WorldWideScience

Sample records for alloy steel transition

  1. Alloyed steel

    International Nuclear Information System (INIS)

    The composition and properties are listed of alloyed steel for use in the manufacture of steam generators, collectors, spacers, emergency tanks, and other components of nuclear power plants. The steel consists of 0.08 to 0.11% w.w. C, 0.6 to 1.4% w.w. Mn, 0.35 to 0.6% w.w. Mo, 0.02 to 0.07% w.w. Al, 0.17 to 0.37% w.w. Si, 1.7 to 2.7% w.w. Ni, 0.03 to 0.07% w.w. V, 0.005 to 0.012% w.w. N, and the rest is Fe. The said steel showed a sufficiently low transition temperature between brittle and tough structures, a greater depth of hardenability, and better weldability than similar steels. (B.S.)

  2. Ductile-to-brittle transition in a low alloy steel

    International Nuclear Information System (INIS)

    The mechanical properties of pressure vessel steel (and above all its resistance to brittle fracture) are a decisive factor in the complex safety assessment of nuclear power plants. The monitoring of neutron induced embrittlement is provided using Charpy impact tests on standard V-notch specimens due to their small size. Material's ductile-to-brittle transition temperature (DBTT) can be easily characterised using this test. However, Charpy impact energy cannot be immediately used for safety assessment, since fracture toughness is required. Some empirical formulas have been developed, but no direct relationship was still found. When the specimens are tested in the ductile-to-brittle transition region, cleavage crack initiation is preceded by ductile crack growth giving a large scatter to the values of fracture toughness and/or Charpy impact energy. Even if the cleavage initiation and propagation in steels containing isolated spheroidic carbides are qualitatively well understood, no one from existing models can explain the sharp upturn in ductile-to-brittle transition region. In the present work, French tempered bainitic steel 16MND5 (considered as equivalent to the American standard A508 Cl.3) is studied: The large fractographic analysis of CT and Charpy specimens broken in the DBTT range is undertaken to account for the evolution of cleavage fracture mechanisms. In addition to classical scanning electron microscopy, transmission electron microscopy and EBSD technique are used in order to study the propagation of cleavage crack. The classical fracture mechanics using KIc or Jc concepts can hardly describe the unstable brittle fracture in the DBTT range. Hence, the local approach, which aims to predict the fracture of any structural component using local criteria, providing that the mechanical fields in the structure are known, is used. The probability of cleavage fracture in the DBTT range is predicted using the Beremin model based on weakest link theory, e.g. 2

  3. Combined effects of phosphorus segregation and partial intergranular fracture on the ductile-brittle transition temperature in structural alloy steels

    International Nuclear Information System (INIS)

    Research highlights: → Effective P segregation was proposed by segregated P and intergranular fracture. → The DBTT of aged and irradiated steel was analyzed by effective P segregation. → The DBTT of two classes of steels are controlled by differing mechanisms. → Hardening strongly influenced the embrittling potency of segregated P. - Abstract: This article introduced effective P segregation in terms of the product of the amount of segregated P and partial intergranular fracture to account for the combined effects on the ductile-brittle transition temperature (DBTT) measured by dynamic and static notched bar tests on several alloy steels. Effective P segregation characterized a DBTT shift caused by thermal ageing and/or neutron irradiation in various A533B and 2.25Cr-1Mo steels, while P segregation controlled the DBTT independent of the fraction of intergranular fracture in thermally aged 3.5Ni-1.7Cr steels with and without Mo and V. These DBTT behaviors of the two classes of steels are related to differing brittle fracture mechanisms. The present analysis enables one to investigate how the embrittling potency of segregated P in association with partial intergranular fracture is influenced by the differing plasticity and the addition of several alloying elements under dynamic and static loading conditions.

  4. Hybrid laser/arc welding of advanced high strength steel to aluminum alloy by using structural transition insert

    International Nuclear Information System (INIS)

    Highlights: • A concept welding procedure was presented for joining dissimilar alloys. • Controlling of temperature improved mechanical properties. • Microstructure analysis showed presence of tempered martensite. • Optimum stand-off distance caused stability of molten pool. - Abstract: The present investigation is related to the development of the welding procedure of the hybrid laser/arc welding (HLAW) in joining thick dissimilar materials. The HLAW was applied to join aluminum alloy (AA6061) to an advanced high strength steel (AHSS) where an explosively welded transition joint, TRICLAD®, was used as an intermediate structural insert between the thick plates of the aluminum alloy and AHSS. The welds were characterized by an optical microscope, scanning electron microscope (SEM), tensile test, charged coupled device (CCD) camera, and microhardness measurement. The groove angle was optimized for the welding process based on the allowed amount of heat input along the TRICLAD® interface generated by an explosive welding. The weld was fractured in the heat affected zone of the aluminum side in the tensile test. The microhardness was shown that the temperature variation caused minor softening in the heat affected zone satisfying the requirement that the width of the softened heat affected zone in the steel side falls within 15.9 mm far away from the weld centerline. The microstructure analysis showed the presence of tempered martensite at the vicinity of the weld area, which it was a cause of softening in the heat affected zone

  5. Analysis of fracture toughness in transition temperature region of a Mn-Mo-Ni low-alloy steel

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Sang Ho; Hwang, Byoung Chul; Lee, Sung Hak [Pohang Univ. of Science and Technology, Pohang (Korea, Republic of)

    2002-08-01

    This study is concerned with the analysis of fracture toughness in the transition region of a Mn-Mo-Ni low-alloy steel according to ASTM E1921 standard test method. Elastic-plastic cleavage fracture toughness, K{sub Jc} was determined by 3-point bend tests, using precracked Charpy V-notch (PCVN) specimens, and then the measured K{sub Jc} values were interpreted by the 3-parameter Weibull distribution with a theoretical slope of 4. fractographic observation indicated that the critical distance from a precrack tip to a cleavage initiation site linearly increased with increasing the critical J(J{sub c}) value, and that the stretch zone width had a good correlation with K{sub Jc} value, irrespective of testing temperature. Relationship between J{sub c} and critical distance, local fracture stress, and plane strain fracture toughness were discussed on the basis of the cleavage fracture behavior in the transition temperature region.

  6. Analysis of fracture toughness in the transition-temperature region of an Mn-Mo-Ni low-alloy steel

    Science.gov (United States)

    Kim, Sangho; Hwang, Byoungchul; Lee, Sunghak; Lee, Sunghak

    2003-06-01

    This study is concerned with the analysis of fracture toughness in the transition region of an Mn-Mo-Ni low-alloy steel, in accordance with the ASTM E1921 standard test method. Elastic-plastic cleavage fracture toughness ( K Jc ) was determined by three-point bend tests, using precracked Charpy V-notch (PCVN) specimens, and relationships between K Jc , the critical component of J ( J c ), critical distance ( X c ), stretch-zone width (SZW), local fracture stress, and plane-strain fracture toughness ( K Ic were discussed on the basis of the cleavage fracture behavior in the transition region. The master curve and the 95 pct confidence curves well explained the variation in the measured K Jc , and the Weibull slope measured on the Weibull plots was consistent with the theoretical slope of 4. Fractographic observation indicated that X c linearly increased with increasing J c , and that the SZW had a good correlation with K Jc , irrespective of the test temperature. In addition, the local fracture stress was independent of the test temperature, because the tempered bainitic steel used in this study showed a propagation-controlled cleavage fracture behavior.

  7. Effects of grain size on fracture toughness in transition temperature region of Mn-Mo-Ni low-alloy steels

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Sangho; Lee, Sunghak; Lee, Bong Sang

    2003-10-25

    An investigation was conducted into the effect of grain size on fracture toughness in the transition temperature region of Mn-Mo-Ni low-alloy steels used for nuclear pressure vessels. Three kinds of steels with different austenite grain sizes (AGS) were fabricated by varying the contents of Al and N, and their microstructures and mechanical properties were examined. Elastic-plastic cleavage fracture toughness, K{sub Jc}, was determined by three-point bend tests of precracked Charpy V-notch (PCVN) specimens according to ASTM E1921 standard test method. When the AGS decreased, the total number of carbides increased, while the size and the aspect ratio of carbides decreased. Local fracture stresses, estimated from a theoretical stress distribution in front of a crack tip, were found to be mainly determined by the 92nd% size of carbides. Cross-sectional areas beneath fracture surfaces were observed to understand microstructural features to affect the cleavage crack propagation behavior. The results showed that measured cleavage fracture units were smaller than AGSs, indicating that packet boundaries as well as austenite grain boundaries played an important role in the cleavage crack propagation. Based on the electron back-scatter diffraction (EBSD) results, the cleavage fracture units could also be matched with the effective grain sizes determined by the misorientation tolerance angle of 25 deg.

  8. Relationship between grain size and fracture toughness in transition region of Mn-Mo-Ni low-alloy steels

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Sang Ho; Lee, Sung Hak [Pohang Univ. of Science and Technology, Pohang (Korea, Republic of); Oh, Yong Jun [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2002-03-01

    The present study aims at interpreting the effect of grain size on fracture toughness in the transition region of Mn-Mo-Ni low-alloy steels. Three kinds of steels with different austenite grain sizes were fabricated, and their microstructures and mechanical properties were examined. Elastic-plastic cleavage fracture toughness, K{sub Jc}, was determined by 3-point bend tests of precracked Charpy V-notch (PCVN) specimens according to ASTM E1921 standard test method. When the austenite grain size decreased, the total number of carbides increased, while the size and the aspect ratio of carbides decreased. Local fracture stresses, estimated from a theoretical stress distribution in front of a crack tip, were found to be mainly determined by the 92%th size of carbides. Cross-sectional areas beneath fracture surfaces were observed to understand microstructural features to affect the cleavage crack propagation behavior. The results showed that measured cleavage fracture units were smaller than austenite grain sizes, indicating that packet boundaries as well as austenite grain boundaries played an important role in the cleavage crack propagation. Based on the electron back-scatter diffraction (EBSD) results, the cleavage fracture units could also be matched with the effective grain sizes determined by the misorientation tolerance angle of 25 degree.

  9. Characterization of transition behavior in SA508 Gr.4N Ni-Cr-Mo low alloy steels with microstructural alteration by Ni and Cr contents

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Ki-Hyoung; Park, Sang-gyu [Department of Materials Science and Engineering, KAIST, Daejeon 305-701 (Korea, Republic of); Nuclear Materials Research Division, KAERI, Daejeon 305-353 (Korea, Republic of); Kim, Min-Chul, E-mail: mckim@kaeri.re.kr [Nuclear Materials Research Division, KAERI, Daejeon 305-353 (Korea, Republic of); Lee, Bong-Sang [Nuclear Materials Research Division, KAERI, Daejeon 305-353 (Korea, Republic of); Wee, Dang-Moon [Department of Materials Science and Engineering, KAIST, Daejeon 305-701 (Korea, Republic of)

    2011-11-25

    Highlights: {yields} We offer information for determining optimum alloying contents of SA508 Gr.4N steel. {yields} This study shows improvement of toughness with increasing Ni and Cr contents. {yields} Ni content is more effective on the impact toughness than on the fracture toughness. {yields} Cr content is more effective on the fracture toughness. {yields} We offer detailed information on relationship between toughness and microstructure. - Abstract: SA508 Gr.4N Ni-Cr-Mo low alloy steel, in which Ni and Cr contents are higher than in commercial reactor pressure vessel (RPV) steels, may be a candidate RPV material with the improved strength and toughness due to its tempered martensitic microstructure. This study aims at assessing the effects of microstructural factors with alloying element contents on the transition properties of Ni-Cr-Mo low alloy steels. Model alloys with different Ni and Cr contents were fabricated and their Charpy impact toughness and fracture toughness were examined in the transition region according to ASTM E23 and E1921 standard procedures, respectively. The test results showed extensive improvements of both impact toughness and fracture toughness with increasing Ni and Cr contents. However, Ni content was more effective on the impact toughness than on the fracture toughness, while Cr content was more effective on the fracture toughness. In order to identify a difference in effects of alloying elements contents on the fracture toughness and impact toughness, the relations between the transition properties and the scale of the microstructural features such as packets and carbides are discussed in detail.

  10. The effects of the local fracture stress and carbides on the cleavage fracture characteristics of Mn-Mo-Ni low alloy steels in the transition region

    International Nuclear Information System (INIS)

    In the ductile-brittle transition temperature region of SA508 C1.3 Mn-Mo-Ni low alloy steels, the relationship of the local fracture stress and carbides influencing the cleavage fracture behavior was investigated. Based on the ASTM E1921-97 standard method, the reference transition temperatures were determined by three point bending fracture toughness tests. A local fracture stress σf*, was determined from a theoretical stress distribution in front of crack tip using the cleavage initiation distance measured in each fractured specimen surface. The local fracture stress values showed a strong relationship with toughness characteristics of the materials and those were larger in the materials of smaller carbide size. Quantitative analysis of carbides showed that carbides larger than a certain size are mainly responsible for the cleavage fracture in the ductile-brittle transition temperature region. (author)

  11. Effects of alloying elements on fracture toughness in the transition temperature region of base metals and simulated heat-affected zones of Mn-Mo-Ni low-alloy steels

    Science.gov (United States)

    Kim, Sangho; Im, Young-Roc; Lee, Sunghak; Lee, Hu-Chul; Kim, Sung-Joon; Hong, Jun Hwa

    2004-07-01

    This study is concerned with the effects of alloying elements on fracture toughness in the transition temperature region of base metals and heat-affected zones (HAZs) of Mn-Mo-Ni low-alloy steels. Three kinds of steels whose compositions were varied from the composition specification of SA 508 steel (grade 3) were fabricated by vacuum-induction melting and heat treatment, and their fracture toughness was examined using an ASTM E1921 standard test method. In the steels that have decreased C and increased Mo and Ni content, the number of fine M2C carbides was greatly increased and the number of coarse M3C carbides was decreased, thereby leading to the simultaneous improvement of tensile properties and fracture toughness. Brittle martensite-austenite (M-A) constituents were also formed in these steels during cooling, but did not deteriorate fracture toughness because they were decomposed to ferrite and fine carbides after tempering. Their simulated HAZs also had sufficient impact toughness after postweld heat treatment. These findings indicated that the reduction in C content to inhibit the formation of coarse cementite and to improve toughness and the increase in Mo and Ni to prevent the reduction in hardenability and to precipitate fine M2C carbides were useful ways to improve simultaneously the tensile and fracture properties of the HAZs as well as the base metals.

  12. Dissimilar Welding of Titanium Alloys to Steels

    OpenAIRE

    Gao, Yefei; TSUMURA, Takuya; NAKATA, Kazuhiro

    2012-01-01

    This review summarizes the dissimilar welding of titanium alloys to steels over a period of ten recent years, involving the welding processes which are used for the dissimilar welding of titanium alloys to steels, the mechanical properties of the joints and the discussion for the forming mechanism of the interface. Reducing the formation of brittle intermetallic compound (IMC) is a key requirement in the dissimilar welding of titanium alloys to steels, because the strength of the welding join...

  13. Comparison of Impact Properties for Carbon and Low Alloy Steels

    Institute of Scientific and Technical Information of China (English)

    O.H. Ibrahim

    2011-01-01

    The impact properties of hot rolled carbon steel (used for the manufacture of reinforcement steel bars) and the quenched & tempered (Q&T) low alloy steel (used in the pressure vessel industry) were determined. The microstructure of the hot rolled carbon steel contained ferrite/pearlite phases, while that of the quenched and tempered low alloy steel contained bainite structure. Impact properties were determined for both steels by instrumented impact testing at temperatures between -150 and 200℃. The impact properties comprised total impact energy, ductile to brittle transition temperature, crack initiation and propagation energy, brittleness transition temperature and cleavage fracture stress. The Q&T low alloy steel displayed much higher resistance to ductile fracture at high test temperatures, while its resistance to brittle fracture at low test temperatures was a little higher than that of the hot rolled carbon steel. The results were discussed in relation to the difference in the chemical composition and microstructure for the two steels.

  14. Cleanliness of Alloying Structural Steel

    Institute of Scientific and Technical Information of China (English)

    YU Hui-xiang; WANG Xin-hua; ZHANG Jing; LI Hai-bo; WANG Wan-jun

    2011-01-01

    Alloying structural steel used for mechanical structures has a high requirement for cleanliness because its failures are greatly affected by non-metallic inclusions and total oxygen content in steel.It has been reported by some steelmaking plants to have some problems in controlling total oxygen content and inclusions during alloying structural steel production.For this purpose,cleanliness control in 0.2C-0.3Si-0.6Mn-1Cr-0.2Mo steel was investigated.Firstly,low melting temperature zone(≤1873 K) of CaO-Al2O3-MgO system and formation condition of low melting temperature inclusions were investigated through thermodynamic equilibrium calculation.On this basis,industrial tests were carried out.Through sampling at different stages,transformation of oxide inclusions and change of total oxygen content in steel were studied.The results show that:in order to form CaO-Al2O3-MgO system inclusions with low melting temperature,mass percent of Al2O3,MgO and CaO in inclusions should be controlled from 37.6% to 70.8%,0 to 17.4% and 25.5% to 60.6%;For the condition of 1873 K and 0.05%(mass percent) dissolved aluminum in steel,the activities of dissolved oxygen,magnesium and calcium should be controlled as 0.298×10-4-2×10-4,0.1×10-5-40×10-5 and 0.8×10-8-180×10-8 respectively.With secondary refining proceeding,average total oxygen content and inclusion amount decrease,the type of most inclusions changes from Al2O3 after tapping to Al2O3-MgO after top slag is formed during ladle furnace refining and finally to CaO-Al2O3-MgO after RH treatment.In the final products,average total oxygen content was 12.7×10-6 and most inclusions were in spherical shape with size less than 5 μm.

  15. 46 CFR 59.20-1 - Carbon-steel or alloy-steel castings.

    Science.gov (United States)

    2010-10-01

    ... 46 Shipping 2 2010-10-01 2010-10-01 false Carbon-steel or alloy-steel castings. 59.20-1 Section 59... BOILERS, PRESSURE VESSELS AND APPURTENANCES Welding Repairs to Castings § 59.20-1 Carbon-steel or alloy-steel castings. Defects in carbon-steel or alloy-steel castings may be repaired by welding. The...

  16. High-strength, low-alloy steels.

    Science.gov (United States)

    Rashid, M S

    1980-05-23

    High-strength, low-alloy (HSLA) steels have nearly the same composition as plain carbon steels. However, they are up to twice as strong and their greater load-bearing capacity allows engineering use in lighter sections. Their high strength is derived from a combination of grain refinement; precipitation strengthening due to minor additions of vanadium, niobium, or titanium; and modifications of manufacturing processes, such as controlled rolling and controlled cooling of otherwise essentially plain carbon steel. HSLA steels are less formable than lower strength steels, but dualphase steels, which evolved from HSLA steels, have ferrite-martensite microstructures and better formability than HSLA steels of similar strength. This improved formability has substantially increased the utilization potential of high-strength steels in the manufacture of complex components. This article reviews the development of HSLA and dual-phase steels and discusses the effects of variations in microstructure and chemistry on their mechanical properties. PMID:17772810

  17. Simulations of local mechanical fields. Application to the ductile/brittle transition in low alloy steels; Simulations des champs mecaniques locaux. Applications a la transition ductile / fragile dans les aciers faiblement allies

    Energy Technology Data Exchange (ETDEWEB)

    Libert, M.; Rey, C. [Ecole Centrale de Paris, Lab. MSSMat, 92 - Chatenay Malabry (France); Libert, M.; Marini, B. [CEA Saclay, Dept. des Materiaux pour le Nucleaire (DEN/SAC/DMN/SRMA), 91 - Gif sur Yvette (France)

    2006-07-01

    The objective of this study is to take into account the effect of plasticity mechanisms on the ductile/brittle transition in low alloy steels of PWR reactor vessels. A crystalline plasticity model, describing the effect of temperature on the behaviour, has been implemented in a large transformation frame. The material parameters of the model have been determined experimentally and from mechanical tests using an inverse method. Simulations of polycrystalline aggregates have been performed with imposed triaxiality. The study of local heterogeneities shows that the distribution of main stress can be modeled using a distribution of extreme values of first species (Gumbel) and that the parameters of this distribution can be simply described as a function of {sigma}{sub mises} (the average equivalent stress) and T (temperature). This approach will allow to introduce the effect of these heterogeneities in a local approach criterion of rupture. (J.S.)

  18. Development of High Strength Low Alloy Steel for Nuclear Reactor Vessel

    International Nuclear Information System (INIS)

    SA508 Gr. 4N Ni-Cr-Mo low alloy steel has an improved strength and fracture toughness, compared to commercial low alloy steels such as SA508 Gr. 3 Mn-Mo-Ni low alloy steel. In this study, the microstructural observation and baseline test were carried out using SA508 Gr. 4N model alloy of 1 ton scale. Thermal embrittlement and neutron irradiation embrittlement behaviors of SA508 Gr. 4N model alloy were also evaluated. The yield strength of 540MPa, Charpy transition temperature, T41J of -132 .deg. C, Reference temperature, T0 of -146 .deg. C, and RTNDT of -105 .deg. C were obtained from large scale SA508 Gr. 3 low alloy steel. Effect of alloy elements on thermal embrittlement was carefully evaluated and embrittlement mechanism was characterized using small scale model alloys with various alloy composition. Neutron irradiation behavior at high fluence level up to 1.5x1020 n/cm2 corresponding over 80 years operation of RPV were investigated using irradiated samples from research reactor 'HANARO'. The irradiation embrittlement behavior of SA508 Gr. 4N model alloy was similar to that of commercial RPV steel. However, after neutron irradiation up to 1.3x1020 n/cm2, SA508 Gr. 4N model alloy shows lower transition temperature(T41J = -63 .deg. C) than unirradiated commercial RPV steel because it has a superior initial toughness

  19. Compensative alloying of Cr-Si low-alloyed steels

    International Nuclear Information System (INIS)

    The principle of choosing alloy elements in order to suppress the embrittlement of solid solution strengthening is proposed. In the case of Cr-Si low-alloyed steels, the effects of compensative alloying are studied. The ultimate tensile strength and impact toughness of Cr-Si steels microalloyed with Mo, V, and Ti are determined to prove the aspects. The structure of these steels is studied using optical and transmission electron microscopy techniques after applying the optimum heat treatment. The kinetics of phase transformation after quenching and tempering have been examined by means of measurements of specific electrical resistance and magnetic parameters. It is shown that at the Si-content of about 1 wt% high values of tensile strength and impact toughness are simultaneously obtained. It is established by calculations that, for the indicated steel, long-range distortions of the crystal lattice become close to zero at the Si-content of about 1 wt%.

  20. Fracture toughness of irradiated stainless steel alloys

    International Nuclear Information System (INIS)

    The postirradiation fracture toughness responses of Types 316 and 304 stainless steel (SS) wrought products, cast CF8 SS and Type 308 SS weld deposit were characterized at 4270C using J/sub R/-curve techniques. Fast-neutron irradiation of these alloys caused an order of magnitude reduction in J/sub c/ and two orders of magnitude reduction in tearing modulus at neutron exposures above 10 dpa, where radiation-induced losses in toughness appeared to saturate. Saturation J/sub c/ values for the wrought materials ranged from 28 to 31 kJ/m2; the weld exhibited a saturation level of 11 kJ/m2. Maximum allowable flaw sizes for highly irradiated stainless steel components stressed to 90% of the unirradiated yield strength are on the order of 3 cm for the wrought material and 1 cm for the weld. Electron fractographic examination revealed that irradiation displacement damage brought about a transition from ductile microvoid coalescence to channel fracture, associated with local separation along planar deformation bands. The lower saturation toughness value for the weld relative to that for the wrought products was attributed to local failure of ferrite particles ahead of the advancing crack which prematurely initiated channel fracture

  1. Machining of high alloy steels and heat resistant alloys

    International Nuclear Information System (INIS)

    The peculiarities of machining high alloy steels and heat resistant alloys on the base of nickel by cutting are described. The factors worsening the machining of heat resistant materials, namely, the low heat conductivity, strong reverting and high wearing capability, are pointed out. The resign and materials of cutting instruments, providing for high quality machining of heat resistant steels and alloys, are considered. The necessity of regulating thermal processes during cutting with cutting fluids and other coolants (e.g. air with a negative temperature) is noted. The recommended modes of cutting are presented. The efficiency of the conveyer-type method for sawing products and forged intermediate articles is demonstrated by the example of 5KhNM steel

  2. Experience with ferrosilicoaluminum alloy during deoxidation of steel

    OpenAIRE

    Mekhtiyev, A.; Akhmetov, A.; V. Yudakova; Bulatbayev, F.

    2016-01-01

    The article describes the process of deoxidation quiet and low-alloyed steel alloy ferrosilicoaluminum complex in comparison the existing, and with steel deoxidation technology with conventional alloys - ferrosilicon and secondary aluminum. A comparative analysis of quality steel, non-metallic inclusions metallographic studies and studies of the mechanical properties of the resulting steel was done. On a large array of experimental steel proved cost-effectiveness and feasibility of ferrosilic...

  3. Optimization Selection of Overlaying Transition Layer Material of Low-alloy Casting Steel%某低合金铸钢堆焊过渡层材料的优化选择

    Institute of Scientific and Technical Information of China (English)

    毕欢; 周杰; 黄亮; 刘阳; 卢顺; 丁永峰

    2012-01-01

    选用3种过渡层材料RMD136、RMD535和RMD142进行过渡层组织和性能的对比和优化.结果表明,在低合金铸钢表面堆焊前两种材料,能有效避免脱碳层和增碳层出现以及熔合线附近大量碳化物的形成,减弱其开裂倾向,有利于保证组织和性能均匀过渡.过渡层RMD136和RMD535为低碳马氏体钢,低碳马氏体抗裂性好,硬度适中,延性好,能承受中度冲击;线胀系数较小,开裂和变形倾向较小,可作为高强度堆焊材料的过渡层材料;其中采用RMD136过渡层堆焊的力学性能最佳,实现了低合金铸钢、过渡层和覆层之间的高强度连接.%Using RMD136, RMD535 and RMD142 material as overlaying transition layer, the microstructure and properties of the layer was compared and optimized. The results show that overlaying RMD136 and RMD535 on low alloy cast steel surface can effectively avoid the formation of decarburized layer and carburized carbon layer and the fusion of a large number of carbides near the line, weaken its cracking tendency, ensuring the uniform microstructure and properties transition; transition layer RMD136 and RMD535 is low-carbon martensitic steel, which has better crack resistance, moderate hardness, ductility, can withstand moderate impact; the coefficient of linear expansion of the above two layers is small, and the tendency of crack and deformation is small, which can be used as the transition layer of the surfacing materials with high strength; the mechanical property of low alloy cast steel overlaying RMD136 transition layer is best, which can confirm the high strength connection among the low alloy cast alloy, the transition layer and cladding.

  4. Effect of thermal cycling on the alloy 800/2.25 Cr-1 Mo steel joint

    International Nuclear Information System (INIS)

    The critical part of the trimetallic transition joint (type 304 stainless steel/Alloy 800/2.25 Cr-1 Mo steel), the Alloy 800/2.25 Cr-1 Mo steel joint welded with Inconel 182, was subjected to thermal cycling between room temperature and 873 K. The thermal cycling test procedure used produces accelerated failures in transition joints similar to those observed in steam generators of operating power plants. On thermal cycling, precipitation at the weld/ferritic steel interface decreased on post-weld heat treatment. This precipitation increased with increased prior ageing and applied stress. The results of these tests indicated a considerable improvement in performance of the trimetallic transition joint compared to the direct (bimetallic) transition joint. (orig.)

  5. Crack stability analysis of low alloy steel primary coolant pipe

    Energy Technology Data Exchange (ETDEWEB)

    Tanaka, T.; Kameyama, M. [Kansai Electric Power Company, Osaka (Japan); Urabe, Y. [Mitsubishi Heavy Industries, Ltd., Takasago (Japan)] [and others

    1997-04-01

    At present, cast duplex stainless steel has been used for the primary coolant piping of PWRs in Japan and joints of dissimilar material have been applied for welding to reactor vessels and steam generators. For the primary coolant piping of the next APWR plants, application of low alloy steel that results in designing main loops with the same material is being studied. It means that there is no need to weld low alloy steel with stainless steel and that makes it possible to reduce the welding length. Attenuation of Ultra Sonic Wave Intensity is lower for low alloy steel than for stainless steel and they have advantageous inspection characteristics. In addition to that, the thermal expansion rate is smaller for low alloy steel than for stainless steel. In consideration of the above features of low alloy steel, the overall reliability of primary coolant piping is expected to be improved. Therefore, for the evaluation of crack stability of low alloy steel piping to be applied for primary loops, elastic-plastic future mechanics analysis was performed by means of a three-dimensioned FEM. The evaluation results for the low alloy steel pipings show that cracks will not grow into unstable fractures under maximum design load conditions, even when such a circumferential crack is assumed to be 6 times the size of the wall thickness.

  6. ``Global and local approaches of fracture in the ductile to brittle regime of a low alloy steel``; ``Approches globale et locale de la rupture dans le domaine de transition fragile-ductile d`un acier faiblement allie``

    Energy Technology Data Exchange (ETDEWEB)

    Renevey, S

    1998-12-31

    The study is a contribution to the prediction of flow fracture toughness of low alloy steel and to a better knowledge of fracture behavior in the ductile to brittle transition region. Experiments were performed on a nozzle cut-off from a pressurized water reactor vessel made of steels A508C13 type steel. Axisymmetrical notched specimens were tested to study the fracture onset in a volume element while pre-cracked specimens were used to investigate cleavage fracture after stable crack growth. Systematic observations of fracture surfaces showed manganese sulfide inclusions (MnS) at cleavage sites or in the vicinity. The experimental results were used for modelling by the local approach to fracture. In a volume element the fracture is described by an original probabilistic model. This model is based on volume fraction distributions of MnS inclusions gathered in clusters and on the assumption of a competition without interaction between ductile and cleavage fracture modes. This model was applied to pre-cracked specimens (CT specimens). It is able to describe the scatter in the toughness after a small stable crack growth if a temperature effect on the cleavage stress is assumed. So, the modelling is able to give a lower bound of fracture toughness as a function of temperature. (author) 100 refs.

  7. Stainless Steel to Titanium Bimetallic Transitions

    Energy Technology Data Exchange (ETDEWEB)

    Kaluzny, J. A. [Fermilab; Grimm, C. [Fermilab; Passarelli, D. [Fermilab

    2015-01-01

    In order to use stainless steel piping in an LCLS-II (Linac Coherent Light Source Upgrade) cryomodule, stainless steel to titanium bimetallic transitions are needed to connect the stainless steel piping to the titanium cavity helium vessel. Explosion bonded stainless steel to titanium transition pieces and bimetallic transition material samples have been tested. A sample transition tube was subjected to tests and x-ray examinations between tests. Samples of the bonded joint material were impact and tensile tested at room temperature as well as liquid helium temperature. The joint has been used successfully in horizontal tests of LCLS-II cavity helium vessels and is planned to be used in LCLS-II cryomodules. Results of material sample and transition tube tests will be presented.

  8. Amorphous Alloy Surpasses Steel and Titanium

    Science.gov (United States)

    2004-01-01

    In the same way that the inventions of steel in the 1800s and plastic in the 1900s sparked revolutions for industry, a new class of amorphous alloys is poised to redefine materials science as we know it in the 21st century. Welcome to the 3rd Revolution, otherwise known as the era of Liquidmetal(R) alloys, where metals behave similar to plastics but possess more than twice the strength of high performance titanium. Liquidmetal alloys were conceived in 1992, as a result of a project funded by the California Institute of Technology (CalTech), NASA, and the U.S. Department of Energy, to study the fundamentals of metallic alloys in an undercooled liquid state, for the development of new aerospace materials. Furthermore, NASA's Marshall Space Flight Center contributed to the development of the alloys by subjecting the materials to testing in its Electrostatic Levitator, a special instrument that is capable of suspending an object in midair so that researchers can heat and cool it in a containerless environment free from contaminants that could otherwise spoil the experiment.

  9. Niobium in steels and alloys

    International Nuclear Information System (INIS)

    Data are presented on the reserves and processing of niobium raw materials followed by brief review of the current status and long-range trends in the commercial usage of niobium and its compounds. A survey is made of the physical properties of niobium and its chemical reactions with elements of direct concern in the manufacture of ferroalloys, quality steels and other products. Niobium minerals and ores, along with common ore processing practices are described briefly. Attention is paid to Brazilian niobium ores, and to the Araxa deposit specifically. Some emphasis has been given to methods of processing lean niobium ores not easily amenable to simple concentration. A systematic review is presented of the techniques used in the production of niobium ferroalloys. (E.G.)

  10. Bimetallic layered castings alloy steel – carbon cast steel

    Directory of Open Access Journals (Sweden)

    T. Wróbel

    2011-01-01

    Full Text Available In paper is presented technology of bimetallic layered castings based on founding method of layer coating directly in cast processso-called method of mould cavity preparation. Prepared castings consist two fundamental parts i.e. bearing part and working part (layer. The bearing part of bimetallic layered casting is typical foundry material i.e. ferritic-pearlitic carbon cast steel, whereas working part (layer is plate of austenitic alloy steel sort X10CrNi 18-8. The ratio of thickness between bearing and working part is 8:1. The quality of the bimetallic layered castings was evaluated on the basis of ultrasonic NDT (non-destructive testing, structure and macro- and microhardness researches.

  11. Characterization of ductile-brittle transition behavior in Mn-Mo-Ni low alloy steels for reactor pressure vessel by small punch test

    Energy Technology Data Exchange (ETDEWEB)

    Kim, M. C.; Lee, B. S.; Park, S. D.; Kim, K. B

    2004-12-01

    Small Punch (SP) tests were performed to evaluate the ductile-brittle transition behavior of Reactor Pressure Vessel (RPV) steels produced by different manufacturing (refining) processes. The results were compared to the standard test results, such as the conventional Charpy impact tests, JIC test and the Master Curve fracture toughness tests in accordance with the ASTM standard E1921. The SP transition temperatures (TSP), which are determined by the middle of the upper SP energy, showed a good correlation with the Charpy index temperatures. And the critical fracture strength, {sigma}{sup *}{sub f(sp)} from small punch test were found to have a linear relationship to the values from the pre-cracked specimens({sigma}{sup *}{sub f(PCVN)}). From the observation of thickness changes according to displacement, Equivalent strain(Eq) could be obtained as a function of ball displacement. It is found that relation between specimen thickness and ball displacement is not dependent on material properties and it is expressed as a function of ball displacement, and then SP equivalent strain(Eq) have close relationship with the fracture toughness(J{sub IC})

  12. FORIDA Towers - Analysis of steel transition piece

    DEFF Research Database (Denmark)

    Jensen, Lars Rom; Dollerup, Niels; Damkilde, Lars

    This report is a detailed analysis of the transition piece connecting the hybrid wind turbine towers lower UHPFRC part with the top steel part. The analysis of the transition piece includes a validation of the Service Limit State (SLS), the Ultimate Limit State (ULS) and the Fatigue loads. The...

  13. Deoxidation Behavior of Alloys Bearing Barium in Molten Steel

    Institute of Scientific and Technical Information of China (English)

    LI Yang; JIANG Zhou-hua; JIANG Mao-fa; WANG Jun-wen; GU Wen-bing

    2003-01-01

    The deoxidation behaviors of alloys bearing barium in pipe steel were researched with MgO crucible under argon atmosphere in MoSi2 furnace at 1 873 K. The total oxygen contents of molten steel, the distribution, size and morphology of deoxidation products in the steel were surveyed. The metamorphic mechanism for deoxidation products of alloy bearing barium was also discussed. The results show that applying alloy bearing barium to the pipe steel, very low total oxygen contents can be obtained, and deoxidation products, which easily float up from molten steel, can be changed into globular shape and uniformly distributed in steel. The equilibrium time of total oxygen is about 25 min, and the terminal total oxygen contents range from 0.002 0 % to 0.002 2 % after treating with SiCa wire. The best deoxidizers are SiAlBaCa and SiAlBaCaSr.

  14. Low alloy steel versus ADI – differences and similarities

    Directory of Open Access Journals (Sweden)

    A. Krzyńska

    2009-01-01

    Full Text Available The results of comparison between the microstructure of selected bainitic low alloy steel and austempered ductile iron ADI are presented. The aim of the comparison was to find out differences and similarities existing in these iron carbon commercial alloys. In this paper our own results on ADI structure and literature data were used. It follows from discussion presented here that both microstructure and properties of ADI are very close that which are observed in low alloy carbon steel. Moreover, we suggest that there is no so doubt to treat ADI mechanical properties as steel containing nodular inclusions of graphite.

  15. 48 CFR 252.225-7030 - Restriction on Acquisition of Carbon, Alloy, and Armor Steel Plate.

    Science.gov (United States)

    2010-10-01

    ... of Carbon, Alloy, and Armor Steel Plate. 252.225-7030 Section 252.225-7030 Federal Acquisition... Acquisition of Carbon, Alloy, and Armor Steel Plate. As prescribed in 225.7011-3, use the following clause: Restriction on Acquisition of Carbon, Alloy, and Armor Steel Plate (DEC 2006) (a) Carbon, alloy, and...

  16. Cracking in electron beam welding of low alloy steels

    International Nuclear Information System (INIS)

    The study of the cracking in electron beam welding of low alloy steel plates (steel ASTM-A387 gr 22) of high thickness shows that the welding speed to be the essential parameter. A low speed improves the resistance to cracking. The low segregation obtained with this process minimizes the effect of impurities

  17. Comparative Structural Strength Research of Hardened Carbon Steel and Hot-Rolled Alloy Steel

    Science.gov (United States)

    Bogomolov, A. V.; Zhakupov, A. N.; Kanayev, A. T.; Sikach, I. A.; Tugumov, K. K.

    2016-08-01

    Experiments on quantitative evaluation of fatigue strength showed that St5ps and St5sp carbon steels with A400 strength class can be fully applied for erection of constructions and buildings having cyclical loads during operation. Study of corrosion resistance of hardened carbon steel in comparison with hot-rolled alloy steel consists in difference in structures and hence, difference in intensity of electric and chemical processes featuring presence of steel in concrete. Structure of St5sp steel with A400 strength class in surface area has significantly less corrosion rate than ferritic-perlitic structure of 35GS steel with A400 strength class.

  18. Influence of additional alloying with nitrogen on structure and properties of high chromium steel Kh17 after hot rolling

    International Nuclear Information System (INIS)

    A study was made into the structure and mechanical properties of steel Kh17 with 0.16% N after hot rolling under various conditions. It is shown that nitrogen alloying promotes steel transition into a two-phase state (α+γ) in heating above 850 deg C and affects mechanical properties of the steel in a hot rolled state. Impact strength is at its maximum in nitrogen containing steel kh17 if the rolling is in the temperature range of α-phase solid solution. Depending on the temperatures of hot rolling beginning and completion the distinctions in steel microstructure are investigated

  19. MODULATED STRUCTURES AND ORDERING STRUCTURES IN ALLOYING AUSTENITIC MANGANESE STEEL

    Institute of Scientific and Technical Information of China (English)

    L. He; Z.H. Jin; J.D. Lu

    2001-01-01

    The microstructure of Fe-10Mn-2Cr-1.5C alloy has been investigated with transmission electron microscopy and X-ray diffractometer. The superlattice diffraction spots and satellite reflection pattrens have been observed in the present alloy, which means the appearence of the ordering structure and modulated structure in the alloy. It is also proved by X-ray diffraction analysis that the austenite in the alloy is more stable than that in traditional austenitic manganese steel. On the basis of this investigation,it is suggested that the C-Mn ordering clusters exist in austenitic manganese steel and the chromium can strengthen this effect by linking the weaker C-Mn couples together,which may play an important role in work hardening of austenitic manganese steel.

  20. Performance of stainless steel treated by plasma niobium alloying

    International Nuclear Information System (INIS)

    Nb alloyed layer was prepared by plasma surface alloying technology on surface of stainless steel substrates. Microstructure morphology, depth profiling of the elemental composition and phase structure of the alloyed layer were analyzed. Corrosion performance of the Nb alloyed layer was investigated. The results show that the optimum parameters were: temperature, 1100 degree C; air pressure, 80 Pa, holding time 3 h, source voltage, 900-700 V; and cathode voltage, 600-450 V. The thickness of Nb alloyed layer was about 60 μm. The alloyed layer was mainly composed of NbC and Nb6C5, Cr2Nb and Fe2Nb. The surface Nb content was 50%, which decreased sharply in the first several microns of depths and then gradually in further depths. The Nb alloyed layer has improved resistance to intergranular corrosion and uniform corrosion. (authors)

  1. Structure and mechanical properties of the three-layer material based on a vanadium alloy and corrosion-resistant steel

    Science.gov (United States)

    Nikulin, S. A.; Rozhnov, A. B.; Nechaikina, T. A.; Rogachev, S. O.; Zavodchikov, S. Yu.; Khatkevich, V. M.

    2014-10-01

    The quality of three-layer pipes has been studied; they are manufactured by hot pressing of a three-layer assembly of tubular billets followed by forging and cold rolling. The operating core is made from a V-4Ti-4Cr alloy. The protective claddings are made from corrosion-resistant steels of two grades, 08Kh17T and 20Kh13. The results of investigation into the structure and microhardness of the junction zone of steel and the vanadium alloy, which includes a contact zone and a transition diffusion layer, are reported. The 08Kh17T steel is shown to be a preferred cladding material.

  2. REVIEW AND PROSPECT OF HIGH STRENGTH LOW ALLOY TRIP STEEL

    Institute of Scientific and Technical Information of China (English)

    L. Li; P. Wollants; Y.L. He; B.C. De Cooman; X.C. Wei; Z.Y. Xu

    2003-01-01

    Research status of high strength low alloy TRIP (transformation induced plasticity)steels for automobile structural parts is briefly described. Composition and microstructure factors especially the morphology, size and volume fraction of retained austenite,which largely influence the strength and ductility of the steel, are reviewed and discussed one after another. Modelling of the inter-critical annealing and martempering processes as well as the designing of the TRIP steel aided by commercial software are introduced. Some special aspects of the dynamic mechanical properties of TRIP steel are firstly reported.

  3. Laser surface alloying of aluminium-transition metal alloys

    Directory of Open Access Journals (Sweden)

    Almeida, A.

    1998-04-01

    Full Text Available Laser surface alloying has been used as a tool to produce hard and corrosion resistant Al-transition metal (TM alloys. Cr and Mo are particularly interesting alloying elements to produce stable highstrength alloys because they present low diffusion coefficients and solid solubility in Al. To produce Al-TM surface alloys a two-step laser process was developed: firstly, the material is alloyed using low scanning speed and secondly, the microstructure is modified by a refinement step. This process was used in the production of Al-Cr, Al-Mo and Al-Nb surface alloys by alloying Cr, Mo or Nb powder into an Al and 7175 Al alloy substrate using a CO2 laser. This paper presents a review of the work that has been developed at Instituto Superior Tecnico on laser alloying of Al-TM alloys, over the last years.

    En el presente trabajo se estudia la aleación superficial mediante láser de aluminio con metales de transición. El cromo y el molibdeno son particularmente interesantes porque producen aleaciones de alta resistencia y por el bajo coeficiente de difusión y solución sólida en aluminio. Para producir estas aleaciones se ha seguido un procedimiento desarrollado en dos partes. En primer lugar, el material se alea usando una baja velocidad de procesado y en segundo lugar la estructura se modifica mediante un refinamiento posterior. Este procedimiento se ha empleado en la producción de aleaciones Al-Cr, Al-Mo y Al-Nb mediante aleación con láser de CO2 de polvos de Cr, Mo o Nb en aluminio y la aleación 7175. Este trabajo es una revisión del desarrollado en el Instituto Superior Técnico de Lisboa en los últimos años.

  4. Potential of rapid heat treatment of titanium alloys and steels

    Energy Technology Data Exchange (ETDEWEB)

    Ivasishin, O.M.; Teliovich, R.V. [Institute of Metal Physics, Kiev (Ukraine)

    1999-05-15

    Rapid heat treatment (RHT) of titanium alloys and steels, which includes rapid heating into the single-phase field, {beta} and {gamma} of titanium alloys and steels, respectively, is reviewed. Heating rate is an important parameter that affects the mechanism and kinetics of phase and/or structural transformation. Refinement of grain structure, formation of micro-chemical inhomogeneity and substructure in the high temperature phase following RHT are addressed. Thermo-kinetic effects during rapid heating of material with an initial metastable (quenched or deformed) microstructure are discussed. The response of titanium alloys and steels to RHT is compared. The improvement in mechanical properties of both material system following RHT is also presented. (orig.) 48 refs.

  5. Effect of alloy elements on the anti-corrosion properties of low alloy steel

    Indian Academy of Sciences (India)

    Baorong Hou; Yantao Li; Yanxu Li; Jinglei Zhang

    2000-06-01

    Effect of alloy elements on corrosion of low alloy steel was studied under simulated offshore conditions. The results showed that the elements Cu, P, Mo, W, V had evident effect on corrosion resistance in the atmosphere zone; Cu, P, V, Mo in the splash zone and Cr, Al, Mo in the submerged zone.

  6. 76 FR 78882 - Carbon and Certain Alloy Steel Wire Rod From Mexico: Affirmative Preliminary Determination of...

    Science.gov (United States)

    2011-12-20

    ... Steel Plate From Canada, 66 FR 7617, 7618 (January 24, 2001)) (Canadian Plate), and accompanying Issued... this order is certain hot-rolled products of carbon steel and alloy steel, in coils, of approximately... International Trade Administration Carbon and Certain Alloy Steel Wire Rod From Mexico: Affirmative...

  7. Mechanical properties of low alloy high phosphorus weathering steel

    OpenAIRE

    Jena B.K.; Gupta N; Singh B; Ahoo G.S.

    2015-01-01

    Mechanical behaviour of two low alloy steels (G11 and G12) was studied with respect to different phosphorus contents. Tensile strength and yield strength increased while percentage elongation at fracture decreased on increasing phosphorus content. The SEM and light optical photomicrograph of low phosphorus steel (G11) revealed ferrite and pearlite microstructure. On increasing phosphorus content from 0.25 wt.% to 0.42 wt.%, the morphology of grain changed f...

  8. Feasibility of underwater friction stir welding of hardenable alloy steel

    OpenAIRE

    Overfield, Norman E.

    2010-01-01

    Approved for public release; distribution is unlimited The objective of this thesis is to determine whether friction stir welding (FSW) is a feasible welding process for steels in an underwater environment. Specific benefits would be underwater weld repairs on steel alloy piping systems and/or structures, and crack repairs on control surfaces of submarines without the need for strict environment controls or in the submarine's case, for drydocking. A single tool made of polycrystaline cub...

  9. X-ray photoelectron spectroscopy investigations of zinc-magnesium alloy coated steel

    International Nuclear Information System (INIS)

    The coating layer composition depth profiles and element chemical states of zinc-magnesium alloy coated steel were investigated by X-ray photoelectron spectroscopy depth profiling. Through the analysis of photoelectron signals and Auger signals of different elements on different depth planes of the coating layer, it can be found that the surface of the coating layer contains MgCO3, MgO, Mg(OH)2, metallic Mg, metallic Zn and some complex zinc compounds. Under the surface, there is a Zn2Mg alloy layer with the thickness of about 300 nm accompanied with MgO and Mg(OH)2 in the layer. There is a transitional layer with the thickness of about 200 nm between the Zn2Mg alloy layer and the pure Zn layer, whose components consist of zinc-magnesium alloy without fixed stoichiometry, a little MgO and a little Mg(OH)2.

  10. Ordering in binary transition metal alloys

    Energy Technology Data Exchange (ETDEWEB)

    Rusakov, G. [Institute for Metal Physics UB RAS, 18 Kovalevskoj St., 620990 Ekaterinburg (Russian Federation); Ural State Technical University - UPI, 19 Mira St., 620002 Ekaterinburg (Russian Federation); Son, L., E-mail: ldson@yandex.ru [Ural State Pedagogical University, 26 Cosmonavtov Ave, 620017 Ekaterinburg (Russian Federation); Efimova, E. [Institute for Metal Physics UB RAS, 18 Kovalevskoj St., 620990 Ekaterinburg (Russian Federation); Ural State Technical University - UPI, 19 Mira St., 620002 Ekaterinburg (Russian Federation); Dubinin, N. [Institute for Metallurgy UB RAS, 101 Amundsen St., 620016 Ekaterinburg (Russian Federation); Ural State Technical University - UPI, 19 Mira St., 620002 Ekaterinburg (Russian Federation)

    2012-03-20

    We present the phenomenological thermodynamic modeling of binary alloys which demonstrate solubility of the components at high temperatures, and form intermediate phase near equiatomic composition at lower ones (the so-called sigma-phase). Besides, the regular solution miscibility gap takes place also. The nonequilibrium thermodynamic potential is written out as a sum of the free energy of regular solution and polynomial term of scalar order parameter {phi}, which describes the {sigma}-phase ordering. There are four parameters in the model: the energy of regular solution mixing, the energy of {sigma}-phase formation at zero temperature, and the widths of temperature and concentration intervals of {sigma}-phase existence in the alloy with frozen-in random distribution of components. Up to now, both phase transitions which take place in a number of transition metals binary alloys (the {sigma}-phase formation and miscibility in the regular solution) have been treated separately. In present work, the standard technique of phase diagram calculation allows us to analyze all possible phase diagrams which may arise in the alloy.

  11. Method for plastic working of low-alloy steel

    International Nuclear Information System (INIS)

    To obtain fine-grained structure and to increase plasticity, the method of treating low-alloyed steel (0.1-0.3% C) is suggested. The method includes heating up to temperatures Ac1-Ac1+30 deg C, deformation with the degree of 50-70% and the rate 10-3-10-1 c-1, short-time hold-up up to 30 s at this temperature. The 15KhSND steel is taken for example. The use of this method will permit to obtain fine-grained structure in steels with the grain size up to 5 μm, in this case the plasticity of steel is 3-4 times higher than after treatment according to the known method, and the steel flow stress is 1.5-2 times lower

  12. High specialty stainless steels and nickel alloys for FGD dampers

    Energy Technology Data Exchange (ETDEWEB)

    Herda, W.R.; Rockel, M.B.; Grossmann, G.K. [Krupp VDM GmbH, Werdohl (Germany); Starke, K. [Mannesmann-Seiffert GmbH, Beckum (Germany)

    1997-08-01

    Because of process design and construction, FGD installations normally have bypass ducts, which necessitates use of dampers. Due to corrosion from acid dew resulting from interaction of hot acidic flue gases and colder outside environments, carbon steel cannot be used as construction material under these specific conditions. In the past, commercial stainless steels have suffered by pitting and crevice corrosion and occasionally failed by stress corrosion cracking. Only high alloy specialty super-austenitic stainless steels with 6.5% Mo should be used and considered for this application. Experience in Germany and Europe has shown that with regard to safety and life cycle cost analysis as well as providing a long time warranty, a new specialty stainless steel, alloy 31--UNS N08031--(31 Ni, 27 Cr, 6.5 Mo, 0.2 N) has proven to be the best and most economical choice. Hundreds of tons in forms of sheet, rod and bar, as well as strip (for damper seals) have been used and installed in many FGD installations throughout Europe. Under extremely corrosive conditions, the new advanced Ni-Cr-Mo alloy 59--UNS N06059--(59 Ni, 23 Cr, 16 Mo) should be used. This paper describes qualification and workability of these alloys as pertains to damper applications. Some case histories are also provided.

  13. New Stainless Steel Alloys for Low Temperature Surface Hardening?

    DEFF Research Database (Denmark)

    Christiansen, Thomas Lundin; Dahl, Kristian Vinter; Somers, Marcel A. J.

    2015-01-01

    The present contribution showcases the possibility for developing new surface hardenable stainless steels containing strong nitride/carbide forming elements (SNCFE). Nitriding of the commercial alloys, austenitic A286, and ferritic AISI 409 illustrates the beneficial effect of having SNCFE presen...

  14. Diffusion Bonding between TiAl Based Alloys and Steels

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    The joint of 40Cr steel and TiAl based alloy has been studied by means of a high frequency induction diffusion welder. The experimental results show that, the higher the temperature and pressure, the higher the strength of the joints. The optimum parameters are: T=1123~1323 K,t=10~30 min, P=5~20 MPa.

  15. Strengthening mechanism of steels treated by barium-bearing alloys

    Institute of Scientific and Technical Information of China (English)

    Zhouhua Jiang; Yang Liu

    2008-01-01

    The deoxidation, desulfurization, dephosphorization, microstructure, and mechanical properties of steels treated by barium-bearing alloys were investigated in laboratory and by industrial tests. The results show that barium takes part in the deoxidation reaction at the beginning of the experiments, generating oxide and sulfide compound inclusions, which easily float up from the molten steel, leading to the rapid reduction of total oxygen content to a very low level. The desulfurization and dephosphorization capabilities of calcium-bearing alloys increase with the addition of barium. The results of OM and SEM observations and mechanical property tests show that the structure of the steel treated by barium-bearing alloys is refined remarkably, the iamellar thickness of pearlitic structure decreases, and the pearlitic morphology shows clustering distribution. Less barium exists in steel substrate and the enrichment of barium-bearing precipitated phase mostly occurs in grain boundary and phase boundary, which can prevent the movement of grain boundary and dislocation during the heat treatment and the deformation processes. Therefore, the strength and toughness of barium-treated steels are improved by the effect of grain-boundary strengthening and nail-prick dislocation.

  16. Microstructures and properties of low-alloy fire resistant steel

    Indian Academy of Sciences (India)

    Bimal Kumar Panigrahi

    2006-02-01

    Microstructures and properties of weldable quality low-alloy fire resistant structural steels (YS: 287–415 MPa) and TMT rebar (YS: 624 MPa) have been investigated. The study showed that it is possible to obtain two-thirds of room temperature yield stress at 600°C with 0.20–0.25% Mo and 0.30–0.55% Cr in low carbon hot rolled structural steel. Microalloying the Cr–Mo steel by niobium or vanadium singly or in combination resulted in higher guaranteed elevated temperature yield stress (250–280 MPa). The final rolling temperature should be maintained above austenite recrystallization stop temperature (∼ 900° C) to minimize dislocation hardening. In a quenched and self-tempered 600 MPa class TMT reinforcement bar steel (YS: 624 MPa), low chromium (0.55%) addition produced the requisite yield stress at 600°C. The low-alloy fire resistant steel will have superior thermal conductivity up to 600°C (> 30 W/m.k) compared to more concentrated alloys.

  17. Phase transition ordering-separation: A new approach to heat treatment of alloys

    Science.gov (United States)

    Ustinovshchikov, Yu. I.

    2015-09-01

    The problems of the consequence of heat treatment of alloys performed using the concept of an ordering-separation phase transition are considered. Fe50Cr50 and Ni88Al12 alloys and U13 steel are used as examples to show that this transition occurs at a temperature specific for each system, and a change in the sign of the chemical interaction between alloy component atoms changes the direction of diffusion fluxes in alloys into the opposite direction, which changes the type of microstructure. The detection of this phase transition radically changes the generally accepted concepts of heat treatment of alloys. This finding calls for transmission electron microscopy investigations to modify the phase diagrams where this phase transition was detected. It is concluded that quenching of alloys from a so-called solid-solution field, which is usually performed before tempering (aging), is an unnecessary and useless operation, since the final structure of an alloy forms upon tempering (aging) irrespective of the structure existing before this heat treatment.

  18. Pressurized metallurgy for high performance special steels and alloys

    Science.gov (United States)

    Jiang, Z. H.; Zhu, H. C.; Li, H. B.; L1, Y.; Liu, F. B.

    2016-07-01

    The pressure is one of the basic parameters which greatly influences the metallurgical reaction process and solidification of steels and alloys. In this paper the history and present situation of research and application of pressurized metallurgy, especially pressurized metallurgy for special steels and alloys have been briefly reviewed. In the following part the physical chemistry of pressurized metallurgy is summarized. It is shown that pressurizing may change the conditions of chemical reaction in thermodynamics and kinetics due to the pressure effect on gas volume, solubility of gas and volatile element in metal melt, activity or activity coefficient of components, and change the physical and chemical properties of metal melt, heat transfer coefficient between mould and ingot, thus greatly influencing phase transformation during the solidification process and the solidification structure, such as increasing the solidification nucleation rate, reducing the critical nucleation radius, accelerating the solidification speed and significant macro/micro-structure refinement, and eliminating shrinkage, porosity and segregation and other casting defects. In the third part the research works of pressured metallurgy performed by the Northeastern University including establishment of pressurized induction melting (PIM) and pressurized electroslag remelting (PESR) equipments and development of high nitrogen steels under pressure are described in detail. Finally, it is considered in the paper that application of pressurized metallurgy in manufacture of high performance special steels and alloys is a relatively new research area, and its application prospects will be very broad and bright.

  19. Friction welding of Al–Mg–Si alloy to Ni–Cr–Mo low alloy steel

    OpenAIRE

    Fuji, A; 冨士, 明良

    2004-01-01

    It is difficult to weld the dissimilar material combination of aluminium alloys and low alloy steels using fusion welding processes, on account of the formation of a brittle interlayer composed of intermetallic compound phases and the significant difference in physical and mechanical properties. In the present work an attempt has been made to join these materials via the friction welding method, i.e. one of the solid phase joining processes. In particular, the present paper describes the opti...

  20. Virtual examinations of alloying elements influence on alloy structural steels mechanical properties

    OpenAIRE

    L.A. Dobrzański; R. Honysz

    2011-01-01

    Purpose: The paper introduces analysis results of selected alloying elements influence on mechanical properties of alloy structural steels for quenching and tempering.Design/methodology/approach: Investigations were performed in virtual environment with use of materials science virtual laboratory. Virtual investigations results were verified in real investigative laboratory.Findings: Materials researches performed with use of material science virtual laboratory in range of determining the mec...

  1. TEM study of mechanically alloyed ODS steel powder

    Energy Technology Data Exchange (ETDEWEB)

    Hoffmann, Jan, E-mail: j.hoffmann@kit.edu [Karlsruhe Institute of Technology (KIT), Institute for Applied Materials (IAM-AWP), Karlsruhe (Germany); Klimenkov, Michael; Lindau, Rainer; Rieth, Michael [Karlsruhe Institute of Technology (KIT), Institute for Applied Materials (IAM-AWP), Karlsruhe (Germany)

    2012-09-15

    Compared to present reactors, modern nuclear power plant concepts are based on materials which can be operated at higher temperatures and up to higher neutron doses. Oxide dispersion strengthened (ODS) steels - produced by mechanical alloying - with chromium contents of 9 and 14 wt.% (or even more) are typical candidate materials. As the preparation of TEM samples from milled powders is usually very difficult, a new approach has been successfully adopted coming from the TEM sample preparation of biological tissues. Here, the alloyed powder is first embedded and then cut into thin films of 60-90 nm thickness using a microtom. The focal point is to gain a better knowledge of the solution mechanism of Y{sub 2}O{sub 3} in the steel powder during mechanical alloying. Investigations on mechanically alloyed powders containing 13% Cr and Y{sub 2}O{sub 3} were made using a Tecnai Scanning Transmission Electron Microscope (STEM) with EDX detector. Detailed elemental mappings of the powder particles show the presence of Y{sub 2}O{sub 3} particles after different milling times. The non-dissolved Y{sub 2}O{sub 3} phase was detected on the surface of the mechanically alloyed powder particles in the specimen alloyed at times down to 24 h. After mechanically alloying of 80 h, no Y{sub 2}O{sub 3} phase has been detected. Inside the mechanically alloyed powder, no particles were detected. All further results of the elemental mappings after different milling times are analyzed, compared, and discussed in this paper.

  2. Oxidation behavior of steels and Alloy 800 in supercritical water

    International Nuclear Information System (INIS)

    The oxidation behavior of a ferritic-martensitic steel T91 and a martensitic steel AISI 403 up to 750 h, and of AISI 316L and Alloy 800 up to 336 h in deaerated supercritical water, 450ºC-25 MPa, was investigated in this paper. After exposure up to 750 h, the weight gain data, for steels T91 and AISI 403, was fitted by ∆W=k tn, were n are similar for both steels and k is a little higher for T91. The oxide films grown in the steels were characterized using gravimetry, scanning electron microscopy/energy dispersive X-ray spectroscopy (SEM/EDS) and X-ray diffraction. The films were adherent and exhibited a low porosity. For this low oxygen content supercritical water exposure, the oxide scale exhibited a typical duplex structure, in which the scale is composed of an outer iron oxide layer of magnetite (Fe3O4) and an inner iron/chromium oxide layer of a non-stoichiometric iron chromite (Fe,Cr)3O4. Preliminary results, with AISI 316L and Alloy 800, for two exposure periods (168 and 336 h), are also reported. The morphology shown for the oxide films grown on both materials up to 336 h of oxidation in supercritical water, resembles that of a duplex layer film like that shown by stainless steels and Alloy 800 oxide films grown in a in a high temperature and pressure (220-350ºC) of a primary or secondary coolant of a plant. (author)

  3. Current Status of Development of High Nickel Low Alloy Steels for Commercial Reactor Pressure Vessel

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Min Chul; Lee, B. S.; Park, S. G.; Lee, K. H. [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2008-12-15

    SA508 Gr.3 Mn-Mo-Ni low alloy steels have been used for nuclear reactor pressure vessel steels up to now. Currently, the design goal of nuclear power plant is focusing at larger capacity and longer lifetime. Requirements of much bigger pressure vessels may cause critical problems in the manufacturing stage as well as for the welding stage. Application of higher strength steel may be required to overcome the technical problems. It is known that a higher strength and fracture toughness of low alloy steels such as SA508 Gr.4N low alloy steel could be achieved by increasing the Ni and Cr contents. Therefore, SA508 Gr.4N low alloy steel is very attractive as eligible RPV steel for the next generation PWR systems. In this report, we propose the possibility of SA508 Gr.4N low alloy steel for an application of next generation commercial RPV, based on the literature research result about development history of the RPV steels and SA508 specification. In addition, we have surveyed the research result of HSLA(High Strength Low Alloy steel), which has similar chemical compositions with SA508 Gr.4N, to understand the problems and the way of improvement of SA508 Gr.4N low alloy steel. And also, we have investigated eastern RPV steel(WWER-1000), which has higher Ni contents compared to western RPV steel.

  4. Mechanical properties of low alloy high phosphorus weathering steel

    Directory of Open Access Journals (Sweden)

    Jena B.K.

