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Sample records for anaerobic aquifer polluted

  1. Atrazine removal in Danish anaerobic aquifers

    DEFF Research Database (Denmark)

    Pedersen, Philip Grinder; Arildskov, N.P.; Albrechtsen, Hans-Jørgen

    2002-01-01

    The pesticide atrazine (6-chloro-N-2-ethyl-N-4-isopropyl-1,3,5-triazine -2,4-diamine) was removed from the water phase in anaerobic laboratory batch incubations with sediment and groundwater from a number of Danish anaerobic aquifers, but not in incubations from aerobic aquifers. The removal...

  2. Anaerobic degradation of alkylated benzenes in denitrifying laboratory aquifer columns

    International Nuclear Information System (INIS)

    Toluene and m-xylene were rapidly mineralized in an anaerobic laboratory aquifer column operated under continuous-flow conditions with nitrate as an electron acceptor. The oxidation of toluene and m-xylene was coupled with the reduction of nitrate, and mineralization was confirmed by trapping 14CO2 evolved from 14C-ring-labeled substrates. Substrate degradation also took place when nitrous oxide replaced nitrate as an electron acceptor, but decomposition was inhibited in the presence of molecular oxygen or after the substitution of nitrate by nitrite. The m-xylene-adapted microorganisms in the aquifer column degraded toluene, benzaldehyde, benzoate, m-toluylaldehyde, m-toluate, m-cresol, p-cresol, and p-hydroxybenzoate but were unable to metabolize benzene, naphthalene, methylcyclohexane, and 1,3-dimethylcyclohexane. Isotope-dilution experiments suggested benzoate as an intermediate formed during anaerobic toluene metabolism. The finding that the highly water-soluble nitrous oxide served as electron acceptor for the anaerobic mineralization of some aromatic hydrocarbons may offer attractive options for the in situ restoration of polluted aquifers

  3. Bio-remediation of aquifers polluted by chlorinated solvents

    International Nuclear Information System (INIS)

    Numerous cases of contamination of aquifers by chlorinated aliphatic solvents, largely utilized during the last decades, constitute a public health problem, because of the toxic effect of such compounds. Different types of aerobic or anaerobic bacteria are able to degrade these molecules. Processes of bio remediation are now experimented in order to restore polluted aquifers. We present here the microorganisms and the enzymatic reactions involved in the biodegradation of chlorinated solvents, and different examples of in situ bio remediation operations are described. (author)

  4. Key players and team play: anaerobic microbial communities in hydrocarbon-contaminated aquifers.

    Science.gov (United States)

    Kleinsteuber, Sabine; Schleinitz, Kathleen M; Vogt, Carsten

    2012-05-01

    Biodegradation of anthropogenic pollutants in shallow aquifers is an important microbial ecosystem service which is mainly brought about by indigenous anaerobic microorganisms. For the management of contaminated sites, risk assessment and control of natural attenuation, the assessment of in situ biodegradation and the underlying microbial processes is essential. The development of novel molecular methods, "omics" approaches, and high-throughput techniques has revealed new insight into complex microbial communities and their functions in anoxic environmental systems. This review summarizes recent advances in the application of molecular methods to study anaerobic microbial communities in contaminated terrestrial subsurface ecosystems. We focus on current approaches to analyze composition, dynamics, and functional diversity of subsurface communities, to link identity to activity and metabolic function, and to identify the ecophysiological role of not yet cultured microbes and syntrophic consortia. We discuss recent molecular surveys of contaminated sites from an ecological viewpoint regarding degrader ecotypes, abiotic factors shaping anaerobic communities, and biotic interactions underpinning the importance of microbial cooperation for microbial ecosystem services such as contaminant degradation. PMID:22476263

  5. Anaerobic Degradation of Chlorinated Hydrocarbons in Groundwater Aquifers or "Chlorinated Hydrocarbon Degradation"

    OpenAIRE

    Nielsen, R. Brent; Jay D Keasling

    1997-01-01

    Groundwater contamination by chlorinated hydrocarbons, such as tetrachloroethene (PCE) or trichloroethene (TCE), is a major concern throughout the United States. A developing strategy for the remediation of PCE and TCE contaminated aquifers is anaerobic biodegradation. From a TCE contaminated groundwater site, microorganisms were enriched with the ability to anaerobically convert PCE and TCE completely to ethene. Kinetic studies performed with this culture showed that degradation of PCE, TCE...

  6. Pollution of an aquifer by produced oil field water

    International Nuclear Information System (INIS)

    Brine is produced from reservoirs as a waste material from crude oil and gas after processing. Waste water may be discharged at the surface or reinjected underground. When it is reinjected, it may be mixed with an underground fresh water source for several reasons. From this point of view, forecasting the pollutant concentrations by knowing the historical data at several locations on a field has great importance when planning the necessary precautions for environmental safety. Aquifer-M in Turkey, having the properties of potable water, is contaminated by oil field water that is injected for disposal purposes. A numerical model is used to determine the extent of pollution due to the injection of saline produced water into aquifer-M. Eight observation wells are drilled to take water and core samples in order to identify both rock and fluid properties of aquifer-M. Water samples taken from different intervals of aquifer-M are analyzed to determine the flow paths for the pollutant movement. The results are interpreted with the help of core property data obtained by computerized tomography (CT) analysis and routine core analysis. By using drilling records, log data, and CT analysis results, two subunits in aquifer-M with different lithological properties are identified. All data are used in a ground water pollution model. Aquifer-M has fresh water with salinity of 5-10 ppm, and the chlorine concentration of injected waste water is approximately 3410 pp. Since there is a significant difference between these concentrations, the chlorine ion is selected as the indicative ion for locating the pollution front. The model study indicated that the contaminated water has propagated 18.7 km from the site of injection. (author)

  7. Microcosm experiments to control anaerobic redox conditions when studying the fate of organic micropollutants in aquifer material

    Science.gov (United States)

    Barbieri, Manuela; Carrera, Jesús; Sanchez-Vila, Xavier; Ayora, Carlos; Cama, Jordi; Köck-Schulmeyer, Marianne; López de Alda, Miren; Barceló, Damià; Tobella Brunet, Joana; Hernández García, Marta

    2011-11-01

    The natural processes occurring in subsurface environments have proven to effectively remove a number of organic pollutants from water. The predominant redox conditions revealed to be one of the controlling factors. However, in the case of organic micropollutants the knowledge on this potential redox-dependent behavior is still limited. Motivated by managed aquifer recharge practices microcosm experiments involving aquifer material, settings potentially feasible in field applications, and organic micropollutants at environmental concentrations were carried out. Different anaerobic redox conditions were promoted and sustained in each set of microcosms by adding adequate quantities of electron donors and acceptors. Whereas denitrification and sulfate-reducing conditions are easily achieved and maintained, Fe- and Mn-reduction are strongly constrained by the slower dissolution of the solid phases commonly present in aquifers. The thorough description and numerical modeling of the evolution of the experiments, including major and trace solutes and dissolution/precipitation of solid phases, have been proven necessary to the understanding of the processes and closing the mass balance. As an example of micropollutant results, the ubiquitous beta-blocker atenolol is completely removed in the experiments, the removal occurring faster under more advanced redox conditions. This suggests that aquifers constitute a potentially efficient alternative water treatment for atenolol, especially if adequate redox conditions are promoted during recharge and long enough residence times are ensured.

  8. Testing water pollution in a two layer aquifer

    OpenAIRE

    García León, Manuel; Lin Ye, Jue

    2011-01-01

    Water bodies around urban areas may be polluted with chemical elements from urban or industrial activities. We study the case of underground water pollution. This is a serious problem, since under- ground water is high qualified drinkable water in a world where this natural resource is increasingly reduced. This study is focused on a two-layer aquifer. If the superficial layer is contaminated, the deeper layer could be spoiled as well. This contribution checks the equality of the mean or c...

  9. Aquifer interactions with a polluted mountain river of Nicaragua

    OpenAIRE

    Mendoza, Alfredo; Ulriksen, Peter; Picado, Francisco; Dahlin, Torleif

    2008-01-01

    The interactions between a stream and nearby shallow aquifers were investigated in a mountain basin being polluted by mercury released during mining in central Nicaragua. Hourly data series of water levels and temperatures were analysed using cross-correlation. Resistivity imaging was used to map the subsurface and to complement the hydrological data interpretation. The results show the complex hydrogeological conditions that characterize the region, with weathering and fractured rock as main...

  10. Concurrent nitrate and Fe(III) reduction during anaerobic biodegradation of phenols in a sandstone aquifer

    DEFF Research Database (Denmark)

    Broholm, Mette; Crouzet, C.; Arvin, Erik;

    2000-01-01

    and selected redox sensitive parameters at the end of the experiment. The sandstone material was characterized with respect to oxidation and reduction potential and Fe(II) and Fe(III) speciation prior to use for all microcosms and at the end of the experiments for selected microcosms. The redox conditions......, in the unamended microcosm. For microcosm systems. with solid aquifer materials. dissolution of organic substances from the solid material may occur. A quantitative determination of the speciation (mineral types and quantity) of electron acceptors associated with the solids, at levels relevant for degradation......The biodegradation of phenols (similar to 5, 60, 600 mg 1(-1)) under anaerobic conditions (nitrate enriched and unamended) was studied in laboratory microcosms with sandstone material and groundwater from within an anaerobic ammonium plume in an aquifer, The aqueous phase was sampled and analyzed...

  11. Relating BTEX degradation to the biogeochemistry of an anaerobic aquifer

    International Nuclear Information System (INIS)

    Trends in chemical and microbiological parameters in a petroleum hydrocarbon plume within anaerobic groundwater have been studied. Previously, microbial degradation of the hydrocarbon compounds had been substantiated by the use of deuterated hydrocarbons to determine natural (intrinsic) degradation rates within the contaminant plume. Here, sulfate concentration decreases, Eh decreases, and hydrogen sulfide and bicarbonate concentration increases are shown to be associated with the contaminant plume. These trends indicate microbial degradation of the benzene, toluene, ethylbenzene, and xylene (BTEX) compounds by sulfate-reducing bacteria. Stoichiometry indicates that other consortia of bacteria play a role in the degradation of the hydrocarbons. Total microbial cell numbers were higher within the plume than in the uncontaminated groundwater. There is, however, no direct correlation between total microbial cell numbers, and BTEX, sulfate, bicarbonate, and hydrogen sulfide concentrations within the plume

  12. Evidence for Microbial Iron Reduction in a Landfill Leachate-Polluted Aquifer (Vejen, Denmark)

    DEFF Research Database (Denmark)

    Albrechtsen, Hans-Jørgen; Christensen, Thomas Højlund

    1994-01-01

    Aquifer sediment samples obtained from the anaerobic part of a landfill leachate plume in Vejen, Denmark, were suspended in groundwater or in an artificial medium and incubated. The strictly anaerobic suspensions were tested for reduction of ferric iron (Fe(III)) oxides, which was measured as an...

  13. Overview of the anaerobic toxicity caused by organic forest industry wastewater pollutants.

    NARCIS (Netherlands)

    Sierra-Alvarez, R.; Field, J.A.; Kortekaas, S.; Lettinga, G.

    1994-01-01

    Numerous types of organic environmental pollutants are encountered in forest industry effluents which potentially could inhibit consortia of anaerobic bacteria. The purpose of this study was to collect anaerobic bioassay data from the literature to better estimate the impact of these pollutants on a

  14. Relationships between microbial community structure and hydrochemistry in a landfill leachate-polluted aquifer.

    OpenAIRE

    Roling, W.F.M.; Breukelen, van, R.; Braster, M; Lin, B.; Verseveld, van, Marloes

    2001-01-01

    Knowledge about the relationship between microbial community structure and hydrogeochemistry (e.g., pollution, redox and degradation processes) in landfill leachate-polluted aquifers is required to develop tools for predicting and monitoring natural attenuation. In this study analyses of pollutant and redox chemistry were conducted in parallel with culture-independent profiling of microbial communities present in a well-defined aquifer (Banisveld, The Netherlands). Degradation of organic cont...

  15. Role of Anaerobic Ammonium Oxidation (Anammox) in Nitrogen Removal from a Freshwater Aquifer.

    Science.gov (United States)

    Smith, Richard L; Böhlke, J K; Song, Bongkeun; Tobias, Craig R

    2015-10-20

    Anaerobic ammonium oxidation (anammox) couples the oxidation of ammonium with the reduction of nitrite, producing N2. The presence and activity of anammox bacteria in groundwater were investigated at multiple locations in an aquifer variably affected by a large, wastewater-derived contaminant plume. Anammox bacteria were detected at all locations tested using 16S rRNA gene sequencing and quantification of hydrazine oxidoreductase (hzo) gene transcripts. Anammox and denitrification activities were quantified by in situ (15)NO2(-) tracer tests along anoxic flow paths in areas of varying ammonium, nitrate, and organic carbon abundances. Rates of denitrification and anammox were determined by quantifying changes in (28)N2, (29)N2, (30)N2, (15)NO3(-), (15)NO2(-), and (15)NH4(+) with groundwater travel time. Anammox was present and active in all areas tested, including where ammonium and dissolved organic carbon concentrations were low, but decreased in proportion to denitrification when acetate was added to increase available electron supply. Anammox contributed 39-90% of potential N2 production in this aquifer, with rates on the order of 10 nmol N2-N L(-1) day(-1). Although rates of both anammox and denitrification during the tracer tests were low, they were sufficient to reduce inorganic nitrogen concentrations substantially during the overall groundwater residence times in the aquifer. These results demonstrate that anammox activity in groundwater can rival that of denitrification and may need to be considered when assessing nitrogen mass transport and permanent loss of fixed nitrogen in aquifers. PMID:26401911

  16. In-Situ Anaerobic Biosurfactant Production Process For Remediation Of DNAPL Contamination In Subsurface Aquifers

    Science.gov (United States)

    Albino, J. D.; Nambi, I. M.

    2009-12-01

    Microbial Enhanced Oil Recovery (MEOR) and remediation of aquifers contaminated with hydrophobic contaminants require insitu production of biosurfactants for mobilization of entrapped hydrophobic liquids. Most of the biosurfactant producing microorganisms produce them under aerobic condition and hence surfactant production is limited in subsurface condition due to lack of oxygen. Currently bioremediation involves expensive air sparging or excavation followed by exsitu biodegradation. Use of microorganisms which can produce biosurfactants under anaerobic conditions can cost effectively expedite the process of insitu bioremediation or mobilization. In this work, the feasibility of anaerobic biosurfactant production in three mixed anaerobic cultures prepared from groundwater and soil contaminated with chlorinated compounds and municipal sewage sludge was investigated. The cultures were previously enriched under complete anaerobic conditions in the presence of Tetrachloroethylene (PCE) for more than a year before they were studied for biosurfactant production. Biosurfactant production under anaerobic conditions was simulated using two methods: i) induction of starvation in the microbial cultures and ii) addition of complex fermentable substrates. Positive result for biosurfactant production was not observed when the cultures were induced with starvation by adding PCE as blobs which served as the only terminal electron acceptor. However, slight reduction in interfacial tension was noticed which was caused by the adherence of microbes to water-PCE interface. Biosurfactant production was observed in all the three cultures when they were fed with complex fermentable substrates and surface tension of the liquid medium was lowered below 35 mN/m. Among the fermentable substrates tested, vegetable oil yielded highest amount of biosurfactant in all the cultures. Complete biodegradation of PCE to ethylene at a faster rate was also observed when vegetable oil was amended to the

  17. Aquifer vulnerability to pesticide pollution - Combining soil, land-use and aquifer properties with molecular descriptors

    Science.gov (United States)

    Worrall, F.; Kolpin, D.W.

    2004-01-01

    This study uses an extensive survey of herbicides in groundwater across the midwest United States to predict occurrences of a range of compounds across the region from a combination of their molecular properties and the properties of the catchment of a borehole. The study covers 100 boreholes and eight pesticides. For each of the boreholes its catchment the soil, land-use and aquifer properties were characterized. Discriminating boreholes where pollution occurred from those where no pollution occurred gave a model that was 74% correct with organic carbon content, percentage sand content and depth to the water table being significant properties of the borehole catchment. Molecular topological descriptors as well as Koc, solubility and half-life were used to characterize each compound included in the study. Inclusion of molecular properties makes it possible to discriminate between occurrence and non-occurrence of each compound in each well. The best-fit model combines: organic carbon content, percentage sand content and depth to the water table with molecular descriptors representing molecular size, molecular branching and functional group composition of the herbicides.

  18. Degradation of weathered diesel fuel by microorganisms from a contaminated aquifer in aerobic and anaerobic microcosms

    International Nuclear Information System (INIS)

    A diesel fuel-contaminated aquifer in Menziken, Canton of Aargau, Switzerland, was in situ bioremediated from 1989 to 1994 by adding O2, NO3-, PO43-, and NH4+ through an infiltration well. After a remediation time of 3.5 years, aquifer material from the contaminated zone was excavated and found to contain > 106 hydrocarbon-degrading microorganisms/g and 1.15 ± 0.15 mg/g weathered diesel fuel comprising mainly isoprenoid alkanes and an unresolved complex mixture (UCM) of unknown components. Samples of this material were incubated for up to 470 days in aerobic and anaerobic microcosms. The microbial activity was determined by measuring the production of inorganic carbon and the consumption of O2 and NO3-. The degradation of the weathered diesel fuel was quantified by infrared spectroscopy and by capillary gas chromatography. In aerobic microcosms, all isoprenoid alkanes and most of the UCM were biodegraded as long as a nitrogen source was present. The O2 consumption could be stimulated by adding KH2PO4 and by elevating the temperature to 22 C. In anaerobic microcosms with KNO3, NO3- was consumed, inorganic carbon was produced, and the isoprenoid alkanes and the UCM were partially metabolized. In some selected microcosms, the NO3- consumption rate was stimulated by adding external substrates such as toluene, o-xylene, m-xylene, p-xylene, n-alkanes, or fatty acids. Mineralization of toluene, naphthalene, and hexadecane to CO2 under denitrifying conditions was confirmed by using [14C]-labelled substrates

  19. Interpolation of extensive routine water pollution monitoring datasets: methodology and discussion of implications for aquifer management.

    Science.gov (United States)

    Yuval, Yuval; Rimon, Yaara; Graber, Ellen R; Furman, Alex

    2014-08-01

    A large fraction of the fresh water available for human use is stored in groundwater aquifers. Since human activities such as mining, agriculture, industry and urbanisation often result in incursion of various pollutants to groundwater, routine monitoring of water quality is an indispensable component of judicious aquifer management. Unfortunately, groundwater pollution monitoring is expensive and usually cannot cover an aquifer with the spatial resolution necessary for making adequate management decisions. Interpolation of monitoring data is thus an important tool for supplementing monitoring observations. However, interpolating routine groundwater pollution data poses a special problem due to the nature of the observations. The data from a producing aquifer usually includes many zero pollution concentration values from the clean parts of the aquifer but may span a wide range of values (up to a few orders of magnitude) in the polluted areas. This manuscript presents a methodology that can cope with such datasets and use them to produce maps that present the pollution plumes but also delineates the clean areas that are fit for production. A method for assessing the quality of mapping in a way which is suitable to the data's dynamic range of values is also presented. A local variant of inverse distance weighting is employed to interpolate the data. Inclusion zones around the interpolation points ensure that only relevant observations contribute to each interpolated concentration. Using inclusion zones improves the accuracy of the mapping but results in interpolation grid points which are not assigned a value. The inherent trade-off between the interpolation accuracy and coverage is demonstrated using both circular and elliptical inclusion zones. A leave-one-out cross testing is used to assess and compare the performance of the interpolations. The methodology is demonstrated using groundwater pollution monitoring data from the coastal aquifer along the Israeli

  20. Interpolation of extensive routine water pollution monitoring datasets: methodology and discussion of implications for aquifer management

    Science.gov (United States)

    Yuval; Rimon, Y.; Graber, E. R.; Furman, A.

    2013-07-01

    A large fraction of the fresh water available for human use is stored in groundwater aquifers. Since human activities such as mining, agriculture, industry and urbanization often result in incursion of various pollutants to groundwater, routine monitoring of water quality is an indispensable component of judicious aquifer management. Unfortunately, groundwater pollution monitoring is expensive and usually cannot cover an aquifer with the spatial resolution necessary for making adequate management decisions. Interpolation of monitoring data between points is thus an important tool for supplementing measured data. However, interpolating routine groundwater pollution data poses a special problem due to the nature of the observations. The data from a producing aquifer usually includes many zero pollution concentration values from the clean parts of the aquifer but may span a wide range (up to a few orders of magnitude) of values in the polluted areas. This manuscript presents a methodology that can cope with such datasets and use them to produce maps that present the pollution plumes but also delineates the clean areas that are fit for production. A method for assessing the quality of mapping in a way which is suitable to the data's dynamic range of values is also presented. Local variant of inverse distance weighting is employed to interpolate the data. Inclusion zones around the interpolation points ensure that only relevant observations contribute to each interpolated concentration. Using inclusion zones improves the accuracy of the mapping but results in interpolation grid points which are not assigned a value. That inherent trade-off between the interpolation accuracy and coverage is demonstrated using both circular and elliptical inclusion zones. A leave-one-out cross testing is used to assess and compare the performance of the interpolations. The methodology is demonstrated using groundwater pollution monitoring data from the Coastal aquifer along the Israeli

  1. Interpolation of extensive routine water pollution monitoring datasets: methodology and discussion of implications for aquifer management

    Directory of Open Access Journals (Sweden)

    Yuval

    2013-07-01

    Full Text Available A large fraction of the fresh water available for human use is stored in groundwater aquifers. Since human activities such as mining, agriculture, industry and urbanization often result in incursion of various pollutants to groundwater, routine monitoring of water quality is an indispensable component of judicious aquifer management. Unfortunately, groundwater pollution monitoring is expensive and usually cannot cover an aquifer with the spatial resolution necessary for making adequate management decisions. Interpolation of monitoring data between points is thus an important tool for supplementing measured data. However, interpolating routine groundwater pollution data poses a special problem due to the nature of the observations. The data from a producing aquifer usually includes many zero pollution concentration values from the clean parts of the aquifer but may span a wide range (up to a few orders of magnitude of values in the polluted areas. This manuscript presents a methodology that can cope with such datasets and use them to produce maps that present the pollution plumes but also delineates the clean areas that are fit for production. A method for assessing the quality of mapping in a way which is suitable to the data's dynamic range of values is also presented. Local variant of inverse distance weighting is employed to interpolate the data. Inclusion zones around the interpolation points ensure that only relevant observations contribute to each interpolated concentration. Using inclusion zones improves the accuracy of the mapping but results in interpolation grid points which are not assigned a value. That inherent trade-off between the interpolation accuracy and coverage is demonstrated using both circular and elliptical inclusion zones. A leave-one-out cross testing is used to assess and compare the performance of the interpolations. The methodology is demonstrated using groundwater pollution monitoring data from the Coastal aquifer

  2. Vulnerability and Pollution Risks in the Alluvial Aquifer of Tebessa-Morsott

    OpenAIRE

    S. Kachi; N. Kherici; N. Kachi

    2007-01-01

    We studied the vulnerability and risks of pollution of the alluvial aquifer of Tebessa-Morsott that ranks amongst the major groundwater reservoirs of the region. The method used to asses groundwater vulnerability was the DRASTIC method, based on seven parameters that affect and control the groundwater flow: Depth to groundwater, Impact of the unsaturated zone, net recharge, aquifer media, hydraulic conductivity, soil media, topography. These parameters were obtained from data field, synthetic...

  3. Methanotrophic Bacteria and Facilitated Transport of Pollutants in Aquifer Material

    OpenAIRE

    Jenkins, Michael B.; Chen, Jyh-Herng; Kadner, Debra J.; Lion, Leonard W.

    1994-01-01

    In situ stimulation of methanotrophic bacteria has been considered as a methodology for aquifer remediation. Chlorinated aliphatic hydrocarbons such as trichloroethylene are fortuitously oxidized by the methane monooxygenase produced by methanotrophic bacteria. Experimental results are presented that indicate that both colloidal suspensions containing methanotrophic cells and the soluble extracellular polymers produced by methanotrophic cells have the potential to enhance the transport and re...

  4. Soil aquifer treatment to remove priority organic pollutants in the Llobregat river area

    OpenAIRE

    Huerta, Maria; Solé, Josep; Aceves, Mercè; Valhondo González, Cristina; Hernández, Marta; Gullón Santos, Martín

    2013-01-01

    The Llobregat River is the main source of water supply in this area. This river together with its aquifer has suffered from several damages which had contributed to endanger a suitable ecological and hydrological status; among them, pollution is a serious problem to deal with. In the last decades, the presence of organic pollutants in this river has been demonstrated [1,2]. Some of them are persistent to biological degradation and have shown to survive wastewater treatments almost unaltered a...

  5. Groundwater pollution risk mapping for the Eocene aquifer of the Oum Er-Rabia basin, Morocco

    Science.gov (United States)

    Ettazarini, Said

    2006-11-01

    Sustainable development requires the management and preservation of water resources indispensable for all human activities. When groundwater constitutes the main water resource, vulnerability maps therefore are an important tool for identifying zones of high pollution risk and taking preventive measures in potential pollution sites. The vulnerability assessment for the Eocene aquifer in the Moroccan basin of Oum Er-Rabia is based on the DRASTIC method that uses seven parameters summarizing climatic, geological, and hydrogeological conditions controlling the seepage of pollutant substances to groundwater. Vulnerability maps were produced by using GIS techniques and applying the “generic” and “agricultural” models according to the DRASTIC charter. Resulting maps revealed that the aquifer is highly vulnerable in the western part of the basin and areas being under high contamination risk are more extensive when the “agricultural” model was applied.

  6. Assessing the correlation between anaerobic toluene degradation activity and bssA concentrations in hydrocarbon-contaminated aquifer material.

    Science.gov (United States)

    Kazy, Sufia K; Monier, Amy L; Alvarez, Pedro J J

    2010-09-01

    The assessment of biodegradation activity in contaminated aquifers is critical to demonstrate the performance of bioremediation and natural attenuation and to parameterize models of contaminant plume dynamics. Real time quantitative PCR (qPCR) was used to target the catabolic bssA gene (coding for benzylsuccinate synthase) and a 16S rDNA phylogenetic gene (for total Bacteria) as potential biomarkers to infer on anaerobic toluene degradation rates. A significant correlation (P = 0.0003) was found over a wide range of initial toluene concentrations (1-100 mg/l) between toluene degradation rates and bssA concentrations in anaerobic microcosms prepared with aquifer material from a hydrocarbon contaminated site. In contrast, the correlation between toluene degradation activity and total Bacteria concentrations was not significant (P = 0.1125). This suggests that qPCR targeting of functional genes might offer a simple approach to estimate in situ biodegradation activity, which would enhance site investigation and modeling of natural attenuation at hydrocarbon-contaminated sites. PMID:20204467

  7. Uranium isotopes as natural pollutants in Brazilian aquifers

    International Nuclear Information System (INIS)

    Groundwater samples from springs and wells belonging to several aquifers at Aguas da Prata, Aguas de Lindoia and Rio Claro cities in Sao Paulo State, southeast region of Brazil, were collected to evaluate if the mechanisms related to the dissolution of the unstable isotopes 238U and and 234U can generate concentrations to the liquid phase greater than the national standard of 20 μgl for total uranium. In spite of the studied hydrologic environments do not indicate contamination of the waters due to the presence of these nuclides, the results showed that the contribution of 234U is very important to the radioactivity due to total uranium in the waters, because values as high as 92% are attained in some cases. (author). 30 refs, 6 figs, 2 tabs

  8. Vulnerability and Pollution Risks in the Alluvial Aquifer of Tebessa-Morsott

    Directory of Open Access Journals (Sweden)

    S. Kachi

    2007-01-01

    Full Text Available We studied the vulnerability and risks of pollution of the alluvial aquifer of Tebessa-Morsott that ranks amongst the major groundwater reservoirs of the region. The method used to asses groundwater vulnerability was the DRASTIC method, based on seven parameters that affect and control the groundwater flow: Depth to groundwater, Impact of the unsaturated zone, net recharge, aquifer media, hydraulic conductivity, soil media, topography. These parameters were obtained from data field, synthetic maps relative to the area considered and then identified within each cell after discretization of the studied area in regular square cells. For each cell, DRASTIC rating for each parameter was multiplied by the DRASTIC weight for that cell and summed to determine the DRASTIC index. A detailed vulnerability map was obtained, showing four classes of potential pollution of the aquifer. Check analysis of the quality of groundwater within these zones are carried out in order to assess the risks of contamination. Pollution by nitrates occurs especially in the wells of low depth, but also in certain drillings for drinking water, whereas bacteriological pollution is observed only in the domestic wells.

  9. Removal of pollutants from pulp and paper mill effluent by anaerobic and aerobic treatment in pilot scale bioreactor

    DEFF Research Database (Denmark)

    Singh, P.; Katiyar, D.; Gupta, M.;

    2011-01-01

    Pilot-scale anaerobic and aerobic treatment in a two-step bioreactor was performed for the removal of pollutants from pulp and paper mill effluent. After seven days of anaerobic treatment, colour (45%), lignin (60%), COD (26%) and adsorbable organic halogen (AOX) (20%) were reduced. The...

  10. Aquifers

    Data.gov (United States)

    Earth Data Analysis Center, University of New Mexico — This map layer contains the shallowest principal aquifers of the conterminous United States, Hawaii, Puerto Rico, and the U.S. Virgin Islands, portrayed as...

  11. Isotope-hydrological and hydrochemical study to investigate the penetration of pollution into a deep aquifer

    International Nuclear Information System (INIS)

    Within the city area of Munich the Younger Tertiary aquifer of the Obere Suesswassermolasse (OSM) is rich in water and is tapped by numerous wells reaching down to depths of about 250 m. The deep groundwater generally has the quality of drinking water and is used directly, for instance, by the food industry and as a public emergency water supply. The groundwater in the overlying Quaternary aquifer has become increasingly polluted. The groundwater in the deeper aquifer is more or less separated from the Quaternary gravels by a low-permeable clay and silt layer up to 40 m thick, which contains intermediate sand lenses. Within the city area of Munich the groundwater of the younger Tertiary aquifer is predominantly recharged by leakage through this layer from the Quaternary aquifer due to depression of the groundwater table caused by pumping. Combined isotope-hydrological and hydrochemical investigations were performed and, taking into account the hydrogeological and hydraulic conditions, used to clarify to what extent the clay and silt layer is able to protect the underlying aquifer from penetration of pollutants with different physical and chemical properties, in particular chlorinated hydrocarbons. Water samples were taken, in some cases repeatedly, from about 50 wells tapping the shallow and deep groundwater aquifer in selected sub-areas of the city of Munich, and the concentrations of 2H, 3H, 18O, 13C, 14C, and in some cases 3He, were measured, together with the usual hydrochemical parameters and concentrations of chlorinated hydrocarbons. The analyses of environmental isotopes made it possible to classify the sampling points with respect to the mean residence time of the groundwater. An attempt was also made to correlate the dispersal of pollutants in the Younger Tertiary aquifer with the residence time. The results obtained show that under hydraulic stress of the aquifer young tritium-containing groundwater has in general penetrated down to depths not greater

  12. Behavior of pollutant-degrading microorganisms in aquifers: Predictions for genetically engineered organisms

    Science.gov (United States)

    Krumme, M.L.; Smith, R.L.; Egestorff, J.; Thiem, S.M.; Tiedje, J.M.; Timmis, K.N.; Dwyer, D.F.

    1994-01-01

    Bioremediation via environmental introductions of degradative microorganisms requires that the microbes survive in substantial numbers and effect an increase in the rate and extent of pollutant removal. Combined field and microcosm studies were used to assess these abilities for laboratory-grown bacteria. Following introduction into a contaminated aquifer, viable cells of Pseudomonas sp. B13 were present in the contaminant plume for 447 days; die-off was rapid in pristine areas. In aquifer microcosms, survival of B13 and FR120, a genetically engineered derivative of B13 having enhanced catabolic capabilities for substituted aromatics, was comparable to B13 field results; both bacteria degraded target pollutants in microcosms made with aquifer samples from the aerobic zone of the pollutant plume. Results suggest that field studies with nonrecombinant microorganisms may be coupled to laboratory studies with derivative strains to estimate their bioremediative efficacy. Furthermore, laboratory strains of bacteria can survive for extended periods of time in nature and thus may have important bioremediative applications. ?? 1994 American Chemical Society.

  13. Concurrent nitrate and Fe(III) reduction during anaerobic biodegradation of phenols in a sandstone aquifer

    DEFF Research Database (Denmark)

    Broholm, Mette; Crouzet, C.; Arvin, Erik; Mouvet, C.

    levels relevant for degradation of specific organic compounds in aquifers, cannot always be obtained. Hence, complete mass balances of electron acceptor consumption fur specific organic compounds degradation are difficult to confine. For aquifer materials with low initial Fe(II) content, Fe......(II) determinations on solids and in aqueous phase samples may provide valuable information on Fe(III) reduction. However, in microcosms with natural sediments and where electron acceptors are associated with the sediments, complete mass-balances for substrates and electron accepters are not likely to be obtained. (C...

  14. Characterization of Predominant Reductants in an Anaerobic Leachate-Contaminated Aquifer by Nitroaromatic Probe Compounds

    DEFF Research Database (Denmark)

    Rügge, Kirsten; Hofstetter, Thomas B.; Haderlein, Stefan B.;

    1998-01-01

    landfill leachate plume of a sandy aquifer. Results of field experiments (continuous injection and in situ microcosms) were compared to the findings of laboratory batch and column experiments (using aquifer matrix and model systems for sulfate-and iron-reducing conditions). NACs were transformed within 2......-70 days in the leachate plume as well as in microbially active and in microbially deactivated experiments. Generally, aromatic amines were the predominant reduction products, and these compounds were stable within the time frame and under the conditions of our experiments. Despite the presence of various...

  15. Relationships between microbial community structure and hydrochemistry in a landfill leachate-polluted aquifer.

    Science.gov (United States)

    Röling, W F; van Breukelen, B M; Braster, M; Lin, B; van Verseveld, H W

    2001-10-01

    Knowledge about the relationship between microbial community structure and hydrogeochemistry (e.g., pollution, redox and degradation processes) in landfill leachate-polluted aquifers is required to develop tools for predicting and monitoring natural attenuation. In this study analyses of pollutant and redox chemistry were conducted in parallel with culture-independent profiling of microbial communities present in a well-defined aquifer (Banisveld, The Netherlands). Degradation of organic contaminants occurred under iron-reducing conditions in the plume of pollution, while upstream of the landfill and above the plume denitrification was the dominant redox process. Beneath the plume iron reduction occurred. Numerical comparison of 16S ribosomal DNA (rDNA)-based denaturing gradient gel electrophoresis (DGGE) profiles of Bacteria and Archaea in 29 groundwater samples revealed a clear difference between the microbial community structures inside and outside the contaminant plume. A similar relationship was not evident in sediment samples. DGGE data were supported by sequencing cloned 16S rDNA. Upstream of the landfill members of the beta subclass of the class Proteobacteria (beta-proteobacteria) dominated. This group was not encountered beneath the landfill, where gram-positive bacteria dominated. Further downstream the contribution of gram-positive bacteria to the clone library decreased, while the contribution of delta-proteobacteria strongly increased and beta-proteobacteria reappeared. The beta-proteobacteria (Acidovorax, Rhodoferax) differed considerably from those found upstream (Gallionella, Azoarcus). Direct comparisons of cloned 16S rDNA with bands in DGGE profiles revealed that the data from each analysis were comparable. A relationship was observed between the dominant redox processes and the bacteria identified. In the iron-reducing plume members of the family Geobacteraceae made a strong contribution to the microbial communities. Because the only known

  16. Analysis of arsenic pollution in groundwater aquifers by X-ray fluorescence

    International Nuclear Information System (INIS)

    The serious contamination of groundwater in the southeastern plain of the province of Cordoba (Argentina), a phenomenon mentioned in the literature for over 80 years, has given rise to this initial hydrologic study covering an area over 250 km2. This study analyzes a rural area near a little town called La Francia, and is motivated by the existence of an important pollution with arsenic in the first-aquifer groundwater of the region. This phenomenon has been mentioned for a long time and evidenced by the high incidence of diseases associated with this element in the local population. By means of the X-ray fluorescence (XRF) technique, and using an energy-dispersive spectrometer, 50 samples of groundwater of the rural zone of La Francia from about 100 m deep (second aquifer), were analyzed. The samples were excited with a 3 kW X-ray tube and measured using a reflecting geometry with 45 deg. of incident and take-off directions. Preconcentration techniques for the preparation of the samples were employed in order to obtain an adequate signal-to-noise ratio. The As concentration in water was obtained using calibration curves and the internal standard method for quantification. A high percentage of the analyzed samples showed concentrations lesser than or equal to 0.05 mg l-1. This value corresponds to the maximum pollutant level for humans. The maximum measured value reaches 3 mg l-1 in samples collected in perforations of first-aquifer wells and in some second-aquifer isolated wells

  17. Pollution Vulnerability Assessment of Aquifers Overlain By Glacial Sediment Using Electrical Methods

    Science.gov (United States)

    Kilner, M. D.; West, L. J.; Murray, T.

    The vulnerability of confined aquifers to pollution from sources at the surface depends on the permeability of overlying units. Permeable units such as sand and gravel will provide potential pathways for contaminants to enter the aquifer whereas impermeable units such as clay will retard their movement and hence provide some protection to the aquifer. Aquifer vulnerability assessment in the UK is largely based upon data from boreholes drilled for well installation. However, in areas where the geology of the confining layer is relatively complex (e.g. glacial sequences) aquifer vulnerability is often poorly constrained due to insufficient borehole coverage. Reported here is an investigation of the potential for using geophysical techniques such as resistivity to support improved aquifer vulnerability assessment in such areas. In the area of Holderness, East Yorkshire, UK, glacially derived sediment deposited during the late Devensian (10,000 years BP.) overlies the Cretaceous Chalk, which is the most important groundwater resource in the UK. Despite 5 to 30m of glacial cover being present, there are several examples where large borehole abstractions have been closed down because very minor activities (e.g. coffer dam construction, hedge re- moval) have led to rapid surface water ingress and consequent bacterial contamination of the Chalk. Borehole records from the area have highlighted heterogeneity within the glacial sediment on a sub decametre scale in ice-marginal deposits. Boreholes can not hope to map such heterogeneity throughout Holderness, so the potential of resistivity techniques (profiling and EM31) to provide the spatial resolution required to identify such features has been investigated by forward modelling. Different geological bod- ies with a range of geophysical parameters and electrode configurations were input into RES2DMOD (Loke, 1996) and suitable parameters to use in field trials identi- fied. Subsequent trials over an area of good geological

  18. Assessing agriculture pollution in the Beja aquifer using nitrogen isotopes (South Portugal)

    International Nuclear Information System (INIS)

    This paper intends to give scientific support for political decisions, considering the sustainable development of rural regions under semiarid conditions exploiting shallow aquifers, and promote appropriate use of nitrogen fertilizers, based on EC Water Framework Directive and EC Groundwater Framework Directive in the context of vulnerable aquifers. Stable nitrogen isotopes (15N/14N ratios) can offer a direct way to identify the pollutant sources in groundwater systems. In the research area two major sources of nitrate were identified in agricultural areas, fertilizer and manure, which present different isotopic δ15N signatures. The relative contributions of these two sources to groundwater or surface water can be estimated by mass balance. The analysis of nitrate δ18O together with δ15N improves the ability to trace nitrate sources and cycling. According to field practice in the rural area of Beja, major cause of pollution comes from fertilizers. Isotope results are not conclusive about the possibility that major source of nitrate-N in groundwater comes from agriculture as expected. Further work is required regarding seasonality sampling and laboratory techniques with sufficient accuracy. (author)

  19. Numerical Simulation of the Anaerobic Transformation of Tetrachloroethene to cis-Dichloroethene in a Continuous Flow Aquifer Column

    Science.gov (United States)

    Mustafa, N.; Azizian, M.; Dolan, M.; Semprini, L.

    2007-12-01

    The anaerobic reductive dechlorination of tetrachloroethene (PCE) to cis-dichloroethene (c-DCE) in a laboratory column study was numerically simulated and compared with experimental observations. The column study was conducted with continuous flow and injection of PCE in synthetic groundwater. The column was packed with aquifer solids from the Hanford DOE site and bioaugmented with the Evanite (EV) dechlorinating enrichment culture. After the column was bioaugmented and fed lactate as an electron donor, c-DCE concentrations in the column effluent exceeded the influent PCE concentration. This high c-DCE concentration resulted from enhanced PCE desorption and transformation. A 1-D reactive transport model was developed that included the processes of dispersion, advection, rate-limited sorption and desorption, reductive dechlorination kinetics with competitive inhibition and microbial growth and decay. The model was validated by mass balances, comparisons with analytical solutions and batch kinetic models. Previously determined kinetic and inhibition constants for the EV culture of Yu and Semprini (2004) were input into the model simulations. Initial biomass concentration was assumed to be exponentially distributed along the column. The sorption parameters including the aquifer: water distribution coefficients (Kds) and first-order mass transfer coefficients for PCE, trichloroethene (TCE), and c-DCE were determined in batch laboratory studies. The system of model equations was solved numerically using COMSOL 3.3, which employs finite-element methods. The reactive transport model successfully simulated the initial results of continuous flow column experiment. The increase in c-DCE above the influent PCE concentration was simulated and TCE was shown not to accumulate in the column effluent. The simulations showed that microbial kinetic values generated in previous studies and the sorption parameters generated in batch tests, when used in a transport model, did a

  20. A two-stage anaerobic system for biodegrading wastewater containing terephthalic acid and high strength easily degradable pollutants

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    The high strength easily biodegradable pollutants(represented by CODE) are strong inhibitors of terephthalic acid(TA) anaerobic biodegradation. At the same time, TA can inhibiteasily biodegradable pollutants removal under anaerobic conditionsto a limited extent. This mutual inhibition could happen and causea low removal efficiency of both TA and CODE, when the effluentfrom TA workshops containing TA and easily biodegradable pollutantsare treated by a single anaerobic reactor system. Based upon thetreatment kinetics analysis of both TA degradation and CODEremoval, a two-stage up-flow anaerobic sludge blanket and up-flowfixed film reactor(UASB-UAFF) system for dealing with this kind ofwastewater was developed and run successfully at laboratory scale.An UASB reactor with the methanogenic consortium as the first stageremoves the easily biodegradable pollutants(CODE). An UAFF reactor as the second stage is mainly in charge of TA degradation. At aHRT 18.5h, the CODE and TA removal rate of the system reached 89.2% and 71.6%, respectively.

  1. Impact of Sediment-Bound Iron on Redox Buffering in a Landfill Leachate Polluted Aquifer (Vejen, Denmark)

    DEFF Research Database (Denmark)

    Heron, Gorm; Christensen, Thomas Højlund

    1995-01-01

    Sediments sampled along a central flow line of the leachate pollution plume at the Vejen Landfill, Denmark, were characterized in detail with respect to the forms and pools of Fe(ll) and Fe(lll). After 15 yr of leaching, redox reactions had diminished the pool of iron(ll1) oxides and hydroxides in...... amounts of Fe(ll). This study presents evidence of substantial iron reduction buffering the reducing power of landfill leachate entering a shallow aquifer. It is also proposed that reduced sedimentbound iron species form in the plume, thereby increasing the need for oxygen if the aquifer was to be...

  2. Regression Models for Aquifer Vulnerability to Nitrate Pollution in Osona (NE Spain)

    Science.gov (United States)

    Boy Roura, M.; Nolan, B. T.; Menció Domingo, A.; Mas-Pla, J.

    2012-12-01

    Regression models were developed at a local scale in the Osona region (1,260 square kilometers) to predict nitrate concentrations in groundwater. Osona is a semi-arid region in northeast Spain, where livestock and agricultural activities are very intensive, and therefore, it is vulnerable to nitrate pollution from agricultural sources (European Nitrate Directive (91/676/EEC)). Nitrate concentrations in groundwater are commonly above 50 mg/L as nitrate, reaching up to 500 mg/L in some of the sampled wells. Regression models were based on explanatory variables such as geology, land use, and nitrogen inputs, which control the fate, transport and attenuation of nitrate in groundwater. Regression has been widely used to determine aquifer vulnerability to nitrate in groundwater at large spatial scales. We developed models with and without site-specific groundwater chemistry data to see the extent to which the latter improved the models. Although chemistry data could explain additional variation in groundwater nitrate concentration, such data were available only at the well locations and therefore were less amenable for spatial extrapolation. The data set consisted of nitrate data from 63 sampled wells and the following explanatory variables: 1) soils data consisting of texture and other physical properties; 2) geology indicating presence or absence of aquifers in the region, and their type (unconfined, leaky or confined); 3) land use (agricultural, urban, forested); 4) nitrogen input as manure; 5) occurrence of irrigated crops; 6) estimates of nitrogen uptake developed for 10 different crops; 7) slope; 8) population density, and 9) groundwater chemistry data comprising major ions and trace elements. Variables 1 and 2 were compiled as point data because their polygons were much larger than the well buffers which represented contributing areas to the sampled wells. Variables 3 to 8 were compiled within a 500-meter radius buffer around wells using a GIS-based weighted

  3. MICROBIAL ECOLOGY OF A SHALLOW UNCONFINED GROUND WATER AQUIFER POLLUTED BY MUNICIPAL LANDFILL LEACHATE

    Science.gov (United States)

    The microflora of a shallow anoxic aquifer underlying a municipal landfill In Oklahoma was characterized by direct light microscopy, most probable number of determinations of sulfate reducers and methanogens, and measurements of methanogenesis in aquifer samples containing either...

  4. Prediction of pollution into ore bearing aquifer from ISL-site

    International Nuclear Information System (INIS)

    Outcomes of present mineralogical investigations explain some phenomena observed in previous sorption experiences. First of all they elucidate cutback of filtration coefficients of sediments exposed under pollution process as granulometric fractions of these permeable sediments decreased in its weight ratio in according to impermeable ones. Then sorption graphics are explained by chemical and mineralogical changes in experienced substance. Explores made diagnoses and estimation about 45 authigenous and technogenous minerals playing the essential role in the process of mass transfer of uranium and polluted components in ISL-sites. They are considered in all basic fractions of studied sediments. Bright peculiarities are noticed for gravel and coarse sands, which went to pieces as a result of dilution or decomposition of its cement. Mineral composition of clayey fraction also significantly changed after pollution process. Steep lost of weight of fraction 0.005-0.001mm consisted with partial decomposition of clayey minerals basically of montmorillonite. These investigations show also that ones of the main minerals playing such the essential role are sorptive such as silica, silica gel, common opal, opal-CT, noble opal, allophane, montmorillonite and zeolite minerals. In conclusion the given work shows some filtration properties of aquifer in an ISL-site and predicts the spread of a possible pollution for ISL-site to environment. The extension of pollution could be more one-two dimension of affected by ISL-process. The prediction would be exact if the previous investigation included the desorptive characteristics and sorptive data depending on temperature and pressure. Current investigations continued pervious ones after which some inexplicable matters of migration of contaminated halo from an ISL-polygon are as follows: Identification and specification of all minerals outside ISL-polygon; Calculation of mineral balance for contaminated sites; Specification of flow

  5. Multiobjective optimization for Groundwater Nitrate Pollution Control. Application to El Salobral-Los Llanos aquifer (Spain).

    Science.gov (United States)

    Llopis-Albert, C.; Peña-Haro, S.; Pulido-Velazquez, M.; Molina, J.

    2012-04-01

    Water quality management is complex due to the inter-relations between socio-political, environmental and economic constraints and objectives. In order to choose an appropriate policy to reduce nitrate pollution in groundwater it is necessary to consider different objectives, often in conflict. In this paper, a hydro-economic modeling framework, based on a non-linear optimization(CONOPT) technique, which embeds simulation of groundwater mass transport through concentration response matrices, is used to study optimal policies for groundwater nitrate pollution control under different objectives and constraints. Three objectives were considered: recovery time (for meeting the environmental standards, as required by the EU Water Framework Directive and Groundwater Directive), maximum nitrate concentration in groundwater, and net benefits in agriculture. Another criterion was added: the reliability of meeting the nitrate concentration standards. The approach allows deriving the trade-offs between the reliability of meeting the standard, the net benefits from agricultural production and the recovery time. Two different policies were considered: spatially distributed fertilizer standards or quotas (obtained through multi-objective optimization) and fertilizer prices. The multi-objective analysis allows to compare the achievement of the different policies, Pareto fronts (or efficiency frontiers) and tradeoffs for the set of mutually conflicting objectives. The constraint method is applied to generate the set of non-dominated solutions. The multi-objective framework can be used to design groundwater management policies taking into consideration different stakeholders' interests (e.g., policy makers, agricultures or environmental groups). The methodology was applied to the El Salobral-Los Llanos aquifer in Spain. Over the past 30 years the area has undertaken a significant socioeconomic development, mainly due to the intensive groundwater use for irrigated crops, which has

  6. Attenuation of landfill leachate by UK Triassic sandstone aquifer materials. 2. Sorption and degradation of organic pollutants in laboratory columns

    Science.gov (United States)

    Thornton, Steven F.; Bright, Mildred I.; Lerner, David N.; Tellam, John H.

    2000-05-01

    The sorption and degradation of dissolved organic matter (DOM) and 13 organic micropollutants (BTEX, aromatic hydrocarbons, chloro-aromatic and -aliphatic compounds, and pesticides) in acetogenic and methanogenic landfill leachate was studied in laboratory columns containing Triassic sandstone aquifer materials from the English Midlands. Solute sorption and degradation relationships were evaluated using a simple transport model. Relative to predictions, micropollutant sorption was decreased up to eightfold in acetogenic leachate, but increased up to sixfold in methanogenic leachate. This behaviour reflects a combination of interactions between the micropollutants, leachate DOM and aquifer mineral fraction. Sorption of DOM was not significant. Degradation of organic fractions occurred under Mn-reducing and SO 4-reducing conditions. Degradation of some micropollutants occurred exclusively under Mn-reducing conditions. DOM and benzene were not significantly degraded under the conditions and time span (up to 280 days) of the experiments. Most micropollutants were degraded immediately or after a lag phase (32-115 days). Micropollutant degradation rates varied considerably (half-lives of 8 to >2000 days) for the same compounds (e.g., TeCE) in different experiments, and for compounds (e.g., naphthalene, DCB and TeCA) within the same experiment. Degradation of many micropollutants was both simultaneous and sequential, and inhibited by the utilisation of different substrates. This mechanism, in combination with lag phases, controls micropollutant degradation potential in these systems more than the degradation rate. These aquifer materials have a potentially large capacity for in situ bioremediation of organic pollutants in landfill leachate and significant degradation may occur in the Mn-reducing zones of leachate plumes. However, degradation of organic pollutants in acetogenic leachate may be limited in aquifers with low pH buffering capacity and reducible Mn oxides

  7. Comparison of policies for controlling groundwater nitrate pollution from agriculture in the Eastern Mancha aquifer (Spain).

    Science.gov (United States)

    Peña-Haro, S.; Llopis-Albert, C.; Pulido-Velazquez, M.; Stalder, A.; Garcia-Prats, A.; Henriquez-Dole, L.

    2012-04-01

    Groundwater nitrate pollution from agriculture has given rise to different legal frameworks. The European Water Framework Directive (WFD) is the most recent one. This work aims to help in the definition of the most cost-efficient policy to control non-point groundwater to attain the objectives established in the WFD. In this study we performed a cost-effectiveness analysis of different policies for controlling groundwater nitrate pollution from agriculture. The policies considered were taxes on nitrogen fertilizers, water price, taxes on emissions and fertilizer standards. We used a hydro-economic model, where we maximized the farmer's benefits. The benefits were calculated as sum of crop revenue minus variable and fixed cost per hectare minus the damage costs from nitrogen leaching. In the cost-effectiveness analysis we considered the costs as the reduction on benefits due to the application of a policy and the effectiveness the reduction on nitrate leaching. The methodology was applied to Eastern Mancha aquifer in Spain. The aquifer is part of the Júcar River Basin, which was declared as EU Pilot Basin in 2002 for the implementation of the WFD. Over the past 30 years the area has undertaken a significant socioeconomic development, mainly due to the intensive groundwater use for irrigated crops, which has provoked a steady decline of groundwater levels and a reduction of groundwater discharged into the Júcar River, as well as nitrate concentrations higher than those allowed by the WFD at certain locations (above 100 mg/l.). Crop revenue was calculated using production functions and the amount of nitrate leached was estimated by calibrated leaching functions. These functions were obtained by using an agronomic model (a GIS version of EPIC, GEPIC), and they depend on the water and the fertilizer use. The Eastern Mancha System was divided into zones of homogeneous crop production and nitrate leaching properties. Given the different soil types and climatic

  8. Determining the source of nitrate pollution in the Niger discontinuous aquifers using the natural {15N }/{14N } ratios

    Science.gov (United States)

    Girard, Pierre; Hillaire-Marcel, Claude

    1997-12-01

    In the semi-arid Niamey area (Niger), more than 10% of the deep wells exploiting the fracture network of the Precambrian aquifer are contaminated by nitrates, with concentrations as high as 10 meq l -1. In order to identify the source(s) of this pollution, nitrate and 15N contents in the polluted wells were monitored over a 20-month period. Potential sources of nitrate contamination were also analyzed for their 15N content. The isotopic compositions of nitrate in polluted waters were > + 12‰ and in rare cases exceeded +17‰. Latrines (˜ + 15‰) may be the major nitrate source for wells showing δ15N values above +15‰. Below this value, waters may be polluted by a combination of nitrates from both latrine and soil sources (˜ + 10‰). In some cases, the soil may account for up to 85% of the groundwater nitrate load. This mode of groundwater pollution is thought to be a consequence of deforestation. Despite their reputation as polluting agents, fertilizers ( +0.5 < δ 15N < + 3.6‰ ) which are used in rice paddies close to the contaminated areas, do not appear to be a significant source of nitrate contamination. Denitrification is probably not a significant process in the study area. Results suggest that nitrate contamination of the aquifer is a consequence of unregulated urbanization (home-made latrines) and deforestation. While latrines are limited to the urban zones, intensive cutting of the forest to meet the city dwellers' wood demand occurs in an ever increasing area around the capital, threatening the local water supply.

  9. Correlating phospholipid fatty acids (PLFA) in a landfill leachate polluted aquifer with biogeochemical factors by multivariate statistical methods

    DEFF Research Database (Denmark)

    Ludvigsen, Liselotte; Albrechtsen, Hans-Jørgen; Rootzén, Helle; Christensen, Thomas Højlund

    Different multivariate statistical analyses were applied to phospholipid fatty acids representing the biomass composition and to different biogeochemical parameters measured in 37 samples from a landfill contaminated aquifer at Grindsted Landfill (Denmark). Principal component analysis and...... correspondence analysis were used to identify groups of samples showing similar patterns with respect to biogeochemical variables and phospholipid fatty acid composition. The principal component analysis revealed that for the biogeochemical parameters the first principal component was linked to the pollution...... acids, different groups of samples and outliers were revealed by the principal component analysis. The principal component analysis on data in absolute concentrations revealed that many phospholipid fatty acids reflected the pollution effect on the biomass composition. In contrast, the phospholipid...

  10. The diffusion of buried matter and possible pollution of aquifers in presence of hydrodynamic dispersion

    International Nuclear Information System (INIS)

    The problem of diffusion of buried waste in a moist soil is formulated in cylindrical coordinates and solved by means of integral transform techniques after appropriate asymptotic approximations. The model is then used to predict the possible contamination of aquifers situated at a given depth. (author). 2 refs, 2 figs

  11. Geomicrobial and Geochemical Redox Processes in a Landfill-Polluted Aquifer

    DEFF Research Database (Denmark)

    Ludvigsen, Liselotte; Heron, Gorm; Albrechtsen, Hans-Jørgen; Christensen, Thomas Højlund

    landfill. Sulfate-reducing bacteria and sulfate reduction were observed in the area where methanogenesis took place, but were also observed further downgradient in the leachate plume. Fe(III)-reducing bacteria were found in almost all samples from the entire anaerobic leachate plume, but no ongoing Fe...

  12. Assessing the cost of groundwater pollution: the case of diffuse agricultural pollution in the Upper Rhine valley aquifer.

    Science.gov (United States)

    Rinaudo, J-D; Arnal, C; Blanchin, R; Elsass, P; Meilhac, A; Loubier, S

    2005-01-01

    This paper presents an assessment of the costs of diffuse groundwater pollution by nitrates and pesticides for the industrial and the drinking water sectors in the Upper Rhine valley, France. Pollution costs which occurred between 1988 and 2002 are described and assessed using the avoidance cost method. Geo-statistical methods (kriging) are then used to construct three scenarios of nitrate concentration evolution. The economic consequences of each scenario are then assessed. The estimates obtained are compared with the results of a contingent valuation study carried out in the same study area ten years earlier. PMID:16445184

  13. Anaerobic cleanup of waste water with a high organic and inorganic pollutant burden by separate acidification and methanization

    International Nuclear Information System (INIS)

    The cleaning of heavily polluted waste water was studied in a two-stage test set-up using distiller's wash. The two stages consisted of a pulsed bioreactor each for anaerobic treatment of immobilized biomass. In the first reactor, organic compounds of high molecular weight are converted into fatty acids of low molecular weight; in the second reactor they are degraded into biogas. At the same time, nitrogen compounds are reduced to ammonium and sulfur compounds to sulfides. The conversion rate of organic pollutants was found to deteriorate considerably in the presence of ammonium-nitrogen concentrations of 1.5 kg NH4+-N/m3 or higher and sulfide concentrations of 0.1 kg S2--S/m3 or higher. Given a retention time of 30 hours, some 90% of degradable organic pollutants can be removed from waste water in the second bioreactor. The course of the degradation process was monitored by determining the proportion of the individual low-molecular-weight fatty acids and different sum parameters. Records were also kept of the quantity and composition of the biogas produced by the two reactors. (orig.). 48 figs., 4 tabs

  14. Nitrogen-isotope analysis of groundwater nitrate in carbonate aquifers: Natural sources versus human pollution

    Science.gov (United States)

    Kreitler, Charles W.; Browning, Lawrence A.

