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Sample records for amino-functionalized magnetic nano-adsorbent

  1. Evaluation of magnetic- and carbon-based nano-adsorbents application in pre-purification of paclitaxel from needles of Taxus baccata

    Energy Technology Data Exchange (ETDEWEB)

    Naghavi, M. R., E-mail: mnaghavi@ut.ac.ir; Motamedi, E., E-mail: motamedi.elaheh@gmail.com; Nasiri, J., E-mail: jaber.nasiri@ut.ac.ir; Alizadeh, H., E-mail: halizade@ut.ac.ir [University of Tehran, Division of Molecular Plant Genetics, Department of Agronomy and Plant Breeding, College of Agricultural & Natural Resources (Iran, Islamic Republic of); Fattahi Moghadam, M. R., E-mail: fattahi@ut.ac.ir [University of Tehran, Department of Horticultural Sciences, College of Agricultural & Natural Resources (Iran, Islamic Republic of); Mashouf, A., E-mail: mashouf-alireza@yahoo.com [Shahid Beheshti University, Medicinal Plants and Drugs Research Institute (Iran, Islamic Republic of)

    2015-01-15

    In this investigation, the proficiency of a number of magnetic carbon-based nano-adsorbents is evaluated in pre-purification process of the crude paclitaxel extract obtained from fresh needles of yew tree (Taxus baccata L.). The effectiveness and removal ability of color and impurities from crude extracts, for three novel candidate nano-adsorbents (i.e., Fe{sub 3}O{sub 4} nanoparticles (Fe{sub 3}O{sub 4}Nps), graphite oxide (GO), and their hybrids Fe{sub 3}O{sub 4}Nps/GO) are compared with commercial graphite in three different solvents. In general, both HPLC and UV–Vis spectroscopy results demonstrate that in less polar solvent (i.e., dichloromethane), the adsorption is greatly affected by the electrostatic attractions, while in more polar solvents (i.e., acetone and ethanol) π–π electron interactions taking place between adsorbent and adsorbate are the most dominant factors in sorption. Considering decolorization efficiency, purity of taxol, recovery and reusability of adsorbents, Fe{sub 3}O{sub 4}Nps/GO (50 g/L) in dichloromethane is selected as the best medium for pre-purification of paclitaxel. Additionally, in kinetic studies the sorption equilibrium can be reached within 120 min, and the experimental data are well fitted by the pseudo-second-order model. The Langmuir sorption isotherm model correlates well with the sorption equilibrium data for the crude extract concentration (500–2,000 mg/L). Our findings display promising applications of Fe{sub 3}O{sub 4}Nps/GO, as a cost-effective nano-adsorbent, to provide a suitable vehicle toward improvement of paclitaxel pre-purification.

  2. Evaluation of magnetic- and carbon-based nano-adsorbents application in pre-purification of paclitaxel from needles of Taxus baccata

    Science.gov (United States)

    Naghavi, M. R.; Motamedi, E.; Nasiri, J.; Alizadeh, H.; Fattahi Moghadam, M. R.; Mashouf, A.

    2015-01-01

    In this investigation, the proficiency of a number of magnetic carbon-based nano-adsorbents is evaluated in pre-purification process of the crude paclitaxel extract obtained from fresh needles of yew tree ( Taxus baccata L.). The effectiveness and removal ability of color and impurities from crude extracts, for three novel candidate nano-adsorbents (i.e., Fe3O4 nanoparticles (Fe3O4Nps), graphite oxide (GO), and their hybrids Fe3O4Nps/GO) are compared with commercial graphite in three different solvents. In general, both HPLC and UV-Vis spectroscopy results demonstrate that in less polar solvent (i.e., dichloromethane), the adsorption is greatly affected by the electrostatic attractions, while in more polar solvents (i.e., acetone and ethanol) π-π electron interactions taking place between adsorbent and adsorbate are the most dominant factors in sorption. Considering decolorization efficiency, purity of taxol, recovery and reusability of adsorbents, Fe3O4Nps/GO (50 g/L) in dichloromethane is selected as the best medium for pre-purification of paclitaxel. Additionally, in kinetic studies the sorption equilibrium can be reached within 120 min, and the experimental data are well fitted by the pseudo-second-order model. The Langmuir sorption isotherm model correlates well with the sorption equilibrium data for the crude extract concentration (500-2,000 mg/L). Our findings display promising applications of Fe3O4Nps/GO, as a cost-effective nano-adsorbent, to provide a suitable vehicle toward improvement of paclitaxel pre-purification.

  3. Synthesis and characterization of magnetic β-cyclodextrin-chitosan nanoparticles as nano-adsorbents for removal of methyl blue.

    Science.gov (United States)

    Fan, Lulu; Zhang, Ying; Luo, Chuannan; Lu, Fuguang; Qiu, Huamin; Sun, Min

    2012-03-01

    A novel nano-adsorbent, β-cyclodextrin-chitosan (CDC) modified Fe(3)O(4) nanoparticles (CDCM) is fabricated for removal of methyl blue (MB) from aqueous solution by grafting CDC onto the magnetite surface. The characteristics results of FTIR, SEM and XRD show that CDC is grafted onto Fe(3)O(4) nanoparticles. The grafted CDC on the Fe(3)O(4) nanoparticles contributes to an enhancement of the adsorption capacity because of the strong abilities of CDCM, which includes the multiple hydroxyl, carboxyl groups, amino groups and the formation of an inclusion complex due to the β-CD molecules through host-guest interactions, to adsorb MB. The adsorption of MB onto CDCM is found to be dependent on pH and temperature. Adsorption equilibrium is achieved in 50 min and the adsorption kinetics of MB is found to follow a pseudo-second-order kinetic model. Equilibrium data for MB adsorption are fitted well by Langmuir isotherm model. The maximum adsorption capacity for MB is estimated to be 2.78 g/g at 30°C. The CDCM was stable and easily recovered. Moreover the adsorption capacity was about 90% of the initial saturation adsorption capacity after being used four times. Copyright © 2011 Elsevier B.V. All rights reserved.

  4. Carboxymethyl-{beta}-cyclodextrin conjugated magnetic nanoparticles as nano-adsorbents for removal of copper ions: Synthesis and adsorption studies

    Energy Technology Data Exchange (ETDEWEB)

    Badruddoza, A.Z.M.; Tay, A.S.H.; Tan, P.Y.; Hidajat, K. [Department of Chemical and Biomolecular Engineering, National University of Singapore, 10 Kent Ridge Crescent, Singapore 119260 (Singapore); Uddin, M.S., E-mail: cheshahb@nus.edu.sg [Department of Chemical and Biomolecular Engineering, National University of Singapore, 10 Kent Ridge Crescent, Singapore 119260 (Singapore)

    2011-01-30

    A novel nano-adsorbent, carboxymethyl-{beta}-cyclodextrin modified Fe{sub 3}O{sub 4} nanoparticles (CMCD-MNPs) is fabricated for removal of copper ions from aqueous solution by grafting CM-{beta}-CD onto the magnetite surface via carbodiimide method. The characteristics results of FTIR, TEM, TGA and XPS show that CM-{beta}-CD is grafted onto Fe{sub 3}O{sub 4} nanoparticles. The grafted CM-{beta}-CD on the Fe{sub 3}O{sub 4} nanoparticles contributes to an enhancement of the adsorption capacity because of the strong abilities of the multiple hydroxyl and carboxyl groups in CM-{beta}-CD to adsorb metal ions. The adsorption of Cu{sup 2+} onto CMCD-MNPs is found to be dependent on pH and temperature. Adsorption equilibrium is achieved in 30 min and the adsorption kinetics of Cu{sup 2+} is found to follow a pseudo-second-order kinetic model. Equilibrium data for Cu{sup 2+} adsorption are fitted well by Langmuir isotherm model. The maximum adsorption capacity for Cu{sup 2+} ions is estimated to be 47.2 mg/g at 25 {sup o}C. Furthermore, thermodynamic parameters reveal the feasibility, spontaneity and exothermic nature of the adsorption process. FTIR and XPS reveal that Cu{sup 2+} adsorption onto CMCD-MNPs mainly involves the oxygen atoms in CM-{beta}-CD to form surface-complexes. In addition, the copper ions can be desorbed from CMCD-MNPs by citric acid solution with 96.2% desorption efficiency and the CMCD-MNPs exhibit good recyclability.

  5. Carboxymethyl-β-cyclodextrin conjugated magnetic nanoparticles as nano-adsorbents for removal of copper ions: synthesis and adsorption studies.

    Science.gov (United States)

    Badruddoza, A Z M; Tay, A S H; Tan, P Y; Hidajat, K; Uddin, M S

    2011-01-30

    A novel nano-adsorbent, carboxymethyl-β-cyclodextrin modified Fe(3)O(4) nanoparticles (CMCD-MNPs) is fabricated for removal of copper ions from aqueous solution by grafting CM-β-CD onto the magnetite surface via carbodiimide method. The characteristics results of FTIR, TEM, TGA and XPS show that CM-β-CD is grafted onto Fe(3)O(4) nanoparticles. The grafted CM-β-CD on the Fe(3)O(4) nanoparticles contributes to an enhancement of the adsorption capacity because of the strong abilities of the multiple hydroxyl and carboxyl groups in CM-β-CD to adsorb metal ions. The adsorption of Cu(2+) onto CMCD-MNPs is found to be dependent on pH and temperature. Adsorption equilibrium is achieved in 30 min and the adsorption kinetics of Cu(2+) is found to follow a pseudo-second-order kinetic model. Equilibrium data for Cu(2+) adsorption are fitted well by Langmuir isotherm model. The maximum adsorption capacity for Cu(2+) ions is estimated to be 47.2mg/g at 25 °C. Furthermore, thermodynamic parameters reveal the feasibility, spontaneity and exothermic nature of the adsorption process. FTIR and XPS reveal that Cu(2+) adsorption onto CMCD-MNPs mainly involves the oxygen atoms in CM-β-CD to form surface-complexes. In addition, the copper ions can be desorbed from CMCD-MNPs by citric acid solution with 96.2% desorption efficiency and the CMCD-MNPs exhibit good recyclability. Copyright © 2010 Elsevier B.V. All rights reserved.

  6. Highly effective removal of mercury and lead ions from wastewater by mercaptoamine-functionalised silica-coated magnetic nano-adsorbents: Behaviours and mechanisms

    Science.gov (United States)

    Bao, Shuangyou; Li, Kai; Ning, Ping; Peng, Jinhui; Jin, Xu; Tang, Lihong

    2017-01-01

    A novel hybrid material was fabricated using mercaptoamine-functionalised silica-coated magnetic nanoparticles (MAF-SCMNPs) and was effective in the extraction and recovery of mercury and lead ions from wastewater. The properties of this new magnetic material were explored using various characterisation and analysis methods. Adsorbent amounts, pH levels and initial concentrations were optimised to improve removal efficiency. Additionally, kinetics, thermodynamics and adsorption isotherms were investigated to determine the mechanism by which the fabricated MAF-SCMNPs adsorb heavy metal ions. The results revealed that MAF-SCMNPs were acid-resistant. Sorption likely occurred by chelation through the amine group and ion exchange between heavy metal ions and thiol functional groups on the nanoadsorbent surface. The equilibrium was attained within 120 min, and the adsorption kinetics showed pseudo-second-order (R2 > 0.99). The mercury and lead adsorption isotherms were in agreement with the Freundlich model, displaying maximum adsorption capacities of 355 and 292 mg/g, respectively. The maximum adsorptions took place at pH 5-6 and 6-7 for Hg(II) and Pb(II), respectively. The maximum adsorptions were observed at 10 mg and 12 mg adsorbent quantities for Hg(II) and Pb(II), respectively. The adsorption process was endothermic and spontaneous within the temperature range of 298-318 K. This work demonstrates a unique magnetic nano-adsorbent for the removal of Hg(II) and Pb(II) from wastewater.

  7. Fe3O4@ionic liquid@methyl orange nanoparticles as a novel nano-adsorbent for magnetic solid-phase extraction of polycyclic aromatic hydrocarbons in environmental water samples.

    Science.gov (United States)

    Liu, Xiaofei; Lu, Xin; Huang, Yong; Liu, Chengwei; Zhao, Shulin

    2014-02-01

    A novel nano-adsorbent, Fe3O4@ionic liquid@methyl orange nanoparticles (Fe3O4@IL@MO NPs), was prepared for magnetic solid-phase extraction (MSPE) of polycyclic aromatic hydrocarbons (PAHs) in environmental water samples. The Fe3O4@IL@MO NPs were synthesized by self-assembly of the ionic liquid 1-octadecyl-3-methylimidazolium bromide (C18mimBr) and methyl orange (MO) onto the surface of Fe3O4 silica magnetic nanoparticles, as confirmed by infrared spectroscopy, ultraviolet-visible spectroscopy and superconducting quantum interface device magnetometer. The extraction performance of Fe3O4@IL@MO NPs as a nano-adsorbent was evaluated by using five PAHs, fluorene (FLu), anthracene (AnT), pyrene (Pyr), benzo(a)anthracene (BaA) and benzo(a)pyrene (BaP) as model analytes. Under the optimum conditions, detection limits in the range of 0.1-2 ng/L were obtained by high performance liquid chromatography-fluorescence detection (HPLC-FLD). This method has been successfully applied for the determination of PAHs in environmental water samples by using the MSPE-HPLC-FLD. The recoveries for the five PAHs tested in spiked real water samples were in the range of 80.4-104.0% with relative standard deviations ranging from 2.3 to 4.9%.

  8. Immobilization of tropizyme-P on amino-functionalized magnetic nanoparticles for fruit juice clarification

    Directory of Open Access Journals (Sweden)

    Mayur R Ladole

    2014-12-01

    Full Text Available Nowadays nanoparticles are widely used as a key tool for enzyme immobilization. Tropizyme-P, a pectolytic enzyme was successfully immobilized on amino functionalized magnetic nanoparticles (AMNPs using glutaraldehyde as a cross-linking agent at 15 mM concentration and 4h cross-linking time. The average size of the synthesized AMNPs was found below 80 nm by particle size analyzer. The binding of tropizyme-P on nanoparticles was confirmed by FTIR spectroscopy. SEM analysis revealed that there was no significance difference in the size of nanoparticles after tropizyme-P immobilization. XRD results showed no phase change in nanoparticles after enzyme immobilization. Physical parameters viz. pH and temperature were optimized. The pH was found to be same and there was shift in optimum temperature of immobilized tropizyme-P by 5ºC. Immobilized tropizyme-P had more thermal stability than free one. The kinetic studies revealed an increase in Vmax of the immobilized enzyme. Reusability of immobilized tropizyme-P was found to retain upto 85% of initial activity after sixth cycles of reuse.

  9. Amino-functionalized Fe(3)O(4)@SiO(2) core-shell magnetic nanomaterial as a novel adsorbent for aqueous heavy metals removal.

    Science.gov (United States)

    Wang, Jiahong; Zheng, Shourong; Shao, Yun; Liu, Jingliang; Xu, Zhaoyi; Zhu, Dongqiang

    2010-09-01

    A novel amino-functionalized Fe(3)O(4)@SiO(2) magnetic nanomaterial with a core-shell structure was developed, aiming to remove heavy metal ions from aqueous media. The structural, surface, and magnetic characteristics of the nanosized adsorbent were investigated by elemental analysis, FTIR, N(2) adsorption-desorption, transmission electron microscopy, powder X-ray diffraction, X-ray photoelectron spectroscopy, vibrating sample magnetometry, thermogravimetric analysis, and zeta-potential measurement. The amino-functionalized Fe(3)O(4)@SiO(2) nanoadsorbent exhibited high adsorption affinity for aqueous Cu(II), Pb(II), and Cd(II) ions, resulting from complexation of the metal ions by surface amino groups. Moreover, the adsorption affinity for heavy metal ions was not much impacted by the presence of a cosolute of humic acid (10.6mg/L) or alkali/earth metal ions (Na(+), K(+), Mg(2+)) (0.025-0.30mmol/L). The metal-loaded Fe(3)O(4)@SiO(2)-NH(2) nanoparticles could be recovered readily from aqueous solution by magnetic separation and regenerated easily by acid treatment. Findings of the present work highlight the potential for using amino-functionalized Fe(3)O(4)@SiO(2) magnetic nanoparticles as an effective and recyclable adsorbent for the removal of heavy metal ions in water and wastewater treatment. Copyright 2010 Elsevier Inc. All rights reserved.

  10. Recent Progress on the Use of Functionalizational Magnetic Nano-adsorbents in Environmental Applications%功能化磁性纳米吸附剂在环境方面的应用研究进展

    Institute of Scientific and Technical Information of China (English)

    刘明强; 王会才; 马振华; 姚晓霞

    2016-01-01

    基于磁性纳米颗粒(MNPs)独特的物理和化学性质,把它作为吸附材料为解决环境问题的研究越来越受到广泛关注。通过其表面官能团修饰制备出不同类型的磁性纳米吸附剂,可以除去废水中大量的有机和无机污染物,吸附性能远远超出了传统吸附材料。然而,磁性纳米基吸附技术的成功实施需要对磁性回收阶段,再生过程和废弃再生溶液及废弃吸附剂的的管理进行全面的评估和优化。对近年来国内外使用磁性纳米吸附剂去除废水中的重金属和染料整个过程做了全面的论述。此外,也分析了磁性回收方法的选择和可能的策略以便用于纳米材料的再生和重复使用。%The application of magnetic nanoparticles (MNPs) as adsorbent materials in solving environmental problems has recently received great attention due to their unique physical and chemical properties, which make them superior to traditional adsorbents. The ability of functionalization by anchoring specific functional groups on their surface makes possible the synthesis of different types of engineered MNPs for the removal of a large number of both organic and inorganic contaminants. However, the successful implementation of the MNPs-base adsorption technology needs of the evaluation and optimization of the magnetic recovery stages, the regeneration process and the management of both the spent regeneration solution and the exhausted adsorbent. This work presents a comprehensive review on the use of MNPs in the treatment of polluted wastewaters with toxic metals and dyes. In addition, the magnetic recovery options and the possible strategies that can be employed for the nanomaterials regeneration and reuse are analyzed.

  11. Removal of arsenic from water using nano adsorbents and challenges: A review.

    Science.gov (United States)

    Lata, Sneh; Samadder, S R

    2016-01-15

    Many researchers have used nanoparticles as adsorbents to remove water pollutants including arsenic after modifying the properties of nanoparticles by improving reactivity, biocompatibility, stability, charge density, multi-functionalities, and dispersibility. For arsenic removal, nano adsorbents emerged as the potential alternatives to existing conventional technologies. The present study critically reviewed the past and current available information on the potential of nano adsorbents for arsenic removal from contaminated water and the challenges involved in that. The study discussed the separation and regeneration techniques of nano adsorbents and the performance thereof. The study evaluated the adsorption efficiency of the various nanoparticles based on size of nanoparticles, types of nano adsorbents, method of synthesis, separation and regeneration of the nano adsorbents. The study found that more studies are required on suitable holding materials for the nano adsorbents to improve the permeability and to make the technology applicable at the field condition. The study will help the readers to choose suitable nanomaterials and to take up further research required for arsenic removal using nano adsorbents.

  12. Design of a surface-immobilized 4-nitrophenol molecularly imprinted polymer via pre-grafting amino functional materials on magnetic nanoparticles.

    Science.gov (United States)

    Mehdinia, Ali; Dadkhah, Sahar; Baradaran Kayyal, Tohid; Jabbari, Ali

    2014-10-17

    In order to resolve the low adsorption capacity of the surface molecularly imprinting methods, an approach was developed for the preparation of magnetic imprinted polymers by pre-grafting the amino functional material, 3-aminopropyltriethoxysilane (APTES), on the surface of the silica coated magnetic substrate. APTES was used for amino functionalization of the silica coated Fe3O4 nanoparticles. Amino groups were used for immobilization of the template molecules on the magnetic surface and additionally to react with the terminal vinyl groups of cross-linker, ethylene glycol dimethacrylate (EGDMA), by the Michael addition reaction. In this way, the imprinting sites of the analytes formed on the substrate were increased. The sorbent was synthesized in the presence of 4-nitrophenol (4-NP) and EGDMA as the template and cross-linker, respectively. Different parameters affecting the adsorption, such as pH, desorption solvent type and adsorption time were evaluated and optimized. The prepared magnetic molecularly imprinted polymer (MMIP) showed high adsorption capacity and proper selectivity for the template molecule. The kinetic adsorption curve indicated that 90 min was sufficient to achieve the adsorption equilibrium for MMIP. The maximum adsorption capacity was 129.1 mg g(-1). The experiments exhibited a linear range of 10-3000 μg L(-1) for 4-NP with the correlation coefficient (R(2)) of 0.997. The results of the real sample analysis confirmed the applicability of the proposed MMIP for quantitative analysis of 4-NP in the aqueous samples.

  13. Amino-functionalized core-shell magnetic mesoporous composite microspheres for Pb(II) and Cd(II) removal.

    Science.gov (United States)

    Tang, Yulin; Liang, Song; Wang, Juntao; Yu, Shuili; Wang, Yilong

    2013-04-01

    Amino-functionalized Fe3O4@mesoporous SiO2 core-shell composite microspheres NH2-MS in created in multiple synthesis steps have been investigated for Pb(II) and Cd(II) adsorption. The microspheres were characterized by transmission electron microscope (TEM), scanning electron microscope (SEM), N2 adsorption-desorption, zeta potential measurements and vibrating sample magnetometer. Batch adsorption tests indicated that NH2-MS exhibited higher adsorption affinity toward Pb(II) and Cd(II) than MS did. The Langmuir model could fit the adsorption isotherm very well with maximum adsorption capacity of 128.21 and 51.81 mg/g for Pb(II) and Cd(II), respectively, implying that adsorption processes involved monolayer adsorption. Pb(II) and Cd(II) adsorption could be well described by the pseudo second-order kinetics model, and was found to be strongly dependent on pH and humic acid. The Pb(II)- and Cd(II)-loaded microspheres were effectively desorbed using 0.01 mol/L HCl or EDTA solution. NH2-MS have promise for use as adsorbents in the removal of Pb(II) and Cd(II) in wastewater treatment processes.

  14. Magnetic adsorbent constructed from the loading of amino functionalized Fe3O4 on coordination complex modified polyoxometalates nanoparticle and its tetracycline adsorption removal property study

    Science.gov (United States)

    Ou, Jinzhao; Mei, Mingliang; Xu, Xinxin

    2016-06-01

    A magnetic polyoxometalates based adsorbent has been synthesized successfully through the loading of amino functionalized Fe3O4 (NH2-Fe3O4) on nanoparticle of a coordination complex modified polyoxometalates (CC/POMNP). FTIR illustrate there exist intense hydrogen bonds between NH2-Fe3O4 and CC/POMNP, which keep the stability of this adsorbent. At room temperature, this adsorbent exhibits ferromagnetic character with saturation magnetization of 8.19 emu g-1, which provides prerequisite for fast magnetic separation. Water treatment experiment illustrates this POM based magnetic adsorbent exhibits high adsorption capacity on tetracycline. The adsorption process can be described well with Temkin model, which illustrates the interaction between adsorbent and tetracycline plays the dominated role in tetracycline removal. The rapid, high efficient tetracycline adsorption ability suggests this POM based magnetic adsorbent exhibits promising prospect in medical and agriculture waste water purification. A magnetic polyoxometalates based adsorbent, which exhibits excellent tetracycline adsorption removal property has been synthesized through the loading of NH2-Fe3O4 on coordination complex modified polyoxometalates

  15. Magnetic adsorbent constructed from the loading of amino functionalized Fe{sub 3}O{sub 4} on coordination complex modified polyoxometalates nanoparticle and its tetracycline adsorption removal property study

    Energy Technology Data Exchange (ETDEWEB)

    Ou, Jinzhao; Mei, Mingliang; Xu, Xinxin, E-mail: xuxx@mail.neu.edu.cn

    2016-06-15

    A magnetic polyoxometalates based adsorbent has been synthesized successfully through the loading of amino functionalized Fe{sub 3}O{sub 4} (NH{sub 2}-Fe{sub 3}O{sub 4}) on nanoparticle of a coordination complex modified polyoxometalates (CC/POMNP). FTIR illustrate there exist intense hydrogen bonds between NH{sub 2}-Fe{sub 3}O{sub 4} and CC/POMNP, which keep the stability of this adsorbent. At room temperature, this adsorbent exhibits ferromagnetic character with saturation magnetization of 8.19 emu g{sup −1}, which provides prerequisite for fast magnetic separation. Water treatment experiment illustrates this POM based magnetic adsorbent exhibits high adsorption capacity on tetracycline. The adsorption process can be described well with Temkin model, which illustrates the interaction between adsorbent and tetracycline plays the dominated role in tetracycline removal. The rapid, high efficient tetracycline adsorption ability suggests this POM based magnetic adsorbent exhibits promising prospect in medical and agriculture waste water purification. A magnetic polyoxometalates based adsorbent, which exhibits excellent tetracycline adsorption removal property has been synthesized through the loading of NH{sub 2}-Fe{sub 3}O{sub 4} on coordination complex modified polyoxometalates - Graphical abstract: A magnetic polyoxometalates based adsorbent, which exhibits excellent tetracycline adsorption removal property has been synthesized through the loading of NH{sub 2}-Fe{sub 3}O{sub 4} on coordination complex modified polyoxometalate. Display Omitted - Highlights: • A POM based magnetic adsorbent was fabricated through the loading of NH{sub 2}-Fe{sub 3}O{sub 4} on POM nanoparticle. • This adsorbent possesses excellent tetracycline adsorption property. • Saturation magnetization value of this adsorbent is 8.19 emug−1, which is enough for magnetic separation.

  16. Preparation of amino-functionalized Fe3O4@mSiO2 core-shell magnetic nanoparticles and their application for aqueous Fe(3+) removal.

    Science.gov (United States)

    Meng, Cheng; Zhikun, Wang; Qiang, Lv; Chunling, Li; Shuangqing, Sun; Songqing, Hu

    2018-01-05

    Fe3O4 nanoparticle with magnetic properties and nanoscale features has provoked wide research interest and great potential application. Herein, a modified Stober and template-removing method was adopted to prepare magnetic mesoporous silica nanoparticles (MSNs), comprising a Fe3O4 core and a mesoporous silica shell. The shell was functionalized by amino-groups with tunable removal efficiency for aqueous heavy metals ions. Structural and magnetic properties were characterized by XRD, SEM, FT-IR, vibrating sample magnetometer (VSM) and BET (Brunauer-Emmertt-Teller) techniques. Also, the adsorbing efficiency for heavy metal ions was measured by UV-vis spectrometry. Results revealed that the pure magnetite is cubic with a side length of 40 - 70nm, while the silica-coated magnetite is spherical with a diameter of 220-260nm. The mesoporous silica shell has an average pore size of 2.6nm and a high surface area of 675m(2)·g(-1), which lead to a large adsorption capacity for Fe(3+) (up to 20.66mg of Fe per g of adsorbent). Moreover, rapid magnetic separation and regeneration of as-prepared adsorbent were achieved conveniently. The distinctive structure and the heavy metal ions removal property of magnetic nanocomposites reflect their prospective application in water treatment. Copyright © 2017 Elsevier B.V. All rights reserved.

  17. Surface functionalization of zirconium dioxide nano-adsorbents with 3-aminopropyl triethoxysilane and promoted adsorption activity for bovine serum albumin

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Gen; Wu, Chaochao [Department of Chemistry, College of Sciences, Northeastern University, Shenyang 110819 (China); Zhang, Xia, E-mail: xzhang@mail.neu.edu.cn [Department of Chemistry, College of Sciences, Northeastern University, Shenyang 110819 (China); Liu, Yufeng, E-mail: liuyufeng@bjmu.edu.cn [College of Pharmacy, Liaoning University, Shenyang 110036 (China); Meng, Hao; Xu, Junli; Han, Yide; Xu, Xinxin; Xu, Yan [Department of Chemistry, College of Sciences, Northeastern University, Shenyang 110819 (China)

    2016-06-15

    Surface functionalization of zirconium dioxide (ZrO{sub 2}) nano-adsorbents was carried out by using 3-aminopropyl triethoxysilane (APTES) as the modifier. The addition amount of APTES was varied to determine the optimum modification extent, and the bulk ZrO{sub 2} microparticles were also modified by APTES for comparison. Some means, such as TEM, XRD, FT-IR, XPS and TG-DSC were used to character these ZrO{sub 2} particles. The results showed that the APTES molecules were chemically immobilized on the surface of ZrO{sub 2} nanoparticles via Zr−O−Si bonds, and the nano-ZrO{sub 2} samples showed larger special surface area. In the adsorption of bovine serum albumin (BSA), nano-ZrO{sub 2} samples exhibited enhanced adsorption activity, and APTES modified nano-ZrO{sub 2} with proper APTES content presented the best adsorption property. Under the same adsorption conditions, the equilibrium adsorption capacity of BSA on APTES-ZrO{sub 2}-2 was almost 2.3 times as that on pristine nano-ZrO{sub 2} and 3.0 times as on bulk ZrO{sub 2} microparticles. The increased adsorption capacity of APTES-ZrO{sub 2} nano-adsorbents can be attributed to the chemical interaction between amino and carboxyl groups at APTES-ZrO{sub 2}/BSA interface. The pH-dependent experiments showed that the optimum pH value for the adsorption and desorption was 5.0 and 9.0, respectively, which suggested that the adsorption and release of BSA could be controlled simply by adjusting the solution pH condition. - Highlights: • APTES chemically immobilized on ZrO{sub 2} nanoparticles via Zr−O−Si bond. • Enhanced adsorption capacity of BSA was observed on APTES-ZrO{sub 2}. • Chemical adsorption character of BSA on APTES-ZrO{sub 2}. • Adsorption/release of BSA on APTES-ZrO{sub 2} accomplished by adjusting pH value.

  18. Copper Ferrocyanide-Functionalized Magnetic Adsorbents Using Polyethyleneimine Coated Fe3O4 Nanoparticles for the Removal of Radioactive Cesium.

    Science.gov (United States)

    Yang, Hee-Man; Hong, Sang Bum; Cho, Yong Suk; Lee, Kune-Woo; Seo, Bum-Kyoung; Moon, Jei-Kwon

    2016-03-01

    Copper ferrocyanide-functionalized magnetic nano-adsorbents were successfully synthesized by electrostatic coating of citric acid coated Fe3O4 nanoparticles with polyethyleneimine, and immobilizing copper and ferrocyanide on the surfaces of polyethyleneimine-coated nanoparticles. Radioactive cesium (Cs) adsorption tests were conducted to investigate the effectiveness of the copper ferrocyanide-functionalized magnetic nano-adsorbents toward the removal of radioactive Cs.

  19. Synthesis of amino functionalized magnetic graphenes composite material and its application to remove Cr(VI), Pb(II), Hg(II), Cd(II) and Ni(II) from contaminated water

    Energy Technology Data Exchange (ETDEWEB)

    Guo, Xiaoyao [School of Resources and Environment, University of Jinan, Jinan 250022 (China); Du, Bin, E-mail: dubin61@gmail.com [School of Resources and Environment, University of Jinan, Jinan 250022 (China); Wei, Qin, E-mail: sdjndxwq@163.com [School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022 (China); Yang, Jian [School of Resources and Environment, University of Jinan, Jinan 250022 (China); Hu, Lihua [School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022 (China); Yan, Liangguo; Xu, Weiying [School of Resources and Environment, University of Jinan, Jinan 250022 (China)

    2014-08-15

    Highlights: • Graphenes magnetic composite nanoparticles (Fe{sub 3}O{sub 4}-GS) were used to adsorb metal ions. • The adsorption of metal ions onto Fe{sub 3}O{sub 4}-GS could be well interpreted by the Freundlich equation. • The adsorption of metal ions onto Fe{sub 3}O{sub 4}-GS fit pseudo-second order kinetic model. • Thermodynamic studies illustrated that the adsorption process was endothermic and spontaneous in nature. - Abstract: In the present study, a kind of graphenes magnetic material (Fe{sub 3}O{sub 4}-GS) was prepared by compositing graphene sheet with ferroferric oxide, and shown to be effictive for removing Cr(VI), Pb(II), Hg(II), Cd(II) and Ni(II) ions from aqueous solution. The synthesized sorbent was characterized by SEM, TEM, FTIR, XRD, XPS and BET, respectively. The pH{sub ZPC} value of the sorbent was estimated to be 3.5 by alkaline-titration methods. Fe{sub 3}O{sub 4}-GS can be simply recovered from water with magnetic separation at low magnetic field within one minute. The sorption capacities of the metals were 17.29, 27.95, 23.03, 27.83 and 22.07 mg g{sup −1} for Cr(VI), Pb(II), Hg(II), Cd(II) and Ni(II), respectively. Kinetic data showed good correlation with pseudo-second-order equation and the Freundlich model was found to fit for the isotherm data of all the heavy metal ions. It was found that the metals sorption was accomplished mainly via chelation or ion exchange. The results of thermodynamic studies illustrate that the adsorption process was endothermic and spontaneous in nature.

  20. Synthesis of amino functionalized magnetic graphenes composite material and its application to remove Cr(VI), Pb(II), Hg(II), Cd(II) and Ni(II) from contaminated water.

    Science.gov (United States)

    Guo, Xiaoyao; Du, Bin; Wei, Qin; Yang, Jian; Hu, Lihua; Yan, Liangguo; Xu, Weiying

    2014-08-15

    In the present study, a kind of graphenes magnetic material (Fe3O4-GS) was prepared by compositing graphene sheet with ferroferric oxide, and shown to be effective for removing Cr(VI), Pb(II), Hg(II), Cd(II) and Ni(II) ions from aqueous solution. The synthesized sorbent was characterized by SEM, TEM, FTIR, XRD, XPS and BET, respectively. The pHZPC value of the sorbent was estimated to be 3.5 by alkaline-titration methods. Fe3O4-GS can be simply recovered from water with magnetic separation at low magnetic field within one minute. The sorption capacities of the metals were 17.29, 27.95, 23.03, 27.83 and 22.07 mg g(-1) for Cr(VI), Pb(II), Hg(II), Cd(II) and Ni(II), respectively. Kinetic data showed good correlation with pseudo-second-order equation and the Freundlich model was found to fit for the isotherm data of all the heavy metal ions. It was found that the metals sorption was accomplished mainly via chelation or ion exchange. The results of thermodynamic studies illustrate that the adsorption process was endothermic and spontaneous in nature.

  1. Photochemical preparation and formation mechanism of amino-functionalized magnetic nanogels%胺基磁性纳米凝胶的光化学制备及形成机理

    Institute of Scientific and Technical Information of China (English)

    宫培军; 吴文贤; 姚思德; 童国秀; 乔儒; 李良超

    2011-01-01

    Poly(allylainine-co-iV^V-methylenebisacrylamide) magnetic nanogels (PAAm-Fe3O4) were prepared by photochemical polymerization of allylamine and AyV-methylenebisacrylamide in magnetite aqueous suspension under UV irradiation. The composition, zeta potential, morphology, particle size distribution and magnetic properties of the product were characterized in detail. To explore the initiating process of polymerization, laser flash photolysis was used to investigate the interaction between Fe3C>4 nanoparticles and organic electron donor by employing aniline as the probe molecule, an analogue of allylamine. It indicated an occurrence of electron transfer process from the organic electron donor to Fe3O4 which may be critical to initiate polymerization reaction of amino monomer and form polymer shell on the surface of Fe3C>4 nanoparticles. The mean diameter and diameter distribution of PAAm-Fe3C>4 can be tuned in a moderate range by varing irradiation time or volume of the dropped monomer. The experimental results also proved that nearly spherical PAAm-Fe3O4 possessed a core-shell structure and positive zeta potential and high magnetic content of nearly 88%. Moreover, it behaved quasi-superparamagnetic at room temperature and its saturation magnetization reached to 50 emu/g. Finally, a possible formation mechanism of magnetic nanogel was proposed.%以Fe3O4纳米粒子为磁核,借助紫外光辐照含有烯丙基胺和N,N'-亚甲基双丙烯酰胺的水溶液,制备了胺基功能化的聚(烯丙基胺-共-N,N'-亚甲基双丙烯酰胺)磁性纳米凝胶(PAAm-Fe3O4),对其化学组成、表面电位、形貌、粒径分布及磁学性质进行了分析表征,并研究了光照时间和单体的滴加量对产物的粒径和粒径分布的影响.为探索聚合反应的引发方式,以烯丙基胺的类似物-苯胺为探针,借助激光光解-瞬态吸收装置研究了纳米Fe3O4粒子与有机电子供体的相互作用.结果表明,光化学方法实现了高

  2. Preparation of amino-functionalized silica in aqueous conditions

    Science.gov (United States)

    Cuoq, Fabrice; Masion, Armand; Labille, Jérôme; Rose, Jérôme; Ziarelli, Fabio; Prelot, Benedicte; Bottero, Jean-Yves

    2013-02-01

    Silica particle surfaces were modified with 3-aminopropyltriethoxysilane (APTES) for the fabrication under mild conditions of amino-functionalized silica particles which can be applied in a number of processes, e.g. chromatography. Surface activation was carried out in water at natural pH and in toluene on non-preheated silica in order to compare the grafting efficiency in these two solvents. No successive thermal treatments were carried out after grafting. Grafting extents were then calculated using solid state TOC measurements. Grafting extents of APTES in water and anhydrous solvent were surprisingly found to be the same after a simple rinsing step (i.e. 2.10 ± 0.09 μmol/m2). Thus, in our case, the use of anhydrous solvent is an unnecessary precaution if the silica is further used in water since equivalent grafting extents of APTES are obtained with a simple and eco-friendly grafting process.

  3. Stabilization of a magnetic nano-adsorbent by extracted pectin to remove methylene blue from aqueous solution: A comparative studying between two kinds of cross-likened pectin

    Energy Technology Data Exchange (ETDEWEB)

    Rakhshaee, Roohan, E-mail: rakhshaei@iaurasht.ac.ir [Department of Applied Chemistry, Faculty of Science, Islamic Azad University, Rasht Branch, P.O. Box 41335-3516, Rasht (Iran, Islamic Republic of); Panahandeh, Mohammad [Environmental Research Institute of Jahad Daneshgahi (Iran, Islamic Republic of)

    2011-05-15

    The removal of methylene blue (MB) as a cationic dye from aqueous solution by the stabilized Fe{sub 3}O{sub 4} nano-particles with the extracted pectin from apple waste (FN-PA) increased due to using the cross-linked forms of the bound pectin on the nano-particles surface by glutaraldehyde (FN-PAG) and adipic acid (FN-PAA) as the cross-linking agents. This increase happened in spite of binding some of the adsorbent functional groups of pectin with nano-particles. It can be due to the local concentrate of other free functional groups after connecting with nano-scale particles. Thermodynamic studies showed that the adsorption equilibrium constant and the maximum adsorption capacities increased with increasing temperature for all of the nano-bioparticles. The kinetic followed the second-order models with the highest rate constants viz. 16.23, 19.76 and 23.04 (x10{sup -3} g/mg min) by FN-PAA. The adsorption force arrangement of MB by these nano-biosorbents regarding their activation energy was obtained as: FN-PAA > FN-PAG > FN-PA.

  4. Optimal Surface Amino-Functionalization Following Thermo-Alkaline Treatment of Nanostructured Silica Adsorbents for Enhanced CO2 Adsorption

    Directory of Open Access Journals (Sweden)

    Obdulia Medina-Juárez

    2016-11-01

    Full Text Available Special preparation of Santa Barbara Amorphous (SBA-15, mesoporous silica with highly hexagonal ordered, these materials have been carried out for creating adsorbents exhibiting an enhanced and partially selective adsorption toward CO2. This creation starts from an adequate conditioning of the silica surface, via a thermo-alkaline treatment to increase the population of silanol species on it. CO2 adsorption is only reasonably achieved when the SiO2 surface becomes aminated after put in contact with a solution of an amino alkoxide compound in the right solvent. Unfunctionalized and amine-functionalized substrates were characterized through X-ray diffraction, N2 sorption, Raman spectroscopy, electron microscopy, 29Si solid-state Nuclear Magnetic Resonance (NMR, and NH3 thermal programmed desorption. These analyses proved that the thermo-alkaline procedure desilicates the substrate and eliminates the micropores (without affecting the SBA-15 capillaries, present in the original solid. NMR analysis confirms that the hydroxylated solid anchors more amino functionalizing molecules than the unhydroxylated material. The SBA-15 sample subjected to hydroxylation and amino-functionalization displays a high enthalpy of interaction, a reason why this solid is suitable for a strong deposition of CO2 but with the possibility of observing a low-pressure hysteresis phenomenon. Contrastingly, CH4 adsorption on amino-functionalized, hydroxylated SBA-15 substrates becomes almost five times lower than the CO2 one, thus giving proof of their selectivity toward CO2. Although the amount of retained CO2 is not yet similar to or higher than those determined in other investigations, the methodology herein described is still susceptible to optimization.

  5. Optimal Surface Amino-Functionalization Following Thermo-Alkaline Treatment of Nanostructured Silica Adsorbents for Enhanced CO2 Adsorption

    Science.gov (United States)

    Medina-Juárez, Obdulia; García-Sánchez, Miguel Ángel; Arellano-Sánchez, Ulises; Kornhauser-Straus, Isaac; Rojas-González, Fernando

    2016-01-01

    Special preparation of Santa Barbara Amorphous (SBA)-15, mesoporous silica with highly hexagonal ordered, these materials have been carried out for creating adsorbents exhibiting an enhanced and partially selective adsorption toward CO2. This creation starts from an adequate conditioning of the silica surface, via a thermo-alkaline treatment to increase the population of silanol species on it. CO2 adsorption is only reasonably achieved when the SiO2 surface becomes aminated after put in contact with a solution of an amino alkoxide compound in the right solvent. Unfunctionalized and amine-functionalized substrates were characterized through X-ray diffraction, N2 sorption, Raman spectroscopy, electron microscopy, 29Si solid-state Nuclear Magnetic Resonance (NMR), and NH3 thermal programmed desorption. These analyses proved that the thermo-alkaline procedure desilicates the substrate and eliminates the micropores (without affecting the SBA-15 capillaries), present in the original solid. NMR analysis confirms that the hydroxylated solid anchors more amino functionalizing molecules than the unhydroxylated material. The SBA-15 sample subjected to hydroxylation and amino-functionalization displays a high enthalpy of interaction, a reason why this solid is suitable for a strong deposition of CO2 but with the possibility of observing a low-pressure hysteresis phenomenon. Contrastingly, CH4 adsorption on amino-functionalized, hydroxylated SBA-15 substrates becomes almost five times lower than the CO2 one, thus giving proof of their selectivity toward CO2. Although the amount of retained CO2 is not yet similar to or higher than those determined in other investigations, the methodology herein described is still susceptible to optimization. PMID:28774017

  6. Can amino-functionalized carbon nanotubes carry functional nerve growth factor?

    Institute of Scientific and Technical Information of China (English)

    Wen Chen; Qing Xiong; Quanxia Ren; Yake Guo; Gao Li

    2014-01-01

    Carbon nanotubes can carry protein into cells to induce biological effects. Amino-functionalized carbon nanotubes are soluble and biocompatible, have high reactivity and low toxicity, and can help promote nerve cell growth. In this study, amino-functionalized ethylenediamine-treated multi-walled carbon nanotubes were used to prepare carbon nanotubes-nerve growth factor complexes by non-covalent grafting. The physicochemical properties, cytotoxicity to PC12 and chick embryo dorsal root ganglion, and biological activity of the carbon nanotubes-nerve growth factor complexes were investigated. The results showed that amino functionalization improved carbon nanotubes-nerve growth factor complex dispersibility, reduced their toxicity to PC12 cells, and promoted PC12 cell differentiation and chick embryo dorsal root ganglion.

  7. Amino-functionalized green fluorescent carbon dots as surface energy transfer biosensors for hyaluronidase.

    Science.gov (United States)

    Liu, Siyu; Zhao, Ning; Cheng, Zhen; Liu, Hongguang

    2015-04-21

    Amino-functionalized fluorescent carbon dots have been prepared by hydrothermal treatment of glucosamine with excess pyrophosphate. The produced carbon dots showed stabilized green emission fluorescence at various excitation wavelengths and pH environments. Herein, we demonstrate the surface energy transfer between the amino-functionalized carbon dots and negatively charged hyaluronate stabilized gold nanoparticles. Hyaluronidase can degrade hyaluronate and break down the hyaluronate stabilized gold nanoparticles to inhibit the surface energy transfer. The developed fluorescent carbon dot/gold nanoparticle system can be utilized as a biosensor for sensitive and selective detection of hyaluronidase by two modes which include fluorescence measurements and colorimetric analysis.

  8. Amino-Functional Polybenzimidazole Blends with Enhanced Phosphoric Acid Mediated Proton Conductivity as Fuel Cell Electrolytes

    DEFF Research Database (Denmark)

    Aili, David; Javakhishvili, Irakli; Han, Junyoung;

    2016-01-01

    A new amino-functional polybenzimidazole copolymer is synthesized by homogeneous solution condensation polymerization from a novel monomer, N,N′-bis (2,4-diaminophenyl)-1,3-diaminopropane. The copolymer readily dissolves in organic solvents and shows good film forming characteristics. To balance...... the phosphoric acid uptake and to obtain mechanically robust membranes, the amino-functional polybenzimidazole derivative is blended with high molecular weight poly [2,2′-(m-phenylene)-5,5′-bisbenzimidazole] at different ratios. Due to the high acid uptake, the homogenous blend membranes show enhanced proton...

  9. A robust amino-functionalized titanium(iv) based MOF for improved separation of acid gases.

    Science.gov (United States)

    Vaesen, Sébastien; Guillerm, Vincent; Yang, Qingyuan; Wiersum, Andrew D; Marszalek, Bartosz; Gil, Barbara; Vimont, Alexandre; Daturi, Marco; Devic, Thomas; Llewellyn, Philip L; Serre, Christian; Maurin, Guillaume; De Weireld, Guy

    2013-10-03

    A combination of adsorption, microcalorimetry, infra-red spectroscopy and modeling has been implemented to reveal the potential of the H2S resistant amino-functionalized Ti MOF MIL-125 porous solid for the concomitant elimination of CO2 and H2S from biogas and natural gas.

  10. Amino-Functional Polybenzimidazole Blends with Enhanced Phosphoric Acid Mediated Proton Conductivity as Fuel Cell Electrolytes

    DEFF Research Database (Denmark)

    Aili, David; Javakhishvili, Irakli; Han, Junyoung

    2016-01-01

    A new amino-functional polybenzimidazole copolymer is synthesized by homogeneous solution condensation polymerization from a novel monomer, N,N′-bis (2,4-diaminophenyl)-1,3-diaminopropane. The copolymer readily dissolves in organic solvents and shows good film forming characteristics. To balance ...

  11. 纳米磁粉固定化酶催化合成α-D-葡萄糖-1-磷酸%Efficient Synthesis of α-D-Glucose-1-Phosphate by Maltodextrin Phosphorylase Immobilized on Amino-functionalized Magnetic Nanoparticles

    Institute of Scientific and Technical Information of China (English)

    董青; 欧阳立明; 刘建文; 许建和

    2010-01-01

    α-D-Glucose-1-phosphate(Gle-1-P) is an expensive intermediate in the biosynthesis of nuclcotide glucose.This paper describes a biocataiytic system for the efficient synthesis of Glc-1-P from the low cost raw materials:maltodextrin and phosphate at ordinary temperatares.After molecular cloning and the expression of a maltodextrin phosphorylase (MalPase) gone from E.coli (Escherichia coli) K12,the resultant recombinant enzyme was immobilized on amino-fanctionalized magnetic nanoparticles for recycling and repeated use.Conditions for the biocatalytic reaction were optimized and the immobilized MalPase could be easily recovered and reused over eight cycles in the repeated synthesis of Glc-1-P.After simple purification steps approximately 440 mg of crude product Was obtained with a moderate isolation yield of 70.5%.%建立了以麦芽糊精和磷酸盐为底物,在常温下合成α-D-葡萄糖-1-磷酸的生物催化体系.从大肠杆菌K12中克隆表达了麦芽糊精磷酸化酶,并固定化在氨基修饰的磁性纳米颗粒上,以便于酶的回收和重复利用.在优化的反应条件下,于200ml体系中连续使用该固定化酶8批次,催化合成了α-D-葡萄糖-1-磷酸.经过简单的纯化步骤,最终得到440mg产品,分离产率为70.5%.

  12. Improving the controlled release of water-insoluble emodin from amino-functionalized mesoporous silica

    Energy Technology Data Exchange (ETDEWEB)

    Xu Yunqiang; Wang Chunfeng [Shandong Provincial Key Laboratory of Fine Chemicals, School of Chemistry, Shandong Polytechnic University, Jinan 250353, Shandong (China); Zhou Guowei, E-mail: guoweizhou@hotmail.com [Shandong Provincial Key Laboratory of Fine Chemicals, School of Chemistry, Shandong Polytechnic University, Jinan 250353, Shandong (China); Wu Yue; Chen Jing [Shandong Provincial Key Laboratory of Fine Chemicals, School of Chemistry, Shandong Polytechnic University, Jinan 250353, Shandong (China)

    2012-06-15

    Several types of amino-functionalized mesoporous silica, including F5-SBA-15, F10-SBA-15, and F15-SBA-15 were prepared through co-condensation of tetraethoxysilane (TEOS) and (3-aminopropyl)triethoxysilane (APTES) in varying molar ratios (5 mol%, 10 mol%, and 15 mol%) via a hydrothermal process. The materials obtained were characterized by means of small-angle X-ray powder diffraction, scanning electron microscopy, transmission electron microscopy, N{sub 2} adsorption-desorption, Fourier transformed infrared spectra, and X-ray photoelectron spectroscopy. Increasing APTES molar ratios decreased the degree of orderliness of the functionalized mesoporous silica. Pure and amino-functionalized SBA-15 samples were employed as supports for the controlled release of water-insoluble drug emodin. Loading experiments showed that drug loading capacities mainly depended on the surface areas and pore diameters of the carriers. Controlled release profiles of emodin-loaded samples were studied in phosphate buffered saline (PBS, pH 7.4), and results indicated that the emodin release rate could be controlled by surface amino-functionalized carriers. Emodin loaded on functionalized mesoporous supports exhibited a lower release rate than that of loaded on pure SBA-15, emodin loaded on F10-SBA-15 showed the smallest release amount (71.74 wt%) after stirring in PBS for 60 h. Findings suggest that functionalized mesoporous SBA-15 is a promising carrier for achieving prolonged release time periods.

  13. Polymer Adsorption on Iron Oxide Nanoparticles for One-Step Amino-Functionalized Silica Encapsulation

    Directory of Open Access Journals (Sweden)

    Lionel Maurizi

    2015-01-01

    Full Text Available This paper presents an original method to obtain, in one step, core/shell nanoparticles grafted covalently with polymer and functionalized with amino groups. By combining polyvinyl alcohol (PVA and silica precursors, we were able to obtain silica-coated and amino-functionalized iron oxide nanoparticles (SPIONs cross-linked with PVA. We also showed that using silica and amino-silica precursors together significantly increased the amount of PVA covalently bonded to the SPION surface compared to using only silica precursors. This original and interesting method has high potential for the industrial development of biocompatible functionalized nanoparticles for targeting nanomedicine.

  14. Colossal magnetoresistance in amino-functionalized graphene quantum dots at room temperature: manifestation of weak anti-localization and doorway to spintronics.

    Science.gov (United States)

    Roy, Rajarshi; Thapa, Ranjit; Kumar, Gundam Sandeep; Mazumder, Nilesh; Sen, Dipayan; Sinthika, S; Das, Nirmalya S; Chattopadhyay, Kalyan K

    2016-04-21

    In this work, we have demonstrated the signatures of localized surface distortions and disorders in functionalized graphene quantum dots (fGQD) and consequences in magneto-transport under weak field regime (∼1 Tesla) at room temperature. Observed positive colossal magnetoresistance (MR) and its suppression is primarily explained by weak anti-localization phenomenon where competitive valley (inter and intra) dependent scattering takes place at room temperature under low magnetic field; analogous to low mobility disordered graphene samples. Furthermore, using ab-initio analysis we show that sub-lattice sensitive spin-polarized ground state exists in the GQD as a result of pz orbital asymmetry in GQD carbon atoms with amino functional groups. This spin polarized ground state is believed to help the weak anti-localization dependent magneto transport by generating more disorder and strain in a GQD lattice under applied magnetic field and lays the premise for future graphene quantum dot based spintronic applications.

  15. Sorption of Cd{sup 2+} on mercapto and amino functionalized palygorskite

    Energy Technology Data Exchange (ETDEWEB)

    Liang, Xuefeng [School of Environmental Science and Engineering, Tianjin University, Tianjin 300072 (China); Key Laboratory of Original Environmental Quality of MOA, Agro-Environmental Protection Institute of Ministry of Agriculture, Tianjin 300191 (China); Han, Jun [Institute of Green and Intelligent Technology, Chinese Academy of Sciences, Chongqing 400714 (China); Xu, Yingming, E-mail: dingandliang@gmail.com [Key Laboratory of Original Environmental Quality of MOA, Agro-Environmental Protection Institute of Ministry of Agriculture, Tianjin 300191 (China); Wang, Lin; Sun, Yuebing [Key Laboratory of Original Environmental Quality of MOA, Agro-Environmental Protection Institute of Ministry of Agriculture, Tianjin 300191 (China); Tan, Xin [School of Environmental Science and Engineering, Tianjin University, Tianjin 300072 (China)

    2014-12-15

    Graphical abstract: Sorption of Cd{sup 2+} on PAL, PAL-SH and PAL-NH{sub 2} involved different mechanisms. For pristine palygorskite, Cd{sup 2+} reacted with surface hydroxyl groups to form surface complexation; for mercapto functionalized palygorskite, the complexation of Cd{sup 2+} with mercapto groups existed in addition to the complexation with surface hydroxyl groups; for amino functionalized palygorskite, surface precipitation of Cd{sup 2+} with OH- and CO{sub 2} to form CdCO{sub 3} played an important role in the sorption process except complexation with amino and hydroxyl groups. - Highlights: • Surface modification increased the sorption efficiency significantly. • The sorption process was endothermic and driven by entropy changes. • The sorption mechanisms were investigated by XRD, FTIR, {sup 29}Si CP/MAS NMR and XPS. • The sorption mechanisms involved surface complexation and surface precipitation. - Abstract: Mercapto and amino functionalized palygorskite samples were prepared by nanotexturization method, respectively, and applied for the sorption of Cd{sup 2+} from aqueous solution to investigate the sorption mechanism and assess the application potential for the remediation of Cd polluted water and soils. The samples before and after sorption were characterized through XRD, FTIR, {sup 29}Si CP/MAS NMR and XPS. The sorption thermodynamics, kinetics and mechanisms of Cd{sup 2+} sorption on mercapto and amino functionalized palygorskite were studied. Langmuir isotherm was proved to describe the sorption data better and pseudo second order kinetic model could fit the sorption kinetic processes well. Functionalization increased the sorption amounts significantly compared to pristine palygorskite. The positive enthalpy change confirmed that the sorption process was endothermic. The positive entropy changes revealed that sorption of Cd{sup 2+} was driven by entropy changes. Combined the results of analyses of the diffraction peaks by XRD, vibration

  16. The Curing Process of Epoxy/Amino-Functionalized MWCNTs: Calorimetry, Molecular Modelling, and Electron Microscopy

    Directory of Open Access Journals (Sweden)

    S. G. Prolongo

    2010-01-01

    Full Text Available Curing kinetic of an epoxy resin reinforced with amino-functionalized MWCNTs has been studied by DSC and the obtained results were explained through morphological studies carried out by SEM, TEM, FEG-SEM, and molecular simulation tools. The presence of MWCNTs in the curing reaction induces a retardation effect of curing reaction and a decrease of the reaction heat. Both are associated with the adsorption of curing agent molecules inside carbon nanotubes, which was proved through the application of electron microscopic techniques and molecular simulation tools. It has been also demonstrated that there is a chemical reaction between amine groups anchored to the nanotubes and oxirane rings of epoxy monomer, which improves the nanoreinforcement/matrix interfacial adhesion, appearing a chemical interphase. The glass transition temperature (Tg of epoxy matrix increases by the addition of MWCNTs due to the restriction of its mobility.

  17. Attachment of Lipase on Amino Functionalized Titania Submicrospheres via Covalent Binding

    Institute of Scientific and Technical Information of China (English)

    WU Hong; LIANG Yan-peng; SHI Jia-fu; WANG Xiao-li

    2013-01-01

    A facile and effective method for immobilized lipase was presented.The titania submicrospheres were synthesized via a modified sol-gel method followed by amino functionalization through the chelation between dopamine and titania.Lipase was covalently attached on the functionalized titania surface using glutaraldehyde as the cross linking agent.The loading ratio and relative activity of the immobilized lipase were 230 mg/g titania submicrospheres and 65%,respectively.The kinetic parameters including the Michaelis constant (Km) and the maximum reaction rate (Vmax) changed slightly after immobilization.Compared to free lipase,the immobilized lipase showed favorable pH stability,thermostability,recycling stability and storage stability.The immobilized lipase retained 90% activity after incubation at 50 ℃ for 2 h,while the free lipase retained only 60% activity.The immobilized lipase retained more than 80% activity after 8 batches.

  18. Preparation of Electrospun Nanocomposite Nanofibers of Polyaniline/Poly(methyl methacrylate with Amino-Functionalized Graphene

    Directory of Open Access Journals (Sweden)

    Hanan Abdali

    2017-09-01

    Full Text Available In this paper we report upon the preparation and characterization of electrospun nanofibers of doped polyaniline (PANI/poly(methyl methacrylate (PMMA/amino-functionalized graphene (Am-rGO by electrospinning technique. The successful functionalization of rGO with amino groups is examined by Fourier transforms infrared (FTIR, X-ray photoelectron spectroscopy (XPS and Raman microspectrometer. The strong electric field enables the liquid jet to be ejected faster and also contributes to the improved thermal and morphological homogeneity of PANI/PMMA/Am-rGO. This results in a decrease in the average diameter of the produced fibers and shows that these fibers can find promising uses in many applications such as sensors, flexible electronics, etc.

  19. Synthesis of dendritic polyamide with protected amino functional groups in the periphery

    Institute of Scientific and Technical Information of China (English)

    Ye Li; Meng Chao; Zhang Xiuqiang; Zhang Afang

    2006-01-01

    A homologous series of first- to third-generation dendritic polyamides 2a,3,and 5 with tris(aminoethyl)amine (TREA) as the core and the protected amino functional groups at the periphery were synthesized via active ester route from "Schlüter" type dendron 1a.Their structures were characterized by 1H-NMR and mass spectra.Based on the efficient synthesis of the first generation dendrimer 2a (yield 75%),the synthesis of second-generation dendrimer 3 was found to be more efficient via the convergent method (yield 69%),while the mixed strategy was applied efficiently for the synthesis of the higher generation dendrimer 5 (yield 37%).The overall yield for the third generation dendrimer 5 from Schlüter dendron is 12%.