    2015-01-01

    Full Text Available Mechanical behaviour of two low alloy steels (G11 and G12 was studied with respect to different phosphorus contents. Tensile strength and yield strength increased while percentage elongation at fracture decreased on increasing phosphorus content. The SEM and light optical photomicrograph of low phosphorus steel (G11 revealed ferrite and pearlite microstructure. On increasing phosphorus content from 0.25 wt.% to 0.42 wt.%, the morphology of grain changed from equiaxed shape to pan-cake shape and grain size also increased. The Charpy V notch (CVN impact energy of G11 and G12 steel at room temperature was 32 J and 4 J respectively and their fractographs revealed brittle rupture with cleavage facets for both the steels. However, the fractograph of G11 steel after tensile test exhibited ductile mode of fracture with conical equiaxed dimple while that of G12 steel containing 0.42 wt. % P exhibited transgranular cleavage fracture. Based on this study, G11 steel containing 0.25 wt. % P could be explored as a candidate material for weathering application purpose where the 20°C toughness requirement is 27 J as per CSN EN10025-2:2004 specification.

  5. Thermodynamic Modeling as a Strategy for Casting High Alloy Steels

    Institute of Scientific and Technical Information of China (English)

    Peri Reddy V; S Raman Sankaranarayanan

    2009-01-01

    Strategies based on thermodynamic calculations can be used to overcome the problems associated with oxides encountered in steel plant operations, which can lead to certain difficulties in the process such as clogging of submerged entry nozzle during continuous casting. Approaches to producing high alloy steels by continuous casting have been taken. One of the strategies to avoid the oxidation of chromium is to add a small amount of other elements (subject to other constraints), which do not cause subsequent problems. The problem has been studied using the Thermo-CalcR software, with related databases; and the results obtained for different process conditions or generic com-positions have been presented.

  6. Microbial corrosion of high alloy steels in natural sea water

    International Nuclear Information System (INIS)

    The paper deals with an investigation into regularities of settlement and potential impact of microbial forms on the corrosion of 12Kh18N10T stainless steel depending on its microstructure. It is shown that inhomogeneity of the morphorological composition and quantitative distribution of microorganisms on the surface of alloyed steels is caused by the selectivity of bacterial cells settlement on the substrate structural elements. The corrosion destruction at microscopic level primarily starts in the zones of microorganism concentration. 19 refs.; 3 figs.; 2 tabs

  7. Master alloy for manufacture of stainless and refractory steels and alloys

    International Nuclear Information System (INIS)

    The master alloy contains iron, 0.01 to 0.03% carbon, 0.1 to 2.0% manganese, 0.01 to 0.2% silicon, possibly impurities, such as traces of up to 0.015% sulphur, up to 0.01% phosphorus, 0.01%. nitrogen, 0.1% copper, up to 0.01% cobalt and traces of up to 0.05% arsenic, tin, lead, zinc or bismuth separate or in combination. The master alloy is used in the manufacture of steels and alloys for the chemical industry and for nuclear power. (B.S.)

  8. Description Of Alloy Layer Formation On A Cast Steel Substrate

    Directory of Open Access Journals (Sweden)

    Szajnar J.

    2015-09-01

    Full Text Available A description of alloy layer formation on a steel substrate is presented. Two types of formation are considered: diffusion of carbon and chromium into the solid from the pad in the direction of the cast steel within the FeCrC (grains and diffusion in a layer of liquid chromium cast iron formed in a preceding step. The influence of silicon in the pad on the pad’s transformation into the liquid is also examined. Solidus and liquidus temperatures of high carbon ferrochromium are determined. The larger the content of Si is used in the experiment, the lower the solidus temperature of the FeCrC alloy is observed. This results from the higher intensity of the elements’ diffusion and faster formation of the liquid.

  9. Manifestations of DSA in austenitic stainless steels and inconel alloys

    International Nuclear Information System (INIS)

    The aim of the investigation was to examine and compare different types of DSA (Dynamic Strain Aging) manifestations in AISI 316 austenitic stainless steel (SS) and Inconel 600 and Inconel 690 alloys by means of slow strain rate tensile testing, mechanical loss spectrometry (internal friction) and transmission electron microscopy (TEM). Another aim was to determine differences in the resulting dislocation structures and internal friction response of materials showing and not showing DSA behaviour

  10. Corrosion of low alloy steels in natural seawater. Influence of alloying elements and bacteria

    International Nuclear Information System (INIS)

    Metallic infrastructures immersed in natural seawater are exposed to important corrosion phenomena, sometimes characterised as microbiologically influenced corrosion. The presence of alloying elements in low alloy steels could present a corrosion resistance improvement of the structures. In this context, tests are performed with commercial steel grades, from 0,05 wt pc Cr to 11,5 wt pc Cr. They consist in 'on site' immersion in natural seawater on the one hand, and in laboratory tests with immersion in media enriched with marine sulphide-producing bacteria on the other hand. Gravimetric, microbiological, electrochemical measurements and corrosion product analyses are carried out and show that corrosion phenomenon is composed of several stages. A preliminary step is the reduction of the corrosion kinetics and is correlated with the presence of sessile sulphide-producing bacteria and an important formation of sulphur-containing species. This phase is shorter when the alloying element content of the steel increases. This phase is probably followed by an increase of corrosion, appearing clearly after an 8-month immersion in natural seawater for some of the grade steels. Chromium and molybdenum show at the same time a beneficial influence to generalised corrosion resistance and a toxic effect on sulphide-producing bacteria. This multidisciplinary study reflects the complexity of the interactions between bacteria and steels; sulphide-producing bacteria seem to be involved in corrosion processes in natural seawater and complementary studies would have to clarify occurring mechanisms. (author)

  11. Laser cladding of Ni-based alloy on stainless steel

    Institute of Scientific and Technical Information of China (English)

    XUE Chun-fang; TIAN Xin-li; TAN Yong-sheng; WU Zhi-yuan

    2004-01-01

    The coatings on a stainless steel substrate were conducted by laser cladding of Ni-based alloy, using a 5 kW continuous wave CO2 flow transverse laser. SEM, EDX and X-ray diffraction were used to analyze the microstructure and constituent phases of the obtained coatings by laser cladding with direct injection of the powder into the melt pool. Solidification planar, cellular and dendrite structures were observed in Ni-based alloy coating. There exists an optimum metallurgical bond between Ni-based laser cladding layer and the base material. The high hardness of the Ni-based alloy coating is attributed to the presence of M7C3-type carbides (essentially chromium-riched carbide) dispersed in the γ(Ni,Fe) phase matrix.

  12. Dual Phase Heat Treatment of Low-Alloy Steel

    Institute of Scientific and Technical Information of China (English)

    HAN Jian-min; CUI Shi-hai; LI Wei-jing; MA Xiao-yan

    2005-01-01

    Dual phase heat treatment is an economical and effective way for improving the properties of low carbon steels and low-alloy steel materials. In this paper, the microstructures and mechanical properties of 20MnSi steel treated by different dual phase heat treatment have been studied. The results show that dual phase heat treatment with pre-quenching technique and then heating from room temperature to the critical zone can achieve finer and more homogeneous microstructure than that with pre-normalizing technique and then cooling from austenite zone to the critical zone. Among all factors affecting dual phase heat treatment, quenching temperature at the critical zone and tempering temperature play an important part in mechanical properties. Using proper dual phase heat treatment technique with computer-optimized parameters, the yield strength, the elongation and impact toughness of 20MnSi can reach 860 MPa, 16% and 207 MPa respectively.

  13. Microstructural characterization of intercritically annealed low alloy PM steels

    Energy Technology Data Exchange (ETDEWEB)

    Gueral, A. [Materials Division, Technical Education Faculty, Metallurgy Education Department, Gazi University, 06500 Teknikokullar-Ankara (Turkey); Tekeli, S. [Materials Division, Technical Education Faculty, Metallurgy Education Department, Gazi University, 06500 Teknikokullar-Ankara (Turkey)]. E-mail: stekeli@gazi.edu.tr

    2007-07-01

    In this study, the applicability of intercritical annealing heat treatment, which is usually practiced to high strength low alloy ingot steels (HSLA), to low alloy powder metallurgy (PM) processed steels was investigated. With this heat treatment, it was intended to produce a dual-phase steel structure (ferrite + martensite) in PM steel. The effect of various amount of graphite addition on microstructure was also examined. For these purposes, atomized iron powder (Ancorsteel 1000) was mixed with 0.3 and 0.5 wt% graphite powder. The mixed powders were cold pressed at 700 MPa with single action and sintered at 1120 deg. C for 30 min under pure argon gas atmosphere. Some of the sintered specimens were directly annealed at intercritical heat treatment temperatures of 724, 735 and 760 deg. C and rapidly water quenched. Through these heat treatments, ferrite + martensite microstructure with coarse grain size were produced. The other sintered specimens were first austenitized at 890 deg. C for 12 min before intercritically annealing and then rapidly water quenched to produce fully martensitic structure. These specimens with fully martensitic microstructure were subsequently annealed at intercritical annealing temperatures of 724, 735 and 760 deg. C and rapidly water quenched. Ferrite + martensite microstructure with fine grain size was obtained by this route. The experimental results showed that martensite volume fraction increased with increasing intercritical annealing temperature as well as increasing graphite content. It is thought that mechanical properties of PM steels can be controlled by these heat treatments which are an alternative to traditional heat treatments of quenching + tempering applied usually to PM steels.

  14. High-strength low-alloy (HSLA) steels: Visokotrdna malolegirana (HSLA) konstrukcijska jekla:

    OpenAIRE

    Skobir Balantič, Danijela Anica

    2011-01-01

    Micro-alloyed, high-strength, low-alloy (HSLA) steels are important structural materials and contain small amounts of alloying elements, such as niobium, titanium, vanadium, and aluminium, which enhance the strength through the formation of stable carbides, nitrides or carbonitrides and have an effect on the hardenability. Such steels contain less than 0.1 % of the alloying additions, used individually or in combination. Yield strength increments of two or three times that of plain carbon-man...

  15. Surface Nb-ALLOYING on 0.4C-13Cr Stainless Steel: Microstructure and Tribological Behavior

    Science.gov (United States)

    Yu, Shengwang; You, Kai; Liu, Xiaozhen; Zhang, Yihui; Wang, Zhenxia; Liu, Xiaoping

    2016-02-01

    0.4C-13Cr stainless steel was alloyed with niobium using double glow plasma surface alloying and tribological properties of Nb-alloyed steel such as hardness, friction and wear were measured. Effects of the alloying temperature on microstructure and the tribological behavior of the alloyed steel were investigated compared with untreated steel. Formation mechanisms of Nb-alloyed layers and increased wear resistance were also studied. The result shows that after surface Nb-alloying treatment, the 0.4C-13Cr steel exhibits a diffusion adhesion at the alloyed layer/substrate interface and improved tribological property. The friction coefficient of Nb-alloyed steel is decreased by about 0.3-0.45 and the wear rate after Nb-alloying is only 2-5% of untreated steel.

  16. Plasma Nitriding of Low Alloy Sintered Steels

    Institute of Scientific and Technical Information of China (English)

    Shiva Mansoorzadeh; Fakhreddin Ashrafizadeh; Xiao-Ying Li; Tom Bell

    2004-01-01

    Fe-3Cr-0.5Mo-0.3C and Fe-3Cr-1.4Mn-0.5Mo-0.367C sintered alloys were plasma nitrided at different temperatures. Characterization was performed by microhardness measurement, optical microscopy, SEM and XRD. Both materials had similar nitriding case properties. 1.4% manganese did not change the as-sintered microstructure considerably.It was observed that monophase compound layer, γ, formed with increasing temperature. Compound layer thickness increased with increasing temperature while nitriding depth increased up to a level and then decreased. Core softening was more pronounced at higher temperature owing to cementite coarsening.

  17. Superplastic solid state welding steel and copper alloy based on laser quenching of steel surface

    Institute of Scientific and Technical Information of China (English)

    ZHANG Ke-ke; HAN Cai-xia; QUAN Shu-li; CHENG Guang-hui; YANG Jie; YANG Yun-lin

    2005-01-01

    Based on the feasibility of isothermal superplastic solid state welding of steel and copper alloy, the welded surface of steel surface was ultra-fined through laser quenching, and then the welding process tests between different base metals of 40Cr and QCr0.5 were made under the condition of non vacuum and non shield gas. The experimental results show that, with the sample surface of steel after laser quenching and that of copper alloy carefully cleaned, and under the pre-pressed stress of 56.6 -84.9 MPa, at the welding temperature of 750 -800 ℃ and at initial strain rate of (2.5 - 7.5) × 10-4 s-1 , the solid state welding can be finished in 120 - 180 s so that the strength of the joint is up to that of QCr0.5 base metal and the expansion rate of the joint does not exceed 6%. The plastic deformation of the joint was further analysed. The superplastic deformation of the copper alloy occurs in welding process and the deformation of steel are little.

  18. Experimental and Theoretical Investigations of Hot Isostatically Pressed-Produced Stainless Steel/High Alloy Tool Steel Compound Materials

    Science.gov (United States)

    Lindwall, Greta; Flyg, Jesper; Frisk, Karin; Sandberg, Odd

    2011-05-01

    Consolidation of tool steel powders and simultaneous joining to a stainless 316L steel are performed by hot isostatic pressing (HIP). Two tool steel grades are considered: a high vanadium alloyed carbon tool steel, and a high vanadium and chromium alloyed nitrogen tool steel. The boundary layer arising during diffusion bonding is in focus and, in particular, the diffusion of carbon and nitrogen over the joint. Measurements of the elemental concentration profiles and corrosion tests by the double loop-electrochemical potentiokinetic reactivation (DL-EPR) method are performed. Comparative calculations with the DICTRA software are performed and are found to be in agreement with the experimental results. It is found that the carbon tool steel grade has a more critical influence on the corrosion resistance of the stainless 316L steel in comparison to the nitrogen tool steel grade.

  19. Alloying Elements Transition Into the Weld Metal When Using an Inventor Power Source

    Science.gov (United States)

    Mamadaliev, R. A.; Kuskov, V. N.; Popova, A. A.; Valuev, D. V.

    2016-04-01

    The temperature distribution over the surface of the welded 12Kh18N10T steel plates using the inventor power source ARC-200 has been calculated. In order to imitate multipass welding when conducting the thermal analysis the initial temperature was changed from 298K up to 798K in 100K increments. It has been determined that alloying elements transition into the weld metal depends on temperature. Using an inventor power source facilitates a uniform distribution of alloying elements along the length and height of the weld seam.

  20. Development of Zn50 Brazing Alloy for Joining Mild Steel to Mild Steel (SAE1018

    Directory of Open Access Journals (Sweden)

    S.C. Nwigbo

    2014-09-01

    Full Text Available This work has developed new brazing alloys for joining mild steel to mild steel (SAE1018 at a lower temperature. The alloys blends and error analysis were done by experimental design software (Design Expert 8.0.7.1. Design of experiments was done by Scheffe quadratic mixture method. The liquidus temperatures were predicted by calculation of phase diagrams of the alloying metals. The brazing alloys were produced by gravity technique and melted using silicon carbide graphite crucible. The quality of the brazing alloys was analyzed by optical microscopy (OM, atomic absorption spectroscopy (AAS and fourier transform infrared spectroscopy (FT-IR. Brazed joints were produced by torch method with a commercial flux. Brazing temperatures (liquidus were tracked by a digital infrared/laser pyrometer. Some mechanical properties studied were tensile strength and hardness. Finally, brazed joints produced from the developed brazing alloys were compared to that produced from muntz brass. Six (6 brazing alloys were successfully developed. Zinc and manganese were the main components, to which were added; 3 to 4 %wt silver and 11 to15 %wt modifying element. The microstructure showed a typical eutectic structure with zinc-rich phase distributed uniformly in the matrix with a combination of different sizes of dendrite, rounded blocks of compounds and hypoeutectic structures. AAS results indicated minimal out-gassing of zinc and FT-IR results indicated very low presence of atmospheric gas. The range of brazing temperature for best results was recorded from 690.90 to 735.10 0C. The joints produced from the developed brazing alloys had acceptable strengths with improved stress-strain behaviour compared to muntz brass.

  1. Current Developments of Alloyed Steels for Hot Strip Roughing Mills : Characterization of High-Chromium Steel and Semi-High Speed Steel

    OpenAIRE

    LECOMTE-BECKERS, Jacqueline; Sinnaeve, Mario; Tchuindjang, Jérôme Tchoufack

    2012-01-01

    Two alloys grades for work rolls used in the roughing stand of Hot Strip Mill - high chromium steel (HCS) and semi-high-speed steel (semi-HSS), In this paper, the new semi-high-speed steel grade is studied

  2. Application of nitrogen alloyed steels for Indian Fast Reactor programme

    International Nuclear Information System (INIS)

    Towards building fast reactors for fulfilling energy requirements through second stage of nuclear power program planned by Department of Atomic Energy, a 500 MWe Prototype Fast Breeder Reactor (PFBR) is under advanced stage of construction at Kalpakkam, a coastal site. Nitrogen alloyed types 304LN and 316LN austenitic Stainless Steels have been selected for out of core components except for the steam generator primarily due to inclusion in the design codes favourable effect of nitrogen on mechanical strength and sensitization, and excellent weldability. For the once through steam generator design selected from economics and safety, modified 9Cr-1 Mo (Gr 91) has been selected from inclusion in the design codes, adequate mechanical strength, sound industrial experience and carbon transfer considerations. The presentation highlights the application of nitrogen alloyed types 304LN and 316LN SS, as well as modified 9Cr-1Mo steel for PFBR, and the influence of increased nitrogen alloying on mechanical properties on SS 316L for application to future fast reactors. (author)

  3. Mechanism of Bainite Nucleation in Steel, Iron and Copper Alloys

    Institute of Scientific and Technical Information of China (English)

    Mokuang KANG; Ming ZHU; Mingxing ZHANG

    2005-01-01

    During the incubation period of isothermal treatment(or aging) within the bainitic transformation temperature range in a salt bath (or quenching in water) immediately after solution treatment, not only are the defects formed at high temperatures maintained, but new defects can also be generated in alloys, iron alloys and steels. Due to the segregation of the solute atoms near defects through diffusion, this leads to non-uniform distributions of solute atoms in the parent phase with distinct regions of both solute enrichment and solute depletion. It is proposed that when the Ms temperature at the solute depleted regions is equal to or higher than the isothermal (or aged) temperature,nucleation of bainite occurs within these solute depleted regions in the manner of martensitic shear. Therefore it is considered that, at least in steel, iron and copper alloy systems, bainite is formed through a shear mechanism within solute depleted regions, which is controlled and formed by the solute atoms diffusion in the parent phase.

  4. Hot Forging of Nitrogen Alloyed Duplex Stainless Steels

    Institute of Scientific and Technical Information of China (English)

    P.Chandramohan; S.S. Mohamed Nazirudeen; S.S. Ramakrishnan

    2007-01-01

    Duplex stainless steels are gaining global importance because of the need for a high strength corrosion resistant material. Three compositions of this group were selected with three different nitrogen contents viz, 0.15 wt pct (alloy 1), 0.23 wt pct (alloy 2) and 0.32 wt pct (alloy 3). The steels were melted in a high frequency induction furnace and hot forged to various reductions from 16% to 62%. In this work, the effect of hot forging on the ferrite content, hardness, yield strength, impact strength and grain orientation (texture) were studied. Fracture analysis on all the forged specimens using SEM reveals that a size reduction of 48% results in maximum ductility and impact strength as well as minimal ferrite content and grain size. Thus the mechanical properties are found to have a direct correlation to ferrite content and grain size. The highest impact strength was observed in specimens with the smallest grain size, which was observed in specimens forged to 48% reduction in size.

  5. Tunable magnetocaloric effect in transition metal alloys

    Science.gov (United States)

    Belyea, Dustin D.; Lucas, M. S.; Michel, E.; Horwath, J.; Miller, Casey W.

    2015-10-01

    The unpredictability of geopolitical tensions and resulting supply chain and pricing instabilities make it imperative to explore rare earth free magnetic materials. As such, we have investigated fully transition metal based “high entropy alloys” in the context of the magnetocaloric effect. We find the NiFeCoCrPdx family exhibits a second order magnetic phase transition whose critical temperature is tunable from 100 K to well above room temperature. The system notably displays changes in the functionality of the magnetic entropy change depending on x, which leads to nearly 40% enhancement of the refrigerant capacity. A detailed statistical analysis of the universal scaling behavior provides direct evidence that heat treatment and Pd additions reduce the distribution of exchange energies in the system, leading to a more magnetically homogeneous alloy. The general implications of this work are that the parent NiFeCoCr compound can be tuned dramatically with FCC metal additives. Together with their relatively lower cost, their superior mechanical properties that aid manufacturability and their relative chemical inertness that aids product longevity, NiFeCoCr-based materials could ultimately lead to commercially viable magnetic refrigerants.

  6. 75 FR 69125 - Certain Seamless Carbon and Alloy Steel Standard, Line, and Pressure Pipe From China

    Science.gov (United States)

    2010-11-10

    ..., and by publishing the notice in the Federal Register on May 11, 2010 (75 FR 26273). The hearing was... COMMISSION Certain Seamless Carbon and Alloy Steel Standard, Line, and Pressure Pipe From China Determination... alloy steel standard, line, and pressure pipe (``seamless SLP pipe''), provided for in subheadings...

  7. Cyclic Partial Phase Transformations In Low Alloyed Steels: Modeling and Experiments

    NARCIS (Netherlands)

    Chen, H.

    2013-01-01

    Mechanical properties of low alloyed steels are directly determined by their microstructures. Thanks to versatility in their microstructures, the mechanical properties of low alloyed steels are much more adjustable than other materials. In the industry, one of the most effective ways to obtain the m

  8. 48 CFR 225.7011 - Restriction on carbon, alloy, and armor steel plate.

    Science.gov (United States)

    2010-10-01

    ... 48 Federal Acquisition Regulations System 3 2010-10-01 2010-10-01 false Restriction on carbon, alloy, and armor steel plate. 225.7011 Section 225.7011 Federal Acquisition Regulations System DEFENSE... on carbon, alloy, and armor steel plate....

  9. Compatibility of Austenitic Steel With Molten Lead-Bismuth-Tin Alloy

    Institute of Scientific and Technical Information of China (English)

    ZHANG Rui-qian; LI Yan; WANG Xiao-min

    2011-01-01

    The compatibility of the austenitic AISI 304 steel with Pb-Bi-Sn alloy was analyzed. The AISI 304 steels were immersed in stagnant molten Pb-33.3Bi-33. 3Sn alloy at 400, 500 and 600℃ for different exposure times (100-2 000 h) respectively. XRay diffractio

  10. 75 FR 21658 - Carbon and Certain Alloy Steel Wire Rod From Trinidad and Tobago

    Science.gov (United States)

    2010-04-26

    ... amended, 67 FR 68036 (Nov. 8, 2002). In accordance with sections 201.16(c) and 207.3 of the Commission's... COMMISSION Carbon and Certain Alloy Steel Wire Rod From Trinidad and Tobago AGENCY: United States... in the antidumping duty Investigation No. 731-TA-961 concerning carbon and certain alloy steel...

  11. 75 FR 22372 - Certain Seamless Carbon and Alloy Steel Standard, Line, and Pressure Pipe From the People's...

    Science.gov (United States)

    2010-04-28

    ... International Trade Administration Certain Seamless Carbon and Alloy Steel Standard, Line, and Pressure Pipe... determines that certain seamless carbon and alloy steel standard, line, and pressure pipe from the People's... imports of certain seamless carbon and alloy steel standard, line, and pressure pipe (``seamless...

  12. 75 FR 69050 - Certain Seamless Carbon and Alloy Steel Standard, Line, and Pressure Pipe From the People's...

    Science.gov (United States)

    2010-11-10

    ... International Trade Administration Certain Seamless Carbon and Alloy Steel Standard, Line, and Pressure Pipe... duty order on certain seamless carbon and alloy steel standard, line, and pressure pipe (``seamless... seamless pipe from the PRC. See Certain Seamless Carbon and Alloy Steel Standard, Line, and Pressure...

  13. The quality of the joint between alloy steel and unalloyed cast steel in bimetallic layered castings

    Directory of Open Access Journals (Sweden)

    T. Wróbel

    2012-01-01

    Full Text Available In paper is presented technology of bimetallic layered castings based on founding method of layer coating directly in cast process so-called method of mould cavity preparation. Prepared castings consist two fundamental parts i.e. bearing part and working part (layer. The bearing part of bimetallic layered casting is typical foundry material i.e. ferritic-pearlitic unalloyed cast steel, whereas working part (layer is plate of austenitic alloy steel sort X2CrNi 18-9. The ratio of thickness between bearing and working part is 8:1. The aim of paper was assessed the quality of the joint between bearing and working part in dependence of pouring temperature and carbon concentration in cast steel. The quality of the joint in bimetallic layered castings was evaluated on the basis of ultrasonic non-destructive testing, structure and microhardness researches.

  14. Alternative to Nitric Acid for Passivation of Stainless Steel Alloys

    Science.gov (United States)

    Lewis, Pattie L.; Kolody, Mark; Curran, Jerry

    2013-01-01

    Corrosion is an extensive problem that affects the Department of Defense (DoD) and National Aeronautics and Space Administration (NASA). The deleterious effects of corrosion result in steep costs, asset downtime affecting mission readiness, and safety risks to personnel. Consequently, it is vital to reduce corrosion costs and risks in a sustainable manner. The DoD and NASA have numerous structures and equipment that are fabricated from stainless steel. The standard practice for protection of stainless steel is a process called passivation. Typical passivation procedures call for the use of nitric acid; however, there are a number of environmental, worker safety, and operational issues associated with its use. Citric acid offers a variety of benefits including increased safety for personnel, reduced environmental impact, and reduced operational cost. DoD and NASA agreed to collaborate to validate citric acid as an acceptable passivating agent for stainless steel. This paper details our investigation of prior work developing the citric acid passivation process, development of the test plan, optimization of the process for specific stainless steel alloys, ongoing and planned testing to elucidate the process' resistance to corrosion in comparison to nitric acid, and preliminary results.

  15. Microstructure and properties of laser surface alloyed PM austenitic stainless steel

    OpenAIRE

    Z. Brytan; M. Bonek; L.A. Dobrzański

    2010-01-01

    Purpose: The purpose of this paper is to analyse the effect of laser surface alloying with chromium on the microstructural changes and properties of vacuum sintered austenitic stainless steel type AISI 316L (EN 1.4404).Design/methodology/approach: Surface modification of AISI 316L sintered austenitic stainless steel was carried out by laser surface alloying with chromium powder using high power diode laser (HPDL). The influence of laser alloying conditions, both laser beam power (between 0.7 ...

  16. LOCAL LASER ALLOYING OF STAINLESS STEEL 12H18N10T

    Directory of Open Access Journals (Sweden)

    Mr. Vladimir A. Kim

    2016-06-01

    Full Text Available The article presents the research of local laser alloying of stainless steel 12X18H10T. The steel resists quenching, but it is widely used in food, chemical, oil-processing and other industries. The alloying was carried out by graphite that provided carbon increase in steel and improvement of surface capacity. The article shows details of the structural transformations leading to surfaces hardening, and micro hardness spreading inside the modified layer.

  17. Controlling the ductile to brittle transition in Fe–9%Cr ODS steels

    International Nuclear Information System (INIS)

    Probably the most important range of materials for consideration as the blanket material for the tokamak design for fusion reactors ITER and DEMO is the high alloy Fe–9Cr oxide dispersion strengthened ferritic steels. Ferritic steels possess exceptional thermal conductivity and low thermal expansion and are resistant to void swelling. Their main drawback is high ductile to brittle transition temperatures, particularly in the oxide dispersion strengthened versions. This paper describes attempts to reduce the DBTT in an un-irradiated ferritic steel by a novel heat treatment procedure. New batches of high alloy Fe–9Cr oxide dispersion strengthened (Eurofer) ferritic steel have been produced by a powder metallurgy route, and relatively homogeneous material has been produced by hot isostatic pressing (HIP). Mini-Charpy test specimens were made from materials which had been subjected to a matrix of heat treatments with varying solution treatment temperature (ST), cooling rate from the ST temperature, and tempering treatment. The initial DBTT was in the range of 150–200 °C (423–473 K). Downward shifts of up to approximately 200 °C (473 K) have been observed after solution treatment at 1300 °C (1573 K) followed by slow cooling. This paper describes the microstructure of this material, and discussion is made of the likely microstructural factors needed to produce these DBTT downward shifts

  18. Controlling the ductile to brittle transition in Fe–9%Cr ODS steels

    Energy Technology Data Exchange (ETDEWEB)

    Di Martino, S.F., E-mail: s.f.di-martino@lboro.ac.uk; Riddle, N.B.; Faulkner, R.G.

    2013-11-15

    Probably the most important range of materials for consideration as the blanket material for the tokamak design for fusion reactors ITER and DEMO is the high alloy Fe–9Cr oxide dispersion strengthened ferritic steels. Ferritic steels possess exceptional thermal conductivity and low thermal expansion and are resistant to void swelling. Their main drawback is high ductile to brittle transition temperatures, particularly in the oxide dispersion strengthened versions. This paper describes attempts to reduce the DBTT in an un-irradiated ferritic steel by a novel heat treatment procedure. New batches of high alloy Fe–9Cr oxide dispersion strengthened (Eurofer) ferritic steel have been produced by a powder metallurgy route, and relatively homogeneous material has been produced by hot isostatic pressing (HIP). Mini-Charpy test specimens were made from materials which had been subjected to a matrix of heat treatments with varying solution treatment temperature (ST), cooling rate from the ST temperature, and tempering treatment. The initial DBTT was in the range of 150–200 °C (423–473 K). Downward shifts of up to approximately 200 °C (473 K) have been observed after solution treatment at 1300 °C (1573 K) followed by slow cooling. This paper describes the microstructure of this material, and discussion is made of the likely microstructural factors needed to produce these DBTT downward shifts.

  19. X-ray photoelectron spectroscopy investigations of zinc-magnesium alloy coated steel

    Energy Technology Data Exchange (ETDEWEB)

    Chen Sheng, E-mail: chen_sheng@baosteel.com [Research Institute of Baoshan Iron and Steel Co. Ltd., 655 Fujin Road, Baoshan District, Shanghai 201900 (China); Yan Fei; Xue Fei; Yang Lihong; Liu Junliang [Research Institute of Baoshan Iron and Steel Co. Ltd., 655 Fujin Road, Baoshan District, Shanghai 201900 (China)

    2010-11-01

    The coating layer composition depth profiles and element chemical states of zinc-magnesium alloy coated steel were investigated by X-ray photoelectron spectroscopy depth profiling. Through the analysis of photoelectron signals and Auger signals of different elements on different depth planes of the coating layer, it can be found that the surface of the coating layer contains MgCO{sub 3}, MgO, Mg(OH){sub 2}, metallic Mg, metallic Zn and some complex zinc compounds. Under the surface, there is a Zn{sub 2}Mg alloy layer with the thickness of about 300 nm accompanied with MgO and Mg(OH){sub 2} in the layer. There is a transitional layer with the thickness of about 200 nm between the Zn{sub 2}Mg alloy layer and the pure Zn layer, whose components consist of zinc-magnesium alloy without fixed stoichiometry, a little MgO and a little Mg(OH){sub 2}.

  20. Hydrogen adsorption and diffusion, and subcritical-crack growth in high-strength steels and nickel base alloys

    Science.gov (United States)

    Wei, R. P.; Klier, K.; Simmons, G. W.

    1974-01-01

    Coordinated studies of the kinetics of crack growth and of hydrogen adsorption and diffusion were initiated to develop information that is needed for a clearer determination of the rate controlling process and possible mechanism for hydrogen enhanced crack growth, and for estimating behavior over a range of temperatures and pressures. Inconel 718 alloy and 18Ni(200) maraging steel were selected for these studies. 18Ni(250) maraging steel, 316 stainless steel, and iron single crystal of (111) orientation were also included in the chemistry studies. Crack growth data on 18Ni(250) maraging steel from another program are included for comparison. No sustained-load crack growth was observed for the Inconel 718 alloy in gaseous hydrogen. Gaseous hydrogen assisted crack growth in the 18Ni maraging steels were characterized by K-independent (Stage 2) extension over a wide range of hydrogen pressures (86 to 2000 torr or 12 kN/m2 to 266 kN/m2) and test temperatures (-60 C to +100 C). The higher strength 18Ni(250) maraging steel was more susceptible than the lower strength 200 grade. A transition temperature was observed, above which crack growth rates became diminishingly small.

  1. Comparison on Mechanical Properties of SA508 Gr.3 Cl.1, Cl.2, and Gr.4N Low Alloy Steels for Pressure Vessels

    International Nuclear Information System (INIS)

    In this study, microstructure and mechanical properties of SA508 Gr.3 Cl. 1, Cl.2, and Gr.4N low alloy steels are characterized to compare their properties. To evaluate the fracture toughness in the transition region, the master curve method according to ASTM E1921 was adopted in the cleavage transition region. Tensile tests and Charpy impact tests were also performed to evaluate the mechanical properties, and a microstructural investigation was carried out. The microstructure and mechanical properties of SA508 Gr.3 Cl.1, Cl2 and Gr.4N low alloy steels were characterized.. The predominant microstructure of SA508 Gr.4N model alloy is tempered martensite, while SA508 Gr.3 Cl.1 and Cl.2 steels show a typical tempered upper bainitic structure. SA508 Gr. 4N model alloy shows the best strength and transition behavior among the three SA508 steels. SA508 Gr.3 Cl.2 steel also has quite good strength, but there is a loss of toughness

  2. Comparison on Mechanical Properties of SA508 Gr.3 Cl.1, Cl.2, and Gr.4N Low Alloy Steels for Pressure Vessels

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Min-Chul; Park, Sang-Gyu; Lee, Bong-Sang [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of); Lee, Ki-Hyoung [Korea Institute of Nuclear Safety, Daejeon (Korea, Republic of)

    2014-10-15

    In this study, microstructure and mechanical properties of SA508 Gr.3 Cl. 1, Cl.2, and Gr.4N low alloy steels are characterized to compare their properties. To evaluate the fracture toughness in the transition region, the master curve method according to ASTM E1921 was adopted in the cleavage transition region. Tensile tests and Charpy impact tests were also performed to evaluate the mechanical properties, and a microstructural investigation was carried out. The microstructure and mechanical properties of SA508 Gr.3 Cl.1, Cl2 and Gr.4N low alloy steels were characterized.. The predominant microstructure of SA508 Gr.4N model alloy is tempered martensite, while SA508 Gr.3 Cl.1 and Cl.2 steels show a typical tempered upper bainitic structure. SA508 Gr. 4N model alloy shows the best strength and transition behavior among the three SA508 steels. SA508 Gr.3 Cl.2 steel also has quite good strength, but there is a loss of toughness.

  3. Reactive Boride Brazing on Low-Alloy Automotive Grade Steel

    Science.gov (United States)

    Palanisamy, B.; Upadhyaya, A.

    2011-11-01

    Brazing is a widely used process to improve the performance of steels used in automotive applications. The substrate material is often exposed to harsh conditions in these applications and may affect the service life of the component. Reactive boride brazing aims to improve the mechanical properties of the substrate material by forming a ceramic-metal composite coating in a single-step process in situ. In this study, sintered Ancor 4300 low-alloy steel is used as the substrate with chromium-rich braze and chromium-lean braze materials. The mechanical properties of the brazed samples were studied in detail using microindentation hardness measurements and the transverse rupture test. The results indicate that the brazed superlayer has a 10 times higher hardness. There was a significant improvement in the transverse rupture strength of the steel brazed with the chromium-rich boride as compared to the pure substrate material. In an effort to reduce processing time, green compacts of the substrate were also directly brazed and yielded favorable results.

  4. Effect of amide type modified rapeseed oil as lubricating additive on friction and wear behavior of steel-steel and steel-aluminum alloy systems

    Institute of Scientific and Technical Information of China (English)

    FANG Jian-hua; CHEN Bo-shui; LIU Wei-min; DONG Lin; WANG Jiu

    2004-01-01

    A new type of environmentally friendly lube additive-amide type modified rapeseed oil was synthesized and characterized by infrared spectrum. Its effect on the friction and wear behavior of steel-steel and steel-aluminum alloy systems were investigated with a four-ball machine and an Optimol SRV friction and wear tester respectively.The morphographies of the worn surfaces were analyzed by means of scanning electron microscopy(SEM). The worn surfaces of the 2024Al alloy block were analyzed by means of X-ray photoelectron spectroscopy(XPS). The results show that the modified rapeseed oil as additives can obviously decrease the wear rate and friction coefficient of steel pair and steel-aluminum frictional pair. Its lubrication mechanism is inferred that a high strength complex protection films form on the worn surface of the Al alloy due to the adsorption or tribochemistry reaction of a long chain additive molecule and high reaction activity of N element.

  5. Resistance of the alloy steel used in the fuel gas desulphurization installations

    International Nuclear Information System (INIS)

    The results have been presented of DC polarization and exposure investigations of alloy steels used as construction materials in flue gas desulphurization installations. on the base of analysis of composition of investigated steels and results of polarization studies, conditions have been discussed in which the pitting resistance equivalent (PRE) should be used. Among tested steels the significantly highest resistance to pitting corrosion is exhibited by 654SMO steel, classified as the super austenitic grade. (author). 14 refs, 3 figs, 2 tabs

  6. Effects of V Addition on Microstructure and Hardness of Fe-C-B-Ni-V Hardfacing Alloys Cast on Steel Substrates

    Science.gov (United States)

    Rovatti, L.; Lemke, J. N.; Emami, A.; Stejskal, O.; Vedani, M.

    2015-12-01

    Fe-based hardfacing alloys containing high volume fraction of hard phases are a suitable material to be deposited as wear resistant thick coatings. In the case of alloys containing high amount of interstitial alloying elements, a key factor affecting the performance is dilution with the substrate induced by the coating process. The present research was focused on the analysis of V-bearing Fe-based alloys after calibrated carbon and vanadium additions (in the range from 3 to 5 wt.%) to a commercial Fe-C-B-Ni hardfacing alloy. Vanadium carbides with a petal-like morphology were observed in the high-V hypereutectic alloys allowing to reach hardness values above 700 HV. The solidification range shifted to higher temperatures with increasing amount of vanadium addition and in the case of hypereutectic alloys, the gap remains close to that of the original alloy. In the last step of the research, the microstructural evolution after dilution was analyzed by casting the V-rich alloys on a steel substrate. The dilution, caused by the alloying element diffusion and the local melting of the substrate, modified the microstructure and the hardness for a relevant volume fraction of the hardfacing alloys. In particular, the drop of interstitial elements induced the transition from the hypereutectic to the hypoeutectic microstructure and the formation of near-spherical V-rich carbides. Even after dilution, the hardness of the new alloys remained higher than that measured in the original Fe-C-B-Ni alloy.

  7. Discontinuous structural phase transition of liquid metal and alloys (2)

    International Nuclear Information System (INIS)

    The diameter (df) of diffusion fluid cluster before and after phase transition has been calculated in terms of the paper ''Discontinuous structural phase transition of liquid metal and alloy (1)'' Physics Letters. A 326 (2004) 429-435, to verify quantitatively the discontinuity of structural phase transition; the phenomena of thermal contraction and thermal expansion during the phase transition, together with the evolution model of discontinuous structural phase transition are also discussed in this Letter to explore further the nature of structural transition; In addition, based on the viscosity experimental result mentioned in paper [Y. Waseda, The Structure of Non-Crystalline Materials--Liquids and Amorphous Solids, McGraw-Hill, New York, 1980], we present an approach to draw an embryo of the liquid-liquid (L-L) phase diagram for binary alloys above liquidus in the paper, expecting to guide metallurgy process so as to improve the properties of alloys. The idea that controls amorphous structure and its properties by means of the L-L phase diagram for alloys and by the rapid cooling technique to form the amorphous alloy has been brought forward in the end

  8. Deformation and fracture of low alloy steels at high temperature

    Energy Technology Data Exchange (ETDEWEB)

    Marriott, D.L.; Stubbins, J.F.; Leckie, F.A.; Muddle, B.

    1988-12-01

    This project formed part of the initiative in the AR TD program to characterize high temperature, time-dependent damage processes in low alloy steels, for use in the construction of coal-gasification plant. This project was broadly aimed at adding to the knowledge base for this bainitic form of 2.25Cr 1Mo steel, as it related to time-dependent performance at elevated temperature. Its original intention was to obtain information in specific grades of 2.25Cr 1Mo steel, in particular those containing reduced residual elements and microalloyed modifications, which were being considered as candidate materials at the time. This objective was subsequently modified, in the course of the contract period, to a more generic study of bainitic steel, using the 2.25Cr 1Mo material as a representative of the class. The main thrust of the project was directed initially at the detrimental effect of cyclic loading on creep resistance and manifesting itself in an apparently severe creep-fatigue interaction. Three subtasks were eventually identified. These are: a study of the evolution of microstructural changes in bainitic materials during steady load creep and under constant amplitude cyclic deformation, investigation of the effect of cyclic softening on the fatigue and creep strength of complex geometries, focusing on circumferentially notched bars, and investigation of the influence of environment as a possible cause of observed fatigue/elevated temperature interaction through its effects on crack initiation and propagation, using EDM notched specimens tested in air and vacuum. Results are discussed. 24 refs., 40 figs., 5 tabs.

  9. Highly alloyed stainless steels for sea water applications

    Energy Technology Data Exchange (ETDEWEB)

    Audouard, J.P.; Verneau, M. [Creusot-Loire Industrie, Le Creusot (France). Research Centre for Materials

    1996-10-01

    Natural sea water is known as a very aggressive environment which generates pitting and crevice corrosion on stainless steels. High chromium grades with sufficient molybdenum and nitrogen additions (PREN > 40) are generally recognized as resistant materials in natural sea water bu the material selection criteria must be improved to take into account the effect of climatic conditions and of biocide treatments which are widely used as anti-fouling agents in sea water circuits. The paper deals with the localized corrosion properties of conventional stainless steels (SS), duplex and superaustenitic alloys. The results of laboratory investigations conducted in more or less oxidizing chloride containing media are discussed. Then, immersion tests carried out in natural sea waters in different climatic conditions are presented and discussed. Finally, the effect of biocide addition on fouling and its consequences on corrosion is investigated. The results are interpreted taking into account the chemical composition of the stainless steels and biofilm criteria. The results showed the Mediterranean Sea to be slightly more aggressive than other European seas but a PREN value higher than 40 is sufficient for stainless steels to withstand localized corrosion in European natural sea waters. A residual chlorine level around 0.3--0.4 ppm was found to be very effective to limit the fouling and to avoid localized corrosion on SS. Nevertheless, due to difficulties in monitoring chlorine addition, PREN values higher than 50 are recommended to withstand localized corrosion in treated sea waters. As an example, the new super-austenitic grade 25Cr-22Ni-5.8Mo-1.5Cu-2W-0.45N with a PRENW value of 54 was found to be perfectly resistant to crevice corrosion with 0.5 ppm free chlorine at ambient temperature.

  10. Enhancement of Impact Toughness by Delamination Fracture in a Low-Alloy High-Strength Steel with Al Alloying

    Science.gov (United States)

    Sun, Junjie; Jiang, Tao; Liu, Hongji; Guo, Shengwu; Liu, Yongning

    2016-09-01

    The effect of delamination toughening of martensitic steel was investigated both at room and low temperatures [253 K and 233 K (-20 °C and -40 °C)]. Two low-alloy martensitic steels with and without Al alloying were both prepared. Layered structure with white band and black matrix was observed in Al alloyed steel, while a homogeneous microstructure was displayed in the steel without Al. Both steels achieved high strength (tensile strength over 1600 MPa) and good ductility (elongation over 11 pct), but they displayed stark contrasts on impact fracture mode and Charpy impact energy. Delamination fracture occurred in Al alloyed steel and the impact energies were significantly increased both at room temperature (from 75 to 138 J, i.e., nearly improved up to 2 times) and low temperatures [from 47.9 to 71.3 J at 233 K (-40 °C)] compared with the one without Al. Alloying with Al promotes the segregation of Cr, Mn, Si and C elements to form a network structure, which is martensite with higher carbon content and higher hardness than that of the matrix. And this network structure evolved into a band structure during the hot rolling process. The difference of yield stress between the band structure and the matrix gives rise to a delamination fracture during the impact test, which increases the toughness greatly.

  11. Low temperature mechanical properties, fractographic and metallographic evaluation of several alloy steels

    Science.gov (United States)

    Montano, J. W.

    1973-01-01

    The mechanical properties are presented of alloy steels, 4130, 4140, 4340, 6150, and 8740. Test specimens were manufactured from approximately 1.00 inch (2.54 cm) diameter bar stock which had been heat treated to two different hardness levels. The following mechanical tests were performed at temperatures of 80 F (+26.7 C), 0 F (-17.8 C), -100 F (-73 C), and -200 F (-129 C): (1) tensile test (Ultimate, yield, modulus, elongation, and reduction of area), (2) notched tensile test, (3) charpy V-notched impact test (impact energy), and (4) double shear strength test (ultimate and yield). The test data indicate excellent tensile strength, notched/unnotched tensile ratios, ductility, impact, and shear properties at all test temperatures, except at -200 F (-129 C) where the impact strength of the higher strength group of alloy steels, 4130 (Rc-37) and 4140 (Rc-44) decreased to approximately 9 ft. lbs. (12 joules) and 6 ft. lbs. (8 joules), respectively. Chemical, metallographic, and fractographic analyses were also performed to evaluate microstructure, microhardness and the effect of decrease in temperature on the ductile to brittle failure transition.

  12. Effect of heat-treatment on phase transition temperatures of a superelastic NiTi alloy for medical use

    Energy Technology Data Exchange (ETDEWEB)

    Yeung, K.W.K.; Cheung, K.M.C.; Lu, W.W.; Luk, K.D.K. [Univ. of Hong Kong (China). Dept. of Orthopaedic Surgery; Chung, C.Y. [City Univ. of Hong Kong, Kowloon (China). Dept. of Physics and Materials Science

    2002-07-01

    Surgical correction of scoliosis typically uses stainless steel or titanium alloy spinal instrumentation to straighten the scoliotic spine by 70% only. Our aim is to develop a method to overcome this by using an implantable superelastic (SE) nickel-titanium (NiTi) alloy rod, which will impose a continuous gradual correction force to the spine after the surgery so as to achieve a superior correction. More than 75 specimens made of a Ti-50.0 at% Ni alloy were treated by different heat treatment routes. The Austenitic transition temperature of the NiTi alloy can be adjusted to be available at 37.5 C by altering the heat treatment parameters: time and temperature of heat treatment. The experimental results showed that the heat treatment temperature should set between 400-500 C and the heat treatment time should be less than 60 minutes for the alloy. (orig.)

  13. Experimental investigation of laser beam welding of explosion-welded steel/aluminum structural transition joints

    International Nuclear Information System (INIS)

    The steel/aluminum structural transition joints are widely used in shipbuilding industry due to the advantages of joining these two materials with important weight savings while exploiting their best properties. The use of laser welding to strongly connect components made of Fe and Al alloys as base materials with Fe/Al structural transition joints is very attractive. The authors report results achieved during the laser welding of these particular joints with the scope to evaluate effects of the laser-induced thermal loads on the integrity of the Fe/Al bond interface, from metallurgical and mechanical points of view. The increase of both inter-metallic film thickness and extension were detected as a result of the laser beam induced heat on the Fe/Al bond interface. These increases did not cause severe reductions of the mechanical resistance of the investigated structural transition joint.

  14. Temperature rise and wear of sliding contact of alloy steels

    Science.gov (United States)

    Goswami, Arindam Roy; Sardar, Santanu; Karmakar, Santanu Kumar

    2016-07-01

    The tribo-failure of machine elements under relative sliding velocities is greatly affected by frictional heating and resultant contact temperature rise. Nevertheless, the tribo-failure of automotive components is a combined effect of mechanical, thermal and chemical phenomena. Over the decades, there have been developed a number of different mathematical models for predicting surface temperature rise at sliding contact under different geometries of asperity contacts and operating conditions. The experimental investigation is still relevant today to find out the surface temperature rise at sliding contact along with the outcomes of friction and wear under various operating conditions for real time applications. The present work aims at finding average surface temperature rise at different sliding velocities, normal loads with different surface roughness experimentally. It also involves to prepare two different rough surfaces of alloy steels and to study their influences in the process of generating contact temperature rise under a given operating conditions.

  15. Friction Welding of Aluminium and Aluminium Alloys with Steel

    Directory of Open Access Journals (Sweden)

    Andrzej Ambroziak

    2014-01-01

    Full Text Available The paper presents our actual knowledge and experience in joining dissimilar materials with the use of friction welding method. The joints of aluminium and aluminium alloys with the different types of steel were studied. The structural effects occurring during the welding process were described. The mechanical properties using, for example, (i microhardness measurements, (ii tensile tests, (iii bending tests, and (iv shearing tests were determined. In order to obtain high-quality joints the influence of different configurations of the process such as (i changing the geometry of bonding surface, (ii using the interlayer, or (iii heat treatment was analyzed. Finally, the issues related to the selection of optimal parameters of friction welding process were also investigated.

  16. Process to determine light elements content of steel and alloys

    Energy Technology Data Exchange (ETDEWEB)

    Quintella, Cristina M.A.L.T.M.H.; Castro, Martha T.P.O. [Universidade Federal da Bahia (IQ/UFBA), Salvador, BA (Brazil). Inst. de Quimica. LabLaser; Mac-Culloch, Joao N.L.M. [PETROBRAS, Rio de Janeiro, RJ (Brazil)

    2009-07-01

    The present work reports a process to determine qualitatively and quantitatively elements of molar mass inferior to 23 within materials, by X rays spectra associated with multivariate data analysis, or chemometric analysis. The spectra is acquired between 5 keV and 22 keV when the materials are exposed to X radiation. Here is reported the direct determination of carbon content in steel and metallic alloys. The process is more effective when using spectral regions which are not usually used. From the analysis of these spectral regions which were not considered before, it was possible to detect light elements with molar mass lower than 23, which have low capacity of absorbing and emitting radiation, but have high capacity of scattering radiation. The process here reported has the advantage that X-Ray spectra obtained are calibrated multivariately, showing high potential for development in order to be used in a portable field equipment. (author)

  17. Effects of alloying elements and heat treatments on mechanical properties of Korean reduced-activation ferritic–martensitic steel

    Energy Technology Data Exchange (ETDEWEB)

    Chun, Y.B., E-mail: borobang@gmail.com [Nuclear Materials Division, Korea Atomic Energy Research Institute, Daejeon 305-353 (Korea, Republic of); Kang, S.H.; Noh, S.; Kim, T.K. [Nuclear Materials Division, Korea Atomic Energy Research Institute, Daejeon 305-353 (Korea, Republic of); Lee, D.W. [Nuclear Fusion Engineering Development Division, Korea Atomic Energy Research Institute, Daejeon 305-353 (Korea, Republic of); Cho, S. [National Fusion Research Institute, Daejeon 305-806 (Korea, Republic of); Jeong, Y.H. [Nuclear Materials Division, Korea Atomic Energy Research Institute, Daejeon 305-353 (Korea, Republic of)

    2014-12-15

    As part of an alloy development program for Korean reduced-activation ferritic–martensitic (RAFM) steel, a total of 37 program alloys were designed and their mechanical properties were evaluated with special attention being paid to the effects of alloying elements and heat treatments. A reduction of the normalizing temperature from 1050 °C to 980 °C was found to have a positive effect on the impact resistance, resulting in a decrease in ductile–brittle transition-temperature (DBTT) of the program alloys by an average of 30 °C. The yield strength and creep rupture time are affected strongly by the tempering time at 760 °C but at the expense of ductility. Regarding the effects of the alloying elements, the addition of trace amounts of Zr enhances both the creep and impact resistance: the lowest DBTT was observed for the alloys containing 0.005 wt.% Zr, whereas the addition of 0.01 wt.% Zr extends the creep rupture-time under an accelerated condition. The enhanced impact resistance owing to the normalizing at lower temperature is attributed to a more refined grain structure, which provides more barriers to the propagation of cleavage cracks. Solution softening by Zr addition is suggested as a possible mechanism for enhanced resistance to both impact and creep of the program alloys.

  18. Effects of alloying elements and heat treatments on mechanical properties of Korean reduced-activation ferritic-martensitic steel

    Science.gov (United States)

    Chun, Y. B.; Kang, S. H.; Noh, S.; Kim, T. K.; Lee, D. W.; Cho, S.; Jeong, Y. H.

    2014-12-01

    As part of an alloy development program for Korean reduced-activation ferritic-martensitic (RAFM) steel, a total of 37 program alloys were designed and their mechanical properties were evaluated with special attention being paid to the effects of alloying elements and heat treatments. A reduction of the normalizing temperature from 1050 °C to 980 °C was found to have a positive effect on the impact resistance, resulting in a decrease in ductile-brittle transition-temperature (DBTT) of the program alloys by an average of 30 °C. The yield strength and creep rupture time are affected strongly by the tempering time at 760 °C but at the expense of ductility. Regarding the effects of the alloying elements, the addition of trace amounts of Zr enhances both the creep and impact resistance: the lowest DBTT was observed for the alloys containing 0.005 wt.% Zr, whereas the addition of 0.01 wt.% Zr extends the creep rupture-time under an accelerated condition. The enhanced impact resistance owing to the normalizing at lower temperature is attributed to a more refined grain structure, which provides more barriers to the propagation of cleavage cracks. Solution softening by Zr addition is suggested as a possible mechanism for enhanced resistance to both impact and creep of the program alloys.

  19. The Evolution of the Segregation Behavior of Alloying Elements in a Low-Alloy Steel

    Energy Technology Data Exchange (ETDEWEB)

    A.J. Papworth; D.B. Knorr; D.B. Williams

    2002-08-21

    The segregation of alloying and impurity elements to prior austenite grain boundaries (PAGBs) in low-alloy steels controls temper-embrittlement although the precise microchemical and microstructural interactions are, as yet, unclear because of the many variables involved. Competing segregation and de-segregation phenomena are observed. For example, Auger analyses of fracture surfaces indicate that brittle fracture is caused by the segregation of P to the PAGB. The addition of small amounts ({approx} 0.5 wt%) of Mo appears to regard, but not stop, temper-embrittlement, possibly due to Mo{sub 2}C precipitates that form at elevated temperatures causing de-segregation of Mo from the PAGB. The relationship between segregation and temper embrittlement is further complicated in commercial alloys by both the number of segregating elements and the complex, multi-stage heat treatments. Auger analysis pre-selects the most embrittled boundaries and so the complete distribution of segregants across all PAGBs cannot be determined by this technique. Previous work has shown how X-ray mapping (XRM) in a field-emission gun scanning transmission electron microscope (FEG-STEM) offers a more complete view of the distribution of segregants on both non-embrittled and embrittled PAGBs. XRM was used to observe the evolution of the segregation and desegregation of five elements during four successive heat-treatment stages of commercial low-alloy steel forging. In the last and crucial temper-embrittlement stage, increases in the degree and frequency of Ni segregation occur while other elements either segregate, remain constant or desegregate from the PAGBs.

  20. Improving Corrosion Resistance of Q235 Steel by Ni-Cr Alloyed Layer

    Institute of Scientific and Technical Information of China (English)

    HUANG Jun; ZHANG Pingze; WU Hongyan; BI Qiang

    2012-01-01

    Ni-Cr alloyed layer was formed on surface of Q235 steel by double glow plasma surface metallurgy to improve the corrosion resistance of substrate.The composition and microstructure of alloyed layer was analyzed by SEM and XRD.Potentiodynamic polarization and electrochemical impedance spectroscopy was applied to evaluate the corrosion resistance of the alloyed layer.The results showed working pressure had a great effect on structure of Ni-Cr alloyed layer,and the dense and smooth alloyed layer was prepared at 50 Pa working pressure.Compared with substrate,Ni-Cr alloyed layer exhibited higher corrosion potential,lower corrosion current density and larger charge transfer resistance,which indicated that Ni-Cr alloyed layer significantly modified the corrosion resistance of Q235 steel.

  1. Coherent-Incoherent Transition of ɛ-Carbide in Steels Found with Mechanical Spectroscopy

    Science.gov (United States)

    Shimotomai, Michio

    2016-03-01

    Although a coherent-incoherent transition in the ɛ-carbide precipitated in steels is supposedly linked to hardening and microstructural changes, the existence of this transition has not yet been confirmed. In this paper, we investigate this subject using mechanical spectroscopy. By measuring mechanical loss spectra below room temperature of quench-aged Fe-C alloys, mild steel, and pearlitic steel, we reveal a new broad peak (NBP). This peak is related to thermal activation, and its line shape obeys the equation of the Debye peak with a distribution in relaxation time. The Arrhenius plot yielded a large activation energy and gigantic pre-exponential factor. Its intensity grew by aging at temperatures where precipitation of ɛ-carbide has been reported. However, it starts to decay at duration far too early for ɛ-carbide to transform to cementite. For isothermal aging at 393 K (120 °C), the intensity sharply decreased at durations over 3 hours. This decay was accompanied by appearance of another similar peak (NBP'), which had a peak frequency two orders higher than that of NBP. These peaks had comparable intensity. We attribute NBP and NBP' to coherent and incoherent ɛ-carbides, respectively. We produced a model that attributes the relaxation peaks to reorientations of extra carbon pairs in the ɛ-carbide. The extraordinary values of the Arrhenius parameters may be interpreted by using this model. Based on these results, we assert that mechanical spectroscopy can detect the coherent-incoherent transition in carbon steels. This method will be powerful in studying problems related to the coherency in carbon steels.

  2. Low-Temperature Toughening Mechanism in Thermomechanically Processed High-Strength Low-Alloy Steels

    Science.gov (United States)

    Hwang, Byoungchul; Lee, Chang Gil; Kim, Sung-Joon

    2011-03-01

    High-strength low-alloy (HSLA) steels were fabricated by varying thermomechanical processing conditions such as rolling and cooling conditions in the intercritical region, and the low-temperature toughening mechanism was investigated in terms of microstructure and the associated grain boundary characteristics. The steels acceleratedly cooled to relatively higher temperature had lower tensile strength than those acceleratedly cooled to room temperature due to the increased volume fraction of granular bainite or polygonal ferrite (PF) irrespective of rolling in the intercritical region, while the yield strength was dependent on intercritical rolling, and start and finish cooling temperatures, which affected the formation of PF and low-temperature transformation phases. The steel rolled in the intercritical region and cooled to 673 K (400 °C) provided the best combination of high yield strength and excellent low-temperature toughness because of the presence of fine PF and appropriate mixture of various low-temperature transformation phases such as granular bainite, degenerate upper bainite (DUB), lower bainite (LB), and lath martensite (LM). Despite the high yield strength, the improvement of low-temperature toughness could be explained by the reduction of overall effective grain size based on the electron backscattered diffraction (EBSD) analysis data, leading to the decrease in ductile-to-brittle transition temperature (DBTT).

  3. Stress Induced Phase Transition of Iron-Rhodium Alloys

    OpenAIRE

    Takahashi, M; Oshima, R.

    1995-01-01

    Stress-induced phase transitions(B2-L10, B2-fcc) on an FeRh alloy were investigated with X-ray diffraction (XRD) and transmission electron microscopy(TEM). An Fe-50.5at%Rh alloy was rolled to 80µm thickness, and annealed at 1370K for 173ks. Annealed sample sheets were cold rolled at various rolling rates, and changes of the sample alloy on the phase state were investigated with XRD. The L10 phase appeared in the early stage of cold work. With heavy work appearance of the fcc phase and consequ...

  4. Crack-Growth Behavior of Laser Surface-Alloyed Low-Carbon Steel

    Science.gov (United States)

    Šturm, Roman; Žnidaršič, Matjaž; Grum, Janez

    2013-09-01

    Crack-growth behavior of Nd:YAG laser surface-alloyed as-received low-carbon steel Fe360B was evaluated. Thin surface layer was alloyed with silicon carbide SiC. During laser surface alloying process SiC powder dissolved in the melted pool. The surface-alloyed layer had as-solidified structure composed mainly of dendrites of ferrite, fine martensite needles, and retained austenite. The micro-hardness of the laser surface-alloyed layer was about 850 HV0.1. In laser surface-alloyed layer compressive residual stresses of average amount of σ RS = -100 MPa were obtained. In crack-growth tests comparison between specimens of as-received low-carbon steel Fe360B and the same steel with laser-alloyed surface was made. As the crack propagation was perpendicular to the interface between the laser-alloyed layers and the base metal, laser surface-alloyed specimens exhibited higher crack-growth resistance in the low stress intensity factor range Δ K th than as-received steel specimens.

  5. Nanosized controlled surface pretreatment of biometallic alloy 316L stainless steel.

    Science.gov (United States)

    Abdel-Fattah, Tarek M; Loftis, Derek; Mahapatro, Anil

    2011-12-01

    Stainless steel (AISI 316L) is a medical grade stainless steel alloy used extensively in medical devices and in the biomedical field. 316L stainless steel was successfully electropolished via an ecologically friendly and biocompatible ionic liquid (IL) medium based on Vitamin B4 (NB4) and resulting in nanosized surface roughness and topography. Voltammetry and chronoamperometry tests determined optimum polishing conditions for the stainless steel alloy while atomic force microscopy (AFM) and scanning electron microscopy (SEM) provided surface morphology comparisons to benchmark success of each electropolishing condition. Energy dispersive X-ray analysis (EDX) combined with SEM revealed significantly smoother surfaces for each alloy surface while indicating that the constituent metals comprising each alloy effectively electropolished at uniform rates. PMID:22416578

  6. 78 FR 2658 - Carbon and Certain Alloy Steel Wire Rod From Mexico: Rescission of Antidumping Duty...

    Science.gov (United States)

    2013-01-14

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF COMMERCE International Trade Administration Carbon and Certain Alloy Steel Wire Rod From Mexico: Rescission of... Administration, Department of Commerce. SUMMARY: The Department of Commerce (the ``Department'') is...

  7. Static Recrystallization Behavior of Hot Deformed Austenite for Micro-Alloyed Steel

    Institute of Scientific and Technical Information of China (English)

    Jie HUANG; Zhou XU; Xin XING

    2003-01-01

    Static recrystallization behavior of austenite for micro-alloyed steel during hot rolling was studied and the influence (τ-ε diagram) of holding time and deformation at different deformations and isothermal temperatures on microstructuralstate of austen

  8. Corrosion Behavior and Durability of Low-Alloy Steel Rebars in Marine Environment

    Science.gov (United States)

    Liu, Ming; Cheng, Xuequn; Li, Xiaogang; Yue, Pan; Li, Jun

    2016-10-01

    The corrosion resistance of Cr-modified low-alloy steels and HRB400 carbon steel was estimated using the open-circuit potential, potentiodynamic polarization, electrochemical impedance spectroscopic, and weight loss methods in simulated concrete pore solution. Results show that Cr-modified steels exhibit a higher corrosion resistance with a higher critical chloride level (CTL), lower corrosion current density, and higher impedance than carbon steel. The CTL of the steels significantly reduces with increasing temperature. Weight loss measurement shows that the Cr-modified steels exhibit low corrosion rates and small corrosion pitting. The primary constituents of the corrosion scales are Fe2O3, Fe3O4, β-FeOOH, γ-FeOOH, and α-FeOOH. A large amount of α-FeOOH could be detected in the Cr-modified steel corrosion products. Moreover, the Cr-modified steels demonstrate a higher durability than HRB400 carbon steel.

