WorldWideScience

Sample records for ambient temperature synthesis

  1. Thiamine hydrochloride: An efficient catalyst for one-pot synthesis of quinoxaline derivatives at ambient temperature

    Indian Academy of Sciences (India)

    Omprakash B Pawar; Fulchand R Chavan; Venkat S Suryawanshi; Vishnu S Shinde; Narayan D Shinde

    2013-01-01

    Quinoxaline derivatives have been synthesized in high to excellent yields in the presence of thiamine hydrochloride (VB1) as an inexpensive, non-toxic and metal ion free catalyst at ambient temperature.

  2. Rod-Shaped Magnetite Nano/Microparticles Synthesis at Ambient Temperature

    Directory of Open Access Journals (Sweden)

    Balaprasad Ankamwar

    2013-01-01

    Full Text Available Here, we reported room temperature synthesis of Fe3O4 rod-shaped nano/microparticles by chemical reduction method from FeCl3 precursor and NaBH4 as the reducing agent in the presence of the pyrrole as a capping agent. The magnetic Fe3O4 particles were characterized by several methods, such as SEM, XRD, FTIR, and TGA. The average aspect ratio of Fe3O4 rod-shaped particles was ~2.8. These particles were redispersed in deionised water to form a colloidal solution and showed magnetic properties. This economical synthesis route is scalable, and Fe3O4 particles can be exploited for various applications such as MRI contrast enhancement, biodiseperations, Ni-Fe batteries, and as a catalyst.

  3. Biogenic Synthesis of Fluorescent Carbon Dots at Ambient Temperature Using Azadirachta indica (Neem) gum.

    Science.gov (United States)

    Phadke, Chinmay; Mewada, Ashmi; Dharmatti, Roopa; Thakur, Mukeshchand; Pandey, Sunil; Sharon, Madhuri

    2015-07-01

    Synthesis of fluorescent Carbon Dots (CDs) from various carbonaceous materials apparently has acquired lots of interest amongst researchers as the corollary of the properties of CDs; which are subsequently getting unveiled. In this study we report the use of Azadirachta indica (Neem) Gum as a novel natural pre-cursor for synthesis of CDs at room temperature. Water soluble CDs of around 5-8 nm were obtained after treatment of the gum with ethanol and NaOH. These CDs exhibited green fluorescence in UV-light (λ = 365 nm). These CDs were found to be stable, having many bio-linkers attached on their surface, making it suitable for drug attachment and hence can serve as potential candidates for applications like drug delivery vehicles as well as for biosensors.

  4. Large scale synthesis and formation mechanism of silver nanoparticles in solid-state reactions at ambient temperature

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Aiqin, E-mail: zhangaiqin@zzuli.edu.cn [State Laboratory of Surface and Interface Science and Technology, Henan Collaborative Innovation Center of Environmental Pollution Control and Ecological Restoration, Zhengzhou University of Light Industry, Zhengzhou 450002 (China); Tian, Yakun; Xiao, Yuanhua; Sun, Yuan [State Laboratory of Surface and Interface Science and Technology, Henan Collaborative Innovation Center of Environmental Pollution Control and Ecological Restoration, Zhengzhou University of Light Industry, Zhengzhou 450002 (China); Li, Feng [State Laboratory of Surface and Interface Science and Technology, Henan Collaborative Innovation Center of Environmental Pollution Control and Ecological Restoration, Zhengzhou University of Light Industry, Zhengzhou 450002 (China); American Advanced Nanotechnology, Houston, TX 77459 (United States)

    2015-07-15

    Highlights: • AgNPs were prepared by solid state reaction at ambient temperature. • Only silver nitrate and ascorbic acid were needed in this reaction. • The size of the AgNPs can be tuned conveniently. • Formation mechanism of the AgNPs was investigated. - Abstract: A one-step strategy for preparing Ag nanoparticles (AgNPs) on large scale is demonstrated successfully, based on solid-state reactions at ambient temperature. The environmentally friendly synthesis can be achieved by simply grinding AgNO{sub 3} and ascorbic acid (AA) for about 30 min without adding any solvent and organic protectors. The size of AgNPs can be readily controlled by adjusting the reaction parameters such as AgNO{sub 3}/AA molar ratio and reaction time. The nanostructures of AgNPs and their formation mechanism have been also investigated with XRD, FTIR, FESEM, HRTEM and HPLC–MS. It was found that AA can reduce Ag{sup +} into Ag{sup 0} to form AgNPs directly in accompanying with its first oxidation into 2,3-diketogulonic acid (2,3-DKG) and then a series of fragmentary species of 2,3-DKG.

  5. Large scale synthesis and formation mechanism of silver nanoparticles in solid-state reactions at ambient temperature

    International Nuclear Information System (INIS)

    Highlights: • AgNPs were prepared by solid state reaction at ambient temperature. • Only silver nitrate and ascorbic acid were needed in this reaction. • The size of the AgNPs can be tuned conveniently. • Formation mechanism of the AgNPs was investigated. - Abstract: A one-step strategy for preparing Ag nanoparticles (AgNPs) on large scale is demonstrated successfully, based on solid-state reactions at ambient temperature. The environmentally friendly synthesis can be achieved by simply grinding AgNO3 and ascorbic acid (AA) for about 30 min without adding any solvent and organic protectors. The size of AgNPs can be readily controlled by adjusting the reaction parameters such as AgNO3/AA molar ratio and reaction time. The nanostructures of AgNPs and their formation mechanism have been also investigated with XRD, FTIR, FESEM, HRTEM and HPLC–MS. It was found that AA can reduce Ag+ into Ag0 to form AgNPs directly in accompanying with its first oxidation into 2,3-diketogulonic acid (2,3-DKG) and then a series of fragmentary species of 2,3-DKG

  6. Ambient temperature signalling in plants.

    Science.gov (United States)

    Wigge, Philip A

    2013-10-01

    Plants are exposed to daily and seasonal fluctuations in temperature. Within the 'ambient' temperature range (about 12-27°C for Arabidopsis) temperature differences have large effects on plant growth and development, disease resistance pathways and the circadian clock without activating temperature stress pathways. It is this developmental sensing and response to non-stressful temperatures that will be covered in this review. Recent advances have revealed key players in mediating temperature signals. The bHLH transcription factor PHYTOCHROME INTERACTING FACTOR4 (PIF4) has been shown to be a hub for multiple responses to warmer temperature in Arabidopsis, including flowering and hypocotyl elongation. Changes in chromatin state are involved in transmitting temperature signals to the transcriptome. Determining the precise mechanisms of temperature perception represents an exciting goal for the field.

  7. The relationship between body and ambient temperature and corneal temperature

    DEFF Research Database (Denmark)

    Kessel, Line; Johnson, Leif; Arvidsson, Henrik Sven;

    2010-01-01

    Exposure to elevated ambient temperatures has been mentioned as a risk factor for common eye diseases, primarily presbyopia and cataract. The aim of the present study was to examine the relationship among ambient, cornea, and body core temperature.......Exposure to elevated ambient temperatures has been mentioned as a risk factor for common eye diseases, primarily presbyopia and cataract. The aim of the present study was to examine the relationship among ambient, cornea, and body core temperature....

  8. Effect of ambient pressure on Leidenfrost temperature

    Science.gov (United States)

    Orejon, Daniel; Sefiane, Khellil; Takata, Yasuyuki

    2014-11-01

    The accurate prediction and control of the interaction of liquids with hot surfaces is paramount in numerous areas, including cooling applications. We present results illustrating the effect of ambient pressure on the temperature required for a droplet to levitate over a hot surface, i.e., the Leidenfrost temperature. In the present study the dependence of wetting and levitating temperatures on ambient pressure in a range of subatmospheric pressures is reported. Experimental data indicate that the Leidenfrost temperature decreases with decreasing pressure at subatmospheric pressures. A physical approach for the dependence of Leidenfrost temperature on ambient pressure, based on an analogy with saturation pressure dependence, is proposed. Furthermore, previous literature data for pressures above atmospheric are also included in the analysis to support and validate the proposed approach. In addition, the effect of substrate material, substrate roughness, and type of fluid on the Leidenfrost temperature is discussed.

  9. Application of nano SnO2 as a green and recyclable catalyst for the synthesis of 2-aryl or alkylbenzoxazole derivatives under ambient temperature

    Indian Academy of Sciences (India)

    Seyed Mohammad Vahdat; Shima Ghafouri Raz; Saeed Baghery

    2014-05-01

    Application of nano SnO2 as an efficient and benign catalyst has been explored for the synthesis of 2-aryl or alkylbenzoxazole derivatives via condensation reaction of aldehyde with 2-aminophenol. The reactions proceed under heterogeneous and mild conditions in ethanol at room temperature to provide 2-aryl or alkylbenzoxazoles in high yields.

  10. Water Loss Under Hot Ambient Temperatures

    Directory of Open Access Journals (Sweden)

    S. K. Basu

    1978-07-01

    Full Text Available Male 4 rates were ambient temperature (40 degree,42 degree, and 44 degree calcius for different durations of time upto a maximum of 3 hours. It was observed that there was a rapid loss in body weight accompanied by considerable increase in body temperature of the animals during the first hour of exposure. Thereafter the rate of body weight loss and increase in body temperature were slow till the end of observation period. Intolerance to heat appears to be more correlated with critical body temperature rather than the extent of dehydration.

  11. Control of flowering by ambient temperature.

    Science.gov (United States)

    Capovilla, Giovanna; Schmid, Markus; Posé, David

    2015-01-01

    The timing of flowering is a crucial decision in the life cycle of plants since favourable conditions are needed to maximize reproductive success and, hence, the survival of the species. It is therefore not surprising that plants constantly monitor endogenous and environmental signals, such as day length (photoperiod) and temperature, to adjust the timing of the floral transition. Temperature in particular has been shown to have a tremendous effect on the timing of flowering: the effect of prolonged periods of cold, called the vernalization response, has been extensively studied and the underlying epigenetic mechanisms are reasonably well understood in Arabidopsis thaliana. In contrast, the effect of moderate changes in ambient growth temperature on the progression of flowering, the thermosensory pathway, is only starting to be understood on the molecular level. Several genes and molecular mechanisms underlying the thermosensory pathway have already been identified and characterized in detail. At a time when global temperature is rising due to climate change, this knowledge will be pivotal to ensure crop production in the future. PMID:25326628

  12. Enhancing catalytic performance of palladium in gold and palladium alloy nanoparticles for organic synthesis reactions through visible light irradiation at ambient temperatures.

    Science.gov (United States)

    Sarina, Sarina; Zhu, Huaiyong; Jaatinen, Esa; Xiao, Qi; Liu, Hongwei; Jia, Jianfeng; Chen, Chao; Zhao, Jian

    2013-04-17

    The intrinsic catalytic activity of palladium (Pd) is significantly enhanced in gold (Au)-Pd alloy nanoparticles (NPs) under visible light irradiation at ambient temperatures. The alloy NPs strongly absorb light and efficiently enhance the conversion of several reactions, including Suzuki-Miyaura cross coupling, oxidative addition of benzylamine, selective oxidation of aromatic alcohols to corresponding aldehydes and ketones, and phenol oxidation. The Au/Pd molar ratio of the alloy NPs has an important impact on performance of the catalysts since it determines both the electronic heterogeneity and the distribution of Pd sites at the NP surface, with these two factors playing key roles in the catalytic activity. Irradiating with light produces an even more profound enhancement in the catalytic performance of the NPs. For example, the best conversion rate achieved thermally at 30 °C for Suzuki-Miyaura cross coupling was 37% at a Au/Pd ratio of 1:1.86, while under light illumination the yield increased to 96% under the same conditions. The catalytic activity of the alloy NPs depends on the intensity and wavelength of incident light. Light absorption due to the Localized Surface Plasmon Resonance of gold nanocrystals plays an important role in enhancing catalyst performance. We believe that the conduction electrons of the NPs gain the light absorbed energy producing energetic electrons at the surface Pd sites, which enhances the sites' intrinsic catalytic ability. These findings provide useful guidelines for designing efficient catalysts composed of alloys of a plasmonic metal and a catalytically active transition metal for various organic syntheses driven by sunlight. PMID:23566035

  13. Water Power Calculator Temperature and Analog Input/Output Module Ambient Temperature Testing

    Energy Technology Data Exchange (ETDEWEB)

    Mark D. McKay

    2011-02-01

    Water Power Calculator Temperature and Analog input/output Module Ambient Temperature Testing A series of three ambient temperature tests were conducted for the Water Power Calculator development using the INL Calibration Laboratory’s Tenney Environmental Chamber. The ambient temperature test results demonstrate that the Moore Industries Temperature Input Modules, Analog Input Module and Analog Output Module, ambient temperature response meet or exceed the manufactures specifications

  14. Capacitance at ambient temperature and microstructure of platinum/yttria-stabilized zirconia composites

    NARCIS (Netherlands)

    Hendriks, M.G.H.M.; Zyl, van W.E.; Elshof, ten J.E.; Verweij, H.

    2001-01-01

    The influence of microstructure on the capacitive behavior in the dual-phase composite system platinum/cubic-yttria-stabilized zirconia (YSZ) was studied at ambient temperature. Three different synthesis methods were employed. The volume fraction of Pt metal in the composite was varied between 0 and

  15. Hydrogen Storage at Ambient Temperature by the Spillover Mechanism

    Energy Technology Data Exchange (ETDEWEB)

    Yang , Ralph T.

    2011-02-04

    superactivated carbons (by following detailed doping and activation conditions given in our publications, e.g., Ref. 12), the storage capacities are increased two-fold (doubled) while slightly more than doubled by Ru doping. The bridging technique remains highly empirical and sample-to-sample consistency is difficult to achieve; however, significant enhancements by spillover can be achieved if the synthesis and pretreatment are done properly. Pitfalls in sample syntheses for both metal doped and bridged sorbents are pointed out in the report; deviations from the synthesis and pretreatment conditions will lead to diminished or no spillover effects. Due to the high bulk densities of zeolites, metal doped zeolites are shown to be most promising for achieving high volumetric storage capacities by spillover. Kinetics of both spillover and reverse spillover (i.e., desorption) at ambient temperature are also studied. This report summarizes the progress made in the project.

  16. Low-temperature and ambient-pressure synthesis and shape evolution of nanocrystalline pure, La-doped and Gd-doped CeO{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Basu, Joysurya, E-mail: jbasu@engr.uconn.edu [Department of Chemical, Materials and Biomolecular Engineering, 191 Auditorium Road, University of Connecticut, Storrs 06269, CT (United States); Divakar, R. [Physical Metallurgy Division, Indira Gandhi Centre for Atomic Research, Kalpakkam 603102, TN (India); Winterstein, Jonathan P.; Carter, C. Barry [Department of Chemical, Materials and Biomolecular Engineering, 191 Auditorium Road, University of Connecticut, Storrs 06269, CT (United States)

    2010-04-01

    Nanocrystalline cuboidal ceria has been synthesized by low-temperature hydrothermal reaction of cerium nitrate hexahydrate with hexamethylene tetramine. The particles have been doped with La and Gd by adding aqueous solution of the nitrate salts of the metals to the reaction mixture. The pure and doped particles are cubic in crystal structure and 10-25 nm in size. The pure and La-doped ceria are cuboidal in morphology, whereas the Gd-doped particles are irregular in shape. High-resolution TEM imaging and image simulation indicates that atomic level steps are present on the particle surfaces. The particles are faceted parallel to the {l_brace}1 1 1{r_brace} and {l_brace}1 0 0{r_brace} crystallographic planes and a continuous switching takes place between the two possible surface facets. It appears that the surface energies of the {l_brace}1 1 1{r_brace} and {l_brace}1 0 0{r_brace} facets are quite similar in magnitude and the interplay of surface energy determines the particle shape. Chemically sensitive imaging and spectroscopy shows that the dopants are homogeneously distributed within the particles and that the oxidation state of Ce is a mixture of +3 and +4. No preferential segregation either of the dopant or the oxidation state was observed. However, since the facet switching does depend on the chemistry of the dopant, there must be an affect on the atomic scale.

  17. Effects of ambient temperature on mechanomyography of resting quadriceps muscle.

    Science.gov (United States)

    McKay, William P; Vargo, Michael; Chilibeck, Philip D; Daku, Brian L

    2013-03-01

    It has been speculated that resting muscle mechanical activity, also known as minor tremor, microvibration, and thermoregulatory tonus, has evolved to maintain core temperature in homeotherms, and may play a role in nonshivering thermogenesis. This experiment was done to determine whether resting muscle mechanical activity increases with decreasing ambient temperature. We cooled 20 healthy, human, resting, supine subjects from an ambient temperature of 40° to 12 °C over 65 min. Core temperature, midquadriceps mechanomyography, surface electromyography, and oxygen consumption (VO2) were recorded. Resting muscle mechanical and electrical activity in the absence of shivering increased significantly at temperatures below 21.5 °C. Women defended core temperature more effectively than men, and showed increased resting muscle activity earlier than men. Metabolism measured by VO2 correlated with resting muscle mechanical activity (R = 0.65; p = 0.01). Resting muscle mechanical activity may have evolved, in part, to maintain core temperature in the face of mild cooling.

  18. Effect of Ambient Temperature and Composition on Liquid Droplet Combustion

    Directory of Open Access Journals (Sweden)

    Shah Shahood Alam

    2014-12-01

    Full Text Available An unsteady, spherically symmetric, single component, diffusion controlled gas phase droplet combustion model was developed assuming infinite kinetics and no radiation effects. Finite difference technique was used to solve time dependent equations of energy and species. Adiabatic flame temperature which is important for calculating thermodynamic properties was calculated by employing a detailed method. Effects of ambient temperature and composition on important combustion parameters like adiabatic flame temperature, droplet mass burning rate, burning constant and droplet lifetime were obtained. Results indicated that flame temperature, burning constant and mass burning rate increased with an increase in ambient temperature while the droplet life time decreased. The present gas phase code was used in conjunction with the Olikara and Borman code for obtaining concentration of important species. Emission results showed that for a 100 m n- heptane droplet burning in standard atmosphere, an increase in ambient temperature led to an increase in NO and CO concentrations and a decrease in CO2 and H2O concentrations. Extinction diameter for a 3000 m n- heptane droplet burning in oxygen-helium environment was determined. Also, effects of ambient temperature and composition were obtained on droplet lifetime and mass burning rate as a function of initial droplet diameter. The present gas phase model is simple but realistic and can be incorporated in spray combustion codes.

  19. Ambient temperature perception in papaya for papaya ringspot virus interaction.

    Science.gov (United States)

    Mangrauthia, Satendra K; Singh Shakya, Viplendra P; Jain, R K; Praveen, Shelly

    2009-06-01

    Temperature dramatically affects the host-virus interaction. Outbreaks of viral diseases are frequently associated with the ambient temperature required for host development. Using papaya as a host and Papaya ringspot virus (PRSV) as a pathogen, we studied the effect of temperature on the intensity of disease symptoms and virus accumulation. The phenotypic expression of symptoms and viral accumulation were found to be maximum at ambient temperature (26-31 degrees C) of papaya cultivation. However, there was a drastic difference, 10 degrees C above and below the ambient temperature. The underlying mechanism of these well-known observations are not yet understood completely; however, these observations might help find answers in RNA silencing mechanism of plants. Since viral-derived silencing suppressor proteins play a significant role in RNA silencing mechanism, here we show that PRSV-derived Helper component proteinase (HC-Pro) protein has an affinity for small RNAs in a temperature-dependent manner. This suggested the probable role of HC-Pro in the temperature-regulated host-virus relationship.

  20. Water mediated eco-friendly green protocol for one-pot synthesis of -aminophosphonates at ambient conditions

    Indian Academy of Sciences (India)

    Santhosh Reddy Mandha; Manjula Alla; Vittal Rao Bommena

    2014-05-01

    Increasing environmental awareness and economic concerns have led to the consideration of highly efficient one-pot, three-component, green approaches for important organic synthons. We describe here a simple, elegant and high yielding protocol for the synthesis of -aminophosphonates in totally solvent-free, catalyst-free conditions by reacting aldehydes, amines and trimethyl phosphite at ambient temperature.

  1. Temperature Trapping: Energy-Free Maintenance of Constant Temperatures as Ambient Temperature Gradients Change

    Science.gov (United States)

    Shen, Xiangying; Li, Ying; Jiang, Chaoran; Huang, Jiping

    2016-07-01

    It is crucial to maintain constant temperatures in an energy-efficient way. Here we establish a temperature-trapping theory for asymmetric phase-transition materials with thermally responsive thermal conductivities. Then we theoretically introduce and experimentally demonstrate a concept of an energy-free thermostat within ambient temperature gradients. The thermostat is capable of self-maintaining a desired constant temperature without the need of consuming energy even though the environmental temperature gradient varies in a large range. As a model application of the concept, we design and show a different type of thermal cloak that has a constant temperature inside its central region in spite of the changing ambient temperature gradient, which is in sharp contrast to all the existing thermal cloaks. This work has relevance to energy-saving heat preservation, and it provides guidance both for manipulating heat flow without energy consumption and for designing new metamaterials with temperature-responsive or field-responsive parameters in many disciplines such as thermotics, optics, electromagnetics, acoustics, mechanics, electrics, and magnetism.

  2. Variable capacity utilization, ambient temperature shocks and generation asset valuation

    International Nuclear Information System (INIS)

    This paper discusses generation asset valuation in a framework where capital utilization decisions are endogenous. We use real options approach for valuation of natural gas fueled turbines. Capital utilization choices that we explore include turning on/off the unit, operating the unit at increased firing temperatures (overfiring), and conducting preventive maintenance. Overfiring provides capacity enhancement which comes at the expense of reduced maintenance interval and increased costs of part replacement. We consider the costs and benefits of overfiring in attempt to maximize the asset value by optimally exercising the overfire option. In addition to stochastic processes governing prices, we incorporate an exogenous productivity shock: ambient temperature. We consider how variation in ambient temperature affects the asset value through its effect on gas turbine's productivity. (author)

  3. Ambient air temperature effects on the temperature of sewage sludge composting process

    Institute of Scientific and Technical Information of China (English)

    HUANG Qi-fei; CHEN Tong-bin; GAO Ding; HUANG Ze-chun

    2005-01-01

    Using data obtained with a full-scale sewage sludge composting facility, this paper studied the effects of ambient air temperature on the composting temperature with varying volume ratios of sewage sludge and recycled compost to bulking agent. Two volume ratios were examined experimentally, 1: 0: 1 and 3: 1: 2. The results show that composting temperature was influenced by ambient air temperature and the influence was more significant when composting was in the temperature rising process: composting temperature changed 2.4-6.5℃ when ambient air temperature changed 13℃. On the other hand, the influence was not significant when composting was in the high-temperature and/or temperature falling process: composting temperature changed 0.75-1.3℃ when ambient air temperature changed 8-15 ℃. Hysteresis effect was observed in composting temperature's responses to ambient air temperature. When the ventilation capability of pile was excellent(at a volume ratio of 1:0:1), the hysteresis time was short and ranging 1.1-1.2 h. On the contrary, when the proportion of added bulking agent was low, therefore less porosity in the substrate(at a volume ratio of 3:1:2), the hysteresis time was long and ranging 1.9-3.1 h.

  4. Ambient temperature cadmium zinc telluride radiation detector and amplifier circuit

    International Nuclear Information System (INIS)

    A low noise, low power consumption, compact, ambient temperature signal amplifier for a Cadmium Zinc Telluride (CZT) radiation detector is disclosed. The amplifier can be used within a larger system (e.g., including a multi-channel analyzer) to allow isotopic analysis of radionuclides in the field. In one embodiment, the circuit stages of the low power, low noise amplifier are constructed using integrated circuit (IC) amplifiers , rather than discrete components, and include a very low noise, high gain, high bandwidth dual part preamplification stage, an amplification stage, and an filter stage. The low noise, low power consumption, compact, ambient temperature amplifier enables the CZT detector to achieve both the efficiency required to determine the presence of radionuclides and the resolution necessary to perform isotopic analysis to perform nuclear material identification. The present low noise, low power, compact, ambient temperature amplifier enables a CZT detector to achieve resolution of less than 3% full width at half maximum at 122 keV for a Cobalt-57 isotope source. By using IC circuits and using only a single 12 volt supply and ground, the novel amplifier provides significant power savings and is well suited for prolonged portable in-field use and does not require heavy, bulky power supply components. 9 figs

  5. Microbial community analysis of ambient temperature anaerobic digesters

    Energy Technology Data Exchange (ETDEWEB)

    Ciotola, R. [Ohio State Univ., Columbus, OH (United States). Dept. of Food, Agriculture and Biological Engineering

    2010-07-01

    This paper reported on a study in which designs for Chinese and Indian fixed-dome anaerobic digesters were modified in an effort to produce smaller and more affordable digesters. While these types of systems are common in tropical regions of developing countries, they have not been used in colder climates because of the low biogas yield during the winter months. Although there is evidence that sufficient biogas production can be maintained in colder temperatures through design and operational changes, there is a lack of knowledge about the seasonal changes in the composition of the microbial communities in ambient temperature digesters. More knowledge is needed to design and operate systems for maximum biogas yield in temperate climates. The purpose of this study was to cultivate a microbial community that maximizes biogas production at psychrophilic temperatures. The study was conducted on a 300 gallon experimental anaerobic digester on the campus of Ohio State University. Culture-independent methods were used on weekly samples collected from the digester in order to examine microbial community response to changes in ambient temperature. Microbial community profiles were established using universal bacterial and archaeal primers that targeted the 16S rRNA gene. In addition to the methanogenic archaea, this analysis also targeted some of the other numerically and functionally important microbial taxa in anaerobic digesters, such as hydrolytic, fermentative, acetogenic and sulfate reducing bacteria. According to preliminary results, the composition of the microbial community shifts with changes in seasonal temperature.

  6. Solution based synthesis of simple fcc Si nano-crystals under ambient conditions.

    Science.gov (United States)

    Balcı, Mustafa H; Sæterli, Ragnhild; Maria, Jerome; Lindgren, Mikael; Holmestad, Randi; Grande, Tor; Einarsrud, Mari-Ann

    2013-02-28

    We demonstrate for the first time that simple face-centered cubic (fcc) silicon nano-crystals can be produced by a solution based bottom-up synthesis route under ambient conditions. Simple fcc Si nano-crystals (2-7 nm) were prepared at room temperature by using sodium cyclopentadienide as a reducing agent for silicon tetrachloride. Photoluminescence emission at 550 nm was observed for the fcc silicon nano-crystals upon excitation at 340 nm, indicating that fcc Si nano-crystals were exhibiting direct bandgap like semiconductor properties with very fast radiative recombination rates. The new synthesis route makes possible the production and study of simple fcc polymorphs of Si nano-crystals with an easy alteration of surface termination groups.

  7. Numerical Analysis of Exergy for Air-Conditioning Influenced by Ambient Temperature

    Directory of Open Access Journals (Sweden)

    Jing-Nang Lee

    2014-07-01

    Full Text Available The article presents numerical analysis of exergy for air-conditioning influenced by ambient temperature. The model of numerical simulation uses an integrated air conditioning system exposed in varied ambient temperature to observe change of the four main devices, the compressor, the condenser, the capillary, and the evaporator in correspondence to ambient temperature. The analysis devices of the four devices’s exergy influenced by the varied ambient temperature and found that the capillary has unusual increasing exergy loss vs. increasing ambient temperature in comparison to the other devices. The result shows that reducing exergy loss of the capillary influenced by the ambient temperature is the key for improving working efficiency of an air-conditioning system when influence of the ambient temperature is considered. The higher ambient temperature causes the larger pressure drop of capillary and more exergy loss.

  8. Photoelectron Spectroscopy under Ambient Pressure and Temperature Conditions

    Energy Technology Data Exchange (ETDEWEB)

    Ogletree, D. Frank; Bluhm, Hendrik; Hebenstreit, Eleonore B.; Salmeron, Miquel

    2009-02-27

    We describe the development and applications of novel instrumentation for photoemission spectroscopy of solid or liquid surfaces in the presence of gases under ambient conditions or pressure and temperature. The new instrument overcomes the strong scattering of electrons in gases by the use of an aperture close to the surface followed by a differentially-pumped electrostatic lens system. In addition to the scattering problem, experiments in the presence of condensed water or other liquids require the development of special sample holders to provide localized cooling. We discuss the first two generations of Ambient Pressure PhotoEmission Spectroscopy (APPES) instruments developed at synchrotron light sources (ALS in Berkeley and BESSY in Berlin), with special focus on the Berkeley instruments. Applications to environmental science and catalytic chemical research are illustrated in two examples.

  9. Numerical Analysis of Exergy for Air-Conditioning Influenced by Ambient Temperature

    OpenAIRE

    Jing-Nang Lee; Chien-Chih Chen; Chen-Ching Ting

    2014-01-01

    The article presents numerical analysis of exergy for air-conditioning influenced by ambient temperature. The model of numerical simulation uses an integrated air conditioning system exposed in varied ambient temperature to observe change of the four main devices, the compressor, the condenser, the capillary, and the evaporator in correspondence to ambient temperature. The analysis devices of the four devices’s exergy influenced by the varied ambient temperature and found that the...

  10. Ambient temperature normalization for infrared face recognition based on the second-order polynomial model

    Science.gov (United States)

    Wang, Zhengzi

    2015-08-01

    The influence of ambient temperature is a big challenge to robust infrared face recognition. This paper proposes a new ambient temperature normalization algorithm to improve the performance of infrared face recognition under variable ambient temperatures. Based on statistical regression theory, a second order polynomial model is learned to describe the ambient temperature's impact on infrared face image. Then, infrared image was normalized to reference ambient temperature by the second order polynomial model. Finally, this normalization method is applied to infrared face recognition to verify its efficiency. The experiments demonstrate that the proposed temperature normalization method is feasible and can significantly improve the robustness of infrared face recognition.

  11. Thermal modelling of PV module performance under high ambient temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Diarra, D.C.; Harrison, S.J. [Queen' s Univ., Kingston, ON (Canada). Dept. of Mechanical and Materials Engineering Solar Calorimetry Lab; Akuffo, F.O. [Kwame Nkrumah Univ. of Science and Technology, Kumasi (Ghana). Dept. of Mechanical Engineering

    2005-07-01

    When predicting the performance of photovoltaic (PV) generators, the actual performance is typically lower than test results conducted under standard test conditions because the radiant energy absorbed in the module under normal operation raises the temperature of the cell and other multilayer components. The increase in temperature translates to a lower conversion efficiency of the solar cells. In order to address these discrepancies, a thermal model of a characteristic PV module was developed to assess and predict its performance under real field-conditions. The PV module consisted of monocrystalline silicon cells in EVA between a glass cover and a tedlar backing sheet. The EES program was used to compute the equilibrium temperature profile in the PV module. It was shown that heat is dissipated towards the bottom and the top of the module, and that its temperature can be much higher than the ambient temperature. Modelling results indicate that 70-75 per cent of the absorbed solar radiation is dissipated from the solar cells as heat, while 4.7 per cent of the solar energy is absorbed in the glass cover and the EVA. It was also shown that the operating temperature of the PV module decreases with increased wind speed. 2 refs.

  12. Effect of ambient temperature and relative humidity on interfacial temperature during early stages of drop evaporation.

    Science.gov (United States)

    Fukatani, Yuki; Orejon, Daniel; Kita, Yutaku; Takata, Yasuyuki; Kim, Jungho; Sefiane, Khellil

    2016-04-01

    Understanding drop evaporation mechanisms is important for many industrial, biological, and other applications. Drops of organic solvents undergoing evaporation have been found to display distinct thermal patterns, which in turn depend on the physical properties of the liquid, the substrate, and ambient conditions. These patterns have been reported previously to be bulk patterns from the solid-liquid to the liquid-gas drop interface. In the present work the effect of ambient temperature and humidity during the first stage of evaporation, i.e., pinned contact line, is studied paying special attention to the thermal information retrieved at the liquid-gas interface through IR thermography. This is coupled with drop profile monitoring to experimentally investigate the effect of ambient temperature and relative humidity on the drop interfacial thermal patterns and the evaporation rate. Results indicate that self-generated thermal patterns are enhanced by an increase in ambient temperature and/or a decrease in humidity. The more active thermal patterns observed at high ambient temperatures are explained in light of a greater temperature difference generated between the apex and the edge of the drop due to greater evaporative cooling. On the other hand, the presence of water humidity in the atmosphere is found to decrease the temperature difference along the drop interface due to the heat of adsorption, absorption and/or that of condensation of water onto the ethanol drops. The control, i.e., enhancement or suppression, of these thermal patterns at the drop interface by means of ambient temperature and relative humidity is quantified and reported.

  13. Effect of ambient temperature and relative humidity on interfacial temperature during early stages of drop evaporation

    Science.gov (United States)

    Fukatani, Yuki; Orejon, Daniel; Kita, Yutaku; Takata, Yasuyuki; Kim, Jungho; Sefiane, Khellil

    2016-04-01

    Understanding drop evaporation mechanisms is important for many industrial, biological, and other applications. Drops of organic solvents undergoing evaporation have been found to display distinct thermal patterns, which in turn depend on the physical properties of the liquid, the substrate, and ambient conditions. These patterns have been reported previously to be bulk patterns from the solid-liquid to the liquid-gas drop interface. In the present work the effect of ambient temperature and humidity during the first stage of evaporation, i.e., pinned contact line, is studied paying special attention to the thermal information retrieved at the liquid-gas interface through IR thermography. This is coupled with drop profile monitoring to experimentally investigate the effect of ambient temperature and relative humidity on the drop interfacial thermal patterns and the evaporation rate. Results indicate that self-generated thermal patterns are enhanced by an increase in ambient temperature and/or a decrease in humidity. The more active thermal patterns observed at high ambient temperatures are explained in light of a greater temperature difference generated between the apex and the edge of the drop due to greater evaporative cooling. On the other hand, the presence of water humidity in the atmosphere is found to decrease the temperature difference along the drop interface due to the heat of adsorption, absorption and/or that of condensation of water onto the ethanol drops. The control, i.e., enhancement or suppression, of these thermal patterns at the drop interface by means of ambient temperature and relative humidity is quantified and reported.

  14. Thermoelectric Energy Harvesting from Transient Ambient Temperature Gradients

    Science.gov (United States)

    Moser, André; Erd, Metin; Kostic, Milos; Cobry, Keith; Kroener, Michael; Woias, Peter

    2012-06-01

    We examine a thermoelectric harvester that converts electrical energy from the naturally occurring temperature difference between ambient air and large thermal storage capacitors such as building walls or the soil. For maximum power output, the harvester design is implemented in two steps: source matching of the thermal and electrical interfaces to the energy source (system level) followed by load matching of the generator to these interfaces (subsystem level). Therefore, we measure thermal source properties such as the temperature difference, the air velocity, and the cutoff frequency in two application scenarios (road tunnel and office building). We extend a stationary model of the harvester into the time domain to account for transient behavior of the source. Based on the model and the source measurements, we perform the source and load matching. The resulting harvester consists of a pin fin heat sink with a thermal resistance of 6.2 K/W and a cutoff frequency 2.5 times greater than that of the source, a thermoelectric generator, and a DC/DC step-up converter starting at a total temperature difference of only Δ T = 1.2 K. In a final road tunnel field test, this optimized harvester converts 70 mJ of electrical energy per day without any direct solar irradiation. The energy provided by the harvester enables 415 data transmissions from a wireless sensor node per day.

  15. Optimized Synthesis of Carbon Aerogels via Ambient Pressure Drying Process as Electrode for Supercapacitors

    Institute of Scientific and Technical Information of China (English)

    YUAN Lei; CHANG Lijuan; FU Zhibing; YANG Xi; JIAO Xingli; TANG Yongjian; LIU Xichuan; WANG Chaoyang

    2015-01-01

    Carbon aerogels were synthesized via ambient pressure drying process using resorcinol-formaldehyde as precursor and P123 to strengthen their skeletons. CO2 activation technology was implemented to improve surface areas and adjust pore size distribution. The synthesis process was optimized, and the morphology, structure, adsorption properties and electrochemical behavior of different samples were characterized. The CO2-activated samples achieved a high specific capacitance of 129.2 F/g in 6 M KOH electrolytes at the current density of 1 mA/cm2 within the voltage range of 0-0.8 V. The optimized activation temperature and duration were determined to be 950℃and 4 h, respectively.

  16. EFFECT OF AMBIENT TEMPERATURE ON BODY TEMPERATURE AND REST METABOLIC RATE IN APODEMUS CHEVRIERI DURING POSTNATAL DEVELOPMENT

    OpenAIRE

    Zhu Wan-long; Sun Shu-ran; Ge Fang; Sun Cong-nan; Zhang Lin; Wang Zheng-kun

    2014-01-01

    In order to investigate the ability of constant temperature and thermoregulation in Apodemus chevrieri, body temperature and rest metabolic rate (RMR) were measured during postnatal development (1~42 day) when the A. chevrieri exposed different ambient temperature. The result showed that: body temperature and RMR of pups in A. chevrieri increased according to the increase of ambient temperature during 1 day to 7 day, showed character of poikilotherms; body temperature of pups were lower in lo...

  17. 46 CFR 153.370 - Minimum relief valve setting for ambient temperature cargo tanks.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 5 2010-10-01 2010-10-01 false Minimum relief valve setting for ambient temperature... temperature cargo tanks. The relief valve setting for a containment system that carries a cargo at ambient temperature must at least equal the cargo's vapor pressure at 46 °C (approx. 115 °F)....

  18. Thermoelectric energy harvesting from small ambient temperature transients

    Energy Technology Data Exchange (ETDEWEB)

    Moser, Andre

    2012-07-01

    Wireless sensor networks (WSNs) represent a key technology, used, for instance, in structural health monitoring, building automation systems, or traffic surveillance. Supplying power to a network of spatially distributed sensor nodes, especially at remote locations, is a large challenge: power grids are reliable but costly to install, whereas batteries provide a high flexibility in the installation but have a limited lifetime. This dilemma can be overcome by micro energy harvesting which offers both: reliability and flexibility. Micro energy harvesters are able to convert low grade ambient energy into useful electrical energy and thus provide power for wireless sensor networks or other electronic devices - in-situ, off-grid, and with an almost unlimited lifetime. Thermal energy is an omnipresent source of ambient energy: The day-night-cycle of the sun causes a temperature variation in the ambient air as well as arbitrary solids (soil, building walls, etc.). Unlike the air, solids have a large thermal inertia which dampens the temperature variation. This physical process leads to a temperature difference {Delta}T = T{sub air} - T{sub solid} between air and solid that can be converted directly into electrical energy by a thermoelectric generator (TEG). Thermal and electrical interfaces are necessary to connect the TEG to the thermal energy source (T{sub air}, T{sub solid}) and the electrical load (WSN). Reliable operation of the WSN may only be ensured if the harvester provides sufficient electrical energy, i.e. operates at its maximum power point. The goal of this thesis is to study, design, and test thermoelectric harvesters generating electrical energy from small ambient temperature transients in order to self-sufficiently power a WSN. Current research into thermoelectric energy harvesting, especially analytical modeling and application in the field are treated insufficiently. Therefore, a time-dependent analytical model of the harvester's output power is set

  19. Raman Channel Temperature Measurement of SiC MESFET as a Function of Ambient Temperature and DC Power

    Science.gov (United States)

    Ponchak, George E.; Eldridge, Jeffrey J.; Krainsky, Isay L.

    2009-01-01

    Raman spectroscopy is used to measure the junction temperature of a Cree SiC MESFET as a function of the ambient temperature and DC power. The carrier temperature, which is approximately equal to the ambient temperature, is varied from 25 C to 450 C, and the transistor is biased with VDS=10V and IDS of 50 mA and 100 mA. It is shown that the junction temperature is approximately 52 and 100 C higher than the ambient temperature for the DC power of 500 and 1000 mW, respectively.

  20. ambiental

    Directory of Open Access Journals (Sweden)

    Roque Leal Salcedo

    2008-01-01

    Full Text Available El derecho internacional ambiental es un conocimiento de carácter transversal, que entre otras consideraciones refleja las preocupaciones de la sociedad por la implementación de un modelo de desarrollo sustentable para el respeto a las reglas del medio natural que garantizan la integridad y renovación de los sistemas naturales. El presente artículo enfoca esta visión a través del análisis de material documental revisado, entre ellos tratados internacionales que permiten distinguir el desarrollo del derecho internacional ambiental y el papel de Organización de las Naciones Unidas (ONU, en el propósito común del derecho individual y colectivo de disfrutar de una vida, un ambiente seguro, sano y ecológicamente equilibrado. En función a estas disertaciones las consideraciones finales exponen parte de la visión que ha estructurado la ONU y que representan un aporte considerable en el fomento de la conciencia mundial sobre la necesidad de establecer vínculos entre las naciones para el continuo desarrollo de esta rama del derecho.

  1. The dependence of surface temperature on IGBTs load and ambient temperature

    Directory of Open Access Journals (Sweden)

    Alexander Čaja

    2015-01-01

    Full Text Available Currently, older power electronics and electrotechnics are improvement and at the same time developing new and more efficient devices. These devices produce in their activities a significant part of the heat which, if not effectively drained, causing damage to these elements. In this case, it is important to develop new and more efficient cooling system. The most widespread of modern methods of cooling is the cooling by heat pipe. This contribution is aimed at cooling the insulated-gate bipolar transistor (IGBT elements by loop heat pipe (LHP. IGBTs are very prone to damage due to high temperatures, and therefore is the important that the surface temperature was below 100°C. It was therefore created a model that examined what impact of surface temperature on the IGBT element and heat removal at different load and constant ambient temperature.

  2. The dependence of surface temperature on IGBTs load and ambient temperature

    Science.gov (United States)

    Alexander, Čaja; Marek, Patsch

    2015-05-01

    Currently, older power electronics and electrotechnics are improvement and at the same time developing new and more efficient devices. These devices produce in their activities a significant part of the heat which, if not effectively drained, causing damage to these elements. In this case, it is important to develop new and more efficient cooling system. The most widespread of modern methods of cooling is the cooling by heat pipe. This contribution is aimed at cooling the insulated-gate bipolar transistor (IGBT) elements by loop heat pipe (LHP). IGBTs are very prone to damage due to high temperatures, and therefore is the important that the surface temperature was below 100°C. It was therefore created a model that examined what impact of surface temperature on the IGBT element and heat removal at different load and constant ambient temperature.

  3. Advanced Catalysts for the Ambient Temperature Oxidation of Carbon Monoxide and Formaldehyde

    Science.gov (United States)

    Nalette, Tim; Eldridge, Christopher; Yu, Ping; Alpetkin, Gokhan; Graf, John

    2010-01-01

    The primary applications for ambient temperature carbon monoxide (CO) oxidation catalysts include emergency breathing masks and confined volume life support systems, such as those employed on the Shuttle. While Hopcalite is typically used in emergency breathing masks for terrestrial applications, in the 1970s, NASA selected a 2% platinum (Pt) on carbon for use on the Shuttle since it is more active and also more tolerant to water vapor. In the last 10-15 years there have been significant advances in ambient temperature CO oxidation catalysts. Langley Research Center developed a monolithic catalyst for ambient temperature CO oxidation operating under stoichiometric conditions for closed loop carbon dioxide (CO2) laser applications which is also advertised as having the potential to oxidize formaldehyde (HCHO) at ambient temperatures. In the last decade it has been discovered that appropriate sized nano-particles of gold are highly active for CO oxidation, even at sub-ambient temperatures, and as a result there has been a wealth of data reported in the literature relating to ambient/low temperature CO oxidation. In the shorter term missions where CO concentrations are typically controlled via ambient temperature oxidation catalysts, formaldehyde is also a contaminant of concern, and requires specially treated carbons such as Calgon Formasorb as untreated activated carbon has effectively no HCHO capacity. This paper examines the activity of some of the newer ambient temperature CO and formaldehyde (HCHO) oxidation catalysts, and measures the performance of the catalysts relative to the NASA baseline Ambient Temperature Catalytic Oxidizer (ATCO) catalyst at conditions of interest for closed loop trace contaminant control systems.

  4. Influence of the ambient air temperature on the electrical contact reliability of electromagnetic relay

    Institute of Scientific and Technical Information of China (English)

    YAO Fang; ZHENG Jian-rong; HUANG Zhang-wu

    2007-01-01

    The dynamic contact resistances of HH52P electromagnetic relays are measured under different ambient air temperature. Their diagnostic parameters are extracted and determined. It is found that the ambient air temperature obviously influences some parameters. In order to research its influence on the electrical contact reliability of electromagnetic relay, the statistic analysis is applied to study the static contact resistance, the max of the dynamic contact resistance and the bounce time. It is found that the ambient air temperature regularly influences the three parameters. Thoroughly, the phenomenon is studied and analyzed in the point of material science so as to probe into the essential matter of it.

  5. Preparation of transparent, hard thermochromic polysiloxane/tungsten-doped vanadium dioxide nanocomposite coatings at ambient temperature

    Energy Technology Data Exchange (ETDEWEB)

    Lu, Yinfeng; Zhou, Shuxue, E-mail: zhoushuxue@fudan.edu.cn; Gu, Guangxin; Wu, Limin

    2013-05-01

    Polysiloxane/tungsten-doped vanadium dioxide [VO{sub 2}(W)] nanocomposite coatings were prepared by de-agglomerating and modifying the self-made VO{sub 2}(W) particles with 3-methacryloxypropyltrimethoxysilane in butyl acetate, then mixing MPS-functionalized VO{sub 2}(W) nanoparticles with polysiloxane oligomers and curing the product at ambient temperature with the aid of 3-aminopropyltriethoxysilane. The VO{sub 2}(W) particles were obtained by hydrolysis of vanadyl sulfate mingled with tungstate dopant and subsequent calcination. The structure and properties of the VO{sub 2}(W) particles and nanocomposite coatings were characterized by X-ray diffraction analysis, differential scanning calorimetry, visible-near infrared spectroscopy, pendulum hardness tests, and nanoindentation. The effects of the synthesis conditions and the de-agglomeration process on the properties of the VO{sub 2}(W) particles were investigated. Crystalline VO{sub 2}(W) particles were obtained only with an appropriate amount of air and temperature during the calcination step and were easily reduced to nanometer size by bead-milling. The obtained nanocomposite coatings exhibited high transparency, good thermochromic performance, and ultra-high hardness (∼ 1.0 GPa). - Highlights: • Thermochromic coatings were prepared with VO{sub 2}(W) particles and polysiloxane. • Crystalline VO{sub 2}(W) particles can be reduced to nanosize by bead-milling. • The coatings display transparency of 60% and solar energy moduluation of 23%. • The coatings are ambient-curable, favoring in situ application on windows.

  6. Formic Acid Dehydrogenation on Au-Based Catalysts at Near-Ambient Temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Ojeda, Manuel; Iglesia, Enrique

    2008-11-24

    Formic acid (HCOOH) is a convenient hydrogen carrier in fuel cells designed for portable use. Recent studies have shown that HCOOH decomposition is catalyzed with Ru-based complexes in the aqueous phase at near-ambient temperatures. HCOOH decomposition reactions are used frequently to probe the effects of alloying and cluster size and of geometric and electronic factors in catalysis. These studies have concluded that Pt is the most active metal for HCOOH decomposition, at least as large crystallites and extended surfaces. The identity and oxidation state of surface metal atoms influence the relative rates of dehydrogenation (HCOOH {yields} H{sub 2} + CO{sub 2}) and dehydration (HCOOH {yields} H{sub 2}O + CO) routes, a selectivity requirement for the synthesis of CO-free H{sub 2} streams for low-temperature fuel cells. Group Ib and Group VIII noble metals catalyze dehydrogenation selectively, while base metals and metal oxides catalyze both routes, either directly or indirectly via subsequent water-gas shift (WGS) reactions.

  7. Significance and influence of the ambient temperature as a rate factor of steel reinforcement corrosion

    Indian Academy of Sciences (India)

    V Živica

    2002-10-01

    The rate of corrosion of reinforcement being an electrochemical process, undoubtedly is dependent even on the level of the ambient temperature. Therefore, the ambient temperature seems to be an important factor of the corrosion rate and the durability of the reinforced concrete structures in aggressive environment. The present data on the influence and significance of the ambient temperature in the process of corrosion of reinforcement of the reinforced structures are surprisingly limited and poor. It seems that it is supposed to be a simple increase of corrosion rate when the ambient temperature is increased. The lack of information was a motivation for the present study. It was aimed at the experimental research of the influence of the increase of the ambient temperature on the rate of chloride induced corrosion of steel reinforcement. The results obtained show that the influence of the studied factor is more complex showing an acceleration effect till a temperature of 40°C diversified by the inhibition effects with further increase of the ambient temperature.

  8. Ammonia synthesis at low temperatures

    DEFF Research Database (Denmark)

    Rod, Thomas Holm; Logadottir, Ashildur; Nørskov, Jens Kehlet

    2000-01-01

    have been carried out to evaluate its feasibility. The calculations suggest that it might be possible to catalytically produce ammonia from molecular nitrogen at low temperatures and pressures, in particular if energy is fed into the process electrochemically. (C) 2000 American Institute of Physics........ In contrast to the biological process, the industrial process requires high temperatures and pressures to proceed, and an explanation of this important difference is discussed. The possibility of a metal surface catalyzed process running at low temperatures and pressures is addressed, and DFT calculations...

  9. Silica-based sulfonic acid (MCM-41-SO3H: a practical and efficient catalyst for the synthesis of highly substituted quinolines under solvent-free conditions at ambient temperature

    Directory of Open Access Journals (Sweden)

    Ali Maleki

    2014-06-01

    Full Text Available In this work, a variety of highly substituted quinolines were readily synthesized via Friedlander annulation using Brönsted acid silica-based sulfonic acid as a modified catalyst under solvent-free conditions at room temperature. This efficient procedure has the advantages of giving the target compounds in high yields, short reaction times, simple workup procedure, reusability of the catalyst, and environmentally benign conditions.

  10. Study of the Recombination of H2 and O2 at Ambient Temperature

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    The hydrophobic catalysts was developed at Chalk River Nuclear Laboratories and was used in the recombiner operated at ambient conditions. The advantage of operating a recombiner at ambient temperature were recognized by several researchers. It is clear that significant savings can be realized if the recombiner is operated at ambient temperature without the need for costly heaters and coolers. And the process is safer and more uncomplicated than conventional processes.The experimental conditions as followings: carrier gas is Ar; concentration of H2 is 1%;

  11. Impact of ambient temperature on spring-based relative gravimeter measurements

    Science.gov (United States)

    Fores, B.; Champollion, C.; Moigne, N. Le; Chery, J.

    2016-10-01

    In this paper, we investigate the impact of ambient temperature changes on the gravity reading of spring-based relative gravimeters. Controlled heating experiments using two Scintrex CG5 gravimeters allowed us to determine a linear correlation (R 2> 0.9) between ambient temperature and gravity variations. The relation is stable and constant for the two CG5 we used: -5 nm/s2/° C. A linear relation is also seen between gravity and residual sensor temperature variations (R 2> 0.75), but contrary to ambient temperature, this relation is neither constant over time nor similar between the two instruments. The linear correction of ambient temperature on the controlled heating time series reduced the standard deviation at least by a factor of 2, to less than 10 nm/s2 . The laboratory results allowed for reprocessing the data gathered on a field survey that originally aimed to characterize local hydrological heterogeneities on a karstic area. The correction of two years of monthly CG5 measurements from ambient temperature variations halved the standard deviation (from 62 to 32 nm/s2 ) and led us to a better hydrological interpretation. Although the origin of this effect is uncertain, we suggest that an imperfect control of the sensor temperature may be involved, as well as a change of the properties of an electronic component.

  12. Comparability of tympanic and oral mercury thermometers at high ambient temperatures

    Directory of Open Access Journals (Sweden)

    Chue Amy L

    2012-07-01

    Full Text Available Abstract Background Body temperature can be measured in seconds with tympanic thermometers as opposed to minutes with mercury ones. The aim of this study was to compare tympanic and oral mercury thermometer measurements under high ambient field temperatures. Results Tympanic temperature (measured thrice by 3 operators was compared to oral temperature measured once with a mercury-in-glass thermometer in 201 patients (aged ≥5 years, on the Thai-Myanmar border. Ambient temperature was measured with an electronic thermo-hygrometer. Participants had a mean [min-max] age of 27 [5–60] years and 42% (84 were febrile by oral thermometer. The mean difference in the mercury and tympanic temperature measurement for all observers/devices was 0.09 (95%CI 0.07-0.12°C and intra-class correlation for repeat tympanic measurements was high (≥0.97 for each observer. Deviations in tympanic temperatures were not related to ambient temperature. Conclusion Clinically significant differences were not observed between oral and tympanic temperature measurements at high ambient temperatures in a rural tropical setting.

  13. Interactions Between Housing Density and Ambient Temperature in the Cage Environment: Effects on Mouse Physiology and Behavior

    OpenAIRE

    Toth, Linda A; Trammell, Rita A; Ilsley-Woods, Megan

    2015-01-01

    To determine how housing density and ambient temperature interact to influence the physiology and behavior of mice, we systematically varied housing density (1 to 5 mice per cage) and ambient temperature (22, 26, or 30 °C) and measured effects on body weight, food intake, diurnal patterns of locomotor activity and core temperature, fecal corticosterone, and serum cytokine and adipokine panels. Temperatures inside cages housing 5 mice were 1 to 2 °C higher than the ambient temperature. As the ...

  14. Influence of ambient temperature and diurnal temperature range on incidence of cardiac arrhythmias

    Science.gov (United States)

    Kim, Jayeun; Kim, Ho

    2016-08-01

    We investigated the association between ambient temperature and diurnal temperature range (DTR) and the exacerbation of arrhythmia symptoms, using data from 31,629 arrhythmia-related emergency department (ED) visits in Seoul, Korea. Linear regression analyses with allowances for over-dispersion were applied to temperature variables and ED visits, adjusted for various environmental factors. The effects were expressed as percentage changes in the risk of arrhythmia-related ED visits up to 5 days later, with 95 % confidence intervals (CI), per 1 °C increase in DTR and 1 °C decrease in mean temperature. The overall risk of ED visits increased by 1.06 % (95 % CI 0.39 %, 1.73 %) for temperature and by 1.84 % (0.34, 3.37 %) for DTR. A season-specific effect was detected for temperature during both fall (1.18 % [0.01, 2.37 %]) and winter (0.87 % [0.07, 1.67 %]), and for DTR during spring (3.76 % [0.34, 7.29 %]). Females were more vulnerable, with 1.57 % [0.56, 2.59 %] and 3.84 % [1.53, 6.20 %] for the changes in temperature and DTR, respectively. An age-specific effect was detected for DTR, with 3.13 % [0.95, 5.36 %] for age ≥ 65 years, while a greater increased risk with temperature decrease was observed among those aged <65 (1.08 % [0.17, 2.00 %]) than among those aged ≥65 (1.02 % [0.06, 1.99 %]). Cardiac arrest was inversely related with temperature (1.61 % [0.46, 2.79 %]), while other cardiac arrhythmias depended more on the change in DTR (4.72 % [0.37, 9.26 %]). These findings provide evidence that low-temperature and elevated DTR influence the occurrence of arrhythmia exacerbations or symptoms, suggesting a possible strategy for reducing risk by encouraging vulnerable populations to minimize exposure.

  15. Effects of ambient oxygen concentration on soot temperature and concentration for biodiesel and diesel spray combustion

    KAUST Repository

    Zhang, Ji

    2015-06-01

    Ambient oxygen concentration, a key variable directly related to exhaust gas recirculation (EGR) levels in diesel engines, plays a significant role in particulate matter (PM) and nitrogen oxides (NOx) emissions. The utilization of biodiesel in diesel engines has been investigated over the last decades for its renewable characteristics and lower emissions compared to diesel. In an earlier work, we demonstrated that the soot temperature and concentration of biodiesel were lower than diesel under regular diesel engine conditions without EGR. Soot concentration was quantified by a parameter called KL factor. As a continuous effort, this paper presents an experimental investigation of the ambient oxygen concentration on soot temperature and KL factor during biodiesel and diesel spray combustion. The experiment was implemented in a constant volume chamber system, where the ambient oxygen concentration varied from 21 to 10% and the ambient temperature was kept to 1,000 K. A high speed two-color pyrometry technique was used to measure transient soot temperature and the KL factor of the spray flame. The soot temperature of biodiesel is found to be lower than that of diesel under the same conditions, which follows the same trend from our previous results found when the ambient temperature changes to 21% oxygen conditions. A reduction in ambient oxygen concentration generally reduces the soot temperature for both fuels. However, this is a complicated effect on soot processes as the change of oxygen concentration greatly affects the balance between soot formation and oxidation. The KL factor is observed to be the highest at 12% O2 for diesel and 18% O2 for biodiesel, respectively. On the other hand, the 10% O2 condition shows the lowest KL factor for both fuels. These results can provide quantitative experimental evidences to optimize the ambient oxygen concentration for diesel engines using different fuels for better emissions characteristics. © 2014 American Society of

  16. Fuelling of TCA cycle in hepatic cells Marwari goat during ambient temperature associated stress

    Directory of Open Access Journals (Sweden)

    Kataria N.

    2010-11-01

    Full Text Available The present study was launched to assess the effect of extreme ambient temperature associated stress on fuelling of TCA cycle in hepatic cells of Marwari goat. Based on the fact that whenever a hepatocyte needs fuel for TCA cycle, the activity of enzyme glutamate dehydrogenase (GD increases making alpha-ketoglutarate available for TCA cycle, 600 apparently healthy Marwari goats of either sex, between 6 months to 3 years of age were screened and blood samples were collected during moderate, cold and hot ambient temperature periods to determine the serum glutamate dehydrogenase enzyme and glucose concentration. The mean value of serum GD was significantly (p≤0.05 higher during cold and hot ambient temperature periods in comparison to overall moderate mean value. However, the rise was greater in cold (2.20 times than hot ambient temperature (1.19 times. The serum GD activity was higher in male and younger animals. Serum glucose concentration showed a reverse trend as compared to serum GD activity. The results indicated that in cold condition associated stress the fuelling to TCA cycle was more than moderate and hot ambient temperature periods. Serum GD activity was also found related with glucose homeostasis. Further the study has shown that variations in the enzyme levels are not always pathological and while interpreting clinical data, a clinician must consider these variations.

  17. Experimental and casework validation of ambient temperature corrections in forensic entomology.

    Science.gov (United States)

    Johnson, Aidan P; Wallman, James F; Archer, Melanie S

    2012-01-01

    This paper expands on Archer (J Forensic Sci 49, 2004, 553), examining additional factors affecting ambient temperature correction of weather station data in forensic entomology. Sixteen hypothetical body discovery sites (BDSs) in Victoria and New South Wales (Australia), both in autumn and in summer, were compared to test whether the accuracy of correlation was affected by (i) length of correlation period; (ii) distance between BDS and weather station; and (iii) periodicity of ambient temperature measurements. The accuracy of correlations in data sets from real Victorian and NSW forensic entomology cases was also examined. Correlations increased weather data accuracy in all experiments, but significant differences in accuracy were found only between periodicity treatments. We found that a >5°C difference between average values of body in situ and correlation period weather station data was predictive of correlations that decreased the accuracy of ambient temperatures estimated using correlation. Practitioners should inspect their weather data sets for such differences.

  18. Consequences of fluctuations in the ambient air temperature at Lake Tanganyika --- A wavelet analysis

    OpenAIRE

    Mbungu Tsumbu, Jean-Pierre; Antoine, Jean-Pierre; Bopili-Mbotia-Lepiba, Richard

    2014-01-01

    We study the fluctuations of the horizontal wind speed and of both the ambient air temperature and the water temperature according to the depth. Our study clearly shows how Lake Tanganyika is thermally stratified, showing four different water layers. The study shows how waters of upper layers tend to have the same temperature as the deepest water during the dry season. The water stratification tends then to disappear completely in the dry season. The study is based on the fact that water rele...

  19. Influence of volume working fluid and ambient temperature on cooling efficiency of loop thermosyphon

    Directory of Open Access Journals (Sweden)

    Nemec P.

    2014-03-01

    Full Text Available Article deal with research of device for electrical component cooling used to heat transfer working fluid phase change. Amount of heat flux transferred by thermosyphon loop depend from amount working fluid and from ambient temperature where is heat removal too. In article is described proposal construction of thermosyphon loop, comparisons of his cooling efficiency if is filled 40 % and 50 % volume of working fluid and condenser (ambient temperature from 20, 30 up to 40 °C at heat load from 40 to 360 W.

  20. Dependence of electric strength on the ambient temperature

    Energy Technology Data Exchange (ETDEWEB)

    Čaja, Alexander, E-mail: alexander.caja@fstroj.uniza.sk, E-mail: patrik.nemec@fstroj.uniza.sk, E-mail: milan.malcho@fstroj.uniza.sk; Nemec, Patrik, E-mail: alexander.caja@fstroj.uniza.sk, E-mail: patrik.nemec@fstroj.uniza.sk, E-mail: milan.malcho@fstroj.uniza.sk; Malcho, Milan, E-mail: alexander.caja@fstroj.uniza.sk, E-mail: patrik.nemec@fstroj.uniza.sk, E-mail: milan.malcho@fstroj.uniza.sk [University of Žilina, Faculty of Mechanical Engineering, Department of Power Engeneering, Univerzitná 1, 010 26 Žilina (Slovakia)

    2014-08-06

    At present, the volume concentration of electronic components in their miniaturization to different types of microchips and increasing their performance raises the problem of cooling such elements due to the increasing density of heat flow of heat loss. Compliance with safe operating temperature of active semiconductor element is very closely related to the reliability and durability not only components, but also the entire device. Often it is also necessary to electrically isolate the unit from the side of the cooler air. Cooling demand by natural convection is typical for applications with high operating reliability. To the reliability of the system for removing heat loss increased, it is necessary to minimize need to use the mechanically or electrically powered elements, such as circulation pumps or fans. Experience to date with applications of heat pipe in specific systems appears to be the most appropriate method of cooling.

  1. Quantum Coherent Dynamics at Ambient Temperature in Photosynthetic Molecules

    CERN Document Server

    Walters, Zachary B

    2011-01-01

    Photosynthetic antenna complexes are responsible for absorbing energy from sunlight and transmitting it to remote locations where it can be stored. Recent experiments have found that this process involves long-lived quantum coherence between pigment molecules, called chromophores, which make up these complexes. Expected to decay within 100 fs at room temperature, these coherences were instead found to persist for picosecond time scales, despite having no apparent isolation from the thermal environment of the cell. This paper derives a quantum master equation which describes the coherent evolution of a system in strong contact with a thermal environment. Conditions necessary for long coherence lifetimes are identified, and the role of coherence in efficient energy transport is illuminated. Static spectra and exciton transfer rates for the PE545 complex of the cryptophyte algae CS24 are calculated and shown to have good agreement with experiment.

  2. Dependence of electric strength on the ambient temperature

    International Nuclear Information System (INIS)

    At present, the volume concentration of electronic components in their miniaturization to different types of microchips and increasing their performance raises the problem of cooling such elements due to the increasing density of heat flow of heat loss. Compliance with safe operating temperature of active semiconductor element is very closely related to the reliability and durability not only components, but also the entire device. Often it is also necessary to electrically isolate the unit from the side of the cooler air. Cooling demand by natural convection is typical for applications with high operating reliability. To the reliability of the system for removing heat loss increased, it is necessary to minimize need to use the mechanically or electrically powered elements, such as circulation pumps or fans. Experience to date with applications of heat pipe in specific systems appears to be the most appropriate method of cooling

  3. Impact of Seasonal Variant Temperatures and Laboratory Room Ambient Temperature on Mortality of Rats with Ischemic Brain Injury

    Science.gov (United States)

    Gopalakrishanan, Sivakumar; Babu, Mg. Ramesh; Thangarajan, Rajesh; Punja, Dhiren; Jaganath, Vidyadhara Devarunda; Kanth, Akriti B.; Rao, Mohandas

    2016-01-01

    Introduction A popular rat model for hypoperfusion ischemic brain injury is bilateral common carotid artery occlusion (BCCAO). BCCAO surgery when performed in varying geographical locations and during different seasons of the year is reported to have variable mortality rates. Studies have also documented the diminishing influence of Ketamine-Xylazine (KT-XY) on thermoregulatory functions in rodents. Aim To explore the impact of seasonal variant temperatures and laboratory room ambient temperatures on mortality of rats following BCCAO surgery. Materials and Methods The study has two parts: 1 The first part is an analysis of a three year retrospective data to explore the association between the geographical season (hot summer and cold winter) induced laboratory room ambient temperature variations and the mortality rate in KT-XY anaesthetized BCCAO rats. 2. The second part investigated the effect of conditioned laboratory room ambient temperature (CAT) (23-250C) in KT-XY anaesthetized BCCAO group of rats. Rats were divided into 4 groups(n =8/group) as-Normal control, BCCAO and Sham BCCAO where they were all exposed to unconditioned ambient temperature (UCAT) during their surgery and postoperative care. And finally fourth group rats exposed to CAT during the BCCAO surgery and postoperative care. Results Pearson’s chi-square test indicates a significantly high association (p<0.006) between post-BCCAO mortality and hot season of the year. CAT during the hot season reduced the mortality rate (24% less) in post- BCCAO rats compared to the rats of UCAT. Conclusion Despite seasonal variations in temperature, conditioning the laboratory room ambient temperatures to 23–250C, induces hypothermia in KT-XY anaesthetized ischemic brain injured rodents and improves their survival rate. PMID:27190796

  4. Ambient temperature cured TiB2 cathode coating for aluminum electrolysis

    Institute of Scientific and Technical Information of China (English)

    赖延清; 李庆余; 杨建红; 李劼

    2003-01-01

    The concept of ambient temperature curable TiB2 cathode coating was put forward, and the ambient temperature curable TiB2 cathode coating was prepared successfully. Differing from the previous TiB2 cathode coating solidified approximately at 200 ℃,the ambient temperature curable TiB2 cathode coating can be solidified at room temperature, so the heating equipment is not necessary, which simplifies the preparation process and facilitates the industrial application of TiB2 cathode coating. Many kinds of resin and curing agent were investigated. On the above-mentioned basis, the ambient temperature curable TiB2 cathode coating was prepared with furan resin 5 500 mixed with complex resins B as carbon binder and DXG1 as curing agent in 24 h. The results show that the properties of prepared coating are excellent, the electrical resistivity is 29.8 μΩ*m, the compressive strength is 33.6 MPa, which are all better than the relevant properties of partially graphitized cathode carbon block for aluminum electrolysis prescribed by the GB 8744-88. SEM morphologies show that the section morphology of the TiB2 coating is unaltered during the electrolysis test, the TiB2 coating can be used in aluminum electrolysis industry to save energy and prolong the life of aluminum electrolysis cell.

  5. Influence of the ambient temperature during heat pipe manufacturing on its function and heat transport ability

    Directory of Open Access Journals (Sweden)

    Čaja A.

    2014-03-01

    Full Text Available Heat pipe is heat transfer device working at a minimum temperature difference of evaporator and condenser. Operating temperature of the heat pipe determine by properties of the working substance and pressure achieved during production. The contribution is focused on the determining the effect of the initial surrounding temperature where the heat pipe is manufactured and on the obtaining performance characteristics produced heat pipes in dependence of manufacturing temperature. Generally hold, that the boiling point of the working liquid decrease with decreasing ambient pressure. Based on this can be suppose that producing of lower ambient temperature during heat pipe manufacturing, will create the lower pressure, the boiling point of the working fluid will lower too and the heat pipe should be better performance characteristics.

  6. Soot measurements for diesel and biodiesel spray combustion under high temperature highly diluted ambient conditions

    KAUST Repository

    Zhang, Ji

    2014-11-01

    This paper presents the soot temperature and KL factor for biodiesel, namely fatty acid methyl ester (FAME) and diesel fuel combustion in a constant volume chamber using a two-color technique. The KL factor is a parameter for soot concentration, where K is an absorption coefficient and proportional to the number density of soot particles, L is the geometric thickness of the flame along the optical detection axis, and KL factor is proportional to soot volume fraction. The main objective is to explore a combustion regime called high-temperature and highly-diluted combustion (HTHDC) and compare it with the conventional and low-temperature combustion (LTC) modes. The three different combustion regimes are implemented under different ambient temperatures (800 K, 1000 K, and 1400 K) and ambient oxygen concentrations (10%, 15%, and 21%). Results are presented in terms of soot temperature and KL factor images, time-resolved pixel-averaged soot temperature, KL factor, and spatially integrated KL factor over the soot area. The time-averaged results for these three regimes are compared for both diesel and biodiesel fuels. Results show complex combined effects of the ambient temperature and oxygen concentration, and that two-color temperature for the HTHDC mode at the 10% oxygen level can actually be lower than the conventional mode. Increasing ambient oxygen and temperature increases soot temperature. Diesel fuel results in higher soot temperature than biodiesel for all three regimes. Results also show that diesel and biodiesel fuels have very different burning and sooting behavior under the three different combustion regimes. For diesel fuel, the HTHDC regime offers better results in terms of lower soot than the conventional and LTC regimes, and the 10% O2, 1400 K ambient condition shows the lowest soot concentration while maintaining a moderate two-color temperature. For biodiesel, the 15% O2, 800 K ambient condition shows some advantages in terms of reducing soot

  7. Ambient pressure synthesis of MIL-100(Fe) MOF from homogeneous solution using a redox pathway.

    Science.gov (United States)

    Jeremias, Felix; Henninger, Stefan K; Janiak, Christoph

    2016-05-17

    Micro- to mesoporous iron(iii) trimesate MIL-100(Fe) is a MOF of high interest for numerous applications. With regard to large-scale synthesis, e.g., by continuous flow or the in situ deposition of coatings, a replacement for the conventional, hydrothermal low-yield fluoride-containing synthesis is desirable. In this contribution, we present a method to synthesize crystalline fluoride-free MIL-100(Fe) from iron(iii) nitrate and trimesic acid in zeotropic DMSO/water solution at normal ambient pressure involving a DMSO-nitrate redox pathway. Yields of 72%, surface areas of SBET = 1791 m(2) g(-1) and pore volumes of Vpore = 0.82 cm(3) g(-1) were achieved. PMID:27143562

  8. Effects of Elevated Ambient Temperature on Reproductive Outcomes and Offspring Growth Depend on Exposure Time

    Directory of Open Access Journals (Sweden)

    Huda Yahia Hamid

    2012-01-01

    Full Text Available Reproductive performance has been shown to be greatly affected by changes in environmental factors, such as temperature. However, it is also crucial to identify the particular stage of pregnancy that is most adversely affected by elevated ambient temperature. The aims of this study were to determine the effect on reproductive outcomes of exposure to elevated ambient temperature during different stages of pregnancy and to determine the effect of prenatal heat stress on offspring growth. Sixty pregnant rats were used in this study. The rats were divided equally into four groups as group 1 (control, group 2 (exposed to elevated temperature following implantation, group 3 (exposed to elevated temperature during pre- and periimplantation, and group 4 (exposed to elevated temperature during pre- and periimplantation and following implantation. Groups 3 and 4 had prolonged gestation periods, reduced litter sizes, and male-biased sex ratios. Moreover, the growth patterns of group 3 and 4 pups were adversely affected by prenatal exposure to elevated temperature. The differences between group 1 and group 3 and between group 1 and group 4 were highly significant. However, no significant differences were observed between groups 1 and 2 in the gestation length, sex ratios, and growth patterns. Thus, it can be concluded that exposure to elevated ambient temperature during pre- and periimplantation has stronger adverse effects on reproductive outcomes and offspring growth than postimplantation exposure.

  9. Evaporative cooling for lactating sows under high ambient temperature

    Directory of Open Access Journals (Sweden)

    Charles Kiefer

    2012-05-01

    Full Text Available Two experiments were conducted to evaluate the evaporative cooling of the air at farrowing on the performance of lactating sows under high environmental temperature conditions in the Central West region of Brazil. One hundred and forty-four lactating sows - 46 of first and second farrowing (experiment I and 98 from the third to eighth farrowing (experiment II - were used. Sows were distributed in experimental design of randomized blocks consisting of two rooms (with air cooling and control, with the sow as the experimental unit. The average duration of lactation was 21 days. Sows were fed ad libitum with the same lactation diet. In experiment I, the air cooling increased the daily feed intake, reduced the total and percent weight loss, increased the weight of the piglets and litters at weaning and improved the daily milk production of sows. However, the air cooling did not affect the weight of the sows or the number of piglets at weaning. In experiment II the air cooling increased the daily feed intake of the sows, reduced the total and percent weight loss, increased the weight and the weight gain of the piglets and litters and improved the daily milk production of the sows. Air cooling enables the increase of the daily feed intake and, therefore, of nutrients by the sows, with consequent reduction of mobilization of body reserves and the increase in the milk production and in the weight of piglets and litters at weaning, regardless the farrowing order of the sow.

  10. SRF Performance of CEBAF After Thermal Cycle to Ambient Temperature

    CERN Document Server

    Rimmer, Robert; Preble, Joseph P; Reece, Charles E

    2005-01-01

    In September 2003, in the wake of Hurricane Isabel, JLab was without power for four days after a tree fell on the main power lines feeding the site. This was long enough to lose insulating vacuum in the cryomodules and cryogenic systems resulting in the whole accelerator warming up and the total loss of the liquid helium inventory. This thermal cycle stressed many of the cryomodule components causing several cavities to become inoperable due to helium to vacuum leaks. At the same time the thermal cycle released years of adsorbed gas from the cold surfaces. Over the next days and weeks this gas was pumped away, the insulating vacuum was restored and the machine was cooled back down and re-commissioned. In a testament to the robustness of SRF technology, only a small loss in energy capability was apparent, although individual cavities had quite different field-emission characteristics compared to before the event. In Summer 2004 a section of the machine was again cycled to room temperature during the long maint...

  11. Manufacturing Demonstration Facility: Low Temperature Materials Synthesis

    Energy Technology Data Exchange (ETDEWEB)

    Graham, David E [ORNL; Moon, Ji Won [ORNL; Armstrong, Beth L [ORNL; Datskos, Panos G [ORNL; Duty, Chad E [ORNL; Ivanov, Ilia N [ORNL; Jang, Gyoung Gug [Oak Ridge National Laboratory (ORNL); Jellison Jr, Gerald Earle [ORNL; Joshi, Pooran C [ORNL; Meyer III, Harry M [ORNL; Phelps, Tommy [ORNL

    2016-07-01

    The Manufacturing Demonstration Facility (MDF) low temperature materials synthesis project was established to demonstrate a scalable and sustainable process to produce nanoparticles (NPs) for advanced manufacturing. Previous methods to chemically synthesize NPs typically required expensive, high-purity inorganic chemical reagents, organic solvents and high temperatures. These processes were typically applied at small laboratory scales at yields sufficient for NP characterization, but insufficient to support roll-to-roll processing efforts or device fabrication. The new NanoFermentation processes described here operated at a low temperature (~60 C) in low-cost, aqueous media using bacteria that produce extracellular NPs with controlled size and elemental stoichiometry. Up-scaling activities successfully demonstrated high NP yields and quality in a 900-L pilot-scale reactor, establishing this NanoFermentation process as a competitive biomanufacturing strategy to produce NPs for advanced manufacturing of power electronics, solid-state lighting and sensors.

  12. Manufacturing Demonstration Facility: Low Temperature Materials Synthesis

    Energy Technology Data Exchange (ETDEWEB)

    Graham, David E. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Moon, Ji-Won [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Armstrong, Beth L. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Datskos, Panos G. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Duty, Chad E. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Gresback, Ryan [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Ivanov, Ilia N. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Jacobs, Christopher B. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Jellison, Gerald Earle [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Jang, Gyoung Gug [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Joshi, Pooran C. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Jung, Hyunsung [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Meyer, III, Harry M. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Phelps, Tommy [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2015-06-30

    The Manufacturing Demonstration Facility (MDF) low temperature materials synthesis project was established to demonstrate a scalable and sustainable process to produce nanoparticles (NPs) for advanced manufacturing. Previous methods to chemically synthesize NPs typically required expensive, high-purity inorganic chemical reagents, organic solvents and high temperatures. These processes were typically applied at small laboratory scales at yields sufficient for NP characterization, but insufficient to support roll-to-roll processing efforts or device fabrication. The new NanoFermentation processes described here operated at a low temperature (~60 C) in low-cost, aqueous media using bacteria that produce extracellular NPs with controlled size and elemental stoichiometry. Up-scaling activities successfully demonstrated high NP yields and quality in a 900-L pilot-scale reactor, establishing this NanoFermentation process as a competitive biomanufacturing strategy to produce NPs for advanced manufacturing of power electronics, solid-state lighting and sensors.