  20. Amino Functionalized SiO2 nanoparticles for seeding MOF-5

    Science.gov (United States)

    Falcaro, Paolo; Nairn, Kate M.; Hill, Anita J.; Buso, Dario

    2011-02-01

    Here we present a new type of approach for the mass production of metallorganic frameworks (MOFs). In particular, a heterogeneous process for MOF-5 growth involving amino functionalized silica nanoparticles is presented. The proposed sol-gel approach provides a promising route toward the large-scale production of colloidal MOFs by leveraging the enormous surface areas offered by nano-sized seeds used as nucleating agents. The synthesis of the ceramic seeds (SiO2 NPs) is performed at room temperature and considerable volumes of MOF crystals can be produced in 1/10 of the time required for the conventional solvothermal method. The growth of the crystals has been observed with optical microscopy, scanning electron microscopy (SEM), energy dispersive x-ray spectroscopy (EDX) and the crystal quality has been verified using X-ray powder diffraction.

  1. Synthesis of amino-functionalized mesoporous silica sheets and their application for metal ion capture

    Directory of Open Access Journals (Sweden)

    Kazuma Nakanishi

    2015-03-01

    Full Text Available Novel mesoporous silica sheets with surface amino-functional groups (sheet-NH2 were prepared for the efficient adsorption of aqueous metal ions. The sheet-NH2 were synthesized by a dual-templating process using Pluronic P123 and N-palmitoyl-l-alanine as templates. Two silicone regents were used to form the silica framework: tetraethoxysilane and 3-aminopropyltriethoxysilane. In the synthetic process, the as-prepared silicate was refluxed in ethanol to remove the organic templates remaining from the surface amino groups derived from APTES. The prepared sheet-NH2 showed widths of several micrometres and small thicknesses of approximately 50 nm. The pore diameter, pore volume and BET surface area of sheet-NH2 were determined by nitrogen adsorption–desorption isotherms to be 3.1 nm, 0.73 cm3 g−1 and 189.9 m2 g−1, respectively. TEM, XRD, FT-IR and TG–DTA analysis demonstrated that the sheet material had a disordered mesoporous structure and contained organic chains. The adsorptions of aqueous zinc(II and copper(II metal ions were examined and compared with amino-functionalized conventional mesoporous silica (MCM-NH2, calcined mesoporous silica sheets and silica beads with no porous structures. Notably, the sheet-NH2 exhibited the highest adsorption of both zinc and copper ions among the examined materials. In addition, the metal ion sorption equilibrium data of sheet-NH2 were fitted to the Langmuir isotherm model.

  2. Removal of phosphate by Fe-coordinated amino-functionalized 3D mesoporous silicates hybrid materials

    Institute of Scientific and Technical Information of China (English)

    Jianda Zhang; Zhemin Shen; Zhijian Mei; Shanping Li; Wenhua Wang

    2011-01-01

    Phosphate removal from aqueous waste streams is an important approach to control the eutrophication downstream bodies of water.A Fe(Ⅲ) coordinated amino-functionalized silicate adsorbent for phosphate adsorption was synthesized by a post-grafting and metal cation incorporation process. The surface structure of the adsorbent was characterized by X-ray diffraction, N2 adsoropion/desoprotion technique, and Fourier transform infrared spectroscopy. The experimental results showed that the adsorption equilibrium data were well fitted to the Langmuir equation. The maximum adsorption capacity of the modified silicate material was 51.8 mg/g. The kinetic data from the adsorption of phosphate were fitted to pseudo second-order model. The phosphate adsorption was highly pH dependent and the relatively high removal of phosphate fell within the pH range 3.0-6.0. The coexistence of other anions in soiutions has an adverse effect on phosphate adsorption; a decrease in adsorption capacity followed the order of exogenous anions: F- > SO42- > NO3- > Cl-. In addition, the adsorbed phosphate could be desorbed by NaOH solutions. This silicate adsorbent with a large adsorption capacity and relatively high selectivity could be utilized for the removal of phosphate from aqueous waste streams or in aquatic environment.

  3. Surface decoration of carbon nanosheets with amino-functionalized organosilica nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Baikousi, M.; Dimos, K. [Department of Materials Science and Engineering, University of Ioannina, GR-45110 Ioannina (Greece); Bourlinos, A.B. [Physics Department, University of Ioannina, GR-45110, Ioannina (Greece); Regional Centre of Advanced Technologies and Materials, Faculty of Science, Department of Physical Chemistry, Palacky University in Olomouc, 77146 (Czech Republic); Zboril, R. [Regional Centre of Advanced Technologies and Materials, Faculty of Science, Department of Physical Chemistry, Palacky University in Olomouc, 77146 (Czech Republic); Papadas, I.; Deligiannakis, Y. [Department of Environmental and Natural Resources Management, University of Ioannina, Seferi 2, 30100 Agrinio (Greece); Karakassides, M.A., E-mail: mkarakas@cc.uoi.gr [Department of Materials Science and Engineering, University of Ioannina, GR-45110 Ioannina (Greece)

    2012-02-01

    Carbonaceous nanosheets decorated with amino-functionalized organosilica nanoparticles have been synthesized by a direct pyrolysis of betaine at 400 Degree-Sign C in air, followed by a simple surface treatment with ([3-(2-aminoethylamino) propyl]trimethoxysilane under reflux conditions. Both pristine and organosilica modified carbon nanosheets (OMCNs), were characterized by Fourier-transform infrared (FTIR), Raman, and electron paramagnetic resonance (EPR) spectroscopies, transmission electron microscopy and thermal analysis methods. The experimental data reveal a dramatic increase in the number of radical centers on the surface of the developed OMCN hybrid. The organosilica nanoparticles, ranging in size between 3 and 15 nm, are spherical and homogenously anchored on the surface of carbon nanosheets. The formation of C-O-Si bridges between carbon sheets and the organosilica nanoparticles has been supported by FTIR and EPR. These nanoparticles are bound to the nanosheet surface together with individual functional organosilane groups at a spacing of about 4 Angstrom-Sign distance. The final hybrid is the complex nanosystem composed of 2D carbon nanosheets, spherical organosilica nanoparticles and immobilized amino organosilane molecules.

  4. Configurational study of amino-functionalized silica surfaces: A density functional theory modeling.

    Science.gov (United States)

    Hozhabr Araghi, Samira; Entezari, Mohammad H; Sadeghi Googheri, Mohammad Sadegh

    2015-06-01

    Despite extensive studies of the amino-functionalized silica surfaces, a comprehensive investigation of the effects of configuration and hydrolysis of 3-aminopropyltriethoxysilan (APTES) molecules attached on silica has not been studied yet. Therefore, the methods of quantum mechanics were used for the study of configuration and hydrolysis forms of APTES molecules attached on the surface. For this purpose, five different categories based on the number of hydrolyzed ethoxy groups including 16 configurations were designed and analyzed by the density functional theory (DFT) method. The steric hindrance as an effective factor on the stability order was extracted from structural analysis. Other impressive parameters such as the effects of hydrogen bond and electron delocalization energy were obtained by using the atoms in molecules (AIM) and natural bond orbitals (NBO) theories. Consequently, it was found that the stability of configurations was attributed to steric effects, hydrogen bond numbers and electron delocalization energy. The maximum stability was achieved when at least two of these parameters cooperate with each other.

  5. One-pot synthesis of amino functionalized mesoporous silica materials: using simulations to understand transitions between different structures

    NARCIS (Netherlands)

    patti, A; Mackie, A.D.; Zelenak, V.; Siperstein, F.R.

    2008-01-01

    The rich phase behavior of surfactants can be exploited to design materials with a given desired structure and properties. One example includes amino functionalized mesoporous silicas, which can be used in different environmental applications, including removal of heavy metals from water and CO2

  6. Interfacial synthesis of ordered and stable covalent organic frameworks on amino-functionalized carbon nanotubes with enhanced electrochemical performance.

    Science.gov (United States)

    Sun, Bing; Liu, Jian; Cao, Anmin; Song, Weiguo; Wang, Dong

    2017-06-08

    Highly ordered 2D COFTTA-DHTA was synthesized on amino-functionalized MWCNTs with high crystallinity, regular pore structures and high chemical stability. Coupled with the improved electrical conductivity in the presence of MWCNT skeletons, NH2-f-MWCNT@COFTTA-DHTA showed improved electrochemical performance as a capacitive electrode material.

  7. Development of a Prolonged-Release Drug Delivery System with Magnolol Loaded in Amino-Functionalized Mesoporous Silica

    Directory of Open Access Journals (Sweden)

    Alina Stefanache

    2017-03-01

    Full Text Available Magnolol (MG is a small-molecule neolignan polyphenolic compound isolated from the genus Magnolia. The anti-inflammatory, anti-oxidative, anti-diabetic, anti-tumorgenic, anti-neurodegenerative, anti-depressant and anti-microbial properties of MG are well documented in recent literature. These fascinating multiple biological activities of MG encourage research about the development of new delivery and administration approaches able to maximize its potential benefits. This study describes the amino-functionalization of the SBA-15 (Santa Barbara Amorphous mesoporous matrix by post-synthesis grafting using APTES (3-aminopropyltriethoxysilane and the characterization of amino-functionalized mesoporous silica SBA-15 loaded with MG in order to achieve modified drug delivery systems. The amino-functionalization of silica SBA-15 was carried out by grafting by refluxing in dry toluene. The powders obtained were characterized texturally by Brunauer-Emmett-Teller (BET surface area analysis measurements and morphologically by scanning electron microscopy. MG loading degree in the nanoporous matrix was determined by the HPLC method at λ = 290 nm. Results showed that by grafting the amino groups in the silica SBA-15, we obtained amino-functionalized silica SBA-15 with an ordered structure, with specific surfaces and pore sizes that differ from the original matrix, which was reflected in the amount of MG immobilized and release kinetics profile.

  8. Tuning surface properties of amino-functionalized silica for metal nanoparticle loading: The vital role of an annealing process

    Science.gov (United States)

    Pei, Yuchen; Xiao, Chaoxian; Goh, Tian-Wei; Zhang, Qianhui; Goes, Shannon; Sun, Weijun; Huang, Wenyu

    2016-06-01

    Metal nanoparticles (NPs) loaded on oxides have been widely used as multifunctional nanomaterials in various fields such as optical imaging, sensors, and heterogeneous catalysis. However, the deposition of metal NPs on oxide supports with high efficiency and homogeneous dispersion still remains elusive, especially when silica is used as the support. Amino-functionalization of silica can improve loading efficiency, but metal NPs often aggregate on the surface. Herein, we report that a facial annealing of amino-functionalized silica can significantly improve the dispersion and enhance the loading efficiency of various metal NPs, such as Pt, Rh, and Ru, on the silica surface. A series of characterization techniques, such as diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS), Zeta potential analysis, UV-Vis spectroscopy, thermogravimetric analysis coupled with infrared analysis (TGA-IR), and nitrogen physisorption, were employed to study the changes of surface properties of the amino-functionalized silica before and after annealing. We found that the annealed amino-functionalized silica surface has more cross-linked silanol groups and relatively lesser amount of amino groups, and less positively charges, which could be the key to the uniform deposition of metal NPs during the loading process. These results could contribute to the preparation of metal/oxide hybrid NPs for the applications that require uniform dispersion.

  9. Green and fast synthesis of amino-functionalized graphene quantum dots with deep blue photoluminescence

    Energy Technology Data Exchange (ETDEWEB)

    Blanco, E., E-mail: eduardo.blanco@uca.es; Blanco, G.; Gonzalez-Leal, J. M.; Barrera, M. C.; Domínguez, M.; Ramirez-del-Solar, M. [University of Cádiz, Institute of Electron Microscopy and Materials (Spain)

    2015-05-15

    Graphene quantum dots (GQDs) were prepared using a top-down approach with a green microwave-assisted hydrothermal synthesis from ultrathin graphite, previously ultrasound delaminated. Results obtained by transmission electron microscopy and atomic force microscopy indicate that the so-fabricated GQDs are plates with 6 nm of average diameter, mostly single- or bi-layered. Photoluminescence characterization shows that the strongest emission occurs at 410–415 nm wavelength when the samples are excited at 310–320 nm wavelength. In addition to these down-conversion features, GQDs also exhibit up-conversion photoluminescence when excited in the range 560–800 nm wavelength, with broad emission peaks at 410–450 nm wavelength. Analysis of X-ray photoelectron spectroscopy measurements indicates a higher proportion of C–C sp{sup 2} than sp{sup 3} bonds, with the sp{sup 3} ones mainly located at the GQD surfaces. Also evidences of C–O and C–N bonds at the GQD surface have been observed. The combination of these results with Raman and ultraviolet–visible absorption experiments allows envisaging the GQDs to be composed of amino-functionalized sp{sup 2} islands with a high degree of surface oxidation. This would explain the photoluminescent properties observed in the samples under study. The combined up- and down-conversion photoluminescence processes would made these GQDs a powerful energy-transfer component in GQDs–TiO{sub 2} nanocomposite systems, which could be used in photocatalyst devices with superior performance compared to simple TiO{sub 2} systems.

  10. Transfection system of amino-functionalized calcium phosphate nanoparticles: in vitro efficacy, biodegradability, and immunogenicity study.

    Science.gov (United States)

    Mostaghaci, Babak; Susewind, Julia; Kickelbick, Guido; Lehr, Claus-Michael; Loretz, Brigitta

    2015-03-11

    Many methods have been developed in order to use calcium phosphate (CaP) for delivering nucleotides into living cells. Surface functionalization of CaP nanoparticles (CaP NPs) with N-(2-aminoethyl)-3-aminopropyltrimethoxysilane was shown recently to achieve dispersed NPs with a positive surface charge, capable of transfection (Chem. Mater. 2013, 25 (18), 3667). In this study, different crystal structures of amino-modified CaP NPs (brushite and hydroxyapatite) were investigated for their interaction in cell culture systems in more detail. Qualitative (confocal laser scanning microscopy) and quantitative (flow cytometry) transfection experiments with two cell lines showed the higher transfection efficacy of brushite versus hydroxyapatite. The transfection also revealed a cell type dependency. HEK293 cells were easier to transfect compared to A549 cells. This result was supported by the cytotoxicity results. A549 cells showed a higher degree of tolerance toward the CaP NPs. Further, the impact of the surface modification on the interaction with macrophages and complement as two important components of the innate immune system were considered. The amine surface functionalization had an effect of decreasing the release of proinflammatory cytokines. The complement interaction investigated by a C3a complement activation assay did show no significant differences between CaP NPs without or with amine modification and overall weak interaction. Finally, the degradation of CaP NPs in biological media was studied with respect to the two crystal structures and at acidic and neutral pH. Both amino-modified CaP NPs disintegrate within days at neutral pH, with a notable faster disintegration of brushite NPs at acidic pH. In summary, the fair transfection capability of this amino functionalized CaP NPs together with the excellent biocompatibility, biodegradability, and low immunogenicity make them interesting candidates for further evaluation.

  11. Mechanisms of chromium and arsenite adsorption by amino-functionalized SBA-15.

    Science.gov (United States)

    Wu, Yunhai; Zhou, Jianxin; Jin, Yanping; Cao, Julin; Yilihan, Palizhati; Wen, Yajun; Wu, Yunying

    2014-02-01

    The adsorption of Cr(VI) and As(III) by amino-functionalized SBA-15 (NH2-SBA-15) from single and binary systems were investigated in this work. The effects of pH and temperature on the adsorption of NH2-SBA-15 were studied. Adsorption kinetics, isotherm model, and thermodynamics were studied to analyze the experimental data. pH 2 was the optimum condition for the adsorption of Cr(VI) and pH 4 for As(III) adsorption. Increasing temperature had a positive effect on the removal of both Cr(VI) and As(III). The Freundlich isotherm model can depict the adsorption process best. The pseudo-second-order kinetic model fitted well with the kinetic data of Cr(VI) and As(III) in the single-component system. In the binary system, the adsorption of As(III) by NH2-SBA-15 was slightly enhanced with the presence of Cr(VI); however, As(III) had no obvious effect on the removal of Cr(VI). Regeneration experiments indicated that 0.1 mol/L NaHCO3 was an efficient desorbent for the recovery of Cr(VI) and As(III) from NH2-SBA-15; the desorption rates for Cr(VI) and As(III) were 91.6 and 33.59 %, respectively. After five recycling cycles, the removal rates were 88 and 7 % for Cr(VI) and As(III) adsorption by NH2-SBA-15, respectively.

  12. Synthesis and Characterization of Amino-functionalized Meso-porous Silicate MCM-41 for Removal of Toxic Metal Ions

    Institute of Scientific and Technical Information of China (English)

    HAMID,Sepehrian; SYED,Waqif-Husain; MOHAMMAD,Ghannadi-Maragheh

    2009-01-01

    Amino-functionalized MCM-41 has been prepared by grafting amino containing functional groups onto mesoporous silicate MCM-41 and characterized by powder X-ray diffraction, N2 adsorption/desorption measure-ment, SEM, FT-IR, thermogravimetry and elemental analysis to confirm the ordered mesoporous structure and the functionalization of the amino groups. Sorption behavior for 18 metal ions on this sorbent has been studied and discussed.

  13. Impact of non-functionalized and amino-functionalized multiwall carbon nanotubes on pesticide uptake by lettuce (Lactuca sativa L.).

    Science.gov (United States)

    Hamdi, Helmi; De La Torre-Roche, Roberto; Hawthorne, Joseph; White, Jason C

    2015-03-01

    The effect of non-functionalized and amino-functionalized multiwall carbon nanotube (CNT) exposure, as well as the impact of CNT presence on coexistent pesticide accumulation, was investigated in lettuce (Lactuca sativa L.). Lettuce seeds were sown directly into CNT-amended vermiculite (1000 mg L(-1)) to monitor phytotoxicity during germination and growth. During growth, lettuce seedlings were subsequently exposed to chlordane (cis-chlordane [CS], trans-chlordane [TC] and trans-nonachlor [TN]) and p,p'-DDE (all at 100 ng/L) in the irrigation solution for a 19-d growth period. CNT exposure did not significantly influence seed germination (82-96%) or plant growth. Similarly, pesticide exposure had no impact on plant growth, total pigment production or tissue lipid peroxidation. After 19 d, the root content of total chlordane and p,p'-DDE was 390 and 73.8 µg g(-1), respectively; in plants not exposed to CNTs, the shoot levels were 1.58 and 0.40 µg g(-1), respectively. The presence and type of CNT significantly influenced pesticide availability to lettuce seedlings. Non-functionalized CNT decreased the root and shoot pesticide content by 88% and 78%, respectively, but amino-functionalized CNT effects were significantly more modest, with decreases of 57% in the roots and 23% in the shoots, respectively. The presence of humic acid completely reversed the reduced accumulation of pesticides induced by amino-functionalized CNT, likely due to strong competition over adsorption sites on the nanomaterial (NM). These findings have implications for food safety and for the use of engineered NMs in agriculture, especially with leafy vegetables.

  14. Synthesis and functionalization of magnetite nanoparticles with different amino-functional alkoxysilanes

    Energy Technology Data Exchange (ETDEWEB)

    Bini, Rafael A., E-mail: r_bini11@yahoo.com.br [Institute of Chemistry, Laboratory of Magnetic Materials and Colloids, Sao Paulo State University-UNESP, Caixa Postal 355, Araraquara 14800-900 (Brazil); Marques, Rodrigo Fernando C. [Institute of Science and Technology, Alfenas Federal University, Pocos de Caldas 37701-100 (Brazil); Santos, Francisco J. [Institute of Chemistry, Laboratory of Magnetic Materials and Colloids, Sao Paulo State University-UNESP, Caixa Postal 355, Araraquara 14800-900 (Brazil); Chaker, Juliano A. [FCE, Brasilia University, Caixa Postal 7380, Brasilia 72220-140 (Brazil); Jafelicci, Miguel [Institute of Chemistry, Laboratory of Magnetic Materials and Colloids, Sao Paulo State University-UNESP, Caixa Postal 355, Araraquara 14800-900 (Brazil)

    2012-02-15

    Superparamagnetic iron oxide (SPIO) nanoparticles show great promise for many biotechnological applications. This paper addresses the synthesis and characterization of SPIO nanoparticles grafted with three different alkoxysilanes: 3-aminopropyl-triethoxysilane (APTES), 3-aminopropyl-ethyl-diethoxysilane (APDES) and 3-aminopropyl-diethy-ethoxysilane (APES). SPIO nanoparticles with an average particle diameter of 10 nm were prepared by chemical sonoprecipitation. As confirmed by Fourier transform infrared (FTIR) spectroscopy, silylation of these nanoparticles occurs through a two-step process. Decreasing the number of alkoxide groups reduced the concentration of free amino groups on the SPIO surface ([SPIO-NH{sub 2}]-APTES>APDES>APES). This phenomenon results from steric contributions and the formation of H-bonded amines provided by the ethyl groups present in the APDES and APES molecules. A simulation of SPIO nanoparticles in a saline physiologic solution shows that the ethyl groups impart larger steric stability onto the ferrofluids, which reduces aggregation. The magnetization (M) versus magnetic field (H) curves show that the synthesized iron oxide nanoparticles display superparamagnetic behavior. The zero-field cooling (ZFC) and field cooling (FC) curves show that the changes in the blocking temperature depend on the alkoxysilane-functionalized particle surface. - Highlights: > Superparamagnetic iron oxide nanoparticles were grafted with different alkoxysilanes. > The decrease of alkoxide group number reduced the concentration of free amino group. > We correlate the influence of the amino and ethyl groups with their colloidal property. > Inter-particles aggregation analyzed by magnetic measurement.

  15. A general Suzuki cross-coupling reaction of heteroaromatics catalyzed by nanopalladium on amino-functionalized siliceous mesocellular foam.

    Science.gov (United States)

    Bratt, Emma; Verho, Oscar; Johansson, Magnus J; Bäckvall, Jan-Erling

    2014-05-02

    Suzuki-Miyaura cross-coupling reactions of heteroaromatics catalyzed by palladium supported in the cavities of amino-functionalized siliceous mesocellular foam are presented. The nanopalladium catalyst effectively couples not only heteroaryl halides with boronic acids but also heteroaryl halides with boronate esters, potassium trifluoroborates, MIDA boronates, and triolborates, producing a wide range of heterobiaryls in good to excellent yields. Furthermore, the heterogeneous palladium nanocatalyst can easily be removed from the reaction mixture by filtration and recycled several times with minimal loss in activity. This catalyst provides an alternative, environmentally friendly, low-leaching process for the preparation of heterobiaryls.

  16. Application of Novel Amino-Functionalized NZVI@SiO2 Nanoparticles to Enhance Anaerobic Granular Sludge Removal of 2,4,6-Trichlorophenol

    National Research Council Canada - National Science Library

    Guan, Zeyu; Wan, Jinquan; Ma, Yongwen; Wang, Yan; Shu, Yajie

    2015-01-01

    A novel amino-functionalized silica-coated nanoscale zerovalent iron (NZVI@SiO2-NH2) was successfully synthesized by using one-step liquid-phase method with the surface functionalization of nanoscale zerovalent iron...

  17. Colossal magnetoresistance in amino-functionalized graphene quantum dots at room temperature: manifestation of weak anti-localization and doorway to spintronics

    Science.gov (United States)

    Roy, Rajarshi; Thapa, Ranjit; Kumar, Gundam Sandeep; Mazumder, Nilesh; Sen, Dipayan; Sinthika, S.; Das, Nirmalya S.; Chattopadhyay, Kalyan K.

    2016-04-01

    In this work, we have demonstrated the signatures of localized surface distortions and disorders in functionalized graphene quantum dots (fGQD) and consequences in magneto-transport under weak field regime (~1 Tesla) at room temperature. Observed positive colossal magnetoresistance (MR) and its suppression is primarily explained by weak anti-localization phenomenon where competitive valley (inter and intra) dependent scattering takes place at room temperature under low magnetic field; analogous to low mobility disordered graphene samples. Furthermore, using ab-initio analysis we show that sub-lattice sensitive spin-polarized ground state exists in the GQD as a result of pz orbital asymmetry in GQD carbon atoms with amino functional groups. This spin polarized ground state is believed to help the weak anti-localization dependent magneto transport by generating more disorder and strain in a GQD lattice under applied magnetic field and lays the premise for future graphene quantum dot based spintronic applications.In this work, we have demonstrated the signatures of localized surface distortions and disorders in functionalized graphene quantum dots (fGQD) and consequences in magneto-transport under weak field regime (~1 Tesla) at room temperature. Observed positive colossal magnetoresistance (MR) and its suppression is primarily explained by weak anti-localization phenomenon where competitive valley (inter and intra) dependent scattering takes place at room temperature under low magnetic field; analogous to low mobility disordered graphene samples. Furthermore, using ab-initio analysis we show that sub-lattice sensitive spin-polarized ground state exists in the GQD as a result of pz orbital asymmetry in GQD carbon atoms with amino functional groups. This spin polarized ground state is believed to help the weak anti-localization dependent magneto transport by generating more disorder and strain in a GQD lattice under applied magnetic field and lays the premise for

  18. Preparation of amino-functionalized regenerated cellulose membranes with high catalytic activity.

    Science.gov (United States)

    Wang, Wei; Bai, Qian; Liang, Tao; Bai, Huiyu; Liu, Xiaoya

    2017-09-01

    The modification of regenerated cellulose (RC) membranes was carried out by using silane coupling agents presenting primary and secondary amino-groups. The grafting of the amino groups onto the modified cellulose molecule was confirmed by X-ray photoelectron spectroscopies and (13)C nuclear magnetic resonance spectroscopic analyses. The crystallinity of the cellulose membranes (CM) decreased after chemical modification as indicated by the X-ray diffraction results. Moreover, a denser structure was observed at the surface and cross section of the modified membranes by SEM images. The contact angle measurements showed that the silane coupling treatment enhanced the hydrophobicity of the obtained materials. Then the catalytic properties of two types of modified membranes were studied in a batch process by evaluating their catalytic performance in a Knoevenagel condensation. The results indicated that the cellulose membrane grafted with many secondary amines exhibited a better catalytic activity compared to the one grafted only by primary amines. In addition, the compact structure of the modified membranes permitted their application in a pervaporation catalytic membrane reactor. Therefore, functional CM that prepared in this paper represented a promising material in the field of industrial catalysis. Copyright © 2017 Elsevier B.V. All rights reserved.

  19. Enhancing lithium-sulphur battery performance by strongly binding the discharge products on amino-functionalized reduced graphene oxide

    Science.gov (United States)

    Wang, Zhiyu; Dong, Yanfeng; Li, Hongjiang; Zhao, Zongbin; Bin Wu, Hao; Hao, Ce; Liu, Shaohong; Qiu, Jieshan; Lou, Xiong Wen (David)

    2014-09-01

    Lithium-sulphur batteries are one very appealing power source with high energy density. But their practical use is still hindered by several issues including short lifespan, low efficiency and safety concern from the lithium anode. Polysulphide dissolution and insulating nature of sulphur are generally considered responsible for the capacity degradation. However, the detachment of discharge products, that is, highly polar lithium sulphides, from nonpolar carbon matrix (for example, graphene) has been rarely studied as one critical factor. Here we report the strongly covalent stabilization of sulphur and its discharge products on amino-functionalized reduced graphene oxide that enables stable capacity retention of 80% for 350 cycles with high capacities and excellent high-rate response up to 4 C. The present study demonstrates a feasible and effective strategy to solve the long-term cycling difficulty for lithium-sulphur batteries and also helps to understand the capacity decay mechanism involved.

  20. Enhancing lithium-sulphur battery performance by strongly binding the discharge products on amino-functionalized reduced graphene oxide.

    Science.gov (United States)

    Wang, Zhiyu; Dong, Yanfeng; Li, Hongjiang; Zhao, Zongbin; Wu, Hao Bin; Hao, Ce; Liu, Shaohong; Qiu, Jieshan; Lou, Xiong Wen David

    2014-09-25

    Lithium-sulphur batteries are one very appealing power source with high energy density. But their practical use is still hindered by several issues including short lifespan, low efficiency and safety concern from the lithium anode. Polysulphide dissolution and insulating nature of sulphur are generally considered responsible for the capacity degradation. However, the detachment of discharge products, that is, highly polar lithium sulphides, from nonpolar carbon matrix (for example, graphene) has been rarely studied as one critical factor. Here we report the strongly covalent stabilization of sulphur and its discharge products on amino-functionalized reduced graphene oxide that enables stable capacity retention of 80% for 350 cycles with high capacities and excellent high-rate response up to 4 C. The present study demonstrates a feasible and effective strategy to solve the long-term cycling difficulty for lithium-sulphur batteries and also helps to understand the capacity decay mechanism involved.

  1. Amino-functionalized breath-figure cavities in polystyrene-alumina hybrid films: effect of particle concentration and dispersion.

    Science.gov (United States)

    V, Lakshmi; Raju, Annu; V G, Resmi; Pancrecious, Jerin K; T P D, Rajan; C, Pavithran

    2016-03-14

    We report the formation of breath-figure (BF) patterns with amino-functionalized cavities in a BF incompatible polystyrene (PS) by incorporating functionalized alumina nanoparticles. The particles were amphiphilic-modified and the modifier ratio was regulated to achieve a specific hydrophobic/hydrophilic balance of the particles. The influence of the physical and chemical properties of the particles like particle concentration, the hydrophobic/hydrophilic balance, etc., on particle dispersion in solvents having different polarity and the corresponding changes in the BF patterns have been studied. The amphiphilic-modified alumina particles could successfully assist the BF mechanism, generating uniform patterns in polystyrene films with the cavity walls decorated with the functionalized alumina particles, even from water-miscible solvents like THF. The possibility of fabricating free-standing micropatterned films by casting and drying the suspension under ambient conditions was also demonstrated. The present method opens up a simple route for producing functionalized BF cavities, which can be post-modified by a chemical route for various biological applications.

  2. Adsorption and desorption characteristics of DNA onto the surface of amino functional mesoporous silica with various particle morphologies.

    Science.gov (United States)

    Hikosaka, Ryouichi; Nagata, Fukue; Tomita, Masahiro; Kato, Katsuya

    2016-04-01

    Recently, deoxyribonucleic acid (DNA) adsorption on solid materials has been reported for applications such as genetic diagnosis of diseases, gene delivery, and biosensors. Mesoporous silica (MPS) is an excellent carrier because of its high surface area and large pore volume. Functionalization of the MPS surface can be controlled by silane coupling reagents, and the MPS particle morphology can be easily changed by the synthetic conditions. In this study, to evaluate the ability of DNA adsorption on MPS, the MPS surface was functionalized using four reagents, 3-aminopropyltriethoxysilane (-NH2), N-(2-aminoethyl)-3-aminopropyltriethoxysilane (-2ENH2), N-(6-aminohexyl)aminopropyltrimethoxysilane (-2HNH2), and (3-trimethoxysilylpropyl)diethylenetriamine (-3NH2), each having a different number of amino groups and alkyl chain lengths. Moreover, we prepared three types of MPSs with different particle morphologies: sheet-type structure (MPS sheet), spherical MPS (MCM-41s), and nonporous spherical silica. A high adsorption capacity was observed in MPS sheets with -2HNH2 (sheet-2HNH2) and -3NH2 (sheet-3NH2), as well as MCM-41s with -3NH2 (41s-3NH2). The adsorption and desorption rates of DNA on these three MPSs were then examined and the best results were obtained with 41s-3NH2. These results demonstrate that the amino functionalized MPS materials are useful DNA adsorbents.

  3. Surface ion-imprinted amino-functionalized cellulosic cotton fibers for selective extraction of Cu(II) ions.

    Science.gov (United States)

    Monier, M; Ibrahim, Amr A; Metwally, M M; Badawy, D S

    2015-11-01

    Surface ion-imprinted amino-functionalized cellulosic fibers (Cu-ABZ) were manufactured for efficient selective adsorption of Cu(2+) ions. The chemical modification steps had been characterized utilizing elemental analysis; Fourier transforms infrared (FTIR) along with wide angle X-ray diffraction (XRD) spectroscopy. Also, the morphological structure of the ion-imprinted and the non-imprinted (NI-ABZ) fibers were visualized and compared with that of the native cotton fibers using scanning electron microscope (SEM). In addition, the coordination mode by which the Cu(2+) ions bonded to the active sites were examined by both FTIR and X-ray photo electron spectra (XPS). Both Cu-ABZ and NI-ABZ were implemented in batch experiments for optimizing the conditions by which the Cu(2+) ions can be selectively removal from aqueous medium and pH 5 was the optimum for the metal ion extraction. Moreover, the kinetics and isotherm studies revealed that the adsorption data fitted with pseudo-second-order kinetic and Langmuir models with estimated maximum adsorption capacity 93.6mg/g. Also, the reusability studies indicated that the prepared ion-imprinted adsorbent maintains more than 95% of its original activity after fifth generation cycle.

  4. Biodegradation of polycyclic aromatic hydrocarbons (PAHs) by laccase from Trametes versicolor covalently immobilized on amino-functionalized SBA-15.

    Science.gov (United States)

    Bautista, Luis Fernando; Morales, Gabriel; Sanz, Raquel

    2015-10-01

    A covalent immobilization method based on glutaraldehyde and amino-functionalized SBA-15 supports has been successfully applied to covalently and stably immobilize laccase from Trametes versicolor. The resultant biocatalysts displayed high incorporation yields of enzyme and led to excellent biodegradation rates of selected HPAs models, i.e. naphthalene, phenanthrene and anthracene, in water. The nature of the hydrocarbon chain accompanying the amino group has been shown as determinant for the immobilization as well as for the activity and reusability of the materials. Thus, alkyl moieties displayed higher enzyme loadings than phenyl moieties, being more adequate the larger n-butyl tethering residue likely due to its higher mobility. Using the aminobutyl-based laccase-SBA-15, 82%, 73%, and 55% conversion of naphthalene, phenanthrene and anthracene, respectively, were achieved after 48 h, very close to the values obtained with free laccase under the same reaction conditions. On the other hand, aminopropyl-based laccase-SBA-15 biocatalysts displayed the best reusability properties, retaining higher activity after four repeated uses than the corresponding aminobutyl-based materials.

  5. Carboxyl- and amino-functionalized polystyrene nanoparticles differentially affect the polarization profile of M1 and M2 macrophage subsets.

    Science.gov (United States)

    Fuchs, Ann-Kathrin; Syrovets, Tatiana; Haas, Karina A; Loos, Cornelia; Musyanovych, Anna; Mailänder, Volker; Landfester, Katharina; Simmet, Thomas

    2016-04-01

    Macrophages are key regulators of innate and adaptive immune responses. Exposure to microenvironmental stimuli determines their polarization into proinflammatory M1 and anti-inflammatory M2 macrophages. M1 exhibit high expression of proinflammatory TNF-α and IL-1β, and M2 promote tissue repair, but likewise support tumor growth and cause immune suppression by expressing IL-10. Thus, the M1/M2 balance critically determines tissue homeostasis. By using carboxyl- (PS-COOH) and amino-functionalized (PS-NH2) polystyrene nanoparticles, the effects of surface decoration on the polarization of human macrophages were investigated. The nanoparticles did not compromise macrophage viability nor did they affect the expression of the M1 markers CD86, NOS2, TNF-α, and IL-1β. By contrast, in M2, both nanoparticles impaired expression of scavenger receptor CD163 and CD200R, and the release of IL-10. PS-NH2 also inhibited phagocytosis of Escherichia coli by both, M1 and M2. PS-COOH did not impair phagocytosis by M2, but increased protein mass in M1 and M2, TGF-β1 release by M1, and ATP levels in M2. Thus, nanoparticles skew the M2 macrophage polarization without affecting M1 markers. Given the critical role of the M1 and M2 polarization for the immunological balance in patients with cancer or chronic inflammation, functionalized nanoparticles might serve as tools for reprogramming the M1/M2 polarization.

  6. Amino-functionalized mesoporous silica modified glassy carbon electrode for ultra-trace copper(II) determination

    Energy Technology Data Exchange (ETDEWEB)

    Dai, Xingxin [College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, Jiangsu, 215123 (China); Qiu, Fagui [Department of Quartermaster Engineering, Jilin University, No. 5333, Xi' an Road, Changchun 130062 (China); Zhou, Xuan [College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, Jiangsu, 215123 (China); Long, Yumei, E-mail: yumeilong@suda.edu.cn [College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, Jiangsu, 215123 (China); The Key Lab of Health Chemistry and Molecular Diagnosis of Suzhou (China); Li, Weifeng, E-mail: liweifeng@suda.edu.cn [College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, Jiangsu, 215123 (China); Tu, Yifeng [College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, Jiangsu, 215123 (China)

    2014-10-27

    NH{sub 2}-MCM-41 modified glassy carbon electrode was prepared and it exhibited enhanced anodic stripping response toward Cu (II), which could result from the large surface area of MCM-41 and the good chelating ability of amine-group. The as-constructed electrochemical sensor showed excellent analytical properties in the determination of Cu{sup 2+} and was successfully used for real sample assays. - Highlights: • We report a facile method to selectively detect Cu{sup 2+} based on NH{sub 2}-MCM-41 as sensing platform. • NH{sub 2}-MCM-41 has good affinity toward Cu{sup 2+}. • Detection limit of 0.9 ng L{sup −1} and linear concentration range of 5–1000 ng L{sup −1} are achieved. • The method is successfully applied to detect Cu{sup 2+} in real samples. - Abstract: This paper described a facile and direct electrochemical method for the determination of ultra-trace Cu{sup 2+} by employing amino-functionalized mesoporous silica (NH{sub 2}-MCM-41) as enhanced sensing platform. NH{sub 2}-MCM-41 was prepared by using a post-grafting process and characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM) and fourier transform infrared (FTIR) spectroscopy. NH{sub 2}-MCM-41 modified glassy carbon (GC) electrode showed higher sensitivity for anodic stripping voltammetric (ASV) detection of Cu{sup 2+} than that of MCM-41 modified one. The high sensitivity was attributed to synergistic effect between MCM-41 and amino-group, in which the high surface area and special mesoporous morphology of MCM-41 can cause strong physical absorption, and amino-groups are able to chelate copper ions. Some important parameters influencing the sensor response were optimized. Under optimum experimental conditions the sensor linearly responded to Cu{sup 2+} concentration in the range from 5 to 1000 ng L{sup −1} with a detection limit of 0.9 ng L{sup −1} (S/N = 3). Moreover, the sensor possessed good stability and electrode renewability. In the end, the proposed

  7. MAGNET

    CERN Multimedia

    by B. Curé

    2011-01-01

    The magnet operation was very satisfactory till the technical stop at the end of the year 2010. The field was ramped down on 5th December 2010, following the successful regeneration test of the turbine filters at full field on 3rd December 2010. This will limit in the future the quantity of magnet cycles, as it is no longer necessary to ramp down the magnet for this type of intervention. This is made possible by the use of the spare liquid Helium volume to cool the magnet while turbines 1 and 2 are stopped, leaving only the third turbine in operation. This obviously requires full availability of the operators to supervise the operation, as it is not automated. The cryogenics was stopped on 6th December 2010 and the magnet was left without cooling until 18th January 2011, when the cryoplant operation resumed. The magnet temperature reached 93 K. The maintenance of the vacuum pumping was done immediately after the magnet stop, when the magnet was still at very low temperature. Only the vacuum pumping of the ma...

  8. MAGNET

    CERN Multimedia

    B. Curé

    2012-01-01

      The magnet was energised at the beginning of March 2012 at a low current to check all the MSS safety chains. Then the magnet was ramped up to 3.8 T on 6 March 2012. Unfortunately two days later an unintentional switch OFF of the power converter caused a slow dump. This was due to a misunderstanding of the CCC (CERN Control Centre) concerning the procedure to apply for the CMS converter control according to the beam-mode status at that time. Following this event, the third one since 2009, a discussion was initiated to define possible improvement, not only on software and procedures in the CCC, but also to evaluate the possibility to upgrade the CMS hardware to prevent such discharge from occurring because of incorrect procedure implementations. The magnet operation itself was smooth, and no power cuts took place. As a result, the number of magnetic cycles was reduced to the minimum, with only two full magnetic cycles from 0 T to 3.8 T. Nevertheless the magnet suffered four stops of the cryogeni...

  9. MAGNET

    CERN Multimedia

    Benoit Curé

    2010-01-01

    Operation of the magnet has gone quite smoothly during the first half of this year. The magnet has been at 4.5K for the full period since January. There was an unplanned short stop due to the CERN-wide power outage on May 28th, which caused a slow dump of the magnet. Since this occurred just before a planned technical stop of the LHC, during which access in the experimental cavern was authorized, it was decided to leave the magnet OFF until 2nd June, when magnet was ramped up again to 3.8T. The magnet system experienced a fault also resulting in a slow dump on April 14th. This was triggered by a thermostat on a filter choke in the 20kA DC power converter. The threshold of this thermostat is 65°C. However, no variation in the water-cooling flow rate or temperature was observed. Vibration may have been the root cause of the fault. All the thermostats have been checked, together with the cables, connectors and the read out card. The tightening of the inductance fixations has also been checked. More tem...

  10. MAGNET

    CERN Multimedia

    B. Curé

    2012-01-01

      Following the unexpected magnet stops last August due to sequences of unfortunate events on the services and cryogenics [see CMS internal report], a few more events and initiatives again disrupted the magnet operation. All the magnet parameters stayed at their nominal values during this period without any fault or alarm on the magnet control and safety systems. The magnet was stopped for the September technical stop to allow interventions in the experimental cavern on the detector services. On 1 October, to prepare the transfer of the liquid nitrogen tank on its new location, several control cables had to be removed. One cable was cut mistakenly, causing a digital input card to switch off, resulting in a cold-box (CB) stop. This tank is used for the pre-cooling of the magnet from room temperature down to 80 K, and for this reason it is controlled through the cryogenics control system. Since the connection of the CB was only allowed for a field below 2 T to avoid the risk of triggering a fast d...

  11. MAGNET

    CERN Multimedia

    B. Curé

    2012-01-01

      The magnet and its sub-systems were stopped at the beginning of the winter shutdown on 8th December 2011. The magnet was left without cooling during the cryogenics maintenance until 17th January 2012, when the cryoplant operation resumed. The magnet temperature reached 93 K. The vacuum pumping was maintained during this period. During this shutdown, the yearly maintenance was performed on the cryogenics, the vacuum pumps, the magnet control and safety systems, and the power converter and discharge lines. Several preventive actions led to the replacement of the electrovalve command coils, and the 20A DC power supplies of the magnet control system. The filters were cleaned on the demineralised water circuits. The oil of the diffusion pumps was changed. On the cryogenics, warm nitrogen at 343 K was circulated in the cold box to regenerate the filters and the heat exchangers. The coalescing filters have been replaced at the inlet of both the turbines and the lubricant trapping unit. The active cha...

  12. MAGNET

    CERN Multimedia

    Benoit Curé

    2010-01-01

    The magnet was successfully operated at the end of the year 2009 despite some technical problems on the cryogenics. The magnet was ramped up to 3.8 T at the end of November until December 16th when the shutdown started. The magnet operation met a few unexpected stops. The field was reduced to 3.5 T for about 5 hours on December 3rd due to a faulty pressure sensor on the helium compressor. The following day the CERN CCC stopped unintentionally the power converters of the LHC and the experiments, triggering a ramp down that was stopped at 2.7 T. The magnet was back at 3.8 T about 6 hours after CCC sent the CERN-wide command. Three days later, a slow dump was triggered due to a stop of the pump feeding the power converter water-cooling circuit, during an intervention on the water-cooling plant done after several disturbances on the electrical distribution network. The magnet was back at 3.8 T in the evening the same day. On December 10th a break occurred in one turbine of the cold box producing the liquid ...

  13. MAGNET

    CERN Multimedia

    B. Curé

    2013-01-01

      The magnet was operated without any problem until the end of the LHC run in February 2013, apart from a CERN-wide power glitch on 10 January 2013 that affected the CMS refrigerator, causing a ramp down to 2 T in order to reconnect the coldbox. Another CERN-wide power glitch on 15 January 2013 didn’t affect the magnet subsystems, the cryoplant or the power converter. At the end of the magnet run, the reconnection of the coldbox at 2.5 T was tested. The process will be updated, in particular the parameters of some PID valve controllers. The helium flow of the current leads was reduced but only for a few seconds. The exercise will be repeated with the revised parameters to validate the automatic reconnection process of the coldbox. During LS1, the water-cooling services will be reduced and many interventions are planned on the electrical services. Therefore, the magnet cryogenics and subsystems will be stopped for several months, and the magnet cannot be kept cold. In order to avoid unc...

  14. MAGNET

    CERN Multimedia

    B. Curé

    2011-01-01

    The CMS magnet has been running steadily and smoothly since the summer, with no detected flaw. The magnet instrumentation is entirely operational and all the parameters are at their nominal values. Three power cuts on the electrical network affected the magnet run in the past five months, with no impact on the data-taking as the accelerator was also affected at the same time. On 22nd June, a thunderstorm caused a power glitch on the service electrical network. The primary water cooling at Point 5 was stopped. Despite a quick restart of the water cooling, the inlet temperature of the demineralised water on the busbar cooling circuit increased by 5 °C, up to 23.3 °C. It was kept below the threshold of 27 °C by switching off other cooling circuits to avoid the trigger of a slow dump of the magnet. The cold box of the cryogenics also stopped. Part of the spare liquid helium volume was used to maintain the cooling of the magnet at 4.5 K. The operators of the cryogenics quickly restarted ...

  15. MAGNETS

    Science.gov (United States)

    Hofacker, H.B.

    1958-09-23

    This patent relates to nmgnets used in a calutron and more particularly to means fur clamping an assembly of magnet coils and coil spacers into tightly assembled relation in a fluid-tight vessel. The magnet comprises windings made up of an assembly of alternate pan-cake type coils and spacers disposed in a fluid-tight vessel. At one end of the tank a plurality of clamping strips are held firmly against the assembly by adjustable bolts extending through the adjacent wall. The foregoing arrangement permits taking up any looseness which may develop in the assembly of coils and spacers.

  16. MAGNET

    CERN Multimedia

    B. Curé

    2011-01-01

    The magnet ran smoothly in the last few months until a fast dump occurred on 9th May 2011. Fortunately, this occurred in the afternoon of the first day of the technical stop. The fast dump was due to a valve position controller that caused the sudden closure of a valve. This valve is used to regulate the helium flow on one of the two current leads, which electrically connects the coil at 4.5 K to the busbars at room temperature. With no helium flow on the lead, the voltage drop and the temperatures across the leads increase up to the defined thresholds, triggering a fast dump through the Magnet Safety System (MSS). The automatic reaction triggered by the MSS worked properly. The helium release was limited as the pressure rise was just at the limit of the safety valve opening pressure. The average temperature of the magnet reached 72 K. It took four days to recover the temperature and refill the helium volumes. The faulty valve controller was replaced by a spare one before the magnet ramp-up resumed....

  17. Facile synthesis of amino-functionalized titanium metal-organic frameworks and their superior visible-light photocatalytic activity for Cr(VI) reduction.

    Science.gov (United States)

    Wang, Hou; Yuan, Xingzhong; Wu, Yan; Zeng, Guangming; Chen, Xiaohong; Leng, Lijian; Wu, Zhibin; Jiang, Longbo; Li, Hui

    2015-04-09

    Porous metal-organic frameworks (MOFs) have been arousing a great interest in exploring the application of MOFs as photocatalyst in environment remediation. In this work, two different MOFs, Ti-benzenedicarboxylate (MIL-125(Ti)) and amino-functionalized Ti-benzenedicarboxylate (NH2-MIL-125(Ti)) were successfully synthesized via a facile solvothermal method. The MIL-125(Ti) and NH2-MIL-125(Ti) were well characterized by XRD, SEM, XPS, N2 adsorption-desorption measurements, thermogravimetric analysis and UV-vis diffuse reflectance spectra (DRS). It is revealed that the NH2-MIL-125(Ti) has well crystalline lattice, large surface area and mesoporous structure, chemical and thermal stability, and enhanced visible-light absorption up to 520 nm, which was associated with the chromophore (amino group) in the organic linker. Compared with MIL-125(Ti), NH2-MIL-125(Ti) exhibited more efficient photocatalytic activity for Cr(VI) reduction from aqueous solution under visible-light irradiation. The addition of hole scavenger, the hole scavenger concentration and the pH value of the reaction solution played important roles in the photo-catalytic reduction of Cr(VI). The presence of Ti(3+)-Ti(4+) intervalence electron transfer was the main reason for photo-excited electrons transportation from titanium-oxo clusters to Cr(VI), facilitating the Cr(VI) reduction under the acid condition. It was demonstrated that amino-functionalized Ti(IV)-based MOFs could be promising visible-light photocatalysts for the treatment of Cr(VI)-contained wastewater.

  18. Amino-functionalized mesoporous MCM-41 silica as an efficient adsorbent for water treatment: batch and fixed-bed column adsorption of the nitrate anion

    Science.gov (United States)

    Ebrahimi-Gatkash, Mehdi; Younesi, Habibollah; Shahbazi, Afsaneh; Heidari, Ava

    2015-11-01

    In the present study, amino-functionalized Mobil Composite Material No. 41 (MCM-41) was used as an adsorbent to remove nitrate anions from aqueous solutions. Mono-, di- and tri-amino functioned silicas (N-MCM-41, NN-MCM-41 and NNN-MCM-41) were prepared by post-synthesis grafting method. The samples were characterized by means of X-ray powder diffraction, FTIR spectroscopy, thermogravimetric analysis, scanning electron microscopy and nitrogen adsorption-desorption. The effects of pH, initial concentration of anions, and adsorbent loading were examined in batch adsorption system. Results of adsorption experiments showed that the adsorption capacity increased with increasing adsorbent loading and initial anion concentration. It was found that the Langmuir mathematical model indicated better fit to the experimental data than the Freundlich. According to the constants of the Langmuir equation, the maximum adsorption capacity for nitrate anion by N-MCM-41, NN-MCM-41 and NNN-MCM-41 was found to be 31.68, 38.58 and 36.81 mg/g, respectively. The adsorption kinetics were investigated with pseudo-first-order and pseudo-second-order model. Adsorption followed the pseudo-second-order rate kinetics. The coefficients of determination for pseudo-second-order kinetic model are >0.99. For continuous adsorption experiments, NNN-MCM-41 adsorbent was used for the removal of nitrate anion from solutions. Breakthrough curves were investigated at different bed heights, flow rates and initial nitrate anion concentrations. The Thomas and Yan models were utilized to calculate the kinetic parameters and to predict the breakthrough curves of different bed height. Results from this study illustrated the potential utility of these adsorbents for nitrate removal from water solution.

  19. Carbon coated magnetic nanoparticles as a novel magnetic solid phase extraction adsorbent for simultaneous extraction of methamphetamine and ephedrine from urine samples.

    Science.gov (United States)

    Taghvimi, Arezou; Hamishehkar, Hamed

    2017-01-15

    This paper develops a highly selective, specific and efficient method for simultaneous determination of ephedrine and methamphetamine by a new carbon coated magnetic nanoparticles (C/MNPs) as a magnetic solid phase extraction (MSPE) adsorbent in biological urine medium. The characterization of synthesized magnetic nano adsorbent was completely carried out by various characterization techniques like Fourier transform infrared (FT-IR) spectroscopy, powder x-ray diffraction (XRD), scanning electron microscopy (SEM) and vibrating sample magnetometer (VSM). Nine important parameters influencing extraction efficiency including amount of adsorbent, amounts of sample volume, pH, type and amount of extraction organic solvent, time of extraction and desorption, agitation rate and ionic strength of extraction medium, were studied and optimized. Under optimized extraction conditions, a good linearity was observed in the concentration range of 100-2000ng/mL for ephedrine and 100-2500ng/mL for methamphetamine. Analysis of positive urine samples was carried out by proposed method with the recovery of 98.71 and 97.87% for ephedrine and methamphetamine, respectively. The results indicated that carbon coated magnetic nanoparticles could be applied in clinical and forensic laboratories for simultaneous determination of abused drugs in urine media.

  20. MAGNET

    CERN Multimedia

    B. Curé

    2013-01-01

    The magnet is fully stopped and at room temperature. The maintenance works and consolidation activities on the magnet sub-systems are progressing. To consolidate the cryogenic installation, two redundant helium compressors will be installed as ‘hot spares’, to avoid the risk of a magnet downtime in case of a major failure of a compressor unit during operation. The screw compressors, their motors, the mechanical couplings and the concrete blocks are already available and stored at P5. The metallic structure used to access the existing compressors in SH5 will be modified to allow the installation of the two redundant ones. The plan is to finish the installation and commissioning of the hot spare compressors before the summer 2014. In the meantime, a bypass on the high-pressure helium piping will be installed for the connection of a helium drier unit later during the Long Shutdown 1, keeping this installation out of the schedule critical path. A proposal is now being prepared for the con...

  1. MAGNET

    CERN Multimedia

    B. Curé

    MAGNET During the winter shutdown, the magnet subsystems went through a full maintenance. The magnet was successfully warmed up to room temperature beginning of December 2008. The vacuum was broken later on by injecting nitrogen at a pressure just above one atmosphere inside the vacuum tank. This was necessary both to prevent any accidental humidity ingress, and to allow for a modification of the vacuum gauges on the vacuum tank and maintenance of the diffusion pumps. The vacuum gauges had to be changed, because of erratic variations on the measurements, causing spurious alarms. The new type of vacuum gauges has been used in similar conditions on the other LHC experiments and without problems. They are shielded against the stray field. The lubricants of the primary and diffusion pumps have been changed. Several minor modifications were also carried out on the equipment in the service cavern, with the aim to ease the maintenance and to allow possible intervention during operation. Spare sensors have been bough...

  2. MAGNET

    CERN Multimedia

    Benoit Curé

    2010-01-01

    The magnet worked very well at 3.8 T as expected, despite a technical issue that manifested twice in the cryogenics since June. All the other magnet sub-systems worked without flaw. The issue in the cryogenics was with the cold box: it could be observed that the cold box was getting progressively blocked, due to some residual humidity and air accumulating in the first thermal exchanger and in the adsorber at 65 K. This was later confirmed by the analysis during the regeneration phases. An increase in the temperature difference between the helium inlet and outlet across the heat exchanger and a pressure drop increase on the filter of the adsorber were observed. The consequence was a reduction of the helium flow, first compensated by the automatic opening of the regulation valves. But once they were fully opened, the flow and refrigeration power reduced as a consequence. In such a situation, the liquid helium level in the helium Dewar decreased, eventually causing a ramp down of the magnet current and a field...

  3. MAGNET

    CERN Multimedia

    Benoit Curé.

    The magnet operation restarted end of June this year. Quick routine checks of the magnet sub-systems were performed at low current before starting the ramps up to higher field. It appeared clearly that the end of the field ramp down to zero was too long to be compatible with the detector commissioning and operations plans. It was decided to perform an upgrade to keep the ramp down from 3.8T to zero within 4 hours. On July 10th, when a field of 1.5T was reached, small movements were observed in the forward region support table and it was decided to fix this problem before going to higher field. At the end of July the ramps could be resumed. On July 28th, the field was at 3.8T and the summer CRAFT exercise could start. This run in August went smoothly until a general CERN wide power cut took place on August 3rd, due to an insulation fault on the high voltage network outside point 5. It affected the magnet powering electrical circuit, as it caused the opening of the main circuit breakers, resulting in a fast du...

  4. MAGNET

    CERN Multimedia

    Benoit Curé

    The magnet subsystems resumed operation early this spring. The vacuum pumping was restarted mid March, and the cryogenic power plant was restarted on March 30th. Three and a half weeks later, the magnet was at 4.5 K. The vacuum pumping system is performing well. One of the newly installed vacuum gauges had to be replaced at the end of the cool-down phase, as the values indicated were not coherent with the other pressure measurements. The correction had to be implemented quickly to be sure no helium leak could be at the origin of this anomaly. The pressure measurements have been stable and coherent since the change. The cryogenics worked well, and the cool-down went quite smoothly, without any particular difficulty. The automated start of the turbines had to be fine-tuned to get a smooth transition, as it was observed that the cooling power delivered by the turbines was slightly higher than needed, causing the cold box to stop automatically. This had no consequence as the cold box safety system acts to keep ...

  5. MAGNET

    CERN Multimedia

    B. Curé

    During the winter shutdown, the magnet subsystems went through a full maintenance. The magnet was successfully warmed up to room temperature beginning of December 2008. The vacuum was broken later on by injecting nitrogen at a pressure just above one atmosphere inside the vacuum tank. This was necessary both to prevent any accidental humidity ingress, and to allow for a modification of the vacuum gauges on the vacuum tank and maintenance of the diffusion pumps. The vacuum gauges had to be changed, because of erratic variations on the measurements, causing spurious alarms. The new type of vacuum gauges has been used in similar conditions on the other LHC experiments and without problems. They are shielded against the stray field. The lubricants of the primary and diffusion pumps have been changed. Several minor modifications were also carried out on the equipment in the service cavern, with the aim to ease the maintenance and to allow possible intervention during operation. Spare sensors have been bought. Th...

