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Sample records for alloy su31

  1. Electrical Resistance Alloys and Low-Expansion Alloys

    DEFF Research Database (Denmark)

    Kjer, Torben

    1996-01-01

    The article gives an overview of electrical resistance alloys and alloys with low thermal expansion. The electrical resistance alloys comprise resistance alloys, heating alloys and thermostat alloys. The low expansion alloys comprise alloys with very low expansion coefficients, alloys with very low...

  2. Metal alloy identifier

    Science.gov (United States)

    Riley, William D.; Brown, Jr., Robert D.

    1987-01-01

    To identify the composition of a metal alloy, sparks generated from the alloy are optically observed and spectrographically analyzed. The spectrographic data, in the form of a full-spectrum plot of intensity versus wavelength, provide the "signature" of the metal alloy. This signature can be compared with similar plots for alloys of known composition to establish the unknown composition by a positive match with a known alloy. An alternative method is to form intensity ratios for pairs of predetermined wavelengths within the observed spectrum and to then compare the values of such ratios with similar values for known alloy compositions, thereby to positively identify the unknown alloy composition.

  3. Alloyed steel

    International Nuclear Information System (INIS)

    The composition and properties are listed of alloyed steel for use in the manufacture of steam generators, collectors, spacers, emergency tanks, and other components of nuclear power plants. The steel consists of 0.08 to 0.11% w.w. C, 0.6 to 1.4% w.w. Mn, 0.35 to 0.6% w.w. Mo, 0.02 to 0.07% w.w. Al, 0.17 to 0.37% w.w. Si, 1.7 to 2.7% w.w. Ni, 0.03 to 0.07% w.w. V, 0.005 to 0.012% w.w. N, and the rest is Fe. The said steel showed a sufficiently low transition temperature between brittle and tough structures, a greater depth of hardenability, and better weldability than similar steels. (B.S.)

  4. Mechanical alloying in immiscible alloy systems

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    In recent years, mechanical alloying (MA) of immiscible alloy systems characterized by positive heat of mixing has been extensively investigated. The present article reviews the latest progress in MA of immiscible alloy systems including the mechanisms of non-equilibrium phase transformation and metastable phase formation of the MA-driven supersaturated solid solutions, amorphous phases and nanophase composites as well as their mechanical and physical properties related to those metastable phases.

  5. Alloy Fabrication Laboratory

    Data.gov (United States)

    Federal Laboratory Consortium — At NETL’s Alloy Fabrication Facility in Albany, OR, researchers conduct DOE research projects to produce new alloys suited to a variety of applications, from gas...

  6. PLUTONIUM-THORIUM ALLOYS

    Science.gov (United States)

    Schonfeld, F.W.

    1959-09-15

    New plutonium-base binary alloys useful as liquid reactor fuel are described. The alloys consist of 50 to 98 at.% thorium with the remainder plutonium. The stated advantages of these alloys over unalloyed plutonium for reactor fuel use are easy fabrication, phase stability, and the accompanying advantuge of providing a means for converting Th/sup 232/ into U/sup 233/.

  7. High strength alloys

    Energy Technology Data Exchange (ETDEWEB)

    Maziasz, Phillip James; Shingledecker, John Paul; Santella, Michael Leonard; Schneibel, Joachim Hugo; Sikka, Vinod Kumar; Vinegar, Harold J.; John, Randy Carl; Kim, Dong Sub

    2012-06-05

    High strength metal alloys are described herein. At least one composition of a metal alloy includes chromium, nickel, copper, manganese, silicon, niobium, tungsten and iron. System, methods, and heaters that include the high strength metal alloys are described herein. At least one heater system may include a canister at least partially made from material containing at least one of the metal alloys. At least one system for heating a subterranean formation may include a tublar that is at least partially made from a material containing at least one of the metal alloys.

  8. High strength alloys

    Energy Technology Data Exchange (ETDEWEB)

    Maziasz, Phillip James [Oak Ridge, TN; Shingledecker, John Paul [Knoxville, TN; Santella, Michael Leonard [Knoxville, TN; Schneibel, Joachim Hugo [Knoxville, TN; Sikka, Vinod Kumar [Oak Ridge, TN; Vinegar, Harold J [Bellaire, TX; John, Randy Carl [Houston, TX; Kim, Dong Sub [Sugar Land, TX

    2010-08-31

    High strength metal alloys are described herein. At least one composition of a metal alloy includes chromium, nickel, copper, manganese, silicon, niobium, tungsten and iron. System, methods, and heaters that include the high strength metal alloys are described herein. At least one heater system may include a canister at least partially made from material containing at least one of the metal alloys. At least one system for heating a subterranean formation may include a tubular that is at least partially made from a material containing at least one of the metal alloys.

  9. Creep Resistant Zinc Alloy

    Energy Technology Data Exchange (ETDEWEB)

    Frank E. Goodwin

    2002-12-31

    This report covers the development of Hot Chamber Die Castable Zinc Alloys with High Creep Strengths. This project commenced in 2000, with the primary objective of developing a hot chamber zinc die-casting alloy, capable of satisfactory service at 140 C. The core objectives of the development program were to: (1) fill in missing alloy data areas and develop a more complete empirical model of the influence of alloy composition on creep strength and other selected properties, and (2) based on the results from this model, examine promising alloy composition areas, for further development and for meeting the property combination targets, with the view to designing an optimized alloy composition. The target properties identified by ILZRO for an improved creep resistant zinc die-casting alloy were identified as follows: (1) temperature capability of 1470 C; (2) creep stress of 31 MPa (4500 psi); (3) exposure time of 1000 hours; and (4) maximum creep elongation under these conditions of 1%. The project was broadly divided into three tasks: (1) Task 1--General and Modeling, covering Experimental design of a first batch of alloys, alloy preparation and characterization. (2) Task 2--Refinement and Optimization, covering Experimental design of a second batch of alloys. (3) Task 3--Creep Testing and Technology transfer, covering the finalization of testing and the transfer of technology to the Zinc industry should have at least one improved alloy result from this work.

  10. Biocompatibility of dental alloys

    Energy Technology Data Exchange (ETDEWEB)

    Braemer, W. [Heraeus Kulzer GmbH and Co. KG, Hanau (Germany)

    2001-10-01

    Modern dental alloys have been used for 50 years to produce prosthetic dental restorations. Generally, the crowns and frames of a prosthesis are prepared in dental alloys, and then veneered by feldspar ceramics or composites. In use, the alloys are exposed to the corrosive influence of saliva and bacteria. Metallic dental materials can be classified as precious and non-precious alloys. Precious alloys consist of gold, platinum, and small amounts of non-precious components such as copper, tin, or zinc. The non-precious alloys are based on either nickel or cobalt, alloyed with chrome, molybdenum, manganese, etc. Titanium is used as Grade 2 quality for dental purposes. As well as the dental casting alloys, high purity electroplated gold (99.8 wt.-%) is used in dental technology. This review discusses the corrosion behavior of metallic dental materials with saliva in ''in vitro'' tests and the influence of alloy components on bacteria (Lactobacillus casei and Streptococcus mutans). The test results show that alloys with high gold content, cobalt-based alloys, titanium, and electroplated gold are suitable for use as dental materials. (orig.)

  11. Superplasticity in titanium alloys

    OpenAIRE

    J. Sieniawski; Motyka, M.

    2007-01-01

    Purpose: The paper reports characteristic of superplasticity phenomenon in titanium alloys and possibility of its applications.Design/methodology/approach: The main objective of the paper is to show features of superplastic forming of titanium alloys and current research trends aiming at widespread application of this technology.Findings: In the paper characteristic of selected superplastic titanium alloys was presented. The effect of microstructural parameters on superplasticity was consider...

  12. PLUTONIUM-ZIRCONIUM ALLOYS

    Science.gov (United States)

    Schonfeld, F.W.; Waber, J.T.

    1960-08-30

    A series of nuclear reactor fuel alloys consisting of from about 5 to about 50 at.% zirconium (or higher zirconium alloys such as Zircaloy), balance plutonium, and having the structural composition of a plutonium are described. Zirconium is a satisfactory diluent because it alloys readily with plutonium and has desirable nuclear properties. Additional advantages are corrosion resistance, excellent fabrication propenties, an isotropie structure, and initial softness.

  13. Corrosion resistant amorphous alloys

    International Nuclear Information System (INIS)

    A review of publication data on corrosion resistance of amorphous alloys and the methods of amorphization of surface layers of massive materials (laser treatment, iron implantation, detonation-gas spraying, cathode and ion sputtering, electrodeposition) was made. A study was made on corrosion properties of Fe66Cr11B10Si4 alloy in cast state and after laser irradiation, rendering the surface amorphous as well as the samples of Arenco iron and steel 20 with ion-plasma coatings of Fe-Cr-Ni-Ti alloy. It was established that amorphous coatings posses much higher corrosion resistance as compared to crystalline alloys on the same base

  14. Copper-tantalum alloy

    Science.gov (United States)

    Schmidt, Frederick A.; Verhoeven, John D.; Gibson, Edwin D.

    1986-07-15

    A tantalum-copper alloy can be made by preparing a consumable electrode consisting of an elongated copper billet containing at least two spaced apart tantalum rods extending longitudinally the length of the billet. The electrode is placed in a dc arc furnace and melted under conditions which co-melt the copper and tantalum to form the alloy.

  15. High temperature niobium alloys

    International Nuclear Information System (INIS)

    Niobium alloys are currently being used in various high temperature applications such as rocket propulsion, turbine engines and lighting systems. This paper presents an overview of the various commercial niobium alloys, including basic manufacturing processes, properties and applications. Current activities for new applications include powder metallurgy, coating development and fabrication of advanced porous structures for lithium cooled heat pipes

  16. Thermofluency in zirconium alloys

    International Nuclear Information System (INIS)

    A summary is presented about the theoretical and experimental results obtained at present in thermofluency under radiation in zirconium alloys. The phenomenon of thermofluency is presented in a general form, underlining the thermofluency at high temperature because this phenomenon is similar to the thermofluency under radiation, which ocurrs in zirconium alloys into the operating reactor. (author)

  17. Ultrahigh temperature intermetallic alloys

    Energy Technology Data Exchange (ETDEWEB)

    Brady, M.P.; Zhu, J.H.; Liu, C.T.; Tortorelli, P.F.; Wright, J.L.; Carmichael, C.A.; Walker, L.R. [Oak Ridge National Lab., TN (United States). Metals and Ceramics Div.

    1997-12-01

    A new family of Cr-Cr{sub 2}X based alloys with fabricability, mechanical properties, and oxidation resistance superior to previously developed Cr-Cr{sub 2}Nb and Cr-Cr{sub 2}Zr based alloys has been identified. The new alloys can be arc-melted/cast without cracking, and exhibit excellent room temperature and high-temperature tensile strengths. Preliminary evaluation of oxidation behavior at 1100 C in air indicates that the new Cr-Cr{sub 2}X based alloys form an adherent chromia-based scale. Under similar conditions, Cr-Cr{sub 2}Nb and Cr-Cr{sub 2}Zr based alloys suffer from extensive scale spallation.

  18. Alloys in energy development

    International Nuclear Information System (INIS)

    The development of new and advanced energy systems often requires the tailoring of new alloys or alloy combinations to meet the novel and often stringent requirements of those systems. Longer life at higher temperatures and stresses in aggressive environments is the most common goal. Alloy theory helps in achieving this goal by suggesting uses of multiphase systems and intermediate phases, where solid solutions were traditionally used. However, the use of materials under non-equilibrium conditions is now quite common - as with rapidly solidified metals - and the application of alloy theory must be modified accordingly. Under certain conditions, as in a reactor core, the rate of approach to equilibrium will be modified; sometimes a quasi-equilibrium is established. Thus an alloy may exhibit enhanced general diffusion at the same time as precipitate particles are being dispersed and solute atoms are being carried to vacancy sinks. We are approaching an understanding of these processes and can begin to model these complex systems

  19. HIGH-RESOLUTION SEQUENCE STRATIGRAPHY STUDY OF SINGLE SAND BODY IN THE DEVELOPMENT BLOCK OF COMPLEX FAULT BASIN: TAKE THE SECOND MEMBER OF NANTUN FORMATION OF SU 31 BLOCK OF HAILA'ER BASIN FOR EXAMPLE%复杂断陷盆地开发区块单砂体级高分辨率层序地层学研究——以海拉尔盆地苏31块南屯组二段为例

    Institute of Scientific and Technical Information of China (English)

    张世广

    2011-01-01

    High-resolution sequence stratigraphy study of single sand body have a significant meaning for accelerating, deepening and rolling the geological characteristics cognition of early exploration and development of Hailaer Basin. Using methods and principles of high-resolution sequence stratigraphy, combining drilling, logging, seismic and analysis assay data, two long-terms, 4 mid-terms, 8 short-terms and 46 ultrashort terms of base-level cycles are recognized in Second Member of Nantun Formation of Su 31 Block of Hailaer Basin. Sand body and oil-bearing sand bodies mainly develop in middle to late period of each middle base level decreased half-cycle and the early period of middle base level increased half- cycle of late period of LSC1 decreased half-cycle,early to middle period of LSC2 increased half-cycle. The degree of sand development and sand types and physical properties and oiliness become gradually good with base level decreasing. The degree of sand development and sand types and physical properties and oiliness become gradually bad with base level increasing.%单砂体级高分辨率层序地层学研究对加速深化滚动勘探开发早期海拉尔盆地地质特征认识具有重要意义.运用高分辨率层序地层学原理和方法,结合钻井、测井、地震、分析化验资料,在海拉尔盆地苏31块南屯组二段识别出2个长期、4个中期、8个短期、46个超短期基准面旋回.砂体、含油砂体主要发育于LSC1下降半旋回的晚期和LSC2上升半旋回的早至中期时期中各中期基准面下降半旋回的中至晚期和中期基准面上升半旋回的早期.随着基准面的下降,砂体发育程度、砂体类型、物性、含油性逐渐变好;随着基准面的上升,砂体发育程度、砂体类型、物性、含油性逐渐变差.

  20. Standard Specification for Copper-Aluminum-Silicon-Cobalt Alloy, Copper-Nickel-Silicon-Magnesium Alloy, Copper-Nickel-Silicon Alloy, Copper-Nickel-Aluminum-Magnesium Alloy, and Copper-Nickel-Tin Alloy Sheet and Strip

    CERN Document Server

    American Society for Testing and Materials. Philadelphia

    2015-01-01

    Standard Specification for Copper-Aluminum-Silicon-Cobalt Alloy, Copper-Nickel-Silicon-Magnesium Alloy, Copper-Nickel-Silicon Alloy, Copper-Nickel-Aluminum-Magnesium Alloy, and Copper-Nickel-Tin Alloy Sheet and Strip

  1. Refractory alloy component fabrication

    International Nuclear Information System (INIS)

    Purpose of this report is to describe joining procedures, primarily welding techniques, which were developed to construct reliable refractory alloy components and systems for advanced space power systems. Two systems, the Nb-1Zr Brayton Cycle Heat Receiver and the T-111 Alloy Potassium Boiler Development Program, are used to illustrate typical systems and components. Particular emphasis is given to specific problems which were eliminated during the development efforts. Finally, some thoughts on application of more recent joining technology are presented. 78 figures

  2. Machining of titanium alloys

    CERN Document Server

    2014-01-01

    This book presents a collection of examples illustrating the resent research advances in the machining of titanium alloys. These materials have excellent strength and fracture toughness as well as low density and good corrosion resistance; however, machinability is still poor due to their low thermal conductivity and high chemical reactivity with cutting tool materials. This book presents solutions to enhance machinability in titanium-based alloys and serves as a useful reference to professionals and researchers in aerospace, automotive and biomedical fields.

  3. Titanium alloys. Advances in alloys, processes, products and applications

    OpenAIRE

    Blenkinsop, P.

    1993-01-01

    The last few years have been a period of consolidation of existing alloys and processes. While the aerospace industry remains the principal driving force for alloy development, the paper illustrates examples of new markets being established in "older" alloys, by a combination of product/process development and a re-examination of engineering design parameters. Considerable attention is still being directed towards the titanium aluminide systems, but other more conventional alloy developments ...

  4. INVESTIGATION OF MAGNESIUM ALLOYS MACHINABILITY

    Directory of Open Access Journals (Sweden)

    Berat Barıs BULDUM

    2013-01-01

    Full Text Available Magnesium is the lightest structural metal. Magnesium alloys have a hexagonal lattice structure, which affects the fundamental properties of these alloys. Plastic deformation of the hexagonal lattice is more complicated than in cubic latticed metals like aluminum, copper and steel. Magnesium alloy developments have traditionally been driven by industry requirements for lightweight materials to operate under increasingly demanding conditions. Magnesium alloys have always been attractive to designers due to their low density, only two thirds that of aluminium and its alloys [1]. The element and its alloys take a big part of modern industry needs. Especially nowadays magnesium alloys are used in automotive and mechanical (trains and wagons manufacture, because of its lightness and other features. Magnesium and magnesium alloys are the easiest of all metals to machine, allowing machining operations at extremely high speed. All standard machining operations such as turning, drilling, milling, are commonly performed on magnesium parts.

  5. Structural thermodynamics of alloys

    CERN Document Server

    Manenc, Jack

    1973-01-01

    Technical progress has for a very long time been directly dependent on progress in metallurgy, which is itself connected with improvements in the technology of alloys. Metals are most frequently used in the form of alloys for several reasons: the quantity of pure metal in its native state in the earth's crust is very limited; pure metals must be extracted from ores which are themselves impure. Finally, the methods of treatment used lead more easily to alloys than to pure metals. The most typical case is that of iron, where a pure ore may be found, but which is the starting point for cast iron or steel, alloys of iron and carbon. In addition, the properties of alloys are in general superior to those of pure metals and modem metallurgy consists of controlling these properties so as to make them conform to the requirements of the design office. Whilst the engineer was formerly compelled to adapt his designs and constructions to the materials available, such as wood, stone, bronze, iron, cast iron and ordinary st...

  6. INVESTIGATION OF MAGNESIUM ALLOYS MACHINABILITY

    OpenAIRE

    Berat Barıs BULDUM; Aydın SIK; Iskender OZKUL

    2013-01-01

    Magnesium is the lightest structural metal. Magnesium alloys have a hexagonal lattice structure, which affects the fundamental properties of these alloys. Plastic deformation of the hexagonal lattice is more complicated than in cubic latticed metals like aluminum, copper and steel. Magnesium alloy developments have traditionally been driven by industry requirements for lightweight materials to operate under increasingly demanding conditions. Magnesium alloys have always been attra...

  7. Productive Machining of Titanium Alloys

    OpenAIRE

    Čejka, Libor

    2013-01-01

    This diploma thesis is focused on a productive machining of titanium alloys. At the beginning it deals about titanium and its alloys. It describes chip generation mechanism, tool blunting and surface quality. Further it contains modern strategies of efficient titanium alloys machining. Then it analyzes contemporary manufacturing technology of hinge made of titanium alloy Ti-6Al-4V in Frentech Aerospace s.r.o. company, and at the end finds possibility of savings by inovation of roughing process.

  8. De-alloyed platinum nanoparticles

    Science.gov (United States)

    Strasser, Peter; Koh, Shirlaine; Mani, Prasanna; Ratndeep, Srivastava

    2011-08-09

    A method of producing de-alloyed nanoparticles. In an embodiment, the method comprises admixing metal precursors, freeze-drying, annealing, and de-alloying the nanoparticles in situ. Further, in an embodiment de-alloyed nanoparticle formed by the method, wherein the nanoparticle further comprises a core-shell arrangement. The nanoparticle is suitable for electrocatalytic processes and devices.

  9. Shape Memory Alloys

    Directory of Open Access Journals (Sweden)

    Deexith Reddy

    2016-07-01

    Full Text Available Shape memory alloys (SMAs are metals that "remember" their original shapes. SMAs are useful for such things as actuators which are materials that "change shape, stiffness, position, natural frequency, and other mechanical characteristics in response to temperature or electromagnetic fields" The potential uses for SMAs especially as actuators have broadened the spectrum of many scientific fields. The study of the history and development of SMAs can provide an insight into a material involved in cutting-edge technology. The diverse applications for these metals have made them increasingly important and visible to the world. This paper presents the working of shape memory alloys , the phenomenon of super-elasticity and applications of these alloys.

  10. Double Glow Plasma Surface Alloyed Burn-resistant Titanium Alloy

    Institute of Scientific and Technical Information of China (English)

    ZHANGPing-ze; XUZhong; HEZhi-yong; ZHANGGao-hui

    2004-01-01

    Conventional titanium alloy may be ignited and burnt under high temperature, high pressure and high gas flow velocity condition. In order to avoid this problem, we have developed a new kind of burn-resistant titanium alloy-double glow plasma surface alloying burn-resistant titanium alloy. Alloying element Cr, Mo, Cu are induced into the Ti-6A1-4V and Ti-6.5Al-0.3Mo-1.5Zr-0.25Si substrates according to double glow discharge phenomenon, Ti-Cr ,Ti-Mo, Ti-Cu binary burn-resistant alloy layers are formed on the surface of Ti-6A1-4V and Ti-6.5Al-0.3Mo-1.5Zr-0.25Si alloys. The depth of the surface burn-resistant alloy layer can reach to above 200 microns and alloying element concentration can reach 90%. Burn-resistant property experiments reveal that if Cr concentration reach to 14%, Cu concentration reach to 12%, Mo concentration reach to 10% in the alloying layers, ignition and burn of titanium alloy can be effectively avoided.

  11. Double Glow Plasma Surface Alloyed Burn-resistant Titanium Alloy

    Institute of Scientific and Technical Information of China (English)

    ZHANG Ping-ze; XU Zhong; HE Zhi-yong; ZHANG Gao-hui

    2004-01-01

    Conventional titanium alloy may be ignited and burnt under high temperature, high pressure and high gas flow velocity condition. In order to avoid this problem, we have developed a new kind of burn-resistant titanium alloy-double glow plasma surface alloying burn-resistant titanium alloy. Alloying element Cr, Mo, Cu are induced into the Ti-6Al-4V and Ti-6.5Al-0.3Mo-l.5Zr-0.25Si substrates according to double glow discharge phenomenon, Ti-Cr ,Ti-Mo, Ti-Cu binary burn-resistant alloy layers are formed on the surface of Ti-6Al-4V and Ti-6.5Al-0.3Mo-l.5Zr-0.25Si alloys. The depth of the surface burn-resistant alloy layer can reach to above 200 microns and alloying element concentration can reach 90%.Burn-resistant property experiments reveal that if Cr concentration reach to 14%, Cu concentration reach to 12%, Mo concentration reach to 10% in the alloying layers, ignition and burn of titanium alloy can be effectively avoided.

  12. Machining of Titanium Alloys

    OpenAIRE

    Karásek, Jan

    2008-01-01

    The main goal of this work is the analysis of manufacturing costs for the component of wheel´s blower. Followed by setting up the size of specific cutting force for milling operation of the titanium alloy Ti-Al6-Mo2-Cr2-Fe-Si, the used tool was a milling cutter which is made out of sintered carbide with conical and spherical face. The final values which are at intervals of 1500 to 1800 MPa were compared with the values of the Sandvik Coromant firm kc = 1690 MPa, for titanium alloy with the st...

  13. Tungsten Alloy Outgassing Measurements

    CERN Document Server

    Rutherfoord, John P; Shaver, L

    1999-01-01

    Tungsten alloys have not seen extensive use in liquid argon calorimeters so far. Because the manufacturing process for tungsten is different from the more common metals used in liquid argon there is concern that tungsten could poison the argon thereby creating difficulties for precision calorimetry. In this paper we report measurements of outgassing from the tungsten alloy slugs proposed for use in the ATLAS FCal module and estimate limits on potential poisoning with reasonable assumptions. This estimate gives an upper limit poisoning rate of

  14. Galvanic corrosion in odontological alloys

    International Nuclear Information System (INIS)

    Galvanic corrosion can occur when different alloys are placed in direct contact within the oral cavity or within tissues. Concern has been expressed associated with the coupling of selected restorative materials as well as implant material with various alloys used for restorative procedures. This could be critical if the crown or bridge had subgingival finish line with a metallic zone in contact with the tissue, and the implant was made in titanium alloy. The present work shows the results of galvanic coupling studies done on implants of titanium alloy connected to nickel-chromium and cobalt-chromium alloys. (Author)

  15. High strength ferritic alloy

    International Nuclear Information System (INIS)

    A high strength ferritic steel is specified in which the major alloying elements are chromium and molybdenum, with smaller quantities of niobium, vanadium, silicon, manganese and carbon. The maximum swelling is specified for various irradiation conditions. Rupture strength is also specified. (U.K.)

  16. The in-situ Ti alloying of aluminum alloys and its application in A356 alloys

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    This research has investigated the in-situ Ti alloying of aluminum alloys and its application to A356 alloys and wheels through the evaluation of microstructure and mechanical properties, The results showed that stable titanium content can be obtained by adding a small quantity of TiO2 into electrolyte of pure aluminum. Under this approach, a greater than 95% absorptivity of titanium was achieved, and the microstructure of the specimens was changed to fine equiaxed grains from coarse columnar grains in the pure aluminum. In comparison with the tradition A356 alloys and wheels, the corresponding microstructure in the testing A356 alloys and wheels was finer. Although the tensile strength was similar between the testing and the tradition A356 alloys and wheels, the ductility of the former (testing) is superior to that of the later (tradition), leading to an excellent combination of strength and ductility from the testing alloys and wheels.

  17. Advanced ordered intermetallic alloy deployment

    Energy Technology Data Exchange (ETDEWEB)

    Liu, C.T.; Maziasz, P.J.; Easton, D.S. [Oak Ridge National Lab., TN (United States)

    1997-04-01

    The need for high-strength, high-temperature, and light-weight materials for structural applications has generated a great deal of interest in ordered intermetallic alloys, particularly in {gamma}-based titanium aluminides {gamma}-based TiAl alloys offer an attractive mix of low density ({approximately}4g/cm{sup 3}), good creep resistance, and high-temperature strength and oxidation resistance. For rotating or high-speed components. TiAl also has a high damping coefficient which minimizes vibrations and noise. These alloys generally contain two phases. {alpha}{sub 2} (DO{sub 19} structure) and {gamma} (L 1{sub 0}), at temperatures below 1120{degrees}C, the euticoid temperature. The mechanical properties of TiAl-based alloys are sensitive to both alloy compositions and microstructure. Depending on heat-treatment and thermomechanical processing, microstructures with near equiaxed {gamma}, a duplex structure (a mix of the {gamma} and {alpha}{sub 2} phases) can be developed in TiAl alloys containing 45 to 50 at. % Al. The major concern for structural use of TiAl alloys is their low ductility and poor fracture resistance at ambient temperatures. The purpose of this project is to improve the fracture toughness of TiAl-based alloys by controlling alloy composition, microstructure and thermomechanical treatment. This work is expected to lead to the development of TiAl alloys with significantly improved fracture toughness and tensile ductility for structural use.

  18. Filler metal alloy for welding cast nickel aluminide alloys

    Science.gov (United States)

    Santella, M.L.; Sikka, V.K.

    1998-03-10

    A filler metal alloy used as a filler for welding cast nickel aluminide alloys contains from about 15 to about 17 wt. % chromium, from about 4 to about 5 wt. % aluminum, equal to or less than about 1.5 wt. % molybdenum, from about 1 to about 4.5 wt. % zirconium, equal to or less than about 0.01 wt. % yttrium, equal to or less than about 0.01 wt. % boron and the balance nickel. The filler metal alloy is made by melting and casting techniques such as are melting the components of the filler metal alloy and cast in copper chill molds. 3 figs.

  19. Filler metal alloy for welding cast nickel aluminide alloys

    Energy Technology Data Exchange (ETDEWEB)

    Santella, Michael L. (Knoxville, TN); Sikka, Vinod K. (Oak Ridge, TN)

    1998-01-01

    A filler metal alloy used as a filler for welding east nickel aluminide alloys contains from about 15 to about 17 wt. % chromium, from about 4 to about 5 wt. % aluminum, equal to or less than about 1.5 wt. % molybdenum, from about 1 to about 4.5 wt. % zirconium, equal to or less than about 0.01 wt. % yttrium, equal to or less than about 0.01 wt. % boron and the balance nickel. The filler metal alloy is made by melting and casting techniques such as are melting the components of the filler metal alloy and east in copper chill molds.

  20. High-temperature Titanium Alloys

    Directory of Open Access Journals (Sweden)

    A.K. Gogia

    2005-04-01

    Full Text Available The development of high-temperature titanium alloys has contributed significantly to the spectacular progress in thrust-to-weight ratio of the aero gas turbines. This paper presents anoverview on the development of high-temperature titanium alloys used in aero engines and potential futuristic materials based on titanium aluminides and composites. The role of alloychemistry, processing, and microstructure, in determining the mechanical properties of titanium alloys is discussed. While phase equilibria and microstructural stability consideration haverestricted the use of conventional titanium alloys up to about 600 "C, alloys based on TiPl (or,, E,AINb (0, TiAl (y, and titaniumltitanium aluminides-based composites offer a possibility ofquantum jump in the temperature capability of titanium alloys.

  1. Rare earth ferrosilicon alloy

    International Nuclear Information System (INIS)

    In order to obtain RE ferrosilicon alloy with good quality and competitive price, it is essential that proper choice of raw materials, processing technology and equipments should be made based on the characteristics of Bai-Yun-Ebo mineral deposits. Experimental work and actual production practice indicate that pyrometallurgical method is suitable for the extraction and isolation of the rare earths and comprehensive utilization of the metal values contained in the feed material is capable of reducing cost of production of RE ferrosilicon alloy. In the Bai-Yun-Ebo deposit, the fluorite type medium lean ore (with respect to iron content) makes a reserve of considerable size. The average content of the chief constituents are given

  2. High-temperature Titanium Alloys

    OpenAIRE

    A.K. Gogia

    2005-01-01

    The development of high-temperature titanium alloys has contributed significantly to the spectacular progress in thrust-to-weight ratio of the aero gas turbines. This paper presents anoverview on the development of high-temperature titanium alloys used in aero engines and potential futuristic materials based on titanium aluminides and composites. The role of alloychemistry, processing, and microstructure, in determining the mechanical properties of titanium alloys is discussed. While phase eq...

  3. Multicomponent and High Entropy Alloys

    Directory of Open Access Journals (Sweden)

    Brian Cantor

    2014-08-01

    Full Text Available This paper describes some underlying principles of multicomponent and high entropy alloys, and gives some examples of these materials. Different types of multicomponent alloy and different methods of accessing multicomponent phase space are discussed. The alloys were manufactured by conventional and high speed solidification techniques, and their macroscopic, microscopic and nanoscale structures were studied by optical, X-ray and electron microscope methods. They exhibit a variety of amorphous, quasicrystalline, dendritic and eutectic structures.

  4. Pareto-optimal alloys

    DEFF Research Database (Denmark)

    Bligaard, Thomas; Johannesson, Gisli Holmar; Ruban, Andrei;

    2003-01-01

    Large databases that can be used in the search for new materials with specific properties remain an elusive goal in materials science. The problem is complicated by the fact that the optimal material for a given application is usually a compromise between a number of materials properties and the ......, the Pareto-optimal set, to determine optimal alloy solutions for the compromise between low compressibility, high stability, and cost....

  5. Alloy catalyst material

    DEFF Research Database (Denmark)

    2014-01-01

    The present invention relates to a novel alloy catalyst material for use in the synthesis of hydrogen peroxide from oxygen and hydrogen, or from oxygen and water. The present invention also relates to a cathode and an electrochemical cell comprising the novel catalyst material, and the process use...... of the novel catalyst material for synthesising hydrogen peroxide from oxygen and hydrogen, or from oxygen and water....

  6. Oligocrystalline shape memory alloys

    Energy Technology Data Exchange (ETDEWEB)

    Ueland, Stian M.; Chen, Ying; Schuh, Christopher A. [Department of Materials Science and Engineering, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, MA 02139 (United States)

    2012-05-23

    Copper-based shape memory alloys (SMAs) exhibit excellent shape memory properties in single crystalline form. However, when they are polycrystalline, their shape memory properties are severely compromised by brittle fracture arising from transformation strain incompatibility at grain boundaries and triple junctions. Oligocrystalline shape memory alloys (oSMAs) are microstructurally designed SMA structures in which the total surface area exceeds the total grain boundary area, and triple junctions can even be completely absent. Here it is shown how an oligocrystalline structure provides a means of achieving single crystal-like SMA properties without being limited by constraints of single crystal processing. Additionally, the formation of oSMAs typically involves the reduction of the size scale of specimens, and sample size effects begin to emerge. Recent findings on a size effect on the martensitic transformation in oSMAs are compared and a new regime of heat transfer associated with the transformation heat evolution in these alloys is discussed. New results on unassisted two-way shape memory and the effect of loading rate in oSMAs are also reported. (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  7. Aluminum alloy impact sparkling

    Directory of Open Access Journals (Sweden)

    M. Dudyk

    2008-08-01

    Full Text Available The cast machine parts are widely used in many branches of industry. A very important issue is gaining the appropriate knowledge relating to the application of castings in places of explosion risks including but not limited to mining, chemical industry and rescue works. A possibility of explosion risks occurrence following the impact sparkling of the cast metal parts is still not solved problem in scientific research. In relation to this issue, in this article, the results of the study are presented, and relating to the tendency to impact sparkling of the aluminium alloys used in machine building. On the grounds of the results obtained, it was demonstrated that the registered impact sparkles bunches of feathers from the analyzed alloys: AlSi7Mg, (AK7; AlSi9Mg, (AK9; AlSi6Cu4, (AK64 and AlSi11, (AK11 show significant differences between each other. The quantitative analysis of the temperature distribution and nuclei surface area performed on the example of the alloy AK9 (subjected to defined period of corrosion allows for the statement that they are dangerous in conditions of explosion risk. Following this fact, designers and users of machine parts made from these materials should not use them in conditions where the explosive mixtures occur.

  8. Shape memory alloy thaw sensors

    Science.gov (United States)

    Shahinpoor, Mohsen; Martinez, David R.

    1998-01-01

    A sensor permanently indicates that it has been exposed to temperatures exceeding a critical temperature for a predetermined time period. An element of the sensor made from shape memory alloy changes shape when exposed, even temporarily, to temperatures above the Austenitic temperature of the shape memory alloy. The shape change of the SMA element causes the sensor to change between two readily distinguishable states.

  9. Mo-Si alloy development

    Energy Technology Data Exchange (ETDEWEB)

    Liu, C.T.; Heatherly, L.; Wright, J.L. [Oak Ridge National Lab., TN (United States)

    1996-06-01

    The objective of this task is to develop new-generation corrosion-resistant Mo-Si intermetallic alloys as hot components in advanced fossil energy conversion and combustion systems. The initial effort is devoted to Mo{sub 5}-Si{sub 3}-base (MSB) alloys containing boron additions. Three MSB alloys based on Mo-10.5Si-1.1B (wt %), weighing 1500 g were prepared by hot pressing of elemental and alloy powders at temperatures to 1600{degrees}C in vacuum. Microporosities and glassy-phase (probably silicate phases) formations are identified as the major concerns for preparation of MSB alloys by powder metallurgy. Suggestions are made to alleviate the problems of material processing.

  10. Glass formation in eutectic alloys

    International Nuclear Information System (INIS)

    We have analyzed the glass forming ability around eutectic composition in terms of the competitive growth/formation of primary dendrites, eutectic and glass. It is concluded that the glass forming ability of a eutectic alloy system depends on the type of the eutectics, i.e. symmetric or asymmetric eutectic coupled zone. For the alloy systems with symmetric eutectic coupled zone, the best glass forming alloys should be at or very close to the eutectic composition. For the alloys with asymmetric eutectic coupled zone, which is associated with the irregular eutectic, the best glass forming alloys should be at off-eutectic compositions, probably towards the side of the faceted phase with a high entropy in the phase diagram. (orig.)

  11. Wedlable nickel aluminide alloy

    Energy Technology Data Exchange (ETDEWEB)

    Santella, Michael L. (Knoxville, TN); Sikka, Vinod K. (Oak Ridge, TN)

    2002-11-19

    A Ni.sub.3 Al alloy with improved weldability is described. It contains about 6-12 wt % Al, about 6-12 wt % Cr, about 0-3 wt % Mo, about 1.5-6 wt % Zr, about 0-0.02 wt % B and at least one of about 0-0.15 wt % C, about 0-0.20 wt % Si, about 0-0.01 wt % S and about 0-0.30 wt % Fe with the balance being Ni.

  12. Heating uranium alloy billets

    International Nuclear Information System (INIS)

    Data were obtained for the surface heat transfer coefficient of uranium and the alloys of uranium-0.75 wt percent titanium, uranium-6 wt percent niobium, and uranium-7.5 wt percent niobium-2.5 wt percent zirconium. Samples were heated to 8500C in both a molten salt bath and an argon-purged air furnace, then the samples were cooled in air. Surface heat transfer coefficients were calculated from the experimental data for both heating and cooling of the metals. 4 fig, 4 tables

  13. Stable palladium alloys for diffusion of hydrogen

    Science.gov (United States)

    Patapoff, M.

    1973-01-01

    Literature search on hydrogen absorption effect on palladium alloys revealed existence of alloy compositions in which alpha--beta transition does not take place. Survey conclusions: 40 percent gold alloy of palladium should be used in place of palladium; alloy must be free of interstitial impurities; and metallic surfaces of tube must be clean.

  14. Corrosion of aluminum alloys as a function of alloy composition

    International Nuclear Information System (INIS)

    A study was initiated which included nineteen aluminum alloys. Tests were conducted in high purity water at 3600C and flow tests (approx. 20 ft/sec) in reactor process water at 1300C (TF-18 loop tests). High-silicon alloys and AlSi failed completely in the 3600C tests. However, coupling of AlSi to 8001 aluminum suppressed the failure. The alloy compositions containing iron and nickel survived tht 3600C autoclave exposures. Corrosion rates varied widely as a function of alloy composition, but in directions which were predictable from previous high-temperature autoclave experience. In the TF-18 loop flow tests, corrosion penetrations were similar on all of the alloys and on high-purity aluminum after 105 days. However, certain alloys established relatively low linear corrosion rates: Al-0.9 Ni-0.5 Fe-0.1 Zr, Al-1.0 Ni-0.15 Fe-11.5 Si-0.8 Mg, Al-1.2 Ni-1.8 Fe, and Al-7.0 Ni-4.8 Fe. Electrical polarity measurements between AlSi and 8001 alloys in reactor process water at temperatures up to 1500C indicated that AlSi was anodic to 8001 in the static autoclave system above approx. 500C

  15. Galvanic cells including cobalt-chromium alloys.

    Science.gov (United States)

    Gjerdet, N R

    1980-01-01

    Galvanic cells may be created when dentures made of cobalt-chromium alloys are placed on teeth with metallic restorations. The power of such cells was evaluated in an in vitro galvanic using amalgams, gold alloy, and nickel-chromium alloys. The amalgams and one of the nickel-chromium alloys revealed high corrosion currents when placed in contact with cobalt-chromium alloy, the conventional amalgam showing the highest values. The gold alloy and another nickel-chromium alloy exhibited low corrosion currents and they were noble with respect to cobalt-chromium.

  16. [Prosthetic dental alloys. 1].

    Science.gov (United States)

    Quintero Engelmbright, M A

    1990-11-01

    A wide variety of restoration materials for prosthetic odontology is now available to the dental surgeon, either of the covalent type (acrylic resins), metallic (alloys), ionic (porcelains), or a combination of them, as in the so-called composites, such as the composite resins, or as ceramics-metals mixtures. An example of the latter is a product called Miracle-Mix, a glass ionomere cement reinforced with an amalgam alloy. In those cases where the blend is done by a synterization process, the material is called Cermet. The above-listed alternatives clearly evidence day-to-day advances in odontology, with researchers and manufacturers engaged the world over in improving existing products or developing new ones to enrich the dentist's armamentarium. As a side effect of this constant renewal, those dentists who have failed to update their knowledge fall behind in their practice as they persist in using products they have known for years, and may be deceived by advertisements of too-often unreliable products. It is, therefore, important to be aware of available products and their latest improvements. PMID:2132464

  17. [Prosthetic dental alloys (2)].

    Science.gov (United States)

    Quintero Englembright, M A

    1990-12-01

    A wide variety of restoration materials for prosthetic odontology is now available to the dental surgeon, either of the covalent type (acrylic resins), metallic (alloys), ionic (porcelains), or a combination of them, as in the so-called composites, such as the composite resins, or as ceramics-metals mixtures. An example of the latter is a product called Miracle-Mix, a glass ionomere cement reinforced with an amalgam alloy. In those cases where the blend is done by a synterization process, the material is called Cermet. The above-listed alternatives clearly evidence day-to-day advances in odontology, with researchers and manufacturers engaged the world over in improving existing products or developing new ones to enrich the dentist's armamentarium. As a side effect of this constant renewal, those dentists who have failed to update their knowledge fall behind in their practice as they persist in using products they have known for years, and may be deceived by advertisements of too-often unreliable products. It is, therefore, important to be aware of available products and their latest improvements. PMID:2132470

  18. Density of Liquid Ni-Cr Alloy

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    The density of liquid Ni-Cr alloy was measured by a modified sessile drop method. The density of liquid Ni-Cr alloywas found to decrease with increasing temperature and Cr concentration in the alloy. The molar volume of liquidNi-Cr alloy increases with increasing the Cr concentration in the alloy. The molar volume of Ni-Cr alloy determinedin the present work shows a positive deviation from the linear molar volume.

  19. Mechanically Alloyed High Entropy Composite

    Science.gov (United States)

    Popescu, G.; Adrian, M. M.; Csaki, I.; Popescu, C. A.; Mitrică, D.; Vasile, S.; Carcea, I.

    2016-08-01

    In the last years high entropy alloys have been investigated due to their high hardness, high temperature stability and unusual properties that make these alloys to have significant interest. In comparison with traditional alloys that are based on two or three major elements, this new generation alloys consists at least of 5 principal elements, with the concentration between 5 and 35 at.%. The present paper reports synthesis of high entropy alloys (HEA) and high entropy composites (HEC) synthesized by mechanical alloying (MA). The equiatomic AlCrFeNiMn matrix was used for creating the HEA matrix, starting from elemental powders and as reinforcing material for composites was used pure graphite. The mechanical alloying process was carried out at different duration, in a high energy planetary ball mill, under argon atmosphere. The elemental powders alloying began after '5 hours of milling and was complete after 40 hours. The mechanical alloyed matrix and composite was pressed and heat treated under argon protection. The elemental powers were investigated for physical - technological properties, and by X-ray diffraction and scanning electron microscopy. Phase pressing operation was realized with a hydraulic press and the applied pressure was progressive. The sintering process was carried out at 850°C for 2 h. The X-ray diffraction revealed that the MA process resulted in solid solutions formation and also revealed body- centred cubic (BCC) and face-centred cubic (FCC) structures with average grain size around 40 nm. In addition, nanoscale particles were highlighted by scanning electron microscopy, as well as the homogeneity of the chemical composition of the matrix and composite that was confirmed by EDX microanalysis. It was noted that HEA matrix and HEA composites were processed with a high degree of compaction and with a quite large capacity of mixed powder densification (around 70%).

  20. Alloying and Casting Furnace for Shape Memory Alloys Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The concept in the proposed project is to create a melting, alloying and casting furnace for the processing titanium based SMA using cold crucible techniques. The...

  1. Laser surface alloying of aluminium-transition metal alloys

    Directory of Open Access Journals (Sweden)

    Almeida, A.

    1998-04-01

    Full Text Available Laser surface alloying has been used as a tool to produce hard and corrosion resistant Al-transition metal (TM alloys. Cr and Mo are particularly interesting alloying elements to produce stable highstrength alloys because they present low diffusion coefficients and solid solubility in Al. To produce Al-TM surface alloys a two-step laser process was developed: firstly, the material is alloyed using low scanning speed and secondly, the microstructure is modified by a refinement step. This process was used in the production of Al-Cr, Al-Mo and Al-Nb surface alloys by alloying Cr, Mo or Nb powder into an Al and 7175 Al alloy substrate using a CO2 laser. This paper presents a review of the work that has been developed at Instituto Superior Tecnico on laser alloying of Al-TM alloys, over the last years.

    En el presente trabajo se estudia la aleación superficial mediante láser de aluminio con metales de transición. El cromo y el molibdeno son particularmente interesantes porque producen aleaciones de alta resistencia y por el bajo coeficiente de difusión y solución sólida en aluminio. Para producir estas aleaciones se ha seguido un procedimiento desarrollado en dos partes. En primer lugar, el material se alea usando una baja velocidad de procesado y en segundo lugar la estructura se modifica mediante un refinamiento posterior. Este procedimiento se ha empleado en la producción de aleaciones Al-Cr, Al-Mo y Al-Nb mediante aleación con láser de CO2 de polvos de Cr, Mo o Nb en aluminio y la aleación 7175. Este trabajo es una revisión del desarrollado en el Instituto Superior Técnico de Lisboa en los últimos años.

  2. Mechanical alloying of biocompatible Co-28Cr-6Mo alloy.

    Science.gov (United States)

    Sánchez-De Jesús, F; Bolarín-Miró, A M; Torres-Villaseñor, G; Cortés-Escobedo, C A; Betancourt-Cantera, J A

    2010-07-01

    We report on an alternative route for the synthesis of crystalline Co-28Cr-6Mo alloy, which could be used for surgical implants. Co, Cr and Mo elemental powders, mixed in an adequate weight relation according to ISO Standard 58342-4 (ISO, 1996), were used for the mechanical alloying (MA) of nano-structured Co-alloy. The process was carried out at room temperature in a shaker mixer mill using hardened steel balls and vials as milling media, with a 1:8 ball:powder weight ratio. Crystalline structure characterization of milled powders was carried out by X-ray diffraction in order to analyze the phase transformations as a function of milling time. The aim of this work was to evaluate the alloying mechanism involved in the mechanical alloying of Co-28Cr-6Mo alloy. The evolution of the phase transformations with milling time is reported for each mixture. Results showed that the resultant alloy is a Co-alpha solid solution, successfully obtained by mechanical alloying after a total of 10 h of milling time: first Cr and Mo are mechanically prealloyed for 7 h, and then Co is mixed in for 3 h. In addition, different methods of premixing were studied. The particle size of the powders is reduced with increasing milling time, reaching about 5 mum at 10 h; a longer time promotes the formation of aggregates. The morphology and crystal structure of milled powders as a function of milling time were analyzed by scanning electron microscopy and XR diffraction. PMID:20364362

  3. Dislocation Formation in Alloys

    Science.gov (United States)

    Minami, Akihiko; Onuki, Akira

    2006-05-01

    An interaction between dislocations and phase transitions is studied by a phase field model both in two and three dimensional systems. Our theory is a simple extension of the traditional linear elastic theory, and the elastic energy is a periodic function of local strains which is reflecting the periodicity of crystals. We find that the dislocations are spontaneously formed by quenching. Dislocations are formed from the interface of binary alloys, and slips are preferentially gliding into the soft metals. In three dimensional systems, formation of dislocations under applied strain is studied in two phase state. We find that the dislocation loops are created from the surface of hard metals. We also studied the phase separation above the coexisting temperature which is called as the Cottrell atmosphere. Clouds of metals cannot catch up with the motion of dislocations at highly strained state.

  4. Lead telluride alloy thermoelectrics

    Directory of Open Access Journals (Sweden)

    Aaron D. LaLonde

    2011-11-01

    Full Text Available The opportunity to use solid-state thermoelectrics for waste heat recovery has reinvigorated the field of thermoelectrics in tackling the challenges of energy sustainability. While thermoelectric generators have decades of proven reliability in space, from the 1960s to the present, terrestrial uses have so far been limited to niche applications on Earth because of a relatively low material efficiency. Lead telluride alloys were some of the first materials investigated and commercialized for generators but their full potential for thermoelectrics has only recently been revealed to be far greater than commonly believed. By reviewing some of the past and present successes of PbTe as a thermoelectric material we identify the issues for achieving maximum performance and successful band structure engineering strategies for further improvements that can be applied to other thermoelectric materials systems.

  5. Emissivity measurements on aeronautical alloys

    Energy Technology Data Exchange (ETDEWEB)

    Campo, L. del, E-mail: leire.del-campo@cnrs-orleans.f [Departamento de Fisica de la Materia Condensada, Facultad de Ciencia y Tecnologia, Universidad del Pais Vasco, Barrio Sarriena s/n, 48940 Leioa, Bizkaia (Spain); Perez-Saez, R.B., E-mail: raul.perez@ehu.e [Departamento de Fisica de la Materia Condensada, Facultad de Ciencia y Tecnologia, Universidad del Pais Vasco, Barrio Sarriena s/n, 48940 Leioa, Bizkaia (Spain); Instituto de Sintesis y Estudio de Materiales, Universidad del Pais Vasco, Apdo. 644, 48080 Bilbao (Spain); Gonzalez-Fernandez, L. [Departamento de Fisica de la Materia Condensada, Facultad de Ciencia y Tecnologia, Universidad del Pais Vasco, Barrio Sarriena s/n, 48940 Leioa, Bizkaia (Spain); Esquisabel, X.; Fernandez, I. [Industria de Turbo Propulsores, S.A., Planta de Zamudio, Edificio 300, 48170 Zamudio, Bizkaia (Spain); Gonzalez-Martin, P. [Industria de Turbo Propulsores, S.A., Parque empresarial San Fernando, Avda. Castilla 2, 28830 San Fernando de Henares, Madrid (Spain); Tello, M.J. [Departamento de Fisica de la Materia Condensada, Facultad de Ciencia y Tecnologia, Universidad del Pais Vasco, Barrio Sarriena s/n, 48940 Leioa, Bizkaia (Spain); Instituto de Sintesis y Estudio de Materiales, Universidad del Pais Vasco, Apdo. 644, 48080 Bilbao (Spain)

    2010-01-21

    The emissivity of three Ni and Co based aeronautical alloys is analyzed in this paper. These alloys are employed in high temperature environments whenever good corrosion resistance, high temperature resistance and high strength are essential. Thus, apart from the aeronautical industry, these alloys are also used in other technological applications, as for example, aerospace, nuclear reactors, and tooling. The results in this paper extend the emissivity data for these alloys available in the literature. Emissivity dependence on the radiation wavelength (2-22 {mu}m), sample temperature (200-650 {sup o}C) and emission angle (0-85{sup o}) has been investigated. In addition, the effect of surface finish and oxidation has also been taken into consideration. The data in this paper have several applications, as temperature measurement of a target by pyrometry, low observability of airplanes and thermal radiation heat transfer simulation in airplane nozzles or furnaces.

  6. Auger electron spectroscopy of alloys

    International Nuclear Information System (INIS)

    This thesis describes how the surface compositions of some alloys can be determined by Auger Electron Spectroscopy (AES). The motivation for this research and the reasons for the choice of alloy systems studied are formulated. The theoretical background of AES is briefly discussed and the apparatus used and the experimental procedures applied are described. Four alloy systems have been investigated in this thesis - Ni-Cu and Pd - Ag (consisting of a component active in most cataytic reactions - Ni and Pd; and a component which is almost inactive for a number of reactions - Cu and Ag) and Pt - Pd and Pt-Ir (consisting of two active components). Knowledge of the surface composition of the various alloy systems is shown to be essential for the interpretation of catalytic results. (Auth./C.F.)

  7. Laser welding of aluminium alloys

    OpenAIRE

    Forsman, Tomas

    2000-01-01

    This thesis treats laser welding of aluminium alloys from a practical perspective with elements of mathematical analysis. The theoretical work has in all cases been verified experimentally. The aluminium alloys studied are from the 5xxx and 6xxx groups which are common for example in the automotive industry. Aluminium has many unique physical properties. The properties which more than others have been shown to influence the welding process is its high reflection, high thermal conductivity, lo...

  8. Uranium-Based Cermet Alloys

    International Nuclear Information System (INIS)

    The paper describes certain features of dispersion-hardened uranium-based cermets. As possible hardening materials, consideration was given to UO2, UC, Al2O3, MgO and UBe13. Data were obtained on the behaviour of uranium alloys containing the above-mentioned admixtures during creep tests, short-term strength tests and cyclic thermal treatment. The corrosion resistance o f UBe13-based uranium alloys was also studied. )author)

  9. Friction surfacing of aluminium alloys

    OpenAIRE

    Pereira, Diogo Jorge O. A.

    2012-01-01

    Friction surfacing is a solid state joining process that has attracted much interest in the past decades. This technology allows joining dissimilar metallic materials while avoiding the brittle intermetallic formations, involving temperatures bellow melting point and producing like forged metal structures. Much research using different steels has been made but the same does not happen with aluminium alloys, specially using different aluminium alloys. Friction surface coatings using cons...

  10. TEM microstructure investigations of aluminium alloys used for laser alloying

    Directory of Open Access Journals (Sweden)

    K. Labisz

    2012-12-01

    Full Text Available Purpose: In this paper there are presented results of Transmission Electron Microscope investigation concerning the structure of the AlSi7Cu4 cast aluminium alloy using for alloying and remelting with the high power diode laser (HPDL. There are also presented the results of the thermo-derivative analysis performed using the UMSA (Universal Metallurgical Simulator and Analyser device, allowing to determine the specific points of the solidifying alloy, what is helpful for phase determination occurred in this alloy. In this work especially the changes of the precipitation type, size and shape were determined.Design/methodology/approach: The investigations were performed using electron microscopy for the microstructure and phases determination. By mind of the transmission electron microscopy, especially selected area diffraction method appliance it was possible to determine the phases occurred in the alloy in the as cast state. The morphology and size of the Mg2Si was also possible to determine as well the lattice parameters for this phase.Findings: : The reason of this work was also to present the laser treatment technology, which will be used for further alloying and remelting with ceramic powders – especially carbides and oxides. Particularly the overview will be directed on the laser power to achieve good layer hardness for protection of this hot work tool steel from losing their work stability and to make the tool surface more resistant to action in external conditions. The structure of the surface laser tray changes in a way, that there are very high roughness of the surface zone and the flatness or geometry changes in an important manner, crucial for further investigation.Research limitations/implications: The aluminium samples were examined metallographically using transmission electron microscope with different image techniques.Practical implications: Developing of new technology with appliance of Al alloys, High Power Diode Laser and

  11. Microstructural studies on Alloy 693

    Energy Technology Data Exchange (ETDEWEB)

    Halder, R.; Dutta, R.S. [Materials Science Division, Bhabha Atomic Research Centre, Mumbai 400 085 (India); Sengupta, P., E-mail: praneshsengupta@gmail.com [Materials Science Division, Bhabha Atomic Research Centre, Mumbai 400 085 (India); Samajdar, I. [Dept. of Metall. Engg. and Mater. Sci., Indian Institute of Technology Bombay, Mumbai 400 072 (India); Dey, G.K. [Materials Science Division, Bhabha Atomic Research Centre, Mumbai 400 085 (India)

    2014-10-15

    Superalloy 693, is a newly identified ‘high-temperature corrosion resistant alloy’. Present study focuses on microstructure and mechanical properties of the alloy prepared by double ‘vacuum melting’ route. In general, the alloy contains ordered Ni{sub 3}Al precipitates distributed within austenitic matrix. M{sub 6}C primary carbide, M{sub 23}C{sub 6} type secondary carbide and NbC particles are also found to be present. Heat treatment of the alloy at 1373 K for 30 min followed by water quenching (WQ) brings about a microstructure that is free from secondary carbides and Ni{sub 3}Al type precipitates but contains primary carbides. Tensile property of Alloy 693 materials was measured with as received and solution annealed (1323 K, 60 min, WQ) and (1373 K, 30 min, WQ) conditions. Yield strength, ultimate tensile strength (UTS) and hardness of the alloy are found to drop with annealing. It is noted that in annealed condition, considerable cold working of the alloy can be performed.