  13. Why cross-national differences in role overload? Don't overlook ambient temperature!

    NARCIS (Netherlands)

    Van de Vliert, E.; Van Yperen, N.W.

    1996-01-01

    The finding that, across nations, power distance (expected and accepted unequal interpersonal influence) Is positively related to role overload (Peterson et al., 1995) might he an artifact of the relation between role overload and ambient temperature or other third factors. We related data on power

  14. Gold-Catalyzed Aerobic Oxidation of 5-Hydroxymethylfurfural in Water at Ambient Temperature

    DEFF Research Database (Denmark)

    Gorbanev, Yury; Kegnæs, Søren; Woodley, John;

    2009-01-01

    The aerobic oxidation of 5-hydroxymethylfurfural, a versatile biomass-derived chemical, is examined in water with a titania-supported gold-nanoparticle catalyst at ambient temperature (30 degrees C). The selectivity of the reaction towords 2,5-furandicarboxylic acid and the intermediate oxidation...

  15. Water-free Alkaline Polymer-inorganic Acid Complexes with High Conductivity at Ambient Temperature

    Institute of Scientific and Technical Information of China (English)

    O.V.Chervakov; M.V.Andriianova; V.V.Riabenko; A.V.Markevich; E.M.Shembel; D.Meshri

    2007-01-01

    1 Results Recently increased interest is shown to proton conducting materials based on the alkaline polymer-inorganic acid complexes that is caused by a possibility of their application as the high-temperature electrolyte systems for various electrochemical devices (fuel cells,sensors,lithium power sources etc.).Complexes of inorganic acids with the alkaline polymers (polybenzimidazoles[1],polyvinylpyridines[2]) are characterized by high ionic conductivity at ambient temperatures (up to 10-2 Ω-1·cm-1) a...

  16. SPATIAL VARIABILTY OF AMBIENT TEMPERATURE, RELATIVE HUMIDITY AND AIR VELOCITY IN A COLD STORE

    OpenAIRE

    SERAP AKDEMIR; SELCUK ARIN

    2006-01-01

    Spatial distribution the ambient temperature, relative humidity and air velocity were determined for different storage temperatures such as 0 oC, 1 oC, 2 oC and 3 oC in an experimental cold store. Mapping software were used to show the variability. Spatial distribution of the temperature and the relative humidity was not uniform in the cold store. Reason of bad spatial distributions was bad spatial distribution of air velocity distributed by evaporator. A temperature and/or a relative humi...

  17. The influence of heated or cooled seats on the acceptable ambient temperature range

    DEFF Research Database (Denmark)

    Zhang, Y.F.; Wyon, David Peter; Fang, Lei;

    2007-01-01

    In 11 climate chamber experiments at air temperatures ranging from 15 to 45 degrees C, a total of 24 subjects, dressed in appropriate clothing for entering a vehicle at these temperatures, were each exposed to four different seat temperatures, ranging from cool to warm. In one simulated summer...... continuously. At each ambient room temperature, the percentage dissatisfied was found to be a second-order polynomial function of local heat flow. Zero heat flow was preferred at an air temperature of 22 degrees C and the heat flow that minimized the percentage dissatisfied was found to be a single linear...... function of air temperature in all conditions. The analysis indicates that providing optimal seat temperature would extend the conventional 80% acceptable range of air temperature for drivers and passengers in vehicle cabins by 9.3 degrees C downwards and by 6.4 degrees C upwards....

  18. The monitoring and fatigue behavior of CFCCs at ambient temperature and 1000{degrees}C

    Energy Technology Data Exchange (ETDEWEB)

    Miriyala, N.; Liaw, P.K.; McHargue, C.J. [Univ. of Tennessee, Knoxville, TN (United States)] [and others

    1997-04-01

    Metallographically polished flexure bars of Nicalon/SiC and Nicalon/alumina composites were subjected to monotonic and cycle-fatigue loadings, with loading either parallel or normal to the fabric plies. The fabric orientation did not significantly affect the mechanical behavior of the Nicalon/SiC composite at ambient temperature. However, the mechanical behavior of the Nicalon/alumina composite was significantly affected by the fabric orientation at ambient temperature in air and at 1000{degrees}C in argon atmosphere. In addition, there was a significant degradation in the fatigue performance of the alumina matrix composite at the elevated temperature, owing to creep in the material and degradation in the fiber strength.

  19. Effect of ambient temperatures on disinfection efficiency of various sludge treatment technologies.

    Science.gov (United States)

    Bauerfeld, Katrin

    2014-01-01

    Sewage sludge produced during municipal wastewater treatment has to be treated efficiently in order to reduce impacts on the environment and on public health. In Germany and many countries, large quantities of sludge are reused in agriculture in order to recycle nutrients and organic material. In order to quantify the effect of different ambient temperatures on conventional and advanced sludge treatment technologies as well as on disinfection efficiency, a comprehensive research study was performed at Braunschweig Institute of Technology. The detailed results show that ambient temperature has a strong effect on biological liquid sludge stabilization and on natural dewatering and drying technologies, although microbiological quality of treated sludge, indicated by Escherichia coli concentration, does not meet the requirements for unrestricted reuse in agriculture. Composting and lime treatment of sludge are most efficient on reducing E. coli, as high temperatures and high pH values arise in the material respectively.

  20. The Importance of Ambient Temperature to Growth and the Induction of Flowering.

    Science.gov (United States)

    McClung, C R; Lou, Ping; Hermand, Victor; Kim, Jin A

    2016-01-01

    Plant development is exquisitely sensitive to the environment. Light quantity, quality, and duration (photoperiod) have profound effects on vegetative morphology and flowering time. Recent studies have demonstrated that ambient temperature is a similarly potent stimulus influencing morphology and flowering. In Arabidopsis, ambient temperatures that are high, but not so high as to induce a heat stress response, confer morphological changes that resemble the shade avoidance syndrome. Similarly, these high but not stressful temperatures can accelerate flowering under short day conditions as effectively as exposure to long days. Photoperiodic flowering entails a series of external coincidences, in which environmental cycles of light and dark must coincide with an internal cycle in gene expression established by the endogenous circadian clock. It is evident that a similar model of external coincidence applies to the effects of elevated ambient temperature on both vegetative morphology and the vegetative to reproductive transition. Further study is imperative, because global warming is predicted to have major effects on the performance and distribution of wild species and strong adverse effects on crop yields. It is critical to understand temperature perception and response at a mechanistic level and to integrate this knowledge with our understanding of other environmental responses, including biotic and abiotic stresses, in order to improve crop production sufficiently to sustainably feed an expanding world population. PMID:27602044

  1. The importance of ambient temperature to growth and the induction of flowering.

    Directory of Open Access Journals (Sweden)

    C. Robertson Mcclung

    2016-08-01

    Full Text Available Plant development is exquisitely sensitive to the environment. Light quantity, quality, and duration (photoperiod have profound effects on vegetative morphology and flowering time. Recent studies have demonstrated that ambient temperature is a similarly potent stimulus influencing morphology and flowering. In Arabidopsis, ambient temperatures that are high, but not so high as to induce a heat stress response, confer morphological changes that resemble the shade avoidance syndrome. Similarly, these high but not stressful temperatures can accelerate flowering under short day conditions as effectively as exposure to long days. Photoperiodic flowering entails a series of external coincidences, in which environmental cycles of light and dark must coincide with an internal cycle in gene expression established by the endogenous circadian clock. It is evident that a similar model of external coincidence applies to the effects of elevated ambient temperature on both vegetative morphology and the vegetative to reproductive transition. Further study is imperative, because global warming is predicted to have major effects on the performance and distribution of wild species and strong adverse effects on crop yields. It is critical to understand temperature perception and response at a mechanistic level and to integrate this knowledge with our understanding of other environmental responses, including biotic and abiotic stresses, in order to improve crop production sufficiently to sustainably feed an expanding world population.

  2. Effects of Imidapril on Venous Blood Gas Values in Broiler Chickens Exposed to Low Ambient Temperature

    Institute of Scientific and Technical Information of China (English)

    Xueqin HAO; Meng LI; Shouyan ZHANG; Yongshu WANG; Tongwen SUN

    2013-01-01

    [Objective] This study was designed to evaluate the effects of imidapril on blood gas parameters in broiler chickens.[Method] Twenty-four chickens were randomly divided into three groups (n=8),control group,low temperature group and imidapril group.Chickens in low temperature group and imidapril group were exposed to low ambient temperature (12-18 ℃) from age at 14 d to 45 d,whereas the control group was exposed to 24-30 ℃; chickens in imidapril group were gavaged with imidapril (3 mg/kg) once daily for 30 d.At age of 45 d,blood was taken from wing vein and blood gas parameters were evaluated by blood gas analyzer in Luoyang Central Hospital Affiliated to Zhengzhou University.[Result] Imidapril significantly increased hematocrit (HCT) and total hemoglobin content (THBC) and blood Na concentration in broiler chickens exposed to low ambient temperature.No significant differences were observed in pH,Pco2,Po2,K+,Ca2+,HCO3-,HCO3std,Tco2,BE and SO2c.[Conclusion] Imidapril increases hematocrit,total hemoglobin content and blood Na+concentration in chickens exposed to low ambient temperature.

  3. Design of Cold-Formed Steel Screw Connections with Gypsum Sheathing at Ambient and Elevated Temperatures

    Directory of Open Access Journals (Sweden)

    Wei Chen

    2016-09-01

    Full Text Available Load-bearing cold-formed steel (CFS walls sheathed with double layers of gypsum plasterboard on both sides have demonstrated good fire resistance and attracted increasing interest for use in mid-rise CFS structures. As the main connection method, screw connections between CFS and gypsum sheathing play an important role in both the structural design and fire resistance of this wall system. However, studies on the mechanical behavior of screw connections with double-layer gypsum sheathing are still limited. In this study, 200 monotonic tests of screw connections with single- or double-layer gypsum sheathing at both ambient and elevated temperatures were conducted. The failure of screw connections with double-layer gypsum sheathing in shear was different from that of single-layer gypsum sheathing connections at ambient temperature, and it could be described as the breaking of the loaded sheathing edge combined with significant screw tilting and the loaded sheathing edge flexing fracture. However, the screw tilting and flexing fracture of the loaded sheathing edge gradually disappear at elevated temperatures. In addition, the influence of the loaded edge distance, double-layer sheathing and elevated temperatures is discussed in detail with clear conclusions. A unified design formula for the shear strength of screw connections with gypsum sheathing is proposed for ambient and elevated temperatures with adequate accuracy. A simplified load–displacement model with the post-peak branch is developed to evaluate the load–displacement response of screw connections with gypsum sheathing at ambient and elevated temperatures.

  4. Temperature oscillations near natural nuclear reactor cores and the potential for prebiotic oligomer synthesis.

    Science.gov (United States)

    Adam, Zachary R

    2016-06-01

    Geologic settings capable of driving prebiotic oligomer synthesis reactions remain a relatively unexplored aspect of origins of life research. Natural nuclear reactors are an example of Precambrian energy sources that produced unique temperature fluctuations. Heat transfer models indicate that water-moderated, convectively-cooled natural fission reactors in porous host rocks create temperature oscillations that resemble those employed in polymerase chain reaction (PCR) devices to artificially amplify oligonucleotides. This temperature profile is characterized by short-duration pulses up to 70-100 °C, followed by a sustained period of temperatures in the range of 30-70 °C, and finally a period of relaxation to ambient temperatures until the cycle is restarted by a fresh influx of pore water. For a given reactor configuration, temperature maxima and the time required to relax to ambient temperatures depend most strongly on the aggregate effect of host rock permeability in decreasing the thermal expansion and increasing the viscosity and evaporation temperature of the pore fluids. Once formed, fission-fueled reactors can sustain multi-kilowatt-level power production for 10(5)-10(6) years, ensuring microenvironmental longevity and chemical output. The model outputs indicate that organic synthesis on young planetary bodies with a sizeable reservoir of fissile material can involve more sophisticated energy dissipation pathways than modern terrestrial analog settings alone would suggest.

  5. Temperature oscillations near natural nuclear reactor cores and the potential for prebiotic oligomer synthesis.

    Science.gov (United States)

    Adam, Zachary R

    2016-06-01

    Geologic settings capable of driving prebiotic oligomer synthesis reactions remain a relatively unexplored aspect of origins of life research. Natural nuclear reactors are an example of Precambrian energy sources that produced unique temperature fluctuations. Heat transfer models indicate that water-moderated, convectively-cooled natural fission reactors in porous host rocks create temperature oscillations that resemble those employed in polymerase chain reaction (PCR) devices to artificially amplify oligonucleotides. This temperature profile is characterized by short-duration pulses up to 70-100 °C, followed by a sustained period of temperatures in the range of 30-70 °C, and finally a period of relaxation to ambient temperatures until the cycle is restarted by a fresh influx of pore water. For a given reactor configuration, temperature maxima and the time required to relax to ambient temperatures depend most strongly on the aggregate effect of host rock permeability in decreasing the thermal expansion and increasing the viscosity and evaporation temperature of the pore fluids. Once formed, fission-fueled reactors can sustain multi-kilowatt-level power production for 10(5)-10(6) years, ensuring microenvironmental longevity and chemical output. The model outputs indicate that organic synthesis on young planetary bodies with a sizeable reservoir of fissile material can involve more sophisticated energy dissipation pathways than modern terrestrial analog settings alone would suggest. PMID:26680444

  6. Temperature oscillations near natural nuclear reactor cores and the potential for prebiotic oligomer synthesis

    Science.gov (United States)

    Adam, Zachary R.

    2016-06-01

    Geologic settings capable of driving prebiotic oligomer synthesis reactions remain a relatively unexplored aspect of origins of life research. Natural nuclear reactors are an example of Precambrian energy sources that produced unique temperature fluctuations. Heat transfer models indicate that water-moderated, convectively-cooled natural fission reactors in porous host rocks create temperature oscillations that resemble those employed in polymerase chain reaction (PCR) devices to artificially amplify oligonucleotides. This temperature profile is characterized by short-duration pulses up to 70-100 °C, followed by a sustained period of temperatures in the range of 30-70 °C, and finally a period of relaxation to ambient temperatures until the cycle is restarted by a fresh influx of pore water. For a given reactor configuration, temperature maxima and the time required to relax to ambient temperatures depend most strongly on the aggregate effect of host rock permeability in decreasing the thermal expansion and increasing the viscosity and evaporation temperature of the pore fluids. Once formed, fission-fueled reactors can sustain multi-kilowatt-level power production for 105-106 years, ensuring microenvironmental longevity and chemical output. The model outputs indicate that organic synthesis on young planetary bodies with a sizeable reservoir of fissile material can involve more sophisticated energy dissipation pathways than modern terrestrial analog settings alone would suggest.

  7. The association between ambient temperature and children's lung function in Baotou, China

    Science.gov (United States)

    Li, Shanshan; Guo, Yuming; Williams, Gail; Baker, Peter; Ye, Xiaofang; Madaniyazi, Lina; Kim, Dae-Seon; Pan, Xiaochuan

    2015-07-01

    The objective of this study is to examine the association between ambient temperature and children's lung function in Baotou, China. We recruited 315 children (8-12 years) from Baotou, China in the spring of 2004, 2005, and 2006. They performed three successive forced expiratory measurements three times daily (morning, noon, and evening) for about 5 weeks. The highest peak expiratory flow (PEF) was recorded for each session. Daily data on ambient temperature, relative humidity, and air pollution were monitored during the same period. Mixed models with a distributed lag structure were used to examine the effects of temperature on lung function while adjusting for individual characteristics and environmental factors. Low temperatures were significantly associated with decreases in PEF. The effects lasted for lag 0-2 days. For all participants, the cumulative effect estimates (lag 0-2 days) were -1.44 (-1.93, -0.94) L/min, -1.39 (-1.92, -0.86) L/min, -1.40 (-1.97, -0.82) L/min, and -1.28 (-1.69, -0.88) L/min for morning, noon, evening, and daily mean PEF, respectively, associated with 1 °C decrease in daily mean temperature. Generally, the effects of temperature were slightly stronger in boys than in girls for noon, evening, and daily mean PEF, while the effects were stronger in girls for morning PEF. PM2.5 had joint effects with temperature on children's PEF. Higher PM2.5 increased the impacts of low temperature. Low ambient temperatures are associated with lower lung function in children in Baotou, China. Preventive health policies will be required for protecting children from the cold weather.

  8. Ambient Temperature and Stroke Occurrence: A Systematic Review and Meta-Analysis.

    Science.gov (United States)

    Wang, Xia; Cao, Yongjun; Hong, Daqing; Zheng, Danni; Richtering, Sarah; Sandset, Else Charlotte; Leong, Tzen Hugh; Arima, Hisatomi; Islam, Shariful; Salam, Abdul; Anderson, Craig; Robinson, Thompson; Hackett, Maree L

    2016-01-01

    Biologically plausible associations exist between climatic conditions and stroke risk, but study results are inconsistent. We aimed to summarize current evidence on ambient temperature and overall stroke occurrence, and by age, sex, and variation of temperature. We performed a systematic literature search across MEDLINE, Embase, PsycINFO, CINAHL, Web of Science, and GEOBASE, from inception to 16 October 2015 to identify all population-based observational studies. Where possible, data were pooled for meta-analysis with Odds ratios (OR) and corresponding 95% confidence intervals (CI) by means of the random effects meta-analysis. We included 21 studies with a total of 476,511 patients. The data were varied as indicated by significant heterogeneity across studies for both ischemic stroke (IS) and intracerebral hemorrhage (ICH). Pooled OR (95% CI) in every 1 degree Celsius increase in ambient temperature was significant for ICH 0.97 (0.94-1.00), but not for IS 1.00 (0.99-1.01) and subarachnoid hemorrhage (SAH) 1.00 (0.98-1.01). Meta-analysis was not possible for the pre-specified subgroup analyses by age, sex, and variation of temperature. Change in temperature over the previous 24 h appeared to be more important than absolute temperature in relation to the risk of stroke, especially in relation to the risk of ICH. Older age appeared to increase vulnerability to low temperature for both IS and ICH. To conclude, this review shows that lower mean ambient temperature is significantly associated with the risk of ICH, but not with IS and SAH. Larger temperature changes were associated with higher stroke rates in the elderly. PMID:27420077

  9. Modeling Temperature Development of Li-Ion Battery Packs in Hybrid Refuse Truck Operating at Different Ambient Conditions

    DEFF Research Database (Denmark)

    Coman, Paul Tiberiu; Veje, Christian

    2014-01-01

    This paper presents a dynamic model for simulating the heat dissipation and the impact of Phase Change Materials (PCMs) on the peak temperature in Lithium-ion batteries during discharging operation of a hybrid truck under different ambient temperatures.......This paper presents a dynamic model for simulating the heat dissipation and the impact of Phase Change Materials (PCMs) on the peak temperature in Lithium-ion batteries during discharging operation of a hybrid truck under different ambient temperatures....

  10. Effect of Ambient Temperature on Body Temperature and Rest Metabolic Rate in Apodemus chevrieri During Postnatal Development

    Directory of Open Access Journals (Sweden)

    Zhu Wan-long

    2014-05-01

    Full Text Available In order to investigate the ability of constant temperature and thermoregulation in Apodemus chevrieri, body temperature and rest metabolic rate (RMR were measured during postnatal development (1~42 day when the A. chevrieri exposed different ambient temperature. The result showed that: body temperature and RMR of pups in A. chevrieri increased according to the increase of ambient temperature during 1 day to 7 day, showed character of poikilotherms; body temperature of pups were lower in low temperature(5oC and 10oC, relatively and RMR significant increased when day age is 14 day, it indicated that the pups showed a certain degree of thermoregulation in this phase. Its thermoregulation ability developed quickly during 7 day to 14 day. RMR of pups was extreme significantly higher in low temperature than that in other temperature when day age was 21 day, it showed that the pups had some thermoregulation to low temperature stimulation. The RMR of pups was showed increasing trend in high temperature(35oC when 28 day; when day age was 35 day and 42 day, the thermal neutral zone were 22.5 to 30oC and approaching its adult level. All of these results indicated that pups of A. chevrieri in the different growing period had different thermogenesis and energy allocation to maintain stable to body temperature, thermogenesis was weaker in the early phase of postnatal development, most of energy is used to its growth. After pups were weaned, the ability of constant temperature and thermoregulation developed quickly to adjust variations of environment during postnatal development.

  11. Ambient temperature nanoelectrospray ion mobility detector for high performance liquid chromatography in determining amines.

    Science.gov (United States)

    Chen, Chuang; Hou, Keyong; Wang, Weiguo; Li, Jinghua; Li, Haiyang

    2014-09-01

    A nanoelectrospray ionization ion mobility spectrometer (nanoESI-IMS) working at ambient pressure and ambient temperature was developed as a detector of high performance liquid chromatography (HPLC) to achieve sensitive detection of amines with no derivatization and meanwhile provide another dimension of separation. The easier desolvation property of the charged droplets formed in nanoESI source enabled complete desolvation of the product ions of sixteen amines and drugs using the nanoESI-IMS at ambient temperature. Working at ambient temperature was good for suppressing the dissociation of thermal volatile ions, such as only the proton adducted molecular ions were observed for morphine in the nanoESI-IMS. Besides, the resolving power of the nanoESI-IMS also showed an increasing tendency as lowering the working temperature, an increment of 19 percent and 10 percent was observed for diethylamine and triethylamine as the temperature dropped from 92°C to 32°C. The resolving power of the nanoESI-IMS at 32°C for the 16 tested compounds was amid 33-44. With the nanoESI-IMS coupled to HPLC, a six-compound mixture including isomers was successfully separated and detected without any derivatization. And linear response ranges of 1 to 20, 0.5 to 20, and 0.8 to 20μgml(-1) and limits of detection of 0.25, 0.15, and 0.17μgml(-1) for triethylamine, diethylamine, and butylamine, respectively, were obtained with the hyphenated system. These results showed the excellent performance of the two-dimensional separation and detection method in direct qualitative and quantitative analyses of amines.

  12. Effects of ambient temperature on energy and nitrogen utilization in lipopolysaccharide-challenged growing pigs.

    Science.gov (United States)

    Campos, P H R F; Labussière, E; Hernández-García, J; Dubois, S; Renaudeau, D; Noblet, J

    2014-11-01

    High ambient temperature impacts feed intake, growth, and nutrient utilization in pigs. However, little is known on its effects on immune function and, therefore, on how or if it could modulate the utilization of nutrients in pigs exposed to an inflammatory challenge. The aim of this study was to evaluate the effects of high ambient temperature on energy and nitrogen utilization in pigs submitted to repeated injections of Escherichia coli lipopolysaccharide (LPS). Twenty-eight catheterized and pair-housed female pigs (55 kg BW) were assigned to 1 of the 2 thermal conditions: thermoneutrality (TN, 24°C) or high ambient temperature (HT, 30°C). Within each condition, pigs had a 2-wk adaptation period in climatic-controlled rooms and then were transferred to open-circuit respiration chambers. Pigs remained in respiration chambers for a period of 18 d, which was divided into a 7-d period without LPS (baseline) and a subsequent 11-d period with LPS administration (LPSperiod). The interaction between ambient temperature and period was not significant for most of the traits studied. At baseline, pigs kept at HT had lower ADFI (1,500 vs. 2,003 g/d; P thermic effect of feeding (P = 0.01) and resting HP (P < 0.01). In addition, the LPS induced a reduction in protein (P < 0.01) and fat deposition (P = 0.01) in pigs kept at TN (-79 and -73 g/d, respectively) and at HT (-41 and -44 g/d, respectively). In conclusion, our study confirms that high temperature reduces feed intake, growth performance, and HP. Moreover, our results evidence that irrespective of thermal condition, an inflammatory LPS challenge affects energy utilization through changes in ME intake and maintenance requirements. PMID:25349341

  13. Fatigue monitoring and analysis of orthotropic steel deck considering traffic volume and ambient temperature

    Institute of Scientific and Technical Information of China (English)

    SONG; YongSheng; DING; YouLiang

    2013-01-01

    Fatigue has gradually become a serious issue for orthotropic steel deck used for long-span bridges. Two fatigue effects, namely number of stress cycles and equivalent stress amplitude, were introduced as investigated parameters in this paper. Investigation was focused on their relationships with traffic volume and ambient temperature by using 7-months fatigue monitoring data of an actual bridge. A fatigue analytical model considering temperature-induced changes in material property of asphalt pavement was established for verifying these relationships. The analysis results revealed that the number of stress cycles and equivalent stress amplitude showed a linear correlation with the traffic volume and ambient temperature, respectively, and that the rib-to-deck welded joint was much more sensitive to the traffic volume and ambient temperature than the rib-to-rib welded joint. The applicability of the code-recommended model for fatigue vehicle loading was also discussed, which revealed that the deterministic vehicle loading model requires improvement to account for significant randomness of the actual traffic conditions.

  14. Analyzing the impact of ambient temperature indicators on transformer life in different regions of Chinese mainland.

    Science.gov (United States)

    Bai, Cui-fen; Gao, Wen-Sheng; Liu, Tong

    2013-01-01

    Regression analysis is applied to quantitatively analyze the impact of different ambient temperature characteristics on the transformer life at different locations of Chinese mainland. 200 typical locations in Chinese mainland are selected for the study. They are specially divided into six regions so that the subsequent analysis can be done in a regional context. For each region, the local historical ambient temperature and load data are provided as inputs variables of the life consumption model in IEEE Std. C57.91-1995 to estimate the transformer life at every location. Five ambient temperature indicators related to the transformer life are involved into the partial least squares regression to describe their impact on the transformer life. According to a contribution measurement criterion of partial least squares regression, three indicators are conclusively found to be the most important factors influencing the transformer life, and an explicit expression is provided to describe the relationship between the indicators and the transformer life for every region. The analysis result is applicable to the area where the temperature characteristics are similar to Chinese mainland, and the expressions obtained can be applied to the other locations that are not included in this paper if these three indicators are known.

  15. Test of oxidation behavior of sulfide ores at ambient temperature for fire control

    Institute of Scientific and Technical Information of China (English)

    WU Chao; LI Zi-jun; LI Ming; WU Guo-min

    2007-01-01

    The coincidence of relevant factors, e.g. oxygen absorption quantity, weight increment, water soluble iron ions and sulfate ion of sulfide ore samples in the oxidation process, was tested through experiment. Based on a large number of tests for a group sample of sulfide ores from a mine, some important conclusions were obtained. The results obtained by the investigation indicate that there is no general interpretation relative to the oxygen absorption and the formation products of sulfate ion and water soluble iron ions during the oxidation process of sulfide ores at ambient temperature. However, the weight increment of the sulfide ore samples in the oxidation process at ambient temperature has a linear relationship with the quantity of oxygen absorption.

  16. Evaluation of Aluminum Alloy 2050-T84 Microstructure and Mechanical Properties at Ambient and Cryogenic Temperatures

    Science.gov (United States)

    Hafley, Robert A.; Domack, Marcia S.; Hales, Stephen J.; Shenoy, Ravi N.

    2011-01-01

    Aluminum alloy 2050 is being considered for the fabrication of cryogenic propellant tanks to reduce the mass of future heavy-lift launch vehicles. The alloy is available in section thicknesses greater than that of the incumbent aluminum alloy, 2195, which will enable designs with greater structural efficiency. While ambient temperature design allowable properties are available for alloy 2050, cryogenic properties are not available. To determine its suitability for use in cryogenic propellant tanks, tensile, compression and fracture tests were conducted on 4 inch thick 2050-T84 plate at ambient temperature and at -320degF. Various metallurgical analyses were also performed in order to provide an understanding of the compositional homogeneity and microstructure of 2050.

  17. Evaluation of Aluminum Alloy 2050-T84 Microstructure Mechanical Properties at Ambient and Cryogenic Temperatures

    Science.gov (United States)

    Hafley, Robert A.; Domack, Marcia S.; Hales, Stephen J.; Shenoy, Ravi N.

    2011-01-01

    Aluminum alloy 2050 is being considered for the fabrication of cryogenic propellant tanks to reduce the mass of future heavy-lift launch vehicles. The alloy is available in section thicknesses greater than that of the incumbent aluminum alloy, 2195, which will enable the designs with greater structural efficiency. While ambient temperature design allowable properties are available for alloy 2050, cryogenic properties are not available. To determine its suitability for use in cryogenic propellant tanks, tensile, compression and fracture tests were conducted on 4 inch thick 2050-T84 plate at ambient temperature and at -320 F. Various metallurgical analyses were also performed in order to provide an understanding of the compositional homogeneity and microstructure of 2050.

  18. Ambient temperature: a factor affecting performance and physiological response of broiler chickens

    Science.gov (United States)

    Donkoh, A.

    1989-12-01

    An experiment was conducted to elucidate the influence of four constant ambient temperatures (20°, 25°, 30° and 35°C) on the performance and physiological reactions of male commercial broiler chicks from 3 to 7 weeks of age. A 12 h light-dark cycle was operated, while relative humidity and air circulation were not controlled. Exposure of broiler chickens to the 20°, 25°, 30° and 35°C treatments showed highly significant ( Pchickens, there was an increased blood glucose concentration and a decreased thyroid gland weight. These results indicate that continuous exposure of broiler chickens to high ambient temperatures markedly affects their performance and physiological response.

  19. Detritiation of type 316 stainless steel by treatment with liquids at ambient temperature

    Science.gov (United States)

    Penzhorn, Ralf-Dieter; Torikai, Y.; Matsuyama, M.; Watanabe, K.

    2006-07-01

    The detritiation efficiency of type 316 stainless steel (SS316) using liquids reagents (distilled deionized water, concentrated aqueous ammonia or a diluted hydrochloric acid/nitric acid mixture) was investigated at ambient temperature by means of liquid scintillation counting (LSC) and β-ray-induced X-ray spectrometry (BIXS). After a fast initial removal of tritium trapped on the outermost surface of SS316 with a rate in the order water SS316 specimen. From a practical point of view, the release rate of tritium into liquids is too slow for conditioning applications. Complementary evidence for the occurrence of a chronic liberation of tritium from SS316 into air at ambient temperature was obtained from tritium depth profiling of aged specimens by acid etching.

  20. Comprehensive particle characterization of modern gasoline and diesel passenger cars at low ambient temperatures

    Science.gov (United States)

    Mathis, Urs; Mohr, Martin; Forss, Anna-Maria

    Particle measurements were performed in the exhaust of five light-duty vehicles (Euro-3) at +23, -7, and -20 °C ambient temperatures. The characterization included measurements of particle number, active surface area, number size distribution, and mass size distribution. We investigated two port-injection spark-ignition (PISI) vehicles, a direct-injection spark-ignition (DISI) vehicle, a compressed ignition (CI) vehicle with diesel particle filter (DPF), and a CI vehicle without DPF. To minimize sampling effects, particles were directly sampled from the tailpipe with a novel porous tube diluter at controlled sampling parameters. The diluted exhaust was split into two branches to measure either all or only non-volatile particles. Effect of ambient temperature was investigated on particle emission for cold and warmed-up engine. For the gasoline vehicles and the CI vehicle with DPF, the main portion of particle emission was found in the first minutes of the driving cycle at cold engine start. The particle emission of the CI vehicle without DPF was hardly affected by cold engine start. For the PISI vehicles, particle number emissions were superproportionally increased in the diameter size range from 0.1 to 0.3 μm during cold start at low ambient temperature. Based on the particle mass size distribution, the DPF removed smaller particles ( dp0.5μm). No significant effect of ambient temperature was observed when the engine was warmed up. Peak emission of volatile nanoparticles only took place at specific conditions and was poorly repeatable. Nucleation of particles was predominately observed during or after strong acceleration at high speed and during regeneration of the DPF.

  1. Association between Ambient Temperature and Acute Myocardial Infarction Hospitalisations in Gothenburg, Sweden: 1985–2010

    OpenAIRE

    Janine Wichmann; Annika Rosengren; Karin Sjöberg; Lars Barregard; Gerd Sallsten

    2013-01-01

    Cardiovascular disease (CVD) is the number one cause of death globally and evidence is steadily increasing on the role of non-traditional risk factors such as meteorology and air pollution. Nevertheless, many research gaps remain, such as the association between these non-traditional risk factors and subtypes of CVD, such as acute myocardial infarction (AMI). The objective of this study was to investigate the association between daily ambient temperature and AMI hospitalisations using a case-...

  2. Moisture Stable Ambient Temperature Ionic Liquids: Solvents for the New Millennium. 1. The Heck Reaction

    Directory of Open Access Journals (Sweden)

    Andrea Dallas

    2000-06-01

    Full Text Available In this paper we report examples of the Heck reaction in the new moisture stable ambient temperature ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate ([bmim]PF6. We have found that the yield of product is comparable with Heck reactions carried out in DMF, the conventional solvent for this reaction, and that the ionic liquid/catalyst mixture can be recycled several times.

  3. Dynamical prediction of flu seasonality driven by ambient temperature: influenza vs. common cold

    Science.gov (United States)

    Postnikov, Eugene B.

    2016-01-01

    This work presents a comparative analysis of Influenzanet data for influenza itself and common cold in the Netherlands during the last 5 years, from the point of view of modelling by linearised SIRS equations parametrically driven by the ambient temperature. It is argued that this approach allows for the forecast of common cold, but not of influenza in a strict sense. The difference in their kinetic models is discussed with reference to the clinical background.

  4. Psychophysics of a nociceptive test in the mouse: ambient temperature as a key factor for variation.

    Directory of Open Access Journals (Sweden)

    Ivanne Pincedé

    Full Text Available BACKGROUND: The mouse is increasingly used in biomedical research, notably in behavioral neurosciences for the development of tests or models of pain. Our goal was to provide the scientific community with an outstanding tool that allows the determination of psychophysical descriptors of a nociceptive reaction, which are inaccessible with conventional methods: namely the true threshold, true latency, conduction velocity of the peripheral fibers that trigger the response and latency of the central decision-making process. METHODOLOGY/PRINCIPAL FINDINGS: Basically, the procedures involved heating of the tail with a CO(2 laser, recording of tail temperature with an infrared camera and stopping the heating when the animal reacted. The method is based mainly on the measurement of three observable variables, namely the initial temperature, the heating rate and the temperature reached at the actual moment of the reaction following random variations in noxious radiant heat. The initial temperature of the tail, which itself depends on the ambient temperature, very markedly influenced the behavioral threshold, the behavioral latency and the conduction velocity of the peripheral fibers but not the latency of the central decision-making. CONCLUSIONS/SIGNIFICANCE: We have validated a psychophysical approach to nociceptive reactions for the mouse, which has already been described for rats and Humans. It enables the determination of four variables, which contribute to the overall latency of the response. The usefulness of such an approach was demonstrated by providing new fundamental findings regarding the influence of ambient temperature on nociceptive processes. We conclude by challenging the validity of using as "pain index" the reaction time of a behavioral response to an increasing heat stimulus and emphasize the need for a very careful control of the ambient temperature, as a prevailing environmental source of variation, during any behavioral testing of

  5. Correlations among factors of sulfide ores in oxidation process at ambient temperature

    Institute of Scientific and Technical Information of China (English)

    吴超; 李孜军; 周勃

    2004-01-01

    Spontaneous combustion is one of the serious problems in the mining of sulfide ore deposits. The relevant factors, e. G. Oxygen absorption quantity, mass increase, contents of water soluble iron ions and sulfate ion of sulfide ore samples in the oxidation process were investigated both in theory and experiment. The results from the investigation show that there is no general interpretation relation among the oxygen absorption quantity, the contents of sulfate ion and water soluble iron ions during the oxidation process of sulfide ores at ambient temperature.However, there is a linear relationship between the mass increase of the sulfide ore samples in the oxidation process at ambient temperature and the quantity of oxygen absorption. Therefore, the simple and cheap mass scaling method is suitable for predicting the oxygen absorption performance of sulfide ores at ambient temperature in place of the expensive and complicated chemical method used hitherto. Furthermore, combined with other items of breeding-fire test, the mass increase potential can also be used to predict the spontaneous combustion tendency of sulfide ores.

  6. Ambient air pollution, temperature and out-of-hospital coronary deaths in Shanghai, China

    International Nuclear Information System (INIS)

    Few studies have evaluated the effects of ambient air pollution and temperature in triggering out-of-hospital coronary deaths (OHCDs) in China. We evaluated the associations of air pollution and temperature with daily OHCDs in Shanghai, China from 2006 to 2011. We applied an over-dispersed generalized additive model and a distributed lag nonlinear model to analyze the effects of air pollution and temperature, respectively. A 10 μg/m3 increase in the present-day PM10, PM2.5, SO2, NO2 and CO were associated with increases in OHCD mortality of 0.49%, 0.68%, 0.88%, 1.60% and 0.08%, respectively. A 1 °C decrease below the minimum-mortality temperature corresponded to a 3.81% increase in OHCD mortality on lags days 0–21, and a 1 °C increase above minimum-mortality temperature corresponded to a 4.61% increase over lag days 0–3. No effects were found for in-hospital coronary deaths. This analysis suggests that air pollution, low temperature and high temperature may increase the risk of OHCDs. - Highlights: • Few studies have evaluated the effects of air pollution and temperature on OHCDs in China. • The present-day concentrations of air pollution were associated with OHCDs. • The effect of high temperatures on OHCDs was more immediate than low temperatures. • No significant effects were found for in-hospital coronary deaths. - Ambient air pollution and temperature may trigger out-of-hospital coronary deaths but not in-hospital coronary deaths

  7. THE INFLUENCE OF OBESITY AND AMBIENT TEMPERATURE ON PHYSIOLOGICAL AND OXIDATIVE RESPONSES TO SUBMAXIMAL EXERCISE

    OpenAIRE

    Ahn, N; Kim, K

    2014-01-01

    This study investigated the effects of obesity and ambient temperature on physiological responses and markers of oxidative stress to submaximal exercise in obese and lean people. Sixteen healthy males were divided into an obese group (n=8, %fat: 27.00±3.00%) and a lean group (n=8, %fat: 13.85±2.45%). Study variables were measured during a 60 min submaximal exercise test at 60% VO2max in a neutral (21±1°C) and a cold (4±1°C) environment. Heart rate, blood lactate, rectal temperature, serum lev...

  8. Effect of ambient temperature on endurance performance while wearing cross-country skiing clothing.

    Science.gov (United States)

    Sandsund, Mariann; Saursaunet, Vegard; Wiggen, Øystein; Renberg, Julie; Færevik, Hilde; van Beekvelt, Mireille C P

    2012-12-01

    This study assessed the effects of exposure to cold (-14 and -9 °C), cool (-4 and 1 °C) and moderate warm (10 and 20 °C) environments on aerobic endurance performance-related variables: maximal oxygen consumption (VO(2max)), running time to exhaustion (TTE), running economy and running speed at lactate threshold (LT). Nine male endurance athletes wearing cross-country ski racing suit performed a standard running test at six ambient temperatures in a climatic chamber with a wind speed of 5 m s(-1). The exercise protocol consisted of a 10-min warm-up period followed by four submaximal periods of 5 min at increasing intensities between 67 and 91 % of VO(2max) and finally a maximal test to exhaustion. During the time course mean skin temperature decreased significantly with reduced ambient temperatures whereas T (re) increased during all conditions. T (re) was lower at -14 °C than at -9 and 20 °C. Running economy was significantly reduced in warm compared to cool environments and was also reduced at 20 °C compared to -9 °C. Running speed at LT was significantly higher at -4 °C than at -9, 10 and 20 °C. TTE was significantly longer at -4 and 1 °C than at -14, 10 and 20 °C. No significant differences in VO(2max) were found between the various ambient conditions. The optimal aerobic endurance performance wearing a cross-country ski racing suit was found to be -4 and 1 °C, while performance was reduced under moderate warm (10 and 20 °C) and cold (-14 and -9 °C) ambient conditions.

  9. Thermal responses and perceptions under distinct ambient temperature and wind conditions.

    Science.gov (United States)

    Shimazaki, Yasuhiro; Yoshida, Atsumasa; Yamamoto, Takanori

    2015-01-01

    Wind conditions are widely recognized to influence the thermal states of humans. In this study, we investigated the relationship between wind conditions and thermal perception and energy balance in humans. The study participants were exposed for 20 min to 3 distinct ambient temperatures, wind speeds, and wind angles. During the exposure, the skin temperatures as a physiological reaction and mental reactions of the human body were measured and the energy balance was calculated based on the human thermal-load method. The results indicate that the human thermal load is an accurate indicator of human thermal states under all wind conditions. Furthermore, wind speed and direction by themselves do not account for the human thermal experience. Because of the thermoregulation that occurs to prevent heat loss and protect the core of the body, a low skin temperature was maintained and regional differences in skin temperature were detected under cool ambient conditions. Thus, the human thermal load, which represents physiological parameters such as skin-temperature change, adequately describes the mixed sensation of the human thermal experience.

  10. Synthesis of metal-nitrides using high pressures and temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Guillaume, C; Serghiou, G [University of Edinburgh, School of Engineering and Electronics, Kings Buildings, Mayfield Road, EH9 3JL UK (United Kingdom); Morniroli, J P [Laboratoire de Metallurgie Physique et Genie des Materiaux, UMR CNRS 8517, Universite des Sciences et Technologies de Lille et Ecole Nationale Superieure de Chimie de Lille, Cite Scientifique, 59655 Villeneuve d' Ascq Cedex (France); Frost, D J [Bayerisches Geoinstitut, Universitat Bayreuth, D-95440, Bayreuth (Germany)], E-mail: george.serghiou@ed.ac.uk

    2008-07-15

    Technologically, high density nitrides are showing promise for both ceramic and electronic applications. In a laser-heated diamond cell we prepare high density metal-nitrides by reaction of the nitrogen pressure medium with an elemental substrate. Two of our objectives are to develop criteria governing whether denser than ambient nitride phases will form, and to in particular establish the parameters required for synthesis in a multianvil press using elemental starting materials. We have already synthesized transition metal nitrides in a multianvil press using elemental starting materials, including hexagonal nickel nitride and alkali rhenium nitrides. Unlike previous metals, we also report that Cu does not form a nitride after heating with NaN{sub 3} at 2000 K and 20 GPa. Notably, Cu{sub 3}N is a semiconductor exhibiting weak directional bonds, whereas the immediately adjacent lower atomic number systems are metallic interstitial nitrides. We also briefly mention our work on processing high pressure and temperature recovered reaction products with focused ion beam methods for tailored characterization using electron microscopy.

  11. Influence of ambient temperature on prolactin concentrations in serum of Holstein and Brahman x Hereford heifers.

    Science.gov (United States)

    Wettermann, R P; Tucker, H A; Beck, T W; Meyerhoeffer, D C

    1982-08-01

    Four Holstein and four Brahman x Hereford heifers about 8 mo of age were used in a study to determine whether breed influences the effects of ambient temperature on concentrations' of prolactin in serum. Two heifers of each breed were stanchioned in each of two environmental chambers at 21 C for 7 d, after which chamber temperatures were changed to 7 or 31 C during 6 h. After 5 d at 7, 21 or 31 C, heifers were injected with 60 micrograms thyrotropin-releasing hormone (TRH). A switch-back design was used and each heifer was exposed to all treatments. Concentrations of prolactin in serum of heifers during exposure to 7, 21 or 31 C for 5 d were related to ambient temperature (9.0, 20.9 and 29.5 ng/ml, respectively; P less than .001), but the response was not influenced by breed. Heifers of both breeds responded similarly to treatment with TRH, and prolactin in serum increased (P less than .001) within 5 min from 7.0 +/- 3.2 to 45.7 +/- 8.2 ng/ml in heifers at 7 C, from 13.1 +/- 1.6 to 97.2 +/- 9.6 ng/ml in heifers at 21 C and from 18.2 +/- 3.5 to 96.2 +/- 11.3 ng/ml in heifers at 31 C. We conclude that concentrations of prolactin in serum of heifers are positively associated with ambient temperature and that the effects of temperature on basal and TRH-stimulated concentrations of prolactin do not differ significantly between Holstein and Brahman x Hereford heifers. Thus, differences in tolerance to heat were not related to differences in prolactin secretion. PMID:6815150

  12. Modeling the dependency of radon concentration levels inside ancient Egyptian tombs on the ambient temperature variations

    International Nuclear Information System (INIS)

    Radon concentration inside partially closed places like dwellings, caves and tombs, depends on many parameters. Some parameters are known quantitatively as radon exhalation rate for walls, decay constant, surface to volume ratio and outdoor concentration while other parameters as ventilation rate is in common known qualitatively due to useless of traditional methods (tracer gases) in many places as ancient Egyptian tombs. This work introduces a derived mathematical model to evaluate the sensitivity of radon concentration levels inside single sided opening places as ancient Egyptian tombs on the ambient temperature differences. The obtained formula for the natural ventilation rate depends on the indoor and outdoor temperature difference and the geometrical dimensions of the doorway. The effects of in and out flow mixing, air viscosity, streamline contraction, swirling flow and turbulence, were taken into consideration in terms of an empirical correction factor. According UNSCEAR reports, the exhalation rate Φ=Craλrn fρs(1-ε)L; Cra the effective radium content, λrn decay constant, f emanation fraction, ρs soil grain density, ε porosity and L diffusion length, these are approximately static parameters but the variability of ambient temperature introduces a source of energy of fluctuating strength to radon atoms in rocks which controls the flow rate and the ambient content of radon. Therefore, the change of outdoor and indoor temperature difference causes fluctuation of value and direction of volume flow rate in such places consequently causes the daily variation and on average the seasonal variation of radon concentration. Therefore according to the present model, the daily accurate expectation of radon concentrations inside ancient Egyptian tombs, require precise measurements of indoor and outdoor temperatures

  13. On exhaust emissions from petrol-fuelled passenger cars at low ambient temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Laurikko, J. [VTT Energy, Espoo (Finland). Energy Use

    1998-11-01

    The study at hand deals with regulated and unregulated exhaust emissions from petrol-fuelled cars at low ambient temperatures with present-day or near-future exhaust after treatment systems. The subject has been investigated at VTT over a decade and this report compiles data from various sub-studies carried out between the years 1993 - 1997. Each one of them viewed different aspects of the phenomenon, like determining the low-temperature response of today`s new cars employing three-way catalytic converters or assessing the long-term durability and the influence of vehicle mileage upon the low-temperature emissions performance. Within these studies, together more than 120 cars of model years from 1990 to 1997 have been tested. Most of them were normal, in-service vehicles with total mileages differing between only a few thousand kilometres for new cars up to 80,000 km or even more for the in-use vehicles. Both the US FTP75 and the European test cycle have been employed, and the ambient temperatures ranged from the baseline (+22 deg C) down to +- O deg C, -7 deg C and in some cases even to -20 deg C. The studies attested that new cars having today`s advanced emissions control systems produced fairly low levels of emissions when tested in conditions designated in the regulations that are the basis of the current new-vehicle certification. However, this performance was not necessarily attained at ambient temperatures that were below the normative range. Fairly widespread response was recorded, and cars having almost equal emissions output at baseline could produce largely deviating outcomes in low-temperature conditions. On average, CO and HC emissions increased by a factor of five to 10, depending on the ambient temperature and vehicle type. However, emissions of NO{sub x} were largely unaffected. Apart from these regulated emissions, many unregulated species were also determined, either by using traditional sampling and chromatography methods or on-line, employing

  14. On exergy analysis of industrial plants and significance of ambient temperature

    Energy Technology Data Exchange (ETDEWEB)

    Rian, Berit

    2011-07-01

    The exergy analysis has been a relatively mature theory for more than 30 years. However, it is not that developed in terms of procedures for optimizing systems, which partly explains why it is not that common. Misconceptions and prejudices, even among scientists, are also partly to blame.The main objective of this work was to contribute to the development of an understanding and methodology of the exergy analysis. The thesis was mainly based on three papers, two of which provided very different examples from existing industrial systems in Norway, thus showing the societal perspective in terms of resource utilization and thermodynamics. The last paper and the following investigation were limited to certain aspects of ambient conditions. Two Norwegian operational plants have been studied, one operative for close to 30 years (Kaarstoe steam production and distribution system), while the other has just started its expected 30 years of production (Snoehvit LNG plant). In addition to mapping the current operational status of these plants, the study of the Kaarstoe steam production and distribution system concluded that the potential for increasing the thermodynamic performance by rather cautious actions was significant, whereas the study of the Snoehvit LNG plant showed the considerable profit which the Arctic location provided in terms of reduced fuel consumption. The significance of the ambient temperature led to the study of systems with two ambient bodies (i.e. ambient water and ambient air) of different temperatures, here three different systems were investigated: A regenerative steam injection gas turbine (RSTIG), a simple Linde air liquefaction plant (Air Liq) and an air-source heat pump water heater (HPWH). In particular, the effect of the chosen environment on exergy analysis was negligible for RSTIG, modest for Air Liq and critical for HPWH. It was found that the amount of exergy received from the alternative ambient body, compared to the main exergy flow of

  15. Cyclic deformation behaviour of austenitic steels at ambient and elevated temperatures

    Indian Academy of Sciences (India)

    Th Nebel; D Eifler

    2003-02-01

    The aim of the present investigation is to characterise cyclic deformation behaviour and plasticity-induced martensite formation of metastable austenitic stainless steels at ambient and elevated temperatures, taking into account the influence of the alloying elements titanium and niobium. Titanium and niobium are ferrite-stabilising elements which influence the ferrite crystallisation. Furthermore, They form carbides and/or carbonitrides and thus limit the austenite-stabilising effect of carbon and nitrogen. Several specimen batches of titanium and niobium alloyed austenite and of a pure Cr-Ni-steel for comparison were tested under stress and total strain control at a frequency of 5 Hz and triangular load-time waveforms. Stress-strain-hysteresis and temperature measurements were used at ambient temperature to characterise cyclic deformation behaviour. Plasticity-induced martensite content was detected with non-destructive magnetic measuring techniques. The experiments yield characteristic cyclic deformation curves and corresponding magnetic signals according to the actual fatigue state and the amount of martensite. Fatigue behaviour of X6CrNiTi1810 (AISI 321), X10CrNiCb189 (AISI 348) and X5CrNi1810 (AISI 304) is characterised by cyclic hardening and softening effects which are strongly influenced by specific loading conditions. Martensite formation varies with the composition, loading conditions, temperature and number of cycles.

  16. Changes in ambient temperature at the onset of thermoregulatory responses in exercise-trained rats

    Science.gov (United States)

    Sugimoto, N.; Sakurada, S.; Shido, O.

    Spontaneous running in a wheel has emerged as a useful method of exercise in rodents. We investigated how exercise training with a running wheel affects ambient temperatures (Ta) at the onset of thermoregulatory responses in rats. Female rats were allowed to run freely in the wheel for 6 months. Sedentary control rats did not exercise during the same period. After the exercise training period, they were loosely restrained and Ta values at the onset of tail skin vasodilation and cold- induced thermogenesis were determined by raising or lowering Ta. Resting levels of core temperature and heat production of the exercise-trained rats were significantly higher than those of the controls. Ta values at the onset of tail skin vasodilation and cold-induced thermogenesis of the exercise-trained rats were higher than those of the controls. The results suggest that, in rats, exercise training with a running wheel elevates ambient temperatures for heat loss and heat production, which may then contribute to maintaining the core temperature at a high level.

  17. Deformation at ambient and high temperature of in situ Laves phases-ferrite composites

    International Nuclear Information System (INIS)

    The mechanical behavior of a Fe80Zr10Cr10 alloy has been studied at ambient and high temperature. This Fe80Zr10Cr10 alloy, whoose microstructure is formed by alternate lamellae of Laves phase and ferrite, constitutes a very simple example of an in situ CMA phase composite. The role of the Laves phase type was investigated in a previous study while the present work focuses on the influence of the microstructure length scale owing to a series of alloys cast at different cooling rates that display microstructures with Laves phase lamellae width ranging from ∼50 nm to ∼150 nm. Room temperature compression tests have revealed a very high strength (up to 2 GPa) combined with a very high ductility (up to 35%). Both strength and ductility increase with reduction of the lamella width. High temperature compression tests have shown that a high strength (900 MPa) is maintained up to 873 K. Microstructural study of the deformed samples suggests that the confinement of dislocations in the ferrite lamellae is responsible for strengthening at both ambient and high temperature. The microstructure scale in addition to CMA phase structural features stands then as a key parameter for optimization of mechanical properties of CMA in situ composites. (papers)

  18. Ambient temperature influences core body temperature response in rat lines bred for differences in sensitivity to 8-hydroxy-dipropylaminotetralin.

    Science.gov (United States)

    Nicholas, Andrea C; Seiden, Lewis S

    2003-04-01

    Agonist-induced decrease in core body temperature has commonly been used as a measure of serotonin1A (5-HT(1A)) receptor sensitivity in mood disorder. The thermoregulatory basis for 5-HT(1A) receptor agonist-induced temperature responses in humans and rats remains unclear. Therefore, the influence of ambient temperature on 5-HT(1A) receptor-mediated decreases in core body temperature were measured in rat lines bred for high (HDS) or low (LDS) sensitivity to the selective 5-HT(1A) receptor agonist 8-hydroxy-dipropylaminotetralin (8-OH-DPAT). HDS and LDS rats were injected with either saline, 0.25 or 0.50 mg/kg 8-OH-DPAT at ambient temperatures of 10.5, 24, 30, or 37.5 degrees C, and core temperature was measured by radiotelemetry. For both lines, the thermic response to acute 8-OH-DPAT was greatest at 10.5 degrees C and decreased in magnitude as ambient temperature increased to 30 degrees C, consistent with hypothermia. HDS rats displayed a greater hypothermic response than LDS rats at 10.5, 24, and 30 degrees C. At 37.5 degrees C, LDS rats showed a lethal elevation of temperature in response to 0.50 mg/kg 8-OH-DPAT. All thermic responses to 8-OH-DPAT, including the lethality, were effectively blocked by pretreatment with the 5-HT(1A) receptor antagonist WAY100635, suggesting line differences in thermoregulatory circuits that are influenced by 5-HT(1A) receptor activation. Following repeated injection of 8-OH-DPAT, the magnitude of the hypothermic response decreased in both lines at 10.5 degrees C, but increased in HDS rats treated with 0.50 mg/kg 8-OH-DPAT at 30 and 37.5 degrees C. This pattern was reversed in HDS rats following 8-OH-DPAT challenge at 24 degrees C, suggesting that a compensatory thermoregulatory response accounts for changes in the hypothermic response to chronic 8-OH-DPAT. PMID:12649391

  19. Shaped Refractory Products--Determination of Modulus of Rupture at Ambient Temperature GB/T 3001-2000

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    @@ 1 Scope This standard specifies a method for the determination of the modulus of rupture of dense and insulating shaped refractory products at ambient temperature, under conditions of a constant rate of increase of stress.

  20. Daily ambient temperature and renal colic incidence in Guangzhou, China: a time-series analysis

    Science.gov (United States)

    Yang, Changyuan; Chen, Xinyu; Chen, Renjie; Cai, Jing; Meng, Xia; Wan, Yue; Kan, Haidong

    2016-08-01

    Few previous studies have examined the association between temperature and renal colic in developing regions, especially in China, the largest developing country in the world. We collected daily emergency ambulance dispatches (EADs) for renal colic from Guangzhou Emergency Center from 1 January 2008 to 31 December 2012. We used a distributed-lag nonlinear model in addition to the over-dispersed generalized additive model to investigate the association between daily ambient temperature and renal colic incidence after controlling for seasonality, humidity, public holidays, and day of the week. We identified 3158 EADs for renal colic during the study period. This exposure-response curve was almost flat when the temperature was low and moderate and elevated when the temperature increased over 21 °C. For heat-related effects, the significant risk occurred on the concurrent day and diminished until lag day 7. The cumulative relative risk of hot temperatures (90th percentile) and extremely hot temperatures (99th percentile) over lag days 0-7 was 1.92 (95 % confidence interval, 1.21, 3.05) and 2.45 (95 % confidence interval, 1.50, 3.99) compared with the reference temperature of 21 °C. This time-series analysis in Guangzhou, China, suggested a nonlinear and lagged association between high outdoor temperatures and daily EADs for renal colic. Our findings might have important public health significance to prevent renal colic.

  1. Daily ambient temperature and renal colic incidence in Guangzhou, China: a time-series analysis

    Science.gov (United States)

    Yang, Changyuan; Chen, Xinyu; Chen, Renjie; Cai, Jing; Meng, Xia; Wan, Yue; Kan, Haidong

    2015-11-01

    Few previous studies have examined the association between temperature and renal colic in developing regions, especially in China, the largest developing country in the world. We collected daily emergency ambulance dispatches (EADs) for renal colic from Guangzhou Emergency Center from 1 January 2008 to 31 December 2012. We used a distributed-lag nonlinear model in addition to the over-dispersed generalized additive model to investigate the association between daily ambient temperature and renal colic incidence after controlling for seasonality, humidity, public holidays, and day of the week. We identified 3158 EADs for renal colic during the study period. This exposure-response curve was almost flat when the temperature was low and moderate and elevated when the temperature increased over 21 °C. For heat-related effects, the significant risk occurred on the concurrent day and diminished until lag day 7. The cumulative relative risk of hot temperatures (90th percentile) and extremely hot temperatures (99th percentile) over lag days 0-7 was 1.92 (95 % confidence interval, 1.21, 3.05) and 2.45 (95 % confidence interval, 1.50, 3.99) compared with the reference temperature of 21 °C. This time-series analysis in Guangzhou, China, suggested a nonlinear and lagged association between high outdoor temperatures and daily EADs for renal colic. Our findings might have important public health significance to prevent renal colic.

  2. Alternative Refrigerant Evaluation for High-Ambient-Temperature Environments: R-22 and R-410A Alternatives for Rooftop Air Conditioners

    Energy Technology Data Exchange (ETDEWEB)

    Abdelaziz, Omar [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Shrestha, Som S. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Shen, Bo [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Linkous, Randall Lee [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Goetzler, William [Navigant Consulting Inc., Burlington, MA (United States); Guernsey, Matt [Navigant Consulting Inc., Burlington, MA (United States); Bargach, Youssef [Navigant Consulting Inc., Burlington, MA (United States)

    2016-09-01

    The Oak Ridge National Laboratory (ORNL) High-Ambient-Temperature Evaluation Program for Low-Global Warming Potential (Low-GWP) Refrigerants aims to develop an understanding of the performance of low-GWP alternative refrigerants relative to hydrochlorofluorocarbon (HCFC) and hydrofluorocarbon (HFC) refrigerants in packaged or Rooftop Unit (RTU) air conditioners under high-ambient-temperature conditions. This final report describes the parties involved, the alternative refrigerants selection process, the test procedures, and the final results.

  3. Influence of Physical Activity and Ambient Temperature on Hydration: The European Hydration Research Study (EHRS).

    Science.gov (United States)

    Mora-Rodriguez, Ricardo; Ortega, Juan F; Fernandez-Elias, Valentin E; Kapsokefalou, Maria; Malisova, Olga; Athanasatou, Adelais; Husemann, Marlien; Domnik, Kirsten; Braun, Hans

    2016-01-01

    This study explored the effects of physical activity (PA) and ambient temperature on water turnover and hydration status. Five-hundred seventy three healthy men and women (aged 20-60 years) from Spain, Greece and Germany self-reported PA, registered all food and beverage intake, and collected 24-h urine during seven consecutive days. Fasting blood samples were collected at the onset and end of the study. Food moisture was assessed using nutritional software to account for all water intake which was subtracted from daily urine volume to allow calculation of non-renal water loss (i.e., mostly sweating). Hydration status was assessed by urine and blood osmolality. A negative association was seen between ambient temperature and PA (r = -0.277; p < 0.001). Lower PA with high temperatures did not prevent increased non-renal water losses (i.e., sweating) and elevated urine and blood osmolality (r = 0.218 to 0.163 all p < 0.001). When summer and winter data were combined PA was negatively associated with urine osmolality (r = -0.153; p = 0.001). Our data suggest that environmental heat acts to reduce voluntary PA but this is not sufficient to prevent moderate dehydration (increased osmolality). On the other hand, increased PA is associated with improved hydration status (i.e., lower urine and blood osmolality). PMID:27128938

  4. Influence of Physical Activity and Ambient Temperature on Hydration: The European Hydration Research Study (EHRS

    Directory of Open Access Journals (Sweden)

    Ricardo Mora-Rodriguez

    2016-04-01

    Full Text Available This study explored the effects of physical activity (PA and ambient temperature on water turnover and hydration status. Five-hundred seventy three healthy men and women (aged 20–60 years from Spain, Greece and Germany self-reported PA, registered all food and beverage intake, and collected 24-h urine during seven consecutive days. Fasting blood samples were collected at the onset and end of the study. Food moisture was assessed using nutritional software to account for all water intake which was subtracted from daily urine volume to allow calculation of non-renal water loss (i.e., mostly sweating. Hydration status was assessed by urine and blood osmolality. A negative association was seen between ambient temperature and PA (r = −0.277; p < 0.001. Lower PA with high temperatures did not prevent increased non-renal water losses (i.e., sweating and elevated urine and blood osmolality (r = 0.218 to 0.163 all p < 0.001. When summer and winter data were combined PA was negatively associated with urine osmolality (r = −0.153; p = 0.001. Our data suggest that environmental heat acts to reduce voluntary PA but this is not sufficient to prevent moderate dehydration (increased osmolality. On the other hand, increased PA is associated with improved hydration status (i.e., lower urine and blood osmolality.

  5. Effect of Ambient and Oxygen Temperature on Flow Field Characteristics of Coherent Jet

    Science.gov (United States)

    Liu, Fuhai; Zhu, Rong; Dong, Kai; Hu, Shaoyan

    2016-02-01

    The coherent jets are now used widely in electric arc furnace steelmaking process to increase the stirring ability, reaction rates, and energy efficiency. However, there has been limited research on the basic physics of the coherent jets. In the present study, the characteristics of flow field of supersonic coherent jet in hot and cold condition were studied. The total temperature and axial velocity were measured by combustion experiment. Flow field characteristics of supersonic coherent jet were simulated by Fluent software. The detailed chemical kinetic mechanism is presently used for the modeling of reactions. It consists of 53 species, plus Ar and N2, for a total of 325 reversible reactions. The present study showed that the shrouding flame decreases the entrainment of the ambient gas to the central supersonic jet, which results in a low expansion rate for the coherent supersonic jet. The higher ambient temperature can prolong the potential core of coherent jet and conventional jet. However, the potential core of coherent jet reduces with oxygen temperature increasing, which is opposite to conventional jet.

  6. Daily means ambient temperature prediction using artificial neural network method. A case study of Turkey

    Energy Technology Data Exchange (ETDEWEB)

    Altan Dombayci, Oemer [Department of Technical Programmes, Denizli Vocational College, Pamukkale University, 20070 Denizli (Turkey); Goelcue, Mustafa [Department of Mechanical Education, Technical Education Faculty, Pamukkale University, 20070 Denizli (Turkey)

    2009-04-15

    The objective of this paper is to develop an artificial neural network (ANN) model which can be used to predict daily mean ambient temperatures in Denizli, south-western Turkey. In order to train the model, temperature values, measured by The Turkish State Meteorological Service over three years (2003-2005) were used as training data and the values of 2006 were used as testing data. In order to determine the optimal network architecture, various network architectures were designed; different training algorithms were used; the number of neuron and hidden layer and transfer functions in the hidden layer/output layer were changed. The predictions were performed by taking different number of hidden layer neurons between 3 and 30. The best result was obtained when the number of the neurons is 6. The selected ANN model of a multi-layer consists of 3 inputs, 6 hidden neurons and 1 output. Training of the network was performed by using Levenberg-Marquardt (LM) feed-forward backpropagation algorithms. A computer program was performed under Matlab 6.5 software. For each network, fraction of variance (R{sup 2}) and root-mean squared error (RMSE) values were calculated and compared. The results show that the ANN approach is a reliable model for ambient temperature prediction. (author)

  7. Daily variations in the influence of noradrenaline on preferred ambient temperature of the Siberian hamster.

    Science.gov (United States)

    Jefimow, Małgorzata; Wojciechowski, Michał; Tegowska, Eugenia

    2003-04-01

    Daily variations in sensitivity to noradrenaline (NA) and the activation of nonshivering thermogenesis (NST) are important for survival under a potentially wide range of environmental conditions. However, little is known regarding the ability of the Siberian hamster and other species to activate NST in the day and night when they may be subjected to marked variations in environmental temperature. In this study, the effects of acclimation temperature and time of day on the behavioral thermoregulatory response to NA injections in Siberian hamsters (Phodopus sungorus) was investigated. Hamsters were acclimated for 4 weeks to 23 degrees C and a L:D 12:12 h photoperiod. After acclimation, preferred ambient temperatures (PT(a)) in saline- and NA-injected animals were measured continuously in the temperature gradient system. NA (0.6 mg/kg; s.c.) was given every 4 h while PT(a) was monitored. After NA injections there was a rapid drop in PT(a), decreasing to approximately 15 degrees C within 10-20 min after each NA injection. Following 4 weeks of acclimation to 10 degrees C and a L:D 8:16 h photoperiod, the same hamsters were re-tested in the temperature gradient system. Cold acclimation led to an accentuation in the behavioral response with a decrease in PT(a) of approximately 10 degrees C. The maximal decrease in preferred ambient temperatures was recorded during the light phase of the day and during the second part of the night. Lowering of PT(a) after NA allows for rapid dissipation of the heat from NST. Overall, the behavioral response reflects the daily changes in brown adipose tissue sensitivity to NA and thus capacity for NST.

  8. Tritium release from a nonevaportable getter-pump cartridge exposed to moist air at ambient temperature

    International Nuclear Information System (INIS)

    The amount of tritium released when a commercially available getter-pump cartridge was exposed to moist air at ambient temperatures was measured. The cartridge consisted of Zr-Al powder pressed onto an iron substrate, which is the type of cartridge proposed for use in the Tokomak Fusion Test Reactor. While the initial release of tritium was rapid the total activity released was lss than 0.005% of the cartridge loading. Of this amount, at least 80% was released as tritiated water. 8 figures

  9. Identification of the Products of Oxidation of Quercetin by Air Oxygenat Ambient Temperature

    OpenAIRE

    Viktor A Utsal; Dobryakov, Yuri G; Vitenberg, Alexander G; Makarova, Svetlana V; Anna Yu Eshchenko; Igor G Zenkevich

    2007-01-01

    Oxidation of quercetin by air oxygen takes place in water and aqueous ethanol solutions under mild conditions, namely in moderately-basic media (pH ∼ 8-10) at ambient temperature and in the absence of any radical initiators, without enzymatic catalysis or irradiation of the reaction media by light. The principal reaction products are typical of other oxidative degradation processes of quercetin, namely 3,4-dihydroxy-benzoic (proto-catechuic) and 2,4,6-trihydroxybenzoic (phloroglucinic) a...

  10. Fabrication of AlN thin films on different substrates at ambient temperature

    CERN Document Server

    Cai, W X; Wu, P H; Yang, S Z; Ji, Z M

    2002-01-01

    Aluminium nitride (AlN) is very useful as a barrier in superconductor-insulator-superconductor (SIS) device or as an insulating layer in many other applications. At ambient temperature, we deposit AlN thin films onto different substrates (such as MgO, LaAlO sub 3 and Si) by using radio-frequency magnetron sputtering and pure Al target. X-ray diffraction (XRD) and PHI-scan patterns show that the films grown on MgO substrates are excellent epitaxial films with (101) orientation of a hexagonal lattice. A possible structure of the interface between the film and the substrate is suggested and discussed.

  11. Thermodynamic comparison of PNA/DNA and DNA/DNA hybridization reactions at ambient temperature.

    OpenAIRE

    Schwarz, F. P.; Robinson, S; Butler, J. M.

    1999-01-01

    The thermodynamics of 13 hybridization reactions between 10 base DNA sequences of design 5'-ATGCXYATGC-3' with X, Y = A, C, G, T and their complementary PNA and DNA sequences were determined from isothermal titration calorimetry (ITC) measurements at ambient temperature. For the PNA/DNA hybridization reactions, the binding constants range from 1.8 x 10(6)M(-1)for PNA(TT)/DNA to 4.15 x 10(7)M(-1)for PNA(GA)/DNA and the binding enthalpies range from -194 kJ mol(-1)for PNA(CG)/DNA to -77 kJ mol(...

  12. In situ synthesis of hydroxyapatite nanocomposites using iron oxide nanofluids at ambient conditions.

    Science.gov (United States)

    Sheikh, Lubna; Mahto, Neha; Nayar, Suprabha

    2015-01-01

    This paper describes a simple method for the room temperature synthesis of magnetite/hydroxyapatite composite nanocomposites using ferrofluids. The in situ synthesis of magnetic-hydroxyapatite results in a homogenous distribution of the two phases as seen both in transmission electron micrographs and assembled to a micron range in the confocal micrographs. The selected area diffraction pattern analysis shows the presence of both phases of iron oxide and hydroxyapatite. To the dialyzed ferrofluid, the constituents of hydroxyapatite synthesis was added, the presence of the superparamagnetic iron oxide particles imparts directionality to the hydroxyapatite crystal growth. Electron probe microanalysis confirms the co-existence of both iron and calcium atoms. Vibrating Sample magnetometer data shows magnetization three times more than the parent ferrofluid, the local concentration of iron oxide nanoparticles affects the strength of dipolar interparticle interactions changing the energy barrier for determining the collective magnetic behavior of the sample. The limitations inherent to the use of external magnetic fields which can be circumvented by the introduction of internal magnets located in the proximity of the target by a minimal surgery or by using a superparamagnetic scaffold under the influence of externally applied magnetic field inspires us to increase the magnetization of our samples. The composite in addition shows anti-bacterial properties against the two gram (-ve) bacteria tested. This work is significant as magnetite-hydroxyapatite composites are attracting a lot of attention as adsorbents, catalysts, hyperthermia agents and even as regenerative medicine. PMID:25589209

  13. Estimating methane emissions from landfills based on rainfall, ambient temperature, and waste composition: The CLEEN model.

    Science.gov (United States)

    Karanjekar, Richa V; Bhatt, Arpita; Altouqui, Said; Jangikhatoonabad, Neda; Durai, Vennila; Sattler, Melanie L; Hossain, M D Sahadat; Chen, Victoria

    2015-12-01

    Accurately estimating landfill methane emissions is important for quantifying a landfill's greenhouse gas emissions and power generation potential. Current models, including LandGEM and IPCC, often greatly simplify treatment of factors like rainfall and ambient temperature, which can substantially impact gas production. The newly developed Capturing Landfill Emissions for Energy Needs (CLEEN) model aims to improve landfill methane generation estimates, but still require inputs that are fairly easy to obtain: waste composition, annual rainfall, and ambient temperature. To develop the model, methane generation was measured from 27 laboratory scale landfill reactors, with varying waste compositions (ranging from 0% to 100%); average rainfall rates of 2, 6, and 12 mm/day; and temperatures of 20, 30, and 37°C, according to a statistical experimental design. Refuse components considered were the major biodegradable wastes, food, paper, yard/wood, and textile, as well as inert inorganic waste. Based on the data collected, a multiple linear regression equation (R(2)=0.75) was developed to predict first-order methane generation rate constant values k as functions of waste composition, annual rainfall, and temperature. Because, laboratory methane generation rates exceed field rates, a second scale-up regression equation for k was developed using actual gas-recovery data from 11 landfills in high-income countries with conventional operation. The Capturing Landfill Emissions for Energy Needs (CLEEN) model was developed by incorporating both regression equations into the first-order decay based model for estimating methane generation rates from landfills. CLEEN model values were compared to actual field data from 6 US landfills, and to estimates from LandGEM and IPCC. For 4 of the 6 cases, CLEEN model estimates were the closest to actual.

  14. Estimating methane emissions from landfills based on rainfall, ambient temperature, and waste composition: The CLEEN model.

    Science.gov (United States)

    Karanjekar, Richa V; Bhatt, Arpita; Altouqui, Said; Jangikhatoonabad, Neda; Durai, Vennila; Sattler, Melanie L; Hossain, M D Sahadat; Chen, Victoria

    2015-12-01

    Accurately estimating landfill methane emissions is important for quantifying a landfill's greenhouse gas emissions and power generation potential. Current models, including LandGEM and IPCC, often greatly simplify treatment of factors like rainfall and ambient temperature, which can substantially impact gas production. The newly developed Capturing Landfill Emissions for Energy Needs (CLEEN) model aims to improve landfill methane generation estimates, but still require inputs that are fairly easy to obtain: waste composition, annual rainfall, and ambient temperature. To develop the model, methane generation was measured from 27 laboratory scale landfill reactors, with varying waste compositions (ranging from 0% to 100%); average rainfall rates of 2, 6, and 12 mm/day; and temperatures of 20, 30, and 37°C, according to a statistical experimental design. Refuse components considered were the major biodegradable wastes, food, paper, yard/wood, and textile, as well as inert inorganic waste. Based on the data collected, a multiple linear regression equation (R(2)=0.75) was developed to predict first-order methane generation rate constant values k as functions of waste composition, annual rainfall, and temperature. Because, laboratory methane generation rates exceed field rates, a second scale-up regression equation for k was developed using actual gas-recovery data from 11 landfills in high-income countries with conventional operation. The Capturing Landfill Emissions for Energy Needs (CLEEN) model was developed by incorporating both regression equations into the first-order decay based model for estimating methane generation rates from landfills. CLEEN model values were compared to actual field data from 6 US landfills, and to estimates from LandGEM and IPCC. For 4 of the 6 cases, CLEEN model estimates were the closest to actual. PMID:26346020

  15. Low-temperature-grown continuous graphene films from benzene by chemical vapor deposition at ambient pressure

    Science.gov (United States)

    Jang, Jisu; Son, Myungwoo; Chung, Sunki; Kim, Kihyeun; Cho, Chunhum; Lee, Byoung Hun; Ham, Moon-Ho

    2015-12-01

    There is significant interest in synthesizing large-area graphene films at low temperatures by chemical vapor deposition (CVD) for nanoelectronic and flexible device applications. However, to date, low-temperature CVD methods have suffered from lower surface coverage because micro-sized graphene flakes are produced. Here, we demonstrate a modified CVD technique for the production of large-area, continuous monolayer graphene films from benzene on Cu at 100-300 °C at ambient pressure. In this method, we extended the graphene growth step in the absence of residual oxidizing species by introducing pumping and purging cycles prior to growth. This led to continuous monolayer graphene films with full surface coverage and excellent quality, which were comparable to those achieved with high-temperature CVD; for example, the surface coverage, transmittance, and carrier mobilities of the graphene grown at 300 °C were 100%, 97.6%, and 1,900-2,500 cm2 V-1 s-1, respectively. In addition, the growth temperature was substantially reduced to as low as 100 °C, which is the lowest temperature reported to date for pristine graphene produced by CVD. Our modified CVD method is expected to allow the direct growth of graphene in device manufacturing processes for practical applications while keeping underlying devices intact.

  16. Influence of ambient temperature on whole body and segmental bioimpedance spectroscopy measurements

    Science.gov (United States)

    Medrano, G.; Bausch, R.; Ismail, A. H.; Cordes, A.; Pikkemaat, R.; Leonhardt, S.

    2010-04-01

    Bioimpedance spectroscopy (BIS) measurements are easy to implement and could be used for continuous monitoring. However, several factors (e.g. environment temperature) influence the measurements limiting the accuracy of the technology. Changes in skin temperature produced by changes in ambient temperature are related with changes in skin blood flow and skin impedance. It is assumed that skin impedance change is responsible for the error observed in whole body and segmental measurements. Measurements including body parts more distant from the torso seem to be more affected. In the present article skin and segment impedance have been performed on healthy subjects under extreme changes in environment temperature (13-39 °C). A commercial BIS device with a range between 5 kHz and 1 MHz has been used for the measurements. The results indicate that not only skin impedance, but also impedance of deeper tissue (e.g. muscle) may be responsible for the influence of environment temperature on BIS measurements. Segmental (knee-to-knee) BIS measurements show a relative change of only 2 %, while forearm and whole body impedance changed 14 % and 8 % respectively.