  6. Amino-functionalized poly(L-lactide lamellar single crystals as a valuable substrate for delivery of HPV16-E7 tumor antigen in vaccine development

    Directory of Open Access Journals (Sweden)

    Di Bonito P

    2015-05-01

    Full Text Available Paola Di Bonito,1 Linda Petrone,1 Gabriele Casini,2 Iolanda Francolini,2 Maria Grazia Ammendolia,3 Luisa Accardi,1 Antonella Piozzi,2 Lucio D’Ilario,2 Andrea Martinelli2 1Department of Infectious, Parasitic and Immune-mediated Diseases, Italian National Institute of Health, 2Department of Chemistry, Sapienza University of Rome, Rome, Italy; 3Department of Technology and Health, Italian National Institute of Health, Rome, Italy Background: Poly(L-lactide (PLLA is a biodegradable polymer currently used in many biomedical applications, including the production of resorbable surgical devices, porous scaffolds for tissue engineering, nanoparticles and microparticles for the controlled release of drugs or antigens. The surfaces of lamellar PLLA single crystals (PLLAsc were provided with amino groups by reaction with a multifunctional amine and used to adsorb an Escherichia coli-produced human papillomavirus (HPV16-E7 protein to evaluate its possible use in antigen delivery for vaccine development.Methods: PLLA single crystals were made to react with tetraethylenepentamine to obtain amino-functionalized PLLA single crystals (APLLAsc. Pristine and amino-functionalized PLLAsc showed a two-dimensional microsized and one-dimensional nanosized lamellar morphology, with a lateral dimension of about 15–20 µm, a thickness of about 12 nm, and a surface specific area of about 130 m2/g. Both particles were characterized and loaded with HPV16-E7 before being administered to C57BL/6 mice for immunogenicity studies. The E7-specific humoral-mediated and cell-mediated immune response as well as tumor protective immunity were analyzed in mice challenged with TC-1 cancer cells.Results: Pristine and amino-functionalized PLLAsc adsorbed similar amounts of E7 protein, but in protein-release experiments E7-PLLAsc released a higher amount of protein than E7-APLLAsc. When the complexes were dried for observation by scanning electron microscopy, both samples showed a

  7. Facile synthesis of amino-functionalized titanium metal-organic frameworks and their superior visible-light photocatalytic activity for Cr(VI) reduction

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Hou [College of Environmental Science and Engineering, Hunan University, Changsha 410082 (China); Key Laboratory of Environment Biology and Pollution Control, Hunan University, Ministry of Education, Changsha 410082 (China); Yuan, Xingzhong, E-mail: yxz@hnu.edu.cn [College of Environmental Science and Engineering, Hunan University, Changsha 410082 (China); Key Laboratory of Environment Biology and Pollution Control, Hunan University, Ministry of Education, Changsha 410082 (China); Wu, Yan [College of Environment and Energy, South China University of Technology, Guangzhou 510006 (China); Zeng, Guangming [College of Environmental Science and Engineering, Hunan University, Changsha 410082 (China); Key Laboratory of Environment Biology and Pollution Control, Hunan University, Ministry of Education, Changsha 410082 (China); Chen, Xiaohong [School of Business, Central South University, Changsha 410083 (China); Leng, Lijian; Wu, Zhibin; Jiang, Longbo [College of Environmental Science and Engineering, Hunan University, Changsha 410082 (China); Key Laboratory of Environment Biology and Pollution Control, Hunan University, Ministry of Education, Changsha 410082 (China); Li, Hui [Institute of Bio-energy, Hunan Academy of Forestry, Changsha 410004 (China)

    2015-04-09

    Highlights: • NH{sub 2} functionalized MIL-125(Ti) was fabricated by a facile solvothermal method. • The photocatalyst could reduce Cr(VI)–Cr(III) under visible light irradiation. • The Ti{sup 3+}–Ti{sup 4+} intervalence electron transfer is important for Cr(VI) reduction. • Used NH{sub 2}-MIL-125(Ti) can be recycled for the photocatalytic reduction. - Abstract: Porous metal-organic frameworks (MOFs) have been arousing a great interest in exploring the application of MOFs as photocatalyst in environment remediation. In this work, two different MOFs, Ti-benzenedicarboxylate (MIL-125(Ti)) and amino-functionalized Ti-benzenedicarboxylate (NH{sub 2}-MIL-125(Ti)) were successfully synthesized via a facile solvothermal method. The MIL-125(Ti) and NH{sub 2}-MIL-125(Ti) were well characterized by XRD, SEM, XPS, N{sub 2} adsorption–desorption measurements, thermogravimetric analysis and UV–vis diffuse reflectance spectra (DRS). It is revealed that the NH{sub 2}-MIL-125(Ti) has well crystalline lattice, large surface area and mesoporous structure, chemical and thermal stability, and enhanced visible-light absorption up to 520 nm, which was associated with the chromophore (amino group) in the organic linker. Compared with MIL-125(Ti), NH{sub 2}-MIL-125(Ti) exhibited more efficient photocatalytic activity for Cr(VI) reduction from aqueous solution under visible-light irradiation. The addition of hole scavenger, the hole scavenger concentration and the pH value of the reaction solution played important roles in the photo-catalytic reduction of Cr(VI). The presence of Ti{sup 3+}–Ti{sup 4+} intervalence electron transfer was the main reason for photo-excited electrons transportation from titanium-oxo clusters to Cr(VI), facilitating the Cr(VI) reduction under the acid condition. It was demonstrated that amino-functionalized Ti(IV)-based MOFs could be promising visible-light photocatalysts for the treatment of Cr(VI)-contained wastewater.

  8. One-step synthesis of amino-functionalized ultrasmall near infrared-emitting persistent luminescent nanoparticles for in vitro and in vivo bioimaging

    Science.gov (United States)

    Shi, Junpeng; Sun, Xia; Zhu, Jianfei; Li, Jinlei; Zhang, Hongwu

    2016-05-01

    Near infrared (NIR)-emitting persistent luminescent nanoparticles (NPLNPs) have attracted much attention in bioimaging because they can provide long-term in vivo imaging with a high signal-to-noise ratio (SNR). However, conventional NPLNPs with large particle sizes that lack modifiable surface groups suffer from many serious limitations in bioimaging. Herein, we report a one-step synthesis of amino-functionalized ZnGa2O4:Cr,Eu nanoparticles (ZGO) that have an ultrasmall size, where ethylenediamine served as the reactant to fabricate the ZGO as well as the surfactant ligand to control the nanocrystal size and form surface amino groups. The ZGO exhibited a narrow particle size distribution, a bright NIR emission and a long afterglow luminescence. In addition, due to the excellent conjugation ability of the surface amino groups, the ZGO can be easily conjugated with many bio-functional molecules, which has been successfully utilized to realize in vitro and in vivo imaging. More importantly, the ZGO achieved re-excitation imaging using 650 nm and 808 nm NIR light in situ, which is advantageous for long-term and higher SNR bioimaging.Near infrared (NIR)-emitting persistent luminescent nanoparticles (NPLNPs) have attracted much attention in bioimaging because they can provide long-term in vivo imaging with a high signal-to-noise ratio (SNR). However, conventional NPLNPs with large particle sizes that lack modifiable surface groups suffer from many serious limitations in bioimaging. Herein, we report a one-step synthesis of amino-functionalized ZnGa2O4:Cr,Eu nanoparticles (ZGO) that have an ultrasmall size, where ethylenediamine served as the reactant to fabricate the ZGO as well as the surfactant ligand to control the nanocrystal size and form surface amino groups. The ZGO exhibited a narrow particle size distribution, a bright NIR emission and a long afterglow luminescence. In addition, due to the excellent conjugation ability of the surface amino groups, the ZGO can be

  9. MAGNET

    CERN Multimedia

    Benoit Curé

    2013-01-01

    Maintenance work and consolidation activities on the magnet cryogenics and its power distribution are progressing according to the schedules. The manufacturing of the two new helium compressor frame units has started. The frame units support the valves, all the sensors and the compressors with their motors. This activity is subcontracted. The final installation and the commissioning at CERN are scheduled for March–April 2014. The overhauls of existing cryogenics equipment (compressors, motors) are in progress. The reassembly of the components shall start in early 2014. The helium drier, to be installed on the high-pressure helium piping, has been ordered and will be delivered in the first trimester of 2014. The power distribution for the helium compressors in SH5 on the 3.3kV network is progressing. The 3.3kV switches, between each compressor and its hot spare compressor, are being installed, together with the power cables for the new compressors. The 3.3kV electrical switchboards in SE5 will ...

  10. MAGNET

    CERN Multimedia

    Benoit Curé

    The cooling down to the nominal temperature of 4.5 K was achieved at the beginning of August, in conjunction with the completion of the installation work of the connection between the power lines and the coil current leads. The temperature gradient on the first exchanger of the cold box is now kept within the nominal range. A leak of lubricant on a gasket of the helium compressor station installed at the surface was observed and several corrective actions were necessary to bring the situation back to normal. The compressor had to be refilled with lubricant and a regeneration of the filters and adsorbers was necessary. The coil cool down was resumed successfully, and the cryogenics is running since then with all parameters being nominal. Preliminary tests of the 20kA coil power supply were done earlier at full current through the discharge lines into the dump resistors, and with the powering busbars from USC5 to UXC5 without the magnet connected. On Monday evening August 25th, at 8pm, the final commissionin...

  11. MAGNET

    CERN Multimedia

    B. Curé

    The first phase of the commissioning ended in August by a triggered fast dump at 3T. All parameters were nominal, and the temperature recovery down to 4.5K was carried out in two days by the cryogenics. In September, series of ramps were achieved up to 3 and finally 3.8T, while checking thoroughly the detectors in the forward region, measuring any movement of and around the HF. After the incident of the LHC accelerator on September 19th, corrective actions could be undertaken in the forward region. When all these displacements were fully characterized and repetitive, with no sign of increments in displacement at each field ramp, it was possible to start the CRAFT, Cosmic Run at Four Tesla (which was in fact at 3.8T). The magnet was ramped up to 18.16kA and the 3 week run went smoothly, with only 4 interruptions: due to the VIP visits on 21st October during the LHC inauguration day; a water leak on the cooling demineralized water circuit, about 1 l/min, that triggered a stop of the cooling pumps, and resulte...

  12. Magnetic

    Science.gov (United States)

    Aboud, Essam; El-Masry, Nabil; Qaddah, Atef; Alqahtani, Faisal; Moufti, Mohammed R. H.

    2015-06-01

    The Rahat volcanic field represents one of the widely distributed Cenozoic volcanic fields across the western regions of the Arabian Peninsula. Its human significance stems from the fact that its northern fringes, where the historical eruption of 1256 A.D. took place, are very close to the holy city of Al-Madinah Al-Monawarah. In the present work, we analyzed aeromagnetic data from the northern part of Rahat volcanic field as well as carried out a ground gravity survey. A joint interpretation and inversion of gravity and magnetic data were used to estimate the thickness of the lava flows, delineate the subsurface structures of the study area, and estimate the depth to basement using various geophysical methods, such as Tilt Derivative, Euler Deconvolution and 2D modeling inversion. Results indicated that the thickness of the lava flows in the study area ranges between 100 m (above Sea Level) at the eastern and western boundaries of Rahat Volcanic field and getting deeper at the middle as 300-500 m. It also showed that, major structural trend is in the NW direction (Red Sea trend) with some minor trends in EW direction.

  13. Construction of an electrochemical sensor based on amino-functionalized metal-organic frameworks for differential pulse anodic stripping voltammetric determination of lead.

    Science.gov (United States)

    Wang, Yang; Ge, Huali; Wu, Yichun; Ye, Guiqin; Chen, Huanhuan; Hu, Xiaoya

    2014-11-01

    Metal-organic frameworks composite materials have received tremendous attention because of their versatile structures and tunable porosity for various applications. Herein, amino-functionalized metal-organic frameworks (NH2-Cu3(BTC)2; BTC=benzene-1,3,5-tricarboxylate) was prepared and used as a novel electrode modifier for the determination of trace levels of lead. NH2-Cu3(BTC)2 shows quite a good capability for the efficient adsorption of lead from aqueous solutions. The parameters affecting the electrochemical process, such as electrolyte solution pH, the amount of NH2-Cu3(BTC)2 suspension, accumulation potential and accumulation time, were investigated in detail. Under the optimal conditions, the electrochemical sensor exhibited a linear response to the concentration of lead in the range of 1.0×10(-8)-5.0×10(-7) mol L(-1) (R(2)=0.9951) with a detection limit of 5.0×10(-9) mol L(-1). The relative standard deviation of 11 successive scans was 3.10% for 1.0×10(-8) mol L(-1) lead. The method was validated with certified reference material (stream sediment and milk powder) and the analytical results coincided well with the certified values. Furthermore, the method was successfully applied to the determination of target analytes in tap and lake water samples and good recoveries were obtained from different spiked values.

  14. Amino-Functionalized Multiwalled Carbon Nanotubes Lead to Successful Ring-Opening Polymerization of Poly(ε-caprolactone): Enhanced Interfacial Bonding and Optimized Mechanical Properties.

    Science.gov (United States)

    Roumeli, Eleftheria; Papageorgiou, Dimitrios G; Tsanaktsis, Vasilios; Terzopoulou, Zoe; Chrissafis, Konstantinos; Avgeropoulos, Apostolos; Bikiaris, Dimitrios N

    2015-06-01

    In this work, the synthesis, structural characteristics, interfacial bonding, and mechanical properties of poly(ε-caprolactone) (PCL) nanocomposites with small amounts (0.5, 1.0, and 2.5 wt %) of amino-functionalized multiwalled carbon nanotubes (f-MWCNTs) prepared by ring-opening polymerization (ROP) are reported. This method allows the creation of a covalent-bonding zone on the surface of nanotubes, which leads to efficient debundling and therefore satisfactory dispersion and effective load transfer in the nanocomposites. The high covalent grafting extent combined with the higher crystallinity provide the basis for a significant enhancement of the mechanical properties, which was detected in the composites with up to 1 wt % f-MWCNTs. Increasing filler concentration encourages intrinsic aggregation forces, which allow only minor grafting efficiency and poorer dispersion and hence inferior mechanical performance. f-MWCNTs also cause a significant improvement on the polymerization reaction of PCL. Indeed, the in situ polymerization kinetics studies reveal a significant decrease in the reaction temperature, by a factor of 30-40 °C, combined with accelerated the reaction kinetics during initiation and propagation and a drastically reduced effective activation energy.

  15. Effective Removal of Tetracycline from Aqueous Solution by Organic Acid-Coated Magnetic Nanoparticles.

    Science.gov (United States)

    Guo, Liang; Liang, Yuyan; Chen, Xuelan; Xu, Wei; Wu, Kesheng; Wei, Hua; Xiong, Yonghua

    2016-03-01

    Self-assembled iron oxide nanocomposites are good magnetic nano-adsorbents that can be prepared using simple methods. Four types of organic acid-functionalised (oleic acid, undecenoic acid, caprylic acid or hexanoic acid) magnetic nanoparticles (MNPs) were synthesised through a one-pot chemisorption method for the removal of tetracycline (TC) from aqueous solution. The undecenoic acid-coated MNPs (UA-MNPs) exhibited the highest adsorption efficiency and can be easily retrieved with a low-gradient magnetic separator (0.4 Tesla) at pH 5.0 aqueous solution. The TC adsorption process on the UA-MNPs followed the Langmuir isotherm and the maximum adsorption capacities increased from 86.96 mg g(-1) to 222.2 mg g(-1) with the increase in temperature from 288 K to 318 K. The kinetics of adsorption fits pseudo-second-order model perfectly with a rate constant, 5.946 g mg(-1) min(-1) at 298 K. The positive values of the enthalpy (AH) and the negative value of the free energy (AG) indicated an endothermic and spontaneous adsorption process of TC on the UA-MNPs. Moreover, the UA-MNPs possessed excellent ability to adsorb the other three major types of TC antibiotics, including chlortetracycline, oxytetracycline and doxycycline.

  16. A porous carbon derived from amino-functionalized material of Institut Lavoisier as a solid-phase microextraction fiber coating for the extraction of phthalate esters from tea.

    Science.gov (United States)

    Liang, Weiqian; Wang, Juntao; Zang, Xiaohuan; Wang, Chun; Wang, Zhi

    2016-04-01

    In this work, a porous carbon derived from amino-functionalized material of Institut Lavoisier (C-NH2 -MIL-125) was prepared and coated onto a stainless-steel wire through sol-gel technique. The coated fiber was used for the solid-phase microextraction of trace levels of phthalate esters (diallyl phthalate, di-iso-butyl ortho-phthalate, di-n-butyl ortho-phthalate, benzyl-n-butyl ortho-phthalate, and bis(2-ethylhexy) ortho-phthalate) from tea beverage samples before gas chromatography with mass spectrometric analysis. Several experimental parameters that could influence the extraction efficiency such as extraction time, extraction temperature, sample pH, sample salinity, stirring rate, desorption temperature and desorption time, were investigated. Under the optimal conditions, the linearity existed in the range of 0.05-30.00 μg/L for green jasmine tea beverage samples, and 0.10-30.00 μg/L for honey jasmine tea beverage samples, with the correlation coefficients (r) ranging from 0.9939 to 0.9981. The limits of detection of the analytes for the method were 2.0-3.0 ng/L for green jasmine tea beverage sample, and 4.0-5.0 ng/L for honey jasmine tea beverage sample, depending on the compounds. The recoveries of the analytes for the spiked samples were in the range of 82.0-106.0%, and the precision, expressed as the relative standard deviations, was less than 11.1%.

  17. Preparation and Characterization of Amino-functionalized Silica Nano-particles%氨基官能化介孔二氧化硅的制备和表征

    Institute of Scientific and Technical Information of China (English)

    钟莉; 许艳玲; 杨雪莲; 王倩; 严伟; 石善滕; 李晴

    2016-01-01

    采用不同试验方法合成介孔二氧化硅纳米粒子(MSN),分别对不同方法所得样品进行粒径分析。结果得出:采用NaOH做pH调节剂,以乙醇与水的适宜比例做溶剂,在一定条件下所制得的介孔二氧化硅粒子粒径分布相对均匀,均在200~300 nm间。而后以此方法制得所需样品,分别采用盐酸酸化和煅烧两种方法除去模板剂CTAB,得到MSN,然后在其表面接枝上了-NH2,得到了氨基官能化介孔二氧化硅,并利用TGA、FTIR等方法对产物的结构进行了表征。%Mesoporous silica nano-particles(MSN) were synthesized using different experimental methods, respectively. The result of zize analysis showed that using NaOH as pH adjusting agent, a suitable proportion of ethanol and water as solvent, in certain conditions prepared the MSN particle, which has relatively uniform and concentrated particle size distribution, between 200 nm to 300 nm. The preferred sample prepared in this way, used hydrochloric acid or calcined to romove template CTAB, and then grafted -NH2 on its surface, to obtain amino-functionalized medium mesoporous silica. The TGA, FTIR were used to characterize the product.

  18. One-step synthesis of water-dispersible cysteine functionalized magnetic Fe{sub 3}O{sub 4} nanoparticles for mercury(II) removal from aqueous solutions

    Energy Technology Data Exchange (ETDEWEB)

    Shen, Xiaofang, E-mail: xfshen@jiangnan.edu.cn [State Key Laboratory of Dairy Biotechnology, Technology Center, Bright Dairy and Food Co. Ltd., Shanghai 200436 (China); State Key Laboratory of Food Science and Technology, School of Food Science and Technology, Jiangnan University, Wuxi 214122 (China); Wang, Qin; Chen, WenLing; Pang, Yuehong [State Key Laboratory of Food Science and Technology, School of Food Science and Technology, Jiangnan University, Wuxi 214122 (China)

    2014-10-30

    Graphical abstract: Using Fe{sup 2+} as precursors, air as oxidant and cysteine as protectant, this novel cysteine functionalized Fe{sub 3}O{sub 4} magnetic nanoparticles (Cys-Fe{sub 3}O{sub 4} MNPs) was facilely one-pot synthesized at room temperature by oxidation–precipitation method with the assistance of sonication. Then the Cys-Fe{sub 3}O{sub 4} MNPs were demonstrated as an inexpensive and quite efficient magnetic nano-adsorbent for as high as 95% Hg(II) removal efficiency. These results indicated that Cys-Fe{sub 3}O{sub 4} MNPs is a potentially attractive material for the removal of Hg(II) from water. - Highlights: • A simplified one-step synthesis method of superparamagnetic Cys-Fe{sub 3}O{sub 4} MNPs was developed. • It was synthesized at room temperature by oxidation-precipitation method with the assistance of sonication. • It was demonstrated as an inexpensive and quite efficient magnetic nano-adsorbent for Hg(II) removal. - Abstract: Cysteine functionalized Fe{sub 3}O{sub 4} magnetic nanoparticles (Cys-Fe{sub 3}O{sub 4} MNPs) were prepared facilely for Hg(II) removal from aqueous solutions. Using Fe{sup 2+} as precursors, air as oxidant and Cys as protectant, this novel material was one-pot synthesis at room temperature by oxidation–precipitation method with the assistance of sonication. The MNPs were characterized by TEM, VSM, FTIR, X-ray powder diffraction analysis (XRD) and TGA methods. Under the optimum experimental conditions, the removal efficiency was as high as 95% and the maximum sorption capacity is found to be 380 mg/mol for Hg(II). Study on adsorption kinetics shows that adsorption of Hg(II) onto Cys-Fe{sub 3}O{sub 4} MNPs follows pseudo-first-order kinetic model and the adsorption rate constant was 0.22 min{sup −1}. Additionally, the Hg(II)-loaded Cys-Fe{sub 3}O{sub 4} MNPs could be easily regenerated up to 95% using 1.0 M acetic acid. These results indicated that Cys-Fe{sub 3}O{sub 4} MNPs is a potentially attractive material

  19. Facile preparation of amino functionalized graphene oxide decorated with Fe3O4 nanoparticles for the adsorption of Cr(VI)

    Science.gov (United States)

    Zhao, Donglin; Gao, Xuan; Wu, Changnian; Xie, Rong; Feng, Shaojie; Chen, Changlun

    2016-10-01

    A novel ternary magnetic composite consisting of graphene oxide (GO), diethylenetriamine and Fe3O4 nanoparticles (AMGO) were synthesized by a facile one-step reaction route and characterized. The AMGO was applied as a magnetic adsorbent for the Cr(VI) removal from aqueous solutions and the magnetic separation process only took 40 s. The maximum adsorption capacity of the AMGO for Cr(VI) was 123.4 mg/g, displaying a high efficiency for the removal of Cr(VI), which was much higher than that of MGO. The removal process was pH dependence, endothermic and spontaneous. The pseudo-second-order model described well the adsorption kinetic data and the Langmuir isotherm model fitted the experimental data better than the Freundlich isotherm model. XPS analysis revealed that the Cr(VI) was reduced to the low-toxicity Cr(III) during the adsorption process. Both the Cr(VI) adsorption and subsequent reduction of adsorbed Cr(VI) to Cr(III) contributed to the Cr(VI) removal. In addition, the excellent reproducibility indicate that the AMGO may be a promising adsorption material for the separation and preconcentration of Cr(VI) ions from aqueous solutions in environmental pollution cleanup.

  20. Ultrasonic-assisted synthesis and magnetic studies of iron oxide/MCM-41 nanocomposite

    Energy Technology Data Exchange (ETDEWEB)

    Ursachi, Irina [Department of Physics ' Alexandru Ioan Cuza' University of Iasi, 11 Carol I Boulevard, 700506 Iasi (Romania); Vasile, Aurelia [Department of Chemistry, ' Alexandru Ioan Cuza' University of Iasi, 11 Carol I Boulevard, 700506 Iasi (Romania); Ianculescu, Adelina [Department of Oxide Materials and Engineering, Polytechnics University of Bucharest, 1-7 Gh. Polizu, 011061 Bucharest (Romania); Vasile, Eugeniu [METAV S.A., Research and Development, 31 C.A. Rosetti, 020011, Bucharest (Romania); Stancu, Alexandru, E-mail: alstancu@uaic.ro [Department of Physics ' Alexandru Ioan Cuza' University of Iasi, 11 Carol I Boulevard, 700506 Iasi (Romania)

    2011-11-01

    Highlights: {yields} A quick and facile route for the synthesis of iron oxide/MCM-41 nanocomposite. {yields} Magnetic nanoparticles were stabilized inside the pores of mesoporous silica MCM-41. {yields} The pore size of MCM-41 dictates the properties of iron oxide nanoparticles. {yields} The procedure provides a narrow size distribution of magnetic nanoparticles. - Abstract: Iron oxide nanoparticles were stabilized within the pores of mesoporous silica MCM-41 amino-functionalized by a sonochemical method. Formation of iron oxide nanoparticles inside the mesoporous channels of amino-functionalized MCM-41 was realized by wet impregnation using iron nitrate, followed by calcinations at 550 deg. C in air. The effect of functionalization level on structural and magnetic properties of obtained nanocomposites was studied. The resulting materials were characterized by powder X-ray diffraction (XRD), high-resolution transmission electron microscopy and selected area electron diffraction (HRTEM and SAED), vibrating sample and superconducting quantum interface magnetometers (VSM and SQUID) and nitrogen adsorption-desorption isotherms measurements. The HRTEM images reveal that the most of the iron oxide nanoparticles were dispersed inside the mesopores of silica matrix and the pore diameter of the amino-functionalized MCM-41 matrix dictates the particle size of iron oxide nanoparticles. The obtained material possesses mesoporous structure and interesting magnetic properties. Saturation magnetization value of magnetic iron oxide nanopatricles stabilized in MCM-41 amino-functionalized by in situ sonochemical synthesis was 1.84 emu g{sup -1}. An important finding is that obtained magnetic nanocomposite materials exhibit enhanced magnetic properties than those of iron oxide/MCM-41 nanocomposite obtained by conventional method. The described method is providing a rather short preparation time and a narrow size distribution of iron oxide nanoparticles.

  1. Determination of polycyclic aromatic hydrocarbons in coffee and tea samples by magnetic solid-phase extraction coupled with HPLC-FLD.

    Science.gov (United States)

    Shi, Yating; Wu, Hao; Wang, Chaoqiong; Guo, Xiaozhen; Du, Juanli; Du, Liming

    2016-05-15

    This study reports the synthesis of a benign nano-adsorbent based on an ionic liquid of immobilized Fe3O4@3-(Trimethoxysilyl)propyl methacrylate@ionic liquid magnetic nanoparticles (Fe3O4@MPS@IL NPs). This material was applied to the magnetic solid phase extraction of seven heavy molecular weight polycyclic aromatic hydrocarbons (PAHs) from coffee and tea samples for high performance liquid chromatography coupled with fluorescence detection. The effects of various parameters of the analytical method were investigated, including pH, sorbent amount, desorption solvent, desorption volume, and extraction and desorption time. Under the optimized conditions, good linearities were obtained, with correlation coefficients (R(2)) between 0.9987 and 0.9998. The detection limits of the proposed method were in the range of 0.1-10ngL(-1). The spiked recoveries of the seven PAHs in coffee and tea samples ranged from 87.5% to 104.5%, with RSDs of less than 3.7%. In addition, a satisfactory reproducibility was achieved, with intra- and inter-day precisions with RSDs of less than 3.1% and 3.8%, respectively.

  2. Organic-inorganic hybrid polymer-encapsulated magnetic nanobead catalysts.

    Science.gov (United States)

    Arai, Takayoshi; Sato, Toru; Kanoh, Hirofumi; Kaneko, Katsumi; Oguma, Koichi; Yanagisawa, Akira

    2008-01-01

    A new strategy for the encapsulation of magnetic nanobeads was developed by using the in situ self-assembly of an organic-inorganic hybrid polymer. The hybrid polymer of {[Cu(bpy)(BF(4))(2)(H(2)O)(2)](bpy)}(n) (bpy=4,4'-bipyridine) was constructed on the surface of amino-functionalized magnetic beads and the resulting hybrid-polymer-encapsulated beads were utilized as catalysts for the oxidation of silyl enolates to provide the corresponding alpha-hydroxy carbonyl compounds in high yield. After the completion of the reaction, the catalyst was readily recovered by magnetic separation and the recovered catalyst could be reused several times. Because the current method did not require complicated procedures for incorporating the catalyst onto the magnetic beads, the preparation and the application of various other types of organic-inorganic hybrid-polymer-coated magnetic beads could be possible.

  3. Adsorption-based CO2 Capture by Amino-functionalized Pore-expanded MCM-41 Composite%氨基官能化的扩孔 MCM-41复合材料吸附捕集 CO2

    Institute of Scientific and Technical Information of China (English)

    陈超; 董宇翔

    2015-01-01

    Pore-expanded mesoporous silica ( MCM-41) was synthesized and employed as a host for grafting 3-[2-(2-aminoethylamino)ethylamino]propyl trimethoxysilane to obtain an amino-functionalized mesoporous silica compos-ite.The pore-expanded MCM-41 before and after amine immobilization were characterized by N 2 adsorption-desorption measurement , fourier-transform infrared spectroscopy , and thermal gravimetric analysis .CO2 capture performances of samples were then examined .Results showed that surface area , pore volume, and pore size of amino-functionalized pore-expanded MCM-41 composite were lower than those of pore-expanded MCM-41.At the same time, amino-func-tionalized pore-expanded MCM-41 composite showed much higher CO 2 adsorption capacity than that of pore-expanded MCM-41 only ( their CO2 capture capacity is 28 mg/g and 76 mg/g, respectively ) , and excellent stability in the cyclic CO2 adsorption-desorption experiments .%制备了扩孔的介孔氧化硅MCM-41,然后以其为载体,通过化学接枝法将3-[2-(2-氨基乙基氨基)乙基氨基]丙基-三甲氧基硅烷嫁接到其介孔结构中,制备了氨基官能化的介孔氧化硅复合材料。通过 N2吸附脱附实验、红外光谱、热重分析等手段对氨基官能化前后扩孔 MCM-41的物理化学属性进行了表征,然后考察了复合材料对CO2的吸附捕集性能。结果表明:与单纯扩孔 MCM-41相比,氨基官能化的扩孔 MCM-41复合材料的比表面积、总孔容及孔径均减小;同时,所制复合材料对 CO2的吸附量明显增大(两者的 CO2吸附量分别为28 mg/g 和76 mg/g),且在循环CO2吸附脱附实验中呈现出优异的稳定性。

  4. 胺基修饰的介孔二氧化硅选择性降低卷烟烟气中的氢氰酸%Selectively Reducing HCN Delivery in Mainstream Cigarette Smoke with Amino-functionalized Mesoporous Silica Materials

    Institute of Scientific and Technical Information of China (English)

    周宛虹; 孙文梁; 王律; 周懿华; 王源; 高汉华

    2013-01-01

    In order to selectively reduce the delivery of HCN in mainstream cigarette smoke, an amino-functionalized mesoporous silica material (MCM-41-NH2) was prepared and characterized by means of scanning electron microscopy (SEM), X-ray diffraction (XRD), specific surface area and pore size analyzer (BET) and "C solid-state nuclear magnetic resonance (NMR), then the prepared material was applied to cigarette filter to reduce the deliveries of harmful components in cigarette smoke. The results showed that: 1) Comparing with MCM-41 material, the crystal form of MCM-41-NH2 did not change significantly, however its pore size and specific surface area were reduced by 50%. 2) When MCM-41-NH2 material was added into cigarette filter, up to 25.7% of HCN in mainstream cigarette smoke was selectively reduced, while the physical parameters of cigarette and the deliveries of routine smoke components were basically the same as those of reference cigarette.%为选择性降低卷烟主流烟气中氢氰酸(HCN)的释放量,制备了一种胺基功能化的介孔二氧化硅材料(MCM-41-NH2),运用扫描电镜(SEM)、X-射线衍射(XRD)、比表面积孔径分析(BET)以及13C固体核磁共振谱(”C-NMR)对材料进行了表征,并将材料添加于卷烟滤嘴进行了烟气减害测试.结果表明:①与MCM-41材料相比,MCM-41-NH2的晶型无明显改变,但孔径和比表面积下降了50%.②该材料对卷烟主流烟气中HCN的选择性降低率达到25.7%,而烟支物理参数及烟气常规成分释放量与对照卷烟基本一致.

  5. 氨基功能化SBA-15介孔分子筛的制备与表征%Preparation and Characterization of Amino-functionalized Mesoporous Silica SBA-15

    Institute of Scientific and Technical Information of China (English)

    田博士; 刘少华; 刘艳艳; 詹秀环; 姚新建; 王子云

    2011-01-01

    Amino-functionalized NH2-SBA-15 mesoporous materials ( shorter form NH2-SBA-15 ) were prepared by a post-synthesis method using 3-aminopropyltriethoxysilane as the coupling agent. The structure and performances of NH2-SBA-15 were characterized by FT-IR, element analysis, XRD,SEM and N2 adsorption/desorption. The results showed that amine was successfully grafted on the surface of SBA-15 and the NH2-SBA-15 possessed a well ordered hexagonal mesoporous structure.Compared with pure SBA-15, the surface area, the pore size and the pore volume of the H2-SBA-15 were decreased. The content of amine in the NH2-SBA-15 was about 3.47 mmol·g-1.%以3-氨丙基三乙氧基硅烷为偶联剂,采用后合成法对介孔分子筛(SBA-15)的表面进行改性,制得氨基功能化的介孔NH-SBA-15材料(简称NH-SBA-15),其结构和性能经FT-IR,元素分析,XRD,SEM及低温N吸附-脱附表征.结果表明,氨基成功地嫁接到SBA-15表面,含量高达3.47 mmol·g.与SBA-15相比,NH-SBA-15的比表面积、孔径和孔容减少,且仍具有有序六方介孔结构.

  6. Preparation and characterization of amino functionalized nano-composite material and its application for multi-residue analysis of pesticides in cabbage by gas chromatography-triple quadrupole mass spectrometry.

    Science.gov (United States)

    Zhao, Yong-Gang; Shen, Hao-Yu; Shi, Jia-Wei; Chen, Xiao-Hong; Jin, Mi-Cong

    2011-08-19

    In this paper, a novel and recyclable amino-functionalized nano-composite material (NCM) using tetraethylenepentamine (TEPA) as a coupling agent was synthesized. The properties of the TEPA-NCM were characterized by transmission electron microscopy (TEM), Fourier transform infrared analysis (FTIR), thermogravimetric analysis (TGA) and elemental analysis (EA). An effective dispersive solid-phase extraction (dSPE) procedure using the TEPA-NCM was developed, and comparative studies were carried out among Carbon/NH₂ SPE, primary secondary amine (PSA) dSPE and TEPA-NCM dSPE. The results showed that TEPA-NCM dSPE was faster, easier and more effective to clean and enrich than the Carbon/NH₂ cartridges, and the TEPA-NCM was much more effective to remove the pigments in vegetable samples than the PSA materials. The TEPA-NCM could be reused at least five times without much sacrifice of the cleanup efficiency. Furthermore, a gas chromatography-triple quadrupole mass spectrometry (GC-QqQ-MS/MS) method was established for the simultaneous determination of 29 pesticides (such as organochlorine and organophosphorus pesticides) in vegetables by dSPE using acetonitrile as an extraction solvent and TEPA-NCM as an adsorbent instead of PSA. The recoveries were in the range of 75-114% for all analytes except for trans-chlordane. The RSDs were in the range of 2-17%. The linearities were in the range of 0.4-100.0 μg/kg with determination coefficients (r²) higher than 0.986 for all compounds. The limits of detection (LODs) for all pesticides were less than 0.29 μg/kg and the limits of quantification (LOQs) were between 0.17 and 0.95 μg/kg. The developed method was applied to fifteen real vegetable samples, and it was confirmed that the TEPA-NCM was one of a kind of highly effective dSPE materials used for the pesticides analyses.

  7. 氨基功能化SBA-15的制备及对三价铬吸附性能的研究%Preparation of Amino-functionalized SBA-15 and Its Adsorption Property to Cr^3+

    Institute of Scientific and Technical Information of China (English)

    田志茗; 李乐园; 隋朝

    2012-01-01

    Amino-functionalized mesoporous material SBA-15 (NH2-SBA 15) was prepared by a post-grafting method using 3-aminopropyltrimethoxy-silane (APTMS). The NH2-SBA-15 was characterized by X-ray diffraction (XRD), infrared spectroscopy (IR), transmission electron microscopy (TEM), scanning electron microscopy (SEM) and N2 adsorption/desorption isotherms. It was proved that ATPMS was grafted on SBA-15, and NHe-SBA-15 remained to keep the hexagonal, mesoporous structure. Adsorption property of NH2-SBA-15 to Cr^3+ ion was studied. It was found that in an aqueous medium of pH 4. 5 containing 140 mg·L^-1 Cr^3+ ion, the NH2-SBA-15 behaved to adsorb strongly and equilibrium of adsorption was achieved after 6h at the temperature of 60 ℃, and the adsorptive capacity of Cr^3+ ion at equilibrium was 15.59 mg ·L^-1.%以3-氨丙基三乙氧基硅烷(APTMS)为功能化试剂,用后嫁接法对介孔分子筛SBA-15进行化学改性,制备氨基功能化NH2-SBA-15。采用X射线衍射、红外光谱、透射电子显微镜、扫描电子显微镜、N2吸附-脱附等手段对NH2-SBA-15进行了表征。结果表明:ATPES成功地嫁接到介孔材料SBA-15上,NH2-SBA-15仍保持了SBA-15六方介孔结构。将此材料作为Cr抖的有效吸附剂进一步研究NH2-SBA-15的吸附性能,结果表明:介质PH值为4.5、温度为60℃、Cr^3+溶液质量浓度为140mg·L^-1、吸附时间为6h时,吸附剂的吸附量达15.59mg·L^-1。

  8. Synthesis and Characterization of Amino-Functionalized and Water Soluble Multi-Walled Carbon Nanotubes%氨基化的水溶性多壁碳纳米管的合成及表征

    Institute of Scientific and Technical Information of China (English)

    李玲; 邓小勇; 白明坤; 胡炜; 倪庆顺; 焦正; 吴明红

    2011-01-01

    通过聚醚酰亚胺修饰得到了氨基化的多壁碳纳米管,并采用傅里叶变换红外光谱、透射电镜、拉曼光谱和热重分析对产物进行表征.通过估算,平均每根383 nm长的多壁碳纳米管接枝上了1 200个聚醚酰亚胺分子,约含一级胺的数目为28万个,即平均每100个碳原子接上了1.8个一级胺,大大增加了多壁碳纳米管表面的氨基数量.此外,修饰后的碳纳米管的溶解度显著提高,约2 mg/mL,利于进一步开发其在生物传感器、药物载带、组织工程、生物显像等生物医药领域的应用.%Multi-walled carbon nanotubes (MWCNTs) were functionalized with polyethyleneimine (PEI), thus introducting a plenty of amino groups onto their surface. The product was fully characterized by fourier transform infrared spectroscopy, transmission electron microscopy, Raman spectroscopy analysis and thermogravimetric analysis (TGA). TGA analysis shows the PEI-grafting rate was 17.5%. It is estimated that, each PEI-MWCNT (ca 383 nm long) was grafted with 1200 PEI molecules, containing about 280 thousand amines, which means every 100 carbon atom connected with 1.8 amines. Meanwhile, the polyethyleneimine modification also improved the water solubility of MWCNTs, ~ 2 rag/mL. The synthesis of amino-functionalized and water soluble MWCNTs favors carbon nanotubes-based biomedical application, such as biosensors, drug carrier tape, tissue engineering, bio-imaging and other biomedical field, in the near future.

  9. Conception raisonnée de matériaux barrières incorporant des nano-adsorbants

    OpenAIRE

    Fang, Xiaoyi

    2013-01-01

    A material is defined as “barrier” when it is able to delay the diffusion of a penetrant. There are few possibilities to modulate the barrier properties of a prescribed material (e.g. packaging material). Most of conventional technological strategies aim at increasing the tortuosity path of the penetrant by adding obstacles. Such obstacles could be obtained either by creating a crystalline morphology or by adding of nano-fillers. The gain in diffusion barrier depends on the shape factor of ob...

  10. Preparation of nanoporous activated carbon and its application as nano adsorbent for CO{sub 2} storage

    Energy Technology Data Exchange (ETDEWEB)

    Rashidi, Ali Morad; Kazemi, Davood; Izadi, Nosrat; Pourkhalil, Mahnaz; Jorsaraei, Abbas; Lotfi, Roghayeh [Research Institute of Petroleum Industry, Tehran (Iran, Islamic Republic of); Ganji, Enseyeh [Research Institute of Petroleum Industry, Tehran (Iran, Islamic Republic of)

    2016-02-15

    Nanoporous activated carbons, as adsorbent for CO{sub 2} storage, were prepared from walnut shells via two chemical processes including phosphoric acid treatment and KOH activation at high temperature. Specific surface area and porosities were controlled by KOH concentration and activation temperature. The obtained adsorbents were characterized by N2 adsorption at 77.3 K. Their carbon dioxide adsorption capacities were measured at different pressures at 290 K by using volumetric adsorption equipment. The KOH-treated nanoporous carbons typically led to the production of high specific surface areas and high micropore volumes and showed better performance for CO{sub 2} adsorptions. The maximum experimental value for adsorption capacity happened when pressure increased from 5 to 10 bar (1.861- 2.873mmol·g{sup -1}). It was found that in order to improve the highest capacity of CO{sub 2} adsorption for KOH-modified carbon (9.830-18.208mmol·g{sup -1}), a KOH: C weight ratio of 3.5 and activation temperature of 973 K were more suitable for pore development and micro-mesopore volume enhancement.

  11. Synthesis of streptavidin-conjugated magnetic nanoparticles for DNA detection

    Energy Technology Data Exchange (ETDEWEB)

    Gong Peijun, E-mail: skygpj@zjnu.cn; Peng Zheyang; Wang Yao; Qiao Ru; Mao Weixing; Qian Haisheng; Zhang Mengya; Li Congcong; Shi Shenyuan [College of Chemistry and Life Sciences, Zhejiang Normal University (China)

    2013-04-15

    In this paper, we report a fabrication of streptavidin-coated magnetic nanoparticles used for DNA detection. Initially, amino-functionalized Fe{sub 3}O{sub 4} nanoparticles with high saturation magnetization are prepared by a photopolymerization method using allylamine as monomer. It is followed by covalent immobilization of streptavidin onto the particle surface via a two-step reaction using glutaraldehyde as coupling agent. Streptavidin-coated magnetic nanoparticles are characterized and further tested for their ability to capture DNA target after binding biotinylated oligonucleotide probes. The results show that the products ({approx}27.2 nm) have a maximum biotin-binding capacity of 0.71 nmol mg{sup -1} when the immobilization reaction is conducted with a mass ratio of streptavidin to magnetic carriers above 0.2 in phosphate buffered saline (pH 7.4) for 24 h. In addition, highly negative {zeta}-potential and good magnetic susceptibility of the nanocomposites make them applicable for DNA collection and detection, which is verified by the results from the preliminary application of streptavidin-coated magnetic nanoparticles in DNA detection. Therefore, the magnetic nanoparticles provide a promising approach for rapid collection and detection of gene.

  12. Magnetism and magnetic materials

    CERN Document Server

    Coey, J M D

    2010-01-01

    Covering basic physical concepts, experimental methods, and applications, this book is an indispensable text on the fascinating science of magnetism, and an invaluable source of practical reference data. Accessible, authoritative, and assuming undergraduate familiarity with vectors, electromagnetism and quantum mechanics, this textbook is well suited to graduate courses. Emphasis is placed on practical calculations and numerical magnitudes - from nanoscale to astronomical scale - focussing on modern applications, including permanent magnet structures and spin electronic devices. Each self-contained chapter begins with a summary, and ends with exercises and further reading. The book is thoroughly illustrated with over 600 figures to help convey concepts and clearly explain ideas. Easily digestible tables and data sheets provide a wealth of useful information on magnetic properties. The 38 principal magnetic materials, and many more related compounds, are treated in detail

  13. Magnetic Levitation.

    Science.gov (United States)

    Rossing, Thomas D.; Hull, John R.

    1991-01-01

    Discusses the principles of magnetic levitation presented in the physics classroom and applied to transportation systems. Topics discussed include three classroom demonstrations to illustrate magnetic levitation, the concept of eddy currents, lift and drag forces on a moving magnet, magnetic levitation vehicles, levitation with permanent magnets…

  14. Magnetic Levitation.

    Science.gov (United States)

    Rossing, Thomas D.; Hull, John R.

    1991-01-01

    Discusses the principles of magnetic levitation presented in the physics classroom and applied to transportation systems. Topics discussed include three classroom demonstrations to illustrate magnetic levitation, the concept of eddy currents, lift and drag forces on a moving magnet, magnetic levitation vehicles, levitation with permanent magnets…

  15. Magnetic Nanocapsules

    Institute of Scientific and Technical Information of China (English)

    Zhidong ZHANG

    2007-01-01

    A brief review on recent advances in the area of the magnetic nanocapsules is given. The most applicable nanoencapsulation procedures are introduced, which include: (1) physical techniques such as arc-discharge,evaporating, etc.; (2) chemical techniques such as chemical vapor deposition, solid-state reactions, etc. The structure and magnetic properties of various nanocapsules with different core/shell structures are studied in details, for possibly applications in magnetic recording, magnetic refrigerator, magnetic fluids, superconductors and medicine.

  16. Magnetic Reconnection

    NARCIS (Netherlands)

    Schep, T. J.

    1994-01-01

    This lecture deals with the concept of magnetic field lines and with the conservation of magnetic flux. In high temperature fusion devices like tokamaks flux conservation can be violated and reconnection can occur at closed magnetic field lines. Reconnection processes lead to changes in the global t

  17. Magnetizing of permanent magnets using HTS bulk magnets

    Science.gov (United States)

    Oka, Tetsuo; Muraya, Tomoki; Kawasaki, Nobutaka; Fukui, Satoshi; Ogawa, Jun; Sato, Takao; Terasawa, Toshihisa

    2012-01-01

    A demagnetized Nd-Fe-B permanent magnet was scanned just above the magnetic pole which contains the HTS bulk magnet generating a magnetic field of 3.27 T. The magnet sample was subsequently found to be fully magnetized in the open space of the static magnetic fields. We examined the magnetic field distributions when the magnetic poles were scanned twice to activate the magnet plate inversely with various overlap distances between the tracks of the bulk magnet. The magnetic field of the "rewritten" magnet reached the values of the magnetically saturated region of the material, showing steep gradients at the border of each magnetic pole. As a replacement for conventional pulse field magnetizing methods, this technique is proposed to expand the degree of freedom in the design of electromagnetic devices, and is proposed as a novel practical method for magnetizing rare-earth magnets, which have excellent magnetic performance and require intense fields of more than 3 T to be activated.

  18. Selective extraction and determination of chlorogenic acid in fruit juices using hydrophilic magnetic imprinted nanoparticles.

    Science.gov (United States)

    Hao, Yi; Gao, Ruixia; Liu, Dechun; He, Gaiyan; Tang, Yuhai; Guo, Zengjun

    2016-06-01

    In this paper, the novel hydrophilic magnetic molecularly imprinted nanoparticles were developed for selective separation and determination of chlorogenic acid in aqueous fruit juices. The polymers were prepared by using amino-functionalized magnetic nanoparticles as carriers, branched polyethyleneimine as functional monomer, and chlorogenic acid as template molecule. Branched polyethyleneimine with abundant active amino groups could react with template sufficiently, and its unique dendritic structure may amplify the number of the imprinted cavities. Meanwhile, it would improve the hydrophilicity of imprinted materials for attaining high extraction efficiency. The resulted polymers exhibit fast kinetics, high adsorption capacity, and favorable selectivity. In addition, the obtained nanoparticles were used as solid-phase extraction sorbents for selective isolation and determination of chlorogenic acid in peach, apple, and grape juices (0.92, 4.21, and 0.75 μg mL(-1), respectively).

  19. Magnetic investigations

    Energy Technology Data Exchange (ETDEWEB)

    Bath, G.D.; Jahren, C.E.; Rosenbaum, J.G. [Geological Survey, Denver, CO (USA); Baldwin, M.J. [Fenix and Scisson, Inc., Mercury, NV (USA)

    1983-12-31

    Air and ground magnetic anomalies in the Climax stock area of the NTS help define the gross configuration of the stock and detailed configuration of magnetized rocks at the Boundary and Tippinip faults that border the stock. Magnetizations of geologic units were evaluated by measurements of magnetic properties of drill core, minimum estimates of magnetizations from ground magnetic anomalies for near surface rocks, and comparisons of measured anomalies with anomalies computed by a three-dimensional forward program. Alluvial deposits and most sedimentary rocks are nonmagnetic, but drill core measurements reveal large and irregular changes in magnetization for some quartzites and marbles. The magnetizations of quartz monzonite and granodiorite near the stock surface are weak, about 0.15 A/m, and increase at a rate of 0.00196 A/m/m to 1.55 A/m, at depths greater than 700 m (2300 ft). The volcanic rocks of the area are weakly magnetized. Aeromagnetic anomalies 850 m (2800 ft) above the stock are explained by a model consisting of five vertical prisms. Prisms 1, 2, and 3 represent the near surface outline of the stock, prism 4 is one of the models developed by Whitehill (1973), and prism 5 is modified from the model developed by Allingham and Zietz (1962). Most of the anomaly comes from unsampled and strongly-magnetized deep sources that could be either granite or metamorphosed sedimentary rocks. 48 refs., 23 figs., 3 tabs.

  20. Planetary Magnetism

    Science.gov (United States)

    Connerney, J. E. P.

    2007-01-01

    The chapter on Planetary Magnetism by Connerney describes the magnetic fields of the planets, from Mercury to Neptune, including the large satellites (Moon, Ganymede) that have or once had active dynamos. The chapter describes the spacecraft missions and observations that, along with select remote observations, form the basis of our knowledge of planetary magnetic fields. Connerney describes the methods of analysis used to characterize planetary magnetic fields, and the models used to represent the main field (due to dynamo action in the planet's interior) and/or remnant magnetic fields locked in the planet's crust, where appropriate. These observations provide valuable insights into dynamo generation of magnetic fields, the structure and composition of planetary interiors, and the evolution of planets.

  1. Quantum Magnetism

    CERN Document Server

    Barbara, Bernard; Sawatzky, G; Stamp, P. C. E

    2008-01-01

    This book is based on some of the lectures during the Pacific Institute of Theoretical Physics (PITP) summer school on "Quantum Magnetism", held during June 2006 in Les Houches, in the French Alps. The school was funded jointly by NATO, the CNRS, and PITP, and entirely organized by PITP. Magnetism is a somewhat peculiar research field. It clearly has a quantum-mechanical basis – the microsopic exchange interactions arise entirely from the exclusion principle, in conjunction with respulsive interactions between electrons. And yet until recently the vast majority of magnetism researchers and users of magnetic phenomena around the world paid no attention to these quantum-mechanical roots. Thus, eg., the huge ($400 billion per annum) industry which manufactures hard discs, and other components in the information technology sector, depends entirely on room-temperature properties of magnets - yet at the macroscopic or mesoscopic scales of interest to this industry, room-temperature magnets behave entirely classic...

  2. Magnetics Processing

    Data.gov (United States)

    Federal Laboratory Consortium — The Magnetics Processing Lab equipped to perform testing of magnetometers, integrate them into aircraft systems, and perform data analysis, including noise reduction...

  3. Magnet Systems

    Data.gov (United States)

    Federal Laboratory Consortium — Over the decades, Fermilab has been responsible for the design, construction, test and analysis of hundreds of conventional and superconducting accelerator magnets...

  4. Fluorescence detection and imaging of amino-functionalized organic monolayer

    Energy Technology Data Exchange (ETDEWEB)

    Shirahata, Naoto [National Institute for Materials Science (NIMS), 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047 (Japan)], E-mail: SHIRAHATA.naoto@nims.go.jp; Furumi, Seiichi [National Institute for Materials Science (NIMS), 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047 (Japan); Masuda, Yoshitake; Hozumi, Atsushi [National Institute of Advanced Industrial Science and Technology (AIST), 2266-98 Anagahora, Shimo-shidami, Moriyama, Nagoya 463-8560 (Japan); Sakka, Yoshio [National Institute for Materials Science (NIMS), 1-2-1 Sengen, Tsukuba, Ibaraki 305-0047 (Japan)

    2008-03-03

    Amino-terminated organic monolayer formed on silicon covered with native oxide (SiO{sub 2}/Si) was directly visualized under observation with fluorescent microscopy. This successful fluorescence visualization was achieved by a combination of fluorescamine method and photopatterning of the amino-terminated surface. As a typical example, an amino-terminated self-assembled monolayer (SAM) was formed on SiO{sub 2}/Si substrate in a vapor of 12.5 vol.% solution of N-(6-aminohexyl)-3-aminopropyltrimethoxysilane [H{sub 2}N(CH{sub 2}){sub 6}NH(CH{sub 2}){sub 3}Si(OCH{sub 3}){sub 3}, AHAPS] diluted with absolute toluene. A micropattern of AHAPS-SAM was photolithographycally prepared using 172 nm vacuum ultraviolet (VUV) light under a reduced pressure of 10 Pa for 30 min through a photomask. The resultant micropattern composed of AHAPS- and SiOH-covered regions was provided to fluorescamine method. Due to a nonluminescence of fluorescamine itself under UV/visible irradiation, a fluorescent emission could not be observed on SiOH regions of the micropattern. In contrast, fluorescamine reacted with the outermost amino group of the AHAPS-SAM to give a fluorescent emission. A comprehensible fluorescence method for verifying formation of an amino-terminated organic monolayer has been developed.

  5. A magnetic tri-enzyme nanobiocatalyst for fruit juice clarification.

    Science.gov (United States)

    Sojitra, Uttam V; Nadar, Shamraja S; Rathod, Virendra K

    2016-12-15

    The major complications in fruit juice quality improvement are the presence of polysaccharides components in the form of disrupted fruit cell wall and cell materials. Hence, breakdown of cellulose along with pectin and starch is important for the juice processing. In this context, magnetic tri-enzyme nanobiocatalyst was prepared by simultaneously co-immobilizing three enzymes; α-amylase, pectinase and cellulase onto amino-functionalized magnetic nanoparticle by 60mM glutaraldehyde concentration with 10h cross-linking time for one pot juice clarification. The prepared nanobiocatalyst was characterized by FT-IR, SEM and XRD. The thermal (50-70°C) and pH (3-6) stability studies indicated more than two folds increment in half-life and enhanced tolerance to lower pH. The immobilized enzymes retained up to 75% of residual activity even after eight consecutive cycles of reuse. Finally, the clarification of apple, grapes and pineapple juices using magnetic tri-enzyme showed 41%, 46% and 53% respective reduction in turbidity till 150min treatment.

  6. Magnetic Field

    DEFF Research Database (Denmark)

    Olsen, Nils

    2015-01-01

    of the fluid flow at the top of the core. However, what is measured at or near the surface of the Earth is the superposition of the core field and fields caused by magnetized rocks in the Earth’s crust, by electric currents flowing in the ionosphere, magnetosphere, and oceans, and by currents induced......he Earth has a large and complicated magnetic field, the major part of which is produced by a self-sustaining dynamo operating in the fluid outer core. Magnetic field observations provide one of the few tools for remote sensing the Earth’s deep interior, especially regarding the dynamics...... in the Earth by time-varying external fields. These sources have their specific characteristics in terms of spatial and temporal variations, and their proper separation, based on magnetic measurements, is a major challenge. Such a separation is a prerequisite for remote sensing by means of magnetic field...

  7. Magnetic nanotubes

    Science.gov (United States)

    Matsui, Hiroshi; Matsunaga, Tadashi

    2010-11-16

    A magnetic nanotube includes bacterial magnetic nanocrystals contacted onto a nanotube which absorbs the nanocrystals. The nanocrystals are contacted on at least one surface of the nanotube. A method of fabricating a magnetic nanotube includes synthesizing the bacterial magnetic nanocrystals, which have an outer layer of proteins. A nanotube provided is capable of absorbing the nanocrystals and contacting the nanotube with the nanocrystals. The nanotube is preferably a peptide bolaamphiphile. A nanotube solution and a nanocrystal solution including a buffer and a concentration of nanocrystals are mixed. The concentration of nanocrystals is optimized, resulting in a nanocrystal to nanotube ratio for which bacterial magnetic nanocrystals are immobilized on at least one surface of the nanotubes. The ratio controls whether the nanocrystals bind only to the interior or to the exterior surfaces of the nanotubes. Uses include cell manipulation and separation, biological assay, enzyme recovery, and biosensors.

  8. Aluminum Substituted Cobalt Ferrite (Co-Al-Fe) Nano Adsorbent for Arsenic Adsorption in Aqueous Systems and Detailed Redox Behavior Study with XPS.

    Science.gov (United States)

    Penke, Yaswanth K; Anantharaman, Ganapathi; Ramkumar, Janakarajan; Kar, Kamal K

    2017-04-05

    Arsenic [As(III) and As(V)] adsorption on aluminum substituted cobalt ferrite (Co-Al-Fe) ternary metal oxide adsorbent is reported by means of qualitative and quantitative spectroscopy tools. IR and Raman active signals were observed around 810-920 cm(-1) band indicate different As-OHcomplexed and As-Ouncomplexed stretching vibrations on to the adsorbent. The adsorption behavior of arsenic (III and V) onto these adsorbents is studied as a function of contact time, different concentrations, and pH conditions. The kinetics study on adsorption were performed to understand nature of adsorption which supports the Pseudo Second Order (PSO) model. The adsorption isotherms study indicates Freundlich type of adsorption. The maximum adsorption capacity of Co-Al-Fe adsorbent is observed around 130 and 76 mg g(-1) for As(III) and As(V) systems, respectively. Detailed XPS study of As 3d, Fe 2p, Co 2p, and O 1s spectra has been reported in explaining the redox behavior and ligand exchange reactions in supporting arsenic adsorption mechanism.

  9. Selective adsorption of bovine hemoglobin on functional TiO2 nano-adsorbents: surface physic-chemical properties determined adsorption activity

    Science.gov (United States)

    Guo, Shiguang; Zhang, Jianghua; Shao, Mingxue; Zhang, Xia; Liu, Yufeng; Xu, Junli; Meng, Hao; Han, Yide

    2015-04-01

    Surface functionalized nanoparticles are efficient adsorbents which have shown good potential for protein separation. In this work, we chose two different types of organic molecules, oleic acid (OA) and 3-glycidoxypropyltrimethoxy silane (GPTMS), to functionalize the surface of TiO2 nanoparticles, and we studied the effects of this modification on their surface physicochemical properties in correlation with their selective adsorption of proteins. The results showed that the surface zeta potential and the surface water wettability of the modified TiO2 were significantly changed in comparison with the original TiO2 nanoparticles. The adsorption activities of bovine hemoglobin (BHb) and bovine serum albumin (BSA) on these functionalized TiO2 samples were investigated under different conditions, including pH values, contact time, ion strength, and initial protein concentration. In comparison with the non-specific adsorption of original TiO2, however, both the OA-TiO2 and GPTMS-TiO2 exhibited increased BHb adsorption and decreased BSA adsorption at the same time. Using a binary protein mixture as the adsorption object, a higher separation factor (SF) was obtained for OA-TiO2 under optimum conditions. The different adsorption activities of BHb and BSA on the modified TiO2 were correlated with different interactions at the protein/solid interface, and the chemical force as well as the electrostatic force played an important role in the selective adsorption process.

  10. Magnetic Bearing

    Science.gov (United States)

    1996-01-01

    AVCON, Inc. produces advanced magnetic bearing systems for industrial use, offering a unique technological approach based on contract work done at Marshall Space Flight Center and Lewis Research Center. Designed for the turbopump of the Space Shuttle main engine, they are now used in applications such as electric power generation, petroleum refining, machine tool operation and natural gas pipelines. Magnetic bearings support moving machinery without physical contact; AVCON's homopolar approach is a hybrid of permanent and electromagnets which are one-third the weight, smaller and more power- efficient than previous magnetic bearings.

  11. Lunar magnetism

    Science.gov (United States)

    Hood, L. L.; Sonett, C. P.; Srnka, L. J.

    1984-01-01

    Aspects of lunar paleomagnetic and electromagnetic sounding results which appear inconsistent with the hypothesis that an ancient core dynamo was the dominant source of the observed crustal magnetism are discussed. Evidence is summarized involving a correlation between observed magnetic anomalies and ejecta blankets from impact events which indicates the possible importance of local mechanisms involving meteoroid impact processes in generating strong magnetic fields at the lunar surface. A reply is given to the latter argument which also presents recent evidence of a lunar iron core.

  12. Designing a magnet for magnetic refrigeration

    DEFF Research Database (Denmark)

    Bjørk, Rasmus

    of infinite length, are presented. Once it has been determined which properties are desirable for a magnet used in magnetic refrigeration the design of a new magnet is described. This is a high performance cylindrical magnet for use in a new magnetic refrigeration device being built at Risø DTU. This magnet...