  12. The comparison of corrosion resistance between Baosteel's alloy 690 tube and foreign alloy 690 tube

    International Nuclear Information System (INIS)

    Alloy 690 having excellent corrosion resistance is widely used for SG tubes. The intergranular corrosion and pitting corrosion resistance of Baosteel's alloy 690 tube, Country A alloy 690 tube and Country B alloy 690 tube have been analysed by comparison. It shows that: The intergranular corrosion of Baosteel's alloy 690 tube tested complied with ASTM G28 Standard could satisfy the technical requirement. However.some of Baosteel's alloy 690 tube in intergranular corrosion resistance had less performance than Country A. In addition, pitting corrosion tested with ASTM G48 Standard shown the Baosteel's alloy 690 tube better than Country B. (authors)

  13. Laser cladding of titanium alloy coating on titanium aluminide alloy substrate

    Institute of Scientific and Technical Information of China (English)

    徐子文; 黄正; 阮中健

    2003-01-01

    A new diffusion bonding technique combined with laser cladding process was developed to join TiAl alloy to itself and Ti-alloys. In order to enhance the weldability of TiAl alloys, Ti-alloy coatings were fabricated by laser cladding on the TiAl alloy. Ti powder and shaped Ti-alloy were respectively used as laser cladding materials. The materials characterization was carried out by OM, SEM, EDS and XRD analysis. The results show that the laser cladding process with shaped Ti-alloy remedy the problems present in the conventional process with powder, such as impurities, cracks and pores. The diffusion bonding of TiAl alloy with Ti-alloy coating to itself and Ti-alloy was carried out with a Gleeble 1500 thermal simulator. The sound bonds of TiAl/TiAl, TiAl/Ti were obtained at a lower temperature and with shorter time.

  14. Compensative alloying of Cr-Si low-alloyed steels

    International Nuclear Information System (INIS)

    The principle of choosing alloy elements in order to suppress the embrittlement of solid solution strengthening is proposed. In the case of Cr-Si low-alloyed steels, the effects of compensative alloying are studied. The ultimate tensile strength and impact toughness of Cr-Si steels microalloyed with Mo, V, and Ti are determined to prove the aspects. The structure of these steels is studied using optical and transmission electron microscopy techniques after applying the optimum heat treatment. The kinetics of phase transformation after quenching and tempering have been examined by means of measurements of specific electrical resistance and magnetic parameters. It is shown that at the Si-content of about 1 wt% high values of tensile strength and impact toughness are simultaneously obtained. It is established by calculations that, for the indicated steel, long-range distortions of the crystal lattice become close to zero at the Si-content of about 1 wt%.

  15. Machining of high alloy steels and heat resistant alloys

    International Nuclear Information System (INIS)

    The peculiarities of machining high alloy steels and heat resistant alloys on the base of nickel by cutting are described. The factors worsening the machining of heat resistant materials, namely, the low heat conductivity, strong reverting and high wearing capability, are pointed out. The resign and materials of cutting instruments, providing for high quality machining of heat resistant steels and alloys, are considered. The necessity of regulating thermal processes during cutting with cutting fluids and other coolants (e.g. air with a negative temperature) is noted. The recommended modes of cutting are presented. The efficiency of the conveyer-type method for sawing products and forged intermediate articles is demonstrated by the example of 5KhNM steel

  16. Corrosion Behaviour of New Zr Alloys

    DEFF Research Database (Denmark)

    Tolksdorf, E.

    1974-01-01

    Corrosion studies have indicated that the most promising replacements for Zicaloy-2 are ZrCrFe, ZrVFe and probably ZrNbTa, provided they are in their optimized condition. These alloys are conventionally manufactured alloys. An internally oxidized ZrMgO alloy is even superior, from the corrosion...

  17. Moving Dislocations in Disordered Alloys.

    Energy Technology Data Exchange (ETDEWEB)

    Marian, J; Caro, A

    2006-11-18

    Using atomistic simulations of dislocation motion in Ni and Ni-Au alloys we report a detailed study of the mobility function as a function of stress, temperature and alloy composition. We analyze the results in terms of analytic models of phonon radiation and their selection rules for phonon excitation. We find a remarkable agreement between the location of the cusps in the {sigma}-v relation and the velocity of waves propagating in the direction of dislocation motion. We identify and characterize three regimes of dissipation whose boundaries are essentially determined by the direction of motion of the dislocation, rather than by its screw or edge character.

  18. [Microbiological corrosion of aluminum alloys].

    Science.gov (United States)

    Smirnov, V F; Belov, D V; Sokolova, T N; Kuzina, O V; Kartashov, V R

    2008-01-01

    Biological corrosion of ADO quality aluminum and aluminum-based construction materials (alloys V65, D16, and D16T) was studied. Thirteen microscopic fungus species and six bacterial species proved to be able to attack aluminum and its alloys. It was found that biocorrosion of metals by microscopic fungi and bacteria was mediated by certain exometabolites. Experiments on biocorrosion of the materials by the microscopic fungus Alternaria alternata, the most active biodegrader, demonstrated that the micromycete attack started with the appearance of exudate with pH 8-9 on end faces of the samples. PMID:18669265

  19. Alloy 718 for Oilfield Applications

    Science.gov (United States)

    deBarbadillo, John J.; Mannan, Sarwan K.

    2012-02-01

    Alloy 718 (UNS N07718) was developed for use in aircraft gas turbine engines, but its unique combination of room-temperature strength and aqueous corrosion resistance made it a candidate for oilfield fasteners, valves, drill tools, and completion equipment. As well environments became more severe, stress corrosion and hydrogen embrittlement failures in production equipment drove the evolution of the composition and microstructure that distinguish today's oilfield-grade 718 from aerospace grades. This paper reviews the development of the grade and its applications and describes some of its unique characteristics, testing, and manufacturing methods as well as newer alloys designed for high-pressure high-temperature (HPHT) conditions.

  20. Hydrogen effects in aluminum alloys

    International Nuclear Information System (INIS)

    The permeability of six commercial aluminum alloys to deuterium and tritium was determined by several techniques. Surface films inhibited permeation under most conditions; however, contact with lithium deuteride during the tests minimized the surface effects. Under these conditions phi/sub D2/ = 1.9 x 10-2 exp (--22,400/RT) cc (NTP)atm/sup --1/2/ s-1cm-1. The six alloys were also tested before, during, and after exposure to high pressure hydrogen, and no hydrogen-induced effects on the tensile properties were observed

  1. Current research situation of titanium alloys in China

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    Titanium and its alloys possess excellent comprehensive properties, and they are widely used in many fields. China pays great attentions to the research on new titanium alloys. This paper mainly reviews the research on new Ti alloys in China, for example, high strength and high toughness Ti alloys, burn resistant Tialloys, high temperature Ti alloys, low cost Ti alloys and so on.New basic theories on Ti alloys developed in China in recent years are also reviewed.

  2. Imparting passivity to vapor deposited magnesium alloys

    Science.gov (United States)

    Wolfe, Ryan C.

    Magnesium has the lowest density of all structural metals. Utilization of low density materials is advantageous from a design standpoint, because lower weight translates into improved performance of engineered products (i.e., notebook computers are more portable, vehicles achieve better gas mileage, and aircraft can carry more payload). Despite their low density and high strength to weight ratio, however, the widespread implementation of magnesium alloys is currently hindered by their relatively poor corrosion resistance. The objective of this research dissertation is to develop a scientific basis for the creation of a corrosion resistant magnesium alloy. The corrosion resistance of magnesium alloys is affected by several interrelated factors. Among these are alloying, microstructure, impurities, galvanic corrosion effects, and service conditions, among others. Alloying and modification of the microstructure are primary approaches to controlling corrosion. Furthermore, nonequilibrium alloying of magnesium via physical vapor deposition allows for the formation of single-phase magnesium alloys with supersaturated concentrations of passivity-enhancing elements. The microstructure and surface morphology is also modifiable during physical vapor deposition through the variation of evaporation power, pressure, temperature, ion bombardment, and the source-to-substrate distance. Aluminum, titanium, yttrium, and zirconium were initially chosen as candidates likely to impart passivity on vapor deposited magnesium alloys. Prior to this research, alloys of this type have never before been produced, much less studied. All of these metals were observed to afford some degree of corrosion resistance to magnesium. Due to the especially promising results from nonequilibrium alloying of magnesium with yttrium and titanium, the ternary magnesium-yttrium-titanium system was investigated in depth. While all of the alloys are lustrous, surface morphology is observed under the scanning

  3. An introduction to surface alloying of metals

    CERN Document Server

    Hosmani, Santosh S; Goyal, Rajendra Kumar

    2014-01-01

    An Introduction to Surface Alloying of Metals aims to serve as a primer to the basic aspects of surface alloying of metals. The book serves to elucidate fundamentals of surface modification and their engineering applications. The book starts with basics of surface alloying and goes on to cover key surface alloying methods, such as carburizing, nitriding, chromizing, duplex treatment, and the characterization of surface layers. The book will prove useful to students at both the undergraduate and graduate levels, as also to researchers and practitioners looking for a quick introduction to surface alloying.

  4. Surface Tension Calculation of Undercooled Alloys

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    Based on the Butler equation and extrapolated thermodynamic data of undercooled alloys from those of liquid stable alloys, a method for surface tension calculation of undercooled alloys is proposed. The surface tensions of liquid stable and undercooled Ni-Cu (xNi=0.42) and Ni-Fe (xNi=0.3 and 0.7) alloys are calculated using STCBE (Surface Tension Calculation based on Butler Equation) program. The agreement between calculated values and experimental data is good enough, and the temperature dependence of the surface tension can be reasonable down to 150-200 K under the liquid temperature of the alloys.

  5. Corrosion behavior of Alloy 690 and Alloy 693 in simulated nuclear high level waste medium

    Energy Technology Data Exchange (ETDEWEB)

    Samantaroy, Pradeep Kumar; Suresh, Girija; Paul, Ranita [Corrosion Science and Technology Group, Indira Gandhi Centre for Atomic Research, Kalpakkam 603 102 (India); Kamachi Mudali, U., E-mail: kamachi@igcar.gov.in [Corrosion Science and Technology Group, Indira Gandhi Centre for Atomic Research, Kalpakkam 603 102 (India); Raj, Baldev [Corrosion Science and Technology Group, Indira Gandhi Centre for Atomic Research, Kalpakkam 603 102 (India)

    2011-11-15

    Highlights: > Alloy 690 and Alloy 693, both possess good corrosion resistance in simulated HLW. > SEM and EDS confirms the presence of Cr rich precipitates for both the alloys. > Passive film stability of Alloy 690 was found to be higher than Alloy 693. > Both alloys possess few micro pits even at a concentration of 100 ppm Cl{sup -} ion. - Abstract: Nickel based alloys are candidate materials for the storage of high level waste (HLW) generated from reprocessing of spent nuclear fuel. In the present investigation Alloy 690 and Alloy 693 are assessed by potentiodynamic anodic polarization technique for their corrosion behavior in 3 M HNO{sub 3}, 3 M HNO{sub 3} containing simulated HLW and in chloride medium. Both the alloys were found to possess good corrosion resistance in both the media at ambient condition. Microstructural examination was carried out by SEM for both the alloys after electrolytic etching. Compositional analysis of the passive film formed on the alloys in 3 M HNO{sub 3} and 3 M HNO{sub 3} with HLW was carried out by XPS. The surface of Alloy 690 and Alloy 693, both consists of a thin layer of oxide of Ni, Cr, and Fe under passivation in both the media. The results of investigation are presented in the paper.

  6. High Damping Alloys and Their Application

    Institute of Scientific and Technical Information of China (English)

    Fuxing Yin

    2000-01-01

    Damping alloys show prospective applications in the elimination of unwanted vibrations and acoustic noise. The basic definitions and characterization methods of damping capacity are reviewed in this paper. Several physical mechanisms controlled by the alloy microstructure are responsible for the damping behavior in the damping alloys. Composite, dislocation, ferromagnetic and planar defect types are commonly classified for the alloys, which show the different damping behavior against temperature, frequency of vibration,amplitude of vibration and damping modes. Development of practically applicable damping alloys requires the higher mechanical properties and adequate workability, besides the high damping capacity. A new Mn-Cu damping alloy, named as M2052 alloy, is recently developed with possible industrial applications.

  7. Applications of shape memory alloys in Japan

    Energy Technology Data Exchange (ETDEWEB)

    Asai, M.; Suzuki, Y. [Furukawa Electric Co., Ltd., Yokohama, Kanagawa (Japan). R and D Labs.

    2000-07-01

    In Japan, a first application of shape memory TiNi alloy was a moving flap in an air-conditioner which was developed as sensing function of shape memory alloy at Matsushista Electric Industrial Co. Then, shape memory utilized in a coffee maker, an electric rice-cooker, a thermal mixing valve and etc. were commercialized in Japan. And brassiere wires, a guide wire for medical treatment, an antenna for portable telephone and others were commercialized utilizing superelasticity. At the same time with these commercial products, there was not only progress in fabrication technology to effect accurate transformation temperature, but also the discovery of small hysteresis alloy such as R-phase or TiNiCu alloy and low transformation temperature alloy such as TiNiFe, TiNiV and TiNiCo alloys. Therefore the shape memory alloy market has expanded widely to electric appliances, automobile, residence, medical care and otherfield today. (orig.)

  8. Gold color in dental alloys.

    Science.gov (United States)

    Cameron, T

    1997-01-01

    This article will help the dental laboratory with alloy selection by exploring how the relationship among color, ductility and strength applies to gold and how color can be quantified. Because higher quality materials translate into higher profits, upselling to the dentist and patient is also discussed.

  9. Hydrostatic extrusion of magnesium alloys

    NARCIS (Netherlands)

    Sillekens, W.H.; Bohlen, J.

    2012-01-01

    This chapter deals with the capabilities and limitations of the hydrostatic extrusion process for the manufacturing of magnesium alloy sections. Firstly, the process basics for the hydrostatic extrusion of materials in general and of magnesium in particular are introduced. Next, some recent research

  10. Introduction to hydrogen in alloys

    International Nuclear Information System (INIS)

    Substitutional alloys, both those that form hydrides and those that do not, are discussed, but with more emphasis on the former than the latter. This overview includes the following closely related subjects: (1) the significant effects of substitutional solutes on the pressure-composition-temperature (PCT) equilibria of metal-hydrogen systems, (2) the changes in thermodynamic properties resulting from differences in atom size and from modifications of electronic structure, (3) attractive and repulsive interactions between H and solute atoms and the effects of such interactions on the pressure dependent solubility for H, (4) H trapping in alloys of Group V metals and its effect on the terminal solubility for H (TSH), (5) some other mechanisms invoked to explain the enhancement (due to alloying) of the (TSH) in Group V metals, and (6) H-impurity complexes in alloys of the metals Ni, Co, and Fe. Some results showing that an enhanced TSH may ameliorate the resistance of a metal to hydrogen embrittlement are presented

  11. Fiber reinforced titanium alloy composites

    International Nuclear Information System (INIS)

    The more important titanium matrix composites studied to date are composed of titanium alloy matrices, such as Ti 6Al--4V, reinforced with filaments of boron, silicon carbide, or sapphire, as well as with wires of beryllium or refractory metal alloys. The primary fabrication techniques for these materials involve vacuum hot pressing at 1300 to 16000F, alternate layers of titanium alloy matrix foils, and suitably aligned filament mats. The more ductile reinforcements such as beryllium, have been incorporated into titanium matrix composites by coextrusion. Fabrication of composite gas turbine engine fan blades from both boron (SiC coated) and beryllium reinforced Ti 6Al--4V alloy is described. Feasibility studies have been made in the fabrication of Boron/Ti 6Al--4V composite rings for possible gas turbine engine disc applications. Mechanical properties of various titanium matrix composite systems are presented and demonstrate the attractive elevated temperature properties of some systems to 10000F. (35 fig, 6 tables) (U.S.)

  12. Microstructure and thermal stability of mechanically alloyed Al3Ti/Al alloy

    Institute of Scientific and Technical Information of China (English)

    林建国; 魏浩岩; 黄正

    2001-01-01

    The microstructure stability of Al3Ti/Al alloy prepared by mechanical alloying (MA) was investigated in the simulating environment in which they may be used. The results show that the MA alloy possesses fine microstructure (the grain size is about 0.5  μm). After cycling loaded followed by heat exposure at 350  ℃ for 24  h, no microstructure coarsening of the alloy occurred, which means that the Al3Ti/Al alloy behaves good microstructure stability at high temperature. The compression yield strength of the alloy reaches up to 247  MPa at 350  ℃.

  13. PERSPECTIVES OF MOLIBDENUM CONTAINING MATERIALS APPLICATION FOR ALLOYING OF IRONCARBON ALLOYS DURING MANUFACTURING OF CRITICAL CASTINGS

    Directory of Open Access Journals (Sweden)

    A. G. Slutsky

    2015-01-01

    Full Text Available Motor is one of most important part of automobile determine its economical effectiveness of usage. On the other hand, sleeves, pistons and rings are crucible parts as they determine the service life of a motor. These parts are producing in big scale – dozens of millions pieces. Increase of cylinder sleeves physical-mechanical properties results in prolongation of motor service life and improvement of motor’s characteristics. Nowadays low alloyed cast irons with perlite structure are used to manufacture motor’s sleeves. For alloying purposes such traditional elements as Cr, Ni, Cu, and V are applied. But it is interesting to use molybdenum for cast iron alloying. It is known that alloying of alloys allows considerable increasing of consumption properties of castings. But in spite of advantages of alloys alloying the increase of molybdenum containing iron-carbon alloys production is restricted by economical reasons – high cost of alloying additions. Expenditures on alloying additions can be reduced by the application cheap secondary alloys in the charge. So, the present paper is devoted to investigation of alloying peculiarities during the treatment of ferrous alloys with molybdenum applying different initial materials.

  14. Method of producing superplastic alloys and superplastic alloys produced by the method

    Science.gov (United States)

    Troeger, Lillianne P. (Inventor); Starke, Jr., Edgar A. (Inventor); Crooks, Roy (Inventor)

    2002-01-01

    A method for producing new superplastic alloys by inducing in an alloy the formation of precipitates having a sufficient size and homogeneous distribution that a sufficiently refined grain structure to produce superplasticity is obtained after subsequent PSN processing. An age-hardenable alloy having at least one dispersoid phase is selected for processing. The alloy is solution heat-treated and cooled to form a supersaturated solid solution. The alloy is plastically deformed sufficiently to form a high-energy defect structure useful for the subsequent heterogeneous nucleation of precipitates. The alloy is then aged, preferably by a multi-stage low and high temperature process, and precipitates are formed at the defect sites. The alloy then is subjected to a PSN process comprising plastically deforming the alloy to provide sufficient strain energy in the alloy to ensure recrystallization, and statically recrystallizing the alloy. A grain structure exhibiting new, fine, equiaxed and uniform grains is produced in the alloy. An exemplary 6xxx alloy of the type capable of being produced by the present invention, and which is useful for aerospace, automotive and other applications, is disclosed and claimed. The process is also suitable for processing any age-hardenable aluminum or other alloy.

  15. Nickel-base alloys combat corrosion

    Energy Technology Data Exchange (ETDEWEB)

    Agarwal, D.C. [VDM Technologies Corp., Houston, TX (United States); Herda, W. [Krupp-VDM GmbH, Werdohl (Germany)

    1995-06-01

    The modern chemical process industry must increase production efficiency to remain competitive. Manufacturers typically meet this challenge by utilizing higher temperatures and pressures, and more-corrosive catalysts. At the same time, the industry has to solve the technical and commercial problems resulting from rigid environmental regulations. To overcome these obstacles, new alloys having higher levels of corrosion resistance have been developed. These materials are based on increased understanding of the physical metallurgy of nickel-base alloys, especially the role of alloying elements. Results of many studies have led to innovations in nickel-chromium-molybdenum alloys containing both high and low amounts of nickel. Higher molybdenum and chromium contents, together with nitrogen additions, have opened up an entirely new class of alloys having unique properties. In addition, a new chromium-base, fully wrought super stainless steel shows excellent promise in solving many corrosion problems. These newer alloys have the ability to combat uniform corrosion, localized corrosion, and stress-corrosion cracking in the harsh halogenic environment of the chemical process industry. This article briefly lists some of the major highlights and corrosion data on recent nickel-chromium-molybdenum and nickel-molybdenum alloys, and the development of a chromium-base, wrought super-austenitic alloy known as Nicrofer 3033 (Alloy 33). Some comparisons with existing alloys are presented, along with a few commercial applications.

  16. Alloy substantially free of dendrites and method of forming the same

    Science.gov (United States)

    de Figueredo, Anacleto M.; Apelian, Diran; Findon, Matt M.; Saddock, Nicholas

    2009-04-07

    Described herein are alloys substantially free of dendrites. A method includes forming an alloy substantially free of dendrites. A superheated alloy is cooled to form a nucleated alloy. The temperature of the nucleated alloy is controlled to prevent the nuclei from melting. The nucleated alloy is mixed to distribute the nuclei throughout the alloy. The nucleated alloy is cooled with nuclei distributed throughout.

  17. Preparation of TiMn alloy by mechanical alloying and spark plasma sintering for biomedical applications

    Science.gov (United States)

    Zhang, F.; Weidmann, A.; Nebe, B. J.; Burkel, E.

    2009-01-01

    TiMn alloy was prepared by mechanical alloying and subsequently consolidated by spark plasma sintering (SPS) technique for exploration of biomedical applications. The microstructures, mechanical properties and cytotoxicity of the TiMn alloys were investigated in comparison with the pure Ti and Mn metals. Ti8Mn and Ti12Mn alloys with high relative density (99%) were prepared by mechanical alloying for 60 h and SPS at 700 °C for 5 min. The doping of Mn in Ti has decreased the transformation temperature from α to β phase, increased the relative density and enhanced the hardness of the Ti metal significantly. The Ti8Mn alloys showed 86% cell viability which was comparable to that of the pure Ti (93%). The Mn can be used as a good alloying element for biomedical Ti metal, and the Ti8Mn alloy could have a potential use as bone substitutes and dental implants.

  18. Status of Testing and Characterization of CMS Alloy 617 and Alloy 230

    Energy Technology Data Exchange (ETDEWEB)

    Ren, Weiju [ORNL; Santella, Michael L [ORNL; Battiste, Rick [ORNL; Terry, Totemeier [Idaho National Laboratory (INL); Denis, Clark [Idaho National Laboratory (INL)

    2006-08-01

    Status and progress in testing and characterizing CMS Alloy 617 and Alloy 230 tasks in FY06 at ORNL and INL are described. ORNL research has focused on CMS Alloy 617 development and creep and tensile properties of both alloys. In addition to refurbishing facilities to conduct tests, a significant amount of creep and tensile data on Alloy 230, worth several years of research funds and time, has been located and collected from private enterprise. INL research has focused on the creep-fatigue behavior of standard chemistry Alloy 617 base metal and fusion weldments. Creep-fatigue tests have been performed in air, vacuum, and purified Ar environments at 800 and 1000 C. Initial characterization and high-temperature joining work has also been performed on Alloy 230 and CCA Alloy 617 in preparation for creep-fatigue testing.

  19. New Dental Alloys with Special Consumer Properties

    Institute of Scientific and Technical Information of China (English)

    TYKOCHINSKIY D. S.; VASEKIN V. V.

    2012-01-01

    The purpose of the investigation was to create a new gold alloy of yellow for casting the frames of metal-ceramic dentures.The yellow color corresponds to the consumer and aesthetic needs of some patients,because it is a sign of the metal,which is noble and innocuous.The main alloying elements of the majority of gold alloys for metal-ceramics are platinum and palladium,which increase the strength characteristics.Copper,tin,and other precious metals and base metals are also introduced in these alloys.At the same time,it is necessary to ensure the correspondence of the properties of the alloy with those of the ceramics applied onto the metal frame.For this purpose,the thermal expansion coefficient of the alloy (TEC) should be in a range of 13.5~14.5 × 10-6 K-1 when heated from 20 to 600 ℃.The two-component alloys,alloying of gold with platinum and palladium results in a decrease in the TEC,and the introduction of copper,silver,and tin,increases it.Multidirectional influence of the alloying elements is a factor in achieving compliance of the TEC with the given values of the alloy.In multicomponent systems,however,the mutual influence of individual components on the properties of the alloy is unpredictable.This also applies to the color characteristics of the alloys,which vary in the direction of reducing the yellowness with increasing concentration of platinum and palladium,while other elements may have the opposite effect on the results.Yellowness index (YI),calculated according to the results of spectrophotometric studies,has been chosen as an objective indicator of color.In this study,the requirement for YI was given not less than 25; the color of such alloys can be called light yellow.All the alloys investigated contained 85% (by weight)of gold.Therefore,higher corrosion resistance and biological inertness of a finished dental products were ensured.Among the alloys that met the yellowness/TEC requirements,two alloys have been selected that were "most yellow

  20. First principles theory of disordered alloys and alloy phase stability

    Energy Technology Data Exchange (ETDEWEB)

    Stocks, G.M.; Nicholson, D.M.C.; Shelton, W.A. [and others

    1993-06-05

    These lecture notes review the LDA-KKR-CPA method for treating the electronic structure and energetics of random alloys and the MF-CF and GPM theories of ordering and phase stability built on the LDA- KKR-CPA description of the disordered phase. Section 2 lays out the basic LDA-KKR-CPA theory of random alloys and some applications. Section 3 reviews the progress made in understanding specific ordering phenomena in binary solid solutions base on the MF-CF and GPM theories of ordering and phase stability. Examples are Fermi surface nesting, band filling, off diagonal randomness, charge transfer, size difference or local strain fluctuations, magnetic effects; in each case, an attempt is made to link the ordering and the underlying electronic structure of the disordered phase. Section 4 reviews calculations of electronic structure of {beta}-phase Ni{sub c}Al{sub 1-c} alloys using a version of the LDA-KKR-CPA codes generalized to complex lattices.

  1. Effects of segregation of primary alloying elements on the creep response in magnesium alloys

    DEFF Research Database (Denmark)

    Huang, Y.D.; Dieringa, H.; Hort, N.;

    2008-01-01

    The segregation of primary alloying elements deteriorates the high temperature creep resistance of magnesium alloys. Annealing at high temperatures alleviating their segregations can improve the creep resistance. Present investigation on the effect of segregation of primary alloying elements...... on the creep response may provide some useful information about how to improve the creep resistance of magnesium alloys in the future. (c) 2008 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved....

  2. Copper and nickel adherently electroplated on titanium alloy

    Science.gov (United States)

    Brown, E. E.

    1967-01-01

    Anodic treatment of titanium alloy enables electroplating of tightly adherent coatings of copper and nickel on the alloy. The alloy is treated in a solution of hydrofluoric and acetic acids, followed by the electroplating process.

  3. Constitution and magnetism of iron and its alloys

    International Nuclear Information System (INIS)

    The following topics are covered: structure of iron, magnetism of iron, thermal properties (heat capacity and enthalpy), substitutional alloys of iron, interstitial Fe alloys and compounds, influence of magnetism on the physical properties of Fe alloys (WL)

  4. Bonding theory for metals and alloys

    CERN Document Server

    Wang, Frederick E

    2005-01-01

    Bonding Theory for Metals and Alloys exhorts the potential existence of covalent bonding in metals and alloys. Through the recognition of the covalent bond in coexistence with the 'free' electron band, the book describes and demonstrates how the many experimental observations on metals and alloys can all be reconciled. Subsequently, it shows how the individual view of metals and alloys by physicists, chemists and metallurgists can be unified. The physical phenomena of metals and alloys covered in this book are: Miscibility Gap between two liquid metals; Phase Equilibrium Diagrams; Phenomenon of Melting. Superconductivity; Nitinol; A Metal-Alloy with Memory; Mechanical Properties; Liquid Metal Embrittlement; Superplasticity; Corrosion; The author introduces a new theory based on 'Covalon' conduction, which forms the basis for a new approach to the theory of superconductivity. This new approach not only explains the many observations made on the phenomenon of superconductivity but also makes predictions that ha...

  5. Theory of Random Anisotropic Magnetic Alloys

    DEFF Research Database (Denmark)

    Lindgård, Per-Anker

    1976-01-01

    A mean-field-crystal-field theory is developed for random, multicomponent, anisotropic magnetic alloys. It is specially applicable to rare-earth alloys. A discussion is given of multicritical points and phase transitions between various states characterized by order parameters with different...... spatial directions or different ordering wave vectors. Theoretical predictions based on known parameters for the phase diagrams and magnetic moments for the binary rare-earth alloys of Tb, Dy, Ho, and Er, Tb-Tm, Nd-Pr, and pure double-hcp Nd agree qualitatively with the experimental observations....... Quantitative agreement can be obtained by increasing the interaction between different alloy elements, in particular for alloys with very different axial anisotropy, e.g., Tb-Tm. A model system consisting of a singlet-singlet and singlet-doublet alloy is discussed in detail. A simple procedure to include...

  6. A lightweight shape-memory magnesium alloy

    Science.gov (United States)

    Ogawa, Yukiko; Ando, Daisuke; Sutou, Yuji; Koike, Junichi

    2016-07-01

    Shape-memory alloys (SMAs), which display shape recovery upon heating, as well as superelasticity, offer many technological advantages in various applications. Those distinctive behaviors have been observed in many polycrystalline alloy systems such as nickel titantium (TiNi)–, copper-, iron-, nickel-, cobalt-, and Ti-based alloys but not in lightweight alloys such as magnesium (Mg) and aluminum alloys. Here we present a Mg SMA showing superelasticity of 4.4% at –150°C and shape recovery upon heating. The shape-memory properties are caused by reversible martensitic transformation. This Mg alloy includes lightweight scandium, and its density is about 2 grams per cubic centimeter, which is one-third less than that of practical TiNi SMAs. This finding raises the potential for development and application of lightweight SMAs across a number of industries.

  7. A lightweight shape-memory magnesium alloy.

    Science.gov (United States)

    Ogawa, Yukiko; Ando, Daisuke; Sutou, Yuji; Koike, Junichi

    2016-07-22

    Shape-memory alloys (SMAs), which display shape recovery upon heating, as well as superelasticity, offer many technological advantages in various applications. Those distinctive behaviors have been observed in many polycrystalline alloy systems such as nickel titantium (TiNi)-, copper-, iron-, nickel-, cobalt-, and Ti-based alloys but not in lightweight alloys such as magnesium (Mg) and aluminum alloys. Here we present a Mg SMA showing superelasticity of 4.4% at -150°C and shape recovery upon heating. The shape-memory properties are caused by reversible martensitic transformation. This Mg alloy includes lightweight scandium, and its density is about 2 grams per cubic centimeter, which is one-third less than that of practical TiNi SMAs. This finding raises the potential for development and application of lightweight SMAs across a number of industries. PMID:27463668

  8. Biocorrosion study of titanium-nickel alloys.

    Science.gov (United States)

    Chern Lin, J H; Lo, S J; Ju, C P

    1996-02-01

    The present study provides results of the corrosion behaviour in Hank's physiological solution and some other properties of three Ti-Ni alloys with 18, 25 and 28.4 wt% Ni, respectively. Results indicate that alpha-titanium and Ti2Ni were the two major phases in all three Ti-Ni alloys. The relative amount of the Ti2Ni phase increased with additional Ni content. Hardness of the Ti-Ni alloys also increased with added nickel content, ranging from 310 to 390 VHN, similar to the hardness of enamel. Melting temperatures of the Ti-Ni alloys were all lower than that of pure titanium by least 600 degrees C. The three Ti-Ni alloys behaved almost identically when potentiodynamically polarized in Hank's solution at 37 degrees C. The critical anodic current densities of the alloys were nearly 30 microA/cm2 and the breakdown potentials were all above 1100 mV (SCE).

  9. Corrosion resistance of titanium alloys for dentistry

    International Nuclear Information System (INIS)

    Titanium and its alloys belong to biomaterials which the application scope in medicine increases. Some properties of the alloys, such as high mechanical strength, low density, low Young's modulus, high corrosion resistance and good biotolerance decide about it. The main areas of the application of titanium and its alloys are: orthopedics and traumatology, cardiosurgery, faciomaxillary surgery and dentistry. The results of investigations concerning the corrosion resistance of the technical titanium and Ti6Al14V alloy and comparatively a cobalt alloy of the Vitallium type in the artificial saliva is presented in the work. Significantly better corrosion resistance of titanium and the Ti6Al14V than the Co-Cr-Mo alloy was found. (author)

  10. [Microbial corrosion of dental alloy].

    Science.gov (United States)

    Li, Lele; Liu, Li

    2004-10-01

    There is a very complicated electrolytical environment in oral cavity with plenty of microorganisms existing there. Various forms of corrosion would develop when metallic prosthesis functions in mouth. One important corrosive form is microbial corrosion. The metabolic products, including organic acid and inorganic acid, will affect the pH of the surface or interface of metallic prosthesis and make a change in composition of the medium, thus influencing the electron-chemical reaction and promoting the development of corrosion. The problem of develpoment of microbial corrosion on dental alloy in the oral environment lies in the primary condition that the bacteria adhere to the surface of alloy and form a relatively independent environment that promotes corrosion. PMID:15553877

  11. Microstructure and Slip Character in Titanium Alloys

    OpenAIRE

    Banerjee, D.; Williams, J. C.

    1986-01-01

    Influence of microstructures in titanium alloys on the basic parameters of deformation behaviour such as slip character, slip length and slip intensity have been explored. Commercial titanium alloys contain the hexagonal close packed (alpha) and body centred cubic (bita) phases. Slip in these individual phases is shown to be dependent on the nature of alloying elements through their effect on phase stability as related to decomposition into ordered or w structures. When alpha and bita coexist...

  12. Advanced powder metallurgy aluminum alloys and composites

    Science.gov (United States)

    Lisagor, W. B.; Stein, B. A.

    1982-01-01

    The differences between powder and ingot metallurgy processing of aluminum alloys are outlined. The potential payoff in the use of advanced powder metallurgy (PM) aluminum alloys in future transport aircraft is indicated. The national program to bring this technology to commercial fruition and the NASA Langley Research Center role in this program are briefly outlined. Some initial results of research in 2000-series PM alloys and composites that highlight the property improvements possible are given.

  13. Dissimilar Welding of Titanium Alloys to Steels

    OpenAIRE

    Gao, Yefei; TSUMURA, Takuya; NAKATA, Kazuhiro

    2012-01-01

    This review summarizes the dissimilar welding of titanium alloys to steels over a period of ten recent years, involving the welding processes which are used for the dissimilar welding of titanium alloys to steels, the mechanical properties of the joints and the discussion for the forming mechanism of the interface. Reducing the formation of brittle intermetallic compound (IMC) is a key requirement in the dissimilar welding of titanium alloys to steels, because the strength of the welding join...

  14. Metal Dusting of Heat-Resistant Alloys

    OpenAIRE

    Al-Meshari, Abdulaziz I.

    2008-01-01

    Metal dusting leads to disintegration of such alloys as iron and nickel-based into a ?dust? of particulate metal, metal carbide, carbon, and/or oxide. It occurs in strongly carburising environments at 400-900?C. Literature survey has shown that alloys behave differently in metal dusting conditions based on their composition and the environment. Metal dusting mechanisms for iron and nickel-based alloys have been proposed but, nevertheless, have not been agreed upon and numerous modifications t...

  15. New aluminium alloys with high lithium content

    Energy Technology Data Exchange (ETDEWEB)

    Schemme, K.; Velten, B.

    1989-06-01

    Since the early 80's there have been made great efforts to replace the high strength aluminium alloys for the aircraft and space industry by a new generation of aluminium-lithium alloys. The attractivity of this kind of alloys could be increased by a further reduction of their density, caused by an increasing lithium content (/ge/ 5 wt.% Li). Therefore binary high-lithium containing alloys with low density are produced and metallografically investigated. A survey of their strength and wear behavior is given by using tensile tests and pin abrasing tests. (orig.).

  16. Characterization of a NIMONIC TYPE super alloy

    International Nuclear Information System (INIS)

    Mechanical properties of strength and thermofluence of a NIMONIC type super alloy under thermal treatment was determined. The relationship between microstructure, phases and precipitates was also studied. (author)

  17. Casting Characteristics of Aluminum Die Casting Alloys

    Energy Technology Data Exchange (ETDEWEB)

    Makhlouf M. Makhlouf; Diran Apelian

    2002-02-05

    The research program investigates the casting characteristics of selected aluminum die casting alloys. Specifically, the alloys' tendencies towards die soldering and sludge formation, and the alloys' fluidity and machinability are evaluated. It was found that: When the Fe and Mn contents of the alloy are low; caution has to be taken against possible die soldering. When the alloy has a high sludge factor, particularly a high level of Fe, measures must be taken to prevent the formation of large hardspots. For this kind of alloy, the Fe content should be kept at its lowest allowable level and the Mn content should be at its highest possible level. If there are problems in die filling, measures other than changing the alloy chemistry need to be considered first. In terms of alloy chemistry, the elements that form high temperature compounds must be kept at their lowest allowable levels. The alloys should not have machining problems when appropriate machining techniques and machining parameters are used.

  18. Titanium alloys Russian aircraft and aerospace applications

    CERN Document Server

    Moiseyev, Valentin N

    2005-01-01

    This text offers previously elusive information on state-of-the-art Russian metallurgic technology of titanium alloys. It details their physical, mechanical, and technological properties, as well as treatments and applications in various branches of modern industry, particularly aircraft and aerospace construction. Titanium Alloys: Russian Aircraft and Aerospace Applications addresses all facets of titanium alloys in aerospace and aviation technology, including specific applications, fundamentals, composition, and properties of commercial alloys. It is useful for all students and researchers interested in the investigation and applications of titanium.

  19. Nanodispersed boriding of titanium alloy

    International Nuclear Information System (INIS)

    The problem of improving the operational reliability of machines is becoming increasingly important due to the increased mechanical, thermal and other loads on the details. There are many surface hardening methods for machines parts which breakdown begins with surface corruption. The most promising methods are chemical-thermal treatment. The aim of this work is to study the impact of boriding on the structure and properties of titanium alloy. Materials and Methods: The material of this study is VT3-1 titanium alloy. The boriding were conducted using nanodispersed powder blend based on boric substances. It is established that boriding of paste compounds allows obtaining the surface hardness within 30 - 29 GPa and with declining to 27- 26 GPa in layer to the transition zone (with total thickness up to 110 μm) owing to changes of the layer phase composition where T2B, TiB, TiB2 titanium borides are formed. The increasing of chemical-thermal treatment time from 15 minutes to 2 hours leads to thickening of the borated layer (30 - 110 μm) and transition zone (30 - 190 μm). Due to usage of nanodispersed boric powder, the boriding duration is decreasing in 2 - 3 times. This allows saving time and electric energy. The developed optimal mode of boriding the VT3-1 titanium alloy allows obtaining the required operational characteristics and to combine the saturation of the surface layer with atomic boron and hardening

  20. Nanodispersed boriding of titanium alloy

    Directory of Open Access Journals (Sweden)

    Kateryna O. Kostyk

    2015-12-01

    Full Text Available The problem of improving the operational reliability of machines is becoming increasingly important due to the increased mechanical, thermal and other loads on the details. There are many surface hardening methods for machines parts which breakdown begins with surface corruption. The most promising methods are chemo-thermal treatment. Aim: The aim of this work is to study the impact of boriding on the structure and properties of titanium alloy. Materials and Methods: The material of this study is VT3-1 titanium alloy. The boriding were conducted using nanodispersed powder blend based on boric substances. Results: It is established that boriding of paste compounds allows obtaining the surface hardness within 30...29 GPa and with declining to 27...26 GPa in layer to the transition zone (with total thickness up to 110 μm owing to changes of the layer phase composition where Ti2B, TiB, TiB2 titanium borides are formed. The increasing of chemical-thermal treatment time from 15 minutes to 2 hours leads to thickening of the borated layer (30...110 µm and transition zone (30...190 µm. Conclusions: Due to usage of nanodispersed boric powder, the boriding duration is decreasing in 2...3 times. This allows saving time and electric energy. The developed optimal mode of boriding the VT3-1 titanium alloy allows obtaining the required operational characteristics and to combine the saturation of the surface layer with atomic boron and hardening.

  1. Alloy NASA-HR-1

    Science.gov (United States)

    Chen, Po-Shou; Mitchell, Michael

    2005-01-01

    NASA-HR-1 is a high-strength Fe-Ni-base superalloy that resists high-pressure hydrogen environment embrittlement (HEE), oxidation, and corrosion. Originally derived from JBK-75, NASA-HR-1 has exceptional HEE resistance that can be attributed to its gamma-matrix and eta-free (Ni3Ti) grain boundaries. The chemistry was formulated using a design approach capable of accounting for the simultaneous effects of several alloy additions. This approach included: (1) Systematically modifying gamma-matrix compositions based on JBK-75; (2) Increasing gamma (Ni3(Al,Ti)) volume fraction and adding gamma-matrix strengthening elements to obtain higher strength; and (3) Obtaining precipitate-free grain boundaries. The most outstanding attribute of NASA-HR-1 is its ability to resist HEE while showing much improved strength. NASA-HR-1 has approximately 25% higher yield strength than JXK-75 and exhibits tensile elongation of more than 20% with no ductility loss in a hydrogen environment at 5 ksi, an achievement unparalleled by any other commercially available alloy. Its Cr and Ni contents provide exceptional resistance to environments that promote oxidation and corrosion. Microstructural stability was maintained by improved solid solubility of the gamma-matrix, along with the addition of alloying elements to retard eta (Ni3Ti) precipitation. NASA-HR-1 represents a new system that greatly extends the compositional ranges of existing HEE-resistant Fe-Ni-base superalloys.

  2. Microbial corrosion of aluminum alloy.

    Science.gov (United States)

    Yang, S S; Chen, C Y; Wei, C B; Lin, Y T

    1996-11-01

    Several microbes were isolated from the contaminated fuel-oil in Taiwan and the microbial corrosion of aluminum alloy A356-T6 was tested by MIL-STD-810E test method. Penicillium sp. AM-F5 and Cladosporium resinac ATCC 22712 had significant adsorption and pitting on the surface of aluminum alloy, Pseudomonas acruginosa AM-B5 had weak adsorption and some precipitation in the bottom, and Candida sp. AM-Y1 had the less adsorption and few cavities formation on the surface. pH of the aqueous phase decreased 0.3 to 0.7 unit for 4 months of incubation. The corrosion of aluminum alloy was very significant in the cultures of Penicillium sp. AM-F2, Penicillium sp. AM-F5 and C. resinac ATCC 22712. The major metabolites in the aqueous phase with the inoculation of C. resinac were citric acid and oxalic acid, while succinic acid and fumaric acid were the minors. PMID:10592801

  3. Electrodeposition of engineering alloy coatings

    DEFF Research Database (Denmark)

    Christoffersen, Lasse

    Nickel based electrodeposited alloys were investigated with respect to their deposition process, heat treatment, hardness, corrosion resistance and combined wear-corrosion resistance. The investigated alloys were Ni-B, Ni-P and Ni-W, which are not fully developed for industrial utilisation...... at the moment. It was the intention of this study to investigate whether the mentioned alloy processes are able to substitute conventional deposition techniques for wear and corrosion resistance, namely Ni-P produced by electroless deposition and electrodeposited hard chromium. The considerations......-P and Ni-W, respectively, resulted in hardness values of approx. 1000 HV0.1 in the case of Ni-P(6), approx. 1100 HV0.1 in the case of Ni-W(40-53) and approx. 1300 HV0.1 in the case of Ni-B(5). Cracks, which emerged during electrodeposition and heat treatment, were observed on Ni-W and Ni-B.The corrosion...

  4. Pack cementation coatings for alloys

    Energy Technology Data Exchange (ETDEWEB)

    He, Yi-Rong; Zheng, Minhui; Rapp, R.A. [Ohio State Univ., Columbus, OH (United States)

    1996-08-01

    The halide-activated pack cementation process was modified to produce a Ge-doped silicide diffusion coating on a Cr-Cr{sub 2}Nb alloy in a single processing step. The morphology and composition of the coating depended both on the composition of the pack and on the composition and microstructure of the substrate. Higher Ge content in the pack suppressed the formation of CrSi{sub 2} and reduced the growth kinetics of the coating. Ge was not homogeneously distributed in the coatings. In cyclic and isothermal oxidation in air at 700 and 1050{degrees}C, the Ge-doped silicide coating protected the Cr-Nb alloys from significant oxidation by the formation of a Ge-doped silica film. The codeposition and diffusion of aluminum and chromium into low alloy steel have been achieved using elemental Al and Cr powders and a two-step pack cementation process. Sequential process treatments at 925{degrees}C and 1150{degrees}C yield dense and uniform ferrite coatings, whose compositions are close to either Fe{sub 3}Al or else FeAl plus a lower Cr content, when processed under different conditions. The higher content of Al in the coatings was predicted by thermodynamic calculations of equilibrium in the gas phase. The effect of the particle size of the metal powders on the surface composition of the coating has been studied for various combinations of Al and Cr powders.

  5. Activation analysis for different structural alloys considered for ITER

    International Nuclear Information System (INIS)

    Activation calculations have been made for the austentic steel 316SS, the ferritic alloy HT-9, the titanium alloy Ti6A14V, and the vanadium alloy V5Cr5Ti in a liquid metal (Na) design suggested recently for ITER. The calculations show that the vanadium alloy has the minimum short and long-term radioactivity and BHP. It also has the minimum decay heat at all the time. The titanium alloy has less radioactivity than the austenitic and this ferritic alloys. However, the decay heat of this alloy could exceed that of the conventional alloys

  6. Bond Strength of Gold Alloys Laser Welded to Cobalt-Chromium Alloy

    OpenAIRE

    Watanabe, Ikuya; Wallace, Cameron

    2008-01-01

    The objective of this study was to investigate the joint properties between cast gold alloys and Co-Cr alloy laser-welded by Nd:YAG laser. Cast plates were fabricated from three types of gold alloys (Type IV, Type II and low-gold) and a Co-Cr alloy. Each gold alloy was laser-welded to Co-Cr using a dental laser-welding machine. Homogeneously-welded and non-welded control specimens were also prepared. Tensile testing was conducted and data were statistically analyzed using ANOVA. The homogeneo...

  7. Influence of alloy ingredients on mechanical properties of ternary boride hard alloy clad materials

    Institute of Scientific and Technical Information of China (English)

    LIU Fu-tian; SONG Shi-xue; YANG Jun-ru; HUANG Wei-ling; HUANG Chuan-zhen; CHENG Xin; LI Zhao-qian

    2004-01-01

    Using Mo, B-Fe alloy and Fe powders as raw materials, and adding C, Cr and Ni ingredients, respectively, or C, Cr and Ni mixed powders, ternary boride hard alloy clad materials was prepared on Q235 steel substrate by means of in-situ reaction and vacuum liquid phase sintering technology. The influence of alloy ingredients on the mechanical properties of ternary boride hard alloy clad materials was investigated. The results indicate that a mixture of 0.8% C, 5% Cr and 2% Ni ingredients gives a ternary boride hard alloy clad material with optimal mechanical properties, such as high transverse rupture strength, high hardness and good wear resistance.

  8. Study of Alpha-Sigma Phase Transformation in Mechanically Alloyed Fe-Cr-Sn Alloys

    OpenAIRE

    Costa, B. F. O.; Caër, G. Le; Campos, N. Ayres de

    2001-01-01

    The solubility of tin is significantly extended by mechanical alloying in near equiatomic Fe-Cr alloys. The influences of Sn concentration and of grain size on the kinetics of formation of the sigma-phase have been studied using different techniques. The sigma-phase formation is much faster for as-milled alloys than it is for conventional alloys. The sigma-phase formation rate decreases with the increase of Sn concentration in alloys with nanometer-sized grains as it does in coarse-grained al...

  9. Data set for diffusion coefficients of alloying elements in dilute Mg alloys from first-principles

    Directory of Open Access Journals (Sweden)

    Bi-Cheng Zhou

    2015-12-01

    Full Text Available Diffusion coefficients of alloying elements in Mg are critical for the development of new Mg alloys for lightweight applications. Here we present the data set of the temperature-dependent dilute tracer diffusion coefficients for 47 substitutional alloying elements in hexagonal closed packed (hcp Mg calculated from first-principles calculations based on density functional theory (DFT by combining transition state theory and an 8-frequency model. Benchmark for the DFT calculations and systematic comparison with experimental diffusion data are also presented. The data set refers to “Diffusion coefficients of alloying elements in dilute Mg alloys: A comprehensive first-principles study” by Zhou et al. [1].

  10. Fatigue crack propagation of new aluminum lithium alloy bonded with titanium alloy strap

    Institute of Scientific and Technical Information of China (English)

    Sun Zhenqi; Huang Minghui

    2013-01-01

    A new type of aluminum lithium alloy (A1-Li alloy) Al-Li-S-4 was investigated by test in this paper.Alloy plate of 400 mm × 140 mm × 6 mm with single edge notch was made into samples bonded with Ti-6Al-4V alloy (Ti alloy) strap by FM 94 film adhesive after the surface was treated.Fatigue crack growth of samples was investigated under cyclic loading with stress ratio (R) of 0.1 and load amplitude constant.The results show that Al-Li alloy plate bonded with Ti alloy strap could retard fatigue crack propagation.Retardation effect is related with width and thickness of strap.Flaws have an observable effect on crack propagation direction.

  11. Iron-based amorphous alloys and methods of synthesizing iron-based amorphous alloys

    Energy Technology Data Exchange (ETDEWEB)

    Saw, Cheng Kiong; Bauer, William A.; Choi, Jor-Shan; Day, Dan; Farmer, Joseph C.

    2016-05-03

    A method according to one embodiment includes combining an amorphous iron-based alloy and at least one metal selected from a group consisting of molybdenum, chromium, tungsten, boron, gadolinium, nickel phosphorous, yttrium, and alloys thereof to form a mixture, wherein the at least one metal is present in the mixture from about 5 atomic percent (at %) to about 55 at %; and ball milling the mixture at least until an amorphous alloy of the iron-based alloy and the at least one metal is formed. Several amorphous iron-based metal alloys are also presented, including corrosion-resistant amorphous iron-based metal alloys and radiation-shielding amorphous iron-based metal alloys.

  12. Combinatorial thin film materials science: From alloy discovery and optimization to alloy design

    Energy Technology Data Exchange (ETDEWEB)

    Gebhardt, Thomas, E-mail: gebhardt@mch.rwth-aachen.de; Music, Denis; Takahashi, Tetsuya; Schneider, Jochen M.

    2012-06-30

    This paper provides an overview of modern alloy development, from discovery and optimization towards alloy design, based on combinatorial thin film materials science. The combinatorial approach, combining combinatorial materials synthesis of thin film composition-spreads with high-throughput property characterization has proven to be a powerful tool to delineate composition-structure-property relationships, and hence to efficiently identify composition windows with enhanced properties. Furthermore, and most importantly for alloy design, theoretical models and hypotheses can be critically appraised. Examples for alloy discovery, optimization, and alloy design of functional as well as structural materials are presented. Using Fe-Mn based alloys as an example, we show that the combination of modern electronic-structure calculations with the highly efficient combinatorial thin film composition-spread method constitutes an effective tool for knowledge-based alloy design.

  13. Zirconium alloys produced by recycling zircaloy tunings

    Energy Technology Data Exchange (ETDEWEB)

    Gamba, N.S. [Instituto de Investigaciones en Catálisis y Petroquímica, INCAPE (FIQ, UNL–CONICET), Santiago del Estero 2829, 3000 Santa Fe (Argentina); Carbajal-Ramos, I.A. [Centro Atómico Bariloche, CNEA e Instituto Balseiro, Universidad Nacional de Cuyo, Av. Bustillo 9500, 8400 Bariloche (Argentina); Ulla, M.A.; Pierini, B.T. [Instituto de Investigaciones en Catálisis y Petroquímica, INCAPE (FIQ, UNL–CONICET), Santiago del Estero 2829, 3000 Santa Fe (Argentina); Gennari, F.C., E-mail: gennari@cab.cnea.gov.ar [Centro Atómico Bariloche, CNEA e Instituto Balseiro, Universidad Nacional de Cuyo, Av. Bustillo 9500, 8400 Bariloche (Argentina)

    2013-11-25

    Highlights: •Zr–Ti alloys were successfully produced by two-step procedure. •Zircaloy tunings were used as a valuable source of Zr. •Zircaloy tunings and Ti powders was milled under hydrogen to produce hydride powders. •Hydride powders were decomposed by heating at 900 °C to synthesize the Zr-based alloy. •The procedure could be extended to the production of other Zr-based alloys. -- Abstract: Zircaloy chips were recycled to successfully produce Zr–Ti alloys with bcc structure and different compositions. The procedure developed involves two steps. First, the reactive mechanical alloying (RMA) of the zircaloy tunings and Ti powders was performed to produce metal hydride powders, with a high refinement of the microstructure and a Zr–Ti homogeneous composition. Second, the metal hydride powders were thermally decomposed by heating up to 900 °C to synthesize the Zr-based alloy with a selected composition. The change in the nature of the powders from ductile to brittle during milling avoids both cold working phenomena between the metals and the use of a control agent. A minimum milling time is necessary to produce the solid solution with the selected composition. The microstructure and structure of the final alloys obtained was studied. The present procedure could be extended to the production of Zr-based alloys with the addition of other metals different from Ti.

  14. Tantalum modified ferritic iron base alloys

    Science.gov (United States)

    Oldrieve, R. E.; Blankenship, C. P. (Inventor)

    1977-01-01

    Strong ferritic alloys of the Fe-CR-Al type containing 0.4% to 2% tantalum were developed. These alloys have improved fabricability without sacrificing high temperature strength and oxidation resistance in the 800 C (1475 F) to 1040 C (1900 F) range.