    1983-02-01

    Results of nitrogen-isotope analyses of nitrate in the waters of the Cretaceous Edwards aquifer in Texas, U.S.A., indicate that the source of the nitrate is naturally-occurring nitrogen compounds in the recharge streams. In contrast, nitrogen isotopes of nitrate in the fresh waters of the Pleistocene Ironshore Formation on Grand Cayman Island, West Indies, indicate that human wastes are the source of the nitrate. The Cretaceous Edwards Limestone is a prolific aquifer that produces principally from fracture porosity along the Balcones Fault Zone. Recharge is primarily by streams crossing the fault zone. Rainfall is ˜ 70 cm yr. -1, and the water table is generally deeper than 30 m below land surface. The δ15 N of 73 samples of nitrate from Edwards waters ranged from + 1.9 to + 10‰ with an average of + 6.2‰. This δ15 N range is within the range of nitrate in surface water in the recharge streams ( δ 15N range = + 1 to + 8.3‰ ) and within the range of nitrate in surface water from the Colorado River, Texas, ( δ 15N range = + 1 to + 11‰ ). No sample was found to be enriched in 15N, which would suggest the presence of nitrate from animal waste ( δ 15N range = + 10 to + 22‰ ). The Ironshore Formation contains a small freshwater lens that is recharged entirely by percolation through the soil. Average rainfall is 165 cm yr. -1, and the water table is within 3 m of land surface. The δ15 N of four nitrate samples from water samples of the Ironshore Formation ranged from + 18 to + 23.9‰, which indicates a cesspool/septictank source of the nitrate. Limestone aquifers in humid environments that are recharged by percolation through the soil appear to be more susceptible to contamination by septic tanks than are aquifers in subhumid environments that feature thick unsaturated sections and are recharged by streams.

  15. Simulation of the transfer of organochlorine pollutants in an alluvial aquifer in an alpine valley: the case of tetrachloroethene

    Science.gov (United States)

    Kouamé, A. A.; Jaboyedoff, M.; Tacher, L.; Derron, M.-H.

    2012-04-01

    During a series of environmental analysis carried out in soil and groundwater in the Alpine Valley (Rhone valley Western Switzerland), were identified high levels of chlorinated solvents, particularly the tetrachloroethene. The leakage of this pollutant originates from industry. The geological substratum in this part of the valley is mainly composed of alluvial deposits and the deposit of a large rock avalanche. The sediments are composed of sandy silt, sandy clay, sand and gravel. The rock avalanche deposit which is the wall of the alluvial aquifer consists of fine materials, stones and large debris mainly of limestone. The investigations developed in this area have shown the presence of a contaminant plume of 60 m long and 35 m wide approximately. Thus the technique of venting / sparging was proposed as remediation measure. Despite the effectiveness of this technique, it turns out that there are still some pockets of contamination of groundwater in the area. In order to assess the potential pollution, a numerical modeling was developed by using the Visual Modflow software. The stages of this modeling are: • Selecting the parameters of the models; • Developing conceptual and numerical models; • Calibration and validation of the model; • Reproducing the observed concentrations; • Sensitivity analysis; • Making a parametric study to see at different stages the tetrachloroethene plume. The first results of the simulation show a slow leakage of the pollutant forming a pocket in the water flow direction.

  16. Contribution of the isotopic study of nitrogen to the knowledge of the pollution of underground aquifers by nitrates, in agricultural environment (Brie, Beauce - France)

    International Nuclear Information System (INIS)

    Isotope composition of nitrate nitrogen from aquifers in the highly cultivated areas from Brie and Beauce show three different nitrogen inputs: nitrate from organic matter in soils; nitrate from fertilizers; nitrate from domestic and animal wastes. The isotope composition of those stocks are different enough to trace their origin and establish material balances of nitrogen pollution

  17. Concept of Compound Retention Time for Organic Micro Pollutants in Anaerobic Membrane Bioreactor with Nanofiltration

    KAUST Repository

    Pan, Jiangjiang

    2011-12-01

    Organic micropollutants (OMPs) have received more and more attention in recent years due to their potential harmful effects on public health and aquatic ecosystems, and eliminating OMPs in wastewater treatment systems is an important solution to control OMPs wastage. An innovative hybrid process, anaerobic membrane bioreactor with nanofiltration (AnMBR-NF), in which enhanced OMPs removal is possible based on the concept of compound retention time (CRT) through coupling anaerobic biodegradation and NF rejection, is proposed and examined in terms of preliminary feasibility in this study. First, NF membrane screening through sludge water dead-end filtration tests demonstrated that KOCH NF200 (molecular weight cut-off (MWCO) 200 Da, acid/base stable) performed best in organic matter rejection. Then, selected OMPs (ketobrofen and naproxen) in MQ water and a biologically treated wastewater matrix were filtered through NF200 under constant-pressure dead-end mode, with and without stirring, and several methods (contact angle, scanning electronic microscopy, Zeta potential, Fourier transform infra-red spectroscopy) were used to characterize membranes. Results show selected OMPs in MQ could be rejected (about 40%) by a clean NF200 membrane. The main rejection mechanism was initial absorption by the membrane followed by size exclusion (electric charge interaction plays a less important role). The wastewater matrix could enhance the rejection significantly (up to 90%) because effluent organic matter (EfOM) enhanced size exclusion and electric charge interaction through blocking membrane pores and forming a gel layer as well as binding some OMPs through partitioning followed by retention by NF. Third, an anaerobic bioreactor was set up to evaluate the anaerobic biodegradability of selected OMPs. Results showed selected OMPs could be absorbed by sludge and reached equilibrium within one day, and then were consumed by anaerobic microorganism with a half life 9.4 days for

  18. Correlating phospholipid fatty acids (PLFA) in a landfill leachate polluted aquifer with biogeochemical factors by multivariate statistical methods

    DEFF Research Database (Denmark)

    Ludvigsen, Liselotte; Albrechtsen, Hans-Jørgen; Rootzén, Helle;

    1997-01-01

    acids, different groups of samples and outliers were revealed by the principal component analysis. The principal component analysis on data in absolute concentrations revealed that many phospholipid fatty acids reflected the pollution effect on the biomass composition. In contrast, the phospholipid......Different multivariate statistical analyses were applied to phospholipid fatty acids representing the biomass composition and to different biogeochemical parameters measured in 37 samples from a landfill contaminated aquifer at Grindsted Landfill (Denmark). Principal component analysis and...... effect and to redox processes and the second principal component described the geological and geochemical features of the samples. Dependent on the data transformation of the phospholipid fatty acid profiles in either absolute concentrations (logarithm transformed) or in mol% of total phospholipid fatty...

  19. Fast semi-analytical approach to approximate plumes of dissolved redox-reactive pollutants in heterogeneous aquifers. 1. BTEX

    Science.gov (United States)

    Atteia, O.; Höhener, P.

    2012-09-01

    Various numerical reactive transport models were developed in the last decade to simulate plumes of pollutants in heterogeneous aquifers. However, these models remain difficult to use for the non-specialist, and the computation times are often long. Users who need to fit several model parameters to match predictions with field data in heterogeneous aquifers may be discouraged by the time needed to run the simulations. The objective of this paper is to provide a set of approximations that allow performing almost instantaneous calculations for transport of redox-reactive pollutants, the most common examples being benzene, toluene, ethylbenzene and xylenes (BTEX). The approach relies on two major tools: (i) the use of flux tubes (FT), a variant of stream tubes that include dispersion, and (ii) sequential superposition of the reactions (Mixed Instantaneous and Kinetics Superposition Sequence (MIKSS)). The calculation of transport is uncoupled from the calculation of reactions. The superposition principle has been used previously for the analytical solution of a bimolecular reaction of an electron donor with an acceptor and is here extended to more than one dissolved electron acceptor reacting with more than one donor. The approach is furthermore improved by including limitations of the kinetic reactions according to the availability of the reactants and by combining kinetic and instantaneous reactions. The results computed with this approach are compared to three well known numerical models (RT3D, PHT3D, PHAST) for various test cases including uniform, slightly diverted or highly irregular flow fields and several reaction schemes for BTEX. The FT-MIKSS solution gives nearly the same results as the other models and proved to be very flexible. The major advantage of the FT-MIKSS solution is fast computation times that are generally 100 to 1000 times faster than other numerical models. This approach might be a useful tool during the long fitting procedure of field data

  20. Hydrogeological Charateristics and Vulnerability of Pollution of the Aquifer Grdovski Orman Near Kocani

    OpenAIRE

    Mircovski, Vlado

    2012-01-01

    Master thesis is done defining hydrogeological features of the aquifere Grdovski Orman and vulnerability assessment of his pollution based on filtration characteristics of the water bearing and overlay sediments. Also, it was performed determination the groundwater quality. The definition of the hydrogeological features was done on the basis of the data obtained by making several exploitation wells and pollution vulnerability assessment by hydrogeological data and filtration characteristic...

  1. Deep aquifers: last resort water resources in case of major pollution crisis

    International Nuclear Information System (INIS)

    Within the framework of a reflection dealing with the possibility to insure sufficient drinking water supply in case of major crisis, the Ministry of the Environment undertook an inventory of the aquiferous systems on the whole French (continental) territory. In case of a generalized surface water and groundwater contamination, these aquifers could provide substitution water, qualified as 'a last resorted water' because of its temporary - fast definitive - protection statute. A scale of value relative to the protection level was created, which enables the researchers to identify three levels of protection and to draw up a 1/1,500,000 scale map of France, on which the limits of 98 phreatic water-tables, identified as protected, have been reported. The great majority of the aquifers corresponds to confined waters. A statistical analysis on the existence of protected resources reveals that 16 departments out of 96 have got protected resources on the whole territory, and that 22 others haven't got any that are registered at national scale. Otherwise, 61 towns out of 103 which count more that 50,000 inhabitants have got protected resources, which correspond to 61 % of the urban population. In a second time, the cases of the urban centres of Paris and Lyon will be looked into more in detail, stating precisely the protected resources which could be mobilized and the existing collecting equipments which could possibility be integrated in a device used as a last resort. (authors). 3 figs

  2. Utilization of natural variations in the isotopic abundance of 15N to trace the source of aquifer pollution by nitrates

    International Nuclear Information System (INIS)

    The validity of using the natural isotope nitrogen-15 to trace the source of nitrates contained in aquifers is discussed with reference to experimental devices (lysimeters and experimental plots) and for examples chosen from the Paris area. There are a number of sources of nitrates: (1) industrially synthesized nitrates (fertilizers); (2) nitrates produced by oxidation of organic matter associated with human, agricultural or urban activities; (3) nitrates synthesized in the soil by the decay of organic matter. In the examples studied these sources differ in their 15N content: (1) fertilizers have a delta15N close to zero (atmospheric nitrogen); (2) the nitrates originating from organic pollution have high delta15N (above 10-12 per mille) and this 15N enrichment is associated with the volatilization of ammonia during the ammonia stage of mineralization; (3) the isotopic characterization of the nitrates produced by organic matter in the soil is less evident. Citing several examples, the author demonstrates that these three sources are diffentiated isotopically. Consideration of the parameters nitrate concentration/isotopic composition reveals simple mixture curves. In the most complicated cases - where there is association with other isotopic (3H) or chemical parameters - it is possible qualitatively to trace the sources of nitrogen pollution

  3. Point source pollution and variability of nitrate concentrations in water from shallow aquifers

    Science.gov (United States)

    Nemčić-Jurec, Jasna; Jazbec, Anamarija

    2016-01-01

    Agriculture is one of the several major sources of nitrate pollution, and therefore the EU Nitrate Directive, designed to decrease pollution, has been implemented. Point sources like septic systems and broken sewage systems also contribute to water pollution. Pollution of groundwater by nitrate from 19 shallow wells was studied in a typical agricultural region, middle Podravina, in northwest Croatia. The concentration of nitrate ranged from R6, there was no statistically significant difference in nitrate concentrations (F = 1.98; p = 0.15) during the years 2002-2007. Average concentrations of nitrate in all 19 wells for all the analyzed years were between recommended limit value of 25 mg/l (RLV) and MAV except in 2002 (concentration was under RLV). The results of the repeated measures ANOVA showed statistically significant differences between the wells at the point source distance (proximity) of 20 m (F = 10.6; p < 0.001). Average annual concentrations of nitrate during the years studied are not statistically different, but interaction between proximity and years is statistically significant (F = 2.07; p = 0.04). Results of k-means clustering confirmed division into four clusters according to the pollution. Principal component analysis showed that there is only one significant factor, proximity, which explains 91.6 % of the total variability of nitrate. Differences in water quality were found as a result of different environmental factors. These results will contribute to the implementation of the Nitrate Directive in Croatia and the EU.

  4. Geomicrobial and Geochemical Redox Processes in a Landfill-Polluted Aquifer

    DEFF Research Database (Denmark)

    Ludvigsen, Liselotte; Heron, Gorm; Albrechtsen, Hans-Jørgen; Christensen, Thomas Højlund

    utilized to detect the activity of the redox processes using the investigated electron acceptors. The redox processes investigated were methane production and reduction of sulfate, Fe(III), Mn(IV), and nitrate. The presence of methanogenic bacteria and methanogenic activity were observed close to the...... landfill. Sulfate-reducing bacteria and sulfate reduction were observed in the area where methanogenesis took place, but were also observed further downgradient in the leachate plume. Fe(III)-reducing bacteria were found in almost all samples from the entire anaerobic leachate plume, but no ongoing Fe......(III)-reduction was observed. Sediment analysis with respect to iron species supports these findings, because no clear zone of Fe(III) depletion has been found in the leachate plume. Nitrate-reducers were found in a large section of the plume, but denitrification was observed only in the outskirts of the plume where...

  5. Nitrate groundwater pollution and aquifer vulnerability: the case of the Osona region

    OpenAIRE

    Boy Roura, Mercè

    2013-01-01

    Nitrate groundwater pollution in the Osona region is a persistent and widespread problem. Nitrate concentrations are commonly above the drinking water threshold of 50 mg/L in wells and springs. ANOVA and logistic regression analyses showed that nitrate concentration is more dependent on land use than on the geological setting of springs. Nitrate content presented stationary values in most of the springs over time, while discharge and electrical conductivity evolution depends on the geological...

  6. How can we be sure fracking will not pollute aquifers? Lessons from a major longwall coal mining analogue (Selby, Yorkshire, UK)

    OpenAIRE

    Younger, Paul L.

    2016-01-01

    Development of shale gas by hydraulic fracturing (‘fracking’) is opposed by campaigners who propose (inter alia) that freshwater aquifers could be polluted by upward migration of fractures and any fluids they contain. Prima facie hydrogeological analysis of this proposition has been undertaken. For it to occur, two conditions must be satisfied: (i) sufficient hydraulic interconnection (i.e., a continuous permeable pathway); and(ii) a sustained driving head, oriented upwards. With regard...

  7. Inhibitory Effects of Silver Nanoparticles on Removal of Organic Pollutants and Sulfate in an Anaerobic Biological Wastewater Treatment Process.

    Science.gov (United States)

    Rasool, Kashif; Lee, Dae Sung

    2016-05-01

    The increasing use of silver nanoparticles (AgNPs) in commercial products and industrial processes raises issues regarding the toxicity of sludge biomass in biological wastewater treatment plants, due to potential antimicrobial properties. This study investigated the effects of AgNPs on removal of organic pollutants and sulfate in an anaerobic biological sulfate reduction process. At AgNPs concentrations of up to 10 mg/L, no significant inhibition of sulfate and COD removal was observed. However, at higher concentrations (50-200 mg/L) sulfate and COD removal efficiencies were significantly decreased to 51.8% and 33.6%, respectively. Sulfate and COD reduction followed first-order kinetics at AgNPs concentrations of up to 10 mg/L and second-order kinetics at AgNPs concentrations of 50-200 mg/L. Lactate dehydrogenase release profiles showed increases in cytotoxicity at AgNPs concentrations greater than 50 mg/L suggesting cell membrane disruption. Analysis of extracellular polymeric substances (EPS) from sulfidogenic sludge biomass and of Fourier transform infrared (FT-IR) spectra showed a decrease in concentrations of carbohydrates, proteins, humic substances, and lipids in the presence of AgNPs. Moreover, the interaction of AgNPs with sludge biomass and the damage caused to cell walls were confirmed through scanning electron microscopy with energy dispersive X-ray spectroscopy. PMID:27483773

  8. Nitrate-dependent anaerobic ferrous oxidation (NAFO) by denitrifying bacteria: a perspective autotrophic nitrogen pollution control technology.

    Science.gov (United States)

    Zhang, Meng; Zheng, Ping; Wang, Ru; Li, Wei; Lu, Huifeng; Zhang, Jiqiang

    2014-12-01

    The nitrate-dependent anaerobic ferrous oxidation (NAFO) is an important discovery in the fields of microbiology and geology, which is a valuable biological reaction since it can convert nitrate into nitrogen gas, removing nitrogen from wastewater. The research on NAFO can promote the development of novel autotrophic biotechnologies for nitrogen pollution control and get a deep insight into the biogeochemical cycles. In this work, batch experiments were conducted with denitrifying bacteria as biocatalyst to investigate the performance of nitrogen removal by NAFO. The results showed that the denitrifying bacteria were capable of chemolithotrophic denitrification with ferrous salt as electron donor, namely NAFO. And the maximum nitrate conversion rates (qmax) reached 57.89 mg (g VSS d)−1, which was the rate-limiting step in NAFO. Fe/N ratio, temperature and initial pH had significant influences on nitrogen removal by NAFO process, and their optimal values were 2.0 °C, 30.15 °C and 8.0 °C, respectively. PMID:25461924

  9. Microbial Communities and Their Performances in Anaerobic Hybrid Sludge Bed-Fixed Film Reactor for Treatment of Palm Oil Mill Effluent under Various Organic Pollutant Concentrations

    OpenAIRE

    Kanlayanee Meesap; Nimaradee Boonapatcharoen; Somkiet Techkarnjanaruk; Pawinee Chaiprasert

    2012-01-01

    The anaerobic hybrid reactor consisting of sludge and packed zones was operated with organic pollutant loading rates from 6.2 to 8.2 g COD/L day, composed mainly of suspended solids (SS) and oil and grease (O&G) concentrations between 5.2 to 10.2 and 0.9 to 1.9 g/L, respectively. The overall process performance in terms of chemical oxygen demands (COD), SS, and O&G removals was 73, 63, and 56%, respectively. When the organic pollutant concentrations were increased, the resultant methane poten...

  10. Nitrate pollution of ground waters from shallow basaltic aquifers, Deccan Trap Hydrologic Province, India

    Science.gov (United States)

    Pawar, N. J.; Shaikh, I. J.

    1995-04-01

    Analyses of groundwater samples collected from several locations in a small watershed of the Deccan Trap Hydrologic Province, indicated anomalously higher values of nitrate than the background. However, the NO3 concentrations in water from dug wells under pastureland where the subsurface material consisted of stony waste were minimum. The maximum values were reported for water from dug wells where the principal land use was agricultural. Lowering of NO3 values under shallow water-table conditions suggests denitrification. Higher concentrations of nitrate determined for samples collected from the wells with a deeper water-table indicate that denitrification process is inactive. The high values of nitrate coinciding with agricultural land use indicate fertilizers as the main source of nitrate pollution of ground-water. Decrease in Cl/NO3 ratio for agricultural land use confirms this inference.

  11. Aquifer and Vadose Zone Pollution Determined From Geoelectrical Measurements With Multi- Electrode Wells and Surface Multi-Profiling

    Science.gov (United States)

    de Lima, O. A.; Pereira, P. D.

    2007-05-01

    During the last three years we are developing hydrobiogeological researches to quantitatively describe the underground contamination of a 4.0 km2 area, including two landfill deposits and a tannery industry of Alagoinhas city, Bahia state, Brazil. We used electrical geophysics, geological, geochemical and biological analysis to gain a general understanding of the complex interactions between organic and inorganic pollutants and their environmental impacts. A geological reconnaissance work and a geoelectrical survey using vertical electrical soundings were made around the area to detect and to delineate the extent of the underground contamination plume. The results pointed out the presence of a strong conductive anomaly within the aquifer resulting from invasive fluids both from the landfills and from the surface disposal lagoons from the tannery. Water samples collected at available wells and along the Sauipe river, have shown drastic changes in the total dissolved solids, total chromium, inorganic macro-components, biochemical oxygen demand, chemical oxygen demand, nutrients and bacterial content. As a complimentary work, apparent resistivity and chargeability data were measured as a function of depth along three new multi-electrode wells, and as a function of electrode spacing along five double semi-Schlumberger subsurface profiles. A multi-electrode well is a special monitoring well where we externally install copper electrodes as thin metallic rings spaced by 0.50 m, along its entire filter and casing length. Such electrodes are connected through insulated cables to the ground surface and may be combined into different arrays. Two-side semi-Schlumberger soundings expanded up to 200 m AB/2 spacing and with centers spaced by 50 m along special transverse centered at the plume were inverted using 1D and 2D models. Both techniques were used to detail the groundwater contamination around the Alagoinhas landfills. The electrical measurements performed at the earth

  12. Mitigating Non-Point Source Pollution in the Abbotsford Sumas Aquifer: An Evidence Based Evaluation of the Effectiveness of the BC Action Plan to Tackle Non-Point Source Water Pollution

    OpenAIRE

    Allan, Beverly

    2016-01-01

    At the turn of the 20th century, BC completed its first public status report on the quality of water and found that 10% of the water sources monitored had poor water quality caused primarily by non-point source pollution. The Abbotsford-Sumas Aquifer (ASA) was mentioned in this report and it has had persistent and significant nitrate contamination, primarily from agriculture, for decades despite mitigation efforts. This poses significant public health, ecological and economic risks to the reg...

  13. Anaerobes beyond anaerobic digestion

    OpenAIRE

    Sousa, D. Z.; Pereira, M A; Alves, M.M.

    2009-01-01

    Anaerobic microorganisms are widespread in nature. Sediments, gastrointestinal tracks, volcanic vents, geothermal sources are examples of habitats where anaerobic metabolism prevail, in some cases at extreme temperature, pH and pressure conditions. In such microbial ecosystems waste of some is food for others in a true integrated structure. Anaerobic microorganisms are able to use a wide variety of organic and inorganic compounds. Recalcitrant compounds, such as hydrocarbons, a...

  14. 3D modeling of density and substratum topography effects in a heterogeneous aquifer: the case of the hundred year saline pollution in the Upper Rhine valley

    Science.gov (United States)

    Lucas, Yann; Younes, Anis; Ackerer, Philippe

    2014-05-01

    Knowing the distribution of fresh and saline groundwater is an important issue of the sustainable management of water resources. Here we deal with groundwater plume pollution coming from brines of salted waste heaps in the Upper Rhine aquifer, one of the most important groundwater resources for Western Europe. It has been contaminated in its upstream part by mining brine infiltration coming from potash extraction which started at the beginning of the twentieth century. The salty residues were stored in waste heaps near the mine shafts, and, due to rainwater percolation through the heaps, saline aqueous solutions mixed with groundwater and then progressed in the flow direction, forming high salinity plumes. In the present case, it is proved that density effects are all the more necessary to be considered in a modeling approach that brines density can reach high values just below waste heaps. For this purpose a 3D model is developed using the SEAWAT option of Modflow in a 30 layers model. Simulations are performed on about one hundred years, where chlorine concentration data on the last thirty years are used to constrain the model. In our case, conjugated to a heckled substratum topography, heterogeneous hydrodynamical conditions and the fact that pollution history alternates high pollution phases with relatively low pollution phases, density driven flows lead salted water into original directions downstream waste heaps. From a numerical point of view, it is also shown that discretization degree plays a major role in the density effect modeling.

  15. Assessment of nitrate pollution in the Grand Morin aquifers (France): Combined use of geostatistics and physically based modeling

    International Nuclear Information System (INIS)

    The objective of this work is to combine several approaches to better understand nitrate fate in the Grand Morin aquifers (2700 km2), part of the Seine basin. CAWAQS results from the coupling of the hydrogeological model NEWSAM with the hydrodynamic and biogeochemical model of river PROSE. CAWAQS is coupled with the agronomic model STICS in order to simulate nitrate migration in basins. First, kriging provides a satisfactory representation of aquifer nitrate contamination from local observations, to set initial conditions for the physically based model. Then associated confidence intervals, derived from data using geostatistics, are used to validate CAWAQS results. Results and evaluation obtained from the combination of these approaches are given (period 1977-1988). Then CAWAQS is used to simulate nitrate fate for a 20-year period (1977-1996). The mean nitrate concentrations increase in aquifers is 0.09 mgN L-1 yr-1, resulting from an average infiltration flux of 3500 kgN.km-2 yr-1. - Combined use of geostatistics and physically based modeling allows assessment of nitrate concentrations in aquifer systems

  16. Hg natural pollution of shallow aquifers induced by seawater intrusion at Monte Argentario (Central Italy): Evidences from isotope geochemistry

    International Nuclear Information System (INIS)

    A ground water monitoring campaign was launched by the local administration to evaluate water resources and check for possible aquifer over-exploitation to provide drinking water to the community. Sampling of springs, wells, seawater and lagoon water took place twice during the period 1997/98. The University of Cagliari was responsible for chemical analysis (major ions and trace elements), and the University of Torino was responsible for the isotopic analysis (2H, 18O, 13C of DIC, 34S and 18O of dissolved sulfates, 3H)

  17. Water Pollution

    International Nuclear Information System (INIS)

    This work is about the water pollution. The air and the water interaction cycles is the main idea of the geochemical pollution conception. In the water surface as well as in the deep aquifers we can found cough metals or minerals from the athmosferic air. The activities of mercury fluor and nitrates are important to the pollution study

  18. Biofouling and pollutant removal during long-term operation of an anaerobic membrane bioreactor treating municipal wastewater.

    Science.gov (United States)

    Herrera-Robledo, M; Morgan-Sagastume, J M; Noyola, A

    2010-01-01

    Two different sludge retention times (SRTs) were tested in order to assess the impact on membrane fouling and effluent quality in an anaerobic membrane bioreactor (AnMBR). Two up-flow anaerobic sludge bed (UASB) reactors (1 l volume) coupled to external tubular ultrafiltration membranes (filtration area = 81 cm(2)) were operated at a hydraulic retention time of 3 h and two different SRTs (100 and 60 days). The transmembrane pressure (TMP), flux (J) and relevant parameters to assess water quality were measured. Effluents from UASB reactors were filtered for 500 h without intermediate cleaning. The permeate met Mexican standards for wastewater reclamation in both tested conditions. Abrupt and periodical changes in the TMP and J were noticed during the experimental period. A fouling layer collapse and compression hypothesis was set forth in order to explain these changes. An autopsy performed on biofouled membranes indicated that deposited mass was mainly composed of volatile solids (85%) and the rest related to mineral matter, with the presence of inorganic salts containing Ca, Mg, Fe, P and Si. Biomass in the fouling layer was estimated at 0.27% based on the DNA/biomass ratio for the bacterial biofilm. No clear difference in membrane fouling was detected under the two SRTs applied to the systems. However, when operated over 500 h, repetitive sudden TMP and flux changes occurred later in system A (SRT of 100 days) than in system B (SRT of 60 days) suggesting a stronger fouling layer structure in the former. PMID:20390553

  19. Improving pollutants removal by microalgae Chlorella PY-ZU1 with 15% CO2 from undiluted anaerobic digestion effluent of food wastes with ozonation pretreatment.

    Science.gov (United States)

    Cheng, Jun; Ye, Qing; Xu, Jiao; Yang, Zongbo; Zhou, Junhu; Cen, Kefa

    2016-09-01

    In order to purify various pollutants (3108mg COD/L, 2120mg NH3-N/L) in the undiluted anaerobic digestion effluent of food wastes (UADEFW), ozonation pretreatment was employed to improve pollutants removal by microalgae mutant Chlorella PY-ZU1 with 15% CO2. Ozonation pretreatment broke CC bonds and benzene rings of refractory organics such as unsaturated fatty acids and phenols in UADEFW and degraded them into low-molecular-weight organics such as methanoic acid and methanal, but excessive ozone induced the accumulation of toxic by-products. The microalgal growth rate and biomass yield markedly increased to the peaks of 456mg/L/d and 4.3g/L, respectively, when the UADEFW was pretreated with 2mg-O3/mg-C of ozone. The removal efficiencies of NH3-N, TP and COD reached 99%, 99% and 68%, respectively. The lipid and carbohydrate contents of microalgal biomass increased because of the relative lack of nitrogen when microalgae was cultured with 15% CO2 to purify the UADEFW with ozonation pretreatment. PMID:27243605

  20. Optimal characterization of pollutant sources in contaminated aquifers by integrating sequential-monitoring-network design and source identification: methodology and an application in Australia

    Science.gov (United States)

    Prakash, Om; Datta, Bithin

    2015-09-01

    Often, when pollution is first detected in groundwater, very few spatiotemporal pollutant concentration measurements are available. The contaminant concentration measurement data initially available are generally sparse and insufficient for accurate source characterization. This requires development of a contaminant monitoring plan and its field implementation to collect more data. The location of scientifically chosen monitoring points and the number of measurements are important considerations in improving the source-characterization process, especially in a complex contamination scenario. In order to improve the efficiency of source characterization, a feedback-based methodology is implemented, integrating sequential-monitoring-network design and a source identification method. The simulated annealing (SA) optimization algorithm is used to solve the models for optimal source identification and the monitoring-network-design optimization. This sequence is repeated a few times to improve the accuracy of source characterization. The methodology is based on the premise that concentration measurements from a sequence of implemented monitoring networks provide feedback information on the actual concentration in the site. This additional information, obtained as feedback from monitoring networks designed and implemented based on intermediate source characterization, can result in sequential improvement in the resulting source characterization. The performance of this methodology is evaluated by application to a contaminated aquifer site in New South Wales, Australia, where source location, source-activity initiation time and source-flux (mass per unit time) release history are considered as unknown variables. The performance evaluation results demonstrate potential applicability of the proposed sequential methodology.

  1. Effect of anaerobic digestion at 35, 55 and 60 °C ON pharmaceuticals and organic pollutants

    DEFF Research Database (Denmark)

    Davidsson, Å.; Kjerstadius, H.; Haghighatafshar, S.; Fick, J.; Eriksson, Eva; Olsson, Mikael Emil; Wachtmeister, H.; Cour Jansen, J. la

    The application of treated sewage sludge on farmland is a suggested method for recycling nutrients and reducing demand for commercial fertilizer. However sludge needs to be rendered safe from possible contaminants which can cause acute and long-term health and environmental problems. Residual...... pharmaceuticals and organic contaminants in sludge are mentioned as emerging threats since wastewater treatment plants are not designed to degrade these substances thus yielding an accumulation in sludge. The aim of this study was to evaluate the presence, and reduction, of pharmaceuticals and polycyclic aromatic...... hydrocarbons (PAHs) during anaerobic digestion at 35, 55 and 60ºC and during pasteurization at 70°C. The substrate used was mixed primary and secondary sludge from a 300 000 person-equivalents municipal wastewater treatment plant in southern Sweden. In general no reduction of pharmaceuticals could be observed...

  2. Degradation of organic pollutants and characteristics of activated sludge in an anaerobic/anoxic/oxic reactor treating chemical industrial wastewater

    Directory of Open Access Journals (Sweden)

    Dong Wang

    2014-09-01

    Full Text Available A laboratory-scale anaerobic/anoxic/oxic system operated at the hydraulic retention times (HRT of 20, 40, and 60 h with mixed liquor suspended solids (MLSS concentrations of 3 g/L and 6 g/L was considered for treating chemical industrial wastewater rich in complex organic compounds and total dissolved solids. Extending the HRT and increasing the MLSS concentration resulted in higher removal efficiency for chemical oxygen demand at 72%. Organic compounds in wastewater could be classified into easily-removed and refractory compounds during treatment. The easily-removed compounds consisted primarily of ethers, alcohols, and aldehydes, whereas the refractory compounds included mainly oxygen-containing heterocyclic and benzene-containing compounds. Results from energy-dispersive X-ray spectroscopy showed that several metal ions accumulated in activated sludge, particularly Fe(III. Fe accumulated mainly on the surface of sludge floc pellets and resulted in the compactness of activated sludge, which caused the values of mixed liquor volatile suspended solids /MLSS and sludge volume index to decrease.

  3. Microbial Communities and Their Performances in Anaerobic Hybrid Sludge Bed-Fixed Film Reactor for Treatment of Palm Oil Mill Effluent under Various Organic Pollutant Concentrations

    Directory of Open Access Journals (Sweden)

    Kanlayanee Meesap

    2012-01-01

    Full Text Available The anaerobic hybrid reactor consisting of sludge and packed zones was operated with organic pollutant loading rates from 6.2 to 8.2 g COD/L day, composed mainly of suspended solids (SS and oil and grease (O&G concentrations between 5.2 to 10.2 and 0.9 to 1.9 g/L, respectively. The overall process performance in terms of chemical oxygen demands (COD, SS, and O&G removals was 73, 63, and 56%, respectively. When the organic pollutant concentrations were increased, the resultant methane potentials were higher, and the methane yield increased to 0.30 L CH4/g CODremoved. It was observed these effects on the microbial population and activity in the sludge and packed zones. The eubacterial population and activity in the sludge zone increased to 6.4 × 109 copies rDNA/g VSS and 1.65 g COD/g VSS day, respectively, whereas those in the packed zone were lower. The predominant hydrolytic and fermentative bacteria were Pseudomonas, Clostridium, and Bacteroidetes. In addition, the archaeal population and activity in the packed zone were increased from to 9.1 × 107 copies rDNA/g VSS and 0.34 g COD-CH4/g VSS day, respectively, whereas those in the sludge zone were not much changed. The most represented species of methanogens were the acetoclastic Methanosaeta, the hydrogenotrophic Methanobacterium sp., and the hydrogenotrophic Methanomicrobiaceae.

  4. Alluvial Aquifer

    Data.gov (United States)

    Kansas Data Access and Support Center — This coverage shows the extents of the alluvial aquifers in Kansas. The alluvial aquifers consist of unconsolidated Quaternary alluvium and contiguous terrace...

  5. Intrinsic and enhanced biodegradation of benzene in strongly reduced aquifers

    NARCIS (Netherlands)

    Heiningen, W.N.M. van; Rijnaarts, H.H.M; Langenhoff, A.A.M.

    1999-01-01

    Laboratory microcosm studies were performed to examine intrinsic and enhanced benzene bioremediation using five different sediment and groundwater samples from three deeply anaerobic aquifers sited in northern Netherlands. The influence of addition of nitrate, sulfate, limited amounts of oxygen, and

  6. Transport and degradation of chlorofluorocarbons (CFCs) in the pyritic Rabis Creek aquifer, Denmark

    DEFF Research Database (Denmark)

    Hinsby, K.; Hojberg, A.L.; Engesgaard, P.;

    2007-01-01

    Vertical profiles of the chlorofluorocarbons CFC-11, CFC-12, and CFC-113 penetrating aerobic and anaerobic parts of a shallow sandy aquifer show that the CFC gases are degraded in the <1 m thick transition zone from aerobic to anaerobic groundwater in a pyritic sand aquifer at Rabis Creek, Denmark...

  7. Study of the pollution impact from the usage of sewage and drainage waters on the groundwater of the quaternary aquifer, west Cairo, Egypt

    International Nuclear Information System (INIS)

    Full text: The aim of this study is to assess the water quality of surface and groundwater in the western part of Cairo and to estimate the sources of pollution as salinisation, nutrients, trace elements and microbiological activity as a result of re-use of partially treated drainage and sewage waters for irrigation. In the studied area fresh water problems that need for irrigation arise from the limitation of water resources, high degree of use for cultivating in different seasons and the extension of the reclamation lands. Recently new applications were applied by mixing fresh and wastewater to substitute this decline. Two sewerage stations (Zinen and Abu-Rawash) are located in the area of study for collecting and partially treating wastewater from Giza area. The poorly treated effluents that discharge from these stations in open channels or mixed with fresh water in some canals are flowing through the cultivating land for agricultural irrigation. This could lead to direct pollution to the surface and ground waters in this area, which is the point that needs to detect in this work. The studied area is located in the western region of greater Cairo at latitudes 30 deg. 00' and 30 deg. 15' N and longitudes 31 deg. 00' and 31 deg. 15' E. About 97 water samples were collected from canals, drains and groundwater from the Quaternary aquifer in the area of study. The estimated values of total dissolved solid for most surface and ground waters samples don't exceed 1000 mg/l except about 12% have salinity>1000mg/l. This increase in salinity could be attributed to the ion exchange process between Na- Ca as a result of water- rock interaction, or from the recycling of drainage water containing excess of fertilizers that used in cultivating practices. The predominant water types of surface and groundwater samples are NaHCO3 and Na2SO4 representing meteoric and mixed water type. Few groundwater samples have MgCl2 (marine water type), these samples are located in the east and

  8. Microbial dynamics in natural aquifers

    OpenAIRE

    Bajracharya, Bijendra Man

    2016-01-01

    Microorganisms in groundwater form ecosystems that can transform chemical compounds. Quantitatively understanding microbial dynamics in soils and groundwater is thus essential for pollutant dynamics and biogeochemistry in the subsurface. This dissertation addresses three factors influencing microbial dynamics in aquifers and soils, namely: (1) the influence of grazing on bacteria in eutrophic aquifers, posing the question whether the carrying capacity of bacteria, which has been observed i...

  9. Aquifer thermal energy storage program

    Science.gov (United States)

    Fox, K.

    1980-01-01

    The purpose of the Aquifer Thermal Energy Storage Demonstration Program is to stimulate the interest of industry by demonstrating the feasibility of using a geological formation for seasonal thermal energy storage, thereby, reducing crude oil consumption, minimizing thermal pollution, and significantly reducing utility capital investments required to account for peak power requirements. This purpose will be served if several diverse projects can be operated which will demonstrate the technical, economic, environmental, and institutional feasibility of aquifer thermal energy storage systems.

  10. Which monetary values for the quality of our environment? The example of pollution in the Krška kotlina alluvial aquifer in Slovenia

    Directory of Open Access Journals (Sweden)

    Joerg Prestor

    2009-06-01

    Full Text Available The increasing integration of economic issues into environmental policy has put the valuation of environmentalgoods and services at the forefront of the agenda of experts and researchers involved in the design and implementationof this policy. In the case of water, the European Union Water Framework Directive clearly indicates theneed to consider environmental and resource costs in designing water pricing policies that better account for theenvironmental objectives of the Directive. And the assessment of environmental and resource costs is also referredto in the context of the definition of alternative environmental objectives in cases where costs of reaching the Directive’sobjectives are considered disproportionate or for allowing the development of new sustainable economicactivities.The paper presents the application of contingent valuation to assess the environmental costs that originate fromgroundwater (nitrates and pesticides pollution in the Kr{ko kotlina aquifer. Average willingness-to-pay valuesfor groundwater quality improvements to stabilize groundwater quality below drinking water standards or to reducepollution close to natural background concentrations are equal to 4,7 € and 4,8 € per household per month,respectively. The location where respondents live, their income level or their appurtenance or not to an environmentalorganization are independent variables that influence respondents’ willingness to pay. The relatively lowoverall statistical significance of the regressions obtained stresses that only part of the variability of respondents’responses can be explained with the information obtained and variables considered. This is however in line withsimilar studies undertaken in other parts of Europe and elsewhere.Overall, the paper demonstrates that contingent valuation is possible under Slovenian conditions. In addition toproviding estimate of values of environmental costs and benefits, such contingent valuation surveys

  11. Atrazine removal in Danish anaerobic aquifers

    DEFF Research Database (Denmark)

    Pedersen, Philip Grinder; Arildskov, N.P.; Albrechtsen, Hans-Jørgen

    process was abiotic since atrazine was also removed from microbially inhibited autoclaved and chloroform amended controls, although in controls amended with mercury, atrazine removal was slowed down. (ring-U-C-14)- atrazine amended samples showed no mineralization to (CO2)-C-14 or transformation to...

  12. Economic viability of anaerobic digestion

    Energy Technology Data Exchange (ETDEWEB)

    Wellinger, A. [INFOENERGIE, Ettenhausen (Switzerland)

    1996-01-01

    The industrial application of anaerobic digestion is a relatively new, yet proven waste treatment technology. Anaerobic digestion reduces and upgrades organic waste, and is a good way to control air pollution as it reduces methane and nitrous gas emissions. For environmental and energy considerations, anaerobic digestion is a nearly perfect waste treatment process. However, its economic viability is still in question. A number of parameters - type of waste (solid or liquid), digester system, facility size, product quality and end use, environmental requirements, cost of alternative treatments (including labor), and interest rates - define the investment and operating costs of an anaerobic digestion facility. Therefore, identical facilities that treat the same amount and type of waste may, depending on location, legislation, and end product characteristics, reveal radically different costs. A good approach for evaluating the economics of anaerobic digestion is to compare it to treatment techniques such as aeration or conventional sewage treatment (for industrial wastewater), or composting and incineration (for solid organic waste). For example, the cost (per ton of waste) of in-vessel composting with biofilters is somewhat higher than that of anaerobic digestion, but the investment costs 1 1/2 to 2 times more than either composting or anaerobic digestion. Two distinct advantages of anaerobic digestion are: (1) it requires less land than either composting or incinerating, which translates into lower costs and milder environmental and community impacts (especially in densely populated areas); and (2) it produces net energy, which can be used to operate the facility or sold to nearby industries.

  13. Anaerobic Metabolism: Linkages to Trace Gases and Aerobic Processes

    Science.gov (United States)

    Megonigal, J. P.; Hines, M. E.; Visscher, P. T.

    2003-12-01

    Life evolved and flourished in the absence of molecular oxygen (O2). As the O2 content of the atmosphere rose to the present level of 21% beginning about two billion years ago, anaerobic metabolism was gradually supplanted by aerobic metabolism. Anaerobic environments have persisted on Earth despite the transformation to an oxidized state because of the combined influence of water and organic matter. Molecular oxygen diffuses about 104 times more slowly through water than air, and organic matter supports a large biotic O2 demand that consumes the supply faster than it is replaced by diffusion. Such conditions exist in wetlands, rivers, estuaries, coastal marine sediments, aquifers, anoxic water columns, sewage digesters, landfills, the intestinal tracts of animals, and the rumen of herbivores. Anaerobic microsites are also embedded in oxic environments such as upland soils and marine water columns. Appreciable rates of aerobic respiration are restricted to areas that are in direct contact with air or those inhabited by organisms that produce O2.Rising atmospheric O2 reduced the global area of anaerobic habitat, but enhanced the overall rate of anaerobic metabolism (at least on an area basis) by increasing the supply of electron donors and acceptors. Organic carbon production increased dramatically, as did oxidized forms of nitrogen, manganese, iron, sulfur, and many other elements. In contemporary anaerobic ecosystems, nearly all of the reducing power is derived from photosynthesis, and most of it eventually returns to O2, the most electronegative electron acceptor that is abundant. This photosynthetically driven redox gradient has been thoroughly exploited by aerobic and anaerobic microorganisms for metabolism. The same is true of hydrothermal vents (Tunnicliffe, 1992) and some deep subsurface environments ( Chapelle et al., 2002), where thermal energy is the ultimate source of the reducing power.Although anaerobic habitats are currently a small fraction of Earth

  14. Anaerobic bacteria

    Science.gov (United States)

    Brook I, Goldstein EJ. Diseases caused by non-spore forming anaerobic bacteria. In: Goldman L, Schafer AI, eds. Goldman's Cecil Medicine . 25th ed. Philadelphia, PA: Elsevier Saunders; 2015:chap 297. Stedman's Online ...

  15. Ozark Aquifer

    Data.gov (United States)

    Kansas Data Access and Support Center — These digital maps contain information on the altitude of the base and top, the extent, and the potentiometric surface of the Ozark aquifer in Kansas. The Ozark...

  16. Determination of nitrate pollution sources by using isotopes and hydro-chemical techniques in the shallow Aquifer of Bara basin Northern Kordofan State Sudan

    International Nuclear Information System (INIS)

    This study investigates the nature of the nitrate concentration and its effect on the quality of groundwater in the Bara basin in North Kordofan State Sudan. The principal objective of this study is to: detect possible NO3 sources affecting groundwater quality. The δ15N results included two range of values, which suggested two different nitrogen sources in different parts of the study area. The data used in this study includes lithological logs, pumping and recovery data and chemical analysis. Rock ware, surfer, aquitest and aquichem software programs were used to analyze the data. which is the based on the lithological logs from nine shallow wells and seven deep boreholes. The geological formation was found to be the Umm Ruwaba formation which consists of two aquifers an upper shallow one and the other deep aquifer. The transmissivity of the upper aquifer was found to be 0.528m2 / day, which is good and the average of hydraulic conductivity was found to be 0.084 m/ day, which is high and the storativity is 0.081. The direction of flow of groundwater was found to be from North West to North East over all the area. Chemical analysis showed that the TDS concentration in the study area is within the permissible limits of the Sudanese and the WHO standards. The calcium concentration in the study area also found to be within the permissible limits of the Sudanese and the WHO standards. The nitrate concentration in the upper aquifer ranges between 9.68 and 891 mg/1 which is above the permissible limit of the Sudanese and the WHO standards. The water type in the upper aquifer was found to be calcium-nitrate-chloride-bicarbonate. It appears that the source of the calcium is either for the decay of dead animal bones or the dissolution of calcareous deposits within the upper aquifer. It can be concluded that the quality of groundwater in the study area is good for the human consumption. (Author)

  17. Deposition, persistence and turnover of pollutants: first results from the EU project AquaTerra for selected river basins and aquifers

    DEFF Research Database (Denmark)

    Barth, J.A.C.; Steidle, D.; Kuntz, D.;

    2007-01-01

    the project more than 1700 samples of atmospherically deposited particles, sediments, and water have been collected in the above-mentioned systems. Results show clear spatial patterns of deposition of polyaromatic hydrocarbons (PAHs) with the highest rates in the Meuse Basin. For local inputs, in the...... Brevilles sandy aquifer, the contamination of the groundwater by the pesticides atrazine (AT) and deethylatrazine did not decrease even 5 years after their agricultural inputs were stopped. On the other hand, herbicides such as mecroprop (MCPP), and PAHs, were at least partially degraded microbiologically...... in laboratory studies with soils and aquifer material from selected sites. For sediment transport of contaminants, new flood sampling techniques revealed highest deposition rates of beta-hexachlorocyclohexane (beta-HCH) in river sediments at hotspot areas on the Mulde River in the Bitterfeld region...

  18. Microbial anaerobic digestion (bio-digesters) as an approach to the decontamination of animal wastes in pollution control and the generation of renewable energy.

    Science.gov (United States)

    Manyi-Loh, Christy E; Mamphweli, Sampson N; Meyer, Edson L; Okoh, Anthony I; Makaka, Golden; Simon, Michael

    2013-09-01

    With an ever increasing population rate; a vast array of biomass wastes rich in organic and inorganic nutrients as well as pathogenic microorganisms will result from the diversified human, industrial and agricultural activities. Anaerobic digestion is applauded as one of the best ways to properly handle and manage these wastes. Animal wastes have been recognized as suitable substrates for anaerobic digestion process, a natural biological process in which complex organic materials are broken down into simpler molecules in the absence of oxygen by the concerted activities of four sets of metabolically linked microorganisms. This process occurs in an airtight chamber (biodigester) via four stages represented by hydrolytic, acidogenic, acetogenic and methanogenic microorganisms. The microbial population and structure can be identified by the combined use of culture-based, microscopic and molecular techniques. Overall, the process is affected by bio-digester design, operational factors and manure characteristics. The purpose of anaerobic digestion is the production of a renewable energy source (biogas) and an odor free nutrient-rich fertilizer. Conversely, if animal wastes are accidentally found in the environment, it can cause a drastic chain of environmental and public health complications. PMID:24048207

  19. Microbial Anaerobic Digestion (Bio-Digesters as an Approach to the Decontamination of Animal Wastes in Pollution Control and the Generation of Renewable Energy

    Directory of Open Access Journals (Sweden)

    Golden Makaka

    2013-09-01

    Full Text Available With an ever increasing population rate; a vast array of biomass wastes rich in organic and inorganic nutrients as well as pathogenic microorganisms will result from the diversified human, industrial and agricultural activities. Anaerobic digestion is applauded as one of the best ways to properly handle and manage these wastes. Animal wastes have been recognized as suitable substrates for anaerobic digestion process, a natural biological process in which complex organic materials are broken down into simpler molecules in the absence of oxygen by the concerted activities of four sets of metabolically linked microorganisms. This process occurs in an airtight chamber (biodigester via four stages represented by hydrolytic, acidogenic, acetogenic and methanogenic microorganisms. The microbial population and structure can be identified by the combined use of culture-based, microscopic and molecular techniques. Overall, the process is affected by bio-digester design, operational factors and manure characteristics. The purpose of anaerobic digestion is the production of a renewable energy source (biogas and an odor free nutrient-rich fertilizer. Conversely, if animal wastes are accidentally found in the environment, it can cause a drastic chain of environmental and public health complications.

  20. Fate of pathogens and micro-pollutants during organic wastes and by-products anaerobic digestion - a review; Etat des connaissances sur le devenir des germes pathogenes et des micropolluants au cours de la methanisation des dechets et sous-produits organiques

    Energy Technology Data Exchange (ETDEWEB)

    Couturier, Ch.; Galtier, L.

    1998-09-01

    Based on 300 scientific papers, the following bibliographical research deals with the fate of micro-pollutants (pathogens, heavy metals, organic pollutants) during anaerobic digestion. Different biological and chemical mechanisms allow organic compounds elimination, except from some Polycyclic Aromatic Hydrocarbons (PAHs) and heavy metals which are fixed to the solid biomass, permitting water contamination risks attenuation. Unlike mesophilic digestion, thermophilic digestion is a 'sanitation' process regarding pathogens elimination. However, mesophilic digestion offers an important reliability compared with competitive or complementary processes. In particular, energy recovery from anaerobic digestion allows temperature control and makes easier further sanitation heat treatments. In general, anaerobic digestion represents a tool which can be included in an organic waste treatment line assuming waste selection and good agricultural practices. Otherwise, sanitation problem is still badly handled by waste operators and constructors which have been consulted. Research orientations seem especially interesting in improving knowledge of real industrial processes performances. (author)

  1. Guarani aquifer

    International Nuclear Information System (INIS)

    The environmental protection and sustain ability develop project of Guarani Aquifer System is a join work from Argentina, Brazil, Paraguay and Uruguay with a purpose to increase the knowledge resource and propose technical legal and organizational framework for sustainable management between countries.The Universities funds were created as regional universities support in promotion, training and academic research activities related to environmental al social aspects of the Guarani Aquifer System.The aim of the project is the management and protection of the underground waters resources taking advantage and assesment for nowadays and future generations

  2. Initiation de la modélisation de la lixiviation du nitrate à l'échelle de la parcelle : problématique de la pollution de l'aquifère de l'Oued Souhil, Tunisie.

    OpenAIRE

    De Smet, Sarah

    2012-01-01

    L’aquifère de l’Oued Souhil fait l’objet d’une pollution nitratée (130 mg/l) qui est due à l’utilisation massive de fertilisant, à la baisse du niveau des nappes ainsi qu’à l’utilisation d’eaux usées traitées (EUT). Par conséquent, l’objectif de ce mémoire est de fournir un outil adéquat de modélisation de la lixiviation du nitrate dans les sols sableux tunisiens. A cette fin, un essai d’irrigation en cases lysimétriques (avec répétitions) est effectué selon trois schémas différents : irrigat...

  3. Anaerobic workout

    OpenAIRE

    McAdam, Ewan J.

    2010-01-01

    Anaerobic technology cannot directly replace current wastewater treatment processes exclusively. The UASB reactor configuration removes slightly less organic carbon by comparison as the process relies on lamella separation for passive clarification rather than using fine pores like anMBR. By contrast, whilst anMBR can operate as a single unit process for organic carbon removal, the membrane surface has to be cleaned using gas sparging to limit surface deposition, which requires extra energy. ...

  4. Anaerobic arsenite oxidation with an electrode serving as the sole electron acceptor: A novel approach to the bioremediation of arsenic-polluted groundwater

    Energy Technology Data Exchange (ETDEWEB)

    Pous, Narcis [Laboratory of Chemical and Environmental Engineering (LEQUiA), Institute of the Environment, University of Girona, C/Maria Aurèlia Capmany, 69 E-17071 Girona (Spain); Casentini, Barbara; Rossetti, Simona; Fazi, Stefano [Water Research Institute (IRSA-CNR), National Research Council, Via Salaria Km 29.300, 00015 Monterotondo (Italy); Puig, Sebastià [Laboratory of Chemical and Environmental Engineering (LEQUiA), Institute of the Environment, University of Girona, C/Maria Aurèlia Capmany, 69 E-17071 Girona (Spain); Aulenta, Federico, E-mail: aulenta@irsa.cnr.it [Water Research Institute (IRSA-CNR), National Research Council, Via Salaria Km 29.300, 00015 Monterotondo (Italy)

    2015-02-11

    Highlights: • As(III) was oxidized to As(V) in a bioelectrochemical system. • A polarized graphite electrode served as electron acceptor. • Gammaproteobacteria were the dominating organisms at the electrode. - Abstract: Arsenic contamination of soil and groundwater is a serious problem worldwide. Here we show that anaerobic oxidation of As(III) to As(V), a form which is more extensively and stably adsorbed onto metal-oxides, can be achieved by using a polarized (+497 mV vs. SHE) graphite anode serving as terminal electron acceptor in the microbial metabolism. The characterization of the microbial populations at the electrode, by using in situ detection methods, revealed the predominance of gammaproteobacteria. In principle, the proposed bioelectrochemical oxidation process would make it possible to provide As(III)-oxidizing microorganisms with a virtually unlimited, low-cost and low-maintenance electron acceptor as well as with a physical support for microbial attachment.

  5. Anaerobic arsenite oxidation with an electrode serving as the sole electron acceptor: A novel approach to the bioremediation of arsenic-polluted groundwater

    International Nuclear Information System (INIS)

    Highlights: • As(III) was oxidized to As(V) in a bioelectrochemical system. • A polarized graphite electrode served as electron acceptor. • Gammaproteobacteria were the dominating organisms at the electrode. - Abstract: Arsenic contamination of soil and groundwater is a serious problem worldwide. Here we show that anaerobic oxidation of As(III) to As(V), a form which is more extensively and stably adsorbed onto metal-oxides, can be achieved by using a polarized (+497 mV vs. SHE) graphite anode serving as terminal electron acceptor in the microbial metabolism. The characterization of the microbial populations at the electrode, by using in situ detection methods, revealed the predominance of gammaproteobacteria. In principle, the proposed bioelectrochemical oxidation process would make it possible to provide As(III)-oxidizing microorganisms with a virtually unlimited, low-cost and low-maintenance electron acceptor as well as with a physical support for microbial attachment

  6. Prospects of Anaerobic Digestion Technology in China

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    As the world's largest developing country, China must face the problem of managing municipal solid waste, and the challenge of organic waste disposal is even more serious. Considering the characteristics of traditional waste disposal technologies and the subsequent secondary pollution, anaerobic digestion has various advantages such as reduction in the land needed for disposal and preservation of environmental quality. In light of the energy crisis, this paper focuses on the potential production of biogas from biowaste through anaerobic digestion processes, the problems incurred by the waste collection system, and the efficiency of the anaerobic digestion process. Use of biogas in a combined heat and power cogeneration system is also discussed. Finally, the advantages of anaerobic digestion technology for the Chinese market are summarized. The anaerobic digestion is suggested to be a promising treating technology for the organic wastes in China.

  7. Study of the pollution impact from the usage of sewage and drainage waters on the groundwater of the quaternary aquifer, West Cairo, Egypt

    International Nuclear Information System (INIS)

    The aim of this study is to assess the water quality of surface and groundwater in the western part of Cairo and to estimate the sources of pollution as salinisation, nutrients, trace elements and microbiological activity as a result of re-use of partially treated drainage and sewage waters for irrigation

  8. Anaerobic procedures of wastewater treatment

    OpenAIRE

    Zupančič, Tadeja

    2013-01-01

    Highly polluted wastewater is formed in dairies, pig farms and slaughterhouses. Before released into watercourses, wastewater should be properly processed with different treatment procedures in wastewater treatment plants. The thesis deals with the descriptions of mechanical, physical and chemical, and biological wastewater treatment procedures and the description of the factors which affect the reactions in wastewater treatment plants. I give special emphasis on anaerobic wastewater treatmen...

  9. Biodegradation of cresol isomers in anoxic aquifers.

    OpenAIRE

    Smolenski, W J; Suflita, J M

    1987-01-01

    The biodegradation of o-, m-, and p-cresol was examined in material obtained from a shallow anaerobic alluvial sand aquifer. The cresol isomers were preferentially metabolized, with p-cresol being the most easily degraded. m-Cresol was more persistent than the para-isomer, and o-cresol persisted for over 90 days. Biodegradation of cresol isomers was favored under sulfate-reducing conditions (SRC) compared with that under methanogenic conditions (MC). Slurries that were acclimated to p-cresol ...

  10. Deposition, persistence and turnover of pollutants: First results from the EU project AquaTerra for selected river basins and aquifers

    OpenAIRE

    J. A. C. Barth; Steidle, D.; Kuntz, D.; Gocht, T.; Mouvet, C.; von Tümpling, W.; Lobe, I.; Langenhoff, A.; Albrechtsen, H.-J.; Janniche, G. S.; Morasch, Barbara; Hunkeler, Daniel; Grathwohl, P.