  13. 双醛淀粉修饰的磁性Fe3O4制备及其除去水中Pb2+的研究%Synthesis of magnetical Fe3O4 modified by dialdehyde starch and application in remediation of Pb2+

    Institute of Scientific and Technical Information of China (English)

    杨芳; 王朝辉; 陈跟平

    2012-01-01

    使用油相水热法制备了50nm左右的Fe3O4纳米颗粒,并在其表面包裹上双醛淀粉(DSA),使纳米颗粒表面具有丰富的羟基基团,通过化学方法将乙二胺四乙酸(EDTA)键合在其表面.通过透射电镜(TEM)和XRD表征分析,说明成功合成了粒径为50nm左右的Fe3O4磁性纳米颗粒,并且在其表面用物理吸附的方式包裹了双醛淀粉(DSA);通过红外光谱分析表明,EDTA被成功地键合在纳米复合体的表面;通过磁回滞线(VSM),得出FeO4-NH2和Fe3O4@DAS-EDTA的饱和磁性分别为83和62emu·g-1.并将这一材料应用于吸附不同pH值水中的重金属离子Pb2+,实验结果表明,在pH值为5时,该纳米复合材料对ph2+吸附效果最为显著,除去率可达到98.5%,重复使用6次后,除去率仅降低3%.%The present work reports a facile route for ethylenediaminetetraacetic acid (EDTA) immobilization on the surface of Fe3O4 modified by dialdehyde starch for remediation of Pb2* from aqueous solutions. Transmission electron microscopy images showed magnetic nanoparticles with an average diameter of 50nm. The FT-IR study confirmed the modification of dialdehyde starch on the surface of magnetite nanoparticles. XRD analysis demonstrated that the magnetic nanoparticles had high cryslallinity before and afler modification. Magnetic measurements (VSM) indicated that these nanoparticles could be easily removed through external magnetic force. The research work on the adsorption revealed that 98.5% of Pb2* could be removed from aqueous solutions at pH 5.0, and loaded ions after being treated with O.imol'L"1 HO could be used as a reusable nano-adsorbent.

  14. CRYOGENIC MAGNETS

    Science.gov (United States)

    Post, R.F.; Taylor, C.E.

    1963-05-21

    A cryogenic magnet coil is described for generating magnetic fields of the order of 100,000 gauss with a minimum expenditure of energy lost in resistive heating of the coil inductors and energy lost irreversibly in running the coil refrigeration plant. The cryogenic coil comprises a coil conductor for generating a magnetic field upon energization with electrical current, and refrigeration means disposed in heat conductive relation to the coil conductor for cooling to a low temperature. A substantial reduction in the power requirements for generating these magnetic fields is attained by scaling the field generating coil to large size and particular dimensions for a particular conductor, and operating the coil at a particular optimum temperature commensurate with minimum overall power requirements. (AEC)

  15. Quantum magnetism

    CERN Document Server

    Richter, Johannes; Farnell, Damian; Bishop, Raymod

    2004-01-01

    The investigation of magnetic systems where quantum effects play a dominant role has become a very active branch of solid-state-physics research in its own right. The first three chapters of the "Quantum Magnetism" survey conceptual problems and provide insights into the classes of systems considered, namely one-dimensional, two-dimensional and molecular magnets. The following chapters introduce the methods used in the field of quantum magnetism, including spin wave analysis, exact diagonalization, quantum field theory, coupled cluster methods and the Bethe ansatz. The book closes with a chapter on quantum phase transitions and a contribution that puts the wealth of phenomena into the context of experimental solid-state physics. Closing a gap in the literature, this volume is intended both as an introductory text at postgraduate level and as a modern, comprehensive reference for researchers in the field.

  16. Preparation and properties of pH-responsive control release system of PAA/chlorpyrifos/amino functionalized mesoporous silica%pH响应性PAA/毒死蜱/氨基化介孔硅缓释体系的制备与性能

    Institute of Scientific and Technical Information of China (English)

    林粤顺; 周红军; 周新华; 龚圣; 徐华; 陈铧耀

    2016-01-01

    以共缩聚法合成氨基化介孔硅,采用浸渍法制备毒死蜱/氨基化介孔硅,并以带负电荷的聚丙烯酸(PAA)为功能分子,通过静电吸附作用制备了具有 pH 响应的 PAA/毒死蜱/氨基化介孔硅缓释体系。利用 XRD、N2吸附-脱附、TEM、SEM、TG、Zeta电位和FTIR对PAA/毒死蜱/氨基化介孔硅的结构进行了表征,并探究了其在不同pH和温度下的释药行为。结果表明,PAA通过静电作用包覆于毒死蜱/氨基化介孔硅的表面。缓释体系的药物释放主要受到PAA的阻碍作用,PAA修饰载药氨基化介孔硅显示出明显的pH响应性,当pH≤7时,其药物释放速率随 pH 减小而增大,而在偏碱性条件下的释药速率稍大于中性环境。同时,载药体系的释药速率还受到温度的影响。其释药行为可用Korsmeryer-Pappas动力学模型来描述。%A pH-responsive control release system of PAA/chlorpyrifos/mesoporous silica was prepared by using negative charged polyacrylic acid (PAA) to encapsulate amino functionalized mesoporous silica (NH2-MCM-41) with chlorpyrifos loaded in the pores. The PAA/chlorpyrifos/NH2-MCM-41 system were systematically characterized using X-ray diffraction (XRD), N2 adsorption-desorption, transmission electron microscopy (TEM), scanning electron microscopy (SEM), thermogravimetric analysis (TGA), Zeta potential and Fourier transform infrared spectroscopy (FTIR). The release behavior of chlorpyrifos was studied at various pH and temperature conditions. The experimental results showed that PAA was coated on the surface of chlorpyrifos/amino functionalized mesoporous silica as a result of electrostatic interaction. The chlorpyrifos release from the PAA/chlorpyrifos/NH2-MCM-41 system was inhibited mainly by PAA blockage with significant pH sensitivity, which increased with pH decrease at pH≤7 and was slightly higher in weak base condition than that in neutral condition. The release also exhibited some

  17. Magnetization reversal in ultrashort magnetic field pulses

    CERN Document Server

    Bauer, M; Fassbender, J; Hillebrands, B

    2000-01-01

    We report the switching properties of a thin magnetic film subject to an ultrashort, laterally localized magnetic field pulse, obtained by numerical investigations. The magnetization distribution in the film is calculated on a grid assuming Stoner-like coherent rotation within the grid square size. Perpendicularly and in-plane magnetized films exhibit a magnetization reversal due to a 4 ps magnetic field pulse. Outside the central region the pulse duration is short compared to the precession period. In this area the evolution of the magnetization during the field pulse does not depend strongly on magnetic damping and/or pulse shape. However, the final magnetization distribution is affected by the magnetic damping. Although the pulse duration is short compared to the precession period, the time needed for the relaxation of the magnetization to the equilibrium state is rather large. The influence of the different magnetic anisotropy contributions and the magnetic damping parameter enters into the magnetization ...

  18. An optimized magnet for magnetic refrigeration

    DEFF Research Database (Denmark)

    Bjørk, Rasmus; Bahl, Christian Robert Haffenden; Smith, Anders

    2010-01-01

    A magnet designed for use in a magnetic refrigeration device is presented. The magnet is designed by applying two general schemes for improving a magnet design to a concentric Halbach cylinder magnet design and dimensioning and segmenting this design in an optimum way followed by the construction...... to the maximum energy density. The final design is characterized in terms of a performance parameter, and it is shown that it is one of the best performing magnet designs published for magnetic refrigeration....

  19. Magnetism Materials and Applications

    CERN Document Server

    Trémolet de Lacheisserie, Étienne; Schlenker, Michel

    2005-01-01

    This book treats permanent magnet (hard) materials, magnetically soft materials for low-frequency applications and for high-frequency electronics, magnetostrictive materials, superconductors, magnetic-thin films and multilayers, and ferrofluids. Chapters are dedicated to magnetic recording, the role of magnetism in magnetic resonance imaging (MRI), and instrumentation for magnetic measurements.   

  20. Magnetic monopoles and dipoles

    CERN Multimedia

    Dominguez, Daniel

    2016-01-01

    Conventional bar magnets are also called ‘magnetic dipoles’ because they have two magnetic poles (a “North” and a “South” magnetic pole, like the Earth). In theory, “magnetic monopoles” could exist that act like an isolated “magnetic charge”, i.e. either a “North” or a “South” magnetic pole.

  1. Designing a magnet for magnetic refrigeration

    Energy Technology Data Exchange (ETDEWEB)

    Bjoerk, R.

    2010-03-15

    This thesis investigates the design and optimization of a permanent magnet assembly for use in a magnetic refrigeration device. The heart of magnetic refrigeration is the adiabatic temperature change in the magnetocaloric material which is caused by the magnetic field. In order to design an ideal magnet assembly the magnetocaloric materials and the refrigeration process itself and their properties and performance as a function of magnetic field are investigated. For the magnetocaloric materials it is the magnetization, specific heat capacity and adiabatic temperature that are investigated as functions of the magnetic field. Following this the process utilized by a magnetic refrigerator to provide cooling is investigated using a publicly available one dimensional numerical model. This process is called active magnetic regeneration (AMR). The aim is to determine the performance of the AMR as a function of the magnetic field in order to learn the properties of the optimal magnet assembly. The performance of the AMR as a function of the synchronization and width of the magnetic field with respect to the AMR cycle, the ramp rate and maximum value of the magnetic field are investigated. Other published magnet designs used in magnetic refrigeration devices are also evaluated, using a figure of merit based on the properties of the investigated magnetocaloric materials, to learn the properties of the best magnet designs to date. Following this investigation the Halbach cylinder, which is a hollow permanent magnet cylinder with a rotating remanent flux density, is investigated in detail as it forms the basis of many magnet designs used in magnetic refrigeration. Here the optimal dimensions of a Halbach cylinder, as well as analytical calculations of the magnetic field for a Halbach cylinder of infinite length, are presented. Once it has been determined which properties are desirable for a magnet used in magnetic refrigeration the design of a new magnet is described. This is

  2. Magnetic guns with cylindrical permanent magnets

    DEFF Research Database (Denmark)

    Vokoun, David; Beleggia, Marco; Heller, Luděk

    2012-01-01

    The motion of a cylindrical permanent magnet (projectile) inside a tubular permanent magnet, with both magnets magnetized axially, illustrates nicely the physical principles behind the operation of magnetic guns. The force acting upon the projectile is expressed semi-analytically as derivative...

  3. Magnetics Research Facility

    Data.gov (United States)

    Federal Laboratory Consortium — The Magnetics Research Facility houses three Helmholtz coils that generate magnetic fields in three perpendicular directions to balance the earth's magnetic field....

  4. Kicker magnet

    CERN Multimedia

    CERN PhotoLab

    1966-01-01

    The improved "bare" kicker magnet for the PS fast extraction system is here shown being mounted for testing a vacuum tank similar to the one in which it will be installed, early in 1967 in straight section 97 of the PS.

  5. Magnetic Fluids: Biomedical Applications and Magnetic Fractionation

    OpenAIRE

    Rheinländer, Thomas; Kötitz, Róman; Weitschies, Werner; Semmler, Wolfhard

    2000-01-01

    In addition to engineering applications, magnetic fluids containing magnetic nanoparticles are being increasingly applied to biomedical purposes. Besides the well established use of magnetic particles for biological separation or as contrast agents for magnetic resonance imaging, magnetic particles are also being tested for the inductive heat treatment of tumors or as markers for the quantification of biologically active substances. The properties of magnetic nanoparticles usually exhibit a b...

  6. LHC prototype magnet

    CERN Multimedia

    1991-01-01

    1.5 metre superconducting magnet. This prototype magnet for the LHC was cooled to a few degrees above absolute zero, which allowed it to obtain the world record for the highest magnetic field for an accelerator magnet in 1991.

  7. Magnetization curve modelling of soft magnetic alloys

    Energy Technology Data Exchange (ETDEWEB)

    Meszaros, I, E-mail: meszaros@eik.bme.hu [Department of Materials Science and Engineering, Budapest University of Technology and Economics, Bertalan L. street 7., Budapest, H-1111 (Hungary)

    2011-01-01

    In this paper we present an application of the so called hyperbolic model of magnetization. The model was modified and it was applied for nine different soft magnetic alloys. The tested samples were electro-technical steels (FeSi alloys) and a permalloy (FeNi alloy) with strongly different magnetic properties. Among them there are top, medium and definitely poor quality soft magnetic materials as well. Their minor hysteresis loops and normal magnetization curves were measured by alternating current measurement. The hyperbolic model of magnetization was applied for the experimental normal magnetization curves. It was proved that the applied model is excellent for describing mathematically the experimental magnetization curves.

  8. magnetic horn

    CERN Multimedia

    Neutrinos and antineutrinos are ideal for probing the weak force because it is effectively the only force they feel. How were they made? Protons fired into a metal target produce a tangle of secondary particles. A magnetic horn like this one, invented by Simon Van der Meer, selected pions and focused them into a sharp beam. Pions decay into muons and neutrinos or antineutrinos. The muons were stopped in a wall of 3000 tons of iron and 1000 tons of concrete, leaving the neutrinos or antineutrinos to reach the Gargamelle bubble chamber. A simple change of magnetic field direction on the horn flipped between focusing positively- or negatively-charged pion beams, and so between neutrinos and antineutrinos.

  9. Magnetic switching

    Energy Technology Data Exchange (ETDEWEB)

    Birx, D.; Cook, E.; Hawkins, S.; Poor, S.; Reginato, L.; Schmidt, J.; Smith, M.

    1983-06-01

    The paper discusses the development program in magnetic switching which was aimed at solving the rep-rate and reliability limitations of the ATA spark gaps. The end result has been a prototype physically very similar to the present Advanced Test Accelerator (ATA) pulse power unit but vastly superior in performance. This prototype, which is easily adaptable to the existing systems, has achieved a burst rep-rate of 20 kHz and an output voltage of 500 kV. A one-on-one substitution of the existing pulse power module would result in a 100 MeV accelerator. Furthermore, the high efficiency of the magnetic pulse compression stages has allowed CW operation of the prototype at one kilohertz opening up other applications for the pulse power. Performance and design details will be described.

  10. Magnetic Reconnection

    Energy Technology Data Exchange (ETDEWEB)

    Masaaki Yamada, Russell Kulsrud and Hantao Ji

    2009-09-17

    We review the fundamental physics of magnetic reconnection in laboratory and space plasmas, by discussing results from theory, numerical simulations, observations from space satellites, and the recent results from laboratory plasma experiments. After a brief review of the well-known early work, we discuss representative recent experimental and theoretical work and attempt to interpret the essence of significant modern findings. In the area of local reconnection physics, many significant findings have been made with regard to two- uid physics and are related to the cause of fast reconnection. Profiles of the neutral sheet, Hall currents, and the effects of guide field, collisions, and micro-turbulence are discussed to understand the fundamental processes in a local reconnection layer both in space and laboratory plasmas. While the understanding of the global reconnection dynamics is less developed, notable findings have been made on this issue through detailed documentation of magnetic self-organization phenomena in fusion plasmas. Application of magnetic reconnection physics to astrophysical plasmas is also brie y discussed.

  11. Magnetic semiconductors

    Energy Technology Data Exchange (ETDEWEB)

    Bihler, Christoph

    2009-04-15

    In this thesis we investigated in detail the properties of Ga{sub 1-x}Mn{sub x}As, Ga{sub 1-x}Mn{sub x}P, and Ga{sub 1-x}Mn{sub x}N dilute magnetic semiconductor thin films with a focus on the magnetic anisotropy and the changes of their properties upon hydrogenation. We applied two complementary spectroscopic techniques to address the position of H in magnetic semiconductors: (i) Electron paramagnetic resonance, which provides direct information on the symmetry of the crystal field of the Mn{sup 2+} atoms and (ii) x-ray absorption fine structure analysis which allows to probe the local crystallographic neighborhood of the absorbing Mn atom via analysing the fine structure at the Mn K absorption edge. Finally, we discussed the obstacles that have to be overcome to achieve Curie temperatures above the current maximum in Ga{sub 1-x}Mn{sub x}As of 185 K. Here, we outlined in detail the generic problem of the formation of precipitates at the example of Ge:MN. (orig.)

  12. MAGNET / INFRASTRUCTURE

    CERN Multimedia

    D. Campi

    The final fast discharge of the Magnet took place on 3rd of November. The Coil reached a temperature of 70K by internal energy dissipation. By injecting a current of 200 A room temperature was reached on the 23rd November. During the heating of the coil un-connecting of the first magnet connectors on YBO was started to give the earliest possible access to the assembly groups and to continue the installation of the muon chambers. The removal of the pumping lines and the disconnection of the vacuum system was instead done as soon as the room temperature was reached: more precisely from the 4 to the 18 December. The disconnection of the transfer line from the cold box and the completion of the removal of the control cables of the vacuum system and cryogenics was done at last. In January 2007 the disconnection of MCS-MSS, CDS, vacuum racks and their cable trays was also achieved. After coil disconnection the effort of the magnet team has been mainly devoted in optimizing the lowering and reassembly of the a...

  13. Sonochemical synthesis of magnetic responsive Fe3O4@TMU-17-NH2 composite as sorbent for highly efficient ultrasonic-assisted denitrogenation of fossil fuel.

    Science.gov (United States)

    Mirzaie, Abbas; Musabeygi, Tahereh; Afzalinia, Ahmad

    2016-08-10

    In this work, a novel magnetic responsive composite was fabricated by encapsulation of Fe3O4 nanoparticles into an amino-functionalized MOF (TMU-17-NH2) under ultrasound irradiation. The prepared materials were characterized by several techniques such as elemental analyses, PXRD, FT-IR, N2 adsorption, TGA and ICP. This composite has been applied to the adsorptive removal of nitrogen-contain compounds in model liquid fuel. The prepared composite demonstrates very good performance for the removal of NCCs. The maximum adsorption capacity of IND and QUI over prepared composite calculated 375.93 and 310.18mg·g(-1) at 25°C, respectively. The composite material is magnetically separable and reusable for several times.

  14. Enhancing the magnetic properties of magnetic nanoparticles

    DEFF Research Database (Denmark)

    Ahlburg, Jakob; Saura-Múzquiz, Matilde; Stingaciu, Marian

    ways of enhancing magnetic properties of 3d magnetic compounds. This includes, size control, core-shell particles or mixing hard and soft magnetic materials together to achieve an exchange coupling between the compounds and enhancing the magnetic energy product. In order to control the particle size......Enhancing the magnetic properties of magnetic nanoparticles J. V. Ahlburg, M. S. Músquiz, C. Zeuthen, S. Kjeldgaard, M. Stingaciu, M. Christensen Center for Materials Crystallography, Departement of Chemistry & iNano, Aarhus University, Denmark Strong magnets with a high energy product are vital...... when optimizing the efficiency in the electric industry. But since the rare earth metals, normally used for making strong permanent magnets, are both expensive and difficult to mine, a great demand has come to cheaper types of magnets with a similar magnetic performance. There are several different...

  15. Physics of magnetism and magnetic materials

    CERN Document Server

    Buschow, K H J

    2003-01-01

    In this book, the fundamentals of magnetism are treated, starting at an introductory level. The origin of magnetic moments, the response to an applied magnetic field, and the various interactions giving rise to different types of magnetic ordering in solids are presented and many examples are given. Crystalline-electric-field effects are treated at a level that is sufficient to provide the basic knowledge necessary in understanding the properties of materials in which these effects play a role. Itinerant-electron magnetism is presented on a similar basis. Particular attention has been given to magnetocrystalline magnetic anisotropy and the magnetocaloric effect. Also, the usual techniques for magnetic measurements are presented. About half of the book is devoted to magnetic materials and the properties that make them suitable for numerous applications. The state of the art is presented of permanent magnets, high-density recording materials, soft-magnetic materials, Invar alloys and magnetostrictive materials....

  16. Preparation of poly-L-lysine functionalized magnetic nanoparticles and their influence on viability of cancer cells

    Science.gov (United States)

    Khmara, I.; Koneracka, M.; Kubovcikova, M.; Zavisova, V.; Antal, I.; Csach, K.; Kopcansky, P.; Vidlickova, I.; Csaderova, L.; Pastorekova, S.; Zatovicova, M.

    2017-04-01

    This study was aimed at development of biocompatible amino-functionalized magnetic nanoparticles as carriers of specific antibodies able to detect and/or target cancer cells. Poly-L-lysine (PLL)-modified magnetic nanoparticle samples with different PLL/Fe3O4 content were prepared and tested to define the optimal PLL/Fe3O4 weight ratio. The samples were characterized for particle size and morphology (SEM, TEM and DLS), and surface properties (zeta potential measurements). The optimal PLL/Fe3O4 weight ratio of 1.0 based on both zeta potential and DLS measurements was in agreement with the UV/VIS measurements. Magnetic nanoparticles with the optimal PLL content were conjugated with antibody specific for the cancer biomarker carbonic anhydrase IX (CA IX), which is induced by hypoxia, a physiologic stress present in solid tumors and linked with aggressive tumor behavior. CA IX is localized on the cell surface with the antibody-binding epitope facing the extracellular space and is therefore suitable for antibody-based targeting of tumor cells. Here we showed that PLL/Fe3O4 magnetic nanoparticles exhibit cytotoxic activities in a cell type-dependent manner and bind to cells expressing CA IX when conjugated with the CA IX-specific antibody. These data support further investigations of the CA IX antibody-conjugated, magnetic field-guided/activated nanoparticles as tools in anticancer strategies.

  17. Noncentrosymmetric Magnets Hosting Magnetic Skyrmions.

    Science.gov (United States)

    Kanazawa, Naoya; Seki, Shinichiro; Tokura, Yoshinori

    2017-03-17

    The concept of a skyrmion, which was first introduced by Tony Skyrme in the field of particle physics, has become widespread in condensed matter physics to describe various topological orders. Skyrmions in magnetic materials have recently received particular attention; they represent vortex-like spin structures with the character of nanometric particles and produce fascinating physical properties rooted in their topological nature. Here, a series of noncentrosymmetric ferromagnets hosting skyrmions is reviewed: B20 metals, Cu2 OSeO3 , Co-Zn-Mn alloys, and GaV4 S8 , where Dzyaloshinskii-Moriya interaction plays a key role in the stabilization of skyrmion spin texture. Their topological spin arrangements and consequent emergent electromagnetic fields give rise to striking features in transport and magnetoelectric properties in metals and insulators, such as the topological Hall effect, efficient electric-drive of skyrmions, and multiferroic behavior. Such electric controllability and nanometric particle natures highlight magnetic skyrmions as a potential information carrier for high-density magnetic storage devices with excellent energy efficiency.

  18. Magnetic fluids - suspensions of magnetic dipoles and their magnetic control

    CERN Document Server

    Odenbach, S

    2003-01-01

    Suspensions of magnetic nanoparticles exhibit normal liquid behaviour coupled with superparamagnetic properties. This leads to the possibility to control the properties and the flow of these liquids with moderate magnetic fields. The magnetic control enables various experiments in fluid mechanics and gives rise to the development of numerous technical and medical applications. Ferrofluids and their general properties will be introduced and, as examples for the magnetic control of their flow and properties, thermomagnetic convection and magnetoviscous effects will be discussed in some detail.

  19. Enhancing the magnetic properties of magnetic nanoparticles

    DEFF Research Database (Denmark)

    Ahlburg, Jakob; Saura-Múzquiz, Matilde; Stingaciu, Marian

    with a similar magnetic performance. There are several different ways of enhancing magnetic properties of 3d magnetic compounds. This includes, size control, core-shell particles or mixing hard and soft magnetic materials together to achieve an exchange coupling between the compounds and enhancing the magnetic......Strong magnets with a high energy product are vital when optimizing the efficiency in the electric industry. But since the rare earth metals, normally used for making strong permanent magnets, are both expensive and difficult to mine, a great demand has come to cheaper types of magnets...... energy product. In order to control the particle size, a hydrothermal synthesis is preferred. This followed by reduction or the oxides into either core shell particles, or a mixture of magnetic oxides and a metallic phase....

  20. Thin Magnetically Soft Wires for Magnetic Microsensors

    Directory of Open Access Journals (Sweden)

    Arcady Zhukov

    2009-11-01

    Full Text Available Recent advances in technology involving magnetic materials require development of novel advanced magnetic materials with improved magnetic and magneto-transport properties and with reduced dimensionality. Therefore magnetic materials with outstanding magnetic characteristics and reduced dimensionality have recently gained much attention. Among these magnetic materials a family of thin wires with reduced geometrical dimensions (of order of 1–30 μm in diameter have gained importance within the last few years. These thin wires combine excellent soft magnetic properties (with coercivities up to 4 A/m with attractive magneto-transport properties (Giant Magneto-impedance effect, GMI, Giant Magneto-resistance effect, GMR and an unusual re-magnetization process in positive magnetostriction compositions exhibiting quite fast domain wall propagation. In this paper we overview the magnetic and magneto-transport properties of these microwires that make them suitable for microsensor applications.

  1. Electrically Tunable Magnetism in Magnetic Topological Insulators

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Jing; Lian, Biao; Zhang, Shou-Cheng

    2015-07-14

    The external controllability of the magnetic properties in topological insulators would be important both for fundamental and practical interests. Here we predict the electric-field control of ferromagnetism in a thin film of insulating magnetic topological insulators. The decrease of band inversion by the application of electric fields results in a reduction of magnetic susceptibility, and hence in the modification of magnetism. Remarkably, the electric field could even induce the magnetic quantum phase transition from ferromagnetism to paramagnetism. We further propose a transistor device in which the dissipationless charge transport of chiral edge states is controlled by an electric field. In particular, the field-controlled ferromagnetism in a magnetic topological insulator can be used for voltage based writing of magnetic random access memories in magnetic tunnel junctions. The simultaneous electrical control of magnetic order and chiral edge transport in such devices may lead to electronic and spintronic applications for topological insulators.

  2. MAGNETIC WOVEN FABRICS - PHYSICAL AND MAGNETIC PROPERTIES

    Directory of Open Access Journals (Sweden)

    GROSU Marian C

    2015-05-01

    Full Text Available A coated material is a composite structure that consists of at least two components: base material and coating layer. The purpose of coating is to provide special properties to base material, with potential to be applied in EMI shielding and diverse smart technical fields. This paper reports the results of a study about some physical and magnetic properties of coated woven fabrics made from cotton yarns with fineness of 17 metric count. For this aim, a plain woven fabric was coated with a solution hard magnetic polymer based. As hard magnetic powder, barium hexaferrite (BaFe12O19 was selected. The plain woven fabric used as base has been coated with five solutions having different amounts of hard magnetic powder (15% - 45% in order to obtain five different magnetic woven fabrics. A comparison of physical properties regarding weight (g/m2, thickness (mm, degree of charging (% and magnetic properties of magnetic woven samples were presented. Saturation magnetizing (emu/g, residual magnetizing (emu/g and coercive force (kA/m of pure hard magnetic powder and woven fabrics have been studied as hysteresis characteristics. The magnetic properties of the woven fabrics depend on the mass percentage of magnetic powder from coating solution. Also, the residual magnetism and coercive field of woven fabrics represents only a part of bulk barium hexafferite residual magnetism and coercive field.

  3. The magnetization process: Hysteresis

    Science.gov (United States)

    Balsamel, Richard

    1990-01-01

    The magnetization process, hysteresis (the difference in the path of magnetization for an increasing and decreasing magnetic field), hysteresis loops, and hard magnetic materials are discussed. The fabrication of classroom projects for demonstrating hysteresis and the hysteresis of common magnetic materials is described in detail.

  4. Magnetic Nano-structures

    Institute of Scientific and Technical Information of China (English)

    姚永德

    2004-01-01

    Fabrication of magnetic nano-structures with dots array and wires has been paid attention recently due to the application of high-density magnetic recording. In this study, we fabricated the magnetic dots array and wires through several ways that ensure the arrangement of magnetic dots and wires to be the structures we designed. Their magnetic properties are studied experimentally.

  5. Development of Magnetic Refrigerator

    Science.gov (United States)

    Ogiwara, Hiroyasu; Nakagome, Hideki; Kuriyama, Tohru

    A series of R & D of magnetic refrigerators has been done in order to realize an advanced type cryocooler for superconducting magnets of maglev trains and MRI medical system. As a result of efforts on both the magnetic refrigerator and superconducting magnets, a parasitic type magnetic refrigeration system was proposed.

  6. Docetaxel grafted magnetic nanoparticles as dual-therapeutic agentia for targeting perfusion therapy of urethral carcinoma

    Energy Technology Data Exchange (ETDEWEB)

    Huang, Xiao; Wang, Zhen [Chongqing University, Key Laboratory for Biorheological Science and Technology of Ministry of Education, College of Bioengineering (China); Dai, Hong [Chongqing Three Gorges Central Hospital, Department of Urology (China); Wang, Chunmei [Chongqing Three Gorges Central Hospital, Department of Orthopaedics (China); Xia, Bing [Guangzhou General Hospital of Guangzhou Military Command, Department of Medical Research (China); Chen, Lan; Pan, Jun, E-mail: panj@cqu.edu.cn [Chongqing University, Key Laboratory for Biorheological Science and Technology of Ministry of Education, College of Bioengineering (China)

    2014-12-15

    Although urethral carcinoma has a low incidence, it suffers from a poor curative rate for the low retention of medicine around urethra. In the present study, we developed a kind of magnetic targeting perfusion chemotherapy to detain the chemotherapeutic drugs. Docetaxel (TXT) grafted magnetic nanoparticles, of which size was around 40 nm, were obtained by the conjugation of TXT to amino-functionalized iron oxide (NH{sub 2}@Fe{sub 3}O{sub 4}). They have shown great potential to be targeted to and stayed in desired position of urethra under the externally applied magnetism through in vitro mimic urethral study. Furthermore, they have validly inhibited the growth of direct-contacted human urethral squamous carcinoma cells in vitro (up to 56.34 %) by the combination effects of TXT and NH{sub 2}@Fe{sub 3}O{sub 4}, however, less than 3 % of TXT released from the nanoparticles, which was very few to impair the adjacent normal cells and tissues. Therefore, this kind of novel agentia was expected to hold great potential in clinic urethral carcinoma therapy.

  7. Immunocapture of CD133-positive cells from human cancer cell lines by using monodisperse magnetic poly(glycidyl methacrylate) microspheres containing amino groups

    Energy Technology Data Exchange (ETDEWEB)

    Kuan, Wei-Chih [Department of Chemical Engineering, Systems Biology and Tissue Engineering Research Center, National Chung Cheng University, Minhisung 621, Taiwan (China); Horák, Daniel, E-mail: horak@imc.cas.cz [Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, Heyrovsky Sq. 2, 162 06 Prague 6 (Czech Republic); Plichta, Zdeněk [Institute of Macromolecular Chemistry, Academy of Sciences of the Czech Republic, Heyrovsky Sq. 2, 162 06 Prague 6 (Czech Republic); Lee, Wen-Chien [Department of Chemical Engineering, Systems Biology and Tissue Engineering Research Center, National Chung Cheng University, Minhisung 621, Taiwan (China)

    2014-01-01

    Magnetic poly(glycidyl methacrylate)-based macroporous microspheres with an average particle size of 4.2 μm were prepared using a modified multi-step swelling polymerization method and by introducing amino functionality on their surfaces. Antibody molecules were oxidized on their carbohydrate moieties and bound to the amino-containing magnetic microspheres via a site-directed procedure. CD133-positive cells could be effectively captured from human cancer cell lines (HepG2, HCT116, MCF7, and IMR-32) by using magnetic microspheres conjugated to an anti-human CD133 antibody. After further culture, the immunocaptured CD133-expressing cells from IMR-32 proliferated and gradually detached from the magnetic microspheres. Flow-cytometric analysis confirmed the enrichment of CD133-expressing cells by using the antibody-bound magnetic microspheres. Such microspheres suitable for immunocapture are very promising for cancer diagnosis because the CD133-expressing cells in cancer cell lines have been suggested to be cancer stem cells. - Highlights: • Multi-step swelling polymerization produced poly(glycidyl methacrylate) microspheres. • Anti-human CD133 antibodies were bound to the amino-containing magnetic microspheres. • CD133-positive cells were effectively captured from human cancer cell lines. • Immunocaptured CD133-expressing cells proliferated and were detached from microspheres. • Enrichment of CD133-expressing cells was confirmed by flow-cytometric analysis.

  8. MRI (Magnetic Resonance Imaging)

    Science.gov (United States)

    ... and Procedures Medical Imaging MRI (Magnetic Resonance Imaging) MRI (Magnetic Resonance Imaging) Share Tweet Linkedin Pin it More sharing options ... usually given through an IV in the arm. MRI Research Programs at FDA Magnetic Resonance Imaging (MRI) ...

  9. Magnetism of Carbonados

    Science.gov (United States)

    Kletetschka, G.; Taylor, P. T.; Wasilewski, P. J.

    2000-01-01

    Origin of Carbonado is not clear. Magnetism of Carbonado comes from the surface, indicating contemporary formation of both the surface and magnetic carriers. The interior of carbonado is relatively free of magnetic phases.

  10. Magnetic Resonance Imaging

    Science.gov (United States)

    ... metallic objects from being attracted by the powerful magnet of the MR system, you will typically receive ... teeth with magnetic keepers Other implants that involve magnets Medication patch (i.e., transdermal patch) that contains ...

  11. Magnetized accretion

    Science.gov (United States)

    Heyvaerts, J.

    This lecture reviews in simple terms the general subject of large scale magnetic field coupling to plasma flows in the vicinity of accreting compact stars. The relevant astrophysical phenomenology is summarized. Disk interaction with the magnetosphere of accreting stars is first discussed, in particular the structure of the magnetopause, its stability and plasma ejection in so-called propeller systems. The physics of accretion/ejection is then considered. Acceleration and focusing mechanisms of jets from accretion disks around compact stars or black holes and the question of the self-consistency of accretion and ejection are described. By contrast, small scale MHD turbulence in disks is not discussed, neither are accretion columns near the polar caps of neutron stars or white dwarfs. The reader is only assumed to have some basic knowledge of astrophysics and of fluid mechanics and electromagnetism.

  12. Smashing magnets

    Science.gov (United States)

    Ferrier-Barbut, Igor

    2016-11-01

    Understanding or designing phases of matter relies in the first place on the knowledge at the microscopic level of the interactions taking place between the constituents. In quantum gases, a renewed interest is rising about the interaction between two dipoles, owing to its anisotropic and long-range character. In a new paper, Burdick et al (2016 New J. Phys. 18 113004) demonstrate experimentally the angular-dependence of collisions between two dysprosium atoms, an atomic species that carries a magnetic dipole moment among the largest in the periodic table. This is realized by colliding two 164Dy Bose-Einstein condensates, and the experiments are backed by a theoretical analysis to connect these results with the two-body scattering cross-section. This represents a further step on the way to the full control of dipole-interacting many-body systems.

  13. Electromechanical integrated magnetic gear

    OpenAIRE

    Xiu-hong Hao; Hong-fei Zhang; Ji-de Men

    2016-01-01

    This study proposes a new type of magnetic gear, namely, the electromechanical integrated magnetic gear, that integrates the traditional field-modulated magnetic gear, drive, and control. The topology and operating principle of the electromechanical integrated magnetic gear are described in detail in this article, and the constraints of parameter design and speed ratio of electromechanical integrated magnetic gear are presented. Moreover, magnetic field distribution is analyzed with the finit...

  14. Developing bulk exchange spring magnets

    Energy Technology Data Exchange (ETDEWEB)

    Mccall, Scott K.; Kuntz, Joshua D.

    2017-06-27

    A method of making a bulk exchange spring magnet by providing a magnetically soft material, providing a hard magnetic material, and producing a composite of said magnetically soft material and said hard magnetic material to make the bulk exchange spring magnet. The step of producing a composite of magnetically soft material and hard magnetic material is accomplished by electrophoretic deposition of the magnetically soft material and the hard magnetic material to make the bulk exchange spring magnet.

  15. Magnetic Field Calculator

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The Magnetic Field Calculator will calculate the total magnetic field, including components (declination, inclination, horizontal intensity, northerly intensity,...

  16. Integrated magnetic transformer assembly

    DEFF Research Database (Denmark)

    2014-01-01

    The present invention relates to an integrated magnetics transformer assembly comprising a first magnetically permeable core forming a first substantially closed magnetic flux path and a second magnetically permeable core forming a second substantially closed magnetic flux path. A first input...... inductor winding is wound around a first predetermined segment of the first magnetically permeable core and a second input inductor winding is wound around a first predetermined segment of the second magnetically permeable core. The integrated magnetics transformer assembly further comprises a first output......-winding of the first output inductor winding and the first half-winding of the second output inductor winding are configured to produce aligned, i.e. in the same direction, magnetic fluxes through the first substantially closed magnetic flux path. The integrated magnetics transformer assembly is well- suited for use...

  17. Magnetic domains the analysis of magnetic microstructures

    CERN Document Server

    Hubert, Alex

    1998-01-01

    The book gives a systematic and comprehensive survey of the complete area of magnetic microstructures. It reaches from micromagnetism of nanoparticles to complex structures of extended magnetic materials. The book starts with a comprehensive evaluation of traditional and modern experimental methods for the observation of magnetic domains and continues with the treatment of important methods for the theoretical analysis of magnetic microcstructures. A survey of the necessary techniques in materials characterization is given. The book offers an observation and analysis of magnetic domains in all

  18. Magnetic hyperthermia in solid magnetic colloids

    Science.gov (United States)

    Zubarev, A. Yu.; Iskakova, L. Yu.; Abu-Bakr, A. F.

    2017-02-01

    We present results of theoretical study of magnetic hyperthermia in systems of single-domain ferromagnetic particles homogeneously distributed in a solid matrix. The heat effect is induced by linearly polarized alternating magnetic field. The effect of magnetic interaction between the particles as well as influence of orientation of the particles magnetic axes are in a focus of our consideration. Analysis shows that the interparticle interaction increases intensity of the heat production. The thermal effect in the systems with parallel orientation of the particles axes of easy magnetization is significantly higher than that in the case of random orientation of these axes.

  19. Environmental magnetism

    CERN Document Server

    Thompson, Roy

    1986-01-01

    The scientist will be forced, in the unenthusiastic words of one of my scientific colleagues, 'to slosh about in the primordial ooze known as inter-disciplinary studies'. John Passmore Man's responsibility for nature The present text has arisen from some thirteen years advances in our perception, appraisal and creative use of collaboration between the two authors. During that of order in natural systems. Out of this can come period, upwards of a dozen postgraduates in enhanced insight into processes, structures and Edinburgh, the New University of Ulster and Liver­ systems interactions on all temporal and spatial scales pool have been closely involved in exploring many of and at all integrative levels from subatomic to cosmic. the applications of magnetic measurements described In the environment, elements of order are often in the second half of the book. Much of the text is difficult to appraise and analyse, not only because of based on their work, both published and unpublished. intrinsic complexity, but ...

  20. Hoosier Magnetics

    Energy Technology Data Exchange (ETDEWEB)

    None, None

    2015-09-30

    Hoosier Magnetics proposes to replace the indirect clinker water cooling system with a cooling system that recycles heat from the hot ferrite to preheat the combustion air. This innovative process would significantly reduce the amount of natural gas required to heat the combustion air while eliminating Hoosier’s largest source of downtime. According to the Department of Energy’s Industrial Technologies Program for Energy Efficiency and Renewable Energy, process temperature is customarily used as a rough indication of where preheating air will be cost effective. Previous studies have concluded that processes operating above 1,600° F are ideal candidates for the utilization of pre-heated combustion air. Hoosier Magnetics’ operating temperatures run between 1800-2200° F making Hoosier the perfect candidate. Using preheated air at 1200° F will result in 35% fuel savings, or $298,935 annually. Additionally, the new system would have improved process reliability and result in both production efficiency increases and cost savings. This technology is NOT practiced or utilized on a wide-spread basis but could have a significant energy reduction impact in many different high heat utilizing industries in the country. While the energy savings is apparent with this theory the application and design of such a process has not been studied.

  1. Bifurcation magnetic resonance in films magnetized along hard magnetization axis

    Energy Technology Data Exchange (ETDEWEB)

    Vasilevskaya, Tatiana M., E-mail: t_vasilevs@mail.ru [Ulyanovsk State University, Leo Tolstoy 42, 432017 Ulyanovsk (Russian Federation); Sementsov, Dmitriy I.; Shutyi, Anatoliy M. [Ulyanovsk State University, Leo Tolstoy 42, 432017 Ulyanovsk (Russian Federation)

    2012-09-15

    We study low-frequency ferromagnetic resonance in a thin film magnetized along the hard magnetization axis performing an analysis of magnetization precession dynamics equations and numerical simulation. Two types of films are considered: polycrystalline uniaxial films and single-crystal films with cubic magnetic anisotropy. An additional (bifurcation) resonance initiated by the bistability, i.e. appearance of two closely spaced equilibrium magnetization states is registered. The modification of dynamic modes provoked by variation of the frequency, amplitude, and magnetic bias value of the ac field is studied. Both steady and chaotic magnetization precession modes are registered in the bifurcation resonance range. - Highlights: Black-Right-Pointing-Pointer An additional bifurcation resonance arises in a case of a thin film magnetized along HMA. Black-Right-Pointing-Pointer Bifurcation resonance occurs due to the presence of two closely spaced equilibrium magnetization states. Black-Right-Pointing-Pointer Both regular and chaotic precession modes are realized within bifurcation resonance range. Black-Right-Pointing-Pointer Appearance of dynamic bistability is typical for bifurcation resonance.

  2. A Magnetic Paradox

    Science.gov (United States)

    Arndt, Ebe

    2006-01-01

    Two recent articles in this journal described how an air core solenoid connected to an ac power source may restore the magnetization of a bar magnet with an alternating magnetic field (see Figs. 1 and 2). Although we are quite accustomed to using a constant magnetic field in an air core solenoid to remagnetize a ferromagnet, it is puzzling that we…

  3. Magnetic multilayer structure

    Energy Technology Data Exchange (ETDEWEB)

    Herget, Philipp; O' Sullivan, Eugene J.; Romankiw, Lubomyr T.; Wang, Naigang; Webb, Bucknell C.

    2017-03-21

    A mechanism is provided for an integrated laminated magnetic device. A substrate and a multilayer stack structure form the device. The multilayer stack structure includes alternating magnetic layers and diode structures formed on the substrate. Each magnetic layer in the multilayer stack structure is separated from another magnetic layer in the multilayer stack structure by a diode structure.

  4. Magnetic multilayer structure

    Science.gov (United States)

    Herget, Philipp; O'Sullivan, Eugene J.; Romankiw, Lubomyr T.; Wang, Naigang; Webb, Bucknell C.

    2016-07-05

    A mechanism is provided for an integrated laminated magnetic device. A substrate and a multilayer stack structure form the device. The multilayer stack structure includes alternating magnetic layers and diode structures formed on the substrate. Each magnetic layer in the multilayer stack structure is separated from another magnetic layer in the multilayer stack structure by a diode structure.

  5. Ferroelectricity in spiral magnets

    NARCIS (Netherlands)

    Mostovoy, M

    2006-01-01

    It was recently observed that the ferroelectrics showing the strongest sensitivity to an applied magnetic field are spiral magnets. We present a phenomenological theory of inhomogeneous ferroelectric magnets, which describes their thermodynamics and magnetic field behavior, e.g., dielectric suscepti

  6. Magnetic effects in electrochemistry

    Directory of Open Access Journals (Sweden)

    NEBOJSA D. NIKOLIC

    2005-05-01

    Full Text Available The effect of imposed magnetic fields onto the electrodeposition of magnetic (nickel and non – magnetic (copper metals was analysed. Also, magnetic properties of electrochemically obtained nanocontacts were examined. An effort to establish a possible correlation between the morphologies of the nanocontacts and the effect of the very large ballistic magnetoresistance (BMR effect was made.

  7. Fundamentals of magnetism

    CERN Document Server

    Reis, Mario

    2013-01-01

    The Fundamentals of Magnetism is a truly unique reference text, that explores the study of magnetism and magnetic behavior with a depth that no other book can provide. It covers the most detailed descriptions of the fundamentals of magnetism providing an emphasis on statistical mechanics which is absolutely critical for understanding magnetic behavior. The books covers the classical areas of basic magnetism, including Landau Theory and magnetic interactions, but features a more concise and easy-to-read style. Perfect for upper-level graduate students and industry researchers, The Fu

  8. Magnetic confinement

    Energy Technology Data Exchange (ETDEWEB)

    Batistoni, Paola; De Marco, Francesco; Pieroni, Leonardo (ed.)

    2005-07-01

    The Frascati Tokamak Upgrade (FTU) is a compact, high-magnetic-field tokamak capable of operating at density and magnetic field values similar to, or even encompassing, those of International Thermonuclear Experimental Reactor (ITER) and therefore provides a unique opportunity to explore physics issues that are directly relevant to ITER. During 2004 the experimental activities were focussed on fully exploiting the lower hybrid system (for generating and controlling the plasma current) and the electron cyclotron heating system (joint experiment with the Institute of Plasma Physics of the National Research Council, Milan). With all four gyrotrons in operation, full electron cyclotron power was achieved up to a record level of 1.5 MW. By simultaneously injecting lower hybrid waves, to tailor the plasma current radial profile, and electron cyclotron waves, to heat the plasma centre, good confinement regimes with internal transport barriers were obtained at the highest plasma density values ever achieved for this operation regime (n {approx}1.5X10{sup 20}m{sup -3}). Specific studies were devoted to optimising the coupling of lower hybrid waves to the plasma (by real-time control of the plasma position) and to generating current by electron cyclotron current drive. The new scanning CO{sub 2} interferometer (developed by the Reversed Field Experiment Consortium) for high spatial and time resolution (1 cm/50 {mu}s) density profile measurements was extensively used. The Thomson scattering diagnostic was upgraded and enabled observation of scattered signals associated with the Confinement background plasma dynamics. As for theoretical studies on the dynamics of turbulence in plasmas, the transition from Bohm-like scaling to gyro-Bohm scaling of the local plasma diffusivity was demonstrated on the basis of a generalised four wave model (joint collaboration with Princeton Plasma Physics Laboratory and the University of California at Irvine). The transition from weak to strong

  9. Ultrafast magnetization dynamics

    OpenAIRE

    Woodford, S.

    2008-01-01

    This thesis addresses ultrafast magnetization dynamics from a theoretical perspective. The manipulation of magnetization using the inverse Faraday effect has been studied, as well as magnetic relaxation processes in quantum dots. The inverse Faraday effect – the generation of a magnetic field by nonresonant, circularly polarized light – offers the possibility to control and reverse magnetization on a timescale of a few hundred femtoseconds. This is important both for the technological advant...

  10. Ultrafast Magnetization Dynamics

    OpenAIRE

    Woodford, S.

    2008-01-01

    This thesis addresses ultrafast magnetization dynamics from a theoretical perspective. The manipulation of magnetization using the inverse Faraday effect has been studied, as well as magnetic relaxation processes in quantum dots. The inverse Faraday effect – the generation of a magnetic field by nonresonant, circularly polarized light – offers the possibility to control and reverse magnetization on a timescale of a few hundred femtoseconds. This is important both for the technological advant...

  11. Permanent magnet system of alpha magnetic spectrometer

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    Alpha magnetic spectrometer (AMS) is the first large magnetic spectrometer in space. Its precursor flight was completed successfully in June 1998. The key part of AMS is the permanent magnet system, which was built by the Institute of Electric Engineering, the Institute of High Energy Physics and the Chinese Academy of Launch Vehicle Technology. This system includes a permanent magnet made of high grade NdFeB and a support structure. The unique design of the permanent magnet based on the magic ring fulfills the severe requirements on the magnetic field leakage and the dipole moment for space experiments. The permanent magnet weighs about 2 tons, and provides a geometric acceptance of 0.6 m2 ·sr and an analyzing power BL2 of 0.135 T·m2. It works up to 40℃ without demagnetization. The main structure is a thin double shell, which undergoes the strong magnetic force and torque of the permanent magnet, as well as the large load during launching and landing. The permanent magnet system fulfills the requirements from AMS, and satisfies the strict safety standards of NASA.

  12. Permanent magnet system of alpha magnetic spectrometer

    Institute of Scientific and Technical Information of China (English)

    陈和生

    2000-01-01

    Alpha magnetic spectrometer (AMS) is the first large magnetic spectrometer in space. Its precursor flight was completed successfully in June 1998. The key part of AMS is the permanent magnet system, which was built by the Institute of Electric Engineering, the Institute of High Energy Physics and the Chinese Academy of Launch Vehicle Technology. This system includes a permanent magnet made of high grade NdFeB and a support structure. The unique design of the permanent magnet based on the magic ring fulfills the severe requirements on the magnetic field leakage and the dipole moment for space experiments. The permanent magnet weighs about 2 tons, and provides a geometric acceptance of 0.6 m2·sr and an analyzing power BL2 of 0.135 T·m2. It works up to 40℃ without demagnetization. The main structure is a thin double shell, which undergoes the strong magnetic force and torque of the permanent magnet, as well as the large load during launching and landing. The permanent magnet system fulfills the requirem

  13. Magnetic novae

    Science.gov (United States)

    Zemko, Polina; Orio, Marina

    2016-07-01

    We present the results of optical and X-ray observations of two quiescent novae, V2491 Cyg and V4743 Sgr. Our observations suggest the intriguing possibility of localization of hydrogen burning in magnetic novae, in which accretion is streamed to the polar caps. V2491 Cyg was observed with Suzaku more than 2 years after the outburst and V4743 Sgr was observed with XMM Newton 2 and 3.5 years after maximum. In the framework of a monitoring program of novae previously observed as super soft X-ray sources we also obtained optical spectra of V4743 Sgr with the SALT telescope 11.5 years after the eruption and of V2491 Cyg with the 6m Big Azimutal Telescope 4 and 7 years post-outburst. In order to confirm the possible white dwarf spin period of V2491 Cyg measured in the Suzaku observations we obtained photometric data using the 90cm WIYN telescope at Kitt Peak and the 1.2 m telescope in Crimea. We found that V4743 Sgr is an intermediate polar (IP) and V2491 Cyg is a strong IP candidate. Both novae show modulation of their X-ray light curves and have X-ray spectra typical of IPs. The Suzaku and XMM Newton exposures revealed that the spectra of both novae have a very soft blackbody-like component with a temperature close to that of the hydrogen burning white dwarfs in their SSS phases, but with flux by at least two orders of magnitude lower, implying a possible shrinking of emitting regions in the thin atmosphere that is heated by nuclear burning underneath it. In quiescent IPs, independently of the burning, an ultrasoft X-ray flux component originates at times in the polar regions irradiated by the accretion column, but the soft component of V4743 Sgr disappeared in 2006, indicating that the origin may be different from accretion. We suggest it may have been due to an atmospheric temperature gradient on the white dwarf surface, or to continuing localized thermonuclear burning at the bottom of the envelope, before complete turn-off. The optical spectra of V2491 Cyg and V

  14. Magnetically Damped Furnace Bitter Magnet Coil 1

    Science.gov (United States)

    Bird, M. D.

    1997-01-01

    A magnet has been built by the National High Magnetic Field Laboratory for NASA on a cost reimbursement contract. The magnet is intended to demonstrate the technology and feasibility of building a magnet for space based crystal growth. A Bitter magnet (named after Francis Bitter, its inventor) was built consisting of four split coils electrically in series and hydraulically in parallel. The coils are housed in a steel vessel to reduce the fringe field and provide some on-axis field enhancement. The steel was nickel plated and Teflon coated to minimize interaction with the water cooling system. The magnet provides 0.14 T in a 184 mm bore with 3 kW of power.

  15. Cosmological Magnetic Fields

    CERN Document Server

    Kunze, Kerstin E

    2013-01-01

    Magnetic fields are observed on nearly all scales in the universe, from stars and galaxies upto galaxy clusters and even beyond. The origin of cosmic magnetic fields is still an open question, however a large class of models puts its origin in the very early universe. A magnetic dynamo amplifying an initial seed magnetic field could explain the present day strength of the galactic magnetic field. However, it is still an open problem how and when this initial magnetic field was created. Observations of the cosmic microwave background (CMB) provide a window to the early universe and might therefore be able to tell us whether cosmic magnetic fields are of primordial, cosmological origin and at the same time constrain its parameters. We will give an overview of the observational evidence of large scale magnetic fields, describe generation mechanisms of primordial magnetic fields and possible imprints in the CMB.

  16. Advanced Magnetic Nanostructures

    CERN Document Server

    Sellmyer, David

    2006-01-01

    Advanced Magnetic Nanostructures is devoted to the fabrication, characterization, experimental investigation, theoretical understanding, and utilization of advanced magnetic nanostructures. Focus is on various types of 'bottom-up' and 'top-down' artificial nanostructures, as contrasted to naturally occurring magnetic nanostructures, such as iron-oxide inclusions in magnetic rocks, and to structures such as perfect thin films. Chapter 1 is an introduction into some basic concepts, such as the definitions of basic magnetic quantities. Chapters 2-4 are devoted to the theory of magnetic nanostructures, Chapter 5 deals with the characterization of the structures, and Chapters 6-10 are devoted to specific systems. Applications of advanced magnetic nanostructures are discussed in Chapters11-15 and, finally, the appendix lists and briefly discusses magnetic properties of typical starting materials. Industrial and academic researchers in magnetism and related areas such as nanotechnology, materials science, and theore...

  17. Multifunctionality in molecular magnetism.

    Science.gov (United States)

    Pinkowicz, Dawid; Czarnecki, Bernard; Reczyński, Mateusz; Arczyński, Mirosław

    2015-01-01

    Molecular magnetism draws from the fundamental ideas of structural chemistry and combines them with experimental physics resulting in one of the highest profile current topics, namely molecular materials that exhibit multifunctionality. Recent advances in the design of new generations of multifunctional molecular magnets that retain the functions of the building blocks and exhibit non-trivial magnetic properties at higher temperatures provide promising evidence that they may be useful for the future construction of nanoscale devices. This article is not a complete review but is rather an introduction into thefascinating world of multifunctional solids with magnetism as the leitmotif. We provide a subjective selection and discussion of the most inspiring examples of multifunctional molecular magnets: magnetic sponges, guest-responsive magnets, molecular magnets with ionic conductivity, photomagnets and non-centrosymmetric and chiral magnets.

  18. CME Magnetic Structure and Magnetic Cloud Signature

    Science.gov (United States)

    Li, Yan; Luhmann, J.

    2006-06-01

    An interplanetary coronal mass ejection (ICME) is the counterpart of a coronal mass ejection by definition. However, the relationship between the magnetic structures of the CMEs and that of the situ observations of ICMEs is still quite far from clear, due to observational gaps and the state of our understanding of CMEs. Some studies suggested that the magnetic cloud (MC, a group of ICMEs with fluxrope signatures) magnetic polarity follows the solar large scale magnetic field, and others suggested it follows the local magnetic field of the CME source region. Recent studies found that the relationship is more complex. While solar cycle dependence of the magnetic signature of MCs is clearly evident, the polarity of the MCs does not reverse at the same time when the solar large scale field reverses around solar maximum, but begins to have mixed polarities, and the new polarity may only prevail at the midst of the declining phase. Interestingly, in an independent study of the magnetic topology at the CME source regions, we found a similar solar cycle dependence of the bipolar and quadrupolar topologie. In this work, the link between CMEs and ICMEs is made and the results will shed light on our understanding about the relationship between CME and ICME magnetic structures and how these structures are related to solar local and large scale magnetic fields.Acknowledgement: ATM/NSF-0451438, SRT/NASA-NNG06GE51G and CISM/NSF.

  19. Micro-Magnets

    Science.gov (United States)

    Herlach, F.; Volodin, A.; Van Haesendonck, C.

    2004-11-01

    Suggestions are made regarding the feasibility of building very small electromagnets for experimental applications. These structures would be made by lithographic techniques on a scale of microns. However, pulsed solenoid magnets with a bore on the order of a millimeter are also considered. These must be immersed in the cryogenic liquid used in the experiment, as the small bore does not allow for a separate cryostat. The magnets made by lithography could be single loops (e.g. to provide a field gradient), spirals, Helmholtz pairs, or stacks resembling a Bitter magnet. Superconducting magnets, resistive dc magnets and pulsed magnets (both non-destructive as well as self-destructing) are all considered.

  20. Tamper resistant magnetic stripes

    Science.gov (United States)

    Naylor, Richard Brian; Sharp, Donald J.

    1999-01-01

    This invention relates to a magnetic stripe comprising a medium in which magnetized particles are suspended and in which the encoded information is recorded by actual physical rotation or alignment of the previously magnetized particles within the flux reversals of the stripe which are 180.degree. opposed in their magnetic polarity. The magnetized particles are suspended in a medium which is solid, or physically rigid, at ambient temperatures but which at moderately elevated temperatures, such as 40.degree. C., is thinable to a viscosity permissive of rotation of the particles therein under applications of moderate external magnetic field strengths within acceptable time limits.

  1. Multilayered Magnetic Gelatin Membrane Scaffolds

    Science.gov (United States)

    Samal, Sangram K.; Goranov, Vitaly; Dash, Mamoni; Russo, Alessandro; Shelyakova, Tatiana; Graziosi, Patrizio; Lungaro, Lisa; Riminucci, Alberto; Uhlarz, Marc; Bañobre-López, Manuel; Rivas, Jose; Herrmannsdörfer, Thomas; Rajadas, Jayakumar; De Smedt, Stefaan; Braeckmans, Kevin; Kaplan, David L.; Dediu, V. Alek

    2016-01-01

    A versatile approach for the design and fabrication of multilayer magnetic scaffolds with tunable magnetic gradients is described. Multilayer magnetic gelatin membrane scaffolds with intrinsic magnetic gradients were designed to encapsulate magnetized bioagents under an externally applied magnetic field for use in magnetic-field-assisted tissue engineering. The temperature of the individual membranes increased up to 43.7 °C under an applied oscillating magnetic field for 70 s by magnetic hyperthermia, enabling the possibility of inducing a thermal gradient inside the final 3D multilayer magnetic scaffolds. On the basis of finite element method simulations, magnetic gelatin membranes with different concentrations of magnetic nanoparticles were assembled into 3D multilayered scaffolds. A magnetic-gradient-controlled distribution of magnetically labeled stem cells was demonstrated in vitro. This magnetic biomaterial–magnetic cell strategy can be expanded to a number of different magnetic biomaterials for various tissue engineering applications. PMID:26451743

  2. The magnetic stress tensor in magnetized matter

    CERN Document Server

    Espinosa, Olivier R; Espinosa, Olivier; Reisenegger, Andreas

    2003-01-01

    We derive the form of the magnetic stress tensor in a completely general, stationary magnetic medium, with an arbitrary magnetization field $vec M(vec r)$ and free current density $vec j(vec r)$. We start with the magnetic force density $vec f$ acting on a matter element, modelled as a collection of microscopic magnetic dipoles in addition to the free currents. We show that there is a unique tensor ${bf T}$ quadratic in the magnetic flux density $vec B(vec r)$ and the magnetic field $vec H(vec r)=vec B-4pivec M$ whose divergence is $nablacdot{bf T}=vec f$. In the limit $vec M=0$, the well-known vacuum magnetic stress tensor is recovered. However, the general form of the tensor is asymmetric, leading to a divergent angular acceleration for matter elements of vanishing size. We argue that this is not inconsistent, because it occurs only if $vec M$ and $vec B$ are not parallel, in which case the macroscopic field does indeed exert a torque on each of the microscopic dipoles, so this state is only possible if the...