  17. High cycle fatigue property of Ti-600 alloy at ambient temperature

    International Nuclear Information System (INIS)

    Research highlights: Ti-600, developed by Northwest Institute for Nonferrous Metal Research (NIN) in China, is a near alpha titanium alloy designed for components used in turbine engines up to 600 deg. C. Mechanical behavior of the alloy at ambient temperature and its service temperature has widely been studied, the fatigue property for the alloy has never been systematically discussed. Smooth axial fatigue tests were taken for solutioned plus aged alloy, and the fractographies were observed. In order to get the damage mechanism, OM and TEM microstructures were also investigated. - Abstract: Smooth axial fatigue tests were carried out at ambient temperature on one kind of near alpha titanium alloy named after Ti-600 at a frequency of 120-130 Hz and with two kinds of load ratios. The high cycle fatigue (HCF) strength for the solutioned and aged alloy is found to be 475 MPa fatigued with a load ratio R of 0.1, and which is 315 MPa with a load ratio R of -1. The observed high HCF strength for the samples fatigued with a load ratio R of 0.1 is attributed to its overlapping fine and thin plate like α + β phase microstructure. During the crack propagation region, at the same stress of 600 MPa, the sample with a fatigue life of 1.78 x 106 cycles has a better fatigue resistance than that of the sample with a fatigue life of 8.61 x 105 cycles, because of its smaller striation distance, its well-developed secondary cracks, more wider and coarsened α lathes precipitated at grain boundaries, and the heavily arranged interlacing transformed β microsructures. The average grain size of rare earth phases varies from several micrometers to 0.2 μm, no cracks corresponding to rare earth particles can be initiated.

  18. Impact of Montmorillonite and Calcite on Release and Adsorption of Cyanobacterial Fatty Acids at Ambient Temperature

    Institute of Scientific and Technical Information of China (English)

    Liu Deng; Yang Xiaofen; Wang Hongmei; Li Jihong; Su Nian

    2008-01-01

    Minerals might act as important sorbents of sedimentary organic matter and reduce biodegradation, which favors the formation of hydrocarbon source rocks in the earth's history. Since most organic matter is degraded during the sinking process, at ambient temperature, it is important to investigate the adsorption capacity of different minerals during this process, to assess the organic loss from primary productivity to sedimentary organic matter. In this study, montmorillonite and calcite have been selected to study the impact of different minerals on the release, adsorption, and deposition of cyanobacterial (Synechococcus elonpata) fatty acids (FAs) at ambient temperature. Gas chromatography (GC), gas chromatography-mass spectrometry (GC-MS) have been utilized to detect the variation in fatty acids. Primary results suggest that minerals have a different impact on dissolved organic matter. Montmorillonite can specifically enhance the release of fatty acids from cyanobacterial cells by lowering the pH values of the solution. The adsorption of the dissolved organic matter by montmorillonite will also be enhanced under a lower pH value. Conjunction of fatty acids with montmorillonite to form a complex will favor the sinking and preservation of these organics. Selective adsorption is observed among fatty acids with different carbon numbers. In contrast, calcite does not show any impact on the release and adsorption of organic matter even though it is reportedly capable of acting as a catalyst during the transformation of organic matter at high temperature. The primary data bridge a link between primary productivity and sedimentary organic matter, suggesting the relative importance of claystoncs in the formation of hydrocarbon source rocks in the earth's history.

  19. CO2 capture at ambient temperature in a fixed bed with CaO-based sorbents

    International Nuclear Information System (INIS)

    Highlights: • CaO-based pellets can be used for CO2 capture at ambient temperature. • Pre-hydration of pellets improves CO2 capture capacity significantly. • CO2 capture capacity of 0.5 g/g is obtained in a CaO-based fixed bed. • The capture capacity is sensitive to moisture and CO2 inlet concentration. - Abstract: This work investigates post-combustion CO2 capture at ambient temperature in a fixed bed by means of CaO-based sorbents. Two sorbents were used: limestone and pellets prepared from powdered limestone using calcium aluminate cement as a binder. The results showed that pre-hydration had a significant effect on CO2 capture performance of the two sorbents. For instance, after 8 h pre-hydration, the breakthrough time increased from 21 min to 660 min for lime, and from 19 min to 750 min for pellets. The performance of pellets was more sensitive to hydration conditions than for the lime. At breakthrough, full carbonation conversion over half of the reactor was achieved in a pre-hydrated bed of pellets exposed to a feed with 0.5% CO2, resulting in an average specific capture of 0.51 g CO2/g bed material. This was considered a sufficient capture performance, with a distinct mass transfer zone (MTZ) located in the upper half of the reactor. However, increasing CO2 inlet concentration to 2% shortened the breakthrough time and shifted the MTZ toward the entrance zone of the reactor. It was concluded that capturing CO2 from low-CO2 flue gases at ambient temperature using a fixed bed of pre-hydrated CaO-based pellets is a promising approach that has the potential to achieve reasonable capture performance at relatively low cost. The proposed process can be used for CO2 capture from CO2-depleted flue gases (residual CO2) from processes such as amine scrubbing and calcium looping. And it would allow for the possibility that capture could be increased to any given level required by new legislation for plant with carbon capture

  20. Preferred ambient temperature for old and young men in summer and winter.

    Science.gov (United States)

    Natsume, K; Ogawa, T; Sugenoya, J; Ohnishi, N; Imai, K

    1992-03-01

    To investigate the effects of age on thermal sensitivity, preferred ambient temperature (Tpref) was compared between old (71-76 years) and young (21-30 years) groups, each consisting of six male subjects in summer and winter. The air temperature (Ta) was set at either 20 degrees C or 40 degrees C at commencement. The subject was directed to adjust the Ta for 45 min by manipulating a remote control switch to the level at which he felt most comfortable. In the older group, the Tpref was significantly lower in trails starting at 20 degrees C than that starting at 40 degrees C in summer. The fluctuation of Tpref (temperature difference between maximum and minimum Ta during the last 10 min) was significantly wider in the older group in both summer and winter. Repetition of the same experiment on each subject showed a poorer reproducibility of Tpref in the older group than in the younger group in summer. Tympanic and esophageal temperatures of the older group kept falling throughout the trial starting at 20 degrees C in summer. These results suggest that thermal sensitivity is decreased with advancing age and that thermal perception in the elderly, especially to cold, is less sensitive in summer.

  1. Ambient temperature dependence on emission spectrum of InAs quantum dots

    Energy Technology Data Exchange (ETDEWEB)

    Ngo, C.Y.; Yoon, S.F. [School of Electrical and Electronic Engineering, Nanyang Technological University (Singapore); Chua, S.J. [Institute of Materials Research and Engineering, Faculty of Engineering (Singapore)

    2009-04-15

    Semiconductor superluminescent diodes (SLDs) are important broadband light source for fiber optic gyroscope and biomedical imaging. Quantum dots (QDs) have been proposed to be the best candidate for broadband light sources due to the inhomogeneous broadening of the gain spectrum as a result of the inherited size inhomogeneity of the self-assembled QD growth. In this work, the effect of ambient temperature (25-100 C) on the emission spectrum of InAs QDs with wideband emission was investigated. It was found that the full-width at half-maximum (FWHM) of the photoluminescence (PL) spectra remains more than 125 nm throughout the temperature range, and the redshift as function of temperature is approximately 0.27 meV/K. Activation energy of 270 meV is extracted from the Arrhenius plot and the PL quenching at high temperature is attributed to thermally induced carriers escaping out of the In{sub 0.15}Ga{sub 0.85}As strain-reducing layer. (copyright 2009 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  2. Rice LTG1 is involved in adaptive growth and fitness under low ambient temperature.

    Science.gov (United States)

    Lu, Guangwen; Wu, Fu-Qing; Wu, Weixun; Wang, Hong-Jun; Zheng, Xiao-Ming; Zhang, Yunhui; Chen, Xiuling; Zhou, Kunneng; Jin, Mingna; Cheng, Zhijun; Li, Xueyong; Jiang, Ling; Wang, Haiyang; Wan, Jianmin

    2014-05-01

    Low temperature (LT) is one of the most prevalent factors limiting the productivity and geographical distribution of rice (Oryza sativa L.). Although significant progress has been made in elucidating the effect of LT on seed germination and reproductive development in rice, the genetic component affecting vegetative growth under LT remains poorly understood. Here, we report that rice cultivars harboring the dominant LTG1 (Low Temperature Growth 1) allele are more tolerant to LT (15-25°C, a temperature range prevalent in high-altitude, temperate zones and high-latitude areas), than those with the ltg1 allele. Using a map-based cloning strategy, we show that LTG1 encodes a casein kinase I. A functional nucleotide polymorphism was identified in the coding region of LTG1, causing a single amino acid substitution (I357K) that is associated with the growth rate, heading date and yield of rice plants grown at LT. We present evidence that LTG1 affects rice growth at LT via an auxin-dependent process(es). Furthermore, phylogenetic analysis of this locus suggests that the ltg1 haplotype arose before the domestication of rice in tropical climates. Together, our data demonstrate that LTG1 plays an important role in the adaptive growth and fitness of rice cultivars under conditions of low ambient temperature.

  3. Influence of Ambient Temperature on the CO2 Emitted With Exhaust Gases of Gasoline Vehicles

    Science.gov (United States)

    Chainikov, D.; Chikishev, E.; Anisimov, I.; Gavaev, A.

    2016-08-01

    This article focuses on the regulation of CO2 emitted in the exhaust gases of gasoline vehicles. Based on comparing the world practices of restrictive measures on greenhouse gas emissions with Russian legislation, we conclude that there is a need to adjust the limits of CO2 emission taking into account the negative impact of ambient temperature on CO2 emission. The climatic conditions of many countries stipulate the use of vehicles in temperatures below zero. At the same time, the existing regulations fully take into account the temperature features of the various countries, which casts doubt on the existence of uniform emission standards for all countries. Here, we conduct an experiment on one of the most popular cars in Russia: the Mitsubishi Lancer 9. We establish that lower temperatures are correlated with larger concentrations of CO2 in the exhaust gases. We draw a conclusion about the need to account for the actual operating conditions when establishing limit values on CO2 emissions of vehicles.

  4. Synthesis of Carbon Nanotubes by MWPCVD at Low Temperature

    Institute of Scientific and Technical Information of China (English)

    王升高; 汪建华; 王传新; 马志彬; 满卫东

    2002-01-01

    Growth of carbon nanotubes (CNTs) at low temperature is very important to the applications of nanotubes. In this paper, under the catalytic effect of cobalt nanoparticles supported by SiO2, CNTs were synthesized by microwave plasma chemical vapor deposition (MWPCVD)below 500℃. It demonstrates that MWPCVD can be a very efficient process for the synthesis of CNTs at low temperature.

  5. Ambient-Temperature Passive Magnetic Bearings for Flywheel Energy Storage Systems

    Science.gov (United States)

    Post, R. F.; Bender, D. A.

    2002-05-01

    Based on prior work at the Lawrence Livermore National Laboratory ambient-temperature passive magnetic bearings are being adapted for use in highpower flywheel energy storage systems developed at the Trinity Flywheel Power company. En route to this goal specialized test stands have been built and computer codes have been written to aid in the development of the component parts of these bearing systems. The Livermore passive magnetic bearing system involves three types of elements, as follows: (1) axially symmetric levitation elements, energized by permanent magnets, (2) electrodynamic stabilizers employing axially symmetric arrays of permanent magnet bars (Halbach arrays) on the rotating system, interacting with specially wound electrically shorted stator circuits, and, (3) eddy-current-type vibration dampers, employing axially symmetric rotating pole assemblies interacting with stationary metallic discs. The theory of the Livermore passive magnetic bearing concept describes specific quantitative stability criteria.

  6. Numerical analysis of composite steel-concrete beams in ambient temperature and in fire situation

    Directory of Open Access Journals (Sweden)

    Roberto Martins Gonçalves

    2005-02-01

    Full Text Available This paper presents three-dimensional numerical models of steel-concrete composite beams with full interaction (no slip between concrete slab and steel beam using a non-linear procedure. The threedimensional numerical models must be capable of predicting the response of composite beam at ambient temperature and in fire situation with accuracy. The computer program ABAQUS ® 6.3-1, based on Finite Element Method, was used to analyze the numerical modeling. The accuracy of the models is demonstrated through the results obtained, which are compared with the experimental results presented in other works. The reported results, when compared to experimental data, demonstrate that the numerical models elaborated with shell finite elements show better performance when compared to the results of the numerical models elaborated with solid finite elements.

  7. Stability of succinylcholine chloride injection at ambient temperature and 4 deg C in polypropylene syringes.

    Science.gov (United States)

    Storms, Meredith L; Stewart, James T; Warren, Flynn W

    2003-01-01

    The stability of 20-mg/mL succinylcholine chloride injection in 12-mL polypropylene syringes stored at ambient temperature and 4 deg C for up to 90 days was investigated. Concentration levels of succinylcholine chloride injection were determined at 0, 1, 4, 7, 15, 30, 45, 60, and 90 days after preparation of the syringes by means of a high-performance liquid chromatographic stability-indicating assay. Methylparaben, which was added as a preservative, did not interfere with the assay. The loss in potency was less than 10% after 45 days of storage at 25 deg C and less than 1% after 90 days of storage at 4 deg C. The pH of succinylcholine chloride injection did not change appreciably during the 90-day study period. PMID:23979509

  8. Standard test method for ambient temperature fatigue life of metallic bonded resistance strain gages

    CERN Document Server

    American Society for Testing and Materials. Philadelphia

    2003-01-01

    1.1 This test method covers a uniform procedure for the determination of strain gage fatigue life at ambient temperature. A suggested testing equipment design is included. 1.2 This test method does not apply to force transducers or extensometers that use bonded resistance strain gages as sensing elements. 1.3 Strain gages are part of a complex system that includes structure, adhesive, gage, leadwires, instrumentation, and (often) environmental protection. As a result, many things affect the performance of strain gages, including user technique. A further complication is that strain gages, once installed, normally cannot be reinstalled in another location. Therefore, it is not possible to calibrate individual strain gages; performance characteristics are normally presented on a statistical basis. 1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices ...

  9. Ambient temperature operated acetaldehyde vapour detection of spray deposited cobalt doped zinc oxide thin film.

    Science.gov (United States)

    Shalini, S; Balamurugan, D

    2016-03-15

    Undoped and Co-doped ZnO thin films were prepared by a home built spray pyrolysis method. X-ray diffraction results indicate that both undoped and Co-doped ZnO have a polycrystalline nature and a preferential orientation peak in the (002) plane. From a field-emission scanning electron micrographs of annealed films, a uniform distribution of nanoparticles along with nanorods was observed. UV-Visible measurement indicated that all the films are transparent in the visible region. The electrical resistance was also reported. The acetaldehyde sensing behaviour of the prepared undoped and Co-doped ZnO thin films was studied using the chemi-resistive method at ambient temperature (∼30 °C). In the presence of 10 ppm of acetaldehyde vapour, the Co-doped ZnO thin films showed good sensing response of 74% with fast response and recovery time of 3 s and 110 s respectively. PMID:26748067

  10. Multipole Electrodynamic Ion Trap Geometries for Microparticle Confinement under Standard Ambient Temperature and Pressure Conditions

    CERN Document Server

    Mihalcea, Bogdan M; Stan, Cristina; Visan, Gina T; Ganciu, Mihai; Filinov, Vladimir E; Lapitsky, Dmitry S; Deputatova, Lidiya V; Syrovatka, Roman A

    2015-01-01

    Trapping of microparticles and aerosols is of great interest for physics and chemistry. We report microparticle trapping in multipole linear Paul trap geometries, operating under Standard Ambient Temperature and Pressure (SATP) conditions. An 8-electrode and a 12-electrode linear trap geometries have been designed and tested with an aim to achieve trapping for larger number of particles and to study microparticle dynamical stability in electrodynamic fields. We report emergence of planar and volume ordered structures of the microparticles, depending on the a.c. trapping frequency and particle specific charge ratio. The electric potential within the trap was mapped using the electrolytic tank method. Particle dynamics was simulated using a stochastic Langevin equation. We emphasize extended regions of stable trapping with respect to quadrupole traps, as well as good agreement between experiment and numerical simulations.

  11. The Influence of Ambient Temperature on the Susceptibility of Aedes aegypti (Diptera: Culicidae) to the Pyrethroid Insecticide Permethrin.

    Science.gov (United States)

    Whiten, Shavonn R; Peterson, Robert K D

    2016-01-01

    Insecticides are the most common strategy used for the management of mosquitoes. Changes in ambient temperature can alter the toxicity of insecticides to ectothermic organisms. Studies show organophosphate insecticides exhibit a positive correlation between ambient temperature and mortality for many insect species, and carbamate insecticides exhibit a slightly negative correlation between ambient temperature and mortality. Pyrethroid insecticides exhibit a distinctly negative correlation between increasing ambient temperature and mortality for insects. However, this relationship has not been systematically studied for adult mosquitoes. Therefore, we examined the influence of temperature on the susceptibility of adult Aedes aegypti L. (Diptera: Culicidae) when exposed to permethrin. The median lethal concentration, LC50, was estimated for adult Ae. aegypti when exposed to eight concentrations of permethrin (ranging from 0.06–0.58 ng/cm2) at each of the following temperatures—16, 23, 26, 30, 32, and 34C—for 24 h in bottle assays. The estimated LC50 for each temperature was 0.26, 0.36, 0.36, 0.45, 0.27, and 0.31 ng/cm2, respectively. Results indicated a negative correlation between temperature and mortality from 16 to 30C, a positive correlation between temperature and mortality from 30 to 32C, and a negative correlation between temperature and mortality from 32 to 34C. If mosquito populations are expanding in space and time because of increased ambient temperatures and cannot be managed as effectively with pyrethroids, the spread of mosquito-borne diseases may pose considerable additional risk to public health.

  12. Polymer Electrolyte-Based Ambient Temperature Oxygen Microsensors for Environmental Monitoring

    Science.gov (United States)

    Hunter, Gary W.; Xu, Jennifer C.; Liu, Chung-Chiun

    2011-01-01

    An ambient temperature oxygen microsensor, based on a Nafion polymer electrolyte, has been developed and was microfabricated using thin-film technologies. A challenge in the operation of Nafion-based sensor systems is that the conductivity of Nafion film depends on the humidity in the film. Nafion film loses conductivity when the moisture content in the film is too low, which can affect sensor operation. The advancement here is the identification of a method to retain the operation of the Nafion films in lower humidity environments. Certain salts can hold water molecules in the Nafion film structure at room temperature. By mixing salts with the Nafion solution, water molecules can be homogeneously distributed in the Nafion film increasing the film s hydration to prevent Nafion film from being dried out in low-humidity environment. The presence of organics provides extra sites in the Nafion film to promote proton (H+) mobility and thus improving Nafion film conductivity and sensor performance. The fabrication of ambient temperature oxygen microsensors includes depositing basic electrodes using noble metals, and metal oxides layer on one of the electrode as a reference electrode. The use of noble metals for electrodes is due to their strong catalytic properties for oxygen reduction. A conducting polymer Nafion, doped with water-retaining components and extra sites facilitating proton movement, was used as the electrolyte material, making the design adequate for low humidity environment applications. The Nafion solution was coated on the electrodes and air-dried. The sensor operates at room temperature in potentiometric mode, which measures voltage differences between working and reference electrodes in different gases. Repeat able responses to 21-percent oxygen in nitrogen were achieved using nitrogen as a baseline gas. Detection of oxygen from 7 to 21 percent has also been demonstrated. The room-temperature oxygen micro sensor developed has extremely low power

  13. Identification of the Products of Oxidation of Quercetin by Air Oxygenat Ambient Temperature

    Directory of Open Access Journals (Sweden)

    Viktor A Utsal

    2007-03-01

    Full Text Available Oxidation of quercetin by air oxygen takes place in water and aqueous ethanol solutions under mild conditions, namely in moderately-basic media (pH ∼ 8-10 at ambient temperature and in the absence of any radical initiators, without enzymatic catalysis or irradiation of the reaction media by light. The principal reaction products are typical of other oxidative degradation processes of quercetin, namely 3,4-dihydroxy-benzoic (proto-catechuic and 2,4,6-trihydroxybenzoic (phloroglucinic acids, as well as the decarboxylation product of the latter – 1,3,5-trihydroxybenzene (phloroglucinol. In accordance with the literature data, this process involves the cleavage of the γ-pyrone fragment (ring C of the quercetin molecule by oxygen, with primary formation of 4,6-dihydroxy-2-(3,4-dihydroxybenzoyloxybenzoic acid (depside. However under such mild conditions the accepted mechanism of this reaction (oxidative decarbonylation with formation of carbon monoxide, CO should be reconsidered as preferably an oxidative decarboxylation with formation of carbon dioxide, CO2. Direct head-space analysis of the gaseous components formed during quercetin oxidation in aqueous solution at ambient temperature indicates that the ratio of carbon dioxide/carbon monoxide in the gas phase after acidification of the reaction media is ca. 96:4 %. Oxidation under these mild conditions is typical for other flavonols having OH groups at C3 (e.g., kaempferol, but it is completely suppressed if this hydroxyl group is substituted by a glycoside fragment (as in rutin, or a methyl substituent. An alternative oxidation mechanism involving the direct cleavage of the C2-C3 bond in the diketo-tautomer of quercetin is proposed.

  14. The Effect of High Ambient Temperature on the Elderly Population in Three Regions of Sweden

    Directory of Open Access Journals (Sweden)

    Joacim Rocklöv

    2010-06-01

    Full Text Available The short-term effects of high temperatures are a serious concern in the context of climate change. In areas that today have mild climates the research activity has been rather limited, despite the fact that differences in temperature susceptibility will play a fundamental role in understanding the exposure, acclimatization, adaptation and health risks of a changing climate. In addition, many studies employ biometeorological indexes without careful investigation of the regional heterogeneity in the impact of relative humidity. We aimed to investigate the effects of summer temperature and relative humidity and regional differences in three regions of Sweden allowing for heterogeneity of the effect over the scale of summer temperature. To do so, we collected mortality data for ages 65+ from Stockholm, Göteborg and Skåne from the Swedish National Board of Health and Welfare and the Swedish Meteorological and Hydrological Institute for the years 1998 through 2005. In Stockholm and Skåne on average 22 deaths per day occurred, while in Göteborg the mean frequency of daily deaths was 10. We fitted time-series regression models to estimate relative risks of high ambient temperatures on daily mortality using smooth functions to control for confounders, and estimated non-linear effects of exposure while allowing for auto-regressive correlation of observations within summers. The effect of temperature on mortality was found distributed over the same or following day, with statistically significant cumulative combined relative risk of about 5.1% (CI = 0.3, 10.1 per °C above the 90th percentile of summer temperature. The effect of high relative humidity was statistically significant in only one of the regions, as was the effect of relative humidity (above 80th percentile and temperature (above 90th percentile. In the southernmost region studied there appeared to be a significant increase in mortality with decreasing low summer temperatures that was not

  15. Influence of / ratio on rate of chloride induced corrosion of steel reinforcement and its dependence on ambient temperature

    Indian Academy of Sciences (India)

    V Živica

    2003-08-01

    The permeability of the embedding cement material for the rate of chloride induced corrosion when the ambient temperature is increased has found a dominant position. The importance of the given permeability in the process is based on the fact that it represents a factor conditioning the possibility of the escaping of the unambiguous reaction partners, oxygen and water vapour, from the system embedding cement material-steel, as the ambient temperature is increased. The resulting effect is a slowing down of the corrosion rate when the / ratio over the value 0.6 and the ambient temperature over the value 40°C are increased. Due to the similarity of the chemism of the corrosion process of steel reinforcement, independent of the action of aggressive species, the found relationships are generally valid, e.g. for the corrosion due to carbonation.

  16. Synthesis of tin nanocrystals in room temperature ionic liquids

    OpenAIRE

    Le Vot, Steven; Dambournet, Damien; Groult, Henri; Ngo, Anh-tu; Petit, Christophe; Rizzi, Cécile; Salzemann, Caroline; Sirieix-Plenet, Juliette; Borkiewicz, Olaf J.; Raymundo-Piñero, Encarnación; Gaillon, Laurent

    2014-01-01

    International audience The aim of this work was to investigate the synthesis of tin nanoparticles (NPs) or tin/carbon composites, in room temperature ionic liquids (RTILs), that could be used as structured anode materials for Li-ion batteries. An innovative route for the synthesis of Sn nanoparticles in such media is successfully developed. Compositions, structures, sizes and morphologies of NPs were characterized by high-energy X-ray diffraction (HEXRD), X-ray photoelectron spectroscopy (...

  17. Cold-start emissions of modern passenger cars at different low ambient temperatures and their evolution over vehicle legislation categories

    Science.gov (United States)

    Weilenmann, Martin; Favez, Jean-Yves; Alvarez, Robert

    The emissions of modern gasoline and diesel passenger cars are reduced by catalysts except in cold-starting. Since catalysts require a certain temperature (typically above 300 °C) to work to full efficiency, emissions are significantly higher during the warm-up phase of the car. The duration of this period and the emissions produced depend on the ambient temperature as well as on the initial temperature of the car's propulsion systems. The additional emissions during a warm-up phase, known as "cold-start extra emissions" (CSEEs) for emission inventory modelling, are mostly assessed by emission measurements at an ambient temperature of 23 °C. However, in many European countries average ambient temperatures are below 23 °C. This necessitates emission measurements at lower temperatures in order to model and assess cold-start emissions for real-world temperature conditions. This paper investigates the influence of regulated pollutants and CO 2 emissions of recent gasoline and diesel car models (Euro-4 legislation) at different ambient temperatures, 23, -7 and -20 °C. We present a survey and model of the evolution of cold-start emissions as a function of different car generations (pre-Euro-1 to Euro-4 legislations). In addition the contribution of CSEEs to total fleet running emissions is shown to highlight their increasing importance. For gasoline cars, it turns out that in average real-world driving the majority of the CO (carbon monoxide) and HC (hydrocarbon) total emissions are due to cold-start extra emissions. Moreover, the cold-start emissions increase considerably at lower ambient temperatures. In contrast, cold-start emissions of diesel cars are significantly lower than those of gasoline cars. Furthermore, the transition from Euro-3 to Euro-4 gasoline vehicles shows a trend for a smaller decline for cold-start extra emissions than for legislative limits. Particle and NO x emission of cold-starts are less significant.

  18. Experimental Assessment of residential split type air-conditioning systems using alternative refrigerants to R-22 at high ambient temperatures

    International Nuclear Information System (INIS)

    Highlights: • R290, R407C and R410A in residential split A/C units at high ambient. • 1 and 2 TR residential air conditioners with R22 alternatives at high ambient. • Residential split unit performance at ambients up to 55 °C with R22 alternatives. - Abstract: Steady state performance of residential air conditioning systems using R22 and alternatives R290, R407C, R410A, at high ambient temperatures, have been investigated experimentally. System performance parameters such as optimum refrigerant charge, coefficient of performance, cooling capacity, power consumption, pressure ratio, power per ton of refrigeration and TEWI environmental factor have been determined. All refrigerants were tested in the cooling mode operation under high ambient air temperatures, up to 55 °C, to determine their suitability. Two split type air conditioner of 1 and 2 TR capacities were used. A psychrometric test facility was constructed consisting of a conditioned cool compartment and an environmental duct serving the condenser. Air inside the conditioned compartment was maintained at 25 °C dry bulb and 19 °C wet bulb for all tests. In the environmental duct, the ambient air temperature was varied from 35 °C to 55 °C in 5 °C increments. The study showed that R290 is the better candidate to replace R22 under high ambient air temperatures. It has lower TEWI values and a better coefficient of performance than the other refrigerants tested. It is suitable as a drop-in refrigerant. R407C has the closest performance to R22, followed by R410A

  19. Influence of ambient temperature and AC magnetic field on damping behavior of Fe-13Cr-2.5Mo alloy

    Science.gov (United States)

    Xu, Yong-gang; Li, Ning; Shen, Bao-luo; Hua, Hong-xing

    2007-07-01

    The damping behaviors of Fe-13Cr-2.5Mo alloy at ambient temperatures and the AC magnetic field are tested with the improved reversal torsion machine. The precipitations distributing in the annealed alloy are also observed with SEM. The results show that because the defections decrease during the annealing treatment, causing a higher damping capacity of this alloy. This damping drops linearly to 63% when the ambient temperature changes from 23 °C to 500 °C, resulting from the gradual decrease of ferromagnetism. On the other hand, the AC magnetic field causes the damping capacity to drop sharply, and finally it reaches a much lower level.

  20. Temperature-enhanced synthesis of DMSO-Melanin

    Science.gov (United States)

    Piacenti-Silva, M.; Bronze-Uhle, E. S.; Paulin, J. V.; Graeff, C. F. O.

    2014-01-01

    Melanins are a class of pigmentary conjugated macromolecules found in many biological systems. Functionalization of synthetic melanin provides interesting new properties like the greater solubility of melanin synthesized in dimethyl sulfoxide, D-Melanin. In this work we have studied the influence of temperature on D-Melanin synthesis and its properties. To this end, UV-Vis, Fourier-transform infrared (FTIR) spectroscopy and Nuclear Magnetic Resonance (NMR) techniques have been employed to analyze D-Melanin synthesized within the range of 25-100 °C. Our results reveal that by increasing the synthesis temperature up to 100 °C, the synthesis time can be decreased by a factor of 7 when compared to room temperature. From FTIR and 13C CP/MAS NMR analyses the increase in temperature causes a decrease in the number of carbonyl groups from carboxylic acid and from ionized carboxylic acid. The decarboxylation of D-Melanin monomers at higher temperatures shows that the use of higher synthesis temperatures influences the elimination of carbonyls present in the precursor molecules, thus facilitating the polymerization of D-Melanin.

  1. Viscoelasticity of ambient-temperature nematic binary mixtures of bent-core and rodlike molecules.

    Science.gov (United States)

    Sathyanarayana, P; Jampani, V S R; Skarabot, M; Musevic, I; Le, K V; Takezoe, H; Dhara, S

    2012-01-01

    We report measurements of the temperature variations of physical parameters in ambient-temperature nematic liquid crystal mixtures of bent-core (BC) and rodlike molecules (5CB): birefringence Δn; static dielectric constants ε(||) and ε(⊥); splay K(11) and bend K(33) elastic constants; rotational viscosity γ(1); and diffusion coefficients D(||) and D(⊥) of a microsphere. Both Δn and ε(||) decreases rapidly with increasing BC concentration, whereas ε(⊥) remains almost constant. At a shifted temperature (e.g., T-T(NI)=-10 °C), K(11) increases by ~50% and K(33) decreases by ~80% compared to pure 5CB when the BC concentration is increased to ~43 mol % in the mixture. Viscosities parallel and perpendicular to the director, η(||), η(⊥), which are nearly equal to the Miesowicz viscosities η(2) and η(3), respectively, were obtained by D(||) and D(⊥) using the Stokes-Einstein relation. Both the viscosities at room temperature increase by 60 and 50 times, respectively, whereas γ(1) increases by 180 times (at ~43 mol %) compared to the corresponding values of pure 5CB. The stiffening of K(11) and exorbitantly large enhancement in all the viscosities at a higher mol % of BC indicate that the viscoelastic properties are highly impacted by the presence of smectic clusters of BC molecules that results from the restricted free rotation of the molecules along the bow axis in the nematic phase. A possible attachment model of smectic type clusters of BC molecules surrounding the microparticle is presented. PMID:22400578

  2. Viscoelasticity of ambient-temperature nematic binary mixtures of bent-core and rodlike molecules

    Science.gov (United States)

    Sathyanarayana, P.; Jampani, V. S. R.; Skarabot, M.; Musevic, I.; Le, K. V.; Takezoe, H.; Dhara, S.

    2012-01-01

    We report measurements of the temperature variations of physical parameters in ambient-temperature nematic liquid crystal mixtures of bent-core (BC) and rodlike molecules (5CB): birefringence Δn; static dielectric constants ɛ|| and ɛ⊥; splay K11 and bend K33 elastic constants; rotational viscosity γ1; and diffusion coefficients D|| and D⊥ of a microsphere. Both Δn and ɛ|| decreases rapidly with increasing BC concentration, whereas ɛ⊥ remains almost constant. At a shifted temperature (e.g., T-TNI=-10∘C), K11 increases by ˜50% and K33 decreases by ˜80% compared to pure 5CB when the BC concentration is increased to ˜43 mol % in the mixture. Viscosities parallel and perpendicular to the director, η||, η⊥, which are nearly equal to the Miesowicz viscosities η2 and η3, respectively, were obtained by D|| and D⊥ using the Stokes-Einstein relation. Both the viscosities at room temperature increase by 60 and 50 times, respectively, whereas γ1 increases by 180 times (at ˜43 mol %) compared to the corresponding values of pure 5CB. The stiffening of K11 and exorbitantly large enhancement in all the viscosities at a higher mol % of BC indicate that the viscoelastic properties are highly impacted by the presence of smectic clusters of BC molecules that results from the restricted free rotation of the molecules along the bow axis in the nematic phase. A possible attachment model of smectic type clusters of BC molecules surrounding the microparticle is presented.

  3. Ambient-temperature high damping capacity in TiPd-based martensitic alloys

    Energy Technology Data Exchange (ETDEWEB)

    Xue, Dezhen [Multi-disciplinary Materials Research Center, Frontier Institute of Science and Technology, State Key Laboratory for Mechanical Behavior of Materials, Xi' an Jiaotong University, Xi' an 710049 (China); Theoretical Division, Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Zhou, Yumei, E-mail: zhouyumei@mail.xjtu.edu.cn [Multi-disciplinary Materials Research Center, Frontier Institute of Science and Technology, State Key Laboratory for Mechanical Behavior of Materials, Xi' an Jiaotong University, Xi' an 710049 (China); Ding, Xiangdong [Multi-disciplinary Materials Research Center, Frontier Institute of Science and Technology, State Key Laboratory for Mechanical Behavior of Materials, Xi' an Jiaotong University, Xi' an 710049 (China); Otsuka, Kazuhiro [Ferroic Physics Group, National Institute for Materials Science, Tsukuba 305-0047, Ibaraki (Japan); Lookman, Turab [Theoretical Division, Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Sun, Jun [Multi-disciplinary Materials Research Center, Frontier Institute of Science and Technology, State Key Laboratory for Mechanical Behavior of Materials, Xi' an Jiaotong University, Xi' an 710049 (China); Ren, Xiaobing [Multi-disciplinary Materials Research Center, Frontier Institute of Science and Technology, State Key Laboratory for Mechanical Behavior of Materials, Xi' an Jiaotong University, Xi' an 710049 (China); Ferroic Physics Group, National Institute for Materials Science, Tsukuba 305-0047, Ibaraki (Japan)

    2015-04-24

    Shape memory alloys (SMAs) have attracted considerable attention for their high damping capacities. Here we investigate the damping behavior of Ti{sub 50}(Pd{sub 50−x}D{sub x}) SMAs (D=Fe, Co, Mn, V) by dynamic mechanical analysis. We find that these alloys show remarkably similar damping behavior. There exists a sharp damping peak associated with the B2–B19 martensitic transformation and a high damping plateau (Q{sup −1}~0.02–0.05) over a wide ambient-temperature range (220–420 K) due to the hysteretic twin boundary motion. After doping hydrogen into the above alloys, a new relaxation-type damping peak appears in the martensite phase over 270–360 K. Such a peak is considered to originate from the interaction of hydrogen atoms with twin boundaries and the corresponding damping capacity (Q{sup −1}~0.05–0.09) is enhanced by roughly twice that of the damping plateau for each alloy. Moreover, the relaxation peaks are at higher temperatures for the TiPd-based alloys (270–370 K) than for the TiNi-based alloys (190–260 K). We discuss the influence of hydrogen diffusion, mobility of twin boundaries and hydrogen–twin boundary interaction on the temperature range of the relaxation peak. Our results suggest that a martensite, with appropriate values for twinning shear and hydrogen doping level, provides a route towards developing high damping SMAs for applications in desired temperature ranges.

  4. Non-contact skin emissivity: measurement from reflectance using step change in ambient radiation temperature.

    Science.gov (United States)

    Togawa, T

    1989-02-01

    A method of estimating skin emissivity based on reflectance measurement upon transient stepwise change in the ambient radiation temperature was proposed. To effect this change, two shades at different temperatures were switched mechanically, and the change in radiation from the skin surface was recorded through an aperture for each shade by a high-resolution, fast-response radiometer having a sensitivity within the 8-14 microns range. Measurements were made on the forehead, forearm, palm and back of the hand in 10 male and 10 female subjects. No significant differences in emissivity were observed among sites and between sexes. The overall average of the skin emissivity obtained was 0.971 +/- 0.005 (SD). This result is inconsistent with most reported skin emissivity values. However, as the former studies had many inherent inadequacies, both theoretical and experimental, it is considered that most of these reported skin emissivities are unacceptable. The method proposed in this study has the following advantages: (1) relative calibration between instruments is unnecessary, (2) non-contact measurement can be achieved, and (3) each measurement can be made within one minute.

  5. Enrichment of denitrifying methanotrophic bacteria from Taihu sediments by a membrane biofilm bioreactor at ambient temperature.

    Science.gov (United States)

    Wang, Shenghui; Wu, Qing; Lei, Ting; Liang, Peng; Huang, Xia

    2016-03-01

    Denitrification coupled to anaerobic methane oxidation is a recently discovered process performed by bacteria affiliated to the NC10 phylum. These microorganisms could play important roles in the energy-efficient way of anaerobic wastewater treatment where residual dissolved methane might be removed at the expense of nitrate or nitrite. The difficulty to enrich these microorganisms due to a slow growth rate, especially at low temperatures, limited its application in engineering field. In this study, an NC10 bacteria community was enriched from Taihu sediments by a membrane biofilm bioreactor at ambient temperature of 10-25 °C. After 13 months enrichment, the maximum denitrification rate of the enriched culture reached 0.54 mM day(-1) for nitrate and 1.06 mM day(-1) for nitrite. Anaerobic methane oxidation coupled denitrification was estimated from the (13)C-labeled CO2 ((13)CO2) production during batch incubations with (13)CH4. Furthermore, analysis of 16S rRNA genes clone library confirmed the presence of NC10 phylum bacteria and fluorescence in situ hybridization showed that NC10 bacteria dominated the reactor. All of the results indicated the NC10 bacteria community was competitive in terms of treating nitrate-contaminated water or wastewater under natural conditions. PMID:26578374

  6. Systematic effects from an ambient-temperature, continuously rotating half-wave plate

    Science.gov (United States)

    Essinger-Hileman, T.; Kusaka, A.; Appel, J. W.; Choi, S. K.; Crowley, K.; Ho, S. P.; Jarosik, N.; Page, L. A.; Parker, L. P.; Raghunathan, S.; Simon, S. M.; Staggs, S. T.; Visnjic, K.

    2016-09-01

    We present an evaluation of systematic effects associated with a continuously rotating, ambient-temperature half-wave plate (HWP) based on two seasons of data from the Atacama B-Mode Search (ABS) experiment located in the Atacama Desert of Chile. The ABS experiment is a microwave telescope sensitive at 145 GHz. Here we present our in-field evaluation of celestial (Cosmic Microwave Background (CMB) plus galactic foreground) temperature-to-polarization leakage. We decompose the leakage into scalar, dipole, and quadrupole leakage terms. We report a scalar leakage of ˜0.01%, consistent with model expectations and an order of magnitude smaller than other CMB experiments have been reported. No significant dipole or quadrupole terms are detected; we constrain each to be <0.07% (95% confidence), limited by statistical uncertainty in our measurement. Dipole and quadrupole leakage at this level lead to systematic error on r ≲ 0.01 before any mitigation due to scan cross-linking or boresight rotation. The measured scalar leakage and the theoretical level of dipole and quadrupole leakage produce systematic error of r < 0.001 for the ABS survey and focal-plane layout before any data correction such as so-called deprojection. This demonstrates that ABS achieves significant beam systematic error mitigation from its HWP and shows the promise of continuously rotating HWPs for future experiments.

  7. Systematic effects from an ambient-temperature, continuously-rotating half-wave plate

    CERN Document Server

    Essinger-Hileman, T; Appel, J W; Choi, S K; Crowley, K; Jarosik, N; Page, L A; Parker, L P; Raghunathan, S; Simon, S M; Staggs, S T; Visnjic, K

    2016-01-01

    We present an evaluation of systematic effects associated with a continuously-rotating, ambient-temperature half-wave plate (HWP) based on two seasons of data from the Atacama B-Mode Search (ABS) experiment located in the Atacama Desert of Chile. The ABS experiment is a microwave telescope sensitive at 145 GHz. The HWP allows for rejection of unpolarized atmospheric fluctuations and ground pickup, as well as clear separation of celestial polarization from intensity. In a previous paper, we demonstrated 30 dB rejection of atmospheric fluctuations on timescales of 500 s. Here we present our in-field evaluation of celestial (CMB plus galactic foreground) temperature-to-polarization leakage. We decompose the leakage into scalar, dipole, and quadrupole leakage terms. We report a scalar leakage of ~0.01%, consistent with model expectations and an order of magnitude smaller than other CMB experiments have reported. No significant dipole or quadruple terms are detected; we constrain each to be < 0.06% (95% confide...

  8. Humidity-resistant ambient-temperature solid-electrolyte amperometric sensing apparatus

    Science.gov (United States)

    Zaromb, Solomon

    1994-01-01

    Apparatus and methods for detecting selected chemical compounds in air or other gas streams at room or ambient temperature includes a liquid-free humidity-resistant amperometric sensor comprising a sensing electrode and a counter and reference electrode separated by a solid electrolyte. The sensing electrode preferably contains a noble metal, such as Pt black. The electrolyte is water-free, non-hygroscopic, and substantially water-insoluble, and has a room temperature ionic conductivity .gtoreq.10.sup.-4 (ohm-cm).sup.-1, and preferably .gtoreq.0.01 (ohm-cm).sup.-1. The conductivity may be due predominantly to Ag+ ions, as in Ag.sub.2 WO.sub.4.4AgI, or to F- ions, as in Ce.sub.0.95 Ca.sub.0.05 F.sub.2.95. Electrical contacts serve to connect the electrodes to potentiostating and detecting circuitry which controls the potential of the sensing electrode relative to the reference electrode, detects the signal generated by the sensor, and indicates the detected signal.

  9. Humidity-resistant ambient-temperature solid-electrolyte amperometric sensing apparatus and methods

    Science.gov (United States)

    Zaromb, Solomon

    2001-01-01

    Apparatus and methods for detecting selected chemical compounds in air or other gas streams at room or ambient temperature includes a liquid-free humidity-resistant amperometric sensor comprising a sensing electrode and a counter and reference electrode separated by a solid electrolyte. The sensing electrode preferably contains a noble metal, such as Pt black. The electrolyte is water-free, non-hygroscopic, and substantially water-insoluble, and has a room temperature ionic conductivity .gtoreq.10.sup.-4 (ohm-cm).sup.-1, and preferably .gtoreq.0.01 (ohm-cm).sup.-1. The conductivity may be due predominantly to Ag+ ions, as in Ag.sub.2 WO.sub.4.4AgI, or to F- ions, as in Ce.sub.0.95 Ca.sub.0.05 F.sub.2.95. Electrical contacts serve to connect the electrodes to potentiostating and detecting circuitry which controls the potential of the sensing electrode relative to the reference electrode, detects the signal generated by the sensor, and indicates the detected signal.

  10. Synthesis of novel Ru2C under high pressure-high temperature conditions.

    Science.gov (United States)

    Sanjay Kumar, N R; Chandra Shekar, N V; Chandra, Sharat; Basu, Joysurya; Divakar, R; Sahu, P Ch

    2012-09-12

    We report here, for the first time, synthesis of the Fe(2)N type hexagonal phase of ruthenium carbide by a high pressure-high temperature technique using a laser heated diamond anvil cell (LHDAC). The synthesis is carried out by laser heating a mixture of pure elements, Ru and C, at very low 'pressure' of 5 GPa and T ~ 2000 K. The structure of the temperature quenched high pressure phase is characterized by in situ high pressure x-ray diffraction (HPXRD) and is corroborated by ex situ TEM imaging and diffraction, carried out for the first time on the retrieved sample synthesized by LHDAC. The lattice parameters of Ru(2)C at ambient pressure are found to be a = 2.534 Å and c = 4.147 Å. In situ HPXRD studies up to 14.2 GPa yield a bulk modulus of 178(4) GPa. Electronic structure calculations reveal the system to be metallic in nature with a degree of covalence along the Ru-C bond. As ruthenium is isoelectronic to osmium, this result for Ru(2)C has significant implications in the synthesis and study of osmium carbides. PMID:22906879

  11. Surface-initiated atom transfer radical polymerization of methyl methacrylate from magnetite nanoparticles at ambient temperature.

    Science.gov (United States)

    Raghuraman, G K; Dhamodharan, R

    2006-07-01

    The synthesis of methyl methacrylate (MMA) brush from the surface of magnetite nanoparticles (core-shell structure), from initiator moieties anchored covalently to the nanoparticles, via room temperature atom transfer radical polymerization (ATRP) is described. The surface-initiated polymerization was carried out from a surface-confined initiator containing a 2-bromoisobutyrate moiety with Cu(I)Br/PMDETA catalytic system. The initiator moiety was covalently anchored to the nanoparticles via a two step modification reaction scheme. Controlled polymerization was observed if ethyl-2-bromoisobutyrate (2-EiBrB) was added as a free/sacrificial initiator. A linear increase of molecular weight and a narrow molecular weight distribution of the PMMA formed in solution, provide evidence for a controlled surface-initiated polymerization, leading to surface-attached polymer brushes under mild conditions. The grafted PMMA provides good stability and dispersibility for the nanoparticles in organic solvents.

  12. Moderate Temperature Synthesis of Mesoporous Carbon

    KAUST Repository

    Dua, Rubal

    2013-01-03

    Methods and composition for preparation of mesoporous carbon material are provided. For example, in certain aspects methods for carbonization and activation at selected temperature ranges are described. Furthermore, the invention provides products prepared therefrom.

  13. Staying cool in a changing landscape: the influence of maximum daily ambient temperature on grizzly bear habitat selection.

    Science.gov (United States)

    Pigeon, Karine E; Cardinal, Etienne; Stenhouse, Gordon B; Côté, Steeve D

    2016-08-01

    To fulfill their needs, animals are constantly making trade-offs among limiting factors. Although there is growing evidence about the impact of ambient temperature on habitat selection in mammals, the role of environmental conditions and thermoregulation on apex predators is poorly understood. Our objective was to investigate the influence of ambient temperature on habitat selection patterns of grizzly bears in the managed landscape of Alberta, Canada. Grizzly bear habitat selection followed a daily and seasonal pattern that was influenced by ambient temperature, with adult males showing stronger responses than females to warm temperatures. Cutblocks aged 0-20 years provided an abundance of forage but were on average 6 °C warmer than mature conifer stands and 21- to 40-year-old cutblocks. When ambient temperatures increased, the relative change (odds ratio) in the probability of selection for 0- to 20-year-old cutblocks decreased during the hottest part of the day and increased during cooler periods, especially for males. Concurrently, the probability of selection for 21- to 40-year-old cutblocks increased on warmer days. Following plant phenology, the odds of selecting 0- to 20-year-old cutblocks also increased from early to late summer while the odds of selecting 21- to 40-year-old cutblocks decreased. Our results demonstrate that ambient temperatures, and therefore thermal requirements, play a significant role in habitat selection patterns and behaviour of grizzly bears. In a changing climate, large mammals may increasingly need to adjust spatial and temporal selection patterns in response to thermal constraints.

  14. Tandem olefin metathesis/hydrogenation at ambient temperature: activation of ruthenium carbene complexes by addition of hydrides.

    Science.gov (United States)

    Schmidt, Bernd; Pohler, Michael

    2003-07-21

    Sodium hydride activates ruthenium carbene complexes to catalyze hydrogenation reactions subsequent to ring closing olefin metathesis. Under these conditions, hydrogenation of cyclopentenols proceeds smoothly at ambient temperature and under 1 atm of hydrogen in toluene. An alternative protocol was developed that involves the formation of hydrogen in situ by reaction of excess sodium hydride with protic functional groups and water. PMID:12956069

  15. Egg weights, egg component weights, and laying gaps in Great Tits (Parus major) in relation to ambient temperature

    NARCIS (Netherlands)

    Lessells, C.M.; Dingemanse, N.J.; Both, C.; Blem, C.

    2002-01-01

    We collected 328 freshly laid Great Tit (Parus major) eggs from 38 clutches in 1999 to determine the relationship of whole egg weight, wet yolk weight, wet albumen weight, dry shell weight, and the occurrence of laying gaps with mean ambient temperature in the three days preceding laying, while cont

  16. A note on eating behaviour of dairy cows at different stocking systems - diurnal rhythm and effects of ambient temperature

    NARCIS (Netherlands)

    Taweel, H.Z.; Tas, B.M.; Smit, H.J.; Tamminga, S.; Elgersma, A.

    2006-01-01

    This experiment was aimed at studying the diurnal rhythm of dairy cows eating behaviour at different stocking systems, and quantifying the effect of daily ambient temperature on this diurnal rhythm. In two experiments carried out in the summer of 2003 in The Netherlands, eight dairy cows were offere

  17. Sloths like it hot: ambient temperature modulates food intake in the brown-throated sloth (Bradypus variegatus

    Directory of Open Access Journals (Sweden)

    Rebecca N. Cliffe

    2015-04-01

    Full Text Available Sloths are considered to have one of the lowest mass-specific metabolic rates of any mammal and, in tandem with a slow digestive rate, have been theorized to have correspondingly low rates of ingestion. Here, we show in a study conducted over five months, that three captive Bradypus variegatus (Brown-throated sloths had a remarkably low mean food intake of 17 g kg−1day−1 (SD 4.2. Food consumption was significantly affected by ambient temperature, with increased intake at higher temperatures. We suggest that the known fluctuation of sloth core body temperature with ambient temperature affects the rate at which gut fauna process digesta, allowing for increased rates of fermentation at higher temperatures. Since Bradypus sloths maintain a constantly full stomach, faster rates of fermentation should enhance digestive throughput, increasing the capacity for higher levels of food intake, thereby allowing increased energy acquisition at higher ambient temperatures. This contrasts with other mammals, which tend to show increased levels of food intake in colder conditions, and points to the importance of temperature in regulating all aspects of energy use in sloths.

  18. Synthesis of hexagonal Ni{sub 3}N using high pressures and temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Guillaume, C [University of Edinburgh, School of Engineering and Electronics and Centre for Materials Science, Kings Buildings, Mayfield Road, EH9 3JL (United Kingdom); Morniroli, J P [Laboratoire de Metallurgie Physique et Genie des Materiaux, UMR CNRS 8517, Universite des Sciences et Technologies de Lille et Ecole Nationale Superieure de Chimie de Lille, Cite Scientifique, 59655 Villeneuve d' Ascq Cedex (France); Frost, D J [Bayerisches Geoinstitut, Universitat Bayreuth, D-95440, Bayreuth (Germany); Serghiou, G [University of Edinburgh, School of Engineering and Electronics and Centre for Materials Science, Kings Buildings, Mayfield Road, EH9 3JL (United Kingdom)

    2006-09-20

    The only known bulk ambient pressure nickel nitride phase is hexagonal Ni{sub 3}N (space group P6{sub 3}22). Multianvil synthesis experiments at 20 GPa and 2000 K using nickel (Ni) and sodium azide (NaN{sub 3}) starting materials, and ex situ analysis using transmission electron microscopy and scanning electron microscopy measurements show that this phase can be recovered at ambient pressure (space group P6{sub 3}22, a = 4.62 A, c = 4.30 A, Z = 2). Formation of this phase is correlated with the repulsive interactions between closely spaced nitrogen ions and with the extent of thermal stability of nickel nitride at ambient and at high densities. These two factors are also important in relating the high temperature and pressure behaviour of nickel nitride to those of several other interstitial nitrides recovered from similar pressures after heating. Further, we report formation of a sodium rhenium nitride phase by reaction of the azide with the rhenium capsule in which the reactants were contained.

  19. Design and Application of Variable Temperature Environmental Capsule for Scanning Electron Microscopy in Gases and Liquids at Ambient Conditions

    OpenAIRE

    Al-Asadi, Ahmed S.; Jie ZHANG; Li, Jianbo; Potyrailo, Radislav A.; Kolmakov, Andrei

    2015-01-01

    Scanning electron microscopy (SEM) of nanoscale objects in their native conditions and at different temperatures are of critical importance in revealing details of their interactions with ambient environments. Currently available environmental capsules are equipped with thin electron transparent membranes and allow imaging the samples at atmospheric pressure. However these capsules do not provide the temperature control over the sample. Here we developed and tested a thermoelectric cooling / ...

  20. Strength and Density of Geopolymer Mortar Cured at Ambient Temperature for Use as Repair Material

    Science.gov (United States)

    Warid Wazien, A. Z.; Bakri Abdullah, Mohd Mustafa Al; Abd. Razak, Rafiza; Mohd Remy Rozainy, M. A. Z.; Faheem Mohd Tahir, Muhammad

    2016-06-01

    Geopolymers produced by synthesizing aluminosilicate source materials with an alkaline activator solution promised an excellent properties akin to the existing construction material. This study focused on the effect of various binder to sand ratio on geopolymer mortar properties. Mix design of geopolymer mortar was produced using NaOH concentration of 12 molars, ratio of fly ash/alkaline activator and ratio Na2SiO3/NaOH of 2.0 and 2.5 respectively. Samples subsequently ware cured at ambient temperature. The properties of geopolymer mortar were analysed in term of compressive strength and density at different period which are on the 3rd and 7th day of curing. Experimental results revealed that the addition of sand slightly increase the compressive strength of geopolymer. The optimum compressive strength obtained was up to 31.39 MPa on the 7th day. The density of geopolymer mortar was in the range between 2.0 g/cm3 to 2.23 g/cm3. Based on this findings, the special properties promoted by geopolymer mortar display high potential to be implemented in the field of concrete patch repair.

  1. Male weasels decrease activity and energy expenditure in response to high ambient temperatures.

    Directory of Open Access Journals (Sweden)

    Karol Zub

    Full Text Available The heat dissipation limit (HDL hypothesis suggests that the capacity of endotherms to dissipate body heat may impose constraints on their energy expenditure. Specifically, this hypothesis predicts that endotherms should avoid the detrimental consequences of hyperthermia by lowering their energy expenditure and reducing their activity in response to high ambient temperatures (T(a. We used an extensive data set on the daily energy expenditure (DEE, n = 27 and the daily activity time (AT, n = 48 of male weasels (Mustela nivalis during the spring and summer breeding season to test these predictions. We found that T(a was related in a "hump-shaped" (i.e. convex manner to AT, DEE, resting metabolic rate (RMR and metabolic scope (the ratio of DEE to RMR. These results support the HDL hypothesis because in response to warm Tas male weasels reduced their AT, DEE, and RMR. Although the activity and energy expenditure of large endotherms are most likely to be constrained in response to warm Tas because they are less able to dissipate heat, our results suggest that small endotherms may also experience constraints consistent with the HDL hypothesis.

  2. Examination of design options for 35 Ah ambient temperature Li-TiS sub 2 cells

    Science.gov (United States)

    Shen, D. H.; Rao, S. S.; Yen, S. P. S.; Somoano, R. B.

    1986-01-01

    The Jet Propulsion Laboratory is actively engaged in the development of ambient temperature rechargable lithium cells for future NASA geosynchronous Earth orbit (GEO) missions. To achieve these ambitious goals, Li-TiS2, Li-MoS3, and Li-V6O13 systems were examined in detail. Among these three, the Li-TiS2 system has shown the longest life cycle and highest rate capability. Experimental Li-TiS2 batteries (10.5 V, 0.4 Ah) developed in-house have completed eight simulated and accelerated GEO seasons successfully. Inview of the encouraging results, the design options were examined for a scaled-up Li-TiS2 cell. It is hoped that the results of these studies will provide guidelines for prioritizing the research efforts and guiding the selection of optimized materials. Designs for 35 Ah Li-TiS2 cell were examined because present day geosynchronous satellites are powered by batteries of 35 Ah capacity. A computer program was developed to evaluate the influence of various design parameters on the specific energy and the rate capability of the cells.

  3. Adsorptive removal of sulfur compounds using IRMOF-3 at ambient temperature

    International Nuclear Information System (INIS)

    Zinc-based metal–organic framework (IRMOF-3) was used as adsorbent for removal of dimethyl sulfide, ethyl mercaptan and hydrogen sulfide in fixed bed reactor at ambient temperature. These samples before and after exposure to sulfur compounds were characterized by Fourier transform infrared (FTIR), and X-ray diffraction (XRD), and thermo gravimetric (TG), and X-ray photoelectron spectroscopy (XPS). The results show that IRMOF-3 exhibit the best performance for hydrogen sulfide removal with the highest breakthrough sulfur capacity, followed by ethyl mercaptan and dimethyl sulfide. This is in consistent with the interaction strength between IRMOF-3 and sulfur compounds. In the case of dimethyl sulfide and ethyl mercaptan, the interaction comes from the weak interaction between the amino group in the MOFs and the sulfur atom of the adsorbate. This can also be considered as a hydrogen bond complex in which the amino group in the MOFs and the S atom of the sulfur compounds play the role of H-donor and H-acceptor, respectively. In the case of hydrogen sulfide, the interaction with sulfur atom originates from the amino group and zinc site in the MOFs. The former is more like an acid–base interaction, whereas the latter results in new products of ZnS and H2O and serious destruction of the MOFs.

  4. A robust ambient temperature collection and stabilization strategy: Enabling worldwide functional studies of the human microbiome

    Science.gov (United States)

    Anderson, Ericka L.; Li, Weizhong; Klitgord, Niels; Highlander, Sarah K.; Dayrit, Mark; Seguritan, Victor; Yooseph, Shibu; Biggs, William; Venter, J. Craig; Nelson, Karen E.; Jones, Marcus B.

    2016-01-01

    As reports on possible associations between microbes and the host increase in number, more meaningful interpretations of this information require an ability to compare data sets across studies. This is dependent upon standardization of workflows to ensure comparability both within and between studies. Here we propose the standard use of an alternate collection and stabilization method that would facilitate such comparisons. The DNA Genotek OMNIgene∙Gut Stool Microbiome Kit was compared to the currently accepted community standard of freezing to store human stool samples prior to whole genome sequencing (WGS) for microbiome studies. This stabilization and collection device allows for ambient temperature storage, automation, and ease of shipping/transfer of samples. The device permitted the same data reproducibility as with frozen samples, and yielded higher recovery of nucleic acids. Collection and stabilization of stool microbiome samples with the DNA Genotek collection device, combined with our extraction and WGS, provides a robust, reproducible workflow that enables standardized global collection, storage, and analysis of stool for microbiome studies. PMID:27558918

  5. 27AI MAS-NMR study of inorganic polymer formation at ambient temperature

    Institute of Scientific and Technical Information of China (English)

    Sang-Wook AHN; Hee-Soo LEE; Wan-Hee YANG; Jung-Woo LEE; Young-Keun JEONG

    2011-01-01

    Inorganic polymers are a novel class of materials formed by the polymerization of silicon, aluminium and oxygen species to form an amorphous three-dimensional framework structure. The basis of this process is the alkaline solutions to induce a certain amount of Si and Al atoms to dissolve from a feedstock such as aluminosilicate. A study of 27Al MAS-NMR was carried out in an attempt to understand the reaction mechanism of the inorganic polymerization at ambient temperature. Scanning electron microscopy (SEM) and X-ray diffractometry (XRD) were also employed to establish the composition and microstructure of the inorganic polymerization. Specimens were prepared with different Al/Si mole ratios from the starting materials. The higher the Al content. the more sufficient the Al atoms that can combine with SiO4, and the longer the reaction time. the more the bonded Si-O-Al-O polymer structure, and then the higher the Al content, the fewer the octahedral Al with a uniform Si-O-Al-O structure in four directions, because four Al atoms are combined with SiO4, resulting in a uniform Si-O-Al-O structure in four directions. The results show that they have an amorphous microstructure.

  6. Temperature-induced volatility of molecular markers in ambient airborne particulate matter

    Directory of Open Access Journals (Sweden)

    C. R. Ruehl

    2010-08-01

    Full Text Available Molecular markers are organic compounds used to represent known sources of particulate matter (PM in statistical source apportionment studies. The utility of molecular markers depends on, among other things, their ability to represent PM volatility under realistic atmospheric conditions. We measured the particle-phase concentrations and temperature-induced volatility of commonly-used molecular markers in California's heavily polluted San Joaqin Valley. Concentrations of elemental carbon, organic carbon, levoglucosan, and polycyclic aromatic hydrocarbons were not reduced by mild (~10 K heating. In contrast, both hopane/sterane and n-alkane concentrations were reduced, especially during the summer sampling events at the urban site. These results suggest that hopanes and steranes have effective saturation concentrations ~1 μg m−3, and therefore can be considered semi-volatile in realistic ambient conditions. The volatility behavior of n-alkanes during the urban summer is consistent with that predicted for absorption by suberic acid (a C8 diacid using a group contribution modelling method. Observations can also be matched by an absorbent whose composition is based on recently-obtained high-resolution aerosol mass spectrometer factors (approximately 33% "hydrocarbon-like" and 67% oxygenated organic aerosol. The diminished volatility of the n-alkanes, hopanes, and steranes during rural and/or winter experiments could be explained by a more oxygenated absorbing phase along with a non-absorptive partitioning mechanism, such as adsorption to soot. This suggests that the temperature-induced volatility of large hydrocarbons in PM is most important if a relatively non-polar absorbing organic phase exists. While the activity coefficients of most organic aerosol compounds may be close to unity, the assumption of ideality for large hydrocarbons (e.g., hopanes may result in large errors in partitioning calculations.

  7. Short-term preservation of porcine oocytes in ambient temperature: novel approaches.

    Directory of Open Access Journals (Sweden)

    Cai-Rong Yang

    Full Text Available The objective of this study was to evaluate the feasibility of preserving porcine oocytes without freezing. To optimize preservation conditions, porcine cumulus-oocyte complexes (COCs were preserved in TCM-199, porcine follicular fluid (pFF and FCS at different temperatures (4°C, 20°C, 25°C, 27.5°C, 30°C and 38.5°C for 1 day, 2 days or 3 days. After preservation, oocyte morphology, germinal vesicle (GV rate, actin cytoskeleton organization, cortical granule distribution, mitochondrial translocation and intracellular glutathione level were evaluated. Oocyte maturation was indicated by first polar body emission and spindle morphology after in vitro culture. Strikingly, when COCs were stored at 27.5°C for 3 days in pFF or FCS, more than 60% oocytes were still arrested at the GV stage and more than 50% oocytes matured into MII stages after culture. Almost 80% oocytes showed normal actin organization and cortical granule relocation to the cortex, and approximately 50% oocytes showed diffused mitochondria distribution patterns and normal spindle configurations. While stored in TCM-199, all these criteria decreased significantly. Glutathione (GSH level in the pFF or FCS group was higher than in the TCM-199 group, but lower than in the non-preserved control group. The preserved oocytes could be fertilized and developed to blastocysts (about 10% with normal cell number, which is clear evidence for their retaining the developmental potentiality after 3d preservation. Thus, we have developed a simple method for preserving immature pig oocytes at an ambient temperature for several days without evident damage of cytoplasm and keeping oocyte developmental competence.

  8. The influence of ambient temperature and thermal acclimation on hearing in a eurythermal and a stenothermal otophysan fish.

    Science.gov (United States)

    Wysocki, Lidia Eva; Montey, Karen; Popper, Arthur N

    2009-10-01

    Being ectothermic, fish body temperature generally depends on ambient water temperature. Thus, ambient temperature might affect various sensory systems, including hearing, as a result of metabolic and physiological processes. However, the maintenance of sensory functions in a changing environment may be crucial for an animal's survival. Many fish species rely on hearing for acoustic orientation and communication. In order to investigate the influence of temperature on the auditory system, channel catfish Ictalurus punctatus was chosen as a model for a eurytherm species and the tropical catfish Pimelodus pictus as a model for a stenotherm fish. Hearing sensitivity was measured with animals acclimated or unacclimated to different water temperatures. Ambient water temperature significantly influenced hearing thresholds and the shape of auditory evoked potentials, especially at higher frequencies in I. punctatus. Hearing sensitivity of I. punctatus was lowest at 10 degrees C and increased by up to 36 dB between 10 degrees C and 26 degrees C. Significant differences were also revealed between acclimated and unacclimated animals after an increase in water temperature but not a decrease. By contrast, differences in hearing thresholds were smaller in P. pictus, even if a similar temperature difference (8 degrees C) was considered. However, P. pictus showed a similar trend as I. punctatus in exhibiting higher hearing sensitivity at the highest tested temperature, especially at the highest frequency tested. The results therefore suggest that the functional temperature dependence of sensory systems may differ depending upon whether a species is physiologically adapted to tolerate a wide or narrow temperature range. PMID:19749101

  9. Combustion and Plasma Synthesis of High-Temperature Materials

    Science.gov (United States)

    Munir, Z. A.; Holt, J. B.

    1997-04-01

    KEYNOTE ADDRESS. Self-Propagating High-Temperature Synthesis: Twenty Years of Search and Findings (A. Merzhanov). SOLID-STATE COMBUSTION SYNTHESIS. Recent Progress in Combustion Synthesis of High-Performance Materials in Japan (M. Koizumi & Y. Miyamoto). Modeling and Numerical Computation of a Nonsteady SHS Process (A. Bayliss & B. Matkowsky). New Models of Quasiperiodic Burning in Combustion Synthesis (S. Margolis, et al.). Modeling of SHS Operations (V. Hlavacek, et al.). Combustion Theory for Sandwiches of Alloyable Materials (R. Armstrong & M. Koszykowski). Observations on the Combustion Reaction Between Thin Foils of Ni and Al (U. Anselmi-Tamburini & Z. Munir). Combustion Synthesis of Intermetallic Compounds (Y. Kaieda, et al.). Combustion Synthesis of Nickel Aluminides (B. Rabin, et al.). Self-Propagating High-Temperature Synthesis of NiTi Intermetallics (H. Yi & J. Moore). Shock-Induced Chemical Synthesis of Intermetallic Compounds (S. Work, et al.). Advanced Ceramics Via SHS (T. DeAngelis & D. Weiss). In-Situ Formation of SiC and SiC-C Blocked Solids by Self-Combustion Synthesis (S. Ikeda, et al.). Powder Purity and Morphology Effects in Combustion-Synthesis Reactions (L. Kecskes, et al.). Simultaneous Synthesis and Densification of Ceramic Components Under Gas Pressure by SHS (Y. Miyamoto & M. Koizumi). The Use of Self-Propagating High-Temperature Synthesis of High-Density Titanium Diboride (P. Zavitsanos, et al.). Metal--Ceramic Composite Pipes Produced by a Centrifugal-Thermit Process (O. Odawara). Simultaneous Combustion Synthesis and Densification of AIN (S. Dunmead, et al.). Fabrication of a Functionally Gradient Material by Using a Self-Propagating Reaction Process (N. Sata, et al.). Combustion Synthesis of Oxide-Carbide Composites (L. Wang, et al.). Heterogeneous Reaction Mechanisms in the Si-C System Under Conditions of Solid Combustion (R. Pampuch, et al.). Experimental Modeling of Particle-Particle Interactions During SHS of TiB2 -Al2O3 (K. Logan

  10. Structural and ambient/sub-ambient temperature magnetic properties of Er-substituted cobalt-ferrites synthesized by sol-gel assisted auto-combustion method

    International Nuclear Information System (INIS)

    Er-substituted cobalt-ferrites CoFe2−xErxO4 (0 ≤ x ≤ 0.04) were synthesized by sol-gel assisted auto-combustion method. The precursor powders were calcined at 673–873 K for 4 h, subsequently pressed into pellets and sintered at 1273 K for 4 h. X-ray diffraction (XRD) confirmed the presence of the spinel phase for all the compositions and, additional orthoferrite phase for higher compositions (x = 0.03 and 0.04). The XRD spectra and the Transmission Electron Microscopy micrographs indicate that the nanocrystalline particulates of the Er-substituted cobalt ferrites have crystallite size of ∼120–200 nm. The magnetization curves show an increase in saturation magnetization (MS) and coercivity (HC) for Er-substituted cobalt-ferrites at sub-ambient temperatures. MS for CoFe2O4, CoFe0.99Er0.01O4, CoFe0.98Er0.02O4, and CoFe0.97Er0.03O4 peak at 89.7 Am2/kg, 89.3 Am2/kg, 88.8 Am2/kg, and 87.1 Am2/kg, respectively, at a sub-ambient temperature of ∼150 K. HC substantially increases with decrease in temperature for all the compositions, while it peaks at x = 0.01−0.02 at all temperatures. The combination of Er content—x ∼ 0.02 and the temperature—∼5 K provides the maximum HC ∼ 984 kA/m. Er-substituted cobalt-ferrites have higher cubic anisotropy constant, K1, compared to pure cobalt-ferrite at ambient/sub-ambient temperatures. K1 gradually increases for all compositions in the temperature decreasing from 300 to 100 K. While K1 peaks at ∼150 K for pure cobalt-ferrite, it peaks at ∼50 K for CoFe0.99Er0.01O4, CoFe0.98Er0.02O4, and CoFe0.96Er0.04O4. The MS (∼88.7 Am2/kg), at 5 K, for Er substituted cobalt-ferrite is close to the highest values reported for Sm and Gd substituted cobalt-ferrites. The MS (∼83.5 Am2/kg) at 300 K for Er-substituted cobalt-ferrite is the highest among the lanthanide series element substituted cobalt-ferrites. The HC (at 5 K) for Er substituted cobalt

  11. Plasma synthesis of high temperature ceramic films

    Energy Technology Data Exchange (ETDEWEB)

    Brown, I.G.; Monteiro, O.R.

    1998-11-01

    Thin films of alumina, chromia, mullite, yttria and zirconia have been synthesized using a plasma-based method called metal plasma immersion ion implantation and deposition (Mepiiid)--a highly versatile plasma deposition technique with ion energy control. Monolithic films (a single ceramic component) and multilayer films (individual layers of different ceramic materials) were formed. The films were characterized for their composition and structure in a number of different ways, and the high temperature performance of the films was explored, particularly for their ability to maintain their integrity and adhesion when subjected to repetitive high temperature thermal cycling up 1100 C. We found that the films retain their adhesion and quality without any apparent degradation with time, even after a large number of cycles; (the tests were extended out to a total of 40 cycles each of 24 hours duration). After repetitive high temperature thermal cycling, the film-substrate adhesion was greater than {approx}70 Mpa, the instrumental limit of measurement, and the interface toughness was approximately 0.8 MPa m{sup 1/2}.

  12. Multi-Temperature Zone, Droplet-based Microreactor for Increased Temperature Control in Nanoparticle Synthesis

    KAUST Repository

    Erdem, E. Yegân

    2013-12-12

    Microreactors are an emerging technology for the controlled synthesis of nanoparticles. The Multi-Temperature zone Microreactor (MTM) described in this work utilizes thermally isolated heated and cooled regions for the purpose of separating nucleation and growth processes as well as to provide a platform for a systematic study on the effect of reaction conditions on nanoparticle synthesis. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  13. Solution-phase synthesis of nanomaterials at low temperature

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    This paper reviews the solution-phase synthesis of nanoparticles via some routes at low temperatures, such as room temperature route, wave-assisted synthesis (γ-irradiation route and sonochemical route), directly heating at low temperatures, and hydrothermal/solvothermal methods. A number of strategies were developed to control the shape, the size, as well as the dispersion of nanostructures. Using diethylamine or n-butylamine as solvent, semiconductor nanorods were yielded. By the hydrothermal treatment of amorphous colloids, Bi2S3 nanorods and Se nanowires were obtained. CdS nanowires were prepared in the presence of polyacrylamide. ZnS nanowires were obtained using liquid crystal. The polymer poly (vinyl acetate) tubule acted as both nanoreactor and template for the CdSe nanowire growth. Assisted by the surfactant of sodium dodecyl benzenesulfonate (SDBS), nickel nanobelts were synthesized. In addition, Ag nanowires, Te nanotubes and ZnO nanorod arrays could be prepared without adding any additives or templates.

  14. High atmospheric temperatures and 'ambient incubation' drive embryonic development and lead to earlier hatching in a passerine bird.

    Science.gov (United States)

    Griffith, Simon C; Mainwaring, Mark C; Sorato, Enrico; Beckmann, Christa

    2016-02-01

    Tropical and subtropical species typically experience relatively high atmospheric temperatures during reproduction, and are subject to climate-related challenges that are largely unexplored, relative to more extensive work conducted in temperate regions. We studied the effects of high atmospheric and nest temperatures during reproduction in the zebra finch. We characterized the temperature within nests in a subtropical population of this species in relation to atmospheric temperature. Temperatures within nests frequently exceeded the level at which embryo's develop optimally, even in the absence of parental incubation. We experimentally manipulated internal nest temperature to demonstrate that an average difference of 6°C in the nest temperature during the laying period reduced hatching time by an average of 3% of the total incubation time, owing to 'ambient incubation'. Given the avian constraint of laying a single egg per day, the first eggs of a clutch are subject to prolonged effects of nest temperature relative to later laid eggs, potentially increasing hatching asynchrony. While birds may ameliorate the negative effects of ambient incubation on embryonic development by varying the location and design of their nests, high atmospheric temperatures are likely to constitute an important selective force on avian reproductive behaviour and physiology in subtropical and tropical regions, particularly in the light of predicted climate change that in many areas is leading to a higher frequency of hot days during the periods when birds breed. PMID:26998315

  15. High atmospheric temperatures and ‘ambient incubation’ drive embryonic development and lead to earlier hatching in a passerine bird

    Science.gov (United States)

    Griffith, Simon C.; Mainwaring, Mark C.; Sorato, Enrico; Beckmann, Christa

    2016-01-01

    Tropical and subtropical species typically experience relatively high atmospheric temperatures during reproduction, and are subject to climate-related challenges that are largely unexplored, relative to more extensive work conducted in temperate regions. We studied the effects of high atmospheric and nest temperatures during reproduction in the zebra finch. We characterized the temperature within nests in a subtropical population of this species in relation to atmospheric temperature. Temperatures within nests frequently exceeded the level at which embryo’s develop optimally, even in the absence of parental incubation. We experimentally manipulated internal nest temperature to demonstrate that an average difference of 6°C in the nest temperature during the laying period reduced hatching time by an average of 3% of the total incubation time, owing to ‘ambient incubation’. Given the avian constraint of laying a single egg per day, the first eggs of a clutch are subject to prolonged effects of nest temperature relative to later laid eggs, potentially increasing hatching asynchrony. While birds may ameliorate the negative effects of ambient incubation on embryonic development by varying the location and design of their nests, high atmospheric temperatures are likely to constitute an important selective force on avian reproductive behaviour and physiology in subtropical and tropical regions, particularly in the light of predicted climate change that in many areas is leading to a higher frequency of hot days during the periods when birds breed. PMID:26998315

  16. A Combined State of Charge Estimation Method for Lithium-Ion Batteries Used in a Wide Ambient Temperature Range

    Directory of Open Access Journals (Sweden)

    Fei Feng

    2014-05-01

    Full Text Available Ambient temperature is a significant factor that influences the characteristics of lithium-ion batteries, which can produce adverse effects on state of charge (SOC estimation. In this paper, an integrated SOC algorithm that combines an advanced ampere-hour counting (Adv Ah method and multistate open-circuit voltage (multi OCV method, denoted as “Adv Ah + multi OCV”, is proposed. Ah counting is a simple and general method for estimating SOC. However, the available capacity and coulombic efficiency in this method are influenced by the operating states of batteries, such as temperature and current, thereby causing SOC estimation errors. To address this problem, an enhanced Ah counting method that can alter the available capacity and coulombic efficiency according to temperature is proposed during the SOC calculation. Moreover, the battery SOCs between different temperatures can be mutually converted in accordance with the capacity loss. To compensate for the accumulating errors in Ah counting caused by the low precision of current sensors and lack of accurate initial SOC, the OCV method is used for calibration and as a complement. Given the variation of available capacities at different temperatures, rated/non-rated OCV–SOCs are established to estimate the initial SOCs in accordance with the Ah counting SOCs. Two dynamic tests, namely, constant- and alternated-temperature tests, are employed to verify the combined method at different temperatures. The results indicate that our method can provide effective and accurate SOC estimation at different ambient temperatures.

