directory of Open Access Journals (Sweden)

    Zhao Ermeng


    Full Text Available Multi-fractured horizontal well is applied in tight gas reservoirs due to the low permeability. A new pressure transient model of multi-fractured horizontal well based on discrete-fracture model in which the hydraulic fractures are discretized as 2D entities is built in this paper, The model is divided into hydraulic fracture region and formation region. The model can be solved using the Galerkin finite element method, then the pressure transient type curves are plotted by computer programming. The results show that there are five different flow regimes observed in type curves including early linear flow, early radial flow, elliptical flow, later pseudo-radial flow and boundary response regime. A sensitivity analysis is conducted to study impacts of hydraulic fracture number, hydraulic fracture half-length, hydraulic fracture spacing, and hydraulic fracture conductivity on pressure transient type curves. The new model and obtained results in this paper not only enrich the well testing models, but also play a guiding role in analyzing pressure transient response of multi-fractured horizontal well in tight gas reservoirs.

  1. A combination of energy method and spectral analysis for study of equations of gas motion

    Institute of Scientific and Technical Information of China (English)

    Renjun DUAN; Seiji UKAI; Tong YANG


    There have been extensive studies on the large time behavior of solutions to systems on gas motions, such as the Navier-Stokes equations and the Boltzmann equation. Recently, an approach is introduced by combining the energy method and the spectral analysis to the study of the optimal rates of convergence to the asymptotic profiles. In this paper, we will first illustrate this method by using some simple model and then we will present some recent results on the Navier-Stokes equations and the Boltzmann equation. Precisely, we prove the stability of the non-trivial steady state for the Navier-Stokes equations with potential forces and also obtain the optimal rate of convergence of solutions toward the steady state. The same issue was also studied for the Boltzmann equation in the presence of the general time-space dependent forces. It is expected that this approach can also be applied to other dissipative systems in fluid dynamics and kinetic models such as the model system of radiating gas and the Vlasov-Poisson-Boltzmann system.

  2. Analysis to the entangled states from an extended Chaplygin gas model

    CERN Document Server

    Meng, X H; Ren, J; Meng, Xin He; Hu, Ming Guang; Ren, Jie


    With considerations of the recently released WMAP year three and supernova legacy survey (SNLS) data set analysis that favors models similar to the $% \\Lambda CDM$ model by possibly mild fluctuations around the vacuum energy or the cosmological constant, we extend the original Chaplygin Gas model (ECG) via modifying the Chaplygin Gas equation of state by two parameters to describe an entangled mixture state from an available matter and the rest component (which can take the cosmological constant or dark energy as in the current cosmic stage, or `curvature-like' term, or radiation component in the early epoch, as various phases) coexistence. At low redshifts, the connection of the ECG model and the Born-infeld field is set up. As paradigms, we use the data coming from the recently released SNLS for the first year and also the famous 157 type Ia supernova (Ia SNe) gold dataset to constrain the model parameters. The restricted results demonstrate clearly how large the entangled degree or the ratio between the en...

  3. Sales analysis as a basis for optimising gas procurement; Absatzanalyse als Grundlage optimierter Gasbeschaffung

    Energy Technology Data Exchange (ETDEWEB)

    Jungblut, Ralf [RWE Vertrieb AG, Dortmund (Germany). Produktmanagement, Marketing und Datenmanagement


    German energy suppliers are finding themselves in an increasingly difficult situation in the gas market. With the natural gas glut subsiding and global demand picking up, gas prices are expected to rise over the long term. Counter to the global trend, gas demand in Germany is expected to decrease. Furthermore, short-term fluctuations in economic activity with a potential for impacting on the demand for and price level of natural gas may pose significant economic risks. A detailed knowledge of one's own sales portfolio is therefore extremely important when it comes to gas procurement.

  4. Uncertainty analysis of a coupled ecosystem response model simulating greenhouse gas fluxes from a temperate grassland (United States)

    Liebermann, Ralf; Kraft, Philipp; Houska, Tobias; Breuer, Lutz; Müller, Christoph; Kraus, David; Haas, Edwin; Klatt, Steffen


    Among anthropogenic greenhouse gas emissions, CO2 is the dominant driver of global climate change. Next to its direct impact on the radiation budget, it also affects the climate system by triggering feedback mechanisms in terrestrial ecosystems. Such mechanisms - like stimulated photosynthesis, increased root exudations and reduced stomatal transpiration - influence both the input and the turnover of carbon and nitrogen compounds in the soil. The stabilization and decomposition of these compounds determines how increasing CO2 concentrations change the terrestrial trace gas emissions, especially CO2, N2O and CH4. To assess the potential reaction of terrestrial greenhouse gas emissions to rising tropospheric CO2 concentration, we make use of a comprehensive ecosystem model integrating known processes and fluxes of the carbon-nitrogen cycle in soil, vegetation and water. We apply a state-of-the-art ecosystem model with measurements from a long term field experiment of CO2 enrichment. The model - a grassland realization of LandscapeDNDC - simulates soil chemistry coupled with plant physiology, microclimate and hydrology. The data - comprising biomass, greenhouse gas emissions, management practices and soil properties - has been attained from a FACE (Free Air Carbon dioxide Enrichment) experiment running since 1997 on a temperate grassland in Giessen, Germany. Management and soil data, together with weather records, are used to drive the model, while cut biomass as well as CO2 and N2O emissions are used for calibration and validation. Starting with control data from installations without CO2 enhancement, we begin with a GLUE (General Likelihood Uncertainty Estimation) assessment using Latin Hypercube to reduce the range of the model parameters. This is followed by a detailed sensitivity analysis, the application of DREAM-ZS for model calibration, and an estimation of the effect of input uncertainty on the simulation results. Since first results indicate problems with

  5. Analysis of odour compounds from scented consumer products using gas chromatography-mass spectrometry and gas chromatography-olfactometry. (United States)

    Bartsch, Jennifer; Uhde, Erik; Salthammer, Tunga


    Scented consumer products are being bought in increasing amounts and gaining more popularity. There is, however, relatively little information available about their ingredients, emissions and allergenic potential. Frequently, a mixture of different fragrance substances and not solely an individual substance contributes to the overall desired smell. The aim of this study was to investigate the odorous volatile organic compounds (OVOCs) in consumer products containing fragrances. Over 44 products were selected: various scented candles, printing products with different scent types and other products types particularly meant to be used indoors. Measurements were carried out in a desiccator. Air samples were collected on thermal desorption tubes to determine the released fragrance substances by means of gas chromatography-mass spectrometry (GC-MS). Moreover, gas chromatography-olfactometry (GC-O) was used to obtain sensory data and to ensure no important odorant was overlooked. Using both methods it was possible to distinguish between odour active and inactive compounds and subsequently to identify almost 300 different odorants across all scented products. Besides the advantage of differentiation, as the human nose is a very sensitive detector, GC-O was found to be a useful tool for detecting traces and chosen target compounds. One focus in this study lay on the 26 EU-regulated fragrance allergens to prove their relevance in scented consumer goods. In total, 18 of them were identified, with at least one substance being present in almost every product. Benzyl alcohol, cinnamaldehyde, citronellol, eugenol, linalool and limonene were the prevalently detected allergens. Particularly linalool and limonene were observed in over 50% of the products. In addition, eugenol appeared to be one of the most frequently detected compounds in trace-level concentrations in the candle emissions.

  6. A Novel Association Rule Mining with IEC Ratio Based Dissolved Gas Analysis for Fault Diagnosis of Power Transformers

    Directory of Open Access Journals (Sweden)

    Ms. Kanika Shrivastava


    Full Text Available Dissolved gas Analysis (DGA is the most importantcomponent of finding fault in large oil filledtransformers. Early detection of incipient faults intransformers reduces costly unplanned outages. Themost sensitive and reliable technique for evaluatingthe core of transformer is dissolved gas analysis. Inthis paper we evaluate different transformercondition on different cases. This paper usesdissolved gas analysis to study the history ofdifferent transformers in service, from whichdissolved combustible gases (DCG in oil are usedas a diagnostic tool for evaluating the condition ofthe transformer. Oil quality and dissolved gassestests are comparatively used for this purpose. In thispaper we present a novel approach which is basedon association rule mining and IEC ratio method.By using data mining concept we can categorizefaults based on single and multiple associations andalso map the percentage of fault. This is an efficientapproach for fault diagnosis of power transformerswhere we can find the fault in all obviousconditions. We use java for programming andcomparative study.

  7. Lifecycle analysis of renewable natural gas and hydrocarbon fuels from wastewater treatment plants’ sludge

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Uisung [Argonne National Lab. (ANL), Argonne, IL (United States); Han, Jeongwoo [Argonne National Lab. (ANL), Argonne, IL (United States); Urgun Demirtas, Meltem [Argonne National Lab. (ANL), Argonne, IL (United States); Wang, Michael [Argonne National Lab. (ANL), Argonne, IL (United States); Tao, Ling [National Renewable Energy Lab. (NREL), Golden, CO (United States)


    Wastewater treatment plants (WWTPs) produce sludge as a byproduct when they treat wastewater. In the United States, over 8 million dry tons of sludge are produced annually just from publicly owned WWTPs. Sludge is commonly treated in anaerobic digesters, which generate biogas; the biogas is then largely flared to reduce emissions of methane, a potent greenhouse gas. Because sludge is quite homogeneous and has a high energy content, it is a good potential feedstock for other conversion processes that make biofuels, bioproducts, and power. For example, biogas from anaerobic digesters can be used to generate renewable natural gas (RNG), which can be further processed to produce compressed natural gas (CNG) and liquefied natural gas (LNG). Sludge can be directly converted into hydrocarbon liquid fuels via thermochemical processes such as hydrothermal liquefaction (HTL). Currently, the environmental impacts of converting sludge into energy are largely unknown, and only a few studies have focused on the environmental impacts of RNG produced from existing anaerobic digesters. As biofuels from sludge generate high interest, however, existing anaerobic digesters could be upgraded to technology with more economic potential and more environmental benefits. The environmental impacts of using a different anaerobic digestion (AD) technology to convert sludge into energy have yet to be analyzed. In addition, no studies are available about the direct conversion of sludge into liquid fuels. In order to estimate the energy consumption and greenhouse gas (GHG) emissions impacts of these alternative pathways (sludge-to-RNG and sludge-to-liquid), this study performed a lifecycle analysis (LCA) using the Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET®) model. The energy uses and GHG emissions associated with the RNG and hydrocarbon liquid are analyzed relative to the current typical sludge management case, which consists of a single-stage mesophilic

  8. H2S Analysis in Biological Samples Using Gas Chromatography with Sulfur Chemiluminescence Detection (United States)

    Vitvitsky, Victor; Banerjee, Ruma


    Hydrogen sulfide (H2S) is a metabolite and signaling molecule in biological tissues that regulates many physiological processes. Reliable and sensitive methods for H2S analysis are necessary for a better understanding of H2S biology and for the pharmacological modulation of H2S levels in vivo. In this chapter, we describe the use of gas chromatography coupled to sulfur chemiluminescence detection to measure the rates of H2S production and degradation by tissue homogenates at physiologically relevant concentrations of substrates. This method allows separation of H2S from other sulfur compounds and provides sensitivity of detection to ~15 pg (or 0.5 pmol) of H2S per injected sample. PMID:25725519

  9. Gas chromatography-mass spectrometry analysis of various organic extracts ofMerremia borneensisfrom Sabah

    Institute of Scientific and Technical Information of China (English)

    M Amzad Hossain; Muhammad Dawood Shah; Mahyar Sakari


    Objective:To analyse the chemical composition of different extracts ofMerremia borneensis (M. borneensis) by gas chromatography-mass spectrometry (GC-MS).Methods: The dried leaves powder was extracted with methanol at room temperature by using Soxhlet extractor. Methanol crude extracts ofM. borneensis were extrastel with hexane, chloroform, ethyl acetate and butanol. Results: Qualitative analyses of various organic crude extracts showed that majority of these are flavonoids, terpeniods, alkaloids and glycosides. Most of the identified compounds by GC-MS are biologically important. Further theM. borneensisleaf possesses certain characteristics that can be ascribed to cultivation on a domestic plantation.Conclusions: The suitable extracts for respective compounds can be chosen on the basis of aboveGC-MS analysis. All the major compounds from different extracts are biologically active molecules. Thus the identification of a good number of compounds from various extractsM. borneensis might have some ecological significance.

  10. Application of high-temperature gas chromatography to the analysis of used frying fats

    Energy Technology Data Exchange (ETDEWEB)

    Aguirre, M.; Marmesat, S.; Ruiz Mendez, M. V.; Dobarganes, M. C.


    The determination of polar compounds is the most commonly applied technique in the analysis of used frying fats and oils. High-temperature gas chromatography allows for a quantitative determination of oxidized monomeric FAME and dimeric FAME thus giving extra information on oil degradation starting from the fraction of polar compounds. Polar compounds are trans esterified and methyl esters are separated in a VF-5ht Ultimetal column (150 degree centigrade -held for 5 min- rising at 5 degree centigrade min-1 to 370 degree centigrade and held for 5 min) using methyl tricosanoate as internal standard. Results are compared with those obtained by more complex alternative methodology using high-performance size-exclusion chromatography. (Author)

  11. Thermodynamic Analysis of Beam down Solar Gas Turbine Power Plant equipped with Concentrating Receiver System (United States)

    Azharuddin; Santarelli, Massimo


    Thermodynamic analysis of a closed cycle, solar powered Brayton gas turbine power plant with Concentrating Receiver system has been studied. A Brayton cycle is simpler than a Rankine cycle and has an advantage where the water is scarce. With the normal Brayton cycle a Concentrating Receiver System has been analysed which has a dependence on field density and optical system. This study presents a method of optimization of design parameter, such as the receiver working temperature and the heliostats density. This method aims at maximizing the overall efficiency of the three major subsystem that constitute the entire plant, namely, the heliostat field and the tower, the receiver and the power block. The results of the optimization process are shown and analysed.

  12. Agriculture-industrial residues x natural gas. An economic of energy analysis

    Energy Technology Data Exchange (ETDEWEB)

    Avellar, L.H.N. [Pos-Graduacao em Engenharia Mecanica, Guaratingueta, SP (Brazil); Carrocci, L.R.; Silveira, J.L.; Oliva, V.J. [Universidade Estadul Paulista, Guaratingueta, SP (Brazil). Faculdade de Engenharia de Guaratingueta


    In this paper are presented following, as it's main objective, an economic analysis between biogas coming from agriculture-industrial-residues and natural gas. Above all, also make part of this work, illustrating figures of the most used types of biodigestors in Brazil and all of world, and briefly descriptions of the most used control and reduction technologies of the pollutants emissions from the combustion process through in the atmosphere. Must emphasise, above technical-scientific importance of this work, it's social -economic part at the poignant of the residues seizing with considerable calorific power for the energy generation, thereby promoting the ambiental pollution retrenchment (also detach here), looking for, in a coming future, the sustainable development at all of it completeness.

  13. Carbon monoxide analysis: a comparison of two co-oximeters and headspace gas chromatography

    Energy Technology Data Exchange (ETDEWEB)

    Costantino, A.G.; Park, J.; Caplan, Y.H.

    Three methods (lL-182 Co-Oximeter, lL-282 Co-Oximeter, and headspace gas chromatography) for the analysis of carbon monoxide in postmortem blood were studied and compared using a prepared reference standard, Quantra control materials, and 62 postmortem blood specimens. The methods compared favorably with one another. The linear regression equations for the 62 postmortem blood samples (range = 1.0 to 86% saturation) were: lL-282 vs. lL-182, y = 1.11x - 3.10, r = 0.981; lL-182 vs. GC, y = 0.88x + 2.97, r = 0.973; lL-282 vs. GC, y = 1.00x - 1.24, r = 0.986.

  14. Analysis of EPA and DHA in the viscera of marine fish using gas chromatography. (United States)

    Zhang, De-Yong; Xu, Xiao-Lu; Shen, Xiu-Ying; Mei, Yu; Xu, Hui-Ying


    The viscera of 10 kinds of marine fishes were collected for fish oil extraction and detection of DHA and EPA, two most important polyunsaturated fatty acids. The fish oil extraction ratio for the evaluated fishes varied from 0.95% to 10.18% (wt%). Pseudosciaena crocea presented the highest fish oil yield, followed by Mustelus manazo, Hippoglossus and Sciaenopsocellatus. A gas chromatography method was then established for analysis of EPA/DHA. The EPA concentration (in methyl ester form) in the fish oil varied from 1.39 to 10.65(mg/g). Epinephelus awoara presented the highest EPA concentration (pfish oil varied from 0.58 to 37.02 (mg/g). Epinephelus awoara presented the highest DHA concentration (pfish live was observed. The fishes living in middle depth presented highest EPA/DHA concentration.

  15. Analysis of the surface energy of pharmaceutical powders by inverse gas chromatography. (United States)

    Grimsey, Ian M; Feeley, Jane C; York, Peter


    The behavior of pharmaceutical solids, during either processing or use, can be noticeably affected by the surface energetics of the constituent particles. Several techniques exist to measure the surface energy, for example, sessile drop, and dynamic contact angle measurements. Inverse gas chromatography (IGC) is an alternative technique where the powder surface is characterized by the retention behavior of minute quantities of well-characterized vapors that are injected into a column containing the material of interest. Recently published articles using IGC on pharmaceutical powders have ranged from linking surface energetic data with triboelectric charging to studying the effect of surface moisture on surface energetics. Molecular modelling has also recently been used to explore the links between IGC data and the structural and chemical factors that influence surface properties, thereby achieving predictive knowledge regarding powder behavior during processing. In this minireview, the reported applications of IGC in the analysis of pharmaceutical powders are summarized and the major findings highlighted.

  16. Analysis of a model of fuel cell - gas turbine hybrid power system for enhanced energy efficiency (United States)

    Calay, Rajnish K.; Mustafa, Mohamad Y.; Virk, Mohammad S.; Mustafa, Mahmoud F.


    A simple mathematical model to evaluate the performance of FC-GT hybrid system is presented in this paper. The model is used to analyse the influence of various parameters on the performance of a typical hybrid system, where excess heat rejected from the solid-oxide fuel cell stack is utilised to generate additional power through a gas turbine system and to provide heat energy for space heating. The model is based on thermodynamic analysis of various components of the plant and can be adapted for various configurations of the plant components. Because there are many parameters defining the efficiency and work output of the hybrid system, the technique is based on mathematical and graphical optimisation of various parameters; to obtain the maximum efficiency for a given plant configuration.

  17. Time series analysis of pressure fluctuation in gas-solid fluidized beds

    Directory of Open Access Journals (Sweden)

    C. Alberto S. Felipe


    Full Text Available The purpose of the present work was to study the differentiation of states of typical fluidization (single bubble, multiple bubble and slugging in a gas-solid fluidized bed, using spectral analysis of pressure fluctuation time series. The effects of the method of measuring (differential and absolute pressure fluctuations and the axial position of the probes in the fluidization column on the identification of each of the regimes studied were evaluated. Fast Fourier Transform (FFT was the mathematic tool used to analysing the data of pressure fluctuations, which expresses the behavior of a time series in the frequency domain. Results indicated that the plenum chamber was a place for reliable measurement and that care should be taken in measurement in the dense phase. The method allowed fluid dynamic regimes to be differentiated by their dominant frequency characteristics.

  18. Exergy Analysis of Gas Turbine – Fuel cell based combined Cycle Power Plant

    Directory of Open Access Journals (Sweden)



    Full Text Available The increase in demand for electrical energy leads to the newer power generation systems. Though it is not new, fuel cell technology is one of the promising systems for cleaner and competitive alternate power generation system. When the fuel cells are integrated with the Gas Turbines, the total thermal efficiency of the combined cycle is obtained greater than 60%. In this paper, thermodynamic analysis of SOFC-GT combined system (2.898MW has been carried out, exergy efficiency and exergy destruction of each component are calculated.The effect of compression ratio (rp, turbine inlet temperature (TIT and ambient temperature of air, on the performance of the system has been analyzed. Outcome of the system modeling reveals that SOFC andcombustion chamber are the main sources of exergy destruction. At the optimum compression ratio 9, the total thermal efficiency and exergy efficiency are found to be 63.3% and 60.85% respectively.

  19. Assessment of oil weathering by gas chromatography-mass spectrometry, time warping and principal component analysis

    DEFF Research Database (Denmark)

    Malmquist, Linus M.V.; Olsen, Rasmus R.; Hansen, Asger B.


    Detailed characterization and understanding of oil weathering at the molecular level is an essential part of tiered approaches for forensic oil spill identification, for risk assessment of terrestrial and marine oil spills, and for evaluating effects of bioremediation initiatives. Here......, a chemometricbased method is applied to data from two in vitro experiments in order to distinguish the effects of evaporation and dissolution processes on oil composition. The potential of the method for obtaining detailed chemical information of the effects from evaporation and dissolution processes, to determine...... weathering state and to distinguish between various weathering processes is investigated and discussed. The method is based on comprehensive and objective chromatographic data processing followed by principal component analysis (PCA) of concatenated sections of gas chromatography–mass spectrometry...

  20. Economic and financial feasibility analysis of natural gas urban distribution; Analise da viabilidade economica e financeira para o desenvolvimento da rede urbana de distribuicao de gas natural

    Energy Technology Data Exchange (ETDEWEB)

    Cabral, Guilherme G.; Cunha, Eduardo N.; Teixeira, Clovis C. [Companhia de Gas do Estado do RS (SULGAS), Porto Alegre, RS (Brazil)


    SULGAS has developed more judicious systematics investments analysis in the natural gas distribution plants in urban areas . A survey has been made of the variables that influence this type of investment, identifying the most relevant ones. Spread sheet in platform Microsoft Excel and Visual Basic was elaborated that makes possible the deterministic analysis, sensibility, and risk analysis of the projects, through consolidated indicators usable in economic engineering. The great differentiation of this proposal is the possibility/flexibility of the economic impact analysis that each future customer has in the branch where he is linked. The spread sheet presents graphical platforms in which the schematical drawings of the projects are inserted on satellite photos of the region, making possible the projects architectures visualization in parallel with the economic analysis. This graphical platform is tied with the alternatives selected in the economic analysis, being brought up to date the images in accordance with the projects selected in the spread sheet. The risk analysis are carried out through the Monte Carlo simulation, generating investment return probability from each branch, cell, or customer, depending on the criteria defined in the spread sheet. This makes possible the insertion and economic analysis of the factors that can influence the investments in NG distribution system, becoming an important tool in the decision making. (author)

  1. The analysis of energy consumption and greenhouse gas emissions of a large-scale commercial building in Shanghai, China

    Directory of Open Access Journals (Sweden)

    Xin Wang


    Full Text Available Reasonable test, diagnosis, and analysis are meaningful for building energy efficiency retrofit and management. Energy consumption and greenhouse gas emission of a large-scale commercial building are described in this article. Basic information about energy consumption equipment is included in the investigation. Further diagnoses about the operational state of air-conditioning water systems, and ducted systems were implemented. Energy consumption decreased 200 kWh/m2 per year from 2007 to 2009 after energy-saving reconstruction in 2006. Next, a carbon audit was carried out; this comprised CO2 emission statistics associated with the energy use and categorization and structural analysis (categorization refers to energy categorization and structural analysis means the composition and its proportion relationship of all kinds of primary energy and secondary energy in energy production or consumption. Greenhouse gas emissions could be less than 150 kg/m2 per year from 2007 to 2009. An analysis of the correlation between CO2 emissions, building gross domestic product, and energy efficiency is also presented. This article makes an analysis on the energy utilization and energy-saving reconstruction of a public commercial building in Shanghai and then makes an analysis of carbon audit about greenhouse gas emissions related to energy utilization (it analyzes the status of building’s energy utilization and greenhouse gas emissions, to have a more comprehensive understanding on the internal relationship between energy consumption and its greenhouse gas emissions and provide researchful reference data for the development with reduction strategies of greenhouse gas emission in future building.