  9. 77 FR 56809 - Certain Small Diameter Seamless Carbon and Alloy Steel Standard, Line, and Pressure Pipe From...

    Science.gov (United States)

    2012-09-14

    ... Diameter Seamless Carbon and Alloy Steel Standard, Line and Pressure Pipe From Germany, 60 FR 39704 (August...\\ \\3\\ See Certain Small Diameter Seamless Carbon and Alloy Standard, Line, and Pressure Pipe From... International Trade Administration Certain Small Diameter Seamless Carbon and Alloy Steel Standard, Line,...

  10. Irradiation damage behavior of low alloy steel wrought and weld materials

    International Nuclear Information System (INIS)

    A study was undertaken to evaluate the irradiation damage response of several different types of low alloy steel. The materials included vitange type ASTM A302 Grade B (A302B) plates and welds containing different nickel (Ni) and copper (Cu) concentrations, 3.5% Ni steels similar to ASTM A508 Class 4, welds containing about 1% Ni (similar to type 105S), and 3.5% Ni steels with 'superclean' composition (extremely low phosphorus, sulfur, manganese and silicon). To determine irradiation damage behavior, all materials were irradiated at several different irradiation damage levels ranging from 0.0003 dpa to 0.06 dpa at an irradiation damage levels ranging from 0.003 dpa to 0.06 dpa at an irradiation temperature of about 232 degrees C (450 degrees F). Complete Charpy V-notch impact energy transition temperature curves were generated for all materials before and after irradiation to determine the transition temperature at 41J (30 ft-lb) or 47J (35 ft-lb) and the upper shelf energy. The irradiation damage behavior was measured by the shift in the Charpy 41J or 47J transition temperature (ΔTT41J or ΔTT47J) and lowering of the upper shelf Charpy energy at a given irradiation damage level. It was found that chemical composition greatly influenced irradiation damage behavior. The highest irradiation damage (greatest ΔTT) was found in an A302B type weld contaiNing 1.28% Ni and 0.20% CU while the least irradiation damage was found in the 3.5% Ni, 0.05% Cu, superclean wrought materials

  11. Initiation of cleavage in a low alloy steel: effect of a ductile damage localized around inclusions

    International Nuclear Information System (INIS)

    The fracture mechanism in a low alloy steel, used in the pressurised water reactor vessel, has been studied in the ductile to brittle transition temperature range. We used the local approach of fracture in conjunction with both fractographic observations and numerical simulations. Previous studies suggested the onset of cleavage to be favoured by the presence of nearby manganese sulphide (MnS) clusters: the ductile damaged zone localised inside a cluster increases the stress around it, and so contribute to the triggering of cleavage due to nearby classical sites, like carbides. The experimental study of size dependence and anisotropy on the global fracture behaviour, together with fractographic observations, give here the proof of the influence of MnS clusters on the onset of cleavage in this steel. Fracture behaviour of pre-cracked specimens tested in the transition regime has then been simulated, by three dimensional finite element method computations. Ductile tearing process preceding the cleavage onset at those temperatures regime was well reproduced by the Rousselier's model. Failure probabilities, related to given stress states, has been given by post-processor calculations, using a probabilistic model based on the specific cleavage fracture process. Fracture toughness scatter of the steel, tested in the transition regime, is then well reproduced by those calculations. However, the critical cleavage stress of an elementary volume, that scales for the fracture process, is still assumed to be temperature dependant. Numerical simulations of the local fracture process suggest that this temperature effect can partly be explained by the temperature dependant decrease of the stress amplification due to the MnS clusters. (author)

  12. Interfacial study of semi-solid aluminum alloy and stainless steel sheathed extrusion

    Institute of Scientific and Technical Information of China (English)

    LIU Hong-wei; GUO Cheng; LIU Xu-feng; SHAO Guang-jie

    2006-01-01

    Using sheathed extrusion technique, the bonding and forming of semi solid aluminum alloy with stainless steel sheath are successfully realized. The relationship between the interfacial shear strength and the solid fraction of semi solid aluminum alloy at different extrusion ratios is analyzed; the interfacial and fracture structure of the sheath material are studied by optical microscopy(OM) and scanning electric microscopy(SEM). The result shows that interfacial shear strength increases with the increase of extrusion ratio, the maximum value of the interfacial shear strength is obtained when solid fraction of aluminum alloy is 30%,solid phase and liquid phase of the semi solid aluminum alloy are bonded with stainless steel by turns along the interface, and the aluminum alloy can not be peeled from the stainless steel completely, which means nicer bonding occurs at the interface.

  13. Industrial Experience on the Caustic Cracking of Stainless Steels and Nickel Alloys - A Review

    Energy Technology Data Exchange (ETDEWEB)

    Rebak, R B

    2005-10-09

    Caustic environments are present in several industries, from nuclear power generation to the fabrication of alkalis and alumina. The most common material of construction is carbon steel but its application is limited to a maximum temperature of approximately 80 C. The use of Nickel (Ni) alloys is recommended at higher temperatures. Commercially pure Ni is the most resistant material for caustic applications both from the general corrosion and the stress corrosion cracking (SCC) perspectives. Nickel rich alloys also offer a good performance. The most important alloying elements are Ni and chromium (Cr). Molybdenum (Mo) is not a beneficial alloying element and it dissolves preferentially from the alloy in presence of caustic environments. Austenitic stainless steels such as type 304 and 316 seem less resistant to caustic conditions than even plain carbon steel. Experimental evidence shows that the most likely mechanism for SCC is anodic dissolution.

  14. Galvanic Interaction between Chalcopyrite and Pyrite with Low Alloy and High Carbon Chromium Steel Ball

    Directory of Open Access Journals (Sweden)

    Asghar Azizi

    2013-01-01

    Full Text Available This study was aimed to investigate the galvanic interaction between pyrite and chalcopyrite with two types of grinding media (low alloy and high carbon chromium steel ball in grinding of a porphyry copper sulphide ore. Results indicated that injection of different gases into mill altered the oxidation-reduction environment during grinding. High carbon chromium steel ball under nitrogen gas has the lowest galvanic current, and low alloy steel ball under oxygen gas had the highest galvanic current. Also, results showed that the media is anodic relative to pyrite and chalcopyrite, and therefore pyrite or chalcopyrite with a higher rest potential acted as the cathode, whilst the grinding media with a lower rest potential acted as the anode, when they are electrochemically contacted. It was also found that low alloy steel under oxygen produced the highest amount of EDTA extractable iron in the slurry, whilst high carbon chromium steel under nitrogen atmosphere led to the lowest amount.

  15. Design of a low-alloy high-strength and high-toughness martensitic steel

    Science.gov (United States)

    Zhao, Yan-jun; Ren, Xue-ping; Yang, Wen-chao; Zang, Yue

    2013-08-01

    To develop a high strength low alloy (HSLA) steel with high strength and high toughness, a series of martensitic steels were studied through alloying with various elements and thermodynamic simulation. The microstructure and mechanical properties of the designed steel were investigated by optical microscopy, scanning electron microscopy, tensile testing and Charpy impact test. The results show that cementite exists between 500°C and 700°C, M7C3 exits below 720°C, and they are much lower than the austenitizing temperature of the designed steel. Furthermore, the Ti(C,N) precipitate exists until 1280°C, which refines the microstructure and increases the strength and toughness. The optimal alloying components are 0.19% C, 1.19% Si, 2.83% Mn, 1.24% Ni, and 0.049% Ti; the tensile strength and the V notch impact toughness of the designed steel are more than 1500 MPa and 100 J, respectively.

  16. Neutron irradiation test of copper alloy/stainless steel joint materials

    OpenAIRE

    山田 弘一; 河村 弘

    2006-01-01

    As a study about the joint technology of copper alloy and stainless steel for utilization as cooling piping in International Thermonuclear Experimental Reactor (ITER), Al2O3-dispersed strengthened copper or CuCrZr was joined to stainless steel by three kinds of joint methods (casting joint, brazing joint and friction welding method) for the evaluation of the neutron irradiation effect on joints. A neutron irradiation test was performed to three types of joints and each copper alloy. The avera...

  17. Effect of inter-critical quenching on mechanical properties of casting low-alloy steel

    OpenAIRE

    Liu Zhongli; Shang Yong

    2013-01-01

    For some casting low-alloy steels, traditional quenching and tempering heat treatments can improve the strength; however, sometimes the ductility is not satisfied. Therefore, some kind of effective heat treatment method seems necessary; one which could improve the ductility, but not seriously affect the strength. In this paper, the effect of inter-critical quenching (IQ) on the mechanical properties of casting low-alloy steel was studied. IQ was added between quenching and tempering heat trea...

  18. Microstructure and mechanical properties of a new type of austempered boron alloyed high silicon cast steel

    OpenAIRE

    Chen Xiang; Li Yanxiang

    2013-01-01

    In the present paper, a new type of austempered boron alloyed high silicon cast steel has been developed, and its microstructures and mechanical properties at different temperatures were investigated. The experimental results indicate that the boron alloyed high silicon cast steel comprises a dendritic matrix and interdendritic eutectic borides in as-cast condition. The dendritic matrix is made up of pearlite, ferrite, and the interdendritic eutectic boride is with a chemical formula of M2B (...

  19. Comparison of fracture properties in SA508 Gr.3 and Gr.4N high strength low alloy steels for advanced pressure vessel materials

    International Nuclear Information System (INIS)

    Nuclear power systems are moving to a larger capacity or smaller modular type. In any either case, advanced pressure vessel materials with high strength and toughness are definitely needed for an optimization of the design and construction, as well as the long-term operation. In this paper, two candidate materials, both of which are within the current ASME specifications of SA508 steel forging, are compared from the view point of fracture resistance properties for a nuclear pressure vessel steel. The microstructure and mechanical properties of SA508 Gr.3 Cl.1, Cl.2, and Gr.4N steels were also characterized. The predominant microstructure of SA508 Gr.4N model alloy is tempered martensite, while SA508 Gr.3 Cl.1 and Cl.2 steels show a tempered upper bainitic structure. SA508 Gr. 4N model alloy showed the best strength and transition behavior among the three types of SA508 steel. SA508 Gr.3 Cl.2 steel has good strength and fracture toughness, but there is a decrease in the upper-self energy. The fracture resistance and fatigue crack growth rate of SA508 Gr.3 Cl.2 and Gr.4N steels were comparable to those of SA508 Gr.3 Cl.1 steel. In terms of mechanical properties, SA508 Gr.4N steel is a fascinating material for the pressure vessel application although it still needs verification on the aging behavior such as the irradiation embrittlement resistance

  20. Fe-Cr-V ternary alloy-based ferritic steels for high- and low-temperature applications

    International Nuclear Information System (INIS)

    The phase stability of alloys and steels developed for application in nuclear fission and fusion technology is one of the decisive factors determining the potential range of operating temperatures and radiation conditions that the core elements of a power plant can tolerate. In the case of ferritic and ferritic-martensitic steels, the choice of the chemical composition is dictated by the phase diagram for binary FeCr alloys where in the 0-9% range of Cr composition the alloy remains in the solid solution phase at and below the room temperature. For Cr concentrations exceeding 9% the steels operating at relatively low temperatures are therefore expected to exhibit the formation of α' Cr-rich precipitates. These precipitates form obstacles for the propagation of dislocations, impeding plastic deformation and embrittling the material. This sets the low temperature limit for the use of of high (14% to 20%) Cr steels, which for the 20% Cr steels is at approximately 600 deg. C. On the other hand, steels containing 12% or less Cr cannot be used at temperatures exceeding ∼600 deg. C due to the occurrence of the α-γ transition (912 deg. C in pure iron and 830 deg. C in 7% Cr alloy), which weakens the steel in the high temperature limit. In this study, we investigate the physical properties of a concentrated ternary alloy system that attracted relatively little attention so far. The phase diagram of ternary Fe-Cr-V alloy shows no phase boundaries within a certain broad range of Cr and V concentrations. This makes the alloy sufficiently resistant to corrosion and suggests that steels and dispersion strengthened materials based on this alloy composition may have better strength and stability at high temperatures. Experimental heats were produced on a laboratory scale by arc melting the material components to pellets, then by melting the pellets in an induction furnace and casting the melt into copper moulds. The compositions in weight percent (iron base) are 10Cr5V, 10Cr

  1. Comparison of Channel Segregation Formation in Model Alloys and Steels via Numerical Simulations

    Science.gov (United States)

    Cao, Y. F.; Chen, Y.; Li, D. Z.; Liu, H. W.; Fu, P. X.

    2016-06-01

    In the current study, the evolutions of channel segregations in several alloy systems, such as the typically used model alloys ( e.g., Ga-In, Sn-Pb, Sn-Bi, Al-Cu, and Ni-based superalloy) and some special steels, are numerically simulated in a cavity solidified unidirectionally. The simulations are based on a modified continuum macrosegregation model with an extension to the multicomponent systems. The results of model alloys and steels indicate that when the thermosolutal convection is strong enough, flow instability occurs, which in turn destabilizes the mushy zone. Subsequently, the channel segregation forms with the continuous interaction between solidification and flow. The formation behavior and severity of channel segregations in various systems are different owing to their distinct melt convection strengths and solidification natures. In the current simulations, channels are apparent for model alloys with high content of solutes, whereas they are slight in some special steels, such as 27SiMn steel, and totally disappear in carbon steels. These occurrence features of channel segregation in simulations of steels are consistent with the analyses by a modified Rayleigh number associated with alloying elements, and both outcomes are well supported by the fully sectioned steel ingots in experiments.

  2. The Influence of Post Weld Heat Treatment in Alloy 82/182 Dissimilar Metal Weld between Low Alloy Steel and 316L Stainless Steel

    International Nuclear Information System (INIS)

    Dissimilar metal welds (DMWs) using an Alloy 82/182 are widely used to join low alloy steel components and stainless steel pipes in pressurized water reactors (PWRs). It has been reported that tensile residual stress would be generated within DMWs during the welding processes. It is thought as main reason for primary water stress corrosion cracking (PWSCC) resulting in deterioration of long-term integrity. The application of post weld heat treatment (PWHT) has been considered to reduce the tensile residual stress after welding process. Meanwhile, the PWHT could affect the changes in microstructure, mechanical properties, and corrosion resistance. Therefore, in this study, the effects of PWHT on the microstructure, mechanical properties and corrosion behaviors of base metals of low alloy steel and stainless steel and welding materials of Alloy 82/182 are evaluated. The influence of PWHT in DMW has been investigated. SA 508 and 316L SS exhibited tempered bainite and austenitic grains with a few residual stringer type ferrite. Grain boundary carbides are not precipitated owing to low carbon and insufficient exposure time in 316L SS. The change of mechanicals properties in base metals is not observed. In case of Alloy 182, after PWHT, grain boundaries are covered with film-like continuous Cr-rich carbides

  3. The Influence of Post Weld Heat Treatment in Alloy 82/182 Dissimilar Metal Weld between Low Alloy Steel and 316L Stainless Steel

    Energy Technology Data Exchange (ETDEWEB)

    Hong, Sunghoon; Hong, Jong-Dae; Jang, Changheui [Korea Advanced Institute of Science and Technology, Daejeon (Korea, Republic of); Lee, Kyoung Soo [KHNP-CRI, Daejeon (Korea, Republic of)

    2014-10-15

    Dissimilar metal welds (DMWs) using an Alloy 82/182 are widely used to join low alloy steel components and stainless steel pipes in pressurized water reactors (PWRs). It has been reported that tensile residual stress would be generated within DMWs during the welding processes. It is thought as main reason for primary water stress corrosion cracking (PWSCC) resulting in deterioration of long-term integrity. The application of post weld heat treatment (PWHT) has been considered to reduce the tensile residual stress after welding process. Meanwhile, the PWHT could affect the changes in microstructure, mechanical properties, and corrosion resistance. Therefore, in this study, the effects of PWHT on the microstructure, mechanical properties and corrosion behaviors of base metals of low alloy steel and stainless steel and welding materials of Alloy 82/182 are evaluated. The influence of PWHT in DMW has been investigated. SA 508 and 316L SS exhibited tempered bainite and austenitic grains with a few residual stringer type ferrite. Grain boundary carbides are not precipitated owing to low carbon and insufficient exposure time in 316L SS. The change of mechanicals properties in base metals is not observed. In case of Alloy 182, after PWHT, grain boundaries are covered with film-like continuous Cr-rich carbides.

  4. Influence of alloying elements and nitrogen content on deformation resistance of chromium-nickel stainless steels

    International Nuclear Information System (INIS)

    Four groups of steels with a type Kh20N15 matrix differing in the contents of nitrogen and additional alloying element (Cu, Si, V or Nb) were studied for the influence of the alloying system on deformation resistance in hot rolling. The one-pass rolling was carried out at 900, 1000, 1100 and 1200 deg C with 20, 40 and 60 % reductions. Experimental data statistical processing showed that vanadium alloying results in a sharp increase of nitrogen content influence comparable with strain hardening. The hardening effect in copper- and silicon-containing alloys almost is independent of nitrogen concentration. Niobium-containing alloys lie between two above mentioned groups

  5. Design and identification of high performance steel alloys for structures subjected to underwater impulsive loading

    Science.gov (United States)

    Wei, Xiaoding; Latourte, Felix; Feinberg, Zack; Olson, Gregory; Espinosa, Horacio; Micro; Nanomechanics Laboratory Team; Olson Group Team

    2011-06-01

    To characterize the performance of naval structures, underwater blast experiments have been developed. Martensitic and austenitic steel alloys were designed to optimize the performance of structures subjected to impulsive loads. The deformation and fracture characteristics of the designed steel alloys were investigated experimentally and computationally. The experiments were based on an instrumented fluid structure interaction apparatus, in which deflection profiles were recorded. The computational study was based on a modified Gurson damage model able to accurately describe ductile failure under various loading paths. The model was calibrated for two high performance martensitic steels (HSLA-100 and BA-160) and an austenitic steel (TRIP-120). The martensitic steel (BA-160) was designed to maximize strength and fracture toughness while the austenitic steel (TRIP-120) was designed to maximize uniform ductility. The combined experimental-computational approach provided insight into the relationships between material properties and blast resistance of structures.

  6. 76 FR 45509 - Final Results of Antidumping Duty Changed Circumstances Review: Carbon and Certain Alloy Steel...

    Science.gov (United States)

    2011-07-29

    ... Circumstances Review: Carbon and Certain Alloy Steel Wire Rod from Mexico, 75 FR 67685 (November 3, 2010...) concrete reinforcing bars and rods. Also excluded are (f) free machining steel products (i.e., products... percent or more of bismuth, 0.08 percent or more of sulfur, more than 0.04 percent of phosphorus,...

  7. Friction Stir Lap Welding of Magnesium Alloy to Steel: A Preliminary Investigation

    Science.gov (United States)

    Jana, S.; Hovanski, Y.; Grant, G. J.

    2010-12-01

    An initial study was made to evaluate the feasibility of joining magnesium alloy AZ31 sheet to galvanized steel sheet in a lap configuration using friction stir welding (FSW). Two different automotive sheet steels were used for comparative evaluation of the dissimilar joining potential: a 0.8 mm thick, electrogalvanized (EG) mild steel, and a 1.5 mm thick hot-dipped galvanized (HDG) high-strength, low-alloy (HSLA) steel. These steels were joined to 2.33 mm thick AZ31B magnesium sheet. A single FSW tool design was used for both dissimilar welds, and the process parameters were kept the same. The average peak load for the AZ31-1.5 mm steel weld joint in lap shear mode was found to be 6.3 ± 1.0 kN. For the AZ31-0.8 mm steel weld, joint strength was 5.1 ± 1.5 kN. Microstructural investigation indicates melting of the Zn coating present on the steel sheets, and subsequent alloying with the Mg sheet resulted in the formation of a solidified Zn-Mg alloy layer.

  8. Friction Stir Lap Welding of Magnesium Alloy to Steel: A Preliminary Investigation

    Energy Technology Data Exchange (ETDEWEB)

    Jana, Saumyadeep; Hovanski, Yuri; Grant, Glenn J.

    2010-12-01

    An initial study was made to evaluate the feasibility of joining Magnesium alloy AZ31 sheet to galvanized steel sheet in lap configuration using friction stir welding (FSW). Two different automotive sheet steels were used for comparative evaluation of the dissimilar joining potential; a 0.8mm thick, electro galvanized (EG) mild steel, and a 1.5mm thick hot dipped galvanized (HDG) high-strength, low-alloy steel (HSLA). These steels were joined to 2.33mm thick AZ31B magnesium sheet. A single FSW tool design was used for both dissimilar welds, and process parameters were kept the same. Average peak load for the AZ31-1.5 mm steel weld joint in lap shear mode was found to be 6.3 ± 1.0 kN. For the AZ31-0.8 mm steel weld, joint strength was 5.1 ± 1.5 kN. Microstructural investigation indicates melting of the Zn coating at the interface and subsequent alloying with the Mg sheet resulting in formation of solidified Zn-Mg alloy layer at AZ31/steel interface.

  9. 77 FR 54926 - Certain Seamless Carbon and Alloy Steel; Standard, Line, and Pressure Pipe From Germany

    Science.gov (United States)

    2012-09-06

    ... FR 19711) and determined on July 6, 2012, that it would conduct an expedited review (77 FR 42763... COMMISSION Certain Seamless Carbon and Alloy Steel; Standard, Line, and Pressure Pipe From Germany... steel standard, line, and pressure pipe from Germany would be likely to lead to continuation...

  10. RBF-Type Artificial Neural Network Model Applied in Alloy Design of Steels

    Institute of Scientific and Technical Information of China (English)

    YOU Wei; LIU Ya-xiu; BAI Bing-zhe; FANG Hong-sheng

    2008-01-01

    RBF model, a new type of artificial neural network model was developed to design the content of carbon in low-alloy engineering steels. The errors of the ANN model are. MSE 0. 052 1, MSRE 17. 85%, and VOF 1. 932 9. The results obtained are satisfactory. The method is a powerful aid for designing new steels.

  11. Microstructure and properties of laser surface alloyed PM austenitic stainless steel

    Directory of Open Access Journals (Sweden)

    Z. Brytan

    2010-05-01

    Full Text Available Purpose: The purpose of this paper is to analyse the effect of laser surface alloying with chromium on the microstructural changes and properties of vacuum sintered austenitic stainless steel type AISI 316L (EN 1.4404.Design/methodology/approach: Surface modification of AISI 316L sintered austenitic stainless steel was carried out by laser surface alloying with chromium powder using high power diode laser (HPDL. The influence of laser alloying conditions, both laser beam power (between 0.7 and 2.0 kW and powder feed rate (1.0-4.5 g/min at constant scanning rate of 0.5m/min on the width of alloyed surface layer, penetration depth, microstructure evaluated by LOM, SEM x-ray analysis, surface roughness and microhardness were presented.Findings: The microstructures of Cr laser alloyed surface consist of different zones, starting from the superficial zone rich in alloying powder particles embedded in the surface; these particles protrude from the surface and thus considerably increase the surface roughness. Next is alloyed zone enriched in alloying element where ferrite and austenite coexists. The following transient zone is located between properly alloyed material and the base metal and can be considered as a very narrow HAZ zone. The optimal microstructure homogeneity of Cr alloyed austenitic stainless steel was obtained for powder feed rate of 2.0 and 4.5 g/min and laser beam power of 1.4 kW and 2 kW.Practical implications: Laser surface alloying can be an efficient method of surface layer modification of sintered stainless steel and by this way the surface chromium enrichment can produce microstructural changes affecting mechanical properties.Originality/value: Application of high power diode laser can guarantee uniform heating of treated surface, thus uniform thermal cycle across treated area and uniform penetration depth of chromium alloyed surface layer.

  12. The study of quantitativeness in atom probe analysis of alloying elements in steel

    International Nuclear Information System (INIS)

    The quantitativeness in atom probe analysis of dilute solute alloying elements in steel was systematically investigated. The samples of binary Fe-Si, Fe-Ti, Fe-Cr, Fe-Cu, Fe-Mn and Fe-Mo alloys were prepared for present study. The apparent compositions of alloying elements were examined by three-dimensional atom probe (3DAP) under various experimental conditions. The temperature dependence of the apparent compositions varied largely with the alloys, which indicated that the degree of preferential evaporation or retention varied with the alloying elements. Furthermore, the analysis direction dependence of the apparent Mn composition was examined in the Fe-Mn alloy. The experimental results indicated that the order of the field evaporation rate of elements in steel was Cu>Cr>Mn∼Mo>Fe>Ti∼Si. The field evaporability of alloying elements in steel was discussed in terms of the solution enthalpy of the alloying elements and the phase types of the binary Fe alloys.

  13. Fatigue of carbon and low-alloy steels in LWR environments

    International Nuclear Information System (INIS)

    Fatigue tests have been conducted on A106-Gr B carbon steel and A533-Gr B low-alloy steel to evaluate the effects of an oxygenated-water environment on the fatigue life of these steels. For both steels, environmental effects are modest in PWR water at all strain rates. Fatigue data in oxygenated water confirm the strong dependence of fatigue life on dissolved oxygen (DO) and strain rate. The effect of strain rate on fatigue life saturates at some low value, e.g., between 0.0004 and 0.001%/s in oxygenated water with ∼0.8 ppm DO. The data suggest that the saturation value of strain rate may vary with DO and sulfur content of the steel. Although the cyclic stress-strain and cyclic-hardening behavior of carbon and low-alloy steels is distinctly different, the degradation of fatigue life of these two steels with comparable sulfur levels is similar. The carbon steel exhibits pronounced dynamic strain aging, whereas strain-aging effects are modest in the low-alloy steel. Environmental effects on nucleation of fatigue crack have also been investigated. The results suggest that the high-temperature oxygenated water has little or no effect on crack nucleation

  14. Role of alloying elements and carbides in the chlorine-induced corrosion of steels and alloys

    Directory of Open Access Journals (Sweden)

    Hans Jürgen Grabke

    2004-03-01

    Full Text Available The high temperature corrosion of steels and Ni-base alloys in oxidizing and chloridizing environments is of practical interest in relation to problems in waste incineration plants and power plants using Cl containing fuels. The behaviour of the most important alloying elements Fe, Cr, Ni, Mo, Mn, Si, Al upon corrosion in an oxidizing and chloridizing atmosphere was elucidated: the reactions and kinetics can be largely understood on the base of thermodynamic data, i.e. free energy of chloride formation, vapor pressure of the chlorides and oxygen pressure pO2 needed for the conversion chlorides -> oxides. The mechanism is described by 'active oxidation', comprising inward penetration of chlorine into the scale, formation of chlorides at the oxide/metal interface, evaporation of the chlorides and conversion of the evaporating chlorides into oxides, which occurs in more or less distance from the surface (depending on pO2. This process leads to loose, fragile, multilayered oxides which are unprotective (therefore: active oxidation. Fe and Cr are rapidly transferred into such scale, Ni and Mo are relatively resistant. In many cases, the grain boundaries of the materials are strongly attacked, this is due to a susceptibility of chromium carbides to chloridation. In contrast the carbides Mo2C, TiC and NbC are less attacked than the matrix. Alloys on the basis Fe-Cr-Si proved to be rather resistant, and the alloying elements Ni and Mo clearly retard the attack in an oxidizing and chloridizing environment.

  15. Interfacial characterization of resistance spot welded joint of steel and aluminum alloy

    Institute of Scientific and Technical Information of China (English)

    Zhang Weihua; Sun Daqian; Yin Shiqiang; Han Lijun; Qiu Xiaoming; Chen Qinglei

    2010-01-01

    The dissimilar material resistance spot welding of galvanized high strength steel and aluminum alloy had been conducted. The welded joint exhibited a thin reaction layer composed of Fe2Al5 and Fe4Al13 phases at steel/aluminum interface. The welded joint presented a tensile shear load of 3.3 kN with an aluminum alloy nugget diameter of 5.7 ram. The interfucial failure mode was observed for the tensile shear specimen and fracture occurred at reaction layer and aluminum alloy fusion zone beside the interface. The reaction layer with compounds was the main reason for reduction of the welded joint mechanical property.

  16. Sintered stainless steel surface alloyed with Si3N4 powder

    OpenAIRE

    L.A. Dobrzański; Z. Brytan; W. Pakieła

    2011-01-01

    Purpose: The goal of this study was to investigate effects of laser surface alloying with Si3N4 powder on the microstructural changes and properties of vacuum sintered stainless steels, both austenitic X2CrNi17-12-2, ferritic X6Cr13 and duplex X2CrNiMo22-8-2.Design/methodology/approach: High power diode laser (HPDL) was applied to surface modification of sintered stainless steels with Si3N4 powder. The influence of laser alloying conditions on the width, penetration depth of alloyed surface l...

  17. Fatigue failure of micro-alloyed 23MnB4 steel

    Directory of Open Access Journals (Sweden)

    S. Rusz

    2008-12-01

    Full Text Available Purpose: In the following paper there have been the structure and fatigue properties of micro-alloyed 23MnB4 steel in initial state and after heat treatment evaluated.Design/methodology/approach: Fatigue test of micro-alloyed 23MnB4 steel was completed by metallographic and fracture analyses. For scope the methods of the light microscopy and SEM were used.Findings: Microstructure of examined alloy in initial state was characterized mostly by fine ferrite with pearlitic net and in state after heat treatment was formed by martensite or partly by bainite and after tempering was formed by tempered martensite. Objective of this work consisted in determination of fatigue characteristics of micro-alloyed 23MnB4 steel, including fracture analyze. Results of fatigue testing at various stress levels for the samples in initial state and after the heat treatment have confirmed that obtained values of cycles to rupture were at least 585 000 cycles. Change of fatigue properties in dependence on heat treatment of the used steel.Research limitations/implications: For define fracture area a samples must be provide with notch. The experiment was limited by occurrence a void in cast alloys.Practical implications: The results may be utilized for application of the investigated material in process of manufacturing.Originality/value: These results contribute to explanation of fracture mechanism of micro-alloyed 23MnB4 steel.

  18. The application limits of alloyed 13%Cr tubular steels for downhole duties

    Energy Technology Data Exchange (ETDEWEB)

    Cooling, P.J.; Kennani, M.B.; Martin, J.W. [BP Exploration, Sunbury on Thames (United Kingdom); Nice, P.I. [Statoil, Stavanger (Norway)

    1998-12-31

    In the past few years, a new family of materials has entered the downhole tubular market, known as the ``alloyed 13%Cr steels.`` These are a development of the conventional API 5CT grade 13%Cr steels to which alloying elements of Ni, Mo and Cu have been added, hence offering a number of advantages. In the present paper, domains of application for the 95ksi grade alloyed 13%Cr steels with respect to sour service conditions have been defined on pH vs. H{sub 2}S partial pressure plots. Corrosion properties have also been determined for two other aspects; chloride stress corrosion cracking (ClSCC) and high temperature corrosion resistance. The results have reiterated the importance of solution chemistry, pH and H{sub 2}S partial pressure in defining the corrosion properties of steels.

  19. Parameters Optimization of Low Carbon Low Alloy Steel Annealing Process

    Institute of Scientific and Technical Information of China (English)

    Maoyu ZHAO; Qianwang CHEN

    2013-01-01

    A suitable match of annealing process parameters is critical for obtaining the fine microstructure of material.Low carbon low alloy steel (20CrMnTi) was heated for various durations near Ac temperature to obtain fine pearlite and ferrite grains.Annealing temperature and time were used as independent variables,and material property data were acquired by orthogonal experiment design under intercritical process followed by subcritical annealing process (IPSAP).The weights of plasticity (hardness,yield strength,section shrinkage and elongation) of annealed material were calculated by analytic hierarchy process,and then the process parameters were optimized by the grey theory system.The results observed by SEM images show that microstructure of optimization annealing material are consisted of smaller lamellar pearlites (ferrite-cementite)and refining ferrites which distribute uniformly.Morphologies on tension fracture surface of optimized annealing material indicate that the numbers of dimple fracture show more finer toughness obviously comparing with other annealing materials.Moreover,the yield strength value of optimization annealing material decreases apparently by tensile test.Thus,the new optimized strategy is accurate and feasible.

  20. Effect of Alloy 625 Buffer Layer on Hardfacing of Modified 9Cr-1Mo Steel Using Nickel Base Hardfacing Alloy

    Science.gov (United States)

    Chakraborty, Gopa; Das, C. R.; Albert, S. K.; Bhaduri, A. K.; Murugesan, S.; Dasgupta, Arup

    2016-04-01

    Dashpot piston, made up of modified 9Cr-1Mo steel, is a part of diverse safety rod used for safe shutdown of a nuclear reactor. This component was hardfaced using nickel base AWS ER NiCr-B alloy and extensive cracking was experienced during direct deposition of this alloy on dashpot piston. Cracking reduced considerably and the component was successfully hardfaced by application of Inconel 625 as buffer layer prior to hardface deposition. Hence, a separate study was undertaken to investigate the role of buffer layer in reducing the cracking and on the microstructure of the hardfaced deposit. Results indicate that in the direct deposition of hardfacing alloy on modified 9Cr-1Mo steel, both heat-affected zone (HAZ) formed and the deposit layer are hard making the thickness of the hard layer formed equal to combined thickness of both HAZ and deposit. This hard layer is unable to absorb thermal stresses resulting in the cracking of the deposit. By providing a buffer layer of Alloy 625 followed by a post-weld heat treatment, HAZ formed in the modified 9Cr-1Mo steel is effectively tempered, and HAZ formed during the subsequent deposition of the hardfacing alloy over the Alloy 625 buffer layer is almost completely confined to Alloy 625, which does not harden. This reduces the cracking susceptibility of the deposit. Further, unlike in the case of direct deposition on modified 9Cr-1Mo steel, dilution of the deposit by Ni-base buffer layer does not alter the hardness of the deposit and desired hardness on the deposit surface could be achieved even with lower thickness of the deposit. This gives an option for reducing the recommended thickness of the deposit, which can also reduce the risk of cracking.

  1. Sulfide Stress Corrosion Cracking Resistance of Modified ASTM A694 F60 Low Alloy Steel for Subsea Applications

    OpenAIRE

    Stridsklev, Camilla A

    2013-01-01

    The resistance to sulfide stress corrosion cracking (SSC) of modified ASTM A694 F60 low alloy steel, produced by two different manufacturers, was studied by four-point bend-testing. The two materials are named material A and material B in this report. Both materials were tested in two different environments with different severity, one ?sweet-transition region? test and one ?sour service? test. The test conditions were controlled by the H2S partial pressure (pH2S) and pH. These parameters wer...

  2. Structure and properties of a layered steel/vanadium alloy/steel composite prepared by high-pressure torsion

    Science.gov (United States)

    Nikulin, S. A.; Rogachev, S. O.; Rozhnov, A. B.; Khatkevich, V. M.; Nechaikina, T. A.; Morozov, M. V.

    2016-04-01

    The microstructure and hardness of a layered steel 08Kh17T/V-10Ti-5Cr/steel 08Kh17T composite, which was prepared by torsion under a high hydrostatic pressure at temperatures of 20, 200, and 400°C, have been studied. Severe plastic deformation under used conditions is shown to provide good joining of layers, which is accompanied by their substantial hardening (from 2.0 to 3.5 times). During deformation at temperatures of 20 and 200°C, fragmentation of the vanadium alloy layer into thinner layers is observed; at 400°C, mainly a plane interface between the vanadium alloy and the steel layers is formed.

  3. Study of austenitic stainless steel welded with low alloy steel filler metal. [tensile and impact strength tests

    Science.gov (United States)

    Burns, F. A.; Dyke, R. A., Jr.

    1979-01-01

    The tensile and impact strength properties of 316L stainless steel plate welded with low alloy steel filler metal were determined. Tests were conducted at room temperature and -100 F on standard test specimens machined from as-welded panels of various chemical compositions. No significant differences were found as the result of variations in percentage chemical composition on the impact and tensile test results. The weldments containing lower chromium and nickel as the result of dilution of parent metal from the use of the low alloy steel filler metal corroded more severely in a marine environment. The use of a protective finish, i.e., a nitrile-based paint containing aluminum powder, prevented the corrosive attack.

  4. Laser Alloyed Coatings of TiB2/Graphite on 9Cr18 Stainless Steel Surface

    Institute of Scientific and Technical Information of China (English)

    YING Li-xia; WANG Li-qin; JIA Xiao-mei; GU Le

    2007-01-01

    Modified coatings including carbide of iron, nickel, chromium, silicon, and titanium are obtained on 9Cr18 stainless steel surface by laser alloying. The processing method, the microstructure, the interface, the tribological properties, and the forming mechanisms of the coatings are analyzed. The results show that the microstructure of the alloyed coatings is mainly irregular FeC crystals. Carbides of chromium and iron are around the FeC crystals. Small granular TiC disperses in the alloyed coatings. The microhardness of the alloyed coatings is greatly improved because of the occurrence of carbide with high hardness. At the same time, the wear resistance of the alloyed coatings are higher than that of 9Cr18 stainless steel.

  5. Study of the Metallurgical Aspects of Steel Micro-Alloying by Titan

    Directory of Open Access Journals (Sweden)

    Kijac, J.

    2006-01-01

    Full Text Available The metal properties upgrading applying it’s alloying with the simultaneous limitation of the impurities represents a prospective possibility of the metallurgical production further development. The interaction of the alloying substance active element with oxygen in metal and adjacent multiphase environment occurs under the actual conditions. Present paper is oriented particularly to the thermodynamic aspects of deoxygenation by titan in process of production of micro alloyed low carbon steel in two plants (oxygen converter 1-OC1 and 2-OC2 with the different effect of micro-alloy exploitation. Analysis of the effect of the metallurgical factors on the titan smelting loss in micro-alloyed steel production points at the need to master the metal preparation for the alloying and especially has got the decisive effect upon the oxidizing ability and rate of the slag phase availability. When comparing the micro-alloying matter yield among the individual production units, disclosed have been better results obtained in plant OC 2. Confirmed has been the effect of the slag amount (average amount of 7,3 t at OC 1 and 5,83 t at OC 2 and its quality during the steel tapping as one among the most significant factors affecting the alloying process and which also represent its oxidizing potential.

  6. Short-term exposure of low-alloyed steels in Qinghai Salt Lake atmosphere

    Institute of Scientific and Technical Information of China (English)

    LI QiaoXia; WANG ZhenYao; HAN Wei; YU GuoCai; HAN EnHou

    2009-01-01

    The rusts formed on carbon steel and weathering steel exposed in Oinghai Salt Lake atmosphere for 6 months were characterized by X-ray diffraction (XRD), infrared transmission spectroscopy (IRS), scanning electron microscopy (SEM), electron probe micro analyzer (EPMA) and electrochemical polarization techniques. The two kinds of steels showed the similar corrosion rate, corrosion product composition and electrochemical polarization behavior. Their rusts were mainly composed of β-FeOOH, Fe_8(O,OH)_(16)Cl_(1.3) and a little γ-FeOOH. Cl~- played an important role during the corrosion process of low-alloyed steels. The alloyed elements Cr, Ni and Cu in weathering steel were detected in the rusts; however, they showed no remarkable protective ability.

  7. Influence of Trace Alloying Elements on Corrosive Resistance of Cast Stainless Steel

    Institute of Scientific and Technical Information of China (English)

    DUAN Han-qiao; YAN Xiang; WEI Bo-kang; LIN Han-tong

    2005-01-01

    The influences of trace alloying elements niobium, vanadium and zirconium on the corrosive resistance of 18-8 type cast stainless steel have been studied in deta() orthogonal design experiments. The results show that zirconium is mainly in the form of compound inclusions, which is unfavorable to promote the corrosive resistance of the cast stainless steel. It can alleviate the disadvantageous influence of carbon addition on corrosive resistance when some elements such as vanadium and niobium exist in the steel, and niobium has a remarkable influence on the intergranular corrosive resistance but unobvious on the pitting corrosion, and vanadium has a slightly favorable influence on the corrosive resistance of the steel.

  8. High Carbon Alloy Steels with Multiple Types of Ultra-fine Carbides and Their Characteristics

    Institute of Scientific and Technical Information of China (English)

    MA Yong-qing; GAO Hong-tao; QI Yu-hong; ZHANG Zhan-ping; DAI Yu-mei; LIU Yan-xia

    2004-01-01

    Under normal forging and annealing conditions, there are different ultra fine carbides (M3C, M23C6, M7C3, M6C and MC) in high carbon alloy steels when alloy composition design is carried out properly. On the basis of carbides transformation orderliness, the alloy composition design of the high carbon alloy steels is conducted by phase-equilibrium thermodynamic calculation for Fe-Cr-W-Mo-V-C system. The nucleation and growth of new carbides, dissolution of previous partial carbides in these steels during annealing process, all these lead to ultra-fine distribution of carbides. Due to different crystal structures of carbides and different thermodynamics as well dynamics parameters of the carbides dissolution and precipitation, the range of quenching temperature of these steels is widened, and the good temper-resistance is obtained. The characteristics of heat treatment process and microstructure variance, and the carbides transformation for different temperature are explained by the phase-equilibrium component satisfactorily. Their bend and yield strength,flexibility and toughness all are advanced markedly comparing with that of kindred steels. Results of the applications have proved that the microstructure of ultra-fine carbides in these steels played importance roles in the enhancement of edginess and fatigue crack resistance of the die and knives.

  9. Effects of Nitrogen Content and Austenitization Temperature on Precipitation in Niobium Micro-alloyed Steels

    Institute of Scientific and Technical Information of China (English)

    Lei CAO; Zhong-min YANG; Ying CHEN; Hui-min WANG; Xiao-li ZHAO

    2015-01-01

    The influences of nitrogen content and austenitization temperature on Nb(C,N)precipitation in niobium micro-alloyed steels were studied by different methods:optical microscopy,tensile tests,scanning electron mi-croscopy,transmission electron microscopy,physicochemical phase analysis,and small-angle X-ray scattering. The results show that the strength of the steel with high nitrogen content is slightly higher than that of the steel with low nitrogen content.The increase in the nitrogen content does not result in the increase in the amount of Nb(C,N) precipitates,which mainly depends on the niobium content in the steel.The mass fraction of small-sized Nb(C,N) precipitates (1-10 nm)in the steel with high nitrogen content is less than that in the steel with low nitrogen con-tent.After austenitized at 1 150 ℃,a number of large cuboidal and needle-shaped particles are detected in the steel with high nitrogen content,whereas they dissolve after austenitized at 1 200 ℃ and the Nb(C,N)precipitates become finer in both steels.Furthermore,the results also show that part of the nitrogen in steel involves the formation of al-loyed cementite.

  10. One-Step Quenching and Partitioning Heat Treatment of Medium Carbon Low Alloy Steel

    Science.gov (United States)

    Tariq, Fawad; Baloch, Rasheed Ahmed

    2014-05-01

    This paper presents the results of novel one-step quenching and partitioning (Q&P) heat treatment conducted on medium carbon low alloy steel sheet. Samples were austenitised at 1193 K followed by interrupted quenching at 473 K for different partitioning times and finally they were quenched in water. Dilatometry was employed for selection of treatment temperatures. Optical and scanning electron microscopy was carried out to examine the microstructural changes. Volume fraction of retained austenite was measured by x-ray diffraction technique. Resulting microstructures were correlated with the mechanical properties such hardness, tensile strength, elongation, impact absorbed energy, etc. The notch tensile and fracture toughness properties of Q&P steels are still lacking therefore notch tensile strength and plain strain fracture toughness tests were conducted and results are reported here. Results of Q&P treatments were also compared with the properties obtained by conventional Quenching and Tempering (Q&T) and normalizing treatments. Optimum strength-ductility balance of about 2000 MPa tensile strength with 11% elongation was achieved in samples quenched at 473 K and isothermally partitioned for 100 s. Higher ductility of Q&P steel was attributed to the presence of 6.8% film-type interlath retained austenite. Fine-grained martensitic structure with high density of interphase boundaries imparted ultrahigh strength. It was further noted that the impact toughness, notch tensile strength and fracture toughness of 1000 s partitioned samples was higher than 100 s partitioned samples. Possible reasons for high toughness are synergetic effect of recovery of dislocations, partial loss of martensite tetragonality and precipitation of fine transition carbides.

  11. Laser surface alloying of sintered stainless steels with SiC powder

    Directory of Open Access Journals (Sweden)

    Z. Brytan

    2011-07-01

    Full Text Available Purpose: The goal of this study is to investigate effects of laser surface alloying with SiC powder on microstructural changes and properties of vacuum sintered austenitic X2CrNiMo17-12-2, ferritic X6Cr13 and duplex X2CrNiMo22-8-2 stainless steels.Design/methodology/approach: Surface modification of sintered stainless steels was carried out by laser surface alloying with SiC powder using high power diode laser (HPDL. The influence of laser alloying conditions, the laser beam power (between 0.7 and 2.1 kW at constant scanning rate on the width of alloyed surface layer and penetration depth were studied. The resulting microstructure in laser alloyed surface layer was examined using light and scanning electron microscopy. Phase composition was determined by the X-ray diffraction method. The microhardness results of modified surface layer were also studied.Findings: The alloyed surface layer has a fine dendritic microstructure with iron-chromium carbides precipitations. The surface layer was enriched in silicon and carbon that produced microstructural changes and resulting microhardness increase. Beside studied stainless steels the duplex one revealed highest hardening effect by laser alloying with SiC powder, where related microhardness was about 500-600 HV.Practical implications: Laser surface alloying with SiC powder can be an efficient method of surface layer hardening of sintered stainless steels and produce significant improvement of surface layer properties in terms of hardness and wear resistance.Originality/value: Application of high power diode laser can guarantee uniform heating of treated surface, thus uniform thermal cycle across processed area and uniform penetration depth of alloyed surface layer.

  12. 77 FR 21968 - Seamless Carbon and Alloy Steel Standard, Line, and Pressure Pipe From the People's Republic of...

    Science.gov (United States)

    2012-04-12

    ... International Trade Administration Seamless Carbon and Alloy Steel Standard, Line, and Pressure Pipe From the... countervailing duty order on seamless carbon and alloy steel standard, line, and pressure pipe from the People's... Antidumping and Countervailing Duty Administrative Reviews and Request for Revocation in Part, 76 FR...

  13. 75 FR 29972 - Certain Seamless Carbon and Alloy Steel Standard, Line, and Pressure Pipe from the People's...

    Science.gov (United States)

    2010-05-28

    ... Determination, 75 FR 22372 (April 28, 2010) (``Preliminary Determination''). On May 3, 2010, Tianjin Pipe (Group... International Trade Administration Certain Seamless Carbon and Alloy Steel Standard, Line, and Pressure Pipe... antidumping duty investigation of certain seamless carbon and alloy steel standard, line, and pressure...

  14. 75 FR 6183 - Certain Seamless Carbon and Alloy Steel Standard, Line, and Pressure Pipe from the People's...

    Science.gov (United States)

    2010-02-08

    ... investigation on certain seamless carbon and alloy steel standard, line, and pressure pipe from the People's Republic of China. See Certain Seamless Carbon and Alloy Steel Standard, Line, and Pressure Pipe From the People's Republic of China: Initiation of Antidumping Duty Investigation, 74 FR 52744 (October 14,...

  15. 75 FR 57449 - Certain Seamless Carbon and Alloy Steel Standard, Line, and Pressure Pipe from the People's...

    Science.gov (United States)

    2010-09-21

    ... International Trade Administration Certain Seamless Carbon and Alloy Steel Standard, Line, and Pressure Pipe... determined that certain seamless carbon and alloy steel standard, line, and pressure pipe from the People's..., in Part, and Postponement of Final Determination, 75 FR 22372 (April 28, 2010)...

  16. 75 FR 34980 - Circular Welded Non-Alloy Steel Pipe from the Republic of Korea: Final Results of the Antidumping...

    Science.gov (United States)

    2010-06-21

    ... Welded Non-Alloy Steel Pipe and Tube From Brazil, the Republic of Korea, Mexico, and Venezuela, 61 FR... Sales at Less Than Fair Value: Certain Circular Welded Non-Alloy Steel Pipe from Korea, 57 FR 49453... Korea: Preliminary Results and Rescission in Part of the Antidumping Duty Administrative Review, 74...

  17. 76 FR 36089 - Circular Welded Non-Alloy Steel Pipe From the Republic of Korea: Final Results of the Antidumping...

    Science.gov (United States)

    2011-06-21

    ... Welded Non-Alloy Steel Pipe and Tube From Brazil, the Republic of Korea, Mexico, and Venezuela, 61 FR... Welded Non-Alloy Steel Pipe from Korea, 57 FR 49453 (November 2, 1992). These deposit requirements shall... Republic of Korea: Preliminary Results of the Antidumping Duty Administrative ] Review, 75 FR...

  18. 76 FR 49437 - Certain Circular Welded Non-Alloy Steel Pipe From Mexico: Preliminary Results of Antidumping Duty...

    Science.gov (United States)

    2011-08-10

    ... Circumstances Review: Certain Circular Welded Non-Alloy Steel Pipe From Mexico, 75 FR 82374 (December 30, 2010... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF COMMERCE International Trade Administration Certain Circular Welded Non-Alloy Steel Pipe From Mexico: Preliminary...

  19. 77 FR 73617 - Certain Circular Welded Non-Alloy Steel Pipe From Mexico: Preliminary Results and Partial...

    Science.gov (United States)

    2012-12-11

    ... Value: Circular Welded Non-Alloy Steel Pipe From Mexico, 57 FR 42953 (September 17, 1992). Notification... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF COMMERCE International Trade Administration Certain Circular Welded Non-Alloy Steel Pipe From Mexico: Preliminary...

  20. 78 FR 79664 - Certain Circular Welded Non-Alloy Steel Pipe From Mexico: Final Results of the 2011-2012...

    Science.gov (United States)

    2013-12-31

    ... Than Fair Value: Circular Welded Non-Alloy Steel Pipe From Mexico, 57 FR 42953 (September 17, 1992... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF COMMERCE International Trade Administration Certain Circular Welded Non-Alloy Steel Pipe From Mexico: Final Results...

  1. 78 FR 28190 - Carbon and Certain Alloy Steel Wire Rod From Mexico: Final Results of Antidumping Duty...

    Science.gov (United States)

    2013-05-14

    ... Certain Alloy Steel Wire Rod From Mexico, 67 FR 55800 (August 30, 2002). Notification to Importers This... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF COMMERCE International Trade Administration Carbon and Certain Alloy Steel Wire Rod From Mexico: Final Results...

  2. 76 FR 66899 - Certain Circular Welded Non-Alloy Steel Pipe From Brazil, Mexico, the Republic of Korea, and...

    Science.gov (United States)

    2011-10-28

    ...-Alloy Steel Pipe and Tube from Mexico, 74 FR 41681 (August 18, 2009). \\3\\ The Department found that Yieh... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF COMMERCE International Trade Administration Certain Circular Welded Non-Alloy Steel Pipe From Brazil, Mexico,...

  3. 77 FR 13545 - Carbon and Certain Alloy Steel Wire Rod From Mexico: Notice of Final Results of Antidumping Duty...

    Science.gov (United States)

    2012-03-07

    ... Changed Circumstances Review: Carbon and Certain Alloy Steel Wire Rod from Mexico, 76 FR 45509 (July 29... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF COMMERCE International Trade Administration Carbon and Certain Alloy Steel Wire Rod From Mexico: Notice of Final...

  4. 46 CFR 54.25-15 - Low temperature operation-high alloy steels (modifies UHA-23(b) and UHA-51).

    Science.gov (United States)

    2010-10-01

    ... (incorporated by reference; see 46 CFR 54.01-1) for service temperatures below −425 °F., UHA-51(b)(1) through (5... 46 Shipping 2 2010-10-01 2010-10-01 false Low temperature operation-high alloy steels (modifies....25-15 Low temperature operation—high alloy steels (modifies UHA-23(b) and UHA-51). (a)...

  5. Alloy element redistribution during sintering of powder metallurgy steels

    OpenAIRE

    Tahir, Abdul Malik

    2014-01-01

    Homogenization of alloying elements is desired during sintering of powder metallurgy components. The redistribution processes such as penetration of liquid phase into the interparticle/grain boundaries of solid particles and subsequent solid-state  diffusion of alloy element(s) in the base powder, are important for the effective homogenization of alloy element(s) during liquid phase sintering of the mixed powders. The aim of this study is to increase the understanding of alloy element redistr...

  6. Structural models for amorphous transition metal binary alloys

    International Nuclear Information System (INIS)

    A dense random packing of 445 hard spheres with two different diameters in a concentration ratio of 3 : 1 was hand-built to simulate the structure of amorphous transition metal-metalloid alloys. By introducing appropriate pair potentials of the Lennard-Jones type, the structure is dynamically relaxed by minimizing the total energy. The radial distribution functions (RDF) for amorphous Fe0.75P0.25, Ni0.75P0.25, Co0.75P0.25 are obtained and compared with the experimental data. The calculated RDF's are resolved into their partial components. The results indicate that such dynamically constructed models are capable of accounting for some subtle features in the RDF of amorphous transition metal-metalloid alloys

  7. Ultrasonic Spot Welding of Aluminum to High-Strength Low-Alloy Steel: Microstructure, Tensile and Fatigue Properties

    Science.gov (United States)

    Patel, V. K.; Bhole, S. D.; Chen, D. L.

    2014-04-01

    The structural applications of lightweight aluminum alloys inevitably involve dissimilar welding with steels and the related durability issues. This study was aimed at evaluating the microstructural change, lap shear tensile load, and fatigue resistance of dissimilar ultrasonic spot-welded joints of aluminum-to-galvanized high-strength low-alloy (HSLA) steel. Two non-uniform layers were identified in between Al and HSLA steel via SEM/EDS and XRD. One was an Al-Zn eutectic layer and the other was a thin (<2 μm) layer of intermetallic compound (IMC) of Al and Fe in the nugget zone. The lap shear tensile testing gave a maximum load of 3.7 kN and the sample failed initially in between the Al-Zn eutectic film and Al-Fe IMC, and afterward from the region containing Al on both matching fracture surfaces. The fatigue test results showed a fatigue limit of about 0.5 kN (at 1 × 107 cycles). The maximum cyclic stress at which transition of the fatigue fracture from transverse through-thickness crack growth mode to the interfacial failure mode occurs increases with increasing energy input.

  8. Mechanics property Study for Interface Bim Composite of Zinc Alloy ZAS35/Carbon Steel

    Institute of Scientific and Technical Information of China (English)

    陈基勇; 耿浩然; 杨爱玲

    2002-01-01

    The distortional fields of interface-U-field and V-field-have been obtained after the mechanics property for the geometric distortion of interface of cracked zinc alloy ZAS35/carbon steel is analyzed by means of a laser moire interferometry. The optimum cast preheating temperature has been decided in the light of the experiment of shear strength. After the microstructure of interface of bimetal composite of zinc alloy ZAS35/carbon steel is analyzed and studied with a X ray diffraction and an electronic scanning mirror (ESM), the phase component of metallurgical bond of interface of zinc alloy ZAS35/carbon steel has been gained, and the results of interface scan of distribution of elements Fe/Zn have been obtained with the dip coating temperature of 700(C. The above working theory, the experimental technology and its results will be introduced in this paper, and its results will be analyzed.

  9. Bonding evolution with sintering temperature in low alloyed steels with chromium

    Directory of Open Access Journals (Sweden)

    Fuentes-Pacheco L.

    2009-01-01

    Full Text Available At present, high performance PM steels for automotive applications follow a processing route that comprises die compaction of water-atomized powder, followed by sintering and secondary treatments, and finishing operations. This study examines Cr-alloyed sintered steels with two level of alloying. In chromium-alloyed steels, the surface oxide on the powder is of critical importance for developing the bonding between the particles during sintering. Reduction of this oxide depends mainly on three factors: temperature, dew point of the atmosphere, and carbothermic reduction provided by the added graphite. The transformation of the initial surface oxide evolves sequence as temperature increases during sintering, depending on the oxide composition. Carbothermic reduction is supposed to be the controlling mechanism, even when sintering in hydrogen-containing atmospheres. The effect of carbothermic reduction can be monitored by investigating the behavior of the specimens under tensile testing, and studying the resultant fracture surfaces.

  10. Fracture performance of high strength steels, aluminium and magnesium alloys during plastic deformation

    Directory of Open Access Journals (Sweden)

    Yu Haiyan

    2015-01-01

    Full Text Available A series of uniaxial tension tests were performed for 5052 and 6061 aluminum alloys, AZ31B magnesium alloy, TRIP600 and DP600 steels, to obtain a better understanding of their fracture performance. Scanning electron microscope (SEM observation of the microstructure evolution was conducted. The dimple structure, orientation relationship between the fracture surface and tensile direction, necking behavior were analyzed. The fracture mechanism and fracture mode of each material was discussed in detail. The results show that TRIP600 steel is subject to a typical inter-granular ductile fracture combined by shear fracture. DP600 steel belongs to mainly ductility mixed with normal fracture. Both 5052 and 6061 aluminum alloys are subject to a mixed ductility fracture and brittle fracture. AA5052 and AA6061 belong to a typical shear fracture and a normal fracture, respectively. Magnesium AZ31B is typical of a brittle fracture combined with normal fracture.

  11. Characterization of Rust Layer Formed on Low Alloy Steel Exposed in Marine Atmosphere

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    The iron rust phases formed on Iow alloy steels containing different quantities of Cr element have been characterizedusing EPMA, Raman spectroscopy, TEM, optical microscopy etc. The ion selective properties of synthesized rust filmswith the same phase constituent as the atmospheric corrosion products were investigated using self-made apparatus.The results showed that corrosion loss of steels exposed in marine atmosphere decreased rapidly as the Cr contentof the steel was increased. Cr-containing steels were covered by a uniform compacted rust layer composed of fineparticles with an average diameter of several nanometers. Inner rust layer of Cr-containing steel (2 mass fraction)was composed of α-CrxFel-xOOH, with Cr content of about 5 mass fraction. Such rust layer showed cation selectiveproperty, and could depress the penetration of Cl- to contact substrate steel directly.

  12. Load carrying capacity of RCC beams by replacing steel reinforcement bars with shape memory alloy bars

    Science.gov (United States)

    Bajoria, Kamal M.; Kaduskar, Shreya S.

    2016-04-01

    In this paper the structural behavior of reinforced concrete (RC) beams with smart rebars under two point loading system has been numerically studied, using Finite Element Method. The material used in this study is Super-elastic Shape Memory Alloys (SE SMAs) which contains nickel and titanium. In this study, different quantities of steel and SMA rebars have been used for reinforcement and the behavior of these models under two point bending loading system is studied. A comparison of load carrying capacity for the model between steel reinforced concrete beam and the beam reinforced with S.M.A and steel are performed. The results show that RC beams reinforced with combination of shape memory alloy and steel show better performance.

  13. Fine structures in Fe3Al alloy layer of a new hot dip aluminized steel

    Indian Academy of Sciences (India)

    Li Yajiang; Wang Juan; Zhang Yonglan; X Holly

    2002-12-01

    The fine structure in the Fe–Al alloy layer of a new hot dip aluminized steel (HDA) was examined by means of X-ray diffractometry (XRD), electron diffraction technique, etc. The test results indicated that the Fe–Al alloy layer of the new aluminized steel mainly composed of Fe3Al, FeAl and -Fe (Al) solid solution. There was no brittle phase containing higher aluminum content, such as FeAl3 (59.18% Al) and Fe2Al7 (62.93% Al). The tiny cracks and embrittlement, formerly caused by these brittle phases in the conventional aluminum-coated steel, were effectively eliminated. There was no microscopic defect (such as tiny cracks, pores or loose layer) in the coating. This is favourable to resist high temperature oxidation and corrosion of the aluminized steel.

  14. Erosion Resistance Behaviours of H13 Steel to Molten ADC12 Alloy

    Institute of Scientific and Technical Information of China (English)

    MIN Yong-an; XU Luo-ping; WU Xiao-chun; LI Lin; WANG Rong

    2004-01-01

    H13 hot work steel samples and surface water vapor oxidized H13 samples were immersed into molten ADC12alloy under static resting or dynamic rotating conditions. Weigh-losing method was used to discover the influences of temperature, time and surface conditions on the erosion resistance of H13 steel. The interfaces between the steel and the molten alloy were studied with optical microscopy to compare the different erosion resistance behaviours. The results show that the composite layer outside of the compounds layers changes obviously with increasing temperature, lasting time or sample movement. The better erosion resistance of H13 steel can be endowed with the oxide films, which would gradually decrease along with the dissolve of the films.

  15. Effect of thermal aging to microstructure of the interface of low alloy Steel and Ni-based alloy filler metal of dissimilar weld metal

    Energy Technology Data Exchange (ETDEWEB)

    Choi, Kyoung Joon; Shin, Sang Hoon; Kim, Jong Jin; Choi, Sang Il; Kim, Ji Hyun [Ulsan National Institute of Science and Technology, Ulsan (Korea, Republic of)

    2012-10-15

    Dissimilar Metal Welds (DMWs) is generally applied to nuclear power plants for manufacturing and machining in structural components such as reactor pressure vessels and pressurizer nozzles. Alloy 152 is used frequently as filler metal in the manufacture of the DMW in light water reactors to join the low alloy steel pressure vessel nozzles and steam generator nozzles to nickel-based wrought alloy or austenitic stainless steel components. However, in recent years cracking phenomena has been observed in the welded joints. Additionally, the number of long-term aged nuclear power plants is increasing. Concerns have been raised to the integrity and reliability in the joint transition zone due to the high susceptibility of the heat affected zone (HAZ) and the fusion boundary (FB) to stress corrosion cracking in combination with thermal aging. Since the material microstructure and chemical composition are key parameters affecting the stress corrosion cracking, improving the understanding of stress corrosion cracking at the FB region requires fundamental understanding of the unique microstructure of the FB region in DMW. Despite the potential degradation and consequent risk in the DMW, there is still a lack of the fundamental understanding of microstructure in the FB region, in particular the region containing unidentified band structures near the FB. As the life of nuclear power plants becomes long cycle, concerns have been raised to the integrity and reliability in the region after getting thermal aging effect. The long term exposure of this kind of material could experience the thermal aging which can form the chromium carbides near the FB by promoting the diffusion of C content at the service temperature. Therefore, the current study is aiming at the investigation of the thermal effect on the interface between Alloy 152 filler metal and A533 Gr. B. The used tools are Vickers hardness tester and Scanning Electron Microscope (SEM)

  16. Microstructure and corrosion behavior of shielded metal arc-welded dissimilar joints comprising duplex stainless steel and low alloy steel

    Science.gov (United States)

    Srinivasan, P. Bala; Muthupandi, V.; Sivan, V.; Srinivasan, P. Bala; Dietzel, W.

