Australia's tyranny of distance in oil spill response

International Nuclear Information System (INIS)

Lipscombe, Ray

2000-01-01

In view of the quantity of oil spilled, smaller spills generally receive less attention than headline grabbing incidents such as the 'Amoco Cadiz', 'Exxon Valdez', 'Braer' and 'Sea Empress'. The latter incidents involve the loss of significant quantities of oil, the establishment of relatively complex spill response management structures and the involvement of significant numbers of personnel and equipment. As such, large spills from tankers have the potential to create problem areas, for example in establishing and maintaining effective communications, logistics and resource management systems. In general terms spill response personnel are well aware that large spills come complete with significant operational and administrative problems, however what may not be so well recognised is that smaller spills also have the potential to present response personnel with their own unique problems. One of the major problems to be overcome when responding to spills in Australia is the 'tyranny of distance'. In quite a few responses, Australian oil spill response managers have had to move personnel and equipment thousands of kilometres to provide an effective outcome. This paper outlines a range of problems that have been encountered by Australian personnel over the years. These include health and safety, communications, logistics and equipment issues. For the purpose of this paper a 'smaller' spill has been defined as one involving a discharge of less than 1000 tonnes of oil. (Author)

Amoco-US Environmental Protection Agency, pollution prevention project, Yorktown, Virginia: Surface water data

International Nuclear Information System (INIS)

Baloo, S.

1991-08-01

The report summarizes the surface water sampling program at the Amoco Refinery at Yorktown, Virginia. This was undertaken as a part of the joint project between Amoco Corporation and the United States Environmental Protection Agency to review pollution prevention alternatives at a petroleum refinery. The surface water data provides a snapshot of surface water pollutant generation and discharge from the refinery. Different process units contribute to the total wastewater flow of 460 GPM in the refinery. Water in the ditch system, which is non-process water, is free of organic contamination. Oil and grease, phenols, ammonia and sulfides are the significant components measured in the process wastewater. The concentrations of organics in most water streams leaving the individual process units are relatively low, in the 1-5 parts per million (ppm) range. A few individual streams such as the crude desalter brine and tank water draws have high pollutant loadings. Concentrations of metals in the refinery wastewater are very low. The wastewater treatment plant is very effective in reducing the pollutant loading in the water with overall removal efficiencies greater than 99% for most organics and inorganics

Australia's tyranny of distance in oil spill response

Energy Technology Data Exchange (ETDEWEB)

Lipscombe, Ray [Australian Maritime Safety Authority, Environment Protection Group, Canberra, ACT (Australia)

2000-08-01

In view of the quantity of oil spilled, smaller spills generally receive less attention than headline grabbing incidents such as the 'Amoco Cadiz', 'Exxon Valdez', 'Braer' and 'Sea Empress'. The latter incidents involve the loss of significant quantities of oil, the establishment of relatively complex spill response management structures and the involvement of significant numbers of personnel and equipment. As such, large spills from tankers have the potential to create problem areas, for example in establishing and maintaining effective communications, logistics and resource management systems. In general terms spill response personnel are well aware that large spills come complete with significant operational and administrative problems, however what may not be so well recognised is that smaller spills also have the potential to present response personnel with their own unique problems. One of the major problems to be overcome when responding to spills in Australia is the 'tyranny of distance'. In quite a few responses, Australian oil spill response managers have had to move personnel and equipment thousands of kilometres to provide an effective outcome. This paper outlines a range of problems that have been encountered by Australian personnel over the years. These include health and safety, communications, logistics and equipment issues. For the purpose of this paper a 'smaller' spill has been defined as one involving a discharge of less than 1000 tonnes of oil. (Author)

Oil and chemical spill research and development in the United Kingdom

International Nuclear Information System (INIS)

Goodman, C.

1992-01-01

The Marine Pollution Control Unit (MPCU) falls within the UK Department of Transport's Marine Directorate and is the lead agency in the UK for the control of marine pollution. The MPCU assumes central government's responsibility for controlling two aspects of marine pollution: at sea response to oil and chemical spills from ships, and coordinating beach cleaning activities. All research funded by the MPCU is therefore directed at these two responsibilities. The MPCU was established in 1978 after a series of major tanker incidents in European waters (notably the AMOCO CADIZ, France) in recognition of the fact that it was not reasonable to expect the owners of tankers which operate on a world-wide basis to make arrangements for dealing with oil spills wherever they may occur. The UK Government therefore decided to set up a response unit, the MPCU, with specific responsibilities for dealing with oil and chemical spills from ships at sea. The responsibility for dealing with pollution once it comes ashore lies with the local authorities. However, to avoid expenditure by individual authorities on specialized equipment which will be rarely required, the government decided to set up stockpiles of such equipment in strategic locations to be drawn on by authorities as and when necessary. The government also provides training in the use of this equipment, offers scientific and technical advice and, for major spills, will coordinate beach cleaning activities

Sediments as indicators of artificial radionuclide distribution west of La Hague

International Nuclear Information System (INIS)

Guegueniat, P.; Auffret, J.P.; Ballada, J.

1981-01-01

Four-year investigations of the coastal surface sediments and associated radionuclides in the English Channel show complex distribution patterns around La Hague. Plutonium ratios in the particulate fraction confirm the general understanding gathered from long-term gamma studies - mainly that accumulation of La Hague generated radionuclides is in the Bay of Mont-Saint-Michel and along the Normandy-Brittany Coast. The oil from the Amoco Cadiz accident caused a significant increase in coastal sediment activity of 144 Ce. Experimental studies with plutonium and hydrocarbons indicate that plutonium is more difficult to desorb than 144 Ce. (author)

California’s Groundwater Regime: The Cadiz Case

Directory of Open Access Journals (Sweden)

Julia Sizek

2018-01-01

Full Text Available Recent California legislation has promised solutions to longstanding problems in groundwater management through an emphasis on management of groundwater itself, rather than on the rights of overlying property owners. In this short communication, I argue that the promises of scientific management relies on property law and jurisdiction and therefore that scientific claims about the water itself are less important than private property claims in the case of a Cadiz Inc.’s proposed groundwater extraction project in Southeastern California. While private property in land insulates Cadiz Inc. (Los Angeles, CA, USA from political contestation, opposition to the project has increasingly focused on the right to transport and transfer water through lands not held by Cadiz Inc. This legal strategy points to how California groundwater law is still fundamentally ruled by private property in land, which shifts the grounds of environmental politics from extraction itself to the transport of extracted materials. This case serves as a good example of the intersection of political ecology and legal geography.

Comparison of the reorganisations of BP and Shell and possible opportunities for Middle East and North African Oil companies

Energy Technology Data Exchange (ETDEWEB)

Jenkins, Gilbert

1999-07-01

A critical analysis is provided of the recent reorganisations of the downstream and petrochemical activities of BP and Shell. BP (or BP Amoco including Arco) and Shell are preparing for the next decade anticipating the environment and changing the companies to maximise their profitability in that environment. For the oil producing countries of the Middle East and North Africa (MENA), there are lessons to be learned both from the forecasts which BP Amoco and Shell are making and from the way these companies intend to operate. BP Amoco's view of oil refining is that the surplus capacity is endemic; Shell's view is that it is transient. BP Amoco will market oil products selectively across the world; Shell is still intent on a global approach. Both BP Amoco and Shell will minimise their wholesaling activities in the retail market and expand their merchandising with ever better quality sites. In the petrochemicals sector, the companies are taking similar actions, ie concentrating on positions of strength and selling business activities with low market shares or poor profitability. Petrochemical sites will be favoured when they have access to company produced hydrocarbon feedstocks. From the analysis, it is suggested that MENA oil companies will need to consider carefully the timing of any new refinery building. The reorganisation of the major OECD-based oil companies should offer opportunities for MENA companies to secure outlets for LPG and condensates, to form marketing alliances in OECD markets and to become involved in OECD-based petrochemical businesses.

Comparison of the reorganisations of BP and Shell and possible opportunities for Middle East and North African Oil companies

International Nuclear Information System (INIS)

Jenkins, Gilbert

1999-01-01

A critical analysis is provided of the recent reorganisations of the downstream and petrochemical activities of BP and Shell. BP (or BP Amoco including Arco) and Shell are preparing for the next decade anticipating the environment and changing the companies to maximise their profitability in that environment. For the oil producing countries of the Middle East and North Africa (MENA), there are lessons to be learned both from the forecasts which BP Amoco and Shell are making and from the way these companies intend to operate. BP Amoco's view of oil refining is that the surplus capacity is endemic; Shell's view is that it is transient. BP Amoco will market oil products selectively across the world; Shell is still intent on a global approach. Both BP Amoco and Shell will minimise their wholesaling activities in the retail market and expand their merchandising with ever better quality sites. In the petrochemicals sector, the companies are taking similar actions, ie concentrating on positions of strength and selling business activities with low market shares or poor profitability. Petrochemical sites will be favoured when they have access to company produced hydrocarbon feedstocks. From the analysis, it is suggested that MENA oil companies will need to consider carefully the timing of any new refinery building. The reorganisation of the major OECD-based oil companies should offer opportunities for MENA companies to secure outlets for LPG and condensates, to form marketing alliances in OECD markets and to become involved in OECD-based petrochemical businesses

Amoco-US Environmental Protection Agency, pollution prevention project, Yorktown, Virginia: Project peer review. Report of the Peer Review Committee of the Amoco/EPA Pollution Prevention Project at the Yorktown, Virginia refinery

International Nuclear Information System (INIS)

Klee, H.; Podar, M.

1991-01-01

The Amoco/EPA Pollution Prevention Project involved a number of representatives from federal and Virginia regulatory agencies, and Amoco's refining business. Participants believed that the Project could benefit from a broader perspective than these organizations along might provide. The Project Work Group selected an independent Peer Review Process which was conducted by Resource for the Future (RFF), a Washington DC think tank. A group of technical, policy and environmental experts from diverse backgrounds served as Peer Review members. The Peer Review Committee met on three occasions to discuss (1) the Project Work Plan (2) sampling data and interpretation and (3) project conclusions and recommendations. The focus of the meeting was on the general scope and content of the project

Potentially beneficial spill-related effects of chemicals routinely added to crude oils

International Nuclear Information System (INIS)

Ross, S.; Maharaj, S.

1993-01-01

Amoco Trinidad Oil Company produces 60,000 bbl/d of oil from the Trinidadian offshore. The oil is pipelined ashore where it is processed and returned offshore to a buoy mooring for transport up Trinidad's east coast. Amoco Trinidad has developed comprehensive oil spill contingency plans, starting from computer models of spill scenarios. The models used initially assumed that the oils would emulsify quickly and the spills would become highly viscous and persistent, reaching the shoreline in 15-24 h. Such behavior would render ineffective the use of dispersants as a spill countermeasure. Studies showed a poor potential capability of physical recovery systems for spills off the Trinidad east coast due to high sea states, strong winds, and other factors. These results led to questioning of the spill model's assumptions, and laboratory tests were conducted to study the actual behavior of the crude oils. It was found that the oil was difficult to emulsify and highly prone to breakup and dispersion. These surprising results were explained by the presence of surfactants added during processing. A revised modelling exercise showed that if the surfactants stay with the oil, spills up to 100,000 bbl will dissipate in 15 h or less at average wind conditions. To guard against the possibility that the surfactants may not stay with the spilled oil, and to help accelerate dispersion of oil spills, Amoco Trinidad has developed a dispersant-use capacity for its spill contingency plan. It is suggested that additives normally added to crude oils during production and processing in other areas may also be providing spill cleanup benefits similar to those found in the Trinidad case. 9 refs., 1 fig., 4 tabs

Evaluation of stabilization-solidification techniques

International Nuclear Information System (INIS)

Goubier, R.

1989-01-01

This paper reports that among the techniques applied to treat polluting residue in France for the past ten years has been the mixing of pollutants with reactive agents in order to fix the contaminants and to give them a solid consistency. The first applications of these stabilization/solidification processes occurred in 1978 in the treatment of oil residues from the AMOCO CADIZ spill. They have also been used for the treatment of a mayor dump site for petroleum residues, for the disposal of mineral sludges of a detoxication plant, and for the rehabilitation of sites contaminated by various industrial residues, specially acid tars generated by oil refining plants. Although from the beginning these techniques appeared to be able to transform filthy lagoons into solid and apparently safe areas, it was necessary to evaluate their efficiency and to determine the conditions and limits of application

Environmental Assessment/Baseline Survey to Establish New Drop Zone (DZ) in Cadiz, Ohio

Science.gov (United States)

2009-03-01

International Airport LATN Low Altitude Tactical Navigation MACA Military Airspace Collision Avoidance µg/m3 microgram per cubic meter MSL mean...Environmental Assessment and Baseline Survey 3-3 To Establish New Drop Zone in Cadiz, OH The 911 AW has a Military Airspace Collision Avoidance ( MACA ) plan...in Cadiz, OH The 911 AW flight safety would revise their existing MACA plan to include activities at the new drop zone. The MACA includes placing a

Quality of compost from composting plant in Puerto Real (Cadiz, Spain); Calidad del compost procedente de la planta de compostaje de Puerto Real (Cadiz)

Energy Technology Data Exchange (ETDEWEB)

Godillo Romero, M. D.; Quiroga Alonso, J. M.; Garrido Perez, C.; Rodriguez Barros, R.; Sales Marquez, D. [Universidad de Cadiz (Spain)

2000-07-01

The compost taken from the Compost Plant, treating urban solid residues from the Consorcio Bahia de Cadiz in the municipal district of Puerto Real, Cadiz, has been analysed for its particular qualities over the years 1990-1996. With this in mind we have determined the most important of parameters with a view to defining the quality of this organic fertilizer extracted from urban solid residues (USR): pH, conductivity, rejection through net meshing, humidity, organic matter, carbon, nitrogen, C/N relationship, cadmium, copper, nickel, lead, tin, zinc and mercury. The compost gathered complies with the established legal requisites concerning fertilizers and their related substances. The quality in the first years of this study is better due possibly to the construction of the bio-recycling plant leaving the latter as a holding plant. (Author)

Experiences with linear solvers for oil reservoir simulation problems

Energy Technology Data Exchange (ETDEWEB)

Joubert, W.; Janardhan, R. [Los Alamos National Lab., NM (United States); Biswas, D.; Carey, G.

1996-12-31

This talk will focus on practical experiences with iterative linear solver algorithms used in conjunction with Amoco Production Company`s Falcon oil reservoir simulation code. The goal of this study is to determine the best linear solver algorithms for these types of problems. The results of numerical experiments will be presented.

Surface circulation in the Gulf of Cadiz: Model and mean flow structure

Science.gov (United States)

Peliz, Alvaro; Dubert, Jesus; Marchesiello, Patrick; Teles-Machado, Ana

2007-11-01

The mean flow structure of the Gulf of Cadiz is studied using a numerical model. The model consists of a set of one-way nested configurations attaining resolutions on the order of 2.6 km in the region of the Gulf of Cadiz. In the large-scale configuration, the entrainment of the Mediterranean Water is parameterized implicitly through a nudging term. In medium- and small-scale nested configurations, the Mediterranean outflow is introduced explicitly. The model reproduces all the known features of the Azores Current and of the circulation inside the Gulf of Cadiz. A realistic Mediterranean Undercurrent is generated and Meddies develop at proper depths on the southwest tip of the Iberian slope. The hypothesis that the Azores Current may generate in association with the Mediterranean outflow (β-plume theories) is confirmed by the model results. The time-mean flow is dominated by a cyclonic cell generated in the gulf which expands westward and has transports ranging from 4 to 5 Sv. The connection between the cell and the Azores Current is analyzed. At the scale of the Gulf, the time-mean flow cell is composed by the westward Mediterranean Undercurrent, and by a counterflow running eastward over the outer edge of the Mediterranean Undercurrent deeper vein, as the latter is forced downslope. This counterflow feeds the entrainment at the depths of the Mediterranean Undercurrent and the Atlantic inflow at shallower levels. Coastward and upslope of this recirculation cell, a second current running equatorward all the way along the northern part of the gulf is revealed. This current is a very robust model result that promotes continuity between the southwestern Iberian coast and the Strait of Gibraltar, and helps explain many observations and recurrent SST features of the Gulf of Cadiz.

Developments in the strategic planning of the major oil companies

International Nuclear Information System (INIS)

Jenkins, Gilbert

2000-01-01

This paper focuses on the changes in strategic planning of the major oil companies since the 1970s, and considers the reorganisations of the companies, and upstream and downstream planning. New directions for the major companies downstream operation in the retail and aviation sectors, and the influence of the BP/AMOCO/ARCO/BURMAH, EXXON/MOBIL and TOTAL/FINA/ELF mergers on the international oil industry are explored. Tables illustrating the earnings of the major oil companies for upstream and downstream operations, and chemicals in 1999, and for BP UK exploration and production, and refining and marketing profits (quarterly) for 1983-2000 are presented

Tsunamigenic earthquakes in the Gulf of Cadiz: fault model and recurrence

Directory of Open Access Journals (Sweden)

L. M. Matias

2013-01-01

Full Text Available The Gulf of Cadiz, as part of the Azores-Gibraltar plate boundary, is recognized as a potential source of big earthquakes and tsunamis that may affect the bordering countries, as occurred on 1 November 1755. Preparing for the future, Portugal is establishing a national tsunami warning system in which the threat caused by any large-magnitude earthquake in the area is estimated from a comprehensive database of scenarios. In this paper we summarize the knowledge about the active tectonics in the Gulf of Cadiz and integrate the available seismological information in order to propose the generation model of destructive tsunamis to be applied in tsunami warnings. The fault model derived is then used to estimate the recurrence of large earthquakes using the fault slip rates obtained by Cunha et al. (2012 from thin-sheet neotectonic modelling. Finally we evaluate the consistency of seismicity rates derived from historical and instrumental catalogues with the convergence rates between Eurasia and Nubia given by plate kinematic models.

Exploitation of tidal power in the Bay of Cadiz: ancient tidal mills

Directory of Open Access Journals (Sweden)

José J. Alonso del Rosario

2006-03-01

Full Text Available Tidal mills were the main industrial activity in the Bay of Cadiz for centuries. They were the last step in the production of salt and flour made by grinding grains. They were installed along the shallow channels, called “caños”, around the Bay, where the frictional and geometrical effects are very strong. The authors have analyzed the propagation of the semidiurnal tidal waves along the Caño de Sancti Petri and the available tidal power in the area. The ancient tidal mills were located where the available tidal potential energy is highest, which ensured productivity for grinding salt and wheat in ancient times. Some considerations about the possibility of installing tidal power plants in the Bay of Cadiz now are given, which show that it could be a real and renewal alternative source of energy for the area.

Determination of parameter Vs30 using FK and SPAC techniques in the Bahia de Cadiz (South of Espana)

International Nuclear Information System (INIS)

Schmidt Diaz, Victor

2012-01-01

A measurement campaign of ambient vibrations was carried out in April 2008 in the Bahia de Cadiz (southern of Espana). The H / V techniques and array of sensors placed in series have been applied in order to classify soils according to the Vs30 parameter in six nearby towns: Cadiz, Chiclana, Rota, Puerto Real, San Fernando and El Puerto de Santa Maria. The H/V technique has confirmed that in the towns of Cadiz, Chiclana and El Puerto de Santa Maria, the medium is heterogeneous and with horizontal layering which allows to observe the dispersion phenomena. The soil profile in Puerto Real has been horizontal but homogeneous and in Rota and San Fernando have been significant changes in a short distance, according to the differences observed in the H / V obtained in two sites 50 m apart, therefore the profile is without be horizontal. The array technique in series has showed clear definition of dispersion curve and well defined soil profile (models with less error) in Cadiz, Chiclana and El puerto de Santa Maria but the results are inconclusive for Rota and San Fernando, due to unclear dispersion curves obtained. In general, the soil types that predominate in the area can be classified as B and C according to Eurocode 8, based on the values of Vs30 obtained using FK and SPAC techniques. (author) [es

The Erika tanker shipwreck, one year later. synthesis; Naufrage du petrolier Erika, un an apres. synthese

Energy Technology Data Exchange (ETDEWEB)

NONE

2000-12-01

In december 1999 the Erika tanker shipwreck broke along the Brittany coast leading to the most important sea pollution by hydrocarbons, since the Amoco-Cadiz. One year after this accident the Ministry of the territory management and of the environment takes stock on the actions carried on after the shipwreck: the management of the POLMAR fund, the shoreline cleaning, the land and water ecosystems restoration, the wastes storage and processing, the ecological consequences. A special part is devoted to the maritime transport regulations and safety and to the victims compensation. (A.L.B.)

1984 CRC (Coordinating Research Council, Inc.) Octane Number Requirement Rating Workshop.

Science.gov (United States)

1985-06-01

Richard J . Tither Mobil Oil Corporation Sam D. Vallas Amoco Oil Company Douglas A. Voss Chevron Research Company Andy Vukovic Shell Canada Dave G...Instrumentation, * Preparation a Test Fuels: Procurement of Fuels and Cans, and Coordina- tion of On-Site Handling e Data Handling and Analysis j 2 nI |S 0- B-2 V...Doug McCorkell Union Oil Company of California James D. Merritt Amoco Oil Company Michael J . Mlotkowski Mobil Oil Corporation John Pandosh Sun Tech

A slumbering beast

International Nuclear Information System (INIS)

Koch, G.

1995-01-01

Amoco Canada's bid to buy out Home Oil Co. Ltd., produced allegations against Amoco's position in the natural gas liquids (NGL) business, accusing it of monopolistic and obstructionist tactics which stifle competition. The charges were levelled by the president of Kinetic Resources, a subsidiary of PanCanadian Petroleum, and one of Amoco's main competitors. According to the charge Amoco, which owns or operates many of the fractionation and storage facilities , refused to ship other producer's NGL for a fair fee, forcing these producers without fractionation facilities of their own into selling their NGL to Amoco, thus significantly lessening competition . Amoco denied it engaged in unfair business practices. 2 ills

Dosages d'hydrocarbures dans l'eau et le sédiment marins par infrarouge et chromatographie gazeuse sur colonne capillaire Hydrocarbon Titration in Water and Marine Sediments by Infrared Analysis and Gas Chromatography in a Capillary Column

Directory of Open Access Journals (Sweden)

Morel G.

2006-11-01

Full Text Available Nous avons étudié l'évolution des hydrocarbures pétroliers dans un site confiné, celui de l'Aber-Benoît (Finistère, à la suite de l'accident du super-pétrolier Amoco-Cadiz en mars 1978. Pour ce faire, plusieurs méthodes ont été mises en oeuvre, et tout particulièrement la chromato-graphie gazeuse sur colonne capillaire : le protocole analytique est décrit pour l'eau et pour le sédiment, après optimisation des techniques de filtration, de préconcentration et de fractionnement préalables à la mesure. Il est possible de travailler sur des échantillons de deux litres d'eau de mer ou de cinquante grammes de sédiment, avec des seuils de détection du niveau de la partie par trillion (ppt dans l'eau et de la centaine de ppt dans le sédiment. The evolution of petroleum hydrocarbons was analyzed in a confined site, at Aber-Benoît in the Finistère department, following the accident of the supertanker Amoco Cadiz in March 1978. To do this, several methods were developed, including, in particular, capillary coulumn as chromatography. The analytical procedure is described for water and sediment after optimization of filtering, preconcentrating and fractionating techniques prior to measuring. Analyses can be made with two liters of seawater or fifty grams of sediment, with detection thresholds in parts per trillion (ppt in water and the hundredth of a ppt in sediment.

Thrust-wrench interference tectonics in the Gulf of Cadiz (Africa-Iberia plate boundary in the North-East Atlantic): Insights from analog models

OpenAIRE

Duarte , João ,; Rosas , Filipe ,; Terrinha , Pedro; Gutscher , Marc-André ,; Malavielle , Jacques; Silva , Sonia; Matias , Luis

2011-01-01

International audience; In the Gulf of Cadiz key segment of the Africa-Iberia plate boundary (North-East Atlantic ocean), three main different modes of tectonic interference between a recently identified wrench system (SWIM) and the Gulf of Cadiz Accretionary Wedge (GCAW) were tested through analog sand-box modeling: a) An active accretionary wedge on top of a pre-existent inactive basement fault; b) An active strike-slip fault cutting a previously formed, inactive, accretionary wedge; and c)...

The experience of western oil companies in Russia

International Nuclear Information System (INIS)

Moerland, A.

1994-01-01

The oil and gas industry is the most important industry to Russia providing 52% of all hard currency earnings for the country. The oil production is declining by more than 30% during recent years from 10.3 billion barrels per day in 1990 to 7.1 billion barrels today. The paper discusses the Amoco engagement in the Priobskoye Field in western Siberia containing up to 5 billion barrels of recoverable oil requiring capital investments of more than 25 billion dollars over the first 20 years. Over the last five years, foreign companies have worked with their Russian counterparts to complete numerous feasibility studies on many projects. In the next few months, important developments may take place such as the offshore Sakhalin in the East and the Timan Pechora region in the North. The experienced barriers connected to the activities, burden of taxes, policy issues etc., are dealt with

The experience of western oil companies in Russia

Energy Technology Data Exchange (ETDEWEB)

Moerland, A. [Amoco Erusia Petroleum Co., Moscow (Russian Federation)

1994-12-31

The oil and gas industry is the most important industry to Russia providing 52% of all hard currency earnings for the country. The oil production is declining by more than 30% during recent years from 10.3 billion barrels per day in 1990 to 7.1 billion barrels today. The paper discusses the Amoco engagement in the Priobskoye Field in western Siberia containing up to 5 billion barrels of recoverable oil requiring capital investments of more than 25 billion dollars over the first 20 years. Over the last five years, foreign companies have worked with their Russian counterparts to complete numerous feasibility studies on many projects. In the next few months, important developments may take place such as the offshore Sakhalin in the East and the Timan Pechora region in the North. The experienced barriers connected to the activities, burden of taxes, policy issues etc., are dealt with

Origin of Fluids and Salts at Mercator Mud Vulcano, Gulf of Cadiz

OpenAIRE

Katja Heeschen; M. Haeckel; C. Berndt; D. Teagle; M. Palmer; D. Green; M. Cooper; H. Vaneste; V. Liebetrau

2008-01-01

The Gulf of Cadiz is located at the plate boundary between the Eurasian and African plates and is characterized by widespread mud volcanism all along the continental margins. It is commonly believed that this results from sediment dewatering enhanced by the compressional forces within the accretionary prism. Recently, 3D seismic data and geochemical sediment cores indicated that in addition to compressional tectonics, halokinesis controls the location and dynamics of the Mercator mud volca...

It only hurts when you produce : ten years of federal/provincial conflict over oil industry revenue sharing

International Nuclear Information System (INIS)

Smith, D.C.

1998-01-01

This book presents a collection of more than 300 cartoons which were published in 'Oilweek Magazine' between February 1973 and 1983. For the oil industry, this decade represented a time of increased provincial royalties and rising federal taxation. The cartoons depict the ongoing federal-provincial conflict over oil industry revenue sharing. The implication of the title is that while federal and provincial governments each determined the oil industry to be their own golden goose, the goose concluded that future demands for golden eggs would be painful to satisfy. At the time, the cartoons were submitted anonymously, but were well received by 'Oilweek' readers. In 1986, Amoco Regional Petroleum Engineering Supervisor Don Smith, revealed that he was the anonymous artist

Chemosymbiotic species from the Gulf of Cadiz (NE Atlantic: distribution, life styles and nutritional patterns

Directory of Open Access Journals (Sweden)

C. F. Rodrigues

2013-04-01

Full Text Available Previous work in the mud volcanoes from the Gulf of Cadiz (South Iberian Margin revealed a high number of chemosymbiotic species, namely bivalves and siboglinid polychaetes. In this study we give an overview of the distribution and life styles of these species in the Gulf of Cadiz, determine the role of autotrophic symbionts in the nutrition of selected species using stable isotope analyses (δ13C, δ15N and δ34S and investigate the intra-specific variation of isotope signatures within and between study sites. During our studies, we identified twenty siboglinidae and nine bivalve chemosymbiotic species living in fifteen mud volcanoes. Solemyid bivalves and tubeworms of the genus Siboglinum are widespread in the study area, whereas other species were found in a single mud volcano (e.g. "Bathymodiolus" mauritanicus or restricted to deeper mud volcanoes (e.g. Polybrachia sp., Lamelisabella denticulata. Species distribution suggests that different species may adjust their position within the sediment according to their particular needs, and to the intensity and variability of the chemical substrata supply. Tissue stable isotope signatures for selected species are in accordance with values found in other studies, with thiotrophy as the dominant nutritional pathway, and with methanotrophy and mixotrophy emerging as secondary strategies. The heterogeneity in terms of nutrient sources (expressed in the high variance of nitrogen and sulphur values and the ability to exploit different resources by the different species may explain the high diversity of chemosymbiotic species found in the Gulf of Cadiz. This study increases the knowledge on distributional patterns and resource partitioning of chemosymbiotic species and highlights how trophic fuelling varies on spatial scales with direct implications to seep assemblages and potentially to the biodiversity of continental margin.

Size and profitability in the international oil- and gas industry

International Nuclear Information System (INIS)

Osmundsen, Petter; Mohn, Klaus; Espedal, Harald; Loevaas, Kjell

2002-01-01

Many industrial sectors have gone through a series of mergers and acquisitions. In the international oil- and gas industry this has produced new companies such as ExxonMobil and TotalFinaElf. BP and Amoco merged and then subjugated Atlantic Richfield (ARCO). ChevronTexaco has been established and ConocoPhillips are currently working on the same thing. Saga was previously acquired by Norsk Hydro and Statoil, and Shell recently bought Enterprise and Pennzoil-Quaker. Taking the stock market's principles for corporate analysis and valuation as a starting point, this article discusses the forces behind this consolidation process

Audit of cataract surgery in Cadiz: visual outcomes and complications.

Science.gov (United States)

Royo-Dujardin, L; Alcalde-Vílchez, E; Rodríguez-de la Rúa, E; Novalbos-Ruiz, J P

2018-06-01

To publish the outcomes and complications of age-related cataract surgery in Cadiz (Spain). Due to the lack of national audits, a comparison was made between the results obtained here and those of the most recent European audit, EUREQUO (2013), and the British audit RCOphth NOD (2015). A prospective, longitudinal, before-after study of 312 patients undergoing cataract surgery in the University Hospitals of Puerta del Mar and Puerto Real (Cadiz), in 2013-14. Outcome measurements included sociodemographic characteristics, visual acuity (VA), symptoms secondary to cataract, ocular comorbidity, waiting time, expertise of surgeon (consultant vs. trainee), rate and type of surgical complications. The median age at surgery was 73.92±7.31. Almost all (98.3%) of patients at consultation had a VA ≥0.60logMAR, with a mean pre-surgical VA of 1.01logMAR (0.92-1.10). There was a 6.7% complication rate, with 3.8% posterior capsule ruptures and 2.8% corneal decompensations. No cases of endophthalmitis occurred. The mean post-operative VA was 0.28logMAR (0.22-0.33). More than three-quarters (78.8%) of cases achieved a post-operative VA ≤0.3logMAR, and 27.6% of cases achieved a VA ≤0.0logMAR. Our success rate was inferior to the EUREQUO and RCOphth NOD studies, with the percentage of patients acquiring a postoperative VA ≤0.3logMAR being 98% and 89%, respectively. However, the populations were not comparable. It is hoped that this study will encourage other public hospitals in Spain to undertake audits and share their results, in order to provide a tool for constructive criticism and quality improvement initiatives. Copyright © 2018 Sociedad Española de Oftalmología. All rights reserved.

Chemosynthetic bacteria found in bivalve species from mud volcanoes of the Gulf of Cadiz.

Science.gov (United States)

Rodrigues, Clara F; Webster, Gordon; Cunha, Marina R; Duperron, Sébastien; Weightman, Andrew J

2010-09-01

As in other cold seeps, the dominant bivalves in mud volcanoes (MV) from the Gulf of Cadiz are macrofauna belonging to the families Solemyidae (Acharax sp., Petrasma sp.), Lucinidae (Lucinoma sp.), Thyasiridae (Thyasira vulcolutre) and Mytilidae (Bathymodiolus mauritanicus). The delta(13)C values measured in solemyid, lucinid and thyasirid specimens support the hypothesis of thiotrophic nutrition, whereas isotopic signatures of B. mauritanicus suggest methanotrophic nutrition. The indication by stable isotope analysis that chemosynthetic bacteria make a substantial contribution to the nutrition of the bivalves led us to investigate their associated bacteria and their phylogenetic relationships based on comparative 16S rRNA gene sequence analysis. PCR-denaturing gradient gel electrophoresis analysis and cloning of bacterial 16S rRNA-encoding genes confirmed the presence of sulfide-oxidizing symbionts within gill tissues of many of the studied specimens. Phylogenetic analysis of bacterial 16S rRNA gene sequences demonstrated that most bacteria were related to known sulfide-oxidizing endosymbionts found in other deep-sea chemosynthetic environments, with the co-occurrence of methane-oxidizing symbionts in Bathymodiolus specimens. This study confirms the presence of several chemosynthetic bivalves in the Gulf of Cadiz and further highlights the importance of sulfide- and methane-oxidizing symbionts in the trophic ecology of macrobenthic communities in MV.

Molecular and carbon isotopic variability of hydrocarbon gases from mud volcanos in the Gulf of Cadiz, NE Atlantic.

NARCIS (Netherlands)

Stadnitskaia, A.; Ivanov, M.K.; Blinova, V.; Kreulen, R.; van Weering, T.C.E.

2006-01-01

Investigations of molecular and carbon isotopic variability of hydrocarbon gases from methane through butanes (pentanes) have been performed on six mud volcanoes from two fluid venting provinces located in the Gulf of Cadiz, NE Atlantic. The main aims were to define the basic gas types, to describe

Meddy Interaction With A Deep Cyclone In The Gulf of Cadiz

Science.gov (United States)

Carton, Xavier; Cherubin, Laurent

Hydrological measurements made in July 1999 in the Gulf of Cadiz reveal the presence of two meddies, one south of Cape Saint Vincent, the other one near the Moroccan shelf and their interaction with a deep cyclone. The thermohaline anomalies of the meddies reach 60-70 km diameter, and are concentrated between 750 and 1500m depths; they reach 2C and 0.5 in salinity. The cyclone is shallower (between 600 and 1300m) with a weaker signature of Mediterranean water (12C at 800m, 36.2 in salinity between 800 and 1200m). This cyclone is coupled with one of the meddies as a baroclinic dipole. This dipole tears a long warm and salty filament away from the other meddy at 1200m. The long term evolution of these eddies is described by means of deep-drogued drifting buoy trajectories: the isolated meddy drifts southwestward, the dipole remains coherent while moving along the continental shelf until it reaches Cape Saint Vincent where it splits. A three-layer quasi-geostrophic model is used to evaluate the possible origin of the meddy and cyclone near the Portuguese coast, and to assess if their interactions, both mutual, with the domain boundaries, and with bottom topography, can account for their motion and deformation. L. Cherubin, X. Carton, J. Paillet, Y. Morel, A. Serpette, 2000: "Instability of the Mediterranean water undercurrents southwest of Portugal: effects of baroclinicity and of topography", Oceanologica Acta, 23, 551-573. X. Carton, L. Cherubin, J. Paillet, Y. Morel, A. Serpette, B. Le Cann, 2002: "Meddy coupling with a deep cyclone in the Gulf of Cadiz ". To appear in J. Mar. Syst.

Cold-water coral mounds on the Pen Duick Escarpment, Gulf of Cadiz: The MiCROSYSTEMS project approach

NARCIS (Netherlands)

Van Rooij, D.; Blamart, D.; De Mol, L.; Mienis, F.; Pirlet, H.; Wehrmann, L. M.; Barbieri, R.; Maignien, L.; Templer, S. P.; de Haas, H.; Hebbeln, D.; Frank, N.; Larmagnat, S.; Stadnitskaia, A.; Stivaletta, N.; van Weering, T.; Zhang, Y.; Hamoumi, N.; Cnudde, V.; Duyck, P.; Henriet, J.-P.; The MiCROSYSTEMS MD 169 Shipboard Party

2011-01-01

Here we present a case study of three cold-water coral mounds in a juvenile growth stage on top of the Pen Duick Escarpment in the Gulf of Cadiz; Alpha, Beta and Gamma mounds. Although cold-water corals are a common feature on the adjacent cliffs, mud volcanoes and open slope, no actual living

Religious Intolerance in the Cortes of Cadiz

Directory of Open Access Journals (Sweden)

Juan Pablo Domínguez

2017-05-01

Full Text Available In recent years there has been no shortage of studies on religious intolerance in the Cadiz Cortes, but many of them are burdened by two critical errors. The first one is to focus the arguments on article 12 of the Constitution, without paying attention to other parliamentary debates in which the intolerant policy of the Cortes was more clearly expounded. The second common mistake is to ignore the circumstances which prevented some deputies from freely speaking their minds on religious matters. Through a detailed analysis of the proceedings of the Cortes, as well as other sources of the period, this article is intended to remedy both shortcomings, and thus to question certain common assumptions in current historiography. This approach leads to the conclusion that, while some deputies may had hidden his penchant for freedom of conscience, the decrees and speeches of the Cortes were more intolerant than many suppose. Not only they ordered to punish all dissenters from the Church's doctrines, but they decreed death penalty for anyone who dared to suggest the introduction of religious freedom in Spain.

Cadiz, Jamaica or London? The British colony at Cadiz and the changes of English trade with Spanish America (1655-1750 ¿Cádiz, Jamaica o Londres? La colonia británica de Cádiz y las transformaciones del comercio inglés con la América española (1655-1750

Directory of Open Access Journals (Sweden)

José Ignacio Martínez Ruiz

2012-03-01

Full Text Available Neither the exchanges through Jamaica, which had been seized from Spain in 1655, nor the privileges enjoyed by the South Sea Company as the result of the Tratado del Asiento from 1713 onwards entailed the decadence of the British merchant colony at Cadiz in the late seventeenth and early eighteenth centuries. In order to explain this apparent paradox, the article analyses the contribution of the Cadiz Factory to British imperial and commercial expansion in a period characterised by the strengthening of the ties between the Atlantic, Mediterranean and Asian worlds.Ni los intercambios realizados a través de Jamaica, conquistada a España en 1655, ni los privilegios disfrutados por la Compañía del Mar del Sur en virtud del Tratado del Asiento a partir de 1713 conllevaron la decadencia de la colonia mercantil británica de Cádiz a finales del siglo XVII y comienzos del siglo XVIII. Con objeto de explicar esta aparente paradoja, el artículo analiza la forma en que la Cadiz Factory contribuyó a la expansión comercial e imperial británica en un periodo caracterizado por el reforzamiento de los lazos entre los mundos atlántico, mediterráneo y asiático.

Chemosymbiotic bivalves from the mud volcanoes of the Gulf of Cadiz, NE Atlantic, with descriptions of new species of Solemyidae, Lucinidae and Vesicomyidae.

Science.gov (United States)

Olive, Graham; Rodrigues, Clara F; Cunha, Marina R

2011-01-01

The chemosymbiotic bivalves collected from the mud volcanoes of the Gulf of Cadiz are reviewed. Of the thirteen species closely associated with chemosynthetic settings two Solemyidae, Solemya (Petrasma) elarraichensissp. n. and Acharax gadiraesp. n., one Lucinidae, Lucinoma asapheussp. n., and one Vesicomyidae, Isorropodon megadesmussp. n. are described and compared to close relatives of their respective families. The biodiversity and distribution of the chemosymbiotic bivalves in the Gulf of Cadiz are discussed and compared to the available information from other cold seeps in the Eastern Atlantic and Mediterranean. Although there is considerable similarity at the genus level between seep/mud volcano fields in the Eastern Atlantic and Mediterranean, there is little overlap at the species level. This indicates a high degree of endemism within chemosymbiotic bivalve assemblages.

Interaction of tectonic and depositional processes that control the evolution of the Iberian Gulf of Cadiz margin

Science.gov (United States)

Maldonado, A.; Nelson, C.H.

1999-01-01

This study provides an integrated view of the growth patterns and factors that controlled the evolution of the Gulf of Cadiz continental margin based on studies of the tectonic, sedimentologic and oceanographic history of the area. Seven sedimentary regimes are identified, but there are more extensive descriptions of the late Cenozoic regimes because of the larger data base. The regimes of the Mesozoic passive margin include carbonate platforms, which become mixed calcareous-terrigenous deposits during the Late Cretaceous-early Tertiary. The Oligocene and Early Miocene terrigenous regimes developed, in contrast, over the active and transcurrent margins near the African-Iberian plate boundary. The top of the Gulf of Cadiz olistostrome, emplaced in the Late Miocene, is used as a key horizon to define the 'post-orogenic' depositional regimes. The Late Miocene progradational margin regime is characterized by a large terrigenous sediment supply to the margin and coincides with the closing of the Miocene Atlantic-Mediterranean gateways. The terrigenous drift depositional regime of the Early Pliocene resulted from the occurrence of high eustatic sea level and the characteristics of the Mediterranean outflow currents that developed after the opening of the Strait of Gibraltar. The Late Pliocene and Quaternary regimes are dominated by sequences of deposits related to cycles of high and low sea levels. Deposition of shelf-margin deltas and slope wedges correlate with regressive and low sea level regimes caused by eustasy and subsidence. During the highstand regimes of the Holocene, inner shelf prograding deltas and deep-water sediment drifts were developed under the influence of the Atlantic inflow and Mediterranean outflow currents, respectively. A modern human cultural regime began 2000 years ago with the Roman occupation of Iberia; human cultural effects on sedimentary regimes may have equalled natural factors such as climate change. Interplay of tectonic and

Distribution of butyltins (TBT, DBT, MBT) in sediments of Gulf of Cadiz (Spain) and its bioaccumulation in the clam Ruditapes philippinarum

Digital Repository Service at National Institute of Oceanography (India)

Garg, A.; Anton-Martin, R.; Garcia-Luque, E.; Riba, I.; DelValls, T.A.

Surface sediment samples were analyzed for organotins namely tributyltin (TBT), dibutyltin and monobutyltin from six areas located in the Gulf of Cadiz (14 stations), Spain. The total butyltin ranged between undetected and 1,580 ng Sn g sup(-1). TBT...

Developing our resources doesn't have to cost us the Earth

International Nuclear Information System (INIS)

Century, J.R.; Wonfor, J.; Fuenning, P.; Hewitt, T. Jr.; Tenant, R.; Breiteneder, M.

1991-01-01

The Environmental Geology Division of the CSPG was organized in 1990 to promote the study, evaluation, and protection of the environment as it related to geology and the earth sciences. Since the problems range from local to global, a pragmatic approach to activities was adopted, matching professional strengths with our environmental concerns. The following standing committees were formed with specific priority projects underway: (1) scientific measurements of global change, (2) environmental protection solutions, (3) environmental effects of recent geological processes, (4) monitoring global changes by remote sensing, and (5) economic and environmental energy rationalization. Examples of the effects of man-made and naturally occurring events are best illustrated through remote sensing images. The Amoco Cadiz major oil spill of 1978 off the Brittany coast and a 1977 winter Chinook in the Calgary region are contrasts in change. Land reclamation of coal mines in the Grand Cache area of the Alberta Foothills illustrates a balanced approach to resource extraction and surface environmental values. A recent environmentally successful case history of a sour gas plant project will be presented also. The Hewitt Oil Golden Spike emission-free gas-processing plant was opened in 1987 after a small operating company and the affected public went from confrontation to cooperation. Illustrations from the geologic record of geosphere/biosphere green-house gas variations (CO 2 and CH 4 ) show current high rates of increase greater than any since 150,000 years B.P

Effect of pretreating of host oil on coprocessing

Energy Technology Data Exchange (ETDEWEB)

Hajdu, P.E.; Tierney, J.W.; Wender, I. [Univ. of Pittsburgh, PA (United States)

1995-12-31

The principal objective of this research was to determine if coprocessing performance (i.e., coal conversion and oil yield) could be significantly improved by pretreating the heavy resid prior to reacting it with coal. For this purpose, two petroleum vacuum resids (1000{degrees}F+), one from the Amoco Co. and another from the Citgo Co., were used as such and after they had been pretreated by catalytic hydrogenation and hydrocracking reactions. The pretreatments were aimed at improving the host oil by; (1) converting any aromatic structures in the petroleum to hydroaromatic compounds capable of donating hydrogen, (2) cracking the heavy oil to lower molecular weight material that might serve as a better solvent, (3) reducing the coking propensity of the heavy oil through the hydrogenation of polynuclear aromatic compounds, and (4) removing metals and heteroatoms that might poison a coprocessing catalyst. Highly dispersed catalysts, including fine particle Fe- and Mo-based, and dicobalt octacarbonyl, Co{sub 2}(CO){sub 8}, were used in this study. The untreated and pretreated resids were extensively characterized in order to determine chemical changes brought about by the pretreatments. The modified heavy oils were then coprocessed with an Illinois No. 6 coal as well as with a Wyodak coal, and compared to coprocessing with untreated resids under the same hydroliquefaction conditions. The amount of oil derived from coal was estimated by measuring the level of phenolic oxygen (derived mainly from coal) present in the oil products. Results are presented and discussed.

Screening study for waste biomass to ethanol production facility using the Amoco process in New York State. Appendices to the final report

Energy Technology Data Exchange (ETDEWEB)

NONE

1995-08-01

The final report evaluates the economic feasibility of locating biomass-to-ethanol waste conversion facilities in New York State. Part 1 of the study evaluates 74 potential sites in New York City and identifies two preferred sites on Staten Island, the Proctor and Gamble and the Arthur Kill sites for further consideration. Part 2 evaluates upstate New York and determines that four regions surrounding the urban centers of Albany, Buffalo, Rochester, and Syracuse provide suitable areas from which to select specific sites for further consideration. A conceptual design and economic viability evaluation were developed for a minimum-size facility capable of processing 500 tons per day (tpd) of biomass consisting of wood or paper, or a combination of the two for upstate regions. The facility would use Amoco`s biomass conversion technology and produce 49,000 gallons per day of ethanol and approximately 300 tpd of lignin solid by-product. For New York City, a 1,000-tpd processing facility was also evaluated to examine effects of economies of scale. The reports evaluate the feasibility of building a biomass conversion facility in terms of city and state economic, environmental, and community factors. Given the data obtained to date, including changing costs for feedstock and ethanol, the project is marginally attractive. A facility should be as large as possible and located in a New York State Economic Development Zone to take advantage of economic incentives. The facility should have on-site oxidation capabilities, which will make it more financially viable given the high cost of energy. This appendix to the final report provides supplemental material supporting the evaluations.

Size and profitability in the international oil- and gas industry; Stoerrelse og loennsomhet i den internasjonale olje- og gassindustrien

Energy Technology Data Exchange (ETDEWEB)

Osmundsen, Petter; Mohn, Klaus; Espedal, Harald; Loevaas, Kjell

2002-07-01

Many industrial sectors have gone through a series of mergers and acquisitions. In the international oil- and gas industry this has produced new companies such as ExxonMobil and TotalFinaElf. BP and Amoco merged and then subjugated Atlantic Richfield (ARCO). ChevronTexaco has been established and ConocoPhillips are currently working on the same thing. Saga was previously acquired by Norsk Hydro and Statoil, and Shell recently bought Enterprise and Pennzoil-Quaker. Taking the stock market's principles for corporate analysis and valuation as a starting point, this article discusses the forces behind this consolidation process.

10 CFR 210.1 - Records.

Science.gov (United States)

2010-01-01

... Chemical Corp. Allied Transport Amerada Hess Corp. American Natural Crude Oil Assoc. Amoco Production... Trading, Inc. International Processors Isthmus Trading Corporation J & M Transport J. & J.'s Fast Stop J... Mundy Food Market Munford, Inc. Mutual Petroleum NRG Oil Company National Convenience Stores National...

Environmental Assessment/Baseline Survey to Establish New Drop Zone (DZ) in Cadiz, Ohio, Pittsburgh Air Reserve Station, Coraopolis, Pennsylvania

Science.gov (United States)

2009-03-01

International Airport LATN Low Altitude Tactical Navigation MACA Military Airspace Collision Avoidance µg/m3 microgram per cubic meter MSL mean sea...Drop Zone in Cadiz, OH The 911 AW has a Military Airspace Collision Avoidance ( MACA ) plan that includes procedures for clearing local airspace prior...existing MACA plan to include activities at the new drop zone. The MACA includes placing a radio call into the local airport to clear local traffic

Geological and Structural evolution of the Eurasia Africa plate boundary in the Gulf of Cadiz Central Eastern Atlantic Sea.

OpenAIRE

D’Oriano, Filippo

2010-01-01

Iberia Africa plate boundary, cross, roughly W-E, connecting the eastern Atlantic Ocean from Azores triple junction to the Continental margin of Morocco. Relative movement between the two plate change along the boundary, from transtensive near the Azores archipelago, through trascurrent movement in the middle at the Gloria Fracture Zone, to transpressive in the Gulf of Cadiz area. This study presents the results of geophysical and geological analysis on the plate boundary area offshore Gibral...

Estimate of the annual effective dose for natural radionuclides of anthropogenic origin in the Bay of Cadiz

International Nuclear Information System (INIS)

Rodrigo, J. F.; Martinez-Ramos, C.; Barbero, L.; Casas-Ruiz, M.

2011-01-01

Knowledge of radioactivity levels in soils has a double interest: on the one hand, allows you to set the reference values ??(base Linne) from a region or geographic area, and secondly, to evaluate the external radiation dose received by the population and biota, through appropriate dosimetric model. The natural radioactivity, especially the radionuclides in the natural series. The aim of this study is to determine the levels of gamma emitting radionuclides in marine sediments of the Bay of Cadiz, and dose rates from external radiation received in the areas studied. (Author)

Fluctuations of Mediterranean outflow water circulation in the Gulf of Cadiz during MIS 5 to 7: Evidence from benthic foraminiferal assemblage and stable isotope records

Digital Repository Service at National Institute of Oceanography (India)

Singh, A.D.; Rai, A.K.; Tiwari, M.; Naidu, P.D.; Verma, K.; Chaturvedi, M.; Niyogi, A.; Pandey, D.

the Messinian salinity crisis. Nature, 462, 778-782. doi:10.1038/nature08555. Gonthier, E.G., Faugères, J.C., Stow, D.A.V., 1984. Contourite facies of the Faro Drift, Gulf of Cadiz. In: Stow, D.A.V., Piper, D.J.W. (Eds.), Fine‐ grained sediments: Deep...

Coccolith concentrations in the Gulf of Cadiz at the IODP Site U1390 (Exp 339), in the last ~20,000 years

Science.gov (United States)

Angulo, M.; Balestra, B.

2013-12-01

Our project is dedicated to the study of sediment samples gathered from the Gulf of Cadiz during the Integrated Ocean Drilling Project (IODP), Expedition 339 at Site U1390. The Gulf of Cadiz is an area of the Atlantic Ocean located directly south of Portugal and the western end of the Strait of Gibraltar. We analyzed the sediment samples to obtain the numbers of coccoliths per gram of sediment in each sample. Coccolithophores (from which the coccoliths are the fossils that remain in the sediments) are one of the most abundant groups of living phytoplankton and they are significant components of marine sediment. In order to prepare our samples for counting (the process by which we determined the number of coccoliths in our samples) we utilized about 23 samples from the uppermost 17 meters of the sediment core. This process involved collecting subsamples of each individual sample and then oven drying them. Then we weighted them by utilizing a microbalance to collect the desired amount of sample we needed (between 2 and 4 mg). Several of our samples were slightly below and above this desired amount due to human error. Once we gathered the desired amount of samples for our project, we proceeded to use a filtration system to obtain filters. Then we put the filters into an oven to dry them. After the samples were dried over the course of a day, we proceeded to prepare them for viewing through the microscope. To do this, we cut the filter and placed it upon a microscope slide. Then, we applied oil to the slide, cover and placed it under the Light Microscope (LM). We looked at five different views in each filters under the microscope, counting the number of coccoliths in each view. The counting has been expressed in terms of numbers of coccoliths per gram of sediment (total coccolith concentration). Our results showed us that the amount of coccoliths in the sediment samples receded during the cold periods of time, such as an ice age, and fluctuated in an upward pattern as

Comparing sediment quality in Spanish littoral areas affected by acute (Prestige, 2002) and chronic (Bay of Algeciras) oil spills

International Nuclear Information System (INIS)

Morales-Caselles, C.; Kalman, J.; Riba, I.; DelValls, T.A.