  2. Regional versus detailed velocity analysis to quantify hydrate and free gas in marine sediments : the south Shetland margin case study

    Energy Technology Data Exchange (ETDEWEB)

    Tinivella, U.; Loreto, M.F.; Accaino, F. [Inst. Nazionale di Oceanografia di Geofisica Sperimentale, Trieste (Italy)


    The presence of gas hydrate and free gas within marine sediments, deposited along the South Shetland margin, offshore the Antarctic Peninsula, was confirmed by low and high resolution geophysical data, acquired during three research cruises in 1989-1990. Seismic data analysis has demonstrated the presence of a bottom simulating reflector that is very strong and continuous in the eastern part of the margin. This seismic dataset was used in the past to extract detailed velocity information of the shallow structures by using traditional tomographic inversion and jointly tomographic inversion and pre-stack depth migration tool. This paper presented a method to obtain a regional seismic velocity field and information about hydrate and free gas presence in the marine sediments, by using an improved method of the standard analysis of the pre-stack depth migration output. The velocity field was obtained with a layer stripping approach and tomographic inversion of the reflections observed in common image gathering. The paper presented the seismic data and regional and detailed velocity analysis. The results of residual semblance analyses were also presented. Gas phase concentrations were then discussed. The velocity analysis revealed the presence of three main layers characterizing the first kilometer of sediments below the sea floor. In addition, velocity models and related gas-phase sections showed that gas was concentrated in different parts of the profile than where the hydrate was concentrated. This observation confirmed that geological structures and sedimentary processes controlled the gas and hydrate distribution, as observed along other margins. 7 refs., 5 figs.

  3. Depletion Analysis of Modular High Temperature Gas-cooled Reactor Loaded with LEU/Thorium Fuel

    Energy Technology Data Exchange (ETDEWEB)

    Sonat Sen; Gilles Youinou


    Thorium based fuel has been considered as an option to uranium-based fuel, based on considerations of resource utilization (Thorium is more widely available when compared to Uranium). The fertile isotope of Thorium (Th-232) can be converted to fissile isotope U-233 by neutron capture during the operation of a suitable nuclear reactor such as High Temperature Gas-cooled Reactor (HTGR). However, the fertile Thorium needs a fissile supporter to start and maintain the conversion process such as U-235 or Pu-239. This report presents the results of a study that analyzed the thorium utilization in a prismatic HTGR, namely Modular High Temperature Gas-Cooled Reactor (MHTGR) that was designed by General Atomics (GA). The collected for the modeling of this design come from Chapter 4 of MHTGR Preliminary Safety Information Document that GA sent to Department of Energy (DOE) on 1995. Both full core and unit cell models were used to perform this analysis using SCALE 6.1 and Serpent 1.1.18. Because of the long mean free paths (and migration lengths) of neutrons in HTRs, using a unit cell to represent a whole core can be non-trivial. The sizes of these cells were set to match the spectral index between unit cell and full core domains. It was found that for the purposes of this study an adjusted unit cell model is adequate. Discharge isotopics and one-group cross-sections were delivered to the transmutation analysis team. This report provides documentation for these calculations

  4. Understanding gas phase modifier interactions in rapid analysis by differential mobility-tandem mass spectrometry. (United States)

    Kafle, Amol; Coy, Stephen L; Wong, Bryan M; Fornace, Albert J; Glick, James J; Vouros, Paul


    A systematic study involving the use and optimization of gas-phase modifiers in quantitative differential mobility-mass spectrometry (DMS-MS) analysis is presented using nucleoside-adduct biomarkers of DNA damage as an important reference point for analysis in complex matrices. Commonly used polar protic and polar aprotic modifiers have been screened for use against two deoxyguanosine adducts of DNA: N-(deoxyguanosin-8-yl)-4-aminobiphenyl (dG-C8-4-ABP) and N-(deoxyguanosin-8-y1)-2-amino-l-methyl-6-phenylimidazo[4,5-b]pyridine (dG-C8-PhIP). Particular attention was paid to compensation voltage (CoV) shifts, peak shapes, and product ion signal intensities while optimizing the DMS-MS conditions. The optimized parameters were then applied to rapid quantitation of the DNA adducts in calf thymus DNA. After a protein precipitation step, adduct levels corresponding to less than one modification in 10(6) normal DNA bases were detected using the DMS-MS platform. Based on DMS fundamentals and ab initio thermochemical results, we interpret the complexity of DMS modifier responses in terms of thermal activation and the development of solvent shells. At very high bulk gas temperature, modifier dipole moment may be the most important factor in cluster formation and cluster geometry, but at lower temperatures, multi-neutral clusters are important and less predictable. This work provides a useful protocol for targeted DNA adduct quantitation and a basis for future work on DMS modifier effects.

  5. Linear solvation energy relationships as classifiers in non-target analysis - a gas chromatographic approach. (United States)

    Ulrich, Nadin; Mühlenberg, Jana; Retzbach, Heiko; Schüürmann, Gerrit; Brack, Werner


    Linear solvation energy relationships (LSERs) are applied as classifiers to predict the logarithmic retention factors logk from the structures of candidate compounds in non-target analysis. By comparison of the predicted value with the experimentally determined logk, progressive exclusion of candidates is done. The approach is based on the determination of stationary phase parameters to describe ten different gas chromatographic columns under four isothermal conditions. To demonstrate retention prediction and the application of the classifier model, twelve compounds with the molecular formula C(12)H(10)O(2) were selected, while experimental logk values were compared to the predicted values and exclusion of potential candidate compounds was performed. The analytical power of the approach was demonstrated on the basis of experimentally determined compound descriptors achieved from gas chromatographic measurements. The prediction got less accurate when calculated compound descriptors were employed. For the time being insufficient precision in estimating the descriptors limits the possibility to exclude candidate compounds in non-target analysis. It is expected that new approaches to estimate compound descriptors, will improve this situation. At present, the insufficient accuracy of descriptor estimates can be dealt with larger prognosis intervals. Furthermore, the combination of two stationary phases with corresponding retention prediction further advanced the exclusion of potential candidates. The most appropriate pair of stationary phases was selected by the application of four different orthogonal strategies. In addition, the classifier was applied for a validation set with different molecular composition, where column selection was considered on the basis of the differences in the compound descriptors of the corresponding candidate compounds.

  6. Orientation-free and differentially pumped addition of a low-flux reactive gas beam to a surface analysis system (United States)

    Harthcock, Colin; Jahanbekam, Abdolreza; Eskelsen, Jeremy R.; Lee, David Y.


    We describe an example of a piecewise gas chamber that can be customized to incorporate a low flux of gas-phase radicals with an existing surface analysis chamber for in situ and stepwise gas-surface interaction experiments without any constraint in orientation. The piecewise nature of this gas chamber provides complete angular freedom and easy alignment and does not require any modification of the existing surface analysis chamber. In addition, the entire gas-surface system is readily differentially pumped with the surface chamber kept under ultra-high-vacuum during the gas-surface measurements. This new design also allows not only straightforward reconstruction to accommodate the orientation of different surface chambers but also for the addition of other desired features, such as an additional pump to the current configuration. Stepwise interaction between atomic oxygen and a highly ordered pyrolytic graphite surface was chosen to test the effectiveness of this design, and the site-dependent O-atom chemisorption and clustering on the graphite surface were resolved by a scanning tunneling microscope in the nm-scale. X-ray photoelectron spectroscopy was used to further confirm the identity of the chemisorbed species on the graphite surface as oxygen.

  7. Thermodynamic Analysis of Alternative Marine Fuels for Marine Gas Turbine Power Plants

    Institute of Scientific and Technical Information of China (English)

    Mohamed M El Gohary; Nader R Ammar


    The marine shipping industry faces challenges to reduce engine exhaust emissions and greenhouse gases (GHGs) from ships, and in particular, carbon dioxide. International regulatory bodies such as the International Maritime Organization and National Environmental Agencies of many countries have issued rules and regulations to drastically reduce GHG and emissions emanating from marine sources. This study investigates the possibility of using natural gas and hydrogen as alternative fuels to diesel oil for marine gas turbines and uses a mathematical model to assess the effect of these alternative fuels on gas turbine thermodynamic performance. Results show that since natural gas is categorized as a hydrocarbon fuel, the thermodynamic performance of the gas turbine cycle using natural gas was close to that of the diesel case. However, the gas turbine thermal efficiency was found to be slightly lower for natural gas and hydrogen fuels compared to diesel fuel.

  8. Thermodynamic analysis of alternative marine fuels for marine gas turbine power plants (United States)

    El Gohary, Mohamed M.; Ammar, Nader R.


    The marine shipping industry faces challenges to reduce engine exhaust emissions and greenhouse gases (GHGs) from ships, and in particular, carbon dioxide. International regulatory bodies such as the International Maritime Organization and National Environmental Agencies of many countries have issued rules and regulations to drastically reduce GHG and emissions emanating from marine sources. This study investigates the possibility of using natural gas and hydrogen as alternative fuels to diesel oil for marine gas turbines and uses a mathematical model to assess the effect of these alternative fuels on gas turbine thermodynamic performance. Results show that since natural gas is categorized as a hydrocarbon fuel, the thermodynamic performance of the gas turbine cycle using natural gas was close to that of the diesel case. However, the gas turbine thermal efficiency was found to be slightly lower for natural gas and hydrogen fuels compared to diesel fuel.


    Directory of Open Access Journals (Sweden)

    Tabunshchikov Yuriy Andreevich


    The research also contemplates the structure of expenses associated with the piping of gas distribution networks. Mathematical equations have been derived to perform sufficiently accurate calculations of costs of construction of various types and various lengths of gas pipelines.

  10. Thermodynamic analysis for a regenerative gas turbine cycle in coking process

    Directory of Open Access Journals (Sweden)

    Zelong Zhang, Lingen Chen, Yanlin Ge, Fengrui Sun


    Full Text Available A regenerative gas turbine cycle driven by residual coke oven gas is proposed in this paper. The thermal efficiency and the work output (per ton of coke of the system are analyzed based on thermodynamics and the theory of gas turbine cycle. The influences of the gas release rate, the residual gas rate and the effectiveness of regenerator on the performance of the cycle are analyzed by using numerical examples. It is found that the work output increases with the increase of the residual gas rate while decreases with the increase of the gas release rate. The cycle with regenerator can reach higher thermal efficiency and bigger work output, which means that the coke oven gas is used more effectively. Moreover, there exist two optimal pressure ratios of compressor which lead the maximum thermal efficiency and the maximum specific work, respectively.

  11. Headspace Analysis of Philippine Civet Coffee Beans Using Gas Chromatography-Mass Spectrometry and Electronic Nose (United States)

    Ongo, E.; Sevilla, F.; Antonelli, A.; Sberveglieri, G.; Montevecchi, G.; Sberveglieri, V.; de Paola, E. L.; Concina, I.; Falasconi, M.


    Civet coffee, the most expensive and best coffee in the world, is an economically important export product of the Philippines. With a growing threat of food adulteration and counterfeiting, a need for quality authentication is essential to protect the integrity and strong market value of Philippine civet coffee. At present, there is no internationally accepted method of verifying whether a bean is an authentic civet coffee. This study presented a practical and promising approach to identify and establish the headspace qualitative profile of Philippine civet coffee using electronic nose (E-nose) and gas chromatography-mass spectrometry (GC-MS). E-nose analysis revealed that aroma characteristic is one of the most important quality indicators of civet coffee. The findings were supported by GC-MS analysis. Principal component analysis (PCA) exhibited a clearly separated civet coffees from their control beans. The chromatographic fingerprints indicated that civet coffees differed with their control beans in terms of composition and concentration of individual volatile constituents.

  12. Finite Element Analysis of Squirrel Cage Ball Bearingsfor Gas Turbine Engines

    Directory of Open Access Journals (Sweden)

    Benny George


    Full Text Available Squirrel cage ball bearings are used in recent aero engines to overcome the vibration andstability problems associated with rotor systems supported by conventional bearings. The criticaldesign feature of squirrel cage bearing is to provide flexible support to rotor system. The outerring of the bearing is configured such that it acts as a flexible bearing support, and hence, weightis minimised. The bearing is mounted directly on a rigid intermediate casing of a gas turbineengine. Finite element analysis helps to obtain a suitable geometry at the design stage. A 3-Dmodel of the bearing is created using IDEAS software. Finite element analysis using contactelement has been carried out for finding the deformation and stresses in the webs at variouslocations using ANSYS software. The deformations are compared with those of experimentalvalues for an axial load. The deformation in the webs is used to check the pressure balance inthe compressor and the load acting on the bearing. Finally, a procedure for doing the finiteelement analysis of ball bearings for combined axial and radial load is laid down.

  13. Metal-Assisted Laser-Induced Gas Plasma for the Direct Analysis of Powder Using Pulse CO2 Laser (United States)

    Khumaeni, A.; Lie, Z. S.; Kurniawan, K. H.; Kagawa, K.


    Analysis of powder samples available in small quantities has been carried out using metal-assisted gas plasma by utilizing a transversely excited atmospheric (TEA) CO2 laser. The powder was homogeneously mixed with Si grease, and the mixed powder was painted on a metal subtarget. When a TEA CO2 laser was directly focused on the metal subtarget at atmospheric pressure of He gas, a high-temperature He gas plasma was induced. It is assumed that the powder particles were vaporized to be effectively atomized and excited in the gas plasma region. This method has been employed in the rapid analyses of elements in organic and inorganic powder samples present in small quantities. Detection of trace elements of Cr and Pb has been successfully made by using the supplement powder and loam soil, respectively. The detection limits of Pb in loam soil were approximately 20 mg/kg.


    Directory of Open Access Journals (Sweden)

    Elisabete Coentrão Marques


    Full Text Available Operational safety is a worrying factor within any company, especially in the oil and gas sector. The objective of this work was to analyze the application of technical regulation of the management system for operational safety on marine installations for drilling and production of oil and natural gas from the National Agency of Petroleum, Natural Gas and Biofuels in manuals of a company in the oil and gas sector. The methodology was based on documentary analysis. It was observed that the company management can achieve the technical factors of work, building design and integration as operational safety in each of the management practices. Concluded that the format and information of manuals are placed as potential to eliminate the risks for the company and the environment.

  15. Gas chromatography-olfactometry analysis of the volatile compounds of two commercial Irish beef meats

    NARCIS (Netherlands)

    Machiels, D.; Ruth, van S.M.; Posthumus, M.A.; Istasse, L.


    The volatile flavour compounds of two commercial Irish beef meats (labelled as conventional and organic) were evaluated by gas chromatography-olfactometry and were identified by gas chromatography-mass spectrometry. The volatile compounds were isolated in a model mouth system. Gas chromatography-olf

  16. Rapid direct analysis to discriminate geographic origin of extra virgin olive oils by flash gas chromatography electronic nose and chemometrics. (United States)

    Melucci, Dora; Bendini, Alessandra; Tesini, Federica; Barbieri, Sara; Zappi, Alessandro; Vichi, Stefania; Conte, Lanfranco; Gallina Toschi, Tullia


    At present, the geographical origin of extra virgin olive oils can be ensured by documented traceability, although chemical analysis may add information that is useful for possible confirmation. This preliminary study investigated the effectiveness of flash gas chromatography electronic nose and multivariate data analysis to perform rapid screening of commercial extra virgin olive oils characterized by a different geographical origin declared in the label. A comparison with solid phase micro extraction coupled to gas chromatography mass spectrometry was also performed. The new method is suitable to verify the geographic origin of extra virgin olive oils based on principal components analysis and discriminant analysis applied to the volatile profile of the headspace as a fingerprint. The selected variables were suitable in discriminating between "100% Italian" and "non-100% Italian" oils. Partial least squares discriminant analysis also allowed prediction of the degree of membership of unknown samples to the classes examined.

  17. Petrophysical Analysis and Geographic Information System for San Juan Basin Tight Gas Reservoirs

    Energy Technology Data Exchange (ETDEWEB)

    Martha Cather; Robert Lee; Robert Balch; Tom Engler; Roger Ruan; Shaojie Ma


    The primary goal of this project is to increase the availability and ease of access to critical data on the Mesaverde and Dakota tight gas reservoirs of the San Juan Basin. Secondary goals include tuning well log interpretations through integration of core, water chemistry and production analysis data to help identify bypassed pay zones; increased knowledge of permeability ratios and how they affect well drainage and thus infill drilling plans; improved time-depth correlations through regional mapping of sonic logs; and improved understanding of the variability of formation waters within the basin through spatial analysis of water chemistry data. The project will collect, integrate, and analyze a variety of petrophysical and well data concerning the Mesaverde and Dakota reservoirs of the San Juan Basin, with particular emphasis on data available in the areas defined as tight gas areas for purpose of FERC. A relational, geo-referenced database (a geographic information system, or GIS) will be created to archive this data. The information will be analyzed using neural networks, kriging, and other statistical interpolation/extrapolation techniques to fine-tune regional well log interpretations, improve pay zone recognition from old logs or cased-hole logs, determine permeability ratios, and also to analyze water chemistries and compatibilities within the study area. This single-phase project will be accomplished through four major tasks: Data Collection, Data Integration, Data Analysis, and User Interface Design. Data will be extracted from existing databases as well as paper records, then cleaned and integrated into a single GIS database. Once the data warehouse is built, several methods of data analysis will be used both to improve pay zone recognition in single wells, and to extrapolate a variety of petrophysical properties on a regional basis. A user interface will provide tools to make the data and results of the study accessible and useful. The final deliverable

  18. Numerical analysis of gas emission rule from a goaf of tailing roadway

    Institute of Scientific and Technical Information of China (English)

    LI Zong-xiang; HUANG Zhi-an; ZHANG Ai-ran; SONG Jian-guo


    Targeting the problem of large amounts of gas emission from the goaf of the No.14201 working face in the Shaqu coal mine of Huajin Coking Coal Co. Ltd., we used a negative exponential function to describe the attenuation process of gas emission in goaf (the stable source) based on the principle of field flow. Equations of two-component flow (gas and air) and see- page-diffusion in a heterogeneous goaf flow field are solved by means of numerical simulation and fluid mechanics principles of air movement and gas distribution during gas emission from goaf. The results indicate that the air diversion volume has a negative, exponential relation with the volume of gas emitted from goaf to the working face and is clearly inversely related to gas concentration. We calculated the minimum amount of air diversion and distributed air volume in the tailing roadway required for safe production.

  19. Loading and stress analysis of gas pipeline structures; Analise de esforcos e tensoes em estruturas de gasodutos durante despressurizacoes

    Energy Technology Data Exchange (ETDEWEB)

    Frisoli, Caetano [TRANSPETRO - PETROBRAS Transporte S.A., Rio de Janeiro, RJ (Brazil); Frota, Cristiane Souto [TBG - Transportadora Brasileira Gasoduto Bolivia Brasil S.A., Rio de Janeiro, RJ (Brazil); Silva, Luis Fernando Figueira da; Carvalho, Marcio da Silveira [Pontificia Univ. Catolica do Rio de Janeiro, RJ (Brazil). Dept. de Engenharia Mecanica; Savi, Marcelo Amorim [Universidade Federal, Rio de Janeiro, RJ (Brazil). Coordenacao dos Programas de Pos-graduacao de Engenharia. Dept. de Engenharia Mecanica; Pacheco, Pedro Manuel Calas Lopes [Centro Federal de Educacao Tecnologica do Rio de Janeiro (CEFET-RJ), Rio de Janeiro, RJ (Brazil)


    Repairing and maintenance activities on Bolivia-Brazil gas pipeline often need blow down lines. During the blow down process, the high speed of discharging gases imposes great efforts to the structures. A detailed analysis of this situation is essential for a safe operation. This paper describes two phases of a project, developed under TBG coordination. It consists in analyzing the stress and forces involved in this operation, in order to design facilities to blow down pipes and develop a safe blow down procedure for the gas pipeline. The first phase consists of a supersonic flowing simulation in the blow down gas pipeline device. The pressure behavior, mass flow and the speed at the device's ending point are calculated for different operational conditions. In the second phase, the equivalent loading caused by blow down operations is used as input in a stress analysis program to determine stress, critical sessions evaluation and material recommendations for blow down devices. (author)

  20. Application of evolved gas analysis to cold-cap reactions of melter feeds for nuclear waste vitrification

    Energy Technology Data Exchange (ETDEWEB)

    Kruger, Albert A.; Chun, Jaehun; Hrma, Pavel R.; Rodriguez, Carmen P.; Schweiger, Michael J.


    In the vitrification of nuclear wastes, the melter feed (a mixture of nuclear waste and glass-forming and modifying additives) experiences multiple gas-evolving reactions in an electrical glass-melting furnace. We employed the thermogravimetry-gas chromatography-mass spectrometry (TGA-GC-MS) combination to perform evolved gas analysis (EGA). Apart from identifying the gases evolved, we performed quantitative analysis relating the weighed sum of intensities of individual gases linearly proportional with the differential themogravimetry. The proportionality coefficients were obtained by three methods based on the stoichiometry, least squares, and calibration. The linearity was shown to be a good first-order approximation, in spite of the complicated overlapping reactions.

  1. Thermal and Evolved Gas Analysis of Calcite Under Reduced Operating Pressures: Implications for the 2011 MSL Sample Analysis at Mars (SAM) Instrument (United States)

    Lauer, H. V. Jr.; Ming, D. W.; Sutter, B.; Mahaffy, P. R.


    The Mars Science Laboratory (MSL) is scheduled for launch in 2011. The science objectives for MSL are to assess the past or present biological potential, to characterize the geology, and to investigate other planetary processes that influence habitability at the landing site. The Sample Analysis at Mars (SAM) is a key instrument on the MSL payload that will explore the potential habitability at the landing site [1]. In addition to searching for organic compounds, SAM will have the capability to characterized evolved gases as a function of increasing temperature and provide information on the mineralogy of volatile-bearing phases such as carbonates, sulfates, phyllosilicates, and Fe-oxyhydroxides. The operating conditions in SAM ovens will be maintained at 30 mb pressure with a He carrier gas flowing at 1 sccm. We have previously characterized the thermal and evolved gas behaviors of volatile-bearing species under reduced pressure conditions that simulated operating conditions of the Thermal and Evolved Gas Analyzer (TEGA) that was onboard the 2007 Mars Phoenix Scout Mission [e.g., 2-8]. TEGA ovens operated at 12 mb pressure with a N2 carrier gas flowing at 0.04 sccm. Another key difference between SAM and TEGA is that TEGA was able to perform differential scanning calorimetry whereas SAM only has a pyrolysis oven. The operating conditions for TEGA and SAM have several key parameter differences including operating pressure (12 vs 30 mb), carrier gas (N2 vs. He), and carrier gas flow rate (0.04 vs 1 sccm). The objectives of this study are to characterize the thermal and evolved gas analysis of calcite under SAM operating conditions and then compare it to calcite thermal and evolved gas analysis under TEGA operating conditions.