    2006-12-01

    This work describes the results of an investigation on a dissimilar weld joint comprising a boiler-grade low alloy steel and duplex stainless steel (DSS). Welds produced by shielded metal arc-welding with two different electrodes (an austenitic and a duplex grade) were examined for their microstructural features and properties. The welds were found to have overmatching mechanical properties. Although the general corrosion resistance of the weld metals was good, their pitting resistance was found to be inferior when compared with the DSS base material.

  17. Tribological Properties of WS2 Nanoparticles Lubricants on Aluminum-Silicon Alloy and Carbon Steels

    OpenAIRE

    Riyadh A. AL-SAMARAI; Yarub AL-DOURI; Haftirman HAFTIRMAN; Khiarel Rafzi AHMAD

    2013-01-01

    The rheological properties of nanometric tungsten disulphide (WS2) nanoparticles oil lubricants and its tribological performance with two hypereutectic Al-Si alloy and carbon steel are examined. These two oils are used to reduce wear and friction and to explore the actions via tribological pin-on-disk tests. The pin was made from hypereutectic Al-Si alloy on steel disk, taking into consideration the effect of loads (10, 20, 30 N) and different speed (200, 300, 400 rpm). Oils with and without ...

  18. The mechanism of the surface alloy layer creation for cast steel

    Directory of Open Access Journals (Sweden)

    A. Walasek

    2012-01-01

    Full Text Available The paper presents a detailed description of the process of creation of a surface alloy layer (using high-carbon ferrochromium on the cast steel casting. The mechanism of the surface alloy layer is based on the known theories [5,6]. The proposed course of formation of the layers has been extended to decarburization stage of steel. The research included proving the presence of carbon-lean zone. The experiment included the analysis of the distribution of elements and microhardness measurement.

  19. Laser welding of AZ31B magnesium alloy to Zn-coated steel

    International Nuclear Information System (INIS)

    Highlights: ► Magnesium alloy was successfully laser welded to Zn-coated steel. ► The joint strength exceeded 6000 N on a 25 mm wide specimen. ► A 450 nm thick layer of Fe3Al was uniformly formed on the steel surface. -- Abstract: The characteristics of laser lap welding of AZ31B magnesium alloy to Zn-coated steel were investigated. Welding was difficult when the laser beam was irradiated onto the AZ31B alloy and the processing parameters were set to obtain a keyhole welding mode. The difference in the physical properties between the two materials resulted in unstable welding process particularly when the laser beam penetrated into the steel specimen and a keyhole was formed therein. By switching to a conduction mode, the process stability was improved and successful welding could be achieved because the liquid metal film remained unbroken and the laser beam did not penetrate into the material. A 25 mm wide joint failed in tensile shear testing at loads exceeding 6000 N. This high joint strength was attributed to the formation of a 450 nm thick layer of Fe3Al intermetallic compound on the steel surface as a result of the interaction between Al from the AZ31B alloy and Fe. The presence of Zn-coating layer was essential to eliminate the negative effects of oxides on the joining process.

  20. LASER SURFACE ALLOYING OF A MILD STEEL FOR CORROSION RESISTANCE IMPROVEMENT

    OpenAIRE

    Fouquet, F.; Renaud, L.; Millet, J.; Mazille, H.

    1991-01-01

    Surface alloys were produced by laser melting of different predeposits into the outer part of a mild steel substrate. Three types of coatings were used : electroless nickel (containing phosphorous), electroless nickel in which chromium carbide particles were introduced during deposition and duplex coatings made of, first, a nickel layer (electroless or electrodeposited) and then, a chromium layer. The surface alloying treatments were performed using a cw high power CO2 laser and the multiple ...

  1. The effect of dissolved stainless steel alloy elements on the activity and growth of SRB

    OpenAIRE

    F. A. Lopes; Morin, P.; Oliveira, Rosário; Melo, L. F.

    2000-01-01

    Sulphate reducing bacteria have an important role in the sulphur cycle, and therefore in wastewater treatment systems. They are able to form biofilms on metallic surfaces, leading to fouling and corrosion problems. These bacteria are among the micro-organisms most frequently implicated in microbial corrosion of iron and ferrous alloys. Alloying elements added to steels for the improvement of their corrosion resistance such as molybdenum and nickel can be dissolved in bulk liqui...

  2. Surface hardening of steels by alloying under laser heating with subsequent chemical thermal treatment

    International Nuclear Information System (INIS)

    The combination of laser alloying of carbon and low-chromium steels (20, 40, 45, 20Kh and 40Kh) with nitride-forming elements (V, Cr, Mo, Al) and subsequent nitriding is under consideration as a promising technology of enhancing wear resistance of steels. It is shown that the technology proposed permits increasing microhardness, wear resistance and favourable distribution of residual stresses in surface layers

  3. Stress corrosion cracking and hydrogen embrittlement of thick section high strength low alloy steel.

    OpenAIRE

    Needham, William Donald

    1986-01-01

    An experimental study was conducted to evaluate the corrosion performance of weldments of a high strength low alloy(HSLA) steel in a simulated seawater environment. This steel, designated HSLA80, was developed by the United States Navy for use in ship structural applications. Stress corrosion CRACKING(SCC) and hydrogen embrittlement(HEM) were investigated by conducting 42 Wedge-Opening load(WOL) tests as a function of stress intensity and corrosion potential and 33 Slow Strain Rate(SSR) tests...

  4. Cold weld cracking susceptibility of high strength low alloyed (HSLA) steel NIONIKRAL 70

    OpenAIRE

    Tawengi, A. S.; A. Sedmak; Grabulov, V.

    2014-01-01

    In view of the importance of high strength low alloy (HSLA) steels, particularly for critical applications such as offshore plat forms, pipeline and pressure vessels, this paper reports on an investigation of how to weld this type of steel without cold cracking. Using manual metal arc welding process and Tekken test (Y - Grove test) has been carried out both to observe the cold cracking phenome non, and to investigate the influencing factors, such as preheating temperature and energy input, a...

  5. The welding of austenitic-ferritic Mo-alloyed Cr-Ni-Steel

    International Nuclear Information System (INIS)

    This paper provides general information and guidance on the welding of austenitic-ferritic Mo-alloyed Cr-Ni stainless steel. Information is given on the various chemical compositions and on resistance to corrosion and on the mechanical and physical properties of commercially available steels. The effect of welding on the base metal and the selection of welding processes and welding consumables are described

  6. Effects of strain and trapping on hydrogen-induced cracking in high strength low alloy steels

    OpenAIRE

    Bosch, Cédric; Delafosse, David; Longaygue, Xavier

    2010-01-01

    International audience In pearlitic steels, hydrogen trapping at interphase boundaries may induce hydrogen- cracking in the absence of external applied stress such as in blistering and Hydrogen Induced Cracking. However, in low alloy steels containing a much lower density of such trapping sites and/or when hydrogen activity is reduced, most instances of hydrogen-induced cracking involve strong interactions between local plasticity and hydrogen effects. We investigated the effects of these ...

  7. Comparative MRI compatibility of 316 L stainless steel alloy and nickel-titanium alloy stents.

    Science.gov (United States)

    Holton, Andrea; Walsh, Edward; Anayiotos, Andreas; Pohost, Gerald; Venugopalan, Ramakrishna

    2002-01-01

    The initial success of coronary stenting is leading to a proliferation in peripheral stenting. A significant portion of the stents used in a clinical setting are made of 316 low carbon stainless steel (SS). Other alloys that have been used for stent manufacture include tantalum, MP35N, and nickel-titanium (NiTi). The ferromagnetic properties of SS cause the production of artifacts in magnetic resonance imaging (MRI). The NiTi alloys, in addition to being known for their shape memory or superelastic properties, have been shown to exhibit reduced interference in MRI. Thus, the objective of this study was to determine the comparative MRI compatibility of SS and NiTi stents. Both gradient echo and spin-echo images were obtained at 1.5 and 4.1 T field strengths. The imaging of stents of identical geometry but differing compositions permitted the quantification of artifacts produced due to device composition by normalizing the radio frequency shielding effects. These images were analyzed for magnitude and spatial extent of signal loss within the lumen and outside the stent. B1 mapping was used to quantify the attenuation throughout the image. The SS stent caused significant signal loss and did not allow for visibility of the lumen. However, the NiTi stent caused only minor artifacting and even allowed for visualization of the signal from within the lumen. In addition, adjustments to the flip angle of standard imaging protocols were shown to improve the quality of signal from within the lumen. PMID:12549230

  8. Corrosion inhibition by naturally occurring Hibiscus sabdariffa plant extract on a mild steel alloy in HCl solution

    OpenAIRE

    AMEER, MAGDA ABDO MAHMOUD; FEKRY, AMANY MOHAMED

    2015-01-01

    The corrosion inhibition of mild steel alloys is of tremendous technological importance due to their increased industrial applications. Potentiodynamic polarization and electrochemical impedance spectroscopy techniques were used to establish the effect of different concentrations of HCl on the corrosion behavior of mild steel. A study was conducted on the inhibition of dissolution for a mild steel alloy in the most corrosive concentration of HCl (5 M) by adding different concentrations of aqu...

  9. Electronic Structures and Alloying Behaviors of Ferrite Phases in High Co-Ni Secondary Hardened Martensitic Steels

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    @@The electronic structure of ferrite (tempered martensite phase) in high Co-Ni secondary hardened martensitic steel has been investigated. The local density of states (LDOS) of alloying elements in the steel displays the relationship between solid solubility and the shape of the LDOS. The bond order integral (BOI) between atoms in the steel shows that the directional bonding of the p orbital of Si or C leads to the brittleness of the steel. At last, ∑BOI between atoms demonstrate that C, Co, Mn, Cr, Mo, Si strengthen the alloyed steel through solid-solution effects.

  10. 78 FR 33809 - Seamless Carbon and Alloy Steel Standard, Line, and Pressure Pipe From the People's Republic of...

    Science.gov (United States)

    2013-06-05

    ...In response to a request from an interested party, United States Steel Corporation (``U.S. Steel''), the Department of Commerce (``the Department'') initiated an administrative review of the antidumping duty order on seamless carbon and alloy steel standard, line, and pressure pipe from the People's Republic of China. The period of review is November 1, 2011, through October 31, 2012. Based on......

  11. Tensile and impact behaviour of sinter-forged Cr, Ni and Mo alloyed powder metallurgy steels

    International Nuclear Information System (INIS)

    Sintered and forged low-alloy P/M steels containing Cr, Ni and Mo were subjected to tensile, hardness and impact tests, in order to understand the influence of the alloying elements and microstructure on their mechanical properties. Elemental powders of atomized iron, graphite, chromium, nickel and molybdenum were mixed in suitable proportions using a ball mill, compacted and sintered in order to yield the following alloy compositions: Fe-0.2%C, Fe-0.2%C-1%Cr, Fe-0.2%C-1%Cr-2%Ni, Fe-0.2%C-2%Ni and Fe-0.2%C-2%Ni-1.5%Mo. Cylindrical compacts of 24 mm diameter and 32 mm height were prepared from the powder mixes in a 1000 kN hydraulic press using suitable cylindrical die-punch combination. Sintering of the ceramic-coated cylindrical preforms was carried out at 1000 ± 10 oC in a muffle furnace for a period of 120 min. Immediately after sintering, the cylindrical compacts were hot upset forged and drawn into square cross-section bars of density values to near-theoretical using a 2000 kN friction screw press. The size of the bars was maintained as 10 x 10 x 110 mm for preparing tensile specimen and 12 x 12 x 70 mm for impact specimen. Standard tensile and impact specimens were machined off from the forged square rods. Standard procedure was followed for conducting tensile test and impact test on the forged alloys. Hardness of the hot forged alloys was also measured using Rockwell hardness tester. Microstructures of the alloys were examined for correlating with the mechanical properties. Fractographs of the fractured surfaces of the tensile specimens were obtained using a scanning electron microscope. From the present study, it is contended that the alloying elements Cr, Ni and Mo have strong influence on the tensile and impact properties of the low-alloy steels studied. Among all the five alloys considered, the steel with chromium addition has exhibited the highest tensile strength with the corresponding impact strength being the least. The same alloy has also been

  12. A new approach to alloy compensation in a thickness measurement of high-tensile steel

    International Nuclear Information System (INIS)

    In on-line manufacturing iron-making process, several kinds of element are mixed in iron in order to meet the required quality for a final product. In this paper, the results show that the alloy compensation method is needed to improve accuracy required at thickness gauge, that is, ±0.5% at the target thickness. In addition, the alloy compensation method in measurement will be proposed in the form of correction function of each element weight percentage to be alloyed using the analyzed result of MCNP simulation program. Finally, an automatic thickness compensation method applied to the high-tensile steel product during manufacturing is introduced. (authors)

  13. Development of microstructure in high-alloy steel K390 using semi-solid forming

    Science.gov (United States)

    Opatova, K.; Aisman, D.; Rubesova, K.; Ibrahim, K.; Jenicek, S.

    2016-03-01

    Semi-solid processing of light alloys, namely aluminium and magnesium alloys, is a widely known and well-established process. By contrast, processing of powder steels which have high levels of alloying elements is a rather new subject of research. Thixoforming of high-alloy steels entails a number of technical difficulties. If these are overcome, the method can offer a variety of benefits. First of all, the final product shape and the desired mechanical properties can be obtained using a single forming operation. Semi-solid forming can produce unusual powder steel microstructures unattainable by any other route. Generally, the microstructures, which are normally found in thixoformed steels, consist of large fractions of globular or polygonal particles of metastable austenite embedded in a carbide network. An example is the X210Cr12 steel which is often used for semi-solid processing experiments. A disadvantage of the normal microstructure configuration is the brittleness of the carbide network, in which cracks initiate and propagate, causing low energy fractures. However, there is a newly-developed mini-thixoforming route which produces microstructures with an inverted configuration. Here, the material chosen for this purpose was K390 steel, in which the content of alloying elements is up to 24%. Its microstructure which was obtained by mini- thixoforming did not contain polyhedral austenite grains but hard carbides embedded in a ductile austenitic matrix. This provided the material with improved toughness. The spaces between the austenite grains were filled with a eutectic in which chromium, molybdenum and cobalt were distributed uniformly. After the processing parameters were optimized, complexshaped demonstration products were manufactured by this route. These products showed an extraordinary compressive strength and high wear resistance, thanks to the hardness of their microstructure constituents, predominantly the carbides.

  14. Medium carbon vanadium micro alloyed steels for drop forging

    Energy Technology Data Exchange (ETDEWEB)

    Jeszensky, Gabor; Plaut, Ronald Lesley

    1992-12-31

    Growing competitiveness of alternative manufacturing routes requires cost minimization in the production of drop forged components. The authors analyse the potential of medium carbon, vanadium microalloyed steels for drop forging. Laboratory and industrial experiments have been carried out emphasizing deformation and temperature cycles, strain rates and dwell times showing a typical processing path, associated mechanical properties and corresponding microstructures. The steels the required levels of mechanical properties on cooling after forging, eliminating subsequent heat treatment. The machinability of V-microalloyed steels is also improved when compared with plain medium carbon steels. (author) 17 refs., 19 figs., 5 tabs.

  15. Effects of LWR environments on fatigue life of carbon and low-alloy steels

    International Nuclear Information System (INIS)

    SME Boiler and Pressure Vessel Code provides construction of nuclear power plant components. Figure I-90 Appendix I to Section III of the Code specifies fatigue design curves for structural materials. While effects of environments are not explicitly addressed by the design curves, test data suggest that the Code fatigue curves may not always be adequate in coolant environments. This paper reports the results of recent fatigue tests that examine the effects of steel type, strain rate, dissolved oxygen level, strain range, loading waveform, and surface morphology on the fatigue life of A 106-Gr B carbon steel and A533-Gr B low-alloy steel in water

  16. Structural Phase Transitions by Design in Monolayer Alloys.

    Science.gov (United States)

    Duerloo, Karel-Alexander N; Reed, Evan J

    2016-01-26

    Two-dimensional monolayer materials are a highly anomalous class of materials under vigorous exploration. Mo- and W-dichalcogenides are especially unusual two-dimensional materials because they exhibit at least three different monolayer crystal structures with strongly differing electronic properties. This intriguing yet poorly understood feature, which is not present in graphene, may support monolayer phase engineering, phase change memory and other applications. However, knowledge of the relevant phase boundaries and how to engineer them is lacking. Here we show using alloy models and state-of-the-art density functional theory calculations that alloyed MoTe2-WTe2 monolayers support structural phase transitions, with phase transition temperatures tunable over a large range from 0 to 933 K. We map temperature-composition phase diagrams of alloys between pure MoTe2 and pure WTe2, and benchmark our methods to analogous experiments on bulk materials. Our results suggest applications for two-dimensional materials as phase change materials that may provide scale, flexibility, and energy consumption advantages. PMID:26647117

  17. Effect of alloying on elastic properties of ZrN based transition metal nitride alloys

    KAUST Repository

    Kanoun, Mohammed

    2014-09-01

    We report the effect of composition and metal sublattice substitutional element on the structural, elastic and electronic properties of ternary transition metal nitrides Zr1-xMxN with M=Al, Ti, Hf, V, Nb, W and Mo. The analysis of the elastic constants, bulk modulus, shear modulus, Young\\'s modulus, and Poisson\\'s ratio provides insights regarding the mechanical behavior of Zr1-xMxN. We predict that ternary alloys are more ductile compared to their parent binary compounds. The revealed trend in the mechanical behavior might help for experimentalists on the ability of tuning the mechanical properties during the alloying process by varying the concentration of the transition metal. © 2014 Elsevier B.V.

  18. High-strength economically alloyed corrosion-resistant steels with the structure of nitrogen martensite

    Science.gov (United States)

    Bannykh, O.; Blinov, V.; Lukin, E.

    2016-04-01

    The use of nitrogen as the main alloying element allowing one both to increase the corrosion resistance and mechanical properties of steels and to improve their processability is a new trend in physical metallurgy of high-strength corrosion resistant steels. The principles of alloying, which are developed for high-nitrogen steel in IMET RAS, ensure the formation of the structure, which contains predetermined amounts of martensite (70-80%) and austenite (20-30%) and is free from δ-ferrite, σ-phase, and Cr23C6 carbide. These principles were used as the base for the creation of new high-strength corrosion-resistant weldable and deformable 0Kh16AN5B, 06Kh16AN4FD, 08Kh14AN4MDB, 09Kh16AN3MF, 27Kh15AN3MD2, 40Kh13AN3M2, and 19Kh14AMB steels, which are operative at temperatures ranging from - 70 to 400°C. The developed nitrogen-containing steels compared with similar carbon steels are characterized by a higher resistance to pitting and crevice corrosion and are resistant to stress corrosion cracking. The new steels successfully passed trial tests as heavy duty articles.

  19. Plastic behaviour and microstructure characterization high manganese aluminium alloyed steel for the automotive industry

    Directory of Open Access Journals (Sweden)

    D. Kuc

    2012-03-01

    Full Text Available Purpose: Automotive industry constantly demands high-strength steels which are characterized by the energy absorption possibilities during a collision. Such materials may, in the future, replace the currently used conventional steels. The groups of steels which meet these criteria are the austenitic steels and austenitic-ferritic steels with high manganese content (15-30% and high aluminium content (1-9%. Design/methodology/approach: Susceptibility of steel to cracking at high temperatures was tested on Gleeble 3800 simulator: zero resistance temperature was determined (TZW, zero plasticity temperature was determined (TZP, plasticity reversal temperature was determined (TNP. Research was completed by determination of steel plasticity and stress applying in next stage the deformation of samples in temperature from 850 to 1175°C. This temperature range corresponding with the field of parameters of plastic processing. For samples after tension the ultimate tensile strength was determined (Rm together with contraction (Z. Character of fractures of stretched samples was tested with the use of scanning microscope Hitachi S-4200.Findings: The tests show that the tested steel is characterised by relatively lower temperatures in comparison with low-alloyed steels. Tested steel has high plasticity in temperature wear to temperature of plastic processing 1150-800°C.Practical implications: The obtained steel is characterised by beneficial properties which outbalance the austenitic steels type TWIP and may be applied in vehicle construction on elements connected with safety.Originality/value: Conducted simulation will be helpful by elaboration of technology of continuous casting and the choice of the right parameters for plastic processing of high-manganese steel with aluminium.

  20. Alloy 31 - a high alloyed Ni-Cr-Mo-steel - properties and applications for the process industry: Alloy 31 - visoko legirano Ni-Cr-Mo jeklo - lastnosti in aplikacije za procesno industrijo:

    OpenAIRE

    Brill, U.; Mast, Ralph; Rommerskirchen, I.; Schambach, L.

    1998-01-01

    Alloy 31 (Nicrofer 3127 hMo) is an austentic nickel-chromium-molybdenum steel comprising about 0.2 wt-% nitrogen to stabilize the austenitic structure. The alloy was developed to fill the gap between the commercial stainless steels and the nickel-base alloys. It is a material for many high-severity applications where conventional stainless steels have proven unadequate. On the other hand, Alloy 31 shows a high resistance to pitting and crevice corrosion in neutral and acid aqueous solutions, ...

  1. Liquid Phase Sintering of Highly Alloyed Stainless Steel

    DEFF Research Database (Denmark)

    Mathiesen, Troels

    1996-01-01

    Liquid phase sintering of stainless steel is usually applied to improve corrosion resistance by obtaining a material without an open pore system. The dense structure normally also give a higher strength when compared to conventional sintered steel. Liquid phase sintrering based on addition...

  2. The Effect of Microstructure on the Abrasion Resistance of Low Alloyed Steels

    NARCIS (Netherlands)

    Xu, X.

    2016-01-01

    The thesis attempts to develop advanced high abrasion resistant steels with low hardness in combination with good toughness, processability and low alloying additions. For this purpose, a novel multi-pass dual-indenter (MPDI) scratch test approach has been developed to approach the real continuous a

  3. 75 FR 26273 - Certain Seamless Carbon and Alloy Steel Standard, Line, and Pressure Pipe From China

    Science.gov (United States)

    2010-05-11

    ... COMMISSION Certain Seamless Carbon and Alloy Steel Standard, Line, and Pressure Pipe From China AGENCY... pipe (``seamless SLP pipe''), provided for in subheadings 7301.19.10, 7304.19.50, 7304.31.60, 7304.39... China of seamless SLP pipe, and that such products are being sold in the United States at less than...

  4. Practical measurement of silicon in low alloy steels by differential pulse stripping voltammetry

    International Nuclear Information System (INIS)

    A sensitive differential pulse anodic stripping voltammetry has been adapted to allow the determination of Si in low-alloy steels using a hanging mercury drop electrode. The method has been qualified using certified ASTM standards and is now running in routine. The present report describes the experimental details, thereby allowing the reader to carry out the measurements precisely. (author)

  5. Computing solubility products using ab initio methods; precipitation of NbC in low alloyed steel

    NARCIS (Netherlands)

    Klymko, T.; Sluiter, M.H.F.

    2012-01-01

    The solubility product of NbC in low alloyed steel is computed from electronic density functional methods including the effects of electronic, vibrational, and magnetic excitations. Although many simplifications are made in the computations, agreement with experimental data is within the scatter of

  6. Experience of using of the intermediate plate in laser welding of stainless steel and titanium alloy

    OpenAIRE

    Пугачева, Н. Б.; Мичуров, Н. С.

    2014-01-01

    Considered the effect of the intermediate plates for welding dissimilar difficult-to-weld materials in terms of stainless steel 12Х18Н10Т (12H18N10T) and titanium alloy ВТ1-0 (VT1-0). defined the effect of additives nanopowder on the structure and properties of welded joint.

  7. Comparison of heat effects associated with metal cutting method on ST 37 alloy steel

    Directory of Open Access Journals (Sweden)

    L. Dahil

    2014-04-01

    Full Text Available In this study, by examining effects of the heat on the cut surface of material formed by the processes, such as Plasma, Laser, Wire Erosion applied on St 37 alloy steel material, it has been determined that minimum cutting damage occurs in wire erosion process.

  8. Study made of corrosion resistance of stainless steel and nickel alloys in nuclear reactor superheaters

    Science.gov (United States)

    Greenberg, S.; Hart, R. K.; Lee, R. H.; Ruther, W. E.; Schlueter, R. R.

    1967-01-01

    Experiments performed under conditions found in nuclear reactor superheaters determine the corrosion rate of stainless steel and nickel alloys used in them. Electropolishing was the primary surface treatment before the corrosion test. Corrosion is determined by weight loss of specimens after defilming.

  9. Strength and toughness improvement of low-alloy steel for nuclear applications

    Energy Technology Data Exchange (ETDEWEB)

    Lee, H. C.; Lee, S. H.; Ku, Y. M.; Lee, B. J. [Seoul National University, Seoul (Korea)

    2002-04-01

    Low carbon low alloy steels are used in nuclear power plants as pressure vessel, steam generator, etc. Nuclear pressure vessel material requires good combination of strength/ toughness, good weldability and high resistance to neutron irradiation and corrosion fatigue. For SA508III steels, most widely used in the production of nuclear power plant, attaining good toughness prior to service is one of the utmost designing goals. This work has been carried out by the combination of thermodynamic calculation, microstructural observation and evaluation of designed alloy, and the evaluation of HAZ characteristics. In this work, the means of alloy design developed in the previous study were adopted. Cr/Mo contents was controlled and Ni contents was increased to improve toughness. High toughness values were obtained in designed low carbon steels, with higher strength level than that of SA508III steels. A high CVN energy of 220J was obtained at -100 .deg. C, and a low DBTT of about-100 .deg. C was obtained in 60Cr alloy prepared in this work. 38 refs., 61 figs., 32 tabs. (Author)

  10. Critical assessment of computational thermodynamics in the alloy design of PM high speed steels

    Energy Technology Data Exchange (ETDEWEB)

    Trabadelo, V. [CEIT, Po Manuel Lardizabal 15, 20018 San Sebastian (Spain); Gimenez, S. [K.U. Leuven, Kasteelpark Arenberg 44, B3001 Heverlee (Belgium); Gomez-Acebo, T. [TECNUN, Po Manuel Lardizabal 15, 20018 San Sebastian (Spain); Iturriza, I. [CEIT, Po Manuel Lardizabal 15, 20018 San Sebastian (Spain)]. E-mail: iiturriza@ceit.es

    2005-08-15

    The experimental powder M42HVIG is used to illustrate how the adequate selection of the constituent phases involved in the calculation of multicomponent phase diagrams is a key factor for success in the computer-aided alloy design of highly sinterable high speed steel compositions.

  11. 77 FR 59892 - Carbon and Certain Alloy Steel Wire Rod From Mexico: Affirmative Final Determination of...

    Science.gov (United States)

    2012-10-01

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF COMMERCE International Trade Administration Carbon and Certain Alloy Steel Wire Rod From Mexico: Affirmative Final... Administration, Department of Commerce. SUMMARY: On December 20, 2011, the Department of Commerce (the...

  12. Corrosion resistance of Zn-Co-Fe alloy coatings on high strength steel

    NARCIS (Netherlands)

    Lodhi, Z.F.; Mol, J.M.C.; Hovestad, A.; Hoen-Velterop, L. 't; Terryn, H.; Wit, J.H.W.de

    2009-01-01

    The corrosion properties of electrodeposited zinc-cobalt-iron (Zn-Co-Fe) alloys (up to 40 wt.% Co and 1 wt.% Fe) on steel were studied by using various electrochemical techniques and compared with zinc (Zn) and cadmium (Cd) coatings in 3.5% NaCl solution. It was found that with an increase in Co con

  13. Segregation of alloying elements in thermomechanically rolled medium-Mn multiphase steels

    Directory of Open Access Journals (Sweden)

    A. Grajcar

    2012-12-01

    Full Text Available Purpose: The aim of the paper is to assess the tendency of alloying elements to macro- and microsegregation during hot-forging and successive thermomechanical rolling of medium-Mn Al-bearing steel sheets.Design/methodology/approach: The macro- and microsegregation of alloying elements was assessed by EDS and WDS measurements across the thickness of the roughly-forged flats and thermomechanically processed 3.3 mm sheets. The microstructure was revealed using combined methods of optical microscopy (OM and scanning electron microscopy (SEM. Morphological features of microstructural constituents were discussed with focusing on retained austenite. Findings: It was found that the final multiphase microstructure is mainly dependent on the Mn content and the effect of Nb microaddition is relatively low. The 3Mn steels possess very fine bainite-based microstructures whereas the steels containing 5% Mn are characterized by lath bainitic-martensitic microstructures. All the steels contain retained austenite as fine granules or layers located between bainitic ferrite laths. Some fraction of martensite-austenite (M-A islands was also identified. The tendency of Mn and Al to macrosegregation was found after the initial hot-forging. It disappears after successive rough and thermomechanical rolling whereas thin martensite and martensite-austenite microbands as a result of Mn microsegregation locally occur.Research limitations/implications: Further investigations are required to quantify the local changes of chemical composition especially in formed microbands and X-ray quantitative phase analysis should be applied to assess a fraction of retained austenite.Practical implications: The knowledge of the macro- and microsegregation of alloying elements in advanced medium-Mn steels containing retained austenite can be useful in designing the thermomechanical rolling procedures of multiphase steel sheets.Originality/value: A problem of macro- and microsegregation of

  14. Cavitation erosion behavior of WC coatings on CrNiMo stainless steel by laser alloying

    Institute of Scientific and Technical Information of China (English)

    Xiao-bin Zhang; Chang-sheng Liu; Xiao-dong Liu; Jiang Dong; Bo Yu

    2009-01-01

    The WC powder was precoated on the surface of CrNiMo stainless steel and then made into an alloying layer by using the laser alloying technique.Phases in the layers were investigated by X-ray diffraction (XRD) analysis and surface morphologies after cavitation erosion were observed with the help of scanning electron microscopy (SEM).The cavitation erosion behavior of the CrNiMo stainless steel and WC laser alloying layer in distilled water was tested with the help of ultrasonic vibration cavitation ero-sion equipment.The results showed that the thickness of the laser alloying layer was about 0.13 mm.The layer had a dense micro-structure, metallurgically bonded to the substrate, and no crack had been found.The cavitation erosion mass loss rate of the laser al-loying layer was only 2/5 that of the CrNiMo stainless steel.The layer had better cavitation resistance properties because of its met-allurgical combination and the strengthening effects of the precipitate phases.

  15. Mechanical Behavior of Two High Strength Alloy Steels Under Conditions of Cyclic Tension

    Science.gov (United States)

    Srivatsan, T. S.; Manigandan, K.; Sastry, S.; Quick, T.; Schmidt, M. L.

    2014-01-01

    The results of a recent study aimed at understanding the conjoint influence of load ratio and microstructure on the high cycle fatigue properties and resultant fracture behavior of two high strength alloy steels is presented and discussed. Both the chosen alloy steels, i.e., 300M and Tenax™ 310 have much better strength and ductility properties to offer in comparison with the other competing high strength steels having near similar chemical composition. Test specimens were precision machined from the as-provided stock of each steel. The machined specimens were deformed in both uniaxial tension and cyclic fatigue under conditions of stress control. The test specimens of each alloy steel were cyclically deformed over a range of maximum stress at two different load ratios and the number of cycles to failure recorded. The specific influence of load ratio on cyclic fatigue life is presented and discussed keeping in mind the maximum stress used during cyclic deformation. The fatigue fracture surfaces were examined in a scanning electron microscope to establish the macroscopic mode and to concurrently characterize the intrinsic features on the fracture surface. The conjoint influence of nature of loading, maximum stress, and microstructure on cyclic fatigue life is discussed.

  16. Corrosion of nickel alloys and stainless steels in polluted or confined PWR environments

    International Nuclear Information System (INIS)

    This document addresses the issue of corrosion of materials used in PWR nuclear reactors, notably in steam generators which have been particularly affected by this kind of degradation due to a progressive accumulation of impurities. The authors first present the different materials used in secondary circuit and in auxiliary circuits of PWRs: carbon steels and low alloyed steels, nickel alloys, stainless steels, and other materials. They discuss the degradation of steam generator tubes by corrosion: corrosion environments, types of corrosion (wastage, pitting, intergranular stress corrosion cracking), and influence of the environment and of the microstructure. They also propose a brief overview of modelling efforts in the case of the 600 alloy, and indicates measures to mitigate the tube degradation by corrosion (water treatment, better design of steam generators and secondary circuit, improvement of corrosion resistance). The next part addresses the degradation by stress corrosion cracking of stainless steels in polluted environments in PWRs reactors: return on experience, stress corrosion cracking in media contaminated by impurities (intergranular corrosion of sensitized or work hardened steels, transgranular corrosion by chloride ions, corrosion by diluted sulphate + chloride, corrosion in concentrated boric acid solutions)

  17. Analysis Of The Austenite Grain Growth In Low-Alloy Boron Steel With High Resistance To Abrasive Wear

    OpenAIRE

    Białobrzeska B.; Dudziński W.

    2015-01-01

    Today low-alloy steels with boron achieve high resistance to abrasive wear and high strength. These features are obtained by using advanced technology of manufacturing. This makes boron steels increasingly popular and their application more diverse. Application of these steels can extend the lifetime of very expensive machine construction in many industries such as mining, the automotive, and agriculture industries. An interesting subgroup of these materials is steel with boron intended for h...

  18. Simultaneous Co-deposition of Zn-Mg Alloy Layers on Steel Strip by PVD Process

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Tae Yeob [POSCO Technical Research Laboratories, Gwangyang (Korea, Republic of); Goodenough, Mark [Strategic Marketing, Tata Steel, Warwickshire (United Kingdom)

    2011-12-15

    This is the first release of an interim report on the development of coating technology of Zn-Mg alloy layers on steel strip by EML-PVD (electromagnetic levitation - physical vapor deposition) process in an air-to-air type continuous PVD pilot plant. It intends to introduce a basic principle of the EML-PVD process together with the high speed PVD pilot plant built in Posco. Due to the agitation effect provided by the high frequency induction coil, simultaneous evaporation of Zn and Mg from a droplet could produce alloy coating layers with Mg content of 6% to 12% depending on the composition of the droplet inside the coil. For its superior corrosion resistance, Zn-Mg alloy coated steel would be a very promising material for automotive, electrical appliances, and construction applications.

  19. MODELING OF AUSTENITE GRAIN SIZE IN LOW-ALLOY STEEL WELD METAL

    Institute of Scientific and Technical Information of China (English)

    A.G.Huang; Y.S.Wang; Z.Y.Li; J.G.Xiong; Q.Hu

    2004-01-01

    The size of austenite grain hassignificant effects on components and proportions of various ferrites in low-alloy steel weld metal.Therefore,it is important to determine the size of austenite grain in the weld metal.In this paper,a model based upon the carbon diffusion rate is developed for computing austenite grain size in low-alloy steel weld metal during continuous cooling.The model takes into account the effects of the weld thermal cycles,inclusion particles and various alloy elements on the austenite grain growth.The calculating results agree reasonably with those reported experimental observations.The model demonstrates a significant promise to understand the weld microstructure and properties based on the welding science.

  20. Nondestructive inspection assessment of eddy current and electrochemical analysis to separate inconel and stainless steel alloys

    Energy Technology Data Exchange (ETDEWEB)

    Moore, D.G.; Sorensen, N.R.

    1998-02-01

    This report presents a nondestructive inspection assessment of eddy current and electrochemical analysis to separate inconel alloys from stainless steel alloys as well as an evaluation of cleaning techniques to remove a thermal oxide layer on aircraft exhaust components. The results of this assessment are presented in terms of how effective each technique classifies a known exhaust material. Results indicate that either inspection technique can separate inconel and stainless steel alloys. Based on the experiments conducted, the electrochemical spot test is the optimum for use by airframe and powerplant mechanics. A spot test procedure is proposed for incorporation into the Federal Aviation Administration Advisory Circular 65-9A Airframe & Powerplant Mechanic - General Handbook. 3 refs., 70 figs., 7 tabs.

  1. Effects of milling process and alloying additions on oxide particle dispersion in austenitic stainless steel

    International Nuclear Information System (INIS)

    An oxide dispersion strengthened (ODS) austenitic stainless steel was developed by mechanical alloying (MA) of advanced SUS316 stainless steel. A nano-characterization was performed to understand details of the effect of minor alloying elements in the distribution of dispersoids. It is shown that Y2O3 particles dissolve into the austenitic matrix after the MA for 6 h. Annealing at 1073 K or higher temperatures result in a distribution of fine oxide particles in the recrystallized grains in the ODS austenitic stainless steel. Additions of Hafnium or Zirconium led to the distribution of finer oxide particles than in samples without these elements, resulting in an increase in the hardness of the samples. The most effective concentration of Hf and Zr to increase the hardness was 0.6 and 0.2–0.3 wt%, respectively

  2. Aging of maraging steel welds during aluminium alloy die casting

    OpenAIRE

    Klobčar, Damjan; Pleterski, Matej; Taljat, Boštjan; Kosec, Ladislav; Tušek, Janez

    2015-01-01

    The aim of this study is to evaluate precipitation annealing of 18% Ni maraging steel repair welds during aluminium die casting and to predict the prolonged in-service tool life. The emphasis of this study is the influence ofpost-weld precipitation annealing heat treatment and aluminium die casting thermal cycling on metallurgical and mechanical properties. A series of specimens of 1.2344 tool steel is prepared to which 1.6356 maraging steel is GTA weld cladded. Analysis of weld microstructur...

  3. Influence of technetium on the microstructure of a stainless steel-zirconium alloy

    International Nuclear Information System (INIS)

    Stainless steel-zirconium alloys are being developed for the disposal of metallic waste generated during the electrometallurgical treatment of spent Experimental Breeder Reactor (EBR-II) fuel. The metallic waste contains the fission product technetium, which must be incorporated into a stable waste form matrix to prevent its release into the environment. The baseline waste form for metallic waste from EBR-II fuels is a stainless steel-15 wt% zirconium (SS-15Zr) alloy. The microstructure of SS-15Zr alloys containing 2 wt% technetium was characterized using a combination of microscopy, spectroscopy, diffraction, and chemical analysis techniques. Peaks corresponding to the iron solid solutions ferrite and austenite, ZrFe2-type Laves polytypes C36 and C15, and an Fe23Zr6-type intermetallic were identified in diffraction patterns of the alloy. Discrete technetium-rich phases were not observed either in diffraction patterns or in the microstructure; the element partitioned into various phases of the SS-15Zr alloy. Technetium favors ferrite and austenite over the Zr-based intermetallics. The lattice parameters of the Zr-based intermetallics are smaller than those in an alloy without technetium, which appears to substitute at the zirconium sites of the intermetallic lattice

  4. Effect of microstructure on the susceptibility of low-alloy steels to hydrogen attack

    Energy Technology Data Exchange (ETDEWEB)

    Williams, R.O.

    1981-08-01

    In an alloy steel in which one or more alloy additions stabilize the carbide phase, the carbon activity depends on the microstructure and the prior thermal history. The carbon activity is a major factor in the susceptibility of such steels to form internal methane bubbles when heated in high-pressure hydrogen. Thus one can expect to vary the susceptibility to hydrogen attack of a given steel by its prior treatment. The problem has two aspects. First, one needs to be able to calculate the equilibrium carbon activity when the steel is in internal equilibrium. A computer program in the appendix of this report takes care of part of this problem. When the thermodynamics of the mixed carbide phase is adequately modeled, then this problem can be solved. The second part is the rate of approach to equilibrium. An analysis of the rate of coarsening of carbides in such steels shows that this rate is enhanced by a fine carbide dispersion. Such a fine dispersion is also desirable for the maximum strength. Thus, we believe that under favorable circumstances the resistance to hydrogen attack can be enhanced by suitable thermal treatments of the steels used for the pressure vessels for hydrogen service. 12 figures.

  5. A Transmission Electron Microscopy Study of Plate Martensite Formation in High-carbon Low Alloy Steels

    Institute of Scientific and Technical Information of China (English)

    Albin Stormvinter; Peter Hedstr(o)m; Annika Borgenstam

    2013-01-01

    The martensitic microstructures in two high-carbon low alloy steels have been investigated by classical and automated crystallographic analysis under a transmission electron microscope.It is found that the martensitic substructure changes from consisting mostly of transformation twins for 1.20 mass% carbon (C) steel to both transformation twins and planar defects on {101}M for 1.67 mass% C steel.In the 1.67 mass% C steel it is further found that small martensite units have a rather homogeneous substructure,while large martensite units are more inhomogeneous.In addition,the martensite units in both steels are frequently found to be of zigzag patterns and have distinct crystallographic relationships with neighboring martensite units,e.g.kink or wedge couplings.Based on the present findings the development of martensite in high-carbon low alloy steels is discussed and a schematic of the martensite formation is presented.Moreover,whether the schematic view can be applied to plate martensite formation in general,is discussed.

  6. The improvement of cryogenic mechanical properties of Fe-12 Mn and Fe-8 Mn alloy steels through thermal/mechanical treatments

    Science.gov (United States)

    Hwang, S. K.; Morris, J. W., Jr.

    1979-01-01

    An investigation has been made to improve the low temperature mechanical properties of Fe-8Mn and Fe-12Mn-0.2 Ti alloy steels. A reversion annealing heat treatment in the two-phase (alpha + gamma) region following cold working has been identified as an effective treatment. In an Fe-12Mn-0.2Ti alloy a promising combination of low temperature (-196 C) fracture toughness and yield strength was obtained by this method. The improvement of properties was attributed to the refinement of grain size and to the introduction of a uniform distribution of retained austenite (gamma). It was also shown that an Fe-8Mn steel could be grain-refined by a purely thermal treatment because of its dislocated alpha-prime martensitic structure and absence of epsilon martensite. As a result, a significant reduction of ductile to brittle transition temperature was obtained.

  7. THE ELECTROCONDUCTIVITY OF THE LIQUID ALLOYS OF TRANSITION METALS

    Directory of Open Access Journals (Sweden)

    V.T.Shvets

    2004-01-01

    Full Text Available The concentration dependance of electroresistivity of the liquid binary alloys of transition metals Fe, Co and Ni is calculated. We considered the contribution to conductivity from the s-electrons, described within the model of nearly free electrons. The role of the partially occupied d-bands is reduced to resonance scattering of the s-electrons on d-states. The interaction of the s- and d-electrons is described by the hybridization potential of s- and d-states. The interaction with the ions, not including the partially occupied d-states, is described using the pseudopotential of the electron-ion interaction. The electroresistivity of the alloys is calculated in the second order of the perturbation theory in pseudopotential and hybridization potential. The concentration dependance of electroresistivity of the binary alloys approaches the linear regime as the resonance scattering of the s-electrons on d-states prevails over the scattering on the ions. The calculations exhibit good agreement with the experimental data.

  8. Oxidation kinetics of high strength low alloy steels at elevated temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Talekar, Anjali [Materials Science and Engineering, Chemical and Metallurgical Engineering Department, MS 388, University of Nevada, 1664 North Virginia Street, Reno, NV 89557 (United States); Chandra, Dhanesh [Materials Science and Engineering, Chemical and Metallurgical Engineering Department, MS 388, University of Nevada, 1664 North Virginia Street, Reno, NV 89557 (United States)], E-mail: dchandra@unr.edu; Chellappa, Raja [Geophysical Laboratory, Carnegie Institution of Washington, 5251 Broad Branch Road, Washington, DC 20015 (United States); Daemen, Jaak [Mining Engineering Department, University of Nevada, Reno, NV 89557 (United States); Tamura, Nobumichi; Kunz, Martin [Advanced Light Source, Lawrence Berkeley National Laboratories, MS 2R0222, Berkeley, CA 94720 (United States)

    2008-10-15

    High strength low alloy (HSLA) steels are candidate Rockbolt materials for use as underground roof supports at Yucca Mountain nuclear waste repository. Oxidation kinetics of International Rollforms Split Set Friction Rock Stabilizers (SS46), and Swellex Mn24 steels have been determined by temperature modulated thermogravimetry at temperatures ranging between 600 and 900 deg. C in pure oxygen atmosphere for 100 hr. The imposed sinusoidal temperature modulations ({+-}5 deg. C for a period of 1 cycle per 200 s) on the isothermal temperature did not have any noticeable effect on the weight gain characteristics during oxidation. Weight gain data on the steels indicate two distinct regions with different oxidation profiles, where a definite change in rates of oxidation is observed: a first oxidation regime where the steels followed a rate law y = kt{sup 0.40-0.63} (changing index of rate law depending upon steel and temperature) and a second stage oxidation regime that follows the parabolic law. The results of characterization of the oxide films using SEM/EDAX, X-ray diffraction and Synchrotron white beam X-ray microdiffraction are presented. The oxidation data of the steels presented here is expected to be useful for characterizing those steels for use in underground rock bolt system and as roof support for the DOE proposed Yucca Mountain Nuclear Waste Repository. To the best of our knowledge this is the first time thermogravimetric studies of this kind have been done on these steels.

  9. Diffusion Bonding Behavior and Characterization of Joints Made Between 316L Stainless Steel Alloy and AZ31 Magnesium Alloy

    Science.gov (United States)

    Elthalabawy, Waled Mohamed

    The 316L austenitic stainless steel and AZ31 magnesium alloy have physical and mechanical properties which makes these alloys suitable in a number of high technology based industries such as the aerospace and automotive sectors. However, for these alloys to be used in engineering applications, components must be fabricated and joined successfully. The differences in the physical and metallurgical properties between these two alloys prevents the use of conventional fusion welding processes commonly employed in aerospace and transport industry. Therefore, alternative techniques need to be developed and diffusion bonding technology is a process that has considerable potential to join these two dissimilar alloys. In this research work both solid-state and transient liquid phase (TLP) bonding processes were applied. The solid-state bonding of 316L steel to AZ31 magnesium alloy was possible at a bonding temperature of 550°C for 120 minutes using a pressure of 1.3 MPa. The interface characterization of the joint showed a thin intermetallic zone rich in Fe-Al was responsible for providing a metallurgical bond. However, low joint shear strengths were recorded and this was attributed to the poor surface to surface contact. The macro-deformation of the AZ31 alloy prevented the use of higher bonding pressures and longer bonding times. In order to overcome these problems, the TLP bonding process was implemented using pure Cu and Ni foils as interlayers which produced a eutectic phase at the bonding temperature. This research identified the bonding mechanism through microstructural and differential scanning calorimetry investigations. The microstructural characterization of the TLP joints identified intermetallics which became concentrated along the 316L steel/AZ31 bond interface due to the "pushing effect" of the solid/liquid interface during isothermal solidification stage of bonding. The size and concentration of the intermetallics had a noticeable effect on the final joint

  10. Influence of high-temperature exposure on the microstructure and mechanical properties of dissimilar metal welds between modified 9Cr-1Mo steel and alloy 800

    Science.gov (United States)

    Sireesha, M.; Albert, Shaju K.; Sundaresan, S.

    2005-06-01

    Transition joints between ferritic steel and austenitic stainless steel are commonly encountered in high-temperature components of power plants. Service failures in these are known to occur as a result, mainly, of thermal stresses due to expansion coefficient differentials. In order to mitigate the problem, a trimetallic configuration involving an intermediate piece of a material such as Alloy 800 between the ferritic and austenitic steels has been suggested. In our work, modified 9Cr-1Mo steel and 316LN stainless steel are used as the ferritic and austenitic components and the thermal behavior of the joints between modified 9Cr-1Mo steel and Alloy 800 is described in this article. The joints, made using the nickel-base filler material INCONEL 82/182 (INCONEL 82 for the root pass by gas-tungsten arc welding and INCONEL 182 for the filler passes by shielded-metal arc welding), were aged at 625 °C for periods up to 5000 hours. The microstructural changes occurring in the weld metal as well as at the interfaces with the two parent materials are characterized in detail. Results of across-the-weld hardness surveys and cross-weld tension tests and weld metal Charpy impact tests are correlated with the structural changes observed. Principally, the results show that (1) the tendency for carbon to diffuse from the ferritic steel into the weld metal is much less pronounced than when 2.25Cr-1Mo steel is used as the ferritic part; and (2) intermetallic precipitation occurs in the weld metal for aging durations longer than 2000 hours, but the weld metal toughness still remains adequate in terms of the relevant specification.

  11. Influence of Alloying Elements Corrosion Resistance of Cold on Mechanical Properties and Rolled C-Mn-Si TRIP Steels

    Institute of Scientific and Technical Information of China (English)

    ZHANG Ling-yun; WU Di; LI Zhuang

    2012-01-01

    The rust layer plays an important role in the corrosion of steel in chlorinated environments. Salt spray, po- tentiodynamic polarization curve and tensile test were conducted in laboratory for the specimens after two-stage heat treatment. The influence of the alloying elements on mechanical properties and corrosion resistance of three kinds of steels was investigated by observing the microstructure and the morphologies of rust layer. The results show that the highest value (29%) of total elongation for steel A is obtained. The mechanical property of the specimen for steel C exhibits best strength ductility balance (21 384 MPa ·%) because of the presence of the multiphase microstructures after a two-stage heat treatment and the addition of the alloying elements. The corrosion products are known to be a complex mixture of Fe3O4 , Fe2O3 and α-FeOOH for steel C. The presence of the alloying elements results in the for mation of compact and dense rust layers in steel B and C. Passive film protects the substrate of TRIP (transformation induced plasticity) steel containing a complex mix of multiphase. Superior corrosion performance is exhibited for steel C with low alloying contents due to the enrichment of alloying elements within the rust layers.

  12. Study of the sensitisation of a highly alloyed austenitic stainless steel, Alloy 926 (UNS N08926), by means of scanning electrochemical microscopy

    OpenAIRE

    Leiva García, Rafael; Akid, R.; Greenfield, D.; Gittens, J.; Muñoz Portero, María José; García Antón, José

    2012-01-01

    The feedback mode of a scanning electrochemical microscope (SECM) was applied to study differences in the reactivity of a highly alloyed austenitic stainless steel, Alloy 926 (UNS N08926), in its unsensitised and sensitised state. Alloy 926 was heated at 825 °C for 1 h in an inert atmosphere in order to produce a sensitised metallurgical condition. Sensitisation was due to chromium carbide formation at the grain boundaries. The oxygen reduction reaction was used as an indicator to monitor the...

  13. Phase stability of laves intermetallics in a stainless steel-zirconium alloy

    International Nuclear Information System (INIS)

    Phase transformations occurring in a stainless steel-15 wt% zirconium (SS-15Zr) alloy were studied by in situ neutron diffraction. Neutron diffraction patterns as a function of time were obtained on alloys that were held at various elevated temperatures (1084-1275 C). As-cast SS-15Zr alloys contain ferrite, austenite, ZrFe2-type Laves polytypes C36 and C15, and small amounts of a Fe23Zr6-type intermetallic. Annealing at high temperatures resulted in an increase of the Fe23Zr6, intermetallic content. The C15 Laves polytype is the equilibrium phase for T ≤ 1230 C; C36 is the stable polytype at higher temperatures (∼1275 C). Phase changes were slow for temperatures <1100 C.These findings have important implications for use of the SS-15Zr alloy as a nuclear waste form

  14. High temperature corrosion of low and high alloy steels under molten carbonate fuel cell conditions

    International Nuclear Information System (INIS)

    The corrosion behavior of eight low and high alloy steels was investigated under simulating the conditions at the cathode of a molten carbonate fuel cell at 650 C. Different Li-containing iron oxides (LiFeO2 and LiFe5O8) were formed in contact with the eutectic (Li, K)-carbonate melt depending on the Cr-content of the steel. These oxides show low solubility in the melt and protect the metallic material against further corrosive attack. Fast growing scales of Fe3O4 and LiFe5O8 were observed on the low alloy ferritic steel 10 CrMo 9 10. Higher alloy steels form LiFeO2 in contact with the melt and mixed Fe-Cr-spinels underneath. Steels with Cr-contents over 20 wt.% Cr form a mixed LiCr1-xFexO2 and LiCrO2 layer in contact with the metal. Marker experiments on the commercial steel 1.4404 (X2 CrNiMo 17 13 2) show that the outer LiFeO2 layer grows mainly by outward diffusion of iron ions (Fe3+), whereas the inner (Fe,Ni)Cr2O4 spinel layer grows inward. After 500 hours, LiFe5O8 was formed between the spinel and the LiFeO2 layer, but it had disappeared after several thousand hours of exposure as it was fully transformed to LiFeO2. Co-containing LiFeO2 was found after 500 hours on the high Co-containing steel 1.4971 (X12 CrCoNi 21 20), but is not stable after several thousand hours exposure. Co diffuses outward to form a protective LiCoO2 layer of a few microns in thickness. Protective Cr2O3 layers were not observed on steels with high Co-content (≥25 wt.% Cr) due to peroxide ions in the melt, which cause oxidation Cr2O3 and flux to chromate, which is highly soluble in the melt. Further quantitative investigations on total corrosion considering the chromate formation have shown that high alloy steels with high amounts of Cr form mainly K2CrO4. (orig.)

  15. High temperature corrosion of low and high alloy steels under molten carbonate fuel cell conditions

    Energy Technology Data Exchange (ETDEWEB)

    Biedenkopf, P.; Spiegel, M.; Grabke, H.J. [Max-Planck-Institut fuer Eisenforschung GmbH, Duesseldorf (Germany)

    1997-08-01

    The corrosion behavior of eight low and high alloy steels was investigated under simulating the conditions at the cathode of a molten carbonate fuel cell at 650 C. Different Li-containing iron oxides (LiFeO{sub 2} and LiFe{sub 5}O{sub 8}) were formed in contact with the eutectic (Li, K)-carbonate melt depending on the Cr-content of the steel. These oxides show low solubility in the melt and protect the metallic material against further corrosive attack. Fast growing scales of Fe{sub 3}O{sub 4} and LiFe{sub 5}O{sub 8} were observed on the low alloy ferritic steel 10 CrMo 9 10. Higher alloy steels form LiFeO{sub 2} in contact with the melt and mixed Fe-Cr-spinels underneath. Steels with Cr-contents over 20 wt.% Cr form a mixed LiCr{sub 1-x}Fe{sub x}O{sub 2} and LiCrO{sub 2} layer in contact with the metal. Marker experiments on the commercial steel 1.4404 (X2 CrNiMo 17 13 2) show that the outer LiFeO{sub 2} layer grows mainly by outward diffusion of iron ions (Fe{sup 3+}), whereas the inner (Fe,Ni)Cr{sub 2}O{sub 4} spinel layer grows inward. After 500 hours, LiFe{sub 5}O{sub 8} was formed between the spinel and the LiFeO{sub 2} layer, but it had disappeared after several thousand hours of exposure as it was fully transformed to LiFeO{sub 2}. Co-containing LiFeO{sub 2} was found after 500 hours on the high Co-containing steel 1.4971 (X12 CrCoNi 21 20), but is not stable after several thousand hours exposure. Co diffuses outward to form a protective LiCoO{sub 2} layer of a few microns in thickness. Protective Cr{sub 2}O{sub 3} layers were not observed on steels with high Co-content ({>=}25 wt.% Cr) due to peroxide ions in the melt, which cause oxidation Cr{sub 2}O{sub 3} and flux to chromate, which is highly soluble in the melt. Further quantitative investigations on total corrosion considering the chromate formation have shown that high alloy steels with high amounts of Cr form mainly K{sub 2}CrO{sub 4}. (orig.) 22 refs.

  16. Alloying and heat treatment optimization of Fe/Cr/C steels for improved mechanical properties

    International Nuclear Information System (INIS)

    The effects of alloying elements and heat treatments on the microstructural changes and strength-toughness properties were investigated in optimization of vacuum melted Fe/Cr/C base steels. The structure of the steels in the as-quenched conditions consisted of highly dislocated autotempered lath martensite (strong phase) and thin continuous interlath films of retained austenite (tough phase). It has been emphasized again that the mechanical properties of the steels are sensitive to the amount and the stability of retained austenite. To increase the stability of retained austenite in the as-quenched condition 2 w/o Mn or 2 w/o Ni was added to the base steel, viz., Fe/3Cr/0.3C. Partial replacement of Cr by about 0.5 w/o Mo did not alter the beneficial microstructure

  17. Change of tensile behavior of a high-strength low-alloy steel with tempering temperature

    Energy Technology Data Exchange (ETDEWEB)

    Yan Wei; Zhu Lin [Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016 (China); Sha Wei [Metals Research Group, School of Planning, Architecture and Civil Engineering, Queen' s University of Belfast, Belfast BT7 1NN (United Kingdom); Shan Yiyin, E-mail: yyshan@imr.ac.cn [Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016 (China); Yang Ke [Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016 (China)

    2009-08-20

    The tensile behavior of a high-strength low-alloy (HSLA) steel after tempering at different temperatures from 200 to 700 deg. C was investigated. The steel showed similar tensile behavior with almost no change in strength for tempering below 400 deg. C. However, when the tempering temperature was increased from 500 to 650 deg. C, the steel displayed not only a decrease in strength, but also gradually the upper yield points and lower strain-hardening ability. When the tempering temperature was increased up to 700 deg. C, the steel exhibited a 'round roof' shaped tensile curve and a high strain-hardening exponent. These interesting phenomena of tensile behavior are well explained in view of the interactions of mobile dislocations and dissolved C and N atoms and their effects on the strain-hardening exponent.

  18. Moessbauer study of the annealing effect on low-alloyed steels

    International Nuclear Information System (INIS)

    Structural analyses of Fe-Cr and Fe-Cr-Ni low-alloyed steels before and after annealing at 600 deg. C using Moessbauer spectrometry, X-ray diffraction and scanning electron microscopy are reported. At the received state, the two steels present a fine bainitic microstructure with equal hardness. From Moessbauer analysis, two iron sites are identified as substitutional by Cr, Mo, Ni atoms and as insertional by carbon in bainitic ferrite. Both sites are locally deformed by residual stresses. The presence of small quantities of retained austenite and ε carbide has been observed. Annealing for one hour at 600 deg. C causes a decrease in hardness for both steels with a decrease of retained austenite. After longer time of annealing, precipitation of (Fe,Ni)23C6 occurs in the Fe-Cr-Ni steel and increases hardness

  19. Influence of silicon addition on the mechanical properties and corrosion resistance of low-alloy steel

    Indian Academy of Sciences (India)

    M Hebda; H Dębecka; J Kazior

    2015-12-01

    The addition of silicon to low-alloy steel allows to modify the materials' microstructure and thus to improve their corrosion resistance and mechanical properties. The influence of adding different amounts of silicon on the properties (density, transverse rupture strength, microhardness and corrosion resistance) and microstructure of low-alloy steel was investigated. Samples were prepared via the mechanical alloying process, which is the most useful method to homogeneously introduce silicon to low-alloy steel. Sintering was performed by using the spark plasma sintering (SPS) technique. After the SPS process, half of each of the obtained samples was heat-treated in a vacuum furnace. The results show that high-density materials were achieved, and a homogeneous and fine microstructure was obtained. The investigated compositions containing 1 wt% of silicon had better corrosion resistance than samples with 3 wt% of silicon addition. Furthermore, corrosion resistance as well as the mechanical and plastic properties of the samples with 1 wt% of silicon can be further improved by applying heat treatment.

  20. Study on fatigue resistance of low alloy steels with Mo and Cr

    Science.gov (United States)

    Enculescu, E.; Chicet, D. L.; Dia, V.; Stanciu, S.

    2016-08-01

    This paper presents, based on a case study, the analysis of the factors that influence the mechanical cyclic fatigue resistance of two grades of low alloy steel with Mo and Cr. It was studied the fatigue behavior in real operating conditions of some active elements manufactured from the two low-alloyed steel grades, elements that are equipping some farm implements. Using the fractographic analysis, optical microscopy and scanning electron microscopy, were analyzed the samples that carried away because of the fatigue fracture. On samples taken from the two brands of low alloy steels with Mo and Cr were performed tempering thermal treatments that modified the structure, in order to improve the operating characteristics. The effect of those thermal treatments was initially observed by microstructural analysis of metallographic prepared samples (by polishing and chemical attack using nital reagent), that revealed a troostite type structure. On the heat-treated samples were determined a number of mechanical properties: hardness, impact strength and tensile test. There was observed an improvement of the impact bending strength for both alloys and a tensile behavior that favors increasing resistance to fatigue.

  1. Chemical Homogenization Of Liquid Steel Flowed Through Continuous Casting Slab Tundish During Alloying Process

    Directory of Open Access Journals (Sweden)

    Cwudziński A.

    2015-06-01

    Full Text Available This paper presents the results of research on the behaviour of an alloy addition in steel flowing through the tundish used for casting slabs. The device under examination is a wedge-shaped single-nozzle tundish of a capacity of 30 Mg. Due to the complexity of alloy addition dissolution and dispersion in metallurgical processes, a decision was made to use the Species Model available within the Ansys-Fluent® program. For describing the turbulence, the Realizable k-ɛ model was chosen. By defining the heat losses on respective planes making up the virtual model, the non-isothermal conditions existing during the flow of liquid steel through the tundish were considered. From the performed numerical simulations, the fields of steel flow and steel temperature and alloy addition concentration in the tundish working space were obtained. In order to accurately illustrate the process of chemical homogenization in the tundish working space, mixing curves were recorded. Based on the obtained results (mixing curves, the mixing time needed for achieving the 95% level of chemical homogenization was calculated.

  2. A fracture mechanics approach for estimating fatigue crack initiation in carbon and low-alloy steels in LWR coolant environments

    International Nuclear Information System (INIS)

    A fracture mechanics approach for elastic-plastic materials has been used to evaluate the effects of light water reactor (LWR) coolant environments on the fatigue lives of carbon and low-alloy steels. The fatigue life of such steel, defined as the number of cycles required to form an engineering-size crack, i.e., 3-mm deep, is considered to be composed of the growth of (a) microstructurally small cracks and (b) mechanically small cracks. The growth of the latter was characterized in terms of ΔJ and crack growth rate (da/dN) data in air and LWR environments; in water, the growth rates from long crack tests had to be decreased to match the rates from fatigue S-N data. The growth of microstructurally small cracks was expressed by a modified Hobson relationship in air and by a slip dissolution/oxidation model in water. The crack length for transition from a microstructurally small crack to a mechanically small crack was based on studies on small crack growth. The estimated fatigue S-N curves show good agreement with the experimental data for these steels in air and water environments. At low strain amplitudes, the predicted lives in water can be significantly lower than the experimental values

  3. Structure and properties of surface layers obtained by alloying of the hot work tool steels

    Directory of Open Access Journals (Sweden)

    L.A. Dobrzański

    2006-04-01

    Full Text Available Purpose: The aim of the present work was to study the microstructure and properties produced after laser alloying of the 55NiCrMoV7 and X40CrMoV5-1 an alloy hot-work tool steels.Design/methodology/approach: Structure investigation was performed using the light microscope Leica MEF4A supplied by Zeiss. Phase composition and crystallographic structure were determined by the X-ray diffraction method using the DRON 2.0. The measurements of microhardness have been performed using Shimadzu microhardness intender equipped with electronic sensor that allows the direct readout of the hardness values.Findings: The metallographic investigations on light microscope show that steel after laser remelting can be characterized by a dendrite structure. Metallographic examinations on the scanning microscope with the EDX attachment confirm the occurrence of the niobium carbides in the surface layer of the investigated steels.Research limitations/implications: In order to evaluate with more detail the possibility of applying these surface layers in tools, further investigations should be concentrated on the determination of the thermal fatigue resistance of the layers.Practical implications: The surface layer of the hot work steel alloyed with ceramic powder have good properties and make possibility for uses it in various technical and industrial applications.Originality/value: The microstructure and properties of the surface layer of the 55NiCrMoV7 and X40CrMoV5-1 hot-work tool steels alloying with ceramic powder were compared.