2007-01-01

The quality of sediments collected from two areas of the Spanish coast affected by different sources of contaminants has been compared in this study. The areas studied are the coast of Galicia affected by the oil spill from the tanker Prestige (November 2002) and the Gulf of Cadiz which suffers continuous inputs of contaminants from industries located in the area and from oil spills. Contamination by several chemicals (metals, PCBs and PAHs) that bind to sediments was analyzed, and two toxicity tests (Microtox[reg]) and amphipod 10-day bioassay) were conducted. PAHs were identified as the compounds responsible for the toxic effects. Results show differences between an acute impact related to the sinking of the tanker Prestige and the chronic impact associated with continuous oil spills associated with the maritime and industrial activities in the Bay of Algeciras, this being the most polluted part of the two coastal areas studied in this work. - Littoral sediments affected by low or moderated but continuous oil spills are more polluted than those affected by accidental oil spills such as the Prestige

To the partnership in Kanegafuchi Chemical Industry and solar cell; Kaneka, taiyo denchi de teikei he

Energy Technology Data Exchange (ETDEWEB)

NONE

1999-07-01

Kanegafuchi Chemical Ind. clarified that the consultation was advanced in the direction in which the business cooperates with BP Amoco Corp. in international oil majors on the solar cell business on 11 th capital. In full amount fund subsidiary of the bell pool chemistry, the solar cell making and selling company is established in the joint venture in Europe and America, Asia, when the BP Amoco Corp. does capital participation in money mosquito solar tech which is the production marketer of solar cell. The plan which develops the amorphous solar cell of low cost which the bell pool chemistry developed in the world. The consultation of the partnership is also arranging prospect in the end June, and it seems to greatly jump by uniting with the BP Amoco Corp. of the largest hand. (translated by NEDO)

Microbes safely, effectively bioremediate oil field pits

International Nuclear Information System (INIS)

Shaw, B.; Block, C.S.; Mills, C.H.

1995-01-01

Natural and augmented bioremediation provides a safe, environmental, fast, and effective solution for removing hydrocarbon stains from soil. In 1992, Amoco sponsored a study with six bioremediation companies, which evaluated 14 different techniques. From this study, Amoco continued using Environmental Protection Co.'s (EPC) microbes for bioremediating more than 145 sites near Farmington, NM. EPC's microbes proved effective on various types of hydrocarbon molecules found in petroleum stained soils from heavy crude and paraffin to volatiles such as BTEX (benzene, toluene, ethylbenzene, xylene) compounds. Controlled laboratory tests have shown that these microbes can digest the hydrocarbon molecules with or without free oxygen present. It is believed that this adaptation gives these microbes their resilience. The paper describes the bioremediation process, environmental advantages, in situ and ex situ bioremediation, goals of bioremediation, temperature effects, time, cost, and example sites that were treated

The water erosion processes in the retreat erosive of cliff on soft rocks in the province of Cadiz (Spain); Los procesos de erosion hidrica en el retroceso erosivo de acantilados sobre rocas blandas en la provincia de Cadiz

Energy Technology Data Exchange (ETDEWEB)

Rendon Aragon, J. J.; Gracia Prieto, F. J.; Rio Rodriguez, L. del

2009-07-01

The littoral cliffs on soft materials of the Atlantic Cadiz coast show an important activity of the fresh water erosion processes, sometimes even more significant than the marine erosion processes. The connection of the lower cliffs with sandy beaches favours aeolian sand invasion, which fills previous rills and reduces the water erosion intensity by increasing infiltration. Cliff retreat and rill erosion measurement by using erosion sticks has shown very variables values, most of them higher than the estimated error of the employed methods. This indicates the existence of other factors influencing the distribution of water erosion processes along these cliffs, which have to be studied through different techniques. (Author) 5 refs.

Improving environmental strategies of the UK oil and gas industry

International Nuclear Information System (INIS)

Tanega, J.

1992-01-01

The paper is a strategic review of the current environmental policies and practices of the UK Oil and Gas Industry. It begins with an analysis of the current environmental impacts of the UK Oil and Gas Industry, including air emissions, effluents to sea and industrial wastes. The importance of environmental issues to UK operators is related to financial conseqeunces of environmental damage to the North Sea, poor public opinion and the spectre of increased government regulations. There is a survey of the best practices of environmental management programmes, including environmental assessment, monitoring auditing and contingency planning and emergency response, with historical lessons from Cadiz to Valdez and the industry's reaction to Exxon Valdez. After critically assessing the weaknesses of environmental management programmes, the author calls for systematic environmental assessment, employing inventory, monitoring, risk assessment and quantified risk assessment. There are recommendations on how to minimise the impact on the environment through the use of existing technology, training, incident response and crisis management, auditing, testing and industry-wide collaboration. (Author)

The use of multivariate analysis to link sediment contamination and toxicity data to establish sediment quality guidelines: an example in the Gulf of Cadiz (Spain); El uso del analisis multivariante en la union de datos de toxicidad y contaminacion para establecer guias de calidad de sedimento: Un ejemplo en la Bahia de Cadiz (Espana)

Energy Technology Data Exchange (ETDEWEB)

Del Valls, T. Angel; Forja, Jesus M [Departamento de Quimica Fisica, Facultad de Ciencias del Mar, Universidad de Cadiz, Cadiz, (Spain); Gomez-Parra, Abelardo [Instituto de Ciencias Marinas de Andalucia, CSIC, Puerto Real, Cadiz, (Spain)

1998-03-01

To evaluate marine sediment quality in the Gulf of Cadiz, chemical concentration and toxicity test endpoints from sediments were linked using multivariate analysis. Sediment samples were collected synoptically at seven stations in two littoral ecosystems of the Gulf of Cadiz (five in the Bay of Cadiz and two in the salt marsh of the Barbate River), and subjected to six separate, replicated sediment toxicity tests and comprehensive sediment chemistry analyses. The toxic effects of sediments were tested using three operational sediment phases: whole sediment, using the estuarine amphipod Microdeutopus gryllotalpa (10 d static: survival) and the estuarine clam Ruditapes philippinaru (48 h static: survival) and of the marine fish Sparus aurata (48 h static. Survival); and interstitial water, using populations of the estuarine rotifer Brachionus Plicatilis (7 d static: Population decline) and of the marine bacteria Photobacterium phosphoreum (Microtox ). To evaluate the levels of contamination, the concentrations in the sediments of organic carbon, 14 trace metals (Fe, Mn, Cu, Zn, Pb, Cd, Ag, Hg, As, Sn, V, Ni, Co and Cr) and the surfactant linear alkylbenzenesulphonate (LAS) were measured. The results of the toxicity tests were compared in a dose-response relationship between sites, demonstrating a general agreement between the toxicity values determined by all the tests, except in the case of interstitial water toxicity (principally due to toxic mixtures of trace metals). Data derived from sediment chemistry and bioassays were assembled by multivariate statistical techniques (PCA and factor analysis), showing that the two data types could be represented by only five factors corresponding to five overlapping chemical-biological effect relations. Positive prevalence of these factors in the cases studied was used to establish those ranges in chemical concentrations associated with adverse effects. The sediment quality guidelines, in terms of concentrations at or below

Testing Nordmøre grids on the target and by-catch species of the commercial bottom trawl fishery in the Gulf of Cadiz

Directory of Open Access Journals (Sweden)

Mariángeles Gamaza

2015-12-01

Full Text Available Sorting grids have been tested worldwide in trawl fisheries. Here we report upon the first trials performed using Nordmøre sorting grids with four different bar spacings in the trawl fisheries of the Gulf of Cadiz targeting crustaceans as the main resource. A total of 288 valid hauls and 67 commercial species were caught. Escapement and escape size selectivity were evaluated for the most important target and by-catch species. A decrease in the percentage of biomass escape was recorded with increasing grid spacing for the two target species, deep-water rose shrimp (Parapenaeus longirostris and Norway lobster (Nephrops norvegicus, from 24% to 8% for the former and from 86 to 9% for the latter, with a 15-mm and 30-mm grid respectively. In general, high escape rates were found for most finfish and cephalopods. For hake (Merluccius merluccius, as the main by-catch species, the results showed an escape rate decreasing from 96% to 71% as the bar spacing increased. Our findings suggest the 30-mm grid would be effective for the deep-water crustacean trawlers but different mitigation measures will be required for other métiers in the multispecies trawl fishery of the Gulf of Cadiz.

The anti-liberal deputies in the Cortes of Cadiz (1810-1813

Directory of Open Access Journals (Sweden)

María del Mar Alarcón Alarcón

2017-09-01

Full Text Available This article attempts to analyze, mainly drawing on the Parliamentary Debates, the political positions adopted by some anti-liberal deputies in the Cortes of Cadiz. This representative chamber (which was the leading organ of political power in the Spanish lands not controlled by the Bonapartist regime was set up as a discussion and decision-making space,which entailed a rupture with conceptions of politics prevailing during the Ancien Régime, including Absolutism. The more conservative and reactionary groups used several mechanisms and ways (the propaganda machine, army, pulpit, municipal posts, diplomacy and Parliamentary elections, among others to put an end to that new place. Despite of its impact on the making and development of Society and State in Contemporary Spain, historians have paid little attention to the genesis and social bases of the Counter-Revolution. A small number of studies are focused on the origins of this historical movement, as well as on the various ideas and political attitudes of the deputies opposed to the constitutional regime of 1812. These gaps in knowledge have motivated the present pages. Our aim is to offer a first approach to the question.

The oil industry and climate change: strategies and ethical dilemmas

International Nuclear Information System (INIS)

Hove, S. van den; Le Menestrel, M.; Bettignies, H.C. de

2002-01-01

This paper explores the different climate change strategies chosen by three major multinational oil corporations: ExxonMobil, TotalFinaElf and BP Amoco. They are referred to, as the 'fight against emission constraints,' 'wait and see,' and 'proactive' strategies, respectively. The justifications given to support these strategies are identified. They cover the business, scientific, political, economic, technological and social dimensions. In a business ethics framework, the issue of climate change brings forth an ethical dilemma for the oil industry, in the form of a tension between profits and CO 2 emissions. The strategies are analysed as three attitudes towards this dilemma: (i) placing priority on the business consequences while weakening the perception that anthropogenic greenhouse gas emissions are causing climate change; (ii) avoiding responsibility; and (iii) placing priority on the need for a modification of the business process while limiting the negative effect in terms of business consequences. In conclusion, we propose that beyond the ethical issues proper to climate change itself, additional ethical issues are raised if society at large is instrumentalised by an industry in its search for profit. Publicly gauging and valorising the ethical commitment of a corporation appear as ways of inducing more collaborative and proactive attitudes by business actors. (Author)

The oil industry and climate change. Strategies and ethical dilemmas

International Nuclear Information System (INIS)

Van den Hove, S.; Le Menestrel, Marc; De Bettignies, Henri-Claude

2002-01-01

This paper explores the different climate change strategies chosen by three major multinational oil corporations: ExxonMobil, TotalFinaElf and BP Amoco. They are referred to, as the 'fight against emission constraints,' 'wait and see', and 'proactive' strategies, respectively. The justifications given to support these strategies are identified. They cover the business, scientific, political, economic, technological and social dimensions. In a business ethics framework, the issue of climate change brings forth an ethical dilemma for the oil industry, in the form of a tension between profits and CO2 emissions. The strategies are analysed as three attitudes towards this dilemma: (1) placing priority on the business consequences while weakening the perception that anthropogenic greenhouse gas emissions are causing climate change; (2) avoiding responsibility; and (3) placing priority on the need for a modification of the business process while limiting the negative effect in terms of business consequences. In conclusion, we propose that beyond the ethical issues proper to climate change itself, additional ethical issues are raised if society at large is instrumentalised by an industry in its search for profit. Publicly gauging and valorising the ethical commitment of a corporation appear as ways of inducing more collaborative and proactive attitudes by business actors

The hydro-climatic history of the Gulf of Cadiz throughout the last ~570 kyr from IODP 339 Site U1386

Science.gov (United States)

Kaboth, Stefanie; de Boer, Bas; Bahr, Andrè; Zeeden, Christian; Lourens, Lucas

2016-04-01

Here we present the first continuous and high-resolution (~ 1 kyr) benthic δ18O record from IODP Site U1386 (Gulf of Cadiz, IODP Exp. 339) representing the last 570 kyr. We find distinct and periodic δ18O enrichment events overimposed on patterns of global ice volume change as inferred from the global mean δ18O signal (i.e. LR04). These events occur most prominently during glacials, and are characterized by a relative increase of up to 1‰. The observed glacial δ18O enrichment represents a striking difference to deep-sea benthic δ18O records worldwide but is not without precedent as similar δ18O variability can be observed in the planktic signal of the Red Sea (Sites KL11 and KL23). There, similar glacial δ18O enrichment events have not raised particular interest since their occurrence was attributed to sea level induced salinity increase within this virtually landlocked basin. Our results suggest that the glacial δ18O enrichment at Site U1386 present salinity and/or temperature variability related to changes in the position of the frontal zone between subpolar and subtropical water masses within the Gulf of Cadiz. Interestingly, the δ18O enrichments at Site U1386 strongly reflect precession and semi-precession patterns. Since similar patterns can be observed in the Red Sea isotopic records, we argue that part of the inferred sea level reconstructions are biased by a regional and precession controlled mechanism.

The water erosion processes in the retreat erosive of cliff on soft rocks in the province of Cadiz (Spain)

International Nuclear Information System (INIS)

Rendon Aragon, J. J.; Gracia Prieto, F. J.; Rio Rodriguez, L. del

2009-01-01

The littoral cliffs on soft materials of the Atlantic Cadiz coast show an important activity of the fresh water erosion processes, sometimes even more significant than the marine erosion processes. The connection of the lower cliffs with sandy beaches favours aeolian sand invasion, which fills previous rills and reduces the water erosion intensity by increasing infiltration. Cliff retreat and rill erosion measurement by using erosion sticks has shown very variables values, most of them higher than the estimated error of the employed methods. This indicates the existence of other factors influencing the distribution of water erosion processes along these cliffs, which have to be studied through different techniques. (Author) 5 refs.

Searching for Seismically Active Faults in the Gulf of Cadiz

Science.gov (United States)

Custodio, S.; Antunes, V.; Arroucau, P.

2015-12-01

The repeated occurrence of large magnitude earthquakes in southwest Iberia in historical and instrumental times suggests the presence of active fault segments in the region. However, due to an apparently diffuse seismicity pattern defining a broad region of distributed deformation west of Gibraltar Strait, the question of the location, dimension and geometry of such structures is still open to debate. We recently developed a new algorithm for earthquake location in 3D complex media with laterally varying interface depths, which allowed us to relocate 2363 events having occurred from 2007 to 2013, using P- and S-wave catalog arrival times obtained from the Portuguese Meteorological Institute (IPMA, Instituto Portugues do Mar e da Atmosfera), for a study area lying between 8.5˚W and 5˚W in longitude and 36˚ and 37.5˚ in latitude. The most remarkable change in the seismicity pattern after relocation is an apparent concentration of events, in the North of the Gulf of Cadiz, along a low angle northward-dipping plane rooted at the base of the crust, which could indicate the presence of a major fault. If confirmed, this would be the first structure clearly illuminated by seismicity in a region that has unleashed large magnitude earthquakes. Here, we present results from the joint analysis of focal mechanism solutions and waveform similarity between neighboring events from waveform cross-correlation in order to assess whether those earthquakes occur on the same fault plane.

The Research Administrator's Responsibility for Buying from Minority-Owned Companies.

Science.gov (United States)

Shaffer, Lyle E.

1979-01-01

The author, the president of Amoco Venture Capital Company, a subsidiary of Standard Oil Company of Indiana designed to promote minority purchasing and finance minority enterprise, describes his program and the national program to promote minority enterprise. Ways that research administrators can develop minority sources for laboratory needs are…

Sedimentology models from activity concentration measurements: application to the 'Bay of Cadiz' Natural Park (SW Spain)

International Nuclear Information System (INIS)

Ligero, R.A.; Vidal, J.; Melendez, M.J.; Hamani, M.; Casas-Ruiz, M.

2009-01-01

A previous study on seabed sediments of the Bay of Cadiz (SW of Spain) enabled us to identify several relations between sedimentological variables and activity concentrations of environmental radionuclides such as 137 Cs, 226 Ra, 232 Th and 40 K. In this paper the study has been extended to a large neighbouring inter-tidal area in order to establish if the above mentioned models can be generalized. As a result we have determined that the measured activity concentrations are closely to the values predicted by the theoretical models (correlation coefficient range = 0.85-0.93). Furthermore, the proposal model for granulometric facies as a function of activity concentrations of the abovementioned radionuclides provides for the sediments distribution a representation which agrees with the values of the tidal energy distribution obtained using numeric models calibrated with experimental data from current meters and water level recorders

Soil Properties Database of Spanish Soils. Volume VII.- Andalucia (b): Cadiz, Malaga, Granada y Almeria; Base de Datos de Propiedades Edafologicas de los Suelos Espanoles. volumen VII.- Andalucia (b): Cadiz, Malaga, Granda y Almeria

Energy Technology Data Exchange (ETDEWEB)

Trueba, C; Millan, R; Schmid, T; Lago, C [Ciemat. Madrid (Spain); Roquero, C; Magister, M [UPM. Madrid (Spain)

1999-05-01

The soil vulnerability determines the sensitivity of the soil after an accidental radioactive contamination due to Cs-137 and Sr-90. The Departamento de Impacto Ambiental de la Energia of CIEMAT is carrying out an assessment of the radiological vulnerability of the different Spanish soils found on the Iberian Peninsula. This requires the knowledge of the soil properties for the various types of existing soils. In order to achieve this aim, a bibliographical compilation of soil profiles has been made to characterize the different soil types and create a database of their properties. Depending on the year of publication and the type of documentary source, the information compiled from the available bibliography is very heterogeneous. Therefore, an important effort has been made to normalize and process the information prior its incorporation to the database. This volume presents the criteria applied to normalize and process the data as well as the soil properties of the various soil types belonging to provinces of Cadiz, Malaga, Granada and Almeria of the Comunidad Autonoma de Andalucia. (Author) 78 refs.

Soil Properties Database of Spanish Soils. Volume VII.- Andalucia (b): Cadiz, Malaga, Granada y Almeria

International Nuclear Information System (INIS)

Trueba, C.; Millan, R.; Schmid, T.; Lago, C.; Roquero, C; Magister, M.

1999-01-01

The soil vulnerability determines the sensitivity of the soil after an accidental radioactive contamination due to Cs-137 and Sr-90. The Departamento de Impacto Ambiental de la Energia of CIEMAT is carrying out an assessment of the radiological vulnerability of the different Spanish soils found on the Iberian Peninsula. This requires the knowledge of the soil properties for the various types of existing soils. In order to achieve this aim, a bibliographical compilation of soil profiles has been made to characterize the different soil types and create a database of their properties. Depending on the year of publication and the type of documentary source, the information compiled from the available bibliography is very heterogeneous. Therefore, an important effort has been made to normalize and process the information prior to its incorporation to the database. This volume presents the criteria applied to normalize and process the data as well as the soil properties of the various soil types belonging to the provinces of Cadiz, Malaga, Granada and Almeria of the Comunidad Autonoma de Andalucia. (Author) 78 refs

A clean and healthful condition

International Nuclear Information System (INIS)

Morse, H.N.

1990-01-01

In a suit brought in the District Court of the United States for the SOuthern District of Texas under the Comprehensive Environmental Response, Compensation, and Liability Act of 1980, Amoco Oil Co. (Amoco) sought a declaratory judgment for liablilty and response cost damages from Borden Inc. (Borden), from which Amoco had purchased contaminated industrial property. The property at issue is a 114-acre tract of land in Texas City, TX. FOr many years, Borden operated a phosphate fertilizer plant on the site. As a by-product of the fertilizer manufacturing process, large quantities of phosphogypsum were produced. The site now contains a large inactive pile of phosphogypsum covering approximately 35 acres. Phosphogypsum alone contains low levels of radioactivity. More highly radioactive sludges and scales from processing equipment, however, were dumped into the phosphogypsum pile creating hot areas within the pile. Additionally, during processing, radioactive materials became concentrated in manufacturing equipment, pipe, and filter cloths used in production. These materials constitute off-pile wastes and were left primarily near a junkyard on the property and near the abandoned manufacturing buildings. Some of the off-pile sites contain over 500 times the background level of radiation

Microbial diversity in Frenulata (Siboglinidae, Polychaeta) species from mud volcanoes in the Gulf of Cadiz (NE Atlantic).

Science.gov (United States)

Rodrigues, Clara F; Hilário, Ana; Cunha, Marina R; Weightman, Andrew J; Webster, Gordon

2011-06-01

Frenulates are a group of gutless marine annelids belonging to the Siboglinidae that are nutritionally dependent upon endosymbiotic bacteria. We have characterized the bacteria associated with several frenulate species from mud volcanoes in the Gulf of Cadiz by PCR-DGGE of bacterial 16S rRNA genes, coupled with analysis of 16S rRNA gene libraries. In addition to the primary symbiont, bacterial consortia (microflora) were found in all species analysed. Phylogenetic analyses indicate that the primary symbiont in most cases belongs to the Gammaproteobacteria and were related to thiotrophic and methanotrophic symbionts from other marine invertebrates, whereas members of the microflora were related to multiple bacterial phyla. This is the first molecular evidence of methanotrophic bacteria in at least one frenulate species. In addition, the occurrence of the same bacterial phylotype in different Frenulata species, from different depths and mud volcanoes suggests that there is no selection for specific symbionts and corroborates environmental acquisition as previously proposed for this group of siboglinids.

An early approach for the evaluation of repair processes in fish after exposure to sediment contaminated by an oil spill.

Science.gov (United States)

Salamanca, Maria J; Jimenez-Tenorio, Natalia; Reguera, Diana F; Morales-Caselles, Carmen; Delvalls, T Angel

2008-12-01

A chronic bioassay was carried out under laboratory conditions using juvenile Solea senegalensis to determine the toxicity of contaminants from an oil spill(Prestige). Also, the repair processes in fish affected by contaminants due to oil exposure were evaluated. Over 30 days individuals were exposed to clean sediment (control) and to sediment contaminated by a mixture of polyaromatic hydrocarbons (PAHs) and other substances. The physicochemical parameters of the tanks (salinity, temperature, pH and dissolved oxygen) were controlled during the exposure period. Clean sediment from the Bay of Cadiz (Spain) was used as negative control and was mixed with fuel oil to prepare the dilution (0.5% w:w dry-weight). After the exposure period, fish were labeled and transferred to "clean tanks" (tanks without sediment) in order to study the recovery and the repair processes in the exposed organisms. A biomarker of exposure (ethoxyresorufin-O-deethylase activity - EROD activity) and a biomarker of effect (histopathology) were analyzed during the exposure and recovery period. After 10, 20 and 30 days of exposure, individuals showed significant induction (P tank", enabled a first evaluation of the repair process of the induced damages due to the fuel oil exposure. After the recovery phase, control individuals showed a more significant decrease (P repair processes probably need longer recovery periods to observe significant improvement of the affected organs. This will be further investigated in the future.

Morphodynamic characterization of the Spanish beaches of the Gulf of Cadiz

Energy Technology Data Exchange (ETDEWEB)

Benavente, J.; Gracia, F. J.; Rio, L. del; Anfuso, G.; Rodriguez-Ramirez, A.

2015-07-01

During the1980s several attempts were made to classify beaches according to their morphodynamic behav- iour. Published papers proposed classifications based mainly on wave incident energy and beach character- istics, such as foreshore slopes and sediment settling velocities. In the 1990s more complex classifications appeared, where the effect of tides on wave action was included, highlighting their relevance to the determi- nation of the morphodynamic state of the beach. In this paper we present a beach monitoring programme, in which more than 30 beaches located along the Spanish shores of the Gulf of Cadiz and the Strait of Gibraltar were surveyed for four years (2000-2004). The long study period allowed the monitoring of beach morphologies related both to fair weather (summer) and storm (winter) conditions. The coastal setting in the study area provided the opportunity for covering a wide range of tidal conditions, from high mesotidal (MSTR ca. 4 m) to microtidal (MSTR around 1 m). Furthermore, the dimensions of the study area permitted the mon- itoring of beaches linked to different boundary conditions, thus including both attached and detached beach- es located at varying distances from main sediment sources, and influenced by different wave regimes. The analysis of the beach morphologies related to such contrasting conditions allowed the identification of the real significance of the tidal effect on beach profile morphology and hence on beach morphodynamics. Finally, we conclude that the effect of tides on wave action is the main factor determining beach morphody- namic behaviour. (Author)

Coastal counter-currents setup patterns in the Gulf of Cadiz

Science.gov (United States)

Relvas, P.; Juniór, L.; Garel, E.; Drago, T.

2017-12-01

Alongshore coastal counter-currents (CCC) are frequent features of Eastern Boundary Upwelling Systems, where they temporally alternate with upwelling driven jets of opposite direction. Along the northern margin of the Gulf of Cadiz inner shelf, these CCCs are oriented poleward (eastward) and responsible for sharp temperature increases during the upwelling season, along with potential decline in water quality at the coast. This research is based on a multi-year ADCP velocity time-series (2008-2017), recorded at a single location (23 m water depth) over 13 deployments up to 3 months-long. The analysis focuses on the water column alongshore velocities during current inversions (i.e., the transition from equatorward upwelling jets to poleward CCCs). A set of parameters were derived from the flow structure to identify distinct types of inversions and to hypothesize about their driving mechanisms. Results show that 77% of the inversions start near the bed, propagating then to the upper layers. The bottom layer also changes direction before the surface layer for most events (71%). The vertical shear in this case is one order of magnitude greater than in the (less frequent) opposite situation. No seasonal variability is observed in the CCC occurrences. However, the parameters analysed in this study suggest different types of inversion between winter and summer. In winter, inversions are well defined (low variability), with similar patterns near the surface and bed layers as a result of a strong barotropic component. In summer the inversion patterns are more variable. In particular, the upper and bed layers are often importantly decoupled during inversions, indicating the strengthening of baroclinicity. A categorization of inversions events is proposed based on cross-correlation and multi-variable analyses of the developed parameters. Various types of inversion are obtained, suggesting that CCCs are driven by different forcings that may act separately or jointly.

Additions to the Tanaidomorpha (Crustacea: Tanaidacea) from mud volcanoes and coral mounds of the Gulf of Cadiz and Horseshoe Continental Rise.

Science.gov (United States)

Esquete, Patricia; Cunha, Marina R

2018-02-05

The Tanaidacea collection from various research cruises carried out in the Gulf of Cadiz and Horseshoe Continental Rise between 2004 and 2012 yielded four species new to science that are described herein. Two belong to genera recorded for the first time since the original descriptions of their type species: Cetiopyge, described from the Gulf of Mexico and Gamboa from shallow waters of Macaronesia. The other two belong to the genera Collettea and Paragathotanais, both with a worldwide distribution. Additionally, specimens of Tumidochelia uncinata are described and illustrated to complete previous descriptions. Identification keys to all known genera of Nototanaidae, and the Eastern Atlantic species of Paragathotanais and Collettea are provided. This works raises the number of tanaidacean species known from the deep-sea habitats in the study region to a total of 22.

Macrofaunal assemblages from mud volcanoes in the Gulf of Cadiz: abundance, biodiversity and diversity partitioning across spatial scales

Science.gov (United States)

Cunha, M. R.; Rodrigues, C. F.; Génio, L.; Hilário, A.; Ravara, A.; Pfannkuche, O.

2013-04-01

The Gulf of Cadiz is an extensive seepage area in the south Iberian margin (NE Atlantic) encompassing over 40 mud volcanoes (MVs) at depths ranging from 200 to 4000 m. The area has a long geologic history and a central biogeographic location with a complex circulation ensuring oceanographic connectivity with the Mediterranean Sea, equatorial and North Atlantic regions. The geodynamics of the region promotes a notorious diversity in the seep regime despite the relatively low fluxes of hydrocarbon-rich gases. We analyse quantitative samples taken during the cruises TTR14, TTR15 and MSM01-03 in seven mud volcanoes grouped into Shallow MVs (Mercator: 350 m, Kidd: 500 m, Meknès: 700 m) and Deep MVs (Captain Arutyunov: 1300 m, Carlos Ribeiro: 2200 m, Bonjardim: 3000 m, Porto: 3900 m) and two additional Reference sites (ca. 550 m). Macrofauna (retained by a 500 μm sieve) was identified to species level whenever possible. The samples yielded modest abundances (70-1567 individuals per 0.25 m2), but the local and regional number of species is among the highest ever reported for cold seeps. Among the 366 recorded species, 22 were symbiont-hosting bivalves (Thyasiridae, Vesicomyidae, Solemyidae) and tubeworms (Siboglinidae). The multivariate analyses supported the significant differences between Shallow and Deep MVs: The environmental conditions at the Shallow MVs make them highly permeable to the penetration of background fauna leading to high diversity of the attendant assemblages (H': 2.92-3.94; ES(100): 28.3-45.0; J': 0.685-0.881). The Deep MV assemblages showed, in general, contrasting features but were more heterogeneous (H': 1.41-3.06; ES(100): 10.5-30.5; J': 0.340-0.852) and often dominated by one or more siboglinid species. The rarefaction curves confirmed the differences in biodiversity of Deep and Shallow MVs as well as the convergence of the latter to the Reference sites. The Bray-Curtis dissimilarity demonstrated the high β-diversity of the assemblages

Governments, contractors seen headed for era of cooperation

International Nuclear Information System (INIS)

McHaffie, E.R.; Jarvis, M.G.; Barber, S.A.

1993-01-01

The oil and gas industry is on the threshold of a new era in international oil and gas investments. It will be an era of increasing flexibility and cooperation among investors, oil companies, and host governments. And it will develop as a necessary response to flat oil prices and the growing mobility of capital. This article will cover three essential elements of this topic: the effect of fiscal terms on the economics of a project investment; how recent changes in global economies have impacted the economics of the projects the authors evaluated at Amoco; some potential trends that fiscal provisions, and the pattern of investment in the upstream petroleum industry, may take

Late Quaternary high resolution micropaleontological and sedimentological records in the Gulf of Cadiz.

Science.gov (United States)

Balestra, B.; Ducassou, E.; Zarikian, C.; Bout-Roumazeilles, V.; Flores, J. A.; Paytan, A.

2017-12-01

We present preliminary micropaleontological and sedimentological data from IODP Site U1390 (Expedition 339), located in the central middle slope of the Gulf of Cadiz, since the last glaciation. This site has been targeted for reconstruction of regional paleo-circulation as it shows particularly high sedimentation rates, throughout the Holocene and the Last Glacial Maximum (LGM). We use micropaleontological and sedimentological proxies to understand the bottom current variations through time and the ecological conditions at the sea surface (planktonic foraminifer, pteropod and nannofossil assemblages), and the sea bottom (ostracod assemblages). Eleven samples, chosen at transitions of planktonic foraminifer assemblages, have been dated by AMS radiocarbon analyses. Preliminary results from benthic ostracod assemblages show variations in bottom water ventilation and food supply. Planktonic foraminifer assemblages clearly show the well-known cold events of this period such as the Younger Dryas and Heinrich stadial associated to coarser sediment, and warmer phases such as the Bölling-Allerød associated to muddy sediment. Other bio-events within the Holocene period are also recorded. The preservation of the coccolithophore assemblages is good to moderate. Coccolith abundances (expressed in coccoliths/gr of sediment) show higher values during the Holocene and generally are like assemblages previously reported for the same area. Implications for characterization of the Holocene, the last termination and LGM ecological conditions at high resolution and their potential fluctuations (i.e. amplitude and magnitude) under the influence of the lower core of the Mediterranean Outflow Water (MOW), with this multi proxy approach based on sedimentological, and paleontological data will be discussed.

Investment opportunities in an increasingly competitive environment

International Nuclear Information System (INIS)

Webb, Martin

1999-01-01

Four topic areas are considered: (1) The global context for energy investments, (2) Strategic investments in the gas chain, (3) Conventional and changing approaches to investing in gas and power, (4) New areas of opportunity. The presentation considers the challenging global context for investments and the current oil price outlook and more specifically the backdrop to the growth in demand for gas and its increasing availability and the implications of factors such as energy market liberalization. It notes the regional nature of gas and power markets and considers the issue of stranded supply and demand. It identifies an increasing trend towards investments up and down the gas chain by both traditional and new players and explores BP Amoco's own corporate response. The presentation then briefly reviews four major gas investments which BP Amoco has either already taken or is considering. It then discusses investments in gas to power and the growing environmental agenda, which is bringing a range of new and non-traditional investment opportunities

Investment opportunities in an increasingly competitive environment

Energy Technology Data Exchange (ETDEWEB)

Webb, Martin

1999-07-01

Four topic areas are considered: (1) The global context for energy investments, (2) Strategic investments in the gas chain, (3) Conventional and changing approaches to investing in gas and power, (4) New areas of opportunity. The presentation considers the challenging global context for investments and the current oil price outlook and more specifically the backdrop to the growth in demand for gas and its increasing availability and the implications of factors such as energy market liberalization. It notes the regional nature of gas and power markets and considers the issue of stranded supply and demand. It identifies an increasing trend towards investments up and down the gas chain by both traditional and new players and explores BP Amoco's own corporate response. The presentation then briefly reviews four major gas investments which BP Amoco has either already taken or is considering. It then discusses investments in gas to power and the growing environmental agenda, which is bringing a range of new and non-traditional investment opportunities.

The business impact and value of 3-D seismic

International Nuclear Information System (INIS)

Aylor, W.K.

1996-01-01

3-D Seismic has had a profound and lasting impact on the hydrocarbon exploration and production industry. It is a technology which is often excellent at assessing the risk associated with trap definition, seal and reservoir distribution, the very parameters which are the most critical to optimizing the economics associated with E and P projects. This paper discusses Amoco Corporation's experience with 3-D Seismic when used for new field rate acceleration, older field extension, and wildcat exploration. Its emphasis is on assessing the value added by 3-D by reviewing recent E and P experiences in a post-appraisal mode and then in applying the lessons learned from these analyses and case histories to potential new projects. This work is significant because it first assesses the impact 3-D has had on a large number of business situations at Amoco; that is, it is based on data collected on159 3-D surveys acquired at Amoco between 1991--1994. Second, it uses the data collected from these surveys and applies the business improvements observed in the data to typical international business opportunities to quantify, in expected value $ terms, the value that the technology brings to an average project. Finally, it looks at project economics not only from an oil company perspective, but from the standpoint of a host government, with a discussion of insights and implications of the data, economics and techniques utilized

Foreign adventures -- in Yemen and beyond

International Nuclear Information System (INIS)

Harvie, W.

1995-01-01

The year 1994 was reviewed for oil and gas producers, in terms of revenue, profit, capital expenditures and total assets. Companies with best and worst performances in share price, cash flow and net revenue for the year were listed. Summaries of business activity and strategies were provided for several blue chip companies including Canadian Occidental, Rigel Energy Corp., Summit Resources, and Amoco. A top 100 financial ranking list of publicly traded energy companies was also supplied

Cádiz como eje vertebrador en España del discurso dialógico musical entre México y Andalucía en la etapa preflamenca. Cadiz as the backbone in Spain of musical dialogue between Mexico and Andalucia in preflamenco period.

Directory of Open Access Journals (Sweden)

Lénica Reyes Zúñiga

2011-05-01

Full Text Available Durante siglos Cádiz ha sido puerta de entrada de músicas y danzas procedentes de América, hecho que fue trascendental en la etapa de conformación del flamenco. La importante presencia de piezas musicales mexicanas que fueron integradas en esta ciudad hasta el punto de convertirse en nuevos estilos preflamencos propiamente gaditanos, es un fenómeno que no ha sido atendido en la literatura flamenca. El estudio del diálogo musical transatlántico entre Andalucía y México desde un enfoque etnomusicológico, es decisivo para la comprensión de los procesos de cambio musical producidos durante la etapa preflamenca, en la que Cádiz desempeñó un papel vertebrador.Over the centuries Cadiz has been a gateway for musics and dances from America. This fact was capital during flamenco conformation process. A significant presence of mexican music was integrated into the city, to the point of becoming new “gaditano” preflamencos styles. This phenomena has not been analyzed properly in flamenco literature until now. The study of transoceanic musical dialogue between Andalusia and Mexico from an ethnomusicological approach, is capital for the understanding of musical change processes during preflamenco period, being Cadiz an important point of convergence.

Hazard potential of widespread but hidden historic offshore heavy metal (Pb, Zn) contamination (Gulf of Cadiz, Spain).

Science.gov (United States)

Hanebuth, Till J J; King, Mary Lee; Mendes, Isabel; Lebreiro, Susana; Lobo, Francisco J; Oberle, Ferdinand K; Antón, Laura; Ferreira, Paulo Alves; Reguera, Maria Isabel

2018-05-10

Natural and human-induced seabed sediment disturbances affect wide areas of the global coastal ocean. These recurrent to chronic disturbances mobilize significant amounts of material, including substances that have the potential to significantly harm the environment once re-released. This very challenging issue is difficult to deal with if sub-surface contaminant concentrations are unknown. Based on the analysis of 11 new, up to 5-m long sediment cores taken offshore in the Gulf of Cadiz, the contamination history (using the trace elements lead and zinc) is well documented over major parts of the gulf. Ore mining and metal processing industries on the southwestern Iberian Peninsula started five thousand years ago and experienced a first peak during the Roman Period, which can be detected over the entire gulf. The Industrial Era added a massive, shelf-wide heavy metal excursion of unprecedented dimension. This metal contamination to the coastal ocean decreased in the 1990s and appears to be today limited to larger areas off the Tinto/Odiel and Guadiana River mouths. The unforeseen, significant finding of this study is that the gulf-wide, peak heavy metal concentration, stemming from the Industrial Era, is widely overlain by a modern sediment veneer just thick enough to cover the contaminant horizon, but thin enough to have this layer within the reach of natural or human-induced sediment mobilization events. Published by Elsevier B.V.

A high-resolution hydrodynamic-biogeochemical coupled model of the Gulf of Cadiz – Alboran Sea region.

Directory of Open Access Journals (Sweden)

D. M. MACIAS

2014-12-01

Full Text Available The southern Iberia regional seas comprise the Gulf of Cadiz and the Alboran Sea sub-basins connected by the narrow Strait of Gibraltar. Both basins are very different in their hydrological and biological characteristics but are, also, tightly connected to each other. Integrative studies of the whole regional oceanic system are scarce and difficult to perform due to the relative large area to cover and the different relevant time-scales of the main forcings in each sub-basin. Here we propose, for the first time, a fully coupled, 3D, hydrodynamic-biogeochemical model that covers, in a single domain (~2km resolution both marine basins for a 20 years simulation (1989-2008. Model performance is assessed against available data in terms of spatial and temporal distributions of biological variables. In general, the proposed model is able to represent the climatological distributions of primary and secondary producers and also the main seasonality of primary production in the different sub-regions of the analyzed basins. Potential causes of the observed mismatches between model and data are identified and some solutions are proposed for future model development. We conclude that most of these mismatches could be attributed to the missing tidal forcing in the actual model configuration. This model is a first step to obtain a meaningful tool to study past and future oceanographic conditions in this important marine region constituting the unique connection of the Mediterranean Sea with the open world’s ocean.

A set of rapid-response models for pollutant dispersion assessments in southern Spain coastal waters

International Nuclear Information System (INIS)

Perianez, R.; Caravaca, F.

2010-01-01

Three rapid-response Lagrangian particle-tracking dispersion models have been developed for southern Spain coastal waters. The three domains cover the Gulf of Cadiz (Atlantic Ocean), the Alboran Sea (Mediterranean), and the Strait of Gibraltar with higher spatial resolution. The models are based on different hydrodynamic submodels, which are run in advance. Tides are calculated using a 2D barotropic model in the three cases. Models used to obtain the residual circulation depend on the physical oceanography of each region. Thus, two-layer models are applied to Gibraltar Strait and Alboran Sea and a 3D baroclinic model is used in the Gulf of Cadiz. Results from these models have been compared with observations to validate them and are then used by the particle-tracking models to calculate dispersion. Chemical, radioactive and oil spills may be simulated, incorporating specific processes for each kind of pollutant. Several application examples are provided.

The petroleum industry in 1998 - 1999 edition

International Nuclear Information System (INIS)

1999-01-01

The drop of the oil quotations, which reached up to 50 % of their 1997 average value, was the outstanding event of the year 1998. A comparable event was observed more than 25 years ago before the first oil crack. 1998 was also the year of major changes in the petroleum industry with the BP-Amoco fusion, followed by the Exxon-Mobil fusion (the biggest fusion of the worldwide history of industry), and finally followed by the Total-Petrofina one. This document presents, in the form of thematic articles, the impact of the 1998 events on the entire petroleum activities. It comprises the most recent reference data, necessary for the understanding of the economy of this sector. (J.S.)

Origin of carbonate concretions from mud mounds in the Gulf of Cadiz (SW Iberian Peninsula); Origen de las concreciones carbonatadas de los monticulos de fango en el Golfo de Cadiz (SO Peninsula Iberica)

Energy Technology Data Exchange (ETDEWEB)

Rejas, M.; Taberner, C.; Pueyo, J. J.; Giralt, S.; Mata, M. P.; Gibert, J. M. de; Diaz del Rio, V.

2015-07-01

The Gulf of Cadiz displays a number of structures that are associated with fluid circulation (mud volcanoes, mud mounds and pockmarks).This area has been used as natural laboratory for the sedimentological, bio- logical and biogeochemical studies of these environments. Analysis of the associated authigenic carbonates has been widely used as a proxy to yield insights into the circulation and chemical composition of these flu- ids. A study of carbonate concretions from the Iberico, Cornide and Arcos mud mounds in the Diasom Field was undertaken to better understand the origin and type of fluids from which these concretions precipitated. The concretions display varying morphologies, some of which correspond to bioturbation traces. X-ray dif- fractions revealed that these carbonate concretions are mainly composed of dolomite, Fe-rich dolomite, high magnesium calcite (HMC) and ankerite. The δ{sup 1}3 C values of carbonate minerals ranged between -48.3 and-10.9 V-PDB, which suggests that the main processes involved in their genesis are organic matter oxidation, bac- terial sulphate-reduction (BSR) and anaerobic methane oxidation (AOM). The origin of the methane is main- ly thermogenic, and only few concretions yielded δ{sup 1}3C values lower than -40 V-PDB, suggesting oxidation of microbial methane. Fluids involved in the carbonate precipitation are interpreted as being related to gas hydrate destabilisation (δ{sup 18}O fluid-V-SMOW values higher than +2%) and, to a lesser extent, modified seawater enriched in {sup 18}O due to rock-water interaction. Nevertheless, the highest δ{sup 1}8O fluid-V-SMOW values suggest that the influence of other deep-seated fluids due to clay-mineral dehydration cannot be ruled out. (Author)

Source and impact of lead contamination on {delta}-aminolevulinic acid dehydratase activity in several marine bivalve species along the Gulf of Cadiz

Energy Technology Data Exchange (ETDEWEB)

Company, R.; Serafim, A.; Lopes, B.; Cravo, A. [CIMA, University of Algarve, Campus de Gambelas, 8005-139 Faro (Portugal); Kalman, J.; Riba, I.; DelValls, T.A. [Catedra UNESCO/UNITWIN/WiCop, Department of Physical-Chemistry, Faculty Marine and Environmental Sciences, University of Cadiz, 11510 Puerto Real, Cadiz (Spain); Blasco, J. [Instituto Ciencias Marinas Andalucia (CSIC), Campus Rio San Pedro, 11510 Puerto Real, Cadiz (Spain); Delgado, J. [Department of Geology, University of Huelva, Avda Fuerzas Armadas s/n, 21071 Huelva (Spain); Sarmiento, A.M. [Catedra UNESCO/UNITWIN/WiCop, Department of Physical-Chemistry, Faculty Marine and Environmental Sciences, University of Cadiz, 11510 Puerto Real, Cadiz (Spain); Department of Geology, University of Huelva, Avda Fuerzas Armadas s/n, 21071 Huelva (Spain); Nieto, J.M. [Department of Geology, University of Huelva, Avda Fuerzas Armadas s/n, 21071 Huelva (Spain); Shepherd, T.J.; Nowell, G. [Department of Earth Sciences, University of Durham, Science Laboratories, Durham DH1 3LE (United Kingdom); Bebianno, M.J., E-mail: mbebian@ualg.pt [CIMA, University of Algarve, Campus de Gambelas, 8005-139 Faro (Portugal)

2011-01-17

Coastal areas and estuaries are particularly sensitive to metal contamination from anthropogenic sources and in the last few decades the study of space-time distribution and variation of metals has been extensively researched. The Gulf of Cadiz is no exception, with several rivers draining one of the largest concentrations of sulphide deposits in the world, the Iberian Pyrite Belt (IPB). Of these rivers, the Guadiana, one of the most important in the Iberian Peninsula, together with smaller rivers like the Tinto and Odiel, delivers a very high metal load to the adjacent coastal areas. The purpose of this work was to study the source and impact of lead (Pb) drained from historical or active mining areas in the IPB on the activity of a Pb inhibited enzyme ({delta}-aminolevulinic acid dehydratase, ALAD) in several bivalve species along the Gulf of Cadiz. Seven marine species (Chamelea gallina, Mactra corallina, Donax trunculus, Cerastoderma edule, Mytilus galloprovincialis, Scrobicularia plana and Crassostrea angulata) were collected at 12 sites from Mazagon, near the mouth of the rivers Tinto and Odiel (Spain), to Cacela Velha (Ria Formosa lagoon system, Portugal). Lead concentrations, ALAD activity and lead isotope ratios ({sup 206}Pb/{sup 204}Pb, {sup 207}Pb/{sup 204}Pb and {sup 208}Pb/{sup 204}Pb) were determined in the whole soft tissues. The highest Pb concentrations were determined in S. plana (3.50 {+-} 1.09 {mu}g g{sup -1} Pb d.w.) and D. trunculus (1.95 {+-} 0.10 {mu}g g{sup -1} Pb d.w.), while M. galloprovincialis and C. angulata showed the lowest Pb levels (<0.38 {mu}g g{sup -1} Pb d.w.). In general, ALAD activity is negatively correlated with total Pb concentration. However this relationship is species dependent (e.g. linear for C. gallina ALAD = -0.36[Pb] + 0.79; r = 0.837; or exponential for M. galloprovincialis ALAD = 2.48e{sup -8.3[Pb]}; r = 0.911). This indicates that ALAD activity has considerable potential as a biomarker of Pb and moreover, in

Source and impact of lead contamination on δ-aminolevulinic acid dehydratase activity in several marine bivalve species along the Gulf of Cadiz

International Nuclear Information System (INIS)

Company, R.; Serafim, A.; Lopes, B.; Cravo, A.; Kalman, J.; Riba, I.; DelValls, T.A.; Blasco, J.; Delgado, J.; Sarmiento, A.M.; Nieto, J.M.; Shepherd, T.J.; Nowell, G.; Bebianno, M.J.

2011-01-01

Coastal areas and estuaries are particularly sensitive to metal contamination from anthropogenic sources and in the last few decades the study of space-time distribution and variation of metals has been extensively researched. The Gulf of Cadiz is no exception, with several rivers draining one of the largest concentrations of sulphide deposits in the world, the Iberian Pyrite Belt (IPB). Of these rivers, the Guadiana, one of the most important in the Iberian Peninsula, together with smaller rivers like the Tinto and Odiel, delivers a very high metal load to the adjacent coastal areas. The purpose of this work was to study the source and impact of lead (Pb) drained from historical or active mining areas in the IPB on the activity of a Pb inhibited enzyme (δ-aminolevulinic acid dehydratase, ALAD) in several bivalve species along the Gulf of Cadiz. Seven marine species (Chamelea gallina, Mactra corallina, Donax trunculus, Cerastoderma edule, Mytilus galloprovincialis, Scrobicularia plana and Crassostrea angulata) were collected at 12 sites from Mazagon, near the mouth of the rivers Tinto and Odiel (Spain), to Cacela Velha (Ria Formosa lagoon system, Portugal). Lead concentrations, ALAD activity and lead isotope ratios ( 206 Pb/ 204 Pb, 207 Pb/ 204 Pb and 208 Pb/ 204 Pb) were determined in the whole soft tissues. The highest Pb concentrations were determined in S. plana (3.50 ± 1.09 μg g -1 Pb d.w.) and D. trunculus (1.95 ± 0.10 μg g -1 Pb d.w.), while M. galloprovincialis and C. angulata showed the lowest Pb levels ( -1 Pb d.w.). In general, ALAD activity is negatively correlated with total Pb concentration. However this relationship is species dependent (e.g. linear for C. gallina ALAD = -0.36[Pb] + 0.79; r = 0.837; or exponential for M. galloprovincialis ALAD = 2.48e -8.3[Pb] ; r = 0.911). This indicates that ALAD activity has considerable potential as a biomarker of Pb and moreover, in marine bivalve species with different feeding habits. Lead isotope data

Fishery and life history of spot-tail mantis shrimp, Squilla mantis (Crustacea: Stomatopoda, in the Gulf of Cadiz (eastern central Atlantic

Directory of Open Access Journals (Sweden)

Yolanda Vila

2013-03-01

Full Text Available Squilla mantis is an economically important species that is mainly caught by the Sanlucar de Barrameda bottom trawl fleet in the Gulf of Cadiz (eastern central Atlantic. Annual landings have ranged between 24 t in 1999 and 600 t in 2003, with a mean value of 269 t for the period 1984-2010. Catches have a marked seasonality, peaking in winter and showing the lowest values in summer. Larval abundance was negatively correlated with depth and distance from the coast but positively correlated with sea surface temperature. No correlation with sea surface salinity was found. The highest larval abundance was observed in June at 20-25 m depth, while adults were mostly found at 30-35 m depth. This species is mainly concentrated in the area of influence of the Guadalquivir River but is very scarce in the rest of the study area. The maturation of the ovary and the activity of the sexual accessory glands begin in early winter. The population is age-structured in three year classes and females reach first maturity within the second year class, at 23.7 mm carapace length.

Characterization of High Thermal Conductivity Carbon Fibers and a Self-Reinforced Graphite Panel

National Research Council Canada - National Science Library

Adams, P

1998-01-01

... (XRD) and high-resolution field emission (FE) scanning electron microscopy (SEM). Of the four experimental fibers, two were produced from Amoco's standard petroleum pitch, and two were produced from an Amoco experimental pitch precursor...

Area near Monkman, B.C., becoming world class exploration play, BP says

International Nuclear Information System (INIS)

Anon.

1992-01-01

This paper reports on two major oil companies in the western Canada sedimentary basin which have completed several significant gas discoveries, including a well with one of the highest flow rates ever in Canada. BP Canada Inc. completed discoveries at its Brazion and Burnt River wells in the Monkman area of northeastern British Columbia. The Monkman area is developing into a world class natural gas exploration play. Meanwhile, Amoco Canada Petroleum Co. Ltd. completed four Alberta gas discoveries in 1991 and participated with BP and PetroCanada Inc. in four British Columbia discoveries

Enrichment of sulfate reducing anaerobic methane oxidizing community dominated by ANME-1 from Ginsburg Mud Volcano (Gulf of Cadiz) sediment in a biotrickling filter.