  2. Analysis of Gas Membrane Ultra-High Purification of Small Quantities of Mono-Isotopic Silane

    Energy Technology Data Exchange (ETDEWEB)

    de Almeida, Valmor F. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division; Hart, Kevin J. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division


    A small quantity of high-value, crude, mono-isotopic silane is a prospective gas for a small-scale, high-recovery, ultra-high membrane purification process. This is an unusual application of gas membrane separation for which we provide a comprehensive analysis of a simple purification model. The goal is to develop direct analytic expressions for estimating the feasibility and efficiency of the method, and guide process design; this is only possible for binary mixtures of silane in the dilute limit which is a somewhat realistic case. Among the common impurities in crude silane, methane poses a special membrane separation challenge since it is chemically similar to silane. Other potential problematic surprises are: ethylene, diborane and ethane (in this order). Nevertheless, we demonstrate, theoretically, that a carefully designed membrane system may be able to purify mono-isotopic, crude silane to electronics-grade level in a reasonable amount of time and expenses. We advocate a combination of membrane materials that preferentially reject heavy impurities based on mobility selectivity, and light impurities based on solubility selectivity. We provide estimates for the purification of significant contaminants of interest. To improve the separation selectivity, it is advantageous to use a permeate chamber under vacuum, however this also requires greater control of in-leakage of impurities in the system. In this study, we suggest cellulose acetate and polydimethylsiloxane as examples of membrane materials on the basis of limited permeability data found in the open literature. We provide estimates on the membrane area needed and priming volume of the cell enclosure for fabrication purposes when using the suggested membrane materials. These estimates are largely theoretical in view of the absence of reliable experimental data for the permeability of silane. Last but not least, future extension of this work to the non-dilute limit may apply to the recovery of silane from

  3. Analysis of Gas Membrane Ultra-High Purification of Small Quantities of Mono-Isotopic Silane

    Energy Technology Data Exchange (ETDEWEB)

    de Almeida, Valmor F [ORNL; Hart, Kevin J [ORNL


    A small quantity of high-value, crude, mono-isotopic silane is a prospective gas for a small-scale, high-recovery, ultra-high membrane purification process. This is an unusual application of gas membrane separation for which we provide a comprehensive analysis of a simple purification model. The goal is to develop direct analytic expressions for estimating the feasibility and efficiency of the method, and guide process design; this is only possible for binary mixtures of silane in the dilute limit which is a somewhat realistic case. Among the common impurities in crude silane, methane poses a special membrane separation challenge since it is chemically similar to silane. Other potential problematic surprises are: ethylene, diborane and ethane (in this order). Nevertheless, we demonstrate, theoretically, that a carefully designed membrane system may be able to purify mono-isotopic, crude silane to electronics-grade level in a reasonable amount of time and expenses. We advocate a combination of membrane materials that preferentially reject heavy impurities based on mobility selectivity, and light impurities based on solubility selectivity. We provide estimates for the purification of significant contaminants of interest. To improve the separation selectivity, it is advantageous to use a permeate chamber under vacuum, however this also requires greater control of in-leakage of impurities in the system. In this study, we suggest cellulose acetate and polydimethylsiloxane as examples of membrane materials on the basis of limited permeability data found in the open literature. We provide estimates on the membrane area needed and priming volume of the cell enclosure for fabrication purposes when using the suggested membrane materials. These estimates are largely theoretical in view of the absence of reliable experimental data for the permeability of silane. Last but not least, future extension of this work to the non-dilute limit may apply to the recovery of silane from

  4. Quantification of fentanyl in serum by isotope dilution analysis using capillary gas chromatography

    Energy Technology Data Exchange (ETDEWEB)

    Sera, Shoji; Goromaru, Tsuyoshi [Fukuyama Univ., Hiroshima (Japan); Sameshima, Teruko; Kawasaki, Koichi; Oda, Toshiyuki


    The quantitative determination of fentanyl (FT) in serum was examined by isotope dilution analysis using a capillary gas chromatograph equipped with a surface ionization detector. The separation of FT and its deuterated analogue, FT-{sup 2}H{sub 19}, was achieved within 15 min a column temperature of 260degC by using a 25 m column. Measurement of the samples prepared by the addition of a known amount of FT in the range of 0.2 to 40 ng/ml with 20 ng/ml of FT-{sup 2}H{sub 19} to human control serum allowed observation of a linear relationship between the peak area ratio and the added amount ratio. The correlation coefficient obtained by regression analysis was 0.999. The advantage of the present isotope dilution method was demonstrated by comparison with other FT analogues which substituted a propionyl group with an acetyl group or a phenethyl group with a benzyl group as the internal standard. The present method was used to determine the serum level of FT in surgical patients after i.v. administration. No endogenous compounds and concomitant drugs interfered with the detection of FT or FT-{sup 2}H{sub 19}. This method was considered to be useful for the pharmacokinetic study of FT in patients. (author)

  5. Trace analysis of sulfamethazine in animal feed, human urine, and wastewater by electron capture gas chromatography

    Energy Technology Data Exchange (ETDEWEB)

    Holder, C.L.; Thompson, H.C. Jr.; Bowman, M.C.


    Sulfamethazine, a widely used antibacterial drug additive in feeds for swine, chickens, and cattle, was scheduled for toxicological evaluation because of potential human health hazards associated with its residues in edible animal tissues. Analytical chemical procedures that would ensure proper concentration, homogeneity, and stability of the drug in dosed feed and its safe usage during the animal studies were prerequisites for such toxicological tests. Electron capture gas chromatographic (EC/GC) methods were therefore devised for the analysis of sulfamethazine residues in animal feed, human urine, and wastewater at levels as low as 100, 10, and 10 ppb, respectively. Sample extracts were cleaned up by using liquid/liquid partitioning, and the extracts were subjected to two derivatizations followed by cleanup on a silica gel column. The derivatizations of sulfamethazine consisted of methylation followed by trifluoroacetylation of the primary amine function. Ancillary data concerning stability of the compound in animal feed, water, and as a dry residue on glass, extraction efficiencies, partition values with various solvents, and the analysis of residues in feed by high pressure liquid chromatography (HPLC) at levels as low as 1.0 ppm are presented.

  6. Multiresidue analysis of environmental pollutants in edible vegetable oils by gas chromatography-tandem mass spectrometry. (United States)

    Zhou, Rui-Ze; Jiang, Jie; Mao, Ting; Zhao, Ya-Song; Lu, Yong


    A novel multiresidue determination of polycyclic aromatic hydrocarbons (PAHs), phthalate esters (PAEs) and alkylphenols (APs) in edible vegetable oils was developed. The samples were extracted with hexane-saturated acetonitrile, and after concentration, the extract was directly qualitatively and quantitatively analyzed by gas chromatography-tandem mass spectrometry (GC-MS/MS) with multiple reaction monitoring (MRM) in positive ion mode. The calibration curve displayed good linearity in the range of 2-100 μg/L, with correlation coefficients greater than 0.99. The mean recoveries were 70.0-110.8% by analysis of spiked oil, and the relative standard deviations (RSDs) were 2.1-10.2% (n=6), respectively. The limits of detection (LODs) for the 23 PAHs, 17 PAEs and 3 APs were 0.1-1.0 μg/kg, 0.1-4.0 μg/kg and 1.2-3.0 μg/kg, respectively. The established method effectively avoided interference from large amounts of lipids and pigments. It was applied to real sample and shown to be a rapid and reliable alternative for determination and confirmation in routine analysis.

  7. In situ Analysis of Organic Compounds on Mars using Chemical Derivatization and Gas Chromatography Mass Spectrometry (United States)

    Glavin, D. P.; Buch, A.; Cabane, M.; Coll, P.; Navarro-Gonzalez, R.; Mahaffy, P. R.


    One of the core science objectives of NASA's 2009 Mars Science Laboratory (MSL) mission is to determine the past or present habitability of Mars. The search for key organic compounds relevant to terrestrial life will be an important part of that assessment. We have developed a protocol for the analysis of amino acids and carboxylic acids in Mars analogue materials using gas chromatography mass spectrometry (GCMS). As shown, a variety of carboxylic acids were readily identified in soil collected from the Atacama Desert in Chile at part-per-billion levels by GCMS after extraction and chemical derivatization using the reagent N,N-tert.-butyl (dimethylsilyl) trifluoroacetamide (MTBSTFA). Several derivatized amino acids including glycine and alanine were also detected by GCMS in the Atacama soil at lower concentrations (chromatogram not shown). Lacking derivatization capability, the Viking pyrolysis GCMS instruments could not have detected amino acids and carboxylic acids, since these non-volatile compounds require chemical transformation into volatile species that are stable in a GC column. We are currently optimizing the chemical extraction and derivatization technique for in situ GCMS analysis on Mars. Laboratory results of analyses of Atacama Desert samples and other Mars analogue materials using this protocol will be presented.

  8. Lifecycle Greenhouse Gas Analysis of an Anaerobic Codigestion Facility Processing Dairy Manure and Industrial Food Waste. (United States)

    Ebner, Jacqueline H; Labatut, Rodrigo A; Rankin, Matthew J; Pronto, Jennifer L; Gooch, Curt A; Williamson, Anahita A; Trabold, Thomas A


    Anaerobic codigestion (AcoD) can address food waste disposal and manure management issues while delivering clean, renewable energy. Quantifying greenhouse gas (GHG) emissions due to implementation of AcoD is important to achieve this goal. A lifecycle analysis was performed on the basis of data from an on-farm AcoD in New York, resulting in a 71% reduction in GHG, or net reduction of 37.5 kg CO2e/t influent relative to conventional treatment of manure and food waste. Displacement of grid electricity provided the largest reduction, followed by avoidance of alternative food waste disposal options and reduced impacts associated with storage of digestate vs undigested manure. These reductions offset digester emissions and the net increase in emissions associated with land application in the AcoD case relative to the reference case. Sensitivity analysis showed that using feedstock diverted from high impact disposal pathways, control of digester emissions, and managing digestate storage emissions were opportunities to improve the AcoD GHG benefits. Regional and parametrized emissions factors for the storage emissions and land application phases would reduce uncertainty.

  9. Life cycle greenhouse gas emissions analysis of catalysts for hydrotreating of fast pyrolysis bio-oil

    Energy Technology Data Exchange (ETDEWEB)

    Snowden-Swan, Lesley J.; Spies, Kurt A.; Lee, Guo-Shuh J.; Zhu, Yuanyuan


    Bio-oil from fast pyrolysis of biomass requires multi-stage catalytic hydroprocessing to produce hydrocarbon drop-in fuels. The current proposed process design involves fixed beds of ruthenium-based catalyst and conventional petroleum hydrotreating catalyst. Similar to petroleum processing, the catalyst is spent as a result of coking and other deactivation mechanisms, and must be changed out periodically. Biofuel life cycle greenhouse gas (GHG) assessments typically ignore the impact of catalyst consumed during fuel conversion as a result of limited lifetime, representing a data gap in the analyses. To help fill this data gap, life cycle GHGs were estimated for two representative examples of fast pyrolysis bio-oil hydrotreating catalyst, NiMo/Al2O3 and Ru/C, and integrated into the conversion-stage GHG analysis. Life cycle GHGs for the NiMo/Al2O3 and Ru/C catalysts are estimated at 5.5 and 81 kg CO2-e/kg catalyst, respectively. Contribution of catalyst consumption to total conversion-stage GHGs is 0.5% for NiMo/Al2O3 and 5% for Ru/C. This analysis does not consider secondary sourcing of metals for catalyst manufacture and therefore these are likely to be conservative estimates compared to applications where a spent catalyst recycler can be used.

  10. CFD analysis of combustion of natural gas and syngas from biomass pyrolysis in the combustion chamber of a micro gas turbine

    Energy Technology Data Exchange (ETDEWEB)

    Fantozzi, Francesco; Laranci, Paolo; D' Alessandro, Bruno [University of Perugia (DII/UNIPG) (Italy). Dept. of Industrial Engineering], Emails:,,


    Micro gas turbines (MGT) can be profitably used for the production of distributed energy (DE), with the possibility to use gaseous fuels with low BTU derived from biomass or waste through the pyrolysis or gasification processes. These synthesis gases (SG) show significant differences with respect to natural gas (NG), in terms of composition, calorific value, content of hydrogen, tar and particulate matter content; such differences can be turn into problems of ignition, instability burning, difficulties in controlling the emissions and fouling. CFD analysis of the combustion process is an essential tool for identifying the main critical arising in using these gases, in order to modify existing geometries and to develop new generation of combustor for use with low BTU gases. This paper describes the activities of experimental and numerical analysis carried out to study the combustion process occurring inside an existing annular Rich-Quench-Lean (RQL) Combustion Chamber (CC) of a 80 kW MGT. In the paper some results of a CFD study of the combustion process performed with an original developed chemical models are reported in terms of temperature and velocity distributions inside the CC and in terms of compositions of turbine inlet gas and of its thermodynamic parameters (mass flow, temperature, pressure). An evaluation of pollutant emissions of CO, CO{sub 2} and NOx and a comparison with the available experimental data relating to the case of combustion of NG is also provided in the paper. Moreover, the carried out investigation concerns the case of operation with a SG fuel derived from biomass in an Integrated Pyrolysis Regenerated Plant (IPRP). (author)

  11. Uncertainty analysis of integrated gasification combined cycle systems based on Frame 7H versus 7F gas turbines. (United States)

    Zhu, Yunhua; Frey, H Christopher


    Integrated gasification combined cycle (IGCC) technology is a promising alternative for clean generation of power and coproduction of chemicals from coal and other feedstocks. Advanced concepts for IGCC systems that incorporate state-of-the-art gas turbine systems, however, are not commercially demonstrated. Therefore, there is uncertainty regarding the future commercial-scale performance, emissions, and cost of such technologies. The Frame 7F gas turbine represents current state-of-practice, whereas the Frame 7H is the most recently introduced advanced commercial gas turbine. The objective of this study was to evaluate the risks and potential payoffs of IGCC technology based on different gas turbine combined cycle designs. Models of entrained-flow gasifier-based IGCC systems with Frame 7F (IGCC-7F) and 7H gas turbine combined cycles (IGCC-7H) were developed in ASPEN Plus. An uncertainty analysis was conducted. Gasifier carbon conversion and project cost uncertainty are identified as the most important uncertain inputs with respect to system performance and cost. The uncertainties in the difference of the efficiencies and costs for the two systems are characterized. Despite uncertainty, the IGCC-7H system is robustly preferred to the IGCC-7F system. Advances in gas turbine design will improve the performance, emissions, and cost of IGCC systems. The implications of this study for decision-making regarding technology selection, research planning, and plant operation are discussed.


    The paper discusses the analysis of trace-level organic combustion process emissions using novel multidimensional gas chromatography-mass spectrometry (MDGC-MS) procedures. It outlines the application of the technique through the analyses of various incinerator effluent and produ...

  13. Thermo-economic analysis of a solid oxide fuel cell and steam injected gas turbine plant integrated with woodchips gasification

    DEFF Research Database (Denmark)

    Mazzucco, Andrea; Rokni, Masoud


    This paper presents a thermo-economic analysis of an integrated biogas-fueled solid oxide fuel cell (SOFC) system for electric power generation. Basic plant layout consists of a gasification plant (GP), an SOFC and a retrofitted steam-injected gas turbine (STIG). Different system configurations...

  14. Abnormal tyrosine and phenylalanine metabolism in patients with tyrosyluria and phenylketonuria; gas-liquid chromatographic analysis of urinary metabolites

    NARCIS (Netherlands)

    Wadman, S.K.; Heiden, C. van der; Ketting, D.; Sprang, F.J. van


    Gas-liquid chromatographic methods have been developed for the analysis of: urinary phenylalanine metabolites (I) in patients with phenylketonuria, tyrosine metabolites (II) in patients with a disturbed tyrosine metabolism at the level of p-hydroxyphenylpyruvate hydroxylase, and homogentisic acid in

  15. Ionic liquids as silica deactivating agents in gas chromatography for direct analysis of primary amines in water

    NARCIS (Netherlands)

    Krzyzaniak, A.; Weggemans, W.; Schuur, B.; Haan, de A.B.


    Analysis of primary amines in aqueous samples remains a challenging analytical issue. The preferred approach by gas chromatography is hampered by interactions of free silanol groups with the highly reactive amine groups, resulting in inconsistent measurements. Here, we report a method for direct ana

  16. Analysis of benzene, toluene, ethylbenzene and xylenes in soils by headspace and gas chromatography/flame ionization detector

    Directory of Open Access Journals (Sweden)

    Jurandir Pereira Pinto


    Full Text Available The constituents of gasoline: benzene, toluene, ethylbenzene and xylenes (BTEX are frequently found in soils due to leaks in fuel storage tanks and they present chronic toxicity. In this work it was developed and validated a methodology of BTEX analysis in soil by gas chromatography/ flame ionization detector and static headspace. The recovery of BTEX in soil samples was evaluated using soils with different textures (sandy and loamy. The analysis method showed good resolution, in a low time of analysis (less than 30 minutes. Limits of quantification of 0.05 mg Kg¯¹ soil for benzene, toluene, ethylbenzene and xylenes are below the guiding values that range from 0.15 to 95 mg Kg¯¹ soil, established to determine soil quality. It was verified that the methodology enables the use of this method for BTEX analysis of soil samples for passive environmental identification of gas stations.

  17. Parametric Analysis of the Exergoeconomic Operation Costs, Environmental and Human Toxicity Indexes of the MF501F3 Gas Turbine

    Directory of Open Access Journals (Sweden)

    Edgar Vicente Torres-González


    Full Text Available This work presents an energetic, exergoeconomic, environmental, and toxicity analysis of the simple gas turbine M501F3 based on a parametric analysis of energetic (thermal efficiency, fuel and air flow rates, and specific work output, exergoeconomic (exergetic efficiency and exergoeconomic operation costs, environmental (global warming, smog formation, acid rain indexes, and human toxicity indexes, by taking the compressor pressure ratio and the turbine inlet temperature as the operating parameters. The aim of this paper is to provide an integral, systematic, and powerful diagnostic tool to establish possible operation and maintenance actions to improve the gas turbine’s exergoeconomic, environmental, and human toxicity indexes. Despite the continuous changes in the price of natural gas, the compressor, combustion chamber, and turbine always contribute 18.96%, 53.02%, and 28%, respectively, to the gas turbine’s exergoeconomic operation costs. The application of this methodology can be extended to other simple gas turbines using the pressure drops and isentropic efficiencies, among others, as the degradation parameters, as well as to other energetic systems, without loss of generality.

  18. Gas chromatography mass spectrometry computer analysis of volatile halogenated hydrocarbons in man and his environment--A multimedia environmental study. (United States)

    Barkley, J; Bunch, J; Bursey, J T; Castillo, N; Cooper, S D; Davis, J M; Erickson, M D; Harris, B S; Kirkpatrick, M; Michael, L C; Parks, S P; Pellizzari, E D; Ray, M; Smith, D; Tomer, K B; Wagner, R; Zweidinger, R A


    As part of a study to make a comparative analysis of selected halogenated compounds in man and the environmental media, a quantitative gas chromatography mass spectrometric analysis of the levels of the halogenated compounds found in the breath, blood and urine of an exposed population (Old Love Canal area, Niagara, New York) and their immediate environment (air and water) was undertaken. In addition, levels of halogenated hydrocarbons in air samples taken in the general Buffalo, Niagara Falls area were determined.

  19. The Concept and Security Analysis of Wireless Sensor Network for Gas Lift in Oilwells

    Directory of Open Access Journals (Sweden)

    Bielecki Bartlomiej


    Full Text Available Pipelines, wellbores and ground installations are permanently controlled by sensors spread across the crucial points in the whole area. One of the most popular techniques to support proper oil drive in a wellbore is a Gas Lift. In this paper we present the concept of using wireless sensor network (WSN in the oil and gas industry installations. Assuming that Gas Lift Valves (GLVs in a wellbore annulus are sensor controlled, the proper amount of injected gas should be provided. In a ground installation, the optimized amount of loaded gas is a key factor in the effcient oil production. This paper considers the basic foundations and security requirements of WSN dedicated to Gas Lift Installations. Possible attack scenarios and their influence on the production results are shown as well.

  20. Analysis on produce mechanism and influence factor of CO gas on the coal exploitation working face

    Institute of Scientific and Technical Information of China (English)

    DENG Jun; JIANG Zhi-gang; XIAO Lei


    Summarized the four main sources of CO gas on the working face based oninvestigation and local observation: firstly, it analyzed the mechanism that CO gas wasproduced by spontaneous combustion and oxygenation of gob residual coal; next, it illus-trated the theory that special coal seam deposits natural CO gas, and provided correlativeexperiment data; and then, it illustrated the reason of the CO gas in working face in-creased relatively in the course of coal cutter's shearing, according to the translation be-tween mechanism energy and inner energy and the rupture of carbon molecule side chainduring coal exploitation; lastly, illustrated the reason of CO gas appearance and the rela-tively release quantity during coal mine blasting underground. We find out the source ofCO gas on the working face accurately, and provide advantages for appropriate preventionand practical management measures.

  1. Flammable Gas Safety Program: actual waste organic analysis FY 1996 progress report; Flammable Gas Safety Program: actual waste organic analysis FY 1996 progress report

    Energy Technology Data Exchange (ETDEWEB)

    Clauss, S.A.; Grant, K.E.; Hoopes, V.; Mong, G.M.; Rau, J.; Steele, R.; Wahl, K.H.


    This report describes the status of optimizing analytical methods to account for the organic components in Hanford waste tanks, with emphasis on tanks assigned to the Flammable Gas Watch List. The methods developed are illustrated by their application to samples from Tanks 241-SY-103 and 241-S-102. Capability to account for organic carbon in Tank SY-101 was improved significantly by improving techniques for isolating organic constituents relatively free from radioactive contamination and by improving derivatization methodology. The methodology was extended to samples from Tank SY-103 and results documented in this report. Results from analyzing heated and irradiated SY-103 samples (Gas Generation Task) and evaluating methods for analyzing tank waste directly for chelators and chelator fragments are also discussed.

  2. Analysis of nanowire transistor based nitrogen dioxide gas sensor – A simulation study

    Directory of Open Access Journals (Sweden)

    Gaurav Saxena


    Full Text Available Sensors sensitivity, selectivity and stability has always been a prime design concern for gas sensors designers. Modeling and simulation of gas sensors aids the designers in improving their performance. In this paper, different routes for the modeling and simulation of a semiconducting gas sensor is presented. Subsequently, by employing one of the route, the response of Zinc Oxide nanowire transistor towards nitrogen dioxide ambient is simulated. In addition to the sensing mechanism, simulation study of gas species desorption by applying a recovery voltage is also presented.


    Institute of Scientific and Technical Information of China (English)

    Xu Boyan; Liang Fuyou; Cai Shaoli


    Aiming at the change in intake air flow caused by the injection of natural gas in intake manifold ifone simply replaces the gasoline injector with natural gas injector with the installing position of injector in intake manifold unchanged, and also the reflection of gas toward intake manifold inlet resulted from the impingement between the injected large volumetric natural gas jet and intake valve, an impulsively started natural gas jet injected from a gas injector is characterized as a three-dimensional unsteady compressible viscous turbulent flow, based on which its transient development process is numerically analyzed using general-purpose CFD codes. The predicted velocity vector maps show a vortex, which indicates the occurrence of an unsteady state jet region, is formed downstream of the jet. A schlieren apparatus is utilized to get several groups of visible schlieren photographs of natural gas jets. In the experiment, photographs of natural gas jets taken by a CCD camera are laid in a portrait processor where the shapes, tip penetration distance and injection angles of the gas jets are investigated. Comparisons between predicted results and measurements indicate an excellent agreement between simulations and experimental results.