  15. Methods for Electrodepositing Composition-Modulated Alloys

    DEFF Research Database (Denmark)

    Leisner, Peter; Nielsen, Christian Bergenstof; Tang, Peter Torben;

    1996-01-01

    Materials exhibiting unique mechanical, physical and chemical properties can be obtained by combining thin layers of different metals or alloys forming a multilayered structure. Two general techniques exist for electrodepositing composition-modulated alloy (CMA) materials; dual-bath and single-ba...

  16. Electroplating Zn-Al Alloy Technology

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    The method of controlling separating anode and separating power source was used to perform orthogonal optimization for the parameters in electroplating Zn-Al alloy.The electroplating Zn-Al alloy technology was decided, in which the content of Al is about 12%-15%.

  17. Solidification shrinkage of Ni-Cr alloys

    Energy Technology Data Exchange (ETDEWEB)

    Xiao Feng [Materials Interfacial Physical-Chemistry Research Institute, Chongqing Institute of Technology, No. 4 Xingsheng Road, Yangjiaping, Chongqing 400050 (China); Yang Renhui [Materials Interfacial Physical-Chemistry Research Institute, Chongqing Institute of Technology, No. 4 Xingsheng Road, Yangjiaping, Chongqing 400050 (China)]. E-mail: yangrh2004@21cn.com; Fang Liang [Department of Applied Physics, Chongqing University, No. 174 Shazhong Road, Shapingba, Chongqing 400044 (China); Zhang Chi [Materials Interfacial Physical-Chemistry Research Institute, Chongqing Institute of Technology, No. 4 Xingsheng Road, Yangjiaping, Chongqing 400050 (China)

    2006-07-25

    Ni-Cr superalloy is widely used in casting of critical components in gas-turbine engines. Because of the significant change in density of alloy in mushy state, porosity is likely to arise in the alloy parts due to the solidification shrinkage. On the other hand, because Ni-Cr alloy is very hard and difficult to be machined, the net-shape casting of the alloy is a cheap process. Therefore, it is essential to measure the solidification shrinkage of mushy alloy for obtaining low-cost net-shape casting ingot without inner porosity. However, there have been a few reports on the solidification shrinkage of the liquid Ni-Cr alloy. In this work, the solidification shrinkage of Ni-Cr alloy was calculated by measuring its density using modified sessile drop method. It has been found that, for Ni-(0-24.53)% Cr alloys, the solidification shrinkage value fluctuates in the range of 0.91-2.02% and it tends to increase with increasing Cr concentration in 0-10% Cr. However, for Cr concentration more than 10%, the solidification shrinkage holds on a certain value of 2.00%.

  18. Materials data handbook: Aluminum alloy 2219

    Science.gov (United States)

    Muraca, R. F.; Whittick, J. S.

    1972-01-01

    A summary of the materials property information for aluminum 2219 alloy is presented. The scope of the information includes physical and mechanical properties at cryogenic, ambient, and elevated temperatures. Information on material procurement, metallurgy of the alloy, corrosion, environmental effects, fabrication, and joining techniques is developed.

  19. Preparation of hydrogenated amorphous silicon tin alloys

    OpenAIRE

    Vergnat, M.; Marchal, G.; Piecuch, M.

    1987-01-01

    This paper describes a new method to obtain hydrogenated amorphous semiconductor alloys. The method is reactive co-evaporation. Silicon tin hydrogenated alloys are prepared under atomic hydrogen atmosphere. We discuss the influence of various parameters of preparation (hydrogen pressure, tungsten tube temperature, substrate temperature, annealing...) on electrical properties of samples.

  20. Sputtered Clusters from Niobium-Vanadium Alloys

    DEFF Research Database (Denmark)

    Schou, Jørgen; Hofer, W. O.

    1982-01-01

    A series of Nb&z.sbnd;V alloys have been irradiated by 6 keV argon ions. Homonuclear and heteronuclear clusters emitted from these alloys have been studied by means of post-ionization and/or secondary ion mass spectrometry. The intensity of clusters of atomic masses up to approximately 300 amu wa...

  1. Theory of Rare-Earth Alloys

    DEFF Research Database (Denmark)

    Lindgård, Per-Anker

    1977-01-01

    A mean-field random alloy theory combined with a simple calculation of the exchange interaction J(c,Q) is shown to quantitatively account for the phase diagrams for alloys of rare-earth metals with Y, Lu, Sc, and other rare-earth metals. A concentration-dependent J(c,Q) explains the empirical 2...

  2. Friction Stir Welding of Aluminum Alloys

    Institute of Scientific and Technical Information of China (English)

    FU Zhi-hong; HE Di-qiu; WANG Hong

    2004-01-01

    Friction stir welding(FSW), a new solid-state welding technology invited in the early 1990s,enables us weld aluminum alloys and titanium alloys etc. The processing of FSW, the microstructure in FSW alloysand the factors influencing weld quality are introduced. The complex factors affecting the properties are researched.

  3. Trends of Chinese RE Hydrogen Storage Alloys

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    @@ Ⅰ . Status of Chinese RE Hydrogen Storage Alloys 1. R εt D of RE Hydrogen Storage Alloys in China AB5 hydrogen storage materials, taking rare earth mischmetals as raw materials, developed rapidly in China in recent years. Today, different countries attach importance to the development and application of the new environmental protection reproducible power sources.

  4. Corrosion resistance improvement of titanium base alloys

    Directory of Open Access Journals (Sweden)

    Mihai V. Popa

    2010-01-01

    Full Text Available The corrosion resistance of the new Ti-6Al-4V-1Zr alloy in comparison with ternary Ti-6Al-4V alloy in Ringer-Brown solution and artificial Carter-Brugirard saliva of different pH values was studied. In Ringer-Brown solution, the new alloy presented an improvement of all electrochemical parameters due to the alloying with Zr; also, impedance spectra revealed better protective properties of its passive layer. In Carter-Brugirard artificial saliva, an increase of the passive film thickness was proved. Fluoride ions had a slight negative influence on the corrosion and ion release rates, without to affect the very good stability of the new Ti-6Al-4V-1Zr alloy.

  5. New zirconium alloys for nuclear application

    International Nuclear Information System (INIS)

    Zirconium alloys are widely used in the nuclear industry, mainly in fuel cladding tubes and structural components for PWR plants. The service life of these components, which operate under high temperatures conditions (∼ 300 deg C), has led to developing new alloys with the aim to improve the mechanical properties, corrosion resistance and irradiation damage. The variation in the composition of the alloy produces second phase particles which alter the materials properties according to their size and distribution, is essential therefore, knowledge their characteristics. Analysis of second phase particles in zirconium alloys are carried out by scanning electron microscopy, transmission electron microscopy and image analysis. This study used the zircaloy-4 to illustrate the characterization of these alloys through the study of second phase particles. (author)

  6. Long - range foundry Al composite alloys

    Directory of Open Access Journals (Sweden)

    A. D. Mekhtiev

    2014-10-01

    Full Text Available The technology of obtaining nanostructural composite aluminum alloys consists in the plasma injection of refractory nanometric particles with simultaneous two-plane magnetic dynamic mixing of the melt. Particularly important in obtaining composite aluminum matrix alloys is the provision of the introduced particles wettability with the matrix melt for forming stable adhesive bonds. Nanostructured powder components can be considered not only to be a starting product for producing nanostructural composite aluminum alloys but as an independent commerce product. Nanostructural composite metal matrix alloys make one of the most prospective structural materials of the future, and liquid-phase technologies of their obtaining are the most competitive in producing products of nanostructural composite aluminum alloys in the industrial scale.

  7. Internal chlorination of Ni-Cr alloys

    Energy Technology Data Exchange (ETDEWEB)

    Berztiss, D.; Hennesen, K.; Grabke, H.J. [Max-Planck-Institut fuer Eisenforschung GmbH, Duesseldorf (Germany)

    1998-12-31

    In contrast to internal oxidation, sulfidation and carburization, very little information is available regarding internal chlorination, especially diffusion of chlorine in metallic alloys. This paper describes results of experiments on Ni-Cr alloys (<10 wt% Cr) exposed in an atmosphere containing radioactive HCl. The diffusion of chlorine in the alloy can be determined by measurement of residual {beta}-activity from the sample surface. Successively thin layers (0.5-10 {mu}m) of the alloy were removed by lapping and the surface activity was measured to obtain a depth profile. Both single and polycrystalline materials were tested. Through this work it should be determined if there is in fact solubility and diffusion of chlorine in Ni-based alloys as some authors have proposed or if the ingress of chlorine is mainly a grain boundary phenomenon. (orig.)

  8. [Use of titanium alloys for medical instruments].

    Science.gov (United States)

    Feofilov, R N; Chirkov, V K; Levin, M V

    1977-01-01

    On the ground of an analysis into properties of titanium and its alloys the fields of their possible utilization for making various medical instruments are proposed. Because of their insufficient hardness and wear-resistance the titanium alloys cannot be recommended for making medical instruments with thin cutting edges. For the reasons of their insufficient strength, low wear-resistance and substandard modulus of elasticity, it is inexpedient to use titanium alloys in making many types of clamping medical instruments. Nor is it advisable to employ titanium alloys in handles of the instruments, for this may lead to a contact corrosion of their working parts. The use of titanium alloys is recommended for making bone-joining members, retracting medical instruments, of the spatula and speculum types, some kinds of non-magnetic pincers and ultrasonic medical instruments.

  9. Mechanical behaviour of aluminium-lithium alloys

    Indian Academy of Sciences (India)

    N Eswara Prasad; A A Gokhale; P Rama Rao

    2003-02-01

    Aluminium-lithium alloys hold promise of providing a breakthrough response to the crying need for lightweight alloys for use as structurals in aerospace applications. Considerable worldwide research has gone into developing a range of these alloys over the last three decades. As a result, substantial understanding has been developed of the microstructure-based micromechanisms of strengthening, of fatigue and fracture as well as of anisotropy in mechanical properties. However, these alloys have not yet greatly displaced the conventionally used denser Al alloys on account of their poorer ductility, fracture toughness and low cycle fatigue resistance. This review aims to summarise the work pertaining to study of structure and mechanical properties with a view to indicate the directions that have been and can be pursued to overcome property limitations.

  10. Crystallographic attributes of a shape-memory alloy

    OpenAIRE

    Bhattacharya, Kaushik

    1999-01-01

    Shape-memory Alloys are attractive for many potential applications. In an attempt to provide ideas and guidelines for the development of new shape-memory alloys, this paper reports on a series of investigations that examine the reasons in the crystallography that make (i) shape-memory alloys special amongst martensites and (ii) Nickel-Titanium special among shape-memory alloys.

  11. REVIEW ON RESEARCH AND DEVELOPMENT OF MAGNESIUM ALLOYS

    Institute of Scientific and Technical Information of China (English)

    Z.Yaug; J.P.Li; J.X.Zhang; G.W.Lorimer; J.Robson

    2008-01-01

    The current research and development of magnesium alloys is summarized. Several aspects of magnesium alloys are described: cast Mg alloy, wrought Mg alloy, and novel processing. The subjects are discussed individually and recommendations for further study arc listed in the final section.

  12. Shot peening of aluminium alloys

    International Nuclear Information System (INIS)

    Shot peening is a process of cold-hammering where a metallic surface is pelted with spherical grains. Each grain bumping into the surface acts as a hammer head and creates a small crater. The overlapping of these craters produces a residual compression layer just underneath the surface. It is well known that cracks cannot spread in a compression zone. In most cases of fatigue rupture and stress corrosion cracks propagate from the surface towards the inside so shot peening allows a longer lifetime of castings. Moreover most materials present a better resistance due to the cold-hammering effect of shot peening. Metallic surfaces can be treated in workshops or directly on site. Typical pieces that undergo shot peening on site are storing tanks, gas and steam turbines, tubes of steam generators and piping in oil or nuclear or chemical industries. This article describes shot peening from a theoretical and general point of view and presents the application to aluminium-lithium alloys. In the case of aluminium alloys shot peening can be used to shape the piece (peen-forming). (A.C.)

  13. Niobium-titanium oxide alloys

    International Nuclear Information System (INIS)

    Oxide dispersion strengthening of niobium with TiO2 has lead to a material which combines superior mechanical properties with the excellent biocompatibility and corrosion resistance of the soft metal niobium. Modern analytical tools including TEM with advanced analysis features (EDX and EELS) were used to clarify the mechanism being a dissolution of the oxide at sintering temperatures and a controlled precipitation by proper aging. The influence of variations of the oxide content, the sintering conditions and the aging treatment were investigated in order to optimize the alloy. The best combination of properties was found with a Nb-1%TiO2 variant with optimized oxygen content. Strength can very well be correlated with TEM data of dispersion parameters. Applications for this ODS niobium alloy are seen in the field of high-load bearing medical implants but also in chemical engineering wherever the good corrosion resistance of niobium is needed in combination with higher mechanical and thermal strength. 14 refs., 17 figs., 3 tabs. (Author)

  14. Processing of Aluminum Alloys Containing Displacement Reaction Products

    OpenAIRE

    Stawovy, Michael Thomas

    1998-01-01

    Aluminum and metal-oxide powders were mixed using mechanical alloying. Exothermic displacement reactions could be initiated in the powders either by mechanical alloying alone or by heat treating the mechanically alloyed powders. Exponential relationships developed between the initiation time of the reaction and the mechanical alloying charge ratio. The exponential relationships were the result of changes in the intensity and quantity of collisions occurring during mechanical alloying. Di...

  15. Impurity control and corrosion resistance of magnesium-aluminum alloy

    Energy Technology Data Exchange (ETDEWEB)

    Liu, M. [GM China Lab; Song, GuangLing [ORNL

    2013-01-01

    The corrosion resistance of magnesium alloys is very sensitive to the contents of impurity elements such as iron. In this study, a series of diecast AXJ530 magnesium alloy samples were prepared with additions of Mn and Fe. Through a comprehensive phase diagram calculation and corrosion evaluation, the mechanisms for the tolerance limit of Fe in magnesium alloy are discussed. This adds a new dimension to control the alloying impurity in terms of alloying composition design and casting conditions.

  16. Density and Structure Analysis of Molten Ni-W Alloys

    Institute of Scientific and Technical Information of China (English)

    Feng XIAO; Liang FANG

    2004-01-01

    Density of molten Ni and Ni-W alloys was measured in the temperature range of 1773~1873 K with a sessile drop method.The density of molten Ni and Ni-W alloys trends to decrease with increasing temperature. The density and molar volume of the alloys trend to increase with increasing W concentration in the alloys. The calculation result shows an ideal mixing of Ni-W alloys.

  17. Microstructure of undercooled Pb-Sn alloys

    Directory of Open Access Journals (Sweden)

    Walman Benício de Castro

    2001-01-01

    Full Text Available Melt undercooling opens new solidification pathways for non-equilibrium phases and non-conventional microstructures. Several techniques, including the fluxing technique, have been developed in order to reduce nucleation sites and to produce high undercoolings for metals and alloys. In this work the fluxing technique was applied to Pb-25wt%Sn (hypoeutectic, Pb-61.9wt%Sn (eutectic and Pb-90wt%Sn (hypereutectic alloys to investigate the influence of the undercooling on the microstructure of these alloys. For the hypoeutectic alloy, an increasing of the undercooling (deltaTe from 7 to 13 K resulted in interdendritic eutectic refinement. For the hypereutectic alloy, an increasing of undercooling from 8 to 16 K resulted in a reduction of the beta-Sn primary dendrites arm spacing from 50 m to 30 m. For the both hypoeutectic and eutectic alloys, an increasing of the undercooling resulted in an interdendritic eutectic with anomalous morphology. The results indicated that the critical eutectic undercooling, deltaTe*, that causes a transition from lamellar eutectic to anomalous eutectic in the Pb-Sn alloys, is around 6 K.

  18. Surface modification of Ti alloy by electro-explosive alloying and electron-beam treatment

    Energy Technology Data Exchange (ETDEWEB)

    Gromov, Victor, E-mail: gromov@physics.sibsiu.ru; Kobzareva, Tatiana, E-mail: kobzarevatanya@mail.ru; Budovskikh, Evgeniy, E-mail: budovskih-ea@physics.sibsiu.ru; Baschenko, Lyudmila, E-mail: gromov@physics.sibsiu.ru [Siberian State Industrial University, 42, Kirov Str., Novokuznetsk, 654007 (Russian Federation); Ivanov, Yuryi, E-mail: yufi55@mail.ru [Institute of High Current Electronics SB RAS, 4, Akademicheskii Av. Tomsk, 634055 (Russian Federation); National Research Tomsk State University, 30, Lenina Av. Tomsk, 634034 (Russian Federation)

    2016-01-15

    By methods of modern physical metallurgy the analysis of structure phase states of titanium alloy VT6 is carried out after electric explosion alloying with boron carbide and subsequent irradiation by pulsed electron beam. The formation of an electro-explosive alloying zone of a thickness up to 50 µm, having a gradient structure, characterized by decrease in the concentration of carbon and boron with increasing distance to the treatable surface has been revealed. Subsequent electron-beam treatment of alloying zone leads to smoothing of the alloying area surface and is accompanied by the multilayer structure formation at the depth of 30 µm with alternating layers with different alloying degrees having the structure of submicro - and nanoscale level.

  19. Surface modification of Ti alloy by electro-explosive alloying and electron-beam treatment

    Science.gov (United States)

    Gromov, Victor; Kobzareva, Tatiana; Ivanov, Yuryi; Budovskikh, Evgeniy; Baschenko, Lyudmila

    2016-01-01

    By methods of modern physical metallurgy the analysis of structure phase states of titanium alloy VT6 is carried out after electric explosion alloying with boron carbide and subsequent irradiation by pulsed electron beam. The formation of an electro-explosive alloying zone of a thickness up to 50 µm, having a gradient structure, characterized by decrease in the concentration of carbon and boron with increasing distance to the treatable surface has been revealed. Subsequent electron-beam treatment of alloying zone leads to smoothing of the alloying area surface and is accompanied by the multilayer structure formation at the depth of 30 µm with alternating layers with different alloying degrees having the structure of submicro - and nanoscale level.

  20. Effects of alloying side B on Ti-based AB2 hydrogen storage alloys

    Institute of Scientific and Technical Information of China (English)

    王家淳; 于荣海; 刘庆

    2004-01-01

    Ti-based AB2-type hydrogen storage alloys are a group of promising materials, which will probably replace the prevalent rare earth-based AB5-type alloys and be adopted as the main cathode materials of nickelmetal hydride (Ni-MH) batteries in the near future. Alloying in side B is a major way to improve the performance of Ti-based AB2-type alloys. Based on recent studies, the effects of alloying elements in side B upon the performance of Ti-based AB2 -type hydrogen storage alloys are systematically reviewed here. These performances are divided into two categories, namely PCI characteristics, including hydrogen storage capacity (HSC), plateau pressure (PP), pressure hysteresis (PH) and pressure plateau sloping (PPS) , and electrochemical properties, including discharge capacity (DC), activation property (AP), cycling stability (CS) and high-rate dischargeability (HRD). Furthermore, the existing problems in these investigations and some suggestions for future research are proposed.

  1. Preparation of casting alloy ZL101 with coarse aluminum-silicon alloy

    Institute of Scientific and Technical Information of China (English)

    YOU Jing; WANG Yao-wu; FENG Nai-xiang; YANG Ming-sheng

    2008-01-01

    The coarse Al-Si alloy produced by carbothermal reduction of aluminous ore contains 55% Al, 25% Si and some impurities. The main impurities are slag and iron. The process of manufacturing casting Al-Si alloy ZL101 with the coarse Al-Si alloy was studied. The phase constitution and microstructure of the coarse Al-Si alloy, slag and ZL101 were examined by X-ray diffractometry and scanning electron microscopy. The results show that the content of silicon and iron in the casting alloy reduces with the increase of the dosage of purificant and manganese, but increases with the rise of filtering temperature. It is found that casting Al-Si alloy conforming to industrial standard can be produced after refining by using purificant, and removing iron by using manganese and added magnesium.

  2. Antibacterial biodegradable Mg-Ag alloys

    Directory of Open Access Journals (Sweden)

    D Tie

    2013-06-01

    Full Text Available The use of magnesium alloys as degradable metals for biomedical applications is a topic of ongoing research and the demand for multifunctional materials is increasing. Hence, binary Mg-Ag alloys were designed as implant materials to combine the favourable properties of magnesium with the well-known antibacterial property of silver. In this study, three Mg-Ag alloys, Mg2Ag, Mg4Ag and Mg6Ag that contain 1.87 %, 3.82 % and 6.00 % silver by weight, respectively, were cast and processed with solution (T4 and aging (T6 heat treatment.The metallurgical analysis and phase identification showed that all alloys contained Mg4Ag as the dominant β phase. After heat treatment, the mechanical properties of all Mg-Ag alloys were significantly improved and the corrosion rate was also significantly reduced, due to presence of silver. Mg(OH2 and MgO present the main magnesium corrosion products, while AgCl was found as the corresponding primary silver corrosion product. Immersion tests, under cell culture conditions, demonstrated that the silver content did not significantly shift the pH and magnesium ion release. In vitro tests, with both primary osteoblasts and cell lines (MG63, RAW 264.7, revealed that Mg-Ag alloys show negligible cytotoxicity and sound cytocompatibility. Antibacterial assays, performed in a dynamic bioreactor system, proved that the alloys reduce the viability of two common pathogenic bacteria, Staphylococcus aureus (DSMZ 20231 and Staphylococcus epidermidis (DSMZ 3269, and the results showed that the killing rate of the alloys against tested bacteria exceeded 90%. In summary, biodegradable Mg-Ag alloys are cytocompatible materials with adjustable mechanical and corrosion properties and show promising antibacterial activity, which indicates their potential as antibacterial biodegradable implant materials.

  3. Laser surface treatment of cast magnesium alloys

    Directory of Open Access Journals (Sweden)

    L.A. Dobrzański

    2009-02-01

    Full Text Available Purpose: The goal of this work was to investigate influence of laser treatment on structure and properties MCMgAl3Zn1, MCMgAl6Zn1, MCMgAl9Zn1 and MCMgAl12Zn1 cast magnesium alloys.Design/methodology/approach: Tests were made on the experimental MCMgAl3Zn1 MCMgAl6Zn1 MCMgAl9Zn1 and MCMgAl12Zn1 casting magnesium alloys. Laser treatment was made using the Rofin DL020 HPDL high power diode laser in the argon shield gas cover with the technique of the continuous powder supply to the remelted pool area.Findings: Investigations of the surface layers carried out confirm that laser treatment of the surface layer of the Mg-Al-Zn casting magnesium alloys is feasible using the HPDL high power diode laser ensuring better properties compared to alloys properties after the regular heat treatment after employing the relevant process parameters. Occurrences were found based on the metallographic examinations of the remelted zone (RZ and the heat affected zone (HAZ in alloyed surface layer of the investigated casting magnesium alloy.Research limitations/implications: This investigation presents different laser power and in this research was used two powders, namely tungsten-, and titanium carbide.Practical implications: Reinforcing the surface of cast magnesium alloys by adding TiC and WC particles is such a possible way to achieve the possibilities of the laser melt injection process, which is a potential technique to produce a Metal-Matrix Composite (MMC layer in the top layer of a metal workpiece.Originality/value: The originality of this work is applying of High Power Diode Laser for alloying of magnesium alloy using hard particles like tungsten- and titanium carbide.

  4. PRODUCTION OF WELDMENTS FROM SINTERED TITANIUM ALLOYS

    Directory of Open Access Journals (Sweden)

    A. YE. Kapustyan

    2014-04-01

    Full Text Available Purpose. Limited application of details from powder titanium alloys is connected with the difficulties in obtaining of long-length blanks, details of complex shape and large size. We can solve these problems by applying the welding production technology. For this it is necessary to conduct a research of the structure and mechanical properties of welded joints of sintered titanium alloys produced by flash welding. Methodology. Titanium industrial powders, type PT5-1 were used as original substance. Forming of blanks, whose chemical composition corresponded to BT1-0 alloy, was carried out using the powder metallurgy method. Compounds were obtained by flash welding without preheating. Microstructural investigations and mechanical tests were carried out. To compare the results investigations of BT1-0 cast alloy were conducted. Findings. Samples of welded joints of sintered titanium blanks from VT1-0 alloy using the flash butt welding method were obtained. During welding the microstructure of basic metal consisting of grains of an a-phase, with sizes 40...70 mkm, is transformed for the seam weld and HAZ into the lamellar structure of an a-phase. The remaining pores in seam weld were practically absent; in the HAZ their size was up to 2 mkm, with 30 mkm in the basic metal. Attainable level of mechanical properties of the welded joint in sintered titanium alloys is comparable to the basic metal. Originality. Structure qualitative changes and attainable property complex of compounds of sintered titanium alloys, formed as a result of flash butt welding were found out. Practical value. The principal possibility of high-quality compounds obtaining of sintered titanium alloys by flash welding is shown. This gives a basis for wider application of sintered titanium alloys due to long-length blanks production that are correspond to deformable strand semi finished product.

  5. Cast bulk glassy alloys:fabrication,alloy development and properties

    Institute of Scientific and Technical Information of China (English)

    Qingsheng Zhang; Chunling Qin; Akihisa Inoue

    2010-01-01

    Metallic glasses represent an interesting group of materials as they possess outstanding physical, chemical and mechanical properties compared to their crystalline counterparts. Currently, with well designed compositions it is possible to cast liquid alloys into the glassy state at low critical cooling rates from 100 K·s-1 to 1 K·s-1 and in large critical sample sizes up to several centimeters, which significantly enhances the promise for possible applications as advanced engineering materials. This paper reviews the development of(ZrCu)-based bulk metallic glasses with large sizes by copper mold casting and their unique properties. Additionally, the ex-situ and in-situ second phases reinforced BMG composites with large plasticity are also presented.

  6. Antibacterial biodegradable Mg-Ag alloys

    OpenAIRE

    D Tie; F Feyerabend; W-D Müller; Schade, R; Liefeith, K; KU Kainer; Willumeit, R.

    2013-01-01

    The use of magnesium alloys as degradable metals for biomedical applications is a topic of ongoing research and the demand for multifunctional materials is increasing. Hence, binary Mg-Ag alloys were designed as implant materials to combine the favourable properties of magnesium with the well-known antibacterial property of silver. In this study, three Mg-Ag alloys, Mg2Ag, Mg4Ag and Mg6Ag that contain 1.87 %, 3.82 % and 6.00 % silver by weight, respectively, were cast and processed with solut...

  7. Antibacterial Mg-Ag biodegradable alloys

    OpenAIRE

    Tie, Di

    2013-01-01

    The use of magnesium alloys as degradable metals for biomedical applications is topic of ongoing research. As a further aspect, the demand for multifunctional materials is increasing. Hence, binary Mg-Ag alloys were designed to combine the favourable properties of magnesium with the wellknown antibacterial property of silver. In this study, three Mg-Ag alloys, Mg2Ag, Mg4Ag and Mg6Ag which contain 1.87%, 3.82% and 6.00% silver by weight respectively were casted and processed with solution and ...

  8. Current assisted superplastic forming of titanium alloy

    Directory of Open Access Journals (Sweden)

    Wang Guofeng

    2015-01-01

    Full Text Available Current assisted superplastic forming combines electric heating technology and superplastic forming technology, and can overcome some shortcomings of traditional superplastic forming effectively, such as slow heating rate, large energy loss, low production efficiency, etc. Since formability of titanium alloy at room temperature is poor, current assisted superplastic forming is suitable for titanium alloy. This paper mainly introduces the application of current assisted superplastic forming in the field of titanium alloy, including forming technology of double-hemisphere structure and bellows.

  9. Thermodynamics and Structure of Plutonium Alloys

    Energy Technology Data Exchange (ETDEWEB)

    Allen, P G; Turchi, P A; Gallegos, G F

    2004-01-30

    The goal of this project was to investigate the chemical and structural effects of gallium and impurity elements, iron and nickel, on the phase behavior and crystallography of Pu-Ga alloys. This was done utilizing a theoretical chemical approach to predict binary and ternary alloy energetics, phase stability, and transformations. The modeling results were validated with experimental data derived from the synthesis of selected alloys and advanced characterization tools. The ultimate goal of this work was to develop a robust predictive capability for studying the thermodynamics and the structure-properties relationships in complex materials of high relevance to the Laboratory and DOE mission.

  10. Graded coatings for metallic implant alloys

    Energy Technology Data Exchange (ETDEWEB)

    Saiz, Eduardo; Tomsia, Antoni P.; Fujino, Shigeru; Gomez-Vega, Jose M.

    2002-08-01

    Graded glass and glass-hydroxyapatite coatings on Ti-based and Co-Cr alloys have been prepared using a simple enameling technique. The composition of the glasses has been tailored to match the thermal expansion of the alloys. By controlling the firing time, and temperature, it has been possible to control the reactivity between the glass and the alloy and to fabricate coatings (25 to 150 mu m thick) with excellent adhesion to the substrate, resistant to corrosion and able to precipitate hydroxyapatite during in vitro tests in simulated body fluid.

  11. Surface tension of tin-lithium alloys

    International Nuclear Information System (INIS)

    Temperature and concentration dependences of surface tension of tin-lithium alloys in the range of temperatures 250-410 deg C and concentrations 6.3-15.0 at. % Li were measured by the big drop method. It was ascertained that lithium is a surfactant component of Sn-Li system. Positive sign of surface tension temperature coefficients suggests prevailing lithium desorption from the liquid alloy surface with temperature increase. Calculated value of maximum lithium adsorption in its alloys with tin, containing about 4 at. % Li, makes up 8.5 x 10-6 mol/m2

  12. Laser repair hardfacing of titanium alloy turbine

    OpenAIRE

    A. Klimpel; D. Janicki; A. Lisiecki; A. Rzeźnikiewicz

    2011-01-01

    Purpose: of this paper: work out repair technology of worn abutments of aircraft jet engine blades forged of titanium alloy WT3-1.Design/methodology/approach: The study were based on the analysis of laser HPDL powder surfacing of titanium alloy plates using wide range chemical composition consumables of titanium alloys and mixtures of pure titanium and spherical powder of WC indicated that very hard and highest quality deposits are provided by powder mixture of 40-50%Ti+60-50%WC.Findings: It ...

  13. Corrosion behavior of magnesium and magnesium alloys

    Institute of Scientific and Technical Information of China (English)

    I.M.Baghni; WU Yin-shun(吴荫顺); LI Jiu-qing(李久青); ZHANG Wei(张巍)

    2004-01-01

    The automotive industry has crossed the threshold from using magnesium alloys in interior applications such as instrument panels and steering wheels to unprotected environment such as oil pan, cylinder head and wheels. The expanding territory of magnesium leads to new challenges: mainly environmental degradation of the alloys used and how they can be protected. The present critical review is aimed at understanding the corrosion behavior of magnesium and magnesium alloys in industrial and marine environments, and the effect of microstructure, additive elements and inhibitors on the corrosion mechanism.

  14. Stress corrosion cracking of titanium alloys

    Science.gov (United States)

    Statler, G. R.; Spretnak, J. W.; Beck, F. H.; Fontana, M. G.

    1974-01-01

    The effect of hydrogen on the properties of metals, including titanium and its alloys, was investigated. The basic theories of stress corrosion of titanium alloys are reviewed along with the literature concerned with the effect of absorbed hydrogen on the mechanical properties of metals. Finally, the basic modes of metal fracture and their importance to this study is considered. The experimental work was designed to determine the effects of hydrogen concentration on the critical strain at which plastic instability along pure shear directions occurs. The materials used were titanium alloys Ti-8Al-lMo-lV and Ti-5Al-2.5Sn.

  15. Electron microscopy of nuclear zirconium alloys

    International Nuclear Information System (INIS)

    Transmission electron microscopy observations of the microstructure of zirconium alloys used in fuel sheaths of nuclear power reactors are reported. Specimens were observed after different thermal and mechanical treatment, similar to those actually used during fabrication of the sheaths. Electron micrographs and electron diffraction patterns of second phase particles present in zircaloy-2 and zircaloy-4 were also obtained, as well as some characteristic parameters. Images of oxides and hydrides most commonly present in zirconium alloys are also shown. Finally, the structure of a Zr-2,5Nb alloy used in CANDU reactors pressure tubes, is observed by electron microscopy. (Author)

  16. On Silicides in High Temperature Titanium Alloys

    OpenAIRE

    Ramachandra, C.; Vakil Singh; P. Rama Rao

    1986-01-01

    High temperature titanium alloys like IMI 685 contain small amounts of silicon (~ 0.25 wt. per cent) to improve creep resistance. Different types of silicides, namely Ti5Si3 (TiZr)5Si3(S1) and (TiZr)6 Si3 (S2), have been observed to precipitate in various silicon-bearing titanium alloys depending upon their composition and heat treatment. The precipitation of silicides, their orientation relationship with the matrix in different alloys, and the beneficial influence of thermo-mechanical treatm...

  17. Procurement and Initial Characterization of Alloy 230 and CMS Alloy 617

    International Nuclear Information System (INIS)

    Material for initial testing of alloy 230 and a controlled-chemistry variant of alloy 617 has been procured in the form of plates. 3/4-inch thick alloy 230 plate was commercially procured from Haynes International, and 2-inch thick CCA 617, an existing controlled-chemistry variant of alloy 617, was obtained from Alstom Power through the ultra-supercritical fossil energy program. This report describes the procurement of these plates and their characteristics in terms of vendor-supplied chemistry and mechanical properties. Further detailed characterization tests are planned for this fiscal year, and this report will be updated in September 2006 to include the results of these tests

  18. Grain refinement of an AZ63B magnesium alloy by an Al-1C master alloy

    Energy Technology Data Exchange (ETDEWEB)

    Yichuan Pan; Xiangfa Liu; Hua Yang [The Key Lab. of Liquid Structure and Heredity of Materials, Shandong Univ., Jinan (China)

    2005-12-01

    In order to develop a refiner of Mg-Al alloys, an Al-1C (in wt.%) master alloy was synthesized using a casting method. The microstructure and grain-refining performance of the Al-1C master alloy were investigated using X-ray diffraction (XRD), electron probe microanalysis (EPMA) and a grain-refining test. The microstructure of the Al-1C master alloy is composed of {alpha}-Al solid solution, Al{sub 4}C{sub 3} particles, and graphite phases. After grain refinement of AZ63B alloy by the Al-1C master alloy, the mean grain size reached a limit when 2 wt.% Al-C master alloy was added at 800 C and held for 20 min in the melt before casting. The minimum mean grain size is approximately 48 {mu}m at the one-half radius of the ingot and is about 17% of that of the unrefined alloy. The Al-1C master alloy results in better grain refinement than C{sub 2}Cl{sub 6} and MgCO{sub 3} carbon-containing refiners. (orig.)

  19. HAYNES 244 alloy – a new 760 ∘C capable low thermal expansion alloy

    Directory of Open Access Journals (Sweden)

    Fahrmann Michael G.

    2014-01-01

    Full Text Available HAYNES® 244TM alloy is a new 760∘C capable, high strength low thermal expansion (CTE alloy. Its nominal chemical composition in weight percent is Ni – 8 Cr – 22.5 Mo – 6 W. Recently, a first mill-scale heat of 244 alloy was melted by Haynes International, and processed to various product forms such as re-forge billet, plate, and sheet. This paper presents key attributes of this new alloy (CTE, strength, low-cycle fatigue performance, oxidation resistance, thermal stability as they pertain to the intended use in rings and seals of advanced gas turbines.

  20. Wear Behaviour of Zinc-Aluminium Alloys and the Bearings Produced from these Alloys

    OpenAIRE

    SAVAŞKAN, Temel; PÜRÇEK, Gençağa

    2000-01-01

    In this study, two ternary zinc-aluminum-copper and two quaternary zinc-aluminum-copper-silicon alloys were produced by permanent mould casting. The wear behaviour of these alloys were investigated with a pin-on-disc machine The wear behaviour of the journal bearings produced from these alloys was investigated with a bearing test rig. The wear resistance of zinc-aluminum based alloys was found to be higher than that of CuSn12 bronze. ın addition, the bearings produced from the zinc-...

  1. Standard Specification for Electric Fusion-Welded Ni-Cr-Co-Mo Alloy (UNS N06617), Ni-Fe-Cr-Si Alloys (UNS N08330 and UNS N08332), Ni-Cr-Fe-Al Alloy (UNS N06603), Ni-Cr-Fe Alloy (UNS N06025), and Ni-Cr-Fe-Si Alloy (UNS N06045) Pipe

    CERN Document Server

    American Society for Testing and Materials. Philadelphia

    2014-01-01

    Standard Specification for Electric Fusion-Welded Ni-Cr-Co-Mo Alloy (UNS N06617), Ni-Fe-Cr-Si Alloys (UNS N08330 and UNS N08332), Ni-Cr-Fe-Al Alloy (UNS N06603), Ni-Cr-Fe Alloy (UNS N06025), and Ni-Cr-Fe-Si Alloy (UNS N06045) Pipe

  2. Recycling potential of titanium alloys

    International Nuclear Information System (INIS)

    This study examines just how long one must contain radioactive titanium before it can be safely reprocessed. It was assumed that the spent first wall and blanket structural material would be completely reprocessed in a standard manufacturing facility capable of both primary and secondary fabrication. It was found that reprocessing could occur when the chemical hazard associated with inhalation was greater than the hazard associated with inhalating the same amount of radioactive species. This conclusion allowed the use of the threshold limiting value (TLV) to set a limit on the airborne concentration of the elements. Then by calculating the time required for that amount of material to decay to the same diluent factor indicated by the biological hazard potential (BHP) in air, the time for reprocessing was determined. Based on these assumptions, it was determined that it is feasible to think of titanium, and some of its alloying elements as being recyclable in a relatively short time period

  3. Shape memory alloy based motor

    Indian Academy of Sciences (India)

    S V Sharma; M M Nayak; N S Dinesh

    2008-10-01

    Design and characterization of a new shape memory alloy wire based Poly Phase Motor has been reported in this paper. The motor can be used either in stepping mode or in servo mode of operation. Each phase of the motor consists of an SMA wire with a spring in series. The principle of operation of the poly phase motor is presented. The motor resembles a stepper motor in its functioning though the actuation principles are different and hence has been characterized similar to a stepper motor. The motor can be actuated in either direction with different phase sequencing methods, which are presented in this work. The motor is modelled and simulated and the results of simulations and experiments are presented. The experimental model of the motor is of dimension 150 mm square, 20 mm thick and uses SMA wire of 0·4 mm diameter and 125 mm of length in each phase.

  4. Phase diagrams for surface alloys

    DEFF Research Database (Denmark)

    Christensen, Asbjørn; Ruban, Andrei; Stoltze, Per;

    1997-01-01

    We discuss surface alloy phases and their stability based on surface phase diagrams constructed from the surface energy as a function of the surface composition. We show that in the simplest cases of pseudomorphic overlayers there are four generic classes of systems, characterized by the sign...... of the heat of segregation from the bulk and the sign of the excess interactions between the atoms in the surface (the surface mixing energy). We also consider the more complicated cases a with ordered surface phases, nonpseudomorphic overlayers, second layer segregation, and multilayers. The discussion...... is based on density-functional calculations using the coherent-potential approximation and on effective-medium theory. We give self-consistent density-functional results for the segregation energy and surface mixing energy for all combinations of the transition and noble metals. Finally we discuss...

  5. Ageing of zirconium alloy components

    International Nuclear Information System (INIS)

    India has two types (pressurized heavy water reactors (PHWRs) and boiling water reactors (BWRs)) of commercial nuclear reactors in operation, in addition to research reactors. Many of the life limiting critical components in these reactors are fabricated from zirconium alloys. The progressive degradation of these components caused by the cumulative exposure of high energy neutron irradiation with increasing period of reactor operation was monitored to assess the degree of ageing. The components/specimens examined included fuel element claddings removed from BWRs, pressure tubes and garter springs removed from PHWRs and calandria tube specimens used in PHWRs. The tests included tension test (for cladding, garter spring), fracture toughness test (for pressure tube), crush test (for garter spring), and measurement of irradiation induced growth (for calandria tube). Results of various tests conducted are presented and applications of the test results are elaborated for residual life estimation/life extension of the components

  6. Spectrochemical analysis of alloy-800

    International Nuclear Information System (INIS)

    An emission spectrographic method for the determination of seven elements in alloy-800 is described. The metal sample is converted to oxide and a 10 per cent carrier mixture (AgCl+LiF+C) is used for the determination of Al, Co, Cu, Mn, Mo and V. 45mg of this (sample + carrier) mixture is taken in a carrier distillation electrode and excited in a d.c. arc. The concentration ranges of the elements determined varies between 200ppm and 0.8 per cent and the coefficient of variation has been found to be around 15 per cent. For the determination of titanium, the sample oxide is glued to the flat tops of a pair of graphite electrodes and excited with a.c. spark. The concentration range covered is 0.35 to 2.0 per cent and the coefficient of variation is found to be ± 3 per cent. (author). 5 figs., 4 tabs

  7. Environmental Studies on Titanium Aluminide Alloys

    Science.gov (United States)

    Brindley, William J.; Bartolotta, Paul A.; Smialek, James L.; Brady, Michael P.

    2005-01-01

    Titanium aluminides are attractive alternatives to superalloys in moderate temperature applications (600 to 850 C) by virtue of their high strength-to-density ratio (high specific strength). These alloys are also more ductile than competing intermetallic systems. However, most Ti-based alloys tend to degrade through interstitial embrittlement and rapid oxidation during exposure to elevated temperatures. Therefore, their environmental behavior must be thoroughly investigated before they can be developed further. The goals of titanium aluminide environmental studies at the NASA Lewis Research Center are twofold: characterize the degradation mechanisms for advanced structural alloys and determine what means are available to minimize degradation. The studies to date have covered the alpha 2 (Ti3Al), orthorhombic (Ti2AlNb), and gamma (TiAl) classes of alloys.

  8. Processing magnesium alloys by severe plastic deformation

    Science.gov (United States)

    Figueiredo, Roberto B.; Aguilar, Maria Teresa P.; Cetlin, Paulo Roberto; Langdon, Terence G.

    2014-08-01

    The use of severe plastic deformation techniques for processing magnesium alloys has moved from the early difficulties of processing to a stage of tailoring the best properties of these materials. The present paper reviews processing, structure and mechanical properties characterization. It is shown that ultrafine-grained structures are obtained in magnesium alloys processed by multiple passes of Equal-Channel Angular Pressing at moderate temperatures. Ultrafine-grained structures are also obtained by room temperature processing by High- Pressure Torsion. The ultrafine-grained structures increase strength and introduce excellent superplastic capabilities in many magnesium alloys. Moreover, processing magnesium alloys by severe plastic deformation leads to the development of anisotropy in mechanical behavior.

  9. Room temperature creep in metals and alloys

    Energy Technology Data Exchange (ETDEWEB)

    Deibler, Lisa Anne [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States). Materials Characterization and Performance

    2014-09-01

    Time dependent deformation in the form of creep and stress relaxation is not often considered a factor when designing structural alloy parts for use at room temperature. However, creep and stress relaxation do occur at room temperature (0.09-0.21 Tm for alloys in this report) in structural alloys. This report will summarize the available literature on room temperature creep, present creep data collected on various structural alloys, and finally compare the acquired data to equations used in the literature to model creep behavior. Based on evidence from the literature and fitting of various equations, the mechanism which causes room temperature creep is found to include dislocation generation as well as exhaustion.

  10. Ternary alloy nanocatalysts for hydrogen evolution reaction

    Indian Academy of Sciences (India)

    SOUMEN SAHA; SONALIKA VAIDYA; KANDALAM V RAMANUJACHARY; SAMUEL E LOFLAND; ASHOK K GANGULI

    2016-04-01

    Cu–Fe–Ni ternary alloys (size ∼55–80 nm) with varying compositions viz. CuFeNi (A1), CuFe2Ni (A2) and CuFeNi2 (A3) were successfully synthesized using microemulsion. It is to be noted that synthesis of nanocrystallineternary alloys with precise composition is a big challenge which can be overcome by choosing an appropriate microemulsion system. High electrocatalytic activity towards HER in alkaline medium was achieved by the formation of alloys of metals with low and high binding energies. A high value of current density (228 mA cm$^2$) at an overpotential of 545 mV was obtained for CuFeNi (A1), which is significantly high as compared to the previously reported Ni$_{59}$Cu$_{41}$ alloy catalyst.

  11. Printability of alloys for additive manufacturing

    Science.gov (United States)

    Mukherjee, T.; Zuback, J. S.; De, A.; DebRoy, T.

    2016-01-01

    Although additive manufacturing (AM), or three dimensional (3D) printing, provides significant advantages over existing manufacturing techniques, metallic parts produced by AM are susceptible to distortion, lack of fusion defects and compositional changes. Here we show that the printability, or the ability of an alloy to avoid these defects, can be examined by developing and testing appropriate theories. A theoretical scaling analysis is used to test vulnerability of various alloys to thermal distortion. A theoretical kinetic model is used to examine predisposition of different alloys to AM induced compositional changes. A well-tested numerical heat transfer and fluid flow model is used to compare susceptibilities of various alloys to lack of fusion defects. These results are tested and validated with independent experimental data. The findings presented in this paper are aimed at achieving distortion free, compositionally sound and well bonded metallic parts. PMID:26796864

  12. High-entropy alloy: challenges and prospects

    Directory of Open Access Journals (Sweden)

    Y.F. Ye

    2016-07-01

    Full Text Available High-entropy alloys (HEAs are presently of great research interest in materials science and engineering. Unlike conventional alloys, which contain one and rarely two base elements, HEAs comprise multiple principal elements, with the possible number of HEA compositions extending considerably more than conventional alloys. With the advent of HEAs, fundamental issues that challenge the proposed theories, models, and methods for conventional alloys also emerge. Here, we provide a critical review of the recent studies aiming to address the fundamental issues related to phase formation in HEAs. In addition, novel properties of HEAs are also discussed, such as their excellent specific strength, superior mechanical performance at high temperatures, exceptional ductility and fracture toughness at cryogenic temperatures, superparamagnetism, and superconductivity. Due to their considerable structural and functional potential as well as richness of design, HEAs are promising candidates for new applications, which warrants further studies.

  13. NASA-427: A New Aluminum Alloy

    Science.gov (United States)

    Nabors, Sammy A.

    2015-01-01

    NASA's Marshall Space Flight Center researchers have developed a new, stronger aluminum alloy, ideal for cast aluminum products that have powder or paint-baked thermal coatings. With advanced mechanical properties, the NASA-427 alloy shows greater tensile strength and increased ductility, providing substantial improvement in impact toughness. In addition, this alloy improves the thermal coating process by decreasing the time required for heat treatment. With improvements in both strength and processing time, use of the alloy provides reduced materials and production costs, lower product weight, and better product performance. The superior properties of NASA-427 can benefit many industries, including automotive, where it is particularly well-suited for use in aluminum wheels.

  14. Solidification of Al alloys under electromagnetic field

    Institute of Scientific and Technical Information of China (English)

    崔建忠

    2003-01-01

    New theories and technology in the electromagnetic field were put forward about DC casting of Al alloys, including the fundamental research works, I.e, effects of the electromagnetic field on solidus and liquidus, macrosegregation of the main alloying elements, microstructures, content of alloying elements in grains and grain size after solidification under electromagnetic field, and also including a new process-DC casting under low frequency electromagnetic field(LFEMC), which can refine microstructure, eliminate macrosegregation, increase the content of alloying elements within grains, decrease the residual stress, avoid cracks and improve surface quality, and another new process-DC casting under low frequency electromagnetic vibration(LFEVC), which is a high effective method for grain refining.

  15. Stress-corrosion cracking of titanium alloys.

    Science.gov (United States)

    Blackburn, M. J.; Feeney, J. A.; Beck, T. R.

    1973-01-01

    In the light of research material published up to May 1970, the current understanding of the experimental variables involved in the stress-corrosion cracking (SCC) behavior of titanium and its alloys is reviewed. Following a brief summary of the metallurgy and electrochemistry of titanium alloys, the mechanical, electrochemical, and metallurgical parameters influencing SCC behavior are explored with emphasis on crack growth kinetics. Macro- and microfeatures of fractures are examined, and it is shown that many transgranular SCC failures exhibit morphological and crystallographic features similar to mechanical cleavage failures. Current SCC models are reviewed with respect to their ability to explain the observed SCC behavior of titanium and its alloys. Possible methods for eliminating or minimizing stress corrosion hazards in titanium or titanium alloy components are described.

  16. On Silicides in High Temperature Titanium Alloys

    Directory of Open Access Journals (Sweden)

    C. Ramachandra

    1986-04-01

    Full Text Available High temperature titanium alloys like IMI 685 contain small amounts of silicon (~ 0.25 wt. per cent to improve creep resistance. Different types of silicides, namely Ti5Si3 (TiZr5Si3(S1 and (TiZr6 Si3 (S2, have been observed to precipitate in various silicon-bearing titanium alloys depending upon their composition and heat treatment. The precipitation of silicides, their orientation relationship with the matrix in different alloys, and the beneficial influence of thermo-mechanical treatment on the distribution of silicides have been pointed out. The effect of silicides on mechanical properties and fracture of the commercial alloy IMI 685 is also indicated.

  17. Simulation of nuclei morphologies for binary alloy

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    We study the critical nuclei morphologies of a binary alloy by the string method. The dynamic equation of the string, connecting the metastable phase (liquid) and stable phase (solid), is governed by Helmholtz free energy for the binary alloy system at a given temperature. The stationary string through the critical nucleus (saddle point) is obtained if the relaxation time of the string is su?ciently large. The critical nucleus radius and energy barrier to nucleation of a pure alloy with isotropic interface energy in two and three dimensions are calculated, which are consistent with the classical nucleation theory. The critical nuclei morphologies are sensitive to the anisotropy strength of interface energy and interface thickness of alloy in two and three dimensions. The critical nucleus and energy barrier to nucleation become smaller if the anisotropy strength of the interface energy is increased, which means that it is much easier to form a stable nucleus if the anisotropy of the interface energy is considered.

  18. Vertical solidification of dendritic binary alloys

    Science.gov (United States)

    Heinrich, J. C.; Felicelli, S.; Poirier, D. R.

    1991-01-01

    Three numerical techniques are employed to analyze the influence of thermosolutal convection on defect formation in directionally solidified (DS) alloys. The finite-element models are based on the Boussinesq approximation and include the plane-front model and two plane-front models incorporating special dendritic regions. In the second model the dendritic region has a time-independent volume fraction of liquid, and in the last model the dendritic region evolves as local conditions dictate. The finite-element models permit the description of nonlinear thermosolutal convection by treating the dendritic regions as porous media with variable porosities. The models are applied to lead-tin alloys including DS alloys, and severe segregation phenomena such as freckles and channels are found to develop in the DS alloys. The present calculations and the permeability functions selected are shown to predict behavior in the dendritic regions that qualitatively matches that observed experimentally.

  19. High hardness of alloyed ferrite after nitriding

    International Nuclear Information System (INIS)

    Detailed layer-by layer structure and phase analyses of the diffusion layer of nitrided binary alloys of iron with aluminium, chromium, vanadium and titanium have been carried out by means of a complex technique. Transition d-metals (chromium, vanadium and titanium) raise to a greater degree the solubility of nitrogen in the α solid solution, sharply increases the hardness of ferrite and decrease the depth of the layer. Nitrided binary alloys of iron with chromium, vanadium and titanium are strengthened through precipitation from the nitrogen-saturated α-solid solution of nitrides of alloying elements TiN, VN and CrN of a structure B1. A maximum hardness of ferrite alloyed by chromium, vanadium and titanium is observed after nitriding at 550 deg C when the precipitated special nitrides are fully coherent with the α matrix

  20. Characteristics on Bi-Pb Based Alloys Quenched from Melt

    Institute of Scientific and Technical Information of China (English)

    Rizk Mostafa Shalaby

    2009-01-01

    Three different bismuth-lead systems namely, Wood's alloy (Bi50Pb25Sn12.5Cd12.5), Newton's alloy (Bi50Pb31.2Sn18.8) and Rose's alloy (Bi50Pb28Sn22), with one used as fusible alloys were quenched from melt by melt spinning technique. Thermal analysis, structure and mechanical properties of all alloys have been studied and analyzed. From X-ray diffraction analysis, an intermetallic compound phase, designated Pb7Bi3 is detected. The formation of an intermetallic compound phase causes a pronounced increase in the electrical resistivity. The Wood's alloy containing-cadmium exhibits mechanical properties superior to both the Newton's and Rose's alloys. The presence of cadmium in Wood's alloy decreases its melting point. Wood's alloy has better properties, which make it useful in various applications such as in protection shields for radiotherapy, locking of mechanical devices and welding at low temperature.

  1. Novel Directional Solidification Processing of Hypermonotectic Alloys

    Science.gov (United States)

    Kaukler, William; Fedoseyev, Alex

    2002-01-01

    A model has been developed that determines the size of Liquid (sub 11) droplets generated during application of ultrasonic energy (as a function of amplitude) to immiscible alloys. The initial results are in accordance with experimental results based on Succinonitrile - Glycerol "alloys" and pure tin dispersions. Future work will take into account the importance of other effects, e.g., thermo-vibrational convection, sound attenuation, viscosity variations, and compositional changes.

  2. Microstructure of hydroextruded niobium alloy NTs-1

    International Nuclear Information System (INIS)

    Comparative analysis of microstructure of niobium alloy NTs-1 rods, produced by hydroextrusion ad hot pressing, has been carried out. It is established, that cold hydroextrusion of electron-beam melted ingots of the alloy NTs-1, permits to attain a more heterogeneous structure in semifinished products, as compared with hot pressing. Considerable (up to 90%) deformation degree, resulting in the lowest grain heterogeneity in metal, should be used

  3. Microstructure of undercooled Pb-Sn alloys

    OpenAIRE

    Castro Walman Benício de; Maia Manuel de Lucena; Kiminami Claudio Shyinti; Bolfarini Claudemiro

    2001-01-01

    Melt undercooling opens new solidification pathways for non-equilibrium phases and non-conventional microstructures. Several techniques, including the fluxing technique, have been developed in order to reduce nucleation sites and to produce high undercoolings for metals and alloys. In this work the fluxing technique was applied to Pb-25wt%Sn (hypoeutectic), Pb-61.9wt%Sn (eutectic) and Pb-90wt%Sn (hypereutectic) alloys to investigate the influence of the undercooling on the microstructure of t...

  4. Mechanical properties of tantalum-niobium alloys

    Energy Technology Data Exchange (ETDEWEB)

    Chamdawalla, N; Ettmayer, P.; Femboeck, J.; Aschenbrenner, W.; Bildstein, H.

    1986-02-01

    Young's modulus and shear modulus have been measured on fully dense polycrystalline sintered (swaged and forged and recrystallized) tantalum-niobium alloys. Young's modulus decreases steadily and monotonously from pure tantalum to pure niobium. Ultimate tensile strength values have been measured at 6 different temperatures between 20 and 1500/sup 0/ C. No significant solution hardening effect could be observed. Room temperature and hot hardness of the alloys were evaluated. (orig.).