  3. Magnetic Graphene Nanohole Superlattices

    CERN Document Server

    Yu, Decai; Liu, Miao; Liu, Wei; Liu, Feng

    2008-01-01

    We investigate the magnetic properties of nano-holes (NHs) patterned in graphene using first principles calculations. We show that superlattices consisting of a periodic array of NHs form a new family of 2D crystalline "bulk" magnets whose collective magnetic behavior is governed by inter-NH spin-spin interaction. They exhibit long-range magnetic order well above room temperature. Furthermore, magnetic semiconductors can be made by doping magnetic NHs into semiconducting NH superlattices. Our findings offer a new material system for fundamental studies of spin-spin interaction and magnetic ordering in low dimensions, and open up the exciting opportunities of making engineered magnetic materials for storage media and spintronics applications.

  4. Enhanced Magnetic Model 2015

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The Enhanced Magnetic Model (EMM) extends to degree and order 720, resolving magnetic anomalies down to 56 km wavelength. The higher resolution of the EMM results in...

  5. Magnetic fields in galaxies

    CERN Document Server

    Beck, Rainer

    2013-01-01

    Most of the visible matter in the Universe is ionized, so that cosmic magnetic fields are quite easy to generate and due to the lack of magnetic monopoles hard to destroy. Magnetic fields have been measured in or around practically all celestial objects, either by in-situ measurements of spacecrafts or by the electromagnetic radiation of embedded cosmic rays, gas or dust. The Earth, the Sun, solar planets, stars, pulsars, the Milky Way, nearby galaxies, more distant (radio) galaxies, quasars and even intergalactic space in clusters of galaxies have significant magnetic fields, and even larger volumes of the Universe may be permeated by "dark" magnetic fields. Information on cosmic magnetic fields has increased enormously as the result of the rapid development of observational methods, especially in radio astronomy. In the Milky Way, a wealth of magnetic phenomena was discovered, which are only partly related to objects visible in other spectral ranges. The large-scale structure of the Milky Way's magnetic fie...

  6. ISR magnet power supplies

    CERN Multimedia

    1970-01-01

    At the left, for the main magnets, the 18 kV switchgear is in the foreground and at the rear are cubicles with rectifiers and filters. At the right, rear, are rectifiers for pole face windings and auxiliary magnets.

  7. Magnetic Resonance (MR) Defecography

    Science.gov (United States)

    ... their nature and the strength of the MRI magnet. Many implanted devices will have a pamphlet explaining ... large cylinder-shaped tube surrounded by a circular magnet. You will lie on a moveable examination table ...

  8. Project Magnet 1996

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — Project Magnet data include low altitude, high density individual track line surveys, high altitude vector data and regional magnetic anomaly grids.

  9. Active magnetic regenerator

    Science.gov (United States)

    Barclay, John A.; Steyert, William A.

    1982-01-01

    The disclosure is directed to an active magnetic regenerator apparatus and method. Brayton, Stirling, Ericsson, and Carnot cycles and the like may be utilized in an active magnetic regenerator to provide efficient refrigeration over relatively large temperature ranges.

  10. Electromechanical integrated magnetic gear

    Directory of Open Access Journals (Sweden)

    Xiu-hong Hao

    2016-06-01

    Full Text Available This study proposes a new type of magnetic gear, namely, the electromechanical integrated magnetic gear, that integrates the traditional field-modulated magnetic gear, drive, and control. The topology and operating principle of the electromechanical integrated magnetic gear are described in detail in this article, and the constraints of parameter design and speed ratio of electromechanical integrated magnetic gear are presented. Moreover, magnetic field distribution is analyzed with the finite element method. Subsequently, the harmonics of the magnetic field and the electromagnetic torque are calculated. The static torques on all the components are exhibited by finite element method and torque test. The effects of the design parameters on the torques and the torque densities are discussed, and the results show that electromechanical integrated magnetic gear has a high speed ratio and can generate a high torque at low speed. The maximum torques are affected by air-gap thickness and other parameters.

  11. Magnetic induction hyperthermia

    Science.gov (United States)

    Nikiforov, V. N.

    2007-09-01

    A review of physical principles and experimental data on magnetic hyperthermia are presented. The main principles of magnetic hyperthermia are considered. Results of its application in the therapy of oncology diseases are presented.

  12. Boulder Magnetic Observatory

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — These data are vector and scalar component values of the Earth's magnetic field for 2004 recorded at the Boulder Magnetic Observatory in Colorado. Vector values are...

  13. Enhanced Magnetic Model 2010

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The Enhanced Magnetic Model (EMM) extends to degree and order 720, resolving magnetic anomalies down to 56 km wavelength. The higher resolution of the EMM results in...

  14. Magnetism basics and applications

    CERN Document Server

    Stefanita, Carmen-Gabriela

    2012-01-01

    This textbook is aimed at engineering students who are likely to come across magnetics applications in their professional practice. Whether designing lithography equipment containing ferromagnetic brushes, or detecting defects in aeronautics, some basic knowledge of 21st century magnetism is needed. From the magnetic tape on the pocket credit card to the read head in a personal computer, people run into magnetism in many products. Furthermore, in a variety of disciplines tools of the trade exploit magnetic principles, and many interdisciplinary laboratory research areas cross paths with magnetic phenomena that may seem mysterious to the untrained mind. Therefore, this course offers a broad coverage of magnetism topics encountered more often in this millenium, revealing key concepts on which many practical applications rest. Some traditional subjects in magnetism are discussed in the first half of the book, followed by areas likely to spark the curiosity of those more interested in today’s technological achi...

  15. Magnetic Field Grid Calculator

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The Magnetic Field Properties Calculator will computes the estimated values of Earth's magnetic field(declination, inclination, vertical component, northerly...

  16. Axial Halbach Magnetic Bearings

    Science.gov (United States)

    Eichenberg, Dennis J.; Gallo, Christopher A.; Thompson, William K.

    2008-01-01

    Axial Halbach magnetic bearings have been investigated as part of an effort to develop increasingly reliable noncontact bearings for future high-speed rotary machines that may be used in such applications as aircraft, industrial, and land-vehicle power systems and in some medical and scientific instrumentation systems. Axial Halbach magnetic bearings are passive in the sense that unlike most other magnetic bearings that have been developed in recent years, they effect stable magnetic levitation without need for complex active control.

  17. The Earth's Magnetic Field

    OpenAIRE

    Edda Lína Gunnarsdóttir 1988

    2012-01-01

    The Earth's magnetic field is essential for life on Earth, as we know it, to exist. It forms a magnetic shield around the planet, protecting it from high energy particles and radiation from the Sun, which can cause damage to life, power systems, orbiting satellites, astronauts and spacecrafts. This report contains a general overview of the Earth's magnetic field. The different sources that contribute to the total magnetic field are presented and the diverse variations in the field are describ...

  18. Magnetic actuators and sensors

    CERN Document Server

    Brauer, John R

    2014-01-01

    An accessible, comprehensive guide on magnetic actuators and sensors, this fully updated second edition of Magnetic Actuators and Sensors includes the latest advances, numerous worked calculations, illustrations, and real-life applications. Covering magnetics, actuators, sensors, and systems, with updates of new technologies and techniques, this exemplary learning tool emphasizes computer-aided design techniques, especially magnetic finite element analysis, commonly used by today's engineers. Detailed calculations, numerous illustrations, and discussions of discrepancies make this text an inva

  19. Magnetic cluster excitations

    Science.gov (United States)

    Furrer, Albert; Waldmann, Oliver

    2013-01-01

    Magnetic clusters, i.e., assemblies of a finite number (between two or three and several hundred) of interacting spin centers which are magnetically decoupled from their environment, can be found in many materials ranging from inorganic compounds and magnetic molecules to artificial metal structures formed on surfaces and metalloproteins. Their magnetic excitation spectra are determined by the nature of the spin centers and of the magnetic interactions, and the particular arrangement of the mutual interaction paths between the spin centers. Small clusters of up to four magnetic ions are ideal model systems in which to examine the fundamental magnetic interactions, which are usually dominated by Heisenberg exchange, but often complemented by anisotropic and/or higher-order interactions. In large magnetic clusters, which may potentially deal with a dozen or more spin centers, there is the possibility of novel many-body quantum states and quantum phenomena. In this review the necessary theoretical concepts and experimental techniques to study the magnetic cluster excitations and the resulting characteristic magnetic properties are introduced, followed by examples of small clusters, demonstrating the enormous amount of detailed physical information that can be retrieved. The current understanding of the excitations and their physical interpretation in the molecular nanomagnets which represent large magnetic clusters is then presented, with a section devoted to the subclass of single-molecule magnets, distinguished by displaying quantum tunneling of the magnetization. Finally, there is a summary of some quantum many-body states which evolve in magnetic insulators characterized by built-in or field-induced magnetic clusters. The review concludes by addressing future perspectives in the field of magnetic cluster excitations.

  20. Magnetic fusion technology

    CERN Document Server

    Dolan, Thomas J

    2014-01-01

    Magnetic Fusion Technology describes the technologies that are required for successful development of nuclear fusion power plants using strong magnetic fields. These technologies include: ? magnet systems, ? plasma heating systems, ? control systems, ? energy conversion systems, ? advanced materials development, ? vacuum systems, ? cryogenic systems, ? plasma diagnostics, ? safety systems, and ? power plant design studies. Magnetic Fusion Technology will be useful to students and to specialists working in energy research.

  1. Rotating superconductor magnet for producing rotating lobed magnetic field lines

    Science.gov (United States)

    Hilal, Sadek K.; Sampson, William B.; Leonard, Edward F.

    1978-01-01

    This invention provides a rotating superconductor magnet for producing a rotating lobed magnetic field, comprising a cryostat; a superconducting magnet in the cryostat having a collar for producing a lobed magnetic field having oppositely directed adjacent field lines; rotatable support means for selectively rotating the superconductor magnet; and means for energizing the superconductor magnet.

  2. Common Magnets, Unexpected Polarities

    Science.gov (United States)

    Olson, Mark

    2013-01-01

    In this paper, I discuss a "misconception" in magnetism so simple and pervasive as to be typically unnoticed. That magnets have poles might be considered one of the more straightforward notions in introductory physics. However, the magnets common to students' experiences are likely different from those presented in educational…

  3. Iron dominated magnets

    Energy Technology Data Exchange (ETDEWEB)

    Fischer, G.E.

    1985-07-01

    These two lectures on iron dominated magnets are meant for the student of accelerator science and contain general treatments of the subjects design and construction. The material is arranged in the categories: General Concepts and Cost Considerations, Profile Configuration and Harmonics, Magnetic Measurements, a few examples of ''special magnets'' and Materials and Practices. Extensive literature is provided.

  4. Magnetism in meteorites

    Science.gov (United States)

    Herndon, J. M.; Rowe, M. W.

    1974-01-01

    An overview is presented of magnetism in meteorites. A glossary of magnetism terminology followed by discussion of the various techniques used for magnetism studies in meteorites are included. The generalized results from use of these techniques by workers in the field are described. A brief critical analysis is offered.

  5. Nanochemistry and magnetism

    Science.gov (United States)

    Buchachenko, A. L.

    2009-10-01

    An analysis of magnetism of nanochemical systems opens up new ways to creating ferromagnets from diamagnetic substances and new principles for constructing molecular ferromagnets, hybrid magnetic materials, and monomolecular magnets on the basis of high-spin molecules and complexes. Their use in spin computing is considered.

  6. The Juno Magnetic Field Investigation

    DEFF Research Database (Denmark)

    Connerney, J. E. P.; Benn, Mathias; Bjarnø, Jonas Bækby

    2017-01-01

    The Juno Magnetic Field investigation (MAG) characterizes Jupiter’s planetary magnetic field and magnetosphere, providing the first globally distributed and proximate measurements of the magnetic field of Jupiter. The magnetic field instrumentation consists of two independent magnetometer sensor ...

  7. Magnetic hyperthermia with hard-magnetic nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Kashevsky, Bronislav E., E-mail: bekas@itmo.by [A.V Luikov Heat and Mass Transfer Institute, Belarus Academy of Sciences, P. Brovka str. 15, Minsk 220072 (Belarus); Kashevsky, Sergey B.; Korenkov, Victor S. [A.V Luikov Heat and Mass Transfer Institute, Belarus Academy of Sciences, P. Brovka str. 15, Minsk 220072 (Belarus); Istomin, Yuri P. [N. N. Alexandrov National Cancer Center of Belarus, Lesnoy-2, Minsk 223040 (Belarus); Terpinskaya, Tatyana I.; Ulashchik, Vladimir S. [Institute of Physiology, Belarus Academy of Sciences, Akademicheskaya str. 28, Minsk 220072 (Belarus)

    2015-04-15

    Recent clinical trials of magnetic hyperthermia have proved, and even hardened, the Ankinson-Brezovich restriction as upon magnetic field conditions applicable to any site of human body. Subject to this restriction, which is harshly violated in numerous laboratory and small animal studies, magnetic hyperthermia can relay on rather moderate heat source, so that optimization of the whole hyperthermia system remains, after all, the basic problem predetermining its clinical perspectives. We present short account of our complex (theoretical, laboratory and small animal) studies to demonstrate that such perspectives should be related with the hyperthermia system based on hard-magnetic (Stoner–Wohlfarth type) nanoparticles and strong low-frequency fields rather than with superparamagnetic (Brownian or Neél) nanoparticles and weak high-frequency fields. This conclusion is backed by an analytical evaluation of the maximum absorption rates possible under the field restriction in the ideal hard-magnetic (Stoner–Wohlarth) and the ideal superparamagnetic (single relaxation time) systems, by theoretical and experimental studies of the dynamic magnetic hysteresis in suspensions of movable hard-magnetic particles, by producing nanoparticles with adjusted coercivity and suspensions of such particles capable of effective energy absorption and intratumoral penetration, and finally, by successful treatment of a mice model tumor under field conditions acceptable for whole human body. - Highlights: • Hard-magnetic nanoparticles are shown superior for hyperthetmia to superparamagnetic. • Optimal system parameters are found from magnetic reversal model in movable particle. • Penetrating suspension of HM particles with aggregation-independent SAR is developed. • For the first time, mice with tumors are healed in AC field acceptable for human body.

  8. Permanent-Magnet Meissner Bearing

    Science.gov (United States)

    Robertson, Glen A.

    1994-01-01

    Permanent-magnet meissner bearing features inherently stable, self-centering conical configuration. Bearing made stiffer or less stiff by selection of magnets, springs, and spring adjustments. Cylindrical permanent magnets with axial magnetization stacked coaxially on rotor with alternating polarity. Typically, rare-earth magnets used. Magnets machined and fitted together to form conical outer surface.

  9. Magnetism: a supramolecular function

    Energy Technology Data Exchange (ETDEWEB)

    Decurtins, S.; Pellaux, R.; Schmalle, H.W. [Zurich Univ., Inst. fuer Anorganische Chemie, Zurich (Switzerland)

    1996-11-01

    The field of molecule-based magnetism has developed tremendously in the last few years. Two different extended molecular - hence supramolecular -systems are presented. The Prussian-blue analogues show some of the highest magnetic ordering temperature of any class of molecular magnets, T{sub c} = 315 K, whereas the class of transition-metal oxalate-bridged compounds exhibits a diversity of magnetic phenomena. Especially for the latter compounds, the elastic neutron scattering technique has successfully been proven to trace the magnetic structure of these supramolecular and chiral compounds. (author) 18 figs., 25 refs.

  10. Switchable molecular magnets.

    Science.gov (United States)

    Sato, Osamu

    2012-01-01

    Various molecular magnetic compounds whose magnetic properties can be controlled by external stimuli have been developed, including electrochemically, photochemically, and chemically tunable bulk magnets as well as a phototunable antiferromagnetic phase of single chain magnet. In addition, we present tunable paramagnetic mononuclear complexes ranging from spin crossover complexes and valence tautomeric complexes to Co complexes in which orbital angular momentum can be switched. Furthermore, we recently developed several switchable clusters and one-dimensional coordination polymers. The switching of magnetic properties can be achieved by modulating metals, ligands, and molecules/ions in the second sphere of the complexes.

  11. Magnetic nanocomposite sensor

    KAUST Repository

    Alfadhel, Ahmed

    2016-05-06

    A magnetic nanocomposite device is described herein for a wide range of sensing applications. The device utilizes the permanent magnetic behavior of the nanowires to allow operation without the application of an additional magnetic field to magnetize the nanowires, which simplifies miniaturization and integration into microsystems. In5 addition, the nanocomposite benefits from the high elasticity and easy patterning of the polymer-based material, leading to a corrosion-resistant, flexible material that can be used to realize extreme sensitivity. In combination with magnetic sensor elements patterned underneath the nanocomposite, the nanocomposite device realizes highly sensitive and power efficient flexible artificial cilia sensors for flow measurement or tactile sensing.

  12. Magnetism and metallurgy of soft magnetic materials

    CERN Document Server

    Chen, Chih-Wen

    2011-01-01

    Soft magnetic materials are economically and technologically the most important of all magnetic materials. In particular, the development of new materials and novel applications for the computer and telecommunications industries during the past few decades has immensely broadened the scope and altered the nature of soft magnetic materials. In addition to metallic substances, nonmetallic compounds and amorphous thin films are coming increasingly important. This thorough, well-organized volume - on of the most comprehensive treatments available - offers a coherent, logical presentation of the p

  13. Magnetic volumetric hologram memory with magnetic garnet.

    Science.gov (United States)

    Nakamura, Yuichi; Takagi, Hiroyuki; Lim, Pang Boey; Inoue, Mitsuteru

    2014-06-30

    Holographic memory is a promising next-generation optical memory that has a higher recording density and a higher transfer rate than other types of memory. In holographic memory, magnetic garnet films can serve as rewritable holographic memory media by use of magneto-optical effect. We have now demonstrated that a magnetic hologram can be recorded volumetrically in a ferromagnetic garnet film and that the signal image can be reconstructed from it for the first time. In addition, multiplicity of the magnetic hologram was also confirmed; the image could be reconstructed from a spot overlapped by other spots.

  14. Molecule-based magnets

    Indian Academy of Sciences (India)

    J V Yakhmi

    2009-06-01

    The conventional magnetic materials used in current technology, such as, Fe, Fe2O3, Cr2O3, SmCo5, Nd2Fe14B etc are all atom-based, and their preparation/processing require high temperature routes. Employing self-assembly methods, it is possible to engineer a bulk molecular material with long-range magnetic order, mainly because one can play with the weak intermolecular interactions. Since the first successful synthesis of molecular magnets in 1986, a large variety of them have been synthesized, which can be categorized on the basis of the chemical nature of the magnetic units involved: organic-, metal-based systems, heterobimetallic assemblies, or mixed organic–inorganic systems. The design of molecule-based magnets has also been extended to the design of poly-functional molecular magnets, such as those exhibiting second-order optical nonlinearity, liquid crystallinity, or chirality simultaneously with long-range magnetic order. Solubility, low density and biocompatibility are attractive features of molecular magnets. Being weakly coloured, unlike their opaque classical magnet ‘cousins’ listed above, possibilities of photomagnetic switching exist. Persistent efforts also continue to design the ever-elusive polymer magnets towards applications in industry. While providing a brief overview of the field of molecular magnetism, this article highlights some recent developments in it, with emphasis on a few studies from the author’s own lab.

  15. Magnetically responsive enzyme powders

    Energy Technology Data Exchange (ETDEWEB)

    Pospiskova, Kristyna, E-mail: kristyna.pospiskova@upol.cz [Regional Centre of Advanced Technologies and Materials, Palacky University, Slechtitelu 11, 783 71 Olomouc (Czech Republic); Safarik, Ivo, E-mail: ivosaf@yahoo.com [Regional Centre of Advanced Technologies and Materials, Palacky University, Slechtitelu 11, 783 71 Olomouc (Czech Republic); Department of Nanobiotechnology, Institute of Nanobiology and Structural Biology of GCRC, Na Sadkach 7, 370 05 Ceske Budejovice (Czech Republic)

    2015-04-15

    Powdered enzymes were transformed into their insoluble magnetic derivatives retaining their catalytic activity. Enzyme powders (e.g., trypsin and lipase) were suspended in various liquid media not allowing their solubilization (e.g., saturated ammonium sulfate and highly concentrated polyethylene glycol solutions, ethanol, methanol, 2-propanol) and subsequently cross-linked with glutaraldehyde. Magnetic modification was successfully performed at low temperature in a freezer (−20 °C) using magnetic iron oxides nano- and microparticles prepared by microwave-assisted synthesis from ferrous sulfate. Magnetized cross-linked enzyme powders were stable at least for two months in water suspension without leakage of fixed magnetic particles. Operational stability of magnetically responsive enzymes during eight repeated reaction cycles was generally without loss of enzyme activity. Separation of magnetically modified cross-linked powdered enzymes from reaction mixtures was significantly simplified due to their magnetic properties. - Highlights: • Cross-linked enzyme powders were prepared in various liquid media. • Insoluble enzymes were magnetized using iron oxides particles. • Magnetic iron oxides particles were prepared by microwave-assisted synthesis. • Magnetic modification was performed under low (freezing) temperature. • Cross-linked powdered trypsin and lipase can be used repeatedly for reaction.

  16. Tunneling magnetic force microscopy

    Science.gov (United States)

    Burke, Edward R.; Gomez, Romel D.; Adly, Amr A.; Mayergoyz, Isaak D.

    1993-01-01

    We have developed a powerful new tool for studying the magnetic patterns on magnetic recording media. This was accomplished by modifying a conventional scanning tunneling microscope. The fine-wire probe that is used to image surface topography was replaced with a flexible magnetic probe. Images obtained with these probes reveal both the surface topography and the magnetic structure. We have made a thorough theoretical analysis of the interaction between the probe and the magnetic fields emanating from a typical recorded surface. Quantitative data about the constituent magnetic fields can then be obtained. We have employed these techniques in studies of two of the most important issues of magnetic record: data overwrite and maximizing data-density. These studies have shown: (1) overwritten data can be retrieved under certain conditions; and (2) improvements in data-density will require new magnetic materials. In the course of these studies we have developed new techniques to analyze magnetic fields of recorded media. These studies are both theoretical and experimental and combined with the use of our magnetic force scanning tunneling microscope should lead to further breakthroughs in the field of magnetic recording.

  17. Magnetically recoverable nanocatalysts

    KAUST Repository

    Polshettiwar, Vivek

    2011-05-11

    A broad overview on magnetically recoverable nanocatalysts is presented and the use of magnetic nanomaterials as catalysts is discussed. Magnetic materials are used as organocatalysts and their applications range to challenging reactions, such as hydroformylation and olefin metathesis. Magnetic nanomaterials are also being used in environmental applications, such as for photo- and biocatalysis and for the adsorption and removal of pollutants from air and water. These materials show great promise as enantioselective catalysts, which are used extensively for the synthesis of medicines, drugs, and other bioactive molecules. By functionalizing these materials using chiral ligands, a series of chiral nanocatalysts can be designed, offering great potential to reuse these otherwise expensive catalyst systems. Characterization of magnetic catalysts is often a challenging task, and NMR characterization of these catalysts is difficult because the magnetic nature of the materials interferes with the magnetic field of the spectrometer.

  18. Magnetism in lanthanide superlattices

    DEFF Research Database (Denmark)

    Goff, J.P.; Sarthour, R.S.; McMorrow, D.F.

    2000-01-01

    Neutron diffraction studies of heavy rare-earth superlattices have revealed the stabilization of novel magnetic phases chat are not present in bulk materials. The most striking result is the propagation of the magnetic ordering through nonmagnetic spacer materials. Here we describe some recent X......-ray magnetic resonant scattering studies of light rare-earth superlattices, which illuminate the mechanism of interlayer coupling, and provide access to different areas of Physics. such as the interplay between superconductivity and magnetism. Magnetic X-ray diffraction is found to be particularly well suited...... to the study of the modulated magnetic structures in superlattices, and provides unique information on the conduction-electron spin-density wave responsible for the propagation of magnetic order. (C) 2000 Elsevier Science B.V. All rights reserved....

  19. Superconducting pulsed magnets

    CERN Document Server

    CERN. Geneva

    2006-01-01

    Lecture 1. Introduction to Superconducting Materials Type 1,2 and high temperature superconductors; their critical temperature, field & current density. Persistent screening currents and the critical state model. Lecture 2. Magnetization and AC Loss How screening currents cause irreversible magnetization and hysteresis loops. Field errors caused by screening currents. Flux jumping. The general formulation of ac loss in terms of magnetization. AC losses caused by screening currents. Lecture 3. Twisted Wires and Cables Filamentary composite wires and the losses caused by coupling currents between filaments, the need for twisting. Why we need cables and how the coupling currents in cables contribute more ac loss. Field errors caused by coupling currents. Lecture 4. AC Losses in Magnets, Cooling and Measurement Summary of all loss mechanisms and calculation of total losses in the magnet. The need for cooling to minimize temperature rise in a magnet. Measuring ac losses in wires and in magnets. Lecture 5. Stab...

  20. Superconducting bulk magnets for magnetic levitation systems

    Science.gov (United States)

    Fujimoto, H.; Kamijo, H.

    2000-06-01

    The major applications of high-temperature superconductors have mostly been confined to products in the form of wires and thin films. However, recent developments show that rare-earth REBa 2Cu 3O 7- x and light rare-earth LREBa 2Cu 3O 7- x superconductors prepared by melt processes have a high critical-current density at 77 K and high magnetic fields. These superconductors will promote the application of bulk high-temperature superconductors in high magnetic fields; the superconducting bulk magnet for the Maglev train is one possible application. We investigated the possibility of using bulk magnets in the Maglev system, and examined flux-trapping characteristics of multi-superconducting bulks arranged in array.

  1. Active Magnetic Bearings – Magnetic Forces

    DEFF Research Database (Denmark)

    Kjølhede, Klaus

    2006-01-01

    Parameter identification procedures and model validation are major steps towards intelligent machines supported by active magnetic bearings (AMB). The ability of measuring the electromagnetic bearing forces, or deriving them from measuring the magnetic flux, strongly contributes to the model...... validation and leads to novel approaches in identifying crucial rotor parameters. This is the main focus of this paper, where an intelligent AMB is being developed with the aim of aiding the accurate identification of damping and stiffness coefficients of journal bearings and seals. The main contribution...... of the magnetic forces are led by using different experimental tests: (I) by using hall sensors mounted directly on the poles (precise measurements of the magnetic flux) and by an auxiliary system, composed of strain gages and flexible beams attached to the rotor; (II) by measuring the input current and bearing...

  2. Magnetization arrangement of hard magnetic phases and mechanism of magnetization and reversal magnetization of nano-composite magnets

    Institute of Scientific and Technical Information of China (English)

    LIU Xin-cai; XIE Ren; PAN Jing

    2009-01-01

    During the process of directional solidification, laser remelting/solidification in the layer on sintered magnets, die-upsetting of cast magnets, or die-upsetting of nano-composites, the arrangements of the easy-magnetization-axes of the hard magnetic phases (Nd_2Fe_(14)B, SmCo_5 or Sm_2Co_(17) type) in their designed directions have been studied. In Fe-Pt nano-composite magnets, attempts have been taken to promote phase transformation from disordered, soft magnetic A1 to ordered, hard magnetic L_(10) FePt phase at reduced temperatures. The dependence of the magnetization and reversal magnetization processes on the microstructures, involving the morphology and three critical sizes of particles of the FePt nano-composite magnets, are summarized. With the decrease of the nominal thickness of the anisotropic FePt film epitaxially grown on the single crystal MgO (001) substrate, the reversal magnetization process firstly changes from full domain wall displacement to partial magnetic wall pinning related to the morphology change, where the coercive force increases abruptly. The reversal magnetization process secondly changes from magnetic wall pinning to incoherent magnetization rotation associated with the particles being below the first critical size at which multi-domain particles turn into single domain ones, where the coercive force is still increased. And the reversal magnetization mode thirdly changes from incoherent to coherent rotation referred to the second critical size, where the increase of the coercive force keeps on. However, when the particle size decreases to approach the third critical size where the particles turn into the supperparamagnetic state, the coercive force begins to decrease due to the interplay of the size effect and the incomplete ordering induced by the size effect. Meanwhile, due to the size effect, Curie temperature of the ultra-small FePt particles reduces.

  3. Magnetic Excitations and Magnetic Ordering in Praseodymium

    DEFF Research Database (Denmark)

    Houmann, Jens Christian Gylden; Chapellier, M.; Mackintosh, A. R.;

    1975-01-01

    The dispersion relations for magnetic excitons propagating on the hexagonal sites of double-hcp Pr provide clear evidence for a pronounced anisotropy in the exchange. The energy of the excitations decreases rapidly as the temperature is lowered, but becomes almost constant below about 7 K......, in agreement with a random-phase-approximation calculation. No evidence of magnetic ordering has been observed above 0.4 K, although the exchange is close to the critical value necessary for an antiferromagnetic state....

  4. Magnetic-seeding filtration

    Energy Technology Data Exchange (ETDEWEB)

    DePaoli, D.W.; Tsouris, C. [Oak Ridge National Lab., TN (United States); Yiacoumi, Sotira

    1997-10-01

    Magnetic-seeding filtration is a technology under development for the enhanced removal of magnetic and non-magnetic particulates from liquids. This process involves the addition of a small amount of magnetic seed particles (such as naturally occurring iron oxide) to a waste suspension, followed by treatment with a magnetic filter. Non-magnetic and weakly magnetic particles are made to undergo nonhomogeneous flocculation with the seed particles, forming flocs of high magnetic susceptibility that are readily removed by a conventional high-gradient magnetic filter. This technology is applicable to a wide range of liquid wastes, including groundwater, process waters, and tank supernatants. Magnetic-seeding filtration may be used in several aspects of treatment, such as (1) removal of solids, particularly those in the colloidal size range that are difficult to remove by conventional means; (2) removal of contaminants by precipitation processes; and (3) removal of contaminants by sorption processes. Waste stream characteristics for which the technology may be applicable include (1) particle sizes ranging from relatively coarse (several microns) to colloidal particles, (2) high or low radiation levels, (3) broad-ranging flow rates, (4) low to moderate solids concentration, (5) cases requiring high decontamination factors, and (6) aqueous or non-aqueous liquids. At this point, the technology is at the bench-scale stage of development; laboratory studies and fundamental modeling are currently being employed to determine the capabilities of the process.

  5. Magnetism in Medicine

    Science.gov (United States)

    Schenck, John

    2000-03-01

    For centuries physicians, scientists and others have postulated an important role, either as a cause of disease or as a mode of therapy, for magnetism in medicine. Although there is a straightforward role in the removal of magnetic foreign bodies, the majority of the proposed magnetic applications have been controversial and have often been attributed by mainstream practitioners to fraud, quackery or self-deception. Calculations indicate that many of the proposed methods of action, e.g., the field-induced alignment of water molecules or alterations in blood flow, are of negligible magnitude. Nonetheless, even at the present time, the use of small surface magnets (magnetotherapy) to treat arthritis and similar diseases is a widespread form of folk medicine and is said to involve sales of approximately one billion dollars per year. Another medical application of magnetism associated with Mesmer and others (eventually known as animal magnetism) has been discredited, but has had a culturally significant role in the development of hypnotism and as one of the sources of modern psychotherapy. Over the last two decades, in marked contrast to previous applications of magnetism to medicine, magnetic resonance imaging or MRI, has become firmly established as a clinical diagnostic tool. MRI permits the non-invasive study of subtle biological processes in intact, living organisms and approximately 150,000,000 diagnostic studies have been performed since its clinical introduction in the early 1980s. The dramatically swift and widespread acceptance of MRI was made possible by scientific and engineering advances - including nuclear magnetic resonance, computer technology and whole-body-sized, high field superconducting magnets - in the decades following World War Two. Although presently used much less than MRI, additional applications, including nerve and muscle stimulation by pulsed magnetic fields, the use of magnetic forces to guide surgical instruments, and imaging utilizing

  6. Optimally segmented magnetic structures

    DEFF Research Database (Denmark)

    Insinga, Andrea Roberto; Bahl, Christian; Bjørk, Rasmus;

    ], or are applicable only to analytically solvable geometries[4]. In addition, some questions remained fundamentally unanswered, such as how to segment a given design into N uniformly magnetized pieces.Our method calculates the globally optimal shape and magnetization direction of each segment inside a certain......We present a semi-analytical algorithm for magnet design problems, which calculates the optimal way to subdivide a given design region into uniformly magnetized segments.The availability of powerful rare-earth magnetic materials such as Nd-Fe-B has broadened the range of applications of permanent...... designarea with an optional constraint on the total amount of magnetic material. The method can be applied to any objective functional which is linear respect to the field, and with any combination of linear materials. Being based on an analytical-optimization approach, the algorithm is not computationally...

  7. Magnetic Coordinate Systems

    CERN Document Server

    Laundal, K M

    2016-01-01

    Geospace phenomena such as the aurora, plasma motion, ionospheric currents and associated magnetic field disturbances are highly organized by Earth's main magnetic field. This is due to the fact that the charged particles that comprise space plasma can move almost freely along magnetic field lines, but not across them. For this reason it is sensible to present such phenomena relative to Earth's magnetic field. A large variety of magnetic coordinate systems exist, designed for different purposes and regions, ranging from the magnetopause to the ionosphere. In this paper we review the most common magnetic coordinate systems and describe how they are defined, where they are used, and how to convert between them. The definitions are presented based on the spherical harmonic expansion coefficients of the International Geomagnetic Reference Field (IGRF) and, in some of the coordinate systems, the position of the Sun which we show how to calculate from the time and date. The most detailed coordinate systems take the...

  8. The First Magnetic Fields

    CERN Document Server

    Widrow, Lawrence M; Schleicher, Dominik; Subramanian, Kandaswamy; Tsagas, Christos G; Treumann, Rudolf A

    2011-01-01

    We review current ideas on the origin of galactic and extragalactic magnetic fields. We begin by summarizing observations of magnetic fields at cosmological redshifts and on cosmological scales. These observations translate into constraints on the strength and scale magnetic fields must have during the early stages of galaxy formation in order to seed the galactic dynamo. We examine mechanisms for the generation of magnetic fields that operate prior during inflation and during subsequent phase transitions such as electroweak symmetry breaking and the quark-hadron phase transition. The implications of strong primordial magnetic fields for the reionization epoch as well as the first generation of stars is discussed in detail. The exotic, early-Universe mechanisms are contrasted with astrophysical processes that generate fields after recombination. For example, a Biermann-type battery can operate in a proto-galaxy during the early stages of structure formation. Moreover, magnetic fields in either an early genera...

  9. Remanent magnetism at Mars

    Science.gov (United States)

    Curtis, S. A.; Ness, N. F.

    1988-01-01

    It is shown that a strong case can be made for an intrinsic magnetic field of dynamo origin for Mars earlier in its history. The typical equatorial magnetic field intensity would have been equal to about 0.01-0.1 gauss. The earlier dynamo activity is no longer extant, but a significant remanent magnetic field may exist. A highly non-dipole magnetic field could result from the remanent magnetization of the surface. Remanent magnetization may thus play an important role in the Mars solar wind interactions, in contrast to Venus with its surface temperatures above the Curie point. The anomalous characteristics of Mars'solar wind interaction compared to that of Venus may be explicable on this basis.

  10. The 2017 Magnetism Roadmap

    Science.gov (United States)

    Sander, D.; Valenzuela, S. O.; Makarov, D.; Marrows, C. H.; Fullerton, E. E.; Fischer, P.; McCord, J.; Vavassori, P.; Mangin, S.; Pirro, P.; Hillebrands, B.; Kent, A. D.; Jungwirth, T.; Gutfleisch, O.; Kim, C. G.; Berger, A.

    2017-09-01

    Building upon the success and relevance of the 2014 Magnetism Roadmap, this 2017 Magnetism Roadmap edition follows a similar general layout, even if its focus is naturally shifted, and a different group of experts and, thus, viewpoints are being collected and presented. More importantly, key developments have changed the research landscape in very relevant ways, so that a novel view onto some of the most crucial developments is warranted, and thus, this 2017 Magnetism Roadmap article is a timely endeavour. The change in landscape is hereby not exclusively scientific, but also reflects the magnetism related industrial application portfolio. Specifically, Hard Disk Drive technology, which still dominates digital storage and will continue to do so for many years, if not decades, has now limited its footprint in the scientific and research community, whereas significantly growing interest in magnetism and magnetic materials in relation to energy applications is noticeable, and other technological fields are emerging as well. Also, more and more work is occurring in which complex topologies of magnetically ordered states are being explored, hereby aiming at a technological utilization of the very theoretical concepts that were recognised by the 2016 Nobel Prize in Physics. Given this somewhat shifted scenario, it seemed appropriate to select topics for this Roadmap article that represent the three core pillars of magnetism, namely magnetic materials, magnetic phenomena and associated characterization techniques, as well as applications of magnetism. While many of the contributions in this Roadmap have clearly overlapping relevance in all three fields, their relative focus is mostly associated to one of the three pillars. In this way, the interconnecting roles of having suitable magnetic materials, understanding (and being able to characterize) the underlying physics of their behaviour and utilizing them for applications and devices is well illustrated, thus giving an

  11. Molecules in Magnetic Fields

    Science.gov (United States)

    Berdyugina, Svetlana

    2015-08-01

    Molecules probe cool matter in the Universe and various astrophysical objects. Their ability to sense magnetic fields provides new insights into magnetic properties of these objects. During the past fifteen years we have carried out a theoretical study of molecular magnetic effects such as the Zeeman, Paschen-Back and Hanle effects and their applications for inferring magnetic structures and spatial inhomogeneities on the Sun, cool stars, brown dwarfs, and exoplanets from molecular spectro-polarimetry (e.g., Berdyugina 2011). Here, we present an overview of this study and compare our theoretical predictions with recent laboratory measurements of magnetic properties of some molecules. We present also a new web-based tool to compute molecular magnetic effects and polarized spectra which is supported by the ERC Advanced Grant HotMol.

  12. Magnetic nanocap arrays with tilted magnetization

    Science.gov (United States)

    Albrecht, Manfred

    2009-03-01

    In modern magnetic recording materials the ``superparamagnetic effect'' has become increasingly important as new magnetic hard disk drive products are designed for higher storage densities. In this regard, patterned media [1], where two-dimensional arrays of nanostructures are used, is one of the concepts that might provide the required areal density in future magnetic recording devices. However, also nanostructure arrays will ultimately need high anisotropy material such as L10-FePt to provid enough thermal stability and thus much higher writing fields than currently obtainable from perpendicular magnetic recording heads. One proposed solution to this problem is the use of tilted magnetic recording media [2]. The basic idea is to tilt the easy axis of the magnetic medium from the perpendicular direction to 45 degree. In this case, the switching field will be reduced by a foctor of two in the Stoner-Wohlfarth limit. Recently, this approach was realized by oblique film deposition onto arrays of self-assembled spherical particles [3-5]. In this presentation, recent results on different film systems including Co/Pt multilayers, FePt and CoPtCr-SiO2 alloys which have been deposited onto SiO2 particle monolayers will be presented. It turned out that by tuning the growth conditions single domain nanocaps with enhanced magnetic coercivity and tilted anisostropy axis can be achieved even for particle sizes below 50 nm. [4pt] [1] B. D. Terris and T. Thomson, J. Phys. D: Appl. Phys. 38 (2005) R199 [0pt] [2] J.-P. Wang, Nat. Mater. 4, 191 (2005). [0pt] [3] M. Albrecht et al., Nat. Mater. 4, 203 (2005). [0pt] [4] T. Ulbrich et al., Phys. Rev. Lett. 96 (2006) 077202. [0pt] [5] D. Makarov et al., Appl. Phys. Lett. 93, 153112 (2008).

  13. Magnetic latching solenoid

    Science.gov (United States)

    Marts, D.J.; Richardson, J.G.; Albano, R.K.; Morrison, J.L. Jr.

    1995-11-28

    This invention discloses a D.C. magnetic latching solenoid that retains a moving armature in a first or second position by means of a pair of magnets, thereby having a zero-power requirement after actuation. The first or second position is selected by reversing the polarity of the D.C. voltage which is enough to overcome the holding power of either magnet and transfer the armature to an opposite position. The coil is then de-energized. 2 figs.

  14. Magnetic latching solenoid

    Energy Technology Data Exchange (ETDEWEB)

    Marts, Donna J. (Idaho Falls, ID); Richardson, John G. (Idaho Falls, ID); Albano, Richard K. (Idaho Falls, ID); Morrison, Jr., John L. (Idaho Falls, ID)

    1995-01-01

    This invention discloses a D.C. magnetic latching solenoid that retains a moving armature in a first or second position by means of a pair of magnets, thereby having a zero-power requirement after actuation. The first or second position is selected by reversing the polarity of the D.C. voltage which is enough to overcome the holding power of either magnet and transfer the armature to an opposite position. The coil is then de-energized.

  15. GHz magnetic film inductors

    CERN Document Server

    Korenivski, V

    2000-01-01

    Use of magnetic films for miniaturization of planar inductors operating at ultra-high frequencies is reviewed. Materials and design aspects determining the efficiency of the devices are analyzed. Mechanisms involved in magnetic dissipation and their role in limiting the device operation frequency range and quality factor are discussed. Typical inductor geometries are considered. A magnetically sandwiched strip inductor is argued to hold a promise for GHz applications.

  16. Organic magnetic field sensor

    Energy Technology Data Exchange (ETDEWEB)

    McCamey, Dane; Boehme, Christoph

    2017-01-24

    An organic, spin-dependent magnetic field sensor (10) includes an active stack (12) having an organic material with a spin-dependence. The sensor (10) also includes a back electrical contact (14) electrically coupled to a back of the active stack (12) and a front electrical contact (16) electrically coupled to a front of the active stack (12). A magnetic field generator (18) is oriented so as to provide an oscillating magnetic field which penetrates the active stack (12).

  17. Theoretical magnetic flux emergence

    OpenAIRE

    MacTaggart, David

    2011-01-01

    Magnetic flux emergence is the subject of how magnetic fields from the solar interior can rise and expand into the atmosphere to produce active regions. It is the link that joins dynamics in the convection zone with dynamics in the atmosphere. In this thesis, we study many aspects of magnetic flux emergence through mathematical modelling and computer simulations. Our primary aim is to understand the key physical processes that lie behind emergence. The first chapter intro...

  18. Magnetic record support

    Science.gov (United States)

    Nakayama, M.; Morita, H.; Tokuoka, Y.; Izumi, T.; Fukuda, K.; Kubota, Y.

    1984-01-01

    The magnetic layer of a magnetic record support is coated with a thin film of a polymer with a siloxane bond. The magnetic layer consists of a thin film obtained by vacuum metallization, cathode sputtering or dispersion of a ferromagnetic metal powder in a binder. The polymer with a siloxane bond is produced by the polymerization of an organic silicon compound which inherently contains or is able to form this bond. Polymerization is preferably performed by plasma polymerization.

  19. Magnetic Electrochemical Finishing Machining

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    How to improve the finishing efficiency and surface roughness have been all along the objective of research in electrochemical polishing. However, the research activity, i.e. during electrochemical polishing, directly introduce the magnetic field to study how the magnetic field influences on the finishing efficiency, quality and the electrochemical process in the field of finishing machining technology, is insufficient. When introducing additional magnetic field in the traditional electrochemical pol...

  20. Magnetic Spring Device

    OpenAIRE

    Hassam, A. B.; Rodgers, J. C.

    2009-01-01

    A cylindrical system is proposed that will store magnetic energy in a localized azimuthal field that can then be quickly released on Alfvenic timescales, accompanied by the formation of a flowing Z-pinch plasma. The magnetized plasma is MHD in character and will have unilateral axial momentum with Alfvenic speeds. Conventional plasma gun injectors (Marshall type) have a limited parameter space of operation. The "magnetic spring" momentum injector differs from Marshall guns in that it has an a...

  1. SPS : the magnet system

    CERN Multimedia

    CERN Neyrac Films

    1974-01-01

    English version. Part of a series of films about the SPS. This one ois from May 1974 to December 1974. Roy Billinge, Vince Hatton explain about magnet system. Technical requirements, accuracy checks, installation, magnetic measurements, mechanical measurements. Discussion of a particular problem which can come from variation in the thickness of the vacuum chambers. Dipoles, quadrapoles and other speciality magnets. Necessity for close international cooperation to coordinate the work. Nice meeting sequence at end. (calculator on the table.)

  2. Magnets in prosthetic dentistry.

    Science.gov (United States)

    Riley, M A; Walmsley, A D; Harris, I R

    2001-08-01

    Magnetic retention is a popular method of attaching removable prostheses to either retained roots or osseointegrated implants. This review chronicles the development of magnets in dentistry and summarizes future research in their use. The literature was researched by using the Science Citation Index and Compendex Web from 1981 to 2000. Articles published before 1981 were hand researched from citations in other publications. Articles that discussed the use of magnets in relation to prosthetic dentistry were selected.

  3. LHCb experiment magnets

    CERN Multimedia

    Maximilien Brice

    2004-01-01

    The leading members of the LHCb magnet project, from left to right: Pierre-Ange Giudici, who organized and supervised the industrial production of the coils; Marcello Losasso, who performed the 3D calculations to optimise the magnetic field; Olivier Jamet, responsible for the 3D design; Jean Renaud, in charge of the magnet assembly, and Wilfried Flegel, project leader. The LHCb detector will investigate matter-antimatter differences in B mesons at the LHC. The coils of the detector's huge dipole magnet are seen here in April 2004.

  4. Biomaterials and magnetism

    Indian Academy of Sciences (India)

    D Bahadur; Jyotsnendu Giri

    2003-06-01

    Magnetism plays an important role in different applications of health care. Magnetite (Fe34) is biocompatible and therefore is one of the most extensively used biomaterials for different applications ranging from cell separation and drug delivery to hyperthermia. Other than this, a large number of magnetic materials in bulk as well as in the form of nano particles have been exploited for a variety of medical applications. In this review, we summarize the salient features of clinical applications, where magnetic biomaterials are used. Magnetic intracellular hyperthermia for cancer therapy is discussed in detail.

  5. Covariant Magnetic Connection Hypersurfaces

    CERN Document Server

    Pegoraro, F

    2016-01-01

    In the single fluid, nonrelativistic, ideal-Magnetohydrodynamic (MHD) plasma description magnetic field lines play a fundamental role by defining dynamically preserved "magnetic connections" between plasma elements. Here we show how the concept of magnetic connection needs to be generalized in the case of a relativistic MHD description where we require covariance under arbitrary Lorentz transformations. This is performed by defining 2-D {\\it magnetic connection hypersurfaces} in the 4-D Minkowski space. This generalization accounts for the loss of simultaneity between spatially separated events in different frames and is expected to provide a powerful insight into the 4-D geometry of electromagnetic fields when ${\\bf E} \\cdot {\\bf B} = 0$.

  6. Magnetic Nernst effect

    Science.gov (United States)

    Brechet, Sylvain D.; Ansermet, Jean-Philippe

    2015-09-01

    The thermodynamics of irreversible processes in continuous media predicts the existence of a magnetic Nernst effect that results from a magnetic analog to the Seebeck effect in a ferromagnet and magnetophoresis occurring in a paramagnetic electrode in contact with the ferromagnet. Thus, a voltage that has DC and AC components is expected across a Pt electrode as a response to the inhomogeneous magnetic induction field generated by magnetostatic waves of an adjacent YIG slab subject to a temperature gradient. The voltage frequency and dependence on the orientation of the applied magnetic induction field are quite distinct from that of spin pumping.

  7. Oscillating Permanent Magnets.

    Science.gov (United States)

    Michaelis, M. M.; Haines, C. M.

    1989-01-01

    Describes several ways to partially levitate permanent magnets. Computes field line geometries and oscillation frequencies. Provides several diagrams illustrating the mechanism of the oscillation. (YP)

  8. Magnetic flocculation and filtration

    Energy Technology Data Exchange (ETDEWEB)

    Yiacoumi, Sotira; Chin, Ching-Ju; Yin, Tung-Yu [Georgia Inst. of Tech., Atlanta, GA (United States). School of Civil and Environmental Engineering; Tsouris, C., DePaoli, D.W.; Chattin, M.R.; Spurrier, M. [Oak Ridge National Lab., TN (United States)

    1996-10-01

    A model is available in predicting flocculation frequencies between particles of various properties under the influence of a magnetic field. This model provides a basic understanding of fundamental phenomena, such as particle-particle and particle-collector interactions, occurring in HGMF (high gradient magnetic field), and will be extended to describe experimental data of particle flocculation and filtration and predict the performance of high- gradient magnetic filters. It is also expected that this model will eventually lead to a tool for design and optimization of magnetic filters for environmental, metallurgical, biochemical, and other applications.

  9. Superconducting magnets for MRI

    Energy Technology Data Exchange (ETDEWEB)

    Williams, J.E.

    1984-08-01

    Three types of magnets are currently used to provide the background field required for magnet resonance imaging (MRI). (i) Permanent magnets produce fields of up to 0.3 T in volumes sufficient for imaging the head or up to 0.15 T for whole body imaging. Cost and simplicity of operation are advantages, but relatively low field, weight (up to 100 tonnes) and, to a small extent, instability are limitations. (ii) Water-cooled magnets provide fields of up to 0.25 T in volumes suitable for whole body imaging, but at the expense of power (up to 150 kW for 0.25 T) and water-cooling. Thermal stability of the field requires the maintenance of constant temperature through periods both of use and of quiescence. (iii) Because of the limitations imposed by permanent and resistive magnets, particularly on field strength, the superconducting magnet is now most widely used to provide background fields of up to 2 T for whole body MRI. It requires very low operating power and that only for refrigeration. Because of the constant low temperature, 4.2 K, at which its stressed structure operates, its field is stable. The following review deals principally with superconducting magnets for MRI. However, the sections on field analysis apply to all types of magnet and the description of the source terms of circular coils and of the principals of design of solenoids apply equally to resistive solenoidal magnets.

  10. Engineering magnetism in semiconductors

    Directory of Open Access Journals (Sweden)

    Tomasz Dietl

    2006-11-01

    Full Text Available Transition metal doped III-V, II-VI, and group IV compounds offer an unprecedented opportunity to explore ferromagnetism in semiconductors. Because ferromagnetic spin-spin interactions are mediated by holes in the valence band, changing the Fermi level using co-doping, electric fields, or light can directly manipulate the magnetic ordering. Moreover, engineering the Fermi level position by co-doping makes it possible to modify solubility and self-compensation limits, affecting magnetic characteristics in a number of surprising ways. The Fermi energy can even control the aggregation of magnetic ions, providing a new route to self-organization of magnetic nanostructures in a semiconductor host.

  11. Magnetic S-parameter

    DEFF Research Database (Denmark)

    Sannino, Francesco

    2010-01-01

    We propose a direct test of the existence of gauge duals for nonsupersymmetric asymptotically free gauge theories developing an infrared fixed point by computing the S-parameter in the electric and dual magnetic description. In particular we show that at the lower bound of the conformal window...... the magnetic S-parameter, i.e. the one determined via the dual magnetic gauge theory, assumes a simple expression in terms of the elementary magnetic degrees of freedom. The results further support our recent conjecture of the existence of a universal lower bound on the S parameter and indicates...

  12. Electromechanical magnetization switching

    Energy Technology Data Exchange (ETDEWEB)

    Chudnovsky, Eugene M. [Department of Physics and Astronomy, Lehman College and Graduate School, The City University of New York, 250 Bedford Park Boulevard West, Bronx, New York 10468-1589 (United States); Jaafar, Reem [Department of Mathematics, Engineering and Computer Science, LaGuardia Community College, The City University of New York, 31-10 Thomson Avenue, Long Island City, New York 11101 (United States)

    2015-03-14

    We show that the magnetization of a torsional oscillator that, in addition to the magnetic moment also possesses an electrical polarization, can be switched by the electric field that ignites mechanical oscillations at the frequency comparable to the frequency of the ferromagnetic resonance. The 180° switching arises from the spin-rotation coupling and is not prohibited by the different symmetry of the magnetic moment and the electric field as in the case of a stationary magnet. Analytical equations describing the system have been derived and investigated numerically. Phase diagrams showing the range of parameters required for the switching have been obtained.

  13. Magnetic chemically peculiar stars

    CERN Document Server

    Schöller, Markus

    2015-01-01

    Chemically peculiar (CP) stars are main-sequence A and B stars with abnormally strong or weak lines for certain elements. They generally have magnetic fields and all observables tend to vary with the same period. Chemically peculiar stars provide a wealth of information; they are natural atomic and magnetic laboratories. After a brief historical overview, we discuss the general properties of the magnetic fields in CP stars, describe the oblique rotator model, explain the dependence of the magnetic field strength on the rotation, and concentrate at the end on HgMn stars.

  14. Magnetism v.5

    CERN Document Server

    Suhl, Harry

    1973-01-01

    Magnetism, Volume V: Magnetic Properties of Metallic Alloys deals with the magnetic properties of metallic alloys and covers topics ranging from conditions favoring the localization of effective moments to the s-d model and the Kondo effect, along with perturbative, scattering, and Green's function theories of the s-d model. Asymptotically exact methods used in addressing the Kondo problem are also described.Comprised of 12 chapters, this volume begins with a review of experimental results and phenomenology concerning the formation of local magnetic moments in metals, followed by a Har

  15. Radial Halbach Magnetic Bearings

    Science.gov (United States)

    Eichenberg, Dennis J.; Gallo, Christopher A.; Thompson, William K.

    2009-01-01

    Radial Halbach magnetic bearings have been investigated as part of an effort to develop increasingly reliable noncontact bearings for future high-speed rotary machines that may be used in such applications as aircraft, industrial, and land-vehicle power systems and in some medical and scientific instrumentation systems. Radial Halbach magnetic bearings are based on the same principle as that of axial Halbach magnetic bearings, differing in geometry as the names of these two types of bearings suggest. Both radial and axial Halbach magnetic bearings are passive in the sense that unlike most other magnetic bearings that have been developed in recent years, they effect stable magnetic levitation without need for complex active control. Axial Halbach magnetic bearings were described in Axial Halbach Magnetic Bearings (LEW-18066-1), NASA Tech Briefs, Vol. 32, No. 7 (July 2008), page 85. In the remainder of this article, the description of the principle of operation from the cited prior article is recapitulated and updated to incorporate the present radial geometry. In simplest terms, the basic principle of levitation in an axial or radial Halbach magnetic bearing is that of the repulsive electromagnetic force between (1) a moving permanent magnet and (2) an electric current induced in a stationary electrical conductor by the motion of the magnetic field. An axial or radial Halbach bearing includes multiple permanent magnets arranged in a Halbach array ("Halbach array" is defined below) in a rotor and multiple conductors in the form of wire coils in a stator, all arranged so the rotary motion produces an axial or radial repulsion that is sufficient to levitate the rotor. A basic Halbach array (see Figure 1) consists of a row of permanent magnets, each oriented so that its magnetic field is at a right angle to that of the adjacent magnet, and the right-angle turns are sequenced so as to maximize the magnitude of the magnetic flux density on one side of the row while

  16. Magnetic and optical properties of Ag@SiO{sub 2}-FITC-Fe{sub 3}O{sub 4} hybrid nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Sui, Ning [Université de Lyon, Institut des Nanotechnologies de Lyon–INL, UMR CNRS 5270, Site Ecole Centrale de Lyon, 36 Avenue Guy de Collongue, F-69134 Ecully Cedex (France); College of Material Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042 (China); Monnier, Virginie, E-mail: virginie.monnier@ec-lyon.fr [Université de Lyon, Institut des Nanotechnologies de Lyon–INL, UMR CNRS 5270, Site Ecole Centrale de Lyon, 36 Avenue Guy de Collongue, F-69134 Ecully Cedex (France); Salvia, Marie-Virginie; Chevolot, Yann; Souteyrand, Eliane [Université de Lyon, Institut des Nanotechnologies de Lyon–INL, UMR CNRS 5270, Site Ecole Centrale de Lyon, 36 Avenue Guy de Collongue, F-69134 Ecully Cedex (France)

    2014-03-15

    Highlights: • New magnetic/fluorescent nanoparticles were synthesized. • The silver core led to a maximum 4-fold enhanced fluorescence of fluorophore. • Maximum enhancement factor was obtained when metal-fluorophore distance is 5 nm. • Magnetism and fluorescence appeared simultaneously for nanoparticles in solution. -- Abstract: Nanoparticles composed of a silver core coated with a silica shell (Ag@SiO{sub 2}) were prepared. A dye, fluorescein isothiocyanate (FITC), was further encapsulated during the growth of a second silica shell onto Ag@SiO{sub 2} nanoparticles. The proximity of silver nanoparticles led to a 4-fold maximal enhancement in the fluorescence of FITC when the first silica shell thickness was set at 5 nm. After amino-functionalization of Ag@SiO{sub 2}-FITC nanoparticles, iron oxide nanoparticles were bonded to their surface. The magnetic and metal-enhanced fluorescence properties appeared simultaneously when Ag@SiO{sub 2}-FITC-Fe{sub 3}O{sub 4} hybrid nanoparticles were dispersed in a solution.

  17. Enzymatic interesterification of soybean oil and methyl stearate blends using lipase immobilized on magnetic Fe3O4/SBA-15 composites as a biocatalyst.

    Science.gov (United States)

    Zang, Xuezhen; Xie, Wenlei

    2014-01-01

    The magnetic Fe3O4/SBA-15 composites were prepared, and treated with 3-aminopropyltriethoxysilane as a carrier material for enzyme immobilization. The immobilization of Candida rugosa lipase onto the amino-functionalized Fe3O4/SBA-15 composite was investigated by using glutaraldehyde as a coupling reagent. The immobilized lipase was then employed as a biocatalyst for the interesterification of soybean oil and methyl stearate in a laboratory-scale operation at 45°C. Various techniques, such as Fourier transform infrared spectroscopy (FT-IR), powder X-ray diffraction (XRD), and vibrating sample magnetometry (VSM), were used for the characterization of the immobilized lipase composite. The immobilized lipase behaved superparamagnetic and showed excellent response at applied magnetic field. The obtained results showed that the immobilized lipase could efficiently catalyze the interesterification reaction. Moreover, the interesterification reaction parameters, such as reaction temperature, substrate ratio and reaction time were investigated regarding the stearoyl incorporation into the triacylglycerols. Further, the immobilized lipase proved to be easily separated from the reaction mixture by applying an external magnetic field and to be stable in the repeated use for four cycles.

  18. Recyclable magnetic nanocluster crosslinked with poly(ethylene oxide)-block-poly(2-vinyl-4,4-dimethylazlactone) copolymer for adsorption with antibody.

    Science.gov (United States)

    Prai-In, Yingrak; Boonthip, Chatchai; Rutnakornpituk, Boonjira; Wichai, Uthai; Montembault, Véronique; Pascual, Sagrario; Fontaine, Laurent; Rutnakornpituk, Metha

    2016-10-01

    Surface modification of magnetic nanoparticle (MNP) with poly(ethylene oxide)-block-poly(2-vinyl-4,4-dimethylazlactone) (PEO-b-PVDM) diblock copolymers and its application as recyclable magnetic nano-support for adsorption with antibody were reported herein. PEO-b-PVDM copolymers were first synthesized via a reversible addition-fragmentation chain-transfer (RAFT) polymerization using poly(ethylene oxide) chain-transfer agent as a macromolecular chain transfer agent to mediate the RAFT polymerization of VDM. They were then grafted on amino-functionalized MNP by coupling with some azlactone rings of the PVDM block to form magnetic nanoclusters with tunable cluster size. The nanocluster size could be tuned by adjusting the chain length of the PVDM block. The nanoclusters were successfully used as efficient and recyclable nano-supports for adsorption with anti-rabbit IgG antibody. They retained higher than 95% adsorption of the antibody during eight adsorption-separation-desorption cycles, indicating the potential feasibility in using this novel hybrid nanocluster as recyclable support in cell separation applications.