  17. Ambient-Temperature Passive Magnetic Bearings for Flywheel Energy Storage Systems

    Energy Technology Data Exchange (ETDEWEB)

    Bender, D.; Post, R.

    2000-05-26

    Based on prior work at the Lawrence Livermore National Laboratory ambient-temperature passive magnetic bearings are being adapted for use in high-power flywheel energy storage systems developed at the Trinity Flywheel Power company. En route to this goal specialized test stands have been built and computer codes have been written to aid in the development of the component parts of these bearing systems. The Livermore passive magnetic bearing system involves three types of elements, as follows: (1) Axially symmetric levitation elements, energized by permanent magnets., (2) electrodynamic ''stabilizers'' employing axially symmetric arrays of permanent magnet bars (''Halbach arrays'') on the rotating system, interacting with specially wound electrically shorted stator circuits, and, (3) eddy-current-type vibration dampers, employing axially symmetric rotating pole assemblies interacting with stationary metallic discs. The theory of the Livermore passive magnetic bearing concept describes specific quantitative stability criteria. The satisfaction of these criteria will insure that, when rotating above a low critical speed, a bearing system made up of the three elements described above will be dynamically stable. That is, it will not only be stable for small displacements from equilibrium (''Earnshaw-stable''), but will also be stable against whirl-type instabilities of the types that can arise from displacement-dependent drag forces, or from mechanical-hysteritic losses that may occur in the rotor. Our design problem thus becomes one of calculating and/or measuring the relevant stiffnesses and drag coefficients of the various elements and comparing our results with the theory so as to assure that the cited stability criteria are satisfied.

  18. Alcohol synthesis in a high-temperature slurry reactor

    Energy Technology Data Exchange (ETDEWEB)

    Roberts, G.W.; Marquez, M.A.; McCutchen, M.S. [North Carolina State Univ., Raleigh, NC (United States)

    1995-12-31

    The overall objective of this contract is to develop improved process and catalyst technology for producing higher alcohols from synthesis gas or its derivatives. Recent research has been focused on developing a slurry reactor that can operate at temperatures up to about 400{degrees}C and on evaluating the so-called {open_quotes}high pressure{close_quotes} methanol synthesis catalyst using this reactor. A laboratory stirred autoclave reactor has been developed that is capable of operating at temperatures up to 400{degrees}C and pressures of at least 170 atm. The overhead system on the reactor is designed so that the temperature of the gas leaving the system can be closely controlled. An external liquid-level detector is installed on the gas/liquid separator and a pump is used to return condensed slurry liquid from the separator to the reactor. In order to ensure that gas/liquid mass transfer does not influence the observed reaction rate, it was necessary to feed the synthesis gas below the level of the agitator. The performance of a commercial {open_quotes}high pressure {close_quotes} methanol synthesis catalyst, the so-called {open_quotes}zinc chromite{close_quotes} catalyst, has been characterized over a range of temperature from 275 to 400{degrees}C, a range of pressure from 70 to 170 atm., a range of H{sub 2}/CO ratios from 0.5 to 2.0 and a range of space velocities from 2500 to 10,000 sL/kg.(catalyst),hr. Towards the lower end of the temperature range, methanol was the only significant product.

  19. Cold Start Emissions of Spark-Ignition Engines at Low Ambient Temperatures as an Air Quality Risk

    Directory of Open Access Journals (Sweden)

    Bielaczyc Piotr

    2014-12-01

    Full Text Available SI engines are highly susceptible to excess emissions when started at low ambient temperatures. This phenomenon has multiple air quality and climate forcing implications. Direct injection petrol engines feature a markedly different fuelling strategy, and so their emissions behaviour is somewhat different from indirect injection petrol engines. The excess emissions of direct injection engines at low ambient temperatures should also differ. Additionally, the direct injection fuel delivery process leads to the formation of PM, and DISI engines should show greater PM emissions at low ambient temperatures. This study reports on laboratory experiments quantifying excess emissions of gaseous and solid pollutants over a legislative driving cycle following cold start at a low ambient temperature for both engine types. Over the legislative cycle for testing at -7°C (the UDC, emissions of HC, CO, NOx and CO2 were higher when tested at -7°C than at 24°C. Massive increases in emissions of HC and CO were observed, together with more modest increases in NOx and CO2 emissions. Results from the entire driving cycle showed excess emissions in both phases (though they were much larger for the UDC. The DISI vehicle showed lower increases in fuel consumption than the port injected vehicles, but greater increases in emission of HC and CO. DISI particle number emissions increased by around 50%; DISI particle mass by over 600%. The observed emissions deteriorations varied somewhat by engine type and from vehicle to vehicle. Excesses were greatest following start-up, but persisted, even after several hundred seconds’ driving. The temperature of the intake air appeared to have a limited but significant effect on emissions after the engine has been running for some time. All vehicles tested here comfortably met the relevant EU limits, providing further evidence that these limits are no longer challenging and need updating.

  20. Experimental and numerical analysis of spray-atomization characteristics of biodiesel fuel in various fuel and ambient temperatures conditions

    International Nuclear Information System (INIS)

    The purpose of this work is to reveal the effects of fuel temperatures and ambient gas conditions on the spray-atomization behavior of soybean oil methyl ester (SME) fuel. The spray-atomization behavior was analyzed through spray parameters such as the axial distance from the nozzle tip, local and overall Sauter mean diameter (SMD). These parameters were obtained from a spray visualization system and a droplet measuring system. In addition, the experimental results were compared with the numerical results calculated by the KIVA-3V code. It was revealed that the increase of the fuel temperature (from 300 K to 360 K) little affects the spray liquid tip penetration. The increase of the ambient gas temperature (from 300 K to 450 K) caused a increase in the spray liquid tip penetration. Also, biodiesel fuel evaporation actively occurred due to the increase in the fuel temperature and the ambient gas temperature. Of special significance was that the highest vapor fuel mass concentration was observed at the center region of the spray axis. In the results of the microscopic characteristics, the detected local droplet size at the axial direction and overall droplet size at the axial and radial direction in a control volume increased when the fuel temperature increased. This is believed to be due to an increase in the number of small droplets that quickly evaporated. In addition, the increased fuel temperature caused the decrease of the number of droplets and the increase of the vapor fuel mass. The mean axial velocity of droplets decreased with increasing fuel temperature.

  1. Ambient Air Temperature Does Not Predict whether Small or Large Workers Forage in Bumble Bees (Bombus impatiens

    Directory of Open Access Journals (Sweden)

    Margaret J. Couvillon

    2010-01-01

    Full Text Available Bumble bees are important pollinators of crops and other plants. However, many aspects of their basic biology remain relatively unexplored. For example, one important and unusual natural history feature in bumble bees is the massive size variation seen between workers of the same nest. This size polymorphism may be an adaptation for division of labor, colony economics, or be nonadaptive. It was also suggested that perhaps this variation allows for niche specialization in workers foraging at different temperatures: larger bees might be better suited to forage at cooler temperatures and smaller bees might be better suited to forage at warmer temperatures. This we tested here using a large, enclosed growth chamber, where we were able to regulate the ambient temperature. We found no significant effect of ambient or nest temperature on the average size of bees flying to and foraging from a suspended feeder. Instead, bees of all sizes successfully flew and foraged between 16∘C and 36∘C. Thus, large bees foraged even at very hot temperatures, which we thought might cause overheating. Size variation therefore could not be explained in terms of niche specialization for foragers at different temperatures.

  2. Synthesis and Microdiffraction at Extreme Pressures and Temperatures

    OpenAIRE

    Lavina, Barbara; Dera, Przemyslaw; Meng, Yue

    2013-01-01

    High pressure compounds and polymorphs are investigated for a broad range of purposes such as determine structures and processes of deep planetary interiors, design materials with novel properties, understand the mechanical behavior of materials exposed to very high stresses as in explosions or impacts. Synthesis and structural analysis of materials at extreme conditions of pressure and temperature entails remarkable technical challenges. In the laser heated diamond anvil cell (LH-DAC), very ...

  3. Qualidade interna do ovo de avestruz após estocagem em temperatura ambiente e refrigerada Internal quality of ostrich eggs after storage in ambient temperature and in cooling condition storage

    Directory of Open Access Journals (Sweden)

    Andréa Kammers Pleti

    2009-09-01

    Full Text Available O objetivo deste trabalho foi avaliar as alterações da qualidade interna de três tipos de ovos de avestruzes: frescos, armazenados sob temperatura ambiente (25°C e sob temperatura de refrigeração (5°C, durante três, sete, 14, 21 e 28 dias de armazenamento. Houve queda significativa na Unidade Haugh, aumento do pH e diminuição da viscosidade em relação ao tempo de armazenamento. Os ovos mantidos em temperatura ambiente apresentaram maiores alterações do que os ovos armazenados sob refrigeração. Houve uma crescente perda de peso durante os dias de armazenamento, tanto sob temperatura ambiente, quanto em temperatura refrigerada, porém a perda de peso foi mais evidente na temperatura ambiente.The objective of this research was to evaluate the inside changes quality of fresh ostrich eggs and eggs stored in ambient temperature (25°C and in cooling condition storage (5°C, during 3, 7, 14, 21 and 28 days after storage. There was a considerable slump at Unity Haugh, pH increasing and viscosity decreasing related to time storage. Eggs stored in ambienttemperature showed more alterations than the ones stored under refrigeration. There was an increasing loss of weight during the days of storage in ambient temperature and in cooling condition storage, although the loss of weight was more notable in the ambient temperature.

  4. Synthesis of Nanoscale Tips Using Femtosecond Laser Radiation under Ambient Condition

    OpenAIRE

    Venkatakrishnan K; Sivakumar M; Tan B

    2009-01-01

    Abstract We report a unique growth of platelet-shaped nanoscale tips of transparent dielectric using femtosecond laser radiation at MHz pulse repetition rate with nitrogen background gas flow under ambient condition. The tips grew with sharp nanoscale apex while their base and lengths are of the order of few hundred nanometers. In the absence of nitrogen, the irradiation leads to nanofibrous structure formation. The collision between the nitrogen gas atoms and the vapor species slows down plu...

  5. Brachial Artery Responses to Ambient Pollution, Temperature, and Humidity in People with Type 2 Diabetes: A Repeated-Measures Study

    OpenAIRE

    Zanobetti, Antonella; Luttmann-Gibson, Heike; Horton, Edward S.; Cohen, Allison; Coull, Brent A.; Hoffmann, Barbara; Schwartz, Joel D; Mittleman, Murray A.; Li, Yongsheng; Stone, Peter H.; de Souza, Celine; Lamparello, Brooke; Koutrakis, Petros; Gold, Diane R.

    2014-01-01

    Background: Extreme weather and air pollution are associated with increased cardiovascular risk in people with diabetes. Objectives: In a population with diabetes, we conducted a novel assessment of vascular brachial artery responses both to ambient pollution and to weather (temperature and water vapor pressure, a measure of humidity). Methods: Sixty-four 49- to 85-year-old Boston residents with type 2 diabetes completed up to five study visits (279 repeated measures). Brachial artery diamete...

  6. The effect of nitriding on the fretting wear of a high strength steel at ambient and elevated temperatures

    OpenAIRE

    Pearson, Stephen R.

    2013-01-01

    This work is an experimental evaluation of the wear and friction of a high strength alloy steel (super-CMV (SCMV» in its as heat treated and plasma nitrided states under fretting conditions in air, at both ambient and elevated temperatures. In order to conduct the experimental programme, a new test rig and associated data processing and assessment capability was developed. Wearing couples in homogeneous and heterogeneous arrangements were tested to assess the effectiveness of the nitridi...

  7. Energy from Biomass - Comparision of biogas production at ambient temperature and at mesophilic temperature in semicontenous anaerobic digester using vegetable market waste

    Directory of Open Access Journals (Sweden)

    Dhanalakshmi Sridevi V.

    2014-03-01

    Full Text Available Studies are conducted in semicontinuous anaerobic reactors of 2 L Capacity with effective volume of 1.5 L. Experiments were carried out in the mesophilic temperature range maintained at 35°C in a thermostat, and parallel experiments were performed at ambient temperature on biogas production from the month of Februray to August. The reactors were operated with an organic loading rate of 0.5 gVS/L/d with 25 days HRT. The feed stock used for the study was vegetable market waste obtained from Koyambedu vegetable market. The specific biogas production was found to be 0.530 L gVS add-1 for the reactor operated at mesophilic temperature and in the range of 0.431 to 0.732 L gVSadd -1 for the reactor operated in the ambient temperature condition from the month of February to August. The daily biogas production was found to be similar (approximately 350 mL/d when reactors were operated at mesophilic and ambient temperature except for the period of May and June wherein higher amount of daily biogas production (472 and 529 mL/d was observed in the reactor operated at ambient temperature. The ratio of total VFA and alkalinity and propionic acid to acetic acid (PA/AA was found to be in the range of 0.25 – 0.4 and 0.34 - 1.38 during the operation of the reactor for the entire period, which was within the range reported for digester stability.

  8. Sow and litter response to supplemental dietary fat in lactation diets during high ambient temperatures.

    Science.gov (United States)

    Rosero, D S; van Heugten, E; Odle, J; Cabrera, R; Arellano, C; Boyd, R D

    2012-02-01

    The objective of this experiment was to determine the impact of supplemental dietary fat on total lactation energy intake and sow and litter performance during high ambient temperatures (27 ± 3°C). Data were collected from 337 mixed-parity sows from July to September in a 2,600-sow commercial unit in Oklahoma. Diets were corn-soybean meal-based with 7.5% corn distillers dried grains with solubles and 6.0% wheat middlings and contained 3.24 g of standardized ileal digestible Lys/Mcal of ME. Animal-vegetable fat blend (A-V) was supplemented at 0, 2, 4, or 6%. Sows were balanced by parity, with 113, 109, and 115 sows representing parity 1, 2, and 3 to 7 (P3+), respectively. Feed disappearance (subset of 190 sows; 4.08, 4.18, 4.44, and 4.34 kg/d, for 0, 2, 4, and 6%, respectively; P feed (sow and litter BW gain relative to feed intake) was not affected (P = 0.56), but gain:Mcal ME declined linearly with the addition of A-V (0.16, 0.15, 0.15, and 0.14 for 0, 2, 4, and 6%, respectively; P sows (3.95 kg/d) had less (P feed disappearance than P2 (4.48 kg/d) and P3+ (4.34 kg/d) sows. Body weight change in P1 sows was greater (P sows (-0.32 vs. -0.07 and 0.12 kg/d), whereas backfat loss was less (P sows compared with P1 and P2 sows. Dietary A-V improved litter ADG (P sows. Sows bred within 8 d after weaning (58.3, 72.0, 70.2, and 74.7% for 0, 2, 4, and 6%, respectively); conception rate (78.5, 89.5, 89.2, and 85.7%) and farrowing rate (71.4, 81.4, 85.5, and 78.6%) were improved (P sows were greater (P sows had lower (P sows, and respiration rate was reduced (P sows compared with P2 and P3+ sows. In conclusion, A-V improved feed disappearance and caloric intake, resulting in improved litter weight gain and subsequent reproductive performance of sows; however, feed and caloric efficiency were negatively affected.

  9. Effect of different arbuscular mycorrhizal fungi on growth and physiology of maize at ambient and low temperature regimes

    DEFF Research Database (Denmark)

    Chen, Xiaoying; Song, Fengbin; Liu, Fulai;

    2014-01-01

    The effect of four different arbuscular mycorrhizal fungi (AMF) on the growth and lipid peroxidation, soluble sugar, proline contents, and antioxidant enzymes activities of Zea mays L. was studied in pot culture subjected to two temperature regimes. Maize plants were grown in pots filled...... with a mixture of sandy and black soil for 5 weeks, and then half of the plants were exposed to low temperature for 1 week while the rest of the plants were grown under ambient temperature and severed as control. Different AMF resulted in different root colonization and low temperature significantly decreased AM...... colonization. Low temperature remarkably decreased plant height and total dry weight but increased root dry weight and root-shoot ratio. The AM plants had higher proline content compared with the non-AM plants. The maize plants inoculated with Glomus etunicatum and G. intraradices had higher malondialdehyde...

  10. Testing an e2v CCD230-42 sensor for dark current performance at ambient temperatures - Final Paper

    Energy Technology Data Exchange (ETDEWEB)

    Dungee, Ryan [SLAC National Accelerator Lab., Menlo Park, CA (United States)

    2015-08-20

    The design of the Guidance Focus and Alignment (GFA) system for the Dark Energy Spectroscopic Instrument (DESI) project calls for a set of charge-coupled devices (CCDs) which operate at ambient temperature. Here we assess the performance of these CCDs under such conditions. Data was collected from –21°C to 28°C and used to determine the effect of temperature on the effectiveness of dark current subtraction. Comparing the dark current uncertainty to our expected signal has shown that the DESI design specifications will be met without need for significant changes.

  11. Effect of ambient temperature and sodium bicarbonate supplementation on water and electrolyte balances in dry and lactating Holstein cows

    OpenAIRE

    Khelil-Arfa, Hajer; Faverdin, Philippe; Boudon, Anne

    2014-01-01

    The aim of this study was to quantify the effect of the interaction between 2 constant ambient temperatures [thermoneutrality (TN; 15°C) and high temperature (HT; 28°C)] and 2 levels of Na bicarbonate supplementation [calculated to provide diet Na contents of 0.20% DM (Na(-)) and 0.50% DM (Na(+))] on water partitioning in dairy cows. Treatments were compared on 4 dry and 4 mid-lactation Holstein cows according to 2 Latin squares (1 for each physiological stage) over the course of 4 periods of...

  12. Scanning Electron Microscopic Study of Rockfish Preserved at Either Ambient Temperature or by Isothermal Freeze-Fixation

    OpenAIRE

    Lampila, L. E.; Mohr, V.; Reid, D. S.

    1985-01-01

    Fresh rockfish (Bocaccio, Sebastus paucispinis) fillets were blast frozen and stored at either -5 °C or -20 °C for 60 days . At defined sampling intervals, speci mens were removed and chemically fixed at either ambient temperature or isothermally, at the respective storage temperatures (-5 °C or -20°C) . The results indicated that isothermally freeze - fixed specimens showed a degree of crushing and/or distortion of the muscle fiber, the deposition of presumed ice crystals in the cell membran...

  13. Imaging structured water and bound polysaccharide on mica surface at ambient temperature

    NARCIS (Netherlands)

    Spagnoli, Chiara; Loos, Katja; Ulman, Abraham; Cowman, Mary K.

    2003-01-01

    The presence of a water layer on the surface of muscovite mica under ambient conditions is well established. The water molecules are well ordered and seem to be oriented, leading to an icelike monolayer (probably ferroelectric) in epitaxial relation with the mica surface. We have imaged and characte

  14. Design of a new reactor-like high temperature near ambient pressure scanning tunneling microscope for catalysis studies.

    Science.gov (United States)

    Tao, Franklin Feng; Nguyen, Luan; Zhang, Shiran

    2013-03-01

    Here, we present the design of a new reactor-like high-temperature near ambient pressure scanning tunneling microscope (HT-NAP-STM) for catalysis studies. This HT-NAP-STM was designed for exploration of structures of catalyst surfaces at atomic scale during catalysis or under reaction conditions. In this HT-NAP-STM, the minimized reactor with a volume of reactant gases of ∼10 ml is thermally isolated from the STM room through a shielding dome installed between the reactor and STM room. An aperture on the dome was made to allow tip to approach to or retract from a catalyst surface in the reactor. This dome minimizes thermal diffusion from hot gas of the reactor to the STM room and thus remains STM head at a constant temperature near to room temperature, allowing observation of surface structures at atomic scale under reaction conditions or during catalysis with minimized thermal drift. The integrated quadrupole mass spectrometer can simultaneously measure products during visualization of surface structure of a catalyst. This synergy allows building an intrinsic correlation between surface structure and its catalytic performance. This correlation offers important insights for understanding of catalysis. Tests were done on graphite in ambient environment, Pt(111) in CO, graphene on Ru(0001) in UHV at high temperature and gaseous environment at high temperature. Atom-resolved surface structure of graphene on Ru(0001) at 500 K in a gaseous environment of 25 Torr was identified. PMID:23556828

  15. Ambient temperature effect on changes in heat exchange and skin and coat thermoisolation induced with nembutal in guinea pigs.

    Science.gov (United States)

    Laszczyńska, J

    1983-01-01

    The experiment was carried out on adult male guinea pigs not adapted to cold at temperatures of 29 degrees, 20 degrees and 12 degrees C. During 150 minutes after nembutal injection the following values were recorded: oxygen consumption, subcutaneous, cutaneous and hair-coat temperatures. Using Hatfield's disc heat loss from the body surface by radiation and convection was measured. Nembutal not only inhibited thermogenetic processes at low ambient temperature, but decreased also heat production in a thermoneutral environment. This effect increased with decreasing ambient temperature. At the same time, there was a reduction in heat loss, although in a lower degree. The final result was a fall of the rectal temperature (even by 10 degrees C in a cold environment). Following nembutal administration skin thermoinsulation decreased slightly but the thermoinsulating activity of the hair-coat increased (the pilomotor response was more pronounced than in waking animals). Thermoregulation disturbances induced by nembutal included mainly thermogenesis impairment. The effect of general anaesthesia on heat loss was without any greater importance for maintenance of thermic homeostasis of the organism. PMID:6675430

  16. Temperature Dependence on The Synthesis of Jatropha Biolubricant

    Science.gov (United States)

    Gunam Resul, Muhammad Faiz M.; Idaty Mohd Ghazi, Tinia; Idris, Azni

    2011-02-01

    Jatropha oil has good potential as the renewable energy as well as lubricant feedstock. The synthesis of jatropha biolubricant was performed by transesterification of jatropha methyl ester (JME) with trimethyl-ol-propane (TMP) with sodium methoxide (NaOCH3) catalyst. The effects of temperature on the synthesis were studied at a range between 120°C and 200°C with pressure kept at 10mbar. The conversion of JME to jatropha biolubricant was found to be the highest (47%) at 200°C. However, it was suggested that the optimum temperature of the reaction is at 150°C due to insignificant improvement in biolubricant production. To maintain forward reaction, the excess amount of JME was maintained at 3.9:1 ratios to TMP. Kinetic study was done and compared. The synthesis was found to follow a second order reaction with overall rate constant of 1.49 × 10-1 (%wt/wt.min.°C)-1. The estimated activation energy was 3.94 kJ/mol. Pour point for jatropha biolubricant was at -3°C and Viscosity Index (VI) ranged from 178 to 183. The basic properties of jatropha biolubricant, pour point and viscosities are found comparable to other plant based biolubricant, namely palm oil and soybean based biolubricant.

  17. Temperature Dependence on The Synthesis of Jatropha Biolubricant

    Energy Technology Data Exchange (ETDEWEB)

    Resul, Muhammad Faiz M Gunam; Ghazi, Tinia Idaty Mohd; Idris, Azni, E-mail: tinia@eng.upm.edu.my [Department of Chemical and Environmental Engineering, Faculty of Engineering, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor (Malaysia)

    2011-02-15

    Jatropha oil has good potential as the renewable energy as well as lubricant feedstock. The synthesis of jatropha biolubricant was performed by transesterification of jatropha methyl ester (JME) with trimethyl-ol-propane (TMP) with sodium methoxide (NaOCH3) catalyst. The effects of temperature on the synthesis were studied at a range between 120 deg. C and 200 deg. C with pressure kept at 10mbar. The conversion of JME to jatropha biolubricant was found to be the highest (47%) at 200 deg. C. However, it was suggested that the optimum temperature of the reaction is at 150 deg. C due to insignificant improvement in biolubricant production. To maintain forward reaction, the excess amount of JME was maintained at 3.9:1 ratios to TMP. Kinetic study was done and compared. The synthesis was found to follow a second order reaction with overall rate constant of 1.49 x 10-1 (%wt/wt.min.deg. C)-1. The estimated activation energy was 3.94 kJ/mol. Pour point for jatropha biolubricant was at -3 deg. C and Viscosity Index (VI) ranged from 178 to 183. The basic properties of jatropha biolubricant, pour point and viscosities are found comparable to other plant based biolubricant, namely palm oil and soybean based biolubricant.

  18. Experimental investigation on heating performance of heat pump for electric vehicles at −20 °C ambient temperature

    International Nuclear Information System (INIS)

    Highlights: • An ASHP system with refrigerant injection for EVs is designed, for cold regions. • The heat performances of the system are tested at −20 °C ambient temperature. • The system cycle process with refrigerant injection are analyzed on lgP-H diagrams. • The effects of refrigerant injection, dryness, and in-car inlet state are discussed. • The new system can improve heating and own better application prospect. - Abstract: Since the performance of conventional air source heat pump (ASHP) for electric vehicles (EVs) is apt to decline sharply in low ambient temperature, it will consume more electricity of the cell, and affect driving mileage in cold regions. Aiming at developing high efficiency heating system for EVs in cold regions, an ASHP system applying refrigerant injection for EVs is designed, as well as the test bench is built to investigate its performance. According to the operation condition of EVs, heating performances are tested on different in-car inlet air temperature and various fresh air ratios under −20 °C ambient temperature. The system cycle process with refrigerant injection, as well as the influences of refrigerant injection and dryness are also analyzed and discussed. The results show that the heating capacity of the ASHP with refrigerant injection can be increased up to 31%, and in comparison with the conventional heat pump system its heating performance is better when in-car inlet temperature is above −10 °C. Therefore, ASHP with refrigerant injection has great potentiality to be applied for the EVs in cold regions

  19. Ambient temperature effects on photo induced gonadal cycles and hormonal secretion patterns in Great Tits from three different breeding latitudes.

    Science.gov (United States)

    Silverin, Bengt; Wingfield, John; Stokkan, Karl-Arne; Massa, Renato; Järvinen, Antero; Andersson, Nils-Ake; Lambrechts, Marcel; Sorace, Alberto; Blomqvist, Donald

    2008-06-01

    The present study determines how populations of Great Tits (Parus major) breeding in southern, mid and northern European latitudes have adjusted their reproductive endocrinology to differences in the ambient temperature during the gonadal cycle. A study based on long-term breeding data, using the Colwell predictability model, showed that the start of the breeding season has a high predictability ( approximately 0.8-0.9) at all latitudes, and that the environmental information factor (I(e)) progressively decreased from mid Italy (I(e)>4) to northern Finland (I(e)breeding season with decreasing latitude. This hypothesis was verified by exposing photosensitive Great Tits from northern Norway, southern Sweden and northern Italy to sub-maximal photo-stimulatory day lengths (13L:11D) under two different ambient temperature regimes (+4 degrees C and +20 degrees C). Changes in testicular size, plasma levels of LH and testosterone were measured. The main results were: (1) Initial testicular growth rate, as well as LH secretion, was affected by temperature in the Italian, but not in birds from the two Scandinavian populations. (2) Maximum testicular size, maximum LH and testosterone levels were maintained for a progressively shorter period of time with increasing latitude, regardless of whether the birds were kept on a low or a high ambient temperature. (3) In birds from all latitudes, the development of photorefractoriness, as indicated by testicular regression and a decrease in plasma levels of LH and testosterone, started much earlier (with the exception for LH Great Tits from northern Scandinavia) when kept on +20 degrees C than when kept on +4 degrees C. The prolonging effects of a low temperature was more pronounced in Mediterranean birds, than in birds from Scandinavia, and more pronounced in Great Tits from southern Scandinavia than in Great Tits from northern Scandinavia. Ecological implications of the results are discussed, as well as possible impact of global

  20. Biodegradation of Synthetic Polyesters (BTA and PCL with Natural Flora in Soil Burial and Pure Cultures under Ambient Temperature

    Directory of Open Access Journals (Sweden)

    Mona K. Gouda

    2012-03-01

    Full Text Available The aim of this study was to study the biodegradation of two synthetic polyesters, one aliphaticaromatic (1, 4-butanediol, terephthalic-adipic acid, BTA and the other aliphatic (poly (,-caprolactone, PCL, under different soil types (canal shore soil, garden soil, compost and Peat moss, respectively, as well as using locally isolated cultures at ambient temperature. The results showed that the BTA films buried in canal shore and garden soil were degraded faster than that in the other soils. After six weeks about 90, 88 and 80% were degraded in garden, canal shore soil and compost respectively, while only 52% were degraded in Peat moss. On the other hand, 95 and 93% weight loss was obtained for PCL films buried for three weeks in canal shore and garden soil respectively. The Scanning Electron Microscope photos confirm the results of weight loss and revealed the presence of cracks and fungal growth on films buried in different soils. The results with pure cultures, especially with Fusarium solani, also confirmed the biodegradability of two polyesters under ambient temperature. Finally, it could be concluded that both synthetic polyester are degradable under ambient conditions.

  1. Ambient temperature and outpatient visits for acute exacerbation of chronic bronchitis in Shanghai: a time series analysis.

    Science.gov (United States)

    Huang, Fang; Zhao, Ang; Chen, Ren Jie; Kan, Hai Dong; Kuang, Xing Ya

    2015-01-01

    The association between ambient temperature and acute exacerbation of chronic bronchitis (AECB) was still unknown. Therefore, we performed an epidemiological study in a large hospital of Shanghai to explore the relationship about temperature and outpatient visit for AECB. We adopted a quasi-Poisson generalized additive models and distributed lag nonlinear models to estimate the accumulative effects of temperature on AECB across multiple days. We found significant non-linear effects of cold temperature on hospital visits for AECB, and the potential effect of cold temperature might last more than 2 weeks. The relative risks of extreme cold (first percentiles of temperature throughout the study period) and cold (10th percentile of temperature) temperature over lags 0-14 d were 2.98 [95% confidence intervals (CI): 1.77, 5.04] and 1.63 (95% CI: 1.21, 2.19), compared with the 25th percentile of temperature. However, we found no positive association between hospital visits and hot weather. This study showed that exposure to both extreme cold and cold temperatures were associated with increased outpatient visits for AECB in a large hospital of Shanghai. PMID:25566865

  2. Splashing phenomena of room temperature liquid metal droplet striking on the pool of the same liquid under ambient air environment

    CERN Document Server

    Li, Haiyan; Wang, Lei; Gao, Yunxia; Liu, Jing

    2013-01-01

    In this article, the fluid dynamics of room temperature liquid metal (RTLM) droplet impacting onto a pool of the same liquid in ambient air was investigated. A series of experiments were conducted in order to disclose the influence of the oxidation effect on the impact dynamics. The droplet shape and impact phenomenology were recorded with the aid of a high-speed digital camera. The impact energy stored in the splash structures was estimated via a theoretical model and several morphological parameters obtained from instantaneous images of the splash. It was observed that the droplet shape and the splashing morphology of RTLM were drastically different from those of water, so was the impact dynamics between room temperature LM pool and high temperature LM pool. The energy analysis disclosed that the height of the jet is highly sensitive to the viscosity of the fluid, which is subjected to the oxidation effect and temperature effect simultaneously, and thus perfectly explained the phenomena. These basic finding...

  3. Responses of wheat and rice to factorial combinations of ambient and elevated CO2 and temperature in FACE experiments.

    Science.gov (United States)

    Cai, Chuang; Yin, Xinyou; He, Shuaiqi; Jiang, Wenyu; Si, Chuanfei; Struik, Paul C; Luo, Weihong; Li, Gang; Xie, Yingtian; Xiong, Yan; Pan, Genxing

    2016-02-01

    Elevated CO2 and temperature strongly affect crop production, but understanding of the crop response to combined CO2 and temperature increases under field conditions is still limited while data are scarce. We grew wheat (Triticum aestivum L.) and rice (Oryza sativa L.) under two levels of CO2 (ambient and enriched up to 500 μmol mol(-1) ) and two levels of canopy temperature (ambient and increased by 1.5-2.0 °C) in free-air CO2 enrichment (FACE) systems and carried out a detailed growth and yield component analysis during two growing seasons for both crops. An increase in CO2 resulted in higher grain yield, whereas an increase in temperature reduced grain yield, in both crops. An increase in CO2 was unable to compensate for the negative impact of an increase in temperature on biomass and yield of wheat and rice. Yields of wheat and rice were decreased by 10-12% and 17-35%, respectively, under the combination of elevated CO2 and temperature. The number of filled grains per unit area was the most important yield component accounting for the effects of elevated CO2 and temperature in wheat and rice. Our data showed complex treatment effects on the interplay between preheading duration, nitrogen uptake, tillering, leaf area index, and radiation-use efficiency, and thus on yield components and yield. Nitrogen uptake before heading was crucial in minimizing yield loss due to climate change in both crops. For rice, however, a breeding strategy to increase grain number per m(2) and % filled grains (or to reduce spikelet sterility) at high temperature is also required to prevent yield reduction under conditions of global change.

  4. Secondary limonene endo-ozonide: A major product from gas-phase ozonolysis of R-( +)-limonene at ambient temperature

    Science.gov (United States)

    Nørgaard, A. W.; Nøjgaard, J. K.; Larsen, K.; Sporring, S.; Wilkins, C. K.; Clausen, P. A.; Wolkoff, P.

    A 16 s old gas-phase ambient temperature and 1% relative humidity reaction mixture of ozone and R-limonene (ca. 1:10) was sampled on XAD-2 resin followed by pressurized liquid extraction with dichloromethane at ambient temperature. Low temperature on-column injection and gas chromatography (GC) revealed equal amounts of diastereomeric secondary endo-limonene ozonides, in addition to 4-acetyl-1-methyl-cyclohexene (AMCH), 3-isopropyl-6-oxo-heptanal (IPOH), and endo-limonene mono-epoxides. The secondary endo-limonene ozonides began to decrease at extraction temperature above 150C and were absent at 200C. Their formation was unaffected by an increase of the relative humidity to 15%. The identification of the secondary limonene ozonides was confirmed by (1) unique consecutive losses of OH and H2O2, respectively, from the protonated quasi-molecular ion in GC-chemical ionization mass spectrometry mode (isobutane), in addition to high resolution mass determination of [M-OH] and [M- H2O2] ions in EI mode; (2) comparison of mass spectral data to that of synthesized secondary endo-limonene ozonides; and (3) oxidation of dimethyl sulfide to dimethyl sulfoxide and subsequent increase of IPOH.

  5. Effect of different arbuscular mycorrhizal fungi on growth and physiology of maize at ambient and low temperature regimes.

    Science.gov (United States)

    Chen, Xiaoying; Song, Fengbin; Liu, Fulai; Tian, Chunjie; Liu, Shengqun; Xu, Hongwen; Zhu, Xiancan

    2014-01-01

    The effect of four different arbuscular mycorrhizal fungi (AMF) on the growth and lipid peroxidation, soluble sugar, proline contents, and antioxidant enzymes activities of Zea mays L. was studied in pot culture subjected to two temperature regimes. Maize plants were grown in pots filled with a mixture of sandy and black soil for 5 weeks, and then half of the plants were exposed to low temperature for 1 week while the rest of the plants were grown under ambient temperature and severed as control. Different AMF resulted in different root colonization and low temperature significantly decreased AM colonization. Low temperature remarkably decreased plant height and total dry weight but increased root dry weight and root-shoot ratio. The AM plants had higher proline content compared with the non-AM plants. The maize plants inoculated with Glomus etunicatum and G. intraradices had higher malondialdehyde and soluble sugar contents under low temperature condition. The activities of catalase (CAT) and peroxidase of AM inoculated maize were higher than those of non-AM ones. Low temperature noticeably decreased the activities of CAT. The results suggest that low temperature adversely affects maize physiology and AM symbiosis can improve maize seedlings tolerance to low temperature stress.

  6. Effect of Different Arbuscular Mycorrhizal Fungi on Growth and Physiology of Maize at Ambient and Low Temperature Regimes

    Directory of Open Access Journals (Sweden)

    Xiaoying Chen

    2014-01-01

    Full Text Available The effect of four different arbuscular mycorrhizal fungi (AMF on the growth and lipid peroxidation, soluble sugar, proline contents, and antioxidant enzymes activities of Zea mays L. was studied in pot culture subjected to two temperature regimes. Maize plants were grown in pots filled with a mixture of sandy and black soil for 5 weeks, and then half of the plants were exposed to low temperature for 1 week while the rest of the plants were grown under ambient temperature and severed as control. Different AMF resulted in different root colonization and low temperature significantly decreased AM colonization. Low temperature remarkably decreased plant height and total dry weight but increased root dry weight and root-shoot ratio. The AM plants had higher proline content compared with the non-AM plants. The maize plants inoculated with Glomus etunicatum and G. intraradices had higher malondialdehyde and soluble sugar contents under low temperature condition. The activities of catalase (CAT and peroxidase of AM inoculated maize were higher than those of non-AM ones. Low temperature noticeably decreased the activities of CAT. The results suggest that low temperature adversely affects maize physiology and AM symbiosis can improve maize seedlings tolerance to low temperature stress.

  7. Low-Temperature Synthesis Routes to Intermetallic Superconductors

    Energy Technology Data Exchange (ETDEWEB)

    Schaak, Raymond E

    2008-01-08

    Over the past few years, our group has gained expertise at developing low-temperature solution-based synthetic pathways to complex nanoscale solids, with particular emphasis on nanocrystalline intermetallic compounds. Our synthetic capabilities are providing tools to reproducibly generate intermetallic nanostructures with simultaneous control over crystal structure, composition, and morphology. This DOE-funded project aims to expand these capabilities to intermetallic superconductors. This could represent an important addition to the tools that are available for the synthesis and processing of intermetallic superconductors, which traditionally utilize high-temperature, high-pressure, thin film, or gas-phase vacuum deposition methods. Our current knowledge of intermetallic superconductors suggests that significant enhancements could result from the inherent benefits of low-temperature solution synthesis, e.g. metastable phase formation, control over nanoscale morphology to facilitate size-dependent property studies, robust and inexpensive processability, low-temperature annealing and consolidation, and impurity incorporation (for doping, stoichiometry control, flux pinning, and improving the critical fields). Our focus is on understanding the superconducting properties as a function of synthetic route, crystal structure, crystallite size, and morphology, and developing the synthetic tools necessary to accomplish this. This research program can currently be divided into two classes of superconducting materials: intermetallics (transition metal/post transition metal) and metal carbides/borides. Both involve the development and exploitation of low-temperature synthesis routes followed by detailed characterization of structures and properties, with the goal of understanding how the synthetic pathways influence key superconducting properties of selected target materials. Because of the low-temperature methods used to synthesize them and the nanocrystalline morphologies

  8. Studies on synthesis of diamond at high pressure and temperature

    Science.gov (United States)

    Kailath, Ansu J.

    Diamond is an essential material of modern industry and probably the most versatile abrasive available today. It also has many other industrial applications attributable to its unique mechanical, optical, thermal and electrical properties. Its usage has grown to the extent that there is hardly a production process in modern industry in which industrial diamond does not play a part. Bulk diamond production today is a major industry. Diamonds can be produced in its thermodynamically stable regions either by direct static conversion, or shock-wave conversion. The pressures and temperatures required for direct static conversion are very high. In the catalyst-solvent method, the material used establishes a reaction path with lower activation energy than for direct transformation. This helps in a quicker transformation under more benign conditions. Hence, catalyst-solvent synthesis is readily accomplished and is now a viable and successful industrial process. Diamonds produced by shock wave are very small (approximately 60mu). Therefore this diamond is limited to applications such as polishing compounds only. The quality, quantity, size and morphology of the crystals synthesized by catalyst-solvent process depend on different conditions employed for synthesis. These details, because of commercial reasons are not disclosed in published literature. Hence, systematic studies have been planned to investigate the effect of various growth parameters on the synthesized crystals. During the growth of synthetic diamond crystals, some catalyst-solvent is retained into the crystals in some form and behaves like an impurity. Several physico-mechanical properties of the crystals are found to depend on the total quantity and distribution of these inclusions. Thus, detailed investigation of the crystallization medium and inclusions in synthesized diamonds was also undertaken in the present work. The work incorporated in this thesis has been divided into seven chapters. The first

  9. Ambient temperature enhanced acute cardiovascular-respiratory mortality effects of PM2.5 in Beijing, China

    Science.gov (United States)

    Li, Yi; Ma, Zhiqiang; Zheng, Canjun; Shang, Yu

    2015-12-01

    Studies have shown that temperature could modify the effect of ambient fine particles on mortality risk. In assessing air pollution effects, temperature is usually considered as a confounder. However, ambient temperature can alter people's physiological response to air pollution and might "modify" the impact of air pollution on health outcomes. This study investigated the interaction between daily PM2.5 and daily mean temperature in Beijing, China, using data for the period 2005-2009. Bivariate PM2.5-temperature response surfaces and temperature-stratified generalized additive model (GAM) were applied to study the effect of PM2.5 on cardiovascular, respiratory mortality, and total non-accidental mortality across different temperature levels. We found that low temperature could significantly enhance the effect of PM2.5 on cardiovascular mortality. For an increase of 10 μg/m3 in PM2.5 concentration in the lowest temperature range (-9.7˜2.6 °C), the relative risk (RR) of cardiovascular mortality increased 1.27 % (95 % CI 0.38˜2.17 %), which was higher than that of the whole temperature range (0.59 %, 95 % CI 0.22-1.16 %). The largest effect of PM2.5 on respiratory mortality appeared in the high temperature range. For an increase of 10 μg/m3 in PM2.5 concentration, RR of respiratory mortality increased 1.70 % (95 % CI 0.92˜3.33 %) in the highest level (23.50˜31.80 °C). For the total non-accidental mortality, significant associations appeared only in low temperature levels (-9.7˜2.6 °C): for an increase of 10 μg/m3 in current day PM2.5 concentration, RR increased 1.27 % (95 % CI 0.46˜2.00 %) in the lowest temperature level. No lag effect was observed. The results suggest that in air pollution mortality time series studies, the possibility of an interaction between air pollution and temperature should be considered.

  10. Solution-phase synthesis of nanomaterials at low temperature

    Institute of Scientific and Technical Information of China (English)

    ZHU YongChun; QIAN YiTai

    2009-01-01

    This paper reviews the solution-phase synthesis of nanoparticles via some routes at low temperatures, such as room temperature route, wave-assisted synthesis (γ-irradiation route and sonochemical route), directly heating at low temperatures, and hydrothermal/solvothermal methods. A number of strategies were developed to control the shape, the size, as well as the dispersion of nanostructures. Using di-ethylamine or n-butylamine as solvent, semiconductor nanorods were yielded. By the hydrothermal treatment of amorphous colloids, Bi2S3 nanorods and Se nanowires were obtained. CdS nanowires were prepared in the presence of polyacrylamide. ZnS nanowires were obtained using liquid crystal. The polymer poly (vinyl acetate) tubule acted as both nanoreactor and template for the CdSe nanowire growth. Assisted by the surfactant of sodium dodecyl benzenesulfonate (SDBS), nickel nanobelts were synthesized. In addition, Ag nanowires, Te nanotubes and ZnO nanorod arrays could be prepared without adding any additives or templates.

  11. Temperature lowering in cryogenic chemical-synthesis techniques and system

    International Nuclear Information System (INIS)

    When evaluating a chemical synthesis process for a reaction that occurs on the cryogenically cooled walls, it is sometimes necessary to reduce the wall temperatures to enhance the chemical process. To evaluate the chemical process at lower than atmospheric boiling of liquid nitrogen, we built a system and used it to reduce the temperature of the liquid nitrogen. The technique of lowering the liquid nitrogen temperature by reducing the pressure of the boil-off is established knowledge. This paper presents the engineering aspects of the system, design features, equipment requirements, methods of control, and results of the chemical synthesis. The heat input to the system was ∼400 watts, placing a relatively large demand on the pumping system. Our system is a scale-up of the small laboratory experiment, and it provides the information needed to design an effective system. The major problem encountered was the large quantity of liquid escaping the system during the processing, placing a large gas load on the vacuum system

  12. Synthesis of tungsten oxide nanoparticles using a hydrothermal method at ambient pressure

    DEFF Research Database (Denmark)

    Ahmadi, Majid; Younesi, Reza; Guinel, Maxime J-F

    2014-01-01

    ) nanoparticles were synthesized using a simple and inexpensive low temperature and low pressure hydrothermal (HT) method. The precursor solution used for the HT process was prepared by adding hydrochloric acid to diluted sodium tungstate solutions (Na2WO4 center dot 2H(2)O) at temperatures below 5 degrees C...

  13. Product engineering by high-temperature flame synthesis

    DEFF Research Database (Denmark)

    Johannessen, Tue; Johansen, Johnny; Mosleh, Majid;

    High-temperature flame processes can be applied as a tool for chemical product engineering. The general principle behind flame synthesis is the decomposition/oxidation of evaporated metal-precursors in a flame, thereby forming metal oxide monomers which nucleate, aggregate, and - to some extent...... hardware by direct deposition of catalysts on process equipment • Modifications of the substrate surfaces to obtain good adhesion during flame-coating • Formation of membrane layers by gas-phase deposition of nano-particles • Catalyst deposition in micro-reactors for rapid catalyst screening...

  14. Depicting the Dependency of Isoprene in Ambient Air and from Plants on Temperature and Solar Radiation by Using Regression Analysis

    Science.gov (United States)

    Saxena, Pallavi; Ghosh, Chirashree

    2016-07-01

    Among all sources of volatile organic compounds, isoprene emission from plants is an important part of the atmospheric hydrocarbon budget. In the present study, isoprene emission capacity at the bottom of the canopies of plant species viz. Dalbergia sissoo and Nerium oleander and in ambient air at different sites selected on the basis of land use pattern viz. near to traffic intersection with dense vegetation, away from traffic intersection with dense vegetation under floodplain area (Site I) and away from traffic intersection with dense vegetation under hilly ridge area (Site II) during three different seasons (monsoon, winter and summer) in Delhi were measured. In order to find out the dependence of isoprene emission rate on temperature and solar radiation, regression analysis has been performed. In case of dependency of isoprene in ambient air on temperature and solar radiation in selected seasons it has been found that high isoprene was found during summer season as compared to winter and monsoon seasons. Thus, positive linear relationship gives the best fit between temperature, solar rdaiation and isoprene during summer season as compared to winter and monsoon season. On the other hand, in case of isoprene emission from selected plant species, it has been found that high temperature and solar radiation promotes high isoprene emission rates during summer season as compared to winter and monsoon seasons in D. sissoo. Thus, positive linear relationship gives the best fit between temperature, solar radiation and isoprene emission rate during summer season as compared to winter and monsoon season. In contrast, in case of Nerium oleander, no such appropriate relationship was obtained. The study concludes that in ambient air, isoprene concentration was found to be high during summer season as compared to other seasons and gives best fit between temperature, solar radiation and isoprene. In case of plants, Dalbergia sissoo comes under high isoprene emission category

  15. Time series analysis of the association between ambient temperature and cerebrovascular morbidity in the elderly in Shanghai, China

    Science.gov (United States)

    Zhang, Xian-Jing; Ma, Wei-Ping; Zhao, Nai-Qing; Wang, Xi-Ling

    2016-01-01

    Research on the association between ambient temperature and cerebrovascular morbidity is scarce in China. In this study, we applied mixed generalized additive model (MGAM) to daily counts of cerebrovascular disease of Shanghai residents aged 65 years or older from 2007–2011, stratified by gender. Weighted daily mean temperature up to lags of one week was smoothed by natural cubic spline, and was added into the model to assess both linear and nonlinear effects of temperature. We found that when the mean temperature increased by 1 °C, the male cases of cerebrovascular disease reduced by 0.95% (95% Confidence Interval (CI): 0.80%, 1.10%) or reduced by 0.34% (95% CI: ‑0.68, 1.36%) in conditions of temperature was below or above 27 °C. However, for every 1 °C increase in temperature, the female cases of cerebrovascular disease increased by 0.34% (95% CI: ‑0.26%, 0.94%) or decreased by 0.92% (95% CI: 0.72, 1.11%) in conditions of temperature was below or above 8 °C, respectively. Temperature and cerebrovascular morbidity is negatively associated in Shanghai. MGAM is recommended in assessing the association between environmental hazards and health outcomes in time series studies.

  16. A complementary role for ELF3 and TFL1 in the regulation of flowering time by ambient temperature.

    Science.gov (United States)

    Strasser, Bárbara; Alvarez, Mariano J; Califano, Andrea; Cerdán, Pablo D

    2009-05-01

    Plants regulate their time to flowering by gathering information from the environment. Photoperiod and temperature are among the most important environmental variables. Sub-optimal, but not near-freezing, temperatures regulate flowering through the thermosensory pathway, which overlaps with the autonomous pathway. Here we show that ambient temperature regulates flowering by two genetically distinguishable pathways, one requiring TFL1 and another requiring ELF3. The delay in flowering time observed at lower temperatures was partially suppressed in single elf3 and tfl1 mutants, whereas double elf3 tfl1 mutants were insensitive to temperature. tfl1 mutations abolished the temperature response in cryptochrome mutants that are deficient in photoperiod perception, but not in phyB mutants, which have a constitutive photoperiodic response. In contrast to tfl1, elf3 mutations were able to suppress the temperature response in phyB mutants, but not in cryptochrome mutants. Gene expression profiles revealed that the tfl1 and elf3 effects are due to the activation of different sets of genes, and identified CCA1 and SOC1/AGL20 as being important cross-talk points. Finally, genome-wide gene expression analysis strongly suggests a general and complementary role for ELF3 and TFL1 in temperature signalling.

  17. Alternative Refrigerant Evaluation for High-Ambient-Temperature Environments: R-22 and R-410A Alternatives for Mini-Split Air Conditioners

    Energy Technology Data Exchange (ETDEWEB)

    Abdelaziz, Omar [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Shrestha, Som S. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Munk, Jeffrey D. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Linkous, Randall Lee [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Goetzler, William [Navigant Consulting Inc., Burlington, MA (United States); Guernsey, Matt [Navigant Consulting Inc., Burlington, MA (United States); Kassuga, Theo [Navigant Consulting Inc., Burlington, MA (United States)

    2015-10-01

    The Oak Ridge National Laboratory (ORNL) High-Ambient-Temperature Evaluation Program for low– global warming potential (Low-GWP) Refrigerants aims to develop an understanding of the performance of low-GWP alternative refrigerants to hydrochlorofluorocarbon (HCFC) and hydrofluorocarbon (HFC) refrigerants in mini-split air conditioners under high-ambient-temperature conditions. This final report describes the parties involved, the alternative refrigerant selection process, the test procedures, and the final results.

  18. Alternative Refrigerant Evaluation for High-Ambient Temperature Environments: R-22 and R-410A Alternatives for Mini-Split Air Conditioners

    Energy Technology Data Exchange (ETDEWEB)

    Abdelaziz, Omar [ORNL; Munk, Jeffrey D [ORNL; Shrestha, Som S [ORNL; Linkous, Randall Lee [ORNL; Goetzler, William [Navigant Consulting Inc.; Guernsey, Matt [Navigant Consulting Inc.; Kassuga, Theo [Navigant Consulting Inc.

    2015-08-01

    The Oak Ridge National Laboratory (ORNL) High-Ambient Temperature Testing Program for Low-GWP Refrigerants aims to develop an understanding of the performance of low-Global Warming Potential (low-GWP) alternatives to Hydrochlorofluorocarbon (HCFC) and Hydrofluorocarbon (HFC) refrigerants in mini-split air conditioners under high ambient temperature conditions. This interim working paper describes the parties involved, the alternative refrigerants selection process, the test procedures, and the preliminary results.

  19. Tailpipe emissions from gasoline direct injection (GDI) and port fuel injection (PFI) vehicles at both low and high ambient temperatures.

    Science.gov (United States)

    Zhu, Rencheng; Hu, Jingnan; Bao, Xiaofeng; He, Liqiang; Lai, Yitu; Zu, Lei; Li, Yufei; Su, Sheng

    2016-09-01

    Vehicle emissions are greatly influenced by various factors that are related to engine technology and driving conditions. Only the fuel injection method and ambient temperature are investigated in this research. Regulated gaseous and particulate matter (PM) emissions from two advanced gasoline-fueled vehicles, one with direct fuel injection (GDI) and the other with port fuel injection (PFI), are tested with conventional gasoline and ethanol-blended gasoline (E10) at both -7 °C and 30 °C. The total particle number (PN) concentrations and size distributions are monitored with an Electrical Low Pressure Impactor (ELPI(+)). The solid PN concentrations are measured with a condensation particle counter (CPC) after removing volatile matters through the particle measurement program (PMP) system. The results indicate that decreasing the ambient temperature from 30 °C to -7 °C significantly increases the fuel consumption and all measured emissions except for NOx. The GDI vehicle exhibits lower fuel consumption than the PFI vehicle but emits more total hydrocarbons (THC), PM mass and solid PN emissions at 30 °C. The adaptability of GDI technology appears to be better than that of PFI technology at low ambient temperature. For example, the CO, THC and PM mass emission factors of the PFI vehicle are higher than those of the GDI vehicle and the solid PN emission factors are comparable in the cold-start tests at -7 °C. Specifically, during start-up the particulate matter emissions of the PFI are much higher than the GDI. In most cases, the geometric mean diameter (GMD) of the accumulation mode particles is 58-86 nm for both vehicles, and the GMD of the nucleation mode particles is 10-20 nm. The results suggest that the gaseous and particulate emissions from the PFI vehicle should not be neglected compared to those from the GDI vehicle especially in a cold environment. PMID:27267738

  20. Tailpipe emissions from gasoline direct injection (GDI) and port fuel injection (PFI) vehicles at both low and high ambient temperatures.

    Science.gov (United States)

    Zhu, Rencheng; Hu, Jingnan; Bao, Xiaofeng; He, Liqiang; Lai, Yitu; Zu, Lei; Li, Yufei; Su, Sheng

    2016-09-01

    Vehicle emissions are greatly influenced by various factors that are related to engine technology and driving conditions. Only the fuel injection method and ambient temperature are investigated in this research. Regulated gaseous and particulate matter (PM) emissions from two advanced gasoline-fueled vehicles, one with direct fuel injection (GDI) and the other with port fuel injection (PFI), are tested with conventional gasoline and ethanol-blended gasoline (E10) at both -7 °C and 30 °C. The total particle number (PN) concentrations and size distributions are monitored with an Electrical Low Pressure Impactor (ELPI(+)). The solid PN concentrations are measured with a condensation particle counter (CPC) after removing volatile matters through the particle measurement program (PMP) system. The results indicate that decreasing the ambient temperature from 30 °C to -7 °C significantly increases the fuel consumption and all measured emissions except for NOx. The GDI vehicle exhibits lower fuel consumption than the PFI vehicle but emits more total hydrocarbons (THC), PM mass and solid PN emissions at 30 °C. The adaptability of GDI technology appears to be better than that of PFI technology at low ambient temperature. For example, the CO, THC and PM mass emission factors of the PFI vehicle are higher than those of the GDI vehicle and the solid PN emission factors are comparable in the cold-start tests at -7 °C. Specifically, during start-up the particulate matter emissions of the PFI are much higher than the GDI. In most cases, the geometric mean diameter (GMD) of the accumulation mode particles is 58-86 nm for both vehicles, and the GMD of the nucleation mode particles is 10-20 nm. The results suggest that the gaseous and particulate emissions from the PFI vehicle should not be neglected compared to those from the GDI vehicle especially in a cold environment.

  1. Kinetics of Antibody Aggregation at Neutral pH and Ambient Temperatures Triggered by Temporal Exposure to Acid.

    Science.gov (United States)

    Imamura, Hiroshi; Honda, Shinya

    2016-09-15

    The purification process of an antibody in manufacturing involves temporal exposure of the molecules to low pH followed by neutralization-pH-shift stress-which causes aggregation. It remains unclear how aggregation triggered by pH-shift stress grows at neutral pH and how it depends on the temperature in an ambient range. We used static and dynamic light scattering to monitor the time-dependent evolution of the aggregate size of the pH-shift stressed antibody between 4.0 and 40.0 °C. A power-law relationship between the effective molecular weight and the effective hydrodynamic radius was found, indicating that the aggregates were fractal with a dimension of 1.98. We found that the aggregation kinetics in the lower-temperature range, 4.0-25.0 °C, were well described by the Smoluchowski aggregation equation. The temperature dependence of the effective aggregation rate constant gave 13 ± 1 kcal/mol of endothermic activation energy. Temporal acid exposure creates an enriched population of unfolded protein molecules that are competent of aggregating. Therefore, the energetically unfavorable unfolding step is not required and the aggregation proceeds faster. These findings provide a basis for predicting the growth of aggregates during storage under practical, ambient conditions. PMID:27537343

  2. Design, Development and Implementation of the IR Signalling Techniques for Monitoring Ambient and Body Temperature in WBANs

    Directory of Open Access Journals (Sweden)

    Attiya Baqai

    2014-07-01

    Full Text Available Healthcare systems such as hospitals, homecare, telemedicine, and physical rehabilitation are expected to be revolutionized by WBAN (Wireless Body Area Networks. This research work aims to investigate, design, optimize, and demonstrate the applications of IR (Infra-Red communication systems in WBAN. It is aimed to establish a prototype WBAN system capable of measuring Ambient and Body Temperature using LM35 as temperature sensor and transmitting and receiving the data using optical signals. The corresponding technical challenges that have to be faced are also discussed in this paper. Investigations are carried out to efficiently design the hardware using low-cost and low power optical transceivers. The experimental results reveal the successful transmission and reception of Ambient and Body Temperatures over short ranges i.e. up to 3-4 meters. A simple IR transceiver with an LED (Light Emitting Diodes, TV remote control IC and Arduino microcontroller is designed to perform the transmission with sufficient accuracy and ease. Experiments are also performed to avoid interference from other sources like AC and TV remote control signals by implementing IR tags

  3. Coagulation Factor and Hemostatic Protein Content of Canine Plasma after Storage of Whole Blood at Ambient Temperature

    OpenAIRE

    Walton, J.E.; Hale, A. S.; Brooks, M. B.; Boag, A.K.; Barnett, W.; Dean, R.

    2014-01-01

    Background Standard practice in canine blood banking is to produce fresh frozen plasma (FFP) by separating and freezing plasma produced from blood within 8 hours of collection. Within canine blood donation programs, this can limit the number of units collected. Hypothesis/Objectives The aim was to compare the coagulation factor and hemostatic protein content (CF&HPC) of plasma produced from blood stored at ambient temperature for 8, 12, and 24 hours. Another aim was to compare the CF&HPC betw...

  4. A conversion model of graphite to ultrananocrystalline diamond via laser processing at ambient temperature and normal pressure

    International Nuclear Information System (INIS)

    The synthesis mechanism of ultrananocrystalline diamond via laser shock processing of graphite suspension was presented at room temperature and normal pressure, which yielded the ultrananocrystalline diamond in size of about 5 nm. X-ray diffraction, high-resolution transmission electron microscopy, and laser Raman spectroscopy were used to characterize the nano-crystals. The transformation model and growth restriction mechanism of high power density with short-pulsed laser shocking of graphite particles in liquid was put forward.

  5. Low temperature synthesis of SiCN nanostructures

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    Silicon carbon nitride (SiCN) nanowires, nanorods and nanotubes have gained much attention due to their excellent field emission and photoluminescence properties. These nanostructures were usually grown using catalysts at high temperature (800―1000℃). In this paper, synthesis of SiCN nanostruc-tures at a temperature less than 500℃ is reported. Various kinds of SiCN nanostructures were synthe-sized using microwave plasma chemical vapor deposition method. Gas mixtures of CH4, H2 and N2 were used as precursors and Si chips were inserted in the sample holder at symmetrical positions around the specimen as additional Si sources. Metallic gallium was used as the liquid medium in a mechanism similar to vapor-liquid-solid. Morphologies of the resultant were characterized by field emission scan-ning electron microscopy. Energy dispersive spectrometry and X-ray photoelectron spectroscopy were used to characterize their compositions and bonding states.

  6. Low temperature synthesis of SiCN nanostructures

    Institute of Scientific and Technical Information of China (English)

    CHENG Wen Juan; MA XueMing

    2009-01-01

    Silicon carbon nitride (SiCN) nanowires, nanorods and nanotubes have gained much attention due to their excellent field emission and photoluminescence properties. These nanostructures were usually grown using catalysts at high temperature (800-1000℃). In this paper, synthesis of SiCN nanostruc-tures at a temperature less than 500℃ is reported. Various kinds of SiCN nanostructures were synthe-sized using microwave plasma chemical vapor deposition method. Gas mixtures of CH4, H2 and N2 were used as precursors and Si chips were inserted in the sample holder at symmetrical positions around the specimen as additional Si sources. Metallic gallium was used as the liquid medium in a mechanism similar to vapor-liquid-solid. Morphologies of the resultant were characterized by field emission scan-ning electron microscopy. Energy dispersive spectrometry and X-ray photoelectron spectroscopy were used to characterize their compositions and bonding states.

  7. Effects of ambient and preceding temperatures and metabolic genes on flight metabolism in the Glanville fritillary butterfly.

    Science.gov (United States)

    Wong, Swee Chong; Oksanen, Alma; Mattila, Anniina L K; Lehtonen, Rainer; Niitepõld, Kristjan; Hanski, Ilkka

    2016-02-01

    Flight is essential for foraging, mate searching and dispersal in many insects, but flight metabolism in ectotherms is strongly constrained by temperature. Thermal conditions vary greatly in natural populations and may hence restrict fitness-related activities. Working on the Glanville fritillary butterfly (Melitaea cinxia), we studied the effects of temperature experienced during the first 2 days of adult life on flight metabolism, genetic associations between flight metabolic rate and variation in candidate metabolic genes, and genotype-temperature interactions. The maximal flight performance was reduced by 17% by 2 days of low ambient temperature (15 °C) prior to the flight trial, mimicking conditions that butterflies commonly encounter in nature. A SNP in phosphoglucose isomerase (Pgi) had a significant association on flight metabolic rate in males and a SNP in triosephosphate isomerase (Tpi) was significantly associated with flight metabolic rate in females. In the Pgi SNP, AC heterozygotes had higher flight metabolic rate than AA homozygotes following low preceding temperature, but the trend was reversed following high preceding temperature, consistent with previous results on genotype-temperature interaction for this SNP. We suggest that these results on 2-day old butterflies reflect thermal effect on the maturation of flight muscles. These results highlight the consequences of variation in thermal conditions on the time scale of days, and they contribute to a better understanding of the complex dynamics of flight metabolism and flight-related activities under conditions that are relevant for natural populations living under variable thermal conditions.

  8. Twinning Behavior of a Basal Textured Commercially Pure Titanium Alloy TA2 at Ambient and Cryogenic Temperatures

    Institute of Scientific and Technical Information of China (English)

    Jin-ru LUO; Xiao SONG; Lin-zhong ZHUANG; Ji-shan ZHANG

    2016-01-01

    Twinning greatly affects the microstructure and mechanical performance of titanium alloys.The twinning behavior of a basal textured commercially pure titanium TA2 plates rolled to 4% reduction at the ambient and cryo-genic temperatures has been investigated.Microstructures of the rolled samples were investigated by optical micro-scope (OM)and the twinning analysis was carried out based on orientation data collected by electron back-scatter diffraction (EBSD).{1 122}contraction twins,{1 124}contraction twins and {1012}extension twins have been ob-served.Twinning mode activity varied with rolling temperature.Twinning is considered as the dominant deformation mechanism during rolling at both temperatures for the strain condition.Larger proportion of grains activates twin-ning during cryorolling,and greater number and more diverse types of twins are observed;manifestly related to the suppression of dislocation slips at the cryogenic temperature.{1 122 }contraction twins are the dominate twin type within samples rolled at both temperatures.Several {1 124}contraction twins are observed in the cryorolled sample while there are only a few in the sample rolled at room temperature.A few tiny {1012}twins have been identified in both samples.{1 124}contraction twins are preferentially activated at cryogenic deformation temperature and the{1012}extension twins may result in local strain accommodation.

  9. Synthesis and microdiffraction at extreme pressures and temperatures.

    Science.gov (United States)

    Lavina, Barbara; Dera, Przemyslaw; Meng, Yue

    2013-10-07

    High pressure compounds and polymorphs are investigated for a broad range of purposes such as determine structures and processes of deep planetary interiors, design materials with novel properties, understand the mechanical behavior of materials exposed to very high stresses as in explosions or impacts. Synthesis and structural analysis of materials at extreme conditions of pressure and temperature entails remarkable technical challenges. In the laser heated diamond anvil cell (LH-DAC), very high pressure is generated between the tips of two opposing diamond anvils forced against each other; focused infrared laser beams, shined through the diamonds, allow to reach very high temperatures on samples absorbing the laser radiation. When the LH-DAC is installed in a synchrotron beamline that provides extremely brilliant x-ray radiation, the structure of materials under extreme conditions can be probed in situ. LH-DAC samples, although very small, can show highly variable grain size, phase and chemical composition. In order to obtain the high resolution structural analysis and the most comprehensive characterization of a sample, we collect diffraction data in 2D grids and combine powder, single crystal and multigrain diffraction techniques. Representative results obtained in the synthesis of a new iron oxide, Fe4O5 (1) will be shown.

  10. Influence of the ambient temperature during heat pipe manufacturing on its function and heat transport ability

    OpenAIRE

    Čaja A.; Nemec P.; Malcho M.

    2014-01-01

    Heat pipe is heat transfer device working at a minimum temperature difference of evaporator and condenser. Operating temperature of the heat pipe determine by properties of the working substance and pressure achieved during production. The contribution is focused on the determining the effect of the initial surrounding temperature where the heat pipe is manufactured and on the obtaining performance characteristics produced heat pipes in dependence of manufacturing temperature. Generally hold,...

  11. Analysing the behaviour of LED module driver under variation of ambient temperature

    Science.gov (United States)

    Bürger, A.; Sanchez, O.

    2015-01-01

    Temperature variations affect the operation of electronic devices. In this article we analyze effects that temperature variation entails a LED lamp commonly used in Brazil. We simulated temperature variations through the use of an oven of 1 m3. Then obtained emission spectrum in the visible, CRI, Correlated Color Temperature, harmonic distortion on the current, supply current, and CIE Chromatic Coordinates x and y in two situations: first with the LED module and controller inside the oven and second with the controller outside. The temperature was monitored in different part of this set. Interesting correlations for specifiers and developers were found.

  12. Analysing the behaviour of LED module driver under variation of ambient temperature

    International Nuclear Information System (INIS)

    Temperature variations affect the operation of electronic devices. In this article we analyze effects that temperature variation entails a LED lamp commonly used in Brazil. We simulated temperature variations through the use of an oven of 1 m3. Then obtained emission spectrum in the visible, CRI, Correlated Color Temperature, harmonic distortion on the current, supply current, and CIE Chromatic Coordinates x and y in two situations: first with the LED module and controller inside the oven and second with the controller outside. The temperature was monitored in different part of this set. Interesting correlations for specifiers and developers were found

  13. Coolant and ambient temperature control for chillerless liquid cooled data centers

    Energy Technology Data Exchange (ETDEWEB)

    Chainer, Timothy J.; David, Milnes P.; Iyengar, Madhusudan K.; Parida, Pritish R.; Simons, Robert E.

    2016-02-02

    Cooling control methods include measuring a temperature of air provided to a plurality of nodes by an air-to-liquid heat exchanger, measuring a temperature of at least one component of the plurality of nodes and finding a maximum component temperature across all such nodes, comparing the maximum component temperature to a first and second component threshold and comparing the air temperature to a first and second air threshold, and controlling a proportion of coolant flow and a coolant flow rate to the air-to-liquid heat exchanger and the plurality of nodes based on the comparisons.

  14. Synthesis and Thermal Insulation Performance of Silica Aerogel from Recycled Coal Gangue by Means of Ambient Pressure Drying

    Institute of Scientific and Technical Information of China (English)

    ZHU Pinghua; ZHENG Meng; ZHAO Shanyu; WU Junyong; XU Haixun

    2015-01-01

    Silica aerogel materials are well recognized for their superinsulation performance and are regarded as one of the hot candidates to revolutionize building insulation. To date, high production cost related to exorbitant precursors as well as cumbrous multi-step hydrophobization process has often narrowed the ifeld of applications. In this work, granular silica aerogel materials were synthesized by extracting SiO2from recycled rich silicon coal gangue, followed by one-step hydrophobization and ambient pressure drying. Lightweight (about 0.16 g/cm3) and nanostructural aerogels were obtained through this route. They exhibit a 3D open porous microstructure with around 600 cm2/g surface area and 20 nm of the average pore diameter, thermal conductivity of 4-5 mm packed granules is 20-25 mW/(m·K), which was proved by both guarded hot plate and hot-wire transient methods. This study offers a new facile route for the synthesis of silica aerogel from recycled solid waste coal gangue and suggests a method, which may lead to a cost reduction in terms of industrial production.

  15. On-Board State-of-Health Estimation at a Wide Ambient Temperature Range in Lithium-Ion Batteries

    Directory of Open Access Journals (Sweden)

    Tiansi Wang

    2015-08-01

    Full Text Available A state-of-health (SOH estimation method for electric vehicles (EVs is presented with three main advantages: (1 it provides joint estimation of cell’s aging states in terms of power and energy (i.e., SOHP and SOHE—because the determination of SOHP and SOHE can be reduced to the estimation of the ohmic resistance increase and capacity loss, respectively, the ohmic resistance at nominal temperature will be taken as a health indicator, and the capacity loss is estimated based on a mechanistic model that is developed to describe the correlation between resistance increase and capacity loss; (2 it has wide applicability to various ambient temperatures—to eliminate the effects of temperature on the resistance, another mechanistic model about the resistance against temperature is presented, which can normalize the resistance at various temperatures to its standard value at the nominal temperature; and (3 it needs low computational efforts for on-board application—based on a linear equation of cell’s dynamic behaviors, the recursive least-squares (RLS algorithm is used for the resistance estimation. Based on the designed performance and validation experiments, respectively, the coefficients of the models are determined and the accuracy of the proposed method is verified. The results at different aging states and temperatures show good accuracy and reliability.

  16. 绿橙常温保鲜的研究%Storage of Hainan Green Oranges at Ambient Temperature

    Institute of Scientific and Technical Information of China (English)

    陈婷; 王志国; 刘四新; 刘艳; 李从发

    2011-01-01

    The effects of different package methods, pre-storage methods, preservatives, and gibberellin on the storage of Hainan green oranges were studied at ambient temperature. The results showed that when they were washed using tap water, and soaked for lmin in the solution composed of 1000 mg/kg imazalil and 50 mg/kg gibberellin, and then packed by polyethylene film, Hainan green oranges could be stored for 28 d at ambient temperature (26~30%), with a good fruit rate of 93.3% and weight loss rate of 1.5% and green color in the pericarp.Prestorage and gibberellin were not good for the storage of Hainan green oranges.%本文主要研究包装方式,预贮、抑菌剂及赤霉素对海南绿橙常温下保鲜效果的影响,结果表明:抑霉唑1000mg/kg浸果1min,晾干后采用O.01mm厚的PE膜单果包装,常温(26~30℃)贮藏28d,好果率为93.3%,失重率为1.5%,果皮色泽青绿,果蒂新鲜,主要营养成分下降速度变缓;而预贮及赤霉素不适宜海南绿橙的采后处理.

  17. Temperature and vacuum ambient effects on the cathodoluminescent degradation of sulfide-based thin film and powder phosphors

    Science.gov (United States)

    Abrams, Billie Lynn

    Changes in the cathodoluminescent (CL) brightness, surface chemistry and morphology of SiO2-coated and uncoated ZnS:Ag,Cl powder, and ZnS:Mn thin films have been investigated using scanning Auger electron spectrometry (AES), optical spectrometry and scanning electron microscopy (SEM). Water partial pressure, surface coatings and temperature were controlled as parameters critical to degradation. In the case of an oxidizing ambient (i.e., high water partial pressure) a non-luminescent oxide layer formed on all materials. In the case of a reducing ambient (i.e., low water and high hydrogen) hydrogen removes S as H2S, leaving elemental Zn which evaporates due to its high vapor pressure. In the case of SiO2-coated ZnS:Ag,Cl, morphological changes were observed on the surface after extended electron beam exposure. This erosion of ZnS is more rapid at higher power densities. Uncoated ZnS:Ag,Cl phosphors exhibited no change in the surface morphology. The SEM images of SiO-coated samples after degradation and reaction rate data suggest that the SiO 2 particles acted as a catalyst for CL and morphological degradation. Temperature effects on degradation were isolated by measuring thermal quenching behavior. Upon heating, the CL intensity decreased, the spectral shape changed and shifted to higher wavelengths. This shift was attributed to band gap narrowing and copper contamination. Full recovery of the CL occurred upon cooling. Evaporation of Zn and degradation of ZnS is accelerated by elevated temperatures caused by electron beam heating. CL loss at high temperatures with constant electron beam exposure was less than that at RT for the same coulombic dose. This supports the predictions of the ESSCR model that elevated temperatures causes a decrease in the residence time of physisorbed species, reducing the rate of surface reactions. After elevated temperature degradation, morphological erosion occurred for uncoated ZnS. At the combined temperature due to electron beam

  18. Research Update: Direct conversion of h-BN into pure c-BN at ambient temperatures and pressures in air

    Energy Technology Data Exchange (ETDEWEB)

    Narayan, Jagdish, E-mail: narayan@ncsu.edu; Bhaumik, Anagh [Department of Materials Science and Engineering, Centennial Campus, North Carolina State University, Raleigh, North Carolina 27695-7907 (United States)

    2016-02-01

    We report a direct conversion of hexagonal boron nitride (h-BN) into pure cubic boron nitride (c-BN) by nanosecond laser melting at ambient temperatures and atmospheric pressure in air. According to the phase diagram, the transformation from h-BN into c-BN can occur only at high temperatures and pressures, as the hBN-cBN-Liquid triple point is at 3500 K/9.5 GPa. Using nanosecond laser melting, we have created super undercooled state and shifted this triple point to as low as 2800 K and atmospheric pressure. The rapid quenching from super undercooled state leads to formation of super undercooled BN (Q-BN). The c-BN phase is nucleated from Q-BN depending upon the time allowed for nucleation and growth.

  19. Research Update: Direct conversion of h-BN into pure c-BN at ambient temperatures and pressures in air

    Directory of Open Access Journals (Sweden)

    Jagdish Narayan

    2016-02-01

    Full Text Available We report a direct conversion of hexagonal boron nitride (h-BN into pure cubic boron nitride (c-BN by nanosecond laser melting at ambient temperatures and atmospheric pressure in air. According to the phase diagram, the transformation from h-BN into c-BN can occur only at high temperatures and pressures, as the hBN-cBN-Liquid triple point is at 3500 K/9.5 GPa. Using nanosecond laser melting, we have created super undercooled state and shifted this triple point to as low as 2800 K and atmospheric pressure. The rapid quenching from super undercooled state leads to formation of super undercooled BN (Q-BN. The c-BN phase is nucleated from Q-BN depending upon the time allowed for nucleation and growth.

