WorldWideScience

Sample records for allen dysert ii

  1. Allen Say.

    Science.gov (United States)

    Beck, Martha Davis

    1999-01-01

    This interview with Allen Say, a Japanese picture book author and illustrator, discusses his apprenticeship to a cartoonist; the use of color; the role of editors; the theme of searching for identity; landscapes; and his move to America. (LRW)

  2. Palladium(II)-Catalyzed Annulation between ortho-Alkenylphenols and Allenes. Key Role of the Metal Geometry in Determining the Reaction Outcome

    Science.gov (United States)

    2016-01-01

    2-Alkenylphenols react with allenes, upon treatment with catalytic amounts of Pd(II) and Cu(II), to give benzoxepine products in high yields and with very good regio- and diastereoselectivities. This contrasts with the results obtained with Rh catalysts, which provided chromene-like products through a pathway involving a β-hydrogen elimination step. Computational studies suggest that the square planar geometry of the palladium is critical to favor the reductive elimination process required for the formation of the oxepine products.

  3. The Allen Telescope Array Twenty-centimeter Survey -- A 700-Square-Degree, Multi-Epoch Radio Dataset -- II: Individual Epoch Transient Statistics

    CERN Document Server

    Croft, Steve; Keating, Garrett; Law, Casey; Whysong, David; Williams, Peter K G; Wright, Melvyn

    2011-01-01

    We present our second paper on the Allen Telescope Array Twenty-centimeter Survey (ATATS), a multi-epoch, ~700 sq. deg. radio image and catalog at 1.4 GHz. The survey is designed to detect rare, bright transients as well as to commission the ATA's wide-field survey capabilities. ATATS explores the challenges of multi-epoch transient and variable source surveys in the domain of dynamic range limits and changing (u,v) coverage. Here we present images made using data from the individual epochs, as well as a revised image combining data from all ATATS epochs. The combined image has RMS noise 3.96 mJy / beam, with a circular beam of 150 arcsec FWHM. The catalog, generated using a false detection rate algorithm, contains 4984 sources, and is >90% complete to 37.9 mJy. The catalogs generated from snapshot images of the individual epochs contain between 1170 and 2019 sources over the 564 sq. deg. area in common to all epochs. The 90% completeness limits of the single epoch catalogs range from 98.6 to 232 mJy. We comp...

  4. The hyperbolic Allen-Cahn equation: exact solutions

    Science.gov (United States)

    Nizovtseva, I. G.; Galenko, P. K.; Alexandrov, D. V.

    2016-10-01

    Using the first integral method, a general set of analytical solutions is obtained for the hyperbolic Allen-Cahn equation. The solutions are presented by (i) the class of continual solutions described by \\tanh -profiles for traveling waves of the order parameter, and (ii) the class of singular solutions which exhibit unbounded discontinuity in the profile of the order parameter at the origin of the coordinate system. It is shown that the solutions include the previous analytical results for the parabolic Allen-Cahn equation as a limited class of \\tanh -functions, in which the inertial effects are omitted.

  5. Synthesis of furan from allenic sulfide derivatives

    Institute of Scientific and Technical Information of China (English)

    2009-01-01

    In this paper, we report the synthesis of furan derivatives from allenic sulfides. By the reaction with NaH, β-Hydroxyl allenic sulfides were found to generate furan products in excellent yields with the removal of phenylthio group. β-Aldehyde allenic sulfides were found to give similar furan products with one more substituent when treated with additional nucleophilic reagents. β-ketone allenic sulfides can also cyclize to give furan derivatives with the promotion of P2O5.

  6. Synthesis of furan from allenic sulfide derivatives

    Institute of Scientific and Technical Information of China (English)

    PENG LingLing; ZHANG Xiu; MA Jie; ZHONG ZhenZhen; ZHANG Zhe; ZHANG Yan; WANG JianBo

    2009-01-01

    In this paper, we report the synthesis of furan derivatives from allenic sulfides. By the reaction with NaH.,β-Hydroxyl allenic sulfides were found to generate furan products in excellent yields with the removal of phenylthio group.β-Aldehyde allenic sulfides were found to give similar furan products with one more substituent when treated with additional nucleophilic reagents. β-ketone allenic sulfides can also cyclize to give furan derivatives with the promotion of P2O5.

  7. Obituary: James Alfred Van Allen, 1914-2006

    Science.gov (United States)