Science.gov (United States)

Bhattarai, Susma; Cassarini, Chiara; Rene, Eldon R; Zhang, Yu; Esposito, Giovanni; Lens, Piet N L

2018-07-01

This study was performed to enrich anaerobic methane-oxidizing archaea (ANME) present in sediment from the Ginsburg Mud Volcano (Gulf of Cadiz) in a polyurethane foam packed biotrickling filter (BTF). The BTF was operated at 20 (±2) °C, ambient pressure with continuous supply of methane for 248 days. Sulfate reduction with simultaneous sulfide production (accumulating ∼7 mM) after 200 days of BTF operation evidenced anaerobic oxidation of methane (AOM) coupled to sulfate reduction. High-throughput sequence analysis of 16S rRNA genes showed that after 248 days of BTF operation, the ANME clades enriched to more than 50% of the archaeal sequences, including ANME-1b (40.3%) and ANME-2 (10.0%). Enrichment of the AOM community was beneficial to Desulfobacteraceae, which increased from 0.2% to 1.8%. Both the inoculum and the BTF enrichment contained large populations of anaerobic sulfur oxidizing bacteria, suggesting extensive sulfur cycling in the BTF. Copyright © 2018 Elsevier Ltd. All rights reserved.

Service alliances : new oilfield partnership techniques cut costs, put expertise to better use

International Nuclear Information System (INIS)

Curran, R.

1997-01-01

The co-operative relationship that is needed between service providers and oil companies was discussed. Oil exploration and oil production companies rely on members of the Petroleum Services Association of Canada (PSAC) for a wide range of specialties such as production testing, cementing and well stimulation, wireline data recording and perforating, drilling and completions, specialized trucking, pipe coating and inspection, blowout prevention, coring and tong services. For example, the Dowell division of Schlumberger Canada Ltd. has had long-term alliances with PanCanadian Petroleum Ltd., Chevron Canada Resources, Amoco Canada Petroleum Co., Suncor Energy Inc., Talisman Energy Inc., and Petro-Canada. Both the service providers and the oil companies work collaboratively to determine which processes should be used to achieve cost-cutting efficiency. The exchange of technological ideas is a definite advantage. In much the same manner, the Dominion Supply Co., (DOSCO) provides a wide variety of equipment and supplies to exploration and production firms, drilling contractors, and service contractors in the petroleum industry. 3 figs

The big bitumen breakthrough

International Nuclear Information System (INIS)

Koch, G.

1996-01-01

The ongoing transformation of the oilsands and heavy oil sector from a poor cousin a few years ago into the cornerstone of the Alberta oil industry, was discussed. Much of this change is due to the development of SAGD (steam assisted gravity drainage) technology for the underground recovery of heavy oil and tarry bitumens, aided by partly government-funded research, and boosted by a revised provincial royalty regime. The thermal recovery process makes use of a pair of horizontal injection and recovery wells, drilled one above the other. The efficiency of this new technology could produce a shift in the petroleum industry's spending towards oil sands and heavy oil if investors conclude that it is more profitable to produce heavy oil than conventional light oil. Some of the oil sands producers that are poised to invest billions of dollars in various underground bitumen projects in Alberta over the next five years include Suncor, Syncrude, Alberta Energy Co., Amoco Canada, Elan Energy, Imperial Oil Resources, CS Resources, Koch Oil, and Gulf Resources. The ultimate goal is recovery costs of $6 per barrel, which is comparable to the costs of the conventional oil sector. The added advantage of oil sands production is, of course, the virtual elimination of the exploration risk. 3 figs

Sedimentary infilling of bedrock-controlled palaeo-embayments off Cape Trafalgar, Strait of Gibraltar (Gulf of Cadiz)

Science.gov (United States)

de Castro, Sandra; Lobo, Francisco J.

2018-02-01

This study investigates two bedrock-controlled palaeo-coastal embayments on the Barbate Platform off Cape Trafalgar near the Strait of Gibraltar (Gulf of Cadiz shelf, SW Iberian Peninsula), aiming to reveal their infilling dynamics and the influence of rocky outcrops on shallow-water hydrodynamics and sediment transport. The approach relies on detailed multibeam bathymetric data, high-resolution seismic profiles and tidal current simulations. Elongated rocky outcrops formed a palaeo-coast when sea level was approximately 35 to 20 m below that of the present day, and bound a relatively flat area. However, the seismic profiles enabled to distinguish two main troughs (A and B) that were infilled following a distinctive evolution during the last transgression. Five seismic units were identified (I to V, from base to top). Deposit A is composed of seismic units II to V and is interpreted as a marine embayment infill, here termed the Barbate palaeo-embayment (BPE). Deposit B is composed of seismic units I to IV and is interpreted as a palaeo-valley infill, here termed the Barbate palaeo-valley (BPV). The complex internal stratigraphic architecture depicts an overall evolution from tidal/fluvial deposits to shallow-water marine deposits. Most significant is the occurrence of coupled tidal flats/estuarine sand bars constituting the infilling of the BPE; this suggests the persistence of a high-energy current in a shallow, confined embayment, which was amplified by the rocky outcrop constrictions and possibly facilitated by the episodic movement of a normal fault. In contrast to this active setting, the nearby straight and narrow BPV was subjected to lower-energy infilling dynamics during its initial flooding phases. There, tidal activity was possibly reduced by the straight morphology of the valley and the occurrence of a topographic constriction (i.e. the Barbate Passage) at the mouth of the valley.

Diet of bottlenose dolphins (Tursiops truncatus from the Gulf of Cadiz: Insights from stomach content and stable isotope analyses.

Directory of Open Access Journals (Sweden)

Joan Giménez

Full Text Available The ecological role of species can vary among populations depending on local and regional differences in diet. This is particularly true for top predators such as the bottlenose dolphin (Tursiops truncatus, which exhibits a highly varied diet throughout its distribution range. Local dietary assessments are therefore critical to fully understand the role of this species within marine ecosystems, as well as its interaction with important ecosystem services such as fisheries. Here, we combined stomach content analyses (SCA and stable isotope analyses (SIA to describe bottlenose dolphins diet in the Gulf of Cadiz (North Atlantic Ocean. Prey items identified using SCA included European conger (Conger conger and European hake (Merluccius merluccius as the most important ingested prey. However, mass-balance isotopic mixing model (MixSIAR, using δ13C and δ15N, indicated that the assimilated diet consisted mainly on Sparidae species (e.g. seabream, Diplodus annularis and D. bellottii, rubberlip grunt, Plectorhinchus mediterraneus, and common pandora, Pagellus erythrinus and a mixture of other species including European hake, mackerels (Scomber colias, S. japonicus and S. scombrus, European conger, red bandfish (Cepola macrophthalma and European pilchard (Sardina pilchardus. These contrasting results highlight differences in the temporal and taxonomic resolution of each approach, but also point to potential differences between ingested (SCA and assimilated (SIA diets. Both approaches provide different insights, e.g. determination of consumed fish biomass for the management of fish stocks (SCA or identification of important assimilated prey species to the consumer (SIA.

Investing in CIS: obstacles and strategies

International Nuclear Information System (INIS)

Anon.

1996-01-01

The CIS (Community of Independent States) needs the help of foreign investments to develop its huge hydrocarbon potentialities. Because of the uncertainties concerning the legal and fiscal context of their activities, the role of the international oil companies has remained limited so far. These problems were discussed in May 1996 during an important ''General Session'' of the OTC 96 congress. Proven and explored onshore oil reserves in Russia are enormous, in particular in Western and Eastern Siberia. However, the economically most interesting resources are located in the offshore zones of the Barents, Pechora and Kara seas and of Eastern Siberia and Okhotsk. This paper describes the last years decay of oil production in CIS and its causes, in particular the obstacles to foreign investments (exportation and transport taxes), the recent contracts and joint-ventures with American major companies (Exxon, Amoco..), and the situation of the Russian industry in petroleum engineering and field exploitation materials. (J.S.)

An investigation of multi-rate sound decay under strongly non-diffuse conditions: The crypt of the Cathedral of Cadiz

Science.gov (United States)

Martellotta, Francesco; Álvarez-Morales, Lidia; Girón, Sara; Zamarreño, Teófilo

2018-05-01

Multi-rate sound decays are often found and studied in complex systems of coupled volumes where diffuse field conditions generally apply, although the openings connecting different sub-spaces are by themselves potential causes of non-diffuse behaviour. However, in presence of spaces in which curved surfaces clearly prevent diffuse field behaviour from being established, things become more complex and require more sophisticated tools (or, better, combinations of them) to be fully understood. As an example of such complexity, the crypt of the Cathedral of Cadiz is a relatively small space characterised by a central vaulted rotunda, with five radial galleries with flat and low ceiling. In addition, the crypt is connected to the main cathedral volume by means of several small openings. Acoustic measurements carried out in the crypt pointed out the existence of at least two decay processes combined, in some points, with flutter echoes. Application of conventional methods of analysis pointed out the existence of significant differences between early decay time and reverberation time, but was inconclusive in explaining the origin of the observed phenomena. The use of more robust Bayesian analysis permitted the conclusion that the late decay appearing in the crypt had a different rate than that observed in the cathedral, thus excluding the explanation based on acoustic coupling of different volumes. Finally, processing impulse responses collected by means of a B-format microphone to obtain directional intensity maps demonstrated that the late decay was originated from the rotunda where a repetitive reflection pattern appeared between the floor and the dome causing both flutter echoes and a longer reverberation time.

Technical developments in other industries and right-sizing of organizations. A retrospective view of corporate down sizing in the U.S

International Nuclear Information System (INIS)

Kragness, M.E.

1994-01-01

The conference paper deals with the Amoco sweeping plan to boost profits and expand operations in US. The company refocused its oil exploration strategy and sought a cultural transformation within the organization in addition to cutting payroll. The paper offers background to help understanding why corporate downsizing has become a popular and perhaps necessary management strategy using the collective experience of many U.S. companies to examine how downsizing has occurred and its human and financial consequences. The paper offers several approaches to workforce management, which address the need to increase employee productivity and corporate profits while minimizing the human and financial costs of layoffs. 40 refs

Technical developments in other industries and right-sizing of organizations. A retrospective view of corporate down sizing in the U.S

Energy Technology Data Exchange (ETDEWEB)

Kragness, M E [ROI Consultants, Inc., Minneapolis, MN (United States)

1994-12-31

The conference paper deals with the Amoco sweeping plan to boost profits and expand operations in US. The company refocused its oil exploration strategy and sought a cultural transformation within the organization in addition to cutting payroll. The paper offers background to help understanding why corporate downsizing has become a popular and perhaps necessary management strategy using the collective experience of many U.S. companies to examine how downsizing has occurred and its human and financial consequences. The paper offers several approaches to workforce management, which address the need to increase employee productivity and corporate profits while minimizing the human and financial costs of layoffs. 40 refs.

Effectiveness of olive oil for the prevention of pressure ulcers caused in immobilized patients within the scope of primary health care: study protocol for a randomized controlled trial.

Science.gov (United States)

Lupiáñez-Pérez, Inmaculada; Morilla-Herrera, Juan Carlos; Ginel-Mendoza, Leovigildo; Martín-Santos, Francisco Javier; Navarro-Moya, Francisco Javier; Sepúlveda-Guerra, Rafaela Pilar; Vázquez-Cerdeiros, Rosa; Cuevas-Fernández-Gallego, Magdalena; Benítez-Serrano, Isabel María; Lupiáñez-Pérez, Yolanda; Morales-Asencio, José Miguel

2013-10-23

Pressure ulcers are considered an important issue, mainly affecting immobilized older patients. These pressure ulcers increase the care burden for the professional health service staff as well as pharmaceutical expenditure. There are a number of studies on the effectiveness of different products used for the prevention of pressure ulcers; however, most of these studies were carried out at a hospital level, basically using hyperoxygenated fatty acids (HOFA). There are no studies focused specifically on the use of olive-oil-based products and therefore this research is intended to find the most cost-effective treatment and achieve an alternative treatment. The main objective is to assess the effectiveness of olive oil, comparing it with HOFA, to treat immobilized patients at home who are at risk of pressure ulcers. As a secondary objective, the cost-effectiveness balance of this new application with regard to the HOFA will be assessed. The study is designed as a noninferiority, triple-blinded, parallel, multi-center, randomized clinical trial. The scope of the study is the population attending primary health centers in Andalucía (Spain) in the regional areas of Malaga, Granada, Seville, and Cadiz. Immobilized patients at risk of pressure ulcers will be targeted. The target group will be treated by application of an olive-oil-based formula whereas the control group will be treated by application of HOFA to the control group. The follow-up period will be 16 weeks. The main variable will be the presence of pressure ulcers in the patient. Secondary variables include sociodemographic and clinical information, caregiver information, and whether technical support exists. Statistical analysis will include the Kolmogorov-Smirnov test, symmetry and kurtosis analysis, bivariate analysis using the Student's t and chi-squared tests as well as the Wilcoxon and the Man-Whitney U tests, ANOVA and multivariate logistic regression analysis. The regular use of olive-oil-based formulas

Planning for high performance project teams

International Nuclear Information System (INIS)

Reed, W.; Keeney, J.; Westney, R.

1997-01-01

Both industry-wide research and corporate benchmarking studies confirm the significant savings in cost and time that result from early planning of a project. Amoco's Team Planning Workshop combines long-term strategic project planning and short-term tactical planning with team building to provide the basis for high performing project teams, better project planning, and effective implementation of the Amoco Common Process for managing projects

Transesterification of jojoba oil, sunflower oil, neem oil, rocket seed oil and linseed oil by tin catalysts

International Nuclear Information System (INIS)

Shah, Mazloom; Tariq, Muhammad; Ali, Saqib; Guo, Qing-Xiang; Fu, Yao

2014-01-01

The methanolysis of jojoba oil has been studied in the presence of tin powder, dibutyltin diacetate (C 4 H 9 ) 2 Sn(OOCCH 3 ) 2 , dioctyltin diacetate (C 8 H 17 ) 2 Sn(OOCCH 3 ) 2 , dibutyltin oxide (C 4 H 9 ) 2 SnO, dioctyltin oxide (C 8 H 17 ) 2 SnO, diphenyltin oxide (C 6 H 5 ) 2 SnO, dibutyltin chloride dihydroxide (C 4 H 9 ) 2 Sn(OH) 2 Cl, butyltinhydroxide hydrate (C 4 H 9 )Sn(=O)OH.xH 2 O, Ni nanoparticles and Pd nanoparticles act as catalysts. Among these, 1 weight % of dibutyltin diacetate shows the maximum conversion. Then, methanolysis of sunflower oil, neem oil, rocket seed oil and linseed oil into methyl esters studied in the presence of 1% dibutyltin diacetate as a catalyst and was compared their percentage conversions. The experimental yield for the conversion of jojoba oil, sunflower oil, neem oil, rocket seed oil and linseed oil into biodiesel was found to be 71%, 51%, 50.78%, 40.90% and 39.66%, respectively. The experimental yield of the conversion of jojoba oil into methyl esters was found to be increased up to 96% by increasing reaction time, without emulsion formation. The synthesis of jojoba seed oil biodiesel (JSOB), soybean oil biodiesel (SOB), neem oil biodiesel (NOB), rocket seed oil biodiesel (RSOB) and linseed oil biodiesel (LSOB) was confirmed by NMR ( 1 H and 13 C) and FT-IR analyses of biodiesel. - Highlights: • Transesterification of jojoba oil into biodiesel by tin and nano catalysts. • 1 weight % dibutyltin diacetate showed highest yield at 60 °C. • Catalytic conversion comparison of five oils using dibutyltin diacetate • The experimental yield of the conversion of jojoba oil increased with time. • FT-IR and NMR ( 1 H and 13 C) characterization

Treatment of uncertainties in the existence of free berths with risk analysis techniques. Establishment of policies in port of Cadiz (SPAIN)

Energy Technology Data Exchange (ETDEWEB)

Awad Nuñez, S.; Camarero Orive, A.; Romero Sanchez-Brunete, M.; Camarero Orive, A.; Gonzalez Cancelas, N.

2016-07-01

This research discusses the challenges involved in the treatment of uncertainties in the existence of free berths during the arrival of cruise ships at seaports. Pursuing this goal, a three-step methodology is adopted: 1) Identifying risk sources and critical risk variables and how they are related; 2) Fitting the Probability Distribution Functions that best represent the behaviour of each critical risk variable; and 3) Simulating the probability of a ship having to wait because there are no free berths using a technique that combines statistical concepts (random sampling) with the ability of computers to generate pseudo-random numbers and automate estimations of the values of the set of critical risk variables. The innovative use of risk analysis techniques in this field allows the establishment of policies to improve the planning and management of port infrastructure, for example, deciding when it is necessary to work to increase the number of berths. As a case of study, we applied this methodology to study whether the enlargement of the wharf in the port of Cadiz (Spain) is necessary right now considering the number of cruise ships that have arrived at the port in the past three years, their date and hour of arrival, their length and draught, the duration of their stay in port and their waiting time before being able to enter the port. This action would require moving logistics activities to a new terminal, but would bring to the city the opportunity to rethink the seafront, introducing new cruiser links with the city centre and developing a better seaport-city integration. (Author)

Creating field management information systems using microsoft{reg_sign} software

Energy Technology Data Exchange (ETDEWEB)

Handsel-Johnson, P.L.; Schroeder, C.Y.

1995-12-31

A Field management information system (FMIS) was created for the Trinidad Resource Development teams in Amoco`s Intemational Operations Group. This application uses Microsoft Access {reg_sign}2.0 and the other Microsoft Office 4.2 software products. The purpose of this information system is to assist these teams in the management of their producing oil and gas fields. This is accomplished by providing: (1) centralized data storage for a variety of data, such as well, production, engineering and geologic in various forms, including raw, interpreted and derived, (2) customized analysis, planning and reporting tools, such as reservoir performance summaries and dynamic field management plans, and (3) the capability to easily exchange data with a variety of engineering and geoscience analytical software. Additional benefits provided to the Resource Development teams by this approach are: (1) improved data accuracy and accessibility from a centralized, relational database, (2) enhanced efficiency as a result of the application being tailored to the teams` operating environment and work processes, and (3) access to an expanded knowledge base by consolidating information from several fields into one database. In short, this product was developed in response to the Trinidad Resource Development teams` need to improve their data integrity, efficiency and analysis and planning capability. The resultant application is not just a database, but rather, a field management information system.

Seasonal functioning and dynamics of Caulerpa prolifera meadows in shallow areas: An integrated approach in Cadiz Bay Natural Park

Science.gov (United States)

Vergara, Juan J.; García-Sánchez, M. Paz; Olivé, Irene; García-Marín, Patricia; Brun, Fernando G.; Pérez-Lloréns, J. Lucas; Hernández, Ignacio

2012-10-01

The rhizophyte alga Caulerpa prolifera thrives in dense monospecific stands in the vicinity of meadows of the seagrass Cymodocea nodosa in Cadiz Bay Natural Park. The seasonal cycle of demographic and biometric properties, photosynthesis, and elemental composition (C:N:P) of this species were monitored bimonthly from March 2004 to March 2005. The number of primary assimilators peaked in spring as consequence of the new recruitment, reaching densities up to 104 assimilators·m-2. A second peak was recorded in late summer, with a further decrease towards autumn and winter. Despite this summer maximum, aboveground biomass followed a unimodal pattern, with a spring peak about 400 g dry weight·m-2. In conjunction to demographic properties of the population, a detailed biometric analysis showed that the percentage of assimilators bearing proliferations and the number of proliferations per assimilator were maximal in spring (100% and c.a. 17, respectively), and decreased towards summer and autumn. The size of the primary assimilators was minimal in spring (May) as a result of the new recruitments. However, the frond area per metre of stolon peaked in early spring and decreased towards the remainder of the year. The thallus area index (TAI) was computed from two different, independent approaches which both produced similar results, with a maximum TAI recorded in spring (transient values up to 18 m2·m-2). The relative contribution of primary assimilators and proliferations to TAI was also assessed. Whereas the number of proliferations accounted for most of the TAI peak in spring, its contribution decreased during the year, to a minimum in winter, where primary assimilators were the main contributors to TAI. The present study represents the first report of the seasonal dynamics of C. prolifera in south Atlantic Spanish coasts, and indicates the important contribution of this primary producer in shallow coastal ecosystems.

Vertical distribution of major, minor and trace elements in sediments from mud volcanoes of the Gulf of Cadiz: evidence of Cd, As and Ba fronts in upper layers

Science.gov (United States)

Carvalho, Lina; Monteiro, Rui; Figueira, Paula; Mieiro, Cláudia; Almeida, Joana; Pereira, Eduarda; Magalhães, Vítor; Pinheiro, Luís; Vale, Carlos

2018-01-01

Mud volcanoes are feature of the coastal margins where anaerobic oxidation of methane triggers geochemical signals. Elemental composition, percentage of fine particles and loss on ignition were determined in sediment layers of eleven gravity cores retrieved from four mud volcanoes (Sagres, Bonjardim, Soloviev and Porto) and three undefined structures located on the deep Portuguese margin of the Gulf of Cadiz. Calcium was positively correlated to Sr and inversely to Al as well as to most of the trace elements. Vertical profiles of Ba, Cd and As concentrations, and their ratios to Al, in Porto and Soloviev showed pronounced enhancements in the top 50-cm depth. Sub-surface enhancements were less pronounced in other mud volcanoes and were absent in sediments from the structures. These profiles were interpreted as diagenetic enrichments related to the anaerobic oxidation of methane originated from upward methane-rich fluxes. The observed barium fronts were most likely caused by the presence of barite which precipitated at the sulphate-methane transition zone. Cd and As enrichments have probably resulted from successive dissolution/precipitation of sulphides in response to vertical shifts of redox boundaries.

Metal working oils. Cutting oils, rolling oils, quenching oils, rust preventive oils; Kinzoku kakoyu. Sessakuyu, atsuenyu, yakiireyu, boseiyu

Energy Technology Data Exchange (ETDEWEB)

Koyama, S. [Idemitsu Kosan Co. Ltd., Tokyo (Japan)

1996-04-01

With the demand against complicating working techniques for a background, foundations of the consideration for each of the lubricants in future are outlined. 1. Cutting oils: From the standpoint of speeding up and fireproofing, share of water-soluble type has come up to 30-40%. In this type, emulsifying dispersants and preservatives are combined. 2. Rolling oils: According to thinning of the standard thickness of steel plates, pressure of contacting surfaces has come up to 300 kg/mm{sup 2}(max.) and slip speed has increased too. In stainless steel plates, in order to get rid of the heat-streak (baking streak originated from wearing-out of oil film) shifting from neat oil to emulsion type is required. 3. Quenching oils: Following two systems are recent tendencies, the mineral oil system having excellent thermostability or the water system containing polyalkylneglycol etc., but the latter is expected from the viewpoint of fireproofing. 4. Rust preventive oils: As this oils do not aim at the rust prevention for long term, degreasing property is required. 20 refs., 5 figs., 1 tab.

Making alliances work -- Using a computer-based management system to integrate the supply chain

International Nuclear Information System (INIS)

Johnson, J.B.; Randolph, S.

1995-01-01

Traditionally, price has been king in the selection of suppliers and service companies in the upstream oil and gas market. Three years ago, Amoco began to question this selection practice and embarked on an extensive benchmarking effort that has led the company to a proven strategy for goods and services procurement called supply-chain management (SCM). However, the company found that managing compact, integrated supply chains is not always easy. Several implementation issues need to be reconciled for alliances to achieve their full bottom-line potential benefits consistently. Issues that must be resolved, whether they are called alliances, supply chains, or integrated services, are (1) whether these new working relationships are profitable for all the entities involved, from suppliers through to end users; (2) how to assess and improve risk management; (3) how to reduce total system costs; and (4) how to improve performance for each of the alliance members and for the alliance as a whole. This brief describes one possible solution to the complex issues involved in making alliances work: a computer-facilitated management system designed to integrate the work processes of different organizations. In the case described, the Drilling Management System (DMS) was developed and used by the Amoco (U.K.) Well Dept. The system uses off-the-shelf commercial software to improve the performance of the company's drilling operations by integrating the activities of the company and its suppliers

Seasonal variation of early diagenesis and greenhouse gas production in coastal sediments of Cadiz Bay: Influence of anthropogenic activities

Science.gov (United States)

Burgos, Macarena; Ortega, Teodora; Bohórquez, Julio; Corzo, Alfonso; Rabouille, Christophe; Forja, Jesús M.

2018-01-01

Greenhouse gas production in coastal sediments is closely associated with the early diagenesis processes of organic matter and nutrients. Discharges from anthropogenic activities, particularly agriculture, fish farming and waste-water treatment plants supply large amounts of organic matter and inorganic nutrients that affect mineralization processes. Three coastal systems of Cadiz Bay (SW Spain) (Guadalete River, Rio San Pedro Creek and Sancti Petri Channel) were chosen to determine the seasonal variation of organic matter mineralization. Two sampling stations were selected in each system; one in the outer part, close to the bay, and another more inland, close to a discharge point of effluent related to anthropogenic activities. Seasonal variation revealed that metabolic reactions were driven by the annual change of temperature in the outer station of the systems. In contrast, these reactions depended on the amount of organic matter reaching the sediments in the outermost part of the systems, which was higher during winter. Oxygen is consumed in the first 0.5 cm indicating that suboxic and anoxic processes, such as denitrification, sulfate reduction and methanogenesis are important in these sediments. Sulfate reduction seems to account for most of the mineralization of organic matter at the marine stations, while methanogenesis is the main pathway at the sole freshwater station of this study, located inside the estuary of the Guadalete River, because of the lack of sulfate as electron acceptor. Results point to denitrification being the principal process of N2O formation. Diffusive fluxes varied between 2.6 and 160 mmol m-2 d-1 for dissolved inorganic carbon (DIC); 0.9 and 164.3 mmol m-2 d-1 for TA; 0.8 and 17.4 μmol m-2 d-1 for N2O; and 0.1 μmol and 13.1 mmol m-2 d-1 for CH4, indicating that these sediments act as a source of greenhouse gases to the water column.

Oil vulnerability index of oil-importing countries

International Nuclear Information System (INIS)

Gupta, Eshita

2008-01-01

This paper assesses the relative oil vulnerability of 26 net oil-importing countries for the year 2004 on the basis of various indicators - the ratio of value of oil imports to gross domestic product (GDP), oil consumption per unit of GDP, GDP per capita and oil share in total energy supply, ratio of domestic reserves to oil consumption, exposure to geopolitical oil market concentration risks as measured by net oil import dependence, diversification of supply sources, political risk in oil-supplying countries, and market liquidity. The approach using the principal component technique has been adopted to combine these individual indicators into a composite index of oil vulnerability. Such an index captures the relative sensitivity of various economies towards developments of the international oil market, with a higher index indicating higher vulnerability. The results show that there are considerable differences in the values of individual indicators of oil vulnerability and overall oil vulnerability index among the countries (both inter and intraregional). (author)

Oil vulnerability index of oil-importing countries

Energy Technology Data Exchange (ETDEWEB)

Gupta, Eshita [The Energy and Resources Institute, Darbari Seth Block, Habitat Place, New Delhi 110 003 (India)

2008-03-15

This paper assesses the relative oil vulnerability of 26 net oil-importing countries for the year 2004 on the basis of various indicators - the ratio of value of oil imports to gross domestic product (GDP), oil consumption per unit of GDP, GDP per capita and oil share in total energy supply, ratio of domestic reserves to oil consumption, exposure to geopolitical oil market concentration risks as measured by net oil import dependence, diversification of supply sources, political risk in oil-supplying countries, and market liquidity. The approach using the principal component technique has been adopted to combine these individual indicators into a composite index of oil vulnerability. Such an index captures the relative sensitivity of various economies towards developments of the international oil market, with a higher index indicating higher vulnerability. The results show that there are considerable differences in the values of individual indicators of oil vulnerability and overall oil vulnerability index among the countries (both inter and intraregional). (author)

Giant Oil Fields - The Highway to Oil: Giant Oil Fields and their Importance for Future Oil Production

International Nuclear Information System (INIS)

Robelius, Fredrik

2007-01-01

Since the 1950s, oil has been the dominant source of energy in the world. The cheap supply of oil has been the engine for economic growth in the western world. Since future oil demand is expected to increase, the question to what extent future production will be available is important. The belief in a soon peak production of oil is fueled by increasing oil prices. However, the reliability of the oil price as a single parameter can be questioned, as earlier times of high prices have occurred without having anything to do with a lack of oil. Instead, giant oil fields, the largest oil fields in the world, can be used as a parameter. A giant oil field contains at least 500 million barrels of recoverable oil. Only 507, or 1 % of the total number of fields, are giants. Their contribution is striking: over 60 % of the 2005 production and about 65 % of the global ultimate recoverable reserve (URR). However, giant fields are something of the past since a majority of the largest giant fields are over 50 years old and the discovery trend of less giant fields with smaller volumes is clear. A large number of the largest giant fields are found in the countries surrounding the Persian Gulf. The domination of giant fields in global oil production confirms a concept where they govern future production. A model, based on past annual production and URR, has been developed to forecast future production from giant fields. The results, in combination with forecasts on new field developments, heavy oil and oil sand, are used to predict future oil production. In all scenarios, peak oil occurs at about the same time as the giant fields peak. The worst-case scenario sees a peak in 2008 and the best-case scenario, following a 1.4 % demand growth, peaks in 2018

Oil risk in oil stocks

NARCIS (Netherlands)

Scholtens, Bert; Wang, L

2008-01-01

We assess the oil price sensitivities and oil risk premiums of NYSE listed oil & gas firms' returns by using a two-step regression analysis under two different arbitrage pricing models. Thus, we apply the Fama and French (1992) factor returns in a study of oil stocks. In all, we find that the return

[Grand Banks activity : updates and opportunities

International Nuclear Information System (INIS)

Bruce, G.

1998-01-01

An overview of the exploration and on-going activities by the petroleum industry on the Grand Banks of Newfoundland was presented. The two offshore oil developments underway are Hibernia and Terra Nova, both located in the Jeanne d'Arc Basin. Current production from Hibernia is 68,000 bopd, expected to rise to 130,000 bopd in 1999. The Terra Nova Field is still under development. Total recoverable reserves from the 17 discoveries made in the Jeanne d'Arc Basin are estimated at 1.6 billion barrels of oil and 4 trillion cubic feet of gas. Industry participants in the area include Amoco, Petro-Canada, Mobil, Chevron, Husky and Norsk Hydro. Petro-Canada believes the Grand Banks represent one of the best opportunities for oil anywhere in the world. There are currently 21 exploration licenses held on the Grand Banks. Major attractions of the area include the large reserve potential, the relatively low finding costs, the size of the pools being discovered, improvements in offshore technology that have substantially lowered development costs, and a profit-sensitive generic royalty regime that ensures reasonable rates of return for investors. figs

The North Atlantic Oscillation and sea surface temperature affect loggerhead abundance around the Strait of Gibraltar

Directory of Open Access Journals (Sweden)

José C. Báez

2011-04-01

Full Text Available The aim of this study was to explore the possible link between variations in the North Atlantic Oscillation (NAO and sea surface temperature (SST and the abundance of loggerhead turtles around the Strait of Gibraltar, using stranding data for the Andalusian coastal area as a proxy for abundance. The annual average SST (from November to October in the Gulf of Cadiz was negatively associated with the total number of loggerhead strandings each year from November 1997 to October 2006 in the Gulf of Cadiz and the Alboran Sea. The average NAO index was positively associated with the number of strandings in the Gulf of Cadiz in the following year. Prevailing westerly winds during positive NAO phases and the subsequent delayed decrease in SST may lead to turtles from the west Atlantic accumulating in the Gulf of Cadiz and unsuccessfully attempting to return. Secondary causes, such as buoyancy, cold stunning, longline fisheries, net fisheries, debilitated turtle syndrome, and trauma may also increase the number of turtle strandings.

Vegetable oil spills : oil properties and behaviour

International Nuclear Information System (INIS)

Fingas, M.; Fieldhouse, B.; Jokuty, P.

2001-01-01

In 1997, the United States Environmental Protection Agency conducted a thorough review of the issue regarding vegetable oil spills. Recent attention has refocused on this issue as a result of an incident where 20 tons of canola oil was spilled in the Vancouver Harbour in 2000. In the past, vegetable oils were suggested to be a useful test material because they were thought to be innocuous. It was even suggested they be used to remove petroleum oil residues from beaches. However, recent studies have shown that spills of vegetable oils can have major environmental consequences, equivalent to those of petroleum oil spills. The spills have devastating effects on birds and intertidal organisms. This paper presented a summary of historical vegetable spills from around the world. In this study, specific behaviour tests were examined for several oils including canola, soy bean, olive, castor and corn oils. Evaporation, water-in-oil emulsification and chemical dispersion were measured and were found to be nearly zero, suggesting that vegetable oil spills are not very soluble in water. The aquatic toxicity of vegetable oil is low, but their fate is quite different from petroleum. Vegetable oils do not evaporate to a significant degree, they do not form water-in-oil emulsions, nor do they disperse in water. The physical properties of vegetable oils were also measured, including density and viscosity. This paper presented the aquatic toxicity of several vegetable oils along with other environmental data including the degradation rates noted in the literature. Most environmental damage reported in the literature is by contact with birds feathers resulting in hypothermia and secondly by smothering of intertidal organisms. The effect of vegetable oil on fish has not been well studied, but it is expected that there will be little destructive effect except where smothering can occur. 35 refs., 3 tabs

Vegetable oil spills : oil properties and behaviour

Energy Technology Data Exchange (ETDEWEB)

Fingas, M.; Fieldhouse, B.; Jokuty, P. [Environment Canada, Ottawa, ON (Canada). Emergencies Science Div

2001-07-01

In 1997, the United States Environmental Protection Agency conducted a thorough review of the issue regarding vegetable oil spills. Recent attention has refocused on this issue as a result of an incident where 20 tons of canola oil was spilled in the Vancouver Harbour in 2000. In the past, vegetable oils were suggested to be a useful test material because they were thought to be innocuous. It was even suggested they be used to remove petroleum oil residues from beaches. However, recent studies have shown that spills of vegetable oils can have major environmental consequences, equivalent to those of petroleum oil spills. The spills have devastating effects on birds and intertidal organisms. This paper presented a summary of historical vegetable spills from around the world. In this study, specific behaviour tests were examined for several oils including canola, soy bean, olive, castor and corn oils. Evaporation, water-in-oil emulsification and chemical dispersion were measured and were found to be nearly zero, suggesting that vegetable oil spills are not very soluble in water. The aquatic toxicity of vegetable oil is low, but their fate is quite different from petroleum. Vegetable oils do not evaporate to a significant degree, they do not form water-in-oil emulsions, nor do they disperse in water. The physical properties of vegetable oils were also measured, including density and viscosity. This paper presented the aquatic toxicity of several vegetable oils along with other environmental data including the degradation rates noted in the literature. Most environmental damage reported in the literature is by contact with birds feathers resulting in hypothermia and secondly by smothering of intertidal organisms. The effect of vegetable oil on fish has not been well studied, but it is expected that there will be little destructive effect except where smothering can occur. 35 refs., 3 tabs.

Converting heavy oils into light oils, etc

Energy Technology Data Exchange (ETDEWEB)

Mony, H

1915-12-22

A process is described for transforming heavy oils obtained by the carbonization of lignites, peats, coals, shales into light oils, and also the heavy oils of mineral and vegetable origin, consisting of heating the heavy oils or tars in the presence of one or more solid substances or liquids suitably chosen to cause the distillation of the oils under atmospheric pressure at an appropriate temperature; solid and liquid substances which favor the production of light products under the influence of heat being added preferably to the oil to be treated before putting it in the retort and before heating, so that light oils are obtained by treatment of the heavy oils in a single operation.

Iranian-Oil-Free Zone and international oil prices

International Nuclear Information System (INIS)

Farzanegan, Mohammad Reza; Raeisian Parvari, Mozhgan

2014-01-01

One of the main elements of economic sanctions against Iran due to its nuclear and military programs is crude oil exportation restrictions in addition to investment in Iranian energy related projects. Senders of such sanction are interested in understanding the impacts of such embargos on international oil prices. We apply unrestricted vector autoregressive (VAR) model, using impulse response functions (IRF) and variance decomposition analysis (VDA) tools with annual data from 1965 to 2012 to analyze the dynamic response of international oil prices to Iranian oil export sanction. Controlling for the supply of non-Iranian oil, the world GDP per capita, and post-Islamic revolution exogenous dummy variables, we show that international oil prices respond negatively and statistically significant to increasing shock in absolute negative changes of the Iranian oil exports – our proxy of Iran oil sanctions – following the first 2 years after shock. The main reason is the positive response of the non-Iranian oil supply to negative shocks in Iranian oil exports, filling the missing supply of Iranian oil in international markets. - Highlights: • We analyze the interconnections between Iranian oil supply and global oil prices. • We use VAR modeling and annual data from 1965 to 2012 for the case of Iran. • There are no inflationary effects of Iranian oil sanction on world oil prices. • Non-Iranian oil supply offsets the missing Iranian oil in the market

Mineralogical and geochemical study of mud volcanoes in north ...

African Journals Online (AJOL)

The gulf of Cadiz is one of the most interesting areas to study mud volcanoes and structures related to cold fluid seeps since their discovery in 1999. In this study, we present results from gravity cores collected from Ginsburg and Meknes mud volcanoes and from circular structure located in the gulf of Cadiz (North Atlantic ...

Green bio-oil extraction for oil crops

Science.gov (United States)

Zainab, H.; Nurfatirah, N.; Norfaezah, A.; Othman, H.

2016-06-01

The move towards a green bio-oil extraction technique is highlighted in this paper. The commonly practised organic solvent oil extraction technique could be replaced with a modified microwave extraction. Jatropha seeds (Jatropha curcas) were used to extract bio-oil. Clean samples were heated in an oven at 110 ° C for 24 hours to remove moisture content and ground to obtain particle size smaller than 500μm. Extraction was carried out at different extraction times 15 min, 30 min, 45 min, 60 min and 120 min to determine oil yield. The biooil yield obtained from microwave assisted extraction system at 90 minutes was 36% while that from soxhlet extraction for 6 hours was 42%. Bio-oil extracted using the microwave assisted extraction (MAE) system could enhance yield of bio-oil compared to soxhlet extraction. The MAE extraction system is rapid using only water as solvent which is a nonhazardous, environment-friendly technique compared to soxhlet extraction (SE) method using hexane as solvent. Thus, this is a green technique of bio-oil extraction using only water as extractant. Bio-oil extraction from the pyrolysis of empty fruit bunch (EFB), a biomass waste from oil palm crop, was enhanced using a biocatalyst derived from seashell waste. Oil yield for non-catalytic extraction was 43.8% while addition of seashell based biocatalyst was 44.6%. Oil yield for non-catalytic extraction was 43.8% while with addition of seashell-based biocatalyst was 44.6%. The pH of bio-oil increased from 3.5 to 4.3. The viscosity of bio-oil obtained by catalytic means increased from 20.5 to 37.8 cP. A rapid and environment friendly extraction technique is preferable to enhance bio-oil yield. The microwave assisted approach is a green, rapid and environmental friendly extraction technique for the production of bio-oil bearing crops.

Geochemical characteristics and early diagenesis of recent carbonate mound sediments in the Gulf of Cadiz

Science.gov (United States)

Hamaekers, Helen; Foubert, Anneleen; Wienberg, Claudia; Hebbeln, Dierk; Swennen, Rudy

2010-05-01

Cold-water coral carbonate mounds occur in patches along the continental margin of the North Atlantic Ocean, from northern Norway down to Mauretania. Recent research has been focused on carbonate mounds in the Gulf of Cadiz, especially along the Moroccan margin. The Pen Duick, the Renard and the Vernadsky carbonate mound provinces in the Gulf of Cádiz are only some of the mound provinces which have been the subject of several recent research projects (Foubert et al., 2008; Wienberg et al., 2009). No living scleractinians could be found on top of those carbonate mounds. During cruise 64PE284 of RV Pelagia, gravity cores have been taken through carbonate mounds in the Carbonate Mound Provinces (CMP) SE of Yuma mud volcano and N of Meknes mud volcano. These cores have been analysed by several methods such as Magnetic Susceptibility (MS), X-Ray Fluorescence (XRF), Inductive Coupled Plasma Optical Emission Spectroscopy (ICP-OES) and X-Ray Diffraction (XRD) to determine the geochemical characteristics of carbonate mounds, which can be used to quantify the effects of early diagenetic processes which may have altered the palaeo-environmental characteristics of the carbonate mounds. Dating has been done with 14C and U/Th methods pointing to mound growth phases being restricted to glacial periods. XRF and ICP-OES measurements give both qualitative and quantitative data of the chemical composition of the core. The main elements that have been analysed are Ca, Si, Fe, Sr, Al, K, Mg, Ti. According to the trend they follow, they can be devided in two groups, representative for the two encountered fraction types. These two fraction types (biogenic carbonate-rich fraction and terrigenous silicate-rich fraction) can be coupled to interglacial/glacial palaeo-environmental conditions. XRD measurements give an overview of the mineralogical composition of the cores. Thin sections, analysed by cathodeluminescence and classical optical petrography, and micro-CT scans are used to

Effect of mineral oil, sunflower oil, and coconut oil on prevention of hair damage.

Science.gov (United States)

Rele, Aarti S; Mohile, R B

2003-01-01

Previously published results showed that both in vitro and in vivo coconut oil (CNO) treatments prevented combing damage of various hair types. Using the same methodology, an attempt was made to study the properties of mineral oil and sunflower oil on hair. Mineral oil (MO) was selected because it is extensively used in hair oil formulations in India, because it is non-greasy in nature, and because it is cheaper than vegetable oils like coconut and sunflower oils. The study was extended to sunflower oil (SFO) because it is the second most utilized base oil in the hair oil industry on account of its non-freezing property and its odorlessness at ambient temperature. As the aim was to cover different treatments, and the effect of these treatments on various hair types using the above oils, the number of experiments to be conducted was a very high number and a technique termed as the Taguchi Design of Experimentation was used. The findings clearly indicate the strong impact that coconut oil application has to hair as compared to application of both sunflower and mineral oils. Among three oils, coconut oil was the only oil found to reduce the protein loss remarkably for both undamaged and damaged hair when used as a pre-wash and post-wash grooming product. Both sunflower and mineral oils do not help at all in reducing the protein loss from hair. This difference in results could arise from the composition of each of these oils. Coconut oil, being a triglyceride of lauric acid (principal fatty acid), has a high affinity for hair proteins and, because of its low molecular weight and straight linear chain, is able to penetrate inside the hair shaft. Mineral oil, being a hydrocarbon, has no affinity for proteins and therefore is not able to penetrate and yield better results. In the case of sunflower oil, although it is a triglyceride of linoleic acid, because of its bulky structure due to the presence of double bonds, it does not penetrate the fiber, consequently resulting

Chemometric techniques in oil classification from oil spill fingerprinting.

Science.gov (United States)

Ismail, Azimah; Toriman, Mohd Ekhwan; Juahir, Hafizan; Kassim, Azlina Md; Zain, Sharifuddin Md; Ahmad, Wan Kamaruzaman Wan; Wong, Kok Fah; Retnam, Ananthy; Zali, Munirah Abdul; Mokhtar, Mazlin; Yusri, Mohd Ayub

2016-10-15

Extended use of GC-FID and GC-MS in oil spill fingerprinting and matching is significantly important for oil classification from the oil spill sources collected from various areas of Peninsular Malaysia and Sabah (East Malaysia). Oil spill fingerprinting from GC-FID and GC-MS coupled with chemometric techniques (discriminant analysis and principal component analysis) is used as a diagnostic tool to classify the types of oil polluting the water. Clustering and discrimination of oil spill compounds in the water from the actual site of oil spill events are divided into four groups viz. diesel, Heavy Fuel Oil (HFO), Mixture Oil containing Light Fuel Oil (MOLFO) and Waste Oil (WO) according to the similarity of their intrinsic chemical properties. Principal component analysis (PCA) demonstrates that diesel, HFO, MOLFO and WO are types of oil or oil products from complex oil mixtures with a total variance of 85.34% and are identified with various anthropogenic activities related to either intentional releasing of oil or accidental discharge of oil into the environment. Our results show that the use of chemometric techniques is significant in providing independent validation for classifying the types of spilled oil in the investigation of oil spill pollution in Malaysia. This, in consequence would result in cost and time saving in identification of the oil spill sources. Copyright © 2016. Published by Elsevier Ltd.

21 CFR 172.861 - Cocoa butter substitute from coconut oil, palm kernel oil, or both oils.

Science.gov (United States)

2010-04-01

... kernel oil, or both oils. 172.861 Section 172.861 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT... substitute from coconut oil, palm kernel oil, or both oils. The food additive, cocoa butter substitute from coconut oil, palm kernel oil, or both oils, may be safely used in food in accordance with the following...

Multi-media pollution prevention: A case study of a refinery

International Nuclear Information System (INIS)

Schmitt, R.E.; Podar, M.K.

1994-01-01

In late 1989, Amoco Corporation and the United States Environmental Protection Agency began a voluntary, joint project to study pollution prevention opportunities at an industrial facility. Amoco proposed use of its refinery at Yorktown, Virginia, to conduct a multi-media assessment of releases to the environment, then to develop and evaluate options to reduce these releases. A Workgroup composed of state, federal, and Amoco representatives provided oversight to the Project. Monthly Workgroup meetings provided Project oversight, a forum for presentations on different Project components, and an opportunity for informal discussion of different viewpoints about environmental management. The Workgroup identified four objectives for this study: (1) Inventory refinery releases to the environment to define their chemical type, quantity, source, and medium of release; (2) develop options to reduce selected releases identified, as well as rank and prioritize the options based on a variety of criteria and perspectives; (3) identify and evaluate factors as technical, legislative, regulatory, institutional, permitting, and economic, that impede or encourage pollution prevention; and (4) enhance participates' knowledge of refinery and regulatory systems

Quantification of rice bran oil in oil blends

Energy Technology Data Exchange (ETDEWEB)

Mishra, R.; Sharma, H. K.; Sengar, G.

2012-11-01

Blends consisting of physically refined rice bran oil (PRBO): sunflower oil (SnF) and PRBO: safflower oil (SAF) in different proportions were analyzed for various physicochemical parameters. The quantification of pure rice bran oil in the blended oils was carried out using different methods including gas chromatographic, HPLC, ultrasonic velocity and methods based on physico-chemical parameters. The physicochemical parameters such as ultrasonic velocity, relative association and acoustic impedance at 2 MHz, iodine value, palmitic acid content and oryzanol content reflected significant changes with increased proportions of PRBO in the blended oils. These parameters were selected as dependent parameters and % PRBO proportion was selected as independent parameters. The study revealed that regression equations based on the oryzanol content, palmitic acid composition, ultrasonic velocity, relative association, acoustic impedance, and iodine value can be used for the quantification of rice bran oil in blended oils. The rice bran oil can easily be quantified in the blended oils based on the oryzanol content by HPLC even at a 1% level. The palmitic acid content in blended oils can also be used as an indicator to quantify rice bran oil at or above the 20% level in blended oils whereas the method based on ultrasonic velocity, acoustic impedance and relative association showed initial promise in the quantification of rice bran oil. (Author) 23 refs.

Oil spills

International Nuclear Information System (INIS)

Katsouros, M.H.

1992-01-01

The world annually transports 1.7 billion tons of oil by sea, and oil spills, often highly concentrated discharges, are increasing from a variety of sources. The author discusses sources of oils spills: natural; marine transportation; offshore oil production; atmospheric sources; municipal industrial wastes and runoff. Other topics include: the fate of the spilled oil; the effects of the oil; the response to oil spills; and prevention of oil spills. 30 refs., 1 fig., 4 tabs

工业PTA氧化过程中4-CBA浓度的模糊神经网络模型%Fuzzy Neural Network Model of 4-CBA Concentration for Industrial Purified Terephthalic Acid Oxidation Process

Institute of Scientific and Technical Information of China (English)

刘瑞兰; 苏宏业; 牟盛静; 贾涛; 陈渭泉; 褚健

2004-01-01

A fuzzy neural network (FNN) model is developed to predict the 4-CBA concentration of the oxidation unit in purified terephthalic acid process. Several technologies are used to deal with the process data before modeling.First, a set of preliminary input variables is selected according to prior knowledge and experience. Secondly, a method based on the maximum correlation coefficient is proposed to detect the dead time between the process variables and response variables. Finally, the fuzzy curve method is used to reduce the unimportant input variables. The simulation results based on industrial data show that the relative error range of the FNN model is narrower than that of the American Oil Company (AMOCO) model. Furthermore, the FNN model can predict the trend of the 4-CBA concentration more accurately.

Hydroprocesssing of light gas oil - rape oil mixtures

Energy Technology Data Exchange (ETDEWEB)

Walendziewski, Jerzy; Stolarski, Marek; Luzny, Rafal; Klimek, Bartlomiej [Faculty of Chemistry, Wroclaw University of Technology, ul. Gdanska 7/9, 50-310 Wroclaw (Poland)

2009-05-15

Two series of experiments of hydroprocessing of light gas oil - rape oil mixtures were carried out. The reactor feed was composed of raw material: first series - 10 wt.% rape oil and 90 wt.% of diesel oil; second series - 20 wt.% rape oil and 80 wt.% of diesel oil. Hydroprocessing of both mixtures was performed with the same parameter sets, temperature (320, 350 and 380 C), hydrogen pressure 3 and 5 MPa, LHSV = 2 h{sup -} {sup 1} and hydrogen feed ratio of 500 Nm{sup 3}/m{sup 3}. It was stated that within limited range it is possible to control vegetable oil hydrogenolysis in the presence of light gas oil fraction (diesel oil boiling range) through the proper selection of the process parameters. Hydrogenolysis of ester bonds and hydrogenation of olefinic bonds in vegetable oils are the main reactions in the process. Basic physicochemical properties of the obtained hydroprocessed products are presented. (author)

Oil Spills

Science.gov (United States)

... up. How Oil Harms Animals and Plants in Marine Environments In general, oil spills can affect animals and plants in two ways: from the oil ... up. How Oil Harms Animals and Plants in Marine Environments In general, oil spills can affect animals and plants in two ways: from the oil ...

Oil/gas collector/separator for underwater oil leaks

Energy Technology Data Exchange (ETDEWEB)

Henning, C.D.

1992-12-31

This invention is comprised of an oil/gas collector/separator for recovery of oil leaking, for example, from an offshore or underwater oil well. The separator is floated over the point of the leak and tethered in place so as to receive oil/gas floating, or forced under pressure, toward the water surface from either a broken or leaking oil well casing, line, or sunken ship. The separator is provided with a downwardly extending skirt to contain the oil/gas which floats or is forced upward into a dome wherein the gas is separated from the oil/water, with the gas being flared (burned) at the top of the dome, and the oil is separated from water and pumped to a point of use. Since the density of oil is less than that of water it can be easily separated from any water entering the dome.

27 CFR 21.98 - Bone oil (Dipple's oil).

Science.gov (United States)

2010-04-01

... 27 Alcohol, Tobacco Products and Firearms 1 2010-04-01 2010-04-01 false Bone oil (Dipple's oil....98 Bone oil (Dipple's oil). (a) Color. The color shall be a deep brown. (b) Distillation range. When... below 90 °C. (c) Pyrrol reaction. Prepare a 1.0 percent solution of bone oil in 95 percent alcohol...

Compositional modification of crude oil during oil recovery

Energy Technology Data Exchange (ETDEWEB)

Zhu, Yangming; Weng, Huanxin [Department of Earth Sciences, Zhejiang University, Hangzhou 310027 (China); Chen, Zulin; Chen, Qi [Petroleum Geochemistry Research Center, Jianghan Petroleum University, Jingzhou, Hubei (China)

2003-05-01

Ten crude oils from two recovery stages spanning 5-10-year interval of five productive wells in the Tarim Basin, northwest China were analyzed for their compositional modification during production process. Significant compositional changes in polar and nonpolar fractions between the previous oil samples and the latter ones were noted at both bulk and molecular level. The latter oil samples appear to contain more aromatic fraction and less asphaltenes and resin, and their gas chromatography (GC) data for whole oil show reduced alkanes with low molecular weight and enhanced high homologue relative to the previous oil samples. Compared with the oils collected from the previous recovery stage, the concentration of basic type of nitrogen-containing compounds and organic acids in oils from the latter recovery stage have a reducing trend, suggesting the occurrence of interaction between crude oil and reservoir rock.