  20. Recombination of H2 and O2 catalyzed by hydrophobic Pt/C/FN catalyst at ambient temperature

    International Nuclear Information System (INIS)

    Pt/C(w(Pt)=10%) catalyst was prepared by microwave heating method at high pressure, and the average size of Pt particles was (2.1 ± 0.7) nm. Then polytetrafluoroethylene (PTFE) and the Pt/C catalyst were supported on foamed nickel (FN) to obtain hydrophobic Pt/C/FN catalyst. The effects of reaction temperature and H2 flow rate on the catalytic activity of the Pt/C/FN catalyst were determined for the recombination reaction of H2-O2 at ambient temperature. The catalytic activity of the hydrophobic Pt/C/FN catalyst is found to be remarkablely higher than that of the commercial hydrophilic Pt/Al2O3 catalyst. Its catalytic activity decreases little under moist environment, compared with dried condition. The influence of CO on its catalytic activity was examined under excess O2. The H2 conversion is influenced by CO slightly. (authors)

  1. Analysis of multi-band pyrometry for emissivity and temperature measurements of gray surfaces at ambient temperature

    Science.gov (United States)

    Araújo, António

    2016-05-01

    A multi-band pyrometry model is developed to evaluate the potential of measuring temperature and emissivity of assumably gray target surfaces at 300 K. Twelve wavelength bands between 2 and 60 μm are selected to define the spectral characteristics of the pyrometers. The pyrometers are surrounded by an enclosure with known background temperature. Multi-band pyrometry modeling results in an overdetermined system of equations, in which the solution for temperature and emissivity is obtained through an optimization procedure that minimizes the sum of the squared residuals of each system equation. The Monte Carlo technique is applied to estimate the uncertainties of temperature and emissivity, resulting from the propagation of the uncertainties of the pyrometers. Maximum reduction in temperature uncertainty is obtained from dual-band to tri-band systems, a small reduction is obtained from tri-band to quad-band, with a negligible reduction above quad-band systems (a reduction between 6.5% and 12.9% is obtained from dual-band to quad-band systems). However, increasing the number of bands does not always reduce uncertainty, and uncertainty reduction depends on the specific band arrangement, indicating the importance of choosing the most appropriate multi-band spectral arrangement if uncertainty is to be reduced. A reduction in emissivity uncertainty is achieved when the number of spectral bands is increased (a reduction between 6.3% and 12.1% is obtained from dual-band to penta-band systems). Besides, emissivity uncertainty increases for pyrometers with high wavelength spectral arrangements. Temperature and emissivity uncertainties are strongly dependent on the difference between target and background temperatures: uncertainties are low when the background temperature is far from the target temperature, tending to very high values as the background temperature approaches the target temperature.

  2. Ambient Temperature Based Thermal Aware Energy Efficient ROM Design on FPGA

    DEFF Research Database (Denmark)

    Saini, Rishita; Bansal, Neha; Bansal, Meenakshi;

    2015-01-01

    temperature is a temperature of surroundings. Airflow is measured in Linear Feet per Minute (LFM). Medium profile and high profile are two different heat sink profile available in XPower analyzer.When frequency goes from 4.0GHz to 1.0GHz, there is 21.8% reduction in clock power, 75% reduction in I/O Power, 35...

  3. Single step low temperature synthesis of gadolinium gallium garnet nanopowders

    Institute of Scientific and Technical Information of China (English)

    Rekha Mann; Kiranmala Laishram; Neelam Malhan

    2012-01-01

    Solution combustion synthesis of single-phase gadolinium gallium oxide (Gd3Ga5O12,GGG) nanopowders,by a fuel mixture approach using urea and glycine at a low temperature of 500 ℃,was being reported for the first time.Based on the fact that urea and glycine are good fuels for gallium oxide and gadolinium oxide synthesis,the fuel mixture composition was obtained,which could lead to direct phase pure cubic Gd3Ga5O12 formation without any subsequent calcination step.Combustion was carried out in furnace pre-heated at 500 ℃.Thermogravimetric analysis (TGA) of combustion product showed negligible mass loss indicating direct formation of GGG powder.Fourier transform infrared (FTIR) spectrum of combusted product showed peak characteristic of GGG in case of mixed fuel.X-ray diffraction (XRD) confirmed formation of phase pure GGG at 500 ℃ in preheated furnace.Very fine,well dispersed nanometric particles of size range of 50-100 nm were obtained,being uniform and close to spherical morphology as observed by transmission electron microscope (TEM).

  4. The burden of ambient temperature on years of life lost in Guangzhou, China

    Science.gov (United States)

    Yang, Jun; Ou, Chun-Quan; Guo, Yuming; Li, Li; Guo, Cui; Chen, Ping-Yan; Lin, Hua-Liang; Liu, Qi-Yong

    2015-08-01

    Limited evidence is available on the association between temperature and years of life lost (YLL). We applied distributed lag non-linear model to assess the nonlinear and delayed effects of temperature on YLL due to cause-/age-/education-specific mortality in Guangzhou, China. We found that hot effects appeared immediately, while cold effects were more delayed and lasted for 14 days. On average, 1 °C decrease from 25th to 1st percentile of temperature was associated with an increase of 31.15 (95%CI: 20.57, 41.74), 12.86 (8.05, 17.68) and 6.64 (3.68, 9.61) YLL along lag 0-14 days for non-accidental, cardiovascular and respiratory diseases, respectively. The corresponding estimate of cumulative hot effects (1 °C increase from 75th to 99th percentile of temperature) was 12.71 (-2.80, 28.23), 4.81 (-2.25, 11.88) and 2.81 (-1.54, 7.16). Effect estimates of cold and hot temperatures-related YLL were higher in people aged up to 75 years and persons with low education level than the elderly and those with high education level, respectively. The mortality risks associated with cold and hot temperatures were greater on the elderly and persons with low education level. This study highlights that YLL provides a complementary method for assessing the death burden of temperature.

  5. Solid-state ligand-driven light-induced spin change at ambient temperatures in bis(dipyrazolylstyrylpyridine)iron(II) complexes.

    Science.gov (United States)

    Takahashi, Kazuhiro; Hasegawa, Yuta; Sakamoto, Ryota; Nishikawa, Michihiro; Kume, Shoko; Nishibori, Eiji; Nishihara, Hiroshi

    2012-05-01

    We previously reported that an Fe(II) complex ligated by two (Z)-2,6-di(1H-pyrazol-1-yl)-4-styrylpyridine ligands (Z-H) presented a solid state ligand-driven light-induced spin change (LD-LISC) upon one-way Z-to-E photoisomerization, although modulation of the magnetism was trivial at ambient temperatures (Chem. Commun.2011, 47, 6846). Here, we report the synthesis of new derivatives of Z-H, Z-CN and Z-NO(2), in which electron-withdrawing cyano and nitro substituents are introduced at the 4-position of the styryl group to attain a more profound photomagnetism at ambient temperatures. Z-CN and Z-NO(2) undergo quantitative one-way Z-to-E photochromism upon excitation of the charge transfer band both in acetonitrile and in the solid state, similar to the behavior observed for Z-H. In solution, these substituents stabilized the low-spin (LS) states of Z-CN and Z-NO(2), and the behavior was quantitatively analyzed according to the Evans equation. The photomagnetic properties in the solid state, on the other hand, cannot be explained in terms of the substituent effect alone. Z-CN displayed photomagnetic properties almost identical to those of Z-H. Z-CN preferred the high-spin (HS) state at all temperatures tested, whereas photoirradiated Z-CN yielded a lower χ(M)T at ambient temperatures. The behavior of Z-NO(2) was counterintuitive, and the material displayed surprising photomagnetic properties in the solid state. Z-NO(2) occupied the LS state at low temperatures and underwent thermal spin crossover (SCO) with a T(1/2) of about 270 K. The photoirradiated Z-NO(2) displayed a higher value of χ(M)T and the modulation of χ(M)T exceeded that of Z-H or Z-CN. Z-NO(2)·acetone, in which acetone molecules were incorporated into the crystal lattice, further stabilized the LS state (T(1/2) > 300 K), thereby promoting large modulations of the χ(M)T values (87% at 273 K and 64% at 300 K) upon Z-to-E photoisomerization. Single crystal X-ray structure analysis revealed that

  6. Self propagating high temperature synthesis of ferrites in magnetic fields

    CERN Document Server

    Affleck, L

    2002-01-01

    Self propagating high temperature synthesis (SHS) reactions have been performed on mixtures of BaO sub 2 , Fe and Fe sub 2 O sub 3 to form barium ferrite, BaFe sub 1 sub 2 O sub 1 sub 9. Reactions were conducted in zero field and in an applied magnetic field of 1.1 T with the aim of exploring the influence of the field. The temperature and velocity of the reactions were measured and the products, both post-SHS and post-annealing, were characterised by techniques including X-ray diffraction, Moessbauer spectroscopy, vibrating sample magnetometry and electron microprobe analysis. The applied magnetic field was found to lead to hotter and faster reactions, a greater degree of conversion of the reactants, a needle-like microstructure in the post-SHS product, and a reduced coercive field (approx 20-30 %) in the annealed product, compared to zero field. Sodium perchlorate was used as an internal oxidising agent, and found to produce similar effects. Correlations were observed between the temperature reached in the ...

  7. Effects of temperature, algae biomass and ambient nutrient on the absorption of dissolved nitrogen and phosphate by Rhodophyte Gracilaria asiatica

    Institute of Scientific and Technical Information of China (English)

    DU Rongbin; LIU Liming; WANG Aimin; WANG Yongqiang

    2013-01-01

    Gracilaria asiatica,being highly efficient in nutrient absorption,is cultivated in sea cucumber ponds to remove nutrients such as nitrogen and phosphate.It was cultured in a laboratory simulating field conditions,and its nutrient absorption was measured to evaluate effects of environmental conditions.Ammonia nitrogen (AN),nitrate nitrogen (NN),total inorganic nitrogen (TIN),and soluble reactive phosphorus (SRP) uptake rate and removal efficiency were determined in a 4x2 factorial design experiment in water temperatures (T) at 15℃ and 25℃,algae biomass (AB) at 0.5 g/L and 1.0 g/L,total inorganic nitrogen (TIN) at 30 μmol/L and 60 μmol/L,and soluble reactive phosphorus (SRP) at 3 and 6 μmol/L.AB and ambient TIN or SRP levels significantly affected uptake rate and removal efficiency of AN,NN,TIN,and SRP (P<0.001).G.asiatica in AB of 0.5 g/L showed higher uptake rate and lower removal efficiency relative to that with AB of 1.0 g/L.Nitrogen and phosphorus uptake rate rose with increasing ambient nutrient concentrations; nutrient removal efficiency decreased at higher environmental nutrient concentrations.The algae preferred to absorb AN to NN.Uptake rates of AN,NN,and SRP were significantly affected by temperature (P<0.001); uptake rate was higher for the 25℃ group than for the 15℃ group at the initial experiment stage.Only the removal efficiency of AN and SRP showed a significant difference between the two temperature groups (P<0.01).The four factors had significant interactive effects on absorption of N and P,implying that G.asiatica has great bioremedial potential in sea cucumber culture ponds.

  8. Influence of ambient temperatures on metabolic responses of Murrah buffaloes of varying physiological states from arid tracts in India

    Directory of Open Access Journals (Sweden)

    Ashish Joshi

    2012-12-01

    Full Text Available Ambient temperature associated variations in metabolic responses of Murrah breed ofbuffaloes of varying physiological states belonging to arid tracts were investigated. Healthy adultfemale Murrah buffaloes were grouped according to physiological states into group A (non-pregnantmilch, pregnant milch and pregnant dry and group B (primipara and multipara and blood sampleswere collected during moderate, hot and cold environmental temperature periods to obtain sera.Metabolic responses were assessed by analyzing serum urea, creatinine, total proteins, cholesterol,triglycerides and glucose and the moderate mean values were 5.18±0.04 mmol L-1, 118.00±1.00 μmolL-1, 71.00±0.12 gL-1, 3.30±0.02 mmol L-1, 1.28±0.01 mmol L-1 and 3.7±0.02 mmol L-1, respectively.The mean values of serum urea and creatinine were significantly (p≤0.05 higher during hot and coldambiences, the mean value of total serum proteins and triglycerides were significantly (p≤0.05 lowerduring hot and cold ambiences and the mean values of cholesterol and glucose were significantly(p≤0.05 lower during hot ambience and significantly (p≤0.05 higher during cold ambience ascompared to respective moderate mean value. The mean values of non pregnant milch, pregnant milchand pregnant dry animals differed significantly (p≤0.05 from each other in all the environmentalperiods. It was concluded that extreme hot and cold ambient temperatures affected the buffaloes ofall physiological states which was evident in the form of variations in the metabolic responses tocombat the environmental challenges.

  9. Model Study of the Influence of Ambient Temperature and Installation Types on Surface Temperature Measurement by Using a Fiber Bragg Grating Sensor

    Directory of Open Access Journals (Sweden)

    Yi Liu

    2016-07-01

    Full Text Available Surface temperature is an important parameter in clinical diagnosis, equipment state control, and environmental monitoring fields. The Fiber Bragg Grating (FBG temperature sensor possesses numerous significant advantages over conventional electrical sensors, thus it is an ideal choice to achieve high-accuracy surface temperature measurements. However, the effects of the ambient temperature and installation types on the measurement of surface temperature are often overlooked. A theoretical analysis is implemented and a thermal transfer model of a surface FBG sensor is established. The theoretical and simulated analysis shows that both substrate strain and the temperature difference between the fiber core and hot surface are the most important factors which affect measurement accuracy. A surface-type temperature standard setup is proposed to study the measurement error of the FBG temperature sensor. Experimental results show that there are two effects influencing measurement results. One is the “gradient effect”. This results in a positive linear error with increasing surface temperature. Another is the “substrate effect”. This results in a negative non-linear error with increasing surface temperature. The measurement error of the FBG sensor with single-ended fixation are determined by the gradient effect and is a linear error. It is not influenced by substrate expansion. Thus, it can be compensated easily. The measurement errors of the FBG sensor with double-ended fixation are determined by the two effects and the substrate effect is dominant. The measurement error change trend of the FBG sensor with fully-adhered fixation is similar to that with double-ended fixation. The adhesive layer can reduce the two effects and measurement error. The fully-adhered fixation has lower error, however, it is easily affected by substrate strain. Due to its linear error and strain-resistant characteristics, the single-ended fixation will play an

  10. Model Study of the Influence of Ambient Temperature and Installation Types on Surface Temperature Measurement by Using a Fiber Bragg Grating Sensor.

    Science.gov (United States)

    Liu, Yi; Zhang, Jun

    2016-07-01

    Surface temperature is an important parameter in clinical diagnosis, equipment state control, and environmental monitoring fields. The Fiber Bragg Grating (FBG) temperature sensor possesses numerous significant advantages over conventional electrical sensors, thus it is an ideal choice to achieve high-accuracy surface temperature measurements. However, the effects of the ambient temperature and installation types on the measurement of surface temperature are often overlooked. A theoretical analysis is implemented and a thermal transfer model of a surface FBG sensor is established. The theoretical and simulated analysis shows that both substrate strain and the temperature difference between the fiber core and hot surface are the most important factors which affect measurement accuracy. A surface-type temperature standard setup is proposed to study the measurement error of the FBG temperature sensor. Experimental results show that there are two effects influencing measurement results. One is the "gradient effect". This results in a positive linear error with increasing surface temperature. Another is the "substrate effect". This results in a negative non-linear error with increasing surface temperature. The measurement error of the FBG sensor with single-ended fixation are determined by the gradient effect and is a linear error. It is not influenced by substrate expansion. Thus, it can be compensated easily. The measurement errors of the FBG sensor with double-ended fixation are determined by the two effects and the substrate effect is dominant. The measurement error change trend of the FBG sensor with fully-adhered fixation is similar to that with double-ended fixation. The adhesive layer can reduce the two effects and measurement error. The fully-adhered fixation has lower error, however, it is easily affected by substrate strain. Due to its linear error and strain-resistant characteristics, the single-ended fixation will play an important role in the FBG sensor

  11. Model Study of the Influence of Ambient Temperature and Installation Types on Surface Temperature Measurement by Using a Fiber Bragg Grating Sensor.

    Science.gov (United States)

    Liu, Yi; Zhang, Jun

    2016-01-01

    Surface temperature is an important parameter in clinical diagnosis, equipment state control, and environmental monitoring fields. The Fiber Bragg Grating (FBG) temperature sensor possesses numerous significant advantages over conventional electrical sensors, thus it is an ideal choice to achieve high-accuracy surface temperature measurements. However, the effects of the ambient temperature and installation types on the measurement of surface temperature are often overlooked. A theoretical analysis is implemented and a thermal transfer model of a surface FBG sensor is established. The theoretical and simulated analysis shows that both substrate strain and the temperature difference between the fiber core and hot surface are the most important factors which affect measurement accuracy. A surface-type temperature standard setup is proposed to study the measurement error of the FBG temperature sensor. Experimental results show that there are two effects influencing measurement results. One is the "gradient effect". This results in a positive linear error with increasing surface temperature. Another is the "substrate effect". This results in a negative non-linear error with increasing surface temperature. The measurement error of the FBG sensor with single-ended fixation are determined by the gradient effect and is a linear error. It is not influenced by substrate expansion. Thus, it can be compensated easily. The measurement errors of the FBG sensor with double-ended fixation are determined by the two effects and the substrate effect is dominant. The measurement error change trend of the FBG sensor with fully-adhered fixation is similar to that with double-ended fixation. The adhesive layer can reduce the two effects and measurement error. The fully-adhered fixation has lower error, however, it is easily affected by substrate strain. Due to its linear error and strain-resistant characteristics, the single-ended fixation will play an important role in the FBG sensor

  12. Model Study of the Influence of Ambient Temperature and Installation Types on Surface Temperature Measurement by Using a Fiber Bragg Grating Sensor

    Science.gov (United States)

    Liu, Yi; Zhang, Jun

    2016-01-01

    Surface temperature is an important parameter in clinical diagnosis, equipment state control, and environmental monitoring fields. The Fiber Bragg Grating (FBG) temperature sensor possesses numerous significant advantages over conventional electrical sensors, thus it is an ideal choice to achieve high-accuracy surface temperature measurements. However, the effects of the ambient temperature and installation types on the measurement of surface temperature are often overlooked. A theoretical analysis is implemented and a thermal transfer model of a surface FBG sensor is established. The theoretical and simulated analysis shows that both substrate strain and the temperature difference between the fiber core and hot surface are the most important factors which affect measurement accuracy. A surface-type temperature standard setup is proposed to study the measurement error of the FBG temperature sensor. Experimental results show that there are two effects influencing measurement results. One is the “gradient effect”. This results in a positive linear error with increasing surface temperature. Another is the “substrate effect”. This results in a negative non-linear error with increasing surface temperature. The measurement error of the FBG sensor with single-ended fixation are determined by the gradient effect and is a linear error. It is not influenced by substrate expansion. Thus, it can be compensated easily. The measurement errors of the FBG sensor with double-ended fixation are determined by the two effects and the substrate effect is dominant. The measurement error change trend of the FBG sensor with fully-adhered fixation is similar to that with double-ended fixation. The adhesive layer can reduce the two effects and measurement error. The fully-adhered fixation has lower error, however, it is easily affected by substrate strain. Due to its linear error and strain-resistant characteristics, the single-ended fixation will play an important role in the FBG

  13. Temperature and electron density distributions of laser-induced plasmas generated with an iron sample at different ambient gas pressures

    International Nuclear Information System (INIS)

    Intensity, temperature and electron density distributions of laser-induced plasmas (LIPs) have been measured by emission spectroscopy with two-dimensional spatial resolution and temporal resolution. The plasmas have been generated with an iron sample at different pressures of air, in the range 10-1000 mbar. An experimental system based in an imaging spectrometer equipped with an intensified CCD detector has been used to obtain the spectra with two-dimensional spatial resolution. The evolution of the intensity distributions is described by the blast wave model only at initial times. The temperature distributions are shown to correspond to a slight difference between the intensity distributions of two Fe I emission lines that have a high difference of their upper energy levels (3.38 eV). The electron density distributions have similar features to those of the temperature distributions. The features of the intensity and temperature distributions show a significant change with the ambient gas pressure: they have separated maxima in the plasmas generated at pressures below 100 mbar, whereas at higher pressures, the maxima of the two distributions coincide

  14. Temperature and electron density distributions of laser-induced plasmas generated with an iron sample at different ambient gas pressures

    Science.gov (United States)

    Aguilera, J. A.; Aragón, C.

    2002-09-01

    Intensity, temperature and electron density distributions of laser-induced plasmas (LIPs) have been measured by emission spectroscopy with two-dimensional spatial resolution and temporal resolution. The plasmas have been generated with an iron sample at different pressures of air, in the range 10-1000 mbar. An experimental system based in an imaging spectrometer equipped with an intensified CCD detector has been used to obtain the spectra with two-dimensional spatial resolution. The evolution of the intensity distributions is described by the blast wave model only at initial times. The temperature distributions are shown to correspond to a slight difference between the intensity distributions of two Fe I emission lines that have a high difference of their upper energy levels (3.38 eV). The electron density distributions have similar features to those of the temperature distributions. The features of the intensity and temperature distributions show a significant change with the ambient gas pressure: they have separated maxima in the plasmas generated at pressures below 100 mbar, whereas at higher pressures, the maxima of the two distributions coincide.

  15. Physical exercise-induced changes in the core body temperature of mice depend more on ambient temperature than on exercise protocol or intensity

    Science.gov (United States)

    Wanner, Samuel Penna; Costa, Kátia Anunciação; Soares, Anne Danieli Nascimento; Cardoso, Valbert Nascimento; Coimbra, Cândido Celso

    2014-08-01

    The mechanisms underlying physical exercise-induced hyperthermia may be species specific. Therefore, the present study aimed to investigate the effects of exercise intensity and ambient temperature on the core body temperature ( T core) of running mice, which provide an important experimental model for advancing the understanding of thermal physiology. We evaluated the influence of different protocols (constant- or incremental-speed exercises), treadmill speeds and ambient temperatures ( T a) on the magnitude of exercise-induced hyperthermia. To measure T core, a telemetric sensor was implanted in the abdominal cavity of male adult Swiss mice under anesthesia. After recovering from the surgery, the animals were familiarized to running on a treadmill and then subjected to the different running protocols and speeds at two T a: 24 °C or 34 °C. All of the experimental trials resulted in marked increases in T core. As expected, the higher-temperature environment increased the magnitude of running-induced hyperthermia. For example, during incremental exercise at 34 °C, the maximal T core achieved was increased by 1.2 °C relative to the value reached at 24 °C. However, at the same T a, neither treadmill speed nor exercise protocol altered the magnitude of exercise-induced hyperthermia. We conclude that T core of running mice is influenced greatly by T a, but not by the exercise protocols or intensities examined in the present report. These findings suggest that the magnitude of hyperthermia in running mice may be regulated centrally, independently of exercise intensity.

  16. Epitaxial growth of MgB2 films at ambient temperature

    Science.gov (United States)

    Shishido, Hiroaki; Yoshida, Takuya; Nakagami, Takatoshi; Ishida, Takekazu

    We grew crystalline MgB2 thin films using molecular beam epitaxy at a low substrate temperature of 110 °C under an ultrahigh vacuum of about 10-6 Pa. MgB2 thin films were deposited on the (001) surface of a 4H-SiC substrate with an epitaxial Mg buffer layer. The epitaxial growth was confirmed by X-ray diffraction measurements. MgB2 thin films show a sharp superconducting transition at 27.2 K, with a relatively narrow superconducting transition width ΔTc = 0.9 K. The growth temperature was lower than any in prior reports on superconducting MgB2 thin films. The presence of the epitaxial Mg buffer layer is crucial for reducing the epitaxial temperature.

  17. All-solid-state lithium-oxygen battery with high safety in wide ambient temperature range

    OpenAIRE

    Hirokazu Kitaura; Haoshen Zhou

    2015-01-01

    There is need to develop high energy storage devices with high safety to satisfy the growing industrial demands. Here, we show the potential to realize such batteries by assembling a lithium-oxygen cell using an inorganic solid electrolyte without any flammable liquid or polymer materials. The lithium-oxygen battery using Li1.575Al0.5Ge1.5(PO4)3 solid electrolyte was examined in the pure oxygen atmosphere from room temperature to 120 °C. The cell works at room temperature and first full disch...

  18. A Decrease in Ambient Temperature Induces Post-Mitotic Enlargement of Palisade Cells in North American Lake Cress.

    Directory of Open Access Journals (Sweden)

    Rumi Amano

    Full Text Available In order to maintain organs and structures at their appropriate sizes, multicellular organisms orchestrate cell proliferation and post-mitotic cell expansion during morphogenesis. Recent studies using Arabidopsis leaves have shown that compensation, which is defined as post-mitotic cell expansion induced by a decrease in the number of cells during lateral organ development, is one example of such orchestration. Some of the basic molecular mechanisms underlying compensation have been revealed by genetic and chimeric analyses. However, to date, compensation had been observed only in mutants, transgenics, and γ-ray-treated plants, and it was unclear whether it occurs in plants under natural conditions. Here, we illustrate that a shift in ambient temperature could induce compensation in Rorippa aquatica (Brassicaceae, a semi-aquatic plant found in North America. The results suggest that compensation is a universal phenomenon among angiosperms and that the mechanism underlying compensation is shared, in part, between Arabidopsis and R. aquatica.

  19. Association Between High Ambient Temperature and Risk of Stillbirth in California.

    Science.gov (United States)

    Basu, Rupa; Sarovar, Varada; Malig, Brian J

    2016-05-15

    Recent studies have linked elevated apparent temperatures with adverse birth outcomes, such as preterm delivery, but other birth outcomes have not been well studied. We examined 8,510 fetal deaths (≥20 weeks' gestation) to estimate their association with mean apparent temperature, a combination of temperature and humidity, during the warm season in California (May-October) from 1999 to 2009. Mothers whose residential zip codes were within 10 km of a meteorological monitor were included. Meteorological data were provided by the California Irrigation Management Information System, the US Environmental Protection Agency, and the National Climatic Data Center, while the California Department of Public Health provided stillbirth data. Using a time-stratified case-crossover study design, we found a 10.4% change (95% confidence interval: 4.4, 16.8) in risk of stillbirth for every 10°F (5.6°C) increase in apparent temperature (cumulative average of lags 2-6 days). Risk varied by maternal race/ethnicity and was greater for younger mothers, less educated mothers, and male fetuses. The highest risks were observed during gestational weeks 20-25 and 31-33. No associations were found during the cold season (November-April), and the observed associations were independent of air pollutants. This study adds to the growing body of literature identifying pregnant women and their fetuses as subgroups vulnerable to heat exposure. PMID:27037268

  20. Predator-released compounds, ambient temperature and competitive exclusion among differently sized Daphnia species

    NARCIS (Netherlands)

    Vijverberg, J.; Vos, Matthijs

    2006-01-01

    1. We studied the effects of fish water and temperature on mechanisms of competitive exclusion among two Daphnia species in flow-through microcosms. The large-bodied D. pulicaria outcompeted the medium sized D. galeata × hyalina in fish water, but not in the control treatment. Daphnia galeata × hyal

  1. Facile palladium catalyzed Suzuki-Miyaura coupling in air and water at ambient temperature

    KAUST Repository

    Marziale, Alexander N.

    2010-01-01

    A new palladacyclic catalyst yields high activities in aqueous Suzuki-Miyaura coupling at room temperature. Using an optimized protocol, a broad range of products can be isolated in good to excellent yields and high purity by simple filtration. © 2010 The Royal Society of Chemistry.

  2. Synthesis of manganese spinel nanoparticles at room temperature by coprecipitation

    Energy Technology Data Exchange (ETDEWEB)

    Giovannelli, F., E-mail: fabien.giovannelli@univ-tours.fr [GREMAN, UMR 7347 CNRS-CEA, Universite Francois Rabelais, 15 rue de la chocolaterie, 41000 BLOIS (France); Autret-Lambert, C.; Mathieu, C.; Chartier, T.; Delorme, F. [GREMAN, UMR 7347 CNRS-CEA, Universite Francois Rabelais, 15 rue de la chocolaterie, 41000 BLOIS (France); Seron, A [BRGM, 3 Avenue Claude Guillemin, BP 36009, 45060 ORLEANS Cedex 2 (France)

    2012-08-15

    This paper is focused on a new route to synthesize Mn{sub 3}O{sub 4} nanoparticles by alkalisation by sodium hydroxide on a manganeous solution at room temperature. The precipitates obtained at different pH values have been characterized by XRD and TEM. Since the first addition of sodium hydroxide, a white Mn(OH){sub 2} precipitate appears. At pH=7, {gamma}-MnOOH phase is predominant with needle like shaped particles. At pH=10, hausmanite nanoparticles, which exhibits well defined cubic shape in the range 50-120 nm are obtained. This new precipitation route is a fast and easy environmentally friendly process to obtain well crystallized hausmanite nanoparticles. - Graphical abstract: TEM image showing Mn{sub 3}O{sub 4} particles after a precipitation at pH=10. Highlights: Black-Right-Pointing-Pointer A new route to synthesize Mn{sub 3}O{sub 4} nanoparticles has been demonstrated. Black-Right-Pointing-Pointer Synthesis has been performed by precipitation at room temperature. Black-Right-Pointing-Pointer The size of the Mn{sub 3}O{sub 4} nanoparticles is between 50 and 120 nm.

  3. Experimental assessment of the energy consumption of urban rail vehicles during stabling hours: Influence of ambient temperature

    International Nuclear Information System (INIS)

    Urban rail has widely recognised potential to reduce congestion and air pollution in metropolitan areas, given its high capacity and environmental performance. Nevertheless, growing capacity demands and rising energy costs may call for significant energy efficiency improvements in such systems. Energy consumed by stabled rolling stock has been traditionally overlooked in the scientific literature in favour of analysing traction loads, which generally account for the largest share of this consumption. Thus, this paper presents the methodology and results of an experimental investigation that aimed to assess the energy use of stabled vehicles in the Tyne and Wear Metro system (UK). It is revealed that approximately 11% of the rolling stock's total energy consumption is due to the operation of on-board auxiliaries when stabled, and investigation of these loads is therefore a worthwhile exercise. Heating is responsible for the greatest portion of this energy, and an empirical correlation between ambient temperature and power drawn is given. This could prove useful for a preliminary evaluation of further energy saving measures in this area. Even though this investigation focused on a particular metro system in a relatively cold region, its methodology may also be valid for other urban and main line railways operating in different climate conditions. - Highlights: •Energy use of stabled vehicles in an actual metro system is experimentally examined. •Stabling hours account for about 11% of the vehicles' total energy consumption. •Heating is the major consumer during stabling hours. •An empirical correlation between ambient temperature and power drawn is derived. •The methodology described may also be applied to other urban and main line railways

  4. Impacts of Ambient Temperature and Pressure on PM2.5 Emission Profiles of Light-Duty Diesel Vehicles

    Science.gov (United States)

    Wang, Chenyu; Wu, Ye; Li, Zhenhua; Hao, Jiming

    2012-01-01

    The impact of the environmental factors on the emissions of particulate matter (PM) number, size distribution and mass size distribution from diesel passenger cars was evaluated. Particle measurements from five modern light-duty diesel vehicles (LDDV) were performed in June and November 2011. Commercial low sulfur diesel fuel (less than 50 ppm) was used during the testing of these vehicles which were not equipped with after-treatment devices. The dynamometer test was based on the Economic Commission of Europe (ECE) 15 cycles. The results indicate that PM2.5 emissions from LDDV are significantly affected by ambient temperature and pressure. A comparison of the emissions concentration of PM2.5 in these two different months showed that the number concentration in June was (3.8 ± 0.69) × 107 cm-3 and (2.5 ± 0.66) × 107 cm-3 in November. The PM concentration of about 30 nm diameter was 25 ± 6% of the total emissions in November while only 14 ± 3% of total emissions in June. In the 60 nm to 2.5 μm test range, November data shows less of a contribution for number than data from June testing. The concentration of mass emissions in June was (325 ± 44) mg/m3 and (92 ± 30) mg/m3 in November. The contribution of the number of PM particles in November testing is lower than testing in June by 34% and the mass concentration in November is 70% lower than that in June. With the decrease of ambient temperature and the increase of ambient pressure, both the oxygen concentration in cylinder and air-fuel ratio are increased, which caused lower particle number and mass emissions during November testing. The size distribution is also altered by these changes: the more efficient in-cylinder combustion resulted in a higher proportion of particles in the 30 nm and smaller range than for other particle sizes.

  5. A high-temperature, ambient-pressure ultra-dry operando reactor cell for Fourier-transform infrared spectroscopy

    International Nuclear Information System (INIS)

    The construction of a newly designed high-temperature, high-pressure FT-IR reaction cell for ultra-dry in situ and operando operation is reported. The reaction cell itself as well as the sample holder is fully made of quartz glass, with no hot metal or ceramic parts in the vicinity of the high-temperature zone. Special emphasis was put on chemically absolute water-free and inert experimental conditions, which includes reaction cell and gas-feeding lines. Operation and spectroscopy up to 1273 K is possible, as well as pressures up to ambient conditions. The reaction cell exhibits a very easy and variable construction and can be adjusted to any available FT-IR spectrometer. Its particular strength lies in its possibility to access and study samples under very demanding experimental conditions. This includes studies at very high temperatures, e.g., for solid-oxide fuel cell research or studies where the water content of the reaction mixtures must be exactly adjusted. The latter includes all adsorption studies on oxide surfaces, where the hydroxylation degree is of paramount importance. The capability of the reaction cell will be demonstrated for two selected examples where information and in due course a correlation to other methods can only be achieved using the presented setup

  6. A high-temperature, ambient-pressure ultra-dry operando reactor cell for Fourier-transform infrared spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Köck, Eva-Maria; Kogler, Michaela; Pramsoler, Reinhold; Klötzer, Bernhard; Penner, Simon, E-mail: simon.penner@uibk.ac.at [Institute of Physical Chemistry, University of Innsbruck, Innrain 80-82, A-6020 Innsbruck (Austria)

    2014-08-15

    The construction of a newly designed high-temperature, high-pressure FT-IR reaction cell for ultra-dry in situ and operando operation is reported. The reaction cell itself as well as the sample holder is fully made of quartz glass, with no hot metal or ceramic parts in the vicinity of the high-temperature zone. Special emphasis was put on chemically absolute water-free and inert experimental conditions, which includes reaction cell and gas-feeding lines. Operation and spectroscopy up to 1273 K is possible, as well as pressures up to ambient conditions. The reaction cell exhibits a very easy and variable construction and can be adjusted to any available FT-IR spectrometer. Its particular strength lies in its possibility to access and study samples under very demanding experimental conditions. This includes studies at very high temperatures, e.g., for solid-oxide fuel cell research or studies where the water content of the reaction mixtures must be exactly adjusted. The latter includes all adsorption studies on oxide surfaces, where the hydroxylation degree is of paramount importance. The capability of the reaction cell will be demonstrated for two selected examples where information and in due course a correlation to other methods can only be achieved using the presented setup.

  7. A high-temperature, ambient-pressure ultra-dry operando reactor cell for Fourier-transform infrared spectroscopy.

    Science.gov (United States)

    Köck, Eva-Maria; Kogler, Michaela; Pramsoler, Reinhold; Klötzer, Bernhard; Penner, Simon

    2014-08-01

    The construction of a newly designed high-temperature, high-pressure FT-IR reaction cell for ultra-dry in situ and operando operation is reported. The reaction cell itself as well as the sample holder is fully made of quartz glass, with no hot metal or ceramic parts in the vicinity of the high-temperature zone. Special emphasis was put on chemically absolute water-free and inert experimental conditions, which includes reaction cell and gas-feeding lines. Operation and spectroscopy up to 1273 K is possible, as well as pressures up to ambient conditions. The reaction cell exhibits a very easy and variable construction and can be adjusted to any available FT-IR spectrometer. Its particular strength lies in its possibility to access and study samples under very demanding experimental conditions. This includes studies at very high temperatures, e.g., for solid-oxide fuel cell research or studies where the water content of the reaction mixtures must be exactly adjusted. The latter includes all adsorption studies on oxide surfaces, where the hydroxylation degree is of paramount importance. The capability of the reaction cell will be demonstrated for two selected examples where information and in due course a correlation to other methods can only be achieved using the presented setup. PMID:25173282

  8. A high-temperature, ambient-pressure ultra-dry operando reactor cell for Fourier-transform infrared spectroscopy

    Science.gov (United States)

    Köck, Eva-Maria; Kogler, Michaela; Pramsoler, Reinhold; Klötzer, Bernhard; Penner, Simon

    2014-08-01

    The construction of a newly designed high-temperature, high-pressure FT-IR reaction cell for ultra-dry in situ and operando operation is reported. The reaction cell itself as well as the sample holder is fully made of quartz glass, with no hot metal or ceramic parts in the vicinity of the high-temperature zone. Special emphasis was put on chemically absolute water-free and inert experimental conditions, which includes reaction cell and gas-feeding lines. Operation and spectroscopy up to 1273 K is possible, as well as pressures up to ambient conditions. The reaction cell exhibits a very easy and variable construction and can be adjusted to any available FT-IR spectrometer. Its particular strength lies in its possibility to access and study samples under very demanding experimental conditions. This includes studies at very high temperatures, e.g., for solid-oxide fuel cell research or studies where the water content of the reaction mixtures must be exactly adjusted. The latter includes all adsorption studies on oxide surfaces, where the hydroxylation degree is of paramount importance. The capability of the reaction cell will be demonstrated for two selected examples where information and in due course a correlation to other methods can only be achieved using the presented setup.

  9. Dependence of nitrogen concentration in type Ib diamonds on synthesis temperature

    Institute of Scientific and Technical Information of China (English)

    TIAN Yu; JIA XiaoPeng; ZANG ChuanYi; LI ShangSheng; XIAO HongYu; ZHANG YaFei; HUANG GuoFeng; LI Rui; HAN QiGang; MA LiQiu; LI Yong; CHEN XiaoZhou; ZHANG Chong; MA HongAn

    2009-01-01

    Type Ib diamonds were grown by the temperature gradient method (TGM) at 5.5 GPa and 1500-1560 K in a china-type cubic anvil high pressure apparatus using Ni70Mn25Co5 alloy as solvent/catalyst. The concentration of nitrogen (CN) in type Ib diamonds synthesized at different synthesis temperatures was measured by a Fourier transform infrared (FTIR) spectrometer. The dependence of CN in diamond on synthesis temperature was studied. For the type Ib diamonds synthesized using Ni70Mn25Co5 as catalyst, its CN decreases along with the increase of synthesis temperature.

  10. Heterogeneous Palladium Chloride Catalyzed Ligand-free Suzuki-Miyaura Coupling Reactions at Ambient Temperature

    Institute of Scientific and Technical Information of China (English)

    WANG Min; WANG Lei

    2008-01-01

    A mild and efficient ligand-free Suzuki-Miyaura coupling reaction catalyzed by heterogeneous palladium chloride was developed at room temperature in a short reaction time under air atmosphere.Various phenyl iodides,bromides and activated chlorides were coupled with sodium tetraphenylborate or phenylboronic acids efficiently to afford the corresponding cross-coupled products in good to excellent yields.Furthermore,the catalyst could be recycled up to four times without loss of its activity.

  11. Suppression of ambient temperature creep by eutectic phase for hexagonal close-packed metal

    Energy Technology Data Exchange (ETDEWEB)

    Matsunaga, Tetsuya, E-mail: matsunaga@imr.tohoku.ac.jp; Abe, Tomonori, E-mail: tomonori-abe@imr.tohoku.ac.jp; Itoh, Shun, E-mail: shun-itoh@imr.tohoku.ac.jp; Satoh, Yuhki, E-mail: ysatoh@imr.tohoku.ac.jp; Abe, Hiroaki, E-mail: abe.hiroaki@imr.tohoku.ac.jp

    2014-03-15

    Zr–Si alloys were designed to contain eutectic phase surrounding the parent phase to suppress creep behavior of claddings. Creep tests conducted at 294–573 K showed that creep behavior was inhibited and that the creep failure time of new Zr alloy became longer than that of a conventional alloy: Zircaloy-4. Results show that the eutectic phase can suppress creep at operating temperatures prevailing in current nuclear power plants.

  12. Ambient organic carbon to elemental carbon ratios: Influence of the thermal–optical temperature protocol and implications

    Energy Technology Data Exchange (ETDEWEB)

    Cheng, Yuan, E-mail: ycheng@mail.tsinghua.edu.cn [State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing (China); He, Ke-bin, E-mail: hekb@tsinghua.edu.cn [State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing (China); State Environmental Protection Key Laboratory of Sources and Control of Air Pollution Complex, Beijing (China); Duan, Feng-kui; Du, Zhen-yu [State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing (China); Zheng, Mei [College of Environmental Sciences and Engineering, Peking University, Beijing (China); Ma, Yong-liang [State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing (China)

    2014-01-01

    Ambient organic carbon (OC) to elemental carbon (EC) ratios are strongly associated with not only the radiative forcing due to aerosols but also the extent of secondary organic aerosol (SOA) formation. An inter-comparison study was conducted based on fine particulate matter samples collected during summer in Beijing to investigate the influence of the thermal–optical temperature protocol on the OC to EC ratio. Five temperature protocols were used such that the NIOSH (National Institute for Occupational Safety and Health) and EUSAAR (European Supersites for Atmospheric Aerosol Research) protocols were run by the Sunset carbon analyzer while the IMPROVE (the Interagency Monitoring of Protected Visual Environments network)-A protocol and two alternative protocols designed based on NIOSH and EUSAAR were run by the DRI analyzer. The optical attenuation measured by the Sunset carbon analyzer was more easily biased by the shadowing effect, whereas total carbon agreed well between the Sunset and DRI analyzers. The EC{sub IMPROVE-A} (EC measured by the IMPROVE-A protocol; similar hereinafter) to EC{sub NIOSH} ratio and the EC{sub IMPROVE-A} to EC{sub EUSAAR} ratio averaged 1.36 ± 0.21 and 0.91 ± 0.10, respectively, both of which exhibited little dependence on the biomass burning contribution. Though the temperature protocol had substantial influence on the OC to EC ratio, the contributions of secondary organic carbon (SOC) to OC, which were predicted by the EC-tracer method, did not differ significantly among the five protocols. Moreover, the SOC contributions obtained in this study were comparable with previous results based on field observation (typically between 45 and 65%), but were substantially higher than the estimation provided by an air quality model (only 18%). The comparison of SOC and WSOC suggests that when using the transmittance charring correction, all of the three common protocols (i.e., IMPROVE-A, NIOSH and EUSAAR) could be reliable for the estimation

  13. Ambient organic carbon to elemental carbon ratios: Influence of the thermal–optical temperature protocol and implications

    International Nuclear Information System (INIS)

    Ambient organic carbon (OC) to elemental carbon (EC) ratios are strongly associated with not only the radiative forcing due to aerosols but also the extent of secondary organic aerosol (SOA) formation. An inter-comparison study was conducted based on fine particulate matter samples collected during summer in Beijing to investigate the influence of the thermal–optical temperature protocol on the OC to EC ratio. Five temperature protocols were used such that the NIOSH (National Institute for Occupational Safety and Health) and EUSAAR (European Supersites for Atmospheric Aerosol Research) protocols were run by the Sunset carbon analyzer while the IMPROVE (the Interagency Monitoring of Protected Visual Environments network)-A protocol and two alternative protocols designed based on NIOSH and EUSAAR were run by the DRI analyzer. The optical attenuation measured by the Sunset carbon analyzer was more easily biased by the shadowing effect, whereas total carbon agreed well between the Sunset and DRI analyzers. The ECIMPROVE-A (EC measured by the IMPROVE-A protocol; similar hereinafter) to ECNIOSH ratio and the ECIMPROVE-A to ECEUSAAR ratio averaged 1.36 ± 0.21 and 0.91 ± 0.10, respectively, both of which exhibited little dependence on the biomass burning contribution. Though the temperature protocol had substantial influence on the OC to EC ratio, the contributions of secondary organic carbon (SOC) to OC, which were predicted by the EC-tracer method, did not differ significantly among the five protocols. Moreover, the SOC contributions obtained in this study were comparable with previous results based on field observation (typically between 45 and 65%), but were substantially higher than the estimation provided by an air quality model (only 18%). The comparison of SOC and WSOC suggests that when using the transmittance charring correction, all of the three common protocols (i.e., IMPROVE-A, NIOSH and EUSAAR) could be reliable for the estimation of SOC by the EC

  14. Dynamic instability at the origin of oxygen ion conduction in solid oxides at ambient temperature

    Indian Academy of Sciences (India)

    Helmut Schober; Werner Paulus; Tanguy Berthier; Olivier Hernandez; Monica Ceretti; Stefan Eibl; Mark Johnson; Marie Plazanet; Carlo Lamberti

    2008-11-01

    The conduction of ions in solids is of paramount importance for many technological devices like solid oxide fuel cells. It is inherent to solids that ions are trapped within potential wells. Their transport thus has to be activated at the price of elevated temperatures, a condition that is often incompatible with technological applications. While atomic vibrations have the potential of assisting the diffusion process, little is known about the exact conditions that have to be reunited to trigger such a process. Here we show that dynamic instability is responsible for the large ion conduction in SrFeO2.5 with brownmillerite-type structure. Using ab-initio molecular dynamics calculations we observe the migration of oxygen ions away from the original lattice positions into the vacancy channels of the brownmillerite structure. The escape of the oxygen ion is rendered possible by the destabilization of a shallow potential well due to low-lying vibrational modes, the existence of which is confirmed by neutron spectroscopy. Analysing the lattice dynamics as a function of structural parameters it is possible to identify the structural subtleties responsible for the instability. It is found that in the isostructural compound CaFeO2.5, fast oxygen ion diffusion is absent at low temperatures. The origin of this behaviour lies with the slightly different iron–oxygen distances rendering the potentials better defined and less amenable to dynamical destabilization. The here-introduced concept of dynamical instability is not restricted to the discussed class of materials but may be applied to any system that features ion conduction at low temperatures.

  15. An Ambient Temperature Molten Sodium-Vanadium Battery with Aqueous Flowing Catholyte.

    Science.gov (United States)

    Liu, Caihong; Shamie, Jack S; Shaw, Leon L; Sprenkle, Vincent L

    2016-01-20

    In this study, we have investigated the key factors dictating the cyclic performance of a new type of hybrid sodium-based flow batteries (HNFBs) that can operate at room temperature with high cell voltages (>3 V), multiple electron transfer redox reactions per active ion, and decoupled design of power and energy. HNFBs are composed of a molten Na-Cs alloy anode, flowing aqueous catholyte, and a Na-β″-Al2O3 solid electrolyte as the separator. The surface functionalization of graphite felt electrodes for the flowing aqueous catholyte has been studied for its effectiveness in enhancing V(2+)/V(3+), V(3+)/V(4+), and V(4+)/V(5+) redox couples. The V(4+)/V(5+) redox reaction has been further investigated at different cell operation temperatures for its cyclic stability and how the properties of the solid electrolyte membrane play a role in cycling. These fundamental understandings provide guidelines for improving the cyclic performance and stability of HNFBs with aqueous catholytes. We show that the HNFB with aqueous V-ion catholyte can reach high storage capacity (∼70% of the theoretical capacity) with good Coulombic efficiency (90% ± 1% in 2-30 cycles) and cyclic performance (>99% capacity retention for 30 cycles). It demonstrates, for the first time, the potential of high capacity HNFBs with aqueous catholytes, good capacity retention and long cycling life. This is also the first demonstration that Na-β″-Al2O3 solid electrolyte can be used with aqueous electrolyte at near room temperature for more than 30 cycles. PMID:26720551

  16. An Ambient Temperature Molten Sodium-Vanadium Battery with Aqueous Flowing Catholyte.

    Science.gov (United States)

    Liu, Caihong; Shamie, Jack S; Shaw, Leon L; Sprenkle, Vincent L

    2016-01-20

    In this study, we have investigated the key factors dictating the cyclic performance of a new type of hybrid sodium-based flow batteries (HNFBs) that can operate at room temperature with high cell voltages (>3 V), multiple electron transfer redox reactions per active ion, and decoupled design of power and energy. HNFBs are composed of a molten Na-Cs alloy anode, flowing aqueous catholyte, and a Na-β″-Al2O3 solid electrolyte as the separator. The surface functionalization of graphite felt electrodes for the flowing aqueous catholyte has been studied for its effectiveness in enhancing V(2+)/V(3+), V(3+)/V(4+), and V(4+)/V(5+) redox couples. The V(4+)/V(5+) redox reaction has been further investigated at different cell operation temperatures for its cyclic stability and how the properties of the solid electrolyte membrane play a role in cycling. These fundamental understandings provide guidelines for improving the cyclic performance and stability of HNFBs with aqueous catholytes. We show that the HNFB with aqueous V-ion catholyte can reach high storage capacity (∼70% of the theoretical capacity) with good Coulombic efficiency (90% ± 1% in 2-30 cycles) and cyclic performance (>99% capacity retention for 30 cycles). It demonstrates, for the first time, the potential of high capacity HNFBs with aqueous catholytes, good capacity retention and long cycling life. This is also the first demonstration that Na-β″-Al2O3 solid electrolyte can be used with aqueous electrolyte at near room temperature for more than 30 cycles.

  17. The Effect of Ambient Temperature and Exercise to the Level of Exhaustion on

    Directory of Open Access Journals (Sweden)

    Somaye Kasharafifard

    2014-06-01

    Full Text Available Background: The increase in the amount of heat shock protein and C-reactive protein occurring as a result of stress was done with the aims of returning cell homeostasis, successful restoration of cell injury and protection of cell against more injuries. Materials and Methods: Fifteen climber and 15 non athlete subjects were chosen. A selected aerobic test was done by the subjects using Monark bicycle under two different conditions. Before starting the test, the subjects were exposed to a normal condition with the temperature of 24±2°C for an hour and a blood sample was taken from all the subjects. Then immediately, the subjects took the selected aerobic test to the level of exhaustion and blood sample was taken again. A week later, these subjects were exposed to a heated environment with the temperature of 38±2°C, followed by blood sample taking. Finally, the test was done by the subjects to the level of exhaustion and the last blood sample was taken. Then, the amount of heat shock protein (HSP and C - reactive protein (CRP in blood samples was measured. Results: A meaningful difference was observed in the changes of heat shock proteins (p=0.012 and C-reactive protein (p=0.02 between athlete and non athlete subjects. There was no meaningful difference in CRP and HSP in normal and hot condition for non athlete subjects before and after the test. But the result of the study demonstrates that There was a meaningful difference for athletes in both conditions before and after the test (p=0.002. Conclusion: Based on the study, it is claimed that while an athlete is exposed to several stressful conditions (e.g. high temperature and physical exercise, compared to a non athlete, the reaction of his body cells is more significant in order to prevent the injury.

  18. Research Update: Direct conversion of amorphous carbon into diamond at ambient pressures and temperatures in air

    International Nuclear Information System (INIS)

    We report on fundamental discovery of conversion of amorphous carbon into diamond by irradiating amorphous carbon films with nanosecond lasers at room-temperature in air at atmospheric pressure. We can create diamond in the form of nanodiamond (size range <100 nm) and microdiamond (>100 nm). Nanosecond laser pulses are used to melt amorphous diamondlike carbon and create a highly undercooled state, from which various forms of diamond can be formed upon cooling. The quenching from the super undercooled state results in nucleation of nanodiamond. It is found that microdiamonds grow out of highly undercooled state of carbon, with nanodiamond acting as seed crystals

  19. Radappertization of steak breast chicken grilled for storage at ambient temperature

    International Nuclear Information System (INIS)

    Gamma radiation with high doses was used on steak breast chicken. The doses of 25 kGy and 50 kGy were used on the fillets vacuum packaged; the storage temperature was 22-25 deg C for 180 days, and the analysis were done each 30 days. The microbiology (Clostridium perfringens); physical-chemical (humidity, protein, lipids, pH, color and TBA); and sensorial analysis, were done. The samples did not showed colony for any treatment by irradiation during storage period. The irradiated samples showed both higher humidity and brightness than those no irradiated. All treatment showed high notes on hedonic scale, by sensorial analysis. (author)

  20. Effect of Surrogate Aggregates on the Thermal Conductivity of Concrete at Ambient and Elevated Temperatures

    Directory of Open Access Journals (Sweden)

    Tae Sup Yun

    2014-01-01

    Full Text Available The accurate assessment of the thermal conductivity of concretes is an important part of building design in terms of thermal efficiency and thermal performance of materials at various temperatures. We present an experimental assessment of the thermal conductivity of five thermally insulated concrete specimens made using lightweight aggregates and glass bubbles in place of normal aggregates. Four different measurement methods are used to assess the reliability of the thermal data and to evaluate the effects of the various sensor types. The concrete specimens are also assessed at every 100°C during heating to ~800°C. Normal concrete is shown to have a thermal conductivity of ~2.25 W m−1 K−1. The surrogate aggregates effectively reduce the conductivity to ~1.25 W m−1 K−1 at room temperature. The aggregate size is shown not to affect thermal conduction: fine and coarse aggregates each lead to similar results. Surface contact methods of assessment tend to underestimate thermal conductivity, presumably owing to high thermal resistance between the transducers and the specimens. Thermogravimetric analysis shows that the stages of mass loss of the cement paste correspond to the evolution of thermal conductivity upon heating.

  1. Differential chromosomal and mitochondrial DNA synthesis in temperature-sensitive mutants of Ustilago maydis

    Energy Technology Data Exchange (ETDEWEB)

    Unrau, P.

    1977-01-01

    The amount and type of residual DNA synthesis was determined in eight temperature-sensitive mutants of the smut fungus Ustilago maydis after incubation at the restrictive temperature (32/sup 0/C) for eight hours. Mutants ts-220, ts-207, ts-432 and ts-346 were found to have an overall reduction in the synthesis of both nuclear and mitochondrial DNA in comparison to the wild-type. In mutants ts-20, tsd 1-1, ts-84 and pol 1-1 nuclear DNA synthesis was depressed relative to mitochondrial synthesis. The DNA-polymerase mutant pol 1-1 had persistent nuclear synthesis at about 50% of the rate of synthesis of mitochondrial DNA and similar behavior was observed in a diploid homozygous strain. Mutant ts-84 had an initial burst of DNA synthesis which was reduced for nuclear but not mitochondrial synthesis after three hours preincubation at 32/sup 0/C. tsd 1-1 and ts-20 had nuclear residual synthesis amounting to about 25% of the relative rate of mitochondrial synthesis which correlates to increasing UV sensitivity of these strains on incubation at 32/sup 0/C. A pol 1-1 ts-84 double mutant had an additive loss of nuclear DNA synthesis which indicates that the steps of replication involved may be sequential.

  2. Using Estimated On-Site Ambient Temperature Has Uncertain Benefit When Estimating Postmortem Interval

    Directory of Open Access Journals (Sweden)

    Laurent Dourel

    2010-01-01

    Full Text Available The forensic entomologist uses weather station data as part of the calculation when estimating the postmortem interval (PMI. To reduce the potential inaccuracies of this method caused by the distance between the crime scene and the meteorological station, temperature correlation data from the site of the corpse may be used. This experiment simulated the impact of retrospective weather data correction using linear regression between seven stations and sites in three climatic exposure groups during three different seasons as part of the accumulated degree days calculation for three necrophagous species (Diptera: Calliphoridae. No consistent benefit in the use of correlation or the original data from the meteorological stations was observed. In nine cases out of 12, the data from the weather station network limited the risk of a deviation from reality. The forensic entomologist should be cautious when using this correlation model.

  3. Migration and release behavior of tritium in SS316 at ambient temperature

    Science.gov (United States)

    Torikai, Y.; Murata, D.; Penzhorn, R.-D.; Akaishi, K.; Watanabe, K.; Matsuyama, M.

    2007-06-01

    BIXS measurements indicate that immersion into water or chemical etching of SS316 contaminated with tritium at moderate temperatures causes an immediate reduction of the outermost surface concentration of tritium. The fraction of surface tritium removed by water, i.e. 30-50%, is small in comparison to the total tritium present in the specimen. Allowing a specimen to age whose surface and subsurface had been removed by etching up to a depth where the concentration of tritium is mostly constant revealed that within a few months a re-growth of tritium up to a saturation value higher than half of that originally present on the specimen takes place. Concurrently, a small but steady liberation of tritium at rates increasing from 0.1 to 0.3 kBq/h was noticed.

  4. Station for spatially distributed measurements of soil moisture and ambient temperature

    Science.gov (United States)

    Jankovec, Jakub; Šanda, Martin; Haase, Tomáš; Sněhota, Michal; Wild, Jan

    2013-04-01

    Third generation of combined thermal and soil moisture standalone field station coded TMS3 with wireless communication is presented. The device combines three thermometers (MAXIM/DALLAS Semiconductor DS7505U with -55 to +125°C range and 0.0625°C resolution, 0.5°C precision in 0 to +70°C range and 2°C precision out of this range). Soil moisture measurement is performed based on time domain transmission (TDT) principle for the full range of soil moisture with 0.025% resolution within the full possible soil moisture span for the most typical conditions of dry to saturated soils with safe margins to enable measurements in freezing, hot or saline soils. Principal compact version is designed for temperature measurements approximately at heights -10, 0 and +15 cm relative to soil surface when installed vertically and soil moisture measurements between 0 and 12 cm below surface. Set of buriable/subsurface stations each with 2.2 meter extension cord with soil and surface temperature measurement provides possibility to scan vertical soil profile for soil moisture and temperature at desired depths. USB equipped station is designed for streamed direct data acquisition in laboratory use in 1s interval. Station is also equipped with the shock sensor indicating the manipulation. Presented version incorporates life time permanent data storage (0.5 million logs). Current sensor design aims towards improved durability in harsh outdoor environment with reliable functioning in wet conditions withstanding mechanical or electric shock destruction. Insertion into the soil is possible by pressing with the use of a simple plastic cover. Data are retrieved by contact portable pocket collector (second generation) or by RFID wireless communication for hundreds meter distance (third generation) in either star pattern of GSM hub to stations or lined up GSM to station to another station both in comprised data packets. This option will allow online data harvesting and real time process

  5. Effects of ambient air temperature, humidity and rainfall on annual survival of adult little penguins Eudyptula minor in southeastern Australia

    Science.gov (United States)

    Ganendran, L. B.; Sidhu, L. A.; Catchpole, E. A.; Chambers, L. E.; Dann, P.

    2015-12-01

    Seabirds are subject to the influences of local climate variables during periods of land-based activities such as breeding and, for some species, moult; particularly if they undergo a catastrophic moult (complete simultaneous moult) as do penguins. We investigated potential relationships between adult penguin survival and land-based climate variables (ambient air temperature, humidity and rainfall) using 46 years of mark-recapture data of little penguins Eudyptula minor gathered at a breeding colony on Phillip Island in southeastern Australia. Our results showed that adult penguin survival had a stronger association with land-based climate variables during the moult period, when birds were unable to go to sea for up to 3 weeks, than during the breeding period, when birds could sacrifice breeding success in favour of survival. Annual adult survival probability was positively associated with humidity during moult and negatively associated with rainfall during moult. Prolonged heat during breeding and moult had a negative association with annual adult survival. Local climate projections suggest increasing days of high temperatures, fewer days of rainfall which will result in more droughts (and by implication, lower humidity) and more extreme rainfall events. All of these predicted climate changes are expected to have a negative impact on adult penguin survival.

  6. Effects of ambient air temperature, humidity and rainfall on annual survival of adult little penguins Eudyptula minor in southeastern Australia

    Science.gov (United States)

    Ganendran, L. B.; Sidhu, L. A.; Catchpole, E. A.; Chambers, L. E.; Dann, P.

    2016-08-01

    Seabirds are subject to the influences of local climate variables during periods of land-based activities such as breeding and, for some species, moult; particularly if they undergo a catastrophic moult (complete simultaneous moult) as do penguins. We investigated potential relationships between adult penguin survival and land-based climate variables (ambient air temperature, humidity and rainfall) using 46 years of mark-recapture data of little penguins Eudyptula minor gathered at a breeding colony on Phillip Island in southeastern Australia. Our results showed that adult penguin survival had a stronger association with land-based climate variables during the moult period, when birds were unable to go to sea for up to 3 weeks, than during the breeding period, when birds could sacrifice breeding success in favour of survival. Annual adult survival probability was positively associated with humidity during moult and negatively associated with rainfall during moult. Prolonged heat during breeding and moult had a negative association with annual adult survival. Local climate projections suggest increasing days of high temperatures, fewer days of rainfall which will result in more droughts (and by implication, lower humidity) and more extreme rainfall events. All of these predicted climate changes are expected to have a negative impact on adult penguin survival.

  7. Effect of season and high ambient temperature on activity levels and patterns of grizzly bears (Ursus arctos.

    Directory of Open Access Journals (Sweden)

    Michelle L McLellan

    Full Text Available Understanding factors that influence daily and annual activity patterns of a species provides insights to challenges facing individuals, particularly when climate shifts, and thus is important in conservation. Using GPS collars with dual-axis motion sensors that recorded the number of switches every 5 minutes we tested the hypotheses: 1. Grizzly bears (Ursus arctos increase daily activity levels and active bout lengths when they forage on berries, the major high-energy food in this ecosystem, and 2. Grizzly bears become less active and more nocturnal when ambient temperature exceeds 20°C. We found support for hypothesis 1 with both male and female bears being active from 0.7 to 2.8 h longer in the berry season than in other seasons. Our prediction under hypothesis 2 was not supported. When bears foraged on berries on a dry, open mountainside, there was no relationship between daily maximum temperature (which varied from 20.4 to 40.1°C and the total amount of time bears were active, and no difference in activity levels during day or night between warm (20.4-27.3°C and hot (27.9-40.1°C days. Our results highlight the strong influence that food acquisition has on activity levels and patterns of grizzly bears and is a challenge to the heat dissipation limitation theory.

  8. Effect of season and high ambient temperature on activity levels and patterns of grizzly bears (Ursus arctos).

    Science.gov (United States)

    McLellan, Michelle L; McLellan, Bruce N

    2015-01-01

    Understanding factors that influence daily and annual activity patterns of a species provides insights to challenges facing individuals, particularly when climate shifts, and thus is important in conservation. Using GPS collars with dual-axis motion sensors that recorded the number of switches every 5 minutes we tested the hypotheses: 1. Grizzly bears (Ursus arctos) increase daily activity levels and active bout lengths when they forage on berries, the major high-energy food in this ecosystem, and 2. Grizzly bears become less active and more nocturnal when ambient temperature exceeds 20°C. We found support for hypothesis 1 with both male and female bears being active from 0.7 to 2.8 h longer in the berry season than in other seasons. Our prediction under hypothesis 2 was not supported. When bears foraged on berries on a dry, open mountainside, there was no relationship between daily maximum temperature (which varied from 20.4 to 40.1°C) and the total amount of time bears were active, and no difference in activity levels during day or night between warm (20.4-27.3°C) and hot (27.9-40.1°C) days. Our results highlight the strong influence that food acquisition has on activity levels and patterns of grizzly bears and is a challenge to the heat dissipation limitation theory.

  9. Novel Cubic Magnetite Nanoparticle Synthesis Using Room Temperature Ionic Liquid

    Directory of Open Access Journals (Sweden)

    M. Sundrarajan

    2012-01-01

    Full Text Available Room Temperature Ionic liquids are relatively more useful in the synthesis of inorganic nanostructured materials because of their unique properties. To synthesize the iron oxide nanoparticle in simple precipitation method, a novel ionic liquid was used as the greener medium and stabilizing agent namely “1-n-butyl-3-methylimidazolium trifluoromethane sulfonate [BMIM][TfO]”. The crystallinity, chemical structure, morphology and magnetic properties of the synthesized magnetite nanoparticles have been characterized by using X-ray diffraction (XRD, Fourier Transform Infrared (FT-IR, Scanning electron microscopy (SEM, Atomic force microscopy(AFM, Transmission electron microscopy (TEM and Vibrating sample magnetometer (VSM studies. The XRD study is divulge that the synthesized magnetite nanoparticles have inverse spinel face centered cubic structure. The FT-IR vibration peaks show the formation of Fe3O4 nanoparticles, where the vibration peak for Fe-O is deliberately presence at 584 cm-1. The average particle size of the synthesized nanoparticles is found to be 35 nm. Homogeneously dispersed cubic shape with superstructure is found through SEM, AFM and TEM examination studies. The synthesized iron oxide nanoparticles have a high saturation magnetization value of 25 emu/g, which is very much useful for biomedical applications.

  10. Evaluation of an Absorption Heat Pump to Mitigate Plant Capacity Reduction Due to Ambient Temperature Rise for an Air-Cooled Ammonia and Water Cycle: Preprint

    International Nuclear Information System (INIS)

    Air-cooled geothermal plants suffer substantial decreases in generating capacity at increased ambient temperatures. As the ambient temperature rises by 50 F above a design value of 50 F, at low brine-resource temperatures, the decrease in generating capacity can be more than 50%. This decrease is caused primarily by increased condenser pressure. Using mixed-working fluids has recently drawn considerable attention for use in power cycles. Such cycles are more readily amenable to use of absorption ''heat pumps.'' For a system that uses ammonia and water as the mixed-working fluid, this paper evaluates using an absorption heat pump to reduce condenser backpressure. At high ambient temperatures, part of the turbine exhaust vapor is absorbed into a circulating mixed stream in an absorber in series with the main condenser. This steam is pumped up to a higher pressure and heated to strip the excess vapor, which is recondensed using an additional air-cooled condenser. The operating conditions are chosen to reconstitute this condensate back to the same concentration as drawn from the original system. We analyzed two power plants of nominal 1-megawatt capacity. The design resource temperatures were 250 F and 300 F. Ambient temperature was allowed to rise from a design value of 50 F to 100 F. The analyses indicate that using an absorption heat pump is feasible. For the 300 F resource, an increased brine flow of 30% resulted in a net power increase of 21%. For the 250 F resource, the increase was smaller. However, these results are highly plant- and equipment-specific because evaluations must be carried out at off-design conditions for the condenser. Such studies should be carried out for specific power plants that suffer most from increased ambient temperatures

  11. Temperature-induced volatility of molecular markers in ambient airborne particulate matter

    Directory of Open Access Journals (Sweden)

    C. R. Ruehl

    2011-01-01

    Full Text Available Molecular markers are organic compounds used to represent known sources of particulate matter (PM in statistical source apportionment studies. The utility of molecular markers depends on, among other things, their ability to represent PM volatility under realistic atmospheric conditions. We measured the particle-phase concentrations and temperature-induced volatility of commonly-used molecular markers in California's heavily polluted San Joaqin Valley. Concentrations of elemental carbon, organic carbon, levoglucosan, and polycyclic aromatic hydrocarbons were not reduced by mild (~10 K heating. In contrast, both hopane/sterane and n-alkane concentrations were reduced, especially during the summer sampling events at the urban site. These results suggest that hopanes and steranes have effective saturation concentrations ~1 μg m−3, and therefore can be considered semi-volatile. The volatility of an individual compound depends both on its inherent properties (primarily vapour pressure and the interactions between itself and any potential absorbing phase. The volatility behavior of n-alkanes during the urban summer is consistent with that predicted for absorption by suberic acid (a C8 diacid using a group contribution modelling method. Observations can also be matched by an absorbent whose composition is based on recently-obtained high-resolution aerosol mass spectrometer factors (approximately 33% "hydrocarbon-like" and 67% oxygenated organic aerosol. The reduced evaporation of the n-alkanes, hopanes, and steranes with mild heating during rural and/or winter experiments could be explained by a more oxygenated absorbing phase along with a non-absorptive partitioning mechanism, such as adsorption to soot. This suggests that the temperature-induced volatility of large hydrocarbons in PM is most important if a relatively non-polar absorbing organic phase exists. While the activity coefficients of most organic

  12. Performance, at ambient temperature, of ionization chambers filled with a liquid dielectric

    International Nuclear Information System (INIS)

    The authors describe the performance characteristics of ionization chambers filled with carefully purified normal hexane. A detailed study of the background of a detector of this type enabled them to define the conditions in which it is possible to stabilize this background and to reduce it to about 10-14 A/cm2, for a uniform electric field of 8000 V/cm. Under irradiation with alpha or gamma rays, and at laboratory temperature, the current which passes through the chamber is a linear function of the applied electric field, up to a critical field value which is a function of the degree of purity of the liquid. Above that critical value, a process of ion-multiplication takes place, somewhat, similar to that which takes place in gases. The change in the ionization current then becomes exponential. In that area of multiplication the authors detected impulses created by the passage of individual alpha particles. The low mobility of the ions in the hexane and their extensive recombination considerably limits the amplitude of the impulses, which can easily be confused with the amplifier's background if a certain number of precautions are not taken. Impulses were recorded with amplitudes varying between 2.5 x 10-5 and 25 x 10-5 V, and with growth-times between 2 and 20 μs in electric fields of 21600 to 65600 V/cm. A number of preliminary results for other liquid fillings are given. (author)

  13. Survival rate of salmonella on cooked pig ear pet treats at refrigerated and ambient temperature storage.

    Science.gov (United States)

    Taormina, Peter J

    2014-01-01

    Pet treats, including pig ears, have been implicated as vehicles of human salmonellosis, and Salmonella has been isolated on commercially produced pig ears. Therefore, behavior of the pathogen on this very low water activity (aw) pet treat is of interest. The survival of Salmonella serotypes Newport and Typhimurium DT104 was measured on natural (aw 0.256) and smoked (aw 0.306) pig ear pet treat products inoculated at ca. 6.5 log CFU per sample and stored at 4.4 or 22°C for 365 days. Surviving populations of Salmonella were enumerated periodically, and a modified Weibull model was used to fit the inactivation curves for log populations. After 14 days, the decline of Salmonella was significantly (P 4.5 log for each combination of serotype and pig ear type at 22°C but remained detectable by enrichment. The model parameter for days to first decimal reduction of Salmonella on pig ears was two to three times higher at 4.4°C compared with 22°C, demonstrating that Salmonella slowly declines on very low aw refrigerated pet treats and more rapidly at room temperature. This information may be useful for pet treat safety assessments. PMID:24405998

  14. Hydration products of lime-metakaolin pastes at ambient temperature with ageing

    Energy Technology Data Exchange (ETDEWEB)

    Gameiro, A., E-mail: agameiro@lnec.pt [National Laboratory of Civil Engineering, Materials Department, Av. do Brasil, 101, 1700 Lisbon (Portugal); Santos Silva, A., E-mail: ssilva@lnec.pt [National Laboratory of Civil Engineering, Materials Department, Av. do Brasil, 101, 1700 Lisbon (Portugal); Veiga, R., E-mail: rveiga@lnec.pt [National Laboratory of Civil Engineering, Buildings Department, Av. do Brasil, 101, 1700 Lisbon (Portugal); Velosa, A., E-mail: avelosa@ua.pt [Department of Civil Engineering, Geobiotec, University of Aveiro, Campus Universitario de Santiago, 3810-193 Aveiro (Portugal)

    2012-05-10

    Highlights: Black-Right-Pointing-Pointer We study the compounds formed in lime/MK blended pastes and their stability over time. Black-Right-Pointing-Pointer Different mixes of lime/MK pastes show different reaction kinetics during curing time, being the pozzolanic compounds formed directly proportional to the lime by MK replacement. Black-Right-Pointing-Pointer Some pozzolanic products are found to be unstable during the hydration reaction employed in our study. - Abstract: Mortars constituted of lime mixtures with pozzolanic additions have been extensively used in the past for the construction of historic and traditional buildings. This paper presents the results of blended pastes of lime and metakaolin (MK), namely compounds formed and their stability over time. This research is part of an extensive study aiming at the formulation of lime based mortars for restoration purposes. It has been shown for several years that MK has been applied in inorganic binders due to its capacity to react vigorously with calcium hydroxide (CH). In the presence of water originating a series of major hydrated phases, namely tetra calcium aluminate hydrate (C{sub 4}AH{sub 13}), calcium silicates hydrates (CSH) and calcium aluminium silicate hydrates (stratlingite - C{sub 2}ASH{sub 8}). Several blended pastes of lime and MK, with different substitution rates of lime by MK (wt%) were prepared and cured at a temperature of 20 Degree-Sign C and relative humidity RH > 95%. The phase composition of the formed hydrated phases was determined by X-ray diffraction (XRD) and simultaneous thermal analysis (TG-DTA). The obtained results showed that lime/MK pastes compositions displayed different reaction kinetics during curing time, being the pozzolanic products content directly proportional to the substitution rate of lime by MK. Also, a relationship between the increase stratlingite content and the MK substitution rate of lime by MK was found.

  15. A moderate increase in ambient temperature modulates the Atlantic cod (Gadus morhua spleen transcriptome response to intraperitoneal viral mimic injection

    Directory of Open Access Journals (Sweden)

    Hori Tiago S

    2012-08-01

    pIC at 10°C vs. 16°C at 6HPI. These results substantially increase our understanding of the genes and molecular pathways involved in the negative impacts of elevated ambient temperature on fish health, and may also be valuable to our understanding of how accelerated global climate change could impact cold-water marine finfish species.

  16. The influence of the starvation-predation trade-off on the relationship between ambient temperature and body size among endotherms

    NARCIS (Netherlands)

    McNamara, John M.; Higginson, Andrew D.; Verhulst, Simon

    2016-01-01

    Aim: The tendency for animals at higher latitudes to be larger (Bergmann's rule) is generally explained by recourse to latitudinal effects on ambient temperature and the food supply, but these receive only mixed support and do not explain observations of the inverse to Bergmann's rule. Our aim was t

  17. Using wireless rumen sensors for evaluating the effects of diet and ambient temperature in nonlactating dairy goats.

    Science.gov (United States)

    Castro-Costa, A; Salama, A A K; Moll, X; Aguiló, J; Caja, G

    2015-07-01

    Sixteen Murciano-Granadina dairy goats, provided with wireless rumen sensors for pH and temperature, were used to assess the rumen environment variations produced by extreme forage to concentrate diets (experiment 1) and climatic conditions (experiment 2). To avoid the interference of feed intake, goats were fed at maintenance level. Rumen sensors were inserted by surgery and programmed to collect and store rumen pH and temperature every 30min. In experiment 1, 8 dry goats (38.6±2.3kg of body weight) in tiestalls were divided into 2 groups and fed at maintenance level with 2 diets varying in forage-to-concentrate ratio [high forage (HF) 70:30; low forage (LF) 30:70] according to a crossover design. Diets were offered once daily for 4h and tap water (4 L, 9.8±0.4°C) was offered for only 30min at 6h after feeding. Rectal temperatures were recorded 3 times during the day. Rumen pH fell immediately after feeding, reaching a nadir depending on the diet (HF=6.35±0.07 at 11h after feeding; LF=6.07±0.07 at 6h after feeding) and being on average greater (0.31±0.06) in HF than LF goats. No diet effects were detected in rectal (38.2±0.1°C) and ruminal (38.9±0.1°C) mean temperatures, which were positively correlated. Rumen temperature dramatically changed by feeding (1.4±0.1°C) and drinking (-3.4±0.1°C), and 2h were necessary to return to the fasting value (38.2±0.1°C). In experiment 2, 8 dry goats (43.9±1.0kg of body weight) were kept in metabolic cages, fed a 50:50 diet and exposed to 2 climatic conditions following a crossover design. Conditions were thermoneutral (TN; 20 to 23°C day-night) and heat stress (HS; 12-h day at 37°C and 12-h night at 30°C). Humidity (40±5%) and photoperiod (light-dark, 12-12h) were similar. Goats were fed at maintenance level, the feed being offered once daily and water at ambient temperature was freely available. Intake, rectal temperature, and respiratory rate were recorded 3 times daily. Despite no differing in dry matter

  18. Effects of ambient temperature and oxygen concentration on diesel spray combustion using a single-nozzle injector in a constant volume combustion chamber

    KAUST Repository

    Jing, Wei

    2013-09-02

    This work investigates the effects of ambient conditions on diesel spray combustion in an optically accessible, constant volume chamber using a single-nozzle fuel injector. The ambient O2 concentration was varied between five discrete values from 10% to 21% and three different ambient temperatures (800 K, 1000 K, and 1200 K). These conditions simulate different exhaust gas recirculation (EGR) levels and ambient temperatures in diesel engines. Both conventional diesel combustion and low temperature combustion (LTC) modes were observed under these conditions. A transient analysis and a quasi-steady state analysis are employed in this article. The transient analysis focuses on the flame development from beginning to the end, illustrating how the flame structure changes during this process; the quasi-steady state analysis focuses on the stable flame structure. The transient analysis was conducted using high-speed imaging of both OH* chemiluminescence and natural luminosity (NL). In addition, three different images were acquired using an ICCD camera, corresponding to OH* chemiluminescence, narrow-band flame emission at 430 nm (Band A) and at 470 nm (Band B), and were used to investigate the quasi-steady state combustion process. From the transient analysis, it was found that the NL signal becomes stronger and confined to narrow regions when the temperature and O2 concentration increase during the development of flame. The OH* intensity is much lower for the 10% ambient O2 and 800 K conditions compared to the higher temperatures and O2 levels. This implies the occurrence of LTC under these conditions. Results from the quasi-steady combustion stage indicate that high-temperature reactions effectively oxidize the soot in the downstream locations where only OH* signal is observed. In addition, an area was calculated for each spectral region, and results show that the area of Band A and Band B emissions in these images is larger than the area of OH* emissions at the lower O2

  19. Ambient temperature effects on the extrinsic incubation period of Wuchereria bancrofti in Aedes polynesiensis : implications for filariasis transmission dynamics and distribution in French Polynesia

    OpenAIRE

    Lardeux, Frédéric; Cheffort, J.