    Ludwig, George H.; McIlwain, Carl Edwin

    2006-12-01

    new Physics and Astronomy building was completed in 1964 (rechristened in 1982, appropriately, as Van Allen Hall), he set up his private working room apart from his departmental office in a large, soon-cluttered, corner office on the seventh floor. That room became the center of his activity in 1985, when he retired as Department Head and active teacher. There, through his retirement years and until shortly before his death, he continued his roles as researcher, advisor, and mentor, serving at times as Professor Emeritus, Carver Professor of Physics, and Regent Distinguished Professor. Van Allen maintained membership in over a dozen professional organizations and received over a dozen Honorary ScD degrees. His additional awards and other distinct forms of recognition are far too numerous to list here, but include AAS's Gerard P. Kuiper Prize, the Crafoord Prize of the Royal Swedish Academy of Science, the National Medal of Science presented by U.S. President Reagan, the National Science Foundation's Vannevar Bush Award, NASA's Lifetime Achievement Award, the 2006 Smithsonian National Air and Space Museum Lifetime Achievement Trophy, the Gold Medal of the Royal Astronomy Society, AGU's John A. Fleming Award and William Bowie Medal, and the Abelson Prize by the American Association for the Advancement of Science. In addition to those many public acknowledgements of his prodigious contributions, James A. Van Allen will be fondly remembered by his many students, who now populate the entire realm of modern space research. He is survived by his wife, Abigail Fithian Halsey II Van Allen, and his five children, Cynthia Van Allen Schaffner, Dr. Margot Van Allen Cairns, Sarah Van Allen Trimble, Thomas Halsey Van Allen, and Peter C. Van Allen.

  8. Substituent effects on dynamics at conical intersections: Allene and methyl allenes

    Energy Technology Data Exchange (ETDEWEB)

    Neville, Simon P. [Department of Chemistry, University of Ottawa, 10 Marie Curie, Ottawa, Ontario K1N 6N5 (Canada); Wang, Yanmei [State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Institute of Physics and Mathematics, Chinese Academy of Sciences, Wuhan 430071 (China); Boguslavskiy, Andrey E.; Stolow, Albert, E-mail: albert.stolow@nrc-cnrc.gc.ca [Department of Chemistry, University of Ottawa, 10 Marie Curie, Ottawa, Ontario K1N 6N5 (Canada); National Research Council of Canada, 100 Sussex Drive, Ottawa, Ontario K1A 0R6 (Canada); Department of Physics, University of Ottawa, 150 Louis Pasteur, Ottawa ON K1N 6N5 (Canada); Schuurman, Michael S., E-mail: michael.schuurman@nrc-cnrc.gc.ca [Department of Chemistry, University of Ottawa, 10 Marie Curie, Ottawa, Ontario K1N 6N5 (Canada); National Research Council of Canada, 100 Sussex Drive, Ottawa, Ontario K1A 0R6 (Canada)

    2016-01-07

    We report a joint experimental and theoretical study on the ultrafast excited state dynamics of allene and a series of its methylated analogues (1,2-butadiene, 1,1-dimethylallene, and tetramethylallene) in order to elucidate the conical intersection mediated dynamics that give rise to ultrafast relaxation to the ground electronic state. We use femtosecond time-resolved photoelectron spectroscopy (TRPES) to probe the coupled electronic-vibrational dynamics following UV excitation at 200 nm (6.2 eV). Ab initio multiple spawning (AIMS) simulations are employed to determine the mechanistic details of two competing dynamical pathways to the ground electronic state. In all molecules, these pathways are found to involve as follows: (i) twisting about the central allenic C–C–C axis followed by pyramidalization at one of the terminal carbon atoms and (ii) bending of allene moiety. Importantly, the AIMS trajectory data were used for ab initio simulations of the TRPES, permitting direct comparison with experiment. For each molecule, the decay of the TRPES signal is characterized by short (30 fs, 52 fs, 23 fs) and long (1.8 ps, 3.5 ps, [306 fs, 18 ps]) time constants for 1,2-butadiene, 1,1-dimethylallene, and tetramethylallene, respectively. However, AIMS simulations show that these time constants are only loosely related to the evolution of electronic character and actually more closely correlate to large amplitude motions on the electronic excited state, modulating the instantaneous vertical ionization potentials. Furthermore, the fully substituted tetramethylallene is observed to undergo qualitatively different dynamics, as displacements involving the relatively massive methyl groups impede direct access to the conical intersections which give rise to the ultrafast relaxation dynamics observed in the other species. These results show that the branching between the “twisting” and “bending” pathways can be modified via the selective methylation of the terminal

  9. The Van Allen Probes mission

    CERN Document Server

    Burch, James

    2014-01-01

    This collection of articles provides broad and detailed information about NASA’s Van Allen Probes (formerly known as the Radiation Belt Storm Probes) twin-spacecraft Earth-orbiting mission. The mission has the objective of achieving predictive understanding of the dynamic, intense, energetic, dangerous, and presently unpredictable belts of energetic particles that are magnetically trapped in Earth’s space environment above the atmosphere. It documents the science of the radiation belts and the societal benefits of achieving predictive understanding. Detailed information is provided about the Van Allen Probes mission design, the spacecraft, the science investigations, and the onboard instrumentation that must all work together to make unprecedented measurements within a most unforgiving environment, the core of Earth’s most intense radiation regions.
 This volume is aimed at graduate students and researchers active in space science, solar-terrestrial interactions and studies of the up...