    2008-01-01

    Deposition, turnover and movement of persistent organic pollutants (POP) were investigated in the EU integrated project “AquaTerra”, which is among the first funded environmental projects within the 6th Framework Program by the European Commission. Project work integrates across various disciplines that range from biogeochemistry, environmental engineering, computer modelling and chemistry to socio-economic sciences. Field study areas are the river basins of the Ebro, the Meuse, the Elbe and ...

  11. Anaerobic thermophiles.

    Science.gov (United States)

    Canganella, Francesco; Wiegel, Juergen

    2014-01-01

    The term "extremophile" was introduced to describe any organism capable of living and growing under extreme conditions. With the further development of studies on microbial ecology and taxonomy, a variety of "extreme" environments have been found and an increasing number of extremophiles are being described. Extremophiles have also been investigated as far as regarding the search for life on other planets and even evaluating the hypothesis that life on Earth originally came from space. The first extreme environments to be largely investigated were those characterized by elevated temperatures. The naturally "hot environments" on Earth range from solar heated surface soils and water with temperatures up to 65 °C, subterranean sites such as oil reserves and terrestrial geothermal with temperatures ranging from slightly above ambient to above 100 °C, to submarine hydrothermal systems with temperatures exceeding 300 °C. There are also human-made environments with elevated temperatures such as compost piles, slag heaps, industrial processes and water heaters. Thermophilic anaerobic microorganisms have been known for a long time, but scientists have often resisted the belief that some organisms do not only survive at high temperatures, but actually thrive under those hot conditions. They are perhaps one of the most interesting varieties of extremophilic organisms. These microorganisms can thrive at temperatures over 50 °C and, based on their optimal temperature, anaerobic thermophiles can be subdivided into three main groups: thermophiles with an optimal temperature between 50 °C and 64 °C and a maximum at 70 °C, extreme thermophiles with an optimal temperature between 65 °C and 80 °C, and finally hyperthermophiles with an optimal temperature above 80 °C and a maximum above 90 °C. The finding of novel extremely thermophilic and hyperthermophilic anaerobic bacteria in recent years, and the fact that a large fraction of them belong to the Archaea has definitely

  12. Anaerobic Thermophiles

    Directory of Open Access Journals (Sweden)

    Francesco Canganella

    2014-02-01

    Full Text Available The term “extremophile” was introduced to describe any organism capable of living and growing under extreme conditions. With the further development of studies on microbial ecology and taxonomy, a variety of “extreme” environments have been found and an increasing number of extremophiles are being described. Extremophiles have also been investigated as far as regarding the search for life on other planets and even evaluating the hypothesis that life on Earth originally came from space. The first extreme environments to be largely investigated were those characterized by elevated temperatures. The naturally “hot environments” on Earth range from solar heated surface soils and water with temperatures up to 65 °C, subterranean sites such as oil reserves and terrestrial geothermal with temperatures ranging from slightly above ambient to above 100 °C, to submarine hydrothermal systems with temperatures exceeding 300 °C. There are also human-made environments with elevated temperatures such as compost piles, slag heaps, industrial processes and water heaters. Thermophilic anaerobic microorganisms have been known for a long time, but scientists have often resisted the belief that some organisms do not only survive at high temperatures, but actually thrive under those hot conditions. They are perhaps one of the most interesting varieties of extremophilic organisms. These microorganisms can thrive at temperatures over 50 °C and, based on their optimal temperature, anaerobic thermophiles can be subdivided into three main groups: thermophiles with an optimal temperature between 50 °C and 64 °C and a maximum at 70 °C, extreme thermophiles with an optimal temperature between 65 °C and 80 °C, and finally hyperthermophiles with an optimal temperature above 80 °C and a maximum above 90 °C. The finding of novel extremely thermophilic and hyperthermophilic anaerobic bacteria in recent years, and the fact that a large fraction of them belong

  13. Anaerobe Tolerance to Oxygen and the Potentials of Anaerobic and Aerobic Cocultures for Wastewater Treatment

    Directory of Open Access Journals (Sweden)

    M.T. Kato

    1997-12-01

    Full Text Available The anaerobic treatment processes are considered to be well-established methods for the elimination of easily biodegradable organic matter from wastewaters. Some difficulties concerning certain wastewaters are related to the possible presence of dissolved oxygen. The common belief is that anaerobes are oxygen intolerant. Therefore, the common practice is to use sequencing anaerobic and aerobic steps in separate tanks. Enhanced treatment by polishing off the residual biodegradable oxygen demand from effluents of anaerobic reactors, or the biodegradation of recalcitrant wastewater pollutants, usually requires sequenced anaerobic and aerobic bacteria activities. However, the combined activity of both bacteria can also be obtained in a single reactor. Previous experiments with either pure or mixed cultures showed that anaerobes can tolerate oxygen to a certain extent. The oxygen toxicity to methanogens in anaerobic sludges was quantified in batch experiments, as well as in anaerobic reactors. The results showed that methanogens have a high tolerance to oxygen. In practice, it was confirmed that dissolved oxygen does not constitute any detrimental effect on reactor treatment performance. This means that the coexistence of anaerobic and aerobic bacteria in one single reactor is feasible and increases the potentials of new applications in wastewater treatment

  14. Anaerobic digestion: biodegradability and biogas production of model wastes

    OpenAIRE

    Lausund, Erlend

    2014-01-01

    Anaerobic digestion is a desirable treatment practice in terms of minimizing volume, treating of pollutants and biogas production. In this thesis model wastes have been investigated with respect to biogas and methane production in order to find out what wastes are suitable for anaerobic digestion, and discussing ways to further the research to optimize the production of renewable energy.

  15. Anaerobic Digestion: Process

    DEFF Research Database (Denmark)

    Angelidaki, Irini; Batstone, Damien J.

    2011-01-01

    Organic waste may degrade anaerobically in nature as well as in engineered systems. The latter is called anaerobic digestion or biogasification. Anaerobic digestion produces two main outputs: An energy-rich gas called biogas and an effluent. The effluent, which may be a solid as well as liquid with...... very little dry matter may also be called a digest. The digest should not be termed compost unless it specifically has been composted in an aerated step. This chapter describes the basic processes of anaerobic digestion. Chapter 9.5 describes the anaerobic treatment technologies, and Chapter 9.......6 addresses the mass balances and environmental aspects of anaerobic digestion....

  16. Anaerobic Metabolism and Bioremediation of Explosives-Contaminated Soil

    Science.gov (United States)

    Boopathy, Raj

    Nitroaromatic compounds pollute soil, water, and food via use of pesticides, plastics, pharmaceuticals, landfill dumping of industrial wastes, and the military use of explosives. Biotransformation of trinitrotoluene and other nitroaromatics by aerobic bacteria in the laboratory has been frequently reported, but the anaerobic bacterial metabolism of nitroaromatics has not been studied as extensively perhaps due to the difficulty in working with anaerobic cultures and the slow growth of anaerobes. Sulfate-reducing and methanogenic bacteria can metabolize nitroaromatic compounds under anaerobic conditions if appropriate electron donors and electron acceptors are present in the environment.

  17. Assessment of heavy metal and bacterial pollution in coastal aquifers from SIPCOT industrial zones, Gulf of Mannar, South Coast of Tamil Nadu, India

    Science.gov (United States)

    Selvam, S.; Antony Ravindran, A.; Venkatramanan, S.; Singaraja, C.

    2015-06-01

    Heavy metals and microbiological contamination were investigated in groundwater in the industrial and coastal city of Thoothukudi. The main sources of drinking water in this area are water bores which are dug up to the depth of 10-50 m in almost every house. A number of chemical and pharmaceutical industries have been established since past three decades. Effluents from these industries are reportedly being directly discharged onto surrounding land, irrigation fields and surface water bodies forming point and non-point sources of contamination for groundwater in the study area. The study consists of the determination of physico-chemical properties, trace metals, heavy metals and microbiological quality of drinking water. Heavy metals were analysed using Inductively Coupled Plasma Mass Spectrometry and compared with the (WHO in Guidelines for drinking water quality, 2004) standards. The organic contamination was detected in terms of most probable number (MPN) test in order to find out faecal coliforms that were identified through biochemical tests. A comparison of the results of groundwater samples with WHO guidelines reveals that most of the groundwater samples are heavily contaminated with heavy metals like arsenic, selenium, lead, boron, aluminium, iron and vanadium. The selenium level was higher than 0.01 mg/l in 82 % of the study area and the arsenic concentration exceeded 0.01 mg/l in 42 % of the area. The results reveal that heavy metal contamination in the area is mainly due to the discharge of effluents from copper industries, alkali chemical industry, fertiliser industry, thermal power plant and sea food industries. The results showed that there are pollutions for the groundwater, and the total Coliform means values ranged from 0.6-145 MPN ml-1, faecal Coliform ranged from 2.2-143 MPN ml-1, Escherichia coli ranged from 0.9 to 40 MPN ml-1 and faecal streptococci ranged from 10-9.20 × 102 CFU ml-1. The coastal regions are highly contaminated with total

  18. Biodegradation of disinfection byproducts as a potential removal process during aquifer storage recovery

    Science.gov (United States)

    Landmeyer, J.E.; Bradley, P.M.; Thomas, J.M.

    2000-01-01

    The biodegradation potential of two drinking water disinfection byproducts was investigated using aquifer materials obtained from approximately 100 and 200 meters below land surface in an aerobic aquifer system undergoing aquifer storage recovery of treated surface water. No significant biodegradation of a model trihalomethane compound, chloroform, was observed in aquifer microcosms under aerobic or anaerobic conditions. In contrast, between 16 and 27 percent mineralization of a radiolabeled model haloacetic acid compound, chloroacetic acid, was observed. These results indicate that although the potential for biodegradation of chloroacetic acid exists in deep aquifer systems, chloroform entrained within these aquifers or formed in situ will tend to persist. These results have important implications for water managers planning to meet anticipated lowered permissible levels of tri-halomethanes in drinking water.The biodegradation potential of two drinking water disinfection byproducts was investigated using aquifer materials obtained from approximately 100 and 200 meters below land surface in an aerobic aquifer system undergoing aquifer storage recovery of treated surface water. No significant biodegradation of a model trihalomethane compound, chloroform, was observed in aquifer microcosms under aerobic or anaerobic conditions. In contrast, between 16 and 27 percent mineralization of a radiolabeled model haloacetic acid compound, chloroacetic acid, was observed. These results indicate that although the potential for biodegradation of chloroacetic acid exists in deep aquifer systems, chloroform entrained within these aquifers or formed in situ will tend to persist. These results have important implications for water managers planning to meet anticipated lowered permissible levels of trihalomethanes in drinking water.Aquifer-storage-recovery injection water often contains disinfection byproducts. Results are presented from a study in which two model disinfection

  19. Proceedings of the 10. world congress on anaerobic digestion 2004 : anaerobic bioconversion, answer for sustainability

    International Nuclear Information System (INIS)

    This conference reviewed the broad scope of anaerobic process-related activities taking place globally and confirmed the possibilities of using anaerobic processes to add value to industrial wastewaters, municipal solid wastes and organic wastes while minimizing pollution and greenhouse gases. It focused on biomolecular tools, instrumentation of anaerobic digestion processes, anaerobic bioremediation of chlorinated organics, and thermophilic and mesophilic digestion. Several papers focused on the feasibility of using waste products to produce hydrogen and methane for electricity generation. The sessions of the conference were entitled acidogenesis; microbial ecology; process control; sulfur content; technical development; domestic wastewater; agricultural waste; organic municipal solid wastes; instrumentation; molecular biology; sludges; agricultural feedstock; bioremediation; industrial wastewater; hydrogen production; pretreatments; sustainability; and integrated systems. The conference featured 387 posters and 192 oral presentations, of which 111 have been indexed separately for inclusion in this database. refs., tabs., figs

  20. Confined aquifer vulnerability induced by a pumping well in a leakage area

    Science.gov (United States)

    Meng, X.; Deng, B.; Shao, J.; Yin, M.; Liu, D.; Hu, Q.

    2015-05-01

    Due to the pollution of shallow groundwater and the rapid development of society and economy which consume more freshwater, the exploitation of confined groundwater is steadily increasing in north China. Therefore, the rapid decline of the confined groundwater head increases the risk of confined aquifer pollution by leaky recharge from shallow aquifers. In this paper, a quantitative method for assessing confined aquifer vulnerability to contamination due to pumping has been developed. This method is based on the shallow and confined groundwater flow model and the advection and dispersion in the aquitard, including sorption. The cumulative time for the pollutant concentration at the top boundary of confined aquifer exceeding the maximum allowable level is defined as the confined aquifer vulnerability index, which can be obtained by numerically solving the solute transport equation. A hypothetical example is chosen as a case study to illustrate the whole process. The results indicate that the proposed method is a practical and reasonable assessment method of confined aquifer vulnerability.

  1. Rates of microbial metabolism in deep coastal plain aquifers

    Science.gov (United States)

    Chapelle, F.H.; Lovley, D.R.

    1990-01-01

    Rates of microbial metabolism in deep anaerobic aquifers of the Atlantic coastal plain of South Carolina were investigated by both microbiological and geochemical techniques. Rates of [2-14C]acetate and [U-14C]glucose oxidation as well as geochemical evidence indicated that metabolic rates were faster in the sandy sediments composing the aquifers than in the clayey sediments of the confining layers. In the sandy aquifer sediments, estimates of the rates of CO2 production (millimoles of CO2 per liter per year) based on the oxidation of [2-14C]acetate were 9.4 x 10-3 to 2.4 x 10-1 for the Black Creek aquifer, 1.1 x 10-2 for the Middendorf aquifer, and microbial metabolism in deep subsurface environments. This has important implications for the use of laboratory incubations in attempts to estimate biorestoration capacities of deep aquifers. The rate estimates from geochemical modeling indicate that deep aquifers are among the most oligotrophic aquatic environments in which there is ongoing microbial metabolism.

  2. Gender comparisons in anaerobic power and anaerobic capacity tests.

    OpenAIRE

    Maud, P. J.; Shultz, B B

    1986-01-01

    The purpose of the study was to compare anaerobic power and anaerobic capacity test scores between young active men and women. Three performance measures of anaerobic power and two of anaerobic capacity were administered to a sample comprising 52 male and 50 female college students (means age = 21.4 yrs). Results indicated significant differences between men and women in body height, weight and per cent fat, in fat free mass (FFM), anaerobic power, and anaerobic capacity when recorded as gros...

  3. Characterization of Aquifer Hydraulic Parameters: from Theis to Hydraulic Tomography

    OpenAIRE

    D'Oria, Marco

    2010-01-01

    Groundwater is in many parts of the world an important source of fresh water for several purpose such as domestic and industrial use and irrigation. Pollution and bad management of groundwater are only two of the problems that affect the aquifers around the world. Detailed information about the spatial distribution of hydraulic properties in subsurface are of crucial importance for a proper management of groundwater and for the prediction of the solutes transport in aquifer and therefore for ...

  4. Rates of microbial metabolism in deep coastal plain aquifers

    International Nuclear Information System (INIS)

    Rates of microbial metabolism in deep anaerobic aquifers of the Atlantic coastal plain of South Carolina were investigated by both microbiological and geochemical techniques. Rates of [2-14C]acetate and [U-14C]glucose oxidation as well as geochemical evidence indicated that metabolic rates were faster in the sandy sediments composing the aquifers than in the clayey sediments of the confirming layers. In the many aquifer sediments, estimates of the rates of CO2 production (millimoles of CO2 per liter per year) based on the oxidation of [2-14C] acetate were 9.4 x 10-3 to 2.4 x 10-1 for the Black Creek aquifer, 1.1 x 10-2 for the Middendorf aquifer, and -5 for the Cape Fear aquifer. These estimates were at least 2 orders of magnitude lower than previously published estimates that were based on the accumulation of CO2 in laboratory incubations of similar deep subsurface sediments. In contrast, geochemical modeling of groundwater chemistry changes along aquifer flowpaths gave rate estimates that ranged from 10-4 to 10-6 mmol of CO2 production could have been no more than 10-4 mmol per liter per year. Thus, laboratory incubations may greatly overestimate the in situ rates of microbial metabolism in deep subsurface environments. This has important implications for the use of laboratory incubations in attempts to estimate biorestoration capacities of deep aquifers. The rate estimates from geochemical modeling indicate that deep aquifers are among the most oligotrophic aquatic environments in which there is ongoing microbial metabolism

  5. Perspectives for anaerobic digestion

    DEFF Research Database (Denmark)

    Ahring, Birgitte Kiær

    2003-01-01

    to the soil. Anaerobic digestion (AD) is one way of achieving this goal and it will furthermore, reduce energy consumption or may even be net energy producing. This chapter aims at provide a basic understanding of the world in which anaerobic digestion is operating today. The newest process developments...

  6. Anaerobic sludge granulation

    NARCIS (Netherlands)

    Hulshoff Pol, L.W.; Castro Lopes, de S.I.; Lettinga, G.; Lens, P.N.L.

    2004-01-01

    This paper reviews different theories on anaerobic sludge granulation in UASB-reactors that have been proposed during the past two decades
    This paper reviews different theories on anaerobic sludge granulation in UASB-reactors that have been proposed during the past two decades. The initial stage

  7. Arsenic release from Floridan Aquifer rock during incubations simulating aquifer storage and recovery operations.

    Science.gov (United States)

    Jin, Jin; Zimmerman, Andrew R; Norton, Stuart B; Annable, Michael D; Harris, Willie G

    2016-05-01

    While aquifer storage and recovery (ASR) is becoming widely accepted as a way to address water supply shortages, there are concerns that it may lead to release of harmful trace elements such as arsenic (As). Thus, mechanisms of As release from limestone during ASR operations were investigated using 110-day laboratory incubations of core material collected from the Floridan Aquifer, with treatment additions of labile or refractory dissolved organic matter (DOM) or microbes. During the first experimental phase, core materials were equilibrated with native groundwater lacking in DO to simulate initial non-perturbed anaerobic aquifer conditions. Then, ASR was simulated by replacing the native groundwater in the incubations vessels with DO-rich ASR source water, with DOM or microbes added to some treatments. Finally, the vessels were opened to the atmosphere to mimic oxidizing conditions during later stages of ASR. Arsenic was released from aquifer materials, mainly during transitional periods at the beginning of each incubation stage. Most As released was during the initial anaerobic experimental phase via reductive dissolution of Fe oxides in the core materials, some or all of which may have formed during the core storage or sample preparation period. Oxidation of As-bearing Fe sulfides released smaller amounts of As during the start of later aerobic experimental phases. Additions of labile DOM fueled microbially-mediated reactions that mobilized As, while the addition of refractory DOM did not, probably due to mineral sorption of DOM that made it unavailable for microbial utilization or metal chelation. The results suggest that oscillations of groundwater redox conditions, such as might be expected to occur during an ASR operation, are the underlying cause of enhanced As release in these systems. Further, ASR operations using DOM-rich surface waters may not necessarily lead to additional As releases. PMID:26878636

  8. Hydrogeochemical Analysis of an Overexploited Aquifer In Bangladesh Toward Managed Aquifer Recharge Project Implementation

    Science.gov (United States)

    Rahman, M. A.; Wiegand, B. A.; Pervin, M.; Sauter, M.

    2012-12-01

    In most parts of the upper Dupitila aquifer (Dhaka City, Bangladesh) the average groundwater depletion reaches 2-3 m/year due to increasing water demands of the growing population. To counteract overexploitation of the aquifer, a more sustainable water management is required. The analysis of the local water resources system suggests that Managed Aquifer Recharge (MAR) would help to restore groundwater resources to strengthen water supply of Dhaka City, e.g., by using collected urban monsoon runoff and excess surface water from rivers. To assess possible effects of surface water or rainwater injection on groundwater quality, a comprehensive hydrogeochemical survey of the Dupitila aquifer is required. This paper presents hydrogeochemical data to document the current status of groundwater quality and to evaluate potential groundwater pollution by mobilization of hazardous chemicals as a result of changes in the hydrochemical equilibria. We performed a comprehensive review of available secondary data sources and will present new results from hydrochemical and Sr isotope investigations of water samples that were conducted within this study. Currently, groundwater quality in the upper Dupitila aquifer is characterized by variations in the electrical conductivity in the range of 200 to 1100 μS/cm, which may indicate some anthropogenic contamination by leakage from waste disposal including the sewage network and from surface water infiltration into the groundwater aquifer. Dissolved oxygen concentrations range from 1.0 to 4.9 mg/L (average 2.5 mg/L) in the upper Dupitila aquifer, while the lower Dupilita aquifer shows dissolved oxygen concentrations in the range 0 to 0.7 mg/L. Concentrations of major ions show some variation primarily due to a sedimentologically/mineralogically heterogeneous aquifer composition (sand, gravel, clay horizons), but may also be affected by anthropogenic processes. The groundwater composition is predominated by Ca-Mg-HCO3 and saturation values

  9. Anaerobic Digestion and its Applications

    Science.gov (United States)

    Anaerobic digestion is a natural biological process. The initials "AD" may refer to the process of anaerobic digestion, or the built systems of anaerobic digesters. While there are many kinds of digesters, the biology is basically the same for all. Anaerobic digesters are built...

  10. Early Mesozoic basin aquifers

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set represents the extent of the Early Mesozoic basin aquifers in the states of Massachusettes, Connecticut, New York, New Jersey, Pennsylvania, Maryland,...

  11. Lower Cretaceous aquifers

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set represents the extent of the Lower Cretaceous aquifers in the states of Montana, Wyoming, South Dakota, Kansas, Nebraska, Iowa, and Minnesota..

  12. Ogallala Aquifer Mapping Program

    International Nuclear Information System (INIS)

    A computerized data file has been established which can be used efficiently by the contour-plotting program SURFACE II to produce maps of the Ogallala aquifer in 17 counties of the Texas Panhandle. The data collected have been evaluated and compiled into three sets, from which SURFACE II can generate maps of well control, aquifer thickness, saturated thickness, water level, and the difference between virgin (pre-1942) and recent (1979 to 1981) water levels. 29 figures, 1 table

  13. APPLICATION OF ANAEROBIC BIOTECHNOLOGY FOR PHARMACEUTICAL WASTEWATER TREATMENT

    Directory of Open Access Journals (Sweden)

    Shreeshivadasan Chelliapan and Paul J. Sallis

    2011-01-01

    Full Text Available The wastewater generated from pharmaceutical industry generally contain high organic load and the treatment is primarily carried out using two major types of biological methods; aerobic and anaerobic. However, due to high strength, it is infeasible to treat some pharmaceutical wastewater using aerobic biological processes. As an alternative, an anaerobic process is preferred to remove high strength organic matter. Anaerobic wastewater treatment is considered as the most cost effective solution for organically polluted industrial waste streams. In particular the development of high rate systems, in which hydraulic retention times (HRT are uncoupled from solids retention times (SRT, has led to a worldwide acceptance of anaerobic wastewater treatment. In this paper, literature on anaerobic digestion, anaerobic reactor technology and existing anaerobic treatment of pharmaceutical wastewater are presented. In addition, fate of pharmaceuticals in the environment was also discussed in brief. A case study of a laboratory investigation into the treatment of pharmaceutical wastewater containing the antibiotic Tylosin in an anaerobic reactor was also given. Specifically, it was determined whether the anaerobic reactor could be used as a pre-treatment system at an existing pharmaceutical production plant. The performance of the reactor treating real pharmaceutical wastewater at various organic loading rate (OLR was investigated and showed efficient substrate removal at low OLRs (0.43 – 1.86 kg COD.m-3.d-1 by promoting efficient chemical oxygen demand (COD reduction (70 – 75%. Under these conditions, an average of 95% Tylosin reduction was achieved in the UASR. However, increasing the OLRs to 3.73 kg COD.m-3.d-1 by reducing the hydraulic retention time (HRT (4 – 2 d reduced the COD removal efficiency (45%. Changes in the organic loading affected the treatment performance of the anaerobic reactor, and at high OLRs, it was not able to withstand the short

  14. Comparison of Aerobic and Anaerobic Biodegradation of Sugarcane Vinasse.

    Science.gov (United States)

    Mota, V T; Araújo, T A; Amaral, M C S

    2015-07-01

    Vinasse is the main liquid waste from ethanol production, and it has a considerable pollution potential. Biological treatment is a promising alternative to reduce its organic load. The aim of this study was to analyze the biodegradation of sugarcane juice vinasse in aerobic and anaerobic conditions. The content of carbohydrates, proteins and volatile fatty acids was evaluated. Vinasse samples showed a high biodegradability (>96.5 %) and low percentage of inert chemical oxygen demand (COD) (<3.2 %) in both aerobic and anaerobic conditions. The rates of substrate utilization were slightly higher in aerobic reactors, but COD stabilization occurred simultaneously in the anaerobic reactors, confirming its suitability for anaerobic digestion. Inert COD in anaerobic conditions was lower than in aerobic conditions. On the other hand, COD from metabolic products in the anaerobic reactors was higher than in the aerobic ones, indicating an increased release of soluble microbial products (SMPs) by anaerobic microorganisms. The results indicated that carbohydrates were satisfactorily degraded and protein-like substances were the major components remaining after biological degradation of vinasse. PMID:25957273

  15. Robust regulation of anaerobic digestion processes.

    Science.gov (United States)

    Mailleret, L; Bernard, O; Steyer, J P

    2003-01-01

    This paper deals with the problem of controlling anaerobic digestion processes. A two-step (i.e. acidogenesis-methanization) mass balance model is considered for a 1 m3 fixed bed digester treating industrial wine distillery wastewater. The control law aims at regulating the organic pollution level while avoiding washout of biomass. To this end, a simple output feedback controller is considered which regulates a variable strongly related to the Chemical Oxygen Demand (COD). Numerical simulations assuming noisy measurements first illustrate the robustness of this control procedure. Then, the regulating procedure is implemented on the considered anaerobic digestion process in order to validate and demonstrate its efficiency in real life experiments. PMID:14640204

  16. Biomarkers of Microbial Metabolism for Monitoring in-situ Anaerobic PAH Degradation

    Science.gov (United States)

    Young, L.; Phelps, C.; Battistelli, J.

    2002-12-01

    Monoaromatic and polycyclic aromatic compounds found in petroleum and its products are subject to biodegradation in the absence of oxygen. These anaerobic pathways reveal novel mechanism of microbial transformation through a series of metabolites and intermediates which are unique to the anaerobic degradation process. The presence of these compounds in-situ, then conceptually can serve as indicators that anaerobic degradation is taking place. We have laboratory studies and field samples which support this concept for BTX and PAH compounds. Environments in which these anaerobic degradation processes have been observed include freshwater and estuarine sediments, groundwater from impacted aquifers at a former manufactured gas plant and gasoline station, and a creosote-contaminated aquifer. Analytical protocols were developed to detect nanomolar concentrations from soil slurries and groundwater samples and microcosm studies verified their formation from field samples and use as biomarkers of activity. Recent studies on the mechanisms of anaerobic naphthalene and methylnaphthalene metabolism have identified several unusual compounds that can serve as biomarkers for monitoring in situ PAH biodegradation. For naphthalene these include 2-naphthoic acid (2-NA), tetrahydro-2-naphthoic acid (TH-2-NA), hexahydro-2-naphthoic acid (HH-2-NA) and methylnaphthoic acid (MNA) generated by sulfate-reducing bacteria degrading naphthalene or methylnaphthalene. Groundwater samples were analyzed from wells distributed throughout an anaerobic, creosote-contaminated aquifer and also from a leaking underground storage site. Samples were extracted, derivatized and analyzed by GC/MS. The concentration of 2-NA at each monitoring well was quantified and correlated to the zones of naphthalene contamination. Taken together with measurements of the aquifer's physical characteristics, these biomarker data can be used to describe the extent of naphthalene biodegradation at these site.

  17. Caractérisation expérimentale et modélisation des effets des pratiques culturales sur la pollution nitrique d'un aquifère en zone de grande culture

    OpenAIRE

    Beaudoin, Nicolas

    2006-01-01

    Surface and groundwaters must regain good chemical and biological quality before 2015 according to European Directives. Good Agricultural Practices (GAPs) establish a compromise between the risks of pollution and the loss of revenue. The minimum result expected is conformity with the drinking water standard of 50 mgNO3.L-1 in the collected water and the avoidance of transfer of pollution from the hydrosphere into the atmosphere. However their implementation does not guarantee that these objec...

  18. Specific yield, High Plains aquifer

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This raster data set represents specific-yield ranges in the High Plains aquifer of the United States. The High Plains aquifer underlies 112.6 million acres...

  19. Particle Pollution

    Science.gov (United States)

    ... Your Health Particle Pollution Public Health Issues Particle Pollution Recommend on Facebook Tweet Share Compartir Particle pollution ... see them in the air. Where does particle pollution come from? Particle pollution can come from two ...

  20. Aquifer stability investigations

    Energy Technology Data Exchange (ETDEWEB)

    Allen, R.D.; Doherty, T.J.

    1981-09-01

    The study of compressed air energy storage (CAES) in porous rock reservoirs is carried out within the Reservoir Stability Studies Program at Pacific Northwest Laboratory. The goal of the study is to establish criteria for long-term stability of aquifer CAES reservoirs. These criteria are intended to be guidelines and check lists that utilities and architect-engineering firms may use to evaluate reservoir stability at candidate CAES sites. These criteria will be quantitative where possible, qualitative where necessary, and will provide a focal point for CAES relevant geotechnical knowledge, whether developed within this study or available from petroleum, mining or other geotechnical practices using rock materials. The Reservoir Stability Studies Program had four major activities: a state-of-the-art survey to establish preliminary stability criteria and identify areas requiring research and development; numerical modeling; laboratory testing to provide data for use in numerical models and to investigate fundamental rock mechanics, thermal, fluid, and geochemical response of aquifer materials; and field studies to verify the feasibility of air injection and recovery under CAES conditions in an aquifer, to validate and refine the stability criteria, and to evaluate the accuracy and adequacy of the numerical and experimental methodologies developed in previous work. Three phases of study, including preliminary criteria formulation, numerical model development, and experimental assessment of CAES reservoir materials have been completed. Present activity consists of construction and operation of the aquifer field test, and associated numerical and experimental work in support of that activity. Work is presently planned to be complete by 1983 at the end of the field test. At that time the final stability criteria for aquifers will be issued. Attached here also are preliminary criteria for aquifers.

  1. Anaerobic biotransformation of estrogens

    Energy Technology Data Exchange (ETDEWEB)

    Czajka, Cynthia P. [Department of Microbiology, University of Manitoba, Winnipeg, MB, R3T 2N2 (Canada); Londry, Kathleen L. [Department of Microbiology, University of Manitoba, Winnipeg, MB, R3T 2N2 (Canada)]. E-mail: londryk@cc.umanitoba.ca

    2006-08-31

    Estrogens are important environmental contaminants that disrupt endocrine systems and feminize male fish. We investigated the potential for anaerobic biodegradation of the estrogens 17-{alpha}-ethynylestradiol (EE2) and 17-{beta}-estradiol (E2) in order to understand their fate in aquatic and terrestrial environments. Cultures were established using lake water and sediment under methanogenic, sulfate-, iron-, and nitrate-reducing conditions. Anaerobic degradation of EE2 (added at 5 mg/L) was not observed in multiple trials over long incubation periods (over three years). E2 (added at 5 mg/L) was transformed to estrone (E1) under all four anaerobic conditions (99-176 {mu}g L{sup -1} day{sup -1}), but the extent of conversion was different for each electron acceptor. The oxidation of E2 to E1 was not inhibited by E1. Under some conditions, reversible inter-conversion of E2 and E1 was observed, and the final steady state concentration of E2 depended on the electron-accepting condition but was independent of the total amount of estrogens added. In addition, racemization occurred and E1 was also transformed to 17-{alpha}-estradiol under all but nitrate-reducing conditions. Although E2 could be readily transformed to E1 and in many cases 17-{alpha}-estradiol under anaerobic conditions, the complete degradation of estrogens under these conditions was minimal, suggesting that they would accumulate in anoxic environments.

  2. The anaerobic digestion process

    Energy Technology Data Exchange (ETDEWEB)

    Rivard, C.J. [National Renewable Energy Lab., Golden, CO (United States); Boone, D.R. [Oregon Graduate Inst., Portland, OR (United States)

    1996-01-01

    The microbial process of converting organic matter into methane and carbon dioxide is so complex that anaerobic digesters have long been treated as {open_quotes}black boxes.{close_quotes} Research into this process during the past few decades has gradually unraveled this complexity, but many questions remain. The major biochemical reactions for forming methane by methanogens are largely understood, and evolutionary studies indicate that these microbes are as different from bacteria as they are from plants and animals. In anaerobic digesters, methanogens are at the terminus of a metabolic web, in which the reactions of myriads of other microbes produce a very limited range of compounds - mainly acetate, hydrogen, and formate - on which the methanogens grow and from which they form methane. {open_quotes}Interspecies hydrogen-transfer{close_quotes} and {open_quotes}interspecies formate-transfer{close_quotes} are major mechanisms by which methanogens obtain their substrates and by which volatile fatty acids are degraded. Present understanding of these reactions and other complex interactions among the bacteria involved in anaerobic digestion is only now to the point where anaerobic digesters need no longer be treated as black boxes.

  3. Anaerobic biological treatment

    International Nuclear Information System (INIS)

    The Enso-Fenox process has been very successfully used to remove chlorinated phenolic compounds from pulp bleaching effluents. It is a two-stage anaerobic/aerobic process consisting of a nonmethanogenic anaerobic fluidized bed followed by a trickling filter. Studies have been conducted on reductive dechlorination of chlorinated aromatic compounds under anaerobic conditions with chlorinated phenols as the sole carbon and energy source. Approximately 40% of the added chlorophenols was converted to CH4 and CO2. Substrate loading rates were 20 mg/L/d at hydraulic detention times of 2-4 days with 90% substrate conversion efficiency. Reductive dechlorination of mono, di-, tri-, and pentachlorophenols has been demonstrated in anaerobic sewage sludge. The following constituents were tested in the laboratory at their approximate concentrations in coal conversion wastewater (CCWW) and were anaerobically degraded in serum bottles: 1,000 mg/L phenol; 500 mg/L resorcinol; 1,000 mg/L benzoic acid; 500 mg/L p-cresol; 200 mg/L pyridine; 2,000 mg/L benzoic acid; 250 mg/L 40 methylcatechol; 500 mg/L 4-ethylpyridine; and 2,000 mg/L hexanoic acid. A petrochemical may initially exhibit toxicity to an unacclimated population of methane-fermenting bacteria, but with acclimation the toxicity may be greatly reduced or disappear. In addition, the microorganisms may develop the capacity to actually degrade compounds which showed initial toxicity. Since biomass digestion requires a complete consortium of bacteria, it is relevant to study the effect of a given process as well as to individual steps within the process. A toxicant can inhibit the rate-limiting step and/or change the step that is rate-limiting. Both manifestations of toxicity can severely affect the overall process

  4. Elucidation of the thermophilic phenol biodegradation pathway via benzoate during the anaerobic digestion of municipal solid waste

    OpenAIRE

    Hoyos, C.; Hoffmann, M; Guenne, A.; Mazéas, L.

    2014-01-01

    International audience Anaerobic digestion makes it possible to valorize municipal solid waste (MSW) into biogas and digestate which are, respectively, a renewable energy source and an organic amendment for soil. Phenols are persistent pollutants present in MSW that can inhibit the anaerobic digestion process and have a toxic effect on microbiota if they are applied to soil together with digestate. It is then important to define the operational conditions of anaerobic digestion which allow...

  5. Environment Of Underground Water And Pollution

    Energy Technology Data Exchange (ETDEWEB)

    Han, Jeong Sang

    1998-02-15

    This book deals with environment of underground water and pollution, which introduces the role of underground water in hydrology, definition of related study of under water, the history of hydro-geology, basic conception of underground water such as origin of water, and hydrogeologic characteristic of aquifers, movement of underground water, hydrography of underground water and aquifer test analysis, change of an underground water level, and water balance analysis and development of underground water.

  6. Environment Of Underground Water And Pollution

    International Nuclear Information System (INIS)

    This book deals with environment of underground water and pollution, which introduces the role of underground water in hydrology, definition of related study of under water, the history of hydro-geology, basic conception of underground water such as origin of water, and hydrogeologic characteristic of aquifers, movement of underground water, hydrography of underground water and aquifer test analysis, change of an underground water level, and water balance analysis and development of underground water.

  7. EFFECT OF ANAEROBIOSIS ON FILTER MEDIA POLLUTANT RETENTION

    Science.gov (United States)

    This paper presents the results of experiments conducted to determine if four potential filter media (sand, activated carbon, peat moss, and compost) could retain previously-trapped pollutants even under anaerobic conditions. The results indicated that permanent retention of heav...

  8. Groundwater dynamics of an aquifer system dependent on the Rhine river. Development of pollutant plumes and consequences for monitoring; Grundwasserdynamik eines vom Rhein gepraegten Aquifersystems. Entwicklung von Schadstofffahnen und Konsequenzen fuer Monitoring-Ansaetze

    Energy Technology Data Exchange (ETDEWEB)

    Danzer, J.; Baumeister, S.; Olbertz, R.

    2005-06-01

    For an industrial site on the Rhine, which is typical of industrial sites in floodlands, the groundwater dynamics was modelled on a large scale in order to provide data on the local groundwater dynamics as well as the dynamics of pollutant plume formation. A monitoring programme developed on this basis enables realistic assessment of potential hazards and/or a quantification of NA processes. (orig.)

  9. Anaerobic azo dye reduction

    OpenAIRE

    Zee, van der, KG Kristoffer

    2002-01-01

    Azo dyes, aromatic moieties linked together by azo (-N=N-) chromophores, represent the largest class of dyes used in textile-processing and other industries. The release of these compounds into the environment is undesirable, not only because of their colour, but also because many azo dyes and their breakdown products are toxic and/or mutagenic to life. To remove azo dyes from wastewater, a biological treatment strategy based on anaerobic reduction of the azo dyes, followed by aerobic transfo...

  10. Management of city aquifers from anthropogenic activities: Example of the Windhoek aquifer, Namibia

    Science.gov (United States)

    Mapani, Benjamin S.; Schreiber, Ute

    As the city of Windhoek is growing rapidly, it has become increasingly obvious that dangers to the underlying groundwater aquifer have become imminent, and need addressing immediately. Water infiltration and the transportation of contaminants from anthropogenic activities through soils into the bedrock and hence the aquifer involve soil maturity, chemical and microbial processes and the climate of a particular area. The thin immature soil horizon (circa 5-20 cm) over the Windhoek schist implies that most areas of the city are built directly on bedrock, making the aquifer vulnerable. Anthropogenic activities from the use of pesticides for weed control, oil spills, toxic chemical spills, dumping of undesired substances by residents and high fertilizer application rates for lawns can lead to the contamination of groundwater. The result of our study show that the soil composition in Windhoek lacks mature clay minerals and is enriched in micas, quartz and albite. Some areas in the northern and southern industrial areas show contamination in heavy metals Pb, Zn, Cu and Ni. To the west of the city, close to the textile factory, soils are contaminated with ammonium compounds. The hydrochemistry of these pesticides and fertilizers can cause severe pollution to the groundwater if the practice is not carefully monitored. In addition, the rapid expansion of uncontrolled settlements without proper sanitation and reticulation has made the problems much more difficult. The geology of the city of Windhoek consists of the Kuiseb Schist, locally known as the “Windhoek Schist” and amphibolites. The Kuiseb schist possesses pervasive cleavage that renders the underlying lithology to be permeable to percolating water and fluids from the surface into the aquifer. The fissility and fracture density of the schist imply that leakage of surface waters, phenols, septic tank spills and industrial contaminants may reach the aquifer in unusually high rainfall years. Organic fuels and oils

  11. Subsurface storage of liquids in the Floridan aquifer system in south Florida

    Science.gov (United States)

    Meyer, Frederick W.

    1989-01-01

    The Floridan aquifer system in south Florida is composed chiefly of carbonate rocks that range in age from early Miocene to Paleocene. The top of the Floridian aquifer system generally occurs at depths ranging from 500 to 1,000 ft, and the average thickness is about 3,000 ft. It is divided into three general hydrogeologic units that include Upper Floridan aquifer, the middle confining unit, and the Lower Floridan aquifer. Groundwater movement in the Upper Floridan aquifer is generally from the area of highest head in central Florida, eastward to the Straits of Florida, westward to the Gulf of Mexico, and, to a much lesser extent, southward. Injection of nontoxic liquid wastes into deep, saline parts of the Floridan aquifer system as a pollution-control measure began in 1943 with injection of oilfield brine in southwest Florida. Since then, the practice has quickly expanded, and many high capacity municipal and industrial injection wells are now in operation in southeast Florida. The principal use of the Floridan aquifer system in south Florida is for subsurface storage of liquid waste. The Boulder Zone of the Lower Floridan aquifer is extensively used as a receptacle for injected treated municipal wastewater, oilfield brine and, to a lesser extent, industrial wastewater. Pilot studies indicate a potential for cyclic storage of freshwater in the Upper Floridan aquifer in south Florida. (USGS)

  12. Treatment of Distillery Wastewater by Anaerobic Methods

    Directory of Open Access Journals (Sweden)

    Vandana Patyal

    2015-12-01

    Full Text Available One of the major environmental problems faced by the world is management of wastes. Industrial processes create a wide range of wastewater pollutants; which are not only difficult but costly to treat. Characteristics of wastewater and level of pollutants vary significantly from industry to industry. To control this problem today emphasis is laid on waste minimization and revenue generation through by-product and energy recovery. Pollution prevention focuses on preventing the harmful effect of generated wastewater on the environment, while waste minimization refers to reducing the volume or toxicity of hazardous wastes by water recycling and reuse, process modifications and by by-product recovery. Production of ethyl alcohol in distilleries based on cane sugar molasses constitutes a major industry in Asia and South America. The world’s total production of alcohol from cane molasses is more than13 million m3 /annum. The aqueous distillery effluent stream known as spent wash is a dark brown highly organic effluent and is approximately 12-15 times by volume of the product alcohol. This highly aqueous, organic soluble containing residue is considered a troublesome and potentially polluting waste due to its extremely high BOD and COD values. Because of the high concentration of organic load, distillery spent wash is a potential source of renewable energy. The paper reviews the possibility of anaerobic treatment of the distillery wastewater.

  13. Arsenic in Groundwater: The Deep Late Pleistocene Aquifers of the Western Bengal Basin.

    Science.gov (United States)

    McArthur, J M; Ghosal, U; Sikdar, P K; Ball, J D

    2016-04-01

    in groundwaters from 145 wells across central West Bengal, India, those from Pleistocene aquifers at depths >70 m beneath paleo-interfluves contain polluted groundwater in overlying aquifers. We postulate that the As was liberated in situ by reduction of minimal iron oxyhydroxides in the gray Pleistocene sands by organic matter infiltrating from riverbeds during late Pleistocene or earliest Holocene times. Mitigation of the widespread As-pollution in shallow aquifers through exploitation of deep Pleistocene aquifers would improve if guided by an understanding of the distribution of buried paleo-channels and paleo-interfluves and the knowledge that As may be present naturally in groundwater at depths >150 m beneath deep paleo-channels. PMID:27010474

  14. New perspectives in anaerobic digestion

    DEFF Research Database (Denmark)

    van Lier, J.B.; Tilche, A.; Ahring, Birgitte Kiær;

    2001-01-01

    requirements. In fact, most advances were achieved during the last three decades, when high-rate reactor systems were developed and a profound insight was obtained in the microbiology of the anaerobic communities. This insight led to a better understanding of anaerobic treatment and, subsequently, to a broader......The IWA specialised group on anaerobic digestion (AD) is one of the oldest working groups of the former IAWQ organisation. Despite the fact that anaerobic technology dates back more than 100 years, the technology is still under development, adapting novel treatment systems to the modern...

  15. Animal and industrial waste anaerobic digestion: USA status report

    Energy Technology Data Exchange (ETDEWEB)

    Lusk, P.D. [Resource Development Associates, Washington, DC (United States)

    1996-01-01

    Pollutants from unmanaged animal and bio-based industrial wastes can degrade the environment, and methane emitted from decomposing wastes may contribute to global climate change. One waste management system prevents pollution and converts a disposal problem into a new profit center. Case studies of operating systems indicate that the anaerobic digestion of animal and industrial wastes is a commercially available bioconversion technology with considerable potential for providing profitable coproducts, including a cost-effective renewable fuel. Growth and concentration of the livestock industry create opportunities to properly dispose of the large quantities of manures generated at dairy, swine, and poultry farms. Beyond the farm, extension of the anaerobic digestion process to recover methane has considerable potential for certain classified industries - with a waste stream characterization similar to livestock manures. More than 35 example industries have been identified, and include processors of chemicals, fiber, food, meat, milk, and pharmaceuticals. Some of these industries already recover methane for energy. This status report examines some current opportunities for recovering methane from the anaerobic digestion of animal and industrial wastes in the US. Case studies of operating digesters, including project and maintenance histories, and the operator`s {open_quotes}lessons learned,{close_quotes} are included as a reality check. Factors necessary for successful projects, as well as a list of reasons explaining why some anaerobic digestion projects fail, are provided. The role of management is key; not only must digesters be well engineered and built with high-quality components, they must also be sited at facilities willing to incorporate the uncertainties of a new technology. Anaerobic digestion can provide monetary benefits and mitigate possible pollution problems, thereby sustaining development while maintaining environmental quality.

  16. A study of chlorinated solvent contamination of the aquifers of an industrial area in central Italy: a possibility of bioremediation

    Directory of Open Access Journals (Sweden)

    FEDERICA eMATTEUCCI

    2015-09-01

    Full Text Available Perchloroethene, Trichloroethene, and other chlorinated solvents are widespread groundwater pollutants. They form Dense Non Aqueous Phase Liquids (DNAPLs that sink through permeable groundwater aquifers until non-permeable zone is reached. In Italy there are many situations of serious contamination of groundwater that might compromise their use in industry, agriculture, private, as the critical case of a Central Italy valley located in the province of Teramo (Val Vibrata, characterized by a significant chlorinated solvents contamination. Data from the various monitoring campaigns that have taken place over time were collected, and new samplings were carried out, resulting in a complete database. The data matrix was processed with a multivariate statistic analysis (in particular Principal Components Analysis, PCA and was then imported into Geographic Information System (GIS, to obtain a model of the contamination. A microcosm anaerobic study was utilized to assess the potential for in situ natural or enhanced bioremediation. Most of the microcosms were positive for dechlorination, particularly those inoculated with a mineral medium. This indicate the presence of an active native dechlorinating population in the subsurface, probably inhibited by co-contaminants in the groundwater, or more likely by the absence or lack of nutritional factors. Among the tested electron donors (i.e., yeast extract, lactate, and butyrate lactate and butyrate enhanced dechlorination of chlorinated compounds. PCA and GIS studies allowed delimiting the contamination; the microcosm study helped to identify the conditions to promote the bioremediation of the area.

  17. Sole Source Aquifers for NY and NJ

    Data.gov (United States)

    U.S. Environmental Protection Agency — This layer is the designated sole source aquifers of New York and New Jersey. A Sole Source Aquifer, is an aquifer that supplies 50% or more of the drinking water...

  18. Natural attenuation processes of nitrate in a saline lake-aquifer system: Pétrola Basin (Central Spain)

    Science.gov (United States)

    Valiente, Nicolas; Menchen, Alfonso; Jirsa, Franz; Hein, Thomas; Wanek, Wolfgang; Gomez-Alday, Juan Jose

    2016-04-01

    Saline wetlands associated with intense agricultural activities in semi-arid to arid climates are among the most vulnerable environments to NO3‑ pollution. The endorheic Pétrola Basin (High Segura River Basin, Central Spain) was declared vulnerable to NO3‑ pollution by the Regional Government of Castilla-La Mancha in 1998. The hypersaline lake was classified as a heavily modified waterbody, due to the inputs of pollutants from agricultural sources and urban waste waters, the latest are discharged directly into the lake without proper treatment. Previous studies showed that the aquifer system has two main flow components: regional groundwater flow from recharge areas into the lake, and a density-driven flow from the lake to the underlying aquifer. The NO3‑ inputs derived from agriculture originate from nitrification of synthetic ammonium fertilizers, and afterwards, NO3‑ is expected to be attenuated by denitrification (up to 60%) in the saltwater-freshwater interface around the lake. However, the spatial and temporal pattern of nitrate reduction in lake sediments is not known. In this study, an isotope pairing technique was used in order to clarify the main pathways for the NO3‑ attenuation linked to the sediment-water interface. For that purpose mesocosm experiments were performed: organic-rich lake sediment (up to 23% organic carbon content) was incubated for 96 hours with the addition of 15N nitrate tracer. During the experiments two factors were modified: light and oxic conditions. Analyzing inorganic N-species (n=20) over time (72 hours) showed that NO3‑ attenuation was coupled with an increment in the NH4+ concentration (from 0.8 mg/L up to 5.3 mg/L) and a decrease in redox values (from 135.1 mV up to -422 mV) in the water column. The main outcome of this study was to elucidate the importance of different microbial pathways denitrification, dissimilatory nitrate reduction to ammonium (DNRA) and anaerobic ammonium oxidation (Anammox), in

  19. Isotope techniques in the study of the Guarani Aquifer

    International Nuclear Information System (INIS)

    The IAEA, through the Technical Cooperation Project (RLA8036), supports the application of isotope tools as part of a large international project which addresses a number of key questions in hydrolgeology and groundwater uses of the Guarani Aquifer. Groundwater constitutes around 95% of all the planet's fresh and liquid water. It is used by more than two billion people in the world and is considered as the greatest strategic reserve for the next decades. About 26% of the available freshwater in the world is in South America, and more than 50% of its population is supplied by groundwater. Low vulnerability to short climate variations places groundwater in a privileged position when societies' sustainability is evaluated. In spite of this importance, in many of our countries, groundwater resources have not received, nor receive, the attention deserved. During the last decade, the interest in South America about groundwater has grown but the few available management schemes operating in most countries are no longer adequate. As a result of a lack of adequate management schemes, ground pollution and inadequate well-head protection measures, some overexploitation (greater water extraction than the aquifer's potential) and pollution signs have been observed in some aquifers. If actions are not taken to ensure the preservation of these resources and correction measures are not adopted in critical areas, we will place at risk public and private water supply schemes, mainly in urban centres. The actions to be adopted will depend on the existing technical knowledge of the aquifers an on the countries' initiatives

  20. Comparing the value of bioproducts from different stages of anaerobic membrane bioreactors.

    Science.gov (United States)

    Khan, M A; Ngo, H H; Guo, W S; Liu, Y W; Zhou, J L; Zhang, J; Liang, S; Ni, B J; Zhang, X B; Wang, J

    2016-08-01

    The anaerobic digestion process in anaerobic membrane bioreactors is an effective way for waste management, energy sustainability and pollution control in the environment. This digestion process basically involves the production of volatile fatty acids and biohydrogen as intermediate products and methane as a final product. This paper compares the value of bioproducts from different stages of anaerobic membrane bioreactors through a thorough assessment. The value was assessed in terms of technical feasibility, economic assessment, environmental impact and impact on society. Even though the current research objective is more inclined to optimize the production of methane, the intermediate products could also be considered as economically attractive and environment friendly options. Hence, this is the first review study to correlate the idea into an anaerobic membrane bioreactor which is expected to guide future research pathways regarding anaerobic process and its bioproducts. PMID:27233838

  1. The vulnerability of the free aquifers using functions of time of trip

    International Nuclear Information System (INIS)

    The determination of an aquifers vulnerability degree represents a support instrument for hydraulic resources management. It is also important for territory ordering and planning because it guarantors groundwater conservation. Achieving the determination of procedures for vulnerability maps construction, using measurable parameters, integrated as a function, is a practical methodology with very important and vantages over traditional methodologies. It is considered that the pollutant trip time from the surface to the aquifers is a good vulnerability indicator

  2. Anaerobic Treatment of Agricultural Residues and Wastewater - Application of High-Rate Reactors

    OpenAIRE

    Parawira, Wilson

    2004-01-01

    The production of methane via anaerobic digestion of agricultural residues and industrial wastewater would benefit society by providing a clean fuel from renewable feedstocks. This would reduce the use of fossil-fuel-derived energy and reduce environmental impact, including global warming and pollution. Limitation of carbon dioxide and other emissions through emission regulations, carbon taxes, and subsidies on biomass energy is making anaerobic digestion a more attractive and competitive tec...

  3. State Detection and Feedback Control of the Anaerobic Wastewater Treatment Using Fuzzy Logic

    OpenAIRE

    Murnleitner, Ernst

    2005-01-01

    Anaerobic treatment of wastewater offers the advantage of the elimination of the main part of pollutants, which saves disposal charges. Compared to the aerobic technology, less sludge is formed, and energy is produced in the form of biogas. However, anaerobic treatment has also several drawbacks. These are the more difficult handling and the extreme long characteristical times, whereby particularly an overload can lead to a complete break-down of the plant. A restart takes weeks to months, wh...

  4. Timeline of bio-hydrogen production by anaerobic digestion of biomass

    OpenAIRE

    Bernadette E. TELEKY; Mugur C. BĂLAN; Nikolausz, Marcell

    2015-01-01

    Anaerobic digestion of biomass is a process capable to produce biohydrogen, a clean source of alternative energy. Lignocellulosic biomass from agricultural waste is considered a renewable energy source; therefore its utilization also contributes to the reduction of water, soil and air pollution. The study consists in five consecutive experiments designed to utilize anaerobic bacterial enrichment cultures originating from the Hungarian Lake, Hévíz. Wheat straw was used as com...

  5. Anaerobic wastewater treatment using anaerobic baffled bioreactor: a review

    Science.gov (United States)

    Hassan, Siti; Dahlan, Irvan

    2013-09-01

    Anaerobic wastewater treatment is receiving renewed interest because it offers a means to treat wastewater with lower energy investment. Because the microorganisms involved grow more slowly, such systems require clever design so that the microbes have sufficient time with the substrate to complete treatment without requiring enormous reactor volumes. The anaerobic baffled reactor has inherent advantages over single compartment reactors due to its circulation pattern that approaches a plug flow reactor. The physical configuration of the anaerobic baffled reactor enables significant modifications to be made; resulting in a reactor which is proficient of treating complex wastewaters which presently require only one unit, ultimately significant reducing capital costs. This paper also concerns about mechanism, kinetic and hydrodynamic studies of anaerobic digestion for future application of the anaerobic baffled reactor for wastewater treatment.

  6. High Temperature Aquifer Storage

    Science.gov (United States)

    Ueckert, Martina; Niessner, Reinhard; Baumann, Thomas

    2016-04-01

    Combined heat and power generation (CHP) is highly efficient because excess heat is used for heating and/or process energy. However, the demand of heat energy varies considerably throughout the year while the demand for electrical energy is rather constant. It seems economically and ecologically highly beneficial for municipalities and large power consumers such as manufacturing plants to store excess heat in groundwater aquifers and to recuperate this energy at times of higher demand. Within the project High Temperature Aquifer Storage, scientists investigate storage and recuperation of excess heat energy into the bavarian Malm aquifer. Apart from high transmissivity and favorable pressure gradients, the hydrochemical conditions are crucial for long-term operation. An enormous technical challenge is the disruption of the carbonate equilibrium - modeling results indicated a carbonate precipitation of 10 - 50 kg/d in the heat exchangers. The test included five injection pulses of hot water (60 °C up to 110 °C) and four tracer pulses, each consisting of a reactive and a conservative fluorescent dye, into a depth of about 300 m b.s.l. resp. 470 m b.s.l. Injection and production rates were 15 L/s. To achieve the desired water temperatures, about 4 TJ of heat energy were necessary. Electrical conductivity, pH and temperature were recorded at a bypass where also samples were taken. A laboratory container at the drilling site was equipped for analysing the concentration of the dyes and the major cations at sampling intervals of down to 15 minutes. Additional water samples were taken and analysed in the laboratory. The disassembled heat exchanger prooved that precipitation was successfully prevented by adding CO2 to the water before heating. Nevertheless, hydrochemical data proved both, dissolution and precipitation processes in the aquifer. This was also suggested by the hydrochemical modelling with PhreeqC and is traced back to mixture dissolution and changing

  7. Contribution to the study of Arapey Salto-Aquifer System (Department of Salto - Uruguay)

    International Nuclear Information System (INIS)

    This paper provide hydrogeological data about the Salto Arapey aquifer system constituted by sedimentary deposits and fisurate effusive rocks, respectively Tertiary and Cretacic aged. The information belongs to an area located at latitude South 31º20' West. North of the Salto city (NW of Uruguay) 500 km away from Montevideo. A regional aquifer system can be defined where the biggest flows are originated in the basaltic fisurate d rocks of the Arapey formation. Environment features are also considered and data about the main polluting agents - both organic and inorganic ones- are provided, bearing in mind that they justify an urgent safety design to protect the aquifer system

  8. La pollution du bassin de la Seine par les nitrates : Comprendre l'origine et la migration des nitrates dans l'écosystème pour mieux protéger les aquifères

    OpenAIRE

    Ledoux, Emmanuel; Monget, Jean Marie; Schott, Céline; Garnier, Cécile; Beaudoin, Nicolas

    2009-01-01

    Le cycle de l’azote est aujourd’hui, à l’échelle de la planète, le plus profondément perturbé des grands cycles biogéochimiques. L’azote qui entre à 80 % dans la composition de l’atmosphère se transforme en nitrates dans les sols. Une partie de ces nitrates est ensuite entraînée vers les eaux de surface et souterraines. Ce phénomène – absolument naturel – a été fortement amplifié par l’utilisation d’engrais de synthèse depuis le milieu du XXe siècle. Cinquante ans plus tard, la pollution croi...