    2001-01-01

    Temperature effects on development of the human filarial parasite #Wuchereria bancrofti$ (Cobbold) (Filaridea : Onchocercidae) in the main Pacific vector #Aedes polynesiensis$ Marks (Diptera : Culicidae) are analysed in relation to ambient climatic conditions. A statistical model of the extrinsic cycle duration as a function of temperature is described and used to distinguish three patterns of #W. bancrofti$ transmission dynamics : continuous, fluctuating and discontinuous, occurring from nor...

  20. In Situ Ambient Pressure X-ray Photoelectron Spectroscopy of Cobalt Perovskite Surfaces under Cathodic Polarization at High Temperatures

    KAUST Repository

    Crumlin, Ethan J.

    2013-08-08

    Heterostructured oxide interfaces have demonstrated enhanced oxygen reduction reaction rates at elevated temperatures (∼500-800 C); however, the physical origin underlying this enhancement is not well understood. By using synchrotron-based in situ ambient pressure X-ray photoelectron spectroscopy (APXPS), we focus on understanding the surface electronic structure, elemental composition, and chemical nature of epitaxial La0.8Sr 0.2CoO3-δ (LSC113), (La 0.5Sr0.5)2CoO4±δ (LSC214), and LSC214-decorated LSC113 (LSC 113/214) thin films as a function of applied electrical potentials (0 to -800 mV) at 520 C and p(O2) of 1 × 10-3 atm. Shifts in the top of the valence band binding energy and changes in the Sr 3d and O 1s spectral components under applied bias reveal key differences among the film chemistries, most notably in the degree of Sr segregation to the surface and quantity of active oxygen sites in the perovskite termination layer. These differences help to identify important factors governing the enhanced activity of oxygen electrocatalysis observed for the LSC113/214 heterostructured surface. © 2013 American Chemical Society.

  1. Antioxidant activity of date palm fruit (phoenix dactylifra L.) extract for oxidative stabilisation of butter oil at ambient temperature

    International Nuclear Information System (INIS)

    In this study, long term preservation of butter oil was achieved through ethanolic extract of date palm fruit (Phoenix dactylifera L.). Butter oil was supplemented with date palm fruit extract (DPFE) at three different concentrations i.e. 250, 500 and 750 ppm (T 1, T/sub 2/ and T/sub 3/) and compared with a control. Total phenolic content, DPPH free radical scavenging activity and inhibition of linoleic acid peroxidation of the DPFE was 5.19 GAE, 74.2 and 81%, respectively. IC/sub 50/ value of date extract for the inhibition of DPPH and linoleic acid peroxidation was 2.45 and 0.82 mg/mL, respectively. The loss of oleic acid and linoleic acid in control after six months of storage was 16 and 52% as compared to T/sub 3/ which was 4% and 14%.T/sub 3/ yielded the lowest concentration of primary and secondary oxidation products with no effect on sensory attributes. DPFE can be used to enhance the shelf life of butter oil at ambient temperature. (author)

  2. Performance of a completely autotrophic nitrogen removal over nitrite process for treating wastewater with different substrates at ambient temperature

    Institute of Scientific and Technical Information of China (English)

    Xiaoyan Chang; Dong Li; Yuhai Liang; Zhuo Yang; Shaoming Cui; Tao Liu; Huiping Zeng

    2013-01-01

    The stability and parameters of a bio-ceramic filter for completely autotrophic nitrogen removal were investigated.The completely autotrophic nitrogen removal over nitrite (CANON) reactor was fed with different concentrations of ammonia (400,300,and 200 mg N/L) but constant influent ammonia load.The results showed that the CANON system can achieve good treatment performance at ambient temperature (15-23℃).The average removal rate and removal loading of NH4 +-N and TN was 83.90%,1.26 kg N/(m3.day),and 70.14%,1.09 kg N/(m3.day),respectively.Among the influencing factors like pH,dissolved oxygen and alkalinity,it was indicated that the pH was the key parameter of the performance of the CANON system.Observing the variation of pH would contribute to better control of the CANON system in an intuitive and fast way.Denaturing gradient gel electrophoresis analysis of microorganisms further revealed that there were some significant changes in the community structure of ammonium oxidizing bacteria,which had low diversity in different stages,while the species of anaerobic ammonium oxidizing (anammox) bacteria were fewer and the community composition was relatively stable.These observations showed that anaerobic ammonia oxidation was more stable than the aerobic ammonia oxidation,which could explain that why the CANON system maintained a good removal efficiency under the changing substrate conditions.

  3. Lithium-functionalized metal-organic frameworks that show >10 wt% H2 uptake at ambient temperature.

    Science.gov (United States)

    Han, Sang Soo; Jung, Dong Hyun; Choi, Seung-Hoon; Heo, Jiyoung

    2013-08-26

    We have used grand canonical Monte Carlo simulations with a first-principles-based force field to show that metal-organic frameworks (MOFs) with Li functional groups (i.e. C-Li bonds) allow for exceptional H2 uptake at ambient temperature. For example, at 298 K and 100 bar, IRMOF-1-4Li shows a total H2 uptake of 5.54 wt% and MOF-200-27Li exhibits a total H2 uptake of 10.30 wt%, which are much higher than the corresponding values with pristine MOFs. Li-functionalized MOF-200 (MOF-200-27Li) shows 11.84 wt% H2 binding at 243 K and 100 bar. These hydrogen-storage capacities exceed the 2015 DOE target of 5.5 wt% H2. Moreover, the incorporation of Li functional groups into MOFs provides more benefits, such as higher delivery amount, for H2 uptake than previously reported Li-doped MOFs.

  4. Chemometric optimization of a low-temperature plasma source design for ambient desorption/ionization mass spectrometry

    International Nuclear Information System (INIS)

    Low-temperature plasmas (LTPs) are attractive sources for atomic and molecular mass spectrometry (MS). In the past, the LTP probe, which was first described by Harper et al., was used successfully for direct molecular mass spectrometric analysis with minimal sample pretreatment in a variety of applications. Unfortunately, the desorption/ionization source itself is commercially not available and custom-built LTP set-ups with varying geometry and operational configurations were utilized in the past. In the present study, a rapid chemometrics approach based on systematic experiments and multivariate data analysis was used to optimize the LTP probe geometry and positioning relative to the atmospheric-pressure inlet of a mass spectrometer. Several parameters were studied including the probe geometry, electrode configuration, quartz tube dimensions, probe positioning and operating conditions. It was found that the plasma-to-MS-inlet distance, the plasma-to-sample-plate distance, and the angle between the latter are very important. Additional effects on the analytical performance were found for the outer electrode width, the positioning of the electrodes, the inner diameter of the quartz tube, the quartz wall thickness, and the gas flow. All experiments were performed using additional heating of the sample to enhance thermal desorption and maximize the signal (T = 150 °C). After software-assisted optimization, attractive detection limits were achieved (e.g., 1.8 × 10−7 mol/L for 4-acetamidothiophenol). Moreover, relative standard deviation (RSD) improved from values of up to 30% before optimization to < 15% RSD after the procedure was completed. This chemometrics approach for method optimization is not limited to LTP-MS and considered to be attractive for other plasma-based instrumentation as well. - Highlights: • Plasmas are useful in ambient desorption/ionization mass spectrometry. • Rapid and direct analysis is performed without sample preparation.

  5. Physiological Effects of Ergot Alkaloid and Indole-Diterpene Consumption on Sheep under Hot and Thermoneutral Ambient Temperature Conditions.

    Science.gov (United States)

    Henry, Michelle L E; Kemp, Stuart; Dunshea, Frank R; Leury, Brian J

    2016-06-02

    A controlled feeding study was undertaken to determine the physiological and production effects of consuming perennial ryegrass alkaloids (fed via seed) under extreme heat in sheep. Twenty-four Merino ewe weaners (6 months; initial BW 30.8 ± 1.0 kg) were selected and the treatment period lasted 21 days following a 14 day acclimatisation period. Two levels of two factors were used. The first factor was alkaloid, fed at a nil (NilAlk) or moderate level (Alk; 80 μg/kg LW ergovaline and 20.5 μg/kg·LW lolitrem B). The second factor was ambient temperature applied at two levels; thermoneutral (TN; constant 21-22 °C) or heat (Heat; 9:00 AM-5:00 PM at 38 °C; 5:00 PM-9:00 AM at 21-22 °C), resulting in four treatments, NilAlk TN, NilAlk Heat, Alk TN and Alk Heat. Alkaloid consumption reduced dry matter intake ( p = 0.008), and tended to reduce liveweight ( p = 0.07). Rectal temperature and respiration rate were increased by both alkaloid and heat ( p < 0.05 for all). Respiration rate increased to severe levels when alkaloid and heat were combined, indicating the short term effects which may be occurring in perennial ryegrass toxicosis (PRGT) areas during severe weather conditions, a novel finding. When alkaloid ingestion and heat were administered separately, similar physiological responses occurred, indicating alkaloid ingestion causes a similar heat stress response to 38 °C heat.

  6. Physiological Effects of Ergot Alkaloid and Indole-Diterpene Consumption on Sheep under Hot and Thermoneutral Ambient Temperature Conditions

    Directory of Open Access Journals (Sweden)

    Michelle L. E. Henry

    2016-06-01

    Full Text Available A controlled feeding study was undertaken to determine the physiological and production effects of consuming perennial ryegrass alkaloids (fed via seed under extreme heat in sheep. Twenty-four Merino ewe weaners (6 months; initial BW 30.8 ± 1.0 kg were selected and the treatment period lasted 21 days following a 14 day acclimatisation period. Two levels of two factors were used. The first factor was alkaloid, fed at a nil (NilAlk or moderate level (Alk; 80 μg/kg LW ergovaline and 20.5 μg/kg·LW lolitrem B. The second factor was ambient temperature applied at two levels; thermoneutral (TN; constant 21–22 °C or heat (Heat; 9:00 AM–5:00 PM at 38 °C; 5:00 PM–9:00 AM at 21–22 °C, resulting in four treatments, NilAlk TN, NilAlk Heat, Alk TN and Alk Heat. Alkaloid consumption reduced dry matter intake ( p = 0.008, and tended to reduce liveweight ( p = 0.07. Rectal temperature and respiration rate were increased by both alkaloid and heat ( p < 0.05 for all. Respiration rate increased to severe levels when alkaloid and heat were combined, indicating the short term effects which may be occurring in perennial ryegrass toxicosis (PRGT areas during severe weather conditions, a novel finding. When alkaloid ingestion and heat were administered separately, similar physiological responses occurred, indicating alkaloid ingestion causes a similar heat stress response to 38 °C heat.

  7. Chemometric optimization of a low-temperature plasma source design for ambient desorption/ionization mass spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Albert, Anastasia [University of Muenster, Institute of Inorganic and Analytical Chemistry, Corrensstraße 30, 48149 Muenster (Germany); Engelhard, Carsten, E-mail: engelhard@chemie.uni-siegen.de [University of Siegen, Department of Chemistry and Biology, Adolf-Reichwein-Straße 2, 57076 Siegen (Germany)

    2015-03-01

    Low-temperature plasmas (LTPs) are attractive sources for atomic and molecular mass spectrometry (MS). In the past, the LTP probe, which was first described by Harper et al., was used successfully for direct molecular mass spectrometric analysis with minimal sample pretreatment in a variety of applications. Unfortunately, the desorption/ionization source itself is commercially not available and custom-built LTP set-ups with varying geometry and operational configurations were utilized in the past. In the present study, a rapid chemometrics approach based on systematic experiments and multivariate data analysis was used to optimize the LTP probe geometry and positioning relative to the atmospheric-pressure inlet of a mass spectrometer. Several parameters were studied including the probe geometry, electrode configuration, quartz tube dimensions, probe positioning and operating conditions. It was found that the plasma-to-MS-inlet distance, the plasma-to-sample-plate distance, and the angle between the latter are very important. Additional effects on the analytical performance were found for the outer electrode width, the positioning of the electrodes, the inner diameter of the quartz tube, the quartz wall thickness, and the gas flow. All experiments were performed using additional heating of the sample to enhance thermal desorption and maximize the signal (T = 150 °C). After software-assisted optimization, attractive detection limits were achieved (e.g., 1.8 × 10{sup −7} mol/L for 4-acetamidothiophenol). Moreover, relative standard deviation (RSD) improved from values of up to 30% before optimization to < 15% RSD after the procedure was completed. This chemometrics approach for method optimization is not limited to LTP-MS and considered to be attractive for other plasma-based instrumentation as well. - Highlights: • Plasmas are useful in ambient desorption/ionization mass spectrometry. • Rapid and direct analysis is performed without sample preparation.

  8. Diurnal variations of airborne pollen concentration and the effect of ambient temperature in three sites of Mexico City

    Science.gov (United States)

    Ríos, B.; Torres-Jardón, R.; Ramírez-Arriaga, E.; Martínez-Bernal, A.; Rosas, I.

    2016-05-01

    Pollen is an important cause of allergic respiratory ailments in the Mexico City Metropolitan Area (MCMA). However, very little is known if ambient air temperature correlates with the early blooming of plants observed in other urban areas around the world. A research study was conducted during the dry season of 2012-2013 at three representative sites of the MCMA with different urban characteristics with the aim to understand the relationships between the profusion and diversity of pollen against temperature and other meteorological variables and degree of urbanization. Pollen samples were collected using a Hirst-type trap sampler in the sites: Merced (highly urbanized), Iztapalapa (medium-high urbanized) and Coyoacan (moderately urbanized). Urbanization levels were determined using a composite index based on population density, proportion of surface covered by construction and asphalt, and urban heat island intensity. A set of representative pollen sampling tapes were assayed under a light microscope at magnification of ×1,000 and converted to grains per cubic meter. The most representative pollen types found in the three sites were, regardless of urbanization levels were: Fraxinus, Cupressaceae/Taxodiaceae, Casuarina, Alnus, Myrtaceae, and Pinus. Total pollen concentration was greatest in the moderately urbanized area, although earlier blooming took place at the highly urbanized zone. Total pollen concentration in the medium-high urbanized site has the lowest because the green areas in this zone of MCMA are few. In a diurnal basis, the most abundant pollen types peaked near midday or in the afternoon evening at the three sites. A Spearman test showed a positive correlation among bihourly pollen concentrations, temperature and relative humidity in all sites, but wind speed just correlated in Iztapalapa and Coyoacan. The results obtained suggest that Urban Heat Island Intensity can disturb flowering periods and pollen concentrations, largely in the highly urbanized

  9. Ferrous sulfate based low temperature synthesis and magnetic properties of nickel ferrite nanostructures

    Energy Technology Data Exchange (ETDEWEB)

    Tejabhiram, Y., E-mail: tejabhiram@gmail.com [Nanotechnology Research Center, SRM University, SRM Nagar, Kattankulathur, Kancheepuram District, TN 603203 (India); Pradeep, R. [Department of Physics and Nanotechnology, SRM University, SRM Nagar, Kattankulathur, Kancheepuram District, TN 603203 (India); Helen, A.T.; Gopalakrishnan, C. [Nanotechnology Research Center, SRM University, SRM Nagar, Kattankulathur, Kancheepuram District, TN 603203 (India); Ramasamy, C. [Department of Pharmacy Practice, SRM University, SRM Nagar, Kattankulathur, Kancheepuram District, TN 603203 (India)

    2014-12-15

    Highlights: • Novel low temperature synthesis of nickel ferrite nanoparticles. • Comparison with two conventional synthesis techniques including hydrothermal method. • XRD results confirm the formation of crystalline nickel ferrites at 110 °C. • Superparamagnetic particles with applications in drug delivery and hyperthermia. • Magnetic properties superior to conventional methods found in new process. - Abstract: We report a simple, low temperature and surfactant free co-precipitation method for the preparation of nickel ferrite nanostructures using ferrous sulfate as the iron precursor. The products obtained from this method were compared for their physical properties with nickel ferrites produced through conventional co-precipitation and hydrothermal methods which used ferric nitrate as the iron precursor. X-ray diffraction analysis confirmed the synthesis of single phase inverse spinel nanocrystalline nickel ferrites at temperature as low as 110 °C in the low temperature method. Electron microscopy analysis on the samples revealed the formation of nearly spherical nanostructures in the size range of 20–30 nm which are comparable to other conventional methods. Vibrating sample magnetometer measurements showed the formation of superparamagnetic particles with high magnetic saturation 41.3 emu/g which corresponds well with conventional synthesis methods. The spontaneous synthesis of the nickel ferrite nanoparticles by the low temperature synthesis method was attributed to the presence of 0.808 kJ mol{sup −1} of excess Gibbs free energy due to ferrous sulfate precursor.

  10. Disturbances in pro-oxidant-antioxidant balance after passive body overheating and after exercise in elevated ambient temperatures in athletes and untrained men.

    Directory of Open Access Journals (Sweden)

    Wanda Pilch

    Full Text Available The aim of the study was to investigate pro-oxidant-antioxidant balance in two series of examinations with two types of stressors (exogenous heat and the combined exogenous and endogenous heat in trained and untrained men. The exogenous stressor was provided by Finnish sauna session, whereas the combined stressor was represented by the exercise in elevated ambient temperature. The men from the two groups performed the physical exercise on a cycle ergometer with the load of 53 ± 2% maximal oxygen uptake at the temperature of 33 ± 1 °C and relative humidity of 70% until their rectal temperature rose by 1.2 °C. After a month from completion of the exercise test the subjects participated in a sauna bathing session with the temperature of 96 ± 2 °C, and relative humidity of 16 ± 5%. 15-minutes heating and 2-minute cool-down in a shower with the temperature of 20 °C was repeated until rectal temperature rose by 1.2 °C compared to the initial value. During both series of tests rectal temperature was measured at 5-minute intervals. Before both series of tests and after them body mass was measured and blood samples were taken for biochemical tests. Serum total protein, serum concentration of lipid peroxidation products and serum antioxidants were determined. The athletes were characterized by higher level of antioxidant status and lower concentration of lipid peroxidation products. Physical exercise at elevated ambient temperature caused lower changes in oxidative stress indices compared to sauna bathing. Sauna induced a shift in pro-oxidant-antioxidant balance towards oxidation, which was observed less intensively in the athletes compared to the untrained men. This leads to the conclusion that physical exercise increases tolerance to elevated ambient temperature and oxidative stress.

  11. Correlation of rectal temperature and peripheral temperature from implantable radio-frequency microchips in Holstein steers challenged with lipopolysaccharide under thermoneutral and high ambient temperatures.

    Science.gov (United States)

    Reid, E D; Fried, K; Velasco, J M; Dahl, G E

    2012-12-01

    Early detection of disease can speed treatment, slow spread of disease in a herd, and improve health status of animals. Immune stimulation increases rectal temperature (RT). Injectable radio-frequency implants (RFI) can provide temperature at the site of implantation. The fidelity of peripheral site temperature, determined by RFI, relative to RT is unknown in cattle. We hypothesized that during lipopolysaccharide (LPS) challenge, temperature at 3 peripheral sites would be similar to RT in steers (n = 4; BW 77 ± 2.1 kg). The 3 sites were 1) subcutaneous (SC) at the base of the ear (ET); 2) SC posterior to the poll (PT); and 3) SC beneath the umbilical fold (UT). Steers were housed in controlled temperature (CT) rooms (between 18 and 21°C; n = 2/room). Rectal temperature, ET, PT, and UT were recorded every 8 h daily. On d 7, 21, 22, 36, and 37, RT and RFI were taken every 5 min for 6 h, every 15 min for 3 h, and every 30 min for 15 h. To test RFI during a simulated immune challenge, LPS (E. coli 055:B5) was injected intravenously (i.v.) at 1000 h on d 22 and 37. Basal temperatures (°C) were RT (38.7 ± 0.20), ET (37.1 ± 0.86), PT (36.7 ± 0.57), and UT (36.3 ± 0.97). Rectal temperature increased to 39.9 ± 0.30°C after LPS, but ET, PT, and UT decreased. Heat stress also increases RT, which makes it difficult to identify sick animals using RT. The second hypothesis tested was that ET positively correlates to RT and negatively correlates to RT during LPS under heat stress. Four steers (127 ± 7.3 kg) were housed in CT chambers (n = 2/chamber), implanted with a RFI, and allowed 2 wk to acclimate. One chamber remained at 20°C, the other was increased to 34°C starting at 0800 h for a period of 48 h. The LPS was administered i.v. to all steers at 1000 h on d 2. After a 2-wk recovery at 20°C, the temperature was increased in the other chamber, resulting in a crossover design with each steer serving as its own control. Pearson's correlation coefficients for ET and

  12. Variability of Battery Wear in Light Duty Plug-In Electric Vehicles Subject to Ambient Temperature, Battery Size, and Consumer Usage: Preprint

    Energy Technology Data Exchange (ETDEWEB)

    Wood, E.; Neubauer, J.; Brooker, A. D.; Gonder, J.; Smith, K. A.

    2012-08-01

    Battery wear in plug-in electric vehicles (PEVs) is a complex function of ambient temperature, battery size, and disparate usage. Simulations capturing varying ambient temperature profiles, battery sizes, and driving patterns are of great value to battery and vehicle manufacturers. A predictive battery wear model developed by the National Renewable Energy Laboratory captures the effects of multiple cycling and storage conditions in a representative lithium chemistry. The sensitivity of battery wear rates to ambient conditions, maximum allowable depth-of-discharge, and vehicle miles travelled is explored for two midsize vehicles: a battery electric vehicle (BEV) with a nominal range of 75 mi (121 km) and a plug-in hybrid electric vehicle (PHEV) with a nominal charge-depleting range of 40 mi (64 km). Driving distance distributions represent the variability of vehicle use, both vehicle-to-vehicle and day-to-day. Battery wear over an 8-year period was dominated by ambient conditions for the BEV with capacity fade ranging from 19% to 32% while the PHEV was most sensitive to maximum allowable depth-of-discharge with capacity fade ranging from 16% to 24%. The BEV and PHEV were comparable in terms of petroleum displacement potential after 8 years of service, due to the BEV?s limited utility for accomplishing long trips.

  13. Two-minute synthesis of PbS nanocubes with high yield and good dispersibility at room temperature

    International Nuclear Information System (INIS)

    A novel water/glycerol/polyvinylpyrrolidone (PVP) ternary system is developed to realize the successful growth of PbS nanocubes with a narrow size distribution and sharp facets and edges using a one-step synthesis at room temperature for the first time. The synthesis is very fast, high yield, environment-friendly, and low cost. The product possesses uniform dimensionality, high crystallinity and better dispersibility. After dispersing the nanocubes in water or ethanol, the as-formed colloidal suspensions can maintain excellent stability for more than one year under ambient conditions. Uniform silica layers were successfully coated onto the nanocubes via a modified Stoeber method to enhance their performance for promising applications. Moreover, by soaking the as-prepared PbS/SiO2 core-shell nanocubes in hydrochloric acid aqueous solution, well-resolved cubic SiO2 nanoboxes were obtained. The formation mechanism and the reason for the better dispersibility and excellent stability of the as-obtained nanocubes are also discussed rationally.

  14. Response of the modern lactating sow and progeny to source and level of supplemental dietary fat during high ambient temperatures.

    Science.gov (United States)

    Rosero, D S; van Heugten, E; Odle, J; Arellano, C; Boyd, R D

    2012-08-01

    The objective of this study was to determine the response to increments of 2 sources of dietary fat on lactating sow and progeny performance during high ambient temperatures. Data were collected from 391 sows (PIC Camborough) from June to September in a 2,600-sow commercial unit in Oklahoma. Sows were randomly assigned to a 2 × 3 factorial arrangement of treatments and a control diet. Factors included 1) fat sources, animal-vegetable blend (A-V) and choice white grease (CWG), and 2) fat levels (2%, 4%, and 6%). The A-V blend contained 14.5% FFA with an iodine value of 89, peroxide value of 4.2 mEq/kg, and anisidine value of 23, whereas CWG contained 3.7% FFA with an iodine value of 62, peroxide value of 9.8 mEq/kg, and anisidine value of 5. Diets were corn-soybean meal based, with 8.0% distillers dried grains with solubles and 6.0% wheat middlings, and contained 3.56-g standardized ileal digestible Lys/Mcal ME. Sows were balanced by parity, with 192 and 199 sows representing parity 1 and parity 3 to 5, respectively. Feed refusal increased linearly (P feed and energy intake increased linearly (P Sows fed CWG diets had reduced (linear, P sow and litter gain relative to feed intake) compared with the G:F of sows fed the control diet or the diets containing the A-V blend (0.50, 0.43, and 0.44, respectively; P feed efficiency than CWG. Subsequent litter size and reproductive performance was improved by inclusion of both sources of fat in diets fed to lactating sows.

  15. Degradation of phenol in an upflow anaerobic sludge blanket(UASB) reactor at ambient temperatureKE

    Institute of Scientific and Technical Information of China (English)

    KE Shui-zhou1; SHI Zhou; ZHANG Tong; Herbert H. P. FANG

    2004-01-01

    A synthetic wastewater containing phenol as sole substrate was treated in a 2.8 L upflow anaerobic sludge blanket(UASB) reactor at ambient temperature. The operation conditions and phenol removal efficiency were discussed, microbial population in the UASB sludge was identified based on DNA cloning, and pathway of anaerobic phenol degradation was proposed. Phenol in wastewater was degraded in an UASB reactor at loading rate up to 18 gCOD/(L·d), With a 1:1 recycle ratio, at 26(1℃, pH 7.0-7.5. An UASB reactor was able to remove 99% of phenol up to 1226 mg/L in wastewater with 24 h of hydraulic retention time(HRT). For HRT below 24 h, phenol degradation efficiency decreased with HRT, from 95.4% at 16 h to 93.8% at 12 h. It further deteriorated to 88.5% when HRT reached 8 h. When the concentration of influent phenol of the reactor was 1260 mg/L(corresponding COD 3000 mg/L), with the HRT decreasing(from 40 h to 4 h, corresponding COD loading increasing), the biomass yields tended to increase from 0.265 to 3.08 g/(L·d). While at 12 h of HRT, the biomass yield was lower. When HRT was 12 h, the methane yield was 0.308 L/(gCOD removed), which was the highest. Throughout the study, phenol was the sole organic substrate. The effluent contained only residual phenol without any detectable intermediates, such as benzoate, 4-hydrobenzoate or volatile fatty acids(VFAs). Based on DNA cloning analysis, the sludge was composed of five groups of microorganisms. Desulfotomaculum and Clostridium were likely responsible for the conversion of phenol to benzoate, which was further degraded by Syntrophus to acetate and H2/CO2. Methanogens lastly converted acetate and H2/CO2 to methane. The role of epsilon-Proteobacteria was, however, unsure.

  16. Effects of ambient temperature, feather cover, and housing system on energy partitioning and performance in laying hens.

    Science.gov (United States)

    van Krimpen, M M; Binnendijk, G P; van den Anker, I; Heetkamp, M J W; Kwakkel, R P; van den Brand, H

    2014-11-01

    Environmental factors, such as ambient temperature (T), feather cover (FC), and housing system (HS), probably affect energy requirements of laying hens. Using a 3 × 2 × 2 factorial arrangement, interaction effects of T (11, 16, and 21°C), FC (100 and 50%), and HS (cage and floor housing) on energy partitioning and performance of laying hens were investigated. Six batches of 70 H&N Brown Nick laying hens, divided over 2 respiration chambers, were exposed to the T levels in three 2-wk periods. Heat production (HP) was determined by indirect calorimetry. The ME intake was calculated by subtracting energy in manure/litter from that in feed and wood shavings. The NE was calculated by subtracting HP from ME. The ME intake increased by 1% for each degree reduction in T. In hens with intact plumage, HP was not affected by T, whereas at decreasing T, HP increased in hens with 50% FC (P cages (P cages compared to the floor system (P cages, 24.7% of NE for production was spent on body fat deposition, whereas in the floor system, 9.0% of NE for production was released from body fat reserves. The ME intake was predicted by the equation (R(2) = 0.74) ME intake (kJ/d) = 612 BW(0.75) - (8.54 × T) + (28.36 × ADG) + (10.43 × egg mass) - (0.972 × FC). Hen performances were not affected by treatments, indicating the adaptive capacity of young laying hens to a broad range of environmental conditions. PMID:25349350

  17. Correlation of rectal temperature and peripheral temperature from implantable radio-frequency microchips in Holstein steers challenged with lipopolysaccharide under thermoneutral and high ambient temperatures.

    Science.gov (United States)

    Reid, E D; Fried, K; Velasco, J M; Dahl, G E

    2012-12-01

    Early detection of disease can speed treatment, slow spread of disease in a herd, and improve health status of animals. Immune stimulation increases rectal temperature (RT). Injectable radio-frequency implants (RFI) can provide temperature at the site of implantation. The fidelity of peripheral site temperature, determined by RFI, relative to RT is unknown in cattle. We hypothesized that during lipopolysaccharide (LPS) challenge, temperature at 3 peripheral sites would be similar to RT in steers (n = 4; BW 77 ± 2.1 kg). The 3 sites were 1) subcutaneous (SC) at the base of the ear (ET); 2) SC posterior to the poll (PT); and 3) SC beneath the umbilical fold (UT). Steers were housed in controlled temperature (CT) rooms (between 18 and 21°C; n = 2/room). Rectal temperature, ET, PT, and UT were recorded every 8 h daily. On d 7, 21, 22, 36, and 37, RT and RFI were taken every 5 min for 6 h, every 15 min for 3 h, and every 30 min for 15 h. To test RFI during a simulated immune challenge, LPS (E. coli 055:B5) was injected intravenously (i.v.) at 1000 h on d 22 and 37. Basal temperatures (°C) were RT (38.7 ± 0.20), ET (37.1 ± 0.86), PT (36.7 ± 0.57), and UT (36.3 ± 0.97). Rectal temperature increased to 39.9 ± 0.30°C after LPS, but ET, PT, and UT decreased. Heat stress also increases RT, which makes it difficult to identify sick animals using RT. The second hypothesis tested was that ET positively correlates to RT and negatively correlates to RT during LPS under heat stress. Four steers (127 ± 7.3 kg) were housed in CT chambers (n = 2/chamber), implanted with a RFI, and allowed 2 wk to acclimate. One chamber remained at 20°C, the other was increased to 34°C starting at 0800 h for a period of 48 h. The LPS was administered i.v. to all steers at 1000 h on d 2. After a 2-wk recovery at 20°C, the temperature was increased in the other chamber, resulting in a crossover design with each steer serving as its own control. Pearson's correlation coefficients for ET and

  18. Ambient and elevated temperature fracture and cyclic-fatigue properties in a series of Al-containing silicon carbides

    Energy Technology Data Exchange (ETDEWEB)

    Yuan, Rong [Univ. of California, Berkeley, CA (United States)

    2004-01-01

    A series of in situ toughened, Al, B and C containing, silicon carbide ceramics (ABC-SiC) has been examined with Al contents varying from 3 to 7 wt%. With increasing Al additions, the grain morphology in the as-processed microstructures varied from elongated to bimodal to equiaxed, with a change in the nature of the grain-boundary film from amorphous to partially crystalline to fully crystalline. Fracture toughness and cyclic fatigue tests on these microstructures revealed that although the 7 wt.% Al containing material (7ABC) was extremely brittle, the 3 and particularly 5 wt.% Al materials (3ABC and 5ABC, respectively) displayed excellent crack-growth resistance at both ambient (25°C) and elevated (1300 C) temperatures. Indeed, no evidence of creep damage, in the form of grain-boundary cavitation, was seen at temperatures at 1300°C or below. The enhanced toughness of the higher Al-containing materials was associated with extensive crack bridging from both interlocking grains (in 3ABC) and uncracked ligaments (in 5ABC); in contrast, the 7ABC SiC showed no such bridging, concomitant with a marked reduction in the volume fraction of elongated grains. Mechanistically, cyclic fatigue-crack growth in 3ABC and 5ABC SiC involved the progressive degradation of such bridging ligaments in the crack wake, with the difference in the degree of elastic vs. frictional bridging affecting the slope, i.e., Paris law exponent, of the crack-growth curve. In addition an investigation of fracture resistance in non-transforming ceramics toughened by grain bridging mechanism is presented using linear elastic fracture mechanics (LEFM). Linear superposition theorems are used for the superposition of crack opening displacements, as well as stress intensity factors, resulting from the external tractions and the internal compressive bridging stresses. Specifically weight functions are used to relate the CODs, stress intensity factors, and tractions and the bridging stress. Expressions are

  19. Experimental study on the effect of ambient temperature on ready-mix concrete strength. Part 2: Industrial implementation

    Directory of Open Access Journals (Sweden)

    Puig Montraveta, J.

    2010-06-01

    Full Text Available This paper is the second part of an experimental study about the effect of environmental temperature on the concrete performance, from an industrial perspective. An earlier article on its effect on aggregate, paste, mortar and concrete workability and mechanical properties reported that high temperature had a clearly adverse impact on strength, which can generally be offset with overdoses of both cement and water to maintain the original water/cement ratio. In this second part of the paper the basis of a methodological formulation is presented, with the purpose of carry out the optimization of the overdosage of cement in concrete in hot climates, in order to be industrially implemented in ready mix concrete plants. This proposal has been successfully applied in some ready mix concrete plants of the company Promotora Mediterránea 2, S.A. (PROMSA, considering that the cement content (overdosage in concrete can be optimized without any adverse effect in its performance, reason why it is possible to reduce the production costs of concrete without reducing its quality.

    El presente artículo constituye la segunda parte de un estudio experimental sobre la influencia de la temperatura ambiental sobre las prestaciones del hormigón, desde una perspectiva industrial. En la primera, se estudió el efecto sobre las propiedades de trabajabilidad y mecánicas, en áridos, pasta, mortero y hormigones, detectando un claro efecto negativo de la temperatura elevada sobre la resistencia, que se suele solucionarcon una sobredosificación en cemento y agua, para mantenerla relación agua/cemento original.En esta segunda parte del artículo, se presentan las bases de una formulación metodológica para llevar a cabo la optimización de la sobredosificación de cemento en el hormigón en climas cálidos, para ser implementada industrialmente en plantas de hormigón preparado. Dicha propuesta se ha aplicado con éxito a escala industrial en plantas de producci

  20. The effects of fabric for sleepwear and bedding on sleep at ambient temperatures of 17°C and 22°C

    OpenAIRE

    Shin, Mirim

    2016-01-01

    Mirim Shin,1 Mark Halaki,1 Paul Swan,2 Angus Ireland,2 Chin Moi Chow1 1Exercise, Health and Performance Research Group, Faculty of Health Sciences, The University of Sydney, Lidcombe, 2Australian Wool Innovation Limited, The Woolmark Company, Sydney, NSW, Australia Abstract: The fibers used in clothing and bedding have different thermal properties. This study aimed to investigate the influences of textile fabrics on sleep under different ambient temperature (Ta) conditions. Seventeen healthy ...

  1. α-Bromodiazoacetamides – a new class of diazo compounds for catalyst-free, ambient temperature intramolecular C–H insertion reactions

    Directory of Open Access Journals (Sweden)

    Åsmund Kaupang

    2013-07-01

    Full Text Available In this work, we introduce a new class of halodiazocarbonyl compounds, α-halodiazoacetamides, which through a metal-free, ambient-temperature thermolysis perform intramolecular C–H insertions to produce α-halo-β-lactams. When carried out with α-bromodiazoacetamides bearing cyclic side chains, the thermolysis reaction affords bicyclic α-halo-β-lactams, in some cases in excellent yields, depending on the ring size and substitution pattern of the cyclic amide side chains.

  2. Effect of Dietary L-ascorbic Acid (L-AA) on Production Performance, Egg Quality Traits and Fertility in Japanese Quail (Coturnix japonica) at Low Ambient Temperature

    OpenAIRE

    Shit, N.; Singh, R P; Sastry, K. V. H.; Agarwal, R.; Singh, R.; Pandey, N K; J Mohan

    2012-01-01

    Environmental stress boosts the levels of stress hormones and accelerates energy expenditure which subsequently imbalance the body’s homeostasis. L-ascorbic acid (L-AA) has been recognized to mitigate the negative impact of environmental stress on production performances in birds. The present investigation was carried out to elucidate the effect of different dietary levels of L-AA on production performance, egg quality traits and fertility in Japanese quail at low ambient temperature. Sixty m...

  3. The effects of fabric for sleepwear and bedding on sleep at ambient temperatures of 17°C and 22°C

    OpenAIRE

    Shin, Mirim; Halaki, Mark; Swan, Paul; Ireland, Angus H; Chow, Chin Moi

    2016-01-01

    The fibers used in clothing and bedding have different thermal properties. This study aimed to investigate the influences of textile fabrics on sleep under different ambient temperature (T a) conditions. Seventeen healthy young participants (ten males) underwent nine nights of polysomnography testing including an adaptation night. Participants were randomized to each of the three binary factors: sleepwear (cotton vs wool), bedding (polyester vs wool), and T a (17°C vs 22°C with relative humid...

  4. The effects of fabric for sleepwear and bedding on sleep at ambient temperatures of 17°C and 22°C

    OpenAIRE

    Shin, Mirim

    2016-01-01

    Mirim Shin,1 Mark Halaki,1 Paul Swan,2 Angus Ireland,2 Chin Moi Chow1 1Exercise, Health and Performance Research Group, Faculty of Health Sciences, The University of Sydney, Lidcombe, 2Australian Wool Innovation Limited, The Woolmark Company, Sydney, NSW, Australia Abstract: The fibers used in clothing and bedding have different thermal properties. This study aimed to investigate the influences of textile fabrics on sleep under different ambient temperature (Ta) conditions. Seventeen healthy ...

  5. High-Energy-Low-Temperature Technologies for the Synthesis of Nanoparticles: Microwaves and High Pressure

    Directory of Open Access Journals (Sweden)

    Witold Lojkowski

    2014-11-01

    Full Text Available Microwave Solvothermal Synthesis (MSS is a chemical technology, where apart from possible effects of microwaves on the chemical reaction paths, microwave heating allows the precise planning of a time-temperature schedule, as well as to achieve high super-saturation of the reagents uniformly in the reactor vessel. Thus, MSS is suitable for production of nanoparticles with small grain size distribution and a high degree of crystallinity. A further advantage of the technology is a much lower synthesis temperature than for gas phase, plasma or sol-gel technologies. New reactors have been developed to exploit these advantages of the MSS technology of nanoparticles synthesis and to scale up the production rate. Reactor design and realization has been shown to be decisive and critical for the control of the MSS technology. Examples of oxidic and phosphatic nanoparticles synthesis have been reported.

  6. Microwave-assisted low temperature synthesis of wurtzite ZnS quantum dots

    International Nuclear Information System (INIS)

    In this work we report, for the first time, on microwave assisted synthesis of wurtzite ZnS quantum dots (QDs) in controlled reaction at temperature as low as 150 °C. The synthesis can be done in different microwave absorbing solvents with multisource or single source precursors. The QDs are less than 3 nm in size as characterized by transmission electron microscopy (TEM) using selected area electron diffraction (SAED) patterns to confirm the wurtzite phase of ZnS QDs. The optical properties were investigated by UV–Vis absorption which shows blue shift in absorption compared to bulk wurtzite ZnS due to quantum confinement effects. The photoluminescence (PL) spectra of QDs reveal point defects related emission of ZnS QDs. - Graphical abstract: Microwave assisted synthesis of wurtzite ZnS quantum dots (QDs) have been achieved in controlled reaction at temperature as low as 150 °C. The synthesis was performed in different microwave absorbing solvents with multisource or single source precursors for very short reaction periods due to effective heating with microwaves. Highlights: ► Wurtzite a high temperature phase of ZnS was synthesized at low temperature. ► Low temperature synthesis was possible because of the use of microwave absorbing solvents. ► Capping agent was used to control the size of Quantum Dots. ► Two different systems were developed using single molecular precursor and multisource precursors

  7. Effect of surface machining and cold working on the ambient temperature chloride stress corrosion cracking susceptibility of AISI 304L stainless steel

    International Nuclear Information System (INIS)

    Effect of plastic deformation induced by cold rolling or surface machining on the susceptibility to chloride-induced stress corrosion cracking at ambient temperature of 304L austenitic stainless steel was investigated in this study. The test material was subjected to three treatments: (a) solution annealed, (b) cold rolled and (c) surface machined to induce different levels of strain/stresses in the material. Subsequently constant strained samples were produced as per ASTM G30 for each condition and these were exposed to 1 M HCl at ambient temperature until cracking occurred. Subsequently the cracked samples were characterized using stereo microscopy, optical microscopy and atomic force microscopy to understand the effect of microstructural changes produced by straining on the susceptibility to stress corrosion cracking at ambient temperature. Strained surface produced by machining accelerated the process of crack initiation resulting in densely distributed shallow surface cracks in a very short period of time as compared to solution annealed and cold worked sample. Crack propagation in cold worked sample was along the slip lines and cracking occurred much earlier than in the solution annealed sample.

  8. Milk and Blood Cortisol and T3 Hormones Content and Milk Composition in Buffaloes as a Function of Lactating Number and Ambient Temperature

    International Nuclear Information System (INIS)

    The effect of lactating number and ambient temperature on T3 and cortisol levels in each of milk and blood and milk composition of lactating Water buffaloes was the objective of this study. The experiment was carried out on 72 animals including two periods through 1994. The first was carried out on 36 animals in February where the average of ambient temperature was 17.5 degree, while the second was conducted on another 36 animals in July where the average of ambient temperature was 37.1 degree . In both two periods, the animals were classified according to lactating number into 6 equal groups from the 1st to 6 th lactation number. The data showed that milk yield and T3, either in milk or in blood and milk fat, protein and lactose were significantly lower in July than in February. Whereas the opposite was true with cortisol level either in milk or in blood. Concerning the effect of lactation number, it was observed that milk and blood T3, milk and blood cortisol and milk fat, protein and lactose were affected significantly due to lactation number

  9. Preparation of high temperature superconductor ceramics using cuban reactives. Optimization of the synthesis method

    International Nuclear Information System (INIS)

    Results of the crystallographic characterization of a group of Cuban Products, which are evaluated to be employed in HTSC fabrication are presented in this paper. The first results on the synthesis of HTSC (RBa2Cu307δ, R= Y, La, Nd) using Cuban reactives, are presented. The so called 'solid state reaction method of synthesis' was optimized, obtaining a critical temperature of more than 93 k

  10. Arabian Oryx (Oryx leucoryx) Respond to Increased Ambient Temperatures with a Seasonal Shift in the Timing of Their Daily Inactivity Patterns.

    Science.gov (United States)

    Davimes, Joshua G; Alagaili, Abdulaziz N; Gravett, Nadine; Bertelsen, Mads F; Mohammed, Osama B; Ismail, Khairy; Bennett, Nigel C; Manger, Paul R

    2016-08-01

    The Arabian oryx inhabits an environment where summer ambient temperatures can exceed 40 °C for extended periods of time. While the oryx uses a suite of adaptations that aid survival, the effects of this extreme environment on inactivity are unknown. To determine how the oryx manages inactivity seasonally, we measured the daily rhythm of body temperature and used fine-grain actigraphy, in 10 animals, to reveal when the animals were inactive in relation to ambient temperature and photoperiod. We demonstrate that during the cooler winter months, the oryx was inactive during the cooler parts of the 24-h day (predawn hours), showing a nighttime (nocturnal) inactivity pattern. In contrast, in the warmer summer months, the oryx displayed a bimodal inactivity pattern, with major inactivity bouts (those greater than 1 h) occurring equally during both the coolest part of the night (predawn hours) and the warmest part of the day (afternoon hours). Of note, the timing of the daily rhythm of body temperature did not vary seasonally, although the amplitude did change, leading to a seasonal alteration in the phase relationship between inactivity and the body temperature rhythm. Because during periods of inactivity the oryx were presumably asleep for much of the time, we speculate that the daytime shift in inactivity may allow the oryx to take advantage of the thermoregulatory physiology of sleep, which likely occurs when the animal is inactive for more than 1 h, to mitigate environmentally induced increases in body temperature. PMID:27154303

  11. Characterization and synthesis of carbon aggregates in high temperature environment

    OpenAIRE

    Russo, Carmela

    2013-01-01

    Carbon materials in all its forms, from the natural carbon solid materials, as coal and graphite, to the synthesized carbon materials, as carbon black, pitch fibers, fullerenes, carbon nanotubes, etc,. have been object of many studies regarding their characteristics and behaviour due to their importance in the energy and industrial sectors. Recently, most of the research efforts have been focused on the synthesis of new carbon materials and in particular on their physico-chemical propertie...

  12. CsF mediated rapid condensation of 1,3-cyclohexadione with aromatic aldehydes: Comparative study of conventional heating vs.ambient temperature

    Institute of Scientific and Technical Information of China (English)

    Kamalakar P. Nandre; Vijay S. Patil; Sidhanath V. Bhosale

    2011-01-01

    A mild, efficient and high yielding protocol for the synthesis of 2,2'-arylmethelene dicyclohexane-1,3-dione derivatives at room temperature and 9-aryl-l,8-dihydrooctahydroxanthene at conventional heating using cesium fluoride as a catalyst is reported. The major advantages of this reaction are excellent yield, very short reaction time and use of inexpensive catalyst.

  13. A meta-analysis of the effects of high ambient temperature on growth performance of growing-finishing pigs.

    Science.gov (United States)

    Renaudeau, D; Gourdine, J L; St-Pierre, N R

    2011-07-01

    High ambient temperature (T) is one of the most important climatic factors influencing pig performance. Increased T occurs sporadically during summer heat waves in temperate climates and year round in tropical climates. Results of published experiments assessing the effects of high T on pig performance are surprisingly variable. Thus, a meta-analysis was performed to aggregate our knowledge and attempt to explain differences in the results across studies on the effect of increased T on ADFI and ADG in growing-finishing pigs. Data for ADFI and ADG were extracted from 86 and 80 trials, respectively, from articles published in scientific journals indexed in PubMed, Science Direct, and from proceedings of scientific meetings through November 2009. Data on ADFI and ADG were analyzed using a linear mixed model that included the linear and the quadratic effects of T and BW, and their interactions as continuous, fixed effects variables, and the trial as a random effect factor (i.e., block). In addition, the effects of housing type (2 levels: individual and group housing) and the year of publication (3 levels: 1970 to 1989, 1990 to 1999, and 2000 to 2009) on the intercept and the linear regression term for T (i.e., the slope) were also tested. Results showed that high T had a curvilinear effect on ADFI and ADG and that this effect was more pronounced in heavier pigs. Across T, ADFI was less when pigs were group-housed. The intercept and the regression coefficient (slope) for T were significantly affected by the year of publication. The effect of increased T was greater in more contemporary works, suggesting that modern genotypes could be more sensitive to heat stress than older genotypes of lesser growth potential. In conclusion, pig performance decreases at an accelerating rate as T is increased. The large between-study variability on the effects of high T on pig performance is partially explained by differences in pig BW and to a lesser extent by the year the study was

  14. Low-temperature synthesis of graphene on nickel foil by microwave plasma chemical vapor deposition

    OpenAIRE

    Kim, Y.; Song, W.; Lee, S. Y.; Jeon, C; Jung, W.; Kim, M.; Park, C. -Y.

    2011-01-01

    Microwave plasma chemical vapor deposition (MPCVD) was employed to synthesize high quality centimeter scale graphene film at low temperatures. Monolayer graphene was obtained by varying the gas mixing ratio of hydrogen and methane to 80:1. Using advantages of MPCVD, the synthesis temperature was decreased from 750 °C down to 450 °C. Optical microscopy and Raman mapping images exhibited that a large area monolayer graphene was synthesized regardless of the temperatures. Since the overall trans...

  15. Acclimatization of the Temperature Sensitivity of Ecosystem Respiration: Synthesis of a 5-year Global Change Experiment

    Science.gov (United States)

    Ogle, K.; Ryan, E.; Pendall, E. G.

    2013-12-01

    The loss of carbon from ecosystems (ecosystem respiration, Reco) is a dynamic process and temperature is a key factor governing short- and long-term Reco dynamics. The goal of this study is to evaluate the temperature sensitivity of Reco and to learn how it adjusts to environmental conditions such as temperature and experimental warming. To do this, we synthesized 5 years of Reco data generated by the Prairie Heating and CO2 Enrichment (PHACE) study that was conducted in a semi-arid grassland in southeastern Wyoming. The PHACE experiment consists of 6 treatments involving atmospheric CO2 (ambient, elevated), temperature (ambient, warmed), and soil water (ambient, shallow irrigation, deep irrigation). Thus, PHACE provided a unique opportunity to explore how the temperature response of Reco over daily, weekly, and longer time scales is governed by the experimental treatments and co-occurring environmental variation. We synthesized the Reco data using a semi-mechanistic temperature response model that involves a temperature sensitivity term (Eo) analogous to an energy of activation. We explored how Eo varies in response to the experimental treatments and current and antecedent soil water and temperature within a Bayesian framework that allowed us to incorporate a novel stochastic model for the antecedent variables. For example, antecedent temperature is modeled as a weighted average of past daily temperatures, and we estimated the unknown daily weights that quantify potential lag responses and time-scales over which past temperatures affect Eo. Thus, changes in Eo describe instantaneous responses of Reco to temperature, the antecedent temperature effects describe relatively short-term (days/weeks) acclimatization, and the effects of experimental warming describe longer term (months/years) acclimatization potential of Reco. Our analysis predicted that Eo can vary by a factor of 2 or more over the growing season. Although not significant, the trend was for Eo to be

  16. Theoretical modelling of Staphylococcus aureus growth in a cooked meat product kept at ambient temperature using temperature profiles of selected Mexican cities Modelagem teórica de crescimento de Staphylococcus aureus em um produto à base de carne cozida deixada à temperatura ambiente, usando perfis de temperatura de cidades do México

    Directory of Open Access Journals (Sweden)

    Rosa Baeza

    2009-03-01

    Full Text Available A theoretical model is used to predict the growth of Staphylococcus aureus in a pasteurized meat product kept at ambient temperatures for several hours. For this purpose, the temperature profiles of some cities of Mexico were combined with literature data on the kinetics of S. aureus growth. As shown by theoretical predictions, if the food is kept at ambient temperature, the average daily temperature may not give accurate predictions.Um modelo teórico é utilizado para prever o crescimento de Staphylococcus aureus em um produto à base de carne (pasteurizado deixado por várias horas à temperatura ambiente. Para isso, perfis de temperatura de algumas cidades do México foram combinados com resultados de literatura sobre a cinética de crescimento de S. aureus. Como demonstrado por previsões teóricas, se o alimento é deixado à temperatura ambiente, a utilização da média diária da temperatura pode não dar previsões exatas.

  17. The flavoprotein Tah18-dependent NO synthesis confers high-temperature stress tolerance on yeast cells

    Energy Technology Data Exchange (ETDEWEB)

    Nishimura, Akira; Kawahara, Nobuhiro [Graduate School of Biological Sciences, Nara Institute of Science and Technology, 8916-5 Takayama, Ikoma, Nara 630-0192 (Japan); Takagi, Hiroshi, E-mail: hiro@bs.naist.jp [Graduate School of Biological Sciences, Nara Institute of Science and Technology, 8916-5 Takayama, Ikoma, Nara 630-0192 (Japan)

    2013-01-04

    Highlights: Black-Right-Pointing-Pointer NO is produced from L-arginine in response to elevated temperature in yeast. Black-Right-Pointing-Pointer Tah18 was first identified as the yeast protein involved in NO synthesis. Black-Right-Pointing-Pointer Tah18-dependent NO synthesis confers tolerance to high-temperature on yeast cells. -- Abstract: Nitric oxide (NO) is a ubiquitous signaling molecule involved in the regulation of a large number of cellular functions. In the unicellular eukaryote yeast, NO may be involved in stress response pathways, but its role is poorly understood due to the lack of mammalian NO synthase (NOS) orthologues. Previously, we have proposed the oxidative stress-induced L-arginine synthesis and its physiological role under stress conditions in yeast Saccharomyces cerevisiae. Here, our experimental results indicated that increased conversion of L-proline into L-arginine led to NO production in response to elevated temperature. We also showed that the flavoprotein Tah18, which was previously reported to transfer electrons to the Fe-S cluster protein Dre2, was involved in NO synthesis in yeast. Gene knockdown analysis demonstrated that Tah18-dependent NO synthesis confers high-temperature stress tolerance on yeast cells. As it appears that such a unique cell protection mechanism is specific to yeasts and fungi, it represents a promising target for antifungal activity.

  18. Part 2. Association of daily mortality with ambient air pollution, and effect modification by extremely high temperature in Wuhan, China.

    Science.gov (United States)

    Qian, Zhengmin; He, Qingci; Lin, Hung-Mo; Kong, Lingli; Zhou, Dunjin; Liang, Shengwen; Zhu, Zhichao; Liao, Duanping; Liu, Wenshan; Bentley, Christy M; Dan, Jijun; Wang, Beiwei; Yang, Niannian; Xu, Shuangqing; Gong, Jie; Wei, Hongming; Sun, Huilin; Qin, Zudian

    2010-11-01

    Fewer studies have been published on the association between daily mortality and ambient air pollution in Asia than in the United States and Europe. This study was undertaken in Wuhan, China, to investigate the acute effects of air pollution on mortality with an emphasis on particulate matter (PM*). There were three primary aims: (1) to examine the associations of daily mortality due to all natural causes and daily cause-specific mortality (cardiovascular [CVD], stroke, cardiac [CARD], respiratory [RD], cardiopulmonary [CP], and non-cardiopulmonary [non-CP] causes) with daily mean concentrations (microg/m3) of PM with an aerodynamic diameter--10 pm (PM10), sulfur dioxide (SO2), nitrogen dioxide (NO2), or ozone (O3); (2) to investigate the effect modification of extremely high temperature on the association between air pollution and daily mortality due to all natural causes and daily cause-specific mortality; and (3) to assess the uncertainty of effect estimates caused by the change in International Classification of Disease (ICD) coding of mortality data from Revision 9 (ICD-9) to Revision 10 (ICD-10) code. Wuhan is called an "oven city" in China because of its extremely hot summers (the average daily temperature in July is 37.2 degrees C and maximum daily temperature often exceeds 40 degrees C). Approximately 4.5 million residents live in the core city area of 201 km2, where air pollution levels are higher and ranges are wider than the levels in most cities studied in the published literature. We obtained daily mean levels of PM10, SO2, and NO2 concentrations from five fixed-site air monitoring stations operated by the Wuhan Environmental Monitoring Center (WEMC). O3 data were obtained from two stations, and 8-hour averages, from 10:00 to 18:00, were used. Daily mortality data were obtained from the Wuhan Centres for Disease Prevention and Control (WCDC) during the study period of July 1, 2000, to June 30, 2004. To achieve the first aim, we used a regression of

  19. Ambient temperature deposition of gallium nitride/gallium oxynitride from a deep eutectic electrolyte, under potential control.

    Science.gov (United States)

    Sarkar, Sujoy; Sampath, S

    2016-05-11

    A ternary, ionically conducting, deep eutectic solvent based on acetamide, urea and gallium nitrate is reported for the electrodeposition of gallium nitride/gallium indium nitride under ambient conditions; blue and white light emitting photoluminescent deposits are obtained under potential control. PMID:27074315

  20. Efeito da temperatura ambiental na densidade e ponto de congelamento do leite de cabra Effects of ambiental temperature on density and freezing point of goat's milk

    Directory of Open Access Journals (Sweden)

    L.H.A. BRASIL

    1999-12-01

    14 days each one, during the which, the animals under heat stress were exposed to medium air temperature of 33,87ºC, between 8:00 and 17:00 hs including simulated solar radiation from 10:00 to 15:00 hs. On the second week of each experimental interval, individuality milk samples were collected dairy by morning and afternoon, adding preservative. In the end of the week, the samples of each milking were mixed, forming a composed samples which were effected pH, titratable acidity, density and crioscopic point. The results indicated that the obtained values for density and crioscopic point are compatible with the others authors have found it in other countries. It was verified biggers values for the density on the milk milked in the morning, in relation with the afternoon, being that the unequal interval between the milkings could influenced the results. It’s not observed significal statistic differences for this goat milk propriety in termoneutrality and heat stress conditions. To the crioscopic point it not verified statistical difference between the milk milked by morning and afternoon. There was significal statistic difference between the goat milk in termoneutrality and termic stress conditions, being the medium value bigger to the termoneutrality conditions.

  1. Self propagating high temperature synthesis of metal oxides. Reactions in external magnetic fields

    CERN Document Server

    Aguas, M D

    2001-01-01

    The preparation of metal oxides by Self-Propagating High-Temperature Synthesis is reported. The reactions are started with a point source of ignition; typically a hot wire. A synthesis wave is observed moving out from the point source and reactions terminate in seconds. Products obtained can be classified into ferrites (magnetic applications) and stannates (gas sensing applications). Ferrites were synthesised under variable external magnetic fields. The synthesis wave is hotter in the presence of an external magnetic field for hard ferrite synthesis. For spinel ferrites the opposite was observed. Materials synthesised in the field show differences in their bulk magnetic properties (coercivity and saturation magnetisation), structures and microstructures. Combustion reactions in large fields revealed changes in unit cell volume (shrinkage was observed for hard ferrites while expansion was observed for spinel ferrites). SHS synthesised hard ferrites show two distinct components; one has large grain structure co...

  2. FY07 LDRD Final Report Synthesis under High Pressure and Temperature of New Metal Nitrides

    Energy Technology Data Exchange (ETDEWEB)

    Crowhurst, J C; Sadigh, B; Aberg, D; Zaug, J M; Goncharov, A F

    2008-09-23

    The original aim of this LDRD was to determine with unprecedented precision the melting curve of iron to geophysically relevant pressures. In the course of developing much of the technology and techniques required to obtain this information we have encountered and studied novel chemical reactions some of whose products are stable or metastable under ambient conditions. Specifically we have synthesized nitrides of the platinum group metals including platinum, iridium, and palladium. We have also carried out in depth first principles theoretical investigations into the nature of these materials. We believed that the scientific impact of continuing this work would be greater than that of the original goals of this project. Indeed the work has led to a number of high profile publications with additional publications in preparation. While nitrides of the transition metals are generally of tremendous technological importance, those of the noble metals in particular have enjoyed much experimental and theoretical attention in the very short time since they were first synthesized. The field was and clearly remains open for further study. While the scientific motivation for this research is different from that originally proposed, many of the associated methods in which we have now gained experience are similar or identical. These include use of the diamond anvil cell combined with technologies to generate high temperatures, the in-situ technique of Raman scattering using our purpose-built, state-of-the-art system, analytical techniques for determining the composition of recovered samples such as x-ray photoelectron spectroscopy, and finally synchrotron-based techniques such as x-ray diffraction for structural and equation of state determinations. Close interactions between theorists and experimentalists has and will continue to allow our group to rapidly and reliably interpret complicated results on the structure and dynamics of these compounds and also additional novel

  3. Facile Synthesis of Ferrocenylenones in Free Solvent at Room Temperature

    Institute of Scientific and Technical Information of China (English)

    Shun Jun JI; Shun Yi WANG; Zhi Liang SHEN; Ming Feng ZHOU

    2003-01-01

    The rate of formation of aldol condensation products by being ground acetylferrocene and various aromatic aldehydes without solvent was dramatically enhanced comparing to the conventional methods. The yield is high (84 % - 96 %) at room temperature.

  4. Ambient Space and Ambient Sensation

    DEFF Research Database (Denmark)

    Schmidt, Ulrik

    The ambient is the aesthetic production of the sensation of being surrounded. As a concept, 'ambient' is mostly used in relation to the music genre 'ambient music' and Brian Eno's idea of environmental background music. However, the production of ambient sensations must be regarded as a central...... aspect of the aesthetization of modern culture in general, from architecture, transport and urbanized lifeforms to film, sound art, installation art and digital environments. This presentation will discuss the key aspects of ambient aesthetization, including issues such as objectlessness...

  5. One-Step Instant Synthesis of Protein-Conjugated Quantum Dots at Room Temperature

    OpenAIRE

    Xuewen He; Li Gao; Nan Ma

    2013-01-01

    We present a new general facile strategy for the preparation of protein-functionalized QDs in a single step at ambient conditions. We demonstrated that highly luminescent red to near-infrared (NIR) protein-functionalized QDs could be synthesized at room temperature in one second through a one-pot reaction that proceeds in aqueous solution. Herein protein-functionalized QDs were successfully constructed for a variety of proteins with a wide range of molecular weights and isoelectric points. Th...

  6. Process assessment of small scale low temperature methanol synthesis

    Science.gov (United States)

    Hendriyana, Susanto, Herri; Subagjo

    2015-12-01

    Biomass is a renewable energy resource and has the potential to make a significant impact on domestic fuel supplies. Biomass can be converted to fuel like methanol via several step process. The process can be split into following main steps: biomass preparation, gasification, gas cooling and cleaning, gas shift and methanol synthesis. Untill now these configuration still has a problem like high production cost, catalyst deactivation, economy of scale and a huge energy requirements. These problems become the leading inhibition for biomass conversion to methanol, which should be resolved to move towards the economical. To address these issues, we developed various process and new configurations for methanol synthesis via methyl formate. This configuration combining two reactors: the one reactor for the carbonylation of methanol and CO to form methyl formate, and the second for the hydrogenolysis of methyl formate and H2 to form two molecule of methanol. Four plant process configurations were compared with the biomass basis is 300 ton/day. The first configuration (A) is equipped with a steam reforming process for converting methane to CO and H2 for increasing H2/CO ratio. CO2 removal is necessary to avoid poisoning the catalyst. COSORB process used for the purpose of increasing the partial pressure of CO in the feed gas. The steam reforming process in B configuration is not used with the aim of reducing the number of process equipment, so expect lower investment costs. For C configuration, the steam reforming process and COSORB are not used with the aim of reducing the number of process equipment, so expect lower investment costs. D configuration is almost similar to the configuration A. This configuration difference is in the synthesis of methanol which was held in a single reactor. Carbonylation and hydrogenolysis reactions carried out in the same reactor one. These processes were analyzed in term of technical process, material and energy balance and economic

  7. Process assessment of small scale low temperature methanol synthesis

    Energy Technology Data Exchange (ETDEWEB)

    Hendriyana [Chemical Engineering Department, Faculty of Engineering, Jenderal Achmad Yani Univerity (Indonesia); Chemical Engineering Department, Faculty of Industrial Technology, InstitutTeknologi Bandung (Indonesia); Susanto, Herri, E-mail: herri@che.itb.ac.id; Subagjo [Chemical Engineering Department, Faculty of Industrial Technology, InstitutTeknologi Bandung (Indonesia)

    2015-12-29

    Biomass is a renewable energy resource and has the potential to make a significant impact on domestic fuel supplies. Biomass can be converted to fuel like methanol via several step process. The process can be split into following main steps: biomass preparation, gasification, gas cooling and cleaning, gas shift and methanol synthesis. Untill now these configuration still has a problem like high production cost, catalyst deactivation, economy of scale and a huge energy requirements. These problems become the leading inhibition for biomass conversion to methanol, which should be resolved to move towards the economical. To address these issues, we developed various process and new configurations for methanol synthesis via methyl formate. This configuration combining two reactors: the one reactor for the carbonylation of methanol and CO to form methyl formate, and the second for the hydrogenolysis of methyl formate and H{sub 2} to form two molecule of methanol. Four plant process configurations were compared with the biomass basis is 300 ton/day. The first configuration (A) is equipped with a steam reforming process for converting methane to CO and H{sub 2} for increasing H{sub 2}/CO ratio. CO{sub 2} removal is necessary to avoid poisoning the catalyst. COSORB process used for the purpose of increasing the partial pressure of CO in the feed gas. The steam reforming process in B configuration is not used with the aim of reducing the number of process equipment, so expect lower investment costs. For C configuration, the steam reforming process and COSORB are not used with the aim of reducing the number of process equipment, so expect lower investment costs. D configuration is almost similar to the configuration A. This configuration difference is in the synthesis of methanol which was held in a single reactor. Carbonylation and hydrogenolysis reactions carried out in the same reactor one. These processes were analyzed in term of technical process, material and energy

  8. Physiological responses to temperature and haeme synthesis modifiers in earthworm Lumbricus terrestris (Annelida: Oligochaeta).

    Science.gov (United States)

    Khan, M A Q; Khan, Munawwar Ali; Hurlock, Peter; Ahmed, S A

    2012-01-01

    Earthworms (Lumbricus terrestris) acclimated at 2° and 6°C above their average habitat temperature (10°C) had respectively 15 and 40% higher rate of respiration than those at habitat temperature. At 14°C, the rate of respiration and blood hemoglobin (Hb) concentration both increased by ∼60 and 50%, respectively, of the values at habitat temperature. At higher temperatures the rate of respiration and Hb synthesis started decreasing. At 20-23°C, the respiration and Hb concentration decreased respectively by about 85% and 35% of that at 14°C. Decrease in blood Hb concentration at higher temperatures appeared to be due to the lowering of the activity of blood enzyme δ-aminolaevulinic acid dehydratase (ALAD). Exposure of 20-23°C-acclimated pale worms to ALAD inhibitor (lead), lowered the already compromised rate of respiration and blood Hb concentration; while exposure to hexachlorobenzene (HCB, inducer of haeme synthesis) and ferric chloride (enhancer of haeme synthesis) did not overcome the inhibitory effect of high temperature on Hb synthesis. At 20-23°C the affinity of Hb for oxygen also decreased as indicated by the lowering of oxy-Hb (HbO) concentration in blood. The lowering of concentration of blood Hb and its affinity for oxygen may lower the amount of oxygen delivered to cells, which may limit the level of aerobic metabolism (glycolysis, oxidative phosphorylation), as indicated by an increase in blood glucose concentration and a decrease in in vitro activities of mitochondrial electron transport system components (ETS) namely NADH-cytochrome c reductase, succinate dehydrogenase, cytochrome c oxidase, and ATPases. Although the oxygen concentration in air, at sea level, does not decrease significantly from 6° to 20-23°C (lack of hypoxia), lowering of both Hb and HbO concentrations by high temperature may cause significant hypoxemia. The latter may lead to inhibition of the activity of muscle mitochondrial respiratory enzymes (ETS). The resulting

  9. Low-temperature synthesis of graphene on nickel foil by microwave plasma chemical vapor deposition

    Science.gov (United States)

    Kim, Y.; Song, W.; Lee, S. Y.; Jeon, C.; Jung, W.; Kim, M.; Park, C.-Y.

    2011-06-01

    Microwave plasma chemical vapor deposition (MPCVD) was employed to synthesize high quality centimeter scale graphene film at low temperatures. Monolayer graphene was obtained by varying the gas mixing ratio of hydrogen and methane to 80:1. Using advantages of MPCVD, the synthesis temperature was decreased from 750 °C down to 450 °C. Optical microscopy and Raman mapping images exhibited that a large area monolayer graphene was synthesized regardless of the temperatures. Since the overall transparency of 89% and low sheet resistances ranging from 590 to 1855 Ω/sq of graphene films were achieved at considerably low synthesis temperatures, MPCVD can be adopted in manufacturing future large-area electronic devices based on graphene film.

  10. The synthesis of [2-13C]2-nitropropane at room temperature and at atmospheric pressure

    NARCIS (Netherlands)

    Jacquemijns M; Zomer G

    1990-01-01

    In this report the synthesis of [2-13C]2-nitropropane at room temperature is described. [2-13C]Acetone was converted into the oxime with hydroxy hydrochloridelamine and sodium carbonate. Treatment with hypobromic acid resulted in 2-13C]2-bromo-2-nitropropane. Hydrogenation with sodium borohydride

  11. Room and low temperature synthesis of carbon nanofibres

    CERN Document Server

    Boskovic, B O

    2002-01-01

    Carbon nanotubes and nanofibres have attracted attention in recent years as new materials with a number of very promising potential applications. Carbon nanotubes are potential candidates for field emitters in flat panel displays. Carbon nanofibres could also be used as a hydrogen storage material and as a filling material in polymer composites. Carbon nanotubes are already used as tips in scanning probe microscopy due to their remarkable mechanical and electrical properties, and could be soon used as nanotweezers. Use of carbon nanotubes in nanoelectronics will open further miniaturisation prospects. Temperatures ranging from 450 to 1000 deg C have been a required for catalytic growth of carbon nanotubes and nanofibres. Researchers have been trying to reduce the growth temperatures for decades. Low temperature growth conditions will allow the growth of carbon nanotubes on different substrates, such glass (below 650 deg C) and as plastics (below 150 deg C) over relatively large areas, which is especially suit...

  12. Low Temperature Synthesis of Composition Poros Materials from Mortar Sands

    Science.gov (United States)

    Kazmina, O. V.; Volland, S. N.; Dushkina, M. A.

    2014-08-01

    It is established that the eliminations of construction sand with the content of SiO2 about 70 wt. % and particle size less than 60 μm are suitable for the production of a foamglass-crystal material on the basis of the low-temperature frit, which was synthesized at the temperature 900 °C. The obtained foamglass-crystal material exceeds foamglass (by 3.0 times) and clayite (by 1.5 times) by strength and is characterized by low value of water absorption (0.1 %).

  13. Research on Ambient Adaptability of Temperature Measuring Device for Oil-Immersed Transformer%油浸变压器测温装置的环境适应性研究

    Institute of Scientific and Technical Information of China (English)

    戴缘生; 陕华平; 童在林; 李文

    2012-01-01

    The influencing mechanism of ambient temperature of oil surface thermometer is researched. The method to discern influence degree of ambient temperature of thermometer is presented.%研究了油面温度计的环境温度变化影响机理,提出了一套有效鉴别温度计环境温度影响量水平的方法。

  14. High-Temperature Phase Transitions in CsH2PO4 Under Ambient and High-Pressure Conditions: A Synchrotron X-ray Diffraction Study

    Energy Technology Data Exchange (ETDEWEB)

    Botez,C.; Hermosillo, J.; Zhang, J.; Qian, J.; Zhao, Y.; Majzlan, J.; Chianelli, R.; Pantea, C.

    2007-01-01

    To clarify the microscopic origin of the temperature-induced three-order-of-magnitude jump in the proton conductivity of CsH2PO4 (superprotonic behavior), we have investigated its crystal structure modifications within the 25-300 C temperature range under both ambient- and high-pressure conditions using synchrotron x-ray diffraction. Our high-pressure data show no indication of the thermal decomposition/polymerization at the crystal surface recently proposed as the origin of the enhanced proton conductivity. Instead, we found direct evidence that the superprotonic behavior of the title material is associated with a polymorphic structural transition to a high-temperature cubic phase. Our results are in excellent agreement with previous high-pressure ac impedance measurements.

  15. Synthesis and characterization of flexible thermographic phosphor temperature sensors

    Science.gov (United States)

    Mitchell, Katherine E.; Gardner, Victor; Allison, Stephen W.; Sabri, Firouzeh

    2016-10-01

    The temperature dependence of the emission characteristics of thermographic phosphors has been used extensively for surface temperature measurements of systems where thermal management is critical for the safe operation of the system. The instantaneous, remote, and highly accurate nature of this form of temperature measurement makes it a very attractive measurement technique. However, the destructive nature of depositing phosphors directly onto the surface of interest and the complications of working with fine powders has limited the use of this technique in all areas. This work focuses on the design and characterization of polymer-encapsulated thermographic phosphor flexible sensors for surface temperature assessment. La2O2S:Eu powder was embedded in an elastomeric sleeve at concentrations of 10%, 25%, and 50% wt. and fully characterized. The effect of spin-coating on emission characteristics of La2O2S:Eu was tested and the decay times were compared to results obtained from bulk-doped samples previously created by the authors.

  16. Volume reduction on all particle size of the contaminated soil. Continuous processing technology of attrition, chemical wash under an ambient temperature and pressure condition and magnetic separation

    International Nuclear Information System (INIS)

    An examination was conducted in order to establish a practical purification system that could largely reduce the storage volume of radioactive waste in the Intermediate Storage Facility. The examination consists of a 3-step washing treatment of contaminated soil, which includes “Milling Washing” of removed contaminated soil, chemical extraction of fine soil fraction resulted from the “Milling Washing” under an ambient temperature and pressure condition, and magnetic separation of cesium from the extracted solution. As a result of the examination, we succeeded in development of a safe system with low initial cost and running cost. (author)

  17. Influence of Feeding Enzymatically Hydrolyzed Yeast Cell Wall on Growth Performance and Digestive Function of Feedlot Cattle during Periods of Elevated Ambient Temperature

    OpenAIRE

    Salinas-Chavira, J.; Arzola, C.; González-Vizcarra, V.; Manríquez-Núñez, O. M.; Montaño-Gómez, M. F.; Navarrete-Reyes, J. D.; Raymundo, C.; Zinn, R. A.

    2015-01-01

    In experiment 1, eighty crossbred steers (239±15 kg) were used in a 229-d experiment to evaluate the effects of increasing levels of enzymatically hydrolyzed yeast (EHY) cell wall in diets on growth performance feedlot cattle during periods of elevated ambient temperature. Treatments consisted of steam-flaked corn-based diets supplemented to provide 0, 1, 2, or 3 g EHY/hd/d. There were no effects on growth performance during the initial 139-d period. However, from d 139 to harvest, when 24-h ...

  18. Self-propagating high-temperature synthesis in Ti-W-C system

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    The effects of W content and preheat temperature on combustion temperature, combustion velocity and product components of self-propagating high-temperature synthesis(SHS) in Ti-W-C system were investigated. The results show that with decreasing W content and increasing preheat temperature, the combustion temperature and combustion velocity increases, the SHS reaction becomes complete and the particle size of product increases. There exist two combustion mechanisms. When Ti powder in combustion front was molten by high combustion temperature, SHS product was formed by melt-solution-precipitation mechanism. When the combustion temperature was not high enough to make Ti powder melt in combustion front, the product was formed through diffusion-solution-in-solid-state.

  19. Synthesis of cadmium chalcogenide nanotubes at room temperature

    KAUST Repository

    Pan, Jun

    2012-10-01

    Cadmium chalcogenide (CdE, E=S, Se, Te) polycrystalline nanotubes have been synthesized from precursor of CdS/cadmium thiolate complex at room temperature. The precursor was hydrothermally synthesized at 180 °C using thioglycolic acid (TGA) and cadmium acetate as starting materials. The transformation from the rod-like precursor of CdS/cadmium thiolate complex to CdS, CdSe and CdTe nanotubes were performed under constant stirring at room temperature in aqueous solution containing S 2-, Se 2- and Te 2-, respectively. The nanotube diameter can be controlled from 150 to 400 nm related to the dimension of templates. The XRD patterns show the cadmium chalcogenide nanotubes all corresponding to face-centered cubic structure. © 2012 Elsevier B.V. All rights reserved.

  20. Ambient Sensors

    NARCIS (Netherlands)

    Börner, Dirk; Specht, Marcus

    2014-01-01

    This software sketches comprise two custom-built ambient sensors, i.e. a noise and a movement sensor. Both sensors measure an ambient value and process the values to a color gradient (green > yellow > red). The sensors were built using the Processing 1.5.1 development environment. Available under th

  1. Det ambiente

    DEFF Research Database (Denmark)

    Schmidt, Ulrik

    Om begrebet "det ambiente", der beskriver, hvad der sker, når vi fornemmer baggrundsmusikkens diskrete beats, betragter udsigten gennem panoramavinduet eller tager 3D-brillerne på og læner os tilbage i biografsædet. Bogen analyserer, hvorfan ambiente oplevelser skabes, og hvilke konsekvenser det...