  10. EFICACIA DE LA COMBINACIÓN DEL INJERTO LIBRE DE TEJIDO CONECTIVO Y LA TÉCNICA DE ALLEN EN EL TRATAMIENTO DE LA RECESIÓN GINGIVAL CLASE II DE MILLER EN PACIENTES DE LA CONSULTA PRIVADA. AREQUIPA. 2012

    OpenAIRE

    LUJAN VALENCIA, SARA

    2015-01-01

    RECESIÓN GINGIVAL CONCEPTO FACTORES ETIOLÓGICOS SÍNTOMAS CLÍNICOS DIAGNÓSTICO CLASIFICACIÓN DE LA RECESIÓN PAPEL DE LA ENCÍA QUERATINIZADA EN LA CONSERVACIÓN DE LA SALUD GINGIVAL CONDICIONES NECESARIAS PARA EL ÉXITO DEL RECUBRIMIENTO RADICULAR TRATAMIENTO DE LAS RECESIONES GINGIVALES TRATAMIENTO CONSERVADOR TRATAMIENTO QUIRÚRGICO INJERTO LIBRE DE TEJIDO CONECTIVO Y LA TÉCNICO DE ALLEN INJERTO LIBRE DE TEJIDO CONECTIVO TÉCNICA QUIRÚRGICA BIOMODIFICACIÓN DE LA SUPERFICIE RADICULAR TÉCNICA DE AL...

  11. Van Allen Discovery Most Important

    Science.gov (United States)

    Jastrow, R.

    1959-01-01

    The first step toward the exploration of space occurred approximately 22 months ago as a part of the International Geophysical Year. In the short interval since October, 1957, the new tools of research, the satellite and the space rocket, have produced two unexpected results of fundamental scientific importance. First, instruments placed in the Explorer satellites by James A. Van Allen have revealed the existence of layers of energetic particles in the outer atmosphere. This discovery constitutes the most significant research achievement of the IGY satellite program. The layers may provide the explanation for the aurora and other geophysical phenomena, and they will also influence the design of vehicles for manned space flight, whose occupants must be shielded against their harmful biological effects. Second, the shape of the earth has been determined very accurately with the aid of data from the first Vanguard. As a result of this investigation, we have found that our planet tends toward the shape of a pear, with its stem at the North Pole. This discovery may produce major changes in our ideas on the interior structure of the earth.

  12. Phosphine catalysis of allenes with electrophiles.

    Science.gov (United States)

    Wang, Zhiming; Xu, Xingzhu; Kwon, Ohyun

    2014-05-07

    Nucleophilic phosphine catalysis of allenes with electrophiles is one of the most powerful and straightforward synthetic strategies for the generation of highly functionalized carbocycle or heterocycle structural motifs, which are present in a wide range of bioactive natural products and medicinally important substances. The reaction topologies can be controlled through a judicious choice of the phosphine catalyst and the structural variations of starting materials. This Tutorial Review presents selected examples of nucleophilic phosphine catalysis using allenes and electrophiles.

  13. Allenes and computational chemistry: from bonding situations to reaction mechanisms.

    Science.gov (United States)

    Soriano, Elena; Fernández, Israel

    2014-05-07

    The present review is focused on the application of computational/theoretical methods to the wide and rich chemistry of allenes. Special emphasis is made on the interplay and synergy between experimental and computational methodologies, rather than on recent developments in methods and algorithms. Therefore, this review covers the state-of-the-art applications of computational chemistry to understand and rationalize the bonding situation and vast reactivity of allenes. Thus, the contents of this review span from the most fundamental studies on the equilibrium structure and chirality of allenes to recent advances in the study of complex reaction mechanisms involving allene derivatives in organic and organometallic chemistry.

  14. Woody Allen, serial schlemiel ?

    Directory of Open Access Journals (Sweden)

    Frédérique Brisset

    2011-04-01

    Full Text Available Woody Allen a développé au fil des années une persona cinématographique de schlemiel new-yorkais aisément reconnaissable par le spectateur. Elle marque nombre de ses films, qu’il y apparaisse en tant qu’acteur ou y dirige des substituts comédiens comme déclinaisons de lui-même. Si cette figure prototypique est le fondement de la sérialité dans sa filmographie, il est des traits stylistiques qui en portent trace tout au long de son œuvre : la récurrence annuelle de ses réalisations, la signature formelle symbolisée par ses génériques à la typographie singulière, le rythme de ses dialogues ponctués d’interjections et l’usage de l’autocitation sont autant de procédés qui marquent son cinéma d’un sceau très personnel. Ils fonctionnent comme des clins d’œil au spectateur qui reçoit dès lors LE Woody Allen millésimé comme une invitation à retrouver son microcosme. Ainsi la sérialité se pose comme à la fois initiale et conséquentielle de son système filmique, processus de création unique dans le cinéma américain.Woody Allen has long constructed a cinematographic persona of schlemiel New- Yorker that the audience can easily identify. It impacts most of his films, whether he stars in them or directs “substitute” actors to impersonate his character. If this prototypical figure is the basis of seriality in his cinematography, serial stylistic features can also be found all along his career: the annual recurrence of his productions, the formal signature symbolised by the typography of his singular credit titles, his rhythmical interjection-punctuated dialogues and the use of self-quotation imprint a very personal seal upon his movies. They all work as a recognition signals for the audience who thus receive THE Woody Allen vintage as an invitation to re-enter his microcosm. Seriality is then both initial and consequential to his cinematographic system, a unique creative process in American film history.