  9. High Temperature Aquifer Storage

    Science.gov (United States)

    Ueckert, Martina; Niessner, Reinhard; Baumann, Thomas

    2015-04-01

    Combined heat and power generation (CHP) is highly efficient because excess heat is used for heating and/or process energy. However, the demand of heat energy varies considerably throughout the year while the demand for electrical energy is rather constant. It seems economically and ecologically highly beneficial for municipalities and large power consumers such as manufacturing plants to store excess heat in groundwater aquifers and to recuperate this energy at times of higher demand. Apart from the hydrogeological conditions, high transmissivity and favorable pressure gradients, the hydrochemical conditions are crucial for long-term operation. Within the project High Temperature Aquifer Storage, scientists investigate storage and recuperation of excess heat energy into the bavarian Malm aquifer. After one year of planning, construction, and the successful drilling of a research well to 495 m b.s.l. the first large scale heat storage test in the Malm aquifer was finished just before Christmas 2014. An enormous technical challenge was the disruption of the carbonate equilibrium - modeling results indicated a carbonate precipitation of 10-50 kg/d in the heat exchangers. The test included five injection pulses of hot water (60 °C up to 110 °C) and four tracer pulses, each consisting of a reactive and a conservative fluorescent dye. Injection and production rates were 15 L/s. About 4 TJ of heat energy were necessary to achieve the desired water temperatures. Electrical conductivity, pH and temperature were recorded at a bypass where also samples were taken. A laboratory container at the drilling site was equipped for the analysis of the concentration of the tracers and the cation concentrations at sampling intervals of down to 15 minutes. Additional water samples were taken and analyzed for major ions and trace elements in the laboratory. The disassembled heat exchanger proved that precipitation was successfully prevented by adding CO2 to the water before heating

  10. Molecular characterization of anaerobic dehalogenation by Desulfitobacterium dehalogenans

    OpenAIRE

    Smidt, H.

    2001-01-01

    Haloorganics such as chlorophenols and chlorinated ethenes are among the most abundant pollutants in soil, sediments and groundwater, mainly caused by past and present industrial and agricultural activities. Due to bioaccumulation and toxicity, these compounds threaten the integrity of the environment, and human and animal health. A recently discovered, phylogenetically diverse, group of anaerobic so-called halorespiring bacteria is able to couple the reductive dehalogenation of various haloo...

  11. Degradation of BTEX by anaerobic bacteria: physiology and application

    OpenAIRE

    Weelink, S.A.B.; Eekert, van, M.H.A.; Stams, A.J.M.

    2010-01-01

    Pollution of the environment with aromatic hydrocarbons, such as benzene, toluene, ethylbenzene and xylene (so-called BTEX) is often observed. The cleanup of these toxic compounds has gained much attention in the last decades. In situ bioremediation of aromatic hydrocarbons contaminated soils and groundwater by naturally occurring microorganisms or microorganisms that are introduced is possible. Anaerobic bioremediation is an attractive technology as these compounds are often present in the a...

  12. Techniques for anaerobic susceptibility testing.

    Science.gov (United States)

    Thornsberry, C

    1977-03-01

    Minimal inhibitory concentrations (MICs) of antimicrobial agents for anaerobic bacteria can be determined by agar dilution and broth dilution (including microdilution) techniques. If MICs are not determined routinely, the disk broth or category methods are recommended for routine use. The Bauer-Kirby disk diffusion method and its interpretative standards should not be used for anaerobes. PMID:850089

  13. Anaerobic Digestion of Piggery Waste

    NARCIS (Netherlands)

    Velsen, van A.F.M.

    1981-01-01

    Anaerobic digestion is a biological process by which organic matter is converted to methane and carbon dioxide by microbes in the absence of air (oxygen). In nature, anaerobic conversions occur at all places where organic material accumulates and the supply of oxygen is deficient, e.g. in marshes an

  14. Groundwater vulnerability mapping in Guadalajara aquifers system (Western Mexico)

    Science.gov (United States)

    Rizo-Decelis, L. David; Marín, Ana I.; Andreo, Bartolomé

    2016-04-01

    Groundwater vulnerability mapping is a practical tool to implement strategies for land-use planning and sustainable socioeconomic development coherent with groundwater protection. The objective of vulnerability mapping is to identify the most vulnerable zones of catchment areas and to provide criteria for protecting the groundwater used for drinking water supply. The delineation of protection zones in fractured aquifers is a challenging task due to the heterogeneity and anisotropy of hydraulic conductivities, which makes difficult prediction of groundwater flow organization and flow velocities. Different methods of intrinsic groundwater vulnerability mapping were applied in the Atemajac-Toluquilla groundwater body, an aquifers system that covers around 1300 km2. The aquifer supplies the 30% of urban water resources of the metropolitan area of Guadalajara (Mexico), where over 4.6 million people reside. Study area is located in a complex neotectonic active volcanic region in the Santiago River Basin (Western Mexico), which influences the aquifer system underneath the city. Previous works have defined the flow dynamics and identified the origin of recharge. In addition, the mixture of fresh groundwater with hydrothermal and polluted waters have been estimated. Two main aquifers compose the multilayer system. The upper aquifer is unconfined and consists of sediments and pyroclastic materials. Recharge of this aquifer comes from rainwater and ascending vertical fluids from the lower aquifer. The lower aquifer consists of fractured basalts of Pliocene age. Formerly, the main water source has been the upper unit, which is a porous and unconsolidated unit, which acts as a semi-isotropic aquifer. Intense groundwater usage has resulted in lowering the water table in the upper aquifer. Therefore, the current groundwater extraction is carried out from the deeper aquifer and underlying bedrock units, where fracture flow predominates. Pollution indicators have been reported in

  15. Deploying anaerobic digesters: Current status and future possibilities

    Energy Technology Data Exchange (ETDEWEB)

    Lusk, P. [International Energy Agency, Paris (France); Wheeler, P. [ETSU (United Kingdom); Rivard, C. [National Renewable Energy Lab., Golden, CO (United States)

    1996-01-01

    Unmanaged pollutants from putrescible farm, industrial, and municipal wastes degrade in the environment, and methane emitted from their decomposition may contribute to global climate change. Under modern environmental regulations, these wastes are becoming difficult to dispose of using traditional means. One waste management system, anaerobic digestion or AD, not only provides pollution prevention but can also convert a disposal problem into a new profit center. This report is drawn from a special session of the Second Biomass Conference of the Americas. Selected papers are indexed separately for inclusion in the Energy Science and Technology Database.

  16. Noise Pollution

    Science.gov (United States)

    ... EPA Home Air and Radiation Noise Pollution Noise Pollution This page has moved. You should be immediately ... gov/clean-air-act-overview/title-iv-noise-pollution Local Navigation Air & Radiation Home Basic Information Where ...

  17. Water Pollution

    Science.gov (United States)

    Bowen, H. J. M.

    1975-01-01

    Deals with water pollution in the following categories: a global view, self purification, local pollution, difficulties in chemical analysis, and remedies for water pollution. Emphasizes the extent to which man's activities have modified the cycles of certain elements. (GS)

  18. Air Pollution

    Science.gov (United States)

    Air pollution is a mixture of solid particles and gases in the air. Car emissions, chemicals from factories, dust, ... a gas, is a major part of air pollution in cities. When ozone forms air pollution, it's ...

  19. Noise Pollution

    Science.gov (United States)

    ... Overview » Title IV - Noise Pollution Title IV - Noise Pollution The 1990 Clean Air Act Amendments added a ... abatement 7642 Authorization of appropriations What is Noise Pollution? The traditional definition of noise is “unwanted or ...

  20. Air Pollution

    Science.gov (United States)

    Air pollution is a mixture of solid particles and gases in the air. Car emissions, chemicals from factories, dust, pollen and ... Ozone, a gas, is a major part of air pollution in cities. When ozone forms air pollution, ...

  1. Anaerobic fungal populations

    International Nuclear Information System (INIS)

    The development of molecular techniques has greatly broadened our view of microbial diversity and enabled a more complete detection and description of microbial communities. The application of these techniques provides a simple means of following community changes, for example, Ishii et al. described transient and more stable inhabitants in another dynamic microbial system, compost. Our present knowledge of anaerobic gut fungal population diversity within the gastrointestinal tract is based upon isolation, cultivation and observations in vivo. It is likely that there are many species yet to be described, some of which may be non-culturable. We have observed a distinct difference in the ease of cultivation between the different genera, for example, Caecomyes isolates are especially difficult to isolate and maintain in vitro, a feature that is likely to result in the under representation of this genera in culture-based enumerations. The anaerobic gut fungi are the only known obligately anaerobic fungi. For the majority of their life cycles, they are found tightly associated with solid digesta in the rumen and/or hindgut. They produce potent fibrolytic enzymes and grow invasively on and into the plant material they are digesting making them important contributors to fibre digestion. This close association with intestinal digesta has made it difficult to accurately determine the amount of fungal biomass present in the rumen, with Orpin suggesting 8% contribution to the total microbial biomass, whereas Rezaeian et al. more recently gave a value of approximately 20%. It is clear that the rumen microbial complement is affected by dietary changes, and that the fungi are more important in digestion in the rumens of animals fed with high-fibre diets. It seems likely that the gut fungi play an important role within the rumen as primary colonizers of plant fibre, and so we are particularly interested in being able to measure the appearance and diversity of fungi on the plant

  2. Characterization of the vadose zone above a shallow aquifer contaminated with gas condensate hydrocarbons

    International Nuclear Information System (INIS)

    A gas production site in the Denver Basin near Ft. Lupton, Colorado has leaked gas condensate hydrocarbons from an underground concrete tank used to store produced water. The leak has contaminated a shallow aquifer. Although the source of pollution has been removed, a plume of hydrocarbon contamination still remains for nearly 46 m from the original source. An extensive monitoring program was conducted in 1993 of the groundwater and saturated sediments. The objective was to determine if intrinsic aerobic or anaerobic bioremediation of hydrocarbons occurred at the site at a rate that would support remediation. Geochemical indicators of hydrogen biodegradation by microorganisms in the saturated zone included oxygen depletion, increased alkalinity, sulfate depletion, methane production and Fe2+ production associated with hydrogen contamination. The presence of sulfate-reducing bacteria and methanogens was also much higher in the contaminated sediments. Degraded hydrocarbon metabolites were found in contaminated groundwater. An extensive characterization of the vadose zone was conducted in which the vadose zone was sample in increments of 15 cm from the surface to the water table at contaminated and non contaminated sites. The samples were tested for individual C3+ hydrocarbons, methane, CO2, total organic carbon, total inorganic carbon, and total petroleum hydrocarbons. The vadose zone consisted of an active and aerobic bioreactor fueled by condensate hydrocarbons transported into the unsaturated zone by evaporation of hydrocarbons at the water table. It was concluded that the unsaturated zone makes an important contribution to the natural attenuation of gas condensate hydrocarbons in the area. 17 refs., 2 tabs., 28 figs

  3. Winter meeting on ground water pollution

    International Nuclear Information System (INIS)

    At the winter meeting 1995 pollution from the most usual waste disposal sites was discussed: pesticides, chlorinated solvents, sanitary landfills and tar. Transport and biodegradation of pesticides and chlorinated solvents in soils, aquifers and ground water, and remediation means were considered on basis of the Danish and foreign experience. (EG)

  4. Integrating the Sciences to Investigate Groundwater Pollution

    Science.gov (United States)

    Grady, Julie R.; Madden, Andrew S.

    2010-01-01

    Investigations that integrate concepts from geological sciences with biology and chemistry are rare. The authors present an investigation that introduces high school students to microbe-mineral interactions by tying together anaerobic respiration, reduction reactions, metal ion solubility, and groundwater pollution. During the investigation,…

  5. Biodegradation of cresol isomers in anoxic aquifers

    Energy Technology Data Exchange (ETDEWEB)

    Smolenski, W.J.; Suflita, J.M.

    1987-04-01

    The biodegradation of o-, m-, and p-cresol was examined in material obtained from a shallow anaerobic alluvial sand aquifer. The cresol isomers wer preferentially metabolized, with p-cresol being the most easily degraded. m-Cresol was more persistent than the para-isomer, and o-cresol persisted for over 90 days. Biodegradations of cresol isomers was favored under sulfate-reducing conditions (SRC) compared with that under methanogenic conditions (MC). Slurries that were acclimated to p-cresol metabolism transformed this substrate at 18 and 330 nmol/h per g (dry weight) for MC and SRC, respectively. Inhibition of electron flow to sulfate reduction with 2.0 mM molybdate reduced p-cresol metabolism in incubations containing sulfate. When methanogenesis was blocked with 5 mM bromoethanesulfonic acid in incubations lacking sulfate, p-cresol catabolism was retarded. Under SRC 3.4 mol of sulfate was consumed per mol of p-cresol metabolized. The addition of sulfate to methanogenic incubations stimulated p-cresol degradation. Simultaneous adaptation studies in combination with spectrophotometric and chromatographic analysis of metabolites indicated that p-cresol was oxidized under SRC to p-hydroxybenzoate via the corresponding alcohol and aldehyde. This series of reactions was inhibited under sulfate-limited or aerobic conditions. Therefore, the primary catabolic event for p-cresol decomposition under SRC appears to involve the hydroxylation of the aryl methyl group.

  6. Parotitis due to anaerobic bacteria.

    Science.gov (United States)

    Matlow, A; Korentager, R; Keystone, E; Bohnen, J

    1988-01-01

    Although Staphylococcus aureus remains the pathogen most commonly implicated in acute suppurative parotitis, the pathogenic role of gram-negative facultative anaerobic bacteria and strict anaerobic organisms in this disease is becoming increasingly recognized. This report describes a case of parotitis due to Bacteroides disiens in an elderly woman with Sjögren's syndrome. Literature reports on seven additional cases of suppurative parotitis due to anaerobic bacteria are reviewed. Initial therapy of acute suppurative parotitis should include coverage for S. aureus and, in a very ill patient, coverage of gram-negative facultative organisms with antibiotics such as cloxacillin and an aminoglycoside. A failure to respond clinically to such a regimen or isolation of anaerobic bacteria should lead to the consideration of the addition of clindamycin or penicillin. PMID:3287567

  7. Mississippi River Valley alluvial aquifer

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set represents the extent of the Mississippi River Valley alluvial aquifer in the states of Missouri, Kentucky, Tennessee, Arkansas, Mississippi, and...

  8. Southeastern Coastal Plain aquifer system

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set represents the extent of the Southeastern Coastal Plain aquifer system in Kentucky, Tennessee, Mississippi, Alabama, Georgia, and South Carolina.

  9. Region 9 Sole Source Aquifers

    Data.gov (United States)

    U.S. Environmental Protection Agency — There are 7 polygons representing 6 individual sole source aquifer boundaries and one streamflow source area in California, Arizona, and Nevada. Various efforts...

  10. (SUPERCEDED) High Plains aquifer (SUPERCEDED)

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set represents the extent of the High Plains aquifer in the states of South Dakota, Wyoming, Nebraska, Colorado, Kansas, New Mexico, Oklahoma, and Texas....

  11. Digital data sets that describe aquifer characteristics of the Enid isolated terrace aquifer in northwestern Oklahoma

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set consists of digitized aquifer boundaries for the Enid isolated terrace aquifer in northwestern Oklahoma. The Enid isolated terrace aquifer covers...

  12. Digital data sets that describe aquifer characteristics of the Elk City aquifer in western Oklahoma

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set consists of digitized aquifer boundaries for the Elk City aquifer in western Oklahoma. The aquifer covers an area of approximately 193,000 acres and...

  13. Recovery of energetically overexploited urban aquifers using surface water

    Science.gov (United States)

    García-Gil, Alejandro; Vázquez-Suñé, Enric; Sánchez-Navarro, José Ángel; Mateo Lázaro, Jesús

    2015-12-01

    Shallow aquifers have an important role in reducing greenhouse gases through helping manage the temperature of urban environments. Nevertheless, the uncontrolled rapid use of shallow groundwater resources to heat or cool urban environments can cause thermal pollution that will limit the long term sustainability of the resource. Therefore, there is a need for appropriate mitigation/remediation strategies capable of recovering energetically overexploited aquifers. In this work, a novel remediation strategy based on surface water recharge into aquifers is presented. To evaluate the capabilities of such measures for effective remediation, this strategy is optimized for a management problem raised in the overheated "Urban Alluvial Aquifer of Zaragoza" (Spain). The application of a transient groundwater flow and heat transport model under 512 different mitigation scenarios has enabled to quantify and discuss the magnitude of the remediation effect as a respond to injection rates of surface water, seasonal schedule of the injection and location of injection. The quantification of the relationship between these variables together with the evaluation of the amount of surface water injected per year in each scenario proposed have provided a better understanding of the system processes and an optimal management alternative. This work also makes awareness of the magnitude of the remediation procedure which is in an order of magnitude of tenths of years.

  14. Fertilizer standards for controlling groundwater nitrate pollution from agriculture: El Salobral-Los Llanos case study, Spain

    OpenAIRE

    S. Peña-Haro; Llopis-Albert, C.; M. Pulido-Velazquez; Pulido-Velazquez, D.

    2010-01-01

    Although the legislation on groundwater quality targets pollutant concentration, the effects of measures on non-point source pollution control are often evaluated in terms of their emission reduction potential at the source, not on their capacity of reducing the pollutant concentration in groundwater. This paper applies a hydro-economic modelling framework to an aquifer, El Salobral-Los Llanos aquifer (Mancha Oriental, Spain), where nitrate concentrations higher than those allowed by the EU W...

  15. Evaluation of ethyl tert-butyl ether biodegradation in a contaminated aquifer by compound-specific isotope analysis and in situ microcosms

    Energy Technology Data Exchange (ETDEWEB)

    Bombach, Petra, E-mail: petra.bombach@ufz.de [UFZ – Helmholtz Centre for Environmental Research, Department of Isotope Biogeochemistry, Permoserstrasse 15, D-04318 Leipzig (Germany); Isodetect GmbH Leipzig, Deutscher Platz 5b, D-04103 Leipzig (Germany); Nägele, Norbert [Kuvier the Biotech Company S.L., Ctra. N-I, p.k. 234–P.E. INBISA 23" a, E-09001 Burgos (Spain); Rosell, Mònica [UFZ – Helmholtz Centre for Environmental Research, Department of Isotope Biogeochemistry, Permoserstrasse 15, D-04318 Leipzig (Germany); Grup de Mineralogia Aplicada i Medi Ambient, Departament de Cristallografia, Mineralogia i Dipòsits Minerals, Facultat de Geologia, Universitat de Barcelona (UB), C/Martí i Franquès s/n, 08028 Barcelona (Spain); Richnow, Hans H. [UFZ – Helmholtz Centre for Environmental Research, Department of Isotope Biogeochemistry, Permoserstrasse 15, D-04318 Leipzig (Germany); Fischer, Anko [Isodetect GmbH Leipzig, Deutscher Platz 5b, D-04103 Leipzig (Germany)

    2015-04-09

    Highlights: • In situ biodegradation of ETBE was investigated in a fuel contaminated aquifer. • Degradation was studied by CSIA and in situ microcosms in combination with TLFA-SIP. • ETBE was degraded when ETBE was the main groundwater contaminant. • ETBE was also degraded in the presence of BTEX and MTBE. • Hydrochemical analysis indicated aerobic and anaerobic ETBE biodegradation. - Abstract: Ethyl tert-butyl ether (ETBE) is an upcoming groundwater pollutant in Europe whose environmental fate has been less investigated, thus far. In the present study, we investigated the in situ biodegradation of ETBE in a fuel-contaminated aquifer using compound-specific stable isotope analysis (CSIA), and in situ microcosms in combination with total lipid fatty acid (TLFA)-stable isotope probing (SIP). In a first field investigation, CSIA revealed insignificant carbon isotope fractionation, but low hydrogen isotope fractionation of up to +14‰ along the prevailing anoxic ETBE plume suggesting biodegradation of ETBE. Ten months later, oxygen injection was conducted to enhance the biodegradation of petroleum hydrocarbons (PH) at the field site. Within the framework of this remediation measure, in situ microcosms loaded with [{sup 13}C{sub 6}]-ETBE (BACTRAP{sup ®}s) were exposed for 119 days in selected groundwater wells to assess the biodegradation of ETBE by TLFA-SIP under the following conditions: (i) ETBE as main contaminant; (ii) ETBE as main contaminant subjected to oxygen injection; (iii) ETBE plus other PH; (iv) ETBE plus other PH subjected to oxygen injection. Under all conditions investigated, significant {sup 13}C-incorporation into microbial total lipid fatty acids extracted from the in situ microcosms was found, providing clear evidence of ETBE biodegradation.

  16. Risk assesment of an urban aquifer based on environmental tracers

    Directory of Open Access Journals (Sweden)

    Branka Trček

    2013-06-01

    Full Text Available Groundwater from a Pleistocene sandy-gravel aquifer is a drinking water resource for the Union brewery, located nearthe centre of Ljubljana (Slovenia. A large part of the aquifer recharge area is highly urbanized, which represents a greatrisk for the groundwater quality assurance. The groundwater dating techniques were used to study the contaminationrisk of this drinking-water resource. The application of chlorofluorocarbons (CFCs, sulphur hexafluoride (SF6 andtritium-helium-3 (3H-3He age indicator was tested, as they haven’t been used in Slovene urban areas so far. The resultsreflect that the 3H-3He dating technique is the most suitable for a groundwater age determination in the study urbanaquifer, since SF6 and particularly CFCs concentrations could be affected by the local contaminations. They indicatedthat average groundwater residence times range from 10 to 30 years. Boreholes that are more distant from the Ši{enskihrib hill are more vulnerable to contamination due to flow of young groundwater from a direction of the main aquifer,which is exposed to the urban pollution. The presented results were supplemented with chemical investigations ofgroundwater organic pollutants. An unknown trace organic pollutant with a base ion mass-to-charge ratio 147 was putinto focus. Its identification based on chromatographic separation and a mass spectrometric detection with GC-MS,LC-MS and LC-TOF MS techniques. The newly detected trace organic pollutant in sampled groundwater representstogether with the 3H and 3He data a new technique to study the flow paths and contaminant transport in the urbanaquifer in both, the lateral and vertical directions.

  17. Environmental assessment of the potential effects of aquifer thermal energy storage systems on microorganisms in groundwater

    Energy Technology Data Exchange (ETDEWEB)

    Hicks, R.J.; Stewart, D.L.

    1988-03-01

    The primary objective of this study was to evaluate the potential environmental effects (both adverse and beneficials) of aquifer thermal energy storage (ATES) technology pertaining to microbial communities indigenous to subsurface environments (i.e., aquifers) and the propagation, movement, and potential release of pathogenic microorganisms (specifically, Legionella) within ATES systems. Seasonal storage of thermal energy in aquifers shows great promise to reduce peak demand; reduce electric utility load problems; contribute to establishing favorable economics for district heating and cooling systems; and reduce pollution from extraction, refining, and combustion of fossil fuels. However, concerns that the widespread implementation of this technology may have adverse effects on biological systems indigeneous to aquifers, as well as help to propagate and release pathogenic organisms that enter thee environments need to be resolved. 101 refs., 2 tabs.

  18. Heat Transport Modeling in an Aquifer Downgradient a Municipal Solid Waste Landfill in Italy

    Directory of Open Access Journals (Sweden)

    Rajandrea Sethi

    2007-01-01

    Full Text Available Heat generation inside municipal solid waste (MSW landfills is due to aerobic and anaerobic exothermic reactions occurring inside the waste. The result of heat generation and transport inside sanitary landfill leads to a temperature field that varies from mesophylic range (optimum at 30 40 °C to thermophylic range (optimum at 50-60 °C. Due to high temperatures at the bottom of the landfill, liner systems can be severely damaged. The increment in convective and conductive heat transport could lead to an increase of the temperature in the surrounding geological layers and in the underlying aquifer. Hydrodynamic thermodispersion and convection are the most important mechanisms of heat transport in saturated porous medium with a moving fluid such as aquifer systems. The aim of the study is to model and investigate the origin of a thermal anomaly in the aquifer underneath a municipal landfill in the North of Italy. In order to model the system a detailed experimental analysis was conducted inside the landfill, measuring the temperature of the biogas and leachate, and in the aquifer system measuring the temperature in monitoring wells and conducting a constant rate pumping test. Heat transport model has been exploited using the analogy between heat and mass transport in porous media. The model showed that the thermal anomaly is due to convective and conductive heat transport from the landfill to the aquifer.

  19. In situ biorestoration of contaminated aquifers and hazardous waste sites in Texas

    International Nuclear Information System (INIS)

    Texas is one of the nation's most polluted states, and its aquifers are at risk from contamination by numerous industrial and hazardous waste sites (Texas Water Commission, 1989). Because ground water supplies a significant amount of drinking water for the state, contamination of Texas aquifer is a major concern. One method that is sometimes used to remediate contaminated ground water and subsurface materials is in situ bioremediation (ISB). This paper discusses ISB and its potential application to remediate ground water and subsurface materials in Texas. To assess application of ISB in Texas, aquifer characteristics and ground water to pollution as well as the location of possible contamination sources are determined to locate those areas of the state that are at risk from ground water contamination

  20. Anaerobic treatment of sulfate-containing wastewater from distilleries

    International Nuclear Information System (INIS)

    Bioprocess evaluation of a staged arrangement of a Pulse Driven Loop Reaktor (PDLR) and a Pulsed Anaerobic Filter (PAF) using highly polluted cherry slops as industrial wastewater shows a COD removal efficiency of 80-90% at loading rates of 8-4 kg COD/(M3.d). Contamination of cherry slops by sulfate (2 g/l) and copper (150-200 mg/l) reduces COD degradation to 40-50 percent. A pulsed anaerobic baffled reactor was envisaged as a corrective tool to improve mineralisation in the presence of sulfate-rich substrates by confining sulfate reducing bacteria to the first 4 chambers of the reactor. Phasing slightly improves COD degradation yield, but is not sufficient for stable process performance. Consequently, the use of lactic acid in stead of sulfuric acid in cherry-fermentation was suggested as a preventive method to avoid sulphide-induced digester failure. (orig.)

  1. Water pollution

    OpenAIRE

    Institute, Marine

    2013-01-01

    Students will learn about what causes water pollution and how to be environmentally aware. *Note: Students should understand the concept of the water cycle before moving onto water pollution (see Lesson Plan “Oceans all Around Us”).

  2. Water quality and nitrogen mass loss from anaerobic lagoon columns receiving pretreated influent

    Science.gov (United States)

    Control methods are needed to abate ammonia losses from swine anaerobic lagoons to reduce contribution of confined swine operations to air pollution. In a 15-month meso-scale column study, we evaluated the effect of manure pretreatment on water quality, reduction of N losses, and sludge accumulation...

  3. Ecology and biogeography of bacterial communities associated with chloroethene-contaminated aquifers

    Directory of Open Access Journals (Sweden)

    PierreRossi

    2012-07-01

    Full Text Available Massive usage, along with careless handling, storage, spills and leakages made chloroethenes (CEs one of the most abundant classes of groundwater contaminants. Anaerobic organohalide-respiring bacteria (OHRB can couple reductive dechlorination of CEs with energy conservation, a central microbial process in (enhanced natural attenuation of CE-contaminated aquifers. Spatial variability of OHRB guild members present in contaminated sites has not yet been investigated in detail and it is not known whether the spatial localization of contaminated sites could impact differentially remediation capacities. The goal of this study was to investigate how spatially-distant microbial communities responded to the presence of CEs. Bacterial communities associated with five geographically distant European CEs-contaminated aquifers were analyzed with terminal-restriction fragment length polymorphism. Numerical ecology tools were used to assess the separate and combined effects on the communities of their spatial localization, their local environmental conditions and their contaminant concentrations. Three spatial scales were used for the assessment of the structuration of the communities as a function of geographical distances, namely at the aquifer scale, at medium (50 km and long (ca. 1000 km distances between aquifers. As a result, bacterial communities were structured with an almost identical contribution by both the geographical position of the aquifer and local environmental variables, especially electron donors and acceptors. The impact of environmental factors decreased with distance between aquifers, with the concomitant increase in importance of a geographical factor. Contrastingly, CEs contributed at a low extent at the medium scale and became important only when all aquifers were considered together, at a large geographical scale, suggesting that distant communities were structured partially by a common niche specialization in organohalide

  4. Air Pollution.

    Science.gov (United States)

    Barker, K.; And Others

    Pollution of the general environment, which exposes an entire population group for an indeterminate period of time, certainly constitutes a problem in public health. Serious aid pollution episodes have resulted in increased mortality and a possible relationship between chronic exposure to a polluted atmosphere and certain diseases has been…

  5. ADAPTATIONS OF INDIGENOUS BACTERIA TO FUEL CONTAMINATION IN KARST AQUIFERS IN SOUTH-CENTRAL KENTUCKY

    Science.gov (United States)

    Byl, Thomas D.; Metge, David W.; Daniel T. Agymang; Bradley, Michael W.; Hileman, Gregg; Harvey, Ronald W.

    2014-01-01

    The karst aquifer systems in southern Kentucky can be dynamic and quick to change. Microorganisms that live in these unpredictable aquifers are constantly faced with environmental changes. Their survival depends upon adaptations to changes in water chemistry, taking advantage of positive stimuli and avoiding negative environmental conditions. The U.S. Geological Survey conducted a study in 2001 to determine the capability of bacteria to adapt in two distinct regions of water quality in a karst aquifer, an area of clean, oxygenated groundwater and an area where the groundwater was oxygen depleted and contaminated by jet fuel. Water samples containing bacteria were collected from one clean well and two jet fuel contaminated wells in a conduit-dominated karst aquifer. Bacterial concentrations, enumerated through direct count, ranged from 500,000 to 2.7 million bacteria per mL in the clean portion of the aquifer, and 200,000 to 3.2 million bacteria per mL in the contaminated portion of the aquifer over a twelve month period. Bacteria from the clean well ranged in size from 0.2 to 2.5 mm, whereas bacteria from one fuel-contaminated well were generally larger, ranging in size from 0.2 to 3.9 mm. Also, bacteria collected from the clean well had a higher density and, consequently, were more inclined to sink than bacteria collected from contaminated wells. Bacteria collected from the clean portion of the karst aquifer were predominantly (,95%) Gram-negative and more likely to have flagella present than bacteria collected from the contaminated wells, which included a substantial fraction (,30%) of Gram-positive varieties. The ability of the bacteria from the clean portion of the karst aquifer to biodegrade benzene and toluene was studied under aerobic and anaerobic conditions in laboratory microcosms. The rate of fuel biodegradation in laboratory studies was approximately 50 times faster under aerobic conditions as compared to anaerobic, sulfur-reducing conditions. The

  6. Constraining nitrogen cycling hotspots in contaminated aquifers

    Science.gov (United States)

    Wells, Naomi; Knoeller, Kay

    2014-05-01

    Accurate assessments of the fate of inorganic nitrogen (N) in groundwater are needed in order to mitigate the threat that ammonium (NH4+) and nitrate (NO3-) pose to water quality and the long-term health of down-gradient ecosystems. However, such assessments are currently limited by difficulties in measuring the biological attenuation (via either denitrification or anaerobic ammonia oxidation (anammox)) of these reactive species in-situ. Based on the knowledge that both of these processes can create unique fractionation patterns in the residual N pools, the objective of this research was to build a template for identifying and quantifying N removal hotspots within complex aquifers using isofluxes. The variations in concentration and isotopic abundance of multiple dissolved inorganic N species (δ15N of NH4+, and δ15N and δ18O of NO2- and NO3-) were measured in 100 wells across two contaminated megasites in Western Europe. The sampling locations were selected span the NH4+ (the dominant N form in both sites) concentration gradient (0 to 900 mg NH4+-N l-1) over depth and distance, which coincided with gradients in co-contaminants BTEX and sulphate of 0 to 5 mg l-1 4 to 11000 mg l-1, respectively. Although NO2- is a key component of both anaerobic and aerobic ammonium oxidation, it is rarely detected in groundwater. Yet, by analysing for it on-site, we found that NO2- concentrations reached up to 0.7 mg NO2-N l-1 and had a highly sensitive isotopic composition (mean of -5 ±23o (δ15N) and +11 ±12o (δ18O)). The largest NO2- concentrations coincided with those of NH4+ levels, meaning that attenuation fluxes could be partitioned between anammox and denitrification using simple isotope mass balance calculations based on Rayleigh type isotope fractionation and established nitrate (δ15N and δ18O) isotope dynamics during denitrification. The constraints on N attenuation within these complex hydrological and chemical setting created by overlaying isoflux maps for each

  7. Molecular analysis of microbial community in a groundwater sample polluted by landfill leachate and seawater

    Institute of Scientific and Technical Information of China (English)

    TIAN Yang-jie; YANG Hong; WU Xiu-juan; LI Dao-tang

    2005-01-01

    Seashore landfill aquifers are environments of special physicochemical conditions (high organic load and high salinity), and microbes in leachate-polluted aquifers play a significant role for intrinsic bioremediation. In order to characterize microbial diversity and look for clues on the relationship between microbial community structure and hydrochemistry, a culture-independent examination of a typical groundwater sample obtained from a seashore landfill was conducted by sequence analysis of 16S rDNA clone library. Two sets of universal 16S rDNA primers were used to amplify DNA extracted from the groundwater so that problems arising from primer efficiency and specificity could be reduced. Of 74 clones randomly selected from the libraries, 30 contained unique sequences whose analysis showed that the majority of them belonged to bacteria (95.9%), with Proteobacteria (63.5%) being the dominant division. One archaeal sequence and one eukaryotic sequence were found as well. Bacterial sequences belonging to the following phylogenic groups were identified: Bacteroidetes (20.3%), β, γ, δ and ε-subdivisions of Proteobacteria (47.3%, 9.5%, 5.4% and 1.3%, respectively), Firmicutes (1.4%), Actinobacteria (2.7%), Cyanobacteria (2.7%). The percentages of Proteobacteria and Bacteroides in seawater were greater than those in the groundwater from a non-seashore landfill, indicating a possible influence of seawater. Quite a few sequences had close relatives in marine or hypersaline environments. Many sequences showed affiliations with microbes involved in anaerobic fermentation. The remarkable abundance of sequences related to (per)chlorate-reducing bacteria (C1RB) in the groundwater was significant and worthy of further study.

  8. Anaerobic digestion of solid material

    DEFF Research Database (Denmark)

    Vavilin, V.A.; Lokshina, L.Y.; Flotats, X.;

    2007-01-01

    A new multidimensional (3 and 2D) anaerobic digestion model for cylindrical reactor with non-uniform influent concentration distributions was developed to study the way in which mixing intensity affects the efficiency of continuous-flow anaerobic digestion. Batch experiments reported and simulated...... improve the continuous flow reactor performance at the relatively low influent methanogenic biomass concentration. In the continuously stirred tank reactor (CSTR) there are two steady states with and without methane production at slightly different values of initial methanogenic biomass concentration....... In the system, the threshold methanogenic biomass concentration existed because of inhibition by high VFA concentration. High methanogenic biomass concentration is required for efficient anaerobic digestion of MSW in order to avoid possible inhibition due to high VFA build-up. Thus, CSTR configuration might...

  9. Genomic and Physiological Characterization of the Chromate-Reducing, Aquifer-Derived Firmicute Pelosinus sp. Strain HCF1

    OpenAIRE

    Beller, Harry R.; Han, Ruyang; Karaoz, Ulas; Lim, HsiaoChien; Eoin L. Brodie

    2013-01-01

    Pelosinus spp. are fermentative firmicutes that were recently reported to be prominent members of microbial communities at contaminated subsurface sites in multiple locations. Here we report metabolic characteristics and their putative genetic basis in Pelosinus sp. strain HCF1, an isolate that predominated anaerobic, Cr(VI)-reducing columns constructed with aquifer sediment. Strain HCF1 ferments lactate to propionate and acetate (the methylmalonyl-coenzyme A [CoA] pathway was identified in t...

  10. RISK FACTORS IN NEONATAL ANAEROBIC INFECTIONS

    Directory of Open Access Journals (Sweden)

    M. S. Tabib

    2008-06-01

    Full Text Available Anaerobic bacteria are well known causes of sepsis in adults but there are few studies regarding their role in neonatal sepsis. In an attempt to define the incidence of neonatal anaerobic infections a prospective study was performed during one year period. A total number of 400 neonates under sepsis study were entered this investigation. Anaerobic as well as aerobic cultures were sent. The patients were subjected to comparison in two groups: anaerobic culture positive and anaerobic culture negative and this comparison were analyzed statistically. There were 7 neonates with positive anaerobic culture and 35 neonates with positive aerobic culture. A significant statistical relationship was found between anaerobic infections and abdominal distention and pneumonia. It is recommended for those neonates with abdominal distention and pneumonia refractory to antibiotic treatment to be started on antibiotics with anaerobic coverage.

  11. As contamination in Mercedes aquifer groundwater

    International Nuclear Information System (INIS)

    This work is about the quality of the groundwater an the arsenic content in different aquifers in Uruguay. The first data obtained of arsenic concentrations are from subterranes water in the Mercedes aquifers

  12. National Sole Source Aquifer GIS Layer

    Data.gov (United States)

    U.S. Environmental Protection Agency — This data set contains indexes and Esri shape files of boundaries of the designated sole source aquifers and related aquifer boundaries. Data provide a vector...

  13. Saturated thickness, High Plains aquifer, 2009

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This raster data set represents the saturated thickness of the High Plains aquifer of the United States, 2009, in feet. The High Plains aquifer underlies...

  14. Intrinsic bioremediation of petroleum hydrocarbons in a gas condensate-contaminated aquifer

    International Nuclear Information System (INIS)

    A study was designed to determine if the intrinsic bioremediation of gas condensate hydrocarbons represented an important fate process in a shallow aquifer underlying a natural gas production site. For over 4 yr, changes in the groundwater, sediment, and vadose zone chemistry in the contaminated portion of the aquifer were interpreted relative to a background zone. Changes included decreased dissolved oxygen and sulfate levels and increased alkalinity, Fe(II), and methane concentrations in the contaminated groundwater, suggesting that aerobic heterotrophic respiration depleted oxygen reserves leaving anaerobic conditions in the hydrocarbon-impacted subsurface. Dissolved hydrogen levels in the contaminated groundwater indicated that sulfate reduction and methanogenesis were predominant biological processes, corroborating the geochemical findings. Furthermore, 10--1000-fold higher numbers of sulfate reducers and methanogens were enumerated in the contaminated sediment relative to background. Putative metabolites were also detected in the contaminated groundwater, including methylbenzylsuccinic acid, a signature intermediate of anaerobic xylene decay. Laboratory incubations showed that benzene, toluene, ethylbenzene, and each of the xylene isomers were biodegraded under sulfate-reducing conditions as was toluene under methanogenic conditions. These results coupled with a decrease in hydrocarbon concentrations in contaminated sediment confirm that intrinsic bioremediation contributes to the attenuation of hydrocarbons in this aquifer

  15. Alpine Groundwater - Pristine Aquifers Under Threat?

    Science.gov (United States)

    Schneider, P.; Lange, A.

    2014-12-01

    Glacier and permafrost retreat are prominent climate change indicators. However, the characteristics of climate and hydrology in mountain areas remain poorly understood relative to lowland areas. Specifically, not much is known about alpine groundwater, its recharge and water quality variations, as these remote reservoirs are rarely monitored. As global temperatures rise, glaciers and permafrost will continue to retreat forming new sediment deposits and changing infiltration conditions in high alpine terrain. Climate change impacts the hydro-chemical composition of alpine waters, accelerates weathering processes, and potentially triggers mobilization of pollutants. Accordingly, we monitored groundwater quantity and quality parameters of an alpine porous aquifer near the Tiefenbach glacier in the Gotthard Massif in Switzerland. The goal of this research was to assess quality and seasonal storage dynamics of groundwater above the timberline (2000 m). To translate hydrological science into an ecosystem service context, we focused on four attributes: Water quantity: observations of groundwater level fluctuations combined with analysis of contributing water sources based on stable isotope analysis to give a quantitative understanding of origin and amount of water, Water quality: groundwater level, groundwater temperature and electrical conductivity were used as proxies for sampling of hydro-chemical parameters with automated water samplers during primary groundwater recharge periods (snowmelt and rainfall events), Location: Alpine terrain above the timberline, especially recharge into/out of an alpine porous aquifer at a pro-glacial floodplain and Date of annual melt (albedo effect) and timing of flow (snow- and icemelt from May to September) and groundwater recharge during the growing season. The study found that the summer groundwater temperatures depend on the date of annual melt and are more sensitive to climate forcing than lowland groundwater temperatures

  16. Anaerobic Digestion of Piggery Waste

    OpenAIRE

    Velsen, van, L.S.

    1981-01-01

    Anaerobic digestion is a biological process by which organic matter is converted to methane and carbon dioxide by microbes in the absence of air (oxygen). In nature, anaerobic conversions occur at all places where organic material accumulates and the supply of oxygen is deficient, e.g. in marshes and lake sediments. Microbial formation of methane also plays a role in the ruminant digestion.In digestion units, the external conditions acting upon the process can be regulated to speed it up as c...

  17. Anaerobic membrane bioreactors for municipal wastewater treatment

    OpenAIRE

    Fawehinmi, Folasade

    2006-01-01

    Anaerobic treatment has historically been considered unsuitable for the treatment of domestic wastewaters. The work presented in this thesis focuses on the incorporation of membranes into the anaerobic bioreactor to uncouple solid retention time and hydraulic retention time. This in turn prevents biomass washout and allows sufficient acclimatisation periods for anaerobes. However, the exposure of membranes to anaerobic biomass comes with its own inherent problems namely fouling. Fouling w...

  18. Molecular genetic studies on obligate anaerobic bacteria

    International Nuclear Information System (INIS)

    Molecular genetic studies on obligate anaerobic bacteria have lagged behind similar studies in aerobes. However, the current interest in biotechnology, the involvement of anaerobes in disease and the emergence of antibioticresistant strains have focused attention on the genetics of anaerobes. This article reviews molecular genetic studies in Bacteroides spp., Clostridium spp. and methanogens. Certain genetic systems in some anaerobes differ from those in aerobes and illustrate the genetic diversity among bacteria

  19. Viscosity evolution of anaerobic granular sludge

    NARCIS (Netherlands)

    Pevere, A.; Guibaud, G.; Hullebusch, van E.D.; Lens, P.N.L.; Baudu, M.

    2006-01-01

    The evolution of the apparent viscosity at steady shear rate of sieved anaerobic granular sludge (20¿315 ¿m diameter) sampled from different full-scale anaerobic reactors was recorded using rotation tests. The ¿limit viscosity¿ of sieved anaerobic granular sludge was determined from the apparent vis

  20. Kinetics and modeling of anaerobic digestion process

    DEFF Research Database (Denmark)

    Gavala, Hariklia N.; Angelidaki, Irini; Ahring, Birgitte Kiær

    2003-01-01

    Anaerobic digestion modeling started in the early 1970s when the need for design and efficient operation of anaerobic systems became evident. At that time not only was the knowledge about the complex process of anaerobic digestion inadequate but also there were computational limitations. Thus...

  1. Inibição de lodo biológico anaeróbio por constituintes de efluente de laboratório de controle de poluição Inhibition of anaerobic biological sludge by effluent constituents of pollution control laboratory

    Directory of Open Access Journals (Sweden)

    Larissa de Carvalho Alves

    2005-09-01

    of H2SO4, containing heavy metals such as chromium, silver and mercury and organic compounds as phenol. The presence of these elements in the laboratory effluent can cause inhibition of the biological activity, especially in the anaerobic treatment processes due to the sensitivity of the methanogens to some chemical compounds. This work had as objective to characterize the effluent from the Federal University of Rio de Janeiro Chemistry School Environmental Technology Laboratory (LTA/UFRJ and to determine which constituents of the effluent one would be inhibitors for anaerobic microorganisms in the treatment of the sewage generated in the campus. The effluent one presents a weekly average production of 43.4 L, with pH = 0.7, COD = 1350 mg/L, sulfate = 33500 mg/L; 28.2 mg Hg/L; 82.1 mg Cr total/L; 30.8 mg Cu/L; 57.4 mg Fe total/L; 16.2 mg Al/L and 2.44 g Na/L. The parameters analyzed presented high variability as the study was conducted in function of the analyses and researches carried out in that period. In experimental design performed, the elements sodium, chromium, phenol and sulfate, as well as the interactions sulfate-mercury and sulfate-sodium, were significantly more effective on the inhibition of the specific methanogenic activity (SMA. The effects of the other elements (cupper, mercury, aluminum and iron, analyzed alone and their interactions were not significant for a confidence level of 95% in the t-Student distribution. The results indicate the necessity of a specific treatment for the laboratory effluent, since universities must be examples of combating pollution and encouraging the environmental control.

  2. Chemical controls on abiotic and biotic release of geogenic arsenic from Pleistocene aquifer sediments to groundwater.

    Science.gov (United States)

    Gillispie, Elizabeth C; Andujar, Erika; Polizzotto, Matthew L

    2016-08-10

    Over 150 million people in South and Southeast Asia consume unsafe drinking water from arsenic-rich Holocene aquifers. Although use of As-free water from Pleistocene aquifers is a potential mitigation strategy, such aquifers are vulnerable to geogenic As pollution, placing millions more people at potential risk. The goal of this research was to define chemical controls on abiotic and biotic release of geogenic As to groundwater. Batch incubations of sediments with natural chemical variability from a Pleistocene aquifer in Cambodia were conducted to evaluate how interactions among arsenic, manganese and iron oxides, and dissolved and sedimentary organic carbon influenced As mobilization from sediments. The addition of labile dissolved organic carbon produced the highest concentrations of dissolved As after >7 months, as compared to sediment samples incubated with sodium azide or without added carbon, and the extent of As release was positively correlated with the percent of initial extractable Mn released from the sediments. The mode of As release was impacted by the source of DOC supplied to the sediments, with biological processes responsible for 81% to 85% of the total As release following incubations with lactate and acetate but only up to 43% to 61% of the total As release following incubations with humic and fulvic acids. Overall, cycling of key redox-active elements and organic-carbon reactivity govern the potential for geogenic As release to groundwater, and results here may be used to formulate better predictions of the arsenic pollution potential of aquifers in South and Southeast Asia. PMID:27463026

  3. Anaerobic digestion of vegetation water as an energy source

    Energy Technology Data Exchange (ETDEWEB)

    de Ursinos, J.A.F.R.; Gamero, R.N.; Cabello, R.L.; Buendia, A.J.G.; de Jauregui, G.M.M.S.

    In this work, the possibility is shown of vegetation water depuration (wastewater from the olive oil obtaining process) by anaerobic digestion. The research was carried out in a 70 cu.m capacity ''contact method'' pilot plant; during which an average of 0.85 cu.m biogas/kg of BOD removed, was obtained; at the same time the efficiency in pollution power reduction was about 80 percent. In agreement with the energy balance the application of this purification process to the oil-mills overflow would permits its electrical and calorific independence. (Refs. 14).

  4. Mathematical Modelling of Cassava Wastewater Treatment Using Anaerobic Baffled Reactor

    OpenAIRE

    A.O. Ibeje

    2013-01-01

    The performance of an anaerobic baffled reactor (ABR) was evaluated in the treatment of cassava wastewater as a pollutant residue. An ABR divided in four equal volume compartments (total volume 4L) and operated at 35°C was used in cassava wastewater treatment. Feed tank chemical oxygen demand (COD) was varied from 2000 to 7000mg L-1. The objective of the study was to formulate an improved mathematical model to describe cassava wastewater treatment without taking into account its inhibition ch...

  5. Anaerobic Biodegradation of Ethylene Glycol within Hydraulic Fracturing Fluid

    Science.gov (United States)

    Heyob, K. M.; Mouser, P. J.

    2014-12-01

    Ethylene glycol (EG) is a commonly used organic additive in hydraulic fracturing fluids used for shale gas recovery. Under aerobic conditions, this compound readily biodegrades to acetate and CO2 or is oxidized through the glycerate pathway. In the absence of oxygen, organisms within genera Desulfovibrio, Acetobacterium, and others can transform EG to acetaldehyde, a flammable and suspected carcinogenic compound. Acetaldehyde can then be enzymatically degraded to ethanol or acetate and CO2. However, little is known on how EG degrades in the presence of other organic additives, particularly under anaerobic conditions representative of deep groundwater aquifers. To better understand the fate and attenuation of glycols within hydraulic fracturing fluids we are assessing their biodegradation potential and pathways in batch anaerobic microcosm treatments. Crushed Berea sandstone was inoculated with groundwater and incubated with either EG or a synthetic fracturing fluid (SFF) containing EG formulations. We tracked changes in dissolved organic carbon (DOC), EG, and its transformation products over several months. Approximately 41% of bulk DOC in SFF is degraded within 21 days, with 58% DOC still remaining after 63 days. By comparison, this same SFF degrades by 70% within 25 days when inoculated with sediment-groundwater microbial communities, suggesting that bulk DOC degradation occurs at a slower rate and to a lesser extent with bedrock. Aerobic biodegradation of EG occurs rapidly (3-7 days); however anaerobic degradation of EG is much slower, requiring several weeks for substantial DOC loss to be observed. Ongoing experiments are tracking the degradation pathways of EG alone and in the presence of SFF, with preliminary data showing incomplete glycol transformation within the complex hydraulic fracturing fluid mixture. This research will help to elucidate rates, processes, and pathways for EG biodegradation and identify key microbial taxa involved in its degradation.

  6. Characterization of polluted sites. Assessment of pollutant behaviour and transfer in mediums; Caracterisation des sites pollues. L`evaluation du comportement et du transfert des polluants dans les milieux

    Energy Technology Data Exchange (ETDEWEB)

    Goubier, R. [Agence de l`Environnement et de la Maitrise de l`Energie, 75 - Paris (France); Chassagnac, T. [CSD Azur (France); Schlegel, T. [ATE, (France); Coste, B. [ANTEA, (France)

    1996-12-31

    After a presentation of methods and tools for the basic and extensive characterization of polluted sites and the study of evolution and transfer of current organic pollutants in the ground, the example of the rehabilitation of an old Rhone-Poulenc site (at Chauny, France) polluted with metals and arsenic, is described: soil and aquifer diagnosis, risk analysis and determination of migration schemes

  7. Modeling multi-component transport and enhanced anaerobic dechlorination processes in a single fracture-clay matrix system

    DEFF Research Database (Denmark)

    Chambon, Julie Claire Claudia; Broholm, Mette Martina; Binning, Philip John;

    2010-01-01

    Clayey tills contaminated with chlorinated solvents are a threat to groundwater and are difficult to remediate. A numerical model is developed for assessing leaching processes and for simulating the remediation via enhanced anaerobic dechlorination. The model simulates the transport...... to the physical processes, mainly diffusion in the matrix, than to the biogeochemical processes, when dechlorination is assumed to take place in a limited reaction zone only. The inclusion of sequential dechlorination in clay fracture transport models is crucial, as the contaminant flux to the aquifer...... of a contaminant in a single fracture-clay matrix system coupled with a reactive model for anaerobic dechlorination. The model takes into account microbially driven anaerobic dechlorination, where sequential Monod kinetics with competitive inhibition is used to model the reaction rates, and degradation...

  8. Oxygen Effects in Anaerobic Digestion

    Directory of Open Access Journals (Sweden)

    Deshai Botheju

    2009-10-01

    Full Text Available Interaction of free oxygen in bio-gasification is a sparsely studied area, apart from the common argument of oxygen being toxic and inhibitory for anaerobic micro-cultures. Some studies have, however, revealed increased solubilisation of organic matter in the presence of some free oxygen in anaerobic digestion. This article analyses these counterbalancing phenomena with a mathematical modelling approach using the widely accepted biochemical model ADM 1. Aerobic oxidation of soluble carbon and inhibition of obligatory anaerobic organisms are modelled using standard saturation type kinetics. Biomass dependent first order hydrolysis kinetics is used to relate the increased hydrolysis rate with oxygen induced increase in biomass growth. The amended model, ADM 1-Ox (oxygen, has 25 state variables and 22 biochemical processes, presented in matrix form. The computer aided simulation tool AQUASIM 2.1 is used to simulate the developed model. Simulation predictions are evaluated against experimental data obtained using a laboratory batch test array comprising miniature anaerobic bio-reactors of 100 ml total volume each, operated under different initial air headspaces giving rise to the different oxygen loading conditions. The reactors were initially fed with a glucose solution and incubated at 35 Celsius, for 563 hours. Under the oxygen load conditions of 22, 44 and 88 mg/L, the ADM1-Ox model simulations predicted the experimental methane potentials quite adequately. Both the experimental data and the simulations suggest a linear reduction of methane potential with respect to the increase in oxygen load within this range.

  9. Anaerobic Treatment of Methanolic Wastes

    NARCIS (Netherlands)

    Lettinga, G.; Geest, van der A.Th.; Hobma, S.W.; Laan, van der J.B.R.

    1979-01-01

    Although it is well known that methanol can be fermented directly by a specific species of methane bacteria, viz. Methanosarcina barkeri, until now little information was available about the effect of important environmental factors on the anaerobic fermentation of methanol. As methanol can be the m

  10. Anaerobe-Aerobe Submerged Biofilter Technology for Domestic Waste Water Treatment

    International Nuclear Information System (INIS)

    Water pollution in the big cities in Indonesia, especially in DKI Jakarta has shown serious problems. One of the potential sources of water pollution is domestic wastewater that is wastewater from kitchens, laundry, bathing and toilets. These problems have become more serious since the spreads of sewerage systems are still low, so that domestic, institutional and commercial wastewater cause severe water pollution in many rivers or shallow ground water. Bases on the fact that the progress of development of sewerage system is still low, it is important to develop low cost technology for individual house hold or semi communal wastewater treatment such as using anaerobic and aerobic submerged biofilter. This paper describes alternative technology for treatment of household wastewater or organic wastewater using anaerobic and aerobic submerged biofilter. Using this technology can decrease BOD, COD and Suspended Solids (SS) concentration more than 90 %. (author)

  11. Attenuation capacity of a coastal aquifer under managed recharge by reclaimed wastewater

    Science.gov (United States)

    Christodoulou, George; Dokou, Zoi; Tzoraki, Ourania; Gaganis, Petros; Karatzas, George

    2013-08-01

    Managed Aquifer Recharge (MAR) is becoming an increasingly attractive water management option, especially in semiarid areas. Nevertheless, field studies on the fate and transport of priority substances, heavy metals and pharmaceutical products within the recharged aquifer are rare. Based on the above, the objective of this project is to study the hydrological conditions of the coastal aquifer of Ezousa (Cyprus) and its ability to attenuate pollutants. The Ezousa riverbed is a locally important aquifer used for a MAR project where treated effluent from the Paphos Waste Water Treatment Plant is recharged into the aquifer through a number of artificial ponds along the riverbed. Additionally, groundwater is pumped for irrigation purposes from wells located nearby. The hydrological conditions of the area are unique due to the construction of the Kannaviou dam in 2005 that reduced natural recharge of the Ezousa aquifer significantly, inducing the saltwater intrusion phenomenon. A three-dimensional finite element model of the area was constructed using the FEFLOW software to simulate the groundwater flow conditions and transport of Phosphorous and cooper in the subsurface from the recharge process. The model was calibrated using hydraulic head and chemical data for the time period of 2002-2011. The groundwater model was coupled with a geochemical model PHREEQC attempting to evaluate nitrate and Copper processes. Inverse modeling calculation was used to determine sets of moles transfers of phases that are attributed to the water composition change in groundwater between the mixture of natural groundwater and reclaimed wastewater and the final water composition.

  12. Information Pollution

    OpenAIRE

    Noruzi, Alireza

    2000-01-01

    The exponential growth of information resources creates new challenges for end-users. The correct information may be polluted by misinformation, disinformation, propaganda or incorrect information via the Internet and other media. This paper defines 'information pollution' as "the contamination of information by misinformation, disinformation, propaganda and incorrect information." The purpose of this paper is to present the methods of information pollution. It is concluded that it is sometim...

  13. Air Pollution

    OpenAIRE

    Lawther, P. J.

    2014-01-01

    The human costs of air pollution are considerable in Jordan. According to a report published in 2000 by the World Bank under the Mediterranean Environmental Technical Assistance Program (METAP), approximately 600 people die prematurely each year in Jordan because of urban pollution. 50-90% of air pollution in Jordanian towns is caused by road traffic. Readings taken in 2007 by Jordanian researchers showed that levels of black carbon particles in the air were higher in urban areas (caused by v...

  14. Aquifer thermal energy stores in Germany

    International Nuclear Information System (INIS)

    This paper describes the state of essential demonstration projects of heat and cold storage in aquifers in Germany. Into the energy supply system of the buildings of the German Parliament in Berlin, there are integrated both a deep brine-bearing aquifer for the seasonal storage of waste heat from power and heat cogeneration and a shallow-freshwater bearing aquifer for cold storage. In Neubrandenburg, a geothermal heating plant which uses a 1.200 m deep aquifer is being retrofitted into an aquifer heat storage system which can be charged with the waste heat from a gas and steam cogeneration plant. The first centralised solar heating plant including an aquifer thermal energy store in Germany was constructed in Rostock. Solar collectors with a total area of 1000m2 serve for the heating of a complex of buildings with 108 flats. A shallow freshwater-bearing aquifer is used for thermal energy storage. (Authors)

  15. Performance of the In Situ Microcosm Technique for Measuring the Degradation of Organic Chemicals in Aquifers

    DEFF Research Database (Denmark)

    Nielsen, Per H.; Christensen, Thomas Højlund; Albrechtsen, Hans-Jørgen

    1996-01-01

    An in situ microcosm (ISM) consists of a stainless steel cylinder isolating about 2 L of the aquifer and is equipped with valves allowing for loading and sampling from the ground surface. During the last five years, this technique has been used frequently to study the degradation of organic...... chemicals in polluted and pristine aquifers representing different redox environments. The ISM technique has great potential for providing field-relevant degradation potentials and rate constants, but care must be taken in using the equipment and interpreting the results. This paper provides details...