  2. Synthesis of ZnO Nanostructures for Low Temperature CO and UV Sensing

    Directory of Open Access Journals (Sweden)

    Nazar Abbas Shah

    2012-10-01

    Full Text Available In this paper, synthesis and results of the low temperature sensing of carbon monoxide (CO gas and room temperature UV sensors using one dimensional (1-D ZnO nanostructures are presented. Comb-like structures, belts and rods, and needle-shaped nanobelts were synthesized by varying synthesis temperature using a vapor transport method. Needle-like ZnO nanobelts are unique as, according to our knowledge, there is no evidence of such morphology in previous literature. The structural, morphological and optical characterization was carried out using X-ray diffraction, scanning electron microscopy and diffused reflectance spectroscopy techniques. It was observed that the sensing response of comb-like structures for UV light was greater as compared to the other grown structures. Comb-like structure based gas sensors successfully detect CO at 75 °C while other structures did not show any response.

  3. Fabrication of Titanium Diboride-Cu Composite by Self-High Temperature Synthesis plus Quick Press

    Institute of Scientific and Technical Information of China (English)

    Jinyong ZHANG; Zhengyi FU; Weimin WANG

    2005-01-01

    Titanium diboride based composites, good candidates for contact materials, have high hardness, Young's modulus,high temperature stability, and excellent electrical, thermal conductivity. However a good interface of TiB2/Cu is very difficult to achieve for oxidation of TiB2. To avoid this oxidation behavior, the in situ combusting synthesis technology, SHS, was used to prepare TiB2/Cu composite. Thecharacters of Ti-B-xCu SHS were studied in detail,such as combustion temperature, products phases and grain size. Based on the experimental results a proper technology way of self-high temperature synthesis plus quick press (SHS/QP) was determined and compact TiB2/Cu composites with relative density over than 97 pct of the theoretical were fabricated by this method. The properties and microstructures of these TiB2 based composites were also investigated.

  4. Synthesis of MIL-100(Fe at Low Temperature and Atmospheric Pressure

    Directory of Open Access Journals (Sweden)

    Jing Shi

    2013-01-01

    Full Text Available MIL-100(Fe, a mesoporous metal-organic framework (MOF, has a large BET specific surface area and pore volume with the presence of a significant amount of accessible Lewis acid metal sites upon dehydration. The structural characteristics of MIL-100(Fe make it a good candidate for potential applications in gas storage, separation, and heterogeneous catalysis. Mainly, this MOF is obtained by the hydrothermal synthesis in a Teflon-lined autoclave at high temperature (>150°C under static conditions. However, this method has several disadvantages such as high temperature, high (autogenous pressure, long time, and comparable low MOF yield. Therefore, development of a facile method for synthesis of MIL-100(Fe is vitally important for fundamental understanding and practical application. Herein, MIL-100(Fe is synthesized by a facile low-temperature (90% still could be achieved, suggesting that this simple and energy saving method has the potential to be used practically.

  5. The effects of ambient temperature and mixing time of glass ionomer cement material on the survival rate of proximal ART restorations in primary molars

    Directory of Open Access Journals (Sweden)

    Arthur M Kemoli

    2014-01-01

    Full Text Available Objective: Temperature fluctuations and material mixing times are likely to affect the consistency and integrity of the material mixture, and hence the restoration made out of it. The purpose of the present study was to determine the influence of the ambient temperature and the mixing time of glass ionomer cement (GIC restorative material on the survival rate of proximal atraumatic restorative treatment (ART restorations placed in primary molars. Materials and Methods: A total of 804 restorations were placed in the primary molars of 6-8-year-olds using the ART approach. The restorations were then followed for a period of 2 years and evaluated at given intervals. The data collected were analyzed using SPSS computer statistical program, and the results tested and compared using the Chi-square, Kaplan Meier survival analysis and Cox Proportional hazard statistical tests. Results: The cumulative survival rate of the restorations dropped from the initial 94.4% to 30.8% at the end of 2 years. The higher survival rate of the restorations was associated with the experienced operators and assistants when using the rubber dam isolation method. However, there was no statistically significant difference in the survival rate of the restorations when related to the room temperature and the mixing time of the GIC materials used in spite of the variations in the temperature recoded and the methods used in mixing the materials. Conclusion: The ambient temperature and mixing time of GIC did not have a significant effect on the survival of the proximal ART restorations.

  6. Distribuição vertical e horizontal de temperaturas do ar em ambientes protegidos Vertical and horizontal distribution of air temperature in a plastic greenhouse

    Directory of Open Access Journals (Sweden)

    Raquel A. Furlan

    2002-04-01

    Full Text Available Este trabalho foi realizado na área experimental do Departamento de Engenharia Rural da Escola Superior de Agricultura "Luiz de Queiroz", Piracicaba, SP, Brasil, em dois ambientes protegidos construídos no sentido leste-oeste, com área total de 112 m² e coberto com plástico (150 micra, tratado contra raios ultravioleta. Para caracterizar a distribuição espacial da temperatura do ar no ambiente protegido, instalaram-se termopares (cobre-constantã formando malhas, com espaçamento horizontal entre eles de 3,0 m e nas alturas de 0,5, 1,0, 2,0, 3,0 e 4,0 m em relação ao solo. Os dados foram armazenados a cada 15 min por sistemas automáticos de aquisição de dados nos ambientes protegidos. O sistema de nebulização constituiu-se de duas linhas com 70 bocais totais, instalados a uma altura de 3,0 m, utilizando-se uma pressão de trabalho de 200 kPa. A nebulização não afetou o gradiente vertical de temperatura, que manteve a tendência de aumento de temperatura com a altura, em relação ao nível do solo, enquanto o efeito na redução de temperatura pelo sistema de nebulização somente foi eficaz durante a realização da mesma. Para a representação da distribuição espacial de temperatura do ar no ambiente protegido nos diferentes níveis de altura, construiu-se superfícies isotérmicas a partir dos resultados. Verifica-se que a nebulização apresentou maior efeito na homogeneização da distribuição de temperatura no ambiente protegido no nível referente a 2,0 m de altura, em relação ao solo.This work was conducted in the experimental area of the Department of Rural Engineering of "Escola Superior de Agricultura Luiz de Queiroz", University of São Paulo, Piracicaba, São Paulo, Brazil. Two greenhouses were installed in the east-west direction, with 6.4 m of width, 17.5 m of length and 3.0 m high, with total area of 112 m²; covered by plastic of 150 micra thickness, treated against ultra violet rays. To characterize the

  7. Synthesis of fluorophosphate glasses with low melting temperatures

    OpenAIRE

    Leissner, J; Sebastian, K; Roggendorf, Hans; Schmidt, Helmut K.

    1991-01-01

    Fluorophosphate glasses can combine low melting temperatures with a good chemical durability. In order to vary optical properties while retaining other features some new compositions were synthesized and some of their properties were investigated. The glasses were melted at 450°C by using SnO, PbF2, SnF2, NH4H2PO4 and NH4PF6 as raw materials. Metal fluorides like ZrF4 and ZnF2 were introduced, too. The Tg ranges between 87 and 141°C. Preliminary results concerning the transmission spectra in ...

  8. Ambient Dried Aerogels

    Science.gov (United States)

    Jones, Steven M.; Paik, Jong-Ah

    2013-01-01

    A method has been developed for creating aerogel using normal pressure and ambient temperatures. All spacecraft, satellites, and landers require the use of thermal insulation due to the extreme environments encountered in space and on extraterrestrial bodies. Ambient dried aerogels introduce the possibility of using aerogel as thermal insulation in a wide variety of instances where supercritically dried aerogels cannot be used. More specifically, thermoelectric devices can use ambient dried aerogel, where the advantages are in situ production using the cast-in ability of an aerogel. Previously, aerogels required supercritical conditions (high temperature and high pressure) to be dried. Ambient dried aerogels can be dried at room temperature and pressure. This allows many materials, such as plastics and certain metal alloys that cannot survive supercritical conditions, to be directly immersed in liquid aerogel precursor and then encapsulated in the final, dried aerogel. Additionally, the metalized Mylar films that could not survive the previous methods of making aerogels can survive the ambient drying technique, thus making multilayer insulation (MLI) materials possible. This results in lighter insulation material as well. Because this innovation does not require high-temperature or high-pressure drying, ambient dried aerogels are much less expensive to produce. The equipment needed to conduct supercritical drying costs many tens of thousands of dollars, and has associated running expenses for power, pressurized gasses, and maintenance. The ambient drying process also expands the size of the pieces of aerogel that can be made because a high-temperature, high-pressure system typically has internal dimensions of up to 30 cm in diameter and 60 cm in height. In the case of this innovation, the only limitation on the size of the aerogels produced would be in the ability of the solvent in the wet gel to escape from the gel network.

  9. Low-Temperature Synthesis of Superconducting Nanocrystalline MgB2

    Directory of Open Access Journals (Sweden)

    Jun Lu

    2010-01-01

    Full Text Available Magnesium diboride (MgB2 is considered a promising material for practical application in superconducting devices, with a transition temperature near 40 K. In the present paper, nanocrystalline MgB2 with an average particle size of approximately 70 nm is synthesized by reacting LiBH4 with MgH2 at temperatures as low as 450°C. This synthesis approach successfully bypasses the usage of either elemental boron or toxic diborane gas. The superconductivity of the nanostructures is confirmed by magnetization measurements, showing a superconducting critical temperature of 38.7 K.

  10. Apatite-structured compounds: Synthesis and high-temperature investigation

    Energy Technology Data Exchange (ETDEWEB)

    Knyazev, Alexander V.; Chernorukov, Nikolai G. [Nizhny Novgorod State University, Gagarin Prospekt 23/2, 603950 Nizhny Novgorod (Russian Federation); Bulanov, Evgeny N., E-mail: bulanoven@yandex.ru [Nizhny Novgorod State University, Gagarin Prospekt 23/2, 603950 Nizhny Novgorod (Russian Federation)

    2012-02-15

    Highlights: Black-Right-Pointing-Pointer 25 Apatite-structured compounds of different composition were synthesized. Black-Right-Pointing-Pointer Phase transformations of them in wide temperature interval were investigated. Black-Right-Pointing-Pointer For the first time polymorphic transitions were observed on 6 apatites. Black-Right-Pointing-Pointer Thermal expansion coefficients of all studied phases were calculated. Black-Right-Pointing-Pointer The direct communication between thermal stability and expansion anisotropy was observed. - Abstract: The phase transitions and thermal expansion of apatite-structured compounds with the general formula M{sup II}{sub 5}(A{sup V}O{sub 4}){sub 3}L (M{sup II} = Ca, Sr, Cd, Ba, Pb; A{sup V} = P, V, Cr, Mn; L = OH, F, Cl, Br, I) have been studied by high-temperature X-ray diffraction and differential thermal analysis. Polymorphic transition nature was explained on the basis of the structure data. Connection between thermal stability and peculiarities of thermal expansion, which were explained in assumption of composition and structure of apatites was ascertained.

  11. 氧化铁常温脱硫研究综述%A review on studies of ambient temperature ferric oxide desulfurizers

    Institute of Scientific and Technical Information of China (English)

    贺恩云; 樊惠玲; 王小玲; 王龙江; 李叶; 黄冠

    2014-01-01

    氧化铁脱硫剂具有廉价易得,硫容高,再生简单等优点,因而受到广大科研工作者广泛关注。综述了氧化铁常温脱硫及再生原理,脱硫剂的制备,以及脱硫剂表面 pH 值、水含量等工艺参数对氧化铁脱硫性能的影响。并提出γ-Fe2O3是常温脱硫研究的新方向。%Ferric oxide desulfurizers have many advantages, such as cheapness, high sulfur capacity and easy regeneration, so researchers show great interest in the study on them. The principles of ferric oxide ambient temperature desulfurization and regeneration, the preparation of desulfurizers, and the effects of sorbent surface pH value, water content and other parameters on desulfurization performances of ferric oxides were reviewed. And it was proposed that γ-Fe2O3 should be a new direction for the research of ambient temperature desulfurization.

  12. Shelf-life enhancement of fresh ginger rhizomes at ambient temperatures by combination of gamma-irradiation, biocontrol and closed polyethylene bag storage

    International Nuclear Information System (INIS)

    The feasibility of a combination process involving gamma-irradiation, packing in closed polyethylene bags and biological control of fungi causing storage rot was evaluated as a means of extending the shelf-life of fresh ginger rhizomes at ambient temperatures (25–30°C). Storage in closed polyethylene bags reduced weight loss but increased sprouting and rooting, which could be prevented by gamma irradiation to 60 Gy. Rotting caused by Sclerotium rolfsii was, however, a major cause of spoilage during extended storage. Four isolates of Trichoderma sp. isolated from sclerotia of S. rolfsii infecting ginger rhizomes, one of Gliocfadium uirens, and four isolates of fluorescent Pseudomonas were tested, out of which, one isolate of Trichoderma was found to be highly effective in suppressing the growth of S. rolfsii. The efficacy of the antagonist was demonstrated under simulated market conditions using artificially inoculated rhizomes. The recommended procedure consists of dipping washed, air dried rhizomes in Trichoderma suspension (108spores ml-1), air-drying, packing in 250 gauge LDPE bags followed by irradiation to 60 Gy. Rhizomes thus treated remained in good marketable condition for up to 2 months at ambient temperature without sprouting or significant loss of quality and less than 5% weight loss. An in vitro bioassay system was developed to demonstrate the efficacy of the antagonist to protect the cut surface of sliced rhizomes inoculated with the pathogen. The method could be used for rapid screening of antagonists

  13. Corrosion fatigue studies on A533-B, C-Mn and Ducol W30 pressure vessel steels at ambient temperature and pressure in aqueous environments

    International Nuclear Information System (INIS)

    Corrosion fatigue crack growth tests have been performed on three pressure vessel steels, A533-B, Ducol W30 and a C-Mn steel, in simulated water reactor environments at ambient temperature and pressure. A533-B and Ducol W30 had a bainitic, and the C-Mn a ferritic-pearlitic, microstructure- above a cyclic stress intensity level of 25 MN.msup(3/2), crack growth rates are in general greater for the ferritic-pearlitic material. Tests have covered a range of stress ratios and frequencies, there being a strong effect of frequency on growth rates, but a small effect of stress ratio. Examination of several specimen orientations has shown there to be no significant effect of growth rates. Mechanisms of corrosion fatigue have been discussed in the light of features observed on specimen fracture surfaces. The ferritic-pearlitic steel has shown a transition in fracture mode from transgranular quasi-cleavage to intergranular cracking on lowering the cyclic stress intensity, the transition occurring when the plastic zone size at the crack tip became less than four times the grain size. The cleavage mode indicates that this material is susceptible to hydrogen embrittlement in these aqueous environments at ambient temperature. The bainitic steels have not in general shown these fracture modes and appear less susceptible to hydrogen embrittlement. The enhancement of growth rates, above those obtained in air, is controlled by a dissolution mechanism. (author)

  14. Design and development of an ambient-temperature continuously-rotating achromatic half-wave plate for CMB polarization modulation on the POLARBEAR-2 experiment

    CERN Document Server

    Hill, Charles A; Chinone, Yuji; Goeckner-Wald, Neil; Hazumi, Masashi; Keating, Brian; Kusaka, Akito; Lee, Adrian T; Matsuda, Frederick; Plambeck, Richard; Suzuki, Aritoki; Takakura, Satoru

    2016-01-01

    We describe the development of an ambient-temperature continuously-rotating half-wave plate (HWP) for study of the Cosmic Microwave Background (CMB) polarization by the POLARBEAR-2 (PB2) experiment. Rapid polarization modulation suppresses 1/f noise due to unpolarized atmospheric turbulence and improves sensitivity to degree-angular-scale CMB fluctuations where the inflationary gravitational wave signal is thought to exist. A HWP modulator rotates the input polarization signal and therefore allows a single polarimeter to measure both linear polarization states, eliminating systematic errors associated with differencing of orthogonal detectors. PB2 projects a 365-mm-diameter focal plane of 7,588 dichroic, 95/150 GHz transition-edge-sensor bolometers onto a 4-degree field of view that scans the sky at $\\sim$ 1 degree per second. We find that a 500-mm-diameter ambient-temperature sapphire achromatic HWP rotating at 2 Hz is a suitable polarization modulator for PB2. We present the design considerations for the PB...

  15. Neutral gas temperature maps of the pin-to-plate Argon micro discharge into the ambient air

    CERN Document Server

    Xu, Shaofeng; Majeed, Asif

    2015-01-01

    This study is designed to explore the two dimensional temperature maps of the atmospheric argon discharge consisting of pin-to-plane electrodes supplied by a high voltage DC source. After checking the stability of the micro discharge, the two dimensional image plane focused by a quartz lens was scanned by the fiber probe driven by a 3D Mobile Platform. The rotational and vibrational temperatures are calculated using nitrogen emissions collected by the high resolution spectrometer and high sensitive intensified charge coupled device (ICCD). The rotational temperature varies from 1558.15 K to 2621.14 K and vibrational temperature varies from 3010.38 K to 3774.69 K, indicating a great temperature gradient due to small discharge size. The temperature maps show a lateral expansion and a sharp truncation in the radial direction. A double layers discharge is identified, where an arc discharge coats the glow discharge.

  16. Effects of dietary DL-2-hydroxy-4(methylthio)butanoic acid supplementation on growth performance, indices of ascites syndrome, and antioxidant capacity of broilers reared at low ambient temperature

    Science.gov (United States)

    Yang, G. L.; Zhang, K. Y.; Ding, X. M.; Zheng, P.; Luo, Y. H.; Bai, S. P.; Wang, J. P.; Xuan, Y.; Su, Z. W.; Zeng, Q. F.

    2016-01-01

    This study examined the effects of dietary DL-2-hydroxy-4(methylthio)butanoic acid (DL-HMTBA) supplementation on growth performance, antioxidant capacity, and ascites syndrome (AS) in broilers reared at low ambient temperature (LAT) from 7 to 28 days of age. Eight hundred 7-day-old broilers were randomly assigned to two ambient temperatures (LAT and normal ambient temperature [NAT]), four supplemental DL-HMTBA levels (0.17, 0.34, 0.51, and 0.68 %) of the basal diet in a 2 × 4 factorial arrangement (ten replicate pens; ten birds/pen). LAT and NAT indicate temperatures of 12-14 and 24-26 °C in two chambers, respectively, and broilers were reared at these temperatures from 7 to 28 days of age. LAT significantly decreased body weight gain (P recommended supplemental of DL-HMTBA level was 0.46 %.

  17. A practical synthesis of 3,4-diethoxybenzthioamide based on Friedel-Crafts reaction with potassium thiocyanate in methanesulfonic acid.

    Science.gov (United States)

    Aki, Shinji; Fujioka, Takafumi; Ishigami, Masashi; Minamikawa, Jun-ichi

    2002-09-01

    The synthesis of 3,4-diethoxybenzthioamide, the key intermediate for OPC-6535, is achieved by employing Friedel-Crafts reaction of 1,2-diethoxybenzene with potassium thiocyanate in methanesulfonic acid at ambient temperature.

  18. EFFECT OF PRE-TREATMENTS ON PHYSICO-CHEMICAL COMPOSITION OF DEHYDRATED JACKFRUIT CHIPS DURING STORAGE AT AMBIENT TEMPERATURE

    Directory of Open Access Journals (Sweden)

    ROHAN R. PATIL, MANDAR KHANVILKAR, D. N. MOKAT*, P. P. RELEKAR AND R K. H. PUJARI

    2014-08-01

    The dehydrated chips of jackfruit pre-treated with ascorbic acid (T4 recorded maximum mean score for colour, flavour and texture irrespective of storage period. The organoleptic scores of these dehydrated jackfruit chips for all above attributes were declined with the increase in storage period from 0 to 60 days. The dehydrated chips pre-treated with ascorbic acid (T4 recorded maximum overall acceptability score of 6.91 at 60 days of storage which clearly indicated its suitability for making good quality chips and also for storing them for 60 days at ambient conditions without much loss of sensory and nutritional qualities of chips.Keywords: Physico chemical composition of dehydrated chips of jackfruit (Artocarpus heterophyllus and storage period.

  19. Det Ambiente

    DEFF Research Database (Denmark)

    Schmidt, Ulrik

    Det ambiente er iscenesættelsen af en karakteristisk sanseoplevelse, der er kendetegnet ved fornemmelsen af at være omgivet. I dag bliver begrebet om det ambiente mest anvendt i forbindelse med musikgenren ’ambient musik’. Det ambiente er dog ikke essentielt knyttet til det musikalske, men må...... forstås som et betydeligt bredere fænomen i den moderne æstetiske kultur, der spiller en væsentlig rolle i oplevelsen af moderne transportformer, arkitektur, film, lydkunst, installationskunst og digitale multimedieiscenesættelser. En forståelse af det ambiente er derfor centralt for forståelsen af en...... moderne æstetiseret oplevelseskultur i almindelighed. Da det ambiente ikke hidtil har været gjort til genstand for en mere indgående teoretisk behandling, er der dog stor usikkerhed omkring, hvad fænomenet overhovedet indebærer. Hovedformålet med Det ambiente – Sansning, medialisering, omgivelse er derfor...

  20. Alterations in sheep peripheral blood mononuclear cell proliferation and cytokine release by polyunsaturated fatty acid supplementation in the diet under high ambient temperature.

    Science.gov (United States)

    Ciliberti, Maria Giovanna; Albenzio, Marzia; Annicchiarico, Giovanni; Sevi, Agostino; Muscio, Antonio; Caroprese, Mariangela

    2015-02-01

    The aim of this study was to investigate the effects of polyunsaturated fatty acid (PUFA) supplementation from different sources in the diet of dairy sheep under high ambient temperatures on ex vivo lymphocyte proliferation and inflammatory responses. The experiment was carried out during summer: 32 Comisana ewes were divided into 4 groups of 8. The FS group was supplemented with whole flaxseed, the AG group was supplemented with Ascophyllum nodosum, the FS+AG group was supplemented with a combination of flaxseed and A. nodosum. The fourth group (CON group) was a control and received a diet containing no supplement. The average maximum temperature was around 33°C during wk 2 and 3, whereas the mean temperature never decreased below 26°C. Following 15 d of treatment with respective diets, peripheral blood mononuclear cells (PBMC) from sheep who received a diet supplemented with A. nodosum had impaired cell proliferation responses and IL-6 production after mitogen stimulation compared with PBMC from FS+AG sheep. In addition, PBMC from AG sheep displayed impaired cell proliferation compared with cells from the CON group. The FS+AG cells produced lower levels of IL-10 than CON cells, and higher IL-6 than AG and CON cells. Results demonstrated that the supplementation with PUFA from different sources in a sheep's diet can influence their immunological responses under high ambient temperatures depending on the composition of fatty acid supplementation. In particular, synergistic effects of different PUFA from flaxseed and A. nodosum, simultaneously administrated in the sheep diet, were observed on activation of inflammation response. PMID:25497814

  1. High-Temperature Microfluidic Synthesis of CdSe Nanocrystals inNanoliter Droplets

    Energy Technology Data Exchange (ETDEWEB)

    Chan, Emory M.; Alivisatos, A. Paul; Mathies, Richard A.

    2005-06-09

    The high-temperature synthesis of CdSe nanocrystals innanoliter-volume droplets flowing in a perfluorinated carrier fluidthrough a microfabricated reactor is presented. A flow-focusing nanojetstructure with a step increase in channel height reproducibly generatedoctadecene droplets in Fomblin Y 06/6 perfluorinated polyether atcapillary numbers up to 0.81 and with a droplet:carrier fluid viscosityratio of 0.035. Cadmium and selenium precursors flowing in octadecenedroplets through a high-temperature (240-300 degrees C) glassmicroreactor produced high quality CdSe nanocrystals, as verified byoptical spectroscopy and transmission electron microscopy. Isolating thereaction solution in droplets prevented particle deposition andhydrodynamic dispersion, allowing the reproducible synthesis ofnanocrystals at three different temperatures and four different residencetimes in the span of four hours. Our synthesis of a wide range ofnanocrystals at high temperatures, high capillary numbers, and lowviscosity ratio illustrates the general utility of droplet-basedmicrofluidic reactors to encapsulate nanoliter volumes of organic oraqueous solutions and to precisely control chemical or biochemicalreactions.

  2. Multiplexed Sensor for Synthesis Gas Compsition and Temperature

    Energy Technology Data Exchange (ETDEWEB)

    Steven Buckley; Reza Gharavi; Marco Leon

    2007-10-01

    The overall goal of this project has been to develop a highly sensitive, multiplexed TDL-based sensor for CO{sub 2}, CO, H{sub 2}O (and temperature), CH{sub 4}, H{sub 2}S, and NH{sub 3}. Such a sensor was designed with so-called 'plug-and-play' characteristics to accommodate additional sensors, and provided in situ path-integrated measurements indicative of average concentrations at speeds suitable for direct gasifier control. The project developed the sensor and culminated in a real-world test of the underlying technology behind the sensor. During the project, new underlying measurements of spectroscopic constants for all of the gases of interest performed, in custom cells built for the project. The envisioned instrument was built from scratch from component lasers, fiber optics, amplifier blocks, detectors, etc. The sensor was tested for nearly a week in an operational power plant. The products of this research are expected to have a direct impact on gasifier technology and the production of high-quality syngas, with substantial broader application to coal and other energy systems. This report is the final technical report on project DE-FG26-04NT42172. During the project we completed all of the milestones planned in the project, with a modification of milestone (7) required due to lack of funding and personnel.

  3. Online Estimation of Model Parameters and State of Charge of LiFePO4 Batteries Using a Novel Open-Circuit Voltage at Various Ambient Temperatures

    Directory of Open Access Journals (Sweden)

    Fei Feng

    2015-04-01

    Full Text Available This study describes an online estimation of the model parameters and state of charge (SOC of lithium iron phosphate batteries in electric vehicles. A widely used SOC estimator is based on the dynamic battery model with predeterminate parameters. However, model parameter variances that follow with their varied operation temperatures can result in errors in estimating battery SOC. To address this problem, a battery online parameter estimator is presented based on an equivalent circuit model using an adaptive joint extended Kalman filter algorithm. Simulations based on actual data are established to verify accuracy and stability in the regression of model parameters. Experiments are also performed to prove that the proposed estimator exhibits good reliability and adaptability under different loading profiles with various temperatures. In addition, open-circuit voltage (OCV is used to estimate SOC in the proposed algorithm. However, the OCV based on the proposed online identification includes a part of concentration polarization and hysteresis, which is defined as parametric identification-based OCV (OCVPI. Considering the temperature factor, a novel OCV–SOC relationship map is established by using OCVPI under various temperatures. Finally, a validating experiment is conducted based on the consecutive loading profiles. Results indicate that our method is effective and adaptable when a battery operates at different ambient temperatures.

  4. The Short-Term Effect of Ambient Temperature on Mortality in Wuhan, China: A Time-Series Study Using a Distributed Lag Non-Linear Model

    Directory of Open Access Journals (Sweden)

    Yunquan Zhang

    2016-07-01

    Full Text Available Less evidence concerning the association between ambient temperature and mortality is available in developing countries/regions, especially inland areas of China, and few previous studies have compared the predictive ability of different temperature indictors (minimum, mean, and maximum temperature on mortality. We assessed the effects of temperature on daily mortality from 2003 to 2010 in Jiang’an District of Wuhan, the largest city in central China. Quasi-Poisson generalized linear models combined with both non-threshold and double-threshold distributed lag non-linear models (DLNM were used to examine the associations between different temperature indictors and cause-specific mortality. We found a U-shaped relationship between temperature and mortality in Wuhan. Double-threshold DLNM with mean temperature performed best in predicting temperature-mortality relationship. Cold effect was delayed, whereas hot effect was acute, both of which lasted for several days. For cold effects over lag 0–21 days, a 1 °C decrease in mean temperature below the cold thresholds was associated with a 2.39% (95% CI: 1.71, 3.08 increase in non-accidental mortality, 3.65% (95% CI: 2.62, 4.69 increase in cardiovascular mortality, 3.87% (95% CI: 1.57, 6.22 increase in respiratory mortality, 3.13% (95% CI: 1.88, 4.38 increase in stroke mortality, and 21.57% (95% CI: 12.59, 31.26 increase in ischemic heart disease (IHD mortality. For hot effects over lag 0–7 days, a 1 °C increase in mean temperature above the hot thresholds was associated with a 25.18% (95% CI: 18.74, 31.96 increase in non-accidental mortality, 34.10% (95% CI: 25.63, 43.16 increase in cardiovascular mortality, 24.27% (95% CI: 7.55, 43.59 increase in respiratory mortality, 59.1% (95% CI: 41.81, 78.5 increase in stroke mortality, and 17.00% (95% CI: 7.91, 26.87 increase in IHD mortality. This study suggested that both low and high temperature were associated with increased mortality in Wuhan, and

  5. The Short-Term Effect of Ambient Temperature on Mortality in Wuhan, China: A Time-Series Study Using a Distributed Lag Non-Linear Model

    Science.gov (United States)

    Zhang, Yunquan; Li, Cunlu; Feng, Renjie; Zhu, Yaohui; Wu, Kai; Tan, Xiaodong; Ma, Lu

    2016-01-01

    Less evidence concerning the association between ambient temperature and mortality is available in developing countries/regions, especially inland areas of China, and few previous studies have compared the predictive ability of different temperature indictors (minimum, mean, and maximum temperature) on mortality. We assessed the effects of temperature on daily mortality from 2003 to 2010 in Jiang’an District of Wuhan, the largest city in central China. Quasi-Poisson generalized linear models combined with both non-threshold and double-threshold distributed lag non-linear models (DLNM) were used to examine the associations between different temperature indictors and cause-specific mortality. We found a U-shaped relationship between temperature and mortality in Wuhan. Double-threshold DLNM with mean temperature performed best in predicting temperature-mortality relationship. Cold effect was delayed, whereas hot effect was acute, both of which lasted for several days. For cold effects over lag 0–21 days, a 1 °C decrease in mean temperature below the cold thresholds was associated with a 2.39% (95% CI: 1.71, 3.08) increase in non-accidental mortality, 3.65% (95% CI: 2.62, 4.69) increase in cardiovascular mortality, 3.87% (95% CI: 1.57, 6.22) increase in respiratory mortality, 3.13% (95% CI: 1.88, 4.38) increase in stroke mortality, and 21.57% (95% CI: 12.59, 31.26) increase in ischemic heart disease (IHD) mortality. For hot effects over lag 0–7 days, a 1 °C increase in mean temperature above the hot thresholds was associated with a 25.18% (95% CI: 18.74, 31.96) increase in non-accidental mortality, 34.10% (95% CI: 25.63, 43.16) increase in cardiovascular mortality, 24.27% (95% CI: 7.55, 43.59) increase in respiratory mortality, 59.1% (95% CI: 41.81, 78.5) increase in stroke mortality, and 17.00% (95% CI: 7.91, 26.87) increase in IHD mortality. This study suggested that both low and high temperature were associated with increased mortality in Wuhan, and that

  6. Origin of low temperature deactivation of Ni5Ga3 nanoparticles as catalyst for methanol synthesis

    DEFF Research Database (Denmark)

    Gardini, Diego; Sharafutdinov, Irek; Damsgaard, Christian Danvad;

    ] confirm dealloying as responsible for high temperature (T > 300 °C) deactivation, this does not explain the activity loss in the low temperature regime (T temperature (T = 200, 210, 250 °C) deactivation of silica supported Ni5Ga3 nanoparticles...... as catalyst for methanol production. Synthesis, followed by deactivation and a series of regeneration steps at increasing temperature in pure H2 has been carried out in a fixed-bed reactor connected to a gas chromatography system. In each regeneration step, CH4 is generated and the activity of the catalyst...... is subsequently increased, suggesting the presence of carbon containing species blocking the active sites of the alloy nanoparticles (Figure 1). Carbon deposition has furthermore been investigated by temperature programmed oxidation (TPO) of a deactivated catalyst in a fixed-bed reactor connected to a mass...

  7. Combustion synthesis and structural analysis of nanocrystalline nickel ferrite at low temperature regime

    International Nuclear Information System (INIS)

    Combustion synthesis of single phase Nickel ferrite was successfully achieved at low temperature regime. The obtained powders were calcinated to increase the crystallinity and their characterization change due to calcinations is investigated in detail. Citric acid used as a chelating agent for the synthesis of nickel ferrite. Pure single phase nickel ferrites were found at this low temperature. The average crystalline sizes were measured by using powder XRD measurements. Surface morphology was investigated through Transmission Electron Microscope (TEM). Particle size calculated in XRD is compared with TEM results. Magnetic behaviour of the samples is analyzed by using Vibrating Sample Magnetometer (VSM). Saturation magnetization, coercivity and retentivity are measured and their results are discussed in detail

  8. Combustion synthesis and structural analysis of nanocrystalline nickel ferrite at low temperature regime

    Energy Technology Data Exchange (ETDEWEB)

    Shanmugavel, T., E-mail: gokulrajs@hotmail.com, E-mail: shanmugavelnano@gmail.com [Department of Physics, Anna University of Technology, Coimbatore-641 047 (India); Raj, S. Gokul, E-mail: gokulrajs@hotmail.com, E-mail: shanmugavelnano@gmail.com [Department of Physics, Vel tech University, Avadi, Chennai-600062 India (India); Rajarajan, G. [Department of Physics, Selvam College of Technology, Namakkal-637005 India (India); Kumar, G. Ramesh [Department of Physics, University College of Engineering, Anna University Chennai, Arni 632317 (India); Boopathi, G. [Department of Physics, Presidency College (Autonomous), Chennai - 600005 (India)

    2015-06-24

    Combustion synthesis of single phase Nickel ferrite was successfully achieved at low temperature regime. The obtained powders were calcinated to increase the crystallinity and their characterization change due to calcinations is investigated in detail. Citric acid used as a chelating agent for the synthesis of nickel ferrite. Pure single phase nickel ferrites were found at this low temperature. The average crystalline sizes were measured by using powder XRD measurements. Surface morphology was investigated through Transmission Electron Microscope (TEM). Particle size calculated in XRD is compared with TEM results. Magnetic behaviour of the samples is analyzed by using Vibrating Sample Magnetometer (VSM). Saturation magnetization, coercivity and retentivity are measured and their results are discussed in detail.

  9. The effect of temperature in flux-assisted synthesis of SnNb2O6

    KAUST Repository

    Noureldine, D.

    2014-10-03

    A flux-assisted method was used to synthesize SnNb2O6 as a visible-light-responsive metal oxide photocatalyst. The role of synthesis temperature was investigated in detail using different reaction temperatures (300, 500, 600, 800, 1000 °C). The obtained products were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), Brunauer-Emmett-Teller method (BET). The synthesis with SnCl2 as a flux led to tin niobate particles in the platelet morphology with smooth surfaces. The synthesized crystal showed 2D anisotropic growth along the (600) plane as the flux ratio increased. The particles synthesized with a high reactant to flux ratio (1:10 or higher) exhibited improved photocatalytic activity for hydrogen evolution from an aqueous methanol solution under visible radiation (λ > 420 nm). © (2014) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.

  10. Effect of Ambient Temperature on Total Organic Gas Speciation Profiles from Light-Duty Gasoline Vehicle Exhaust.

    Science.gov (United States)

    Roy, Anirban; Sonntag, Darrell; Cook, Richard; Yanca, Catherine; Schenk, Charles; Choi, Yunsoo

    2016-06-21

    Total organic gases (TOG) emissions from motor vehicles include air toxic compounds and contribute to formation of ground-level ozone and secondary organic aerosol (SOA). These emissions are known to be affected by temperature; however previous studies have typically focused only on the temperature dependence of total emission factors and select toxic compounds. This study builds on the previous research by performing an evaluation of a comprehensive set of gas-phase organic compounds present in gasoline motor vehicle exhaust. A fleet of five vehicles using port fuel injection engine technology and running on E10 fuel was tested. Overall, three temperatures (0, 20, and 75 °F; or -18, -7, and 24 °C), two driving conditions (urban-FTP75 and aggressive driving-US06) and 161 compounds were evaluated; the emissions distributions were used to construct speciation profiles for each driving cycle and temperature. Overall, the speciation results indicated a significant increase in alkane and methane content, and decrease in alcohol, aldehyde and ketone content with decreasing temperature. These were verified using a statistical significance test. The fraction and composition of Mobile Source Air Toxics (MSATs) were significantly affected by temperature for both driving cycles. The ozone forming potentials of these profiles were evaluated using the maximum incremental reactivity (MIR) scale. Aromatic content was predicted to be a major driver behind the ozone forming potentials. Additionally, the decreasing ozone potential could be attributed to increased methane fractions with increasing temperature. PMID:27203618

  11. X-ray sensing materials stability: influence of ambient storage temperature on essential thermal properties of undoped vitreous selenium

    International Nuclear Information System (INIS)

    Amorphous selenium (a-Se) is currently used in x-ray image detectors as an x-ray photoconductor. Normally a-Se films used in device applications are fabricated by the evaporation of vitreous bulk material loaded into boats in a typical vacuum deposition system. The resistance against crystallization is an important factor in both film and bulk forms of a-Se. Previous work has indicted that the resistance to crystallization is surprisingly more pronounced around 35 °C [1]. In this work we have therefore examined the essential thermal properties of vitreous selenium (99.999%) samples that have been stored at different temperatures. The thermal characterization experiments involved a series of DSC (Differential Scanning Calorimetry) measurements in which have monitored the glass transition and melting endotherms, and the crystallization exotherm in heating-cooling-heating scans. In DSC experiments, a sample would be heated to a temperature above the melting temperature, equilibrated, then cooled at a fixed rate down to 20 °C, then equilibrated and finally scanned again under a heating schedule. The samples were isothermally stored at temperatures corresponding to 18, 35 and 55 °C. The thermal analysis results show that there are distinct differences in the thermal properties. We have examined the stability in terms of the difference in the crystallization onset temperature (Tc) and the onset of glass transition temperature (Tg). We also examined the Hruby coefficient (Kgl) of these samples, that is Kgl = (Tc – Tg)/(Tm – Tc) where Tc is the crystallization onset temperature and Tm is the melting onset temperature. We have found Kgl to depend on the storage temperature. Surprisingly, we observed that the Hruby coefficient is actually larger at 35 °C compared to the values at 18 and 55 °C

  12. Ambient Gestures

    OpenAIRE

    Karam, Maria; Hare, Jonathon; Lewis, Paul; schraefel, m.c.

    2006-01-01

    We present Ambient Gestures, a novel gesture-based system designed to support ubiquitous ‘in the environment’ interactions with everyday computing technology. Hand gestures and audio feedback allow users to control computer applications without reliance on a graphical user interface, and without having to switch from the context of a non-computer task to the context of the computer. The Ambient Gestures system is composed of a vision recognition software application, a set of gestures to be p...

  13. Synthesis and Characterization of (Z)-Furan-2-carbaldehyde Thiosemicarbazone at Low Temperature

    OpenAIRE

    Abbasi, Alireza; Geranmayeh, Shokoofeh; Taheri, Ali Naghi; Shahroosvand, Hashem; Shabani, Mohsen

    2010-01-01

    The compound, C6H7N3OS, has been prepared and characterized by condensation between thiosemicarbazide and furan-2-carbaldehyde and its structure was elucidated by x-ray analysis (at 150 K), NMR and IR spectroscopy methods (at ambient temperature). It crystallizes in the monoclinic space group P21/c (No. 14), a = 13.5099(3) Å, b = 5.67430(10) Å, c = 23.4755(6) Å, β= 117.367(2)°, V = 1598.20(7) Å3 and Z = 8. The crystal structure was solved and refined to R = 0.0290 with 2942 unique reflections...

  14. The Aluminum Based Composite Produced by Self Propagating High Temperature Synthesis

    Directory of Open Access Journals (Sweden)

    Agus PRAMONO

    2016-05-01

    Full Text Available Self-propagating high-temperature synthesis method can be used for producing aluminum and boron carbide based composites. The experimental composites were fabricated using cobalt and carbon as catalysts. The microstructure of the material was studied using Scanning Electron Microscopy and the mechanical properties were determined using micro-hardness testing. Al/B4C based composites with improved properties were obtained and the role of Co/C catalysts was studied.

  15. The synthesis of [2-13C]2-nitropropane at room temperature and at atmospheric pressure

    OpenAIRE

    Jacquemijns M; Zomer G

    1990-01-01

    In this report the synthesis of [2-13C]2-nitropropane at room temperature is described. [2-13C]Acetone was converted into the oxime with hydroxy hydrochloridelamine and sodium carbonate. Treatment with hypobromic acid resulted in 2-13C]2-bromo-2-nitropropane. Hydrogenation with sodium borohydride gave [2-13C]2-nitropropane in 14,3% overall yield.

  16. Influence of Feeding Enzymatically Hydrolyzed Yeast Cell Wall on Growth Performance and Digestive Function of Feedlot Cattle during Periods of Elevated Ambient Temperature

    Science.gov (United States)

    Salinas-Chavira, J.; Arzola, C.; González-Vizcarra, V.; Manríquez-Núñez, O. M.; Montaño-Gómez, M. F.; Navarrete-Reyes, J. D.; Raymundo, C.; Zinn, R. A.

    2015-01-01

    In experiment 1, eighty crossbred steers (239±15 kg) were used in a 229-d experiment to evaluate the effects of increasing levels of enzymatically hydrolyzed yeast (EHY) cell wall in diets on growth performance feedlot cattle during periods of elevated ambient temperature. Treatments consisted of steam-flaked corn-based diets supplemented to provide 0, 1, 2, or 3 g EHY/hd/d. There were no effects on growth performance during the initial 139-d period. However, from d 139 to harvest, when 24-h temperature humidity index averaged 80, EHY increased dry matter intake (DMI) (linear effect, p0.10) on carcass characteristics. In experiment 2, four Holstein steers (292±5 kg) with cannulas in the rumen and proximal duodenum were used in a 4×4 Latin Square design experiment to evaluate treatments effects on characteristics of ruminal and total tract digestion in steers. There were no treatment effects (p>0.10) on ruminal pH, total volatile fatty acid, molar proportions of acetate, butyrate, or estimated methane production. Supplemental EHY decreased ruminal molar proportion of acetate (p = 0.08), increased molar proportion of propionate (p = 0.09), and decreased acetate:propionate molar ratio (p = 0.07) and estimated ruminal methane production (p = 0.09). It is concluded that supplemental EHY may enhance DMI and ADG of feedlot steers during periods of high ambient temperature. Supplemental EHY may also enhance ruminal fiber digestion and decrease ruminal acetate:propionate molar ratios in feedlot steers fed steam-flaked corn-based finishing diets. PMID:26194225

  17. Inverse relationship between ambient temperature and admissions for diabetic ketoacidosis and hyperglycemic hyperosmolar state: A 14-year time-series analysis.

    Science.gov (United States)

    Lu, Chin-Li; Chang, Hsin-Hui; Chen, Hua-Fen; Ku, Li-Jung Elizabeth; Chang, Ya-Hui; Shen, Hsiu-Nien; Li, Chung-Yi

    2016-09-01

    This study aimed to investigate the association of admissions for diabetic ketoacidosis (DKA) and hyperglycemic hyperosmolar state (HHS) with ambient temperature and season, respectively in patients with diabetes mellitus (DM), after excluding known co-morbidities that predispose onset of acute hyperglycemia events. This was a time series correlation analysis based on medical claims of 40,084 and 33,947 episodes of admission for DKA and HHS, respectively over a 14-year period in Taiwan. These episodes were not accompanied by co-morbidities known to trigger incidence of DKA and HHS. Monthly temperature averaged from 19 meteorological stations across Taiwan was correlated with monthly rate of admission for DKA or HHS, respectively, using the 'seasonal Autoregressive Integrated Moving Average' (seasonal ARIMA) regression method. There was an inverse relationship between ambient temperature and rates of admission for DKA (β=-0.035, p<0.001) and HHS (β=-0.016, p<0.001), despite a clear decline in rates of DKA/HHS admission in the second half of the study period. We also noted that winter was significantly associated with increased rates of both DKA (β=0.364, p<0.001) and HHS (β=0.129, p<0.05) admissions, as compared with summer. On the other hand, fall was associated with a significantly lower rate of HHS admission (β=-0.016, p<0.05). Further stratified analyses according to sex and age yield essentially similar results. It is suggested that meteorological data can be used to raise the awareness of acute hyperglycemic complication risk for both patients with diabetes and clinicians to further avoid the occurrence of DKA and HHS. PMID:27395337

  18. DOE STI Product/Final Report Number 3 Electrochemical Investigation of Novel Electrolytes for Ambient Temperature Sodium Batteries

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Ketack; Lang, Christopher M.; Doyle, Kevin; Kohl, Paul A.

    2005-12-01

    The need for low-cost, high-energy density, durable, secondary batteries continues to rise with the demands of the electronics and automobile industries. A room-temperature version of the (high-temperature) ''Zebra Cell'' may provide an interesting technology for portable electronics and transportation. Sodium-based batteries have received attention as an alternative to the lithium-based batteries due to several factors including the absence of dendrite formation during sodium deposition and the abundance of sodium. This work focused on (1) the development of room-temperature ionic liquids (IL) for use in electrochemical devices, including batteries, (2) development and evaluation of secondary sodium batteries using room-temperature ILs, and (3) advancing the fundamental understanding of the electrochemical processes involving ILs and battery technology. Several objectives were accomplished during this program.

  19. Ambient-temperature Conditioning as a Probe of Double-C Transformation Mechanisms in Pu-2.0 at. % Ga

    Energy Technology Data Exchange (ETDEWEB)

    Jeffries, J R; Blobaum, K M; Wall, M A; Schwartz, A J

    2008-04-02

    The gallium-stabilized Pu-2.0 at. % Ga alloy undergoes a partial or incomplete low-temperature martensitic transformation from the metastable {delta} phase to the gallium-containing, monoclinic {alpha}{prime} phase near -100 C. This transformation has been shown to occur isothermally and it displays anomalous double-C kinetics in a time-temperature-transformation (TTT) diagram, where two nose temperatures anchoring an upper- and lower-C describe minima in the time for the initiation of transformation. The underlying mechanisms responsible for the double-C behavior are currently unresolved, although recent experiments suggest that a conditioning treatment--wherein, following an anneal at 375 C, the sample is held at a sub-anneal temperature for a period of time--significantly influences the upper-C of the TTT diagram. As such, elucidating the effects of the conditioning treatment upon the {delta} {yields} {alpha}{prime} transformation can provide valuable insights into the fundamental mechanisms governing the double-C kinetics of the transition. Following a high-temperature anneal, a differential scanning calorimeter (DSC) was used to establish an optimal conditioning curve that depicts the amount of {alpha}{prime} formed during the transformation as a function of conditioning temperature for a specified time. With the optimal conditioning curve as a baseline, the DSC was used to explore the circumstances under which the effects of the conditioning treatment were destroyed, resulting in little or no transformation.

  20. Use of ethyl lactate to extract bioactive compounds from Cytisus scoparius: Comparison of pressurized liquid extraction and medium scale ambient temperature systems.

    Science.gov (United States)

    Lores, Marta; Pájaro, Marta; Álvarez-Casas, Marta; Domínguez, Jorge; García-Jares, Carmen

    2015-08-01

    An important trend in the extraction of chemical compounds is the application of new environmentally friendly, food grade solvents. Ethyl lactate (ethyl 2-hydroxypropanoate), produced by fermentation of carbohydrates, is miscible with both hydrophilic and hydrophobic compounds being a potentially good solvent for bioactive compounds. Despite its relatively wide use as a general solvent, the utilization of ethyl lactate as an extraction solvent has only recently been considered. Here, we evaluate the possible use of ethyl lactate to extract phenolic compounds from wild plants belonging to Cytisus scoparius, and we compare the characteristics of the extracts obtained by Pressurized Solvent Extraction (the total phenolics content, the antioxidant activity and the concentration of the major polyphenols) with those of other extracts obtained with methanol. In order to explore the industrial production of the ethyl lactate Cytisus extract, we also evaluate medium scale ambient temperature setups. The whole plant and the different parts (flowers, branches, and seed pods) were evaluated separately as potential sources of polyphenols. All extracts were analyzed by LC-MS/MS for accurate identification of the major polyphenols. Similar phenolic profiles were obtained when using ethyl lactate or methanol. The main bioactives found in the Cytisus extract were the non-flavonoid phenolic compounds caffeic and protocatechuic acids and 3,4-dihydroxybenzaldehyde; the flavonoids rutin, kaempferol and quercetin; the flavones chrysin, orientin and apigenin; and the alkaloid lupanine. Regarding the comparison of the extraction systems, although the performance of the PLE was much better than that of the ambient-temperature columns, the energy consumption was also much higher. Ethyl lactate has resulted an efficient extraction solvent for polyphenols from C. scoparius, yielding extracts with high levels of plant phenolics and antioxidant activity. The antimicrobial activity of these

  1. The role of irradiation on microbiological safety and shelf-life extension of non-sterile and sterile convenience meat products stored at ambient temperatures

    International Nuclear Information System (INIS)

    The effect of gamma irradiation in combination with vacuum packaging on the microbiological and sensory quality of Intermediate Moisture (IM) buffalo, chicken or lamb meat cubes, and number of ready-to-cook ethnic meat products stored at ambient temperature (30 ± 2 deg. C) was studied. Irradiation treatment (2.5, 5 and 10 kGy) resulted in a dose-dependent reduction in the total viable count as well as levels of potentially pathogenic Staphylococcus spp. and these samples remained microbiologically superior to their non-irradiated counterparts upon extended storage. Irradiation (10 kGy) treatment of vacuum packed IM spiced lamb and chicken cubes resulted in a product in which no viable microorganisms could be detected for 12 months of storage at ambient temperature (30 ± 2 deg. C). Initial analysis of non-irradiated samples showed total viable counts of >106 CFU/g, Staphylococcus counts of >105 CFU/g and mould counts of 103 CFU/g which upon 3 months of storage under similar conditions spoiled showing visible mould growth. Ready-to-use shelf-stable mutton and chicken sheek kababs, mutton and chicken chilli were developed by reducing the water activity either by grilling or by hot air-drying, vacuum packing and irradiation. Microbiological analysis revealed a dose-dependent reduction in the total viable count and in potentially pathogenic Staphylococcus spp. upon irradiation treatment (2.5, 5 and 10 kGy). The products subjected to irradiation at 10 kGy showed an absence of viable microorganisms and also had high sensory acceptability up to 9 months at ambient temperature. Amenability of various ready-to-cook and ready-to-eat chicken, mutton and pork products for radappertization using locally available packaging material was evaluated. The sensory quality of all products without gravy was found to be acceptable. However, traditional gravy based products showed changes in the sensory attributes (colour and flavour) leading to lower acceptability of the products

  2. Changes in ambient temperature and oxygenation during the proestrus do not affect duration, regularity and repeatability of the estrus cycle in female rats.

    Directory of Open Access Journals (Sweden)

    Grazyna Wójcik

    2009-12-01

    Full Text Available There are a lot of factors affecting the release of hormones from the anterior part of pituitary gland and their interactions with other parts of the endocrine, nervous and immune systems. The special significance of the proestrus phase of the estrous cycle of the rat, during which LH and FSH levels increase, followed by ovulation is known. The short length of the estrous cycle and the well recognized sequence of vaginal lavage cytology make it useful for investigating the influence of a stressful environment on the reproductive function. Short duration and mild changes in environmental conditions is considered as a factor analogous to psychological stress. The study was undertaken to determine the effects of a short duration change in the ambient temperature and oxygenation (30 minutes on the proestrus phase of reproductive cycle and on the repeatability and regularity of phases of the reproductive cycle of Wistar strain rats. The animals were kept under standard conditions and had food and water available ad libitum. The climatic chamber with automatically adjustable and monitored internal parameters (temperature, oxygenation, humidity was used to develop stress conditions. An estimation of the vaginal lavage using the microscope was done to determine the estrous cycle. The animals were divided into 6 groups. On the day of experiment: the control group (CG stayed in the climatic chamber for 30 minutes (ambient temperature 21 degrees C, normoxia - 21% O(2, the five test groups (TG - I - V remained in the climatic chamber for 30 minutes, in the established environmental conditions (I - 21 degrees C, 10% O(2; II - 10 degrees C, 21% O(2; III - 10 degrees C, 10% O(2; IV - 35 degrees C, 21% O(2; V - 35 degrees C, 10% O(2. During the following days after the experiment, a microscopic estimation of vaginal lavage was collected over again. There were no changes of duration and sequence of the present estrous cycle and repeatability of the next cycles

  3. Response of branchial Na(+)/K(+) ATPase to changes in ambient temperature in Atlantic cod (Gadus morhua) and whiting (Merlangius merlangus).

    Science.gov (United States)

    Michael, Katharina; Koschnick, Nils; Pörtner, Hans-O; Lucassen, Magnus

    2016-05-01

    The maintenance of ion and pH homeostasis despite changes in ambient temperature is crucial for ectothermic organisms. Thermal sensitivity of Na(+)/K(+) ATPase mRNA expression, protein expression and activity was determined in gills of North Sea cod (NC) and Northeastern Arctic cod (NEAC), acclimated for 6 weeks at 4 and 10 °C and compared to field samples of North Sea cod (sNC), acclimatized to early spring (4 °C) and summer (18 °C) conditions. The same analyses were conducted in gills of the confamiliar whiting, acclimated at 4 and 10 °C. Branchial Na(+)/K(+) ATPase capacities remained uncompensated at functional and protein levels in NC and NEAC at both acclimation temperatures. Na(+)/K(+) ATPase mRNA expression in NEAC acclimated at 10 °C was about twofold higher compared to NC, indicating some population-specific differentiation at this level. Lower Na(+)/K(+) ATPase capacities in gills of warm-acclimatized sNC at common assay temperatures indicate thermal compensation between seasonal extremes, and post-translational modifications contributed to this mitigation at high assay temperature. Together, cod compensates Na(+)/K(+) ATPase capacities on the warm edge of the thermal window and below 4 °C, respectively. In contrast, whiting Na(+)/K(+) ATPase capacities were cold compensated at 4 °C, supported by 1.5-fold higher mRNA and protein expression. Besides, capacities were lower in whiting compared to NC and NEAC at optimum temperature, which may be advantageous in terms of reduced maintenance cost, but at temperatures ≤4 °C, compensation may represent an energy trade-off to maintain homeostasis. The species-specific response of gadid Na(+)/K(+) ATPase indicates certain threshold temperatures beyond which compensation of the pump is elicited, possibly related to the different biogeography of these species.

  4. Synthesis and properties of Mn1-XFeXS single-crystals at room temperature

    International Nuclear Information System (INIS)

    Results of the first synthesis of Mn1-XFeXS single-crystals and its structural, electrical and magnetic properties at room temperature are presented. The Mn2+→Fe2+ substitution in Mn1-XFeXS solid solutions is accompanied by a compression of the NaCl lattice and a small deformation of the octahedral environments, and the concentration transition from dielectric to semimetal. Single-line Mossbauer spectra indicate the paramagnetic state Mn1-XFeXS sulfides at room temperature

  5. Review of the effect of ambient temperature on population health%气温对人群健康影响研究进展

    Institute of Scientific and Technical Information of China (English)

    栾桂杰; 周脉耕

    2015-01-01

    气温是与人类生活密切相关的环境因素,全球气候变化导致极端气象事件发生频率和概率呈现增加态势,极端气温事件和由此造成对人体健康的不良影响将会更多,气温对健康的影响日益受到关注,尤其是对慢性非传染性疾病的影响。本文综述了当前气温对健康影响的研究现状,以及研究的新热点领域。%Temperature is an environment factors that is closely related to human life,global climate change has increased the frequency and probability of extreme weather events,extreme temperature weather events and the resulting adverse impact on human health will be more,and the impact of temperature on health is increasingly concerned,especially for chronic and noncommunicable diseases.The paper reviews the current research status of the effect of ambient tem-perature on health,and summarizes the new hotspot of the recent research.

  6. Axial- and radial-resolved electron density and excitation temperature of aluminum plasma induced by nanosecond laser: Effect of the ambient gas composition and pressure

    Directory of Open Access Journals (Sweden)

    Mahmoud S. Dawood

    2015-11-01

    Full Text Available The spatial variation of the characteristics of an aluminum plasma induced by a pulsed nanosecond XeCl laser is studied in this paper. The electron density and the excitation temperature are deduced from time- and space- resolved Stark broadening of an ion line and from a Boltzmann diagram, respectively. The influence of the gas pressure (from vacuum up to atmospheric pressure and compositions (argon, nitrogen and helium on these characteristics is investigated. It is observed that the highest electron density occurs near the laser spot and decreases by moving away both from the target surface and from the plume center to its edge. The electron density increases with the gas pressure, the highest values being occurred at atmospheric pressure when the ambient gas has the highest mass, i.e. in argon. The excitation temperature is determined from the Boltzmann plot of line intensities of iron impurities present in the aluminum target. The highest temperature is observed close to the laser spot location for argon at atmospheric pressure. It decreases by moving away from the target surface in the axial direction. However, no significant variation of temperature occurs along the radial direction. The differences observed between the axial and radial direction are mainly due to the different plasma kinetics in both directions.

  7. CONTAINMENT VESSEL TEMPERATURE FOR PU-238 HEAT SOURCE CONTAINER UNDER AMBIENT, FREE CONVECTION AND LOW EMISSIVITY COOLING CONDITIONS

    Energy Technology Data Exchange (ETDEWEB)

    Gupta, N.; Smith, A.

    2011-02-14

    The EP-61 primary containment vessel of the 5320 shipping package has been used for storage and transportation of Pu-238 plutonium oxide heat source material. For storage, the material in its convenience canister called EP-60 is placed in the EP-61 and sealed by two threaded caps with elastomer O-ring seals. When the package is shipped, the outer cap is seal welded to the body. While stored, the EP-61s are placed in a cooling water bath. In preparation for welding, several containers are removed from storage and staged to the welding booth. The significant heat generation of the contents, and resulting rapid rise in component temperature necessitates special handling practices. The test described here was performed to determine the temperature rise with time and peak temperature attained for an EP-61 with 203 watts of internal heat generation, upon its removal from the cooling water bath.

  8. Low-temperature facile synthesis of graphene and graphene-carbon nanotubes hybrid on dielectric surfaces

    International Nuclear Information System (INIS)

    Various carbon based nanostructures (graphene, graphene-CNTs hybrid and three-dimensional (3D) carbon network) have been grown separately on low-temperature (600 °C) substrates by using a chemical vapor deposition system with a two-heating reactor. The two-heating reactor is utilized to offer sufficient, well-proportioned floating C atoms and provide a simple method for low-temperature deposition. Morphology and electrical properties of the carbon based nanostructures can be controlled by the substrate surfaces. A relatively flat surface is beneficial for the synthesis of graphene and surfaces with nanodots are required to directly grow graphene-carbon nanotube hybrids. A chemical vapor deposition mechanism dependent on the temperature gradient is proposed, suggesting that the transfer-free carbon nanostructures can be deposited on different substrates. These results open an easy way for direct and high-efficiency deposition of various carbon nanostructures on the low-temperature dielectric substrates. (papers)

  9. Optimization of synthesis of upconversion luminescence material NaYF4:Er3+,Yb3+ nanometer-phosphor by low-temperature combustion synthesis method

    Institute of Scientific and Technical Information of China (English)

    LU Liping; ZHANG Xiyan

    2013-01-01

    A kind of Er3+-yb3+ co-doped natrium yttrium fluoride nanometer-phosphor sensitive to 980 nm was synthesized by the low-temperature combustion synthesis method,which expanded the application range of the low-temperature combustion synthesis (LCS) method which is always used in the synthesis of oxides and compound oxides.The synthesis conditions were optimized with orthogonal experiments and the optimum technological parameters were obtaincd.Intense upconversion emissions at 522,540 and 653 nm corresponding to the 2H11/2,4S3/2,and 4F9/2 transitions to the 4I15/2 ground state were observed when excited by continuous wavclength (CW) laser radiation at 980 nm.The effect of the carbamide amount on the phase formation and the luminescence intensity was analyzed.The average particle size of the sample was 30-40 nm.

  10. The effect of natural and synthetic antioxidants on performance, egg quality and blood constituents of laying hens grown under high ambient temperature

    OpenAIRE

    Al-Harthi, Mohammed A.

    2014-01-01

    A total of 216 laying hens was kept at high ambient temperature (32±4°C, 60% relative humidity) from week 24 to 32 of age. Birds were divided in 8 treatments with 9 replicates of 3 hens each. The groups were fed the same basal diet and submitted to these dietary treatments: control, un-supplemented; green tea (GT), fed GT at 1 g/kg diet; brown marine algae (BMA), fed BMA at 1 g/kg diet; vitamin E (vit. E), fed vit. E at 300 mg/kg diet; GT+BMA, fed GT and BMA at 1 g/kg of each; GT+vit. E, fed ...

  11. Optimal design of self-propagating high temperature one-dimensional nano-SnO2 synthesis

    Institute of Scientific and Technical Information of China (English)

    Nian LIU; Guodong ZHANG

    2011-01-01

    The success in synthesizing high purity SnO2 nanobelts via self-propagating high temperature synthesis was achieved.According to the experimental results,a relationship between the residual heat of the reaction system at 2848 K and SnO2 nanobelts yield was identified.The most appropriate formula for this self-propagating high temperature synthesis method is turned out to be composed of Sn powder and thermite with weight ratio of 1∶1.

  12. The effects of fabric for sleepwear and bedding on sleep at ambient temperatures of 17°C and 22°C

    Directory of Open Access Journals (Sweden)

    Shin M

    2016-04-01

    Full Text Available Mirim Shin,1 Mark Halaki,1 Paul Swan,2 Angus Ireland,2 Chin Moi Chow1 1Exercise, Health and Performance Research Group, Faculty of Health Sciences, The University of Sydney, Lidcombe, 2Australian Wool Innovation Limited, The Woolmark Company, Sydney, NSW, Australia Abstract: The fibers used in clothing and bedding have different thermal properties. This study aimed to investigate the influences of textile fabrics on sleep under different ambient temperature (Ta conditions. Seventeen healthy young participants (ten males underwent nine nights of polysomnography testing including an adaptation night. Participants were randomized to each of the three binary factors: sleepwear (cotton vs wool, bedding (polyester vs wool, and Ta (17°C vs 22°C with relative humidity set at 60%. Skin temperature (Tsk and core temperature (Tc were monitored throughout the sleep period. Sleep onset latency (SOL was significantly shortened when sleeping in wool with trends of increased total sleep time and sleep efficiency compared to cotton sleepwear. At 17°C, the proportion of sleep stages 1 (%N1 and 3 (%N3 and rapid eye movement sleep was higher, but %N2 was lower than at 22°C. Interaction effects (sleepwear × Ta showed a significantly shorter SOL for wool than cotton at 17°C but lower %N3 for wool than cotton at 22°C. A significantly lower %N2 but higher %N3 was observed for wool at 17°C than at 22°C. There was no bedding effect on sleep. Several temperature variables predicted the sleep findings in a stepwise multiple regression analysis and explained 67.8% of the variance in SOL and to a lesser degree the %N2 and %N3. These findings suggest that sleepwear played a contributory role to sleep outcomes and participants slept better at 17°C than at 22°C.Keywords: cotton, polyester, wool, polysomnography, skin temperature, core body temperature

  13. The dependence of body weight in copepodite stages of Pseudocalanus spp. on variations of ambient temperature and food concentration

    Directory of Open Access Journals (Sweden)

    Lidia Dzierzbicka-Głowacka

    2004-03-01

    Full Text Available Quantitative expressions are presented describing the effects of temperature and food concentration on the mean body weight of copepodite stages of Pseudocalanus spp. The calculations were made on the basis of experimental data from the literature for three geographically separate populations of Pseudocalanus from Puget Sound (Washington, USA, from the southern North Sea and the Baltic Sea. Relationships were obtained between the coefficient of daily exponential growth of body weight of Pseudocalanus sp. from Puget Sound and temperature in the 8-15.5oC range and food concentrations from 10 mgC m-3 to excess, as well as for Pseudocalanus elongatus from the southern North Sea at high food concentrations and in the 4-15oC temperature range. Also computed was the mean body weight for stages CII to CV of P. elongatus from the southern Baltic Sea at 5oC. The empirical models presented here can be used with good precision in mathematical models of pelagic communities. The results presented here indicate that Pseudocalanus sp. from Puget Sound (a species resembling Pseudocalanus minutus is similar to P. elongatus from the southern North Sea and the English Channel with respect to growth parameters in the studied range of temperatures for excess food. P. elongatus collected in the Baltic Sea (Gulf of Gdańsk differs from P. elongatus from the southern North Sea.

  14. Palladium-Catalyzed Nitration of Meyer-Schuster Intermediates with tBuONO as Nitrogen Source at Ambient Temperature.

    Science.gov (United States)

    Lin, Yuanguang; Kong, Weiguang; Song, Qiuling

    2016-08-01

    A novel domino palladium-catalyzed nitration of Meyer-Schuster intermediates which were generated in situ from propargylic alcohols was developed, by the use of t-BuONO, leading to α-nitro enones in good to excellent yields at room temperature with a broad functional group tolerance. PMID:27434133

  15. High-T(sub c) Superconductor-Normal-Superconductor Junctions with Polyimide-Passivated Ambient Temperature Edge Formation

    Science.gov (United States)

    Barner, J. B.; Kleinsasser, A. W.; Hunt, B. D.

    1996-01-01

    The ability to controllably fabricate High-Temperature Superconductor (HTS) S-Normal-S (SNS) Josephson Juntions (JJ's) enhances the possibilities fro many applications, including digital circuits, SQUID's, and mixers. A wide variety of approaches to fabricating SNS-like junctions has been tried and analyzed in terms of proximity effect behavior.

  16. Effects of relative humidity and ambient temperature on the ballistic delivery of micro-particles to excised porcine skin.

    Science.gov (United States)

    Kendall, Mark; Rishworth, Stephen; Carter, Fiona; Mitchell, Thomas

    2004-03-01

    The effectiveness of ballistic particle delivery to the skin is often dependent upon breaching the stratum corneum (SC) and targeting cells within defined layers of the viable epidermis. This paper experimentally determines the influence of relative humidity (RH) and temperature on the ballistic delivery of particles to the skin. Gold particles of radius 0.9+/-0.6 microm were accelerated by a hand-held supersonic device to impact freshly excised porcine skin at 410-665 m per s. Increasing the RH from 15% to 95% (temperature at 25 degrees C) led to a particle penetration increase by a factor of 1.8. Temperature increases from 20 degrees C to 40 degrees C (RH at 15%) enhanced particle penetration 2-fold. In both cases, these increases were sufficient to move the target layer from the SC to the viable epidermis. Relative trends in particle penetration compared well with predictions from a theoretical model well. Calculated absolute penetration depths are 6-fold greater than the measurements. The inversely calculated dynamic yield stress of the SC is up to a factor of 10 higher than reported quasi-static measurements, due to changes in tissue failure modes over a strain-rate range spanning 10 orders of magnitude. If targeted particle delivery is required, it is recommended that the environmental RH and temperature be monitored.

  17. Experimental Study of Ambient Air Temperature Effects on The Performance of a General Vapor-Compression Refrigeration Cycle

    Directory of Open Access Journals (Sweden)

    Ayad T. Mustafa

    2013-05-01

    Full Text Available         In this work an experimental study for the vapor – compression refrigeration cycle has been performed under temperature range of  9.7-32°C. The effect of      varying temperature on heat exchangers pressures, cooling capacity, net power consumption, and coefficient of performance COP are studied .                                   The results indicated that condenser pressure, evaporator pressure, and power consumption increased with the increase of temperature. The data also indicated that cooling capacity increased as temperature increased until 15.6°C then after it decreased with further temperature increase. Also COP follow the same tread of cooling capacity.                                                                                                              

  18. Periodic usage of low-protein methionine-fortified diets in broiler chickens under high ambient temperature conditions: effects on performance, slaughter traits, leukocyte profiles and antibody response

    Science.gov (United States)

    Ghasemi, Hossein Ali; Ghasemi, Rohollah; Torki, Mehran

    2014-09-01

    This study was performed to evaluate the effects of adding methionine supplements to low-protein diets and subsequent re-feeding with a normal diet on the productive performance, slaughter parameters, leukocyte profiles and antibody response in broiler chickens reared under heat stress conditions. During the whole experimental period (6-49 days), the birds were raised in battery cages located in high ambient temperature in an open-sided housing system. A total of 360 6-day-old male chickens were divided into six treatments in six replicates with ten chicks each. Six isoenergetic diets, with similar total sulfur amino acids levels, were formulated to provide 100 and 100 (control), 85 and 100 (85S), 70 and 100 (70S), 85 and 85 (85SG), 70 and 85 (70S85G), and 70 and 70 % (70SG) of National Research Council recommended levels for crude protein during the starter (6-21 day) and grower (22-42 day) periods, respectively. Subsequently, all groups received a diet containing the same nutrients during the finisher period (43-49 day). The results showed that, under heat stress conditions, average daily gain and feed conversion ratio and performance index from day 6 to 49, breast and thigh yields and antibody titer against Newcastle disease in the birds fed diets 85S, 70S and 85SG were similar to those of birds fed control diet, whereas feeding diets 70S85G and 70SG significantly decreased the values of above-mentioned parameters. Additionally, diets 85S, 70S and 85SG significantly decreased mortality rate and heterophil:lymphocyte ratio compared with the control diet. In conclusion, the results indicate that supplementation of methionine to diets 85S, 70S and 85SG, and then re-feeding with a conventional diet is an effective tool to maintain productive performance and to improve health indices and heat resistance in broilers under high ambient temperature conditions.

  19. Room temperature synthesis of an optically and thermally responsive hybrid PNIPAM-gold nanoparticle

    Energy Technology Data Exchange (ETDEWEB)

    Morones, J. Ruben, E-mail: morones@bu.ed [Boston University, Department of Biomedical Engineering (United States); Frey, Wolfgang, E-mail: wfrey@mail.utexas.ed [University of Texas at Austin, Department of Biomedical Engineering (United States)

    2010-05-15

    Composites of metal nanoparticles and environmentally sensitive polymers are useful as nanoactuators that can be triggered externally using light of a particular wavelength. We demonstrate a synthesis route that is easier than grafting techniques and allows for the in situ formation of individual gold nanoparticles encapsulated by an environmentally sensitive polymer, while also providing a strong interaction between the polymer and the metal particle. We present a one-pot, room-temperature synthesis route for gold metal nanoparticles that uses poly-N-isopropyl acrylamide as the capping and stabilizing agent and ascorbic acid as the reducing agent and achieves size control similar to the most common citric acid synthesis. We show that the composite can be precipitated reversibly by temperature or light using the non-radiative decay and conversion to heat of the surface plasmon resonance of the metal nanoparticle. The precipitation is induced by the collapse of the polymer cocoon surrounding each gold nanoparticle, as can be seen by surface plasmon spectroscopy. The experiments agree with theoretical models for the heat generation in a colloidal suspension that support fast switching with low laser power densities. The synthesized composite is a simple nanosized opto-thermal switch.

  20. Increased upper critical field for nanocrystalline MoN thin films deposited on AlN buffered substrates at ambient temperature

    Science.gov (United States)

    Baskaran, R.; Thanikai Arasu, A. V.; Amaladass, E. P.; Vaidhyanathan, L. S.; Baisnab, D. K.

    2016-05-01

    Molybdenum nitride (MoN) thin films have been deposited using reactive DC magnetron sputtering on aluminum nitride buffered oxidized silicon substrates at ambient temperature. GIXRD of aluminum nitride (AlN) deposited under similar conditions has revealed the formation of wurtzite phase AlN. GIXRD characterization of molybdenum thin films deposited on AlN buffered oxidized silicon substrates has indicated the formation of nanocrystalline MoN thin films. The electrical resistivity measurements indicate MoN thin films have a superconducting transition temperature of ~8 K. The minimum transition width of the MoN thin film is 0.05 K at 0 T. The inferred upper critical field B c2(0) for these nanocrystalline MoN thin films obtained by fitting the temperature dependence of critical field with Werthamer, Helfand and Hohenberg theory lies in the range of 17-18 T which is the highest reported in literature for MoN thin films.

  1. Synthesis and characterization of boron-oxygen-hydrogen thin films at low temperatures

    International Nuclear Information System (INIS)

    We have studied the influence of synthesis temperature on chemical composition and mechanical properties of X-ray amorphous boron-oxygen-hydrogen (B-O-H) films. These B-O-H films have been synthesized by RF sputtering of a B-target in an Ar atmosphere. Upon increasing the synthesis temperature from room temperature to 550 deg. C, the O/B and H/B ratios decrease from 0.73 to 0.15 and 0.28 to 0.07, respectively, as determined by elastic recoil detection analysis. It is reasonable to assume that potential sources of O and H are residual gas and laboratory atmosphere. The elastic modulus, as measured by nanoindentation, increases from 93 to 214 GPa, as the O/B and H/B ratios decreases within the range probed. Hence, we have shown that the effect of impurity incorporation on the elastic properties is extensive and that the magnitude of the incorporation is a strong function of the substrate temperature

  2. Ethylene glycol assisted low-temperature synthesis of boron carbide powder from borate citrate precursors

    Directory of Open Access Journals (Sweden)

    Rafi-ud-din

    2014-09-01

    Full Text Available B4C powders were synthesized by carbothermal reduction of ethylene glycol (EG added borate citrate precursors, and effects of EG additions (0–50 mol% based on citric acid on the morphologies and yields of synthesized B4C powders were investigated. The conditions most suitable for the preparation of precursor were optimized and optimum temperature for precursor formation was 650 °C. EG additions facilitated low-temperature synthesis of B4C at 1350 °C, which was around 100–300 °C lower temperature compared to that without EG additions. The lowering of synthesis temperature was ascribed to the enlargement of interfacial area caused by superior homogeneity and dispersibility of precursors enabling the diffusion of reacting species facile. The 20% EG addition was optimal with free residual carbon lowered to 4%. For smaller EG additions, the polyhedral and rod-like particles of synthesized product co-existed. With higher EG additions, the morphology of synthesized product was transformed into needle and blade-like structure.

  3. Impact of synthesis temperature on hydrogen storage and emission from Ni/Ce composite oxides

    Energy Technology Data Exchange (ETDEWEB)

    Tang, Leung P.; Diamond, Louise; MacDonald, Marion; McMillan, Brian G.; Morrow, James; Spicer, Mark D.; Berlouis, Leonard E.A. [WestCHEM, Department of Pure and Applied Chemistry, University of Strathclyde, 295 Cathedral Street, Glasgow G1 1XL (United Kingdom); Weston, Michael [ITI Energy, The Exchange No.1, 62 Market Street, Aberdeen AB11 5PJ (United Kingdom)

    2009-09-15

    Hydrogen storage and emission from Ni/Ce (0.1:1) composite oxides, prepared by the co-precipitation method at -2 C, 22 C and 60 C using triethylamine as the precipitating agent, are investigated. The as-prepared uncalcined materials exhibit small amounts of H{sub 2} emission even without prior exposure to H{sub 2}, with the amount dependent on the synthesis temperature. Examination of the CO, CO{sub 2} and H{sub 2}O emission profiles suggest a link between the presence and stability of carbonate species within these composite materials and the H{sub 2} emission. Following activation in pure hydrogen at 250 C, all samples show increased H{sub 2} emission levels but it is only in the sample synthesised at 60 C that a simultaneous decrease in the H{sub 2} emission temperature is found. H{sub 2}O emission below 250 C in the activated material indicates that this also originates from hydrogen stored in the material. The activation conditions are shown to have a significant impact on the level of H{sub 2} interaction with these materials. A marked increase of the crystallite size with synthesis temperature, from 1.7 nm at -2 C to 11.7 nm at 60 C, is also found. The difference in of H{sub 2} interaction is associated with a change in the nature/morphology of the materials precipitated at the different temperatures. (author)

  4. Design and construction of a heat stage for investigations of samples by atomic force microscopy above ambient temperatures

    DEFF Research Database (Denmark)

    Bækmark, Thomas Rosleff; Bjørnholm, Thomas; Mouritsen, Ole G.

    1997-01-01

    The construction from simple and cheap commercially available parts of a miniature heat stage for the direct heating of samples studied with a commercially available optical-lever-detection atomic force microscope is reported. We demonstrate that by using this heat stage, atomic resolution can be...... be obtained on highly oriented pyrolytic graphite at 52 °C. The heat stage is of potential use for the investigation of biological material at physiological temperatures. ©1997 American Institute of Physics....