  5. Manufacturing development of low activation vanadium alloys

    International Nuclear Information System (INIS)

    General Atomics is developing manufacturing methods for vanadium alloys as part of a program to encourage the development of low activation alloys for fusion use. The culmination of the program is the fabrication and installation of a vanadium alloy structure in the DIII-D tokamak as part of the Radiative Divertor modification. Water-cooled vanadium alloy components will comprise a portion of the new upper divertor structure. The first step, procuring the material for this program has been completed. The largest heat of vanadium alloy made to date, 1200 kg of V-4Cr-4Ti, has been produced and is being converted into various product forms. Results of many tests on the material during the manufacturing process are reported. Research into potential fabrication methods has been and continues to be performed along with the assessment of manufacturing processes particularly in the area of joining. Joining of vanadium alloys has been identified as the most critical fabrication issue for their use in the Radiative Divertor Program. Joining processes under evaluation include resistance seam, electrodischarge (stud), friction and electron beam welding. Results of welding tests are reported. Metallography and mechanical tests are used to evaluate the weld samples. The need for a protective atmosphere during different welding processes is also being determined. General Atomics has also designed, manufactured, and will be testing a helium-cooled, high heat flux component to assess the use of helium cooled vanadium alloy components for advanced tokamak systems. The component is made from vanadium alloy tubing, machined to enhance the heat transfer characteristics, and joined to end flanges to allow connection to the helium supply. Results are reported

  6. Electrical resistivity of liquid noble metal alloys

    International Nuclear Information System (INIS)

    Calculations of the dependence of the electrical resistivity in liquid Ag-Au, Cu-Ag, Cu-Au binary alloys on composition are reported. The structure of the binary alloy is described as a hard sphere system. A one-parameter local pseudopotential, which incorporates s-d hybridization effects phenomenologically, is employed in the resistivity calculation. A reasonable agreement with experimental trends is observed in cases where experimental information is available. (author)

  7. Electrical Conductivity of Aluminium Alloy Foams

    Institute of Scientific and Technical Information of China (English)

    凤仪; 郑海务; 朱震刚; 祖方遒

    2002-01-01

    Closed-cell aluminium alloy foams were produced using the powder metallurgical technique. The effect of porosityand cell diameter on the electrical conductivity of foams was investigated and the results were compared with anumber of models. It was found that the percolation theory can be successfully applied to describe the dependenceof the electrical conductivity of aluminium alloy foams on the relative density. The cell diameter has a negligibleeffect on the electrical conductivity of foams.

  8. Lightweight Protective Coatings For Titanium Alloys

    Science.gov (United States)

    Wiedemann, Karl E.; Taylor, Patrick J.; Clark, Ronald K.

    1992-01-01

    Lightweight coating developed to protect titanium and titanium aluminide alloys and titanium-matrix composite materials from attack by environment when used at high temperatures. Applied by sol-gel methods, and thickness less than 5 micrometers. Reaction-barrier and self-healing diffusion-barrier layers combine to protect titanium alloy against chemical attack by oxygen and nitrogen at high temperatures with very promising results. Can be extended to protection of other environmentally sensitive materials.

  9. Titanium and titanium alloys fundamentals and applications

    CERN Document Server

    Peters, Manfred

    2003-01-01

    This handbook is an excellent reference for materials scientists and engineers needing to gain more knowledge about these engineering materials. Following introductory chapters on the fundamental materials properties of titanium, readers will find comprehensive descriptions of the development, processing and properties of modern titanium alloys. There then follows detailed discussion of the applications of titanium and its alloys in aerospace, medicine, energy and automotive technology.

  10. High damping indium-tin alloys

    OpenAIRE

    Dooris, A.; Lakes, Roderick S.; Myers, B.; Stephens, N

    2015-01-01

    This research is directed toward the development of materials of high stiffness and high mechanical damping for the purpose of damping vibrations instructures and machinery. To this end, indium-tin alloys are considered. Cast In-Sn exhibits substantial damping for a metal. Quenching substantially improved the damping of indium-tin alloy but the effect gradually disappeared due to aging. Cold work of 1.3% permanent shear strain had the effect of moderately increasing the damping of indium-tin,...

  11. Refining processes of selected copper alloys

    OpenAIRE

    S. Rzadkosz; Kranz, M; P. Nowicki; M. Piekos

    2009-01-01

    The analysis of the refining effectiveness of the liquid copper and selected copper alloys by various micro additions and special refiningsubstances – was performed. Examinations of an influence of purifying, modifying and deoxidation operations performed in a metal bath on the properties of certain selected alloys based on copper matrix - were made. Refining substances, protecting-purifying slag, deoxidation and modifying substances containing micro additions of such elements as: zirconium, ...

  12. LASER CLADDING ON ALUMINIUM BASE ALLOYS

    OpenAIRE

    Pilloz, M.; Pelletier, J; Vannes, A.; Bignonnet, A.

    1991-01-01

    laser cladding is often performed on iron or titanium base alloys. In the present work, this method is employed on aluminum alloys ; nickel or silicon are added by powder injection. Addition of silicon leads to sound surface layers, but with moderated properties, while the presence of nickel induces the formation of hard intermetallic compounds and then to an attractive hardening phenomena ; however a recovery treatment has to be carried out, in order to eliminate porosity in the near surface...

  13. Oxidation of alloys for advanced steam turbines

    Energy Technology Data Exchange (ETDEWEB)

    Holcomb, Gordon R.; Covino, Bernard S., Jr.; Bullard, Sophie J.; Ziomek-Moroz, M.; Alman, David E.

    2005-01-01

    Ultra supercritical (USC) power plants offer the promise of higher efficiencies and lower emissions. Current goals of the U.S. Department of Energy’s Advanced Power Systems Initiatives include coal generation at 60% efficiency, which would require steam temperatures of up to 760°C. This research examines the steamside oxidation of advanced alloys for use in USC systems, with emphasis placed on alloys for high- and intermediate-pressure turbine sections.

  14. Oxidation of advanced steam turbine alloys

    Energy Technology Data Exchange (ETDEWEB)

    Holcomb, G.R.; Covino, B.S., Jr.; Bullard, S.J.; Ziomek-Moroz, M.

    2006-03-01

    Advanced or ultra supercritical (USC) steam power plants offer the promise of higher efficiencies and lower emissions. Current goals of the U.S. Department of Energy’s Advanced Power Systems Initiatives include coal generation at 60% efficiency, which would require steam temperatures of up to 760°C. This research examines the steamside oxidation of advanced alloys for use in USC systems, with emphasis placed on alloys for high- and intermediate-pressure turbine sections.

  15. Production of weldments from sintered titanium alloys

    OpenAIRE

    Kapustyan, A. YE.; A. V. Ovchinnikov; Vakulenko, I. A.

    2014-01-01

    Purpose. Limited application of details from powder titanium alloys is connected with the difficulties in obtaining of long-length blanks, details of complex shape and large size. We can solve these problems by applying the welding production technology. For this it is necessary to conduct a research of the structure and mechanical properties of welded joints of sintered titanium alloys produced by flash welding. Methodology. Titanium industrial powders, type PT5-1 were used as original subst...

  16. PRODUCTION OF WELDMENTS FROM SINTERED TITANIUM ALLOYS

    OpenAIRE

    A. YE. Kapustyan; A. V. Ovchinnikov; Vakulenko, I. A.

    2014-01-01

    Purpose. Limited application of details from powder titanium alloys is connected with the difficulties in obtaining of long-length blanks, details of complex shape and large size. We can solve these problems by applying the welding production technology. For this it is necessary to conduct a research of the structure and mechanical properties of welded joints of sintered titanium alloys produced by flash welding. Methodology. Titanium industrial powders, type PT5-1 were used as original subst...

  17. Structure changes and mechanical properties of laser alloyed magnesium cast alloys

    Directory of Open Access Journals (Sweden)

    W. Kwaśny

    2009-02-01

    Full Text Available Purpose: The aim of this work was to investigate structure and mechanical properties of the MCMgAl12Zn1 casting magnesium alloys after laser treatment. The laser treatment was carried out using a high power diode laser (HPDL.Design/methodology/approach: The laser processing of TiC, WC, SiC particles in MCMgAl12Zn1 and the resulted microstructures and properties are discussed in this paper. The resulting microstructure in the modified surface layer was examined. Phase composition was determined by the X-ray diffraction method using XPert device. The measurements of hardness after laser melt injection was also studied.Findings: Structure of the solidyifying material after laser alloying is characteristic with occurrences of areas with the diversified morphology, dependent on solidification rate of the magnesium alloys, is characteristic of structure of the solidified material after laser alloying. The MCMgAl12Zn1 casting magnesium alloys after laser alloying demonstrate similar hardness tests results, in reference to hardness of the alloys before their laser treatment.Research limitations/implications: In this research three powders (titanium carbide, tungsten carbide and silicon carbide were used to reinforcing the surface of the MCMgAl12Zn1 casting magnesium alloys.Practical implications: High power diode laser can be used as an economical substitute for CO2 and Nd:YAG lasers to modify the surface magnesium alloy by feeding the carbide particles.Originality/value: The originality of this work is applying of High Power Diode Laser for laser treatment of cast magnesium alloy consisting in fusion penetration of the hard particles of titanium, tungsten, and silicon carbides into the remelted surface layer of the alloy.

  18. Nanoprecipitation in a beta-titanium alloy

    International Nuclear Information System (INIS)

    Highlights: • In-situ SANS has been applied to study precipitation in β -Ti alloy. • Rate of precipitation is far more rapid in the cold-rolled alloy than non cold-rolled. • The rapid precipitation dramatically improves the alloy hardness. • Extensive ω phase is present after 400 °C/16 h heat-treatment. • SANS modelling and TEM-EDX shows the precipitates are Ti rich. - Abstract: This paper represents the first application of small angle neutron scattering (SANS) to the study of precipitate nucleation and growth in β-Ti alloys in an attempt to observe both the precipitation process in-situ and to quantify the evolving microstructure that affects mechanical behaviour. TEM suggests that athermal ω can be induced by cold-rolling Gum metal, a β-Ti alloy. During thermal exposure at 400°C, isothermal ω particles precipitate at a greater rate in cold-rolled material than in the recovered, hot deformed state. SANS modelling is consistent with disc shaped nanoparticles, with length and radius under 6nm after thermal exposures up to 16h. Modelling suggests that the nanoprecipitate volume fraction and extent of Nb partitioning to the β matrix is greater in the cold-rolled material than the extruded. The results show that nucleation and growth of the nanoprecipitates impart strengthening to the alloy

  19. Hydrogen storage systems from waste Mg alloys

    Science.gov (United States)

    Pistidda, C.; Bergemann, N.; Wurr, J.; Rzeszutek, A.; Møller, K. T.; Hansen, B. R. S.; Garroni, S.; Horstmann, C.; Milanese, C.; Girella, A.; Metz, O.; Taube, K.; Jensen, T. R.; Thomas, D.; Liermann, H. P.; Klassen, T.; Dornheim, M.

    2014-12-01

    The production cost of materials for hydrogen storage is one of the major issues to be addressed in order to consider them suitable for large scale applications. In the last decades several authors reported on the hydrogen sorption properties of Mg and Mg-based systems. In this work magnesium industrial wastes of AZ91 alloy and Mg-10 wt.% Gd alloy are used for the production of hydrogen storage materials. The hydrogen sorption properties of the alloys were investigated by means of volumetric technique, in situ synchrotron radiation powder X-ray diffraction (SR-PXD) and calorimetric methods. The measured reversible hydrogen storage capacity for the alloys AZ91 and Mg-10 wt.% Gd are 4.2 and 5.8 wt.%, respectively. For the Mg-10 wt.% Gd alloy, the hydrogenated product was also successfully used as starting reactant for the synthesis of Mg(NH2)2 and as MgH2 substitute in the Reactive Hydride Composite (RHC) 2LiBH4 + MgH2. The results of this work demonstrate the concrete possibility to use Mg alloy wastes for hydrogen storage purposes.

  20. Nanoprecipitation in a beta-titanium alloy

    Energy Technology Data Exchange (ETDEWEB)

    Coakley, James, E-mail: j.coakley06@imperial.ac.uk [Department of Materials, Imperial College, South Kensington, London SW7 2AZ, England (United Kingdom); Vorontsov, Vassili A. [Department of Materials, Imperial College, South Kensington, London SW7 2AZ, England (United Kingdom); Littrell, Kenneth C. [Oak Ridge National Laboratory, Chemical and Engineering Materials Division, Oak Ridge, TN 37831 (United States); Heenan, Richard K. [Rutherford Appleton Laboratory, Didcot, Oxon OX11 0QX, England (United Kingdom); Ohnuma, Masato [Laboratory of Quantum Beam System Engineering, Hokkaido University, Sapporo 060-0808 (Japan); Jones, Nicholas G. [Department of Materials Science and Metallurgy, University of Cambridge, Cambridge CB2 3QZ, England (United Kingdom); Dye, David [Department of Materials, Imperial College, South Kensington, London SW7 2AZ, England (United Kingdom)

    2015-02-25

    Highlights: • In-situ SANS has been applied to study precipitation in β -Ti alloy. • Rate of precipitation is far more rapid in the cold-rolled alloy than non cold-rolled. • The rapid precipitation dramatically improves the alloy hardness. • Extensive ω phase is present after 400 °C/16 h heat-treatment. • SANS modelling and TEM-EDX shows the precipitates are Ti rich. - Abstract: This paper represents the first application of small angle neutron scattering (SANS) to the study of precipitate nucleation and growth in β-Ti alloys in an attempt to observe both the precipitation process in-situ and to quantify the evolving microstructure that affects mechanical behaviour. TEM suggests that athermal ω can be induced by cold-rolling Gum metal, a β-Ti alloy. During thermal exposure at 400°C, isothermal ω particles precipitate at a greater rate in cold-rolled material than in the recovered, hot deformed state. SANS modelling is consistent with disc shaped nanoparticles, with length and radius under 6nm after thermal exposures up to 16h. Modelling suggests that the nanoprecipitate volume fraction and extent of Nb partitioning to the β matrix is greater in the cold-rolled material than the extruded. The results show that nucleation and growth of the nanoprecipitates impart strengthening to the alloy.

  1. Initial cytotoxicity of novel titanium alloys.

    Science.gov (United States)

    Koike, M; Lockwood, P E; Wataha, J C; Okabe, T

    2007-11-01

    We assessed the biological response to several novel titanium alloys that have promising physical properties for biomedical applications. Four commercial titanium alloys [Super-TIX(R) 800, Super-TIX(R) 51AF, TIMETAL(R) 21SRx, and Ti-6Al-4V (ASTM grade 5)] and three experimental titanium alloys [Ti-13Cr-3Cu, Ti-1.5Si and Ti-1.5Si-5Cu] were tested. Specimens (n = 6; 5.0 x 5.0 x 3.0 mm(3)) were cast in a centrifugal casting machine using a MgO-based investment and polished to 600 grit, removing 250 mum from each surface. Commercially pure titanium (CP Ti: ASTM grade 2) and Teflon (polytetrafluoroethylene) were used as positive controls. The specimens were cleaned and disinfected, and then each cleaned specimen was placed in direct contact with Balb/c 3T3 fibroblasts for 72 h. The cytotoxicity [succinic dehydrogenase (SDH) activity] of the extracts was assessed using the MTT method. Cytotoxicity of the metals tested was not statistically different compared to the CP Ti and Teflon controls (p > 0.05). These novel titanium alloys pose cytotoxic risks no greater than many other commonly used alloys, including commercially pure titanium. The promising short-term biocompatibility of these Ti alloys is probably due to their excellent corrosion resistance under static conditions, even in biological environments. PMID:17385227

  2. Crystallization of amorphous Zr-Be alloys

    Science.gov (United States)

    Golovkova, E. A.; Surkov, A. V.; Syrykh, G. F.

    2015-02-01

    The thermal stability and structure of binary amorphous Zr100 - x Be x alloys have been studied using differential scanning calorimetry and neutron diffraction over a wide concentration range (30 ≤ x ≤ 65). The amorphous alloys have been prepared by rapid quenching from melt. The studied amorphous system involves the composition range around the eutectic composition with boundary phases α-Zr and ZrBe2. It has been found that the crystallization of alloys with low beryllium contents ("hypoeutectic" alloys with x ≤ 40) proceeds in two stages. Neutron diffraction has demonstrated that, at the first stage, α-Zr crystallizes and the remaining amorphous phase is enriched to the eutectic composition; at the second stage, the alloy crystallizes in the α-Zr and ZrBe2 phases. At higher beryllium contents ("hypereutectic" alloys), one phase transition of the amorphous phase to a mixture of the α-Zr and ZrBe2 phases has been observed. The concentration dependences of the crystallization temperature and activation energy have been revealed.

  3. Point-charge electrostatics in disordered alloys

    CERN Document Server

    Wolverton, C; Froyen, S; Wei, S H; Zunger, Alex

    1996-01-01

    A simple analytic model of point-ion electrostatics has been previously proposed in which the magnitude of the net charge q_i on each atom in an ordered or random alloy depends linearly on the number N_i^(1) of unlike neighbors in its first coordination shell. Point charges extracted from recent large supercell (256-432 atom) local density approximation (LDA) calculations of Cu-Zn random alloys now enable an assessment of the physical validity and accuracy of the simple model. We find that this model accurately describes (i) the trends in q_i vs. N_i^(1), particularly for fcc alloys, (ii) the magnitudes of total electrostatic energies in random alloys, (iii) the relationships between constant-occupation-averaged charges and Coulomb shifts (i.e., the average over all sites occupied by either $A$ or $B$ atoms) in the random alloy, and (iv) the linear relation between the site charge q_i and the constant- charge-averaged Coulomb shift (i.e., the average over all sites with the same charge) for fcc alloys. Howe...

  4. Development of Advanced Alloys using Fullerenes

    Science.gov (United States)

    Sims, J.; Wasz, M.; O'Brien, J.; Callahan, D. L.; Barrera, E. V.

    1994-01-01

    Development of advanced alloys using fullerenes is currently underway to produce materials for use in the extravehicular mobility unit (EMU). These materials will be directed toward commercial usages as they are continually developed. Fullerenes (of which the most common is C(sub 60)) are lightweight, nanometer size, hollow molecules of carbon which can be dispersed in conventional alloy systems to enhance strength and reduce weight. In this research, fullerene interaction with aluminum is investigated and a fullerene-reinforced aluminum alloy is being developed for possible use on the EMU. The samples were manufactured using standard commercial approaches including powder metallurgy and casting. Alloys have been processed having 1.3, 4.0 and 8.0 volume fractions of fullerenes. It has been observed that fullerene dispersion is related to the processing approach and that they are stable for the processing conditions used in this research. Emphasis will be given to differential thermal analysis and wavelength dispersive analysis of the processed alloys. These two techniques are particularly useful in determining the condition of the fullerenes during and after processing. Some discussion will be given as to electrical properties of fullerene-reinforced materials. Although the aluminum and other advanced alloys with fullerenes are being developed for NASA and the EMU, the properties of these materials will be of interest for commercial applications where specific Dual-Use will be given.

  5. Biocorrosion study of titanium-cobalt alloys.

    Science.gov (United States)

    Chern Lin, J H; Lo, S J; Ju, C P

    1995-05-01

    The present work provides experimental results of corrosion behaviour in Hank's physiological solution and some other properties of in-house fabricated titanium-cobalt alloys with cobalt ranging from 25-30% in weight. X-ray diffraction (XRD) shows that, in water-quenched (WQ) alloys, beta-titanium is largely retained, whereas in furnace-cooled (FC) alloys, little beta-titanium is found. Hardness of the alloys increases with increasing cobalt content, ranging from 455 VHN for WQ Ti-25 wt% Co to 525 VHN for WQ Ti-30 wt% Co. Differential thermal analysis (DTA) indicates that melting temperatures of the alloys are lower than that of pure titanium by about 600 degrees C. Potentiodynamic polarization results show that all measured break-down potentials in Hank's solution at 37 degrees C are higher than 800 mV. The breakdown potential for the FC Ti-25 Wt% Co alloy is even as high as nearly 1200 mV.

  6. Initial cytotoxicity of novel titanium alloys.

    Science.gov (United States)

    Koike, M; Lockwood, P E; Wataha, J C; Okabe, T

    2007-11-01

    We assessed the biological response to several novel titanium alloys that have promising physical properties for biomedical applications. Four commercial titanium alloys [Super-TIX(R) 800, Super-TIX(R) 51AF, TIMETAL(R) 21SRx, and Ti-6Al-4V (ASTM grade 5)] and three experimental titanium alloys [Ti-13Cr-3Cu, Ti-1.5Si and Ti-1.5Si-5Cu] were tested. Specimens (n = 6; 5.0 x 5.0 x 3.0 mm(3)) were cast in a centrifugal casting machine using a MgO-based investment and polished to 600 grit, removing 250 mum from each surface. Commercially pure titanium (CP Ti: ASTM grade 2) and Teflon (polytetrafluoroethylene) were used as positive controls. The specimens were cleaned and disinfected, and then each cleaned specimen was placed in direct contact with Balb/c 3T3 fibroblasts for 72 h. The cytotoxicity [succinic dehydrogenase (SDH) activity] of the extracts was assessed using the MTT method. Cytotoxicity of the metals tested was not statistically different compared to the CP Ti and Teflon controls (p > 0.05). These novel titanium alloys pose cytotoxic risks no greater than many other commonly used alloys, including commercially pure titanium. The promising short-term biocompatibility of these Ti alloys is probably due to their excellent corrosion resistance under static conditions, even in biological environments.

  7. An Analysis of Selected Properties of ZA Alloys

    Science.gov (United States)

    Gervais, E.; Barnhurst, R. J.; Loong, C. A.

    1985-11-01

    Zinc-aluminum (ZA) alloys are a relatively new family of zinc foundry alloys having superior melting and casting characteristics and attractive mechanical properties. The ZA-8 and ZA-12 alloys are moderate to high strength materials while ZA-27 is a high-strength alloy. All can be sand cast, permanent molded and pressure die cast. An extensive characterization program is being implemented to develop appropriate and reliable engineering data for designers. Property development in all aspects of ZA metallurgy is welladvanced. The data available on selected physical and mechanical properties of ZA alloys is compared here with the properties of traditional casting alloys.

  8. Study of fatigue behaviour of 7475 aluminium alloy

    Indian Academy of Sciences (India)

    B B Verma; J D Atkinson; M Kumar

    2001-04-01

    Fatigue properties of a thermomechanically treated 7475 aluminium alloy have been studied in the present investigation. The alloy exhibited superior fatigue life compared to conventional structural aluminium alloys and comparable stage II crack growth rate. It was also noticed that the fatigue crack initiated from a surface grain and the crack extension was dominated by ductile striations. Analysis also revealed that this alloy possessed fracture toughness and tensile properties superior to that noticed with other structural aluminium alloys. Therefore the use of this alloy can safely reduce the overall weight of the aircraft.

  9. Corrosion Behavior of Au, Hastelloy C-276 Alloy and Monel 400 Alloy in Molten Lithium Fluoride

    Institute of Scientific and Technical Information of China (English)

    WANG; Chang-shui; GUO; Jun-kang

    2013-01-01

    For searching better corrosion-resistant material in high temperature,we investigated the corrosion behavior of Au,Haynes C-276 alloy and Monel 400 alloy in molten lithium fluoride at 950℃.The corrosion products and fine structures of the corroded specimens were characterized by inductively coupled plasma mass spectrometry(ICP-MS),scanning electron microscope(SEM),energy dispersive

  10. AN ELECTROPLATING METHOD OF FORMING PLATINGS OF NICKEL, COBALT, NICKEL ALLOYS OR COBALT ALLOYS

    DEFF Research Database (Denmark)

    1997-01-01

    An electroplating method of forming platings of nickel, cobalt, nickel alloys or cobalt alloys with reduced stresses in an electrodepositing bath of the type: Watt's bath, chloride bath or a combination thereof, by employing pulse plating with periodic reverse pulse and a sulfonated naphthalene...... additive. This method makes it possible to deposit nickel, cobalt, nickel or cobalt platings without internal stresses....

  11. Study on microstructure and properties of Mg-alloy surface alloying layer fabricated by EPC

    Directory of Open Access Journals (Sweden)

    Chen Dongfeng

    2010-02-01

    Full Text Available AZ91D surface alloying was investigated through evaporative pattern casting (EPC technology. Aluminum powder (0.074 to 0.104 mm was used as the alloying element in the experiment. An alloying coating with excellent properties was fabricated, which mainly consisted of adhesive, co-solvent, suspending agent and other ingredients according to desired proportion. Mg-alloy melt was poured under certain temperature and the degree of negative pressure. The microstructure of the surface layer was examined by means of scanning electron microscopy. It has been found that a large volume fraction of network new phases were formed on the Mg-alloy surface, the thickness of the alloying surface layer increased with the alloying coating increasing from 0.3 mm to 0.5 mm, and the microstructure became compact. Energy dispersive X-ray (EDX analysis was used to determine the chemical composition of the new phases. It showed that the new phases mainly consist of β-Mg17Al12, in addition to a small quantity of inter-metallic compounds and oxides. A micro-hardness test and a corrosion experiment to simulate the effect of sea water were performed. The result indicated that the highest micro-hardness of the surface reaches three times that of the matrix. The corrosion rate of alloying samples declines to about a fifth of that of the as-cast AZ91D specimen.

  12. Bond strength of gold alloys laser welded to cobalt-chromium alloy.

    Science.gov (United States)

    Watanabe, Ikuya; Wallace, Cameron

    2008-01-01

    The objective of this study was to investigate the joint properties between cast gold alloys and Co-Cr alloy laser-welded by Nd:YAG laser. Cast plates were fabricated from three types of gold alloys (Type IV, Type II and low-gold) and a Co-Cr alloy. Each gold alloy was laser-welded to Co-Cr using a dental laser-welding machine. Homogeneously-welded and non-welded control specimens were also prepared. Tensile testing was conducted and data were statistically analyzed using ANOVA. The homogeneously-welded groups showed inferior fracture load compared to corresponding control groups, except for Co-Cr. In the specimens welded heterogeneously to Co-Cr, Type IV was the greatest, followed by low-gold and Type II. There was no statistical difference (Pcontrol and that welded to Co-Cr. Higher elongations were obtained for Type II in all conditions, whereas the lowest elongation occurred for low-gold welded to Co-Cr. This study indicated that, of the three gold alloys tested, the Type IV gold alloy was the most suitable alloy for laser-welding to Co-Cr. PMID:19088892

  13. Oxidation resistant coating for titanium alloys and titanium alloy matrix composites

    Science.gov (United States)

    Brindley, William J. (Inventor); Smialek, James L. (Inventor); Rouge, Carl J. (Inventor)

    1992-01-01

    An oxidation resistant coating for titanium alloys and titanium alloy matrix composites comprises an MCrAlX material. M is a metal selected from nickel, cobalt, and iron. X is an active element selected from Y, Yb, Zr, and Hf.

  14. Effect of alloying addition and microstructural parameters on mechanical properties of 93% tungsten heavy alloys

    Energy Technology Data Exchange (ETDEWEB)

    Ravi Kiran, U., E-mail: uravikiran@gmail.com [Defence Metallurgical Research Laboratory, Kanchanbagh, Hyderabad 500 058 (India); Panchal, A.; Sankaranarayana, M. [Defence Metallurgical Research Laboratory, Kanchanbagh, Hyderabad 500 058 (India); Nageswara Rao, G.V.S. [National Institute of Technology, Warangal 506004 (India); Nandy, T.K. [Defence Metallurgical Research Laboratory, Kanchanbagh, Hyderabad 500 058 (India)

    2015-07-29

    Liquid phase sintering, heat treatment and swaging studies on three tungsten heavy alloys, 93W–4.9Ni–2.1Fe (wt%), 93W–4.2Ni–1.2Fe–1.6Co (wt%) and 93W–4.9Ni–1.9Fe–0.2Re (wt%) were carried out in detail with respect to microstructure, tensile and impact properties. All the alloys were sintered and swaged to 40% deformation. The results indicate that Re addition reduces the grain size of the alloy compared to W–Ni–Fe and W-Ni-Fe-Co alloys. W–Ni–Fe–Re alloy shows superior tensile properties in heat treated condition as compared to W–Ni–Fe and W–Ni–Fe–Co alloys. SEM study of fractured specimens clearly indicates that the failure in case of W–Ni–Fe–Re was due to transgranular cleavage of tungsten grains and W–W de-cohesion. W–Ni–Fe and W–Ni–Fe–Co alloys also failed by mixed mode failure. However, in these cases, ductile dimples corresponding the failure of the matrix phase was rarely seen. Thermo-mechanical processing resulted in significant changes in mechanical properties. While W–Ni–Fe–Re alloy showed the highest tensile strength (1380 MPa), W–Ni–Fe–Co exhibited the highest elongation (12%) to failure. A detailed analysis involving microstructure, mechanical properties and failure behavior was undertaken in order to understand the property trends.

  15. Effect of alloy elements on the anti-corrosion properties of low alloy steel

    Indian Academy of Sciences (India)

    Baorong Hou; Yantao Li; Yanxu Li; Jinglei Zhang

    2000-06-01

    Effect of alloy elements on corrosion of low alloy steel was studied under simulated offshore conditions. The results showed that the elements Cu, P, Mo, W, V had evident effect on corrosion resistance in the atmosphere zone; Cu, P, V, Mo in the splash zone and Cr, Al, Mo in the submerged zone.

  16. Densities of Some Low Melting Plutonium Alloys

    International Nuclear Information System (INIS)

    The change in fuel density with temperature is an important parameter in nuclear reactor design. For molten fuels, such as are used in LAMPRE-type reactor it is also necessary to know the volume change on melting. A volumeter employing NaK as a working fluid was used to obtain'these data for various plutonium and cerium base alloys over the range 25-800°C. Cerium and several low-melting binary cerium alloys were studied with this equipment. Cerium, Ce-Co, Ce-Ni, and Ce-Cu alloys all exhibit an increase in density on melting, while a Ce-Mn alloy expands on melting. The melting temperatures of several of these alloys differ from those reported in the literature, and the compositions of several eutectics in these systems are also reported incorrectly. The densities of unstabilized and gallium- stabilized plutonium and Pu-10 at.% Fe were measured and compared over this temperature range. All these materials expand on freezing. At 675°C, molten unstabilized plutonium is approximately 2% more dense than Pu-l wt.% Ga alloy. Molten Pu-Fe alloy containing 0.2 wt.% Ga at 435°C is 0.8% less dense than unstabilized alloy. This indicates that there is short-range ordering of plutonium atoms by gallium in the liquid state. The materials containing gallium melted over a 20°C temperature range, while the unstabilized materials melted sharply. Pu-Co-Ce alloys containing 3, 5, 6.2 and 8 g Pu/cm3 were investigated. They all melt in the range 425-442°C and expand on freezing. This expansion increases with increasing plutonium content from 1.3% for the 3 g Pu/cm3 alloy to 3% for the 8 g Pu/cm3 material. Manganese additions to this fuel system are being studied in an attempt to reduce this expansion on freezing. (author)

  17. Alloy development for irradiation performance. Quarterly progress report for period ending December 31, 1980

    International Nuclear Information System (INIS)

    Progress is reported in eight sections: analysis and evaluation studies, test matrices and test methods development, Path A Alloy Development (austenitic stainless steels), Path C Alloy Development (Ti and V alloys), Path D Alloy Development (Fe alloys), Path E Alloy Development (ferritic steels), irradiation experiments and materials inventory, and materials compatibility and hydrogen permeation studies

  18. Alloy development for irradiation performance. Quarterly progress report for period ending December 31, 1980

    Energy Technology Data Exchange (ETDEWEB)

    1981-04-01

    Progress is reported in eight sections: analysis and evaluation studies, test matrices and test methods development, Path A Alloy Development (austenitic stainless steels), Path C Alloy Development (Ti and V alloys), Path D Alloy Development (Fe alloys), Path E Alloy Development (ferritic steels), irradiation experiments and materials inventory, and materials compatibility and hydrogen permeation studies. (DLC)

  19. Minor alloying behavior in bulk metallic glasses and high-entropy alloys

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    The effect of minor alloying on several bulk metallic glasses and high-entropy al-loys was studied. It was found that minor Nb addition can optimize the interface structure between the W fiber and the Zr-based bulk metallic glass in the compos-ites,and improve the mechanical properties. Minor Y addition can destabilize the crystalline phases by inducing lattice distortion as a result to improve the glass-forming ability,and the lattice distortion energy is closely related to the effi-ciency of space filling of the competing crystalline phases. A long-period ordered structure can precipitate in the Mg-based bulk metallic glass by yttrium alloying. For the high-entropy alloys,solid solution can be formed by alloying,and its me-chanical properties can be comparable to most of the bulk metallic glasses.

  20. Analysis of heavy alloying elements segregation in gravity cast experimental Mg-Al-Zn-RE alloy

    Directory of Open Access Journals (Sweden)

    A. Żydek

    2010-01-01

    Full Text Available Microstructure of experimental AZ91 alloy with an addition of rare earth elements (RE at a level of 4 wt.% was examined by means of light microscopy. The investigated AZ91 + 4 wt.% RE alloy was fabricated by adding cerium rich mish metal to molten commercial AZ91 alloy. In the microstructure of the resulting alloy, besides α solid solution, α + γ eutectic and discontinuous precipitates of γ phase, also the Al11RE3 phase with needle-like morphology and the polygonal Al10RE2Mn7 phase were revealed. No segregation of rare earth elements was found in the investigated gravity cast alloy, which was confirmed by statistical analysis of cerium concentrations in selected parts of the cast. Similar results were obtained for manganese. Ce and Mn concentrations were determined by a spectrophotometric method.

  1. Plasma surface alloying of titanium alloy for enhancing burn-resistant property

    Institute of Scientific and Technical Information of China (English)

    ZHANG Ping-ze; XU Zhong; ZHANG Gao-hui; HE Zhi-yong; YAO Zheng-jun

    2006-01-01

    Conventional titanium alloy may be ignited and burnt under high temperature, high pressure and high gas flow velocity condition. In order to avoid this problem, burn-resistant alloying layers were made on the surface of Ti-6Al-4V and Ti-6.5Al-0.3Mo-1.5Zr-0.25Si titanium alloys by using double glow plasma surface alloying technology (DG Technology). Two typical burn-resistant layers Ti-Cr and Ti-Mo were made by DG plasma chromizing and DG plasma molybdenizing, respectively. Burn-resistant properties were tested by layer ignition method using 2 kW laser machine. Ignition experiments result reveals that the ignition temperature of alloyed layer with Mo and Cr concentration above 10% is about 200℃ higher than ignition temperature of Ti-6Al-4V substrate.

  2. Modification of the titanium alloy surface in electroexplosive alloying with boron carbide and subsequent electron-beam treatment

    International Nuclear Information System (INIS)

    The modification of the VT6 titanium alloy surface in electroexplosion alloying with plasma being formed in titanium foil with a weighed powder of boron carbide with subsequent irradiation by a pulsed electron beam has been carried out. An electroexplosive alloying zone of a thickness up to 50 μm with a gradient structure is found to form. The subsequent electron-beam treatment of the alloying zone results in smoothing of the alloying surface and is accompanied by the formation of the multilayer structure with alternating layers of various alloying degree at a depth of 30 μm

  3. Modification of the titanium alloy surface in electroexplosive alloying with boron carbide and subsequent electron-beam treatment

    Science.gov (United States)

    Gromov, Victor E.; Budovskikh, Evgeniy A.; Ivanov, Yurii F.; Bashchenko, Lyudmila P.; Wang, Xinli; Kobzareva, Tatyana Yu.; Semin, Alexander P.

    2015-10-01

    The modification of the VT6 titanium alloy surface in electroexplosion alloying with plasma being formed in titanium foil with a weighed powder of boron carbide with subsequent irradiation by a pulsed electron beam has been carried out. An electroexplosive alloying zone of a thickness up to 50 μm with a gradient structure is found to form. The subsequent electron-beam treatment of the alloying zone results in smoothing of the alloying surface and is accompanied by the formation of the multilayer structure with alternating layers of various alloying degree at a depth of 30 μm.

  4. Modification of the titanium alloy surface in electroexplosive alloying with boron carbide and subsequent electron-beam treatment

    Energy Technology Data Exchange (ETDEWEB)

    Gromov, Victor E., E-mail: gromov@physics.sibsiu.ru; Budovskikh, Evgeniy A., E-mail: budovskikh-ea@physics.sibsiu.ru; Bashchenko, Lyudmila P., E-mail: gromov@physics.sibsiu.ru; Kobzareva, Tatyana Yu., E-mail: gromov@physics.sibsiu.ru; Semin, Alexander P., E-mail: gromov@physics.sibsiu.ru [Siberian State Industrial University, Novokuznetsk, 654007 (Russian Federation); Ivanov, Yurii F., E-mail: yufi55@mail.ru [Institute of High Current Electronics SB RAS, Tomsk, 634055 (Russian Federation); National Research Tomsk State University, Tomsk, 634050 (Russian Federation); Wang, Xinli, E-mail: wangxl520@hotmail.com [Northeastern University, Liaoning, Shenyang 110819 China (China)

    2015-10-27

    The modification of the VT6 titanium alloy surface in electroexplosion alloying with plasma being formed in titanium foil with a weighed powder of boron carbide with subsequent irradiation by a pulsed electron beam has been carried out. An electroexplosive alloying zone of a thickness up to 50 μm with a gradient structure is found to form. The subsequent electron-beam treatment of the alloying zone results in smoothing of the alloying surface and is accompanied by the formation of the multilayer structure with alternating layers of various alloying degree at a depth of 30 μm.

  5. The influence of alloy composition on residual stresses in heat treated aluminium alloys

    International Nuclear Information System (INIS)

    The as quenched properties of eight different heat treatable aluminium alloys are related to residual stress magnitudes with the objective being to establish if there is a relationship between the residual stress and the as quenched alloy hardness and strength. Near surface residual stresses were assessed with X-ray diffraction using both the established sin2ψ method and the more recent cos α technique. Through thickness residual stresses were also characterised using neutron diffraction. The alloys were chosen to encompass a wide range of strengths. The low to medium strength alloys were 6060 and 6082, medium to high strength 2618A, 2014A, 7075, 7010 and two variants of 7449, while the very high strength alloy was the powder metallurgy alloy N707. To assess the as quenched strength, dynamic hardness and tensile properties were determined from samples tested immediately after quenching to minimise the influence of precipitation hardening by natural aging. In addition, hot hardness measurements were made in situ on samples cooled to simulate quench paths. Within the experimental constraints of the investigation, the distribution of residual stress through the thickness was found to follow the same pattern for all the alloys investigated, varying from tensile in the interior to surface compression. The influence of alloy strength was manifested as a change in the observed residual stress magnitudes, and surface residual stresses were found to vary linearly with as quenched hardness and strength. - Highlights: • As quenched aluminium alloys contain high magnitude residual stresses. • Surface is compressive balance by a tensile core. • As quenched surface residual stress is linear function of alloy strength. • In situ hot hardness demonstrates rapid change in intrinsic hardness during rapid cooling

  6. The influence of alloy composition on residual stresses in heat treated aluminium alloys

    Energy Technology Data Exchange (ETDEWEB)

    Robinson, J.S., E-mail: jeremy.robinson@ul.ie [Department of Mechanical, Aeronautical and Biomedical Engineering, University of Limerick (Ireland); Redington, W. [Materials and Surface Science Institute, University of Limerick (Ireland)

    2015-07-15

    The as quenched properties of eight different heat treatable aluminium alloys are related to residual stress magnitudes with the objective being to establish if there is a relationship between the residual stress and the as quenched alloy hardness and strength. Near surface residual stresses were assessed with X-ray diffraction using both the established sin{sup 2}ψ method and the more recent cos α technique. Through thickness residual stresses were also characterised using neutron diffraction. The alloys were chosen to encompass a wide range of strengths. The low to medium strength alloys were 6060 and 6082, medium to high strength 2618A, 2014A, 7075, 7010 and two variants of 7449, while the very high strength alloy was the powder metallurgy alloy N707. To assess the as quenched strength, dynamic hardness and tensile properties were determined from samples tested immediately after quenching to minimise the influence of precipitation hardening by natural aging. In addition, hot hardness measurements were made in situ on samples cooled to simulate quench paths. Within the experimental constraints of the investigation, the distribution of residual stress through the thickness was found to follow the same pattern for all the alloys investigated, varying from tensile in the interior to surface compression. The influence of alloy strength was manifested as a change in the observed residual stress magnitudes, and surface residual stresses were found to vary linearly with as quenched hardness and strength. - Highlights: • As quenched aluminium alloys contain high magnitude residual stresses. • Surface is compressive balance by a tensile core. • As quenched surface residual stress is linear function of alloy strength. • In situ hot hardness demonstrates rapid change in intrinsic hardness during rapid cooling.

  7. High-Strength Low-Alloy (HSLA) Mg-Zn-Ca Alloys with Excellent Biodegradation Performance

    Science.gov (United States)

    Hofstetter, J.; Becker, M.; Martinelli, E.; Weinberg, A. M.; Mingler, B.; Kilian, H.; Pogatscher, S.; Uggowitzer, P. J.; Löffler, J. F.

    2014-04-01

    This article deals with the development of fine-grained high-strength low-alloy (HSLA) magnesium alloys intended for use as biodegradable implant material. The alloys contain solely low amounts of Zn and Ca as alloying elements. We illustrate the development path starting from the high-Zn-containing ZX50 (MgZn5Ca0.25) alloy with conventional purity, to an ultrahigh-purity ZX50 modification, and further to the ultrahigh-purity Zn-lean alloy ZX10 (MgZn1Ca0.3). It is shown that alloys with high Zn-content are prone to biocorrosion in various environments, most probably because of the presence of the intermetallic phase Mg6Zn3Ca2. A reduction of the Zn content results in (Mg,Zn)2Ca phase formation. This phase is less noble than the Mg-matrix and therefore, in contrast to Mg6Zn3Ca2, does not act as cathodic site. A fine-grained microstructure is achieved by the controlled formation of fine and homogeneously distributed (Mg,Zn)2Ca precipitates, which influence dynamic recrystallization and grain growth during hot forming. Such design scheme is comparable to that of HSLA steels, where low amounts of alloying elements are intended to produce a very fine dispersion of particles to increase the material's strength by refining the grain size. Consequently our new, ultrapure ZX10 alloy exhibits high strength (yield strength R p = 240 MPa, ultimate tensile strength R m = 255 MPa) and simultaneously high ductility (elongation to fracture A = 27%), as well as low mechanical anisotropy. Because of the anodic nature of the (Mg,Zn)2Ca particles used in the HSLA concept, the in vivo degradation in a rat femur implantation study is very slow and homogeneous without clinically observable hydrogen evolution, making the ZX10 alloy a promising material for biodegradable implants.

  8. Iron - based bulk amorphous alloys

    Directory of Open Access Journals (Sweden)

    R. Babilas

    2010-07-01

    Full Text Available Purpose: The paper presents a structure characterization, thermal and soft magnetic properties analysis of Fe-based bulk amorphous materials in as-cast state and after crystallization process. In addition, the paper gives some brief review about achieving, formation and structure of bulk metallic glasses as a special group of amorphous materials.Design/methodology/approach: The studies were performed on Fe72B20Si4Nb4 metallic glass in form of ribbons and rods. The amorphous structure of tested samples was examined by X-ray diffraction (XRD, transmission electron microscopy (TEM and scanning electron microscopy (SEM methods. The thermal properties of the glassy samples were measured using differential thermal analysis (DTA and differential scanning calorimetry (DSC. The magnetic properties contained initial and maximum magnetic permeability, coercive force and magnetic after-effects measurements were determined by the Maxwell-Wien bridge and VSM methods.Findings: The X-ray diffraction and transmission electron microscopy investigations revealed that the studied as-cast bulk metallic glasses in form of ribbons and rods were amorphous. Two stage crystallization process was observed for studied bulk amorphous alloy. The differences of crystallization temperature between ribbons and rods with chosen thickness are probably caused by different amorphous structures as a result of the different cooling rates in casting process. The SEM images showed that studied fractures could be classified as mixed fractures with indicated two zones contained “river” and “smooth” areas. The changing of chosen soft magnetic properties (μr, Bs, Hc obtained for samples with different thickness is a result of the non-homogenous amorphous structure of tested metallic glasses. The annealing process in temperature range from 373 to 773 K causes structural relaxation of tested amorphous materials, which leads to changes in their physical properties. The qualitative

  9. Cleanliness of Alloying Structural Steel

    Institute of Scientific and Technical Information of China (English)

    YU Hui-xiang; WANG Xin-hua; ZHANG Jing; LI Hai-bo; WANG Wan-jun

    2011-01-01

    Alloying structural steel used for mechanical structures has a high requirement for cleanliness because its failures are greatly affected by non-metallic inclusions and total oxygen content in steel.It has been reported by some steelmaking plants to have some problems in controlling total oxygen content and inclusions during alloying structural steel production.For this purpose,cleanliness control in 0.2C-0.3Si-0.6Mn-1Cr-0.2Mo steel was investigated.Firstly,low melting temperature zone(≤1873 K) of CaO-Al2O3-MgO system and formation condition of low melting temperature inclusions were investigated through thermodynamic equilibrium calculation.On this basis,industrial tests were carried out.Through sampling at different stages,transformation of oxide inclusions and change of total oxygen content in steel were studied.The results show that:in order to form CaO-Al2O3-MgO system inclusions with low melting temperature,mass percent of Al2O3,MgO and CaO in inclusions should be controlled from 37.6% to 70.8%,0 to 17.4% and 25.5% to 60.6%;For the condition of 1873 K and 0.05%(mass percent) dissolved aluminum in steel,the activities of dissolved oxygen,magnesium and calcium should be controlled as 0.298×10-4-2×10-4,0.1×10-5-40×10-5 and 0.8×10-8-180×10-8 respectively.With secondary refining proceeding,average total oxygen content and inclusion amount decrease,the type of most inclusions changes from Al2O3 after tapping to Al2O3-MgO after top slag is formed during ladle furnace refining and finally to CaO-Al2O3-MgO after RH treatment.In the final products,average total oxygen content was 12.7×10-6 and most inclusions were in spherical shape with size less than 5 μm.

  10. Multi-functional magnesium alloys containing interstitial oxygen atoms.

    Science.gov (United States)

    Kang, H; Choi, H J; Kang, S W; Shin, S E; Choi, G S; Bae, D H

    2016-01-01

    A new class of magnesium alloys has been developed by dissolving large amounts of oxygen atoms into a magnesium lattice (Mg-O alloys). The oxygen atoms are supplied by decomposing titanium dioxide nanoparticles in a magnesium melt at 720 °C; the titanium is then completely separated out from the magnesium melt after solidification. The dissolved oxygen atoms are located at the octahedral sites of magnesium, which expand the magnesium lattice. These alloys possess ionic and metallic bonding characteristics, providing outstanding mechanical and functional properties. A Mg-O-Al casting alloy made in this fashion shows superior mechanical performance, chemical resistance to corrosion, and thermal conductivity. Furthermore, a similar Mg-O-Zn wrought alloy shows high elongation to failure (>50%) at room temperature, because the alloy plastically deforms with only multiple slips in the sub-micrometer grains (alloys are expected to open a new paradigm in commercial alloy design. PMID:26976372

  11. Recent progress on gas tungsten arc welding of vanadium alloys

    Energy Technology Data Exchange (ETDEWEB)

    King, J.F.; Grossbeck, M.L.; Goodwin, G.M.; Alexander, D.J. [Oak Ridge National Lab., TN (United States)

    1997-04-01

    This is a progress report on a continuing research project to acquire a fundamental understanding of the metallurgical processes in the welding of vanadium alloys. It also has the goal of developing techniques for welding structural vanadium alloys. The alloy V-4Cr-4Ti is used as a representative alloy of the group; it is also the prime candidate vanadium alloy for the U.S. Fusion Program at the present time. However, other alloys of this class were used in the research as necessary. The present work focuses on recent findings of hydrogen embrittlement found in vanadium alloy welds. It was concluded that the atmosphere in the inert gas glove box was insufficient for welding 6mm thick vanadium alloy plates.

  12. Density of Ni-Cr Alloy in the Mushy State

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    The density of Ni-Cr alloy in the mushy state has been measured using the modified sessile drop method. The density of Ni-Cr alloy in the mushy state was found to decrease with increasing temperature and Cr concentration in alloy.The molar volume of Ni-Cr alloy in the mushy state therefore increases with increasing the Cr concentration in alloy.The ratio of the difference of density divided by the temperature difference between liquidus and solidus temperatures decreases with increasing Cr concentration. The density of the alloy increased with the precipitation of a solid phase in alloy during the solidification process. The temperature dependence of the density of alloy in the mushy state was not linear but biquadratic.

  13. Production, Properties and Applications of Bulk Amorphous Alloys

    Institute of Scientific and Technical Information of China (English)

    Tao Zhang; Akihisa Inoue

    2000-01-01

    A review is given of recent work concerned with the production method, the characteristic properties(1) Bulk amorphous system; (2) Mechanical and magnetic properties of bulkamorphous alloys; (3)application of bulk amorphous alloys.

  14. Composite purification technology and mechanism of recycled aluminum alloys

    Institute of Scientific and Technical Information of China (English)

    房文斌; 耿耀宏; 安阁英; 叶荣茂

    2002-01-01

    Iron-rich inclusions in aluminum alloys can be effectively removed by composite purification of sedimentation and filtration technology.The results show that the purposed method has no negative effects on aluminum alloys and obviously improve their mechanical properties.

  15. Measurement and analyses of molten Ni-Co alloy density

    Institute of Scientific and Technical Information of China (English)

    XIAO Feng; K. MUKAI; FANG Liang; FU Ya; YANG Ren-hui

    2006-01-01

    With the advent of powerful mathematical modeling techniques for material phenomena, there is renewed interest in reliable data for the density of the Ni-based superalloys. Up to now, there has been few report on the density of molten Ni-Co alloy.In order to obtain more accurate density data for molten Ni-Co alloy, the density of molten Ni-Co alloy was measured with a modified sessile drop method, and the accommodation of different atoms in molten Ni-Co alloy was analyzed. The density of alloy is found to decrease with increasing temperature and Co concentration in the alloy. The molar volume of molten Ni-Co alloy increases with increasing Co concentration. The molar volume of Ni-Co alloy determined shows a positive deviation from the linear molar volume, and the deviation of molar volume from ideal mixing increases with increasing Co concentration over the experimental concentration range.

  16. The Origin of the Name "Onion's Fusible Alloy"

    Science.gov (United States)

    Jensen, William B.

    2010-01-01

    In response to a reader query, this article traces the history of fusible alloys, including Newton's metal, D'Arcet's metal, Rose's metal, Onion's fusible alloy, and Wood's metal. (Contains 1 table and 1 figure.)

  17. Advances of Titanium Alloys and Its Biological Surface Modification

    Institute of Scientific and Technical Information of China (English)

    XU Ke-wei; HUANG Ping

    2004-01-01

    This paper reviews the past, present and future of surface modification of titanium alloy from the point of view of preparation of hard tissue replacement implants. The development of titanium alloy is also described.

  18. Development on research of advanced rare-earth aluminum alloy

    Institute of Scientific and Technical Information of China (English)

    聂祚仁; 金头男; 邹景霞; 付静波; 杨军军; 左铁镛

    2003-01-01

    The active mechanisms of rare earth element erbium ( Er ) in part of aluminum alloys were investigated. Based on the investigation of the effect of the unitary rare earth elements (Er, La, Y, Ce, Nd, Gd, and Sc) and the transition element zirconium on the aluminum alloys, it is concluded that, with Er alloyed, high purity aluminum and Al-Mg alloys are featured with refined grain structure, superior heat stability and even higher hardness or tensile strength with unchanged ductility; but Er is not beneficial to the mechanical property of Al-Cu alloy, so is Sc. It may also be concluded, to most of the aluminum alloys, Er can be an effective alloying element, like Sc; and for the lower price of Er, the cost of modifying aluminum alloys by Er will be reduced.

  19. [Study on biocompatibility of titanium alloys].

    Science.gov (United States)

    Kodama, T

    1989-06-01

    The biocompatibility of two different titanium alloys, Ti-6Al-4V ELI and Ti-5Al-2, 5Fe, and pure titanium were evaluated. The results were as follows: 1) Titanium alloys were implanted into the dorsal subcutaneous tissues of the Hartley guinea-pig for 12 weeks, immersed in calf serum or in Ringer's solution for 8 weeks. The surface changes of the titanium alloys were observed by SEM and the chemical composition was analyzed by XMA. No evident surface changes were found. 2) Three hundred mg, 200 mg and 100 mg of the powders of the tested materials were immersed in 2ml of Eagle's MEM, incubated for 1-7 days, 8-21 days and 22-70 days at 37 C degrees. The amount of metallic elements dissolved in the solutions was measured by ICP and AAS. The detected corrosion rates of V and Al contained in the solution, in which Ti-6Al-4V ELI 100 mg was immersed for 1-7 days, were 194.3 +/- 17.6 and 73.0 +/- 28, 1 pg/mg alloy/day, respectively. V was released more than Al. The amount of Ti was below the detectable limit. The solution Ti-5Al-2.5 Fe 100 mg immersed for 1-7 days contained 31.9 +/- 34.4 pg/mg alloy/day Fe and 25.7 +/- 6.3 pg/mg alloy/day Al. Only in the solution 300 mg immersed for 1-7 days was Ti detected at 1.4 pg/mg alloy/day. 3) By the bacterial mutation assay of Salmonella typhimurium TA 98, Salmonella typhimurium TA 100 and Escherichia coli WP2 uvrA, the solutions, in which the tested materials were immersed, were not found to be mutagenic. 4) By the UDS assay, the grain counts on autoradiography with the solutions, in which the tested materials were immersed, were not greater than the negative control. The results suggest an excellent corrosion resistance of the titanium alloys. Mutagenicity was negative by these mutation assays, indicating that the tested alloys and pure titanium are safe for humans and animals.

  20. Amorphous Alloy Surpasses Steel and Titanium

    Science.gov (United States)

    2004-01-01

    In the same way that the inventions of steel in the 1800s and plastic in the 1900s sparked revolutions for industry, a new class of amorphous alloys is poised to redefine materials science as we know it in the 21st century. Welcome to the 3rd Revolution, otherwise known as the era of Liquidmetal(R) alloys, where metals behave similar to plastics but possess more than twice the strength of high performance titanium. Liquidmetal alloys were conceived in 1992, as a result of a project funded by the California Institute of Technology (CalTech), NASA, and the U.S. Department of Energy, to study the fundamentals of metallic alloys in an undercooled liquid state, for the development of new aerospace materials. Furthermore, NASA's Marshall Space Flight Center contributed to the development of the alloys by subjecting the materials to testing in its Electrostatic Levitator, a special instrument that is capable of suspending an object in midair so that researchers can heat and cool it in a containerless environment free from contaminants that could otherwise spoil the experiment.