  16. Surfactant-enhanced aquifer remediation at the Portsmouth Gaseous Diffusion Plant

    International Nuclear Information System (INIS)

    Many DOE facilities are situated in areas of sand and gravel which have become polluted with dense, non-aqueous phase liquids or DNAPLs, such as chlorinated solvents, from the various industrial operations at these facilities. The presence of such DNAPLs in sand and gravel aquifers is now recognized as the principal factor in the failure of standard ground-water remediation methods, i.e., open-quotes pump-and-treatclose quotes operations, to decontaminate such systems. The principal objective of this study is to demonstrate that multi-component DNAPLs can be readily solubilized in sand and gravel aquifers by dilute surfactant solutions

  17. An anaerobic field injection experiment in a landfill leachate plume (Grindsted, Denmark)

    DEFF Research Database (Denmark)

    Albrechtsen, Hans-Jørgen; Bjerg, Poul Løgstrup; Ludvigsen, L.;

    1999-01-01

    Redox conditions may be environmental factors which affect the fate of the xenobiotic organic compounds. Therefore the redox conditions were characterized in an anaerobic, leachate-contaminated aquifer 15–60 m downgradient from the Grindsted Landfill, Denmark, where an field injection experiment...... time during the experimental period of 924 days owing to variations in the leachate from the landfill. However, no indication of change in the redox environment resulting from the field injection experiment or natural variation was observed in the individual sampling points. The methane, Fe......, Fe(III) was the dominant electron acceptor in the region of the aquifer, which was investigated. Because of the complexity of a landfill leachate plume, several redox processes may occur simultaneously, and an array of methods must be applied for redox characterization in such multicomponent systems....

  18. Treatment of melanoidin wastewater by anaerobic digestion and coagulation.

    Science.gov (United States)

    Arimi, Milton M; Zhang, Yongjun; Götz, Gesine; Geißen, Sven-Uwe

    2015-01-01

    Melanoidins are dark-coloured recalcitrant pollutants found in many industrial wastewaters including coffee-manufacturing effluent, molasses distillery wastewater (MDWW) and other wastewater with molasses as the raw material. The wastewaters are mostly treated with anaerobic digestion after some dilution to minimize the inhibition effect. However, the dark colour and recalcitrant dissolved organic carbon (DOC) mainly caused by melanoidin are not effectively removed. The aim of this study was to investigate the removal of colour and remnant DOC by different coagulants from anaerobically digested MDWW. From the six coagulants tested, ferric chloride had the highest melanoidin (48%), colour (92.7%) and DOC (63.3%) removal at pH 5 and a dosage of 1.6 g/l. Both polymer and inorganic salt coagulants tested had optimal colour, melanoidin and DOC removal at acidic pH. The molecular size distribution of synthetic melanoidins by liquid chromatography-organic carbon detection indicated a preferential removal of high-molecular-weight melanoidins over low weight melanoidins by the coagulation. Further studies should focus on how to improve biodegradability of the treated effluent for it to be reused as dilution water for anaerobic digestion. PMID:25799161

  19. Use of environmental isotopes to characterize the groundwaters from tertiary aquifers of Kuttanad, Kerala, India

    International Nuclear Information System (INIS)

    Kuttanad area commonly known as the 'rice bowl' of Kerala is of importance as it contributes to the majority of rice production of the state. Even though more than 75% of the area is covered by surface waters and wetlands, groundwater is the only source of potable water supply to the nearby Alleppey town and the rural areas of Kuttanad because of contamination and inherent water quality problems in surface waters. Due to large-scale exploitation of groundwater resources for almost five decades, it is important to understand the sustainability of aquifers in this area in view of the increasing demand for domestic and irrigation requirements. Since the hydraulic gradient is mild and owing to the lowering of piezometric heads over the years, seawater ingression and deterioration of water quality in some parts of this coastal aquifer is apprehended. More over, the impact of agricultural pollution by the excessive use of fertilizers and pesticides need to be dealt with for the protection and mitigation of pollution in aquifers. As a pre-requisite to address the above problems, a systematic environmental isotope (oxygen 18, tritium, carbon 13 and carbon 14)) study is carried out to understand the flow pattern, source and process of replenishment and possible hydraulic interconnection between aquifers and surface waters of this region. From the hydrogeological settings, it is seen that Kuttanad is a multiaquifer system of formations of Eocene to Recent age. Quarternary Alluvium and Laterite form the top phreatic aquifer and is underlain by Tertiary sediments that are under confined condition. Archaean crystalline rock forms the basement and is exposed at the eastern periphery of the area. There are four distinct groups of formations in Tertiary sediments namely, Warkali bed, Quilon bed, Vaikom bed and Alleppey bed of which Vaikom and Warkali are potential aquifers. Pre-monsoon (May, 2000) and post-monsoon (November 2000) samples were collected from tube wells tapping

  20. Three-dimensional modelling of an injection experiment in the anaerobic part of a landfill plume

    DEFF Research Database (Denmark)

    Juul Petersen, Michael; Engesgaard, Peter Knudegaard; Bjerg, Poul Løgstrup; Rügge, Kirsten

    Analytical and numerical three-dimensional (3-D) simulations have been conducted and compared to data obtained from a large-scale (50 m), natural gradient field injection experiment. Eighteen different xenobiotic compounds (i.e. benzene, toluene, o-xylene, naphthalene, 1,1,1-TCA, PCE, and TCE) and...... bromide as a conservative tracer, were for 195 days injected in the anaerobic part of the leachate plume downgradient of the Grindsted Landfill, Denmark. The injection area is an unconfined sandy aquifer with heterogeneities of clay and silt layers. Simulations with homogeneous and heterogeneous hydraulic...

  1. Effect of incubation conditions on anaerobic susceptibility testing results.

    OpenAIRE

    Murray, P R; Niles, A C

    1982-01-01

    We determined the effect of performing antimicrobial susceptibility tests in five different anaerobic incubation systems: GasPak jar, large GasPak jar, evacuated-gassed anaerobic jar, anaerobic chamber, and Bio-Bag. Growth of the anaerobes was equivalent in all five incubation systems. The results of testing 38 anaerobes against 11 antimicrobial agents were comparable for the anaerobic jars and anaerobic chamber. However, discordant results were observed for metronidazole and cefamandole test...

  2. Methanogenic degradation kinetics of phenolic compounds in aquifer-derived microcosms

    Science.gov (United States)

    Godsy, E.M.; Goerlitz, D.F.; Grbic-Galic, D.

    1992-01-01

    In this segment of a larger multidisciplinary study of the movement and fate of creosote derived compounds in a sand-and-gravel aquifer, we present evidence that the methanogenic degradation of the major biodegradable phenolic compounds and concomitant microbial growth in batch microcosms derived from contaminated aquifer material can be described using Monod kinetics. Substrate depletion and bacterial growth curves were fitted to the Monod equations using nonlinear regression analysis. The method of Marquardt was used for the determination of parameter values that best fit the experimental data by minimizing the residual sum of squares. The Monod kinetic constants (??max, Ks, Y, and kd) that describe phenol, 2-, 3-, and 4-methylphenol degradation and concomitant microbial growth were determined under conditions that were substantially different from those previously reported for microcosms cultured from sewage sludge. The Ks values obtained in this study are approximately two orders of magnitude lower than values obtained for the anaerobic degradation of phenol in digesting sewage sludge, indicating that the aquifer microorganisms have developed enzyme systems that are adapted to low nutrient conditions. The values for kd are much less than ??max, and can be neglected in the microcosms. The extremely low Y values, approximately 3 orders of magnitude lower than for the sewage sludge derived cultures, and the very low numbers of microorganisms in the aquifer derived microcosms suggest that these organisms use some unique strategies to survive in the subsurface environment. ?? 1992 Kluwer Academic Publishers.

  3. Anaerobic Biotransformation and Mobility of Pu and of Pu-EDTA

    International Nuclear Information System (INIS)

    The enhanced mobility of radionuclides by co-disposed chelating agent, ethylenediaminetetraacetate (EDTA), is likely to occur only under anaerobic conditions. Our extensive effort to enrich and isolate anaerobic EDTA-degrading bacteria has failed. Others has tried and also failed. To explain the lack of anaerobic biodegradation of EDTA, we proposed that EDTA has to be transported into the cells for metabolism. A failure of uptake may contribute to the lack of EDTA degradation under anaerobic conditions. We demonstrated that an aerobic EDTA-degrading bacterium strain BNC1 uses an ABC-type transporter system to uptake EDTA. The system has a periplasmic binding protein that bind EDTA and then interacts with membrane proteins to transport EDTA into the cell at the expense of ATP. The bind protein EppA binds only free EDTA with a Kd of 25 nM. The low Kd value indicates high affinity. However, the Kd value of Ni-EDTA is 2.4 x 10-10 nM, indicating much stronger stability. Since Ni and other trace metals are essential for anaerobic respiration, we conclude that the added EDTA sequestrates all trace metals and making anaerobic respiration impossible. Thus, the data explain the lack of anaerobic enrichment cultures for EDTA degradation. Although we did not obtain an EDTA degrading culture under anaerobic conditions, our finding may promote the use of certain metals that forms more stable metal-EDTA complexes than Pu(III)-EDTA to prevent the enhanced mobility. Further, our data explain why EDTA is the most dominant organic pollutant in surface waters, due to the lack of degradation of certain metal-EDTA complexes.

  4. Geochemistry at the sulfate reduction-methanogenesis transition zone in an anoxic aquifer

    DEFF Research Database (Denmark)

    Jakobsen, Rasmus; Cold, L.

    2007-01-01

    The study addresses a 10 m deep phreatic postglacial sandy aquifer of vertically varying lithology and horizontally varying infiltration water chemistry, displaying calcite dissolution, ion-exchange, and anaerobic redox processes. The simple variations in lithology and infiltration combine into a...... complex groundwater chemistry, showing ongoing Fe-oxide reduction, sulfate reduction and methanogenesis. Rates of sulfate reduction, methanogenesis and methane oxidation were measured directly using radiotracers. Maximum rates were 1.5 mM/yr for sulfate reduction, 0.3 mM/yr for methanogenesis, and only 4...

  5. Stimulation of aerobic degradation of bentazone, mecoprop and dichlorprop by oxygen addition to aquifer sediment

    DEFF Research Database (Denmark)

    Levi, Suzi; Hybel, Anne-Marie; Bjerg, Poul Løgstrup;

    2014-01-01

    In order to investigate aerobic degradation potential for the herbicides bentazone, mecoprop and dichlorprop, anaerobic groundwater samples from two monitoring and three drinking water wells near a drinking water abstraction field in Nybølle, Denmark, were screened for their degradation potential...... herbicides in microcosms using groundwater and sandy aquifer materials. To maintain a certain oxygen concentration this level was measured from the outside of the bottles with a fibre oxygen meter using oxygen-sensitive luminescent sensor foil mounted inside the microcosm, to which supplementary oxygen was...

  6. Stimulation of aerobic degradation of bentazone, mecoprop and dichlorprop by oxygen addition to aquifer sediment

    International Nuclear Information System (INIS)

    In order to investigate aerobic degradation potential for the herbicides bentazone, mecoprop and dichlorprop, anaerobic groundwater samples from two monitoring and three drinking water wells near a drinking water abstraction field in Nybølle, Denmark, were screened for their degradation potential for the herbicides. In the presence of oxygen 14C-labelled bentazone and mecoprop were removed significantly from the two monitoring wells' groundwater samples. Oxygen was added to microcosms in order to investigate whether different oxygen concentrations stimulate the biodegradation of the three herbicides in microcosms using groundwater and sandy aquifer materials. To maintain a certain oxygen concentration this level was measured from the outside of the bottles with a fibre oxygen meter using oxygen-sensitive luminescent sensor foil mounted inside the microcosm, to which supplementary oxygen was added. The highest oxygen concentrations (corresponding to 4–11 mg L−1) stimulated degradation (a 14–27% increase for mecoprop, 3–9% for dichlorprop and 15–20% for bentazone) over an experimental period of 200 days. Oxygen was required to biodegrade the herbicides, since no degradation was observed under anaerobic conditions. This is the first time bentazone degradation has been observed in aquifer material at low oxygen concentrations (2 mg L−1). The sediment had substantial oxygen consumption (0.92–1.45 O2 g-1 dw over 200 days) and oxygen was depleted rapidly in most incubations soon after its addition, which might be due to the oxidation of organic matter and other reduced species such as Fe2+, S2− and Mn in sediment before the biodegradation of herbicides takes place. This study suggests that oxygen enhancement around a drinking water abstraction field could stimulate the bioremediation of diffuse source contamination. - Highlights: • Addition of different oxygen concentrations stimulated degradation of herbicides in anaerobic aquifer sediment material.

  7. Air Pollution.

    Science.gov (United States)

    Air quality is affected by many types of pollutants that are emitted from various sources, including stationary and mobile. These sources release both criteria and hazardous air pollutants, which cause health effects, ecological harm, and material damage. They are generally categ...

  8. Upflow anaerobic sludge blanket reactor--a review.

    Science.gov (United States)

    Bal, A S; Dhagat, N N

    2001-04-01

    Biological treatment of wastewater basically reduces the pollutant concentration through microbial coagulation and removal of non-settleable organic colloidal solids. Organic matter is biologically stabilized so that no further oxygen demand is exerted by it. The biological treatment requires contact of the biomass with the substrate. Various advances and improvements in anaerobic reactors to achieve variations in contact time and method of contact have resulted in development of in suspended growth systems, attached growth or fixed film systems or combinations thereof. Although anaerobic systems for waste treatment have been used since late 19th century, they were considered to have limited treatment efficiencies and were too slow to serve the needs of a quickly expanding wastewater volume, especially in industrialized and densely populated areas. At present aerobic treatment is the most commonly used process to reduce the organic pollution level of both domestic and industrial wastewaters. Aerobic techniques, such as activated sludge process, trickling filters, oxidation ponds and aerated lagoons, with more or less intense mixing devices, have been successfully installed for domestic wastewater as well as industrial wastewater treatment. Anaerobic digestion systems have undergone modifications in the last two decades, mainly as a result of the energy crisis. Major developments have been made with regard to anaerobic metabolism, physiological interactions among different microbial species, effects of toxic compounds and biomass accumulation. Recent developments however, have demonstrated that anaerobic processes might be an economically attractive alternative for the treatment of different types of industrial wastewaters and in (semi-) tropical areas also for domestic wastewaters. The anaerobic degradation of complex, particulate organic matter has been described as a multistep process of series and parallel reactions. It involves the decomposition of organic and

  9. Arsenic release from shallow aquifers of the Hetao Basin, Inner Mongolia: Evidence from bacterial community in aquifer sediments and groundwater

    Science.gov (United States)

    Li, Y.; Guo, H.

    2013-12-01

    Indigenous microbes play crucial roles in arsenic mobilization in high arsenic groundwater systems. Databases concerning the presence and the activity of microbial communities are very useful in evaluating the potential of microbe-mediated arsenic mobilization in shallow aquifers hosting high arsenic groundwater. This study characterized microbial communities in groundwaters at different depths with different arsenic concentrations by DGGE and one sediment by 16S rDNA gene clone library, and evaluated arsenic mobilization in microcosm batches with the presence of indigenous bacteria. DGGE fingerprints revealed that the community structure changed substantially with depth at the same location. It indicated that a relatively higher bacterial diversity was present in the groundwater sample with lower arsenic concentration. The clone library of sediment sample 2009M1 and DGGE profiles of microbial community structures of groundwater samples indicated NO3-, Fe(III) and SO42- reducing bacteria are abundant in the As-affected aquifer, which are facultative or anaerobic chemoautotrophic bacteria. Pseudomonas that was rich in both high arsenic groundwater and sediment included a great number of denitrifying bacterium strains that may contribute to the low concentration of nitrate in the groundwater. Fe(III)-reducing bacteria belonging to different species, such as Aquabacterium sp., Thauera sp., Georgfuchsia sp., Methyloversatilis sp., Clostridium sp., were widely found in the community. The genus Desulfosporosinus observed in the sediment sample of 2009M1 was believed to be sulfate reducer. These results offered direct evidences that anaerobic reducing bacteria play a role in the formation of toxic, mobile As(III) in the groundwater of the Hetao basin, especially Fe(III)-reducing bacteria. Incubation of sediments without the addition of organic carbon source showed a significant release of arsenic (predominantly as As(III)). By contrast, sterile incubations and incubations

  10. Use of environmental isotopes to characterise the groundwaters from tertiary aquifers of Kuttanad, Kerala, India

    International Nuclear Information System (INIS)

    Kuttanad area commonly known as the 'rice bowl' of Kerala is of importance as it contributes to the majority of rice production of the state. Even though more than 75% of the area is covered by surface waters and wetlands, groundwater is the only source of potable water supply to the nearby Alleppey town and the rural areas of Kuttanad because of contamination and inherent water quality problems in surface waters. Due to large-scale exploitation of groundwater resources for almost five decades, it is important to understand the sustainability of aquifers in this area in view of the increasing demand for domestic and irrigation requirements. Since the hydraulic gradient is mild and owing to the lowering of piezometric heads over the years, seawater ingression and deterioration of water quality in some parts of this coastal aquifer is apprehended. More over, the impact of agricultural pollution by the excessive use of fertilizers and pesticides need to be dealt with for the protection and mitigation of pollution in aquifers. As a pre-requisite to address the above problems, a systematic environmental isotope (δD, δ18O, 3H, 13C and 14C) study is carried out to understand the flow pattern, source and process of replenishment and possible hydraulic interconnection between aquifers and surface waters of this region. From the hydrogeological settings, it is seen that Kuttanad is a multi-aquifer system of formations of Eocene to Recent age. Quarternary Alluvium and Laterite form the top phreatic aquifer and is underlain by Tertiary sediments that are under confined condition. Archaean crystalline rock forms the basement and is exposed at the eastern periphery of the area. There are four distinct groups of formations in Tertiary sediments namely, Warkali bed, Quilon bed, Vaikom bed and Alleppey bed of which Vaikom and Warkali are potential aquifers. Pre-monsoon (May, 2000) and post-monsoon (November 2000) samples were collected from tube wells tapping different aquifers

  11. Denitrification in a BTEX Contaminated Aquifer Containing Reduced Sulfur

    Science.gov (United States)

    Eckert, P.; Appelo, C.; Wisotzky, F.; Obermann, P.

    2001-05-01

    prior to the reaction of the organic pollutants. Thus, reduction products which accumulated earlier during the natural attenuation of BTEX were the first to react when nitrate was added as electron acceptor for enhanced bioremediation of the pollution. For BTEX degradation, a rate law based on Monod kinetics for natural organic matter was adapted to fit the observed decrease of nitrate. Sulfides may be common at other petroleum polluted sites, and enhanced remediation by addition of oxidants may be retarded by the unintended and possibly unexpected oxidation of these solids. The Duesseldorf case is therefore of interest for indicating the complex geochemical reactions which occur when other electron donors are present in the aquifer besides the aromatic compounds targeted for the remediation.

  12. RESPONSE OF RICE ROOT IN RESPIRATION AT JOINTING STAGE TO OZONE POLLUTION AND ALTERNATION OF ANAEROBIC AND AEROBIC CONDITIONS%水稻拔节期根系呼吸对臭氧污染和厌氧—有氧环境变化的响应

    Institute of Scientific and Technical Information of China (English)

    寇太记; 朱建国

    2013-01-01

    Effects of elevated atmospheric ozone (pO3) (50% higher than the ambient pO3 in concentration) on root respiration and biomass accumulation and distribution of rice (Oryza sativa L.cv.Xiandao 63) at the jointing stage were investigated in fully open-air field conditions,and effect of alternation of anaerobic and aerobic conditions on root respiration was analyzed using special gas-collecting installations.Results show that under elevated pO3canopy and total biomass of the crop decreased slightly,while its root dry matter weight and ratio of root/canopy dropped significantly by 14.7% and 10.4%,respectively.The mixture of N2 and O2at a ratio of 9∶1 or 9.5∶0.5 was the most propitious for root respiration,whereas in pure N2,natural air and CO2-saturated distilled water root respiration rate was lowered to a varying degree.The treatment of elevated pO3 coupled with measurement inn CO2-saturated distilled water and the treatment of ambient air coupled with measurement in pure N2 was the least in root respiration rate,indicating that although the condition in which root respiration was measured affected root respiration rate,the impact was restricted in degree by the atmospheric environment in which the plant grew.The root respiration rate of rice growing under elevated ozone was 23.6% ~52.7% higher than that under natural atmosphere when measured in pure gas condition,and the difference between the two was insignificant when the measurement was done in CO2-saturated distilled water,showing that the influence of ozone pollution on root respiration obviously decreased.Under elevated and ambient pO3 environments,root respiration of the rice displayed a curve of convex quadratic function with increasing oxygen supply in the gaseous environment for measurement.The oxygen concentration of 5%~ 10% in the environment promoted rice root respiration,while stronge anaerobic condition (i.e.,pure N2) and aerobic conditions (i.e.,air) both affected root

  13. [Optimization of aerobic/anaerobic subsurface flow constructed wetlands].

    Science.gov (United States)

    Li, Feng-Min; Shan, Shi; Li, Yuan-Yuan; Li, Yang; Wang, Zheng-Yu

    2012-02-01

    Previous studies showed that setting aerobic and anaerobic paragraph segments in the subsurface constructed wetlands (SFCWs) can improve the COD, NH4(+)-N, and TN removal rate, whereas the oxygen enrichment environment which produced by the artificial aeration could restrain the NO3(-)-N and NO2(-)-N removal process, and to a certain extent, inhibit the denitrification in SFCWs Therefore, in this research the structure and technology of SFCW with aerobic and anaerobic paragraph segments were optimized, by using the multi-point water inflow and setting the corresponding section for the extra pollutant removal. Results showed that with the hydraulic load of 0.06 m3 x (m2 x d)(-1), the COD, NH4(+)-N and TN removal efficiencies in the optimized SFCW achieved 91.6%, 100% and 87.7% respectively. COD/N increased to 10 speedily after the inflow supplement. The multi-point water inflow could add carbon sources, and simultaneously maximum utilization of wetland to remove pollutants. The optimized SFCW could achieve the purposes of purification process optimization, and provide theoretical basis and application foundation for improving the total nitrogen removal efficiency. PMID:22509578

  14. Anaerobic digestion of solid material

    DEFF Research Database (Denmark)

    Vavilin, V.A.; Lokshina, L.Y.; Flotats, X.; Angelidaki, Irini

    2007-01-01

    A new multidimensional (3 and 2D) anaerobic digestion model for cylindrical reactor with non-uniform influent concentration distributions was developed to study the way in which mixing intensity affects the efficiency of continuous-flow anaerobic digestion. Batch experiments reported and simulated...... improve the continuous flow reactor performance at the relatively low influent methanogenic biomass concentration. In the continuously stirred tank reactor (CSTR) there are two steady states with and without methane production at slightly different values of initial methanogenic biomass concentration. In...... failure. According to the distributed models a plug-flow reactor with non-uniform influent concentration distributions where methanogenic and hydrolytic microorganisms are separated has significant methane production and solids removal at the relatively low influent methanogenic biomass concentration...

  15. Characteristics and performance of anaerobic wastewater treatment (a review)

    International Nuclear Information System (INIS)

    Summary: Pakistan's current population of 180 million is expected to grow to about 221 million by the year 2025. In developing countries such as Pakistan water pollution is a major threat to the livelihood of people. Pakistan is also currently experiencing profound demographic, economic changes and energy crisis that have major implications for water management. The contamination of aquatic and terrestrial ecosystems with heavy metals is a major environmental problem. Each pollution problem calls for specific optimal and cost effective solution so if one technology proves less or ineffective other takes its place. Every day the vast amounts of the municipal, industrial and agricultural wastes are released in to the environment and create serious problems. Anaerobic digestion is very attractive and cost-effective option and technology for the highly loaded waste water treatment and energy conversion. The anaerobic process is in many ways ideal for waste treatment. It has several significant advantages over other available methods. In this process organic matter is utilized as source of electron donor to reduce carbon dioxide to produce methane gas. It involves three bacterial groups namely: hydrolytic, acetogenic and methanogenic bacteria that work optimally at pH and temperature ranges of 6.8 to 7.5 and 30-35 degree C, respectively. The residence time in a digester varies with the amount and type of feed material, the configuration of the digestion system, and whether it be one-stage or two-stage. It is ideal for all kinds of wastewaters. Currently anaerobic technology is being operated at full scale in many industrialized nations. (author)

  16. Interconnectivity between the Superficial Aquifer and the Deep Confined Aquifers of the Gnangara Mound, Western Australia

    International Nuclear Information System (INIS)

    Perth groundwater resources are obtained from three major aquifers that occur beneath the Perth metropolitan area: the Superficial aquifer, Leederville aquifer and Yarragadee aquifer. Each aquifer has a unique seasonal water level pattern controlled by soils, geomorphology and geology. Land use is mainly responsible for variations in recharge; however, the hydraulic properties control aquifer response and water level pattern to a greater degree. Groundwater in the three aquifers is generally of very good quality except in localised areas. Salinity increases with depth and in direction of groundwater flow in the three aquifers. The best water quality is in the Superficial aquifer in the Wanneroo well field area. The geochemistry and stable isotope signatures from the three major aquifers revealed distinct water types that suggest very little hydraulic connection or mixing of waters between these aquifers at the present abstraction and recharge regimes. The results also show that the Leederville and Yarragadee aquifers were recharged during earlier cooler times while the Superficial aquifer is being recharged at present

  17. Groundwater vulnerability to pollution mapping of Ranchi district using GIS

    OpenAIRE

    Krishna, R.; Iqbal, J.; Gorai, A. K.; Pathak, G.; Tuluri, F.; P. B. Tchounwou

    2014-01-01

    Groundwater pollution due to anthropogenic activities is one of the major environmental problems in urban and industrial areas. The present study demonstrates the integrated approach with GIS and DRASTIC model to derive a groundwater vulnerability to pollution map. The model considers the seven hydrogeological factors [Depth to water table (D), net recharge (R), aquifer media (A), soil media (S), topography or slope (T), impact of vadose zone (I) and hydraulic Conductivity(C)] for generating ...

  18. Anaerobic digestion of aliphatic polyesters.

    Science.gov (United States)

    Šmejkalová, Pavla; Kužníková, Veronika; Merna, Jan; Hermanová, Soňa

    2016-01-01

    Anaerobic processes for the treatment of plastic materials waste represent versatile and effective approach in environmental protection and solid waste management. In this work, anaerobic biodegradability of model aliphatic polyesters, poly(L-lactic acid) (PLA), and poly(ɛ-caprolactone) (PCL), in the form of powder and melt-pressed films with varying molar mass, was studied. Biogas production was explored in batch laboratory trials at 55 ± 1°C under a nitrogen atmosphere. The inoculum used was thermophilic digested sludge (total solids concentration of 2.9%) from operating digesters at the Central Waste Water Treatment Plant in Prague, Czech Republic. Methanogenic biodegradation of PCLs typically yielded from 54 to 60% of the theoretical biogas yield. The biodegradability of PLAs achieved from 56 to 84% of the theoretical value. High biogas yield (up to 677 mL/g TS) with high methane content (more than 60%), comparable with conventionally processed materials, confirmed the potential of polyester samples for anaerobic treatment in the case of their exploitation in agriculture or as a packaging material in the food industry. PMID:27191559

  19. Isotope hydrological investigation in Thiruvanmiyur aquifer Chennai, Tamil Nadu

    International Nuclear Information System (INIS)

    Hydrosalinity evolution and interconnections between aquifers is examined in Thiruvanmiyur aquifer situated south of Chennai, Tamil Nadu. Different aquifer systems have been differentiated using environmental tritium, stable isotope (18O) and hydrological data. Results show that groundwater salinity is due to dissolution of aquifer material and possibility of aquifer interconnections is remote. (author)

  20. Environmental Pollution

    International Nuclear Information System (INIS)

    This book tells US that what nature is, which gives descriptions of the world of living things like the role of plant, order of the vegetable kingdom, the world of plant, destruction of the natural world, and the world of bugs, nature and human with man's survive and change of nature, environment and human, and in creasing population and environment, philosophy of conservation of nature on meaning, destroy and management, and direction, air pollution spot, water pollution, soil pollution conservation of nature and industry case of foreign country and view of environment and environmental assimilating capacity.

  1. Innovative reactive layer to enhance soil aquifer treatment: successful installation in the Llobregat aquifer (Catalonia, ne Spain)

    Energy Technology Data Exchange (ETDEWEB)

    Hernandez, M.; Gilbert, O.; Bernat, X.; Valhondo, C.; Kock-Schulmeyer, M.; Huerta-Fontela, M.; Colomer, M. V.

    2014-10-01

    The Life+ ENSAT project has demonstrated the effectiveness of a reactive organic layer on the improvement of recharge water quality in an aquifer recharge system. The vegetal compost layer was installed at the bottom of an existing infiltration pond in the Llobregat Lower Valley (Barcelona region) with the purpose of promoting biodegradation and improving the removal emerging micro-pollutants from Llobregat River water. A comprehensive monitoring of water quality including bulk chemistry, emerging micro-pollutants and priority substances indicated that hydro biochemical changes within the organic layer enhance denitrification processes and reduce the levels of gemfibrozil and carbamazepine TP. This effect is due to the release of dissolved organic carbon which promotes biodegradation processes at local scale in the unsaturated zones, without affecting the furthest piezometers. The reactive layer is still active more than 3 years after its installation. The economic assessment of this innovative reactive layer shows that it is a promising solution for the improvement of aquifer recharge with low quality waters, not only technically but also from the economic sustainability standpoint. (Author)

  2. Innovative reactive layer to enhance soil aquifer treatment: successful installation in the Llobregat aquifer (Catalonia, ne Spain)

    International Nuclear Information System (INIS)

    The Life+ ENSAT project has demonstrated the effectiveness of a reactive organic layer on the improvement of recharge water quality in an aquifer recharge system. The vegetal compost layer was installed at the bottom of an existing infiltration pond in the Llobregat Lower Valley (Barcelona region) with the purpose of promoting biodegradation and improving the removal emerging micro-pollutants from Llobregat River water. A comprehensive monitoring of water quality including bulk chemistry, emerging micro-pollutants and priority substances indicated that hydro biochemical changes within the organic layer enhance denitrification processes and reduce the levels of gemfibrozil and carbamazepine TP. This effect is due to the release of dissolved organic carbon which promotes biodegradation processes at local scale in the unsaturated zones, without affecting the furthest piezometers. The reactive layer is still active more than 3 years after its installation. The economic assessment of this innovative reactive layer shows that it is a promising solution for the improvement of aquifer recharge with low quality waters, not only technically but also from the economic sustainability standpoint. (Author)

  3. Ground water pollution: General studies. (Latest citations from the NTIS bibliographic database). Published Search

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-05-01

    The bibliography contains citations concerning sources, contaminant transport, and monitoring of pollutants in aquifers. Topics include pollution characterization from landfills and mine drainage, descriptions of study programs undertaken by specific states, and Superfund site studies of contaminated areas. The uses of mathematical models are also discussed. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  4. Organic micropollutants in aerobic and anaerobic membrane bioreactors: Changes in microbial communities and gene expression

    KAUST Repository

    Harb, Moustapha

    2016-07-09

    Organic micro-pollutants (OMPs) are contaminants of emerging concern in wastewater treatment due to the risk of their proliferation into the environment, but their impact on the biological treatment process is not well understood. The purpose of this study is to examine the effects of the presence of OMPs on the core microbial populations of wastewater treatment. Two nanofiltration-coupled membrane bioreactors (aerobic and anaerobic) were subjected to the same operating conditions while treating synthetic municipal wastewater spiked with OMPs. Microbial community dynamics, gene expression levels, and antibiotic resistance genes were analyzed using molecular-based approaches. Results showed that presence of OMPs in the wastewater feed had a clear effect on keystone bacterial populations in both the aerobic and anaerobic sludge while also significantly impacting biodegradation-associated gene expression levels. Finally, multiple antibiotic-type OMPs were found to have higher removal rates in the anaerobic MBR, while associated antibiotic resistance genes were lower.

  5. Organic micropollutants in aerobic and anaerobic membrane bioreactors: Changes in microbial communities and gene expression.

    Science.gov (United States)

    Harb, Moustapha; Wei, Chun-Hai; Wang, Nan; Amy, Gary; Hong, Pei-Ying

    2016-10-01

    Organic micro-pollutants (OMPs) are contaminants of emerging concern in wastewater treatment due to the risk of their proliferation into the environment, but their impact on the biological treatment process is not well understood. The purpose of this study is to examine the effects of the presence of OMPs on the core microbial populations of wastewater treatment. Two nanofiltration-coupled membrane bioreactors (aerobic and anaerobic) were subjected to the same operating conditions while treating synthetic municipal wastewater spiked with OMPs. Microbial community dynamics, gene expression levels, and antibiotic resistance genes were analyzed using molecular-based approaches. Results showed that presence of OMPs in the wastewater feed had a clear effect on keystone bacterial populations in both the aerobic and anaerobic sludge while also significantly impacting biodegradation-associated gene expression levels. Finally, multiple antibiotic-type OMPs were found to have higher removal rates in the anaerobic MBR, while associated antibiotic resistance genes were lower. PMID:27441825

  6. Molecular ecology of anaerobic reactor systems

    DEFF Research Database (Denmark)

    Hofman-Bang, H. Jacob Peider; Zheng, D.; Westermann, Peter; Ahring, Birgitte Kiær; Raskin, L.

    2003-01-01

    Anaerobic reactor systems are essential for the treatment of solid and liquid wastes and constitute a core facility in many waste treatment plants. Although much is known about the basic metabolism in different types of anaerobic reactors, little is known about the microbes responsible for these ...... specific nucleic acid probes are discussed and exemplified by studies of anaerobic granular sludge, biofilm and digester systems...... malfunctions of anaerobic digesters occasionally experienced, leading to sub-optimal methane production and wastewater treatment. Using a variety of molecular techniques, we are able to determine which microorganisms are active, where they are active, and when they are active, but we still need to determine...... abundance of each microbe in anaerobic reactor systems by rRNA probing. This chapter focuses on various molecular techniques employed and problems encountered when elucidating the microbial ecology of anaerobic reactor systems. Methods such as quantitative dot blot/fluorescence in-situ probing using various...

  7. Digital data sets that describe aquifer characteristics of the Elk City aquifer in western Oklahoma

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set consists of digitized polygons of constant hydraulic conductivity values for the Elk City aquifer in western Oklahoma. The aquifer covers an area of...

  8. Digital data sets that describe aquifer characteristics of the Enid isolated terrace aquifer in northwestern Oklahoma

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set consists of digitized water-level elevation contours for the Enid isolated terrace aquifer in northwestern Oklahoma. The Enid isolated terrace aquifer...

  9. Digital data sets that describe aquifer characteristics of the Elk City aquifer in western Oklahoma

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set consists of digitized polygons of constant recharge values for the Elk City aquifer in western Oklahoma. The aquifer covers an area of approximately...

  10. Digital data sets that describe aquifer characteristics of the Elk City aquifer in western Oklahoma

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set consists of digitized water-level elevation contours for the Elk City aquifer in western Oklahoma. The aquifer covers an area of approximately 193,000...

  11. Digital data sets that describe aquifer characteristics of the Rush Springs aquifer in western Oklahoma

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set consists of digitized aquifer boundaries for the Rush Springs aquifer in western Oklahoma. This area encompasses all or part of Blaine, Caddo,...

  12. Digital data sets that describe aquifer characteristics of the Antlers aquifer in southeastern Oklahoma

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set consists of digitized aquifer boundaries of the Antlers aquifer in southeastern Oklahoma. The Early Cretaceous-age Antlers Sandstone is an important...

  13. Digital data sets that describe aquifer characteristics of the High Plains aquifer in western Oklahoma

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set consists of digital aquifer boundaries for the High Plains aquifer in western Oklahoma. This area encompasses the panhandle counties of Cimarron,...

  14. Nitrate pollution of groundwater; all right…, but nothing else?

    Science.gov (United States)

    Menció, Anna; Mas-Pla, Josep; Otero, Neus; Regàs, Oriol; Boy-Roura, Mercè; Puig, Roger; Bach, Joan; Domènech, Cristina; Zamorano, Manel; Brusi, David; Folch, Albert

    2016-01-01

    Contamination from agricultural sources and, in particular, nitrate pollution, is one of the main concerns in groundwater management. However, this type of pollution entails the entrance of other substances into the aquifer, as well as it may promote other processes. In this study, we deal with hydrochemical and isotopic analysis of groundwater samples from four distinct zones in Catalonia (NE Spain), which include 5 different aquifer types, to investigate the influence of fertilization on the overall hydrochemical composition of groundwater. Results indicate that intense fertilizer application, causing high nitrate pollution in aquifers, also homogenize the contents of the major dissolved ions (i.e.; Cl(-), SO4(2-), Ca(2+), Na(+), K(+), and Mg(2+)). Thus, when groundwater in igneous and sedimentary aquifers is compared, significant differences are observed under natural conditions for Cl(-), Na(+) and Ca(2+) (with p-values ranging from agricultural pollution, but to their enhancing effect upon the biogeochemical processes that control water-rock interactions. Such results raise awareness that these processes should be evaluated in advance in order to assess an adequate groundwater resources management. PMID:26363397

  15. Hydrochemistry of New Zealand's aquifers

    International Nuclear Information System (INIS)

    Groundwater chemistry on a national scale has never been studied in New Zealand apart from a few studies on nitrate concentrations and pesticides. These studies are covered in Chapter 8 of this book. However general studies of groundwater chemistry, groundwater-rock interaction and regional characteristics of water quality have not been previously addressed in much detail. This is partly because New Zealand aquifers are relatively small on a world scale and are geologically and tectonically diverse (see Chapter 3). But New Zealand has also recently lacked a centralised agency responsible for groundwater quality, and therefore, no national assessments have been undertaken. In recent years, the Institute of Geological and Nuclear Sciences has managed a programme of collecting and analysing the groundwater chemistry of key New Zealand aquifers. This programme is called the National Groundwater Monitoring Programme (NGMP) and is funded by the New Zealand Public Good Science Fund. The programme started in 1990 using only 22 wells, with four regional authorities of the country participating. The NGMP now includes all 15 regional and unitary authorities that use groundwater and over 100 monitoring sites. The NGMP is considered a nationally significant database by the New Zealand Foundation for Research Science and Technology. The NGMP allows a national comparison of aquifer chemistries because the samples are all analysed at one laboratory in a consistent manner and undergo stringent quality control checks. Poor quality analyses are thus minimised. In addition, samples are collected quarterly so that long-term seasonal trends in water quality can be analysed, and the effects of changes in land use and the vulnerability of aquifers to contaminant leaching can be assessed. This chapter summarises the water quality data collected for the NGMP over the past 10 years. Some records are much shorter than others, but most are greater than three years. Additional information is

  16. Light Pollution

    Science.gov (United States)

    Riegel, Kurt W.

    1973-01-01

    Outdoor lighting is light pollution which handicaps certain astronomical programs. Protective measures must be adopted by the government to aid observational astronomy without sacrificing legitimate outdoor lighting needs. (PS)

  17. Monitoring of the hydrocarbons changes in the aquifer of a petroleum refinery

    International Nuclear Information System (INIS)

    This paper presents the results of a study in which the soil and groundwater near an oil refinery was subjected to hydrogeochemical and hydrogeological surveys to determine if petroleum products had leaked from tanks and pipes. Polluted groundwater had been observed in the area for the past 15 years. The main soil and groundwater pollutants are polycyclic aromatic hydrocarbons (PAH), benzene, toluene, and xylene (BTX) and non-aqueous phase liquids (LNAPL). The pollutants remain on the surface of a local aquifer in free phase. Three hydrocarbon plumes were also observed in the porous aquifer near the refinery. Accurate information of the prevailing conditions was needed in order to effectively assess potential remediation measures. Pollution fingerprinting and bioslurping were applied in an effort to monitor and evaluate the prevailing pollution status. Most of the free phase compounds are volatile or semi volatile hydrocarbons, which means that air sparging may effectively remove the groundwater pollutants. The installation of an active groundwater remediation system was also recommended following the recovery of free phase liquids. 4 refs., 8 figs

  18. Air pollution

    International Nuclear Information System (INIS)

    Australian cites experience a number of current and emerging air pollution problems. Concentrations of traditional primary pollutants such as CO, lead and dust have fallen in recent years as a consequence of air pollutant control measures, and the widespread introduction of lead-free petrol. However, recommended guidelines for ozone, the principal component of photochemical smog, are regularly exceeded in major capital cities in the summer months. In addition, it is predicted that extensive urban expansion will lead to much greater dependence on the motor vehicle as the primary means of transportation. Effects of air pollution are felt at a variety of scales. Traditionally, concerns about gaseous and particulate emissions from industrial and vehicular sources were focused on local impacts due to exposure to toxic species such as CO and lead. As noted above, concentrations of these pollutants have been reduced by a variety of control measures. Pollutants which have effects at a regional scale, such as photochemically-produced ozone, and acidic gases and particles have proved more difficult to reduce. In general, these pollutants arc not the result of direct emissions to atmosphere, but result from complex secondary processes driven by photochemical reactions of species such as NO2 and aldehydes. In addition, global effects of gaseous and particulate emissions to the atmosphere have received significant recent attention, concentrations of atmospheric CO2 with predicted impacts on global climate, and ozone depletion due to anthropogenic emissions of chlorine-containing chemicals are the two major examples. Combustion processes from petrol- and diesel-fuelled vehicles, make major contributions to air pollution, and the magnitude of this contribution is discussed in this article

  19. In vitro susceptibility testing of anaerobic bacteria.

    Science.gov (United States)

    Washington, J A

    1979-01-01

    In vitro susceptibility testing of anaerobic bacteria should be limited to isolates from persistent or recurrent infections that have been treated adequately and appropriately with antimicrobial agents and, in reference centers, to collections of isolates in order to monitor alterations in susceptibility of species to various antimicrobial agents. An agar dilution reference method is being evaluated currently; however, practicality limits sporadic testing of single isolates to disk elution or broth dilution techniques. No single disk diffusion method has yet been found to be acceptable for testing anaerobic bacteria, and the results obtained with standardized procedures for aerobic and facultatively anaerobic bacteria are not applicable to anaerobic bacteria. PMID:288163

  20. Anaerobic co-digestion of dairy manure and potato waste

    Science.gov (United States)

    Yadanaparthi, Sai Krishna Reddy

    Dairy and potato are two important agricultural commodities in Idaho. Both the dairy and potato processing industries produce a huge amount of waste which could cause environmental pollution. To minimize the impact of potential pollution associated with dairy manure (DM) and potato waste (PW), anaerobic co-digestion has been considered as one of the best treatment process. The purpose of this research is to evaluate the anaerobic co-digestion of dairy manure and potato waste in terms of process stability, biogas generation, construction and operating costs, and potential revenue. For this purpose, I conducted 1) a literature review, 2) a lab study on anaerobic co-digestion of dairy manure and potato waste at three different temperature ranges (ambient (20-25°C), mesophilic (35-37°C) and thermophilic (55-57°C) with five mixing ratios (DM:PW-100:0, 90:10, 80:20, 60:40, 40:60), and 3) a financial analysis for anaerobic digesters based on assumed different capital costs and the results from the lab co-digestion study. The literature review indicates that several types of organic waste were co-digested with DM. Dairy manure is a suitable base matter for the co-digestion process in terms of digestion process stability and methane (CH4) production (Chapter 2). The lab tests showed that co-digestion of DM with PW was better than digestion of DM alone in terms of biogas and CH4 productions (Chapter 3). The financial analysis reveals DM and PW can be used as substrate for full size anaerobic digesters to generate positive cash flow within a ten year time period. Based on this research, the following conclusions and recommendations were made: ▸ The ratio of DM:PW-80:20 is recommended at thermophilic temperatures and the ratio of DM:PW-90:10 was recommended at mesophilic temperatures for optimum biogas and CH4 productions. ▸ In cases of anaerobic digesters operated with electricity generation equipment (generators), low cost plug flow digesters (capital cost of 600/cow

  1. An evaluation of aquifer intercommunication between the unconfined and Rattlesnake Ridge aquifers on the Hanford Site

    International Nuclear Information System (INIS)

    During 1986, Pacific Northwest Laboratory conducted a study of a portion of the Rattlesnake Ridge aquifer (confined aquifer) that lies beneath the B Pond - Gable Mountain Pond area of the Hanford Site. The purpose was to determine the extent of intercommunication between the unconfined aquifer and the uppermost regionally extensive confined aquifer, referred to as the Rattlesnake Ridge aquifer. Hydraulic head data and chemical data were collected from the ground water in the study area during December 1986. The hydraulic head data were used to determine the effects caused by water discharged to the ground from B Pond on both the water table of the unconfined aquifer and the potentiometric surface of the confined aquifer. The chemical data were collected to determine the extent of chemical constituents migrating from the unconfined aquifer to the confined aquifer. Analysis of chemical constituents in the Rattlesnake Ridge aquifer demonstrated that communication between the unconfined and confined aquifers had occurred. However, the levels of contaminants found in the Rattlesnake Ridge aquifer during this study were below the DOE Derived Concentration Guides

  2. Ground Pollution Science

    International Nuclear Information System (INIS)

    This book deals with ground pollution science and soil science, classification of soil and fundamentals, ground pollution and human, ground pollution and organic matter, ground pollution and city environment, environmental problems of the earth and ground pollution, soil pollution and development of geological features of the ground, ground pollution and landfill of waste, case of measurement of ground pollution.

  3. Draft Genome Sequence of MCPA-Degrading Sphingomonas sp. Strain ERG5, Isolated from a Groundwater Aquifer in Denmark

    DEFF Research Database (Denmark)

    Nielsen, Tue Kjærgaard; Kot, Witold; Sørensen, Sebastian R;

    2015-01-01

    Sphingomonas sp. strain ERG5 was isolated from a bacterial community, originating from a groundwater aquifer polluted with low pesticide concentrations. This bacterium degrades 2-methyl-4-chlorophenoxyacetic acid (MCPA) in a wide spectrum of concentrations and has been shown to function in...

  4. Anaerobic digestion of stillage to produce bioenergy in the sugarcane-to-ethanol industry.

    Science.gov (United States)

    Fuess, Lucas Tadeu; Garcia, Marcelo Loureiro

    2014-01-01

    Stillage is the main wastewater from ethanol production, containing a high chemical oxygen demand in addition to acidic and corrosive characteristics. Though stillage may be used as a soil fertilizer, its land application may be considered problematic due its high polluting potential. Anaerobic digestion represents an effective alternative treatment to reduce the pollution load of stillage. In addition, the methane gas produced within the process may be converted to energy, which can be directly applied to the treatment plant. The objective of this paper was to investigate the energetic potential of anaerobic digestion applied to stillage in the sugarcane ethanol industry. An overall analysis of the results indicates energy recovery capacity (ERC) values for methane ranging from 3.5% to 10%, respectively, for sugarcane juice and molasses. The processes employed to obtain the fermentable broth, as well as the distillation step, represent the main limiting factors to the energetic potential feasibility. Considering financial aspects the annual savings could reach up to US$ 30 million due to anaerobic digestion of stillage in relatively large-scale distilleries (365,000 m3 of ethanol per year). The best scenarios were verified for the association between anaerobic digestion of stillage and combustion of bagasse. In this case, the fossil fuels consumption in distilleries could be fully ceased, such the ERC of methane could reach values ranging from 140% to 890%. PMID:24600872

  5. Regional water quality patterns in an alluvial aquifer: Direct and indirect influences of rivers

    Science.gov (United States)

    Baillieux, A.; Campisi, D.; Jammet, N.; Bucher, S.; Hunkeler, D.

    2014-11-01

    The influence of rivers on the groundwater quality in alluvial aquifers can be twofold: direct and indirect. Rivers can have a direct influence via recharge and an indirect one by controlling the distribution of fine-grained, organic-carbon rich flood deposits that induce reducing conditions. These direct and indirect influences were quantified for a large alluvial aquifer on the Swiss Plateau (50 km2) in interaction with an Alpine river using nitrate as an example. The hydrochemistry and stable isotope composition of water were characterized using a network of 115 piezometers and pumping stations covering the entire aquifer. Aquifer properties, land use and recharge zones were evaluated as well. This information provided detailed insight into the factors that control the spatial variability of groundwater quality. Three main factors were identified: (1) diffuse agricultural pollution sources; (2) dilution processes resulting from river water infiltrations, revealed by the δ18OH2O and δ2HH2O contents of groundwater; and (3) denitrification processes, controlled by the spatial variability of flood deposits governed by fluvial depositional processes. It was possible to quantify the dependence of the nitrate concentration on these three factors at any sampling point of the aquifer using an end-member mixing model, where the average nitrate concentration in recharge from the agricultural area was evaluated at 52 mg/L, and the nitrate concentration of infiltrating river at approximately 6 mg/L. The study shows the importance of considering the indirect and direct impacts of rivers on alluvial aquifers and provides a methodological framework to evaluate aquifer scale water quality patterns.

  6. Evolution of carbon isotope signatures during reactive transport of hydrocarbons in heterogeneous aquifers

    Science.gov (United States)

    Höyng, Dominik; Prommer, Henning; Blum, Philipp; Grathwohl, Peter; Mazo D'Affonseca, Fernando

    2015-03-01

    Compound-specific isotope analysis (CSIA) of organic pollutants has become a well-established tool for assessing the occurrence and extent of biodegradation processes in contaminated aquifers. However, the precision of CSIA is influenced by the degree to which assumptions underlying CSIA data interpretation hold under realistic field-scale conditions. For the first time this study demonstrates how aquifer analogs combined with reactive transport models offer an underexplored way to develop generic process understanding, evaluate monitoring and quantification strategies in highly heterogeneous subsurface settings. Data from high-resolution aquifer analogs were used in numerical experiments to track the propagation of a representative oxidizable organic compound (toluene) within a variety of realistic heterogeneous aquifers and to investigate its detailed fate. The simulations were used to analyze (1) the effects of physical aquifer heterogeneities on spatiotemporal patterns of contaminant concentrations and isotope signatures, (2) the performance of the commonly applied Rayleigh equation and (3) the applicability of an extension of the Rayleigh equation for complex hydrogeological conditions. The results indicate that if field-derived enrichment factors are applied without corrections for dilution, the conventional Rayleigh equation is inaccurate and estimates for biodegradation are typically overestimated and unreliable in heterogeneous aquifers. Underestimations can occur due to the partial source zone depletion. In contrast, if dilution can be accurately accounted for, field-derived enrichment factors comprise a suitable alternative to laboratory-derived and redox-specific enrichment factors. The study also examines to what extent variations in monitoring/sampling strategies influence the obtained results. Especially measurements from long-screened wells (> 1 m) reveal to be inappropriate for the application of the Rayleigh equation in the investigated aquifer

  7. Hydrogeochemistry and isotopic tracing of nitrate contamination of two aquifer systems on Jeju Island, Korea.

    Science.gov (United States)

    Koh, Eun-Hee; Kaown, Dugin; Mayer, Bernhard; Kang, Bong-Rae; Moon, Hee Sun; Lee, Kang-Kun

    2012-01-01

    The groundwater of Jeju Island (Republic of Korea) is vulnerable to contamination because its aquifers are mainly composed of highly permeable geological units and its agricultural fields are often exposed to excessive use of predominantly synthetic fertilizers. In the Gosan area of Jeju Island, we investigated nitrate contamination in both a perched aquifer above an impermeable clay bed and the regional groundwater beneath this aquitard. The δO and δD values indicate that the perched groundwater is recharged by local precipitation, whereas the regional groundwater is recharged mainly by regional flow from an adjacent mountainous region. The perched groundwater contained very high NO-N concentrations of up to 87 mg/L. The isotopic composition of nitrate in the perched groundwater showed that synthetic fertilizers applied in high excesses of crop N needs were the main cause of aquifer pollution. Elevated nitrate concentrations were also observed in the regional groundwater especially after precipitation events. Concentration and isotopic data revealed that the inflow of shallow perched groundwater along the poorly cemented or uncemented annulus of regional groundwater wells was one of the main reasons for the nitrate contamination observed in the regional groundwater. In both aquifers, δN and δO values showed that the sources of nitrate were derived from synthetic fertilizers that had been recycled in the soil zone by nitrification and in some portions of the perched aquifer (dissolved oxygen concentrations <2 mg/L) indicated that denitrification occurred locally. PMID:23128740

  8. Intrinsic vulnerability assessment of Sette Comuni Plateau aquifer (Veneto Region, Italy).

    Science.gov (United States)

    Cucchi, Franco; Franceschini, Giuliana; Zini, Luca; Aurighi, Marina

    2008-09-01

    Maps illustrating the different degrees of vulnerability within a given area are integral to environmental protection and management policies. The assessment of the intrinsic vulnerability of karst areas is difficult since the type and stage of karst development and the related underground discharge behavior are difficult to determine and quantify. Geographic Information Systems techniques are applied to the evaluation of the vulnerability of an aquifer in the alpine karst area of the Sette Comuni Plateau, in the Veneto Region of northern Italy. The water resources of the studied aquifer are of particular importance to the local communities. This aquifer must therefore be protected from both inappropriate use as well as possible pollution. The SINTACS and SINTACS P(RO) K(ARST) vulnerability assessment methods have been utilized here to create the vulnerability map. SINTACS P(RO) K(ARST) is an adaptation of the parametric managerial model (SINTACS) to karst hydrostructures. The vulnerability map reveals vast zones (81% of the analyzed areas) with a high degree of vulnerability. The presence of well-developed karst structures in these highly vulnerable areas facilitate water percolation, thereby enhancing the groundwater vulnerability risk. Only 1.5 of the studied aquifer have extremely high-vulnerability levels, however these areas include all of the major springs utilized for human consumption. This vulnerability map of the Sette Comuni Plateau aquifer is an indispensable tool for both the effective management of water resources and as support to environmental planning in the Sette Comuni Plateau area. PMID:17628323

  9. [Studies on the anaerobic phased solid digester system for municipal solid waste (MSW) treatment].

    Science.gov (United States)

    Wang, Jun-qin; Shen, Dong-sheng

    2004-05-01

    Through analyzing and detecting the leaching pollutant (COD) in two bioreactors, anaerobic phased solid digester system and leachate direct-recirculating landfill, the changing rule of municipal solid waste and the characteristics of methanogenesis were studied. The results showed that anaerobic phased solid digester system accelerated the process of degrading municipal solid waste and stabilizing landfill site. The relationship between the leaching pollutant (COD) and refuse age was logarithmic linear correlation. More than 80% of biogas in volume occured in the methanogenisis bioreactor, the methane content in which was 55%-69%. The preferable volumetric COD loading rate of the methanogenisis bioreactor was 6.5-7.5 g/(L x d). PMID:15327275

  10. Anaerobic degradation of aromatic hydrocarbons

    International Nuclear Information System (INIS)

    This paper reports that toluene and m-xylene were rapidly mineralized in a denitrifying laboratory aquifer column operated under continuous flow conditions in the complete absence of molecular oxygen. A bacterium, tentatively identified as a Pseudomonas sp., was isolated from this column. This organism mineralized toluene and m-xylene under pure culture conditions with nitrate or nitrous oxide as the sole electron acceptors. Carbon balance studies using 0.3mM [ring-UL-14C]toluene revealed that more than 50 percent of the radioactivity was evolved as 14CO2

  11. Digital data sets that describe aquifer characteristics of the Vamoosa-Ada aquifer in east-central Oklahoma

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set consists of digitized aquifer boundaries for the Vamoosa-Ada aquifer in east-central Oklahoma. The Vamoosa-Ada aquifer is an important source of water...

  12. Digital data sets that describe aquifer characteristics of the Tillman terrace and alluvial aquifer in southwestern Oklahoma

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set consists of digital aquifer boundaries for the Tillman terrace and alluvial aquifer in southwestern Oklahoma. The Tillman terrace aquifer encompasses...

  13. Anaerobic Capacities of Leaf Litter

    OpenAIRE

    Kusel, K.; Drake, H L

    1996-01-01

    Leaf litter displayed a capacity to spontaneously form organic acids, alcohols, phenolic compounds, H(inf2), and CO(inf2) when incubated anaerobically at 20(deg)C either as buffered suspensions or in a moistened condition in microcosms. Acetate was the predominant organic product formed regardless of the degree of litter decomposition. Initial rates of acetate formation in litter suspensions and microcosms approximated 2.6 and 0.53 (mu)mol of acetate per g (dry weight) of litter per h, respec...

  14. Anaerobic digestion of coffee waste

    OpenAIRE

    L. Neves; Ribeiro, R.; Oliveira, Rosário; Alves, M. M.

    2005-01-01

    The anaerobic co-digestion of five different by-products from instant coffee substitutes production was studied in mesophilic conditions. The co-substrate was the excess of sewage sludge from the wastewater treatment plant located in the same coffee factory. Four of the tested wastes produced methane in the range of 0.24-0.28 m³CH4(STP)/kgVSinitial . Reduction of 50-73% in total solids and 75-80% in volatile solids were obtained and the hydrolysis rate constants were in the ran...