  4. Geological evolution and analysis of confirmed or suspected gas hydrate localities: Volume 10, Basin analysis, formation and stability of gas hydrates of the Aleutian Trench and the Bering Sea

    Energy Technology Data Exchange (ETDEWEB)

    Krason, J.; Ciesnik, M.


    Four major areas with inferred gas hydrates are the subject of this study. Two of these areas, the Navarin and the Norton Basins, are located within the Bering Sea shelf, whereas the remaining areas of the Atka Basin in the central Aleutian Trench system and the eastern Aleutian Trench represent a huge region of the Aleutian Trench-Arc system. All four areas are geologically diverse and complex. Particularly the structural features of the accretionary wedge north of the Aleutian Trench still remain the subjects of scientific debates. Prior to this study, suggested presence of the gas hydrates in the four areas was based on seismic evidence, i.e., presence of bottom simulating reflectors (BSRs). Although the disclosure of the BSRs is often difficult, particularly under the structural conditions of the Navarin and Norton basins, it can be concluded that the identified BSRs are mostly represented by relatively weak and discontinuous reflectors. Under thermal and pressure conditions favorable for gas hydrate formation, the relative scarcity of the BSRs can be attributed to insufficient gas supply to the potential gas hydrate zone. Hydrocarbon gas in sediment may have biogenic, thermogenic or mixed origin. In the four studied areas, basin analysis revealed limited biogenic hydrocarbon generation. The migration of the thermogenically derived gases is probably diminished considerably due to the widespread diagenetic processes in diatomaceous strata. The latter processes resulted in the formation of the diagenetic horizons. The identified gas hydrate-related BSRs seem to be located in the areas of increased biogenic methanogenesis and faults acting as the pathways for thermogenic hydrocarbons.

  5. A gas ionisation detector in the axial (Bragg) geometry used for the time-of-flight elastic recoil detection analysis

    Energy Technology Data Exchange (ETDEWEB)

    Siketić, Zdravko; Skukan, Natko; Bogdanović Radović, Iva [Ruđer Bošković Institute, Bijenička cesta 54, 10000 Zagreb (Croatia)


    In this paper, time-of-flight elastic recoil detection analysis spectrometer with a newly constructed gas ionization detector for energy detection is presented. The detector is designed in the axial (Bragg) geometry with a 3 × 3 array of 50 nm thick Si{sub 3}N{sub 4} membranes as an entrance window. 40 mbar isobutane gas was sufficient to stop a 30 MeV primary iodine beam as well as all recoils in the detector volume. Spectrometer and detector performances were determined showing significant improvement in the mass and energy resolution, respectively, comparing to the spectrometer with a standard silicon particle detector for an energy measurement.

  6. Risk Analysis on Leakage Failure of Natural Gas Pipelines by Fuzzy Bayesian Network with a Bow-Tie Model

    Directory of Open Access Journals (Sweden)

    Xian Shan


    Full Text Available Pipeline is the major mode of natural gas transportation. Leakage of natural gas pipelines may cause explosions and fires, resulting in casualties, environmental damage, and material loss. Efficient risk analysis is of great significance for preventing and mitigating such potential accidents. The objective of this study is to present a practical risk assessment method based on Bow-tie model and Bayesian network for risk analysis of natural gas pipeline leakage. Firstly, identify the potential risk factors and consequences of the failure. Then construct the Bow-tie model, use the quantitative analysis of Bayesian network to find the weak links in the system, and make a prediction of the control measures to reduce the rate of the accident. In order to deal with the uncertainty existing in the determination of the probability of basic events, fuzzy logic method is used. Results of a case study show that the most likely causes of natural gas pipeline leakage occurrence are parties ignore signage, implicit signage, overload, and design defect of auxiliaries. Once the leakage occurs, it is most likely to result in fire and explosion. Corresponding measures taken on time will reduce the disaster degree of accidents to the least extent.

  7. Numerical analysis of heat transfer in the exhaust gas flow in a diesel power generator (United States)

    Brito, C. H. G.; Maia, C. B.; Sodré, J. R.


    This work presents a numerical study of heat transfer in the exhaust duct of a diesel power generator. The analysis was performed using two different approaches: the Finite Difference Method (FDM) and the Finite Volume Method (FVM), this last one by means of a commercial computer software, ANSYS CFX®. In FDM, the energy conservation equation was solved taking into account the estimated velocity profile for fully developed turbulent flow inside a tube and literature correlations for heat transfer. In FVM, the mass conservation, momentum, energy and transport equations were solved for turbulent quantities by the K-ω SST model. In both methods, variable properties were considered for the exhaust gas composed by six species: CO2, H2O, H2, O2, CO and N2. The entry conditions for the numerical simulations were given by experimental data available. The results were evaluated for the engine operating under loads of 0, 10, 20, and 37.5 kW. Test mesh and convergence were performed to determine the numerical error and uncertainty of the simulations. The results showed a trend of increasing temperature gradient with load increase. The general behaviour of the velocity and temperature profiles obtained by the numerical models were similar, with some divergence arising due to the assumptions made for the resolution of the models.

  8. A Principle Component Analysis of Galaxy Properties from a Large, Gas-Selected Sample

    Directory of Open Access Journals (Sweden)

    Yu-Yen Chang


    concluded that this is in conflict with the CDM model. Considering the importance of the issue, we reinvestigate the problem using the principal component analysis on a fivefold larger sample and additional near-infrared data. We use databases from the Arecibo Legacy Fast Arecibo L-band Feed Array Survey for the gas properties, the Sloan Digital Sky Survey for the optical properties, and the Two Micron All Sky Survey for the near-infrared properties. We confirm that the parameters are indeed correlated where a single physical parameter can explain 83% of the variations. When color (g-i is included, the first component still dominates but it develops a second principal component. In addition, the near-infrared color (i-J shows an obvious second principal component that might provide evidence of the complex old star formation. Based on our data, we suggest that it is premature to pronounce the failure of the CDM model and it motivates more theoretical work.

  9. Characterization of 22 Vibrio species by gas chromatography analysis of their cellular fatty acids. (United States)

    Urdaci, M C; Marchand, M; Grimont, P A


    The cellular fatty acid compositions of 51 Vibrio strains belonging to 22 species as well as five Aeromonas strains were determined by using capillary gas-liquid chromatography (GLC). The major fatty acids were most often hexadecenoic, hexadecanoic and octadecenoic acids. Heptadecenoic acid was present in significant amounts in V. alginolyticus, V. natriegens, V. parahaemolyticus and "Vibrio navarrensis". Twenty fatty acids including branched and hydroxy acids were detected in the genus Vibrio. Quantitative results were treated by principal component analysis to display groups of strains. The first three components (accounting for 69% of the variance) showed the type strains of V. fischeri, V. ordalii, V. damsela, V. mediterranei, V. tubiashii, V. campbellii, V. pelagius, V. gazogenes, and V. nereis to be unclustered. V. alginolyticus (4 strains) and V. parahaemolyticus (4 strains) showed some overlap and the type strain of V. natriegens was in their neighborhood. V. harveyi (4 strains) formed a cluster and V. vulnificus was in its vicinity. V. cholerae (5 strains) overlapped with V. diazotrophicus (3 strains) and was close to the type strain of V. mimicus and V. anguillarum. V. metschnikovii (3 strains) clustered with the type strain of V. cincinnatiensis. A decision tree was devised for the identification of Vibrio species based on qualitative characteristics of fatty acid patterns. However, the following three groups, V. alginolyticus-V. parahaemolyticus-V. natriegens, V. metschnikovii-V. cincinnatiensis and V. cholerae-V. mimicus could not be split into such a decision tree.

  10. Fractal analysis of fracture increasing spontaneous imbibition in porous media with gas-saturated

    KAUST Repository

    Cai, Jianchao


    Spontaneous imbibition (SI) of wetting liquid into matrix blocks due to capillary pressure is regarded as an important recovery mechanism in low permeability fractured reservoir. In this paper, an analytical model is proposed for characterizing SI horizontally from a single plane fracture into gas-saturated matrix blocks. The presented model is based on the fractal character of pores in porous matrix, with gravity force included in the entire imbibition process. The accumulated mass of wetting liquid imbibed into matrix blocks is related to a number of factors such as contact area, pore fractal dimension, tortuosity, maximum pore size, porosity, liquid density and viscosity, surface tension, contact angle, as well as height and tilt angle of the fracture. The mechanism of fracture-enhanced SI is analyzed accordingly. Because of the effect of fracture, the gravity force is positive to imbibition process. Additionally, the farther away from the fracture top of the pore, the more influential the hydrostatic pressure is upon the imbibition action. The presented fractal analysis of horizontal spontaneous imbibition from a single fracture could also shed light on the scaling study of the mass transfer function between matrix and fracture system of fractured reservoirs. © 2013 World Scientific Publishing Company.

  11. Kinematical analysis of the ionized gas in the nuclear region of NGC 4214

    CERN Document Server

    Maíz-Appelániz, J; Mas-Hesse, J M; Tenorio-Tagle, G


    We present in this paper a detailed study of the kinematical properties of the ionized gas around the young massive star clusters in the nucleus of NGC 4214. The analysis is based on bidimensional spectroscopical data, allowing to derive the spatial variation of different properties (intensity, velocity and width / line splitting) of the emission lines H\\alpha and [O III] \\lambda 5007 along the nuclear region. We have found that the Giant H II region around the two most massive clusters in NGC 4214 (A and B) is resolved into two clearly separated regions. We have not detected superbubbles with the properties we would expect according to the evolutionary state of the stellar clusters, but just a partial ring feature around the most massive one and two expanding shells around cluster B. The first expanding shell seems to have experienced blowout, whereas the second one is still complete. A possible explanation to this phenomenon is that the most massive stars in a starburst spend a large fraction of their lives...

  12. Validation of SCALE for High Temperature Gas-Cooled Reactors Analysis

    Energy Technology Data Exchange (ETDEWEB)

    Ilas, Germina [ORNL; Ilas, Dan [ORNL; Kelly, Ryan P [ORNL; Sunny, Eva E [ORNL


    This report documents verification and validation studies carried out to assess the performance of the SCALE code system methods and nuclear data for modeling and analysis of High Temperature Gas-Cooled Reactor (HTGR) configurations. Validation data were available from the International Handbook of Evaluated Reactor Physics Benchmark Experiments (IRPhE Handbook), prepared by the International Reactor Physics Experiment Evaluation Project, for two different HTGR designs: prismatic and pebble bed. SCALE models have been developed for HTTR, a prismatic fuel design reactor operated in Japan and HTR-10, a pebble bed reactor operated in China. The models were based on benchmark specifications included in the 2009, 2010, and 2011 releases of the IRPhE Handbook. SCALE models for the HTR-PROTEUS pebble bed configuration at the PROTEUS critical facility in Switzerland have also been developed, based on benchmark specifications included in a 2009 IRPhE draft benchmark. The development of the SCALE models has involved a series of investigations to identify particular issues associated with modeling the physics of HTGRs and to understand and quantify the effect of particular modeling assumptions on calculation-to-experiment comparisons.

  13. Meta-Analysis of Estimates of Life Cycle Greenhouse Gas Emissions from Concentrating Solar Power: Preprint

    Energy Technology Data Exchange (ETDEWEB)

    Heath, G. A.; Burkhardt, J. J.


    In reviewing life cycle assessment (LCA) literature of utility-scale CSP systems, this analysis focuses on clarifying central tendency and reducing variability in estimates of life cycle greenhouse gas (GHG) emissions through a meta-analytical process called harmonization. From 125 references reviewed, 10 produced 36 independent GHG emission estimates passing screens for quality and relevance: 19 for parabolic trough technology and 17 for power tower technology. The interquartile range (IQR) of published GHG emission estimates was 83 and 20 g CO2eq/kWh for trough and tower, respectively, with medians of 26 and 38 g CO2eq/kWh. Two levels of harmonization were applied. Light harmonization reduced variability in published estimates by using consistent values for key parameters pertaining to plant design and performance. Compared to the published estimates, IQR was reduced by 69% and median increased by 76% for troughs. IQR was reduced by 26% for towers, and median was reduced by 34%. A second level of harmonization was applied to five well-documented trough LC GHG emission estimates, harmonizing to consistent values for GHG emissions embodied in materials and from construction activities. As a result, their median was further reduced by 5%, while the range increased by 6%. In sum, harmonization clarified previous results.

  14. Integrated Life Cycle Energy and Greenhouse Gas Analysis of Exterior Wall Systems for Residential Buildings

    Directory of Open Access Journals (Sweden)

    Reza Broun


    Full Text Available This paper investigates the breakdown of primary energy use and greenhouse gas (GHG emissions of two common types of exterior walls in the U.K.: insulated concrete form (ICF and cavity walls. A comprehensive assessment was conducted to evaluate the environmental performance of each exterior wall system over 50 years of service life in Edinburgh and Bristol. The results indicate that for both wall systems, use phase is the major contributor to the overall environmental impacts, mainly due to associated electricity consumption. For the ICF wall system in Edinburgh, 91% of GHG emissions were attributed to the use phase, with 7.8% in the pre-use and 1.2% in end-of-life phases. For the same system in Bristol, emissions were 89%, 9% and 2%, respectively. A similar trend was observed for cavity wall systems in both locations. It was concluded that in each scenario, the ICF wall system performed better when compared to the cavity wall system. The results of the sensitivity analysis clearly show that the uncertainties relevant to the change of the thickness of the wall are quite tolerable: variable up to 5%, as far as energy and greenhouse emissions are concerned.

  15. Cycle Analysis of Micro Gas Turbine-Molten Carbonate Fuel Cell Hybrid System (United States)

    Kimijima, Shinji; Kasagi, Nobuhide

    A hybrid system based on a micro gas turbine (µGT) and a high-temperature fuel cell, i.e., molten carbonate fuel cell (MCFC) or solid oxide fuel cell (SOFC), is expected to achieve a much higher efficiency than conventional distributed power generation systems. In this study, a cycle analysis method and the performance evaluation of a µGT-MCFC hybrid system, of which the power output is 30kW, are investigated to clarify its feasibility. We developed a general design strategy in which a low fuel input to a combustor and higher MCFC operating temperature result in a high power generation efficiency. A high recuperator temperature effectiveness and a moderate steam-carbon ratio are the requirements for obtaining a high material strength in a turbine. In addition, by employing a combustor for complete oxidation of MCFC effluents without additional fuel input, i.e., a catalytic combustor, the power generation efficiency of a µGT-MCFC is achieved at over 60%(LHV).

  16. Determination of Milk Fat Adulteration with Vegetable Oils and Animal Fats by Gas Chromatographic Analysis. (United States)

    Kim, Jin-Man; Kim, Ha-Jung; Park, Jung-Min


    This study assessed the potential application of gas chromatography (GC) in detecting milk fat (MF) adulteration with vegetable oils and animal fats and of characterizing samples by fat source. One hundred percent pure MF was adulterated with different vegetable oils and animal fats at various concentrations (0%, 10%, 30%, 50%, 70%, and 90%). GC was used to obtain the fatty acid (FA) profiles, triacylglycerol (TG) contents, and cholesterol contents. The pure MF and the adulterated MF samples were discriminated based on the total concentrations of saturated FAs and on the 2 major FAs (oleic acid [C18:1n9c] and linoleic acid [C18:2n6c], TGs [C52 and C54], and cholesterol contents using statistical analysis to compared difference. These bio-markers enabled the detection of as low as 10% adulteration of non-MF into 100% pure MF. The study demonstrated the high potential of GC to rapidly detect MF adulteration with vegetable and animal fats, and discriminate among commercial butter and milk products according to the fat source. These data can be potentially useful in detecting foreign fats in these butter products. Furthermore, it is important to consider that several individual samples should be analyzed before coming to a conclusion about MF authenticity.

  17. Portable Dew Point Mass Spectrometry System for Real-Time Gas and Moisture Analysis (United States)

    Arkin, C.; Gillespie, Stacey; Ratzel, Christopher


    A portable instrument incorporates both mass spectrometry and dew point measurement to provide real-time, quantitative gas measurements of helium, nitrogen, oxygen, argon, and carbon dioxide, along with real-time, quantitative moisture analysis. The Portable Dew Point Mass Spectrometry (PDP-MS) system comprises a single quadrupole mass spectrometer and a high vacuum system consisting of a turbopump and a diaphragm-backing pump. A capacitive membrane dew point sensor was placed upstream of the MS, but still within the pressure-flow control pneumatic region. Pressure-flow control was achieved with an upstream precision metering valve, a capacitance diaphragm gauge, and a downstream mass flow controller. User configurable LabVIEW software was developed to provide real-time concentration data for the MS, dew point monitor, and sample delivery system pressure control, pressure and flow monitoring, and recording. The system has been designed to include in situ, NIST-traceable calibration. Certain sample tubing retains sufficient water that even if the sample is dry, the sample tube will desorb water to an amount resulting in moisture concentration errors up to 500 ppm for as long as 10 minutes. It was determined that Bev-A-Line IV was the best sample line to use. As a result of this issue, it is prudent to add a high-level humidity sensor to PDP-MS so such events can be prevented in the future.

  18. CFD Analysis of the Fuel Temperature in High Temperature Gas-Cooled Reactors

    Energy Technology Data Exchange (ETDEWEB)

    In, W. K.; Chun, T. H.; Lee, W. J.; Chang, J. H. [Korea Atomic Energy Research Institute, Taejon (Korea, Republic of)


    High temperature gas-cooled reactors (HTGR) have received a renewed interest as potential sources for future energy needs, particularly for a hydrogen production. Among the HTGRs, the pebble bed reactor (PBR) and a prismatic modular reactor (PMR) are considered as the nuclear heat source in Korea's nuclear hydrogen development and demonstration project. PBR uses coated fuel particles embedded in spherical graphite fuel pebbles. The fuel pebbles flow down through the core during an operation. PMR uses graphite fuel blocks which contain cylindrical fuel compacts consisting of the fuel particles. The fuel blocks also contain coolant passages and locations for absorber and control material. The maximum fuel temperature in the core hot spot is one of the important design parameters for both PBR and PMR. The objective of this study is to predict the fuel temperature distributions in PBR and PMR using a computational fluid dynamics(CFD) code, CFX-5. The reference reactor designs used in this analysis are PBMR400 and GT-MHR600.

  19. Analysis of siloxanes in hydrocarbon mixtures using comprehensive two-dimensional gas chromatography. (United States)

    Ghosh, Abhijit; Seeley, Stacy K; Nartker, Steven R; Seeley, John V


    A comprehensive two-dimensional gas chromatography (GC×GC) method for separating siloxanes from hydrocarbons has been developed using a systematic process. First, the retention indices of a set of siloxanes and a set of hydrocarbons were determined on 6 different stationary phases. The retention indices were then used to model GC×GC separation on 15 different stationary phase pairs. The SPB-Octyl×DB-1 pair was predicted to provide the best separation of the siloxanes from the hydrocarbons. The efficacy of this stationary phase pair was experimentally tested by performing a GC×GC analysis of gasoline spiked with siloxanes and by analyzing biogas obtained from a local wastewater treatment facility. The model predictions agreed well with the experimental results. The SPB-Octyl×DB-1 stationary phase pair constrained the hydrocarbons to a narrow range of secondary retention times and fully isolated the siloxanes from the hydrocarbon band. The resulting GC×GC method allows siloxanes to be resolved from complex mixtures of hydrocarbons without requiring the use of a selective detector.

  20. Gas chromatographic quantitative analysis of methanol in wine: operative conditions, optimization and calibration model choice. (United States)

    Caruso, Rosario; Gambino, Grazia Laura; Scordino, Monica; Sabatino, Leonardo; Traulo, Pasqualino; Gagliano, Giacomo


    The influence of the wine distillation process on methanol content has been determined by quantitative analysis using gas chromatographic flame ionization (GC-FID) detection. A comparative study between direct injection of diluted wine and injection of distilled wine was performed. The distillation process does not affect methanol quantification in wines in proportions higher than 10%. While quantification performed on distilled samples gives more reliable results, a screening method for wine injection after a 1:5 water dilution could be employed. The proposed technique was found to be a compromise between the time consuming distillation process and direct wine injection. In the studied calibration range, the stability of the volatile compounds in the reference solution is concentration-dependent. The stability is higher in the less concentrated reference solution. To shorten the operation time, a stronger temperature ramp and carrier flow rate was employed. With these conditions, helium consumption and column thermal stress were increased. However, detection limits, calibration limits, and analytical method performances are not affected substantially by changing from normal to forced GC conditions. Statistical data evaluation were made using both ordinary (OLS) and bivariate least squares (BLS) calibration models. Further confirmation was obtained that limit of detection (LOD) values, calculated according to the 3sigma approach, are lower than the respective Hubaux-Vos (H-V) calculation method. H-V LOD depends upon background noise, calibration parameters and the number of reference standard solutions employed in producing the calibration curve. These remarks are confirmed by both calibration models used.


    Directory of Open Access Journals (Sweden)

    Mr. Dmitrii G. Kolykhalov


    Full Text Available Тhis article is devoted to the gas-liquid systems of the aircraft and their structural and technological analysis. The paper shows the characteristics of pipelines, considers the types of working fluids and gases and covers the range of perceived internal pressures. The paper presents the classification of pipelines of flying vehicles from the point of view of their working conditions, taking into account the perceived internal pressure. The article also shows the classification scheme of major groups and types of pipe connections and fittings. The article focuses on the scheme of permanent joints made with soldering and welding, as well as the split of mobile and fixed joints of different types. The authors study the combined connections. The authors have also developed classification schemes of aircraft piping systems that depend on the system pressure. A classification scheme of piping connections, depending on the method of connection, mobility, presence of seals is singled out. The research is ilustrated with examples of compounds of different types.

  2. Gas chromatographic analysis of histamine in mahi-mahi (Coryphaena hippurus). (United States)

    Antoine, Francis R; Wei, Cheng-I; Otwell, W Steve; Sims, Charlie A; Littell, Ramon C; Hogle, Amanda D; Marshall, Maurice R


    Several authors have studied histamine using gas chromatography (GC) as a tool for quantitation, but the methods used were not always suitable depending on the kind of food. Problems frequently cited include incomplete histamine elution from the columns and peak tailing. Histamine is of interest because it is the factor common to all cases of scombroid poisoning, it has physiological and biological activity, and it is a chemical indicator of fish quality. In this study a modified GC method was used to quantify histamine in mahi-mahi (Coryphaena hippurus). Mean recovery was 67% for the GC method, compared with 90% for the AOAC fluorometric method. There was a 0.96 correlation of the GC histamine values with those of the AOAC fluorometric method. A temperature program, splitless/split injection, and analyte cleanup were essential for GC properties. Histamine retention time was 8.2 min. The method allowed peak height to be used for quantitation and simultaneous analysis of cadaverine and putrescine.

  3. An analysis of the chaotic motion of particles of different sizes in a gas fluidized bed

    Institute of Scientific and Technical Information of China (English)


    The dynamic behavior of individual particles during the mixing/segregation process of particle mixtures in a gas fluidized bed is analyzed. The analysis is based on the results generated from discrete particle simulation, with the focus on the trajectory of and forces acting on individual particles.Typical particles are selected representing three kinds of particle motion:a flotsam particle which is initially at the bottom part of the bed and finally fluidized at the top part of the bed; a jetsam particle which is initially at the top part of the bed and finally stays in the bottom de-fluidized layer of the bed; and a jetsam particle which is intermittently joining the top fluidized and bottom de-fluidized layers. The results show that the motion of a particle is chaotic at macroscopic or global scale, but can be well explained at a microscopic scale in terms of its interaction forces and contact conditions with other particles, particle-fluid interaction force, and local flow structure. They also highlight the need for establishing a suitable method to link the information generated and modeled at different time and length scales.