  1. A jumping shape memory alloy under heat

    Science.gov (United States)

    Yang, Shuiyuan; Omori, Toshihiro; Wang, Cuiping; Liu, Yong; Nagasako, Makoto; Ruan, Jingjing; Kainuma, Ryosuke; Ishida, Kiyohito; Liu, Xingjun

    2016-02-01

    Shape memory alloys are typical temperature-sensitive metallic functional materials due to superelasticity and shape recovery characteristics. The conventional shape memory effect involves the formation and deformation of thermally induced martensite and its reverse transformation. The shape recovery process usually takes place over a temperature range, showing relatively low temperature-sensitivity. Here we report novel Cu-Al-Fe-Mn shape memory alloys. Their stress-strain and shape recovery behaviors are clearly different from the conventional shape memory alloys. In this study, although the Cu-12.2Al-4.3Fe-6.6Mn and Cu-12.9Al-3.8Fe-5.6Mn alloys possess predominantly L21 parent before deformation, the 2H martensite stress-induced from L21 parent could be retained after unloading. Furthermore, their shape recovery response is extremely temperature-sensitive, in which a giant residual strain of about 9% recovers instantly and completely during heating. At the same time, the phenomenon of the jumping of the sample occurs. It is originated from the instantaneous completion of the reverse transformation of the stabilized 2H martensite. This novel Cu-Al-Fe-Mn shape memory alloys have great potentials as new temperature-sensitive functional materials.

  2. Ion-induced surface modification of alloys

    International Nuclear Information System (INIS)

    In addition to the accumulation of the implanted species, a considerable number of processes can affect the composition of an alloy in the surface region during ion bombardment. Collisions of energetic ions with atoms of the alloy induce local rearrangement of atoms by displacements, replacement sequences and by spontaneous migration and recombination of defects within cascades. Point defects form clusters, voids, dislocation loops and networks. Preferential sputtering of elements changes the composition of the surface. At temperatures sufficient for thermal migration of point defects, radiation-enhanced diffusion promotes alloy component redistribution within and beyond the damage layer. Fluxes of interstitials and vacancies toward the surface and into the interior of the target induce fluxes of alloying elements leading to depth-dependent compositional changes. Moreover, Gibbsian surface segregation may affect the preferential loss of alloy components by sputtering when the kinetics of equilibration of the surface composition becomes competitive with the sputtering rate. Temperature, time, current density and ion energy can be used to influence the individual processes contributing to compositional changes and, thus, produce a rich variety of composition profiles near surfaces. 42 references

  3. Modeling selective intergranular oxidation of binary alloys

    Science.gov (United States)

    Xu, Zhijie; Li, Dongsheng; Schreiber, Daniel K.; Rosso, Kevin M.; Bruemmer, Stephen M.

    2015-01-01

    Intergranular attack of alloys under hydrothermal conditions is a complex problem that depends on metal and oxygen transport kinetics via solid-state and channel-like pathways to an advancing oxidation front. Experiments reveal very different rates of intergranular attack and minor element depletion distances ahead of the oxidation front for nickel-based binary alloys depending on the minor element. For example, a significant Cr depletion up to 9 μm ahead of grain boundary crack tips was documented for Ni-5Cr binary alloy, in contrast to relatively moderate Al depletion for Ni-5Al (˜100 s of nm). We present a mathematical kinetics model that adapts Wagner's model for thick film growth to intergranular attack of binary alloys. The transport coefficients of elements O, Ni, Cr, and Al in bulk alloys and along grain boundaries were estimated from the literature. For planar surface oxidation, a critical concentration of the minor element can be determined from the model where the oxide of minor element becomes dominant over the major element. This generic model for simple grain boundary oxidation can predict oxidation penetration velocities and minor element depletion distances ahead of the advancing front that are comparable to experimental data. The significant distance of depletion of Cr in Ni-5Cr in contrast to the localized Al depletion in Ni-5Al can be explained by the model due to the combination of the relatively faster diffusion of Cr along the grain boundary and slower diffusion in bulk grains, relative to Al.

  4. Explosive compaction of CuCr alloys

    Institute of Scientific and Technical Information of China (English)

    李金平; 罗守靖; 龚朝晖; 牛玮; 纪松

    2002-01-01

    The production of CuCr alloys utilizing explosive compaction was studied. Mixture powders of CuCr alloys placed in tubes with a dimension of d14.0mm×21.4mm can be compacted using explosive pads of 16.5mm or 22.5mm. Thicker pads of explosive make the compacts more porous. The effects of the ratio of me/mp, ratio of me/(mp+mt) and impact energy on the density of compacts were similar, they were chosen to control explosive compaction, respectively. When adequate value of the parameters me/mp, me/(mt+mp) and impact energy of unit area of tube was chosen, high density(7.858g/cm3), high hardness(HB189) and low conductance (13.6MS/m) of CuCr alloys could be made by explosive compaction. The general properties of CuCr alloys by explosive compaction are similar to those of CuCr alloys by traditional process.

  5. Vanadium alloys - overview and recent results

    Science.gov (United States)

    Muroga, T.; Nagasaka, T.; Abe, K.; Chernov, V. M.; Matsui, H.; Smith, D. L.; Xu, Z.-Y.; Zinkle, S. J.

    2002-12-01

    This paper reviews recent progress in research on vanadium alloys with emphasis on V-4Cr-4Ti as a reference composition. New high purity V-4Cr-4Ti ingots and products (NIFS-HEATs) were made. The improved purity of the alloys made a practical demonstration of enhanced feasibility of recycling as a method of handling after use in fusion reactors. Significant progress has been made in the understanding of physical metallurgy of V-4Cr-4Ti and effects of O, N and C on the alloy properties such as low and high temperature mechanical properties, welding properties and low temperature irradiation effects, by means of including the comparison of various large heats and model alloys with different impurity levels. The effects of other trace impurities on some of the properties are also discussed. Other current efforts to characterize V-4Cr-4Ti, to improve its properties and to explore advanced vanadium alloys are reviewed. Issues remaining for the future investigations are discussed.

  6. A jumping shape memory alloy under heat.

    Science.gov (United States)

    Yang, Shuiyuan; Omori, Toshihiro; Wang, Cuiping; Liu, Yong; Nagasako, Makoto; Ruan, Jingjing; Kainuma, Ryosuke; Ishida, Kiyohito; Liu, Xingjun

    2016-02-16

    Shape memory alloys are typical temperature-sensitive metallic functional materials due to superelasticity and shape recovery characteristics. The conventional shape memory effect involves the formation and deformation of thermally induced martensite and its reverse transformation. The shape recovery process usually takes place over a temperature range, showing relatively low temperature-sensitivity. Here we report novel Cu-Al-Fe-Mn shape memory alloys. Their stress-strain and shape recovery behaviors are clearly different from the conventional shape memory alloys. In this study, although the Cu-12.2Al-4.3Fe-6.6Mn and Cu-12.9Al-3.8Fe-5.6Mn alloys possess predominantly L2(1) parent before deformation, the 2H martensite stress-induced from L2(1) parent could be retained after unloading. Furthermore, their shape recovery response is extremely temperature-sensitive, in which a giant residual strain of about 9% recovers instantly and completely during heating. At the same time, the phenomenon of the jumping of the sample occurs. It is originated from the instantaneous completion of the reverse transformation of the stabilized 2H martensite. This novel Cu-Al-Fe-Mn shape memory alloys have great potentials as new temperature-sensitive functional materials.

  7. Fermi surface effects in terbium alloys

    International Nuclear Information System (INIS)

    Work is reported which was conducted to test of the relation of the generalized susceptibility (and therefore, the ordering properties) for Tb to the Fermi energy of Tb. In order to properly analyze the data a simple theory was developed to account for the effects on band structure which accompany alloying and attendant lattice size changes. Using this simple theory, the alloys of Tb with Mg are understood as a combination of Fermi energy lowering and of lattice contraction. The tendency of Th to promote the ferromagnetic structure in Th is understood as a combination of the Fermi energy being raised and of the lattice being expanded. The theory was also useful in explaining the interesting behavior of the Tb with Yb alloys which upon preliminary analysis did not seem to follow the theoretical predictions. After consideration of the volume effect, indeed the Tb with Yb alloys showed promotion of the helical structure as predicted. The complicated behavior of the Tb with Yb alloys is a case where the volume and valence effects compete. Results show that the magnetic ordering properties of the rare earths are intimately related to the Fermi surface geometry through the generalized susceptibility

  8. Ductile Fe-based amorphous alloy

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Hong-Kyu; Lee, Kwang-Bok [Department of Materials Science and Engineering, Korea University, Seoul 136-701 (Korea, Republic of); Lee, Jae-Chul, E-mail: jclee001@korea.ac.kr [Department of Materials Science and Engineering, Korea University, Seoul 136-701 (Korea, Republic of)

    2012-08-30

    Highlights: Black-Right-Pointing-Pointer Fe-based amorphous alloy with a strength and fracture strain of 4.7 GPa and 8.0% was synthesized. Black-Right-Pointing-Pointer Addition of a minute amount of V promoted the phase separation of the constituent elements. Black-Right-Pointing-Pointer Phase separation lowered alloys' packing density and alleviated the degree of strain localization. - Abstract: Experiments demonstrated that the addition of a minute amount of V to Fe{sub 52}Co{sub (20-x)}B{sub 20}Si{sub 4}Nb{sub 4}V{sub x} amorphous alloy induces atomic-scale phase separation, which dramatically enhances the plasticity. Especially, Fe{sub 52}Co{sub 17.5}B{sub 20}Si{sub 4}Nb{sub 4}V{sub 2.5} amorphous alloy exhibited a strength of 4.7 GPa and a fracture strain of 8.0%, which is the largest strain reported for Fe-based amorphous alloys. In this study, the structural origin of the enhanced plasticity is explored by examining the role played by the phase separating element on the packing density and strain localization.

  9. POTENTIAL USE OF MAGNESIUM ALLOYS FOR THE AUTOMOTIVE INDUSTRY

    OpenAIRE

    KANDEMİR, Kudret; A. Çetin CAN

    2003-01-01

    Recently, there is a high interest in using lightweight materials for automotive applications where weight reduction and improvement in comfort are needed. Magnesium alloys with excellent specific strength and stiffness properties can be comparable with steel and aluminum alloys for applications in the automotive industry. For this reason, the properties of magnesium alloys are in the focus of research. This study aims at reviewing and evaluating the prospects of magnesium alloys use and appl...

  10. Softening Behaviour of Selected Commercially Pure Aluminium Model Alloys

    OpenAIRE

    Sande, Gunnar

    2012-01-01

    A characterization of the softening behaviour of four different commercially pure aluminium alloys has been carried out. The work is related to the MOREAL project (Modelling towards value-added recycling friendly aluminium alloys), where the main goal is to quantify the effect of the elements in recyclable aluminium alloys on microstructure and mechanical properties during thermo-mechanical processing. Typical elements are iron (Fe), silicon (Si) and manganese (Mn), and the alloys studied in ...

  11. Microalloying with Cd of Antifriction Sn-Sb-Cu Alloys

    OpenAIRE

    Cinca Ionel Lupinca; Constantin Marta; Attila Szabo

    2012-01-01

    In the case of bimetallic sliding linings with superior technological characteristics, the use of an antifriction ally is imposed an alloy of the type Sn-Sb-Cu, which possesses a high adherence to the steel stand and a high durability in exploitation. For this reason we use the microalloying of the antifriction alloy with cadmium. The microalloying with Cd of antifriction alloys Sn-Sb-Cu determines an increase of the adhesion property of the antifriction alloy on the steel ...

  12. POTENTIAL USE OF MAGNESIUM ALLOYS FOR THE AUTOMOTIVE INDUSTRY

    Directory of Open Access Journals (Sweden)

    Kudret KANDEMİR

    2003-01-01

    Full Text Available Recently, there is a high interest in using lightweight materials for automotive applications where weight reduction and improvement in comfort are needed. Magnesium alloys with excellent specific strength and stiffness properties can be comparable with steel and aluminum alloys for applications in the automotive industry. For this reason, the properties of magnesium alloys are in the focus of research. This study aims at reviewing and evaluating the prospects of magnesium alloys use and applications in the automotive industry.

  13. Microstructure and Aging of Powder-Metallurgy Al Alloys

    Science.gov (United States)

    Blackburn, L. B.

    1987-01-01

    Report describes experimental study of thermal responses and aging behaviors of three new aluminum alloys. Alloys produced from rapidly solidified powders and contain 3.20 to 5.15 percent copper, 0.24 to 1.73 percent magnesium, 0.08 to 0.92 percent iron, and smaller amounts of manganese, nickel, titanium, silicon, and zinc. Peak hardness achieved at lower aging temperatures than with standard ingot-metallurgy alloys. Alloys of interest for automobile, aircraft, and aerospace applications.

  14. Technique of Aluminum Alloy Composite by Inversion Casting

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    The influence of the temperature of liquid aluminum alloy, the dipping time in liquid alloy and the thickness of base strips on the solidified layer was studied during the process of producing aluminum alloy composite strips used in automobile radiator with inversion casting. It is concluded that there is welding as well as diffusion of alloying elements between the base strip and the coating. Experiments proved that the interface has a good bonding.

  15. NUCLEATION RATE OF DIAMOND FILMS ON WC-Co ALLOYS

    OpenAIRE

    SHA LIU

    2005-01-01

    Diamond-coated hard alloys are prospective tool materials for extreme cutting conditions. Nucleation rate is one of important factors that affect the qualities of diamond thin films on WC-Co alloys. However, theoretical reports on nucleation rate of diamond films on WC-Co alloys are scarce. Combining the unique diamond strong orientation with substrate surface properties, an improved theoretical formula on nucleation rate of diamond films on the WC-Co alloys is deduced in this paper. First, t...

  16. Evaluation of Ti-Cr-Cu alloys for dental applications

    Science.gov (United States)

    Koike, Marie; Okabe, Toru; Itoh, Masayuki; Okuno, Osamu; Kimura, Kohei; Takeda, Osamu; Okabe, Toru H.

    2005-12-01

    This study examined the characteristics of as-cast Ti-Cr(7 19%)-Cu(3 7%) (all percentages in this article are mass%) alloys to evaluate their suitability for dental applications; studies on the alloy structures and mechanical properties, grindability, and corrosion behavior were included in the investigation. The alloys were centrifugally cast and bench-cooled in investment molds. The x-ray diffractometry of the as-cast alloys bench-cooled in the molds indicated the following phases: α+β+ω in the 7% Cr and 7% Cr+3% Cu; β+ω in the 13%Cr; and β in the 13%Cr+3% Cu through the 19%Cr+3% Cu alloys. The strengths of the binary β Ti-Cr and ternary β Ti-Cr-Cu alloys with 13 and 19% Cr were approximately two times higher than those of CP Ti. The alloy ductility was dependent on the chemical composition and thus, the microstructure. The 7% Cr alloys were extremely brittle and hard due to the ω phase, but the ductility was restored in the 13 and 19% Cr alloys. The hardness (HV) of the cast 13 and 19% Cr alloys was approximately 300 350 compared with a value of 200 for CP Ti. The grindability of the cast alloys was examined using a rotating SiC wheel at speeds (circumferential) of 500 and 1250 m/min. At the higher speed, the grindability of the 13 and 19% Cr alloys increased with the Cu content. The grindability of the 13% Cr alloy with 7% Cu was similar to that of CP Ti. Evaluation of the corrosion behavior in an artificial saliva revealed that the alloys are like many other titanium alloys within the normal intraoral oxidation potential. The wear resistance testing of these alloys also showed favorable results.

  17. Effect of Microstructure on the Performance of Corrosion Resistant Alloys

    OpenAIRE

    Kishan Roodbari, Marzieh

    2015-01-01

    Corrosion by pitting in aluminum alloys is a very complex process that can be affected by various factors such as chemical composition and microstructure of the alloys. The electrochemistry and distribution of second phases populating the alloy are the main factors that significantly influence the corrosion of aluminum alloys. The purpose of the present work is to contribute to a deeper understanding of how the chemical composition and microstructure affect the ability of an al...

  18. Possibilities of mechanical properties and microstructure improvement of magnesium alloys

    OpenAIRE

    I. Juřička; L.A. Dobrzański; L. Čižek; Kocich, R.; M. Greger

    2007-01-01

    Purpose: Magnesium alloys are the very progressive materials whereon is due to improve their end-useproperties, which . Especially, wrought Mg alloys attract attention since they have more advantageous mechanicalproperties than cast Mg alloys.Design/methodology/approach: The presented article shows some specific physical-metallurgicalcharacteristics of magnesium alloys of the AZ91 kind after hot forming. Special attention has been focused onthe analysis of mutual relations existing between th...

  19. The Progress on Laser Surface Modification Techniques of Titanium Alloy

    Institute of Scientific and Technical Information of China (English)

    LIANG Cheng; PAN Lin; Al Ding-fei; TAO Xi-qi; XIA Chun-huai; SONG Yan

    2004-01-01

    Titanium alloy is widely used in aviation, national defence, automobile, medicine and other fields because of their advantages in lower density, corrosion resistance, and fatigue resistance etc. As titanium alloy is higher friction coefficients, weak wear resistance, bad high temperature oxidation resistance and lower biocompatibility, its applications are restricted. Using laser surface modification techniques can significantly improve the surface properties of titanium alloy. a review is given for progress on laser surface modification techniques of titanium alloy in this paper.

  20. Galvanic aspects of aluminum sacrificial anode alloys in seawater.

    OpenAIRE

    Cummings, Jon Richard

    2012-01-01

    Galvanic aspects of aluminum sacrificial anode alloys in artificial seawater were investigated. Specifically, two mercury-bearing alloys and one tin-bearing alloy were studied. The polarization behavior of the aluminum sacrificial anode alloys coupled to HY-80 steel is discussed. Current versus time curves were obtained for aluminum/steel galvanic couples immersed in artificial seawater for specific intervals. Scanning elecron microscopy was used to characterize the anode dissolution patt...

  1. Alloy element redistribution during sintering of powder metallurgy steels

    OpenAIRE

    Tahir, Abdul Malik

    2014-01-01

    Homogenization of alloying elements is desired during sintering of powder metallurgy components. The redistribution processes such as penetration of liquid phase into the interparticle/grain boundaries of solid particles and subsequent solid-state  diffusion of alloy element(s) in the base powder, are important for the effective homogenization of alloy element(s) during liquid phase sintering of the mixed powders. The aim of this study is to increase the understanding of alloy element redistr...

  2. NEW METHOD OF PRODUCTION OF ALUNINUM SILICON ALLOYS

    OpenAIRE

    V. K. Afanasiev; E. L. Marukovich; M. N. Churik; V. V. Gertsen; A. V. Gorshenin; A. A. Samon

    2015-01-01

    A new approach to the preparation of aluminum-silicon alloys, based on the concept of the leading role of hydrogen in determining the structure and properties of alloys consists in using as charge materials of silicon dioxide (silica) and hydrogen instead of crystalline silicon was described. Practical ways to implement the new method were proposed on the example of industrial alloys prepared on charge synthetic alloy. It is shown that the application of the proposed method allows to improve ...

  3. Microstructures and properties of aluminum die casting alloys

    Energy Technology Data Exchange (ETDEWEB)

    M. M. Makhlouf; D. Apelian; L. Wang

    1998-10-01

    This document provides descriptions of the microstructure of different aluminum die casting alloys and to relate the various microstructures to the alloy chemistry. It relates the microstructures of the alloys to their main engineering properties such as ultimate tensile strength, yield strength, elongation, fatigue life, impact resistance, wear resistance, hardness, thermal conductivity and electrical conductivity. Finally, it serves as a reference source for aluminum die casting alloys.

  4. Evolution of Hydrogen Storage Alloys Prepared by Special Methods

    Institute of Scientific and Technical Information of China (English)

    Guo Hong; Zhang Ximin; Jing Hai; Li Chengdong; Xu Jun

    2004-01-01

    Microstructure characteristics and electrochemical properties of hydrogen storage alloys prepared by gas atomization, melt spinning and strip casting respectively were outlined.The advantages, disadvantages and research development of the above methods for preparing hydrogen storage alloys were explained.The strip casting is a new special means for preparing AB5 rare earth hydrogen storage alloys of high performance and low cost, and the study of the strip casting for preparing hydrogen storage alloys is presented specially.

  5. STRUCTURE FORMATION OF ALLOYS ON IRON BASIS AFTER LASER ALLOYING

    Directory of Open Access Journals (Sweden)

    О. V. Diachenko

    2016-01-01

    Full Text Available The paper is devoted to investigations on influence of laser treatment regimes of gas-thermal and adhesive coatings from self-fluxing powders on iron basis and after melting with modifying plaster on their roughness and phase composition. One of mathematical planning methods that is a complete factor experiment method has been used for investigation of parameters’ influence on micro-geometry of coatings. The executed investigations have made it possible to observe a general regularity which does not depend on a type of alloying plaster: while increasing speed of laser beam relatively to treated part, beam diameter value of Ra parameter is becoming less. Decrease in height of surface irregularities in case of increasing laser beam speed is related with intensification of evaporation processes. An increase in beam diameter diminishes Ra parameter of the surface. This is due to the fact that decrease in power density occurs at high rate of beam defocusing. Overlapping coefficient does not exert a pronounced effect on Ra parameter of fused coatings. While increasing the speed of laser beam relatively to the part structure is transferred from dendrite into supersaturated one with carbide and boride precipitations. It has been established that technological parameters of laser treatment and particularly speed of laser beam influence on coating composition. While increasing the speed up to v5 = 5 × 10–3 m/s amount of chromium has become larger by 1.5-fold that resulted in increase of micro-hardness of the coating from 9.5–10.1 GPa up to 11.04–15.50 GPa.

  6. Standard Specification for Nickel-Chromium-Molybdenum-Columbium Alloy (UNS N06625), Nickel-Chromium-Molybdenum-Silicon Alloy (UNS N06219), and Nickel-Chromium-Molybdenum-Tungsten Alloy (UNS N06650) Rod and Bar

    CERN Document Server

    American Society for Testing and Materials. Philadelphia

    2014-01-01

    Standard Specification for Nickel-Chromium-Molybdenum-Columbium Alloy (UNS N06625), Nickel-Chromium-Molybdenum-Silicon Alloy (UNS N06219), and Nickel-Chromium-Molybdenum-Tungsten Alloy (UNS N06650) Rod and Bar

  7. Laser surface alloying fabricated porous coating on NiTi shape memory alloy

    Institute of Scientific and Technical Information of China (English)

    ZHANG Song; ZHANG Chun-hua; MAN Hau-chung; LIU Chang-sheng

    2007-01-01

    Laser surface alloying technique was applied to fabricate a metallic porous coating on a solid NiTi shape memory alloy. By laser surface alloying a 40%TiH2-60%NiTi powder mixture on the surface of NiTi alloy using optimized laser process parameters, a porous but crack-free NiTi layer can be fabricated on the NiTi substrate. The porous coating is metallurgically bonded to the substrate NiTi alloy. The pores are uniformly distributed and are interconnected with each other in the coating. An average pore size of less than 10 μm is achieved. The Ni content of the porous layer is much less than that of the original NiTi surface. The existence of the porous coating on the NiTi alloy causes a 37% reduction of the tensile strength and 55% reduction of the strain as compared with the NiTi alloy. Possible biomedical or other applications for this porous surface with good mechanical strength provided by the substrate are prospective.

  8. Fabrication and characterization of niobium based Fe-Cr alloys via mechanical alloying

    International Nuclear Information System (INIS)

    Niobium (Nb) based alloys and composites are currently used in various high temperature applications such as rocket engine nozzles, superconducting magnets, and automotive structural components. Niobium has also been traditionally employed as a micro-alloying element to fabricate high strength, low alloy steels and nickel based superalloys (example: Inconel 718) on account of its ability to form nano dispersions/precipitates which effectively impede high temperature grain growth. Traditionally, niobium alloys such as C-103 (Nb-10Hf-1Ti) and FS-85 (Nb-10W-28Ta-1Zr) having excellent high temperature properties have been fabricated using arc melting and e-beam melting methods. However these alloys have not been widely used on account of their high fabrication costs. On the other hand, nanostructured steels such as oxide dispersion strengthened (ODS) alloys (example: 12Y1, 12YWT, FeCrAl, HT-9, Hestalloy etc) are being proposed for high temperature structural applications for new generation nuclear reactors. In this context we present some of the work related to fabrication and characterization of some known ODS steel compositions with Nb as a micro-alloying element that is currently underway at the High Temperature Materials Laboratory at Virginia Commonwealth University in context of high temperature nuclear applications. (author)

  9. Mechanical behaviour of pressed and sintered titanium alloys obtained from master alloy addition powders.

    Science.gov (United States)

    Bolzoni, L; Esteban, P G; Ruiz-Navas, E M; Gordo, E

    2012-11-01

    The fabrication of the workhorse Ti-6Al-4V alloy and of the Ti-3Al-2.5V alloy was studied considering the master alloy addition variant of the blending elemental approach conventionally used for titanium powder metallurgy. The powders were characterised by means thermal analysis and X-ray diffraction and shaped by means of uniaxial pressing. The microstructural evolution with the sintering temperature (900-1400 °C) was evaluated by SEM and EDS was used to study the composition. XRD patterns as well as the density by Archimedes method were also obtained. The results indicate that master alloy addition is a suitable way to fabricate well developed titanium alloy but also to produce alloy with the desired composition, not available commercially. Density of 4.3 g/cm³ can be obtained where a temperature higher than 1200 °C is needed for the complete diffusion of the alloying elements. Flexural properties comparable to those specified for wrought Ti-6Al-4V medical devices are, generally, obtained.

  10. The physical metallurgy of mechanically-alloyed, dispersion-strengthened Al-Li-Mg and Al-Li-Cu alloys

    Science.gov (United States)

    Gilman, P. S.

    1984-01-01

    Powder processing of Al-Li-Mg and Al-Li-Cu alloys by mechanical alloying (MA) is described, with a discussion of physical and mechanical properties of early experimental alloys of these compositions. The experimental samples were mechanically alloyed in a Szegvari attritor, extruded at 343 and 427 C, and some were solution-treated at 520 and 566 C and naturally, as well as artificially, aged at 170, 190, and 210 C for times of up to 1000 hours. All alloys exhibited maximum hardness after being aged at 170 C; lower hardness corresponds to the solution treatment at 566 C than to that at 520 C. A comparison with ingot metallurgy alloys of the same composition shows the MA material to be stronger and more ductile. It is also noted that properly aged MA alloys can develop a better combination of yield strength and notched toughness at lower alloying levels.

  11. Grain refinement of hypoeutectic Al-Si alloy prepared with ELTA by Al-4B master alloy

    Institute of Scientific and Technical Information of China (English)

    WANG Ming-xing; MENG Xiang-yong; LIU Zhi-yong; LIU Zhong-xia; WENG Yong-gang; SONG Tian-fu; YANG Sheng

    2006-01-01

    Electrolytic low-titanium aluminum (ELTA) was produced by adding TiO2 powder to an industrial aluminum electrolyzer.The grain refining effect of Al-4B master alloy in the hypoeutectic Al-Si alloy prepared by using ELTA was investigated, and compared with those of Al-5Ti, Al-5Ti-1B and Al-4B master alloys in the similar alloy prepared by using pure Al. The results indicate that when Al-4B is added to the melt of the alloy prepared by using ELTA in terms of the Ti/B mass ratio of 5:1, the grain refining effect is better than those of Al-5Ti, Al-5Ti-1B and Al-4B master alloys. Thus, using Al-4B to refine the grain of Al-Si alloys prepared by using ELTA will possibly become a feasible way of obtaining Al-Si alloy with homogeneous and fine microstructure.

  12. Corrosion behavior of vanadium alloys in flowing lithium

    International Nuclear Information System (INIS)

    Corrosion data are presented for several vanadium alloys exposed to flowing lithium at 427, 482 and 5380C. The corrosion behavior was evaluated by measuring weight change. Metallographic results and data on the nonmetallic element transfer in lithium-exposed specimens are also presented. The influence of alloy composition and exposure conditions on the corrosion behavior of vanadium alloys is discussed. (orig.)

  13. Foaming behaviour of Al-Si-Cu-Mg alloys

    Energy Technology Data Exchange (ETDEWEB)

    Kim, A. [Kongju National University (Korea). Dept. of Mechanical Engineering; Cho, S.S. [Chungnam National University, Daejeon (Korea). School of Materials Engineering; Lee, H.J. [Hanbat National University, Daejeon (Korea). Dept. of Building Service Engineering

    2004-12-15

    The powder metallurgical route was utilised to obtain the Al-5Si-4Cu-4Mg (alloy 544) and Al-3Si-2Cu-2Mg (alloy 322) foams. Various steps such as centrifugal atomisation, mixing alloy powder and foaming agent (1 wt-%TiH{sub 2}), cold compaction of mixture, hot extrusion and foaming in a preheated furnace were performed. Foaming behaviour of the alloys was investigated by digital microscopy, image analysis, scanning electron microscopy (SEM) and energy dispersive X-ray (EDX) mapping in this study. It was found that alloy 544 takes a shorter period of time to initiate pore nucleation than alloy 322. Alloy 544 had a higher pore growth rate than alloy 322 at the same pre-set furnace temperature. In both alloys, crack-like pore nucleation occurred between aluminium alloy powders elongated in a direction parallel to the extrusion direction. Both alloys showed the same foaming sequence of crack-like pore nucleation, spherical pore growth, coalescence of neighbouring pores and collapse of pores adjacent to the free surface of specimen. The time required to start pore nucleation decreased with the increase of foaming temperature. The cell walls of both alloys consisted of {alpha}-Al phase and eutectic phase. (author)

  14. 21 CFR 872.3080 - Mercury and alloy dispenser.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 8 2010-04-01 2010-04-01 false Mercury and alloy dispenser. 872.3080 Section 872...) MEDICAL DEVICES DENTAL DEVICES Prosthetic Devices § 872.3080 Mercury and alloy dispenser. (a) Identification. A mercury and alloy dispenser is a device with a spring-activated valve intended to measure...

  15. ZINTL IONS AS STRUCTURAL UNITS IN LIQUID ALLOYS

    NARCIS (Netherlands)

    VANDERLUGT, W

    1991-01-01

    Anion clustering according to a rule discovered by E. Zintl may occur in ionic alloys. The chemical bonds between the anions are predominantly covalent. The drastic consequences of this effect for the electronic and structural properties of liquid ionic alloys are demonstrated for alloys of alkali m

  16. New development of anodizing process of magnesium alloys

    Institute of Scientific and Technical Information of China (English)

    BAI Li-qun; LI Di

    2004-01-01

    Magnesium alloy, a kind of environment-friendly material with promising and excellent properties, is a good choice for a number of applications. The research and development of anodizing on magnesium alloys and its application situation are reviewed, and the anodizing development trend on magnesium alloys is summarized.

  17. Microstructure and properties of modified and conventional 718 alloys

    Institute of Scientific and Technical Information of China (English)

    LIU Fang; SUN Wen-ru; DU Jin-hui; DONG Jian-xin; GUO Shou-ren; YANG Hong-cai; HU Zhuang-qi

    2006-01-01

    Continuing the effort to redesign IN718 alloy in order to provide microstructural and mechanical stability beyond 650 ℃, IN718 alloy was modified by increasing the Al, P and B contents, and the microstructure and mechanical properties of the modified alloy were compared with those of the conventional alloy by SEM and TEM. The precipitation of the grain boundaries of the two alloys is different. The Cr-rich phase, Laves phase and α-Cr phase are easily observed in the modified alloy. The γ″ and γ′ phases in the modified alloy are precipitated in a "compact form". The tensile strengths of the modified alloy at room temperature and 680 ℃ are obviously higher than those of the conventional one. The impact energy of the modified alloy is only about half of that of the conventional alloy. Ageing at 680 ℃ up to 1 000 h lowers the tensile properties and impact energy of both the conventional and modified 718 alloys, except increasing the ductility at 680 ℃. It is concluded that the modified alloy is more stable than the conventional one.

  18. 21 CFR 872.3710 - Base metal alloy.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 8 2010-04-01 2010-04-01 false Base metal alloy. 872.3710 Section 872.3710 Food... DEVICES DENTAL DEVICES Prosthetic Devices § 872.3710 Base metal alloy. (a) Identification. A base metal alloy is a device composed primarily of base metals, such as nickel, chromium, or cobalt, that...

  19. 21 CFR 872.3060 - Noble metal alloy.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 8 2010-04-01 2010-04-01 false Noble metal alloy. 872.3060 Section 872.3060 Food... DEVICES DENTAL DEVICES Prosthetic Devices § 872.3060 Noble metal alloy. (a) Identification. A noble metal alloy is a device composed primarily of noble metals, such as gold, palladium, platinum, or silver,...

  20. NEW DEVELOPMENT IN DOUBLE GLOW SURFACE ALLOYING TECHNOLOGY

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    Several kinds of special alloys are produced on the surfaces of iron and steels by using double glow surface alloying technology. Surface Ni-Cr-Mo-Nb alloy,surface precipitation hardening high speed steel and surface precipitation hardening stainless steel are introduced.

  1. Method of making quasicrystal alloy powder, protective coatings and articles

    Science.gov (United States)

    Shield, J.E.; Goldman, A.I.; Anderson, I.E.; Ellis, T.W.; McCallum, R.W.; Sordelet, D.J.

    1995-07-18

    A method of making quasicrystalline alloy particulates is disclosed wherein an alloy is superheated and the melt is atomized to form generally spherical alloy particulates free of mechanical fracture and exhibiting a predominantly quasicrystalline in the atomized condition structure. The particulates can be plasma sprayed to form a coating or consolidated to form an article of manufacture. 3 figs.

  2. Development and application of titanium alloy casting technology in China

    Institute of Scientific and Technical Information of China (English)

    NAN Hai; XIE Cheng-mu; ZHAO Jia-qi

    2005-01-01

    The development and research of titanium cast alloy and its casting technology, especially its application inaeronautical industry in China are presented. The technology of molding, melting and casting of titanium alloy, casting quality control are introduced. The existing problems and development trend in titanium alloy casting technology are also discussed.

  3. Investigation of joining techniques for advanced austenitic alloys

    Energy Technology Data Exchange (ETDEWEB)

    Lundin, C.D.; Qiao, C.Y.P.; Kikuchi, Y.; Shi, C.; Gill, T.P.S.

    1991-05-01

    Modified Alloys 316 and 800H, designed for high temperature service, have been developed at Oak Ridge National Laboratory. Assessment of the weldability of the advanced austenitic alloys has been conducted at the University of Tennessee. Four aspects of weldability of the advanced austenitic alloys were included in the investigation.

  4. Effect of alloying elements Al and Ca on corrosion resistance of plasma anodized Mg alloys

    Science.gov (United States)

    Anawati, Asoh, Hidetaka; Ono, Sachiko

    2016-04-01

    Plasma anodizing is a surface treatment used to form a ceramic-type oxide film on Mg alloys by the application of a high anodic voltage to create intense plasma near the metal surface. With proper selection of the process parameters, the technique can produce high quality oxide with superior adhesion, corrosion resistance, micro-hardness, wear resistance and strength. The effect of alloying element Al on plasma anodizing process of Mg alloys was studied by comparing the anodizing curves of pure Mg, AZ31, and AZ61 alloys while the effect of Ca were studied on AZ61 alloys containing 0, 1, and 2 wt% Ca. Anodizing was performed in 0.5 M Na3PO4 solution at a constant current density of 200 Am-2 at 25°C. Anodic oxide films with lava-like structure having mix composition of amorphous and crystal were formed on all of the alloys. The main crystal form of the oxide was Mg3(PO4)2 as analyzed by XRD. Alloying elements Al and Ca played role in modifying the plasma lifetime during anodization. Al tended to extend the strong plasma lifetime and therefore accelerated the film thickening. The effect of Ca on anodizing process was still unclear. The anodic film thickness and chemical composition were altered by the presence of Ca in the alloys. Electrochemical corrosion test in 0.9% NaCl solution showed that the corrosion behavior of the anodized specimens depend on the behavior of the substrate. Increasing Al and Ca content in the alloys tended to increase the corrosion resistance of the specimens. The corrosion resistance of the anodized specimens improved significantly about two orders of magnitude relative to the bare substrate.

  5. Coupling between bulk ordering and surface segregation: from alloy surfaces to surface alloys

    International Nuclear Information System (INIS)

    -The knowledge of the alloy surfaces is of prime interest to understand their catalytic properties. On the one hand, the determination of the stability of the surface alloys depends very strongly on the behaviours of the AcB1-c alloy surfaces. On the other hand, the knowledge of the kinetics of the formation-dissolution of surface alloys can allow to understand the equilibrium segregation isotherm. We have then studied the relation between the equilibrium surface segregation in an alloy AcB1-c and the kinetics of dissolution of a few metallic layers of A/B and the inverse deposit. We have used an energetic model derived from the electronic structure (T.I.B.M.) allowing us to study the surface segregation both in the disordered state and in the ordered one. The kinetics of dissolution were studied using the kinetic version of this model (K.T.I.B.M.) consistent with the equilibrium model. To illustrate our study, we have chosen the Cu-Pd system, a model for the formation of surface alloys and for which a great number of studies, both experimental and theoretical, are in progress. We then have shown for the (111) surface of this system that the surface alloys obtained during the dissolution are related to the alloy surfaces observed for the equilibrium segregation. The Cu-Pd system is characteristic of systems which have a weak segregation energy. Then, we have performed an equivalent study for a system with a strong segregation energy. Our choice was directly put on the Pt-Sn system. The surface behaviour, both in equilibrium and during the kinetics of dissolution, is very different from the Cu-Pd case. In particular, we have found pure 2-D surface alloys. Finally, a quenched molecular dynamics study has allowed us to determine the relative stability of various possible surface superstructures. (author)

  6. Electrocatalysts having platium monolayers on palladium, palladium alloy, and gold alloy core-shell nanoparticles, and uses thereof

    Science.gov (United States)

    Adzic, Radoslav; Mo, Yibo; Vukmirovic, Miomir; Zhang, Junliang

    2010-12-21

    The invention relates to platinum-coated particles useful as fuel cell electrocatalysts. The particles are composed of a noble metal or metal alloy core at least partially encapsulated by an atomically thin surface layer of platinum atoms. The invention particularly relates to such particles having a palladium, palladium alloy, gold alloy, or rhenium alloy core encapsulated by an atomic monolayer of platinum. In other embodiments, the invention relates to fuel cells containing these electrocatalysts and methods for generating electrical energy therefrom.

  7. Structure of molten Al-Si alloys

    International Nuclear Information System (INIS)

    The temperature variation of the structure and microstructure of molten eutectic Al1-xSix alloys (x = 0.122 and 0.20) have been studied by neutron diffraction and small-angle neutron scattering (SANS), as well as measurements performed on pure liquid Al. All measurements have been performed at five temperatures in a heating-cooling loop. The SANS results unambiguously show that for the eutectic alloy (x = 0.122) the microstructure changes with increasing temperature in a partly reversible way while for the hypereutectic (x = 0.20) alloy the change is almost completely irreversible. This change in microstructure also manifests itself in the shape of the static structure factor S(Q)

  8. Welding of gamma titanium aluminide alloys

    Science.gov (United States)

    Smashey, Russell W. (Inventor); Kelly, Thomas J. (Inventor); Snyder, John H. (Inventor); Sheranko, Ronald L. (Inventor)

    1998-01-01

    An article made of a gamma titanium aluminide alloy is welded, as for example in the weld repair of surface cracks, by removing foreign matter from the area to be welded, first stress relieving the article, cooling the entire article to a welding temperature of from about 1000.degree. F. to about 1400.degree. F., welding a preselected region in an inert atmosphere at the welding temperature, and second stress relieving the article. Welding is preferably accomplished by striking an arc in the preselected region so as to locally melt the alloy in the preselected region, providing a filler metal having the same composition as the gamma titanium aluminide alloy of the article, and feeding the filler metal into the arc so that the filler metal is melted and fused with the article to form a weldment upon solidification.

  9. The metallurgy of high temperature alloys

    Science.gov (United States)

    Tien, J. K.; Purushothaman, S.

    1976-01-01

    Nickel-base, cobalt-base, and high nickel and chromium iron-base alloys are dissected, and their microstructural and chemical components are assessed with respect to the various functions expected of high temperature structural materials. These functions include the maintenance of mechanical integrity over the strain-rate spectrum from creep resistance through fatigue crack growth resistance, and such alloy stability expectations as microstructural coarsening resistance, phase instability resistance and oxidation and corrosion resistance. Special attention will be given to the perennial conflict and trade-off between strength, ductility and corrosion and oxidation resistance. The newest developments in the constitution of high temperature alloys will also be discussed, including aspects relating to materials conservation.

  10. High temperature alloys: their exploitable potential

    Energy Technology Data Exchange (ETDEWEB)

    Marriott, J.B.; Merz, M.; Nihoul, J.; Ward, J. (eds.) (Commission of the European Communities, Petten (Netherlands). Joint Nuclear Research Center; NET-TEAM, Garching (DE))

    1987-01-01

    This book is the proceedings of a conference dealing with fundamental and technical aspects of the applications of high temperature alloys. It is split into five sections which cover the opening session of the conference and four further sessions covering: the theoretical and practical limits for HT alloys; the potential for development in alloys and processing; engineering considerations; the future outlook. The different sessions each included a number of invited papers followed by a series of posters and were concluded by a presentation of a 'synthesis' by a session rapporteur and general discussion. This structure is retained in the proceedings, including the discussion points in those cases where the authors have provided written answers to the questions raised. This book will be of interest to metallurgists, materials scientists, physicists and research workers in high temperature materials.

  11. Steam Initiated Surface Modification of Aluminium Alloys

    DEFF Research Database (Denmark)

    Din, Rameez Ud

    , crystalline nano-particles, role of steam-based treatment on adhesion of industrially applied powder coating, and investigations of a failed painted aluminium window profile due to defects in the extruded profile. Chapters 13 and 14 describe the overall discussion, conclusions and future work based......The extensive demand of aluminium alloys in various industries such as in transportationis mainly due to the high strength to weight ratio, which could be translated into fuel economy and efficiency. Corrosion protection of aluminium alloys is an important aspect for all applications which includes...... the use of aluminium alloys in the painted form requiring a conversion coating to improve the adhesion. Chromate based conversion coating processes are extremely good for these purposes, however the carcinogenic and toxic nature of hexavalent chromium led to the search for more benign and eco...

  12. Structure of molten Al-Si alloys

    Energy Technology Data Exchange (ETDEWEB)

    Dahlborg, U. [CNRS, Ecole des Mines, Nancy, France; Besser, M. [Ames Laboratory; Calvo-Dahlborg, M. [CNRS, Ecole des Mines, Nancy, France; Cuello, G. [Institut Laue-Langevin (ILL); Dewhurst, C. D. [Institut Laue-Langevin (ILL); Kramer, Matthew J. [Ames Laboratory; Morris, James R [ORNL; Sordelet, Daniel [Ames Laboratory

    2007-01-01

    The temperature variation of the structure and microstructure of molten eutectic Al{sub 1-x}Si{sub x} alloys (x = 0.122 and 0.20) have been studied by neutron diffraction and small-angle neutron scattering (SANS), as well as measurements performed on pure liquid Al. All measurements have been performed at five temperatures in a heating-cooling loop. The SANS results unambiguously show that for the eutectic alloy (x = 0.122) the microstructure changes with increasing temperature in a partly reversible way while for the hypereutectic (x = 0.20) alloy the change is almost completely irreversible. This change in microstructure also manifests itself in the shape of the static structure factor S(Q).

  13. High-strength iron aluminide alloys

    Energy Technology Data Exchange (ETDEWEB)

    McKamey, C.G.; Maziasz, P.J.

    1996-06-01

    Past studies have shown that binary Fe{sub 3}Al possesses low creep-rupture strength compared to many other alloys, with creep-rupture lives of less than 5 h being reported for tests conducted at 593{degrees}C and 207 MPa. The combination of poor creep resistance and low room-temperature tensile ductility due to a susceptibility to environmentally-induced dynamic hydrogen embrittlement has limited use of these alloys for structural applications despite their excellent corrosion properties. With regard to the ductility problem, alloy development efforts have produced significant improvements, with ductilities of 10-20% and tensile yield strengths as high as 500 MPa being reported. Likewise, initial improvements in creep resistance have been realized through small additions of Mo, Nb, and Zr.

  14. Oxygen diffusion in vanadium-based alloys

    International Nuclear Information System (INIS)

    The experimental study of transport and equilibrium properties of oxygen in vanadium-based alloys was made by EMF measurements on solid electrolytic cells over the temperature range of 873 to 14230K. The oxygen diffusion in vanadium was not significantly modified by small additions of Ti, Cr, Ni, Nb and Ta. The increase in the activation energy for oxygen diffusion in the V-based alloys containing Cr, Ni, Nb and Ta probably reflects the effect of these substitutional solutes on the activity coefficient of oxygen. The oxygen activity was increased by the addition of 1 at % of Cr, Ni and Nb, and decreased by the addition of Ti and Ta. However, the effects in the alloys containing Nb and Ta are very small

  15. Steam generated conversion coating on aluminium alloys

    DEFF Research Database (Denmark)

    Din, Rameez Ud; Jellesen, Morten Stendahl; Ambat, Rajan

    and growth of oxide film on different intermetallic particles and corrosion behaviour of such alloys.Surface morphology was observed by using FEG-SEM, EDX and FIB-SEM. Metal oxide surface characterization and compositional depth profiling were investigated by using XPS and GD-OES respectively......Aluminium and its alloys are widely used in aerospace industry owing to their high strength to weight ratio. The surface of aluminium under normal conditions has a thin oxide film (2.5-10 nm) responsible for its inherent corrosion resistance. This oxide film can further be converted or transformed......) depending on the preparation parameters/conditions. Moreover, with the knowledge of factors controlling film growth, composition and morphology, such oxide layers carry huge potential for practical applications. Pure aluminium (AA1090, 99.94 wt. %) and other aluminium alloy surfaces were exposed to high...

  16. Glow discharge amorphous silicon tin alloys

    Energy Technology Data Exchange (ETDEWEB)

    Mahan, A H; Sanchez, A; Williamson, D L; von Roedern, B; Madan, A

    1984-06-01

    We present basic density of states, photoresponse, and transport measurements made on low bandgap a-SiSn:H alloys produced by RF glow discharge deposition of SiH/sub 4/, H/sub 2/ and Sn(CH/sub 3/)/sub 4/. Although we demonstrate major changes in the local bonding structure and the density of states, the normalized photoresponse still remains poor. We provide evidence that two types of defect levels are produced with Sn alloying, and that the resultant density of states increase explains not only the n- to p-type conductivity transition reported earlier, but also the photoresponse behavior. We also report that a-SiSn:H can be doped with P. From our device analysis we suggest that in order to improve the alloy performance significantly, the density of states should be decreased to levels comparable to or lower than those presently obtained in a-Si:H.

  17. Alloy 800 welding experience at UKAEA Springfields

    International Nuclear Information System (INIS)

    Investigatins into the welding of alloy 800 at the Reactor Fuel Element Laboratories, Springfields, commenced about three years ago following an extended development programme on tube to tube plate welding of low alloy and stainless steels for the Prototype Fast Reactor. The techniques and approach developed for critical fuel element welding applications had proved equally suitable for the precision welding requirements on the much heavier sections of heat exchangers. It had been demonstrated that the same control of weld quality and profile could be achieved with consistency and the permissible range of critical parameters could be readily defined. Because of this, development work was continued to include other materials, such as alloy 800, which might be of potential use. The tungsten inert gas (T.I.G.) arc welding process is used, and the equipment, including the control system, is described. Tube to tube-plate welding, and tube to tube butt welding, are discussed. (author)

  18. Irradiation creep of vanadium-base alloys

    Energy Technology Data Exchange (ETDEWEB)

    Tsai, H.; Billone, M.C.; Strain, R.V.; Smith, D.L. [Argonne National Lab., IL (United States); Matsui, H. [Tohoku Univ. (Japan)

    1998-03-01

    A study of irradiation creep in vanadium-base alloys is underway with experiments in the Advanced Test Reactor (ATR) and the High Flux Isotope Reactor (HFIR) in the United States. Test specimens are thin-wall sealed tubes with internal pressure loading. The results from the initial ATR irradiation at low temperature (200--300 C) to a neutron damage level of 4.7 dpa show creep rates ranging from {approx}0 to 1.2 {times} 10{sup {minus}5}/dpa/MPa for a 500-kg heat of V-4Cr-4Ti alloy. These rates were generally lower than reported from a previous experiment in BR-10. Because both the attained neutron damage levels and the creep strains were low in the present study, however, these creep rates should be regarded as only preliminary. Substantially more testing is required before a data base on irradiation creep of vanadium alloys can be developed and used with confidence.

  19. Microstructure and Slip Character in Titanium Alloys

    Directory of Open Access Journals (Sweden)

    D. Banerjee

    1986-04-01

    Full Text Available Influence of microstructures in titanium alloys on the basic parameters of deformation behaviour such as slip character, slip length and slip intensity have been explored. Commercial titanium alloys contain the hexagonal close packed (alpha and body centred cubic (bita phases. Slip in these individual phases is shown to be dependent on the nature of alloying elements through their effect on phase stability as related to decomposition into ordered or w structures. When alpha and bita coexist, their relative crystallographic orientations, size, shape and volume fraction, control the nature of slip. For a given composition, structure may be manipulated through appropriate thermomechanical treatment to obtain the desired deformation behaviour and therefore fracture mode.

  20. Fatigue - corrosion of endoprosthesis titanium alloys.

    Science.gov (United States)

    Cornet, A; Muster, D; Jaeger, J H

    1979-01-01

    Commercial total hip prostheses often show certain metallurgical faults (porosities, coarse grains, growth dendrites, carbide networks). In order to investigate more accurately the role played by these different parameters in prostheses failure we performed a large number of systematic corrosion, fatigue and fatigue - corrosion tests on these materials and on commercial total hip prostheses. Ultimate strengthes seem to be reached for cast cobalt alloys, whereas titanium alloys, such as Ta 6 V, present very high fatigue limit under corrosion. Thus, rotative bending fatigue - corrosion tests in biological environment provide values about 50 DaN/mm2. This value, is nevertheless appreciably higher than those obtained with stellites and stainless steel. Titanium alloys, because of their mechanical performances, their weak Young's modulus (11000 DaN/mm2) and their relative lightness (4.5. g/cm3), which are associated with a good biocompatibility, seem very promising for permanent implants realisation.

  1. Calorimetry studies on U-Cr alloys

    International Nuclear Information System (INIS)

    A calorimetric study of Uranium-Chromium system is of interest on both basic and applied fronts. With the advent of U-Pu-Zr alloy as the fuel, in combination with ferritic-martensitic steel as the cladding material, the metal fuelled fast reactors constitute the second major step in Indian nuclear power program. In such a context, a fundamental investigation on the high temperature phase stability of U-Cr alloys is of particular relevance in getting further insight in to the complex issue of the metallurgical compatibility of ferritic steels with metallic Uranium-Zirconium fuel. It may be added that following U-Fe, and U-Zr binaries, the U-Cr constitutes one of the important subsystems of the complex U-Zr-Pu-Fe- Cr-Mn-Si-V-Nb-C-N multinary system. In the current study, the results of calorimetry investigations on U, U-2, 3, 7, 15wt. % Cr alloys are presented

  2. Non-alloyed Ni3Al based alloys – preparation and evaluation of mechanical properties

    Directory of Open Access Journals (Sweden)

    J. Malcharcziková

    2013-07-01

    Full Text Available The paper reports on the fabrication and mechanical properties of Ni3Al based alloy, which represents the most frequently used basic composition of nickel based intermetallic alloys for high temperature applications. The structure of the alloy was controlled through directional solidification. The samples had a multi-phase microstructure. The directionally solidified specimens were subjected to tensile tests with concurrent measurement of acoustic emission (AE. The specimens exhibited considerable room temperature ductility before fracture. During tensile testing an intensive AE was observed.

  3. Development of environmentally friendly cast alloys. High-zinc Al alloys

    Directory of Open Access Journals (Sweden)

    W.K. Krajewski

    2010-10-01

    Full Text Available Purpose: The main purpose of this paper is presenting the results obtained in years 2007 – 2010 in frame of the project Marie Curie Transfer of Knowledge – CastModel. The project was focused, among others, at elaborating new, environmentally friendly cast alloys based on the Al-Zn system. Particularly, efforts were aimed at improving ductility of the sand cast high-zinc aluminium alloys (HZnAl by using the newly elaborated master alloys, based on the Al-Zn-Ti system.Design/methodology/approach: The presented work is focused on the nucleation of the high-zinc Al-20 wt% Zn (HZnAl AlZn20 alloy, known as the high damping one, aiming at improving plastic properties of the sand castings. The melted alloy was nucleated with AlTi5B1 (TiBAl and AlTi3C0.15 (TiCAl refiners as well as with the newly introduced ZnAl-Ti3 one. During the research the following experimental techniques were used: LM, SEM-EBSD, EDS, TA, DSC, Quantitative Metallography, UTS, Elongation and Attenuation coefficient measurements.Findings: During the performed examinations it was found out that significant increasing of the grain population of the inoculated alloy increases plasticity represented by elongation. The attenuation coefficient of the nucleated alloy, measured using an Olympus Epoch XT device, preserves its high value. The results obtained allow to characterize the examined AlZn20 alloy as promissive, having good strength and damping properties as well as the environmentally friendly alloy because of its comparatively low melting temperatures.Practical implications: The grain-refined high-zinc aluminium alloys can be used as the high damping substitutes of the traditional, more energy consumable Fe-based foundry alloys.Originality/value: The newly elaborated ZnAl-Ti based master alloys show high refining potency and quick dissolution in low melting temperatures of about 500°C, and are the promissive alternatives of the traditional AlTi-based ones.

  4. Role of Stress in Thin Film Alloy Thermodynamics: Competition between Alloying and Dislocation Formation

    International Nuclear Information System (INIS)

    Using scanning tunneling microscopy (STM) and first-principles local-spin-density-approximation calculations to study submonolayer films of Co1-cAg c/Ru( 0001) alloys, we have discovered a novel phase-separation mechanism. When the Ag concentration c exceeds 0.4, the surface phase separates between a dislocated, pure Ag phase and a pseudomorphically strained Co0.6Ag 0.4 surface alloy. We attribute the phase separation to the competition between two stress relief mechanisms: surface alloying and dislocation formation. The agreement between STM measurements and our calculated phase diagram supports this interpretation

  5. First-principles density functional calculations for Mg alloys: A tool to aid in alloy development

    International Nuclear Information System (INIS)

    In studying the thermodynamics and phase stability of Mg alloys, one is often confronted with the lack of accurate, quantitative experimental data. This deficiency can be partially rectified via first-principles calculations based on density functional theory. In this paper, we will illustrate the utility of first-principles energetics for Mg alloys using three case studies (i) formation energies of ordered/disordered solid phases; (ii) solute-vacancy binding energies in Mg; (iii) point defect formation energies of β-Mg17Al12. These first-principles calculations can provide highly accurate thermodynamic and kinetic information for Mg alloys.