Oil and influence: the oil weapon examined

Energy Technology Data Exchange (ETDEWEB)

Maull, H

1975-01-01

The term ''oil weapon'' as used here signifies any manipulation of the price and/or supply of oil by exporting nations with the intention of changing the political behavior of the consumer nations. The political potential of the oil price is fairly restricted so, in effect, the supply interruptions are of prime concern. Manipulating price does, in principle, offer the possibilities of both conferring rewards and inflicting sanctions. Oil could be sold on preferential prices and terms. A precondition for using the oil weapon successfully would be the ability to cause real and serious damage to the consumer countries. Four damaging potentials for using the oil weapon could include its application by: (1) one producer against one consumer; (2) one producer against all consumers; (3) a group of producers against one consumer; and (4) by a group of producers against all consumers. It is concluded that the oil weapon will continue to be a force in the international system. (MCW)

Comparative safety assessment of surface versus submarine plutonium shipments

International Nuclear Information System (INIS)

Knepper, D.S.; Feltus, M.A.

1993-01-01

The recent shipment of plutonium from France to Japan aboard the freighter Akatsuki Maru touched off protests from environmental and antinuclear organizations. These protests arose from the fear of an accidental sinking of the vessel that would release its cargo to the sea, as well as the threat of a terrorist nation highjacking the ship for its cargo to produce atomic weapons. The sinking of a merchant ship is not uncommon, as illustrated by the famous losses of the tankers Amoco Cadiz and Exxon Valdez. The highjacking of a lightly armed freighter such as the Akatsuki Maru is possible and would not be unduly difficult for a well-equipped terrorist nation. The combined threats of weapons proliferation and environmental damage arising from the diversion or destruction of a sea vessel carrying plutonium will continue to abound as the reprocessing of spent nuclear fuel increases. An alternate method for the transportation with reduced risks of both diversion and destruction needs to be developed. The shipment aboard the Akatsuki Maru was originally proposed to be flown from France to Japan over the continental United States. This proposal was rejected by the Reagan administration in 1988. A third alternative to the current ideas of air transport and surface transport is subsurface transport. This research project investigates the transportation of plutonium by submarine and compares it to the current method of transportation by freighter. This analysis involves a study of the military threat to a submarine by a terrorist nation and comparable threat to a surface vessel. To study the nonmilitary aspects of plutonium shipping, a fault-tree evaluation is performed for transportation by submarine and compared with the current risk analysis performed for surface vessels

Biochemically enhanced oil recovery and oil treatment

Science.gov (United States)

Premuzic, Eugene T.; Lin, Mow

1994-01-01

This invention relates to the preparation of new, modified organisms, through challenge growth processes, that are viable in the extreme temperature, pressure and pH conditions and salt concentrations of an oil reservoir and that are suitable for use in microbial enhanced oil recovery. The modified microorganisms of the present invention are used to enhance oil recovery and remove sulfur compounds and metals from the crude oil.

Research of losses of oil oil and mineral oil at transportation and storage

International Nuclear Information System (INIS)

Akzhigitov, A.S.

2005-01-01

Full text : All way of hydrocarbonic raw material from a mouth of oil wells up to the consumer is accompanied by losses which occur as a result of evaporation, outflow and change of quality. Therefore preservation of quantity and quality of oil and mineral oil during transportation and storages is the major not only economic, but also an ecological problem. The facilitated fractional structure, the big maintenance concern to prominent features of the majority oil from underground salts adjournment Prycaspi in them of the easy hydrocarbons, the raised gas factor in conditions of deposits and presence in structure of gases, except for hydrocarbons and sour a component, - hydrogen sulphide, carbonic gas, etc. The superficial tests stabilized on phase structure oil depending on conditions of preparation for external transport and the subsequent processing can contain this or that quantity of residual hydrogen sulphide, easy hydrocarbons and the lowest sulfhydrates. For change of temperature and external pressure, during transportation and storage the part of easy hydrocarbons and not hydrocarbonic connections (sulfur organic) can be allocated from oil in a gaseous phase and in case of hit in an atmosphere sharply worsens ecology. In the Western Kazakhstan during the years period the temperature of air sometimes reaches up to 40-45 degrees. As is known, at such temperature there is a strengthened warming up of the open surface of oil tanks, that finally leads to increase evaporation easy oil and oil hydrocarbons. With this purpose experiences by quantitative definition evaporation lungs oil and petromixes of the Western Kazakhstan were spent. As a result of the lead works it is found out, that the size of losses at the given fixed temperature depends on evaporation by nature, fractional and hydrocarbonic structures of oil

Influence of oil and mineral characteristics on oil-mineral interaction

International Nuclear Information System (INIS)

Wood, P.A.; Lunel, T.; Daniel, F.; Swannell, R.; Lee, K.; Stoffyn-Egli, P.

1998-01-01

A laboratory study was conducted to simulate the process of oil-mineral interaction in seawater. Thirteen different crudes, emulsions and oil products were used in the study. The objective was to improve the fundamental understanding of the characteristics of oils and minerals that influence the process. The findings of an initial phase of studies based on the swirling flask and marine simulation procedures were also described. Oil content associated with flocs to oil and mineral characteristics were discussed. Emulsions were prepared at 10 degrees C by vigorously mixing the oil with excess artificial seawater in a Kilner jar using a high shear homogenizer. Topped oils were prepared by distillation to 250 degrees C. The biodegraded oil was prepared from the topped crude oil. Biodegradation was achieved over a 28 day period using natural seawater and naturally occurring hydrocarbon degraders. The relationships between oil concentration, oil density and mineral exchange capacity were determined. The study showed that greater oil concentrations in the water column could be expected with (1) the presence of mineral fines, (2) minerals with greater cation exchange rates, (3) minerals with finer sizes, and (4) oils of lower viscosity and density. It was determined that in coastal waters the viscosity of the oil/emulsion will likely be the main factor affecting oil-mineral interactions. The viscosity limit for allowing oil fines interaction is likely to be dependent on the energy in the coastal zone affected by the oil pollution. 18 refs., 5 tabs., 13 figs

Dynamic correlation between stock market and oil prices: The case of oil-importing and oil-exporting countries

OpenAIRE

Filis, George; Degiannakis, S.; Floros, C.

2011-01-01

The paper investigates the time-varying correlation between stock market prices and oil prices for oil-importing and oil-exporting countries. A DCC-GARCH-GJR approach is employed to test the above hypothesis based on data from six countries; Oil-exporting: Canada, Mexico, Brazil and Oil-importing: USA, Germany, Netherlands. The contemporaneous correlation results show that i) although time-varying correlation does not differ for oil-importing and oil-exporting economies, ii) the correlation i...

What is behind the increase in oil prices? Analyzing oil consumption and supply relationship with oil price

International Nuclear Information System (INIS)

Gallo, Andres; Mason, Paul; Shapiro, Steve; Fabritius, Michael

2010-01-01

The continuing increases in oil prices have renewed the argument over the real culprits behind these movements. The growth in demand for oil in international markets, especially from the United States and China, is often identified as the main source of consumption pressure on prices, and thus the upward trend in oil prices. This paper uses unit root tests with two endogenous breaks to analyze the characteristics of oil prices, production, and consumption for several countries. By taking into account structural breaks, we find that many countries' oil consumption and oil prices are stationary, while other countries' are not. We also perform causality tests to determine the direction of any possible relationship between oil price and oil consumption and production. Our statistical analysis reveals that production variables cause oil prices, while oil prices tend to cause consumption. As a result, we claim that the blame for the recent fluctuations in oil prices is more appropriately associated with supply factors, not consumption influences. (author)

Oil flow in deep waters: comparative study between light oils and heavy oils

Energy Technology Data Exchange (ETDEWEB)

Andreolli, Ivanilto [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil)

2009-12-19

Ultra deeper waters fields are being exploited due to technological development. Under this scenario, the flow design is accomplished through pipelines subjected to low temperature and high pressure. Moreover, these flow lines are usually long causing a fast fluid cooling, which may affect flow assurance in some cases. Problems during topsides production plant's restart might occur if the oil is viscous and even in steady state a significant different behavior can be noticed, if compared to a less viscous oil. A comparison between light and heavy oil through a case study with the objective to show some heavy oil flow particularities is the purpose of this paper. Permanent and transient analyses for a specific geometry are presented. The results showed that thermal and proper viscosity modeling are required for heavy oil flow, differently from that of light oil flow, due to the exponential viscosity dependence to temperature and because the predominant laminar regime. In addition, on heavier and heavier oil flow systems, it is essential to consider exportation system's restart. (author)

Japan FRI research activities on oil tank/spilled oil fire

International Nuclear Information System (INIS)

Koseki, Hiroshi

1992-01-01

Introduction of research activities on oil tank/spilled oil fire at FRI, Japan is done. FRI has a long history of studying oil tank and spilled oil fires. Many large oil fire tests were done. The purpose of these studies is different with research of response of oil spill, but the accumulation of this knowledge is useful for conducting elimination of spilled oil on the sea with burning. Therefore to do collaboration with fire science research groups, such as FRI is useful for future activities for response to oil spills

Yield and characteristics of shale oil from the retorting of oil shale and fine oil-shale ash mixtures

International Nuclear Information System (INIS)

Niu, Mengting; Wang, Sha; Han, Xiangxin; Jiang, Xiumin

2013-01-01

Highlights: • The whole formation process of shale oil might be divided into four stages. • Higher ash/shale mass ratio intensified the cracking and coking of shale oil. • Ash/shale ratio of 1:2 was recommended for oil shale fluidized bed retort with fine oil-shale ash as solid heat carrier. - Abstract: For exploring and optimizing the oil shale fluidized bed retort with fine oil-shale ash as a solid heat carrier, retorting experiments of oil shale and fine oil-shale ash mixtures were conducted in a lab-scale retorting reactor to investigate the effects of fine oil-shale ash on shale oil. Oil shale samples were obtained from Dachengzi Mine, China, and mixed with fine oil-shale ash in the ash/shale mass ratios of 0:1, 1:4, 1:2, 1:1, 2:1 and 4:1. The experimental retorting temperature was enhanced from room temperature to 520 °C and the average heating rate was 12 °C min −1 . It was found that, with the increase of the oil-shale ash fraction, the shale oil yield first increased and then decreased obviously, whereas the gas yield appeared conversely. Shale oil was analyzed for the elemental analysis, presenting its atomic H/C ratio of 1.78–1.87. Further, extraction and simulated distillation of shale oil were also conducted to explore the quality of shale oil. As a result, the ash/shale mixing mass ratio of 1:2 was recommended only for the consideration of increasing the yield and quality of shale oil

Palm Oil

Science.gov (United States)

Palm oil is obtained from the fruit of the oil palm tree. Palm oil is used for preventing vitamin A deficiency, cancer, ... blood pressure, high cholesterol, and cyanide poisoning. Palm oil is used for weight loss and increasing the ...

Diesel oil

Science.gov (United States)

Oil ... Diesel oil ... Diesel oil poisoning can cause symptoms in many parts of the body. EYES, EARS, NOSE, AND THROAT Loss of ... most dangerous effects of hydrocarbon (such as diesel oil) poisoning are due to inhaling the fumes. NERVOUS ...

Shale-oil-derived additives for fuel oils

International Nuclear Information System (INIS)

Raidma, E.; Leetsman, L.; Muoni, R.; Soone, Y.; Zhiryakov, Y.

2002-01-01

Studies have shown that the oxidation, wearing, and anticorrosive properties of shale oil as an additive to liquid fuels and oils enable to improve the conditions of their use. Studies conducted by Institute of Oil Shale have shown that it is possible, on the basis of shale oil produced by Viru Keemia Grupp AS (Viru Chemistry Group Ltd.) and, particularly, on the basis of its fractions 230-320 and 320-360 deg C to produce efficient and stable additives for liquid fuels to improve their combustion and storage properties. In the production of additives from shale oil the prerequisite taken into account is its complexity of composition and high concentration of neutral and phenolic oxygen compounds. Additives produced from shale oil have multifunctional properties which enable to improve operational data of liquid fuels and to increase the power of diesel engines and boilers. (author)

Investigating oiled birds from oil field waste pits

International Nuclear Information System (INIS)

Gregory, D.G.; Edwards, W.C.

1991-01-01

Procedures and results of investigations concerning the oiling of inland raptors, migratory water-fowl and other birds are presented. Freon washings from the oiled birds and oil from the pits were analyzed by gas chromatography. In most instances the source of the oil could be established by chromatographic procedures. The numbers of birds involved (including many on the endangered species list) suggested the need for netting or closing oil field waste pits and mud disposal pits. Maintaining a proper chain of custody was important

Toxicities of Selected Essential Oils, Silicone Oils, and Paraffin Oil against the Common Bed Bug (Hemiptera: Cimicidae).

Science.gov (United States)

Zha, Chen; Wang, Changlu; Li, Andrew

2018-02-09

The common bed bug [Cimex lectularius L. (Hemiptera: Cimicidae)] and tropical bed bug [Cimex hemipterus F. (Hemiptera: Cimicidae)] resurged in the United States and many other countries over the past decades. The need for safe and effective bed bug control products propelled the development of numerous 'green insecticides', mostly with essential oils listed as active ingredients. Various inorganic and organic oils also were used for bed bug management. However, there are no published studies on their toxicities against bed bugs. In this study, we screened 18 essential oils, three silicone oils, and paraffin oil (C5-20 paraffins) for their toxicities against bed bugs. All the oils exhibited insecticidal activity in topical assays. Their toxicities varied significantly; all of the evaluated essential oils were less effective than silicone oils and paraffin oil. The LD50 values of the most effective essential oil (blood orange), paraffin oil, and the most effective silicone oil (dodecamethylpentasiloxane) are 0.184 ± 0.018, 0.069 ± 0.012, and 0.036 ± 0.005 mg per bug, respectively. Direct spray of 1% water solution of 3-[hydroxy (polyethyleneoxy) propyl] heptamethyltrisiloxane, the only silicone oil that mixes well with water, resulted in 92% bed bug mortality after 1 d. Results of this study indicate silicone oils and paraffin oil have the potential to be used as safer alternative bed bug control materials. © The Author(s) 2017. Published by Oxford University Press on behalf of Entomological Society of America. All rights reserved. For permissions, please e-mail: journals.permissions@oup.com.

Oil on seawater

International Nuclear Information System (INIS)

Boerresen, J.A.

1993-01-01

The present book discusses the effects of oil spills at sea. Topics covered are as follow: Petroleum properties; oil spills at sea; harmfulness of oil spills; effects from acute oil spills; experience of oil spills; oil spill contingency planning in Norway; oil spill protecting equipment and methods; emergency of unloading equipment. 252 refs., 86 figs., 54 tabs

Method of removing paraffin from mineral oils, shale oils, tar oils, and their fractions or residues

Energy Technology Data Exchange (ETDEWEB)

Palmquist, F T.E.

1949-09-08

A method is described for removing paraffin from mineral oils, shale oils, tar oils, and their fractions or residues by centrifuging in the presence of oil-dissolving and paraffin-precipitating solvents, by which the precipitated paraffin is made to pass through an indifferent auxiliary liquid, in which a removal of oil takes place, characterized in that as auxiliary liquid is used a liquid or mixture of liquids whose surface tension against the oil solution is sufficiently low for the paraffin to pass the layer of auxiliary liquid in the form of separate crystals.

Asian oil demand

International Nuclear Information System (INIS)

Fesharaki, F.

2005-01-01

This conference presentation examined global oil market development and the role of Asian demand. It discussed plateau change versus cyclical movement in the global oil market; supply and demand issues of OPEC and non-OPEC oil; if high oil prices reduce demand; and the Asian oil picture in the global context. Asian oil demand has accounted for about 50 per cent of the global incremental oil market growth. The presentation provided data charts in graphical format on global and Asia-Pacific incremental oil demand from 1990-2005; Asia oil demand growth for selected nations; real GDP growth in selected Asian countries; and, Asia-Pacific oil production and net import requirements. It also included charts in petroleum product demand for Asia-Pacific, China, India, Japan, and South Korea. Other data charts included key indicators for China's petroleum sector; China crude production and net oil import requirements; China's imports and the share of the Middle East; China's oil exports and imports; China's crude imports by source for 2004; China's imports of main oil products for 2004; India's refining capacity; India's product balance for net-imports and net-exports; and India's trade pattern of oil products. tabs., figs

Brine crude oil interactions at the oil-water interface

DEFF Research Database (Denmark)

Chakravarty, Krishna Hara; Fosbøl, Philip Loldrup; Thomsen, Kaj

2015-01-01

The impact of brine salinity and its ionic composition on oil displacement efficiency has been investigated extensively in recent years due to the potential of enhanced oil recovery (EOR). Wettability alterations through relative interactions at the mineral surface have been the basis of proposed...... in enhancing oil emulsion formation by increasing interactions between polar acids and brine solutions. The results propose the potential use of HPO42- ions in reservoirs having inactive mineral surfaces. The relative oil affinity of different ions including K+, Na+, Mg2+, and Ca2+ (cations), and Cl-, SO42...... and thus reduces the interfacial viscoelasticity of the trapped oil. These results show significant correlation between oil emulsion formation and increased oil recovery. Copyright 2015; Society of Petroleum Engineers...

Detection of argan oil adulterated with vegetable oils: New markers

Energy Technology Data Exchange (ETDEWEB)

Ourrach, I.; Rada, M.; Perez-Camino, M. C.; Benaissa, M.; Guinda, A

2012-07-01

This work aims to contribute to controlling the authenticity of pure argan oil, a valuable Moroccan product. Fatty acids, hydrocarbon fraction, 3,5-stigmastadiene, the alkyl esters of fatty acids, chlorophyllic pigments and physical properties such as viscosity, density and refractive index were studied in order to detect the adulteration of argan oil with edible vegetable oils. The results found in this study show that 3,5-stigmastadiene, kaurene and pheophytin-a can be used as possible new markers for argan oil blends of up to 5% with refined, sunflower and virgin olive oils. Due to the similarity of the fatty acid compositions of the edible oils studied and argan oil, fatty acids can be employed as markers for the detection of argan oil adulteration at levels higher than 10%. Among the physical properties studied, the refractive index shows significant differences for sunflower oil and its blend at 10% with argan oil. (Author) 35 refs.

Modification of Oil Palm Plantation Wastes as Oil Adsorbent for Palm Oil Mill Effluent (POME)

International Nuclear Information System (INIS)

Noraisah Jahi; Ling, E.S.; Rizafizah Othaman; Suria Ramli

2015-01-01

This research was conducted to modify oil palm solid wastes chemically to become oil adsorbent for palm oil mill effluent (POME). The purpose of modification on oil palm leaves (OPL) and oil palm frond (OPF) was to change the hydrophilic nature to a more hydrophobic character. This study also exploited the production of sorbent materials with high efficiency in the oil uptake for POME from OPL and OPF. Chemical modification was carried out using 200 mL of 1.0 M lauric acid solution for 6 hrs at room temperature. The modified OPL and OPF were preceded to adsorption test for POME and the capacity of oil adsorbed was compared between them. FTIR analysis supported the modification to occur with the increase in a peak of C-H group and the presence of C=O originated from lauric acid structure chain. The hydrophobicity of modified OPL and OPF samples was supported by XRD and contact angle analysis with modified OPL became more hydrophobic than the modified OPF, which had been 38.15 % and 24.67 % respectively. Both the analyses proved that the result from the oil adsorption test on POME showed the presence of a new peak attribute at C=C stretching of aromatics for the oil in POME proved that it was attached on the sorbent materials. Based on SEM analysis, the perforated and rough surface had been observed on modified OPL and OPF samples because oil layers on OPL and OPF surfaces were observed on the modified samples after the adsorption test. All the analyses in the study agreed that the results from oil adsorption test showed that the modified OPL had higher adsorption capacity than the modified OPF with the percentage of oil uptake at 83.74 % and 39.84 % respectively. The prepared adsorbent showed the potential to be used as a low-cost adsorbent in oil for POME. (author)

The oil and oil services industry international context 2008

International Nuclear Information System (INIS)

Serbutoviez, S.; Silva, C.

2008-11-01

Oil companies rarely do their own major work within the framework of their investments or in the operation of their facilities. They most often act as project coordinators, thereby opening up a vast market for equipment, services and engineering, involving many companies of widely-varying sizes, which constitute the oil services industry. This document provides a panorama of the international oil context in three distinct parts, for 2007, for the first three quarters of 2008, and aspects of trends for 2009. - The first part is devoted to a rapid description of the oil context and the economic environment in which it is evolving. - The second part examines the evolution of world investment in exploration-production (E and P) activities, distinguishing the investments made by oil and oil product/service companies throughout the E and P chain from the more targeted ones of three specific sectors: seismic, drilling and the construction of offshore production equipment. These markets are observed exclusively for oil product/service companies. - The last part is devoted to investments in the refining sector, focusing on the changes in the fundamentals, particularly the equilibrium between refining capacities and medium- term oil demand. This latter analysis involves both oil and oil product/service companies. (authors)

The functioning of the oil market during an oil crisis

International Nuclear Information System (INIS)

Hughes, G.; Siner, M.; Tijdhof, B.

2003-01-01

The title study regarding the functioning of the oil market during an oil crisis is carried out with particular reference to the strategic behaviour of oil companies. Section 2 identifies major oil supply disruptions since 1951 and describes some important changes in the market that have occurred in recent decades; Section 3 reviews the economic literature of the functioning of oil markets during disruptions and models of oil supply disruptions; Section 4 examines the response of oil markets to recent supply disruptions; Section 5 examines the incentives and scope for strategic behaviour; Section 6 considers the implications of our analysis for the design of policy responses to oil supply disruptions; Appendix A describes the background to the four recent oil supply disruptions; Appendix B discusses the relationship between spot and futures prices for a storable commodity; and Appendix C is the bibliography

HOW PROPERTIES OF EDIBLE OILS ARE IMPROVED BY ESSENTIAL OILS

Directory of Open Access Journals (Sweden)

SONIA AMARIEI

2016-10-01

Full Text Available The main aim of the present paper is to find out whether the addition of essential oils determines better oxidation stability and positive change of sensory and hedonic perception of edible oils. The oxidation stability of sunflower, corn and grape seed oils was analyzed in the presence of antioxidants in essential oils of rosemary (Rosmarinus officinalis, thyme (Thymus vulgaris and basil (Ocimum basilicum during storage, under conditions of accelerated oxidative processes (4 days, at 60 °C. The total phenolic compounds of these essential oils were determined by the Folin-Ciocalteu method. The DPPH method was used to evaluate the antioxidant capacity of basil, rosemary and thyme essential oils in comparison with known synthetic antioxidant L(+-ascorbic acid. The addition of essential oils to edible oils, the amounts proposed in analyses, determines a favorable influence on their oxidation stability as well as their taste. The influence of addition of essential oils on the taste of edible oils was studied in two products consumed mainly at breakfast, bread and spinach leaves. The results recommend the use of these plant extracts as additives in edible oils rather than synthetic antioxidants.

Mexican oil industry: Shifting to difficult oil

Energy Technology Data Exchange (ETDEWEB)

Bazan G., Gerardo; Gonzalez, Cristobal J.

2010-09-15

Mexico has stepped into an important transition of declining oil fields and new challenging oil projects. The aim of this paper is to show a new perspective of the oil resources that have been exploited throughout the Mexican territory, as well as the remaining resources yet to be exploited. We have developed a resources/production-costs chart that illustrates the historical and future development of the Mexican oil industry, showing the shift that the industry will face in the coming years; this chart was taken from a model already in use by the most prestige energy agencies in the world.

Oil markets to 2010: the impact of non-Opec oil

International Nuclear Information System (INIS)

Enav, Peter

1998-09-01

This report provides an in-depth assessment of oil development scenarios in every non-Opec oil producing country from 1998 to 2010, in addition to evaluating the extent and direction of future oil trade for Opec and non-Opec countries alike. It re-assesses world oil consumption patterns in light of the Asian financial crisis, providing a concise yet comprehensive coverage of an often-neglected oil production group. The oil market development scenario is analysed in each country, with detailed consideration of the major players providing historical production, consumption, import and export data; current oil balance - production, imports and exports; an assessment of oil development policy; analysis of potential development obstacles considering regulatory, financial, political and environmental issues; oil production and consumption projections to 2010, by type; and import and export projections to 2010, by destination and source. More than 80 tables supplying essential statistics on the world's non-Opec markets accompany the report, with maps and schematic diagrams showing existing and potential infrastructure and fields. (Author)

Coconut oil has less satiating properties than medium chain triglyceride oil.

Science.gov (United States)

Kinsella, R; Maher, T; Clegg, M E

2017-10-01

It is well established that the consumption of medium-chain triglycerides (MCT) can increase satiety and reduce food intake. Many media articles promote the use of coconut oil for weight loss advocating similar health benefits to that of MCT. The aim of this study was to examine the effect of MCT oil compared to coconut oil and control oil on food intake and satiety. Following an overnight fast, participants consumed a test breakfast smoothie containing 205kcal of either (i) MCT oil (ii) coconut oil or (iii) vegetable oil (control) on three separate test days. Participants recorded appetite ratings on visual analogue scales and were presented with an ad libitum lunch meal of preselected sandwiches 180min after consumption of the breakfast. The results showed a significant difference in energy and macronutrient intakes at the ad libitum meal between the three oils with the MCT oil reducing food intake compared to the coconut and control oil. Differences in food intake throughout the day were found for energy and fat, with the control having increased food intake compared to the MCT and coconut. The MCT also increased fullness over the three hours after breakfast compared to the control and coconut oils. The coconut oil was also reported as being less palatable than the MCT oil. The results of this study confirm the differences that exist between MCT and coconut oil such that coconut oil cannot be promoted as having similar effects to MCT oil on food intake and satiety. Crown Copyright © 2017. Published by Elsevier Inc. All rights reserved.

Separation of oil and grease from oil sludge using surfactant

International Nuclear Information System (INIS)

Ainon Abdul Aziz; Syed Hakimi Sakuma Syed Ahmad; Zalina Laili

2005-01-01

The objective of the experiments was to observe the efficiency of the surfactant to remove oil and grease from oil sludges using various surfactant concentration ranging from 10 %, 15 %, 20 % and 30 %. The surfactant solution consists of two mixtures of Aqua 2000 and D Bond. The oil sludge were subjected to heating and surfactant treatment process. Remaining oil and grease concentration were observed on the oil sludges after treatment. Small scale experiments were conducted by heating process, without heating process and heating process with addition of sodium chloride. Surfactant solution was added in each process. Results shows that there is separation of oil and grease from the oil sludges. There were formation of mini emulsions (oil in water). The higher the concentration of surfactant used, the higher the concentrations of mini emulsion formed as observed. Solid remains after the treatment process were found to contain lesser oil concentration with presence of bitumen, sediment, organic and inorganic materials. After a washing process using distilled water, the solid was still black but less oily than before the treatment. There is no separation of oil occurred in aqueous solution for the control experiment. (Author)

Oil Spills

Science.gov (United States)

Oil spills often happen because of accidents, when people make mistakes or equipment breaks down. Other causes include natural disasters or deliberate acts. Oil spills have major environmental and economic effects. Oil ...

Process for complete conversion of coal oils, shale oils, etc

Energy Technology Data Exchange (ETDEWEB)

Dubois, P

1911-07-08

A process is described for complete conversion of mineral coal oil, shale oil, and other similar oils in pitch, characterized by these oils being mixed with a nonvolatile substance with a boiling point on the average higher than the boiling point of the oil to be treated, and then being heated under pressure with the introduction of air, whereby the heating is interrupted if necessary on account of the known exothermic reaction and the conversion of the oil in the pitch or its distillation can be carried out without further heating.

Increasing oil recovery from heavy oil waterfloods

Energy Technology Data Exchange (ETDEWEB)

Brice, B.W. [Society of Petroleum Engineers, Canadian Section, Calgary, AB (Canada)]|[BP Exploration, Calgary, AB (Canada)

2008-10-15

In an effort to optimize waterflood strategies in Alaska, the authors examined the results of up to 50 years of waterflooding on 166 western Canadian waterfloods recovering oil of less than 30 degrees API. The study determined the best operating practices for heavy oil waterflooding by investigating the difference between waterflooding of heavy oil and lighter oil counterparts. Operators of light oil waterflooding are advised to begin waterflooding early and maintain the voidage replacement ratio (VRR) at 1. However, this study showed that it is beneficial to delay the start of waterflooding until a certain fraction of the original oil in place was recovered. Varying the VRR was also shown to correlate with increased ultimate recovery. This statistical study of 166 western Canadian waterfloods also examined the effect of injection strategy and the effect of primary production before waterflooding. Some pre-waterflood production and under injection time is advantageous for ultimate recovery by waterfloods. Specific recommendations were presented for waterfloods in reservoirs with both high and low API gravity ranges. Each range showed a narrow sweet spot window where improved recovery occurred. 27 refs., 13 figs.

Comparative Effect of Dietary Soybean Oil, Fish Oil, and Coconut Oil on Performance, Egg Quality and Some Blood Parameters in Laying Hens.

Science.gov (United States)

Dong, X F; Liu, S; Tong, J M

2018-04-14

Two hundred and sixteen 28-wk-old Hy-line laying hens were randomly distributed to three dietary treatments and fed 1of 3 diets containing 8% soybean oil, fish oil, or coconut oil from 28 to 47 wk of age to investigate comparative effect of dietary soybean oil, fish oil, and coconut oil on the performance, egg quality and blood malondialdehyde (MDA), aspartate transaminase (AST) and uric acid (UA). Hens fed fish oil showed poor performance compared with soybean oil or coconut oil, and especially egg weight throughout the trial was significantly and consistently decreased (P oil. Unexpectedly, shell reflectivity throughout the majority of the trial was consistently and significantly higher (P oil than that when fed soybean oil or coconut oil. Dietary treatments affected (P oil treatment was higher (P oil group. Albumen height, Haugh unit and yolk color were influenced by dietary treatments only at 1 or 2 time points. However, average albumen height and Haugh unit in fish oil treatment were higher (P soybean oil or coconut oil treatments and average yolk color in coconut oil treatment was higher (P soybean oil group. Serum MDA, AST and UA concentrations were increased (P oil during the majority of the first 2 mo of the trial. These data suggested that the inclusion of fish oil into feed may reduce the performance of laying hens, especially the egg weight, decrease the intensity of egg brown color and increase blood MDA, AST and UA levels compared with soybean oil or coconut oil. As a result, hens fed fish oil may lay smaller, longer and lighter-brown eggs whereas those fed coconut oil produce blunter and darker-brown eggs relative to soybean oil.

Production of oil from Israeli oil shale

International Nuclear Information System (INIS)

Givoni, D.

1993-01-01

Oil shale can be utilized in two-ways: direct combustion to generate steam and power or retorting to produce oil or gas. PAMA has been developing both direct combustion and retorting processes. Its main effort is in the combustion. An oil shale fired steam boiler was erected in the Rotem industrial complex for demonstration purposes. PAMA has also been looking into two alternative retorting concepts - slow heating of coarse particles and fast heating of fine particles. The present paper provides operating data of oil shale processing in the following scheme: (a) retorting in moving bed, pilot and bench scale units, and (b) retorting in a fluidized bed, bench scale units. (author)

Genetic determinism of oil acidity among some DELI oil palm (Elaeis ...

African Journals Online (AJOL)

USER

2016-08-24

Aug 24, 2016 ... Key words: Elaeis guineensis Jacq., free fatty acid content, crude palm oil, inheritance. INTRODUCTION. The oil palm (Elaeis ... of world's production of vegetable oils. The highest palm oil producing countries ... Without prior refining, acidic palm oil is improper for human consumption (Anonymous, 2005).

Improving oil classification quality from oil spill fingerprint beyond six sigma approach.

Science.gov (United States)

Juahir, Hafizan; Ismail, Azimah; Mohamed, Saiful Bahri; Toriman, Mohd Ekhwan; Kassim, Azlina Md; Zain, Sharifuddin Md; Ahmad, Wan Kamaruzaman Wan; Wah, Wong Kok; Zali, Munirah Abdul; Retnam, Ananthy; Taib, Mohd Zaki Mohd; Mokhtar, Mazlin

2017-07-15

This study involves the use of quality engineering in oil spill classification based on oil spill fingerprinting from GC-FID and GC-MS employing the six-sigma approach. The oil spills are recovered from various water areas of Peninsular Malaysia and Sabah (East Malaysia). The study approach used six sigma methodologies that effectively serve as the problem solving in oil classification extracted from the complex mixtures of oil spilled dataset. The analysis of six sigma link with the quality engineering improved the organizational performance to achieve its objectivity of the environmental forensics. The study reveals that oil spills are discriminated into four groups' viz. diesel, hydrocarbon fuel oil (HFO), mixture oil lubricant and fuel oil (MOLFO) and waste oil (WO) according to the similarity of the intrinsic chemical properties. Through the validation, it confirmed that four discriminant component, diesel, hydrocarbon fuel oil (HFO), mixture oil lubricant and fuel oil (MOLFO) and waste oil (WO) dominate the oil types with a total variance of 99.51% with ANOVA giving F stat >F critical at 95% confidence level and a Chi Square goodness test of 74.87. Results obtained from this study reveals that by employing six-sigma approach in a data-driven problem such as in the case of oil spill classification, good decision making can be expedited. Copyright © 2017. Published by Elsevier Ltd.

Comparative effects of dietary corn oil, safflower oil, fish oil and palm oil on metabolism of ethanol and carnitine in the rat.

Science.gov (United States)

Sachan, Dileep S; Yatim, Ayub M; Daily, James W

2002-06-01

This study was launched to determine comparative effects of corn oil (CO), safflower oil (SO), fish oil (FO) and palm oil (PO) on carnitine status and ethanol metabolism in rats. Twenty-four male Sprague-Dawley rats (300 g bw) were randomly divided into four groups (n = 6) and fed a semisynthetic diets containing fat as oils listed above. Blood and 24 hour urine samples were collected before and after dietary treatment and acute ethanol administration. Samples were analyzed for blood-ethanol concentration (BEC) and carnitine species. The diets containing FO and PO retarded ethanol metabolism compared to the diets containing CO and SO. The effect of these dietary fats on carnitine species in plasma and urine was varied before and after dietary treatment and following a single oral ethanol dose. The liver carnitine content was higher in the PO group after dietary and ethanol treatment. It is concluded that attenuation of ethanol clearance was related to unique fatty acid makeup of the oils that in part may be attributed to the composite ratio of saturated to unsaturated fatty acids in the oils.

Wash-oil problem

Energy Technology Data Exchange (ETDEWEB)

Chlosta, J

1941-01-01

Meier-Grolman and others have deduced from experimental studies of the vapor pressure of solutions of benzene in paraffin oil and Solway oil-paraffin oil mixtures that the higher the proportion of aliphatic compounds in a wash oil, the less suitable it is for benzene scrubbing. This generalization is not supported. Paraffin oils from brown-coal tar and low viscous oils from the Fischer-Tropsch hydrocarbon synthesis process are both being successfully used for benzene scrubbing.

Oil-in-oil emulsions stabilised solely by solid particles.

Science.gov (United States)

Binks, Bernard P; Tyowua, Andrew T

2016-01-21

A brief review of the stabilisation of emulsions of two immiscible oils is given. We then describe the use of fumed silica particles coated with either hydrocarbon or fluorocarbon groups in acting as sole stabilisers of emulsions of various vegetable oils with linear silicone oils (PDMS) of different viscosity. Transitional phase inversion of emulsions, containing equal volumes of the two oils, from silicone-in-vegetable (S/V) to vegetable-in-silicone (V/S) occurs upon increasing the hydrophobicity of the particles. Close to inversion, emulsions are stable to coalescence and gravity-induced separation for at least one year. Increasing the viscosity of the silicone oil enables stable S/V emulsions to be prepared even with relatively hydrophilic particles. Predictions of emulsion type from calculated contact angles of a silica particle at the oil-oil interface are in agreement with experiment provided a small polar contribution to the surface energy of the oils is included. We also show that stable multiple emulsions of V/S/V can be prepared in a two-step procedure using two particle types of different hydrophobicity. At fixed particle concentration, catastrophic phase inversion of emulsions from V/S to S/V can be effected by increasing the volume fraction of vegetable oil. Finally, in the case of sunflower oil + 20 cS PDMS, the study is extended to particles other than silica which differ in chemical type, particle size and particle shape. Consistent with the above findings, we find that only sufficiently hydrophobic particles (clay, zinc oxide, silicone, calcium carbonate) can act as efficient V/S emulsion stabilisers.

Comparative study of ozonized olive oil and ozonized sunflower oil

Directory of Open Access Journals (Sweden)

Díaz Maritza F.

2006-01-01

Full Text Available In this study the ozonized olive and sunflower oils are chemical and microbiologically compared. These oils were introduced into a reactor with bubbling ozone gas in a water bath at room temperature until they were solidified. The peroxide, acidity and iodine values along with antimicrobial activity were determined. Ozonization effects on the fatty acid composition of these oils were analyzed using Gas-Liquid Chromatographic Technique. An increase in peroxidation and acidity values was observed in both oils but they were higher in ozonized sunflower oil. Iodine value was zero in ozonized olive oil whereas in ozonized sunflower was 8.8 g Iodine per 100 g. The antimicrobial activity was similar for both ozonized oils except for Minimum Bactericidal Concentrations of Pseudomona aeruginosa. Composition of fatty acids in both ozonized oils showed gradual decrease in unsaturated fatty acids (C18:1, C18:2 with gradual increase in ozone doses.

Oil crises

International Nuclear Information System (INIS)

Linderoth, H.

1992-01-01

The author's aim was to give very precise information on the many causes and effects of the oil crises that have occurred since 1900, and at the same time offer the reader the possibility to build up a basic knowledge of the oil industry and market, as he feels that the public is often subjected to misleading information. Political and economical aspects are elaborated. First-hand sources such as statistics and investigations have been used as far as possible to give information on the oil market. An oil crisis is defined by the author as a significant change in the price of oil compared to prices of other goods. Changes can be in the form of either rising or falling prices. A special chapter concentrates on Denmark in relation to the oil crises. (AB) (165 refs.)

[Efficiency evaluation of capsaicinoids to discriminate bio-waste oils from edible vegetable oils].

Science.gov (United States)

Mao, Lisha; Liu, Honghe; Kang, Li; Jiang, Jie; Liao, Shicheng; Liu, Guihua; Deng, Pingjian

2014-07-01

To evaluate the efficiency of capsaicinoids to discriminate bio-waste oil from edible vegetable oil. 14 raw vegetable oils, 24 fried waste oils, 34 kitchen-waste oils, 32 edible non-peanut vegetable oil, 32 edible peanuts oil, 16 edible oil add flavorand and 11 refined bio-waste oils were prepared and examined for capsaicinoids including capsaicin, dihydrocapsaicin and nonylic acid vanillylamide. The detection results of the above samples were statistically tested based on sample category to assessment identify the effectiveness of the bio-waste oils with capsaicinoids. As a indicator, capsaincin was possessed of high detection sensitivity and has the highest efficiency to discern kitchen-waste oils and refined bio-waste oils samples from edible non-peanut vegetable oil correctly. The accuracy rate of identification were 100% and 90.1% respectively. There is the background in peanut oil. CONCLUSION Capsaicin added in cooking process can be retained in the refining process and hardly be removed in the refining process. In the case of fully eliminating the background interference, capsaicinoids can effectively identify bio-waste oils and edible vegetable oil in combination.

Oil trading manual

International Nuclear Information System (INIS)

Long, D.

1995-01-01

This manual provides basic information on all aspects of oil trading. Topics reviewed in Part 1 include physical characteristics and refining and oil pricing arrangements. Part 2 on instruments and markets contains chapters on crude oil markets, product markets, forward and futures contracts, forward paper markets, oil future exchanges, options, swaps and long term oil markets. Part 3 deals with administration and has chapters on operations and logistics, credit control, accounting, taxation of oil trading, contracts and legal and regulatory issues. (UK)

Myristica oil poisoning

Science.gov (United States)

Nutmeg oil; Myristicin ... Myristica oil ( Myristica fragrans ) can be harmful. It comes from the seed of a nutmeg. ... Myristica oil is found in: Aromatherapy products Mace Nutmeg Other products may also contain myristica oil.

Mining and oil. Oil shale's contribution to future oil supply; Bergbau und Oel. Der Beitrag des Oelschiefers zur Oelversorgung

Energy Technology Data Exchange (ETDEWEB)

Linden, Eike von der [Linden Advisory, Dreieich (Germany)

2012-05-15

Crude oil contributes in Germany and globally approximately one third to the consumption of primary energies and actually is and in the foreseeable future will be the most important energy source. Recently shale oil as an unconventional oil has gained attention in public discussions. Depending on temperatures oil shale contains either already matured fluid shale oil or immature waxy kerogen. For determination of kerogen containing oil shale and shale oil common definitions for fluid hydrocarbons will be presented. Fluid hydrocarbons (molecular chains > C{sub 5}H{sub 12}) originate from animal substance which had been settled millions of years in sediments on sea- or lakebeds under anaerobic conditions. High pressure and high temperatures effect conversion to hydrocarbons. With sufficient permeability the liquid hydrocarbons migrate from the sediment as the source rock and get assembled in porous rocks under the cover of an impermeable rock strata, in so called entrapment structures. In case there is no impermeable rock strate the hydrocarbons will diffuse into the atmosphere. The hydrocarbons in entrapment structures are called conventional oil and are extracted by drilling wells. The extractable oil as part of the oil in place depends on the viscosity of the oil, the permeability of the host rock and applied exploitation methods which can affect pressure, viscosity and permeability. The exploitation achieves 30 to 50% of the oil in place. When the source rock consisting of strata hundreds of meters thick is not sufficiently permeable the matured hydrocarbons remain at its place of origination. These hydrocarbons are called shale oil and belong to the unconventional oil resources. For exploitation of shale oil by wells the source rock must be treated by intensive energy input, amongst others, by fracking which creates artificial permeability and by pressure which affects migration of the hydrocarbons to the well. The exploitation methods for shale oil do not

Comparison of lubricant properties of castor oil and commercial engine oil

Directory of Open Access Journals (Sweden)

Binfa Bongfa

2015-06-01

Full Text Available The tribological performance of crude Nigeria-based castor oil has been investigated and compared with that of a foreign, 20W-50 high quality crankcase oil, to see its suitability as base oil for lubricating oils in indigenous vehicle and power plants engines. The experiment was conducted using a four ball tester. The results showed that unrefined castor oil has superior friction reduction and load bearing capability in an unformulated form than the commercial oil; can compete favourably with the commercial oil in wear protection when formulated with suitable antiwear agent, hence can be a good alternative base stock for crankcase oils suitable for Nigeria serviced vehicles, and plants engines from tribological, environmental, and non-food competitive points of view.

RESEARCH OIL RECOVERY MECHANISMS IN HEAVY OIL RESERVOIRS

Energy Technology Data Exchange (ETDEWEB)

Anthony R. Kovscek; William E. Brigham

1999-06-01

The United States continues to rely heavily on petroleum fossil fuels as a primary energy source, while domestic reserves dwindle. However, so-called heavy oil (10 to 20{sup o}API) remains an underutilized resource of tremendous potential. Heavy oils are much more viscous than conventional oils. As a result, they are difficult to produce with conventional recovery methods such as pressure depletion and water injection. Thermal recovery is especially important for this class of reservoirs because adding heat, usually via steam injection, generally reduces oil viscosity dramatically. This improves displacement efficiency. The research described here was directed toward improved understanding of thermal and heavy-oil production mechanisms and is categorized into: (1) flow and rock properties; (2) in-situ combustion; (3) additives to improve mobility control; (4) reservoir definition; and (5) support services. The scope of activities extended over a three-year period. Significant work was accomplished in the area of flow properties of steam, water, and oil in consolidated and unconsolidated porous media, transport in fractured porous media, foam generation and flow in homogeneous and heterogeneous porous media, the effects of displacement pattern geometry and mobility ratio on oil recovery, and analytical representation of water influx. Significant results are described.

Experimental study on kinetics oil oil-suspended particulate matter aggregation

International Nuclear Information System (INIS)

Sun, J.; Environment Canada, Ottawa, ON; Khelifa, A.; Wang, Z.; Brown, C.; Fieldhouse, B.; Yang, C.; Zheng, X.; Wong, S.; So, L.C.

2009-01-01

Past studies of oil spills have shown that oil suspended particulate matter aggregates (OSAs) play a role in enhancing the natural cleansing of oiled shorelines. OSAs result from aggregation between suspended oil droplets and suspended particulate matter (SPM) in aquatic environments. During this process, oil dispersion into the water column is significantly increased since the surface of the oil droplet is surrounded by sediment particles. In addition, the accelerated biodegradation of the oil can be attributed to the greater oil-water contact area. This study focused on the kinetic aspects of OSA formation, with particular reference to the time scale of this process and its significance to oil dispersion following oil spills in water. A laboratory study was conducted to measure the time scale of OSA formation and its variations with mixing conditions. A reciprocating shaker and various oil/sediment mixtures were used to prepare the OSAs. Standard reference material 1941b was used as the natural sediment mixed with Arabian medium crude and artificial seawater under various mixing energies. The sediment-to-oil ratio remained constant for all experiments. Gas chromatography-flame ionization detection (GC-FID) analysis was used to measure the total petroleum hydrocarbons (TPH) trapped in negatively buoyant OSAs. Results showed that the TPH in OSAs increased exponentially with shaking time and reached an equilibrium value within 3 hours. The equilibrium decreased from 3 hours to 1.3 hours when the shaking rate increased from 2.0 to 2.3 Hz. It was concluded that high mixing energy enhances OSA formation and shortens the time for OSA formation. 42 refs., 6 tabs., 5 figs

Experimental study on kinetics oil oil-suspended particulate matter aggregation

Energy Technology Data Exchange (ETDEWEB)

Sun, J. [Ocean Univ. of China, Qingdoa (China). Environmental Science and Engineering Inst.; Environment Canada, Ottawa, ON (Canada). Emergencies Science and Technology Section, Emergencies, Operational Analytical Laboratories and Research Support Division; Khelifa, A.; Wang, Z.; Brown, C.; Fieldhouse, B.; Yang, C. [Environment Canada, Ottawa, ON (Canada). Emergencies Science and Technology Section, Emergencies, Operational Analytical Laboratories and Research Support Division; Zheng, X. [Ocean Univ. of China, Qingdoa (China). Environmental Science and Engineering Inst.; Wong, S. [Ottawa Univ., ON (Canada). Dept. of Chemistry; So, L.C. [Waterloo Univ., ON (Canada). Faculty of Engineering

2009-07-01

Past studies of oil spills have shown that oil suspended particulate matter aggregates (OSAs) play a role in enhancing the natural cleansing of oiled shorelines. OSAs result from aggregation between suspended oil droplets and suspended particulate matter (SPM) in aquatic environments. During this process, oil dispersion into the water column is significantly increased since the surface of the oil droplet is surrounded by sediment particles. In addition, the accelerated biodegradation of the oil can be attributed to the greater oil-water contact area. This study focused on the kinetic aspects of OSA formation, with particular reference to the time scale of this process and its significance to oil dispersion following oil spills in water. A laboratory study was conducted to measure the time scale of OSA formation and its variations with mixing conditions. A reciprocating shaker and various oil/sediment mixtures were used to prepare the OSAs. Standard reference material 1941b was used as the natural sediment mixed with Arabian medium crude and artificial seawater under various mixing energies. The sediment-to-oil ratio remained constant for all experiments. Gas chromatography-flame ionization detection (GC-FID) analysis was used to measure the total petroleum hydrocarbons (TPH) trapped in negatively buoyant OSAs. Results showed that the TPH in OSAs increased exponentially with shaking time and reached an equilibrium value within 3 hours. The equilibrium decreased from 3 hours to 1.3 hours when the shaking rate increased from 2.0 to 2.3 Hz. It was concluded that high mixing energy enhances OSA formation and shortens the time for OSA formation. 42 refs., 6 tabs., 5 figs.

Oil intensities and oil prices : evidence for Latin America

OpenAIRE

Alaimo, Veronica; Lopez, Humberto

2008-01-01

Crude oil prices have dramatically increased over the past years and are now at a historical maximum in nominal terms and very close to it in real terms. It is difficult to argue, at least for net oil importers, that higher oil prices have a positive impact on welfare. In fact, the negative relationship between oil prices and economic activity has been well documented in the literature. Ye...

A catalogue of crude oil and oil product properties, 1990

International Nuclear Information System (INIS)

Bobra, M.A.; Callaghan, S.

1990-09-01

This catalogue is a compilation of available data on crude oils and petroleum products. The emphasis of the catalogue is upon oils which could potentially impact Canada's environment. Other oils which are unlikely to be of direct Canadian concern are also included because they have been well characterized and used in relevant studies. The properties listed for each oil are those which will provide an indication of a spilled oil's environmental behaviour and effects. The properties on which data is provided include API gravity, density, viscosity, interfacial tension, pour point, flash point, vapor pressure, volatility and component distribution, emulsion formation tendency and stability, weathering, dispersability, major hydrocarbon groups, aqueous solubility, toxicity, sulfur content, fire point, and wax content. Most of the chemical-physical properties listed in this catalogue were measured using standard tests. For certain properties, data are given at different temperatures and for different degrees of oil weathering. An oil's degree of weathering is expresed as the volume or weight percent evaporated from the fresh oil. Weathered oils used for testing were artificially weathered by gas stripping following the method of Mackay and Stiver. 109 refs

A catalogue of crude oil and oil product properties, 1992

International Nuclear Information System (INIS)

Whiticar, S.; Bobra, M.; Liuzzo, P.; Callaghan, S.; Fingas, M.; Jokuty, P.; Ackerman, F.; Cao, J.

1993-02-01

This catalogue is a compilation of available data on crude oils and petroleum products. The emphasis of the catalogue is upon oils which could potentially impact Canada's environment. Other oils which are unlikely to be of direct Canadian concern are also included because they have been well characterized and used in relevant studies. The properties listed for each oil are those which will provide an indication of a spilled oil's environmental behaviour and effects. The properties on which data is provided include API gravity, density, viscosity, interfacial tension, pour point, flash point, vapor pressure, volatility and component distribution, emulsion formation tendency and stability, weathering, dispersability, major hydrocarbon groups, aqueous solubility, toxicity, sulfur content, fire point, and wax content. Most of the chemical-physical properties listed in this catalogue were measured using standard tests. For certain properties, data are given at different temperatures and for different degrees of oil weathering. An oil's degree of weathering is expresed as the volume or weight percent evaporated from the fresh oil. Weathered oils used for testing were artificially weathered by gas stripping following the method of Mackay and Stiver. 140 refs

Neutron Backscattered Technique for Quantification of Oil Palm Fruit Oil Content

International Nuclear Information System (INIS)

Ismail Mustapha; Samihah Mustaffha; Md Fakarudin Ab Rahman; Roslan Yahya; Lahasen Norman Shah Dahing; Nor Paiza Mohd Hasan; Jaafar Abdullah

2013-01-01

Non-destructive and real time method becomes a well-liked method to researchers in the oil palm industry since 2000. This method has the ability to detect oil content in order to increase the production of oil palm for better profit. Hence, this research investigates the potential of neutron source to estimate oil content in palm oil fruit since oil palm contains hydrogen with chemical formula C 55 H 96 O 6 . For this paper, oil palm loose fruit was being used and divided into three groups. These three groups are ripe, under-ripe and bruised fruit. A total of 21 loose fruit for each group were collected from a private plantation in Malaysia. Each sample was scanned using neutron backscattered technique. The higher neutron count, the more hydrogen content, and the more oil content in palm oil fruit. The best correlation result came from the ripe fruits with r 2 =0.98. This research proves that neutron backscattered technique can be used as a non-destructive and real time grading system for palm oil. (author)

Mitsubishi Oil to become a major oil player?