  4. 78 FR 48647 - Certain Circular Welded Non-Alloy Steel Pipe from Mexico: Preliminary Results and Partial...

    Science.gov (United States)

    2013-08-09

    ... From the Federal Register Online via the Government Publishing Office DEPARTMENT OF COMMERCE International Trade Administration Certain Circular Welded Non-Alloy Steel Pipe from Mexico: Preliminary Results... Administration, International Trade Administration, Department of Commerce. SUMMARY: In response to requests...

  5. A general scheme for the estimation of oxygen binding energies on binary transition metal surface alloys

    DEFF Research Database (Denmark)

    Greeley, Jeffrey Philip; Nørskov, Jens Kehlet

    2005-01-01

    A simple scheme for the estimation of oxygen binding energies on transition metal surface alloys is presented. It is shown that a d-band center model of the alloy surfaces is a convenient and appropriate basis for this scheme; variations in chemical composition, strain effects, and ligand effects...... for the estimation of oxygen binding energies on a wide variety of transition metal alloys. (c) 2005 Elsevier B.V. All rights reserved....

  6. Mechanical and Electrochemical Behavior of a High Strength Low Alloy Steel of Different Grain Sizes

    Science.gov (United States)

    Ghosh, K. S.; Mondal, D. K.

    2013-08-01

    Various heat treatments applied to a fine-grained high strength low alloy (HSLA) steel resulted in producing different grain sizes. Optical and scanning electron microstructures of the different alloy states exhibited varying ferrite grains which have increased with the increase of annealing time and decrease of cooling rates. TEM structures of the as-received HSLA steel displayed characteristics microstructural features, distribution, and morphology of microalloy precipitates. Hardness and tensile strength values have decreased with the increase of grain sizes. Potentiodynamic electrochemical polarization of the different alloy states in 3.5 wt pct NaCl solution showed typical active metal/alloy behavior. Tensile specimens of the as-received and heat-treated alloy cathodically charged with hydrogen, followed by tensile testing, did not indicate any noticeable loss of ductility. FESEM fractographs of hydrogen-charged samples showed a few chain of voids in the presence of cup and cone ductile fracture features in tensile-tested samples without hydrogen charging as well.

  7. Structure and properties of hotwork tool steel alloyed by WC carbides by a use of high power diode laser

    OpenAIRE

    M. Bonek; L.A. Dobrzański; Klimpel, A

    2007-01-01

    Purpose: The paper presents the effect of alloying with tungsten carbide on properties of the X40CrMoV5-1 steel surface layer, using the high power diode laser (HPDL).Design/methodology/approach: The structural mechanism of surface layer development was determined and the effect of alloying parameters, gas protection method, and thickness of paste layer applied onto the steel surface on structure refinement and influence of these factors on the mechanical properties of surface layer was studi...

  8. Investigation on laser brazing AA6056 Al alloy to XC18 low-carbon steel

    Institute of Scientific and Technical Information of China (English)

    Jianjun Ding; Feiqun Li; Feng Qu; Patrice Peyre; Remy Fabbro

    2005-01-01

    @@ Based on the studies of influence of YAG laser heating conditions for Al alloy melt and steel on wettability,the mechanics of the laser overlap braze welding of 6056 Al and XC18 steel sheet has been investigated.Under the temperature range which is above the melting point of the Al alloy and below the melting point of the steel, two dissimilar metals can be joined by means of laser braze welding. There is no crack observed in the joining area, i.e. Al-Fe intermetallic phase (Fe3Al/FeAl/FeAl3/Fe2Al5) layer formed by solution and diffusion between liquid-solid interface. The temperature range can be defined as the process temperatures of laser braze welding of Al-Fe materials. Selecting a higher laser heating temperature can improve the wettability of Al melt to steel surface, but the intermetallic phase layer is also thicker. When the laser heating temperature is so high that the joining surface of steel is melted, there is a crack trend in the joining area.

  9. Reducing the content of alloying elements in high-speed steel during heating in salt baths

    International Nuclear Information System (INIS)

    Barium chloride salt baths are primarily used for the high-temperature quench heating of a tool formed from high-speed steels. If the barium chloride melt should have a decarbonizing effect on the surface components that are heated in it, the authors maintain that it may also affect the content of alloying elements in the surface layers of high-speed-steel components that are heated in it. Commercial salt baths with a rectifier -- chemically pure magnesium fluoride -was used for the investigation. Cooling was accomplished in a caustic melt. Analysis of the results of investigation of the molybdenum, tungsten, and cobalt distributions in steel R9M4K8 as well as the tungsten and cobalt distributions in steel R9K5 indicated that the cobalt content does not diminish on heating to 12300C. A decrease in molybdenum content occurs in the surface layers during the quench heating of a tool formed from high-speed tungsten-molybdenum steel in a barium chloride salt bath after the required heating time, while a decrease in the tungsten content takes place with more prolonged hold times. It is shown to be possible to reduce or completely eliminate loss of alloying elements in the surface layers of a high-speedsteel tool during heat treatment when magnesium fluoride in combination with silicon carbide additives is used as a rectifier

  10. Corrosion behavior of EUROFER steel in flowing eutectic Pb?17Li alloy

    Science.gov (United States)

    Konys, J.; Krauss, W.; Voss, Z.; Wedemeyer, O.

    2004-08-01

    Reduced-activation-ferritic-martensitic (RAFM) steels are considered for application in fusion technology as structural materials. The alloy EUROFER 97 was developed on the basis of the experience gained with steels of the OPTIFER, MANET and F82H-mod. type. These alloys will be in contact with the liquid breeder Pb-17Li and their corrosion behavior is of significance for their successful application. Corrosion tests of EUROFER 97 in flowing Pb-17Li at 480 °C were performed up to about 12 000 h to evaluate the kinetics of the dissolution attack. The exposed samples were analysed by metallography and scanning electron microscopy (SEM) with EDX. The results show that EUROFER 97 is attacked by flowing liquid Pb-17Li with a flow velocity of about 0.3 m/s similar to the earlier examined steels and that the typical steel elements are dissolved. The observed attack is of uniform type with values of about 90 μm/year. The corrosion rate is a somewhat smaller for EUROFER compared to the other RAFM steels but with equal activation energy.

  11. Effect of Ti additions on micro-alloyed Nb TRIP steel

    Energy Technology Data Exchange (ETDEWEB)

    Jung, Jaehyuk; Lee, Seok-Jae; De Cooman, B.C. [Materials Design Laboratory, Graduate Institute of Ferrous Technology, Pohang University of Science and Technology, Pohang (Korea, Republic of); Kim, Sungil [Technical Research Laboratories, POSCO, Gwangyang (Korea, Republic of)

    2011-07-15

    In the present study, the influence of Ti-additions on the mechanical properties of Nb-microalloyed TRIP steel is investigated. Ti micro-alloying additions to multi-phase Nb TRIP steel result in a substantial increase of the yield strength and a reduction of strain hardening. The increase of the yield strength can be attributed mainly to grain refinement with a relatively small contribution of precipitation hardening. Based on general principles and well-known models of alloying strengthening, metallurgical reasons for the observed mechanical behavior of the steel can be formulated. The contribution of precipitation hardening is relatively small as Ti-addition result in the formation of coarse (Nb,Ti)(C,N) particles. The addition of Ti to a Nb-microalloyed TRIP steel leads to a pronounced enhancement of precipitation kinetics of (Nb,Ti)(C,N), thereby increasing their phase fraction. The precipitates coarsen and tend to form groups of aggregates of particles rather than single isolated particles with increasing intercritical annealing time. In addition, Ti-addition to Nb-microalloyed TRIP steel has a direct influence on the chemical composition of the precipitates, which become Ti-rich. (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  12. Atomically Thin Ordered Alloys of Transition Metal Dichalcogenides: Stability and Band Structures

    DEFF Research Database (Denmark)

    Pandey, Mohnish; Jacobsen, Karsten Wedel; Thygesen, Kristian Sommer

    2016-01-01

    to be close to zero for several alloys and below 20 meV/atom for all the alloys. We explore to what extent the electronic properties like the band gap and band edge positions of the alloy can be evaluated by taking the weighted average of the corresponding properties of the pristine systems. In general......, this approach works well with the only exception being Cr containing compounds. Because the calculated properties of the alloys are very similar to the weighted averages, we expect that the trends observed for the ordered alloys will also hold for more realistic disordered alloys......We explore the possibility of modulating the electronic band edges of the transition metal dichalcogenides (TMD) via alloying of different semiconductors within the same group (intra-group alloying). The stability of the ordered alloys is assessed from the calculated mixing enthalpy which is found...

  13. Effect of Nitriding on Fatigue Characteristics of Cr-Mo Alloy Steel

    Energy Technology Data Exchange (ETDEWEB)

    Oh, Kwang Keun; Kim, Jae Hoon; Choi, Hoon Seok [Chungnam National University, Daejeon (Korea, Republic of)

    2015-06-15

    CrMo alloy steel was nitrided using two types of processing methods, ion-nitriding processing and nitrocarburizing. Both processes were conducted for a duration of 30 min. To compare the surface hardness of the alloys created by the different processes , microhardness tests were conducted, and fatigue tests of each material were performed by a cantilever rotary bending fatigue test machine (Yamamoto, YRB 200) in the very high cycle regime (N > 10{sup 7}cycle). Fractography of the fractured surfaces was conducted by scanning electron microscopy - to observe the fracture mechanisms of very high cycle fatigue and the effect of the nitriding process on the fatigue characteristics.

  14. Structure and properties of surface layers obtained by alloying of the hot work tool steels

    OpenAIRE

    L.A. Dobrzański; A. Polok; E. Jonda

    2006-01-01

    Purpose: The aim of the present work was to study the microstructure and properties produced after laser alloying of the 55NiCrMoV7 and X40CrMoV5-1 an alloy hot-work tool steels.Design/methodology/approach: Structure investigation was performed using the light microscope Leica MEF4A supplied by Zeiss. Phase composition and crystallographic structure were determined by the X-ray diffraction method using the DRON 2.0. The measurements of microhardness have been performed using Shimadzu microhar...

  15. Cold weld cracking susceptibility of high strength low alloyed (HSLA steel NIONIKRAL 70

    Directory of Open Access Journals (Sweden)

    A. S. Tawengi

    2014-10-01

    Full Text Available In view of the importance of high strength low alloy (HSLA steels, particularly for critical applications such as offshore plat forms, pipeline and pressure vessels, this paper reports on an investigation of how to weld this type of steel without cold cracking. Using manual metal arc welding process and Tekken test (Y - Grove test has been carried out both to observe the cold cracking phenome non, and to investigate the influencing factors, such as preheating temperature and energy input, as well as electrode strength and diameter. How ever the results of the experiments show that there is a risk of cold cracking.

  16. Dynamic Recrystallization and Grain Growth Behavior of 20SiMn Low Carbon Alloy Steel

    Institute of Scientific and Technical Information of China (English)

    DONG Lanfeng; ZHONG Yuexian; MA Qingxian; YUAN Chaolong; MA Lishen

    2008-01-01

    A senes of thermodynamics experiments were used to optimize the hot forging process of 20SiMn low-carbon alloy steel.A dynamic recrystallization and grain growth model was developed for the 20SiMn steel for common production conditions of heavy forgings by doing a nonlinear curve fit of the expenment data.Optimized forging parameters were developed based on the control of the dynamic recrystallization and the MnS secondary phase.The data shows that the initial grain size and the MnS secondary phase all affect the behavior of the 20SiMn dynamic recrystallization and grain growth.

  17. Development of Forsterite Based Insulating Board for Alloy Steel Con—casting Tundish

    Institute of Scientific and Technical Information of China (English)

    ZHAOJi-zeng; ZHOULei; 等

    1994-01-01

    To meet the operation requirement of com-casting tundish for alloy steel.a forsterite based insulating board has been developed.The effects of binder ,fiber and other additives on the properties of the properties of the products have been described;the theoretial reason of assuring containing clear steel by using inorganic binder bonded forsterite based insulating board were also discussed;the mineral composition and microstructure of the products have been analyzed by means of XRD.SEM and microscope ,The results indicate that the forsteite based insulating board with excel-lent performance and dood application results has been obtained.

  18. BORATING OF CARBON AND ALLOY STEEL IN BOILING LAYER

    Directory of Open Access Journals (Sweden)

    N. Koukhareva

    2012-01-01

    Full Text Available The paper describes how to obtain boride coatings on steel 20, 4X5MФС, X12M being treated in a boiling layer of metallothermic powder environment. Phase and chemical compositions, hardness and wear- resistance of boride coatings

  19. FERRITE STRUCTURE AND MECHANICAL PROPERTIES OF LOW ALLOY DUPLEX STEELS

    Energy Technology Data Exchange (ETDEWEB)

    Hoel, R.H.; Thomas, G.

    1981-04-01

    The purpose of this communication is threefold. 1) To confirm the presence of and to characterize the precipitates in the ferrite phase of the base + Nb and base + Mo steels, 2) to study any possible variation in precipitate density as the martensitic volume fraction is changed and 3) to determine the level of precipitation strengthening.

  20. Literature Survey on the Stress Corrosion Cracking of Low-Alloy Steels in High Temperature Water

    Energy Technology Data Exchange (ETDEWEB)

    Seifert, H.P

    2002-02-01

    The present report is a summary of a literature survey on the stress corrosion cracking (SCC) behaviour/ mechanisms in low-alloy steels (LAS) in high-temperature water with special emphasis to primary-pressure-boundary components of boiling water reactors (BWR). A brief overview on the current state of knowledge concerning SCC of low-alloy reactor pressure vessel and piping steels under BWR conditions is given. After a short introduction on general aspects of SCC, the main influence parameter and available quantitative literature data concerning SCC of LAS in high-temperature water are discussed on a phenomenological basis followed by a summary of the most popular SCC models for this corrosion system. The BWR operating experience and service cracking incidents are discussed with respect to the existing laboratory data and background knowledge. Finally, the most important open questions and topics for further experimental investigations are outlined. (author)

  1. Laser fusion-brazing of aluminum alloy to galvanized steel with pure Al filler powder

    Science.gov (United States)

    Liu, Jia; Jiang, Shichun; Shi, Yan; Kuang, Yulin; Huang, Genzhe; Zhang, Hong

    2015-03-01

    The fusion-brazing connection of the dissimilar metal 5052 aluminum alloy/ST07Z steel was achieved by using the Nd:YAG laser with pure Al filler powder, and the effects of the laser power and powder feeding speed on the formation and mechanical properties of the resultant joints were investigated. The experimental results show that melting-brazing connection of 5052 aluminum alloy/galvanized steel can be successfully achieved, and the zinc plating layer has played the role of flux, assuring the brazing properties. The intermetallic compound layer was generated on the welded brazing interface. The joint exhibited a shear strength of 174 N/mm if the thickness of the intermetallic layer at the interface is about 6-7 μm.

  2. Mechanical and Microstructural Properties of Low Alloy-Treated Steel Used in Reinforced Concrete

    Directory of Open Access Journals (Sweden)

    F. Niang

    2012-03-01

    Full Text Available The aim of this communication is a comparative study of various types of reinforcements made of mild steel used in reinforced concretes in Senegal and Benin, in order to evaluate their standards. This benchmarking is based on the study of the mechanical and microstructural properties of the various selected products. The results obtained show that the ferrous alloys, used as reinforcing bars in Senegal and Benin, do not respect the performance criteria recommended in the building sector (standard NF has 35-016. In fact, the yield point, the elongation at rupture as well as the geometrical tolerances remain overall lower than the recommended values. The conclusions proposed prospects for heat treatments that should ensure optimization of the properties of the low alloy-treated steel used in the building sector.

  3. Influence of Boron on transformation behavior during continuous cooling of low alloyed steels

    Energy Technology Data Exchange (ETDEWEB)

    Terzic, A., E-mail: Adnan.Terzic@imf.tu-freiberg.de [Technische Universität Bergakademie Freiberg, Institute of Metal Forming, Bernhard-von-Cotta-Str. 4, 09596 Freiberg (Germany); Calcagnotto, M. [Salzgitter Mannesmann Forschung GmbH, Eisenhüttenstr. 99, 38239 Salzgitter (Germany); Guk, S. [Technische Universität Bergakademie Freiberg, Institute of Metal Forming, Bernhard-von-Cotta-Str. 4, 09596 Freiberg (Germany); Schulz, T. [Salzgitter Mannesmann Forschung GmbH, Eisenhüttenstr. 99, 38239 Salzgitter (Germany); Kawalla, R. [Technische Universität Bergakademie Freiberg, Institute of Metal Forming, Bernhard-von-Cotta-Str. 4, 09596 Freiberg (Germany)

    2013-11-01

    Abstracts: The phase transformation behavior during continuous cooling of low-carbon (LC) Boron-treated steels was studied. Furthermore, the influence of combining Boron with Nb or Ti or V on transformation kinetics was investigated. Additions of Boron to LC steels have a strong influence on the ferrite transformation. By adding 30 ppm Boron to a Boron-free reference alloy the suppressing effect on the ferrite transformation is most pronounced, whereas 10 ppm Boron has almost no effect and 50 ppm Boron the same effect as 30 ppm Boron. Thereby the critical Boron concentration for transformation kinetics in this alloying concept is 30 ppm. The combination of Boron with Ti shifts the phase fields to shorter times and increase the ferrite start temperature, whereas the combination of B+V and B+Nb only affects the ferrite start temperature. Hardness values are mostly influenced by the presence of Boron and strongly depend on the cooling rate.

  4. Research on CMT welding of nickel-based alloy with stainless steel

    Institute of Scientific and Technical Information of China (English)

    2007-01-01

    Cold Metal Transfer (CMT) welding technique is a new welding technique introduced by Fronius company. CMT welding of nickel-based alloy with stainless steel was carried out using CuSi3 filler wire in this paper. Effects of welding parameters, including welding current, welding speed, etc, on weld surface appearance were tested. Microstructure and mechanical properties of CMT weld were studied. The results show that the thickness of interface reaction layer of the nickel-based alloy is 14.3μm, which is only 4.33% of base material. The weld is made up of two phases,α-copper and iron-based solid solution. Rupture occurs initially at the welded seam near the edge of stainless steel in shear test. The maximum shear strength of the CuSi3 welded joint is 184.9MPa.

  5. Laser surface alloying of carbon steel and α-Fe with CrB2 particles

    International Nuclear Information System (INIS)

    A continuous wave, 2.5kW CO2 laser was used to surface alloy AISI 1045 steel and α-Fe with CrB2 by the powder injection method. CrB2 particles (100-150μ size) were injected into the molten bath of the substrate. The particles were partially dissolved in the bath, forming a melted layer of Fe-Cr-B-C. The solidification resulted in the formation of iron borides and undissolved CrB2 in the case of Armco iron and additional α-ferrite, γ-austenite and chromium carbides in the SAE 1045 steel. The hardness was high, 1250 HV in both cases, caused mainly by the borides. The overlap of the laser passes did not affect the hardness distribution throughout the alloyed layer. The structure and properties of the layers were studied using X-ray diffraction, Auger electron spectroscopy, scanning electron microscopy and optical microscopy. (orig.)

  6. Characterization of atom clusters in irradiated pressure vessel steels and model alloys

    International Nuclear Information System (INIS)

    In order to characterize the microstructural evolution of the iron solid solution under irradiation, two pressure vessel steels irradiated in service conditions and, for comparison, low copper model alloys irradiated with neutrons and electrons have been studied. The characterization has been carried out mainly thanks to small angle neutron scattering and atom probe experiments. Both techniques lead to the conclusion that clusters develop with irradiations. In Fe-Cu model alloys, copper clusters are formed containing uncertain proportions of iron. In the low copper industrial steels, the feature is more complex. Solute atoms like Ni, Mn and Si, sometimes associated with Cu, segregate as ''clouds'' more or less condensed in the iron solid solution. These silicides, or at least Si, Ni, Mn association, may facilitate the copper segregation although the initial iron matrix contains a low copper concentration. (authors). 24 refs., 3 figs., 2 tabs

  7. Effect Mo Addition on Corrosion Property and Sulfide Stress Cracking Susceptibility of High Strength Low Alloy Steels

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Woo Yong; Koh, Seong Ung; Kim, Kyoo Young [Pohang University of Science and Technology, Pohang (Korea, Republic of)

    2005-04-15

    The purpose of this work is to understand the effect of Mo addition on SSC susceptibility of high strength low alloy steels in terms of microstructure and corrosion property. Materials used in this study are high strength low alloy (HSLA) steels with carbon content of 0.04wt% and Mo content varying from 0.1 to 0.3wt%. The corrosion property of steels was evaluated by immersion test in NACE-TM01-77 solution A and by analyzing the growth behavior of surface corrosion products. SSC resistance of steels was evaluated using constant load test. Electrochemical test was performed to investigate initial corrosion rate. Addition of Mo increased corrosion rate of steels by enhancing the porosity of surface corrosion products. however, corrosion rate was not directly related to SSC susceptibility of steels

  8. 77 FR 43806 - Seamless Carbon and Alloy Steel Standard, Line, and Pressure Pipe From the People's Republic of...

    Science.gov (United States)

    2012-07-26

    ... International Trade Administration Seamless Carbon and Alloy Steel Standard, Line, and Pressure Pipe From the... Administrative Reviews and Request for Revocation in Part, 76 FR 82268 (December 30, 2011). The review covers 32... Charging Development Co., Ltd.; Wuxi Resources Steel Making Co., Ltd.; Wuxi Seamless Special Pipe Co.,...

  9. The influence of chemical constitution on abrasive wear of alloy cast steel Cr, Mo, V, Cu, Ni type

    International Nuclear Information System (INIS)

    In the work were presented some elements of a wide research programme of the influence of alloying element contents such as Cr, Mo, V on the abrasive wear of hot working cast steel. The dependence between the mass decrement quantity and the element contents on cast steel structure were shown. (author)

  10. Microstructural development at weld interface between Zr-based glassy alloy and stainless steel by resistance microwelding

    Science.gov (United States)

    Fukumoto, S.; Minami, M.; Soeda, A.; Matsushima, M.; Takahashi, M.; Yokoyama, Y.; Fujimoto, K.

    2012-08-01

    Zr-based bulk metallic glasses are expected to be welded to conventional structural alloys. Dissimilar welding of metallic glasses to stainless steel was carried out by resistance microwelding. The metallurgical analysis of the weld interface revealed the welding mechanism. A thin reaction layer was formed between the two liquid materials. The melting of stainless steel should be limited to obtain sound joints.

  11. Gas bubbles evolution peculiarities in ferritic-martensitic and austenitic steels and alloys under helium-ion irradiation

    NARCIS (Netherlands)

    Chernov, [No Value; Kalashnikov, AN; Kahn, BA; Binyukova, SY

    2003-01-01

    Transmission electron microscopy has been used to investigate the gas bubble evolution in model alloys of the Fe C system, ferritic-martensitic steels of 13Cr type, nickel and austenitic steels under 40-keV helium-ion it. radiation up to a fluence of 5 x 10(20) m(-2) at the temperature of 920 K. It

  12. Effect of welding process on the microstructure and properties of dissimilar weld joints between low alloy steel and duplex stainless steel

    Science.gov (United States)

    Wang, Jing; Lu, Min-xu; Zhang, Lei; Chang, Wei; Xu, Li-ning; Hu, Li-hua

    2012-06-01

    To obtain high-quality dissimilar weld joints, the processes of metal inert gas (MIG) welding and tungsten inert gas (TIG) welding for duplex stainless steel (DSS) and low alloy steel were compared in this paper. The microstructure and corrosion morphology of dissimilar weld joints were observed by scanning electron microscopy (SEM); the chemical compositions in different zones were detected by energy-dispersive spectroscopy (EDS); the mechanical properties were measured by microhardness test, tensile test, and impact test; the corrosion behavior was evaluated by polarization curves. Obvious concentration gradients of Ni and Cr exist between the fusion boundary and the type II boundary, where the hardness is much higher. The impact toughness of weld metal by MIG welding is higher than that by TIG welding. The corrosion current density of TIG weld metal is higher than that of MIG weld metal in a 3.5wt% NaCl solution. Galvanic corrosion happens between low alloy steel and weld metal, revealing the weakness of low alloy steel in industrial service. The quality of joints produced by MIG welding is better than that by TIG welding in mechanical performance and corrosion resistance. MIG welding with the filler metal ER2009 is the suitable welding process for dissimilar metals jointing between UNS S31803 duplex stainless steel and low alloy steel in practical application.

  13. Studies of oxide reduction and nitrogen uptake in sintering of chromium-alloyed steel powder

    OpenAIRE

    Bergman, Ola

    2008-01-01

    The powder metallurgy (PM) process route is very competitive for mass production of structural steel components with complex shape, due to efficient material utilisation, low energy consumption, and short overall production time. The most commonly used alloying elements are the processing friendly metals Cu, Ni and Mo. However, the prices for these metals are today high and volatile, which threatens to make the PM process less competitive compared to conventional metal forming processes. Cons...

  14. Theoretical calculation of the impact work in the alloying non-quenched and tempered steel

    Institute of Scientific and Technical Information of China (English)

    LIU; Zhilin; LIN; Cheng

    2006-01-01

    Coupled with hot-continuous rolling technology and based on the calculation of the finishing rolling impact work in the non-quenched and tempered Si-Mn steel, the calculations of the finishing rolling impact work in the alloying non-quenched and tempered steel with the elements of Cr, Ni, Mo, W, Cu, V, Nb and Ti are studied with the covalent electron number nA of the strongest bond in alloying phases, the smallest electron density difference △ρ of phase interfaces, and the number of atom states σ(σ') which keep the interface electron density continuous. The calculated results show that the finishing rolling impact work of the alloying non-quenched and tempered steel intensely depends on strengthening mechanisms. The solution strengthening, interface strengthening, precipitation strengthening of pearlite, and dispersion strengthening will result in the decrease of the finishing rolling impact work; the refinement strengthening, the precipitation strengthening of V, Nb and Ti in o-Fe-C-V(Nb, Ti), and the residual austenite containing Ni on the boundary of α-Fe-C-Ni will increase the impact work; and the increments or decrements can be calculated with nA, △ρ, σ(σ') and weights of alloying elements. The calculation formulas of the finishing rolling impact work in this paper are intergraded with the suggested ones of the finishing rolling tensile strength, yield strength, and elongation of the non-quenched and tempered steel. The calculated results agree well with the measured ones.

  15. Fracture toughness of welded joints of a high strength low alloy steel

    International Nuclear Information System (INIS)

    The fracture toughness of the different regions of welded joints of a high strength low alloy steel, Niocor 2, was evaluated at different temperatures and compared with the toughness of the base metal. The studied regions were: the weld metal, fusion boundary and heat affected zone. The welding process used was the manual metal arc. It is shown that the weld metal region has the highest toughness values. (Author)

  16. Investigations for assessing the proneness to dynamic strain ageing of low alloy steels

    International Nuclear Information System (INIS)

    Plastic deformation of four low-alloy steels (four basic materials and two welding materials) for pipeline construction was investigated with regard to the influence of dynamic strain ageing on the localisation of deformation. First, the materials were classified in terms of ageing resistance on the basis of mechanical materials tests. After this, plastic strain was induced in the materials, and local deformations were analyzed. The deformation process was analyzed in detail

  17. Development of welding consumables for wet underwater welding of high-alloy corrosion-resistant steel

    OpenAIRE

    Kakhovskyi, Yurij; Kakhovskyi, Mykola

    2015-01-01

    This paper discusses a technology of mechanized wet underwater welding of high-alloy corrosion-resistance steel. The main aim of the investigation is development of self-shielded flux-cored wire for wet underwater welding for the first time in the world practice. A mathematical method of experiment design was used for determination of quantity and quality characteristics. Besides, quantitive and qualitative indices of welding-technological characteristics such as weld metal gas saturation, st...

  18. Microstructure evolution during laser-aided direct metal deposition of alloy tool steel

    International Nuclear Information System (INIS)

    Laser-aided direct metal deposition has been used to form an alloy tool steel coating. The microstructure of the deposited material was analyzed by means of scanning electron microscopy and transmission electron microscopy. The formation relationships among martensite, ε-carbide, cementite and austenite in the coating are discussed. The effect of rapid solidification associated with direct metal deposition on lattice parameters is also reported.

  19. Velocity hardening influence on the martensite transformation nature in constructional average alloy steel

    Institute of Scientific and Technical Information of China (English)

    Tsellermaer; V.; V.; Popova; N.; A.; Klimashin; S.; I.; Tihonikova; O.; V.; Konovalov; S.; V.; Kozlov; E.; V.; Gromov; V.; E.

    2005-01-01

    The quantitative study of the hardening velocity influence on the α-phase morphology in 30CrNi3MoVA (0.3% C, 1% Cr,3% Ni, 1% Mo, 1% V) cast average alloy steel after gomogenization (1125℃, 13 h), normalizing (980℃, 10 h) and high tempering (660℃, 10 h. with cooling on air) is the aim of this work.……

  20. Velocity hardening influence on the martensite transformation nature in constructional average alloy steel

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    @@ The quantitative study of the hardening velocity influence on the α-phase morphology in 30CrNi3MoVA (0.3% C, 1% Cr,3% Ni, 1% Mo, 1% V) cast average alloy steel after gomogenization (1125℃, 13 h), normalizing (980℃, 10 h) and high tempering (660℃, 10 h. with cooling on air) is the aim of this work.

  1. Automated equipment for determining the magnetic susceptibility of steels and alloys

    Directory of Open Access Journals (Sweden)

    G. V. Snizhnoi

    2012-10-01

    Full Text Available Automated equipment for determining the susceptibility of steels and alloys proposed. The principle of operation of equipment units and their main characteristics are presented. Microprocessor system with AVR microcontrollers from ATMEL for equipment used. The algorithm of the program a microprocessor system for automatic operation of equipment considered. Dependence of the current compensation of the current force field as a text file on your computer equipment can be formed.

  2. SAW surfacing of low-alloyed steel with super-ferrite additional material

    OpenAIRE

    Klimpel, A; T. Kik; J. Górka; A. Czupryński; P. Sitarz

    2009-01-01

    Purpose: of these researches was to investigate influence of heat input in SAW surfacing of low-alloyed steel with super-ferrite filler material on quality of deposits.Design/methodology/approach: the quality of single and multilayer, stringer beads was assessed by metallographic examinations, stresses measurements and hardness tests.Findings: due to the fact that it was used at automated surfacing stand, the analysis of properties of the deposits was performed for single and multilayer, str...

  3. The diffusion of chromium in a duplex alloy steel

    International Nuclear Information System (INIS)

    Diffusion of chromium in a duplex stainless steel containing approximately 8% ferrite has been investigated in the temperature range 600 to 10000C using the standard serial sectioning technique. The resulting concentration profiles exhibited up to four distinct regions. The two main regions are attributed to volume diffusion in the austenite and ferrite phases, the other zones being due to short circuiting paths. Volume diffusion in the austenite phase is in good agreement with chromium diffusion in Type 316 steel. The chromium diffusion coefficient in the ferrite phase of approximate composition 25 wt % Cr, 5 wt % Ni is given by: Dsub(α) = (6.0(+11,-3)) x 10-6 exp - ((212+-5)/RT) m2s-1 the activation energy being expressed in kJ.mol-1. Little evidence was found for enhanced chromium diffusion along austenite/ferrite interface boundaries. (author)

  4. Mechanical and tribological properties of the surface layer of the hot work tool steel obtained by laser alloying

    OpenAIRE

    K. Lukaszkowicz; A. Kriz; E. Jonda; L.A. Dobrzański

    2007-01-01

    Purpose: The paper presents results on the mechanical and tribological properties examinations of the X40CRMoV5-1 hot work alloy tool steel alloyed with carbide powders using the high power diode laser (HPDL).Design/methodology/approach: Metallographic examinations of the material structures after laser alloying of their surface layer were made on light microscope. The tribological wear relationships using pin-on-disc test were specified for surface layers subject to laser treatment, determi...

  5. Engineering phase transitions in Heusler alloys: Towards better magnetic refrigerants

    Science.gov (United States)

    Shamberger, Patrick Jacob

    The central question investigated in this dissertation is whether, through appropriate materials design, a martensitic transformation (MT) can enhance the magnetocaloric effect (MCE) of a material and improve its performance as a magnetic refrigerant. Very large magnetocaloric effects have been demonstrated near first-order magneto-structural phase transitions where there is a large difference in magnetization between parent and daughter phases. Despite this potential, first-order phase transitions are typically associated with hysteresis losses and kinetic limitations that may detract from the performance of magnetic refrigerants. The role of these factors in material performance is generally underappreciated. Here, we evaluate different aspects of the overall performance of one model material system, Ni-Mn-Sn Heusler alloys. Our aim is to establish key limitations that may exist in this model system, and to identify potential approaches to reducing these limitations. This dissertation is divided into four principle sections: 1) Alloy Structure. Here, we report phase stability, lattice parameters, and atomic ordering across various sections in the Ni-Mn-Sn ternary. Furthermore, we calculate the Bain strain associated with the phase transformation, and observe no evidence for intermediate phases in the phase transformation. 2) MT Kinetics. Isothermal and constant cooling rate transformations behave consistently with a nucleation-limited MT. We demonstrate that nucleation is distributed over a range of temperatures due to compositional and elastic strain energy heterogeneities in the system. 3) MT Hysteresis. We quantify the hysteresis loss associated with the temperature- and magnetic field-induced MT, and demonstrate the limitations that hysteresis exerts on the extent of transformation (and thus, on the MCE). Furthermore, we consider the role of transformation strain on the hysteresis associated with the first-order phase transition. 4) Low field magnetic anomaly

  6. Flow Stress Analysis and Hot Bending of P11 Alloy Steel

    Science.gov (United States)

    Ma, Fu-ye; Jin, Kai; Wang, Hui; Pei, Wen-Jiao; Tang, Xiao-Bin; Tao, Jie; Guo, Xun-Zhong

    2016-07-01

    Based on the growing application value of the P11 alloy steel in the nuclear power field, its dynamic recrystallization (DRX) behavior was firstly investigated by means of isothermal hot compression experiments, under the conditions of a testing temperature range between 800 and 950 °C, and a strain rate range between 0.01 and 2/s. Furthermore, optical microscopy and transmission electron microscopy were also employed to analyze the effect of the mechanism of the strain rate on DRX. The results indicated that the grain size could be significantly refined with the increase of strain rate. Also, the recrystallized volume fraction was increased and the dislocation density decreased with the decrease of strain rate, for the same strain values. Subsequently, numerical simulations, under the assistance of experimental results on DRX behavior, were successfully used to study the hot push bending process and simultaneously obtain the processing parameters of the actual work-pieces. Finally, some comparative analyses were performed and discussed in parallel with the deformed actual work-pieces. The EBSD results on the deformed P11 alloy steel were emphasized for exploring the forming properties of this alloy steel.

  7. Flow Stress Analysis and Hot Bending of P11 Alloy Steel

    Science.gov (United States)

    Ma, Fu-ye; Jin, Kai; Wang, Hui; Pei, Wen-Jiao; Tang, Xiao-Bin; Tao, Jie; Guo, Xun-Zhong

    2016-09-01

    Based on the growing application value of the P11 alloy steel in the nuclear power field, its dynamic recrystallization (DRX) behavior was firstly investigated by means of isothermal hot compression experiments, under the conditions of a testing temperature range between 800 and 950 °C, and a strain rate range between 0.01 and 2/s. Furthermore, optical microscopy and transmission electron microscopy were also employed to analyze the effect of the mechanism of the strain rate on DRX. The results indicated that the grain size could be significantly refined with the increase of strain rate. Also, the recrystallized volume fraction was increased and the dislocation density decreased with the decrease of strain rate, for the same strain values. Subsequently, numerical simulations, under the assistance of experimental results on DRX behavior, were successfully used to study the hot push bending process and simultaneously obtain the processing parameters of the actual work-pieces. Finally, some comparative analyses were performed and discussed in parallel with the deformed actual work-pieces. The EBSD results on the deformed P11 alloy steel were emphasized for exploring the forming properties of this alloy steel.

  8. Corrosion behaviour of stainless steel alloys in molten (Na,K)NO{sub 3} eutectic mixture

    Energy Technology Data Exchange (ETDEWEB)

    Attia, A.A. [Zagazik Univ. (Egypt). Chem. Dept.; Ali, A.-H.; Masri, A.N.A.; Baraka, A.M. [High Technological Inst., Ramadan Tenth City (Egypt)

    1999-09-01

    In the present article it is aimed to study the corrosion (oxidation) behaviour of two types of stainless steel alloys, ferritic (15.03% Cr) and austenitic (20.45% Cr, 8.37% Ni), in molten (Na, K)NO{sub 3} mixture at different temperatures ranging from 400-600 C. In this investigation the technique of potential-time and current-time under the open-circuit conditions is employed. The variation of potential with time at different temperatures was explained in terms of propagation and thickening of oxide film with a rate which depends on the temperature. It is assumed that the oxide film thickens according to a solid state mechanism under high field strength. The activation energy of the corrosion process was estimated using Arrhenius plots. The calculated values are found to be 21.36 KJ/mol for the ferritic stainless steel alloy and 23.3 KJ/mol for the austenitic one. The low value of activation energy signifies diffusion controlled process occurring in the oxide matrix. The corrosion products formed on the surface of stainless steel alloys are identified by X-ray diffraction analysis. Also the melt is chemically analysed to detect the amount of Fe, Cr and Ni in the melt after the completion of experiment. (orig.)

  9. Nickel-coated Steel Stud to Aluminum Alloy Joints Made by High Frequency Induction Brazing

    Institute of Scientific and Technical Information of China (English)

    GE Jiaqi; WANG Kehong; ZHANG Deku; WANG Jian

    2015-01-01

    Nickel-coated 45 steel studs and 6061 aluminum alloy with 4047 Al alloy foil asfi ller metal were joined by using high frequency induction brazing. The microstructure of Fe/Al brazed joint was studied by means of optical microscopy (OM), scanning electron microscope (SEM), energy dispersive X-ray (EDX), and X-ray diffraction (XRD). Results showed that 45 steel stud and 6061 aluminum alloy could be successfully joined by high frequency induction brazing with proper processing parameters. The bonding strength of the joint was of the order of 88 MPa. Ni coating on steel stud successfully avoided the generation of Fe-Al intermetallic compound which is brittle by blocking the contact between Al and Fe. Intermetallic compounds, i e,Al3Ni2, Al1.1Ni0.9 and Al0.3Fe3Si0.7 presented in Al side, FeNi and Fe-Al-Ni ternary eutectic structure were formed in Fe side. The micro-hardness in intermetallic compound layer was 313 HV. The joint was brittle fractured in the intermetallic compounds layer of Al side, where plenty of Al3Ni2 intermetallic compounds were distributed continuously.

  10. Fatigue strain-life behavior of carbon and low-alloy steels, austenitic stainless steels, and Alloy 600 in LWR environments

    Energy Technology Data Exchange (ETDEWEB)

    Keisler, J.; Chopra, O.K.; Shack, W.J. [Argonne National Lab., IL (United States)

    1995-08-01

    The existing fatigue strain vs. life (S-N) data, foreign and domestic, for carbon and low-alloy steels, austenitic stainless steels, and Alloy 600 used in the construction of nuclear power plant components have been compiled and categorized according to material, loading, and environmental conditions. Statistical models have been developed for estimating the effects of the various service conditions on the fatigue life of these materials. The results of a rigorous statistical analysis have been used to estimate the probability of initiating a fatigue crack. Data in the literature were reviewed to evaluate the effects of size, geometry, and surface finish of a component on its fatigue life. The fatigue S-N curves for components have been determined by adjusting the probability distribution curves for smooth test specimens for the effect of mean stress and applying design margins to account for the uncertainties due to component size/geometry and surface finish. The significance of the effect of environment on the current Code design curve and on the proposed interim design curves published in NUREG/CR-5999 is discussed. Estimations of the probability of fatigue cracking in sample components from BWRs and PWRs are presented.

  11. Fatigue strain-life behavior of carbon and low-alloy steels, austenitic stainless steels, and Alloy 600 in LWR environments

    International Nuclear Information System (INIS)

    The existing fatigue strain vs. life (S-N) data, foreign and domestic, for carbon and low-alloy steels, austenitic stainless steels, and Alloy 600 used in the construction of nuclear power plant components have been compiled and categorized according to material, loading, and environmental conditions. Statistical models have been developed for estimating the effects of the various service conditions on the fatigue life of these materials. The results of a rigorous statistical analysis have been used to estimate the probability of initiating a fatigue crack. Data in the literature were reviewed to evaluate the effects of size, geometry, and surface finish of a component on its fatigue life. The fatigue S-N curves for components have been determined by adjusting the probability distribution curves for smooth test specimens for the effect of mean stress and applying design margins to account for the uncertainties due to component size/geometry and surface finish. The significance of the effect of environment on the current Code design curve and on the proposed interim design curves published in NUREG/CR-5999 is discussed. Estimations of the probability of fatigue cracking in sample components from BWRs and PWRs are presented

  12. Influence of yttrium on laser surface alloying organization of 40Cr steel

    Institute of Scientific and Technical Information of China (English)

    WU Anqi; LIU Qibin; QIN Shuijie

    2011-01-01

    In order to improve the performance of the metal rollers,Mo+Y2O3 alloy powders were used to coat uniformly on the surface of 40Cr steel roller substrates for the laser surface alloying treatment by a CO2 laser,The results showed that many good consequences were obtained after adding the rare earth oxide Y2O3.The crystal grains of the alloy layer were significantly refine& The boundary of crystal grains was strengthened.The uniformity and density of the rnicrostructure were increased.The hardness and wearing resistance of the alloy layer were considerably improved.The valence electron structure analysis of the alloy layer was made by the empirical electron theory of solids and molecules (EET).The calculated results demonstrated that Y should be mixed in the first stage and Fe should be in the eighteenth hybrid bands.The analyzed outcomes illustrated that the electron theory of the solid solution shows the strengthening effect on the alloying layer,which has enhanced bond and confirmed the experimental results.

  13. Laser Surface Alloying of 316L Stainless Steel with Ru and Ni Mixtures

    Directory of Open Access Journals (Sweden)

    M. B. Lekala

    2012-01-01

    Full Text Available The surfaces of AISI 316L stainless steel were laser alloyed with ruthenium powder and a mixture of ruthenium and nickel powders using a cw Nd:YAG laser set at fixed operating parameters. The microstructure, elemental composition, and corrosion characteristics of the alloyed zone were analyzed using optical and scanning electron microscopy (SEM, energy dispersive X-ray spectroscopy (EDX, and corrosion potential measurements. The depth of alloyed zone was measured using the AxioVision program and found to be approximately 1.8 mm for all the alloyed specimens. Hardness profile measurements through the surface-substrate interface showed a significant increase from 160 HV for the substrate to a maximum of 247 HV for the alloyed layer. The sample laser alloyed with 80 wt% Ni-20 wt% presented the most noble corrosion potential (Ecorr of −0.18 V and the lowest corrosion current density (icorr.

  14. Dissimilar metals TIG welding-brazing of aluminum alloy to galvanized steel

    Institute of Scientific and Technical Information of China (English)

    San-bao LIN; Jian-ling SONG; Guang-chao MA; Chun-li YANG

    2009-01-01

    Dissimilar metals TIG welding-brazing of aluminum alloy to galvanized steel was investigated, and the wettability and spreadability of aluminum filler metal on the steel surface were analyzed. The resultant joint was characterized in order to determine the brittle intermetallic compound (IMC) in the interfacial layer, and the mechan-ical property of the joint was tested. The results show that the zinc coated layer can improve the wettability and spreadability of liquid aluminum filler metal on the surface of the steel, and the wetting angle can reach less than 20°. The lap joint has a dual characteristic and can be divided into a welding part on the aluminum side and a brazing part on the steel side. The interfacial IMC layer in the steel side is about 9.0 μm in thickness, which transfers from (α-Al + FeAl3) in the welded seam side to (Fe2Al5+ FeAl2) and (FeAl2+ FeAl) in the steel side. The crystal grain of the welded seam is obviously larger in size in the aluminum side. The local incomplete brazing is found at the root of the lap joint, which weakens the property of the joint. The fracture of the joint occurs at the root and the average tensile strength reaches 90 MPa.

  15. Boronization and Carburization of Superplastic Stainless Steel and Titanium-Based Alloys

    Directory of Open Access Journals (Sweden)

    Masafumi Matsushita

    2011-07-01

    Full Text Available Bronization and carburization of fine-grain superplastic stainless steel is reviewed, and new experimental results for fine grain Ti88.5Al4.5V3Fe2Mo2 are reported. In superplastic duplex stainless steel, the diffusion of carbon and boron is faster than in non-superplastic duplex stainless steel. Further, diffusion is activated by uniaxial compressive stress. Moreover, non-superplastic duplex stainless steel shows typical grain boundary diffusion; however, inner grain diffusion is confirmed in superplastic stainless steel. The presence of Fe and Cr carbides or borides is confirmed by X-ray diffraction, which indicates that the diffused carbon and boron react with the Fe and Cr in superplastic stainless steel. The Vickers hardness of the carburized and boronized layers is similar to that achieved with other surface treatments such as electro-deposition. Diffusion of boron into the superplastic Ti88.5Al4.5V3Fe2Mo2 alloy was investigated. The hardness of the surface exposed to boron powder can be increased by annealing above the superplastic temperature. However, the Vickers hardness is lower than that of Ti boride.

  16. Softening Behavior of Hardness and Surface Fatigue of Rolling-Sliding Contact in the Case of Developed Alloy Steels

    Science.gov (United States)

    Redda, Daniel Tilahun; Nakanishi, Tsutomu; Deng, Gang

    To get high performance, downsizing and weight saving of the power transmission systems, the improvement of machine elements has been required. In this study, case-carburized gear materials for a high load-carrying capacity were developed. Low-alloyed steels with 1%Cr-0.2%Mo, 1%Cr-0.2%Mo-1%Si and 1%Cr-0.2%Mo-2%Ni (Cr-Mo steel, Cr-Mo-Si steel and Cr-Mo-Ni steel) were melted in a hypoxia vacuum. Test rollers were made of the developed steels, and they were carburized (Type A and Type B), hardened and tempered. Heating retention tests were carried out to investigate the softening behavior of hardness at high heating temperatures in the case of the developed steels. Roller tests were conducted under the rolling-sliding contact and high-load conditions to study the surface fatigue of the developed steels. From the obtained test results, it was found that the softening behavior of surface hardness at high temperatures in the cases of Cr-Mo-Si steel (Type A) and Cr-Mo-Ni steel (Type B) is lower than that in the cases of Cr-Mo steel (Type A) and Cr-Mo steel (Type B). In the cases of Cr-Mo-Si steel (A) and Cr-Mo-Ni steel (B), micro- and small-pitting area ratios are smaller and large-pitting life is longer than those in the cases of Cr-Mo steel(A) and Cr-Mo steel(B) under the same carburizing treatment method and high-load conditions. Furthermore, the relationship between the softening behavior of surface hardness on the heating pattern and the surface fatigue on the rolling-sliding contact of the developed alloy steels was clarified.

  17. Effect of Cr content on the corrosion performance of low-Cr alloy steel in a CO2 environment

    Science.gov (United States)

    Xu, Lining; Wang, Bei; Zhu, Jinyang; Li, Wei; Zheng, Ziyi

    2016-08-01

    Low-Cr alloy steel demonstrates lower corrosion rate than does C steel in a high-temperature and high-pressure CO2-containing environment. This study aimed to clarify the role of the Cr content in mitigating corrosion and reports the performance of 1%Cr, 2%Cr, 3%Cr, 4%Cr, 5%Cr, and 6.5%Cr steels. The results show that low-Cr alloy steel in CO2 at 80 °C and 0.8 MPa possesses spontaneous prepassivation characteristics when the Cr content is 3% or higher. Furthermore, the formation and peel-off of a prepassivation film on 3%Cr-6.5%Cr steels surfaces during polarization demonstrate that adequate amount of Cr in the steel substrate can cause protective layer. The main component of prepassivation film on 3%Cr steel is Cr(OH)3. Thus, the role of Cr is revealed. An adequate amount of Cr in the steel substrate causes the formation of protective Cr(OH)3 layer, which helps low-Cr steel to possess prepassivation characteristics. Prepassivation is the reason why low-Cr steel has a lower corrosion rate than C steel.

  18. Laser surface treatment of the hot work tool steel alloyed with TaC and VC carbide powders

    OpenAIRE

    L.A. Dobrzański; E. Jonda; Klimpel, A

    2009-01-01

    Purpose: The paper presents investigation results of the structure and properties of alloying surface layer of the X40CrMoV5-1 hot work tool steel, using the high power diode laser HPDL. Tantalum and vanadium carbides powders were used for alloying and the X40CrMoV5-1 conventionally heat treated steel was used as reference material.Design/methodology/approach: Metallographic examinations of the material structures after laser alloying surface layer were made on light microscope and transmissi...

  19. Crack growth kinetics across weld interface between Alloy 182 and low Alloy steel and that between Alloy 182 and metals to simulate weld dilution zone

    International Nuclear Information System (INIS)

    Crack growth kinetics across weld interface between Alloy 182 and LAS (Low Alloy Steel) and that between Alloy 182 and Metals to simulate weld dilution zone was investigated by CBB (Creviced Bent Beam) test. The main objective of this study is to investigate dynamic influence for a crack initiated in Alloy 182 to propagate into LAS. Specimens were subjected to CBB tests for 2000 h each in simulated BWR water with 8 ppm of dissolved oxygen. Mechanics conditions were described by equivalent stress intensity factor KJ values which are J values from elasto-plastic analysis. In small-sized specimens of 2 mm in thickness, cracks which initiated in Alloy 182 propagated into Metal21-4 (20%Ni, 4%Cr), while they did not into Metal21-5 (10%Ni, 2%Cr). In moderate-sized specimens of 10 mm in thickness, cracks did advance into Metals and LAS under KJ values more than 80 MPa·m1/2. (author)

  20. ATR-A1 irradiation experiment on vanadium alloys and low activation steels

    Energy Technology Data Exchange (ETDEWEB)

    Tasi, H.; Strain, R.V.; Gomes, I.; Hins, A.G.; Smith, D.L.

    1996-04-01

    To study the mechanical properties of vanadium alloys under neutron irradiation at low temperatures, an experiment was designed and constructed for irradiation in the Advanced Test Reactor (ATR). The experiment contained Charpy, tensile, compact tension, TEM, and creep specimens of vanadium alloys. It also contained limited low-activation ferritic steel specimens as part of the collaborative agreement with Monbusho of Japan. The design irradiation temperatures for the vanadium alloy specimens in the experiment are {approx}200 and 300{degrees}C, achieved with passive gap-gap sizing and fill gas blending. To mitigate vanadium-to-chromium transmutation from the thermal neutron flux, the test specimens are contained inside gadolinium flux filters. All specimens are lithium-bonded. The irradiation started in Cycle 108A (December 3, 1995) and is expected to have a duration of three ATR cycles and a peak influence of 4.4 dpa.

  1. Effect of Mn Content and Solution Annealing Temperature on the Corrosion Resistance of Stainless Steel Alloys

    Directory of Open Access Journals (Sweden)

    Ihsan-ul-Haq Toor

    2014-01-01

    Full Text Available The corrosion behavior of two specially designed austenitic stainless steels (SSs having different Nickel (Ni and Manganese (Mn contents was investigated. Prior to electrochemical tests, SS alloys were solution-annealed at two different temperatures, that is, at 1030°C for 2 h and 1050°C for 0.5 h. Potentiodynamic polarization (PD tests were carried out in chloride and acidic chloride, whereas linear polarization resistance (LPR and electrochemical impedance spectroscopy (EIS was performed in 0.5 M NaCl solution at room temperature. SEM/EDS investigations were carried out to study the microstructure and types of inclusions present in these alloys. Experimental results suggested that the alloy with highest Ni content and annealed at 1050°C/0.5 hr has the highest corrosion resistance.

  2. Electroless plating of Ni-Zn(Fe)-P alloy on carbon steel sheets

    Institute of Scientific and Technical Information of China (English)

    WANG Sen-lin; WU Hui-huang

    2004-01-01

    The autocatalytic deposition of Ni-Zn(Fe)-P alloys were carried out on carbon steel sheets from bath containing nickel sulfate, zinc sulfate, sodium hypophosphite, sodium citrate and boric acid. The effects of pH and mole ratio of NiSO4/ZnSO4 on the deposition rate and the composition of deposit were studied. It is found that the presence of zinc sulfate in the bath has an inhibitory effect on the alloy deposition. As a consequence, the mole fraction of zinc in the deposits never reaches high value, which is less than 18.0%. The structure and surface morphology of Ni-Zn(Fe)-P coatings were charactered by XRD and SEM. The alloys plated at all conditions consist of amorphous phase coexisting with a crystalline cubic Ni phase. The surface morphology of coating is dependent on the deposition parameters.

  3. Solid particle erosion of steels and nickel based alloys candidates for USC steam turbine blading

    Energy Technology Data Exchange (ETDEWEB)

    Cernuschi, Federico; Guardamagna, Cristina; Lorenzoni, Lorenzo [ERSE SpA, Milan (Italy); Robba, Davide [CESI, Milan (Italy)

    2010-07-01

    The main objective of COST536 Action is to develop highly efficient steam power plant with low emissions, from innovative alloy development to validation of component integrity. In this perspective, to improve the operating efficiency, materials capable of withstanding higher operating temperatures are required. For the manufacturing of components for steam power plants with higher efficiency steels and nickel-based alloys with improved oxidation resistance and creep strength at temperature as high as 650 C - 700 C have to be developed. Candidate alloys for manufacturing high pressure steam turbine diaphragms, buckets, radial seals and control valves should exhibit, among other properties, a good resistance at the erosion phenomena induced by hard solid particles. Ferric oxide (magnetite) scales cause SPE by exfoliating from boiler tubes and steam pipes (mainly super-heaters and re-heaters) and being transported within the steam flow to the turbine. In order to comparatively study the erosion behaviour of different materials in relatively short times, an accelerated experimental simulation of the erosion phenomena must be carried out. Among different techniques to induce erosion on material targets, the use of an air jet tester is well recognised to be one of the most valid and reliable. In this work the results of SPE comparative tests performed at high temperatures (550 C, 600 C and 650 C) at different impaction angles on some steels and nickel based alloys samples are reported. (orig.)

  4. The microstructural, mechanical, and fracture properties of austenitic stainless steel alloyed with gallium

    Science.gov (United States)

    Kolman, D. G.; Bingert, J. F.; Field, R. D.

    2004-11-01

    The mechanical and fracture properties of austenitic stainless steels (SSs) alloyed with gallium require assessment in order to determine the likelihood of premature storage-container failure following Ga uptake. AISI 304 L SS was cast with 1, 3, 6, 9, and 12 wt pct Ga. Increased Ga concentration promoted duplex microstructure formation with the ferritic phase having a nearly identical composition to the austenitic phase. Room-temperature tests indicated that small additions of Ga (less than 3 wt pct) were beneficial to the mechanical behavior of 304 L SS but that 12 wt pct Ga resulted in a 95 pct loss in ductility. Small additions of Ga are beneficial to the cracking resistance of stainless steel. Elastic-plastic fracture mechanics analysis indicated that 3 wt pct Ga alloys showed the greatest resistance to crack initiation and propagation as measured by fatigue crack growth rate, fracture toughness, and tearing modulus. The 12 wt pct Ga alloys were least resistant to crack initiation and propagation and these alloys primarily failed by transgranular cleavage. It is hypothesized that Ga metal embrittlement is partially responsible for increased embrittlement.

  5. The measurement of phosphorus in low alloy steels by electrochemical methods

    International Nuclear Information System (INIS)

    The oscillo-polarographic method reported by Chen for the determination of phosphorus in silicates, iron ores, carbonates and tea leaves has been thoroughly studied and enhanced in view of the determination of P in various steels. Together with a carefully selected sample dissolution method, the chromatographic separation reported by Hanada et al. for eliminating the matrix has also been examined. The results of these investigations allowed finding out a path towards the successful electrochemical measurement of P in low alloy ferritic steels without eliminating the matrix. The limit of detection is 5.2 micro gram-1 in the metal. The precision ranges between 5 and 15 % relative to the mean measured values. The finely tuned method has been successfully validated using five NIST standard steels. The chromatographic method remains an option for addressing other metals in the future, should they contain unacceptable levels of possibly interfering elements.. Detailed experimental procedures are given.

  6. Mechanism of laser welding on dissimilar metals between stainless steel and W-Cu alloy

    Institute of Scientific and Technical Information of China (English)

    Kai Chen; Zhiyong Wang; Rongshi Xiao; Tiechuan Zuo

    2006-01-01

    @@ CO2 laser is employed to join a piece of powder metallurgical material (PMM) to a stainless steel in butt joint welding mode. The powder Ni35, as a filler powder, is used. The weld metal comes from three parts of stainless steel, powder Ni35, and Cu in W-Cu PMM. It is indicated that some parts of the W-Cu base metal are heated by laser and the metal Cu at the width of 0.06-0.12 mm from the edge is melted into the melting pool in the laser welding process. The formation of firm weld joint is just because that the melting liquid metal could fill the position occupied by metal Cu and surround the metal W granules fully. The analysis results indicate that the mechanism of the laser welding for stainless steel and W-Cu alloy is a special mode of fusion-brazing welding.

  7. The measurement of phosphorus in low alloy steels by electrochemical methods

    Energy Technology Data Exchange (ETDEWEB)

    Rahier, A.; Campsteyn, A.; Verheyen, E.; Verpoucke, G.

    2008-08-15

    The oscillo-polarographic method reported by Chen for the determination of phosphorus in silicates, iron ores, carbonates and tea leaves has been thoroughly studied and enhanced in view of the determination of P in various steels. Together with a carefully selected sample dissolution method, the chromatographic separation reported by Hanada et al. for eliminating the matrix has also been examined. The results of these investigations allowed finding out a path towards the successful electrochemical measurement of P in low alloy ferritic steels without eliminating the matrix. The limit of detection is 5.2 micro gram{sup -1} in the metal. The precision ranges between 5 and 15 % relative to the mean measured values. The finely tuned method has been successfully validated using five NIST standard steels. The chromatographic method remains an option for addressing other metals in the future, should they contain unacceptable levels of possibly interfering elements.. Detailed experimental procedures are given.

  8. Systematic investigation of the fatigue performance of a friction stir welded low alloy steel

    International Nuclear Information System (INIS)

    Highlights: • The fatigue behaviour of a friction stir welded low alloy steel has been assessed. • The welds’ fatigue lives outperform the International Institute of Welding’s recommendations for fusion welds. • The slow weld exhibits the best fatigue performance of the investigated welds. • Fracture surface analysis shows that minor embedded flaws do not offer crack initiation sites. • Process-related surface breaking flaws have a significant effect on the fatigue life. - Abstract: A comprehensive fatigue performance assessment of friction stir welded DH36 steel has been undertaken to address the relevant knowledge gap for this process on low alloy steel. A detailed set of experimental procedures specific to friction stir welding has been put forward, and the consequent study extensively examined the weld microstructure and hardness in support of the tensile and fatigue testing. The effect of varying welding parameters was also investigated. Microstructural observations have been correlated to the weldments’ fatigue behaviour. The typical fatigue performance of friction stir welded steel plates has been established, exhibiting fatigue lives well above the weld detail class of the International Institute of Welding even for tests at 90% of yield strength, irrespective of minor instances of surface breaking flaws which have been identified. An understanding of the manner in which these flaws impact on the fatigue performance has been established, concluding that surface breaking irregularities such as these produced by the tool shoulder’s features on the weld top surface can be the dominant factor for crack initiation under fatigue loading

  9. Microstructure and mechanical properties of a new type of austempered boron alloyed high silicon cast steel

    Directory of Open Access Journals (Sweden)

    Chen Xiang

    2013-05-01

    Full Text Available In the present paper, a new type of austempered boron alloyed high silicon cast steel has been developed, and its microstructures and mechanical properties at different temperatures were investigated. The experimental results indicate that the boron alloyed high silicon cast steel comprises a dendritic matrix and interdendritic eutectic borides in as-cast condition. The dendritic matrix is made up of pearlite, ferrite, and the interdendritic eutectic boride is with a chemical formula of M2B (M represents Fe, Cr, Mn or Mo which is much like that of carbide in high chromium white cast iron. Pure ausferrite structure that consists of bainitic ferrite and retained austenite can be obtained in the matrix by austempering treatment to the cast steel. No carbides precipitate in the ausferrite structure and the morphology of borides remains almost unchanged after austempering treatments. Secondary boride particles precipitate during the course of austenitizing. The hardness and tensile strength of the austempered cast steel decrease with the increase of the austempering temperature, from 250 篊 to 400 篊. The impact toughness is 4-11 J昪m-2 at room temperature and the impact fracture fractogragh indicates that the fracture is caused by the brittle fracture of the borides.

  10. Effect of Alloying Elements on Thermal Wear of Cast Hot-Forging Die Steels

    Institute of Scientific and Technical Information of China (English)

    WANG Shu-qi; CHEN Kang-min; CUI Xiang-hong; JIANG Qi-chuan; HONG Bian

    2006-01-01

    The effect of main alloying elements on thermal wear of cast hot-forging die steels was studied. The wear mechanism was discussed. The results show that alloying elements have significant influences on the thermal wear of cast hot-forging die steels. The wear rates decrease with an increase in chromium content from 3% to 4% and molybdenum content from 2% to 3%, respectively. With further increase of chromium and molybdenum contents, chromium slightly reduces the wear resistance and molybdenum severely deteriorates the wear resistance with high wear rate. Lower vanadium/carbon ratio (1.5-2.5) leads to a lower wear resistance with higher wear rate. With an increase in vanadium/carbon ratio, the wear resistance of the cast steel substantially increases. When vanadium/carbon ratio is 3, the wear rate reaches the lowest value. The predominant mechanism of thermal wear of cast hot-forging die steels are oxidation wear and fatigue delamination. The Fe2O3 and Fe3O4 or lumps of brittle wear debris are formed on the wear surface.