  15. 33 CFR 80.1440 - Port Allen, Kauai, HI.

    Science.gov (United States)

    2010-07-01

    ... 33 Navigation and Navigable Waters 1 2010-07-01 2010-07-01 false Port Allen, Kauai, HI. 80.1440 Section 80.1440 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY INTERNATIONAL NAVIGATION RULES COLREGS DEMARCATION LINES Pacific Islands § 80.1440 Port Allen, Kauai, HI. A line drawn...

  16. Phase-transfer-catalysed asymmetric synthesis of tetrasubstituted allenes

    Science.gov (United States)

    Hashimoto, Takuya; Sakata, Kazuki; Tamakuni, Fumiko; Dutton, Mark J.; Maruoka, Keiji

    2013-03-01

    Allenes are molecules based on three carbons connected by two cumulated carbon-carbon double bonds. Given their axially chiral nature and unique reactivity, substituted allenes have a variety of applications in organic chemistry as key synthetic intermediates and directly as part of biologically active compounds. Although the demands for these motivated many endeavours to make axially chiral, substituted allenes by exercising asymmetric catalysis, the catalytic asymmetric synthesis of fully substituted ones (tetrasubstituted allenes) remained largely an unsolved issue. The fundamental obstacle to solving this conundrum is the lack of a simple synthetic transformation that provides tetrasubstituted allenes in the action of catalysis. We report herein a strategy to overcome this issue by the use of a phase-transfer-catalysed asymmetric functionalization of 1-alkylallene-1,3-dicarboxylates with N-arylsulfonyl imines and benzylic and allylic bromides.

  17. The Allen Telescope Array Commensal Observing System

    CERN Document Server

    Williams, Peter K G

    2012-01-01

    This memo describes the system used to conduct commensal correlator and beamformer observations at the Allen Telescope Array (ATA). This system was deployed for ~2 years until the ATA hibernation in 2011 and was responsible for collecting >5 TB of data during thousands of hours of observations. The general system design is presented and the implementation is discussed in detail. I emphasize the rationale for various design decisions and attempt to document a few aspects of ATA operations that might not be obvious to non-insiders. I close with some recommendations from my experience developing the software infrastructure and managing the correlator observations. These include: reuse existing systems; solve, don't avoid, tensions between projects, and share infrastructure; plan to make standalone observations to complement the commensal ones; and be considerate of observatory staff when deploying new and unusual observing modes. The structure of the software codebase is documented.

  18. James Van Allen The First Eight Billion Miles

    CERN Document Server

    Foerstner, Abigail

    2009-01-01

    Astrophysicist and space pioneer James Van Allen (1914-2006), for whom the Van Allen radiation belts were named, was among the principal scientific investigators for twenty-four space missions, including Explorer I in 1958, the first successful U.S. satellite; Mariner 2's 1962 flyby of Venus, the first successful mission to another planet; and the 1970's Pioneer 10 and Pioneer 11, missions that surveyed Jupiter and Saturn. Abigail Foerstner blends space science, drama, military agenda's, cold war politics, and the events of Van Allen's lengthy career to create the first biography of this highl

  19. Chiral allylic and allenic metal reagents for organic synthesis.

    Science.gov (United States)

    Marshall, James A

    2007-10-26

    This account traces the evolution of our work on the synthesis of chiral allylic and allenic organometal compounds of tin, silicon, zinc, and indium and their application to natural product synthesis over the past quarter century.

  20. The Trail Inventory of Private John Allen NFH [Cycle 3

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — The purpose of this report is to create a baseline inventory of all non-motorized trails on Private John Allen National Fish Hatchery. Trails in this inventory are...

  1. The Trail Inventory of Private John Allen NFH [Cycle 2

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — The purpose of this report is to create a baseline inventory of all non-motorized trails on Private John Allen National Fish Hatchery. Trails in this inventory are...

  2. Regiodivergent and Stereoselective Hydrosilylation of 1,3-Disubstituted Allenes.

    Science.gov (United States)

    Miller, Zachary D; Dorel, Ruth; Montgomery, John

    2015-07-27

    Methods for the highly stereoselective and regiodivergent hydrosilylation of 1,3-disubstituted allenes have been developed. The synthesis of E allylsilanes is accomplished with palladium NHC catalysts, and trisubstituted Z alkenylsilanes are accessed with nickel NHC catalysts. Unsymmetrically substituted allenes are well tolerated with nickel catalysis and afford Z alkenylsilanes. Evidence for a plausible mechanism was obtained through an isotopic double-labeling crossover study.

