WorldWideScience

Sample records for alumina scale spallation

  1. Moisture-Induced Alumina Scale Spallation: The Hydrogen Factor

    Science.gov (United States)

    Smialek, James L.

    2010-01-01

    For some time the oxidation community has been concerned with interfacial spallation of protective alumina scales, not just upon immediate cool down, but as a time-delayed phenomenon. Moisture-induced delayed spallation (MIDS) and desktop spallation (DTS) of thermal barrier coatings (TBCs) refer to this process. It is most apparent for relatively adherent alumina scales that have survived initial cool down in a dry environment, have built up considerable thickness and strain energy, and have been somewhat damaged, such as by cyclic oxidation cracking. Indeed, a "sensitive zone" can be described that maximizes the observed effect as a function of all the relevant factors. Moisture has been postulated to serve as a source of interfacial hydrogen embrittlement. Hydrogen is derived from reaction with aluminum in the alloy at an exposed interface. The purpose of this monograph is to trace the close analogy of this phenomenon to other hydrogen-induced effects, such as embrittlement of aluminides and blistering of alloys and anodic alumina films. A formalized, top-down, logic-tree structure is presented as a guide to this discussion. A theoretical basis for interfacial weakening by hydrogen is first cited, as are demonstrations of hydrogen detection as a reaction product or interfacial species. Further support is provided by critical experiments that recreate the moisture effect, but by isolating hydrogen from other potential causative factors. These experiments include tests in H 2-containing atmospheres or cathodic hydrogen charging. Accordingly, they strongly indicate that interfacial hydrogen, derived from moisture, is the key chemical species accounting for delayed alumina scale spallation.

  2. Sulfur and Moisture Effects on Alumina Scale and TBC Spallation

    Science.gov (United States)

    Smialek, James L.

    2007-01-01

    It has been well established that a few ppmw sulfur impurity may segregate to the interface of thermally grown alumina scales and the underlying substrate, resulting in bond degradation and premature spallation. This has been shown for NiAl and NiCrAl-based alloys, bare single crystal superalloys, or coated superalloys. The role of reactive elements (especially Y) has been to getter the sulfur in the bulk and preclude interfacial segregation. Pt additions are also very beneficial, however a similar thermodynamic explanation does not apply. The purpose of the present discussion is to highlight some observations of these effects on Rene'142, Rene'N5, PWA1480, and PWA1484. For PWA1480, we have mapped cyclic oxidation and spallation in terms of potential sulfur interfacial layers and found that a cumulative amount of about one monolayer is sufficient to degrade long term adhesion. Depending on substrate thickness, optimum performance occurs if sulfur is reduced below about 0.2-0.5 ppmw. This is accomplished in the laboratory by hydrogen annealing or commercially by melt-fluxing. Excellent 1150 C cyclic oxidation is thus demonstrated for desulfurized Rene'142, Rene'N5, and PWA1484. Alternatively, a series of N5 alloys provided by GE-AE have shown that as little as 15 ppmw of Y dopant was effective in providing remarkable scale adhesion. In support of a Y-S gettering mechanism, hydrogen annealing was unable to desulfurize these alloys from their initial level of 5 ppmw S. This impurity and critical doping level corresponds closely to YS or Y2S3 stoichiometry. In many cases, Y-doped alloys or alloys with marginal sulfur levels exhibit an oxidative sensitivity to the ambient humidity called Moisture-Induced Delayed Spallation (MIDS). After substantial scale growth, coupled with damage from repeated cycling, cold samples may spall after a period of time, breathing on them, or immersing them in water. While stress corrosion arguments may apply, we propose that the underlying

  3. Delayed Alumina Scale Spallation on Rene'n5+y: Moisture Effects and Acoustic Emission

    Science.gov (United States)

    Smialek, James L.; Morscher, Gregory N.

    2001-01-01

    The single crystal superalloy Rene'N5 (with or without Y-doping and hydrogen annealing) was cyclically oxidized at 1150 C for 1000 hours. After considerable scale growth (>= 500 hours), even the adherent alumina scales formed on Y-doped samples exhibited delayed interfacial spallation during subsequent water immersion tests, performed up to one year after oxidation. Spallation was characterized by weight loss, the amount of spalled area, and acoustic emission response. Hydrogen annealing (prior to oxidation) reduced spallation both before and after immersion, but without measurably reducing the bulk sulfur content of the Y-doped alloys. The duration and frequency of sequential, co-located acoustic emission events implied an interfacial crack growth rate at least 10(exp -3) m/s, but possibly higher than 10(exp 2) m/s. This is much greater than classic moisture-assisted slow crack growth rates in bulk alumina (10(exp -6) to 10(exp -3) m/s), which may still have occurred undetected by acoustic emission. An alternative failure sequence is proposed: an incubation process for preferential moisture ingress leads to a local decrease in interfacial toughness, thus allowing fast fracture driven by stored strain energy.

  4. Stress determination in thermally grown alumina scales using ruby luminescence

    Energy Technology Data Exchange (ETDEWEB)

    Renusch, D.; Veal, B.W.; Koshelev, I.; Natesan, K.; Grimsditch [Argonne National Lab., IL (United States); Hou, P.Y. [Lawrence Berkeley Lab., CA (United States)

    1996-06-01

    By exploiting the strain dependence of the ruby luminescence line, we have measured the strain in alumina scales thermally grown on Fe-Cr- Al alloys. Results are compared and found to be reasonably consistent with strains determined using x rays. Oxidation studies were carried out on alloys Fe - 5Cr - 28Al and Fe - 18Cr - 10Al (at.%). Significantly different levels of strain buildup were observed in scales on these alloys. Results on similar alloys containing a ``reactive element`` (Zr or Hf) in dilute quantity are also presented. Scales on alloys containing a reactive element (RE) can support significantly higher strains than scales on RE-free alloys. With the luminescence technique, strain relief associated with spallation thresholds is readily observed.

  5. GRAIN-SCALE FAILURE IN THERMAL SPALLATION DRILLING

    Energy Technology Data Exchange (ETDEWEB)

    Walsh, S C; Lomov, I; Roberts, J J

    2012-01-19

    Geothermal power promises clean, renewable, reliable and potentially widely-available energy, but is limited by high initial capital costs. New drilling technologies are required to make geothermal power financially competitive with other energy sources. One potential solution is offered by Thermal Spallation Drilling (TSD) - a novel drilling technique in which small particles (spalls) are released from the rock surface by rapid heating. While TSD has the potential to improve drilling rates of brittle granitic rocks, the coupled thermomechanical processes involved in TSD are poorly described, making system control and optimization difficult for this drilling technology. In this paper, we discuss results from a new modeling effort investigating thermal spallation drilling. In particular, we describe an explicit model that simulates the grain-scale mechanics of thermal spallation and use this model to examine existing theories concerning spalling mechanisms. We will report how borehole conditions influence spall production, and discuss implications for macro-scale models of drilling systems.

  6. Improved alumina scale adhesion of electron beam physical vapor deposited Dy/Hf-doped β-NiAl coatings

    Energy Technology Data Exchange (ETDEWEB)

    Li, Dongqing; Guo, Hongbo, E-mail: Guo.hongbo@buaa.edu.cn; Peng, Hui; Gong, Shengkai; Xu, Huibin

    2013-10-15

    The cyclic oxidation behavior of Dy/Hf-doped β-NiAl coatings produced by electron beam physical vapor deposition (EB-PVD) was investigated. For the undoped NiAl coating, numerous voids were formed at the alumina scale/coating interface and large rumpling developed in the scale, leading to premature oxide spallation. The addition of Dy and Hf both improved scale adhesion and the alumina scale grown on the NiAl-Hf coating showed better adhesion than that on the NiAl-Dy coating, although the suppressing effect on interfacial void formation and the scale rumpling resistance were stronger in the NiAl-Dy coating. It is proposed that the segregation of Dy and Hf ions at the scale/coating interfaces not only prevent interfacial sulfur segregation but also may directly enhance interfacial adhesion by participating in bonding across the interfaces, and this strengthening effect is relatively stronger for Hf ionic segregation.

  7. Improved alumina scale adhesion of electron beam physical vapor deposited Dy/Hf-doped β-NiAl coatings

    Science.gov (United States)

    Li, Dongqing; Guo, Hongbo; Peng, Hui; Gong, Shengkai; Xu, Huibin

    2013-10-01

    The cyclic oxidation behavior of Dy/Hf-doped β-NiAl coatings produced by electron beam physical vapor deposition (EB-PVD) was investigated. For the undoped NiAl coating, numerous voids were formed at the alumina scale/coating interface and large rumpling developed in the scale, leading to premature oxide spallation. The addition of Dy and Hf both improved scale adhesion and the alumina scale grown on the NiAl-Hf coating showed better adhesion than that on the NiAl-Dy coating, although the suppressing effect on interfacial void formation and the scale rumpling resistance were stronger in the NiAl-Dy coating. It is proposed that the segregation of Dy and Hf ions at the scale/coating interfaces not only prevent interfacial sulfur segregation but also may directly enhance interfacial adhesion by participating in bonding across the interfaces, and this strengthening effect is relatively stronger for Hf ionic segregation.

  8. Effect of Substrate Thickness on Oxide Scale Spallation for Solid Oxide Fuel Cells

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Wenning N.; Sun, Xin; Stephens, Elizabeth V.; Khaleel, Mohammad A.

    2011-07-01

    In this paper, the effect of the ferritic substrate's thickness on the delamination/spallation of the oxide scale was investigated experimentally and numerically. At the high-temperature oxidation environment of solid oxide fuel cells (SOFCs), a combination of growth stress with thermal stresses may lead to scale delamination/buckling and eventual spallation during SOFC stack cooling, even leading to serious degradation of cell performance. The growth stress is induced by the growth of the oxide scale on the scale/substrate interface, and thermal stress is induced by a mismatch of the coefficient of thermal expansion between the oxide scale and the substrate. The numerical results show that the interfacial shear stresses, which are the driving force of scale delamination between the oxide scale and the ferritic substrate, increase with the growth of the oxide scale and also with the thickness of the ferritic substrate; i.e., the thick ferritic substrate can easily lead to scale delamination and spallation. Experimental observation confirmed the predicted results of the delamination and spallation of the oxide scale on the ferritic substrate.

  9. The mechanical reliability of alumina scales and coatings

    Energy Technology Data Exchange (ETDEWEB)

    Alexander, K.B.; Pruebner, K.; Tortorelli, P.F. [Oak Ridge National Lab., TN (United States)

    1996-08-01

    The mechanical integrity of oxide scales ultimately determines their ability to protect materials from corrosion and other environmental effects arising from deleterious reactions with gases and condensable products. The microstructure and mechanical behavior of alumina products thermally grown or deposited on Fe-28 at.% Al intermetallic alloys are being characterized in order to develop the knowledge and means to control the mechanical reliability of alumina scales by microstructural manipulation through design and processing. Mechanical characterization involved gravimetric data from cyclic oxidation experiments, in-situ observation of oxidized specimens undergoing flexural loading in a scanning electron microscope, and measurements of hardness, elastic modulus and cracking resistance by nanoindentation. Values of cracking thresholds for Al{sub 2}O{sub 3} scales were consistent with other measurements for surface and bulk alumina. The oxidation behavior of Fe{sub 3}Al alloys coated with a thin (0.5 - 1 {mu}m) alumina film deposited by plasma synthesis has been studied. During exposure in the oxidizing environment, new oxide was formed between the coating and the substrate. The presence of the deposited amorphous oxide inhibited the subsequent thermal oxidation of the metal. Because the thermally grown alumina forms under the deposit, the adherence of the coating is controlled by the strength of the metal/oxide interface that develops during oxidation.

  10. Stress and adhesion of chromia-rich scales on ferritic stainless steels in relation with spallation

    Directory of Open Access Journals (Sweden)

    A. Galerie

    2004-03-01

    Full Text Available The relation between chromia scale spallation during oxidation or cooling down of ferritic stainless steels is generally discussed in terms of mechanical stresses induced by volume changes or differential thermal expansion. In the present paper, growth and thermal stress measurements in scales grown on different ferritic steel grades have shown that the main stress accumulation occurs during isothermal scale growth and that thermal stresses are of minor importance. However, when spallation occurs, it is always during cooling down. Steel-oxide interface undulation seems to play a major role at this stage, thus relating spallation to the metal mechanical properties, thickness and surface preparation. A major influence on spallation of the minor stabilizing elements of the steels was observed which could not be related to any difference in stress state. Therefore, an original inverted blister test was developed to derive quantitative values of the metal-oxide adhesion energy. These values clearly confirmed that this parameter was influenced by scale thickness and by minor additions, titanium greatly increasing adhesion whereas niobium decreased it.

  11. SPALLATION ANALYSIS WITH A CLOSED TRANS-SCALE FORMULATION OF DAMAGE EVOLUTION

    Institute of Scientific and Technical Information of China (English)

    WANG Haiying; BAI Yilong; XIA Mengfen; KE Fujiu

    2004-01-01

    A closed, trans-scale formulation of damage evolution based on the statistical microdamage mechanics is summarized in this paper. The dynamic function of damage bridges the mesoscopic and macroscopic evolution of damage. The spallation in an aluminium plate is studied with this formulation. It is found that the damage evolution is governed by several dimensionless parameters,i.e., imposed Deborah numbers De* and De, Mach number M and damage number S. In particular,the most critical mode of the macroscopic damage evolution, i.e., the damage localization, is determined by Deborah number De*. Deborah number De* reflects the coupling and competition between the macroscopic loading and the microdamage growth. Therefore, our results reveal the multi-scale nature of spallation. In fact, the damage localization results from the nonlinearity of the microdamage growth. In addition, the dependence of the damage rate on imposed Deborah numbers De* and De,Mach number M and damage number S is discussed.

  12. Mitigation and Prediction of Spallation of Oxide Scales on Ferritic Stainless Steel

    Energy Technology Data Exchange (ETDEWEB)

    Chou, Y. S. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Stephens, Elizabeth V. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Xu, Zhijie [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Xu, Wei [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Koeppel, Brian J. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Stevenson, Jeffry W. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2015-02-04

    This report summarizes results from experimental and modeling studies performed by researchers at Pacific Northwest National Laboratory on behalf of the Solid-State Energy Conversion Alliance (SECA) Core Technology Program. The results indicate that application of physical surface modifications, such as surface blasting, prior to application of protective surface coatings can substantially increase oxide scale spallation resistance during long-term exposure to elevated temperatures (e.g., 800-850ºC). To better understand and predict the benefits of surface modification, an integrated modeling framework was developed and applied to the obtained experimental results.

  13. Lightweight alumina refractory aggregate: Phase 3, Full-scale demonstration

    Energy Technology Data Exchange (ETDEWEB)

    Swansiger, T.G.; Pearson, A.

    1996-07-16

    Technical problems (higher than target fired density, and poor intermediate strength after burnout but before sintering) were addressed and solved; solution involved use of large loading of CP-5 alumina (controlled pore, rehydratable), increased loading of one of the binders, and a steam aging step. Resistance of the lightweight aggregate in a brick formulation to steel slag penetration was assessed in a preliminary test and found to be almost as good as that of T-64. Pelletized process economic feasibility study was updated, based on production levels of 10,000 and 20,000 mt/year, the most up- to-date raw material costs, and the assumption of a retrofit into the Arkansas plant tabular production facility. For the 10,000 mt/y production level, the required selling price of 35% more than the T- 64 selling price exceeds the {le}25% objective. The market survey will determine whether to proceed with the full scale demonstration that will produce at least 54.4 mt (120,000 lb) of the aggregate for incorporation into products, followed by end-user testing and evaluation.

  14. EFFECT OF SURFACE CONDITION ON SPALLATION BEHAVIOR OF OXIDE SCALE ON SS 441 SUBSTRATE USED IN SOFC

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Wenning N.; Sun, Xin; Stephens, Elizabeth V.; Khaleel, Mohammad A.

    2011-03-01

    As operating temperature of SOFC decreases, ferritic stainless steel has attracted a great deal of attention for its use as an interconnect in SOFCs because of its gas-tightness, low electrical resistivity, ease of fabrication, and cost-effectiveness. However, oxidation reaction of the metallic interconnects in a typical SOFC working environment is unavoidable. The growth stresses in the oxide scale and on the scale/substrate interface combined with the thermal stresses induced by thermal expansion coefficient mismatch between the oxide scale and the substrate may lead to scale delamination/buckling and eventual spallation during stack cooling, which can lead to serious cell performance degradation. Therefore, the interfacial adhesion strength between the oxide scale and substrate is crucial to the reliability and durability of the metallic interconnect in SOFC operating environments. In this paper, we investigated the effect of the surface conditions on the interfacial strength of oxide scale and SS441 substrate experimentally. Contrary to the conventional sense, it was found that rough surface of SS441 substrate will decrease the interfacial adhesive strength of the oxide scale and SS441 substrate

  15. The mechanical reliability of alumina scales and coatings

    Energy Technology Data Exchange (ETDEWEB)

    Alexander, K.B.; Pruebner, K.; Tortorelli, P.F.

    1996-06-01

    In many high-temperature fossil energy systems, corrosion and deleterious reactions with gases and condensable products in the operating environment often compromise materials performance. The presence of a stable surface oxide (either as thermally-grown scales or deposited coatings) can effectively protect the materials from these reactions if the oxides are slow-growing, dense and adherent to the substrate. The protection these brittle oxide films provide has long been a critical issue, particularly for applications involving severe high-temperature thermal cycles or very aggressive (for example, sulfidizing) environments. The various factors which control the scale/coating integrity and adherence are not well understood. The present multilaboratory collaborative work is intended to define the relationships between substrate characteristics (composition, microstructure, and mechanical behavior) and the structure and protective properties of deposited oxide coatings and/or thermally grown scales. Through such studies, the ultimate goal is to assure environmental protection through effective processing and materials selection leading to the development of corrosion-resistant, high-temperature materials for improved energy and environmental control systems.

  16. Atomic-scale non-contact AFM studies of alumina supported nanoparticles

    DEFF Research Database (Denmark)

    Jensen, Thomas Nørregaard; Meinander, Kristoffer; Simonsen, Søren Bredmose;

    ATOMIC-SCALE NON-CONTACT ATOMIC FORCE STUDIES OF ALUMINA SUPPORTED NANOPARTICLES Thomas N. Jensen, Kristoffer Meinander, Flemming Besenbacher and Jeppe V. Lauritsen Interdisciplinary Nanoscience Center, Aarhus University, DK-8000 Aarhus C, Denmark Heterogeneous catalysis plays a crucial role...... materials is a prerequisite for the synthesis of more sintering stable catalysts and the realizations of nanocatalysts implementing catalyst particles with a tailored size and morphology. In the last two decades the atomic force microscope (AFM) has become one of the premier tools for studying surfaces...... at the nanometre scale [1]. When operated in the so-called non-contact mode (nc-AFM), this technique yields genuine atomic resolution and offers a unique tool for atomic-scale studies of clean surfaces, as well as, nanoparticles and thin films on these surfaces irrespective of the substrate being electrically...

  17. Development of advanced materials for spallation neutron sources and radiation damage simulation based on multi-scale models

    Energy Technology Data Exchange (ETDEWEB)

    Kawai, Masayoshi, E-mail: masayoshi.kawai@kek.jp [High Energy Accelerator Research Organization (KEK), Tsukuba, Ibaraki 305-0801 (Japan); Kurishita, Hiroaki [Institute for Materials Research, Tohoku University, Oarai, Ibaraki 311-1313 (Japan); Kokawa, Hiroyuki [Graduate School of Engineering, Tohoku University, Aramaki Aza Aoba, Aoba-ku, Sendai, Miyagi 980-8579 (Japan); Watanabe, Seiichi; Sakaguchi, Norihito [School of Engineering, Hokkaido University, Kita-ku, Sapporo 060-8628 (Japan); Kikuchi, Kenji [Institute of Applied Beam Science, Ibaraki University, Tokai-mura, Naka-gun, Ibaraki 319-1195 (Japan); Saito, Shigeru [J-PARC, Japan Atomic Energy Agency (JAEA), Tokai-mura, Naka-gun, Ibaraki 319-1195 (Japan); Yoshiie, Toshimasa [Kyoto University Research Reactor Institute, Kumatori, Sennan-gun, Osaka 590-0494 (Japan); Iwase, Hiroshi [High Energy Accelerator Research Organization (KEK), Tsukuba, Ibaraki 305-0801 (Japan); Ito, Takahiro [Toyohashi University of Technology, Tenpaku-cho, Toyohasi-shi, Aichi 441-8580 (Japan); Hashimoto, Satoshi; Kaneko, Yoshihisa [Osaka City University, Sugimoto, Sumiyoshi-ku, Osaka 558-8585 (Japan); Futakawa, Masatoshi [J-PARC, Japan Atomic Energy Agency (JAEA), Tokai-mura, Naka-gun, Ibaraki 319-1195 (Japan); Ishino, Shiori [University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-8656 (Japan)

    2012-12-15

    This report describes the status review of the JSPS Grant Team to develop advanced materials for the spallation neutron sources and modeling of radiation damage. One of the advanced materials is a toughness enhanced, fine-grained tungsten material (W-TiC) having four-times larger fracture toughness than ordinary tungsten and appreciable RT ductility in the recrystallized state. The other is an intergranular crack (IGC)-resistant austenitic stainless steel which was processed by the grain-boundary engineering (GBE). The experimental results are devoted to corrosion in a lead-bismuth eutectic, arrest of corrosion of weld-decay, radiation damage and creep rupture as well as new technique of GBE using a laser and annealing procedure. New technique seems to be applicable to large or complicated-shaped components. A series of the multi-scale models is built up from nuclear reaction between incident particles and medium nuclei to material property change due to radiation damage. Sample calculation is made on 3 mm-thick nickel bombarded by 3 GeV protons.

  18. Development of advanced materials for spallation neutron sources and radiation damage simulation based on multi-scale models

    Science.gov (United States)

    Kawai, Masayoshi; Kurishita, Hiroaki; Kokawa, Hiroyuki; Watanabe, Seiichi; Sakaguchi, Norihito; Kikuchi, Kenji; Saito, Shigeru; Yoshiie, Toshimasa; Iwase, Hiroshi; Ito, Takahiro; Hashimoto, Satoshi; Kaneko, Yoshihisa; Futakawa, Masatoshi; Ishino, Shiori; JSPS Grant Team

    2012-12-01

    This report describes the status review of the JSPS Grant Team to develop advanced materials for the spallation neutron sources and modeling of radiation damage. One of the advanced materials is a toughness enhanced, fine-grained tungsten material (W-TiC) having four-times larger fracture toughness than ordinary tungsten and appreciable RT ductility in the recrystallized state. The other is an intergranular crack (IGC)-resistant austenitic stainless steel which was processed by the grain-boundary engineering (GBE). The experimental results are devoted to corrosion in a lead-bismuth eutectic, arrest of corrosion of weld-decay, radiation damage and creep rupture as well as new technique of GBE using a laser and annealing procedure. New technique seems to be applicable to large or complicated-shaped components. A series of the multi-scale models is built up from nuclear reaction between incident particles and medium nuclei to material property change due to radiation damage. Sample calculation is made on 3 mm-thick nickel bombarded by 3 GeV protons.

  19. Development of advanced materials for spallation neutron sources and radiation damage simulation based on multi-scale models

    International Nuclear Information System (INIS)

    This report describes the status review of the JSPS Grant Team to develop advanced materials for the spallation neutron sources and modeling of radiation damage. One of the advanced materials is a toughness enhanced, fine-grained tungsten material (W-TiC) having four-times larger fracture toughness than ordinary tungsten and appreciable RT ductility in the recrystallized state. The other is an intergranular crack (IGC)-resistant austenitic stainless steel which was processed by the grain-boundary engineering (GBE). The experimental results are devoted to corrosion in a lead–bismuth eutectic, arrest of corrosion of weld-decay, radiation damage and creep rupture as well as new technique of GBE using a laser and annealing procedure. New technique seems to be applicable to large or complicated-shaped components. A series of the multi-scale models is built up from nuclear reaction between incident particles and medium nuclei to material property change due to radiation damage. Sample calculation is made on 3 mm-thick nickel bombarded by 3 GeV protons.

  20. Oxygen Permeability and Grain-Boundary Diffusion Applied to Alumina Scales

    Science.gov (United States)

    Smialek, James L.; Jacobson, Nathan S.; Gleeson, Brian; Hovis, David B.; Heuer, Arthur H.

    2013-01-01

    High-temperature oxygen permeability measurements had determined grain-boundary diffusivities (deltaD(sub gb)) in bulk polycrystalline alumina (Wada, Matsudaira, and Kitaoka). They predict that oxygen deltaD(sub gb,O) varies with oxygen pressure as P(O2)(sup -1/6) at low pressure whereas aluminum deltaD(sub gb),Al varies with P(O2)(sup +3/16) at high pressure. These relations were used to evaluate alumina scale growth in terms of diffusivity and grain size. A modified Wagner treatment for dominant inward oxygen growth produces the concise solution: ?(sub i) = k(sub p,i)×G(sub i) = 12 deltaD(sub gb,O,int), where ?(sub i) is a constant and k(sub p,i) and G(sub i) refer to instantaneous values of the scale parabolic growth constant and grain size, respectively. A commercial FeCrAl(Zr) alloy was oxidized at 1100 to 1400 degC to determine k(sub p,i), interfacial grain size, ?, and thus deltaD(sub gb,O,int). The deltaD(sub gb,O,int) values predicted from oxidation at (375 kJ/mole) were about 20 times less than those obtained above (at 298 kJ/mole), but closer than extrapolations from high-temperature bulk measurements. The experimental oxidation results agree with similar FeCrAl(X) studies, especially where both k(sub p,i) and G(sub i) were characterized. This complete approach accounts for temperature-sensitive oxidation effects of grain enlargement, equilibrium interface pressure variation, and grain-boundary diffusivity.

  1. European Spallation Source

    Science.gov (United States)

    Eshraqi, Mohammad; McGinnis, David; Lindroos, Mats

    The following sections are included: * Neutron usage and historical background * Spallation * History of spallation sources * The ESS facility * The ESS linac * Beam physics * The front-end and the normal conducting linac * Superconducting linac * RF sources * Summary * References

  2. Growth strains and stress relaxation in alumina scales during high temperature oxidation

    Energy Technology Data Exchange (ETDEWEB)

    Hou, P.Y.; Paulikas, A.P.; Veal, B.W.

    2004-03-23

    A novel X-ray technique was used, exploiting synchrotron radiation at the Advanced Photon Source at Argonne National Laboratory, to investigate the growth stresses in {alpha}-Al{sub 2}O{sub 3}. In-situ measurements of Debye-Scherrer diffraction patterns from the scale were recorded during oxidation and cooling, and the elliptical distortion of the diffraction rings was analyzed to yield the in-plane strain. Fe-28Al, Fe-40Al, Fe-40Al-0.2Hf, Fe-20Cr-10Al and Ni-50Al (at. %) were studied. Data were acquired in air at temperatures between 950-1100 C and during cool down. In all cases, the steady stage growth strain was relatively low (<0.1%) and was either tensile or compressive depending on the alloy. A higher tensile strain often existed during the initial oxidation period when transition alumina was present. Thermal stresses imposed on NiAl by reducing the sample temperature to 950 C for a period of time showed noticeable stress relaxation by creep. Different degrees of relaxation were also found during cooling depending on alloy composition and scale microstructure. On all Fe-based alloys, the first formed {alpha}-Al{sub 2}O{sub 3} was highly textured with the degree of texture decreasing with further oxidation. The relationships between stress development, scale wrinkling, oxide phase changes, and the effect of reactive element addition on growth stresses are discussed. Results are compared with other reports of growth stresses in Al{sub 2}O{sub 3} scales.

  3. TEM and SNMS studies of protective alumina scales on NiCrAlY-alloys.

    Science.gov (United States)

    Clemens, D; Vosberg, V; Hobbs, W; Breuer, U; Quadakkers, W J; Nickel, H

    1996-06-01

    The effect of Si addition on the oxidation behaviour of NiCrAlY alloys in the temperature range 950 bis 1100 degrees C has been investigated. During isothermal oxidation oxide growth rates were practically independent of the Si-content. However during cyclic oxidation Si additions were beneficial. Si additions of 1-2(m)/(0) appeared to shift the onset for spallation to longer times. It was found that Si stabilizes the beta-phase and probably it suppresses the formation of metastable Al(2)O(3) modifications. PMID:15045347

  4. Spallation Neutron Source (SNS)

    Data.gov (United States)

    Federal Laboratory Consortium — The SNS at Oak Ridge National Laboratory is a next-generation spallation neutron source for neutron scattering that is currently the most powerful neutron source in...

  5. Spallation: understanding for predicting !?

    International Nuclear Information System (INIS)

    This HDR report summarizes about ten years spent around spallation reaction modelling. Spallation reactions are defined as interaction of a light particle, say a nucleon, and a nucleus at an incident energy from 100 MeV up to 2-3 GeV. These reactions are divided in two steps. A first and fast phase, direct reactions also called intranuclear cascade, following by a slower phase, deexcitation of the remnant nucleus. Using the combination of INCL4, the intranuclear cascade model developed by the group, and the deexcitation code Abla from GSI, as a connecting thread, the multi-faceted spallation is presented. Chapter one deals with physics and codes, then different types of benchmarks are addressed, followed by several domains where spallation modelling plays a role, and finally, taking advantage of what has been said previously and of what can be read in the literature, new developments are suggested. (author)

  6. Ultrafiltro de alumina Alumina ultrafilter

    Directory of Open Access Journals (Sweden)

    M. F. de Souza

    1999-06-01

    Full Text Available Membranas de alumina AKP-50 foram preparadas sobre um substrato de alumina APC-SG de alta resistência mecânica. As membranas foram sinterizadas a 1000 °C e possuem uma distribuição estreita de poros de 40 a 90 nm, espessura média de 57 mm e taxa de fluxo de 0,4 m3/m2h. O filtro assim obtido é classificado como ultrafiltro sendo capaz de reter bactérias e alguns vírus. São quimicamente inertes e resistem a temperaturas inferiores a 1000 °C. A aderência entre as camadas permite a limpeza por contra-fluxo.Alumina ceramic membranes with unimodal pore size distribution in the 40 to 90 nm range were prepared on alumina porous substrates. The 57mm thickness membrane made from AKP-50 alumina shows 0,4 m3/m2h flow rate. The two layer substrate, prepared to have high mechanical strength, was made from commercially available APC-SG alumina. The filter made of three layers, membrane, intermediate layer and substrate, is classified as ultra-filter being able to retain bacteria and some viruses. Adherence between the three layers allows reverse washing. Filters are chemically inert and resistant to temperatures below 1000oC.

  7. Pulsed spallation Neutron Sources

    Energy Technology Data Exchange (ETDEWEB)

    Carpenter, J.M. [Argonne National Lab., IL (United States)

    1994-12-31

    This paper reviews the early history of pulsed spallation neutron source development at Argonne and provides an overview of existing sources world wide. A number of proposals for machines more powerful than currently exist are under development, which are briefly described. The author reviews the status of the Intense Pulsed Neutron Source, its instrumentation, and its user program, and provides a few examples of applications in fundamental condensed matter physics, materials science and technology.

  8. Outline of spallation neutron source engineering

    Energy Technology Data Exchange (ETDEWEB)

    Watanabe, Noboru [Center for Neutron Science, Tokai Research Establishment, Japan Atomic Energy Research Institute, Tokai, Ibaraki (Japan)

    2001-01-01

    Slow neutrons such as cold and thermal neutrons are unique probes which can determine structures and dynamics of condensed matter in atomic scale. The neutron scattering technique is indispensable not only for basic sciences such as condensed matter research and life science, but also for basic industrial technology in 21 century. It is believed that to survive in the science-technology competition in 21 century would be almost impossible without neutron scattering. However, the intensity of neutrons presently available is much lower than synchrotron radiation sources, etc. Thus, R and D of intense neutron sources become most important. The High-Intensity Proton Accelerator Project is now being promoted jointly by Japan Atomic Energy Research Institute and High Energy Accelerator Research Organization, but there has so far been no good text which covers all the aspects of pulsed spallation neutron sources. The present review was prepare aiming at giving a better understanding on pulsed spallation neutron sources not only to neutron source researchers but also more widely to neutron scattering researchers and accelerator scientists in this field. The contents involve, starting from what is neutron scattering and what neutrons are necessary for neutron scattering, what is the spallation reaction, how to produce neutrons required for neutron scattering more efficiently, target-moderator-reflector neutronics and its engineering, shielding, target station, material issues, etc. The author have engaged in R and D of pulsed apallation neutron sources and neutron scattering research using them over 30 years. The present review is prepared based on the author's experiences with useful information obtained through ICANS collaboration and recent data from the JSNS (Japanese Spallation Neutron Source) design team. (author)

  9. Influences of Yttrium on Adhesion of Oxide Scale of Fe-Cr-Al Alloy

    Institute of Scientific and Technical Information of China (English)

    辛丽; 李美栓; 周龙江; 王福会; 李铁藩

    2001-01-01

    The 1100 ℃ isothermal oxidation behavior of Fe-23Cr-5Al alloy modified by yttrium addition was studied by means of thermogravimetric analysis, scanning electron microscopy and energy dispersive X-ray analysis. Yttrium was added to this alloy in the forms of metallic addition, yttrium oxide and ion implant. Cracking and spalling occurred on the convoluted scale formed on Y-free alloy and exposed the substrate. A flat dense scale without spallation was formed on the yttrium alloying addition or yttrium oxide dispersion alloy. The scale adhesion was also improved by 1×1017Y+/cm2-implantation. The results indicate the convoluted morphology of the scale on Fe-23Cr-5Al-0.21Ti alloy is related to the growth mechanism of the alumina scale, and the spallation of the scale is related to sulfur segregation at the scale/alloy interface. The main reason that the adhesion of alumina scale is improved by yttrium addition lies in the following. Yttrium is liable to form a stable yttrium sulfide with sulfur in the alloy and prevent sulfur interface from segregation. Another reason is that the growth mechanism of alumina scale is changed by yttrium addition.

  10. Developing a Small-Scale De-Fluoridation Filter for Use in Rural Northern Ghana with Activated Alumina As the Sorbent

    Science.gov (United States)

    Craig, L.; Stillings, L. L.

    2014-12-01

    reaction time, the larger grain size adsorbed only 59% of F-, while at the finer grain size 90% was adsorbed. Future work will determine the volume of high F- water that can be treated before activated alumina needs to be regenerated or changed. These data will aid in the design of a small-scale F- adsorption filter in the study area, and will predict the longevity of activated alumina as the sorbent.

  11. Materials for spallation neutron sources

    Energy Technology Data Exchange (ETDEWEB)

    Sommer, W.F.; Daemen, L.L. [comps.

    1996-03-01

    The Workshop on Materials for Spallation Neutron Sources at the Los Alamos Neutron Science Center, February 6 to 10, 1995, gathered scientists from Department of Energy national laboratories, other federal institutions, universities, and industry to discuss areas in which work is needed, successful designs and use of materials, and opportunities for further studies. During the first day of the workshop, speakers presented overviews of current spallation neutron sources. During the next 3 days, seven panels allowed speakers to present information on a variety of topics ranging from experimental and theoretical considerations on radiation damage to materials safety issues. An attempt was made to identify specific problems that require attention within the context of spallation neutron sources. This proceedings is a collection of summaries from the overview sessions and the panel presentations.

  12. Status of spallation neutron source

    Energy Technology Data Exchange (ETDEWEB)

    Oyama, Yukio [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment

    1997-03-01

    Existing and planned facilities using proton accelerator driven spallation neutron source are reviewed. These include new project of neutron science proposed from Japan Atomic Energy Research Institute. The present status of facility requirement and accelerator technology leads us to new era of neutron science such as neutron scattering research and nuclear transmutation study using very intense neutron source. (author)

  13. Calcium aluminate in alumina

    Science.gov (United States)

    Altay, Arzu

    The properties of ceramic materials are determined not only by the composition and structure of the phases present, but also by the distribution of impurities, intergranular films and second phases. The phase distribution and microstructure both depend on the fabrication techniques, the raw materials used, the phase-equilibrium relations, grain growth and sintering processes. In this dissertation research, various approaches have been employed to understand fundamental phenomena such as grain growth, impurity segregation, second-phase formation and crystallization. The materials system chosen was alumina intentionally doped with calcium. Atomic-scale structural analyses of grain boundaries in alumina were carried on the processed samples. It was found that above certain calcium concentrations, CA6 precipitated as a second phase at all sintering temperatures. The results also showed that abnormal grain growth can occur after precipitation and it is not only related to the calcium level, but it is also temperature dependent. In order to understand the formation mechanism of CA6 precipitates in calcium doped alumina samples, several studies have been carried out using either bulk materials or thin films The crystallization of CA2 and CA6 powders has been studied. Chemical processing techniques were used to synthesize the powders. It was observed that CA2 powders crystallized directly, however CA6 powders crystallized through gamma-Al 2O3 solid solution. The results of energy-loss near-edge spectrometry confirmed that gamma-Al2O3 can dissolve calcium. Calcium aluminate/alumina reaction couples have also been investigated. All reaction couples were heat treated following deposition. It was found that gamma-Al2O3 was formed at the interface as a result of the interfacial reaction between the film and the substrate. gamma-Al 2O3 at the interface was stable at much higher temperatures compared to the bulk gamma-Al2O3 formed prior to the CA6 crystallization. In order to

  14. Spallation radiation effects in materials

    Energy Technology Data Exchange (ETDEWEB)

    Mansur, L.K.; Farrell, K.; Wechsler, M.S. [Oak Ridge National Lab., TN (United States)

    1996-06-01

    Spallation refers to the process whereby particles (chiefly neutrons) are ejected from nuclei upon bombardment by high-energy protons. Spallation neutron sources (SNS`s) use these neutrons for neutron scattering and diffraction research, and SNS`s are proposed as the basis for systems for tritium production and transmutation of nuclear waste. Materials in SNS`s are exposed to the incident proton beam (energies typically about 1000 MeV) and to the spallation neutrons (spectrum of energies extending up to about 1000 MeV). By contrast the fission neutrons in nuclear reactors have an average energy of only about 2 MeV, and the neutrons in fusion reactors would have energies below about 14 MeV. Furthermore, the protons and neutrons in SNS`s for scattering and diffraction research are pulsed at frequencies of about 10 to 60 Hz, from which significant changes in the kinetics of point and extended defects may be expected. In addition, much higher transmutation rates occur in SNS-irradiated materials, On the whole, then, significant differences in microstructural development and macroscopic properties may result upon exposure in SNS systems, as compared with fission and fusion irradiations. In a more general sense, subjecting materials to new radiation environments has almost routinely led to new discoveries. To the extent that data are avaiable, however, the spallation environment appears to increase the degree of damage without introducing totally new effects. The first part of this presentation is an overview of radiation effects in materials, outlining essential concepts and property changes and their physical bases. This background is followed by a description of SNS irradiation environments and the effects on materials of exposure to these environments. A special discussion is given of the selection of target (e.g., liquid mercury), container (e.g., austenitic stainless steel or ferritic/martensitic steel), and structural materials in SNS systems.

  15. Fracture toughness of advanced alumina ceramics and alumina matrix composites used for cutting tool edges

    Directory of Open Access Journals (Sweden)

    M. Szutkowska

    2012-10-01

    Full Text Available Purpose: Specific characteristics in fracture toughness measurements of advanced alumina ceramics and alumina matrix composites with particular reference to α-Al2O3, Al2O3-ZrO2, Al2O3-ZrO2-TiC and Al2O3-Ti(C,N has been presented.Design/methodology/approach: The present study reports fracture toughness obtained by means of the conventional method and direct measurements of the Vickers crack length (DCM method of selected tool ceramics based on alumina: pure alumina, alumina-zirconia composite with unstabilized and stabilized zirconia, alumina–zirconia composite with addition of TiC and alumina–nitride-carbide titanium composite with 2wt% of zirconia. Specimens were prepared from submicro-scale trade powders. Vicker’s hardness (HV1, fracture toughness (KIC at room temperature, the indentation fracture toughness, Young’s modulus and apparent density were also evaluated. The microstructure was observed by means of scanning electron microscopy (SEM.Findings: The lowest value of KIC is revealed by pure alumina ceramics. The addition of (10 wt% unstabilized zirconia to alumina or a small amount (5 wt% of TiC to alumina–zirconia composite improve fracture toughness of these ceramics in comparison to alumina ceramics. Alumina ceramics and alumina-zirconia ceramics reveal the pronounced character of R-curve because of an increasing dependence on crack growth resistance with crack extension as opposed to the titanium carbide-nitride reinforced composite based on alumina. R-curve has not been observed for this composite.Practical implications: The results show the method of fracture toughness improvement of alumina tool ceramics.Originality/value: Taking into account the values of fracture toughness a rational use of existing ceramic tools should be expected.

  16. Dissolution of alumina in stainless steelmaking slags

    Energy Technology Data Exchange (ETDEWEB)

    Divakar, M.; Lahiri, A.K. [Indian Inst. of Science, Bangalore (India). Dept. of Metallurgy; Goernerup, M. [Uddeholm Technology AB (Sweden)

    2001-02-01

    Dissolution of alumina in stainless steelmaking slags was studied by conducting laboratory scale experiments on typical slags in the temperature range 1823-1923 K. The mechanism of dissolution was studied under the actual steelmaking conditions where several phenomena such as simultaneous reduction of chromium, iron and vanadium oxides by carbon, in-situ gas generated due to the reduction, foam/emulsion formation occur. The kinetics of alumina dissolution are studied under the influence of the above mentioned phenomena. (orig.)

  17. Bauxite and alumina

    Science.gov (United States)

    Bray, E.L.

    2009-01-01

    The article provides information on bauxite and alumina mining. U.S. states like Alabama, Arkansas and Georgia produced small amounts of bauxite and bauxitic clays for nonmetallurgical uses. Total metallurgical-grade bauxite imports in 2008 is cited. The leading suppliers of bauxite to the U.S. are Jamaica, Guinea and Brazil. The estimated domestic production of alumina in 2008 is mentioned. It also discusses consumption and prices of both bauxite and alumina.

  18. Cold moderators for spallation sources

    International Nuclear Information System (INIS)

    Moderators using liquid and solid methane and liquid hydrogen are currently in use at major spallation neutron sources. Los Alamos Neutron Scattering Center (LANSCE) is planning the use of liquid methane as part of a major update program planned in about three years time. This report presents a general overview of some of these devices and outlines the general engineering design of the proposed LANSCE moderator, including some suggested solutions to the radiation damage problems of methane. Also included is a brief overview of a possible combined H2/Ch4 moderator for high intensity proton beams. 15 figs

  19. Cold moderators for spallation sources

    International Nuclear Information System (INIS)

    Moderators using both liquid and solid methane and liquid hydrogen are currently in use at major spallation neutron sources. Los Alamos Neutron Scattering Center (LANSCE) is planning the use of liquid methane as part of a major update program planned in about three years time. This report presents an overview of some of these devices and outlines the general engineering design of the proposed LANSCE moderator, including some suggested solutions to the radiation damage problems of methane. Also included is a brief overview of a possible combined H2/CH4 moderator for high-intensity proton beams, which is covered in more detail in a separate paper. 15 figs

  20. Spallation performance of extracorporeal membrane oxygenation tubing.

    Science.gov (United States)

    Peek, G J; Thompson, A; Killer, H M; Firmin, R K

    2000-09-01

    During the prolonged roller pump use of extracorporeal membrane oxygenation (ECMO), tubing wear generates spallation. The spallation performance of Tygon S-65-HL was measured and compared with a potential new ECMO tubing, LVA (Portex 800-500-575). Spallation was measured by on-line laser diode particle counting (HIAC) during simulated ECMO. The effects of differing levels of occlusion and pump speed were examined, as was the effect of spallation over time. The spallation produced by Tygon S-65-HL was less than that seen with LVA during 24 h of simulated ECMO (p < 0.001), and after 72 h had fallen almost to zero. Spallation with Tygon tubing increases with increasing pump speed and decreases over time. There appears to be only a weak correlation with occlusion, which is surprising. The spallation performance of Tygon S-65-HL was variable and under some conditions exceeded that of LVA. Overall, however, Tygon S-65-HL produced less spallation than LVA. Therefore, LVA cannot be recommended for clinical ECMO use. PMID:11001170

  1. Large Scale Laser Crystallization of Solution-based Alumina-doped Zinc Oxide (AZO) Nanoinks for Highly Transparent Conductive Electrode

    Science.gov (United States)

    Nian, Qiong; Callahan, Michael; Saei, Mojib; Look, David; Efstathiadis, Harry; Bailey, John; Cheng, Gary J.

    2015-10-01

    A new method combining aqueous solution printing with UV Laser crystallization (UVLC) and post annealing is developed to deposit highly transparent and conductive Aluminum doped Zinc Oxide (AZO) films. This technique is able to rapidly produce large area AZO films with better structural and optoelectronic properties than most high vacuum deposition, suggesting a potential large-scale manufacturing technique. The optoelectronic performance improvement attributes to UVLC and forming gas annealing (FMG) induced grain boundary density decrease and electron traps passivation at grain boundaries. The physical model and computational simulation developed in this work could be applied to thermal treatment of many other metal oxide films.

  2. Oxidation-induced strains in thermally grown alumina scales on Ni-base alloys: An in situ synchrotron radiation study

    Science.gov (United States)

    Reddy, Kancharla-Arun K.

    The stresses developed during the formation of alpha-Al2O 3 on Ni-base alloy bond coats can lead to premature failure of thermal barrier systems, which have been used for almost three decades to extend the life of gas turbine systems. Conventional X-ray diffraction techniques are difficult and have not been totally satisfactory for measuring the stresses in situ in Al2O3 scales. In this work, in situ evolution of growth strains in Al2O3 scales formed on a variety of Ni-base alloys, as well as thermal mismatch strains developed during cooling have been studied using 21.6 keV X-ray synchrotron radiation. The lattice strains in the Al 2O3 scales were obtained by analyzing the elliptical distortions of Debye-Scherrer (DS) diffraction rings which develop in response to the presence of in-plane stresses in the oxide. A model NiCrAlY bond coat alloy was investigated in air at four oxidation temperatures: 950, 1000, 1050 and 1100°C. While the growth stresses in alpha-Al 2O3 were tensile at all temperatures, stress relaxation is observed only at 1050 and 1100°C. Stresses in the TGOs in these samples at room temperature were also measured by piezospectroscopy and laboratory XRD, with good agreement between all three methods. A quasi-peritectoid phase transformation in the bond coat leads to a greatly increased room temperature compressive stresses in the samples oxidized at 1050 and 1100°C. The evolution of growth stresses in single crystal NiAl at 1100°C is dependent on crystallographic orientation. Epitaxial issues at the NiAl/Al 2O3 interface appear to govern initial formation of gamma- or theta-Al2O3 and its subsequent transformation to the stable and denser alpha-Al2O3 polymorph. This transformation generates tensile stresses in alpha-Al2O 3, which relax with further oxidation. The present work also independently confirms an error in the sign of one of the elastic constants reported in the literature. The value of c14 reported in the literature is -22 GPa but this

  3. Spallator: a new option for nuclear power

    Energy Technology Data Exchange (ETDEWEB)

    Steinberg, M.; Grand, P.; Takahashi, H.; Powell, J.R.; Kouts, H.J.

    1983-06-01

    The principles of the spallator reactor are reviewed. Advances in linear accelerator technology allow the design and construction of high current (hundreds of mA) continuous wave high energy (thousands of MeV) proton machines in the near term. Spallation neutronic calculations building on existing experimental results, indicate substantial neutron yields on uranium targets. Spallator target assembly designs based on water cooled reactor technology indicate operable efficient systems. Fuel cycles are presented which supply fissile material to thermal power reactors and reduce fission product waste. Preliminary comparative analysis indicates an economically competitive system in which a single purpose self-sufficient spallator supplies fuel to a number of LWRs. The spallator assures a long-term LWR power reactor economy. International interest in advancing the technology is indicated.

  4. PREFACE: Neutrino physics at spallation neutron sources

    Science.gov (United States)

    Avignone, F. T.; Chatterjee, L.; Efremenko, Y. V.; Strayer, M.

    2003-11-01

    Unique because of their super-light masses and tiny interaction cross sections, neutrinos combine fundamental physics on the scale of the miniscule with macroscopic physics on the scale of the cosmos. Starting from the ignition of the primal p-p chain of stellar and solar fusion reactions that signal star-birth, these elementary leptons (neutrinos) are also critical players in the life-cycles and explosive deaths of massive stars and the production and disbursement of heavy elements. Stepping beyond their importance in solar, stellar and supernova astrophysics, neutrino interactions and properties influence the evolution, dynamics and symmetries of the cosmos as a whole. Further, they serve as valuable probes of its material content at various levels of structure from atoms and nuclei to valence and sea quarks. In the light of the multitude of physics phenomena that neutrinos influence, it is imperative to enhance our understanding of neutrino interactions and properties to the maximum. This is accentuated by the recent evidence of finite neutrino mass and flavour mixing between generations that reverberates on the plethora of physics that neutrinos influence. Laboratory experiments using intense neutrino fluxes would allow precision measurements and determination of important neutrino reaction rates. These can then complement atmospheric, solar and reactor experiments that have enriched so valuably our understanding of the neutrino and its repertoire of physics applications. In particular, intermediate energy neutrino experiments can provide critical information on stellar and solar astrophysical processes, along with advancing our knowledge of nuclear structure, sub-nuclear physics and fundamental symmetries. So where should we look for such intense neutrino sources? Spallation neutron facilities by their design are sources of intense neutrino pulses that are produced as a by-product of neutron spallation. These neutrino sources could serve as unique laboratories

  5. Challenges and Strategies in the Synthesis of Mesoporous Alumina Powders and Hierarchical Alumina Monoliths

    Directory of Open Access Journals (Sweden)

    Anne Galarneau

    2012-02-01

    Full Text Available A new rapid, very simple and one-step sol-gel strategy for the large-scale preparation of highly porous γ-Al2O3 is presented. The resulting mesoporous alumina materials feature high surface areas (400 m2 g−1, large pore volumes (0.8 mL g−1 and the ��-Al2O3 phase is obtained at low temperature (500 °C. The main advantages and drawbacks of different preparations of mesoporous alumina materials exhibiting high specific surface areas and large pore volumes such as surfactant-nanostructured alumina, sol-gel methods and hierarchically macro-/mesoporous alumina monoliths have been analyzed and compared. The most reproducible synthesis of mesoporous alumina are given. Evaporation-Induced Self-Assembly (EISA is the sole method to lead to nanostructured mesoporous alumina by direct templating, but it is a difficult method to scale-up. Alumina featuring macro- and mesoporosity in monolithic shape is a very promising material for in flow applications; an optimized synthesis is described.

  6. Reuse of activated alumina

    Energy Technology Data Exchange (ETDEWEB)

    Hobensack, J.E. [Martin Marietta Energy Systems, Inc., Piketon, OH (United States)

    1991-12-31

    Activated alumina is used as a trapping media to remove trace quantities of UF{sub 6} from process vent streams. The current uranium recovery method employs concentrated nitric acid which destroys the alumina pellets and forms a sludge which is a storage and disposal problem. A recently developed technique using a distilled water rinse followed by three dilute acid rinses removes on average 97% of the uranium, and leaves the pellets intact with crush strength and surface area values comparable with new material. Trapping tests confirm the effectiveness of the recycled alumina as UF{sub 6} trapping media.

  7. Targets for neutron beam spallation sources

    International Nuclear Information System (INIS)

    The meeting on Targets for Neutron Beam Spallation Sources held at the Institut fuer Festkoerperforschung at KFA Juelich on June 11 and 12, 1979 was planned as an informal get-together for scientists involved in the planning, design and future use of spallation neutron sources in Europe. These proceedings contain the papers contributed to this meeting. For further information see hints under relevant topics. (orig./FKS)

  8. Physics and technology of spallation neutron sources

    Energy Technology Data Exchange (ETDEWEB)

    Bauer, G.S.

    1998-08-01

    Next to fission and fusion, spallation is an efficient process for releasing neutrons from nuclei. Unlike the other two reactions, it is an endothermal process and can, therefore, not be used per se in energy generation. In order to sustain a spallation reaction, an energetic beam of particles, most commonly protons, must be supplied onto a heavy target. Spallation can, however, play an important role as a source of neutrons whose flux can be easily controlled via the driving beam. Up to a few GeV of energy, the neutron production is roughly proportional to the beam power. Although sophisticated Monte Carlo codes exist to compute all aspects of a spallation facility, many features can be understood on the basis of simple physics arguments. Technically a spallation facility is very demanding, not only because a reliable and economic accelerator of high power is needed to drive the reaction, but also, and in particular, because high levels of radiation and heat are generated in the target which are difficult to cope with. Radiation effects in a spallation environment are different from those commonly encountered in a reactor and are probably even more temperature dependent than the latter because of the high gas production rate. A commonly favored solution is the use of molten heavy metal targets. While radiation damage is not a problem in this case, except for the container, a number of other issues are discussed. (author)

  9. Physics and technology of spallation neutron sources

    International Nuclear Information System (INIS)

    Next to fission and fusion, spallation is an efficient process for releasing neutrons from nuclei. Unlike the other two reactions, it is an endothermal process and can, therefore, not be used per se in energy generation. In order to sustain a spallation reaction, an energetic beam of particles, most commonly protons, must be supplied onto a heavy target. Spallation can, however, play an important role as a source of neutrons whose flux can be easily controlled via the driving beam. Up to a few GeV of energy, the neutron production is roughly proportional to the beam power. Although sophisticated Monte Carlo codes exist to compute all aspects of a spallation facility, many features can be understood on the basis of simple physics arguments. Technically a spallation facility is very demanding, not only because a reliable and economic accelerator of high power is needed to drive the reaction, but also, and in particular, because high levels of radiation and heat are generated in the target which are difficult to cope with. Radiation effects in a spallation environment are different from those commonly encountered in a reactor and are probably even more temperature dependent than the latter because of the high gas production rate. A commonly favored solution is the use of molten heavy metal targets. While radiation damage is not a problem in this case, except for the container, a number of other issues are discussed. (author)

  10. Study of the molybdenum retention in alumina; Estudio de la retencion de molibdeno en alumina

    Energy Technology Data Exchange (ETDEWEB)

    Wilkinson, Maria V.; Mondino, Angel V.; Manzini, Alberto [Comision Nacional de Energia Atomica, Buenos Aires (Argentina). Centro Atomico Ezeiza. Radioquimica y Quimica de las Radiaciones

    2002-07-01

    The Argentine National Atomic Energy Commission routinely produces {sup 99} Mo by fission of highly enriched uranium contained in targets irradiated in RA-3 reactor. The current process begins with the dissolution of the irradiated target in a basic media, considering the possibility of changing the targets, it could be convenient to dissolve them in acid media. The use of alumina as a first separation step in acid dissolution processes is already known although it is necessary to determine both the type of alumina to be used and the separation conditions. The study of molybdenum retention in alumina was performed at laboratory scale, using Mo-99 as radiotracer. Different kinds of alumina were tried, varying charge solution acidity. Influence of uranium concentration in the loading solution on molybdenum retention was also studied. (author)

  11. Modeling adsorption on fluoride and application of Box–Behnken design and response surface methodology for arsenic(V removal from aqueous solution using Nano-Scale Alumina on Multi Walled Carbon Nanotube

    Directory of Open Access Journals (Sweden)

    H Zarei

    2016-01-01

    Full Text Available Objective and Background: Fluoride is an element widely found in the earth crust. Advantages and disadvantages of fluoride in the human body are depended on its concentration. Long-term consumption of drinking water contaminated with arsenic can cause adverse health effects such as skin lesions and cancer in humans. The aim of this study was to study efficiency of nano alumina on multi walled carbon nano tube  for removal As(V and fluoride from aqueous solution. Materials and Method: In this study, nano-scale crystalline alumina was synthesized on single walled carbon nanotube by sol-gel method for using as a sorbent for solid phase extraction of Fluorine ion and arsenic(V. Response surface methodology based on Box-Behnken was used to assess the effect of independent variables on the response function and prediction of the best response value. In this study, effect of different parameters, such as contact time (10 to 120 min, pH (3-9, adsorbent dosage (0.25-1.5 g/L and initial concentration of fluoride (2-8 mg/L on efficiency of process was investigated. The structure of nano-scale alumina on multi walled carbon nano tube was determined by XRD and SEM techniques. Moreover, Freundlich and Langmuir isotherm models were used to calculate equilibrium constant. Results: It was found that by increasing contact time and adsorbent dosage the rate of fluoride removal increased. However, by increasing pH and initial concentration the efficiency of fluoride removal decreased. High value for R2 (0.94 shows that removal of arsenic(V can be described by this model. The Freundlich isotherm was the best fitted graph for experimental data with R2 more than 0.997. Conclusion: In this study, it was observed that efficiency of arsenic(V and fluoride  removal was greatly increased by using nano-scale alumina on multi walled carbon nanotubes (MWCNTs.

  12. The Spallation Neutron Source A Powerful Tool for Materials Research

    CERN Document Server

    Mason, Thomas E; Crawford, R K; Herwig, K W; Klose, F; Ankner, J F

    2005-01-01

    The wavelengths and energies of thermal and cold neutrons are ideally matched to the length and energy scales in the materials that underpin technologies of the present and future: ranging from semiconductors to magnetic devices, composites to biomaterials and polymers. The Spallation Neutron Source (SNS) will use an accelerator to produce the most intense beams of neutrons in the world when it is complete at the end of 2005. The project is being built by a collaboration of six U.S. Department of Energy laboratories. It will serve a diverse community of users drawn from academia, industry, and government labs with interests in condensed matter physics, chemistry, engineering materials, biology, and beyond.

  13. New science at the European Spallation Source

    Energy Technology Data Exchange (ETDEWEB)

    Finney, J.L. [University Coll., London (United Kingdom). Dept. of Physics and Astronomy

    1996-05-01

    The European Spallation Source is a trans-European project aimed at the ultimate construction of a next-generation pulsed spallation neutron source that will deliver 30 times the beam power of ISIS. The reference design for the proposed source has been set, and work is in progress to develop an updated scientific case for the construction of the source early in the next century. Together with improvements in instrumentation, effective flux gains of over two orders of magnitude are likely in some areas, opening up major new opportunities for the exploitation of neutron studies in fundamental, strategic, and applied science. (author)

  14. Management of Tritium in European Spallation Source

    DEFF Research Database (Denmark)

    Ene, Daniela; Andersson, Kasper Grann; Jensen, Mikael;

    2015-01-01

    The European Spallation Source (ESS) will produce tritium via spallation and activation processes during operational activities. Within the location of ESS facility in Lund, Sweden site it is mandatory to demonstrate that the management strategy of the produced tritium ensures the compliance...... with the country regulation criteria. The aim of this paper is to give an overview of the different aspects of the tritium management in ESS facility. Besides the design parameter study of the helium coolant purification system of the target the consequences of the tritium releasing into the environment were also...

  15. Windowless target: Design of the XT-ADS spallation target

    International Nuclear Information System (INIS)

    The design of the XT-ADS spallation target is performed within the European integrated project EUROTRANS (FP6 Contract FI6W-516520) that has started in April 2005. At the current status of the spallation target design process, the boundary conditions for the spallation target loop with respect to the XT-ADS performance requirements and the design of the subcritical core and primary system have been established. The next steps will concentrate on further development of the spallation target nozzle, the vacuum and spallation product confinement system and the pumping, LIDAR (LIght Detection And Ranging) and cooling system

  16. Spallation neutron source RF cavity bias system

    International Nuclear Information System (INIS)

    The Spallation Neutron Source r.f. cavity bias system is described under the topic headings: bias system, r.f. cavity, cables, d.c. bias power supply, transistor regulator and control system. Calculation of 4 core 300 mm solid aluminium cable inductance, coaxial shunt frequency response and transistor regulator computed frequency response, are discussed in appendices 1-3. (U.K.)

  17. Material selection for spallation neutron source windows

    Energy Technology Data Exchange (ETDEWEB)

    Sordo, F. [ETSII/Universidad Politecnica de Madrid, J. Gutierrez Abascal, 2-28006 Madrid (Spain); Abanades, A. [ETSII/Universidad Politecnica de Madrid, J. Gutierrez Abascal, 2-28006 Madrid (Spain)], E-mail: abanades@etsii.upm.es; Lafuente, A.; Martinez-Val, J.M. [ETSII/Universidad Politecnica de Madrid, J. Gutierrez Abascal, 2-28006 Madrid (Spain); Perlado, M. [Instituto de Fusion Nuclear (DENIM)/ETSII/Universidad Politecnica, Madrid, J. Gutierrez Abascal, 2-28006 Madrid (Spain)

    2009-11-15

    High performance neutron sources are being proposed for many scientific and industrial applications, ranging from material studies, hybrid reactors and transmutation of nuclear wastes. In the case of transmutation of nuclear wastes, accelerator driven systems (ADS) are considered as one of the main technical options for such purpose. In ADS a high performance spallation neutron source becomes an essential element for its operation and control. This spallation source must fulfil very challenging nuclear and thermo-mechanical requirements, because of the high neutron rates needed in ADS. The material selection for this key component becomes of paramount importance, particularly the source window that separates the vacuum accelerator tube from the spallation material where the accelerated protons impinge. In this paper, an integral analysis of spallation sources is done, taking as a reference the projects in this field proposal in the framework of European projects. Our analysis and calculations show that titanium and vanadium alloys are more suitable than steel as structural material for an industrial ADS beam window, mostly due to its irradiation damage resistance.

  18. SUPERCONDUCTING LINAC FOR THE SPALLATION NEUTRON SOURCE

    International Nuclear Information System (INIS)

    The Spallation Neutron Source (SNS) linac is comprised of both normal and superconducting rf (SRF) accelerating structures. The SRF linac accelerates the beam from 186 to 1250 MeV through 117 elliptical, multi-cell niobium cavities. This paper describes the SRF linac architecture, physics design considerations, cavity commissioning, and the expected beam dynamics performance

  19. Improvement in nanoscale contact resistance of alumina

    Energy Technology Data Exchange (ETDEWEB)

    Bhattacharya, Manjima; Chakraborty, Riya; Mandal, Ashok Kumar [CSIR - Central Glass and Ceramic Research Institute, Kolkata (India); Dey, Arjun [CSIR - Central Glass and Ceramic Research Institute, Kolkata (India); ISRO Satellite Centre, Thermal Systems Group, Bangalore (India); Mukhopadhyay, Anoop Kumar [CSIR - Central Glass and Ceramic Research Institute, Kolkata (India); Central Glass and Ceramic Research Institute, Kolkata 32 (India)

    2012-06-15

    In all contact-related applications such as the wear-resistant inserts, biomedical implants, high strain rate impact-resistant plates, etc., nanohardness, i.e. the intrinsic contact resistance at the nano scale, plays a major role. In spite of the wealth of literature, the studies on nanohardness of dense, coarse-grain alumina ceramics which represent many commercial varieties; have reasonably good hardness at the macro scale and characteristically exhibit R-curve behaviour, are far from significant. Here, to the best of our knowledge, we report for the first time the experimental observations of the increase in intrinsic contact resistance at the nano scale with the loading rate applied to a high-density ({proportional_to}95 % of theoretical) coarse-grain ({proportional_to}20 {mu}m) alumina ceramics. These observations were explained in terms of the initiation of nanoscale plasticity and maximum shear stress generated just underneath the nanoindenter. (orig.)

  20. Thermal-hydraulic analysis of LBE spallation target for accelerator-driven systems

    Indian Academy of Sciences (India)

    Aniseh Ahmed Atef Abdalla; Jiyang Yu; Yongwel Yang

    2013-01-01

    In an accelerator-driven subcritical system (ADS), a high-performance spallation neutron source is used to feed the subcritical reactor. Neutron generation depends on the proton beam intensity. If the beam intensity is increased by a given factor, the number of generated neutrons will increase. The mechanism yielding a high rate of neutron production per energy is the spallation process, and this mechanism produces very high-energy deposition in the spallation target material. Producing a high rate of neutrons is accompanied by creation of problems of decay heat cooling and radiological protection. As a first step in designing a full-scale industrial ADS, a small-scale experimental ADS, which is similar to the European experimental ADS (XADS) is analysed. The analysis presented in this paper is based on lead–bismuth eutectic (LBE) cooled XADS-type experimental reactors, designed during the European experimental (PDS-XADS) project. Computational fluid dynamics analysis has been carried out for the spallation target. Steady-state behaviour and shear stress transport turbulence model with the automatic wall treatment were applied in the present analysis.

  1. Deformation Behaviour of Coarse Grain Alumina under Shock Loading

    Science.gov (United States)

    Gupta, Satish

    2013-06-01

    To develop better understanding of the shock wave induced deformation behavior of coarse grain alumina ceramics, and for measurement of its Hugoniot Elastic Limit (HEL), in-situ and recovery gas gun experiments have been carried out on coarse grain alumina (grain size ~ 10 μm), prepared in the form of discs (>99.9% TMD) by pressure-less sintering of alpha alumina powder at 1583 K. The HEL value of 1.9 GPa has been determined from the kink in the pressure history recorded using piezoresistance gauge and also from the free surface velocity history of the sample shocked to 9 GPa. The nano-indentation measurements on the alumina samples shocked to 6.5 GPa showed hardness value 15% lower than 21.3 GPa for unshocked alumina, and strong Indentation Size Effect (ISE); the hardness value was still lower and the ISE was stronger for the sample shocked to 12 GPa. The XRD measurements showed reduced particle size and increased microstrains in the shocked alumina fragments. SEM, FESEM and TEM measurements on shock treated samples showed presence of grain localized micro- and nano-scale deformations, micro-cleavages, grain-boundary microcracks, extensive shear induced deformations, and localized micro-fractures, etc. These observations led to the development of a qualitative model for the damage initiation and its subsequent growth mechanisms in shocked alumina. The work performed in collaboration with K.D. Joshi of BARC and A.K. Mukhopadhyay of CGCRI.