  19. Ultrafast magnetization dynamics in diluted magnetic semiconductors

    Energy Technology Data Exchange (ETDEWEB)

    Morandi, O [INRIA Nancy Grand-Est and Institut de Recherche en Mathematiques Avancees, 7 rue Rene Descartes, F-67084 Strasbourg (France); Hervieux, P-A; Manfredi, G [Institut de Physique et Chimie des Materiaux de Strasbourg, 23 rue du Loess, F-67037 Strasbourg (France)], E-mail: morandi@dipmat.univpm.it

    2009-07-15

    We present a dynamical model that successfully explains the observed time evolution of the magnetization in diluted magnetic semiconductor quantum wells after weak laser excitation. Based on the pseudo-fermion formalism and a second-order many-particle expansion of the exact p-d exchange interaction, our approach goes beyond the usual mean-field approximation. It includes both the sub-picosecond demagnetization dynamics and the slower relaxation processes that restore the initial ferromagnetic order in a nanosecond timescale. In agreement with experimental results, our numerical simulations show that, depending on the value of the initial lattice temperature, a subsequent enhancement of the total magnetization may be observed within the timescale of a few hundred picoseconds.

  20. Electro-Magnetic Quadrupole Magnets in the LCLS FEL Undulator

    Energy Technology Data Exchange (ETDEWEB)

    Emma, P.

    2005-01-31

    We discuss various aspects of electro-magnetic quadrupole (EMQ) magnets for the LCLS FEL undulator, including their utility in beam-based alignment (BBA), magnet design issues, and impact on tunnel environment, reliability, and cost.

  1. Magnetic Properties and Intergranular Action in Bonded Hybrid Magnets

    Institute of Scientific and Technical Information of China (English)

    Hua Zhenghe; Li Shandong; Han Zhida; Wang Dunhui; Zhong Wei; Gu Benxi; Lu Mu; Zhang Jianrong; Du Youwei

    2007-01-01

    Magnetic properties and intergranular action in bonded hybrid magnets, based on NdFeB and strontium ferrite powders were investigated. The long-range magnetostatic interaction and short-range exchange coupling interaction existed simultaneously in bonded hybrid magnets, and neither of them could be neglected. Some magnetic property parameters of hybrid magnets could be approximately obtained by adding the hysteresis loops of two magnets pro rata.

  2. Magnetic absorption dichroism and sum rules in itinerant magnets

    OpenAIRE

    Strange, Paul

    1994-01-01

    In this letter we discuss X-ray magnetic dichroism in magnetic materials where an itinerant model of the magnetic behaviour is appropriate. Inspired by progress made in interpreting dichroism spectra in a localized approach, we show that dichroism spectra are an excellent measure of the orbital and spin magnetic moments in itinerant magnets. By performing an energy decomposition of the sum rules we show that the structure found in dichroism spectra reflects the energy dependence of the magnet...

  3. PS auxiliary magnet

    CERN Multimedia

    CERN PhotoLab

    1974-01-01

    Units of the PS auxiliary magnet system. The picture shows how the new dipoles, used for vertical and horizontal high-energy beam manipulation, are split for installation and removal so that it is not necessary to break the accelerator vacuum. On the right, adjacent to the sector valve and the windings of the main magnet, is an octupole of the set.

  4. Magnetic support system

    NARCIS (Netherlands)

    Nijsse, G.J.P.; Spronck, J.W.

    1999-01-01

    There is described a support system enabling supporting an object such as a platform (1) free from vibration, in that bearing elements (50) have a stiffness (k) which at a working point (z0) equals zero. A bearing element (50) comprises two magnetic couplings (51, 52) provided by permanent magnets

  5. Magnetic Particle Technology

    Science.gov (United States)

    Oliveira, Luiz C.A.; A. Rios, Rachel V.R.; Fabris, Jose D.; Lago, Rachel M.; Sapag, Karim

    2004-01-01

    An exciting laboratory environment is activated by the preparation and novel use of magnetic materials to decontaminate water through adsorption and magnetic removal of metals and organics. This uncomplicated technique is also adaptable to the possible application of adsorbents to numerous other environmental substances.

  6. Solid state magnetism

    CERN Document Server

    Crangle, John

    1991-01-01

    Solid state magnetism is important and attempts to understand magnetic properties have led to an increasingly deep insight into the fundamental make up of solids. Both experimental and theoretical research into magnetism continue to be very active, yet there is still much ground to cover before there can be a full understanding. There is a strong interplay between the developments of materials science and of magnetism. Hundreds of new materials have been dis­ covered, often with previously unobserved and puzzling magnetic prop­ erties. A large and growing technology exists that is based on the magnetic properties of materials. Very many devices used in everyday life involve magnetism and new applications are being invented all the time. Under­ standing the fundamental background to the applications is vital to using and developing them. The aim of this book is to provide a simple, up-to-date introduction to the study of solid state magnetism, both intrinsic and technical. It is designed to meet the needs a...

  7. Magnetically controlled permeability membranes

    KAUST Repository

    Kosel, Jurgen

    2013-10-31

    A bioactive material delivery system can include a thermoresponsive polymer membrane and nanowires distributed within the thermoresponsive polymer membrane. Magnetic activation of a thermoresponsive polymer membrane can take place via altering the magnetization or dimensions of nanowires dispersed or ordered within the membrane matrix.

  8. Selected topics in magnetism

    CERN Document Server

    Gupta, L C

    1993-01-01

    Part of the ""Frontiers in Solid State Sciences"" series, this volume presents essays on such topics as spin fluctuations in Heisenberg magnets, quenching of spin fluctuations by high magnetic fields, and kondo effect and heavy fermions in rare earths amongst others.

  9. Wobbly Corner: Magnetism

    Science.gov (United States)

    Corbett, Lisa; Maklad, Rania; Dunne, Mick; Grace, Pierre

    2014-01-01

    During a final seminar with BA year 4 science specialist trainee teachers, the authors posed a question about the difficulties associated with understanding magnetism. The ensuing discussion focused on a number of concerns commonly identified by students, which may also be of interest to classroom teachers teaching magnetism. Issues raised…

  10. Magnetization of ancient ceramics

    NARCIS (Netherlands)

    Van Klinken, J

    2001-01-01

    The saturation magnetization sigma of soft baked pottery appears to be determined during the firing process by transitions between the iron oxides magnetite, maghemite, hematite and perhaps goethite. The finding of large variations in a motivated the design and construction of a 'magnetization-gravi

  11. Magnetic support system

    NARCIS (Netherlands)

    Nijsse, G.J.P.; Spronck, J.W.

    1999-01-01

    There is described a support system enabling supporting an object such as a platform (1) free from vibration, in that bearing elements (50) have a stiffness (k) which at a working point (z0) equals zero. A bearing element (50) comprises two magnetic couplings (51, 52) provided by permanent magnets (

  12. Neutrino Magnetic Moment

    OpenAIRE

    Balantekin, A. B.

    2006-01-01

    Current experimental and observational limits on the neutrino magnetic moment are reviewed. Implications of the recent results from the solar and reactor neutrino experiments for the value of the neutrino magnetic moment are discussed. It is shown that spin-flavor precession in the Sun is suppressed.

  13. AGS Booster prototype magnets

    Energy Technology Data Exchange (ETDEWEB)

    Danby, G.; Jackson, J.; Lee, Y.Y.; Phillips, R.; Brodowski, J.; Jablonski, E.; Keohane, G.; McDowell, B.; Rodger, E.

    1987-03-19

    Prototype magnets have been designed and constructed for two half cells of the AGS Booster. The lattice requires 2.4m long dipoles, each curved by 10/sup 0/. The multi-use Booster injector requires several very different standard magnet cycles, capable of instantaneous interchange using computer control from dc up to 10 Hz.

  14. Magnetic Implants Aid Hearing

    Institute of Scientific and Technical Information of China (English)

    陈宏

    1995-01-01

    The next generation of hearing aids may use tiny magnets that fit inside the ear. Researchersat a California company and an engineer at the University of Virginia are both developing systems that rely on magnets to convey sounds. Conventional hearing aids have three components:a microphone, an amplifier, and a speaker. The microphone picks up sounds and sends them to the am-

  15. Magnetism in massive stars

    NARCIS (Netherlands)

    Henrichs, H.F.

    2012-01-01

    Stars with mass more than 8 solar masses end their lives as neutron stars, which we mostly observe as highly magnetized objects. Where does this magnetic field come from? Such a field could be formed during the collapse, or is a (modified) remnant of a fossil field since the birth of the star, or ot

  16. Checking BEBC superconducting magnet

    CERN Multimedia

    1974-01-01

    The superconducting coils of the magnet for the 3.7 m Big European Bubble Chamber (BEBC) had to be checked, see Annual Report 1974, p. 60. The photo shows a dismantled pancake. By December 1974 the magnet reached again the field design value of 3.5 T.

  17. Magnetic-seeding filtration

    Energy Technology Data Exchange (ETDEWEB)

    Ying, T.Y.; Chin, C.J.; Lu, S.C.; Yiacoumi, S. [Georgia Institute of Technology, Atlanta, GA (United States). School of Civil and Environmental Engineering] [and others

    1997-10-01

    Magnetic-seeding filtration consists of two steps: heterogeneous particle flocculation of magnetic and nonmagnetic particles in a stirred tank and high-gradient magnetic filtration (HGMF). The effects of various parameters affecting magnetic-seeding filtration (HGMF). The effects of various parameters affecting magnetic seeding filtration are theoretically and experimentally investigated. A trajectory model that includes hydrodynamic resistance, van der Waals, and electrostatic forces is developed to calculate the flocculation frequency in a turbulent-shear regime. Fractal dimension is introduced to simulate the open structure of aggregates. A magnetic-filtration model that consists of trajectory analysis, a particle build-up model, a breakthrough model, and a bivariate population-balance model is developed to predict the breakthrough curve of magnetic-seeding filtration. A good agreement between modeling results and experimental data is obtained. The results show that the model developed in this study can be used to predict the performance of magnetic-seeding filtration without using empirical coefficients or fitting parameters. 35 refs., 7 figs., 1 tab.

  18. Stellar magnetic cycles

    Science.gov (United States)

    Baliunas, S. L.

    2004-05-01

    Is hope for understanding the solar magnetic cycle to be found in stars? Observations of stars with significant sub-surface convective zones -- masses smaller than about 1.5 solar masses on the lower main sequence and many types of cool, post-main-sequence stars -- indicate the presence of surface and atmospheric inhomogeneities analogous to solar magnetic features, making stellar magnetic activity a cosmically widespread phenomenon. Observations have been made primarily in visible wavelengths, and important information has also been derived from the ultraviolet and x-ray spectrum regions. Interannual to interdecadal variability of spectrum indicators of stellar magnetic features is common, and in some cases similar in appearance to the 11-year sunspot cycle. Successful models of the physical processes responsible for stellar magnetic cycles, typically cast as a magnetohydrodynamic dynamo, require advances in understanding not only convection but also the magnetic field's interaction with it. The observed facts that underpin the hope for models will be summarized. Properties of stellar magnetic cycles will be compared and contrasted with those of the sun, including inferences from paleo-environmental reservoirs that contain information on solar century- to millennial-scale magnetic variability. Partial support of this research came from NASA NAG5-7635, NRC COBASE, CRDF 322, MIT-MSG 5710001241, JPL 1236821, AF 49620-02-1-0194, Richard Lounsberry Foundation, Langley-Abbot, Rollins, Scholarly Studies and James Arthur Funds (Smithsonian Institution) and several generous individuals.

  19. Streched Magnetic Moments

    CERN Document Server

    Zamick, Larry

    2012-01-01

    We note that for a system of 2 nucleons in a stretched case (J=J1+J2) the magnetic moment of the combined system is the sum of the magnetic moments of the 2 constituents. In general there is no additive rule for g factors.

  20. TMX magnets: mechanical design

    Energy Technology Data Exchange (ETDEWEB)

    Hinkle, R.E.; Harvey, A.R.; Calderon, M.O.; Chargin, A.K.; Chen, F.F.K.; Denhoy, B.S.; Horvath, J.A.; Reed, J.R.; Waugh, A.F.

    1977-09-27

    The Tandem Mirror Experiment (TMX) system, part of the Lawrence Livermore Laboratory magnetic mirror program incorporates in its design various types of coils or magnets. This paper describes the physical construction of each coil within the system as well as the structural design required for their support and installation.

  1. The LHCb magnet

    CERN Multimedia

    Maximilien Brice

    2004-01-01

    The LHCb magnet consists of two huge 27 tonne coils mounted inside a 1450 tonne iron yoke. As charged particles pass through the magnet's field their trajectories will be bent according to their momentum, allowing their momentum to be measured as they pass through the detector walls. LHCb will study bottom quarks, which will be produced close to the two colliding proton beams.

  2. Magnetic Structure of Erbium

    DEFF Research Database (Denmark)

    Gibbs, D.; Bohr, Jakob; Axe, J. D.

    1986-01-01

    , and at positions split symmetrically about the fundamental. As the temperature is lowered below 52 K the charge and magnetic scattering display a sequence of lock-in transitions to rational wave vectors. A spin-slip description of the magnetic structure is presented which explains the wave vectors...

  3. Magnetic bipolar transistor

    OpenAIRE

    Fabian, Jaroslav; Zutic, Igor; Sarma, S. Das

    2003-01-01

    A magnetic bipolar transistor is a bipolar junction transistor with one or more magnetic regions, and/or with an externally injected nonequilibrium (source) spin. It is shown that electrical spin injection through the transistor is possible in the forward active regime. It is predicted that the current amplification of the transistor can be tuned by spin.

  4. Teaching Tips: Mind Magnets

    Science.gov (United States)

    Fortenberry, Callie L.; Fowler, Teri W.

    2006-01-01

    Mind magnets are maps to guide instruction and facilitate the comprehension processes. They extend individual comprehension strategy instruction, which does not typically show students how to link application of appropriate strategies to whole texts. The mind magnet framework allows teachers to plan powerful interactions between the reader and the…

  5. Strong Little Magnets

    Science.gov (United States)

    Moloney, Michael J.

    2007-01-01

    Did you know that some strong little cylindrical magnets available in local hardware stores can have an effective circumferential current of 2500 A? This intriguing information can be obtained by hanging a pair of magnets at the center of a coil, as shown in Fig. 1, and measuring the oscillation frequency as a function of coil current.

  6. Magnetic shape memory fatigue

    Science.gov (United States)

    Heczko, Oleg; Straka, Ladislav; Soderberg, Outi; Hannula, Simo-Pekka

    2005-05-01

    Single crystal specimens of having compositions close to Ni2MnGa and exhibiting magnetic shape memory effect (MSME) were tested in a rotating magnetic field at a frequency of 5.7 Hz. The applied magnetic field, about 0.7 T was strong enough to induce the MSME. Test of one specimen was discontinued because of the structural failure of the specimens after 0.5 million cycles. Second specimen was tested up to 37 millions cycles. The evolution of the martensitic morphology and crack propagation were observed by optical microscopy. To characterize the magnetic shape memory behavior the simultaneous measurements of the field-induced strain and magnetization as a function of the magnetic field and external load was used. The full MSM effect, about 6% obtained prior the test, decreased to about 3% during the first million cycles. This value stayed then approximately constant up to 37 millions cycles of rotating magnetic field. The magnetic field needed to initiate the MSME increased. The observed behavior is discussed within the framework of observed martensitic band structure in the specimens and the existence of initial cracks and other obstacles for martensitic twin boundary motion.

  7. One thousand magnets delivered!

    CERN Multimedia

    2005-01-01

    The little matchstick-like objects, neatly lined up like colouring pencils in their box, are in fact LHC magnets seen from the air. These particular ones are being stored at Point 19 just alongside SM18, the magnet assembly and testing hall, which can be seen on the right of the picture. On the right in the background, is the Meyrin site.

  8. Analogue Magnetism: An Ansatz

    CERN Document Server

    Osano, Bob

    2016-01-01

    We present an ansatz for the relationship between magnetic flux density and fluid vorticity evolution equations. We also suggest that the magnetic flux density evolution equations be compared to the evolution equation for an effective vorticity ($\\omega_{eff}$), which bears a power law relation to the ordinary vorticity.

  9. Synthesis and Characterization of Magnetic Molecularly Imprinted Polymer for the Enrichment of Ofloxacin Enantiomers in Fish Samples

    Directory of Open Access Journals (Sweden)

    Yan-Fei Wang

    2016-07-01

    Full Text Available A new method for the isolation and enrichment of ofloxacin enantiomers from fish samples was developed using magnetic molecularly imprinted polymers (MMIPs. These polymers can be easily collected and rapidly separated using an external magnetic field, and also exhibit a high specific recognition for ofloxacin enantiomers. The preparation of amino-functionalized MMIPs was carried out via suspension polymerization and a ring-opening reaction using rac-ofloxacin as a template, ethylenediamine as an active group, glycidyl methacrylate and methyl methacrylate as functional monomers, divinylbenzene as a cross-linker, and Fe3O4 nanoparticles as magnetic cores. The characteristics of the MMIPs were assessed using transmission electron microscopy (TEM, X-ray powder diffraction (XRD, Fourier-transform infrared spectroscopy (FT-IR, and vibrating sample magnetometer (VSM measurements. Furthermore, the adsorption properties were determined using Langmuir and Freundlich isotherm models. The conditions for use of these MMIPs as magnetic solid-phase extraction (MSPE sorbents, including pH, adsorption time, desorption time, and eluent, were investigated in detail. An extraction method using MMIPs coupled with high performance liquid chromatography (HPLC was developed for the determination of ofloxacin enantiomers in fish samples. The limits of quantitation (LOQ for the developed method were 0.059 and 0.067 μg∙mL−1 for levofloxacin and dextrofloxacin, respectively. The recovery of ofloxacin enantiomers ranged from 79.2% ± 5.6% to 84.4% ± 4.6% and ofloxacin enantiomers had good linear relationships within the concentration range of 0.25–5.0 μg∙mL−1 (R2 > 0.999. The obtained results demonstrate that MSPE-HPLC is a promising approach for preconcentration, purification, and simultaneous separation of ofloxacin enantiomers in biomatrix samples.

  10. The magnetic properties of the hollow cylindrical ideal remanence magnet

    DEFF Research Database (Denmark)

    Bjørk, Rasmus

    2016-01-01

    We consider the magnetic properties of the hollow cylindrical ideal remanence magnet. This magnet is the cylindrical permanent magnet that generates a uniform field in the cylinder bore, using the least amount of magnetic energy to do so. The remanence distribution of this magnet is derived...... and the generated field is compared to that of a Halbach cylinder of equal dimensions. The ideal remanence magnet is shown in most cases to generate a significantly lower field than the equivalent Halbach cylinder, although the field is generated with higher efficiency. The most efficient Halbach cylinder is shown...... to generate a field exactly twice as large as the equivalent ideal remanence magnet....

  11. Magnetic Properties of Erbium Gallium Gallate under High Magnetic Field

    Institute of Scientific and Technical Information of China (English)

    Zhang Xijuan; Cheng Haiying; Yang Cuihong; Wang Wei

    2004-01-01

    A theoretical investigation on the magnetic properties of rare-earth Er3+ in Er3 Ga5 O12 was reported. The average magnetic moments(M) for applied magnetic field H parallel to the [001 ], [ 100], [ 110], [ 111 ] direction was studied based on the quantum theory. Temperature dependence of the magnetic properties is analyzed for H applied parallel to the [ 100] and [ 111 ] crystallographic directions. The magnetization decreases with increasing temperature,showing good agreement with thermal effect. A strong anisotropy of the magnetization is found under high magnetic field, but when the magnetic field is small, M and H are proportional.

  12. The magnetic properties of the hollow cylindrical ideal remanence magnet

    CERN Document Server

    Bjørk, R

    2016-01-01

    We consider the magnetic properties of the hollow cylindrical ideal remanence magnet. This magnet is the cylindrical permanent magnet that generates a uniform field in the cylinder bore, using the least amount of magnetic energy to do so. The remanence distribution of this magnet is derived and the generated field is compared to that of a Halbach cylinder of equal dimensions. The ideal remanence magnet is shown in most cases to generate a significantly lower field than the equivalent Halbach cylinder, although the field is generated with higher efficiency. The most efficient Halbach cylinder is shown to generate a field exactly twice as large as the equivalent ideal remanence magnet.

  13. Magnetic forces produced by rectangular permanent magnets in static microsystems.

    Science.gov (United States)

    Gassner, Anne-Laure; Abonnenc, Mélanie; Chen, Hong-Xu; Morandini, Jacques; Josserand, Jacques; Rossier, Joel S; Busnel, Jean-Marc; Girault, Hubert H

    2009-08-21

    Finite element numerical simulations were carried out in 2D geometries to map the magnetic field and force distribution produced by rectangular permanent magnets as a function of their size and position with respect to a microchannel. A single magnet, two magnets placed in attraction and in repulsion have been considered. The goal of this work is to show where magnetic beads are preferentially captured in a microchannel. These simulations were qualitatively corroborated, in one geometrical case, by microscopic visualizations of magnetic bead plug formation in a capillary. The results show that the number of plugs is configuration dependent with: in attraction, one plug in the middle of the magnets; in repulsion, two plugs near the edges of the magnets; and with a single magnet, a plug close to the center of the magnet. The geometry of the magnets (h and l are the height and length of the magnets respectively) and their relative spacing s has a significant impact on the magnetic flux density. Its value inside a magnet increases with the h/l ratio. Consequently, bar magnets produce larger and more uniform values than flat magnets. The l/s ratio also influences the magnetic force value in the microchannel, both increasing concomitantly for all the configurations. In addition, a zero force zone in the middle appears in the attraction configuration as the l/s ratio increases, while with a single magnet, the number of maxima and minima goes from one to two, producing two focusing zones instead of only one.

  14. Magnetic separation of antibiotics by electrochemical magnetic seeding

    Energy Technology Data Exchange (ETDEWEB)

    Ihara, I; Toyoda, K [Department of Agricultural Engineering and Socio Economics, Kobe University, Nada, Kobe 657-8501 (Japan); Beneragama, N; Umetsu, K [Department of Animal Science, Obihiro University of Agriculture and Veterinary Medicine, Obihiro, Hokkaido 080-8555 (Japan)], E-mail: ihara@port.kobe-u.ac.jp

    2009-03-01

    Magnetic separation of several classes of antibiotics was investigated using electrochemical magnetic seeding. Electrocoagulation with a sacrificial anode followed by addition of magnetite particles was applied for the magnetic seeding of antibiotics. With electrochemical magnetic seeding using an iron anode, tetracycline antibiotics (oxytetracycline, chlortetracycline, doxycycline and tetracycline) and cephalosporin antibiotic (cefdinir) were rapidly removed from synthetic wastewater by magnetic separation using a neodymium magnet. Iron and aluminium anodes were suitable for magnetic seeding of the antibiotics. The results indicated that the ability of antibiotics to form strong complex with iron and aluminium allowed the higher removal by magnetic separation. This method would be appropriate for rapid treatment of antibiotics in wastewater.

  15. Review and comparison of magnet designs for magnetic refrigeration

    DEFF Research Database (Denmark)

    Bjørk, Rasmus; Bahl, Christian Robert Haffenden; Smith, Anders

    2010-01-01

    One of the key issues in magnetic refrigeration is generating the magnetic field that the magnetocaloric material must be subjected to. The magnet constitutes a major part of the expense of a complete magnetic refrigeration system and a large effort should therefore be invested in improving...... the magnet design. A detailed analysis of the efficiency of different published permanent magnet designs used in magnetic refrigeration applications is presented in this paper. Each design is analyzed based on the generated magnetic flux density, the volume of the region where this flux is generated...

  16. Quasi-continuous magnets

    Energy Technology Data Exchange (ETDEWEB)

    Sims, J.R. [Los Alamos National Lab., NM (United States); Naumovich, G.J.; Hoang, T.A.; Dent, P.C. [Everson Electric Co., Bethlehem, PA (United States)

    1996-05-01

    The National High Magnetic Field Laboratory is completing a quasi-continuous magnet which will sustain a constant field of 60 T for 100 ms in a 32-mm 77 K bore. This magnet consists of 9 mechanically independent, nested, liquid nitrogen-cooled coils which are individually reinforced by high-strength stainless steel outer shells. The coils were wound from rectangular large cross-section, high-strength, high-conductivity copper conductor insulated wtih polyimide and fiberglass tapes. After winding, the coils were inserted into closely fitted, stainless steel reinforcing shells and impregnated with epoxy resin. Design, analysis, material, fabrication and operational issues for this class of magnets are reviewed. Fabrication and quality assurance testing of the 60 T coil set are covered in detail. Future growth of and possible links from this technology to other magnet systems are discussed. Needed improvements in design, analysis, materials, and fabrication are outlined.

  17. Lanthanide single molecule magnets

    Energy Technology Data Exchange (ETDEWEB)

    Tang, Jinkui; Zhang, Peng [Chinese Academy of Sciences, Changchun (China). Changchun Inst. of Applied Chemistry

    2015-10-01

    This book begins by providing basic information on single-molecule magnets (SMMs), covering the magnetism of lanthanide, the characterization and relaxation dynamics of SMMs and advanced means of studying lanthanide SMMs. It then systematically introduces lanthanide SMMs ranging from mononuclear and dinuclear to polynuclear complexes, classifying them and highlighting those SMMs with high barrier and blocking temperatures - an approach that provides some very valuable indicators for the structural features needed to optimize the contribution of an Ising type spin to a molecular magnet. The final chapter presents some of the newest developments in the lanthanide SMM field, such as the design of multifunctional and stimuli-responsive magnetic materials as well as the anchoring and organization of the SMMs on surfaces. In addition, the crystal structure and magnetic data are clearly presented with a wealth of illustrations in each chapter, helping newcomers and experts alike to better grasp ongoing trends and explore new directions.

  18. GHz nuclear magnetic resonance

    Energy Technology Data Exchange (ETDEWEB)

    Cross, T.A.; Drobny, G.; Trewhella, J.

    1994-12-01

    For the past dozen years, 500- and 600-MHz spectrometers have become available in many laboratories. The first 600-MHz NMR spectrometer (at Carnegie Mellon University) was commissioned more than 15 years ago and, until 1994, represented the highest field available for high-resolution NMR. This year, we have witnessed unprecedented progress in the development of very high field magnets for NMR spectroscopy, including the delivery of the first commercial 750-MHz NMR spectrometers. In addition, NMR signals have been obtained from 20-Tesla magnets (850 MHz for {sup 1}H`s) at both Los Alamos National Laboratory and Florida State University in the NHMFL (National High Magnetic Field Laboratory). These preliminary experiments have been performed in magnets with 100-ppm homogeneity, but a 20-Tesla magnet developed for the NHMFL will be brought to field this year with a projected homogeneity of 0.1 ppm over a 1-cm-diam spherical volume.

  19. Electricity and magnetism

    CERN Document Server

    Purcell, Edward M

    2013-01-01

    For 50 years, Edward M. Purcell's classic textbook has introduced students to the wonders of electricity and magnetism. The third edition has been brought up to date and is now in SI units. It features hundreds of new examples, problems and figures and contains discussions of real-life applications. The textbook covers all the standard introductory topics, such as electrostatics, magnetism, circuits, electromagnetic waves and electric and magnetic fields in matter. Taking a non-traditional approach, magnetism is derived as a relativistic effect. Mathematical concepts are introduced in parallel with the physics topics at hand, making the motivations clear. Macroscopic phenomena are derived rigorously from microscopic phenomena. With worked examples, hundreds of illustrations and nearly 600 end-of-chapter problems and exercises, this textbook is ideal for electricity and magnetism courses. Solutions to the exercises are available for instructors at www.cambridge.org/9781107014022.

  20. Metallic Magnetic Nanoparticles

    Directory of Open Access Journals (Sweden)

    A. Hernando

    2005-01-01

    Full Text Available In this paper, we reviewed some relevant aspects of the magnetic properties of metallic nanoparticles with small size (below 4 nm, covering the size effects in nanoparticles of magnetic materials, as well as the appearance of magnetism at the nanoscale in materials that are nonferromagnetic in bulk. These results are distributed along the text that has been organized around three important items: fundamental magnetic properties, different fabrication procedures, and characterization techniques. A general introduction and some experimental results recently obtained in Pd and Au nanoparticles have also been included. Finally, the more promising applications of magnetic nanoparticles in biomedicine are indicated. Special care was taken to complete the literature available on the subject.

  1. Physics of magnetic nanostructures

    CERN Document Server

    Owens, Frank J

    2015-01-01

    This book discusses how the important properties of materials such as the cohesive energy, and the electronic and vibrational structures are affected when materials have at least one length in the nanometer range. The author uses relatively simple models of the solid state to explain why these changes in the size and dimension in the nanometer regime occur. The text also reviews the physics of magnetism and experimental methods of measuring magnetic properties necessary to understanding how nanosizing affects magnetism. Various kinds of magnetic structures are presented by the author in order to explain how nanosizing influences their magnetic properties. The book also presents potential and actual applications of nanomaterials in the fields of medicine and computer data storage.

  2. Superconducting Accelerator Magnets

    CERN Document Server

    Mess, K H; Wolff, S

    1996-01-01

    The main topic of the book are the superconducting dipole and quadrupole magnets needed in high-energy accelerators and storage rings for protons, antiprotons or heavy ions. The basic principles of low-temperature superconductivity are outlined with special emphasis on the effects which are relevant for accelerator magnets. Properties and fabrication methods of practical superconductors are described. Analytical methods for field calculation and multipole expansion are presented for coils without and with iron yoke. The effect of yoke saturation and geometric distortions on field quality is studied. Persistent magnetization currents in the superconductor and eddy currents the copper part of the cable are analyzed in detail and their influence on field quality and magnet performance is investigated. Superconductor stability, quench origins and propagation and magnet protection are addressed. Some important concepts of accelerator physics are introduced which are needed to appreciate the demanding requirements ...

  3. Magnetic entropy and cooling

    DEFF Research Database (Denmark)

    Hansen, Britt Rosendahl; Kuhn, Luise Theil; Bahl, Christian Robert Haffenden

    2010-01-01

    Some manifestations of magnetism are well-known and utilized on an everyday basis, e.g. using a refrigerator magnet for hanging that important note on the refrigerator door. Others are, so far, more exotic, such as cooling by making use of the magnetocaloric eect. This eect can cause a change...... or nitrogen liquefaction or for room-temperature cooling. The magnetocaloric eect can further be used to determine phase transition boundaries, if a change in the magnetic state occurs at the boundary.In this talk, I will introduce the magnetocaloric eect (MCE) and the two equations, which characterize...... in the temperature of a magnetic material when a magnetic eld is applied or removed. For many years, experimentalists have made use of dilute paramagnetic materials to achieve milliKelvin temperatures by use of the magnetocaloric eect. Also, research is done on materials, which might be used for hydrogen, helium...

  4. An integrated magnetics component

    DEFF Research Database (Denmark)

    2013-01-01

    The present invention relates to an integrated magnetics component comprising a magnetically permeable core comprising a base member extending in a horizontal plane and first, second, third and fourth legs protruding substantially perpendicularly from the base member. First, second, third...... extending substantially orthogonally to the first flux path. Another aspect of the invention relates to a multiple-input isolated power converter comprising the integrated magnetics component....... and fourth output inductor windings are wound around the first, second, third and fourth legs, respectively. A first input conductor of the integrated magnetics component has a first conductor axis and extends in-between the first, second, third and fourth legs to induce a first magnetic flux through a first...

  5. Lanthanide single molecule magnets

    CERN Document Server

    Tang, Jinkui

    2015-01-01

    This book begins by providing basic information on single-molecule magnets (SMMs), covering the magnetism of lanthanide, the characterization and relaxation dynamics of SMMs, and advanced means of studying lanthanide SMMs. It then systematically introduces lanthanide SMMs ranging from mononuclear and dinuclear to polynuclear complexes, classifying them and highlighting those SMMs with high barrier and blocking temperatures – an approach that provides some very valuable indicators for the structural features needed to optimize the contribution of an Ising type spin to a molecular magnet. The final chapter presents some of the newest developments in the lanthanide SMM field, such as the design of multifunctional and stimuli-responsive magnetic materials as well as the anchoring and organization of the SMMs on surfaces. In addition, the crystal structure and magnetic data are clearly presented with a wealth of illustrations in each chapter, helping newcomers and experts alike to better grasp ongoing trends and...

  6. Study on healthcare magnetic concrete

    Institute of Scientific and Technical Information of China (English)

    YANG Yushan; DONG Faqin; FENG Jianjun

    2006-01-01

    Magnetic concrete was prepared by adding SrFe12O9 magnetic functional elementary material into concrete, and its magnetism was charged by magnetizing machine. The effect of SrFe12O9 content on magnetic field intensity and the attenuation of magnetic field intensity were investigated in different medium. The blood viscosity of rats kept in magnetic concrete was carried out. The results show that magnetic concrete can be prepared by adding SrFe12O9, and magnetic fields intensity increases with the augment of ferrite content. The attenuation of magnetic fields is mainly related with the density of medium, but it is secondary to the properties of medium. The blood viscosity of rats decreases under magnetic condition, but the blood cells remain the same as before. Experimental results support that magnetic concrete has great healthcare function.

  7. Magnetic Resonance Imaging (MRI) -- Head

    Medline Plus

    Full Text Available ... Us News Physician Resources Professions Site Index A-Z Magnetic Resonance Imaging (MRI) - Head Magnetic resonance imaging ( ... if possible, or removed prior to the MRI scan. Because they can interfere with the magnetic field ...

  8. Children's (Pediatric) Magnetic Resonance Imaging

    Medline Plus

    Full Text Available ... Resources Professions Site Index A-Z Children’s (Pediatric) Magnetic Resonance Imaging Children’s magnetic resonance imaging (MRI) uses a powerful magnetic field, radio waves ...

  9. Children's (Pediatric) Magnetic Resonance Imaging

    Medline Plus

    Full Text Available ... Resources Professions Site Index A-Z Children’s (Pediatric) Magnetic Resonance Imaging Children’s magnetic resonance imaging (MRI) uses a powerful magnetic field, radio ...

  10. Magnetic Resonance Imaging (MRI) -- Head

    Medline Plus

    Full Text Available ... Site Index A-Z Magnetic Resonance Imaging (MRI) - Head Magnetic resonance imaging (MRI) of the head uses ... of the Head? What is MRI of the Head? Magnetic resonance imaging (MRI) is a noninvasive medical ...

  11. Magnetically responsive dry fluids

    Science.gov (United States)

    Sousa, Filipa L.; Bustamante, Rodney; Millán, Angel; Palacio, Fernando; Trindade, Tito; Silva, Nuno J. O.

    2013-07-01

    Ferrofluids and dry magnetic particles are two separate classes of magnetic materials with specific niche applications, mainly due to their distinct viscosity and interparticle distances. For practical applications, the stability of these two properties is highly desirable but hard to achieve. Conceptually, a possible solution to this problem would be encapsulating the magnetic particles but keeping them free to rotate inside a capsule with constant interparticle distances and thus shielded from changes in the viscosity of the surrounding media. Here we present an example of such materials by the encapsulation of magnetic ferrofluids into highly hydrophobic silica, leading to the formation of dry ferrofluids, i.e., a material behaving macroscopically as a dry powder but locally as a ferrofluid where magnetic nanoparticles are free to rotate in the liquid.Ferrofluids and dry magnetic particles are two separate classes of magnetic materials with specific niche applications, mainly due to their distinct viscosity and interparticle distances. For practical applications, the stability of these two properties is highly desirable but hard to achieve. Conceptually, a possible solution to this problem would be encapsulating the magnetic particles but keeping them free to rotate inside a capsule with constant interparticle distances and thus shielded from changes in the viscosity of the surrounding media. Here we present an example of such materials by the encapsulation of magnetic ferrofluids into highly hydrophobic silica, leading to the formation of dry ferrofluids, i.e., a material behaving macroscopically as a dry powder but locally as a ferrofluid where magnetic nanoparticles are free to rotate in the liquid. Electronic supplementary information (ESI) available. See DOI: 10.1039/c3nr01784b

  12. Rare Earths and Magnetic Refrigeration

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    Magnetic refrigeration is a revolutionary, efficient, environmentally friendly cooling technology, which is on the threshold of commercialization. The magnetic rare earth materials are utilized as the magnetic refrigerants in most cooling devices, and for many cooling application the Nd2Fe14B permanent magnets are employed as the source of the magnetic field. The status of the near room temperature magnetic cooling was reviewed.

  13. Magnetic measurements inside the Omicron magnet.

    CERN Multimedia

    1977-01-01

    The multipurpose detection system (Omicron) built at the SC in the late seventies in the Proton Hall made use of the large aperture magnet (on loan from Rutherford Lab, 85 cm gap height, 1 m width, 1.8 m length, 1 Tesla peak field). See CERN Courier 17 (1977) p. 61.

  14. Magnetically Coupled Magnet-Spring Oscillators

    Science.gov (United States)

    Donoso, G.; Ladera, C. L.; Martin, P.

    2010-01-01

    A system of two magnets hung from two vertical springs and oscillating in the hollows of a pair of coils connected in series is a new, interesting and useful example of coupled oscillators. The electromagnetically coupled oscillations of these oscillators are experimentally and theoretically studied. Its coupling is electromagnetic instead of…

  15. Review and comparison of magnet designs for magnetic refrigeration

    CERN Document Server

    Bjørk, R; Smith, A; Pryds, N

    2014-01-01

    One of the key issues in magnetic refrigeration is generating the magnetic field that the magnetocaloric material must be subjected to. The magnet constitutes a major part of the expense of a complete magnetic refrigeration system and a large effort should therefore be invested in improving the magnet design. A detailed analysis of the efficiency of different published permanent magnet designs used in magnetic refrigeration applications is presented in this paper. Each design is analyzed based on the generated magnetic flux density, the volume of the region where this flux is generated and the amount of magnet material used. This is done by characterizing each design by a figure of merit magnet design efficiency parameter, $\\Lambda_\\mathrm{cool}$. The designs are then compared and the best design found. Finally recommendations for designing the ideal magnet design are presented based on the analysis of the reviewed designs.

  16. Magnetic Resonance Force Microscopy System

    Data.gov (United States)

    Federal Laboratory Consortium — The Magnetic Resonance Force Microscopy (MRFM) system, developed by ARL, is the world's most sensitive nuclear magnetic resonance (NMR) spectroscopic analysis tool,...

  17. Magnetism a very short introduction

    CERN Document Server

    Blundell, Stephen J

    2012-01-01

    Magnetism: A Very Short Introduction explains the mysteries and importance of magnetism. For centuries magnetism has been used for various exploits: as a great healer, a navigation aid through compasses, and through motors, generators, and turbines it has given us power. Our understanding of electricity and magnetism, from the work of Galvani, Ampère, Faraday, and Tesla is explored, and how Maxwell and Faraday's work led to the unification of electricity and magnetism is explained. With a discussion of the relationship between magnetism and relativity, quantum magnetism, and its impact on computers and information storage, how magnetism has changed our fundamental understanding of the Universe is shown.

  18. Electromagnetic acceleration of permanent magnets

    CERN Document Server

    Dolya, S N

    2015-01-01

    We consider the acceleration of the permanent magnets, consisting of neodymium iron boron by means of the running magnetic field gradient. It is shown that the specific magnetic moment per nucleon in neodymium iron boron is determined by the remained magnetization of the substance. The maximum accessable gradient of the magnetic field accelerating the permanent magnets is determined by the coercive force thirty kilogauss. For the neodymium iron boron magnets this gradient is equal to twenty kilogauss divided by one centimeter. The finite velocity of the magnets six kilometers per second, the length of acceleration is six hundred thirty-seven meters.

  19. Model of THz Magnetization Dynamics

    Science.gov (United States)

    Bocklage, Lars

    2016-01-01

    Magnetization dynamics can be coherently controlled by THz laser excitation, which can be applied in ultrafast magnetization control and switching. Here, transient magnetization dynamics are calculated for excitation with THz magnetic field pulses. We use the ansatz of Smit and Beljers, to formulate dynamic properties of the magnetization via partial derivatives of the samples free energy density, and extend it to solve the Landau-Lifshitz-equation to obtain the THz transients of the magnetization. The model is used to determine the magnetization response to ultrafast multi- and single-cycle THz pulses. Control of the magnetization trajectory by utilizing the THz pulse shape and polarization is demonstrated. PMID:26956997

  20. Children's (Pediatric) Magnetic Resonance Imaging

    Medline Plus

    Full Text Available ... Magnetic Resonance, Functional (fMRI) - Brain Children's (Pediatric) CT (Computed Tomography) Magnetic Resonance Imaging (MRI) Safety Contrast Materials Children and Radiation ...

  1. Children's (Pediatric) Magnetic Resonance Imaging

    Medline Plus

    Full Text Available ... Magnetic Resonance, Functional (fMRI) - Brain Children's (Pediatric) CT (Computed Tomography) Magnetic Resonance Imaging (MRI) Safety Contrast Materials Children and Radiation Safety ...

  2. Active Magnetic Regenerative Liquefier

    Energy Technology Data Exchange (ETDEWEB)

    Barclay, John A. [Heracles Energy Corporation d.b.a. Prometheus Energy, Washington, DC (United States); Oseen-Send, Kathryn [Heracles Energy Corporation d.b.a. Prometheus Energy, Washington, DC (United States); Ferguson, Luke [Heracles Energy Corporation d.b.a. Prometheus Energy, Washington, DC (United States); Pouresfandiary, Jamshid [Heracles Energy Corporation d.b.a. Prometheus Energy, Washington, DC (United States); Cousins, Anand [Heracles Energy Corporation d.b.a. Prometheus Energy, Washington, DC (United States); Ralph, Heather [Heracles Energy Corporation d.b.a. Prometheus Energy, Washington, DC (United States); Hampto, Tom [Heracles Energy Corporation d.b.a. Prometheus Energy, Washington, DC (United States)

    2016-01-12

    This final report for the DOE Project entitled Active Magnetic Regenerative Liquefier (AMRL) funded under Grant DE-FG36-08GO18064 to Heracles Energy Corporation d.b.a. Prometheus Energy (Heracles/Prometheus) describes an active magnetic regenerative refrigerator (AMRR) prototype designed and built during the period from July 2008 through May 2011. The primary goal of this project was to make significant technical advances toward highly efficient liquefaction of hydrogen. Conventional hydrogen liquefiers at any scale have a maximum FOM of ~0.35 due primarily to the intrinsic difficulty of rapid, efficient compression of either hydrogen or helium working gases. Numerical simulation modeling of high performance AMRL designs indicates certain designs have promise to increase thermodynamic efficiency from a FOM of ~0.35 toward ~0.5 to ~0.6. The technical approach was the use of solid magnetic working refrigerants cycled in and out of high magnetic fields to build an efficient active regenerative magnetic refrigeration module providing cooling power for AMRL. A single-stage reciprocating AMRR with a design temperature span from ~290 K to ~120 K was built and tested with dual magnetic regenerators moving in and out of the conductively-cooled superconducting magnet subsystem. The heat transfer fluid (helium) was coupled to the process stream (refrigeration/liquefaction load) via high performance heat exchangers. In order to maximize AMRR efficiency a helium bypass loop with adjustable flow was incorporated in the design because the thermal mass of magnetic refrigerants is higher in low magnetic field than in high magnetic field. Heracles/Prometheus designed experiments to measure AMRR performance under a variety of different operational parameters such as cycle frequency, magnetic field strength, heat transfer fluid flow rate, amount of bypass flow of the heat transfer fluid while measuring work input, temperature span, cooling capability as a function of cold temperature

  3. MAGNETIC CIRCUIT EQUIVALENT OF THE SYNCHRONOUS MOTOR WITH INCORPORATED MAGNETS

    Directory of Open Access Journals (Sweden)

    Fyong Le Ngo

    2015-01-01

    Full Text Available Magnetic circuitry computation is one of the central stages of designing a synchronous motor with incorporated magnets, which can be performed by means of a simplified method of the magnetic-circuits equivalent modeling. The article studies the magnetic circuit of the motor with the rotor-incorporated magnets, which includes four sectors: constant magnets with the field pole extension made of magnetically soft steel, magniflux dispersion sections containing air barriers and steel bridges; the air gap; the stator grooves, cogs and the frame yoke. The authors introduce an equivalent model of the magnetic circuit. High-energy magnets with a linear demagnetization curve are employed in the capacity of constant magnets. Two magnets create the magnetic flux for one pole. The decline of magnetic potential in the steel of the pole is negligible consequent on the admission that the poles magnetic inductivity µ = ∞. The rotor design provides for the air barriers and the steel bridges that close leakage flux. The induction-permeability curve linearization serves for the bridges magnetic saturation accountability and presents a polygonal line consisting of two linear sections. The estimation of the magnet circuit section including the cogs and the frame yoke is executed with account of the steel saturation, their magnetic conductivities thereat being dependent on the saturation rate. Relying on the equivalent model of the magnetic circuit, the authors deduce a system of two equations written from the first and the second Kirchhoff laws of the magnetic circuits. These equations allow solving two problems: specifying dimensions of the magnets by the preset value of the magnetic flow in the clearance and determining the clearance magnetic flow at the preset motor rotor-and-stator design.

  4. Magnetic Coordinate Systems

    Science.gov (United States)

    Laundal, K. M.; Richmond, A. D.

    2017-03-01

    Geospace phenomena such as the aurora, plasma motion, ionospheric currents and associated magnetic field disturbances are highly organized by Earth's main magnetic field. This is due to the fact that the charged particles that comprise space plasma can move almost freely along magnetic field lines, but not across them. For this reason it is sensible to present such phenomena relative to Earth's magnetic field. A large variety of magnetic coordinate systems exist, designed for different purposes and regions, ranging from the magnetopause to the ionosphere. In this paper we review the most common magnetic coordinate systems and describe how they are defined, where they are used, and how to convert between them. The definitions are presented based on the spherical harmonic expansion coefficients of the International Geomagnetic Reference Field (IGRF) and, in some of the coordinate systems, the position of the Sun which we show how to calculate from the time and date. The most detailed coordinate systems take the full IGRF into account and define magnetic latitude and longitude such that they are constant along field lines. These coordinate systems, which are useful at ionospheric altitudes, are non-orthogonal. We show how to handle vectors and vector calculus in such coordinates, and discuss how systematic errors may appear if this is not done correctly.

  5. Magnetically mediated thermoacoustic imaging

    Science.gov (United States)

    Feng, Xiaohua; Gao, Fei; Zheng, Yuanjin

    2014-03-01

    In this paper, alternating magnetic field is explored for inducing thermoacoustic effect on dielectric objects. Termed as magnetically mediated thermo-acoustic (MMTA) effect that provides a contrast in conductivity, this approach employs magnetic resonance for delivering energy to a desired location by applying a large transient current at radio frequency below 50MHz to a compact magnetically resonant coil. The alternating magnetic field induces large electric field inside conductive objects, which then undergoes joule heating and emanates acoustic signal thermo-elastically. The magnetic mediation approach with low radio frequency can potentially provide deeper penetration than microwave radiation due to the non-magnetic nature of human body and therefore extend thermoacoustic imaging to deep laid organs. Both incoherent time domain method that applies a pulsed radio frequency current and coherent frequency domain approach that employs a linear chirp signal to modulate the envelop of the current are discussed. Owing to the coherent processing nature, the latter approach is capable of achieving much better signal to noise ratio and therefore potential for portable imaging system. Phantom experiments are carried out to demonstrate the signal generation together with some preliminary imaging results. Ex-vivo tissue studies are also investigated.

  6. Magnetically controlled solar nebula

    Science.gov (United States)

    Stepinski, T. F.; Reyes-Ruiz, M.

    1993-01-01

    It is widely believed that a primordial solar nebula, the precursor of the Sun and its planetary system, could be best described in terms of an accretion disk. Such an accretion disk is though to be turbulent, and it is usually imagined that turbulent viscosity alone provides the torque responsible for the structure and the evolution of the nebula. However, it was found that an MHD dynamo operating in a turbulent nebula can contemporaneously produce magnetic fields capable of significantly altering or even dominating the total torque. Thus, it seems that no model of a viscous solar nebula is complete without taking magnetic fields into consideration. It was demonstrated that there are usually two distinct regions of nebular disk where a dynamo can operate: the inner region, where the magnetic field coupled to gas due to relatively high thermal ionization; and the outer region, where this coupling is achieved due to nonthermal ionization. Most models also show the existence of an intermediate region, 'the magnetic gap,' where neither thermal nor nonthermal sources can produce enough ionization to provide the necessary coupling between the magnetic field and the gas. The location and width of the gap change substantially from one model to another. At present, we can only estimate the strength of a generated magnetic field. It seems that a large-scale magnetic field is likely to be in the equipartition with the turbulent kinetic energy; however, the intense magnetic fluctuations may greatly exceed this equipartition strength on short time and length scales. To show how a dynamo-generated magnetic field changes the structure of a viscous nebula, we consider four nebula models extensively.

  7. PREFACE: Geometrically frustrated magnetism Geometrically frustrated magnetism

    Science.gov (United States)

    Gardner, Jason S.

    2011-04-01

    Frustrated magnetism is an exciting and diverse field in condensed matter physics that has grown tremendously over the past 20 years. This special issue aims to capture some of that excitement in the field of geometrically frustrated magnets and is inspired by the 2010 Highly Frustrated Magnetism (HFM 2010) meeting in Baltimore, MD, USA. Geometric frustration is a broad phenomenon that results from an intrinsic incompatibility between some fundamental interactions and the underlying lattice geometry based on triangles and tetrahedra. Most studies have centred around the kagomé and pyrochlore based magnets but recent work has looked at other structures including the delafossite, langasites, hyper-kagomé, garnets and Laves phase materials to name a few. Personally, I hope this issue serves as a great reference to scientist both new and old to this field, and that we all continue to have fun in this very frustrated playground. Finally, I want to thank the HFM 2010 organizers and all the sponsors whose contributions were an essential part of the success of the meeting in Baltimore. Geometrically frustrated magnetism contents Spangolite: an s = 1/2 maple leaf lattice antiferromagnet? T Fennell, J O Piatek, R A Stephenson, G J Nilsen and H M Rønnow Two-dimensional magnetism and spin-size effect in the S = 1 triangular antiferromagnet NiGa2S4 Yusuke Nambu and Satoru Nakatsuji Short range ordering in the modified honeycomb lattice compound SrHo2O4 S Ghosh, H D Zhou, L Balicas, S Hill, J S Gardner, Y Qi and C R Wiebe Heavy fermion compounds on the geometrically frustrated Shastry-Sutherland lattice M S Kim and M C Aronson A neutron polarization analysis study of moment correlations in (Dy0.4Y0.6)T2 (T = Mn, Al) J R Stewart, J M Hillier, P Manuel and R Cywinski Elemental analysis and magnetism of hydronium jarosites—model kagome antiferromagnets and topological spin glasses A S Wills and W G Bisson The Herbertsmithite Hamiltonian: μSR measurements on single crystals

  8. Frontiers in Magnetic Materials

    CERN Document Server

    Narlikar, Anant V

    2005-01-01

    Frontiers in Magnetic Materials focuses on the current achievements and state-of-the-art advancements in magnetic materials. Several lines of development- High-Tc Superconductivity, Nanotechnology and refined experimental techniques among them – raised knowledge and interest in magnetic materials remarkably. The book comprises 24 chapters on the most relevant topics written by renowned international experts in the field. It is of central interest to researchers and specialists in Physics and Materials Science, both in academic and industrial research, as well as advanced students.

  9. Cryogenic Hybrid Magnetic Bearing

    Science.gov (United States)

    Meeks, Crawford R.; Dirusso, Eliseo; Brown, Gerald V.

    1994-01-01

    Cryogenic hybrid magnetic bearing is example of class of magnetic bearings in which permanent magnets and electromagnets used to suspend shafts. Electromagnets provide active control of position of shaft. Bearing operates at temperatures from -320 degrees F (-196 degrees C) to 650 degrees F (343 degrees C); designed for possible use in rocket-engine turbopumps, where effects of cryogenic environment and fluid severely limit lubrication of conventional ball bearings. This and similar bearings also suitable for terrestrial rotating machinery; for example, gas-turbine engines, high-vacuum pumps, canned pumps, precise gimbals that suspend sensors, and pumps that handle corrosive or gritty fluids.

  10. Magnetic-seeding filtration

    Energy Technology Data Exchange (ETDEWEB)

    Depaoli, D. [Oak Ridge National Lab., TN (United States)

    1996-10-01

    This task will investigate the capabilities of magnetic-seeding filtration for the enhanced removal of magnetic and nonmagnetic particulates from liquids. This technology appies to a wide range of liquid wastes, including groundwater, process waters, and tank supernatant. Magnetic-seeding filtration can be used in several aspects of treatment, such as (1) removal of solids, particularly those in the colloidal-size range that are difficult to remove by conventional means; (2) removal of contaminants by precipitation processes; and (3) removal of contaminants by sorption processes.

  11. Magnetic Actuators and Sensors

    Science.gov (United States)

    Brauer, John R.

    2005-12-01

    Magnetic actuators and sensors are needed to enable computer and manual control of motion. Magnetic actuators allow a small electrical signal to move small or large objects. To sense the amount of motion, magnetic sensors are frequently used. This book provides the most up-to-date coverage of topics important to modern engineers, both electrical and mechanical. The author includes the latest findings and design techniques from computer models. The latest software tools are used.

  12. Electrically controlled magnetism

    Science.gov (United States)

    Binek, Ch.; He, Xi; Wang, Yi; Sahoo, S.

    2008-08-01

    Manipulation of magnetically ordered states by electrical means is a promising approach towards novel spintronics devices. We report on the electric control of surface magnetism in Cr2O3 thin films and uniaxial anisotropy in ferroelectric/ferromagnetic heterostructures, respectively. Artificial magnetoelectricity is realized in a BaTiO3/Fe heterostructure. Here, thermally induced coercivity changes of the Fe hysteresis loop are used to derive the stress imposed by the ferroelectric BaTiO3 substrate on the adjacent Fe film. Electrically induced coercivity changes give rise to a giant magnetoelectric susceptibility in the vicinity of the magnetic coercive field.

  13. Magnetic refrigeration materials

    Institute of Scientific and Technical Information of China (English)

    戴闻; 沈保根; 高政祥

    2001-01-01

    Magnetic refrigeration has drawn much attention because of its greater efficiency and higher reliability than the traditional gas-cycle refrigeration technology. Recently, a kind of new materials with a giant magnetocaloric effect in the subroom temperature range, Gd5 (Six Ge1- x)4, was discovered, which boosts the search for high-performance magnetic refrigerants. However, the intermetallic compounds Gd5 (SixGe1 - x )4 belong to the first order transition materials; their performance in practical magnetic refrigeration cycles remains controversial. In this paper the developing tendency of the refrigerants are discussed on the basis of our work.

  14. Biomimetic magnetic nanoparticles

    Directory of Open Access Journals (Sweden)

    Michael T. Klem

    2005-09-01

    Full Text Available Magnetic nanoparticles are of considerable interest because of their potential use in high-density memory devices, spintronics, and applications in diagnostic medicine. The conditions for synthesis of these materials are often complicated by their high reaction temperatures, costly reagents, and post-processing requirements. Practical applications of magnetic nanoparticles will require the development of alternate synthetic strategies that can overcome these impediments. Biomimetic approaches to materials chemistry have provided a new avenue for the synthesis and assembly of magnetic nanomaterials that has great potential for overcoming these obstacles.

  15. Magnetic entropy and cooling

    DEFF Research Database (Denmark)

    Hansen, Britt Rosendahl; Kuhn, Luise Theil; Bahl, Christian Robert Haffenden

    2010-01-01

    in the temperature of a magnetic material when a magnetic eld is applied or removed. For many years, experimentalists have made use of dilute paramagnetic materials to achieve milliKelvin temperatures by use of the magnetocaloric eect. Also, research is done on materials, which might be used for hydrogen, helium...... the eect: the isothermal magnetic entropy change and the adiabatic temperature change. Some of the manifestations and utilizations of the MCE will be touched upon in a general way and nally I will talk about the results I have obtained on a sample of Gadolinium Iron Garnet (GdIG, Gd3Fe5O12), which...

  16. Advanced Magnetic Metrology Instrumentation

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    The extraordinary progress in magnetic peripheral storage systems has been fueled by the ad vancements in heads (MR, GMR, spin valves) and in very high coercivity, Iow remanence thickness product (Mrt) media. These advancements are imposing new performance require ments on the magnetometers (VSMs) used to characterize these materials. At the same time, they have introduced a new paradigm for in-process (nondestructive, robotic) magnetic metrol ogy tools to assure the stringent product uniformity requirements. In this paper, we discuss the recent advancements in magnetometry for characterizing state-of-the-art media and heads, as well as other magnetic materials.

  17. Investigations on the magnetization behavior of magnetic composite particles

    Science.gov (United States)

    Eichholz, Christian; Knoll, Johannes; Lerche, Dietmar; Nirschl, Hermann

    2014-11-01

    In life sciences the application of surface functionalized magnetic composite particles is establishing in diagnostics and in downstream processing of modern biotechnology. These magnetic composite particles consist of non-magnetic material, e.g. polystyrene, which serves as a matrix for the second magnetic component, usually colloidal magnetite. Because of the multitude of magnetic cores these magnetic beads show a complex magnetization behavior which cannot be described with the available approaches for homogeneous magnetic material. Therefore, in this work a new model for the magnetization behavior of magnetic composite particles is developed. By introducing an effective magnetization and considering an overall demagnetization factor the deviation of the demagnetization of homogeneously magnetized particles is taken into account. Calculated and experimental results show a good agreement which allows for the verification of the adapted model of particle magnetization. Besides, a newly developed magnetic analyzing centrifuge is used for the characterization of magnetic composite particle systems. The experimental results, also used for the model verification, give both, information about the magnetic properties and the interaction behavior of particle systems. By adding further components to the particle solution, such as salts or proteins, industrial relevant systems can be reconstructed. The analyzing tool can be used to adapt industrial processes without time-consuming preliminary tests with large samples in the process equipments.

  18. Random porous media and magnetic separation of magnetic colloids

    NARCIS (Netherlands)

    Baars, R.J.