  4. Acrylamide analysis in food by liquid chromatographic and gas chromatographic methods. (United States)

    Elbashir, Abdalla A; Omar, Mei M Ali; Ibrahim, Wan Aini Wan; Schmitz, Oliver J; Aboul-Enein, Hassan Y


    Acrylamide (AA) is a compound classified as carcinogenic to humans by the International Agency for Research on Cancer. It was first discovered to be present in certain heated processed food by the Swedish National Food Administration (SNFA) and University of Stockholm in early 2002. The major pathway for AA formation in food is the Maillard reaction between reducing sugar and the amino acid asparagine at high temperature. Since the discovery of AA's presence in food, many analytical methods have been developed for determination of AA contents in different food matrices. Also, several studies have been conducted to develop extraction procedures for AA from difficult food matrices. AA is a small, highly polar molecule, which makes its extraction and analysis challenging. Many articles and reviews have been published dealing with AA in food. The aim of the review is to discuss AA formation in food, the factors affecting AA formation and removal, AA exposure assessment, AA extraction and cleanup from food samples, and analytical methods used in AA determination, such as high-performance liquid chromatography (HPLC) and gas chromatography (GC). Special attention is given to sample extraction and cleanup procedures and analytical techniques used for AA determination.

  5. Precursors of stall and surge processes in gas turbines revealed by wavelet analysis

    Energy Technology Data Exchange (ETDEWEB)

    Dremin, I.M.; Ivanov, O.V.; Nechitailo, V.A. [P.N. Lebedev Physical Institute, Moscow (Russian Federation); Furletov, V.I. [Central Institute for Aviation Motors, Moscow (Russian Federation); Terziev, V.G. [TEKO, Moscow (Russian Federation)


    Multiresolution wavelet analysis of pressure variations in a gas turbine compressor reveals the existence of precursors of stall and surge processes. Signals from eight pressure sensors positioned at various places within the compressor were recorded and digitized in three different operating modes in stationary conditions with a recording interval of 1 ms during 5-6 s. It has been discovered that there exists a scale of 32 intervals over which the dispersion (variance) of the wavelet coefficients shows a remarkable drop of about 40% for more than 1 s prior to the development of the malfunction. A shuffled sample of the same values of the pressure does not show such a drop demonstrating the dynamical origin of this effect. Higher order correlation moments reveal different slopes in these two regions differing by the variance values. The log-log dependence of the moments does not show clear fractal behavior because the scales of 16 and 32 intervals are not on the straight line of monofractals. This is a clear indication of the nonlinear response of the system at this scale. These results provide a means for automatic regulation of an engine, preventing possible failures. (author)

  6. Suspended trapping gas chromatography I fourier transform mass spectrometry for analysis of complex organic mixtures. (United States)

    Hogan, J D; Laude, D A


    The superior sensitivity , dynamic range, and mass measurement accuracy of suspended trapping pulse sequences for gas chromatography combined with Fourier transform mass spectrometry (GC/FTMS) separations of complex organic mixtures is demonstrated. By combining intense ionization conditions with a suspended trapping event prior to detection the working range of the trapped ion cell is increased by 10(3) . Improved detection limits are shown for the GC/FTMS separation of a peppermint oil, with the suspended trapping total ion chromatogram yielding 28 peaks, compared with 15 with a conventional trapping pulse sequence. A fivefold to fifteenfold improvement in signal-to-noise for suspended trapping measurements is also demonstrated with comparison spectra from separations of an unleaded gasoline sample. Suspended trapping spectra show little mass discrimination when an external ion reservoir is used, and chromatographic peak heights differ from conventional spectra by less than 30% if the initial ion population is within the space charge limit of the cell. Finally, average wide band mass measurement errors for components differing in concentration by several orders of magnitude are improved by a factor of 6 to 20 with suspended trapping compared with conventional trapping . For example, average errors of 8.7 ppm are obtained for a suspended trapping GC/FTMS separation of peppermint oil from a single calibration table in which the analysis is perfonned in the absence of calibrant.

  7. FTIR gas analysis with improved sensitivity and selectivity for CWA and TIC detection (United States)

    Phillips, Charles M.; Tan, Huwei


    This presentation describes the use of an FTIR (Fourier Transform Infrared)-based spectrometer designed to continuously monitor ambient air for the presence of chemical warfare agents (CWAs) and toxic industrial chemicals (TICs). The necessity of a reliable system capable of quickly and accurately detecting very low levels of CWAs and TICs while simultaneously retaining a negligible false alarm rate will be explored. Technological advancements in FTIR sensing have reduced noise while increasing selectivity and speed of detection. These novel analyzer design characteristics are discussed in detail and descriptions are provided which show how optical throughput, gas cell form factor, and detector response are optimized. The hardware and algorithms described here will explain why this FTIR system is very effective for the simultaneous detection and speciation of a wide variety of toxic compounds at ppb concentrations. Analytical test data will be reviewed demonstrating the system's sensitivity to and selectivity for specific CWAs and TICs; this will include recent data acquired as part of the DHS ARFCAM (Autonomous Rapid Facility Chemical Agent Monitor) project. These results include analyses of the data from live agent testing for the determination of CWA detection limits, immunity to interferences, detection times, residual noise analysis and false alarm rates. Sensing systems such as this are critical for effective chemical hazard identification which is directly relevant to the CBRNE community.

  8. Nonlinear analysis of gas-water/oil-water two-phase flow in complex networks

    CERN Document Server

    Gao, Zhong-Ke; Wang, Wen-Xu


    Understanding the dynamics of multi-phase flows has been a challenge in the fields of nonlinear dynamics and fluid mechanics. This chapter reviews our work on two-phase flow dynamics in combination with complex network theory. We systematically carried out gas-water/oil-water two-phase flow experiments for measuring the time series of flow signals which is studied in terms of the mapping from time series to complex networks. Three network mapping methods were proposed for the analysis and identification of flow patterns, i.e. Flow Pattern Complex Network (FPCN), Fluid Dynamic Complex Network (FDCN) and Fluid Structure Complex Network (FSCN). Through detecting the community structure of FPCN based on K-means clustering, distinct flow patterns can be successfully distinguished and identified. A number of FDCN’s under different flow conditions were constructed in order to reveal the dynamical characteristics of two-phase flows. The FDCNs exhibit universal power-law degree distributions. The power-law exponent ...

  9. Metrological control of the gas flow and analysis of mass conservation in Bolivia-Brasil gas pipeline; Controle metrologico da vazao de gas e analise da conservacao de massa no gasoduto Bolivia-Brazil

    Energy Technology Data Exchange (ETDEWEB)

    Palhares, Julio Cesar [TBG - Transportadora Brasileira Gasoduto Bolivia-Brasil, S.A., Rio de Janeiro, RJ (Brazil); Orlando, Alcir de Faro; Frota, Mauricio Nogueira [Pontificia Univ. Catolica do Rio de Janeiro, RJ (Brazil). Curso de Pos-graduacao em Metrologia para Qualidade Industrial


    International gas pipelines reflect a integrated commerce and impose a metrological challenge for the custody transferences that indistinctly imply in significant economic impact. This work argues the complex analysis of the mass balance and expression of uncertainties of the Gasoduto Bolivia-Brasil (3.150 Km of length, 557 Km in Bolivian territory and 2.593 Km that cross Brazil of West for East), today carrying approximately 60% from its maximum capacity (30 million of cubic meters daily), operating for the Transportadora Brasileira Gasoduto Bolivia Brasil S.A., a enterprise controlled by PETROBRAS Gas S/A (GASPETRO). The TBG measuring methods always taking care of the necessities of the customers as well as being lined up with the changes of the natural gas market. In six years of existence, the TBG came along with the legislation created for regulating agency in formation and adjusted to the establishment of the contract inspector, important landmarks of the evolution of the market. This work presents the definitions that guide the metrological subjects of the TBG, making use of efficient tools in answers for each demand and searching to satisfy its proper necessities, the necessities of its customers and the new demands of the regulating agency. (author)

  10. Cogeneration with gas turbine associated to the absorption refrigeration system: a computer program for exergy economics analysis; Cogeracao com turbina a gas associada ao sistema de refrigeracao por absorcao: um programa computacional para analise exergoeconomica

    Energy Technology Data Exchange (ETDEWEB)

    Antunes, Julio Santana [UNESP, Guaratingueta, SP (Brazil). Faculdade de Engenharia. Dept. de Matematica] E-mail:; Silveira, Jose Luz; Balestieri, Jose Antonio Perrella [UNESP, Guaratingueta, SP (Brazil). Faculdade de Engenharia. Dept. de Energia


    This paper presents the development of a computer program for exergy and economic analysis of cogeneration systems applying gas turbine associated to the absorption refrigeration system. The computer program selects gas turbine systems viewing the operation under thermal parity through a data base composed by gas turbines commercially available in the market, under the ISO (International Standard Organization). The computer program corrects the system performance parameters selected for the installation local conditions. The exergy and economic analysis are made based on the lowest exergy manufacturing cost where the best system is considered. A case study of the computer program application is presented.

  11. Development of a carbohydrate silylation method in ionic liquids for their gas chromatographic analysis. (United States)

    Ruiz-Aceituno, L; Carrero-Carralero, C; Ramos, L; Martinez-Castro, I; Sanz, M L


    This paper reports on the feasibility of silylation of low molecular weight carbohydrates dissolved in different ionic liquids (ILs) for their further analysis by gas chromatography (GC). Derivatization reagents (nature and amounts), temperature and time of reaction and stirring conditions were evaluated for different carbohydrates (i.e., glucose, mannose, fructose and lactose) dissolved in 1-ethyl-3-methylimidazolium dicyanamide [EMIM][DCA]. Evaluation of conformational isomerism of glucose dissolved in [EMIM][DCA] revealed the effect of the time of dissolution in the equilibration of α- and β-furanoses (up to 3% and 6%, respectively, after 70 h of incubation) and that 21 h sufficed to obtain results similar to those provided by the reference method involving pyridine. Once optimized, the proposed derivatization procedure provided satisfactory yields (i.e., close to 100%) using 100 μL of trimethylsilylimidazole (TMSI) at mild conditions (25°C) for a relatively short time (1h) for most of the investigated carbohydrates. Under these experimental conditions, linear responses (i.e., R(2) better than 0.974) were obtained in the tested range of 0.25-1mg of the derivatized target compounds. Other reagents, such as N,O-bis(trimethylsilyl)trifluoroacetamide (BSTFA)+1% trimethylchlorosilane (TMCS), were successfully used under ultrasonic conditions for aldose monosaccharides and disaccharides derivatization, while BSTFA was useful for ketose monosaccharides. The possibility of using the proposed method for the derivatization of selected carbohydrates dissolved in different ILs and the efficiency of the method applied to the analysis of carbohydrates present in real samples (fruit juices) have also been investigated.

  12. Impact of reduced tillage on the greenhouse gas balance - a meta-analysis (United States)

    Don, Axel; Jantz, Marc


    Minimum tillage and no-tillage has been acknowledged as human induced measure for climate mitigation due to its potential to sequester additional soil carbon. However, there is increasing evidence that reduced tillage affects the vertical distribution of carbon in the soil profile, but hardy increases soil carbon stocks. Additionally, reduced tillage may increase the N2O emissions that would counterbalance the positive effects of soil carbon sequestration. Here we present a new meta-analysis on the full field scale effect of reduced tillage and no-tillage for the temperate zone including soil organic carbon, N2O and diesel derived fossil fuel emissions for field management. This analysis was performed using strict selection criteria and included data from more than 115 sites on soil carbon stock changes and from more than 30 sites with measured N2O fluxes on paired fields with conventional and reduced tillage. Soil organic carbon stocks did hardly increase (mean ±standard deviation: 2 ±11 Mg C ha-1) under no tillage as compared to moldboard ploughing. At 38% of all sites decreasing soil carbon stocks were detected under no-tillage as compared to conventional tillage. On the other hand, N2O emissions increased by around 40% on no-tillage fields with large deviations between sites. Thus, the total greenhouse gas balance turned out to be more negative for most no-tillage fields as compared to conventional tillage fields. The large observed scatter and deviations between sites and their controlling factors are discussed.

  13. Analysis of 23 polycyclic aromatic hydrocarbons in smokeless tobacco by gas chromatography-mass spectrometry. (United States)

    Stepanov, Irina; Villalta, Peter W; Knezevich, Aleksandar; Jensen, Joni; Hatsukami, Dorothy; Hecht, Stephen S


    Smokeless tobacco contains 28 known carcinogens and causes precancerous oral lesions and oral and pancreatic cancer. A recent study conducted by our research team identified eight different polycyclic aromatic hydrocarbons (PAHs) in U.S. moist snuff, encouraging further investigations of this group of toxicants and carcinogens in smokeless tobacco products. In this study, we developed a gas chromatography-mass spectrometry method that allows simultaneous analysis of 23 various PAHs in smokeless tobacco after a simple two-step extraction and purification procedure. The method produced coefficients of variation under 10% for most PAHs. The limits of quantitation for different PAHs varied between 0.3 and 11 ng/g tobacco, starting with a 300 mg sample. The recovery of the stable isotope-labeled internal standards averaged 87%. The method was applied to analysis of 23 moist snuff samples that included various flavors of the most popular U.S. moist snuff brands, as well as 17 samples representing the currently marketed brands of spit-free tobacco pouches, a relatively new type of smokeless tobacco. The sum of all detected PAHs in conventional moist snuff averaged 11.6 (+/-3.7) microg/g dry weight; 20% of this amount was comprised of carcinogenic PAHs. The levels of PAHs in new spit-free tobacco products were much lower than those in moist snuff; the sum of all detected PAHs averaged 1.3 (+/-0.28) microg/g dry weight. Our findings render PAHs one of the most prevalent groups of carcinogens in smokeless tobacco. Urgent measures are required from the U.S. tobacco industry to modify manufacturing processes so that the levels of these toxicants and carcinogens in U.S. moist snuff are greatly reduced.

  14. Fault tree analysis of fire and explosion accidents for dual fuel (diesel/natural gas) ship engine rooms (United States)

    Guan, Yifeng; Zhao, Jie; Shi, Tengfei; Zhu, Peipei


    In recent years, China's increased interest in environmental protection has led to a promotion of energy-efficient dual fuel (diesel/natural gas) ships in Chinese inland rivers. A natural gas as ship fuel may pose dangers of fire and explosion if a gas leak occurs. If explosions or fires occur in the engine rooms of a ship, heavy damage and losses will be incurred. In this paper, a fault tree model is presented that considers both fires and explosions in a dual fuel ship; in this model, dual fuel engine rooms are the top events. All the basic events along with the minimum cut sets are obtained through the analysis. The primary factors that affect accidents involving fires and explosions are determined by calculating the degree of structure importance of the basic events. According to these results, corresponding measures are proposed to ensure and improve the safety and reliability of Chinese inland dual fuel ships.

  15. Fault Tree Analysis of Fire and Explosion Accidents for Dual Fuel (Diesel/Natural Gas) Ship Engine Rooms

    Institute of Scientific and Technical Information of China (English)

    Yifeng Guan; Jie Zhao; Tengfei Shiand Peipei Zhu


    In recent years, China’s increased interest in environmental protection has led to a promotion of energy-efficient dual fuel (diesel/natural gas) ships in Chinese inland rivers. A natural gas as ship fuel may pose dangers of fire and explosion if a gas leak occurs. If explosions or fires occur in the engine rooms of a ship, heavy damage and losses will be incurred. In this paper, a fault tree model is presented that considers both fires and explosions in a dual fuel ship;in this model, dual fuel engine rooms are the top events. All the basic events along with the minimum cut sets are obtained through the analysis.The primary factors that affect accidents involving fires and explosions are determined by calculating the degree of structure importance of the basic events.According to these results, corresponding measures are proposed to ensure and improve the safety and reliability of Chinese inland dual fuel ships.

  16. Analysis of the occurrence of flow-induced pulsations in a gas control station

    NARCIS (Netherlands)

    Peters, M.C.A.M.; Riezebos, H.J.


    Strong flow-induced pulsations were observed at some measurement and control stations of the major gas transport company in the Netherlands, Gasunie. These resonances occur when the gas flow is passing closed side branches in the system at a sufficiently high velocity. Unsteady vortex shedding at th


    Directory of Open Access Journals (Sweden)

    Y. A. Losiouk


    Full Text Available The paper considers a possibility to involve bio-gas generated at testing grounds of hard domestic garbage in power supply system in the Republic of Belarus. An example of optimization using mathematical modeling of plant operation which is used for bio-gas enrichment is given in the paper. 

  18. Quantitative risk analysis of gas explosions in tunnels; probability, effects, and consequences

    NARCIS (Netherlands)

    Weerheijm, J.; Voort, M.M. van der; Verreault, J.; Berg, A.C. van den


    Tunnel accidents with transports of combustible liquefied gases may lead to explosions. Depending on the substance involved this can be a Boiling Liquid Expanding Vapour Explosion (BLEVE), a Gas Expansion Explosion (GEE) or a gas explosion. Quantification of the risk of these scenarios is important

  19. A Lossy Fabry-perot Based Optical Filter for Natural Gas Analysis

    NARCIS (Netherlands)

    Ayerden, N.P.; Ghaderi, M.; De Graaf, G.; Wolffenbuttel, R.F.


    A set-up for optical gas composition measurement based on absorption spectroscopy is composed of a white light source, a gas cell and a spectrometer. The Fabry-Perot optical filter is suitable for miniaturization of this system, as it is composed of only two reflectors with a transparent layer in-be

  20. Techno-economic analysis of biomethanol production via hybrid steam reforming of glycerol with natural gas

    NARCIS (Netherlands)

    Balegedde Ramachandran, P.; Oudenhoven, S.R.G; Kersten, S.R.A.; Rossum, van G.; Ham, van der A.G.J.


    The present article deals with the techno-economic assessment of the hybrid steam reforming (HSR) process of glycerol (obtained via transesterification) together with natural gas to produce biomethanol via the synthesis gas route. In this techno-economic assessment, a model is developed in the UniSi

  1. Preliminary formation analysis for compressed air energy storage in depleted natural gas reservoirs :

    Energy Technology Data Exchange (ETDEWEB)

    Gardner, William Payton


    The purpose of this study is to develop an engineering and operational understanding of CAES performance for a depleted natural gas reservoir by evaluation of relative permeability effects of air, water and natural gas in depleted natural gas reservoirs as a reservoir is initially depleted, an air bubble is created, and as air is initially cycled. The composition of produced gases will be evaluated as the three phase flow of methane, nitrogen and brine are modeled. The effects of a methane gas phase on the relative permeability of air in a formation are investigated and the composition of the produced fluid, which consists primarily of the amount of natural gas in the produced air are determined. Simulations of compressed air energy storage (CAES) in depleted natural gas reservoirs were carried out to assess the effect of formation permeability on the design of a simple CAES system. The injection of N2 (as a proxy to air), and the extraction of the resulting gas mixture in a depleted natural gas reservoir were modeled using the TOUGH2 reservoir simulator with the EOS7c equation of state. The optimal borehole spacing was determined as a function of the formation scale intrinsic permeability. Natural gas reservoir results are similar to those for an aquifer. Borehole spacing is dependent upon the intrinsic permeability of the formation. Higher permeability allows increased injection and extraction rates which is equivalent to more power per borehole for a given screen length. The number of boreholes per 100 MW for a given intrinsic permeability in a depleted natural gas reservoir is essentially identical to that determined for a simple aquifer of identical properties. During bubble formation methane is displaced and a sharp N2methane boundary is formed with an almost pure N2 gas phase in the bubble near the borehole. During cycling mixing of methane and air occurs along the boundary as the air bubble boundary moves. The extracted gas mixture changes as a

  2. Future human resources development in British Columbia's offshore oil and gas industry : preliminary analysis

    Energy Technology Data Exchange (ETDEWEB)

    Jothen, K. [Human Capital Strategies, Victoria, BC (Canada)


    Since 2001, three major studies have concluded that there are no apparent scientific or technological impediments to lifting a longstanding moratorium on West Coast oil and gas exploration and development. Over 300 occupations are involved in offshore oil and gas activity, and should the moratorium be lifted, labour demand is projected to reach 27,000 new employment openings. This report presents a preliminary analysis of factors that may facilitate offshore oil and gas development in British Columbia (BC), with specific reference to human resources. The report also highlights the broader planning environment of BC offshore oil and gas development and the potential impacts of economic, social, demographic and political factors. Potential gaps in regional training resources were identified within the context of a general overview of education training programs currently available elsewhere. Demand pressures on the supply of skilled labour for future development were considered. Interviews with key industry and stakeholder representatives were conducted. Additionally, a comparison of labour demand from oil and gas development on the east coast revealed a significant employment multiplier impact of offshore activities, averaging 3 jobs per 1 offshore job. An outline of previous employment growth patterns were provided for future reference. It was concluded that early planning and development of educational and training programs is essential in addressing eventual skills shortages. In addition to training measures, a range of public policy options should be considered, including retention measures to remove regulatory disincentives and innovative local agreements. Steps to rectify shortages in trades workers, technicians and experienced production workers is advisable, as these shortages are already evident in current onshore oil and gas activities elsewhere in Canada. A detailed description of offshore oil and gas occupations was provided, as well as questionnaires

  3. [Quantitative analysis of content and spectrum of altered mineral in the oil and gas microseepage area]. (United States)

    Li, Qian-qian; Chen, Xiao-Mei; Liu, Xing; Ni, Guo-Qiang


    With the Yulin Prefecture in China as the research area and the mineral compositions and reflectance spectra of 119 samples collected in the research area as research data, the present paper analyzes the correlation between the carbonate content of surface altered minerals caused by oil and gas microseepage and such charactersitic parameters of depth, width of its spectral absorption peak, establishes and evaluates a method for determining carbonate content, and proposes a new method for characterizing the degree of oil and gas microseepage by using the carbonate content. Research results show that this method is not only suitable for characterizing the oil and gas microseepage degree of carbonates, but also suitable for studying the oil and gas micro-seepage degree of other types of altered minerals. Therefore, the method can provide reference for studying oil and gas exploration technology by using spectral information of hyperspectral remote sensing.

  4. Impact Analysis of Generalized Audit Software (GAS Utilization to Auditor Performances

    Directory of Open Access Journals (Sweden)

    Aries Wicaksono


    Full Text Available This study aimed to understand whether the use of Generalized Audit Software (GAS in the audit process have an impact on the auditors performance and to acquire conclusions in the evaluation form towards GAS audit process to provide a positive impact on the performance of auditors. The models used to evaluate the impact of GAS were Quantity of Work, Quality of Work, Job Knowledge, Creativeness, Cooperation, Dependability, Initiative, and Personal Qualities. The method used in this research was a qualitative method of analytical descriptive and evaluative, by analyzing the impact of the GAS implementation to the components of the user’s performance. The results indicate that the use of GAS has a positive impact on user’s performance components.