  15. Ultrasonic cell disruption of stabilised sludge with subsequent anaerobic digestion.

    Science.gov (United States)

    Onyeche, T I; Schläfer, O; Bormann, H; Schröder, C; Sievers, M

    2002-05-01

    The world-wide increasing environmental awareness and its subsequent regulations have led to the application of improved technologies in wastewater purification plants. This has resulted in higher wastewater and sludge productions. Sludge is the by-product of such plants and it is not only rich in organic carbon and pathogens but also in heavy metals and other environmental pollutants. In Europe, agricultural application of dried sludge (bio-solids) is confronted with negative reactions from the citizens, governmental organisations, farmers and the food industry. Ultrasonic disruption of sludge is a popular mechanical disruption process in sludge treatment. During ultrasonic treatment, high frequency acoustic signals are used to initiate the cavitation process. The applied ultrasonic field leads to a breakdown of cohesive forces of the liquid molecules resulting in the generation of cavitation bubbles. A shock wave is released by the collapse of the cavitation bubbles and propagates in the surrounding medium forming jet streams that cause the disruption of cells in sludge. Disruption of sludge cells enables the release of light organic substances into the sludge water thereby exposing them for further anaerobic digestion. This paper presents results on the disruption of conventionally stabilised sludge through the application of the ultrasonic field. In order to reduce the specific energy input (i.e. ratio of the consumed energy during ultrasonic disruption to the input sludge mass) and improve biogas production, the total solids content of the stabilised sludge was increased before disruption. The anaerobic digestion of sludge samples was carried out in a set of specially constructed laboratory anaerobic digesters. Results showed that subsequent anaerobic digestion of the ultrasonically disrupted sludge could improve biogas production with reduced sludge quantity that is vital to the economic consideration of the wastewater treatment plants. This process

  16. Geochemistry and mineralogy of arsenic in (natural) anaerobic groundwaters

    International Nuclear Information System (INIS)

    Here new data from field bioremediation experiments and geochemical modeling are reported to illustrate the principal geochemical behavior of As in anaerobic groundwaters. In the field bioremediation experiments, groundwater in Holocene alluvial aquifers in Bangladesh was amended with labile water-soluble organic C (molasses) and MgSO4 to stimulate metabolism of indigenous SO4-reducing bacteria (SRB). In the USA, the groundwater was contaminated by Zn, Cd and SO4, and contained 1000 μg/L) under geochemical conditions consistent with bacterial Fe-reducing conditions. With time, groundwater became more reducing and biogenic SO4 reduction began, and Cd and Zn were virtually completely removed due to precipitation of sphalerite (ZnS) and other metal sulfide mineral(s). Following precipitation of chalcophile elements Zn and Cd, the concentrations of Fe and As both began to decrease in groundwater, presumably due to formation of As-bearing FeS/FeS2. By the end of the six-month experiment, dissolved As had returned to below background levels. In the initial Bangladesh experiment, As decreased to virtually zero once biogenic SO4 reduction commenced but increased to pre-experiment level once SO4 reduction ended. In the ongoing experiment, both SO4 and Fe(II) were amended to groundwater to evaluate if FeS/FeS2 formation causes longer-lived As removal. Because As-bearing pyrite is the common product of SRB metabolism in Holocene alluvial aquifers in both the USA and Southeast Asia, it was endeavored to derive thermodynamic data for arsenian pyrite to better predict geochemical processes in naturally reducing groundwaters. Including the new data for arsenian pyrite into Geochemist's Workbench, its stability field completely dominates in reducing Eh-pH space and 'displaces' other As-sulfides (orpiment, realgar) that have been implied to be important in previous modeling exercises and reported in rare field conditions. In summary, when anaerobic bacterial metabolism is

  17. Hydro-geological properties of the Savian aquifer in the county Obrenovac

    Directory of Open Access Journals (Sweden)

    Stojadinović Dušan D.

    2005-01-01

    Full Text Available The paper presents a description of hydrogeological researches of alluvial layers of the Sava River in the area of the source "Vić Bare" near Obrenovac. This source supplies groundwater to that town. The depth of these layers amounts to 25 m. With regard to collecting capacity, the most significant are gravel-sand sediments of high filtration properties. Their average depth amounts to about 13 m with the underlying layer made of Pleistocene clays. Compact aquifer is formed within these sediments and it refills partly from the Sava River at places where river cuts its channel into the gravel-sand layer. The analysis of the groundwater regime in the riparian area points out that groundwater levels follow stages of the Sava River. Such an influence lessens with the distance. Established hydraulic connection between the river and the aquifer enables its permanent replenishment. On the other hand, due to certain pollutions this river flow might bring along, it represents a potential danger. Those pollutions could enter water-bearing layer of the aquifer as well as the exploitation well of the source. Such presumptions have been confirmed in the experiment of pollution transport carried out in the water-bearing layer. Unabsorbable chloride was used as a tracer whose movement velocity through exploitation well proved that there were real possibilities of intrusion of aggressive pollutants into the water-bearing layer and into the aquifer as well. Therefore, the protection of the source must be in the function of the protection of surface waters.

  18. Fate of MTBE and DCPD Compounds Relative to BTEX in Gasoline-Contaminated Aquifers

    OpenAIRE

    Olivella, L.; Figueras, M.; J. Fraile; Vilanova, M.; Ginebreda, A.; Barceló, D.

    2002-01-01

    The aim of this communication is to provide preliminary results on MTBE monitoring, and at the same time to propose some new tracers of gasoline pollution in groundwater. An overview is presented on benzene-toluene-ethylbenzene-xylene (BTEX), methyl tertiary-butyl ether (MTBE), and dicyclopentadienes (DCPD) contents in gasoline formulations. Their specific fate in gasoline-contaminated aquifers are consistent with their physical-chemical properties.

  19. Anaerobic digestion of oily wastewater as a valuable source of bioenergy

    OpenAIRE

    Cavaleiro, A. J.; Salvador, Andreia Filipa Ferreira; Alves, M. M.

    2008-01-01

    Lipids are a group of organic pollutants whose conversion into biogas has been considered very difficult. During the anaerobic treatment of lipid-rich wastewater this conversion generally decreases with the increase of the organic loading rate (OLR) applied, due to long chain fatty acids (LCFA) accumulation. To overcome this problem, correct equilibrium between LCFA accumulation and degradation should be assured [1, 2, 3], and discontinuous operation was proposed by Pereira et ...

  20. Phytoremediation of Anaerobic Digester Effluent for Water Purification and Production of Animal Feed

    OpenAIRE

    Abdel E. Ghaly; H. A. Farag

    2007-01-01

    The application of phytoremediation for purification of an anaerobically treated dairy manure and production of forage crops was investigated. Four crops (two cereals and two grasses) were examined for their ability to grow hydroponically and to remove pollutants (nutrients) from dairy wastewater. The preliminary experiments showed that timothygrass and orchardgrass did not perform well as aquatic plants. Only 24 and 29% of the seeds germinated after 19-21 days giving a crop yield of 21 and 1...

  1. ASSESSMENT OF WASTE TREATMENT AND ENERGY RECOVERY FROM DAIRY INDUSTRIAL WASTE BY ANAEROBIC DIGESTION

    OpenAIRE

    Richa Kothari, Virendra Kumar, and Vineet Veer Tyagi

    2011-01-01

    Waste treatment with simultaneous energy generation was studied in anaerobic digester using dairy industry waste (sludge, influent) as substrate. No pretreatment or solid liquid separation was applied. Batch fermentation experiments were performed with three different substrates at organic pollution load (OPL) under mesophilic range of temperature (30_+C). Experimental data evidence the effectiveness of waste on both the removal efficiency in terms of substrate degradation and biogas yield, p...

  2. A contribution to resource recovery from wastewater. Anaerobic processes for organic matter and nitrogen treatment

    OpenAIRE

    Basset Olivé, Núria

    2015-01-01

    Organic matter and nutrients present in urban and industrial wastewater should be removed or valorised to reduce its impact on the environment. Conventional wastewater treatments are focused on the removal of these pollution sources at the minimum cost. The idea of resource recovery from wastewater is changing the concept of the conventional wastewater treatment plants that tend to incorporate little by little processes as anaerobic digestion, MBR, biofilm, granulation, etc. However, their ap...

  3. Anaerobic granular sludge and biofilm reactors

    DEFF Research Database (Denmark)

    Skiadas, Ioannis V.; Gavala, Hariklia N.; Schmidt, Jens Ejbye; Ahring, Birgitte Kiær

    2003-01-01

    role of the anaerobic digestion in the wastewater treatment plants from a pre-treatment method to the main biological treatment method. The application of staged high-rate anaerobic digesters has shown the larger potential among the recent developments in this direction. The most common high...

  4. Anaerobic Infections in Children with Neurological Impairments.

    Science.gov (United States)

    Brook, Itzhak

    1995-01-01

    Children with neurological impairments are prone to develop serious infection with anaerobic bacteria. The most common anaerobic infections are decubitus ulcers; gastrostomy site wound infections; pulmonary infections (aspiration pneumonia, lung abscesses, and tracheitis); and chronic suppurative otitis media. The unique microbiology of each of…

  5. Instrumentation in anaerobic treatment - research and practice

    NARCIS (Netherlands)

    Spanjers, H.; Lier, van J.B.

    2006-01-01

    High rate anaerobic treatment reactors are able to uncouple solids and liquid retention time, resulting in high biomass concentrations. Principal advantages of anaerobic treatment include: energy efficiency, low biomass yield, low nutrient requirement and high volumetric organic loadings. In order t

  6. Anaerobic degradation of linear alkylbenzene sulfonate

    DEFF Research Database (Denmark)

    Mogensen, Anders Skibsted; Haagensen, Frank; Ahring, Birgitte Kiær

    2003-01-01

    increases during anaerobic stabilization due to transformation of easily degradable organic matter. Hence, LAS is regarded as resistant to biodegradation under anaerobic conditions. We present data from a lab-scale semi-continuously stirred tank reactor (CSTR) spiked with linear dodecylbenzene sulfonate (C...

  7. Geohydrology of the Cerro Prieto geothermal aquifer

    Energy Technology Data Exchange (ETDEWEB)

    Sanchez R, J.; de la Pena L, A.

    1981-01-01

    The most recent information on the Cerro Prieto geothermal aquifer is summarized, with special emphasis on the initial production zone where the wells completed in the Alpha aquifer are located. These wells produce steam for power plant units 1 and 2. Brief comments also are made on the Beta aquifer, which underlies the Alpha aquifer in the Cerro Prieto I area and which extends to the east to what is known as the Cerro Prieto II and Cerro Prieto III areas. The location of the area studied is shown. The Alpha and Beta aquifers differ in their mineralogy and cementing mineral composition, temperatures, and piezometric levels. The difference in piezometric levels indicates that there is no local communication between the two aquifers. This situation has been verified by a well interference test, using well E-1 as a producer in the Beta aquifer and well M-46 as the observation well in the Alpha aquifer. No interference between them was observed. Information on the geology, geohydrology, and geochemistry of Cerro Prieto is presented.

  8. VULNERABILITY OF KARST AQUIFERS TO CHEMICAL CONTAMINATION

    Science.gov (United States)

    Ground water flow in karst aquifers is very different from flow in granular or fractured aquifers. arst ground water flow is often turbulent within discrete conduits that are convergent in the upper reaches and divergent in the lower, simulating discharge to one or more springs. ...

  9. Effects of four aromatic organic pollutants on microbial glucose metabolism and thymidine incorporation in marine sediments

    International Nuclear Information System (INIS)

    The metabolism of D-(U-14C)glucose and the incorporation of (methyl-3H)thymidine by aerobic and anaerobic marine sediment microbes exposed to 1 to 1000 ppm anthracene, naphthalene, p,p'-dichlorodiphenyltrichloroethane, and pentachlorophenol were examined. Cell-specific rates of (14C)glucose metabolism averaged 1.7 x 10-21 and 0.5 x 10-21 mol/min per cell for aerobic and anaerobic sediment slurries, respectively; (3H)thymidine incorporation rates averaged 43 x 10-24 and 9 x 10-24 mol/min per cell for aerobic and anaerobic slurries, respectively. Aerobic sediments exposed to three of the organic pollutants for 2 to 7 days showed recovery of both activities. Anaerobic sediments showed little recovery after 2 days of pre-exposure to the pollutants. The authors conclude that (i) anaerobic sediments are more sensitive than aerobic sediments to pollutant additions; (ii) (3H)thymidine incorporation is more sensitive to pollutant additions than is (14C)glucose metabolism; and (iii) the toxicity of the pollutants increased in the following order: anthracene, p,p'-dichlorodiphenyltrichloroethane, naphthalene, and pentachlorophenol

  10. Anaerobic biorefinery: Current status, challenges, and opportunities.

    Science.gov (United States)

    Sawatdeenarunat, Chayanon; Nguyen, Duc; Surendra, K C; Shrestha, Shilva; Rajendran, Karthik; Oechsner, Hans; Xie, Li; Khanal, Samir Kumar

    2016-09-01

    Anaerobic digestion (AD) has been in use for many decades. To date, it has been primarily aimed at treating organic wastes, mainly manures and wastewater sludge, and industrial wastewaters. However, with the current advancements, a more open mind is required to look beyond these somewhat restricted original applications of AD. Biorefineries are such concepts, where multiple products including chemicals, fuels, polymers etc. are produced from organic feedstocks. The anaerobic biorefinery concept is now gaining increased attention, utilizing AD as the final disposal step. This review aims at evaluating the potential significance of anaerobic biorefineries, including types of feedstocks, uses for the produced energy, as well as sustainable applications of the generated residual digestate. A comprehensive analysis of various types of anaerobic biorefineries has been developed, including both large-scale and household level applications. Finally, future directives are highlighted showing how anaerobic biorefinery concept could impact the bioeconomy in the near future. PMID:27005786

  11. Anaerobic granular sludge and biofilm reactors

    DEFF Research Database (Denmark)

    Skiadas, Ioannis V.; Gavala, Hariklia N.; Schmidt, Jens Ejbye;

    2003-01-01

    The long retention time of the active biomass in the high-rate anaerobic digesters is the key factor for the successful application of the high rate anaerobic wastewater treatment. The long solids retention time is achieved due to the specific reactor configuration and it is enhanced...... by the immobilization of the biomass, which forms static biofilms, particle-supported biofilms, or granules depending on the reactor's operational conditions. The advantages of the high-rate anaerobic digestion over the conventional aerobic wastewater treatment methods has created a clear trend for the change...... of the role of the anaerobic digestion in the wastewater treatment plants from a pre-treatment method to the main biological treatment method. The application of staged high-rate anaerobic digesters has shown the larger potential among the recent developments in this direction. The most common high...

  12. Molecular ecology of anaerobic reactor systems

    DEFF Research Database (Denmark)

    Hofman-Bang, H. Jacob Peider; Zheng, D.; Westermann, Peter;

    2003-01-01

    Anaerobic reactor systems are essential for the treatment of solid and liquid wastes and constitute a core facility in many waste treatment plants. Although much is known about the basic metabolism in different types of anaerobic reactors, little is known about the microbes responsible...... to the abundance of each microbe in anaerobic reactor systems by rRNA probing. This chapter focuses on various molecular techniques employed and problems encountered when elucidating the microbial ecology of anaerobic reactor systems. Methods such as quantitative dot blot/fluorescence in-situ probing using various...... and malfunctions of anaerobic digesters occasionally experienced, leading to sub-optimal methane production and wastewater treatment. Using a variety of molecular techniques, we are able to determine which microorganisms are active, where they are active, and when they are active, but we still need to determine...

  13. Stable groundwater quality in deep aquifers of Southern Bangladesh: The case against sustainable abstraction

    International Nuclear Information System (INIS)

    In forty six wells > 150 m deep, from across the arsenic-polluted area of south-central Bangladesh, groundwater composition remained unchanged between 1998 and 2011. No evidence of deteriorating water quality was found in terms of arsenic, iron, manganese, boron, barium or salinity over this period of 13 years. These deep tubewells have achieved operating lives of more than 20 years with minimal institutional support. These findings confirm that tubewells tapping the deep aquifers in the Bengal Basin provide a safe, popular, and economic, means of arsenic mitigation and are likely to do so for decades to come. Nevertheless, concerns remain about the sustainability of a resource that could serve as a source of As-safe water to mitigate As-pollution in shallower aquifers in an area where tens of millions of people are exposed to dangerous levels of arsenic in well water. The conjunction of the stable composition in deep groundwater and the severe adverse health effects of arsenic in shallow groundwater lead us to challenge the notion that strong sustainability principles should be applied to the management of deep aquifer abstraction in Bangladesh is, the notion that the deep groundwater resource should be preserved for future generations by protecting it from adverse impacts, probably of a minor nature, that could occur after a long time and might not happen at all. Instead, we advocate an ethical approach to development of the deep aquifer, based on adaptive abstraction management, which allows possibly unsustainable exploitation now in order to alleviate crippling disease and death from arsenic today while also benefiting future generations by improving the health, education and economy of living children. - Highlights: • Tens of millions of people in Bangladesh are affected by arsenic pollution of groundwater. • Deep wells in potentially non-renewable aquifers are the dominant form of mitigation. • Water quality in these aquifers has remained stable for 13

  14. A Transient Groundwater Flow Model for Evaluating River-Aquifer Exchange

    Science.gov (United States)

    Zanini, A.; Chelli, A.; Pecoraro, R.; Celico, F.

    2014-12-01

    The study area is an industrial site (in the North of Italy) contaminated through heavy metal and chlorinated hydrocarbons. The site presents an area of about 5 km2 and a complex geology. During 2013 and 2014 the hydrogeological conceptual model was reviewed and the result was a main unconfined aquifer that presents an impervious bottom at about 30 m below ground. A small portion of the aquifer is split by a non-continuous aquitard. Below the impervious bottom, there are confined aquifers that are not polluted. The boundary conditions of the aquifer are constant head upstream (obtained from a regional piezometry) and constant head downstream that represents a lake stage. Moreover a river inside the study area, that could feed or dry the aquifer depending on its stage, manages the groundwater head levels. The study area presents more than 100 pumping wells that have the objective of realizing a hydraulic barrier and to prevent the flow of pollutants downstream. The area is monitored with about 120 monitoring wells, which are used, through a periodic sampling and monitoring, to control the pollution and to estimate the flow direction. During the last year a numerical flow model has been developed by means of MODFLOW 2000 (Harbaugh, 2000) with the aim at becoming a management tool of the hydraulic barrier. The calibration procedure, initially, was performed in steady state condition using the PEST procedure (Doherty, 2007). The goal was to reproduce the monthly observations at the monitoring wells varying the hydraulic conductivity of the main aquifer and of the aquitard. The second step of the calibration was the extension of the calibration to transient data. The period from September 1st 2013 to June 31st 2014 was reproduced. In order to avoid problem with the starting conditions only the observations collected in 2014 were used to estimate the aquifer parameters. The period September 1st 2013 to December 31st was used as warm up in order to obtain reliable

  15. Economics of Managed Aquifer Recharge

    Directory of Open Access Journals (Sweden)

    Robert G. Maliva

    2014-05-01

    Full Text Available Managed aquifer recharge (MAR technologies can provide a variety of water resources management benefits by increasing the volume of stored water and improving water quality through natural aquifer treatment processes. Implementation of MAR is often hampered by the absence of a clear economic case for the investment to construct and operate the systems. Economic feasibility can be evaluated using cost benefit analysis (CBA, with the challenge of monetizing benefits. The value of water stored or treated by MAR systems can be evaluated by direct and indirect measures of willingness to pay including market price, alternative cost, value marginal product, damage cost avoided, and contingent value methods. CBAs need to incorporate potential risks and uncertainties, such as failure to meet performance objectives. MAR projects involving high value uses, such as potable supply, tend to be economically feasible provided that local hydrogeologic conditions are favorable. They need to have low construction and operational costs for lesser value uses, such as some irrigation. Such systems should therefore be financed by project beneficiaries, but dichotomies may exist between beneficiaries and payers. Hence, MAR projects in developing countries may be economically viable, but external support is often required because of limited local financial resources.

  16. Water Pollution

    Science.gov (United States)

    ... phosphorus make algae grow and can turn water green. Bacteria, often from sewage spills, can pollute fresh or salt water. You can help protect your water supply: Don't pour household products such as cleansers, beauty products, medicines, auto fluids, paint, and lawn care ...

  17. Water Pollution

    Science.gov (United States)

    We all need clean water. People need it to grow crops and to operate factories, and for drinking and recreation. Fish and wildlife depend on ... and phosphorus make algae grow and can turn water green. Bacteria, often from sewage spills, can pollute ...

  18. Groundwater Pollution Source Characterization of an Old Landfill

    DEFF Research Database (Denmark)

    Kjeldsen, Peter

    Only a few landfill investigations have focused on both the quantity and the quality of leachate as a source of groundwater pollution. The investigation of Vejen Landfill in Denmark included an introductionary historical survey (old maps, aerial photographs, interviews, etc.), leachate quality...... drainage ditch and a southerly leach to the secondary aquifer were taking place. To evaluate the proportion of leachate discharging to the drainage ditch, piezometers were installed in the shallow leachate-affected aquifer. On the basis of several soundings, the groundwater surface was mapped and the...

  19. Simulation of the transfer of hydrocarbons in unconfined aquifer in tropical zone: the case of benzene

    Science.gov (United States)

    Agnès Kouamé, Amenan; Jaboyedoff, Michel; Derron, Marc-Henri; Kouamé, Kan Jean

    2016-04-01

    Groundwater is the largest global reserves of continental freshwater (Bosca, 2002) and also an important source of drinking water in many parts of the world (Brassington. 2007). However, this resource is today threatened by pollution such as inadequate supply of drinking water services, inaccessibility and / or dilapidated sanitation facilities and excessive use fertilizers, and industrial wastewater and solid waste pesticides (Boubacar, 2010) and the rapid urbanization in great cities (Foster, 2001). Abidjan, the largest city in Côte d'Ivoire is also facing pollution problems such as illegal dumping of waste, waste oil spilled garages, land application of domestic and industrial wastewater, automotive workshops, overexploitation of sand in the Ebrié lagoon, open waste dump of Akouédo and the spill of about 400,000 liters of toxic waste from the ship "Probo Koala" in August 2006. The Abidjan aquifer or the Continental terminal aquifer is the main source of supply drinking water. It is mainly composed of sandy and it is an unconfined aquifer as a whole (Jourda, 1987). According to Gilli and al., (2012), the recharge of unconfined aquifers comes mostly from the infiltration of surface water including rainwater. These waters on their transport in the basement could carry certain pollutants into groundwater. Kouamé (2007) reports a potential groundwater pollution of the "Continental terminal" aquifer in Abidjan. In addition to the cases cited pollution, there has been a proliferation of service stations in the district of Abidjan and this can cause possible pollution. We deemed it necessary to conduct a study on the groundwater pollution of Abidjan by oil in general. We chose benzene to simulate organic pollution in case of accident. To observe the likely evolution of such contaminants in the subsurface, we developed hydrogeological models that couple groundwater flow and benzene transport with FEFLOW software in steady and transient states. The models are composed

  20. Integrating indicator-based geostatistical estimation and aquifer vulnerability of nitrate-N for establishing groundwater protection zones

    Science.gov (United States)

    Jang, Cheng-Shin; Chen, Shih-Kai

    2015-04-01

    Groundwater nitrate-N contamination occurs frequently in agricultural regions, primarily resulting from surface agricultural activities. The focus of this study is to establish groundwater protection zones based on indicator-based geostatistical estimation and aquifer vulnerability of nitrate-N in the Choushui River alluvial fan in Taiwan. The groundwater protection zones are determined by univariate indicator kriging (IK) estimation, aquifer vulnerability assessment using logistic regression (LR), and integration of the IK estimation and aquifer vulnerability using simple IK with local prior means (sIKlpm). First, according to the statistical significance of source, transport, and attenuation factors dominating the occurrence of nitrate-N pollution, a LR model was adopted to evaluate aquifer vulnerability and to characterize occurrence probability of nitrate-N exceeding 0.5 mg/L. Moreover, the probabilities estimated using LR were regarded as local prior means. IK was then used to estimate the actual extent of nitrate-N pollution. The integration of the IK estimation and aquifer vulnerability was obtained using sIKlpm. Finally, groundwater protection zones were probabilistically determined using the three aforementioned methods, and the estimated accuracy of the delineated groundwater protection zones was gauged using a cross-validation procedure based on observed nitrate-N data. The results reveal that the integration of the IK estimation and aquifer vulnerability using sIKlpm is more robust than univariate IK estimation and aquifer vulnerability assessment using LR for establishing groundwater protection zones. Rigorous management practices for fertilizer use should be implemented in orchards situated in the determined groundwater protection zones.

  1. Intrinsic and specific vulnerability of groundwater in central Spain: the risk of nitrate pollution

    Science.gov (United States)

    Martínez-Bastida, Juan J.; Arauzo, Mercedes; Valladolid, Maria

    2010-05-01

    The intrinsic vulnerability of groundwater in the Comunidad de Madrid (central Spain) was evaluated using the DRASTIC and GOD indexes. Groundwater vulnerability to nitrate pollution was also assessed using the composite DRASTIC (CD) and nitrate vulnerability (NV) indexes. The utility of these methods was tested by analyzing the spatial distribution of nitrate concentrations in the different aquifers located in the study area: the Tertiary Detrital Aquifer, the Moor Limestone Aquifer, the Cretaceous Limestone Aquifer and the Quaternary Aquifer. Vulnerability maps based on these four indexes showed very similar results, identifying the Quaternary Aquifer and the lower sub-unit of the Moor Limestone Aquifer as deposits subjected to a high risk of nitrate pollution due to intensive agriculture. As far as the spatial distribution of groundwater nitrate concentrations is concerned, the NV index showed the greatest statistical significance ( p < 0.01). This new type of multiplicative model offers greater accuracy in estimations of specific vulnerability with respect to the real impact of each type of land use. The results of this study provide a basis on which to guide the designation of nitrate vulnerable zones in the Comunidad de Madrid, in line with European Union Directive 91/676/EEC.

  2. Survival of bacterial indicators and the functional diversity of native microbial communities in the Floridan aquifer system, south Florida

    Science.gov (United States)

    Lisle, John T.

    2014-01-01

    model than when exposed to groundwater from the APPZ (range: 0.540–0.684 h-1). The inactivation rates for the first phase of the models for P. aeruginosa were not significantly different between the UFA (range: 0.144–0.770 h-1) and APPZ (range: 0.159–0.772 h-1) aquifer zones. The inactivation rates for the second phase of the model for this P. aeruginosa were also similar between UFA (range: 0.003–0.008 h-1) and APPZ (0.004–0.005 h-1) zones, although significantly slower than the model’s first phase rates for this bacterial species. Geochemical data were used to determine which dissimilatory biogeochemical reactions were most likely to occur under the native conditions in the UFA and APPZ zones using thermodynamics principles to calculate free energy yields and other cell-related energetics data. The biogeochemical processes of acetotrophic and hydrogenotrophic sulfate reduction, methanogenesis and anaerobic oxidation of methane dominated in all six groundwater sites. A high throughput DNA microarray sequencing technology was used to characterize the diversity in the native aquifer bacterial communities (bacteria and archaea) and assign putative physiological capabilities to the members of those communities. The bacterial communities in both zones of the aquifer were shown to possess the capabilities for primary and secondary fermentation, acetogenesis, methanogenesis, anaerobic methane oxidation, syntrophy with methanogens, ammonification, and sulfate reduction. The data from this study provide the first determination of bacterial indicator survival during exposure to native geochemical conditions of the Floridan aquifer in south Florida. Additionally, the energetics and functional bacterial diversity characterizations are the first descriptions of native bacterial communities in this region of the Floridan aquifer and reveal how these communities persist under such extreme conditions. Collectively, these types of data can be used to develop and refine

  3. Benzene dispersion and natural attenuation in an alluvial aquifer with strong interactions with surface water

    Science.gov (United States)

    Batlle-Aguilar, Jordi; Brouyère, Serge; Dassargues, Alain; Morasch, Barbara; Hunkeler, Daniel; Höhener, Patrick; Diels, Ludo; Vanbroekhoven, Karolien; Seuntjens, Piet; Halen, Henri

    2009-05-01

    SummaryField and laboratory investigations have been conducted at a former coke plant, in order to assess pollutant attenuation in a contaminated alluvial aquifer, discharging to an adjacent river. Various organic (BTEX, PAHs, mineral oils) and inorganic (As, Zn, Cd) compounds were found in the aquifer in concentrations exceeding regulatory values. Due to redox conditions of the aquifer, heavy metals were almost immobile, thus not posing a major risk of dispersion off-site the brownfield. Field and laboratory investigations demonstrated that benzene, among organic pollutants, presented the major worry for off-site dispersion, mainly due to its mobility and high concentration, i.e. up to 750 mg L -1 in the source zone. However, benzene could never be detected near the river which is about 160 m downgradient the main source. Redox conditions together with benzene concentrations determined in the aquifer have suggested that degradation mainly occurred within 100 m distance from the contaminant source under anoxic conditions, and most probably with sulphate as main oxidant. A numerical groundwater flow and transport model, calibrated under transient conditions, was used to simulate benzene attenuation in the alluvial aquifer towards the Meuse River. The mean benzene degradation rate used in the model was quantified in situ along the groundwater flow path using compound-specific carbon isotope analysis (CSIA). The results of the solute transport simulations confirmed that benzene concentrations decreased almost five orders of magnitude 70 m downgradient the source. Simulated concentrations have been found to be below the detection limit in the zone adjacent to the river and consistent with the absence of benzene in downgradient piezometers located close to the river reported in groundwater sampling campaigns. In a transient model scenario including groundwater-surface water dynamics, benzene concentrations were observed to be inversely correlated to the river water

  4. Groundwater flow system and Nitrogen cycle in volcanic aquifer of pyroclastic flow uplands, Japan

    Science.gov (United States)

    Mikami, K.; Shimada, J.; Tashiro, S.; Niimi, H.

    2007-12-01

    Study area is well-known agriculture area in Southern Kyushu, Japan and highly depends on groundwater resources for their everyday use. Local unconfined groundwater aquifer is widely polluted by Nitrate-Nitrogen originated from agriculture and cattle farming. It will become serious problem if this unconfined Nitrate pollution enlarges into the confined aquifer system which is used for local city water source. The detailed three dimensional groundwater flow system study has been done by using existing wells in the basin to understand the three dimensional distribution pattern of Nitrate-Nitrogen in the aquifer. However, the detailed groundwater age analysis by using Tritium for unconfined and confined groundwater has not been succeeded because of present low atmosphere tritium concentration. Thus we applied to challenge the CFCs dating method. Although the CFCs method has been widely used for dating the young groundwater instead of tritium in many countries, in Japan CFCs has been used only by Oceanographic study and has not been used in the field of Hydrology. The history and fate of Nitrate contamination have been shown in multidisciplinary local transect studies in areas with agricultural sources (Bohlke and Denver 1995). However, identification of Nitrogen sources can be difficult in larger regional studies because of co-occurrence of multiple anthropogenic Nitrogen sources and uncertainty in Nitrogen transformation pathways. Thus, the characterization of N geochemistry remains challenging, particularly in aquifer-scale assessments (Stephen 2006). In this study, the evidence of the shallow groundwater flowing towards deep aquifer was verified by the groundwater dating and the detailed Nitrogen reduction process was confirmed along the groundwater flow.

  5. Visualization of residual organic liquid trapped in aquifers

    International Nuclear Information System (INIS)

    Organic liquids that are essentially immiscible with water migrate through the subsurface under the influence of capillary, viscous, and buoyancy forces. These liquids originate from the improper disposal of hazardous wastes, and the spills and leaks of petroleum hydrocarbons and solvents. The flow visualization experiments described in this study examined the migration of organic liquids through the saturated zone of aquifers, with a primary focus on the behavior of the residual organic liquid saturation, referring to that portion of the organic liquid that is trapped by capillary forces. Etched glass micromodels were used to visually observe dynamic multiphase displacement processes in pore networks. The resulting fluid distributions were photographed. Pore and blob casts were produced by a technique in which an organic liquid was solidified in place within a sand column at the conclusion of a displacement. The columns were sectioned and examined under optical and scanning electron microscopes. Photomicrographs of these sections show the morphology of the organic phase and its location within the sand matrix. The photographs from both experimental techniques reveal that in the saturated zone large amounts of residual organic liquid are trapped as isolated blobs of microscopic size. The size, shape, and spatial distribution of these blobs of residual organic liquid affect the dissolution of organic liquid into the water phase and the biotransformation of organic components. These processes are of concern for the prediction of pollution migration and the design of aquifer remediation schemes

  6. Remediation of Trichloroethylene and Monochlorobenzene-Contaminated Aquifers Using the ORC-GAC-Fe0-CaCO3 System:Volatilization, Precipitation,and Porosity Losses

    Institute of Scientific and Technical Information of China (English)

    LIN Qi; V. PLAGENTZ; D. SCHAFER; A. DAHMKE

    2007-01-01

    The objectives of this study were to illustrate the reaction processes, to identify and quantify the precipitates formed, and to estimate the porosity losses in order to eliminate drawbacks during remediating monochlorobenzene (MCB) and trichloroethylene (TCE)-contaminated aquifers using the ORC-GAC-Fe0-CaCO3 system. The system consisted of four columns (112 cm long and 10 cm in diameter) with oxygen-releasing compound (ORC), granular activated carbon (GAC),zero-valent iron (Fe0), and calcite used sequentially as the reactive media. The concentrations of MCB in the GAC column effluent and TCE in the Fe0 column effluent were below the detection limit. However, the concentrations of MCB and TCE in the final calcite column exceeded the maximum contaminant level (MCL) under the Safe Drinking Water Act of the US Environmental Protection Agency (US EPA) that protects human health and environment. These results suggested that partitioning of MCB and TCE into the gas phase could occur, and also that transportation of volatile organic pollutants in the gas phase was important. Three main precipitates formed in the ORC-GAC-Fe0-CaCO3 system:CaCO3 in the ORC column along with Fe(OH)2 and FeCO3 in the Fe0 column. The total porosity losses caused by mineral precipitation corresponded to about 0.24% porosity in the ORC column, and 1% in the Fe0 column. The most important cause of porosity losses was anaerobic corrosion of iron. The porosity losses caused by gas because of the production and entrapment of oxygen in the ORC column and hydrogen in the Fe0 column should not be ignored. Volatilization, precipitation and porosity losses were considered to be the main drawbacks of the ORC-GAC-Fe0-CaCO3 system in remediating the MCB and TCE-contaminated aquifers. Thus, measurements such as using a suitable oxygen-releasing compound, weakening the increase in pH using a buffer material such as soil, stimulating biodegradation rates and minimizing the plugging caused by the relatively high

  7. Cultivable Anaerobic Microbiota of Infected Root Canals

    Directory of Open Access Journals (Sweden)

    Takuichi Sato

    2012-01-01

    Full Text Available Objective. Periapical periodontitis is an infectious and inflammatory disease of the periapical tissues caused by oral bacteria invading the root canal. In the present study, profiling of the microbiota in infected root canals was performed using anaerobic culture and molecular biological techniques for bacterial identification. Methods. Informed consent was obtained from all subjects (age ranges, 34–71 years. Nine infected root canals with periapical lesions from 7 subjects were included. Samples from infected root canals were collected, followed by anaerobic culture on CDC blood agar plates. After 7 days, colony forming units (CFU were counted and isolated bacteria were identified by 16S rRNA gene sequencing. Results. The mean bacterial count (CFU in root canals was (0.5±1.1×106 (range 8.0×101–3.1×106, and anaerobic bacteria were predominant (89.8%. The predominant isolates were Olsenella (25.4%, Mogibacterium (17.7%, Pseudoramibacter (17.7%, Propionibacterium (11.9% and Parvimonas (5.9%. Conclusion. The combination of anaerobic culture and molecular biological techniques makes it possible to analyze rapidly the microbiota in infected root canals. The overwhelming majority of the isolates from infected root canals were found to be anaerobic bacteria, suggesting that the environment in root canals is anaerobic and therefore support the growth of anaerobes.

  8. Predicting the denitrification capacity of sandy aquifers from shorter-term incubation experiments and sediment properties

    Directory of Open Access Journals (Sweden)

    W. Eschenbach

    2013-02-01

    Full Text Available Knowledge about the spatial variability of denitrification rates and the lifetime of denitrification in nitrate-contaminated aquifers is crucial to predict the development of groundwater quality. Therefore, regression models were derived to estimate the measured cumulative denitrification of aquifer sediments after one year of incubation from initial denitrification rates and several sediment parameters, namely total sulphur, total organic carbon, extractable sulphate, extractable dissolved organic carbon, hot water soluble organic carbon and potassium permanganate labile organic carbon.

    For this purpose, we incubated aquifer material from two sandy Pleistocene aquifers in Northern Germany under anaerobic conditions in the laboratory using the 15N tracer technique. The measured amount of denitrification ranged from 0.19 to 56.2 mg N kg−1 yr−1. The laboratory incubations exhibited high differences between non-sulphidic and sulphidic aquifer material in both aquifers with respect to all investigated sediment parameters. Denitrification rates and the estimated lifetime of denitrification were higher in the sulphidic samples. For these samples, the cumulative denitrification measured during one year of incubation (Dcum(365 exhibited distinct linear regressions with the stock of reduced compounds in the investigated aquifer samples. Dcum(365 was predictable from sediment variables within a range of uncertainty of 0.5 to 2 (calculated Dcum(365/measured Dcum(365 for aquifer material with a Dcum(365 > 20 mg N kg−1 yr−1. Predictions were poor for samples with lower Dcum(365, such as samples from the NO3 bearing groundwater zone, which includes the non-sulphidic samples, from the upper part of both aquifers where denitrification is not sufficient to

  9. Effective distribution of emulsified edible oil for enhanced anaerobic bioremediation

    Science.gov (United States)

    Borden, Robert C.

    2007-10-01

    Recent laboratory and field studies have shown that injection of emulsified edible oils can provide an effective, low-cost alternative for stimulating anaerobic biodegradation processes. A pilot-scale permeable reactive bio-barrier (PRBB) was installed at a perchlorate and chlorinated solvent impacted site by injecting 380 L of commercially available emulsion (EOS ®) containing emulsified soybean oil, food-grade surfactants, lactate, and yeast extract through ten direct push injection wells over a two day period. Soil cores collected six months after emulsion injection indicate the oil was distributed up to 5 m downgradient of the injection wells. A previously developed emulsion transport model was used to simulate emulsion transport and retention using independently estimated model parameters. While there was considerable variability in the soil sampling results, the model simulations generally agreed with the observed oil distribution at the field site. Model sensitivity analyses indicate that increasing the injection flow rate or diluting the oil with more water will have little effect on final oil distribution in the aquifer. The only effective approach for enhancing the spread of emulsified oil away from the injection well appears to be injecting a greater mass of oil.

  10. Groundwater exploration and exploitation of the Caracas aquifer, Venezuela

    International Nuclear Information System (INIS)

    The Caracas valley is bordered by crystalline rocks, and the valley fill (Caracas aquifer) comprises the weathering products of these rocks, such as fluvial gravels and sands, in addition to clay and silts from former lakes. All these sediments intercalate in a very irregular manner. Groundwater recharge below Caracas is pronounced because of significant exfiltrations of drinking water out of the distribution net. This creates an important dilution potential for pollutants and stimulates the development of microbiological activity. These, however, cannot favour groundwater withdrawal from the active recharge zone, because protection measures will be difficult to realize. It is therefore recommended that groundwater exploitation be restricted to the passive recharge zone by wells with filter screens more than 100 m below the surface

  11. First results of the isotopic study (18O, 2H, 3H) of the Douala Quaternary aquifer (Cameroon)

    International Nuclear Information System (INIS)

    The Quaternary sandy aquifer of the Douala sedimentary basin generally shows homogeneous isotopic abundances (18O, 2H, 3H) of water sampled at different depths.The large majority of these samples indicated a direct and fast infiltration of precipitation, without significant evaporation. This homogeneity can moreover be accentuated under the pumping effects, connecting various levels of the multilayer aquifer. These results show that pollution from the surface can quickly reach the deeper layers, and seems to corroborate those obtained on the basis of field measurements and chemical analyses. (author)

  12. First results of the isotopic study (18O, 2H, 3H) of the Douala Quaternary aquifer (Cameroon)

    International Nuclear Information System (INIS)

    The quaternary sandy aquifer of the Douala sedimentary basin generally indicates homogeneity in isotopic abundance (18O, 2H, 3H) of water sampled at different depths. The large majority of these samples indicated a direct and fast infiltration of the precipitations, without significant evaporation. This homogeneity can moreover be accentuated under the pumping effects, putting in communication various levels of the multilayer aquifer. These results show that pollution from the surface can quickly reach the deeper layers, and seems to corroborate those obtained on the basis of field measurements and chemical analyses. (author)

  13. Anaerobic xylose fermentation by Spathaspora passalidarum

    DEFF Research Database (Denmark)

    Hou, Xiaoru

    2012-01-01

    reductase (XR) and NAD+-dependent xylitol dehydrogenase (XDH). Thus, the capacity of S. passalidarum to utilize xylose under anaerobic conditions is possibly due to the balance between the cofactor’s supply and demand through this XR–XDH pathway. Only few XRs with NADH preference have been reported so far....... 2-Deoxy glucose completely inhibited the conversion of xylose by S. passalidarum under anaerobic conditions, but only partially did that under aerobic conditions. Thus, xylose uptake by S. passalidarum may be carried out by different xylose transport systems under anaerobic and aerobic conditions...

  14. Potential for anaerobic conversion of xenobiotics

    DEFF Research Database (Denmark)

    Mogensen, Anders Skibsted; Dolfing, J.; Haagensen, Frank;

    2003-01-01

    This review covers the latest research on the anaerobic biodegradation of aromatic xenobiotic compounds, with emphasis on surfactants, polycyclic aromatic hydrocarbons, phthalate esters, polychlorinated biphenyls, halogenated phenols, and pesticides. The versatility of anaerobic reactor systems...... regarding the treatment of xenobiotics is shown with the focus on the UASB reactor, but the applicability of other reactor designs for treatment of hazardous waste is also included. Bioaugmentation has proved to be a viable technique to enhance a specific activity in anaerobic reactors and recent research...... on reactor and in situ bioaugmentation is reported....

  15. Recharge from rectangular areas to finite aquifers

    Science.gov (United States)

    Rao, N. H.; Sarma, P. B. S.

    1981-10-01

    A generalized analytical solution is derived for the growth of groundwater mound in finite aquifers bounded by open water bodies, in response to recharge from rectangular areas. Finite Fourier transforms are used to solve the linearized differential equation of groundwater flow. Unlike earlier solutions, the method presented here does not require the use of tables for evaluation of complicated functions. The solution is evaluated by comparison with existing numerical and analytical results. In stream-aquifer systems similar to those described above, application of the proposed solution is more realistic than using solutions available for infinite aquifers.

  16. Hazardous Air Pollutants

    Science.gov (United States)

    ... Facebook Twitter Google+ Pinterest Contact Us Hazardous Air Pollutants Hazardous air pollutants are those known to cause ... protect against adverse environmental effects. About Hazardous Air Pollutants What are hazardous air pollutants? Health and Environmental ...

  17. The Internet Pollution

    Institute of Scientific and Technical Information of China (English)

    唐宁宁

    2005-01-01

    Life today has brought new problems. As we know, there are fourterrible pollutions in the world: water pollution, noise pollution, air pol-lution and rubbish pollution. Water pollution kills our fish and pollutesour drinking water. Noise pollution makes us talk louder and become angry more easily. Air pollution makes us hold our breath longer and be badto all living things in the world. Rubbish pollution often makes our livingenvironment much dirtier. But I think that the Internet pollution is anothernew pollution in the world.

  18. Anaerobic respirometry as a tool for substrate characterisation aiming at modelling of manures anaerobic modelling of manures anaerobic digestion

    OpenAIRE

    Girault, R.; Sadowski, A.G.; Béline, F.

    2010-01-01

    Modelling of anaerobic digestion is more and more used as a tool for process optimization or interpreting observed phenomena within research projects. The most used model is the Anaerobic Digestion Model n°1 (ADM1) but some other models are also available (either simpler or more complex). Whatever the model, one of the major key issue is the fractionation and characterisation of the influent. For substrates like activated sludge from wastewater treatment plants, detailed influent characterisa...

  19. Anaerobe Tolerance to Oxygen and the Potentials of Anaerobic and Aerobic Cocultures for Wastewater Treatment

    OpenAIRE

    1997-01-01

    The anaerobic treatment processes are considered to be well-established methods for the elimination of easily biodegradable organic matter from wastewaters. Some difficulties concerning certain wastewaters are related to the possible presence of dissolved oxygen. The common belief is that anaerobes are oxygen intolerant. Therefore, the common practice is to use sequencing anaerobic and aerobic steps in separate tanks. Enhanced treatment by polishing off the residual biodegradable oxygen deman...

  20. Models for wellhead protection in regional unconfined aquifers and stratified aquifers

    OpenAIRE

    Feseker, T.; Krijgsman, B; J. P. Lobo Ferreira

    2004-01-01

    Mathematical concepts are used for the development of wellhead protection and zoning methodologies, based on analytical solutions and on groundwater flow and particle tracking finite differences. Wellhead protection limits are a function of the local geology, of the aquifer parameters and the regional hydraulic characteristics of the aquifer, and of the extraction rates or of the productivity of the aquifer. In the vertical dimension the analysis was performed using an axisymmetric flow model...

  1. Influence of aquifer heterogeneity on the design and modelling of Aquifer Thermal Energy Storage (ATES) systems

    OpenAIRE

    Bridger, David W.

    2006-01-01

    A modelling study was carried out to evaluate the influence of aquifer heterogeneity, as represented by geologic layering, on heat transport and storage in aquifer thermal energy storage (ATES) systems. An existing ATES system installed within a heterogeneous aquifer system in Agassiz, British Columbia, Canada was used as a case study. Two 3D heat transport models of the study site were developed and calibrated using the heat transport code FEFLOW, including: a "simple" model domain with unif...

  2. Radial Dupuit interface flow to assess the aquifer storage and recovery potential of saltwater aquifers

    OpenAIRE

    Bakker, M.

    2009-01-01

    A new accurate numerical solution is presented for aquifer storage and recovery (ASR) systems in coastal aquifers; flow is approximated as radial Dupuit interface flow. The radial velocities of points on the interface are a function of time, the vertical coordinate, and the dimensionless parameter D (the discharge of the well divided by the product of the hydraulic conductivity, the square of the aquifer thickness, and the dimensionless density difference). The recovery efficiency of an ASR s...

  3. Assessment of groundwater vulnerability and risk to pollution in Kathmandu Valley, Nepal.

    Science.gov (United States)

    Shrestha, Sangam; Semkuyu, Dickson John; Pandey, Vishnu P

    2016-06-15

    Groundwater vulnerability and risk assessment is a useful tool for groundwater pollution prevention and control. In this study, GIS based DRASTIC model have been used to assess intrinsic aquifer vulnerability to pollution whereas Groundwater Risk Assessment Model (GRAM) was used to assess the risk to groundwater pollution in the groundwater basin of Kathmandu Valley. Seven hydrogeological factors were used in DRASTIC model to produce DRASTIC Index (DI) map which represent intrinsic groundwater vulnerability to pollution of the area. The seven hydrogeological factors used were depth to water, net recharge, aquifer media, soil media, topography, impact of vadose zone, and hydraulic conductivity of aquifer. GIS based GRAM was used to produce likelihood of release of hazards, likelihood of detection of hazards, consequence of hazards and residual risk of groundwater contamination in terms of nitrate in the groundwater basin. It was found that more than 50% of the groundwater basin area in the valley is susceptible to groundwater pollution and these areas are mostly in Northern groundwater district Low and very low vulnerable areas account for only 13% and are located in Central and Southern groundwater districts. However after taking into account the barriers to groundwater pollution and likelihood of hazards release and detection, it was observed that most areas i.e. about 87% of the groundwater basin are at moderate residual risk to groundwater pollution. The resultant groundwater vulnerability and risk map provides a basis for policy makers and planner's ability to use information effectively for decision making at protecting the groundwater from pollutants. PMID:26971207

  4. Anaerobic digestion of organic solid waste for energy production

    Energy Technology Data Exchange (ETDEWEB)

    Nayono, Satoto Endar

    2010-07-01

    The total amount of municipal solid waste is continuously rising. Consequently, there are millions of tons of solid waste being produced every year which have to be safely disposed without any negative impact to the environment. On the other hand, as one of the driving forces for economic and social development the availability of energy in sufficient and sustainable amount has been becoming world's main interest. However, depending on the way the energy is produced, distributed and used, it may contribute to environmental problems such as water, land and air pollution or even global climate change. Anaerobic digestion as a pre-treatment prior to landfill disposal or composting offers several advantages, such as minimization of masses and volume, inactivation of biological and biochemical processes in order to avoid landfill-gas and odor emissions, reduction of landfill settlements and energy production in the form of methane. Therefore, anaerobic digestion of bio-degradable solid wastes can be considered an alternative option to improve the environment condition caused by organic solid waste and at the same time taking an advantage as an environmentally-friendly resource of energy. This study was carried out in order to evaluate the performance of anaerobic reactors treating OFMSW (organic fraction of municipal solid waste), especially in terms of its energy recovery, either by investigating the maximum organic loading rate or by co-digestion with other types of wastes for energy recovery. In order to reach the research purpose, several experimental activities such as characteristics examination of different organic solid wastes, which are potential substrates for anaerobic digestion and performance evaluation of the anaerobic reactors treating OFMSW were initiated. The Except for source-sorted OFMSW (later called biowaste), the substrates examined in this study were pressing leachate from an OFMSW composting plant (press water), source-sorted foodwaste

  5. The vulnerability of the Dupi Tila Aquifer, Dhaka, Bangladesh

    OpenAIRE

    Hasan, M. K.

    1999-01-01

    The Dupi Tila aquifer in Bangladesh is of national importance, providing over 95% of the water supply for the capital city, Dhaka. The demand for water is rising inexorably. There is concern about the sustainability of the aquifer and its vulnerability to contamination. In Dhaka, the Dupi Tila aquifer is confined by the Madhupur Clay. Natural recharge to the aquifer is by vertical leakage through the Madhupur Clay. However, large-scale development of the aquifer since 1971 has ...

  6. Characterizing the Anaerobic Response of Chlamydomonas reinhardtii by Quantitative Proteomics

    OpenAIRE

    Terashima, Mia; Specht, Michael; Naumann, Bianca; Hippler, Michael

    2010-01-01

    The versatile metabolism of the green alga Chlamydomonas reinhardtii is reflected in its complex response to anaerobic conditions. The anaerobic response is also remarkable in the context of renewable energy because C. reinhardtii is able to produce hydrogen under anaerobic conditions. To identify proteins involved during anaerobic acclimation as well as to localize proteins and pathways to the powerhouses of the cell, chloroplasts and mitochondria from C. reinhardtii in aerobic and anaerobic...

  7. Solute changes during aquifer storage recovery testing in a limestone/clastic aquifer

    Science.gov (United States)

    Mirecki, J.E.; Campbell, B.G.; Conlon, K.J.; Petkewich, M.D.

    1998-01-01

    Aquifer storage recovery (ASR) was tested in the Santee Limestone/Black Mingo Aquifer near Charleston, South Carolina, to assess the feasibility for subsurface storage of treated drinking water. Water quality data obtained during two representative ASR tests were interpreted to show three things: (1) recovery efficiency of ASR in this geological setting; (2) possible changes in physical characteristics of the aquifer during ASR testing; and (3) water quality changes and potability of recovered water during short (one- and six-day) storage durations in the predominantly carbonate aquifer. Recovery efficiency for both ASR tests reported here was 54%. Successive ASR tests increased aquifer permeability of the Santee Limestone/Black Mingo Aquifer. It is likely that aquifer permeability increased during short storage periods due to dissolution of carbonate minerals and amorphous silica in aquifer material by treated drinking water. Dissolution resulted in an estimated 0.3% increase in pore volume of the permeable zones. Ground water composition generally evolved from a sodium-calcium bicarbonate water to a sodium chloride water during storage and recovery. After short duration, stored water can exceed the U.S. Environmental Protection Agency maximum contaminant level (MCL) for chloride (250 mg/L). However, sulfate, fluoride, and trihalomethane concentrations remained below MCLs during storage and recovery.Aquifer storage recovery (ASR) was tested in the Santee Limestone/Black Mingo Aquifer near Charleston, South Carolina, to assess the feasibility for subsurface storage of treated drinking water. Water quality data obtained during two representative ASR tests were interpreted to show three things: (1) recovery efficiency of ASR in this geological setting; (2) possible changes in physical characteristics of the aquifer during ASR testing; and (3) water quality changes and potability of recovered water during short (one- and six-day) storage durations in the predominantly

  8. Water Pollution. Project COMPSEP.

    Science.gov (United States)

    Lantz, H. B., Jr.

    This is an introductory program on water pollution. Examined are the cause and effect relationships of water pollution, sources of water pollution, and possible alternatives to effect solutions from our water pollution problems. Included is background information on water pollution, a glossary of pollution terminology, a script for a slide script…

  9. Anaerobic degradation of linear alkylbenzene sulfonate

    DEFF Research Database (Denmark)

    Mogensen, Anders Skibsted; Haagensen, Frank; Ahring, Birgitte Kiær

    2003-01-01

    increases during anaerobic stabilization due to transformation of easily degradable organic matter. Hence, LAS is regarded as resistant to biodegradation under anaerobic conditions. We present data from a lab-scale semi-continuously stirred tank reactor (CSTR) spiked with linear dodecylbenzene sulfonate (C......% of the added C-12 LAS was bioavailable and 20% was biotransformed when spiking with 100 mg/L of C-12 LAS and a TS concentration of 14.2 mg/L. Enhanced bioavailability of C-12 LAS was obtained in an upflow anaerobic sludge blanket (UASB) reactor inoculated with granular sludge and sewage sludge. Biodegradation......Linear alkylbenzene sulfonate (LAS) found in wastewater is removed in the wastewater treatment facilities by sorption and aerobic biodegradation. The anaerobic digestion of sewage sludge has not been shown to contribute to the removal. The concentration of LAS based on dry matter typically...

  10. Volcanic and sedimentary-rock aquifers

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set represents the extent of the Volcanic and sedimentary-rock aquifers in the states of Montana, Wyoming, Idaho, Nevada, California, Oregon, and...

  11. North Atlantic Coastal Plain aquifer system

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set represents the extent of the North Atlantic Coastal Plain aquifer system in North Carolina, Virginia, Maryland, Deleware, and New Jersey.

  12. As contamination in Mercedes (Uruguay) aquifer groundwater

    International Nuclear Information System (INIS)

    The study presents data on the concentration of arsenic in groundwater aquifer Mercedes, where the highest concentration area is located in New Palmira.A geological formation decryption of the Mercedes for the Upper Cretaceous is made.

  13. Hydrogeologic characterization of devonian aquifers in Uruguay

    International Nuclear Information System (INIS)

    This article carried out the assistance research project implementation in devonian sedimentary units as a potentials aquifers and their best use to school supplying and rural population in central area of Uruguay.

  14. Aquifer vulnerability for Colorado and New Mexico

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The U.S. Geological Survey Data Series provides raster data representing an estimate of aquifer vulnerability calculated for each 30-meter raster cell. Depth to...

  15. Investigating sources and pathways of perfluoroalkyl acids (PFAAs) in aquifers in Tokyo using multiple tracers

    Energy Technology Data Exchange (ETDEWEB)

    Kuroda, Keisuke, E-mail: keisukekr@gmail.com [Department of Urban Engineering, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo, Tokyo 113-8656 (Japan); Murakami, Michio [Institute of Industrial Science, The University of Tokyo, 4-6-1 Komaba, Meguro, Tokyo 153-8505 (Japan); Oguma, Kumiko [Department of Urban Engineering, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo, Tokyo 113-8656 (Japan); Takada, Hideshige [Laboratory of Organic Geochemistry (LOG), Institute of Symbiotic Science and Technology, Tokyo University of Agriculture and Technology, Fuchu, Tokyo 183-8509 (Japan); Takizawa, Satoshi [Department of Urban Engineering, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo, Tokyo 113-8656 (Japan)

    2014-08-01

    We employed a multi-tracer approach to investigate sources and pathways of perfluoroalkyl acids (PFAAs) in urban groundwater, based on 53 groundwater samples taken from confined aquifers and unconfined aquifers in Tokyo. While the median concentrations of groundwater PFAAs were several ng/L, the maximum concentrations of perfluorooctane sulfonate (PFOS, 990 ng/L), perfluorooctanoate (PFOA, 1800 ng/L) and perfluorononanoate (PFNA, 620 ng/L) in groundwater were several times higher than those of wastewater and street runoff reported in the literature. PFAAs were more frequently detected than sewage tracers (carbamazepine and crotamiton), presumably owing to the higher persistence of PFAAs, the multiple sources of PFAAs beyond sewage (e.g., surface runoff, point sources) and the formation of PFAAs from their precursors. Use of multiple methods of source apportionment including principal component analysis–multiple linear regression (PCA–MLR) and perfluoroalkyl carboxylic acid ratio analysis highlighted sewage and point sources as the primary sources of PFAAs in the most severely polluted groundwater samples, with street runoff being a minor source (44.6% sewage, 45.7% point sources and 9.7% street runoff, by PCA–MLR). Tritium analysis indicated that, while young groundwater (recharged during or after the 1970s, when PFAAs were already in commercial use) in shallow aquifers (< 50 m depth) was naturally highly vulnerable to PFAA pollution, PFAAs were also found in old groundwater (recharged before the 1950s, when PFAAs were not in use) in deep aquifers (50–500 m depth). This study demonstrated the utility of multiple uses of tracers (pharmaceuticals and personal care products; PPCPs, tritium) and source apportionment methods in investigating sources and pathways of PFAAs in multiple aquifer systems. - Highlights: • Aquifers in Tokyo had high levels of perfluoroalkyl acids (up to 1800 ng/L). • PFAAs were more frequently detected than sewage

  16. Investigating sources and pathways of perfluoroalkyl acids (PFAAs) in aquifers in Tokyo using multiple tracers

    International Nuclear Information System (INIS)

    We employed a multi-tracer approach to investigate sources and pathways of perfluoroalkyl acids (PFAAs) in urban groundwater, based on 53 groundwater samples taken from confined aquifers and unconfined aquifers in Tokyo. While the median concentrations of groundwater PFAAs were several ng/L, the maximum concentrations of perfluorooctane sulfonate (PFOS, 990 ng/L), perfluorooctanoate (PFOA, 1800 ng/L) and perfluorononanoate (PFNA, 620 ng/L) in groundwater were several times higher than those of wastewater and street runoff reported in the literature. PFAAs were more frequently detected than sewage tracers (carbamazepine and crotamiton), presumably owing to the higher persistence of PFAAs, the multiple sources of PFAAs beyond sewage (e.g., surface runoff, point sources) and the formation of PFAAs from their precursors. Use of multiple methods of source apportionment including principal component analysis–multiple linear regression (PCA–MLR) and perfluoroalkyl carboxylic acid ratio analysis highlighted sewage and point sources as the primary sources of PFAAs in the most severely polluted groundwater samples, with street runoff being a minor source (44.6% sewage, 45.7% point sources and 9.7% street runoff, by PCA–MLR). Tritium analysis indicated that, while young groundwater (recharged during or after the 1970s, when PFAAs were already in commercial use) in shallow aquifers (< 50 m depth) was naturally highly vulnerable to PFAA pollution, PFAAs were also found in old groundwater (recharged before the 1950s, when PFAAs were not in use) in deep aquifers (50–500 m depth). This study demonstrated the utility of multiple uses of tracers (pharmaceuticals and personal care products; PPCPs, tritium) and source apportionment methods in investigating sources and pathways of PFAAs in multiple aquifer systems. - Highlights: • Aquifers in Tokyo had high levels of perfluoroalkyl acids (up to 1800 ng/L). • PFAAs were more frequently detected than sewage

  17. Performance analysis of upflow anaerobic sludge blanket reactors in the treatment of swine wastewater

    Directory of Open Access Journals (Sweden)

    Luiz A. V. Sarmento

    2007-07-01

    Full Text Available The adoption of confined systems for swine production have been increased the use of water in these installations and, consequently, an each time greater production of wastewater. Diagnostics have been showed a high level of water pollution due the waste material release on lands without criterions and in waters without previous treatment. The utilization of anaerobic process to reduce the liquid residues pollutant power has been detaching because beyond reducing the environmental pollution they allow to recover the energetic potential as fertilizer and biogas. In this work the performance of two real scale upflow anaerobic sludge blanket reactors treating swine wastewater were evaluated through operational system analysis, physical-chemical parameters of pollution and biogas production measurement. The results permitted to verify upflow rate speeds above of the value for which these reactors were designed and hydraulic residence times under of the design value. These factors affected negatively the treatment and had reflected on the law removal of the physical-chemical parameters and biogas production. The maximum removal efficiencies reached for TSS, BOD and COD were 72,5%, 34,7% and 40,0%, respectively. The mean rate of biogas liberation was 0,011 m-³ m-².h-1.