  2. INJECTION CHOICE FOR SPALLATION NEUTRON SOURCE RING.

    Energy Technology Data Exchange (ETDEWEB)

    WEI,J.; BEEBE-WANG,J.; BLASKIEWICZ,M.; BRODOWSKI,J.; FEDOTOV,A.; GARDNER,C.; LEE,Y.Y.; RAPARIA,D.; DANILOV,V.; HOLMES,J.; PRIOR,C.; REES,G.; MACHIDA,S.

    2001-06-18

    Injection is key in the low-loss design of high-intensity proton facilities like the Spallation Neutron Source (SNS). During the design of both the accumulator and the rapid-cycling-synchrotron version of the SNS, extensive comparison has been made to select injection scenarios that satisfy SNS's low-loss design criteria. This paper presents issues and considerations pertaining to the final choice of the SNS injection systems.

  3. Laser-Induced Spallation of Microsphere Monolayers

    OpenAIRE

    Hiraiwa, Morgan; Stossel, Melicent; Khanolkar, Amey; Wang, Junlan; Boechler, Nicholas

    2016-01-01

    The detachment of a semi-ordered monolayer of polystyrene microspheres adhered to an aluminum-coated glass substrate is studied using a laser-induced spallation technique. The microsphere-substrate adhesion force is estimated from substrate surface displacement measurements obtained using optical interferometry, and a rigid-body model that accounts for the inertia of the microspheres. The estimated adhesion force is compared with estimates obtained from interferometric measurement of the out-...

  4. Neutron scattering and spallation neutron sources

    International Nuclear Information System (INIS)

    Neutron scattering as a probe of microscopic structure and dynamics is a powerful tool for research in a wide variety of fields, and an accelerator-based spallation neutron source can supply high flux pulses for neutron scattering. The characteristics of neutron scattering, the principle and development of spallation neutron sources, and their advantages in multidisciplinary applications are summarized. In the proposed project of the Chinese Spallation Neutron Source the target station will consist of a piece-stacked tungsten target, a Be/Fe reflector and an Fe/heavy concrete bio-protected shelter. The pulsed neutron flux will be up to 2.4 x 1016 n/cm2/s under a nuclear power of 100 kW. Five neutron scattering instruments--a high flux powder diffractometer, a high resolution powder diffractometer, small angle diffractometer, multi-functional reflectometer and direct geometry inelastic spectrometer, will be constructed as the first step to cover most neutron scattering applications. (authors)

  5. Spallation reactions studied with 4-detector arrays

    Indian Academy of Sciences (India)

    J Galin

    2001-07-01

    Recently there has been a renewed interest in the study of spallation reactions in basic nuclear physics as well as in potential applications. Spallation reactions induced by light projectiles (protons, antiprotons, pions, etc.) in the GeV range allow the formation of hot nuclei which do not suffer the collective excitations (compression, rotation, deformation) unavoidable when using massive projectiles. Such nuclei provide an ideal testbench for probing their decay as a function of excitation energy. In these investigations, 4-detector arrays for charged particles and neutrons play a major role in the event-by-event sorting according to the excitation energy of the nucleus. Spallation reactions induced on heavy nuclei allow the conversion of the incident GeV proton into several tens of evaporated neutrons. The neutron production in thick targets has been investigated in great detail thanks to the use of high efficiency neutron detector arrays. When scattered on samples of inert or biological materials, these neutrons can be used to study details of the material structure. They could also be utilized for the transmutation of long-lived nuclear wastes or for the feeding of sub-critical nuclear reactors. The role of different types of multi-detector arrays is highlighted in this paper. Several references are also given for different uses of high efficiency neutron detectors in other contexts.

  6. A comparison between short pulse spallation source and long pulse spallation source

    Energy Technology Data Exchange (ETDEWEB)

    Aizawa, Kazuya; Watanabe, Noboru; Suzuki, Jun-ichi; Niimura, Nobuo; Morii, Yukio; Katano, Susumu; Osakabe, Toyotaka; Teshigawara, Makoto [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment; Mezei, F.

    1997-11-01

    The performance for a 5 MW short pulse spallation source (SPSS) and a 4.5 MW long pulse spallation source (LPSS) in a JAERI program which is based on the availability of a 1.5 GeV superconducting linac with a 30 mA peak current for both proton and H{sup -} beams is discussed. We have examined the superiority of SPSS to LPSS. While a LPSS facility is a second option, we propose an SPSS facility as a first option. (author)

  7. Study on ADS Pb (Pb/Bi) spallation target

    International Nuclear Information System (INIS)

    The neutron yield and double differential cross section of outgoing neutron produced in p+Pb spallation reaction up to 1.6 GeV have been investigated by some theoretical. Residual radioactivity, energy deposition and radiation damage of the Pb target were studied as well. A verification facility commented of a swimming pool reactor driven by a pulsed low energy high current accelerator (150-300 MeV/3mA) is planned in the next phase of our project. Pb-Bi eutectic is one of the options as the target material in the facility. In order to investigate the material compatibility and the thermohydraulics of Pb-Bi eutectic, a simplified small-scale loop is under designing. (author)

  8. Prototype Spallation Neutron Source Rotating Target Assembly Final Test Report

    Energy Technology Data Exchange (ETDEWEB)

    McManamy, Thomas J [ORNL; Graves, Van [Oak Ridge National Laboratory (ORNL); Garmendia, Amaia Zarraoa [IDOM Bilbao; Sorda, Fernando [ESS Bilbao; Etxeita, Borja [IDOM Bilbao; Rennich, Mark J [ORNL

    2011-01-01

    A full-scale prototype of an extended vertical shaft, rotating target assembly based on a conceptual target design for a 1 to 3-MW spallation facility was built and tested. Key elements of the drive/coupling assembly implemented in the prototype include high integrity dynamic face seals, commercially available bearings, realistic manufacturing tolerances, effective monitoring and controls, and fail-safe shutdown features. A representative target disk suspended on a 3.5 meter prototypical shaft was coupled with the drive to complete the mechanical tests. Successful operation for 5400 hours confirmed the overall mechanical feasibility of the extended vertical shaft rotating target concept. The prototype system showed no indications of performance deterioration and the equipment did not require maintenance or relubrication.

  9. Monitoring of heavy water flow in a 'cannelloni' spallation target through fluctuation analysis of measured temperatures

    International Nuclear Information System (INIS)

    A simple and reliable technique of heavy water flow rate monitoring in a 'cannelloni' spallation target is described in this paper. The Swiss Spallation Neutron Source (SINQ) is a large scale facility for matter scattering at Paul Scherrer Institute; neutrons are produced in the spallation target composed of a bundle of zircaloy rods filled with lead. A beam of high speed protons strikes the rods. Neutrons and a large amount of thermal power (up to 800 kW) are produced by spallation reaction. Cooling is essential for safe and proper work of the target. Redundancy of all the monitoring systems is considered beneficial for overall safety of the facility. The paper below introduces an alternative way for coolant (heavy water, D2O) flow monitoring by measurement of propagation of thermal transient fronts in the target. Several data processing methods are analyzed. The heavy water (D2O) circulates between the bundle of rods and a heat exchanger. The proton beam current is not fully stable - as a rule there are at least 4 – 6 beam trips occurring during one hour of the target operation. These proton beam trips lead to a rapid change in heat release in the target spallation zone and corresponding change in the cooling water temperature. Such temperature fluctuation front arise in the water flow from the target's spallation zone towards the heat exchanger. The target cooling loop is equipped with several thermocouples placed along the heavy water flow path; the thermocouples are connected to a data acquisition system, which records the signals. The thermocouples placed at different distances downstream the target spallation zone react one by one to the passage of a temperature fluctuation front. Thus the water flow rate can be calculated based on time difference between the moments this temperature front been detected at different time by sequently placed thermocouples. (author)

  10. Mesoscale Modelling of the Response of Aluminas

    International Nuclear Information System (INIS)

    The response of polycrystalline alumina to shock is not well addressed. There are several operating mechanisms that only hypothesized which results in models which are empirical. A similar state of affairs in reactive flow modelling led to the development of mesoscale representations of the flow to illuminate operating mechanisms. In this spirit, a similar effort is undergone for a polycrystalline alumina. Simulations are conducted to observe operating mechanisms at the micron scale. A method is then developed to extend the simulations to meet response at the continuum level where measurements are made. The approach is validated by comparison with continuum experiments. The method and results are presented, and some of the operating mechanisms are illuminated by the observed response

  11. Neutronic performance issues for the Spallation Neutron Source moderators

    Energy Technology Data Exchange (ETDEWEB)

    Iverson, E.B.; Murphy, B.D. [Oak Ridge National Laboratory, Spallation Neutron Source, Oak Ridge, TN (United States)

    2001-03-01

    We continue to develop the neutronic models of the Spallation Neutron Source target station and moderators in order to better predict the neutronic performance of the system as a whole and in order to better optimize that performance. While we are not able to say that every model change leads to more intense neutron beams being predicted, we do feel that such changes are advantageous in either performance or in the accuracy of the prediction of performance. We have computationally and experimentally studied the neutronics of hydrogen-water composite moderators such as are proposed for the SNS Project. In performing these studies, we find that the composite moderator, at least in the configuration we have examined, does not provide performance characteristics desirable for the instruments proposed and being designed for this neutron scattering facility. The pulse width as a function of energy is significantly broader than for other moderators, limiting attainable resolution-bandwidth combinations. Furthermore, there is reason to expect that higher-energy (0.1-1 eV) applications will be significantly impacted by bimodal pulse shapes requiring enormous effort to parameterize. As a result of these studies, we have changed the SNS design, and will not use a composite moderator at this time. We have analyzed the depletion of a gadolinium poison plate in a hydrogen moderator at the Spallation Neutron Source, and found that conventional poison thicknesses will be completely unable to last the desired component lifetime of three operational years. A poison plate 300-600 {mu}m thick will survive for the required length of time, but will somewhat degrade the intensity (by as much as 15% depending on neutron energy) and the consistency of the neutron source performance. Our results should scale fairly easily to other moderators on this or any other spallation source. While depletion will be important for all highly-absorbing materials in high-flux regions, we feel it likely

  12. Spallation recoil II: Xenon evidence for young SiC grains

    Science.gov (United States)

    Ott, U.; Altmaier, M.; Herpers, U.; Kuhnhenn, J.; Merchel, S.; Michel, R.; Mohapatra, R. K.

    2005-11-01

    We have determined the recoil range of spallation xenon produced by irradiation of Ba glass targets with ˜1190 and ˜268 MeV protons, using a catcher technique, where spallation products are measured in target and catcher foils. The inferred range for 126Xe produced in silicon carbide is ˜0.19 μm, which implies retention of ˜70% for 126Xe produced in "typical" presolar silicon carbide grains of 1 μm size. Recoil loss of spallation xenon poses a significantly smaller problem than loss of the spallation neon from SiC grains. Ranges differ for the various Xe isotopes and scale approximately linearly as function of the mass difference between the target element, Ba, and the product. As a consequence, SiC grains of various sizes will have differences in spallation Xe composition. In an additional experiment at ˜66 MeV, where the recoil ranges of 22Na and 127Xe produced on Ba glass were determined using γ-spectrometry, we found no evidence for recoil ranges being systematically different at this lower energy. We have used the new data to put constraints on the possible presolar age of the SiC grains analyzed for Xe by Lewis et al. (1994). Uncertainties in the composition of the approximately normal Xe component in SiC (Xe-N) constitute the most serious problem in determining an age, surpassing remaining uncertainties in Xe retention and production rate. A possible interpretation is that spallation contributions are negligible and that trapped 124Xe/126Xe is ˜5% lower in Xe-N than in Q-Xe. But also for other reasonable assumptions for the 124Xe/126Xe ratio in Xe-N (e.g., as in Q-Xe), inferred exposure ages are considerably shorter than theoretically expected lifetimes for interstellar grains. A short presolar age is in line with observations by others (appearance, grain size distribution) that indicate little processing in the interstellar medium (ISM) of surviving (crystalline) SiC. This may be due to amorphization of SiC in the ISM on a much shorter time scale

  13. QGSM development for spallation reactions modeling

    Directory of Open Access Journals (Sweden)

    Gudima K.K.

    2012-12-01

    Full Text Available The growing interest in spallation neutron sources, accelerator-driven systems, R&D of rare isotope beams, and development of external beam radiation therapy necessitated the improvement of nuclear reaction models for both stand-alone codes for the analysis of nuclear reactions and event generators within the Monte Carlo transport systems for calculations of interactions of high-energy particles with matter in a wide range of energy and in arbitrary 3D geometry of multicomponent targets. The exclusive approach to the description of nuclear reactions is the most effective for detailed calculation of inelastic interactions with atomic nuclei. It provides the correct description of particle production, single- and double-differential spectra, recoil, and fission product yields. This approach has been realized in the Quark Gluon String Model (QGSM for nuclear reactions induced by photons, hadrons, and high energy heavy ions. In this article, improved versions of the QGSM model and a corresponding code have been developed tested and bench marked against experimental data for neutron production in spallation reactions on thin and thick targets in the energy range from a few MeV to several GeV/nucleon.

  14. The Chinese Spallation Neutron Source Project

    International Nuclear Information System (INIS)

    The proposal of the Chinese Spallation Neutron Source (CSNS) project was granted in the beginning of 2002 after three review meetings, organized by the Chinese Academy of Sciences (CAS) and other scientific organizations. Physicists from the Institute of Physics (IP) and the Institute of High Energy Physics (IHEP), both belonging to CAS, consequently started a conceptual design and feasibility study. The CSNS plan calls for a 70-MeV H- linac and a 1.6 GeV rapid cycling synchrotron producing a proton current of 62.5 μA (100kW) at a 25 Hz repetition rate. It should be able to be upgraded to a higher beam power in its second phase. The CSNS target station design team, has initiated to conceptual design of the targetmoderator system based on the suggestions and comments from an international advisory team, in the first moderator-target planning meeting of CSNS project (21-26, April 2002 in Beijing). In consideration of the characteristics of the spallation neutron source, the budgets and possible requests for future users in China, five multi-purpose neutron scattering spectrometers were proposed as the first step

  15. Spallation studies on shock loaded uranium

    Energy Technology Data Exchange (ETDEWEB)

    Tonks, D.L.; Hixson, R.; Gustavsen, R.L.; Vorthman, J.E.; Kelly, A.; Zurek, A.K.; Thissel, W.R. [Los Alamos National Lab., NM (United States)

    1997-12-31

    Uranium samples at two different purity levels were used for spall strength measurements at three different stress levels. A 50 mm single-stage gas-gun was used to produce planar impact conditions using Z-cut quartz impactors. Samples of depleted uranium were taken from very high purity material and from material that had 300 ppm of carbon added. A pair of shots was done for each impact strength, one member of the pair with VISAR diagnostics and the second with soft recovery for metallographical examination. A series of increasing final stress states were chosen to effectively freeze the microstructural damage at three places in the development to full spall separation. This allowed determination of the dependence of spall mechanisms on stress level and sample purity. This report will discuss both the results of the metallurgical examination of soft recovered samples and the modeling of the free surface VISAR data. The micrographs taken from the recovered samples show brittle cracking as the spallation failure mechanism. Deformation induced twins are plentiful and obviously play a role in the spallation process. The twins are produced in the initial shock loading and, so, are present already before the fracture process begins. The 1 d characteristics code CHARADE has been used to model the free surface VISAR data.

  16. Alumina-Reinforced Zirconia Composites

    Science.gov (United States)

    Choi, Sung R.; Bansal, Narottam P.

    2003-01-01

    Alumina-reinforced zirconia composites, used as electrolyte materials for solid oxide fuel cells, were fabricated by hot pressing 10 mol percent yttria-stabilized zirconia (10-YSZ) reinforced with two different forms of alumina particulates and platelets each containing 0 to 30 mol percent alumina. Major mechanical and physical properties of both particulate and platelet composites including flexure strength, fracture toughness, slow crack growth, elastic modulus, density, Vickers microhardness, thermal conductivity, and microstructures were determined as a function of alumina content either at 25 C or at both 25 and 1000 C. Flexure strength and fracture toughness at 1000 C were maximized with 30 particulate and 30 mol percent platelet composites, respectively, while resistance to slow crack growth at 1000 C in air was greater for 30 mol percent platelet composite than for 30 mol percent particulate composites.

  17. Alumina supported iridium catalysts - preparation

    International Nuclear Information System (INIS)

    This report describes the method employed in the preparation of alumina supported iridium catalysts, with metal contents between 30 and 40%, that will be used for hydrazine monopropellant decomposition. (author)

  18. Effects of Platinum Additions and Sulfur Impurities on the Microstructure and Scale Adhesion Behavior of Single-Phase CVD Aluminide Bond Coatings

    Energy Technology Data Exchange (ETDEWEB)

    Cooley, K.M.; Haynes, J.A.; Lee, W.Y.; Pint, B.A.; Wright, I.G.; Zhang, Y.

    1999-02-28

    The adhesion of alumina scales to aluminide bond coats is a life-limiting factor for some advanced thermal barrier coating systems. This study investigated the effects of aluminide bond coat sulfur and platinum contents on alumina scale adhesion and coating microstructural evolution during isothermal and cyclic oxidation testing at 1150 C. Low-sulfur NiAl and NiPtAl bond coats were fabricated by chemical vapor deposition (CVD). Lowering the sulfur contents of CVD NiAl bond coatings significantly improved scale adhesion, but localized scale spallation eventually initiated along coating grain boundaries. Further improvements in scale adhesion were obtained with Pt additions. The observed influences of Pt additions included: (1) mitigation of the detrimental effects of high sulfur levels, (2) drastic reductions in void growth along the scale-metal interface, (3) alteration of the oxide-metal interface morphology, and (4) elimination of Ta-rich oxides in the Al{sub 2}O{sub 3} scales during thermal cycling. The results of this study also suggested that the microstructure (especially the grain size) of CVD aluminide bond coatings plays a significant role in scale adhesion.

  19. Determination of spallation neutron flux through spectral adjustment techniques

    Science.gov (United States)

    Mosby, M. A.; Engle, J. W.; Jackman, K. R.; Nortier, F. M.; Birnbaum, E. R.

    2016-08-01

    The Los Alamos Isotope Production Facility (IPF) creates medical isotopes using a proton beam impinged on a target stack. Spallation neutrons are created in the interaction of the beam with target. The use of these spallation neutrons to produce additional radionuclides has been proposed. However, the energy distribution and magnitude of the flux is not well understood. A modified SAND-II spectral adjustment routine has been used with radioactivation foils to determine the differential neutron fluence for these spallation neutrons during a standard IPF production run.

  20. The Los Alamos Long-Pulse-Spallation-Source driver

    International Nuclear Information System (INIS)

    A Los Alamos study has investigated the possibility of adapting the LANSCE facility to a 1-MW Long-Pulse Spallation Source (LPSS) delivering H+ beam to a new spallation target in 1-ms long pulses at a repetition rate of 60 Hz, while maintaining the present short-pulse capabilities. The study noted limitations of the LANSCE linac and has specified a scheme for high-reliability operation with low beam loss. Such an upgrade would provide a very inexpensive spallation source equivalent to a large reactor. Novel aspects of the scheme are stressed. (author) 5 figs

  1. Radiochemical aspects of liquid mercury spallation targets

    CERN Document Server

    Neuhausen, Joerg; Eichler, Bernd; Eller, Martin; Horn, Susanne; Schumann, Dorothea; Stora, Thierry

    2012-01-01

    Liquid metal spallation targets using mercury as target material are used in state-of-the-art high power pulsed neutron sources that have been constructed in the USA and Japan within the last decade. Similar target concepts were also proposed for next generation ISOL, beta-beam and neutrino facilities. A large amount of radioactivity will be induced in the liquid metal during operation caused by the interaction of the target material with the intense proton beam. This radioactivity - carried by a wide range of radioisotopes of all the elements of the periodic table from hydrogen up to thallium - must be considered for the assessment of safe operation and maintenance procedures as well as for a final disposal of the used target material and components. This report presents an overview on chemical investigations performed in our laboratory that deal with the behavior of radionuclides in proton irradiated mercury samples. The solubility of elements in mercury was calculated using thermodynamical data obtained by...

  2. Neutrino detection at a spallation source

    CERN Document Server

    Huang, Ming-Yang

    2015-01-01

    In this paper, we study the detection of accelerator neutrinos and supernova (SN) neutrinos at China Spallation Neutron Source (CSNS). Firstly, by using the code FLUKA, the processes of accelerator neutrinos production during the proton beam hitting on the tungsten target can be simulated, and the yield efficiency, numerical flux, average energy of different flavor neutrinos are given. Secondly, the detection of accelerator neutrinos through two reaction channels: the neutrino-electron reactions and the neutrino-carbon reactions, is studied, and the neutrino event numbers can be calculated. Finally, while considering the SN shock effects, the MSW effects, the neutrino collective effects, and the Earth matter effects, the detection of SN neutrinos on the Earth is studied. Then, the event numbers of SN neutrinos observed through various reaction channels are given.

  3. Measurements of neutron spallation cross section. 2

    Energy Technology Data Exchange (ETDEWEB)

    Kim, E.; Nakamura, T. [Tohoku Univ., Sendai (Japan). Cyclotron and Radioisotope Center; Imamura, M.; Nakao, N.; Shibata, S.; Uwamino, Y.; Nakanishi, N.; Tanaka, Su.

    1997-03-01

    Neutron spallation cross section of {sup 59}Co(n,xn){sup 60-x}Co, {sup nat}Cu(n,sp){sup 56}Mn, {sup nat}Cu(n,sp){sup 58}Co, {sup nat}Cu(n,xn){sup 60}Cu, {sup nat}Cu(n,xn){sup 61}Cu and {sup nat}Cu(n,sp){sup 65}Ni was measured in the quasi-monoenergetic p-Li neutron fields in the energy range above 40 MeV which have been established at three AVF cyclotron facilities of (1) INS of Univ. of Tokyo, (2) TIARA of JAERI and (3) RIKEN. Our experimental data were compared with the ENDF/B-VI high energy file data by Fukahori and the calculated cross section data by Odano. (author)

  4. The European scene regarding spallation neutron sources

    Energy Technology Data Exchange (ETDEWEB)

    Bauer, G.S. [Paul Scherrer Institut, Villigen (Austria)

    1996-06-01

    In Europe, a short pulse spallation neutron source, ISIS, has been operating for over 10 years, working its way up to a beam power level of 200 kW. A continuous source, SINQ, designed for a beam power of up to 1 MW, is scheduled to start operating at the end of 1996, and a detailed feasibility study has been completed for a 410 kW short pulse source, AUSTRON. Each of these sources seems to have settled for a target concept which is at or near the limits of its feasibility: The ISIS depleted uranium plate targets, heavy water cooled and Zircaloy clad, have so far not shown satisfactory service time and operation is likely to continue with a Ta-plate target, which, in the past has been used successfully for the equivalent of one full-beam-year before it was taken out of service due to degrading thermal properties. SINQ will initially use a rod target, made of Zircaloy only, but plans exist to move on to clad lead rods as quickly as possible. Apart from the not yet explored effect of hydrogen and helium production, there are also concerns about the generation of 7-Be in the cooling water from the spallation of oxygen, which might result in undesirably high radioactivity in the cooling plant room. A Liquid metal target, also under investigation for SINQ, would not only reduce this problem to a level of about 10 %, but would also minimize the risk of radiolytic corrosion in the beam interaction zone. Base on similar arguments, AUSTRON has been designed for edge cooled targets, but thermal and stress analyses show, that this concept is not feasible at higher power levels.

  5. Strain rate effects for spallation of concrete

    Directory of Open Access Journals (Sweden)

    Häussler-Combe Ulrich

    2015-01-01

    Full Text Available Appropriate triaxial constitutive laws are the key for a realistic simulation of high speed dynamics of concrete. The strain rate effect is still an open issue within this context. In particular the question whether it is a material property – which can be covered by rate dependent stress strain relations – or mainly an effect of inertia is still under discussion. Experimental and theoretical investigations of spallation of concrete specimen in a Hopkinson Bar setup may bring some evidence into this question. For this purpose the paper describes the VERD model, a newly developed constitutive law for concrete based on a damage approach with included strain rate effects [1]. In contrast to other approaches the dynamic strength increase is not directly coupled to strain rate values but related to physical mechanisms like the retarded movement of water in capillary systems and delayed microcracking. The constitutive law is fully triaxial and implemented into explicit finite element codes for the investigation of a wide range of concrete structures exposed to impact and explosions. The current setup models spallation experiments with concrete specimen [2]. The results of such experiments are mainly related to the dynamic tensile strength and the crack energy of concrete which may be derived from, e.g., the velocity of spalled concrete fragments. The experimental results are compared to the VERD model and two further constitutive laws implemented in LS-Dyna. The results indicate that both viscosity and retarded damage are required for a realistic description of the material behaviour of concrete exposed to high strain effects [3].

  6. Mechanism of spallation in platinum aluminide/electron beam physical vapor-deposited thermal barrier coatings

    Energy Technology Data Exchange (ETDEWEB)

    Gell, M.; Vaidyanathan, K.; Barber, B.; Cheng, J.; Jordan, E. [Univ. of Connecticut, Storrs, CT (United States)

    1999-02-01

    The spallation failure of a commercial thermal barrier coating (TBC), consisting of a single-crystal RENE N5 superalloy, a platinum aluminide (Pt-Al) bond coat, and an electron beam-deposited 7 wt pct yttria-stabilized zirconia ceramic layer (7YSZ), was studied following cyclic furnace testing. In the uncycled state and prior to deposition of the ceramic, the Pt-Al bond-coat surface contains a cellular network of ridges corresponding to the underlying bond-coat grain-boundary structure. With thermal cycling, the ridges and associated grain boundaries are the sites of preferential oxidation and cracking, which results in the formation of cavities that are partially filled with oxide. Using a fluorescent penetrant dye in conjunction with a direct-pull test, it is shown that, when specimens are cycled to about 80 pct of life, these grain-boundary regions show extensive debonding. The roles of oxidation and cyclic stress in localized grain boundary region spallation are discussed. The additional factors leading to large-scale TBC spallation are described.

  7. Gelcasting polycrystalline alumina

    Energy Technology Data Exchange (ETDEWEB)

    Janney, M.A. [Oak Ridge National Lab., TN (United States)

    1997-04-01

    This work is being done as part of a CRADA with Osram-Sylvania, Inc. (OSI) OSI is a major U.S. manufacturer of high-intensity lighting. Among its products is the Lumalux{reg_sign} line of high-pressure sodium vapor arc lamps, which are used for industrial, highway, and street lighting. The key to the performance of these lamps is the polycrystalline alumina (PCA) tube that is used to contain the plasma that is formed in the electric arc. That plasma consists of ionized sodium, mercury, and xenon vapors. The key attributes of the PCA tubes are their transparency (95% total transmittance in the visible region), their refractoriness (inner wall temperature can reach 1400{degrees}C), and their chemical resistance (sodium and mercury vapor are extremely corrosive). The current efficiency of the lamps is very high, on the order of several hundred lumens / watt. (Compare - incandescent lamps -13 lumens/watt fluorescent lamps -30 lumens/watt.) Osram-Sylvania would like to explore using gelcasting to form PCA tubes for Lumalux{reg_sign} lamps, and eventually for metal halide lamps (known as quartz-halogen lamps). Osram-Sylvania, Inc. currently manufactures PCA tubes by isostatic pressing. This process works well for the shapes that they presently use. However, there are several types of tubes that are either difficult or impossible to make by isostatic pressing. It is the desire to make these new shapes and sizes of tubes that has prompted Osram-Sylvania`s interest in gelcasting. The purpose of the CRADA is to determine the feasibility of making PCA items having sufficient optical quality that they are useful in lighting applications using gelcasting.

  8. Impact cratering experiments into quartzite, sandstone and tuff: The effects of projectile size and target properties on spallation

    Science.gov (United States)

    Poelchau, Michael H.; Kenkmann, Thomas; Hoerth, Tobias; Schäfer, Frank; Rudolf, Michael; Thoma, Klaus

    2014-11-01

    Impact cratering experiments were performed on quartzite, tuff, and dry and water-saturated sandstones in the framework of the MEMIN research unit. 2.5-12 mm diameter projectiles were accelerated to ∼5 km/s. Evaluation of the resulting craters shows that crater volumes and crater efficiencies of large-scale experiments are greater than predicted by strength scaling laws. A method to approximate the transient crater volume shows that this effect is largely due to an increase in spallation. Strength scaling laws are used to determine the reduction of tensile strength in large-scale experiments and show a decrease by a factor of 1.8-3.6. This strength reduction can be correlated with a decrease in strain rate for larger projectiles, and with the Weibull theory of strength reduction for larger rock sample sizes. Further variations in spallation are observed between different target materials; a decrease in spall is suggested to be controlled by increased porosity.

  9. Proceedings of the international workshop on spallation materials technology

    Energy Technology Data Exchange (ETDEWEB)

    Mansur, L.K.; Ullmaier, H. [comps.

    1996-10-01

    This document contains papers which were presented at the International Workshop on Spallation Materials Technology. Topics included: overviews and thermal response; operational experience; materials experience; target station and component design; particle transport and damage calculations; neutron sources; and compatibility.

  10. Proceedings of the international workshop on spallation materials technology

    International Nuclear Information System (INIS)

    This document contains papers which were presented at the International Workshop on Spallation Materials Technology. Topics included: overviews and thermal response; operational experience; materials experience; target station and component design; particle transport and damage calculations; neutron sources; and compatibility

  11. Some results of applied spallation physics research at Los Alamos

    International Nuclear Information System (INIS)

    At the Los Alamos National Laboratory, we have an active effort in the general area of Applied Spallation Physics Research. The main emphasis of this activity has been on obtaining basic data relevant to spallation neutron source development, accelerator breeder technology, and validation of computer codes used in these applications. We present here an overview of our research effort and show some measured and calculated results of differential and clean integral experiments

  12. Lightweight alumina refractory aggregate. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Swansiger, T.G.; Pearson, A.

    1996-07-16

    Objective was to develop a lightweight, high alumina refractory aggregate for use in various high performance insulating (low thermal conductivity) refractory applications (e.g., in the aluminium, glass, cement, and iron and steel industries). A new aggregate process was developed through bench and pilot-scale experiments involving extrusion of a blend of calcined and activated alumina powders and organic extrusion aids and binders. The aggregate, with a bulk density approaching 2.5 g/cc, exhibited reduced thermal conductivity and adequate fired strength compared to dense tabular aggregate. Refractory manufacturers were moderately enthusiastic over the results. Alcoa prepared an economic analysis for producing lightweight aggregate, based on a retrofit of this process into existing Alcoa production facilities. However, a new, competing lightweight aggregate material was developed by another company; this material (Plasmal{trademark})had a significantly more favorable cost base than the Alcoa/DOE material, due to cheap raw materials and fewer processing steps. In late 1995, Alcoa became a distributor of Plasmal. Alcoa estimated that {ge}75% of the market originally envisioned for the Alcoa/DOE aggregate would be taken by Plasmal. Hence, it was decided to terminate the contract without the full- scale demonstration.

  13. Development of Cast Alumina-Forming Austenitic Stainless Steels

    Science.gov (United States)

    Muralidharan, G.; Yamamoto, Y.; Brady, M. P.; Walker, L. R.; Meyer, H. M., III; Leonard, D. N.

    2016-09-01

    Cast Fe-Ni-Cr chromia-forming austenitic stainless steels with Ni levels up to 45 wt.% are used at high temperatures in a wide range of industrial applications that demand microstructural stability, corrosion resistance, and creep strength. Although alumina scales offer better corrosion protection at these temperatures, designing cast austenitic alloys that form a stable alumina scale and achieve creep strength comparable to existing cast chromia-forming alloys is challenging. This work outlines the development of cast Fe-Ni-Cr-Al austenitic stainless steels containing about 25 wt.% Ni with good creep strength and the ability to form a protective alumina scale for use at temperatures up to 800-850°C in H2O-, S-, and C-containing environments. Creep properties of the best alloy were comparable to that of HK-type cast chromia-forming alloys along with improved oxidation resistance typical of alumina-forming alloys. Challenges in the design of cast alloys and a potential path to increasing the temperature capability are discussed.

  14. Deexcitation Modes in Spallation Nuclear Reactions

    Science.gov (United States)

    Velasco, F. G.; Guzmán, F.; Rodriguez, O.; Tumbarell, O.; Souza, D. A.; Samana, A. R.; Andrade-II, E.; Bernal Castillo, J. L.; Deppman, A.

    2016-08-01

    Spallation nuclear reactions in the range of 0.2 to 1.2 GeV are studied using the CRISP code. A new approach for the deexcitation stage of the compound nucleus was introduced. For the calculations of the level densities, this approach is based on the Back-shifted Fermi gas model (BSFG), which takes into account pairing effects and shell corrections, whereas the calculation of the fission barriers were performed by means of the Extended Thomas-Fermi plus Strutinsky Integral (ETFSI) method, which is a high-speed approximation to the Hartree-Fock method with pairing correlations treated as in the usual BCS plus blocking approach. This procedure is more appropriate to calculate level densities for exotic nuclei. Satisfactory results were obtained and compared with experimental data obtained in the GSI experiments. As another important result, we highlight some directions for the development of a qualitatively superior version of the CRISP code with the implementation of more realistic and suitable physical models to be applied in stable and exotic nuclei that participate in the process. This new version of the code includes several substantial changes in the decay of the hot compound nucleus which allow satisfactory agreement with the experimental data and a reduction of the adjustment parameters.

  15. The Spallation Neutron Source accelerator system design

    Science.gov (United States)

    Henderson, S.; Abraham, W.; Aleksandrov, A.; Allen, C.; Alonso, J.; Anderson, D.; Arenius, D.; Arthur, T.; Assadi, S.; Ayers, J.; Bach, P.; Badea, V.; Battle, R.; Beebe-Wang, J.; Bergmann, B.; Bernardin, J.; Bhatia, T.; Billen, J.; Birke, T.; Bjorklund, E.; Blaskiewicz, M.; Blind, B.; Blokland, W.; Bookwalter, V.; Borovina, D.; Bowling, S.; Bradley, J.; Brantley, C.; Brennan, J.; Brodowski, J.; Brown, S.; Brown, R.; Bruce, D.; Bultman, N.; Cameron, P.; Campisi, I.; Casagrande, F.; Catalan-Lasheras, N.; Champion, M.; Champion, M.; Chen, Z.; Cheng, D.; Cho, Y.; Christensen, K.; Chu, C.; Cleaves, J.; Connolly, R.; Cote, T.; Cousineau, S.; Crandall, K.; Creel, J.; Crofford, M.; Cull, P.; Cutler, R.; Dabney, R.; Dalesio, L.; Daly, E.; Damm, R.; Danilov, V.; Davino, D.; Davis, K.; Dawson, C.; Day, L.; Deibele, C.; Delayen, J.; DeLong, J.; Demello, A.; DeVan, W.; Digennaro, R.; Dixon, K.; Dodson, G.; Doleans, M.; Doolittle, L.; Doss, J.; Drury, M.; Elliot, T.; Ellis, S.; Error, J.; Fazekas, J.; Fedotov, A.; Feng, P.; Fischer, J.; Fox, W.; Fuja, R.; Funk, W.; Galambos, J.; Ganni, V.; Garnett, R.; Geng, X.; Gentzlinger, R.; Giannella, M.; Gibson, P.; Gillis, R.; Gioia, J.; Gordon, J.; Gough, R.; Greer, J.; Gregory, W.; Gribble, R.; Grice, W.; Gurd, D.; Gurd, P.; Guthrie, A.; Hahn, H.; Hardek, T.; Hardekopf, R.; Harrison, J.; Hatfield, D.; He, P.; Hechler, M.; Heistermann, F.; Helus, S.; Hiatt, T.; Hicks, S.; Hill, J.; Hill, J.; Hoff, L.; Hoff, M.; Hogan, J.; Holding, M.; Holik, P.; Holmes, J.; Holtkamp, N.; Hovater, C.; Howell, M.; Hseuh, H.; Huhn, A.; Hunter, T.; Ilg, T.; Jackson, J.; Jain, A.; Jason, A.; Jeon, D.; Johnson, G.; Jones, A.; Joseph, S.; Justice, A.; Kang, Y.; Kasemir, K.; Keller, R.; Kersevan, R.; Kerstiens, D.; Kesselman, M.; Kim, S.; Kneisel, P.; Kravchuk, L.; Kuneli, T.; Kurennoy, S.; Kustom, R.; Kwon, S.; Ladd, P.; Lambiase, R.; Lee, Y. Y.; Leitner, M.; Leung, K.-N.; Lewis, S.; Liaw, C.; Lionberger, C.; Lo, C. C.; Long, C.; Ludewig, H.; Ludvig, J.; Luft, P.; Lynch, M.; Ma, H.; MacGill, R.; Macha, K.; Madre, B.; Mahler, G.; Mahoney, K.; Maines, J.; Mammosser, J.; Mann, T.; Marneris, I.; Marroquin, P.; Martineau, R.; Matsumoto, K.; McCarthy, M.; McChesney, C.; McGahern, W.; McGehee, P.; Meng, W.; Merz, B.; Meyer, R.; Meyer, R.; Miller, B.; Mitchell, R.; Mize, J.; Monroy, M.; Munro, J.; Murdoch, G.; Musson, J.; Nath, S.; Nelson, R.; Nelson, R.; O`Hara, J.; Olsen, D.; Oren, W.; Oshatz, D.; Owens, T.; Pai, C.; Papaphilippou, I.; Patterson, N.; Patterson, J.; Pearson, C.; Pelaia, T.; Pieck, M.; Piller, C.; Plawski, T.; Plum, M.; Pogge, J.; Power, J.; Powers, T.; Preble, J.; Prokop, M.; Pruyn, J.; Purcell, D.; Rank, J.; Raparia, D.; Ratti, A.; Reass, W.; Reece, K.; Rees, D.; Regan, A.; Regis, M.; Reijonen, J.; Rej, D.; Richards, D.; Richied, D.; Rode, C.; Rodriguez, W.; Rodriguez, M.; Rohlev, A.; Rose, C.; Roseberry, T.; Rowton, L.; Roybal, W.; Rust, K.; Salazer, G.; Sandberg, J.; Saunders, J.; Schenkel, T.; Schneider, W.; Schrage, D.; Schubert, J.; Severino, F.; Shafer, R.; Shea, T.; Shishlo, A.; Shoaee, H.; Sibley, C.; Sims, J.; Smee, S.; Smith, J.; Smith, K.; Spitz, R.; Staples, J.; Stein, P.; Stettler, M.; Stirbet, M.; Stockli, M.; Stone, W.; Stout, D.; Stovall, J.; Strelo, W.; Strong, H.; Sundelin, R.; Syversrud, D.; Szajbler, M.; Takeda, H.; Tallerico, P.; Tang, J.; Tanke, E.; Tepikian, S.; Thomae, R.; Thompson, D.; Thomson, D.; Thuot, M.; Treml, C.; Tsoupas, N.; Tuozzolo, J.; Tuzel, W.; Vassioutchenko, A.; Virostek, S.; Wallig, J.; Wanderer, P.; Wang, Y.; Wang, J. G.; Wangler, T.; Warren, D.; Wei, J.; Weiss, D.; Welton, R.; Weng, J.; Weng, W.-T.; Wezensky, M.; White, M.; Whitlatch, T.; Williams, D.; Williams, E.; Wilson, K.; Wiseman, M.; Wood, R.; Wright, P.; Wu, A.; Ybarrolaza, N.; Young, K.; Young, L.; Yourd, R.; Zachoszcz, A.; Zaltsman, A.; Zhang, S.; Zhang, W.; Zhang, Y.; Zhukov, A.

    2014-11-01

    The Spallation Neutron Source (SNS) was designed and constructed by a collaboration of six U.S. Department of Energy national laboratories. The SNS accelerator system consists of a 1 GeV linear accelerator and an accumulator ring providing 1.4 MW of proton beam power in microsecond-long beam pulses to a liquid mercury target for neutron production. The accelerator complex consists of a front-end negative hydrogen-ion injector system, an 87 MeV drift tube linear accelerator, a 186 MeV side-coupled linear accelerator, a 1 GeV superconducting linear accelerator, a 248-m circumference accumulator ring and associated beam transport lines. The accelerator complex is supported by ~100 high-power RF power systems, a 2 K cryogenic plant, ~400 DC and pulsed power supply systems, ~400 beam diagnostic devices and a distributed control system handling ~100,000 I/O signals. The beam dynamics design of the SNS accelerator is presented, as is the engineering design of the major accelerator subsystems.

  16. The spallation neutron source: New opportunities

    Indian Academy of Sciences (India)

    Ian S Anderson

    2008-11-01

    The spallation neutron source (SNS) facility became operational in the spring of 2006, and is now well on its way to become the world-leading facility for neutron scattering. Furthermore, the SNS and the HFIR reactor facility, newly outfitted with a brilliant cold source and guide hall, were brought together within a single Neutron Sciences Directorate at ORNL providing the opportunity to develop science and instrumentation programs which take advantage of the unique characteristics of each source. SNS and HFIR will both operate as scientific user facilities. Access to these facilities is being managed under an integrated proposal system, which also includes the Center for Nanophase Materials Sciences (CNMS) and the electron microscopes in the Shared Research Equipment (SHARE) program. Presently, SNS has three instruments operating in the user program and seven more will begin operations in 2008. When complete, the facility will accommodate 25 instruments enabling researchers from the United States and abroad to study materials science that forms the basis for new technologies in telecommunications, manufacturing, transportation, information technology, biotechnology, and health.

  17. The Spallation Neutron Source accelerator system design

    Energy Technology Data Exchange (ETDEWEB)

    Henderson, S., E-mail: stuarth@fnal.gov [Oak Ridge National Laboratory, P.O. Box 2008, Oak Ridge, TN 37831 (United States); Abraham, W. [Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA 94720 (United States); Aleksandrov, A. [Oak Ridge National Laboratory, P.O. Box 2008, Oak Ridge, TN 37831 (United States); Allen, C. [Techsource, Inc., 1475 Central Avenue, Suite 250, Los Alamos, NM 87544-3291 (United States); Alonso, J. [Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA 94720 (United States); Anderson, D. [Oak Ridge National Laboratory, P.O. Box 2008, Oak Ridge, TN 37831 (United States); Arenius, D. [Thomas Jefferson National Accelerator Facility, 12000 Jefferson Avenue, Newport News, VA 23606 (United States); Arthur, T. [Oak Ridge National Laboratory, P.O. Box 2008, Oak Ridge, TN 37831 (United States); Assadi, S. [Techsource, Inc., 1475 Central Avenue, Suite 250, Los Alamos, NM 87544-3291 (United States); Ayers, J.; Bach, P. [Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA 94720 (United States); Badea, V. [Brookhaven National Laboratory, P.O. Box 5000, Upton, NY 11973-5000 (United States); Battle, R. [Oak Ridge National Laboratory, P.O. Box 2008, Oak Ridge, TN 37831 (United States); Beebe-Wang, J. [Brookhaven National Laboratory, P.O. Box 5000, Upton, NY 11973-5000 (United States); Bergmann, B.; Bernardin, J.; Bhatia, T.; Billen, J.; Birke, T.; Bjorklund, E. [Los Alamos National Laboratory, P.O. Box 1663, Los Alamos, NM 87545 (United States); and others

    2014-11-01

    The Spallation Neutron Source (SNS) was designed and constructed by a collaboration of six U.S. Department of Energy national laboratories. The SNS accelerator system consists of a 1 GeV linear accelerator and an accumulator ring providing 1.4 MW of proton beam power in microsecond-long beam pulses to a liquid mercury target for neutron production. The accelerator complex consists of a front-end negative hydrogen-ion injector system, an 87 MeV drift tube linear accelerator, a 186 MeV side-coupled linear accelerator, a 1 GeV superconducting linear accelerator, a 248-m circumference accumulator ring and associated beam transport lines. The accelerator complex is supported by ∼100 high-power RF power systems, a 2 K cryogenic plant, ∼400 DC and pulsed power supply systems, ∼400 beam diagnostic devices and a distributed control system handling ∼100,000 I/O signals. The beam dynamics design of the SNS accelerator is presented, as is the engineering design of the major accelerator subsystems.

  18. Development of nuclear design criteria for neutron spallation sources

    Energy Technology Data Exchange (ETDEWEB)

    Sordo, F.; Abanades, A. [E.T.S. Industriales, Madrid Polytechnic University, UPM, J.Gutierrez Abascal, 2 -28006 Madrid (Spain)

    2008-07-01

    Spallation neutron sources allow obtaining high neutronic flux for many scientific and industrial applications. In recent years, several proposals have been made about its use, notably the European Spallation Source (ESS), the Japanese Spallation Source (JSNS) and the projects of Accelerator-Driven Subcritical reactors (ADS), particularly in the framework of EURATOM programs. Given their interest, it seems necessary to establish adequate design basis for guiding the engineering analysis and construction projects of this kind of installations. In this sense, all works done so far seek to obtain particular solutions to a particular design, but there has not been any general development to set up an engineering methodology in this field. In the integral design of a spallation source, all relevant physical processes that may influence its behaviour must be taken into account. Neutronic aspects (emitted neutrons and their spectrum, generation performance..), thermomechanical (energy deposition, cooling conditions, stress distribution..), radiological (spallation waste activity, activation reactions and residual heat) and material properties alteration due to irradiation (atomic displacements and gas generation) must all be considered. After analysing in a systematic manner the different options available in scientific literature, the main objective of this thesis was established as making a significant contribution to determine the limiting factors of the main aspects of spallation sources, its application range and the criteria for choosing optimal materials. To achieve this goal, a series of general simulations have been completed, covering all the relevant physical processes in the neutronic and thermal-mechanical field. Finally, the obtained criteria have been applied to the particular case of the design of the spallation source of subcritical reactors PDX-ADS and XT-ADS. These two designs, developed under the European R and D Framework Program, represent nowadays

  19. MECHANICAL BEHAVIOUR OF ALUMINA-ZIRCONIA COMPOSITE BY SLURRY METHOD

    OpenAIRE

    JYOTI PRAKASH; DEVENDRA KUMAR; KALYANI MOHANTA

    2011-01-01

    Alumina has got some excellent properties like chemical inertness, thermal and mechanical strength against hazardous environment. Alumina is a good ceramic material which is being used for structuralapplications. To enhance the toughness and strength of the body some Zirconia is also used with it. The use of Zirconia in alumina is known as toughening of alumina. One difficulty arises, when alumina and alumina toughened composite are sintered , because the low sinterability of Alumina-Zirconia...

  20. Tagging Spallation Backgrounds with Showers in Water-Cherenkov Detectors

    CERN Document Server

    Li, Shirley Weishi

    2015-01-01

    Cosmic-ray muons and especially their secondaries break apart nuclei ("spallation") and produce fast neutrons and beta-decay isotopes, which are backgrounds for low-energy experiments. In Super-Kamiokande, these beta decays are the dominant background in 6--18 MeV, relevant for solar neutrinos and the diffuse supernova neutrino background. In a previous paper, we showed that these spallation isotopes are produced primarily in showers, instead of in isolation. This explains an empirical spatial correlation between a peak in the muon Cherenkov light profile and the spallation decay, which Super-Kamiokande used to develop a new spallation cut. However, the muon light profiles that Super-Kamiokande measured are grossly inconsistent with shower physics. We show how to resolve this discrepancy and how to reconstruct accurate profiles of muons and their showers from their Cherenkov light. We propose a new spallation cut based on these improved profiles and quantify its effects. Our results can significantly benefit ...

  1. Processing and Performance of Alumina Fiber Reinforced Alumina Composites

    Institute of Scientific and Technical Information of China (English)

    P.Y.Lee; T.Uchijima; T.Yano

    2003-01-01

    Processing of alumina fiber-reinforced alumina matrix composites by hot-pressing was described. The mechanical properties of the composites fabricated by different sintering conditions including temperature and pressure have been investigated. The results indicated that the higher sintering temperature and pressure corresponded to the higher bulk density and higher maximum strength of the composite, whereas the pseudo-ductility of the composite was lower. The preliminary results of the composite with monazite-coated fibers showed that maximum strength could be improved up to 35% compared with the noncoated fiber composite in the same sintering condition. Moreover, the fracture behavior of the composite changed from completely brittle fracture to non-brittle fracture under the suitable sintering conditions. SEM observation of the fracture surface indicated that the coating worked as a protective barrier and avoided sintering of the fibers together even at high temperature and pressure during densification process.

  2. Sintering behaviour of spinel–alumina composites

    Indian Academy of Sciences (India)

    Soumen Pal; A K Bandyopadhyay; P G Pal; S Mukherjee; B N Samaddar

    2009-04-01

    Study of alumina–magnesia binary phase diagram reveals that around 40–50 wt% alumina dissolves in spinel (MgAl2O4) at 1600°C. Solid solubility of alumina in spinel decreases rapidly with decreasing temperature, which causes exsolution of alumina from spinel phase. Previous work of one of the authors revealed that the exsolution of alumina makes some interlocking structures in between alumina and spinel phases. In the present investigation, refractory grade calcined alumina and spinel powder were used to make different batch compositions. Green pellets, formed at a pressure of 1550 kg cm-2 were fired at different temperatures of 1500°, 1550° and 1600°C for 2 h soaking time. Bulk density, percent apparent porosity, firing shrinkage etc were measured at each temperature. Sintering results were analysed to understand the mechanism of spinel–alumina interactions. SEM study of present samples does not reveal the distinct precipitation of needle shaped -alumina from spinel, but has some effect on densification process of spinel–alumina composites. Microstructural differences between present and previous work suggest an ample scope of further work in spinel–alumina composites.

  3. Modeling of water radiolysis at spallation neutron sources

    Energy Technology Data Exchange (ETDEWEB)

    Daemen, L.L.; Kanner, G.S.; Lillard, R.S.; Butt, D.P.; Brun, T.O.; Sommer, W.F.

    1998-12-01

    In spallation neutron sources neutrons are produced when a beam of high-energy particles (e.g., 1 GeV protons) collides with a (water-cooled) heavy metal target such as tungsten. The resulting spallation reactions produce a complex radiation environment (which differs from typical conditions at fission and fusion reactors) leading to the radiolysis of water molecules. Most water radiolysis products are short-lived but extremely reactive. When formed in the vicinity of the target surface they can react with metal atoms, thereby contributing to target corrosion. The authors will describe the results of calculations and experiments performed at Los Alamos to determine the impact on target corrosion of water radiolysis in the spallation radiation environment. The computational methodology relies on the use of the Los Alamos radiation transport code, LAHET, to determine the radiation environment, and the AEA code, FACSIMILE, to model reaction-diffusion processes.

  4. Characterization of the radiation background at the Spallation Neutron Source

    Science.gov (United States)

    DiJulio, Douglas D.; Cherkashyna, Nataliia; Scherzinger, Julius; Khaplanov, Anton; Pfeiffer, Dorothea; Cooper-Jensen, Carsten P.; Fissum, Kevin G.; Kanaki, Kalliopi; Kirstein, Oliver; Ehlers, Georg; Gallmeier, Franz X.; Hornbach, Donald E.; Iverson, Erik B.; Newby, Robert J.; Hall-Wilton, Richard J.; Bentley, Phillip M.

    2016-09-01

    We present a survey of the radiation background at the Spallation Neutron Source (SNS) at Oak Ridge National Laboratory, TN, USA during routine daily operation. A broad range of detectors was used to characterize primarily the neutron and photon fields throughout the facility. These include a WENDI-2 extended range dosimeter, a thermoscientific NRD, an Arktis 4He detector, and a standard NaI photon detector. The information gathered from the detectors was used to map out the neutron dose rates throughout the facility and also the neutron dose rate and flux profiles of several different beamlines. The survey provides detailed information useful for developing future shielding concepts at spallation neutron sources, such as the European Spallation Source (ESS), currently under construction in Lund, Sweden.

  5. Ion guiding in alumina capillaries

    DEFF Research Database (Denmark)

    Juhász, Z.; Sulik, B.; Biri, S.;

    2009-01-01

    Transmission of a few keV impact energy Ne ions through capillaries in anodic alumina membranes has been studied with different ion counting methods using an energy dispersive electrostatic spectrometer, a multichannel plate (MCP) array and sensitive current-measurement. In the present work, we...... focus our attention to the measurements with the MCP array. The alumina capillaries were prepared by electro-chemical oxidation of aluminium foils. For the present experiments guiding of 3-6 keV Ne ions has been studied in two samples with capillary diameter of about 140 nm and 260 nm and with capillary...... length of about 15 μm. At these energies, the ions have been efficiently guided by the capillaries up to few degrees tilt angle. In this work, we compare the results obtained by the energy dispersive spectrometer to those studied by the MCP array. © 2008 Elsevier B.V. All rights reserved....

  6. Neutron scattering instrumentation for biology at spallation neutron sources

    Energy Technology Data Exchange (ETDEWEB)

    Pynn, R. [Los Alamos National Laboratory, NM (United States)

    1994-12-31

    Conventional wisdom holds that since biological entities are large, they must be studied with cold neutrons, a domain in which reactor sources of neutrons are often supposed to be pre-eminent. In fact, the current generation of pulsed spallation neutron sources, such as LANSCE at Los Alamos and ISIS in the United Kingdom, has demonstrated a capability for small angle scattering (SANS) - a typical cold- neutron application - that was not anticipated five years ago. Although no one has yet built a Laue diffractometer at a pulsed spallation source, calculations show that such an instrument would provide an exceptional capability for protein crystallography at one of the existing high-power spoliation sources. Even more exciting is the prospect of installing such spectrometers either at a next-generation, short-pulse spallation source or at a long-pulse spallation source. A recent Los Alamos study has shown that a one-megawatt, short-pulse source, which is an order of magnitude more powerful than LANSCE, could be built with today`s technology. In Europe, a preconceptual design study for a five-megawatt source is under way. Although such short-pulse sources are likely to be the wave of the future, they may not be necessary for some applications - such as Laue diffraction - which can be performed very well at a long-pulse spoliation source. Recently, it has been argued by Mezei that a facility that combines a short-pulse spallation source similar to LANSCE, with a one-megawatt, long-pulse spallation source would provide a cost-effective solution to the global shortage of neutrons for research. The basis for this assertion as well as the performance of some existing neutron spectrometers at short-pulse sources will be examined in this presentation.

  7. Bauxite Mining and Alumina Refining

    OpenAIRE

    Donoghue, A. Michael; Frisch, Neale; Olney, David

    2014-01-01

    Objective: To describe bauxite mining and alumina refining processes and to outline the relevant physical, chemical, biological, ergonomic, and psychosocial health risks. Methods: Review article. Results: The most important risks relate to noise, ergonomics, trauma, and caustic soda splashes of the skin/eyes. Other risks of note relate to fatigue, heat, and solar ultraviolet and for some operations tropical diseases, venomous/dangerous animals, and remote locations. Exposures to bauxite dust,...

  8. Charge-induced reversible bending in nanoporous alumina-aluminum composite

    Science.gov (United States)

    Cheng, Chuan; Ngan, A. H. W.

    2013-05-01

    Upon electrical charging, reversible bending was found in nanoporous anodic alumina-aluminum foil composites, as directly observed by an optical microscope and detected by in situ nanoindentation. The bending is thought to be the result of charge-induced surface stresses in the nanoporous alumina. The results suggest the possibility of a type of composite foil materials for applications as micro-scale actuators to transform electrical energy into mechanical energy.

  9. Neutron scattering instruments for the Spallation Neutron Source (SNS)

    Energy Technology Data Exchange (ETDEWEB)

    Crawford, R.K.; Fornek, T. [Argonne National Lab., IL (United States); Herwig, K.W. [Oak Ridge National Lab., TN (United States)

    1998-07-01

    The Spallation Neutron Source (SNS) is a 1 MW pulsed spallation source for neutron scattering planned for construction at Oak Ridge National Laboratory. This facility is being designed as a 5-laboratory collaboration project. This paper addresses the proposed facility layout, the process for selection and construction of neutron scattering instruments at the SNS, the initial planning done on the basis of a reference set of ten instruments, and the plans for research and development (R and D) to support construction of the first ten instruments and to establish the infrastructure to support later development and construction of additional instruments.

  10. Detection of supernova neutrinos at spallation neutron sources

    Science.gov (United States)

    Huang, Ming-Yang; Guo, Xin-Heng; Young, Bing-Lin

    2016-07-01

    After considering supernova shock effects, Mikheyev-Smirnov-Wolfenstein effects, neutrino collective effects, and Earth matter effects, the detection of supernova neutrinos at the China Spallation Neutron Source is studied and the expected numbers of different flavor supernova neutrinos observed through various reaction channels are calculated with the neutrino energy spectra described by the Fermi-Dirac distribution and the “beta fit” distribution respectively. Furthermore, the numerical calculation method of supernova neutrino detection on Earth is applied to some other spallation neutron sources, and the total expected numbers of supernova neutrinos observed through different reactions channels are given. Supported by National Natural Science Foundation of China (11205185, 11175020, 11275025, 11575023)

  11. Fundamental physics possibilities at the European Spallation Source

    DEFF Research Database (Denmark)

    Klinkby, Esben Bryndt; Batkov, Konstantin; Mezei, Ferenc;

    2016-01-01

    -moderator-reector design that wouldallow for ultra cold neutron production and extraction. For completeness, the paper also discusspossible discovery physics experiments that are presently being studied in the framework of ESS.In parallel to the topics discussed here, work is ongoing investigating the scientic potential......The construction of the European Spallation has recently started in Lund, Sweden.In addition to the neutron scattering instruments the ESS is designed to serve, the constructionof a new spallation source opens up new possibilities for fundamental physics experiments. Inthis paper some of the...... forin-beam fundamental physics experiments at the ESS....

  12. Results From Cavitation Damage Experiments With Mercury Spallation Targets At The LANSCE WNR In 2008

    International Nuclear Information System (INIS)

    Damage assessment from proton beam induced cavitation experiments on mercury spallation targets done at the LANSCE WNR facility has been completed. The experiments investigated two key questions for the Spallation Neutron Source target, namely, how damage is affected by flow velocity in the SNS coolant channel geometry, and how damage scales with proton beam intensity at a given constant charge per pulse. With regard to the former question, prior in-beam experiments indicated that the coolant channel geometry with stagnant mercury was especially vulnerable to damage which might warrant a design change. Yet other results indicated a reduction in damage with the introduction of flow. Using more prototypic to the SNS, the 2008 experiment damage results show the channel is less vulnerable than the bulk mercury side of the vessel wall. They also show no benefit from increasing channel flow velocity beyond nominal SNS speeds. The second question probed a consensus belief that damage scales with beam intensity (protons per unit area) by a power law dependence with exponent of around 4. Results from a 2005 experiment did not support this power law dependence but some observations were inconsistent and unexplained. These latest results show weaker damage dependence.

  13. Synthesis of high porosity, monolithic alumina aerogels

    Energy Technology Data Exchange (ETDEWEB)

    Poco, J F; Satcher, J H; Hrubesh, L W

    2000-09-20

    Many non-silica aerogels are notably weak and fragile in monolithic form. Particularly, few monolithic aerogels with densities less than 50kg/m3 have any significant strength. It is especially difficult to prepare uncracked monoliths of pure alumina aerogels that are robust and moisture stable. In this paper, we discuss the synthesis of strong, stable, monolithic, high porosity (>98% porous) alumina aerogels, using a two-step sol-gel process. The alumina aerogels have a polycrystalline morphology that results in enhanced physical properties. Most of the measured physical properties of the alumina aerogels are superior to those for silica aerogels for equivalent densities.

  14. Spallation reactions. A successful interplay between modeling and applications

    CERN Document Server

    David, J -C

    2015-01-01

    The spallation reactions are a type of nuclear reaction which occur in space by interaction of the cosmic rays with interstellar bodies. The first spallation reactions induced with an accelerator took place in 1947 at the Berkeley cyclotron (University of California) with 200 MeV deuterons and 400 MeV alpha beams. They highlighted the multiple emission of neutrons and charged particles and the production of a large number of residual nuclei far different from the target nuclei. The same year R. Serber describes the reaction in two steps: a first and fast one with high-energy particle emission leading to an excited remnant nucleus, and a second one, much slower, the de-excitation of the remnant. In 2010 IAEA organized a worskhop to present the results of the most widely used spallation codes within a benchmark of spallation models. If one of the goals was to understand the deficiencies, if any, in each code, one remarkable outcome points out the overall high-quality level of some models and so the great improv...

  15. Neutron science opportunities at pulsed spallation neutron sources

    International Nuclear Information System (INIS)

    Using the IPNS Upgrade plan developed at Argonne National Laboratory as a worked example of the design of a pulsed spallation neutron source, this paper explores some of the scientific applications of an advanced facility for materials science studies and the instrumentation for those purposes

  16. Neutron spin echo spectroscopy on the spallation neutron source

    International Nuclear Information System (INIS)

    An investigation has been made into the practicability of combining the neutron spin echo and time-of-flight techniques on the Rutherford Laboratory Spallation Neutron Source. Preliminary specifications are presented for a quasielastic instrument with an energy resolution down to approximately 10 neV and an inelastic spectrometer for measuring excitation widths approximately 1 μ eV. (author)

  17. Transuranics Transmutation Using Neutrons Spectrum from Spallation Reactions

    Directory of Open Access Journals (Sweden)

    Maurício Gilberti

    2015-01-01

    Full Text Available The aim is to analyse the neutron spectrum influence in a hybrid system ADS-fission inducing transuranics (TRUs transmutation. A simple model consisting of an Accelerator-Driven Subcritical (ADS system containing spallation target, moderator or coolant, and spheres of actinides, “fuel,” at different locations in the system was modelled. The simulation was performed using the MCNPX 2.6.0 particles transport code evaluating capture (n,γ and fission (n,f reactions, as well as the burnup of actinides. The goal is to examine the behaviour and influences of the hard neutron spectrum from spallation reactions in the transmutation, without the contribution or interference of multiplier subcritical medium, and compare the results with those obtained from the neutron fission spectrum. The results show that the transmutation efficiency is independent of the spallation target material used, and the neutrons spectrum from spallation does not contribute to increased rates of actinides transmutation even in the vicinity of the target.

  18. Fission, spallation or fusion-based neutron sources

    Indian Academy of Sciences (India)

    Kurt N Clausen

    2008-10-01

    In this paper the most promising technology for high power neutron sources is briefly discussed. The conclusion is that the route to high power neutron sources in the foreseeable future is spallation – short or long pulse or even CW – all of these sources will have areas in which they excel.

  19. HYSPEC : A CRYSTAL TIME OF FLIGHT HYBRID SPECTROMETER FOR THE SPALLATION NEUTRON SOURCE.

    Energy Technology Data Exchange (ETDEWEB)

    SHAPIRO,S.M.; ZALIZNYAK,I.A.

    2002-12-30

    This document lays out a proposal by the Instrument Development Team (IDT) composed of scientists from leading Universities and National Laboratories to design and build a conceptually new high-flux inelastic neutron spectrometer at the pulsed Spallation Neutron Source (SNS) at Oak Ridge. This instrument is intended to supply users of the SNS and scientific community, of which the IDT is an integral part, with a platform for ground-breaking investigations of the low-energy atomic-scale dynamical properties of crystalline solids. It is also planned that the proposed instrument will be equipped with a polarization analysis capability, therefore becoming the first polarized beam inelastic spectrometer in the SNS instrument suite, and the first successful polarized beam inelastic instrument at a pulsed spallation source worldwide. The proposed instrument is designed primarily for inelastic and elastic neutron spectroscopy of single crystals. In fact, the most informative neutron scattering studies of the dynamical properties of solids nearly always require single crystal samples, and they are almost invariably flux-limited. In addition, in measurements with polarization analysis the available flux is reduced through selection of the particular neutron polarization, which puts even more stringent limits on the feasibility of a particular experiment. To date, these investigations have mostly been carried out on crystal spectrometers at high-flux reactors, which usually employ focusing Bragg optics to concentrate the neutron beam on a typically small sample. Construction at Oak Ridge of the high-luminosity spallation neutron source, which will provide intense pulsed neutron beams with time-averaged fluxes equal to those at medium-flux reactors, opens entirely new opportunities for single crystal neutron spectroscopy. Drawing upon experience acquired during decades of studies with both crystal and time-of-flight (TOF) spectrometers, the IDT has developed a conceptual

  20. Influence of Alumina Addition on the Optical Property of Zirconia/Alumina Composite Dental Ceramics

    Institute of Scientific and Technical Information of China (English)

    JIANG Li; LIAO Yunmao; LI Wei; WAN Qianbing; ZHAO Yongqi

    2011-01-01

    The influence of various alumina additions on the optical property of zirconia/alumina composite ceramics was investigated.The relative sintered densities,transmittances,color and the microstructure of the composite ceramics were studied.The experimental results showed that the relative sintered densities and transmittances decreased with alumina addition.The lightness increased obviously but the chroma change was small.Pure zirconia nanopowders sintered densely could obtain the relatively high transmittance,while the transmittance and the lightness of slight addition changed significantly.The zirconia/alumina composite ceramics with alumina addition less than 7.5wt% could achieve the relatively stable and reliable optical properties.