  3. Reactivity and Chemoselectivity of Allenes in Rh(I)-Catalyzed Intermolecular (5 + 2) Cycloadditions with Vinylcyclopropanes: Allene-Mediated Rhodacycle Formation Can Poison Rh(I)-Catalyzed Cycloadditions

    Science.gov (United States)

    2015-01-01

    Allenes are important 2π building blocks in organic synthesis and engage as 2-carbon components in many metal-catalyzed reactions. Wender and co-workers discovered that methyl substituents on the terminal allene double bond counterintuitively change the reactivities of allenes in [Rh(CO)2Cl]2-catalyzed intermolecular (5 + 2) cycloadditions with vinylcyclopropanes (VCPs). More sterically encumbered allenes afford higher cycloadduct yields, and such effects are also observed in other Rh(I)-catalyzed intermolecular cycloadditions. Through density functional theory calculations (B3LYP and M06) and experiment, we explored this enigmatic reactivity and selectivity of allenes in [Rh(CO)2Cl]2-catalyzed intermolecular (5 + 2) cycloadditions with VCPs. The apparent low reactivity of terminally unsubstituted allenes is associated with a competing allene dimerization that irreversibly sequesters rhodium. With terminally substituted allenes, steric repulsion between the terminal substituents significantly increases the barrier of allene dimerization while the barrier of the (5 + 2) cycloaddition is not affected, and thus the cycloaddition prevails. Computation has also revealed the origin of chemoselectivity in (5 + 2) cycloadditions with allene-ynes. Although simple allene and acetylene have similar reaction barriers, intermolecular (5 + 2) cycloadditions of allene-ynes occur exclusively at the terminal allene double bond. The terminal double bond is more reactive due to the enhanced d−π* backdonation. At the same time, insertion of the internal double bond of an allene-yne has a higher barrier as it would break π conjugation. Substituted alkynes are more difficult to insert compared with acetylene, because of the steric repulsion from the additional substituents. This leads to the greater reactivity of the allene double bond relative to the alkynyl group in allene-ynes. PMID:25379606

  4. Ruthenium-catalyzed C-C coupling of fluorinated alcohols with allenes: dehydrogenation at the energetic limit of β-hydride elimination.

    Science.gov (United States)

    Sam, Brannon; Luong, Tom; Krische, Michael J

    2015-04-27

    Ruthenium(II) complexes catalyze the CC coupling of 1,1-disubstituted allenes and fluorinated alcohols to form homoallylic alcohols bearing all-carbon quaternary centers with good to complete levels of diastereoselectivity. Whereas fluorinated alcohols are relatively abundant and tractable, the corresponding aldehydes are often not commercially available because of their instability.

  5. The Evolving Space Weather System—Van Allen Probes Contribution

    Science.gov (United States)

    Zanetti, L. J.; Mauk, B. H.; Fox, N. J.; Barnes, R. J.; Weiss, M.; Sotirelis, T. S.; Raouafi, N.-E.; Kessel, R. L.; Becker, H. N.

    2014-10-01

    The overarching goal and purpose of the study of space weather is clear—to understand and address the issues caused by solar disturbances on humans and technological systems. Space weather has evolved in the past few decades from a collection of concerned agencies and researchers to a critical function of the National Weather Service of NOAA. The general effects have also evolved from the well-known telegraph disruptions of the mid-1800s to modern day disturbances of the electric power grid, communications and navigation, human spaceflight and spacecraft systems. The last two items in this list, and specifically the effects of penetrating radiation, were the impetus for the space weather broadcast implemented on NASA's Van Allen Probes' twin pair of satellites, launched in August of 2012 and orbiting directly through Earth's severe radiation belts. The Van Allen Probes mission, formerly the Radiation Belt Storm Probes (RBSP), was renamed soon after launch to honor the discoverer of Earth's radiation belts at the beginning of the space age, the late James Van Allen (the spacecraft themselves are still referred to as RBSP-A and RBSP-B). The Van Allen Probes are one part of NASA's Living With a Star program formulated to advance the scientific understanding of the connection between solar disturbances, the resulting heliospheric conditions, and their effects on the geospace and Earth environment.

  6. Sharp Interface Limit for a Stokes/Allen-Cahn System

    CERN Document Server

    Abels, Helmut

    2016-01-01

    We consider the sharp interface limit of a coupled Stokes/Allen-Cahn system, when a parameter $\\varepsilon>0$ that is proportional to the thickness of the diffuse interface tends to zero, in a two dimensional bounded domain. For sufficiently small times we prove convergence of the solutions of the Stokes/Allen-Cahn system to solutions of a sharp interface model, where the interface evolution is given by the mean curvature equation with an additional convection term coupled to a two-phase Stokes system with an additional contribution to the stress tensor, which describes the capillary stress. To this end we construct a suitable approximation of the solution of the Stokes/Allen-Cahn system, using three levels of the terms in the formally matched asymptotic calculations, and estimate the difference with the aid of a suitable refinement of a spectral estimate due to Chen for the linearized Allen-Cahn operator. Moreover, a careful treatment of the coupling terms is needed.