  5. Practical Policy Applications of Uncertainty Analysis for National Greenhouse Gas Inventories

    Energy Technology Data Exchange (ETDEWEB)

    Gillenwater, M. [Environmental Resources Trust (United States)], E-mail:; Sussman, F.; Cohen, J. [ICF International (United States)


    International policy makers and climate researchers use greenhouse gas emissions inventory estimates in a variety of ways. Because of the varied uses of the inventory data, as well as the high uncertainty surrounding some of the source category estimates, considerable effort has been devoted to understanding the causes and magnitude of uncertainty in national emissions inventories. In this paper, we focus on two aspects of the rationale for quantifying uncertainty: (1) the possible uses of the quantified uncertainty estimates for policy (e.g., as a means of adjusting inventories used to determine compliance with international commitments); and (2) the direct benefits of the process of investigating uncertainties in terms of improving inventory quality. We find that there are particular characteristics that an inventory uncertainty estimate should have if it is to be used for policy purposes: (1) it should be comparable across countries; (2) it should be relatively objective, or at least subject to review and verification; (3) it should not be subject to gaming by countries acting in their own self-interest; (4) it should be administratively feasible to estimate and use; (5) the quality of the uncertainty estimate should be high enough to warrant the additional compliance costs that its use in an adjustment factor may impose on countries; and (6) it should attempt to address all types of inventory uncertainty. Currently, inventory uncertainty estimates for national greenhouse gas inventories do not have these characteristics. For example, the information used to develop quantitative uncertainty estimates for national inventories is often based on expert judgments, which are, by definition, subjective rather than objective, and therefore difficult to review and compare. Further, the practical design of a potential factor to adjust inventory estimates using uncertainty estimates would require policy makers to (1) identify clear environmental goals; (2) define these


    Energy Technology Data Exchange (ETDEWEB)

    Lee, S; Richard Dimenna, R


    The computational fluid dynamics (CFD) modeling technique was applied to the estimation of maximum benzene concentration for the vapor space inside a large-scaled and high-level radioactive waste tank at Savannah River site (SRS). The objective of the work was to perform the calculations for the benzene mixing behavior in the vapor space of Tank 48 and its impact on the local concentration of benzene. The calculations were used to evaluate the degree to which purge air mixes with benzene evolving from the liquid surface and its ability to prevent an unacceptable concentration of benzene from forming. The analysis was focused on changing the tank operating conditions to establish internal recirculation and changing the benzene evolution rate from the liquid surface. The model used a three-dimensional momentum coupled with multi-species transport. The calculations included potential operating conditions for air inlet and exhaust flows, recirculation flow rate, and benzene evolution rate with prototypic tank geometry. The flow conditions are assumed to be fully turbulent since Reynolds numbers for typical operating conditions are in the range of 20,000 to 70,000 based on the inlet conditions of the air purge system. A standard two-equation turbulence model was used. The modeling results for the typical gas mixing problems available in the literature were compared and verified through comparisons with the test results. The benchmarking results showed that the predictions are in good agreement with the analytical solutions and literature data. Additional sensitivity calculations included a reduced benzene evolution rate, reduced air inlet and exhaust flow, and forced internal recirculation. The modeling results showed that the vapor space was fairly well mixed and that benzene concentrations were relatively low when forced recirculation and 72 cfm ventilation air through the tank boundary were imposed. For the same 72 cfm air inlet flow but without forced recirculation

  7. Multi-species trace gas analysis with dual-wavelength quantum cascade laser (United States)

    Jágerská, Jana; Tuzson, Béla; Looser, Herbert; Jouy, Pierre; Hugi, Andreas; Mangold, Markus; Soltic, Patrik; Faist, Jérôme; Emmenegger, Lukas


    Simultaneous detection of multiple gas species using mid-IR laser spectroscopy is highly appealing for a large variety of applications ranging from air quality monitoring, medical breath analysis to industrial process control. However, state-of-the-art distributed-feedback (DFB) mid-IR lasers are usually tunable only within a narrow spectral range, which generally leads to one-laser-one-compound measurement strategy. Thus, multi-species detection involves several lasers and elaborate beam combining solutions [1]. This makes them bulky, costly, and highly sensitive to optical alignment, which limits their field deployment. In this paper, we explore an alternative measurement concept based on a dual-wavelength quantum cascade laser (DW-QCL) [2]. Such a laser can emit at two spectrally distinct wavelengths using a succession of two DFB gratings with different periodicities and a common waveguide to produce one output beam. The laser design was optimized for NOx measurements and correspondingly emits single-mode at 5.26 and 6.25 μm. Electrical separation of the respective laser sections makes it possible to address each wavelength independently. Thereby, it is possible to detect NO and NO2 species with one laser using the same optical path, without any beam combining optics, i.e. in a compact and cost-efficient single-path optical setup. Operated in a time-division multiplexed mode, the spectrometer reaches detection limits at 100 s averaging of 0.5 and 1.5 ppb for NO2 and NO, respectively. The performance of the system was validated against the well-established chemiluminescence detection while measuring the NOx emissions on an automotive test-bench, as well as monitoring the pollution at a suburban site. [1] B. Tuzson, K. Zeyer, M. Steinbacher, J. B. McManus, D. D. Nelson, M. S. Zahniser, and L. Emmenegger, 'Selective measurements of NO, NO2 and NOy in the free troposphere using quantum cascade laser spectroscopy,' Atmospheric Measurement Techniques 6, 927-936 (2013

  8. Recommendations for improved data processing from expired gas analysis indirect calorimetry. (United States)

    Robergs, Robert A; Dwyer, Dan; Astorino, Todd


    There is currently no universally recommended and accepted method of data processing within the science of indirect calorimetry for either mixing chamber or breath-by-breath systems of expired gas analysis. Exercise physiologists were first surveyed to determine methods used to process oxygen consumption ((.)VO2) data, and current attitudes to data processing within the science of indirect calorimetry. Breath-by-breath datasets obtained from indirect calorimetry during incremental exercise were then used to demonstrate the consequences of commonly used time, breath and digital filter post-acquisition data processing strategies. Assessment of the variability in breath-by-breath data was determined using multiple regression based on the independent variables ventilation (VE), and the expired gas fractions for oxygen and carbon dioxide, FEO2 and FECO2, respectively. Based on the results of explanation of variance of the breath-by-breath (.)VO2 data, methods of processing to remove variability were proposed for time-averaged, breath-averaged and digital filter applications. Among exercise physiologists, the strategy used to remove the variability in (.)VO2 measurements varied widely, and consisted of time averages (30 sec [38%], 60 sec [18%], 20 sec [11%], 15 sec [8%]), a moving average of five to 11 breaths (10%), and the middle five of seven breaths (7%). Most respondents indicated that they used multiple criteria to establish maximum ((.)VO2 ((.)VO2max) including: the attainment of age-predicted maximum heart rate (HR(max)) [53%], respiratory exchange ratio (RER) >1.10 (49%) or RER >1.15 (27%) and a rating of perceived exertion (RPE) of >17, 18 or 19 (20%). The reasons stated for these strategies included their own beliefs (32%), what they were taught (26%), what they read in research articles (22%), tradition (13%) and the influence of their colleagues (7%). The combination of VE, FEO2 and FECO2 removed 96-98% of (.)VO2 breath-by-breath variability in incremental

  9. Experimental studies and model analysis of noble gas fractionation in porous media (United States)

    Ding, Xin; Kennedy, B. Mack.; Evans, William C.; Stonestrom, David A.


    The noble gases, which are chemically inert under normal terrestrial conditions but vary systematically across a wide range of atomic mass and diffusivity, offer a multicomponent approach to investigating gas dynamics in unsaturated soil horizons, including transfer of gas between saturated zones, unsaturated zones, and the atmosphere. To evaluate the degree to which fractionation of noble gases in the presence of an advective–diffusive flux agrees with existing theory, a simple laboratory sand column experiment was conducted. Pure CO2 was injected at the base of the column, providing a series of constant CO2 fluxes through the column. At five fixed sampling depths within the system, samples were collected for CO2 and noble gas analyses, and ambient pressures were measured. Both the advection–diffusion and dusty gas models were used to simulate the behavior of CO2 and noble gases under the experimental conditions, and the simulations were compared with the measured depth-dependent concentration profiles of the gases. Given the relatively high permeability of the sand column (5 ´ 10−11 m2), Knudsen diffusion terms were small, and both the dusty gas model and the advection–diffusion model accurately predicted the concentration profiles of the CO2 and atmospheric noble gases across a range of CO2 flux from ?700 to 10,000 g m−2 d−1. The agreement between predicted and measured gas concentrations demonstrated that, when applied to natural systems, the multi-component capability provided by the noble gases can be exploited to constrain component and total gas fluxes of non-conserved (CO2) and conserved (noble gas) species or attributes of the soil column relevant to gas transport, such as porosity, tortuosity, and gas saturation.

  10. Characteristics analysis and dynamic responses of micro-gas-lubricated journal bearings with a new slip model (United States)

    Zhang, Wen-Ming; Meng, Guang; Huang, Hai; Zhou, Jian-Bin; Chen, Jie-Yu; Chen, Di


    In this paper, a new slip model based on kinetic theory of gases for gas-lubricated journal bearings in micro-electro-mechanical systems (MEMS) is applied using a physical approach. The corresponding modified governing equation and mathematic model are presented and the flow rate is plotted versus the inverse Knudsen number. Pressure distributions along the gas bearing at various Knudsen numbers and bearing numbers are plotted and the load carrying capacities are also obtained. A numerical analysis of a rigid rotor supported by gas-lubricated journal bearings is presented for dynamic behaviour. The slip flow effect on the properties, including pressure distribution, load carrying capacity and dynamic coefficients, of the micro-gas-lubricated journal bearings and dynamic responses of the micro rotor-bearing system are estimated and analysed in detail. It is shown that the dynamic coefficients increase with increasing bearing number except for two damping coefficients and the rotor-bearing system runs at a much higher rotating speed to keep stable when slip flow occurs. Moreover, the oscillation period of the rotor operating with the slip model is longer than that with the continuum flow. In addition, the whirl frequency is reduced from 0.422 to 0.079 under the slip effect. Therefore, the results of this study contribute to a further understanding of the characteristics and nonlinear dynamics of gas-film rotor-bearing systems in MEMS.

  11. Direct thermal desorption in the analysis of cheese volatiles by gas chromatography and gas chromatography-mass spectrometry: comparison with simultaneous distillation-extraction and dynamic headspace. (United States)

    Valero, E; Sanz, J; Martínez-Castro, I


    Direct thermal desorption (DTD) has been used as a technique for extracting volatile components of cheese as a preliminary step to their gas chromatographic (GC) analysis. In this study, it is applied to different cheese varieties: Camembert, blue, Chaumes, and La Serena. Volatiles are also extracted using other techniques such as simultaneous distillation-extraction and dynamic headspace. Separation and identification of the cheese components are carried out by GC-mass spectrometry. Approximately 100 compounds are detected in the examined cheeses. The described results show that DTD is fast, simple, and easy to automate; requires only a small amount of sample (approximately 50 mg); and affords quantitative information about the main groups of compounds present in cheeses.


    Directory of Open Access Journals (Sweden)

    Ilyasov R. H.


    Full Text Available The energy market shows strong exposure to seasonal fluctuations. A striking example of the impact of seasonality is the dynamics of the production of natural and associated gas in Russia. We use two approaches to the identification and analysis of seasonality: classical econometric based on different smoothing procedure; spline method uses an approximation of the economic dynamics of cubic splines and phase analysis. In the comparison of the two methods are used to identify the benefits of using spline functions when modeling economic dynamics and phase analysis of seasonality

  13. Analysis of phthalate esters in soils near an electronics manufacturing facility and from a non-industrialized area by gas purge microsyringe extraction and gas chromatography. (United States)

    Wu, Wei; Hu, Jia; Wang, Jinqi; Chen, Xuerong; Yao, Na; Tao, Jing; Zhou, Yi-Kai


    Here, a novel technique is described for the extraction and quantitative determination of six phthalate esters (PAEs) from soils by gas purge microsyringe extraction and gas chromatography. Recovery of PAEs ranged from 81.4% to 120.3%, and the relative standard deviation (n=6) ranged from 5.3% to 10.5%. Soil samples were collected from roadsides, farmlands, residential areas, and non-cultivated areas in a non-industrialized region, and from the same land-use types within 1 km of an electronics manufacturing facility (n=142). Total PAEs varied from 2.21 to 157.62 mg kg(-1) in non-industrialized areas and from 8.63 to 171.64 mg kg(-1) in the electronics manufacturing area. PAE concentrations in the non-industrialized area were highest in farmland, followed (in decreasing order) by roadsides, residential areas, and non-cultivated soil. In the electronics manufacturing area, PAE concentrations were highest in roadside soils, followed by residential areas, farmland, and non-cultivated soils. Concentrations of dimethyl phthalate (DMP), diethyl phthalate (DEP), and di-n-butyl phthalate (DnBP) differed significantly (P<0.01) between the industrial and non-industrialized areas. Principal component analysis indicated that the strongest explanatory factor was related to DMP and DnBP in non-industrialized soils and to butyl benzyl phthalate (BBP) and DMP in soils near the electronics manufacturing facility. Congener-specific analysis confirmed that diethylhexyl phthalate (DEHP) was a predictive indication both in the non-industrialized area (r(2)=0.944, P<0.01) and the industrialized area (r(2)=0.860, P<0.01). The higher PAE contents in soils near the electronics manufacturing facility are of concern, considering the large quantities of electronic wastes generated with ongoing industrialization.

  14. Analysis of Modifications on a Spark Ignition Engine for Operation with Natural Gas

    Directory of Open Access Journals (Sweden)

    Ramasamy D.


    Full Text Available Transportation is one of the key contributors to petroleum usage and emissions to the atmosphere. According to researchers, there are many ways to use transport by using renewable energy sources. Of these solutions, the immediate solution which requires less modification to current engine technology is by using gaseous fuels. Natural gas is the fuel of choice for minor modification to current engines. As it can be derived from anaerobic digestion process, the potential as a renewable energy source is tremendous, especially for an agricultural country such a Malaysia. The aim in the future will be operating an engine with natural gas only with pipelines straight to houses for easy filling. The fuel is light and can be easily carried in vehicles when in compressed form. As such, Compressed Natural Gas (CNG is currently used in bi-fuel engines, but is mostly not optimized in term of their performance. The focus of the paper is to optimize a model of natural gas engine by one dimensional flow modeling for operation with natural gas. The model is analyzed for performance and emission characteristics produced by a gasoline engine and later compared with natural gas. The average performance drop is about 15% from its gasoline counterpart. The 4% benchmark indicates that the modification to ignition timing and compression ratio does improve engine performance using natural gas as fuel.

  15. Theoretic analysis of middle ear gas composition under conditions of nonphysiologic ventilation. (United States)

    Ostfeld, E J; Silberberg, A


    As gas flows in and out of the nasopharynx, the pressure in that region fluctuates. It drops below or rises above atmospheric pressure, which is itself not constant but is subject to changes in altitude and weather. Such pressure changes in the nasopharynx produce a pumping of gas into and out of the middle ear. The net amount of middle ear gas transferred from or to the nasopharynx will, component for component, in steady state exactly equal the amount of middle ear gas transferred to or from the microcirculation by means of diffusional absorption by (or release from) the mucosa. In the case of a permanently patulous eustachian tube, a single parameter, characteristic of the rate of ventilation through the open eustachian tube, is found to determine the gas composition in the middle ear, whereas in the case of a middle ear ventilated by tympanostomy, two rate-of-ventilation parameters, one for gas flow through the ventilation tube and one for flow through a periodically open eustachian tube, determine the steady state gas composition. A high rate of ventilation favors absorption of oxygen and venting of carbon dioxide from the middle ear in both cases.

  16. Analysis of the physical atomic forces between noble gas atoms, alkali ions and halogen ions (United States)

    Wilson, J. W.; Heinbockel, J. H.; Outlaw, R. A.


    The physical forces between atoms and molecules are important in a number of processes of practical importance, including line broadening in radiative processes, gas and crystal properties, adhesion, and thin films. The components of the physical forces between noble gas atoms, alkali ions, and halogen ions are analyzed and a data base for the dispersion forces is developed from the literature based on evaluations with the harmonic oscillator dispersion model for higher order coefficients. The Zener model of the repulsive core is used in the context of the recent asymptotic wave functions of Handler and Smith; and an effective ionization potential within the Handler and Smith wave functions is defined to analyze the two body potential data of Waldman and Gordon, the alkali-halide molecular data, and the noble gas crystal and salt crystal data. A satisfactory global fit to this molecular and crystal data is then reproduced by the model to within several percent. Surface potentials are evaluated for noble gas atoms on noble gas and salt crystal surfaces with surface tension neglected. Within this context, the noble gas surface potentials on noble gas and salt crystals are considered to be accurate to within several percent.

  17. Analysis of the Molecules Structure and Vertical Electron Affinity of Organic Gas Impact on Electric Strength

    Institute of Scientific and Technical Information of China (English)

    JIAO Juntao; XIAO Dengming; ZHAO Xiaoling; DENG Yunkun


    It is necessary to find an efficient selection method to pre-analyze the gas electric strength from the perspective of molecule structure and the properties for finding the alternative gases to sulphur hexafluoride (SF6).As the properties of gas are determined by the gas molecule structure,the research on the relationship between the gas molecule structure and the electric strength can contribute to the gas pre-screening and new gas development.In this paper,we calculated the vertical electron affinity,molecule orbits distribution and orbits energy of gas molecules by the means of density functional theory (DFT) for the typical structures of organic gases and compared their electric strengths.By this method,we find part of the key properties of the molecule which are related to the electric strength,including the vertical electron affinity,the lowest unoccupied molecule orbit (LUMO) energy,molecule orbits distribution and negativeion system energy.We also listed some molecule groups such as unsaturated carbons double bonds (C=C) and carbonitrile bonds (C≡N) which have high electric strength theoretically by this method.

  18. Analysis of the Molecules Structure and Vertical Electron Affinity of Organic Gas Impact on Electric Strength (United States)

    Jiao, Juntao; Xiao, Dengming; Zhao, Xiaoling; Deng, Yunkun


    It is necessary to find an efficient selection method to pre-analyze the gas electric strength from the perspective of molecule structure and the properties for finding the alternative gases to sulphur hexafluoride (SF6). As the properties of gas are determined by the gas molecule structure, the research on the relationship between the gas molecule structure and the electric strength can contribute to the gas pre-screening and new gas development. In this paper, we calculated the vertical electron affinity, molecule orbits distribution and orbits energy of gas molecules by the means of density functional theory (DFT) for the typical structures of organic gases and compared their electric strengths. By this method, we find part of the key properties of the molecule which are related to the electric strength, including the vertical electron affinity, the lowest unoccupied molecule orbit (LUMO) energy, molecule orbits distribution and negative-ion system energy. We also listed some molecule groups such as unsaturated carbons double bonds (C=C) and carbonitrile bonds (C≡N) which have high electric strength theoretically by this method. supported by National Natural Science Foundation of China (Nos. 51177101 and 51337006)

  19. Analysis of Simulated Output Characteristics of Gas Sensor Based on Graphene Nanoribbon

    Directory of Open Access Journals (Sweden)

    A. Mahmoudi


    Full Text Available This work presents simulated output characteristics of gas sensor transistors based on graphene nanoribbon (GNRFET. The device studied in this work is a new generation of gas sensing devices, which are easy to use, ultracompact, ultrasensitive, and highly selective. We will explain how the exposure to the gas changes the conductivity of graphene nanoribbon. The equations of the GNRFET gas sensor model include the Poisson equation in the weak nonlocality approximation with proposed sensing parameters. As we have developed this model as a platform for a gas detection sensor, we will analyze the current-voltage characteristics after exposure of the GNRFET nanosensor device to NH3 gas. A sensitivity of nearly 2.7% was indicated in our sensor device after exposure of 1 ppm of NH3. The given results make GNRFET the right candidate for use in gas sensing/measuring appliances. Thus, we will investigate the effect of the channel length on the ON- and OFF-current.

  20. Clinical significance of blood gas and electrolyte analysis, CK, CK-MB and HBDH changes in neonatal asphyxia

    Institute of Scientific and Technical Information of China (English)

    Bao-Hua Xu; Xin Lin; Mi-Jia Huang


    Objective:To investigate the clinical significance of blood gas and electrolyte analysis, CK, CK-MB and HBDH changes in neonatal asphyxia.Methods:A total of 100 newborns with asphyxia who visited in our hospital were collected, and divided into severe group (n=20) and mild group (n=80) according to the asphyxia degree, and 50 healthy newborns regarded as control group. The 3 groups received blood gas analysis (pH, BE and PaCO2), electrolyte (K+, Na+ and Ca2+) and 3 kinds of enzymes (CK, CK-MB and HBDH) were tested and compared.Results: Compared with control group, pH and BE of blood gas indexes decreased significantly and PaCO2 increased significantly in severe group (P0.05). Compared with mild group, pH and BE of blood gas indexes decreased significantly and PaCO2 increased significantly in severe group (P0.05). Compared with mild group, the level of Ca2+ decreased significantly in severe group (P<0.05); Compared with control group, the levels of CK, CK-MB and HBDH increased significantly in severe and mild group (P<0.05). Compared with mild group, the levels of CK, CK-MB and HBDH increased significantly in severe group (P<0.05).Conclusions:The detection of blood gas and electrolyte analysis, CK, CK-MB and HBDH can provide an objective evidence for the diagnosis of neonatal asphyxia and estimation of severity degree which was helpful in clinical treatment.

  1. Characterization of an upper Permian tight gas reservoir. A multidisciplinary, multiscale analysis from the rotliegend, northern Germany

    Energy Technology Data Exchange (ETDEWEB)

    Antrett, Philipp [RWTH Aachen Univ. (Germany). Energy and Mineral Resources Group


    Outstanding Ph.D. thesis nominated for a Springer Theses Prize by the RWTH Aachen University, Germany. Uses various approaches and covers a broad range of disciplines. Integrated study, carried out on multiple scales with state of the art technical equipment, that only few laboratories can offer worldwide. ''The thesis of Philipp Antrett is focused on reservoir properties, petrography, lithofacies and sedimentology, core analysis and nanoporosity studies. It will be of major interest for colleagues involved in the exploration and production of tight gas reservoirs in Northern Europe and elsewhere.'' - Francois Roure, August 2012 This thesis describes a multidisciplinary, multiscale approach to the analysis of tight gas reservoirs. It focused initially on the facies architecture of a Permian tight gas field in the Southern Permian Basin (SPB), East Frisia, northern Germany. To improve field development, 3D seismic data, wireline and core data were compared to a reservoir analogue in the Panamint Valley, California, United States. In addition to the large scale approach, a work flow that investigates microporosity by combining Scanning Electron Microscopy-Broad Ion Beam (SEM-BIB) and optical microscopy was developed. For a better understanding of the depositional environment and reservoir rock distribution in the SPB, a sedimentary facies analysis of four cores from the tight gas field in East Frisia was compared to a second study area in northern central Germany. This study demonstrates that tight gas exploration and production requires multidisciplinary, multiscale approaches beyond standard seismic interpretation work flows to better understand the temporal and spatial evolution of these complex reservoirs.