International Nuclear Information System (INIS)

Ash, N.

1994-01-01

Mitsubishi Oil became a wholly-owned Japanese company in 1984. Before that, since 1981, it had been a joint venture between Mitsubishi and Getty oil. Recently the company has discovered a major new oilfield off the coast of Vietnam. In addition it has a strategic stake in the Canadian Athabasca Far Sands, major investments in Angola and operations in Papua New Guinea and Gabon. It aims to cover 30 % of the crude oil imports to its four existing, and fifth projected, refineries from owned sources by the end of the century. Mitsubishi has a network of 4500 service stations in Japan and has become one of the largest lubricating oil producers. The company's main overseas sales are of jet fuel, lubricating and tanker oils, sulphur and some petrochemicals. (UK)

Recycling used palm oil and used engine oil to produce white bio oil, bio petroleum diesel and heavy fuel

Science.gov (United States)

Al-abbas, Mustafa Hamid; Ibrahim, Wan Aini Wan; Sanagi, Mohd. Marsin

2012-09-01

Recycling waste materials produced in our daily life is considered as an additional resource of a wide range of materials and it conserves the environment. Used engine oil and used cooking oil are two oils disposed off in large quantities as a by-product of our daily life. This study aims at providing white bio oil, bio petroleum diesel and heavy fuel from the disposed oils. Toxic organic materials suspected to be present in the used engine oil were separated using vacuum column chromatography to reduce the time needed for the separation process and to avoid solvent usage. The compounds separated were detected by gas chromatography-mass spectrometry (GC-MS) and found to contain toxic aromatic carboxylic acids. Used cooking oils (thermally cracked from usage) were collected and separated by vacuum column chromatography. White bio oil produced was examined by GC-MS. The white bio oil consists of non-toxic hydrocarbons and is found to be a good alternative to white mineral oil which is significantly used in food industry, cosmetics and drugs with the risk of containing polycyclic aromatic compounds which are carcinogenic and toxic. Different portions of the used cooking oil and used engine were mixed to produce several blends for use as heavy oil fuels. White bio oil was used to produce bio petroleum diesel by blending it with petroleum diesel and kerosene. The bio petroleum diesel produced passed the PETRONAS flash point and viscosity specification test. The heat of combustion of the two blends of heavy fuel produced was measured and one of the blends was burned to demonstrate its burning ability. Higher heat of combustion was obtained from the blend containing greater proportion of used engine oil. This study has provided a successful recycled alternative for white bio oil, bio petroleum fuel and diesel which can be an energy source.

Global Trends and Development Prospects for Oil and the Oil Products Market

Directory of Open Access Journals (Sweden)

Maria Dorozhkina

2006-03-01

Full Text Available This article discusses the important issue of the development of the global market of oil and oil products. It offers an overview of how this market was formed and its current status, classification, location and potential of countries in the oil and oil processing business. It analyzes the Ukrainian oil products market. The article discusses the shortcomings and strategic areas for the development of Ukraine’s oil transport system. It presents an optimum method for creating integration groups in order to develop the oil processing business in Ukraine for the future. The article considers the main trends and outlines development prospects for the global oil and oil products market.

The oil price

International Nuclear Information System (INIS)

Alba, P.

2000-01-01

Statistical analysis cannot, alone, provide an oil price forecast. So, one needs to understand the fundamental phenomena which control the past trends since the end of world war II After a first period during which oil, thanks to its abundance, was able to increase its market share at the expense of other energies, the first oil shock reflects the rarefaction of oil resource with the tilting of the US production curve from growth to decline. Since then, the new situation is that of a ''cohabitation'' between oil and the other energies with the oil price, extremely volatile, reflecting the trial and error adjustment of the market share left to the other energies. Such a context may explain the recent oil price surge but the analogy between the US oil situation at the time of the first shock and that existing today for the world outside Middle East suggest another possibility, that of a structural change with higher future oil prices. The authors examine these two possibilities, think that the oil price will reflect both as long as one or the other will not become proven, and conclude with a series of political recommendations. (authors)

Oil My Love

International Nuclear Information System (INIS)

Gay, Michel

2014-01-01

The author first describes how oil will disappear from non-producing countries, notably France and Europe and will therefore lead to an energy crisis. He outlines that renewable energies will have a weak contribution in the replacement of fossil energies (in this case, oil and gas). To illustrate these trends, the author proposes an appendix which presents and discusses the evolution of global consumption of fossil fuels, the evolution of production of different oil grades, a forecast of global oil demand by 2035, evolutions of productions and exports. Another appendix discusses additional issues on oil: the meaning of reserves, solutions for France in case of shortage of oil, the world oil situation (USA, China, Russia, the European Union, Japan)

Non-Petroleum Oils

Science.gov (United States)

These include synthetics such as silicone fluids and tung oils, wood-derivative oils such as resin/rosin, animal fats/oil, and seed oils. Many have similar physical properties to petroleum-based, such as water insolubility and formation of slicks.

Symposium DD: Low-Dimensional Materials-Synthesis, Assembly, Property Scaling and Modeling. Held in San Francisco, CA on April 9-13, 2007

Science.gov (United States)

2008-06-01

Ciencia e Ingenieria de los Materiales , Universidad de Costa Rica, San Jose, Costa Rica. We have developed a new unifying tight-binding theory that...Fisico Matem6ticas, Universidad Aut6noma de Nuevo Le6n, San Nicolas de los Garza, Nuevo LeAfA3n, Mexico; 2Chemical Engineering Department and Texas...ORNL), Oak Ridge, Tennessee; 2Departamento de Ciencia de los Materiales e IM y QI, Universidad de Cadiz, Puerto Real, Cadiz, Spain; 3Departamento de

Hydrocarbon oils

Energy Technology Data Exchange (ETDEWEB)

Foorwood, G F; Taplay, J G

1916-12-12

Hydrocarbon oils are hydrogenated, cracked, or treated for the removal of sulfur by bringing their vapors mixed with steam at temperatures between 450 and 600/sup 0/C into contact with a form of carbon that is capable of decomposing steam with the production of nascent hydrogen at those temperatures. The forms of carbon used include lamp-black, soot, charcoals derived from wood, cellulose, and lignite, and carbons obtained by carbonizing oil residues and other organic bodies at temperatures below 600/sup 0/C. The process is applied to the treatment of coal oil, shale oil, petroleum, and lignite oil. In examples, kerosene is cracked at 570/sup 0/C, cracked spirit is hydrogenated at 500/sup 0/C, and shale spirit is desulfurized at 530/sup 0/C. The products are led to a condenser and thence to a scrubber, where they are washed with creosote oil. After desulfurization, the products are washed with dilute caustic soda to remove sulfurretted hydrogen.

The oil industry in 2007

International Nuclear Information System (INIS)

2008-01-01

The various contributions present and comment many data about the evolutions of different parts of the oil industry until 2007: world oil and gas markets, worldwide oil exploration and production, oil exploration and production in France, oil and oil-related industry in France, hydrocarbon supplies, oil refining in France, fuel quality, substitution fuels, inner transportation of oil products, storage of oil products, consumption of oil products, taxing of oils products, price of oil products, distribution of oil products

The oil industry in 2006

International Nuclear Information System (INIS)

2007-01-01

The various contributions present and comment many data about the evolutions of different parts of the oil industry until 2006: world oil and gas markets, worldwide oil exploration and production, oil exploration and production in France, oil and oil-related industry in France, hydrocarbon supplies, oil refining in France, fuel quality, substitution fuels, inner transportation of oil products, storage of oil products, consumption of oil products, taxing of oils products, price of oil products, distribution of oil products

Detection of olive oil adulteration by low-field NMR relaxometry and UV-Vis spectroscopy upon mixing olive oil with various edible oils

Directory of Open Access Journals (Sweden)

S. Ok

2017-03-01

Full Text Available Adulteration of olive oil using unhealthy substitutes is considered a threat for public health. Low-field (LF proton (1H nuclear magnetic resonance (NMR relaxometry and ultra-violet (UV visible spectroscopy are used to detect adulteration of olive oil. Three different olive oil with different oleoyl acyl contents were mixed with almond, castor, corn, and sesame oils with three volumetric ratios, respectively. In addition, Arbequina olive oil was mixed with canola, flax, grape seed, peanut, soybean, and sunflower seed oils with three volumetric ratios. Transverse magnetization relaxation time (T2 curves were fitted with bi-exponential decaying functions. T2 times of each mixture of olive oils and castor oils, and olive oils and corn oils changed systematically as a function of volumetric ratio. To detect the adulteration in the mixtures with almond and sesame oils, both LF 1H NMR relaxometry and UV-Vis spectroscopy were needed, where UV-Vis-spectroscopy detected the adulteration qualitatively. In the mixtures of Arbequina olive oil and flax, peanut, soybean, and sunflower seed oils, both T21 and T22 values became longer systematically as the content of the olive oil was decreased. The unique UV-Vis maximum absorbance of flax oil at 320.0 nm shows the adulteration of olive oil qualitatively.

Detection of olive oil adulteration by low-field NMR relaxometry and UV-Vis spectroscopy upon mixing olive oil with various edible oils

International Nuclear Information System (INIS)

Ok, S.

2017-01-01

Adulteration of olive oil using unhealthy substitutes is considered a threat for public health. Low-field (LF) proton (1H) nuclear magnetic resonance (NMR) relaxometry and ultra-violet (UV) visible spectroscopy are used to detect adulteration of olive oil. Three different olive oil with different oleoyl acyl contents were mixed with almond, castor, corn, and sesame oils with three volumetric ratios, respectively. In addition, Arbequina olive oil was mixed with canola, flax, grape seed, peanut, soybean, and sunflower seed oils with three volumetric ratios. Transverse magnetization relaxation time (T2) curves were fitted with bi-exponential decaying functions. T2 times of each mixture of olive oils and castor oils, and olive oils and corn oils changed systematically as a function of volumetric ratio. To detect the adulteration in the mixtures with almond and sesame oils, both LF 1H NMR relaxometry and UV-Vis spectroscopy were needed, where UV-Vis-spectroscopy detected the adulteration qualitatively. In the mixtures of Arbequina olive oil and flax, peanut, soybean, and sunflower seed oils, both T21 and T22 values became longer systematically as the content of the olive oil was decreased. The unique UV-Vis maximum absorbance of flax oil at 320.0 nm shows the adulteration of olive oil qualitatively. [es

Kolkhoung (Pistacia khinjuk Hull Oil and Kernel Oil as Antioxidative Vegetable Oils with High Oxidative Stability and Nutritional Value

Directory of Open Access Journals (Sweden)

Maryam Asnaashari

2015-01-01

Full Text Available In this study, in order to introduce natural antioxidative vegetable oil in food industry, the kolkhoung hull oil and kernel oil were extracted. To evaluate their antioxidant efficiency, gas chromatography analysis of the composition of kolkhoung hull and kernel oil fatty acids and high–performance liquid chromatography analysis of tocopherols were done. Also, the oxidative stability of the oil was considered based on the peroxide value and anisidine value during heating at 100, 110 and 120 °C. Gas chromatography analysis showed that oleic acid was the major fatty acid of both types of oil (hull and kernel and based on a low content of saturated fatty acids, high content of monounsaturated fatty acids, and the ratio of ω-6 and ω-3 polyunsaturated fatty acids, they were nutritionally well-balanced. Moreover, both hull and kernel oil showed high oxidative stability during heating, which can be attributed to high content of tocotrienols. Based on the results, kolkhoung hull oil acted slightly better than its kernel oil. However, both of them can be added to oxidation–sensitive oils to improve their shelf life.

Neogene to recent contraction and basin inversion along the Nubia-Iberia boundary in SW Iberia

Science.gov (United States)

Ramos, Adrià; Fernández, Oscar; Terrinha, Pedro; Muñoz, Josep Anton

2017-02-01

The SW of Iberia is currently undergoing compression related to the convergence between Nubia and Iberia. Multiple compressive structures, and their related seismic activity, have been documented along the diffuse Nubia-Iberia plate boundary, including the Gorringe bank west of the Gulf of Cadiz, and the Betic-Rif orogen to the east. Despite seismic activity indicating a dominant compressive stress along the Algarve margin in the Gulf of Cadiz, the structures at the origin of this seismicity remain elusive. This paper documents the contractional structures that provide linkage across the Gulf of Cadiz and play a major role in defining the present-day seismicity and bathymetry of this area. The structures described in this paper caused the Neogene inversion of the Jurassic oblique passive margin that formed between the central Atlantic and the Ligurian Tethys. This example of a partially inverted margin provides insights into the factors that condition the inversion of passive margins.

Experimental oil release on Haltenbanken 1982. Drifting and spreading of oil. [Norway

Energy Technology Data Exchange (ETDEWEB)

Soerstroem, S.E.; Johansen, Oe; Celius, K.K.; Audunson, T.; Steinbakke, P.

1984-03-29

In the experiment, 100 m/sup 3/ of Statfjord crude oil was released at Haltenbanken. The oil was followed for 7 days and projects concerning drifting and spreading of oil, microbiological decay and ecological effects, ecological studies of the impact on fish, zooplancton, fish eggs and larvae, training with equipment and control functions and experiment leading and coordination were carried out. In this project ''drifting and spreading of oil'' information on physical environment, decay of oil, mixing of oil in water, oil spill surveillance, warning and simulation and numerical modelling are collected. The results of these areas were compared to the mathematical simulation and warning models Oilsim and Sliktrak. New methods for in situ measurements for relative values of oil in water were used. It was found that most of the physical and chemical changes of oil spills occur during the first 24 hours. The drifting and alterations of the oil was recorded and a new simulation model for three-dimentional spreading of oil in water was made. 49 tables, 130 drawings, 32 references.

Oil biodegradation

NARCIS (Netherlands)

Rahsepar, Shokouhalsadat; Langenhoff, Alette A.M.; Smit, Martijn P.J.; Eenennaam, van Justine S.; Murk, Tinka; Rijnaarts, Huub H.M.

2017-01-01

During the Deepwater Horizon (DwH) oil spill, interactions between oil, clay particles and marine snow lead to the formation of aggregates. Interactions between these components play an important, but yet not well understood, role in biodegradation of oil in the ocean water. The aim of this study

Estimation on oil demand and oil saving potential of China's road transport sector

International Nuclear Information System (INIS)

Lin, Boqiang; Xie, Chunping

2013-01-01

China is currently in the stage of industrialization and urbanization, which is characterized by rigid energy demand and rapid growth of energy consumption. Therefore, energy conservation will become a major strategy for China in a transition to low-carbon economy. China's transport industry is of high energy consumption. In 2010, oil consumption in transport industry takes up 38.2% of the country's total oil demand, of which 23.6% is taken up by road transport sector. As a result, oil saving in China's road transport sector is vital to the whole nation. The co-integration method is developed to find a long-run relationship between oil consumption and affecting factors such as GDP, road condition, labor productivity and oil price, to estimate oil demand and to predict future oil saving potential in China's transport sector under different oil-saving scenarios. Monte Carlo simulation is further used for risk analysis. Results show that under BAU condition, oil demand of China's road transport sector will reach 278.5 million ton of oil equivalents (MTOE) in 2020. Oil saving potential will be 86 MTOE and 131 MTOE under moderate oil-saving scenario and advanced oil-saving scenario, respectively. This paper provides a reference to establishing oil saving policy for China's road transport sector. - Highlights: • We adopt the co-integration model to estimate oil demand and oil saving potential of China's road transport sector. • Monte Carlo simulation is further used for risk analysis. • GDP, ratio of classified highway, labor productivity and oil price are main factors affecting oil consumption. • Scenario analysis approach is applied to calculate oil saving potential under different energy saving scenarios. • Future policy for oil conservation in China's road transport sector is suggested

Cracking hydrocarbon oils

Energy Technology Data Exchange (ETDEWEB)

Seigle, A A.F.M.

1922-12-20

Hydrocarbon oils such as petroleum, peat, shale, or lignite oils, heavy tars, resin oils, naphthalene oils, etc., are vaporized by being fed from a tank through a preheater to the lower part of a vertical annular retort heated by a flame projected down the central cavity from a burner. The oil vapors rise through annular passages formed by disks, on which are placed chips of copper, iron, aluminum, etc., to act as catalysts.

Efficient way of importing crude oil from oil producing countries - A review on diversification policy of crude oil import

Energy Technology Data Exchange (ETDEWEB)

Lee, Dal Sok [Korea Energy Economics Institute, Euiwang (Korea)

1999-03-01

Since the second oil crisis, the government has operated the import diversification support program to reduce the risk of crude oil import from Middle-East region and to raise the ability of dealing with the risk. This study tried to seek policy trends in future through reviewing the market environment related to the crude oil import diversification policy and the goal, instrument and effect of the policy. The supply and demand of crude oil and the price are influenced by market system in the world oil market and there are various types of crude oil trading available to both sellers and buyers. There is a probability that the suspension of supply in a certain area could be led to the price issue rather than the physical use of crude oil. In addition, the advantage of price with long-term contract of crude oil was abolished since the price of crude oil imported by term contract has been linked to spot prices. As a result, it is shown that the potential benefit from crude oil import diversification policy is reduced although political and social insecurity still exists in Middle-East region. Therefore, it is desirable to maintain the existing support program until the amount of stored oil reaches the optimum level and to help private enterprises determine the import considering economical efficiency and risk. (author). 36 refs., 5 figs., 23 tabs.

Transformer oil maintenance

Energy Technology Data Exchange (ETDEWEB)

White, J. [A.F. White Ltd., Brantford, ON (Canada)

2002-08-01

Proactive treatment is required in the case of transformer oil, since the oil degrades over time, which could result in the potential failure of the transformer or costly repairs. A mineral-based oil is used for transformers because of its chemical properties and dielectric strength. Water and particulate are the main contaminants found in transformer oil, affecting the quality of the oil through reduced insulation. Acid that forms in the oil when reacting with oxygen is called oxidization. It reduces the heat dissipation of the transformer as the acid forms sludge which settles on the windings of the transformer. The first step in the preventive maintenance program associated with transformer oil is the testing of the oil. The base line is established through initial testing, and subsequent annual testing identifies any changes. The minimal requirements are: (1) dielectric breakdown, a measure of the voltage conducted by the oil; (2) neutralization/acid number, which detects the level of acid present in the oil; (3) interfacial tension, which identifies the presence of polar compounds; (4) colour, which displays quality, aging and the presence of contaminants; and (5) water, which decreases the dielectric breakdown voltage. The analysis of the gases present in the oil is another useful tool in a maintenance program for the determination of a possible fault such as arcing, corona or overheated connections and is accomplished through Dissolved Gas Analysis (DGA). Remediation treatment includes upgrading the oil. Ideally, reclamation should be performed in the early stages of the acid buildup before sludging occurs. Onsite reclamation includes Fuller's earth processing and degasification, a process briefly described by the author.

Oil mixing behavior after an oil spill: identification conflicts of different fingerprints.

Science.gov (United States)

He, Shijie; Yu, Hongjun; Luo, Yongming; Wang, Chuanyuan; Li, Xueshuang; Li, Zhongping

2018-04-01

Clearing up whether spilled oil is mixed or not can strengthen the accuracy of oil spill identification. In the present study, the biomarkers in spilled oil samples were detected. The weathering modes of different types of diagnostic ratio and carbon isotope values of individual n-alkanes were also analyzed. The results showed that the diagnostic ratios of steroids, terpenes and aromatics, and weathering characteristics of carbon isotope composition (δ 13 C) of individual n-alkanes supported the idea that Dalian oil spill emerged from a single oil source. Furthermore, commonly used diagnostic ratios of n-alkanes indicated that the Dalian oil spill had undergone the oil mixing process. The different identifying outcomes indicate that some kinds of n-alkane-rich substance (such as oil dispersants) were mixed in the Dalian spilled oil and interfered with the routine diagnosis ratios of n-alkanes.

Stabilization of Softwood-Derived Pyrolysis Oils for Continuous Bio-oil Hydroprocessing

Energy Technology Data Exchange (ETDEWEB)

Olarte, Mariefel V.; Zacher, Alan H.; Padmaperuma, Asanga B.; Burton, Sarah D.; Job, Heather M.; Lemmon, Teresa L.; Swita, Marie S.; Rotness, Leslie J.; Neuenschwander, Gary N.; Frye, John G.; Elliott, Douglas C.

2015-10-15

The use of fast pyrolysis as a potential renewable liquid transportation fuel alternative to crude oil depends on successful catalytic upgrading to produce a refinery-ready product with oxygen content and qualities (i.e. specific functional group or compound content) that is compatible with the product’s proposed insertion point. Catalytic upgrading of bio-oil requires high temperature and pressure, while similar to crude oil hydrotreating, is not as straightforward for the thermally unstable pyrolysis oil. For years, a two-temperature zone, downflow trickle bed reactor was the state-of-the art for continuous operation. However, pressure excursion due to plug formation still occurred, typically at the high temperature transition zone, leading to a process shutdown within 140 h. Recently, a bio-oil pre-treatment process, together with a robust commercial catalyst, was found to be enabling the continuous operation of the two-zone hydroprocessing system. Here, we report the results on pre-treating bio-oil at 413 K and 8.4 MPa of flowing H2 (500 L H2/L bio-oil, 0.5 L bio-oil/L catalyst bed) and the attempts to characterize this oil product to understand the chemistry which enabled the long-term processing of bio-oil.

Kolkhoung (Pistacia khinjuk) Hull Oil and Kernel Oil as Antioxidative Vegetable Oils with High Oxidative Stability 
and Nutritional Value.

Science.gov (United States)

Asnaashari, Maryam; Hashemi, Seyed Mohammad Bagher; Mehr, Hamed Mahdavian; Yousefabad, Seyed Hossein Asadi

2015-03-01

In this study, in order to introduce natural antioxidative vegetable oil in food industry, the kolkhoung hull oil and kernel oil were extracted. To evaluate their antioxidant efficiency, gas chromatography analysis of the composition of kolkhoung hull and kernel oil fatty acids and high-performance liquid chromatography analysis of tocopherols were done. Also, the oxidative stability of the oil was considered based on the peroxide value and anisidine value during heating at 100, 110 and 120 °C. Gas chromatography analysis showed that oleic acid was the major fatty acid of both types of oil (hull and kernel) and based on a low content of saturated fatty acids, high content of monounsaturated fatty acids, and the ratio of ω-6 and ω-3 polyunsaturated fatty acids, they were nutritionally well--balanced. Moreover, both hull and kernel oil showed high oxidative stability during heating, which can be attributed to high content of tocotrienols. Based on the results, kolkhoung hull oil acted slightly better than its kernel oil. However, both of them can be added to oxidation-sensitive oils to improve their shelf life.

Oil/gas collector/separator for underwater oil leaks

International Nuclear Information System (INIS)

Henning, C.D.

1993-01-01

An oil/gas collector/separator for underwater oil leaks is described comprising: a cylindrical tank; a hollow float member for supporting said tank in a substantially upright position; a skirt assembly secured to said hollow float member and extending in a direction away from said float member opposite said tank; means for removing oil from said tank; and means for removing gas from said tank

Canada's crude oil resources : crude oil in our daily lives

International Nuclear Information System (INIS)

Bott, R.

2001-10-01

Created in 1975, the Petroleum Communication Foundation is a not-for-profit organization. The objective of the Foundation is to inform Canadians about the petroleum industry in Canada. It produces educational, fact-based publications and programs, employing a multi-stakeholder review process. The first section of this publication is devoted to crude oil and the benefits that are derived from it. It begins by providing a brief definition of crude oil, then moves to the many uses in our daily lives and the environmental impacts like air pollution, spills, and footprint on the land from exploration and production activities. Section 2 details the many uses of crude oil and identifies the major oil producing regions of Canada. A quick mention is made of non-conventional sources of crude oil. The search for crude oil is the topic of section 3 of the document, providing an overview of the exploration activities, the access rights that must be obtained before gaining access to the resource. The drilling of oil is discussed in section 4. Section 5 deals with issues pertaining to reservoirs within rocks, while section 6 covers the feeding of the refineries, discussing topics from the movement of oil to market to the refining of the crude oil, and the pricing issues. In section 7, the uncertain future is examined with a view of balancing the supply and demand, as crude oil is a non-renewable resource. Supplementary information is provided concerning additional publications published by various organizations and agencies. figs

Intrastate conflict in oil producing states: A threat to global oil supply?

International Nuclear Information System (INIS)

Toft, Peter

2011-01-01

In this paper I investigate how often and how much outbreaks of intrastate conflict in oil producing states translates into oil supply shortfalls. The Libyan conflict that broke out in February 2011 highlighted the fear that intrastate conflict in oil producing states may imply shortfalls and ensuing volatile global oil prices. I argue, however, that it is far from certain that shortfalls following conflict outbreak will occur, since both sides in a conflict face incentives simultaneously to protect and maintain oil installations and to strike and destroy these. Based on a quantitative analysis of 39 intrastate wars in oil producing countries (1965-2007) I conclude that outbreak of conflict does not translate into production decline with any certainty. In fact, likelihoods are less than 50% for reductions to occur. In many cases growing production actually followed conflict outbreak. I conclude by investigating four characteristics of intrastate conflict that may explain when oil production is at risk during conflict: (1) proximity of oil producing fields to key battle zones, (2) duration of conflict, (3) separatism and the location of oil in separatist territory, and (4) the relative size of oil production. While the first three factors did not prove important, oil producer size could be significant. But further research is needed to establish this with greater certainty. - Highlights: → Oil shortfall during intrastate conflict is not a given. → Statistical analysis of 39 intrastate conflicts in oil producing countries since 1965. → Examination of four characteristics of intrastate conflict in oil producing countries. → Marginal significance related to large producers and production shortfall.

Intrastate conflict in oil producing states: A threat to global oil supply?

Energy Technology Data Exchange (ETDEWEB)

Toft, Peter, E-mail: peter.toft@ec.europa.eu [Institute for Energy, Joint Research Centre of the European Commission, Westerduinweg 3, 1755 ZG Petten (Netherlands)

2011-11-15

In this paper I investigate how often and how much outbreaks of intrastate conflict in oil producing states translates into oil supply shortfalls. The Libyan conflict that broke out in February 2011 highlighted the fear that intrastate conflict in oil producing states may imply shortfalls and ensuing volatile global oil prices. I argue, however, that it is far from certain that shortfalls following conflict outbreak will occur, since both sides in a conflict face incentives simultaneously to protect and maintain oil installations and to strike and destroy these. Based on a quantitative analysis of 39 intrastate wars in oil producing countries (1965-2007) I conclude that outbreak of conflict does not translate into production decline with any certainty. In fact, likelihoods are less than 50% for reductions to occur. In many cases growing production actually followed conflict outbreak. I conclude by investigating four characteristics of intrastate conflict that may explain when oil production is at risk during conflict: (1) proximity of oil producing fields to key battle zones, (2) duration of conflict, (3) separatism and the location of oil in separatist territory, and (4) the relative size of oil production. While the first three factors did not prove important, oil producer size could be significant. But further research is needed to establish this with greater certainty. - Highlights: > Oil shortfall during intrastate conflict is not a given. > Statistical analysis of 39 intrastate conflicts in oil producing countries since 1965. > Examination of four characteristics of intrastate conflict in oil producing countries. > Marginal significance related to large producers and production shortfall.

Characterization of Oxidative Stability of Fish Oil- and Plant Oil-Enriched Skimmed Milk

DEFF Research Database (Denmark)

Saga, Linda C.; Kristinova, Vera; Kirkhus, Bente

2013-01-01

oat oil and camelina oil to protect fish oil in bulk and as fish oil-enriched skimmed milk emulsions was evaluated. Results of oxidative stability of bulk oils and blends assessed by the Schaal oven weight gain test and by the rancimat method showed significant increase in oxidative stability when oat...... oil was added to fish oil in only 5 and 10 %, whereas no protective effect of camelina oil was observed when evaluated by these methods. Moreover, fish oil blended with oat oil conferred the lowest PV and lower amounts of volatile compounds during the storage period of 14 days at 4 °C. Surprisingly......, skimmed milk supplemented with fish-oat oil blend gave the highest scores for off-flavors in the sensory evaluation, demonstrating that several methods, including sensory analysis, should be combined to illustrate the complete picture of lipid oxidation in emulsions....

Comparison between jojoba oil and other vegetable oils as a substitute to petroleum

Energy Technology Data Exchange (ETDEWEB)

El Kinawy, O. [National Research centre, Dokki, Cairo (Egypt)

2004-06-15

Jojoba oil and other vegetable oils, such as soybean, sunflower and castor oils, were evaluated to be used as lubricants. Three standard mineral lubricating oils were considered in this study as reference. The essential parameters tested for comparison were the oil viscosity, viscosity index, and viscosity--temperature and shear rate--shear stress relationships. The effect of excessive heating on the vegetable oils' stability was studied and the corresponding parameters were also measured. Jojoba oil was found to be the best among all tested oils, whereas it gave the minimum change in viscosity gradient and hence the highest viscosity index. There was a linear relation between shear rate and shear stress of all oils before and after heat deterioration. Therefore, these oils were considered as Newtonion liquids. However, the oil viscosity, as well as the rate of viscosity variation with temperature, ({delta}{sup '}{eta}/{delta}{tau}) were affected by heat deterioration being lowered in value, in case of jojoba oil, and higher value, in case of castor oil. Jojoba oil was examined for other important properties for its use as a lubricant, such as refractive index, acid value, peroxide value, saponification value, iodine value, flash, fire and pour points. (author)

Brief: Information technology outsourcing -- one company's experience

International Nuclear Information System (INIS)

Klochko, J.W.; Bester, L.W.

1994-01-01

To address the pressures of the 1990's business climate, Amoco Canada Petroleum Co. Ltd. went through an aggressive evaluation and restructuring of its business operations. This precipitated a critical review of its information technology (IT) strategy with a goal of maintaining effectiveness while reducing overall costs. To meet the challenge of substantially reducing expenses while continuing to maintain effective service levels, the company entered a 5-year agreement to outsource its data center and network operations. this paper discusses the business forces that brought Amoco Canada to consider outsourcing, the processes surrounding the outsourcing decision, and the results to date. The authors demonstrate that by understanding the role of IT in its business plans, the company successfully met its outsourcing objectives

The Study of the Desulfurization Process of Oil and Oil Products of "Zhanazhol" Oil Field Using the Approaches of Green Chemistry

OpenAIRE

Zhaksyntay K. Kairbekov; Zhannur K. Myltykbaeva; Nazym T. Smagulova; Dariya K. Kanseitova

2015-01-01

In this paper we studied sono catalytic oxidative desulfurization of oil and diesel fraction from “Zhanazhol” oil deposits. We have established that the combined effect of the ultrasonic field and oxidant (ozone-air mixture) in the presence of the catalyst on the oil is potentially very effective method of desulfurization of oil and oil products. This method allows increasing the degree of desulfurization of oil by 62%.

Shale oil. II. Gases from oil shale

Energy Technology Data Exchange (ETDEWEB)

McKee, R H; Manning, P D.V.

1927-01-01

Oil shale (from Colorado) was pyrolyzed, and the gaseous products obtained were studied. The organic material present in oil shale contains carboxyl groups that lose carbon dioxide during pyrolysis before the formation of soluble bitumen. Nitrogen was evolved as ammonia in two stages and was not continuous. The first evolution was from loosely combined nitrogen structures, whereas the second was from more stable forms. No hydrocarbons were present as such in the kerogen. The gaseous products from oil-shale pyrolysis were similar to those obtained by distillation of colophony, amber, coal, and wood. This places the kerogen of the oil shale in the same series of carbonaceous substances as those from which coals are formed. Kerogen appeared to be decomposed in three steps; namely, to insoluble bitumen, to soluble bitumen, and to oil (gas evolution accompanied each step). Its low solubility and the character of its pyrolytic gas indicated that kerogen is largely a resinous residue from vegetation of the past era and may have been formed by the tranportation of coal-forming organic debris to inland salty lakes or carried to the sea by clay-laden waters. The salt water and the natural settling action precipitated the clay and organic matter in an almost homogeneous deposit. Oil shales have existed to the present time because they have not been subjected to high pressures or elevated temperatures that would have changed them to petroleum.

Assessment of an oil palm population from Nigerian Institute for Oil ...

African Journals Online (AJOL)

Oil palm (Elaeis guineensis Jacq.), a monocotyledonous plant belonging to the Arecaceae family, is one of the most important oil crops in the world. In Nigeria, oil palm has benefited immensely from conventional breeding efforts resulting in high yields that have been achieved with this breeding material. However, oil palm ...

Quantification of rice bran oil in oil blends

Directory of Open Access Journals (Sweden)

Mishra, R.

2012-03-01

Full Text Available Blends consisting of physically refined rice bran oil (PRBO: sunflower oil (SnF and PRBO: safflower oil (SAF in different proportions were analyzed for various physicochemical parameters. The quantification of pure rice bran oil in the blended oils was carried out using different methods including gas chromatographic, HPLC, ultrasonic velocity and methods based on physico-chemical parameters. The physicochemical parameters such as ultrasonic velocity, relative association and acoustic impedance at 2 MHz, iodine value, palmitic acid content and oryzanol content reflected significant changes with increased proportions of PRBO in the blended oils. These parameters were selected as dependent parameters and % PRBO proportion was selected as independent parameters. The study revealed that regression equations based on the oryzanol content, palmitic acid composition, ultrasonic velocity, relative association, acoustic impedance, and iodine value can be used for the quantification of rice bran oil in blended oils. The rice bran oil can easily be quantified in the blended oils based on the oryzanol content by HPLC even at a 1% level. The palmitic acid content in blended oils can also be used as an indicator to quantify rice bran oil at or above the 20% level in blended oils whereas the method based on ultrasonic velocity, acoustic impedance and relative association showed initial promise in the quantification of rice bran oil.

Se analizaron diversos parámetros físico-químicos para la evaluación de mezclas de aceites en diferentes proporciones que incluyen: aceite de salvado de arroz físícamente refinado (PRBO: aceite de girasol (SNF y las mezclas PRBO: aceite de cártamo (SAF en diferentes proporciones. La cuantificación de la presencia del aceite de salvado de arroz en las mezclas se llevó a cabo por diferentes métodos, como cromatografía de gases (GC, cromatografía líquida (HPLC, ultrasonidos y métodos basados en otros parámetros f

The oil market

International Nuclear Information System (INIS)

Amic, E.; Lautard, P.

1999-01-01

This chapter examines the structure of the oil industry and the impacts of the oil markets on the hedging strategies of the energy consumers, the oil company, and the energy derivatives' provider. An introduction to market perspectives is presented, and the hedging operations in the jet fuel market in the airline sector are discussed. Trading and risk management within an oil company, the derivatives provider, trading derivatives in a multi-dimensional world, locational risks, and the modelling of term structure and the role of storage are considered. Industrial spreads and the role of refining, future market developments and market strategies for crude oil and oil products, and marketing packages and market risk are addressed

[Laser induced fluorescence spectrum characteristics of common edible oil and fried cooking oil].

Science.gov (United States)

Mu, Tao-tao; Chen, Si-ying; Zhang, Yin-chao; Chen, He; Guo, Pan; Ge, Xian-ying; Gao, Li-lei

2013-09-01

In order to detect the trench oil the authors built a trench oil rapid detection system based on laser induced fluorescence detection technology. This system used 355 nm laser as excitation light source. The authors collected the fluorescence spectrum of a variety of edible oil and fried cooking oil (a kind of trench oil) and then set up a fluorescence spectrum database by taking advantage of the trench oil detection system It was found that the fluorescence characteristics of fried cooking oil and common edible oil were obviously different. Then it could easily realize the oil recognition and trench oil rapid detection by using principal component analysis and BP neural network, and the overall recognition rate could reach as high as 97.5%. Experiments showed that laser induced fluorescence spectrum technology was fast, non-contact, and highly sensitive. Combined with BP neural network, it would become a new technique to detect the trench oil.

Co-processing of standard gas oil and biocrude oil to hydrocarbon fuels

International Nuclear Information System (INIS)

Agblevor, Foster A.; Mante, O.; McClung, R.; Oyama, S.T.

2012-01-01

The major obstacle in thermochemical biomass conversion to hydrocarbon fuels using pyrolysis has been the high oxygen content and the poor stability of the product oils, which cause them to solidify during secondary processing. We have developed a fractional catalytic pyrolysis process to convert biomass feedstocks into a product termed “biocrude oils” (stable biomass pyrolysis oils) which are distinct from unstable conventional pyrolysis oils. The biocrude oils are stable, low viscosity liquids that are storable at ambient conditions without any significant increases in viscosity; distillable at both atmospheric pressure and under vacuum without char or solid formation. About 15 wt% biocrude oils containing 20–25% oxygen were blended with 85 wt% standard gas oil and co-cracked in an Advanced Catalyst Evaluation (ACE™) unit using fluid catalytic cracking (FCC) catalysts to produce hydrocarbon fuels that contain negligible amount of oxygen. For the same conversion of 70% for both the standard gas oil and the biocrude oil/gas oil blends, the product gasoline yield was 44 wt%, light cycle oil (LCO) 17 wt%, heavy cycle oil (HCO) 13 wt%, and liquefied petroleum gas (LPG) 16 wt%. However, the coke yield for the standard gas oil was 7.06 wt% compared to 6.64–6.81 wt% for the blends. There appeared to be hydrogen transfer from the cracking of the standard gas oil to the biocrude oil which subsequently eliminated the oxygen in the fuel without external hydrogen addition. We have demonstrated for the first time that biomass pyrolysis oils can be successfully converted into hydrocarbons without hydrogenation pretreatment. -- Highlights: ► The co-processed product had less than 1% oxygen content and contained biocarbons determined by 14 C analysis. ► The co-processing did not affect the yields of gasoline, LCO, and HCO. ► First demonstration of direct conversion of pyrolysis oils into drop-in hydrocarbon fuels.

Oil pollution

International Nuclear Information System (INIS)

Mankabady, Samir.

1994-08-01

Oil enters the marine environment when it is discharged, or has escaped, during transport, drilling, shipping, accidents, dumping and offshore operations. This book serves as a reference both on the various complex international operational and legal matters of oil pollution using examples such as the Exxon Valdez, the Braer and Lord Donaldson's report. The chapters include the development of international rules on the marine environment, the prevention of marine pollution from shipping activities, liability for oil pollution damage, the conflict of the 1990 Oil Pollution Act and the 1992 protocols and finally the cooperation and response to pollution incidents. (UK)

Do oil dispersants make spilled oil more toxic to fish?

International Nuclear Information System (INIS)

Hodson, P.

2010-01-01

The Deepwater Horizon blowout in the Gulf of Mexico was the world's largest oil spill in terms of duration and volume spilled. Clean-up operations, which involved the continuous and wide-spread use of oil dispersant at the surface and at the seabed discharge point at 1500 metres depth, gave rise to public concern about dispersant toxicity. Reports from the United States Environmental Protection Agency (EPA) claimed little difference in acute toxicity to marine fish and invertebrate species among commonly available dispersants and between dispersed and non-dispersed Louisiana Sweet Crude. Technically, the toxicity of waterborne hydrocarbons does not vary with chemical dispersion. However, the EPA omitted any consideration of loading, and misled the public about the risks of dispersant use in oil clean-up. This study examined the chronic toxicity of dispersed oil to fish embryos. The study revealed that toxicity expressed as oil loading increases by a factor of 10 to 1000 times with dispersion, largely because 10 to 1000 times more oil enters the water column. Since the action of dispersant is on the exposure component of the risk equation, not on the potency of the toxic components of oil, then the risk of oil toxicity to fish increases an equivalent amount.

Influence of Oil Viscosity on Alkaline Flooding for Enhanced Heavy Oil Recovery

Directory of Open Access Journals (Sweden)

Yong Du

2013-01-01

Full Text Available Oil viscosity was studied as an important factor for alkaline flooding based on the mechanism of “water drops” flow. Alkaline flooding for two oil samples with different viscosities but similar acid numbers was compared. Besides, series flooding tests for the same oil sample were conducted at different temperatures and permeabilities. The results of flooding tests indicated that a high tertiary oil recovery could be achieved only in the low-permeability (approximately 500 mD sandpacks for the low-viscosity heavy oil (Zhuangxi, 390 mPa·s; however, the high-viscosity heavy oil (Chenzhuang, 3450 mPa·s performed well in both the low- and medium-permeability (approximately 1000 mD sandpacks. In addition, the results of flooding tests for the same oil at different temperatures also indicated that the oil viscosity put a similar effect on alkaline flooding. Therefore, oil with a high-viscosity is favorable for alkaline flooding. The microscopic flooding test indicated that the water drops produced during alkaline flooding for oils with different viscosities differed significantly in their sizes, which might influence the flow behaviors and therefore the sweep efficiencies of alkaline fluids. This study provides an evidence for the feasibility of the development of high-viscosity heavy oil using alkaline flooding.

The Russian oil

International Nuclear Information System (INIS)

Rucker, Laurent

2003-01-01

This article proposes a brief discussion of various assessments of Russian oil reserves, of the evolutions of Russian oil production (Russia is the second world producer after Saudi Arabia), of the distribution of Russian oil exports among various regions, and of the decrease of Russian oil consumption between 1992 and 2002. It describes the evolution of the actor system as the oil sector has been largely privatised since 1992, and indicates the main companies which should control the Russia market on a medium term. It also discusses the obstacles for the development of Production Sharing Agreements (PSA) between these companies. It addresses the issue of modernisation of the oil transport system as its status and its condition are often an obstacle to oil export for Russian companies. The article finally discusses the price issue, the relationship between Russia and other OPEC countries, and the need for huge investments

A Study on the efficient alleviation of domestic oil price at international oil crisis

Energy Technology Data Exchange (ETDEWEB)

Lee, Young Ku [Korea Energy Economics Institute, Euiwang (Korea)

1999-01-01

For alleviating domestic oil price when the international oil crisis happens, the government has been reacted directly such as using stored oil or alleviation fund. Although the release of stored oil works for short-term depending on the type of crisis, concerning that most of oil crisis had been resulted in temporary supply reduction rather than long-term supply suspension, utilizing the domestic alleviation fund is regarded more economical than storing oil. However, it has been suggested to compare efficiencies of alleviation fund and a futures market regarding the perspectives that using alleviation fund is more inefficient than utilizing a futures market. Moreover, the direct management by government is less efficient than indirect management. As an efficient way to alleviate domestic oil price at international oil crisis, this study presents an effective utilization of trading in futures of crude oil. There is a high probability of occurrence of this kind of oil crisis by judging from the world political situation and the trend of oil market. In such a case, the government as a crude oil importer should minimize the stored oil and utilize a futures market effectively. The subject of alleviating oil price by trading in futures is an oil supplier, such as oil refining companies or oil importers not the government as a prerequisite. Furthermore, the government should approve to include appropriate cost for preparing oil price alleviation in the oil price and it is required that such a government policy should be consistent. (author). 41 refs., 3 figs., 15 Tabs.

Process for separating and recovering oil from oil-sands, etc

Energy Technology Data Exchange (ETDEWEB)

Preller, H

1921-02-24

A process for separating and recovering oil from oil-sands, bitumen from oil-chalk, oil-shale, and coal, according to Patent 400,122, is described. It is characterized in that the mined material falling on account of its weight is exposed to the running hot water in circulation through the wash-chamber and the clarifying chamber arranged separate or built on (circulation) being obtained by pumps or injectors in a regulatable motion.

Nylon 6,6 Nonwoven Fabric Separates Oil Contaminates from Oil-in-Water Emulsions.

Directory of Open Access Journals (Sweden)

Ryan A Ortega

Full Text Available Industrial oil spills into aquatic environments can have catastrophic environmental effects. First responders to oil spills along the coast of the Gulf of Mexico in the southern United States have used spunbond nylon fabric bags and fences to separate spilled oil and oil waste from contaminated water. Low area mass density spunbond nylon is capable of sorbing more than 16 times its mass in low viscosity crude oil and more than 26 times its mass in higher viscosity gear lube oil. Nylon bags separated more than 95% of gear lube oil contaminate from a 4.5% oil-in-water emulsion. Field testing of spunbond nylon fences by oil spill first responders has demonstrated the ability of this material to contain the oily contaminate while allowing water to flow through. We hypothesize that the effectiveness of nylon as an oil filter is due to the fact that it is both more oleophilic and more hydrophilic than other commonly used oil separation materials. The nylon traps oil droplets within the fabric or on the surface, while water droplets are free to flow through the fabric to the water on the opposite side of the fabric.

Spilled oil and infaunal activity - Modification of burrowing behavior and redistribution of oil

Science.gov (United States)

Clifton, H.E.; Kvenvolden, K.A.; Rapp, J.B.

1984-01-01

A series of experiments in Willapa Bay, Washington, indicates the degree to which the presence of spilled oil modifies the burrowing behavior of infauna and the extent to which the animals redistribute oil into intertidal sediment. Small amounts of North Slope crude oil introduced at low tide directly into burrow openings (mostly made by the crustacean Callianassa) resulted in a limited and temporary reduction in the number of burrow openings. In contrast, a layer of oil-saturated sand 1 cm thick buried about 5 cm below the sediment surface sharply reduced the number of burrow openings. After a year, the few new burrows penetrated only the margins of the experimental plot, and bioturbation below the buried oil-saturated sand layer declined dramatically. The experiments suggest that small amounts of oil temporarily stranded by tides in themselves have no long-range effect on burrowing behavior. The fauna, however, are capable of introducing measurable amounts of oil into the subsurface, where it is retained long after the rest of the stranded oil had washed away. A buried layer of oil-saturated sand greatly reduces infaunal activity; the oil presents an effective barrier that can persist for years. The oil incorporated into the sediment from burrow openings showed evidence of degradation after 7 months. In contrast the layer of buried oil remained essentially undergraded after a period of two years, even though oil in lower concentrations above the layer was degraded after a period of one year. This variation in degree of degradation of the buried oil, as well as the heterogeneity of oil distribution wherever the oil has been incorporated from the surface, emphasises the importance of careful sampling in any attempt to locate or monitor the presence of spilled oil in the substrate.In a series of experiments in Willapa Bay, Washington, small amounts of North Slope crude oil introduced at low tide directly into burrow openings resulted in a limited and temporary

Clean and Secure Energy from Domestic Oil Shale and Oil Sands Resources

Energy Technology Data Exchange (ETDEWEB)

Spinti, Jennifer [Inst. for Clean and Secure Energy, Salt Lake City, UT (United States); Birgenheier, Lauren [Inst. for Clean and Secure Energy, Salt Lake City, UT (United States); Deo, Milind [Inst. for Clean and Secure Energy, Salt Lake City, UT (United States); Facelli, Julio [Inst. for Clean and Secure Energy, Salt Lake City, UT (United States); Hradisky, Michal [Inst. for Clean and Secure Energy, Salt Lake City, UT (United States); Kelly, Kerry [Inst. for Clean and Secure Energy, Salt Lake City, UT (United States); Miller, Jan [Inst. for Clean and Secure Energy, Salt Lake City, UT (United States); McLennan, John [Inst. for Clean and Secure Energy, Salt Lake City, UT (United States); Ring, Terry [Inst. for Clean and Secure Energy, Salt Lake City, UT (United States); Ruple, John [Inst. for Clean and Secure Energy, Salt Lake City, UT (United States); Uchitel, Kirsten [Inst. for Clean and Secure Energy, Salt Lake City, UT (United States)

2015-09-30

This report summarizes the significant findings from the Clean and Secure Energy from Domestic Oil Shale and Oil Sands Resources program sponsored by the Department of Energy through the National Energy Technology Laboratory. There were four principle areas of research; Environmental, legal, and policy issues related to development of oil shale and oil sands resources; Economic and environmental assessment of domestic unconventional fuels industry; Basin-scale assessment of conventional and unconventional fuel development impacts; and Liquid fuel production by in situ thermal processing of oil shale Multiple research projects were conducted in each area and the results have been communicated via sponsored conferences, conference presentations, invited talks, interviews with the media, numerous topical reports, journal publications, and a book that summarizes much of the oil shale research relating to Utah’s Uinta Basin. In addition, a repository of materials related to oil shale and oil sands has been created within the University of Utah’s Institutional Repository, including the materials generated during this research program. Below is a listing of all topical and progress reports generated by this project and submitted to the Office of Science and Technical Information (OSTI). A listing of all peer-reviewed publications generated as a result of this project is included at the end of this report; Geomechanical and Fluid Transport Properties 1 (December, 2015); Validation Results for Core-Scale Oil Shale Pyrolysis (February, 2015); and Rates and Mechanisms of Oil Shale Pyrolysis: A Chemical Structure Approach (November, 2014); Policy Issues Associated With Using Simulation to Assess Environmental Impacts (November, 2014); Policy Analysis of the Canadian Oil Sands Experience (September, 2013); V-UQ of Generation 1 Simulator with AMSO Experimental Data (August, 2013); Lands with Wilderness Characteristics, Resource Management Plan Constraints, and Land Exchanges

Quality control of mixtures consisting of engine oil and rapeseed oil by means of online oil sensors; Qualitaetsueberwachung von Motoroel-Rapsoelmischungen mit Online-Oelsensoren. Labortests

Energy Technology Data Exchange (ETDEWEB)

Thuneke, Klaus; Schreiber, Katja [Technologie- und Foerderzentrum, Straubing (Germany)

2013-10-01

It was the goal of the work to investigate interactions between motor oils and rapeseed oil fuel and to test oil sensors for monitoring the quality of aged mixtures of motor oil and rapeseed oil. At first oil samples were aged in the laboratory, whereby motor oil type, share of rapeseed oil and aeration was varied. Depending on type of engine oil different ageing effects were noticed. Higher shares of rapeseed and aeration stimulate increase of viscosity and acid value. In a further step online oil sensors were tested in both, a model of a lubrication system and a test engine. The signals of the sensors plausibly described the oil ageing process by the indicators dynamic or acoustic viscosity, permittivity number, specific electric conductivity. In particular viscosity and permittivity are suitable for showing changes in different motor oil rapeseed oil mixtures during oil ageing. However, for a reliable control system detecting critical rapeseed oil enrichment in the motor oil onboard, further work has to be done. (orig.)

Electricity/oil substitution

International Nuclear Information System (INIS)

Melvin, J.G.

1980-09-01

The extent to which electricity could substitute for imported oil in Canada is assessed and it is concluded that the bulk of projected oil imports could be displaced. This substitution of electricity for oil could be largely completed within two decades, with existing technology, using Canadian resources. The substitution of electricity for imported oil would result in relatively low energy costs and would stimulate economic growth. Energy self-sufficiency through the substitution of electricity for oil is uniquely a Canadian option; it is not open to other industrial countries. The option exists because of Canada's resources of oil sands for essential liquid fuels, hydraulic and nuclear electrical potential, and natural gas as an interim source of energy. While other countries face an energy crisis due to declining supplies of oil, Canada faces opportunities. The policies of Federal and Provincial governments, as perceived by individual decision makers, will have a major influence on Canada's ability to realize opportunities. (auth)

An Estimate of Recoverable Heavy Oil Resources of the Orinoco Oil Belt, Venezuela

Science.gov (United States)

Schenk, Christopher J.; Cook, Troy A.; Charpentier, Ronald R.; Pollastro, Richard M.; Klett, Timothy R.; Tennyson, Marilyn E.; Kirschbaum, Mark A.; Brownfield, Michael E.; Pitman, Janet K.