  7. An Evaluation of the Allen J. Ellender Fellowship Program.

    Science.gov (United States)

    Boesel, Justin; Gutmann, Babette

    The Allen J. Ellender Fellowship Program provides fellowships to economically disadvantaged secondary school students, secondary school teachers and administrators, and economically disadvantaged older citizens, and recent immigrants for participation in the Close Up Foundation's week-long civics education programs in Washington, D.C. The Close Up…

  8. Stark absorption spectroscopy of peridinin and allene-modified analogues

    Energy Technology Data Exchange (ETDEWEB)

    Kusumoto, Toshiyuki; Horibe, Tomoko [Department of Physics and CREST-JST, Graduated School of Science, Osaka City University, 3-3-138 Sugimoto, Sumiyoshi-ku, Osaka 558-8585 (Japan); Kajikawa, Takayuki; Hasegawa, Shinji [Department of Chemistry, School of Science and Technology, Kwansei Gakuin University, Gakuen 2-1, Sanda, Hyogo 669-1337 (Japan); Iwashita, Takashi [Suntory Institute for Bioorganic Research, Wakayamadai 1-1-1, Shimamoto, Mishimagunn, Osaka 618-8503 (Japan); Cogdell, Richard J. [Glasgow Biomedical Research Centre, University of Glasgow, 120 University Place, Glasgow G12 8QQ, Scotland (United Kingdom); Birge, Robert R.; Frank, Harry A. [Department of Chemistry, University of Connecticut, 55 North Eagleville Road, Storrs, CT 06269-3060 (United States); Katsumura, Shigeo [Department of Chemistry, School of Science and Technology, Kwansei Gakuin University, Gakuen 2-1, Sanda, Hyogo 669-1337 (Japan); Hashimoto, Hideki, E-mail: hassy@sci.osaka-cu.ac.jp [Department of Physics and CREST-JST, Graduated School of Science, Osaka City University, 3-3-138 Sugimoto, Sumiyoshi-ku, Osaka 558-8585 (Japan)

    2010-07-19

    Stark absorption spectra of peridinin (Per) and five allene-modified analogues and their angular dependence as a function of an externally applied electric field were measured in methyl methacrylate polymer at 77 K. In all cases, the energetically lowest absorption band has a significant change of static dipole-moment upon photoexcitation ({Delta}{mu}). In particular, Per has the largest value of |{Delta}{mu}|. The angles between {Delta}{mu} and the transition dipole-moment of all the analogues were determined. It is suggested that the allene group in Per plays a key role as the electron donor in the charge transfer process following photoexcitation. The results of MNDO-PSDCI calculations support this idea.

  9. Performing Allen's test in immobile hand: The Esmarch bandage method

    Directory of Open Access Journals (Sweden)

    Nebil Yesiloglu

    2015-12-01

    Full Text Available In this study, an alternative method of assessing hand vascular flow using a modification of Allen's test is presented. This technique may be helpful for patients who have immobile hands due to severe trauma, patients scheduled for free tissue transfer reconstruction, patients under general anesthesia in intensive care units that require serial arterial blood gas analyses, and emergency coronary by-pass candidates who decided to receive radial arterial grafts. [Hand Microsurg 2015; 4(3.000: 83-85

  10. Neuroinformatics of the Allen Mouse Brain Connectivity Atlas.

    Science.gov (United States)

    Kuan, Leonard; Li, Yang; Lau, Chris; Feng, David; Bernard, Amy; Sunkin, Susan M; Zeng, Hongkui; Dang, Chinh; Hawrylycz, Michael; Ng, Lydia

    2015-02-01

    The Allen Mouse Brain Connectivity Atlas is a mesoscale whole brain axonal projection atlas of the C57Bl/6J mouse brain. Anatomical trajectories throughout the brain were mapped into a common 3D space using a standardized platform to generate a comprehensive and quantitative database of inter-areal and cell-type-specific projections. This connectivity atlas has several desirable features, including brain-wide coverage, validated and versatile experimental techniques, a single standardized data format, a quantifiable and integrated neuroinformatics resource, and an open-access public online database (http://connectivity.brain-map.org/). Meaningful informatics data quantification and comparison is key to effective use and interpretation of connectome data. This relies on successful definition of a high fidelity atlas template and framework, mapping precision of raw data sets into the 3D reference framework, accurate signal detection and quantitative connection strength algorithms, and effective presentation in an integrated online application. Here we describe key informatics pipeline steps in the creation of the Allen Mouse Brain Connectivity Atlas and include basic application use cases.

  11. New Cooled Feeds for the Allen Telescope Array

    Science.gov (United States)

    Welch, Wm. J.; Fleming, Matthew; Munson, Chris; Tarter, Jill; Harp, G. R.; Spencer, Robert; Wadefalk, Niklas

    2017-04-01

    We developed a new generation of low-noise, broadband feeds for the Allen Telescope Array at the Hat Creek Observatory in Northern California. The new feeds operate over the frequency range 0.9 to 14 GHz. The noise temperatures of the feeds have been substantially improved by cooling the entire feed structure as well as the low-noise amplifiers to 70 K. To achieve this improved performance, the new feeds are mounted in glass vacuum bottles with plastic lenses that maximize the microwave transmission through the bottles. Both the cooled feeds and their low-noise amplifiers produce total system temperatures that are in the range 25–30 K from 1 GHz to 5 GHz and 40–50 K up to 12.5 GHz.