  1. Sinter forging of zirconia toughened alumina

    NARCIS (Netherlands)

    He, Y.J.; Winnubst, A.J.A.; Verweij, H.; Burggraaf, A.J.

    1994-01-01

    Sinter forging experiments have been carried out on powder compacts of zirconia toughened alumina (ZTA) Ceramics Alumina-15 wt% zirconia was prepared by a gel precipitation method and calcined at temperatures of 900 or 1100°C. Full densification of ZTA ceramics was obtained within 15 min at 1400°C a

  2. Thermal-Hydraulic Analysis of PDS-XADS Spallation Target%PDS-XADS散裂靶热工水力分析

    Institute of Scientific and Technical Information of China (English)

    艾尼塞; 俞冀阳; 杨永伟

    2013-01-01

    本文对小型加速器驱动的次临界系统(ADS)-PDS-XADS散裂靶进行了热工水力分析.分析的XADS型实验堆基于欧洲PDS-XADS实验项目的设计,使用铅铋合金(LBE)作为冷却剂.散裂靶是ADS的核心部件之一,用以确保反应堆功率维持在指定水平.本文利用计算流体力学软件ANSYSCFX 11.0对散裂靶的下部区域进行热工水力分析.分析采用稳态计算、剪切应力输运(SST)湍流模型,在壁面边界条件处采用自动壁面函数法,针对不同的散裂靶设计进行计算流体力学(CFD)分析,最后根据散裂靶设计限值选择最优设计方案.%The thermal-hydraulic analysis of PDS-XADS spallation target for 80 MW reactor core power was studied. PDS-XADS is a small scale experimental accelerator driven sub-critical system (ADS). The analysis presented in this paper was based on lead bismuth eutectic (LBE) cooled XADS type experimental reactors, which are the designs of the European experimental PDS-XADS project. The spallation target is a very important component of ADS because it is responsible to keep the reactor power at the required level by spallation reactions. A high rate of neutron production by spallation reaction creates the problem of decay heat cooling. LBE flow is properly cooled, but the window is not properly cooled because of the stagnation point in the pole of the window. It would be very difficult to keep the window temperature below the design limit, which is an important design limit challenge. Thermal-hydraulic analysis of LBE spallation target was carried out by using ANSYS CFX 11.0. The detailed CFD analysis, which reveals thermal and hydraulic conditions in the window and spallation region, was carried out for different spallation target designs. Finally, the spallation target design limit was used to choose the best design.

  3. Diffusion of Cr, Fe, and Ti ions from Ni-base alloy Inconel-718 into a transition alumina coating

    International Nuclear Information System (INIS)

    Heat treating metals at high temperatures trigger diffusion processes which may lead to the formation of oxide layers. In this work the diffusion of Cr, Fe and Ti into an alumina coating applied to Inconel-718 is being investigated. Mass gain measurements, UV–vis spectroscopy and transmission electron microscopy were applied in order to study the evolution of the diffusion process. It was found that mainly Cr as well as minor amounts of Fe and Ti are being incorporated into the alumina coating upon prolonged heat treatment at 700 °C. It could be shown that alumina coatings being void of Cr have the same oxidation related mass gain as uncoated samples. However, incorporation of Cr into the alumina coating decreased their mass gain below that of uncoated substrates forming a Cr oxide scale only. - Highlights: ► We investigated the diffusion of Cr into alumina coatings applied on IN-718. ► The ingress of Cr led to the formation of mixed alumina/chromium coatings. ► The mass gain of mixed alumina/chromium coatings was compared to uncoated IN-718. ► The mixed alumina/chromium coatings improved the oxidation resistance of IN-718.

  4. High-Power Linac for the Spallation Neutron Source

    Science.gov (United States)

    Rej, D. J.

    2002-04-01

    The Spallation Neutron Source (SNS) will be the world’s most intense source of neutrons for fundamental science and industrial applications. Design and construction of this facility, located at Oak Ridge, is a joint venture between six DOE laboratories. Construction began in 1999 and is currently ahead of the scheduled 2006 completion date. Injecting a high-power, pulsed proton beam into a mercury target produces neutrons. In this talk, we review the physics requirements, design, and status of the construction of the 1-GeV, 1.4-MW average power RF linac for SNS. The accelerator consists of a drift tube linac (DTL), a coupled-cavity linac (CCL), and a superconducting rf (SRF) linac. The phase and quadrupole settings are set to avoid structure and parametric resonances, with coherent resonances posing minimal risk for emittance growth. The DTL is 37 m long and accelerates the ions to 87 MeV. The CCL is 55 m long and accelerates the ions to 186 MeV. The rf structure design and stability for both the DTL and CCL have been validated with scale models. The SRF linac has a modular design to accelerate ions to 1000 MeV, with a straightforward upgrade to 1.3 GeV at a later date. 3D particle-in-cell simulations of beam dynamics are performed to validate performance. The accelerator utilizes 93 MW of pulsed power operating continuously at 60-Hz with an 8factor. Approximately one hundred 402.5 or 805-MHz klystrons, with outputs between 0.55 and 5 MW, are used. The klystrons are powered by a novel converter-modulator that takes advantage of recent advances in IGBT switch plate assemblies and low-loss material cores for boost transformer. Beam diagnostics include position, phase, profile, and current monitors. They are designed to enable accurate beam steering and matching, and to minimize beam loss that would lead to activation and prevent hands-on maintenance.

  5. A non-equilibrium microscopic description of spallation

    CERN Document Server

    Napolitani, P

    2016-01-01

    We investigate the prompt emission of few intermediate-mass fragments in spallation reactions induced by protons and deuterons in the 1 GeV range. Such emission has a minor contribution to the total reaction cross section, but it may overcome evaporation and fission channels in the formation of light nuclides. The role of mean-field dynamics and phase-space fluctuations in these reactions is investigated through the Boltzmann-Langevin transport equation. We found that a process of frustrated fragmentation and re-aggregation is a prominent mechanism of production of IMFs which can not be assimilated to the statistical decay of a compound nucleus. Very interestingly, this process may yield a small number of IMF in the exit channel, which may even reduce to two, and be wrongly confused with ordinary asymmetric fission. This interpretation, inspired by nuclear-spallation experiments, can be generalised to heavy-ion collisions approaching the fragmentation threshold.

  6. Measured radionuclide production from copper, gold and lead spallation targets

    International Nuclear Information System (INIS)

    Spallation target materials are chosen so as to produce large numbers of neutrons while at the same time avoiding the creation of long-lived radioactive wastes. While there has been considerable research to determine the number of neutrons produced per incident particle for various target materials, there has been less effort to precisely quantify the types and amounts of radionuclides produced. Accurate knowledge of the radioactive species produced by spallation reactions is important for specifying waste disposal criteria for targets. In order to verify the production rates calculated by LAHET, a study has been conducted using the Texas A ampersand M University (TAMU) Cyclotron to measure radionuclide yields from copper, gold, and lead targets

  7. Overcoming High Energy Backgrounds at Pulsed Spallation Sources

    CERN Document Server

    Cherkashyna, Nataliia; DiJulio, Douglas D.; Khaplanov, Anton; Pfeiffer, Dorothea; Scherzinger, Julius; Cooper-Jensen, Carsten P.; Fissum, Kevin G.; Ansell, Stuart; Iverson, Erik B.; Ehlers, Georg; Gallmeier, Franz X.; Panzner, Tobias; Rantsiou, Emmanouela; Kanaki, Kalliopi; Filges, Uwe; Kittelmann, Thomas; Extegarai, Maddi; Santoro, Valentina; Kirstein, Oliver; Bentley, Phillip M.

    2015-01-01

    Instrument backgrounds at neutron scattering facilities directly affect the quality and the efficiency of the scientific measurements that users perform. Part of the background at pulsed spallation neutron sources is caused by, and time-correlated with, the emission of high energy particles when the proton beam strikes the spallation target. This prompt pulse ultimately produces a signal, which can be highly problematic for a subset of instruments and measurements due to the time-correlated properties, and different to that from reactor sources. Measurements of this background have been made at both SNS (ORNL, Oak Ridge, TN, USA) and SINQ (PSI, Villigen, Switzerland). The background levels were generally found to be low compared to natural background. However, very low intensities of high-energy particles have been found to be detrimental to instrument performance in some conditions. Given that instrument performance is typically characterised by S/N, improvements in backgrounds can both improve instrument pe...

  8. The spallation in reverse kinematics: what for a coincidence measurement?

    International Nuclear Information System (INIS)

    The Spaladin installation has been designed to study spallation reactions in reverse kinematics. Furthermore, the heavy and light fragments are detected by coincidence which allows us to get an instantaneous picture of the reaction at a level of accuracy better than that obtained through inclusive measurement. The first part is dedicated to the theoretical description of the different mechanisms involved in the spallation reactions. In the second part we describe the Spaladin installation and report some results on the reaction: Fe56 + p at an energy of 1 GeV/nucleon. In the third part we expose the performance of the installation through its simulation with the Geant-IV model. We present a study about the sensitivity of the Spaladin installation to theoretical predictions. The fourth part is dedicated to the future experiments that will be performed with the Spaladin installation. (A.C.)

  9. Neutronic studies of the coupled moderators for spallation neutron sources

    Institute of Scientific and Technical Information of China (English)

    Yin Wen; Liang Jiu-Qing

    2005-01-01

    We investigate the neutronic performance of coupled moderators to be implemented in spallation neutron sources by Monte-Carlo simulation and give the slow neutron spectra for the cold and thermal moderators. CH4 moderator can provide slow neutrons with highly desirable characteristics and will be used in low-power spallation neutron soureces. The slow neutron intensity extracted from different angles has been calculated. The capability of moderation of liquid H2 is lower than H2O and liquid CH4 due to lower atomic number density of hydrogen but we can compensate for this disadvantage by using a premoderator. The H2O premoderator of 2cm thickness can reduce the heat deposition in the cold moderator by about 33% without spoiling the neutron pulse.

  10. LATIS modeling of laser induced midplane and backplane spallation

    Energy Technology Data Exchange (ETDEWEB)

    Glinksky, M.E.; Bailey, D.S.; London, R.A.

    1997-03-05

    The computer code LATIS is used to simulate midplane and backplane spallation resulting from short pulsed laser absorption. A 1-D planar geometry is simulated with an exponential laser absorption profile. The laser pulse length is assumed to be much shorter than the sound transit time across the laser absorption length. The boundary conditions are a fixed front plane and free backplane (backplane spall) and a free front plane and a fixed midplane (midplane spall). The NBS/NRC equation of state for water is used with a self- consistent yet empirical material strength and failure model. The failure model includes the effects of void nucleation, growth and coalescence. Definite signatures of the nucleation and coalescence thresholds are found in the back surface motion for backplane spallation.

  11. Current status of JAERI spallation target material program

    Science.gov (United States)

    Kikuchi, K.; Sasa, T.; Ishikura, S.; Mukugi, K.; Kai, T.; Ouchi, N.; Ioka, I.

    2001-07-01

    In the joint project of spallation neutron source between JAERI and KEK, material technology has been developed for the mercury target in the neutron source facility, the lead-bismuth target in the transmutation test facility, superconducting accelerator, post-irradiation examination and the ion beam test. Design of target system is progressing for the mercury spallation target: a pressure test of moderator, an impacting test in mercury and a corrosion test have been carried out. For nuclear transmutation with ADS an engineering facility is proposed. A material corrosion test loop is built-up and SS316 and F82H steels are to be tested in a flowing Pb-Bi. Fracture toughness of superconducting cavity material was found to be considerably large at 4 K. Irradiated samples at SINQ are to be transported to JAERI Hot Laboratory. For simulating radiation damage small disk specimens were irradiated in single, dual and triple ion beam modes.

  12. Spallation Mechanism of RC Slabs Under Contact Detonation

    Institute of Scientific and Technical Information of China (English)

    YUAN Lin; GONG Shunfeng; JIN Weiliang

    2008-01-01

    The spallation of the concrete slabs or walls resulting from contact detonation constitutes risk to the personnel and equipment inside the structures because of the high speed concrete fragments even though the overall structures or structural members are not destroyed completely.Correctly predicting the damage caused by any potential contact detonation can lead to better fortification design to withstand the blast Ioadings.It is therefore of great significance to study the mechanism involved in the spallation of concrete slabs and walls.Existing studies on this topic often employ simplified material models and 1D wave analysis, which cannot reproduce the realistic response in the spallation process.Numerical simulations are therefore carried out under different contact blast Ioadings in the free air using LS-DYNA.Sophisticated concrete and reinforcing bar material models are adopted, taking into account the strain rate effect on both tension and compression.The erosion technique is used to model the fracture and failure of materials under tensile stress.Full processes of the deformation and dynamic damage of reinforced concrete (RC) slabs and plain concrete slabs are thus observed realistically.It is noted that with the increase of quantity of explosive, the dimensions of damage crater increase and the slabs experience four different damage patterns, namely explosive crater, spalling, perforation, and punching.Comparison between the simulation results of plain concrete slabs and those of RC slabs show that reinforcing bars can enhance the integrity and shearing resistance of the slabs to a certain extent, and meanwhile attenuate the ejection velocity and decrease the size of the concrete fragments.Therefore,optimizing reinforcement arrangement can improve the anti-spallation capability of the slabs and walls to a certain extent.

  13. Integral measurements of neutron production in spallation targets

    International Nuclear Information System (INIS)

    Measurements of neutron production for thick iron, tungsten and lead targets of different diameter prototypic for spallation systems have been made at SATURNE in an incident proton energy range from 400 MeV to 2 GeV. TIERCE code system calculations are in good agreement with experiment for iron and large diameter tungsten and lead targets. They overestimate the measured neutron production for tungsten and lead targets for diameter ≤20 cm. (author)

  14. Irradiation facilities at the spallation neutron source SINQ

    Energy Technology Data Exchange (ETDEWEB)

    Lehmann, E.; Ledermann, J.; Aebersold, H.; Kuehne, G.; Kohlik, K. [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

    1997-09-01

    Four independent experiments for sample irradiation are under construction and in preparation for operational tests at the spallation source SINQ. Three of them are located inside a thermal beam port with end positions inside or near the moderator tank. The other experiment will be established at the end position of a super mirror lined neutron guide for applications with cold neutrons. (author) 3 figs., 1 tab., 6 refs.

  15. Spallation neutron source and other high intensity froton sources

    Energy Technology Data Exchange (ETDEWEB)

    Weiren Chou

    2003-02-06

    This lecture is an introduction to the design of a spallation neutron source and other high intensity proton sources. It discusses two different approaches: linac-based and synchrotron-based. The requirements and design concepts of each approach are presented. The advantages and disadvantages are compared. A brief review of existing machines and those under construction and proposed is also given. An R&D program is included in an appendix.

  16. Detection of supernova neutrinos at spallation neutron sources

    OpenAIRE

    Huang, Ming-Yang; Guo, Xin-Heng; Young, Bing-Lin

    2015-01-01

    After considering the supernova shock effects, the Mikheyev-Smirnov-Wolfenstein effects, the neutrino collective effects, and the Earth matter effects, the detection of supernova neutrinos at China Spallation Neutron Sources is studied and the event numbers of different flavor supernova neutrinos observed through various reaction channels are calculated with the neutrino energy spectra described by the Fermi-Dirac distribution and "beta fit" distribution respectively. Furthermore, the numeric...

  17. Advanced spallation neutron sources for condensed matter research

    International Nuclear Information System (INIS)

    Advanced spallation neutron sources afford significant advantages over existing high flux reactors. The effective flux is much greater than that currently available with reactor sources. A ten-fold increase in neutron flux will be a major benefit to a wide range of condensed matter studies, and it will realise important experiments that are marginal at reactor sources. Moreover, the high intensity of epithermal neutrons open new vistas in studies of electronic states and molecular vibrations. (author)

  18. Spallation of glass materials under laser induced shocks

    OpenAIRE

    De Rességuier, T.; Cottet, F.

    1994-01-01

    The investigation of spallation in brittle materials like glass is usually limited by the severe destruction of the specimens. In this paper, an original study of this phenomenon, based on the post-shock examination of damaged targets, is presented. A high-power pulsed laser is used to generate very short compressive pulses in glass plates. A fractured layer is observed near the free surface of the recovered samples. The influences of the experimental parameters upon the thickness of this lay...

  19. Decommissioning and PIE of the MEGAPIE spallation target

    Energy Technology Data Exchange (ETDEWEB)

    Latge, C.; Henry, J. [CEA-Cadarache, DEN-DTN, 13108 Saint-Paul-les-Durance (France); Wohlmuther, M.; Dai, Y.; Gavillet, D.; Hammer, B.; Heinitz, S.; Neuhausen, J.; Schumann, D.; Thomsen, K.; Tuerler, A.; Wagner, W. [PSI, Villigen (Switzerland); Gessi, A. [ENEA, Brasimone (Italy); Guertin, A. [CNRS, Subatech, Nantes (France); Konstantinovic, M. [SCK-CEN, Mol (Belgium); Lindau, R. [KIT, Karlsruhe (Germany); Maloy, S. [DOE-LANL, Los Alamos (United States); Saito, S. [JAEA, Tokai (Japan)

    2013-07-01

    A key experiment in the Accelerated Driven Systems roadmap, the MEGAwatt PIlot Experiment (MEGAPIE) (1 MW) was initiated in 1999 in order to design and build a liquid lead-bismuth spallation target, then to operate it into the Swiss spallation neutron facility SINQ at Paul Scherrer Institute. The target has been designed, manufactured, and tested during integral tests, before irradiation carried out end of 2006. During irradiation, neutron and thermo hydraulic measurements were performed allowing deep interpretation of the experiment and validation of the models used during design phase. The decommissioning, Post Irradiation Examinations and waste management phases were defined properly. The phases dedicated to cutting, sampling, cleaning, waste management, samples preparation and shipping to various laboratories were performed by PSI teams: all these phases constitute a huge work, which allows now to perform post-irradiation examination (PIE) of structural material, irradiated in relevant conditions. Preliminary results are presented in the paper, they concern chemical characterization. The following radio-nuclides have been identified by γ-spectrometry: {sup 60}Co, {sup 101}Rh, {sup 102}Rh, {sup 108m}Ag, {sup 110m}Ag, {sup 133}Ba, {sup 172}Hf/Lu, {sup 173}Lu, {sup 194}Hg/Au, {sup 195}Au, {sup 207}Bi. For some of these nuclides the activities can be easily evaluated from γ-spectrometry results ({sup 207}Bi, {sup 194}Hg/Au), while other nuclides can only be determined after chemical separations ({sup 108m}Ag, {sup 110m}Ag, {sup 195}Au, {sup 129}I, {sup 36}Cl and α-emitting {sup 208-210}Po). The concentration of {sup 129}I is lower than expected. The chemical analysis already performed on spallation and corrosion products in the lead-bismuth eutectic (LBE) are very relevant for further applications of LBE as a spallation media and more generally as a coolant.

  20. Superhydrophobicity of Bionic Alumina Surfaces Fabricated by Hard Anodizing

    Institute of Scientific and Technical Information of China (English)

    Jing Li; Feng Du; Xianli Liu; Zhonghao Jiang; Luquan Ren

    2011-01-01

    Bionic alumina samples were fabricated on convex dome type aluminum alloy substrate using hard anodizing technique.The convex domes on the bionic sample were fabricated by compression molding under a compressive stress of 92.5 MPa.The water contact angles of the as-anodized bionic samples were measured using a contact angle meter (JC2000A) with the 3 μL water drop at room temperature.The measurement of the wetting property showed that the water contact angle of the unmodified as-anodized bionic alumina samples increases from 90° to 137° with the anodizing time.The increase in water contract angle with anodizing time arises from the gradual formation of hierarchical structure or composite structure.The structure is composed of the micro-scaled alumina columns and pores.The height of columns and the depth of pores depend on the anodizing time.The water contact angle increases significantly from 96° to 152° when the samples were modified with self-assembled monolayer of octadecanethiol (ODT),showing a change in the wettability from hydrophobicity to super-hydrophobicity.This improvement in the wetting property is attributed to the decrease in the surface energy caused by the chemical modification.

  1. Alumina Thin Film Growth: Experiments and Modeling

    OpenAIRE

    Wallin, Erik

    2007-01-01

    The work presented in this thesis deals with experimental and theoretical studies related to the growth of crystalline alumina thin films. Alumina, Al2O3, is a polymorphic material utilized in a variety of applications, e.g., in the form of thin films. Many of the possibilities of alumina, and the problems associated with thin film synthesis of the material, are due to the existence of a range of different crystalline phases. Controlling the formation of the desired phase and the transformati...

  2. Analysis of the mass formula dependence of spallation product distribution

    International Nuclear Information System (INIS)

    A new version of a spallation reaction simulation code NUCLEUS has been developed by incorporating the newly revised Uno and Yamada's mass formula. The mass formula dependence of the spallation product distribution has been investigated by comparing the new results with those calculated by the original version which uses the combination of the Cameron's mass formula and the mass table compiled by Wapstra et al. Detailed differences between these two mass formulas are shown in the comparisons of mass excess values. The distributions of spallation products of a uranium target nucleus bombarded by high energy (0.38 - 2.9 GeV) protons have been calculated with the new and original versions of NUCLEUS. The calculated results show that there is no significant discrepancy in the non-fission component of cumulative product yields such as the mass distribution and the number of emitted neutrons but in the fission component Uno and Yamada's mass formula reproduces the measured data obtained from thin foil experiments significantly better, especially in the neutron excess side, than the Cameron's one. (author)

  3. Calculation of the spallation product distribution in the evaporation process

    International Nuclear Information System (INIS)

    Some investigations are performed for the calculational model of nuclear spallation reaction in the evaporation process. A new version of a spallation reaction simulation code NUCLEUS has been developed by incorporating the newly revised Uno ampersand Yamada's mass formula and extending the counting region of produced nuclei. The differences between the new and original mass formulas are shown in the comparisons of mass excess values. The distributions of spallation products of a uranium target nucleus bombarded by energy (0.38 - 2.9 GeV) protons have been calculated with the new and original versions of NUCLEUS. In the fission component Uno ampersand Yamada's mass formula reproduces the measured data obtained from thin foil experiments significantly better, especially in the neutron excess side, than the combination of the Cameron's mass formula and the mass table compiled by Wapstra, et al., in the original version of NUCLEUS. Discussions are also made on how the mass-yield distribution of products varies dependent on the level density parameter a characterizing the particle evaporation. 16 refs., 7 figs., 1 tab

  4. Astrophysical Li-7 as a product of big bang nucleosynthesis and galactic cosmic-ray spallation

    Science.gov (United States)

    Olive, Keith A.; Schramm, David N.

    1992-01-01

    The astrophysical Li-7 abundance is considered to be largely primordial, while the Be and B abundances are thought to be due to galactic cosmic ray (GCR) spallation reactions on top of a much smaller big bang component. But GCR spallation should also produce Li-7. As a consistency check on the combination of big bang nucleosynthesis and GCR spallation, the Be and B data from a sample of hot population II stars is used to subtract from the measured Li-7 abundance an estimate of the amount generated by GCR spallation for each star in the sample, and then to add to this baseline an estimate of the metallicity-dependent augmentation of Li-7 due to spallation. The singly reduced primordial Li-7 abundance is still consistent with big bang nucleosynthesis, and a single GCR spallation model can fit the Be, B, and corrected Li-7 abundances for all the stars in the sample.

  5. Recent Development of High Alumina Refractories in China

    Institute of Scientific and Technical Information of China (English)

    WANGJin-xiang; LIUJie-hua

    1994-01-01

    The paper reviews the achievements which have been attained recently in China in high alumina refractories raw materials and their products,including 1) homogenization ,urification and electric fusion of high alumina raw materials and synthesizing of spinel from natural raw materials;2) processing principle and characteristics and microstructural features of creep-resistance high alu-mina brick ,alumina-magnesia-carbon brick and thermal shock resistanced high alumina brikc and their application in practice.

  6. Disposal strategy of proton irradiated mercury from high power spallation sources

    OpenAIRE

    Chiriki, Suresh

    2010-01-01

    Large spallation sources are intended to be constructed in Europe (EURISOL: nuclear physics research facility and ESS: European Spallation Source). These facilities would accumulate more than 20 metric tons of irradiated mercury in the target, which has to be treated as highly radioactive and chemo-toxic waste. Liquid waste cannot be tolerated in European repositories. As part of this work on safety/decommissioning of high-power spallation sources, our investigations were focused mainly...

  7. Energy dependence of isotopic spectra from spallation residues; Dependance en energie des spectres isotopiques de residus de spallation

    Energy Technology Data Exchange (ETDEWEB)

    Audouin, L

    2003-09-01

    Spallation reactions are collisions between heavy nuclei and light particle with an energy of a few hundreds MeV. The y are considered as a suitable way to create high- flux neutrons sources, which may used for example for the transmutation of nuclear wastes (hybrid reactors). The study of the residues from such reactions is both a way to understand the physics of the spallation and to provide information required for the design of industrial targets. The residues from the spallation of lead by proton at 500 MeV have been measured using the inverse kinematics technique in the FRS (fragments recoil separator). spectrometer from GSI (Barmstadt). This low energy required the use of new technique, for the experimental setup as well as during the analysis. The fragments were identified in-flight, prior to {beta} decay. Complete isotopic distributions are obtained with an accuracy ranging between 10 and 30%. Detailed information on the reaction kinematics are also obtained. Data are in excellent agreement with radio-chemical measurements, and bring new insights about the spallation process. The comparison with data measured on the same system with an incident energy of 1 GeV allows to discuss the influence of the projectile energy on the residues formation. It is concluded that the independence of the shape of the isobaric production cross sections regarding mass and energy of the projectile is preserved at low incident energies. The behaviour of Monte-Carlo codes is discussed with respect to those sets of data. The calculations show an improving agreement with decreasing energy, indicating that high-energy phenomena, for which some common assumptions become questionable, are the main reason for the observed discrepancies. (author)

  8. Electron cloud instabilities in the Proton Storage Ring and Spallation Neutron Source

    OpenAIRE

    Blaskiewicz, M.; Furman, M.A.; Pivi, M.; Macek, R.J.

    2002-01-01

    Electron cloud instabilities in the Los Alamos Proton Storage Ring (PSR) and those foreseen for the Oak Ridge Spallation Neutron Source (SNS) are examined theoretically, numerically, and experimentally.

  9. Burned Microporous Alumina-Graphite Brick

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    @@ 1 Scope This standard specifies the definition,classifica-tion,technical requirements,test methods,inspection rules,marking,packing,transportation and quality certificate of burned microporous alumina-graphite brick.

  10. Loss tangent measurements on unirradiated alumina

    Energy Technology Data Exchange (ETDEWEB)

    Zinkle, S.J.; Goulding, R.H. [Oak Ridge National Lab., TN (United States)

    1996-04-01

    Unirradiated room temperature loss tangent for sapphire and several commercial grades of polycrystalline alumina are complied for frequencies between 10{sup 5} and 4x10{sup 11} Hz. Sapphire exhibits significantly lower values for the loss tangent at frequencies up to 10{sup 11} Hz. The loss tangents of 3 different grades of Wesgo alumina (AL300, AL995, AL998) and 2 different grades of Coors alumina (AD94, AD995) have typical values near {approx}10{sup -4} at a frequency of 10{sup 8} Hz. On the other hand, the loss tangent of Vitox alumina exhibits a large loss peak tan d{approx} 5x10{sup -3} at this frequency.

  11. Acoustic Emission and Damage Characteristics of Alumina

    Institute of Scientific and Technical Information of China (English)

    REN Hui-lan; NING Jian-guo; HE Jian-hua

    2009-01-01

    gy, AE counts, AE amplitude changing with loading time are analyzed for the notched alumina specimen. It is indicated that AE characteristic parameters reflect the damage process and fracture of material.

  12. Silicide characterization at alumina-niobium interfaces

    OpenAIRE

    McKeown, JT; Radmilovic, Velimir R; Gronsky, R.; Glaeser, AM

    2011-01-01

    Alumina–niobium interfaces formed by liquidfilm-assisted joining with copper/niobium/copper interlayers exhibited microstructures that depend on the nature of the alumina components. Characterization of these interfaces in the transmission electron microscope provided insight on the relationship between interfacial microstructure and fracture performance. Interfaces between sapphire and niobium and those between high-purity (99.9%) polycrystalline alumina and niobium were free of secondary ph...

  13. Alumina Recovery from Kaolin with Mineral Impurities

    Institute of Scientific and Technical Information of China (English)

    SI Peng; QIAO Xiuchen; YU Jianguo

    2012-01-01

    The alumina recovery from low grade kaolin (K-JS) treated through thermal and mechanical methods was investigated.High grade kaolin (K-SX) was used as comparison.The optimum calcination temperatures for K-JS and K-SX were both 600 ℃,which resulted in 89.34wt% of alumina extraction from K-JS and 83.37wt% from K-SX.With the increase in calcination temperature,the chemical reactivity of calcined K-JS and K-SX to acid decreased.Mechanical treatment was much more effective in increasing the alumina extraction from activated kaolin.Around 99wt% of alumina was extracted from K-JS ground for 10 hours and 95wt% of alumina was extracted from K-SX ground for 20 hours.The IR results showed that the substitute of Al for Si occurred in calcined K-SX,however,the impurities in K-JS decreased this substitute.More alumina could be extracted from low grade kaolin than that from high grade kaolin under identical thermal or mechanical conditions.

  14. Spallation Neutrons Used for Imaging in the Time and Energy Domain

    International Nuclear Information System (INIS)

    SINQ, the Swiss national source for neutron research, is based on the principle of spallation, where protons from a 590 MeV cyclotron are sent to a lead target with highest possible beam intensity. The proton beam current from the PSI’s cyclotron is of the order of 2 mA, corresponding to about 1 MW deposited beam power in the target region. SINQ is a large scale user facility. The spallation neutrons with initial energies of up to 100 MeV are slowed to thermal energies within the moderator tank filled with heavy water (D2O). Further reduction of the neutron energy can take place in the cold source, which is operated at about 25 K and is filled with liquid deuterium. Unlike similar spallation sources (SNS, Oak Ridge, United States of America; JPARC, Tokai, Japan; ISIS, Didcot, United Kingdom), SINQ is not a pulsed source but provides a constant neutron flux level. As such, it compares to a research reactor with about 15 MW of thermal power. Neutron imaging as an advanced technique for neutron research, applied studies and industrial testing is established at SINQ with two beamlines: NEUTRA for thermal neutrons and ICON for cold neutrons. This capability has only minor representation compared to the scattering facilities at SINQ, with about 15 such installations. Modern neutron imaging techniques are exclusively based on digital systems, where each pixel can be considered an individual neutron counter. Neutron imaging experiments are mainly performed in transmission mode where the comparison between the initial and transmitted radiation is used to describe the properties of the sample material in the beam. For standard applications, the full incident neutron spectrum is used, which delivers an energy average attenuation value. Recent developments at the SINQ imaging beamlines permit time dependent investigations, in particular of cyclic processes, with frames in the millisecond range. This option is of high interest for studying the injection of fuel into running

  15. The Prototype Fundamental Power Coupler For The Spallation Neutron Source Superconducting Cavities: Design And Initial Test Results

    International Nuclear Information System (INIS)

    Each of the 805 MHz superconducting cavities of the Spallation Neutron Source (SNS) is powered via a coaxial Fundamental Power Coupler (FPC) with a 50 Omega impedance and a warm planar alumina window. The design is derived from the experience of other laboratories; in particular, a number of details are based on the coupler developed for the KEK B-Factory superconducting cavities. However, other design features have been modified to account for the fact that the SNS FPC will transfer a considerably lower average power than the KEK-B coupler. Four prototypes have been manufactured so far, and preliminary tests performed on two of them at Los Alamos National Laboratory (LANL). During these tests, peak powers of over 500 kW were transferred through the couplers in the test stand designed and built for this purpose. This paper gives details of the coupler design and of the results obtained from the RF tests on the test stand during the last few months. A more comprehensive set of tests is planned for the near future

  16. New spallation neutron sources, their performance and applications

    International Nuclear Information System (INIS)

    Pulsed spallation sources now operating in the world are at the KEK Laboratory in Japan (the KENS source), at Los Alamos National Laboratory (WNR) and at Argonne National Laboratory (IPNS), both the latter being in the US. The Intense Pulsed Neutron Source (IPNS) is currently the world's most intense source with a peak neutron flux of 4 x 1014 n cm-2s-1 at a repetition rate of 30 Hz, and globally producing approx. 1.5 x 1015 n/sec. Present pulsed sources are still relatively weak compared to their potential. In 1985 the Rutherford Spallation Neutron Source will come on line, and eventually be approx. 30 more intense than the present IPNS. Later, in 1986 the WNR/PSR option at Los Alamos will make that facility of comparable intensity, while a subcritical fission booster at IPNS will keep IPNS competitive. These new sources will expand the applications of pulsed neutrons but are still based on accelerators built for other scientific purposes, usually nuclear or high-energy physics. Accelerator physicists are now designing machines expressly for spallation neutron research, and the proton currents attainable appear in the milliamps. (IPNS now runs at 0.5 GeV and 14 μA). Such design teams are at the KFA Laboratory Julich, Argonne National Laboratory and KEK. Characteristics, particularly the different time structure of the pulses, of these new sources will be discussed. Such machines will be expensive and require national, if not international, collaboration across a wide spectrum of scientific disciplines. The new opportunities for neutron research will, of course, be dramatic with these new sources

  17. Nondiffractive applications of neutrons at the spallation source SINQ

    Energy Technology Data Exchange (ETDEWEB)

    Lehmann, E. [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

    1996-11-01

    The paper delivers an overview about experiments with neutrons from the spallation source SINQ which are not especially devoted to neutron scattering. A total of six experimental facilities are under construction using thermal as well as cold neutrons. Starting with some general considerations about the interaction of neutrons with matter, the principles, boundary conditions and the experimental set up of these experiments are described briefly. Some more details are given for the neutron radiography facility NEUTRA as the author`s special interest and research field. (author) 7 figs., 2 tabs., 9 refs.

  18. Beginnings of remote handling at the RAL Spallation Neutron Source

    International Nuclear Information System (INIS)

    Expenditure of funds and resources for remote maintenance systems traditionally are delayed until late in an accelerator's development. However, simple remote-surveillance equipment can be included early in facility planning to set the stage for future remote-handling needs and to identify appropriate personnel. Some basic equipment developed in the UK at the Spallation Neutron Source (SNS) that serves this function and that has been used to monitor beam loss during commissioning is described. A photograph of this equipment, positioned over the extractor septum magnet, is shown. This method can serve as a pattern approach to the problem of initiating remote-handling activities in other facilities

  19. VESPA: The vibrational spectrometer for the European Spallation Source

    Science.gov (United States)

    Fedrigo, Anna; Colognesi, Daniele; Bertelsen, Mads; Hartl, Monika; Lefmann, Kim; Deen, Pascale P.; Strobl, Markus; Grazzi, Francesco; Zoppi, Marco

    2016-06-01

    VESPA, Vibrational Excitation Spectrometer with Pyrolytic-graphite Analysers, aims to probe molecular excitations via inelastic neutron scattering. It is a thermal high resolution inverted geometry time-of-flight instrument designed to maximise the use of the long pulse of the European Spallation Source. The wavelength frame multiplication technique was applied to provide simultaneously a broad dynamic range (about 0-500 meV) while a system of optical blind choppers allows to trade flux for energy resolution. Thanks to its high flux, VESPA will allow the investigation of dynamical and in situ experiments in physical chemistry. Here we describe the design parameters and the corresponding McStas simulations.

  20. Design Optimization and the path towards a 2 MW Spallation Neutron Source

    Energy Technology Data Exchange (ETDEWEB)

    M. Blaskiewicz; N. Catalan-Lasheras; D. Davino; A. Fedotov; Y. Lee; N. Malitsky; Y. Papaphilippou; D. Raparia; A. Shishlo; N. Tsoupas; J. Wei; W. Weng; S. Zhang; J. Billen; S. Kurennoy; S. Nath; J. Stovall; H. Takeda; L. Young; R. Keller; J. Staples; A. Aleksandrov; Y. Cho; P. Chu; S. Cousineau; V. Danilov; M. Doleans; J. Galambos; J. Holmes; N. Holtkamp; D. Jeon; S. Kim; R. Kustom; E. Tanke; W. Wan; R. Sundelin

    2001-08-01

    The Spallation Neutron Source (SNS) is designed to ultimately reach an average proton beam power of 2 MW for pulsed neutron production. The SNS physics groups analyze the machine performance within the hardware constraints, optimize the accelerator design, and establish the best path towards a 2 MW and higher spallation neutron source.

  1. Research activities on structure materials of spallation neutron source at SINQ

    Energy Technology Data Exchange (ETDEWEB)

    Bauer, G.S.; Dai, Y. [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

    1997-09-01

    With the growing interests on powerful spallation neutron sources, especially with liquid metal targets, and accelerator driven energy systems, spallation materials science and technology have been received wide attention. At SINQ, material research activities are focused on: a) liquid metal corrosion; b) radiation damage; and c) interaction of corrosion and radiation damage. (author) 1 fig., refs.

  2. Study of Mechanical Properties and Fracture Mode of Alumina-Silicon Carbide Nanocomposites

    Science.gov (United States)

    Rahimnezhad Yazdi, A.; Baharvandi, H. R.; Abdizadeh, H.; Ehsani, N.

    In this study Al2O3-SiC nanocomposites have been fabricated by mixing of alumina and silicon carbide nano powders, followed by hot pressing at 1700°C. The mechanical properties and fracture mode of Al2O3-SiC nanocomposites containing different volume fractions (5, 10 and 15%) of nano scale SiC particles were investigated and compared with those of alumina. Al2O3-SiC powders were prepared by planetary milling in isopropanol. Fracture mode of specimens was investigated by means of scanning electron microscopy. Nanocomposites were tougher than alumina when they were hot pressed at the same temperature, and the values of nanocomposite's flexural strength and hardness were higher than those of alumina. Flexural strength, hardness and fracture toughness of the nanocomposites increase by increasing the volume percent of SiC up to 10% and then decrease slightly. The Scanning electron microscopy observations showed that fracture mode changes from intergranular for alumina to transgranular for nanocomposites. Finally X-ray diffraction analysis couldn't detect any chemical reactions between Al2O3 and SiC particles.

  3. High contrast laser marking of alumina

    Energy Technology Data Exchange (ETDEWEB)

    Penide, J. [Applied Physics Department, University of Vigo, EEI, Lagoas-Marcosende, 9, Vigo 36310 (Spain); Quintero, F., E-mail: fquintero@uvigo.es [Applied Physics Department, University of Vigo, EEI, Lagoas-Marcosende, 9, Vigo 36310 (Spain); Riveiro, A. [Applied Physics Department, University of Vigo, EEI, Lagoas-Marcosende, 9, Vigo 36310 (Spain); Fernández, A. [Department of Engineering Design, University of Vigo, Escuela de Ingeniería Industrial, Campus Universitario, Vigo E-36310 (Spain); Val, J. del [Applied Physics Department, University of Vigo, EEI, Lagoas-Marcosende, 9, Vigo 36310 (Spain); Comesaña, R. [Materials Engineering, Applied Mechanics and Construction Department, University of Vigo, EEI, Lagoas-Marcosende, Vigo E-36310 (Spain); Lusquiños, F.; Pou, J. [Applied Physics Department, University of Vigo, EEI, Lagoas-Marcosende, 9, Vigo 36310 (Spain)

    2015-05-01

    Highlights: • Laser marking of alumina using near infrared (NIR) lasers was experimentally analyzed. • Color change produced by NIR lasers is due to thermally induced oxygen vacancies. • Laser marking results obtained using NIR lasers and green laser are compared. • High contrast marks on alumina were achieved. - Abstract: Alumina serves as raw material for a broad range of advanced ceramic products. These elements should usually be identified by some characters or symbols printed directly on them. In this sense, laser marking is an efficient, reliable and widely implemented process in industry. However, laser marking of alumina still leads to poor results since the process is not able to produce a dark mark, yielding bad contrast. In this paper, we present an experimental study on the process of marking alumina by three different lasers working in two wavelengths: 1064 nm (Near-infrared) and 532 nm (visible, green radiation). A colorimetric analysis has been carried out in order to compare the resulting marks and its contrast. The most suitable laser operating conditions were also defined and are reported here. Moreover, the physical process of marking by NIR lasers is discussed in detail. Field Emission Scanning Electron Microscopy, High Resolution Transmission Electron Microscopy and X-ray Photoelectron Spectroscopy were also employed to analyze the results. Finally, we propose an explanation for the differences of the coloration induced under different atmospheres and laser parameters. We concluded that the atmosphere is the key parameter, being the inert one the best choice to produce the darkest marks.

  4. Superplastic properties of alumina-zirconia composites

    International Nuclear Information System (INIS)

    Superplastic deformation of two alumina-zirconia composites batches: the first with tetragonal ZrO2 stabilised with 3 mol.% Y2O3 and the second with ZrO2 stabilised with 2 mol.% Y2O3 (containing alumina volume fraction 10 - 86%) was studied. Grain sizes of two constituents were about 0.18-0.37 μm in the batch 1 and 0.36-0.14 μm in the batch 2. The composites were studied as a function of stress (20-130 MPa) and temperature (1451-1623 K) in compressive and bending tests. The strain rate was analysed in function of alumina volume fraction. It appeared that, the bigger than predicted by the rule of mixture strain rate decrease in function of alumina volume fraction is caused by improved creep resistance due to zirconium and yttrium ions doping of alumina grains. In zirconia grains modified interface-controlled Coble creep and simultaneously the intragranular dislocations motions contribute to the accommodation of grain boundary sliding (which is now thought to be main mechanism of superplastic behaviour). (author)

  5. High contrast laser marking of alumina

    International Nuclear Information System (INIS)

    Highlights: • Laser marking of alumina using near infrared (NIR) lasers was experimentally analyzed. • Color change produced by NIR lasers is due to thermally induced oxygen vacancies. • Laser marking results obtained using NIR lasers and green laser are compared. • High contrast marks on alumina were achieved. - Abstract: Alumina serves as raw material for a broad range of advanced ceramic products. These elements should usually be identified by some characters or symbols printed directly on them. In this sense, laser marking is an efficient, reliable and widely implemented process in industry. However, laser marking of alumina still leads to poor results since the process is not able to produce a dark mark, yielding bad contrast. In this paper, we present an experimental study on the process of marking alumina by three different lasers working in two wavelengths: 1064 nm (Near-infrared) and 532 nm (visible, green radiation). A colorimetric analysis has been carried out in order to compare the resulting marks and its contrast. The most suitable laser operating conditions were also defined and are reported here. Moreover, the physical process of marking by NIR lasers is discussed in detail. Field Emission Scanning Electron Microscopy, High Resolution Transmission Electron Microscopy and X-ray Photoelectron Spectroscopy were also employed to analyze the results. Finally, we propose an explanation for the differences of the coloration induced under different atmospheres and laser parameters. We concluded that the atmosphere is the key parameter, being the inert one the best choice to produce the darkest marks

  6. Monitoring Transport Across Modified Nanoporous Alumina Membranes

    Directory of Open Access Journals (Sweden)

    Erich D. Steinle

    2007-11-01

    Full Text Available This paper describes the use of several characterization methods to examinealumina nanotubule membranes that have been modified with specific silanes. The functionof these silanes is to alter the transport properties through the membrane by changing thelocal environment inside the alumina nanotube. The presence of alkyl groups, either long(C18 or short and branched (isopropyl hydrocarbon chains, on these silanes significantlydecreases the rate of transport of permeant molecules through membranes containingalumina nanotubes as monitored via absorbance spectroscopy. The presence of an ionicsurfactant can alter the polarity of these modified nanotubes, which correlates to anincreased transport of ions. Fluorescent spectroscopy is also utilized to enhance thesensitivity of detecting these permeant molecules. Confirmation of the alkylsilaneattachment to the alumina membrane is achieved with traditional infrared spectroscopy,which can also examine the lifetime of the modified membrane. The physical parameters ofthese silane-modified porous alumina membranes are studied via scanning electronmicroscopy. The alumina nanotubes are not physically closed off or capped by the silanesthat are attached to the alumina surfaces.

  7. Enhanced gas separation factors of microporous polymer constrained in the channels of anodic alumina membranes

    Science.gov (United States)

    Chernova, Ekaterina; Petukhov, Dmitrii; Boytsova, Olga; Alentiev, Alexander; Budd, Peter; Yampolskii, Yuri; Eliseev, Andrei

    2016-08-01

    New composite membranes based on porous anodic alumina films and polymer of intrinsic microporosity (PIM-1) have been prepared using a spin-coating technique. According to scanning electron microscopy, partial penetration of polymer into the pores of alumina supports takes place giving rise to selective polymeric layers with fiber-like microstructure. Geometric confinement of rigid PIM-1 in the channels of anodic alumina causes reduction of small-scale mobility in polymeric chains. As a result, transport of permanent gases, such as CH4, becomes significantly hindered across composite membranes. Contrary, the transport of condensable gases (CO2, C4H10), did not significantly suffer from the confinement due to high solubility in the polymer matrix. This strategy enables enhancement of selectivity towards CO2 and C4H10 without significant loss of the membrane performance and seems to be prospective for drain and sweetening of natural gas.

  8. Complementarity of long pulse and short pulse spallation sources

    International Nuclear Information System (INIS)

    The complementarity of short pulse spallation sources (SPSS) and steady state (CW) reactors is a widely accepted concept. SPSS and long pulse spallation sources (LPSS) are complementary in two ways: a) in their performance in neutron scattering experiments LPSS closely emulate CW reactors. In this respect two facets of the time-of-flight (TOF) monochromator method adequate for LPSS will be discussed: the superiority of the TOF approach to the crystal monochromator method in high resolution powder diffraction, and the novel technique of repetition rate multiplication in TOF spectroscopy, b) LPSS combined with adequate chopper systems can also emulate SPSS in a number of applications. It will be shown that the LPSS method of producing short neutron pulses is more efficient for cold and thermal neutrons (below an energy of about 100 MeV), while SPSS is the more favourable approach for hot, epithermal neutrons, i.e. in the slowing down regime in contrast to the moderated regime. These two aspects of complementarity of LPSS and SPSS lead to the conclusions that for about 75% of the spectrum of neutron scattering experiments as known of today the LPSS approach is the most advantageous one with a feasible neutron intensity exceeding that available at ILL by a factor of about 30, while for the remaining 25% of applications the SPSS technique is superior with a well-known potential of a similar gain over present day performances. (author) 7 figs., 6 refs

  9. Slow neutron leakage spectra from spallation neutron sources

    International Nuclear Information System (INIS)

    An efficient technique is described for Monte Carlo simulation of neutron beam spectra from target-moderator-reflector assemblies typical of pulsed spallation neutron sources. The technique involves the scoring of the transport-theoretical probability that a neutron will emerge from the moderator surface in the direction of interest, at each collision. An angle-biasing probability is also introduced which further enhances efficiency in simple problems. These modifications were introduced into the VIM low energy neutron transport code, representing the spatial and energy distributions of the source neutrons approximately as those of evaporation neutrons generated through the spallation process by protons of various energies. The intensity of slow neutrons leaking from various reflected moderators was studied for various neutron source arrangements. These include computations relating to early measurements on a mockup-assembly, a brief survey of moderator materials and sizes, and a survey of the effects of varying source and moderator configurations with a practical, liquid metal cooled uranium source Wing and slab, i.e., tangential and radial moderator arrangements, and Be vs CH2 reflectors are compared. Results are also presented for several complicated geometries which more closely represent realistic arrangements for a practical source, and for a subcritical fission multiplier such as might be driven by an electron linac. An adaptation of the code was developed to enable time dependent calculations, and investigated the effects of the reflector, decoupling and void liner materials on the pulse shape

  10. Spallation production of neutron deficient radioisotopes in North America

    Energy Technology Data Exchange (ETDEWEB)

    Jamriska, D.J.; Peterson, E.J. [Los Alamos National Laboratory, Los Alamos, NM (United States); Carty, J. [US Department of Energy, Office of Isotope Production and Distribution, Germantown, MD (United States)

    1997-10-01

    The United States Department of Energy produces a number of neutron deficient radioisotopes by high energy proton induced spallation reactions in accelerators at Los Alamos National Laboratory in New Mexico and Brookhaven National Laboratory in New York. Research isotopes are also recovered from targets irradiated at TRIUMF in British Columbia, Canada. The radioisotopes recovered are distributed for use in nuclear medicine, environmental research, physics research, and industry worldwide. In addition to the main product line of Sr-82 from either Mo or Rb targets, Cu-67 from ZnO targets, and Ge-68 from RbBr targets, these irradiation facilities also produce some unique isotopes in quantities not available from any other source such as Be-10, Al-26, Mg-28, Si-32, El-44, Fe-52, Gd-248, and Hg-194. We will describe the accelerator irradiation facilities at the Los Alamos and Brookhaven National Laboratories. The high level radiochemical processing facilities at Los Alamos and brief chemical processes from Los Alamos and Brookhaven will be described. Chemical separation techniques have been developed to recover the radioisotopes of interest in both high radiochemical purity and yield and at the same time trying to reduce or eliminate the generation of mixed waste. nearly 75 neutron deficient radioisotopes produced in spallation targets have been produced and distributed to researchers around the world since the inception of the program in 1974

  11. Radiation problems expected for the German spallation neutron source

    International Nuclear Information System (INIS)

    The German project for the construction of a Spallation Neutron Source with high proton beam power (5.5 MW) will have to cope with a number of radiation problems. The present report describes these problems and proposes solutions for keeping exposures for the staff and release of activity and radiation into the environment as low as reasonably achievable. It is shown that the strict requirements of the German radiation protection regulations can be met. The main problem will be the exposure of maintenance personnel to remanent gamma radiation, as is the case at existing proton accelerators. Closed ventilation and cooling systems will reduce the release of (mainly short-lived) activity to acceptable levels. Shielding requirements for different sections are discussed, and it is demonstrated by calculations and extrapolations from experiments that fence-post doses well below 150 mrem/y can be obtained at distances of the order of 100 metres from the principal source points. The radiation protection system proposed for the Spallation Neutron Source is discussed, in particular the needs for monitor systems and a central radiation protection data base and alarm system. (orig.)

  12. Oak Ridge Spallation Neutron Source (ORSNS) target station design integration

    Energy Technology Data Exchange (ETDEWEB)

    McManamy, T.; Booth, R.; Cleaves, J.; Gabriel, T. [and others

    1996-06-01

    The conceptual design for a 1- to 3-MW short pulse spallation source with a liquid mercury target has been started recently. The design tools and methods being developed to define requirements, integrate the work, and provide early cost guidance will be presented with a summary of the current target station design status. The initial design point was selected with performance and cost estimate projections by a systems code. This code was developed recently using cost estimates from the Brookhaven Pulsed Spallation Neutron Source study and experience from the Advanced Neutron Source Project`s conceptual design. It will be updated and improved as the design develops. Performance was characterized by a simplified figure of merit based on a ratio of neutron production to costs. A work breakdown structure was developed, with simplified systems diagrams used to define interfaces and system responsibilities. A risk assessment method was used to identify potential problems, to identify required research and development (R&D), and to aid contingency development. Preliminary 3-D models of the target station are being used to develop remote maintenance concepts and to estimate costs.

  13. Dynamical Mechanical Properties for AD90 Alumina

    Institute of Scientific and Technical Information of China (English)

    REN Hui-lan; NING Jian-guo; LI Ping

    2007-01-01

    The dynamic response of polycrystalline alumina was investigated in the pressure range of 0 -13 GPa by planar impact experiments.Velocity interferometer system for any reflector(VISAR) was used to obtain free surface velocity profile and determine the Hugoniot elastic limit,and manganin gauges were employed to obtain the stress-time histories and determine Hugoniot curve.Both the free surface particle velocity profiles and Hugoniot curves indicate the dispersion of the "plastic" wave for alumina.With the measured stress histories,the complete histories of strain,particle velocity,specific volume and specific internal energy are gained by using path line principle of Lagrange analysis.The dynamic mechanical behaviors for alumina under impact loading are analyzed,such as nonlinear characteristic,strain rate dependence,dispersion and declination of shock wave in the material.

  14. Synthesis and characterization of alumina precursor and alumina to be used as nano composite; Sintese e caracterizacao de precursores de alumina e alumina para uso em nanocompositos

    Energy Technology Data Exchange (ETDEWEB)

    Antunes, M.L.P., E-mail: malu@sorocaba.unesp.b [Universidade Estadual Paulista Julio de Mesquita Filho (UNESP), Sorocaba, SP (Brazil); Santos, H. Souza [Universidade de Sao Paulo (IF/USP), SP (Brazil). Inst. de Fisica; Santos, P. Souza [Universidade de Sao Paulo (EP/USP), SP (Brazil). Escola Politecnica

    2009-07-01

    With the evolution of nanomaterials technology, mainly in the 90s, it was possible to observe produced composites with alumina matrix and nanomaterial as reinforcing materials. It results in a significant improvement of mechanical proprieties of these composites. Thenceforth the study of synthesis and characterization of nanostructured materials has attracted great scientific interest. In this perspective, the aim of this work is to present an experimental procedure to obtain nordstrandite (aluminum hydroxide) with nanometric dimensions. Nordstrandite synthesis, obtained by the reaction of slightly amalgamated aluminum foil with aqueous ethylene glycol, which allows the control of the size of crystal produced. This control could be confirmed by X-Ray Diffraction and Electron Microscopy. Thermal transformation study is also presented. This study allowed the identification of transition aluminas that have potential to produce nanometric aluminas. (author)

  15. Comparison Between Experiments and Molecular Dynamic Simulations of Spallation Induced by Ultra-Short Laser Shock on Micrometric Tantalum Targets

    Science.gov (United States)

    Cuq-Lelandais, J.-P.; Boustie, M.; Soulard, L.; Berthe, L.; Sollier, A.; Bontaz-Carion, J.; Combis, P.; de Rességuier, T.; Lescoute, E.

    2009-12-01

    Shock wave propagation and the spallation within materials induced by laser shock have been investigated for roughly two decades. With the latest laser technologies evolution, one can access to shorter regimes in durations, going below the picosecond range. Shots performed with the LULI 100 TW facility evidence the possibility to obtain spallation in a few microns thick metallic target. Such conditions provide an experimental data layout which may be directly comparable with molecular dynamic simulations reachable to these scales. Molecular dynamic simulations on a single crystal of Tantalum have been performed with the CEA TERA 10 computer. First, the Hugoniot calculated by the equilibrium molecular dynamics has been compared with experimental data to check the potential (EAM) relevance to reproduce the shock wave propagation. Then, large scale simulations on a micrometric target have been performed. We have observed the microscopic ductile damage process, the pore apparition and their time and space evolution. The results are compared with experimental results and classical one-dimensional hydrodynamic simulations.

  16. Blocking of grain reorientation in self-doped alumina materials

    International Nuclear Information System (INIS)

    Alumina nanoparticles 10-20 nm in diameter were nucleated on alumina particles, 150 nm average diameter, by a colloidal route followed by calcination. It is shown that after sintering, the final grain size is up to 20% smaller due to the addition of the alumina nanoparticles. Electron backscattered diffraction analysis shows that whereas a correlation in the relative crystalline orientations between neighbouring grains exists in the pure materials, the addition of alumina nanoparticles results in a random crystalline orientation.

  17. REMOVING RADIUM FROM WATER BY PLAIN AND TREATED ACTIVATED ALUMINA

    Science.gov (United States)

    The research determined the feasibility of using BaSO4-impregnated activated alumina and plain activated alumina for radium removal from groundwater by fixed-bed adsorption. The major factors influencing radium adsorption onto the two types of alumina were identified. The radium ...

  18. Tribological properties of nanoscale alumina-zirconia composites

    NARCIS (Netherlands)

    Kerkwijk, B.; Winnubst, A.J.A.; Verweij, H.; Mulder, E.J.; Metselaar, H.S.C.; Schipper, D.J.

    1999-01-01

    The tribological properties of zirconia (Y-TZP), alumina and their composites, alumina dispersed in zirconia (ADZ) and zirconia-toughened alumina (ZTA), were investigated. These ceramics are made by colloidal processing methods such that well-defined, homogeneous microstructures with submicron grain

  19. A Novel Processing Route for Ni-doped Alumina Composites

    Institute of Scientific and Technical Information of China (English)

    JING Mao-xiang; SHEN Xiang-qian; ZHOU Jian-xin; LI Dong-hong; LI Wang-xing

    2006-01-01

    Alumina-based composites containing 0-15wt% Ni metallic phase were produced by hot press-sintering Ni-coated alumina powders. The Ni-coated alumina powders were prepared by the aqueous heterogeneous precipitation of alumina micro-powders and nickel sulfate salt followed by reduction process. The microstructural features and dispersion of Ni phase in Ni-coated alumina powders and the subsequent alumina-Ni cermets were investigated using scanning electron microscope (SEM), X-ray diffractometer (XRD), and transmission electron microscope (TEM). The relative density of the hot press-sintered composites was measured with the Archimedes' method while the fracture strength and the fracture toughness were defined with the three-point bending method and the micro-indentation fracture method. In the formation of alumina-Ni cermets from sintered Ni-coated alumina powders, Ni phase to some extent limits the densification rate and stifles the coarsening and growing process of alumina grains. The Ni phase is found to be located at the interfaces and the triple-joint junctions of alumina grains which results into alteration of the fracture mode of alumina and its increased fracture strength and fracture toughness if compared with monolithic alumina.

  20. Spallation occurrence from polyamide materials irradiated by thermal plasma with water absorption

    Science.gov (United States)

    Nakano, Tomoyuki; Tanaka, Yasunori; Nakagawa, T.; Shinsei, N.; Uesugi, Y.; Ishijima, T.

    2016-09-01

    This paper first describes the effect of water absorption in polyamide material irradiated by thermal plasmas on the occurrence of spallation phenomena. The interaction between polyamide materials and arc plasmas occurs particularly in the low voltage circuit breaker and aerospace fields. Spallation phenomena are those in which polymer particles are ejected from polymer bulk materials irradiated by high heat flux. To confirm the effect of water absorption into the polyamide material on spallation phenomena, polyamide specimens with and without water absorption were irradiated by Ar inductively coupled thermal plasma. The results show that the polyamide specimen with water absorption ejected spallation particles, whereas the polyamide specimen without water absorption were only slightly ejected, indicating that water absorption promotes the occurrence of spallation. The cooling effects of the spallation polyamide 66 (PA66) particles ablation were also estimated in hot air to assess the arc quenching ability from the spallation particle inclusion. This estimation showed that 10 and more PA66 particles inclusion might decrease the air temperature by 3000 K effectively, which can be useful to enhance arc quenching in circuit breakers working in air.

  1. Study on alumina-alumina brazing for application in vacuum chambers of proton synchrotron

    International Nuclear Information System (INIS)

    The paper describes an experimental study to standardize vacuum brazing process to obtain satisfactory high purity alumina brazed joints for application in rapid cycle proton synchrotron machine. Two different brazing routes, adopted for making alumina-alumina brazed joints, included (i) multi-step Mo-Mn metallization and brazing with BVAg-8 alloy and (ii) advanced single-step active brazing with CuSil-ABA alloy. Brazed alumina specimens, prepared by both the routes, yielded ultra high vacuum compatible, helium leak tight and bakeable joints. Active-brazed specimens exhibited satisfactory strength values in tensile and four-point bend tests. Metallized-brazed specimens, although exhibited relatively lower tensile strength than the targeted value, displayed satisfactory flexural strength in four-point bend test. The results of the study demonstrated that active brazing is the simple and cost effective alternative to conventional metallization route for producing satisfactory brazed joints for application in rapid cycle proton synchrotron machine. (author)

  2. Selective metallization of alumina by laser

    NARCIS (Netherlands)

    Shrivastva, P.B.; Boose, C.A.; Kolster, B.H.; Harteveld, C.; Meinders, B.

    1991-01-01

    Nickel has been selectively deposited on an alumina substrate without any pretreatment from a flow of a nickel acetate solution using the focused beam of an excimer laser. Nickel spots as well as nickel lines were drawn and subsequently plated with an electroless Ni-B coating. Excellent adhesion of

  3. Optimization of He-II UCN source with spallation neutron source

    Energy Technology Data Exchange (ETDEWEB)

    Mishima, K.; Choi, E.; Yoshimura, M. [Osaka Univ., Ibaraki (Japan). Research Center for Nuclear Physics; Ooi, M.; Kiyanagi, Y. [Hokkaido Univ., Sapporo (Japan); Masuda, Y.; Muto, S. [High Energy Accelerator Research Organization, Tsukuba, Ibaraki (Japan); Tanaka, M. [Kobe Tokiwa Collage, Kobe, Hyogo (Japan)

    2001-03-01

    A spallation neutron source was designed for super thermal UCN production in He-II. The configuration of neutron production target, moderator and He-II bottle was optimized in order to obtain high neutron flux with low {gamma} heating in He-II. In the optimization the advantage of the spallation neutron source is used: The spallation neutron source has high n/{gamma} ratio and freedom in target moderator configuration in comparison with the reactor. As a result, a great improvement in UCN density is expected compared with the present most intense UCN source at the Grenoble reactor. (authors)

  4. Evolution of a spallation reaction: experiment and Monte Carlo simulation

    CERN Document Server

    Enke, M; Hilscher, D; Jahnke, U; Schapiro, O; Letourneau, A; Galin, J; Goldenbaum, F; Lott, B; Peghaire, A; Filges, D; Neef, R D; Nünnighoff, K; Paul, N; Schaal, H; Sterzenbach, G; Tietze, A; Pienkowski, L

    1999-01-01

    Reaction cross sections and production cross sections for neutrons, hydrogen, and helium have been measured for 1.2, 1.8 GeV p+Fe, Ni, Ag, Ta, W, Au, Pb and U and are compared with different intra-nuclear-cascade- combined with evaporation-models. Agreement for neutrons and considerable differences for light charged particles are observed between experiment and calculation as well as between different models. The discrepancies are associated with specific deficiencies in the models. The exclusive data measured with two 4 pi-detectors for neutron and charged particle detection allowed furthermore a systematic comparison of observables characteristic of different stages of the temporal evolution of a spallation reaction: inelastic collision probability, excitation energy distribution, pre-equilibrium emission, and inclusive production cross sections.

  5. Spallation RI beam facility and heavy element nuclear chemistry

    Energy Technology Data Exchange (ETDEWEB)

    Nagame, Yuichiro [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment

    1997-11-01

    An outline of the spallation RI (Radioactive Ion) beam facility is presented. Neutron-rich nuclides are produced in the reaction of high intensity (10-1000 {mu}A) protons with energy of 1.5 GeV and an uranium carbide target. Produced nuclides are ionized in an isotope separator on-line (ISOL) and accelerated by the JAERI tandem and the booster linac. Current progress and a future project on the development of the RI beam facility are given. Studies of transactinide elements, including the synthesis of superheavy elements, nuclear structure far from stability, and RI-probed material science are planned with RI beams. An outlook of the transactinide nuclear chemistry studies using neutron-rich RI beams is described. (author)

  6. The concept of a European spallation neutron source (ESS)

    Energy Technology Data Exchange (ETDEWEB)

    Bauer, G.S. [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

    1997-11-01

    The next generation neutron source in Europe, which was studied by a collaboration between twelve laboratories, has been conceived as a 5 MW short pulse spallation source because of the superior overall scientific potential attributed to such a facility relative to all other options considered. While the accelerator side can use essentially established technology with some extensions in performance, a novel target concept based on the use of Mercury as a flowing liquid metal target was developed, which is not only expected to lead the way further into the future, but which was also found to give the best neutronic performance of all known choices. Close permanent interaction with a large user community yielded important input for the concept in general and for the upcoming R and D and design phases in particular. (author)

  7. Spallation production of neutron deficient radioisotopes in North America

    Energy Technology Data Exchange (ETDEWEB)

    Jamriska, D.J.; Peterson, E.J. [Los Alamos National Lab., NM (United States); Carty, J. [Dept. of Energy, Germantown, MD (United States). Office of Isotope Production and Distribution

    1997-12-31

    The US Department of Energy produces a number of neutron deficient radioisotopes by high energy proton induced spallation reactions in accelerators at Los Alamos National Laboratory in New Mexico and Brookhaven National Laboratory in New York. Research isotopes are also recovered from targets irradiated at TRIUMF in British Columbia, Canada. The radioisotopes recovered are distributed for use in nuclear medicine, environmental research, physics research, and industry worldwide. In addition to the main product line of Sr-82 from either Mo or Rb targets, Cu-67 from ZnO targets, and Ge-68 and RbBr targets, these irradiation facilities also produce some unique isotopes in quantities not available from any other source such as Al-26, Mg-28, Si-32, Ti-44, Fe-52, Gd-148, and Hg-194. The authors will describe the accelerator irradiation facilities at the Los Alamos and Brookhaven National Laboratories. The high level radiochemical processing facilities at Los Alamos and brief chemical processes will be described.