    2016-01-01

    The separation of magnetic nanoparticles from a stable dispersion is a challenging task because of the nanoparticles' thermal motion and relatively small magnetic moments. Strong magnetic gradients are required to capture such particles, which can be achieved in a high-gradient magnetic separator. I

  19. ANALYTIC EXPRESSION OF MAGNETIC FIELD DISTRIBUTION OF RECTANGULAR PERMANENT MAGNETS

    Institute of Scientific and Technical Information of China (English)

    苟晓凡; 杨勇; 郑晓静

    2004-01-01

    From the molecular current viewpoint,an analytic expression exactly describing magnetic field distribution of rectangular permanent magnets magnetized sufficiently in one direction was derived from the Biot-Savart's law. This expression is useful not only for the case of one rectangular permanent magnet bulk, but also for that of several rectangular permanent magnet bulks. By using this expression,the relations between magnetic field distribution and the size of rectangular permanent magnets as well as the magnitude of magnetic field and the distance from the point in the space to the top (or bottom) surface of rectangular permanent magnets were discussed in detail. All the calculating results are consistent with experimental ones. For transverse magnetic field which is a main magnetic field of rectangular permanent magnets,in order to describe its distribution,two quantities,one is the uniformity in magnitude and the other is the uniformity in distribution of magnetic field,were defined. Furthermore, the relations between them and the geometric size of the magnet as well as the distance from the surface of permanent magnets were investigated by these formulas. The numerical results show that the geometric size and the distance have a visible influence on the uniformity in magnitude and the uniformity in distribution of the magnetic field.

  20. Numerical analysis of thermally actuated magnets for magnetization of superconductors

    Energy Technology Data Exchange (ETDEWEB)

    Li Quan; Yan Yu; Rawlings, Colin; Coombs, Tim, E-mail: ql229@cam.ac.u [EPEC Superconductivity Group, Engineering Department, University of Cambridge, Trumpington Street. Cambridge, CB2 1PZ (United Kingdom)

    2010-06-01

    Superconductors, such as YBCO bulks, have extremely high potential magnetic flux densities, comparing to rare earth magnets. Therefore, the magnetization of superconductors has attracted broad attention and contribution from both academic research and industry. In this paper, a novel technique is proposed to magnetize superconductors. Unusually, instead of using high magnetic fields and pulses, repeatedly magnetic waves with strength of as low as rare earth magnets are applied. These magnetic waves, generated by thermally controlling a Gadolinium (Gd) bulk with a rare earth magnet underneath, travel over the flat surface of a YBCO bulk and get trapped little by little. Thus, a very small magnetic field can be used to build up a very large magnetic field. In this paper, the modelling results of thermally actuated magnetic waves are presented showing how to transfer sequentially applied thermal pulses into magnetic waves. The experiment results of the magnetization of YBCO bulk are also presented to demonstrate how superconductors are progressively magnetized by small magnetic field

  1. Effective magnetic moment of neutrinos in strong magnetic fields

    CERN Document Server

    Pérez, A; Masood, S S; Gaitan, R; Rodríguez, S

    2002-01-01

    In this paper we compute the effective magnetic moment of neutrinos propagating in dense high magnetized medium. Taking typical values of magnetic field and densities of astrophysical objects (such as the cores of supernovae and neutron stars) we obtain an effective type of dipole magnetic moment in agreement with astrophysical and cosmological bounds. (Author)

  2. Modeling and analysis of magnetic dipoles in weak magnetic field

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    The magnetic leakage field distribution resulting from linear defects of a tube sample in the geomagnetic field is modeled according to the magnetic dipole theory.The formula to compute the normal component of the weak magnetic field is deduced based on the spatial distribution of the magnetic dipole.The shape and characteristics of the zero line (an important criterion for magnetic memory testing) of the normal field is analyzed under different longitudinal magnetizations.Results show that the characteristics of the zero line should be considered when the metal magnetic memory testing method is used to find and locate the defect.

  3. Magnetic Nanoparticles in Non-magnetic CNTs and Graphene

    Science.gov (United States)

    Kayondo, Moses; Seifu, Dereje

    Magnetic nanoparticles were embedded in non-magnetic CNTs and graphene matrix to incorporate all the advantages and the unique properties of CNTs and graphene. Composites of CNTs and graphene with magnetic nanoparticles may offer new opportunities for a wide variety of potential applications such as magnetic data storage, magnetic force microscopy tip, electromagnetic interference shields, thermally conductive films, reinforced polymer composites, transparent electrodes for displays, solar cells, gas sensors, magnetic nanofluids, and magnetically guided drug delivery systems. Magnetic nanoparticles coated CNTs can also be used as an electrode in lithium ion battery to replace graphite because of the higher theoretical capacity. Graphene nanocomposites, coated with magnetic sensitive nanoparticles, have demonstrated enhanced magnetic property. We would like to acknowledge support by NSF-MRI-DMR-1337339.

  4. Effects of magnetic field on fluidization properties of magnetic pearls

    Institute of Scientific and Technical Information of China (English)

    Maoming Fan; Zhenfu Luo; Yuemin Zhao; Qingru Chen; Daniel Tao; Xiuxiang Tao; Zhenqiang Chen

    2007-01-01

    An experimental study of the influence of external magnetic field on the fluidization behavior of magnetic pearls was carried out. Magnetic pearls are a magnetic form of iron oxide that mainly consists of Fe2O3 which are recovered from a high-volume power plant fly ash from pulverized coal combustion. Due to its abundance, low price and particular physical and chemical properties, magnetic pearls can be used as a heavy medium for minerals or solid waste dry separation based on density difference. This paper introduces the properties of magnetic pearls and compares the performance of magnetic pearls fluidised bed operation with or without an external magnetic field. Experimental results show that an external magnetic field significantly improves the fluidization performance of magnetic pearls such as uniformity and stability.

  5. Magnetic susceptibility, magnetization, magnetic moment and characterization of Carancas meteorite

    CERN Document Server

    Rosales, Domingo

    2015-01-01

    On September, 15th, 2007, in the community of Carancas (Puno, Peru) a stony meteorite formed a crater explosive type with a mean diameter of 13.5 m. some samples meteorite fragments were collected. The petrologic analysis performed corresponds to a meteorite ordinary chondrite H 4-5. In this paper we have analyzed the magnetic properties of a meteorite fragment with a proton magnetometer. Also in order to have a complete characterization of the Carancas meteorite and its crater, from several papers, articles and reports, we have made a compilation of the most important characteristics and properties of this meteorite.

  6. Magnetically Actuated Seal

    Science.gov (United States)

    Pinera, Alex

    2013-01-01

    This invention is a magnetically actuated seal in which either a single electromagnet, or multiple electromagnets, are used to control the seal's position. This system can either be an open/ close type of system or an actively controlled system.

  7. Magnetically Actuated Seal Project

    Data.gov (United States)

    National Aeronautics and Space Administration — FTT proposes development of a magnetically actuated dynamic seal. Dynamic seals are used throughout the turbopump in high-performance, pump-fed, liquid rocket...

  8. Self pumping magnetic cooling

    Science.gov (United States)

    Chaudhary, V.; Wang, Z.; Ray, A.; Sridhar, I.; Ramanujan, R. V.

    2017-01-01

    Efficient thermal management and heat recovery devices are of high technological significance for innovative energy conservation solutions. We describe a study of a self-pumping magnetic cooling device, which does not require external energy input, employing Mn-Zn ferrite nanoparticles suspended in water. The device performance depends strongly on magnetic field strength, nanoparticle content in the fluid and heat load temperature. Cooling (ΔT) by ~20 °C and ~28 °C was achieved by the application of 0.3 T magnetic field when the initial temperature of the heat load was 64 °C and 87 °C, respectively. These experiments results were in good agreement with simulations performed with COMSOL Multiphysics. Our system is a self-regulating device; as the heat load increases, the magnetization of the ferrofluid decreases; leading to an increase in the fluid velocity and consequently, faster heat transfer from the heat source to the heat sink.

  9. World Magnetic Model 2015

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The World Magnetic Model is the standard model used by the U.S. Department of Defense, the U.K. Ministry of Defence, the North Atlantic Treaty Organization (NATO)...

  10. Last PS magnet refurbished

    CERN Multimedia

    2009-01-01

    PS Magnet Refurbishment Programme Completed. The 51st and final refurbished magnet was transported to the PS on Tuesday 3 February. The repair and consolidation work on the PS started back in 2003 when two magnets and a busbar connection were found to be faulty during routine high-voltage tests. The cause of the fault was a combination of age and radiation on electrical insulation. After further investigation the decision was taken to overhaul half of the PS’s 100 magnets to reduce the risk of a similar fault. As from 20 February the PS ring will start a five-week test programme to be ready for operation at the end of March.

  11. Large Superconducting Magnet Systems

    CERN Document Server

    Védrine, P.

    2014-07-17

    The increase of energy in accelerators over the past decades has led to the design of superconducting magnets for both accelerators and the associated detectors. The use of Nb−Ti superconducting materials allows an increase in the dipole field by up to 10 T compared with the maximum field of 2 T in a conventional magnet. The field bending of the particles in the detectors and generated by the magnets can also be increased. New materials, such as Nb3Sn and high temperature superconductor (HTS) conductors, can open the way to higher fields, in the range 13–20 T. The latest generations of fusion machines producing hot plasma also use large superconducting magnet systems.

  12. Ultrafast Magnetic Light

    CERN Document Server

    Makarov, Sergey V; Krasnok, Alexander E; Belov, Pavel A

    2015-01-01

    We propose a novel concept for efficient dynamic tuning of optical properties of a high refractive index subwavelength nanoparticle with a magnetic Mie-type resonance by means of femtosecond laser radiation. This concept is based on ultrafast generation of electron-hole plasma within such nanoparticle, drastically changing its transient dielectric permittivity. This allows to manipulate by both electric and magnetic nanoparticle responses, resulting in dramatic changes of its extinction cross section and scattering diagram. Specifically, we demonstrate the effect of ultrafast switching-on a Huygens source in the vicinity of the magnetic dipole resonance. This approach enables to design ultrafast and compact optical switchers and modulators based on the "ultrafast magnetic light" concept.

  13. Magnetic interactions between nanoparticles

    DEFF Research Database (Denmark)

    Mørup, Steen; Hansen, Mikkel Fougt; Frandsen, Cathrine

    2010-01-01

    We present a short overview of the influence of inter-particle interactions on the properties of magnetic nanoparticles. Strong magnetic dipole interactions between ferromagnetic or ferrimagnetic particles, that would be superparamagnetic if isolated, can result in a collective state...... of nanoparticles. This collective state has many similarities to spin-glasses. In samples of aggregated magnetic nanoparticles, exchange interactions are often important and this can also lead to a strong suppression of superparamagnetic relaxation. The temperature dependence of the order parameter in samples...... of strongly interacting hematite nanoparticles or goethite grains is well described by a simple mean field model. Exchange interactions between nanoparticles with different orientations of the easy axes can also result in a rotation of the sub-lattice magnetization directions....

  14. Magnetic and superconducting nanowires

    DEFF Research Database (Denmark)

    Piraux, L.; Encinas, A.; Vila, L.

    2005-01-01

    magnetic and superconducting nanowires. Using different approaches entailing measurements on both single wires and arrays, numerous interesting physical properties have been identified in relation to the nanoscopic dimensions of these materials. Finally, various novel applications of the nanowires are also...

  15. 1000th magnet delivered!

    CERN Multimedia

    2006-01-01

    On Monday 20 February members of the AT Department marked the delivery of the 1000th superconducting dipole magnet to CERN. Only 232 more of the dipole magnets are needed for the LHC. The 35-tonne-dipoles are 15 meters long and are being manufactured by three companies: Babcock Noell Nuclear in Germany (which completed its contract in November 2005), Ansaldo Superconduttori in Italy and Alstom-Jeumont in France. 'The production is proceeding well and we expect to be complete in October as foreseen,' said Lucio Rossi, Head of the Magnets and Superconductors Group (AT-MAS). In total, 1650 main magnets are needed for the LHC, of which 1300 have already been delivered.

  16. 1000th magnet delivered!

    CERN Multimedia

    2006-01-01

    On Monday 20 February members of the AT Department marked the delivery of the 1000th superconducting dipole magnet to CERN. Only 232 more of the dipole magnets are needed for the LHC. The 35 tonne-dipoles are 15 meters long and are being manufactured by three companies: Babcock Noell Nuclear in Germany (which finished its contract in November 2005), Ansaldo Superconduttori in Italy and Alstom-Jeumont in France. "The production is proceeding well and we expect to be complete in October as previously foreseen," said Lucio Rossi, Head of the Magnets and Superconductors Group (AT-MAS). In total, 1650 main magnets are needed for the LHC, of which 1300 have been delivered.

  17. Magnetic Resonance Sensors

    Directory of Open Access Journals (Sweden)

    Robert H. Morris

    2014-11-01

    Full Text Available Magnetic Resonance finds countless applications, from spectroscopy to imaging, routinely in almost all research and medical institutions across the globe. It is also becoming more frequently used for specific applications in which the whole instrument and system is designed for a dedicated application. With beginnings in borehole logging for the petro-chemical industry Magnetic Resonance sensors have been applied to fields as varied as online process monitoring for food manufacture and medical point of care diagnostics. This great diversity is seeing exciting developments in magnetic resonance sensing technology published in application specific journals where they are often not seen by the wider sensor community. It is clear that there is enormous interest in magnetic resonance sensors which represents a significant growth area. The aim of this special edition of Sensors was to address the wide distribution of relevant articles by providing a forum to disseminate cutting edge research in this field in a single open source publication.[...

  18. Neutrino magnetic moment

    Energy Technology Data Exchange (ETDEWEB)

    Chang, D. (Northwestern Univ., Evanston, IL (USA). Dept. of Physics and Astronomy Fermi National Accelerator Lab., Batavia, IL (USA)); Senjanovic, G. (Zagreb Univ. (Yugoslavia). Dept. of Theoretical Physics)

    1990-01-01

    We review attempts to achieve a large neutrino magnetic moment ({mu}{sub {nu}} {le} 10{sup {minus}11}{mu}{sub B}), while keeping neutrino light or massless. The application to the solar neutrino puzzle is discussed. 24 refs.

  19. Magnetic Catalysis in Graphene

    CERN Document Server

    Winterowd, Christopher; Zafeiropoulos, Savvas

    2015-01-01

    One of the most important developments in condensed matter physics in recent years has been the discovery and characterization of graphene. A two-dimensional layer of Carbon arranged in a hexagonal lattice, graphene exhibits many interesting electronic properties, most notably that the low energy excitations behave as massless Dirac fermions. These excitations interact strongly via the Coulomb interaction and thus non-perturbative methods are necessary. Using methods borrowed from lattice QCD, we study the graphene effective theory in the presence of an external magnetic field. Graphene, along with other $(2+1)$-dimensional field theories, has been predicted to undergo spontaneous breaking of flavor symmetry including the formation of a gap as a result of the external magnetic field. This phenomenon is known as magnetic catalysis. Our study investigates magnetic catalysis using a fully non-perturbative approach.

  20. Quantum Theory of Magnetism

    CERN Document Server

    Nolting, Wolfgang

    2009-01-01

    Magnetism is one of the oldest and most fundamental problems of Solid State Physics although not being fully understood up to now. On the other hand it is one of the hottest topic of current research. Practically all branches of modern technological developments are based on ferromagnetism, especially what concerns information technology. The book, written in a tutorial style, starts from the fundamental features of atomic magnetism, discusses the essentially single-particle problems of dia- and paramagnetism, in order to provide the basis for the exclusively interesting collective magnetism (ferro, ferri, antiferro). Several types of exchange interactions, which take care under certain preconditions for a collective ordering of localized or itinerant permanent magnetic moments, are worked out. Under which conditions these exchange interactions are able to provoke a collective moment ordering for finite temperatures is investigated within a series of theoretical models, each of them considered for a very spec...

  1. ANOMALOUS MAGNETIC FILMS,

    Science.gov (United States)

    Three types of anomalous nickel-iron magnetic films characterized by hysteresigraph and torque-magnetometer measurements; bitter-pattern observations; reprint from ’ Journal of Applied Physics .’

  2. Magnetically Coupled Microcalorimeters

    Science.gov (United States)

    Bandler, S. R.; Irwin, K. D.; Kelly, D.; Nagler, P. N.; Porst, J. P.; Rotzinger, H.; Sadleir, J. E.; Seidel, G. M.; Smith, S. J.; Stevenson, T. R.

    2012-01-01

    Magnetic calorimeters have been under development for over 20 years targeting a wide variety of different applications that require very high resolution spectroscopy. They have a number of properties that distinguish them from other 10w temperature detectors. In this paper we review these properties and emphasize the types of application to which they are most suited. We will describe what has been learned about the best materials, geometries, and read-out amplifiers and our understanding of the measured performance and theoretical limits. While most magnetic calorimeter research has concentrated on the use of paramagnets to provide the temperature sensitivity, recently magnetically coupled microcalorimeters have been in development that utilize the diamagnetic response of superconductors. We will contrast some of the properties of the two different magnetic sensor types.

  3. Magnets for Pain Relief

    Science.gov (United States)

    ... better ways to prevent, diagnose, and treat diseases. Web site: www.nih.gov/health/clinicaltrials/ Key References Colbert AP, Markov MS, Souder JS. Static magnetic field therapy: dosimetry considerations. Journal of Alternative ...

  4. Magnetic vortex racetrack memory

    Science.gov (United States)

    Geng, Liwei D.; Jin, Yongmei M.

    2017-02-01

    We report a new type of racetrack memory based on current-controlled movement of magnetic vortices in magnetic nanowires with rectangular cross-section and weak perpendicular anisotropy. Data are stored through the core polarity of vortices and each vortex carries a data bit. Besides high density, non-volatility, fast data access, and low power as offered by domain wall racetrack memory, magnetic vortex racetrack memory has additional advantages of no need for constrictions to define data bits, changeable information density, adjustable current magnitude for data propagation, and versatile means of ultrafast vortex core switching. By using micromagnetic simulations, current-controlled motion of magnetic vortices in cobalt nanowire is demonstrated for racetrack memory applications.

  5. ISR Radial Field Magnet

    CERN Multimedia

    1983-01-01

    There were 37 (normal) + 3 (special) Radial Field magnets in the ISR to adjust vertically the closed orbit. Gap heights and strengths were 200 mm and .12 Tm in the normal magnets, 220 mm and .18 Tm in the special ones. The core length was 430 mm in both types. Due to their small length as compared to the gap heights the end fringe field errors were very important and had to be compensated by suitably shaping the poles. In order to save on cables, as these magnets were located very far from their power supplies, the coils of the normal type magnets were formed by many turns of solid cpper conductor with some interleaved layers of hollow conductor directly cooled by circulating water

  6. Magnetic gripper device

    Science.gov (United States)

    Meyer, Ross E.

    1993-01-01

    A climbing apparatus is provided for climbing ferromagnetic surfaces, such as storage tanks and steel frame structures. A magnet assembly is rotatably mounted in a frame assembly. The frame assembly provides a pair of cam surfaces having different dimensions so that, when the frame is rotated, the cam surfaces contact the ferromagnetic surface to separate the magnet assembly from the surface. The different cam dimensions enable one side of the magnet at a time to be detached from the surface to reduce the effort needed to disengage the climbing apparatus. The cam surface also provides for smoothly attaching the apparatus. A hardened dowel pin is also attached to the frame and the pointed end of the dowel engages the surface when the magnet is attached to the surface to prevent downward sliding movement of the assembly under the weight of the user.

  7. High field superconducting magnets

    Science.gov (United States)

    Hait, Thomas P. (Inventor); Shirron, Peter J. (Inventor)

    2011-01-01

    A superconducting magnet includes an insulating layer disposed about the surface of a mandrel; a superconducting wire wound in adjacent turns about the mandrel to form the superconducting magnet, wherein the superconducting wire is in thermal communication with the mandrel, and the superconducting magnet has a field-to-current ratio equal to or greater than 1.1 Tesla per Ampere; a thermally conductive potting material configured to fill interstices between the adjacent turns, wherein the thermally conductive potting material and the superconducting wire provide a path for dissipation of heat; and a voltage limiting device disposed across each end of the superconducting wire, wherein the voltage limiting device is configured to prevent a voltage excursion across the superconducting wire during quench of the superconducting magnet.

  8. Magnetic WKB Constructions

    Science.gov (United States)

    Bonnaillie-Noël, V.; Hérau, F.; Raymond, N.

    2016-08-01

    This paper is devoted to the semiclassical magnetic Laplacian. Until now WKB expansions for the eigenfunctions were only established in the presence of a non-zero electric potential. Here we tackle the pure magnetic case. Thanks to Feynman-Hellmann type formulas and coherent states decomposition, we develop here a magnetic Born-Oppenheimer theory. Exploiting the multiple scales of the problem, we are led to solve an effective eikonal equation in pure magnetic cases and to obtain WKB expansions.We also investigate explicit examples for which we can improve our general theorem: global WKB expansions, quasi-optimal Agmon estimates and upper bound of the tunelling effect (in symmetric cases).We also apply our strategy to get more accurate descriptions of the eigenvalues and eigenfunctions in a wide range of situations analyzed in the last two decades.

  9. World Magnetic Model 2010

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The World Magnetic Model is the standard model used by the U.S. Department of Defense, the U.K. Ministry of Defence, the North Atlantic Treaty Organization (NATO)...

  10. Magnetic Pulse Welding Technology

    Directory of Open Access Journals (Sweden)

    Ahmad K. Jassim

    2011-12-01

    Full Text Available In this paper, the benefits of using Magnetic Pulse machine which is belong to Non-conventional machine instead of conventional machine. Magnetic Pulse Technology is used for joining dissimilar metals, and for forming and cutting metals. It is a non contact technique. Magnetic field is used to generate impact magnetic pressure for welding and forming the work piece by converted the electrical energy to mechanical energy. It is enable us to design previously not possible by welding dissimilar materials and allowing to welds light and stronger materials together. It can be used to weld metallic with non metallic materials to created mechanical lock on ceramics, polymers, rubbers and composites. It is green process; there is no heat, no radiation, no gas, no smoke and sparks, therefore the emissions are negligible.

  11. Magnetic separation of algae

    Energy Technology Data Exchange (ETDEWEB)

    Nath, Pulak; Twary, Scott N.

    2016-04-26

    Described herein are methods and systems for harvesting, collecting, separating and/or dewatering algae using iron based salts combined with a magnetic field gradient to separate algae from an aqueous solution.

  12. Study of Magnetic Nanocomposites by NMR and Bulk Magnetization Techniques

    Directory of Open Access Journals (Sweden)

    Matveev V.

    2014-07-01

    Full Text Available Magnetic nanocomposites possess complex and nonuniform magnetic structure. As a result it is necessary to use different physical methods to describe their properties. In this work we have applied a combination of micro and macro approaches to understand more deeply magnetic properties of some cobaltcontaining nanocomposites. Testing of magnetic structure of the samples at molecular level was done with NMR and Mössbauer techniques whereas static (SQUID and dynamic magnetic (M2, see below measurements – at macro level.

  13. Quantization of edge currents along magnetic barriers and magnetic guides

    CERN Document Server

    Dombrowski, N; Raikov, G D

    2010-01-01

    We investigate the edge conductance of particles submitted to an Iwatsuka magnetic field, playing the role of a purely magnetic barrier. We also consider magnetic guides generated by generalized Iwatsuka potentials. In both cases we prove quantization of the edge conductance. Next, we consider magnetic perturbations of such magnetic barriers or guides, and prove stability of the quantized value of the edge conductance. Further, we establish a sum rule for edge conductances. Regularization within the context of disordered systems is discussed as well.

  14. A superconducting magnetic gear

    Science.gov (United States)

    Campbell, A. M.

    2016-05-01

    A comparison is made between a magnetic gear using permanent magnets and superconductors. The objective is to see if there are any fundamental reasons why superconducting magnets should not provide higher power densities than permanent magnets. The gear is based on the variable permeability design of Attilah and Howe (2001 IEEE Trans. Magn. 37 2844-46) in which a ring of permanent magnets surrounding a ring of permeable pole pieces with a different spacing gives an internal field component at the beat frequency. Superconductors can provide much larger fields and forces but will saturate the pole pieces. However the gear mechanism still operates, but in a different way. The magnetisation of the pole pieces is now constant but rotates with angle at the beat frequency. The result is a cylindrical Halbach array which produces an internal field with the same symmetry as in the linear regime, but has an analytic solution. In this paper a typical gear system is analysed with finite elements using FlexPDE. It is shown that the gear can work well into the saturation regime and that the Halbach array gives a good approximation to the results. Replacing the permanent magnets with superconducting tapes can give large increases in torque density, and for something like a wind turbine a combined gear and generator is possible. However there are major practical problems. Perhaps the most fundamental is the large high frequency field which is inevitably present and which will cause AC losses. Also large magnetic fields are required, with all the practical problems of high field superconducting magnets in rotating machines. Nevertheless there are ways of mitigating these difficulties and it seems worthwhile to explore the possibilities of this technology further.

  15. Explosive Turbulent Magnetic Reconnection

    OpenAIRE

    Higashimori, Katsuaki; Yokoi, Nobumitsu; Hoshino, Masahiro

    2013-01-01

    We report simulation results for turbulent magnetic reconnection obtained using a newly developed Reynolds-averaged magnetohydrodynamics model. We find that the initial Harris current sheet develops in three ways, depending on the strength of turbulence: laminar reconnection, turbulent reconnection, and turbulent diffusion. The turbulent reconnection explosively converts the magnetic field energy into both kinetic and thermal energy of plasmas, and generates open fast reconnection jets. This ...

  16. Permanent magnet design methodology

    Science.gov (United States)

    Leupold, Herbert A.

    1991-01-01

    Design techniques developed for the exploitation of high energy magnetically rigid materials such as Sm-Co and Nd-Fe-B have resulted in a revolution in kind rather than in degree in the design of a variety of electron guidance structures for ballistic and aerospace applications. Salient examples are listed. Several prototype models were developed. These structures are discussed in some detail: permanent magnet solenoids, transverse field sources, periodic structures, and very high field structures.

  17. Biofunctionalized Magnetic Nanowires

    KAUST Repository

    Kosel, Jurgen

    2013-12-19

    Magnetic nanowires can be used as an alternative method overcoming the limitations of current cancer treatments that lack specificity and are highly cytotoxic. Nanowires are developed so that they selectively attach to cancer cells via antibodies, potentially destroying them when a magnetic field induces their vibration. This will transmit a mechanical force to the targeted cells, which is expected to induce apoptosis on the cancer cells.

  18. LHC Magnet test failure

    CERN Multimedia

    2007-01-01

    "On Tueday, March 22, a Fermilab-built quadrupole magnet, one of an "inner triplet" of three focusing magnets, failed a high-pressure test at Point 5 in the tunnel of the LHC accelerator at CERN. Since Tuesday, teams at CERN and Fermilab have worked closely together to address the problem and have identified the cause of the failure. Now they are at work on a solution.:" (1 page)

  19. Hybrid Magnetics and Power Applications

    DEFF Research Database (Denmark)

    Mo, Wai Keung; Paasch, Kasper

    A hybrid magnetic approach, merging two different magnetic core properites such as ferrite and iron powder cores, is an effective solution for power converter applications. It can offer similar magnetic properties to that of magnetic powder cores but showing less copper loss than powder cores...

  20. NMR magnet technology at MIT

    Energy Technology Data Exchange (ETDEWEB)

    Williams, J.E.C.; Bobrov, E.S.; Iwasa, Y.; Punchard, W.F.B.; Wrenn, J.; Zhukovsky, A. (Massachusetts Inst. of Tech., Cambridge, MA (United States). Francis Bitter National Magnet Lab.)

    1992-01-01

    The design and construction of high field superconducting NMR magnets has much in common with other types of adiabatic superconducting magnets. However, two issues have a particular relevance to NMR magnets. They are field drift and homogeneity. In this paper the control of these factors in the particular context of high field NMR spectrometer magnets is examined.

  1. Magnetic metallic multilayers

    Energy Technology Data Exchange (ETDEWEB)

    Hood, R.Q.

    1994-04-01

    Utilizing self-consistent Hartree-Fock calculations, several aspects of multilayers and interfaces are explored: enhancement and reduction of the local magnetic moments, magnetic coupling at the interfaces, magnetic arrangements within each film and among non-neighboring films, global symmetry of the systems, frustration, orientation of the various moments with respect to an outside applied field, and magnetic-field induced transitions. Magnetoresistance of ferromagnetic-normal-metal multilayers is found by solving the Boltzmann equation. Results explain the giant negative magnetoresistance encountered in these systems when an initial antiparallel arrangement is changed into a parallel configuration by an external magnetic field. The calculation depends on (1) geometric parameters (thicknesses of layers), (2) intrinsic metal parameters (number of conduction electrons, magnetization, and effective masses in layers), (3) bulk sample properties (conductivity relaxation times), (4) interface scattering properties (diffuse scattering versus potential scattering at the interfaces, and (5) outer surface scattering properties (specular versus diffuse surface scattering). It is found that a large negative magnetoresistance requires considerable asymmetry in interface scattering for the two spin orientations. Features of the interfaces that may produce an asymmetrical spin-dependent scattering are studied: varying interfacial geometric random roughness with no lateral coherence, correlated (quasi-periodic) roughness, and varying chemical composition of the interfaces. The interplay between these aspects of the interfaces may enhance or suppress the magnetoresistance, depending on whether it increases or decreases the asymmetry in the spin-dependent scattering of the conduction electrons.

  2. Aging in Magnetic Superlattices

    Science.gov (United States)

    Mukherjee, Tathagata; Pleimling, Michel; Binek, Christian

    2010-03-01

    Aging phenomena can be observed in non-equilibrium systems with slow relaxation dynamics. Magnetic specimens with well defined interactions and dimensions can serve as model systems for universal aspects of aging. Magnetic thin films provide access to a wide range of microscopic parameters. Superlattice structures allow tuning the intra and inter-plane exchange and enable geometrical confinement of the spin fluctuations. We use Co/Cr thin film superlattices to study magnetic aging. The static and dynamic magnetic properties are affected via the Co and Cr film thicknesses. The Curie temperature of the Co films is reduced from the bulk value by geometrical confinement. Cr provides antiferromagnetic coupling between the Co films. In-plane magnetic set fields of some 10-100 mT are applied and the sample is exposed to the latter for various waiting times. After removing the field, relaxation of the magnetization is recorded via longitudinal Kerr-magnetometry and SQUID. The relaxation data are analyzed by scaling plots revealing universal aspects of aging. Financial support by NRI, and NSF through EPSCoR, Career DMR-0547887, DMR-0904999, and MRSEC.

  3. Soft magnetic wires

    Science.gov (United States)

    Vázquez, M.

    2001-06-01

    An overview of the present state of the art on the preparation techniques, outstanding magnetic properties and applications of soft magnetic micro and nanowires is presented. Rapid solidification techniques (in-rotating-water quenching and drawing methods) to fabricate amorphous microwires with diameter in the range from 100 down to 1 μm are first described. Electrodeposition is also employed to prepare composite microtubes (magnetic coatings) and to fill porous membranes (diameter of the order of 0.1 μm). Magnetic behaviours of interest are related to the different hysteresis loops of samples: square-shaped loops typical of bistable behaviour, and nearly non-hysteretic loop with well-defined transverse anisotropy field. The role played by magnetic dipolar interactions in the magnetic behaviour of arrays of micro and nanowires is described. A particular analysis is done on the giant magnetoimpedance (GMI) effect in the radio and microwave frequency ranges exhibited by ultrasoft microwires. Finally, a few examples of applications are introduced for magnetostrictive and non-magnetostrictive wires, they are: “magnetoelastic pens”, micromotors; DC current-sensors based on GMI, and sharpened amorphous wire tips in spin polarised scanning tunneling microscopy.

  4. Magnetic anisotropy in nanostructures

    CERN Document Server

    Eisenbach, M

    2001-01-01

    method for solving the LDA Kohn-Sham equation. This extended code allows us to perform fully relativistic calculations to enable us to investigate the spin orbit coupling effects leading to anisotropies and potentially non collinear ordering of magnetic moments in these systems of magnetic inclusions in copper. With this approach we find that depending on the orientation of the atoms along the 100 or 110 direction in copper the ground state orientation of the magnetic moments in the chain is either perpendicular or parallel to the chain direction, when the magnetic dipolar interaction energy is added to the final ab initio result. In this thesis we investigate the effect of magnetic anisotropies in nanostructured materials. The main emphasis in our work presented here is on systems that have an underlying one dimensional structure, like nanowires or atomic chains. In a simple classical one dimensional model we show the rich ground state structure of magnetic orientations one might expect to find in such syste...

  5. Magnetic flux concentration methods for magnetic energy harvesting module

    Directory of Open Access Journals (Sweden)

    Wakiwaka Hiroyuki

    2013-01-01

    Full Text Available This paper presents magnetic flux concentration methods for magnetic energy harvesting module. The purpose of this study is to harvest 1 mW energy with a Brooks coil 2 cm in diameter from environmental magnetic field at 60 Hz. Because the harvesting power is proportional to the square of the magnetic flux density, we consider the use of a magnetic flux concentration coil and a magnetic core. The magnetic flux concentration coil consists of an air­core Brooks coil and a resonant capacitor. When a uniform magnetic field crossed the coil, the magnetic flux distribution around the coil was changed. It is found that the magnetic field in an area is concentrated larger than 20 times compared with the uniform magnetic field. Compared with the air­core coil, our designed magnetic core makes the harvested energy ten­fold. According to ICNIRP2010 guideline, the acceptable level of magnetic field is 0.2 mT in the frequency range between 25 Hz and 400 Hz. Without the two magnetic flux concentration methods, the corresponding energy is limited to 1 µW. In contrast, our experimental results successfully demonstrate energy harvesting of 1 mW from a magnetic field of 0.03 mT at 60 Hz.

  6. Interaction between two magnetic dipoles in a uniform magnetic field

    Directory of Open Access Journals (Sweden)

    J. G. Ku

    2016-02-01

    Full Text Available A new formula for the interaction force between two magnetic dipoles in a uniform magnetic field is derived taking their mutual magnetic interaction into consideration and used to simulate their relative motion. Results show that when the angle β between the direction of external magnetic field and the centerline of two magnetic dipoles is 0 ° or 90 °, magnetic dipoles approach each other or move away from each other in a straight line, respectively. And the time required for them to contact each other from the initial position is related to the specific susceptibility and the diameter of magnetic particles, medium viscosity and magnetic field strength. When β is between 0 ° and 90 °, magnetic dipole pair performs approximate elliptical motion, and the motion trajectory is affected by the specific susceptibility, diameter and medium viscosity but not magnetic field strength. However, time required for magnetic dipoles to complete the same motion trajectory is shorter when adopting stronger magnetic field. Moreover, the subsequent motion trajectory of magnetic dipoles is ascertained once the initial position is set in a predetermined motion trajectory. Additionally, magnetic potential energy of magnetic dipole pairs is transformed into kinetic energy and friction energy during the motion.

  7. MAGNETIC NEUTRON SCATTERING

    Energy Technology Data Exchange (ETDEWEB)

    ZALIZNYAK,I.A.; LEE,S.H.

    2004-07-30

    Much of our understanding of the atomic-scale magnetic structure and the dynamical properties of solids and liquids was gained from neutron-scattering studies. Elastic and inelastic neutron spectroscopy provided physicists with an unprecedented, detailed access to spin structures, magnetic-excitation spectra, soft-modes and critical dynamics at magnetic-phase transitions, which is unrivaled by other experimental techniques. Because the neutron has no electric charge, it is an ideal weakly interacting and highly penetrating probe of matter's inner structure and dynamics. Unlike techniques using photon electric fields or charged particles (e.g., electrons, muons) that significantly modify the local electronic environment, neutron spectroscopy allows determination of a material's intrinsic, unperturbed physical properties. The method is not sensitive to extraneous charges, electric fields, and the imperfection of surface layers. Because the neutron is a highly penetrating and non-destructive probe, neutron spectroscopy can probe the microscopic properties of bulk materials (not just their surface layers) and study samples embedded in complex environments, such as cryostats, magnets, and pressure cells, which are essential for understanding the physical origins of magnetic phenomena. Neutron scattering is arguably the most powerful and versatile experimental tool for studying the microscopic properties of the magnetic materials. The magnitude of the cross-section of the neutron magnetic scattering is similar to the cross-section of nuclear scattering by short-range nuclear forces, and is large enough to provide measurable scattering by the ordered magnetic structures and electron spin fluctuations. In the half-a-century or so that has passed since neutron beams with sufficient intensity for scattering applications became available with the advent of the nuclear reactors, they have became indispensable tools for studying a variety of important areas of modern

  8. MAGNETIC NEUTRON SCATTERING

    Energy Technology Data Exchange (ETDEWEB)

    ZALIZNYAK,I.A.; LEE,S.H.

    2004-07-30

    Much of our understanding of the atomic-scale magnetic structure and the dynamical properties of solids and liquids was gained from neutron-scattering studies. Elastic and inelastic neutron spectroscopy provided physicists with an unprecedented, detailed access to spin structures, magnetic-excitation spectra, soft-modes and critical dynamics at magnetic-phase transitions, which is unrivaled by other experimental techniques. Because the neutron has no electric charge, it is an ideal weakly interacting and highly penetrating probe of matter's inner structure and dynamics. Unlike techniques using photon electric fields or charged particles (e.g., electrons, muons) that significantly modify the local electronic environment, neutron spectroscopy allows determination of a material's intrinsic, unperturbed physical properties. The method is not sensitive to extraneous charges, electric fields, and the imperfection of surface layers. Because the neutron is a highly penetrating and non-destructive probe, neutron spectroscopy can probe the microscopic properties of bulk materials (not just their surface layers) and study samples embedded in complex environments, such as cryostats, magnets, and pressure cells, which are essential for understanding the physical origins of magnetic phenomena. Neutron scattering is arguably the most powerful and versatile experimental tool for studying the microscopic properties of the magnetic materials. The magnitude of the cross-section of the neutron magnetic scattering is similar to the cross-section of nuclear scattering by short-range nuclear forces, and is large enough to provide measurable scattering by the ordered magnetic structures and electron spin fluctuations. In the half-a-century or so that has passed since neutron beams with sufficient intensity for scattering applications became available with the advent of the nuclear reactors, they have became indispensable tools for studying a variety of important areas of modern

  9. Planet migration and magnetic torques

    Science.gov (United States)

    Strugarek, A.; Brun, A. S.; Matt, S. P.; Reville, V.

    2016-10-01

    The possibility that magnetic torques may participate in close-in planet migration has recently been postulated. We develop three dimensional global models of magnetic star-planet interaction under the ideal magnetohydrodynamic (MHD) approximation to explore the impact of magnetic topology on the development of magnetic torques. We conduct twin numerical experiments in which only the magnetic topology of the interaction is altered. We find that magnetic torques can vary by roughly an order of magnitude when varying the magnetic topology from an aligned case to an anti-aligned case. Provided that the stellar magnetic field is strong enough, we find that magnetic migration time scales can be as fast as ~100 Myr. Hence, our model supports the idea that magnetic torques may participate in planet migration for some close-in star-planet systems.

  10. Magnetic separation in microfluidic systems

    DEFF Research Database (Denmark)

    Smistrup, Kristian

    2007-01-01

    This Ph.D. thesis presents theory, modeling, design, fabrication, experiments and results for microfluidic magnetic separators. A model for magnetic bead movement in a microfluidic channel is presented, and the limits of the model are discussed. The effective magnetic field gradient is defined...... for fabrication of silicon based systems. This fabrication scheme is explained, and it is shown how, it is applied with variations for several designs of magnetic separators. An experimental setup for magnetic separation experiments has been developed. It has been coupled with an image analysis program....... It is shown conceptually how such a system can be applied for parallel biochemical processing in a microfluidic system. ’Passive’ magnetic separators are presented, where on-chip soft magnetic elements are magnetized by an external magnetic field and create strong magnetic fields and gradients inside...

  11. Study of Magnetic Domain Dynamics Using Nonlinear Magnetic Responses: Magnetic Diagnostics of the Itinerant Magnet MnP

    Science.gov (United States)

    Mito, Masaki; Matsui, Hideaki; Tsuruta, Kazuki; Deguchi, Hiroyuki; Kishine, Jun-ichiro; Inoue, Katsuya; Kousaka, Yusuke; Yano, Shin-ichiro; Nakao, Yuya; Akimitsu, Jun

    2015-10-01

    The nonlinear and linear magnetic responses to an ac magnetic field H are useful for the study of the magnetic dynamics of both magnetic domains and their constituent spins. In particular, the third-harmonic magnetic response M3ω reflects the dynamics of magnetic domains. Furthermore, by considering the ac magnetic response as a function of H, we can evaluate the degree of magnetic nonlinearity, which is closely related to M3ω. In this study, a series of approaches was used to examine the itinerant magnet MnP, in which both ferromagnetic and helical phases are present. On the basis of this investigation, we systematize the diagnostic approach to evaluating nonlinearity in magnetic responses.

  12. Lodestone: Nature's own permanent magnet

    Science.gov (United States)

    Wasilewski, P.

    1976-01-01

    Magnetic hysteresis and microstructural details are presented which explain why the class of magnetic iron ores defined as proto-lodestones, can behave as permanent magnets, i.e. lodestones. Certain of these proto-lodestones which are not permanent magnets can be made into permanent magnets by charging in a field greater than 1000 oersted. This fact, other experimental observations, and field evidence from antiquity and the middle ages, which seems to indicate that lodestones are found as localized patches within massive ore bodies, suggests that lightning might be responsible for the charging of lodestones. The large remanent magnetization, high values of coercive force, and good time stability for the remanent magnetization are all characteristics of proto-lodestone iron ores which behave magnetically as fine scale ( 10 micrometer) intergrowths when subjected to magnetic hysteresis analysis. The magnetic results are easily understood by analysis of the complex proto lodestone microstructural patterns observable at the micrometer scale and less.

  13. Handbook of Advanced Magnetic Materials

    CERN Document Server

    Liu, Yi; Shindo, Daisuke

    2006-01-01

    From high-capacity, inexpensive hard drives to mag-lev trains, recent achievements in magnetic materials research have made the dreams of a few decades ago reality. The objective of Handbook of Advanced Magnetic Materials is to provide a timely, comprehensive review of recent progress in magnetic materials research. This broad yet detailed reference consists of four volumes: 1.) Nanostructured advanced magnetic materials, 2.) Characterization and simulation of advanced magnetic materials, 3.) Processing of advanced magnetic materials, and 4.) Properties and applications of advanced magnetic materials The first volume documents and explains recent development of nanostructured magnetic materials, emphasizing size effects. The second volume provides a comprehensive review of both experimental methods and simulation techniques for the characterization of magnetic materials. The third volume comprehensively reviews recent developments in the processing and manufacturing of advanced magnetic materials. With the co...

  14. Negative magnetic relaxation in superconductors

    Directory of Open Access Journals (Sweden)

    Krasnoperov E.P.

    2013-01-01

    Full Text Available It was observed that the trapped magnetic moment of HTS tablets or annuli increases in time (negative relaxation if they are not completely magnetized by a pulsed magnetic field. It is shown, in the framework of the Bean critical-state model, that the radial temperature gradient appearing in tablets or annuli during a pulsed field magnetization can explain the negative magnetic relaxation in the superconductor.

  15. Magnetic cooling at Risoe DTU

    OpenAIRE

    Nielsen, Kaspar Kirstein; Bjørk, Rasmus; Jensen, Jesper Buch; Bahl, Christian Robert Haffenden; Pryds, Nini; Smith, Anders; Nordentoft, Anders; Hattel, Jesper Henri

    2009-01-01

    Magnetic refrigeration at room temperature is of great interest due to a long-term goal of making refrigeration more energy-efficient, less noisy and free of any environmentally hostile materials. A refrigerator utilizing an active magnetic regenerator (AMR) is based on the magnetocaloric effect, which manifests itself as a temperature change in magnetic materials when subjected to a varying magnetic field. In this work we present the current state of magnetic refrigeration research at Risoe ...

  16. EDITORIAL: Ultrafast magnetization processes

    Science.gov (United States)

    Hillebrands, Burkard

    2008-09-01

    This Cluster Issue of Journal of Physics D: Applied Physics is devoted to ultrafast magnetization processes. It reports on the scientific yield of the Priority Programme 1133 'Ultrafast Magnetization Processes' which was funded by the Deutsche Forschungsgemeinschaft in the period 2002-2008 in three successive two-year funding periods, supporting research of 17-18 groups in Germany. Now, at the end of this Priority Programme, the members feel that the achievements made in the course of the programme merit communication to the international scientific community in a concerted way. Therefore, each of the projects of the last funding period presents a key result in a published contribution to this Cluster Issue. The purpose of the funding by a Priority Programme is to advance knowledge in an emerging field of research through collaborative networked support over several locations. Priority Programmes are characterized by their enhanced quality of research through the use of new methods and forms of collaboration in emerging fields, by added value through interdisciplinary cooperation, and by networking. The aim of the Priority Programme 1133 'Ultrafast Magnetization Processes' may be well characterized by the call for projects in June 2001 after the programme was approved by the Deutsche Forschungsgemeinschaft: 'The aim of the priority programme is the achievement of a basic understanding of the temporal evolution of fast magnetization processes in magnetically ordered films, multilayers and micro-structured systems. The challenge lies in the advancement of the field of ultrafast magnetization processes into the regime of a few femtoseconds to nanoseconds, a topic not yet well explored. A general aim is to understand the fundamental mechanisms needed for applications in ultrafast magneto-electronic devices. The fundamental topic to be addressed is the response of the magnetization of small structures upon the application of pulsed magnetic fields, laser pulses or

  17. Magnetic Nanocomposite Cilia Sensors

    KAUST Repository

    Alfadhel, Ahmed

    2016-07-19

    Recent progress in the development of artificial skin concepts is a result of the increased demand for providing environment perception such as touch and flow sensing to robots, prosthetics and surgical tools. Tactile sensors are the essential components of artificial skins and attracted considerable attention that led to the development of different technologies for mimicking the complex sense of touch in humans. This dissertation work is devoted to the development of a bioinspired tactile sensing technology that imitates the extremely sensitive hair-like cilia receptors found in nature. The artificial cilia are fabricated from permanent magnetic, biocompatible and highly elastic nanocomposite material, and integrated on a giant magneto-impedance magnetic sensor to measure the stray field. A force that bends the cilia changes the stray field and is therefore detected with the magnetic sensor, providing high performance in terms of sensitivity, power consumption and versatility. The nanocomposite is made of Fe nanowires (NWs) incorporated into polydimethylsiloxane (PDMS). Fe NWs have a high remanent magnetization, due the shape anisotropy; thus, they are acting as permanent nano-magnets. This allows remote device operation and avoids the need for a magnetic field to magnetize the NWs, benefiting miniaturization and the possible range of applications. The magnetic properties of the nanocomposite can be easily tuned by modifying the NWs concentration or by aligning the NWs to define a magnetic anisotropy. Tactile sensors are realized on flexible and rigid substrates that can detect flow, vertical and shear forces statically and dynamically, with a high resolution and wide operating range. The advantage to operate the sensors in liquids and air has been utilized to measure flows in different fluids in a microfluidic channel. Various dynamic studies were conducted with the tactile sensor demonstrating the detection of moving objects or the texture of objects. Overall

  18. Laccase-conjugated amino-functionalized nanosilica for efficient degradation of Reactive Violet 1 dye

    Science.gov (United States)

    Gahlout, Mayur; Rudakiya, Darshan M.; Gupte, Shilpa; Gupte, Akshaya

    2017-08-01

    Immobilization of enzyme with nanostructures enhances its ideal characteristics, which may allow the enzyme to become more stable and resistant. The present investigation deals with the formulation of laccase nanosilica conjugates to overcome the problems associated with its stability and reusability. Synthesized nanosilica and laccase nanoparticles were spherical shaped, with the mean size of 220 and 615 nm, respectively. Laccase nanoparticles had an optimum temperature of 55 °C and pH 4.0 for the oxidation of ABTS. Laccase nanoparticle retained 79% of residual activity till 20th cycle. It also showed 91% of its initial activity at lower temperatures even after 60 days. Laccase nanoparticles were applied for Reactive Violet 1 degradation wherein 96.76% of decolourization was obtained at pH 5.0 and 30 °C within 12 h. Toxicity studies on microbes and plants suggested that the degraded metabolites were less toxic than control dye. Thus, the method applied for immobilization increased storage stability and reusability of laccase, and therefore, it can be utilized for efficient degradation of azo dyes.

  19. Biodistribution of amino-functionalized diamond nanoparticles. In vivo studies based on 18F radionuclide emission.

    Science.gov (United States)

    Rojas, Santiago; Gispert, Juan D; Martín, Roberto; Abad, Sergio; Menchón, Cristina; Pareto, Deborah; Víctor, Víctor M; Alvaro, Mercedes; García, Hermenegildo; Herance, J Raúl

    2011-07-26

    Nanoparticles have been proposed for several biomedical applications; however, in vivo biodistribution studies to confirm their potential are scarce. Nanodiamonds are carbon nanoparticles that have been recently proposed as a promising biomaterial. In this study, we labeled nanodiamonds with (18)F to study their in vivo biodistribution by positron emission tomography. Moreover, the impact on the biodistribution of their kinetic particle size and of the surfactant agents has been evaluated. Radiolabeled diamond nanoparticles accumulated mainly in the lung, spleen, and liver and were excreted into the urinary tract. The addition of surfactant agents did not lead to significant changes in this pattern, with the exception of a slight reduction in the urinary excretion rate. On the other hand, after filtration of the radiolabeled diamond nanoparticles to remove those with a larger kinetic size, the uptake in the lung and spleen was completely inhibited and significantly reduced in the liver.

  20. β-Amino functionalization of cinnamic Weinreb amides in ionic liquid

    Directory of Open Access Journals (Sweden)

    Yi-Ning Wang

    2016-11-01

    Full Text Available 2-Ns-Protected β-amino Weinreb amides were synthesized by aminochlorination of α,β-unsaturated Weinreb amides in an ionic liquid, 1-n-butyl-3-methylimidazolium bis(trifluoromethanesulfonylimide ([BMIM][NTf2]. Processed without the use of metal catalysts or the need of an inert gas atmosphere, the presented process can be readily performed as a one-pot synthesis at room temperature. Moreover, the preparation has the distinct advantages of the use of 2-NsNCl2 as an inexpensive and stable nitrogen/halogen source and the ionic liquid as a recyclable reaction media. Nine examples were examined, and modest to good isolated chemical yields (40–83% were obtained.

  1. SYNTHESIS AND CHARACTERIZATION OF AMINO FUNCTIONALIZED LADDER-LIKE POLYSILSESQUIOXANES AND THEIR HYBRID FILMS WITH POLYIMIDE

    Institute of Scientific and Technical Information of China (English)

    Qiu-shuang Gao; Guo-feng Tian; Sheng-li Qi; Zhan-peng Wu; De-zhen Wu

    2013-01-01

    Ladder-like polysilsesquioxanes (LPSQs) with different amino contents have been synthesized by controlling of the dosage of Pd/C catalyst.The concentration and activity of amino groups were investigated by Fourier transform infrared spectroscopy.Polyimide (PI)/LPSQ hybrid films have been prepared by incorporating of the obtained LPSQs with different amino contents into PI matrix,respectively.The interfacial interactions between PI matrix and LPSQ were studied with scanning electron microscopy and X-ray photoelectron spectroscopy,meanwhile the thermal and mechanical properties of the hybrid films were studied using dynamic mechanical analysis and tensile tests.The results indicate that the functionality of LPSQ has great effects on the interfacial interactions and the properties of hybrid films.With the increase of amino content,both the interracial interactions and the cross-linking density of hybrids enhanced,which results in the decline of surface silicon concentration,increase of Young's modulus and drop of elongation at break.Excessive amino content makes the hybrid films brittle and leads to incomplete imidization.

  2. Amino-functionalized metal-organic frameworks as tunable heterogeneous basic catalysts

    Energy Technology Data Exchange (ETDEWEB)

    Fischer, M.; Hartmann, M. [Erlangen-Nuernberg Univ., Erlangen (Germany). Erlangen Catalysis Resource Center

    2011-07-01

    Metal-organic framework (MOF) materials have been explored for applications in heterogeneous catalysis in recent years. In addition to the use of MOFs as supports for the deposition of highly dispersed metal particles, the incorporation of active centers such as coordinatively unsaturated metal sites and the functionalization of the organic linkers with acidic or basic groups seems to be most promising. In our contribution, three different MOFs carrying amino groups at their organic linkers, namely Fe-MIL-101-NH{sub 2} (S{sub BET} = 3438 m{sup 2}g{sup -1}), Al-MIL-101-NH{sub 2} (S{sub BET} = 3099 m{sup 2}g{sup -1}) and CAU-1 (S{sub BET} = 1492 m{sup 2}g{sup -1}), were synthesized and tested in the Knoevenagel condensation of benzaldehyde with malononitrile and with ethyl cyanoacetate, respectively. It is shown that the expected products benzylidenemalononitrile (BzMN) and ethyl a-cyanocinnamate (EtCC) are formed with selectivities of more than 99 % and yields of 90 to 95 % after 3 h (for BzMN). Due to the very small pore windows of CAU-1 (0.3 to 0.4 nm) the reaction proceeds much slower over this catalyst in comparison to the amino-MIL-101 derivatives, which possess open pore windows of up to 1.6 nm. Finally, leaching tests confirm that the reaction is heterogeneously catalyzed. Moreover, the catalysts are recyclable without significant loss of activity. (orig.)

  3. Magnetically textured ferrofluid in a non-magnetic matrix: Magnetic properties

    Indian Academy of Sciences (India)

    Mrudul Gadhvi; R V Upadhyay; Kinnari Parekh; R V Mehta

    2004-04-01

    Texturing of two different magnetic fluids were carried out in paraffin wax under the influence of an external magnetic field. The textured samples were characterized using magnetization measurement and a.c. susceptibility techniques. The results are discussed in the light of ratio of anisotropic energy to magnetic and thermal energies.

  4. Design Study Of Cyclotron Magnet With Permanent Magnet

    Science.gov (United States)

    Kim, Hyun Wook; Chai, Jong Seo

    2011-06-01

    Low energy cyclotrons for Positron emission tomography (PET) have been wanted for the production of radio-isotopes after 2002. In the low energy cyclotron magnet design, increase of magnetic field between the poles is needed to make a smaller size of magnet and decrease power consumption. The Permanent magnet can support this work without additional electric power consumption in the cyclotron. In this paper the study of cyclotron magnet design using permanent magnet is shown and also the comparison between normal magnet and the magnet which is designed with permanent magnet is shown. Maximum energy of proton is 8 MeV and RF frequency is 79.3 MHz. 3D CAD design was done by CATIA P3 V5 R18 [1] and the All field calculations had been performed by OPERA-3D TOSCA [2]. The self-made beam dynamics program OPTICY [3] is used for making isochronous field and other calculations.

  5. Solar Magnetic Flux Ropes

    Indian Academy of Sciences (India)

    Boris Filippov; Olesya Martsenyuk; Abhishek K. Srivastava; Wahab Uddin

    2015-03-01

    In the early 1990s, it was found that the strongest disturbances of the space–weather were associated with huge ejections of plasma from the solar corona, which took the form of magnetic clouds when moved from the Sun. It is the collisions of the magnetic clouds with the Earth's magnetosphere that lead to strong, sometimes catastrophic changes in space–weather. The onset of a coronal mass ejection (CME) is sudden and no reliable forerunners of CMEs have been found till date. The CME prediction methodologies are less developed compared to the methods developed for the prediction of solar flares. The most probable initial magnetic configuration of a CME is a flux rope consisting of twisted field lines which fill the whole volume of a dark coronal cavity. The flux ropes can be in stable equilibrium in the coronal magnetic field for weeks and even months, but suddenly they lose their stability and erupt with high speed. Their transition to the unstable phase depends on the parameters of the flux rope (i.e., total electric current, twist, mass loading, etc.), as well as on the properties of the ambient coronal magnetic field. One of the major governing factors is the vertical gradient of the coronal magnetic field, which is estimated as decay index (). Cold dense prominence material can be collected in the lower parts of the helical flux tubes. Filaments are, therefore, good tracers of the flux ropes in the corona, which become visible long before the beginning of the eruption. The perspectives of the filament eruptions and following CMEs can be estimated by a comparison of observed filament heights with calculated decay index distributions. The present paper reviews the formation of magnetic flux ropes, their stable and unstable phases, eruption conditions, and also discusses their physical implications in the solar corona.

  6. Rigidly connected magnetic lines: twisting and winding of magnetic lines

    Science.gov (United States)

    Prasad, G.

    2017-10-01

    The dynamical process of magnetic flux variation in a fluid's stream tube is described by constructing 1+1+ (2) decomposition of the gradient of fluid's 4-velocity. The necessary and sufficient conditions are obtained for a spacelike congruence to be a congruence of rigidly connected spacelike curves. The evolution of magnetic flux in a magnetic tube is explored under the assumptions that magnetic lines are rigidly connected and the chemical potential of the fluid is constant along a magnetic tube. The interplay between magnetic and stream tubes is demonstrated. It is shown that the growth of magnetic energy in a magnetic tube cannot exceed to that of a stream tube. It is found that the proper time variation of twist of magnetic lines is caused by gravitation inside a neutron star if magnetic lines are rigidly connected and charge neutrality condition holds. Helmholtz-like magnetic vorticity flux conservation in a magnetic tube constituted by rigidly connected geodetic magnetic lines is derived under the assumption that the charge neutrality condition holds. It is shown that the winding of frozen-in poloidal magnetic field due to differential rotation requires meridional circulation in an axisymmetric stationary hydromagnetic configuration.

  7. Dynamic interaction between rotor and axially-magnetized passive magnetic bearing considering magnetic eccentricity

    DEFF Research Database (Denmark)

    Enemark, Søren; Santos, Ilmar

    2014-01-01

    Passive magnetic bearings are known due to the excellent characteristics in terms of friction and no requirement of additional energy sources to work. However, passive magnetic bearings do not provide damping, are not stable and, depending on their design, may also introduce magnetic eccentricity....... Such magnetic eccentricities are generated by discrepancies in magnet fabrication. In this framework the main focus of the work is the theoretical as well as experimental investigation of the nonlinear dynamics of a rotor-bearing system with strong emphasis on the magnetic eccentricities and non......-linear stiffness. In this investigation passive magnetic bearings using axially- aligned neodymium cylinder magnets are investigated. The cylinder magnets are axially magnetised for rotor as well as bearings. Compared to bearings with radial magnetisation, the magnetic stiffness of axially-aligned bearings...

  8. Influence of magnetic domain walls and magnetic field on the thermal conductivity of magnetic nanowires.

    Science.gov (United States)

    Huang, Hao-Ting; Lai, Mei-Feng; Hou, Yun-Fang; Wei, Zung-Hang

    2015-05-13

    We investigated the influence of magnetic domain walls and magnetic fields on the thermal conductivity of suspended magnetic nanowires. The thermal conductivity of the nanowires was obtained using steady-state Joule heating to measure the change in resistance caused by spontaneous heating. The results showed that the thermal conductivity coefficients of straight and wavy magnetic nanowires decreased with an increase in the magnetic domain wall number, implying that the scattering between magnons and domain walls hindered the heat transport process. In addition, we proved that the magnetic field considerably reduced the thermal conductivity of a magnetic nanowire. The influence of magnetic domain walls and magnetic fields on the thermal conductivity of polycrystalline magnetic nanowires can be attributed to the scattering of long-wavelength spin waves mediated by intergrain exchange coupling.