  12. (Hetero)aromatics from dienynes, enediynes and enyne-allenes.

    Science.gov (United States)

    Raviola, Carlotta; Protti, Stefano; Ravelli, Davide; Fagnoni, Maurizio

    2016-08-01

    The construction of aromatic rings has become a key objective for organic chemists. While several strategies have been developed for the functionalization of pre-formed aromatic rings, the direct construction of an aromatic core starting from polyunsaturated systems is yet a less explored field. The potential of such reactions in the formation of aromatics increased at a regular pace in the last few years. Nowadays, there are reliable and well-established procedures to prepare polyenic derivatives, such as dienynes, enediynes, enyne-allenes and hetero-analogues. This has stimulated their use in the development of innovative cycloaromatizations. Different examples have recently emerged, suggesting large potential of this strategy in the preparation of (hetero)aromatics. Accordingly, this review highlights the recent advancements in this field and describes the different conditions exploited to trigger the process, including thermal and photochemical activation, as well as the use of transition metal catalysis and the addition of electrophiles/nucleophiles or radical species.

  13. High Resolution Infrared Spectroscopy of Allene -D4.

    Science.gov (United States)

    Rousan, Khetam Ibrahim Khasawinah

    Two parallel bands of allene-d(,4), (nu)(,6) (occurring at 1920.2289 cm('-1)) and (nu)(,5) (occurring at 2228.4133 cm('-1)), and the perpendicular band, (nu)(,8) (occurring at 2321.2484 cm('-1)), were recorded by using two spectrometers under high resolution. The combination band, (nu)(,2) + (nu)(,7), was measured also; the band origin is located at 2276.0053 cm('-1), rather distant from the previously reported one at 2267.0 cm('-1). Initially, by using the 4.5 m grating spectrometer, deconvolution of the spectra achieved a resolution of (TURN)0.007 cm('-1). Although the resolution was high, a detailed analysis of the K structure could not be obtained. Other measurements were carried out by using a BOMEM Fourier transform spectrometer. Deconvolution of the spectra achieved a resolution of (TURN)0.002 cm(' -1). This made it possible to resolve and analyze these bands in detail. Successful ground state and upper state analyses were completed from this data. Combining all the three bands together, a ground state analysis has resulted in better values of. (DIAGRAM, TABLE OR GRAPHIC OMITTED...PLEASE SEE DAI). than the previously published works on the same molecule by others. A set of accurate spectroscopic constants was obtained for each band. The spectrum of the (nu)(,8) band was analyzed in detail, including the perturbations. The perturbed states for (nu)(,8) were assigned as 2(nu)(,9) + (nu)(,10), (nu)(,2) + (nu)(,9) + (nu)(,11) and 2(nu)(,3) + (nu)(,4), and the spectroscopic constants for those perturbed states were calculated.

  14. Prozaci asemel GTD ehk getting things done / David Allen ; interv. Endrik Randoja

    Index Scriptorium Estoniae

    Allen, David

    2007-01-01

    Konsultant ja koolitaja David Allen oma aja- ja enesejuhtimise meetodist GTD - getting things done. Vt. samas: Väikesed nipid, et tõhusam olla; Milles seisneb Alleni meetod; Kuidas ma oma ülesannet täitsin - logiraamat

  15. [Book review] Green engineering: environmentally conscious design, by David T. Allen and David R. Shonnard

    Science.gov (United States)

    Boustany, R.G.

    2002-01-01

    Review of: Green engineering: Environmentally conscious design / David T. Allen and David R. Shonnard / Prentice-Hall, Inc., One Lake Street, Upper Saddle River, NJ 07458. 2002. 552 pages. ISBN 0-13-061908-6.

  16. The Trail Inventory of Private John Allen National Fish Hatchery [Cycle 1

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — The purpose of this report is to create a baseline inventory of all non-motorized trails on Private John Allen National Fish Hatchery. Trails in this inventory are...

  17. SETI Observations of Exoplanets with the Allen Telescope Array

    CERN Document Server

    Harp, G R; Tarter, Jill C; Dreher, John; Jordan, Jane; Shostak, Seth; Smolek, Ken; Kilsdonk, Tom; Wimberly, M K R; Ross, John; Barott, W C; Ackermann, R F; Blair, Samantha

    2016-01-01

    We report radio SETI observations on a large number of known exoplanets and other nearby star systems using the Allen Telescope Array (ATA) for about 19000 hours from May 2009 to Dec 2015. This search focused on narrow-band radio signals from a set totaling 9293 stars, including 2015 exoplanet stars and Kepler objects of interest and an additional 65 whose planets may be close to their Habitable Zone. The ATA observations were made using multiple synthesized beams and an anticoincidence filter to help identify terrestrial radio interference. Stars were observed over frequencies from 1-9 GHz in multiple bands that avoid strong terrestrial communication frequencies. Data were processed in near-real time for narrow-band (0.7-100 Hz) continuous and pulsed signals with transmitter/receiver relative accelerations from -0.3 to 0.3 m/s^2. A total of 1.9 x 10^8 unique signals requiring immediate follow-up were detected in observations covering more than 8 x 10^9 star-MHz. We detected no persistent signals from extrate...