  11. Effect of Aluminum and Silicon on Atmospheric Corrosion of Low-alloying Steel under Containing NaHSO{sub 3} Wet/dry Environment

    Energy Technology Data Exchange (ETDEWEB)

    Xinhua, Chen; Junhua, Dong; Enhou, Han; Wei, Ke [Institute of Metal Research, Chinese Academy of Sciences, Shenyang (China)

    2008-12-15

    The atmospheric corrosion performance of Al-alloying Si-alloying and Al-Si-alloying steel were studied by wet/dry cyclic corrosion tests (CCT) at 30 .deg. C and 60% relative humidity (RH). The corrosion electrolyte used for CCT was 0.052 wt% NaHSO{sub 3} (pH{approx}4) solution. The result of gravimetry demonstrated that Al-Si-bearing steels showed lower corrosion resistance than other rusted steels. But the rusted 0.7%Si-alloying steel showed a better corrosion resistance than rusted mild steel. Polarization curves demonstrated that Al-/Si-alloying and Al-Si-alloying improved the rest potential of steel at the initial stage: and accelerated the cathodic reduction and anodic dissolution after a rust layer formed on the surfaces of steels. XRD results showed that Al-Si-alloying decreased the volume fraction of Fe{sub 3}O{sub 4} and {alpha}-FeOOH. The recycle of acid accelerated the corrosion of steel at the initial stage. After the rust layer formed on the steel, the leak of rust destabilized the rust layer due to the dissolution of compound containing Al (such as FeAl{sub 2}O{sub 4}, (Fe, Si){sub 2}(Fe, Al)O{sub 4}). Al-Si-alloying is hence not suitable for improving the anti-corrosion resistance of steel in industrial atmosphere.

  12. Effect of Aluminum and Silicon on Atmospheric Corrosion of Low-alloying Steel under Containing NaHSO3 Wet/dry Environment

    International Nuclear Information System (INIS)

    The atmospheric corrosion performance of Al-alloying Si-alloying and Al-Si-alloying steel were studied by wet/dry cyclic corrosion tests (CCT) at 30 .deg. C and 60% relative humidity (RH). The corrosion electrolyte used for CCT was 0.052 wt% NaHSO3 (pH∼4) solution. The result of gravimetry demonstrated that Al-Si-bearing steels showed lower corrosion resistance than other rusted steels. But the rusted 0.7%Si-alloying steel showed a better corrosion resistance than rusted mild steel. Polarization curves demonstrated that Al-/Si-alloying and Al-Si-alloying improved the rest potential of steel at the initial stage: and accelerated the cathodic reduction and anodic dissolution after a rust layer formed on the surfaces of steels. XRD results showed that Al-Si-alloying decreased the volume fraction of Fe3O4 and α-FeOOH. The recycle of acid accelerated the corrosion of steel at the initial stage. After the rust layer formed on the steel, the leak of rust destabilized the rust layer due to the dissolution of compound containing Al (such as FeAl2O4, (Fe, Si)2(Fe, Al)O4). Al-Si-alloying is hence not suitable for improving the anti-corrosion resistance of steel in industrial atmosphere

  13. Mechanical properties and hot-rolled microstructures of a low carbon bainitic steel with Cu-P alloying

    International Nuclear Information System (INIS)

    Highlights: → Mechanical properties and microstructures of low carbon bainite steel are examined. → Cu-P alloying promotes strengthening and uniform plastic deformation. → Cu-P alloying delays recovery process during rolling interval. → Lowering rolling temperature is favorable to increasing toughness. - Abstract: A low carbon bainitic steel with Cu-P alloying was developed. The new steel aims to meet the demand of high strength, high toughness and resistance to chloride ion corrosion for the components used in the environment of sea water and oceanic atmosphere. Mechanical properties of the steel were tested and strengthening and toughening mechanisms were analyzed by comparing hot-rolled microstructures of the low carbon bainitic steels with and without Cu-P alloying. The results show that Cu-P alloying provided strong solution strengthening with weak effect on ductility. The toughness loss caused by Cu-P alloying could be balanced by increasing the amount of martensite/remained austenite (M/A island) at lower finishing temperature. The static recovery process during rolling interval was delayed by the interaction of phosphorous, copper atoms with dislocations, which was favorable to the formation of bainitic plates. Super-fine Nb(C, N) particles precipitated on dislocations had coherency with bainite ferrite at 830 deg. C finishing temperature. Raising finishing temperature to 880 deg. C, Nb(C, N) particles were prone to coarsening and losing coherency. It was also found that no accurate lattice match relationship among retained austenite, martensite and bainite in granular bainitic microstructure.

  14. Mechanical properties and hot-rolled microstructures of a low carbon bainitic steel with Cu-P alloying

    Energy Technology Data Exchange (ETDEWEB)

    Cui, W.F., E-mail: wenfangcui@yahoo.com.cn [Key Laboratory for Anisotropy and Texture of Materials (Ministry of Education), Northeastern University, Shenyang 110004 (China); Zhang, S.X. [Key Laboratory for Anisotropy and Texture of Materials (Ministry of Education), Northeastern University, Shenyang 110004 (China); Technology Center of Laiwu Iron and Steel (Group) Co. Ltd., Laiwu 271104 (China); Jiang, Y. [School of Chemical Engineering, University of Queensland, Brisbane 4072 (Australia); Dong, J. [Technology Center of Laiwu Iron and Steel (Group) Co. Ltd., Laiwu 271104 (China); Liu, C.M. [Key Laboratory for Anisotropy and Texture of Materials (Ministry of Education), Northeastern University, Shenyang 110004 (China)

    2011-08-15

    Highlights: {yields} Mechanical properties and microstructures of low carbon bainite steel are examined. {yields} Cu-P alloying promotes strengthening and uniform plastic deformation. {yields} Cu-P alloying delays recovery process during rolling interval. {yields} Lowering rolling temperature is favorable to increasing toughness. - Abstract: A low carbon bainitic steel with Cu-P alloying was developed. The new steel aims to meet the demand of high strength, high toughness and resistance to chloride ion corrosion for the components used in the environment of sea water and oceanic atmosphere. Mechanical properties of the steel were tested and strengthening and toughening mechanisms were analyzed by comparing hot-rolled microstructures of the low carbon bainitic steels with and without Cu-P alloying. The results show that Cu-P alloying provided strong solution strengthening with weak effect on ductility. The toughness loss caused by Cu-P alloying could be balanced by increasing the amount of martensite/remained austenite (M/A island) at lower finishing temperature. The static recovery process during rolling interval was delayed by the interaction of phosphorous, copper atoms with dislocations, which was favorable to the formation of bainitic plates. Super-fine Nb(C, N) particles precipitated on dislocations had coherency with bainite ferrite at 830 deg. C finishing temperature. Raising finishing temperature to 880 deg. C, Nb(C, N) particles were prone to coarsening and losing coherency. It was also found that no accurate lattice match relationship among retained austenite, martensite and bainite in granular bainitic microstructure.

  15. Simultaneous material flow analysis of nickel, chromium, and molybdenum used in alloy steel by means of input-output analysis.

    Science.gov (United States)

    Nakajima, Kenichi; Ohno, Hajime; Kondo, Yasushi; Matsubae, Kazuyo; Takeda, Osamu; Miki, Takahiro; Nakamura, Shinichiro; Nagasaka, Tetsuya

    2013-05-01

    Steel is not elemental iron but rather a group of iron-based alloys containing many elements, especially chromium, nickel, and molybdenum. Steel recycling is expected to promote efficient resource use. However, open-loop recycling of steel could result in quality loss of nickel and molybdenum and/or material loss of chromium. Knowledge about alloying element substance flow is needed to avoid such losses. Material flow analyses (MFAs) indicate the importance of steel recycling to recovery of alloying elements. Flows of nickel, chromium, and molybdenum are interconnected, but MFAs have paid little attention to the interconnected flow of materials/substances in supply chains. This study combined a waste input-output material flow model and physical unit input-output analysis to perform a simultaneous MFA for nickel, chromium, and molybdenum in the Japanese economy in 2000. Results indicated the importance of recovery of these elements in recycling policies for end-of-life (EoL) vehicles and constructions. Improvement in EoL sorting technologies and implementation of designs for recycling/disassembly at the manufacturing phase are needed. Possible solutions include development of sorting processes for steel scrap and introduction of easier methods for identifying the composition of secondary resources. Recovery of steel scrap with a high alloy content will reduce primary inputs of alloying elements and contribute to more efficient resource use. PMID:23528100

  16. Stainless steel-zirconium alloy waste forms for metallic fission products and actinides during treatment of spent nuclear fuel

    International Nuclear Information System (INIS)

    Stainless steel-zirconium waste form alloys are being developed for the disposal of metallic wastes recovered from spent nuclear fuel using an electrometallurgical process developed by Argonne National Laboratory. The metal waste form comprises the fuel cladding, noble metal fission products and other metallic constituents. Two nominal waste form compositions are being developed: (1) stainless steel-15 wt% zirconium for stainless steel-clad fuels. The noble metal fission products are the primary source of radiation and their contribution to the waste form radioactivity has been calculated. The disposition of actinide metals in the waste alloys is also being explored. Simulated waste form alloys were prepared to study the baseline alloy microstructures and the microstructural distribution of noble metals and actinides, and to evaluate corrosion performance

  17. Enhancement of mechanical properties of alloy steels on hot forging

    International Nuclear Information System (INIS)

    The paper present the results of an investigation into the effects of the basic parameters of high-temperature thermomechanical treatment (HTTMT) under hot forging. It is shown that forging in open dies of 45Kh, 20Kh13 and 08Kh18N10T steel blanks following the established HTTMT modes improves the ultimate strength by 46, 56 and 2% respectively, and yield limit - by 65, 66 and 14%, as compared with their production in compliance with factory modes, preserving the level of ductility and impact strength

  18. Tool steels

    DEFF Research Database (Denmark)

    Højerslev, C.

    2001-01-01

    resistance against abrasive wear and secondary carbides (if any) increase the resistance against plastic deformation. Tool steels are alloyed with carbide forming elements (Typically: vanadium, tungsten, molybdenumand chromium) furthermore some steel types contains cobalt. Addition of alloying elements...

  19. Compatibility of graphite with a martensitic-ferritic steel, an austenitic stainless steel and a Ni-base alloy up to 1250 C

    International Nuclear Information System (INIS)

    To study the chemical interactions between graphite and a martensitic-ferritic steel (1.4914), an austenitic stainless steel (1.4919; AISI 316), and a Ni-base alloy (Hastelloy X) isothermal reaction experiments were performed in the temperature range between 900 and 1250 C. At higher temperatures a rapid and complete liquefaction of the components occurred as a result of eutectic interactions. The chemical interactions are diffusion-controlled processes and can be described by parabolic rate laws. The reaction behavior of the two steels is very similar. The chemical interactions of the steels with graphite are much faster above 1100 C than those for the Ni-base alloy. Below 1000 C the effect is opposite. (orig.)

  20. Impact tests of the tungsten coated stainless steels prepared by using magnetron sputtering with ion beam mixing or electron beam alloying treatment

    International Nuclear Information System (INIS)

    Tungsten films were deposited on stainless steel (SS) with ion beam mixing (IBM) or electron beam alloying (EBA) treatment. The ductile–brittle transition behaviors of the specimens were investigated by means of instrumented Charpy impact test at a series of temperature, and SEM was used to observe the morphology of the cross section. Impact tests show that different treatment methods with W films do not have much influence on crack initiation, while EBA treatment with W films can more effectively prevent crack propagation, namely improve the impact toughness of SS than using IBM treatment. The reason that caused this difference was discussed

  1. Impact tests of the tungsten coated stainless steels prepared by using magnetron sputtering with ion beam mixing or electron beam alloying treatment

    Science.gov (United States)

    Zou, Yu; Zhan, Chang-Yong; Yang, Bin; Wu, Jian-Chun

    2013-05-01

    Tungsten films were deposited on stainless steel (SS) with ion beam mixing (IBM) or electron beam alloying (EBA) treatment. The ductile-brittle transition behaviors of the specimens were investigated by means of instrumented Charpy impact test at a series of temperature, and SEM was used to observe the morphology of the cross section. Impact tests show that different treatment methods with W films do not have much influence on crack initiation, while EBA treatment with W films can more effectively prevent crack propagation, namely improve the impact toughness of SS than using IBM treatment. The reason that caused this difference was discussed.

  2. Impact tests of the tungsten coated stainless steels prepared by using magnetron sputtering with ion beam mixing or electron beam alloying treatment

    Energy Technology Data Exchange (ETDEWEB)

    Zou, Yu; Zhan, Chang-Yong; Yang, Bin [Key Lab. For Radiation Physics and Technology of Education Ministry of China, Institute of Nuclear Science and Technology, Sichuan University, Chengdu 610064 (China); Wu, Jian-Chun, E-mail: jcwu@scu.edu.cn [Key Lab. For Radiation Physics and Technology of Education Ministry of China, Institute of Nuclear Science and Technology, Sichuan University, Chengdu 610064 (China)

    2013-05-15

    Tungsten films were deposited on stainless steel (SS) with ion beam mixing (IBM) or electron beam alloying (EBA) treatment. The ductile–brittle transition behaviors of the specimens were investigated by means of instrumented Charpy impact test at a series of temperature, and SEM was used to observe the morphology of the cross section. Impact tests show that different treatment methods with W films do not have much influence on crack initiation, while EBA treatment with W films can more effectively prevent crack propagation, namely improve the impact toughness of SS than using IBM treatment. The reason that caused this difference was discussed.

  3. Influence of alloying on hydrogen-assisted cracking and diffusible hydrogen content in Cr–Mo steel welds

    Indian Academy of Sciences (India)

    S K Albert; V Ramasubbu; N Parvathavarthini; T P S Gill

    2003-06-01

    Study of hydrogen-assisted cracking and measurement of diffusible hydrogen content in different Cr–Mo steel welds shows that under identical conditions, susceptibility to cracking increased and diffusible hydrogen content decrease with increase in alloy content. Hydrogen permeation studies show that hydrogen diffusivity decreases and solubility increases with increase in alloy content. Thus decrease in diffusible hydrogen content with increase in alloying is attributed to increase in apparent solubility and decrease in apparent diffusivity of hydrogen. Analysis of the results indicates that variation of diffusible hydrogen content and apparent diffusivity of hydrogen with alloy content can be represented as a function of carbon equivalent CE1 originally proposed to predict the hardness in the heat-affected zone of alloy steel welds.

  4. SECM Study of Effect of Chromium Content on the Localized Corrosion Behavior of Low-Alloy Steels in Chloride Environment

    Science.gov (United States)

    Indira, K.; Nishimura, T.

    2016-10-01

    This paper investigates the effect of chromium (Cr) content (0, 1, 3 and 5% Cr) in epoxy-coated alloy steel against corrosion using in situ electrochemical techniques such as EIS and SECM in a 3% NaCl solution. The EIS results revealed that the epoxy-coated Cr steel exhibited higher impedance values than carbon steel, which is attributed to the greater resistance of Cr steel toward corrosion. Based on the cyclic voltammogram results, the tip potentials were set at -0.7, 0.04 and 0.60 V for determining the concentration of dissolved oxygen at cathodic region, and oxidation of Cr2+ and Fe2+ at anodic region, respectively. The SECM measurements showed that, the tip current in the anodic region has decreased with increase in Cr content of the sample, which indicates that the oxidation of Fe2+ and Cr2+ decreases (corrosion is reduced) with the increase in Cr content of the steel. Besides, 5% Cr steel can maintain the highest corrosion resistance, and 1 and 3% Cr steels have higher corrosion resistance than the 0% Cr steel. This higher corrosion resistance of Cr steel samples could be due to the formation of Cr-rich hydro-oxide layers [Cr(OH)3 as a corrosion product] on the surface of the samples. Thus, the epoxy-coated Cr alloy steel has greater corrosion resistance in a chloride-containing environment than the carbon steel. Hence, epoxy-coated Cr alloy steel can be successfully used as a construction material in structures.

  5. Effects of alloying elements on sticking occurring during hot rolling of ferritic stainless steels

    International Nuclear Information System (INIS)

    In this study, effects of alloying elements on the sticking occurring during hot rolling of five kinds of ferritic STS430J1L stainless steels were investigated by analyzing high-temperature hardness and oxidation behavior of the rolled steels. Hot-rolling simulation tests were conducted by a high-temperature wear tester which could simulate actual hot rolling. The simulation test results revealed that the sticking process proceeded with three stages, i.e., nucleation, growth, and saturation. Since the hardness continuously decreased as the test temperature increased, whereas the formation of Fe-Cr oxides in the rolled steel surface region increased, the sticking of five stainless steels was evaluated by considering both the high-temperature hardness and oxidation effects. The addition of Zr, Cu, or Si had a beneficial effect on the sticking resistance, while the Ni addition did not show any difference in the sticking. Particularly in the case of the Si addition, Si oxides formed first in the initial stage of high-temperature oxidation, worked as initiation sites for Fe-Cr oxides, accelerated the formation of Fe-Cr oxides, and thus raised the sticking resistance by about 10 times in comparison with the steel without Si content

  6. Fatigue crack propagation in carburized high alloy bearing steels

    Science.gov (United States)

    Averbach, B. L.; Lou, Bingzhe; Pearson, P. K.; Fairchild, R. E.; Bamberger, E. N.

    1985-07-01

    Fatigue cracks were propagated through carburized cases in M-50NiL (0.1 C,4 Mo, 4 Cr, 1.3 V, 3.5 Ni) and CBS-1000M (0.1 C, 4.5 Mo, 1 Cr, 0.5 V, 3 Ni) steels at constant stress intensity ranges, ΔK, and at a constant cyclic peak load. Residual compressive stresses of the order of 140 MPa (20 Ksi) were developed in the M-50NiL cases, and in tests carried out at constant ΔK values it was observed that the fatigue crack propagation rates, da/dN, slowed significantly. In some tests, at constant peak loads, cracks were stopped in regions with high compressive stresses. The residual stresses in the cases in CBS-1000M steel were predominantly tensile, probably because of the presence of high retained austenite contents, and da/dN was accelerated in these cases. The effects of residual stress on the fatigue crack propagation rates are interpreted in terms of a pinched clothespin model in which the residual stresses introduce an internal stress intensity, Ki where Ki, = σid{i/1/2} (σi = internal stress, di = characteristic distance associated with the internal stress distribution). The effective stress intensity becomes Ke = Ka + Ki where Ka is the applied stress intensity. Values of Ki were calculated as a function of distance from the surface using experimental measurements of σi and a value of di = 11 mm (0.43 inch). The resultant values of Ke were taken to be equivalent to effective ΔK values, and da/dN was determined at each point from experimental measurements of fatigue crack propagation obtained separately for the case and core materials. A reasonably good fit was obtained with data for crack growth at a constant ΔK and at a constant cyclic peak load. The carburized case depths were approximately 4 mm, and the possible effects associated with the propagation of short cracks were considered. The major effects were observed at crack lengths of about 2 mm, but the contributions of short crack phenomena were considered to be small in these experiments, since the

  7. Measurement of the superconducting transition temperature of Dural and titanium 6Al-4V alloys

    Energy Technology Data Exchange (ETDEWEB)

    Divakar, U; Henry, S; Kraus, H; Tolhurst, A J B [University of Oxford, Denys Wilkinson Building, Keble Road, Oxford OX1 3RH (United Kingdom)

    2008-06-15

    We have measured the superconducting transition temperatures of commercial alloys Dural and titanium 6Al-4V, to assess their suitability for use in the cryoEDM neutron electric dipole moment experiment. Our sample of aluminium alloy Dural became a superconductor at 0.84 {+-} 0.07 K but the titanium alloy did not show any superconducting behaviour down to the experimental limit of 0.17 {+-} 0.11 K.

  8. Alternative Fabrication Routes toward Oxide-Dispersion-Strengthened Steels and Model Alloys

    Science.gov (United States)

    Bergner, Frank; Hilger, Isabell; Virta, Jouko; Lagerbom, Juha; Gerbeth, Gunter; Connolly, Sarah; Hong, Zuliang; Grant, Patrick S.; Weissgärber, Thomas

    2016-07-01

    The standard powder metallurgy (PM) route for the fabrication of oxide-dispersion-strengthened (ODS) steels involves gas atomization to produce a prealloyed powder, mechanical alloying (MA) with fine oxide powders, consolidation, and finally thermal/thermomechanical treatment (TMT). It is well established that ODS steels with superior property combinations, for example, creep and tensile strength, can be produced by this PM/MA route. However, the fabrication process is complex and expensive, and the fitness for scaling up to the industrial scale is limited. At the laboratory scale, production of small amounts of well-controlled model systems continues to be desirable for specific purposes, such as modeling-oriented experiments. Thus, from the laboratory to industrial application, there is growing interest in complementary or alternative fabrication routes for ODS steels and related model systems, which offer a different balance of cost, convenience, properties, and scalability. This article reviews the state of the art in ODS alloy fabrication and identifies promising new routes toward ODS steels. The PM/AM route for the fabrication of ODS steels is also described, as it is the current default process. Hybrid routes that comprise aspects of both the PM route and more radical liquid metal (LM) routes are suggested to be promising approaches for larger volumes and higher throughput of fabricated material. Although similar uniformity and refinement of the critical nanometer-sized oxide particles has not yet been demonstrated, ongoing innovations in the LM route are described, along with recent encouraging preliminary results for both extrinsic nano-oxide additions and intrinsic nano-oxide formation in variants of the LM route. Finally, physicochemical methods such as ion beam synthesis are shown to offer interesting perspectives for the fabrication of model systems. As well as literature sources, examples of progress in the authors' groups are also highlighted.

  9. Alternative Fabrication Routes toward Oxide-Dispersion-Strengthened Steels and Model Alloys

    Science.gov (United States)

    Bergner, Frank; Hilger, Isabell; Virta, Jouko; Lagerbom, Juha; Gerbeth, Gunter; Connolly, Sarah; Hong, Zuliang; Grant, Patrick S.; Weissgärber, Thomas

    2016-11-01

    The standard powder metallurgy (PM) route for the fabrication of oxide-dispersion-strengthened (ODS) steels involves gas atomization to produce a prealloyed powder, mechanical alloying (MA) with fine oxide powders, consolidation, and finally thermal/thermomechanical treatment (TMT). It is well established that ODS steels with superior property combinations, for example, creep and tensile strength, can be produced by this PM/MA route. However, the fabrication process is complex and expensive, and the fitness for scaling up to the industrial scale is limited. At the laboratory scale, production of small amounts of well-controlled model systems continues to be desirable for specific purposes, such as modeling-oriented experiments. Thus, from the laboratory to industrial application, there is growing interest in complementary or alternative fabrication routes for ODS steels and related model systems, which offer a different balance of cost, convenience, properties, and scalability. This article reviews the state of the art in ODS alloy fabrication and identifies promising new routes toward ODS steels. The PM/AM route for the fabrication of ODS steels is also described, as it is the current default process. Hybrid routes that comprise aspects of both the PM route and more radical liquid metal (LM) routes are suggested to be promising approaches for larger volumes and higher throughput of fabricated material. Although similar uniformity and refinement of the critical nanometer-sized oxide particles has not yet been demonstrated, ongoing innovations in the LM route are described, along with recent encouraging preliminary results for both extrinsic nano-oxide additions and intrinsic nano-oxide formation in variants of the LM route. Finally, physicochemical methods such as ion beam synthesis are shown to offer interesting perspectives for the fabrication of model systems. As well as literature sources, examples of progress in the authors' groups are also highlighted.

  10. A novel active fire protection approach for structural steel members using NiTi shape memory alloy

    International Nuclear Information System (INIS)

    A novel active fire protection approach, based on integrating a shape memory alloy, NiTi, with a steel structure, was proposed to satisfy the fire resistance requirements in structural design. To demonstrate the principles of this approach, a simple structure in the form of a simply supported steel beam was used. The internal action of the beam due to a transverse applied load was reduced by utilizing the shape memory effect in the NiTi alloy at rising temperatures. As a result, the net internal action from the load design was kept below the deteriorated load capacity of the beam during the fire scenario for period of time that was longer than that of the original beam without the NiTi alloy. By integrating the NiTi alloy into the beam system, the structure remained stable even though the steel temperature exceeded the critical temperature which may have caused the original beam structure to collapse. Prior to testing the composite NiTi–steel beam under simulated fire conditions, the NiTi alloy specimens were characterized at high temperatures. At 300 °C, the stiffness of the specimens increased by three times and its strength by four times over that at room temperature. The results obtained from the high-temperature characterization highlighted the great potential of the alloy being used in fire engineering applications. (paper)

  11. Thermal Diffusivity and Thermal Conductivity of Five Different Steel Alloys in the Solid and Liquid Phases

    Science.gov (United States)

    Wilthan, B.; Schützenhöfer, W.; Pottlacher, G.

    2015-08-01

    The need for characterization of thermophysical properties of steel and nickel-based alloys was addressed in the FFG-Bridge Project 810999 in cooperation with a partner from industry, Böhler Edelstahl GmbH & Co KG. To optimize numerical simulations of production processes, such as remelting or plastic deformation, additional, and more accurate data were necessary for the alloys under investigation. With a fast ohmic pulse heating circuit system, the temperature-dependent specific electrical resistivity, density, and specific heat capacity for a set of five high alloyed steels were measured. Hence, using the Wiedemann-Franz law with a Lorenz number of , the thermal diffusivity and thermal conductivity could be calculated for the solid and liquid phases up to temperatures of 2500 K. This experimental approach is limited by the following requirements for the specimens: they have to be electrically conducting, the melting point has to be high enough for the implemented pyrometric temperature measurement, and one has to be able to draw wires of the material. The latter restriction is technologically challenging with some of the materials being very brittle. For all samples, electrical and temperature signals are recorded and a fast shadowgraph method is used to measure the volume expansion. For each material under investigation, a set of data including the chemical composition, the density at room temperature, solidus and liquidus temperatures, and the change of enthalpy, resistivity, density, thermal conductivity, and thermal diffusivity as a function of temperature is reported.

  12. Study of ultrasonically assisted turning of stainless steel and brass alloys

    International Nuclear Information System (INIS)

    Ultrasonically assisted turning (UAT) is a hybrid machining technique employing high-frequency small-amplitude vibration superimposed on the tool movement during turning. It is superior to conventional turning (CT) with regard to cutting forces, surface quality and machining accuracy. The aim of this study is to investigate the effect of different machining parameters on stainless steel and brass alloys, during both UAT and CT, and evaluate improvements of cutting forces, surface roughness, surface integrity, and machining accuracy. An experimental setup for UAT at Loughborough University was used to accomplish this investigation. This setup used a Picoscope data acquisition add-on with Kistler three-component dynamometer, Seco DNMG cutting inserts were utilized, a surface tester from Taylor Hobson was used to evaluate surface roughness, Alicona Infinite Focus microscope was used to evaluate surface roughness and surface integrity, while Metris CMM with Renishaw probe was employed to evaluate machining accuracy. Cylindrical workpieces of steel and brass alloys were turned under CT and UAT conditions; cutting forces, surface roughness, and machining accuracy produced with both techniques where compared. Significant improvements were noticed in the ultrasonically assisted machining when compared to the CT for both alloys

  13. Welding of thin sheets of high strength zinc alloy coated steels

    International Nuclear Information System (INIS)

    Zinc alloy coated, high strength (G550) sheet steels are important materials in automobile manufacture, building and construction. Spot or arc welding is typically required in the component manufacturing process, but these processes result in localised softening because of the weld thermal cycle. As a consequence, the strength is normally downgraded significantly for design purposes to values typical of the annealed Zn or Zn alloy grades (G250 or G300). The investigation described in this paper involved the examination of the effect of the welding process and welding variables on butt welding on 1mm thick Zn-coated and Zn-Al-coated sheet steels. It has been demonstrated that these sheet steels can be successfully welded by both FCAW and GMAW methods using appropriately low welding heat inputs. However, strength loss below the minimum specified 5.50 MPa tensile strength did occur because of transformation and recrystallisation of the recovery annealed base metal structure as a result of the heat input of the welding process. The extent of the strength loss increased with increasing nominal weld heat input due to an increased width of the softened heat affected zone (HAZ) regions and grain growth in the grain refined and recrystallised regions. The maximum loss in yield strength at the highest heat input of 130 J/mm was about 150 MPa, suggesting that a minimum yield stress of 400 MPa can be safely used for structural design calculations.

  14. Effect of inter-critical quenching on mechanical properties of casting low-alloy steel

    Directory of Open Access Journals (Sweden)

    Liu Zhongli

    2013-07-01

    Full Text Available For some casting low-alloy steels, traditional quenching and tempering heat treatments can improve the strength; however, sometimes the ductility is not satisfied. Therefore, some kind of effective heat treatment method seems necessary; one which could improve the ductility, but not seriously affect the strength. In this paper, the effect of inter-critical quenching (IQ on the mechanical properties of casting low-alloy steel was studied. IQ was added between quenching and tempering heat treatment; and the microstructure and mechanical properties were compared to the same steel with the traditional quenching and tempering treatments. The experimental results show that the microstructure comprises small-size ferrite and martensite when the IQ is adopted; and that different temperatures can control the ferrite quantity and distribution, and, as a result, influence the mechanical properties. In the case of IQ, the tensile strength decreases just a little, but the ductility increases a lot; and the strength-ductility product (its value is the arithmetic product of elongation and tensile strength increases by between 6% and 10%, which means the IQ heat treatment can improve comprehensive mechanical properties.

  15. Study of electroless Ni-W-P alloy coating on martensitic stainless steel

    Science.gov (United States)

    Nikitasari, Arini; Mabruri, Efendi

    2016-04-01

    Electroless nickel phospor (Ni-P) is widely used in many industries due to their corrosion and wear resistance, coating uniformity, and ability to coat non-conductive surfaces. The unique properties of tungsten such as high hardness, higher melting point, lower coefficient of linear thermal expansion, and high tensile strength have created a lot of interest in developing ternary Ni-W-P alloys. This article presents the study of electroless Ni-W-P alloys coating using acid or alkaline bath on martensitic stainless steel. Nickel sulfate and sodium tungstate were used as nickel and tungsten sources, respectively, and sodium hypophosphite was used as a reducing agent. Acid or alkaline bath refer to bath pH condition was adjusted by adding sulfuric acid. Martensitic stainless steel was immersed in Ni-W-P bath for 15, 30, and 60 minutes. The substrate of martensitic stainless steel was subjected to pre-treatment (polishing and cleaning) and activation prior to electroless plating. The plating characteristics were investigated for concentration ratio of nickel and hypophosphite (1:3), sodium tungstate concentration 0,1 M, immersion time (15 min, 30 min, 60 min), and bath condition (acid, alkaline). The electroless Ni-W-P plating was heat treated at 400°C for 1 hour. Deposits were characterized using scanning electron microscope (SEM) and corrosion measurement system (CMS).

  16. Intergranular brittle fracture of a low alloy steel induced by grain boundary segregation of impurities: influence of the microstructure

    International Nuclear Information System (INIS)

    The study contributes to improve the comprehension of intergranular embrittlement induced by the phosphorus segregation along prior austenitic grain boundaries of low alloy steels used in pressurized power reactor vessel. A part of this study was performed using a A533 steel which contains chemical fluctuations (ghost lines) with two intensities. Axi-symmetrically notched specimens were tested and intergranular brittle de-cohesions were observed in the ghost lines. The fracture initiation sites observed on fracture surfaces were identified as MnS inclusions. A bimodal statistic obtained in a probabilistic model of the fracture is explained by the double population of ghost lines' intensities. A metallurgical study was performed on the same class of steel by studying the influence of the microstructure on the susceptibility to temper embrittlement. Brittle fracture properties of such microstructures obtained by dilatometric experiments were tested on sub-sized specimens to measure the V-notched fracture toughness. Fraction areas of brittle fracture modes were determined on surface fractures. A transition of the fracture mode with the microstructure is observed. It is shown that tempered microstructures of martensite and lower bainite are more susceptible to intergranular embrittlement than tempered upper bainitic microstructure. The intergranular fracture is the most brittle mode. The analysis of crystalline mis-orientations shows a grain boundary structure appreciably more coherent for tempered microstructures of martensite and lower bainite. The higher density of random grain boundaries is susceptible to drag the phosphorus in the upper bainitic matrix and to make the quantity of free phosphorus decreasing. Microstructure observations show a difference in the size and the spatial distribution of carbides, essentially cementite, between tempered martensite and upper bainite. It can explain the bigger susceptibility of this last microstructure to cleavage mode

  17. Changes of inclusion, texture and magnetic property of non-oriented Si steel treated by Ca alloy

    Science.gov (United States)

    Lv, X.; Zhang, F.; Chen, X.

    2015-04-01

    Based on the industrial production of non-oriented Si steel, Ca treatment by Ca alloy adding during the RH refining process was studied. The changes of inclusion, crystal texture and microstructure, and its effect on magnetic properties of final steel sheets were analyzed. The results showed that, in present work, Ca treatment can improve the texture proportion of {110} and {111} significantly, and the formation of MnS and AlN inclusions were restrained. Meanwhile, the recrystallization effects of hot rolled strip get bad and the fiber structure enhanced obviously. The grain size of finished steel sheets increased as the increase of Ca alloy adding amount quickly, and then decreased. Compared with the non-Ca treatment charge, the numbers of inclusions whose size below 1.0μm will decrease by 68.06%, 87.50% and 94.94%, the texture proportion of {110} and {111} was 30.3%, 39.1%, 17.6% and 2.8%, 5.5%, 20.6%, while the correspondent Ca alloy adding amount is 0.67 kg/t steel, 1.00 kg/t steel and 1.67 kg/t steel, respectively. In addition, the core loss gradually decreases to a stable level as the increasing of Ca added, and the magnetic induction decreases quickly after slow increasing, respectively. The optimal Ca treatment mode depends on the chemical compositions of steel grades.

  18. Effect of antimony on the corrosion behavior of low-alloy steel for flue gas desulfurization system

    International Nuclear Information System (INIS)

    The alloying effect of Sb in a new low-alloy steel for the purpose of FGD materials was investigated by potentiodynamic polarization, linear polarization resistance measurement, electrochemical impedance spectroscopy (EIS) and weight loss measurements in an aggressive solution of 16.9 vol.% H2SO4 + 0.35 vol.% HCl (modified green death solution) at 60 deg. C, pH -0.3. All measurements confirmed the marked improvement in the corrosion behavior of the low-alloy steel via the addition of a small amount of Sb, particularly for the 0.10Sb steel. Pitting corrosion was detected by scanning electron microscopy (SEM) on the surface of blank steel and 0.05Sb steel, but not 0.10Sb steel, after weight loss measurements. X-ray photoelectron spectroscopy (XPS) analysis of the corroded surfaces after EIS and linear polarization measurements showed that the decrease in corrosion rates was due to the formation of a protective Sb2O5 oxide film on the surface of the Sb-containing steels. Moreover, the addition of 0.10% Sb stimulated the development of high corrosion inhibiting, Cu-containing compounds which further inhibited the anodic and cathodic reactions

  19. Influence of heat input on weld bead geometry using duplex stainless steel wire electrode on low alloy steel specimens

    Directory of Open Access Journals (Sweden)

    Ajit Mondal

    2016-12-01

    Full Text Available Gas metal arc welding cladding becomes a popular surfacing technique in many modern industries as it enhances effectively corrosion resistance property and wear resistance property of structural members. Quality of weld cladding may be enhanced by controlling process parameters. If bead formation is found acceptable, cladding is also expected to be good. Weld bead characteristics are often assessed by bead geometry, and it is mainly influenced by heat input. In this paper, duplex stainless steel E2209 T01 is deposited on E250 low alloy steel specimens with 100% CO2 gas as shielding medium with different heats. Weld bead width, height of reinforcement and depth of penetration are measured. Regression analysis is done on the basis of experimental data. Results reveal that within the range of bead-on-plate welding experiments done, parameters of welding geometry are on the whole linearly related with heat input. A condition corresponding to 0.744 kJ/mm heat input is recommended to be used for weld cladding in practice.

  20. Tensile and pack compressive tests of some sheets of aluminum alloy, 1025 carbon steel, and chromium-nickel steel

    Science.gov (United States)

    Atchison, C S; Miller, James A

    1942-01-01

    Tensile and compressive stress-strain curves, stress-deviation curves, and secant modulus-stress curves are given for longitudinal and transverse specimens of 17S-T, 24S-T, and 24S-RT aluminum-alloy sheet in thicknesses from 0.032 to 0.081 inch, 1025 carbon steel sheet in thicknesses of 0.054 and 0.120 inch, and chromium-nickel steel sheet in thicknesses form 0.020 to 0.0275 inch. Significant differences were found between the tensile and the compressive stress-strain curves, and also the corresponding corollary curves; similarly, differences were found between the curves for the longitudinal and transverse directions. These differences are of particular importance in considering the compressive strength of aircraft structures made of thin sheet. They are explored further for the case of compression by giving tangent modulus-stress curves in longitudinal and transverse compression and dimensionless curves of the ratio of tangent modulus to Young's modulus and of the ratio of reduced modulus for a rectangular section to Young's modulus, both plotted against the ratio of stress to secant yield strength.

  1. Surface Modification of Micro-Alloyed High-Strength Low-Alloy Steel by Controlled TIG Arcing Process

    Science.gov (United States)

    Ghosh, P. K.; Kumar, Ravindra

    2015-02-01

    Surface modification of micro-alloyed HSLA steel plate has been carried out by autogenous conventional and pulse current tungsten inert gas arcing (TIGA) processes at different welding parameters while the energy input was kept constant. At a given energy input the influence of pulse parameters on the characteristics of surface modification has been studied in case of employing single and multi-run procedure. The role of pulse parameters has been studied by considering their summarized influence defined by a factor Φ. The variation in Φ and pulse frequency has been found to significantly affect the thermal behavior of fusion and accordingly the width and penetration of the modified region along with its microstructure, hardness and wear characteristics. It is found that pulsed TIGA is relatively more advantageous over the conventional TIGA process, as it leads to higher hardness, improved wear resistance, and a better control over surface characteristics.

  2. Oxidation behavior of nickel-base superalloys and High Strength Low Alloy (HSLA) steels at elevated temperatures

    Science.gov (United States)

    Talekar, Anjali S.

    Alloy C-22 (UNS N06022) and High Strength Low Alloy (HSLA) steels are candidate materials for use in outer layer of waste storage packages and as rock bolts in the underground roof supports at Yucca Mountain nuclear waste repository respectively. Oxidation kinetics of three Ni-base Superalloys and two HSLA Steels, Split Set Friction Rock Stabilizers (SS-46) and Swellex Mn-24, have been determined by isothermal high temperature continuous measurement thermogravimetry at temperatures ranging between 600°C to 1100°C in pure oxygen atmosphere for predetermined periods of exposures (48 hours for the Superalloys and 100 hours for HSLA steels). The two other Ni-base Superalloys selected were Alloy-263 (UNS N07263) and Alloy-282. These are similar in their Cr composition to Alloy C-22 and have variations in the contents of other alloying elements namely Co and Mo. The alloys were selected for comparison of their oxidation resistance with C-22 as a baseline material. All three Superalloys are known chromia formers. All the superalloys were evaluated for determining their kinetic parameters and the activation energies for the superalloys were also calculated. The activation energy for the parabolic regime of Alloy-282 is found to be 232 kJ/mol. The slope of the curves on a plot of kp as a function of (1/T) show Alloy-282 to have better oxidation resistance up to 980°C and thereafter the rate constants are similar for all three alloys, but when activation energies over the whole temperature range are calculated, Alloy-263 shows the best average oxidation resistance. Surface characterization by means of microscopy as well as X-ray photoelectron spectroscopy showed the nature of oxides formed. Based on the kinetics and the characterization, proposed mechanisms for oxidation of these alloys at high temperatures are put forth. Temperature modulated thermogravimetry was used for studies on HSLA steels. The imposed sinusoidal temperature modulations on the isothermal temperature

  3. Spark Plasma Sintering of Low Alloy Steel Modified with Silicon Carbide

    Directory of Open Access Journals (Sweden)

    Hebda M.

    2016-06-01

    Full Text Available The influence of adding different amounts of silicon carbide on the properties (density, transverse rupture strength, microhardness and corrosion resistance and microstructure of low alloy steel was investigated. Samples were prepared by mechanical alloying (MA process and sintered by spark plasma sintering (SPS technique. After the SPS process, half of each of obtained samples was heat-treated in a vacuum furnace. The results show that the high-density materials have been achieved. Homogeneous and fine microstructure was obtained. The heat treatment that followed the SPS process resulted in an increase in the mechanical and plastic properties of samples with the addition 1wt. % of silicon carbide. The investigated compositions containing 1 wt.% of SiC had better corrosion resistance than samples with 3 wt.% of silicon carbide addition. Moreover, corrosion resistance of the samples with 1 wt.% of SiC can further be improved by applying heat treatment.

  4. Influence of zirconium on microstructure and toughness of low-alloy steel weld metals

    Science.gov (United States)

    Trindade, V. B.; Mello, R. S. T.; Payão, J. C.; Paranhos, R. P. R.

    2006-06-01

    The influence of zirconium on microstructure and toughness of low-alloy steel weld metal was studied. Weld metals with different zirconium contents were obtained adding iron-zirconium alloy in the welding flux formulation. Weld metal chemical composition proved that zirconium was able to be transferred from the flux to the weld metal. The addition of zirconium refined the weld metal microstructure, increasing the acicular ferrite content. Weld metal toughness, determined by means of impact Charpy-V tests, showed that the zirconium addition is beneficial up to a content of 0.005 wt.%. Above this level, zirconium was not able to produce further microstructure refinement, although the toughness was reduced, possibly due to the formation of microconstituent such as the martensite-austenite constituent (M-A), which is considered to be deleterious to the weld metal toughness.

  5. Inverse correlation between cohesive energy and thermal expansion coefficient in liquid transition metal alloys.

    Science.gov (United States)

    Gangopadhyay, A K; Bendert, J C; Mauro, N A; Kelton, K F

    2012-09-19

    The volume expansion coefficients (α) of twenty-five glass-forming transition metal alloy liquids, measured using the electrostatic levitation technique, are reported. An inverse correlation between α and the cohesive energy is found. The predicted values of α from this relationship agree reasonably well with the published data for thirty other transition metal and alloy liquids; some disagreement was found for a few alloys containing significant amounts of group III and IV elements. A theoretical argument for this empirical relationship is presented. PMID:22842287

  6. Inverse correlation between cohesive energy and thermal expansion coefficient in liquid transition metal alloys

    International Nuclear Information System (INIS)

    The volume expansion coefficients (α) of twenty-five glass-forming transition metal alloy liquids, measured using the electrostatic levitation technique, are reported. An inverse correlation between α and the cohesive energy is found. The predicted values of α from this relationship agree reasonably well with the published data for thirty other transition metal and alloy liquids; some disagreement was found for a few alloys containing significant amounts of group III and IV elements. A theoretical argument for this empirical relationship is presented. (paper)

  7. Dynamic deformation and fragmentation response of maraging steel linear cellular alloy

    Science.gov (United States)

    Jakus, Adam E.; Fredenberg, David A.; McCoy, Tammy; Thadhani, Naresh; Cochran, Joe K.

    2012-03-01

    The dynamic deformation and fragmentation response of 25% dense 9-cell linear cellular alloy (LCA) made of unaged 250 maraging steel, fabricated using a direct reduction and extrusion technique, is investigated. Explicit finite element simulations were implemented using AUTODYN finite element code. The maraging steel properties were defined using a Johnson-Cook strength model with previously validated parameters. Rod-on-anvil impact tests were performed using the 7.6mm helium gas gun and the transient deformation and fragmentation response was recorded with highspeed imaging. Analysis of observed deformation states of specimens and finite element simulations reveal that in the case of the 9-cell LCA, dissipation of stress and strain occurs along the interior cell wells resulting in significant and ubiquitous buckling prior to confined fragmentation.

  8. Dissimilar ultrasonic spot welding of Mg-Al and Mg-high strength low alloy steel

    Directory of Open Access Journals (Sweden)

    V.K. Patel

    2014-01-01

    Full Text Available Sound dissimilar lap joints were achieved via ultrasonic spot welding (USW, which is a solid-state joining technique. The addition of Sn interlayer during USW effectively blocked the formation of brittle al12Mg17 intermetallic compound in the Mg-Al dissimilar joints without interlayer, and led to the presence of a distinctive composite-like Sn and Mg2Sn eutectic structure in both Mg-Al and Mg-high strength low alloy (HSLA steel joints. The lap shear strength of both types of dissimilar joints with a Sn interlayer was significantly higher than that of the corresponding dissimilar joints without interlayer. Failure during the tensile lap shear tests occurred mainly in the mode of cohesive failure in the Mg-Al dissimilar joints and in the mode of partial cohesive failure and partial nugget pull-out in the Mg-HSLA steel dissimilar joints.

  9. High Power Laser Welding. [of stainless steel and titanium alloy structures

    Science.gov (United States)

    Banas, C. M.

    1972-01-01

    A review of recent developments in high power, carbon dixoide laser welding is presented. Deep penetration welding in stainless steel to 0.5-in. thick, high speed welding in thin gage rimmed steel and gas shielded welding in Ti-6Al-4V alloy are described. The effects of laser power, power density, focusing optics, gas-shielding techniques, material properties and weld speed on weld quality and penetration are discussed. It is shown that laser welding performance in thin materials is comparable to that of electron beams. It is further shown that high quality welds, as evidenced by NDT, mechanical and metal-lographic tests, can be achieved. The potential of the laser for industrial welding applications is indicated.

  10. Corrosion of AISI 4130 Steel Alloy under Hydrodynamic Condition in Ethylene Glycol + Water + NO2-Solution

    Institute of Scientific and Technical Information of China (English)

    I. Danaee; M. Niknejad Khomami; A.A. Attar

    2013-01-01

    The electrochemical behavior of steel alloy in ethylene glycol-water mixture at different solution rotating speeds was investigated by polarization curves and AC impedance measurements (EIS).The results obtained showed that corrosion rate was not changed significantly at different rotating speeds and was decreased with increasing ethylene glycol concentration.The effect of nitrite as an inhibitor was studied and high inhibition efficiency was obtained.It was found that surface passivation occurred in the presence of inhibitor.The inhibiting effect of the nitrite was explained on the basis of the competitive adsorption between the inorganic anions and the aggressive Cl-ions and the adsorption isotherm basically obeys the Flory-Huggins adsorption isotherm.Thermodynamic parameters for steel corrosion and inhibitor adsorption were determined,which revealed that the adsorption process is spontaneous.

  11. Standard guide for estimating the atmospheric corrosion resistance of low-alloy steels

    CERN Document Server

    American Society for Testing and Materials. Philadelphia

    2004-01-01

    1.1 This guide presents two methods for estimating the atmospheric corrosion resistance of low-alloy weathering steels, such as those described in Specifications A242/A242M, A588/A588M, A606 Type 4, A709/A709M grades 50W, HPS 70W, and 100W, A852/A852M, and A871/A871M. One method gives an estimate of the long-term thickness loss of a steel at a specific site based on results of short-term tests. The other gives an estimate of relative corrosion resistance based on chemical composition. 1.2 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard.

  12. Alloy Shrinkage factors for the investment casting of 17-4PH stainless steel parts

    Energy Technology Data Exchange (ETDEWEB)

    Sabau, Adrian S [ORNL; Porter, Wallace D [ORNL

    2008-01-01

    In this study, the alloy shrinkage factors were obtained for the investment casting of 17-4PH stainless steel parts. For the investment casting process, unfilled wax and fused silica with a zircon prime coat were used for patterns and shell molds, respectively. Dimensions of the die tooling, wax pattern, and casting were measured using a Coordinate Measurement Machine. For all the properties, the experimental data available in the literature did not cover the entire temperature range necessary for process simulation. A comparison between the predicted material property data measured property data is made. It was found that most material properties were accurately predicted over the most of the temperature range of the process. Several assumptions were made in order to obtain a complete set of mechanical property data at high temperatures. Thermal expansion measurements for the 17-4PH alloy were conducted at heating and cooling. As a function of temperature, the thermal expansion for both the alloy and shell mold materials showed different evolution at heating and cooling. Thus, one generic simulation were performed with thermal expansion obtained at heating and another one with thermal expansion obtained at cooling. The alloy dimensions were obtained from numerical simulation results of solidification, heat transfer, and deformation phenomena. As compared with experimental results, the numerical simulation results for the shrinkage factors were slightly over-predicted.

  13. Dissimilar ultrasonic spot welding of Mg-Al and Mg-high strength low alloy steel

    OpenAIRE

    Patel, V K; D. L. Chen; S.D. Bhole

    2014-01-01

    Sound dissimilar lap joints were achieved via ultrasonic spot welding (USW), which is a solid-state joining technique. The addition of Sn interlayer during USW effectively blocked the formation of brittle al12Mg17 intermetallic compound in the Mg-Al dissimilar joints without interlayer, and led to the presence of a distinctive composite-like Sn and Mg2Sn eutectic structure in both Mg-Al and Mg-high strength low alloy (HSLA) steel joints. The lap shear strength of both types of dissimilar join...

  14. The effects of dynamic load on behaviour of welded joint A-387 Gr. 11 alloyed steel

    Directory of Open Access Journals (Sweden)

    O. Popović

    2013-01-01

    Full Text Available The in-service behaviour of alloyed steel A-387 Gr. 11 Class 1, for pressure vessels, used for high temperature applications, depends on the properties of its welded joint, with parent metal (BM, heat-affected-zone (HAZ and weld metal (WM, as constituents. Charpy testing of BM, WM and HAZ, together with, determination of the parameters of fatigue-crack growth and fatigue threshold ΔKth was used, in order to understand, how heterogeneity of structure and different mechanical properties of welded joint constituents affect on crack initiation and propagation.

  15. Effects of heat treatment on properties of multi-element low alloy wear-resistant steel

    Directory of Open Access Journals (Sweden)

    SONG Xu-ding

    2007-02-01

    Full Text Available The paper has studied the mechanical properties and heat treatment effects on multi-element low alloy wear-resistant steel (MLAWS used as a material for the liner of rolling mill torii. The results show that when quenched at 900-920℃ and tempered at 350-370℃, the MLAWS has achieved hardness above 60 HRC, tensile strength greater than 1 600 MPa, impact toughness higher than 18J/cm2 and fracture toughness greater than 37 MPa

  16. Interface reaction between nickel-base self-fluxing alloy coating and steel substrate

    Science.gov (United States)

    Otsubo, F.; Era, H.; Kishitake, K.

    2000-06-01

    The interface reaction between a nickel-base, self-fluxing alloy coating and a steel substrate has been investigated to examine the formation of “pores,” which are observed along the interface of used boiler tubes. It was found that lumpy precipitates form along the interface instead of pores after heating at high temperatures and that the precipitates are of Fe2B boride. The adhesion strength of the coating is not decreased by the formation of Fe2B precipitates along the interface because of the increase of the adhesion due to interdiffusion.

  17. Dynamic strain ageing of deformed nitrogen-alloyed AISI 316 stainless steels

    Energy Technology Data Exchange (ETDEWEB)

    Ehrnsten, U.; Toivonen, A. [Materials and Structural Integrity, VTT Technical Research Centre of Finland, Kemistintie 3, P.O. Box 1704, FIN-02044 VTT (Finland); Ivanchenko, M.; Nevdacha, V.; Yagozinskyy, Y.; Haenninen, H. [Department of Mechanical Engineering, Helsinki University of Technology Puumiehenkuja 3, P.O. Box 4200, FIN-02015 HUT (Finland)

    2004-07-01

    Intergranular stress corrosion cracking has occurred in BWR environment in non-sensitized, deformed austenitic stainless steel materials. The affecting parameters are so far not fully known, but deformation mechanisms may be decisive. The effect of deformation and nitrogen content on the behaviour of austenitic stainless steels was investigated. The materials were austenitic stainless steels of AISI 316L type with different amounts of nitrogen (0.03 - 0.18%) and they were mechanically deformed 0, 5 and 20%. The investigations are focused on the dynamic strain ageing (DSA) behaviour. A few crack growth rate measurements are performed on nuclear grade AISI 316NG material with different degrees of deformation (0, 5 and 20%). The effects of DSA on mechanical properties of these materials are evaluated based on peaks in ultimate tensile strength and strain hardening coefficient and minimum in ductility in the DSA temperature range. Additionally, internal friction measurements have been performed in the temperature range of -100 to 600 deg. C for determining nitrogen interactions with other alloying elements and dislocations (cold-worked samples). The results show an effect of nitrogen on the stainless steel behaviour, e.g. clear indications of dynamic strain ageing and changes in the internal friction peaks as a function of nitrogen content and amount of deformation. (authors)

  18. Examination of the Oxidation Protection of Zinc Coatings Formed on Copper Alloys and Steel Substrates

    Science.gov (United States)

    Papazoglou, M.; Chaliampalias, D.; Vourlias, G.; Pavlidou, E.; Stergioudis, G.; Skolianos, S.

    2010-01-01

    The exposure of metallic components at aggressive high temperature environments, usually limit their usage at similar application because they suffer from severe oxidation attack. Copper alloys are used in a wide range of high-quality indoor and outdoor applications, statue parts, art hardware, high strength and high thermal conductivity applications. On the other hand, steel is commonly used as mechanical part of industrial set outs or in the construction sector due to its high mechanical properties. The aim of the present work is the examination of the oxidation resistance of pack cementation zinc coatings deposited on copper, leaded brass and steel substrates at elevated temperature conditions. Furthermore, an effort made to make a long-term evaluation of the coated samples durability. The oxidation results showed that bare substrates appear to have undergone severe damage comparing with the coated ones. Furthermore, the mass gain of the uncoated samples was higher than this of the zinc covered ones. Particularly zinc coated brass was found to be more resistant to oxidation conditions in which it was exposed as it has the lower mass gain as compared to the bare substrates and zinc coated copper. Zinc coated steel was also proved to be more resistive than the uncoated steel.

  19. Characterization of microstructure obtained by quenching and partitioning process in low alloy martensitic steel

    International Nuclear Information System (INIS)

    Microstructure of low alloy martensitic steel treated by quenching and partitioning (Q and P) process was characterized by means of SEM, TEM, EBSD and XRD. Mechanical properties of steel processed by Q and P and the same steel processed by quenching and tempering (Q and T) were measured by uniaxial tensile test. The study suggests that microstructure is mainly composed of three phases, i.e. initial martensite, fresh martensite and retained austenite. The initial martensite formed at the first quenching step is easily etched; the fresh martensite is formed at the final quenching step and looks like 'blocky' type phase with size about 0.2-3 μm, and the retained austenite is mainly located on the packet boundary and initial austenite grain boundary. The measured volume fractions and carbon contents of these phases were slightly different from those predicted by the constrained paraequilibrium (CPE) model proposed by Speer, which was interpreted by the effects of the different grain sizes of the untransformed austenite after first quenching. Mechanical properties of steels processed by Q and P assume much higher strength and ductility than those processed by Q and T. It is concluded that Q and P process is a promising approach to control the multiphase structure with hard matrix and a ductile retained austenite, which gives an excellent combination of strength and ductility.

  20. Formation of nanostructured NiAl coating on carbon steel by using mechanical alloying

    Energy Technology Data Exchange (ETDEWEB)

    Mohammadnezhad, M., E-mail: M.mohammadnezhad@ma.iut.ac.ir [Department of Materials Engineering, Isfahan University of Technology, Isfahan 84156-83111 (Iran, Islamic Republic of); Shamanian, M.; Enayati, M.H. [Department of Materials Engineering, Isfahan University of Technology, Isfahan 84156-83111 (Iran, Islamic Republic of)

    2012-12-15

    Highlights: Black-Right-Pointing-Pointer Mechanical alloying process could be used for the deposition of nanostructured NiAl intermetallic coatings at ambient atmosphere. Black-Right-Pointing-Pointer Thicker coatings could be formed on the substrate and produced maximum value of around 470 {mu}m after treatment of 480 min. Black-Right-Pointing-Pointer The hardness of the coating on the substrate was more than seven times that of the initial steel substrate. Black-Right-Pointing-Pointer The diffraction patterns before heat treatment, suggests the NiAl intermetallic and another phase and after heat treatment, suggests completely a NiAl intermetallic at 480 min. - Abstract: Nanostructured NiAl intermetallics coatings were generated on carbon steel by using mechanical alloying in ambient temperature and pressure. Ni and Al powders were mixed with the composition of Ni-50 at% Al. The process involved powder particles trapped between the ball and cold welding at surface. Coatings were examined using X-ray diffraction, scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The results showed that the phase transmutation during process and subsequent heat treatment are strongly dependent on mechanical alloying time. After 480 min heat treatment of mechanically alloyed sample, only NiAl peaks were viewed. Ball encounters and failures consecutively reduced the coarse grains of the coating to the nanoscale. The size of nanocrystalline grains in the NiAl coating ranged between 28 and 130 nm. The creation of the coatings was studied at milling intervals between 60 and 600 min. The average thickness and hardness of the surface layers at 480 min, were 470 {mu}m and 930 HV, respectively.

  1. Dualism of precipitation morphology in high strength low alloy steel

    Energy Technology Data Exchange (ETDEWEB)

    Chih-Yuan, Chen, E-mail: chen6563@gmail.com [Department of Energy Engineering, National United University, Miaoli 36003, Taiwan (China); Department of Materials Science and Engineering, National Taiwan University, Taipei 10617, Taiwan (China); Chien-Chon, Chen [Department of Energy Engineering, National United University, Miaoli 36003, Taiwan (China); Jer-Ren, Yang, E-mail: jryang@ntu.edu.tw [Department of Materials Science and Engineering, National Taiwan University, Taipei 10617, Taiwan (China)

    2015-02-25

    While the role of microalloying elements on precipitation strengthening in ferrite matrix during austenite/ferrite transformation is quite clear, some uncertainty still exists concerning the variability of the microhardness distribution of ferrite grains in the isothermal holding condition. The objective of the present study was to clarify the intrinsic characteristics of carbide precipitation morphology in the ferrite matrix under different processing temperatures and times and to correlate it with austenite decomposition kinetics to elucidate why a large microhardness distribution occurs at low isothermal holding temperature. Better understanding of carbide precipitation behavior can help researchers to determine the root cause of variation in microhardness distribution, which would allow metallurgists to produce high quality steels. Measurement with a Vickers hardness indenter revealed that, in specimens isothermally held at 625 °C, the range of Vickers hardness distribution was 240–420 after 5 min of isothermal holding, and 270–340 after 60 min. For specimens isothermally held at 725 °C, the range of Vickers hardness distribution was 200–330 for 5 min of isothermal holding, and 200–250 for 60 min. Therefore, the average microhardness decreased with the isothermal holding temperature and time, and a larger range of distribution occurred with short isothermal holding times. Transmission electron microscopy (TEM) images showed that interface precipitation and random precipitation can occur within the same ferrite grain. The reason is that the austenite decomposition rate varies with transformation temperature and time. An excessively fast austenite/ferrite interface movement velocity, which usually happens in small ferrite grains, would cause these ferrite grains with microalloying elements to exceed their solubility. Furthermore, these microalloying elements will be precipitated randomly after isothermal holding at longer times. Consequently, a large

  2. Dualism of precipitation morphology in high strength low alloy steel

    International Nuclear Information System (INIS)

    While the role of microalloying elements on precipitation strengthening in ferrite matrix during austenite/ferrite transformation is quite clear, some uncertainty still exists concerning the variability of the microhardness distribution of ferrite grains in the isothermal holding condition. The objective of the present study was to clarify the intrinsic characteristics of carbide precipitation morphology in the ferrite matrix under different processing temperatures and times and to correlate it with austenite decomposition kinetics to elucidate why a large microhardness distribution occurs at low isothermal holding temperature. Better understanding of carbide precipitation behavior can help researchers to determine the root cause of variation in microhardness distribution, which would allow metallurgists to produce high quality steels. Measurement with a Vickers hardness indenter revealed that, in specimens isothermally held at 625 °C, the range of Vickers hardness distribution was 240–420 after 5 min of isothermal holding, and 270–340 after 60 min. For specimens isothermally held at 725 °C, the range of Vickers hardness distribution was 200–330 for 5 min of isothermal holding, and 200–250 for 60 min. Therefore, the average microhardness decreased with the isothermal holding temperature and time, and a larger range of distribution occurred with short isothermal holding times. Transmission electron microscopy (TEM) images showed that interface precipitation and random precipitation can occur within the same ferrite grain. The reason is that the austenite decomposition rate varies with transformation temperature and time. An excessively fast austenite/ferrite interface movement velocity, which usually happens in small ferrite grains, would cause these ferrite grains with microalloying elements to exceed their solubility. Furthermore, these microalloying elements will be precipitated randomly after isothermal holding at longer times. Consequently, a large

  3. Newly Designed Cr-Mn Alloyed Ultra-high Strength Steel without Boron Addition for Hot-stamping Processing

    Institute of Scientific and Technical Information of China (English)

    Guo-hui ZHU; Hong-bing ZHOU; Qin-yi LI; Qi-wei CHEN; Hai-rong GU; Yong-gang LIU

    2015-01-01

    A newly designed hot-stamping steel alloyed by chromium (Cr)and manganese (Mn)without boron (B) addition was developed for automobile mass reduction.The experimental results showed the Cr-Mn alloyed steel could be quenched to full martensite microstructure when the cooling rate was higher than 1 4 ℃/s.Yield strength, tensile strength and elongation of the experimental hot stamping part reached 1 1 8 0 MPa,1 6 4 5 MPa and 8.4%, respectively.The experimental hot stamping part possessed higher tensile strength and elongation,compared with conventional hot-stamping steel of 2 2 MnB5 .Furthermore,excellent processing flexibility would be obtained in this novel hot-stamping steel because of its lower critical cooling rate and phase transformation temperature.The design of the composition and investigations of microstructure,mechanical properties and hot-stamping processing were also studied.

  4. Brazing open cell reticulated copper foam to stainless steel tubing with vacuum furnace brazed gold/indium alloy plating

    Science.gov (United States)

    Howard, Stanley R.; Korinko, Paul S.

    2008-05-27

    A method of fabricating a heat exchanger includes brush electroplating plated layers for a brazing alloy onto a stainless steel tube in thin layers, over a nickel strike having a 1.3 .mu.m thickness. The resultant Au-18 In composition may be applied as a first layer of indium, 1.47 .mu.m thick, and a second layer of gold, 2.54 .mu.m thick. The order of plating helps control brazing erosion. Excessive amounts of brazing material are avoided by controlling the electroplating process. The reticulated copper foam rings are interference fit to the stainless steel tube, and in contact with the plated layers. The copper foam rings, the plated layers for brazing alloy, and the stainless steel tube are heated and cooled in a vacuum furnace at controlled rates, forming a bond of the copper foam rings to the stainless steel tube that improves heat transfer between the tube and the copper foam.