  9. Performance of repulsive type magnetic bearing system under nonuniform magnetization of permanent magnet

    OpenAIRE

    Ohji, T.; Mukhopadhyay, S. C.; Iwahara, Masayoshi; Yamada, Sotoshi

    2000-01-01

    Permanent magnet bearing system utilizes the repulsive forces between the stator and rotor permanent magnets (PM) for the levitation of the system and it results a simplified axial control scheme. A repulsive type magnetic bearing system based on the above principle was fabricated in our laboratory. Material characteristics and the configuration of the permanent magnets are the central component for this type of bearing system. Due to aging or as both the magnets are repelling each other, the...

  10. Forces Between a Permanent Magnet and a Soft Magnetic Plate

    DEFF Research Database (Denmark)

    Beleggia, Marco; Vokoun, David; De Graef, Marc

    2012-01-01

    Forces between a hard/permanent magnet of arbitrary shape and an ideally soft magnetic plate in close proximity are derived analytically from the image method applied to magnetostatics. We found that the contact force, defined as the force required to detach the hard magnet from the plate......, coincides with that between two identical touching permanent magnets. Furthermore, if the hard and the soft magnets are displaced by some amount, their attraction equals that between two identical permanent magnets displaced by twice that amount. Experimental results are presented that validate...

  11. Comparing superconducting and permanent magnets for magnetic refrigeration

    DEFF Research Database (Denmark)

    Bjørk, Rasmus; Nielsen, Kaspar Kirstein; Bahl, C. R. H.

    2016-01-01

    We compare the cost of a high temperature superconducting (SC) tape-based solenoidwith a permanent magnet (PM) Halbach cylinder for magnetic refrigeration.Assuming a five liter active magnetic regenerator volume, the price of each type ofmagnet is determined as a function of aspect ratio of the r......We compare the cost of a high temperature superconducting (SC) tape-based solenoidwith a permanent magnet (PM) Halbach cylinder for magnetic refrigeration.Assuming a five liter active magnetic regenerator volume, the price of each type ofmagnet is determined as a function of aspect ratio...

  12. AA quadrupole magnet

    CERN Multimedia

    1980-01-01

    Focusing magnet used for the AA (antiproton accumulator).Making an antiproton beam took a lot of time and effort. Firstly, protons were accelerated to an energy of 26 GeV in the PS and ejected onto a metal target. From the spray of emerging particles, a magnetic horn picked out 3.6 GeV antiprotons for injection into the AA through a wide-aperture focusing quadrupole magnet. For a million protons hitting the target, just one antiproton was captured, 'cooled' and accumulated. It took 3 days to make a beam of 3 x 10^11 - three hundred thousand million - antiprotons. About focusing magnets (quadrupoles): Quadrupole magnets are needed to focus the particle beams and squeeze them so that more particles collide when the beams cross. Particle beams are stored for about 10 hours in the LHC. During this time, the particles make four hundred million revolutions around the machine, travelling a distance equivalent to the diameter of the solar system.

  13. Turbulent General Magnetic Reconnection

    CERN Document Server

    Eyink, Gregory L

    2014-01-01

    Plasma flows with an MHD-like turbulent inertial range, such as the solar wind, require a generalization of General Magnetic Reconnection (GMR) theory. We introduce the slip-velocity source vector, which gives the rate of development of slip velocity per unit arc length of field line. The slip source vector is the ratio of the curl of the non ideal electric field in the Generalized Ohm's Law and the magnetic field strength. It diverges at magnetic nulls, unifying GMR with magnetic null-point reconnection. Only under restrictive assumptions is the slip velocity related to the gradient of the quasi potential (integral of parallel electric field along field lines). In a turbulent inertial range the curl becomes extremely large while the parallel component is tiny, so that line slippage occurs even while ideal MHD becomes accurate. The resolution of this paradox is that ideal MHD is valid for a turbulent inertial-range only in a weak sense which does not imply magnetic line freezing. The notion of weak solution i...

  14. Magnetically Coupled Calorimeters

    Science.gov (United States)

    Bandler, Simon

    2011-01-01

    Calorimeters that utilize the temperature sensitivity of magnetism have been under development for over 20 years. They have targeted a variety of different applications that require very high resolution spectroscopy. I will describe the properties of this sensor technology that distinguish it from other low temperature detectors and emphasize the types of application to which they appear best suited. I will review what has been learned so far about the best materials, geometries, and read-out amplifiers and our understanding of the measured performance and theoretical limits. I will introduce some of the applications where magnetic calorimeters are being used and also where they are in development for future experiments. So far, most magnetic calorimeter research has concentrated on the use of paramagnets to provide temperature sensitivity; recent studies have also focused on magnetically coupled calorimeters that utilize the diamagnetic response of superconductors. I will present some of the highlights of this research, and contrast the properties of the two magnetically coupled calorimeter types.

  15. Extraterrestrial magnetic minerals

    Science.gov (United States)

    Pechersky, D. M.; Markov, G. P.; Tsel'movich, V. A.; Sharonova, Z. V.

    2012-07-01

    Thermomagnetic and microprobe analyses are carried out and a set of magnetic characteristics are measured for 25 meteorites and 3 tektites from the collections of the Vernadsky Geological Museum of the Russian Academy of Sciences and Museum of Natural History of the North-East Interdisciplinary Science Research Institute, Far Eastern Branch of the Russian Academy of Sciences. It is found that, notwithstanding their type, all the meteorites contain the same magnetic minerals and only differ by concentrations of these minerals. Kamacite with less than 10% nickel is the main magnetic mineral in the studied samples. Pure iron, taenite, and schreibersite are less frequent; nickel, various iron spinels, Fe-Al alloys, etc., are very rare. These minerals are normally absent in the crusts of the Earth and other planets. The studied meteorites are more likely parts of the cores and lower mantles of the meteoritic parent bodies (the planets). Uniformity in the magnetic properties of the meteorites and the types of their thermomagnetic (MT) curves is violated by secondary alterations of the meteorites in the terrestrial environment. The sediments demonstrate the same monotony as the meteorites: kamacite is likely the only extraterrestrial magnetic mineral, which is abundant in sediments and associated with cosmic dust. The compositional similarity of kamacite in iron meteorites and in cosmic dust is due to their common source; the degree of fragmentation of the material of the parent body is the only difference.

  16. Magnetic binary nanofillers

    Energy Technology Data Exchange (ETDEWEB)

    Morales Mendoza, N. [INQUIMAE, CONICET-UBA, Ciudad Universitaria, Pab2, (C1428EHA) Bs As (Argentina); LPyMC, Dep. De Fisica, FCEN-UBA and IFIBA -CONICET, Ciudad Universitaria, Cap. Fed. (Argentina); Goyanes, S. [LPyMC, Dep. De Fisica, FCEN-UBA and IFIBA -CONICET, Ciudad Universitaria, Cap. Fed. (Argentina); Chiliotte, C.; Bekeris, V. [LBT, Dep. De Fisica, FCEN-UBA. Ciudad Universitaria, Pab1, C1428EGA CABA (Argentina); Rubiolo, G. [LPyMC, Dep. De Fisica, FCEN-UBA and IFIBA -CONICET, Ciudad Universitaria, Cap. Fed. (Argentina); Unidad de Actividad Materiales, CNEA, Av Gral. Paz 1499, San Martin (1650), Prov. de Bs As (Argentina); Candal, R., E-mail: candal@qi.fcen.uba.ar [INQUIMAE, CONICET-UBA, Ciudad Universitaria, Pab2, (C1428EHA) Bs As (Argentina); Escuela de Ciencia y Tecnologia, 3iA, Universidad de Gral. San Martin, San Martin, Prov. Bs As (Argentina)

    2012-08-15

    Magnetic binary nanofillers containing multiwall carbon nanotubes (MWCNT) and hercynite were synthesized by Chemical Vapor Deposition (CVD) on Fe/AlOOH prepared by the sol-gel method. The catalyst precursor was fired at 450 Degree-Sign C, ground and sifted through different meshes. Two powders were obtained with different particle sizes: sample A (50-75 {mu}m) and sample B (smaller than 50 {mu}m). These powders are composed of iron oxide particles widely dispersed in the non-crystalline matrix of aluminum oxide and they are not ferromagnetic. After reduction process the powders are composed of {alpha}-Fe nanoparticles inside hercynite matrix. These nanofillers are composed of hercynite containing {alpha}-Fe nanoparticles and MWCNT. The binary magnetic nanofillers were slightly ferromagnetic. The saturation magnetization of the nanofillers depended on the powder particle size. The nanofiller obtained from powder particles in the range 50-75 {mu}m showed a saturation magnetization 36% higher than the one formed from powder particles smaller than 50 {mu}m. The phenomenon is explained in terms of changes in the magnetic environment of the particles as consequence of the presence of MWCNT.

  17. Magnetoacoustic Sensing of Magnetic Nanoparticles.

    Science.gov (United States)

    Kellnberger, Stephan; Rosenthal, Amir; Myklatun, Ahne; Westmeyer, Gil G; Sergiadis, George; Ntziachristos, Vasilis

    2016-03-11

    The interaction of magnetic nanoparticles and electromagnetic fields can be determined through electrical signal induction in coils due to magnetization. However, the direct measurement of instant electromagnetic energy absorption by magnetic nanoparticles, as it relates to particle characterization or magnetic hyperthermia studies, has not been possible so far. We introduce the theory of magnetoacoustics, predicting the existence of second harmonic pressure waves from magnetic nanoparticles due to energy absorption from continuously modulated alternating magnetic fields. We then describe the first magnetoacoustic system reported, based on a fiber-interferometer pressure detector, necessary for avoiding electric interference. The magnetoacoustic system confirmed the existence of previously unobserved second harmonic magnetoacoustic responses from solids, magnetic nanoparticles, and nanoparticle-loaded cells, exposed to continuous wave magnetic fields at different frequencies. We discuss how magnetoacoustic signals can be employed as a nanoparticle or magnetic field sensor for biomedical and environmental applications.

  18. Replacement reactor to revolutionise magnets

    CERN Document Server

    Atkins, G

    2002-01-01

    Electric motors, hearing aids and magnetic resonance imaging are only some of the applications that will benefit from the first advances in magnets in a quarter of a century. Magnets achieve their characteristics when electrons align themselves to produce a unified magnetic field. Neutrons can probe these magnetic structures. The focus is not just on making more powerful magnets, but also identifying the characteristics that make magnets cheaper and easier for industry to manufacture. Staff from the ANSTO's Neutron Scattering Group have already performed a number of studies on the properties of magnets using using HIFAR, but the Replacement Research Reactor that will produce cold neutrons would allow scientists to investigate the atomic properties of materials with large molecules. A suite of equipment will enable studies at different temperatures, pressures and magnetic fields

  19. Magnetic Reconnection in Astrophysical Environments

    CERN Document Server

    Lazarian, A; Vishniac, E; Kowal, G

    2014-01-01

    Magnetic reconnection is a process that changes magnetic field topology in highly conducting fluids. Traditionally, magnetic reconnection was associated mostly with solar flares. In reality, the process must be ubiquitous as astrophysical fluids are magnetized and motions of fluid elements necessarily entail crossing of magnetic frozen in field lines and magnetic reconnection. We consider magnetic reconnection in realistic 3D geometry in the presence of turbulence. This turbulence in most astrophysical settings is of pre-existing nature, but it also can be induced by magnetic reconnection itself. In this situation turbulent magnetic field wandering opens up reconnection outflow regions, making reconnection fast. We discuss Lazarian \\& Vishniac (1999) model of turbulent reconnection, its numerical and observational testings, as well as its connection to the modern understanding of the Lagrangian properties of turbulent fluids. We show that the predicted dependences of the reconnection rates on the level of...

  20. Magnetic digital microfluidics - a review.

    Science.gov (United States)

    Zhang, Yi; Nguyen, Nam-Trung

    2017-03-14

    A digital microfluidic platform manipulates droplets on an open surface. Magnetic digital microfluidics utilizes magnetic forces for actuation and offers unique advantages compared to other digital microfluidic platforms. First, the magnetic particles used in magnetic digital microfluidics have multiple functions. In addition to serving as actuators, they also provide a functional solid substrate for molecule binding, which enables a wide range of applications in molecular diagnostics and immunodiagnostics. Second, magnetic digital microfluidics can be manually operated in a "power-free" manner, which allows for operation in low-resource environments for point-of-care diagnostics where even batteries are considered a luxury item. This review covers research areas related to magnetic digital microfluidics. This paper first summarizes the current development of magnetic digital microfluidics. Various methods of droplet manipulation using magnetic forces are discussed, ranging from conventional magnetic particle-based actuation to the recent development of ferrofluids and magnetic liquid marbles. This paper also discusses several new approaches that use magnetically controlled flexible substrates for droplet manipulation. In addition, we emphasize applications of magnetic digital microfluidics in biosensing and medical diagnostics, and identify the current limitations of magnetic digital microfluidics. We provide a perspective on possible solutions to close these gaps. Finally, the paper discusses the future improvement of magnetic digital microfluidics to explore potential new research directions.

  1. Obtaining Magnetic Properties of Meteorites Using Magnetic Scanner

    Science.gov (United States)

    Kletetschka, G.; Nabelek, L.; Mazanec, M.; Simon, K.; Hruba, J.

    2015-12-01

    Magnetic images of Murchison meteorite's and Chelyabinsk meteorite's thin section have been obtained from magnetic scanning system from Youngwood Science and Engineering (YSE) capable of resolving magnetic anomalies down to 10-3 mT range from about 0.3 mm distance between the probe and meteorite surface (resolution about 0.15 mm). Anomalies were produced repeatedly, each time after application of magnetic field pulse of varying amplitude and constant, normal or reversed, direction. This process resulted in both magnetizing and demagnetizing of the meteorite thin section, while keeping the magnetization vector in the plane of the thin section. Analysis of the magnetic data allows determination of coercivity of remanence (Bcr) for the magnetic sources in situ. Value of Bcr is critical for calculating magnetic forces applicable during missions to asteroids where gravity is compromised. Bcr was estimated by two methods. First method measured varying dipole magnetic field strength produced by each anomaly in the direction of magnetic pulses. Second method measured deflections of the dipole direction from the direction of magnetic pulses (Nabelek et al., 2015). Nabelek, L., Mazanec, M., Kdyr, S., and Kletetschka, G., 2015, Magnetic, in situ, mineral characterization of Chelyabinsk meteorite thin section: Meteoritics & Planetary Science.

  2. New ALPHA-2 magnet

    CERN Multimedia

    Anaïs Schaeffer

    2012-01-01

    On 21 June, members of the ALPHA collaboration celebrated the handover of the first solenoid designed for the ALPHA-2 experiment. The magnet has since been successfully installed and is working well.   Khalid Mansoor, Sumera Yamin and Jeffrey Hangst in front of the new ALPHA-2 solenoid. “This was the first of three identical solenoids that will be installed between now and September, as the rest of the ALPHA-2 device is installed and commissioned,” explains ALPHA spokesperson Jeffrey Hangst. “These magnets are designed to allow us to transfer particles - antiprotons, electrons and positrons - between various parts of the new ALPHA-2 device by controlling the transverse size of the particle bunch that is being transferred.” Sumera Yamin and Khalid Mansoor, two Pakistani scientists from the National Centre for Physics in Islamabad, came to CERN in February specifically to design and manufacture these magnets. “We had the chance to work on act...

  3. Cosmic magnetic fields

    CERN Document Server

    Kronberg, Philipp P

    2016-01-01

    Magnetic fields are important in the Universe and their effects contain the key to many astrophysical phenomena that are otherwise impossible to understand. This book presents an up-to-date overview of this fast-growing topic and its interconnections to plasma processes, astroparticle physics, high energy astrophysics, and cosmic evolution. The phenomenology and impact of magnetic fields are described in diverse astrophysical contexts within the Universe, from galaxies to the filaments and voids of the intergalactic medium, and out to the largest redshifts. The presentation of mathematical formulae is accessible and is designed to add insight into the broad range of topics discussed. Written for graduate students and researchers in astrophysics and related disciplines, this volume will inspire readers to devise new ways of thinking about magnetic fields in space on galaxy scales and beyond.

  4. Skyrmions in magnetic materials

    CERN Document Server

    Seki, Shinichiro

    2016-01-01

    This brief reviews current research on magnetic skyrmions, with emphasis on formation mechanisms, observation techniques, and materials design strategies. The response of skyrmions, both static and dynamical, to various electromagnetic fields is also covered in detail. Recent progress in magnetic imaging techniques has enabled the observation of skyrmions in real space, as well as the analysis of their ordering manner and the details of their internal structure. In metallic systems, conduction electrons moving through the skyrmion spin texture gain a nontrivial quantum Berry phase, which provides topological force to the underlying spin texture and enables the current-induced manipulation of magnetic skyrmions. On the other hand, skyrmions in an insulator can induce electric polarization through relativistic spin-orbit interaction, paving the way for the control of skyrmions by an external electric field without loss of Joule heating. Because of its nanometric scale, particle nature, and electric controllabil...

  5. Magnetic hyperbolic optical metamaterials.

    Science.gov (United States)

    Kruk, Sergey S; Wong, Zi Jing; Pshenay-Severin, Ekaterina; O'Brien, Kevin; Neshev, Dragomir N; Kivshar, Yuri S; Zhang, Xiang

    2016-04-13

    Strongly anisotropic media where the principal components of electric permittivity or magnetic permeability tensors have opposite signs are termed as hyperbolic media. Such media support propagating electromagnetic waves with extremely large wave vectors exhibiting unique optical properties. However, in all artificial and natural optical materials studied to date, the hyperbolic dispersion originates solely from the electric response. This restricts material functionality to one polarization of light and inhibits free-space impedance matching. Such restrictions can be overcome in media having components of opposite signs for both electric and magnetic tensors. Here we present the experimental demonstration of the magnetic hyperbolic dispersion in three-dimensional metamaterials. We measure metamaterial isofrequency contours and reveal the topological phase transition between the elliptic and hyperbolic dispersion. In the hyperbolic regime, we demonstrate the strong enhancement of thermal emission, which becomes directional, coherent and polarized. Our findings show the possibilities for realizing efficient impedance-matched hyperbolic media for unpolarized light.

  6. Rock and mineral magnetism

    CERN Document Server

    O’Reilly, W

    1984-01-01

    The past two decades have witnessed a revolution in the earth sciences. The quantitative, instrument-based measurements and physical models of. geophysics, together with advances in technology, have radically transformed the way in which the Earth, and especially its crust, is described. The study of the magnetism of the rocks of the Earth's crust has played a major part in this transformation. Rocks, or more specifically their constituent magnetic minerals, can be regarded as a measuring instrument provided by nature, which can be employed in the service of the earth sciences. Thus magnetic minerals are a recording magnetometer; a goniometer or protractor, recording the directions of flows, fields and forces; a clock; a recording thermometer; a position recorder; astrain gauge; an instrument for geo­ logical surveying; a tracer in climatology and hydrology; a tool in petrology. No instrument is linear, or free from noise and systematic errors, and the performance of nature's instrument must be assessed and ...

  7. Perspectives on magnetic reconnection

    Science.gov (United States)

    Yamada, Masaaki

    2016-01-01

    Magnetic reconnection is a topological rearrangement of magnetic field that occurs on time scales much faster than the global magnetic diffusion time. Since the field lines break on microscopic scales but energy is stored and the field is driven on macroscopic scales, reconnection is an inherently multi-scale process that often involves both magnetohydrodynamic (MHD) and kinetic phenomena. In this article, we begin with the MHD point of view and then describe the dynamics and energetics of reconnection using a two-fluid formulation. We also focus on the respective roles of global and local processes and how they are coupled. We conclude that the triggers for reconnection are mostly global, that the key energy conversion and dissipation processes are either local or global, and that the presence of a continuum of scales coupled from microscopic to macroscopic may be the most likely path to fast reconnection. PMID:28119547

  8. A Magnetic Consistency Relation

    CERN Document Server

    Jain, Rajeev Kumar

    2012-01-01

    If cosmic magnetic fields are indeed produced during inflation, they are likely to be correlated with the scalar metric perturbations that are responsible for the Cosmic Microwave Background anisotropies and Large Scale Structure. Within an archetypical model of inflationary magnetogenesis, we show that there exists a new simple consistency relation for the non-Gaussian cross correlation function of the scalar metric perturbation with two powers of the magnetic field in the squeezed limit where the momentum of the metric perturbation vanishes. We emphasize that such a consistency relation turns out to be extremely useful to test some recent calculations in the literature. Apart from primordial non-Gaussianity induced by the curvature perturbations, such a cross correlation might provide a new observational probe of inflation and can in principle reveal the primordial nature of cosmic magnetic fields.

  9. Magnetic hyperbolic optical metamaterials

    CERN Document Server

    Kruk, Sergey S; Pshenay-Severin, Ekaterina; O'Brien, Kevin; Neshev, Dragomir N; Kivshar, Yuri S; Zhang, Xiang

    2015-01-01

    Strongly anisotropic media where the principal components of the electric permittivity and/or magnetic permeability tensor have opposite signs are termed as hyperbolic media. Such media support propagating electromagnetic waves with extremely large wavevectors, and therefore they exhibit unique optical properties. However in all artificial and natural optical structures studied to date the hyperbolic dispersion originates solely from their electric response. This restricts functionality of these materials for only one polarization of light and inhibits impedance matching with free space. Such restrictions can be overcome in media having components of opposite signs in both electric and magnetic tensors. Here we present the first experimental demonstration of the magnetic hyperbolic dispersion in three-dimensional metamaterials. We measure experimentally metamaterial's dispersion and trace the topological transition between the elliptic and hyperbolic regimes. We experimentally demonstrate that due to the uniq...

  10. Cardiovascular Magnetic Resonance Imaging

    Science.gov (United States)

    Pelc, Norbert

    2000-03-01

    Cardiovascular diseases are a major source of morbidity and mortality in the United States. Early detection of disease can often be used to improved outcomes, either through direct interventions (e.g. surgical corrections) or by causing the patient to modify his or her behavior (e.g. smoking cessation or dietary changes). Ideally, the detection process should be noninvasive (i.e. it should not be associated with significant risk). Magnetic Resonance Imaging (MRI) refers to the formation of images by localizing NMR signals, typically from protons in the body. As in other applications of NMR, a homogeneous static magnetic field ( ~0.5 to 4 T) is used to create ``longitudinal" magnetization. A magnetic field rotating at the Larmor frequency (proportional to the static field) excites spins, converting longitudinal magnetization to ``transverse" magnetization and generating a signal. Localization is performed using pulsed gradients in the static field. MRI can produce images of 2-D slices, 3-D volumes, time-resolved images of pseudo-periodic phenomena such as heart function, and even real-time imaging. It is also possible to acquire spatially localized NMR spectra. MRI has a number of advantages, but perhaps the most fundamental is the richness of the contrast mechanisms. Tissues can be differentiated by differences in proton density, NMR properties, and even flow or motion. We also have the ability to introduce substances that alter NMR signals. These contrast agents can be used to enhance vascular structures and measure perfusion. Cardiovascular MRI allows the reliable diagnosis of important conditions. It is possible to image the blood vessel tree, quantitate flow and perfusion, and image cardiac contraction. Fundamentally, the power of MRI as a diagnostic tool stems from the richness of the contrast mechanisms and the flexibility in control of imaging parameters.

  11. Magnetism in curved geometries

    Science.gov (United States)

    Streubel, Robert; Fischer, Peter; Kronast, Florian; Kravchuk, Volodymyr P.; Sheka, Denis D.; Gaididei, Yuri; Schmidt, Oliver G.; Makarov, Denys

    2016-09-01

    Extending planar two-dimensional structures into the three-dimensional space has become a general trend in multiple disciplines, including electronics, photonics, plasmonics and magnetics. This approach provides means to modify conventional or to launch novel functionalities by tailoring the geometry of an object, e.g. its local curvature. In a generic electronic system, curvature results in the appearance of scalar and vector geometric potentials inducing anisotropic and chiral effects. In the specific case of magnetism, even in the simplest case of a curved anisotropic Heisenberg magnet, the curvilinear geometry manifests two exchange-driven interactions, namely effective anisotropy and antisymmetric exchange, i.e. Dzyaloshinskii-Moriya-like interaction. As a consequence, a family of novel curvature-driven effects emerges, which includes magnetochiral effects and topologically induced magnetization patterning, resulting in theoretically predicted unlimited domain wall velocities, chirality symmetry breaking and Cherenkov-like effects for magnons. The broad range of altered physical properties makes these curved architectures appealing in view of fundamental research on e.g. skyrmionic systems, magnonic crystals or exotic spin configurations. In addition to these rich physics, the application potential of three-dimensionally shaped objects is currently being explored as magnetic field sensorics for magnetofluidic applications, spin-wave filters, advanced magneto-encephalography devices for diagnosis of epilepsy or for energy-efficient racetrack memory devices. These recent developments ranging from theoretical predictions over fabrication of three-dimensionally curved magnetic thin films, hollow cylinders or wires, to their characterization using integral means as well as the development of advanced tomography approaches are in the focus of this review.

  12. Magnet management in electric machines

    Energy Technology Data Exchange (ETDEWEB)

    Reddy, Patel Bhageerath; El-Refaie, Ayman Mohamed Fawzi; Huh, Kum Kang

    2017-03-21

    A magnet management method of controlling a ferrite-type permanent magnet electrical machine includes receiving and/or estimating the temperature permanent magnets; determining if that temperature is below a predetermined temperature; and if so, then: selectively heating the magnets in order to prevent demagnetization and/or derating the machine. A similar method provides for controlling magnetization level by analyzing flux or magnetization level. Controllers that employ various methods are disclosed. The present invention has been described in terms of specific embodiment(s), and it is recognized that equivalents, alternatives, and modifications, aside from those expressly stated, are possible and within the scope of the appending claims.

  13. DC Magnetics Measurement System Design

    Science.gov (United States)

    Mastny, Timothy

    2012-01-01

    This report will detail the updates to the magnetics measurement system design and testing procedures that are required for performing static (DC) magnetics testing of future flight hardware. An older magnetics testing system had to be integrated with new procedures and hardware to meet the demands of future testing programs and accommodate an upcoming magnetics tests. The next test will be for the Geostationary Operational Environmental Satellite R-Series (GOES-R), which will verify that the SAFT Battery component meets its specifications for magnetic cleanliness. The satellite is scheduled to launch in 2015 with magnetics testing to be completed on the battery in November 2012.

  14. Uniform excitations in magnetic nanoparticles

    DEFF Research Database (Denmark)

    Mørup, Steen; Frandsen, Cathrine; Hansen, Mikkel Fougt

    2010-01-01

    We present a short review of the magnetic excitations in nanoparticles below the superparamagnetic blocking temperature. In this temperature regime, the magnetic dynamics in nanoparticles is dominated by uniform excitations, and this leads to a linear temperature dependence of the magnetization...... and the magnetic hyperfine field, in contrast to the Bloch T3/2 law in bulk materials. The temperature dependence of the average magnetization is conveniently studied by Mössbauer spectroscopy. The energy of the uniform excitations of magnetic nanoparticles can be studied by inelastic neutron scattering....

  15. Uniform excitations in magnetic nanoparticles

    DEFF Research Database (Denmark)

    Mørup, Steen; Frandsen, Cathrine; Hansen, Mikkel Fougt

    2010-01-01

    We present a short review of the magnetic excitations in nanoparticles below the superparamagnetic blocking temperature. In this temperature regime, the magnetic dynamics in nanoparticles is dominated by uniform excitations, and this leads to a linear temperature dependence of the magnetization...... and the magnetic hyperfine field, in contrast to the Bloch T3/2 law in bulk materials. The temperature dependence of the average magnetization is conveniently studied by Mössbauer spectroscopy. The energy of the uniform excitations of magnetic nanoparticles can be studied by inelastic neutron scattering....

  16. Magnetic fields in diffuse media

    CERN Document Server

    Pino, Elisabete; Melioli, Claudio

    2015-01-01

    This volume presents the current knowledge of magnetic fields in diffuse astrophysical media. Starting with an overview of 21st century instrumentation to observe astrophysical magnetic fields, the chapters cover observational techniques, origin of magnetic fields, magnetic turbulence, basic processes in magnetized fluids, the role of magnetic fields for cosmic rays, in the interstellar medium and for star formation. Written by a group of leading experts the book represents an excellent overview of the field. Nonspecialists will find sufficient background to enter the field and be able to appreciate the state of the art.

  17. Magnet management in electric machines

    Science.gov (United States)

    Reddy, Patel Bhageerath; El-Refaie, Ayman Mohamed Fawzi; Huh, Kum Kang

    2017-03-21

    A magnet management method of controlling a ferrite-type permanent magnet electrical machine includes receiving and/or estimating the temperature permanent magnets; determining if that temperature is below a predetermined temperature; and if so, then: selectively heating the magnets in order to prevent demagnetization and/or derating the machine. A similar method provides for controlling magnetization level by analyzing flux or magnetization level. Controllers that employ various methods are disclosed. The present invention has been described in terms of specific embodiment(s), and it is recognized that equivalents, alternatives, and modifications, aside from those expressly stated, are possible and within the scope of the appending claims.

  18. Superconductivity for Magnets

    CERN Document Server

    Flükiger, R

    2014-01-01

    The present state of development of a series of industrial superconductors is reviewed in consideration of their future applications in high field accelerator magnets, with particular attention on the material aspect. The discussion is centred on Nb3Sn and MgB2, which are industrially available in a round wire configuration in kilometre lengths and are already envisaged for use in the LHC Upgrade (HL-LHC). The two systems Bi-2212 and R.E.123 may be used in magnets with even higher fields in future accelerators: they are briefly described.

  19. Explosive turbulent magnetic reconnection.

    Science.gov (United States)

    Higashimori, K; Yokoi, N; Hoshino, M

    2013-06-21

    We report simulation results for turbulent magnetic reconnection obtained using a newly developed Reynolds-averaged magnetohydrodynamics model. We find that the initial Harris current sheet develops in three ways, depending on the strength of turbulence: laminar reconnection, turbulent reconnection, and turbulent diffusion. The turbulent reconnection explosively converts the magnetic field energy into both kinetic and thermal energy of plasmas, and generates open fast reconnection jets. This fast turbulent reconnection is achieved by the localization of turbulent diffusion. Additionally, localized structure forms through the interaction of the mean field and turbulence.

  20. Solar Magnetic Fields

    Indian Academy of Sciences (India)

    J. O. Stenflo

    2008-03-01

    Since the structuring and variability of the Sun and other stars are governed by magnetic fields, much of present-day stellar physics centers around the measurement and understanding of the magnetic fields and their interactions. The Sun, being a prototypical star, plays a unique role in astrophysics, since its proximity allows the fundamental processes to be explored in detail. The PRL anniversary gives us an opportunity to look back at past milestones and try to identify the main unsolved issues that will be addressed in the future.

  1. Nonlinear magnetic metamaterials.

    Science.gov (United States)

    Shadrivov, Ilya V; Kozyrev, Alexander B; van der Weide, Daniel W; Kivshar, Yuri S

    2008-12-08

    We study experimentally nonlinear tunable magnetic metamaterials operating at microwave frequencies. We fabricate the nonlinear metamaterial composed of double split-ring resonators where a varactor diode is introduced into each resonator so that the magnetic resonance can be tuned dynamically by varying the input power. We demonstrate that at higher powers the transmission of the metamaterial becomes power-dependent and, as a result, such metamaterial can demonstrate various nonlinear properties. In particular, we study experimentally the power-dependent shift of the transmission band and demonstrate nonlinearity-induced enhancement (or suppression) of wave transmission. (c) 2008 Optical Society of America

  2. Ultrasonic magnetic abrasive finishing

    Institute of Scientific and Technical Information of China (English)

    LU Ya-ping; MA Ji; ZHANG Jun-qiang; WANG Long-shan

    2006-01-01

    Put forward a new kind of polishing method, ultrasonic magnetic abrasive finishing (UMAF), and studied its mechanism of improving polishing efficiency. By analyzing all kind of forces acting on single abrasive particle in the polishing process and calculating the size of the composition of forces, get the conclusion that UMAF will enhance the efficiency of the normal magnetic abrasive finishing(MAF) due to the ultrasonic vibration increases the cutting force and depth. At last the idea of designing the UMAF system based on numerical control milling machine is put forward which is convenient to setup and will accelerate the practical application of MAF.

  3. Magnetism in layered Ruthenates

    Energy Technology Data Exchange (ETDEWEB)

    Steffens, Paul C.

    2008-07-01

    In this thesis, the magnetism of the layered Ruthenates has been studied by means of different neutron scattering techniques. Magnetic correlations in the single-layer Ruthenates of the series Ca{sub 2-x}Sr{sub x}RuO{sub 4} have been investigated as function of Sr-concentration (x=0.2 and 0.62), temperature and magnetic field. These inelastic neutron scattering studies demonstrate the coexistence of ferromagnetic paramagnon scattering with antiferromagnetic fluctuations at incommensurate wave vectors. The temperature dependence of the amplitudes and energies of both types of excitations indicate the proximity to magnetic instabilities; their competition seems to determine the complex behavior of these materials. In Ca{sub 1.8}Sr{sub 0.2}RuO{sub 4}, which shows a metamagnetic transition, the ferromagnetic fluctuations are strongly suppressed at low temperature, but appear at higher temperature or application of a magnetic field. In the high-field phase of Ca{sub 1.8}Sr{sub 0.2}RuO{sub 4} above the metamagnetic transition, a ferromagnetic magnon dominates the excitation spectrum. Polarized neutron scattering revealed the existence of a very broad signal around the zone centre, in addition to the well-known incommensurate excitations at Q=(0.3,0.3,0) in the unconventional superconductor Sr{sub 2}RuO{sub 4}. With this additional contribution, it is possible to set up a general model for the Q-dependent magnetic susceptibility, which is well consistent with the results of other measurement methods that do not resolve the Q-dependence. Upon doping with Ti, the incommensurate fluctuations are enhanced, in particular near the critical concentration for the onset of magnetic order, but no divergence down to very low temperature is observed. In the bilayer Ti-doped Ca{sub 3}Ru{sub 2}O{sub 7}, the existence of magnetic order with a propagation vector of about ((1)/(4),(1)/(4),0) has been discovered and characterized in detail. Above and below T{sub N}, excitations at this

  4. Magnetically Damped Furnace (MDF)

    Science.gov (United States)

    1998-01-01

    The Magnetically Damped Furnace (MDF) breadboard is being developed in response to NASA's mission and goals to advance the scientific knowledge of microgravity research, materials science, and related technologies. The objective of the MDF is to dampen the fluid flows due to density gradients and surface tension gradients in conductive melts by introducing a magnetic field during the sample processing. The MDF breadboard will serve as a proof of concept that the MDF performance requirements can be attained within the International Space Station resource constraints.

  5. On Magnetized Neutron Stars

    CERN Document Server

    Lopes, Luiz L

    2014-01-01

    In this work we review the formalism normally used in the literature about the effects of density-dependent magnetic fields on the properties of neutron stars, expose some ambiguities that arise and propose a way to solve the related problem. Our approach uses a different prescription for the calculation of the pressure based on the chaotic field formalism for the stress tensor and also a different way of introducing a variable magnetic field, which depends on the energy density rather than on the baryonic density.

  6. Controlling magnetism with multiferroics

    Directory of Open Access Journals (Sweden)

    Ying-Hao Chu

    2007-10-01

    Full Text Available Multiferroics, materials combining multiple order parameters, offer an exciting way of coupling phenomena such as electronic and magnetic order. Using epitaxial growth and heteroepitaxy, researchers have grown high-quality thin films and heterostructures of the multiferroic BiFeO3. The ferroelectric and antiferromagnetic domain structure and coupling between these two order parameters in BiFeO3 is now being studied. We describe the evolution of our understanding of the connection between structure, properties, and new functionalities (including electrical control of magnetism using BiFeO3 as a model system.

  7. Materials chemistry: A magnetic facelift for non-magnetic metals

    Science.gov (United States)

    Raman, Karthik V.; Moodera, Jagadeesh S.

    2015-08-01

    Copper and manganese have been engineered to show magnetism at room temperature in thin films interfaced with organic molecules. The findings show promise for developing new magnetic materials. See Letter p.69

  8. Magnetic Helicity and Large Scale Magnetic Fields: A Primer

    CERN Document Server

    Blackman, Eric G

    2014-01-01

    Magnetic fields of laboratory, planetary, stellar, and galactic plasmas commonly exhibit significant order on large temporal or spatial scales compared to the otherwise random motions within the hosting system. Such ordered fields can be measured in the case of planets, stars, and galaxies, or inferred indirectly by the action of their dynamical influence, such as jets. Whether large scale fields are amplified in situ or a remnant from previous stages of an object's history is often debated for objects without a definitive magnetic activity cycle. Magnetic helicity, a measure of twist and linkage of magnetic field lines, is a unifying tool for understanding large scale field evolution for both mechanisms of origin. Its importance stems from its two basic properties: (1) magnetic helicity is typically better conserved than magnetic energy; and (2) the magnetic energy associated with a fixed amount of magnetic helicity is minimized when the system relaxes this helical structure to the largest scale available. H...

  9. Magnetic Force Between Magnetic Nano Probes at Optical Frequency

    CERN Document Server

    Guclu, Caner; Capolino, Filippo

    2014-01-01

    Magnetic force microscopy based on the interaction of static magnetic materials was demonstrated in the past with resolutions in the order of nanometers. Measurement techniques based on forces between electric dipoles oscillating at optical frequencies have been also demonstrated leading to the standard operation of the scanning force microscope (SFM). However the investigations of a SFM based on the magnetic force generated by magnetic dipole moments oscillating at optical frequencies has not been tackled yet. With this goal in mind we establish a theoretical model towards observable magnetic force interaction between two magnetically polarizable nanoparticles at optical frequency and show such a force to be in the order of piconewtons which could be in principle detected by conventional microscopy techniques. Two possible principles for conceiving magnetically polarizable nano probes able to generate strong magnetic dipoles at optical frequency are investigated based on silicon nanoparticles and on clusters...

  10. Mechanics of magnetic fluid column in strong magnetic fields

    Science.gov (United States)

    Polunin, V. M.; Ryapolov, P. A.; Platonov, V. B.

    2017-06-01

    Elastic-and magnetic properties of magnetic fluid confined by ponderomotive force in a tube fixed in horizontal position are considered. The system is placed in a strong magnetic field under the influence of external static and dynamic perturbations. An experimental setup has been developed. A theoretical basis of the processes of magnetic colloid elastic deformation has been proposed. The values of the static ponderomotive elasticity coefficient and the elasticity coefficient under dynamic action are experimentally determined. The calculations of the saturation magnetization for two magnetic fluid samples, carried out according to the equation containing the dynamic elasticity coefficient, are in good agreement with the experimental magnetization curve. The described method is of interest when studying magnetophoresis and aggregation of nanoparticles in magnetic colloids.

  11. Magnetic microfluidic platform for biomedical applications using magnetic nanoparticles

    KAUST Repository

    Stipsitz, Martin

    2015-05-01

    Microfluidic platforms are well-suited for biomedical analysis and usually consist of a set of units which guarantee the manipulation, detection and recognition of bioanalyte in a reliable and flexible manner. Additionally, the use of magnetic fields for perfoming the aforementioned tasks has been steadily gainining interest. This is due to the fact that magnetic fields can be well tuned and applied either externally or from a directly integrated solution in the diagnostic system. In combination with these applied magnetic fields, magnetic nanoparticles are used. In this paper, we present some of our most recent results in research towards a) microfluidic diagnostics using MR sensors and magnetic particles and b) single cell analysis using magnetic particles. We have successfully manipulated magnetically labeled bacteria and measured their response with integrated GMR sensors and we have also managed to separate magnetically labeled jurkat cells for single cell analysis. © 2015 Trans Tech Publications, Switzerland.

  12. Magnetic Microparticle Aggregation For Viscosity Determination By Magnetic Resonance

    Science.gov (United States)

    Hong, Rui; Cima, Michael J.; Weissleder, Ralph; Josephson, Lee

    2009-01-01

    Micron-sized magnetic particles were induced to aggregate when placed in homogeneous magnetic fields, like those of magnetic resonance (MR) imagers and relaxometers, and then spontaneously returned to their dispersed state when removed from the field. Associated with the aggregation and dispersion of the magnetic particles were time dependent increases and decreases in the spin-spin relaxation time (T2) of the water. Magnetic nanoparticles, with far smaller magnetic moments per particle, did not undergo magnetically induced aggregation, and exhibited time independent values of T2. The rate of T2 change associated with magnetic micro-particle aggregation was used to determine the viscosity of liquid samples, providing a method that can be of particular advantage for determining the viscosity of small volumes of potentially biohazardous samples of blood or blood plasma. PMID:18306403

  13. Magnetic Properties of Magnetic Nanoparticles for Efficient Hyperthermia

    Directory of Open Access Journals (Sweden)

    Ihab M. Obaidat

    2015-01-01

    Full Text Available Localized magnetic hyperthermia using magnetic nanoparticles (MNPs under the application of small magnetic fields is a promising tool for treating small or deep-seated tumors. For this method to be applicable, the amount of MNPs used should be minimized. Hence, it is essential to enhance the power dissipation or heating efficiency of MNPs. Several factors influence the heating efficiency of MNPs, such as the amplitude and frequency of the applied magnetic field and the structural and magnetic properties of MNPs. We discuss some of the physics principles for effective heating of MNPs focusing on the role of surface anisotropy, interface exchange anisotropy and dipolar interactions. Basic magnetic properties of MNPs such as their superparamagnetic behavior, are briefly reviewed. The influence of temperature on anisotropy and magnetization of MNPs is discussed. Recent development in self-regulated hyperthermia is briefly discussed. Some physical and practical limitations of using MNPs in magnetic hyperthermia are also briefly discussed.

  14. Plasma-induced magnetic responses during nonlinear dynamics of magnetic islands due to resonant magnetic perturbations

    Energy Technology Data Exchange (ETDEWEB)

    Nishimura, Seiya, E-mail: n-seiya@kobe-kosen.ac.jp [Kobe City College of Technology, Kobe, Hyogo 651-2194 (Japan)

    2014-12-15

    Resonant magnetic perturbations (RMPs) produce magnetic islands in toroidal plasmas. Self-healing (annihilation) of RMP-induced magnetic islands has been observed in helical systems, where a possible mechanism of the self-healing is shielding of RMP penetration by plasma flows, which is well known in tokamaks. Thus, fundamental physics of RMP shielding is commonly investigated in both tokamaks and helical systems. In order to check this mechanism, detailed informations of magnetic island phases are necessary. In experiments, measurement of radial magnetic responses is relatively easy. In this study, based on a theoretical model of rotating magnetic islands, behavior of radial magnetic fields during the self-healing is investigated. It is confirmed that flips of radial magnetic fields are typically observed during the self-healing. Such behavior of radial magnetic responses is also observed in LHD experiments.

  15. Three-dimensional magnetic reconnection through a moving magnetic null

    OpenAIRE

    Lukin, V. S.; Linton, M. G.

    2011-01-01

    A computational study of three-dimensional magnetic reconnection between two flux ropes through a moving reconnection site is presented. The configuration is considered in the context of two interacting spheromaks constrained by a perfectly conducting cylindrical boundary and oriented to form a single magnetic field null at its center. The initial magnetic field configuration is embedded into a uniform thermal plasma and is unstable to tilting. As the spheromaks tilt, their magnetic fi...

  16. Magnetic activity at Mars - Mars Surface Magnetic Observatory

    DEFF Research Database (Denmark)

    Vennerstrøm, Susanne; Menvielle, M.; Merayo, José M.G.

    2012-01-01

    We use the extensive database of magnetic observations from the Mars Global Surveyor to investigate magnetic disturbances in the Martian space environment statistically, both close to and far from crustal anomalies. We discuss the results in terms of possible ionospheric and magnetospheric currents...... a magnetic experiment at the martian surface, the Mars Surface Magnetic Observatory (MSMO) including the science objectives, science experiment requirements, instrument and basic operations. We find the experiment to be feasible within the constraints of proposed stationary landing platforms....

  17. Repulsive Magnetic Levitation Systems Using Motion Control of Magnets

    OpenAIRE

    水野, 毅; 石野, 裕二; 荒木, 獻次; 大内, 泰平

    1995-01-01

    Repulsive magnetic levitation systems with magnets driven by actuators were studied in this paper. In one system, a levitation magnet was driven in the direction of repulsive force to control the position and vibration of the levitated object. In another, a levitation magnet was moved in the lateral directions to stabilize the system in the manner of an inverted pendulum. The first type was studied experimentally with an experimental setup using a magnetostrictive actuator. The damping charac...

  18. Optical fibers with composite magnetic coating for magnetic field sensing

    Energy Technology Data Exchange (ETDEWEB)

    Radojevic, V.; Nedeljkovic, D.; Talijan, N. E-mail: ntalijan@elab.tmf.bg.ac.yu; Trifunovic, D.; Aleksic, R

    2004-05-01

    The investigated system for optical fiber sensor was multi-mode optical fiber with magnetic composite coating. Polymer component of composite coating was poly (ethylene-co-vinyl acetate)-EVA, and the magnetic component was powder of SmCo{sub 5} permanent magnet in form of single domain particles. The influence of the applied external magnetic field on the change of intensity of the light signal propagated through optical fiber was investigated.

  19. Optical fibers with composite magnetic coating for magnetic field sensing

    Science.gov (United States)

    Radojevic, V.; Nedeljkovic, D.; Talijan, N.; Trifunovic, D.; Aleksic, R.

    2004-05-01

    The investigated system for optical fiber sensor was multi-mode optical fiber with magnetic composite coating. Polymer component of composite coating was poly (ethylene-co-vinyl acetate)-EVA, and the magnetic component was powder of SmCo5 permanent magnet in form of single domain particles. The influence of the applied external magnetic field on the change of intensity of the light signal propagated through optical fiber was investigated.

  20. Anisotropically structured magnetic aerogel monoliths

    Science.gov (United States)

    Heiligtag, Florian J.; Airaghi Leccardi, Marta J. I.; Erdem, Derya; Süess, Martin J.; Niederberger, Markus

    2014-10-01

    Texturing of magnetic ceramics and composites by aligning and fixing of colloidal particles in a magnetic field is a powerful strategy to induce anisotropic chemical, physical and especially mechanical properties into bulk materials. If porosity could be introduced, anisotropically structured magnetic materials would be the perfect supports for magnetic separations in biotechnology or for magnetic field-assisted chemical reactions. Aerogels, combining high porosity with nanoscale structural features, offer an exceptionally large surface area, but they are difficult to magnetically texture. Here we present the preparation of anatase-magnetite aerogel monoliths via the assembly of preformed nanocrystallites. Different approaches are proposed to produce macroscopic bodies with gradient-like magnetic segmentation or with strongly anisotropic magnetic texture.Texturing of magnetic ceramics and composites by aligning and fixing of colloidal particles in a magnetic field is a powerful strategy to induce anisotropic chemical, physical and especially mechanical properties into bulk materials. If porosity could be introduced, anisotropically structured magnetic materials would be the perfect supports for magnetic separations in biotechnology or for magnetic field-assisted chemical reactions. Aerogels, combining high porosity with nanoscale structural features, offer an exceptionally large surface area, but they are difficult to magnetically texture. Here we present the preparation of anatase-magnetite aerogel monoliths via the assembly of preformed nanocrystallites. Different approaches are proposed to produce macroscopic bodies with gradient-like magnetic segmentation or with strongly anisotropic magnetic texture. Electronic supplementary information (ESI) available: Digital photographs of dispersions and gels with different water-to-ethanol ratios; magnetic measurements of an anatase aerogel containing 0.25 mol% Fe3O4 nanoparticles; XRD patterns of the iron oxide and

  1. Generating the optimal magnetic field for magnetic refrigeration

    DEFF Research Database (Denmark)

    Bjørk, Rasmus; Insinga, Andrea Roberto; Smith, Anders

    2016-01-01

    remanence distribution for any desired magnetic field. The method is based on the reciprocity theorem, which through the use of virtual magnets can be used to calculate the optimal remanence distribution. Furthermore, we present a method for segmenting a given magnet design that always results...

  2. Microfluidic magnetic separator using an array of soft magnetic elements

    DEFF Research Database (Denmark)

    Smistrup, Kristian; Lund-Olesen, Torsten; Hansen, Mikkel Fougt;

    2006-01-01

    We present the design, fabrication, characterization, and demonstration of a new passive magnetic bead separator. The device operates in an effective state when magnetized by an external magnetic field of only 50 mT, which is available from a tabletop electromagnet. We demonstrate the complete...

  3. Magnetic Forces and DNA Mechanics in Multiplexed Magnetic Tweezers

    NARCIS (Netherlands)

    De Vlaminck, I.; Henighan, T.; Van Loenhout, M.T.J.; Burnham, D.R.; Dekker, C.

    2012-01-01

    Magnetic tweezers (MT) are a powerful tool for the study of DNA-enzyme interactions. Both the magnet-based manipulation and the camera-based detection used in MT are well suited for multiplexed measurements. Here, we systematically address challenges related to scaling of multiplexed magnetic

  4. Magnetic catalyst bodies

    NARCIS (Netherlands)

    Teunissen, Wendy; Bol, A.A.; Geus, John W.

    2001-01-01

    After a discussion about the importance of the size of the catalyst bodies with reactions in the liquid-phase with a suspended catalyst, the possibilities of magnetic separation are dealt with. Deficiencies of the usual ferromagnetic particles are the reactivity and the clustering of the particles.

  5. High Performance Magnets

    Science.gov (United States)

    2000-03-29

    Our efforts in this project were focused on three different materials, namely; interstitial Sm-Fe carbides and nitrides, high energy product Nd2Fe14B ...magnets with MgO addition, and nanocomposite Nd2Fe14B /alpha-Fe consisting of a fine mixture of hard and soft phases. In the Sm-Fe carbides and

  6. Optimal magnetic attitude control

    DEFF Research Database (Denmark)

    Wisniewski, Rafal; Markley, F.L.

    1999-01-01

    because control torques can only be generated perpendicular to the local geomagnetic field vector. This has been a serious obstacle for using magnetorquer based control for three-axis stabilization of a low earth orbit satellite. The problem of controlling the spacecraft attitude using only magnetic...

  7. Functional Magnetic Resonance Imaging

    Science.gov (United States)

    Voos, Avery; Pelphrey, Kevin

    2013-01-01

    Functional magnetic resonance imaging (fMRI), with its excellent spatial resolution and ability to visualize networks of neuroanatomical structures involved in complex information processing, has become the dominant technique for the study of brain function and its development. The accessibility of in-vivo pediatric brain-imaging techniques…

  8. Single spin magnetic resonance

    Science.gov (United States)

    Wrachtrup, Jörg; Finkler, Amit

    2016-08-01

    Different approaches have improved the sensitivity of either electron or nuclear magnetic resonance to the single spin level. For optical detection it has essentially become routine to observe a single electron spin or nuclear spin. Typically, the systems in use are carefully designed to allow for single spin detection and manipulation, and of those systems, diamond spin defects rank very high, being so robust that they can be addressed, read out and coherently controlled even under ambient conditions and in a versatile set of nanostructures. This renders them as a new type of sensor, which has been shown to detect single electron and nuclear spins among other quantities like force, pressure and temperature. Adapting pulse sequences from classic NMR and EPR, and combined with high resolution optical microscopy, proximity to the target sample and nanoscale size, the diamond sensors have the potential to constitute a new class of magnetic resonance detectors with single spin sensitivity. As diamond sensors can be operated under ambient conditions, they offer potential application across a multitude of disciplines. Here we review the different existing techniques for magnetic resonance, with a focus on diamond defect spin sensors, showing their potential as versatile sensors for ultra-sensitive magnetic resonance with nanoscale spatial resolution.

  9. Functional Magnetic Resonance Imaging

    Science.gov (United States)

    Voos, Avery; Pelphrey, Kevin

    2013-01-01

    Functional magnetic resonance imaging (fMRI), with its excellent spatial resolution and ability to visualize networks of neuroanatomical structures involved in complex information processing, has become the dominant technique for the study of brain function and its development. The accessibility of in-vivo pediatric brain-imaging techniques…

  10. Search for Magnetic Monopoles

    CERN Multimedia

    2002-01-01

    This experiment is proposed to investigate the possible production of magnetic monopoles at the ISR. Very different values are in principle possible for the magnetic charge of such objects, and the present experiment intends to cover a range of magnetic charges from g, to 12 g, where g is the classical minimum charge of the Dirac theory, .ce g = 1/2e The detector consists of three double layers of solid track detector, which are only sensitive to highly ionizing particles, such as monopoles should be. The detector is placed directly in the vacuum chamber, to avoid the large energy losses that a monopole would suffer in a solid wall. A solenoidal magnet is placed between the intersection region and the detector and around the detector itself, in order to accelerate monopoles to an energy such that they are able to traverse the successive sensitive layers of the detector. The thickness of the sensitive layers is chosen to avoid confusion with possible background arising from highly ionizing ions. The experiment...

  11. Electricity and magnetism

    CERN Document Server

    Robertson, William C

    2005-01-01

    Shocked by static? Mixed up about magnets? Curious about currents? This book will help you get beyond memorizing electricity-related formulas, rules, and procedures so you can understand the topic at a deep level deep enough to teach it with confidence and comfort. By covering the basics of static electricity, current electricity, and magnetism, the book develops a scientific model showing that electricity and magnetism are really the same phenomenon in different forms. A bonus feature: access to interactive software that you can download from the NSTA Web site. The software will help you investigate electrical circuits from simple to complex without having to buy a lot of expensive materials (or risking electrocution!). Electricity and Magnetism is the fifth title in the award-winning NSTA Press Stop Faking It! Series. As author Bill Robertson writes, The book you have in your hands is not a textbook. It is, however, designed to help you get science at a level you never thought possible, and also to bring yo...

  12. Twisted molecular magnets

    DEFF Research Database (Denmark)

    Inglis, Ross; Milios, Constantinos J.; Jones, Leigh F.

    2012-01-01

    The use of derivatised salicylaldoximes in manganese chemistry has led to the synthesis of a family of approximately fifty hexanuclear ([Mn(III)(6)]) and thirty trinuclear ([Mn(III)(3)]) Single-Molecule Magnets (SMMs). Deliberate, targeted structural distortion of the metallic core afforded family...

  13. Magnetic targeted drug delivery

    Directory of Open Access Journals (Sweden)

    Timothy Wiedmann

    2009-10-01

    Full Text Available Lung cancer is the most common cause of death from cancer in both men and women. Treatment by intravenous or oral administration of chemotherapy agents results in serious and often treatment-limiting side effects. Delivery of drugs directly to the lung by inhalation of an aerosol holds the promise of achieving a higher concentration in the lung with lower blood levels. To further enhance the selective lung deposition, it may be possible to target deposition by using external magnetic fields to direct the delivery of drug coupled to magnetic particles. Moreover, alternating magnetic fields can be used to induce particle heating, which in turn controls the drug release rate with the appropriate thermal sensitive material.With this goal, superparamagetic nanoparticles (SPNP were prepared and characterized, and enhanced magnetic deposition was demonstrated in vitro and in vivo. SPNPs were also incorporated into a lipid-based/SPNP aerosol formulation, and drug release was shown to be controlled by thermal activation. Because of the inherent imaging potential of SPNPs, this use of nanotechnology offers the possibility of coupling the diagnosis of lung cancer to drug release, which perhaps will ultimately provide the “magic bullet” that Paul Ehrlich originally sought.

  14. Magnetic Stimulation and Epilepsy

    Science.gov (United States)

    2013-10-14

    investigated using behavioral recording and electroencephalographic (EEG) recording. The results (Figures 1~7) obtained have been submitted to Epilepsia ...Magnetic Stimulation on Penicillin-Induced Seizures in Rats. Epilepsia (submitted). * corresponding author. IV. OTHER CHANGES N/A V. FUTURE PLANS

  15. Magnetic rare earth superlattices

    DEFF Research Database (Denmark)

    Majkrzak, C.F.; Kwo, J.; Hong, M.;

    1991-01-01

    Advances in molecular beam epitaxy deposition techniques have recently made it possible to grow, an atomic plane at a time, single crystalline superlattices composed of alternating layers of a magnetic rare earth, such as Gd, Dy, Ho, or Er, and metallic Y, which has an identical chemical structure...

  16. LHC Superconducting Magnets

    CERN Document Server

    Jean Leyder

    2000-01-01

    The LHC is the next step in CERN's quest to unravel the mysteries of the Universe. It will accelerate protons to energies never before achieved in laboratories, and to hold them on course it will use powerful superconducting magnets on an unprecedented scale.

  17. LEAR bending magnet quadrant

    CERN Multimedia

    CERN PhotoLab

    1981-01-01

    During 1981, the PS South-Hall, no longer used for physics experiments, was cleared for the installation of the Low Energy Antiproton Ring, LEAR. In October 1981, 3 of the 4 bending magnet quadrants were in place, this is one of them.

  18. Magnetic-Optical Filter

    CERN Document Server

    Formicola, I; Pinto, C; Cerulo, P

    2007-01-01

    Magnetic-Optical Filter (MOF) is an instrument suited for high precision spectral measurements for its peculiar characteristics. It is employed in Astronomy and in the field of the telecommunications (it is called FADOF there). In this brief paper we summarize its fundamental structure and functioning.

  19. Quantum vacuum magnetic birefringence

    Energy Technology Data Exchange (ETDEWEB)

    Berceau, Paul; Battesti, Remy; Fouche, Mathilde; Frings, Paul; Nardone, Marc; Portugall, Oliver; Rikken, Geert L. J. A.; Rizzo, Carlo, E-mail: carlo.rizzo@lncmi.cnrs.fr [UPR 3228, CNRS-UPS-UJF-INSA, Laboratoire National des Champs Magnetiques Intenses (France)

    2012-05-15

    In this contribution to EXA2011 congress, we present the status of the BMV (Birefringence Magnetique du Vide) experiment which is based on the use of a state-of-the-art optical resonant cavity and high pulsed magnetic fields, and it is hosted by the Laboratoire National des Champs Magnetiques Intenses in Toulouse, France.

  20. Magnetism of quaternary sediments

    Science.gov (United States)

    Heller, Friedrich

    Magnetism of Quaternary sediments was the topic of a well-attended symposium held during the 13th INQUA (International Union of Quaternary Research) congress in Beijing, China, August 2-9. More than 40 papers were delivered by scientists from Belgium, England, France, Germany, Japan, New Zealand, Sweden, Switzerland, Taiwan, the United States, the Soviet Union, Yugoslavia, and other countries. The host country contributed to a productive session that was part of the first large scientific meeting to take place in Beijing after the June 4, 1989, upheaval.Nearly half of the studies focused on paleomagnetic and rock magnetic properties of loess in Alaska, Central Asia, China, and New Zealand. Magnetostratigraphic polarity dating was done at some sections in the western (Shaw et al.) and central Chinese loess plateau (Bai and Hus; Wang and Evans; Yue). The interpretation of the polarity pattern found in the western loess plateau still is not unambiguous. In the central part, certain polarity boundaries, such as the Brunhes/Matuyama (B/M) boundary, are found in slightly different stratigraphic positions (Hus et al.; Yue). In deep-sea sediments the lock-in depth of natural remanent magnetization (NRM) at the B/M boundary seems to be a linear function of sedimentation rate (de Menocal et al.). Although the magnetization process in the Chinese loess is not well understood, detailed records of polarity transitions have been reported for the B/M and the Jaramillo R→N transition (Ma et al.; Rolph).