  18. Anaerobic membrane bioreactor under extreme conditions (poster)

    OpenAIRE

    Munoz Sierra, J.D.; De Kreuk, M.K.; Spanjers, H.; van Lier, J B

    2013-01-01

    Membrane bioreactors ensure biomass retention by the application of micro or ultrafiltration processes. This allows operation at high sludge concentrations. Previous studies have shown that anaerobic membrane bioreactors is an efficient way to retain specialist microorganisms for treating wastewaters from different industries such as coke, textile, food, and chemical. However, few research has been found into the use of membrane bioreactors for anaerobic treatment of wastewater under extreme ...

  19. Anaerobic Biodegradability of Agricultural Renewable Fibers

    OpenAIRE

    Shi, Bo; Lortscher, Peter; Palfery, Doris

    2013-01-01

    Natural fiber-based paper and paperboard products are likely disposed of in municipal wastewater, composting, or landfill after an intended usage. However, there are few studies reporting anaerobic sludge digestion and biodegradability of agricultural fibers although the soiled sanitary products, containing agricultural fibers, are increasingly disposed of in municipal wastewater or conventional landfill treatment systems, in which one or more unit operations are anaerobic digestion. We condu...

  20. Psychrophilic anaerobic treatment of low strength wastewaters.

    OpenAIRE

    Rebac, S.

    1998-01-01

    The main objective of this thesis was to design a high-rate anaerobic system for the treatment low strength wastewaters under psychrophilic conditions.Psychrophilic (3 to 20 °C) anaerobic treatment of low strength synthetic and malting wastewater was investigated using a single and two stage expanded granular sludge bed (EGSB) reactor system. The chemical oxygen demand (COD) removal efficiencies found in the experiments with synthetic wastewater exceeded 90 % in the single stage reactor at im...

  1. Anaerober Abbau von Kresolen und Monohydroxybenzoaten

    OpenAIRE

    Müller, Jochen A.

    2000-01-01

    All aromatic compounds are potential substrates for microorganisms. Hence, microorganisms play an eminent role in the global carbon cycle. The present work describes the anaerobic degradation of cresols and toluene, both bulk chemicals of the petroleum industry, and the anaerobic degradation of 3-hydroxybenzoate, a model compound for degradation of lignin-monomers. Degradation pathways for these aromatic substrates are postulated on the basis of in vitro measurements of key enzymes in various...

  2. Anaerobic digester for treatment of organic waste

    Energy Technology Data Exchange (ETDEWEB)

    Sharma, V. K. [Indian Insitute of Technology, Delhi (India)]|[ENEA, Centro Ricerche Trisaia, Matera (Italy); Fortuna, F.; Canditelli, M.; Cornacchia, G. [ENEA, Centro Ricerche Trisaia, Matera (Italy). Dipt. Ambiente; Farina, R. [ENEA, centro Ricerche ``Ezio Clementel``, Bologna (Italy). Dipt. Ambiente

    1997-09-01

    The essential features of both new and more efficient reactor systems and their appropriate applications for various organic waste management situations, description of several working plants are discussed in the present communication. It is hoped that significant development reported here would be useful in opening a new vista to the application of anaerobic biotechnology for the waste treatment of both low/high organic strength and specialized treatment for toxic substances, using appropriate anaerobic methods.

  3. Anaerobic Digestion of Paper Mill Wastewater

    OpenAIRE

    Shreeshivadasan Chelliapan; Siti Baizura Mahat; Md. Fadjil Md. Din; A. Yuzir; Othman, N.

    2012-01-01

    In general, paper mill wastewater contains complex organic substances which could not be treated completely using conventional treatment processes, e.g. aerobic processes. As a result, anaerobic technology is a promising alternative for paper mill wastewater treatment due to its ability to degrade hard organic compounds. In the present study, treatment of paper mill wastewater using a stage anaerobic reactor was investigated. The more specific objectives of this study were to confirm whether ...

  4. Sleep Deprivation Induced Anxiety and Anaerobic Performance

    OpenAIRE

    Selma Arzu Vardar; Levent Öztürk; Cem Kurt; Erdogan Bulut; Necdet Sut; Erdal Vardar

    2007-01-01

    The aim of this study was to investigate the effects of sleep deprivation induced anxiety on anaerobic performance. Thirteen volunteer male physical education students completed the Turkish version of State Anxiety Inventory and performed Wingate anaerobic test for three times: (1) following a full-night of habitual sleep (baseline measurements), (2) following 30 hours of sleep deprivation, and (3) following partial-night sleep deprivation. Baseline measurements were performed the day before ...

  5. EFFECT OF MUSIC ON ANAEROBIC EXERCISE PERFORMANCE

    OpenAIRE

    Atan, T.

    2013-01-01

    For years, mostly the effects of music on cardiorespiratory exercise performance have been studied, but a few studies have examined the effect of music on anaerobic exercise. The purpose of this study was to assess the effect of listening to music and its rhythm on anaerobic exercise: on power output, heart rate and the concentration of blood lactate. 28 male subjects were required to visit the laboratory on 6 occasions, each separated by 48 hours. Firstly, each subject performed the Running-...

  6. Comparative Studies of Alternative Anaerobic Digestion Technologies

    OpenAIRE

    Inman, David C.

    2004-01-01

    Washington D.C. Water and Sewage Authority is planning to construct a new anaerobic digestion facility at its Blue Plains WWTP by 2008. The research conducted in this study is to aid the designers of this facility by evaluating alternative digestion technologies. Alternative anaerobic digestion technologies include thermophilic, acid/gas phased, and temperature phased digestion. In order to evaluate the relative merits of each, a year long study evaluated the performance of bench scale dig...

  7. Isotope hydrology: applications to mining, urban and pollution problems in Southern Africa

    International Nuclear Information System (INIS)

    Environmental isotope techniques have found fruitful and growing applications in the field of geohydrology. Over the past few decades numerous studies involving isotope hydrology have been conducted in south and southern Africa. This paper concentrates on a three of these studies which concern: the geohydrology of and recharge to the aquifer providing a major ground water supply to a diamond mine in an arid environment; proving incipient pollution and pollutant source apportionment to a karstified dolomite aquifer in a mixed residential, industrial and agricultural area; pinpointing mains leaks and establishing ground water behaviour in urban environments. (author)

  8. Benchmarking worldwide CO₂ saline aquifer injections

    OpenAIRE

    Hosa, Aleksandra; Esentia, Mina; Stewart, Jamie; Haszeldine, Stuart

    2010-01-01

    Carbon Capture, Transport and Storage is a very active field of research, especially for the past decade. From the UK perspective, a commercially crucial aspect is the saline aquifer research, since there are predicted to be vast storage capacities in the sedimentary formations of the North Sea. The following report reviews the ongoing work on practical injections of CO2 as research tests for storage projects and specifically focuses on industrial sized saline aquifer injections.

  9. Improving Aquifer Thermal Energy Storage Efficiency

    OpenAIRE

    S. Kranz; G. Blöcher; Ali Saadat

    2015-01-01

    Aquifer thermal energy storage systems play an important role for the future energy supply systems. Such systems can decouple energy availability (e.g. fluctuating renewable energy, waste heat) and energy supply in times of demand. In order to fully contribute to the sustainability of energy supply, the essential requirements of energy storages are high energy efficiency, high reliability, cost effectiveness, as well as operational flexibility. Aquifer Thermal Energy Storage Systems (ATES) me...

  10. Estimating aquifer thickness using multiple pumping tests

    OpenAIRE

    Maréchal, Jean-Christophe; Vouillamoz, Jean-Michel; Mohan Kumar, M.S.; Dewandel, Benoit

    2010-01-01

    A method to estimate aquifer thickness and hydraulic conductivity has been developed, consisting of multiple pumping tests. The method requires short-duration pumping cycles on an unconfined aquifer with significant seasonal water-table fluctuations. The interpretation of several pumping tests at a site in India under various initial conditions provides information on the change in hydrodynamic parameters in relation to the initial water-table level. The transmissivity linearly decreases comp...

  11. Annual and nycthemeral studies of the survival and circulation of indicator bacteria in a schist aquifer.

    Science.gov (United States)

    Grisey, Elise; Belle, Emilien; Mudry, Jacques; Aleya, Lotfi

    2011-07-01

    Escherichia coli and Enterococci are widely used as indicators of faecal contamination of groundwater while total coliforms, which are of environmental but also of faecal origin, are indicators of the overall quality of the water. The survival of bacteria in groundwater is dependent on many factors including temperature, competition with indigenous bacteria and entrapment in aquifer material. Previous studies showed two sources of faecal contamination of a schist aquifer: infiltration into the ground from nearby septic tank effluents and seepage of landfill leachate. Water samples for bacterial analysis were collected from a piezometer on a monthly basis (15 months) and every six hours over two non-consecutive days. The intermittent sampling showed relatively stable concentrations of bacteria over time after the removal of stagnant water. Therefore, a continuous bacterial contamination without significant daily variation exists. The ratio of E. coli densities to total coliforms densities (EC/TC) allowed differentiation between the sources of faecal pollution in groundwater by comparing the populations of faecal bacteria with those of environmental bacteria. Enumeration indicated that the densities of bacteria were much higher in this schist aquifer than those in alluvial aquifers contaminated by a septic tank reported in the literature. PMID:21882565

  12. Interlaboratory study of a method for determining nonvolatile organic carbon in aquifer materials

    Science.gov (United States)

    Caughey, M.E.; Barcelona, M.J.; Powell, R.M.; Cahill, R.A.; Gron, C.; Lawrenz, D.; Meschi, P.L.

    1995-01-01

    The organic carbon fraction in aquifer materials exerts a major influence on the subsurface mobilities of organic and organic-associated contaminants. The spatial distribution of total organic carbon (TOC) in aquifer materials must be determined before the transport of hydrophobic organic pollutants in aquifers can be modeled accurately. Previous interlaboratory studies showed that it is difficult to measure TOC concentrations 1%. We have tested a new analytical method designed to improve the accuracy and precision of nonvolatile TOC quantitation in geologic materials that also contain carbonate minerals. Four authentic aquifer materials and one NIST standard reference material were selected as test materials for a blind collaborative study. Nonvolatile TOC in these materials ranged from 0.05 to 1.4%, while TIC ranged from 0.46 to 12.6%. Sample replicates were digested with sulfurous acid, dried at 40??C, and then combusted at 950??C using LECO or UIC instruments. For the three test materials that contained >2% TIC, incomplete acidification resulted in a systematic positive bias of TOC values reported by five of the six laboratories that used the test method. Participants did not have enough time to become proficient with the new method before they analyzed the test materials. A seventh laboratory successfully used an alternative method that analyzed separate liquid and solid fractions of the acidified sample residues. ?? 1995 Springer-Verlag.

  13. The influence of bedrock hydrogeology on catchment-scale nitrate fate and transport in fractured aquifers.

    Science.gov (United States)

    Orr, Alison; Nitsche, Janka; Archbold, Marie; Deakin, Jenny; Ofterdinger, Ulrich; Flynn, Raymond

    2016-11-01

    Characterising catchment scale biogeochemical processes controlling nitrate fate in groundwater constitutes a fundamental consideration when applying programmes of measures to reduce risks posed by diffuse agricultural pollutants to water quality. Combining hydrochemical analyses with nitrate isotopic data and physical hydrogeological measurements permitted characterisation of biogeochemical processes influencing nitrogen fate and transport in the groundwater in two fractured bedrock aquifers with contrasting hydrogeology but comparable nutrient loads. Hydrochemical and isotopic analyses of groundwater samples collected from moderately fractured, diffusely karstified limestone indicated nitrification controlled dissolved nitrogen fate and delivery to aquatic receptors. By contrast nitrate concentrations in groundwater were considerably lower in a low transmissivity highly lithified sandstone and pyrite-bearing shale unit with patchy subsoil cover. Geophysical and hydrochemical investigations showed shallower intervals contained hydraulically active fractures where denitrification was reflected through lower nitrogen levels and an isotopic enrichment ratio of 1.7 between δ(15)N and δ(18)O. Study findings highlight the influence of bedrock hydrogeological conditions on aqueous nitrogen mobility. Investigation results demonstrate that bedrock conditions need to be considered when implementing catchment management plans to reduce the impact of agricultural practices on the quality of groundwater and baseflow in receiving rivers. Nitrate isotopic signatures in the groundwater of a freely draining catchment underlain by a karstified aquifer and a poorly draining aquifer with a low transmissivity aquifer. PMID:27432726

  14. SLEEP DEPRIVATION INDUCED ANXIETY AND ANAEROBIC PERFORMANCE

    Directory of Open Access Journals (Sweden)

    Selma Arzu Vardar

    2007-12-01

    Full Text Available The aim of this study was to investigate the effects of sleep deprivation induced anxiety on anaerobic performance. Thirteen volunteer male physical education students completed the Turkish version of State Anxiety Inventory and performed Wingate anaerobic test for three times: (1 following a full-night of habitual sleep (baseline measurements, (2 following 30 hours of sleep deprivation, and (3 following partial-night sleep deprivation. Baseline measurements were performed the day before total sleep deprivation. Measurements following partial sleep deprivation were made 2 weeks later than total sleep deprivation measurements. State anxiety was measured prior to each Wingate test. The mean state anxiety following total sleep deprivation was higher than the baseline measurement (44.9 ± 12.9 vs. 27.6 ± 4.2, respectively, p = 0.02 whereas anaerobic performance parameters remained unchanged. Neither anaerobic parameters nor state anxiety levels were affected by one night partial sleep deprivation. Our results suggest that 30 hours continuous wakefulness may increase anxiety level without impairing anaerobic performance, whereas one night of partial sleep deprivation was ineffective on both state anxiety and anaerobic performance

  15. Predicting long-term denitrification capacity of sandy aquifers from incubation experiments and sediment properties

    Directory of Open Access Journals (Sweden)

    W. Eschenbach

    2012-07-01

    Full Text Available Knowledge about the spatial variability of denitrification rates and the lifetime of denitrification in nitrate-contaminated aquifers is crucial to predict the development of groundwater quality. Therefore, regression models were derived to estimate the measured denitrification capacity of incubated aquifer sediments from initial denitrification rates and several sediment parameters, namely total sulphur, total organic carbon, extractable sulfate, extractable dissolved organic carbon, hot water soluble organic carbon and potassium permanganate labile organic carbon.

    For this purpose, we incubated aquifer material from two sandy Pleistocene aquifers in Northern Germany under anaerobic conditions in the laboratory using the 15N tracer technique. The measured long-term denitrification capacities ranged from 0.18 to 56.2 mg N kg−1 yr−1. The laboratory incubations exhibited high differences between non-sulphidic and sulphidic aquifer material in both aquifers with respect to all investigated sediment parameters. Denitrification rates and the estimated lifetime of denitrification were higher in the sulphidic samples. Denitrification capacity measured during one year of incubation (Dcap was predictable from sediment variables within a range of uncertainty of 0.5 to 2 (calculated Dcap/measured Dcap for aquifer material with a Dcap > 20 mg N kg−1 yr−1. Predictions were poor for samples with lower Dcap like samples from the NO3-bearing groundwater zone, which includes the non-sulphidic samples, from the upper part of both aquifers where Dcap is not sufficient to protect groundwater from anthropogenic NO3 input. Calculation of Dcap from initial denitrification rates was only successful for samples from the NO

  16. The Leachate Release and Microstructure of the Sewage Sludge under the Anaerobic Fermentation

    Directory of Open Access Journals (Sweden)

    Yiqie Dong

    2015-01-01

    Full Text Available Pollutant release, pore structure, and thermal effect of sewage sludge during anaerobic fermentation were investigated. Results showed that the pH value firstly declined and then increased during anaerobic fermentation. The BOD5 and organics of sewage sludge declined, and the BOD5 of samples which was originally neutral declined as much as 53.6%. The micropore of samples was relatively developed. The biggest adsorption amount was 69.2 cm3/g. The average pore size was enlarged about 16.0–19.8% under anaerobic fermentation. There existed endothermic valley during heating procedure of 0–200∘C because of the dehydration, and the mass loss was 60.9–72.5%. The endothermic valley of the sample fluctuated at the 14th day in the anaerobic fermentation. During the heating procedure of 200–600∘C, there existed exothermal peaks because of the oxidation and burning of the organics. The curve of sample which was originally neutral had comparatively large endothermic valley and exothermal peak.

  17. Biotechnological Utilization with a Focus on Anaerobic Treatment of Cheese Whey: Current Status and Prospects

    Directory of Open Access Journals (Sweden)

    Aspasia A. Chatzipaschali

    2012-09-01

    Full Text Available Cheese whey utilization is of major concern nowadays. Its high organic matter content, in combination with the high volumes produced and limited treatment options make cheese whey a serious environmental problem. However, the potential production of biogas (methane, hydrogen or other marketable products with a simultaneous high COD reduction through appropriate treatment proves that cheese whey must be considered as an energy resource rather than a pollutant. The presence of biodegradable components in the cheese whey coupled with the advantages of anaerobic digestion processes over other treatment methods makes anaerobic digestion an attractive and suitable treatment option. This paper intends to review the most representative applications of anaerobic treatment of cheese whey currently being exploited and under research. Moreover, an effort has been made to categorize the common characteristics of the various research efforts and find a comparative basis, as far as their results are concerned. In addition, a number of dairy industries already using such anaerobic digestion systems are presented.

  18. The nitrogen cycle in highly urbanized tropical regions and the effect of river-aquifer interactions: The case of Jakarta and the Ciliwung River

    Science.gov (United States)

    Costa, Diogo; Burlando, Paolo; Priadi, Cindy; Shie-Yui, Liong

    2016-09-01

    Groundwater is extensively used in Jakarta to compensate for the limited public water supply network. Recent observations show a rise in nitrate (NO3-) levels in the shallow aquifer, thus pointing at a potential risk for public health. The detected levels are still below national and international regulatory limits for drinking water but a strategy is necessary to contain the growing problem. We combine 3 years of available data in the Ciliwung River, the major river flowing through Jakarta, with a distributed river-aquifer interaction model to characterise the impact of urbanisation on the N-cycle of both surface and groundwater systems. Results show that the N-cycle in the river-aquifer system is heterogeneous in space, seasonal dependent (i.e. flow regime) and strongly affected by urban pollution. Results suggest also that although the main sources of N related groundwater pollution are leaking septic tanks, the aquifer interaction with the Ciliwung River may locally have a strong effect on the concentrations. In the general context of pollution control in urban areas, this study demonstrates how advanced process-based models can be efficiently used in combination with field measurements to bring new insights into complex contamination problems. These are essential for more effective and integrated management of water quality in river-aquifer systems.

  19. Caractérisation expérimentale et modélisation des effets des pratiques culturales sur la pollution nitrique d'un aquifère en zone de grande culture Application au site de Bruyères (02)

    OpenAIRE

    Beaudoin, Nicolas

    2006-01-01

    Les eaux superficielles et souterraines doivent recouvrer une bonne qualité chimique et biologique avant 2015, d'après la Directive Cadre Européenne. Les Bonnes Pratiques Agricoles (BPA) établissent un compromis entre les risques de pollution et de perte de revenu. Le résultat minimal escompté est de respecter la norme de potabilité de 50 mgNO3.L-1 dans les eaux de captage et d'éviter les transferts de pollution de l'hydrosphère vers l'atmosphère. Cependant leur mise en oeuvre ne garantit pas...

  20. [Anaerobic membrane bioreactors for treating agricultural and food processing wastewater at high strength].

    Science.gov (United States)

    Wei, Yuan-Song; Yu, Da-Wei; Cao, Lei

    2014-04-01

    As the second largest amounts of COD discharged in 41 kinds of industrial wastewater, it is of great urgency for the agricultural and food processing industry to control water pollution and reduce pollutants. Generally the agricultural and food processing industrial wastewater with high strength COD of 8 000-30 000 mg x L(-1), is mainly treated with anaerobic and aerobic processes in series, but which exists some issues of long process, difficult maintenance and high operational costs. Through coupling anaerobic digestion and membrane separation together, anaerobic membrane bioreactor (AnMBR) has typical advantages of high COD removal efficiency (92%-99%), high COD organic loading rate [2.3-19.8 kg x (m3 x d)(-1)], little sludge discharged (SRT > 40 d) and low cost (HRT of 8-12 h). According to COD composition of high strength industrial wastewater, rate-limiting step of methanation could be either hydrolysis and acidification or methanogenesis. Compared with aerobic membrane bioreactor (MBR), membrane fouling of AnMBR is more complicated in characterization and more difficult in control. Measures for membrane fouling control of AnMBR are almost the same as those of MBR, including cross flow, air sparging and membrane relaxation. For meeting discharging standard of food processing wastewater with high strength, AnMBR is a promising technology with very short process, by enhancing COD removal efficiency, controlling membrane fouling and improving energy recovery. PMID:24946624

  1. Anaerobic microbial processes in a petroleum plume in fractured rock, northern Canada

    International Nuclear Information System (INIS)

    Fuel plumes are among the most common groundwater pollution problems at polluted sites throughout Canada, including the Canadian Shield region. However, the microbial processes that occur under cold climate conditions in fuel-contaminated groundwater are poorly understood. This study focused on evidence for anaerobic microbial processes in fuel plumes in groundwater at a Canadian Shield site in the Northwest Territories, within a zone mapped as having extensive discontinuous permafrost. In particular, the study examined redox-sensitive species in the groundwater, specifically iron, manganese, sulfate and nitrate. The data reported in the paper were based on a sampling program conducted in September 2007. The data showed strong evidence that anaerobic microorganisms are active in fuel-contaminated groundwater in fractured rock at the study site. The microbial processes include the reduction of electron acceptors, notably sulfate, ferric iron, manganese and possibly nitrate. It is possible that such anaerobic processes play an important role in the biodegradation of dissolved petroleum hydrocarbons in the groundwater at this site. However, it was concluded that additional analysis is needed in order to infer rates of these processes in the groundwater and to understand the relationship of these processes to degradation of the fuel plume. 14 refs., 8 figs.

  2. Anaerobic digestion of cellulosic wastes

    International Nuclear Information System (INIS)

    Anaerobic digestion is a potentially attractive technology for volume reduction of low-level radioactive cellulosic wastes. A substantial fraction of the waste is converted to off-gas and a relatively small volume of biologically stabilized sludge is produced. Process development work has been completed using a 75-L digester to verify rates and conversions obtained at the bench scale. Start-up and operating procedures have been developed, and effluent was generated for characterization and disposal studies. Three runs using batch and fed-batch conditions were made lasting 36, 90, and 423 d. Solids solubilization rates and gas production rates averaged approximately 1.8 g cellulose per L of reactor per d and 1.2 L of off-gas per L reactor per d. Greater than 80% destruction of the volatile suspended solids was obtained. A simple dynamic process model was constructed to aid in process design and for use in process monitoring and control of a large-scale digester

  3. Anaerobic digestion of cellulosic wastes

    International Nuclear Information System (INIS)

    Anaerobic digestion is a potentially attractive technology for volume reduction of cellulosic wastes. A substantial fraction of the waste is converted to off-gas and a relatively small volume of biologically stabilized sludge is produced. Process development work is underway using a 75-L digester to verify rates and conversions obtained at the bench scale, to develop start-up and operating procedures, and to generate effluent for characterization and disposal studies. Three runs using batch and batch-fed conditions have been made lasting 36, 90, and over 200 days. Solids solubilization and gas production rates and total solids destruction have met or exceeded the target values of 0.6 g cellulose per L of reactor per day, 0.5 L off-gas per L of reactor per day, and 80% destruction of solids, respectively. Successful start-up procedures have been developed, and preliminary effluent characterization and disposal studies have been done. A simple dynamic process model has been constructed to aid in further process development and for use in process monitoring and control of a large-scale digester. 7 references, 5 figures, 1 table

  4. Anaerobic Nitrogen Fixers on Mars

    Science.gov (United States)

    Lewis, B. G.

    2000-07-01

    The conversion of atmospheric nitrogen gas to the protein of living systems is an amazing process of nature. The first step in the process is biological nitrogen fixation, the transformation of N2 to NH3. The phenomenon is crucial for feeding the billions of our species on Earth. On Mars, the same process may allow us to discover how life can adapt to a hostile environment, and render it habitable. Hostile environments also exist on Earth. For example, nothing grows in coal refuse piles due to the oxidation of pyrite and marcasite to sulfuric acid. Yet, when the acidity is neutralized, alfalfa and soybean plants develop root nodules typical of symbiotic nitrogen fixation with Rhizobium species possibly living in the pyritic material. When split open, these nodules exhibited the pinkish color of leghemoglobin, a protein in the nodule protecting the active nitrogen-fixing enzyme nitrogenase against the toxic effects of oxygen. Although we have not yet obtained direct evidence of nitrogenase activity in these nodules (reduction of acetylene to ethylene, for example), these findings suggested the possibility that nitrogen fixation was taking place in this hostile, non-soil material. This immediately raises the possibility that freeliving anaerobic bacteria which fix atmospheric nitrogen on Earth, could do the same on Mars.

  5. A Simplified Methodology For Risk Assessment of The Oolitic Limestone Aquifer, West of Alexandria Coastal Zone

    International Nuclear Information System (INIS)

    Groundwater risk analysis helps to assess the effects of contaminants reach to specific position in groundwater system after introduction at some location above the uppermost aquifer. This provides a basis for initiating protective and mitigation measures for important groundwater resources. An attempt has been made in the present study to assess the risk of diffuse groundwater pollution at the north western coast of Alexandria against landfill waste disposal as well as agricultural pollutants leachates which are the main land use in the studied area. A simplified weighing/ rating approach have been functioned for this purpose, Slovene methodology, which is relevant for fissured carbonate aquifers that characterize the studied area. This method is based on an origin-pathway-target model, which applies for both resource and source protection. Conservative values for the intrinsic geological, hydrogeological, geo morphological and climatological parameters have been reviewed and determined for assessment of the source and resource vulnerability, hazards and risk (lithology, texture and structure of soil zone, lithology and thickness of the unsaturated zone and aquifer conditions, morphological features, slope and vegetation cover, average annual stormy days, travel time and karst network , the fertilizers and pesticide used for agriculture, the volume of unlined waste disposal site). The methodology applied in the present study emphasizes how the physical properties of the hydrological system can be integrated in an index that reflects the level of risk of a diffuse pollution to groundwater. This aligns with the prospective of site safety evaluation around risky installations such as a nuclear power plants or waste disposal facilities where assurance should be done that the risk to the public and environment is acceptably low. According to the functioned methodology, the fissured limestone under study is low vulnerable and highly protectable against surface diffuse

  6. Indoor Air Pollution (Environmental Health Student Portal)

    Science.gov (United States)

    ... Students to Environmental Health Information Menu Home Air Pollution Air Pollution Home Indoor Air Pollution Outdoor Air Pollution ... Pollution Indoor Air Pollution Print this Page Air Pollution Air Pollution Home Indoor Air Pollution Outdoor Air Pollution ...

  7. Processes affecting groundwater quality in arid zones: The case of the Bou-Areg coastal aquifer (North Morocco)

    International Nuclear Information System (INIS)

    Highlights: • Investigation on the main sources of salinization in the Bou-Areg aquifer. • Salinity derives from dissolution, water–rock interaction and agricultural inputs. • Manure, septic effluents and fertilizers are the main causes of human pollution. • Discharge of polluted waters in the Lagoon of Nador is altering its quality. • Saline water intrusion from the lagoon in the aquifer can be considered negligible. - Abstract: The coastal aquifer of Bou-Areg (Morocco) has been studied to identify the main processes causing groundwater salinization, using a multi tracer (general chemistry and isotopes – δ2H, δ18O, δ13C, δ15NNO3, δ18ONO3) geochemical approach. Groundwater is characterized by the widespread occurrence of brackish waters (TDS < 500 mg L−1) with high cation contents, which are balanced by elevated dissolved NO3- (reaching a maximum of 208 mg L−1) and Cl−. Lagoon samples represent a mixture of fresh water and sea water, showing a Na/Cl ratio in agreement with that of sea water and an excess of Ca. The high Ca values represent the main peculiarity of the groundwater–lagoon water system. Two types of groundwater could be identified: (i) freshwater, separated from the whole system and located at the limit of the irrigated area, characterized by low TDS, depleted isotopic composition and relatively high quality; and (ii) water mainly recharged by mountain runoff, interacting with local recharge and acquiring salinity from different sources, thus creating a complex system of dilute waters. Hydrochemical results confirm that the high salinity of the aquifer is caused by the coexistence of dissolution of evaporate rocks and carbonates from Miocene strata, water–rock interaction, and human impacts due to agricultural return flows. The latter represents the main contribution to groundwater salinization, especially in the central part of the aquifer, as well as one of the main causes of the general increase in NO3- concentrations

  8. Anaerobic digestion and opportunities for international technology transfer

    International Nuclear Information System (INIS)

    Unmanaged pollutants from organic farm, industrial, and municipal wastes degrade in the environment, and methane emitted from their decomposition may contribute to global climate change. Under modern environmental regulations, these wastes are becoming difficult to dispose of using traditional means. One waste management system, anaerobic digestion or AD, not only prevents pollution but can also convert a disposal problem into a new profit center. This report summarizes the current status of AD as a key technology that both reduces waste and recovers a fuel and other valuable co-products, and AD possibilities for the future. Beyond the technology arena, this paper also discusses the efforts of the International Energy Agency (IEA) Bioenergy AD Activity to encourage technology deployment. The Activity aims to provide reliable information on the cost-effectiveness of AD, markets for biogas and the other co-products, advanced technologies for biogas utilization, environmental benefits, and institutional barriers. The Activity's principal objectives are to accelerate exchange of information and practical experience, identify barriers to the deployment of AD technology, encourage the use of AD technology, and, where relevant, assist and encourage national Pilot and Demonstration (P and D) programs. The goal of these objectives is to increase the deployment of AD technologies and to transfer the ''lessons learned'' from past experience. (author)

  9. Aquifer Storage Recovery (ASR) of chlorinated municipal drinking water in a confined aquifer

    Science.gov (United States)

    Izbicki, John A.; Petersen, Christen E.; Glotzbach, Kenneth J.; Metzger, Loren F.; Christensen, Allen H.; Smith, Gregory A.; O'Leary, David R.; Fram, Miranda S.; Joseph, Trevor; Shannon, Heather

    2010-01-01

    About 1.02 x 106 m3 of chlorinated municipal drinking water was injected into a confined aquifer, 94-137 m below Roseville, California, between December 2005 and April 2006. The water was stored in the aquifer for 438 days, and 2.64 x 106 m3 of water were extracted between July 2007 and February 2008. On the basis of Cl data, 35% of the injected water was recovered and 65% of the injected water and associated disinfection by-products (DBPs) remained in the aquifer at the end of extraction. About 46.3 kg of total trihalomethanes (TTHM) entered the aquifer with the injected water and 37.6 kg of TTHM were extracted. As much as 44 kg of TTHMs remained in the aquifer at the end of extraction because of incomplete recovery of injected water and formation of THMs within the aquifer by reactions with freechlorine in the injected water. Well-bore velocity log data collected from the Aquifer Storage Recovery (ASR) well show as much as 60% of the injected water entered the aquifer through a 9 m thick, high-permeability layer within the confined aquifer near the top of the screened interval. Model simulations of ground-water flow near the ASR well indicate that (1) aquifer heterogeneity allowed injected water to move rapidly through the aquifer to nearby monitoring wells, (2) aquifer heterogeneity caused injected water to move further than expected assuming uniform aquifer properties, and (3) physical clogging of high-permeability layers is the probable cause for the observed change in the distribution of borehole flow. Aquifer heterogeneity also enhanced mixing of native anoxic ground water with oxic injected water, promoting removal of THMs primarily through sorption. A 3 to 4-fold reduction in TTHM concentrations was observed in the furthest monitoring well 427 m downgradient from the ASR well, and similar magnitude reductions were observed in depth-dependent water samples collected from the upper part of the screened interval in the ASR well near the end of the extraction

  10. Review of Aquifer Storage and Recovery Performance in the Upper Floridan Aquifer in Southern Florida

    Science.gov (United States)

    Reese, Ronald S.

    2006-01-01

    Introduction: Interest and activity in aquifer storage and recovery (ASR) in southern Florida has increased greatly during the past 10 to 15 years. ASR wells have been drilled to the carbonate Floridan aquifer system at 30 sites in southern Florida, mostly by local municipalities or counties located in coastal areas. The primary storage zone at these sites is contained within the brackish to saline Upper Floridan aquifer of the Floridan aquifer system. The strategy for use of ASR in southern Florida is to store excess freshwater available during the wet season in an aquifer and recover it during the dry season when needed for supplemental water supply. Each ASR cycle is defined by three periods: recharge, storage, and recovery. This fact sheet summarizes some of the findings of a second phase retrospective assessment of existing ASR facilities and sites.

  11. Basement Aquifers : How Useful Are Gravity Data ?

    Science.gov (United States)

    Genthon, P.; Mouhouyouddine, A. H.; Hinderer, J.; Hector, B.; Yameogo, S.

    2014-12-01

    Gravity data with a few microgal precision were proved to be able to constrain the specific yield of various kinds of aquifer in West Africa from annual fluctuations of both the gravimetric and piezometric signals (Pfeffer et al., Geophys. J. Int., 2011; Hector et al., Geophys. J. Int., 2013). However some recent papers reported a disappointing potential of gravity measurements during a pumping experiment in a sandy aquifer (Blainey et al., WRR, 2007; Herckenrath et al., WRR, 2012) and their poor ability in constraining the transmissity and specific yield of the aquifer, which are the parameters to which pumping tests give access. Fresh basement rocks present generally a null porosity and the structure of basement aquifers is given by the weathering profile. In tropical climate, this profile consists of a few tens meter thick saprolite layer, with noticeable porosity but low permeability overlying the weathering front. This weathering front includes in many instances a fractured medium and presents a high permeability with variable porosity. It is hardly sampled in coring experiments. We present some numerical simulation results on the ability of gravity to constrain the transmissivity of this medium. Due to poroelasticity of clay minerals in the saprolite, soil subsidence is expected to occur during pumping with a significant gravity effect. Gravity measurements have therefore to be completed with leveling data at a millimetric precision. We present first the results of numerical modeling of the gravity and subsidence for a theoretical horizontally stratified basement aquifer, and show that gravity and leveling are able to provide independently the poroelasticity coefficient and a single transmissivity coefficient for the bottom of the aquifer, if the properties of the upper saprolites are known. We will discuss then the general case, where the aquifer presents a vertical fracture where the weathering profile thickens.

  12. Multidepth pumping tests in deep aquifers.

    Science.gov (United States)

    Alam, N; Olsthoorn, T N

    2014-09-01

    Multidepth pumping tests (MDPTs), in which different sections of a screen are pumped in sequence, are not being used by hydrogeologists, despite the capability of such tests to resolve uncertainties in the estimation of aquifer characteristics. MDPTs can be used to discern the effects of partial penetration and vertical anisotropy. This article demonstrates the use of MDPTs for a deep and vertically anisotropic aquifer, based on a real and unique series of pumping tests conducted in the Indus Basin. Traditional single-layer methods, which incorporate partial penetration and vertical scaling, were employed to evaluate these tests. However, the drawdowns of the 19 piezometers at different depths for which times series data were available could not be matched, presumably because of the layered structure of the aquifer. Numerical (MODFLOW) and multilayer analytical (Hemker and Maas 1987; Hemker 1999) approaches were used to assess the benefits of using MDPTs in the analysis of deep layered and anisotropic aquifers. The multilayer analytical solution results are consistent with the measured and numerically computed drawdowns. The original step-drawdown data were used to verify the model independently. The results of statistical analyses indicate that the parameters for a three-layer system are uniquely estimated. A sensitivity analysis showed that aquifer depths greater than 900 m do not affect the drawdown. The multilayer analytical solution was implemented in MATLAB and can be found in the online version of this article. This multilayer analytical approach was implemented in MLU by Hemker and Randall (2013) for up to 40 layers. The results of this study will be useful in groundwater management, exploration, and optimal well depth estimation for the Indus Basin aquifer and other vertically heterogeneous aquifers. PMID:24428328

  13. Aquifer recharge with reclaimed water in the Llobregat Delta. Laboratory batch experiments and field test site.

    Science.gov (United States)

    Tobella, J.

    2010-05-01

    Summary Spain, as most other Mediterranean countries, faces near future water shortages, generalized pollution and loss of water dependent ecosystems. Aquifer recharge represents a promising option to become a source for indirect potable reuse purposes but presence of pathogens as well as organic and inorganic pollutants should be avoided. To this end, understanding the processes of biogeochemical degradation occurring within the aquifer during infiltration is capital. A set of laboratory batch experiments has been assembled in order to assess the behaviour of selected pesticides, drugs, estrogens, surfactant degradation products, biocides and phthalates under different redox conditions. Data collected during laboratory experiments and monitoring activities at the Sant Vicenç dels Horts test site will be used to build and calibrate a numerical model (i) of the physical-chemical-biochemical processes occurring in the batches and (ii) of multicomponent reactive transport in the unsaturated/saturated zone at the test site. Keywords Aquifer recharge, batch experiments, emerging micropollutants, infiltration, numerical model, reclaimed water, redox conditions, Soil Aquifer Treatment (SAT). 1. Introduction In Spain, the Llobregat River and aquifers, which supply water to Barcelona, have been overexploited for years and therefore, suffer from serious damages: the river dries up on summer, riparian vegetation has disappeared and seawater has intruded the aquifer. In a global context, solutions to water stress problems are urgently needed yet must be sustainable, economical and safe. Recent developments of analytical techniques detect the presence of the so-called "emerging" organic micropollutants in water and soils. Such compounds may affect living organisms when occurring in the environment at very low concentrations (microg/l or ng/l). In wastewater and drinking water treatment plants, a remarkable removal of these chemicals from water can be obtained only using

  14. Anaerobic digestion of agricultural wastes

    Energy Technology Data Exchange (ETDEWEB)

    Hobson, P.N.

    1984-01-01

    Farm digesters can operate satisfactorily and have a useful role on the farm. Gas production from the farm digester treating animal slurries could be boosted by adding silage liquid, old potatoes, waste cabbages and other crop wastes to the slurry, although the energy economics of maceration have not been calculated. Pollution control and types of digester are discussed. Uses of digested slurry other than for fertilizers are being tested - as protein supplement to farm animal feeds, silage making, hydroponics, fish farming and growing of worms on algae. Overall, digestion could be a contributor to power requirements especially in countries with high all year round crop production.

  15. The effect of outside conditions on anaerobic ammonia oxidation reaction

    Institute of Scientific and Technical Information of China (English)

    YANG Min; WANG Shu-bo

    2016-01-01

    Organic carbon, inorganic carbon, temperature, pH and ORP are all to have a certain influence on the anaerobic ammonia oxidation reaction. We can draw some conclusions on the optimum conditions of anaerobic ammonia oxidation reaction. The optimum temperature of the anaerobic ammonia oxidation reaction is 30-35℃. And the optimum pH of the anaerobic ammonia reaction is 7.5-8.3. The presence of organic matters can affect the anaerobic ammonia reaction, and different organic matters have different influence on it. The concentration of the inorganic carbon also exist great influence on the reaction. High inorganic carbon concentration also can inhibit anaerobic ammonia oxidation reaction.

  16. Metabolic interactions between methanogenic consortia and anaerobic respiring bacteria

    DEFF Research Database (Denmark)

    Stams, A.J.; Oude Elferink, S.J.; Westermann, Peter

    2003-01-01

    Most types of anaerobic respiration are able to outcompete methanogenic consortia for common substrates if the respective electron acceptors are present in sufficient amounts. Furthermore, several products or intermediate compounds formed by anaerobic respiring bacteria are toxic to methanogenic...... consortia. Despite the potentially adverse effects, only few inorganic electron acceptors potentially utilizable for anaerobic respiration have been investigated with respect to negative interactions in anaerobic digesters. In this chapter we review competitive and inhibitory interactions between anaerobic...... respiring populations and methanogenic consortia in bioreactors. Due to the few studies in anaerobic digesters, many of our discussions are based upon studies of defined cultures or natural ecosystems...

  17.  Distribution and composition of microbial populations in landfill leachate contaminated aquifer (Grindsted, Denmark)

    DEFF Research Database (Denmark)

    Ludvigsen, L; Albrechtsen, HJ; Ringelberg, DB;

    1999-01-01

    To investigate whether landfill leachates affected the microbial biomass and/or community composition of the extant microbiota, 37 samples were collected along a 305-m transect of a shallow landfill-leachate polluted aquifer. The samples were analyzed for total numbers of bacteria by use of the...... 5.4 × 104 cells/g dw. Populations of sulfate reducers decreased with an increase in horizontal distance from the landfill ranging from a high of 9.0 × 103 cells/g dw to a low of 6 cells/g dw. Iron, manganese, and nitrate reducers were detected throughout the leachate plume all at maximum cell...... AODC, MPN, PLFA, and ATP analyses in the characterization of the extant microbiota within the Grindsted aquifer revealed that as distance increased from the leachate source, viable biomass decreased and community composition shifted. These results led to the conclusion that the landfill leachate...

  18. Timeline of bio-hydrogen production by anaerobic digestion of biomass

    Directory of Open Access Journals (Sweden)

    Bernadette E. TELEKY

    2015-12-01

    Full Text Available Anaerobic digestion of biomass is a process capable to produce biohydrogen, a clean source of alternative energy. Lignocellulosic biomass from agricultural waste is considered a renewable energy source; therefore its utilization also contributes to the reduction of water, soil and air pollution. The study consists in five consecutive experiments designed to utilize anaerobic bacterial enrichment cultures originating from the Hungarian Lake, Hévíz. Wheat straw was used as complex substrate to produce hydrogen. The timeline evolution of hydrogen production was analyzed and modelled by two functions: Logistic and Boltzmann. The results proved that hydrogen production is significant, with a maximum of 0.24 mlN/ml and the highest hydrogen production occurs between the days 4-10 of the experiment.

  19. Anaerobic biotechnological approaches for production of liquid energy carriers from biomass

    DEFF Research Database (Denmark)

    Karakashev, Dimitar Borisov; Thomsen, Anne Belinda; Angelidaki, Irini

    2007-01-01

    determined by substrates and microbial communities available as well as the operating conditions applied. In this review, we evaluate the recent biotechnological approaches employed in ethanol and ABE fermentation. Practical applicability of different technologies is discussed taking into account the......In recent years, increasing attention has been paid to the use of renewable biomass for energy production. Anaerobic biotechnological approaches for production of liquid energy carriers (ethanol and a mixture of acetone, butanol and ethanol) from biomass can be employed to decrease environmental...... pollution and reduce dependency on fossil fuels. There are two major biological processes that can convert biomass to liquid energy carriers via anaerobic biological breakdown of organic matter: ethanol fermentation and mixed acetone, butanol, ethanol (ABE) fermentation. The specific product formation is...

  20. Analytical study of fatty acids in bioreactor of an anaerobic treatment of distillery effluent

    International Nuclear Information System (INIS)

    An anaerobic digestion in bioreactors, offers a two-fold benefit: pollution potential reduction and biogas production. In this study, fatty acids in an anaerobic reactor are studied. The reactor exhibits a notable variation at different corks (1-6). The concentrations for both acetic acid and propionic acid are at maximum range at cork 2 and 5. For isobutyric acid; it is maximum at 1 and 2 corks. Butyric acid is maximum at 5; isovaleric acid is maximum at cork-2. This shows that cork-2 location has its maximum activity for fatty acids. Being nearest to the agitator this location has maximum agitation and resulted more formation of the fatty acids. This acidic effect will ultimately affect the reactor output for Biogas generation. (author)

  1. Anaerobic biodegradability essays from brewery wastewater using granular and flocculent sludges

    Directory of Open Access Journals (Sweden)

    C J Collazos Chávez

    2010-03-01

    Full Text Available At the beginning of nineties the colombian beer industry begun the application of anaerobic technology for the treatment of their wastewater efluents throught different regions of the country. These treatment plants have not been working appropriately due to different factors, and are creating concern among the industrial sector and the water pollution control agencies. This work constitutes the second phase of a research project designed to establish a selection and improvement criteria of the sludges used in the systems. It also looks to analyze other associated factors such as: waste, characteristics, operation conditions and design parameters. The investigation was conducted in two phases using granular and floculent sludges. This method was used for determining the anaerobic biodegradability of wastewater from two industrial plants.

  2. Mapping global vulnerability index in mining sectors: A case study Moulares-Redayef aquifer system, southwestern Tunisia

    Science.gov (United States)

    Khelif, Nadia; Jmal, Ikram; Bouri, Salem

    2016-09-01

    Contrary to the DRASTIC model grouping together the saturated and unsaturated zones to compute a global intrinsic vulnerability index, the global vulnerability index method incorporates both hydrogeological and hydrochemical data for a comprehensive index mapping for the saturated zones. This concept depends on the behavior and the uses of the groundwater. The main aim of this study is to propose a scientific basis for sustainable land use planning and groundwater management of the Moulares-Reayef aquifer, located in Southwestern Tunisia. The overexploitation of this aquifer causes the threat of groundwater quality by various sources of pollution. The global vulnerability index was applied in the Moulares-Reayef aquifer. The results show that the most favorable zones to pollutant percolation are situated along the wadis (Tabaddit, Zallaz, Berka, …) which are drained by continuous discharges. The global vulnerability values were correlated with nitrates values for validation. It revealed a significant correlation showing that high values of nitrates occurred in highly vulnerable zones with a value of 0.69 for the Pearson coefficient. The global vulnerability evaluation shows that the aquifer is characterized by high vertical vulnerability and high susceptibility.

  3. Nitrate pollution of groundwater by pit latrines in developing countries

    OpenAIRE

    Templeton, Michael R.; Acile S. Hammoud; Adrian P. Butler; Laura Braun; Julie-Anne Foucher; Johanna Grossmann; Moussa Boukari; Serigne Faye; Jean Patrice Jourda

    2015-01-01

    Pit latrines are one of the most common forms of onsite sanitation facilities in many developing countries. These latrines are suitable as a means of isolating human waste, however, conditions within pits often lead to nitrification of the contained waste. In areas with a near-surface aquifer, the potential for nitrate pollution arising from pit latrines cannot be ignored. In this study, site visits were made to three densely populated, peri-urban areas near three West African cities (Dakar, ...

  4. ANAEROBIC BIOLOGICAL TREATMENT OF PRODUCED WATER

    Energy Technology Data Exchange (ETDEWEB)

    John R. Gallagher

    2001-07-31

    During the production of oil and gas, large amounts of water are brought to the surface and must be disposed of in an environmentally sensitive manner. This is an especially difficult problem in offshore production facilities where space is a major constraint. The chief regulatory criterion for produced water is oil and grease. Most facilities have little trouble meeting this criterion using conventional oil-water separation technologies. However, some operations have significant amounts of naphthenic acids in the water that behave as oil and grease but are not well removed by conventional technologies. Aerobic biological treatment of naphthenic acids in simulated-produced water has been demonstrated by others; however, the system was easily overloaded by the large amounts of low-molecular-weight organic acids often found in produced waters. The objective of this research was to determine the ability of an anaerobic biological system to treat these organic acids in a simulated produced water and to examine the potential for biodegradation of the naphthenic acids in the anaerobic environment. A small fixed-film anaerobic biological reactor was constructed and adapted to treat a simulated produced water. The bioreactor was tubular, with a low-density porous glass packing material. The inocula to the reactor was sediment from a produced-water holding pond from a municipal anaerobic digester and two salt-loving methanogenic bacteria. During start-up, the feed to the reactor contained glucose as well as typical produced-water components. When glucose was used, rapid gas production was observed. However, when glucose was eliminated and the major organic component was acetate, little gas was generated. Methane production from acetate may have been inhibited by the high salt concentrations, by sulfide, or because of the lack, despite seeding, of microbes capable of converting acetate to methane. Toluene, a minor component of the produced water (0.1 g/L) was removed in the

  5. ANAEROBIC BIOLOGICAL TREATMENT OF PRODUCED WATER; TOPICAL

    International Nuclear Information System (INIS)

    During the production of oil and gas, large amounts of water are brought to the surface and must be disposed of in an environmentally sensitive manner. This is an especially difficult problem in offshore production facilities where space is a major constraint. The chief regulatory criterion for produced water is oil and grease. Most facilities have little trouble meeting this criterion using conventional oil-water separation technologies. However, some operations have significant amounts of naphthenic acids in the water that behave as oil and grease but are not well removed by conventional technologies. Aerobic biological treatment of naphthenic acids in simulated-produced water has been demonstrated by others; however, the system was easily overloaded by the large amounts of low-molecular-weight organic acids often found in produced waters. The objective of this research was to determine the ability of an anaerobic biological system to treat these organic acids in a simulated produced water and to examine the potential for biodegradation of the naphthenic acids in the anaerobic environment. A small fixed-film anaerobic biological reactor was constructed and adapted to treat a simulated produced water. The bioreactor was tubular, with a low-density porous glass packing material. The inocula to the reactor was sediment from a produced-water holding pond from a municipal anaerobic digester and two salt-loving methanogenic bacteria. During start-up, the feed to the reactor contained glucose as well as typical produced-water components. When glucose was used, rapid gas production was observed. However, when glucose was eliminated and the major organic component was acetate, little gas was generated. Methane production from acetate may have been inhibited by the high salt concentrations, by sulfide, or because of the lack, despite seeding, of microbes capable of converting acetate to methane. Toluene, a minor component of the produced water (0.1 g/L) was removed in the

  6. The hydrogeochemistry of a heavily used aquifer in the Mexican wine-producing Guadalupe Valley, Baja California

    Science.gov (United States)

    Daesslé, L. W.; Mendoza-Espinosa, L. G.; Camacho-Ibar, V. F.; Rozier, W.; Morton, O.; van Dorst, L.; Lugo-Ibarra, K. C.; Quintanilla-Montoya, A. L.; Rodríguez-Pinal, A.

    2006-10-01

    The Guadalupe Valley aquifer is the only water source for one of the most important wine industries in Mexico, and also the main public water supply for the nearby city of Ensenada. This groundwater is monitored for major ion, N-NO3, P-PO4, Fe, As, Se, Mo, Cd, Cu, Pb, Zn and Sb concentrations, as well as TDS, pH, dissolved oxygen and temperature. High concentrations of N-NO3 (26 mg l-1), Se (70 μg l-1), Mo (18 μg l-1) and Cu (4.3 μg l-1) suggest that groundwater is being polluted by the use of fertilizers only in the western section of the aquifer, known as El Porvenir graben. Unlike the sites located near the main recharge area to the East of the aquifer, the water in El Porvenir graben has low tritium concentrations (water residence time. No significant variations in water quality (generally water quality. However, the wells nearest to the main recharge area in the Eastern aquifer show a slight but constant increase in TDS with time, probably as a result of the high (˜200 L S-1) uninterrupted extraction of water at this specific recharge site. Relatively high As concentrations for the aquifer (10.5 μg l-1) are only found near the northern limit of the basin associated with a geological fault.

  7. Preventive measures of water pollution in China; Chugoku ni okeru suishitsu odaku boshi taisaku

    Energy Technology Data Exchange (ETDEWEB)

    Qian, Y.; Huang, X.

    1996-01-10

    This paper describes the progress and the major results of research and development on technologies and measures to prevent water pollution in China. Tests and researches have been performed on an upward anaerobic sludge blanket (UASB), a vertical baffled anaerobic sludge blanket, two-phase anaerobic digestion, and an anaerobic fluidized bed. When anaerobically digested sludge and aerobic active sludge are inoculated in the UASB, particle-shaped sludge was formed well in both sludges. This technology has begun to be used in breweries and citric acid factories. With anaerobic treatment of waste water containing sulfate, the sulfate was recovered as sulfur by using the first and second phases. Research and development is being progressed on the oxidation ditch technology as an improved version of the active sludge method. In a pilot test of a soil treatment system and a stabilization pond treatment system as alternative technology for the active sludge method, the BOD in the treated water was found 2.5 mg{times}1/l. Attentions are drawn on primary treatment, a living organism contact oxidation method, and a continuous filtration treatment process as technologies to turn polluted water into resources. 6 refs., 1 tab.

  8. Deconstructing nitrate isotope dynamics in aquifers

    Science.gov (United States)

    Granger, J.

    2012-12-01

    The natural abundance N and O stable isotope ratios of nitrate provide an invaluable tool to differentiate N sources to the environment, track their dispersal, and monitor their attenuation by biological transformations. The interpretation of patterns in isotope abundances relies on knowledge of the isotope ratios of the source end-members, as well as on constraints on the isotope discrimination imposed on nitrate by respective biological processes. Emergent observations from mono-culture experiments of denitrifying bacteria reveal nitrate fractionation trends that appear at odds with trends ascribed to denitrification in soils and aquifers. This discrepancy raises the possibility that additional biological N transformations may be acting in tandem with denitrification. Here, the N and O isotope enrichments associated with nitrate removal by denitrification in aquifers are posited to bear evidence of coincident biological nitrate production - from nitrification and/or from anammox. Simulations are presented from a simple time-dependent one-box model of a groundwater mass ageing that is subject to net nitrate loss by denitrification with coincident nitrate production by nitrification or anammox. Within boundary conditions characteristic of freshwater aquifers, the apparent slope of the parallel enrichments in nitrate N and O isotopes associated with net N loss to denitrification can vary in proportion to the nitrate added simultaneous by oxidative processes. Pertinent observations from nitrate plumes in suboxic to anoxic aquifers are examined to validate this premise. In this perspective, nitrate isotope distributions suggest that we may be missing important N fluxes inherent to most aquifers.

  9. Removal of steroid estrogens from municipal wastewater in a pilot scale expanded granular sludge blanket reactor and anaerobic membrane bioreactor.

    Science.gov (United States)

    Ito, Ayumi; Mensah, Lawson; Cartmell, Elise; Lester, John N

    2016-01-01

    Anaerobic treatment of municipal wastewater offers the prospect of a new paradigm by reducing aeration costs and minimizing sludge production. It has been successfully applied in warm climates, but does not always achieve the desired outcomes in temperate climates at the biochemical oxygen demand (BOD) values of municipal crude wastewater. Recently the concept of 'fortification' has been proposed to increase organic strength and has been demonstrated at the laboratory and pilot scale treating municipal wastewater at temperatures of 10-17°C. The process treats a proportion of the flow anaerobically by combining it with primary sludge from the residual flow and then polishing it to a high effluent standard aerobically. Energy consumption is reduced as is sludge production. However, no new treatment process is viable if it only addresses the problems of traditional pollutants (suspended solids - SS, BOD, nitrogen - N and phosphorus - P); it must also treat hazardous substances. This study compared three potential municipal anaerobic treatment regimes, crude wastewater in an expanded granular sludge blanket (EGSB) reactor, fortified crude wastewater in an EGSB and crude wastewater in an anaerobic membrane bioreactor. The benefits of fortification were demonstrated for the removal of SS, BOD, N and P. These three systems were further challenged with the removal of steroid estrogens at environmental concentrations from natural indigenous sources. All three systems removed these compounds to a significant degree, confirming that estrogen removal is not restricted to highly aerobic autotrophs, or aerobic heterotrophs, but is also a faculty of anaerobic bacteria. PMID:26212345

  10. Elucidation of the thermophilic phenol biodegradation pathway via benzoate during the anaerobic digestion of municipal solid waste.