  5. Calculation of the end-rolling strength in Q235 strip steel by the alloying electron structure parameters

    Institute of Scientific and Technical Information of China (English)

    LIU Zhilin; LIN Cheng; LIU Yan; GUO Yanchang

    2005-01-01

    Combined with the phase transformations in rolling, the phase configuration, the tensile strength, and the yield strength with different terminal rolling grain sizes in Q235 strip steel have been theoretically calculated using the covalent electron number (nA) of the strongest bond in phase cells and the interface electron density difference (Ap) in alloys. The calculated results agree well with the results of real production. Therefore, the calculation method of terminal rolling tensile and yield strength in the non-quenched-tempered steel containing pearlite is given by the alloying electron structure parameters.

  6. Electrochemical Behavior and Microstructure of Recyclable Aluminium-magmesium Alloy Hot-dip Coating Deposited on Low Carbon Steel Substrates

    Institute of Scientific and Technical Information of China (English)

    Panomkorn KWAKHONG; Apichart ARTNASEAW; Chaiyaput KRUEHONG

    2015-01-01

    With the abundance and good corrosion resistance of aluminium, hot-dip technique was used to prepare the recycled Al with 8.2 mass% Mg alloy coating on low carbon steel substrates. Electrochemical behavior of this coating was investigated by an-odic polarization and open circuit potential measurement. Its microstructure and composition were observed by scanning electron microscope and energy-dispersive X-ray spectrometry, respectively. The long lasting corrosion performance of coated steels was in-vestigated under the salt fog spray test. From anodic polarization curves and open circuit potential, recycled Al with 8.2 mass% Mg coating performed adequate sacriifcial ability. At 0.40 V, current density of recycled Al with 8.2 mass% Mg alloy coating was about 200 000 times higher than that of pure recycled Al coating, and was about 0.5 times lower than that of Zn coating. The microstruc-ture of recycled Al with 8.2 mass% Mg alloy coating on the steel substrate consisted of Al3Mg2, Al-Fe intermetallic compound and Al matrix. The results from salt fog spray test showed that recycled Al with 8.2 mass% Mg alloy coated steel had similar corrosion resistance ability to Zn coated steel.

  7. Tempering of martensitic steel for fasteners: Effects of micro-alloying on microstructure and mechanical property evolution

    OpenAIRE

    Öhlund, C.E.I.C.

    2015-01-01

    The research presented in this thesis aims to deepen our understanding of the effect of micro-alloying on the microstructure and mechanical property evolution during tempering of martensitic steel for fasteners. The ongoing trend of engine down-sizing has led to the need for stronger and more temperature resistant fasteners than currently available according to international standards. A new martensitic fastener steel called KNDS4 has been developed, that combines higher strength with improve...

  8. Effect of welding processes on mechanical and microstructural characteristics of high strength low alloy naval grade steel joints

    OpenAIRE

    S. Ragu Nathan; V. Balasubramanian; S. Malarvizhi; Rao, A G

    2015-01-01

    Naval grade high strength low alloy (HSLA) steels can be easily welded by all types of fusion welding processes. However, fusion welding of these steels leads to the problems such as cold cracking, residual stress, distortion and fatigue damage. These problems can be eliminated by solid state welding process such as friction stir welding (FSW). In this investigation, a comparative evaluation of mechanical (tensile, impact, hardness) properties and microstructural features of shielded metal ar...

  9. Characterization of Nanocrystallizatin Surface Layer of 0.4C-1Cr Low Alloy Steel Prepared by Ultrasonic Particulate Peening

    Institute of Scientific and Technical Information of China (English)

    ZHANGJun-bao; LIUYu-liang; ZHAOXin-qi; WUJie; SONGHong-wei; XIONGTian-ying

    2004-01-01

    A nanostructured surface layer was fabricated in a quenched and tempered 0.4C-ICr low alloy steel by ultrasonic particulate peening technique. The microstructure of the nanocrystalline surface layer was characterized by means of TEM and Moessbauer spectroscopy. Experimental results reveal that both cementite and ferrite nanocrystals with an average size of 5 nm were formed in the surface layer of the steel, phase transformation of austenite and dissolution of cementite maybe occur in the process of ultrasonic particulate peening.

  10. Characterization of Nanocrystallizatin Surface Layer of 0.4C-1Cr Low Alloy Steel Prepared by Ultrasonic Particulate Peening

    Institute of Scientific and Technical Information of China (English)

    ZHANG Jun-bao; LIU Yu-liang; ZHAO Xin-qi; WU Jie; SONG Hong-wei; XIONG Tian-ying

    2004-01-01

    A nanostructured surface layer was fabricated in a quenched and tempered 0.4C-1Cr low alloy steel by ultrasonic particulate peening technique. The microstructure of the nanocrystalline surface layer was characterized by means of TEM and Mossbauer spectroscopy. Experimental results reveal that both cementite and ferrite nanocrystals with an average size of 5 nm were formed in the surface layer of the steel, phase transformation of austenite and dissolution of cementite maybe occur in the process of ultrasonic particulate peening.

  11. Modeling of primary dendrite arm spacing variations in thin-slab casting of low carbon and low alloy steels

    OpenAIRE

    Mehrara, H; Santillana, B; Eskin, DG; Boom, R; Katgerman, L; Abbel, G

    2011-01-01

    Solidification structure of a High Strength Low Alloy (HSLA) steel, in terms of dendrite arm spacing distribution across the shell thickness, is studied in a breakout shell from a thin-slab caster at Tata Steel in IJmuiden. Columnar dendrites were found to be the predominant morphology throughout the shell with size variations across the shell thickness. Primary Dendrite Arm Spacing (PDAS) increases by increasing the distance from meniscus or slab surface. Subsequently, a model is proposed to...

  12. Influence of the pulsed plasma treatment on the corrosion resistance of the low-alloy steel plated by Ni-based alloy

    Science.gov (United States)

    Dzhumaev, P.; Yakushin, V.; Kalin, B.; Polsky, V.; Yurlova, M.

    2016-04-01

    This paper presents investigation results of the influence of high temperature pulsed plasma flows (HTPPF) treatment on the corrosion resistance of low-alloy steel 0.2C-Cr-Mn- Ni-Mo cladded by the rapidly quenched nickel-based alloy. A technique that allows obtaining a defect-free clad layer with a good adhesion to the substrate was developed. It is shown that the preliminary treatment of steel samples by nitrogen plasma flows significantly increases their corrosion resistance in the conditions of intergranular corrosion test in a water solution of sulfuric acid. A change of the corrosion mechanism of the clad layer from intergranular to uniform corrosion was observed as a result of sub-microcrystalline structure formation and homogeneous distribution of alloying elements in the plasma treated surface layer thus leading to the significant increase of the corrosion resistance.

  13. Alloying the X40CrMoV5-1 steel surface layer with tungsten carbide by the use of a high power diode laser

    International Nuclear Information System (INIS)

    The paper presents the effect of alloying with tungsten carbide on properties of the X40CrMoV5-1 steel surface layer, using the high power diode laser (HPDL). Selection of laser operating conditions is discussed, as well as thickness of the alloying layer, and their influence on structure and chemical composition of the steel. Analysis of the influence of the process conditions on the thicknesses of the alloyed layer and heat-affected zone is presented

  14. Alloying the X40CrMoV5-1 steel surface layer with tungsten carbide by the use of a high power diode laser

    Energy Technology Data Exchange (ETDEWEB)

    Dobrzanski, L.A. [Institute of Engineering Materials and Biomaterials, Silesian University of Technology, 44-100 Gliwice, Konarskiego St. 18A (Poland); Bonek, M. [Institute of Engineering Materials and Biomaterials, Silesian University of Technology, 44-100 Gliwice, Konarskiego St. 18A (Poland)]. E-mail: mb@zmn.mt.polsl.gliwice.pl; Hajduczek, E. [Institute of Engineering Materials and Biomaterials, Silesian University of Technology, 44-100 Gliwice, Konarskiego St. 18A (Poland); Klimpel, A. [Welding Department, Silesian University of Technology, 44-100 Gliwice, Konarskiego St. 18A (Poland)

    2005-07-15

    The paper presents the effect of alloying with tungsten carbide on properties of the X40CrMoV5-1 steel surface layer, using the high power diode laser (HPDL). Selection of laser operating conditions is discussed, as well as thickness of the alloying layer, and their influence on structure and chemical composition of the steel. Analysis of the influence of the process conditions on the thicknesses of the alloyed layer and heat-affected zone is presented.

  15. Gas bubbles evolution peculiarities in ferritic-martensitic and austenitic steels and alloys under helium-ion irradiation

    Science.gov (United States)

    Chernov, I. I.; Kalashnikov, A. N.; Kalin, B. A.; Binyukova, S. Yu

    2003-12-01

    Transmission electron microscopy has been used to investigate the gas bubble evolution in model alloys of the Fe-C system, ferritic-martensitic steels of 13Cr type, nickel and austenitic steels under 40-keV helium-ion irradiation up to a fluence of 5 × 10 20 m -2 at the temperature of 920 K. It was shown that helium-ion irradiation at high temperature resulted in formation of bubbles with a greater size and a smaller density in Fe and ferritic-martensitic steels than those in nickel and austenitic steels. Large gaseous bubbles in ferritic component are uniformly distributed in grains body in Fe-C alloys as well as in ferritic-martensitic steels. The bubbles with a higher density and a smaller size than those in ferritic component are formed in martensitic grains of steels and Fe-C alloys with a high carbon content ( NC>0.01 wt%), which leads to a small level of swelling of martensite in comparison with that of ferrite. In addition, the bubbles in martensitic grains have a tendency to ordered distribution.

  16. Gas bubbles evolution peculiarities in ferritic-martensitic and austenitic steels and alloys under helium-ion irradiation

    Energy Technology Data Exchange (ETDEWEB)

    Chernov, I.I. E-mail: chernov@phm.mephi.ru; Kalashnikov, A.N.; Kalin, B.A.; Binyukova, S.Yu

    2003-12-01

    Transmission electron microscopy has been used to investigate the gas bubble evolution in model alloys of the Fe-C system, ferritic-martensitic steels of 13Cr type, nickel and austenitic steels under 40-keV helium-ion irradiation up to a fluence of 5 x 10{sup 20} m{sup -2} at the temperature of 920 K. It was shown that helium-ion irradiation at high temperature resulted in formation of bubbles with a greater size and a smaller density in Fe and ferritic-martensitic steels than those in nickel and austenitic steels. Large gaseous bubbles in ferritic component are uniformly distributed in grains body in Fe-C alloys as well as in ferritic-martensitic steels. The bubbles with a higher density and a smaller size than those in ferritic component are formed in martensitic grains of steels and Fe-C alloys with a high carbon content (N{sub C}>0.01 wt%), which leads to a small level of swelling of martensite in comparison with that of ferrite. In addition, the bubbles in martensitic grains have a tendency to ordered distribution.

  17. Superfluid helium testing of a stainless steel to titanium piping transition joint

    Energy Technology Data Exchange (ETDEWEB)

    Soyars, W.; /Fermilab; Basti, A.; Bedeschi, F.; /INFN, Pisa; Budagov, J.; /Dubna, JINR; Foley, M.; Harms, E.; Klebaner, A.; Nagaitsev, S.; /Fermilab; Sabirov, B.; Dubna, JINR

    2009-11-01

    Stainless steel-to-titanium bimetallic transitions have been fabricated with an explosively bonded joint. This novel joining technique was conducted by the Russian Federal Nuclear Center, working under contract for the Joint Institute for Nuclear Research. These bimetallic transitions are being considered for use in future superconducting radio-frequency cavity cryomodule assemblies. This application requires cryogenic testing to demonstrate that this transition joint remains leak-tight when sealing superfluid helium. To simulate a titanium cavity vessel connection to a stainless steel service pipe, bimetallic transition joints were paired together to fabricate piping assemblies. These piping assemblies were then tested in superfluid helium conditions at Fermi National Accelerator Laboratory test facilities. The transition joint test program will be described. Fabrication experience and test results will be presented.

  18. Development of Semi-Stochastic Algorithm for Optimizing Alloy Composition of High-Temperature Austenitic Stainless Steels (H-Series) for Desired Mechanical and Corrosion Properties.

    Energy Technology Data Exchange (ETDEWEB)

    Dulikravich, George S.; Sikka, Vinod K.; Muralidharan, G.

    2006-06-01

    The goal of this project was to adapt and use an advanced semi-stochastic algorithm for constrained multiobjective optimization and combine it with experimental testing and verification to determine optimum concentrations of alloying elements in heat-resistant and corrosion-resistant H-series stainless steel alloys that will simultaneously maximize a number of alloy's mechanical and corrosion properties.

  19. Effect of copper precipitates on the toughness of low alloy steels for pressure boundary components

    Energy Technology Data Exchange (ETDEWEB)

    Foehl, J.; Willer, D.; Katerbau, K.H. [Materialpruefungsanstalt, Univ. Stuttgart (Germany)

    2004-07-01

    The ferritic bainitic steel 15NiCuMoNb5 (WB 36)is widely used for pressure boundary components. Due to the high copper content which leads to precipitation hardening high strength and toughness are characteristic for this type of steel. However, in the initial state, there is still a high amount of dissolved copper in an oversaturated state which makes the steel susceptible to thermal ageing. Ageing and annealing experiments were performed, and the change in microstructure was investigated by small angle neutron scattering (SANS), measurements of the residual electric resistance and hardness measurements. A correlation between micro structural changes and changes in mechanical properties could be established. It could clearly be shown that significant effects on strength and toughness have to be considered when the size of the copper rich precipitates vary in the range from 1.2 to 2.2 nm in radius. The changes in microstructure affect both, the Carpy impact transition temperature and the fracture toughness qualitatively and quantitatively in a similar way. The investigations have contributed to a better understanding of precipitation hardening by copper not only for this type of steel but also for copper containing steels and weld subjected to neutron irradiation. (orig.)

  20. XPS and micro-mechanical characterisation of nitrogen ion implanted low alloy steel

    Institute of Scientific and Technical Information of China (English)

    A.O.Olofinjana; Z.Chen; J.M.Bell

    2001-01-01

    The surface composition of low alloy steel after N2+ implantation was studied with X-rayphoto-electron spectroscopy (XPS). The effect of the implantation on the mechanical hardnesswas evaluated by ultra-micro hardness indentation. Chemical characterisation of the surface indi-cated that a thin layer rich in N, C and Si was formed. It is shown that Fe played little role in thechemical composition and the structure of the modified surface. The mechanical hardness of N2+implanted surface was 35-50 GPa compared with a value of 10 GPa for the untreated sample. Itis thought that the high hardness observed on the surface and in the sub-surface was as a resultof chemical modification to form a film of Si doped carbon nitride. There is strong evidence fromthe XPS and the nanoindentation studies that the bonding structure of the C-N in the near surfaceis essentially sp3 types expected in crystalline C3N4. The value of nitrogen ion implantation asprocess for improving the wear resistance of low alloy steels is emphasized.

  1. Tribological Properties of WS2 Nanoparticles Lubricants on Aluminum-Silicon Alloy and Carbon Steels

    Directory of Open Access Journals (Sweden)

    Riyadh A. AL-SAMARAI

    2013-06-01

    Full Text Available The rheological properties of nanometric tungsten disulphide (WS2 nanoparticles oil lubricants and its tribological performance with two hypereutectic Al-Si alloy and carbon steel are examined. These two oils are used to reduce wear and friction and to explore the actions via tribological pin-on-disk tests. The pin was made from hypereutectic Al-Si alloy on steel disk, taking into consideration the effect of loads (10, 20, 30 N and different speed (200, 300, 400 rpm. Oils with and without WS2 nanoparticles reveal the loss rate due to friction. The results show that WS2 nanoparticles oil-dispersed lubricants are capable of reducing wear, improved by a mechanism which was characterized not only by the viscosity of the WS2 nanoparticles suspensions but also the promotion of contact’s surface as combined anti-corrosion, as well as effective reduction of friction on the surface film. Therefore, a lubricant added to nanoparticles can protect the piston surface.

  2. Strain-induced Precipitation in Ti Micro-alloyed Interstitial-free Steel

    Institute of Scientific and Technical Information of China (English)

    Ya-jun HUI; Yang YU; Lin WANG; Chang WANG; Wen-yuan LI; Bin CHEN

    2016-01-01

    Stress relaxation method was carried out on a Ti micro-alloyed interstitial-free (IF)steel at the tempera-ture ranging from 800 to 1 000 ℃.The results show that the softening kinetics curves of deformed austenite can be divided into three stages.At the first stage,the stress has a sharp drop due to the onset of recrystallization.At the second stage,a plateau appears on the relaxation curves indicating the start and finish of strain-induced precipitation. At the third stage,the stress curves begin to descend again because of coarsening of precipitates.Precipitation-time-temperature (PTT)diagram exhibited a “C”shape,and the nose point of the PTT diagram is located at 900 ℃ and the start precipitation time of 10 s.The theoretical calculation shows that the strain-induced precipitates were con-firmed as almost pure TiC particles.The TiC precipitates were heterogeneously distributed in either a chain-like or cell-like manner observed by transmission electron microscopy (TEM),which indicates the precipitates nucleated on dislocations or dislocation substructures.In addition,a thermodynamic analytical model was presented to describe the precipitation in Ti micro-alloyed IF steel,which shows a good agreement between the experimental observation and the predictions of the model.

  3. Effects of Mo Composites on the Corrosion Behaviors of Low Alloy Steel

    Institute of Scientific and Technical Information of China (English)

    LIANG Chenghao; GUO Jianwei; HU Xianqi

    2007-01-01

    By using electrochemical and weight loss methods, the effect of MoO42-on the corrosion behaviors of low alloy steel was investigated in the 55%LiBr+0.07 mol/L LiOH solution at high temperature.The results show that MoO42-, being an anodic inhibitor, would form a passive film rapidly and impede both anodic and cathodic reactions. Moreover, Na2MoO4 effectively prevents corrosion in 55%LiBr+0.07 mol/L LiOH solution when its concentration is higher than 200 mg/L. Some elements of alloy, such as chromium and nickel, may cause the widening of passive potential region and the decrease of passive density, which indicates that the corrosion resistance increases. AES analysis shows that molybdenum participates in forming a protection film. The synergistic effect between chromium and molybdenum induces Cr-steel to be in passive state in lower Na2MoO4 concentration.

  4. Research and service experience with environmentally assisted cracking of low-alloy steel

    Energy Technology Data Exchange (ETDEWEB)

    Hickling, J. [Electric Power Reasearch Inst., Palo Alto, CA (United States); Seifert, H.P.; Ritter, S. [Paul Scherrer Inst. (Switzerland)

    2005-01-01

    Environmentally assisted cracking (EAC) of carbon and low-alloy steels has been identified as a possible degradation mechanism for pressure vessels and piping in nuclear power plants. Selected aspects of research and service experience with cracking of these materials in high-temperature water are reviewed, with special emphasis on the primary pressure boundary in boiling water reactors. The main factors controlling EAC susceptibility under reactor conditions are discussed with regard to both crack initiation and crack growth. The adequacy and conservatism of the relevant engineering criteria for component design and disposition of detected or postulated flaws are evaluated in the context of recent research results, e.g., on the effects of so-called ''ripple loading'' or of water chemistry transients. Finally, the relevant operating experience over the last 30 years is briefly summarized and compared with the background knowledge which has been accumulated in more recent laboratory experiments. Some of the insights gained in this work may also be of value in improving understanding and prediction of the EAC behavior of carbon and low-alloy steels in certain fossil plant components, if appropriate allowances are made for differences in temperature and water chemistry. (orig.)

  5. Mechanical properties of low-alloy-steels with bainitic microstructures and varying carbon content

    Science.gov (United States)

    Weber, A.; Klarner, J.; Vogl, T.; Schöngrundner, R.; Sam, G.; Buchmayr, B.

    2016-03-01

    Materials used in the oilfield industry are subjected to special conditions. These requirements for seamless steel tubes are between the priorities of strength, toughness and sour gas resistance. Steels with bainitic microstructure provide a great opportunity for those harsh environmental conditions. With different morphologies of bainite, like carbide free, upper or lower bainite, the interaction of high tensile strength and elongation is assumed to be better than with tempered martensite. To form carbide free bainite two ways of processing are proposed, isothermal holding with accurate time control or controlled continuous cooling. Both require knowledge of time-temperature transformation behaviour, which can be reached through a detailed alloying concept, focused on the influence of silicon to supress the carbide nucleation and chromium to stabilize the austenite fraction. The present work is based on three alloys with varying silicon and chromium contents. The carbide free microstructure is obtained by a continuous cooling path. Additionally different heat treatments were done to compare the inherent performance of the bainitic morphologies. The bainitic structures were characterized metallographically for their microstructure and the primary phase by means of transmission electron microscopy. The mechanical properties of carbide-free structures were analysed with quasi-static tensile tests and Charpy impact tests. Moreover, investigations about hydrogen embrittlement were done with focus on the effect of retained austenite. The results were ranked and compared qualitatively.

  6. Original position statistic distribution analysis study of low alloy steel continuous casting billet

    Institute of Scientific and Technical Information of China (English)

    WANG Haizhou; ZHAO Pei; CHEN Jiwen; LI Meiling; YANG Zhijun; WU Chao

    2005-01-01

    The homogeneity of low alloy steels continuous casting billet obtained under different technological conditions has been investigated by original position statistic distribution analysis technique. On the basis of systematic analysis of ten thousands primary optical signals at the corresponding original positions, the quantitative statistic distribution information of each element was obtained. The biggest degrees of segregation of low alloy steel continuous casting billet were calculated accurately according to the quantitative distribution maps of the contents. It was suggested that the weight ratio in a certain content range was used to judge the homogeneity of the materials, and the two models -- the total weight ratio of contents (the degree of statistic homogeneity, H) within the permissive content range (C0±R) and the median value confidence extension ratio (the degree of statistic segregation, S) at 95% of confidence limit of weight ratio -- were put forward. The two models reflect the composition and state distribution regularity of the metal materials in a large region. The difference between the sample with high columnar crystal and the sample with high equiaxed crystal has been studied by using the two models.

  7. Fracture Toughness (K1C) evaluation for dual phase medium carbon low alloy steels using circumferential notched tensile (CNT) specimens

    OpenAIRE

    Kenneth Kanayo Alaneme

    2011-01-01

    The fracture behavior of dual phase medium carbon low alloy steels produced using two different chemical compositions (A - 0.34C, 0.75Mn, 0.12Cr, 0.13Ni steel and B - 0.3C, 0.97Mn, 0.15Cr steel) was investigated using circumferential notched tensile (CNT) specimens. Intercritical treatments were performed on samples with composition A by 1) austenitizing at 860 °C for 1 hour cooling in air, then treating at 770 °C for 30 minutes before oil quenching; 2) austenitizing at 860 °C for 1 hour quen...

  8. Initiation of environmentally-assisted cracking in low-alloy steels

    Energy Technology Data Exchange (ETDEWEB)

    Wire, G.L.; Li, Y.Y.

    1996-06-01

    Environmentally-Assisted Cracking (EAC) in low alloy steels is activated by a critical level of sulfide ions at the crack tip, which is produced from dissolution of sulfide inclusions (MnS, FeS, etc.) in the steel following exposure by a growing crack. EAC of concern herein is the increase of fatigue crack growth rate of up to 40 to 100 times the rate in air that occurs at 240--300 C in high temperature LWR or boiler water environments. The initiation of EAC is the onset of the higher fatigue crack growth rates in fully developed cracks already presumed to be present due to fatigue, stress corrosion cracking, or induced by fabrication. Initiation of EAC is induced by a change in loading parameters causing the fatigue crack growth rate to increase from a small multiple (2--4) to 40--100 times the air rate. A steady state theory developed by Combrade, suggests that EAC will initiate only above a critical crack velocity and cease below this same velocity. However, more recent tests show that EAC can persist down to much lower velocities (100 times lower) in low oxygen water at slightly lower temperatures. A special set of experiments on high sulfur plate material demonstrate that EAC will not initiate from surface cracks with low sulfide inventories at low crack tip velocities. Transient diffusion calculations show that a finite crack extension at a high crack tip velocity is necessary to initiate EAC, providing a possible explanation for the lack of high crack growth observations reported in low alloy steels in structural applications involving low oxygen environments.

  9. Quantitative observations of hydrogen-induced, slow crack growth in a low alloy steel

    Science.gov (United States)

    Nelson, H. G.; Williams, D. P.

    1973-01-01

    Hydrogen-induced slow crack growth, da/dt, was studied in AISI-SAE 4130 low alloy steel in gaseous hydrogen and distilled water environments as a function of applied stress intensity, K, at various temperatures, hydrogen pressures, and alloy strength levels. At low values of K, da/dt was found to exhibit a strong exponential K dependence (Stage 1 growth) in both hydrogen and water. At intermediate values of K, da/dt exhibited a small but finite K dependence (Stage 2), with the Stage 2 slope being greater in hydrogen than in water. In hydrogen, at a constant K, (da/dt) sub 2 varied inversely with alloy strength level and varied essentially in the same complex manner with temperature and hydrogen pressure as noted previously. The results of this study provide support for most of the qualitative predictions of the lattice decohesion theory as recently modified by Oriani. The lack of quantitative agreement between data and theory and the inability of theory to explain the observed pressure dependence of slow crack growth are mentioned and possible rationalizations to account for these differences are presented.

  10. Formation of nanostructured NiAl coating on carbon steel by using mechanical alloying

    Science.gov (United States)

    Mohammadnezhad, M.; Shamanian, M.; Enayati, M. H.

    2012-12-01

    Nanostructured NiAl intermetallics coatings were generated on carbon steel by using mechanical alloying in ambient temperature and pressure. Ni and Al powders were mixed with the composition of Ni-50 at% Al. The process involved powder particles trapped between the ball and cold welding at surface. Coatings were examined using X-ray diffraction, scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The results showed that the phase transmutation during process and subsequent heat treatment are strongly dependent on mechanical alloying time. After 480 min heat treatment of mechanically alloyed sample, only NiAl peaks were viewed. Ball encounters and failures consecutively reduced the coarse grains of the coating to the nanoscale. The size of nanocrystalline grains in the NiAl coating ranged between 28 and 130 nm. The creation of the coatings was studied at milling intervals between 60 and 600 min. The average thickness and hardness of the surface layers at 480 min, were 470 μm and 930 HV, respectively.

  11. Effect of plasma nitrided layers on low- alloy steel on its hydrogen degradation

    Directory of Open Access Journals (Sweden)

    A. Zieliński

    2006-04-01

    Full Text Available Purpose: Purpose of this paper is evaluation of susceptibility to hydrogen degradation of structural low-alloy steel, plasma nitrided in the atmosphere with various contents of N2 and H2.Design/methodology/approach: Susceptibility of 34CrAlNi7-10 steel and samples with various plasma nitrided layers have been evaluated under monotonically increasing load in 0.005 M H2SO4 solution. Slow-strain rate tensile test (SSRT test was carried out under cathodic polarisation. Elongation, reduction in area, fracture energy and tensile strength were chosen as measures of susceptibility to hydrogen embrittlement. Fracture modes of failed samples were examined with the use of scanning electron microscope (SEM.Findings: All tested samples revealed susceptibility to hydrogen degradation under hydrogenation. Samples with nitrided layer have lower lost of reduction in are than base metal samples. The nitrided layer established in standard atmosphere 30% H2 and 70% N2 has the highest resistance to hydrogen degradation.Research limitations/implications: Further research should be taken to reveal the exact mechanism of increased plasticity of nitided layer with absorbed hydrogen.Practical implications: Plasma nitriding may prevent hydrogen charging of machines and vehicles parts in hydrogen generating environments, and thus decreasing susceptibility to hydrogen embrittlement.Originality/value: Under the increasing load and hydrogen generating environments plasma nitrided layers are effective barriers to hydrogen entry into a bulk of steel, and additionally increased plasticity of nitrided layers with absorbed hydrogen was observed.

  12. Surface properties of low alloy steel treated by plasma nitrocarburizing prior to laser quenching process

    Science.gov (United States)

    Wang, Y. X.; Yan, M. F.; Li, B.; Guo, L. X.; Zhang, C. S.; Zhang, Y. X.; Bai, B.; Chen, L.; Long, Z.; Li, R. W.

    2015-04-01

    Laser quenching (LQ) technique is used as a part of duplex treatments to improve the thickness and hardness of the surface layers of steels. The present study is to investigate the surface properties of low alloy steel treated by plasma nitrocarburizing (PNC) prior to a laser quenching process (PNC+LQ). The microstructure and properties of PNC+LQ layer determined are compared with those obtained by PNC and LQ processes. OM, XRD, SEM and EDS analyses are utilized for microstructure observation, phases identification, morphology observation and chemical composition detection, respectively. Microhardness tester and pin-on-disc tribometer are used to investigate the mechanical properties of the modified layers. Laser quenching of plasma nitrocarburized (PNC+LQ) steel results in much improved thickness and hardness of the modified layer in comparison with the PNC or LQ treated specimens. The mechanism is that the introduction of trace of nitrogen decreases the eutectoid point, that is, the transformation hardened region is enlarged under the same temperature distribution. Moreover, the layer treated by PNC+LQ process exhibits enhanced wear resistance, due to the lubrication effect and optimized impact toughness, which is contributed to the formation of oxide film consisting of low nitrogen compound (FeN0.076) and iron oxidation (mainly of Fe3O4).

  13. Friction stir weld assisted diffusion bonding of 5754 aluminum alloy to coated high strength steels

    International Nuclear Information System (INIS)

    Highlights: • Successful lap joints of Al 5754 sheet to coated DP600 and 22MnB5 steels. • Negligible effect of welding speed on mechanical properties of Al 5754/22MnB5 joints. • Lower strength of Al 5754/22MnB5 joints compared with Al 5754/DP600 joints. - Abstract: In the present paper friction stir-induced diffusion bonding is used for joining sheets of 5754 aluminum alloy to coated high strength steels (DP600 and 22MnB5) by promoting diffusion bonding in an overlap configuration. Mechanical performance and microstructures of joints were analyzed by overlap shear testing, metallography, and X-ray diffraction. Our results show that the strength of joint is dependent upon tool travel speed and the depth of the tool pin relative to the steel surface. The thickness and types of intermetallic compounds formed at the interface play a significant role in achieving a joint with optimum performance. That is, the formation of high aluminum composition intermetallic compounds (i.e. Al5Fe2) at the interface of the friction stir lap joint appeared to have a more negative effect on joint strength compared to the presence of high iron composition intermetallic phases (i.e. FeAl). This is in agreement with previously reported findings that FeAl intermetallic can improve the fracture toughness and interface strength in Al/St joints

  14. Strengthening Mechanisms for Ti-and Nb-Ti-micro-alloyed High-strength Steels

    Institute of Scientific and Technical Information of China (English)

    Chuan-feng MENG; Yi-de WANG; Ying-hui WEI; Bin-qing SHI; Tian-xie CUI; Yu-tian WANG

    2016-01-01

    The strengthening mechanisms of hot-rolled steels micro-alloyed with Ti (ST-TQ500)and Nb-Ti (NT-TQ500)were investigated by examining the microstructures of steels using optical microscope (OM),scanning elec-tron microscope (SEM)and transmission electron microscope (TEM).The results revealed almost no differences in the solute solution strengthening and fine-grained strengthening of the two steels,whereas the contributions of pre-cipitation strengthening and dislocation strengthening were different for ST-TQ500 and NT-TQ500.The measured precipitation strengthening effect of ST-TQ500 was 88 MPa higher than that of NT-TQ500;this difference was pri-marily attributed to the stronger precipitation effect of the Ti-containing nanoscale particles.The dislocation strengthening effect of ST-TQ500 was approximately 80 MPa lower than that of NT-TQ500.This is thought to be related to differences in deformation behavior during the finishing rolling stage;the inhibition of dynamic recrystalli-zation from Nb in NT-TQ500 (Nb-Ti)may lead to higher density of dislocations in the microstructure.

  15. Microstructure and formability of ZnNi alloy electrodeposited sheet steel

    Energy Technology Data Exchange (ETDEWEB)

    Lin, C.S.; Lee, H.B.; Hsieh, S.H.

    2000-02-01

    ZnNi alloy electrodeposited sheet steels were made from a chloride bath using a high-speed flow cell. A Ni-rich flash coating was deposited first, upon which the ZnNi coating, with Ni contents ranging from 8 to 16 wt pct, was subsequently electrodeposited. It is demonstrated that the Ni content of the coating affects the forming properties and microstructure of the ZnNi coatings. The hardness of the ZnNi coating increased with Ni content, leading to poor formability and inferior adhesion of the coated steels, as evident from the large amount of coating loss during swift cupping and coating peel-off during low-temperature adhesion tests. On the other hand, the friction force between the coated steel and cupping die decreased with increasing Ni content. At low Ni contents of 8 wt pct, the coating had a porous equiaxed grain structure. As the Ni content increased, the coating surface changed to dense faceted morphologies. A pyramid morphology was observed for 16 wt pct ZnNi coatings. An X-ray diffraction (XRD) analysis showed that all coatings containing up to 16 wt pct Ni contained only {gamma} phase. Transmission electron microscopy (TEM) observations showed the 8 wt pct Ni coating to have a fine-grained structure, which changed to a columnar structure at 16 wt pct Ni. The formation of the columnar structure is explained by the smaller amount of hydrogen discharge as the bath Ni ion concentration increased.

  16. Transition in Deformation Mechanism of AZ31 Magnesium Alloy during High-Temperature Tensile Deformation

    Directory of Open Access Journals (Sweden)

    Masafumi Noda

    2011-01-01

    Full Text Available Magnesium alloys can be used for reducing the weight of various structural products, because of their high specific strength. They have attracted considerable attention as materials with a reduced environmental load, since they help to save both resources and energy. In order to use Mg alloys for manufacturing vehicles, it is important to investigate the deformation mechanism and transition point for optimizing the material and vehicle design. In this study, we investigated the transition of the deformation mechanism during the high-temperature uniaxial tensile deformation of the AZ31 Mg alloy. At a test temperature of 523 K and an initial strain rate of 3×10−3 s-1, the AZ31 Mg alloy (mean grain size: ~5 μm exhibited stable deformation behavior and the deformation mechanism changed to one dominated by grain boundary sliding.

  17. Tempering of martensitic steel for fasteners: Effects of micro-alloying on microstructure and mechanical property evolution

    NARCIS (Netherlands)

    Öhlund, C.E.I.C.

    2015-01-01

    The research presented in this thesis aims to deepen our understanding of the effect of micro-alloying on the microstructure and mechanical property evolution during tempering of martensitic steel for fasteners. The ongoing trend of engine down-sizing has led to the need for stronger and more temper

  18. 75 FR 57444 - Certain Seamless Carbon and Alloy Steel Standard, Line, and Pressure Pipe from the People's...

    Science.gov (United States)

    2010-09-21

    ... Standard, Line, and Pressure Pipe From China, 74 FR 57521 (November 6, 2009) and Certain Seamless Carbon... export restraints, the GOC is providing inputs to downstream producers of seamless pipe. \\8\\ See 75 FR at... International Trade Administration Certain Seamless Carbon and Alloy Steel Standard, Line, and Pressure...

  19. 78 FR 25253 - Seamless Carbon and Alloy Steel Standard, Line, and Pressure From the People's Republic of China...

    Science.gov (United States)

    2013-04-30

    ...The Department of Commerce (``the Department'') is rescinding the administrative review of the countervailing duty order on certain seamless carbon and alloy steel standard, line, and pressure pipe (``seamless pipe'') from the People's Republic of China (``PRC'') for the period January 1, 2011, through December 31,...

  20. 75 FR 13255 - Certain Seamless Carbon and Alloy Steel Standard, Line, and Pressure Pipe from the People's...

    Science.gov (United States)

    2010-03-19

    ... Pressure Pipe From the People's Republic of China: Initiation of Antidumping Duty Investigation, 74 FR... International Trade Administration Certain Seamless Carbon and Alloy Steel Standard, Line, and Pressure Pipe..., line, and pressure pipe (``seamless pipe'') from the People's Republic of China (``PRC'') with...

  1. 75 FR 78216 - Certain Circular Welded Non-Alloy Steel Pipe From Mexico: Preliminary Results of Antidumping Duty...

    Science.gov (United States)

    2010-12-15

    ... questionnaire response at Exhibit S-5. While TUNA had a general knowledge that some of its pipe would be... Mexico, 75 FR 67685 (November 3, 2010). Therefore, we are continuing to refer to this entity as TUNA for... Welded Non-Alloy Steel Pipe from Korea, 57 FR 49453 (November 2, 1992) (Antidumping Duty Order)....

  2. 78 FR 63450 - Carbon and Certain Alloy Steel Wire Rod From Brazil, Indonesia, Mexico, Moldova, Trinidad and...

    Science.gov (United States)

    2013-10-24

    ... Act. See Initiation of Five-Year (``Sunset'') Reviews, 78 FR 33063 (June 3, 2013) (``Notice of..., Moldova, Trinidad and Tobago, and Ukraine: Final Results of the Expedited Second Sunset Reviews of the... on carbon and certain alloy steel wire rod (``wire rod'') from Brazil, Indonesia, Mexico,...

  3. 78 FR 60316 - Carbon and Certain Alloy Steel Wire Rod From Brazil, Indonesia, Mexico, Moldova, Trinidad and...

    Science.gov (United States)

    2013-10-01

    ... both that the domestic interested party group response to its notice of institution (78 FR 33103, June... Certain Alloy Steel Wire Rod From Brazil, Indonesia, Mexico, Moldova, Trinidad and Tobago, and Ukraine..., Indonesia, Mexico, Moldova, Trinidad and Tobago, and Ukraine would be likely to lead to continuation...

  4. 78 FR 76653 - Carbon and Certain Alloy Steel Wire Rod From Brazil, Indonesia, Mexico, Moldova, Trinidad and...

    Science.gov (United States)

    2013-12-18

    ... reviews were such that full reviews pursuant to section 751(c)(5) of the Act should proceed (78 FR 60316... Certain Alloy Steel Wire Rod From Brazil, Indonesia, Mexico, Moldova, Trinidad and Tobago, and Ukraine... from Brazil, Indonesia, Mexico, Moldova, Trinidad and Tobago, and Ukraine. AGENCY: United...

  5. 76 FR 76369 - Circular Welded Non-Alloy Steel Pipe From the Republic of Korea: Preliminary Results of the...

    Science.gov (United States)

    2011-12-07

    ... Less Than Fair Value: Certain Circular Welded Non-Alloy Steel Pipe from Korea, 57 FR 49453 (November 2...: Light- Walled Rectangular Pipe and Tube From Mexico, 73 FR 5515, 5522 (January 30, 2008) (``LWR Pipe... Rectangular Pipe and Tube from Mexico, 73 FR 35649 (June 24, 2008). In particular, we analyze...

  6. 75 FR 44763 - Certain Circular Welded Non-Alloy Steel Pipe From Mexico; Extension of Time Limit for Preliminary...

    Science.gov (United States)

    2010-07-29

    ... and Request for Revocation in Part, 74 FR 68229 (December 23, 2009). The current deadline for the... International Trade Administration Certain Circular Welded Non-Alloy Steel Pipe From Mexico; Extension of Time... Department) received a timely request from domestic interested parties Allied Tube and Conduit...

  7. A ferric-austenitic CrNiMoN steel alloy to be used as material to manufacture welded components

    International Nuclear Information System (INIS)

    A chromium-nickel-molybdenum-nitrogen steel alloy (ferritic-austenite) is used to manufacture welded articles which without thermal treatment are resistant to pitting corrosion, intergranular corrosion (Monypenny-Stauss test) or boiling in 65% nitric acid with subsequent cross-breaking test. (IHOE)

  8. Comparison of the corrosion behavior and surface morphology of NiTi alloy and stainless steels in sodium chloride solution

    Directory of Open Access Journals (Sweden)

    Kožuh S.

    2016-01-01

    Full Text Available The corrosion behavior of NiTi alloy and stainless steels (AISI 316L and X2CrNiMoN22-5-3 in 0.9% sodium chloride (0.154 moll-1 solution was investigated using open circuit potential measurements, potentiodynamic polarization and electrochemical impedance spectroscopy measurements. Microstructural analyses before and after electrochemical tests were performed with the scanning electron microscopy (SEM equipped with energy dispersive spectrometry (EDS. The lowest corrosion current density has NiTi alloy and the extent of the passive range increased in the order AISI 316L stainless steel < NiTi alloy < X2CrNiMoN22-5-3 duplex stainless steel. The oxide film formed on all samples has a double-layer structure consisting of a barrier-type inner layer and a porous outer layer. Oxide films formed on the surface of steels mainly contains iron oxides and chromium oxide, while the surface film of the NiTi alloy mainly contains TiO2 oxide.

  9. Computer simulation of the influence of the alloying elements on secondary hardness of the high-speed steels

    International Nuclear Information System (INIS)

    The paper presents the method of modelling of high-speed steels' (HSS) properties, being basing on chemical composition and heat treatment parameters, employing neural networks. An example of its application possibility the computer simulation was made of the influence of the particular alloying elements on hardness and obtained results are presented. (author)

  10. 76 FR 67407 - Carbon and Certain Alloy Steel Wire Rod From Mexico: Notice of Preliminary Results of Antidumping...

    Science.gov (United States)

    2011-11-01

    ... financial expense, by multiplying the G&A and financial expense ratio by the sum of the costs reported in... Alloy Steel Wire Rod from Mexico, (76 FR 45509 (July 29, 2011)). We preliminarily determine that, during..., Indonesia, Mexico, Moldova, Trinidad and Tobago, and Ukraine, 67 FR 65945 (October 29, 2002) (Wire...

  11. [The industrial environment in the electric-furnace steel smelting, converter and open-hearth furnace methods of manufacturing manganese-alloyed steels].

    Science.gov (United States)

    Karnaukh, N G; Petrov, G A; Gapon, V A; Poslednichenko, I P; Shmidt, S E

    1992-01-01

    Inspection of the environment in manganese-alloyed steel production showed inadequate hygienic conditions of the technological processes employed. Air was more polluted by manganese oxides during the oxygen-converter process though their highest concentrations, 38 times exceeding the MAS, appeared during the casting of steel. An electric furnace coated by dust-noise-proof material and gas cleaning is preferable from a hygienic point of view. The influence of unfavourable microclimate, intensive infrared irradiation and loud noise on workers necessitates automation and mechanization of the process in order to improve the working conditions.

  12. Corrosion of high Ni-Cr alloys and Type 304L stainless steel in HNO3-HF

    International Nuclear Information System (INIS)

    Nineteen alloys were evaluated as possible materials of construction for steam heating coils, the dissolver vessel, and the off-gas system of proposed facilities to process thorium and uranium fuels. Commercially available alloys were found that are satisfactory for all applications. With thorium fuel, which requires HNO3-HF for dissolution, the best alloy for service at 1300C when complexing agents for fluoride are used is Inconel 690; with no complexing agents at 1300C, Inconel 671 is best. At 950C, six other alloys tested would be adequate: Haynes 25, Ferralium, Inconel 625, Type 304L stainless steel, Incoloy 825, and Haynes 20 (in order of decreasing preference); based on composition, six untested alloys would also be adequate. The ions most effective in reducing fluoride corrosion were the complexing agents Zr4+ and Th4+; Al3+ was less effective. With uranium fuel, modestly priced Type 304L stainless steel is adequate. Corrosion will be most severe in HNO3-HF used occasionally for flushing and in solutions of HNO3 and corrosion products (ferric and dichromate ions). HF corrosion can be minimized by complexing the fluoride ion and by passivation of the steel with strong nitric acid. Corrosion caused by corrosion products can be minimized by operating at lower temperatures

  13. Master curve characterization of the fracture toughness behavior in SA508 Gr.4N low alloy steels

    Science.gov (United States)

    Lee, Ki-Hyoung; Kim, Min-Chul; Lee, Bong-Sang; Wee, Dang-Moon

    2010-08-01

    The fracture toughness properties of the tempered martensitic SA508 Gr.4N Ni-Mo-Cr low alloy steel for reactor pressure vessels were investigated by using the master curve concept. These results were compared to those of the bainitic SA508 Gr.3 Mn-Mo-Ni low alloy steel, which is a commercial RPV material. The fracture toughness tests were conducted by 3-point bending with pre-cracked charpy (PCVN) specimens according to the ASTM E1921-09c standard method. The temperature dependency of the fracture toughness was steeper than those predicted by the standard master curve, while the bainitic SA508 Gr.3 steel fitted well with the standard prediction. In order to properly evaluate the fracture toughness of the Gr.4N steels, the exponential coefficient of the master curve equation was changed and the modified curve was applied to the fracture toughness test results of model alloys that have various chemical compositions. It was found that the modified curve provided a better description for the overall fracture toughness behavior and adequate T0 determination for the tempered martensitic SA508 Gr.4N steels.

  14. Pack cementation Cr-Al coating of steels and Ge-doped silicide coating of Cr-Nb alloy

    Energy Technology Data Exchange (ETDEWEB)

    He, Y.R.; Zheng, M.H.; Rapp, R.A. [Ohio State Univ., Columbus, OH (United States)

    1995-08-01

    Carbon steels or low-alloy steels used in utility boilers, heat exchangers, petrochemical plants and coal gasification systems are subjected to high temperature corrosion attack such as oxidation, sulfidation and hot corrosion. The pack cementation coating process has proven to be an economical and effective method to enhance the corrosion resistance by modifying the surface composition of steels. With the aid of a computer program, STEPSOL, pack cementation conditions to produce a ferrite Cr-Al diffusion coating on carbon-containing steels by using elemental Cr and Al powders have been calculated and experimentally verified. The cyclic oxidation kinetics for the Cr-Al coated steels are presented. Chromium silicide can maintain high oxidation resistance up to 1100{degrees}C by forming a SiO{sub 2} protective scale. Previous studies at Ohio State University have shown that the cyclic oxidation resistance of MOSi{sub 2} and TiSi{sub 2} can be further improved by Ge addition introduced during coating growth. The halide-activated pack cementation process was modified to produce a Ge-doped silicide diffusion coating in a single processing step for the ORNL-developed Cr-Nb advanced intermetallic alloy. The oxidation behavior of the silicide-coated Cr-Nb alloy was excellent: weight gain of about 1 mg/cm{sup 2} upon oxidation at 1100{degrees}C in air for 100 hours.

  15. Resistance of the alloy steel used in the fuel gas desulphurization installations; Odpornosc na korozje wzerowa stali stopowych stosowanych w instalacjach odsiarczania spalin

    Energy Technology Data Exchange (ETDEWEB)

    Krakowiak, S.; Darowski, K. [Politechnika Gdanska, Gdansk (Poland)

    1996-12-31

    The results have been presented of DC polarization and exposure investigations of alloy steels used as construction materials in flue gas desulphurization installations. on the base of analysis of composition of investigated steels and results of polarization studies, conditions have been discussed in which the pitting resistance equivalent (PRE) should be used. Among tested steels the significantly highest resistance to pitting corrosion is exhibited by 654SMO steel, classified as the super austenitic grade. (author). 14 refs, 3 figs, 2 tabs.

  16. Effect of mechanical alloying atmosphere on the microstructure and Charpy impact properties of an ODS ferritic steel

    International Nuclear Information System (INIS)

    Two types of oxide dispersion strengthened (ODS) ferritic steels, with the composition of Fe-14Cr-2W-0.3Ti-0.3Y2O3 (in weight percent), have been produced by mechanically alloying elemental powders of Fe, Cr, W, and Ti with Y2O3 particles either in argon atmosphere or in hydrogen atmosphere, degassing at various temperatures, and compacting the mechanically alloyed powders by hot isostatic pressing. It was found in particular that mechanical alloying in hydrogen yields a significant reduction in oxygen content in the materials, a lower dislocation density, and a strong improvement in the fast fracture properties of the ODS ferritic steels, as measured by Charpy impact tests.

  17. Effect of aluminum on the corrosion resistance of low-alloy steel in 10 wt% sulfuric acid solution

    Energy Technology Data Exchange (ETDEWEB)

    Nam, N.D.; Kim, W.C.; Kim, J.G. [Department of Advanced Materials Science and Engineering, Sungkyunkwan University, 300 Chunchun-dong, Jangan-gu, Suwon 440-746 (Korea, Republic of)

    2012-11-15

    The aqueous corrosion behavior of low-alloy steel with aluminum contents was examined in a 10 wt% H{sub 2}SO{sub 4} (pH 0.13) solution using electrochemical techniques and surface analyses. The corrosion resistance of the new alloy steel was evaluated in terms of electrochemical parameters, such as passive current density, film, and charge transfer resistances. The results showed that a high Al content in the steel imparted better passivation behavior resulting in a lower corrosion rate. It related to the enrichment of iron carbonate and hydrocarbon by the dissolution of the carbide phase. (Copyright copyright 2012 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  18. Modeling of primary dendrite arm spacing variations in thin-slab casting of low carbon and low alloy steels

    Science.gov (United States)

    Mehrara, H.; Santillana, B.; Eskin, D. G.; Boom, R.; Katgerman, L.; Abbel, G.

    2012-01-01

    Solidification structure of a High Strength Low Alloy (HSLA) steel, in terms of dendrite arm spacing distribution across the shell thickness, is studied in a breakout shell from a thin-slab caster at Tata Steel in IJmuiden. Columnar dendrites were found to be the predominant morphology throughout the shell with size variations across the shell thickness. Primary Dendrite Arm Spacing (PDAS) increases by increasing the distance from meniscus or slab surface. Subsequently, a model is proposed to describe the variation of the PDAS with the shell thickness (the distance from slab surface) under solidifiction conditions experienced in the primary cooling zone of thin-slab casting. The proposed relationship related the PDAS to the shell thickness and, hence, can be used as a tool for predicting solidifcation structure and optimizing the thin-slab casting of low alloy steels.

  19. Calculation of the yield and tensile strength in the alloying non quenched-tempered steel by the electron structure parameters

    Institute of Scientific and Technical Information of China (English)

    LIU Zhilin; LIN Cheng; LIU Yan; GUO Yanchang

    2005-01-01

    Based on the phase transformations and strengthening mechanisms during roiling, the strength increments △σb under different strengthening mechanisms are calculated with the covalent electron number nA of the strongest bond in phase cells of alloys and the interface electron density difference △ρ matching the interface stress in alloys. The calculation method of the finishing rolling yield strength is proposed, and it is integrated with the proposed calculation formulas of strength of non quenched-tempered steel. Therefore,the general formulas to simultaneously calculate both the finishing rolling strength and the yield strength of the continuous casting-rolling and non quenched-tempered steel are given. Taken the pipeline steel X70 as an example, the predictions of properties and technological parameters are performed before production or online.

  20. Evaluation of Stress Corrosion Cracking Susceptibility Using Fracture Mechanics Techniques, Part 1. [environmental tests of aluminum alloys, stainless steels, and titanium alloys

    Science.gov (United States)

    Sprowls, D. O.; Shumaker, M. B.; Walsh, J. D.; Coursen, J. W.

    1973-01-01

    Stress corrosion cracking (SSC) tests were performed on 13 aluminum alloys, 13 precipitation hardening stainless steels, and two titanium 6Al-4V alloy forgings to compare fracture mechanics techniques with the conventional smooth specimen procedures. Commercially fabricated plate and rolled or forged bars 2 to 2.5-in. thick were tested. Exposures were conducted outdoors in a seacoast atmosphere and in an inland industrial atmosphere to relate the accelerated tests with service type environments. With the fracture mechanics technique tests were made chiefly on bolt loaded fatigue precracked compact tension specimens of the type used for plane-strain fracture toughness tests. Additional tests of the aluminum alloy were performed on ring loaded compact tension specimens and on bolt loaded double cantilever beams. For the smooth specimen procedure 0.125-in. dia. tensile specimens were loaded axially in constant deformation type frames. For both aluminum and steel alloys comparative SCC growth rates obtained from tests of precracked specimens provide an additional useful characterization of the SCC behavior of an alloy.

  1. Cessation of environmentally-assisted cracking in a low-alloy steel: Theoretical analysis

    Energy Technology Data Exchange (ETDEWEB)

    Wire, G.L.

    1997-02-01

    Environmentally Assisted Cracking (EAC) can cause increases in fatigue crack growth rates of 40 to 100 times the rate in air for low alloy steels. The increased rates can lead to very large predicted crack growth. EAC is activated by a critical level of dissolved sulfides at the crack tip. Sulfide inclusions (MnS) in the steel produce corrosive sulfides in solution following exposure by a growing crack. In stagnant, low oxygen water conditions considered here, diffusion is the dominant mass transport mechanism acting to change the sulfide concentration within the crack. The average crack tip velocity is below the level required to produce the critical crack tip sulfide ion concentration required for EAC. Crack extension analyses also consider the breakthrough of large, hypothetical embedded defects with the attendant large freshly exposed sulfide inventory. Combrade et al. noted that a large inventory of undissolved metallurgical sulfides on crack flanks could trigger EAC, but did not quantify the effects. Diffusion analysis is extended herein to cover breakthrough of embedded defects with large sulfide inventories. The mass transport via diffusion is limited by the sulfide solubility. As a result, deep cracks in high sulfur steels are predicted to retain undissolved sulfides for extended but finite periods of time t{sub diss} which increase with the crack length and the metallurgical sulfide content in the steel. The analysis shows that the duration of EAC is limited to t{sub diss} providing V{sub eac}, the crack tip velocity associated with EAC is less than V{sub In}, the crack tip velocity below which EAC will not occur in an initially sulfide free crack. This condition on V{sub eac} need only be met for a short time following crack cleanup to turn off EAC. The predicted crack extension due to limited duration of EAC is a small fraction of the initial embedded defect size and would not greatly change calculated crack depths.

  2. Effect of Temperature on the Toughness of Locally Manufactured Low Alloy Steel SUP9 Used for Manufacturing Leaf Springs

    Directory of Open Access Journals (Sweden)

    Muhammad Ishaque Abro

    2011-10-01

    Full Text Available The effect of heat treatment on locally manufactured low alloy steel grade SUP9 most frequently used in making leaf springs for automobiles was studied. While for determination of toughness and hardness Charpy impact testing machine and Rockwell hardness tester were used. The cryogenic test temperatures were achieved by soaking the samples in liquid nitrogen and temperature was measured using digital thermometer capable of reading the temperature from -40-200oC. Hardening, tempering and austempering treatments were conducted using muffle furnace and salt bath furnace. After heat treatment samples were quenched in oil. The results of present work confirmed that toughness and hardness are inversely related with each other and are highly dependent on the type of heat treatment employed. Highest toughness was measured after austempering at 450oC. Effect of test temperature revealed that toughness of the samples increased significantly with decreasing temperature. DBTT (Ductile to Brittle Transition Temperature of the austempered samples was observed at -10oC, whereas, that of tempered samples could not be determined. Based on the test results authors wish to recommend the 600oC tempering temperature in place of 450oC where normally tempering is practiced in Alwin industry Karachi during manufacturing of leaf spring.

  3. Characterisation of reactor steels in the brittle-ductile transition region using the small punch test

    International Nuclear Information System (INIS)

    Two ferritic reactor steels (A 533 B and A508) were investigated using the small punch test for different temperatures and irradiation states, with particular interest in the ductile-tensile transition region. The material characteristics obtained with the aid of neuronal nets were compared with the results of conventional tests. (orig.)

  4. Copper and phosphorus effect on residual embrittlement of irradiated model alloys and RPV steels after annealing

    International Nuclear Information System (INIS)

    The dependence of the recovery of the transition temperature shift after annealing (475 deg. C, 100 h) on copper and phosphorus contents has been studied on irradiated reactor pressure vessel (RPV) materials. A set of model alloys with low nickel content, lower than 0.2 mass%, was used for the study. Copper and phosphorus contents were varied in a wide range: 0.005-0.99 and 0.002-0.039 mass%, respectively. Recovery efficiency has been estimated by the value of residual embrittlement after annealing, measured in terms of a shift in transition temperature (ΔTKres). A comparison of the results obtained on model alloys with data for VVER-440 RPV materials has also been carried out. Comparative analysis has confirmed the conclusion that ΔTKres is independent of phosphorus content while the effect of copper on ΔTKres is not significant for typical VVER-440 RPV materials with a typical range of Cu contents between 0.10 and 0.24 mass%. However, for model alloys with a wider range of copper content, copper mainly controls the value of ΔTKres

  5. Corrosion and cracking behaviour of steel and alloys in liquid H{sub 2}S

    Energy Technology Data Exchange (ETDEWEB)

    Longaygue, X. [Institut Francais du Petrole, 1 et 4 avenue de Bois Preau 92852 Rueil-Malmaison (France); Duval, S. [Institut Francais du Petrole, BP no 3, 69390 Vernaison (France)

    2004-07-01

    When oil and gas wells with very high partial pressure of H{sub 2}S, e.g. H{sub 2}S-rich gas, are under production, the presence of liquid H{sub 2}S is highly probable in the process operations. Until now, corrosion engineers and materials designers have paid little attention to this situation because it is rarely encountered in practice. However, such a scenario recently met an increasing interest in the context of the Sprex development, a new H{sub 2}S pre-extraction process used for the treatment of very sour natural gases, which produces the separated acid gases as a liquid phase for re-injection to a disposal reservoir. It is generally accepted that pure liquid H{sub 2}S is not corrosive by itself towards carbon or low alloy steels, but the presence of water in production and reservoir fluids could make this medium much more corrosive, although this latter assumption is poorly documented. The aim of this paper is to present the corrosion and cracking behaviour of a pipeline carbon steel and of corrosion resistant alloys (CRA) (with Cr > 16%) after exposure to the following media: i) liquid H{sub 2}S saturated with water, and ii) liquid H{sub 2}O saturated with H{sub 2}S. For both solutions, the addition of solid sulphur on some specimens was considered to take into account the possible introduction of oxygen into the system, followed by a reaction with H{sub 2}S. The tests were performed at 80 deg. C in a laboratory autoclave where both phases coexisted, using U-bend specimens as well as rectangular corrosion coupons. The main conclusion of this study is that liquid H{sub 2}S is rather less critical for corrosion and cracking of construction alloys than 'classical' sour solutions, like H{sub 2}S-saturated water. As a consequence, the materials selection will be governed by the same criteria, with the following alternatives: i) use of carbon steels in conjunction with corrosion inhibitors, e.g. higher operation expense; or ii) selection of a CRA

  6. ALLOYING-DRIVEN PHASE STABILITY IN GROUP-VB TRANSITION METALS UNDER COMPRESSION

    Energy Technology Data Exchange (ETDEWEB)

    Landa, A; Soderlind, P

    2011-04-11

    The change in phase stability of Group-VB (V, Nb, and Ta) transition metals due to pressure and alloying is explored by means of first-principles electronic-structure calculations. It is shown that under compression stabilization or destabilization of the ground-state body-centered cubic (bcc) phase of the metal is mainly dictated by the band-structure energy that correlates well with the position of the Kohn anomaly in the transverse acoustic phonon mode. The predicted position of the Kohn anomaly in V, Nb, and Ta is found to be in a good agreement with data from the inelastic x-ray or neutron scattering measurements. In the case of alloying the change in phase stability is defined by the interplay between the band-structure and Madelung energies. We show that band-structure effects determine phase stability when a particular Group-VB metal is alloyed with its nearest neighbors within the same d-transition series: the neighbor with less and more d electrons destabilize and stabilize the bcc phase, respectively. When V is alloyed with neighbors of a higher (4d- or 5d-) transition series, both electrostatic Madelung and band-structure energies stabilize the body-centered-cubic phase. The opposite effect (destabilization) happens when Nb or Ta is alloyed with neighbors of the 3d-transition series.

  7. Master curve analysis of the SA508 Gr. 4N Ni-Mo-Cr low alloy steels for reactor pressure vessels

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Ki Hyoung; Wee, Dang Moon [KAIST, Daejeon (Korea, Republic of); Kim, Min Chul; Lee, Bong Sang [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2009-10-15

    Low alloy steels used as Reactor Pressure Vessels (RPVs) materials directly relate to the safety margin and the life span of reactors. Currently, SA508 Gr.3 low alloy steel is generally used for RPV material. But, for larger capacity and long-term durability of RPV, materials that have better properties including strength and toughness are needed. Therefore, tempered martensitic SA508 Gr.4N low alloy steel is considered as a candidate material due to excellent mechanical properties. The fracture toughness loss caused by irradiation embrittlement during reactor operation is one of the important issues for ferritic RPV steels, because the decrease of fracture toughness is directly related to the integrity of RPVs. One reliable and efficient concept to evaluate the fracture toughness of ferritic steels is master curve method. In ASTM E1921, it is clearly mentioned the universal shape of the median toughness-temperature curve for ferritic steels including tempered martensitic steels. However, currently, concerns have arisen regarding the appropriateness of the universal shape in ASTM for the tempered martensitic steels such as Eurofer97. Therefore, it may be necessary to assess the master curve applicability for the tempered martensitic SA508 Gr.4N low alloy steel. In this study, the fracture toughness behavior with temperature of the tempered martensitic SA508 Gr.4N low alloy steels was evaluated using the ASTM E1921 master curve method. And the results were compared with those of the bainitic SA508 Gr.3 low alloy steel. Furthermore, the way to define the fracture toughness behavior of Gr.4N steels well is discussed.

  8. Microstructures and mechanical properties of magnesium alloy and stainless steel weld-joint made by friction stir lap welding

    International Nuclear Information System (INIS)

    Highlights: → Friction stir lap welding technology with cutting pin was successfully employed to form lap joint of magnesium and steel. → The cutting pin made the lower steel participate in deformation and the interface was no longer flat. → A saw-toothed structure formed due to a mechanical mixing of the magnesium and steel was found at the interface. → A high-strength joint was produced which fractured in the magnesium side. -- Abstract: Friction stir lap welding was conducted on soft/hard metals. A welding tool was designed with a cutting pin of rotary burr made of tungsten carbide, which makes the stirring pin possible to penetrate and cut the surface layer of the hard metal. Magnesium alloy AZ31 and stainless steel SUS302 were chosen as soft/hard base metals. The structures of the joining interface were analyzed by scanning electron microscopy (SEM). The joining strength was evaluated by tensile shear test. The results showed that flower-like interfacial morphologies were presented with steel flashes and scraps, which formed bonding mechanisms of nail effect by long steel flashes, zipper effect by saw-tooth structure and metallurgical bonding. The shear strength of the lap joint falls around the shear strength of butt joint of friction stir welded magnesium alloy.

  9. Effects of austenite grain size and cooling rate on Widmanstaetten ferrite formation in low-alloy steels

    Energy Technology Data Exchange (ETDEWEB)

    Bodnar, R.L.; Hansen, S.S. (Bethlehem Steel Corp., PA (United States). Hot Rolled Products Div.)