  8. Projectile dependency of radioactivities of spallation products induced in copper

    Energy Technology Data Exchange (ETDEWEB)

    Yashima, Hiroshi; Sugita, Hiroshi; Nakamura, Takashi; Shiomi, Tomoyuki [Tohoku Univ., Department of Quantum Science and Energy Engineering, Sendai, Miyagi (Japan); Uwamino, Yoshitomo; Ito, Sachiko [Institute of Physical and Chemical Research, Wako, Saitama (Japan); Fukumura, Akifumi [National Institute of Radiological Sciences, Chiba (Japan)

    2001-03-01

    The reaction cross-sections of spallation products in a Cu target by 230 MeV/nucleon Ne, C, He, p and 100 MeV/nucleon Ne, C ions were obtained. Irradiation experiments were performed at HIMAC (Heavy Ion Medical Accelerator in Chiba), National Institute of Radiological Sciences. Gamma-ray spectra from activation samples were measured with an HPGe detector. >From the gamma-ray spectra, we obtained the variation of reaction cross sections of Cl-38, Cr-49, Mn-55, Cu-60, Cu-61 and Co-62m in Cu sample with Cu target thickness and mass-yield distribution of nuclides in Cu sample on the surface of Cu target. The results showed that the dependence of the cross-sections to the projectile mass varies with the mass number difference between Cu and produced nuclide. (author)

  9. Room-temperature LINAC structures for the spallation neutron source

    Energy Technology Data Exchange (ETDEWEB)

    Billen, J. H. (James H.); Young, L. M. (Lloyd M.); Kurennoy, S. (Sergey); Crandall, K. R. (Kenneth R.)

    2001-04-01

    Los Alamos National Laboratory is building room-temperature rf accelerating structures for the Spallation Neutron Source (SNS). These structures, for H{sup -} ions, consist of six 402.5-MHz, 2-MW drift-tube linac (DTL) tanks from 2.5 to 87 MeV followed by four 805-MHz, 4-MW coupled-cavity linac (CCL) modules to 186 MeV. The DTL uses permanent magnet quadrupoles inside the drift tubes arranged in a 6{beta}{lambda} FFODDO lattice with every third drift tube available for diagnostics and steering. The CCL uses a 13{beta}{lambda} FODO electromagnetic quadrupole lattice. Diagnostics and magnets occupy the 2.5{beta}{lambda} spaces between 8-cavity segments. This paper discusses design of the rf cavities and low-power modeling work.

  10. BEAM INSTRUMENTATION FOR THE SPALLATION NEUTRON SOURCE RING.

    Energy Technology Data Exchange (ETDEWEB)

    WITKOVER,R.L.; CAMERON,P.R.; SHEA,T.J.; CONNOLLY,R.C.; KESSELMAN,M.

    1999-03-29

    The Spallation Neutron Source (SNS) will be constructed by a multi-laboratory collaboration with BNL responsible for the transfer lines and ring. [1] The 1 MW beam power necessitates careful monitoring to minimize un-controlled loss. This high beam power will influence the design of the monitors in the high energy beam transport line (HEBT) from linac to ring, in the ring, and in the ring-to-target transfer line (RTBT). The ring instrumentation must cover a 3-decade range of beam intensity during accumulation. Beam loss monitoring will be especially critical since un-controlled beam loss must be kept below 10{sup -4}. A Beam-In-Gap (BIG) monitor is being designed to assure out-of-bucket beam will not be lost in the ring.

  11. Radiological Hazard of Spallation Products in Accelerator-Driven System

    International Nuclear Information System (INIS)

    The central issue underlying this paper is related to elucidating the hazard of radioactive spallation products that might be an important factor affecting the design option of accelerator-driven systems (ADSs). Hazard analysis based on the concept of Annual Limit on Intake identifies alpha-emitting isotopes of rare earths (REs) (dysprosium, gadolinium, and samarium) as the dominant contributors to the overall toxicity of traditional (W, Pb, Pb-Bi) targets. The matter is addressed from several points of view: code validation to simulate their yields, choice of material for the neutron producing targets, and challenging the beam type. The paper quantitatively determines the domain in which the toxicity of REs exceeds that of polonium activation products broadly discussed now in connection with advertising lead-bismuth technology for the needs of ADSs

  12. The Spallation Neutron Source Beam Commissioning and Initial Operations

    Energy Technology Data Exchange (ETDEWEB)

    Henderson, Stuart [Argonne National Lab. (ANL), Argonne, IL (United States); Aleksandrov, Alexander V. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Allen, Christopher K. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Assadi, Saeed [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Bartoski, Dirk [University of Texas, Houston, TX (United States). Anderson Cancer Center; Blokland, Willem [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Casagrande, F. [Michigan State Univ., East Lansing, MI (United States); Campisi, I. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Chu, C. [Michigan State Univ., East Lansing, MI (United States); Cousineau, Sarah M. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Crofford, Mark T. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Danilov, Viatcheslav [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Deibele, Craig E. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Dodson, George W. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Feshenko, A. [Inst. for Nuclear Research (INR), Moscow (Russian Federation); Galambos, John D. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Han, Baoxi [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Hardek, T. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Holmes, Jeffrey A. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Holtkamp, N. [SLAC National Accelerator Lab., Menlo Park, CA (United States); Howell, Matthew P. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Jeon, D. [Inst. for Basic Science, Daejeon (Korea); Kang, Yoon W. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Kasemir, Kay [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Kim, Sang-Ho [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Kravchuk, L. [Institute for Nuclear Research (INR), Moscow (Russian Federation); Long, Cary D. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); McManamy, T. [McManamy Consulting, Inc., Middlesex, MA (United States); Pelaia, II, Tom [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Piller, Chip [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Plum, Michael A. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Pogge, James R. [Tennessee Technological Univ., Cookeville, TN (United States); Purcell, John David [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Shea, T. [European Spallation Source, Lund (Sweden); Shishlo, Andrei P [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Sibley, C. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Stockli, Martin P. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Stout, D. [Michigan State Univ., East Lansing, MI (United States); Tanke, E. [European Spallation Source, Lund (Sweden); Welton, Robert F [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Zhang, Y. [Michigan State Univ., East Lansing, MI (United States); Zhukov, Alexander P [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2015-09-01

    The Spallation Neutron Source (SNS) accelerator delivers a one mega-Watt beam to a mercury target to produce neutrons used for neutron scattering materials research. It delivers ~ 1 GeV protons in short (< 1 us) pulses at 60 Hz. At an average power of ~ one mega-Watt, it is the highest-powered pulsed proton accelerator. The accelerator includes the first use of superconducting RF acceleration for a pulsed protons at this energy. The storage ring used to create the short time structure has record peak particle per pulse intensity. Beam commissioning took place in a staged manner during the construction phase of SNS. After the construction, neutron production operations began within a few months, and one mega-Watt operation was achieved within three years. The methods used to commission the beam and the experiences during initial operation are discussed.

  13. The NNbar Experiment at the European Spallation Source

    CERN Document Server

    Frost, M J

    2016-01-01

    The observation of neutron to antineutron oscillation would be the first experimental evidence to show that baryon number is not a conserved quantity. It also provides an answer to the hypothesized post-sphaleron baryogenesis mechanism shortly after the Big Bang. The free oscillation time {\\tau_{n\\rightarrow\\bar{n}} has a lower limit at 8.7 x 10^7 seconds determined at ILL in 1994. Current beyond Standard Model theories of this oscillation time estimate the value to be on the order of 10^{10} seconds. A new experiment is proposed at the European Spallation Source that has 1000 times the sensitivity of the previous experiment, and would confirm the viability of those beyond Standard Model theories.

  14. Alumina ceramics prepared with new pore-forming agents

    Directory of Open Access Journals (Sweden)

    Zuzana Živcová

    2008-06-01

    Full Text Available Porous ceramics have a wide range of applications at all length scales, ranging from fi ltration membranes and catalyst supports to biomaterials (scaffolds for bone ingrowths and thermally or acoustically insulating bulk materials or coating layers. Organic pore-forming agents (PFAs of biological origin can be used to control porosity, pore size and pore shape. This work concerns the characterization and testing of several less common pore-forming agents (lycopodium, coffee, fl our and semolina, poppy seed, which are of potential interest from the viewpoint of size, shape or availability. The performance of these new PFAs is compared to that of starch, which has become a rather popular PFA for ceramics during the last decade. The PFAs investigated in this work are in the size range from 5 μm (rice starch to approximately 1 mm (poppy seed, all with more or less isometric shape. The burnout behavior of PFAs is studied by thermal analysis, i.e. thermogravimetry and differential thermal analysis. For the preparation of porous alumina ceramics from alumina suspensions containing PFAs traditional slip casting (into plaster molds and starch consolidation casting (using metal molds are used in this work. The resulting microstructures are investigated using optical microscopy, combined with image analysis, as well as other methods (Archimedes method of double-weighing in water, mercury intrusion porosimetry.

  15. Spallation recoil and age of presolar grains in meteorites

    Science.gov (United States)

    Ott, U.; Begemann, F.

    2000-01-01

    We have determined the recoil losses from silicon carbide grain size fractions of spallation neon produced by irradiation with 1.6 GeV protons. During the irradiation the SiC grains were dispersed in paraffin wax in order to avoid re-implantation into neighboring grains. Analysis for spallogenic 21Ne of grain size separates in the size range 0.3 μm to 6 μm and comparison with the 22Na activity of the SiC+paraffin mixture indicates an effective recoil range of 2-3 μm with no apparent effect from acid treatments such as routinely used in the isolation of meteoritic SiC grains. Our results indicate that the majority of presolar SiC grains in primitive meteorites, which are ~μm-sized, will have lost essentially all spallogenic Ne produced by cosmic ray interaction in the interstellar medium. This argues against the validity of previously published presolar ages of Murchison SiC (~10 to ~130 Ma; increasing with grain size; Lewis et al., 1994), where recoil losses had been based on calculated recoil energies. It is argued that the observed variations in meteoritic SiC grain size fractions of 21Ne/22Ne ratios are more likely due to the effects of nucleosynthesis in the He burning shell of the parent AGB stars which imposes new boundary conditions on nuclear parameters and stellar models. It is suggested that spallation-Xe produced on the abundant Ba and REE in presolar SiC, rather than spallogenic Ne, may be a promising approach to the presolar age problem. There is a hint in the currently available Xe data (Lewis et al., 1994) that the large (>1 μm) grains may be younger than the smaller (<1 μm) ones.

  16. MECHANICAL BEHAVIOUR OF ALUMINA-ZIRCONIA COMPOSITE BY SLURRY METHOD

    Directory of Open Access Journals (Sweden)

    JYOTI PRAKASH

    2011-02-01

    Full Text Available Alumina has got some excellent properties like chemical inertness, thermal and mechanical strength against hazardous environment. Alumina is a good ceramic material which is being used for structuralapplications. To enhance the toughness and strength of the body some Zirconia is also used with it. The use of Zirconia in alumina is known as toughening of alumina. One difficulty arises, when alumina and alumina toughened composite are sintered , because the low sinterability of Alumina-Zirconia forced the compact to give very low density body. To overcome this problem alumina and alumina composites are made from slurry method which gives nearly theoretical density. The combined effect of alumina and Zirconia on the phase transformation and microstructure development of heat-treated Alumina-Zirconia composites has been studied. Slurry is prepared by adding water, dispersant, binder and anti-foaming agent. In the present study, Sintering schedule is optimized and kept constant for all samples. After sintering, mechanical behaviour of the composite has been studied.

  17. Overview of the Conceptual Design of the Future VENUS Neutron Imaging Beam Line at the Spallation Neutron Source

    Science.gov (United States)

    Bilheux, Hassina; Herwig, Ken; Keener, Scott; Davis, Larry

    VENUS (Versatile Neutron Imaging Beam line at the Spallation Neutron Source) will be a world-class neutron-imaging instrument that will uniquely utilize the Spallation Neutron Source (SNS) time-of-flight (TOF) capabilities to measure and characterize objects across several length scales (mm to μm). When completed, VENUS will provide academia, industry and government laboratories with the opportunity to advance scientific research in areas such as energy, materials, additive manufacturing, geosciences, transportation, engineering, plant physiology, biology, etc. It is anticipated that a good portion of the VENUS user community will have a strong engineering/industrial research focus. Installed at Beam line 10 (BL10), VENUS will be a 25-m neutron imaging facility with the capability to fully illuminate (i.e., umbra illumination) a 20 cm x 20 cm detector area. The design allows for a 28 cm x 28 cm field of view when using the penumbra to 80% of the full illumination flux. A sample position at 20 m will be implemented for magnification measurements. The optical components are comprised of a series of selected apertures, T0 and bandwidth choppers, beam scrapers, a fast shutter to limit sample activation, and flight tubes filled with Helium. Techniques such as energy selective, Bragg edge and epithermal imaging will be available at VENUS.

  18. Degradation of alumina and zirconia toughened alumina (ZTA) hip prostheses tested under microseparation conditions in a shock device

    CERN Document Server

    Uribe, Juliana; Gremillard, Laurent; Reynard, Bruno

    2013-01-01

    This paper considers the degradation of alumina and zirconia toughened alumina vs. alumina for hip implants. The materials are as assumed to be load bearing surfaces subjected to shocks in wet conditions. The load is a peak of force; 9 kN was applied over 15 ms at 2 Hz for 800,000 cycles. The volumetric wear and roughness are lower for ZTA than for alumina. The long ZTA ageing did not seem to have a direct influence on the roughness. The ageing increased the wear volumes of ZTA and it was found to have a higher wear resistance compared to alumina.

  19. Study of alumina-trichite reinforcement of a nickel-based matric by means of powder metallurgy

    Science.gov (United States)

    Walder, A.; Hivert, A.

    1982-01-01

    Research was conducted on reinforcing nickel based matrices with alumina trichites by using powder metallurgy. Alumina trichites previously coated with nickel are magnetically aligned. The felt obtained is then sintered under a light pressure at a temperature just below the melting point of nickel. The halogenated atmosphere technique makes it possible to incorporate a large number of additive elements such as chromium, titanium, zirconium, tantalum, niobium, aluminum, etc. It does not appear that going from laboratory scale to a semi-industrial scale in production would create any major problems.

  20. Initial observations of cavitation-induced erosion of liquid metal spallation target vessels at the Spallation Neutron Source

    Energy Technology Data Exchange (ETDEWEB)

    McClintock, David A [ORNL; Riemer, Bernie [ORNL; Ferguson, Phillip D [ORNL; Carroll, Adam J [ORNL; Dayton, Michael J [ORNL

    2012-01-01

    During operation of the Spallation Neutron Source (SNS) at Oak Ridge National Laboratory the mechanical properties of the AISI 316L target module are altered by high-energy neutron and proton radiation. The interior surfaces of the target vessel are also damaged by cavitation-induced erosion, which results from repetitive rapid heating of the liquid mercury by high-energy proton beam pulses. Until recently no observations of cavitation-induced erosion were possible for conditions prototypical to the SNS. Post irradiation examination (PIE) of the first and second operational SNS targets was performed to gain insight into the radiation-induced changes in mechanical properties of the 316L target material and the extent of cavitation-induced erosion to the target vessel inner surfaces. Observations of cavitation-induced erosion of the first and second operational SNS target modules are presented here, including images of the target vessel interiors and specimens removed from the target beam-entrance regions.

  1. Graphene coated with alumina and its utilization as a thermal conductivity enhancer for alumina sphere/thermoplastic polyurethane composite

    International Nuclear Information System (INIS)

    Graphene was oxidized with H2O2 to introduce additional anchoring sites for effective alumina coating on graphene by the sol–gel method. The X-ray photoelectron spectroscopy studies showed that the oxygen-containing groups such as hydroxyl group useful for coating were introduced by the oxidation. The transmission electron microscopy images and thermogravimetric analysis data demonstrated that the additional anchoring sites enhanced the efficiency of the alumina coating. A small amount of alumina-coated graphene synergistically improved the thermal conductivity of the alumina sphere/thermoplastic polyurethane (TPU) composite without any increase in the electrical conductivity, because the electrical conductivity of graphene effectively decreased by the alumina coating. Moreover, the synergistic effect of a small amount of graphene was enhanced by the alumina coating, and the stiffening of the alumina sphere/TPU composite due to the added graphene was alleviated by the alumina coating. - Highlights: • Oxidation of graphene with H2O2 introduced anchoring sites for alumina coating. • The anchoring sites improved the efficiency of alumina coating on graphene. • The alumina-coated graphene synergistically enhanced the thermal conductivity

  2. Graphene coated with alumina and its utilization as a thermal conductivity enhancer for alumina sphere/thermoplastic polyurethane composite

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Ki Tae; Dao, Trung Dung [Department of Chemistry, Energy Harvest-Storage Research Center, University of Ulsan, Ulsan 680-749 (Korea, Republic of); Jeong, Han Mo, E-mail: hmjeong@mail.ulsan.ac.kr [Department of Chemistry, Energy Harvest-Storage Research Center, University of Ulsan, Ulsan 680-749 (Korea, Republic of); Anjanapura, Raghu V. [Center for Emerging Technologies, Jain Global Campus, Jain University, Jakkasandra, Ramanagara 562-112 (India); Aminabhavi, Tejraj M. [Soniya College of Pharmacy, S. R. Nagar, Dharwad 580-002 (India)

    2015-03-01

    Graphene was oxidized with H{sub 2}O{sub 2} to introduce additional anchoring sites for effective alumina coating on graphene by the sol–gel method. The X-ray photoelectron spectroscopy studies showed that the oxygen-containing groups such as hydroxyl group useful for coating were introduced by the oxidation. The transmission electron microscopy images and thermogravimetric analysis data demonstrated that the additional anchoring sites enhanced the efficiency of the alumina coating. A small amount of alumina-coated graphene synergistically improved the thermal conductivity of the alumina sphere/thermoplastic polyurethane (TPU) composite without any increase in the electrical conductivity, because the electrical conductivity of graphene effectively decreased by the alumina coating. Moreover, the synergistic effect of a small amount of graphene was enhanced by the alumina coating, and the stiffening of the alumina sphere/TPU composite due to the added graphene was alleviated by the alumina coating. - Highlights: • Oxidation of graphene with H{sub 2}O{sub 2} introduced anchoring sites for alumina coating. • The anchoring sites improved the efficiency of alumina coating on graphene. • The alumina-coated graphene synergistically enhanced the thermal conductivity.

  3. Rheological Properties of Aqueous Nanometric Alumina Suspensions

    Energy Technology Data Exchange (ETDEWEB)

    Chuanping Li

    2004-12-19

    Colloidal processing is an effective and reliable approach in the fabrication of the advanced ceramic products. Successful colloidal processing of fine ceramic powders requires accurate control of the rheological properties. The accurate control relies on the understanding the influences of various colloidal parameters on the rheological properties. Almost all research done on the rheology paid less attention to the interactions of particle and solvent. However, the interactions of the particles are usually built up through the media in which the particles are suspended. Therefore, interactions of the particle with the media, the adsorbed layers on the particle surface, and chemical and physical properties of media themselves must influence the rheology of the suspension, especially for the dense suspensions containing nanosized particles. Relatively little research work has been reported in this area. This thesis addresses the rheological properties of nanometric alumina aqueous suspensions, and paying more attention to the interactions between particle and solvent, which in turn influence the particle-particle interactions. Dense nanometric alumina aqueous suspensions with low viscosity were achieved by environmentally-benign fructose additives. The rheology of nanometric alumina aqueous suspensions and its variation with the particle volume fraction and concentration of fructose were explored by rheometry. The adsorptions of solute (fructose) and solvent (water) on the nanometric alumina particle surfaces were measured and analyzed by TG/DSC, TOC, and NMR techniques. The mobility of water molecules in the suspensions and its variation with particle volume fractions and fructose additive were determined by the {sup 17}O NMR relaxation method. The interactions between the nanometric alumina particles in water and fructose solutions were investigated by AFM. The results indicated that a large number of water layers were physically bound on the particles

  4. Rheological Properties of Aqueous Nanometric Alumina Suspensions

    Energy Technology Data Exchange (ETDEWEB)

    Li, Chuanping [Iowa State Univ., Ames, IA (United States)

    2004-01-01

    Colloidal processing is an effective and reliable approach in the fabrication of the advanced ceramic products. Successful colloidal processing of fine ceramic powders requires accurate control of the rheological properties. The accurate control relies on the understanding the influences of various colloidal parameters on the rheological properties. Almost all research done on the rheology paid less attention to the interactions of particle and solvent. However, the interactions of the particles are usually built up through the media in which the particles are suspended. Therefore, interactions of the particle with the media, the adsorbed layers on the particle surface, and chemical and physical properties of media themselves must influence the rheology of the suspension, especially for the dense suspensions containing nanosized particles. Relatively little research work has been reported in this area. This thesis addresses the rheological properties of nanometric alumina aqueous suspensions, and paying more attention to the interactions between particle and solvent, which in turn influence the particle-particle interactions. Dense nanometric alumina aqueous suspensions with low viscosity were achieved by environmentally-benign fructose additives. The rheology of nanometric alumina aqueous suspensions and its variation with the particle volume fraction and concentration of fructose were explored by rheometry. The adsorptions of solute (fructose) and solvent (water) on the nanometric alumina particle surfaces were measured and analyzed by TG/DSC, TOC, and NMR techniques. The mobility of water molecules in the suspensions and its variation with particle volume fractions and fructose additive were determined by the 17O NMR relaxation method. The interactions between the nanometric alumina particles in water and fructose solutions were investigated by AFM. The results indicated that a large number of water layers were physically bound on the particles

  5. Shielding the LANSCE [Los Alamos Neutron Scattering Center] 800-MeV spallation neutron source

    International Nuclear Information System (INIS)

    Neutrons produced by medium-energy (800-MeV) proton reactions at the Los Alamos Neutron Scattering Center spallation neutron source cause a variety of difficult shield problems. We describe the general shielding questions encountered at such a spallation source, and contrast spallation and reactor source shielding issues using an infinite slab-shield composed of 100 cm of iron and 15 cm of borated polyethylene. The calculations show that (for an incident spallation spectrum characteristic of neutrons leaking at 90 degrees from a tungsten target) high-energy neutrons dominate the dose at the shield surface. Secondary low-energy neutrons (produced by high-energy neutron attenuation) and attendant gamma-rays add significantly to the dose. The primary low-energy neutrons produced directly at the tungsten source contribute negligibly to the dose, and behave similarly to neutrons with a fission spectrum distribution. 8 refs., 10 figs

  6. Mercury purification in the megawatt liquid metal spallation target of EURISOL-DS

    CERN Document Server

    Neuhausen, Joerg; Eller, Martin; Schumann, Dorothea; Eichler, Bernd; Horn, Susanne

    High power spallation targets are going to be used extensively in future research and technical facilities such as spallation neutron sources, neutrino factories, radioactive beam facilities or accelerator driven systems for the transmutation of long-lived nuclear waste. Within EURISOL-DS, a 4 MW liquid metal spallation target is designed to provide neutrons for a fission target, where neutron rich radionuclides will be produced. For the spallation target, mercury is planned to be used as target material. A large amount of radionuclides ranging from atomic number Z=1 to 81 will be produced in the liquid metal during long term irradiation. It is planned to remove those radionuclides by chemical or physicochemical methods to reduce its radioactivity. For the development of a purification procedure, knowledge about the chemical state of the different elements present in the mixture is required. We present a general concept of applicable separation techniques in a target system and show some results of experiment...

  7. Technology and science at a high-power spallation source: Proceedings

    Energy Technology Data Exchange (ETDEWEB)

    1994-01-01

    These proceedings cover many aspects of the usefulness of spallation neutrons. Nine different areas are considered: surfaces and interfaces, engineering, materials science, polymers and complex fluids, chemistry, structural biology, nuclear engineering and radiation effects, condensed matter physics and fundamental physics.

  8. Spallation neutron sources at the INR RAS: present status and prospects

    International Nuclear Information System (INIS)

    The paper presents the program of development of spallation neutron sources for research in nuclear and solid state physics, radiation damage physics, problems of the weapon plutonium utilization and nuclear waste transmutation. (author) 10 figs., 1 tab., 17 refs

  9. Technology and science at a high-power spallation source: Proceedings

    International Nuclear Information System (INIS)

    These proceedings cover many aspects of the usefulness of spallation neutrons. Nine different areas are considered: surfaces and interfaces, engineering, materials science, polymers and complex fluids, chemistry, structural biology, nuclear engineering and radiation effects, condensed matter physics and fundamental physics

  10. An attempt to analyse spallation yelds with a four-parameter formula

    International Nuclear Information System (INIS)

    A semiempirical four-parameter formula, following the formalism of Gupta, is proposed in order to systematise spallation yields. A preliminary test made by comparing calculated and experimentally determined cross sections for 2-GeV bremsstrahlung-induced spallation in natural copper gave very encouraging results (a coefficient of reproducibility R = 1.7 or better). The formula will be used for an exhaustive study of intermediate- and high-energy photospallation of medium-weight nuclei

  11. High-pressure phases of alumina

    Science.gov (United States)

    Lyle, Matthew; Pickard, Chris; Needs, Richard

    2014-03-01

    Alumina (Al2O3) has been widely used as a pressure standard in static diamond anvil cell experiments and is a major chemical component of the Earth. So a detailed knowledge of its high-pressure stability is of great importance in both materials science and deep Earth science. A phase transition is known to occur at roughly 80-100 GPa between corundum and the Rh2O3 (II) structure. A second phase transition to the CaIrO3 structure occurs at even higher pressures. Here we present a computational structure search to reveal three additional structures which are competitive at these pressures but hitherto unknown to be stable in high-pressure alumina.

  12. Li + ion diffusion in nanoscale alumina coatings

    Science.gov (United States)

    Johannes, Michelle; Bernstein, Noam

    Nanoscale coatings of alumina are used to stabilize surfaces for a variety of technologies. Diffusion of ions through these coatings is of primary importance: in some cases, diffusion is unwanted (e.g. corrosion) and in others (e.g. electrode materials), it is necessary. In this work DFT and AIMD calculations are used to investigate Li+ ion diffusion through a nano-layer of alumina, examining the phase (alpha, gamma, and amorphous), ion concentration, and electron count dependence. We look at the role of the surface itself in promoting diffusion. One of our main findings is that as the number of ions or charge increases, the diffusivity rises. We show how our data can explain electrochemical data from coated LiCoO2 cathodes and may point toward better and more efficient coatings for stabilizing electrodes.

  13. Nanoparticles in alumina: Microscopy and Theory

    Science.gov (United States)

    Idrobo, Juan C.; Halabica, Andrej; Rashkeev, Sergey; Glazoff, Michael V.; Boatner, Lynn A.; Haglund, Richard F.; Pennycook, Stephen. J.; Pantelides, Sokrates T.

    2007-03-01

    Transition-metal nanoparticles formed by ion implantation in alumina can be used to modify the optical properties of naturally oxidized and anodized aluminum. Here, we report atomic-resolution Z-contrast images using a scanning transmission electron microscope (STEM) of CoFe and other metal nanoparticles in alumina. We also report electron energy loss spectra (EELS) and relate them to visual appearance and optical properties. Finally, we report first-principles density- functional calculations of nucleation mechanisms for these nanoparticles. This research was sponsored by the Office of Basic Energy Sciences, Division of Materials Sciences and Engineering, U.S. Department of Energy, under contract DE-AC05- 00OR22725 with Oak Ridge National Laboratory, managed and operated by UT-Battelle, by NSF grant No. DMR-0513048, and by Alcoa Inc.

  14. Ultraviolet photoluminescence of porous anodic alumina films

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    Photoluminescence (PL) properties of porous anodic alumina (PAA) films prepared by using electrochemical anodization technique in a mixed solution of oxalic and sulfuric acid have been investigated. The PAA films have an intensive ultraviolet PL emission around 350 nm, of which a possible PL mechanism has been proposed. It was found that the incorporated oxalic ions, which could transform into PL centers and exist in the PAA films, are responsible for this ultraviolet PL emission.

  15. Tribological behaviour of anodised alumina nanohoneycombs

    OpenAIRE

    Wang, Shuo; 王硕

    2012-01-01

    Anodic alumina nanohoneycombs (AAO) have been widely used because of its convenient fabrication and controllable pores’ geometry. A lot of investigations have been conducted to study its physical and chemical properties. However, the mechanical properties, especially tribological properties, of such a popular nanomaterial still remain almost unknown. In this project, a series of scratch experiments were conducted on AAO films fabricated by a two-step anodisation method. The testing system...

  16. Selective metallization of alumina by laser

    OpenAIRE

    Shrivastva, P.B.; Boose, C.A.; Kolster, B.H.; Harteveld, C; Meinders, B.

    1991-01-01

    Nickel has been selectively deposited on an alumina substrate without any pretreatment from a flow of a nickel acetate solution using the focused beam of an excimer laser. Nickel spots as well as nickel lines were drawn and subsequently plated with an electroless Ni-B coating. Excellent adhesion of the metallized layers was achieved, since with laser irradiation, both etching and deposition took place simultaneously.

  17. High contrast laser marking of alumina

    Science.gov (United States)

    Penide, J.; Quintero, F.; Riveiro, A.; Fernández, A.; del Val, J.; Comesaña, R.; Lusquiños, F.; Pou, J.

    2015-05-01

    Alumina serves as raw material for a broad range of advanced ceramic products. These elements should usually be identified by some characters or symbols printed directly on them. In this sense, laser marking is an efficient, reliable and widely implemented process in industry. However, laser marking of alumina still leads to poor results since the process is not able to produce a dark mark, yielding bad contrast. In this paper, we present an experimental study on the process of marking alumina by three different lasers working in two wavelengths: 1064 nm (Near-infrared) and 532 nm (visible, green radiation). A colorimetric analysis has been carried out in order to compare the resulting marks and its contrast. The most suitable laser operating conditions were also defined and are reported here. Moreover, the physical process of marking by NIR lasers is discussed in detail. Field Emission Scanning Electron Microscopy, High Resolution Transmission Electron Microscopy and X-ray Photoelectron Spectroscopy were also employed to analyze the results. Finally, we propose an explanation for the differences of the coloration induced under different atmospheres and laser parameters. We concluded that the atmosphere is the key parameter, being the inert one the best choice to produce the darkest marks.

  18. Spallation-based science and technology and associated nuclear data requirements

    International Nuclear Information System (INIS)

    Rapid advances in accelerator technology in recent years promise average proton beam currents as high as 250 mA with energies greater than one GeV. Such an accelerator could produce very high intensities of neutrons and other nuclear particles thus opening up new areas of science and technology. An example is the efficient burning of transuranic and fission product waste. With such a spallation-burner it appears that high-level waste might be converted to low-level waste on a time scale comparable to the human lifespan at a reasonable additional cost for electric power generation. The emphasis of this paper is on the design of a high power proton target for neutron production, on the nuclear data needed to operate this target safely and effectively, and on data requirements for transmutation. It is suggested that a pilot facility consisting of a 1.6 GeV accelerator and target operating at 25 ma is the next major step in developing this technology. Bursts of protons near the terawatt level might also be generated using such an accelerator with a proton accumulator ring. Research prospects based on such proton bursts are briefly described. The status of established nuclear data needs and of accelerator-based sources for nuclear data measurements is reviewed. 6 refs., 8 figs., 2 tabs

  19. Improvements to the internal and external antenna H(-) ion sources at the Spallation Neutron Source.

    Science.gov (United States)

    Welton, R F; Dudnikov, V G; Han, B X; Murray, S N; Pennisi, T R; Pillar, C; Santana, M; Stockli, M P; Turvey, M W

    2014-02-01

    The Spallation Neutron Source (SNS), a large scale neutron production facility, routinely operates with 30-40 mA peak current in the linac. Recent measurements have shown that our RF-driven internal antenna, Cs-enhanced, multi-cusp ion sources injects ∼55 mA of H(-) beam current (∼1 ms, 60 Hz) at 65-kV into a Radio Frequency Quadrupole (RFQ) accelerator through a closely coupled electrostatic Low-Energy Beam Transport system. Over the last several years a decrease in RFQ transmission and issues with internal antennas has stimulated source development at the SNS both for the internal and external antenna ion sources. This report discusses progress in improving internal antenna reliability, H(-) yield improvements which resulted from modifications to the outlet aperture assembly (applicable to both internal and external antenna sources) and studies made of the long standing problem of beam persistence with the external antenna source. The current status of the external antenna ion source will also be presented.

  20. 纳米氧化锆增韧氧化铝基陶瓷刀具切削性能的研究%Study on Cutting Performance of Nano-scale Zirconia Toughening Alumina Matrix Ceramic Tool Materials

    Institute of Scientific and Technical Information of China (English)

    钟金豹; 黄传真

    2012-01-01

    Compared to the commercial ceramic tool SG4, the cutting performance of nano-scale ZrO2 toughening Al2O3 matrix ceramics tool materials, such as A15Zc and A20Z(c +m), in machining the hardened T10A steel were researched respectively. And the wear resistance and the main wear patterns of A15Zc and A20Z( c + m) were analyzed respectively at the low speed of 99. 5m/min and the high speed of 268. 5m/min.%研究了新型陶瓷刀具Al5Zc和A20Z(c+m)切削淬硬T10A时的切削性能,并与已经商业化的陶瓷刀具SG4的切削性能进行了对比.分析了两种陶瓷刀具在低速切削(99.5m/min)和高速切削(268.5m/min)时的抗磨损能力和主要磨损形态.

  1. Synthesis and characterization of single-crystalline alumina nanowires

    Institute of Scientific and Technical Information of China (English)

    ZHAO Qing; XU Xiang-yu; ZHANG Hong-zhou; CHEN Yao-feng; XU Jun; YU Da-peng

    2005-01-01

    Alumina nanowires were synthesized on large-area silicon substrate via simple thermal evaporation method of heating a mixture of aluminum and alumina powders without using any catalyst or template. The phase structure and the surface morphology of the as-grown sample were analyzed by X-ray diffractometry(XRD) and scanning electron microscopy (SEM), respectively. The chemical composition and the microstructure of the as-grown alumina nanowires were characterized using transmission electron microscope(TEM). The nanowires are usually straight and the single crystalline has average diameter of 40 nm and length of 3 - 5 μm. The growth direction is along the [002] direction. Well aligned alumina nanowire arrays were observed on the surface of many large particles. The catalyst-free growth of the alumina nanowires was explained under the framework of a vapor-solid(VS)growth mechanism. This as-synthesized alumina nanowires could find potential applications in the fabrication of nanodevices.

  2. Influence of TAC on Dispersion of Aqueous Nano Alumina Suspension

    Institute of Scientific and Technical Information of China (English)

    ZHAO Wei; YANG De-an; SONG Jian-jing; YANG Zi; LIANG Chong; XU Ming-xia; XU Ting-xian

    2004-01-01

    The stability of aqueous nano alumina powder suspensions with and without dispersant tri-ammonium citrate (TAC) was investigated by measuring zeta potential at different pH values. The isoelectric point (IEP) of alumina powder shifts towards more acidic pH range by adding TAC dispersant. The results illustrate that adsorption of TAC on alumina powder surface existed in the aqueous suspension, which leads to a high stability of the suspension.

  3. Fission and spallation data evaluation using induced-activity method

    CERN Document Server

    Karapetyan, G S

    2015-01-01

    The induced-activity investigations in off-line analysis performed in different experiments, concerning pre-actinide and actinide nuclei, are here presented and discussed. Generalized expressions for the determination of independent yields/cross sections of radioactive nuclei, formed in the targets, are derived and analysed. The fragment mass distribution from U-238, Th-232 and Ta-181 photofission at the bremsstrahlung end-point energies of 50 and 3500 MeV, and from Am-241, U-238 and Np-237 fission induced by 660-MeV protons, are scrutinized from the point of view of the multimodal fission approach. The results of these studies are hence compared with theoretical model calculations using the CRISP code. We subsequently discuss the complex particle-induced reaction, such as heavy-ions and deuterons, by using the thick-target thick-catcher technique and the two-step vector model framework as well. This is accomplished in order to present the investigation of the main processes (fission, spallation and (multi)fr...

  4. rf improvements for Spallation Neutron Source H- ion sourcea)

    Science.gov (United States)

    Kang, Y. W.; Fuja, R.; Goulding, R. H.; Hardek, T.; Lee, S.-W.; McCarthy, M. P.; Piller, M. C.; Shin, K.; Stockli, M. P.; Welton, R. F.

    2010-02-01

    The Spallation Neutron Source at Oak Ridge National Laboratory is ramping up the accelerated proton beam power to 1.4 MW and just reached 1 MW. The rf-driven multicusp ion source that originates from the Lawrence Berkeley National Laboratory has been delivering ˜38 mA H- beam in the linac at 60 Hz, 0.9 ms. To improve availability, a rf-driven external antenna multicusp ion source with a water-cooled ceramic aluminum nitride (AlN) plasma chamber is developed. Computer modeling and simulations have been made to analyze and optimize the rf performance of the new ion source. Operational statistics and test runs with up to 56 mA medium energy beam transport beam current identify the 2 MHz rf system as a limiting factor in the system availability and beam production. Plasma ignition system is under development by using a separate 13 MHz system. To improve the availability of the rf power system with easier maintenance, we tested a 70 kV isolation transformer for the 80 kW, 6% duty cycle 2 MHz amplifier to power the ion source from a grounded solid-state amplifier.

  5. ENGINEERING DESIGN OF THE EURISOL MULTI-MW SPALLATION TARGET

    CERN Document Server

    Adonai Herrera-Martinez*, Yacine Kadi, Morteza Ashrafi-Nik, Karel Samec, Janis Freibergs, Ernests Platacis

    The European Isotope Separation On-Line Radioactive Ion Beam project (EURISOL) is set to design the ‘next-generation’ European Isotope Separation On-Line (ISOL) Radioactive Ion Beam (RIB) facility. It will extend and amplify current research on nuclear physics, nuclear astrophysics and fundamental interactions beyond the year 2010. In EURISOL, four target stations are foreseen, three direct targets of approximately 100 kW of beam power and one multi-MW target assembly, all driven by a high-power particle accelerator. In this high power target station, high-intensity RIBs of neutron-rich isotopes will be obtained by inducing fission in several actinide targets surrounding a liquid metal spallation neutron source. This article summarises the work carried out within Task 2 of the EURISOL Design Study, with special attention to the coupled neutronics of the mercury proton-to-neutron converter and the fission targets. The overall performance of the facility, which will sustain fast neutron fluxes of the order ...

  6. Engineering design of the EURISOL multi-MW spallation target

    CERN Document Server

    Herrera-Martínez, A; Ashrafi-Nik, M; Samec, K; Freibergs, J; Platacis, E

    2007-01-01

    The European Isotope Separation On-Line Radioactive Ion Beam project (EURISOL) is set to design the 'next-generation' European Isotope Separation On-Line (ISOL) Radioactive Ion Beam (RIB) facility. It will extend and amplify current research on nuclear physics, nuclear astrophysics and fundamental interactions beyond the year 2010. In EURISOL, four target stations are foreseen, three direct targets of approximately 100 kW of beam power and one multi-MW target assembly, all driven by a high-power particle accelerator. In this high power target station, high-intensity RIBs of neutron-rich isotopes will be obtained by inducing fission in several actinide targets surrounding a liquid metal spallation neutron source. This article summarises the work carried out within Task 2 of the EURISOL Design Study, with special attention to the coupled neutronics of the mercury proton-to-neutron converter and the fission targets. The overall performance of the facility, which will sustain fast neutron fluxes of the order of 1...

  7. A High Intensity Linac for the National Spallation Neutron Source

    Science.gov (United States)

    Jason, A.; Bhatia, T.; Billen, J.; Schrage, D.; Kurennoy, S.; Krawczyk, F.; Lynch, M.; Nath, S.; Shafer, R.; Takeda, H.; Tallerico, P.; Wangler, T.; Wood, R.; Young, L.; Grand, P.; McKenzie-Wilson, R.

    1997-05-01

    The National Spallation Neutron Source to be constructed at Oak Ridge National Laboratory, requires a linac capable of delivering up to 5 MW of beam power to an accumulator ring with a nominal 6.2% duty factor and an energy of 1 GeV. Los Alamos, responsible for the linac design, has developed an appropriate room-temperature linac that consists of a drift-tube section from 2.5 to 20 MeV, a coupled-cavity drift-tube section to 100 MeV, and a coupled-cavity section to 1 GeV. The initial scenario requires an average 1.1-mA beam current with a corresponding 28 mA peak current and a 1.2-Mhz chopped time structure corresponding to the ring period. Upgrade to a 4.4 mA average current requires funneling with a peak current of 112 mA in the high-energy sections. Further parameters are presented along with beam dynamics and structure choices and mechanical and rf engineering considerations.

  8. rf improvements for Spallation Neutron Source H-ion source

    Energy Technology Data Exchange (ETDEWEB)

    Kang, Yoon W [ORNL; Fuja, Raymond E [ORNL; Goulding, Richard Howell [ORNL; Hardek, Thomas W [ORNL; Lee, Sung-Woo [ORNL; McCarthy, Mike [ORNL; Piller, Chip [ORNL; Shin, Ki [ORNL; Stockli, Martin P [ORNL; Welton, Robert F [ORNL

    2010-01-01

    The Spallation Neutron Source at Oak Ridge National Laboratory is ramping up the accelerated proton beam power to 1.4 MW and just reached 1 MW. The rf-driven multicusp ion source that originates from the Lawrence Berkeley National Laboratory has been delivering 38 mA H beam in the linac at 60 Hz, 0.9 ms. To improve availability, a rf-driven external antenna multicusp ion source with a water-cooled ceramic aluminum nitride AlN plasma chamber is developed. Computer modeling and simulations have been made to analyze and optimize the rf performance of the new ion source. Operational statistics and test runs with up to 56 mA medium energy beam transport beam current identify the 2 MHz rf system as a limiting factor in the system availability and beam production. Plasma ignition system is under development by using a separate 13 MHz system. To improve the availability of the rf power system with easier maintenance, we tested a 70 kV isolation transformer for the 80 kW, 6% duty cycle 2 MHz amplifier to power the ion source from a grounded solid-state amplifier. 2010 American Institute of Physics.

  9. Neutron diffractometers for structural biology at spallation neutron sources

    International Nuclear Information System (INIS)

    Spallation neutron sources are ideal for diffraction studies of proteins and oriented molecular complexes. With spoliation neutrons and their time dependent wavelength structure, it is easy to electronically select data with an optimal wavelength bandwidth and cover the whole Laue spectrum as time (wavelength) resolved snapshots. This optimized data quality with best peak-to-background ratios and provides adequate spatial and energy resolution to eliminate peak overlaps. The application of this concept will use choppers to select the desired Laue wavelength spectrum and employ focusing optics and large cylindrical 3He detectors to optimize data collection rates. Such a diffractometer will cover a Laue wavelength range from 1 to 5 Angstrom with a flight path length of 10m and an energy resolution of 0.25 Angstrom. Moderator concepts for maximal flux distribution within this energy range will be discussed using calculated flux profiles. Since the energy resolution required for such timed data collection in this super Laue techniques is not very high, the use of a linac only (LAMPF) spoliation target is an exciting possibility with an order of magnitude increase in flux

  10. Spallation Neutron Source Accident Terms for Environmental Impact Statement Input

    International Nuclear Information System (INIS)

    This report is about accidents with the potential to release radioactive materials into the environment surrounding the Spallation Neutron Source (SNS). As shown in Chap. 2, the inventories of radioactivity at the SNS are dominated by the target facility. Source terms for a wide range of target facility accidents, from anticipated events to worst-case beyond-design-basis events, are provided in Chaps. 3 and 4. The most important criterion applied to these accident source terms is that they should not underestimate potential release. Therefore, conservative methodology was employed for the release estimates. Although the source terms are very conservative, excessive conservatism has been avoided by basing the releases on physical principles. Since it is envisioned that the SNS facility may eventually (after about 10 years) be expanded and modified to support a 4-MW proton beam operational capability, the source terms estimated in this report are applicable to a 4-MW operating proton beam power unless otherwise specified. This is bounding with regard to the 1-MW facility that will be built and operated initially. See further discussion below in Sect. 1.2

  11. The COHERENT Experiment at the Spallation Neutron Source

    CERN Document Server

    Akimov, D; Awe, C; Barbeau, P S; Barton, P; Becker, B; Below, V; Bolozdynya, A; Burenkov, A; Cabrera-Palmer, B; Collar, J I; Cooper, R J; Cooper, R L; Cuesta, C; Dean, D; Detwiler, J; Efremenko, Y; Elliott, S R; Fields, N; Fox, W; Galindo-Uribarri, A; Green, M; Heath, M; Hedges, S; Herman, N; Hornback, D; Iverson, E B; Kaufman, L; Klein, S R; Khromov, A; Konovalev, A; Kumpan, A; Leadbetter, C; Li, L; Lu, W; Melikyan, A; Markoff, D; Miller, K; Middlebrook, M; Mueller, P; Naumov, P; Newby, J; Parno, D; Penttila, S; Perumpilly, G; Radford, D; Ray, H; Raybern, J; Reyna, D; Rich, G C; Rimal, D; Rudik, D; Scholberg, K; Scholz, B; Snow, W M; Sosnovchev, A; Shakirov, A; Suchyta, S; Suh, B; Tayloe, R; Thornton, R T; Tolstukhin, A; Vetter, K; Yu, C H

    2015-01-01

    The COHERENT collaboration's primary objective is to measure coherent elastic neutrino-nucleus scattering (CEvNS) using the unique, high-quality source of tens-of-MeV neutrinos provided by the Spallation Neutron Source (SNS) at Oak Ridge National Laboratory (ORNL). In spite of its large cross section, the CEvNS process has never been observed, due to tiny energies of the resulting nuclear recoils which are out of reach for standard neutrino detectors. The measurement of CEvNS has now become feasible, thanks to the development of ultra-sensitive technology for rare decay and weakly-interacting massive particle (dark matter) searches. The CEvNS cross section is cleanly predicted in the standard model; hence its measurement provides a standard model test. It is relevant for supernova physics and supernova-neutrino detection, and enables validation of dark-matter detector background and detector-response models. In the long term, precision measurement of CEvNS will address questions of nuclear structure. COHERENT...

  12. Neutron diffractometers for structural biology at spallation neutron sources

    Energy Technology Data Exchange (ETDEWEB)

    Schoenborn, B.P.; Pitcher, E. [Los Alamos National Laboratory, NM (United States)

    1994-12-31

    Spallation neutron sources are ideal for diffraction studies of proteins and oriented molecular complexes. With spoliation neutrons and their time dependent wavelength structure, it is easy to electronically select data with an optimal wavelength bandwidth and cover the whole Laue spectrum as time (wavelength) resolved snapshots. This optimized data quality with best peak-to-background ratios and provides adequate spatial and energy resolution to eliminate peak overlaps. The application of this concept will use choppers to select the desired Laue wavelength spectrum and employ focusing optics and large cylindrical {sup 3}He detectors to optimize data collection rates. Such a diffractometer will cover a Laue wavelength range from 1 to 5{Angstrom} with a flight path length of 10m and an energy resolution of 0.25{Angstrom}. Moderator concepts for maximal flux distribution within this energy range will be discussed using calculated flux profiles. Since the energy resolution required for such timed data collection in this super Laue techniques is not very high, the use of a linac only (LAMPF) spoliation target is an exciting possibility with an order of magnitude increase in flux.

  13. Deep borehole excavation by hydrostatic-decompression/suction spallation

    Energy Technology Data Exchange (ETDEWEB)

    Ruhle, J.L. [California State Univ., Fullerton, CA (United States). Dept. of Geological Sciences

    1996-09-01

    Any deep drilling system that seeks to abrade or claw its way through deeply buried rock is highly energy-intensive and very much like trying to cut a pane of glass with a hacksaw. Since rock is very weak in tension, it should require far less energy input to fail the rock at the bottom of a deep borehole if the rock were subjected to tensional loads. Furthermore, a significant amount of elastic energy is stored in the matrix of deeply buried rock, and a large amount of hydraulic and pneumatic energy is stored in the pore-fluids of deeply buried rock. Given the relative ease of inducing deep-borehole breakouts by means of minor downward adjustments in drilling fluid density, and given the stress-relief core-disking effects associated with deep coring operations, the rock at the bottom of a deep borehole should readily destroy itself by means of its own self-contained energy if a deliberate and concerted effort were made to induce a rockburst at the bottom of the borehole. A drilling apparatus has recently been designed and prototyped which is intended to excavate rock at the bottom of a deep borehole by means of hydrostatic-decompression and suction-spallation effects. The initial test results are presented and evaluated.

  14. Beam scraping efficiency in the 5 MW spallation neutron source

    Energy Technology Data Exchange (ETDEWEB)

    Stevens, A.J.

    1993-12-01

    Numerical calculations have been performed to evaluate the performance of a simple beam scraping system in the lattice of a rapid cycling (30 Hz) proton accelerator designed to be a high intensity spallation neutron source. The assumption has been made that beam loss will be dominated by rf capture inefficiency at injection (600 MeV kinetic) which is simulated as described below. Comparison is made with a ``sample calculation`` intended to illustrate betatron (beam halo) scraping at full energy which was assumed to be 3 GeV. The parameters of the lattice are those of the design as of April, 1993. The results described here are restricted to a geometry wherein the primary scraper is treated as an aperture in the X (horizontal) coordinate. Evaluation of the efficacy of two dimensional scrapers, or scraping systems which employ magnetic fields remain as topics for further study. The purpose of this study was to determine to what extent beam losses can be confined to a local region of the proposed lattice. The remainder of this note describes the general methodology employed, the rf capture beam loss simulation, and the beam halo growth ``sample calculation``. Section V briefly summarizes the results of this study.

  15. Corrosion of Refractory Alumina-Graphite and Alumina-Graphite-Zirconia in Slag Containing Titania

    Institute of Scientific and Technical Information of China (English)

    XU Yuan; LIU Qing-cai; BAI Chen-guang; CHEN Deng-fu; Joseph W Newkirk

    2004-01-01

    The corrosion of refractory alumina-graphite and alumina-graphite-zirconia in the slag containing titania was studied by immersion tests (quasi-static and dynamic tests). Combining direct observation with microscopic investigations, a mechanism for corrosion was proposed based on the oxidation of graphite and the dissolution of refractory components. During the corrosion process, there are some special phenomena and laws that can be explained by the relation between the corrosion rate and the TiO2 mass percent, the rotational refractory velocity and the morphology of the deteriorated layer.

  16. Simulation study of neutrino nucleus cross section measurement in a segmented detector at a spallation neutron source

    Institute of Scientific and Technical Information of China (English)

    YANG Zhen-Wei; DING Ming-Ming; CHEN Shao-Min; WANG Zhe; ZHANG Feng; GAO Yuan-Ning

    2012-01-01

    Knowledge ofνe-Fe/Pb differential cross sections for νe energy below several tens of MeV scale is believed to be crucial in understanding supernova physics.In a segmented detector at a spallation neutron source,νe energy reconstructed from the electron range measurement is strongly affected because both multiple scattering and electromagnetic showers occur along the electron passage in target materials.In order to estimate these effects,a simulation study has been performed with a cube block model assuming perfect tracking precision.The energy spectrum distortion is observed to be proportional to the atomic number of the target material.Feasibility of unfolding the distorted νe energy spectrum is studied for both Fe and Pb.An evaluation of the statistical accuracy attainable is therefore provided for a segmented detector.

  17. Rheology of Alumina-Based Graphite-Containing Castables

    Institute of Scientific and Technical Information of China (English)

    YE Fangbao; M. Rigaud; LIU Xinhong; ZHONG Xiangchong

    2005-01-01

    In this work, the rheological behavior of ultra-low cement alumina-based castables with addition of flake graphite and extruded graphite pellets has been investigated by using IBB rheometer. Emphasis has been laid on the influence of the type and amount of carbon addition on rheological properties of the alumina-based castables and the results are compared with corresponding alumina castable samples without any carbon addition. It is found that alumina-based castables with extruded graphite pellets have good rheological behavior and flowability with lower water demand ( < 6. 3% )and no segregation during the shearing of castable.

  18. Effect of Alumina Dopant on Transparency of Tetragonal Zirconia

    Directory of Open Access Journals (Sweden)

    Haibin Zhang

    2012-01-01

    Full Text Available Aiming to characterize the effect of alumina dopant on transparency, powders of yttria stabilized tetragonal zirconia doped with alumina (TZ-3Y-E are used as starting material to fabricate transparent tetragonal ZrO2 by high-pressure spark plasma sintering (HP-SPS. However, low transparency of the resultant TZ-3Y-E specimens does not suggest a beneficial effect of alumina dopant although nanometric grains and high density have been achieved. The mechanism is analyzed by comparing with the results of as-sintered yttria stabilized tetragonal zirconia without alumina dopant.

  19. Initial observations of cavitation-induced erosion of liquid metal spallation target vessels at the Spallation Neutron Source

    Energy Technology Data Exchange (ETDEWEB)

    McClintock, D.A., E-mail: mcclintockda@ornl.gov [Neutron Facilities Development Division, Oak Ridge National Laboratory, P.O. Box 2008, Bldg. 8600, MS 6466, Oak Ridge, TN 37831-6466 (United States); Riemer, B.W.; Ferguson, P.D.; Carroll, A.J.; Dayton, M.J. [Neutron Facilities Development Division, Oak Ridge National Laboratory, P.O. Box 2008, Bldg. 8600, MS 6466, Oak Ridge, TN 37831-6466 (United States)

    2012-12-15

    During operation of the Spallation Neutron Source (SNS) at Oak Ridge National Laboratory the mechanical properties of the AISI 316L target module are altered by high-energy neutron and proton radiation. The interior surfaces of the target vessel are also damaged by cavitation-induced erosion, which results from repetitive rapid heating of the liquid mercury by high-energy proton beam pulses. Until recently no observations of cavitation-induced erosion were possible for conditions fully prototypic to the SNS. Post-Irradiation Examination (PIE) of the first and second operational SNS targets was performed to gain insight into the radiation-induced changes in mechanical properties of the 316L target material and the extent of cavitation-induced erosion to the mercury vessel inner surfaces. Observations of cavitation-induced erosion of the first and second operational SNS target modules are presented here, including images of the target vessel interiors and specimens removed from the target beam-entrance regions.

  20. Damping Behavior of Alumina Epoxy Nano-Composites

    Science.gov (United States)

    Katiyar, Priyanka; Kumar, Anand

    2016-05-01

    Polymer nano composites, consisting of a polymer matrix with nanoparticle filler, have been predicted to be one of the most beneficial applications of nanotechnology. Addition of nano particulates to a polymer matrix enhances its performance by capitalizing on the nature and properties of the nano-scale fillers. The damping behavior of composites with nano structured phases is significantly different from that of micro structured materials. Viscoelastic homopolymer exhibit a high material damping response over a relatively narrow range of temperature and frequencies. In many practical situations, a polymeric structure is required to possess better strength and stiffness properties together with a reasonable damping behavior. Viscoelastic polymers show higher loss factor beyond the glassy region which comes with a significant drop in the specific modulus. Addition of nano alumina particles to epoxy leads to improved strength and stiffness properties with an increase in glass transition temperature while retaining its damping capability. Experimental investigations are carried out on composite beam specimen fabricated with different compositions of alumina nano particles in epoxy to evaluate loss factor, tan δ. Impact damping method is used for time response analysis. A single point Laser is used to record the transverse displacement of a point on the composite beam specimen. The experimental results are compared with theoretical estimation of loss factor using Voigt estimation. The effect of inter phase is included in theoretical estimation of loss factor. The result reveals that the study of interface properties is very important in deriving the overall loss factor of the composite since interface occupies a significant volume fraction in the composite.

  1. NMR Revealed Activated Alumina-Water Interaction

    Institute of Scientific and Technical Information of China (English)

    ZHOU Rui; ZHOU Yan; HU Kai; JI Zhen-ping; CHENG Gong-zhen

    2005-01-01

    Three different spin-lattice relaxation times (T1) of water were obtained in activated alumina-water slurry system, which indicate that there exist three states of water: bound water, pore water and bulk water. The chemical shift (δH) decreases as the amount of water added to the system increases due to the differences in contribution of these three states of water in the samples. The δH value for adsorbed water decreases nearly linearly and T1 increases with elevating temperature, which result from the decrease in the content of bound water by the increase in thermal motion.

  2. Nanotube Arrays in Porous Anodic Alumina Membranes

    Institute of Scientific and Technical Information of China (English)

    Liang LI; Naoto KOSHIZAKI; Guanghai LI

    2008-01-01

    This review summarizes the various techniques developed for fabricating nanotube arrays in porous anodic alumina membranes (AAMs). After a brief introduction to the fabrication process of AAMs, taking carbons, metals, semiconductors, organics, biomoleculars, and heterojunctions as typical examples, attention will be focused on the recently established methods to fabricate nanotubes in AAM, including electrochemical deposition, surface sol-gel, modified chemical vapor deposition, atomic layer deposition, and layer-by-layer growth. Every method is demonstrated by one or two reported results. Finally, this review is concluded with some perspectives on the research directions and focuses on the AAM-based nanotubes fields.

  3. Feasibility study of a 1-MW pulsed spallation source

    International Nuclear Information System (INIS)

    A feasibility study of a 1-MW pulsed spallation source based on a rapidly cycling proton synchrotron (RCS) has been completed. The facility consists of a 400-MeV H- linac, a 30-Hz RCS that accelerates the 400-MeV beam to 2 GeV, and two neutron-generating target stations. The design time-averaged current of the accelerator system is 0.5 mA, or 1.04x1014 protons per pulse. The linac system consists of a H- ion source, a 2-MeV RFQ, a 70-MeV DTL and a 330-MeV CCL. Transverse phase space painting to achieve a Kapchinskij-Vladimirskij (K-V) distribution of the injected particles in the RCS is accomplished by charge exchange injection and programming of the closed orbit during injection. The synchrotron lattice uses FODO cells of ≅ 90o phase advance. Dispersion-free straight sections are obtained by using a missing magnet scheme. Synchrotron magnets are powered by a dual-frequency resonant circuit that excites the magnets at a 20-Hz rate and de-excites them at a 60-Hz rate, resulting in an effective rate of 30 Hz, and reducing the required peak rf voltage by 1/3. A key feature of the design of this accelerator system is that beam losses are minimized from injection to extraction, reducing activation to levels consistent with hands-on maintenance. Details of the study are presented. (author) 8 figs., 2 tabs., 7 refs

  4. 5 MW pulsed spallation neutron source, Preconceptual design study

    Energy Technology Data Exchange (ETDEWEB)

    1994-06-01

    This report describes a self-consistent base line design for a 5 MW Pulsed Spallation Neutron Source (PSNS). It is intended to establish feasibility of design and as a basis for further expanded and detailed studies. It may also serve as a basis for establishing project cost (30% accuracy) in order to intercompare competing designs for a PSNS not only on the basis of technical feasibility and technical merit but also on the basis of projected total cost. The accelerator design considered here is based on the objective of a pulsed neutron source obtained by means of a pulsed proton beam with average beam power of 5 MW, in {approx} 1 {mu}sec pulses, operating at a repetition rate of 60 Hz. Two target stations are incorporated in the basic facility: one for operation at 10 Hz for long-wavelength instruments, and one operating at 50 Hz for instruments utilizing thermal neutrons. The design approach for the proton accelerator is to use a low energy linear accelerator (at 0.6 GeV), operating at 60 Hz, in tandem with two fast cycling booster synchrotrons (at 3.6 GeV), operating at 30 Hz. It is assumed here that considerations of cost and overall system reliability may favor the present design approach over the alternative approach pursued elsewhere, whereby use is made of a high energy linear accelerator in conjunction with a dc accumulation ring. With the knowledge that this alternative design is under active development, it was deliberately decided to favor here the low energy linac-fast cycling booster approach. Clearly, the present design, as developed here, must be carried to the full conceptual design stage in order to facilitate a meaningful technology and cost comparison with alternative designs.

  5. The COHERENT Experiment at the Spallation Neutron Source

    Energy Technology Data Exchange (ETDEWEB)

    Elliott, Steven Ray [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

    2015-09-30

    The COHERENT collaboration's primary objective is to measure coherent elastic neutrino- nucleus scattering (CEvNS) using the unique, high-quality source of tens-of-MeV neutrinos provided by the Spallation Neutron Source (SNS) at Oak Ridge National Laboratory (ORNL). In spite of its large cross section, the CEvNS process has never been observed, due to tiny energies of the resulting nuclear recoils which are out of reach for standard neutrino detectors. The measurement of CEvNS has now become feasible, thanks to the development of ultra-sensitive technology for rare decay and weakly-interacting massive particle (dark matter) searches. The CEvNS cross section is cleanly predicted in the standard model; hence its measurement provides a standard model test. It is relevant for supernova physics and supernova-neutrino detection, and enables validation of dark-matter detector background and detector-response models. In the long term, precision measurement of CEvNS will address questions of nuclear structure. COHERENT will deploy multiple detector technologies in a phased approach: a 14-kg CsI[Na] scintillating crystal, 15 kg of p-type point-contact germanium detectors, and 100 kg of liquid xenon in a two-phase time projection chamber. Following an extensive background measurement campaign, a location in the SNS basement has proven to be neutron-quiet and suitable for deployment of the COHERENT detector suite. The simultaneous deployment of the three COHERENT detector subsystems will test the N=2 dependence of the cross section and ensure an unambiguous discovery of CEvNS. This document describes concisely the COHERENT physics motivations, sensitivity and plans for measurements at the SNS to be accomplished on a four-year timescale.

  6. 21 CFR 73.1010 - Alumina (dried aluminum hydroxide).

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 1 2010-04-01 2010-04-01 false Alumina (dried aluminum hydroxide). 73.1010 Section 73.1010 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES GENERAL LISTING OF COLOR ADDITIVES EXEMPT FROM CERTIFICATION Drugs § 73.1010 Alumina (dried...

  7. Textural stability of titania–alumina composite membranes

    NARCIS (Netherlands)

    Kumar, Krishnankutty-Nair P.; Keizer, Klaas; Burggraaf, Anthonie J.

    1993-01-01

    Textural evolution (porosity reduction, pore and crystallite growth) in titania–alumina composite membranes has been studied using thermal analysis, X-ray diffraction, field emission scanning electron microscopy and N2 physisorption techniques. The presence of alumina in the membranes improved the t

  8. Development of Reproducing Alumina-Magnesia-Carbon Bricks

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    The reproducing alumina-magnesia-carbon bricks were prepared with the dumped bricks as starting materials. The bulk density, apparent porosity, crushing strength, modolus of rupture and slag resistance of the specimen were analyzed. The results show that the used refractories can be reused and recycled by the right method. The reproducing alumina-magnesia-carbon bricks with better abilities were prepared.

  9. Evaluation of nano-porous alumina membranes for hemodialysis application.

    Science.gov (United States)

    Attaluri, Anil Chandra; Huang, Zhongping; Belwalkar, Amit; Van Geertruyden, William; Gao, Dayong; Misiolek, Wojciech

    2009-01-01

    Globally, kidney failure has consistently been a major health problem. The number of patients suffering from kidney failure is radically increasing. Some studies forecast an exponential growth in the number of kidney failure patients during the coming years. This emphasizes the importance of hemodialysis (HD) membranes. Current dialysis membranes (cellulose based and synthetic polymer membranes) have irregular pore shapes and sizes, nonuniform pore distribution and limited reusable capability, which leads to low efficiency of toxin removal. New alumina membranes with uniform, controllable and well-structured nanoscale pores, channeled pores aligned perpendicular to the membrane plane, high porosity, high thermal and chemical resistance, and better mechanical properties are certainly preferable to currently used membranes. Determination of transport properties of alumina membranes will assist in the development of the alumina membranes for enhancing hemodialysis. Experiments were performed to evaluate hydraulic permeability, solute diffusive permeability, sieving coefficient, and clearance of four solutes (urea, creatinine, Vancomycin, and inulin) for alumina membrane. Based on comparison of these values against those of polyethersulfone (PES) membranes, transport performance of alumina membrane was determined. Hydraulic conductivity of the alumina membrane was approximately twice that of the PES membrane and inulin sieving coefficient for alumina membrane is approximately 21% higher than that for PES membrane. Alumina membrane has higher solute clearances and no albumin leakage, which makes it an effective replacement for current dialysis membranes. PMID:19293709

  10. Chemical modification/grafting of mesoporous alumina with polydimethylsiloxane (PDMS)

    NARCIS (Netherlands)

    Pinheiro de Melo, A.F.; Nijmeijer, A.; Sripathi, V.G.P.; Winnubst, A.J.A.

    2015-01-01

    A method for polydimethylsiloxane grafting of alumina powders is described which involves chemical modification of the surface of mesoporous (5 nm) γ-alumina flakes with a linker (3-aminopropyltriethoxysilane: APTES), either by a solution phase (SPD) or a vapour phase (VPD) reaction, followed by PDM

  11. 40 CFR 721.10120 - Siloxane modified alumina nanoparticles (generic).

    Science.gov (United States)

    2010-07-01

    ... nanoparticles (generic). 721.10120 Section 721.10120 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... Specific Chemical Substances § 721.10120 Siloxane modified alumina nanoparticles (generic). (a) Chemical... as siloxane modified alumina nanoparticles (PMN P-05-687) is subject to reporting under this...

  12. Characterization of the alumina film with cerium doped on the iron-aluminide diffusion coating

    Energy Technology Data Exchange (ETDEWEB)

    Zhan, Q., E-mail: zhanqin1983@163.com; Yang, H.G.; Zhao, W.W.; Yuan, X.M.; Hu, Y.

    2013-11-15

    An iron-aluminide layer with a thin alumina film on the top as a composite tritium permeation barrier (TPB) coating was characterized under different oxidation conditions. The TPB coating was prepared initially on a China Low Activation Ferritic-Martensitic (CLAM) steel by a pack cementation aluminizing process and then an alumina film was formed on the surface of this iron-aluminide diffusion layer by an oxidizing process. To modify the properties of the FeAl/Al{sub 2}O{sub 3} composite TPB coatings, the rare earth element (cerium) was introduced as a dopant while oxidizing. Characterization showed that a continuous oxide scale with a thickness of about 300–400 nm was formed on the FeAl diffusion layer. The film was mainly composed of Al{sub 2}O{sub 3} doped with a little CeO{sub 2}. In addition, the concentration of α-Al{sub 2}O{sub 3} increased with elevated temperature while oxidizing. The phase transformation behavior of alumina scale on the surface of an iron-aluminide layer was studied in this paper.