    Science.gov (United States)

    Hoyos-Hernandez, Carolina; Hoffmann, Marieke; Guenne, Angeline; Mazeas, Laurent

    2014-02-01

    Anaerobic digestion makes it possible to valorize municipal solid waste (MSW) into biogas and digestate which are, respectively, a renewable energy source and an organic amendment for soil. Phenols are persistent pollutants present in MSW that can inhibit the anaerobic digestion process and have a toxic effect on microbiota if they are applied to soil together with digestate. It is then important to define the operational conditions of anaerobic digestion which allow the complete degradation of phenol. In this context, the fate of phenol during the anaerobic digestion of MSW at 55°C was followed using an isotopic tracing approach ((13)C6-phenol) in experimental microcosms with inoculum from an industrial thermophilic anaerobic digester. With this approach, it was possible to demonstrate the complete phenol biodegradation into methane and carbon dioxide via benzoate. Benzoate is known to be a phenol metabolite under mesophilic conditions, but in this study it was found for the first time to be a phenol degradation product at thermophilic temperature. PMID:24238916

  11. Anaerobic biodegradation of nonylphenol in river sediment under nitrate- or sulfate-reducing conditions and associated bacterial community

    International Nuclear Information System (INIS)

    Highlights: • NP biodegradation can occur under both nitrate- and sulfate-reducing conditions. • Anaerobic condition affects sediment bacterial diversity during NP biodegradation. • NP-degrading bacterial community structure varies under different anaerobic conditions. - Abstract: Nonylphenol (NP) is a commonly detected pollutant in aquatic ecosystem and can be harmful to aquatic organisms. Anaerobic degradation is of great importance for the clean-up of NP in sediment. However, information on anaerobic NP biodegradation in the environment is still very limited. The present study investigated the shift in bacterial community structure associated with NP degradation in river sediment microcosms under nitrate- or sulfate-reducing conditions. Nearly 80% of NP (100 mg kg−1) could be removed under these two anaerobic conditions after 90 or 110 days’ incubation. Illumina MiSeq sequencing analysis indicated that Proteobacteria, Firmicutes, Bacteroidetes and Chloroflexi became the dominant phylum groups with NP biodegradation. The proportion of Gammaproteobacteria, Deltaproteobacteria and Choloroflexi showed a marked increase in nitrate-reducing microcosm, while Gammaproteobacteria and Firmicutes in sulfate-reducing microcosm. Moreover, sediment bacterial diversity changed with NP biodegradation, which was dependent on type of electron acceptor

  12. Natural attenuation of chlorinated volatile organic compounds in a freshwater tidal wetland: Field evidence of anaerobic biodegradation

    Science.gov (United States)

    Lorah, M.M.; Olsen, L.D.

    1999-01-01

    Field evidence collected along two groundwater flow paths shows that anaerobic biodegradation naturally attenuates a plume of chlorinated volatile organic compounds as it discharges from an aerobic sand aquifer through wetland sediments. A decrease in concentrations of two parent contaminants, trichloroethylene (TCE) and 1,1,2,2-tetrachloroethane (PCA), and a concomitant increase in concentrations of anaerobic daughter products occurs along upward flow paths through the Wetland sediments. The daughter products 1,2-dichloroethylene, vinyl chloride, 1,1,2-trichloroethane, and 1,2-dichloroethane are produced from hydrogenolysis of TCE and from PCA degradation through hydrogenolysis and dichloroelimination (reductive dechlorination) pathways. Total concentrations of TCE, PCA, and their degradation products, however, decrease to below detection levels within 0.15-0.30 m of land surface. The enhanced reductive dechlorination of TCE and PCA in the wetland sediments is associated with the naturally higher concentrations of dissolved organic carbon and the lower redox state of the groundwater compared to the aquifer. This field study indicates that wetlands and similar organic-rich environments at groundwater/surface-water interfaces may be important in intercepting groundwater contaminated with chlorinated organics and in naturally reducing concentrations and toxicity before sensitive surface-water receptors are reached.

  13. 不同季节及厌氧发酵对奶牛场污水及沼液各污染指标的影响%Influence of Different Seasons and Anaerobic Fermentation on Pollution Indicators of Wastewater and Biogas Slurry of Dairy Farm

    Institute of Scientific and Technical Information of China (English)

    王庆红; 娜仁花; 王超; 李倜字

    2012-01-01

    随着奶牛养殖业的迅猛发展,奶牛场排放的废弃物越来越集中,产生的环境问题也日益受到人们的关注。其中奶牛场排出的废水严重污染着水体和土壤,因此对其进行排污分析尤为重要。本试验对规模化奶牛场产生污水的主要污染指标及沼液的特性进行了测定分析,以期为规模化奶牛场污水的处理和利用提供依据。%With the rapid development of the dairy industry, pollutants discharged by the dairy farm become increasingly serious, and the consequent environmental problems receive more and more attention from society. Among all the pollutants, wastewater discharged by the dairy farm heavily damages the water body and the earth. Therefore, it is of particular importance to analyze the wastewater discharge. This research tested and analyzed the major pollution indicators and the features of liquid biogas of the wastewater discharged by large-scale dairy farms, so as to provide reference fieures to the treatment .ncl ,,,;1;~.~-;^- ^c

  14. Cadmium removal by Euglena gracilis is enhanced under anaerobic growth conditions

    Energy Technology Data Exchange (ETDEWEB)

    Santiago-Martínez, M. Geovanni; Lira-Silva, Elizabeth; Encalada, Rusely; Pineda, Erika; Gallardo-Pérez, Juan Carlos [Departamento de Bioquímica, Instituto Nacional de Cardiología (Mexico); Zepeda-Rodriguez, Armando [Facultad de Medicina, UNAM, Mexico City (Mexico); Moreno-Sánchez, Rafael; Saavedra, Emma [Departamento de Bioquímica, Instituto Nacional de Cardiología (Mexico); Jasso-Chávez, Ricardo, E-mail: rjass_cardiol@yahoo.com.mx [Departamento de Bioquímica, Instituto Nacional de Cardiología (Mexico)

    2015-05-15

    Highlights: • The protist Euglena gracilis had the ability to grow and remove large amounts of Cd{sup 2+} under anaerobic conditions. • High biomass was attained by combination of glycolytic and mitochondrial carbon sources. • Routes of degradation of glucose, glutamate and malate under anaerobic conditions in E. gracilis are described. • Biosorption was the main mechanism of Cd{sup 2+} removal in anaerobiosis, whereas the Cd{sup 2+} intracellularly accumulated was inactivated by thiol-molecules and polyphosphate. - Abstract: The facultative protist Euglena gracilis, a heavy metal hyper-accumulator, was grown under photo-heterotrophic and extreme conditions (acidic pH, anaerobiosis and with Cd{sup 2+}) and biochemically characterized. High biomass (8.5 × 10{sup 6} cells mL{sup −1}) was reached after 10 days of culture. Under anaerobiosis, photosynthetic activity built up a microaerophilic environment of 0.7% O{sub 2}, which was sufficient to allow mitochondrial respiratory activity: glutamate and malate were fully consumed, whereas 25–33% of the added glucose was consumed. In anaerobic cells, photosynthesis but not respiration was activated by Cd{sup 2+} which induced higher oxidative stress. Malondialdehyde (MDA) levels were 20 times lower in control cells under anaerobiosis than in aerobiosis, although Cd{sup 2+} induced a higher MDA production. Cd{sup 2+} stress induced increased contents of chelating thiols (cysteine, glutathione and phytochelatins) and polyphosphate. Biosorption (90%) and intracellular accumulation (30%) were the mechanisms by which anaerobic cells removed Cd{sup 2+} from medium, which was 36% higher versus aerobic cells. The present study indicated that E. gracilis has the ability to remove Cd{sup 2+} under anaerobic conditions, which might be advantageous for metal removal in sediments from polluted water bodies or bioreactors, where the O{sub 2} concentration is particularly low.

  15. Anaerobic in situ biodegradation of TNT using whey as an electron donor: a case study.

    Science.gov (United States)

    Innemanová, Petra; Velebová, Radka; Filipová, Alena; Čvančarová, Monika; Pokorný, Petr; Němeček, Jan; Cajthaml, Tomáš

    2015-12-25

    Contamination by 2,4,6-trinitrotoluene (TNT), an explosive extensively used by the military, represents a serious environmental problem. In this study, whey has been selected as the most technologically and economically suitable primary substrate for anaerobic in situ biodegradation of TNT. Under laboratory conditions, various additions of whey, molasses, acetate and activated sludge as an inoculant were tested and the process was monitored using numerous chemical analyses including phospholipid fatty acid analysis. The addition of whey resulted in the removal of more than 90% of the TNT in real contaminated soil (7 mg kg(-1) and 12 mg kg(-1) of TNT). The final bioremediation strategy was suggested on the basis of the laboratory results and tested under real conditions at a TNT contaminated site in the Czech Republic. During the pilot test, three repeated injections of whey suspension into the sandy aquifer were performed over a 10-month period. In total, approximately 5m(3) of whey were used. A substantial decrease in the TNT groundwater concentration from the original levels (equalling 1.49 mg l(-1) to 8.58 mg l(-1)) was observed in most of the injection wells, while the concentrations of the TNT biotransformation products were found to be elevated. Pilot-scale application results showed that the anoxic and/or anaerobic conditions in the aquifer were sufficient for TNT bio-reduction by autochthonous microorganisms. Whey application was not accompanied by undesirable effects such as a substantial decrease in the pH or clogging of the wells. The results of the study document the suitability of application of whey to bioremediate TNT contaminated sites in situ. PMID:25882606

  16. Engineering risk analysis of water pollution. Probabilities and fuzzy sets

    International Nuclear Information System (INIS)

    In a unique and comprehensive way, this book analyzes the questions of risk and reliability in water quality. And more than that: It also develops a methodology to evaluate the environmental impact from wastewater disposal on rivers, groundwater and coastal areas. Major topics covered include: - Fuzzy set theory for engineering risk analysis; - uncertainty analysis of water quantity and quality data; - stochastic and fuzzy simulation of hydrosystems: Model selection under uncertainty, water quality management in rivers and aquifers, risk in coastal pollution; - decision theory under uncertainty: Groundwater pollution, risk management, risk-cost trade-offs. (orig./EF)

  17. New Bio-Indicators for Long Term Natural Attenuation of Monoaromatic Compounds in Deep Terrestrial Aquifers.

    Science.gov (United States)

    Aüllo, Thomas; Berlendis, Sabrina; Lascourrèges, Jean-François; Dessort, Daniel; Duclerc, Dominique; Saint-Laurent, Stéphanie; Schraauwers, Blandine; Mas, Johan; Patriarche, Delphine; Boesinger, Cécile; Magot, Michel; Ranchou-Peyruse, Anthony

    2016-01-01

    Deep subsurface aquifers despite difficult access, represent important water resources and, at the same time, are key locations for subsurface engineering activities for the oil and gas industries, geothermal energy, and CO2 or energy storage. Formation water originating from a 760 m-deep geological gas storage aquifer was sampled and microcosms were set up to test the biodegradation potential of BTEX by indigenous microorganisms. The microbial community diversity was studied using molecular approaches based on 16S rRNA genes. After a long incubation period, with several subcultures, a sulfate-reducing consortium composed of only two Desulfotomaculum populations was observed able to degrade benzene, toluene, and ethylbenzene, extending the number of hydrocarbonoclastic-related species among the Desulfotomaculum genus. Furthermore, we were able to couple specific carbon and hydrogen isotopic fractionation during benzene removal and the results obtained by dual compound specific isotope analysis (C = -2.4‰ ± 0.3‰; H = -57‰ ± 0.98‰; AKIEC: 1.0146 ± 0.0009, and AKIEH: 1.5184 ± 0.0283) were close to those obtained previously in sulfate-reducing conditions: this finding could confirm the existence of a common enzymatic reaction involving sulfate-reducers to activate benzene anaerobically. Although we cannot assign the role of each population of Desulfotomaculum in the mono-aromatic hydrocarbon degradation, this study suggests an important role of the genus Desulfotomaculum as potential biodegrader among indigenous populations in subsurface habitats. This community represents the simplest model of benzene-degrading anaerobes originating from the deepest subterranean settings ever described. As Desulfotomaculum species are often encountered in subsurface environments, this study provides some interesting results for assessing the natural response of these specific hydrologic systems in response to BTEX contamination during remediation projects. PMID:26904000

  18. River and Stream Pollution

    Science.gov (United States)

    ... Topics Games Activities Lessons MENU River and Stream Pollution Kids Homepage Topics Pollution River and Stream Pollution ... stream in the first place by disturbing the land as little as possible. Farmers and construction workers ...

  19. Indoor Air Pollution

    Science.gov (United States)

    We usually think of air pollution as being outdoors, but the air in your house or office could also be polluted. Sources of indoor pollution include Mold and pollen Tobacco smoke Household products ...

  20. A study of chlorinated solvent contamination of the aquifers of an industrial area in central Italy: a possibility of bioremediation

    OpenAIRE

    Matteucci, Federica; Ercole, Claudia; del Gallo, Maddalena

    2015-01-01

    Perchloroethene, trichloroethene, and other chlorinated solvents are widespread groundwater pollutants. They form dense non-aqueous phase liquids that sink through permeable groundwater aquifers until non-permeable zone is reached. In Italy, there are many situations of serious contamination of groundwater that might compromise their use in industry, agriculture, private, as the critical case of a Central Italy valley located in the province of Teramo (“Val Vibrata”), characterized by a signi...

  1. Kinetics and modeling of anaerobic digestion process

    DEFF Research Database (Denmark)

    Gavala, Hariklia N.; Angelidaki, Irini; Ahring, Birgitte Kiær

    Anaerobic digestion modeling started in the early 1970s when the need for design and efficient operation of anaerobic systems became evident. At that time not only was the knowledge about the complex process of anaerobic digestion inadequate but also there were computational limitations. Thus, the...... first models were very simple and consisted of a limited number of equations. During the past thirty years much research has been conducted on the peculiarities of the process and on the factors that influence it on the one hand while an enormous progress took place in computer science on the other. The...... combination of both parameters resulted in the development of more and more concise and complex models. In this chapter the most important models found in the literature are described starting from the simplest and oldest to the more recent and complex ones....

  2. [Anaerobic-aerobic infection in acute appendicitis].

    Science.gov (United States)

    Mamchich, V I; Ulitovskiĭ, I V; Savich, E I; Znamenskiĭ, V A; Beliaeva, O A

    1998-01-01

    362 patients with acute appendicitis (AA) were examined. For microbiological diagnosis of aerobic and anaerobic nonclostridial microflora we used complex accelerated methods (including evaluation of gram-negative microorganisms in comparison with tinctorial-fermentative method of differential staining according to oxygen sensitivity of catalasopositive together with aerobic and cathalasonegative anaerobic microorganisms) as well as complete bacteriologic examination with determination of sensitivity of the above microorganism to antimicrobial remedies. High rate of aerobic-anaerobic microbial associations and substantial identity of microflora from appendicis and exudate from abdominal cavity was revealed, which evidenced the leading role of endogenous microorganisms in etiology and pathogenesis of AA and peritonitis i. e. autoinfection. In patients with destructive forms of AA, complicated by peritonitis it is recommended to use the accelerated method of examination of pathologic material as well as the complete scheme of examination with the identification of the isolated microorganisms and the correction of antibiotic treatment. PMID:9511291

  3. Anaerobic lipid degradation through acidification and methanization.

    Science.gov (United States)

    Kim, Ijung; Kim, Sang-Hyoun; Shin, Hang-Sik; Jung, Jin-Young

    2010-01-01

    In biological wastewater treatment high lipid concentration is known to inhibit microorganisms and cause active biomass flotation. To reduce lipid inhibition, a two-phase anaerobic system, consisting of an anaerobic sequencing batch reactor (ASBR) and an upflow anaerobic sludge blanket (UASB) reactor, was applied to synthetic dairy wastewater. During 153 days of operation, the two-phase system showed stable performance in lipid degradation. In the ASBR, a 13% lipid removal efficiency and 10% double bond removal efficiency were maintained. In the UASB, the chemical oxygen demand (COD), lipid and volatile fatty acid (VFA) removal efficiencies were more than 80%, 70% and 95%, respectively, up to organic loading rate 6.5 g COD/L/day. There were no operational problems such as serious scum formation or sludge washout. Protein degradation occurred prior to degradation during acidogenesis. PMID:20134250

  4. Biochemistry and physiology of anaerobic bacteria

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-05-18

    We welcome you to The Power of Anaerobes. This conference serves two purposes. One is to celebrate the life of Harry D. Peck, Jr.,who was born May 18, 1927 and would have celebrated his 73rd birthday at this conference. He died November 20, 1998. The second is to gather investigators to exchange views within the realm of anaerobic microbiology, an area in which tremendous progress has been seen during recent years. It is sufficient to mention discoveries of a new form of life (the archaea), hyper or extreme thermophiles, thermophilic alkaliphiles and anaerobic fungi. With these discoveries has come a new realization about physiological and metabolic properties of microorganisms, and this in turn has demonstrated their importance for the development, maintenance and sustenance of life on Earth.

  5. Biochar from anaerobically digested sugarcane bagasse.

    Science.gov (United States)

    Inyang, Mandu; Gao, Bin; Pullammanappallil, Pratap; Ding, Wenchuan; Zimmerman, Andrew R

    2010-11-01

    This study was designed to investigate the effect of anaerobic digestion on biochar produced from sugarcane bagasse. Sugarcane bagasse was anaerobically digested to produce methane. The digested residue and fresh bagasse was pyrolyzed separately into biochar at 600 degrees C in nitrogen environment. The digested bagasse biochar (DBC) and undigested bagasse biochar (BC) were characterized to determine their physicochemical properties. Although biochar was produced from the digested residue (18% by weight) and the raw bagasse (23%) at a similar rate, there were many physiochemical differences between them. Compared to BC, DBC had higher pH, surface area, cation exchange capacity (CEC), anion exchange capacity (AEC), hydrophobicity and more negative surface charge, all properties that are generally desirable for soil amelioration, contaminant remediation or wastewater treatment. Thus, these results suggest that the pyrolysis of anaerobic digestion residues to produce biochar may be an economically and environmentally beneficial use of agricultural wastes. PMID:20634061

  6. Water-level change, High Plains aquifer, 1995 to 2000

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This raster data set represents water-level change in the High Plains aquifer of the United States from 1995 to 2000, in feet. The High Plains aquifer underlies...

  7. Aquifers of Alluvial and Glacial Origin - Direct Download

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set represents the extent of the alluvial and glacial aquifers north of the southern-most line of glaciation. Aquifers are shown in the States of Maine,...

  8. Water-level change, High Plains aquifer, 2005 to 2009

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This raster data set represents water-level change in the High Plains aquifer of the United States from 2005 to 2009, in feet. The High Plains aquifer underlies...

  9. Water-level change, High Plains aquifer, 1980 to 1995

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This raster data set represents water-level change in the High Plains aquifer of the United States from 1980 to 1995, in feet. The High Plains aquifer underlies...

  10. Water-level change, High Plains aquifer, 2000 to 2005

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This raster data set represents water-level change in the High Plains aquifer of the United States from 2000 to 2005, in feet. The High Plains aquifer underlies...

  11. The effect of pH and operation mode for COD removal of slaughterhouse wastewater with Anaerobic Batch Reactor (ABR)

    OpenAIRE

    Maria Octoviane Dyan; Gita Permana Putra; Budiyono Budiyono; Siswo Sumardiono; Tutuk Djoko Kusworo

    2015-01-01

    Disposal of industrial wastes in large quantities was not in accordance with today's standards of waste into environmental issues that must be overcome with proper treatment. Similarly, the abattoir wastewater that contains too high organic compounds and suspended solids. The amount of liquid waste disposal Slaughterhouse (SW) with high volume also causes pollution. The research aim to resolve this problem by lowering the levels of BOD-COD to comply with effluent quality standard. Anaerobic p...

  12. Fate of organic micropollutants during anaerobic digestion of sewage sludge: localization of micropollutants within sludge organic matter pools

    OpenAIRE

    Aemig, Quentin; Cheron, Claire; Delgenès, Nadine; Houot, Sabine; Patureau, Dominique

    2013-01-01

    Many organic micropolluants enter the environment through wastewaters. Some are partly degraded during wastewater treatment. For others, due to hydrophobic properties, sorption to sludge is the main removal process. Anaerobic digestion is widely used to treat sludge because it produced renewable energy in the form of methane. The digested sludge can be used as organic fertilizer. To evaluate the risk of soil contamination, it is necessary to know if organic pollutants are dissipated during th...

  13. Aquifer parameter estimation from surface resistivity data.

    Science.gov (United States)

    Niwas, Sri; de Lima, Olivar A L

    2003-01-01

    This paper is devoted to the additional use, other than ground water exploration, of surface geoelectrical sounding data for aquifer hydraulic parameter estimation. In a mesoscopic framework, approximated analytical equations are developed separately for saline and for fresh water saturations. A few existing useful aquifer models, both for clean and shaley sandstones, are discussed in terms of their electrical and hydraulic effects, along with the linkage between the two. These equations are derived for insight and physical understanding of the phenomenon. In a macroscopic scale, a general aquifer model is proposed and analytical relations are derived for meaningful estimation, with a higher level of confidence, of hydraulic parameter from electrical parameters. The physical reasons for two different equations at the macroscopic level are explicitly explained to avoid confusion. Numerical examples from existing literature are reproduced to buttress our viewpoint. PMID:12533080

  14. Nitrate reduction in an unconfined sandy aquifer

    DEFF Research Database (Denmark)

    Postma, Diederik Jan; Boesen, Carsten; Kristiansen, Henning; Larsen, Flemming

    1991-01-01

    Nitrate distribution and reduction processes were investigated in an unconfined sandy aquifer of Quaternary age. Groundwater chemistry was studied in a series of eight multilevel samplers along a flow line, deriving water from both arable and forested land. Results show that plumes of nitrate......-contaminated groundwater emanate from the agricultural areas and spread through the aquifer. The aquifer can be subdivided into an upper 10- to 15-m thick oxic zone that contains O2 and NO3-, and a lower anoxic zone characterized by Fe2+-rich waters. The redox boundary is very sharp, which suggests that reduction...... processes of O2 and NO3- occur at rates that are fast compared to the rate of downward water transport. Nitrate-contaminated groundwater contains total contents of dissolved ions that are two to four times higher than in groundwater derived from the forested area. The persistence of the high content of...

  15. Ground Water movement in crystalline rock aquifers

    International Nuclear Information System (INIS)

    Ground water movement studies were performed in crystalline rock aquifers from the upper Acarau River hydrographic basin, state of Ceara, Brazil. The studies included carbon-14, 18O/16O and tritium measurements as well as chemical analysis. A total of 35 wells were surveyed during drought seasons. Carbon-14 values displayed little variation which implied that the water use was adequate despite of the slower recharge conditions. Fairly constant isotopic 18O/16O ratio values in the wells and their similarity with rainwater values indicated that the recharge is done exclusively by pluvial waters. A decreasing tendency within the tritium concentration values were interpreted as a periodic rainwater renewal for these aquifers. The chemical analysis demonstrated that there is in fact no correlation between salinity and the time the water remains in the aquifer itself. (D.J.M.)

  16. The effect of tannic compounds on anaerobic wastewater treatment.

    NARCIS (Netherlands)

    Field, J.A.

    1989-01-01

    Anaerobic wastewater treatment is an alternative to the conventional aerobic treatment processes for the removal of easily biodegradable organic matter in medium to high strength industrial wastestreams. Anaerobic treatment has several advantages, however one important disadvantage is the high sensi

  17. ANAEROBIC AND AEROBIC TREATMENT OF CHLORINATED ALIPHATIC COMPOUNDS

    Science.gov (United States)

    Biological degradation of 12 chlorinated aliphatic compounds (CACs) was assessed in bench-top reactors and in serum bottle tests. Three continuously mixed daily batch-fed reactor systems were evaluated: anaerobic, aerobic, and sequential-anaerobic-aerobic (sequential). Glucose,...

  18. Succession of lignocellulolytic bacterial consortia bred anaerobically from lake sediment

    NARCIS (Netherlands)

    Korenblum, Elisa; Jiménez Avella, Diego; van Elsas, Jan

    2016-01-01

    Anaerobic bacteria degrade lignocellulose in various anoxic and organically rich environments, often in a syntrophic process. Anaerobic enrichments of bacterial communities on a recalcitrant lignocellulose source were studied combining polymerase chain reaction–denaturing gradient gel electrophoresi

  19. Pollution Prevention Pays: Pollution Charges in Cambodia

    OpenAIRE

    Sideth Muong

    2006-01-01

    Across the developing world, governments are grappling with the problem of industrial pollution. A new report from Cambodia looks into a system of pollution levies that would encourage polluting firms to clean up their emissions. This study sets out a series of charges that are projected to produce pollution reductions of up to 85%. It recommends a number of regulatory and administrative changes that would help bring about such an outcome.

  20. Modelling Strategies for Water Supply Companies to Deal with Nitrate Pollution

    OpenAIRE

    Yvonne Haffner; Stefan Gramel

    2001-01-01

    The computer based model presented in this paper regards strategies for water supply companies to deal with nitrate pollution of groundwater aquifers. In Germany, as well as in many other European regions, nitrate pollution is one of the most important problems for water protection and water supply. The simulation of an existing water supply company shows a high level of conformance between simulation results and economic data of the company. The simulation of scenarios with high nitrate poll...

  1. Potential contaminant pathways from hydraulically fractured shale to aquifers.

    Science.gov (United States)

    Myers, Tom

    2012-01-01

    Hydraulic fracturing of deep shale beds to develop natural gas has caused concern regarding the potential for various forms of water pollution. Two potential pathways-advective transport through bulk media and preferential flow through fractures-could allow the transport of contaminants from the fractured shale to aquifers. There is substantial geologic evidence that natural vertical flow drives contaminants, mostly brine, to near the surface from deep evaporite sources. Interpretative modeling shows that advective transport could require up to tens of thousands of years to move contaminants to the surface, but also that fracking the shale could reduce that transport time to tens or hundreds of years. Conductive faults or fracture zones, as found throughout the Marcellus shale region, could reduce the travel time further. Injection of up to 15,000,000 L of fluid into the shale generates high pressure at the well, which decreases with distance from the well and with time after injection as the fluid advects through the shale. The advection displaces native fluids, mostly brine, and fractures the bulk media widening existing fractures. Simulated pressure returns to pre-injection levels in about 300 d. The overall system requires from 3 to 6 years to reach a new equilibrium reflecting the significant changes caused by fracking the shale, which could allow advective transport to aquifers in less than 10 years. The rapid expansion of hydraulic fracturing requires that monitoring systems be employed to track the movement of contaminants and that gas wells have a reasonable offset from faults. PMID:22509908

  2. Aquifer thermal energy storage. International symposium: Proceedings

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-05-01

    Aquifers have been used to store large quantities of thermal energy to supply process cooling, space cooling, space heating, and ventilation air preheating, and can be used with or without heat pumps. Aquifers are used as energy sinks and sources when supply and demand for energy do not coincide. Aquifer thermal energy storage may be used on a short-term or long-term basis; as the sole source of energy or as a partial storage; at a temperature useful for direct application or needing upgrade. The sources of energy used for aquifer storage are ambient air, usually cold winter air; waste or by-product energy; and renewable energy such as solar. The present technical, financial and environmental status of ATES is promising. Numerous projects are operating and under development in several countries. These projects are listed and results from Canada and elsewhere are used to illustrate the present status of ATES. Technical obstacles have been addressed and have largely been overcome. Cold storage in aquifers can be seen as a standard design option in the near future as it presently is in some countries. The cost-effectiveness of aquifer thermal energy storage is based on the capital cost avoidance of conventional chilling equipment and energy savings. ATES is one of many developments in energy efficient building technology and its success depends on relating it to important building market and environmental trends. This paper attempts to provide guidance for the future implementation of ATES. Individual projects have been processed separately for entry onto the Department of Energy databases.

  3. Multivariate monitoring of anaerobic co-digestion

    DEFF Research Database (Denmark)

    Madsen, Michael; Holm-Nielsen, Jens Bo

    warming and environmental concerns. Anaerobic digestion applied in agriculture can simultaneously convert heterogeneous biomasses and wastes from the primary agricultural sector and from the bio processing industries, for instance food processing, pharma, and biofuel production, into valuable organic...... fertiliser and renewable energy. Meanwhile, in order for the biogas sector to become a significant player in the energy supply chain, the anaerobic digestion process has to be controlled to a greater extent than what is implemented as state-of-the-art today. Through application of the philosophy behind...

  4. Susceptibility of anaerobic bacteria to carbenicillin.

    Science.gov (United States)

    Blazevic, D J; Matsen, J M

    1974-05-01

    One hundred and seventy-one strains of anaerobes were tested for susceptibility to carbenicillin by using agar dilution, broth dilution, and two disk diffusion methods. The minimal inhibitory concentration (MIC) for 67% of 51 strains of Bacteroides fragilis, 7 of 9 strains of Bacteroides melaninogenicus, and all of 8 strains of Eubacterium was 100 mug or less per ml. The MICs of the remaining anaerobes were 50 mug or less per ml. The broth dilution results were felt to be the most accurate of the four methods utilized. PMID:4462461

  5. USCG Facility Pollution

    Data.gov (United States)

    Department of Homeland Security — The Marine Casualty and Pollution Data files provide details about marine casualty and pollution incidents investigated by Coast Guard Offices throughout the United...

  6. USCG Vessel Pollution

    Data.gov (United States)

    Department of Homeland Security — The Marine Casualty and Pollution Data files provide details about marine casualty and pollution incidents investigated by Coast Guard Offices throughout the United...

  7. A strategy for aromatic hydrocarbon bioremediation under anaerobic conditions and the impacts of ethanol: a microcosm study.

    Science.gov (United States)

    Chen, Yu Dao; Barker, James F; Gui, Lai

    2008-02-19

    Increased use of ethanol-blended gasoline (gasohol) and its potential release into the subsurface have spurred interest in studying the biodegradation of and interactions between ethanol and gasoline components such as benzene, toluene, ethylbenzene and xylene isomers (BTEX) in groundwater plumes. The preferred substrate status and the high biological oxygen demand (BOD) posed by ethanol and its biodegradation products suggests that anaerobic electron acceptors (EAs) will be required to support in situ bioremediation of BTEX. To develop a strategy for aromatic hydrocarbon bioremediation and to understand the impacts of ethanol on BTEX biodegradation under strictly anaerobic conditions, a microcosm experiment was conducted using pristine aquifer sand and groundwater obtained from Canadian Forces Base Borden, Canada. The initial electron accepter pool included nitrate, sulfate and/or ferric iron. The microcosms typically contained 400 g of sediment, 600 approximately 800 ml of groundwater, and with differing EAs added, and were run under anaerobic conditions. Ethanol was added to some at concentrations of 500 and 5000 mg/L. Trends for biodegradation of aromatic hydrocarbons for the Borden aquifer material were first developed in the absence of ethanol, The results showed that indigenous microorganisms could degrade all aromatic hydrocarbons (BTEX and trimethylbenzene isomers-TMB) under nitrate- and ferric iron-combined conditions, but not under sulfate-reducing conditions. Toluene, ethylbenzene and m/p-xylene were biodegraded under denitrifying conditions. However, the persistence of benzene indicated that enhancing denitrification alone was insufficient. Both benzene and o-xylene biodegraded significantly under iron-reducing conditions, but only after denitrification had removed other aromatics. For the trimethylbenzene isomers, 1,3,5-TMB biodegradation was found under denitrifying and then iron-reducing conditions. Biodegradation of 1,2,3-TMB or 1,2,4-TMB was

  8. Unconfined Aquifer Flow Theory - from Dupuit to present

    OpenAIRE

    Mishra, Phoolendra K.; Kuhlman, Kristopher L.

    2013-01-01

    Analytic and semi-analytic solution are often used by researchers and practicioners to estimate aquifer parameters from unconfined aquifer pumping tests. The non-linearities associated with unconfined (i.e., water table) aquifer tests makes their analysis more complex than confined tests. Although analytical solutions for unconfined flow began in the mid-1800s with Dupuit, Thiem was possibly the first to use them to estimate aquifer parameters from pumping tests in the early 1900s. In the 195...

  9. Conceptual and numerical modeling approach of the Guarani Aquifer System

    OpenAIRE

    Rodríguez, L.; Vives, L; Gomez, A.

    2013-01-01

    In large aquifers, relevant for their considerable size, regional groundwater modeling remains challenging given geologic complexity and data scarcity in space and time. Yet, it may be conjectured that regional scale groundwater flow models can help in understanding the flow system functioning and the relative magnitude of water budget components, which are important for aquifer management. The Guaraní Aquifer System is the largest transboundary aquifer in South America. It contains an enormo...

  10. Groundwater thermal-effective injection systems in shallow aquifers: possible alternatives to vertical water wells

    Science.gov (United States)

    Lo Russo, Stefano; Taddia, Glenda; Cerino Abdin, Elena

    2014-05-01

    Urbanized areas have environmental features that may influence the development of low-enthalpy geothermal systems and the choice of the most suitable among the available (roughly earth-coupled closed-loop and groundwater open-loop type). In particular, if compared to less anthropized areas, some characteristic urban elements require particular attention: underground extensive use, contamination of groundwater, interference between the systems, authorization procedures and planning restrictions, the competition with cogeneration systems and the impact on emissions of pollutants. In this general context, the increasing implementation in several areas of the world of the open-loop groundwater heat pumps technology which discharge into the aquifer for cooling and heating buildings, could potentially cause, even in the short term, a significant environmental impact associated with thermal interference with groundwater, particularly in the shallow aquifers. The discharge of water at different temperatures compared to baseline (warmer in summer and colder in winter) poses a number of problems in relation to the potential functionality of many existing situations of use of the groundwater (drinking water wells, agricultural, industrial, etc.). In addition, there may be cases of interference between systems, especially in the more densely urbanized areas. Appropriate hydrogeological investigations should be performed for the characterization of the main hydrogeological parameters of the subsoil at the considered site in order to minimize the environmental impact of discharges into aquifers. The current Italian legislation related to withdrawals and discharges into aquifers designs a framework suitable for the protection of groundwater and induce deciding the best configuration of the plant with a case by case approach. An increased contact area between the dispersant system and the ground makes it possible to affect a greater volume of aquifer and, consequently, reduce the

  11. Startup and stabilization of anaerobic membrane bioreactors at ambient temperature

    OpenAIRE

    Benito Peña, Carlos

    2015-01-01

    There has been an increasing interest in wastewater treatment in last decades to reduce human footprint. Primarily, anaerobic technology focused on treatment and stabilization of sludge, but now the tendency is to give it a major role in low cost treatment of high/low strength wastewaters, since anaerobic digestion offers energy generation through gas production. Anaerobic membrane bioreactors (AnMBR) combine anaerobic digestion with membrane filtration. They are becoming a feasible opti...

  12. The Financial Feasibility of Anaerobic Digestion for Ontario's Livestock Industries

    OpenAIRE

    Weersink, Alfons; Mallon, Shawn

    2007-01-01

    This report is an investigation of the financial feasibility of farm based anaerobic digestion investments under Ontario's Standard Offer Contract electricity prices. Using Ontario Ministry of Agriculture, Food and Rural Affairs (OMAFRA) Agricultural Anaerobic Digestion Calculation Spreadsheet (AADCS) anaerobic digestion inputs, outputs, cost and revenues were estimated and used to conduct a financial analysis on the feasibility of four sized farm base anaerobic digestion investments. The res...

  13. The effect of tannic compounds on anaerobic wastewater treatment.

    OpenAIRE

    Field, J. A.

    1989-01-01

    Anaerobic wastewater treatment is an alternative to the conventional aerobic treatment processes for the removal of easily biodegradable organic matter in medium to high strength industrial wastestreams. Anaerobic treatment has several advantages, however one important disadvantage is the high sensitivity of the anaerobic bacteria (ie. methanogenic bacteria) to toxic compounds. The anaerobic technologies were initially developed for the treatment of non-toxic organic wastewaters. As the techn...

  14. Aquifer properties of the Chalk of England

    OpenAIRE

    MacDonald, Alan M.; Allen, David J

    2001-01-01

    Aquifer properties data from 2100 pumping tests carried out in the Chalk aquifer have been collated as part of a joint British Geological Survey/Environment Agency project. The dataset is highly biased: most pumping tests have been undertaken in valley areas where the yield of the Chalk is highest. Transmissivity values from measured sites give the appearance of log-normality, but are not truly log-normal. The median of available data is 540 m2/d and the 25th and 75th percentiles 190 m2/d and...

  15. Cold water aquifer storage. [air conditioning

    Science.gov (United States)

    Reddell, D. L.; Davison, R. R.; Harris, W. B.

    1980-01-01

    A working prototype system is described in which water is pumped from an aquifer at 70 F in the winter time, chilled to a temperature of less than 50 F, injected into a ground-water aquifer, stored for a period of several months, pumped back to the surface in the summer time. A total of 8.1 million gallons of chilled water at an average temperature of 48 F were injected. This was followed by a storage period of 100 days. The recovery cycle was completed a year later with a total of 8.1 million gallons recovered. Approximately 20 percent of the chill energy was recovered.

  16. Predicted nitrate and arsenic concentrations in basin-fill aquifers of the Southwest Principal Aquifers study area

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This product "Predicted nitrate and arsenic concentrations in basin-fill aquifers of the Southwest Principal Aquifers study area" is a 1:250,000-scale vector...

  17. Digital data sets that describe aquifer characteristics of the Vamoosa-Ada aquifer in east-central Oklahoma

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set consists of digitized polygons of constant recharge values for the Vamoosa-Ada aquifer, in east-central Oklahoma. The Vamoosa-Ada aquifer is an...

  18. Digital data sets that describe aquifer characteristics of the Vamoosa-Ada aquifer in east-central Oklahoma

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set consists of digitized polygons of constant hydraulic conductivity values for the Vamoosa-Ada aquifer in east-central Oklahoma. The Vamoosa-Ada aquifer...

  19. Digital data sets that describe aquifer characteristics of the Vamoosa-Ada aquifer in east-central Oklahoma

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set consists of digitized water-level elevation contours for the Vamoosa-Ada aquifer in east-central Oklahoma. The Vamoosa-Ada aquifer is an important...

  20. EPA Region 6 Sole Source Aquifers in Louisiana, Geographic NAD83, EPA (1996) [sole_source_aquifers_LA_EPA_1996

    Data.gov (United States)

    Louisiana Geographic Information Center — Polygon layer of EPA Region 6 sole source aquifers in Louisiana. The sole source aquifers represented are Chicot and Southern Hills in Louisiana/Mississippi.

  1. Examples of transient sounding from groundwater exploration in sedimentary aquifers

    Science.gov (United States)

    Fitterman, D.V.

    1987-01-01

    Examples of the use of transient electromagnetic soundings for three groundwater exploration problems in sedimentary aquifers are given. The examples include: 1) estimating depths to water table and bedrock in an alluvium-filled basin, 2) mapping a confined freshwater aquifer in bedrock sediments, and 3) locating a freshwater/saltwater interface in a glacial-outwash aquifer. -from Author

  2. Groundwater modeling of the Calera Aquifer region in Central Mexico

    Science.gov (United States)

    The Calera Aquifer is the main source of water for irrigated agriculture, industrial, and drinking water purposes in the Calera Aquifer Region (CAR) in the state of Zacatecas, Mexico. Irrigated agriculture accounts for 80% of the total groundwater extracted from the Calera Aquifer. In recent years, ...

  3. Review: The Yucatán Peninsula karst aquifer, Mexico

    DEFF Research Database (Denmark)

    Bauer-Gottwein, Peter; Gondwe, Bibi Ruth Neuman; Charvet, Guillaume;

    2011-01-01

    The Yucatán Peninsula karst aquifer is one of the most extensive and spectacular karst aquifer systems on the planet. This transboundary aquifer system extends over an area of approximately 165,000 km2 in México, Guatemala and Belize. The Triassic to Holocene Yucatán limestone platform is located...

  4. Treatment of domestic sewage in a two-step system anaerobic filter/anaerobic hybrid reactor at low temperature

    NARCIS (Netherlands)

    Elmitwalli, T.A.; Zeeman, G.; Oahn, K.L.T.; Lettinga, G.

    2002-01-01

    The treatment of domestic sewage at low temperature of 13 degrees Celsius was investigated in a two-step system consisting of an anaerobic filter (AF) + an anaerobic hybrid (AH) reactor operated at different hydraulic retention times (HRTs)

  5. The IWA Anaerobic digestion model no 1. (ADM1)

    DEFF Research Database (Denmark)

    Batstone, Damien J.; Keller, J.; Angelidaki, Irini;

    2002-01-01

    The IWA Anaerobic Digestion Modelling Task Group was established in 1997 at the 8th World Congress on Anaerobic Digestion (Sendai, Japan) with the goal of developing a generalised anaerobic digestion model. The structured model includes multiple steps describing biochemical as well...

  6. Stability of anaerobic reactors under micro-aeration conditions

    International Nuclear Information System (INIS)

    Oxidation of sulphide in anaerobic bioreactors by introducing limited amounts of oxygen provides a relatively simple strategy for reducing the levels of sulphite in anaerobic digesters (biogas and effluent). The introduction of limited amounts of air is a general practice in agricultural anaerobic digesters, it is estimated that worldwide over 3.000 units are operated under such conditions. (Author)

  7. Anaerobic Digestion. Student Manual. Biological Treatment Process Control.

    Science.gov (United States)

    Carnegie, John W., Ed.

    This student manual contains the textual material for a four-lesson unit on anaerobic digestion control. Areas addressed include: (1) anaerobic sludge digestion (considering the nature of raw sludge, purposes of anaerobic digestion, the results of digestion, types of equipment, and other topics); (2) digester process control (considering feeding…

  8. Pollution par les nitrates des eaux souterraines du bassin d'Essaouira (Maroc)

    Science.gov (United States)

    Laftouhi, Nour-Eddine; Vanclooster, Marnik; Jalal, Mohammed; Witam, Omar; Aboufirassi, Mohamed; Bahir, Mohamed; Persoons, Étienne

    2003-03-01

    The Essaouira Basin (Morocco) contains a multi-layered aquifer situated in fractured and karstic materials from the Middle and Upper Cretaceous (the Cenomanian, Turonian and Senonian). Water percolates through the limestone and dolomite formations of the Turonian stage either through the marls and calcareous marls of the Cenomanian or through the calcareous marly materials of the Senonian. The aquifer system may be interconnected since the marl layer separating the Turonian, Cenomanian and Senonian aquifers is thin or intensively fractured. In that case, the water is transported through a network of fractures and stratification joints. This paper describes the extent of the nitrate pollution in the area and its origin. Most of the wells and drillholes located in the Kourimat perimeter are contaminated by nitrates with some concentrations over 400 mg l-1. Nitrate contamination is also observed in the surface water of the Qsob River, which constitutes the natural outlet of the multi-layered complex aquifer system. In this area, agriculture is more developed than in the rest of the Essaouira Basin. Diffuse pollution of the karstic groundwater body by agricultural fertiliser residues may therefore partially explain the observed nitrate pollution. However, point pollution around the wells, springs and drillholes from human wastewater, livestock faeces and the mineralisation of organic debris close to the Muslim cemeteries cannot be excluded.

  9. Modeling of pheratic aquifers on E, coli transport influenced by preconsolidation and compressibility of soil

    OpenAIRE

    solomon Ndubuisi Eluozo

    2012-01-01

    The rate of pollution on soil are the major problem of ground water contamination in the study area,  the   influence from   preconsolidation and compressibility of soil influence on E.coli transport  has been carried out. This  is  to determine the rate of influence on  E.coli transport in pheratic aquifers, mathematical model were developed to monitor the influence on the preconsolidation and compressibility of soil on  microbial transports, experimental analysis were also carried out throu...

  10. Study of the feasibility of an aquifer storage and recovery system in a deep aquifer in Belgium

    OpenAIRE

    Vandenbohede, A.; Van Houtte, E.; Lebbe, L.

    2008-01-01

    The feasibility of aquifer storage and recovery (ASR) was tested in a deep aquifer near Koksijde, Belgium. To achieve this, oxic drinking water was injected into a deep aquifer (the Tienen Formation) that contains anoxic brackish water. The hydraulic properties of the aquifer were determined using a step-drawdown test. Chemical processes caused by the injection of the water were studied by two push—pull tests. The step-drawdown test was interpreted by means of an inverse numerical model, resu...

  11. Aquifer geochemistry at potential aquifer storage and recovery sites in coastal plain aquifers in the New York city area, USA

    Science.gov (United States)

    Brown, C.J.; Misut, P.E.

    2010-01-01

    The effects of injecting oxic water from the New York city (NYC) drinking-water supply and distribution system into a nearby anoxic coastal plain aquifer for later recovery during periods of water shortage (aquifer storage and recovery, or ASR) were simulated by a 3-dimensional, reactive-solute transport model. The Cretaceous aquifer system in the NYC area of New York and New Jersey, USA contains pyrite, goethite, locally occurring siderite, lignite, and locally varying amounts of dissolved Fe and salinity. Sediment from cores drilled on Staten Island and western Long Island had high extractable concentrations of Fe, Mn, and acid volatile sulfides (AVS) plus chromium-reducible sulfides (CRS) and low concentrations of As, Pb, Cd, Cr, Cu and U. Similarly, water samples from the Lloyd aquifer (Cretaceous) in western Long Island generally contained high concentrations of Fe and Mn and low concentrations of other trace elements such as As, Pb, Cd, Cr, Cu and U, all of which were below US Environmental Protection Agency (USEPA) and NY maximum contaminant levels (MCLs). In such aquifer settings, ASR operations can be complicated by the oxidative dissolution of pyrite, low pH, and high concentrations of dissolved Fe in extracted water.The simulated injection of buffered, oxic city water into a hypothetical ASR well increased the hydraulic head at the well, displaced the ambient groundwater, and formed a spheroid of injected water with lower concentrations of Fe, Mn and major ions in water surrounding the ASR well, than in ambient water. Both the dissolved O2 concentrations and the pH of water near the well generally increased in magnitude during the simulated 5-a injection phase. The resultant oxidation of Fe2+ and attendant precipitation of goethite during injection provided a substrate for sorption of dissolved Fe during the 8-a extraction phase. The baseline scenario with a low (0.001M) concentration of pyrite in aquifer sediments, indicated that nearly 190% more water

  12. Environmental impacts of anaerobic digestion and the use of anaerobic residues as soil amendment

    Energy Technology Data Exchange (ETDEWEB)

    Mosey, F.E. [VFA Services Ltd., Herts (United Kingdom)

    1996-01-01

    This paper defines the environmental role of anaerobic digestion within the overall objective of recovering energy from renewable biomass resources. Examples and opportunities for incorporating anaerobic digestion into biomass-to-energy schemes are discussed, together with environmental aspects of anaerobic digestion plants. These include visual, public amenity, pathogens and public health, odor control, and gaseous emissions. Digestate disposal and the benefits of restrictions on recycling organic wastes and biomass residues back to the land are discussed, particularly as they relate to American and European codes of practice and environmental legislation. The paper concludes that anaerobic digestion, if performed in purpose-designed reactors that efficiently recover and use biogas, is an environmentally benign process that can enhance energy recovery and aid the beneficial land use of plant residues in many biomass-to-energy schemes.

  13. Digital data sets that describe aquifer characteristics of the Rush Springs aquifer in western Oklahoma

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set consists of digitized water-level elevation contours for the Rush Springs aquifer in western Oklahoma. This area encompasses all or part of Blaine,...

  14. Digital data sets that describe aquifer characteristics of the Enid isolated terrace aquifer in northwestern Oklahoma

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set consists of digitized polygons of constant hydraulic conductivity values for the Enid isolated terrace aquifer in northwestern Oklahoma. The Enid...

  15. State Aquifer Recharge Atlas Plates, Geographic NAD83, LDEQ (1999) [aquifer_recharge_potential_LDEQ_1988

    Data.gov (United States)

    Louisiana Geographic Information Center — This is a polygon dataset depicting the boundaries of aquifer systems in the state of Louisiana and adjacent areas of Texas, Arkansas and a portion of Mississippi....

  16. Digital data sets that describe aquifer characteristics of the Antlers aquifer in southeastern Oklahoma

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set consists of digitized water-level elevation contours for the Antlers aquifer in southeastern Oklahoma. The Early Cretaceous-age Antlers Sandstone is...

  17. Digital data sets that describe aquifer characteristics of the Enid isolated terrace aquifer in northwestern Oklahoma

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set consists of a digitized polygon of a constant recharge value for the Enid isolated terrace aquifer in northwestern Oklahoma. The Enid isolated terrace...

  18. Digital data sets that describe aquifer characteristics of the Antlers aquifer in southeastern Oklahoma

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set consists of digitized polygons of constant recharge values for the Antlers aquifer in southeastern Oklahoma. The Early Cretaceous-age Antlers...

  19. Digital data sets that describe aquifer characteristics of the High Plains aquifer in western Oklahoma

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set consists of digital polygons of constant recharge rates for the High Plains aquifer in Oklahoma. This area encompasses the panhandle counties of...

  20. Digital data sets that describe aquifer characteristics of the Rush Springs aquifer in western Oklahoma

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set consists of digitized polygons of constant hydraulic conductivity values for the Rush Springs aquifer in western Oklahoma. This area encompasses all...

  1. Digital data sets that describe aquifer characteristics of the Central Oklahoma aquifer in central Oklahoma

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set consists of digitized polygons of a constant recharge value for the Central Oklahoma aquifer in central Oklahoma. This area encompasses all or part of...

  2. Digital data sets that describe aquifer characteristics of the Rush Springs aquifer in western Oklahoma

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set consists of digitized polygons of constant recharge values for the Rush Springs aquifer in western Oklahoma. This area encompasses all or part of...

  3. Aquifer Boundary of the Wood River Valley Aquifer System, South-Central Idaho

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This dataset contains the boundary of the Wood River Valley aquifer system as modified and expanded from that defined by Skinner and others (2007): It has been...

  4. Digital data sets that describe aquifer characteristics of the Central Oklahoma aquifer in central Oklahoma

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set consists of digitized polygons of a constant hydraulic conductivity value for the Central Oklahoma aquifer in central Oklahoma. This area encompasses...

  5. Digital data sets that describe aquifer characteristics of the Central Oklahoma aquifer in central Oklahoma

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set consists of digitized water-level elevation contours for the Central Oklahoma aquifer in central Oklahoma. This area encompasses all or part of...

  6. Digital data sets that describe aquifer characteristics of the High Plains aquifer in western Oklahoma

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set consists of digital polygons of constant hydraulic conductivity values for the High Plains aquifer in Oklahoma. This area encompasses the panhandle...

  7. Digital data sets that describe aquifer characteristics of the High Plains aquifer in western Oklahoma

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set consists of digitized water-level elevation contours for the High Plains aquifer in western Oklahoma. This area encompasses the panhandle counties of...

  8. Digital data sets that describe aquifer characteristics of the Antlers aquifer in southeastern Oklahoma

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This data set consists of digitized polygons of a constant hydraulic conductivity value for the Antlers aquifer in southeastern Oklahoma. The Early Cretaceous-age...

  9. Geochemical evolution and time scale of seawater intrusion into the coastal aquifer of Israel

    International Nuclear Information System (INIS)

    The dynamics of seawater intrusion into a coast is commonly estimated by a rise in salinity and/or by theoretical hydrological models. Estimations using radioactive isotopes are reported only in several works. Here we present an attempt to quantify the geochemical processes and the time scale of seawater intrusion into a coastal aquifer from the changes in the major ions composition of the waters and the natural distribution of the cosmogenic isotopes Carbon 14 and tritium. Saline and brackish groundwaters were sampled from observation and pumping wells in the Israeli coastal aquifer. In addition, detailed profiles across the fresh-saline groundwater interface (resolution of 10 cm) were provided using a Multi Layer Sampler (MLS) that was installed three times in this zone. All groundwater samples were analyzed for their chemical composition, stable carbon and oxygen isotopes, Carbon 14 CDIC in the dissolved inorganic carbon) and tritium activity. The coastal rock was analyzed for its chemical contents and stable and radioactive carbon isotope composition of the carbonate and of the organic matter. The chemical and the stable isotope data revealed three distinct water types (end members) that are placed in different zones in the coastal aquifer: 1. Slightly modified Mediterranean seawater with its salinity (SWS); 2. Slightly diluted (with up to 20% fresh groundwater) saline groundwater (SDS); and 3. Fresh groundwater (FGW). The SWS waters show in most cases excess in total alkalinity and DIC and depletion in Carbon 13 and Carbon 14 C with respect to normal seawater, indicating that anaerobic oxidation of organic matter is the first diagenetic reaction that affect seawater during its penetration into the bottom sediments. Later on, the SWS waters dilutes, gain Ca 2+ and Sr 2+ and deplete in K+ suggesting that mixing with fresh water and cation exchange are the main diagenetic processes that transforms SWS into SDS. At the fresh-saline water interface, SDS waters show

  10. Effects of microbially induced transformations and shift in bacterial community on arsenic mobility in arsenic-rich deep aquifer sediments.

    Science.gov (United States)

    Das, Suvendu; Liu, Chia-Chuan; Jean, Jiin-Shuh; Lee, Chuan-Chun; Yang, Huai-Jen

    2016-06-01

    Elevated concentration of arsenic (As) prevailed in deep aquifers of Chianan Plain, Taiwan. Arsenic release in relation to microbially induced transformations and shift in bacterial communities in deep aquifer sediments of Budai, southwestern Taiwan were investigated using microcosm experiments and substrate amendments over 90 days of anaerobic incubation. The results revealed that As reduction was independent of Fe reduction and a modest rate of sedimentary As release into aqueous phase occurred at the expense of the native organic carbon. Addition of lactate resulted in a parallel increase in As(III) (3.7-fold), Fe(II) (6.2-fold) and Mn (3.5 fold) in aqueous phase compared to un-amended slurries and the enrichment of sequences related to mostly Bacillus, Flavisolibacter, and Geobacter spp, suggesting the important role of these bacteria in As enrichment through reductive dissolution of As-bearing Fe and Mn minerals. The increase in phosphate-extractable As in solid phase with concomitant rise in As in aqueous phase over the course of incubation further attested to the importance of reductive dissolution in promoting As release. Furthermore, the increase in arrA gene abundance with addition of labile carbon suggests that dissimilatory As reduction also may contribute to As enrichment in the water of the deep aquifer of Budai. PMID:26897570

  11. A simple and sensitive quality control method of the anaerobic atmosphere for identification and antimicrobial susceptibility testing of anaerobic bacteria

    DEFF Research Database (Denmark)

    Justesen, Tage; Justesen, Ulrik Stenz

    2013-01-01

    The maintenance of a strict anaerobic atmosphere is essential for the culture of strict anaerobic bacteria. We describe a simple and sensitive quality control method of the anaerobic atmosphere, based on the measurement of the zone diameter around a 5-μg metronidazole disk when testing an...

  12. Anaerobic membrane bioreactors: Are membranes really necessary?

    NARCIS (Netherlands)

    Davila, M.; Kassab, G.; Klapwijk, A.; Lier, van J.B.

    2008-01-01

    Membranes themselves represent a significant cost for the full scale application of anaerobic membrane bioreactors (AnMBR). The possibility of operating an AnMBR with a self-forming dynamic membrane generated by the substances present in the reactor liquor would translate into an important saving. A

  13. Applications of the anaerobic digestion process

    DEFF Research Database (Denmark)

    Angelidaki, Irini; Ellegaard, L.; Ahring, Birgitte Kiær

    2003-01-01

    and resource/energy recovery have been developed. Treatment of biowastes by anaerobic digestion processes is in many cases the optimal way to convert organic waste into useful products such as energy (in the form of biogas) and a fertilizer product. Other waste management options, such as land filling...

  14. Analysis of denitrification in swine anaerobic lagoons

    Science.gov (United States)

    Anaerobic lagoons are a common management practice for the treatment of swine wastewater. Although these lagoons were once thought to be relatively simple; their physical, chemical, and biological processes are actually very sophisticated. To get a better understanding of the processes which occur i...

  15. Anaerobic work capacity in elite wheelchair athletes

    NARCIS (Netherlands)

    van der Woude, L H; Bakker, W H; Elkhuizen, J W; Veeger, DirkJan (H. E. J.); Gwinn, T

    1997-01-01

    To study the anaerobic work capacity in wheelchair athletes, 67 elite wheelchair athletes (50 male) were studied in a 30-second sprint test on a computer-controlled wheelchair ergometer during the World Championships and Games for the Disabled in Assen (1990). The experimental set-up (ergometer, pro

  16. Anaerobic effluent disinfection using ozone: Byproducts formation

    NARCIS (Netherlands)

    Silva, G.H.R.; Daniel, L.A.; Bruning, H.; Rulkens, W.H.

    2010-01-01

    This research was aimed at studying oxidation processes, coliform inactivation effectiveness and disinfection byproducts (DBPs) associated with the disinfection of anaerobic sanitary wastewater effluent with ozone applied at doses of 5.0, 8.0 and 10.0mg O(3)L(-1) for contact times of 5, 10 and 15 mi

  17. Anaerobic hydrolysis during digestion of complex substrates

    NARCIS (Netherlands)

    Sanders, W.T.M.

    2001-01-01

    Complex waste(water) such as, raw sewage, dairy wastewater, slaughterhouse wastewater, fish processing wastewater, primary sludge and the organic fraction of municipal solid waste have been proven to be degradable under anaerobic conditions. However, during the digestion process the conversion of th

  18. Sulfate-reducing bacteria in anaerobic bioreactors.

    NARCIS (Netherlands)

    Oude Elferink, S.J.W.H.

    1998-01-01

    The treatment of industrial wastewaters containing high amounts of easily degradable organic compounds in anaerobic bioreactors is a well-established process. Similarly, wastewaters which in addition to organic compounds also contain sulfate can be treated in this way. For a long time, the occurrenc

  19. Anaerobic digestion in sustainable biomass chains

    NARCIS (Netherlands)

    Pabon Pereira, C.P.

    2009-01-01

    This thesis evaluates the potential contribution of anaerobic digestion (AD) to the sustainability of biomass chains. Results provide insights in the technological potential to recover energy and valuable by-products from energy crops and residues, and evaluate biomass cascades involving AD technolo

  20. Anaerobic digestion of slaughterhouse by-products

    DEFF Research Database (Denmark)

    Hejnfelt, Anette; Angelidaki, Irini

    2009-01-01

    Anaerobic digestion of animal by-products was investigated in batch and semi-continuously fed, reactor experiments at 55 degrees C and for some experiments also at 37 degrees C. Separate or mixed by-products from pigs were tested. The methane potential measured by batch assays for meat- and bone...