  5. Tensile deformation behaviors of Zircaloy-4 alloy at ambient and elevated temperatures: In situ neutron diffraction and simulation study

    Science.gov (United States)

    Li, Hongjia; Sun, Guangai; Woo, Wanchuck; Gong, Jian; Chen, Bo; Wang, Yandong; Fu, Yong Qing; Huang, Chaoqiang; Xie, Lei; Peng, Shuming

    2014-03-01

    Tensile stress-strain relationship of a rolled Zircaloy-4 (Zr-4) plate was examined in situ using a neutron diffraction method at room temperature (RT, 25 °C) and an elevated temperature (250 °C). Variations of lattice strains were obtained as a function of macroscopic bulk strains along prismatic (101¯0), basal (0 0 0 2) and pyramidal (101¯1) planes in the hexagonal close-packed structure of the Zr-4. The mechanisms of strain responses in these three major planes were simulated using elastic-plastic self-consistent (EPSC) model based on Hill-Hutchinson method, thus the inter-granular stresses and deformation systems of each individual grain under loading were obtained. Results show that there is a good agreement between the EPSC modeling and neutron diffraction measurements in terms of macroscopic stress-strain relationship and lattice strain evolutions of the planes at RT. However, there is a slight discrepancy in the lattice strains obtained from the EPSC modeling and neutron diffraction when the specimen was deformed at 250 °C. Analysis of grain structure and texture obtained using electron back-scattered diffraction suggests that dynamic recovery process is significant during the tensile deformation at the elevated temperature, which was not considered in the simulation.

  6. Modificações nas atividades da poligalacturonase e pectinametilesterase em morangos armazenados a temperatura ambiente Modifications in the activities of poligalacturonase and pectinametilesterase in stored strawberries the ambient temperature

    Directory of Open Access Journals (Sweden)

    Polyanna Alves Silva

    2009-01-01

    Full Text Available Objetivou-se, neste trabalho, avaliar as modificações da poligalacturonase (PG e da pectinametilesterase (PME em morangos cultivados na região de Lavras, MG, e armazenados em temperatura ambiente. Foram utilizados morangos das cultivares 'Oso-grande', 'Toyorrinho' e 'Tudla'. Utilizou-se o delineamento inteiramente casualizado com 4 repetições, sendo os tratamentos arranjados em esquema fatorial (3X2, sendo 3 cultivares e 2 dias de análises (0 e 5 dias. A parcela experimental foi constituída por 10 frutos. Durante o armazenamento houve uma diminuição nos teores de pectina total e um aumento nos de pectina solúvel em todas as variedades analisadas. A atividade da PG e PME aumentaram com o período de armazenamento, independente da cultivar.The objective of this research was to evaluate the modifications of the polygalacturonase (PG and the pectinmethilesterase (PME in strawberries cultivated in the region of Lavras, MG, and stored at room temperature. Strawberries of the research were used for plantation of 'Oso-grande', 'Toyorrinho' and 'Tudla'. The entirely randomized design with 4 replicates was used, being the treatments arranged in factorial (3x2, being 3 plantations and 2 days of analyses (0 and 5 days. The experimental parcel was consisted by 10 fruits. During the storage there was a reduction in the levels of total pectin and an increase in the ones of soluble pectin in all the analyzed varieties. With the period of storage the PG and PME activity grew, independent of the cultivar.

  7. Temperature induced size selective synthesis of hybrid Cds/pepsin nanocrystals and their photoluminescence investigation

    Energy Technology Data Exchange (ETDEWEB)

    Keshari, Ashish K., E-mail: jeevaneshk26@yahoo.co.i [Nanophosphor Application Centre, University of Allahabad, Allahabad 211002 (India); Department of Physics, University of Allahabad, Allahabad 211002 (India); Singh, Prashant K. [Centre for Biotechnology, University of Allahabad, Allahabad 211002 (India); Parashar, Vyom [Nanophosphor Application Centre, University of Allahabad, Allahabad 211002 (India); Pandey, Avinash C. [Nanophosphor Application Centre, University of Allahabad, Allahabad 211002 (India); Department of Physics, University of Allahabad, Allahabad 211002 (India)

    2010-02-15

    There is growing interest in materials chemistry for taking advantage of the physical and chemical properties of biomolecules in the development of next generation nanoscale materials for opto-electronic applications. A biomimetic approach to materials synthesis offers the possibility of controlling size, shape, crystal structure, orientation, and organization. The great progress has been made in the control that can be exerted over optical materials synthesis using biomolecules (protein, nucleic acid)/mineral interfaces as templates for directed synthesis. We have synthesized the CdS nanocrystals using pepsin by biomimetic technique at four different set temperatures. X-ray diffraction (XRD) and small angle X-ray scattering (SAXS) results showed that we are able to tune the size and distribution profile just by tuning the reaction (Rx) temperature and goes towards excitonic Bhor radius (2.5 nm) at low temperature (4 deg. C). The narrow absorption peak at 260 nm from Cd{sup 2+}-pepsin complex dominates and indicates the size dispersion of the modified CdS nanoparticles are fairly monodisperse. Effective mass approximation (EMA) shows large blue-shift (approx1 eV) in the band gap for the cubic phase from bulk hexagonal CdS. The photoluminescence (PL) and photoluminescence excitation (PLE) spectra are dominated by a strong and narrow band-edge emission tunable in the blue region indicating a narrow size distribution. The reduction in PL efficiency is observed when the Rx temperature increases however no change in PLE spectra and temporal profiles of the band-edge PL is observed. At 4 deg. C, high emission efficiency with shift of PL spectrum in the violet region is observed for 1.7 nm size CdS quantum dots (QDs). Presence of pepsin has slowed the PL decay which is of the order of 100 mus.

  8. A review of nanostructured lithium ion battery materials via low temperature synthesis.

    Science.gov (United States)

    Chen, Jiajun

    2013-01-01

    Nanostructured materials afford us new opportunities to improve the current technology for synthesizing Li ion batteries. Generating nanomaterials with new properties via an inexpensive approach offers a tremendous potential for realizing high performance Li-ion batteries. In this review, I mainly summarize some of the recent progress made, and describe the patents awarded on synthesizing nanostructured cathode materials for these batteries via low temperature wet- chemistry methods. From an economical view, such syntheses, especially hydrothermal synthesis, may offer the opportunities for significantly lowering the cost of manufacturing battery materials, while conferring distinct environmental advantages. Recent advances in in-situ (real time) X-ray diffraction for studying hydrothermal synthesis have great potential for bettering the rational design of advanced lithium-electrode materials. The development of this technique also will be discussed.

  9. Production of advanced materials by methods of self-propagating high-temperature synthesis

    CERN Document Server

    Tavadze, Giorgi F

    2013-01-01

    This translation from the original Russian book outlines the production of a variety of materials by methods of self-propagating high-temperature synthesis (SHS). The types of materials discussed include: hard, refractory, corrosion and wear-resistant materials, as well as other advanced and speciality materials. The authors address the issue of optimal parameters for SHS reactions occurring during processes involving a preliminary metallothermic reduction stage, and they calculate this using thermodynamic approaches. In order to confirm the effectiveness of this approach, the authors describe experiments focussing on the synthesis of elemental crysalline boron, boron carbides and nitrides. Other parts of this brief include theoretical and experimental results on single-stage production of hard alloys on the basis of titanium and zirconium borides, as well as macrokinetics of degassing and compaciton of SHS-products.This brief is suitable for academics, as well as those working in industrial manufacturing com...

  10. Synthesis of nano-scale silicon wires by excimer laser ablation at high temperature

    Science.gov (United States)

    Yu, D. P.; Lee, C. S.; Bello, I.; Sun, X. S.; Tang, Y. H.; Zhou, G. W.; Bai, Z. G.; Zhang, Z.; Feng, S. Q.

    1998-02-01

    We report below synthesis of nano-scale silicon wires by using laser ablation at high temperature. By this approach we have been able to produce silicon nano wires (SiNW's) with a very high yield, a uniform diameter distribution and a high purity. The structure, morphology and chemical composition of the SiNWs have been characterized by using high resolution X-ray diffraction (XRD), high resolution electron microscopy (HREM), as well as spectroscopy of energy dispersive X-ray fluorescence (EDAX). Our results should be of great interest to researchers working on mesoscopic physical phenomena, such as quantum confinement effects related to materials of reduced dimensions and should lead to the development of new applications for nano-scale devices, together with providing a powerful method for synthesis of similar one-dimensional conducting and semi-conducting wire.

  11. Unraveling the complexity of iron oxides at high pressure and temperature: Synthesis of Fe5O6.

    Science.gov (United States)

    Lavina, Barbara; Meng, Yue

    2015-06-01

    The iron-oxygen system is the most important reference of rocks' redox state. Even as minor components, iron oxides can play a critical role in redox equilibria, which affect the speciation of the fluid phases chemical differentiation, melting, and physical properties. Until our recent finding of Fe4O5, iron oxides were assumed to comprise only the polymorphs of FeO, Fe3O4, and Fe2O3. Combining synthesis at high pressure and temperature with microdiffraction mapping, we have identified yet another distinct iron oxide, Fe5O6. The new compound, which has an orthorhombic structure, was obtained in the pressure range from 10 to 20 GPa upon laser heating mixtures of iron and hematite at ~2000 K, and is recoverable to ambient conditions. The high-pressure orthorhombic iron oxides Fe5O6, Fe4O5, and h-Fe3O4 display similar iron coordination geometries and structural arrangements, and indeed exhibit coherent systematic behavior of crystallographic parameters and compressibility. Fe5O6, along with FeO and Fe4O5, is a candidate key minor phase of planetary interiors; as such, it is of major petrological and geochemical importance. We are revealing an unforeseen complexity in the Fe-O system with four different compounds-FeO, Fe5O6, Fe4O5, and h-Fe3O4-in a narrow compositional range (0.75 buffers at conditions of the Earth's mantle can be defined. PMID:26601196

  12. The Influence of Synthesis Temperature on the Structure, Composition and Magnetic Properties of Nanocomposites NiCo/C

    Directory of Open Access Journals (Sweden)

    D.G. Muratov

    2015-12-01

    Full Text Available By method of IR-pyrolysis the precursor of polyacrylonitrile and compounds of cobalt and nickel metalcarbon nanocomposites were obtained, representing nanoparticles of alloy NiCo, dispersed in nanocrystalline carbon matrix. NiCo / C nanocomposites are ferromagnets. Magnetization and the coercive force depends on the size and composition of the alloy nanoparticles NiCo. The average size of metal nanoparticles is determined by the synthesis temperature and in range of 350-800 °C is 10-80 nm, respectively. According to the results of TEM it was detected that with increasing synthesis temperature the maximum synthesis of nanoparticles size distribution shifts to larger sizes. The magnetization and coercivity depend on the size and composition of the nanoparticles of alloy NiCo. With increasing synthesis temperature from 350 to 800 °C the magnetization increases from 0.055 to 17 A·m2/kg.

  13. Influence of ageing on the quasistatic fracture toughness of an SS 316(N) weld at ambient and elevated temperatures

    Science.gov (United States)

    Sasikala, G.; Ray, S. K.

    2011-01-01

    The leak before break analysis of SS 316L(N) components of the prototype fast breeder reactor requires the elastic plastic fracture toughness parameter J for 0.2 mm crack extension, J0.2, especially for the welds, at the operating temperatures. The J- R curves for the welds produced using the consumable developed by Indira Gandhi Centre for Atomic Research, were determined in the as-welded condition as well as after thermal ageing (923 K/4200 h) conditions at 298 K and 643 K, using unloading compliance method for 298 K and normalization method for 643 K. The aged material exhibited pop-in crack extensions of magnitudes that, according to ASTM E1820 standard, could be ignored for multi-specimen data analysis for determining J0.2. Therefore, for this condition, J nom- Δ a curves were established using the multiple specimen method and also single specimen normalization method; for the latter, a modification earlier developed by the authors for accounting for small pop-in crack extensions was used. The value of J0.2 from both methods showed excellent reproducibility. Ageing is seen to reduce the toughness of this material considerably at both the testing temperatures.

  14. Plasma synthesis of nanopowders

    Energy Technology Data Exchange (ETDEWEB)

    Vollath, Dieter, E-mail: dieter.vollath@nanoconsulting.d [NanoConsulting (Germany)

    2008-12-15

    There is a huge variety of plasma processes for synthesis of nanoparticulate powders. They may be grouped with respect to operating temperature, which is the essential parameter with respect to the properties of the products. In view of industrial production, the highest degree of maturity is found in high temperature processes working under ambient pressure. For products, where well-defined properties are demanded, low temperature microwave plasma processes are best suited. Additionally, these processes allow coating of the produced particles, even with organic phases. Other processes where plasmas are involved, such as laser or flame processes coupled with electric fields have, to some extent, a high potential for development.

  15. Direct detection of fatty acid ethyl esters using low temperature plasma (LTP) ambient ionization mass spectrometry for rapid bacterial differentiation.

    Science.gov (United States)

    Zhang, J Isabella; Costa, Anthony B; Tao, W Andy; Cooks, R Graham

    2011-08-01

    Low temperature plasma mass spectrometry (LTP-MS) was employed to detect fatty acid ethyl esters (FAEE) from bacterial samples directly. Positive ion mode FAEE mass spectrometric profiles of sixteen different bacterial samples were obtained without extraction or other sample preparation. In the range m/z 200-300, LTP mass spectra show highly reproducible and characteristic patterns. To identify the FAEE's associated with the characteristic peaks, accurate masses were recorded in the full scan mode using an LTQ/Orbitrap instrument, and tandem mass spectrometry was performed. Data were examined by principal component analysis (PCA) to determine the degree of differentiation possible amongst different bacterial species. Gram-positive and gram-negative bacteria are readily distinguished, and 11 out of 13 Salmonella strains show distinctive patterns. Growth media effects are observed but do not interfere with species recognition based on the PCA results. PMID:21706093

  16. Occurrence of gaseous and particulate polycyclic aromatic hydrocarbons in the urban atmosphere: study of sources and ambient temperature effect on the gas/particle concentration and distribution

    Energy Technology Data Exchange (ETDEWEB)

    Tsapakis, Manolis [Environmental Chemical Processes Laboratory (ECPL), Department of Chemistry, University of Crete, EL-71409 Heraklion (Greece); Stephanou, Euripides G. [Environmental Chemical Processes Laboratory (ECPL), Department of Chemistry, University of Crete, EL-71409 Heraklion (Greece)]. E-mail: stephanou@chemistry.uoc.gr

    2005-01-01

    The presence of polycyclic aromatic hydrocarbons (PAHs) in an urban region (Heraklion, Greece) and processes that govern their atmospheric fate were studied from November 2000 until February 2002. Sixteen samples were collected, by using an artifact-free sampling device, on a monthly basis and the concentration of PAHs in gas and particulate phase was determined. The most abundant members (gas + particles) were phenanthrene (20.0 {+-} 7.0 ng m{sup -3}), fluoranthene (6.5 {+-} 1.7 ng m{sup -3}), pyrene (6.6 {+-} 2.4 ng m{sup -3}), and chrysene (3.1 {+-} 1.5 ng m{sup -3}). Total concentration (gas + particulate) of PAH ranged from 44.3 to 129.2 ng m{sup -3}, with a mean concentration of 79.3 ng m{sup -3}. Total concentration of PAHs in gas phase ranged from 31.4 to 84.7 ng m{sup -3} with non-observable seasonal variation. Conversely, maximum PAH concentrations in the particulate phase occurred during winter months. Particulate concentration varied from 11.4 to 44.9 ng m{sup -3}, with an average of 25.2 ng m{sup -3}. PAH distribution between gas and particulate phase was in agreement with the sub-cooled vapor pressure. Shift in gas/particle distribution due to difference in ambient temperature elucidated to some extent the seasonal variation of the concentration of PAHs in particles. - Capsule: Ambient PAH partitioning between gas and particle phases vary between compounds and with environmental conditions.

  17. The effects of fabric for sleepwear and bedding on sleep at ambient temperatures of 17°C and 22°C.

    Science.gov (United States)

    Shin, Mirim; Halaki, Mark; Swan, Paul; Ireland, Angus H; Chow, Chin Moi

    2016-01-01

    The fibers used in clothing and bedding have different thermal properties. This study aimed to investigate the influences of textile fabrics on sleep under different ambient temperature (T a) conditions. Seventeen healthy young participants (ten males) underwent nine nights of polysomnography testing including an adaptation night. Participants were randomized to each of the three binary factors: sleepwear (cotton vs wool), bedding (polyester vs wool), and T a (17°C vs 22°C with relative humidity set at 60%). Skin temperature (T sk) and core temperature (T c) were monitored throughout the sleep period. Sleep onset latency (SOL) was significantly shortened when sleeping in wool with trends of increased total sleep time and sleep efficiency compared to cotton sleepwear. At 17°C, the proportion of sleep stages 1 (%N1) and 3 (%N3) and rapid eye movement sleep was higher, but %N2 was lower than at 22°C. Interaction effects (sleepwear × T a) showed a significantly shorter SOL for wool than cotton at 17°C but lower %N3 for wool than cotton at 22°C. A significantly lower %N2 but higher %N3 was observed for wool at 17°C than at 22°C. There was no bedding effect on sleep. Several temperature variables predicted the sleep findings in a stepwise multiple regression analysis and explained 67.8% of the variance in SOL and to a lesser degree the %N2 and %N3. These findings suggest that sleepwear played a contributory role to sleep outcomes and participants slept better at 17°C than at 22°C. PMID:27217803

  18. The Effect of Seasonal Ambient Temperatures on Fire-Stimulated Germination of Species with Physiological Dormancy: A Case Study Using Boronia (Rutaceae)

    Science.gov (United States)

    Auld, Tony D.; Keith, David A.; Hui, Francis K. C.; Ooi, Mark K. J.

    2016-01-01

    Dormancy and germination requirements determine the timing and magnitude of seedling emergence, with important consequences for seedling survival and growth. Physiological dormancy is the most widespread form of dormancy in flowering plants, yet the seed ecology of species with this dormancy type is poorly understood in fire-prone vegetation. The role of seasonal temperatures as germination cues in these habitats is often overlooked due to a focus on direct fire cues such as heat shock and smoke, and little is known about the combined effects of multiple fire-related cues and environmental cues as these are seldom assessed in combination. We aimed to improve understanding of the germination requirements of species with physiological dormancy in fire-prone floras by investigating germination responses across members of the Rutaceae from south eastern Australia. We used a fully factorial experimental design to quantify the individual and combined effects of heat shock, smoke and seasonal ambient temperatures on germination of freshly dispersed seeds of seven species of Boronia, a large and difficult-to-germinate genus. Germination syndromes were highly variable but correlated with broad patterns in seed morphology and phylogenetic relationships between species. Seasonal temperatures influenced the rate and/or magnitude of germination responses in six species, and interacted with fire cues in complex ways. The combined effects of heat shock and smoke ranged from neutral to additive, synergistic, unitive or negative and varied with species, seasonal temperatures and duration of incubation. These responses could not be reliably predicted from the effect of the application of single cues. Based on these findings, fire season and fire intensity are predicted to affect both the magnitude and timing of seedling emergence in wild populations of species with physiological dormancy, with important implications for current fire management practices and for population

  19. Low Temperature Synthesis of Graphene on Cu(111) from CH4 via Chemical Vapor Deposition

    Science.gov (United States)

    Jacobberger, Robert; Xu, Feng; Wu, Meng-Yin; Arnold, Michael

    2014-03-01

    We report the low temperature CVD synthesis of high-quality, monolayer graphene on epitaxial Cu(111) thin films. The growth temperature of 750 ° C used in this work is around 150 °C lower than previous reports of continuous graphene growth using CH4 as the carbon precursor. Conditions that yield continuous films on Cu(111) result in sub-monolayer coverage on Cu(110) and Cu(100). This demonstrates that Cu(111) is a more effective graphene catalyst than Cu(100), which is predominately used in literature. The single crystal orientation of the Cu(111) thin films allows us to control the graphene orientation over large areas. Field effect measurements show ambipolar carrier behavior and electron and hole mobilities of 2500 cm2/Vs. The Dirac point is near 0 V and the sheet resistance is 2 k Ω/ □. Raman imaging reveals a negligible D:G ratio, indicating a low level of defects in these samples. We find that the graphene becomes more defective on all Cu facets with increasing growth rate. Optical transmittance of 97% over the visible spectrum confirms that the graphene is monolayer. This low temperature synthesis will help enable industrial scale fabrication of high-quality, continuous graphene films.

  20. Effect of temperature during the spray pyrolysis synthesis of silver nanopowder

    International Nuclear Information System (INIS)

    We report the results of the synthesis and characterization of Ag, AgO, AgNO3 nanopowders or mixtures of them, obtained by spray pyrolysis technique. An aqueous solution of AgNO3 with a concentration of 0.2 mol/L was sprayed through a horizontal tubular furnace where the solvent was evaporated and pyrolytic reaction occurs producing AgNO3, AgO and Ag particles. The synthesis was made at 500, 600 and 700 oC. The obtained material was analyzed by Transmission Electron Microscopy, and the optimal temperature to obtain particles of around 10 nm was 600 oC. The X-rays and Electron Diffraction analysis determined the coexistence of the phases of Ag, AgO and AgNO3, whereas the measurement of x-rays fluorescence the presence of Ag was detected. The solution concentration and the carrier flow, the temperature and the temperature gradient in the furnace influence in the phase and size of the particle.. (author)

  1. Effect of feeding whole linseed as a source of polyunsaturated fatty acids on performance and egg characteristics of laying hens kept at high ambient temperature

    Directory of Open Access Journals (Sweden)

    S Ahmad

    2013-03-01

    Full Text Available The present study was conducted to evaluate the effects of feeding whole linseed on the laying performance and egg characteristics in laying hens kept at high ambient environmental temperatures (average 34 ºC; the diurnal temperature range 26 ºC to 41 ºC. Two hundred and forty 38-wk-old white Leghorn laying hens were fed diets containing 0, 5, 10 or 15% whole linseed (as a source of n-3 polyunsaturated fatty acids for a period of 12 weeks. Egg production was recorded daily, while feed intake and egg characteristics were monitored on weekly basis. The results of the study demonstrated that egg production and feed intake decreased, while feed conversion ratio (FCR per dozen of eggs increased (p 0.05 by linseed levels in the diets offered to the laying hens. The results of the present trial suggest that feeding linseed to the laying hens in hot climates has no detrimental effects on egg characteristics, but has suppressive effects on egg production, feed intake and feed efficiency of laying hens.

  2. Effects of ambient temperature and early open-field response on the behaviour, feed intake and growth of fast- and slow-growing broiler strains

    DEFF Research Database (Denmark)

    Nielsen, Birte Lindstrøm

    2012-01-01

    in an open-field test on day 3 after hatching, fast-growing Ross 208 and slow-growing i657 chickens were allocated on day 13 to one of the 48 groups. Each group included either six active or six passive birds from each strain and the groups were housed in floor-pens littered with wood chips and fitted......Increased activity improves broiler leg health, but also increases the heat production of the bird. This experiment investigated the effects of early open-field activity and ambient temperature on the growth and feed intake of two strains of broiler chickens. On the basis of the level of activity...... with two heat lamps. Each group was fed ad libitum and subjected to one of the three temperature treatments: two (HH; 268C), one (HC; 168C to 268C) or no (CC; 168C) heat lamps turned on. Production and behavioural data were collected every 2 weeks until day 57. For both strains, early open-field activity...

  3. Synthesis of silicon carbide in a nitrogen plasma torch: rotational temperature determination and material analysis

    International Nuclear Information System (INIS)

    Experiments on silicon carbide synthesis were performed using a dc nitrogen plasma torch. Measurements of rotational temperature of nitrogen molecules by emission spectroscopy were performed, based on the band (0, 1) of the first negative system of nitrogen N2+(B2Σu+→X2Σg+) for the R branch. Three different plasma torch powers were studied in order to optimize the production of silicon carbide with our experimental set-up. The synthesized products were characterized by x-ray diffraction, scanning electron microscopy and energy dispersive x-ray spectroscopy

  4. Ignition time of self-propagating high-temperature synthesis by laser

    Institute of Scientific and Technical Information of China (English)

    陈森昌; 迟彦惠; 史玉升; 黄树槐

    2002-01-01

    The ignition of self-propagating high-temperature synthesis (SHS) by a laser beam has very well application, but there is lack in study on the ignition process. In order to search the rule of ignition process with laser beam, ignition time of SHS was studied in detail. First one dimension ignition model was introduced: burning is the process in which one layer is ignited by next layer. Then according to Fourier conduction equation, an equation used to calculate the ignition time was deduced. Finally a series of tests were made to verify the equation. The results prove that the change of the parameters in test agrees well with the equation.

  5. Low-Temperature Synthesis of Actinide Tetraborides by Solid-State Metathesis Reactions

    Energy Technology Data Exchange (ETDEWEB)

    Lupinetti, Anthony J.; Garcia, Eduardo; Abney, Kent D.

    2004-12-14

    The synthesis of actinide tetraborides including uranium tetraboride (UB,), plutonium tetraboride (PUB,) and thorium tetraboride (ThB{sub 4}) by a solid-state metathesis reaction are demonstrated. The present method significantly lowers the temperature required to {approx_equal}850 C. As an example, when UCl{sub 4}, is reacted with an excess of MgB{sub 2}, at 850 C, crystalline UB, is formed. Powder X-ray diffraction and ICP-AES data support the reduction of UCl{sub 3}, as the initial step in the reaction. The UB, product is purified by washing water and drying.

  6. Low temperature solution synthesis of zinc antimonide, manganese antimonide, and strontium ruthenate compounds

    Science.gov (United States)

    Noblitt, Jennifer Lenkner

    2011-12-01

    Increasing energy demands are fueling research in the area of renewable energy and energy storage. In particular, Li-ion batteries and superconducting wires are attractive choices for energy storage. Improving safety, simplifying manufacturing processes, and advancing technology to increase energy storage capacity is necessary to compete with current marketed energy storage devices. These advancements are accomplished through the study of new materials and new morphologies. Increasing dependence on and rising demand for portable electronic devices has continued to drive research in the area of Li-ion batteries. In order to compete with existing batteries and be applicable to future energy needs such as powering hybrid vehicles, the drawbacks of Li-ion batteries must be addressed including (i) low power density, (ii) safety, and (iii) high manufacturing costs. These drawbacks can be addressed through new materials and morphologies for the anode, cathode, and electrolyte. New intermetallic anode materials such as ZnSb, MnSb, and Mn2Sb are attractive candidates to replace graphite, the current industry standard anode material, because they are safer while maintaining comparable theoretical capacity. Electrodeposition is an inexpensive method that could be used for the synthesis of these electrode materials. Direct electrodeposition allows for excellent electrical contact to the current collector without the use of a binder. To successfully electrodeposit zinc and manganese antimonides, metal precursors with excellent solubility in water were needed. To promote solubility, particularly for the antimony precursor, coordinating ligands were added to the deposition bath solutions. This work shows that the choice of coordinating ligand and metal-ligand speciation can alter both the electrochemistry and the film composition. This work focuses on the search for appropriate coordinating ligands, solution pH, and bath temperatures so that high quality films of ZnSb, MnSb, and

  7. Buckling tests on axially compressed cylindrical shells made of various austenitic stainless steels at ambient and elevated temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Hautala, K.; Schmidt, H.

    1998-12-01

    The buckling test program comprised 37 axially loaded cylinders made of austenitic stainless steels and 6 reference cylinders made of mild steel. The three test parameters were the steel grade, the shell slenderness and the operating temperature. The chosen steel grades are typical for practical applications: AISI 304 (No. 1.4301) as the basic austenitic stainless steel, AISI 316 L (No. 1.4404) as a molybdenum alloyed and AISI 316 Ti (No. 1.4571) as a molybdenum and titanium alloyed austenitic stainless steel. The chosen shell slendernesses are typical for the above-mentioned elastic-plastic region: r/t=50, 150 and 400, approximately corresponding to non-dimensional slenderness parameters {lambda}=0.3, 0.5 and 0.9 respectively. The chosen testing temperatures cover a wide range of applications: T=20 C, 100 C, 250 C and 400 C. The test cylinders were manufactured from 3.0 mm, 1.0 mm and 0.5 mm steel sheets, cold rolled into the cylindrical shape and longitudianlly TIG-welded. The radii were 150 mm and 200 mm, the length was 350 mm. (orig.) [German] Das Beulversuchsprogramm bestand aus 37 axialbelasteten Zylindern aus austenitischen rostfreien Staehlen und sechs Referenzzylindern aus Baustahl. Die drei Versuchsparameter waren die Stahlsorte, die Schalenschlankheit und die Betriebstemperatur. Die drei ausgewaehlten Stahlsorten sind typisch fuer baupraktische Anwendungen: WNr. 1.4301 (AISI 304) als einfachster, WNr. 1.4404 (AISI 316L) als ein Molybdaen-legierter und WNr. 1.4571 (AISI 316Ti) als ein Molybdaen- und Titanium-legierter austenitischer rostfreier Stahl. Die ausgewaehlten Schalenschlankheiten sind typisch fuer den oben erwaehnten elastisch-plastischen Bereich: r/t=50, 150 und 400, entsprechend dimensionslosen Schlankheitsparametern von naeherungsweise {lambda}=0.3, 0.5 und 0.9. Die ausgewaehlten Versuchstemperaturen decken ein breites Spektrum von Anwendungen ab: T=20 C, 100 C, 250 C und 400 C. Die Versuchszylinder wurden aus 3 mm, 1 mm, und 0.5 mm

  8. Thermal conductivity of silver loaded conductive epoxy from cryogenic to ambient temperature and its application for precision cryogenic noise measurements

    Science.gov (United States)

    Amils, Ricardo I.; Gallego, Juan Daniel; Sebastián, José Luis; Muñoz, Sagrario; Martín, Agustín; Leuther, Arnulf

    2016-06-01

    The pressure to increase the sensitivity of instrumentation has pushed the use of cryogenic Low Noise Amplifier (LNA) technology into a growing number of fields. These areas range from radio astronomy and deep space communications to fundamental physics. In this context manufacturing for cryogenic environments requires a proper thermal knowledge of the materials to be able to achieve adequate design behavior. In this work, we present experimental measurements of the thermal conductivity of a silver filled conductive epoxy (EPO-TEK H20E) which is widely used in cryogenic electronics applications. The characterization has been made using a sample preparation which mimics the practical use of this adhesive in the fabrication of cryogenic devices. We apply the data obtained to a detailed analysis of the effects of the conductive epoxy in a monolithic thermal noise source used for high accuracy cryogenic microwave noise measurements. In this application the epoxy plays a fundamental role since its limited thermal conductivity allows heating the chip with relatively low power. To our knowledge, the cryogenic thermal conductivity data of this epoxy has not been reported before in the literature in the 4-300 K temperature range. A second non-conductive epoxy (Gray Scotch-Weld 2216 B/A), also widely used in cryogenic applications, has been measured in order to validate the method by comparing with previous published data.

  9. Synthesis and characterization of Cu-MFI catalyst for the direct medium temperature range NO decomposition

    Directory of Open Access Journals (Sweden)

    Valkaj Karolina Maduna

    2016-03-01

    Full Text Available In this study the physico-chemical and catalytic properties of copper bearing MFI zeolites (Cu-MFI with different Si/Al and Si/Cu ratios were investigated. Two different methods for incorporation of metal ions into the zeolite framework were used: the ion exchange from the solution of copper acetate and the direct hydrothermal synthesis. Direct synthesis of a zeolite in the presence of copper-phosphate complexes was expected to generate more active copper species necessary for the desired reaction than the conventional ion exchange method. Direct decomposition of NO was used as a model reaction, because this reaction still offers a very attractive approach to NOX removal. The catalytic properties of zeolite samples were studied using techniques, such as XRD, SEM, EPR and nitrogen adsorption/desorption measurements at 77 K. Results of the kinetic investigation revealed that both methods are applicable for the preparation of the catalysts with active sites capable of catalyzing the NO decomposition. It was found out that Cu-MFI zeolites obtained through direct synthesis are promising catalysts for NO decomposition, especially at lower reaction temperatures. The efficiency of the catalysts prepared by both methods is compared and discussed.

  10. Advances in application potential of adsorptive-type solid state gas sensors: high-temperature semiconducting oxides and ambient temperature GasFET devices

    International Nuclear Information System (INIS)

    This paper reviews some scientific considerations about the underlying material properties and the detailed functional principle of two important types of solid state gas sensors. This is used to predict the application potential of these sensor technologies. The classical methodology to use resistance readout of heated semiconducting metal oxides is a straightforward approach to get robust sensors that are simple in design. The usage of materials that are operated at higher temperatures opens up the way for improvements; due to a change in the mechanism of electrical conductivity, better reproducibility and stability of the electrical properties can be attained. The high operation temperatures also lead to changes in the surface reactions with the gases that allow for quicker equilibration times. The next step is taken when devices are used that are based on the readout of the work function of the sensing materials. Suspended gate FETs here serve as the transducer structures. Surface properties are directly used here, which facilitates the preparation of sensing materials. The sensors can be used with a wide range of sensing materials, allowing the development of receptor materials that optimally fit the target gases. Functional improvements include enhanced selectivity and detection of a wider range of gases. These devices may work at room temperature with little energy required for running them and additionally allow direct access to the structure of the analyte molecule without thermal decomposition. (topical review)

  11. Cardiac-specific knockout of ETA receptor mitigates low ambient temperature-induced cardiac hypertrophy and contractile dysfunction

    Institute of Scientific and Technical Information of China (English)

    Yingmei Zhang; Linlin Li; Yinan Hua; Jennifer M. Nunn; Feng Dong; Masashi Yanagisawa; Jun Ren

    2012-01-01

    Cold exposure is associated with oxidative stress and cardiac dysfunction.The endothelin (ET) system,which plays a key role in myocardial homeostasis,may participate in cold exposure-induced cardiovascular dysfunction.This study was designed to examine the role of ET-1 in cold stress-induced cardiac geometric and contractile responses.Wild-type (WT) and ETA receptor knockout (ETAKO) mice were assigned to normal or cold exposure (4℃) environment for 2 and 5 weeks prior to evaluation of cardiac geometry,contractile,and intracellular Ca2+ properties.Levels of the temperature sensor transient receptor potential vanlllold (TRPV1),mitochondrlal proteins for biogenesis and oxidative phosphorylatlon,Including UCP2,HSP90,and PGC1α were evaluated.Cold stress triggered cardiac hypertrophy,depressed myocardial contractile capacity,including fractional shortening,peak shortening,and maximal velocity of shortening/relengthening,reduced intracellular Ca2+ release,prolonged intracellular Ca2+ decay and relengthening duration,generation of ROS and superoxide,as well as apoptosls,the effects of which were blunted by ETAKO.Western blotting revealed downregulated TRPV1 and PGC1α as well as upregulated UCP2 and activation of GSK3β,GATA4,and CREB in cold-stressed WT mouse hearts,which were obliterated by ETAKO.Levels of HSP90,an essential regulator for thermotolerance,were unchanged.The TRPV1 agonist SA13353 attenuated whereas TRPV1 antagonist capsazepino mimicked cold stress- or ET-1-induced cardiac anomalies.The GSK3β Inhibitor SB216763 ablated cold stress-induced cardiac contractile (but not remodeling) changes and ET-1-induced TRPV1 downregulation.These data suggest that ETAKO protects against cold exposure-induced cardiac remodeling and dysfunction mediated through TRPV1 and mitochondrlal function.

  12. Chemometric optimization of a low-temperature plasma source design for ambient desorption/ionization mass spectrometry

    Science.gov (United States)

    Albert, Anastasia; Engelhard, Carsten

    2015-03-01

    Low-temperature plasmas (LTPs) are attractive sources for atomic and molecular mass spectrometry (MS). In the past, the LTP probe, which was first described by Harper et al., was used successfully for direct molecular mass spectrometric analysis with minimal sample pretreatment in a variety of applications. Unfortunately, the desorption/ionization source itself is commercially not available and custom-built LTP set-ups with varying geometry and operational configurations were utilized in the past. In the present study, a rapid chemometrics approach based on systematic experiments and multivariate data analysis was used to optimize the LTP probe geometry and positioning relative to the atmospheric-pressure inlet of a mass spectrometer. Several parameters were studied including the probe geometry, electrode configuration, quartz tube dimensions, probe positioning and operating conditions. It was found that the plasma-to-MS-inlet distance, the plasma-to-sample-plate distance, and the angle between the latter are very important. Additional effects on the analytical performance were found for the outer electrode width, the positioning of the electrodes, the inner diameter of the quartz tube, the quartz wall thickness, and the gas flow. All experiments were performed using additional heating of the sample to enhance thermal desorption and maximize the signal (T = 150 °C). After software-assisted optimization, attractive detection limits were achieved (e.g., 1.8 × 10- 7 mol/L for 4-acetamidothiophenol). Moreover, relative standard deviation (RSD) improved from values of up to 30% before optimization to < 15% RSD after the procedure was completed. This chemometrics approach for method optimization is not limited to LTP-MS and considered to be attractive for other plasma-based instrumentation as well.

  13. Ambient temperature does not affect fuelling rate in absence of digestive constraints in long-distance migrant shorebird fuelling up in captivity.

    Science.gov (United States)

    Petit, Magali; Vézina, François; Piersma, Theunis

    2010-08-01

    Pre-flight fuelling rates in free-living red knots Calidris canutus, a specialized long-distance migrating shorebird species, are positively correlated with latitude and negatively with temperature. The single published hypothesis to explain these relationships is the heat load hypothesis that states that in warm climates red knots may overheat during fuelling. To limit endogenous heat production (measurable as basal metabolic rate BMR), birds would minimize the growth of digestive organs at a time they need. This hypothesis makes the implicit assumption that BMR is mainly driven by digestive organ size variation during pre-flight fuelling. To test the validity of this assumption, we fed captive knots with trout pellet food, a diet previously shown to quickly lead to atrophied digestive organs, during a fuelling episode. Birds were exposed to two thermal treatments (6 and 24 degrees C) previously shown to generate different fuelling rates in knots. We made two predictions. First, easily digested trout pellet food rather than hard-shelled prey removes the heat contribution of the gut and would therefore eliminate an ambient temperature effect on fuelling rate. Second, if digestive organs were the main contributors to variations in BMR but did not change in size during fuelling, we would expect no or little change in BMR in birds fed ad libitum with trout pellets. We show that cold-acclimated birds maintained higher body mass and food intake (8 and 51%) than warm-acclimated birds. Air temperature had no effect on fuelling rate, timing of fuelling, timing of peak body mass or BMR. During fuelling, average body mass increased by 32% while average BMR increased by 15% at peak of mass and 26% by the end of the experiment. Our results show that the small digestive organs characteristic of a trout pellet diet did not prevent BMR from increasing during premigratory fuelling. Our results are not consistent with the heat load hypothesis as currently formulated. PMID:20339851

  14. Low Temperature Synthesis of a Smart Material for Applications in Microwave Frequency Range

    International Nuclear Information System (INIS)

    Low cost MgMn ferrite nanocrystallites have been produced by simple, reliable and inexpensive method. The decomposition temperature was improved to 200C with less heat of combustion. The hydrolysis of cations and inorganic polymerization govern by the pH value are of fundamental importance in this synthesis. The XRD analysis of the assynthesized powder confirms the formation of the single phase MgMnFe2O4 spinel structure. Importantly, the crystalline particles were obtained at low temperature without any further calcination. The thermodynamic behaviour of the precursor was characterised by TG-DAT. TEM and SEM observations showed the morphology and crystal structure of the nanocrystallites. Their magnetic properties were investigated by PPMS. It was found that there was no maximum dielectric loss within the measured frequency range 1 GHz due to excellent compositional control in this technique.

  15. Experimental Study on Igniting Self-propagating High-temperature Synthesis by Laser

    Institute of Scientific and Technical Information of China (English)

    CHEN Senchang; SHI Yusheng; HUANG Shuhuai

    2002-01-01

    An applied range of self-propagating high-temperature synthesis (SHS) is extended under igniting by laser, but there is no study in detail on its ignition process. The ignition time of SHS by laser is studied in detail in this paper for searching igniting law. A laser beam produced by CO2 laser scans back and forth along a straight line on the surface of a sample, and an ignition time is measured under different testing conditions. The results show that the ignition time is the shortest at certain mixing time, the ignition time is longer with decreasing of the density and increasing of the sample density, and the ignition time becomes shorter when pre-heat temperature rises, but the ignition time has no relation with the area and the thickness of samples when the thickness is thicker, and it has no close relation with shield gas of N2.

  16. Effect of temperature and time on solvothermal synthesis of tetragonal BaTiO3

    Indian Academy of Sciences (India)

    Amir Habib; Nils Stelzer; Paul Angerer; Roland Haubner

    2011-02-01

    Tetragonal BaTiO3 nanoparticles are synthesized via solvothermal route in an ethanol water mixture. Ba(OH)2.8H2O is used as Ba precursor and TiO2 (P25 Degussa ∼25 nm, 30% anatase, 70% rutile) is used as Ti precursor in the Ba : Ti molar ratio 2 : 1. Effect of temperature and time study on solvothermal synthesis of BaTiO3 revealed that a moderate reaction temperature i.e. 185°C and longer reaction time favour tetragonal phase stabilization. Dissolution–precipitation appears to be the transformation mechanism for the crystallization of BaTiO3 from particulate TiO2 precursor.

  17. Self-propagating high temperature synthesis for compound thermoelectrics and new criterion for applicability of combustion processing

    Science.gov (United States)

    Tang, Xinfeng; Su, Xianli; Uher, Ctirad; Tang's Group Team; Uher's Group Team

    2015-03-01

    Here we report compound thermoelectric materials (Bi2Te3, Bi2Se3, Cu2Se,Cu2SnSe3, half-Heusler alloys, lead chalcogenides, skutterudites, and magnesium silicides) with thermoelectric properties comparable with materials prepared by the traditional routes of synthesis can be synthesized at a minimal cost and on the time scale of seconds using the self-propagating high temperature synthesis method. Moreover, we found that the criterion often quoted in the literature as the necessary precondition for combustion synthesis, Tad >= 1800 K, is not universal and certainly not applicable to thermoelectric compound semiconductors. Instead, we offer new empirically-based criterion, Tad /Tm , L >1, i.e., the adiabatic temperature must be high enough to melt the lower melting point component, which covers all materials synthesized by self-propagating high temperature synthesis, including the high temperature refractory compounds for which the Tad >= 1800 K criterion was originally developed. Our work opens a new avenue for ultra-fast, low cost, mass production fabrication of efficient thermoelectric materials and the new criterion greatly broadens the scope of materials that can be successfully synthesized by self-propagating high temperature synthesis. We wish to acknowledge support from the National Basic Research Program of China (973 program) under Project 2013CB632502.

  18. Synthesis and characterization of Ni–Cu alloy nanoparticles with a tunable Curie temperature

    International Nuclear Information System (INIS)

    A series of nickel–copper alloy magnetic nanoparticles with a range of Curie points from 51 °C to 63 °C were prepared by the reduction of intimately mixed nickel and copper oxides in a silica matrix using the sol–gel method. The silica matrix was subsequently removed with an etching solution, assisted by sonication. The alloy nanoparticles were characterized using X-ray diffraction (XRD) analysis, thermogravimetric analysis (TGA/SDTA), thermomagnetic analysis (TMA), transmission electron microscopy (TEM), magnetic measurements (SQUID, vibrating-sample magnetometer) and specific absorption rate measurements (SAR). The synthesized nanoparticles show a size in the range 15–20 nm, exhibited superparamagnetic behavior with a blocking temperature (TB) of approximately 135 K and a room-temperature magnetization of 3–9 emu/g, depending on the composition. The nanoparticles showed a relatively high effective anisotropy constant (Keff) and a significant heating ability in an alternating magnetic field. The synthesis method is straightforward and allows the preparation of homogeneous Ni–Cu alloy nanoparticles with a relatively narrow particle size distribution. - Highlights: • Straightforward so-gel synthesis of homogeneous Ni–Cu alloy nanoparticles. • Narrow particle size distribution and controlled Curie point. • Applications in “self-regulating magnetic fluid hyperthermia”. • Heating efficiency of nanoparticles as a function of composition and size

  19. Self-propagating high temperature synthesis of MoSi2 matrix composites

    Institute of Scientific and Technical Information of China (English)

    FENG Peizhong; QU Xuanhui; Akhtar Farid; S.H. Islam

    2006-01-01

    MoSi2 is presently regarded as the most important material for electrical heating and as one with huge potential for high temperature structural uses. MoSi2 and MoSi2 matrix composites were prepared by self-propagating high temperature synthesis (SHS). Pure MoSi2 was obtained and a compound of MoSi2 and WSi2 was synthesized in the form of predominant solid solution (Mo,W)Si2. By adding aluminum of 5.5 at.% to Mo-Si, the crystal structure of MoSi2 changed into a mixture of tetragonal Cllb MoSi2 and hexagonal C40 Mo(Si,Al)2. The (Mo,W)Si2-Mo(Si,Al)2-W(Si,Al)2 composite materials were synthesized by adding aluminum of 5.5 at.% to Mo-W-Si. However, if the amount of the added aluminum was not larger than 2.5 at.%, it did not have any significant effect. SHS is an effective technology for synthesis of MoSi2 and MoSi2 matrix composites.

  20. Synthesis and characterization of Ni–Cu alloy nanoparticles with a tunable Curie temperature

    Energy Technology Data Exchange (ETDEWEB)

    Ferk, Gregor [Faculty of Chemistry and Chemical Engineering, University of Maribor (Slovenia); Stergar, Janja [Faculty of Medicine, University of Maribor (Slovenia); Makovec, Darko [Department for Materials Synthesis, Jožef Stefan Institute, Ljubljana (Slovenia); Hamler, Anton [Faculty of Electrical Engineering and Computer Science, University of Maribor (Slovenia); Jagličić, Zvonko [Institute of Mathematics, Physics and Mechanics and Faculty of Civil and Geodetic Engineering, University of Ljubljana (Slovenia); Drofenik, Miha [Faculty of Chemistry and Chemical Engineering, University of Maribor (Slovenia); Department for Materials Synthesis, Jožef Stefan Institute, Ljubljana (Slovenia); Ban, Irena [Faculty of Chemistry and Chemical Engineering, University of Maribor (Slovenia); Center of Excellence NAMASTE, Ljubljana (Slovenia)

    2015-11-05

    A series of nickel–copper alloy magnetic nanoparticles with a range of Curie points from 51 °C to 63 °C were prepared by the reduction of intimately mixed nickel and copper oxides in a silica matrix using the sol–gel method. The silica matrix was subsequently removed with an etching solution, assisted by sonication. The alloy nanoparticles were characterized using X-ray diffraction (XRD) analysis, thermogravimetric analysis (TGA/SDTA), thermomagnetic analysis (TMA), transmission electron microscopy (TEM), magnetic measurements (SQUID, vibrating-sample magnetometer) and specific absorption rate measurements (SAR). The synthesized nanoparticles show a size in the range 15–20 nm, exhibited superparamagnetic behavior with a blocking temperature (T{sub B}) of approximately 135 K and a room-temperature magnetization of 3–9 emu/g, depending on the composition. The nanoparticles showed a relatively high effective anisotropy constant (K{sub eff}) and a significant heating ability in an alternating magnetic field. The synthesis method is straightforward and allows the preparation of homogeneous Ni–Cu alloy nanoparticles with a relatively narrow particle size distribution. - Highlights: • Straightforward so-gel synthesis of homogeneous Ni–Cu alloy nanoparticles. • Narrow particle size distribution and controlled Curie point. • Applications in “self-regulating magnetic fluid hyperthermia”. • Heating efficiency of nanoparticles as a function of composition and size.

  1. Synthesis of Li2SiO3 at low temperature

    International Nuclear Information System (INIS)

    The main objective of this work is to develop a new synthesis method to obtain one of the more studied ceramics in this field Li2SiO3) in a simple and economic way using different solutions (urea and ammonium hydroxide). The particular objectives are first to prepare the Li2SiO3 ceramic, by means of the use of the reaction conventional technique in solid state at temperatures between 800 and 900 C to compare it with the one proposed in this work and this way to observe the advantages that it would gives us the new method. Later on, the same one was synthesized lithium ceramic (Li2SiO3) by means of the new method at low temperature (between 80 and 90 C), using silicic acid and lithium hydroxide like precursory reagents and different solutions (urea and ammonium hydroxide) for the optimization in their synthesis. Finally, it was carried out the characterization of these materials by means of X-ray diffraction (XRD), electronic microscopes (SEM and TEM), nitrogen physisorption (method BET) and thermal gravimetric analysis (TGA) to observe the differences that exist among the conventional method and the proposed method and by this way to determine the advantages of the last method. (Author)

  2. Low-temperature Magnesiothermic Synthesis of Mesoporous Silicon Carbide from an MCM-48/Polyacrylamide Nanocomposite Precursor

    Institute of Scientific and Technical Information of China (English)

    Zahra Saeedifar; Amir Abbas Nourbakhsh; Roozbeh Javad Kalbasi; Ebrahim Karamian

    2013-01-01

    Mesoporous silicon carbide with high specific surface area was successfully synthesized from an MCM-48/polyacrylamide nanocomposite precursor in the temperature range of 550-600 ℃ (below the melting point of Mg) by means of a magnesiothermic reduction process.The MCM-48/polyacrylamide precursor nanocomposite was prepared by in-situ polymerization of acrylamide monomer in the presence of mesoporous MCM-48 synthesized by sol-gel method.The physicochemical properties and microstructures of the nanocomposite precursor and the low-temperature SiC product were characterized by X-ray diffraction (XRD),differential scanning calorimetry-thermo gravimetric analysis (DSC-TGA),transmission electron microscopy (TEM) and N2 adsorption-desorption.TEM micrographs and Brunauer-Emmett-Teller (BET) gas adsorption studies showed that the SiC powder was nanocrystalline and had a specific surface area of 330 m2/g and a mesoporosity in the range of 2-10 nm.The presence of an exothermic peak in the DSC trace corresponds to the self-combustion process of the SiC magnesiothermic synthesis.The results also show that the carbon in excess to that required to produce SiC plays a role in the reduction of the SiO2.The mechanism of magnesiothermic synthesis of mesoporous SiC is discussed.

  3. Highly efficient redox isomerization of allylic alcohols at ambient temperature catalyzed by novel ruthenium-cyclopentadienyl complexes--new insight into the mechanism.

    Science.gov (United States)

    Martín-Matute, Belén; Bogár, Krisztián; Edin, Michaela; Kaynak, F Betül; Bäckvall, Jan-E

    2005-10-01

    A range of ruthenium cyclopentadienyl (Cp) complexes have been prepared and used for isomerization of allylic alcohols to the corresponding saturated carbonyl compounds. Complexes bearing CO ligands show higher activity than those with PPh3 ligands. The isomerization rate is highly affected by the substituents on the Cp ring. Tetra(phenyl)methyl-substituted catalysts rapidly isomerize allylic alcohols under very mild reaction conditions (ambient temperature) with short reaction times. Substituted allylic alcohols have been isomerized by employing Ru-Cp complexes. A study of the isomerization catalyzed by [Ru(Ph5Cp)(CO)2H] (14) indicates that the isomerization catalyzed by ruthenium hydrides partly follows a different mechanism than that of ruthenium halides activated by KOtBu. Furthermore, the lack of ketone exchange when the isomerization was performed in the presence of an unsaturated ketone (1 equiv), different from that obtained by dehydrogenation of the starting allylic alcohol, supports a mechanism in which the isomerization takes place within the coordination sphere of the ruthenium catalyst. PMID:16028298

  4. Effect of Dietary L-ascorbic Acid (L-AA) on Production Performance, Egg Quality Traits and Fertility in Japanese Quail (Coturnix japonica) at Low Ambient Temperature.

    Science.gov (United States)

    Shit, N; Singh, R P; Sastry, K V H; Agarwal, R; Singh, R; Pandey, N K; Mohan, J

    2012-07-01

    Environmental stress boosts the levels of stress hormones and accelerates energy expenditure which subsequently imbalance the body's homeostasis. L-ascorbic acid (L-AA) has been recognized to mitigate the negative impact of environmental stress on production performances in birds. The present investigation was carried out to elucidate the effect of different dietary levels of L-AA on production performance, egg quality traits and fertility in Japanese quail at low ambient temperature. Sixty matured females (15 wks) were equally divided into three groups (20/group) based on the different dietary levels of L-AA (0, 250 and 500 ppm) and coupled with an equal number of males (1:1) obtained from the same hatch. They were managed in uniform husbandry conditions without restriction of feed and water at 14 h photo-schedule. Except for feed efficiency, body weight change, feed consumption and hen-day egg production were recorded highest in 500 ppm L-AA supplemented groups. Among the all egg quality traits studied, only specific gravity, shell weight and thickness differed significantly (p<0.05) in the present study. Fertility was improved significantly (p<0.01) to a dose dependent manner of L-AA. The findings of the present study concluded that dietary L-AA can be a caring management practice at least in part to alleviate the adverse effect of cold induced stress on production performance in Japanese quail. PMID:25049657

  5. Imaging hydrothermal systems associated with oceanic ridge: ambient noise and travel-time tomographies in the Reykjanes high-temperature area, SW-Iceland.

    Science.gov (United States)

    Jousset, Philippe; Ágústsson, Kristjan; Verdel, Arie; Blanck, Hanna; Franke, Steven; Specht, Sebastian; Stefánsson, Stefán; Tryggvason, Hörður; Erbas, Kemal; Deon, Fiorenza; Erlendsson, Ögmundur; Guðnason, Egill; Hersir, Gylfi; Ryberg, Trond; Halldórsdóttir, Sæunn; Weemstra, Cornelius; Bruhn, David; Flovenz, Ólafur; Friðleifsson, Ómar

    2015-04-01

    Analogue outcrops of hydrothermal fossil systems and simulating pressure/temperature conditions in the laboratory are classical methods for assessing supercritical conditions in magmatic environments. Scientific drilling is used when Earth surface sampled rocks cannot sufficiently explain past geological processes and when geophysical imaging does not sufficiently explain observed phenomena. However, our understanding of structural and dynamic characteristics of geothermal systems can be improved through application of advanced and/or innovative exploration technologies. Unlike resistivity imaging, active and passive seismic techniques have rarely been used in volcanic geothermal areas, because processing techniques were not adapted to geothermal conditions. Recent advances in volcano-seismology have introduced new processing techniques for assessing subsurface structures and controls on fluid flow in geothermal systems. We present here preliminary analyses of seismic records around a geothermal reservoir located both on-land and offshore along the Reykjanes Ridge, SW-Iceland. We deployed 214 on-land stations and 24 Ocean Bottom Seismometers since April 2014. We analyse more than 6 months of part of those records. We present first results of both travel-time tomography and ambient noise tomography and we discuss briefly implications for geothermal exploration in volcanic contexts.

  6. Chemical composition and source of fine and nanoparticles from recent direct injection gasoline passenger cars: Effects of fuel and ambient temperature

    Science.gov (United States)

    Fushimi, Akihiro; Kondo, Yoshinori; Kobayashi, Shinji; Fujitani, Yuji; Saitoh, Katsumi; Takami, Akinori; Tanabe, Kiyoshi

    2016-01-01

    Particle number, mass, and chemical compositions (i.e., elemental carbon (EC), organic carbon (OC), elements, ions, and organic species) of fine particles emitted from four of the recent direct injection spark ignition (DISI) gasoline passenger cars and a port fuel injection (PFI) gasoline passenger car were measured under Japanese official transient mode (JC08 mode). Total carbon (TC = EC + OC) dominated the particulate mass (90% on average). EC dominated the TC for both hot and cold start conditions. The EC/TC ratios were 0.72 for PFI and 0.88-1.0 (average = 0.92) for DISI vehicles. A size-resolved chemical analysis of a DISI car revealed that the major organic components were the C20-C28 hydrocarbons for both the accumulation-mode particles and nanoparticles. Contribution of engine oil was estimated to be 10-30% for organics and the sum of the measured elements. The remaining major fraction likely originated from gasoline fuel. Therefore, it is suggested that soot (EC) also mainly originated from the gasoline. In experiments using four fuels at three ambient temperatures, the emission factors of particulate mass were consistently higher with regular gasoline than with premium gasoline. This result suggest that the high content of less-volatile compounds in fuel increase particulate emissions. These results suggest that focusing on reducing fuel-derived EC in the production process of new cars would effectively reduce particulate emission from DISI cars.

  7. Application of Simplified Anaerobic Digestion Models (SADM’s for Studying the Biodegradability and Kinetics of Cow Manure at Ambient Temperature

    Directory of Open Access Journals (Sweden)

    Yusuf O.L. MOMOH

    2014-02-01

    Full Text Available The application of a set of simplified anaerobic digestion models (SADM’s to describe the anaerobic biodegradability and kinetics of cow manure at ambient temperature was conducted in this study. It was observed that the Hill’s based biogas yield rate model was the most appropriate in describing biogas yield rate from cow manure. Parameter estimation revealed that the half saturation constant expressed as acidified substrate and volatile solids (VS equivalent were 0.163g/l and 21.9g VS/l respectively while the maximum biogas yield rate was estimated to be 1.957ml/g VS/day. The coefficient of acidogenic bacteria adaptation (n and coefficient of acetogenic/methanogenic bacterial cooperativity (m were estimated to be 1.28 and 0.65 respectively. The poor cooperativity amongst the acetogenic/methanogenic bacterial species can be attributed to poor adaptation, possibly due to interaction between ammonia and volatile fatty acids. In addition, the biodegradability and recalcitrance was estimated to be 0.42 and 0.433 respectively, while hydrolysis/acidogenesis was identified as the rate limiting step.

  8. Effects of dietary DL-2-hydroxy-4(methylthio)butanoic acid supplementation on growth performance, indices of ascites syndrome, and antioxidant capacity of broilers reared at low ambient temperature

    Science.gov (United States)

    Yang, G. L.; Zhang, K. Y.; Ding, X. M.; Zheng, P.; Luo, Y. H.; Bai, S. P.; Wang, J. P.; Xuan, Y.; Su, Z. W.; Zeng, Q. F.

    2016-08-01

    This study examined the effects of dietary DL-2-hydroxy-4(methylthio)butanoic acid (DL-HMTBA) supplementation on growth performance, antioxidant capacity, and ascites syndrome (AS) in broilers reared at low ambient temperature (LAT) from 7 to 28 days of age. Eight hundred 7-day-old broilers were randomly assigned to two ambient temperatures (LAT and normal ambient temperature [NAT]), four supplemental DL-HMTBA levels (0.17, 0.34, 0.51, and 0.68 %) of the basal diet in a 2 × 4 factorial arrangement (ten replicate pens; ten birds/pen). LAT and NAT indicate temperatures of 12-14 and 24-26 °C in two chambers, respectively, and broilers were reared at these temperatures from 7 to 28 days of age. LAT significantly decreased body weight gain ( P activity, and total antioxidant capacity (T-AOC) at 21 days ( P = 0.001, 0.015) and 28 days ( P = 0.017, 0.010) and increased feed conversion ratio (FCR) ( P activities at 21 days of age ( P < 0.001 and P = 0.037). The optimal supplemental DL-HMTBA levels in basal diet of broilers aged from 7 to 28 days under low or normal temperatures were similar, so the authors recommended supplemental of DL-HMTBA level was 0.46 %.

  9. Effect of ambient temperature on the thermoregulatory and locomotor stimulant effects of 4-methylmethcathinone in Wistar and Sprague-Dawley rats.

    Directory of Open Access Journals (Sweden)

    M Jerry Wright

    Full Text Available The drug 4-methylmethcathinone (4-MMC; aka, mephedrone, MMCAT, "plant food", "bath salts" is a recent addition to the list of popular recreational psychomotor-stimulant compounds. Relatively little information about this drug is available in the scientific literature, but popular media reports have driven recent drug control actions in the UK and several US States. Online user reports of subjective similarity to 3,4-methylenedioxymethamphetamine (MDMA, "Ecstasy" prompted the current investigation of the thermoregulatory and locomotor effects of 4-MMC. Male Wistar and Sprague-Dawley rats were monitored after subcutaneous administration of 4-MMC (1-10 mg/kg using an implantable radiotelemetry system under conditions of low (23°C and high (27°C ambient temperature. A reliable reduction of body temperature was produced by 4-MMC in Wistar rats at 23°C or 27°C with only minimal effect in Sprague-Dawley rats. Increased locomotor activity was observed after 4-MMC administration in both strains with significantly more activity produced in the Sprague-Dawley strain. The 10 mg/kg s.c. dose evoked greater increase in extracellular serotonin, compared with dopamine, in the nucleus accumbens. Follow-up studies confirmed that the degree of locomotor stimulation produced by 10 mg/kg 4-MMC was nearly identical to that produced by 1 mg/kg d-methamphetamine in each strain. Furthermore, hypothermia produced by the serotonin 1(A/7 receptor agonist 8-hydroxy-N,N-dipropyl-2-aminotetralin (8-OH-DPAT was similar in each strain. These results show that the cathinone analog 4-MMC exhibits thermoregulatory and locomotor properties that are distinct from those established for methamphetamine or MDMA in prior work, despite recent evidence of neuropharmacological similarity with MDMA.

  10. A stochastic model for transmission, extinction and outbreak of Escherichia coli O157:H7 in cattle as affected by ambient temperature and cleaning practices

    KAUST Repository

    Wang, Xueying

    2013-07-18

    Many infectious agents transmitting through a contaminated environment are able to persist in the environment depending on the temperature and sanitation determined rates of their replication and clearance, respectively. There is a need to elucidate the effect of these factors on the infection transmission dynamics in terms of infection outbreaks and extinction while accounting for the random nature of the process. Also, it is important to distinguish between the true and apparent extinction, where the former means pathogen extinction in both the host and the environment while the latter means extinction only in the host population. This study proposes a stochastic-differential equation model as an approximation to a Markov jump process model, using Escherichia coli O157:H7 in cattle as a model system. In the model, the host population infection dynamics are described using the standard susceptible-infected-susceptible framework, and the E. coli O157:H7 population in the environment is represented by an additional variable. The backward Kolmogorov equations that determine the probability distribution and the expectation of the first passage time are provided in a general setting. The outbreak and apparent extinction of infection are investigated by numerically solving the Kolmogorov equations for the probability density function of the associated process and the expectation of the associated stopping time. The results provide insight into E. coli O157:H7 transmission and apparent extinction, and suggest ways for controlling the spread of infection in a cattle herd. Specifically, this study highlights the importance of ambient temperature and sanitation, especially during summer. © 2013 Springer-Verlag Berlin Heidelberg.

  11. New process of low-temperature methanol synthesis from CO/CO2/H2 based on dual-catalysis

    Institute of Scientific and Technical Information of China (English)

    曾健青; TSUBAKINoritatsu; FUJIMOTOKaoru

    2002-01-01

    A new process of low-temperature methanol synthesis from CO/CO2/H2 based on dual-catalysis has been developed. Some alcohols, especially 2-alcohol, were found to have high catalytic promoting effect on the synthesis of methanol from CO hydrogenation. At 443 K and 5 MPa, the synthesis of methanol could process high effectively, resulting from the synergic catalysis of Cu/ZnO solid catalyst and 2-alcohol solvent catalyst. The primary results showed that when 2-butanol was used as reaction solvent, the one-pass average yield and the selectivity of methanol, in 40 h continuous reaction at temperature as low as 443 K and 5 MPa, were high up to 46.51% and 98.94% respectively. The catalytic activity was stable and the reaction temperature was 80 K or so lower than that in current industry synthesis process. This new process hopefully will become a practical method for methanol synthesis at low temperature.

  12. Temperature Fluctuation Synthesis/Simultaneous Densification and Microstructure Control of Titanium Silicon Carbide (Ti3SiC2) Ceramics

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    @@A novel temperature fluctuation synthesis/simultaneous densification process was developed for the preparation of Ti3SiC2 bulk ceramics. In this process, Si is used as an in-situ liquid forming phase and it is favorable for both the solid-liquid synthesis and the densification of Ti3SiC2 ceramics. The present work demonstrated that the temperature fluctuation synthesis/simultaneous densification process is one of the most effective and simple methods for the preparation of Ti3SiC2 bulk materials providing relatively low synthesis temperature, short reaction time, and simultaneous synthesis and densification. This work also showed the capability to control the microstructure, e.g., the preferred orientation, of the bulk Ti3SiC2 materials simply by applying the hot pressing pressure at different stages of the temperature fluctuation process. And textured Ti3SiC2 bulk materials with {002} faces of laminated Ti3SiC2 grains normal to the hot pressing axis were prepared.

  13. Evidence for organic synthesis in high temperature aqueous media - facts and prognosis

    Science.gov (United States)

    Simoneit, Bernd R. T.

    1995-01-01

    Hydrothermal systems are common along the active tectonic areas of the earth. Potential sites being studied for organic matter alteration and possible organic synthesis are spreading ridges, off-axis systems, back-arc activity, hot spots, volcanism, and subduction. Organic matter alteration, primarily reductive and generally from immature organic detritus, occurs in these high temperature and rapid fluid flow hydrothermal regimes. Hot circulating water (temperature range - warm to greater than 400 C) is responsible for these molecular alterations, expulsion and migration. Compounds that are obviously synthesized are minor components because they are generally masked by the pyrolysis products formed from contemporary natural organic precursors. The reactivity of organic compounds in hot water (200-350 C) has been studied in autoclaves, and supercritical water as a medium for chemistry has also been evaluated. This high temperature aqueous organic chemistry and the strong reducing conditions of the natural systems suggest this as an important route to produce organic compounds on the primitive earth. Thus a better understanding of the potential syntheses of organic compounds in hydrothermal systems will require investigations of the chemistry of condensation, autocatalysis, catalysis and hydrolysis reactions in aqueous mineral buffered systems over a range of temperatures from warm to greater than 400 C.

  14. Influence of the temperature in the electrochemical synthesis of cobalt ferrites nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Mazario, E. [Departamento de Quimica Fisica Aplicada, Facultad de Ciencias, Universidad Autonoma de Madrid, UAM, C/Francisco Tomas y Valiente 7, 28049 Cantoblanco, Madrid (Spain); Morales, M.P. [Instituto de Ciencia de Materiales de Madrid, CSIC, C/Sor Juana Ines de la Cruz 3, 28049 Cantoblanco, Madrid (Spain); Galindo, R. [Departamento de Quimica Fisica Aplicada, Facultad de Ciencias, Universidad Autonoma de Madrid, UAM, C/Francisco Tomas y Valiente 7, 28049 Cantoblanco, Madrid (Spain); Herrasti, P., E-mail: pilar.herrasti@uam.es [Departamento de Quimica Fisica Aplicada, Facultad de Ciencias, Universidad Autonoma de Madrid, UAM, C/Francisco Tomas y Valiente 7, 28049 Cantoblanco, Madrid (Spain); Menendez, N. [Departamento de Quimica Fisica Aplicada, Facultad de Ciencias, Universidad Autonoma de Madrid, UAM, C/Francisco Tomas y Valiente 7, 28049 Cantoblanco, Madrid (Spain)

    2012-09-25

    Highlights: Black-Right-Pointing-Pointer Cobalt ferrite nanoparticles were synthesized by new electrochemical method. Black-Right-Pointing-Pointer Temperature affects to percentage of inclusion of Co and diameter of the synthesized nanoparticles. Black-Right-Pointing-Pointer At 80 Degree-Sign C and current densities of 50/25 mA cm{sup -2} applied to Fe and Co, respectively, a stoichiometric CoFe{sub 2}O{sub 4} nanoparticles with 40 nm of diameter were obtained. - Abstract: A new electrochemical method to synthesize cobalt ferrite nanoparticles has been developed. Magnetic measurement, Moessbauer spectroscopy, X-ray diffraction, inductive coupled plasma spectroscopy, and transmission electron microscopy were carried out to characterize the cobalt ferrites synthesized at different temperatures between 25 Degree-Sign C and 80 Degree-Sign C. These techniques confirm the efficiency of the electrochemical method. At room temperature a mixture of different compounds was obtained with a particle diameter around 20 nm, while at 80 Degree-Sign C the synthesis of cobalt ferrite leads to a stoichiometric spinel, with a crystallite size of 40 nm measured by Scherrer equation. The temperature was defined as an important parameter to obtain stoichiometric ferrites and different diameters.

  15. Synthesis of nanostructured carbon by chlorination of calcium carbide at moderate temperatures and its performance evaluation

    Energy Technology Data Exchange (ETDEWEB)

    Dai Chunling [School of Chemistry, Xiangtan University, Hunan 411105 (China); Wang, Xianyou [School of Chemistry, Xiangtan University, Hunan 411105 (China)], E-mail: wxianyou@yahoo.com; Wang Ying [School of Chemical Engineering and Pharmacy, Wuhan Institute of Technology, Hubei 430073 (China); Li Na; Wei Jianliang [School of Chemistry, Xiangtan University, Hunan 411105 (China)

    2008-12-01

    A new type of one-step preparation technique for the calcium carbide-derived carbon (CaC{sub 2}-CDC) was developed. In this study, CaC{sub 2}-CDC was synthesized from CaC{sub 2} in a freshly prepared chlorine environment in the temperature range of 100-600 deg. C. The structure and morphology of as-prepared CaC{sub 2}-CDC were studied by X-ray diffraction, transmission electron microscopy and nitrogen sorption experiment. Analysis of X-ray diffraction and transmission electron microscopy showed that CaC{sub 2}-CDC is an amorphous nanoporous material, and the structure depended on the synthesis temperature. The resultant carbon demonstrated narrow pore size distribution (PSD) and specific surface area (SSA) close to 800 m{sup 2} g{sup -1} (for nitrogen sorption) at a synthesized temperature of 100 deg. C. Increasing the reaction temperature above 400 deg. C resulted in a lower SSA of CaC{sub 2}-CDC due to the beginning of graphitization tendency. The nanoporous structure and narrow PSD of CaC{sub 2}-CDC indicated potential application as electrode materials in supercapacitor. The CaC{sub 2}-CDC exhibited a specific capacitance of 127.7 F g{sup -1} measured from the three-electrode cyclic voltammetry experiment at 10 mV s{sup -1}.

  16. Gas temperature measurements inside a hot wall chemical vapor synthesis reactor.

    Science.gov (United States)

    Notthoff, Christian; Schilling, Carolin; Winterer, Markus

    2012-11-01

    One key but complex parameter in the chemical vapor synthesis (CVS) of nanoparticles is the time temperature profile of the gas phase, which determines particle characteristics such as size (distribution), morphology, microstructure, crystal, and local structure. Relevant for the CVS process and for the corresponding particle characteristics is, however, not the T(t)-profile generated by an external energy source such as a hot wall or microwave reactor but the temperature of the gas carrying reactants and products (particles). Due to a complex feedback of the thermodynamic and chemical processes in the reaction volume with the external energy source, it is very difficult to predict the real gas phase temperature field from the externally applied T(t)-profile. Therefore, a measurement technique capable to determine the temperature distribution of the gas phase under process conditions is needed. In this contribution, we demonstrate with three proof of principle experiments the use of laser induced fluorescence thermometry to investigate the CVS process under realistic conditions.

  17. Self-Propagating High-Temperature Synthesis in the Ti-C-Ni-Mo System on Application of Powerful Ultrasound

    Science.gov (United States)

    Kulak, M. M.; Khina, B. B.

    2014-03-01

    An experimental setup has been developed and a study has been made of the self-propagating high-temperature synthesis in a Ti-C-Ni-Mo system under the conditions of action of ultrasonic vibrations. The influence of the amplitude of ultrasonic vibrations on the combustion rate and temperature and on the phase composition and structure of the derived composite material based on titanium carbide with a metal binder has been determined. The heat-transfer coefficient on the surface of a sample for vibrations at ultrasound frequency has been evaluated. Consideration has been given to possible mechanisms of influence of ultrasonic vibrations on the process of self-propagating high-temperature synthesis. It has been shown that the reduction in the synthesis temperature is due to the cooling of the sample because of the forced convection of the surrounding gas, whereas the change in the structure of the synthesized material is related to the change in the conditions of high-temperature heterogeneous interaction in the wave of self-propagating high-temperature synthesis.

  18. Method of porous materials production based on self-propagating high-temperature synthesis

    International Nuclear Information System (INIS)

    Full text: Machines complicated service conditions make such requirements to functional coatings which any complex alloying material can not meet in principle. In many cases solving this task by powder making for coating using self-propagating high-temperature synthesis (SHS) as flexible technology is reasonable from both technological and economic points of view. Powder production for Ni-Al alloy coating is made according to technological SHS process scheme. Making initial reaction mixture (furnace feed) is the first phase of SHS. The device including hopper for initial components, the system of rotary batches for component delivery to the mixer through the feeding pipes is used for multi component reacting mixtures. Specific feature of the mixer is two mixing sections which can be used separately or both together regarding to the necessary mixing trajectory determined by components particles ratio, their real density and furnace feed concentrations. When reactor is filled with furnace feed through charge pipe compaction mechanism drive is engaged, and feed is compacted by the screw in the reactor. When the compaction is over furnace feed is preliminary heated in the reactor with the help of heating spiral. The composition of protective atmosphere in fusion zone determined by furnace gas analyzer is a mixture of nitrogen and hydrogen 75:25 mole. %. Ni-Al- mixtures synthesis was carried out in the mode of thermal explosion the temperature of which was 913 - 933 K. The product temperature on coming out of the furnace does not exceed in 423 K that prevents completely materials oxidation during the interaction with atmosphere. Synthesized product further undergoes two operations: coarse grinding in jaw crusher and more dispersed in cone inertial crusher. Then powder mixture goes to vibra-classifier and goes out as powder with disperse ability of 63-160 μm used in spraying

  19. Electric Field Effects in Self-Propagating High-Temperature Synthesis under Microgravity Conditions

    Science.gov (United States)

    Unuvar, C.; Frederick, D. M.; Shaw, B. D.; Munir, Z. A.

    2003-01-01

    Self-propagating high-temperature synthesis (SHS) has been used to form many materials. SHS generally involves mixing reactants together (e.g., metal powders) and igniting the mixture such that a combustion (deflagration) wave passes though the mixture. The imposition of an electric field (AC or DC) across SHS reactants has been shown to have a marked effect on the dynamics of wave propagation and on the nature, composition, and homogeneity of the product . The use of an electric field with SHS has been termed "field-assisted SHS". Combustion wave velocities and temperatures are directly affected by the field, which is typically perpendicular to the average wave velocity. The degree of activation by the field (e.g., combustion rate) is related to the current density distribution within the sample, and is therefore related to the temperature-dependent spatial distribution of the effective electrical conductivity of reactants and products. Furthermore, the field can influence other important SHS-related phenomena including capillary flow, mass-transport in porous media, and Marangoni flows. These phenomena are influenced by gravity in conventional SHS processes (i.e., without electric fields). As a result the influence of the field on SHS under reduced gravity is expected to be different than under normal gravity. It is also known that heat loss rates from samples, which can depend significantly on gravity, can influence final products in SHS. This research program is focused on studying field-assisted SHS under reduced gravity conditions. The broad objective of this research program is to understand the role of an electric field in SHS reactions under conditions where gravity-related effects are suppressed. The research will allow increased understanding of fundamental aspects of field-assisted SHS processes as well as synthesis of materials that cannot be formed in normal gravity.

  20. Effect of the synthesis temperature of porous carbon-metal oxide composites on the gold particle morphology

    Science.gov (United States)

    Tsyganova, S. I.; Zhizhaev, A. M.; Mikhlin, Yu. L.; Patrushev, V. V.; Bondarenko, G. N.; Korol'kova, I. V.

    2014-10-01

    The state of gold deposited from a chloride solution on the surface of the porous magnetite-carbon composite obtained from modified birch saw dust at 400 and 800°C was studied by electron microscopy, X-ray photoelectron spectroscopy, and XRD analysis. The shape and size of the deposited gold crystallites depend on the synthesis temperature of the composite. The deposited gold crystallites were mainly ray-shaped at the synthesis temperature of 400°C and spheroid at 800°C.