  13. Spray freeze granulation of submicron alumina and its sintering behavior via spark plasma sintering

    Directory of Open Access Journals (Sweden)

    Liu Wei

    2015-01-01

    Full Text Available Spray freeze granulation is an improved method based on spray granulation, solving many limitations of spray granulation. In this work, spray freeze granulation of submicron alumina is performed to explore the possibility of industrial-scale production of dense alumina via spark plasma sintering. Powder pretreatment such as sedimentation and the selection of granules with the appropriate size are employed for the maximum use of the high qualified as-prepared granules and granule sliding, which would provide a guidance for the industrial-scale production. Debound granules were densified via SPS and the corresponding sintering behaviors such as the recorded shrinkage and shrinkage rate were discussed. The comparison of sintering behaviors between granulated and as-received powder are conducted to identify the role of spray freeze granulation in sinterability for dense alumina. The Vickers hardness (Hv and the fracture toughness (KIC of the freeze granulated body are higher than the corresponding properties of the as-received body due to the more homogenous microstructure with little agglomeration in the particle packing after freeze granulation.

  14. Application of Origen2.1 in the decay photon spectrum calculation of spallation products

    CERN Document Server

    Hong, Shuang; Xu, Hu-Shan; Meng, Hai-Yan; Zhang, Lu; Liu, Zhao-Qing; Gao, Yu-Cui; Chen, Kang

    2016-01-01

    Origen2.1 is a widely used computer code for calculating the burnup, decay, and processing of radioactive materials. However, the nuclide library of Origen2.1 is used for existing reactors like pressurized water reactor, to calculate the photon spectrum released by the decay of spallation products, we have made specific libraries for the ADS tungsten spallation target, based on the results given by a Monte Carlo code: FLUKA. All the data used to make the Origen2.1 libraries is obtained from Nuclear structure & decay Data (NuDat2.6). The accumulated activity of spallation products and the contribution of nuclides to photon emission are given in this paper.

  15. Quantitative measurement of the film interface strength by laser spallation technique

    Institute of Scientific and Technical Information of China (English)

    周明; 张永康; 蔡兰

    2001-01-01

    A novel laser spallation technique for quantitatively measuring the film interface strength is presented. Through the analysis of the physical procedure of the film spallation, a mathematical model is established based on the multiple reflections and transmissions of the stress waves within film, and a formula for calculating the interface strength and the strain rate is obtained. Using this method the interface strength of Cr stainless steel/TiN, Al/EPOXY and Fe/EPOXY are measured. A new method of wave-shape analysis is developed to judge the film spallation intuitionally, and to determine the spall moment, spall depth and spall strength directly. The film interface strength has been measured using single laser shock.

  16. Comparison of deep desulfurization methods in alumina production process

    Institute of Scientific and Technical Information of China (English)

    刘战伟; 李旺兴; 马文会; 尹中林; 武国宝

    2015-01-01

    Several methods of deep desulfurization in alumina production process were studied, and the costs of these methods were compared. It is found that most of the S2− in sodium aluminate solution can be removed by adding sodium nitrate or hydrogen peroxide in digestion process, and in this way the effect of S2− on alumina product quality is eliminated. However, the removal efficiency of2-23SOin sodium aluminate solution is very low by this method. Both S2− and2-23SO in sodium aluminate solution can be removed completely by wet oxidation method in digestion process. The cost of desulfurization by wet oxidation is lower than by adding sodium nitrate or hydrogen peroxide. The results of this research reveal that wet oxidation is an economical and feasible method for the removal of sulfur in alumina production process to improve alumina quality, and provide valuable guidelines for alumina production by high-sulfur bauxite.

  17. Modified-starch Consolidation of Alumina Ceramics

    Institute of Scientific and Technical Information of China (English)

    JU Chenhui; WANG Yanmin; YE Jiandong; HUANG Yun

    2008-01-01

    The alumina ceramics with the homogeneous microstructure and the higher density were fabricated via the modified-starch consolidation process by 1.0 wt%of a modified starch as a consolidator/binder.The swelling behavior of the modified oxidized tapioca starch was analyzed by optical microscope,and two other corn starches(common corn starch and high amylose COrn starch)were also analyzed for comparison.The modified starch used as a binder for the consolidation swelled at about 55℃.began to gelatinize at 65℃ and then was completely gelatinized at 75℃.But the corn starches could not be completely gelatinized even at 80℃for 1 h.The high-strength green bodies(10.6 MPa)with the complex shapes were produced.The green bodies were sintered without any binder burnout procedure at 1700℃and a relative density of 95.3% was obtained for the sintered bodies,which is similar to that of the sintered sample formed by conventional slip casting.In addition,the effect of temperature on the apparent viscosity of the starch/alumina slurry in the process was investigated,and the corresponding mechanism for the starch consolidation was discussed.

  18. Properties of Transition Metal Doped Alumina

    Science.gov (United States)

    Nykwest, Erik; Limmer, Krista; Brennan, Ray; Blair, Victoria; Ramprasad, Rampi

    Crystallographic texture can have profound effects on the properties of a material. One method of texturing is through the application of an external magnetic field during processing. While this method works with highly magnetic systems, doping is required to couple non-magnetic systems with the external field. Experiments have shown that low concentrations of rare earth (RE) dopants in alumina powders have enabled this kind of texturing. The magnetic properties of RE elements are directly related to their f orbital, which can have as many as 7 unpaired electrons. Since d-block elements can have as many as 5 unpaired electrons the effects of substitutional doping of 3d transition metals (TM) for Al in alpha (stable) and theta (metastable) alumina on the local structure and magnetic properties, in addition to the energetic cost, have been calculated by performing first-principles calculations based on density functional theory. This study has led to the development of general guidelines for the magnetic moment distribution at and around the dopant atom, and the dependence of this distribution on the dopant atom type and its coordination environment. It is anticipated that these findings can aid in the selection of suitable dopants help to guide parallel experimental efforts. This project was supported in part by an internship at the Army Research Laboratory, administered by the Oak Ridge Institute for Science and Education, along with a grant of computer time from the DoD High Performance Computing Modernization Program.

  19. Parsing abnormal grain growth in specialty aluminas

    Science.gov (United States)

    Lawrence, Abigail Kremer

    Grain growth in alumina is strongly affected by the impurities present in the material. Certain impurity elements are known to have characteristic effects on abnormal grain growth in alumina. Specialty alumina powders contain multiple impurity species including MgO, CaO, SiO2, and Na 2O. In this work, sintered samples made from alumina powders containing various amounts of the impurities in question were characterized by their grain size and aspect ratio distributions. Multiple quantitative methods were used to characterize and classify samples with varying microstructures. The grain size distributions were used to partition the grain size population into subpopulations depending on the observed deviation from normal behavior. Using both grain size and aspect ratio a new visual representation for a microstructure was introduced called a morphology frequency map that gives a fingerprint for the material. The number of subpopulations within a sample and the shape of the distribution on the morphology map provided the basis for a classification scheme for different types of microstructures. Also using the two parameters a series of five metrics were calculated that describe the character of the abnormal grains in the sample, these were called abnormal character values. The abnormal character values describe the fraction of grains that are considered abnormal, the average magnitude of abnormality (including both grain size and aspect ratio), the average size, and variance in size. The final metric is the correlation between grain size and aspect ratio for the entire population of grains. The abnormal character values give a sense of how different from "normal" the sample is, given the assumption that a normal sample has a lognormal distribution of grain size and a Gaussian distribution of aspect ratios. In the second part of the work the quantified measures of abnormality were correlated with processing parameters such as composition and heat treatment conditions. A

  20. Mercury as a target material for pulsed (fast) spallation neutron sources systems

    International Nuclear Information System (INIS)

    For spallation neutron systems which are not adversely affected by the high thermal absorption cross section, mercury seems to be a good target material because it is liquid at ambient temperatures, shows good compatibility with low nickel content steels, has a high neutron yield, is easy to purify and has no truly long lived isotopes. Its performance in an engineered target for pulsed spallation sources is expected to be superior to that of its solid competitors Ta and W and equivalent to that of Pb or Pb-Bi but at much less overall technical effort. (author) 5 figs., 5 tabs., 11 refs

  1. Geometric optimization of spallation targets for the MYRRHA reactor using MCNPX simulations

    Energy Technology Data Exchange (ETDEWEB)

    Rebello Junior, Andre Luiz P.; Martinez, Aquilino S.; Golcalves, Alessandro C., E-mail: junior.rebello@poli.ufrj.br [Universidade Federal do Rio de Janeiro (UFRJ), Rio de Janeiro, RJ (Brazil). Dept. de Engenharia Nuclear

    2013-07-01

    The present work aims to evaluate the behavior of neutron multiplicity in a spallation target using MCNPX simulations, focusing on its application in the MYRRHA reactor. It was studied the two types of spallation target proposed for the MYRRHA project, windowless and windows target, in order to compare them and nd saturation boundaries. Some saturation boundaries were found and the windowless target proved to be as viable as the windows one. Each one produced nearly the same number of neutrons per incident proton. Using the concept of neutron cost, it was also observed that the optimum conditions on neutron production occur at about 1GeV, for both target designs. (author)

  2. Parametric study of spallation targets for the MYRRHA reactor using MCNPX simulations

    Science.gov (United States)

    Rebello, A. L. P.; Martinez, A. S.; Gonçalves, A. C.

    2014-06-01

    The present work aims to evaluate the behavior of neutron multiplicity in a spallation target using MCNPX simulations, focusing on its application in the MYRRHA reactor. It was studied the two types of spallation target proposed for the MYRRHA project, windowless and windows target, in order to compare them and find saturation boundaries. Some saturation boundaries were found and the windowless target proved to be as viable as the windows one. Each one produced nearly the same number of neutrons per incident proton. Using the concept of neutron cost, it was also observed that the optimum conditions on neutron production occur at about 1GeV, for both target designs.

  3. Target station design for a 1 MW pulsed spallation neutron source

    International Nuclear Information System (INIS)

    Target stations are vital components of the 1 MW, next generation spallation neutron source proposed for LANSCE. By and large, target stations design determines the overall performance of the facility. Many traditional concepts will probably have to be rethought, and many new concepts will have to be put forward to meet the 1 MW challenge. This article gives a brief overview of the proposed neutron spallation source from the target station viewpoint, as well as the general philosophy adopted for the design of the LANSCE-II target stations. Some of the saliant concepts and features envisioned for LANSCE-II are briefly described

  4. Technical design report of spallation neutron source facility in J-PARC

    International Nuclear Information System (INIS)

    One of the experimental facilities in Japan Proton Accelerator Research Complex (J-PARC) is the Materials and Life Science Experimental Facility (MLF), where high-intensity neutron beams are used as powerful probes for basic research on materials and life science, as well as research and development in industrial engineering. Neutrons are generated with nuclear spallation reaction by bombarding a mercury target with high-intensity proton beams. The neutrons are slowed down with supercritical hydrogen moderators and then extracted as beams to each experimental apparatus. The principal design of the spallation neutron source is compiled in this comprehensive report. (author)

  5. Final report on the application of chaos theory to an alumina sensor for aluminum reduction cells

    Energy Technology Data Exchange (ETDEWEB)

    Williford, R.E.; Windisch, C.F. Jr.

    1992-03-01

    Four chaos-related digital signal analysis (DSA) methods were applied to the analysis of voltage and current signals collected from aluminum electrolysis cells. Two separate data bases were analyzed: bench-scale laboratory experiments and a pilot-scale test. The objective was to assess the feasibility of using these types of data and analysis methods as the basis for a non-intrusive sensor to measure the alumina content in the electrolysis bath. This was the first time chaos theory approaches have been employed to analyze aluminum electrolysis cells.

  6. The spallation in reverse kinematics: what for a coincidence measurement?; La spallation en cinematique inverse: pourquoi faire une mesure en coincidence?

    Energy Technology Data Exchange (ETDEWEB)

    Ducret, J.E

    2006-07-15

    The Spaladin installation has been designed to study spallation reactions in reverse kinematics. Furthermore, the heavy and light fragments are detected by coincidence which allows us to get an instantaneous picture of the reaction at a level of accuracy better than that obtained through inclusive measurement. The first part is dedicated to the theoretical description of the different mechanisms involved in the spallation reactions. In the second part we describe the Spaladin installation and report some results on the reaction: Fe{sup 56} + p at an energy of 1 GeV/nucleon. In the third part we expose the performance of the installation through its simulation with the Geant-IV model. We present a study about the sensitivity of the Spaladin installation to theoretical predictions. The fourth part is dedicated to the future experiments that will be performed with the Spaladin installation. (A.C.)

  7. Dissertation: Precompound Emission of Energetic Light Fragments in Spallation Reactions

    Energy Technology Data Exchange (ETDEWEB)

    Kerby, Leslie Marie [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2015-08-04

    Emission of light fragments (LF) from nuclear reactions is an open question. Different reaction mechanisms contribute to their production; the relative roles of each, and how they change with incident energy, mass number of the target, and the type and emission energy of the fragments is not completely understood. None of the available models are able to accurately predict emission of LF from arbitrary reactions. However, the ability to describe production of LF (especially at energies ≳ 30 MeV) from many reactions is important for different applications, such as cosmic-ray-induced Single Event Upsets (SEUs), radiation protection, and cancer therapy with proton and heavy-ion beams, to name just a few. The Cascade-Exciton Model (CEM) version 03.03 and the Los Alamos version of the Quark-Gluon String Model (LAQGSM) version 03.03 event generators in Monte Carlo N-Particle Transport Code version 6 (MCNP6) describe quite well the spectra of fragments with sizes up to ⁴He across a broad range of target masses and incident energies (up to ~ 5 GeV for CEM and up to ~ 1 TeV/A for LAQGSM). However, they do not predict the high energy tails of LF spectra heavier than ⁴He well. Most LF with energies above several tens of MeV are emitted during the precompound stage of a reaction. The current versions of the CEM and LAQGSM event generators do not account for precompound emission of LF larger than ⁴He. The aim of our work is to extend the precompound model in them to include such processes, leading to an increase of predictive power of LF-production in MCNP6. This entails upgrading the Modified Exciton Model currently used at the preequilibrium stage in CEM and LAQGSM. It also includes expansion and examination of the coalescence and Fermi break-up models used in the precompound stages of spallation reactions within CEM and LAQGSM. Extending our models to include emission of fragments heavier than ⁴He at the precompound stage has indeed provided results that have much

  8. Preparation and Testing of Corrosion and Spallation-Resistant Coatings

    Energy Technology Data Exchange (ETDEWEB)

    Hurley, John

    2015-11-01

    with the Rene 80. One-inch-diameter buttons were machined from each of the bonded blocks and sent to Siemens for standard oxidation, spallation, and corrosion testing, which should be complete in the spring of 2016.

  9. Terbium luminescence in alumina xerogel fabricated in porous anodic alumina matrix under various excitation conditions

    International Nuclear Information System (INIS)

    Terbium-doped alumina xerogel layers are synthesized by the sol-gel method in pores of a porous anodic alumina film 1 μm thick with a pore diameter of 150–180 nm; the film is grown on a silicon substrate. The fabricated structures exhibit terbium photoluminescence with bands typical of trivalent terbium terms. Terbium X-ray luminescence with the most intense band at 542 nm is observed for the first time for such a structure. Morphological analysis of the structure by scanning electron microscopy shows the presence of xerogel clusters in pore channels, while the main pore volume remains unfilled and pore mouths remain open. The data obtained confirm the promising applications of fabricated structures for developing matrix converters of X-rays and other ionizing radiations into visible light. The possibilities of increasing luminescence intensity in the matrix converter are discussed.

  10. Microstructural evolution of alumina-zirconia nanocomposites; Evolucao microestrutural de nanocompositos alumina-zirconia

    Energy Technology Data Exchange (ETDEWEB)

    Ojaimi, C.L.; Chinelatto, A.S.A.; Chinelatto, A.L. [Universidade Estadual de Ponta Grossa (UEPG), PR (Brazil); Pallone, E.M.J.A., E-mail: christianelago@yahoo.com.br [Universidade de Sao Paulo (USP), Pirassununga, Sao Paulo, SP (Brazil). Faculdade de Zootecnia e Engenharia de Alimentos

    2012-07-01

    Ceramic materials have limited use due to their brittleness. The inclusion of nanosized particles in a ceramic matrix, which are called nanocomposites, and ceramic processing control by controlling the grain size and densification can aid in obtaining ceramic products of greater strength and toughness. Studies showed that the zirconia nano inclusions in the matrix of alumina favors an increase in mechanical properties by inhibiting the grain growth of the matrix and not by the mechanism of the transformation toughening phase of zirconia. In this work, the microstructural evolution of alumina nanocomposites containing 15% by volume of nanometric zirconia was studied. From the results it was possible to understand the sintering process of these nanocomposites. (author)

  11. Dissolution kinetics for alumina in cryolite melts. Distribution of alumina in the electrolyte of industrial aluminium cells

    Energy Technology Data Exchange (ETDEWEB)

    Kobbeltvedt, Ove

    1997-12-31

    This thesis contributes to the understanding of which factors determine the rate of dissolution of alumina added to the bath in alumina reduction cells. Knowing this may help reduce the occurrences of operation interruptions and thus make it possible to produce aluminium using less energy. When alumina powder was added to a stirred cryolite melt, the alumina dissolved in two distinct main stages. In the first stage, the dissolution rate was very high, which reflects dissolution of single alumina grains that are being dispersed in the bath upon addition. In the second stage, lumps of alumina infiltrated with bath dissolved at a rate considerably slower than that of the first stage. The formation of these alumina agglomerates is the most important contributor to slow dissolution. The parameters varied in the experiments were convection, batch size, and temperature of the bath and of the added alumina. Increased gas stirring of the bath speeded up dissolution in both stages but the size of the batch was of little significance. Increasing the bath temperature had no effect in the first stage but speeded up dissolution considerably in the second stage. Compared to adding alumina at room temperature, preheating it to a high temperature (600 {sup o}C) increased the dissolution rate in the first stage while preheating to lower temperatures (100-300 {sup o}C) decreased the dissolution rate. In the second stage, preheating slowed the dissolution. The two latter phenomena of reduced dissolution rates are ascribed to the removal of moisture from the alumina upon preheating. The bath flow and the distribution of alumina in the bath were measured in four different types of cells. It was found that if a certain asymmetry of the magnetic field traverse to the cell was present, due to the presence of risers, then loops of high velocity bath flow occurred near the short ends of the cell. Thus, alumina added near the short ends is effectively transferred away from the feeding

  12. Microstructural Models of Alumina Nanotubes and Anodic Porous Alumina Film Formed in Sulphuric Acid

    Institute of Scientific and Technical Information of China (English)

    濮林; 陈志强; 谭超; 杨铮; 邹建平; 鲍希茂; 冯端; 施毅; 郑有蚪

    2002-01-01

    Electrochemical stepwise anodization of aluminium in dilute sulphuric acid results in the formation of alumina nanotubes (ANTs) due to the hexagonal split of the anodic porous alumina (APA) film along the cell boundaries containing many voids; that is, the ANTs are the completely detached cell of the APA film. The inner diameters of the ANTs are in the range of 10 - 20 nm, and the aspect ratio (inner diameter/length) of the ANTs can be about 80. The relations found for pore diameter, cell diameter and barrier layer thickness are around 1, 2.7 and 0.85 nm/V, respectively. Transmission electron microscopy (TEM) reveals that the ANT wall has a three-shell structure: an outer shell (metal/oxide interface) consisting of pure alumina oxide, a middle shell of the hydrated oxide or/and hydroxide and an inner shell (oxide/electrolyte interface) of anion incorporated oxide with the thickness ratio of 1:1:2. The structural change of ANTs induced by e-beam irradiation in TEM indicates that the thermal instability of the hydrated oxide or/and hydroxide within the cell wall might be an alternative origin contributing to the self-organization of the cells, leading to a densely packed triangular cell lattice of the APA film.

  13. Mechanical behavior of alumina and alumina-feldspar based ceramics in an acetic acid (4%) environment

    International Nuclear Information System (INIS)

    This study investigates the mechanical properties of alumina-feldspar based ceramics when exposed to an aggressive environment (acetic acid 4%). Alumina ceramics containing different concentrations of feldspar (0%, 1%, 5%, 10%, or 40%) were sintered at either 1300, 1600, or 1700 oC. Flaws (of width 0%, 30%, or 50%) were introduced into the specimens using a saw. Half of these ceramic bodies were exposed to acetic acid. Their flexural strength, KIC, and porosity were measured and the fractured samples were evaluated using scanning electronic- and optical microscopy. It was found that in the ceramic bodies sintered at 1600 oC, feldspar content up to 10% improved flexural strength and KIC, and reduced porosities. Generally, it was found that acetic acid had a weakening effect on the flexural strength of samples sintered at 1700 oC but a beneficial effect on KIC of ceramics sintered at 1600 oC. It was concluded that alumina-based ceramics with feldspar content up to 10% and sintered at higher temperatures would perform better in an aggressive environment similar to oral cavity.

  14. Ballistic Performance of Alumina and Zirconia-toughened Alumina Against 7.62 Armour Piercing Projectile

    Directory of Open Access Journals (Sweden)

    S G. Savio

    2014-09-01

    Full Text Available A study was carried out to compare the ballistic performance of high purity alumina and zirconia-toughened alumina (ZTA using depth of penetration (DoP test configuration against 7.62 mm armour piercing (AP ammunition. The effect of tile thickness on the differential efficiency factor (DEF was studied for tile thickness in the range of 3 mm to 6 mm for alumina tiles and 3 mm to 5 mm for ZTA tiles. The DEF is found to increase as tile thickness increases. An analysis on the failed shots showed that the residual shot weight does not follow a single linear relationship with ceramic tile thickness unlike the residual DoP for all thicknesses of tiles. Post-ballistic analysis on ceramic powder for particle size distribution was carried out and the results are presented.Defence Science Journal, Vol. 64, No. 5, September 2014, pp.477-483, DOI:http://dx.doi.org/10.14429/dsj.64.6745

  15. Scattering and absorption coefficients of silica-doped alumina aerogels.

    Science.gov (United States)

    Fu, Tairan; Tang, Jiaqi; Chen, Kai; Zhang, Fan

    2016-02-01

    Alumina-based aerogels are especially useful in many applications due to their excellent stability at high temperatures. This study experimentally analyzed the radiative properties of silica-doped alumina aerogels through spectral directional-hemispherical measurements for wavelengths of 0.38-25 μm. The silica-doped alumina aerogel samples were prepared with a 1.4∶1 molar ratio of silica to alumina. A two-flux model was used to describe the radiation propagation in a 1D scattering absorbing sample to derive expressions for the normal-hemispherical transmittances and reflectances based on the transport approximation. The normal-hemispherical transmittances and reflectances were measured at various spectral wavelengths and sample thicknesses using the integrating sphere method. The spectral absorption and transport scattering coefficients of silica-doped alumina aerogels were then determined from the measured normal-hemispherical data. The absorption and transport scattering coefficients of silica-doped alumina aerogels are (0.1  cm-1, 36  cm-1) and (0.1  cm-1, 112  cm-1) for wavelengths of 0.38-8.0 μm. The spectral transport scattering coefficient varies in the opposite direction from the spectral absorption coefficient for various wavelengths. The radiative properties for silica and alumina aerogels were quite different for the absorption coefficient for wavelengths of 2.5-8.0 μm and for the transport scattering coefficient for wavelengths of 0.38-2.5 and 3.5-6.0 μm. The measured radiative properties were used to predict the spectral normal-hemispherical reflectance and transmittance of the silica-doped alumina aerogels for various sample thicknesses and wavelengths. The predicted values do not change for the sample thicknesses greater than a critical value. The analysis provides valuable reference data for alumina aerogels for high-temperature applications. PMID:26836071

  16. Crystallography of Alumina-YAG-Eutectic

    Science.gov (United States)

    Farmer, Serene C.; Sayir, Ali; Dickerson, Robert M.; Matson, Lawrence E.

    2000-01-01

    Multiple descriptions of the alumina-YAG eutectic crystallography appear in the ceramic literature. The orientation between two phases in a eutectic system has direct impact on residual stress, morphology, microstructural stability, and high temperature mechanical properties. A study to demonstrate that the different crystallographic relationships can be correlated with different growth constraints was undertaken. Fibers produced by Laser-Heated Float Zone (LHFZ) and Edge-defined Film-fed Growth (EFG) were examined. A map of the orientation relationship between Al2O3 and Y3Al5O12 and their relationship to the fiber growth axis as a function of pull rate are presented. Regions in which a single orientation predominates are identified.

  17. Porous Alumina Based Capacitive MEMS RH Sensor

    CERN Document Server

    Juhasz, L; Timar-Horvath, Veronika; Desmulliez, Marc; Dhariwal, Resh

    2008-01-01

    The aim of a joint research and development project at the BME and HWU is to produce a cheap, reliable, low-power and CMOS-MEMS process compatible capacitive type relative humidity (RH) sensor that can be incorporated into a state-of-the-art, wireless sensor network. In this paper we discuss the preparation of our new capacitive structure based on post-CMOS MEMS processes and the methods which were used to characterize the thin film porous alumina sensing layer. The average sensitivity is approx. 15 pF/RH% which is more than a magnitude higher than the values found in the literature. The sensor is equipped with integrated resistive heating, which can be used for maintenance to reduce drift, or for keeping the sensing layer at elevated temperature, as an alternative method for temperature-dependence cancellation.

  18. Fracture simulation for zirconia toughened alumina microstructure

    CERN Document Server

    Kim, Kyungmok; Forest, Bernard

    2013-01-01

    Purpose - The purpose of this paper is to describe finite element modelling for fracture and fatigue behaviour of zirconia toughened alumina microstructures. Design/methodology/approach - A two-dimensional finite element model is developed with an actual $Al{_2}O{_3}$ - 10 vol% $ZrO{_2}$ microstructure. A bilinear, time-independent cohesive zone law is implemented for describing fracture behaviour of grain boundaries. Simulation conditions are similar to those found at contact between a head and a cup of hip prosthesis. Residual stresses arisen from the mismatch of thermal coefficient between grains are determined. Then, effects of a micro-void and contact stress magnitude are investigated with models containing residual stresses. For the purpose of simulating fatigue behaviour, cyclic loadings are applied to the models. Findings - Results show that crack density is gradually increased with increasing magnitude of contact stress or number of fatigue cycles. It is also identified that a micro-void brings about...

  19. Electrochemical modification process of anodic alumina membrane

    Institute of Scientific and Technical Information of China (English)

    YU Mei; LIU Jian-hua; LI Song-mei

    2006-01-01

    The modification procedure of anodic alumina membrane(AAM) was studied. The AAM structure after modification was characterized by nickel nanowires prepared in AAM. Scanning electron microscopy was used to characterize the topography and structure properties of the AAM and nickel nanowires. The transformation of the current during the voltage reduction was studied. The mechanism of current and structure change during modification was discussed. The results show that a root structure produces after the AAM modification. The length of the root structure depends on the velocity of the voltage reduction. Slow voltage reduction leads to a large length of the root structure,otherwise,a short length of the root structure. At the end of the modification,the barrier layer is thin enough to be passed by electrons. Hence,the direct electrodeposition of one-dimensional nanowires can be carried out on the AAM with barrier layer and aluminum matrix successfully without any other treatments.

  20. Aluminum matrix composites reinforced with alumina nanoparticles

    CERN Document Server

    Casati, Riccardo

    2016-01-01

    This book describes the latest efforts to develop aluminum nanocomposites with enhanced damping and mechanical properties and good workability. The nanocomposites exhibited high strength, improved damping behavior and good ductility, making them suitable for use as wires. Since the production of metal matrix nanocomposites by conventional melting processes is considered extremely problematic (because of the poor wettability of the nanoparticles), different powder metallurgy routes were investigated, including high-energy ball milling and unconventional compaction methods. Special attention was paid to the structural characterization at the micro- and nanoscale, as uniform nanoparticle dispersion in metal matrix is of prime importance. The aluminum nanocomposites displayed an ultrafine microstructure reinforced with alumina nanoparticles produced in situ or added ex situ. The physical, mechanical and functional characteristics of the materials produced were evaluated using different mechanical tests and micros...

  1. Special requirements for alumina ceramic of ESG electrode bowl

    Institute of Scientific and Technical Information of China (English)

    ZHANG Jun-an; XUE Kai; ZHANG Jia-tai; ZHANG Qiang

    2004-01-01

    At present ESG (Electrostatic Suspended Gyro) is the most precise inertia element in the world. The electrode bowl, which has direct effect on the precision of ESG, is a key part to ESG. Through the analysis of the function and characteristic of the electrode bowl in hollow rotor ESG and the present situation of new material development in the world, the alumina ceramic is regarded as the best material for the electrode bowl of hollow rotor ESG. By analyzing the present situation of alumina ceramic in the world, main technique requirements have been put forward for the alumina ceramic of ESG electrode bowl which is also fit for solid rotor ESG.

  2. Wenshan’s 800,000-ton Alumina Project Completed

    Institute of Scientific and Technical Information of China (English)

    2012-01-01

    <正>On September 26,2012,the completion ceremony of the 800,000-ton alumina project was held at the alumina factory in Matang Industrial Park, Wenshan city,Yunnan.Wenshan’s 800,000-ton alumina project and its supporting mining construction projects have been listed as one of 20 major industrial construction projects of Yunnan. The project covers an area of approximately 5,500 mu,with an estimated total investment of RMB 4,987 million. It is invested and built

  3. Design and fabrication of alumina micro reciprocating engine

    Institute of Scientific and Technical Information of China (English)

    JIN Peng; GAO Yu-long; LIU Nan; JIANG Kylie

    2008-01-01

    Microengines are regarded as the potential replacements for batteries. Aimed at the unsatisfactory thermal property of silicon used in the combustion chambers, ceramics are chosen as the construction material in this paper. The fabrication process where alumina has been chosen as the microengine material is discussed. Vigorous FEA has been carried out, and it is found that the material satisfies the stress and deformation require-ments of the design. Then the alumina fabrication process is described. Soft reusable polydimethylsiloxane (PDMS) moulds are produced from SU-8 resist masters, and alumina microengine parts are produced using the PDMS moulds. Images of the ceramic components show that the fabrication satisfies the design requirements.

  4. Reaction of Sillimnite with Alumina at Elevated Temperatures

    Institute of Scientific and Technical Information of China (English)

    SHENYang-yun; SHENYi

    1996-01-01

    The reaction of sillimanite with alumina at temperatures 1650℃ an 1750℃ has been investigated.The results have shown that,in the laboratory test conditions,the higher the alumina content,the lower will be the amounts of glass-phse of the fired body and the higher will be the formation of mullite .In the present tests,however,the reaction in concern has not been completed,the reaction in concern has not been completed.Some uncombined residual alumina still exist in the form of corundum.

  5. Processing of silicon nitride and alumina nanosize powders

    Energy Technology Data Exchange (ETDEWEB)

    Gonzalez, E.J.; Piermarini, G.; Hockey, B.; Malghan, S.G. [National Inst. of Standard and Technology, Gaithersburg, MD (United States)

    1995-08-01

    The effects of pressure on the compaction and subsequent processing of nanosize {gamma} alumina powders were studied. A 3 mm diameter piston/cylinder die was used to compact the nanosize powders to pressures of 1 and 2.5 GPa. The green bodies were sintered at temperatures up to 1600{degrees}C. Results show that green body density can be increased by higher compaction pressures. It appears that as a result of the {gamma}-to-{alpha} transformation in alumina, higher green density does not necessarily produce a higher density sintered alumina body. The microstructures of the sintered bodies are described in terms of porosity and phase content.

  6. Porous alumina based ordered nanocomposite coating for wear resistance

    Science.gov (United States)

    Yadav, Arti; Muthukumar, M.; Bobji, M. S.

    2016-08-01

    Uniformly dispersed nanocomposite coating of aligned metallic nanowires in a matrix of amorphous alumina is fabricated by pulsed electrodeposition of copper into the pores of porous anodic alumina. Uniform deposition is obtained by controlling the geometry of the dendritic structure at the bottom of pores through stepwise voltage reduction followed by mild etching. The tribological behaviour of this nanocomposite coating is evaluated using a ball on flat reciprocating tribometer under the dry contact conditions. The nanocomposite coating has higher wear resistance compared to corresponding porous alumina coating. Wear resistant nanocomposite coating has wide applications especially in protecting the internal surfaces of aluminium internal combustion engines.

  7. Crystal structure determination by powder neutron diffraction at the spallation neutron source, ISIS

    International Nuclear Information System (INIS)

    The paper concerns the determination of crystal structure by powder neutron diffraction at the spallation neutron source, ISIS. The practicability of the technique is illustrated by a study of the crystal structure of ferric arsenate, FeAsO4. (U.K.)

  8. Proceedings of the specialists' meeting on physics and engineering of fission and spallation, 1988

    International Nuclear Information System (INIS)

    The meeting was held on Aug. 10 and Dec. 19, 1988. The proceedings carry a total of 13 reports concerning the physics and engineerings of fission and spallation. The first and second reports, entitled 'IAEA Consultant's Meeting on the Physics of Neutron Emission in Fission (I) and (II)', respectively, give brief comments on major topics discussed in the meeting, recently obtained information, and issues of physical interest in the field of fission and spallation. The other 11 reports are entitled 'A Study on Mass Division in Low-Energy Nuclear Fission', 'Recent Topics on The Nuclear Fission Accompanied with High Spin', 'Nuclear Spallation Engineering and Strong Neutron Source', 'Nuclear Spallation by Gamma-Rays', 'Comment: Photopion Reaction and Photospallation', 'Report on the International Meeting on Physics and Chemistry of Nuclear Fission in Commemoration of the 50th Anniversary of the Discovery of Nuclear Fission', 'Charge Distribution and Neutron Systematics in Heavy-Ion Fission', 'High-Energy Gamma-Rays from Fission of 252Cf', 'Behavior of FP in Chromatographic Separation', 'Formation of Neutron by Light Ion', and 'Annihilation Treatment and Annihilation Furnace Equipped with Proton Accelerator'. (N.K.)

  9. Decay heat calculations for a 500 kW W-Ta spallation target

    Science.gov (United States)

    Yu, Quanzhi; Lu, Youlian; Hu, Zhiliang; Zhou, Bin; Yin, Wen; Liang, Tianjiao

    2015-05-01

    The China Spallation Neutron Source (CSNS) is a short-pulsed neutron scattering facility. The beam power is designed to be 100 kW in Phase I, with the capability of upgrading to 500 kW. Tantalum (Ta)-cladded tungsten (W) was chosen as the spallation target due to its high neutron yield. Ta claddings can solve the problem of the corrosiveness of W plates, although they produce high decay heat after intense irradiation. This paper presents the decay heat distributions and evolutions for the future upgraded 500 kW W-Ta spallation target. The calculations are performed using the MCNPX2.5 Monte Carlo code and the CINDER'90 activation code. The decay heat distributions show that for the W plates, decay heat is mainly produced via the spallation reaction process, whereas for the Ta claddings, it is mainly produced via the neutron capture process. An effective method of reducing the decay heat in the W-Ta target is also presented and discussed.

  10. Migration of radionuclides in a gas cooled solid state spallation target

    DEFF Research Database (Denmark)

    Jørgensen, Thomas; Severin, Gregory; Jensen, Mikael

    2015-01-01

    The current design of the ESS (European Spallation Source) program proposes a rotating solid tungsten target cooled by helium gas and a pulsed beam of protons. For safety reasons any design has to address whether or not the induced radionuclidic isotopes in the target migrate. In this paper we ha...

  11. Final environmental impact statement, construction and operation of the Spallation Neutron Source. Volume 1

    International Nuclear Information System (INIS)

    DOE proposes to construct and operate a state-of-the-art, short-pulsed, spallation neutron source comprised of an ion source, a linear accelerator, a proton accumulator ring, and an experiment building containing a liquid mercury target and a suite of neutron scattering instrumentation. The proposed Spallation neutron Source would be designed to operate at a proton beam power of 1 megawatt. The design would accommodate future upgrades to a peak operating power of 4 megawatts. These upgrades may include construction of a second proton accumulator ring and a second target. This document analyzes the potential environmental impacts from the proposed action and the alternatives. The analysis assumes a facility operating at a power of 1 MW and 4 MW over the life of the facility. The two primary alternatives analyzed in this FEIS are: the proposed action (to proceed with building the Spallation Neutron Source) and the No-Action Alternative. The No-Action Alternative describes the expected condition of the environment if no action were taken. Four siting alternatives for the Spallation Neutron Source are evaluated: Oak Ridge National Laboratory, Oak Ridge, TN, (preferred alternative); Argonne National Laboratory, Argonne, IL; Brookhaven National Laboratory, Upton, NY; and Los Alamos National Laboratory, Los Alamos, NM

  12. Final environmental impact statement, construction and operation of the Spallation Neutron Source Facility. Summary

    International Nuclear Information System (INIS)

    DOE proposes to construct and operate a state-of-the-art, short-pulsed, spallation neutron source comprised of an ion source, a linear accelerator, a proton accumulator ring, and an experiment building containing a liquid mercury target and a suite of neutron scattering instrumentation. The proposed Spallation Neutron Source would be designed to operate at a proton beam power of 1 megawatt. The design would accommodate future upgrades to a peak operating power of 4 megawatts. These upgrades may include construction of a second proton accumulator ring and a second target. This document analyzes the potential environmental impacts from the proposed action and the alternatives. The analysis assumes a facility operating at a power of 1 MW and 4 MW over the life of the facility. The two primary alternatives analyzed in this FEIS are: the proposed action (to proceed with building the Spallation Neutron Source) and the No-Action Alternative. The No-Action Alternative describes the expected condition of the environment if no action were taken. Four siting alternatives for the Spallation Neutron Source are evaluated: Oak Ridge National Laboratory, Oak Ridge, TN, (preferred alternative); Argonne National Laboratory, Argonne, IL; Brookhaven National Laboratory, Upton, NY; and Los Alamos National Laboratory, Los Alamos, NM

  13. BEAM-LOSS DRIVEN DESIGN OPTIMIZATION FOR THE SPALLATION NEUTRON SOURCE (SNS) RING.

    Energy Technology Data Exchange (ETDEWEB)

    WEI,J.; BEEBE-WANG,J.; BLASKIEWICZ,M.; CAMERON,P.; DANBY,G.; GARDNER,C.J.; JACKSON,J.; LEE,Y.Y.; LUDEWIG,H.; MALITSKY,N.; RAPARIA,D.; TSOUPAS,N.; WENG,W.T.; ZHANG,S.Y.

    1999-03-29

    This paper summarizes three-stage design optimization for the Spallation Neutron Source (SNS) ring: linear machine design (lattice, aperture, injection, magnet field errors and misalignment), beam core manipulation (painting, space charge, instabilities, RF requirements), and beam halo consideration (collimation, envelope variation, e-p issues etc.).

  14. Study on target spallation reaction cross sections induced by high energy neutrons and heavy ions

    Energy Technology Data Exchange (ETDEWEB)

    Nakamura, Takashi [Tohoku Univ., Sendai (Japan). Cyclotron and Radioisotope Center

    1996-03-01

    The target spallation reaction cross sections of neutrons and heavy ions which have not been observed are determined in this paper. The object of this work is to make clear the differences between the spallation reaction cross section of neutron and that of proton by comparing the obtained value of neutron with the known value of proton. To this end, the quasi monochromatic neutron field of 20{approx}50 MeV was developed in 4 cyclotrons, INS, CYRIC, TIARA and RIKEN. The nuclear spallation reaction cross sections of C, Al and Bi were measured in the above field and the distribution of nuclear spallation reaction products in Cu determined by C ion beam of HIMAC. {sup 12}C(n,2n){sup 11}C reaction cross section shows the maximum value of about 20 mb at near 40{approx}50 MeV and then the value gradually decreased to 10 mb. The cross sections of {sup 209}Bi(n,Xn) are shown. The distribution of {sup 61}Cu is lower at the entrance and higher in the depth. (S.Y.)

  15. Decay heat calculations for a 500 kW W–Ta spallation target

    Energy Technology Data Exchange (ETDEWEB)

    Yu, Quanzhi, E-mail: qzhyu@iphy.ac.cn [Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China); Lu, Youlian; Hu, Zhiliang; Zhou, Bin [Dongguan Campus, Institute of High Energy Physics, Chinese Academy of Sciences, Dongguan 523800 (China); Dongguan Neutron Science Center, Dongguan 523800 (China); Yin, Wen; Liang, Tianjiao [Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China)

    2015-05-15

    The China Spallation Neutron Source (CSNS) is a short-pulsed neutron scattering facility. The beam power is designed to be 100 kW in Phase I, with the capability of upgrading to 500 kW. Tantalum (Ta)-cladded tungsten (W) was chosen as the spallation target due to its high neutron yield. Ta claddings can solve the problem of the corrosiveness of W plates, although they produce high decay heat after intense irradiation. This paper presents the decay heat distributions and evolutions for the future upgraded 500 kW W–Ta spallation target. The calculations are performed using the MCNPX2.5 Monte Carlo code and the CINDER’90 activation code. The decay heat distributions show that for the W plates, decay heat is mainly produced via the spallation reaction process, whereas for the Ta claddings, it is mainly produced via the neutron capture process. An effective method of reducing the decay heat in the W–Ta target is also presented and discussed.

  16. Enriched vs non-enriched vs non-fissile targets for pulsed spallation neutron sources

    International Nuclear Information System (INIS)

    Numerous options exist among alternatives for target material and design of the neutron producing target in pulsed spallation neutron sources. This report surveys the advantages, disadvantages and limitations of some of the alternatives, including discussions of neutron yields, delayed neutron backgrounds, source pulse widths, source-to-moderator coupling, materials performance, fabrication problems, safeguards and security and hazards questions. (author)

  17. Characterization of Glasses in One Type of Alumina Rich Fly Ash by Chemical Digestion Methods: Implications for Alumina Extraction

    Directory of Open Access Journals (Sweden)

    Lijun Zhao

    2016-01-01

    Full Text Available In recent years, one type of alumina rich fly ash (ARFA with about 50 wt% of alumina has been extensively investigated for alumina extraction in China. Due to the silica in ARFA, alumina extraction would have to generate a huge amount of solid waste. There is a growing interest in the glasses in ARFA, because they are composed mainly of silica and could be removed prior to alumina extraction. In this work, the glasses in ARFA have been investigated by chemical methods, that is, acid and base digestions. The chemical compositions have been measured by XRF for ARFA from the digestion processes. The K2O standard, XRD, and FTIR spectroscopies were successfully used to define the digestions processes, and size analysis and SEM-EDX provided rich information on particle transformations. As a result, acid and base digestion methods were found to produce very similar results for the glasses in ARFA. The K2O standard was attributed to the formation of glasses by illites, and TiO2 and Fe2O3 were proposed to originate from ilmenite in alumina rich coals (ARC. Some implications of the results were also discussed for the alumina extraction from ARFA.

  18. Anodisation with dynamic current control for tailored alumina coatings

    Science.gov (United States)

    Sieber, M.; Althöfer, I.; Höhlich, D.; Scharf, I.; Böttger, D.; Böttger, S.; Böttger, E.; Lampke, T.

    2016-03-01

    The anodic oxidation process is commonly used to refine the surface of aluminium and its alloys. Compared to the substrate, the alumina layers produced by anodising exhibit an increased hardness and chemical resistance. Thus, the corrosion and wear resistance are generally improved. The coatings are also electrically isolating and may serve decorative purposes. Applying a time-variant, dynamic electrical process control by pulse-current or current-steps is a promising approach to improve the coating properties, which is partially deployed in an industrial scale. In the present work, the influence of dynamic electrical process control on the coating properties is examined by means of a design of experiments (DOE). The effects of various electrolyte compositions and temperatures as well as processing time are considered with regard to coating thickness, hardness, wear resistance and the electrical energy consumption during the formation of the coatings. Information about the statistical significance of the effects of the parameters on the considered properties is obtained by an analysis of variance (ANOVA).

  19. Direct spray pyrolysis of aluminum chloride solution for alumina preparation

    Institute of Scientific and Technical Information of China (English)

    吕国志; 张廷安; 王龙; 马思达; 豆志河; 刘燕

    2014-01-01

    The effects of pyrolysis mode and pyrolysis parameters on Cl content in alumina were investigated, and the alumina products were characterized by XRD, SEM and ASAP. The experimental results indicate that the spray pyrolysis efficiency is higher than that of static pyrolysis process, and the reaction and evaporation process lead to a multi-plot state of the alumina products by spray pyrolysis. Aluminum phase starts to transform intoγ-Al2O3 at spray pyrolysis temperature of 600 °C, which is about 200 °C lower than that of static pyrolysis process. The primary particle size of γ-Al2O3 product is 27.62 nm, and Cl content in alumina products is 0.38%at 800 °C for 20 min.

  20. High Alumina Refractory Mortars GB/T 2994-2008

    Institute of Scientific and Technical Information of China (English)

    Wang Jing; Chai Junlan

    2009-01-01

    @@ 1 Scope This standard specifies the classification, techni-cal requirements, test methods, quality appraisal pro-cedure, packing, marking, transportation, storage and quality certificate of high alumina refractory mortars.

  1. High Alumina Refractory Bricks for Electric Arc Furnace Roofs

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    @@ 1 Scope This standard specifies the sort, technical requirement, test method, inspection rules, marking, packing, transportation, storage and quality certification of high alumina refractory bricks for electric arc furnace roofs.

  2. Removing Fluoride Ions with Continously Fed Activated Alumina.

    Science.gov (United States)

    Wu, Yeun C.; Itemaking, Isara Cholapranee

    1979-01-01

    Discussed is the mathematical basis for determining fluoride removal during water treatment with activated alumina. The study indicates that decreasing particle size decreases the pore diffusion effect and increases fluoride removal. (AS)

  3. Fused Cast Alumina Refractory Products for Glass Tank Furnace

    Institute of Scientific and Technical Information of China (English)

    SHEN Keyin

    2006-01-01

    @@ 1 Subject and Scope The standard specifies the requirement, testing method, inspection rule and requirements for the labeling, packing, shipping and storing of the fused cast alumina refractory products for glass tanks.

  4. Spallation Neutron Spectrum on a Massive Lead/Paraffin Target Irradiated with 1 GeV Protons

    CERN Document Server

    Adam, J; Barashenkov, V S; Brandt, R; Golovatiouk, V M; Kalinnikov, V G; Katovsky, K; Krivopustov, M I; Kumar, V; Kumawat, H; Odoj, R; Pronskikh, V S; Solnyshkin, A A; Stegailov, V I; Tsoupko-Sitnikov, V M; Westmeier, W

    2004-01-01

    The spectra of gamma-ray emitted by decaying residual nuclei, produced by spallation neutrons with (n, xn), (n,xnyp), (n,p), (n,gamma) reactions in activation threshold detectors - namely, ^{209}Bi, ^{197}Au, ^{59}Co, ^{115}In, ^{232}Th, were measured in the Laboratory of Nuclear Problems (LNP), JINR, Dubna, Russia. Spallation neutrons were generated by bombarding a 20 cm long cylindrical lead target, 8 cm in diameter, surrounded by a 6 cm thick layer of paraffin moderator, with a 1 GeV proton beam from the Nuclotron accelerator. Reaction rates and spallation neutron spectrum were measured and compared with CASCADE code calculations.

  5. Mechanisms of spallation of electron beam physical vapor deposited thermal barrier coatings with and without platinum aluminide bond coat ridges

    Energy Technology Data Exchange (ETDEWEB)

    Vaidyanathan, K.; Gell, M. [Connecticut Univ., Storrs, CT (United States). Dept. of Metallurgy; Jordan, E. [Dept. Mechanical Engineering, University of Connecticut, CT-06269, Storrs (United States)

    2000-11-01

    Grain boundary ridges, that form on the surface of platinum aluminide [(Ni,Pt)Al] bond coats prior to the deposition of the yttria stabilized zirconia ceramic layer by the electron beam physical vapor deposition (EB-PVD) process, were shown to be the sites for spallation damage initiation in (Ni,Pt)Al/EB-PVD thermal barrier coatings. When these ridges are removed prior to deposition of the ceramic layer, a 3 x life improvement is achieved. This study compares the spallation mechanisms in specimens with and without bond coat ridges, in order to explain the improvement in spallation life. (orig.)

  6. Measurement of nuclide cross-sections of spallation residues in 1 A GeV 238U + proton collisions

    International Nuclear Information System (INIS)

    The production of heavy nuclides from the spallation-evaporation reaction of 238U induced by 1 GeV protons was studied in inverse kinematics. The evaporation residues from tungsten to uranium were identified in-flight in mass and atomic number. Their production cross-sections and their momentum distributions were determined. The data are compared with empirical systematics. A comparison with previous results from the spallation of 208Pb and 197Au reveals the strong influence of fission in the spallation of 238U. (orig.)

  7. Study of particle transport in a high power spallation target for an accelerator-driven transmutation system

    Energy Technology Data Exchange (ETDEWEB)

    Shetty, Nikhil Vittal

    2013-01-31

    AGATE is a project envisaged to demonstrate the feasibility of transmutation in a gas (helium) cooled accelerator-driven system using solid spallation target. Development of the spallation target module and assessing its safety aspects are studied in this work. According to the AGATE concept parameters, 600 MeV protons are delivered on to the segmented tungsten spallation target. The Monte Carlo toolkit Geant4 has been used in the simulation of particle transport. Binary cascade is used to simulate intra-nuclear cascades, along with the G4NDL neutron data library for low energy neutrons (<20 MeV).

  8. Study of particle transport in a high power spallation target for an accelerator-driven transmutation system

    International Nuclear Information System (INIS)

    AGATE is a project envisaged to demonstrate the feasibility of transmutation in a gas (helium) cooled accelerator-driven system using solid spallation target. Development of the spallation target module and assessing its safety aspects are studied in this work. According to the AGATE concept parameters, 600 MeV protons are delivered on to the segmented tungsten spallation target. The Monte Carlo toolkit Geant4 has been used in the simulation of particle transport. Binary cascade is used to simulate intra-nuclear cascades, along with the G4NDL neutron data library for low energy neutrons (<20 MeV).

  9. Adsorption of textile dye onto modified immobilized activated alumina

    OpenAIRE

    Wasti, A.; Ali, Awan M.

    2015-01-01

    The study describes the synthesis of modified immobilized activated alumina (MIAA) and its application for the removal of textile dye from aqueous media. Immobilization was carried out by using the sol–gel method while modifications were made during the synthesis by adding powder activated alumina. Batch adsorption experiments were carried out at 20 ± 1 °C to see the effect of different parameters like contact time, stirring rate, initial concentration of the dye and dose of MIAA. The removal...

  10. Recent advances in silica-alumina refractory: A review

    Directory of Open Access Journals (Sweden)

    Chaouki Sadik

    2014-06-01

    Full Text Available In this article, the elaboration and the characterization of silica-alumina refractory have been reviewed. Refractory oxides encompass a broad range of unary, binary, and ternary ceramic compounds that can be used in structural, insulating, and other applications. This paper provides a historical perspective on the elaboration and the use of silica-alumina refractory, reviews applications for refractory oxides, describes typical processing routes, overviews fundamental structure–property relations, and summarizes the properties of these materials.

  11. The Neutron Science TeraGrid Gateway, a TeraGrid Science Gateway to Support the Spallation Neutron Source

    Energy Technology Data Exchange (ETDEWEB)

    Cobb, John W [ORNL; Geist, Al [ORNL; Kohl, James Arthur [ORNL; Miller, Stephen D [ORNL; Peterson, Peter F [ORNL; Pike, Gregory [ORNL; Reuter, Michael A [ORNL; Swain, William [ORNL; Vazhkudai, Sudharshan S [ORNL; Vijayakumar, Nithya N [ORNL

    2006-01-01

    The National Science Foundation's (NSF's) Extensible Terascale Facility (ETF), or TeraGrid [1] is entering its operational phase. An ETF science gateway effort is the Neutron Science TeraGrid Gateway (NSTG.) The Oak Ridge National Laboratory (ORNL) resource provider effort (ORNL-RP) during construction and now in operations is bridging a large scale experimental community and the TeraGrid as a large-scale national cyberinfrastructure. Of particular emphasis is collaboration with the Spallation Neutron Source (SNS) at ORNL. The U.S. Department of Energy's (DOE's) SNS [2] at ORNL will be commissioned in spring of 2006 as the world's brightest source of neutrons. Neutron science users can run experiments, generate datasets, perform data reduction, analysis, visualize results; collaborate with remotes users; and archive long term data in repositories with curation services. The ORNL-RP and the SNS data analysis group have spent 18 months developing and exploring user requirements, including the creation of prototypical services such as facility portal, data, and application execution services. We describe results from these efforts and discuss implications for science gateway creation. Finally, we show incorporation into implementation planning for the NSTG and SNS architectures. The plan is for a primarily portal-based user interaction supported by a service oriented architecture for functional implementation.

  12. The Neutron Science TeraGrid Gateway, a TeraGrid Science Gateway to Support the Spallation Neutron Source

    International Nuclear Information System (INIS)

    The National Science Foundation's (NSF's) Extensible Terascale Facility (ETF), or TeraGrid (1) is entering its operational phase. An ETF science gateway effort is the Neutron Science TeraGrid Gateway (NSTG.) The Oak Ridge National Laboratory (ORNL) resource provider effort (ORNL-RP) during construction and now in operations is bridging a large scale experimental community and the TeraGrid as a large-scale national cyberinfrastructure. Of particular emphasis is collaboration with the Spallation Neutron Source (SNS) at ORNL. The U.S. Department of Energy's (DOE's) SNS (2) at ORNL will be commissioned in spring of 2006 as the world's brightest source of neutrons. Neutron science users can run experiments, generate datasets, perform data reduction, analysis, visualize results; collaborate with remotes users; and archive long term data in repositories with curation services. The ORNL-RP and the SNS data analysis group have spent 18 months developing and exploring user requirements, including the creation of prototypical services such as facility portal, data, and application execution services. We describe results from these efforts and discuss implications for science gateway creation. Finally, we show incorporation into implementation planning for the NSTG and SNS architectures. The plan is for a primarily portal-based user interaction supported by a service oriented architecture for functional implementation

  13. Antibacterial activity of zinc oxide-coated nanoporous alumina

    Energy Technology Data Exchange (ETDEWEB)

    Skoog, S.A. [Joint Department of Biomedical Engineering, University of North Carolina and North Carolina State University, Box 7115, Raleigh, NC 27695-7115 (United States); Bayati, M.R. [Department of Materials Science and Engineering, North Carolina State University, Box 7907, Raleigh, NC 27695-7907 (United States); Petrochenko, P.E. [Joint Department of Biomedical Engineering, University of North Carolina and North Carolina State University, Box 7115, Raleigh, NC 27695-7115 (United States); Division of Biology, Office of Science and Engineering Laboratories, Center for Devices and Radiological Health, U.S. Food and Drug Administration, Silver Spring, MD 20993 (United States); Stafslien, S.; Daniels, J.; Cilz, N. [Center for Nanoscale Science and Engineering, North Dakota State University, 1805 Research Park Drive, Fargo, ND 58102 (United States); Comstock, D.J.; Elam, J.W. [Energy Systems Division, Argonne National Laboratory, Argonne, IL 60439 (United States); Narayan, R.J., E-mail: roger_narayan@msn.com [Joint Department of Biomedical Engineering, University of North Carolina and North Carolina State University, Box 7115, Raleigh, NC 27695-7115 (United States); Department of Materials Science and Engineering, North Carolina State University, Box 7907, Raleigh, NC 27695-7907 (United States)

    2012-07-25

    Highlights: Black-Right-Pointing-Pointer Atomic layer deposition was used to deposit ZnO on nanoporous alumina membranes. Black-Right-Pointing-Pointer Scanning electron microscopy showed continuous coatings of zinc oxide nanocrystals. Black-Right-Pointing-Pointer Activity against B. subtilis, E. coli, S. aureus, and S. epidermidis was shown. - Abstract: Nanoporous alumina membranes, also known as anodized aluminum oxide membranes, are being investigated for use in treatment of burn injuries and other skin wounds. In this study, atomic layer deposition was used for coating the surfaces of nanoporous alumina membranes with zinc oxide. Agar diffusion assays were used to show activity of zinc oxide-coated nanoporous alumina membranes against several bacteria found on the skin surface, including Bacillus subtilis, Escherichia coli, Staphylococcus aureus, and Staphylococcus epidermidis. On the other hand, zinc oxide-coated nanoporous alumina membranes did not show activity against Pseudomonas aeruginosa, Enterococcus faecalis, and Candida albicans. These results suggest that zinc oxide-coated nanoporous alumina membranes have activity against some Gram-positive and Gram-negative bacteria that are associated with skin colonization and skin infection.

  14. Preparation of spherical hollow alumina particles by thermal plasma

    International Nuclear Information System (INIS)

    Spherical hollow particles were prepared from solid alumina powders using DC arc thermal plasma, and then spray coating was performed with the as-prepared particles. Operating variables for the hollow particle preparation process were additional plasma gas, input power, and carrier gas flow rate. The spherical hollow alumina particles were produced in the case of using additive gas of H2 or N2, while alumina surface was hardly molten in the pure argon thermal plasma. In addition, the hollow particles were well produced in high power and low carrier gas conditions due to high melting point of alumina. Hollow structure was confirmed by focused ion beam-scanning electron microscopy analysis. Morphology and size distribution of the prepared particles that were examined by field emission-scanning electron microscopy and phase composition of the particles was characterized by X-ray diffraction. In the spray coating process, the as-prepared hollow particles showed higher deposition rate. - Highlights: ► Spherical hollow alumina powder was prepared by non-transferred DC arc plasma. ► Diatomic gasses were added in Ar plasma for high power. ► Prepared hollow alumina powder was efficient for the plasma spray coating

  15. High toughness alumina ceramics with elongated grains developed from seeds

    Institute of Scientific and Technical Information of China (English)

    XIE; Zhipeng; (谢志鹏); GAO; Lichun; (高立春); LI; Wenchao; (李文超); XU; Lihua; (徐利华); WANG; Xidong; (王习东)

    2003-01-01

    In the present paper, the influence of α-Al2O3 seeds and sintering methods on elongated grain growth and fracture toughness is investigated. The preparation of alumina ceramics started with commercial aluminum hydroxide. Abrasives were introduced to the starting materials by wet-grinding of high-purity alumina milling balls. Abrasives, playing the role of seeds, lowered the transformation temperature of aluminum hydroxide to alumina. Microstructures with elongated grains were developed by hot-pressing for the above calcined powders containing α-Al2O3 seeds, and alumina grain shapes changed with the amount of seeds introduced. However, only equiaxed grains were observed for the samples pressureless sintered. Fracture toughness of the alumina ceramics was dramatically improved by elongated grains. For the sample hot-pressed at 1600℃ for 2 h under 40 MPa pressure, fracture toughness reached 7.1 MPa·m1/2, which is much higher than that of normal alumina ceramics without elongated grains. In addition, high flexural strength of 630 MPa for the hot-pressed samples was also obtained.

  16. Procoagulant behavior and platelet microparticle generation on nanoporous alumina.

    Science.gov (United States)

    Ferraz, Natalia; Hong, Jaan; Karlsson Ott, Marjam

    2010-05-01

    In the present work, we have investigated platelet microparticle (PMP) generation in whole blood after contact with nanoporous alumina. Alumina membranes with pore sizes of 20 and 200 nm in diameter were incubated with whole blood and the number of PMP in the fluid phase was determined by flow cytometry. The role of the complement system in PMP generation was investigated using an analog of the potent complement inhibitor compstatin. Moreover, the procoagulant activity of the two pore size membranes were compared by measuring thrombin formation. Results indicated that PMP were not present in the fluid phase after whole blood contact with either of the alumina membranes. However, scanning electron microscope micrographs clearly showed the presence of PMP clusters on the 200 nm pore size alumina, while PMP were practically absent on the 20 nm membrane. We probed no influence of complement activation in PMP generation and adhesion and we hypothesize that other specific material-related protein-platelet interactions are taking place. A clear difference in procoagulant activity between the membranes could also be seen, 20 nm alumina showed 100% higher procoagulant activity than 200 nm membrane. By combining surface evaluation and flow cytometry analyses of the fluid phase, we are able to conclude that 200 nm pore size alumina promotes PMP generation and adhesion while the 20 nm membrane does not appreciably cause any release or adhesion of PMP, thus indicating a direct connection between PMP generation and nanoporosity.

  17. Adsorption of itaconic acid from aqueous solutions onto alumina

    Directory of Open Access Journals (Sweden)

    JELENA J. GULICOVSKI

    2008-08-01

    Full Text Available Itaconic acid, IA (C5H6O4, was investigated as a potential flocculant for the aqueous processing of alumina powders. The adsorption of IA, as a function of its concentration and pH value of the solution, onto the alumina surface was studied by the solution depletion method. The stability of the suspensions in the presence of itaconic acid was evaluated in light of the surface charge of the alumina powder used, the degree of dissociation of IA, as well as the sedimentation behavior and rheology of the suspensions. It was found that the adsorption process is extremely pH dependent; the maximum adsorption of IA onto alumina surface occurring at a pH close to the value of the first IA dissociation constant, pKa1. Also, IA does not influence the value of the point of zero charge of alumina. It was shown that IA represents an efficient flocculant for concentrated acidic alumina suspensions.

  18. Antibacterial activity of zinc oxide-coated nanoporous alumina

    International Nuclear Information System (INIS)

    Highlights: ► Atomic layer deposition was used to deposit ZnO on nanoporous alumina membranes. ► Scanning electron microscopy showed continuous coatings of zinc oxide nanocrystals. ► Activity against B. subtilis, E. coli, S. aureus, and S. epidermidis was shown. - Abstract: Nanoporous alumina membranes, also known as anodized aluminum oxide membranes, are being investigated for use in treatment of burn injuries and other skin wounds. In this study, atomic layer deposition was used for coating the surfaces of nanoporous alumina membranes with zinc oxide. Agar diffusion assays were used to show activity of zinc oxide-coated nanoporous alumina membranes against several bacteria found on the skin surface, including Bacillus subtilis, Escherichia coli, Staphylococcus aureus, and Staphylococcus epidermidis. On the other hand, zinc oxide-coated nanoporous alumina membranes did not show activity against Pseudomonas aeruginosa, Enterococcus faecalis, and Candida albicans. These results suggest that zinc oxide-coated nanoporous alumina membranes have activity against some Gram-positive and Gram-negative bacteria that are associated with skin colonization and skin infection.

  19. Experimental measurement of surface temperatures during flame-jet induced thermal spallation

    Science.gov (United States)

    Wilkinson, M. A.; Tester, J. W.

    1993-01-01

    Thermal spallation is a method whereby the surface of a rock is rapidly heated causing small (100 1000 μm) flakes or spalls, to form. When applied to drilling, a supersonic, high temperature (2600 K) gas jet is directed at the rock to provide the heat source and sweep away the spalls. Previous studies of thermal spallation drilling indicate that penetration rates of up to 30 m/hr (100 ft/hr), approximately ten times greater than commonly obtained using conventional rotary mechanical methods, can be achieved in competent, non-fractured hard rock such as granite. A total direct operating cost for drilling in granite using a flame-jet spallation drill was estimated by Browning (1981) to be approximately 9/m in 1991 (about 3/ft) compared to “trouble-free” well drilling costs for conventional rotary methods in similar rock to depths of 3 to 7 km (10000 to 21000 ft) of 300 to 900/m (100 to 300/ft) (Tester and Herzog, 1990, 1992). The Browning estimates for spallation drilling are obviously optimistic in that they don't include capital costs for the rig and associated hardware. However, the substantially higher penetration rates, significantly reduced wear of downhole components, and the high efficiency of rock communition in comparison to rotary methods suggest that substantial cost reductions could be possible in deep drilling applications. For example, in the construction of hot dry rock geothermal power plants where rotary mechanical methods are used for well drilling to depths of (4 to 5 km), about half of the initial capital cost would be required for well drilling alone (Tester and Herzog, 1992). The current study has focused on gaining a better understanding of both the rock failure mechanism that occurs during thermal spallation and the heat transfer from the gas jet to the rock surface. Rock mechanics modeling leads to an expression for the surface temperature during spallation as a function of rock physical properties and the incident heat flux. Surface

  20. Annealing Would Improve beta" - Alumina Solid Electrolyte

    Science.gov (United States)

    Williams, Roger; Homer, Margie; Ryan, Margaret; Cortez, Roger; Shields, Virgil; Kisor, Adam

    2003-01-01

    A pre-operational annealing process is under investigation as a potential means of preventing a sudden reduction of ionic conductivity in a Beta"-alumina solid electrolyte (BASE) during use. On the basis of tests, the sudden reduction of ionic conductivity, followed by a slow recovery, has been found to occur during testing of the solid electrolyte and electrode components of an alkali metal thermal-to-electric converter (AMTEC) cell. At this time, high-temperature tests of limited duration have indicated the superiority of the treated BASE, but reproducible tests over thousands of hours are necessary to confirm that microcracking has been eliminated. The ionic conductivity of the treated BASE is also measured to be higher than untreated BASE at 1,073 K in low-pressure sodium vapor. Microcracking resulting in loss of conductivity was not observed with treated BASE in one high-temperature experiment, but this result must be duplicated over very long testing times to be sure of the effect. Shorter annealing times (10 to 20 hours) were found to result in significantly less loss of mass; it may be necessary for the packed powder mixture to evolve some Na2O before the Na2O can leave the ceramic.