  2. Application of evolved gas analysis to cold-cap reactions of melter feeds for nuclear waste vitrification

    Energy Technology Data Exchange (ETDEWEB)

    Rodriguez, Carmen P. [Pacific Northwest National Laboratory, 902 Battelle Blvd., P.O. Box 999, MSIN K6-24, Richland, WA 99352 (United States); Chun, Jaehun, E-mail: [Pacific Northwest National Laboratory, 902 Battelle Blvd., P.O. Box 999, MSIN K6-24, Richland, WA 99352 (United States); Schweiger, Michael J. [Pacific Northwest National Laboratory, 902 Battelle Blvd., P.O. Box 999, MSIN K6-24, Richland, WA 99352 (United States); Kruger, Albert A. [U.S. Department of Energy Office of River Protection, Richland, WA 99352 (United States); Hrma, Pavel [Pacific Northwest National Laboratory, 902 Battelle Blvd., P.O. Box 999, MSIN K6-24, Richland, WA 99352 (United States); Division of Advanced Nuclear Engineering, Pohang University of Science and Technology, Pohang (Korea, Republic of)


    Highlights: • We applied the TGA-GC–MS combination to perform EGA of glass batches. • We confirmed the proportionality between mass loss rate and gas evolution intensities. • Proportionality coefficients can be obtained via single-reaction calibration. • Quantitative EGA allows mass loss rates to be matched with evolution rates for gases. • Industrial and waste glass technology can benefit from quantitative EGA. - Abstract: In the vitrification of nuclear wastes, the melter feed (a mixture of nuclear waste and glass-forming and modifying additives) experiences multiple gas-evolving reactions in an electrical glass-melting furnace. We employed the thermogravimetry-gas chromatography–mass spectrometry (TGA-GC–MS) combination to perform evolved gas analysis (EGA). Along with identifying the gases evolved, we performed quantitative analysis relating the weighted sum of intensities of individual gases in linear proportion with the differential thermogravimetry. The proportionality coefficients were obtained by three methods based on the stoichiometry, least squares, and calibration. The linearity was shown to be a good first-order approximation, in spite of the complicated overlapping reactions.

  3. An Ultra-Trace Analysis Technique for SF6 Using Gas Chromatography with Negative Ion Chemical Ionization Mass Spectrometry. (United States)

    Jong, Edmund C; Macek, Paul V; Perera, Inoka E; Luxbacher, Kray D; McNair, Harold M


    Sulfur hexafluoride (SF6) is widely used as a tracer gas because of its detectability at low concentrations. This attribute of SF6 allows the quantification of both small-scale flows, such as leakage, and large-scale flows, such as atmospheric currents. SF6's high detection sensitivity also facilitates greater usage efficiency and lower operating cost for tracer deployments by reducing quantity requirements. The detectability of SF6 is produced by its high molecular electronegativity. This property provides a high potential for negative ion formation through electron capture thus naturally translating to selective detection using negative ion chemical ionization mass spectrometry (NCI-MS). This paper investigates the potential of using gas chromatography (GC) with NCI-MS for the detection of SF6. The experimental parameters for an ultra-trace SF6 detection method utilizing minimal customizations of the analytical instrument are detailed. A method for the detection of parts per trillion (ppt) level concentrations of SF6 for the purpose of underground ventilation tracer gas analysis was successfully developed in this study. The method utilized a Shimadzu gas chromatography with negative ion chemical ionization mass spectrometry system equipped with an Agilent J&W HP-porous layer open tubular column coated with an alumina oxide (Al2O3) S column. The method detection limit (MDL) analysis as defined by the Environmental Protection Agency of the tracer data showed the method MDL to be 5.2 ppt.

  4. Computational Fluid Dynamics Analysis of Very High Temperature Gas-Cooled Reactor Cavity Cooling System

    Energy Technology Data Exchange (ETDEWEB)

    Frisani, Angelo; Hassan, Yassin A; Ugaz, Victor M


    The design of passive heat removal systems is one of the main concerns for the modular very high temperature gas-cooled reactors (VHTR) vessel cavity. The reactor cavity cooling system (RCCS) is a key heat removal system during normal and off-normal conditions. The design and validation of the RCCS is necessary to demonstrate that VHTRs can survive to the postulated accidents. The computational fluid dynamics (CFD) STAR-CCM+/V3.06.006 code was used for three-dimensional system modeling and analysis of the RCCS. A CFD model was developed to analyze heat exchange in the RCCS. The model incorporates a 180-deg section resembling the VHTR RCCS experimentally reproduced in a laboratory-scale test facility at Texas A&M University. All the key features of the experimental facility were taken into account during the numerical simulations. The objective of the present work was to benchmark CFD tools against experimental data addressing the behavior of the RCCS following accident conditions. Two cooling fluids (i.e., water and air) were considered to test the capability of maintaining the RCCS concrete walls' temperature below design limits. Different temperature profiles at the reactor pressure vessel (RPV) wall obtained from the experimental facility were used as boundary conditions in the numerical analyses to simulate VHTR transient evolution during accident scenarios. Mesh convergence was achieved with an intensive parametric study of the two different cooling configurations and selected boundary conditions. To test the effect of turbulence modeling on the RCCS heat exchange, predictions using several different turbulence models and near-wall treatments were evaluated and compared. The comparison among the different turbulence models analyzed showed satisfactory agreement for the temperature distribution inside the RCCS cavity medium and at the standpipes walls. For such a complicated geometry and flow conditions, the tested turbulence models demonstrated that the

  5. Greenhouse gas emissions in Europe: a retrospective trend analysis for the period 1990-2008

    Energy Technology Data Exchange (ETDEWEB)

    Borgan, A.; Gugele, B.; Haider, S. (Umweltbundesamt, Vienna (Austria)) (and others)


    This report presents a retrospective overview of the greenhouse gas (GHG) emission trends in Europe from 1990 to 2008, with a particular focus on the underpinning drivers and the influence of EU policies. The analysis is based on the combination of decomposition analyses to identify the respective influence of each identified driver and an overview of the main EU policies and their likely effects on these drivers. The period covered by the analysis stops in 2008. As a result, the analysis avoids the effects of the recent economic crisis on GHG emissions. This reinforces the conclusion on long-term emission drivers. The report covers the EU-27 and presents results for the other EEA member countries (Iceland, Liechtenstein, Norway, Switzerland and Turkey) and Croatia (EU candidate country together with Turkey) as far as data is available. The results can be summarized as: 1) Overall GHG emission trends. EU GHG emissions were reduced between 1990 and 2008. Most of the reductions took place in the 1990s, but emissions have also been decreasing every year from 2003 until the last year considered in this report, 2008. 2) Predominant drivers. For the most part, the GHG emission trends observed in the EU between 1990 and 2008 resulted from economic factors. However, EU policies, some of which were not directly targeting GHG emissions, as well as national policies by some front runner countries, also played a role in these trends. 3) Impacts of EU policies. Between 2000 and 2008, emission trends were more directly targeted by a range of energy and climate policies, e.g. the implementation of the European Climate Change programme. However, the steady increase in energy demand during this period - particularly electricity - outweighed the considerable EU-wide savings generated by energy efficiency improvements and the development of renewable energy. 4) Co-benefits. Taking example from the positive benefits on GHG emissions that resulted from the implementation of non

  6. Mass spectrometry analysis of polychlorinated biphenyls: chemical ionization and selected ion chemical ionization using methane as a reagent gas

    Directory of Open Access Journals (Sweden)



    Full Text Available In the present paper a quadrupole ion trap mass spectrometer, coupled with a gas chromatograph, was used to compare the electron impact ionization (EI and chemical ionization (Cl technique, in terms of their selectivity in polychlorinated biphenyls (PCBs quantitative analysis. The experiments were carried out with a modified Varian SATURN III quadrupole ion-storage mass spectrometer equipped with Varian waveform generator, coupled with a gas chromatograph with DB-5 capillary column. The disadvantage of using EI in the analysis of PCBs congeners is the extensive fragmentation of the molecular ion. The main fragmentation pattern recorded in the EI mass spectra of PCBs was the loss of a chlorine atom from the molecular ion. Therefore the fragment-ion signal overlapped with the molecular-ion cluster of lower mass congener. The fragmentation reactions of PCBs are suppressed if methane is used as a reagent gas for chemical ionization, but fragment ions are also present in the spectrum as an obstruction for quantitative analysis. The most selective method for PCBs quantitative analysis appears to be Cl with mass-selected C2H5+ ions from methane, which results in a mass spectrum with a negligible amount of fragment ions.

  7. Identification of di(ethylhexyl) phthalate as impurity in the analysis by using chromatography gas tandem mass spectrometry (United States)

    Pusfitasari, Eka Dian; Hendarsyah, Hendris; Salahuddin, Ariani, Novita


    Di(ethylhexyl) phthalate (DEHP) is a plasticizer commonly used in plastics. Physically DEHP has a low vapor pressure. DEHP can seep into the liquid in direct contact with the plastic wrapping materials, and typically can occur rapidly if extractable into food or non-polar solvents, such as oil, once the food is packaged in PVC packaging materials. DEHP has been analyzed by using gas chromatography which has a high sensitivity level. If the equipment used for the analysis is made from plastic containing DEHP, then it may be possible that DEHP can be extracted and appear on the outcome of the injection. It can interfere with the process of analysis, especially for the analysis of food samples. This study has identified the present of DEHP in the blank injection performed by Gas Chromatography tandem Mass Spectrometry with Selected Ion Monitoring mode (SIM). Researchers are required to verify whether the gas chromatographic system used is ready for the analysis process. In addition, the comparison and calculation of the intensity of the ion fragmentation spectra generated by mass spectrometry detector can be used for the qualitative determination to ensure the presence of the target compound. In this study is also discussed the differences between the high-intensity fragmentation of DEHP and dioctyl phthalate (DOP).

  8. An improved, automated whole air sampler and gas chromatography mass spectrometry analysis system for volatile organic compounds in the atmosphere (United States)

    Lerner, Brian M.; Gilman, Jessica B.; Aikin, Kenneth C.; Atlas, Elliot L.; Goldan, Paul D.; Graus, Martin; Hendershot, Roger; Isaacman-VanWertz, Gabriel A.; Koss, Abigail; Kuster, William C.; Lueb, Richard A.; McLaughlin, Richard J.; Peischl, Jeff; Sueper, Donna; Ryerson, Thomas B.; Tokarek, Travis W.; Warneke, Carsten; Yuan, Bin; de Gouw, Joost A.


    Volatile organic compounds were quantified during two aircraft-based field campaigns using highly automated, whole air samplers with expedited post-flight analysis via a new custom-built, field-deployable gas chromatography-mass spectrometry instrument. During flight, air samples were pressurized with a stainless steel bellows compressor into electropolished stainless steel canisters. The air samples were analyzed using a novel gas chromatograph system designed specifically for field use which eliminates the need for liquid nitrogen. Instead, a Stirling cooler is used for cryogenic sample pre-concentration at temperatures as low as -165 °C. The analysis system was fully automated on a 20 min cycle to allow for unattended processing of an entire flight of 72 sample canisters within 30 h, thereby reducing typical sample residence times in the canisters to less than 3 days. The new analytical system is capable of quantifying a wide suite of C2 to C10 organic compounds at part-per-trillion sensitivity. This paper describes the sampling and analysis systems, along with the data analysis procedures which include a new peak-fitting software package for rapid chromatographic data reduction. Instrument sensitivities, uncertainties and system artifacts are presented for 35 trace gas species in canister samples. Comparisons of reported mixing ratios from each field campaign with measurements from other instruments are also presented.

  9. Thermodynamic Analysis of a Gas Turbine Power Plant Modelled with an Evaporative Cooler



    Performance of a gas turbine is mainly depends on the inlet air temperature. The power output of a gas turbine depends on the flow of mass through it. Inlet air cooling increases the power output by taking advantage of the gas turbine’s feature of higher mass flow rate when the compressor inlet temperature decreases. This is precisely the reason why on hot days, when air is less dense, power output falls off. A rise of 1°C temperature of inlet air decreases the power output by 1%. In this pap...

  10. Estimation of current density distribution of PAFC by analysis of cell exhaust gas

    Energy Technology Data Exchange (ETDEWEB)

    Kato, S.; Seya, A. [Fuji Electric Co., Ltd., Ichihara-shi (Japan); Asano, A. [Fuji Electric Corporate, Ltd., Yokosuka-shi (Japan)


    To estimate distributions of Current densities, voltages, gas concentrations, etc., in phosphoric acid fuel cell (PAFC) stacks, is very important for getting fuel cells with higher quality. In this work, we leave developed a numerical simulation tool to map out the distribution in a PAFC stack. And especially to Study Current density distribution in the reaction area of the cell, we analyzed gas composition in several positions inside a gas outlet manifold of the PAFC stack. Comparing these measured data with calculated data, the current density distribution in a cell plane calculated by the simulation, was certified.

  11. The development of natural gas supply costs to Europe, the United States and Japan in a globalizing gas market-Model-based analysis until 2030

    Energy Technology Data Exchange (ETDEWEB)

    Lochner, Stefan [Institute of Energy Economics at the University of Cologne (EWI), Albertus-Magnus-Platz, 50923 Cologne (Germany)], E-mail:; Bothe, David [Frontier Economics Limited, Wolfsstr. 16, 50667 Cologne (Germany)], E-mail:


    Quickly declining natural gas reserves in some parts of the world, increasing demand in today's major gas consuming regions, the emergence of new demand centres and the globalization of natural gas markets caused by the rising importance of liquefied natural gas (LNG) are changing global gas supply structures and will continue to do so over the next decades. Applying a global gas market model, we produce a forecast for global gas supply to 2030 and determine the supplier-specific long-run average costs of gas supplied to three major consuming regions. Results for the three regions are compared and analysed with a focus on costs, supply diversification and the different roles of LNG. We find that while European and Japanese external gas supply will be less diversified in international comparison, gas can be supplied at relatively low costs due to the regions' favourable locations in geographic proximity to large gas producers. The US market's supply structure on the other hand will significantly change from its current situation. The growing dependency on LNG imports from around the world will lead to significantly higher supply costs but will also increase diversification as gas will originate from an increasing number of LNG exporting countries.

  12. The development of natural gas supply costs to Europe, the United States and Japan in a globalizing gas market. Model-based analysis until 2030

    Energy Technology Data Exchange (ETDEWEB)

    Lochner, Stefan [Institute of Energy Economics at the University of Cologne (EWI), Albertus-Magnus-Platz, 50923 Cologne (Germany); Bothe, David [Frontier Economics Limited, Wolfsstr. 16, 50667 Cologne (Germany)


    Quickly declining natural gas reserves in some parts of the world, increasing demand in today's major gas consuming regions, the emergence of new demand centres and the globalization of natural gas markets caused by the rising importance of liquefied natural gas (LNG) are changing global gas supply structures and will continue to do so over the next decades. Applying a global gas market model, we produce a forecast for global gas supply to 2030 and determine the supplier-specific long-run average costs of gas supplied to three major consuming regions. Results for the three regions are compared and analysed with a focus on costs, supply diversification and the different roles of LNG. We find that while European and Japanese external gas supply will be less diversified in international comparison, gas can be supplied at relatively low costs due to the regions' favourable locations in geographic proximity to large gas producers. The US market's supply structure on the other hand will significantly change from its current situation. The growing dependency on LNG imports from around the world will lead to significantly higher supply costs but will also increase diversification as gas will originate from an increasing number of LNG exporting countries. (author)

  13. Simultaneous analysis of hemoglobin adducts of acrylamide and glycidamide by gas chromatography-mass spectrometry. (United States)

    Pérez, H L; Cheong, H K; Yang, J S; Osterman-Golkar, S


    Acrylamide (AA) is a carcinogen in experimental animals. Glycidamide (GA), formed by metabolic epoxidation of AA, is believed to be responsible for the carcinogenicity of AA. Occupational exposure to AA has been assessed earlier by measurement of its adducts with N-terminal valine in hemoglobin. A background of AA adducts [N-(2-carbamoylethyl)valine (AAVal), about 30 pmol/g globin] was found in individuals without known exposure to the compound. The method previously available for adducts of GA only allowed analysis of samples from highly exposed individuals and showed similar levels of AAVal and adducts of GA [N-(2-hydroxy-2-carbamoylethyl)valine (GAVal)]. We have developed a sensitive method for simultaneous quantification of adducts of GA and AA, which is suitable down to low exposure levels. The method is based on the so-called modified Edman method, where globin is reacted with pentafluorophenyl isothiocyanate under neutral conditions. The valine adducts are then extracted in the form of pentafluorophenylthiohydantoin (PFPTH) derivatives. The analytical procedure included reaction of the PFPTH derivatives with acetic anhydride in order to protect the hydroxyl group of GAVal. The PFPTH derivatives of AAVal and GAVal were analyzed by gas chromatography/tandem mass spectrometry. ((2)H(3))AAVal-PFPTH was used as the internal standard. The method was applied to samples from 11 workers at an AA production plant, 1 nonexposed nonsmoker, and a few participants of a smoking cessation program. AAVal levels were in the range 27-1854 pmol/g globin. Recorded levels of GAVal were 3-12% of those of AAVal, suggesting that previous measurements of GAVal overestimate GAVal at low levels of exposure to AA.

  14. Analysis of acetylene in blood and urine using cryogenic gas chromatography-mass spectrometry. (United States)

    Kashiwagi, Masayuki; Hara, Kenji; Fujii, Hiroshi; Kageura, Mitsuyoshi; Takamoto, Mutsuo; Matsusue, Aya; Sugimura, Tomoko; Kubo, Shin-ichi


    A method for quantitative analysis of acetylene in blood and urine samples was investigated. Using cryogenic gas chromatography-mass spectrometry (GC-MS), acetylene was measured with isobutane as the internal standard in the headspace method, which revealed a linear response over the entire composite range with an excellent correlation coefficient, both in blood (R = 0.9968, range = 5.39-43.1 microg/ml) and urine (R = 0.9972, range = 2.16-10.8 microg/ml). The coefficients of variation (CV) for blood ranged from 2.62 to 11.6% for intra-day and 4.55 to 10.4% for inter-day. The CV for urine ranged from 2.38 to 3.10% for intra-day and 4.83 to 11.0% for inter-day. The recovery rate as an index of accuracy ranged from 83 to 111%. The present method showed good reliability, and is also simple and rapid. In actual samples from a charred cadaver due to acetylene explosion, the measured concentrations of acetylene by this method were 21.5 microg/ml for femoral vein blood, 17.9 microg/ml for right atrial blood, 25.5 microg/ml for left atrial blood and 7.49 microg/ml for urine. Quantification of acetylene provides important information, because the acetylene concentration is a vital reaction or sign. For example, when acetylene is filled in a closed space and then explodes, in antemortem explosion, the blood acetylene concentration of the cadaver might be significant. On the other hand, in postmortem explosion, acetylene is not detected in blood. Furthermore, when several victims are involved in one explosion, comparison of the sample concentrations can also provide useful information to establish the conditions at the accident scene; therefore, the present method is useful in forensics.

  15. Analysis of a system modelling the motion of a piston in a viscous gas (United States)

    Maity, Debayan; Takahashi, Takéo; Tucsnak, Marius


    We study a free boundary problem modelling the motion of a piston in a viscous gas. The gas-piston system fills a cylinder with fixed extremities, which possibly allow gas from the exterior to penetrate inside the cylinder. The gas is modeled by the 1D compressible Navier-Stokes system and the piston motion is described by the second Newton's law. We prove the existence and uniqueness of global in time strong solutions. The main novelty brought in by our results is that they include the case of nonhomogeneous boundary conditions which, as far as we know, have not been studied in this context. Moreover, even for homogeneous boundary conditions, our results require less regularity of the initial data than those obtained in previous works.

  16. Analysis of Vapour Liquid Equilibria in Unconventional Rich Liquid Gas Condensate Reservoirs (United States)

    Kuczyński, Szymon


    At the beginning of 21st century, natural gas from conventional and unconventional reservoirs has become important fossil energy resource and its role as energy fuel has increased. The exploration of unconventional gas reservoirs has been discussed recently in many conferences and journals. The paper presents considerations which will be used to build the thermodynamic model that will describe the phenomenon of vapour - liquid equilibrium (VLE) in the retrograde condensation in rocks of ultra-low permeability and in the nanopores. The research will be limited to "tight gas" reservoirs (TGR) and "shale gas" reservoirs (SGR). Constructed models will take into account the phenomenon of capillary condensation and adsorption. These studies will be the base for modifications of existing compositional simulators

  17. Analysis of the behaviour of biofuel-fired gas turbine power plants

    Directory of Open Access Journals (Sweden)

    Escudero Marcos


    Full Text Available The utilisation of biofuels in gas turbines is a promising alternative to fossil fuels for power generation. It would lead to a significant reduction of CO2 emissions using an existing combustion technology, although considerable changes appear to be required and further technological development is necessary. The goal of this work is to conduct energy and exergy analyses of the behaviour of gas turbines fired with biogas, ethanol and synthesis gas (bio-syngas, compared with natural gas. The global energy transformation process (i.e., from biomass to electricity also has been studied. Furthermore, the potential reduction of CO2 emissions attained by the use of biofuels has been determined, after considering the restrictions regarding biomass availability. Two different simulation tools have been used to accomplish this work. The results suggest a high interest in, and the technical viability of, the use of Biomass Integrated Gasification Combined Cycle (BioIGCC systems for large scale power generation.

  18. Gas chromatographic analysis of simmondsins and simmondsin ferulates in jojoba meal. (United States)

    Van Boven, M; Holser, R; Cokelaere, M; Flo, G; Decuypere, E


    A capillary gas chromatographic method was developed for the simultaneous determination of simmondsins and simmondsin ferulates in jojoba meal, in detoxified jojoba meal, in jojoba meal extracts, and in animal food mixtures.

  19. Analysis of Stability for Gas-Kinetic Non-Local Traffic Model

    Institute of Scientific and Technical Information of China (English)

    SUN Xi-Ming; DONG Yu-Jie


    @@ The gas-kinetic non-local traffic model is improved by taking into account the relative velocity of the correlated vehicles. The stability of different relaxation time modes is analytically investigated with the perturbation method.

  20. An Introduction to Thermodynamic Performance Analysis of Aircraft Gas Turbine Engine Cycles Using the Numerical Propulsion System Simulation Code (United States)

    Jones, Scott M.


    This document is intended as an introduction to the analysis of gas turbine engine cycles using the Numerical Propulsion System Simulation (NPSS) code. It is assumed that the analyst has a firm understanding of fluid flow, gas dynamics, thermodynamics, and turbomachinery theory. The purpose of this paper is to provide for the novice the information necessary to begin cycle analysis using NPSS. This paper and the annotated example serve as a starting point and by no means cover the entire range of information and experience necessary for engine performance simulation. NPSS syntax is presented but for a more detailed explanation of the code the user is referred to the NPSS User Guide and Reference document (ref. 1).

  1. Analysis of temperature and pressure changes in liquefied natural gas (LNG) cryogenic tanks (United States)

    Chen, Q.-S.; Wegrzyn, J.; Prasad, V.


    Liquefied natural gas (LNG) is being developed as a transportation fuel for heavy vehicles such as trucks and transit buses, to lessen the dependency on oil and to reduce greenhouse gas emissions. The LNG stations are properly designed to prevent the venting of natural gas (NG) from LNG tanks, which can cause evaporative greenhouse gas emissions and result in fluctuations of fuel flow and changes of fuel composition. Boil-off is caused by the heat added into the LNG fuel during the storage and fueling. Heat can leak into the LNG fuel through the shell of tank during the storage and through hoses and dispensers during the fueling. Gas from tanks onboard vehicles, when returned to LNG tanks, can add additional heat into the LNG fuel. A thermodynamic and heat transfer model has been developed to analyze different mechanisms of heat leak into the LNG fuel. The evolving of properties and compositions of LNG fuel inside LNG tanks is simulated. The effect of a number of buses fueled each day on the possible total fuel loss rate has been analyzed. It is found that by increasing the number of buses, fueled each day, the total fuel loss rate can be reduced significantly. It is proposed that an electric generator be used to consume the boil-off gas or a liquefier be used to re-liquefy the boil-off gas to reduce the tank pressure and eliminate fuel losses. These approaches can prevent boil-off of natural gas emissions, and reduce the costs of LNG as transportation fuel.