  6. The influence of copper on the SCC of alloy 600 and alloy 690 steam generator tubes

    International Nuclear Information System (INIS)

    Capsule tests have been performed on alloy 600 and alloy 690 steam generator tubes in acid sulfate environments. The most important result is that alloy 690, which is completely immune in this type of environment, becomes very susceptible to SCC in the presence of copper, even when it is added to the solution under the metallic form. Although the role of copper is not fully understood, its influence can not be explained only by an effect on the electrochemical potential. Complexation, adsorption and diffusion properties of copper could play an important role. (authors)

  7. Master alloy for manufacture of stainless and refractory steels and alloys

    International Nuclear Information System (INIS)

    The master alloy contains iron, 0.01 to 0.03% carbon, 0.1 to 2.0% manganese, 0.01 to 0.2% silicon, possibly impurities, such as traces of up to 0.015% sulphur, up to 0.01% phosphorus, 0.01%. nitrogen, 0.1% copper, up to 0.01% cobalt and traces of up to 0.05% arsenic, tin, lead, zinc or bismuth separate or in combination. The master alloy is used in the manufacture of steels and alloys for the chemical industry and for nuclear power. (B.S.)

  8. Characterization for Fusion Candidate Vanadium Alloys

    Institute of Scientific and Technical Information of China (English)

    T. Muroga; T. Nagasaka; J. M. Chen; Z. Y. Xu; Q. Y. Huang; y. C. Wu

    2004-01-01

    This paper summarizes recent achievements in the characterization of candidate vanadium alloys obtained for fusion in the framework of the Japan-China Core University Program.National Institute for Fusion Science (NIFS) has a program of fabricating high-purity V-4Cr4Ti alloys. The resulting products (NIFS-HEAT-1,2), were characterized by various research groups in the world including Chinese partners. South Western Institute of Physics (SWIP) fabricated a new V-4Cr-4Ti alloy (SWIP-Heat), and carried out a comparative evaluation of hydrogen embrittlement of NIFS-HEATs and SWIP-Heat. The tensile test of hydrogen-doped alloys showed that the NIFS-HEAT maintained the ductility to relatively high hydrogen levels.The comparison of the data with those of previous studies suggested that the reduced oxygen level in the NIFS-HEATs should be responsible for the increased resistance to hydrogen embrittlement.Based on the chemical analysis data of NIFS-HEATs and SWIP-Heats, neutron-induced activation was analyzed in Institute of Plasma Physics (IPP-CAS) as a function of cooling time after the use in the fusion first wall. The results showed that the low level of Co dominates the activity up to 50 years followed by a domination of Nb or Nb and Al in the respective alloys. It was suggested that reduction of Co and Nb, both of which are thought to have been introduced via cross-contamination into the alloys from the molds used should be crucial for reducing further the activation.

  9. Fast LIBS Identification of Aluminum Alloys

    Directory of Open Access Journals (Sweden)

    Tawfik W.

    2007-04-01

    Full Text Available Laser-induced breakdown spectroscopy (LIBS has been applied to analysis aluminum alloy targets. The plasma is generated by focusing a 300 mJ pulsed Nd: YAG laser on the target in air at atmospheric pressure. Such plasma emission spectrum was collected using a one-meter length wide band fused-silica optical fiber connected to a portable Echelle spectrometer with intensified CCD camera. Spectroscopic analysis of plasma evolution of laser produced plasmas has been characterized in terms of their spectra, electron density and electron temperature assuming the LTE and optically thin plasma conditions. The LIBS spectrum was optimized for high S/N ratio especially for trace elements. The electron temperature and density were determined using the emission intensity and stark broadening, respectively, of selected aluminum spectral lines. The values of these parameters were found to change with the aluminum alloy matrix, i.e. they could be used as a fingerprint character to distinguish between different aluminum alloy matrices using only one major element (aluminum without needing to analysis the rest of elements in the matrix. Moreover, It was found that the values of T e and N e decrease with increasing the trace elements concentrations in the aluminum alloy samples. The obtained results indicate that it is possible to improve the exploitation of LIBS in the remote on-line industrial monitoring application, by following up only the values of T e and N e for aluminum in aluminum alloys as a marker for the correct alloying using an optical fiber probe.

  10. Irradiation creep of dispersion strengthened copper alloy

    Energy Technology Data Exchange (ETDEWEB)

    Pokrovsky, A.S.; Barabash, V.R.; Fabritsiev, S.A. [and others

    1997-04-01

    Dispersion strengthened copper alloys are under consideration as reference materials for the ITER plasma facing components. Irradiation creep is one of the parameters which must be assessed because of its importance for the lifetime prediction of these components. In this study the irradiation creep of a dispersion strengthened copper (DS) alloy has been investigated. The alloy selected for evaluation, MAGT-0.2, which contains 0.2 wt.% Al{sub 2}O{sub 3}, is very similar to the GlidCop{trademark} alloy referred to as Al20. Irradiation creep was investigated using HE pressurized tubes. The tubes were machined from rod stock, then stainless steel caps were brazed onto the end of each tube. The creep specimens were pressurized by use of ultra-pure He and the stainless steel caps subsequently sealed by laser welding. These specimens were irradiated in reactor water in the core position of the SM-2 reactors to a fluence level of 4.5-7.1 x 10{sup 21} n/cm{sup 2} (E>0.1 MeV), which corresponds to {approx}3-5 dpa. The irradiation temperature ranged from 60-90{degrees}C, which yielded calculated hoop stresses from 39-117 MPa. A mechanical micrometer system was used to measure the outer diameter of the specimens before and after irradiation, with an accuracy of {+-}0.001 mm. The irradiation creep was calculated based on the change in the diameter. Comparison of pre- and post-irradiation diameter measurements indicates that irradiation induced creep is indeed observed in this alloy at low temperatures, with a creep rate as high as {approx}2 x 10{sup {minus}9}s{sup {minus}1}. These results are compared with available data for irradiation creep for stainless steels, pure copper, and for thermal creep of copper alloys.

  11. Ultraprecision microelectroforming of metals and metal alloys

    Science.gov (United States)

    Loewe, Holger; Ehrfeld, Wolfgang; Diebel, Joerg

    1997-09-01

    In recent years, microsystem technology and its growing importance for actuators, sensors, optics and microfluidics, only to name a few, have gained a lot of attention. Specific applications demand fabrication techniques allowing a fast and reliable replication of microstructure products in a variety of materials. An important technique for replication processes of microstructures in many applications of microsystem technology are microelectroforming processes, generating a variety of metals and metal alloys with tailored characteristics. Here, new results in the development of alloys for specific applications as well as their applications are reported: (1) Newly developed alloys: Nickel-iron alloys enable the production of soft magnetic microstructures e.g. for specific applications in microactuators. Nickel-cobalt and Nickel-tungsten alloys have been employed for the manufacture of microstructured tools with excellent mechanical properties regarding wear and mechanical durability. These tools have been applied to hot-embossing and injection molding processes successfully. (2) Microelectroforming within the frame of the LIGA technique allows the manufacturing of extremely precise electrodes with various cross-sections and heights for (mu) - electro discharge machining. The combination of these techniques enables the production of microstructures from non- electrodepositable materials, like stainless steel e.g. for large scale replication processes. (3) The precision of microelectroforming enables the replication of structured surfaces on a nanoscale for molecular microelectronics or special applications. The new types of alloys reported here significantly enlarge the applicability of microelectroforming processes for tool fabrication or direct use. Moreover combining this process with other microstructuring processes like injection molding or (mu) -EDM techniques generates a powerful tool for microsystem technology.

  12. Liquid eutectic alloys as a cluster solutions

    Directory of Open Access Journals (Sweden)

    I. Shcherba

    2008-11-01

    Full Text Available Purpose: In this research work the results of structure studies for Al0.88Si0.12, Bi0.995Cu0.005, Al0.83Cu0.17 eutecticand Co0.05Cu0.95 peritectic melts have been presented. The structure parameters of molten alloys are comparedwith ones for liquid pure components and with model values.Design/methodology/approach: The structure in liquid state has been studied with use of X-raydiffractometer containing special attachment for investigation of liquid metallic alloys. The system was equippedwith special camera for sample, filled with pure helium in order to avoid the oxidation. Experimental data wereinterpreted with using of random atomic distribution model and self-associated one.Findings: The research has shown that structure of liquid alloys Al0.88Si0.12, Bi0.995Cu0.005, Al0.83Cu0.17 andCo0.05Cu0.95 shows the deviation from random atomic distribution model and these alloys in liquid state attemperatures not far from melting point can be considered as cluster solutions.Practical implications: Existence of clusters in eutectic and peritectic melts influence the structure andproperties of corresponding solid alloys, that is important for casting, soldering, welding and at producing ofcomposite materials on the base of eutectic matrix.Originality/value: Cluster structure of eutectic melts is responsible for behaviour of structure and physicalchemicalproperties. The change of this structure allows to improve the properties of solidificated alloys, bothcrystalline and amorphous.

  13. Microstructural and magnetic behavior of an equiatomic NiCoAlFe alloy prepared by mechanical alloying

    Energy Technology Data Exchange (ETDEWEB)

    Gómez-Esparza, C.D.; Baldenebro-López, F.J.; Santillán-Rodríguez, C.R.; Estrada-Guel, I.; Matutes-Aquino, J.A.; Herrera-Ramírez, J.M., E-mail: martin.herrera@cimav.edu.mx; Martínez-Sánchez, R.

    2014-12-05

    Highlights: • Equiatomic NiCoAlFe powder alloys were synthesized by mechanical alloying. • The nanocrystalline alloys were characterized after milled and annealed conditions. • In alloyed and annealed powders, only BCC and FCC structure phases were observed. • Magnetic properties are strongly affected by the phases formed after annealing. - Abstract: Equiatomic NiCoAlFe powder alloys were synthesized by mechanical alloying. The microstructural evolution of the mechanically alloyed powders at different times was followed with X-ray diffraction and scanning electron microscopy. The as-mechanically alloyed powders were subjected to a rapid annealing treatment at 1273 K and 1473 K during 3 min in vacuum. X-ray diffraction studies show the structure of both, the as-mechanically alloyed and annealed powders, consisted in a mixture of nanocrystalline simple phases (FCC + BCC). Crystallite size, after annealing, still remained in nanoscale. Coercivity increased due to the decrease in crystallite size and because of the defects caused by mechanical alloying in the as-mechanically alloyed samples; then coercivity decreased due to the phenomenon of random magnetic anisotropy and tended to stabilize with longer alloying times. A similar behavior was observed in annealed samples at 1273 K. However, random magnetic anisotropy was not observed after annealing at 1473 K because crystals with larger sizes were produced, and a steady increase in coercivity was observed.

  14. The Influence of Alloy Composition and microstructure on the corrosion behaviour of Cu-Ni alloys in seawater

    NARCIS (Netherlands)

    Drolenga, L.J.P.; IJsseling, F.P.; Kolster, B.H.

    1983-01-01

    The aim of the study was to relate the general corrosion behaviour of CuNi 10-alloys in seawater with its iron content and microstructure. To that end the microstructure of four commercial alloys with various Fe-contents (1.20-1.78%) and there laboratory melted alloys with various Fe-contents (1.5-2

  15. Modeling of Alternative Compositions of Recycled Wrought Aluminum Alloys

    Science.gov (United States)

    Kevorkijan, Varužan

    2013-08-01

    Nowadays, a significant part of postconsumed wrought aluminum scrap is still used for the production of comparatively cheaper cast alloys, in that way losing an important part of the potential added value. The share of postconsumed scrap in wrought aluminum alloys could be increased either by sorting to fractions with the required chemical composition and/or by broadening the standard compositional tolerance limits of alloying elements. The first solution requires hand or automatic sorting of postconsumed scrap as alloys or groups of alloys to the degree of separation sufficient to enable the blending of standard compositions of wrought alloys; the second solution is much more radical, predicting changes in the existing standards for wrought aluminum alloys toward nonstandard alloys but yet having properties acceptable for customers. In this case, the degree of separation of incoming postconsumed scrap required is much less demanding. The model presented in this work enables the design of optimal (standard and nonstandard recycling-friendly) compositions and properties of wrought aluminum alloys with significantly increased amounts of postconsumed scrap. The following two routes were modeled in detail: (I) the blending of standard and nonstandard compositions of wrought aluminum alloys starting from postconsumed aluminum scrap sorted to various degrees simulated by the model and (II) changing the initial standard composition of wrought aluminum alloys to nonstandard "recycling-friendly" ones, with broader concentration tolerance limits of alloying elements and without influencing the selected alloy properties, specified in advance. The applied algorithms were found to be very useful in the industrial design of both procedures: (I) the computation of the required chemical composition of the scrap streams obtained by sorting (or, in other words, the postconsumed scrap sorting level), necessary for achieving the standard wrought alloy composition and (II) the

  16. Pulse reversal plating of nickel alloys

    DEFF Research Database (Denmark)

    Tang, Peter Torben

    2007-01-01

    Pulse plating has previously been reported to improve the properties of nickel and nickel alloy deposits. Typically, focus has been on properties such as grain size, hardness and smoothness. When pulse plating is to be utilised for microtechnologies such as microelectromechanical systems (MEMS......), internal stress and material distribution are even more important. With baths based upon nickel chloride, and nickel and cobalt chlorides, pulse reversal plating of both pure nickel and nickel-cobalt alloys has been used to fabricate tools for microinjection moulding. Pulse reversal plating of ternary soft...

  17. Surface segregation in HAYNES 230 alloy

    International Nuclear Information System (INIS)

    The surface segregation in the Ni-based alloy HAYNES 230 was studied by Auger Electron Spectroscopy and X-ray Photoelectron Spectroscopy between 400 and 1100 deg. C. The qualitative variations of the surface contents of S, P, W, Mo, N, Si, and Mn were determined as a function of annealing temperature and time. It was found that at 925 deg. C the maximum coverage of sulphur at the alloy surface is in the range 0.06-0.15 monolayers. Chromium evaporation from the HAYNES 230 surface under UHV conditions is clearly evidenced for annealing at 1100 deg. C

  18. Surface segregation in HAYNES 230 alloy

    Science.gov (United States)

    Pop, D.; Wolski, K.

    2006-12-01

    The surface segregation in the Ni-based alloy HAYNES 230 was studied by Auger Electron Spectroscopy and X-ray Photoelectron Spectroscopy between 400 and 1100 °C. The qualitative variations of the surface contents of S, P, W, Mo, N, Si, and Mn were determined as a function of annealing temperature and time. It was found that at 925 °C the maximum coverage of sulphur at the alloy surface is in the range 0.06-0.15 monolayers. Chromium evaporation from the HAYNES 230 surface under UHV conditions is clearly evidenced for annealing at 1100 °C.

  19. Model for magnetic-nonmagnetic binary alloys

    Energy Technology Data Exchange (ETDEWEB)

    Razafimandimby, H. [Departement de Physique, Universite de Toliara, 601 Toliara (Madagascar); Randrianasoloharisoa, D. [LPMR, Universite d' Antananarivo (Madagascar); Rakotomahevitra, A. [Departement des Sciences Exactes, Universite de Mahajanga, BP 155 (Madagascar); Parlebas, J.C. [IPCMS, UMR 7504 CNRS-Universite Louis Pasteur, 23 rue du Loess, BP 43, 67034 Strasbourg (France)

    2007-10-15

    An extension of a mean-field approximation (MFA) developed within standard basis operators (SBO) is used to study magnetism in magnetic-nonmagnetic binary alloys. The Curie temperature is calculated from the free energy within the framework of the present approach. The calculated results are in fair agreement with the theoretical results of other research groups for the same problem but utilizing other methods. Finally, the case of NiPt alloys is briefly examined as an example test for the comparison with experiment. (copyright 2007 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  20. Hydrogen pickup mechanism of zirconium alloys

    Science.gov (United States)

    Couet, Adrien

    Although the optimization of zirconium based alloys has led to significant improvements in hydrogen pickup and corrosion resistance, the mechanisms by which such alloy improvements occur are still not well understood. In an effort to understand such mechanisms, a systematic study of the alloy effect on hydrogen pickup is conducted, using advanced characterization techniques to rationalize precise measurements of hydrogen pickup. The hydrogen pick-up fraction is accurately measured for a specially designed set of commercial and model alloys to investigate the effects of alloying elements, microstructure and corrosion kinetics on hydrogen uptake. Two different techniques to measure hydrogen concentrations were used: a destructive technique, Vacuum Hot Extraction, and a non-destructive one, Cold Neutron Prompt Gamma Activation Analysis. The results indicate that hydrogen pickup varies not only from alloy to alloy but also during the corrosion process for a given alloy. For instance Zircaloy type alloys show high hydrogen pickup fraction and sub-parabolic oxidation kinetics whereas ZrNb alloys show lower hydrogen pickup fraction and close to parabolic oxidation kinetics. Hypothesis is made that hydrogen pickup result from the need to balance charge during the corrosion reaction, such that the pickup of hydrogen is directly related to (and indivisible of) the corrosion mechanism and decreases when the rate of electron transport or oxide electronic conductivity sigmao xe through the protective oxide increases. According to this hypothesis, alloying elements (either in solid solution or in precipitates) embedded in the oxide as well as space charge variations in the oxide would impact the hydrogen pick-up fraction by modifying sigmaox e, which drives oxidation and hydriding kinetics. Dedicated experiments and modelling were performed to assess and validate these hypotheses. In-situ electrochemical impedance spectroscopy (EIS) experiments were performed on Zircaloy-4 tubes

  1. Mechanical Properties of Niobium Alloyed Gray Iron

    OpenAIRE

    Hanna, Ivil

    2011-01-01

    The influence of adding an amount of 0.1% and 0.3% niobium to the gray iron alloy used for brake discs, these disc materials are called disc 16 respective 17, have been investigated at RT (room temperature). That is together with two other alloys, the reference disc which contains 0.32% molybdenum but lacks niobium and another one with neither niobium nor molybdenum in it, this is called disc material 15. Focus in this thesis work is on the mechanical properties of the studied materials and f...

  2. Mechanism of Nickel-Aluminium Alloy Electroplating

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    The effect of operating conditions on the aluminium content of Ni-Al alloy deposit and the catalytic function of NaF on electrodeposition in the nonaqueous solution containing aluminium are investigated.The results indicate that the plated aluminuim content will be increased with the rise of current density in a given range.When the current density is 2.5A/dm2,nickle-aluminium alloy containing 13.1 wt% aluminium will be deposited.The plated aluminium content will be increased by 2wt% as 0.1mol/L NaF is added to the bath.

  3. Liquid eutectic alloys as a cluster solutions

    OpenAIRE

    I. Shcherba; Shtablavyi, I.; S. Mudry

    2008-01-01

    Purpose: In this research work the results of structure studies for Al0.88Si0.12, Bi0.995Cu0.005, Al0.83Cu0.17 eutecticand Co0.05Cu0.95 peritectic melts have been presented. The structure parameters of molten alloys are comparedwith ones for liquid pure components and with model values.Design/methodology/approach: The structure in liquid state has been studied with use of X-raydiffractometer containing special attachment for investigation of liquid metallic alloys. The system was equippedwith...

  4. Rapidly solidified titanium alloys by melt overflow

    Science.gov (United States)

    Gaspar, Thomas A.; Bruce, Thomas J., Jr.; Hackman, Lloyd E.; Brasmer, Susan E.; Dantzig, Jonathan A.; Baeslack, William A., III

    1989-01-01

    A pilot plant scale furnace was designed and constructed for casting titanium alloy strips. The furnace combines plasma arc skull melting techniques with melt overflow rapid solidification technology. A mathematical model of the melting and casting process was developed. The furnace cast strip of a suitable length and width for use with honeycomb structures. Titanium alloys Ti-6Al-4V and Ti-14Al-21 Nb were successfully cast into strips. The strips were evaluated by optical metallography, microhardness measurements, chemical analysis, and cold rolling.

  5. Elastic anomalies in Fe-Cr alloys.

    Science.gov (United States)

    Zhang, Hualei; Wang, Guisheng; Punkkinen, Marko P J; Hertzman, Staffan; Johansson, Börje; Vitos, Levente

    2013-05-15

    Using ab initio alloy theory, we determine the elastic parameters of ferromagnetic and paramagnetic Fe(1-c)Cr(c) (0 ≤ c ≤ 1) alloys in the body centered cubic crystallographic phase. Comparison with the experimental data demonstrates that the employed theoretical approach accurately describes the observed composition dependence of the polycrystalline elastic moduli. The predicted single-crystal elastic constants follow complex anomalous trends, which are shown to originate from the interplay between magnetic and chemical effects. The nonmonotonic composition dependence of the elastic parameters has marked implications on the micro-mechanical properties of ferrite stainless steels. PMID:23604218

  6. Process for alloying uranium and niobium

    Science.gov (United States)

    Holcombe, Cressie E.; Northcutt, Jr., Walter G.; Masters, David R.; Chapman, Lloyd R.

    1991-01-01

    Alloys such as U-6Nb are prepared by forming a stacked sandwich array of uraniun sheets and niobium powder disposed in layers between the sheets, heating the array in a vacuum induction melting furnace to a temperature such as to melt the uranium, holding the resulting mixture at a temperature above the melting point of uranium until the niobium dissolves in the uranium, and casting the uranium-niobium solution. Compositional uniformity in the alloy product is enabled by use of the sandwich structure of uranium sheets and niobium powder.

  7. Corrosion resistance of Mg-RE-Zr alloys

    OpenAIRE

    A. Kiełbus; J. Michalska; T. Rzychoń

    2007-01-01

    Purpose: Magnesium alloys are widely used in the automotive and aerospace industries. Data concerning corrosion of Mg alloys are numerous, but those concerning Mg-RE alloys are scarce. In this paper, the corrosion behavior of cast magnesium alloys containing rare earth elements (WE54, WE43 and Elektron21) were investigated by immersion test in 3.5% NaCl for times up to 7 days.Design/methodology/approach: The study was conducted on WE54, WE43 and Elektron 21 alloys in the as-cast condition. I...

  8. Indentation toughness of Mo5Si3-based alloys

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    The indentation toughness of Mo5Si3 -based phases was studied with regard to different alloying elements, amount of alloying addition as well as the presence of secondary phases. Cr, Ti, Nb, Ni and Co were added as alloying elements. The results show that the indentation fracture toughness of Mo5Si3 increases with the alloying additions, from 2.4 Mpa *m1/2 for mon olithic to just over 3 Mpa*m1/2 for highly alloyed Mo5Si3. Small volume fractions of brittle secondary phases may have a positive impact on the inde ntation toughness; while larger fractions seems to lower the toughness.

  9. Magnetic properties of nanostructural γ-Ni-28Fe alloy

    Institute of Scientific and Technical Information of China (English)

    LIU Yin; QIN Xiao-ying; QIU Tai

    2006-01-01

    Nanostructural γ-Ni-28Fe alloy (nano γ-Ni-28Fe) was successfully prepared by mechanochemical alloying(MCA). The relationship between the microstructure and the synthesis conditions was investigated by using XRD, TEM, SEM as well as BET analyzer. The results show that nano γ-Ni-28Fe alloy is composed ora gamma phase (FCC structure). Its grain size is about 20 nm at reduction temperature below 600 ℃. The magnetic measurements indicate that the saturation magnetization ofnano γ-Ni-28Fe alloy to its decrease of the grain size and chemical composition in nano γ-Ni-28Fe alloy.

  10. Challenges for research and development of new aluminum alloys

    Directory of Open Access Journals (Sweden)

    D. Vojtĕch

    2010-07-01

    Full Text Available Modern trends in research and development of new aluminum alloys are characterized in the present work. Although conventional wrought and casting Al-based alloys show good specific strength, as compared to steels or Ti-based alloys, there is still a potential for significant improvement of their performance. It consists in application of new alloying elements, mainly transition metals, and uncommon processing routes, for example powder metallurgy. By this way, qualitatively new materials with ultra high strength and excellent thermal stability can be developed. However, there are many questions to be answered before new alloys can be competitive to conventional Al-based materials.

  11. Annex 5 - Fabrication of U-Al alloy

    International Nuclear Information System (INIS)

    Alloy U-Al with low content of aluminium is often used for fabrication of fuel elements because it is stable under moderate neutron flux density. Additionally this type of alloys show much better characteristics than pure uranium under reactor operating conditions (temperature, mechanical load, corrosion effect of water). This report contains the analysis of the phase diagram of U-Al alloy with low content of aluminium, applied procedure for alloying and casting with detailed description of equipment. Characteristics of the obtained alloy are described and conclusions about the experiment and procedure are presented

  12. A review on hot tearing of magnesium alloys

    Directory of Open Access Journals (Sweden)

    Jiangfeng Song

    2016-09-01

    Full Text Available Hot tearing is often a major casting defect in magnesium alloys and has a significant impact on the quality of their casting products. Hot tearing of magnesium alloys is a complex solidification phenomenon which is still not fully understood, it is of great importance to investigate the hot tearing behaviour of magnesium alloys. This review attempts to summarize the investigations on hot tearing of magnesium alloys over the past decades. The hot tearing criteria including recently developed Kou's criterion are summarized and compared. The numeric simulation and assessing methods of hot tearing, factors influencing hot tearing, and hot tearing susceptibility (HTS of magnesium alloys are discussed.

  13. Structure of nanocomposites of Al–Fe alloys prepared by mechanical alloying and rapid solidification processing

    Indian Academy of Sciences (India)

    S S Nayak; B S Murty; S K Pabi

    2008-06-01

    Structures of Al-based nanocomposites of Al–Fe alloys prepared by mechanical alloying (MA) and subsequent annealing are compared with those obtained by rapid solidification processing (RSP). MA produced only supersaturated solid solution of Fe in Al up to 10 at.% Fe, while for higher Fe content up to 20 at.% the nonequilibrium intermetallic Al5Fe2 appeared. Subsequent annealing at 673 K resulted in more Al5Fe2 formation with very little coarsening. The equilibrium intermetallics, Al3Fe (Al13Fe4), was not observed even at this temperature. In contrast, ribbons of similar composition produced by RSP formed fine cellular or dendritic structure with nanosized dispersoids of possibly a nano-quasicrystalline phase and amorphous phase along with -Al depending on the Fe content in the alloys. This difference in the product structure can be attributed to the difference in alloying mechanisms in MA and RSP.

  14. Characteristics of 14Cr-ODS ferritic alloy fabricated by mechanically alloying and microwave sintering

    Energy Technology Data Exchange (ETDEWEB)

    Zhenhua, Yao [State Key Laboratory of Materia Processing and Die & Mould Technology, Huazhong University of Science and Technology, Wuhan 430074 (China); Weihao, Xiong, E-mail: whxiong@mail.hust.edu.cn [State Key Laboratory of Materia Processing and Die & Mould Technology, Huazhong University of Science and Technology, Wuhan 430074 (China); Bin, Huang; Qingqing, Yang [State Key Laboratory of Materia Processing and Die & Mould Technology, Huazhong University of Science and Technology, Wuhan 430074 (China); Jiang, Jianjun [School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan 430074 (China)

    2015-06-15

    14Cr-ODS ferritic alloys were fabricated by microwave sintering and conventional vacuum sintering. The results showed that the sintering time could be reduced and the sintering temperature could be decreased effectively by adoption of microwave sintering. The tensile strength of the alloy microwave sintered at 1250 °C and the alloy vacuum sintered at 1350 °C were 691.4 MPa and 521.5 MPa respectively. The superior strength of microwave sintered one would be attributed to finer grain size, which was resulted from the shorter sintering time and lower sintering temperature. The elongation of microwave sintered alloy was worse than that of the vacuum sintering one. Nano-oxide precipitates were dispersed homogeneously in the Fe-based matrix, and their size was mostly ranged from several nm to more than 20 nm.

  15. Manufacturing of self-passivating W-Cr-Si alloys by mechanical alloying and HIP

    Energy Technology Data Exchange (ETDEWEB)

    Lopez-Ruiz, P. [CEIT and Tecnun (University of Navarra), E-20018 San Sebastian (Spain); Koch, F. [Max-Planck-Institut fuer Plasmaphysik, EURATOM Association, D-85748 Garching (Germany); Ordas, N. [CEIT and Tecnun (University of Navarra), E-20018 San Sebastian (Spain); Lindig, S. [Max-Planck-Institut fuer Plasmaphysik, EURATOM Association, D-85748 Garching (Germany); Garcia-Rosales, C., E-mail: cgrosales@ceit.es [CEIT and Tecnun (University of Navarra), E-20018 San Sebastian (Spain)

    2011-10-15

    Self-passivating tungsten-based alloys may provide a major safety advantage in comparison with pure tungsten, which is presently the main candidate material for the plasma-facing protection of future fusion power reactors. WCrSi alloys were manufactured by mechanical alloying (MA) and HIP at 1300 deg. C and 200 MPa for 1 h. Different MA conditions were investigated to obtain powders with lowest possible amount of contaminants and small and homogeneous particle and crystallite size. Milling in WC vials under Ar without process control agent provided best results. After HIP densities close to 100% were obtained. First oxidation tests on preliminary alloys showed self-passivating behavior with rates comparable to WCrSi thin films at 800 deg. C but worse performance at 1000 deg. C. In all cases a Cr{sub 2}WO{sub 6} protective layer is formed at the surface.

  16. Role of alloying additions on the properties of Cu–Al–Mn shape memory alloys

    Energy Technology Data Exchange (ETDEWEB)

    Dasgupta, Rupa, E-mail: rupadasgupta@ampri.res.in; Jain, Ashish Kumar; Kumar, Pravir; Hussain, Shahadat; Pandey, Abhishek

    2015-01-25

    Highlights: • Cu based SMAs with high transition temperature could be made using LM route. • The properties depend on alloying composition. • Property characterisation establishes feasibility of making SMAs. - Abstract: The effect of alloying seven different elements [Zn, Si, Fe, Ni, Mg, Cr and Ti] on the microstructure, hardness, phase precipitation and transformation temperature in a Cu–12.5Al–5Mn alloy with a view to possible improvements as a result of these additions is the focus of the reported study. The base alloy has been chosen keeping in mind its ability to exhibit shape memory properties and improved ductility over other Cu-based SMAs. The objective was to ascertain changes or improvements attained due to the individual tertiary additions. The samples were prepared through liquid metallurgy route using pure copper, aluminum, manganese and the respective quaternary alloying elements in right quantities to weigh 1000 g of the alloy in total and were melted together. Samples from the cast alloys were subject to homogenisation treatment at 200 °C for 2 h in a muffle furnace and furnace cooled. Samples from the homogenised alloys were heated and held for 2 h at 920 °C followed by ice quenching to obtain the desired martensitic structure for shape memory behaviour. The alloys in the cast, homogenised and quenched conditions were metallographically polished to observe the martensitic phase formation mainly in quenched samples which is a pre requisite for exhibiting shape memory properties in these alloys. X-ray Diffraction studies were carried out on the cast and quenched samples using Cu Kα target; and the phases identified indicate martensitic phase precipitation; however in some cases the precipitation is incomplete. Differential Scanning Calorimetric [DSC] studies were carried out on quenched samples from room temperature to 600 °C maintaining a constant rate of 10 °C/min. Results indicate clear transformation peaks in all the samples which

  17. Corrosion behavior of friction stir welded AZ31B Mg alloy - Al6063 alloy joint

    Directory of Open Access Journals (Sweden)

    B. Ratna Sunil

    2016-12-01

    Full Text Available In the present work, AZ31B Mg alloy and Al6063 alloy-rolled sheets were successfully joined by friction stir welding. Microstructural studies revealed a sound joint with good mechanical mixing of both the alloys at the nugget zone. Corrosion performance of the joint was assessed by immersing in 3.5% NaCl solution for different intervals of time and the corrosion rate was calculated. The joint has undergone severe corrosion attack compared with both the base materials (AZ31B and Al6063 alloys. The predominant corrosion mechanism behind the high corrosion rate of the joint was found to be high galvanic corrosion. From the results, it can be suggested that the severe corrosion of dissimilar Mg–Al joints must be considered as a valid input while designing structures intended to work in corroding environment.

  18. Site Preference and Alloying Effect of Excess Ni in Ni-Mn-Ga Shape Memory Alloys

    Institute of Scientific and Technical Information of China (English)

    CHEN Jie; LI Yan; SHANG Jia-Xiang; XU Hui-Bin

    2009-01-01

    @@ The formation energies and electronic structures of Ni-rich Ni-Mn-Ga alloys have been investigated by first-principles calculations using the pseudopotential plane wave method baaed on density functional theory. The results show that the alloying Ni prefers to occupy the Mn site directly in Ni9Mn3Ga4 and to occupy the Mn site and drive the displaced Mn atom to the Ga site in Ni9Mn4Ga3, which is in accordance with the experimental result. According to the lattice constants and the density of states analyses, these site preference behaviours are closely related to the smaller lattice distortion and the lower-energy electronic structure when the excess Ni occupies the Mn site. The effect of Ni alloying on martensitic transformation is discussed and the enhancement of martensitic transformation temperature by Ni alloying is estimated by the calculated formation energy difference between anstenite and martensite phases.

  19. Phase evolution and alloying mechanism of titanium aluminide nanoparticles

    International Nuclear Information System (INIS)

    Highlights: • An evolution of phase composition of TiAl alloy nanoparticles was investigated. • An alloying mechanism was analyzed according to the variation of phase composition. • The alloying reaction was possible to perform between the small clusters of Ti and Al. • The alloying product is determined by the temperature of Ti and Al small clusters. • The alloying mechanism can be explained based on Gibbs free energy of alloying reaction. - Abstract: The evolution of phase composition of titanium aluminide nanoparticles synthesized by the flow-levitation method was systematically investigated by adjustment of the evaporating temperature of the mixed metallic droplet and the X-ray diffraction spectrum. Their alloying mechanism was analyzed according to the variation of phase composition. ε(h, l)-TiAl3, γ-TiAl and α2-Ti3Al phases are gradually formed in TiAl alloy nanoparticles with the increasing of evaporating temperature of the mixed droplet. The alloying reaction is possible to perform between the small clusters of Ti and Al during the cooling process with high cooling rate. And the alloying mechanism can be explained based on the Gibbs free energy of alloying reaction of Ti and Al small clusters

  20. Microstructure and properties of 2618-Ti heat resistant aluminum alloy

    Institute of Scientific and Technical Information of China (English)

    王建华; 易丹青; 王斌

    2003-01-01

    The mechanical properties of alloy 2618 with 0.5%(mass fraction) titanium and its microstructures in different states such as as-cast and quenching-aging were investigated. Titanium was added into the alloy with Al-5%Ti master alloy that was extruded severely. Al3Ti particles in the microstructure of cast alloy 2618-Ti are very small because those of master alloy are also small. When titanium is used as an alloying element, it does not affect the morphology of Al9FeNi phase in cast alloy, but decreases the grain size of as-cast alloy remarkably. The grain size of quenching-aging alloy 2618 decreases apparently due to the existence of a great deal of dispersive Al3Ti particles. Adding 0.5%Ti has no effect on the room temperature tensile properties of alloy 2618, but apparently increases the elevated temperature instantaneous tensile properties and that of the alloy which is exposed at 250 ℃ for 100 h.

  1. Phase evolution and alloying mechanism of titanium aluminide nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Luo, J.S.; Li, K.; Li, X.B. [Research Center of Laser Fusion, Science and Technology on Plasma Physics Laboratory, China Academy of Engineering Physics, Mianyang 621900 (China); Shu, Y.J. [Institute of Chemical Materials, China Academy of Engineering Physics, Mianyang 621900 (China); Tang, Y.J., E-mail: tangyongjian2000@sina.com [Research Center of Laser Fusion, Science and Technology on Plasma Physics Laboratory, China Academy of Engineering Physics, Mianyang 621900 (China)

    2014-12-05

    Highlights: • An evolution of phase composition of TiAl alloy nanoparticles was investigated. • An alloying mechanism was analyzed according to the variation of phase composition. • The alloying reaction was possible to perform between the small clusters of Ti and Al. • The alloying product is determined by the temperature of Ti and Al small clusters. • The alloying mechanism can be explained based on Gibbs free energy of alloying reaction. - Abstract: The evolution of phase composition of titanium aluminide nanoparticles synthesized by the flow-levitation method was systematically investigated by adjustment of the evaporating temperature of the mixed metallic droplet and the X-ray diffraction spectrum. Their alloying mechanism was analyzed according to the variation of phase composition. ε(h, l)-TiAl{sub 3,} γ-TiAl and α{sub 2}-Ti{sub 3}Al phases are gradually formed in TiAl alloy nanoparticles with the increasing of evaporating temperature of the mixed droplet. The alloying reaction is possible to perform between the small clusters of Ti and Al during the cooling process with high cooling rate. And the alloying mechanism can be explained based on the Gibbs free energy of alloying reaction of Ti and Al small clusters.

  2. Microstructure and corrosion behavior of Mg-Zn-Ag alloys

    International Nuclear Information System (INIS)

    The majority of Mg components currently in use in the automotive and electronic industries are produced by conventional casting processes. However, there is a strong need to develop new high strength wrought alloys for wide-spread application of Mg alloys in near future. In the present study, new Mg-Zn-Ag alloys were developed and characterized. In order to evaluate the effects of Ag addition on the mechanical properties of the extruded Mg-Zn alloys, the age hardening response and mechanical properties were examined with different amounts of alloying element. The microstructures of the specimens were examined with optical microscopy and transmission electron microscopy. The grain sizes of the alloys in as-extruded condition were markedly reduced with the addition of Ag. The hardness was found to increase more rapidly in the alloys with double aging treatment compared to those with single aging treatment. The peak hardness was also found to be higher in the alloys with double aging treatment. In all heat treatment conditions, the hardnesses of the Mg-Zn-Ag alloys were found to be higher than those of the Mg-Zn alloys. Moreover, the addition of Ag to the Mg-Zn alloys increased the corrosion rate measured by immersion test

  3. High strength beta titanium alloys: New design approach

    International Nuclear Information System (INIS)

    A novel approach for development of high strength and ductile beta titanium alloys was proposed and successfully applied. The microstructure of the designed alloys is fully composed of a bcc β-Ti phase exhibiting dendritic morphology. The new Ti68.8Nb13.6Cr5.1Co6Al6.5 (at%) alloy (BETAtough alloy) exhibits a maximum tensile strength of 1290±50 MPa along with 21±3% of fracture strain. The specific energy absorption value upon mechanical deformation of the BETAtough alloy exceeds that of Ti-based metallic glass composites and commercial high strength Ti-based alloys. The deformation behavior of the new alloys was correlated with their microstructure by means of in-situ studies of the microstructure evolution upon tensile loading in a scanning electron microscope

  4. Fabric cutting application of FeAl-based alloys

    Energy Technology Data Exchange (ETDEWEB)

    Sikka, V.K.; Blue, C.A. [Oak Ridge National Lab., TN (United States). Metals and Ceramics Div.; Sklad, S.P. [Univ. of Virginia, Charlottesville, VA (United States); Deevi, S.C. [Philip Morris U.S.A., Richmond, VA (United States); Shih, H.R. [Jackson State Univ., MS (United States)

    1998-11-01

    Four intermetallic-based alloys were evaluated for cutting blade applications. These alloys included Fe{sub 3}Al-based (FAS-II and FA-129), FeAl-based (PM-60), and Ni{sub 3}Al-based (IC-50). These alloys were of interest because of their much higher work-hardening rates than the conventionally used carbon and stainless steels. The FeAl-based PM-60 alloy was of further interest because of its hardening possibility through retention of vacancies. The vacancy retention treatment is much simpler than the heat treatments used for hardening of steel blades. Blades of four intermetallic alloys and commercially used M2 tool steel blades were evaluated under identical conditions to cut two-ply heavy paper. Comparative results under identical conditions revealed that the FeAl-based alloy PM-60 outperformed the other intermetallic alloys and was equal to or somewhat better than the commercially used M2 tool steel.

  5. Grain Refinement of Permanent Mold Cast Copper Base Alloys

    Energy Technology Data Exchange (ETDEWEB)

    M.Sadayappan; J.P.Thomson; M.Elboujdaini; G.Ping Gu; M. Sahoo

    2005-04-01

    Grain refinement is a well established process for many cast and wrought alloys. The mechanical properties of various alloys could be enhanced by reducing the grain size. Refinement is also known to improve casting characteristics such as fluidity and hot tearing. Grain refinement of copper-base alloys is not widely used, especially in sand casting process. However, in permanent mold casting of copper alloys it is now common to use grain refinement to counteract the problem of severe hot tearing which also improves the pressure tightness of plumbing components. The mechanism of grain refinement in copper-base alloys is not well understood. The issues to be studied include the effect of minor alloy additions on the microstructure, their interaction with the grain refiner, effect of cooling rate, and loss of grain refinement (fading). In this investigation, efforts were made to explore and understand grain refinement of copper alloys, especially in permanent mold casting conditions.

  6. Beta titanium alloys and their role in the titanium industry

    Science.gov (United States)

    Bania, Paul J.

    1994-07-01

    The class of titanium alloys generically referred to as the beta alloys is arguably the most versatile in the titanium family. Since these alloys offer the highest strength-to-weight ratios and deepest hardenability of all titanium alloys, one might expect them to compete favorably for a variety of aerospace applications. To the contrary, however, except for one very successful application (Ti-13V-11Cr-3Al on the SR-71), the beta alloys have remained a very small segment of the industry. As a perspective on this situation, this article reviews some past and present applications of titanium alloys. It also descibes some unique new alloys and applications that promise to reverse historical trends.

  7. In vitro and in vivo studies on biodegradable magnesium alloy

    Institute of Scientific and Technical Information of China (English)

    Lida Hou; Zhen Li; Yu Pan; Li Du; Xinlin Li; Yufeng Zheng; Li Li

    2014-01-01

    The microstructure, mechanical property, electrochemical behavior and biocompatibility of magnesium alloy (BioDe MSM™) were studied in the present work. The experimental results demonstrated that grain refining induced by extrusion improves the alloy strength significantly from 162 MPa for the as-cast alloy to 241 MPa for the as-extruded one. The anticorrosion properties of the as-extruded alloy also increased. Furthermore, the hemolysis ratio was decreased from 4.7%for the as-cast alloy to 2.9%for the as-extruded one, both below 5%. BioDe MSM™alloy shows good biocompatibility after being implanted into the dorsal muscle and the femoral shaft of the New Zealand rabbit, respectively, and there are no abnormalities after short-term implantation. In vivo observation indicated that the corrosion rate of this alloy varies with different implantation positions, with higher degradation rate in the femur than in the muscle.

  8. Development of Lead-Free Copper Alloy-Graphite Castings

    Energy Technology Data Exchange (ETDEWEB)

    Rohatgi, P.K. [Univ. of Wisconsin-Milwaukee (US)

    1999-10-01

    In this project, graphite is used as a substitute for lead in order to maintain the machinability of plumbing components at the level of leaded brass. Graphite dispersed in Cu alloy was observed to impart good machinability and reduce the sizes of chips during machining of plumbing components in a manner similar to lead. Copper alloys containing dispersed graphite particles could be successfully cast in several plumbing fixtures which exhibited acceptable corrosion rate, solderability, platability, and pressure tightness. The power consumption for machining of composites was also lower than that of the matrix alloy. In addition, centrifugally cast copper alloy cylinders containing graphite particles were successfully made. These cylinders can therefore be used for bearing applications, as substitutes for lead-containing copper alloys. The results indicate that copper graphite alloys developed under this DOE project have a great potential to substitute for lead copper alloys in both plumbing and bearing applications.

  9. Performance of stainless steel treated by plasma niobium alloying

    International Nuclear Information System (INIS)

    Nb alloyed layer was prepared by plasma surface alloying technology on surface of stainless steel substrates. Microstructure morphology, depth profiling of the elemental composition and phase structure of the alloyed layer were analyzed. Corrosion performance of the Nb alloyed layer was investigated. The results show that the optimum parameters were: temperature, 1100 degree C; air pressure, 80 Pa, holding time 3 h, source voltage, 900-700 V; and cathode voltage, 600-450 V. The thickness of Nb alloyed layer was about 60 μm. The alloyed layer was mainly composed of NbC and Nb6C5, Cr2Nb and Fe2Nb. The surface Nb content was 50%, which decreased sharply in the first several microns of depths and then gradually in further depths. The Nb alloyed layer has improved resistance to intergranular corrosion and uniform corrosion. (authors)

  10. In vitro and in vivo studies on biodegradable magnesium alloy

    Directory of Open Access Journals (Sweden)

    Lida Hou

    2014-10-01

    Full Text Available The microstructure, mechanical property, electrochemical behavior and biocompatibility of magnesium alloy (BioDe MSM™ were studied in the present work. The experimental results demonstrated that grain refining induced by extrusion improves the alloy strength significantly from 162 MPa for the as-cast alloy to 241 MPa for the as-extruded one. The anticorrosion properties of the as-extruded alloy also increased. Furthermore, the hemolysis ratio was decreased from 4.7% for the as-cast alloy to 2.9% for the as-extruded one, both below 5%. BioDe MSM™ alloy shows good biocompatibility after being implanted into the dorsal muscle and the femoral shaft of the New Zealand rabbit, respectively, and there are no abnormalities after short-term implantation. In vivo observation indicated that the corrosion rate of this alloy varies with different implantation positions, with higher degradation rate in the femur than in the muscle.

  11. Titanium Alloys and Processing for High Speed Aircraft

    Science.gov (United States)

    Brewer, William D.; Bird, R. Keith; Wallace, Terryl A.

    1996-01-01

    Commercially available titanium alloys as well as emerging titanium alloys with limited or no production experience are being considered for a variety of applications to high speed commercial aircraft structures. A number of government and industry programs are underway to improve the performance of promising alloys by chemistry and/or processing modifications and to identify appropriate alloys and processes for specific aircraft structural applications. This paper discusses some of the results on the effects of heat treatment, service temperatures from - 54 C to +177 C, and selected processing on the mechanical properties of several candidate beta and alpha-beta titanium alloys. Included are beta alloys Timetal 21S, LCB, Beta C, Beta CEZ, and Ti-10-2-3 and alpha-beta alloys Ti-62222, Ti-6242S, Timetal 550, Ti-62S, SP-700, and Corona-X. The emphasis is on properties of rolled sheet product form and on the superplastic properties and processing of the materials.

  12. Friction welding of Al–Mg–Si alloy to Ni–Cr–Mo low alloy steel

    OpenAIRE

    Fuji, A; 冨士, 明良

    2004-01-01

    It is difficult to weld the dissimilar material combination of aluminium alloys and low alloy steels using fusion welding processes, on account of the formation of a brittle interlayer composed of intermetallic compound phases and the significant difference in physical and mechanical properties. In the present work an attempt has been made to join these materials via the friction welding method, i.e. one of the solid phase joining processes. In particular, the present paper describes the opti...

  13. Virtual examinations of alloying elements influence on alloy structural steels mechanical properties

    OpenAIRE

    L.A. Dobrzański; R. Honysz

    2011-01-01

    Purpose: The paper introduces analysis results of selected alloying elements influence on mechanical properties of alloy structural steels for quenching and tempering.Design/methodology/approach: Investigations were performed in virtual environment with use of materials science virtual laboratory. Virtual investigations results were verified in real investigative laboratory.Findings: Materials researches performed with use of material science virtual laboratory in range of determining the mec...

  14. A Promising New Class of High-Temperature Alloys: Eutectic High-Entropy Alloys

    OpenAIRE

    Yiping Lu; Yong Dong; Sheng Guo; Li Jiang; Huijun Kang; Tongmin Wang; Bin Wen; Zhijun Wang; Jinchuan Jie; Zhiqiang Cao; Haihui Ruan; Tingju Li

    2014-01-01

    High-entropy alloys (HEAs) can have either high strength or high ductility, and a simultaneous achievement of both still constitutes a tough challenge. The inferior castability and compositional segregation of HEAs are also obstacles for their technological applications. To tackle these problems, here we proposed a novel strategy to design HEAs using the eutectic alloy concept, i.e. to achieve a microstructure composed of alternating soft fcc and hard bcc phases. As a manifestation of this co...

  15. Defect generation and analysis in mechanically alloyed stoichiometric Fe–Ni alloys

    Energy Technology Data Exchange (ETDEWEB)

    Geng, Yunlong, E-mail: gengyunlong@gmail.com [Mechanical & Materials Engineering, University of Nebraska-Lincoln, Lincoln, NE 68588 (United States); Nebraska Center for Materials and Nanoscience, University of Nebraska-Lincoln, Lincoln, NE 68588 (United States); Ablekim, Tursunjan [Center for Materials Research, Washington State University, Pullman, WA 99164 (United States); Koten, Mark A. [Mechanical & Materials Engineering, University of Nebraska-Lincoln, Lincoln, NE 68588 (United States); Nebraska Center for Materials and Nanoscience, University of Nebraska-Lincoln, Lincoln, NE 68588 (United States); Weber, Marc; Lynn, Kelvin [Center for Materials Research, Washington State University, Pullman, WA 99164 (United States); Shield, Jeffrey E. [Mechanical & Materials Engineering, University of Nebraska-Lincoln, Lincoln, NE 68588 (United States); Nebraska Center for Materials and Nanoscience, University of Nebraska-Lincoln, Lincoln, NE 68588 (United States)

    2015-06-05

    Highlights: • An initial increase in strain followed by decrease with further alloying was studied. • A decrease of the net concentration with mechanical alloying was revealed by DBPAS. • Decrease of relative permeability μ{sub r} with internal strain was observed. - Abstract: FeNi, with the chemically-ordered L1{sub 0} tetragonal structure, is a promising material for next-generation rare-earth-free permanent magnets. Due to the extremely low atomic Fe and Ni mobility below the critical chemical order/disorder temperature of 320 °C, no conventional metallurgical methods are able to induce its formation. Diffusion rates could be enhanced with the creation of excessive vacancies. High-energy mechanical alloying was employed to produce a nanocrystalline Fe–50 at.%Ni alloy. The high energy mechanical milling is expected to change the defect characteristics that would be used to study the effect that mechanical alloying has on the defect concentrations. X-ray diffraction revealed that over the entirety of the milling period, the Fe and Ni powders formed an fcc solid solution. The Williamson–Hall equation and Scherrer equation revealed that reductions in grain sizes were caused during alloying. The initial increase in internal strain, and by extension dislocations, was followed by a decrease in strain with further alloying, which was due to the combination effect of creation of dislocation from mechanical deformation and annihilation of dislocations at increasing grain boundaries. Doppler broadening positron annihilation spectroscopy (DB-PAS) showed that the overall number of open-volume defects decreased with increased milling time. Finally, changes of relative permeability, for the mechanically alloyed FeNi phase, were explained by the pinning effect of dislocations.

  16. Development of Strip Casting Technology in Rare Earth Permanent Magnet Alloys and Hydrogen Storage Alloys in China

    Institute of Scientific and Technical Information of China (English)

    Han Weiping; Guo Binglin; Yu Xiaojun; Zhu Jinghan; Cheng Xinghua

    2007-01-01

    The SC technique is now being applied widely in material preparation, especially in rare earth functional materials in virtue of its advanced process and high performance product. The applications of SC technique in rare earth permanent magnet alloys and hydrogen storage alloys were analyzed integrative, on the basis of summary of SC technique development in this paper. The paper mainly includes development history of SC technology, effect of SC technology on alloy microstructure, application of SC technology in RE storage hydrogen alloy and sintered Nd-Fe-B alloy, development of SC equipment and SC product industry. At the same time, the paper points out the existing problem of SC products.

  17. Microstructure and Mechanical Properties of Solution Heat-Treated Alloy 617 ODS Alloy

    International Nuclear Information System (INIS)

    Alloy 617 is a solution hardened Ni-based Superalloy containing Cr, Co, Mo, and Fe, and is among the best candidate materials for the key components of VHTR (Very High Temperature Reactor) system. As an alternative, Oxide Dispersion Strengthened (ODS) Ni-based superalloys, are known to possess superior high temperature mechanical properties and long-term high temperature microstructural stability due to the nano sized oxide dispersoids, which effectively hinder the dislocation motion at high temperature. This study is focused on the fabrication and characterization of nanosized oxide dispersion strengthened alloy 617. The influences of alloy composition and processing variables such as the content of Y2O3, hot extrusion ratio, and hydrogen reduction on the microstructure and mechanical properties were studied. From the analyses of microstructure of solution heat treated Alloy 617 ODS alloy specimens, a proper solid solution heat treatment temperature to reduce carbides is 1250 .deg. C. The major phases present in the alloy 617 ODS were found to be M23C6 and Al-O

  18. Effect of mechanical alloying on FeCrC reinforced Ni alloys

    Energy Technology Data Exchange (ETDEWEB)

    Yilmaz, S. Osman [Univ. of Namik Kemal, Tekirdag (Turkey); Teker, Tanju [Adiyaman Univ. (Turkey). Dept. of Metallurgical and Materials Engineering; Demir, Fatih [Batman Univ. (Turkey)

    2016-05-01

    Mechanical alloying (MA) is a powder metallurgy processing technique involving cold welding, fracturing and rewelding of powder particles in a high-energy ball mill. In the present study, the intermetallic matrix composites (IMCs) of Ni-Al reinforced by M{sub 7}C{sub 3} were produced by powder metallurgical routes via solid state reaction of Ni, Al and M{sub 7}C{sub 3} particulates by mechanical alloying processes. Ni, Al and M{sub 7}C{sub 3} powders having 100 μm were mixed, mechanical alloyed and the compacts were combusted in a furnace. The mechanically alloyed (MAed) powders were investigated by X-ray diffraction (XRD), microhardness measurement, optic microscopy (OM), scanning electron microscopy (SEM) and energy dispersive spectrometry (EDS). The presence of the carbides depressed the formation of unwanted NiAl intermetallic phases. The mechanical alloyed M{sub 7}C{sub 3} particles were unstable and decomposed partially within the matrix during alloying and sintering, and the morphology of the composites changed with the dissolution ratio of M{sub 7}C{sub 3} and sintering temperature.

  19. Alloy development and associated dimensional changes of aluminium alloys during liquid phase sintering

    Energy Technology Data Exchange (ETDEWEB)

    Martin, J.M.; Castro, F. [Centro de Estudios e Investigaciones Tecnicas de Guipuzcoa (CEIT) and TECNUN, San Sebastian (Spain)

    2003-07-01

    The sintering behaviour and microstructural evolution of two aluminium alloys, of the 2XXX and 7XXX series, has been studied under, both, laboratory and industrial conditions. Quenching experiments from selected temperatures during the heating cycles, coupled with microstructural characterisation by Electron Microscopy, were used to investigate the gradual approach towards equilibrium of the alloys, from the as-pressed powder mixtures to the consolidated state after sintering. Differential Scanning Calorimetry was used to identify the reactions leading to the formation of liquid phases during sintering while the associated dimensional changes were determined by Dilatometry. The sinterability of these alloys and the development of necks between the solid aluminium particles is based upon the initial formation of transient liquid phases that favour the incorporation of alloying additions, followed by the development of permanent liquid phases, mainly containing Zn/Mg/Al and Cu/Al for the 7XXX and 2XXX series, respectively, leading to the densification of the alloys. A series of geometrically complex components with adequate dimensional tolerance and properties were industrially produced for an automotive application using the 2XXX series P/M Al alloy. (orig.)