  1. Nanoparticle assisted coagulation of aqueous alumina suspensions

    Directory of Open Access Journals (Sweden)

    Abdullah Fatih Çetinel

    2012-02-01

    Full Text Available Colloidal processing of ceramics offers a high potential to achieve homogeneous microstructures with improved material properties. In this study, a novel forming method is investigated, which was already applied successfully for the fabrication of ceramic matrix composites (CMC, but is also considered to be a suitable direct casting technique for the fabrication of advanced ceramics with tailored microstructure and properties. The so-called nanoparticle assisted coagulation method (NPAC represents a modification of the hydrolysis-assisted solidification (HAS technique. It promises green components with high green strength, uniform density as well as homogeneous and tailored microstructure. Electrostatically stabilized colloidal suspensions with high solid loadings were produced by dispersing various fractions of submicron alumina powder and aluminium hydroxide nano-powder in water without use of any organic binder. Rheology and coagulation kinetics of suspensions and green part properties were studied regarding to modifications of pH value, setting temperature, amount of setting agent, amount of nano-powder, solids loading and process parameters like ultrasound treatment. It could be revealed that the homogeneous core-shell arrangement of submicron and nanoparticles in the colloidal state can be transmitted to the green state, which improves the microstructure and green density of the green parts. For this, the NPAC method is seen as a promising technique for the fabrication of advanced ceramics with tailored microstructure and properties.

  2. Thermal Conductivity of Alumina and Silica Nanofluids

    Science.gov (United States)

    Castellanos, Julian G. Bernal

    This thesis studies the effects of the base fluid, particle type/size, and volumetric concentration on the thermal conductivity of Alumina and Silica nanofluids. The effects of base fluid were observed by preparing samples using ethylene glycol (EG), water, and mixtures of EG/water as the base fluid and Al2O3 (10 nm) nanoparticles. The particles type/size and volumetric concentration effects were tested by preparing samples of nanofluids using Al2O3 (10nm), Al2O3 (150nm), SiO2 (15 nm), and SiO2 (80 nm) nanoparticles and ionized water as base fluid at different volumetric concentrations. All samples were mixed using a sonicator for 30 minutes and a water circulator to maintain the sample at room temperature. The thermal conductivity was measured using a Thermtest Transient Plane Source TPS 500S. The effects of gravity, Brownian motion and thermophoresis were also studied. EG produced the highest thermal conductivity enhancement out of all base fluids tested. Smaller particle size produced a higher enhancement of thermal conductivity, while the volumetric concentration did not have a significant effect in the thermal conductivity enhancement. Finally, gravity, Brownian diffusion and thermophoresis effects played a role in the total enhancement of the thermal conductivity. The nanoparticles were observed to settle rapidly after sonication suggesting gravity effects may play a significant role.

  3. Experimental and numerical investigation of liquid-metal free-surface flows in spallation targets

    International Nuclear Information System (INIS)

    Highlights: • Experimental study of free surface for lead bismuth eutectic target. • Numerical investigation of free surface of a liquid metal target. • Advanced free surface modelling. - Abstract: Accelerator Driven Systems (ADS) are extensively investigated for the transmutation of high-level nuclear waste within many worldwide research programs. The first advanced design of an ADS system is currently developed in SCK• CEN, Mol, Belgium: the Multi-purpose hYbrid Research Reactor for High-tech Applications (MYRRHA). Many European research programs support the design of MYRRHA. In the framework of the Euratom project ‘Thermal Hydraulics of Innovative nuclear Systems (THINS)’ a liquid-metal free-surface experiment is performed at the Karlsruhe Liquid Metal Laboratory (KALLA) of Karlsruhe Institute of Technology (KIT). The experiment investigates a full-scale model of the concentric free-surface spallation target of MYRRHA using Lead Bismuth Eutectic (LBE) as coolant. In parallel, numerical free surface models are developed and tested which are reviewed in the article. A volume-of-fluid method, a moving mesh model, a free surface model combining the Level-Set method with Large-Eddy Simulation model and a smoothed-particle hydrodynamics approach are investigated. Verification of the tested models is based on the experimental results obtained within the THINS project and on previous water experiments performed at the University Catholic de Louvain (UCL) within the Euratom project ‘EUROpean Research Programme for the TRANSmutation of High Level Nuclear Waste in Accelerator Driven System (EUROTRANS)’. The design of the target enables a high fluid velocity and a stable surface at the beam entry. The purpose of this paper is to present an overview of both experimental and numerical results obtained for free surface target characterization. Without entering in technical details, the status, the major achievements and lessons for the future with respect to

  4. Experimental and numerical investigation of liquid-metal free-surface flows in spallation targets

    Energy Technology Data Exchange (ETDEWEB)

    Batta, A., E-mail: batta@kit.edu [Karlsruhe Institute of Technology, Germany Hermann-von-Helmholtz-PLATZ 1, 76344 Eggenstein-Leopoldshafen (Germany); Class, A.G.; Litfin, K.; Wetzel, Th. [Karlsruhe Institute of Technology, Germany Hermann-von-Helmholtz-PLATZ 1, 76344 Eggenstein-Leopoldshafen (Germany); Moreau, V.; Massidda, L. [CRS4 Centre for Advanced Studies, Research and Development in Sardinia, Polaris, Edificio 1, 09010 Pula, CA (Italy); Thomas, S.; Lakehal, D. [ASCOMP GmbH Zurich, Zurich (Switzerland); Angeli, D.; Losi, G. [DIEF – Department of Engineering “Enzo Ferrari”, University of Modena and Reggio Emilia, via Vignolese 905, 41125 Modena (Italy); Mooney, K.G. [University of Massachusetts Amherst, Department of Mechanical and Industrial Engineering, Amherst (United States); Van Tichelen, K. [SCK-CEN, Belgian Nuclear Research Centre, Boeretang 200, 2400 Mol (Belgium)

    2015-08-15

    Highlights: • Experimental study of free surface for lead bismuth eutectic target. • Numerical investigation of free surface of a liquid metal target. • Advanced free surface modelling. - Abstract: Accelerator Driven Systems (ADS) are extensively investigated for the transmutation of high-level nuclear waste within many worldwide research programs. The first advanced design of an ADS system is currently developed in SCK• CEN, Mol, Belgium: the Multi-purpose hYbrid Research Reactor for High-tech Applications (MYRRHA). Many European research programs support the design of MYRRHA. In the framework of the Euratom project ‘Thermal Hydraulics of Innovative nuclear Systems (THINS)’ a liquid-metal free-surface experiment is performed at the Karlsruhe Liquid Metal Laboratory (KALLA) of Karlsruhe Institute of Technology (KIT). The experiment investigates a full-scale model of the concentric free-surface spallation target of MYRRHA using Lead Bismuth Eutectic (LBE) as coolant. In parallel, numerical free surface models are developed and tested which are reviewed in the article. A volume-of-fluid method, a moving mesh model, a free surface model combining the Level-Set method with Large-Eddy Simulation model and a smoothed-particle hydrodynamics approach are investigated. Verification of the tested models is based on the experimental results obtained within the THINS project and on previous water experiments performed at the University Catholic de Louvain (UCL) within the Euratom project ‘EUROpean Research Programme for the TRANSmutation of High Level Nuclear Waste in Accelerator Driven System (EUROTRANS)’. The design of the target enables a high fluid velocity and a stable surface at the beam entry. The purpose of this paper is to present an overview of both experimental and numerical results obtained for free surface target characterization. Without entering in technical details, the status, the major achievements and lessons for the future with respect to

  5. Alumina-on-alumina total hip replacement for femoral neck fracture in healthy patients

    Directory of Open Access Journals (Sweden)

    Moretti Lorenzo

    2011-02-01

    Full Text Available Abstract Background Total hip replacement is considered the best option for treatment of displaced intracapsular fractures of the femoral neck (FFN. The size of the femoral head is an important factor that influences the outcome of a total hip arthroplasty (THA: implants with a 28 mm femoral head are more prone to dislocate than implants with a 32 mm head. Obviously, a large head coupled to a polyethylene inlay can lead to more wear, osteolysis and failure of the implant. Ceramic induces less friction and minimal wear even with larger heads. Methods A total of 35 THAs were performed for displaced intracapsular FFN, using a 32 mm alumina-alumina coupling. Results At a mean follow-up of 80 months, 33 have been clinically and radiologically reviewed. None of the implants needed revision for any reason, none of the cups were considered to have failed, no dislocations nor breakage of the ceramic components were recorded. One anatomic cementless stem was radiologically loose. Conclusions On the basis of our experience, we suggest that ceramic-on-ceramic coupling offers minimal friction and wear even with large heads.

  6. EFFECT OF SPINEL ADDITION ON THE SINTERING BEHAVIOR AND MICROSTRUCTURE OF ALUMINA-SPINEL CERAMICS

    OpenAIRE

    Emre Yalamac

    2014-01-01

    Sintering behaviors of alumina-spinel powder mixtures were investigated up to 1600oC using a vertical dilatometer. Final density and microstructure of pure alumina, magnesium aluminate spinel (MgAl2O4) ceramics and ceramic composites with different alumina-spinel ratio were examined. As a result, the densification and final density of alumina-spinel composites were affected by addition of 10 wt. % and 20 wt. % spinel into alumina. Non-stoichiometric alumina-rich spinel phase was d...

  7. Studies Performed in Preparation for the Spallation Neutron Source Accumulator Ring Commissioning

    CERN Document Server

    Cousineau, Sarah M; Henderson, Stuart; Holmes, Jeffrey Alan; Plum, Michael

    2005-01-01

    The Spallation Neutron Source accumulator ring will compress 1.5?1014, 1 GeV protons from a 1 ms bunch train to a single 695 ns proton bunch for use in neutron spallation. Due to the high beam power, unprecedented control of beam loss will be required in order to control radiation and allow for hands-on maintenance in most areas of the ring. A number of detailed investigations have been performed to understand the primary sources of beam loss and to predict and mitigate problems associated with radiation hot spots in the ring. The ORBIT particle tracking code is used to perform realistic simulations of the beam accumulation in the ring, including detailed modeling of the injection system, transport through the measured magnet fields including higher order multipoles, and beam loss and collimation. In this paper we present the results of a number of studies performed in preparation for the 2006 commissioning of the accumulator ring.

  8. Synthesis of neutron-rich transuranic nuclei in fissile spallation targets

    CERN Document Server

    Mishustin, Igor; Pshenichnov, Igor; Greiner, Walter

    2014-01-01

    A possibility of synthesizing neutron-reach super-heavy elements in spallation targets of Accelerator Driven Systems (ADS) is considered. A dedicated software called Nuclide Composition Dynamics (NuCoD) was developed to model the evolution of isotope composition in the targets during a long-time irradiation by intense proton and deuteron beams. Simulation results show that transuranic elements up to Bk-249 can be produced in multiple neutron capture reactions in macroscopic quantities. However, the neutron flux achievable in a spallation target is still insufficient to overcome the so-called fermium gap. Further optimization of the target design, in particular, by including moderating material and covering it by a reflector will turn ADS into an alternative source of transuranic elements in addition to nuclear fission reactors.

  9. Cost Optimisation of an Instrument Suite at an Accelerator-Driven Spallation Source

    CERN Document Server

    Bentley, P M

    2016-01-01

    This artcile presents an optimisation of performance and cost of neutron scattering instrumentation at the European Spallation Source. This is done by trading detailed cost functions against beam transmission functions in a multi-dimensional, yet simple, parameter space. On the one hand, the neutron guide cost increases as a power of the desired beam divergence, and inversely with the minimum wavelength, due to the supermirror coating needed. On the other hand, the more neutrons are transported to the instrument the greater are the shielding costs to deal with the gamma rays that result from the eventual absorption of the neutrons. There are additional factors in that many of the parameters defining the neutron guide geometry are continuous variables, and the straightness of the guide increases the transmission of high energy spallation products, which affect the specifications of particularly heavy hardware, such as heavy shutters and additional shielding, beam stops etc. Over the suite of 16 instruments, a ...

  10. THERMAL HYDRAULIC ANALYSIS OF A LIQUID-METAL-COOLED NEUTRON SPALLATION TARGET

    Energy Technology Data Exchange (ETDEWEB)

    W. GREGORY; R. MARTIN; T. VALACHOVIC

    2000-07-01

    We have carried out numerical simulations of the thermal hydraulic behavior of a neutron spallation target where liquid metal lead-bismuth serves as both coolant and as a neutron spallation source. The target is one of three designs provided by the Institute of Physics and Power Engineering (IPPE) in Russia. This type of target is proposed for Accelerator-driven Transmutation of Waste (ATW) to eliminate plutonium from hazardous fission products. The thermal hydraulic behavior was simulated by use of a commercial CFD computer code called CFX. Maximum temperatures in the diaphragm window and in the liquid lead were determined. In addition the total pressure drop through the target was predicted. The results of the CFX analysis were close to those results predicted by IPPE in their preliminary analysis.

  11. Measurement of the spallation reaction 56Fe+p in inverse kinematics

    International Nuclear Information System (INIS)

    In this work the spallation reaction 56Fe+p was investigated in inverse kinematics with regard to complete identification of the heavy residues. A ring imaging Cerenkov counter was used for velocity measurements in the experimental setup located at GSI in Darmstadt. A new fast readout electronic was developed and has been operated successfully in the experiment. Momentum reconstruction was carried out with the ALADiN spectrometer and a new software package written for this purpose. Cross sections and velocity distributions for more than 100 mass separated isotopes could be extracted from the dataset and compared with empirical models and other spallation experiments. The experiences gained in this experiment will be used for systematic improvements in the setup of the new spectrometer R3B at FAIR. (orig.)

  12. An apparatus for studying spallation neutrons in the Aberdeen Tunnel laboratory

    CERN Document Server

    Blyth, S C; Chen, X C; Chu, M C; Hahn, R L; Ho, T H; Hsiung, Y B; Hu, B Z; Kwan, K K; Kwok, M W; Kwok, T; Lau, Y P; Lee, K P; Leung, J K C; Leung, K Y; Lin, G L; Lin, Y C; Luk, K B; Luk, W H; Ngai, H Y; Ngan, S Y; Pun, C S J; Shih, K; Tam, Y H; Tsang, R H M; Wang, C H; Wong, C M; Wong, H L; Wong, H H C; Wong, K K; Yeh, M

    2013-01-01

    In this paper, we describe the design, construction and performance of an apparatus installed in the Aberdeen Tunnel laboratory in Hong Kong for studying spallation neutrons induced by cosmic-ray muons under a vertical rock overburden of 611 meter water equivalent (m.w.e.). The apparatus comprises of six horizontal layers of plastic-scintillator hodoscopes for determining the direction and position of the incident cosmic-ray muons. Sandwiched between the hodoscope planes is a neutron detector filled with 650 kg of liquid scintillator doped with about 0.06% of Gadolinium by weight for improving the e?ciency of detecting the spallation neutrons. Performance of the apparatus is also presented.

  13. Challenges and design solutions of the liquid hydrogen circuit at the European Spallation Source

    Science.gov (United States)

    Gallimore, S.; Nilsson, P.; Sabbagh, P.; Takibayev, A.; Weisend, J. G., II; Beßler, Y.; Klaus, M.

    2014-01-01

    The European Spallation Source (ESS), Lund, Sweden will be a 5MW long-pulse neutron spallation research facility and will enable new opportunities for researchers in the fields of life sciences, energy, environmental technology, cultural heritage and fundamental physics. Neutrons are produced by accelerating a high-energy proton beam into a rotating helium-cooled tungsten target. These neutrons pass through moderators to reduce their energy to an appropriate range (cooling medium. There are several technical challenges to overcome in the design of a robust system that will operate under such conditions, not least the 20 kW of deposited heat. These challenges and the associated design solutions will be detailed in this paper.

  14. Synthesis of neutron-rich transuranic nuclei in fissile spallation targets

    Energy Technology Data Exchange (ETDEWEB)

    Mishustin, Igor, E-mail: mishustin@fias.uni-frankfurt.de [Frankfurt Institute for Advanced Studies, J.-W. Goethe University, 60438 Frankfurt am Main (Germany); “Kurchatov Institute”, National Research Center, 123182 Moscow (Russian Federation); Malyshkin, Yury, E-mail: malyshkin@fias.uni-frankfurt.de [Frankfurt Institute for Advanced Studies, J.-W. Goethe University, 60438 Frankfurt am Main (Germany); Institute for Nuclear Research, Russian Academy of Sciences, 117312 Moscow (Russian Federation); Pshenichnov, Igor, E-mail: pshenich@fias.uni-frankfurt.de [Frankfurt Institute for Advanced Studies, J.-W. Goethe University, 60438 Frankfurt am Main (Germany); Institute for Nuclear Research, Russian Academy of Sciences, 117312 Moscow (Russian Federation); Greiner, Walter [Frankfurt Institute for Advanced Studies, J.-W. Goethe University, 60438 Frankfurt am Main (Germany)

    2015-04-15

    A possibility of synthesizing neutron-rich superheavy elements in spallation targets of Accelerator Driven Systems (ADS) is considered. A dedicated software called Nuclide Composition Dynamics (NuCoD) was developed to model the evolution of isotope composition in the targets during a long-time irradiation by intense proton and deuteron beams. Simulation results show that transuranic elements up to {sup 249}Bk can be produced in multiple neutron capture reactions in macroscopic quantities. However, the neutron flux achievable in a spallation target is still insufficient to overcome the so-called fermium gap. Further optimization of the target design, in particular, by including moderating material and covering it by a reflector could turn ADS into an alternative source of transuranic elements in addition to nuclear fission reactors.

  15. Spallation reaction and the probe of nuclear dissipation with excitation energy at scission

    International Nuclear Information System (INIS)

    We study in the framework of the Langevin model the influence of initial excitation energy (E*) of Hg compound nuclei (CNs) on the sensitivity of the excitation energy at scission (Esc*) to the nuclear friction strength (β). It is shown that the sensitivity is enhanced substantially with increasing E*. Moreover, we find that the significant sensitivity of Esc* to β at high E* is little affected by a marked difference in the neutron-to-proton ratio of a CN and in its size and fissility. Our findings suggest that, on the experimental side, a measurement of Esc* in energetic proton-induced spallation reactions can provide not only a sensitive but also a robust probe of nuclear dissipation in fission of highly excited nuclei. Further development of a suitable approach to spallation reaction is discussed. (authors)

  16. Fundamental neutron physics beamline at the spallation neutron source at ORNL

    Energy Technology Data Exchange (ETDEWEB)

    Fomin, N., E-mail: nfomin@utk.edu [University of Tennessee, Knoxville, TN (United States); Greene, G.L. [University of Tennessee, Knoxville, TN (United States); Oak Ridge National Laboratory, Oak Ridge, TN (United States); Allen, R.R.; Cianciolo, V. [Oak Ridge National Laboratory, Oak Ridge, TN (United States); Crawford, C. [University of Kentucky, Lexington, KY (United States); Tito, T.M. [Los Alamos National Laboratory, Los Alamos, NM (United States); Huffman, P.R. [Oak Ridge National Laboratory, Oak Ridge, TN (United States); North Carolina State University, Raleigh, NC (United States); Iverson, E.B. [Oak Ridge National Laboratory, Oak Ridge, TN (United States); Mahurin, R. [Middle Tennessee State University, Murfreesboro, TN (United States); University of Manitoba, Winnipeg, Manitoba (Canada); Snow, W.M. [Indiana University and Center for the Exploration of Energy and Matter, Bloomington, IN (United States)

    2015-02-11

    We describe the Fundamental Neutron Physics Beamline (FnPB) facility located at the Spallation Neutron Source at Oak Ridge National Laboratory. The FnPB was designed for the conduct of experiments that investigate scientific issues in nuclear physics, particle physics, astrophysics and cosmology using a pulsed slow neutron beam. We present a detailed description of the design philosophy, beamline components, and measured fluxes of the polychromatic and monochromatic beams.

  17. Nuclear studies of different target systems for the European Spallation Source (ESS)

    International Nuclear Information System (INIS)

    This paper summarizes nuclear simulation calculations to study various target concepts for the 'European Spallation Source (ESS)' concerning a proton beam power of 5 MW. For different target systems as rotating wheel target, stationary targets and liquid metal targets results of beam energy - and target material investigations, induced radioactivity and afterheat production as well as usable neutron fluxes are discussed. (author) 11 figs., 5 tabs., 5 refs

  18. Coherent Scattering Investigations at the Spallation Neutron Source: a Snowmass White Paper

    Energy Technology Data Exchange (ETDEWEB)

    Akimov, D. [Moscow Engineering Physics Institute (MEPhI), Russia; Bernstein, A. [Lawrence Livermore National Laboratory (LLNL); BarbeauP., [Duke University; Barton, P. J. [Lawrence Berkeley National Laboratory (LBNL); Bolozdynya, A. [Moscow Engineering Physics Institute (MEPhI), Russia; Cabrera-Palmer, B. [Sandia National Laboratories (SNL); Cavanna, F. [Yale University; Cianciolo, Vince [ORNL; Collar, J. [University of Chicago, Enrico Fermi Institute; Cooper, R. J. [Indiana University; Dean, D. J. [Oak Ridge National Laboratory (ORNL); Efremenko, Yuri [University of Tennessee (UTK) and Oak Ridge National Laboratory (ORNL); Etenko, A. [Moscow Engineering Physics Institute (MEPhI), Russia; Fields, N. [University of Chicago, Enrico Fermi Institute; Foxe, M. [Pennsylvania State University, University Park, PA; Figueroa-Feliciano, E. [Massachusetts Institute of Technology (MIT); Fomin, N. [University of Tennessee, Knoxville (UTK); Gallmeier, F. [Oak Ridge National Laboratory (ORNL); Garishvili, I. [University of Tennessee, Knoxville (UTK); Gerling, M. [Sandia National Laboratories (SNL); Green, M. [University of North Carolina, Chapel Hill; Greene, Geoffrey [University of Tennessee, Knoxville (UTK); Hatzikoutelis, A. [University of Tennessee, Knoxville (UTK); Henning, Reyco [University of North Carolina, Chapel Hill; Hix, R. [University of Tennessee (UTK) and Oak Ridge National Laboratory (ORNL); Hogan, D. [University of California-Berkeley; Hornback, D. [University of Tennessee (UTK) and Oak Ridge National Laboratory (ORNL); Jovanovic, I. [Pennsylvania State University, University Park, PA; Hossbach, T. [Pacific Northwest National Laboratory (PNNL); Iverson, Erik B [ORNL; Klein, S. R. [Lawrence Berkeley National Laboratory (LBNL); Khromov, A. [Moscow Engineering Physics Institute (MEPhI), Russia; Link, J. [Virginia Polytechnic Institute and State University; Louis, W. [Los Alamos National Laboratory (LANL); Lu, W. [Oak Ridge National Laboratory (ORNL); Mauger, C. [Los Alamos National Laboratory (LANL); Marleau, P. [Sandia National Laboratories (SNL); Markoff, D. [North Carolina Central University, Durham; Martin, R. D. [University of South Dakota; Mueller, Paul Edward [ORNL; Newby, J. [Oak Ridge National Laboratory (ORNL); Orrell, John L. [Pacific Northwest National Laboratory (PNNL); O' Shaughnessy, C. [University of North Carolina, Chapel Hill; Penttila, Seppo [Oak Ridge National Laboratory (ORNL); Patton, K. [North Carolina State University, Raleigh; Poon, A. W. [Lawrence Berkeley National Laboratory (LBNL); Radford, David C [ORNL; Reyna, D. [Sandia National Laboratories (SNL); Ray, H. [University of Florida, Gainesville; Scholberg, K. [Duke University, North Carolina; Sosnovtsev, V. [Moscow Engineering Physics Institute (MEPhI), Russia; Tayloe, R. [Indiana University; Vetter, K. [Lawrence Berkeley National Laboratory (LBNL); Virtue, C. [Laurentian University, Canada; Wilkerson, J. [University of North Carolina, Chapel Hill; Yoo, J. [Fermi National Accelerator Laboratory (FNAL); Yu, Chang-Hong [ORNL

    2013-01-01

    The Spallation Neutron Source (SNS) at Oak Ridge National Laboratory, Tennessee, provides an intense flux of neutrinos in the few tens-of-MeV range, with a sharply-pulsed timing structure that is beneficial for background rejection. In this white paper, we describe how the SNS source can be used for a measurement of coherent elastic neutrino-nucleus scattering (CENNS), and the physics reach of different phases of such an experimental program (CSI: Coherent Scattering Investigations at the SNS).

  19. Behavior of structural and target materials irradiated in spallation neutron environments

    Energy Technology Data Exchange (ETDEWEB)

    Stubbins, J.F. [Univ. of Illinois, Urbana, IL (United States). Dept. of Nuclear Engineering; Wechsler, M. [North Carolina State Univ., Raleigh, NC (United States). Dept. of Nuclear Engineering; Borden, M.; Sommer, W.F. [Los Alamos National Lab., NM (United States)

    1995-05-01

    This paper describes considerations for selection of structural and target materials for accelerator-driven neutron sources. Due to the operating constraints of proposed accelerator-driven neutron sources, the criteria for selection are different than those commonly applied to fission and fusion systems. Established irradiation performance of various alloy systems is taken into account in the selection criteria. Nevertheless, only limited materials performance data are available which specifically related to neutron energy spectra anticipated for spallation sources.

  20. Construction and operation of the Spallation Neutron Source: Draft environmental impact statement. Volume 1

    International Nuclear Information System (INIS)

    DOE proposes to construct and operate a state-of-the-art, short-pulsed spallation neutron source comprised of an ion source, a linear accelerator, a proton accumulator ring, and an experiment building containing a liquid mercury target and a suite of neutron scattering instrumentation. The proposed Spallation Neutron Source would be designed to operate at a proton beam power of 1 megawatt. The design would accommodate future upgrades to a peak operating power of 4 megawatts. These upgrades may include construction of a second proton accumulation ring and a second target. The US needs a high-flux, short-pulsed neutron source to provide the scientific and industrial research communities with a much more intense source of pulsed neutrons for neutron scattering research than is currently available, and to assure the availability of a state-of-the-art facility in the decades ahead. This next-generation neutron source would create new scientific and engineering opportunities. In addition, it would help replace the neutron science capacity that will be lost by the eventual shutdown of existing sources as they reach the end of their useful operating lives in the first half of the next century. This document analyzes the potential environmental impacts from the proposed action and the alternatives. The analysis assumes a facility operating at a power of 1 MW and 4 MW over the life of the facility. The two primary alternatives analyzed in this EIS are: the proposed action (to proceed with building the Spallation Neutron Source) and the No-Action Alternative. The No-Action Alternative describes the expected condition of the environment if no action were taken. Four siting alternatives for the Spallation Neutron Source are evaluated: Oak Ridge National Laboratory, Oak Ridge, TN, (preferred alternative); Argonne National Laboratory, Argonne, IL (US); Brookhaven National Laboratory, Upton, NY; and Los Alamos National Laboratory, Los Alamos, NM

  1. Process technology and effects of spallation products: Circuit components, maintenance, and handling

    Energy Technology Data Exchange (ETDEWEB)

    Sigg, B.; Haines, S.J.; Dressler, R.; McManamy, T.

    1996-06-01

    Working Session D included an assessment of the status of the technology and components required to: (1) remove impurities from the liquid metal (mercury or Pb-Bi) target flow loop including the effects of spallation products, (2) provide the flow parameters necessary for target operations, and (3) maintain the target system. A series of brief presentations were made to focus the discussion on these issues. The subjects of these presentations, and presenters were: (1) Spallation products and solubilities - R. Dressler; (2) Spallation products for Pb-Bi - Y. Orlov; (3) Clean/up/impurity removal components - B. Sigg; (4) {open_quotes}Road-Map{close_quotes} and remote handling needs - T. McManamy; (5) Remote handling issues and development - M. Holding. The overall conclusion of this session was that, with the exception of (i) spallation product related processing issues, (ii) helium injection and clean-up, and (iii) specialized remote handling equipment, the technology for all other circuit components (excluding the target itself) exists. Operating systems at the Institute of Physics in Riga, Latvia (O. Lielausis) and at Ben-Gurion University in Beer Shiva, Israel (S. Lesin) have demonstrated that other liquid metal circuit components including pumps, heat exchangers, valves, seals, and piping are readily available and have been reliably used for many years. In the three areas listed above, the designs and analysis are not judged to be mature enough to determine whether and what types of technology development are required. Further design and analysis of the liquid metal target system is therefore needed to define flow circuit processing and remote handling equipment requirements and thereby identify any development needs.

  2. Spallation Fragment Investigation on Nb, Au and Pb by Using Many Stage Dynamical Model

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    The formation cross section of the nuclides production of proton-induced nuclear reactions withintermediate energy is of importance for a variety of applications. For instance, the mass and chargedistribution of residual products produced in the spallation reactions needs to be studied, because it canprovide useful information for the disposal of nuclear waste and residual radioactivity generated by thespallation neutron target system. At present work, we developed the many stage dynamical model

  3. Accelerator system of neutron spallation source for nuclear energy technology development

    International Nuclear Information System (INIS)

    High intensity proton accelerators are at present and developed for applications in neutron spallation sources. The advantages of this source are better safety factor, easy in controlling and spent fuel free. A study of conceptual design of required accelerator system has been carried out. Considering the required proton beam and feasibility in the development stages, a stepped linac system is an adequate choice for now

  4. Proton injection and RF capture in the national spallation neutron source

    Energy Technology Data Exchange (ETDEWEB)

    Luccio, A.U.; Beebe-Wang, J.; Maletic, D. [and others

    1997-08-01

    The accelerator system for the 1 to 5 MW National Spallation Neutron Source (NSNS) consists of a linac followed by a 1 GeV proton accumulator ring. Since the ring is a very high current machine, the injection and rf capture of the protons is deeply affected by transverse and longitudinal space charge effects. Results of numerical simulation of the process are presented together with considerations on methods and results of space charge treatment in high intensity proton storage rings.

  5. Process technology and effects of spallation products: Circuit components, maintenance, and handling

    International Nuclear Information System (INIS)

    Working Session D included an assessment of the status of the technology and components required to: (1) remove impurities from the liquid metal (mercury or Pb-Bi) target flow loop including the effects of spallation products, (2) provide the flow parameters necessary for target operations, and (3) maintain the target system. A series of brief presentations were made to focus the discussion on these issues. The subjects of these presentations, and presenters were: (1) Spallation products and solubilities - R. Dressler; (2) Spallation products for Pb-Bi - Y. Orlov; (3) Clean/up/impurity removal components - B. Sigg; (4) open-quotes Road-Mapclose quotes and remote handling needs - T. McManamy; (5) Remote handling issues and development - M. Holding. The overall conclusion of this session was that, with the exception of (i) spallation product related processing issues, (ii) helium injection and clean-up, and (iii) specialized remote handling equipment, the technology for all other circuit components (excluding the target itself) exists. Operating systems at the Institute of Physics in Riga, Latvia (O. Lielausis) and at Ben-Gurion University in Beer Shiva, Israel (S. Lesin) have demonstrated that other liquid metal circuit components including pumps, heat exchangers, valves, seals, and piping are readily available and have been reliably used for many years. In the three areas listed above, the designs and analysis are not judged to be mature enough to determine whether and what types of technology development are required. Further design and analysis of the liquid metal target system is therefore needed to define flow circuit processing and remote handling equipment requirements and thereby identify any development needs

  6. Heavy density liquid metal spallation target studies for Indian ADS programme

    Indian Academy of Sciences (India)

    P Sathamurthy; L M Gantayet; A K Ray

    2007-02-01

    Department of Atomic Energy, India has taken up the development of ADS in view of many attractive features like inherent safety, capability to transmute large quantities of nuclear waste, better utilization of thorium etc. A roadmap has been finalized for the development of ADS. One of the key components of the ADS is the spallation target. Considering the neutron yield, thermal-hydraulics and radiation damage issues, we are proposing to develop spallation target based on heavy density liquid metals like lead and lead-bismuth-eutectic (LBE). Both window and windowless target configurations are presently being studied. In view of the various advantages we are also studying liquid metal flow circulation based on gas lift mechanism. An R&D programme has been initiated to address various physics and technology issues of ADS target. Under this programme, mercury and LBE experimental facilities are presently being set up. Along with these facilities, computational tools related to spallation physics (FLUKA) and CFD are being developed, and the existing ones are utilized to design the entire target loop as well as sub-systems. In this presentation the details of these activities are presented.

  7. Spallation Backgrounds in Super-Kamiokande Are Made in Muon-Induced Showers

    CERN Document Server

    Li, Shirley Weishi

    2015-01-01

    Crucial questions about solar and supernova neutrinos remain unanswered. Super-Kamiokande has the exposure needed for progress, but detector backgrounds are a limiting factor. A leading component is the beta decays of isotopes produced by cosmic-ray muons and their secondaries, which initiate nuclear spallation reactions. Cuts of events after and surrounding muon tracks reduce this spallation decay background by $\\simeq 90\\%$ (at a cost of $\\simeq 20\\%$ deadtime), but its rate at 6 -- 18 MeV is still dominant. A better way to cut this background was suggested in a Super-Kamiokande paper [Bays {\\it et al.}, Phys.~Rev.~D {\\bf 85}, 052007 (2012)] on a search for the diffuse supernova neutrino background. They found that spallation decays above 16 MeV were preceded near the same location by a peak in the apparent Cherenkov light profile from the muon; a more aggressive cut was applied to a limited section of the muon track, leading to decreased background without increased deadtime. We put their empirical discove...

  8. Disposal strategy of proton irradiated mercury from high power spallation sources

    International Nuclear Information System (INIS)

    Large spallation sources are intended to be constructed in Europe (EURISOL: nuclear physics research facility and ESS: European Spallation Source). These facilities would accumulate more than 20 metric tons of irradiated mercury in the target, which has to be treated as highly radioactive and chemo-toxic waste. Liquid waste cannot be tolerated in European repositories. As part of this work on safety/decommissioning of high-power spallation sources, our investigations were focused mainly to study experimentally and theoretically the solidification of liquid mercury waste (selection of an adequate solid mercury form and of an immobilization matrix, chemical engineering process studies on solidification/stabilization and on encapsulating in a matrix). Based on experimental results and supported by literature Hg-chalcogens (HgS, HgSe) will be more stable in repositories than amalgams. Our irradiation experimental studies on mercury waste revealed that mercury sulfide is a reasonable solid for disposal and shows larger stability in possible accidents with water ingress in a repository. Additionally immobilization of mercury in a cement matrix and polysiloxane matrix were tested. HgS formation from liquid target mercury by a wet process is identified as a suitable formation procedure. These investigations reveal that an almost 99.9% elementary Hg conversion can be achieved and that wet process can be reasonably handled under hot cell conditions. (orig.)

  9. Cosmic Ray Spallation in Radio-Quiet Active Galactic Nuclei: A Case Study of NGC 4051

    CERN Document Server

    Turner, T J

    2009-01-01

    We investigate conditions for and consequences of spallation in radio-quiet Seyfert galaxies. The work is motivated by the recent discovery of significant line emission at 5.44 keV in Suzaku data from NGC 4051. The energy of the new line suggests an identification as Cr I Ka emission, however the line is much stronger than would be expected from material with cosmic abundances, leading to a suggestion of enhancement owing to nuclear spallation of Fe by low energy cosmic rays from the active nucleus. We find that the highest abundance enhancements are likely to take place in gas out of the plane of the accretion disk and that timescales for spallation could be as short as a few years. The suggestion of a strong nuclear flux of cosmic rays in a radio-quiet Seyfert galaxy is of particular interest in light of the recent suggestion from Pierre Auger Observatory data that ultra-high-energy cosmic rays may originate in such sources.

  10. Construction and operation of the Spallation Neutron Source: Draft environmental impact statement. Volume 2

    International Nuclear Information System (INIS)

    DOE proposes to construct and operate a state-of-the-art, short-pulsed spallation neutron source comprised of an ion source, a linear accelerator, a proton accumulator ring, and an experiment building containing a liquid mercury target and a suite of neutron scattering instrumentation. The proposed Spallation Neutron Source would be designed to operate at a proton beam power of 1 megawatt. The design would accommodate future upgrades to a peak operating power of 4 megawatts. These upgrades may include construction of a second proton accumulation ring and a second target. Volume 1 of this document analyzes the potential environmental impacts from the proposed action and the alternatives. The analysis assumes a facility operating at a power of 1 MW and 4 MW over the life of the facility. The two primary alternatives analyzed in this EIS are: the proposed action (to proceed with building the Spallation Neutron Source) and the No-Action Alternative. This volume contains the following appendices: (A) SNS accident source terms for EIS input; (B) Reports on the selection of alternative sites for the SNS; (C) Letters of consultation on protected species and cultural resources; (D) Ecological resource survey reports and summaries; (E) Descriptions of ORNL research projects in the Walker Branch Watershed; (F) Atmospheric dispersion and dose calculations for normal and accident conditions; (G) Projected air quality modeling effects at NOAA's Walker Branch Monitoring Tower

  11. Heavy density liquid metal spallation target studies for Indian ADS programme

    Science.gov (United States)

    Satyamurthy, P.; Gantayet, L. M.; Ray, A. K.

    2007-02-01

    Department of Atomic Energy, India has taken up the development of ADS in view of many attractive features like inherent safety, capability to transmute large quantities of nuclear waste, better utilization of thorium etc. A roadmap has been finalized for the development of ADS. One of the key components of the ADS is the spallation target. Considering the neutron yield, thermal-hydraulics and radiation damage issues, we are proposing to develop spallation target based on heavy density liquid metals like lead and lead{bismuth{eutectic (LBE). Both window and windowless target configurations are presently being studied. In view of the various advantages we are also studying liquid metal flow circulation based on gas lift mechanism. An R&D programme has been initiated to address various physics and technology issues of ADS target. Under this programme, mercury and LBE experimental facilities are presently being set up. Along with these facilities, computational tools related to spallation physics (FLUKA) and CFD are being developed, and the existing ones are utilized to design the entire target loop as well as sub-systems. In this presentation the details of these activities are presented.

  12. Disposal strategy of proton irradiated mercury from high power spallation sources

    Energy Technology Data Exchange (ETDEWEB)

    Chiriki, Suresh

    2010-07-01

    Large spallation sources are intended to be constructed in Europe (EURISOL: nuclear physics research facility and ESS: European Spallation Source). These facilities would accumulate more than 20 metric tons of irradiated mercury in the target, which has to be treated as highly radioactive and chemo-toxic waste. Liquid waste cannot be tolerated in European repositories. As part of this work on safety/decommissioning of high-power spallation sources, our investigations were focused mainly to study experimentally and theoretically the solidification of liquid mercury waste (selection of an adequate solid mercury form and of an immobilization matrix, chemical engineering process studies on solidification/stabilization and on encapsulating in a matrix). Based on experimental results and supported by literature Hg-chalcogens (HgS, HgSe) will be more stable in repositories than amalgams. Our irradiation experimental studies on mercury waste revealed that mercury sulfide is a reasonable solid for disposal and shows larger stability in possible accidents with water ingress in a repository. Additionally immobilization of mercury in a cement matrix and polysiloxane matrix were tested. HgS formation from liquid target mercury by a wet process is identified as a suitable formation procedure. These investigations reveal that an almost 99.9% elementary Hg conversion can be achieved and that wet process can be reasonably handled under hot cell conditions. (orig.)

  13. Experimental Study of the Phenomenology of Spallation Neutrons in a Large Lead Block

    CERN Multimedia

    Galvez Altamirano, J; Lopez, C; Perlado, J M; Perez-Navarro, A

    2002-01-01

    %PS211 %title \\\\ \\\\The purpose of PS211 is to determine how neutrons, produced by spallation inside a large Lead volume are slowed down by undergoing a very large number of scatterings, losing each time a small fraction ($\\sim$ 1\\%) of their kinetic energy. The focus is in determining the probability for a spallation neutron produced at an energy of several MeV or more, to survive capture on Lead resonances and to reach resonance energies of materials to be transmuted, such as 5.6 eV for $^{99}$Tc. This process, of Adiabatic Resonance Crossing, involves a subtle interplay between the capture resonances of the Lead medium and of selected impurities. This phenomenology of spallation neutrons in a large Lead volume, is the physics foundation of the Fast Energy Amplifier proposed by C. Rubbia, and could open up new possibilities in the incineration of long-lived nuclear waste such as Actinides or Fission Fragments (e.g. $^{99}$Tc, $^{129}$I, etc.).\\\\ \\\\334 tons of high purity Lead, installed in t7, are exposed to...

  14. Plasma Processes : Plasma sprayed alumina coatings for radiation detector development

    Indian Academy of Sciences (India)

    Mary Alex; V Balagi; K R Prasad; K P Sreekumar; P V Ananthapadmanabhan

    2000-11-01

    Conventional design of radiation detectors uses sintered ceramic insulating modules. The major drawback of these ceramic components is their inherent brittleness. Ion chambers, in which these ceramic spacers are replaced by metallic components with plasma spray coated alumina, have been developed in our Research Centre. These components act as thin spacers that have good mechanical strength as well as high electrical insulation and replace alumina insulators with the same dimensions. As a result, the design of the beam loss monitor ion chamber for CAT could be simplified by coating the outer surface of the HT electrode with alumina. One of the chambers developed for isotope calibrator for brachytherapy gamma sources has its outer aluminium electrode (60 mm dia × 220 mm long) coated with 250 thick alumina (97%) + titania (3%). In view of potential applications in neutron-sensitive ion chambers used in reactor control instrumentation, studies were carried out on alumina 100 to 500 thick coatings on copper, aluminium and SS components. The electrical insulation varied from 108 ohms to 1012 ohms for coating thicknesses above 200 . The porosity in the coating resulted in some fall in electrical insulation due to moisture absorption. An improvement could be achieved by providing the ceramic surface with moisture-repellent silicone oil coating. Irradiation at Apsara reactor core location showed that the coating on aluminium was found to be unaffected after exposure to 1017 nvt fluence.

  15. Aluminas with dispersoids. Tribologic properties and in vivo aging.

    Science.gov (United States)

    Mandrino, A; Moyen, B; Ben Abdallah, A; Treheux, D; Orange, D

    1990-07-01

    Three base alumina ceramics with dispersoids: monoclinic zirconia alumina (A5Z), tetragonal zirconia alumina (A20Z) and aluminalon (Aa20) have been investigated because of their improved mechanical properties with reference to pure alumina (AI203). Bending strength and fracture toughness are twice higher than alumina for the most toughened. These two parameters were measured by four-points bending tests after 1 week, 1, 2, 3, 6, 12 months of non loaded in vivo aging in wistar rats. They showed a little decrease for AI203 and Aa20 and a total stability for A5Z and A20Z even after one year. For tribologic study of the ceramic/polyethylene combination, cylinder against plane and pin on flat tests were conducted on an alternative movement with hip parameters of speed and load in presence of ringer solution. For the most representative test (pin on disk), the friction coefficients were nearly the same for all materials but UHMWPE wear volume was twice lower against A20Z than against AI203. A20Z/UHMWPE combination would be very interesting as new friction couple for total hip arthroplasty. Further studies are currently conducted. PMID:2397268

  16. Preliminary studies for basic design parameters of an accumulator ring for Indian spallation neutron source

    International Nuclear Information System (INIS)

    There is a proposal to build a pulsed spallation neutron source complex in India, driven by a full energy linac followed by a proton accumulator ring (AR) to provide a high average beam power at a spallation target. In this complex, an H- linac will be used as an injector, which will deliver beam pulses of 1-2 ms to the AR. Using a multi-turn charge exchange injection scheme, the pulses will be compressed to ∼ 1 μs in AR. The proton beam will then be further compressed using the RF system of AR to facilitate the firing of the extraction kickers for beam extraction. This extracted proton beam will hit the spallation target to produce the spallation neutrons. This process will repeat with a suitable repetition rate to achieve high average beam power. However, the repetition rate is limited by the constraint of avoiding the frame overlap in time-of-flight experiments. An initial study to fix the base design parameters has been started. In this paper, we discuss some of the basic issues, which decide the choice of the feasible initial parameter space for the proposed AR. We explore the possibility of reducing the required peak beam current from the linac by increasing the injected pulse width in the AR, which will reduce the intensity related effects. In addition, in this configuration required peak RF power will be low and therefore one can even use solid state amplifiers for RF system. Injection of a longer beam pulse into AR will require either a longer circumference AR or higher number of injection turns. We discuss the practical implications of these issues. We also discuss the possible beam power at the target using this configuration (i.e. longer pulse with reduced peak current) at different repetition rate. Considering all these issues, we obtain the possible space of initial parameters for the proposed AR for the spallation neutron source. Finally, we briefly discuss the different choices about the lattice for the AR. (author)

  17. Accelerator driven reactors, - the significance of the energy distribution of spallation neutrons on the neutron statistics

    International Nuclear Information System (INIS)

    In order to make correct predictions of the second moment of statistical nuclear variables, such as the number of fissions and the number of thermalized neutrons, the dependence of the energy distribution of the source particles on their number should be considered. It has been pointed out recently that neglecting this number dependence in accelerator driven systems might result in bad estimates of the second moment, and this paper contains qualitative and quantitative estimates of the size of these efforts. We walk towards the requested results in two steps. First, models of the number dependent energy distributions of the neutrons that are ejected in the spallation reactions are constructed, both by simple assumptions and by extracting energy distributions of spallation neutrons from a high-energy particle transport code. Then, the second moment of nuclear variables in a sub-critical reactor, into which spallation neutrons are injected, is calculated. The results from second moment calculations using number dependent energy distributions for the source neutrons are compared to those where only the average energy distribution is used. Two physical models are employed to simulate the neutron transport in the reactor. One is analytical, treating only slowing down of neutrons by elastic scattering in the core material. For this model, equations are written down and solved for the second moment of thermalized neutrons that include the distribution of energy of the spallation neutrons. The other model utilizes Monte Carlo methods for tracking the source neutrons as they travel inside the reactor material. Fast and thermal fission reactions are considered, as well as neutron capture and elastic scattering, and the second moment of the number of fissions, the number of neutrons that leaked out of the system, etc. are calculated. Both models use a cylindrical core with a homogenous mixture of core material. Our results indicate that the number dependence of the energy

  18. Origin of High-Alumina Basalt, Andesite, and Dacite Magmas.

    Science.gov (United States)

    Hamilton, W

    1964-10-30

    The typical volcanic rocks of most island arcs and eugeosynclines, and of some continental environments, are basalt, andesite, and dacite, of high alumina content. The high-alumina basalt differs from tholeiitic basalt primarily in having a greater content of the components of calcic plagioclase. Laboratory data indicate that in the upper mantle, below the level at which the basaltic component of mantle rock is transformed by pressure to eclogite or pyroxenite, the entire basaltic portion probably is melted within a narrow temperature range, but that above the level of that transformation plagioclase is melted selectively before pyroxene over a wide temperature range. The broad spectrum of high-alumina magmas may represent widely varying degrees of partial melting above the transformation level, whereas narrow-spectrum tholeiite magma may represent more complete melting beneath it.

  19. Pressureless sintering behavior of injection molded alumina ceramics

    Directory of Open Access Journals (Sweden)

    Liu W.

    2014-01-01

    Full Text Available The pressureless sintering behaviors of two widely used submicron alumina (MgOdoped and undoped with different solid loadings produced by injection molding have been studied systematically. Regardless of the sinterability of different powders depending on their inherent properties, solid loading plays a critical role on the sintering behavior of injection molded alumina, which greatly determines the densification and grain size, and leads to its full densification at low temperatures. As compared to the MgO-doped alumina powder, the undoped specimens exhibit a higher sinterability for its smaller particle size and larger surface area. While full densification could be achieved for MgO-doped powders with only a lower solid loading, due to the fact that MgO addition can reduce the detrimental effect of the large pore space on the pore-boundary separation.

  20. Energy transfer in porous anodic alumina/rhodamine 110 nanocomposites

    Energy Technology Data Exchange (ETDEWEB)

    Elhouichet, H., E-mail: habib.elhouichet@fst.rnu.tn [Laboratoire de Physico-Chimie des Materiaux Mineraux et leurs Applications, Centre National de Recherches en Sciences des Materiaux, B.P. 95, Hammam-Lif 2050 (Tunisia); Departement de Physique, Faculte des Sciences de Tunis, University of Tunis Elmanar 2092 Tunis (Tunisia); Harima, N.; Koyama, H. [Hyogo University of Teacher Education, Kato, Hyogo 673-1494 (Japan); Gaponenko, N.V. [Belarusian State University of Informatics and Radioelectronics, P. Browki St. 6, 220013 Minsk (Belarus)

    2012-09-15

    We have used porous anodic alumina (PAA) films as templates for embedding rhodamine 110 (Rh110) molecules and examined their photoluminescence (PL) properties in detail. The analysis of the polarization memory (PM) of PL strongly suggests that there is a significant energy transfer from PAA to Rh110 molecules. The effect of annealing the PAA layer on the PL properties of the nanocomposite has been studied. The results show that the energy transfer becomes more efficient in annealed PAA. - Highlights: Black-Right-Pointing-Pointer Porous anodic alumina-rhodamine 110 nanocomposites are elaborated. Black-Right-Pointing-Pointer Efficient energy transfer from the host to Rh110 molecules is evidenced from measurements of photoluminescence and degree of polarization memory spectra. Black-Right-Pointing-Pointer Thermal annealing of porous anodic alumina can improve the process of excitation transfer.

  1. Alumina Template-Dependant Growth of Cobalt Nanowire Arrays

    Directory of Open Access Journals (Sweden)

    L. Malferrari

    2009-01-01

    Full Text Available Different electrochemical regimes and porous alumina were applied for template synthesis of cobalt nanowire (nw arrays, revealing several peculiar cases. In contrast to quite uniform filling of sulfuric acid alumina templates by alternating current deposition, nonuniform growth of the Co nw tufts and mushrooms was obtained for the case of oxalic acid templates. We showed herein for the first time that such configurations arise from the spontaneous growth of cobalt nw groups evolving from the cobalt balls at the Al/alumina interface. Nevertheless, the uniform growth of densely packed cobalt nw arrays, up to tens of micrometers in length, was obtained via long-term direct current galvanostatic deposition at low current density using oxalic acid templates one-side coated by conducting layer. The unique point of this regime is the formation of hexagonal lattice Co nws with a preferred (100 growth direction.

  2. Calculation of the effective emissivity of blackbodies made of alumina

    International Nuclear Information System (INIS)

    Blackbodies are sources of temperature radiation that are used for calibration of radiation thermometers. Their effective emissivity should be close to the value of 1 to approximate an ideal Planckian radiator. Their effective emissivity depends on the geometry of their cavity and the used material. It can be estimated by measurements, but often it is calculated by numerical methods. For typical graphite blackbodies, it was shown in the past that high effective emissivities better than 0.999 can be reached. In this paper, calculations of the effective emissivity of a alumina blackbody are presented. Alumina is a new material for blackbodies, with different radiation properties. Using two calculation methods (integrative cavity method and Monte Carlo method), the effective cavity emissivity for blank and coated alumina is estimated. It is shown that effective spectral emissivities up to 0.999 87 can be reached. (paper)

  3. Gaseous contaminants in SF{sub 6} interacting with alumina

    Energy Technology Data Exchange (ETDEWEB)

    Lussier, T.; Frechette, M.F.; Larocque, R.Y. [Inst. de Recherche d`Hydro-Quebec, Varennes, Quebec (Canada)

    1996-12-31

    The interaction between CO{sub 2} or SOF{sub 2} (10{sup 3} to 10{sup 4} ppm{sub v}) and alumina (10 g) in SF{sub 6} was investigated. The adsorption kinetics was monitored by taking on-line gas samples. A gas chromatograph coupled to a thermal-conductivity detector served to assess the concentration of each species in the mixtures. Under the chosen experimental conditions, no matrix effect was detected, since the sorptive kinetics involving CO{sub 2}/SF{sub 6} proved similar to that observed with CO{sub 2}/He. The adsorption of SOF{sub 2} was found to be stronger than that observed for CO{sub 2}, although part was transformed into SO{sub 2}. When the alumina sample was exposed to CO{sub 2} then to SOF{sub 2}, some of the CO{sub 2} adsorbed was released, demonstrating a preferential adsorption on alumina.

  4. Porous Alumina as a Promising Biomaterial for Public Health.

    Science.gov (United States)

    Bragazzi, Nicola Luigi; Gasparini, Roberto; Amicizia, Daniela; Panatto, Donatella; Larosa, Claudio

    2015-01-01

    Porous aluminum is a nanostructured material characterized by unique properties, such as chemical stability, regular uniformity, dense hexagonal porous lattice with high aspect ratio nanopores, excellent mechanical strength, and biocompatibility. This overview examines how the structure and properties of porous alumina can be exploited in the field of public health. Porous alumina can be employed for fabricating membranes and filters for bioremediation, water ultrafiltration, and microfiltration/nanofiltration, being a promising technique for having clean and fresh water, which is essential for human health. Porous alumina-based nanobiosensor coated with specific antibodies or peptides seem to be a useful tool to detect and remove pathogens both in food and in water, as well as for environmental monitoring. Further, these applications, being low-energy demanding and cost-effective, are particularly valuable in resource-limited settings and contexts, and can be employed as point of use devices in developing countries, where there is an urgent need of hygiene and safety assurance.

  5. Factors contributing to the breakdown of sodium beta-alumina

    Energy Technology Data Exchange (ETDEWEB)

    Buechele, A.C.

    1982-05-01

    Clarification of the breakdown process occurring during charge transfer in sodium beta alumina solid electrolytes was derived from: (1) studying the effects of molten sodium contact at 350/sup 0/C on single crystal sodium beta alumina and polycrystalline sodium beta alumina; (2) determination of critical current density by monitoring acoustic emissions accompanying crack growth in sodium/sodium beta alumina/sodium cells subjected to linear current ramping at 1 mA cm/sup -2/ sec/sup -1/; (3) failure analysis conducted on cycled electrolytes, some from commercial sodium/sulfur cells, which had been subjected to up to 703 Ahr cm/sup -2/ of charge transfer. Gray coloration developing in beta aluminas in contact with molten sodium was found to be a consequence of formation, through reduction by sodium, of oxygen vacancies charge compensated by electrons. Electronic conductivity of the electrolyte increases as a result. No second phase formation was detected. Colored electrolytes from sodium/sulfur cells show evidence of a newly recognized degradation mechanism in which fracture occurs when sodium is reduced and deposited internally under pressure as metal in regions where an electronic conductivity gradient exists. Heating colored beta aluminas in air produces reoxidation and bleaching. Kinetics and other properties of the coloration and bleaching processes were determined. Critical current density was found to bear an inverse relation to average electrolyte grain size. Evidence was found in the cycled electrolytes for a slow crack growth mechanism and a progressive mode of degradation advancing from the sulfur electrode interface. Implications of the findings for the construction and operation of sodium/sulfur battery systems are discussed.

  6. Monitoring method for neutron flux for a spallation target in an accelerator driven sub-critical system

    Science.gov (United States)

    Zhao, Qiang, He, Zhi-Yong; Yang, Lei; Zhang, Xue-Ying; Cui, Wen-Juan; Chen, Zhi-Qiang; Xu, Hu-Shan

    2016-07-01

    In this paper, we study a monitoring method for neutron flux for the spallation target used in an accelerator driven sub-critical (ADS) system, where a spallation target located vertically at the centre of a sub-critical core is bombarded vertically by high-energy protons from an accelerator. First, by considering the characteristics in the spatial variation of neutron flux from the spallation target, we propose a multi-point measurement technique, i.e. the spallation neutron flux should be measured at multiple vertical locations. To explain why the flux should be measured at multiple locations, we have studied neutron production from a tungsten target bombarded by a 250 MeV-proton beam with Geant4-based Monte Carlo simulations. The simulation results indicate that the neutron flux at the central location is up to three orders of magnitude higher than the flux at lower locations. Secondly, we have developed an effective technique in order to measure the spallation neutron flux with a fission chamber (FC), by establishing the relation between the fission rate measured by FC and the spallation neutron flux. Since this relation is linear for a FC, a constant calibration factor is used to derive the neutron flux from the measured fission rate. This calibration factor can be extracted from the energy spectra of spallation neutrons. Finally, we have evaluated the proposed calibration method for a FC in the environment of an ADS system. The results indicate that the proposed method functions very well. Supported by Strategic Priority Research Program of Chinese Academy of Sciences (XDA03010000 and XDA03030000) and the National Natural Science Foundation of China(91426301).

  7. Effects of yttrium on the sintering and microstructure of alumina-silicon carbide "nanocomposites"

    OpenAIRE

    Cock, AM; Shapiro, IP; Todd, RI; Roberts, SG

    2005-01-01

    Alumina and alumina-based "nanocomposites" with 2 and 5 vol% silicon carbide and varying amounts of yttria (0-1.5 wt%) have been prepared by pressureless sintering in the temperature range 1450°-1650°C. The effects of composition and sintering temperature on density and microstructure are reported. Yttria inhibited sintering in alumina, but enhanced the sinterability of the nanocomposites. It also induced abnormal grain growth in both alumina and nanocomposites, but strongly bimodal grain siz...

  8. Adsorption of textile dye onto modified immobilized activated alumina

    OpenAIRE

    Ayesha Wasti; M. Ali Awan

    2016-01-01

    The study describes the synthesis of modified immobilized activated alumina (MIAA) and its application for the removal of textile dye from aqueous media. Immobilization was carried out by using the sol–gel method while modifications were made during the synthesis by adding powder activated alumina. Batch adsorption experiments were carried out at 20 ± 1 °C to see the effect of different parameters like contact time, stirring rate, initial concentration of the dye and dose of MIAA. The removal...

  9. CRACK PROPAGATION BEHAVIOR AND LIFETIME PREDICTION IN ALUMINA AND ZIRCONIA

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    The lifetime prediction of ceramics is discussed on the basis of the relationship between stress intensity factor KI and crack velocity v. The effects of water environment, the cyclic loading and microstructure of material on KI-v characteristics are studied by carrying out the crack growth tests by the double torsion (DT) method under the static and cyclic loading in both environments of air and water for alumina and zirconia. KI-v characteristics determined by the double torsion method are used to predict time-to-failure under the cyclic loading of alumina and zirconia ceramics. The predictions agree qualitatively with the experimental results.

  10. Direct current plasma spraying of mechanofused alumina-steel particles

    OpenAIRE

    Bouneder, Mohamed; Ageorges, Hélène; El Ganaoui, M.; Pateyron, Bernard; Fauchais, Pierre

    2009-01-01

    Paper project pages 26 Stainless steel particles (60 µm in mean diameter) cladded with an alumina shell (2 µm thick and manufactured by mechanofusion) were sprayed with an Ar-H2 (53-7 slm) d.c. plasma jet (I = 500 A, P = 28 kW, \\rho_th = 56 %). Two main types of particles were collected in flight, as close as 50 mm downstream of the nozzle exit: particles with a steel core with pieces of alumina unevenly distributed at their surface and those consisting of a spherical stainless steel parti...

  11. Comparative study on sintered alumina for ballistic shielding application

    International Nuclear Information System (INIS)

    This work presents a development of the armor made from special ceramic materials and kevlar. An experimental investigation was conducted to study the ballistic penetration resistance on three samples taken from sintered alumina: a commercial one and two formulations A and B made in IAE/CTA. The main differences between the two formulations was the grain size and bend resistance. The knowledge of the mechanisms during the penetration and perforation process allowed to apply a ductile composite laminate made form kevlar under the alumina to delay its rupture. The last ballistic test showed how a Weibull's modulii and other mechanical properties are able to improve ballistic penetration resistance. (author)

  12. Synthesis of alumina based on industrial waste material

    OpenAIRE

    López-Andrés, Sol; Fillali, Laila; Jiménez, José Antonio; Tayibi, Hanan; Padilla, Isabel; López-Delgado, Aurora

    2011-01-01

    A hazardous waste generated in slag milling process by the aluminium industry was used as a raw material for the synthesis of alumina, α-Al2O3. This waste is considered as hazardous material in the European legislation due to the release of toxic gases (hydrogen, ammonia, methane and hydrogen sulphide) in the presence of water. The process developed in this work allows to obtaining 1 ton of alumina from 4 tons of hazardous waste and generates an inert solid residue consisting principally of s...

  13. The Effect of Beam Intensity on Temperature Distribution in ADS Windowless Lead-Bismuth Eutectic Spallation Target

    Directory of Open Access Journals (Sweden)

    Jie Liu

    2014-01-01

    Full Text Available The spallation target is the component coupling the accelerator and the reactor and is regarded as the “heart” of the accelerator driven system (ADS. Heavy liquid metal lead-bismuth eutectic (LBE is served as core coolant and spallation material to carry away heat deposition of spallation reaction and produce high flux neutron. So it is very important to study the heat transfer process in the target. In this paper, the steady-state flow pattern has been numerically obtained and taken as the input for the nuclear physics calculation, and then the distribution of the extreme large power density of the heat load is imported back to the computational fluid dynamics as the source term in the energy equation. Through the coupling, the transient and steady-state temperature distribution in the windowless spallation target is obtained and analyzed based on the flow process and heat transfer. Comparison of the temperature distribution with the different beam intensity shows that its shape is the same as broken wing of the butterfly. Nevertheless, the maximum temperature as well as the temperature gradient is different. The results play an important role and can be applied to the further design and optimization of the ADS windowless spallation target.

  14. Monitoring method of neutron flux for the spallation target used in an accelerator driven sub-critical systems

    CERN Document Server

    Zhao, Qiang; Yang, Lei; Zhang, Xueying; Cui, Wenjuan; Chen, Zhiqiang; Xu, Hushan

    2015-01-01

    In this paper, we study the monitoring method of neutron flux for the spallation target used in an accelerator driven sub-critical (ADS) system, where the spallation target located vertically at the centre of a sub-critical core is bombarded vertically by the high-energy protons from an accelerator. First, by considering the characteristics in the spatial variation of neutron flux from the spallation target, we propose the following multi-point measurement technique, i.e. the spallation neutron flux should be measured at multiple vertical locations. To explain why the flux should be measured at multiple locations, we have studied the neutron production from tungsten target bombarded by a 250 MeV-proton beam with the Geant4-based Monte Carlo simulations. The simulation results have indicated that the neutron flux at the central location is up to three orders of magnitude higher than the flux at the lower locations. Secondly, we have developed an effective technique in order to measure the spallation neutron fl...

  15. Modelling of the spallation reaction: analysis and testing of nuclear models; Simulation de la spallation: analyse et test des modeles nucleaires

    Energy Technology Data Exchange (ETDEWEB)

    Toccoli, C

    2000-04-03

    The spallation reaction is considered as a 2-step process. First a very quick stage (10{sup -22}, 10{sup -29} s) which corresponds to the individual interaction between the incident projectile and nucleons, this interaction is followed by a series of nucleon-nucleon collisions (intranuclear cascade) during which fast particles are emitted, the nucleus is left in a strongly excited level. Secondly a slower stage (10{sup -18}, 10{sup -19} s) during which the nucleus is expected to de-excite completely. This de-excitation is performed by evaporation of light particles (n, p, d, t, {sup 3}He, {sup 4}He) or/and fission or/and fragmentation. The HETC code has been designed to simulate spallation reactions, this simulation is based on the 2-steps process and on several models of intranuclear cascades (Bertini model, Cugnon model, Helder Duarte model), the evaporation model relies on the statistical theory of Weiskopf-Ewing. The purpose of this work is to evaluate the ability of the HETC code to predict experimental results. A methodology about the comparison of relevant experimental data with results of calculation is presented and a preliminary estimation of the systematic error of the HETC code is proposed. The main problem of cascade models originates in the difficulty of simulating inelastic nucleon-nucleon collisions, the emission of pions is over-estimated and corresponding differential spectra are badly reproduced. The inaccuracy of cascade models has a great impact to determine the excited level of the nucleus at the end of the first step and indirectly on the distribution of final residual nuclei. The test of the evaporation model has shown that the emission of high energy light particles is under-estimated. (A.C.)

  16. Final report on the application of chaos theory to an alumina sensor for aluminum reduction cells. Inert Electrodes Program

    Energy Technology Data Exchange (ETDEWEB)

    Williford, R.E.; Windisch, C.F. Jr.

    1992-03-01

    Four chaos-related digital signal analysis (DSA) methods were applied to the analysis of voltage and current signals collected from aluminum electrolysis cells. Two separate data bases were analyzed: bench-scale laboratory experiments and a pilot-scale test. The objective was to assess the feasibility of using these types of data and analysis methods as the basis for a non-intrusive sensor to measure the alumina content in the electrolysis bath. This was the first time chaos theory approaches have been employed to analyze aluminum electrolysis cells.