    1994-04-01

    Deformation dilatometry is used to simulate the hot rolling of 0.20 pct C-1.10 pct Mn steels over a product thickness range of 6 to 170 mm. In addition to a base steel, steels with additions of 0.02 pct Ti, 0.06 pct V, or 0.02 pct Nb are included in the study. The transformation behavior of each steel is explored for three different austenite grain sizes, nominally 30, 55, and 100 [mu]m. In general, the volume fraction of Widmanstaetten ferrite increases in all four steels with increasing austenite grain size and cooling rate, with austenite grain size having the more significant effect. The Nb steel has the lowest transformation temperature range and the greatest propensity for Widmanstaetten ferrite formation, while the amount of Widmanstaetten ferrite is minimized in the Ti steel (as a result of intragranular nucleation of polygonal ferrite on coarse TiN particles). The data emphasize the importance of a refined austenite grain size in minimizing the formation of a coarse Widmanstaetten structure. With a sufficiently fine prior austenite grain size (e.g., [le]30 [mu]m), significant amounts of Widmanstaetten structure can be avoided, even in a Nb-alloyed steel.

  10. Status of ATR-A1 irradiation experiment on vanadium alloys and low-activation steels

    Energy Technology Data Exchange (ETDEWEB)

    Tsai, H.; Strain, R.V.; Gomes, I.; Smith, D.L. [Argonne National Lab., IL (United States); Matsui, H. [Tohoku Univ. (Japan)

    1996-10-01

    The ATR-A1 irradiation experiment was a collaborative U.S./Japan effort to study at low temperature the effects of neutron damage on vanadium alloys. The experiment also contained a limited quantity of low-activation ferritic steel specimens from Japan as part of the collaboration agreement. The irradiation started in the Advanced Test Reactor (ATR) on November 30, 1995, and ended as planned on May 5, 1996. Total exposure was 132.9 effective full power days (EFPDs) and estimated neutron damage in the vanadium was 4.7 dpa. The vehicle has been discharged from the ATR core and is scheduled to be disassembled in the next reporting period.

  11. Influence of Post Weld Heat Treatment on the HAZ of Low Alloy Steel Weldments

    Directory of Open Access Journals (Sweden)

    S. Rasool Mohideen

    2010-06-01

    Full Text Available The heterogeneous nature of weldments demands an additional processing to retain and/or improve the joint properties. Heat Affected Zone, the zone Adjacent to the weld metal zone is critically affected by the sudden dissipation of heat from weld metal during welding. Toughness of this zone becomes weak as the grains get coarsened and the interface between the two regions is more prone to fracture. Post weld heat treatment is thus generally carried out on the weldments to relive the thermal residual stresses and to enhance the properties of welded joints. This paper discusses about the influence of post weld heat treatment on the fracture toughness of low alloy steel weldments. Fracture toughness of heat treated weldments was determined using standard CTOD test and the results were correlated.

  12. Thermal property characterization of a titanium modified austenitic stainless steel (alloy D9)

    Energy Technology Data Exchange (ETDEWEB)

    Banerjee, Aritra [Physical Metallurgy Section, Materials Characterisation Group, Indira Gandhi Centre for Atomic Research, Kalpakkam 603 102 (India); Raju, S. [Physical Metallurgy Section, Materials Characterisation Group, Indira Gandhi Centre for Atomic Research, Kalpakkam 603 102 (India)]. E-mail: sraju@igcar.ernet.in; Divakar, R. [Physical Metallurgy Section, Materials Characterisation Group, Indira Gandhi Centre for Atomic Research, Kalpakkam 603 102 (India); Mohandas, E. [Physical Metallurgy Section, Materials Characterisation Group, Indira Gandhi Centre for Atomic Research, Kalpakkam 603 102 (India); Panneerselvam, G. [Fuel Chemistry Division, Indira Gandhi Centre for Atomic Research, Kalpakkam 603 102 (India); Antony, M.P. [Fuel Chemistry Division, Indira Gandhi Centre for Atomic Research, Kalpakkam 603 102 (India)

    2005-12-01

    The temperature dependence of lattice parameter and enthalpy increment of alloy D9, a titanium modified nuclear grade austenitic stainless steel were studied using high temperature X-ray diffraction and inverse drop calorimetry techniques, respectively. A smooth variation of the lattice parameter of the austenite with temperature was found. The instantaneous and mean linear thermal expansion coefficients at 1350 K were estimated to be 2.12 x 10{sup -5} K{sup -1} and 1.72 x 10{sup -5} K{sup -1}, respectively. The measured enthalpy data were made use of in estimating heat capacity, entropy and Gibbs energy values. The estimated isobaric heat capacity C {sub p} at 298 K was found to be 406 J kg{sup -1} K{sup -1}. An integrated theoretical analysis of the thermal expansion and enthalpy data was performed to obtain approximate values of bulk modulus as a function of temperature.

  13. Mechanism of Residual Stress Reduction in Low Alloy Steel by a Low Frequency Alternating Magnetic Treatment

    Institute of Scientific and Technical Information of China (English)

    Yanli Song; Lin Hua

    2012-01-01

    Residual stress reduction in low alloy steel by a low frequency alternating magnetic treatment and its mechanism were investigated. Experimental results revealed that average stress reductions of 20%-24% were obtained in the welded samples. Moreover, compared with the zones with lower initial stress levels, more remarkable stress reductions were obtained in the stress concentration zones. The microstructures and magnetic domains were observed by scanning electron microscopy (SEM) and atomic force microscopy (AFM). Based on the analysis of the microstructure and magnetic domain changes, the mechanism of stress reduction by the magnetic treatment has been concluded: (1) the magneto-plastic deformations mainly due to the more uniform redistribution of dislocations are the fundamental cause of stress relaxation; and (2) surface topography is also proved to affect the magnetic treatment results to some degree by influencing magnetic domains.

  14. Laser welding of TiNi shape memory alloy and stainless steel using Co filler metal

    Science.gov (United States)

    Li, Hongmei; Sun, Daqian; Cai, Xiaolong; Dong, Peng; Gu, Xiaoyan

    2013-02-01

    Dissimilar metal joints of TiNi shape memory alloy wire and stainless steel wire were welded by laser welding method with and without Co filler metal. Comparative microstructure and properties of laser welded joints with and without Co filler metal have been detailed investigated. The effects of Co filler metal thickness on joint microstructure and properties were also discussed. The results indicated that the addition of Co filler metal had great effect to improve joint microstructure and properties. When 20 μm thick Co filler metal was used, the joint tensile strength and elongation reached the maximum values (347 MPa and 4.2%), and the corresponding joint fracture mode changed from pure brittle feature to mixture of cleavage and dimples due to decreasing brittle intermetallic compounds such as TiFe2, TiCr2, etc. But excessive Co addition resulted in decreasing the joint properties because of forming more Co-Ti intermetallic compounds.

  15. Development of brazing foils to join monocrystalline tungsten alloys with ODS-EUROFER steel

    Energy Technology Data Exchange (ETDEWEB)

    Kalin, B.A. [Moscow Engineering Physics Institute (State University), 31 Kashirskoye Sh., Moscow 115409 (Russian Federation)]. E-mail: BAKalin@mephi.ru; Fedotov, V.T. [Moscow Engineering Physics Institute (State University), 31 Kashirskoye Sh., Moscow 115409 (Russian Federation); Sevrjukov, O.N. [Moscow Engineering Physics Institute (State University), 31 Kashirskoye Sh., Moscow 115409 (Russian Federation); Kalashnikov, A.N. [Moscow Engineering Physics Institute (State University), 31 Kashirskoye Sh., Moscow 115409 (Russian Federation); Suchkov, A.N. [Moscow Engineering Physics Institute (State University), 31 Kashirskoye Sh., Moscow 115409 (Russian Federation); Moeslang, A. [Forschungszentrum Karlsruhe, Institut fuer Materialforschung I, 76021 Karlsruhe (Germany); Rohde, M. [Forschungszentrum Karlsruhe, Institut fuer Materialforschung I, 76021 Karlsruhe (Germany)

    2007-08-01

    Results on rapidly solidified filler metals for brazing W with W and monocrystalline W with EUROFER steel (FS) are presented. Rapidly quenched powder-type filler metals based on Ti{sub bal}-V-Cr-Be were developed to braze polycrystalline W with monocrystalline W. In addition, Fe{sub bal}-Ta-Ge-Si-B-Pd alloys were developed to braze monocrystalline W with FS for helium gas cooled divertors and plasma-facing components. The W to FS brazed joints were fabricated under vacuum at 1150 {sup o}C, using a Ta spacer of 0.1 mm in thickness to account for the different thermal expansions. The monocrystalline tungsten as well as the related brazed joints withstood 30 cycles between 750 {sup o}C/20 min and air cooling/3-5 min.

  16. Development and industrial mastering hot rolling procedure for low-ductile steels and alloys

    International Nuclear Information System (INIS)

    The technique for the development of the sheet hot rolling procedure for low-ductile steels and alloys (0Kh17N14M2, 12Kh21N5T, 20Kh25N20C2,40Kh13, 36NKhTYu etc.) is proposed, using plastometer which permits to obtain the data on the deformation resistance in the wide range of temperatures (800-1300 deg C), of deformation degrees (0.1-0.3) and deformation rates (0.001-300 c-1). With the help of the plastometric data processed on the computer the calculation of the rolling regimes for the sheet with improved surface quality is carried out at the more uniform loading on the mill stands

  17. Nickel coating on high strength low alloy steel by pulse current deposition

    Science.gov (United States)

    Nigam, S.; Patel, S. K.; Mahapatra, S. S.; Sharma, N.; Ghosh, K. S.

    2015-02-01

    Nickel is a silvery-white metal mostly used to enhance the value, utility, and lifespan of industrial equipment and components by protecting them from corrosion. Nickel is commonly used in the chemical and food processing industries to prevent iron from contamination. Since the properties of nickel can be controlled and varied over broad ranges, nickel plating finds numerous applications in industries. In the present investigation, pulse current electro-deposition technique has been used to deposit nickel on a high strength low alloy (HSLA) steel substrate.Coating of nickel is confirmed by X-ray diffraction (XRD) and EDAX analysis. Optical microscopy and SEM is used to assess the coating characteristics. Electrochemical polarization study has been carried out to study the corrosion behaviour of nickel coating and the polarisation curves have revealed that current density used during pulse electro-deposition plays a vital role on characteristics of nickel coating.

  18. Predicting the creep life and failure mode of low-alloy steel weldments

    Energy Technology Data Exchange (ETDEWEB)

    Brear, J.M.; Middleton, C.J.; Aplin, P.F. [ERA Technology Ltd., Leatherhead (United Kingdom)

    1998-12-31

    This presentation reviews and consolidates experience gained through a number of research projects and practical plant assessments in predicting both the life and the likely failure mode and location in low alloy steel weldments. The approach adopted begins with the recognition that the relative strength difference between the microstructural regions is a key factor controlling both life and failure location. Practical methods based on hardness measurement and adaptable to differing weld geometries are presented and evidence for correlations between hardness ratio, damage accumulation and strain development is discussed. Predictor diagrams relating weld life and failure location to the service conditions and the hardness of the individual microstructural constituents are suggested and comments are given on the implications for identifying the circumstances in which Type IV cracking is to be expected. (orig.) 6 refs.

  19. Effects of heat treatment on properties of multi-element low alloy wear-resistant steel

    Institute of Scientific and Technical Information of China (English)

    SONG Xu-ding; FU Han-guang

    2007-01-01

    The paper has studied the mechanical properties and heat treatment effects on multi-element low alloy wear-resistant steel (MLAWS) used as a material for the liner of rolling mill torii. The results show that when quenched at 900-920 ℃ and tempered at 350-370 ℃, the MLAWS has achieved hardness above 60 HRC, tensile strength When the quenching temperature is lower than 900℃, the hardness of the MLAWS increases with the temperature.When the quenching temperature is higher than 900℃, the hardness decreases with the increase of temperature. At a quenching temperature below 920℃, the effect of quenching temperature on the impact toughness is not obvious.In quenching at above 920℃, impact toughness decreases as the temperature increases. When the tempering temperature is exceeding 450℃, the hardness begins to decrease significantly. Tempering at 350℃ has produced the best wear resistance on the MLAWS.

  20. Phase transformation studies af a low alloy steel in the (α + γ phase region

    Directory of Open Access Journals (Sweden)

    Kenneth Kanayoa Alaneme

    2010-03-01

    Full Text Available This research work describes a thermo mechanical investigation of a low alloy steel treated in the (α + γ phase region. The aim is to develop a high tensile, ductile microstructure that could have a wide range of engineering applications. Recent advances in the area of precipitation, recrystallization mechanisms, and α / γ transformations provide strong background to this study. In a preliminary heat treatment, various microstructures (normalized and 450 °C tempered martensite structure were produced and deformed to varying degrees. Subsequently, these microstructures were subjected to various intercritical temperatures (740 and 760 °C for various times and a very high cooling rate. Light (optical microscopic investigations were carried out to study the ensuing microstructures. Mechanical testing results (tensile and hardness values were used to characterize the structures obtained. On analysis of the result, it was observed that well defined micro-duplex structures of ferritic and martensitic nature, possessing good combinations of strength and ductility were obtained.

  1. Statistical analysis of fatigue strain-life data for carbon and low-alloy steels

    International Nuclear Information System (INIS)

    The existing fatigue strain vs life (S-N) data, foreign and domestic, for carbon and low-alloy steels used in the construction of nuclear power plant components have been compiled and categorized according to material, loading, and environmental conditions. A statistical model has been developed for estimating the effects of the various test conditions on fatigue life. The results of a rigorous statistical analysis have been used to estimate the probability of initiating a fatigue crack. Data in the literature were reviewed to evaluate the effects of size, geometry, and surface finish of a component on its fatigue life. The fatigue S-N curves for components have been determined by applying design margins for size, geometry, and surface finish to crack initiation curves estimated from the model

  2. Effects of AlMnCa and AlMnFe Alloys on Deoxidization of Low Carbon and Low Silicon Aluminum Killed Steels

    Institute of Scientific and Technical Information of China (English)

    ZHAN Dong-ping; ZHANG Hui-shu; JIANG Zhou-hua

    2008-01-01

    To confirm the effects of AlMnCa and AIMnFe alloys on the deoxidization and modification of Al2O3 inclu-sions, experiments of 4-heat low carbon and low silicon aluminum killed steels deoxidized by AlMnCa and AlMnFe alloys were done in a MoSi2 furnace at 1 873 K. It is found that the 1# A1MnCa alloy has the best ability of deoxidi-zation and modification of Al2 O3 inclusions than 2# A1MnCa and A1MnFe alloys. Steel A deoxidized by 1# AlMnCa alloy has the lowest total oxygen content in the terminal steel, which is 37 × 10-6. Most of the inclusions in the steel deoxidized by 1# AIMnCa alloy are spherical CaO-containing compound inclusions, and 89. 1% of them are smaller than 10 μm. The diameter of the inclusion bigger than 50 μm is not found in the final steels deoxidized by AlMnCa alloys. Whereas, for the steels deoxidized by AlMnFe alloys, most inclusions in the terminal steel are Al2O3 or Al2O3-MnO inclusions, and a few of them are spherical, and only 76. 8% of them are smaller than 10 μm. Some in-clusions bigger than 50 μm are found in the steel D deoxidized by AlMnFe alloy.

  3. Creep of FINEMET alloy at amorphous to nanocrystalline transition

    NARCIS (Netherlands)

    Csach, K.; Miškuf, J.; Juríková, A.; Ocelík, V.

    2009-01-01

    The application of FINEMET-type materials with specific magnetic properties prepared by the crystallization of amorphous alloys is often limited by their brittleness. The structure of these materials consists of nanosized Fe-based grains surrounded with amorphous phase. Then the final macroscopic me

  4. The tribological difference between biomedical steels and CoCrMo-alloys.

    Science.gov (United States)

    Fischer, Alfons; Weiss, Sabine; Wimmer, Markus A

    2012-05-01

    In orthopedic surgery, different self-mating metal couples are used for sliding wear applications. Despite the fact that in mechanical engineering, self-mating austenitic alloys often lead to adhesion and seizure in biomedical engineering, the different grades of Co-base alloys show good clinical results, e.g., as hip joints. The reason stems from the fact that they generate a so-called tribomaterial during articulation, which consists of a mixture of nanometer small metallic grains and organic substances from the interfacial medium, which act as a boundary lubricant. Even though stainless steel also generate such a tribomaterial, they were ruled out from the beginning already in the 1950s as "inappropriate". On the basis of materials with a clinical track record, this contribution shows that the cyclic creep characteristics within the shear zone underneath the tribomaterial are another important criterion for a sufficient wear behavior. By means of sliding wear and torsional fatigue tests followed by electron microscopy, it is shown that austenitic materials generate wear particles of either nano- or of microsize. The latter are produced by crack initiation and propagation within the shear fatigue zone which is related to the formation of subsurface dislocation cells and, therefore, by the fact that an Ni-containing CrNiMo solid solution allows for wavy-slip. In contrast to this, an Ni-free CrMnMo solid solution with further additions of C and N only shows planar slip. This leads to the formation of nanosize wear particles and distinctly improves the wear behavior. Still, the latter does not fully achieve that of CoCrMo, which also shows a solely planar-slip behavior. This explains why for metallurgical reasons the Ni-containing 316L-type of steels had to fail in such boundary lubricated sliding wear tribosystems. PMID:22498283

  5. Kinetics of glass transition and crystallization in multicomponent bulk amorphous alloys

    Institute of Scientific and Technical Information of China (English)

    2000-01-01

    Differential scanning calorimeter (DSC) is used to investigate apparent activation energy of glass transition and crystallization of Zr-based bulk amorphous alloys by Kissinger equation under non-isothermal condition. It is shown that the glass transition behavior as well as crystallization reaction depends on the heating rate and has a characteristic of kinetic effects. After being isothermally annealed near glass transition temperature, the apparent activation energy of glass transition increases and the apparent activation energy of crystallization reaction decreases. However, the kinetic effects are independent of the pre-annealing.

  6. Study on Interface Structure and Bond Properties between Cemented Carbide and Tool Steel Blazing with amorphous alloy

    Institute of Scientific and Technical Information of China (English)

    Bao Ming-dong; Xu Jin-fu; Xu Xue-bo; Zou Gui-sheng; Huang Geng-hua

    2004-01-01

    Cemented Carbide YG11C and Tool Steel Crl2MoV was blazed with Ni-base amorphous alloys, QG-1011,MBF-20 and MBF-75, using dynamics thermodynamics analogue testing machine Gleeble 1500D. The effects of brazing temperature, holding time and holding pressure on micro-structure and bond strength were investigated. Results showed that YG11C and Cr12MoV were all wetted well by these three Ni-base alloys, and the bond strength was as high as 220MPa,320MPa, 320MPa respectively. When the blazing temperature was at the point over the melting point 60-70℃ of Ni-base alloy, the holding time was about 2-10min, the suitable pressure was benefit for improving the brazing quality.Microanalysis showed Co in cemented carbide diffused into liquid brazing alloy and formed the Fe-Co solid .solution.

  7. Influence of Rare Earths on Improve Impact Property of Structural Alloy Steel with Extra Low Sulfur and Oxygen

    Institute of Scientific and Technical Information of China (English)

    Guo Feng; Lin Qin

    2007-01-01

    The influence of rare earth lanthanum and cerium on impact property of structural alloy steel with extra low sulfur and oxygen was studied by impact test and microanalysis. The results showed that rare earths increased impact power of the steel when their contents were about 0.005%. Proper addition of rare earths could purify grain boundaries and decrease amount of inclusions, and reduced the possibility of crack growth along grain boundaries and through inclusions. Therefore, such steel could absorb more crack growth energy while it was impacted. However, if the content of rare earths is excessive, the grain boundary would be weakened and brittle-hard phosphates and Fe-RE intermetallic would be formed, which worsened impact toughness of steel.

  8. On crystallochemical mechanism of small alloying addition effect on dissolution process of corrosion-resistant steels in active state

    International Nuclear Information System (INIS)

    Regularities of component dissolution and the changes of the surface layer composition of the Fe-Cr and Fe-Cr-Mo steels are studied. The investigations have been carried out taking as an example high-purity ferrite steels of the FeCr18 and FeCr26 type with Mo content from O to 1.7 and from 0 to 1.2 at. % in 1n H2SO4 respectively at room temperature. The notions of dissolution character of energetically heterogeneous alloy surface are developed. A conclusion is made on the mechanism of inhibitting effect of molybdenum on the anode process of steel dissolution in the active state and on the mechanism of its effect on steel passivation capacity

  9. Role of pulsed current on metallurgical and mechanical properties of dissimilar metal gas tungsten arc welding of maraging steel to low alloy steel

    International Nuclear Information System (INIS)

    Highlights: • Effect of current pulsing on weldability of maraging steel and low alloy steel. • Pensive discussions on the role of ErNiCrMo-3 filler on weld mechanical properties. • Improved strength and toughness on using pulsed gas tungsten arc welding. - Abstract: This research work encompasses the investigations carried out on the mechanical and metallurgical properties of maraging steel and AISI 4340 aeronautical steel weldments. The materials were joined by continuous current gas tungsten arc welding (CCGTA) and pulse current (PCGTA) gas tungsten arc welding processes using ErNiCrMo-3 filler wire. Cross sectional macrostructures confirmed proper deposition of the fillers and lack of discontinuities. Optical microscopy studies revealed that at the maraging steel–weld interface, martensite in distorted and block forms prevailed in CCGTA and PCGTA weldments whereas tempered martensite was predominant at the low alloy–weld interfaces of both the welds. Scanning electron microscopy (SEM) with energy dispersive analysis of X-rays (EDAX) analysis apparently showed less elemental migration in PCGTA weldments as compared to the other. Results of X-ray diffraction analysis recorded possible phase formations in various zones of the weldments. Microhardness profiles in either weld zones followed a constant trend whereas it showed a downtrend in the heat affected zones (HAZ) of the maraging steel and very high hardness profiles were observed in the low alloy steel side. Tensile studies on various factors and impact testing showed that PCGTA weldments outperformed the continuous ones in terms of strength, ductility and toughness. Fractograph analysis depicted the nature of failures of tensile and impact tested specimens. Comparison analyses involving influence and nature of pulsed current welds over continuous ones were done to determine the possibility of implementing these joining processes in aerospace applications. Weldments fabricated using PCGTA technique

  10. First-principles study on structural stability of 3d transition metal alloying magnesium hydride

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    A first-principles plane-wave pseudopotential method based on the density functional theory was used to investigate the energy and electronic structure of magnesium hydride (MgH2) alloyed by 3d transition metal elements. Through calculations of the negative heat formation of magnesium hydride alloyed by X (X denotes 3d transition metal) element, it is found that when a little X (not including Sc) dissolves into magnesium hydride, the structural stability of alloying systems decreases, which indicates that the dehydrogenation properties of MgH2 can be improved. After comparing the densities of states(DOS) and the charge distribution of MgH2 with or without X alloying, it is found that the improvement for the dehydrogenation properties of MgH2 alloyed by X attributes to the fact that the weakened bonding between magnesium and hydrogen is caused by the stronger interactions between X (not including Cu) and hydrogen. The calculation results of the improvement for the dehydrogenation properties of MgH2-X (X=Ti, V, Mn, Fe, Co,Ni, Cu) systems are in agreement with the experimental results. Hence, the dehydrogenation properties of MgH2 are expected to be improved by addition of Cr, Zn alloying elements.

  11. Evolution of microstructures and mechanical properties during dissimilar electron beam welding of titanium alloy to stainless steel via copper interlayer

    Energy Technology Data Exchange (ETDEWEB)

    Tomashchuk, I., E-mail: iryna.tomashchuk@u-bourgogne.fr [Laboratoire Interdisciplinaire Carnot de Bourgogne, UMR 6303 CNRS-Université de Bourgogne, 12 rue de la Fonderie, F-71200 Le Creusot (France); Sallamand, P. [Laboratoire Interdisciplinaire Carnot de Bourgogne, UMR 6303 CNRS-Université de Bourgogne, 12 rue de la Fonderie, F-71200 Le Creusot (France); Belyavina, N. [Department of Physics, Taras Shevchenko University, 2, Glushkov Avenue, 03022 Kiev (Ukraine); Pilloz, M. [Laboratoire Interdisciplinaire Carnot de Bourgogne, UMR 6303 CNRS-Université de Bourgogne, 12 rue de la Fonderie, F-71200 Le Creusot (France)

    2013-11-15

    The influence of operational parameters on the local phase composition and mechanical stability of the electron beam welds between titanium alloy and AISI 316L austenitic stainless steel with a copper foil as an intermediate layer has been studied. It was shown that two types of weld morphologies could be obtained depending on beam offset from the center line. Beam shift toward the titanium alloy side results in formation of a large amount of the brittle TiFe{sub 2} phase, which is located at the steel/melted zone interface and leads to reducing the mechanical resistance of the weld. Beam shift toward the steel side inhibits the melting of titanium alloy and, so, the formation of brittle intermetallics at the titanium alloy/melted zone interface. Mechanical stability of the obtained junctions was shown to depend on the thickness of this intermetallic layer. The fracture zone of the weld was found to be a mixture of TiCu (3–42 wt%), TiCu{sub 1−x}Fe{sub x} (x=0.72–0.84) (22–68 wt%) and TiCu{sub 1−x}Fe{sub x} (x=0.09–0.034) (0–22 wt%). In order to achieve the maximal ultimate tensile strength (350 MPa), the diffusion path length of Ti in the melted zone should be equal to 40–80 µm.

  12. Environmentally-Assisted Cracking of Low-Alloy Reactor Pressure Vessel Steels under Boiling Water Reactor Conditions

    Energy Technology Data Exchange (ETDEWEB)

    Seifert, H.P.; Ritter, S

    2002-02-01

    The present report summarizes the experimental work performed by PSI on the environmentally-assisted cracking (EAC) of low-alloy steels (LAS) in the frame of the RIKORR-project during the period from January 2000 to August 2001. Within this project, the EAC crack growth behaviour of different low-alloy reactor pressure vessel (RPV) steels, weld filler and weld heat-affected zone materials is investigated under simulated transient and steady-state BWR/NWC power operation conditions. The EAC crack growth behaviour of different low-alloy RPV steels was characterized by slow rising load (SRL) / low-frequency corrosion fatigue (LFCF) and constant load tests with pre-cracked fracture mechanics specimens in oxygenated high-temperature water at temperatures of either 288, 250, 200 or 150 C. These tests revealed the following important interim results: Under low-flow and highly oxidizing (ECP >= 100 mV SHE) conditions, the ASME XI 'wet' reference fatigue crack growth curve could be significantly exceeded by cyclic fatigue loading at low frequencies (<0.001 Hz), at high and low load-ratios R, and by ripple loading near to DKth fatigue thresholds. The BWR VIP 60 SCC disposition lines may be significantly or slightly exceeded (even in steels with a low sulphur content) in the case of small load fluctuations at high load ratios (ripple loading) or at intermediate temperatures (200 -250 C) in RPV materials, which show a distinct susceptibility to dynamic strain ageing (DSA). (author)

  13. Environmentally-Assisted Cracking of Low-Alloy Reactor Pressure Vessel Steels under Boiling Water Reactor Conditions

    International Nuclear Information System (INIS)

    The present report summarizes the experimental work performed by PSI on the environmentally-assisted cracking (EAC) of low-alloy steels (LAS) in the frame of the RIKORR-project during the period from January 2000 to August 2001. Within this project, the EAC crack growth behaviour of different low-alloy reactor pressure vessel (RPV) steels, weld filler and weld heat-affected zone materials is investigated under simulated transient and steady-state BWR/NWC power operation conditions. The EAC crack growth behaviour of different low-alloy RPV steels was characterized by slow rising load (SRL) / low-frequency corrosion fatigue (LFCF) and constant load tests with pre-cracked fracture mechanics specimens in oxygenated high-temperature water at temperatures of either 288, 250, 200 or 150 C. These tests revealed the following important interim results: Under low-flow and highly oxidizing (ECP >= 100 mV SHE) conditions, the ASME XI 'wet' reference fatigue crack growth curve could be significantly exceeded by cyclic fatigue loading at low frequencies (<0.001 Hz), at high and low load-ratios R, and by ripple loading near to DKth fatigue thresholds. The BWR VIP 60 SCC disposition lines may be significantly or slightly exceeded (even in steels with a low sulphur content) in the case of small load fluctuations at high load ratios (ripple loading) or at intermediate temperatures (200 -250 C) in RPV materials, which show a distinct susceptibility to dynamic strain ageing (DSA). (author)

  14. PERFORMANCE IMPROVEMENT OF CREEP-RESISTANT FERRITIC STEEL WELDMENTS THROUGH THERMO-MECHANICAL TREATMENT AND ALLOY DESIGN

    Energy Technology Data Exchange (ETDEWEB)

    Yamamoto, Yukinori [ORNL; Babu, Prof. Sudarsanam Suresh [University of Tennessee, Knoxville (UTK); Shassere, Benjamin [ORNL; Yu, Xinghua [ORNL

    2016-01-01

    Two different approaches have been proposed for improvement of cross-weld creep properties of the high temperature ferrous structural materials for fossil-fired energy applications. The traditional creep strength-enhanced ferritic (CSEF) steel weldments suffer from Type IV failures which occur at the fine-grained heat affected zone (FGHAZ). In order to minimize the premature failure at FGHAZ in the existing CSEF steels, such as modified 9Cr-1Mo ferritic-martensitic steels (Grade 91), a thermo-mechanical treatment consisting of aus-forging/rolling and subsequent aus-aging is proposed which promotes the formation of stable MX carbonitrides prior to martensitic transformation. Such MX remains undissolved during welding process, even in FGHAZ, which successfully improves the cross-weld creep properties. Another approach is to develop a new fully ferrtic, creep-resistant FeCrAl alloy which is essentially free from Type IV failure issues. Fe-30Cr-3Al base alloys with minor alloying additions were developed which achieved a combination of good oxidation/corrosion resistance and improved tensile and creep performance comparable or superior to Grade 92 steel.

  15. Microstructure and Properties of Lap Joint Between Aluminum Alloy and Galvanized Steel by CMT

    Science.gov (United States)

    Niu, Song; Chen, Su; Dong, Honggang; Zhao, Dongsheng; Zhang, Xiaosheng; Guo, Xin; Wang, Guoqiang

    2016-05-01

    Lap joining of 1-mm-thick Novelist AC 170 PX aluminum alloy to 1.2-mm-thick ST06 Z galvanized steel sheets for automotive applications was conducted by cold metal transfer advanced welding process with ER4043 and ER4047 filler wires. Under the optimized welding parameters with ER4043 filler wire, the tensile shear strength of joint was 189 MPa, reaching 89% of the aluminum alloy base metal. Microstructure and elemental distribution were characterized by optical metalloscope and electron probe microanalysis. The lap joints with ER4043 filler wire had smaller wetting angle and longer bonded line length with better wettability than with ER4047 filler wire during welding with same parameters. The needle-like Al-Fe-Si intermetallic compounds (IMCs) were spalled into the weld and brought negative effect to the tensile strength of joints. With increasing welding current, the needle-like IMCs grew longer and spread further into the weld, which would deteriorate the tensile shear strength.

  16. Electrochemical assessment of some titanium and stainless steel implant dental alloys

    Directory of Open Access Journals (Sweden)

    Echevarría, A.

    2003-12-01

    Full Text Available Commercially pure titanium alloy, Ti-6Al-4V alloy and stainless steel screw implants were evaluated in both Ringer and synthetic saliva physiological solutions at body temperature by EIS (Electrochemical Impedance Spectroscopy with immersion times of 30 d. Results were simulated as a "sandwich system" composed by four capacitors-resistances connected in series with the solution resistance. A model explaining the results in terms of the porosity and thickness of four different layers, was proposed.

    Se utilizó la técnica de la Espectroscopia de Impedancia Electroquímica para evaluar en soluciones fisiológicas artificiales (Ringer y saliva sintética muestras extraídas de tornillos de implantes dentales certificados de titanio comercialmente puro, aleación Ti-6Al-W y acero inoxidable a temperatura corporal, con tiempos de inmersión hasta de 30 d. Los resultados se simularon mediante un modelo del tipo sandwich de cuatro elementos RC, conectados en serie con una resistencia de la solución. A partir de de esta simulación, se propone un modelo que explica los resultados obtenidos en términos de la evolución de la porosidad y el espesor de cuatro diferentes capas que se desarrollan en la superficie de los materiales evaluados.

  17. Burst Martensitic Transformations in a Steel and in a Pu-Ga Alloy

    Energy Technology Data Exchange (ETDEWEB)

    Blobaum, K; Krenn, C; Wall, M; Schwartz, A

    2005-06-14

    Upon cooling a Pu-2.0 at% Ga alloy from the ambient temperature, the metastable delta phase partially transforms martensitically to the alpha-prime phase. Because this transformation involves a 25% volume contraction, plastic accommodation by the delta matrix must occur. When the material is isochronally heated or isothermally annealed above ambient temperatures, the reversion of alpha-prime to delta is likely to occur by the alpha-prime/delta interface moving to consume the alpha-prime particles. This reversion exhibits a burst martensitic mode and is observed as sharp spikes in differential scanning calorimetry data and as steps in resistometry data. These large bursts appear to be the result of an interplay between the autocatalytically driven transformation of individual alpha-prime particles and self-quenching caused by small changes in temperature and/or stress accompanying each burst. The behavior of this Pu-Ga alloy is compared to that of a steel referred to as a ''burst martensite'' in the literature, which also exhibits bursts during both thermal cycling and isothermal holds.

  18. Twin-wire Submerged Arc Welding Process of a High-strength Low-alloy Steel

    Institute of Scientific and Technical Information of China (English)

    YANG Xiuzhi; XU Qinghua; YIN Niandong; XIAO Xinhua

    2011-01-01

    The measurement of thermal cycle curves of a high-strength low-alloy steel (HSLA)subjected twin-wire submerged arc welding (SAW) was introduced. The thermal simulation test was performed by using the obtained curves. The impact toughness at -50 ℃ temperature of the simulated samples was also tested. OM, SEM and TEM of the heat-affected zone (HAZ) of some simulation specimens were investigated. The results showed that the HSLA endured the twin-wire welding thermal cycle, generally, the low-temperature toughness values of each part of HAZ was lower than that of the parent materials, and the microstructure of coarse-grained zone(CGHAZ) mainly made up of granular bainite is the reason of the toughness serious deterioration. Coarse grain, grain boundary carbide extract and M-A island with large size and irregular polygon, along the grain boundary distribution, are the reasons for the toughness deterioration of CGHAZ. The research also showed that selected parameters of twin-wire SAW can meet the requirements to weld the test steel.

  19. Microstructure, Precipitation, and Mechanical Properties of V-N-Alloyed Steel After Different Cooling Processes

    Science.gov (United States)

    Zhang, Jing; Wang, Fu-Ming; Yang, Zhan-Bing; Li, Chang-Rong

    2016-09-01

    Three cooling processes (direct air cooling, water cooling to 1023 K and 873 K (750 °C and 600 °C) followed by air cooling) after hot rolling are designed to develop V-N-alloyed 600 MPa grade high-strength steel for architectural construction. Microstructural characteristics, precipitation behavior, and mechanical properties were investigated. Experimental results indicate that all microstructures are composed of polygonal ferrite and pearlite. Compared to the microstructure obtained from traditional direct air cooling, the grain size of ferrite is refined from 6.5 to 4.6 μm and the interlamellar spacing of pearlite decreases from 136 to 45 nm, respectively, by the application of accelerated cooling and lower finish cooling temperature. The number fraction of high misorientation angle boundaries increases from 44 to 51 pct. Moreover, the sheet spacing of interphase precipitates decreases from (23 to 26 nm) to (14 to 17 nm) and the size of V(C,N) particles reduces from (5 to 8 nm) to (2 to 5 nm). Furthermore, the optimal mechanical properties are obtained in the steel water cooled to 873 K (600 °C), of which the yield strength, tensile strength, total elongation, uniform elongation, and impact energy at room temperature are 753 MPa, 922 MPa, 22 pct, 11 pct, and 36 J, respectively. Besides, the high yield strength is primarily attributed to the refined grains and precipitation hardening from interphase and random precipitation of nano-scale V(C,N) particles.

  20. Characterization and Cytotoxic Assessment of Ballistic Aerosol Particulates for Tungsten Alloy Penetrators into Steel Target Plates

    Directory of Open Access Journals (Sweden)

    Brian E. Schuster

    2010-08-01

    Full Text Available The nature and constituents of ballistic aerosol created by kinetic energy penetrator rods of tungsten heavy alloys (W-Fe-Ni and W-Fe-Co perforating steel target plates was characterized by scanning and transmission electron microscopy. These aerosol regimes, which can occur in closed, armored military vehicle penetration, are of concern for potential health effects, especially as a consequence of being inhaled. In a controlled volume containing 10 equispaced steel target plates, particulates were systematically collected onto special filters. Filter collections were examined by scanning and transmission electron microscopy (SEM and TEM which included energy-dispersive (X-ray spectrometry (EDS. Dark-field TEM identified a significant nanoparticle concentration while EDS in the SEM identified the propensity of mass fraction particulates to consist of Fe and FeO, representing target erosion and formation of an accumulating debris field. Direct exposure of human epithelial cells (A549, a model for lung tissue, to particulates (especially nanoparticulates collected on individual filters demonstrated induction of rapid and global cell death to the extent that production of inflammatory cytokines was entirely inhibited. These observations along with comparisons of a wide range of other nanoparticulate species exhibiting cell death in A549 culture may suggest severe human toxicity potential for inhaled ballistic aerosol, but the complexity of the aerosol (particulate mix has not yet allowed any particular chemical composition to be identified.

  1. Interaction of carbon-vacancy complex with minor alloying elements of ferritic steels

    Science.gov (United States)

    Bakaev, A.; Terentyev, D.; He, X.; Zhurkin, E. E.; Van Neck, D.

    2014-08-01

    Interstitial carbon, dissolved in bcc matrix of ferritic steels, plays an important role in the evolution of radiation-induced microstructure since it exhibits strong interaction with vacancies. Frequent formation and break-up of carbon-vacancy pairs, occurring in the course of irradiation, affect both kinetics of the accumulation of point defect clusters and carbon spatial distribution. The interaction of typical alloying elements (Mn, Ni, Cu, Si, Cr and P) in ferritic steels used as structural materials in nuclear reactors with a carbon-vacancy complex is analyzed using ab initio techniques. It is found that all the considered solutes form stable triple clusters resulting in the increase of the total binding energy by 0.2-0.3 eV. As a result of the formation of energetically favourable solute-carbon-vacancy triplets, the dissociation energy for vacancy/carbon emission is also increased by ∼0.2-0.3 eV, suggesting that the solutes enhance thermal stability of carbon-vacancy complex. Association of carbon-vacancy pairs with multiple solute clusters is found to be favorable for Ni, Cu and P. The energetic stability of solute(s)-carbon-vacancy complexes was rationalized on the basis of pairwise interaction data and by analyzing the variation of local magnetic moments on atoms constituting the clusters.

  2. Pack Aluminide Coatings Formed at 650℃ for Enhancing Oxidation Resistance of Low Alloy Steels

    Institute of Scientific and Technical Information of China (English)

    Z.D.Xiang; S.R.Rose; P.K.Datta

    2004-01-01

    This study aims to investigate the feasibility of forming iron aluminide coatings on a commercial 9Cr-1Mo (wt.%) alloy steel by pack cementation at 650℃ in an attempt to improve its high temperature oxidation resistance. Pack powders containing Al, Al2O3 and a series of halide salts were used to carry out the coating deposition experiments, which enabled identification of the most suitable activator for the pack aluminising process at the intended temperature. The effect of pack aluminium content on the growth kinetics and microstructure of the coatings was then studied by keeping deposition conditions and pack activator content constant while increasing the pack aluminium content from 1.4 wt.% to 6 wt.%. X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) techniques were used to analyse the phases and microstructures of the coatings formed and to determine depth profiles of coating elements in the coating layer. Oxidation resistance of the coating was studied at 650 ~C in air by intermittent weight measurement at room temperature. It was observed that the coating could substantially enhance the oxidation resistance of the steel under these testing conditions, which was attributed to the capability of the iron aluminide phases to form alumina scale on the coating surface through preferential A1 oxidation.

  3. Pack Aluminide Coatings Formed at 650 ℃ for Enhancing Oxidation Resistance of Low Alloy Steels

    Institute of Scientific and Technical Information of China (English)

    Z. D. Xiang; S. R. Rose; P. K. Datta

    2004-01-01

    This study aims to investigate the feasibility of forming iron aluminide coatings on a commercial 9Cr-lMo (wt.%)alloy steel by pack cementation at 650 ℃ in an attempt to improve its high temperature oxidation resistance. Pack powders containing Al, Al2O3 and a series of halide salts were used to carry out the coating deposition experiments, which enabled identification of the most suitable activator for the pack aluminising process at the intended temperature. The effect of pack aluminium content on the growth kinetics and microstructure of the coatings was then studied by keeping deposition conditions and pack activator content constant while increasing the pack aluminium content from 1.4 wt.% to 6 wt.%. X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) techniques were used to analyse the phases and microstructures of the coatings formed and to determine depth profiles of coating elements in the coating layer. Oxidation resistance of the coating was studied at 650 ℃ in air by intermittent weight measurement at room temperature. It was observed that the coating could substantially enhance the oxidation resistance of the steel under these testing conditions, which was attributed to the capability of the iron aluminide phases to form alumina scale on the coating surface through preferential Al oxidation.

  4. Laser welding of TiNi shape memory alloy and stainless steel using Ni interlayer

    International Nuclear Information System (INIS)

    Highlights: ► Laser welding was achieved using Ni interlayer between TiNi SMA and stainless steel. ► Ni interlayer thickness has great effects on joint microstructure and properties. ► Increasing Ni interlayer thickness results in increasing γ-Fe phase in weld metals. ► Excessive addition of Ni results in forming more TiNi3 and pores in the weld metals. ► Suitable Ni interlayer thickness improves the joint quality. -- Abstract: Laser welding of TiNi shape memory alloy wire to stainless steel wire using Ni interlayer was investigated. The results indicated that the Ni interlayer thickness had great effects on the chemical composition, microstructure, gas-pore susceptibility and mechanical properties of laser-welded joints. With an increase of Ni interlayer thickness, the weld Ni content increased and the joint properties increased due to decreasing brittle intermetallic compounds (TiFe2 and TiCr2). The joint fracture occurred in the fusion zone with a brittle intermetallic compound layer. The tensile strength and elongation of the joints reached the maximum values (372 MPa and 4.4%) when weld Ni content was 47.25 wt.%. Further increasing weld Ni content resulted in decreasing the joint properties because of forming more TiNi3 phase, gas-pores and shrinkage cavities in the weld metals. It is necessary to select suitable Ni interlayer thickness (weld composition) for improving the mechanical properties of laser-welded joints.

  5. Hydrogen effects in nitrogen-alloyed austenitic steels; Wirkung von Wasserstoff in stickstofflegierten austenitischen Staehlen

    Energy Technology Data Exchange (ETDEWEB)

    Uhlemann, M.; Mummert, K. [Institut fuer Festkoerper- und Werkstofforschung Dresden e.V. (Germany); Shehata, M.F. [National Research Centre, Cairo (Egypt)

    1998-12-31

    Hydrogen increases the yield strength of nitrogen-alloyed steels, but on the other hand adversely affects properties such as tensile strength and elongation to fracture. The effect is enhanced with increasing nitrogen and hydrogen contents. Under the effect of hydrogen addition, the discontinuous stress-strain characteristic and the distinct elongation limit of hydrogen-free, nitrogen containing steels is no longer observed in the material. This change of mechanical properties is attributed to an interatomic interaction of nitrogen and hydrogen in the lattice, which is shown for instance by such effects as reduction of hydrogen velocity, high solubility, and a particularly strong lattice expansion. The nature of this interaction of nitrogen and hydrogen in the fcc lattice remains to be identified. (orig./CB) [Deutsch] Wasserstoff fuehrt in stickstofflegierten Staehlen zu einer Erhoehung der Streckgrenze, aber gleichzeitig zu einer Abnahme der Zugfestigkeit und Bruchdehnung. Dieser Effekt verstaerkt sich mit zunehmenden Stickstoff- und Wasserstoffgehalten. Ein diskontinuierlicher Spannungs-Dehnungsverlauf mit einer ausgepraegten Streckgrenze in wasserstofffreien hochstickstoffhaltigen Staehlen wird nach Wasserstoffeinfluss nicht mehr beobachtet. Die Aenderung der mechanischen Eigenschaften, wird auf eine interatomare Wechselwirkung von Stickstoff und Wasserstoff im Gitter zurueckgefuehrt, die sich u.a. in geringer Wasserstoffdiffusionsgeschwindigkeit, hoher Loeslichkeit und vor allem in extremer Gitteraufweitung aeussert. Insgesamt ist die Natur der Wechselwirkung zwischen Stickstoff und Wasserstoff im kfz Gitter noch nicht aufgeklaert. (orig.)

  6. Modification of Low-Alloy Steel Surface by Plasma Electrolytic Nitriding

    Science.gov (United States)

    Kusmanov, S. A.; Smirnov, A. A.; Silkin, S. A.; Belkin, P. N.

    2016-07-01

    The structure of the low-alloy steel after plasma electrolytic nitriding (PEN) in electrolyte containing ammonium nitrate was investigated. The cross-sectional microstructure, composition, and phase constituents of modified layer under different processing conditions were characterized. It is shown that anode PEN provides the saturation of steel with nitrogen and formation of α-Fe2O3, FeO, and Fe3O4 oxides, Fe2-3N nitride, and martensite. The aqueous solution that contained 15 wt.% NH4Cl and 5 wt.% NH4NO3 allows one to obtain the hardened layer with a thickness of 80 μm and a microhardness up to 740 HV during 5 min at 850 °C. Surface roughness decreases from 1.5 to 0.8 μm after 5-min PEN at 650 °C. The proposed electrolyte and processing mode (750 °C, 10 min) enable to obtain the decrease in the weight loss after lubricate wear testing by a factor of 2.7. The base-nitrate electrolyte conditioned a decrease in the corrosion current density by a factor of 9 due to passivating effect of the oxide and nitride of iron.

  7. Anisotropic work-hardening behaviour ofstructural steels and aluminium alloys at large strains

    Science.gov (United States)

    Bouvier, S.; Teodosiu, C.; Haddadi, H.; Tabacaru, V.

    2003-03-01

    Sheet metal forming processes may often involve intense forming sequences, leading to large strains and severe strain-path changes. Optimizing such technologies requires a good understanding and description of the anisotropic plastic behaviour of the deformed material, in connection with the evolution of its texture and microstructure. In this paper, we present the predictions provided by a model involving isotropic and kinematioc hardening and by a physically-based microstructural model, which introduces additional internal variables taking into accounthe directional strength of dislocation structures and their polarity. These models have been identified by using sequences of uniaxial traction and simple shear experiments, carried out on various steels (DC06, DP600, HSLA340) and aluminium alloys (AA5182-O, AA6016-T4). The microstructural model proved able predict the complex hardening behaviour displayed, especially by the ferritic steels, namely the transient work-hardening stagnation during reversed deformation in Bauschinger tests, the temporary work-softening during orthogonal tests, and the grain fragmentation at large monotonie strains.

  8. Interaction of carbon–vacancy complex with minor alloying elements of ferritic steels

    Energy Technology Data Exchange (ETDEWEB)

    Bakaev, A., E-mail: abakaev@sckcen.be [SCK-CEN, Nuclear Materials Science Institute, Boeretang 200, Mol B2400 (Belgium); Center for Molecular Modeling, Department of Physics and Astronomy, Ghent University, Technologiepark 903, 9052 Zwijnaarde (Belgium); Department of Experimental Nuclear Physics K-89, Institute of Physics, Nanotechnology and Telecommunications, St. Petersburg State Polytechnical University, 29 Polytekhnicheskaya Str., 195251 St. Petersburg (Russian Federation); Terentyev, D. [SCK-CEN, Nuclear Materials Science Institute, Boeretang 200, Mol B2400 (Belgium); He, X. [China Institute of Atomic Energy, P.O. Box 275-51, 102413 Beijing (China); Zhurkin, E.E. [Department of Experimental Nuclear Physics K-89, Institute of Physics, Nanotechnology and Telecommunications, St. Petersburg State Polytechnical University, 29 Polytekhnicheskaya Str., 195251 St. Petersburg (Russian Federation); Van Neck, D. [Center for Molecular Modeling, Department of Physics and Astronomy, Ghent University, Technologiepark 903, 9052 Zwijnaarde (Belgium)

    2014-08-01

    Interstitial carbon, dissolved in bcc matrix of ferritic steels, plays an important role in the evolution of radiation-induced microstructure since it exhibits strong interaction with vacancies. Frequent formation and break-up of carbon–vacancy pairs, occurring in the course of irradiation, affect both kinetics of the accumulation of point defect clusters and carbon spatial distribution. The interaction of typical alloying elements (Mn, Ni, Cu, Si, Cr and P) in ferritic steels used as structural materials in nuclear reactors with a carbon–vacancy complex is analyzed using ab initio techniques. It is found that all the considered solutes form stable triple clusters resulting in the increase of the total binding energy by 0.2–0.3 eV. As a result of the formation of energetically favourable solute–carbon–vacancy triplets, the dissociation energy for vacancy/carbon emission is also increased by ∼0.2–0.3 eV, suggesting that the solutes enhance thermal stability of carbon–vacancy complex. Association of carbon–vacancy pairs with multiple solute clusters is found to be favorable for Ni, Cu and P. The energetic stability of solute(s)–carbon–vacancy complexes was rationalized on the basis of pairwise interaction data and by analyzing the variation of local magnetic moments on atoms constituting the clusters.

  9. Parameters of straining-induced corrosion cracking in low-alloy steels in high temperature water

    International Nuclear Information System (INIS)

    Tensile tests with slow deformation speed determine parameters of corrosion cracking at low strain rates of low-alloy steels in high-temperature water. Besides the strain rate the temperature and oxygen content of the water prove to be important for the deformation behaviour of the investigated steels 17MnMoV64, 20 MnMoNi55 and 15NiCuMoNb 5. Temperatures about 2400C, increased oxygen contents in the water and low strain rates cause a decrease of the material ductility as against the behaviour in air. Tests on the number of stress cycles until incipient cracking show that the parameters important for corrosion cracking at low strain velocities apply also to low-frequency cyclic loads with high strain amplitude. In knowledge of these influencing parameters the strain-induced corrosion cracking is counteracted by concerted measures taken in design, construction and operation of nuclear power stations. Essential aims in this matter are to avoid as far as possible inelastic strains and to fix and control suitable media conditions. (orig.)

  10. Comparison of surface laser alloying of chosen tool steel using Al2O3 and ZrO2 powder

    Directory of Open Access Journals (Sweden)

    K. Labisz

    2010-03-01

    Full Text Available Purpose: In this work there are presented the investigation results of mechanical properties and microstructure of the hot work tool steel 32CrMoV12-28 alloyed with oxide powders like aluminium oxide and zirconium oxide. The purpose of this work was also to determine the laser treatment conditions for surface hardening of the investigation alloys with appliance of transmission electron microscopy.Design/methodology/approach: The investigations were performed using optical microscopy for the microstructure determination. By mind of the transmission electron microscopy the high resolution and phase determination was possible to obtain. The morphology of the ceramic powder particles was studied as well the lattice parameters for the Fe matrix and phase identification using diffraction methods was applied.Findings: After the laser alloying of the hot work tool steel with the selected oxide powders the structure of the samples changes in a way, that there are zones detected like the remelting zone the heat influence zone where the grains are larger and not so uniform as in the metal matrix. The used oxide powders are not present after the laser treatment in the steel matrix.Research limitations/implications: The investigated steel samples were examined metallographically using optical microscope with different image techniques, SEM, TEM and analyzed using a Rockwell hardness tester, also EDS microanalysis and electron diffraction with Fourier transform was made.Practical implications: As an implication for the practice a new technology can be possible to develop, based no diode laser usage. Some other investigation should be performed in the future, but the knowledge found in this research shows an interesting investigation direction.Originality/value: The combination of TEM investigation for laser alloying of hot work tool steels makes the investigation very attractive for automotive and other heavy industries.

  11. Prediction of microcracking in laser overly welds of alloy 690 to type 316L stainless steel

    International Nuclear Information System (INIS)

    The occurrence of ductility-dip crack in the laser overlay welds of alloy 690 to type 316L stainless steel was predicted by the mechanical and metallurgical approaches. Ductility-dip temperature ranges (DTRs) of alloy 690 laser overlay welds were estimated by Varestraint test during GTA welding. The grain boundary segregation of impurity elements such as P and S was numerically analyzed based on the non-equilibrium cosegregation theory when the welding speed and the amounts of P and S in the weld metal were varied. In accordance with the repression approximation between the DTR and the calculated grain boundary concentrations of P and S, the DTRs of alloy 690 were computed in laser overlay welding. The estimated DTR in laser overlay welds was reduced with an increase in welding speed and with a decrease in the amounts of P and S in the weld metal. Ductility-dip cracking in laser overlay welds was predicted by the plastic strain-temperature curve intersected the DTR. The plastic strain in laser overlay welding was numerically analyzed using the thermo elasto-plastic finite element method. The plastic strain-temperature curve in laser overlay welds intersected the DTR at decreased welding speed and increased (P+S) content in the weld metal. The predicted results of ductility-dip cracking in laser overlay welds were approximately consistent with experiment results. It follows that ductility-dip cracking in laser overlay welds could be successfully predicted based on the estimated DTR from grain boundary segregation analysis combined with the computed plastic strain by FEM analysis. (author)

  12. Exchange interaction and magnetic phase transition in FeRh alloy

    Energy Technology Data Exchange (ETDEWEB)

    Zhou Yumei; Gao Xing; Wang Dingsheng E-mail: dswang@aphy.iphy.ac.cn

    2001-05-01

    The total energies of a series of frozen collinear magnon configurations are calculated for FeRh alloy by the first-principles all-electron linearized augmented planewave method. Effective exchange integrals are obtained by fitting the total energy to an Heisenberg model. Monte Carlo simulation is used to investigate the magnetic phase transition. The obtained phase transition characters are in reasonable agreement with the experiments.

  13. Phase field modeling for dendritic morphology transition and micro-segregation in multi-component alloys

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    By using the phase field model for the solidification of multi-component alloys and coupling with real thermodynamic data, the dendritic morphology transition and the dendritic micro-segregation of Ni-Al-Nb ternary alloys are simulated in two cases, i.e., varying the alloy composition at a fixed under-cooling and varying the undercooling at a fixed alloy composition. The simulated results indicate that with the increase of the dimensionless undercooling U (U=ΔT/ΔT0, where ΔT is the undercooling and ΔT0 the temperature interval between the solidus and liquidus), the dendritic morphology transfers from dendritic to globular growth in both cases. As to the dendritic micro-segregation, both cases present a regularity of increasing at first and then decreasing.

  14. Low-frequency internal friction investigating of the carbide precipitation in solid solution during tempering in high alloyed martensitic steel

    International Nuclear Information System (INIS)

    Research highlights: In this paper, the mechanical properties and the internal friction (IF) of high alloyed martensitic carbon steel were investigated. The relationships between the internal friction and mechanical properties of the steel were researched using dilatometer, X-ray diffraction, Rockwell hardness and impact toughness. The behavior of dislocations and their interactions with point defects were analyzed through the changes of the internal friction spectrum. At some extent, internal friction techniques can be used as a quality control tool in steel industry for heat treatment. - Abstract: In this paper, the mechanical properties and the internal friction (IF) of high alloyed martensitic carbon steel were investigated. The relationships between the internal friction and mechanical properties of the steel containing 0.98 wt.% carbon were researched using dilatometer, X-ray diffraction, Rockwell hardness and impact toughness. The samples were quenched and tempered in order to vary the concentration of carbon in solid solution in the martensite. The internal friction was measured in an inversed torsion pendulum with high vacuum using free decay method. The behavior of dislocations and their interactions with point defects were analyzed through the changes of the internal friction spectrum.

  15. The small punch assessment of toughness losses in low alloy steels

    Energy Technology Data Exchange (ETDEWEB)

    Bulloch, J.H. [ESB, Power Generation, Dublin (Ireland)

    1998-12-31

    The presentation deals at length with the relationship between the Small Punch, SP, test transition temperature Tsp, behaviour and those displayed by the conventional Charpy Fracture Appearance Transition Temperature, FATT, obtained from large test specimens. Essentially it was demonstrated that the total test temperature range trends could reasonably be described by a non-linear expression such as FATT varied inversely with the square of the Tsp. Finally when the Tsp against FATT trends were separated into different steel classes an encouraging picture emerged inasmuch that a reasonable amount of data exhibited good agreement with the predicted effects of grain size. Fractographic details were also discussed and strong effects of strain or loading rates were identified. (orig.) 19 refs.

  16. Upper critical fields and superconducting transition temperatures of some zirconium-base amorphous transition-metal alloys

    Science.gov (United States)

    Karkut, M. G.; Hake, R. R.

    1983-08-01

    Superconducting upper critical fields Hc2(T), transition temperatures Tc and normal-state electrical resistivities ρn have been measured in the amorphous transition-metal alloy series Zr1-xCox, Zr1-xNix, (Zr1-xTix)0.78Ni0.22, and (Zr1-xNbx)0.78Ni0.22. Structural integrity of these melt-spun alloys is indicated by x-ray, density, bend-ductility, normal-state electrical resistivity, superconducting transition width, and mixed-state flux-pinning measurements. The specimens display Tc=2.1-3.8 K, ρn=159-190 μΩ cm, and |(dHc2dT)Tc|=28-36 kG/K. These imply electron mean free paths l~2-6 Å, zero-temperature Ginzburg-Landau coherence distances ξG0~50-70 Å, penetration depths λG0~(7-10)×103 Å, and extremely high dirtiness parameters ξ0l~300-1300. All alloys display Hc2(T) curves with negative curvature and (with two exceptions) fair agreement with the standard dirty-limit theory of Werthamer, Helfand, Hohenberg, and Maki (WHHM) for physically reasonable values of spin-orbit-coupling induced, electron-spin-flip scattering time τso. This is in contrast to the anomalously elevated Hc2(T) behavior which is nearly linear in T that is observed by some, and the unphysically low-τso fits to WHHM theory obtained by others, for various amorphous alloys. Current ideas that such anomalies may be due to alloy inhomogeneity are supported by present results on two specimens for which relatively low-τso fits of Hc2(T) to WHHM theory are coupled with superconductive evidence for inhomogeneity: relatively broad transitions at Tc and Hc2 current-density-dependent transitions at Hc2 and (in one specimen) a J-dependent, high-H (>Hc2), resistive "beak effect." In the Zr1-xCox and Zr1-xNix series, Tc decreases linearly with x (and with unfilled-shell average electron-to-atom ratio in the range 5.05previous results for these systems and contrary to the Tc vs behavior of both amorphous and crystalline transition-metal alloys formed between near neighbors in the Periodic Table. Upper

  17. Effect of material flow on joint strength in activation spot joining of Al alloy and steel sheets

    Science.gov (United States)

    Watanabe, Goro; Yogo, Yasuhiro; Takao, Hisaaki

    2014-08-01

    A new joining method for dissimilar metal sheets was developed where a rotated consumable rod of Al alloy is pressed onto an Al alloy sheet at the part overlapped with a mild steel sheet. The metal flow in the joining region is increased by the through-hole in the Al sheet and consumable Al rod. The rod creates the joint interface and pads out of the thinly joined parts through pressing. This produces a higher joint strength than that of conventional friction stir spot welding. Measurements of the joint interface showed the presence of a 5-10 nm thick amorphous layer consisting of Al and Mg oxides.

  18. Experimental investigations on welding behaviour of sintered and forged Fe–0.3%C–3%Mo low alloy steel

    International Nuclear Information System (INIS)

    Highlights: • Feasible to weld Fe–0.3%C–3%Mo P/M low alloy steel by TIG welding with filler. • Density of parent metal does not influence weld zone microstructure and hardness. • Acicular ferritic structure of WZ and non-martensitic HAZ promotes good weld quality. • Tensile strength of welded joint is higher than that of base metal (Fe–0.3%C–3%Mo). - Abstract: Tungsten Inert Gas (TIG) welding is considered as one of the cleanest welding methods. It is generally adopted for thinner materials with moderate weld joint strengths. Welding of sintered porous materials continues to be a challenge due to the inherent porosity of the parent metals. The present research work attempts to address some of the issues relating to the welding behaviour of sintered and forged Fe–0.3%C–3%Mo low alloy steels under TIG welding. Rectangular strips of size 70 mm × 15 mm × 5 mm, obtained by blending, compacting and sintering of elemental powders of iron, graphite and molybdenum, were upset forged – both hot and cold in order to obtain alloy steel strips of various porosities. Two identical alloy steel strips of equal density were then welded both along longitudinal and transverse directions, by TIG welding, employing filler metal of suitable composition. The welded strips were then subjected to tensile test, hardness test, microstructural and Scanning Electron Microscope (SEM) fractography studies. Cold/hot upsetting of the sintered alloy preforms has led to enhanced density. As a result of improved density, their tensile strength and hardness values were also found to be enhanced. The welded alloy exhibited higher tensile strength compared to the un-welded base metal, due to strengthening by residual stress. Similarly, the strength and hardness of the welded alloy strips were found to be enhanced with increase in density. The tensile strength of welded joint is found to be higher compared to that of the base metal due to alloy metals segregation, rapid cooling

  19. Assessment of The Cracking Properties of Stainless Steel Alloys and their Usability for Laser Welding in Production

    DEFF Research Database (Denmark)

    Juhl, Thomas Winther

    2001-01-01

    Methods to assess stainless steel alloys’ cracking properties and usability for laser welding has been studied. Also tests to assess alloys’ susceptibility to hot cracking has been conducted. Among these is the so-called Weeter test which assesses the alloy by executing a number of spot welds...... to provoke cracking in the alloy. In this work the Weeter test has been modified and changed in order to develop a faster and easier test also applicable to small specimens. The new test, called a Groove test differs from the Weeter test by its procedure in which linear seam welds are conducted instead...

  20. An Investigation of the Microstructure of an Intermetallic Layer in Welding Aluminum Alloys to Steel by MIG Process

    OpenAIRE

    Quoc Manh Nguyen; Shyh-Chour Huang

    2015-01-01

    Butt joints of A5052 aluminum alloy and SS400 steel, with a new type of chamfered edge, are welded by means of metal inert gas welding and ER4043 Al-Si filler metal. The microhardness and microstructure of the joint are investigated. An intermetallic layer is found on the surface of the welding seam and SS400 steel sheet. The hardness of the intermetallic layer is examined using the Vickers hardness test. The average hardness values at the Intermetallic (IMC) layer zone and without the IMC la...