2009-01-01

The Orinoco Oil Belt Assessment Unit of the La Luna-Quercual Total Petroleum System encompasses approximately 50,000 km2 of the East Venezuela Basin Province that is underlain by more than 1 trillion barrels of heavy oil-in-place. As part of a program directed at estimating the technically recoverable oil and gas resources of priority petroleum basins worldwide, the U.S. Geological Survey estimated the recoverable oil resources of the Orinoco Oil Belt Assessment Unit. This estimate relied mainly on published geologic and engineering data for reservoirs (net oil-saturated sandstone thickness and extent), petrophysical properties (porosity, water saturation, and formation volume factors), recovery factors determined by pilot projects, and estimates of volumes of oil-in-place. The U.S. Geological Survey estimated a mean volume of 513 billion barrels of technically recoverable heavy oil in the Orinoco Oil Belt Assessment Unit of the East Venezuela Basin Province; the range is 380 to 652 billion barrels. The Orinoco Oil Belt Assessment Unit thus contains one of the largest recoverable oil accumulations in the world.

A photometric method for the estimation of the oil yield of oil shale

Science.gov (United States)

Cuttitta, Frank

1951-01-01

A method is presented for the distillation and photometric estimation of the oil yield of oil-bearing shales. The oil shale is distilled in a closed test tube and the oil extracted with toluene. The optical density of the toluene extract is used in the estimation of oil content and is converted to percentage of oil by reference to a standard curve. This curve is obtained by relating the oil yields determined by the Fischer assay method to the optical density of the toluene extract of the oil evolved by the new procedure. The new method gives results similar to those obtained by the Fischer assay method in a much shorter time. The applicability of the new method to oil-bearing shale and phosphatic shale has been tested.

Effects of oil and oil burn residues on seabird feathers

DEFF Research Database (Denmark)

Fritt-Rasmussen, Janne; Linnebjerg, Jannie Fries; Sørensen, Martin X.

2016-01-01

It is well known, that in case of oil spill, seabirds are among the groups of animals most vulnerable. Even small amounts of oil can have lethal effects by destroying the waterproofing of their plumage, leading to loss of insulation and buoyancy. In the Arctic these impacts are intensified....... To protect seabirds, a rapid removal of oil is crucial and in situ burning could be an efficient method. In the present work exposure effects of oil and burn residue in different doses was studied on seabird feathers from legally hunted Common eider (Somateria mollissima) by examining changes in total weight...... of the feather and damages on the microstructure (Amalgamation Index) of the feathers before and after exposure. The results of the experiments indicate that burn residues from in situ burning of an oil spill have similar or larger fouling and damaging effects on seabird feathers, as compared to fresh oil....

Effects on bread and oil quality after functionalization with microencapsulated chia oil.

Science.gov (United States)

González, Agustín; Martínez, Marcela L; León, Alberto E; Ribotta, Pablo D

2018-03-23

Omega-3 and omega-6 fatty acids-rich oils suffer oxidation reactions that alter their chemical and organoleptic quality. Microencapsulation can be a powerful tool for protection against ambient conditions. In the present study, the addition of microencapsulated chia oil as an ingredient in bread preparations and its effect on the technological and chemical quality of breads was investigated. Microencapsulation of chia oil was carried out by freeze-drying with soy proteins as wall material and oil release was determined under in vitro gastric and intestinal conditions. Encapsulated oil-containing bread showed no differences in specific volume, average cell area, firmness and chewiness with respect to control bread. Unencapsulated oil-containing bread showed a marked increase in hydroperoxide values respect to control, whereas encapsulated oil-containing bread values were not affected by baking and bread storage. The fatty acid profiles showed a decrease of 13% and 16%, respectively, in α-linolenic acid in the encapsulated and unencapsulated oils with respect to bulk chia oil. Sensory analysis showed no significant differences between bread samples. The addition of encapsulated chia oil did not alter the technological quality of breads and prevented the formation of hydroperoxide radicals. A ration of encapsulated oil-containing bread contributes 60% of the recommended dietary intake of omega-3 fatty acids. © 2018 Society of Chemical Industry. © 2018 Society of Chemical Industry.

Oil sands and heavy oil development issues and prospects under a Liberal government

International Nuclear Information System (INIS)

Shiry, J.

1993-01-01

A short review is presented of some of the factors affecting development of the western Canadian oil sands and heavy oil deposits to the year 2000. The Alberta oil sands resource has at least 1 trillion bbl of recoverable oil. At current prices, technology is the key to reducing costs to a more economic level. Cash operating costs have halved to $15/bbl over the past decade and the oil sands companies have programs to halve that figure again. A problem is the rising cost of natural gas as a fuel, which could jeopardize further development of both oil sand and heavy oil resources. In Saskatchewan, over 25 billion bbl of heavy oil are estimated to be in place. The biggest question is what percentage can be recovered; again, technology such as horizontal wells, 3-dimensional seismic, and steam assisted recovery is playing an important role. Concerns are expressed about the intentions of the new Liberal government concerning oil sand/heavy oil development, especially on the issues of foreign investment, exports, and environmental policy. A Liberal energy policy is not likely to allow U.S. direct investment in an oil sands plant to be tied to export of production, and the energy- and emissions-intensive nature of the oil sand/heavy oil industry will tend to make environmental approvals difficult

Oil shale technology

International Nuclear Information System (INIS)

Lee, S.

1991-01-01

Oil shale is undoubtedly an excellent energy source that has great abundance and world-wide distribution. Oil shale industries have seen ups and downs over more than 100 years, depending on the availability and price of conventional petroleum crudes. Market forces as well as environmental factors will greatly affect the interest in development of oil shale. Besides competing with conventional crude oil and natural gas, shale oil will have to compete favorably with coal-derived fuels for similar markets. Crude shale oil is obtained from oil shale by a relatively simple process called retorting. However, the process economics are greatly affected by the thermal efficiencies, the richness of shale, the mass transfer effectiveness, the conversion efficiency, the design of retort, the environmental post-treatment, etc. A great many process ideas and patents related to the oil shale pyrolysis have been developed; however, relatively few field and engineering data have been published. Due to the vast heterogeneity of oil shale and to the complexities of physicochemical process mechanisms, scientific or technological generalization of oil shale retorting is difficult to achieve. Dwindling supplied of worldwide petroleum reserves, as well as the unprecedented appetite of mankind for clean liquid fuel, has made the public concern for future energy market grow rapidly. the clean coal technology and the alternate fuel technology are currently of great significance not only to policy makers, but also to process and chemical researchers. In this book, efforts have been made to make a comprehensive text for the science and technology of oil shale utilization. Therefore, subjects dealing with the terminological definitions, geology and petrology, chemistry, characterization, process engineering, mathematical modeling, chemical reaction engineering, experimental methods, and statistical experimental design, etc. are covered in detail

Environmental program with operational cases to reduce risk to the marine environment significantly

International Nuclear Information System (INIS)

Cline, J.T.; Forde, R.

1991-01-01

In this paper Amoco Norway Oil Company's environmental program is detailed, followed by example operational programs and achievements aimed to minimize environmental risks to the marine environment at Valhall platform. With a corporate goal to be a leader in protecting the environment, the appropriate strategies and policies that form the basis of the environmental management system are incorporated in the quality assurance programs. Also, included in the program are necessary organizational structures, responsibilities of environmental affairs and line organization personnel, compliance procedures and a waste task force obliged to implement operations improvements. An internal environmental audit system has been initiated, in addition to corporate level audits, which, when communicated to the line organization closes the environmental management loop through experience feed back. Environmental projects underway are significantly decreasing the extent and/or risk of pollution from offshore activities. The cradle to grave responsibility is assumed with waste separated offshore and onshore followed by disposal in audited sites. A $5 MM program is underway to control produced oily solids and reduce oil in produced water aiming to less than 20 ppm. When oil-based mud is used in deeper hole sections, drill solids disposed at sea average less than 60 g oil/kg dry cuttings using appropriate shaker screens, and a washing/centrifuge system to remove fines. Certain oily liquid wastes are being injected down hole whereas previously they were burned using a mud burner. Finally, a program is underway with a goal to eliminate sea discharge of oil on cuttings through injection disposal of oily wastes, drilling with alternative muds such as a cationic water base mud, and/or proper onshore disposal of oily wastes

Utah Heavy Oil Program

Energy Technology Data Exchange (ETDEWEB)

J. Bauman; S. Burian; M. Deo; E. Eddings; R. Gani; R. Goel; C.K. Huang; M. Hogue; R. Keiter; L. Li; J. Ruple; T. Ring; P. Rose; M. Skliar; P.J. Smith; J.P. Spinti; P. Tiwari; J. Wilkey; K. Uchitel

2009-10-20

The Utah Heavy Oil Program (UHOP) was established in June 2006 to provide multidisciplinary research support to federal and state constituents for addressing the wide-ranging issues surrounding the creation of an industry for unconventional oil production in the United States. Additionally, UHOP was to serve as an on-going source of unbiased information to the nation surrounding technical, economic, legal and environmental aspects of developing heavy oil, oil sands, and oil shale resources. UHOP fulGilled its role by completing three tasks. First, in response to the Energy Policy Act of 2005 Section 369(p), UHOP published an update report to the 1987 technical and economic assessment of domestic heavy oil resources that was prepared by the Interstate Oil and Gas Compact Commission. The UHOP report, entitled 'A Technical, Economic, and Legal Assessment of North American Heavy Oil, Oil Sands, and Oil Shale Resources' was published in electronic and hard copy form in October 2007. Second, UHOP developed of a comprehensive, publicly accessible online repository of unconventional oil resources in North America based on the DSpace software platform. An interactive map was also developed as a source of geospatial information and as a means to interact with the repository from a geospatial setting. All documents uploaded to the repository are fully searchable by author, title, and keywords. Third, UHOP sponsored Give research projects related to unconventional fuels development. Two projects looked at issues associated with oil shale production, including oil shale pyrolysis kinetics, resource heterogeneity, and reservoir simulation. One project evaluated in situ production from Utah oil sands. Another project focused on water availability and produced water treatments. The last project considered commercial oil shale leasing from a policy, environmental, and economic perspective.

Financial oil derivatives: from options to oil warrants and synthetic oilfields

International Nuclear Information System (INIS)

Trabia, Xavier

1992-01-01

This study aims to shed light on some of the most interesting financial oil derivatives issued so far in order to assess the potential of this new wave of innovative funding instruments. In Part I some theoretical background is provided and applied to the problem of the American futures option. The ''binomial'' model for valuing future option contracts is presented and the most accurate alternatives for pricing American futures options are reviewed. The role of these numerical procedures in valuing more complex options involved in oil warrants is examined. Comments are made on the behaviour of volatility, which stands as a key interface between theory and practice in oil trading on the oil futures market. Part II of the study describes in detail some of the most famous new financial oil derivatives. Some final conclusions are drawn on the potential of oil trusts and synthetic oilfields to be involved in project and general funding in the oil industry. (44 figures, 11 tables, 53 references) (UK)

Effects of Crude Oil and Oil Products on Growth of Some Edible ...

African Journals Online (AJOL)

The vegetative growth response of three local edible mushrooms: Pleurotus pulmonarius (Pp), Pleurotus tuber-regium (Pt) and Lentinus squarrosulus (Ls) on different concentrations of Crude oil (COIL), Automotive Gasoline Oil (AGO), Fresh Engine Oil (ENGOIL) and Spent Engine Oil (SENGOIL) was investigated. The result ...

Oils; gas

Energy Technology Data Exchange (ETDEWEB)

Day, D T

1922-09-18

Oils and gas are obtained from shale or oil-bearing sand by immersing the shale in and passing it through a bath of liquid oil, cracking the oil-soaked shale, and condensing the vapor and using the condensate to replenish the bath, preferably by passing the gases and vapors direct into the oil-bath container. Shale is fed continuously from a hopper to a bath of oil in an inclined chamber, is carried to the outlet by a conveyer, and through cracking tubes to an outlet pipe by conveyers. The gases and vapors escape by the pipe, a part condensing in the chamber and a run-back pipe and replenishing the bath, and the remainder passing through a condensing tower and condenser connected to reservoirs; the gas is further passed through a scrubber and a pipe to the burner of the retort. The oil condensed in the chamber overflows to the reservoir through a pipe provided with an open pipe to prevent siphoning. The conveyers and a valve on the pipe are operated by gearing. The operation may be conducted at reduced, normal, or increased pressure, e.g., 70 lbs. The temperature of the retort should be about 900 to 1400/sup 0/F, that of the inside of the tubes about 550 to 700/sup 0/F, and that of the chamber about 300/sup 0/F. The chamber and pipe may be insulated or artificially cooled.

Seed oil content and selected qualitative parameters of oils from grape seeds

Directory of Open Access Journals (Sweden)

Vladimír Mašán

2017-01-01

Full Text Available Grape seed oil (Oleum vitis viniferae represents promising plant oil, which is used mainly in gastronomy and for pharmaceutical purposes as well as for various technical applications. In this paper, there were examined oil contents and oil quality properties of seeds taken from 8 grape cultivars. Oil contents were found to be different for each cultivar, which ranged from 11.5% (Dornfelder to 17.5% (Riesling. The results showed a dependence between the length of the growing season for individual varie-ties and the total content of oil in seeds. Fatty acid concentrations in the evaluated oil samples were in various ranges, while the highest values were determined in linoleic acid 70.10 to 71.55%, oleic acid 15.61 to 17.14%, palmitic acid 6.87 to 8.18% and stearic acid 3.16 to 3.90%. Saturated fatty acid values were lower than the values of monounsaturated fatty acids and polyunsaturated fatty acids in all oil samples. The degree of unsaturation in the grape seed oil ranged between 88.6 - 89.21%. Thanks to its content, grape seed oil can be considered as a food supplement improving the nutri-tional value of the human diet.

Olive oil adulterated with hazelnut oils: simulation to identify possible risks to allergic consumers

NARCIS (Netherlands)

Arlorio, M.; Coisson, J. D.; Bordiga, M.; Travaglia, F.; Garino, C.; Zuidmeer, L.; van Ree, R.; Giuffrida, M. G.; Conti, A.; Martelli, A.

2010-01-01

According to European Union Regulation EC 1531/2001, olive oil labelled as oextra-virgino should be cold-pressed and contain no refined oil or oil from other oleaginous seeds or nuts. Adulteration of extra virgin olive oil (EVOO) with hazelnut oil (HAO) is a serious concern both for oil suppliers

Contact Allergy to Neem Oil.

NARCIS (Netherlands)

de Groot, Anton; Jagtman, Berend A; Woutersen, Marjolijn

2018-01-01

A case of allergic contact dermatitis from neem oil is presented. Neem oil (synonyms: Melia azadirachta seed oil [INCI name], nim oil, margosa oil) is a vegetable (fixed) oil obtained from the seed of the neem tree Azadirachta indica by cold pressing. Contact allergy to neem oil has been described

Oil supply and oil politics: Deja Vu all over again

International Nuclear Information System (INIS)

Cleveland, Cutler J.; Kaufmann, Robert K.

2003-01-01

President Bush has identified US dependence on imported oil as an urgent energy, economic, and national security concern. The President's energy plan promotes the development of domestic resources, based on the assumption that economic incentives and the opening of frontier areas for exploration will increase domestic production. If realized, this will reduce dependence on imported oil and reduce OPEC's ability to affect aggregate oil supply and price. The evidence suggests, however, that this policy will not increase significantly US production of crude oil, will not reduce significantly OPEC's influence, and it will distort the US macroeconomy. Even if allowed, production from the Arctic National Wildlife Refuge will have a negligible impact on the world oil markets. Further subsidies to the oil industry will divert resources from other more productive investments. Conservation and energy efficiency merit greater emphasis in US energy policy given their ability to reduce the use of cost-effective and environmentally beneficial ways

Oil supply and oil politics: Deja Vu all over again

International Nuclear Information System (INIS)

Cleveland, C.J.; Kaufmann, R.K.

2003-01-01

President Bush has identified US dependence on imported oil as an urgent energy, economic, and national security concern. The President's energy plan promotes the development of domestic resources, based on the assumption that economic incentives and the opening of frontier areas for exploration will increase domestic production. If realized, this will reduce dependence on imported oil and reduce OPEC's ability to affect aggregate oil supply and price. The evidence suggests, however, that this policy will not increase significantly US production of crude oil, will not reduce significantly OPEC's influence, and it will distort the US macroeconomy. Even if allowed, production from the Arctic National Wildlife Refuge will have a negligible impact on the world oil markets. Further subsidies to the oil industry will divert resources from other more productive investments. Conservation and energy efficiency merit greater emphasis in US energy policy given their ability to reduce the use of cost-effective and environmentally beneficial ways. (author)

Effects of fish oil type, lipid antioxidants and presence of rapeseed oil on oxidative flavour stability of fish oil enriched milk

DEFF Research Database (Denmark)

Bruni Let, Mette; Jacobsen, Charlotte; Meyer, Anne S.

2004-01-01

As a part of our ongoing experiments on optimization of the oxidative stability of fish oils in genuine food systems, this study investigated the oxidative deterioration of fish oil enriched milk emulsions during cold storage. The experimental data showed that addition of rapeseed oil to fish oil...... (1:1) prior to emulsification into milk significantly protected the emulsions against oxidative deterioration. Addition of propyl gallate and a citric acid ester to the fish oil prior to emulsification also protected the fish oil enriched milk during storage. Emulsions containing a rapeseed:fish oil...... mixture were oxidatively stable during 11 d at 2 øC. Thus, no additional inhibitory effect of the added antioxidants was observed. The peroxide value and concentrations of five selected volatiles derived from n- 3 PUFA degradation in rapeseed:fish oil mixture emulsions were not significantly different...

Oil market outlook

International Nuclear Information System (INIS)

Starling, Philip

1997-01-01

The role of the International Energy Agency's (IEA) ''OiMarket Report'' is described in terms of its response to and support for oil companies seeking to monitor short-term global oil market developments. The document is increasingly used for reference both by industry and governments. Data is compiled from oil companies, consultants, and government, and OECD countries provide supply/demand oil balance data by product grade on a monthly basic. (UK)

Biotransformation of natural gas and oil compounds associated with marine oil discharges.

Science.gov (United States)

Brakstad, Odd Gunnar; Almås, Inger K; Krause, Daniel Franklin

2017-09-01

Field data from the Deepwater Horizon (DWH) oil spill in the Gulf of Mexico (GoM) suggested that oxidation of gas compounds stimulated biodegradation of oil compounds in the deep sea plume. We performed experiments with local seawater from a Norwegian fjord to examine if the presence of dissolved gas compounds (methane, ethane and propane) affected biodegradation of volatile oil compounds, and if oil compounds likewise affected gas compound oxidation. The results from the experiment showed comparable oil compound biotransformation rates in seawater at 5 °C between seawater with and without soluble gases. Gas oxidation was not affected by the presence of volatile oil compounds. Contrary to DWH deep sea plume data, propane oxidation was not faster than methane oxidation. These data may reflect variations between biodegradation of oil and gas in seawater environments with different history of oil and gas exposure. Copyright © 2017 Elsevier Ltd. All rights reserved.

Recycling of used oil

International Nuclear Information System (INIS)

Vipulanandan, C.; Ghurye, G.

1992-01-01

This paper reports on used oil which is a valuable resource that should be recycled. Recycling used oil saves energy and natural resources. Used oil can be reprocessed and used as fuel in industrial burners and boilers. Unfortunately, more than 400 million gallons/year of used oil is lost through widespread dumping, partly due to lack of effective recycling procedures. Although used oil is not currently a federally listed hazardous waste, the U.S. EPA has proposed to list it as a hazardous waste, which will make recycling of used oil even more attractive. Laboratory samples, representing used oil, were used for detailed parametric studies and to determine the limitation of extending some of the current physical separation techniques such as sedimentation and centrifuging developed for oil-water and solid-liquid separation

Research on a dispersing solution for burnt crude oils: Aegean Sea oil spill

International Nuclear Information System (INIS)

Bergueiro, J.R.; Morales, N.; Dominguez, F.

1993-01-01

The oil tanker Aegean Sea spilled oil when it grounded during severe storm conditions near La Coruna, Spain. Much of the oil burned after an explosion was caused by the hull breaking apart. Oil which contaminated several beaches was affected by both combustion and weathering. Experiments were conducted on oil sampled from the beaches to investigate dispersion of the oil using Beep Enersperse 1990 at different shaking speeds. Biodegradation experiments were also conducted in the presence of Beep Enersperse 1990 but with seawater absent. Although emulsification of the burnt and weathered oil was very difficult, good dispersion and biodegradation were obtained. After 42 d in a stirred reactor, biodegradation of the oil reached at least 80%. 3 refs., 3 figs., 4 tabs

Assessment of the relationship between oil prices and US oil stocks

International Nuclear Information System (INIS)

Saif Ghouri, Salman

2006-01-01

This paper qualitatively and quantitatively analyzes the relationship between US monthly ending oil stocks position with that of West Texas Intermediate (WTI) oil prices from February 1995 to July 2004. The paper concludes if other things are held constant, WTI is inversely related to the petroleum products (PPP), combined petroleum products and crude oil (CPPP), crude oil alone (Crude), total oil stocks including petroleum products, crude oil and strategic petroleum reserves SPR (Total), total gasoline (TGO), total distillate (TDO). It could not establish a statistically significant and negative relationship with SPR when run alone. One percent increase (decrease) in CPPP, PPP, Crude, Total, TGO and TDO leads to decrease (increase) in WTI, respectively, by 0.70, 0.43, 0.37, 0.97, 0.26 and 0.21 percent. Oil prices are largely influenced by total crude and Crude and PPP inventories levels while modestly with variations in gasoline and distillate stocks levels. Despite a healthy increase of over 22 percent in SPR from January 2001 to April 2004, it did not result in easing of oil prices. Primarily because SPR are meant for security of supply concern and are only released under extreme conditions by the President of United States, they are neither meant for the purposes of balancing supply-demand gap nor for the stability of oil prices. The aggressive SPR buildup in recent years is related to international terrorism, geopolitical situation in the Middle East, particularly in Iraq, that encourages US government to enhance its SPR to meet any short-term eventuality. The analyst must keep a close eye on CPPP and the total oil stocks variation to forecast WTI in the short run whilst gasoline and distillate influence oil prices modestly in the short run. SPR, on the other hand, are expected to play a pivotal role in balancing oil prices and in providing a critical resource for the economy in case of any major shortfall in the long run

Assessment of the relationship between oil prices and US oil stocks

Energy Technology Data Exchange (ETDEWEB)

Saif Ghouri, Salman [Business Environment Section, Corporate Planning Department, Qatar Petroleum, Doha (Qatar)]. E-mail: ghouri@qp.com.qa

2006-11-15

This paper qualitatively and quantitatively analyzes the relationship between US monthly ending oil stocks position with that of West Texas Intermediate (WTI) oil prices from February 1995 to July 2004. The paper concludes if other things are held constant, WTI is inversely related to the petroleum products (PPP), combined petroleum products and crude oil (CPPP), crude oil alone (Crude), total oil stocks including petroleum products, crude oil and strategic petroleum reserves SPR (Total), total gasoline (TGO), total distillate (TDO). It could not establish a statistically significant and negative relationship with SPR when run alone. One percent increase (decrease) in CPPP, PPP, Crude, Total, TGO and TDO leads to decrease (increase) in WTI, respectively, by 0.70, 0.43, 0.37, 0.97, 0.26 and 0.21 percent. Oil prices are largely influenced by total crude and Crude and PPP inventories levels while modestly with variations in gasoline and distillate stocks levels. Despite a healthy increase of over 22 percent in SPR from January 2001 to April 2004, it did not result in easing of oil prices. Primarily because SPR are meant for security of supply concern and are only released under extreme conditions by the President of United States, they are neither meant for the purposes of balancing supply-demand gap nor for the stability of oil prices. The aggressive SPR buildup in recent years is related to international terrorism, geopolitical situation in the Middle East, particularly in Iraq, that encourages US government to enhance its SPR to meet any short-term eventuality. The analyst must keep a close eye on CPPP and the total oil stocks variation to forecast WTI in the short run whilst gasoline and distillate influence oil prices modestly in the short run. SPR, on the other hand, are expected to play a pivotal role in balancing oil prices and in providing a critical resource for the economy in case of any major shortfall in the long run.

The effect of coconut oil and palm oil as substituted oils to cocoa butter on chocolate bar texture and melting point

Science.gov (United States)

Limbardo, Rebecca Putri; Santoso, Herry; Witono, Judy Retti

2017-05-01

Cocoa butter has responsibility for dispersion medium to create a stable chocolate bar. Due to the economic reason, cocoa butter is partially or wholly substituted by edible oils e.g palm oil and coconut oil. The objective of the research was to observe the effect of oil substitution in the chocolate bar towards its melting point and texture. The research were divided in three steps which were preliminary research started with fat content analysis in cocoa powder, melting point analysis of substituted oils anc cocoa butter, and iodine number analysis in vegetable fats (cocoa butter, coconut oil, and palm oil), chocolate bar production with substitution 0%, 20%, 40%, 60%, 80%, and 100%wt of cocoa butter with each of substituted oils, and analysis process to determine the chocolate bar melting point with DSC and chocolate bar hardness with texture analyser. The increasement of substituted oils during substitution in chocolate bar would reduce the melting point of chocolate bar from 33.5°C to 31.6°C in palm oil substitution with cocoa butter and 33.5°C to 30.75°C in coconut oil substitution. The hardness of chocolate with palm oil were around 88.5 to 139 g on the 1st cycle and 22.75 to 132 g on the 2nd cycle. The hardness of chocolate with coconut oil were around 74.75 to 152.5 g on the 1st cycle and 53.25 to 132 g on the 2nd cycle. Maximum amount of fats substitution to produce a stable texture chocolate bar is 60% wt.

Foam-oil interaction in porous media: implications for foam assisted enhanced oil recovery.

Science.gov (United States)

Farajzadeh, R; Andrianov, A; Krastev, R; Hirasaki, G J; Rossen, W R

2012-11-15

The efficiency of a foam displacement process in enhanced oil recovery (EOR) depends largely on the stability of foam films in the presence of oil. Experimental studies have demonstrated the detrimental impact of oil on foam stability. This paper reviews the mechanisms and theories (disjoining pressure, coalescence and drainage, entering and spreading of oil, oil emulsification, pinch-off, etc.) suggested in the literature to explain the impact of oil on foam stability in the bulk and porous media. Moreover, we describe the existing approaches to foam modeling in porous media and the ways these models describe the oil effect on foam propagation in porous media. Further, we present various ideas on an improvement of foam stability and longevity in the presence of oil. The outstanding questions regarding foam-oil interactions and modeling of these interactions are pointed out. Copyright © 2012 Elsevier B.V. All rights reserved.

Effect of lithological composition of oil reservoirs on oil production by a hot agent

Energy Technology Data Exchange (ETDEWEB)

Abbasov, A A; Kasimov, Sh A

1965-01-01

Several small-scale experiments were performed to determine the effect of steam on oil recovery and on permeability of water-sensitive clay-containing cores. Steam has 2 contradictory actions on oil recovery - (1) steam increases temperature and decreases viscosity of the oil, which aids oil recovery; and (2) steam hydrates and swells clays, which reduces permeability and hinders oil recovery. The oil-recovery experiments were carried out with consolidated cores containing 0, 10, and 22% clay, saturated with water and 28 cp crude oil; superheated steam at 125-300$C was used. The following conclusions were made from the experimental results: (1) oil recovery decreased as clay content of cores increased; however, at all temperatures steam recovered more oil than cold water did. (2) As steam temperature increases, oil recovery reaches a maximum, then decreases. The temperature at which oil recovery begins to decrease depends on core clay content; the higher the clay content, the lower this temperature. (3) Irrespective of whether a reservoir contains clay or not, oil recovery is considerably greater with steam than with water.

Rapeseed oil, olive oil, plant sterols, and cholesterol metabolism: an ileostomy study.

Science.gov (United States)

Ellegård, L; Andersson, H; Bosaeus, I

2005-12-01

To study whether olive oil and rapeseed oil have different effects on cholesterol metabolism. Short-term experimental study, with controlled diets. Outpatients at a metabolic-ward kitchen. A total of nine volunteers with conventional ileostomies. Two 3-day diet periods; controlled diet including 75 g of rapeseed oil or olive oil. Cholesterol absorption, ileal excretion of cholesterol, and bile acids. Serum levels of cholesterol and bile acid metabolites. Differences between diets evaluated with Wilcoxon's signed rank sum test. Rapeseed oil diet contained 326 mg more plant sterols than the olive oil diet. Rapeseed oil tended to decrease cholesterol absorption by 11% (P = 0.050), and increased excretion of cholesterol, bile acids, and their sum as sterols by 9% (P = 0.021), 32% (P = 0.038), and 51% (P = 0.011) compared to olive oil. A serum marker for bile acid synthesis (7alpha-hydroxy-4-cholesten-3-one) increased by 28% (P = 0.038) within 10 h of consumption, and serum cholesterol levels decreased by 7% (P = 0.024), whereas a serum marker for cholesterol synthesis (lathosterol) as well as serum levels of plant sterols remained unchanged. Rapeseed oil and olive oil have different effects on cholesterol metabolism. Rapeseed oil, tends to decrease cholesterol absorption, increases excretion of cholesterol and bile acids, increases serum marker of bile acid synthesis, and decreases serum levels of cholesterol compared to olive oil. This could in part be explained by different concentrations of natural plant sterols. Supported by the Göteborg Medical Society, the Swedish Medical Society, the Swedish Board for Agricultural Research (SJFR) grant 50.0444/98 and by University of Göteborg.

Development of new antioxidant systems for frying oil and omega-3 oils

Science.gov (United States)

The development of natural antioxidant systems for frying oil will be discussed in this presentation. This study aimed to utilize vegetable oils such as soybean oil for frying, of which the United States is the world’s largest producer. To overcome the vulnerability of soybean oil to oxidation due t...

OIL AS POLITICAL WEAPON

Directory of Open Access Journals (Sweden)

Mariana, BUICAN

2013-12-01

Full Text Available Oil (called by some black gold has not always been as coveted and used, but only in the last hundred years has established itself as a highly sought after as an indispensable proper functioning of modern economic activity that an important factor in international politics. International oil regime has changed in the last decades. In 1960, oil regime was a private oligopol which had links with governments main consuming countries. By then the price of a barrel of oil was two U.S. dollars and seven major transnational oil companies decided the amount of oil that will be produced. Meanwhile the world region with the largest oil exports were more strongly expressed nationalism and decolonization. Result, it was so in the late 60s in the region occur independent states. They have created an organization aim of this resource to their advantage - OPEC (Organization of Petroleum Exporting Countries. Thus since 1973 there have been changes in the international regime governing oil field, namely producing countries were fixed production rate and price. After this time the oil weapon has become increasingly important in the management of international relations. Oil influenced the great powers to Middle East conflicts that occurred in the last century, but their attitude about the emergence of new sources of oil outside OPEC. In the late 90's, Russia has become a major supplier of oil to the West.

Microbial ecology of methanogenic crude oil biodegradation; from microbial consortia to heavy oil

Energy Technology Data Exchange (ETDEWEB)

Head, Ian M.; Maguire, Michael J.; Sherry, Angela; Grant, Russell; Gray, Neil D.; Aitken, Carolyn M.; Martin Jones, D.; Oldenburg, Thomas B.P.; Larter, Stephen R. [Petroleum Research Group, Geosciences, University of Calgary (Canada)

2011-07-01

This paper presents the microbial ecology of methanogenic crude oil biodegradation. Biodegraded petroleum reservoirs are one of the most dramatic indications of the deep biosphere. It is estimated that heavy oil and oil sands will account for a considerable amount of energy production in the future. Carbon, a major resource for deep subsurface microorganisms, and energy are contained in large quantities in petroleum reservoirs. The aerobic to anaerobic paradigm shift is explained. A key process for in-situ oil biodegradation in petroleum reservoirs is methanogenesis. New paradigms for in-reservoir crude oil biodegradation are discussed. Variations in anaerobic degradation of crude oil hydrocarbons are also discussed. A graph shows the different patterns of crude oil biodegradation under sulfate-reducing and methanogenic conditions. Alternative anaerobic alkane activation mechanisms are also shown. From the study, it can be concluded that methanogenic crude oil degradation is of global importance and led to the establishment of the world's enormous heavy oil deposits.

Economic Exposure to Oil Price Shocks and the Fragility of Oil-Exporting Countries

Directory of Open Access Journals (Sweden)

Toon Vandyck

2018-04-01

Full Text Available From a price range between 100 and 120 USD (U.S. dollars per barrel in 2011–2014, the crude oil price fell from mid-2014 onwards, reaching a level of 26 USD per barrel in January 2016. Here we assess the economic consequences of this strong decrease in the oil price. A retrospective analysis based on data of the past 25 years sheds light on the vulnerability of oil-producing regions to the oil price volatility. Gross domestic product (GDP and government revenues in many Gulf countries exhibit a strong dependence on oil, while more diversified economies improve resilience to oil price shocks. The lack of a sovereign wealth fund, in combination with limited oil reserves, makes parts of Sub-Saharan Africa particularly vulnerable to sustained periods of low oil prices. Next, we estimate the macroeconomic impacts of a 60% oil price drop for all regions in the world. A numerical simulation yields a global GDP increase of roughly 1% and illustrates how the regional impact on GDP relates to oil export dependence. Finally, we reflect on the broader implications (such as migration flows of macroeconomic responses to oil prices and look ahead to the challenge of structural change in a world committed to limiting global warming.

Solidifier effectiveness : variation due to oil composition, oil thickness and temperature

International Nuclear Information System (INIS)

Fieldhouse, B.; Fingas, M.

2009-01-01

This paper provided an overview of solidifier types and composition. Solidifiers are a class of spill treating agents that offer an effective means to convert a liquid oil into a solid material. They are used as a treatment option for oil spills on water. This paper also reported on recent laboratory studies that consist of 4 components: (1) a qualitative examination of the characteristics of the interaction of a broad range of solidifier products with a standard oil to evaluate reaction rate, states of solidification, and the impact of dosage, (2) a comparison of a smaller subset of solidifiers on the standard oil at lower temperatures, (3) solidifier treatment on a range of oils of varying physical properties and composition to assess the potential scope of application, and (4) the treatment of a series of small-scale oil layers of varying thickness to determine the significance of oil thickness on solidifier effectiveness and recovery. This paper also reviewed solidifier chemistry with particular reference to polymer sorbents; cross-linking agents; and cross-linking agents and polymeric sorbents combined. Toxicity is also an important issue regarding solidifiers. The aquatic toxicity of solidifiers is low and not measurable as the products are not water-soluble. There have not been any studies on the effects of the solidifier or the treated oil on surface feeders and shoreline wildlife that may come into contact with the products. It was concluded that oil composition may play a major role in solidifier effectiveness. The effectiveness of solidifiers is also inhibited at reduced temperatures, increased viscosity and density of the oil. 25 refs., 5 tabs., 2 figs., 1 appendix

Effect of citronella essential oil fractions as oil phase on emulsion stability

Science.gov (United States)

Septiyanti, Melati; Meliana, Yenny; Agustian, Egi

2017-11-01

The emulsion system consists of water, oil and surfactant. In order to create stable emulsion system, the composition and formulation between water phase, surfactant and oil phase are very important. Essential oil such as citronella oil has been known as active ingredient which has ability as insect repellent. This research studied the effect of citronella oil and its fraction as oil phase on emulsion stability. The cycle stability test was conducted to check the emulsion stability and it was monitored by pH, density, viscosity, particle size, refractive index, zeta potential, physical appearance and FTIR for 4 weeks. Citronellal fraction has better stability compared to citronella oil and rhodinol fraction with slight change of physical and chemical properties before and after the cycle stability test. However, it is need further study to enhance the stability of the emulsion stability for this formulation.

Application of synthetic fire-resistant oils in oil systems of turbine equipment for NPPs

Science.gov (United States)

Galimova, L. A.

2017-10-01

Results of the investigation of the synthetic fire-resistant turbine oil Fyrquel-L state in oil systems of turbosets under their operation in the equipment and oil supply facilities of nuclear power plants (NPPs) are presented. On the basis of the analysis of the operating experience, it is established that, for reliable and safe operation of the turbine equipment, at which oil systems synthetic fire-resistant oils on the phosphoric acid esters basis are used, special attention should be paid to two main factors, namely, both the guarantee of the normalized oil water content under the operation and storage and temperature regime of the operation. Methods of the acid number maintenance and reduction are shown. Results of the analysis and investigation of influence of temperature and of the variation of the qualitative state of the synthetic fair-resistant oil on its water content are reported. It is shown that the fire-resistant turbine oils are characterized by high hydrophilicity, and, in distinction to the mineral turbine oils, are capable to contain a significant amount of dissolved water, which is not extracted under the use of separation technologies. It is shown that the more degradation products are contained in oil and higher acid number, the more amount of dissolved water it is capable to retain. It is demonstrated that the organization of chemical control of the total water content of fireresistant oils with the use of the coulometric method is an important element to support the reliable operation of oil systems. It is recommended to use automatic controls of water content for organization of daily monitoring of oil state in the oil system. Recommendations and measures for improvement of oil operation on the NPP, the water content control, the use of oil cleaning plants, and the oil transfer for storage during repair works are developed.

21 CFR 102.37 - Mixtures of edible fat or oil and olive oil.

Science.gov (United States)

2010-04-01

... 21 Food and Drugs 2 2010-04-01 2010-04-01 false Mixtures of edible fat or oil and olive oil. 102... for Specific Nonstandardized Foods § 102.37 Mixtures of edible fat or oil and olive oil. The common or usual name of a mixture of edible fats and oils containing less than 100 percent and more than 0 percent...

Exploration of process parameters for continuous hydrolysis of canola oil, camelina oil and algal oil

KAUST Repository

Wang, Weicheng

2012-07-01

Thermal hydrolysis of triglycerides to form free fatty acid (FFA) is a well-established industry practice. Recently, this process has been employed as a first step in the production of biofuels from lipids. To that end, batch and continuous hydrolysis of various feedstocks has been examined at the laboratory scale. Canola, the primary feedstock in this paper, camelina and algal oils were converted to high quality FFA. For the different reaction temperatures, the continuous hydrolysis system was found to provide better yields than the laboratory batch system. In addition, CFD simulation with ANSYS-CFX was used to model the performance and reactant/product separation in the continuous, counter-flow reactor. The effects of reaction temperature, water-to-oil ratio (ratio of water and oil volumetric inflow rate), and preheating of the reactants were examined experimentally. Optimization of these parameters has resulted in an improved, continuous process with high mass yields (89-93%, for reactor temperature of 260°C and water-to-oil ratio of 4:1) and energy efficiency (76%, for reactor temperature of 250°C and water-to-oil ratio of 2:1). Based on the product quality and energy efficiency considerations, the reactor temperature of 260°C and water-to-oil ratio of 4:1 have provided the optimal condition for the lab scale continuous hydrolysis reaction. © 2012 Elsevier B.V.

Exploration of process parameters for continuous hydrolysis of canola oil, camelina oil and algal oil

KAUST Repository

Wang, Weicheng; Turner, Timothy L.; Stikeleather, Larry F.; Roberts, William L.

2012-01-01

Thermal hydrolysis of triglycerides to form free fatty acid (FFA) is a well-established industry practice. Recently, this process has been employed as a first step in the production of biofuels from lipids. To that end, batch and continuous hydrolysis of various feedstocks has been examined at the laboratory scale. Canola, the primary feedstock in this paper, camelina and algal oils were converted to high quality FFA. For the different reaction temperatures, the continuous hydrolysis system was found to provide better yields than the laboratory batch system. In addition, CFD simulation with ANSYS-CFX was used to model the performance and reactant/product separation in the continuous, counter-flow reactor. The effects of reaction temperature, water-to-oil ratio (ratio of water and oil volumetric inflow rate), and preheating of the reactants were examined experimentally. Optimization of these parameters has resulted in an improved, continuous process with high mass yields (89-93%, for reactor temperature of 260°C and water-to-oil ratio of 4:1) and energy efficiency (76%, for reactor temperature of 250°C and water-to-oil ratio of 2:1). Based on the product quality and energy efficiency considerations, the reactor temperature of 260°C and water-to-oil ratio of 4:1 have provided the optimal condition for the lab scale continuous hydrolysis reaction. © 2012 Elsevier B.V.

Cod Liver Oil

Science.gov (United States)

Cod liver oil can be obtained from eating fresh cod liver or by taking supplements. Cod liver oil is used as a source of vitamin A ... called macular degeneration. Some people put cod liver oil on their skin to speed healing of wounds, ...

When oil spills emulsify

International Nuclear Information System (INIS)

Bobra, M.; Fingas, M.; Tennyson, E.

1992-01-01

Cleanup operations of oil spills must take into account the numerous detrimental effects attributable to the emulsification of spilled oil into a stable water-in-oil mousse. The incorporation of water greatly increases the volume of the polluted material. The viscous nature of mousse impedes the efficient operation of most mechanical recovery equipment and results in a cohesive slick that resists dispersion, both natural and artificial. The rate at which spilled oil emulsifies determines the effective window of opportunity for specific countermeasures. Much has been learned from previous studies on petroleum emulsification, but is still remain a poorly understood phenomenon. Although most crude oils can be emulsified, not all spills result in the formation of stable mousse. The formation of mousse results from a complex series of processes. Whether an oil will form mousse or not, and if so, at what rate, depends on an array of different factors including the properties of the oil and the prevailing environmental conditions. We need a greater understanding of the emulsification process to better predict the emulsification behavior of oil spills and utilize the most appropriate countermeasures available. In this paper, the authors report on work to elucidate the role that physicochemical factors play in determining an oil's tendency to emulsify. The authors studied the emulsification behavior of oils of known composition to examine the importance of oil chemistry in the emulsification process

What about oil reserve depletion and crude oil price evolution?

International Nuclear Information System (INIS)

2007-01-01

The objective of this report is to give a synthesis of different points of view with respect to the 'Peak Oil' perspective and to the crude oil price evolution. In the first part, the authors examine the evolutions and assessments of oil reserves and productions, by discussing the different types of reserve, the optimistic and pessimistic points of views. Then, in the second part, they analyse the long term price formation, the various production technical costs (conventional oils, heavy oils and asphaltic sands, coal- and gas-based synthetic hydrocarbons, bio-fuels), the external costs (notably in relationship with greenhouse emissions), the relationship between geopolitical issues and short and middle term price formation. In the third and last part, they discuss the possible evolutions and scenarios in terms of demand, production, and prices

The Asia-Pacific oil market : prospects for Canadian oil

International Nuclear Information System (INIS)

Fesharaki, F.

2004-01-01

The Asia-Pacific region is among the fastest growing oil markets for which analysts predict healthy growth rates due to high energy demands from developing countries such as China. Increased oil demand will mean new refining capacity needs and increased supplies of crude oil. The indigenous crude supply in the Asia-Pacific region is limited and unable to meet the region's needs. Imports are therefore expected to rise continuously. Although the Middle East will continue to be the dominant player in meeting these growing oil needs, Canada has an opportunity to diversify the supply source and play a significant role in meeting the energy needs of the Asia-Pacific region. tabs., figs

Ozonated Olive Oils and Troubles

Directory of Open Access Journals (Sweden)

Bulent Uysal

2014-04-01

Full Text Available One of the commonly used methods for ozone therapy is ozonated oils. Most prominent type of used oils is extra virgin olive oil. But still, each type of unsaturated oils may be used for ozonation. There are a lot of wrong knowledge on the internet about ozonated oils and its use as well. Just like other ozone therapy studies, also the studies about ozone oils are inadequate to avoid incorrect knowledge. Current data about ozone oil and its benefits are produced by supplier who oversees financial interests and make misinformation. Despite the rapidly increasing ozone oil sales through the internet, its quality and efficacy is still controversial. Dozens of companies and web sites may be easily found to buy ozonated oil. But, very few of these products are reliable, and contain sufficiently ozonated oil. This article aimed to introduce the troubles about ozonated oils and so to inform ozonated oil users. [J Intercult Ethnopharmacol 2014; 3(2.000: 49-50

The third oil shock: The effects of lower oil prices

Energy Technology Data Exchange (ETDEWEB)

Pearce, J

1983-01-01

This book assesses how oil prices have affected other elements of the economy and assesses the costs and benefits that could result from lower oil prices for different groups of countries. The book also analyses the extent of OPEC's influence, the consumers countries' needs for energy security and the altered role of the oil industry.

The North Cape oil spill assessment: PAHs in oil

International Nuclear Information System (INIS)

Brown, J.; Boehm, P. D.; Hardestine, J. H.; Douglas, G. S.

1997-01-01

The North Cape oil spill in January 1996 resulted in the release of an estimated 827,000 gallons of No. 2 home heating oil into the nearshore turbulent waters of coastal Rhode Island. The oil was mixed into the water column and was transported on the surface as well as below the surface. Some of the spilled oil entered the coastal ponds behind the beaches. Sampling and chemical analysis for detailed suites of petroleum saturated and polycyclic aromatic hydrocarbons (PAHs) was undertaken as part of the assessment of the fate of the oil spill and of the exposure to the marine environment. The ponds were found to contain significant quantities of background petroleum hydrocarbons, including petrogenic PAHs and combustion PAHs. Initial assessment pointed (incorrectly as it turned out) to widespread contamination due only to the North Cape spill. Application of advanced chemical fingerprinting approaches, and geochemical biomarker data illustrated that many of the PAHs consisted of combustion-related 4- and 5-ringed PAHs, attributable to diesel fuel used routinely by boats in the area. The analysis demonstrated that the use of non-specific total PAH data and insufficient fingerprinting and allocation of petrogenic residues has the potential to overestimate contamination and hence injury to the environment in similar oil spill situations

Determination of Calorific Ability of Fuel Briquettes on the Basis of Oil and Oil Slimes

Science.gov (United States)

Fedyaeva, O. A.; Poshelyuzhnaya, E. G.; Rakhmatulina, E. M.; Zakharov, V. A.; Fisenko, T. E.

2018-01-01

Utilization and neutralization of oil slimes is one of important environmental problems of the oil-extracting, oil-processing and petrochemical industry. The easiest and economic way of utilization of oil slimes is their use as a part of the bricketed boiler fuel. In this work the highest calorific ability of crude oil, the oil slimes and fuel briquettes made on their basis is defined. A research problem was carrying out the technical analysis of oil fuels on the content in them analytical moisture, the cindery rest and volatiles. It is established that in comparison with oil slimes crude oil possesses bigger highest calorific ability, has smaller humidity and an ash-content. The highest calorific abilities of the boiler briquettes made of samples of crude oil, oil slimes and peat made 14 - 26 MJ/kg.

Preliminary use of cashew kernel oil in Clarias gariepinus fingerlings diet: comparison with fish oil and palm oil

Directory of Open Access Journals (Sweden)

Morgane Paul Magouana Anvo

2017-04-01

Full Text Available Abstract The present study was performed to investigate the effect of fish oil (FO, palm oil (PO, and cashew kernel oil (CKO as the dietary lipid sources on the growth performance, tissues fatty acids composition and economical profitability in Clarias gariepinus fingerlings. Three isonitrogenous (49.32%, isolipidic (15.18%, and isoenergetic (21 kJ/g diets were formulated, differed only to the added lipid source and coded accordingly as D1 (fish oil, D2 (palm oil, and D3 (cashew kernel oil. Catfish fingerlings (initial body weight = 2.43 ± 0.04 g were stocked at 1 fish/L and fed to trial diets at 5.6%. At the end of 8 weeks, C. gariepinus fingerlings fed with D1 and D3 had significantly identical growth and feed utilization efficiency. Those fed with D2 exhibited significantly and numerically low growth performance compared, respectively, to D1 and D3. Contrary to whole-body composition of fish, the muscle lipids fatty acids composition was influenced by the fatty acids profile of the dietary lipid sources. High net profit value (NPV of 24.59$, high investment cost analysis (ICA of 10.14$ and low benefit: cost ratio (BCR of 2.42 were observed in fish fed with D1 while those fed with D3 allowed to have high NPV (23.15$, low ICA (7.86$ and high BCR (2.95. Like others vegetable oils, cashew kernel oil can replace expensive fish oil in C. gariepinus fingerlings diet without negatively affecting its growth performances.

Mineral oil

International Nuclear Information System (INIS)

Schult-Bornemann, Karl-Heinz

2015-01-01

The dominant theme in the world energy market was the fall in oil prices in 2014. From 115 US-$/bbl in June it dropped to below 50 US-$/bbl in January 2015. Thereby the shale oil revolution has had the strong impact on the global energy situation, to this point has been predicted for three years. Although no one could predict the exact height of the fall in oil prices, but with oil as a reserve currency for all other fuels, it has not only had an impact on the gas and coal prices, but other commodities, such as copper, have also yielded. About cause and effect, there is a lot of speculation - not all of which are supported by wisdom. [de

Sassafras oil overdose

Science.gov (United States)

Sassafras oil comes from the root bark of the sassafras tree. Sassafras oil overdose occurs when someone swallows more than the ... Safrole is the poisonous ingredient in sassafras oil. It is a clear or ... yellow oily liquid. It can be dangerous in large amounts.

Oil spill risk assessment : relative impact indices by oil type and location

International Nuclear Information System (INIS)

French-McCay, D.; Beegle-Krause, C.J.; Rowe, J.; Rodriguez, W.; Schmidt Etkin, D.

2009-01-01

The aim of the study was to inform policies related to resource allocation for oil spill prevention, preparedness and response activities in Washington State. Oil spill reports and impact modelling studies were evaluated in order to determine major risk consequence factors including spill volume, location, timing, toxicity, persistence, and expected frequency of spills by sector. The Washington Compensation Schedule pre-assessment screening and oil spill compensation schedule regulations (WCS) designed to consider the sensitivity of oiled areas as well as the relative density and seasonal distributions of sensitive biota. Spill incidents were assigned per-gallon impact scores based on geographic location, oil type, and season. The WCS qualitative rating system was used to assess the potential impacts of spills in different geographic systems. Geographic zones were based on geography, circulation of currents, climate, and the WCS sub-regions in estuarine and marine areas on the Pacific coast of Washington State. Oil types included crude, heavy, and light oils; gasoline; jet fuel; and non-petroleum oils. A habitat index was calculated to represent existing stream conditions. It was concluded that the relative impact risk model is a reliable method for characterizing impacts based on spill volume, oil effects, and vulnerability rankings. 25 refs., 20 tabs., 3 figs

Trace metal concentrations in sediments from the southwest of the Iberian Peninsula

Directory of Open Access Journals (Sweden)

Julián Blasco

2010-11-01

Full Text Available Metal sediment concentrations (As, Cd, Cu, Hg, Ni, Pb and Zn in surface sediments (0 to 5 cm from 11 sampling stations in the southwest of the Iberian Peninsula (the Ria Formosa and the Guadiana River, the Ría de Huelva and the Bay of Cadiz were determined in two seasonal periods (autumn 2006 and spring 2007. No seasonal metal concentration pattern was identified, as similar values were found in both periods. The highest concentrations of copper, zinc, lead and cadmium were reported in the Ria of Huelva area, and those of mercury and nickel in the Bay of Cadiz. The hazard potential index (HPiM was determined to assess the potential risk associated with metal contamination (Cu, Cd, Pb and Zn, taking into account extractable (presumed bioavailable fractions of these metals and site-specific sediment quality values. When the HPiM is > 1 there is risk, and according to this index Ría de Huelva is polluted whereas the Bay of Cadiz is not.

Oil slick skimmer

International Nuclear Information System (INIS)

Karterman, D.S.

1993-01-01

A craft for removing an oil slick from a body of water is described comprising: a pair of spacedly arranged paralleled positioned elongated floats, a platform mounted on and extending between said floats, a weir mounted on said platform between said floats and being movable independently and substantially vertical of the longitudinal axis of said floats to a position below the surface of said body of water, a submersible oil receiving and storage means detachedly mounted to said platform between said floats and having an inlet port at one level and comprising a substantially enclosed oil accumulator having an outlet port at a lower level, said weir comprising a sluice gate constructed and arranged to admit into said inlet port of said oil receiving and storage means under the effects of gravity a portion of an oil stick comprising a water and oil mixture skimmed from said body of water, and a first pump connected to said outlet port of said accumulator to control the movement of water from the inside lower level of said accumulator out of said accumulator to thereby control the amount of the oil slick flowing into said accumulator

BIODIESEL FUELS FROM PALM OIL, PALM OIL METHYLESTER ...