  17. Relevance of alumina grit analysis in zircaloy fabrication process

    International Nuclear Information System (INIS)

    Zirconium based alloys are the natural choice for both fuel element and in-core structural components in the water cooled thermal reactors, namely BWRs, PWRs and PHWRs. Nuclear Fuel Complex (NFC), Hyderabad is engaged in the production of zirconium based alloys that are used as hardware in the nuclear industry. After hot working of zircaloy, due to its reactivity, an oxide layer is formed on its surfaces. Hence to remove this oxide layer grit blasting operation using alumina grit sand is followed during which the particles of the sand gets fragmented and the oxide layer on the material thus gets dislodged. Thus alumina grit plays a prominent role in the zircaloy fabrication process. In order to have an ideal and effective removal of the oxide layer from the zircaloy surface, knowledge about the composition of the grit with respect to Al2O3, SiO2, TiO2, Fe2O3, CaO and MgO is essential. Therefore the chemical compositional analysis of alumina grit for confirming to specification becomes an essential step in the Quality Assurance (QA) programme for acceptance of the material. The present paper describes the analytical methodology followed in our laboratory for the chemical analysis of alumina grit samples used in the grit blasting operations

  18. Multifunctional substrates of thin porous alumina for cell biosensors

    KAUST Repository

    Toccafondi, Chiara

    2014-02-27

    We have fabricated anodic porous alumina from thin films (100/500 nm) of aluminium deposited on technological substrates of silicon/glass, and investigated the feasibility of this material as a surface for the development of analytical biosensors aiming to assess the status of living cells. To this goal, porous alumina surfaces with fixed pitch and variable pore size were analyzed for various functionalities. Gold coated (about 25 nm) alumina revealed surface enhanced Raman scattering increasing with the decrease in wall thickness, with factor up to values of approximately 104 with respect to the flat gold surface. Bare porous alumina was employed for micro-patterning and observation via fluorescence images of dye molecules, which demonstrated the surface capability for a drug-loading device. NIH-3T3 fibroblast cells were cultured in vitro and examined after 2 days since seeding, and no significant (P > 0.05) differences in their proliferation were observed on porous and non-porous materials. The effect on cell cultures of pore size in the range of 50–130 nm—with pore pitch of about 250 nm—showed no significant differences in cell viability and similar levels in all cases as on a control substrate. Future work will address combination of all above capabilities into a single device.

  19. Gas and surface diffusion in modified γ-alumina systems

    NARCIS (Netherlands)

    Uhlhorn, R.J.R.; Keizer, K.; Burggraaf, A.J.

    1989-01-01

    The transport of pure gases through a microporous membrane is described. The alumina-based membrane (pores 2.5-4 nm) is suitable for Knudsen diffusion separation. To improve the separation factor, interaction with and mobility on the pore wall of one of the gases of a mixture is necessary. To introd

  20. Controlled growth of single nanowires within a supported alumina template

    Energy Technology Data Exchange (ETDEWEB)

    Vlad, A [Unite de Dispositifs Integres et Circuits Electroniques, Universite Catholique de Louvain (UCL), Place de Levant, 3, B-1348 Louvain-la-Neuve (Belgium); Matefi-Tempfli, M [Unite de Physico-Chimie et de Physique des Materiaux, UCL, Place Croix du Sud, 1, B-1348 Louvain-la-Neuve (Belgium); Faniel, S [Unite de Dispositifs Integres et Circuits Electroniques, Universite Catholique de Louvain (UCL), Place de Levant, 3, B-1348 Louvain-la-Neuve (Belgium); Bayot, V [Unite de Dispositifs Integres et Circuits Electroniques, Universite Catholique de Louvain (UCL), Place de Levant, 3, B-1348 Louvain-la-Neuve (Belgium); Melinte, S [Unite de Dispositifs Integres et Circuits Electroniques, Universite Catholique de Louvain (UCL), Place de Levant, 3, B-1348 Louvain-la-Neuve (Belgium); Piraux, L [Unite de Physico-Chimie et de Physique des Materiaux, UCL, Place Croix du Sud, 1, B-1348 Louvain-la-Neuve (Belgium); Matefi-Tempfli, S [Unite de Physico-Chimie et de Physique des Materiaux, UCL, Place Croix du Sud, 1, B-1348 Louvain-la-Neuve (Belgium)

    2006-10-14

    A simple technique for fabricating single nanowires with well-defined position is presented. The process implies the use of a silicon nitride mask for selective electrochemical growth of the nanowires in a porous alumina template. We show that this method allows the realization of complex nanowire patterns as well as arrays of single nanowires with a precise position and spacing.

  1. Controlled growth of single nanowires within a supported alumina template

    Science.gov (United States)

    Vlad, A.; Mátéfi-Tempfli, M.; Faniel, S.; Bayot, V.; Melinte, S.; Piraux, L.; Mátéfi-Tempfli, S.

    2006-10-01

    A simple technique for fabricating single nanowires with well-defined position is presented. The process implies the use of a silicon nitride mask for selective electrochemical growth of the nanowires in a porous alumina template. We show that this method allows the realization of complex nanowire patterns as well as arrays of single nanowires with a precise position and spacing.

  2. Alumina-encapsulated vaccine formulation with improved thermostability and immunogenicity.

    Science.gov (United States)

    Zhou, Hangyu; Wang, Guangchuan; Li, Xiao-Feng; Li, Yaling; Zhu, Shun-Ya; Qin, Cheng-Feng; Tang, Ruikang

    2016-05-11

    Developing vaccine formulations with excellent thermostability and immunogenicity remains a great challenge. By in situ encapsulating a live-attenuated strain of human enterovirus 71 (EV71) in alumina, we obtained a robust vaccine formulation named EV71@NanoAlum, which features significantly enhanced thermostability and immunogenicity. This attempt follows a material-based tactic for vaccine improvement. PMID:27098047

  3. Structure and surface properties of praseodymium modified alumina

    Energy Technology Data Exchange (ETDEWEB)

    Tankov, I. [Institute of Catalysis, Bulgarian Academy of Sciences, 1113 Sofia (Bulgaria); Pawelec, B. [Instituto de Catalisis y Petroleoquimica, CSIC, Cantoblanco, 28049 Madrid (Spain); Arishtirova, K. [Institute of Catalysis, Bulgarian Academy of Sciences, 1113 Sofia (Bulgaria); Damyanova, S., E-mail: soniad@ic.bas.bg [Institute of Catalysis, Bulgarian Academy of Sciences, 1113 Sofia (Bulgaria)

    2011-10-15

    Mixed PrO{sub 2}-Al{sub 2}O{sub 3} oxides with different PrO{sub 2} content (1-20 wt.%) were prepared by wetness impregnation of {gamma}-alumina with aqueous solution of praseodymium nitrate. The samples were characterized by different techniques, using surface adsorption-desorption of N{sub 2} (S{sub BET}), thermogravimetric analysis (TGA), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), UV-vis diffuse reflectance spectroscopy (DRS), temperature-programmed reduction (TPR) and temperature-programmed desorption of CO{sub 2} (TPD-CO{sub 2}). TGA and XRD showed the presence of small praseodymium oxide species on the alumina surface. XPS and DRS detected electron deficient interaction between deposited praseodymium oxide and alumina. It was observed a lower reduction temperature for supported Pr oxide species compared to that of the bulk Pr{sub 6}O{sub 11}. TPD-CO{sub 2} studies suggested that the deposition of Pr oxide on alumina leaded to increase of the basicity of mixed oxides.

  4. N-doped mesoporous alumina for adsorption of carbon dioxide

    Institute of Scientific and Technical Information of China (English)

    Jayshri A.Thote; Ravikrishna V.Chatti; Kartik S.Iyer; Vivek Kumar; Arti N.Valechha; Nitin K.Labhsetwar; Rajesh B.Biniwale; M.K.N.Yenkie; Sadhana S.Rayalu

    2012-01-01

    N-doped mesoporous alumina has been synthesized using chitosan as the biopolymer template.The adsorbent has been thoroughly investigated for the adsorption of CO2 from a simulated flue gas stream (15% CO2 balanced with N2) and compared with commercially available mesoporous alumina procured from SASOL,Germany.CO2 adsorption was studied under different conditions of pretreatment and adsorption temperature,inlet CO2 concentration and in the presence of oxygen and moisture.The adsorption capacity was determined to be 29.4 mg CO2/g of adsorbent at 55℃.This value was observed to be 4 times higher in comparison to that of commercial mesoporous alumina at a temperature of 55℃.Basicity of alumina surface coupled with the presence of nitrogen in template in synthesized sample is responsible for this enhanced CO2 adsorption.Adsorption capacity for CO2 was retained in the presence of oxygen; however moisture had a deteriorating effect on the adsorption capacity reducing it to nearly half the value.

  5. Dynamical stability of the alpha and theta phases of alumina

    DEFF Research Database (Denmark)

    Lodziana, Zbigniew; Parlinski, K.

    2003-01-01

    Using density functional calculations the phonon dispersion relations, phonon density of states, and free energy of theta and alpha phases of alumina are investigated. The temperature dependence of the free energy indicates that entropy contributes to the destabilization of the alpha phase at the...

  6. State of the art: alumina ceramics for energy applications

    International Nuclear Information System (INIS)

    Prominent ceramic raw materials and products manufacturers were surveyed to determine the state of the art for alumina ceramic fabrication. This survey emphasized current capabilities and limitations for fabrication of large, high-density, high-purity, complex shapes. Some directions are suggested for future needs and development

  7. Effects of maternal exposure to nano-alumina during pregnancy on neurodevelopment in offspring mice

    Institute of Scientific and Technical Information of China (English)

    丁勇

    2013-01-01

    Objective To observe the effects of maternal exposure to nano-alumina during pregnancy on the neurodevelopment in offspring mice.Methods Female ICR mice were exposed to nano-alumina 10 d before mating,and the nano-alumina exposure lasted till offspring mice were born.All the female mice were randomly divided into 5groups:solvent control group (saline) ,nano-carbon group (11.76 mg/ml) ,microalumina group (50 mg/ml) ,50 nm alumina group (50 mg/ml) ,and 13 nm alumina group (50 mg/ml) .All the mice were treated by

  8. The Adsorption of Cr(VI Using Chitosan-Alumina Adsorbent

    Directory of Open Access Journals (Sweden)

    Darjito Darjito

    2013-12-01

    Full Text Available Chitosan as adsorbent has been used widely, however it was not effective yet for metal ions adsorption in industrial scale. In acidic condition, chitosan’s active site tends to decrease. This drawback can was solved by coating of chitosan active site on alumina. This paper discloses to overcome that limitation. The charateristic of the active side was analysed by FTIR spectrometry toward vibration N-H group at 1679.15 cm-1, C=O group of oxalate at 1703.30 cm-1, and Al-O group of alumina at 924.07 cm-1. The adsorption capacity of the developed adsorbent was tester to adsorb Cr(VI ions under various of pH value such as 1, 2, 3, 4, 5, 6, and 7. The contact time affect toward the adsorption was also reported in 20, 30, 40 50, 60, 70, and 80 minute. In addition, the concentration effects (100, 200, 300, 400, 500, and 600 ppm was also studied. Chromium (VI was measured using spectronic-20. Adsorption capacity was obtained at 66.90 mg/g under optimum conditions pH 2, and contact time 60 minute, respectively.

  9. The Adsorption of Cr(VI Ions Using Chitosan-Alumina Adsorbent

    Directory of Open Access Journals (Sweden)

    Darjito Darjito

    2014-06-01

    Full Text Available Chitosan as adsorbent has been used widely, however it was not effective yet for metal ions adsorption in industrial scale. In acidic condition, chitosan’s active site tends to decrease. This drawback can was solved by coating of chitosan active site on alumina. This paper discloses to overcome that limitation. The charateristic of the active side was analysed by FTIR spectrometry toward vibration N-H group at 1679.15 cm-1, C=O group of oxalate at 1703.30 cm-1, and Al-O group of alumina at 924.07 cm-1. The adsorption capacity of the developed adsorbent was tester to adsorb Cr(VI ions under various of pH value such as 1, 2, 3, 4, 5, 6, and 7. The contact time affect toward the adsorption was also reported in 20, 30, 40 50, 60, 70, and 80 minute. In addition, the concentration effects (100, 200, 300, 400, 500, and 600 ppm was also studied. Chromium (VI was measured using spectronic-20. Adsorption capacity was obtained at 66.90 mg/g under optimum conditions pH 2, and contact time 60 minute, respectively.

  10. Proceedings of the workshop on neutron instrumentation for a long-pulse spallation source

    International Nuclear Information System (INIS)

    This workshop was carried out under the auspices of the Lawrence Berkeley National Laboratory Pulsed Spallation Source activity and its Pulsed Spallation Source Committee (PSSC). One of our activities has been the sponsorship of workshops related to neutron production by pulsed sources. At the Crystal City PSSC meeting a decision was made to hold a workshop on the instrumentation opportunities at a long-pulse spallation source (LPSS). The enclosed material represents the results of deliberations of the three working groups into which the participants were divided, covering elastic scattering, inelastic scattering and fundamental physics, as well as contributions from individual participants. We hope that the material in this report will be useful to the neutron scattering community as it develops a road-map for future neutron sources. The workshop was held at LBNL in mid-April with about sixty very dedicated participants from the US and abroad. This report presents the charge for the workshop: Based on the bench mark source parameters provided by Gary Russell, determine how a suite of spectrometers in each of the three working group's area of expertise would perform at an LPSS and compare this performance with that of similar spectrometers at a continuous source or a short-pulse source. Identify and discuss modifications to these spectrometers that would enhance their performance at an LPSS. Identify any uncertainties in the analysis of spectrometer performance that require further research. Describe what R ampersand D is needed to resolve these issues. Discuss how the performance of instruments would be affected by changes in source parameters such as repetition rate, proton pulse length, and the characteristic time of pulse tails. Identify beneficial changes that could become goals for target/moderator designers. Identify novel methods that might be applied at an LPSS. Selected papers are indexed separately for inclusion in the Energy Science and Technology

  11. Advanced morphological analysis of patterns of thin anodic porous alumina

    International Nuclear Information System (INIS)

    Different conditions of fabrication of thin anodic porous alumina on glass substrates have been explored, obtaining two sets of samples with varying pore density and porosity, respectively. The patterns of pores have been imaged by high resolution scanning electron microscopy and analyzed by innovative methods. The regularity ratio has been extracted from radial profiles of the fast Fourier transforms of the images. Additionally, the Minkowski measures have been calculated. It was first observed that the regularity ratio averaged across all directions is properly corrected by the coefficient previously determined in the literature. Furthermore, the angularly averaged regularity ratio for the thin porous alumina made during short single-step anodizations is lower than that of hexagonal patterns of pores as for thick porous alumina from aluminum electropolishing and two-step anodization. Therefore, the regularity ratio represents a reliable measure of pattern order. At the same time, the lower angular spread of the regularity ratio shows that disordered porous alumina is more isotropic. Within each set, when changing either pore density or porosity, both regularity and isotropy remain rather constant, showing consistent fabrication quality of the experimental patterns. Minor deviations are tentatively discussed with the aid of the Minkowski measures, and the slight decrease in both regularity and isotropy for the final data-points of the porosity set is ascribed to excess pore opening and consequent pore merging. - Highlights: • Thin porous alumina is partly self-ordered and pattern analysis is required. • Regularity ratio is often misused: we fix the averaging and consider its spread. • We also apply the mathematical tool of Minkowski measures, new in this field. • Regularity ratio shows pattern isotropy and Minkowski helps in assessment. • General agreement with perfect artificial patterns confirms the good manufacturing

  12. Advanced morphological analysis of patterns of thin anodic porous alumina

    Energy Technology Data Exchange (ETDEWEB)

    Toccafondi, C. [Istituto Italiano di Tecnologia, Department of Nanophysics, Via Morego 30, Genova I 16163 (Italy); Istituto Italiano di Tecnologia, Department of Nanostructures, Via Morego 30, Genova I 16163 (Italy); Stępniowski, W.J. [Department of Advanced Materials and Technologies, Faculty of Advanced Technologies and Chemistry, Military University of Technology, 2 Kaliskiego Str., 00-908 Warszawa (Poland); Leoncini, M. [Istituto Italiano di Tecnologia, Department of Nanostructures, Via Morego 30, Genova I 16163 (Italy); Salerno, M., E-mail: marco.salerno@iit.it [Istituto Italiano di Tecnologia, Department of Nanophysics, Via Morego 30, Genova I 16163 (Italy)

    2014-08-15

    Different conditions of fabrication of thin anodic porous alumina on glass substrates have been explored, obtaining two sets of samples with varying pore density and porosity, respectively. The patterns of pores have been imaged by high resolution scanning electron microscopy and analyzed by innovative methods. The regularity ratio has been extracted from radial profiles of the fast Fourier transforms of the images. Additionally, the Minkowski measures have been calculated. It was first observed that the regularity ratio averaged across all directions is properly corrected by the coefficient previously determined in the literature. Furthermore, the angularly averaged regularity ratio for the thin porous alumina made during short single-step anodizations is lower than that of hexagonal patterns of pores as for thick porous alumina from aluminum electropolishing and two-step anodization. Therefore, the regularity ratio represents a reliable measure of pattern order. At the same time, the lower angular spread of the regularity ratio shows that disordered porous alumina is more isotropic. Within each set, when changing either pore density or porosity, both regularity and isotropy remain rather constant, showing consistent fabrication quality of the experimental patterns. Minor deviations are tentatively discussed with the aid of the Minkowski measures, and the slight decrease in both regularity and isotropy for the final data-points of the porosity set is ascribed to excess pore opening and consequent pore merging. - Highlights: • Thin porous alumina is partly self-ordered and pattern analysis is required. • Regularity ratio is often misused: we fix the averaging and consider its spread. • We also apply the mathematical tool of Minkowski measures, new in this field. • Regularity ratio shows pattern isotropy and Minkowski helps in assessment. • General agreement with perfect artificial patterns confirms the good manufacturing.

  13. On the pressure wave problem in liquid metal targets for pulsed spallation neutron sources

    International Nuclear Information System (INIS)

    A liquid metal target for a pulsed spallation source was modelled on the computer to investigate the effect of the high instantaneous power deposition (60 KJ in 1 μs) on the pressure in the liquid and the resulting stress on the container. It was found that for the short pulse duration the resulting stress would be likely to exceed the allowable design stress for steels of the HT-9 type with low nickel content. Adding a small volume fraction of gas bubbles might be a way to suppress almost completely the generation of pressure waves. (author) 12 figs., 5 refs

  14. Electron cloud development in the Proton Storage Ring and in the Spallation Neutron Source

    OpenAIRE

    Pivi, M.T.F.; Furman, M.A.

    2002-01-01

    We have applied our simulation code "POSINST" to evaluate the contribution to the growth rate of the electron-cloud instability in proton storage rings. Recent simulation results for the main features of the electron cloud in the storage ring of the Spallation Neutron Source (SNS) at Oak Ridge, and updated results for the Proton Storage Ring (PSR) at Los Alamos are presented in this paper. A key ingredient in our model is a detailed description of the secondary emitted-electron energy sp...

  15. Bond strength, bond stress and spallation mechanisms of thermal barrier coatings

    Energy Technology Data Exchange (ETDEWEB)

    Gell, M.; Krishnakumar, V.; McCarron, K.; Barber, B.; Sohn, Y.-H. [Connecticut Univ., Storrs, CT (United States). Dept. of Metall. and Mater. Eng.; Eric, J. [Connecticut Univ., Storrs, CT (United States). Dept. of Mechanical Engineering; Tolpygo, V.K.

    1999-11-01

    Five production thermal barrier coatings were thermally cycled between room temperature and 1121 C (2050 F) to determine relative spallation life. Bond strength measurements were made using a modified ASTM direct pull-test. Bond stress measurements were made in the thermally grown oxide using a laser photoluminescence technique. Bond strength and bond stress measurements were conducted on two electron beam physical vapor deposition coatings as a function of thermal cycling. Each coating showed characteristic values of as-coated strength and stress and changes in strength and stress with thermal cycling. These variations in strength and stress with thermal cycling are related to oxidation and micro-debonding effects. (orig.)

  16. High-power spallation target using a heavy liquid metal free surface flow

    International Nuclear Information System (INIS)

    A prototype of a heavy liquid metal free surface target as proposed for the multi-purpose hybrid research reactor for high-tech applications in Mol, Belgium, has been set up and experimentally investigated at the Karlsruhe Liquid Metal Laboratory. A stable operation was demonstrated in a wide range of operating conditions and the surface shape was detected and compared with numerical pre-calculations employing Star-CD. Results show a very good agreement of experiment and numerical predictions which is an essential input for other windowless target designs like the META:LIC target for the European Spallation Source. (author)

  17. Bond strength, bond stress and spallation mechanisms of thermal barrier coatings

    International Nuclear Information System (INIS)

    Five production thermal barrier coatings were thermally cycled between room temperature and 1121 C (2050 F) to determine relative spallation life. Bond strength measurements were made using a modified ASTM direct pull-test. Bond stress measurements were made in the thermally grown oxide using a laser photoluminescence technique. Bond strength and bond stress measurements were conducted on two electron beam physical vapor deposition coatings as a function of thermal cycling. Each coating showed characteristic values of as-coated strength and stress and changes in strength and stress with thermal cycling. These variations in strength and stress with thermal cycling are related to oxidation and micro-debonding effects. (orig.)

  18. Spallation Neutrons and Pressure SNAP DE-FG02-03ER46085 CLOSE-OUT MAY 2009

    Energy Technology Data Exchange (ETDEWEB)

    Parise, John B

    2009-05-22

    The purpose of the grant was to build a community of scientist and to draw upon their expertise to design and build the world's first dedicated high pressure beamline at a spallation source - the so called Spallation Neutron And Pressure (SNAP) beamline at the Spallation Neutron Source (SNS) at OAk Ridge NAtional LAboratory. . Key to this endeavor was an annual meeting attended by the instrument design team and the executive committee. The discussions at those meeting set an ambitious agenda for beamline design and construction and highlighted key science areas of interest for the community. This report documents in 4 appendices the deliberations at the annual SNAP meetings and the evolution of the beamline optics from concept to construction. The appendices also contain key science opportunities for extreme conditions research.

  19. Spallation Source Modelling for an ADS Using the MCNPX and GEANT4 Packages for Sensitivity Analysis of Reactivity

    Science.gov (United States)

    Antolin, M. Q.; Marinho, F.; Palma, D. A. P.; Martinez, A. S.

    2014-04-01

    A simulation for the time evolution of the MYRRHA conceptual reactor was developed. The SERPENT code was used to simulate the nuclear fuel depletion and the spallation source which drives the system was simulated using both MCNPX and GEANT4 packages. The obtained results for the neutron energy spectrum from the spallation are coherent with each other and were used as input for the SERPENT code which simulated a constant power operation regime. The obtained results show that the criticality of the system is not sensitive to the spallation models employed and only relative small deviations with respect to the inverse kinetic model coming from the point kinetic equations proposed by Gandini were observed.

  20. Processing and Mechanical Properties of Various Zirconia/Alumina Composites for Fuel Cell Applications

    Science.gov (United States)

    Choi, Sung R.; Bansal, Narottam P.

    2002-01-01

    Various electrolyte materials for solid oxide fuel cells were fabricated by hot pressing 10 mol% yttria-stabilized zirconia (10-YSZ) reinforced with two different forms of alumina, particulates and platelets, each containing 0 to 30 mol% alumina. Flexure strength and fracture toughness of both particulate and platelet composites at ambient temperature increased with increasing alumina content, reaching a maximum at 30 mot% alumina. For a given alumina content, strength of particulate composites was greater than that of platelet composites, whereas, the difference in fracture toughness between the two composite systems was negligible. No virtual difference in elastic modulus and density was observed for a given alumina content between particulate and platelet composites. Thermal cycling up to 10 cycles between 200 to 1000 C did not show any effect on strength degradation of the 30 mol% platelet composites, indicative of negligible influence of CTE mismatches between YSZ matrix and alumina grains.

  1. Study on the bound water of several high specific surface-area oxides (beryllia, alumina, silica-alumina)

    International Nuclear Information System (INIS)

    This study is concerned with the bound water of several oxides (beryllia, alumina, silica-alumina) at different steps of their dehydration (heating temperatures between 150 and 1100 deg. C). The following techniques have been used simultaneously: Thermal analysis (a new method has been developed), nitrogen adsorption (study of the texture), Diborane hydrolysis (qualitative and quantitative analysis of surface water), Infra-red spectrography (in the absorption range of water), Nuclear magnetic resonance (in the resonance range of protons). Thanks to these different techniques, five kinds of bound water have been observed. Attention is called on the great influence of the thermal treatment conditions on the evolution of the products resulting from the decomposition of alumina α-trihydrate Al(OH)3 and beryllium α-hydroxide, in the course of the dehydration. Moreover, the author emphasizes the peculiar properties of the two kinds of oxides (alumina and beryllia) prepared through a new method of treatment under low pressure and constant speed of decomposition. Such particular features concern mainly texture, bound water, and consequently, also catalytic activity. (author)

  2. Porous alumina, zirconia and alumina/zirconia for bone repair: fabrication, mechanical and in vitro biological response.

    Science.gov (United States)

    Hadjicharalambous, Chrystalleni; Buyakov, Ales; Buyakova, Svetlana; Kulkov, Sergey; Chatzinikolaidou, Maria

    2015-04-23

    Zirconia (ZrO2) and alumina (Al2O3) based ceramics are widely used for load-bearing applications in bone repair due to their excellent mechanical properties and biocompatibility. They are often regarded as bioinert since no direct bone-material interface is created unless a porous structure intercedes, leading to better bone bonding. In this regard, investigating interactions between cells and porous ceramics is of great interest. In the present study, we report on the successful fabrication of sintered alumina A-61, zirconia Z-50 and zirconia/alumina composite ZA-60 ceramics with medium porosities of 61, 50 and 60%, respectively, indicating a bimodal pore size distribution and good interconnectivity. They exhibit elastic moduli of 3-10 GPa and compressive strength values of 60-240 MPa, similar to those of human cortical bone.We performed in vitro cell-material investigations comparing the adhesion, proliferation and differentiation of mouse pre-osteoblasts MC3T3-E1 on the three porous materials. While all three ceramics demonstrate a strong cell attachment, better cell spreading is observed on zirconia-containing substrates. Significantly higher cell growth was quantified on the latter ceramics, revealing an increased alkaline phosphatase activity, higher collagen production and increased calcium biomineralization compared to A-61. Hence, these porous zirconia-containing ceramics elicit superior biological responses over porous alumina of similar porosity, promoting enhanced biological interaction, with potential use as non-degradable bone grafts or as implant coatings.

  3. EFFECTIVE ELASTIC PROPERTIES OF ALUMINA-ZIRCONIA COMPOSITE CERAMICS - PART 4. TENSILE MODULUS OF POROUS ALUMINA AND ZIRCONIA

    Directory of Open Access Journals (Sweden)

    W. Pabst

    2004-12-01

    Full Text Available In this fourth paper of a series on the effective elastic properties of alumina-zirconia composite ceramics the influence of porosity on the effective tensile modulus of alumina and zirconia ceramics is discussed. The examples investigated are alumina and zirconia ceramics prepared from submicron powders by starch consolidation casting using two different types of starch, potato starch (median size D50 =47.2 µm and corn starch (median size D50 =13.7 µm. The dependence of effective tensile moduli E, on the porosity f, measured for porosities in the ranges of approx. 19-55 vol.% and 10-42 vol.% for alumina and zirconia, respectively, using a resonant frequency technique, was evaluated by fitting with various model relations, including newly developed ones. A detailed comparison of the fitting results suggests the superiority of the new relation E/E0 = (1 - f·(1 - f/fC, developed by the authors (with the tensile modulus of the dense ceramic material E0 and the critical porosity fC, over most other existing fit models. Only for special purposes and well-behaved data sets the recently proposed exponential relation E/E0 = exp [-Bf/(1 - f] and the well-known Phani-Niyogi relation E/E0 = (1 - f/fCN might be preferable.

  4. The reactive element effect of ceria particle dispersion on alumina growth: A model based on microstructural observations

    Science.gov (United States)

    Wang, X.; Peng, X.; Tan, X.; Wang, F.

    2016-07-01

    The oxidation kinetics of alumina-forming metals can be affected by adding a small amount of a reactive (normally rare earth) element oxide (RExOy) and the segregation of the reactive element (RE) ions to the growing alumina grain boundaries (GBs) has been considered as a responsible reason. However, this interpretation remains a controversial issue as to how RE ions are produced by RExOy which is thermodynamically and chemically stable in metals. The question is answered by a model that is based on transmission electron microscopy (TEM) investigation of a CeO2-dispersed nickel aluminide oxidized in air at 1100 °C. The CeO2 dispersion is incorporated into the alumina scale by the inward growth of inner α-Al2O3, where it partially dissolves producing tetravalent Ce cations which then transform to trivalent cations by trapping electrons. The trivalent cations segregate to the α-Al2O3 GBs and diffuse outward along first the GBs and later the twin boundaries (TBs) in the outer γ-Al2O3 layer, being precipitated as Ce2O3 particles near surface.

  5. PREPARATION AND TESTING OF CORROSIONAND SPALLATION-RESISTANT COATINGS

    Energy Technology Data Exchange (ETDEWEB)

    Hurley, John

    2014-11-01

    has been entered into a finite element model using ANSYS so that appropriate force-applying structures can be designed for use in joining structures composed of APMT and the nickel alloys. Finite element modeling has been performed to finalize the fabrication geometry for the corrosion-testing phase. The addition of another bolt increases stress uniformity away from the region where the clamping is applied. It appears that a bolt spacing of approximately 25 mm in each jig is appropriate. This will allow the fabrication of 50-mm-wide sections of joints for the corrosion-testing task. Gasifier sampling activities continue to determine what types of trace contaminants may occur in cleaned syngas that could lead to corrosion or deposition in turbines firing coal syngas. The EERC has several pilot-scale gasifiers that are continually used in a variety of test configurations as determined by the needs of the projects that are funding the tests. We are sampling both noncombusted and combusted syngas produced during some of the pilot-scale gasifier tests. This year sampling was performed of both syngas and combusted syngas while the entrained-flow gasifier (EFG) was firing subbituminous coal from the Antelope Mine in Wyoming. Results of scanning electron microscope analyses of the syngas before combustion showed no submicron particles, only flakes of iron oxide that had likely formed on steel surfaces inside the combustor. As shown in the 2013 annual report, soot was also collected from the syngas when the much-lower-temperature fluid-bed gasifier (FBG) was fired, indicating that the much higher temperature of the EFG prevented soot formation. However, particles collected from the combusted syngas consist almost entirely of submicron soot, and little to no vaporized metals made it past the warm-gas filters and scrubbers in the high-temperature EFG system which could then deposit in a turbine system burning a higher hydrogen syngas. These results are consistent with the

  6. Preparation and testing of corrosion and spallation-resistant coatings

    Energy Technology Data Exchange (ETDEWEB)

    Hurley, John

    2012-09-30

    This Energy & Environmental Research Center (EERC) project is designed to determine if plating APMT, a specific highly oxidation-resistant oxide dispersion-strengthened FeCrAl alloy made by Kanthal, onto nickel-based superalloy turbine parts is a viable method for substantially improving the lifetimes and maximum use temperatures of the parts. The method for joining the APMT plate to the superalloys is called evaporative metal bonding. It involves placing a thin foil of zinc (Zn) between the plate and the superalloy, clamping them together, and heating in an atmosphere-controlled furnace. Upon heating, the Zn melts and dissolves the oxide skins of the alloys at the bond line, allowing the two alloys to diffuse into each other. The Zn then diffuses through the alloys and evaporates from their surfaces. Laboratory testing has shown that the diffusion rate of Zn through the FeCrAl alloy is much faster than through the nickel superalloys. This means that the FeCrAl will serve as a sink for the Zn bonding alloy during the evaporative metal bonding process. Also, the testing has shown that the Zn diffusion mechanism is bulk diffusion, and not intergranular. This is a surprise. However, it means that quantification of the Zn diffusivities in these samples will be significantly simpler than would have been the case if grain boundary diffusion dominated. In addition to the laboratory testing, gas impinger and particulate samples are being collected from a combustor firing syngas and natural gas to determine what types of microcontaminants may reach a turbine firing syngas. The syngas is created in one of two different pilot-scale pressurized coal gasifiers. The initial analysis of the impinger solutions was for standard U.S. Environmental Protection Agency (EPA) Method 29 determination of hazardous metals and did not include major element analysis. When syngas is fired, the amount of Mn in the combustor gas increases substantially. Halogens (Br2 and Cl2) and hydrogen

  7. Quantum molecular dynamics approach to estimate spallation yield from + 208Pb reaction at 800 MeV

    Indian Academy of Sciences (India)

    P K Sarkar; Maitreyee Nandy

    2003-10-01

    The spallation yield of neutrons and other mass fragments produced in 800 MeV proton induced reaction on 208Pb have been calculated in the framework of quantum molecular dynamics (QMD) model. The energy spectra and angular distribution have been calculated. Also, multiplicity distributions of the emitted neutrons and kinetic energy carried away by them have been estimated and compared with the available experimental data. The agreement is satisfactory. A major contribution to the neutron emission comes from statistical decay of the fragments. For mass and charge distributions of spallation productsthe QMD process gives rise to target-like and projectile-like fragments only.

  8. Pressure and stress waves in a spallation neutron source mercury target generated by high-power proton pulses

    CERN Document Server

    Futakawa, M; Conrad, H; Stechemesser, H

    2000-01-01

    The international ASTE collaboration has performed a first series of measurements on a spallation neutron source target at the Alternating Gradient Synchrotron (AGS) in Brookhaven. The dynamic response of a liquid mercury target hit by high-power proton pulses of about 40 ns duration has been measured by a laser Doppler technique and compared with finite elements calculations using the ABAQUS code. It is shown that the calculation can describe the experimental results for at least the time interval up to 100 mu s after the pulse injection. Furthermore, it has been observed that piezoelectric pressure transducers cannot be applied in the high gamma-radiation field of a spallation target.

  9. Proceedings of the workshop on ion source issues relevant to a pulsed spallation neutron source: Part 2 workshop presentations

    Energy Technology Data Exchange (ETDEWEB)

    Schroeder, L.; Leung, Ka-Ngo; Alonso, J. [eds.

    1994-10-01

    As part of the Lawrence Berkeley Laboratory Pulsed Spallation Source study, this Workshop was convened to address ion-source technology`s present status with respect to the next-generation Pulsed Spallation Source in the 1-5 MW range for the neutron scattering community. Considerations of Low Energy Beam Transport (LEBT) parameters and designs were included in the discussions throughout the Workshop. Ion-source requirements and actually-achieved performances were assessed, resulting in a determination of research and development requirements to bridge the gap. Part 1 of these Proceedings summarizes the Workshop; Part 2 contains viewgraphs of Workshop presentations.

  10. Proceedings of the workshop on ion source issues relevant to a pulsed spallation neutron source: Part 2 workshop presentations

    International Nuclear Information System (INIS)

    As part of the Lawrence Berkeley Laboratory Pulsed Spallation Source study, this Workshop was convened to address ion-source technology's present status with respect to the next-generation Pulsed Spallation Source in the 1-5 MW range for the neutron scattering community. Considerations of Low Energy Beam Transport (LEBT) parameters and designs were included in the discussions throughout the Workshop. Ion-source requirements and actually-achieved performances were assessed, resulting in a determination of research and development requirements to bridge the gap. Part 1 of these Proceedings summarizes the Workshop; Part 2 contains viewgraphs of Workshop presentations

  11. Electrostatic levitation facility optimized for neutron diffraction studies of high temperature liquids at a spallation neutron source.

    Science.gov (United States)

    Mauro, N A; Vogt, A J; Derendorf, K S; Johnson, M L; Rustan, G E; Quirinale, D G; Kreyssig, A; Lokshin, K A; Neuefeind, J C; An, Ke; Wang, Xun-Li; Goldman, A I; Egami, T; Kelton, K F

    2016-01-01

    Neutron diffraction studies of metallic liquids provide valuable information about inherent topological and chemical ordering on multiple length scales as well as insight into dynamical processes at the level of a few atoms. However, there exist very few facilities in the world that allow such studies to be made of reactive metallic liquids in a containerless environment, and these are designed for use at reactor-based neutron sources. We present an electrostatic levitation facility, NESL (for Neutron ElectroStatic Levitator), which takes advantage of the enhanced capabilities and increased neutron flux available at spallation neutron sources (SNSs). NESL enables high quality elastic and inelastic neutron scattering experiments to be made of reactive metallic and other liquids in the equilibrium and supercooled temperature regime. The apparatus is comprised of a high vacuum chamber, external and internal neutron collimation optics, and a sample exchange mechanism that allows up to 30 samples to be processed between chamber openings. Two heating lasers allow excellent sample temperature homogeneity, even for samples approaching 500 mg, and an automated temperature control system allows isothermal measurements to be conducted for times approaching 2 h in the liquid state, with variations in the average sample temperature of less than 0.5%. To demonstrate the capabilities of the facility for elastic scattering studies of liquids, a high quality total structure factor for Zr64Ni36 measured slightly above the liquidus temperature is presented from experiments conducted on the nanoscale-ordered materials diffractometer (NOMAD) beam line at the SNS after only 30 min of acquisition time for a small sample (∼100 mg). PMID:26827330

  12. Electrostatic levitation facility optimized for neutron diffraction studies of high temperature liquids at a spallation neutron source

    Science.gov (United States)

    Mauro, N. A.; Vogt, A. J.; Derendorf, K. S.; Johnson, M. L.; Rustan, G. E.; Quirinale, D. G.; Kreyssig, A.; Lokshin, K. A.; Neuefeind, J. C.; An, Ke; Wang, Xun-Li; Goldman, A. I.; Egami, T.; Kelton, K. F.

    2016-01-01

    Neutron diffraction studies of metallic liquids provide valuable information about inherent topological and chemical ordering on multiple length scales as well as insight into dynamical processes at the level of a few atoms. However, there exist very few facilities in the world that allow such studies to be made of reactive metallic liquids in a containerless environment, and these are designed for use at reactor-based neutron sources. We present an electrostatic levitation facility, NESL (for Neutron ElectroStatic Levitator), which takes advantage of the enhanced capabilities and increased neutron flux available at spallation neutron sources (SNSs). NESL enables high quality elastic and inelastic neutron scattering experiments to be made of reactive metallic and other liquids in the equilibrium and supercooled temperature regime. The apparatus is comprised of a high vacuum chamber, external and internal neutron collimation optics, and a sample exchange mechanism that allows up to 30 samples to be processed between chamber openings. Two heating lasers allow excellent sample temperature homogeneity, even for samples approaching 500 mg, and an automated temperature control system allows isothermal measurements to be conducted for times approaching 2 h in the liquid state, with variations in the average sample temperature of less than 0.5%. To demonstrate the capabilities of the facility for elastic scattering studies of liquids, a high quality total structure factor for Zr64Ni36 measured slightly above the liquidus temperature is presented from experiments conducted on the nanoscale-ordered materials diffractometer (NOMAD) beam line at the SNS after only 30 min of acquisition time for a small sample (˜100 mg).

  13. Electrostatic levitation facility optimized for neutron diffraction studies of high temperature liquids at a spallation neutron source

    Energy Technology Data Exchange (ETDEWEB)

    Mauro, N. A., E-mail: namauro@noctrl.edu [Department of Physics, North Central College, Naperville, Illinois 60540 (United States); Vogt, A. J. [Instrument and Source Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States); Derendorf, K. S. [Mechanical Engineering and Materials Science, Washington University, St. Louis, Missouri 63130 (United States); Johnson, M. L.; Kelton, K. F. [Department of Physics and Institute of Materials Science and Engineering, Washington University, 1 Brookings Drive, St. Louis, Missouri 63130 (United States); Rustan, G. E.; Quirinale, D. G.; Goldman, A. I. [Department of Physics and Astronomy, Iowa State University, Ames, Iowa 50011 (United States); Kreyssig, A. [Department of Physics and Astronomy, Iowa State University, Ames, Iowa 50011 (United States); Division of Materials Sciences and Engineering, Ames Laboratory, Ames, Iowa 50011 (United States); Lokshin, K. A. [Department of Materials Science and Engineering, University of Tennessee, Knoxville, Tennessee 37996 (United States); Quantum Condensed Matter Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States); Neuefeind, J. C.; An, Ke [Chemical and Engineering Materials Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States); Wang, Xun-Li [Department of Physics and Materials Science, City University of Hong Kong, 83 Tat Chee Ave., Kowloon (Hong Kong); Egami, T. [Department of Materials Science and Engineering, University of Tennessee, Knoxville, Tennessee 37996 (United States); Department of Physics and Astronomy, Joint Institute for Neutron Sciences, University of Tennessee, Knoxville, Tennessee 37996 (United States)

    2016-01-15

    Neutron diffraction studies of metallic liquids provide valuable information about inherent topological and chemical ordering on multiple length scales as well as insight into dynamical processes at the level of a few atoms. However, there exist very few facilities in the world that allow such studies to be made of reactive metallic liquids in a containerless environment, and these are designed for use at reactor-based neutron sources. We present an electrostatic levitation facility, NESL (for Neutron ElectroStatic Levitator), which takes advantage of the enhanced capabilities and increased neutron flux available at spallation neutron sources (SNSs). NESL enables high quality elastic and inelastic neutron scattering experiments to be made of reactive metallic and other liquids in the equilibrium and supercooled temperature regime. The apparatus is comprised of a high vacuum chamber, external and internal neutron collimation optics, and a sample exchange mechanism that allows up to 30 samples to be processed between chamber openings. Two heating lasers allow excellent sample temperature homogeneity, even for samples approaching 500 mg, and an automated temperature control system allows isothermal measurements to be conducted for times approaching 2 h in the liquid state, with variations in the average sample temperature of less than 0.5%. To demonstrate the capabilities of the facility for elastic scattering studies of liquids, a high quality total structure factor for Zr{sub 64}Ni{sub 36} measured slightly above the liquidus temperature is presented from experiments conducted on the nanoscale-ordered materials diffractometer (NOMAD) beam line at the SNS after only 30 min of acquisition time for a small sample (∼100 mg)

  14. MEGAPIE, a 1 MW pilot experiment for a liquid metal spallation target

    Energy Technology Data Exchange (ETDEWEB)

    Bauer, G.S. [Paul Scherrer Institut, Spallation Neutron Source Division, Villigen-PSI (Switzerland); Salvatores, M. [CEA Cadarache, Direction des Reacteurs Nucleaires, Saint-Paul-lez-Durance Cedex (France); Heusener, G. [Forschungszentrum Karlsruhe, Projekt Nukleare Sicherheitsforschung, Karlsruhe (Germany)

    2001-03-01

    MEGAPIE (Megawatt Pilot Target Experiment) is an initiative launched by Commissariat a l'Energie Atomique, Cadarache (France) and Forschungszentrum Karlsruhe (Germany) in collaboration with Paul Scherrer Institut (Switzerland), to demonstrate, in an international collaboration, the feasibility of a liquid lead bismuth target for spallation facilities at a beam power level of 1 MW. Such a target is under consideration for various concepts of accelerator driven systems (ADS) to be used in transmutation of nuclear waste and other applications world-wide. It also has the potential of increasing significantly the thermal neutron flux available at the spallation neutron source (SINQ) for neutron scattering. SINQ's beam power being close to 1 MW already, this facility offers a unique opportunity to realize such an experiment with a reasonably small number of new ancillary systems. The paper describes the basic features of the experiment and its boundary conditions, the technical concept of the target and underlying research carried out at participating laboratories. (author)

  15. Development of microbubble generator for suppression of pressure waves in mercury target of spallation source

    International Nuclear Information System (INIS)

    A MW-class mercury target for the spallation neutron source is subjected to the pressure waves and cavitation erosion induced by high-intense pulsed-proton beam bombardment. Helium-gas microbubbles injection into mercury is one of the effective techniques to suppress the pressure waves. The microbubble injection technique was developed. The selection test of bubble generators indicated that the bubble generator utilizing swirl flow of liquid (swirl-type bubble-generator) will be suitable from the viewpoint of the produced bubble size. However, when single swirl-type bubble-generator was used in flowing mercury, swirl flow of mercury remains at downstream of the generator. The remaining swirl flow causes the coalescence of bubbles which results in ineffective suppression of pressure waves. To solve this concern, a multi-swirl type bubble-generator, which consists of several single swirl-type bubble-generators arraying in the plane perpendicular to mercury flow direction, was invented. The multi-swirl type bubble-generator was tested in mercury and the geometry was optimized to generate small bubble with low flow resistance based on the test results. It is estimated to generate the microbubbles of 65 μm in radius under the operational condition of the Japanese Spallation Neutron Source mercury target, which is the sufficient size to suppress the pressure waves. (author)

  16. Long-lived products of the spallation of nat Te and nat Mo by protons

    International Nuclear Information System (INIS)

    We have performed experiments of spallation of natural Te targets by 5.0- and 1.85-GeV protons and of a natural Mo target with 1.85-GeV protons at the LBNL Bevatron. In order to determine those cross sections associated to long-lived products, we have brought the targets of the 1.85-GeV proton experiment to the Laboratorio do Acelerador Linear from the IFUSP, to gamma-count them. The Te data revealed the presence of trace amounts of 60 Co (half-life 5.3 yr) and of 22 Na (half-life 2.6 yr) and measurable amounts of 102 Rhm (half-life 2.9 yr) and 125 Sb (half-life 2.7 yr). The Mo target showed the presence of a trace amount of 22 Ma and a measurable amount of 65 Zn (half-life 0.7 yr). Our results for the cross sections on Te are 4.0(2) mb for producing 102 Rhm and 29(1) mb for 125 Sb. We are presently working on the determination of the spallation cross sections on Mo and on upper limits for the trace amounts mentioned. (author)

  17. A neutron booster for spallation sources--application to accelerator driven systems and isotope production

    CERN Document Server

    Galy, J; Van Dam, H; Valko, J

    2002-01-01

    One can design a critical system with fissile material in the form of a thin layer on the inner surface of a cylindrical neutron moderator such as graphite or beryllium. Recently, we have investigated the properties of critical and near critical systems based on the use of thin actinide layers of uranium, plutonium and americium. The thickness of the required fissile layer depends on the type of fissile material, its concentration in the layer and on the geometrical arrangement, but is typically in the mu m-mm range. The resulting total mass of fissile material can be as low as 100 g. Thin fissile layers have a variety of applications in nuclear technology--for example in the design neutron amplifiers for medical applications and 'fast' islands in thermal reactors for waste incineration. In the present paper, we investigate the properties of a neutron booster unit for spallation sources and isotope production. In those applications a layer of fissile material surrounds the spallation source. Such a module cou...

  18. Assessment of the neutron cross section database for mercury for the ORNL spallation source

    Energy Technology Data Exchange (ETDEWEB)

    Leal, L.C.; Spencer, R.R.; Ingersoll, D.T.; Gabriel, T.A. [Oak Ridge National Lab., TN (United States)

    1996-06-01

    Neutron source generation based on a high energy particle accelerator has been considered as an alternative to the canceled Advanced Neutron Source project at Oak Ridge National Laboratory. The proposed technique consists of a spallation neutron source in which neutrons are produced via the interaction of high-energy charged particles in a heavy metal target. Preliminary studies indicate that liquid mercury bombarded with GeV protons provides an excellent neutron source. Accordingly, a survey has been made of the available neutron cross-section data. Since it is expected that spectral modifiers, specifically moderators, will also be incorporated into the source design, the survey included thermal energy, resonance region, and high energy data. It was found that data of individual isotopes were almost non-existent and that the only evaluation found for the natural element had regions of missing data or discrepant data. Therefore, it appears that to achieve the desired degree of accuracy in the spallation source design it is necessary to re-evaluate the mercury database including making new measurements. During the presentation the currently available data will be presented and experiments proposed which can lead to design quality cross sections.

  19. GEANT4 simulations of the n{sub T}OF spallation source and their benchmarking

    Energy Technology Data Exchange (ETDEWEB)

    Lo Meo, S. [Research Centre ' ' Ezio Clementel' ' , ENEA, Bologna (Italy); Section of Bologna, INFN, Bologna (Italy); Cortes-Giraldo, M.A.; Lerendegui-Marco, J.; Guerrero, C.; Quesada, J.M. [Universidad de Sevilla, Facultad de Fisica, Sevilla (Spain); Massimi, C.; Vannini, G. [Section of Bologna, INFN, Bologna (Italy); University of Bologna, Physics and Astronomy Dept. ' ' Alma Mater Studiorum' ' , Bologna (Italy); Barbagallo, M.; Colonna, N. [INFN, Section of Bari, Bari (Italy); Mancusi, D. [CEA-Saclay, DEN, DM2S, SERMA, LTSD, Gif-sur-Yvette CEDEX (France); Mingrone, F. [Section of Bologna, INFN, Bologna (Italy); Sabate-Gilarte, M. [Universidad de Sevilla, Facultad de Fisica, Sevilla (Spain); European Organization for Nuclear Research (CERN), Geneva (Switzerland); Vlachoudis, V. [European Organization for Nuclear Research (CERN), Geneva (Switzerland); Collaboration: The n_TOF Collaboration

    2015-12-15

    Neutron production and transport in the spallation target of the n{sub T}OF facility at CERN has been simulated with GEANT4. The results obtained with different models of high-energy nucleon-nucleus interaction have been compared with the measured characteristics of the neutron beam, in particular the flux and its dependence on neutron energy, measured in the first experimental area. The best agreement at present, within 20% for the absolute value of the flux, and within few percent for the energy dependence in the whole energy range from thermal to 1 GeV, is obtained with the INCL++ model coupled with the GEANT4 native de-excitation model. All other available models overestimate by a larger factor, of up to 70%, the n{sub T}OF neutron flux. The simulations are also able to accurately reproduce the neutron beam energy resolution function, which is essentially determined by the moderation time inside the target/moderator assembly. The results here reported provide confidence on the use of GEANT4 for simulations of spallation neutron sources. (orig.)

  20. Burnup of Cadmium Decoupler Material in the Spallation Neutron Source Moderators

    Energy Technology Data Exchange (ETDEWEB)

    Murphy, BD

    2001-08-21

    At the Spallation Neutron Source being constructed at Oak Ridge National Laboratory, power levels will be greater than at any other operating pulsed spallation neutron scattering facility. Some of the moderators at the facility will contain cadmium that will be used to tailor neutron time distributions by absorbing low-energy neutrons. Because of the higher operating power levels, indications are that there will be considerable burnup of this cadmium during the lifetime of the moderators. Cadmium burnup rates have been calculated for locations around the moderators. Assumed operating conditions for these calculations were a 2-mA beam of 1-GeV protons on the mercury target for 5,000 operating hours per year and a three-year lifetime for the moderators and inner-plug assembly. With the present proposed cadmium thickness in the moderator region (0.05 cm), Monte Carlo calculations indicate considerable depletion of the active cadmium isotope. In places, the calculations indicate complete depletion. An obvious solution to the problem would be to increase the cadmium thickness with a concomitant increase in heat load. Results from some cadmium heating calculations are also presented for a cadmium thickness of 0.05 cm.

  1. Spallation radiation damage and dosimetry for accelerator transmutation of waste applications

    Energy Technology Data Exchange (ETDEWEB)

    Wechsler, M.S.; Lin, C. [North Carolina State Univ., Raleigh, NC (United States). Dept. of Nuclear Engineering; Ferguson, P.D. [Missouri Univ., Rolla, MO (United States). Dept. of Nuclear Engineering; Sommer, W.F. [Los Alamos National Lab., NM (United States)

    1993-10-01

    Proposals are currently being made for systems to treat radioactive waste based on the use of accelerator-driven neutron sources. A linear proton accelerator with energies as high as 1600 MeV and currents up to 250 ma are anticipated for the driver. The neutron fluxes may reach up to 10{sup 20} neutrons/m{sup 2}s as generated by the spallation reactions that occur when the protons strike target materials. Calculations are described to determine radiation fluxes and flux spectra inherent in such systems and to estimate likely radiation effects on system components. The calculations use LAHET, a Monte Carlo high-energy transport code, and MCNP, a generalized-geometry, coupled neutron-photon Monte Carlo transport code. Cross sections for displacement and helium production are presented for spallation neutrons of energies from 21 MeV to 1600 MeV for Inconel 718 (Ni plus 18.5, 18.5, 5.1, and 3 wt % of Cr, Fe, Nb, and Mo, respectively), an alloy that is used for the proton beam entry window in several accelerators. In addition, results for this alloy are presented for the primary knocked-on atom (PKA) spectrum and the transmutation yield for 1600 MeV incident neutrons.

  2. Power spectral analysis for a subcritical reactor system driven by a pulsed spallation neutron source

    International Nuclear Information System (INIS)

    A series of power spectral analyses for a thermal subcritical reactor system driven by a pulsed spallation neutron source was carried out at Kyoto University Critical Assembly (KUCA), to determine the prompt-neutron decay constant of the Accelerator-Driven System (ADS). High-energy protons (100 MeV) obtained from the fixed field alternating gradient accelerator were injected onto a lead-bismuth target, whereby the spallation neutrons were generated. In the cross-power spectral density between time-sequence signal data of two neutron detectors, many delta-function-like peaks at the integral multiple of pulse repetition frequency could be observed. However, no continuous reactor-noise component could be measured. This is because these detectors have too high count-rate to be placed closely to the core. From the point data of these delta-function-like peaks, the prompt-neutron decay constant could be determined. At a slightly subcritical state, the decay constant was consistent with that obtained by a previous power spectral analysis for a pulsed 14 MeV neutron source and by a pulsed neutron experiment. At another deeply subcritical state, however, the present analysis leads to an underestimate of the decay constant. (author)

  3. Waste heat recovery from the European Spallation Source cryogenic helium plants - implications for system design

    Science.gov (United States)

    Jurns, John M.; Bäck, Harald; Gierow, Martin

    2014-01-01

    The European Spallation Source (ESS) neutron spallation project currently being designed will be built outside of Lund, Sweden. The ESS design includes three helium cryoplants, providing cryogenic cooling for the proton accelerator superconducting cavities, the target neutron source, and for the ESS instrument suite. In total, the cryoplants consume approximately 7 MW of electrical power, and will produce approximately 36 kW of refrigeration at temperatures ranging from 2-16 K. Most of the power consumed by the cryoplants ends up as waste heat, which must be rejected. One hallmark of the ESS design is the goal to recycle waste heat from ESS to the city of Lund district heating system. The design of the cooling system must optimize the delivery of waste heat from ESS to the district heating system and also assure the efficient operation of ESS systems. This report outlines the cooling scheme for the ESS cryoplants, and examines the effect of the cooling system design on cryoplant design, availability and operation.

  4. Surface Laser Scanning Measurements for the n_TOF spallation target

    CERN Document Server

    Vlachoudis, V; Cennini, P; Lebbos, E; Lettry, J

    2010-01-01

    The n_TOF spallation target is made of pure lead immersed into cooling water. The target was operating normally from 2001 until august 2004, when an increased transfer of radioactive products from the spallation target to the cooling circuit has been observed. The target was considered damaged by the safety commission (SC/RP), and an investigation campaign started to verify the actual status of the target. According to FLUKA and Ansys calculations the target was working in the elastoplastic regime of the lead material, therefore a deformation might be expected. The present paper describes a laser photographic method and the results of a possible such deformation. The target had a surface activity of the order of 20 mSv/h, therefore we were forced to perform the measurement from distance. The used method, is based on a linelaser and a high resolution digital camera for retrieving the 3D position of the surface of the lead target. Similar methods are used in the film industry and animation studios for scanning ...

  5. Towards the construction of the European spallation source – The Scandinavian experience

    Indian Academy of Sciences (India)

    C J Carlile; C Vettier; P Carlsson

    2008-11-01

    The possible realization of the European spallation source has been a long and winding story. However, thanks to the conjunction of a number of events it now looks highly probable that in 2008 there will indeed be a decision on the site and on a funding partnership of European countries who will together build and operate this long-pulse spallation neutron source. Currently there is a reference design comprising of a 632 m long proton accelerator which will deliver 2 ms pulses of protons to a liquid metal target with 22 instruments receiving thermal and cold neutron beams and providing unprecedented data rates. Lund is one of the two consortia competing to build the ESS – the ESS Scandinavia and a Hungarian–Spanish collaboration which is currently deciding on its preferred site. The Lund experience is one which highlights the many delicate steps which must be taken in order to get close to such decisions in a Europe of 30 plus nations. Of particular interest is the Energy Management Strategy which ESS Scandinavia would implement if Lund were to be the eventual chosen site. This will be set into the context of the political iniatives to mitigate the effects of global warming.

  6. Study of the spallation residues in the reaction Au (800 MeV/nucleon) + p; Etude des residus de spallation dans la reaction Au (800 MeV par nucleon) + p

    Energy Technology Data Exchange (ETDEWEB)

    Mustapha, Brahim [Inst. de Physique Nucleaire, Paris-11 Univ., 91 - Orsay (France)

    1999-09-09

    As a neutron source, the spallation reaction is of importance for different fields of research and for a possible hybrid reactor. The study of spallation residues, their cross sections and their energetic properties, is necessary for such applications and for a better understanding of this process. Several studies of spallation products were done using spectroscopic methods. Only radioactive nuclides were detected. Aiming at a more precise measurement, covering the whole range of spallation residues, this study was done using the reverse kinematics method. A liquid hydrogen target was irradiated by an 800 MeV/nucleon gold beam. The produced nuclei were detected in flight before any radioactive decay with about 10% precision. Independent cross section were then obtained. Velocity distributions were completely reconstructed. In their present forms, the theoretical calculations based upon the two-step model, 'intra-nuclear cascade' + 'evaporation', are unable to reproduce the whole set of experimental aspects. An inter-comparison using different INC/EVA combinations permitted to identify the more significant points in these calculations. The important behaviour of this codes were examined. Due to compensation effects between both steps, cascade and evaporation, this study did not lead to a definite conclusion. (author)

  7. Catalyst materials based on plasma-processed alumina nanopowder

    Directory of Open Access Journals (Sweden)

    Dubencovs Konstantins

    2012-01-01

    Full Text Available A platinum catalyst for glycerol oxidation by molecular oxygen has been developed applying the extractive-pyrolytic method and using, as a support, a fine alumina powder with an average particle size of 30-60 nm processed by plasma technology. The extractive-pyrolytic method (EPM allows affixing small amounts of catalytic metals (1-5% with the particle size ranging from several nanometers to several tens of nanometers onto the surface of the support. The prepared material - 4.8 wt. % platinum on nano-sized alumina - can be used as a catalyst for glycerol oxidation by oxygen with conversion up to 84%, in order to produce some organic acids (glyceric and lactic acid with a selectivity of about 60%.

  8. Nano α-alumina powders from aluminium dross waste

    International Nuclear Information System (INIS)

    The paper describes a solvo thermal chemical process to recycle aluminium dross waste into nano α-alumina powder. The process includes washing to remove the unwanted sodium follow by dissolving of this waste with dilute acid. The solvo thermal process then proceed with addition of propanol to crystallize the aluminium hydroxide. XRD analysis of this crystal shows that it belongs to Gibbs site (Al(OH)3). The crystals were then calcined at 1300 degree C where white powder was produced. Characteristic studies were then performed on this powder using XRD, SEM, EDX and particle size analysis showing that it has single α-alumina crystal phase with almost spherical shape. As the initial particle size is coarse and had a mean particle size of 3.80 μm, high speed wet milling was used and enable to reduce it to 0.49 μm. (Author)

  9. Synthesis of Porous Nano Alumina Powder by Combustion Method

    International Nuclear Information System (INIS)

    Development of Porous Alumina powder by combustion technique using glysine fuel and aluminum nitrate as and oxidizer is able to produce porous Alpha alumina powders. Thermodynamic modeling of the combustion reaction show that as the fuel to oxidant ratio increases, the amount of gases produced and adiabatic flame temperature also increase. X-ray diffraction showed the amorphous structure for as-synthesized powder and present of well-crystallized a- Al2O3 after calcination at 1100 degree Celsius. Morphology microstructure of pore size ranging between 134-495 nm were observed by SEM. The crystallite size (Scherrer) is observed at ∼568.2 A and FWHM 0.143 degree. (author)

  10. Electrochemically grown metallic nanocomb structures on nanoporous alumina templates

    International Nuclear Information System (INIS)

    Electrochemical growth of metallic nanocomb structures on anodized alumina templates is described. Nanocombs originate from the orderly growth and merger of very thin (d=15±5 nm) metallic nanowires which do not completely fill much larger pores (d∼100 nm) in the alumina template (t≤3 μm). Instead, the nanowires prefer growing along the inner corners of the hexagonal pores, coalescing into a highly ordered structure as they emerge, resulting a metallic form reminiscent of the topology of the original template. We disclose here the typical processing conditions and the microstructure of this previously unknown material as observed with a scanning electron microscope (SEM) and energy dispersive x-ray (EDX) spectroscopy. It is shown that Au nanocombs have an anomalous EDX spectra and can emit electrons at a field of ∼1 kV/cm.

  11. Preparation of zirconia-alumina powder by co-precipitation

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    A zirconia-alumina powder with a near spherical shape and an average size of 0.1 ~ 0.2μm was prepared byco-precipitation. XRD analysis shows that α-Al2O3 phase may be directly transformed from amorphous in calcining the hydroxide composite. The ZrO2-Al2O3 composite ceramics manufactured from this powder has the maximum fracture toughness of 9 M Pa·m- 1/2 at 15 % ZrO2 and 740 MPa fracture strength at 5 % ZrO2. Zirconia grains about 1 μm in diameter aredispersed uniformly in the alumina ceramic matrix

  12. Epitaxial growth of tungsten nanoparticles on alumina and spinel surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Rodriguez-Suarez, T; Lopez-Esteban, S; Pecharroman, C; Esteban-Cubillo, A; Moya, J S [Instituto de Ciencia de Materiales de Madrid (ICMM), Consejo Superior de Investigaciones Cientificas (CSIC), C/ Sor Juana Ines de la Cruz 3, 28049, Cantoblanco, Madrid (Spain); Diaz, L A; Torrecillas, R [Nanomaterials and Nanotechnology Research Center (CINN), Consejo Superior de Investigaciones CientIficas (CSIC), C/ Francisco Pintado Fe 26, 33011, Oviedo, Asturias (Spain); Gremillard, L [Universite de Lyon, INSA-Lyon, MATEIS, UMR CNRS 5510, 20 avenue Albert Einstein, Villeurbanne F-69621 (France)], E-mail: jsmoya@icmm.csic.es

    2008-05-28

    Isolated tungsten nanoparticles ({alpha}-W and {beta}-W phase) were synthesized and epitaxially grown on alumina and spinel particle surfaces with an average tungsten size of {<=}20 nm for a low tungsten content (of {<=}1.5 vol%). Using tungsten (VI) ethoxide alcoholic solutions, tungsten trioxide hydrated precursors were attached to a ceramic grains surface as a nanoparticle coating. High-resolution transmission electron microscopy (HRTEM) micrographs showed epitaxial interfaces between alumina, spinel and metallic tungsten. This epitaxial growth is assumed to be due to the effect of water vapour on the sublimation of ortho-tungstic acid during the reduction process in a hydrogen atmosphere. The planes involved in the epitaxy were found to be (22-bar 0){sub Al2O3} parallel (121){sub W} and (311){sub MgAl2O4} parallel (110){sub W}.

  13. Diffusion bonding of titanium-titanium aluminide-alumina sandwich

    Energy Technology Data Exchange (ETDEWEB)

    Wickman, H.A.; Chin, E.S.C. [Army Research Lab., Watertown, MA (United States); Biederman, R.R. [Worcester Polytechnic Inst., MA (United States)

    1995-12-31

    Diffusion bonding of a metallic-intermetallic-ceramic sandwich is of interest for potential armor applications. Low cost titanium, titanium diboride reinforced titanium aluminide (Ti-48at.%Al), and aluminum oxide are diffusion bonded in a vacuum furnace between 1,000 C and 1,400 C. Metallographic examination of the prior bonding interface showed excellent metallurgical coupling between the Ti-48at.%Al composite and the low cost Ti. A series of microstructures representative of phases consistent with a hypothetical Ti-Al-B phase diagram is visible. The alumina-Ti-48at.%Al interfacial bond is achieved through penetration of titanium-aluminum phases into the existing alumina porosity. A detailed microstructural analysis identifying mechanisms of interfacial bonding will be presented for each interfacial zone.