  20. Casting of Titanium and its Alloys

    OpenAIRE

    R. L. Saha; K. T. Jacob

    1986-01-01

    Titaniuni and its alloys have many applications in aerospace, marine and other engineering industries. Titanium requires special melting techniques because of its high reactivity at elevated temperatures and needs special mould materials and methods for castings. This paper reviews the development of titanium casting technology.

  1. Casting of Titanium and its Alloys

    Directory of Open Access Journals (Sweden)

    R. L. Saha

    1986-04-01

    Full Text Available Titaniuni and its alloys have many applications in aerospace, marine and other engineering industries. Titanium requires special melting techniques because of its high reactivity at elevated temperatures and needs special mould materials and methods for castings. This paper reviews the development of titanium casting technology.

  2. Structure Map for Embedded Binary Alloy Nanocrystals

    Energy Technology Data Exchange (ETDEWEB)

    Yuan, C.W.; Shin, S.J.; Liao, C.Y.; Guzman, J.; Stone, P.R.; Watanabe, M.; Ager III, J.W.; Haller, E.E.; Chrzan, D.C.

    2008-09-20

    The equilibrium structure of embedded nanocrystals formed from strongly segregating binary-alloys is considered within a simple thermodynamic model. The model identifies two dimensionlessinterface energies that dictate the structure, and allows prediction of the stable structure for anychoice of these parameters. The resulting structure map includes three distinct nanocrystal mor-phologies: core/shell, lobe/lobe, and completely separated spheres.

  3. Nickel-titanium alloys: a systematic review

    Directory of Open Access Journals (Sweden)

    Marcelo do Amaral Ferreira

    2012-06-01

    Full Text Available OBJECTIVE: A systematic review on nickel-titanium wires was performed. The strategy was focused on Entrez-PubMed-OLDMEDLINE, Scopus and BioMed Central from 1963 to 2008. METHODS: Papers in English and French describing the behavior of these wires and laboratorial methods to identify crystalline transformation were considered. A total of 29 papers were selected. RESULTS: Nickel-titanium wires show exceptional features in terms of elasticity and shape memory effects. However, clinical applications request a deeper knowledge of these properties in order to allow the professional to use them in a rational manner. In addition, the necessary information regarding each alloy often does not correspond to the information given by the manufacturer. Many alloys called "superelastic" do not present this effect; they just behave as less stiff alloys, with a larger springback if compared to the stainless steel wires. CONCLUSIONS: Laboratory tests are the only means to observe the real behavior of these materials, including temperature transition range (TTR and applied tensions. However, it is also possible to determine in which TTR these alloys change the crystalline structure.

  4. Surface heat treatment of zirconium alloy

    International Nuclear Information System (INIS)

    A body composed of a zirconium alloy is afforded enhanced corrosion resistance to a high pressure and high temperature steam environment by an integral surface region of β-quenched zirconium formed in situ by laser beam scanning and afforded good mechanical and structural properties by a bulk region whose metallurgical structure is selected to optimize these mechanical properties. (author)

  5. Structure analysis of Al cast alloy

    Directory of Open Access Journals (Sweden)

    L.A. Dobrzański

    2008-03-01

    Full Text Available Purpose: The developed design methodologies both the material and technological ones will make it possible to improve shortly the quality of materials from the light alloys in the technological process, and the automatic process flow correction will make the production cost reduction possible, and - first of all - to reduce the amount of the waste products.Design/methodology/approach: Castings were analysed in the paper of car engine blocks and heads from the Al-Si-Cu alloys of the AC-AlSi7Cu3Mg type fabricated with the “Cosworth” technological process. In this work the AC-AlSi7Cu3Mg alloy structure was investigated, of this alloy samples were cut of for structure analysis of the cylinder part as well of crankshaft of a fuel engine. The investigation show a difference in the (phase structure morphology as a result of cast cooling rate.Findings: On the quality of casting has influence the walls thickness of car engine elements’.Practical implications: In the metal casting industry, an improvement of component quality depends mainly on better control over the production parameters.Originality/value: The value of the applied methodology was to correct identify the casting effects that occurred during the casting process.

  6. Hydrogenation properties of Mg-Al alloys

    DEFF Research Database (Denmark)

    Andreasen, Anders

    2008-01-01

    . Further, it is found that the kinetics of hydrogenation, as well dehydrogenation, may be significantly improved by alloying compared to pure Mg. The expense of these improvements of the hydrogenation/dehydrogenation properties is a lower gravimetric hydrogen density in the hydrogenated product, (C) 2008...

  7. Localized Corrosion of Alloy 22 -Fabrication Effects-

    Energy Technology Data Exchange (ETDEWEB)

    Rebak, R B

    2005-11-05

    This report deals with the impact of fabrication processes on the localized corrosion behavior of Alloy 22 (N06022). The four fabrication processes that were analyzed are: (1) Surface stress mitigation of final closure weld, (2) Manufacturing of the mockup container, (3) Black annealing of the container and (4) Use of different heats of Alloy 22 for container fabrication. Immersion and Electrochemical tests performed in the laboratory are generally aggressive and do not represent actual repository environments in Yucca Mountain. For example, to determine the intergranular attack in the heat affected zone of a weldment, tests are conducted in boiling acidic and oxidizing solutions according to ASTM standards. These solutions are used to compare the behavior of differently treated metallic coupons. Similarly for electrochemical tests many times pure sodium chloride or calcium chloride solutions are used. Pure chloride solutions are not representative of the repository environment. (1) Surface Stress Mitigation: When metallic plates are welded, for example using the Gas Tungsten Arc Welding (GTAW) method, residual tensile stresses may develop in the vicinity of the weld seam. Processes such as Low Plasticity Burnishing (LPB) and Laser Shock Peening (LSP) could be applied locally to eliminate the residual stresses produced by welding. In this study, Alloy 22 plates were welded and then the above-mentioned surface treatments were applied to eliminate the residual tensile stresses. The aim of the current study was to comparatively test the corrosion behavior of as-welded (ASW) plates with the corrosion behavior of plates with stress mitigated surfaces. Immersion and electrochemical tests were performed. Results from both immersion and electrochemical corrosion tests show that the corrosion resistance of the mitigated plates was not affected by the surface treatments applied. (2) Behavior of Specimens from a Mockup container: Alloy 22 has been extensively tested for

  8. Mechanocaloric effects in shape memory alloys.

    Science.gov (United States)

    Mañosa, Lluís; Planes, Antoni

    2016-08-13

    Shape memory alloys (SMA) are a class of ferroic materials which undergo a structural (martensitic) transition where the associated ferroic property is a lattice distortion (strain). The sensitiveness of the transition to the conjugated external field (stress), together with the latent heat of the transition, gives rise to giant mechanocaloric effects. In non-magnetic SMA, the lattice distortion is mostly described by a pure shear and the martensitic transition in this family of alloys is strongly affected by uniaxial stress, whereas it is basically insensitive to hydrostatic pressure. As a result, non-magnetic alloys exhibit giant elastocaloric effects but negligible barocaloric effects. By contrast, in a number of magnetic SMA, the lattice distortion at the martensitic transition involves a volume change in addition to the shear strain. Those alloys are affected by both uniaxial stress and hydrostatic pressure and they exhibit giant elastocaloric and barocaloric effects. The paper aims at providing a critical survey of available experimental data on elastocaloric and barocaloric effects in magnetic and non-magnetic SMA.This article is part of the themed issue 'Taking the temperature of phase transitions in cool materials'. PMID:27402931

  9. Microstructure Development during Solidification of Aluminium Alloys

    NARCIS (Netherlands)

    Ruvalcaba Jimenez, D.G.

    2009-01-01

    This Thesis demonstrates studies on microstructure development during the solidification of aluminium alloys. New insights of structure development are presented here. Experimental techniques such as quenching and in-situ High-brilliance X-ray microscopy were utilized to study the microstructure evo

  10. Reduction in Defect Content in ODS Alloys

    Energy Technology Data Exchange (ETDEWEB)

    Ritherdon, J.; Jones, A.R.

    2000-02-01

    The work detailed within this report is a continuation of earlier work that was carried out under contract number IDX-SY382V. The earlier work comprised a literature review of the sources and types of defects found principally in Fe-based ODS alloys together with a series of experiments designed to identify defects in ODS Fe{sub 3}Al material and recommend methods of defect reduction. Defects found in the Mechanically Alloyed (MA) ODS Fe{sub 3}Al included regions of incomplete MA, porosity, intrusions and fine-grained stringers. Some defects tended to be found in association with one another e.g. intrusions and fine-grained stringers. Preliminary powder separation experiments were also performed. The scope and objectives of the present work were laid out in the technical proposal ``Reduction in Defect Content in ODS Alloys--II'' which formed the basis of amendment 3 of the current contract. The current studies were devised in the context of the preceding work with a view to extending and concluding certain experiments while exploring new avenues of investigation of defect control and reduction where appropriate. All work proposed was within the context of achieving an ODS Fe{sub 3}Al alloy of improved overall quality and potential creep performance (particularly) in the consolidated, release condition. The interim outturn of the experimental work performed is also reported.

  11. Hydrogen environment embrittlement of turbine disk alloys

    International Nuclear Information System (INIS)

    Differences in reported data on properties of turbine disk materials are examined. Results confirm previous results that Udimet 700 bar stock is severely embrittled when tested in gaseous hydrogen. This extreme sensitivity to embrittlement of Udimet 700 is presumably related to its microstructure. Results that Astroloy forgings exhibit a high degree of resistance to hydrogen environment embrittlement during short-term testing, and possibly long-term testing are also confirmed. Therefore, this alloy could be considered for use as the turbine disk alloy for advanced versions of the APU, thereby permitting an increased turbine inlet temperature and/or higher rotational speed than possible with V-57. V-57 is an iron-base superalloy (stable austenitic stainless steel) and is a member of a class of alloys generally quite resistant to hydrogen environment embrittlement. The results of investigation demonstrate the good resistance of V-57 alloy to embrittlement only during short-term tensile testing. Significant reductions in creep and rupture lives, as well as post-creep residual ductility, were determined. Despite these laboratory results, V-57 turbine disks successfully completed short-time performance testing in the experimental APU

  12. High-strength iron aluminide alloys

    Energy Technology Data Exchange (ETDEWEB)

    McKamey, C.G.; Marrero-Santos, Y.; Maziasz, P.J.

    1995-06-01

    Past studies have shown that binary Fe{sub 3}Al possesses low creep-rupture strength compared to many other alloys, with creep-rupture lives of less than 5 h being reported for tests conducted at 593{degrees}C and 207 MPa. The combination of poor creep resistance and low room-temperature tensile density due to a susceptibility to environmentally-induced dynamic hydrogen embrittlement has limited use of these alloys for structural applications, despite their excellent corrosion properties. Improvements in room temperature tensile ductility have been realized mainly through alloying effects, changes in thermomechanical processing to control microstructure, and by control of the specimen`s surface condition. Ductilities of 10-20% and tensile yield strengths as high as 500 MPa have been reported. In terms of creep-rupture strength, small additions of Mo, Nb, and Zr have produced significant improvements, but at the expense of weldability and room-temperature tensile ductility. Recently an alloy containing these additions, designated FA-180, was shown to exhibit a creep-rupture life of over 2000 h after a heat treatment of 1 h at 1150{degrees}C. This study presents the results of creep-rupture tests at various test temperatures and stresses and discusses the results as part of our effort to understand the strengthening mechanisms involved with heat treatment at 1150{degrees}C.

  13. Atomic displacements in bcc dilute alloys

    Indian Academy of Sciences (India)

    Hitesh Sharma; S Prakash

    2007-04-01

    We present here a systematic investigation of the atomic displacements in bcc transition metal (TM) dilute alloys. We have calculated the atomic displacements in bcc (V, Cr, Fe, Nb, Mo, Ta and W) transition metals (TMs) due to 3d, 4d and 5d TMs at the substitutional site using the Kanzaki lattice static method. Wills and Harrison interatomic potential is used to calculate the atomic force constants, the dynamical matrix and the impurity-induced forces. We have thoroughly investigated the atomic displacements using impurities from 3d, 4d and 5d series in the same host metal and the same impurity in different hosts. We have observed a systematic pattern in the atomic displacements for Cr-, Fe-, Nb-, Mo-, Ta- and W-based dilute alloys. The atomic displacements are found to increase with increase in the number of d electrons for all alloys considered except for V dilute alloys. The 3d impurities are found to be more easily dissolved in the 3d host metals than 4d or 5d TMs whereas 4d and 5d impurities show more solubility in 4d and 5d TMs. In general, the relaxation energy calculation suggests that impurities may be easily solvable in 5d TM hosts when compared to 3d or 4d TMs.

  14. Ordering in binary transition metal alloys

    Energy Technology Data Exchange (ETDEWEB)

    Rusakov, G. [Institute for Metal Physics UB RAS, 18 Kovalevskoj St., 620990 Ekaterinburg (Russian Federation); Ural State Technical University - UPI, 19 Mira St., 620002 Ekaterinburg (Russian Federation); Son, L., E-mail: ldson@yandex.ru [Ural State Pedagogical University, 26 Cosmonavtov Ave, 620017 Ekaterinburg (Russian Federation); Efimova, E. [Institute for Metal Physics UB RAS, 18 Kovalevskoj St., 620990 Ekaterinburg (Russian Federation); Ural State Technical University - UPI, 19 Mira St., 620002 Ekaterinburg (Russian Federation); Dubinin, N. [Institute for Metallurgy UB RAS, 101 Amundsen St., 620016 Ekaterinburg (Russian Federation); Ural State Technical University - UPI, 19 Mira St., 620002 Ekaterinburg (Russian Federation)

    2012-03-20

    We present the phenomenological thermodynamic modeling of binary alloys which demonstrate solubility of the components at high temperatures, and form intermediate phase near equiatomic composition at lower ones (the so-called sigma-phase). Besides, the regular solution miscibility gap takes place also. The nonequilibrium thermodynamic potential is written out as a sum of the free energy of regular solution and polynomial term of scalar order parameter {phi}, which describes the {sigma}-phase ordering. There are four parameters in the model: the energy of regular solution mixing, the energy of {sigma}-phase formation at zero temperature, and the widths of temperature and concentration intervals of {sigma}-phase existence in the alloy with frozen-in random distribution of components. Up to now, both phase transitions which take place in a number of transition metals binary alloys (the {sigma}-phase formation and miscibility in the regular solution) have been treated separately. In present work, the standard technique of phase diagram calculation allows us to analyze all possible phase diagrams which may arise in the alloy.

  15. Laser alloying of Ti–Si compound coating on Ti–6Al–4V alloy for the improvement of bioactivity

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Y. [State Key Laboratory of Material Processing and Die and Mould Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074 (China); The State Key Laboratory Breeding Base of Basic Science of Stomatology (Hubei-MOST) and Key Laboratory of Oral Biomedicine Ministry of Education, Wuhan University, Wuhan 430079 (China); Wang, A.H., E-mail: ahwang@mail.hust.edu.cn [State Key Laboratory of Material Processing and Die and Mould Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074 (China); Zhang, Z.; Zheng, R.R. [State Key Laboratory of Material Processing and Die and Mould Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074 (China); Xia, H.B.; Wang, Y.N. [The State Key Laboratory Breeding Base of Basic Science of Stomatology (Hubei-MOST) and Key Laboratory of Oral Biomedicine Ministry of Education, Wuhan University, Wuhan 430079 (China)

    2014-06-01

    Laser alloying of Ti–Si compound coating on Ti–6Al–4V alloy is carried out by a pulsed Nd:YAG laser. The corresponding microstructure, phase structure, microhardness profiles, corrosion properties and bioactivity of the laser-alloyed coatings are investigated to optimize the atomic ratio of Ti–Si. The laser alloyed Ti–Si compound coatings are free of cracks, and primarily present block-like crystals, lath-like crystals and dendrite crystals. The phase structures of both laser-alloyed Ti + Si and 5Ti + 3Si coatings are mainly consisted of α-Ti and Ti{sub 5}Si{sub 3}, while the laser-alloyed Si coating is mainly consisted of TiSi{sub 2} and Ti{sub 5}Si{sub 3}. Microhardness test indicates that the laser-alloyed Si coating has the highest microhardness. Also, corrosion resistance measurement reveals that the corrosion resistance of the laser-alloyed Si coating is much better than that of the Ti–6Al–4V alloy. Evaluation of bioactivity shows that cell growth on the laser-alloyed Si coating with high volume fraction of Ti–Si compounds is faster than that of the Ti–6Al–4V alloy.

  16. Laser alloying of Ti–Si compound coating on Ti–6Al–4V alloy for the improvement of bioactivity

    International Nuclear Information System (INIS)

    Laser alloying of Ti–Si compound coating on Ti–6Al–4V alloy is carried out by a pulsed Nd:YAG laser. The corresponding microstructure, phase structure, microhardness profiles, corrosion properties and bioactivity of the laser-alloyed coatings are investigated to optimize the atomic ratio of Ti–Si. The laser alloyed Ti–Si compound coatings are free of cracks, and primarily present block-like crystals, lath-like crystals and dendrite crystals. The phase structures of both laser-alloyed Ti + Si and 5Ti + 3Si coatings are mainly consisted of α-Ti and Ti5Si3, while the laser-alloyed Si coating is mainly consisted of TiSi2 and Ti5Si3. Microhardness test indicates that the laser-alloyed Si coating has the highest microhardness. Also, corrosion resistance measurement reveals that the corrosion resistance of the laser-alloyed Si coating is much better than that of the Ti–6Al–4V alloy. Evaluation of bioactivity shows that cell growth on the laser-alloyed Si coating with high volume fraction of Ti–Si compounds is faster than that of the Ti–6Al–4V alloy.

  17. Friction and wear of titanium alloys and copper alloys sliding against titanium 6-percent-aluminum - 4-percent-vanadium alloy in air at 430 C

    Science.gov (United States)

    Wisander, D. W.

    1976-01-01

    Experiments were conducted to determine the friction and wear characteristics of aluminum bronzes and copper-tin, titanium-tin, and copper-silver alloys sliding against a titanium-6% aluminum-4% vanadium alloy (Ti-6Al-4V). Hemispherically tipped riders of aluminum bronze and the titanium and copper alloys were run against Ti-6Al-4V disks in air at 430 C. The sliding velocity was 13 cm/sec, and the load was 250 g. Results revealed that high tin content titanium and copper alloys underwent significantly less wear and galling than commonly used aluminum bronzes. Also friction force was less erratic than with the aluminum bronzes.

  18. Corrosion Behavior of AlSi10Mg Alloy Produced by Additive Manufacturing (AM vs. Its Counterpart Gravity Cast Alloy

    Directory of Open Access Journals (Sweden)

    Avi Leon

    2016-06-01

    Full Text Available The attractiveness of additive manufacturing (AM relates to the ability of this technology to rapidly produce very complex components at affordable costs. However, the properties and corrosion behavior, in particular, of products produced by AM technology should at least match the properties obtained by conventional technologies. The present study aims at evaluating the corrosion behavior and corrosion fatigue endurance of AlSi10Mg alloy produced by selective laser melting (SLM in comparison with its conventional counterpart, gravity cast alloy. The results obtained indicate that the corrosion resistance of the printed and cast alloys was relatively similar, with a minor advantage to the printed alloy. The corrosion fatigue endurance of the printed alloy was relatively improved compared to the cast alloy. This was mainly attributed to the significant differences between the microstructure and defect characteristics of those two alloys.

  19. Design of experiment (DOE) study of biodegradable magnesium alloy synthesized by mechanical alloying using fractional factorial design

    Science.gov (United States)

    Salleh, Emee Marina; Ramakrishnan, Sivakumar; Hussain, Zuhailawati

    2014-06-01

    The biodegradable nature of magnesium (Mg) makes it a most highlighted and attractive to be used as implant materials. However, rapid corrosion rate of Mg alloys especially in electrolytic aqueous environment limits its performance. In this study, Mg alloy was mechanically milled by incorporating manganese (Mn) as alloying element. An attempt was made to study both effect of mechanical alloying and subsequent consolidation processes on the bulk properties of Mg-Mn alloys. 2k-2 factorial design was employed to determine the significant factors in producing Mg alloy which has properties closes to that of human bones. The design considered six factors (i.e. milling time, milling speed, weight percentage of Mn, compaction pressure, sintering temperature and sintering time). Density and hardness were chosen as the responses for assessing the most significant parameters that affected the bulk properties of Mg-Mn alloys. The experimental variables were evaluated using ANOVA and regression model. The main parameter investigated was compaction pressure.

  20. Thermal coatings for titanium-aluminum alloys

    Science.gov (United States)

    Cunnington, George R.; Clark, Ronald K.; Robinson, John C.

    1993-01-01

    Titanium aluminides and titanium alloys are candidate materials for use in hot structure and heat-shield components of hypersonic vehicles because of their good strength-to-weight characteristics at elevated temperature. However, in order to utilize their maximum temperature capability, they must be coated to resist oxidation and to have a high total remittance. Also, surface catalysis for recombination of dissociated species in the aerodynamic boundary layer must be minimized. Very thin chemical vapor deposition (CVD) coatings are attractive candidates for this application because of durability and very light weight. To demonstrate this concept, coatings of boron-silicon and aluminum-boron-silicon compositions were applied to the titanium-aluminides alpha2 (Ti-14Al-21Nb), super-alpha2 (Ti-14Al-23-Nb-2V), and gamma (Ti-33Al-6Nb-1Ta) and to the titanium alloy beta-21S (Ti-15Mo-3Al-3Nb-0.2Si). Coated specimens of each alloy were subjected to a set of simulated hypersonic vehicle environmental tests to determine their properties of oxidation resistance, surface catalysis, radiative emittance, and thermal shock resistance. Surface catalysis results should be viewed as relative performance only of the several coating-alloy combinations tested under the specific environmental conditions of the LaRC Hypersonic Materials Environmental Test System (HYMETS) arc-plasma-heated hypersonic wind tunnel. Tests were also conducted to evaluate the hydrogen transport properties of the coatings and any effects of the coating processing itself on fatigue life of the base alloys. Results are presented for three types of coatings, which are as follows: (1) a single layer boron silicon coating, (2) a single layer aluminum-boron-silicon coating, and (3) a multilayer coating consisting of an aluminum-boron-silicon sublayer with a boron-silicon outer layer.

  1. Fast LIBS Identification of Aluminum Alloys

    Directory of Open Access Journals (Sweden)

    Tawfik W.

    2007-04-01

    Full Text Available Laser-induced breakdown spectroscopy (LIBS has been applied to analysis aluminum alloy targets. The plasma is generated by focusing a 300 mJ pulsed Nd: YAG laser on the target in air at atmospheric pressure. Such plasma emission spectrum was collected using a one-meter length wide band fused-silica optical fiber connected to a portable Echelle spectrometer with intensified CCD camera. Spectroscopic analysis of plasma evolution of laser produced plasmas has been characterized in terms of their spectra, electron density and electron temperature assuming the LTE and optically thin plasma conditions. The LIBS spectrum was optimized for high S/N ratio especially for trace elements. The electron temperature and density were determined using the emission intensity and stark broadening, respectively, of selected aluminum spectral lines. The values of these parameters were found to change with the aluminum alloy matrix, i.e. they could be used as a fingerprint character to distinguish between different aluminum alloy matrices using only one major element (aluminum without needing to analysis the rest of elements in the matrix. Moreover, It was found that the values of T(e and N(e decrease with increasing the trace elements concentrations in the aluminum alloy samples. The obtained results indicate that it is possible to improve the exploitation of LIBS in the remote on-line industrial monitoring application, by following up only the values of T(e and N(e for the aluminum in aluminum alloys using an optical fiber probe.

  2. Computational Materials Program for Alloy Design

    Science.gov (United States)

    Bozzolo, Guillermo

    2005-01-01

    The research program sponsored by this grant, "Computational Materials Program for Alloy Design", covers a period of time of enormous change in the emerging field of computational materials science. The computational materials program started with the development of the BFS method for alloys, a quantum approximate method for atomistic analysis of alloys specifically tailored to effectively deal with the current challenges in the area of atomistic modeling and to support modern experimental programs. During the grant period, the program benefited from steady growth which, as detailed below, far exceeds its original set of goals and objectives. Not surprisingly, by the end of this grant, the methodology and the computational materials program became an established force in the materials communitiy, with substantial impact in several areas. Major achievements during the duration of the grant include the completion of a Level 1 Milestone for the HITEMP program at NASA Glenn, consisting of the planning, development and organization of an international conference held at the Ohio Aerospace Institute in August of 2002, finalizing a period of rapid insertion of the methodology in the research community worlwide. The conference, attended by citizens of 17 countries representing various fields of the research community, resulted in a special issue of the leading journal in the area of applied surface science. Another element of the Level 1 Milestone was the presentation of the first version of the Alloy Design Workbench software package, currently known as "adwTools". This software package constitutes the first PC-based piece of software for atomistic simulations for both solid alloys and surfaces in the market.Dissemination of results and insertion in the materials community worldwide was a primary focus during this period. As a result, the P.I. was responsible for presenting 37 contributed talks, 19 invited talks, and publishing 71 articles in peer-reviewed journals, as

  3. Size Effect on Magnesium Alloy Castings

    Science.gov (United States)

    Li, Zhenming; Wang, Qigui; Luo, Alan A.; Zhang, Peng; Peng, Liming

    2016-06-01

    The effect of grain size on tensile and fatigue properties has been investigated in cast Mg alloys of Mg-2.98Nd-0.19Zn (1530 μm) and Mg-2.99Nd-0.2Zn-0.51Zr (41 μm). The difference between RB and push-pull fatigue testing was also evaluated in both alloys. The NZ30K05-T6 alloy shows much better tensile strengths (increased by 246 pct in YS and 159 pct in UTS) and fatigue strength (improved by ~80 pct) in comparison with NZ30-T6 alloy. RB fatigue testing results in higher fatigue strength compared with push-pull fatigue testing, mainly due to the stress/strain gradient in the RB specimen cross section. The material with coarse grains could be hardened more in the cyclic loading condition than in the monotonic loading condition, corresponding to the lower σ f and the higher σ f/ σ b or σ f/ σ 0.2 ratio compared to the materials with fine grains. The fatigue crack initiation sites and failure mechanism are mainly determined by the applied stress/strain amplitude. In LCF, fatigue failure mainly originates from the PSBs within the surface or subsurface grains of the samples. In HCF, cyclic deformation and damage irreversibly caused by environment-assisted cyclic slip is the crucial factor to influence the fatigue crack. The Coffin-Manson law and Basquin equation, and the developed MSF models and fatigue strength models can be used to predict fatigue lives and fatigue strengths of cast magnesium alloys.

  4. Recycling of Glass Fibre Reinforced Aluminium Laminates and Silicon Removal from Aerospace Al Alloy

    NARCIS (Netherlands)

    Zhu, G.

    2012-01-01

    Aerospace aluminium alloys (7xxx and 2xxx series Al alloy) is one of the important Al alloys in our life. The recycling of aerospace Al alloy plays a significant role in sustainable development of Al industry. The fibre reinforced metal laminates GLARE including 67 wt.% 2024 Al alloy was used as upp

  5. Evaluation of flexural bond strength of porcelain to used nickel-chromium alloy in various percentages

    Directory of Open Access Journals (Sweden)

    VNV Madhav

    2012-01-01

    Fresh nickel-chromium alloy shows the greatest porcelain adherence.There is no significant change in bond strength of ceramic to alloy with up to 75% of used nickel-chromium alloy.At least 25%- of new alloy should be added when recycled nickel-chromium alloy is being used for metal ceramic restorations.

  6. Relationships between the precipitation of α2 ordered phase and alloying elements/electron concentration in α+α2 titanium alloys

    Institute of Scientific and Technical Information of China (English)

    Jun Zhang; Yu Zhang; Li Li; Chunli Wang; Qingjiang Wang; Yuyin Liu

    2005-01-01

    Some experimental α+α2 alloys were prepared by the addition of tin or aluminum elements into Ti-55 alloy. These alloys were designed with varied electron concentration values and named as Sn-rich alloys and Al-rich alloys, respectively. The precipitation and growth of α2 ordered phase in the tested alloys under various heat treatment conditions were investigated. Some comparisons among the experimental results were performed and discussed in detail. Stronger precipitation and growth of α2 ordered phase were caused in Al-rich alloys but relatively weak change in Sn-rich alloys with increasing the electron concentration. The precipitation of α2 ordered phase in Al-rich alloys is stronger than that in Sn-rich alloys when the electron concentration value is the same for the two alloys.

  7. New Developments of Ti-Based Alloys for Biomedical Applications

    Directory of Open Access Journals (Sweden)

    Yuhua Li

    2014-03-01

    Full Text Available Ti-based alloys are finding ever-increasing applications in biomaterials due to their excellent mechanical, physical and biological performance. Nowdays, low modulus β-type Ti-based alloys are still being developed. Meanwhile, porous Ti-based alloys are being developed as an alternative orthopedic implant material, as they can provide good biological fixation through bone tissue ingrowth into the porous network. This paper focuses on recent developments of biomedical Ti-based alloys. It can be divided into four main sections. The first section focuses on the fundamental requirements titanium biomaterial should fulfill and its market and application prospects. This section is followed by discussing basic phases, alloying elements and mechanical properties of low modulus β-type Ti-based alloys. Thermal treatment, grain size, texture and properties in Ti-based alloys and their limitations are dicussed in the third section. Finally, the fourth section reviews the influence of microstructural configurations on mechanical properties of porous Ti-based alloys and all known methods for fabricating porous Ti-based alloys. This section also reviews prospects and challenges of porous Ti-based alloys, emphasizing their current status, future opportunities and obstacles for expanded applications. Overall, efforts have been made to reveal the latest scenario of bulk and porous Ti-based materials for biomedical applications.

  8. A study on new zirconium alloys with improved corrosion resistance

    International Nuclear Information System (INIS)

    In order to improve the corrosion resistance of zirconium alloys, corrosion mechanism of zirconium alloys has been systematically studied. By acquiring mastery of different existing theories, the new frame of theory system was established. And based on existing test results, seven new zirconium alloys were designed. For different alloy systems, different representative manufacturing processes were designed. And autoclave corrosion tests validated author's design theory. Finally, two new zirconium alloys were obtained which had improved corrosion resistance. The specimens were corroded in pure water and lithiated water at 360°C/18.6 MPa after 200 days exposure, two zirconium alloys with copper and silicon additions were better than other five zirconium alloys. And for the zirconium alloys with Nb content (0.8∼1.2) %, conventional low temperature annealing process should be used, which is beneficial to the corrosion resistance improvement. For the zirconium alloy with Nb content (0.2∼0.5) %, β water quenching process instead of intermediate annealing should be used, which can obviously improve the corrosion resistance of zirconium alloys. (author)

  9. Dispersoid reinforced alloy powder and method of making

    Science.gov (United States)

    Anderson, Iver E; Rieken, Joel

    2013-12-10

    A method of making dispersion-strengthened alloy particles involves melting an alloy having a corrosion and/or oxidation resistance-imparting alloying element, a dispersoid-forming element, and a matrix metal wherein the dispersoid-forming element exhibits a greater tendency to react with an introduced reactive species than does the alloying element and wherein one or more atomizing parameters is/are modified to controllably reduce the amount of the reactive species, such as oxygen, introduced into the atomized particles so as to reduce anneal times and improve reaction (conversion) to the desired strengthening dispersoids in the matrix. The atomized alloy particles are solidified as solidified alloy particles or as a solidified deposit of alloy particles. Bodies are made from the dispersion strengthened alloy particles, deposit thereof, exhibit enhanced fatigue and creep resistance and reduced wear as well as enhanced corrosion and/or oxidation resistance at high temperatures by virtue of the presence of the corrosion and/or oxidation resistance imparting alloying element in solid solution in the particle alloy matrix.

  10. Role of Alloying Elements in the Mechanical Behaviors of An Mg-Zn-Zr-Er Alloy

    Science.gov (United States)

    Zhang, Jing; Liu, Min; Dou, Yuchen; Liu, Guobao

    2014-11-01

    The mechanical behavior of the as-extruded and heat-treated Mg-1.5Zn-0.6Zr and Mg-1.5Zn-0.6Zr-2Er alloys was investigated and correlated with microstructure evolution. Deformation mechanisms are detailed. No evidence of twinning was observed under compression in the Er-bearing alloy throughout the grain size range of ~5 to 27 μm at a strain rate of 0.001 or 1/s. The compressive yield strength followed a Hall-Petch relation with a slope of ~10.3 MPa/mm1/2. Er played a major role in the pyramidal slip that was identified as a dominant plastic deformation mechanism. The CRSS for slip system was greatly reduced and was 98 MPa in the as-extruded alloy. While it did not change the mechanical response of the Mg-1.5Zn-0.6Zr-2Er alloy, annealing was found to promote dissolution of Zn in the Mg matrix, leading to an increase in CRSS for extension twinning in the heat-treated Mg-1.5Zn-0.6Zr alloy. As a result, twinning was only observed under a higher strain rate of 1/s in compression. The CRSS for extension twinning for the heat-treated alloy with a grain size of ~28 μm was estimated to be 40 MPa, a bit lower than that for the Er-bearing alloy of the same grain size, which was 42 MPa.

  11. Principles of the alloying of tungsten and development of the manufacturing technology for the tungsten alloys

    International Nuclear Information System (INIS)

    Tungsten alloys (Tm = 3410 oC) are intended for service in reducing and neutral media or in vacuum at temperatures and loads that are too high to be suitable for alloys based on more low-melting metals. The disadvantage of tungsten as bcc transition metal of IV group is its susceptibility to cold brittleness (low plasticity at temperatures below the ductile-brittle transition temperature Td/b). The aim of the present work was to develop the principle of the design of tungsten-based structural alloys and their manufacturing and treatment processes providing the production of high-strength high-temperature tungsten-based materials having a satisfactory low-temperature plasticity and workability both in thin sections and in large-scale articles. To achieve this goal, it was necessary to solve the following problems: 1. to elaborate the methods controlling the cold brittleness of tungsten with allowance for the factors responsible for this damage and with reference to the production method; 2. to elaborate the methods improving strength and high-temperature strength with allowance for the acceleration of diffusion processes in bcc metals at temperatures above 0.6 Tm and for the absence of 'more sluggish' alloying elements (AE) than the most refractory metal tungsten; 3. to elaborate the methods of the uniform distribution of AE and strengthening phases in conventionally melted or powder tungsten alloys for the stabilization of required phase composition and structural state and the required combination of the properties of tungsten-based materials; 4. to elaborate the possibility and reasonability to use one ore another type of alloying and microstructure formation upon the manufacturing and thermoplastic treatment with reference to the type and destination of semiproducts or articles produced from tungsten-based alloys or composites. (author)

  12. Corrosion resistance of Elektron 21 magnesium alloy

    Directory of Open Access Journals (Sweden)

    A. Kiełbus

    2007-05-01

    Full Text Available Purpose: Elektron 21 magnesium alloy containing neodymium, gadolinium and zinc has high strength, good corrosion resistance and excellent castability. It is designed mainly for aerospace applications. The purpose of the investigation was to study the corrosion resistance of Elektron 21 magnesium alloy in as cast condition and after heat treatment in 3.5% NaCl saturated with Mg(OH2 solution.Design/methodology/approach: Solution treatment was performed at 525°C/8h/water, while ageing treatments at following conditions 250°C/4-96h/air. Immersion test was performed in 3.5% NaCl saturated with Mg(OH2 solution at room temperature. Specimens were placed in 3.5% NaCl solution for periods of time between one and 5 days. After immersion test, the microstructure and the appearances of the corroded structure were examined by optical microscopy (Olympus GX-70 and a scanning electron microscopy (Hitachi S3400.Findings: The corrosion rates of Elektron 21 alloy increased with increasing the exposure time and finally (after 5 days reached maximum value 0.092 mg/cm-2day-1. Solution treatment at 520°C for 8 h caused decrease in corrosion rate (0.072 mg cm-2 day-1 due to dissolving of intermetallic phase precipitates at matrix. Ageing at 200°C for 4h and 16h caused next decrease in corrosion rate to value 0.052 and 0,055 mg cm-2 day-1 respectively, while after ageing for 48h corrosion rate increase to value 0.067 mg cm-2 day-1, due to increase of volume fraction and size of β’ phase and precipitations of equilibrium β phase. It was also noticed that the longer time of ageing the higher corrosion rates were observed.Research limitations/implications: Future researches should include investigations of the influence of other environments on the corrosion resistance of Elektron 21 alloy.Practical implications: The improvement of corrosion resistance of Elektron 21 alloy can cause increase in it application in aerospace industry.Originality/value: The

  13. Solid State Joining of Dissimilar Titanium Alloys

    Science.gov (United States)

    Morton, Todd W.

    Solid state joining of titanium via friction stir welding and diffusion bonding have emerged as enablers of efficient monolithic structural designs by the eliminations fasteners for the aerospace industry. As design complexity and service demands increase, the need for joints of dissimilar alloys has emerged. Complex thermomechanical conditions in friction stir weld joints and high temperature deformation behavior differences between alloys used in dissimilar joints gives rise to a highly variable flow pattern within a stir zone. Experiments performed welding Ti-6Al-4V to beta21S show that mechanical intermixing of the two alloys is the primary mechanism for the generation of the localized chemistry and microstructure, the magnitude of which can be directly related to pin rotation and travel speed weld parameters. Mechanical mixing of the two alloys is heavily influenced by strain rate softening phenomena, and can be used to manipulate weld nugget structure by switching which alloy is subjected to the advancing side of the pin. Turbulent mixing of a weld nugget and a significant reduction in defects and weld forces are observed when the beta21S is put on the advancing side of the weld where higher strain rates are present. Chemical diffusion driven by the heat of weld parameters is characterized using energy dispersive x-ray spectroscopy (EDS) and is shown to be a secondary process responsible for generating short-range chemical gradients that lead to a gradient of alpha particle structures. Diffusion calculations are inconsistent with an assumption of steady-state diffusion and show that material interfaces in the weld nugget evolve through the break-down of turbulent interface features generated by material flows. A high degree of recrystallization is seen throughout the welds, with unique, hybrid chemistry grains that are generated at material interfaces in the weld nugget that help to unify the crystal structure of dissimilar alloys. The degree of

  14. Structural and magnetic properties of nanocrystalline Fe–Co–Si alloy powders produced by mechanical alloying

    Energy Technology Data Exchange (ETDEWEB)

    Shyni, P.C.; Perumal, Alagarsamy, E-mail: perumal@iitg.ernet.in

    2015-11-05

    We report the structural and magnetic properties of nanocrystalline Fe{sub 100−x−y}Co{sub y}Si{sub x} (x = 10, 15, y = 0–20) alloy powders prepared by mechanical alloying process in a planetary ball mill. All the as-milled powders exhibit non-equilibrium α-Fe(Co,Si) solid solution with average crystallite size of 7–11 nm. The lattice constant increases initially up to 10 at.% Co and then decreases with further increase in Co content due to delay in dissolution of Co into Fe lattice by the introduction of more Si. The variations of structural parameters such as average crystallite size, dislocation density and fraction of grain boundary as a function of Co content show good correlations among them. The substitution of Co in Fe{sub 100−x−y}Co{sub y}Si{sub x} alloy powder increases both saturation magnetization and coercivity due to atomic ordering which induce additional magnetic anisotropy. Thermomagnetization studies reveal that Curie temperature (T{sub C}) increases at a rate of 4 K per at.% Co for Co content up to 10 at.% and the rate of increase in T{sub C} reduces to 1.4 K per at.% Co for higher Co addition. The variation of structural and magnetic parameters reveals a strong dependence on the composition of Fe–Co–Si alloy. The observed results show the improvement in soft magnetic properties of nanocrystalline Fe–Co–Si alloy powders by proper substitution of Co and Si for Fe. - Graphical abstract: Structural and magnetic properties of nanocrystalline Fe{sub 100−x−y}Co{sub y}Si{sub x} alloy powders prepared by mechanical alloying process in a planetary ball mill are reported. The non-equilibrium solid solution with nanosized crystallites could be obtained for all the alloy powders. The substitution of Co in Fe{sub 100−x−y}Co{sub y}Si{sub x} alloy powder increases both saturation magnetization and coercivity. The Curie temperature also increases with increasing Co content. The observed results show the improvement in soft magnetic

  15. Simulation study for atomic size and alloying effects during forming processes of amorphous alloys

    Institute of Scientific and Technical Information of China (English)

    ZHENG Caixing; LIU Rangsu; PENG Ping; ZHOU Qunyi

    2004-01-01

    A molecular dynamics (MD) simulation study has been performed for the solidification processes of two binary liquid alloys Ag6Cu4 and CuNi by adopting the quantum Sutton-Chen many-body potentials. By analyzing bond-types, it is demonstrated that at the cooling rate of 2×1012K/s, the CuNi forms fcc crystal structures, while the Ag6Cu4 forms amorphous structures. The original reason is that the atomic radius ratio (1.13) of the CuAg is bigger than that (1.025) of the CuNi. This shows that the atomic size difference is indeed the main factor for forming amorphous alloys. Moreover, for Ag60Cu40,corresponding to the deep eutectic point in the phase diagram, it forms amorphous structure easily. This confirms that as to the forming tendency and stability of amorphous alloys, the alloying effect plays a key role. In addition, having analyzed the transformation of microstructures by using the bond-type index and cluster-type index methods, not only the key role of the icosahedral configuration to the formation and stability of amorphous alloys can be explained, but also the solidification processes of liquid metals and the characteristics of amorphous structures can be further understood.

  16. Effect of alloying and heat treatment on the formation of recrystallization cube texture in nickel alloys

    International Nuclear Information System (INIS)

    Specific features of manufacturing thin ribbons with acute cubic texture of nickel and nickel base alloys (Ni-Cr, Ni-W, Ni-Nb, Ni-V) are under consideration. The ribbons are used as substrates to create perfect crystal structure during epitaxial deposition of buffer and functional layers. It is shown that on using alloying elements when obtaining FCC nickel alloys the application of 99.93% pure nickel is possible. To obtain the perfect structure with a {100} cubic component content of 90-95% the initial grain size prior to deformation is desirable to be no greater than 30-40 μm. Nickel base alloys with Va, VIa and VIIa group transition elements remain the cubic texture of recrystallization up to 1000-1150 Deg C. Magnetic and nonmagnetic (with Tc<70 K) ribbons-substrates with a perfect cubic texture can be manufactured from textureless alloy billets with fine grains (below 40 μm) by 98-99% deformation and an one-hour annealing at 900-1100 Deg C in vacuum or protective environment

  17. Enhancement of wear and corrosion resistance of beta titanium alloy by laser gas alloying with nitrogen

    Science.gov (United States)

    Chan, Chi-Wai; Lee, Seunghwan; Smith, Graham; Sarri, Gianluca; Ng, Chi-Ho; Sharba, Ahmed; Man, Hau-Chung

    2016-03-01

    The relatively high elastic modulus coupled with the presence of toxic vanadium (V) in Ti6Al4V alloy has long been a concern in orthopaedic applications. To solve the problem, a variety of non-toxic and low modulus beta-titanium (beta-Ti) alloys have been developed. Among the beta-Ti alloy family, the quaternary Ti-Nb-Zr-Ta (TNZT) alloys have received the highest attention as a promising replacement for Ti6Al4V due to their lower elastic modulus and outstanding long term stability against corrosion in biological environments. However, the inferior wear resistance of TNZT is still a problem that must be resolved before commercialising in the orthopaedic market. In this work, a newly developed laser surface treatment technique was employed to improve the surface properties of Ti-35.3Nb-7.3Zr-5.7Ta alloy. The surface structure and composition of the laser-treated TNZT surface were examined by grazing incidence X-ray diffraction (GI-XRD) and X-ray photoelectron spectroscopy (XPS). The wear and corrosion resistance were evaluated by pin-on-plate sliding test and anodic polarisation test in Hanks' solution. The experimental results were compared with the untreated (or base) TNZT material. The research findings showed that the laser surface treatment technique reported in this work can effectively improve the wear and corrosion resistance of TNZT.

  18. Platinum-ruthenium-palladium alloys for use as a fuel cell catalyst

    Science.gov (United States)

    Gorer, Alexander

    2002-01-01

    A noble metal alloy composition for a fuel cell catalyst, a ternary alloy composition containing platinum, ruthenium and palladium. The alloy shows increased activity as compared to well-known catalysts.

  19. Implants for surgery -- Metallic materials -- Part 3: Wrought titanium 6-aluminium 4-vanadium alloy

    CERN Document Server

    International Organization for Standardization. Geneva

    1996-01-01

    Specifies the characteristics of, and corresponding test methods for, the wrought titanium alloy known as titanium 6-aluminium 4-vanadium alloy (Ti 6-Al 4-V alloy) for use in the manufacture of surgical implants.

  20. NEW METHOD OF PRODUCTION OF ALUNINUM SILICON ALLOYS

    Directory of Open Access Journals (Sweden)

    V. K. Afanasiev

    2015-01-01

    Full Text Available A new approach to the preparation of aluminum-silicon alloys, based on the concept of the leading role of hydrogen in determining the structure and properties of alloys consists in using as charge materials of silicon dioxide (silica and hydrogen instead of crystalline silicon was described. Practical ways to implement the new method were proposed on the example of industrial alloys prepared on charge synthetic alloy. It is shown that the application of the proposed method allows to improve the mechanical properties and reduce the coefficient of thermal expansion alloys, Al-Si. The effect of heat treatment on mechanical properties, density and thermal expansion of synthetic alloys was researched.

  1. Precision forging technologies for magnesium alloy bracket and wheel

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    Fundamental investigations on precision forging technology of magnesium alloys were studied. As-cast billet prestraining and a new concept of hollow billet were proposed in order to reduce the maximum forming load. A scheme of isothermal forming and the use of combined female dies were adopted, which can improve the die filling capacity and ensure the manufacture of high quality forgings. By means of the developed technique, AZ80 alloy wheel and AZ31 alloy bracket were produced successfully at suitable process parameters and applied in the automotive industries. The results show that the hot compression of AZ80 magnesium alloy has the peak flow stresses of pre-strained alloy with finer grain, which are lower by 20% than those of as-cast alloy under the same deformation conditions. The forming load is related to contact area and average positive stress on interface during forging process.

  2. Composition Range of Amorphous Mg-Ni-Y Alloys

    Institute of Scientific and Technical Information of China (English)

    陈红梅; 钟夏平; 欧阳义芳

    2003-01-01

    Based on the thermodynamic point of view, a method for predication of the composition range of amorphous ternary alloys was proposed. The composition range of amorphous ternary alloys is determined by the comparison of the excess free energy of the amorphous alloy and the free energy of competing crystalline states. The free energy is extrapolated from the data of three binary alloys by using Toop′s model. The method was applied to predict the composition range of amorphous Mg-Ni-Y alloys. The theoretical results are in good agreement with the available experimental results. It indicates that the present method can be used to predict the composition range for amorphous ternary alloys.

  3. Trace Carbon in Biomedical Beta-Titanium Alloys: Recent Progress

    Science.gov (United States)

    Zhao, D.; Ebel, T.; Yan, M.; Qian, M.

    2015-08-01

    Owing to their relatively low Young's modulus, high strength, good resistance to corrosion, and excellent biocompatibility, β-titanium (Ti) alloys have shown great potential for biomedical applications. In β-Ti alloys, carbon can exist in the form of titanium carbide (TiC x ) as well as interstitial atoms. The Ti-C binary phase diagram predicts a carbon solubility value of 0.08 wt.% in β-Ti, which has been used as the carbon limit for a variety of β-Ti alloys. However, noticeable grain boundary TiC x particles have been observed in β-Ti alloys containing impurity levels of carbon well below the predicted 0.08 wt.%. This review focuses its attention on trace carbon (≤0.08 wt.%) in biomedical β-Ti alloys containing niobium (Nb) and molybdenum (Mo), and it discusses the nature and precipitation mechanism of the TiC x particles in these alloys.

  4. Production of FR Tubing from Advanced ODS Alloys

    Energy Technology Data Exchange (ETDEWEB)

    Maloy, Stuart Andrew [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Lavender, Curt [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Omberg, Ron [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Lewandowski, John [Case Western Reserve Univ., Cleveland, OH (United States)

    2016-10-25

    Significant research is underway to develop LWR nuclear fuels with improved accident tolerance. One of the leading candidate materials for cladding are the FeCrAl alloys. New alloys produced at ORNL called Gen I and Gen II FeCrAl alloys possess excellent oxidation resistance in steam up to 1400°C and in parallel methods are being developed to produce tubing from these alloys. Century tubing continues to produce excellent tubing from FeCrAl alloys. This memo reports receipt of ~21 feet of Gen I FeCrAl alloy tubing. This tubing will be used for future tests including burst testing, mechanical testing and irradiation testing.

  5. Electrodeposited NiCu Alloy Catalysts for Glucose Oxidation

    International Nuclear Information System (INIS)

    NiCu alloys have been suggested as potential candidates for catalysts in glucose oxidation. In this study, NiCu alloys with different compositions were prepared on a glassy carbon substrate by changing the electrodeposition potential to examine the effect of Ni/Cu ratios in alloys on catalytic activity toward glucose oxidation. Cyclic voltammetry and chronoamperometry showed that NiCu alloys had higher catalytic activity than pure Ni and Cu catalysts. Especially, Ni59Cu41 had superior catalytic activity, which was about twice that of Ni at a given oxidation potential. X-ray analyses showed that the oxidation state of Ni in NiCu alloys was increased with the content of Cu by lattice expansion. Ni components in alloys with higher oxidation state were more effective in the oxidation of glucose

  6. Corrosion of high-density sintered tungsten alloys. Part 1

    International Nuclear Information System (INIS)

    The corrosion behaviour of four tungsten alloys has been evaluated through weight loss measurements after total immersion in both distilled water insight into the mechanism of corrosion was afforded by an examination of the and 5% sodium chloride solutions. Some insight the mechanism of corrosion was afforded by using the Scanning Electron Microscopy and through an analysis of the corrosion products. Pure tungsten and all the alloys studied underwent corrosion during the tests, and in each case the rare of corrosion in sodium chloride solution was markedly less than that in distilled water. A 95% W, 3.5% Ni, 1.5% Fe alloy was found to be the most corrosion resistant of the alloys under the experimental conditions. Examination of the data shows that for each of the tests, copper as an alloying element accelerates corrosion of tungsten alloys. 9 refs., 7 tabs., 12 figs

  7. Development and Processing Improvement of Aerospace Aluminum Alloys

    Science.gov (United States)

    Lisagor, W. Barry; Bales, Thomas T.

    2007-01-01

    This final report, in multiple presentation format, describes a comprehensive multi-tasked contract study to improve the overall property response of selected aerospace alloys, explore further a newly-developed and registered alloy, and correlate the processing, metallurgical structure, and subsequent properties achieved with particular emphasis on the crystallographic orientation texture developed. Modifications to plate processing, specifically hot rolling practices, were evaluated for Al-Li alloys 2195 and 2297, for the recently registered Al-Cu-Ag alloy, 2139, and for the Al-Zn-Mg-Cu alloy, 7050. For all of the alloys evaluated, the processing modifications resulted in significant improvements in mechanical properties. Analyses also resulted in an enhanced understanding of the correlation of processing, crystallographic texture, and mechanical properties.

  8. HIGH CYCLE FATIGUE PROPERTIES OF NICKEL-BASE ALLOY 718

    Institute of Scientific and Technical Information of China (English)

    K.Kobayashi; K.Yamaguchi; M.Hayakawa; M.Kimura

    2004-01-01

    The fatigue properties of nickel-base Alloy 718 with fine- and grain-coarse grains were investigated. In the fine-grain alloy, the fatigue strength normalized by the tensile strengtn was 0.51 at 107 cycles. In contrast, the fatigue strength of the coarse-grain alloy was 0.32 at the same cycles, although the fatigue strengths in the range from 103to 105 cycles are the same for both alloys. The fracture appearances fatigued at around 106 cycles showed internal fractures originating from the flat facets of austenite grains for both alloys. The difference in fatigue strength at 107 cycles between the fine- and coarse-grain alloys could be explained in terms of the sizes of the facets from which the fractures originated.

  9. Intermetallic alloy welding wires and method for fabricating the same

    Science.gov (United States)

    Santella, M.L.; Sikka, V.K.

    1996-06-11

    Welding wires for welding together intermetallic alloys of nickel aluminides, nickel-iron aluminides, iron aluminides, or titanium aluminides, and preferably including additional alloying constituents are fabricated as two-component, clad structures in which one component contains the primary alloying constituent(s) except for aluminum and the other component contains the aluminum constituent. This two-component approach for fabricating the welding wire overcomes the difficulties associated with mechanically forming welding wires from intermetallic alloys which possess high strength and limited ductilities at elevated temperatures normally employed in conventional metal working processes. The composition of the clad welding wires is readily tailored so that the welding wire composition when melted will form an alloy defined by the weld deposit which substantially corresponds to the composition of the intermetallic alloy being joined. 4 figs.

  10. Reaction layers structure of silicide coatings on niobium alloys

    International Nuclear Information System (INIS)

    This paper reports on fused silicide coatings that are used to protect niobium alloys against high temperature oxidation. Quantitative electron microprobe analysis was used to characterize the complex multilayer structure of Si-20w/oFE-20w/oCR fused silicide coating on four niobium containing alloys: niobium, Cb752, WC3009, and Nb-46.5 Ti. The outer coating layer structure on all four alloys was similar, consisting of either two or three phases. The three phase outer coating layer on the niobium, WC3009, and the Nb-Ti substrate alloys was determined to be made of two MSi phases and one MSi2 phase. This outer MSi2 phase contained base alloy elements. Coated samples were compared using cyclic oxidation testing. The fused silicide coating structure and protectiveness were determined to be a function of the base alloy composition

  11. Electrodeposited NiCu Alloy Catalysts for Glucose Oxidation

    Energy Technology Data Exchange (ETDEWEB)

    Lim, Jieun; Park, Hansoo; Kim, Sookil [Chung-Ang Univ., Seoul (Korea, Republic of); Ahn, Sang Hyun; Jang, Jong Hyun [Korea Institute of Science and Technology, Seoul (Korea, Republic of)

    2014-07-15

    NiCu alloys have been suggested as potential candidates for catalysts in glucose oxidation. In this study, NiCu alloys with different compositions were prepared on a glassy carbon substrate by changing the electrodeposition potential to examine the effect of Ni/Cu ratios in alloys on catalytic activity toward glucose oxidation. Cyclic voltammetry and chronoamperometry showed that NiCu alloys had higher catalytic activity than pure Ni and Cu catalysts. Especially, Ni{sub 59}Cu{sub 41} had superior catalytic activity, which was about twice that of Ni at a given oxidation potential. X-ray analyses showed that the oxidation state of Ni in NiCu alloys was increased with the content of Cu by lattice expansion. Ni components in alloys with higher oxidation state were more effective in the oxidation of glucose.