  2. Analysis of the effect of UO{sub 2} high burnup microstructure on fission gas release

    Energy Technology Data Exchange (ETDEWEB)

    Jernkvist, Lars Olof; Massih, Ali [Quantum Technologies AB, Uppsala Science Park (Sweden)


    This report deals with high-burnup phenomena with relevance to fission gas release from UO{sub 2} nuclear fuel. In particular, we study how the fission gas release is affected by local buildup of fissile plutonium isotopes and fission products at the fuel pellet periphery, with subsequent formation of a characteristic high-burnup rim zone micro-structure. An important aspect of these high-burnup effects is the degradation of fuel thermal conductivity, for which prevalent models are analysed and compared with respect to their theoretical bases and supporting experimental data. Moreover, the Halden IFA-429/519.9 high-burnup experiment is analysed by use of the FRAPCON3 computer code, into which modified and extended models for fission gas release are introduced. These models account for the change in Xe/Kr-ratio of produced and released fission gas with respect to time and space. In addition, several alternative correlations for fuel thermal conductivity are implemented, and their impact on calculated fission gas release is studied. The calculated fission gas release fraction in IFA-429/519.9 strongly depends on what correlation is used for the fuel thermal conductivity, since thermal release dominates over athermal release in this particular experiment. The conducted calculations show that athermal release processes account for less than 10% of the total gas release. However, athermal release from the fuel pellet rim zone is presumably underestimated by our models. This conclusion is corroborated by comparisons between measured and calculated Xe/Kr-ratios of the released fission gas.

  3. Gas-transfer analysis. Section H - real gas results via the van der Waals equation of state and virial expansion extension of its limiting Abel-Noble form

    Energy Technology Data Exchange (ETDEWEB)

    Chenoweth, D R


    An ideal-gas, quasi-steady, duct-flow model previously formulated for small scale gas-transfer problems is extended to real gases via the van der Waals equation of state as well as general virial expansions. The model is applicable for an arbitrary series of ducting components where each is described empirically by total pressure and total temperature change correlations. The adequacy of the van der Waals model for gas-transfer calculations is verified by comparisons with: (1) real gas PVT data; (2) the magnitudes of the controlling effects; and (3) approximate limiting case solutions with numerical results using more accurate real-gas modeling. 25 figures.

  4. Fuel flexibility via real-time Raman fuel-gas analysis for turbine system control (United States)

    Buric, M.; Woodruff, S.; Chorpening, B.; Tucker, D.


    The modern energy production base in the U.S. is increasingly incorporating opportunity fuels such as biogas, coalbed methane, coal syngas, solar-derived hydrogen, and others. In many cases, suppliers operate turbine-based generation systems to efficiently utilize these diverse fuels. Unfortunately, turbine engines are difficult to control given the varying energy content of these fuels, combined with the need for a backup natural gas supply to provide continuous operation. Here, we study the use of a specially designed Raman Gas Analyzer based on capillary waveguide technology with sub-second response time for turbine control applications. The NETL Raman Gas Analyzer utilizes a low-power visible pump laser, and a capillary waveguide gas-cell to integrate large spontaneous Raman signals, and fast gas-transfer piping to facilitate quick measurements of fuel-gas components. A U.S. Department of Energy turbine facility known as HYPER (hybrid performance system) serves as a platform for apriori fuel composition measurements for turbine speed or power control. A fuel-dilution system is used to simulate a compositional upset while simultaneously measuring the resultant fuel composition and turbine response functions in real-time. The feasibility and efficacy of system control using the spontaneous Raman-based measurement system is then explored with the goal of illustrating the ability to control a turbine system using available fuel composition as an input process variable.

  5. Neutron activation analysis (NAA), radioisotope production via neutron activation (PNA) and fission product gas-jet (GJA)

    Energy Technology Data Exchange (ETDEWEB)

    Gaeggeler, H.W. [Paul Scherrer Inst. (PSI), Villigen (Switzerland)


    Three different non-diffractive applications of neutrons are outlined, neutron activation analysis, production of radionuclides, mostly for medical applications, and production of short-lived fission nuclides with a so-called gas-jet. It is shown that all three devices may be incorporated into one single insert at SINQ due to their different requests with respect to thermal neutron flux. Some applications of these three facilities are summarized. (author) 3 figs., 1 tab., 8 refs.

  6. 静脉血气分析的文献研究%Literature Review of Venous Blood Gas Analysis

    Institute of Scientific and Technical Information of China (English)

    董敬军; 赵海伶; 黄穗华


    目的 探讨静脉血气分析在临床中的应用.方法 检索2000 ~2010年静脉血气分析方面的文献,统计分析符合标准的文献例数、检测指标、研究方法和结果等资料.结果 在所筛选的42篇文献中,关于危重医学、新生儿监测的最多,其他包括呼吸系统疾病、麻醉医学、心血管系统疾病、糖尿病等.常用的检测指标包括pH、PVO2、SvO2、ERO2等.结论 在对休克、脑卒中、新生儿窒息等患者进行诊治时,静脉血气监测弥补了动脉血气分析的不足,对临床治疗起到了良好的指导作用.%Objective To study the use of venous blood gas analysis in clinical practice. Methods Literatures regarding venous blood gas analysis published between 2000 and 2010 were retrieved to statistically analyze the number of eligible literatures, measures, study methods, and results. Results In 42 eligible literatures, the majority of them were from critical care and neonatal monitoring, in addition to respiratory disorders, anesthesiology, cardiovascular medicine, and diabetes mellitus. The common measures included pH, PvO2 , SvO2 , and ERO2. Conclusion In the diagnosis of shock, cerebral stroke and neonatal apnea,venous blood gas analysis is complementary to arterial blood gas analysis, useful for the direction of clinical treatment.

  7. Compositional Analysis of Cationic Polyacrylamide Resins by Reactive Pyrolysis-Gas Chromatography in the Presence of Organic Alkali


    Ishida, Yasuyuki; Tsuge, Shin; Otani, Hajime; Inokuchi, Fumiaki; Fujii, Yuji; Suetomo, Shigeru; オオタニ, ハジメ; 大谷, 肇


    Reactive pyrolysis-gas chromatography (Py-GC) in the presence of tetramethylammonium hydroxide (TMAH) was successfully applied to the compositional analysis of cationic polyacrylamide (PAAm) resins, prepared from acrylamide (AAm) and dimethylaminoethylmethacrylate (DM). The reactive pyrolysis of cationic PAAm resulted only in hydrolysis of ester linkages in DM units and did not lead to subsequent methylation of hydrolyzates and cyclization. The intense peak of 2-(dimethylamino)ethanol formed ...


    Energy Technology Data Exchange (ETDEWEB)

    M. G. McKellar; E. A. Harvego; A. M. Gandrik


    An updated reference design for a commercial-scale high-temperature electrolysis (HTE) plant for hydrogen production has been developed. The HTE plant is powered by a high-temperature gas-cooled reactor (HTGR) whose configuration and operating conditions are based on the latest design parameters planned for the Next Generation Nuclear Plant (NGNP). The current HTGR reference design specifies a reactor power of 600 MWt, with a primary system pressure of 7.0 MPa, and reactor inlet and outlet fluid temperatures of 322°C and 750°C, respectively. The reactor heat is used to produce heat and electric power to the HTE plant. A Rankine steam cycle with a power conversion efficiency of 44.4% was used to provide the electric power. The electrolysis unit used to produce hydrogen includes 1.1 million cells with a per-cell active area of 225 cm2. The reference hydrogen production plant operates at a system pressure of 5.0 MPa, and utilizes a steam-sweep system to remove the excess oxygen that is evolved on the anode (oxygen) side of the electrolyzer. The overall system thermal-to-hydrogen production efficiency (based on the higher heating value of the produced hydrogen) is 42.8% at a hydrogen production rate of 1.85 kg/s (66 million SCFD) and an oxygen production rate of 14.6 kg/s (33 million SCFD). An economic analysis of this plant was performed with realistic financial and cost estimating The results of the economic analysis demonstrated that the HTE hydrogen production plant driven by a high-temperature helium-cooled nuclear power plant can deliver hydrogen at a competitive cost. A cost of $3.03/kg of hydrogen was calculated assuming an internal rate of return of 10% and a debt to equity ratio of 80%/20% for a reactor cost of $2000/kWt and $2.41/kg of hydrogen for a reactor cost of $1400/kWt.

  9. Development and assessment of analysis methods for MATMOS trace gas retrievals (United States)

    Olsen, K. S.; Toon, G. C.; Boone, C.; Strong, K.


    The Mars Atmospheric Trace Molecule Occultation Spectrometer (MATMOS) mission will deploy a high-resolution infrared Fourier transform spectrometer (FTS) to Mars on-board the ExoMars Trace Gas Orbiter in 2016. MATMOS is a joint investigation between the California Institute of Technology, NASA's Jet Propulsion Laboratory, and the Canadian Space Agency (CSA). The instrument will be similar to, and derives a strong heritage from, the CSA's Atmospheric Chemistry Experiment Fourier Transform Spectrometer (ACE-FTS) on-board SCISAT. Both MATMOS and ACE-FTS measure the absorption spectra of the atmosphere during solar occultation, making up to 30 measurements per day, one at each satellite sunrise and sunset.ACE-FTS analyzes CO2 to determine temperature and pressure as functions of altitude, then simultaneously retrieves vertical profiles of volume mixing ratio (VMR) for more than two dozen gases using least squares minimization. MATMOS will make use of the GGG analysis suite developed for the MkIV balloon flights, the Atmospheric Trace Molecule Spectroscopy experiment and the ground-based Total Carbon Column Observatory Network. Both retrieval methods divide the spectra into smaller spectral windows and use a Voigt instrument line shape. Their forward models are similar and divide the atmosphere into layers that are assumed to have constant temperature, pressure, and VMR for each molecule. GGG uses the inverse method and its own nonlinear least-squares fitting program to derive partial columns along the optical slant path and to retrieve VMR profiles. MATMOS will inventory the composition of the Martian atmosphere with a sensitivity 2-3 orders of magnitude better than any previous instrument. In order to prepare the GGG analysis suite for the upcoming MATMOS mission, 25 ACE occultations have been analyzed using GGG and compared to the ACE-FTS v3.0 retrievals. This work examines the differences between the two algorithms, identifies those that produce inconsistencies

  10. A Novel Association Rule Mining with IEC Ratio Based Dissolved Gas Analysis for Fault Diagnosis of Power Transformers

    Directory of Open Access Journals (Sweden)

    Kanika Shrivastava


    Full Text Available Dissolved gas Analysis (DGA is the most important component of finding fault in large oil filled transformers. Early detection of incipient faults in transformers reduces costly unplanned outages. The most sensitive and reliable technique for evaluating the core of transformer is dissolved gas analysis. In this paper we evaluate different transformer condition on different cases. This paper uses dissolved gas analysis to study the history of different transformers in service, from which dissolved combustible gases (DCG in oil are used as a diagnostic tool for evaluating the condition of the transformer. Oil quality and dissolved gasses tests are comparatively used for this purpose. In this paper we present a novel approach which is based on association rule mining and IEC ratio method. By using data mining concept we can categorize faults based on single and multiple associations and also map the percentage of fault. This is an efficient approach for fault diagnosis of power transformers where we can find the fault in all obvious conditions. We use java for programming and comparative study.

  11. Numerical analysis and field study of time dependent exergy-energy of a gas-steam combined cycle

    Directory of Open Access Journals (Sweden)

    Barari Bamdad


    Full Text Available In this study, time dependent exergy analysis of the Fars Combined Power Plant Cycle has been investigated. Exergy analysis has been used for investigating each part of actual combined cycle by considering irreversibility from Apr 2006 to Oct 2010. Performance analysis has been done for each part by evaluating exergy destruction in each month. By using of exergy analysis, aging of each part has been evaluated respect to time duration. In addition, the rate of lost work for each month has been calculated and variation of this parameter has been considered as a function of aging rate. Finally, effects of exergy destruction of each part have been investigated on exergy destruction of whole cycle. Entire analysis has been done for Unit 3 and 4 of gas turbine cycle which combined by Unit B of steam cycle in Fars Combined Power Plant Cycle located in Fars province in Iran.

  12. A satellite-based analysis of the Val d'Agri (South of Italy) Oil Center gas flaring emissions (United States)

    Faruolo, M.; Coviello, I.; Filizzola, C.; Lacava, T.; Pergola, N.; Tramutoli, V.


    In this paper the Robust Satellite Techniques (RST), a multi-temporal scheme of satellite data analysis, was implemented to analyze the flaring activity of the largest Italian gas and oil pre-treatment plant (i.e. the Ente Nazionale Idrocarburi - ENI - Val d'Agri Oil Center - COVA). For this site, located in an anthropized area characterized by a~large environmental complexity, flaring emissions are mainly related to emergency conditions (i.e. waste flaring), being the industrial process regulated by strict regional laws. With reference to the peculiar characteristics of COVA flaring, the main aim of this work was to assess the performances of RST in terms of sensitivity and reliability in providing independent estimations of gas flaring volumes in such conditions. In detail, RST was implemented on thirteen years of Moderate Resolution Imaging Spectroradiometer (MODIS) medium and thermal infrared data in order to identify the highly radiant records associated to the COVA flare emergency discharges. Then, exploiting data provided by ENI about gas flaring volumes in the period 2003-2009, a MODIS-based regression model was developed and tested. Achieved results indicate that such a model is able to estimate, with a good level of accuracy (R2 of 0.83), emitted gas flaring volumes at COVA.

  13. A satellite-based analysis of the Val d'Agri Oil Center (southern Italy) gas flaring emissions (United States)

    Faruolo, M.; Coviello, I.; Filizzola, C.; Lacava, T.; Pergola, N.; Tramutoli, V.


    In this paper, the robust satellite techniques (RST), a multi-temporal scheme of satellite data analysis, was implemented to analyze the flaring activity of the Val d'Agri Oil Center (COVA), the largest Italian gas and oil pre-treatment plant, owned by Ente Nazionale Idrocarburi (ENI). For this site, located in an anthropized area characterized by a large environmental complexity, flaring emissions are mainly related to emergency conditions (i.e., waste flaring), as industrial processes are regulated by strict regional laws. While regarding the peculiar characteristics of COVA flaring, the main aim of this work was to assess the performances of RST in terms of sensitivity and reliability in providing independent estimations of gas flaring volumes in such conditions. In detail, RST was implemented for 13 years of Moderate Resolution Imaging Spectroradiometer (MODIS) medium and thermal infrared data in order to identify the highly radiant records associated with the COVA flare emergency discharges. Then, using data provided by ENI about gas flaring volumes in the period 2003-2009, a MODIS-based regression model was developed and tested. The results achieved indicate that the such a model is able to estimate, with a good level of accuracy (R2 of 0.83), emitted gas flaring volumes at COVA.

  14. Cycle analysis of an integrated solid oxide fuel cell and recuperative gas turbine with an air reheating system (United States)

    Zhang, Xiongwen; Li, Jun; Li, Guojun; Feng, Zhenping

    Cycle simulation and analysis for two kinds of SOFC/GT hybrid systems were conducted with the help of the simulation tool: Aspen Custom Modeler. Two cycle schemes of recuperative heat exchanger (RHE) and exhaust gas recirculated (EGR) were described according to the air reheating method. The system performance with operating pressure, turbine inlet temperature and fuel cell load were studied based on the simulation results. Then the effects of oxygen utilization, fuel utilization, operating temperature and efficiencies of the gas turbine components on the system performance of the RHE cycle and the EGR cycle were discussed in detail. Simulation results indicated that the system optimum efficiency for the EGR air reheating cycle scheme was higher than that of the RHE cycle system. A higher pressure ratio would be available for the EGR cycle system in comparison with the RHE cycle. It was found that increasing fuel utilization or oxygen utilization would decrease fuel cell efficiency but improve the system efficiency for both of the RHE and EGR cycles. The efficiency of the RHE cycle hybrid system decreased as the fuel cell air inlet temperature increased. However, the system efficiency of EGR cycle increased with fuel cell air inlet temperature. The effect of turbine efficiency on the system efficiency was more obvious than the effect of the compressor and recuperator efficiencies among the gas turbine components. It was also indicated that improving the gas turbine component efficiencies for the RHE cycle increased system efficiency higher than that for the EGR cycle.

  15. Gas chromatography analysis with olfactometric detection (GC-O) as a useful methodology for chemical characterization of odorous compounds. (United States)

    Brattoli, Magda; Cisternino, Ezia; Dambruoso, Paolo Rosario; de Gennaro, Gianluigi; Giungato, Pasquale; Mazzone, Antonio; Palmisani, Jolanda; Tutino, Maria


    The gas chromatography-olfactometry (GC-O) technique couples traditional gas chromatographic analysis with sensory detection in order to study complex mixtures of odorous substances and to identify odor active compounds. The GC-O technique is already widely used for the evaluation of food aromas and its application in environmental fields is increasing, thus moving the odor emission assessment from the solely olfactometric evaluations to the characterization of the volatile components responsible for odor nuisance. The aim of this paper is to describe the state of the art of gas chromatography-olfactometry methodology, considering the different approaches regarding the operational conditions and the different methods for evaluating the olfactometric detection of odor compounds. The potentials of GC-O are described highlighting the improvements in this methodology relative to other conventional approaches used for odor detection, such as sensoristic, sensorial and the traditional gas chromatographic methods. The paper also provides an examination of the different fields of application of the GC-O, principally related to fragrances and food aromas, odor nuisance produced by anthropic activities and odorous compounds emitted by materials and medical applications.

  16. Gas Chromatography Analysis with Olfactometric Detection (GC-O as a Useful Methodology for Chemical Characterization of Odorous Compounds

    Directory of Open Access Journals (Sweden)

    Magda Brattoli


    Full Text Available The gas chromatography-olfactometry (GC-O technique couples traditional gas chromatographic analysis with sensory detection in order to study complex mixtures of odorous substances and to identify odor active compounds. The GC-O technique is already widely used for the evaluation of food aromas and its application in environmental fields is increasing, thus moving the odor emission assessment from the solely olfactometric evaluations to the characterization of the volatile components responsible for odor nuisance. The aim of this paper is to describe the state of the art of gas chromatography-olfactometry methodology, considering the different approaches regarding the operational conditions and the different methods for evaluating the olfactometric detection of odor compounds. The potentials of GC-O are described highlighting the improvements in this methodology relative to other conventional approaches used for odor detection, such as sensoristic, sensorial and the traditional gas chromatographic methods. The paper also provides an examination of the different fields of application of the GC-O, principally related to fragrances and food aromas, odor nuisance produced by anthropic activities and odorous compounds emitted by materials and medical applications.

  17. Exergetic analysis and evaluation of a new application of gas engine heat pumps (GEHPs) for food drying processes

    Energy Technology Data Exchange (ETDEWEB)

    Gungor, Aysegul [Department of Mechanical Engineering, Faculty of Engineering, Gediz University, Izmir (Turkey); Erbay, Zafer [Department of Food Engineering, Faculty of Engineering, Ege University, 35100 Izmir (Turkey); Hepbasli, Arif [Department of Mechanical Engineering, Faculty of Engineering, Ege University, 35100 Izmir (Turkey)


    In this study, three medicinal and aromatic plants (Foeniculum vulgare, Malva sylvestris L. and Thymus vulgaris) were dried in a pilot scale gas engine driven heat pump drier, which was designed, constructed and installed in Ege University, Izmir, Turkey. Drying experiments were performed at an air temperature of 45 C with an air velocity of 1 m/s. In this work, the performance of the drier along with its main components is evaluated using exergy analysis method. The most important component for improving the system efficiency is found to be the gas engine, followed by the exhaust air heat exchanger for the drying system. An exergy loss and flow diagram (the so-called Grassmann diagram) of the whole drying system is also presented to give quantitative information regarding the proportion of the exergy input dissipated in the various system components, while the sustainability index values for the system components are calculated to indicate how sustainability is affected by changing the exergy efficiency of a process. Gas engine, expansion valve and drying ducts account for more than 60% amount of exergy in the system. The exergetic efficiency values are in the range of 77.68-79.21% for the heat pump unit, 39.26-43.24% for the gas engine driven heat pump unit, 81.29-81.56% for the drying chamber and 48.24-51.28% for the overall drying system. (author)

  18. A satellite-based analysis of the Val d'Agri (South of Italy Oil Center gas flaring emissions

    Directory of Open Access Journals (Sweden)

    M. Faruolo


    Full Text Available In this paper the Robust Satellite Techniques (RST, a multi-temporal scheme of satellite data analysis, was implemented to analyze the flaring activity of the largest Italian gas and oil pre-treatment plant (i.e. the Ente Nazionale Idrocarburi – ENI – Val d'Agri Oil Center – COVA. For this site, located in an anthropized area characterized by a~large environmental complexity, flaring emissions are mainly related to emergency conditions (i.e. waste flaring, being the industrial process regulated by strict regional laws. With reference to the peculiar characteristics of COVA flaring, the main aim of this work was to assess the performances of RST in terms of sensitivity and reliability in providing independent estimations of gas flaring volumes in such conditions. In detail, RST was implemented on thirteen years of Moderate Resolution Imaging Spectroradiometer (MODIS medium and thermal infrared data in order to identify the highly radiant records associated to the COVA flare emergency discharges. Then, exploiting data provided by ENI about gas flaring volumes in the period 2003–2009, a MODIS-based regression model was developed and tested. Achieved results indicate that such a model is able to estimate, with a good level of accuracy (R2 of 0.83, emitted gas flaring volumes at COVA.

  19. Spatial distribution of the optogalvanic signal in a microplasma detector for lab-on-a-chip gas analysis (United States)

    Persson, A.; Berglund, M.


    Gas sensors are characterized by their sensitivity and selectivity. This is preferably combined with versatility, where the selectivity can be altered, without complex modifications and whiteout losing sensitivity. If aimed at lab-on-a-chip applications, the sensor also must be able to analyze small samples. Today, sensors combining selectivity and versatility for chip-level gas analysis are scarce; however, this paper investigates how miniaturized optogalvanic spectroscopy can fill this gap. By studying the spatial distribution of the optogalvanic signal inside a microplasma, it is shown that the signal is generated in the minuscule gas volume of the sheath surrounding the plasma probe that collects it. Nevertheless, a strong and stable spectroscopic signal can be extracted from the sheath, and the sample concentrations can be calculated using straightforward plasma theory. The minimum detectable absorption and the noise equivalent absorption sensitivity of the system are estimated to be less than 1.4  ×  10-9 Hz-0.5 and 2.8  ×  10-9 cm-1 Hz-0.5, respectively, without cavity enhancement. Combined with inherited versatility from absorption spectroscopy and the capability of handling sub-nanogram samples, this makes optogalvanic spectrometry an excellent candidate for future lab-on-a-chip gas analyzers.

  20. Sulfur-bearing phases detected by evolved gas analysis of the Rocknest aeolian deposit, Gale Crater, Mars



    The Sample Analysis at Mars (SAM) instrument suite detected SO_2, H_(2)S, OCS, and CS_2 from ~450 to 800°C during evolved gas analysis (EGA) of materials from the Rocknest aeolian deposit in Gale Crater, Mars. This was the first detection of evolved sulfur species from a Martian surface sample during in situ EGA. SO_2 (~3–22 µmol) is consistent with the thermal decomposition of Fe sulfates or Ca sulfites, or evolution/desorption from sulfur-bearing amorphous phases. Reactions between reduced ...