African Journals Online (AJOL)

a

determined by methods outlined by A.O.C.S. (American Oil Chemist Society) [12], Usoro et al. [15], Clark [2], and ... diesel have shown that novel vegetable diesels could be obtained from palm oil. .... C-H stretch for alkenes and aromatics.

Purification of water polluted with oil and sulfurous closed-ring and aromatic compounds contained in oil and oil products using bacteria relating to thiosphaera

International Nuclear Information System (INIS)

Kurashov, V.M.; Sakhno, T.V.; Gavrilov, V.S.; Zijatdinov, R.N.

2005-01-01

The intensity of natural purification (self-purification) of reservoirs polluted with oil and oil products is determined by microorganisms. Hydrocarbon-oxidizing microorganisms are constant natural constituent of biocenose in reservoirs. However, as a result of outflows, the oil and oil products concentration exceeds maximum values allowing normal vital functions of microorganisms resulting in breaking micro-biocenose suppression of vital functions of bacteria. In this regard, elective anaerobic microorganisms of Thiosphaera are worthy of notice. We found out that bacteria belonging to Thiosphaera pantotropha decomposed oil at high oil concentrations in water (at oil concentration like 1 liter of oil in 1 liter of water). And this is when aerobic microorganisms lose their vital functions at maximum concentration of 20 g of oil in 1 liter of water. To intensify the process of oil decomposition we emulsified oil with aqueous solutions of salts. Thiosphaera pantotropha are found out to decompose oil in a wide range of ratio between oil and aqueous solutions of salts: from 1:10 to 10:1. The water solutions salinity made from 20 g/l to 80 g/l. It must be noticed that, since the Thiosphaera pantotropha are elective anaerobes and decompose oil both in presence and in absence of oxygen, it is not necessary anymore to conduct the process under strictly anaerobic conditions and to supply additional oxygen. This makes it possible to simplify the process of biodegradation of oil and to make this process practically more feasible and economically more profitable being compared to the processes based on the use of other species of bacteria. We found out that Thiosphaera decompose sulfurous closed-ring and aromatic compounds in oil which are chemically and thermally stable and can be hardly decomposed, and possess extremely poisonous properties, as well. The use of microorganisms of Thiosphaera pantotropha allows to purify waters polluted with oil and oil products both during

Contained controlled burning of spilled oil during the Exxon Valdez oil spill

International Nuclear Information System (INIS)

Allen, A.A.

1990-01-01

During the evening of the second day following the Exxon Valdez oil spill, an estimated 57,000-114,000 liters of North Slope crude oil were eliminated using in-situ combustion. The oil was collected with 3M's Fire Boom towed in a U-shaped configuration behind two fishing boats. Working with 152 m long tow lines, a 137 m boom was moved at ca 0.26-5.2 m/s through slightly emulsified oil patches in the downwind region of the spill. A gelled fuel ignitor was used to ignite the captured oil, and the size and intensity of the blaze was controlled by adjusting the speed of the vessels. Total burn time was ca 1.25 h, however the intense part of the burn lasted for ca 45 minutes. Using several methods to estimate the total volume of oil collected, the volume resulted in ca 1136 liters of stiff, taffy-like burn residue that could be picked up easily on completion of the burn. The controlled burn thus resulted in an estimated 98% or better elimination of crude oil. It had been planned to use a helitorch to ignite the captured oil, however darkness required the use of the gelled ignitor. Had the helitorch been used, numerous ignition points could have been spread througout the contained oil, providing a much more efficient heating and ultimate ignition of the oil. 5 figs

ECONOMIC CONSEQUENCES OF PEAK OIL FOR THE MAJOR MULTINATIONAL OIL AND GAS COMPANIES

Directory of Open Access Journals (Sweden)

Antonio García-Amate

2018-03-01

Full Text Available The main goal of this work is to analyze the financial statements of the five major multinational oil and gas companies, for the 2011-2015 period, in the framework of the peak oil phenomenon. Peak oil can affect key financial indicators (e.g., earnings volatility, leverage that are used by managers, investors, and stockholders and which may potentially lead to changes in the decision making by management. Our results show that the decline in oil production affects the decisions about investment in new oil wells, leverage, dividends paid, shares purchased and net income involving the five major companies. In addition, we study the evolution of oil prices, and its influence in several items of the financial statements. Even though oil prices were at high levels during 2011-2014, however, the net income of the five companies actually declined due to the impact of peak oil. Finally, data for the last year studied (2015 indicate a general deterioration in return ratios and other accounting variables. Although the new investments should have been profitable, they have been influenced by peak oil, compromising the economic position of the companies. The advice to these companies would be to relax their investments, especially during a period of falling oil prices. Company managers need to recognize the prolonged duration of peak oil and price trends to promote profitability recovery decisions.

Oil analysis in machine diagnostics

Energy Technology Data Exchange (ETDEWEB)

Vaehaeoja, P.

2006-07-01

This study concentrates on developing and tuning various oil analysis methods to meet the requirements of modern industry and environmental analytics. Oil analysis methods form a vital part of techniques used to monitor the condition of machines and may help to improve the overall equipment effectiveness value of a factory in a significant manner. Worm gears are used in various production machines, and their breakdowns may cause significant production losses. Wearing of these gears is relatively difficult to monitor with vibration analysis. Analysis of two indicator metals, copper and iron, may reveal wearing phenomena of worm gears effectively, and savings can be significant. Effective wear metal analysis requires good tools. ICP-OES with kerosene dilution is widely used in wear metal analysis, but purchasing and using of ICP-OES is expensive. A cheaper FAAS technique with similar pre-treatment of oil samples was tested and it proved to be useful especially in analyzing small amounts of samples. The accuracy of FAAS was sufficient for quantitative work in machine diagnostics and waste oil characterization. Solid debris analyses are useful in oil contamination control as well as in detection of wearing mechanisms. Membrane filtration, optical microscopy, SEM and automatic particle counting were applied in analysis of rolling and gear oils. Particle counting is an effective way to detect oil contamination, but in the studied cases even larger particles than those detected in normal ISO classes would be informative. However, membrane filtration and optical microscopy may reveal the wearing machine element exactly. Additives provide oils with desired properties thus they should be monitored intensively. A FTIR method for quantitative analysis of fatty alcohols and fatty acid esters in machinery oils was developed during this work. It has already been used successfully in quantitative and qualitative analysis of machinery oil samples. Various kinds of oils may be

The Asymmetric Effects of Oil Shocks on an Oil-exporting Economy

OpenAIRE

Omar Mendoza; David Vera

2010-01-01

We estimate the effects of unexpected changes in oil prices on output for the case of Venezuela, an oil-exporting economy. Following Hamilton (2003), Lee et al. (1995), and Mork (1989), we estimate measures of oil shocks and determine the effect of these

Manitoba oil activity review, 1992

International Nuclear Information System (INIS)

1993-04-01

In an annual survey of Manitoba's petroleum industry, data are presented on oil and natural gas leases and sales, geophysical activity, exploration and drilling activity, production, oil prices and sales value, royalties and taxes, direct revenues from oil exploration and development, reserves, industry expenditures, and oil fields. Throughout the report, explanations are given of the items covered. Descriptions are made of new developments, the oil market, oil policies, incentive programs, and industrial activities. During 1992, 28 wells were drilled, compared to 54 in 1991. Oil production was down ca 8% from 1991 levels, to 656,415 m 3 ; the value of the oil produced decreased 4% to ca $86.3 million; and provincial revenues from the oil industry decreased by 24%. Oil industry expenditures in the province were estimated at $58 million, down 16% from 1991. As of 4 January 1993, there were 11 oil fields and 120 non-confidential oil pools designated in Manitoba. Crude oil prices fluctuated throughout the year. In 1992, Manitoba's average crude oil price was $20.89/bbl, compared with 1991's average of $20.14/bbl. Manitoba Energy and Mines amended the Drilling Incentive Program to provide a 10,000 m 3 holiday volume for horizontal wells. 12 figs., 17 tabs

Manitoba oil activity review, 1993

International Nuclear Information System (INIS)

1994-07-01

In an annual survey of Manitoba's petroleum industry, data are presented on oil and natural gas leases and sales, geophysical activity, exploration and drilling activity, production, oil prices and sales value, royalties and taxes, direct revenues from oil exploration and development, reserves, industry expenditures, and oil fields. Throughout the report, explanations are given of the items covered. Descriptions are made of new developments, the oil market, oil policies, incentive programs, and industrial activities. During 1993, 87 wells were drilled, compared to 28 in 1992. Oil production was down ca 3% from 1992 levels, to 634,561 m 3 ; the value of the oil produced decreased 10% to ca $77.5 million; and provincial revenues from the oil industry decreased by 4%. Oil industry expenditures in the province were estimated at $73 million, up 26% from 1992. As of 4 January 1994, there were 11 oil fields and 120 non-confidential oil pools designated in Manitoba. Crude oil prices fluctuated throughout the year, between $15.12 and $21.50/bbl. In 1993, Manitoba's average crude oil price was $19.40/bbl, compared with 1992's average of $20.89/bbl. Manitoba Energy and Mines amended the Drilling Incentive Program to provide a 10,000 m 3 holiday volume for horizontal wells. 12 figs., 17 tabs

Process for separating and recovering oil from oil-sands, etc

Energy Technology Data Exchange (ETDEWEB)

Preller, H

1920-07-14

A process for separating and recovering oil from oil-sands, bitumen from oil-chalk, oil shale, and coal is characterized in that the material to be separated feeds, by a self-acting feeding arrangement, to a system with slowly rotating drums alternating in different directions and thereby it is exposed to the action of hot water running opposite to the rotation, direction of the drum, with addition of extraction-medium, so that the light material is washed out and rises to the top. It is carried off, while the heavy material sinks to the bottom and, by bucket-conveyor is removed.

Manitoba oil activity review, 1991

International Nuclear Information System (INIS)

1992-04-01

In an annual survey of Manitoba's petroleum industry, data are presented on oil and natural gas leases and sales, geophysical activity, exploration and drilling activity, production, exports to other provinces and the USA, oil prices and sales value, royalties and taxes, direct revenues from oil exploration and development, reserves, industry expenditures, and oil fields. Throughout the report, explainations are given of the items covered. Descriptions are made of new developments, the oil market, oil policies, incentive programs, and industrial activities. During 1991, 54 wells were drilled, compared to 79 in 1990. Oil production was down ca 3% from 1990 levels, to 712,792 m 3 , the value of the oil produced decreased 21% to ca $90.3 million, and provincial revenues from the oil industry declined by 15%. Oil industry expenditures in the province were estimated at $69 million, down 9% from 1990. As of the end of 1991, there were 11 oil fields and 118 non-confidential oil pools designated in Manitoba. The forecast for 1992 indicates that exploration activity will increase in response to new incentive programs. Crude oil production is expected to decline slightly to about 667,000 m 3 . 9 figs., 17 tabs

Process of transforming into light oils heavy oils from carbonization of lignites, coals, etc

Energy Technology Data Exchange (ETDEWEB)

Mony, H

1926-12-20

A process is described for transforming into light oils the heavy oils coming from the carbonization of lignites, peats, coals, and shales, and heavy oils from original minerals and vegetables, consisting of heating the heavy oils or tars in the presence of one or more solid or liquid substances conveniently chosen, with a veiw to effect distillation of the oils under atmospheric pressure at an appropriate temperature, the solids or liquid substances favoring the formation of light products under the influence of heat, being preferably added to the oil before admitting it to the retort and heating, so that the light oils are obtained from the heavy oils in a single operation.

Oil shale commercialization study

Energy Technology Data Exchange (ETDEWEB)

Warner, M.M.

1981-09-01

Ninety four possible oil shale sections in southern Idaho were located and chemically analyzed. Sixty-two of these shales show good promise of possible oil and probable gas potential. Sixty of the potential oil and gas shales represent the Succor Creek Formation of Miocene age in southwestern Idaho. Two of the shales represent Cretaceous formations in eastern Idaho, which should be further investigated to determine their realistic value and areal extent. Samples of the older Mesozonic and paleozoic sections show promise but have not been chemically analyzed and will need greater attention to determine their potential. Geothermal resources are of high potential in Idaho and are important to oil shale prospects. Geothermal conditions raise the geothermal gradient and act as maturing agents to oil shale. They also might be used in the retorting and refining processes. Oil shales at the surface, which appear to have good oil or gas potential should have much higher potential at depth where the geothermal gradient is high. Samples from deep petroleum exploration wells indicate that the succor Creek shales have undergone considerable maturation with depth of burial and should produce gas and possibly oil. Most of Idaho's shales that have been analyzed have a greater potential for gas than for oil but some oil potential is indicated. The Miocene shales of the Succor Creek Formation should be considered as gas and possibly oil source material for the future when technology has been perfectes. 11 refs.

Raman detection of extra virgin olive oil adulterated with cheaper oils

Science.gov (United States)

Farley, Carlton; Kassu, Aschalew; Mills, Jonathan; Kenney, Brianna; Ruffin, Paul; Sharma, Anup

2016-09-01

Pure extra virgin olive oil (EVOO) is mixed with cheaper edible oils and samples are kept inside clear glass containers, while a 785nm Raman system is used to take measurements as Raman probe is placed against glass container. Several types of oils at various concentrations of adulteration are used. Ratios of peak intensities are used to analyze raw data, which allows for quick, easy, and accurate analysis. While conventional Raman measurements of EVOO may take as long as 2 minutes, all measurements reported here are for integration times of 15s. It is found that adulteration of EVOO with cheaper oils is detectable at concentrations as low as 5% for all oils used in this study.

Comparative techno-economic analysis of biohydrogen production via bio-oil gasification and bio-oil reforming

International Nuclear Information System (INIS)

Zhang, Yanan; Brown, Tristan R.; Hu, Guiping; Brown, Robert C.

2013-01-01

This paper evaluates the economic feasibility of biohydrogen production via two bio-oil processing pathways: bio-oil gasification and bio-oil reforming. Both pathways employ fast pyrolysis to produce bio-oil from biomass stock. The two pathways are modeled using Aspen Plus ® for a 2000 t d −1 facility. Equipment sizing and cost calculations are based on Aspen Economic Evaluation® software. Biohydrogen production capacity at the facility is 147 t d −1 for the bio-oil gasification pathway and 160 t d −1 for the bio-oil reforming pathway. The biomass-to-fuel energy efficiencies are 47% and 84% for the bio-oil gasification and bio-oil reforming pathways, respectively. Total capital investment (TCI) is 435 million dollars for the bio-oil gasification pathway and is 333 million dollars for the bio-oil reforming pathway. Internal rates of return (IRR) are 8.4% and 18.6% for facilities employing the bio-oil gasification and bio-oil reforming pathways, respectively. Sensitivity analysis demonstrates that biohydrogen price, biohydrogen yield, fixed capital investment (FCI), bio-oil yield, and biomass cost have the greatest impacts on facility IRR. Monte-Carlo analysis shows that bio-oil reforming is more economically attractive than bio-oil gasification for biohydrogen production. -- Highlights: ► Biohydrogen production via bio-oil reforming has higher energy efficiency compared to gasification. ► Hydrogen price, fixed capital cost, and feedstock cost most strongly affect IRR. ► Lower risk investment is biohydrogen production via bio-oil reforming

Oils, paintings and chemistry

Directory of Open Access Journals (Sweden)

Maria Eduarda Machado de Araújo

2005-01-01

Full Text Available In oil paintings artists use oils to apply pigments. These oils firstly are liquid and then solidify in a thin film. Many chemical reactions are involved in drying and also in the aging of these oils. Drying is a continuous process that begins with the oxidation of insaturated fatty acids from triglycerides to originate peroxides. These compounds suffer a cascade of reactions that lead to cross linking bonds between fatty acids residues, transforming the oil in a solid film. Identification of the film oil is possible using the palmitic/stearic ratio (P/S by chromatographic (GC and/or spectroscopic techniques. Sterol composition, phytosterols or cholesterol, determined by GC-MS or FTIR techniques, allows investigators to distinguish between oil painting and a temper one that used egg as the binding medium.

Oil shale activities in China

International Nuclear Information System (INIS)

Peng, D.; Jialin, Q.

1991-01-01

China has abundant oil shale resources, of the Early Silurian to Neogene age, the most important being the Tertiary period. The proved oil shale reserves in Fushun amount to 3.6 billion t, in Maoming 4.1 billion t. In Fushun, oil shale is produced by open-pit mining as a byproduct of coal, in Maoming it is also mined in open pits, but without coal. In China, scale oil has been produced from oil shale for 60 years. Annual production of crude shale oil amounts to about 200 000 t. The production costs of shale oil are lower than the price of crude petroleum on the world market. China has accumulated the experience and technologies of oil shale retorting. The Fushun type retort has been elaborated, in which the latent and sensible heat of shale coke is well utilized. But the capacity of such retort is relatively small, therefore it is suitable for use in small or medium oil plants. China has a policy of steadily developing shale oil industry. China is conducting oil shale research and developing oil shale processing technology. Much attention is being pay ed to the comprehensive utilization of oil shale, shale oil, and to environmental problems. In China, oil shale is mostly used for producing shale by retorting, attention will also be paid to direct combustion for power generation. Great achievements in oil shale research have been made in the eighties, and there will be a further development in the nineties. (author), 12 refs., 3 tabs

Treating oil shale

Energy Technology Data Exchange (ETDEWEB)

Dolbear, S H

1921-01-04

Oil shale is treated for the separation of the valuable organic compounds, with a view to economy in subsequent destructive distillation, by grinding to powder, mixing with water to form a pulp, adding a small quantity of an oil liquid and aerating the mixture to form a froth containing the organic compounds. If the powdered shale contains sufficient free oil, the addition of oil to the pulp may be dispensed with. In some cases an electrolyte such as sulfuric acid may be added to the pulp.

Oil refineries

International Nuclear Information System (INIS)

Boehmer, S.; Winter, B.

2001-01-01

In refineries in particular attention is paid to the minimization of the generation of waste. Therefor catalysts in many processes are regenerated, absorbents are recycled and oily by-products are re-refined or used as fuels. This study discusses the origin and utilization of by-products from the oil industry. The processing of crude oils causes by-products and waste resulting from the crude oil itself or from cleaning measures for water pre-treatment, effluent treatment and flue gas treatment. (author)

Sorption of oil in the polyurethane from oil or castor oil; Sorcao de oleo no poliuretano derivado do petroleo ou do oleo de mamona

Energy Technology Data Exchange (ETDEWEB)

Florentino, Wagner M; Goulart, Shane A.S.; Mulinari, Daniella R. [Centro Universitario de Volta Redonda (UniFOA), Volta Redonda, RJ (Brazil)], e-mail: wagner-can@hotmail.com

2011-07-01

The oil outpouring has caused serious environmental problems. To minimize this damage polyurethane foams have been used. In this work, the use of polyurethane from oil and castor oil, in different polyol/diisocyanate mass ratios, to absorb oil was evaluated. Results revealed that the proportion of polyol and diisocyanate influenced in the sorption capacity and the polyurethane from castor oil presented greater sorption capacity. Of this way, can say that the polyurethane from oil can be replaced by castor oil, contributing to sustainable development. (author)

Oil companies make cutbacks

International Nuclear Information System (INIS)

Dupin, Ludovic

2014-01-01

As oil prices are falling, the oil sector faces company restructuring, merger projects, closure of oil fields, and so on. Restructuring is motivated by the costs of offshore exploration and oil production projects. Saudi Arabia tries to fight the emergence of shale gases by reducing oil prices, and somehow succeeds as some projects in the USA are put into question again. Experts perceive this situation as an opportunity for the sector to improve its efficiency and reduce over-staffing

Lavender oil

Science.gov (United States)

Lavender oil is an oil made from the flowers of lavender plants. Lavender poisoning can occur when ... further instructions. This is a free and confidential service. All local poison control centers in the United ...

An overview of empty fruit bunch from oil palm as feedstock for bio-oil production

International Nuclear Information System (INIS)

Chang, Siu Hua

2014-01-01

Empty fruit bunch (EFB) from oil palm is one of the potential biomass to produce biofuels like bio-oil due to its abundant supply and favorable physicochemical characteristics. Confirming the assertion, this paper presents an overview of EFB as a feedstock for bio-oil production. The fundamental characteristics of EFB in terms of proximate analysis, ultimate analysis and chemical composition, as well as the recent advances in EFB conversion processes for bio-oil production like pyrolysis and solvolysis are outlined and discussed. A comparison of properties in terms of proximate analysis, ultimate analysis and fuel properties between the bio-oil from EFB and petroleum fuel oil is included. The major challenges and future prospects towards the utilization of EFB as a useful resource for bio-oil production are also addressed. - Highlights: • Palm EFB has high heating value and low greenhouse gas emissions during combustion. • Conversion of EFB to bio-oil is mainly by fast pyrolysis without and with catalyst. • Bio-oil from EFB is lower in heating value, heavier and more acidic than fuel oil. • The viscosity of bio-oil from EFB is between those of light and heavy fuel oils. • The flash and pour points of bio-oil from EFB are close to those of light fuel oil

Fractional distillation of oil

Energy Technology Data Exchange (ETDEWEB)

Jones, L D

1931-10-31

A method of dividing oil into lubricating oil fractions without substantial cracking by introducing the oil in a heated state into a fractionating column from which oil fractions having different boiling points are withdrawn at different levels, while reflux liquid is supplied to the top of the column, and additional heat is introduced into the column by contacting with the oil therein a heated fluid of higher monlecular weight than water and less susceptible to thermal decomposition than is the highest boiling oil fraction resulting from the distillation, or of which any products produced by thermal decomposition will not occur in the highest boiling distillate withdrawn from the column.

Restructuring: new relationships between the oil companies and the upstream oil firms

International Nuclear Information System (INIS)

Barreau, S.

2001-11-01

Since the 1986 oil shock, international oil companies have focused on their base competencies, concentrating on activities viewed as their core businesses and steadily increasing the number of tasks to be subcontracted to the upstream oil and gas service sector. The upstream oil and gas service companies had to be restructured to face this new challenge. The strategies they launched at the end of the 80's were varied. Some firms became largely integrated (Schlumberger, Baker Hughes, Halliburton) whereas other firms chose to broaden their range of services. However generally, they opted for external investment which led to an important wave of mergers and acquisitions. The first part characterizes the upstream oil and gas sector by introducing the main oil and gas service firms and their recent strategic evolution. This concludes with both an economic valuation and a typology of attempted growth strategies. To illustrate this, a matrix has been created to characterise the dynamic paths of the oil and gas service firms. The purpose of the second part is to consider the economic theories related to industrial strategies. The strategies of innovation, market protection, vertical integration and diversification have been studied to illustrate the main conclusion which is that the aim of all these strategies was to change the relationships between the oil companies and the upstream oil and gas service firms. (author)

Enrichment of Fusobacteria in Sea Surface Oil Slicks from the Deepwater Horizon Oil Spill

OpenAIRE

Gutierrez, Tony; Berry, David; Teske, Andreas; Aitken, Michael D.

2016-01-01

The Deepwater Horizon (DWH) oil spill led to rapid microbial community shifts in the Gulf of Mexico, including the formation of unprecedented quantities of marine oil snow (MOS) and of a massive subsurface oil plume. The major taxa that bloomed in sea surface oil slicks during the spill included Cycloclasticus, and to a lesser extent Halomonas, Alteromonas, and Pseudoalteromonas?organisms that grow and degrade oil hydrocarbons aerobically. Here, we show that sea surface oil slicks at DWH cont...

Oil: Economics and politics

International Nuclear Information System (INIS)

Ayoub, A.

1994-01-01

A review is presented of the evolution of the international petroleum sector since 1973 with a special emphasis on the interdependence between the economic and political factors that influence it. Two issues are focused on: the effects of the nationalization of oil companies on the sharing of oil rents and on changes in the structure of the oil market; and the determination of oil prices. Definitions are presented of oil rents, and the reasons for OPEC nationalization of oil companies are explored. The effects of nationalization on market structures, expansion of free markets, and vertical integration are discussed. The existence of an oil price floor and the reasons for such a floor are examined. It is shown that nationalization induced an internalization of rents by the producing countries, leading to the emergence of a differential rent supported by the politics of the industrialized countries. Nationalization led to the breakup of systems of vertical and horizontal integration, with replacement by a new dual structure with OPEC controlling the upstream activities of the oil sector and oil companies controlling the downstream ones. Prices move between a floor price set by the costs of substitute deposits in the U.S., while the determination of ceiling levels by OPEC rests on successive fragile compromises. Overall oil is still a strategic product, despite the existence of spot markets, forward trading options, etc. 29 refs

SOVENT BASED ENHANCED OIL RECOVERY FOR IN-SITU UPGRADING OF HEAVY OIL SANDS

Energy Technology Data Exchange (ETDEWEB)

Munroe, Norman

2009-01-30

With the depletion of conventional crude oil reserves in the world, heavy oil and bitumen resources have great potential to meet the future demand for petroleum products. However, oil recovery from heavy oil and bitumen reservoirs is much more difficult than that from conventional oil reservoirs. This is mainly because heavy oil or bitumen is partially or completely immobile under reservoir conditions due to its extremely high viscosity, which creates special production challenges. In order to overcome these challenges significant efforts were devoted by Applied Research Center (ARC) at Florida International University and The Center for Energy Economics (CEE) at the University of Texas. A simplified model was developed to assess the density of the upgraded crude depending on the ratio of solvent mass to crude oil mass, temperature, pressure and the properties of the crude oil. The simplified model incorporated the interaction dynamics into a homogeneous, porous heavy oil reservoir to simulate the dispersion and concentration of injected CO2. The model also incorporated the characteristic of a highly varying CO2 density near the critical point. Since the major challenge in heavy oil recovery is its high viscosity, most researchers have focused their investigations on this parameter in the laboratory as well as in the field resulting in disparaging results. This was attributed to oil being a complex poly-disperse blend of light and heavy paraffins, aromatics, resins and asphaltenes, which have diverse behaviors at reservoir temperature and pressures. The situation is exacerbated by a dearth of experimental data on gas diffusion coefficients in heavy oils due to the tedious nature of diffusivity measurements. Ultimately, the viscosity and thus oil recovery is regulated by pressure and its effect on the diffusion coefficient and oil swelling factors. The generation of a new phase within the crude and the differences in mobility between the new crude matrix and the

[Imperial Oil's Cold Lake oil sands operations

International Nuclear Information System (INIS)

Dingle, H. B.

1999-01-01

Imperial Oil Limited's Cold Lake oil sands resources, production and operations in Alberta are discussed. Cold Lake is the company's largest single asset and its largest source of crude oil production. In 1998, Cold Lake accounted for just under half of Imperial's total liquid production, averaging more than 135,000 barrels of bitumen a day. Despite the very difficult operating conditions experienced by the oil sands industry in 1998, Imperial Oil's Cold Lake operations generated a positive cash flow and earnings. Just as important, the near and long-term potential of Cold Lake property continues to be strong, even with the tough market conditions today and the foreseeable future. Proved reserves at the end of 1997 were 1.3 billions barrels, equal to about 24 years of current production, but even more important is Imperial's resource base in the Athabasca region, which represents 150 years of production at current rates. Although production forecasts for the near future are are revised downward because of production shut-in due to low prices, the company is confident of its long-term prospects mainly because of existing infrastructure, superior reservoir quality, 30 years worth of operating improvements and established bitumen-blend markets. Details of the company's future Cold Lake development plans are discussed. The need to continue technology development, which has been at the core of the industry's growth in the past and will continue to be the key to the future, are emphasized

An experimental study on oil supply in a space bearing with an oil-impregnated retainer

Science.gov (United States)

Liu, Jianhai; Fan, Youwen; Wen, Shizhu

1993-06-01

Parched elastohydrodynamic lubrication (EHL) film thickness in a space ball bearing is measured by electrical capacitance and resistance, and parched transients of oil film and lubricant breakdown are observed. With different oil-impregnated polymer retainers, which are employed as oil supply resources, parched degradation is restricted to some degree, even lubricant breakdown disappears and a steady state of the oil film is produced. A long-term space bail bearing demands both the lowest driving torque and a steady state oil film, which depends on a strictly controlled oil supply from oil-impregnated retainers. The results of this experimental research describe the effects of oil supply by amounts of oil in retainers on parched EHL.

Competitiveness in the Brazilian oil industry. The Brazilian 'oil diamond'

International Nuclear Information System (INIS)

Zamith, R.; Moutinho Dos Santos, E.

2000-01-01

It is recognized the economic benefits that might follow the opening process of the Brazilian oil and natural gas industry, which shall experience a fast expansion with the arrival of national and international private investors. However, we should not neglect the broader impact of this process on the future development of all that cluster of national agents that lived around and served the former national oil monopoly, managed by the Brazilian National Oil Company, Petrobras. This work focuses on this larger perspective, discussing about the capacity of Brazil to sustain and expand its competitiveness in the oil business as well as to obtain the maximum economic development from the exploration of its oil and gas reserves. We adopt the work of Michael Porter, from the University of Harvard, about the Competitive Advantage of Nations, as a theoretical model to analyze the Competitive Advantage of Brazil in the global oil industry. By introducing the concept of ''oil diamond'', adapted from the notion introduced by this author, we develop a new understanding of national competitiveness in the oil sector. In this paper, we present the general model as well as a brief characterization of the results found for Brazil Subsequently, we focus on just one leg of the model, for which we discuss, with more detail, about the competitive condition of the country in the opening-up scenario. This leg regards the so-called supporting and supplementary industries that constitute what is denominated in the French tradition the ''para petroleum'' industry. We analyze the conditions for the Brazilian domestic ''para petroleum industry'' to survive and grow in the new competitive environment. (authors)

Applications of supercritical fluid extraction (SFE) of palm oil and oil from natural sources.

Science.gov (United States)

Akanda, Mohammed Jahurul Haque; Sarker, Mohammed Zaidul Islam; Ferdosh, Sahena; Manap, Mohd Yazid Abdul; Ab Rahman, Nik Norulaini Nik; Ab Kadir, Mohd Omar

2012-02-10

Supercritical fluid extraction (SFE), which has received much interest in its use and further development for industrial applications, is a method that offers some advantages over conventional methods, especially for the palm oil industry. SC-CO₂ refers to supercritical fluid extraction (SFE) that uses carbon dioxide (CO₂) as a solvent which is a nontoxic, inexpensive, nonflammable, and nonpolluting supercritical fluid solvent for the extraction of natural products. Almost 100% oil can be extracted and it is regarded as safe, with organic solvent-free extracts having superior organoleptic profiles. The palm oil industry is one of the major industries in Malaysia that provides a major contribution to the national income. Malaysia is the second largest palm oil and palm kernel oil producer in the World. This paper reviews advances in applications of supercritical carbon dioxide (SC-CO₂) extraction of oils from natural sources, in particular palm oil, minor constituents in palm oil, producing fractionated, refined, bleached, and deodorized palm oil, palm kernel oil and purified fatty acid fractions commendable for downstream uses as in toiletries and confectionaries.

RADARSAT SAR data assessment of oil lakes in the Greater Burgan Oil Field, Kuwait

International Nuclear Information System (INIS)

Kwarteng, A. Y.; Al-Ajmi, D.; Singhroy, V.; Saint-Jean, R.

1997-01-01

RADARSAT images recorded in different beam modes were processed and used to assess the oil lakes in the Burgan oil field in Kuwait created by the fire setting of oil wells by the retreating Iraqi forces in the 1990-1991 Gulf War. The images were geometrically registered to each other and used as input to a change detection program. The main interest was to map and differentiate between the oil lakes, tarmats, vegetation, buried oil lakes, and also to evaluate the usefulness of RADARSAT's beam modes in characterizing such features. Results of the RADARSAT imagery analysis were compared to similar studies using optical and SIR-C/X-SAR data. Initially, there have approximately 300 oil lakes covering an area of about 49 sq km. Twenty-one million barrels of oil were recovered and exported; about one million barrels of unrecoverable oil was left in the oil fields. Since then most of the oil has evaporated, dried up to form tarmats, or has been covered by a veneer of sand and is no longer visible on the surface

Applications of Supercritical Fluid Extraction (SFE of Palm Oil and Oil from Natural Sources

Directory of Open Access Journals (Sweden)

Mohd Omar Ab Kadir

2012-02-01

Full Text Available Supercritical fluid extraction (SFE, which has received much interest in its use and further development for industrial applications, is a method that offers some advantages over conventional methods, especially for the palm oil industry. SC-CO2 refers to supercritical fluid extraction (SFE that uses carbon dioxide (CO2 as a solvent which is a nontoxic, inexpensive, nonflammable, and nonpolluting supercritical fluid solvent for the extraction of natural products. Almost 100% oil can be extracted and it is regarded as safe, with organic solvent-free extracts having superior organoleptic profiles. The palm oil industry is one of the major industries in Malaysia that provides a major contribution to the national income. Malaysia is the second largest palm oil and palm kernel oil producer in the World. This paper reviews advances in applications of supercritical carbon dioxide (SC-CO2 extraction of oils from natural sources, in particular palm oil, minor constituents in palm oil, producing fractionated, refined, bleached, and deodorized palm oil, palm kernel oil and purified fatty acid fractions commendable for downstream uses as in toiletries and confectionaries.

Oil shale, shale oil, shale gas and non-conventional hydrocarbons

Directory of Open Access Journals (Sweden)

Clerici A.

2015-01-01

Full Text Available In recent years there has been a world “revolution” in the field of unconventional hydrocarbon reserves, which goes by the name of “shale gas”, gas contained inside clay sediments micropores. Shale gas finds particular development in the United States, which are now independent of imports and see a price reduction to less than one third of that in Europe. With the high oil prices, in addition to the non-conventional gas also “oil shales” (fine-grained sedimentary rocks that contain a large amount of organic material to be used both to be directly burned or to extract liquid fuels which go under the name of shale oil, extra heavy oils and bitumen are becoming an industrial reality. Both unconventional gas and oil reserves far exceed in the world the conventional oil and gas reserves, subverting the theory of fossil fuels scarcity. Values and location of these new fossil reserves in different countries and their production by comparison with conventional resources are presented. In view of the clear advantages of unconventional fossil resources, the potential environmental risks associated with their extraction and processing are also highlighted.

Gambling in the foothills

Energy Technology Data Exchange (ETDEWEB)

Greenway, R.

1997-05-01

Problems involved in drilling oil wells in the heavily thrusted and folded rocks in the foothills region of the Western Canadian Sedimentary Basin was discussed. Foothills wells cost an average of $4 to $7 million to drill and case. Wells are deep and difficult to drill because of the unique geology in the region. Drill bit control using the latest oilpatch technologies such as horizontal drilling and 3-D seismic is crucial to exploration success in this kind of terrain. Rocks in the sequences are typically shales and carbonates. Formation micro imager (FMI), which shows fractures and faults by measuring resistivity changes across the well bore is the tool of choice. The Geological Survey of Canada believes that a natural gas pool probably exists in the southern foothills that may be bigger than the Waterton Sheet III, the main complex of Shell Canada`s Waterton discovery made 40 years ago. Several oil companies have been involved in exploration, and the most extensive 3-D seismic program in Canadian history is currently ongoing in the area. Paradoxically, the foothills also contain some of the most popular recreational areas in the province, and not surprisingly, environmental groups are opposed to any kind of petroleum activity in the area. Nevertheless, companies like Suncor, Husky Oil, Amoco Canada, and Mobil are not deterred. Drilling in the foothills is expensive, and not without risks, but there is potential for significant rewards. 2 figs.

Tracking an oil slick from multiple natural sources, Coal Oil Point, California

International Nuclear Information System (INIS)

Leifer, Ira; Luyendyk, Bruce; Broderick, Kris

2006-01-01

Oil slicks on the ocean surface emitted from natural marine hydrocarbon seeps offshore from Coal Oil Point in the Santa Barbara Channel, California were tracked and sampled over a 2-h period. The objectives were to characterize the seep oil and to track its composition over time using a new sampling device, a catamaran drum sampler (CATDRUMS). The sampler was designed and developed at UCSB. Chromatograms showed that oil originating from an informally named, very active seep area, Shane Seep, primarily evolved during the first hour due to mixing with oil originating from a convergence zone slick surrounding Shane Seep. (author)

Tracking an oil slick from multiple natural sources, Coal Oil Point, California

Energy Technology Data Exchange (ETDEWEB)

Leifer, Ira [Marine Sciences Institute, University of California, Santa Barbara, CA 93106 (United States); Luyendyk, Bruce [Department of Geological Sciences, University of California, Santa Barbara, CA 93106 (United States); Broderick, Kris [Exxon/Mobil Exploration Company, 13401 N. Freeway, Houston, TX 77060 (United States)

2006-06-15

Oil slicks on the ocean surface emitted from natural marine hydrocarbon seeps offshore from Coal Oil Point in the Santa Barbara Channel, California were tracked and sampled over a 2-h period. The objectives were to characterize the seep oil and to track its composition over time using a new sampling device, a catamaran drum sampler (CATDRUMS). The sampler was designed and developed at UCSB. Chromatograms showed that oil originating from an informally named, very active seep area, Shane Seep, primarily evolved during the first hour due to mixing with oil originating from a convergence zone slick surrounding Shane Seep. (author)

The oil barrel price

International Nuclear Information System (INIS)

Blondy, J.; Papon, P.

2009-01-01

This paper proposes an overview and a prospective glance on the oil barrel price. It indicates the relevant indicators: Brent quotation, euro/dollar parity, economic activity indicators, world oil consumption distribution, crude oil production, refining capacity. It briefly presents the involved stake holders: crude oil producers, oil refiners, refined product dealers, and the OPEC. It discusses the major retrospective trends: evolution in relationship with geopolitical events and energy policies, strong correlation between oil demand and economic growth, prevalence of OPEC, growing importance of national oil companies. An emerging trend is noticed: growing role of emerging countries on the crude market. Some prospective issues are discussed: duration and intensity of economic recession, separation between economic growth and energy consumption, pace and ambition level of policies of struggle against climate change, exploitable resources, and geopolitical hazards. Four evolution hypotheses are discussed

Calendula oil processing : seed classification, oil extraction, refining process development and oil quality aspects

NARCIS (Netherlands)

Janssens, R.J.J.

2000-01-01

The difference in Calendula oil quality from fractions obtained after seed classification is enormous. The oil quality varies from excellent to very poor, according to important aspects such as in the hulls and dust fraction, high free fatty acid values (13% vs. 0.6%) are found. This can be

MICROWAVE HEATING AND SEPARATION OF WATER-IN-OIL EMULSION FROM MEXICAN CRUDE OIL

OpenAIRE

VAZQUEZ V., ADRIAN; LOPEZ M., ARTURO; ANDRADE C., LUIS J.; VAZQUEZ A., ARIANA M.

2014-01-01

Microwave heating and gravity sedimentation are alternatives for demulsification and layer separation into oil and water layers, this process was demonstrated in the laboratory and provides an option for reducing and oil recovering from water-in-oil Mexican oil emulsions. The combinatorial process was implemented in a test lab using Mexican crude oil samples. The Laboratory samples were 100% and 50-50%, crude and crude-water respectively, were heated. The results were encouraging show that mi...

Geopolitics of oil markets

International Nuclear Information System (INIS)

Liscom, W.L.

1991-01-01

Geopolitics can inject a great deal of uncertainty and cause fundamental shifts in the overall direction of oil markets, which would otherwise act in a fairly predictable and stable manner. The Iraqi invasion of Kuwait and the response of the USA were definitely linked with oil, and the aftermath of the invasion left four geopolitical issues affecting world oil markets. The provision authorizing $1.6 billion in Iraqi oil exports under the United Nations sanctions was imposed with little concern about the potential impact of these exports on the oil market; Iraq could export as much as 1 million bbl/d and it is unlikely that exports would be stopped once the $1.6 billion limit is reached. By making up most of the supply shortfall during the Kuwait crisis, Saudi Arabia suddenly became the producer of over a third of OPEC oil supplies and now dominates OPEC. The Saudis have indicated it will swing production according to world demand, irrespective of what OPEC wants, so that world oil demand will return strongly and remain. Middle East politics in general will determine the stability of oil supplies in the region for many of the countries. A producer-consumer dialogue at the high governmental level has started, with a view to some type of multilateral understanding in the light of mutual interests in secure oil supplies. This is not likely to have a big impact on oil markets without participation and support from the USA. The recent changes in the Soviet Union have potential impacts in regard to the attraction of that market for Western investment, in particular to assist exports. The worldwide environmental movement will also play a geopolitical role in the world oil market due to its influence on oil taxation policies

Manitoba oil activity review, 1996

International Nuclear Information System (INIS)

1997-01-01

This report is the annual review of Manitoba Crown oil and gas dispositions, mineral owner leasing and revenue, geophysical and drilling activity, areas of activity, oil production and markets, oil prices, value of production, provincial revenue from oil production, surface owners, spills and reclamation, municipal taxes, the Manitoba Drilling Incentive Program, oil reserves, oil industry expenditures, and industry employment. Highlights of the current year are included

Manitoba oil activity review, 1997

International Nuclear Information System (INIS)

1998-01-01

Annual review is presented of Manitoba Crown oil and gas dispositions, mineral owner leasing and revenue, geophysical and drilling activity, areas of activity, oil production and markets, oil prices, value of production, provincial revenue from oil production, surface owners, spills and reclamation, municipal taxes, the Manitoba Drilling Incentive Program, oil reserves, oil industry expenditures, and industry employment. Highlights of the current year are included

Manitoba oil activity review, 1995

International Nuclear Information System (INIS)

1996-01-01

This report is the annual review of Manitoba Crown oil and gas dispositions, mineral owner leasing and revenue, geophysical and drilling activity, areas of activity, oil production and markets, oil prices, value of production, provincial revenue from oil production, surface owners, spills and reclamation, municipal taxes, the Manitoba Drilling Incentive Program, oil reserves, oil industry expenditures, and industry employment. Highlights of the current year are included

The oil market. Call on OPEC determines the oil price

International Nuclear Information System (INIS)

Kingma, D.; Mulder, M.

2001-01-01

Several scenarios are applied to determine the oil price for the medium-long term, based on the so-called 'call on OPEC'. The 'call on OPEC' is part of the demand for oil which has to supplied by OPEC. It is expected that the nominal oil price will be circa $24 per barrel in 2004, based on a global growth of 4%. 2 refs

Allocation of multiple, widely spread oil spills associated with one polluter : GC-MS fingerprinting and diagnostic ratios of spilled oil and oiled seabirds

International Nuclear Information System (INIS)

Hansen, A.B.; Avnskjold, J.

2005-01-01

In January 2005, a Cypriot cargo ship leaked about 5 tons of heavy fuel bunker oil in Kerteminde Bay in the Great Belt, Denmark. The ship was stopped to inspect and collect oil samples from its 2 damaged tanks for forensic oil spill identification by gas chromatography and mass spectrometry. Two weeks following the accident, a series of waterborne and stranded oil spills showed up in the Great Belt area, north and south of the vessel's route. Thousands of oiled seabirds on small islands and coastlines were affected. The Danish Coast Guard suspected that the vessel might be responsible for the observed spills. More than 50 oil samples were collected and sent for forensic analysis at the National Environmental Research Institute. Both waterborne and stranded spill samples showed an almost perfect match of diagnostic ratios and chromatograph with the potential responsible party (PRP) bunker. The spill samples therefore matched the reference oil and were allocated to the spill associated with the Cypriot cargo ship. One sample deviated significantly from the other samples and was not allocated to the ship's accidental spill. Oil samples collected from oiled seabirds showed larger variations between diagnostic ratios and the reference bunker oils. The variations can be attributed to weathering and biodegradation, but also to contamination by non-petrogenic material. It was concluded that the oiled seabirds represented non-match samples that cannot be allocated to the oil spill associated with the Cypriot cargo ship. 14 refs., 3 tabs., 4 figs

Oil goldenberry (Physalis peruviana L.).

Science.gov (United States)

Ramadan, Mohamed F; Mörsel, Jörg-T

2003-02-12

Whole berries, seeds, and pulp/peel of goldenberry (Physalis peruviana L.) were compared in terms of fatty acids, lipid classes, triacylglyerols, phytosterols, fat-soluble vitamins, and beta-carotene. The total lipid contents in the whole berries, seeds, and seedless parts were 2.0, 1.8, and 0.2% (on a fresh weight basis), respectively. Linoleic acid was the dominating fatty acid followed by oleic acid as the second major fatty acid. Palmitic and stearic acids were the major saturates. In pulp/peel oil, the fatty acid profile was characterized by higher amounts of saturates, monoenes, and trienes than in whole berry and seed oils. Neutral lipids comprised >95% of total lipids in whole berry oil and seed oil, while neutral lipids separated in lower level in pulp/peel oil. Triacylglycerols were the predominant neutral lipid subclass and constituted ca. 81.6, 86.6, and 65.1% of total neutral lipids in whole berry, seed, and pulp/peel oils, respectively. Nine triacylglycerol molecular species were detected, wherein three species, C54:3, C52:2, and C54:6, were presented to the extent of approximately 91% or above. The highest level of phytosterols was estimated in pulp/peel oil that contained the highest level of unsaponifiables. In both whole berry and seed oils, campesterol and beta-sitosterol were the sterol markers, whereas Delta5-avenasterol and campesterol were the main 4-desmethylsterols in pulp/peel oil. The tocopherols level was much higher in pulp/peel oil than in whole berry and seed oils. beta- and gamma-tocopherols were the major components in whole berry and seed oils, whereas gamma- and alpha-tocopherols were the main constituents in pulp/peel oil. beta-Carotene and vitamin K(1) were also measured in markedly high levels in pulp/peel oil followed by whole berry oil and seed oil, respectively. Information provided by the present work is of importance for further chemical investigation of goldenberry oil and industrial utilization of the berries as a raw

Treating hydrocarbon oils

Energy Technology Data Exchange (ETDEWEB)

Scott, R; MacIvor, W

1869-09-01

The treatment of hydrocarbon oils, such as coal or shale oils, paraffin oils, and petroleum, either in the crude or more or less refined state has the object of reducing the specific gravity and otherwise improving the qualities of such oils. The oil to be treated is put into any ordinary still and distilled. The vapor escaping during the distillation is passed through one or more heating vessels or chambers and exposed to the heat necessary to produce the change. The heating vessels or chambers may be made of metal, clay, or any other material adapted to endure heat, and they may be made of any desired form, or they may be constituted of a coil of metal pipes or a series of tubes such as are used for heating air for blast furnaces.

Oil sands supply outlook

International Nuclear Information System (INIS)

Dunbar, R.

2004-01-01

In March 2004, The Canadian Energy Research Institute released a report on the expected future supply from Alberta's oil sands. The report indicates that the future for the already well-established oil sands industry is promising, particularly given the outlook for oil prices. The challenges facing the industry include higher industry supply costs and the need for innovative commercial and technological solutions to address the risks of irregularities and changes in crude oil prices. In 2003, the industry produced 874 thousand barrels per day of synthetic crude oil and unprocessed crude bitumen. This represents 35 per cent of Canada's total oil production. Current production capacity has increased to 1.0 million barrels per day (mbpd) due to new projects. This number may increase to 3.5 mbpd by 2017. Some new projects may be deferred due to the higher raw bitumen and synthetic crude oil supply costs. This presentation provided supply costs for a range of oil sands recovery technologies and production projections under various business scenarios. tabs., figs

Oil supply on demand: Oil pumps in serial application; Bedarfsgerechte Oelversorgung: Regeloelpumpen im Serieneinsatz

Energy Technology Data Exchange (ETDEWEB)

Lamparski, C. [S H W Automotive GmbH und Co. KG, Bad Schussenried (Germany)

2007-07-01

Usually, constant displacement oil pumps are used for the oil supply of combustion engines. Gerotor, helical or spur gear pumps or vane pumps are the most common solutions. The disadvantage of the mentioned design is the oil delivery as function of pump speed, independent from the engine needs. Variability of oil delivery for reduction of hydraulic losses is the logical consequence. The first variable displacement oil pump which has fulfilled this requirement is the Internal Regulated Oil Pump (IRP). The mass production of this oil pump started in 2002. The solution for outer gear pumps and vane cells followed shortly. The following contribution gives a summary of different technical concepts for adjusting of oil delivery, beginning with pump pressure as a leading value till map regulation and its transformation in mass production products. (orig.)

Outlook for Saskatchewan heavy oil

International Nuclear Information System (INIS)

Youzwa, P.

1993-01-01

Some of the opportunities and challenges currently facing the heavy oil industry in Saskatchewan are discussed from a government perspective. By the end of September 1993, 220 heavy oil wells were drilled in the province, and 26% of the land sales in 1993 were in heavy oil areas. About 41% of the wells drilled in heavy oil areas were horizontal oil wells. Of the total horizontal wells drilled in Saskatchewan, 48% are for heavy oil, and horizontal well production averages 85 bbl/d. Initial trends suggest that horizontal wells both accelerate production and contribute to ultimate recovery. Total heavy oil production in 1992 reached 28.9 million bbl and recoverable reserves in 1991 were 262.3 million bbl, or 1.5% of total oil in place. The low recovery is not only due to technical factors such as high viscosity but also to low investment in the heavy oil sector due to poor economics. It is hoped that lower interest and exchange rates, the success of horizontal wells and the provincial royalty structure will maintain the recent increase in heavy oil activity. The provincial government recently launched a comprehensive energy strategy in which development of a heavy oil strategy is an important component. Total heavy oil reserves exceed those of light and medium oil and have significant development potential. The Saskatchewan government wishes to adopt a cooperative and partnership approach in its dealings with the heavy oil industry to help realize this potential. 9 figs

Oil production, oil prices, and macroeconomic adjustment under different wage assumptions

International Nuclear Information System (INIS)

Harvie, C.; Maleka, P.T.

1992-01-01

In a previous paper one of the authors developed a simple model to try to identify the possible macroeconomic adjustment processes arising in an economy experiencing a temporary period of oil production, under alternative wage adjustment assumptions, namely nominal and real wage rigidity. Certain assumptions were made regarding the characteristics of actual production, the permanent revenues generated from that oil production, and the net exports/imports of oil. The role of the price of oil, and possible changes in that price was essentially ignored. Here we attempt to incorporate the price of oil, as well as changes in that price, in conjunction with the production of oil, the objective being to identify the contribution which the price of oil, and changes in it, make to the adjustment process itself. The emphasis in this paper is not given to a mathematical derivation and analysis of the model's dynamics of adjustment or its comparative statics, but rather to the derivation of simulation results from the model, for a specific assumed case, using a numerical algorithm program, conducive to the type of theoretical framework utilized here. The results presented suggest that although the adjustment profiles of the macroeconomic variables of interest, for either wage adjustment assumption, remain fundamentally the same, the magnitude of these adjustments is increased. Hence to derive a more accurate picture of the dimensions of adjustment of these macroeconomic variables, it is essential to include the price of oil as well as changes in that price. (Author)

Oil prices, fiscal policy, and economic growth in oil-exporting countries

Science.gov (United States)

El-Anshasy, Amany A.

This dissertation argues that in oil-exporting countries fiscal policy could play an important role in transmitting the oil shocks to the economy and that the indirect effects of the changes in oil prices via the fiscal channel could be quite significant. The study comprises three distinct, yet related, essays. In the first essay, I try to study the fiscal policy response to the changes in oil prices and to their growing volatility. In a dynamic general equilibrium framework, a fiscal policy reaction function is derived and is empirically tested for a panel of 15 oil-exporters covering the period 1970--2000. After the link between oil price shocks and fiscal policy is established, the second essay tries to investigate the impact of the highly volatile oil prices on economic growth for the same sample, controlling for the fiscal channel. In both essays the study employs recent dynamic panel-data estimation techniques: System GMM. This approach has the potential advantages of minimizing the bias resulting from estimating dynamic panel models, exploiting the time series properties of the data, controlling for the unobserved country-specific effects, and correcting for any simultaneity bias. In the third essay, I focus on the case of Venezuela for the period 1950--2001. The recent developments in the cointegrating vector autoregression, CVAR technique is applied to provide a suitable framework for analyzing the short-run dynamics and the long-run relationships among oil prices, government revenues, government consumption, investment, and output.