  12. Research activities of biomedical magnesium alloys in China

    Science.gov (United States)

    Zheng, Yufeng; Gu, Xuenan

    2011-04-01

    The potential application of Mg alloys as bioabsorable/biodegradable implants have attracted much recent attention in China. Advances in the design and biocompatibility evaluation of bio-Mg alloys in China are reviewed in this paper. Bio-Mg alloys have been developed by alloying with the trace elements existing in human body, such as Mg-Ca, Mg-Zn and Mg-Si based systems. Additionally, novel structured Mg alloys such as porous, composited, nanocrystalline and bulk metallic glass alloys were tried. To control the biocorrosion rate of bio-Mg implant to match the self-healing/regeneration rate of the surrounding tissue in vivo, surface modification layers were coated with physical and chemical methods.

  13. Shape memory alloys: New materials for future engineering

    Science.gov (United States)

    Hornbogen, E.

    1988-01-01

    Shape memory is a new material property. An alloy which experiences relative severe plastic deformation resumes its original shape again after heating by 10 to 100 C. Besides simple shape memory, in similar alloys there is the second effect where the change in shape is caused exclusively by little temperature change. In pseudo-elasticity, the alloy exhibits a rubber-like behavior, i.e., large, reversible deformation at little change in tension. Beta Cu and beta NiTi alloys have been used in practice. The probability is that soon alloys based on Fe will become available. Recently increasing applications for this alloy were found in various areas of technology, even medical technology. A review with 24 references is given, including properties, production, applications and fundamental principles of the shape memory effect.

  14. Estimation of thermal expansion properties of quasicrystalline alloys

    Institute of Scientific and Technical Information of China (English)

    齐育红; 张占平; 黑祖昆

    2004-01-01

    By investigating the thermal expansion properties of three quasicrystalline alloys Al65 Cu20 Cr15 quenched,Al65Cu20Cr15 cast and Al65Cu20Fe15 cast particles reinforced Al matrix composites from 25 ℃ to 500 ℃, the thermal expansion coefficients of three quasicrystalline alloys were theoretically estimated. The results show that the thermal expansion coefficients of the composites are much lower than that of pure Al, and the thermal expansion coefficients of the composites reinforced by Al-Cu-Cr quasicrystalline particles are lower than those of the composites reinforced by Al-Cu-Fe quasicrystalline particles. According to estimating, quasicrystalline alloys have negative thermal expansion coefficients, and the thermal expansion coefficients of Al-Cu-Cr quasicrystalline alloys are lower than those of Al-Cu-Fe quasicrystalline alloys. In the alloys, the more the qusicrystalline content, the lower the thermal expansion coefficient.

  15. Predicting the properties of the lead alloys from DFT calculations

    Energy Technology Data Exchange (ETDEWEB)

    Buimaga-Iarinca, L., E-mail: luiza.iarinca@itim-cj.ro; Calborean, A. [National Institute for Research and Development of Isotopic and Molecular Technologies, 67-103 Donat, 400293 Cluj-Napoca (Romania)

    2015-12-23

    We provide qualitative results for the physical properties of the lead alloys at atomic scale by using DFT calculations. Our approach is based on the two assumptions: (i) the geometric structure of lead atoms provides a matrix where the alloying elements can take their positions in the structure as substitutions and (ii) there is a small probability of a direct interaction between the alloying elements, thus the interactions of each alloying element may be approximated by the interactions to the lead matrix. DFT calculations are used to investigate the interaction between several types of impurities and the lead matrix for low concentrations of the alloying element. We report results such as the enthalpy of formation, charge transfer and mechanical stress induced by the impurities in the lead matrix; these results can be used as qualitative guide in tuning the physico-chemical properties of the lead alloys.

  16. Compressive creep behavior of Mg-Sn binary alloy

    Institute of Scientific and Technical Information of China (English)

    2008-01-01

    Mg-Sn based alloy is one of the potential alloys for application at elevated temperature. The compressive creep behavior of ageing-treated Mg-xSn (x=3%, 5%) alloys was investigated at the temperatures of 423 and 473 K and the stresses from 25 MPa to 35 MPa. When the tin content varies, the ageing-treated Mg-xSn alloys show quite different creep resistance, which are mainly attributed to the size and distribution of Mg2Sn phases in the ageing-treated Mg-xSn alloys. The calculated value of stress exponent,n=6.3, suggests that the compressive creep behavior of the ageing-treated Mg-5%Sn alloy is controlled by dislocation creep at the temperature of 473 K and the stresses from 25 MPa to 35 MPa.

  17. Aluminum alloys for ALS cryogenic tanks: Comparative measurements of cryogenic mechanical properties of Al-Li alloys and alloy 2219, February 1993

    International Nuclear Information System (INIS)

    Tensile and fracture toughness were obtained at cryogenic temperatures to compare the Al-Li alloys 8090, 2090, and WL049, and alloy 2219 in various tempers and specimen orientations. The strongest alloy at very low temperatures is WL049-T851, which is about 10 percent stronger than 2090-T81. Both alloys are considerably stronger than 2219-T87. Alloy 2090-T81 is tougher (about 50 percent) than WL049-T851 at low temperatures; the higher toughness is attributed to the presence of fewer constituent particles and the tendency to delaminate at low temperatures. The delamination divides the moving crack, thus separating it into smaller regions where plane stress (rather than plane strain) conditions are conducive to increased toughness

  18. Layered Structures in Deformed Metals and Alloys

    DEFF Research Database (Denmark)

    Hansen, Niels; Zhang, Xiaodan; Huang, Xiaoxu

    2014-01-01

    Layered structures characterize metals and alloys deformed to high strain. The morphology is typical lamellar or fibrous and the interlamellar spacing can span several length scales down to the nanometer dimension. The layered structures can be observed in bulk or in surface regions, which is shown...... by the way of examples of different processing routes: friction, wire drawing, shot peening, high pressure torsion and rolling. The interlamellar spacing reaches from 5-10 nanometers to about one micrometer and the analysis will cover structural evolution, strengthening parameters and strength-structure...... relationships. Finally, the results will be discussed based on universal principles for the evolution of microstructure and properties during plastic deformation of metals and alloys from low to high strain....

  19. Laser Brazing of High Temperature Braze Alloy

    Science.gov (United States)

    Gao, Y. P.; Seaman, R. F.; McQuillan, T. J.; Martiens, R. F.

    2000-01-01

    The Space Shuttle Main Engine (SSME) consists of 1080 conical tubes, which are furnace brazed themselves, manifolds, and surrounding structural jacket making almost four miles of braze joints. Subsequent furnace braze cycles are performed due to localized braze voids between the coolant tubes. SSME nozzle experiences extremely high heat flux (180 mW/sq m) during hot fire. Braze voids between coolant tubes may result in hot combustion gas escape causing jacket bulges. The nozzle can be disqualified for flight or result in mission failure if the braze voids exceed the limits. Localized braze processes were considered to eliminate braze voids, however, damage to the parent materials often prohibited use of such process. Being the only manned flight reusable rocket engine, it has stringent requirement on the braze process. Poor braze quality or damage to the parent materials limits the nozzle service life. The objective of this study was to develop a laser brazing process to provide quality, localized braze joints without adverse affect on the parent materials. Gold (Au-Cu-Ni-Pd-Mn) based high temperature braze alloys were used in both powder and wire form. Thin section iron base superalloy A286 tube was used as substrate materials. Different Laser Systems including CO2 (10.6 micrometers, 1kW), ND:YAG (1.06 micrometers, 4kW). and direct diode laser (808nm. 150W) were investigated for brazing process. The laser process variables including wavelength. laser power, travel speed and angle of inclination were optimized according to bead geometry and braze alloy wetting at minimum heat input level, The properties of laser brazing were compared to that of furnace brazing. Microhardness profiles were used for braze joint property comparison between laser and furnace brazing. The cooling rate of laser brazing was compared to furnace brazing based on secondary dendritic arm spacing, Both optical and Scanning Electron Microscope (SEM) were used to evaluate the microstructures of

  20. Etching Behavior of Aluminum Alloy Extrusions

    Science.gov (United States)

    Zhu, Hanliang

    2014-11-01

    The etching treatment is an important process step in influencing the surface quality of anodized aluminum alloy extrusions. The aim of etching is to produce a homogeneously matte surface. However, in the etching process, further surface imperfections can be generated on the extrusion surface due to uneven materials loss from different microstructural components. These surface imperfections formed prior to anodizing can significantly influence the surface quality of the final anodized extrusion products. In this article, various factors that influence the materials loss during alkaline etching of aluminum alloy extrusions are investigated. The influencing variables considered include etching process parameters, Fe-rich particles, Mg-Si precipitates, and extrusion profiles. This study provides a basis for improving the surface quality in industrial extrusion products by optimizing various process parameters.

  1. Niobium Silicon alloys for Kinetic Inductance Detectors

    CERN Document Server

    Calvo, M; Monfardini, A; Benoit, A; Boudou, N; Bourrion, O; Catalano, A; Dumoulin, L; Goupy, J; Sueur, H Le; Marnieros, S

    2013-01-01

    We are studying the properties of Niobium Silicon amorphous alloys as a candidate material for the fabrication of highly sensitive Kinetic Inductance Detectors (KID), optimized for very low optical loads. As in the case of other composite materials, the NbSi properties can be changed by varying the relative amounts of its components. Using a NbSi film with T_c around 1 K we have been able to obtain the first NbSi resonators, observe an optical response and acquire a spectrum in the band 50 to 300 GHz. The data taken show that this material has very high kinetic inductance and normal state surface resistivity. These properties are ideal for the development of KID. More measurements are planned to further characterize the NbSi alloy and fully investigate its potential.

  2. Thermal Properties of Al-50%Si Alloys

    Institute of Scientific and Technical Information of China (English)

    Akio Nishimoto; Katsuya Akamatsu; Kazuyoshi Nakao; Kazuo Ichii

    2004-01-01

    In order to prepare a hypereutectic Al-Si alloy with low coefficients of thermal expansion (CTE), Al-50was produced by powder metallurgy (P/M) and ingot metallurgy (I/M). P/M specimen was prepared by mechanical alloying(MA) and pulsed electric-current sintering (PECS). The microstructures of specimens were characterized by optical microscopy and scanning electron microscopy (SEM) equipped with energy dispersive X-ray spectroscopy (EDS). Vickers microhardness and CTE measurements were performed. The grains in the P/M specimen were refined with increasing MA time. Primary Si and eutectic Si in the I/M specimen were remarkably refined by adding minute amounts of Sr. The CTE of P/M and I/M specimens were estimated as 7.8×10-6 and 10.7×10-6, respectively. These values were as same as a CTE of Al2O3 ceramics.

  3. Antiferromagnetic behaviour of Tb2Al alloy

    Science.gov (United States)

    Rojas, D. P.; André, G.; Rodríguez Fernández, J.; Sánchez Marcos, J.; Fernández Barquín, L.; Echevarria, C.

    2011-10-01

    The structural, thermal and magnetic properties ol the Tb2Al alloy have been investigated by AC/DC magnetic susceptibility, specific heat, X-ray and neutron diffraction measurements. DC and AC-magnetic susceptibility results are consistent with an AFM order at TN = 52 K. The specific heat data show a lambda anomaly associated to the magnetic transition with a peak at 52 K (cord = 99 J/molTbK). The analysis of thermodiffractograms of neutron diffraction patterns indicates that, below the ordering temperature, the magnetic reflections can be indexed with a commensurate lattice related to the crystallographic cell (Pmna) by a propagation vector k = (1/2, 1/2, 1/2). The results are compared with those reported for other magnetic rare earth alloys of R2Al-type (with R = Nd, Gd and Dy).

  4. Antiferromagnetic behaviour of Tb2Al alloy

    International Nuclear Information System (INIS)

    The structural, thermal and magnetic properties ol the Tb2Al alloy have been investigated by AC/DC magnetic susceptibility, specific heat, X-ray and neutron diffraction measurements. DC and AC-magnetic susceptibility results are consistent with an AFM order at TN = 52 K. The specific heat data show a lambda anomaly associated to the magnetic transition with a peak at 52 K (cord = 99 J/molTbK). The analysis of thermodiffractograms of neutron diffraction patterns indicates that, below the ordering temperature, the magnetic reflections can be indexed with a commensurate lattice related to the crystallographic cell (Pmna) by a propagation vector k = (1/2, 1/2, 1/2). The results are compared with those reported for other magnetic rare earth alloys of R2Al-type (with R = Nd, Gd and Dy).

  5. Electrical conductivity of Cu-Li alloys

    Institute of Scientific and Technical Information of China (English)

    朱达川; 宋明昭; 陈家钊; 涂铭旌; 潘海滨

    2004-01-01

    The electrical conductivity of Cu-Li alloys was studied. And the distribution of electrons near Fermi surface was detected by synchrotron radiation instrument. The results show that the electrical conductivity of Cu-Li alloys decreases from 5. 22 × 10-9 S/m to 3. 69 × 10-9 S/m with the increase of Li content. Li can decrease the oxygen, sulfur and other impurities content in commercial Cu, but Li dissolved in Cu lattice leads to distortion of Cu lattice from 0. 005 %-0. 050 %, affects the valence band of Cu, increases the binding energy of surface electron, and decreases the electron density of Fermi surface simultaneously. So the electrical conductivity decreases gradually with the increase of Li content.

  6. Dry face milling of titanium alloys

    Institute of Scientific and Technical Information of China (English)

    Ahmed Hassan; Zhenqiang Yao

    2004-01-01

    In machining titanium alloys, cutting tools generally wear out very rapidly because of the high cutting temperature resulted from the low thermal conductivity and density of the work material. In order to increase the tool life, it is necessary to suppress the cutting heat as much as possible by applying an abundant amount of coolant, but this will entail serious techno-environmental and biological problems. To study the performance and avoid these limitations, a PVD-coated insert was used to the dry face mill of (α +β) titanium alloys. As a result it was found that the inserts exhibit an excellent cutting performance at low cutting speeds and feed rates, and there is no significant difference in the dominant insert failure mode between the wet and dry cutting in discontinuous cutting.

  7. Stifling of Crevice Corrosion in Alloy 22

    Energy Technology Data Exchange (ETDEWEB)

    Mon, K G; Gordon, G M; Rebak, R B

    2005-06-08

    Artificially creviced Alloy 22 (N06022) specimens may be susceptible to crevice corrosion in presence of hot chloride containing solutions. The presence of oxyanions in the electrolyte, especially nitrate, may inhibit the nucleation and growth of crevice corrosion. Constant potential tests were performed using tightly creviced specimens of Alloy 22. It was found that crevice corrosion may initiate when a constant potential above the crevice repassivation potential is applied. It was found that as the crevice corrosion nucleated, the current initially increased but later decreased. The net measured current can be converted into penetration following a power law fit of the experimental data. The average power law coefficient ''n'' was found to be 0.439, suggesting that even under constant applied potential crevice corrosion penetration is diffusion controlled.

  8. STIFLING OF CREVICE CORROSION IN ALLOY 22

    Energy Technology Data Exchange (ETDEWEB)

    K.G. Mon; G.M. Gordon; R.B. Rebak

    2005-07-01

    Artificially creviced Alloy 22 (N06022) specimens may be susceptible to crevice corrosion in presence of hot chloride containing solutions. The presence of oxyanions in the electrolyte, especially nitrate, may inhibit the nucleation and growth of crevice corrosion. Constant potential tests were performed using tightly creviced specimens of Alloy 22. It was found that crevice corrosion may initiate when a constant potential above the crevice repassivation potential is applied. It was found that as the crevice corrosion nucleated, the current initially increased but later decreased. The net measured current can be converted into penetration following a power law fit of the experimental data. The average power law coefficient ''n'' was found to be 0.439, suggesting that even under constant applied potential, crevice corrosion penetration is diffusion controlled.

  9. Corrosion of carbon-alloyed iron aluminides

    Indian Academy of Sciences (India)

    M Sen; R Balasubramaniam; A V Ramesh Kumar

    2000-10-01

    The corrosion behaviour of two carbon-alloyed intermetallics of composition Fe–28.1Al–2.1C and Fe–27.5Al–3.7C has been studied and compared with that of binary intermetallics. Potentiodynamic polarization studies indicated that the intermetallics exhibited active–passive behaviour in an acidic solution of pH = 1, whereas they exhibited stable passivity in a buffer solution of pH 8.4. Corrosion rates were also obtained by immersion testing. The variation of corrosion rate as a function of time was similar for both the intermetallics. The variation in corrosion rate as a function of time has been explained based on the observed potentiodynamic polarization behaviour. Scanning electron microscopy of corroded surfaces indicated that the carbon-alloyed intermetallics were susceptible to galvanic corrosion, due to the presence of carbides.

  10. Corrosion resistance of Mg-RE-Zr alloys

    Directory of Open Access Journals (Sweden)

    A. Kiełbus

    2007-03-01

    Full Text Available Purpose: Magnesium alloys are widely used in the automotive and aerospace industries. Data concerning corrosion of Mg alloys are numerous, but those concerning Mg-RE alloys are scarce. In this paper, the corrosion behavior of cast magnesium alloys containing rare earth elements (WE54, WE43 and Elektron21 were investigated by immersion test in 3.5% NaCl for times up to 7 days.Design/methodology/approach: The study was conducted on WE54, WE43 and Elektron 21 alloys in the as-cast condition. Immersion test was performed using not deaerated 3.5% NaCl solution at room temperature. Several specimens were placed in 3.5% NaCl solution for periods of time between one and 7 days. The dissolution rates (mg/cm-2day-1 were determined by weight loss measurements.Findings: Elektron 21 alloy exhibits the highest corrosion rate during the immersion test, while WE54 and WE43 alloys had a similar corrosion behavior. The corrosion rates of WE54 and Elektron 21 alloys incresed lineally with increasing the exposure time in 3.5% NaCl, and that of WE43 was almost unchanged and finally reached maximum value 0.26 mg/cm-2day-1.Research limitations/implications: The knowledge about corrosion behavior of Mg-RE-Zr alloys is currently under evaluation on many speciality applications where lightweight connected with optimum corrosion resistance are requiredPractical implications: The comparative results of corrosion behavior of new Mg-RE-Zr alloys leads to optimum choice of alloy for application in automotive, aircraft and aerospace industries.Originality/value: This paper includes the comparative results of corrosion resistance investigations of new Mg-RE–Zr alloys.

  11. Aqueous corrosion study on U-Zr alloy

    International Nuclear Information System (INIS)

    In low power or research reactor, U-Zr alloy is a potential candidate for dispersion fuel. Moreover, Zirconium has a low thermal-neutron cross section and uranium alloyed with Zr has excellent corrosion resistance and dimensional stability during thermal cycling. In the present study aqueous corrosion behavior of U-Zr alloy samples was studied in autoclave at 200 deg C temperature. Corrosion rate was determined from weight loss with time. (author)

  12. China’s Aluminum Alloy Cable Market has Taken Shape

    Institute of Scientific and Technical Information of China (English)

    2014-01-01

    <正>Aluminum alloy cable is a mature product and technology that has been used for nearly fifty years in the U.S.Through six years’promotion,it has been widely recognized and accepted in the China market since 2013,which laid the foundation for the development of the aluminum alloy cable market.Aluminum alloy cable is widely applied in the fields of civil construction and industrial and mining enterprises,especially in real estate,steel and metallurgy.

  13. Influence of Magnesium Alloy Degradation on Undifferentiated Human Cells

    OpenAIRE

    Francesca Cecchinato; Nezha Ahmad Agha; Adela Helvia Martinez-Sanchez; Berengere Julie Christine Luthringer; Frank Feyerabend; Ryo Jimbo; Regine Willumeit-Römer; Ann Wennerberg

    2015-01-01

    Background Magnesium alloys are of particular interest in medical science since they provide compatible mechanical properties with those of the cortical bone and, depending on the alloying elements, they have the capability to tailor the degradation rate in physiological conditions, providing alternative bioresorbable materials for bone applications. The present study investigates the in vitro short-term response of human undifferentiated cells on three magnesium alloys and high-purity magnes...

  14. Mechanical alloying in the Fe-Cu system

    DEFF Research Database (Denmark)

    Jiang, Jianzhong; Gente, C.; Bormann, R.

    1998-01-01

    in the Fe-Cu system is; (3) where the positive energy is stored in the alloys; (4) what the decomposition process of the supersaturated alloys is; and (5) what type of magnetic properties the new materials have. The elucidation of these problems will shed light on the understanding of the mechanisms...... for the preparation of materials under highly non-equilibrium conditions in systems with positive heats of mixing by mechanical alloying....

  15. The Technological Improvements of Aluminum Alloy Coloring by Electrolysis

    Institute of Scientific and Technical Information of China (English)

    LI Nai-jun

    2004-01-01

    The technological process of coloring golden-tawny on aluminum alloy by electrolysis was improved in this paper. The optimum composition of electrolyte was found, the conditions of deposition and anodic oxidation by electrolysis were studied. The oxidative membrane on aluminum alloy was satisfying, the colored aluminum alloy by electrolysis is uniformity,bright and beautiful, and the coloring by electrolysis is convenient and no pollution.

  16. Friction factor of CP aluminium and aluminium–zinc alloys

    Indian Academy of Sciences (India)

    N Vidhya Sagar; K S Anand; A C Mithun; K Srinivasan

    2006-12-01

    Friction factor has been determined for CP aluminium and aluminium–zinc alloys using ring compression test at different temperatures from 303 K to 773 K. It is found that CP aluminium exhibits sticking whereas Al–Zn alloys do not exhibit sticking at elevated temperatures. Hot working of Al–Zn alloy is easier than that of CP aluminium at 773 K. As zinc content increases up to 10 wt% the friction factor decreases up to 0.02.

  17. INFLUENCE OF PARAMETERS OF CRYSTALLIZATION ON MODIFYING OF AN ALLOY

    Directory of Open Access Journals (Sweden)

    V. Yu. Stetsenko

    2015-01-01

    Full Text Available It is shown that extent of modifying of an alloy is proportional to overcooling at its hardening, viscosity of fusion and interphase superficial energy of crystals of the leading phase. The key technological parameters of modifying of an alloy are the speed of its hardening, viscosity of fusion and extent of refinement from surface-active elements. Their adsorption on crystals of the leading phase interferes with modifying of an alloy.

  18. Cobalt alloy ion sources for focused ion beam implantation

    Energy Technology Data Exchange (ETDEWEB)

    Muehle, R.; Doebeli, M. [Paul Scherrer Inst. (PSI), Villigen (Switzerland); Zimmermann, P. [Eidgenoessische Technische Hochschule, Zurich (Switzerland)

    1997-09-01

    Cobalt alloy ion sources have been developed for silicide formation by focused ion beam implantation. Four eutectic alloys AuCo, CoGe, CoY and AuCoGe were produced by electron beam welding. The AuCo liquid alloy ion source was investigated in detail. We have measured the emission current stability, the current-voltage characteristics, and the mass spectrum as a function of the mission current. (author) 1 fig., 2 refs.

  19. Surface composition of ordered alloys: An off-stoichiometric effect

    DEFF Research Database (Denmark)

    Ruban, Andrei

    2002-01-01

    I predict the existence of an off-stoichiometric effect in ordered alloys in the form of a distinct transition in the surface segregation behavior of alloy components near the bulk stoichiometric composition. It is caused by the discontinuity in the effective chemical potential at the stoichiomet...... at the stoichiometric composition. The effect is predicted to occur at the (111) surface of ordered Ni3Al and Pt3Fe alloys....

  20. Microstructure and kinetics of hot deformation WE43 magnesium alloy

    Institute of Scientific and Technical Information of China (English)

    GAO Jiacheng; WANG Qiang; WANG Yong; LI Wei; NIU Wenjuan

    2008-01-01

    The effect of compression on the rnicrostructures and flow behavior of WE43 magnesium alloy was investigated in this article.The relationship between flow stress and strain rate was discussed.According to the empirical formula ε = Aσn exp(-Q/RT),the value of heat activation of WFA3 magnesium alloys is 297.15 kJ/mol.A mechanism of deformation softening of WEA3 alloy in testing hot deformation was identified to be dynamic recrystallization.

  1. Processing and production of molybdenum and tungsten alloys

    International Nuclear Information System (INIS)

    The technological means to produce and process Mo and W alloys are summarized because for many Mo and W alloy systems the mechanical properties can be optimized only by thermomechanical processing requiring production and processing capabilities that are not widely available. First, the producers of commercial Mo and W alloys are presented along with currently available product forms. Second, currently disclosed standard capabilities of producers and processors in the United States are presented. 56 references, 13 figures, 9 tables

  2. Effect of Carbon on DA718 Alloy with P Addition

    Institute of Scientific and Technical Information of China (English)

    Na LI; Shouren GUO; Dezhong LU; Wenru SUN; Yan XU; Zhuangqi HU

    2003-01-01

    Lower content of carbon can further improve the stress rupture life of p-modified DA 718 alloy up to more than 270%.Meanwhile, the ductility of the alloy decreased a little. More boron atoms dissociate due to decreasing carbon content and interact with phosphorus which brings the longer stress rupture life of the alloy. Less carbon may induce more phosphorus segregating in the grain boundary and result in brittleness.

  3. Crystallographic orientation-spray formed hypereutectic aluminium-silicon alloys

    OpenAIRE

    Hamilta de Oliveira Santos; Marilene Morelli Serna; Nelson Batista de Lima; Isolda Costa; Jesualdo Luiz Rossi

    2005-01-01

    Aluminium-silicon alloys have been wide accepted in the automotive, electric and aerospace industries. Preferred orientation is a very common condition for metals and alloys. Particularly, aluminium induces texture during the forming process. The preparation of an aggregate with completely random crystal orientation is a difficult task. The present work was undertaken to analyse the texture by X-ray diffraction techniques, of three spray formed hypereutectic Al-Si alloys. Samples were taken f...

  4. Polymer blends formed by the solid state mechanical alloying process

    OpenAIRE

    Farrell, Michael P.

    1994-01-01

    In the early 1970's a new processing technique to produce metallic alloys was developed by Benjamin and co-workers. This novel technique, called Mechanical Alloying (MA), involves the repeated welding, working hardening, and fracture of metallic powders to form an alloy. The research presented in this thesis describes the use of the MA process to form polymer blends. Until recently there has been no published work discussing the possibility of using this technique with polymers...

  5. Local electrochemical behaviour of 7xxx aluminium alloys

    OpenAIRE

    F. Andreatta

    2004-01-01

    Aluminium alloys of the 7xxx series (Al-Zn-Mg-Cu) are susceptible to localized types of corrosion like pitting, intergranular corrosion and exfoliation corrosion. This represents a limitation for the application of these alloys in the aerospace components because localized corrosion might have a negative effect on safety and costs. This PhD thesis investigates the relation between electrochemical behaviour and microstructure of a number of 7xxx aluminium alloys: AA7075, AA7349 and an experime...

  6. Nanocrystalline Ni-Co Alloy Synthesis by High Speed Electrodeposition

    OpenAIRE

    Jamaliah Idris; Chukwuekezie Christian; Eyu Gaius

    2013-01-01

    Electrodeposition of nanocrystals is economically and technologically viable production path for the synthesis of pure metals and alloys both in coatings and bulk form. The study presents nanocrystalline Ni-Co alloy synthesis by high speed electrodeposition. Nanocrystalline Ni-Co alloys coatings were prepared by direct current (DC) and deposited directly on steel and aluminum substrates without any pretreatment, using high speed electrodeposition method. The influence of the electrolysis par...

  7. Experience with ferrosilicoaluminum alloy during deoxidation of steel

    OpenAIRE

    Mekhtiyev, A.; Akhmetov, A.; V. Yudakova; Bulatbayev, F.

    2016-01-01

    The article describes the process of deoxidation quiet and low-alloyed steel alloy ferrosilicoaluminum complex in comparison the existing, and with steel deoxidation technology with conventional alloys - ferrosilicon and secondary aluminum. A comparative analysis of quality steel, non-metallic inclusions metallographic studies and studies of the mechanical properties of the resulting steel was done. On a large array of experimental steel proved cost-effectiveness and feasibility of ferrosilic...

  8. The Strengthening of Cu-15Ni-8Sn Alloy

    Institute of Scientific and Technical Information of China (English)

    WANG Yan-hui; WANG Ming-pu; HONG Bin

    2004-01-01

    The microstructure, property and relation between them of Cu-15Ni-8Sn alloy are studied by means of TEM and the measurement of hardness. The results show that γ ' metastable phase strengthens alloy because of its ordering structure.The ordering structure includes two types of DO22 and L12 ordering. Their strengthening for the alloy is much stronger than that of spinodal decomposition.

  9. Weldability of commercial Al-Cu-Li alloys

    Energy Technology Data Exchange (ETDEWEB)

    Lippold, J.C. [Ohio State Univ., Columbus (United States); Lin, W. [Edison Welding Inst., Columbus, OH (United States)

    1996-12-31

    A new methodology for assessing weld solidification cracking using the Varestraint test was utilized to evaluate the susceptibility of Al-Cu-Li alloys 2090, 2094, and 2195. These alloys were found to be more susceptible to cracking than Li-free alloys 2014 and 2219. A new index, the solidification cracking temperature range, is used to quantify this susceptibility. The effect of solidification behavior and eutectic liquid film formation on crack behavior is described. (orig.)

  10. ELECTROCHEMICAL STUDIES OF MOBILE CHARGED SPECIES DURING ZIRCONIUM ALLOY OXIDATION

    OpenAIRE

    Smith, James Stephen

    2013-01-01

    This research has used a suite of electrochemical techniques, both in-situ and ex-situ to investigate the mobile charged species in the oxides of zirconium alloys. Limits on the corrosion resistance of existing zirconium alloys used for fuel cladding are a major restriction on the burn-up that can be achieved within a pressurised water reactor (PWR). Developing a full mechanistic understanding of the corrosion process of zirconium alloys in the primary water environment is necessary for prolo...

  11. Study of plasma sprayed copper alloy using positron annihilation

    International Nuclear Information System (INIS)

    A positron annihilation technique has been employed to study the microdefects of copper alloy sprayed on a steel substrate by plasma after being compressed in different thickness. The positron lifetime in the alloy is varied with different amount of compression. It is found that the positron lifetime decreases with increasing of the compression deformation. On the contrary, the positron lifetime is increased for normal alloy after deformation

  12. Recent research and development in titanium alloys for biomedical applications and healthcare goods

    OpenAIRE

    Mitsuo Niinomi

    2003-01-01

    Nb, Ta and Zr are the favorable non-toxic alloying elements for titanium alloys for biomedical applications. Low rigidity titanium alloys composed of non-toxic elements are getting much attention. The advantage of low rigidity titanium alloy for the healing of bone fracture and the remodeling of bone is successfully proved by fracture model made in tibia of rabbit. Ni-free super elastic and shape memory titanium alloys for biomedical applications are energetically developed. Titanium alloys f...

  13. Microstructure and properties of PbCa grade alloys for starting battery grids

    OpenAIRE

    Wesołowski, J.; S. Malara; L. Ciura; W. Kazana

    2016-01-01

    The paper presents results of the studies into microstructure and mechanical properties of PbCa grade alloys for starting battery grids. Three lead-calcium alloys with alloy additions of aluminium, tin, silver and magnesium were studied. Lead alloys were produced in laboratory tests from industrial master alloys and pure elements. The examined alloys have monophase microstructure of tin solid solution in the lead. The range between liquidus and solidus temperatures is c.a. 10 °C. The mechanic...

  14. Atomic engineering of platinum alloy surfaces.

    Science.gov (United States)

    Li, Tong; Bagot, P A J; Marquis, E A; Edman Tsang, S C; Smith, G D W

    2013-09-01

    A major practical challenge in heterogeneous catalysis is to minimize the loading of expensive platinum group metals (PGMs) without degrading the overall catalytic efficiency. Gaining a thorough atomic-scale understanding of the chemical/structural changes occurring during catalyst manufacture/operation could potentially enable the design and production of "nano-engineered" catalysts, optimized for cost, stability and performance. In the present study, the oxidation behavior of a Pt-31 at% Pd alloy between 673-1073 K is investigated using atom probe tomography (APT). Over this range of temperatures, three markedly different chemical structures are observed near the surface of the alloy. At 673 K, the surface oxide formed is enriched with Pd, the concentration of which rises further following oxidation at 773 K. During oxidation at 873 K, a thick, stable oxide layer is formed on the surface with a stoichiometry of PdO, beneath which a Pd-depleted (Pt-rich) layer exists. Above 873 K, the surface composition switches to enrichment in Pt, with the Pt content increasing further with increasing oxidation temperature. This treatment suggests a route for tuning the surfaces of Pt-Pd nanoparticles to be either Pd-rich or Pt-rich, simply by adjusting the oxidation temperatures in order to form two different types of core-shell structures. In addition, comparison of the oxidation behavior of Pt-Pd with Pt-Rh and Pd-Rh alloys demonstrates markedly different trends under the same conditions for these three binary alloys. PMID:23276526

  15. Torsional Stability of Aluminum Alloy Seamless Tubing

    Science.gov (United States)

    Moore, R L; Paul, D A

    1939-01-01

    Torsion tests were made on 51ST aluminum-alloy seamless tubes having diameter-to-thickness ratios of from 77 to 139 and length-to-diameter ratios of from 1 to 60. The torsional strengths developed in the tubes which failed elastically (all tubes having lengths greater than 2 to 6 times the diameter) were in most cases within 10 percent of the value indicated by the theories of Donnel, Timoshenko, and Sturm, assuming a condition of simply supported ends.

  16. Traps in Zirconium Alloys Oxide Layers

    Directory of Open Access Journals (Sweden)

    Helmar Frank

    2005-01-01

    Full Text Available Oxide films long-time grown on tubes of three types of zirconium alloys in water and in steam were investigated, by analysing I-V characteristic measured at constant voltages with various temperatures. Using theoretical concepts of Rose [3] and Gould [5], ZryNbSn(Fe proved to have an exponential distribution of trapping centers below the conduction band edge, wheras Zr1Nb and IMP Zry-4 proved to have single energy trap levels.

  17. FSW characterization of 6082 aluminium alloys sheets

    OpenAIRE

    K. Mroczka; A. Pietras

    2009-01-01

    Purpose: The purpose of the investigations was to elaborate a set of FSW parameters for connecting 6082 aluminium alloy sheets allowing to produce welds of highest strength.Design/methodology/approach: The FSW was tried at different speeds and at additional cooling. The welds microstructure was studied using optical and scanning electron microscopes. The mechanical properties of produced connections are discussed regarding their tensile test and microhardness measurements.Findings: The FSW we...

  18. High Copper Amalgam Alloys in Dentistry

    OpenAIRE

    Gaurav Solanki

    2012-01-01

    Amalgam Restoration is an example of the material giving its name to the process. Amalgam fillings are made up of mercury, powdered silver and tin. They are mixed and packed into cavities in teeth where it hardens slowly and replaces the missing tooth substance. The high copper have become material of choice as compared to low copper alloys nowadays because of their improved mechanical properties, corrosion resistance, better marginal integrity and improved performance in clinical trial. The ...

  19. Discontinuous precipitation in copper base alloys

    Indian Academy of Sciences (India)

    K T Kashyap

    2009-08-01

    Discontinuous precipitation (DP) is associated with grain boundary migration in the wake of which alternate plates of the precipitate and the depleted matrix form. Some copper base alloys show DP while others do not. In this paper the misfit strain parameter, , has been calculated and predicted that if 100 > ± 0.1, DP is observed. This criterion points to diffusional coherency strain theory to be the operative mechanism for DP.

  20. Anisotropic Transport Properties of Complex Metallic Alloys

    OpenAIRE

    Smontara, Ana; Dolinšek, Janez

    2010-01-01

    Anisotropic transport properties (electrical resistivity, ρ, and thermal conductivity, κ) of the Y-phase Al-Ni-Co, o-Al13Co4 and Al4(Cr,Fe) complex metallic alloys were investigated. They belong to the class of decagonal approximant phases with stacked-layer crystallographic structure and allowed us to study the evolution of anisotropic transport properties with increasing structural complexity and the unit cell size.

  1. Deuterium transport and trapping in aluminum alloys

    International Nuclear Information System (INIS)

    A simple model of diffusion and evolution of the density of deuterium in metals is presented. A model of the deuterium evolution in the presence of uniform and nonuniform distributions of traps, as well as perfectly reflecting and partially permeable boundary conditions is discussed. Computers are compared with experimental results describe deuterium distribution after fatigue crack growth of 2219 and 7075 aluminum alloys in a D2O water vapor environment and after ion implantation

  2. A NEW MODEL OF SHAPE MEMORY ALLOYS

    Institute of Scientific and Technical Information of China (English)

    朱祎国; 吕和祥; 杨大智

    2002-01-01

    A new constitutive model of shape memory alloys ( SMAs ) based on Tanaka' s martensite fraction exponential expression is produced. This new model can present recoverable shape memory strain during different phase transformation, and reflect the action of martensite reorientation. Also it can overcome the defect of Tanaka's Model when the SMAs' microstructure is fully martensite . The model is very simple and suitable for using,and the correct behavior of the model is proved by test.

  3. Scanning probe microscopy on new dental alloys

    Science.gov (United States)

    Reusch, B.; Geis-Gerstorfer, J.; Ziegler, C.

    Surface analytical methods such as scanning force microscopy (SFM), scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS) were used to determine the surface properties of amalgam substitutes as tooth filling materials. In particular the corrosion and the passivation behavior of new gallium restorative materials were studied. To give relevant practical data, the measurements were performed with and without the alloys being stored in artificial saliva to simulate physiological oral conditions.

  4. A Novel Surface Treatment for Titanium Alloys

    Science.gov (United States)

    Lowther, S. E.; Park, C.; SaintClair, T. L.

    2004-01-01

    High-speed commercial aircraft require a surface treatment for titanium (Ti) alloy that is both environmentally safe and durable under the conditions of supersonic flight. A number of pretreatment procedures for Ti alloy requiring multi-stages have been developed to produce a stable surface. Among the stages are, degreasing, mechanical abrasion, chemical etching, and electrochemical anodizing. These treatments exhibit significant variations in their long-term stability, and the benefits of each step in these processes still remain unclear. In addition, chromium compounds are often used in many chemical treatments and these materials are detrimental to the environment. Recently, a chromium-free surface treatment for Ti alloy has been reported, though not designed for high temperature applications. In the present study, a simple surface treatment process developed at NASA/LaRC is reported, offering a high performance surface for a variety of applications. This novel surface treatment for Ti alloy is conventionally achieved by forming oxides on the surface with a two-step chemical process without mechanical abrasion. This acid-followed-by-base treatment was designed to be cost effective and relatively safe to use in a commercial application. In addition, it is chromium-free, and has been successfully used with a sol-gel coating to afford a strong adhesive bond after exposure to hot-wet environments. Phenylethynyl containing adhesives were used to evaluate this surface treatment with sol-gel solutions made of novel imide silanes developed at NASA/LaRC. Oxide layers developed by this process were controlled by immersion time and temperature and solution concentration. The morphology and chemical composition of the oxide layers were investigated using scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), and Auger electron spectroscopy (AES). Bond strengths made with this new treatment were evaluated using single lap shear tests.

  5. Laser processing of metals and alloys

    International Nuclear Information System (INIS)

    Laser, due to its high degree of coherence can produce powder density in the range of 103-1011 W/mm2. This high power density of the laser beam enables it to be utilized for many industrial applications, e.g. welding, cutting, drilling, surface treatment, etc. Laser processing of materials has many advantages, e.g. good quality product at high processing speed, least heat affected zone, minimum distortion, etc. In addition, the same laser system can be utilized for different applications, a very cost effective factor for any industry. Therefore laser has been adopted for processing of different materials for a wide range of applications and is now replacing conventional materials processing techniques on commercial merits with several economic and metallurgical advantages. Applications of laser to process materials of different thicknesses varying from 0.1 mm to 100 mm have demonstrat ed its capability as an important manufacturing tool for engineering industries. While lasers have most widely been utilized in welding, cutting and drilling they have also found applications in surface treatment of metals and alloys, e.g. transfor mation hardening and annealing. More recently, there has been significant amount of research being undertaken in laser glazing, laser surface alloying and laser cladding for obtaining improved surface properties. This report reviews the stat us of laser processing of metals and alloys emphasising its metallurgical aspects a nd deals with the different laser processes like welding, cutting, drilling and surface treatment highlighting the types and choice of laser and its interaction with metals and alloys and the applications of these processes. (author). 93 refs., 32 figs., 7 tables

  6. Quasistatic isothermal evolution of shape memory alloys

    OpenAIRE

    Frigeri, Sergio; Krejčí, Pavel; Stefanelli, Ulisse

    2011-01-01

    This paper focuses on a three-dimensional phenomenological model for the isothermal evolution of a polycrystalline shape memory alloy. The model, originally proposed by Auricchio, Taylor, and Lubliner in 1997, is thermodynamically consistent and reproduces the crucial martensitic reorientation effect as well as the tension-compression asymmetric behavior of the material. We prove the existence of a weak solution of the corresponding quasistatic evolution problem by passing to the limit within...

  7. Aluminum alloy nanosecond vs femtosecond laser marking

    Indian Academy of Sciences (India)

    S Rusu; A Buzaianu; D G Galusca; L Ionel; D Ursescu

    2013-11-01

    Based on the lack of consistent literature publications that analyse the effects of laser marking for traceability on various materials, the present paper proposes a study of the influence of such radiation processing on an aluminum alloy, a vastly used material base within several industry fields. For the novelty impact, femtolaser marking has been carried out, besides the standard commercial nanosecond engraving. All the marks have been analysed using profilometry, overhead and cross-section SEM microscopy, respectively and EDAX measurements.

  8. Powder metallurgy of turbine disc alloys

    Energy Technology Data Exchange (ETDEWEB)

    Ingesten, N.G. (Dep. of Engineering Metals)

    1981-03-01

    The first part embraced a study of carbide precipitated in IN 100 and astrology powders. The powder was heat treated at temperatures between 950/sup 0/C and 1150/sup 0/C. After aging at 950-1100/sup 0/C the MC-carbides formed during atomization were replaced by M/sub 23/C/sub 6/-carbides. After 1150/sup 0/C treatments the MC carbides were present again. Precipitation comparable with that obtained in HIP:ed specimens was not observed at free particle surfaces. However, powder particles which had agglomerated during atomization often exhibited considerable precipitation at contiguous surfaces. Obviously, contact between the particles must occur if coarse precipitation at particle surfaces is to develop. Reduced PPB-precipitation was obtained by pre-heat- treatment of powder before compaction. It is suggested that the carbon otherwise available for PPB-precipitation forms carbides in the interior of the powder particles. The aim of the second part was to ..gamma..-strengthen a Co-based super-alloy (Co-15Cr-3Mo-5Ti). Here the Ti-addition gives a coherent and ordered ..gamma..-phase Co/sub 3/Ti. However, upon ageing the alloy is unstable in order to increase the stability modifications of the alloy were prepared by: leaving out the Mo-content, adding 10 % Ni and by decreasing the Ti-content to 4.2 %. In addition, the effect of enhanced grain size and of deformation was investigated. Significant reduction of the transformation rate was only obtained by decresing the Ti-content while deformation of the alloy greatly increased the transformation rate.(author).

  9. Metalworking Techniques Unlock a Unique Alloy

    Science.gov (United States)

    2015-01-01

    Approached by West Hartford, Connecticut-based Abbot Ball Company, Glenn Research Center agreed to test an intriguing alloy called Nitinol 60 that had been largely unused for a half century. Using powdered metallurgy, the partners developed a method for manufacturing and working with the material, which Abbott Ball has now commercialized. Nitinol 60 provides a unique combination of qualities that make it an excellent material for ball bearings, among other applications.

  10. Local order dependent impurity levels in alloy semiconductors

    International Nuclear Information System (INIS)

    We develop a one band/may sites model for an isoelectronic impurity in a semiconductor alloy. The cluster-Bethe-lattice approximation is used to study the dependence of the impurity energy level upon the short range order (SRO) of the alloy. The Kikuchi parametrization is used to describe the latter. We take into account diagonal disorder only, with possible off-diagonal relaxation around the impurity site. All the inequivalent clusters of the impurity site and its first nearest neighbours are considered, thus including the important short range alloy potential fluctuations. Results are presented for the local density of impurity states, for different degrees of SRO in the alloy. (Author)

  11. Corrosion behavior of Ti–39Nb alloy for dentistry

    International Nuclear Information System (INIS)

    To increase an orthopedic implant's lifetime, researchers are now concerned on the development of new titanium alloys with suitable mechanical properties (low elastic modulus–high fatigue strength), corrosion resistance and good workability. Corrosion resistance of the newly developed titanium alloys should be comparable with that of pure titanium. The effect of medical preparations containing fluoride ions represents a specific problem related to the use of titanium based materials in dentistry. The aim of this study was to determine the corrosion behavior of β titanium alloy Ti–39Nb in physiological saline solution and in physiological solution containing fluoride ions. Corrosion behavior was studied using standard electrochemical techniques and X-ray photoelectron spectroscopy. It was found that corrosion properties of the studied alloy were comparable with the properties of titanium grade 2. The passive layer was based on the oxides of titanium and niobium in several oxidation states. Alloying with niobium, which was the important part of the alloy passive layer, resulted in no significant changes of corrosion behavior. In the presence of fluoride ions, the corrosion resistance was higher than the resistance of titanium. - Highlights: • Alloy Ti–39Nb shows excellent corrosion resistance in physiological solution. • Corrosion resistance of Ti–39Nb alloy is significantly higher than that of titanium in the presence of fluoride ions. • The electrochemical impedance spectroscopy indicates a porous passive layer. • Passive layer of the alloy is enriched by niobium

  12. ATOM PROBE STUDY OF TITANIUM BASE ALLOYS : PRELIMINARY RESULTS

    OpenAIRE

    Menand, A.; Chambreland, S.; Martin, C

    1986-01-01

    Two different titanium base alloys, Ti46 Al54 and Ti88.8 Cu2.3, Al8.9, have been studied by atom probe microanalysis. A precipitate of Ti2 Al was analysed in the binary alloys. Micro-analysis of Ti Cu Al alloy revealed the presence of Copper enriched zones. The study has also exhibited a penetration of Hydrogen in the samples, probably due to preparation technique. The results demonstrate the feasibility of studies on titanium base alloys by mean of atom probe.

  13. Novel Magnesium Alloys Developed for Biomedical Application: A Review

    Institute of Scientific and Technical Information of China (English)

    Nan Li; Yufeng Zheng

    2013-01-01

    There is an increasing interest in the development of magnesium alloys both for industrial and biomedical applications.Industrial interest in magnesium alloys is based on strong demand of weight reduction of transportation vehicles for better fuel efficiency,so higher strength,and better ductility and corrosion resistance are required.Nevertheless,biomedical magnesium alloys require appropriate mechanical properties,suitable degradation rate in physiological environment,and what is most important,biosafety to human body.Rather than simply apply commercial magnesium alloys to biomedical field,new alloys should be designed from the point of view of nutriology and toxicology.This article provides a review of state-of-the-art of magnesium alloy implants and devices for orthopedic,cardiovascular and tissue engineering applications.Advances in new alloy design,novel structure design and surface modification are overviewed.The factors that influence the corrosion behavior of magnesium alloys are discussed and the strategy in the future development of biomedical magnesium alloys is proposed.

  14. [Radioactivity of phosphorus implanted TiNi alloy].

    Science.gov (United States)

    Zhao, Xingke; Cai, Wei; Zhao, Liancheng

    2003-09-01

    Exposed to neutron flow, the phosphorus implanted TiNi alloy gets radioactive. This radioactive material is used in vascular stent for prevention and cure of restenosis. Phosphorus implantation is carried out in a plasma immerged ion implantation system, and the dose of phosphorus implantation is in the range of 2-10 x 10(17) cm-2. After ion implantation, the alloy is exposed to the slow neutron flow in a nuclear reactor, the dose of the slow neutron is 1.39-5.88 x 10(19) n/cm2. The radioactivity of the TiNi alloy was measured by liquid scintillation spectrometry and radio-chromic-film dosimetry. The result shows that whether the phosphorus is implanted or not, the TiNi alloy comes to be radioactive after exposure to neutron flow. Just after neutron irradiation, the radiation dose of phosphorus implanted TiNi alloy is about one hundred times higher than that of un-phosphorus implanted TiNi alloy. The radiation difference between phosphorus and un-phosphorus implanted alloy decreases as time elapses. Within three months after neutron irradiation, the average half-decay period of phosphorus implanted TiNi alloy is about 62 days. The radiation ray penetration of phosphorus implanted TiNi alloy is deeper than that of pure 32P; this is of benefit to making radiation uniformity between stent struts and reducing radiation grads beyond the edge of stent.

  15. Precipitate-Accommodated Plasma Nitriding for Aluminum Alloys

    Institute of Scientific and Technical Information of China (English)

    Patama Visittipitukul; Tatsuhiko Aizawa; Hideyuki Kuwahara

    2004-01-01

    Reliable surface treatment has been explored to improve the strength and wear resistance of aluminum alloy parts in automotives. Long duration time as well as long pre-sputtering time are required for plasma nitriding of aluminum or its alloys only with the thickness of a few micrometers. New plasma inner nitriding is proposed to realize the fast-rate nitriding of aluminum alloys. Al-6Cu alloy is employed as a targeting material in order to demonstrate the effectiveness of this plasma nitriding. Mechanism of fast-rate nitriding process is discussed with consideration of the role of Al2Cu precipitates.

  16. Microstructure of Cast Ni-Cr-Al-C Alloy

    Directory of Open Access Journals (Sweden)

    Cios G.

    2015-04-01

    Full Text Available Nickel based alloys, especially nickel based superalloys have gained the advantage over other alloys in the field of high temperature applications, and thus become irreplaceable at high temperature creep and aggressive corrosion environments, such as jet engines and steam turbines. However, the wear resistance of these alloys is insufficient at high temperatures. This work describes a microstructure of a new cast alloy. The microstructure consists of γ matrix strengthened by γ’ fine precipitates (dendrites improving the high temperature strength and of Chromium Cr7C3 primary carbides (in interdendritic eutectics which are designed to improve wear resistance as well as the high temperature strength.

  17. Precipitation hardening and hydrogen embrittlement of aluminum alloy AA7020

    Indian Academy of Sciences (India)

    Santosh Kumar; T K G Namboodhiri

    2011-04-01

    AA7020 Al–Mg–Zn, a medium strength aluminium alloy, is used in welded structures in military and aerospace applications. As it may be subjected to extremes of environmental exposures, including high pressure liquid hydrogen, it could suffer hydrogen embrittlement. Hydrogen susceptibility of alloy AA7020 was evaluated by slow strain-rate tensile testing, and delayed failure testing of hydrogen-charged specimens of air-cooled, duplexaged, and water-quenched duplex agedmaterials. The resistance to hydrogen embrittlement of the alloy was found to be in the order of air-cooled duplex aged alloy > as-received (T6 condition) > water quenched duplex aged material.

  18. Oxidation mechanisms for alloys in single-oxidant gases

    Energy Technology Data Exchange (ETDEWEB)

    Whittle, D.P.

    1981-03-01

    Scales formed on alloys invariably contain the alloy constituents in a ratio different from that in the alloy, owing to the differing thermodynamic tendencies of the alloy components to react with the oxidant and to differences in diffusion rates in scale and alloy phases. This complex interrelationship between transport rates and the thermodynamics of the alloy-oxidant system can be analyzed using multicomponent diffusion theory when transport-controlled growth of single or multi-layered scales occurs. In particular, the superimposition of the diffusion data on an isothermal section of the appropriate phase diagram indicates the likely morphologies of the reaction products, including the sequence of phases found in the scale, the occurrence of internal oxidation and the development of an irregular metal/scale interface. The scale morphologies on alloys are also time-dependent: there is an initial transient stage, a steady state period, and a final breakdown, the latter often related to mechanical influences such as scale adherence, spallation, thermal or mechanical stresses and void formation. Mechanical influences have a more devastating effect in alloy oxidation due to the changes in alloy surface composition during the steady state period.

  19. ANALYSIS OF DECREASE MACHINABILITY POSSIBLE CAUSES FOR CLAIMED ALLOY

    Directory of Open Access Journals (Sweden)

    Nataša Náprstková

    2016-09-01

    Full Text Available The Faculty of Production Technology and Management is often asked by companies with a request to solve a specific technical task. One of these tasks was the analysis of aluminum alloy worsened machinability when the rods from this alloy exhibited against assumption significantly worse (longer chips during machining. The alloy was complaint and, of course, it created economic damage. Obviously, the company was interested in the causes of this alloy behavior change that could possibly generate future complaints procedures to defend itself better, or to avoid mistakes in the production of the material. At the faculty analysis that could contribute to identifying the cause of the worsened machinability were done.

  20. Refining U-Zr-Nb alloys by remelting

    Energy Technology Data Exchange (ETDEWEB)

    Aguiar, B.M.; Kniess, C.T.; Riella, H.G., E-mail: bmaguiar@ipen.b [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil); Ferraz, W.B. [Centro de Desenvolvimento da Tecnologia Nuclear (CDTN/CNEN-MG), Belo Horizonte, MG (Brazil)

    2011-07-01

    The high density U-Zr-Nb and U-Nb uranium-based alloys can be employed as nuclear fuel in a PWR reactor due to their high density and nuclear properties. These alloys can stabilize the gamma phase, however, according to TTT diagrams, at the working temperature of a PWR reactor, all gamma phase transforms to {alpha}'' phase in a few hours. To avoid this kind of transformation during the nuclear reactor operation, the U-Zr-Nb alloy and U-Nn are used in {alpha}'' phase. The stability of {alpha}'' phase depends on the alloy composition and cooling rate. The alloy homogenization has to be very effective to eliminate precipitates rich in Zr and Nb to avoid changes in the alloying elements contents in the matrix. The homogenization was obtained by remelting the alloy and keeping it in the liquid state for enough time to promote floating of the precipitates (usually carbides, less dense) and leaving the matrix free of precipitates. However, this floating by density difference may result in segregation between the alloying elements (Nb and Zr, at the top) and uranium (at the bottom). The homogenized alloys were characterized in terms of metallographic techniques, optical microscopy, scanning electronic microscopy, EDS and X-ray diffraction. In this paper, it is shown that the contents of Zr and Nb at the bottom and at the top of the matrix are constant. (author)