  14. Positron energy-loss measurements in thin alumina films

    International Nuclear Information System (INIS)

    Transmitted-positron energy loss measurements were performed on approximately 100A alumina films with incident positron energies ranging from 0.5 to 3.0 keV. The positrons were electrostatically focussed on the film and the transmitted positrons were energy analyzed using a four-grid retarding field analyzer coupled with a two-stage channel electron multiplier plate connected with a phosphor screen. A strong transmitted elastic peak as well as indications of discrete energy losses were detected in these measurements. The observed discrete loss effects occurred at an average energy of approx. 25 eV and possibly approx. 50 eV. These findings are consistent with reported electron loss peaks due to plasmon excitation in alumina films

  15. Study of preparation and surface morphology of self-ordered nanoporous alumina; Estudo da preparacao e da morfologia de superficie de alumina nanoporosa auto-organizada

    Energy Technology Data Exchange (ETDEWEB)

    Rodrigues, Elisa Marchezini; Martins, Maximiliano Delany, E-mail: elisamarch@gmail.com, E-mail: MG.mdm@cdtn.br [Centro de Desenvolvimento da Tecnologia Nuclear (CDTN/CNEN-MG), Belo Horizonte, MG. (Brazil); Silva, Ronald Arreguy, E-mail: arregsilva@yahoo.com.br [Centro Universitario de Belo Horizonte (UniBH), Belo Horizonte, MG (Brazil)

    2013-07-01

    Nanoporous alumina is a typical material that exhibits self-ordered nanochannels spontaneously organized in hexagonal shape. Produced by anodizing of metallic aluminum, it has been used as a template for production of materials at the nanoscale. This work aimed to study the preparation of nanoporous alumina by anodic anodizing of metallic aluminum substrates. The nanoporous alumina was prepared following the methodology proposed by Masuda and Fukuda (1995), a two-step method consisting of anodizing the aluminum sample in the potentiostatic mode, removing the layer of aluminum oxide (alumina) formed and then repeat the anodization process under the same conditions as the first anodization. This method produces nanoporous alumina with narrow pore diameter distribution and well-ordered structure. (author)

  16. HEIMDAL: A thermal neutron powder diffractometer with high and flexible resolution combined with SANS and neutron imaging - Designed for materials science studies at the European Spallation Source

    Science.gov (United States)

    Holm, Sonja L.; Lefmann, Kim; Henry, Paul F.; Bertelsen, Mads; Schefer, Jürg; Christensen, Mogens

    2016-08-01

    HEIMDAL will be a multi length scale neutron scattering instrument for the study of structures covering almost nine orders of magnitude from 0.01 nm to 50 mm. The instrument is accepted for construction at the European Spallation Source (ESS) and features a variable resolution thermal neutron powder diffractometer (TNPD), combined with small angle neutron scattering (SANS) and neutron imaging (NI). The instrument uses a novel combination of a cold and a thermal guide to fulfill the diverse requirements for diffraction and SANS. With an instrument length of 170 m, HEIMDAL will take advantage of the high neutron flux of the long pulse at ESS, whilst maintaining a high q-resolution due to the long flight path. The q-range coverage is up to 20 Å-1 allowing low-resolution PDF analysis. With the addition of SANS, HEIMDAL will be able to cover a uniquely broad length scale within a single instrumental set-up. HEIMDAL will be able to accommodate modern materials research in a broad variety of fields, and the task of the instrument will be to study advanced functional materials in action, as in situ and in operandi at multiple length scales (0.01-100 nm) quasi simultaneously. The instrument combines state-of-the-art neutron scattering techniques (TNPD, SANS, and NI) with the goal of studying real materials, in real time, under real conditions. This article describes the instrument design ideas, calculations and results of simulations and virtual experiments.

  17. MECHANICAL PROPERTIES OF ZIRCONIA TOUGHENED ALUMINA PREPARED BY DIFFERENT METHODS

    OpenAIRE

    Homerin, P.; Thevenot, F.; Orange, G.; G. FANTOZZI; Vandeneede, V.; Leriche, A.; Cambier, F.

    1986-01-01

    Zirconia Toughened Alumina (ZTA) ceramics were prepared by two different methods from the same raw materials (powders). The first one using attrition milling and hot-pressing ; the second, electrochemical dispersion, slip casting and pressureless sintering. The influence of the processing parameters on the mechanical properties of dense material is examined. The influence of ZrO2 and Y2O3 contents is discussed.

  18. INVESTIGATION OF THERMAL SHOCK BEHAVIOUR IN ALUMINA BASED REFRACTORY BRICKS

    OpenAIRE

    N. Sinan KÖKSAL; B. Sadık ÜNLÜ; Cevdet MERİÇ

    2003-01-01

    cUnderstanding of mechanical and thermal properties of refractory bricks used in industry is an important aspect to determine appropriate operating conditions. In this study, commercial refractory materials used in the sector of iron steel 45 % and 80 % alumina (Al2O3) of content refractory bricks were investigated. To determinate thermal shock behavior and mechanical properties of samples, thermal shock tests were applied by quenching in the water at the temperature differences of 500, 70...

  19. Surface tension of liquid alumina from contactless techniques

    International Nuclear Information System (INIS)

    Full Text: We report new data on surface tension of liquid alumina from 2300 to 3200 K. Aerodynamic levitation of CO2 laser heated liquid drops allowed contactless measurement of vibration frequencies directly related to surface tension. Consistent data were obtained on drops of various weights ranging from 20 to 160 mg. It was also shown that oxydo-reducing character of the atmosphere does not modify sensible the results. (author)

  20. Controlled growth of single nanowires within a supported alumina template

    DEFF Research Database (Denmark)

    Vlad, A.; Mátéfi-Tempfli, M.; Faniel, S.;

    2006-01-01

    A simple technique for fabricating single nanowires with well-defined position is presented. The process implies the use of a silicon nitride mask for selective electrochemical growth of the nanowires in a porous alumina template. We show that this method allows the realization of complex nanowire...... patterns as well as arrays of single nanowires with a precise position and spacing. © IOP Publishing Ltd....

  1. Ordered Nanomaterials Thin Films via Supported Anodized Alumina Templates

    OpenAIRE

    Mohammed eES-SOUNI; Salah ehabouti

    2014-01-01

    Supported anodized alumina template films with highly ordered porosity are best suited for fabricating large area ordered nanostructures with tunable dimensions and aspect ratios. In this paper we first discuss important issues for the generation of such templates, including required properties of the Al/Ti/Au/Ti thin film heterostructure on a substrate for high quality templates. We then show examples of anisotropic nanostructure films consisting of noble metals using these templates, discus...

  2. Ordered Nanomaterial Thin Films via Supported Anodized Alumina Templates

    OpenAIRE

    Es-Souni, Mohammed; Habouti, Salah

    2014-01-01

    Supported anodized alumina template films with highly ordered porosity are best suited for fabricating large-area ordered nanostructures with tunable dimensions and aspect ratios. In this paper, we first discuss important issues for the generation of such templates, including required properties of the Al/Ti/Au/Ti thin-film heterostructure on a substrate for high-quality templates. We then show examples of anisotropic nanostructure films consisting of noble metals using these templates, discu...

  3. Controlled fabrication of patterned lateral porous alumina membranes

    International Nuclear Information System (INIS)

    Confined lateral alumina templates are fabricated with different pore sizes by changing the acid electrolyte and the anodization voltage. The control of the number of pore rows down to one dimension is also achieved, by controlling the thickness of the starting aluminum film as well as the anodization voltage. We observe that the mechanism of pore formation in the lateral regime is very similar to that in the classical vertical situation

  4. Electroless Fabrication of Cobalt Alloys Nanowires within Alumina Template

    OpenAIRE

    Nazila Dadvand; Kipouros, Georges J.

    2007-01-01

    A new method of nanowire fabrication based on electroless deposition process is described. The method is novel compared to the current electroless procedure used in making nanowires as it involves growing nanowires from the bottom up. The length of the nanowires was controlled at will simply by adjusting the deposition time. The nanowires were fabricated within the nanopores of an alumina template. It was accomplished by coating one side of the template by a thin layer of palladium in order t...

  5. Results of recent KROTOS FCI tests. Alumina vs. corium melts

    Energy Technology Data Exchange (ETDEWEB)

    Huhtiniemi, I.; Magallon, D.; Hohmann, H. [Commission of the European Communities, Ispra (Italy). Joint Research Center

    1998-01-01

    Recent results from KROTOS fuel-coolant interaction experiments are discussed. Five tests with alumina were performed under highly subcooled conditions, all of these tests resulted in spontaneous steam explosions. Additionally, four tests were performed at low subcooling to confirm, on one hand, the suppression of spontaneous steam explosions under such conditions and, on the other hand, that such a system is still triggerable using an external initiator. The other test parameters in these alumina tests included the melt superheat and the initial pressure. All the tests in the investigated superheat range (150 K - 750 K) produced a steam explosion and no evidence of the explosion suppression by the elevated initial pressure (in the limited range of 0.1 - 0.375 MPa) was observed in the alumina tests. The corium test series include a test with 3 kg of melt under both subcooled and near saturated conditions at ambient pressure. Two additional tests were performed with subcooled water; one test was performed at an elevated pressure of 0.2 MPa with 2.4 kg of melt and another test with 5.1 kg of melt at ambient pressure. None of these tests with corium produced a propagating energetic steam explosion. However, propagating low energy (about twice the energy of the trigger pulse) events were observed. All corium tests produced significantly higher water level swells during the mixing phase than the corresponding alumina tests. Present experimental evidence suggests that the water depletion in the mixing zone suppresses energetic steam explosions with corium melts at ambient pressure and in the present pour geometry. Processes that could produce such a difference in void generation are discussed. (author)

  6. MICROWAVE JOINING OF ALUMINA CERAMIC AND HYDROXYLAPATITE BIOCERAMIC

    Institute of Scientific and Technical Information of China (English)

    1999-01-01

    Microwave joining is a rapid developmental new techniqu e in recent years.This paper introduces a new microwave joining equipment which was made by our lab,succeeds in alumina ceramic-hydroxylapatite bioceramic j o in in the equipment, and analyzes the join situation of join boundary by using s canni ng electron microscope(SEM),this paper analyzes the mechanism of microwave joini ng also.

  7. Nanocarbon-Coated Porous Anodic Alumina for Bionic Devices

    OpenAIRE

    Morteza Aramesh; Wei Tong; Kate Fox; Ann Turnley; Dong Han Seo; Steven Prawer; Kostya (Ken) Ostrikov

    2015-01-01

    A highly-stable and biocompatible nanoporous electrode is demonstrated herein. The electrode is based on a porous anodic alumina which is conformally coated with an ultra-thin layer of diamond-like carbon. The nanocarbon coating plays an essential role for the chemical stability and biocompatibility of the electrodes; thus, the coated electrodes are ideally suited for biomedical applications. The corrosion resistance of the proposed electrodes was tested under extreme chemical conditions, su...

  8. Short cycle brazing of an alumina dispersion strengthened copper alloy

    International Nuclear Information System (INIS)

    An alumina dispersion strengthened copper alloy (with 0.07 wt, % alumina) has been proposed for several specialized applications in fusion reactors, such as the stabilizer in superconducting magnets and the structural material for divertors and limiters. In this research, brazed joints of the alumina dispersion strengthened copper alloy were developed using resistance heating brazing. The BCuP-3 brazing alloy was chosen based upon its low activation characteristics. Brazing was conducted using a GLEEBLE 1500 system with which time, temperature, and stress were precisely controlled. Butt-brazed joints with different brazing times were evaluated based on tensile and bending fatigue properties. Results from these tests reveal that the optimum braze time is approximately 1 minute at 8000C with a holding stress of 0.5 MPa. Metallography examinations were conducted on both the as brazed structure and the fracture surfaces. In the former, a transition layer (about 10 μm tick) was formed between the braze metal and the base alloy. Microhardness measurements across the braze did not show any hardening or softening effect due to the brazing process. Metallography of the fractured tensile and fatigue samples showed that cracks always penetrated through the interface between the transition layer and the braze metal. Semiquantitative energy dispersive x-ray spectroscopy (EDS) analysis was also performed across the joint. Profiles of P and Ag showed that P diffused very quickly into base metal along grain boundaries. A strong Al peak (associated with the detection of Al2O3) was found that corresponded with the transition layer. The presence of the alumina particles in the transition zone restricts the grain growth process in this region, resulting in relatively fine grain size

  9. Ion irradiation effect of alumina and its luminescence

    Energy Technology Data Exchange (ETDEWEB)

    Aoki, Yasushi; Yamamoto, Shunya; Naramoto, Hiroshi [Japan Atomic Energy Research Inst., Takasaki, Gunma (Japan). Takasaki Radiation Chemistry Research Establishment; My, N.T.

    1997-03-01

    The luminescence spectra of single crystalline alpha-alumina and ruby which has 0.02% of Cr{sub 2}O{sub 3} as a impurity, induced by 200 keV He{sup +} and Ar{sup +} irradiation were measured at room temperature as a function of irradiation dose. The analysis of the measured spectra showed the existence of three main luminescence features in the wavelength region of 250 to 350 nm, namely anionic color centers, F-center at 411 nm and F{sup +}-center at 330 nm and a band observed around 315 nm. As alpha-alumina was irradiated with He{sup +}, F-center and F{sup +}-center luminescence grew and decayed, but the behaviors of those were different from each other. It seems that a concentration quenching occurred on the F-center luminescence in the dose range above 1x10{sup 14} He/cm{sup 2}. Furthermore, F-center luminescence was strongly suppressed in ruby, compared with that in alumina. On the other hand, the luminescence band around 315 nm appeared only in the early stage of irradiation and did not show its growth part. The dose dependent behavior was similar to that of Cr{sup 3+} emission at 695 nm (R-line) in ruby in both cases of He{sup +} and Ar{sup +} irradiation. Based on the experimental results mentioned above, the processes of defect formation and excitation in alumina in the early stage of ion irradiation will be discussed. (author)

  10. Proton adsorption onto alumina: extension of multisite complexation (MUSIC) theory

    Energy Technology Data Exchange (ETDEWEB)

    Nagashima, K.; Blum, F.D.

    1999-09-01

    The adsorption isotherm of protons onto a commercial {gamma}-alumina sample was determined in aqueous nitric acid with sodium nitrate as a background electrolyte. Three discrete regions could be discerned in the log-log plots of the proton isotherm determined at the solution pH 5 to 2. The multisite complexation (MUSIC) model was modified to analyze the simultaneous adsorption of protons onto various kinds of surface species.

  11. Environmental Sustainability of the Alumina Industry in Western Europe

    Directory of Open Access Journals (Sweden)

    Valentina Dentoni

    2014-12-01

    Full Text Available The implementation of European policies on environmental protection is enforcing some substantial modifications in the processing methods and technologies traditionally adopted in the alumina industry and, in particular, in the management of the alumina residue produced. The article analyses the evolution of the alumina production and the residue disposal practices in Western Europe. Some critical aspects regarding the legal implementation of the EU Directive on the landfill of waste are highlighted and discussed. With reference to the requirements established for the landfill of non-hazardous waste, a key point is represented by the possibility of reducing the deposit protection measures if the collection and treatment of leachate is not necessary. The flexibility introduced by the Directive is not incorporated into the Italian law; this fact may represent a major issue in the prospect of disposal conversion from wet to dry methods for companies operating in Italy, as it may endanger the economic sustainability of the plants’ upgrade, as well as the opportunity to attract outside investments.

  12. Investigations of vapour explosions with alumina-droplets in sodium

    International Nuclear Information System (INIS)

    Within the analysis of severe hypothetical fast breeder accidents the consequence of a fuel-coolant interaction has to be considered, i.e. the thermal interaction between hot molten fuel and sodium. Experiments have been performed to study the thermal fragmentation of a molten alumina droplet in sodium. Alumina temperatures up to 3100 K and sodium temperatures up to 1143 K were used. For the first time film boiling of alumina drops in sodium was achieved. With some droplets undergoing film boiling, the fragmentation was triggered by an externally applied pressure wave. In these experiments, the trigger was followed promptly by a strong reaction pressure wave if and only if a contact temperature threshold of TI=2060 K±160 K was exceeded. In agreement with similar experiments in which other materials were studied, this threshold corresponds to an interfacial temperature close to the homogeneous nucleation temperature of the vapourising liquid. Based on the present and previous experimental results a model concept of thermal fragmentation is developed. (orig./HP)

  13. Investigation of vapor explosions with alumina droplets in sodium

    International Nuclear Information System (INIS)

    Within the analysis of severe hypothetical fast breeder accidents the consequence of a fuel-coolant interaction has to be considered i.e. the thermal interaction between hot molten fuel and sodium. Experiments have been performed to study the thermal fragmentation of a molten alumina droplet in sodium. Alumina temperatures up to 3100 K and sodium temperatures up to 1143 K were used. For the first time film boiling of alumina drops in sodium was achieved. With some droplets undergoing film boiling, the fragmentation was triggered by an externally applied pressure wave. The trigger was followed promptly by a strong reaction pressure wave if and only if a contact temperature threshold of TI=2060±160 K was exceeded. In agreement with similar experiments in which other materials were studied this threshold corresponds to an interfacial temperature close to the homogeneous nucleation temperature of the vaporising liquid. Based on the present and previous experimental results a model concept of thermal fragmentation is developed. (orig.)

  14. Thermodynamics of selenium sorption on alumina and montmorillonite

    Directory of Open Access Journals (Sweden)

    Jean-Pierre Morel

    2015-12-01

    Full Text Available The effect of pH and temperature on the thermodynamics of selenium sorption on alumina and montmorillonite was investigated. The equilibrium constants were obtained from batch experiments carried out at 25 and 40°C, under acidic and near to neutral conditions. Microcalorimetry was used to measure directly the enthalpy change upon sorption. These data were analysed by taking into account the different reactions that occur during the sorption process (the acid–base equilibria in the bulk solution on the one hand and the complexation equilibria between surface sites of the solid and solution species on the other hand. This was done using a simple surface model which assumes that the thermodynamic properties of the aluminol surface sites of both alumina and montmorillonite are identical. Two of the considered reactions were found to predominate, one under acidic conditions and one at near neutral pH. The microcalorimetric data allowed to check that the temperature effect on selenium sorption on alumina and montmorillonite can be correctly predicted simply using the above assumption concerning the sorption sites and by applying van’t Hoff relation both to the homogeneous and heterogeneous reactions.

  15. Intensifying digestion of diaspore and separation of alumina and silica

    Institute of Scientific and Technical Information of China (English)

    李小斌; 彭志宏; 刘桂华; 周秋生

    2003-01-01

    It was found that there lies a linear relationship among the thermodynamic data of complicate inorganic compounds with similar components. A method for estimating the thermodynamic data of complicate compound and a thermodynamic database involving alumina production were developed. It was found that the alumina digestion rate of activated diasporic bauxite by means of heat field increased much due to the structure aberration, i.e, from perfect structure to unstable corundum. The results from thermodynamic calculation and experiments showed that it was feasible for desilication at atmospheric pressure, and the effects on equilibrium concentration of SiO2 included temperature, mole ratio of Na2O/Al2O3 (αk), caustic and Na+ concentration. The technology of desilication of green liquor at atmosphere and separation of alumina and silica in aluminate solution with high concentration were established. The reaction activity of compounds containing silica and the converting law among compounds were studied, and the prototype technology of desilication products by hydrotreatment was also developed.

  16. Nanocarbon-Coated Porous Anodic Alumina for Bionic Devices

    Directory of Open Access Journals (Sweden)

    Morteza Aramesh

    2015-08-01

    Full Text Available A highly-stable and biocompatible nanoporous electrode is demonstrated herein. The electrode is based on a porous anodic alumina which is conformally coated with an ultra-thin layer of diamond-like carbon. The nanocarbon coating plays an essential role for the chemical stability and biocompatibility of the electrodes; thus, the coated electrodes are ideally suited for biomedical applications. The corrosion resistance of the proposed electrodes was tested under extreme chemical conditions, such as in boiling acidic/alkali environments. The nanostructured morphology and the surface chemistry of the electrodes were maintained after wet/dry chemical corrosion tests. The non-cytotoxicity of the electrodes was tested by standard toxicity tests using mouse fibroblasts and cortical neurons. Furthermore, the cell–electrode interaction of cortical neurons with nanocarbon coated nanoporous anodic alumina was studied in vitro. Cortical neurons were found to attach and spread to the nanocarbon coated electrodes without using additional biomolecules, whilst no cell attachment was observed on the surface of the bare anodic alumina. Neurite growth appeared to be sensitive to nanotopographical features of the electrodes. The proposed electrodes show a great promise for practical applications such as retinal prostheses and bionic implants in general.

  17. IMPROVED CORROSION RESISTANCE OF ALUMINA REFRACTORIES

    Energy Technology Data Exchange (ETDEWEB)

    John P. Hurley; Patty L. Kleven

    2001-09-30

    The initial objective of this project was to do a literature search to define the problems of refractory selection in the metals and glass industries. The problems fall into three categories: Economic--What do the major problems cost the industries financially? Operational--How do the major problems affect production efficiency and impact the environment? and Scientific--What are the chemical and physical mechanisms that cause the problems to occur? This report presents a summary of these problems. It was used to determine the areas in which the EERC can provide the most assistance through bench-scale and laboratory testing. The final objective of this project was to design and build a bench-scale high-temperature controlled atmosphere dynamic corrosion application furnace (CADCAF). The furnace will be used to evaluate refractory test samples in the presence of flowing corrodents for extended periods, to temperatures of 1600 C under controlled atmospheres. Corrodents will include molten slag, steel, and glass. This test should prove useful for the glass and steel industries when faced with the decision of choosing the best refractory for flowing corrodent conditions.

  18. Comparative study on sintered alumina for ballistic shielding application; Estudo comparativo entre aluminas sinterizadas visando aplicacao em blindagem balistica

    Energy Technology Data Exchange (ETDEWEB)

    Melo, Francisco Cristovao Lourenco de; Goncalves, Diniz Pereira [Centro Tecnico Aeroespacial (CTA), Sao Jose dos Campos, SP (Brazil). Inst. de Aeronautica e Espaco

    1997-12-31

    This work presents a development of the armor made from special ceramic materials and kevlar. An experimental investigation was conducted to study the ballistic penetration resistance on three samples taken from sintered alumina: a commercial one and two formulations A and B made in IAE/CTA. The main differences between the two formulations was the grain size and bend resistance. The knowledge of the mechanisms during the penetration and perforation process allowed to apply a ductile composite laminate made form kevlar under the alumina to delay its rupture. The last ballistic test showed how a Weibull`s modulii and other mechanical properties are able to improve ballistic penetration resistance. (author) 3 refs.

  19. Analysis of bridging stress effect of polycrystalline aluminas using double cantilever beam method III. Bridging stress distribution of polycrystalline aluminas

    Energy Technology Data Exchange (ETDEWEB)

    Sohn, K.S.; Lee, S.H.; Baik, S.G. [Pohang University of Science and Technology, Pohang (Korea, Republic of)

    1996-04-01

    The purpose of the present study is to investigate the microstructural effect on the R-curve behavior in three aluminas with different grain size distributions by analyzing the bridging stress distribution. The crack opening displacement (COD) according to the distance behind the stationary crack tip was measured using an in situ SEM fracture method. the measured COD values in the fine-grained alumina agreed well with Wiederhorn`s solution, while they deviated from Wiederhorn`s solution in the two coarse-grained aluminas because of the increase of the crack closure due to the grain interface bridging in the crack wake. A numerical fitting procedure was conducted by the introduction of the power-law relation and the current theoretical model, together with the measured COD`s, in order to obtain the bridging stress distribution. The results indicated that the bridging stress function and the R-curve computed by the current model were consistent with those computed by the power-law relation, providing a reliable evidence for the bridging stress analysis of the current model. the strain-softening exponent in the power-law relation, n, was calculated to be the range from 2 to 3, and was closely related to the grain size distribution. Thus, it was concluded from the current theoretical model that the grain size distribution affected greatly the bridging stress distribution, thereby resulting in the quantitative analysis of microfracture of polycrystalline aluminas through correlating the local-fracture-controlling microstructure. (author) 25 refs., 14 figs.

  20. Chemical Modification of Porous Alumina for Nanowire Templating and NEXAFS Spectroscopy of Aqueous ATP

    OpenAIRE

    Kelly, Daniel Nicholas

    2010-01-01

    Part One: Chemical Modification of Porous Alumina for Nanowire Templating: A modified sol-gel technique and subsequent polymer coating technique was used to modify the size of nanowires grown via electrodeposition in porous alumina templates. The porous alumina film is initially soaked in a water-containing solution prior to exposure to a different solution of 3-aminopropyltriethoxysilane in toluene. The amount of water in the aqueous solution correlates with the thickness of silane coating ...

  1. Fracture behavior of monazite-coated alumina fiber-reinforced alumina-matrix composites at elevated temperature

    International Nuclear Information System (INIS)

    High-temperature strength, fracture behavior and microstructure were observed for monazite-coated alumina fiber-reinforced alumina matrix composites hot-pressed at 1200-1300degC. The composites with 27-41 vol% alumina fiber showed no significant change in strength at 25-1100degC. However, the strength of the composites decreased markedly at a test temperature higher than 1100degC. The composites hot-pressed at a temperature lower than 1250degC fractured in a pseudoductile manner in the test temperature range from 25degC to 1100degC. Young's modulus of the elastic region decreased with increasing test temperature. These composites showed larger deformation at a test temperature above 1100degC. On the other hand, the composites hot-pressed at more than 1250degC fractured in a brittle manner at 25degC-1200degC of test temperature. The fracture energy of the composite increased with increasing test temperature and decreased with sintering temperature. (author)

  2. Viscosity of aqueous and cyanate ester suspensions containing alumina nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Lawler, Katherine [Iowa State Univ., Ames, IA (United States)

    2009-01-01

    The viscosities of both aqueous and cyanate ester monomer (BECy) based suspensions of alumina nanoparticle were studied. The applications for these suspensions are different: aqueous suspensions of alumina nanoparticles are used in the production of technical ceramics made by slip casting or tape casting, and the BECy based suspensions are being developed for use in an injection-type composite repair resin. In the case of aqueous suspensions, it is advantageous to achieve a high solids content with low viscosity in order to produce a high quality product. The addition of a dispersant is useful so that higher solids content suspensions can be used with lower viscosities. For BECy suspensions, the addition of nanoparticles to the BECy resin is expected to enhance the mechanical properties of the cured composite. The addition of saccharides to aqueous suspensions leads to viscosity reduction. Through DSC measurements it was found that the saccharide molecules formed a solution with water and this resulted in lowering the melting temperature of the free water according to classic freezing point depression. Saccharides also lowered the melting temperature of the bound water, but this followed a different rule. The shear thinning and melting behaviors of the suspensions were used to develop a model based on fractal-type agglomeration. It is believed that the structure of the particle flocs in these suspensions changes with the addition of saccharides which leads to the resultant viscosity decrease. The viscosity of the BECy suspensions increased with solids content, and the viscosity increase was greater than predicted by the classical Einstein equation for dilute suspensions. Instead, the Mooney equation fits the viscosity behavior well from 0-20 vol% solids. The viscosity reduction achieved at high particle loadings by the addition of benzoic acid was also investigated by NMR. It appears that the benzoic acid interacts with the surface of the alumina particle which may

  3. Anodic behaviour of oxidised Ni-Fe alloys in cryolite-alumina melts

    Energy Technology Data Exchange (ETDEWEB)

    Chapman, Vivien, E-mail: v.singleton@student.unsw.edu.a [Centre for Electrochemical and Mineral Processing, School of Chemical Engineering, University of New South Wales, Sydney 2052 (Australia); Welch, Barry J. [Welbank Consulting Ltd., PO Box 207, Whitianga 3542 (New Zealand); Skyllas-Kazacos, Maria [Centre for Electrochemical and Mineral Processing, School of Chemical Engineering, University of New South Wales, Sydney 2052 (Australia)

    2011-01-01

    Nickel-iron alloys have been identified as promising inert anode candidates for the Hall-Heroult process. In this study, binary Ni-Fe alloys of various compositions were subjected to short-term galvanostatic electrolysis in a cryolite-alumina bath at 960 {sup o}C. Prior to electrolysis, the anodes were oxidised at 800 {sup o}C for 48 h, forming a protective scale. Fe{sub 2}O{sub 3}, Ni{sub x}Fe{sub 3-x}O{sub 4} and Ni{sub x}Fe{sub 1-x}O were identified as the major scale components using a combination of X-ray diffraction (XRD) analysis and energy dispersive X-ray spectroscopy (EDX). Anodes having Ni content of 50-65 wt% performed adequately during short-term electrolysis, operating at a steady potential of 3-3.5 V vs. AlF{sub 3}/Al. Overall, it was found that the pre-formed oxide scale was effective in reducing anode wear and fluoridation. In the absence of a pre-formed scale, anodes were shown to undergo appreciable internal corrosion and/or passivation due to metal fluoride formation. Analysis of the anodes following electrolysis was performed using XRD and electron microprobe analysis (EPMA).

  4. Anodic behaviour of oxidised Ni-Fe alloys in cryolite-alumina melts

    International Nuclear Information System (INIS)

    Nickel-iron alloys have been identified as promising inert anode candidates for the Hall-Heroult process. In this study, binary Ni-Fe alloys of various compositions were subjected to short-term galvanostatic electrolysis in a cryolite-alumina bath at 960 oC. Prior to electrolysis, the anodes were oxidised at 800 oC for 48 h, forming a protective scale. Fe2O3, NixFe3-xO4 and NixFe1-xO were identified as the major scale components using a combination of X-ray diffraction (XRD) analysis and energy dispersive X-ray spectroscopy (EDX). Anodes having Ni content of 50-65 wt% performed adequately during short-term electrolysis, operating at a steady potential of 3-3.5 V vs. AlF3/Al. Overall, it was found that the pre-formed oxide scale was effective in reducing anode wear and fluoridation. In the absence of a pre-formed scale, anodes were shown to undergo appreciable internal corrosion and/or passivation due to metal fluoride formation. Analysis of the anodes following electrolysis was performed using XRD and electron microprobe analysis (EPMA).

  5. On the possibility of producing alumina ceramic with a slight electrical conductivity

    CERN Document Server

    Caspers, Fritz

    1989-01-01

    Antistatic alumina ceramic is desirable for certain particle accelerator applications. In general, highly insulating surface close to a charged particle beam must be avoided in order to prevent the formation of ion pockets and other unwanted electrical effects. For the AA vacuum chamber (UHV), an antistatic ferrite has been produced and successfully installed. The fabrication of antistatic alumina might be possible in a similar way. By using certain metal oxides in the cement, which holds the alumina particles together, a slight conductivity could be obtained after the firing and sintering process, without deteriorating the mechanical and outgassing properties of the alumina compound.

  6. The Effect of Novel Synthetic Methods and Parameters Control on Morphology of Nano-alumina Particles.

    Science.gov (United States)

    Xie, Yadian; Kocaefe, Duygu; Kocaefe, Yasar; Cheng, Johnathan; Liu, Wei

    2016-12-01

    Alumina is an inorganic material, which is widely used in ceramics, catalysts, catalyst supports, ion exchange and other fields. The micromorphology of alumina determines its application in high tech and value-added industry and its development prospects. This paper gives an overview of the liquid phase synthetic method of alumina preparation, combined with the mechanism of its action. The present work focuses on the effects of various factors such as concentration, temperature, pH, additives, reaction system and methods of calcination on the morphology of alumina during its preparation. PMID:27206644

  7. The effect of alumina nanofillers size and shape on mechanical behavior of PMMA matrix composite

    Directory of Open Access Journals (Sweden)

    Ben Hasan Somaya Ahmed

    2014-01-01

    Full Text Available Composites with the addition of alumina nanofillers show improvement in mechanical properties. The PMMA polymer was used as a matrix and two different types of nanofillers, having extremely different shapes were added in the matrix to form the composite. Reinforcements were based on alumina nanoparticles having either spherical shape or whiskers having the length to diameter ratio of 100. The influence of alumina fillers size, shape and fillers loading on mechanical properties of prepared composite were studied using the nanoindentation measurements and dynamic mechanical analysis. It was observed that both alumina whiskers and alumina spherical nanoparticles added in the PMMA matrix improved the mechanical properties of the composite but the improvement was significantly higher with alumina whisker reinforcement. The concentration of the reinforcing alumina spherical nanoparticles and alumina whiskers in PMMA matrix varied up to 5 wt. %. The best performance was obtained by the addition of 3 wt. % of alumina whiskers in the PMMA matrix with regard to mechanical properties of the obtained composite.

  8. Surface area, crystal morphology and characterization of transition alumina powders from a new gibbsite precursor

    Directory of Open Access Journals (Sweden)

    Antonio Carlos Vieira Coelho

    2007-06-01

    Full Text Available A new procedure was used to prepare a microcrystalline powder constituted by thin euhedral hexagonal gibbsite plates, 0.2 to 0.6 µm in diameter and 32 nm thick. The powder, fired between 200 and 1000 °C, produced chi and kappa transition aluminas. Alpha-alumina is formed from 1000 °C and recrystallized up to 1500 °C. At 1000 °C, kappa- and alpha-alumina coexisted, but kappa-alumina could only be characterized by SAED. The details of the internal organization of the transition alumina pseudomorphs were clearly observable in TEM due to the great thinness of the I-gibbsite plates. The specific surface area varied from pristine I-gibbsite (24.9 m².g-1 to chi- and kappa transition aluminas (25.4 m².g-1 at 1000 °C to alpha-alumina (4.0 m².g-1 at 1500 °C. The maximum value of specific surface area is 347 m².g-1 in chi-alumina powder at 300 °C, a difference from Bayer gibbsite, in which the chi-alumina highest surface area is 370 m².g-1 at 400 °C.

  9. The equation of state of two alumina-filled epoxy resins

    International Nuclear Information System (INIS)

    The shock Hugoniots of two different alumina-epoxy particulate composites have been measured in terms of shock velocity, particle velocity and shock stress. Both shock velocities and shock stresses increase with increasing amounts of alumina loading. The shock velocity-particle velocity relationships have been shown to be linear, and that with increasing alumina, behaviour shifts from a viscous to a response more commonly seen in metals and ceramics. Comparisons of the calculated hydrodynamic pressure and shock stress suggest that these materials have a constant shear strength with increasing shock stress. Finally, comparison of the material with the highest amount of alumina, with the work of others, shows close agreement

  10. Electromotive force measurements on cells involving beta-alumina solid electrolyte

    Science.gov (United States)

    Choudhury, N. S.

    1973-01-01

    Open-circuit emf measurements have been made to demonstrate that a two-phase, polycrystalline mixture of beta-alumina and alpha-alumina could be used as a solid electrolyte in galvanic cells with reversible electrodes fixing oxygen or aluminum chemical potentials. These measurements indicate that such a two-phase solid electrolyte may be used to monitor oxygen chemical potentials as low as that corresponding to Al and Al2O3 coexistence (potentials of about 10 to the minus 47th power atm at 1000 K). The activity of Na2O in beta-alumina in coexistence with alpha-alumina was also determined by emf measurements.

  11. ACCELERATOR SYSTEMS MODIFICATIONS FOR A SECOND TARGET STATION AT THE OAK RIDGE SPALLATION NEUTRON SOURCE

    Energy Technology Data Exchange (ETDEWEB)

    Galambos, John D [ORNL; Kim, Sang-Ho [ORNL; Plum, Michael A [ORNL

    2014-01-01

    A second target station is planned for the Oak Ridge Spallation Neutron Source. The ion source will be upgraded to increase the peak current from 38 to 49 mA, additional superconducting RF cavities will be added to the linac to increase the H beam energy from 938 to 1300 MeV, and the accumulator ring will receive modifications to the injection and extraction systems to accommodate the higher beam energy. After pulse compression in the storage ring one sixth of the beam pulses (10 out of 60 Hz) will be diverted to the second target by kicker and septum magnets added to the existing Ring to Target Beam Transport (RTBT) line. No further modifications will be made to the RTBT so that when the kicker and septum magnets are turned off the original beam transport lattice will be unaffected. In this paper we will discuss these and other planned modifications and upgrades to the accelerator facility.

  12. Electron cloud development in the Proton Storage Ring and in the Spallation Neutron Source

    International Nuclear Information System (INIS)

    We have applied our simulation code ''POSINST'' to evaluate the contribution to the growth rate of the electron-cloud instability in proton storage rings. Recent simulation results for the main features of the electron cloud in the storage ring of the Spallation Neutron Source(SNS) at Oak Ridge, and updated results for the Proton Storage Ring (PSR) at Los Alamos are presented in this paper. A key ingredient in our model is a detailed description of the secondary emitted-electron energy spectrum. A refined model for the secondary emission process including the so-called true secondary, rediffused and backscattered electrons has recently been included in the electron-cloud code

  13. Spallation Neutron Source Availability Top-Down Apportionment Using Characteristic Factors and Expert Opinion

    International Nuclear Information System (INIS)

    Apportionment is the assignment of top-level requirements to lower tier elements of the overall facility. A method for apportioning overall facility availability requirements among systems and subsystems is presented. Characteristics that influence equipment reliability and maintainability are discussed. Experts, using engineering judgment, scored each characteristic for each system whose availability design goal is to be established. The Analytic Hierarchy Process (AHP) method is used to produce a set of weighted rankings for each characteristic for each alternative system. A mathematical model is derived which incorporates these weighting factors. The method imposes higher availability requirements on those systems in which an incremental increase in availability is easier to achieve, and lower availability requirements where greater availability is more difficult and costly. An example is given of applying this top-down apportionment methodology to the Spallation Neutron Source (SNS) facility

  14. A spallation-based irradiation test facility for fusion and future fission materials

    CERN Document Server

    Samec, K; Kadi, Y; Luis, R; Romanets, Y; Behzad, M; Aleksan, R; Bousson, S

    2014-01-01

    The EU’s FP7 TIARA program for developing accelerator-based facilities has recently demonstrated the unique capabilities of a compact and powerful spallation source for irradiating advanced nuclear materials. The spectrum and intensity of the neutron flux produced in the proposed facility fulfils the requirements of the DEMO fusion reactor for ITER, ADS reactors and also Gen III / IV reactors. Test conditions can be modulated, covering temperature from 400 to 550°C, liquid metal corrosion, cyclical or static stress up to 500 MPa and neutron/proton irradiation damage of up to 25 DPA per annum. The entire “TMIF” facility fits inside a cube 2 metres on a side, and is dimensioned for an accelerator beam power of 100 kW, thus reducing costs and offering great versatility and flexibility.

  15. The performance of neutron spectrometers at a long-pulse spallation source

    International Nuclear Information System (INIS)

    At a recent workshop at Lawrence Berkeley National Laboratory, members of the international neutron scattering community discussed the performance to be anticipated from neutron scattering instruments installed at a 1 MW long-pulse spallation source (LPSS). Also the report of this workshop is long, its principal conclusions can be easily summarised and almost as easily understood. This article presents such a synthesis for a 60 Hz LPSS with 1 msec proton pulses. We discuss some of the limitation of the workshop conclusions and suggest a simple analysis of the performance differences that might be expected between short- and long-pulse sources both of which exploit coupled moderators. (author) 5 figs., 1 tab., 5 refs

  16. Status of pulsed spallation neutron source target work at Brookhaven National Laboratory

    International Nuclear Information System (INIS)

    This paper outlines work carried out at BNL on the Pulsed Spallation Neutron Source (PSNS) target, since the ICANS-XII meeting. A target, reflector, and moderator assembly was designed consistent with a 1.25 GeV proton beam energy. This target consisted of two modules containing randomly packed tungsten spheres and one flux trap. In addition, a study was carried out of the variation of neutron pulse length with proton pulse length for various reflector/pre-moderator configurations. It was found that: - the amplitude of the neutron pulses increases with decreasing proton pulse length, - long proton pulses overlap the neutron pulse developing in the moderator, while shorter proton pulses are complete before the neutron pulse develops in the moderator, - reflector/pro-moderators which slow neutrons by inelastic scattering result in neutron pulses which are narrower, and have shorter tails. (author) 3 figs., 2 tabs., 3 refs

  17. Computer simulations for rf design of a Spallation Neutron Source external antenna H- ion source

    International Nuclear Information System (INIS)

    Electromagnetic modeling of the multicusp external antenna H- ion source for the Spallation Neutron Source (SNS) has been performed in order to optimize high-power performance. During development of the SNS external antenna ion source, antenna failures due to high voltage and multicusp magnet holder rf heating concerns under stressful operating conditions led to rf characteristics analysis. In rf simulations, the plasma was modeled as an equivalent lossy metal by defining conductivity as σ. Insulation designs along with material selections such as ferrite and Teflon could be included in the computer simulations to compare antenna gap potentials, surface power dissipations, and input impedance at the operating frequencies, 2 and 13.56 MHz. Further modeling and design improvements are outlined in the conclusion.

  18. Conceptual design of a cold methane moderator system for the European Spallation Source (ESS)

    CERN Document Server

    Barnert-Wiemer, H

    2002-01-01

    As part of the work for the target station of the planned European spallation source (ESS) the Central Department of Technology at the Forschungszentrum Juelich GmbH is also concerned with the moderators, particular attention being given to the development of cold methane moderators. This report discusses the technical feasibility of solid methane moderators. Methods to tailor the neutron output by adding absorption materials (decouplers or poisons) are not considered here, neither are composite moderators. Based on the given target-moderator-reflector assembly of the ESS project a concept for the ESS cold methane moderators has been developed and is being examined at the Forschungszentrum Juelich. According to this moderator concept the moderator is a fixed bed of small spheres, which makes moderator container filling homogeneous and reproducible. Since spheres form a defined packed bed, cooling of the moderator bed by H sub 2 is reliable. The process of filling the moderator container and of removing the pe...

  19. An update on measurements of helium-production reactions with a spallation neutron source

    International Nuclear Information System (INIS)

    This report gives the status, updated since the last Research Coordination Meeting, of alpha-particle production cross sections, emission spectra and angular distributions which we are measuring at the spallation source of fast neutrons at the Los Alamos Meson Physics Facility (LAMPF). Detectors at angles of 30, 60, 90 and 135 degrees are used to identify alpha particles, measure their energy spectra, and indicate the time-of-flight, and hence the energy, of the neutrons inducing the reaction. The useful neutron energy ranges from less than 1 MeV to approximately 50 MeV for the present experimental setup. Targets under study at present include C, N, 0, 27Al, Si, 51V, 56Fe, 59CO, 58,60Ni, 89Y and 93Nb. Data for 59Co have been re-analyzed. The results illustrate the capabilities of the approach, agreement with literature values, and comparisons with nuclear reaction model calculations

  20. Neutronics studies of solid targets for spallation neutron source using Monte Carlo simulation

    Institute of Scientific and Technical Information of China (English)

    殷雯; 梁九卿

    2003-01-01

    Neutronics studies for a solid target have been done with Monte Carlo high-energy particle transport code NMTC/JAM,when the proton beam with high kinetic energy bombards the target.The effect of the main parameters of the target on the neutron flux is discussed to optimize the target,which will be used for the concept design of the target of spallation neutron source.A target with its aspect ratio 1.5:1 or 2:1 gives the highest neutron flux.Tungsten is the most acceptable material from the technical and economical points of view.Beryllium as a moderating reflector can increase the neutron flux effectively.

  1. Development of a fast traveling-wave beam chopper for the National Spallation Neutron Source

    Energy Technology Data Exchange (ETDEWEB)

    Kurennoy, S.S.; Jason, A.J.; Krawczyk, F.L.; Power, J.

    1997-10-01

    High current and severe restrictions on beam losses, below 1 nA/m, in the designed linac for the National Spallation Neutron Source (NSNS) require clean and fast--with the rise time from 2% to 98% less than 2.5 ns to accommodate a 402.5-MHz beam structure--beam chopping in its front end, at the beam energy 2.5 MeV. The R and D program includes both modification of the existing LANSCE coax-plate chopper to reduce parasitic coupling between adjacent plates, and development of new traveling-wave deflecting structures, in particular, based on a meander line. Using analytical methods and three-dimensional time-domain computer simulations the authors study transient effects in such structures to choose an optimal chopper design.

  2. Acceptance scan technique for the drift tube linac of the spallation neutron source

    Energy Technology Data Exchange (ETDEWEB)

    Jeon, D. [SNS Project, Oak Ridge National Laboratory, Oak Ridge, TN 37831 (United States)]. E-mail: jeond@ornl.gov; Stovall, J. [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Takeda, H. [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Nath, S. [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Billen, J. [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Young, L. [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States); Kisselev, I. [Institute for Nuclear Research of RAS, Troitsk, Russia (Russian Federation); Shishlo, A. [SNS Project, Oak Ridge National Laboratory, Oak Ridge, TN 37831 (United States); Aleksandrov, A. [SNS Project, Oak Ridge National Laboratory, Oak Ridge, TN 37831 (United States); Assadi, S. [SNS Project, Oak Ridge National Laboratory, Oak Ridge, TN 37831 (United States); Chu, C.M. [SNS Project, Oak Ridge National Laboratory, Oak Ridge, TN 37831 (United States); Cousineau, S. [SNS Project, Oak Ridge National Laboratory, Oak Ridge, TN 37831 (United States); Danilov, V. [SNS Project, Oak Ridge National Laboratory, Oak Ridge, TN 37831 (United States); Galambos, J. [SNS Project, Oak Ridge National Laboratory, Oak Ridge, TN 37831 (United States); Henderson, S. [SNS Project, Oak Ridge National Laboratory, Oak Ridge, TN 37831 (United States); Kim, S. [SNS Project, Oak Ridge National Laboratory, Oak Ridge, TN 37831 (United States); Kravchuk, L. [Institute for Nuclear Research of RAS, Troitsk, Russia (Russian Federation); Tanke, E. [SNS Project, Oak Ridge National Laboratory, Oak Ridge, TN 37831 (United States)

    2007-01-01

    For high intensity proton accelerators, it is vital to reduce the machine activation by minimizing the beam loss from many sources. One of such sources is longitudinal mismatch. To minimize a potential mismatch, it is important to set accurately the rf set-point (rf field amplitude and phase) of a high-intensity linac such as the drift tube linac (DTL) of the spallation neutron source. A widely used technique called the acceptance scan was studied extensively and applied successfully to tune the DTL tanks since the initial commissioning. From the acceptance scan one can obtain the longitudinal beam profile at the entrance of each DTL tank. But except tank 1, acceptance scan alone cannot determine the incoming beam energy deviation, leading to small uncertainties in the rf set point.

  3. THE COMMISSIONING PLAN FOR THE SPALLATION NEUTRON SOURCE RING AND TRANSPORT LINES.

    Energy Technology Data Exchange (ETDEWEB)

    RAPARIA,D.BLASKIEWICZ,M.LEE,Y.Y.WEI,J.ET AL.

    2004-03-10

    The Spallation Neutron Source (SNS) accelerator systems will provide a 1 GeV, 1.44 MW proton beam to a liquid mercury target for neutron production. In order to satisfy the accelerator systems' portion of the Critical Decision 4 (CD-4) commissioning goal (which marks the completion of the construction phase of the project), a beam pulse with intensity greater than 1 x 10{sup 13} protons must be accumulated in the ring, extracted in a single turn and delivered to the target. A commissioning plan has been formulated for bringing into operation and establishing nominal operating conditions for the various ring and transport line subsystems as well as for establishing beam conditions and parameters which meet the commissioning goal.

  4. Separation of beam and electrons in the spallation neutron source H- ion source

    International Nuclear Information System (INIS)

    The Spallation Neutron Source (SNS) requires an ion source producing an H- beam with a peak current of 35 mA at a 6.2% duty factor. For the design of this ion source, extracted electrons must be transported and dumped without adversely affecting the H- beam optics. Two issues are considered: (1) electron containment transport and controlled removal; and (2) first-order H- beam steering. For electron containment, various magnetic, geometric and electrode biasing configurations are analyzed. A kinetic description for the negative ions and electrons is employed with self-consistent fields obtained from a steady-state solution to Poisson's equation. Guiding center electron trajectories are used when the gyroradius is sufficiently small. The magnetic fields used to control the transport of the electrons and the asymmetric sheath produced by the gyrating electrons steer the ion beam. Scenarios for correcting this steering by split acceleration and focusing electrodes will be considered in some detail

  5. Computer simulations for rf design of a Spallation Neutron Source external antenna H ion source

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Sung-Woo [ORNL; Goulding, Richard Howell [ORNL; Kang, Yoon W [ORNL; Shin, Ki [ORNL; Welton, Robert F [ORNL

    2010-01-01

    Electromagnetic modeling of the multicusp external antenna H ion source for the Spallation Neutron Source SNS has been performed in order to optimize high-power performance. During development of the SNS external antenna ion source, antenna failures due to high voltage and multicusp magnet holder rf heating concerns under stressful operating conditions led to rf characteristics analysis. In rf simulations, the plasma was modeled as an equivalent lossy metal by defining conductivity as . Insulation designs along with material selections such as ferrite and Teflon could be included in the computer simulations to compare antenna gap potentials, surface power dissipations, and input impedance at the operating frequencies, 2 and 13.56 MHz. Further modeling and design improvements are outlined in the conclusion.

  6. The Design Performance of the Integrated Spallation Neutron Source Vacuum Control System

    CERN Document Server

    Tang, Johnny Y; Ladd, Peter; Williams, Derrick

    2005-01-01

    The Spallation Neutron Source vacuum control systems have been developed within a collaboration of Lawrence Berkeley National Laboratory(LBNL), Los Alamos National Laboratory(LANL), Thomas Jefferson National Accelerator Facility(TJNAF), and Brookhaven National Laboratory(BNL). Each participating lab is responsible for a different section of the machine. Although a great deal of effort has been made to standardize vacuum instrumentation components and the global control system interfaces, the varied requirements of the different sections of the machine made horizontal integration of the individual vacuum control systems both interesting and challenging. To support commissioning, the SNS control system team and the vacuum group developed a set of test strategies and the interlock schemes that allowed horizontal vacuum system integration to be effectively achieved. The design of the vacuum control interlock scheme developed will be presented together with the results of performance measurements made on these sch...

  7. A target-moderator-reflector concept of the JAERI 5 MW pulsed spallation neutron source

    International Nuclear Information System (INIS)

    In Japan Atomic Energy Research Institute the construction of a 5 MW (short) pulsed spallation neutron source is under planning using a projected high power superconducting proton (or H-) linac of 8 MW in total beam power. In the present paper we report our consideration on target-moderator-reflector concept, based on the layout of the tentative neutron instruments for the assumed neutron scattering experiments in future. The choice of cold neutron moderators for high resolution and high intensity experiments, thermal and epithermal neutron moderators for high resolution uses was discussed and a reference layout of target-moderator-reflector system was proposed for detailed neutronic calculation and optimization. The proposed system was designed like that it can provide, at least, 30 beam lines for more than 40 instruments. (author)

  8. A target-moderator-reflector concept of the JAERI 5 MW pulsed spallation neutron source

    Energy Technology Data Exchange (ETDEWEB)

    Watanabe, Noboru; Teshigawara, Makoto; Aizawa, Kazuya; Suzuki, Jyunichi; Oyama, Yukio [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment

    1998-03-01

    In Japan Atomic Energy Research Institute the construction of a 5 MW (short) pulsed spallation neutron source is under planning using a projected high power superconducting proton (or H{sup -}) linac of 8 MW in total beam power. In the present paper we report our consideration on target-moderator-reflector concept, based on the layout of the tentative neutron instruments for the assumed neutron scattering experiments in future. The choice of cold neutron moderators for high resolution and high intensity experiments, thermal and epithermal neutron moderators for high resolution uses was discussed and a reference layout of target-moderator-reflector system was proposed for detailed neutronic calculation and optimization. The proposed system was designed like that it can provide, at least, 30 beam lines for more than 40 instruments. (author)

  9. A neutron booster for spallation sources—application to accelerator driven systems and isotope production

    Science.gov (United States)

    Galy, J.; Magill, J.; Van Dam, H.; Valko, J.

    2002-06-01

    One can design a critical system with fissile material in the form of a thin layer on the inner surface of a cylindrical neutron moderator such as graphite or beryllium. Recently, we have investigated the properties of critical and near critical systems based on the use of thin actinide layers of uranium, plutonium and americium. The thickness of the required fissile layer depends on the type of fissile material, its concentration in the layer and on the geometrical arrangement, but is typically in the μm-mm range. The resulting total mass of fissile material can be as low as 100 g. Thin fissile layers have a variety of applications in nuclear technology—for example in the design neutron amplifiers for medical applications and "fast" islands in thermal reactors for waste incineration. In the present paper, we investigate the properties of a neutron booster unit for spallation sources and isotope production. In those applications a layer of fissile material surrounds the spallation source. Such a module could be developed for spallation targets foreseen in the MYRRHA (L. Van Den Durpel, H. Aı̈t Abderrahim, P. D'hondt, G. Minsart, J.L. Bellefontaine, S. Bodart, B. Ponsard, F. Vermeersch, W. Wacquier. A prototype accelerator driven system in Belgium: the Myrrha project, Technical Committee Meeting on Feasibility and Motivation for Hybrid concepts for Nuclear Energy generation and Transmutation, Madrid, Spain, September 17-19, 1997 [1]). or MEGAPIE (M. Salvatores, G.S. Bauer, G. Heusener. The MEGAPIE initiative: executive outline and status as per November 1999, MPO-1-GB-6/0_GB, 1999 [2]) projects. With a neutron multiplication factor of the booster unit in the range 10-20 (i.e. with a keff of 0.9-0.95), considerably less powerful accelerators would be required to obtain the desired neutron flux. Instead of the powerful accelerators with proton energies of 1 GeV and currents of 10 mA foreseen for accelerator driven systems, similar neutron fluxes can be obtained

  10. Proceedings of the specialists' meeting on physics and engineering of fission and spallation, 1989

    International Nuclear Information System (INIS)

    The third meeting was held on August 1, and the fourth meeting was held on December 12, 1989. The reports of the international conferences on 50 years research on nuclear fission in Germany and USA, and the reports on the nuclear data of fission-produced nuclei for evaluating reactor decay heat, the atomic mass formula considering proton-neutron interaction and unstable nuclei, research on short life fission fragments by on-line isotope separation process, the reactor physics on waste annihilation disposal and fuel breeding with an accelerator, the double differential cross section of back neutrons in nuclear spallation reaction, measurement of fission cross section and fission neutron spectra with fast neutrons, U-235 fission spectra by unfolding activation foil data and production mechanisms of intermediate mass fragments from hot nuclei-emission of complex and fission fragments for 84Kr+27Al at 10.6 MeV/u were made. (K.I.)

  11. EXPERIENCE WITH COLLABORATIVE DEVELOPMENT FOR THE SPALLATION NEUTRON SOURCE FROM A PARTNER LAB PERSPECTIVE.

    Energy Technology Data Exchange (ETDEWEB)

    HOFF, L.T.

    2005-10-10

    Collaborative development and operation of large physics experiments is fairly common. Less common is the collaborative development or operation of accelerators. A current example of the latter is the Spallation Neutron Source (SNS). The SNS project was conceived as a collaborative effort between six DOE facilities. In the SNS case, the control system was also developed collaboratively. The SNS project has now moved beyond the collaborative development phase and into the phase where Oak Ridge National Lab (ORNL) is integrating contributions from collaborating ''partner labs'' and is beginning accelerator operations. In this paper, the author reflects on the benefits and drawbacks of the collaborative development of an accelerator control system as implemented for the SNS project from the perspective of a partner lab.

  12. Development of a fast traveling-wave beam chopper for the National Spallation Neutron Source

    International Nuclear Information System (INIS)

    High current and severe restrictions on beam losses, below 1 nA/m, in the designed linac for the National Spallation Neutron Source (NSNS) require clean and fast--with the rise time from 2% to 98% less than 2.5 ns to accommodate a 402.5-MHz beam structure--beam chopping in its front end, at the beam energy 2.5 MeV. The R and D program includes both modification of the existing LANSCE coax-plate chopper to reduce parasitic coupling between adjacent plates, and development of new traveling-wave deflecting structures, in particular, based on a meander line. Using analytical methods and three-dimensional time-domain computer simulations the authors study transient effects in such structures to choose an optimal chopper design

  13. MEANDER-LINE CURRENT STRUCTURE DEVELOPMENT FOR SPALLATION NEUTRON SOURCE FAST CHOPPER

    Energy Technology Data Exchange (ETDEWEB)

    S. KURRENOY; J. POWER

    2000-10-01

    A new current structure for the fast traveling-wave 2.5-MeV beam chopper in the front end of the Spallation Neutron Source (SNS) has been suggested in [1]. The structure is based on the meander-folded notched stripline with dielectric supports and separators. Its design has been optimized using electromagnetic 3-D modeling with the MAFIA code package to provide rise and fall times in the range of 1 to 2 ns. A full-length (50 cm) prototype has been manufactured, and its preliminary measurements showed a good agreement with the calculations. Detailed measurements results and their comparison with simulations are presented. The latest front-end design requires a shorter, 35-cm chopper with a higher pulse voltage. Its meander-line current structure, based on the same principles, has also been optimized with MAFIA.

  14. Coincidence Doppler broadening study of Eurofer 97 irradiated in spallation environment

    Energy Technology Data Exchange (ETDEWEB)

    Sabelová, V., E-mail: veronika.sabelova@stuba.sk [Institute of Nuclear and Physical Engineering, Faculty of Electrical Engineering and Information Technology, Slovak University of Technology in Bratislava, Ilkovičova 3, 81219 Bratislava (Slovakia); Laboratory for Nuclear Materials, Paul Scherrer Institut, 5232 Villigen PSI (Switzerland); Kršjak, V. [Laboratory for Nuclear Materials, Paul Scherrer Institut, 5232 Villigen PSI (Switzerland); Kuriplach, J. [Department of Low Temperature Physics, Faculty of Mathematics and Physics, Charles University in Prague, V Holešovičkách 2, 18000 Prague 8 (Czech Republic); Dai, Y. [Laboratory for Nuclear Materials, Paul Scherrer Institut, 5232 Villigen PSI (Switzerland); Slugeň, V. [Institute of Nuclear and Physical Engineering, Faculty of Electrical Engineering and Information Technology, Slovak University of Technology in Bratislava, Ilkovičova 3, 81219 Bratislava (Slovakia)

    2015-03-15

    The behavior of transmutation helium during isochronal annealing of irradiated Eurofer 97 was investigated using coincidence Doppler broadening spectroscopy (CDBS). The investigated ferritic martensitic steel was irradiated in 2000 and 2001 in the frame of the STIP-II project at the Swiss neutron spallation source (SINQ) (irradiation with neutrons and protons) at the Paul Scherrer Institute (PSI). During isochronal annealing experiment, coarsening of vacancy clusters and/or growth of helium bubbles was observed at T ⩾ 500 °C. This process causes an increase of low-momentum annihilation events and related increase of the S parameter during thermal treatment of material. On the other hand, the maximum concentration of helium in small vacancy clusters (V{sub n}) was observed after annealing at 400 °C, where an excellent correlation with the calculated CDBS profiles of V{sub n} + He{sub m} clusters was found.

  15. Coincidence Doppler broadening study of Eurofer 97 irradiated in spallation environment

    Science.gov (United States)

    Sabelová, V.; Kršjak, V.; Kuriplach, J.; Dai, Y.; Slugeň, V.

    2015-03-01

    The behavior of transmutation helium during isochronal annealing of irradiated Eurofer 97 was investigated using coincidence Doppler broadening spectroscopy (CDBS). The investigated ferritic martensitic steel was irradiated in 2000 and 2001 in the frame of the STIP-II project at the Swiss neutron spallation source (SINQ) (irradiation with neutrons and protons) at the Paul Scherrer Institute (PSI). During isochronal annealing experiment, coarsening of vacancy clusters and/or growth of helium bubbles was observed at T ⩾ 500 °C. This process causes an increase of low-momentum annihilation events and related increase of the S parameter during thermal treatment of material. On the other hand, the maximum concentration of helium in small vacancy clusters (Vn) was observed after annealing at 400 °C, where an excellent correlation with the calculated CDBS profiles of Vn + Hem clusters was found.

  16. Design of the low energy beam transport line for the China spallation neutron source

    Institute of Scientific and Technical Information of China (English)

    LI Jin-Hai; OUYANG Hua-Fu; FU Shi-Nian; ZHANG Sua-Shun; HE Wei

    2008-01-01

    The design of the China Spallation Neutron Source (CSNS) low-energy beam transport (LEBT) line, which locates between the ion source and the radio-frequency quadrupole (RFQ), has been completed with the TRACE3D code. The design aims at perfect matching, primary chopping, a small emittance growth and sufficient space for beam diagnostics. The line consists of three solenoids, three vacuum chambers, two steering magnets and a pre-chopper. The total length of LEBT is about 1.74 m. This LEBT is designed to transfer 20 mA of H-pulsed beam from the ion source to the RFQ. An induction cavity is adopted as the pre-chopper.The electrostatic octupole steerer is discussed as a candidate. A four-quadrant aperture for beam scraping and beam position monitoring is designed.

  17. Department of Energy review of the National Spallation Neutron Source Project

    International Nuclear Information System (INIS)

    A Department of Energy (DOE) review of the Conceptual Design Report (CDR) for the National Spallation Neutron Source (NSNS) was conducted. The NSNS will be a new high-power spallation neutron source; initially, it will operate at 1 megawatt (MW), but is designed to be upgradeable to significantly higher power, at lower cost, when accelerator and target technologies are developed for higher power. The 53-member Review Committee examined the projected cost, schedule, technical scope, and management structure described in the CDR. For each of the major components of the NSNS, the Committee determined that the project team had produced credible designs that can be expected to work well. What remains to be done is to integrate the design of these components. With the exception of the liquid mercury target, the NSNS Project will rely heavily on proven technologies and, thus, will face a relatively low risk to successful project completion. The Total Project Cost (TPC) presented to the Committee in the CDR was $1.266 billion in as-spent dollars. In general, the Committee felt that the laboratory consortium had presented a credible estimate for each of the major components but that value engineering might produce some savings. The construction schedule presented to the Committee covered six years beginning in FY 1999. The Committee questioned whether all parts of the project could be completed according to this schedule. In particular, the linac and the conventional facilities appeared to have overly optimistic schedules. The NSNS project team was encouraged to reexamine these activities and to consider a more conservative seven-year schedule. Another concern of the Committee was the management structure. In summary, the Committee felt that this Conceptual Design Report was a very credible proposal, and that there is a high probability for successful completion of this major project within the proposed budget, although the six-year proposed schedule may be optimistic

  18. Modelling of the spallation reaction: analysis and testing of nuclear models

    International Nuclear Information System (INIS)

    The spallation reaction is considered as a 2-step process. First a very quick stage (10-22, 10-29 s) which corresponds to the individual interaction between the incident projectile and nucleons, this interaction is followed by a series of nucleon-nucleon collisions (intranuclear cascade) during which fast particles are emitted, the nucleus is left in a strongly excited level. Secondly a slower stage (10-18, 10-19 s) during which the nucleus is expected to de-excite completely. This de-excitation is performed by evaporation of light particles (n, p, d, t, 3He, 4He) or/and fission or/and fragmentation. The HETC code has been designed to simulate spallation reactions, this simulation is based on the 2-steps process and on several models of intranuclear cascades (Bertini model, Cugnon model, Helder Duarte model), the evaporation model relies on the statistical theory of Weiskopf-Ewing. The purpose of this work is to evaluate the ability of the HETC code to predict experimental results. A methodology about the comparison of relevant experimental data with results of calculation is presented and a preliminary estimation of the systematic error of the HETC code is proposed. The main problem of cascade models originates in the difficulty of simulating inelastic nucleon-nucleon collisions, the emission of pions is over-estimated and corresponding differential spectra are badly reproduced. The inaccuracy of cascade models has a great impact to determine the excited level of the nucleus at the end of the first step and indirectly on the distribution of final residual nuclei. The test of the evaporation model has shown that the emission of high energy light particles is under-estimated. (A.C.)

  19. Thermal-hydraulic simulation of mercury target concepts for a pulsed spallation neutron source

    Energy Technology Data Exchange (ETDEWEB)

    Siman-Tov, M.; Wendel, M.; Haines, J. [Oak Ridge National Lab., TN (United States)

    1996-06-01

    The Oak Ridge Spallation Neutron Source (ORSNS) is a high-power, accelerator-based pulsed spallation neutron source being designed by a multi-laboratory team led by Oak Ridge National Laboratory to achieve very high fluxes of neutrons for scientific experiments. The ORSNS is projected to have a 1 MW proton beam upgradable to 5 MW. About 60% of the beam power (1-5 MW, 17-83 kJ/pulse in 0.5 microsec at 60 cps) is deposited in the liquid metal (mercury) target having the dimensions of 65x30x10 cm (about 19.5 liter). Peak steady state power density is about 150 and 785 MW/m{sup 3} for 1 MW and 5 MW beam respectively, whereas peak pulsed power density is as high as 5.2 and 26.1 GW/m{sup 3}, respectively. The peak pulse temperature rise rate is 14 million C/s (for 5 MW beam) whereas the total pulse temperature rise is only 7 C. In addition to thermal shock and materials compatibility, key feasibility issues for the target are related to its thermal-hydraulic performance. This includes proper flow distribution, flow reversals, possible {open_quotes}hot spots{close_quotes} and the challenge of mitigating the effects of thermal shock through possible injection of helium bubbles throughout the mercury volume or other concepts. The general computational fluid dynamics (CFD) code CFDS-FLOW3D was used to simulate the thermal and flow distribution in three preliminary concepts of the mercury target. Very initial CFD simulation of He bubbles injection demonstrates some potential for simulating behavior of He bubbles in flowing mercury. Much study and development will be required to be able to `predict`, even in a crude way, such a complex phenomena. Future direction in both design and R&D is outlined.

  20. Characterisation in water experiments of a 'detached flow' free surface spallation target

    International Nuclear Information System (INIS)

    In the development of accelerator driven systems, ADS, free surface lead-bismuth spallation targets are considered as promising solutions due to their possibility for compactness, their lifetime, and their ability to transport the heat deposited by the proton beam away from the spallation zone. Experiments to characterise the hydraulics of the targets are needed to allow the validation of numerical models and to improve the design. Such experiments have been performed in water on a new concept labelled 'detached flow' geometry. This name was chosen because the liquid undergoes a free fall between the nozzle exit where the main free surface (that separating the void of the beam line from the liquid) is created and a second free surface downstream. The void surrounding the liquid jet plays the role of a buffer. The experiments show that a very stable main free surface with a small recirculation is obtained using this geometry thanks to the presence of the second free surface and the nozzle geometry. The experiments confirm that the level of the second free surface has no influence on the characteristics of the main free surface, improving the main free surface control. The influences of the mass flow rate and of the inlet velocity are evaluated. The free surface level rises linearly with an increase in mass flow rate. The recirculation zone is also stronger in this case. The opposite is found when the mass flow rate is decreased. For all mass flow rates studied, a stable free surface is obtained. Moreover, the outer shape of the liquid jet is similar at all mass flow rates. It is only dictated by the nozzle exit angle. Increasing slightly the inlet velocity for a given mass flow rate has a positive effect on the recirculation stability. The 'detached flow' target is a promising design for ADS.