Shoreline oiling conditions in Prince William Sound following the Exxon Valdez oil spill

International Nuclear Information System (INIS)

Neff, J.M.; Owens, E.H.; Stoker, S.W.; McCormick, D.M.

1995-01-01

Following the Exxon Valdez oil spill of March 24, 1989, in Prince William Sound, Alaska, Exxon conducted comprehensive, systematic shoreline surveys in cooperation with federal and state authorities to obtain information on the distribution and magnitude of shoreline oiling and to identify natural and cultural resources requiring special protection. Similar joint surveys were performed during the springs of 1990, 1991, and 1992 on all Prince william Sound and Gulf of Alaska shorelines that were suspected of having remnants of weathered oil and that would benefit from further cleanup. In the springs of 1990, 1991, and 1992, isolated pockets of subsurface oil were found, chiefly in small scattered zones in coarse cobble/boulder sediments in the upper intertidal or supratidal zones. In 1991, about one-third of the subdivisions in Prince William Sound with surface oil also contained some subsurface oil. The areal extent of this subsurface oil declined by nearly 70% between 1991 and 1992, from about 37,000 m 2 to about 12,000 m 2 . Moreover, where subsurface oil remained in 1992, it was present in lesser amounts. Rates of oil removal were greatest on coastal sections treated early in the spring and summer of 1989. Where shoreline treatment was delayed, the subsequent rate of removal of oil from the shore by natural processes was slower. 27 refs., 10 figs., 3 tabs

Recovery of hydrocarbon oils

Energy Technology Data Exchange (ETDEWEB)

1941-02-10

A process is disclosed for recovery of hydrocarbon oils, especially lubricating oils or diesel oils, through pressure hydrogenation of distillation, extraction of hydrogenation products from coal or coaly materials or from oils such as mineral oils or tars in liquid phase by use in a reaction vessel of fixed-bed catalysts, characterized in that as starting material is employed material which has been freed of asphaltic and resinous material by hydrogenation refining, vacuum-steam distillation, treatment with hydrogen-rich hydrocarbons (hydroforming), or sulfuric acid.

Bulk oil clauses

International Nuclear Information System (INIS)

Gough, N.

1993-01-01

The Institute Bulk Oil Clauses produced by the London market and the American SP-13c Clauses are examined in detail in this article. The duration and perils covered are discussed, and exclusions, adjustment clause 15 of the Institute Bulk Oil Clauses, Institute War Clauses (Cargo), and Institute Strikes Clauses (Bulk Oil) are outlined. (UK)

Economic effects of peak oil

International Nuclear Information System (INIS)

Lutz, Christian; Lehr, Ulrike; Wiebe, Kirsten S.

2012-01-01

Assuming that global oil production peaked, this paper uses scenario analysis to show the economic effects of a possible supply shortage and corresponding rise in oil prices in the next decade on different sectors in Germany and other major economies such as the US, Japan, China, the OPEC or Russia. Due to the price-inelasticity of oil demand the supply shortage leads to a sharp increase in oil prices in the second scenario, with high effects on GDP comparable to the magnitude of the global financial crises in 2008/09. Oil exporting countries benefit from high oil prices, whereas oil importing countries are negatively affected. Generally, the effects in the third scenario are significantly smaller than in the second, showing that energy efficiency measures and the switch to renewable energy sources decreases the countries' dependence on oil imports and hence reduces their vulnerability to oil price shocks on the world market. - Highlights: ► National and sectoral economic effects of peak oil until 2020 are modelled. ► The price elasticity of oil demand is low resulting in high price fluctuations. ► Oil shortage strongly affects transport and indirectly all other sectors. ► Global macroeconomic effects are comparable to the 2008/2009 crisis. ► Country effects depend on oil imports and productivity, and economic structures.

Chemically evolving systems for oil recovery enhancement in heavy oil deposits

Science.gov (United States)

Altunina, L. K.; Kuvshinov, I. V.; Kuvshinov, V. A.; Stasyeva, L. A.

2017-12-01

This work presents the results of laboratory studies and field tests of new physicochemical technologies for enhanced oil recovery of heavy oil fields under natural development conditions and with thermal-steam stimulation using oil-displacing "smart" systems. The systems are based on surfactants and buffer systems. Their rheological and acid-base properties can be regulated by their chemical evolution directly in the formation. Field tests of the technologies carried out on high-viscosity oil deposit in the Usinskoye oilfield have shown that the EOR technologies are environmentally friendly and technologically effective.

Features and application of amino acid oil gelatinizer for controlling oil spills on the sea

Energy Technology Data Exchange (ETDEWEB)

Uemura, Hiroyuki

1987-10-01

Diffusion of oil spills is prevented and the oil can be easily recovered if it is solidified. Features and application of gelling agent for amino acid series oil are introduced. The gelatinizer for amino acid is made of amino acid derivative with solvent added thereto so that oil can be gelatinized by mere spraying of the agent over oil spills. The agent can be intermixed with oil because it floats on the sea. Oil spill is gelatinized instantly and diffusion of the oils is prevented. The oil can easily be recovered with a fishing net and the like. The influence of oil spills to living aquatic resources is greatly lessened, and the gel is safe for workers. It can gelatinize everything except alcohol. Gelatinization has the depressor effect for volatization and is effective for the prevention of fire. The gelatized oil can be burnt up although it contains 10-20 % of water. Oil film on the water can be completely controlled when the agent is sprayed over it. It contributes to the purification of nature since it is readily decomposed. (1 fig, 4 tabs, 3 refs)

Deceased Slabs Drive Oil

Science.gov (United States)

Stein, H. J.; Hannah, J. L.

2017-12-01

The application of Re-Os isotope geochemistry to dating single oils is a nascent field [1,2]. Challenges include dissection of oils into asphaltene-maltene (ASPH-MALT) components in a way that preserves meaningful chronologic and source information. Significantly, oil-water mixing rapidly transfers Os to the oil, while Re exchange is sluggish [3]. The Os initial ratio of the oil is shifted in the direction of Os carried in the aqueous fluid, whereas the Re-Os isotopic age is preserved. We show that this phenomenon is operative in natural systems. Further, we show that deserpentinization of old oceanic slabs [4], may be linked to expulsion of Os-enriched waters into overlying sedimentary sections - a process that may be of fundamental importance for oil generation. This conclusion does not diminish the role of traditional organic-rich shales as source rocks for the hydrocarbon, but shows that external fluids are essential to petroleum generation. Moreover, the external fluids may be an important driver for expulsion and migration of oils. We have taken apart several petroleum systems from source rock, to residual oil, to tar mat development, to in situ live oil, through to produced oil. In many cases, a fluid with low 187Os/188Os - unlike that of normal basinal brines - provides a critical component to the oil-water mixture. Funding - CHRONOS project supported by Norwegian petroleum industry (Eni-Norge, Lundin, Aker BP) Acknowledgement - Christine Fichler [4], who first queried us on old slabs and oil, and stimulated ideas. [1] Georgiev, S.V., Stein, H.J., Hannah, J.L., Galimberti, R., Nali, M., Yang, G., and Zimmerman, A. (2016) Re-Os dating of maltenes and asphaltenes within single samples of crude oil: Geochim. Cosmochim. Acta 179: 53-75. [doi.org/10.1016/j.gca.2016.01.016] [2] DiMarzio, J., Georgiev, S.V., Stein, H.J., and Hannah, J.L. (in press) Residency of rhenium and osmium in a heavy crude oil: Geochim. Cosmochim. Acta. [3] Hurtig, N.C., Georgiev, S

Thermal Cracking of Jatropha Oil with Hydrogen to Produce Bio-Fuel Oil

Directory of Open Access Journals (Sweden)

Yi-Yu Wang

2016-11-01

Full Text Available This study used thermal cracking with hydrogen (HTC to produce bio-fuel oil (BFO from jatropha oil (JO and to improve its quality. We conducted HTC with different hydrogen pressures (PH2; 0–2.07 MPa or 0–300 psig, retention times (tr; 40–780 min, and set temperatures (TC; 623–683 K. By applying HTC, the oil molecules can be hydrogenated and broken down into smaller molecules. The acid value (AV, iodine value, kinematic viscosity (KV, density, and heating value (HV of the BFO produced were measured and compared with the prevailing standards for oil to assess its suitability as a substitute for fossil fuels or biofuels. The results indicate that an increase in PH2 tends to increase the AV and KV while decreasing the HV of the BFO. The BFO yield (YBFO increases with PH2 and tr. The above properties decrease with increasing TC. Upon HTC at 0.69 MPa (100 psig H2 pressure, 60 min time, and 683 K temperature, the YBFO was found to be 86 wt%. The resulting BFO possesses simulated distillation characteristics superior to those of boat oil and heavy oil while being similar to those of diesel oil. The BFO contains 15.48% light naphtha, 35.73% heavy naphtha, 21.79% light gas oil, and 27% heavy gas oil and vacuum residue. These constituents can be further refined to produce gasoline, diesel, lubricants, and other fuel products.

Petroleum Oils

Science.gov (United States)

Different types of crude oil and refined product, of all different chemical compositions, have distinct physical properties. These properties affect the way oil spreads and breaks down, its hazard to marine and human life, and the likelihood of threat.

Slow oil shocks and the 'weakening of the oil price-macroeconomy relationship'

International Nuclear Information System (INIS)

Naccache, Theo

2010-01-01

Many papers have been documenting and analysing the asymmetry and the weakening of the oil price-macroeconomy relationship as off the early eighties. While there seems to be a consensus about the factors causing the asymmetry, namely adjustment costs which offset the benefits of low energy prices, the debate about the weakening of the relationship is not over yet. Moreover, the alternative oil price specifications which have been proposed by, and to restore the stability of the relationship fail to Granger cause output or unemployment in post-1980 data. By using the concept of accelerations of the oil price, we show that the weakening of this relationship corresponds to the appearance of slow oil price increases, which have less impact on the economy. When filtering out these slow oil price variations from the sample, we manage to rehabilitate the causality running from the oil price to the macroeconomy and show that far from weakening, the oil price accelerations-GDP relationship has even been growing stronger since the early eighties. (author)

Have we run out of oil yet? Oil peaking analysis from an optimist's perspective

International Nuclear Information System (INIS)

Greene, David L.; Hopson, Janet L.; Li Jia

2006-01-01

This study addresses several questions concerning the peaking of conventional oil production from an optimist's perspective. Is the oil peak imminent? What is the range of uncertainty? What are the key determining factors? Will a transition to unconventional oil undermine or strengthen OPEC's influence over world oil markets? These issues are explored using a model combining alternative world energy scenarios with an accounting of resource depletion and a market-based simulation of transition to unconventional oil resources. No political or environmental constraints are allowed to hinder oil production, geological constraints on the rates at which oil can be produced are not represented, and when USGS resource estimates are used, more than the mean estimate of ultimately recoverable resources is assumed to exist. The issue is framed not as a question of 'running out' of conventional oil, but in terms of the timing and rate of transition from conventional to unconventional oil resources. Unconventional oil is chosen because production from Venezuela's heavy-oil fields and Canada's Athabascan oil sands is already underway on a significant scale and unconventional oil is most consistent with the existing infrastructure for producing, refining, distributing and consuming petroleum. However, natural gas or even coal might also prove to be economical sources of liquid hydrocarbon fuels. These results indicate a high probability that production of conventional oil from outside of the Middle East region will peak, or that the rate of increase of production will become highly constrained before 2025. If world consumption of hydrocarbon fuels is to continue growing, massive development of unconventional resources will be required. While there are grounds for pessimism and optimism, it is certainly not too soon for extensive, detailed analysis of transitions to alternative energy sources

Comparative toxicity test of water-accommodated fractions of oils and oil dispersants to marine organisms

International Nuclear Information System (INIS)

1989-01-01

This reference method describes a simple procedure for comparing the toxicity of oil, oil dispersants, and mixtures thereof, to marine animals. It allows the toxicity of different dispersants to be rapidly compared to that of oil, or of a mixture of oil an oil dispersant. It is designed for routine monitoring and screening purposes and is not appropriate as a research method. The physical and chemical properties of oil dispersants create many difficulties in the measurements of their toxicity to marine organisms. Strictly speaking, their toxicity can only be accurately estimated using complex procedures and apparatus. (A relatively simple apparatus for preparing oil/water or oil/water/oil dispersant emulsions is described in Appendix B). Simpler methods can provide useful information, provided their limitations are clearly understood and taken into consideration in the assessment and application of their results. Some of the special considerations relating to the measurement of the toxicity of oil and oil dispersants are described in Appendix A. The Appendix also explains the rationale and limitations of the method described here. 3 refs, 4 figs, 2 tabs

New round for oil

International Nuclear Information System (INIS)

Delamarche, Myrtille

2018-01-01

After three years of crisis, oil companies are now strongly reinvesting, while oil prices are stabilizing at a reasonable long-term level, notably due to a rising demand from developing countries. Examples of new investments made by majors such as Total, Shell or Exxon but also by national companies and junior companies, are given. Oil price evolution as well as cost reductions (thanks notably to the digitalisation of the sector, leading to a decrease in exploration costs) are analyzed. The importance of the US oil production, and particularly shale oil production, is pinpointed

Bio-oil fractionation and condensation

Science.gov (United States)

Brown, Robert C; Jones, Samuel T; Pollard, Anthony

2013-07-02

A method of fractionating bio-oil vapors which involves providing bio-oil vapors comprising bio-oil constituents is described. The bio-oil vapors are cooled in a first stage which comprises a condenser having passages for the bio-oil separated by a heat conducting wall from passages for a coolant. The coolant in the condenser of the first stage is maintained at a substantially constant temperature, set at a temperature in the range of 75 to 100.degree. C., to condense a first liquid fraction of liquefied bio-oil constituents in the condenser of the first stage. The first liquid fraction of liquified bio-oil constituents from the condenser in the first stage is collected. Also described are steps for subsequently recovering further liquid fractions of liquefied bio-oil constituents. Particular compositions of bio-oil condensation products are also described.

Biodegradability of northern crude oil

Energy Technology Data Exchange (ETDEWEB)

Cook, F D; Westlake, D W.S.

1976-01-01

Field studies on the microbiological degradation of crude oils encompassed the placing of oil-soaked plots in two areas in the Northwest Territories and Alberta. Replicate plots received amendments of fertilizer, oil-utilizing bacteria, fertilizer plus bacteria or were untreated except for the oil. Changes in microbial numbers and chemical composition of recovered oil were determined periodically. The initial stimulatory effect on bacterial numbers brought about by the addition of fertilizers to oil-soaked plots diminished two years after the application to a point where the differences were no longer significant. Experiments carried out in the Norman Wells area to determine the effect of the amount of fertilizer applied on oil degradation have yielded inconclusive results. The data suggest that at least 2.7 kg of urea-phosphate fertilizer per kl of oil is required to maintain a reasonable oil degradation rate. Preliminary studies on the use of fertilizer coated with chemicals to increase its hydrophobic character indicate that they could be useful in treating wet-land oil spills. Soils from the McKenzie River drainage basin indicate that bacteria are present which can use oil under mesophilic conditions. However, the ability to use the same oil under psychrophilic conditions is more restricted. At least one bacterial species from each mixed population studied was capable of bringing about chemical changes in oil similar to those observed for the original mixed culture. The potential hazards and uses of the seeding of oil spills is discussed relative to the environmental conditions found in the northern part of Canada. 35 refs., 2 figs., 15 tabs.

Oil use and oil dependency: Long-term issues

International Nuclear Information System (INIS)

Serot, D.E.; Belzer, D.B.; Guthrie, S.A.; Roop, J.M.

1989-06-01

The continued dependence of the United States on imported oil is a matter of increasing concern. Under the direction of the Department of Energy's Office of Policy Integration, Pacific Northwest Laboratory conducted a study which was to examine long-term issues related to oil dependence. Major issues addressed are (1) energy efficiency and the role of new technologies, (2) fuel switching, and (3) regional factors affecting fuel use. The study examines all major end-use sectors in the economy, covering the industrial, commercial, residential, transportation, and electric utility sectors. The potential impacts of efficiency improvements in oil- using equipment are assessed through the year 2000. 107 refs., 8 figs., 9 tabs

Effects of dietary conjugated linoleic acid, fish oil and soybean oil on ...

African Journals Online (AJOL)

Dear User!

2013-12-18

Dec 18, 2013 ... The chickens fed diets containing palm oil, soybean oil or fish oil as the ... polyunsaturated fatty acids; LDL, low density lipoprotein; HDL, .... content of muscles in broilers fed different dietary CLA levels. Javadi et al. (2007) ...

Internal features, mineralogy and geochemistry of ferromanganese nodules from the Gulf of Cadiz: The role of the Mediterranean Outflow Water undercurrent

Science.gov (United States)

González, F. J.; Somoza, L.; Lunar, R.; Martínez-Frías, J.; Rubí, J. A. Martín; Torres, T.; Ortiz, J. E.; Díaz-del-Río, V.

2010-03-01

A large suite of Fe-Mn nodules (561 samples) were recovered during the Anastasya2001 cruise (TASYO project) along the continental margin of the Gulf of Cadiz (Eastern Central Atlantic), at the confluence of the Mediterranean Sea with the Atlantic Ocean, where extensive nodule fields were discovered. Based on wide previous studies that included swath bathymetry, multi-channel and very high-resolution seismic reflection, gravimetry, magnetism, heat flow probes and underwater photography surveys, nodules were collected at water depths ranging from 850 to 1000 m, associated with hydrocarbon-derived Mg-calcite, ankerite and dolomite chimneys and crusts. Forty-six selected samples among the various morphological types were used for the laboratory analysis of physical properties (morphology, color, surface texture, sphericity, weight and size), mineralogy (XRD, optical and electronic microscopy), geochemistry (XRF, AAS, ICP-MS, ICP-AES, EPMA, and GC-MS) and stable isotopes. The nodules show a wide range of sizes, densities, weights and morphologies. They are formed by multiple millimeter-thick layers of Fe and Mn oxyhydroxides surrounding the nucleus composed of Early-Middle Miocene plastic marl and sediment, which were derived from underlying units by fluid venting. Massive, laminated, detrital and mottled to dendritic textural features were developed by the Fe and Mn oxyhydroxide layers. The main components are Goethite, lepidocrocite, Mn oxides (7 Å manganates and 10 Å manganates), quartz, and phyllosilicates. Accessory minerals are calcite, dolomite, siderite, rhodochrosite, kutnahorite, pyrite, chalcopyrite, potassium feldspar, zircon, rutile, ilmenite and chlorite. Fe-Mn carbonates from the siderite-rhodochrosite continuous series are the principal constituent of the nuclei. Framboidal, filamentous and globular textures are observed in Fe-Mn oxides and pyrite, suggesting biogenic origin. The nodules show a high mean abundance of Fe (38.6%), moderate Mn (6.0%) and

Distilling hydrocarbon oils

Energy Technology Data Exchange (ETDEWEB)

Schulze, J E

1923-03-19

In distilling mineral oils such as petroleum, shale oil, distillates and topped or residual oils, particularly to obtain lubricating oils, the distillation is carried out under reduced pressures below an absolute pressure of 25 mm. of mercury and preferably below about 5 mm. of mercury, and the distillate is collected in fractions determined by the physical characteristics, such as viscosity, flash point, fire point, etc. Superheated steam may be passed through the liquid during distillation. A horizontal cylindrical still provided with cross braces and peripheral ribs interrupted at the base is connected through a condensing coil immersed in a steam chest and a baffled chamber with distillate receiver and is evacuated by a pump. Steam from a boiler and superheater is injected into the still through a perforated pipe. Steam and light oil vapors passing from the chamber are condensed in a coil.

OPEC's optimal crude oil price

International Nuclear Information System (INIS)

Horn, Manfred

2004-01-01

OPEC decided to stabilise oil prices within a range of 22-28 US Dollar/barrel of crude oil. Such an oil-price-level is far beyond the short and long run marginal costs of oil production, beyond even that in regions with particularly high costs. Nevertheless, OPEC may achieve its goal if world demand for oil increases substantially in the future and oil resources outside the OPEC are not big enough to accordingly increase production. In this case OPEC, which controls about 78% of world oil reserves, has to supply a large share of that demand increase. If we assume OPEC will behave as a partial monopolist on the oil market, which takes into consideration the reaction of the other producers to its own sales strategy, it can reach its price target. Lower prices before 2020 are probable only if the OPEC cartel breaks up. Higher prices are possible if production outside OPEC is inelastic as assumed by some geologists, but they would probably stimulate the production of unconventional oil based on oil sand or coal. Crude oil prices above 30 US Dollar/barrel are therefore probably not sustainable for a long period. (Author)

Oil market prices 1989/1990

International Nuclear Information System (INIS)

Jenkins, G.

1991-01-01

There are many oil markets. Oil Market Prices lists the markets, provides statistics on prices and the volumes of trade, analyses the price structures in the markets and provides supplementary information on ocean freight rates and oil refining margins. Oil Market Prices will serve as a permanent record of crude oil prices including those quoted on the futures and forward markets, the many wholesale prices for refined oil products, prices consumers pay and the average prices received by the oil companies. In all instances the sources of the statistics are given together with comprehensive listing of alternative sources. (Author)

Chemical profiling of gaharu oil

International Nuclear Information System (INIS)

Mat Rasol Awang; Mohd Fajri Osman; Ahsanulkhaliqin Abd Wahab; Khairuddin Abdul Rahim; Shaiful Azuar Mohamad

2006-01-01

Gaharu oil from Aquilaria agallocha and Aquilaria malaccensis Lamk has been reported to contain different phytochemicals components (Ishihara et al., 1993). There are also differences reported by gaharu oil suppliers. The differences suggested they originate from varied of sources of gaharu wood, oleoresin maturity and extraction technology employed. In this study, gaharu oil purchased from different sources were initially analysed and later cross-examined against chemical components of oil extracted from wood sources systematically graded. The gaharu oil components obtained from this work will be presented and discussed. Initiative to profile oil provides impetus to database development and standardisation of gaharu oil. (Author)

Renoprotective effect of virgin coconut oil in heated palm oil diet-induced hypertensive rats.

Science.gov (United States)

Kamisah, Yusof; Ang, Shu-Min; Othman, Faizah; Nurul-Iman, Badlishah Sham; Qodriyah, Hj Mohd Saad

2016-10-01

Virgin coconut oil, rich in antioxidants, was shown to attenuate hypertension. This study aimed to investigate the effects of virgin coconut oil on blood pressure and related parameters in kidneys in rats fed with 5-times-heated palm oil (5HPO). Thirty-two male Sprague-Dawley rats were divided into 4 groups. Two groups were fed 5HPO (15%) diet and the second group was also given virgin coconut oil (1.42 mL/kg, oral) daily for 16 weeks. The other 2 groups were given basal diet without (control) and with virgin coconut oil. Systolic blood pressure was measured pre- and post-treatment. After 16 weeks, the rats were sacrificed and kidneys were harvested. Dietary 5HPO increased blood pressure, renal thiobarbituric acid reactive substance (TBARS), and nitric oxide contents, but decreased heme oxygenase activity. Virgin coconut oil prevented increase in 5HPO-induced blood pressure and renal nitric oxide content as well as the decrease in renal heme oxygenase activity. The virgin coconut oil also reduced the elevation of renal TBARS induced by the heated oil. However, neither dietary 5HPO nor virgin coconut oil affected renal histomorphometry. In conclusion, virgin coconut oil has a potential to reduce the development of hypertension and renal injury induced by dietary heated oil, possibly via its antioxidant protective effects on the kidneys.

Floating Oil-Spill Containment Device

Science.gov (United States)

Jones, Jack A.

2012-01-01

Previous oil containment booms have an open top that allows natural gas to escape, and have significant oil leakage due to wave action. Also, a subsea pyramid oil trap exists, but cannot move relative to moving oil plumes from deepsea oil leaks. The solution is to have large, moveable oil traps. One version floats on the sea surface and has a flexible tarp cover and a lower weighted skirt to completely entrap the floating oil and natural gas. The device must have at least three sides with boats pulling at each apex, and sonar or other system to track the slowly moving oil plume, so that the boats can properly locate the booms. The oil trap device must also have a means for removal of the oil and the natural gas. A second design version has a flexible pyramid cover that is attached by lines to ballast on the ocean floor. This is similar to fixed, metal pyramid oil capture devices in the Santa Barbara Channel off the coast of California. The ballast lines for the improved design, however, would have winches that can move the pyramid to always be located above the oil and gas plume. A third design is a combination of the first two. It uses a submerged pyramid to trap oil, but has no anchor and uses boats to locate the trap. It has ballast weights located along the bottom of the tarp and/or at the corners of the trap. The improved floating oil-spill containment device has a large floating boom and weighted skirt surrounding the oil and gas entrapment area. The device is triangular (or more than three sides) and has a flexible tarp cover with a raised gas vent area. Boats pull on the apex of the triangles to maintain tension and to allow the device to move to optimum locations to trap oil and gas. The gas is retrieved from a higher buoyant part of the tarp, and oil is retrieved from the floating oil layer contained in the device. These devices can be operated in relatively severe weather, since waves will break over the devices without causing oil leaking. Also, natural

Advances in biofuel production from oil palm and palm oil processing wastes: A review

Directory of Open Access Journals (Sweden)

Jundika C. Kurnia

2016-03-01

Full Text Available Over the last decades, the palm oil industry has been growing rapidly due to increasing demands for food, cosmetic, and hygienic products. Aside from producing palm oil, the industry generates a huge quantity of residues (dry and wet which can be processed to produce biofuel. Driven by the necessity to find an alternative and renewable energy/fuel resources, numerous technologies have been developed and more are being developed to process oil-palm and palm-oil wastes into biofuel. To further develop these technologies, it is essential to understand the current stage of the industry and technology developments. The objective of this paper is to provide an overview of the palm oil industry, review technologies available to process oil palm and palm oil residues into biofuel, and to summarise the challenges that should be overcome for further development. The paper also discusses the research and development needs, technoeconomics, and life cycle analysis of biofuel production from oil-palm and palm-oil wastes.

Stabilization of soybean oil during accelerated storage by essential oil of ferulago angulata boiss.

Science.gov (United States)

Sadeghi, Ehsan; Mahtabani, Aidin; Etminan, Alireza; Karami, Farahnaz

2016-02-01

This study has been considered effect of Ferulago angulata essential oil on stabilizing soybean oil during accelerated storage. The essential oil was extracted by Clevenger-type apparatus. For analysis of the essential oil, GC/MS was used. Main components of the essential oil were monoterpene and sesquiterpene hydrocarbons. The essential oil of F. angulata at four concentrations, i.e. 125 (SBO-125), 250 (SBO-250), 500 (SBO-500) and SBO-Mixture (60 ppm TBHQ +60 ppm essential oil) were added to preheated refined soybean oil. TBHQ was used at 120 ppm as standard besides the control. Antioxidant activity index (AAI), free fatty acid (FFA) content, peroxide value (PV) and p-anisidine value (p-AnV) were served for appreciation of efficacy of F. angulata in stabilization of soybean oil. Results from different tests showed that SBO-mixture had highest effect and followed by SBO-TBHQ, SBO-250, SBO-125, SBO-500 and Ctrl. These results reveal F. angulata is a strong antioxidant and can be used instead of synthetic antioxidant.

Heavy oils clean up

International Nuclear Information System (INIS)

Collitt, R.

1997-01-01

High production, transport and refining costs have long led oil companies to shun heavy crude oils. Advances in the technology of upgrading heavy oils, however, are likely to reduce transport costs and improve the refinery output. Research and development by Venezuela's state oil company, Petroleos de Venezuela (PDVSA), has resulted in a process called Aquaconversion which permits the upgrading of heavy crude oils using a catalyst and the hydrogen from steam. This may be carried out at the wellhead in small low-pressure and relatively inexpensive units. In addition, higher distillate yields of higher value could be produced by revamping the thermal cracking units of refineries to incorporate the new technology. This has generated considerable interest in Venezuela's large extra-heavy crude oil reserves and has led multinational oil companies along with PDVSA to pledge $17 billion to their development. Even at a $2 to $3 per barrel upgrading cost, Venezuela's extra heavy crudes are competitive with lighter oils from other countries. Other major markets for the new technology are likely to be China and Russia, given their own large heavy crude reserves. (UK)

Saudi Arabia's oil policy after 1. oil crisis explained with the help of a cartel model

International Nuclear Information System (INIS)

Linderoth, H.

1992-01-01

Saudi Arabian oil policy is analyzed by using a cartel model where Saudi Arabia's oil production is a function of oil price and oil production in other OPEC countries. Elasticities for oil production and oil price are estimated covering oil crises and 3 intercrises periods. During all intercrises periods, production elasticity is not significantly different from 1 which, to a considerable extent, shows that the oil production in Saudi Arabia followed that of the other OPEC countries. During oil crisis periods, production elasticities were either significantly negative or not significantly different from zero. In most cases, the price elasticity was not significantly different from zero. (au)

Using Polymer Alternating Gas to Enhance Oil Recovery in Heavy Oil

Science.gov (United States)

Yang, Yongzhi; Li, Weirong; Zhou, Tiyao; Dong, Zhenzhen

2018-02-01

CO2 has been used to recover oil for more than 40 years. Currently, about 43% of EOR production in U.S. is from CO2 flooding. CO2 flooding is a well-established EOR technique, but its density and viscosity nature are challenges for CO2 projects. Low density (0.5 to 0.8 g/cm3) causes gas to rise upward in reservoirs and bypass many lower portions of the reservoir. Low viscosity (0.02 to 0.08 cp) leads to poor volumetric sweep efficiency. So water-alternating-gas (WAG) method was used to control the mobility of CO2 and improve sweep efficiency. However, WAG process has some other problems in heavy oil reservoir, such as poor mobility ratio and gravity overriding. To examine the applicability of carbon dioxide to recover viscous oil from highly heterogeneous reservoirs, this study suggests a new EOR method--polymer-alternating gas (PAG) process. The process involves a combination of polymer flooding and CO2 injection. To confirm the effectiveness of PAG process in heavy oils, a reservoir model from Liaohe Oilfield is used to compare the technical and economic performance among PAG, WAG and polymer flooding. Simulation results show that PAG method would increase oil recovery over 10% compared with other EOR methods and PAG would be economically success based on assumption in this study. This study is the first to apply PAG to enhance oil recovery in heavy oil reservoir with highly heterogeneous. Besides, this paper provides detailed discussions and comparison about PAG with other EOR methods in this heavy oil reservoir.

Oil Spill Cleanup

Science.gov (United States)

Kauble, Christena Ann

2011-01-01

Several classroom activities using a model of a seashore and an oil spill demonstrate the basic properties of oil spills in oceans. Students brainstorm about how to best clean up the mess. They work in teams, and after agreeing on how they will proceed, their method is tested by measuring the amount of oil removed and by rating the cleanliness of…

The asymmetric relationship between oil revenues and economic activities: The case of oil-exporting countries

International Nuclear Information System (INIS)

Mehrara, Mohsen

2008-01-01

This paper examines the nonlinear or asymmetric relationship between oil revenues and output growth in oil-exporting countries, applying a dynamic panel framework and two different measures of oil shocks. The main results in this paper confirm the stylized facts that in heavily oil-dependent countries lacking the institutional mechanisms de-linking fiscal expenditure from current revenue, oil revenue shocks tend to affect the output in asymmetric and nonlinear ways. The findings suggest that output growth is adversely affected by the negative oil shocks, while oil booms or the positive oil shocks play a limited role in stimulating economic growth. The findings have practical policy implications for decision makers in the area of macroeconomic planning. The use of stabilization and savings funds and diversification of the real sector seems crucial to minimize the harmful effects of oil booms and busts

China's oil use, 1990-2008

International Nuclear Information System (INIS)

Leung, Guy C.K.

2010-01-01

Over the past two decades, China's oil demand has risen steeply. In 1990, it was only about 25% higher than that of 1978, the year economic reform was introduced. By 2008, it had reached 396.0 million tons, roughly four times the 1978 level, making China the second largest oil user worldwide. The country became a net oil importer in 1993, and between 1993 and 2008, its net import dependency - a yardstick for energy security - soared from 7.5% to 50.0%. China's increased demand for oil has made the country a global energy player of critical importance. Although the literature on the global implications of China's oil use has proliferated, relatively few studies have attempted to examine ''how China uses oil.'' Hence, this study covers every oil-consuming facility and sector in China, exploring the patterns of, and factors involved in, oil demand by power plants, oil refineries, heat plants and, gas-works, and industrial, transport, agricultural, household and commercial sectors. It concludes that in virtually all sectors in China, oil demand will grow, with transport and industry leading the way. (author)

Comparative study of ozonized olive oil and ozonized sunflower oil

OpenAIRE

Díaz,Maritza F.; Hernández,Rebeca; Martínez,Goitybell; Vidal,Genny; Gómez,Magali; Fernández,Harold; Garcés,Rafael

2006-01-01

In this study the ozonized olive and sunflower oils are chemical and microbiologically compared. These oils were introduced into a reactor with bubbling ozone gas in a water bath at room temperature until they were solidified. The peroxide, acidity and iodine values along with antimicrobial activity were determined. Ozonization effects on the fatty acid composition of these oils were analyzed using Gas-Liquid Chromatographic Technique. An increase in peroxidation and acidity values was observ...

Comparative analysis of fiscal terms for Alberta oil sands and international heavy and conventional oils

International Nuclear Information System (INIS)

Van Meurs, P.

2007-01-01

There are considerable differences between international heavy oil and Alberta oil sands projects, notably the high viscosity of the bitumen in the oil sands reservoirs. The oil sands bitumen do not flow to wells without heating the bitumen, thereby adding to the already high cost of Alberta oil sand operations. This report provided an economic comparison of Alberta oil sands and international heavy oil projects. It also included a brief scoping review to compare with conventional oil regimes. Full exploration costs including the costs of dry holes were allocated to conventional oil operations in order to obtain a proper comparison. This investigation included the costs of dry holes. The report was a follow up to an earlier study released on April 12, 2007 on the preliminary fiscal evaluation of Alberta oil sand terms. The report provided an economic framework and described project selection. It then provided a discussion of production, costs and price data. Four adjusted projects were presented and compared with Alberta. The Venezuelan royalty formula was also discussed. Last, the report provided a detailed fiscal analysis. Comparisons were offered with Cold Lake and Athabasca Mine. A review of some other fiscal systems applicable to conventional oil were also outlined. It was concluded that Alberta oil sands developments are very competitive. It would be possible to modestly increase government revenues, without affecting the international competitive position of Alberta with respect to conventional oil. There is also some possibility to increase the base royalty on the Alberta oil sands without losing competitiveness. tabs., figs

Effects of cooking method, cooking oil, and food type on aldehyde emissions in cooking oil fumes.

Science.gov (United States)

Peng, Chiung-Yu; Lan, Cheng-Hang; Lin, Pei-Chen; Kuo, Yi-Chun

2017-02-15

Cooking oil fumes (COFs) contain a mixture of chemicals. Of all chemicals, aldehydes draw a great attention since several of them are considered carcinogenic and formation of long-chain aldehydes is related to fatty acids in cooking oils. The objectives of this research were to compare aldehyde compositions and concentrations in COFs produced by different cooking oils, cooking methods, and food types and to suggest better cooking practices. This study compared aldehydes in COFs produced using four cooking oils (palm oil, rapeseed oil, sunflower oil, and soybean oil), three cooking methods (stir frying, pan frying, and deep frying), and two foods (potato and pork loin) in a typical kitchen. Results showed the highest total aldehyde emissions in cooking methods were produced by deep frying, followed by pan frying then by stir frying. Sunflower oil had the highest emissions of total aldehydes, regardless of cooking method and food type whereas rapeseed oil and palm oil had relatively lower emissions. This study suggests that using gentle cooking methods (e.g., stir frying) and using oils low in unsaturated fatty acids (e.g., palm oil or rapeseed oil) can reduce the production of aldehydes in COFs, especially long-chain aldehydes such as hexanal and t,t-2,4-DDE. Copyright © 2016 Elsevier B.V. All rights reserved.

Ozone-Induced Vascular Contractility and Pulmonary Injury Are Differentially Impacted by Diets Enriched With Coconut Oil, Fish Oil, and Olive Oil.

Science.gov (United States)

Snow, Samantha J; Cheng, Wan-Yun; Henriquez, Andres; Hodge, Myles; Bass, Virgina; Nelson, Gail M; Carswell, Gleta; Richards, Judy E; Schladweiler, Mette C; Ledbetter, Allen D; Chorley, Brian; Gowdy, Kymberly M; Tong, Haiyan; Kodavanti, Urmila P

2018-05-01

Fish, olive, and coconut oil dietary supplementation have several cardioprotective benefits, but it is not established if they protect against air pollution-induced adverse effects. We hypothesized that these dietary supplements would attenuate ozone-induced systemic and pulmonary effects. Male Wistar Kyoto rats were fed either a normal diet, or a diet supplemented with fish, olive, or coconut oil for 8 weeks. Animals were then exposed to air or ozone (0.8 ppm), 4 h/day for 2 days. Ozone exposure increased phenylephrine-induced aortic vasocontraction, which was completely abolished in rats fed the fish oil diet. Despite this cardioprotective effect, the fish oil diet increased baseline levels of bronchoalveolar lavage fluid (BALF) markers of lung injury and inflammation. Ozone-induced pulmonary injury/inflammation were comparable in rats on normal, coconut oil, and olive oil diets with altered expression of markers in animals fed the fish oil diet. Fish oil, regardless of exposure, led to enlarged, foamy macrophages in the BALF that coincided with decreased pulmonary mRNA expression of cholesterol transporters, cholesterol receptors, and nuclear receptors. Serum microRNA profile was assessed and demonstrated marked depletion of a variety of microRNAs in animals fed the fish oil diet, several of which were of splenic origin. No ozone-specific changes were noted. Collectively, these data indicate that although fish oil offered vascular protection from ozone exposure, it increased pulmonary injury/inflammation and impaired lipid transport mechanisms resulting in foamy macrophage accumulation, demonstrating the need to be cognizant of potential off-target pulmonary effects that might offset the overall benefit of this vasoprotective supplement.

Analysis of quality of the biogasoils of palm oil and castor oil

International Nuclear Information System (INIS)

Benjumea, Pedro Nel; Agudelo, Jhon Ramiro; Benavides, Alirio Yovany

2004-01-01

Biodiesel is a fuel made from raw materials of renewable origin such as vegetable oils. The objective of this work is to make a quality analysis of two types of biodiesel made from raw materials available in Colombia such as palm oil and castor oil. Biodiesel from palm oil complies with the majority of technical requirements specified by ASTM standards D-975 y D-6751. A high cloud point is the main drawback of this kind of biodiesel. This is a consequence of its highly saturated chemical nature. On the other hand, biodiesel from castor oil presents more difficulties in order to be used in diesel engines because of having a low cetane index and a high viscosity

Hydrodistillation extraction time effect on essential oil yield, composition, and bioactivity of coriander oil.

Science.gov (United States)

Zheljazkov, Valtcho D; Astatkie, Tess; Schlegel, Vicki

2014-01-01

Coriander (Coriandrum sativum L.) is a major essential oil crop grown throughout the world. Coriander essential oil is extracted from coriander fruits via hydrodistillation, with the industry using 180-240 min of distillation time (DT), but the optimum DT for maximizing essential oil yield, composition of constituents, and antioxidant activities are not known. This research was conducted to determine the effect of DT on coriander oil yield, composition, and bioactivity. The results show that essential oil yield at the shorter DT was low and generally increased with increasing DT with the maximum yields achieved at DT between 40 and 160 min. The concentrations of the low-boiling point essential oil constituents: α-pinene, camphene, β-pinene, myrcene, para-cymene, limonene, and γ-terpinene were higher at shorter DT (essential oil constituent, linalool, was 51% at DT 1.15 min, and increased steadily to 68% with increasing DT. In conclusion, 40 min DT is sufficient to maximize yield of essential oil; and different DT can be used to obtain essential oil with differential composition. Its antioxidant capacity was affected by the DT, with 20 and 240 min DT showing higher antioxidant activity. Comparisons of coriander essential oil composition must consider the length of the DT.

75 FR 22363 - United States Standards for Grades of Olive Oil and Olive-Pomace Oil

Science.gov (United States)

2010-04-28

... it as extra virgin olive oil at a premium price. The petitioners requested that the U.S. grade... requirements. The virgin olive oil category, which includes extra virgin olive oil, is unprocessed. Olive oil...: Section 52.1539, Aspect at 20 degrees after 24 hours. Extra virgin and virgin olive oils can be filtered...

The effect of oil pulling with pure coconut oil on Streptococcus mutans: A randomized controlled trial

Directory of Open Access Journals (Sweden)

Varsha Komath Pavithran

2017-01-01

Full Text Available Introduction: Oil pulling as described in ancient Ayurveda involves the use of edible vegetable oils as oral antibacterial agents. It is a practice of swishing oil in the mouth for oral and systemic health benefits. Pure coconut oil has antimicrobial properties and is commonly available in all Indian households. Aim: This study aims to assess the effect of oil pulling therapy with pure coconut oil on Streptococcus mutans count and to compare its efficacy against sesame oil and saline. Materials and Methods: A randomized controlled concurrent parallel- triple blinded clinical trial was conducted. Thirty participants in age range of 20–23 years were randomly allocated into Group A (coconut oil, Group B (sesame oil, and Group C (saline, with 10 in each group. The participants were instructed to swish and pull 10 ml of oil on empty stomach, early morning for 10–15 min. Unstimulated saliva collected before and after oil pulling procedure was analyzed for colony forming units (CFU per ml saliva of S. mutans. The data were analyzed using paired t-test, ANOVA, and post hoc analysis using Tukey's honest significant difference. Statistical significance was set at P < 0.05. Results: A statistically significant reduction in S. mutans CFU count after oil pulling with pure coconut oil (P = 0.001 was found. There was no statistically significant difference between sesame oil and coconut oil (P = 0.97 and between sesame oil and saline (P = 0.061. When efficacy of coconut oil against saline was evaluated, a statistical significant difference (P = 0.039 was found. Conclusion: Oil pulling is an effective method for oral hygiene maintenance as it significantly reduces S. mutans count in the saliva.

seed oil

African Journals Online (AJOL)

Wara

Neem seed oil from the neem tree (Azadiracta indica) finds wide usage one of which is its utilization for cosmetics particularly .... obtained which is higher than that of olive oil 17. mgKOH/g (Davine ... The skin tolerance of shea fat employed as ...

Heavy oil supply economics and supply response to low oil prices

International Nuclear Information System (INIS)

Fisher, L.

1999-01-01

The dynamics of the heavy oil industry are examined, including prices, market demand, supply and supply costs. Price assumptions are provided for the reference case oil price (west Texas intermediate at Cushing). Supply cost methodology is explained. Capital and operating costs for various heavy oil and synthetic sources are derived from modeling results. The range of supply costs for heavy oil and bitumen from various sources, supply costs in terms of reference case market values and in terms of 1995-1996 average market values for Bow River crude, are derived. The CERI long term supply forecast model is explained. Western Canada upstream oil and gas cash flow and capital expenditures, eastern Canada exploration and expenditures by hydrocarbon type, and Canadian heavy oil and bitumen production based on reference case prices are estimated. Based on these projections the outlook for heavy oil at reference case prices for better than average quality resources is judged to be economic. Lower quality resources will require technology gains for successful commercialization. SAGD is a likely candidate in this respect. Again based on reference prices, production is forecast to decline by 100 Kb/d over the next five years. Diluent supply is considered to be adequate throughout the forecast period. As far as thermal bitumen is concerned, the growth could, in fact, exceed the projection, but if so, more upgrading will be required. 11 figs

Oil and biotechnology

Energy Technology Data Exchange (ETDEWEB)

Yasui, Yoshiaki

1988-06-01

The secondary oil recovery due to microorganisms and the production of useful substances from oil distillates using microorganisms are described as examples to solidify the relationship between oil and biotechnology. The secondary crude-oil recovery has been carried out due to the microorganism drive process, which includes the on-the-ground and underground processes. Although the microorganism drive process has been investigated for many years, the selection of the microorganisms is not completely established. Many uncertainties still remain regarding the technical and economic aspects. The single cell protein (SCP) is an example of industrial success in the production of useful substances from the oil. Rumania has produced SCP from normal paraffin and the U. K. from the methanol and the products are used as the protein source for animals. Remarkable progress in the functional efficiency of microorganisms is expected due to the biotechnology for both applications. (4 tabs)

Oil-based paint poisoning

Science.gov (United States)

Paint - oil-based - poisoning ... Hydrocarbons are the primary poisonous ingredient in oil paints. Some oil paints have heavy metals such as lead, mercury, cobalt, and barium added as pigment. These heavy metals can cause additional ...

Environmentally adjusted oil and grease

International Nuclear Information System (INIS)

Andersson, Bert; Lindberg, J.

1992-01-01

With the intention of maintaining healthy environment in our rivers Vattenfall in 1988 initiated a project called 'Environmentally friendly oils'. The goal was to find oils for bearings and hydraulic systems that would cause less negative environmental effects and still maintain a good technical function. Based on the results of the project it is recommended, for both economical and environmental reasons, to change to synthetic oil in bearings and to hydraulic oil made of white oil in regulating systems. The change may be carried out in connection to other work on the system in question. Special care is recommended when cleaning the system from old oil and dirt. In order to maintain the high quality of the oil, also during manufacturing and assembling, one should follow the recommendations outlined in the report. In bearings where used grease leaks into the river, a grease made of white oil should be used. The quality of the rubber sealings must be adapted to the oil used, in order to secure a good function. In order to bring down the number of products and to create an open market some additional changes is necessary in the specifications of oil. Further research regarding oil and sealing is planned. (3 refs.)

Antigenotoxicity of Dietary Coconut Oil

Directory of Open Access Journals (Sweden)

Clara Lim-Sylianco

1992-06-01

Full Text Available Benzo(apyrene, dimethylnitrosamine, methylmethanesulfonate and tetracycline induced formation of micronucleated polychromatic erythrocytes indicating that these substances are genotoxic to bone marrow cells of the experimental mice.Genotoxicity of these substances to germ cells was also observed when low fertility index and high percentage dead implants were induced in experimental mice.When each genotoxin was administered to mice fed with diets containing 18 % coconut oil for 23 days, the formation of micronucleated polychromatic erythrocytes was greatly reduced. Antigenotoxic activity of dietary coconut oil was very much greater than dietary soybean oil.Germ cell genotoxicity of each genotoxin was also reduced when male mice fed the 18 % coconut oil diet were used. When male mice treated with the genotoxin was mated with virgin females, fertility index was increased in the group fed with coconut oil diet. Percentage dead implants was reduced. The antigenotoxic activity of dietary coconut oil on germ cells far exceeds that of dietary soybean oil.Dietary restriction of coconut oil diets enhanced the antigenotoxic activity of coconut oil in bone marrow cells and germs cells.Among the triacylglycerols of coconut oil, trilaurin gave the best antigenotoxic activity in bone marrow cells. Trilaurin is the major triacylglycerol in coconut oil.

Changes in the world market in oil and oil refinements

International Nuclear Information System (INIS)

Ristik, Julija

1996-01-01

Since 1980's the world market for crude oil and oil products has faced significant changes that are going to have a grate influence on the supply and consumption of crude oil derivatives in Macedonia. The knowledge of these changes would have a grate contribution in planning the future development of this part of the energetic system of Macedonia. The purpose of this paper (which is a short version of the introductory report for the ZEMAK session with a theme 'Energetic policy and development of energetics in Macedonia') is to present the actual situation on the market for crude oil products, as well as to give the main factors that would have influence on this market in the future. (author). 4 refs., 3 ills

The Necessity of a Graded Tariff System between Crude Oil and Oil Products

Energy Technology Data Exchange (ETDEWEB)

Kang, B.R. [SK Corporation, Seoul (Korea)

2002-06-01

Even though the graded tariff system between crude oil and oil products has been continuously insisted by oil refining companies since the export and import liberalization of 1997, and its necessity has been admitted by the government, press, and academia, the expanded implementation of the graded tariff system has not been yet realized. Some people says that the graded tariff system between crude oil and oil products is a kind of desperate plans, which oil refining companies suggests to stop the importing companies' rapid growth, so it will eventually restrict the competition of the domestic oil market due to the withering of importing companies. However, the graded tariff system between crude oil and oil products should have been enforced in 1997 as a complementary measure of the import liberalization like other industries or the advanced countries' cases. It is the basic tariff principle that the low tariff is levied on raw materials and the high tariff on final products in order to protect domestic industry. The remaining things are just to form the sympathy and to agree socially for the reorganization of tariff structure in the reasonable way. It is not desirable to make a fool mistake such as a proverb; t is too late to shut the stable door after the horse has bolted. owing to the unreasonable tariff system.

A new oil crisis?

International Nuclear Information System (INIS)

Haffner, R.C.G.; Van Herpt, I.R.Y.

2000-01-01

Recent developments in the oil market are discussed, focusing on the causes of recent price increase, expectations for the near future, why previous oil crises resulted into a recession, and the expected consequences of the oil price increase for the economic growth and inflation. The negative consequences of the high oil price for the European economy can be limited under the condition that claims for higher wages are moderate. 2 refs

Do Oil-Producing Countries Have Normal Oil Overconsumption? An Investigation of Economic Growth and Energy Subsidies

Directory of Open Access Journals (Sweden)

Seyed Reza Mirnezami

2015-07-01

Full Text Available The data shows that oil-producing countries have low oil retail prices and low economic growth compared with other countries. Considering that oil-producing countries experience high oil consumption and low economic growth, it is possible to argue that economic growth is not an appropriate justification for oil consumption and that the main cause for high oil consumption is the low retail price. In addition, it should be noted that the global environmental movement against increasing greenhouse gas emissions—for example, the Kyoto 1998 agreement—seems to have had no effect on oil consumption in oil-producing countries.

Oxidizing oils, etc. [British patent

Energy Technology Data Exchange (ETDEWEB)

Penniman, W B.D.

1926-03-02

The oxidation of crude petroleum and its distillates, shale oils and tars, waxes, sludges, petroleum residues, asphaltic oils, asphalt, malthas, cracked oils and residues from cracking stills, wood tar oils and wood tar, peat and lignite distillates, coal tar oils and coal tar, and oils containing powdered coal, coke or peat, sulphur in suspension, is effected by passing air or other oxygen-containig gas through a layer of the material of a depth sufficient substantially to deoxygenate the air, the pressure being at or below atmospheric pressure.

Oil company profitability: observations on the use of oil product price assessments and associated errors

International Nuclear Information System (INIS)

Jenkins, Gilbert

2000-01-01

Oil companies often report the exact price obtained for crude oil sales. Furthermore, crude oil prices may be linked to the price of Brent crude oil which is actively and very transparently traded on the International Petroleum Exchange. Brent crude oil prices are reported worldwide electronically and in many newspapers on a daily basis. Gas oil (No. 2 Fuel oil in the USA) is actively traded on the IPE and on NYMEX and the prices are also reported worldwide almost instantaneously. One grade of unleaded gasoline is traded on NYMEX but all other oil products do not have regulated and transparent markets. The prices of these products are assessed by price reporters following daily discussions with active oil traders. Two prices are assessed and reported, the bid (low) and offer (high) even if no trade has taken place. The oil industry itself and oil products consumers make much use of these assessed prices. The object of this paper is to provide some statistical detail on the differences between various product price assessments made through 2000. From these differences, it is possible to provide an indication of the precision of oil product price assessments However, it is doubtful if precision data based on a simple determination of the standard deviation of the differences between the assessment made by the various price reporting services would be of practical use. (Author)

Active oil-water interfaces: buckling and deformation of oil drops by bacteria