  18. Wave acceleration of electrons in the Van Allen radiation belts.

    Science.gov (United States)

    Horne, Richard B; Thorne, Richard M; Shprits, Yuri Y; Meredith, Nigel P; Glauert, Sarah A; Smith, Andy J; Kanekal, Shrikanth G; Baker, Daniel N; Engebretson, Mark J; Posch, Jennifer L; Spasojevic, Maria; Inan, Umran S; Pickett, Jolene S; Decreau, Pierrette M E

    2005-09-08

    The Van Allen radiation belts are two regions encircling the Earth in which energetic charged particles are trapped inside the Earth's magnetic field. Their properties vary according to solar activity and they represent a hazard to satellites and humans in space. An important challenge has been to explain how the charged particles within these belts are accelerated to very high energies of several million electron volts. Here we show, on the basis of the analysis of a rare event where the outer radiation belt was depleted and then re-formed closer to the Earth, that the long established theory of acceleration by radial diffusion is inadequate; the electrons are accelerated more effectively by electromagnetic waves at frequencies of a few kilohertz. Wave acceleration can increase the electron flux by more than three orders of magnitude over the observed timescale of one to two days, more than sufficient to explain the new radiation belt. Wave acceleration could also be important for Jupiter, Saturn and other astrophysical objects with magnetic fields.

  19. Toward an integrated route to the vernonia allenes and related sesquiterpenoids

    Directory of Open Access Journals (Sweden)

    Da Xu

    2011-07-01

    Full Text Available The synthesis of a model endocyclic allene related to the vernonia allenes is described. Fragmentation of a suitable decalin derivative gave the simplified germacrane scaffold. Computational analysis of this and related substrates provides insight into the stereoelectronic requirements of C–C fragmentation. The overall strategy to access these and other sesquiterpenes and the key steps in the present sequence are also discussed.

  20. Mathematics and Humor: John Allen Paulos and the Numeracy Crusade

    Directory of Open Access Journals (Sweden)

    Paul H. Grawe

    2015-07-01

    Full Text Available John Allen Paulos at minimum gave the Numeracy movement a name through his book Innumeracy: Mathematical Illiteracy and Its Consequences. What may not be so obvious was Paulos’ strong interest in the relationship between mathematics and mathematicians on the one hand and humor and stand-up-comedian joke structures on the other. Innumeracy itself could be seen as a typically mathematical Gotcha joke on American culture generally. In this perspective, a Minnesotan acculturated to Minnesota-Nice Humor of Self-Immolation Proclivities (SImP looks at the more raw-boned, take-no-prisoners humor style Paulos outlined in Mathematics and Humor and implemented in Innumeracy. Despite the difference in humor styles, there is much to applaud in Paulos’ analysis of the relationship between certain types of humor and professional interests of mathematicians in Mathematics and Humor. Much humor relies on the sense of incongruity which Paulos’ claims to be central to all humor and key to mathematical reductio ad absurdum. Mathematics is rightfully famous for a sense of combinatorial playfulness in its most elegant proofs, as humor often relies on clashing combinations of word play. And a great range of mathematical lore is best understood within a concept of a sudden drop from one sense of certainty to another (essentially a Gotcha on the audience. Innumeracy repeatedly exemplifies Gotchas on the great unwashed and unmathematical majority. Extensive empirical evidence over the last quarter century allows us to synthesize these Paulos observations into the idea that inculcated mathematical humor has strong propensities to complex Intellectual, Advocate, and Crusader humor forms. However, the Paulos humors do not include the Sympathetic Pain humor form, the inclusion of which may increase teaching effectiveness.

  1. Convenient synthesis of β-allenic α-difluoromethylenephosphonic acid monoesters: Potential synthons for cyclic phosphate mimics

    Institute of Scientific and Technical Information of China (English)

    Yun Lin; Jin Tao Liu

    2007-01-01

    β-Allenic α-difluoromethylenephosphonic acid monoesters were prepared under mild conditions for the first time by hydrolyzing the corresponding diethyl phosphonates in aqueous sodium hydroxide solution.

  2. Allen Brain Atlas: an integrated spatio-temporal portal for exploring the central nervous system.

    Science.gov (United States)

    Sunkin, Susan M; Ng, Lydia; Lau, Chris; Dolbeare, Tim; Gilbert, Terri L; Thompson, Carol L; Hawrylycz, Michael; Dang, Chinh

    2013-01-01

    The Allen Brain Atlas (http://www.brain-map.org) provides a unique online public resource integrating extensive gene expression data, connectivity data and neuroanatomical information with powerful search and viewing tools for the adult and developing brain in mouse, human and non-human primate. Here, we review the resources available at the Allen Brain Atlas, describing each product and data type [such as in situ hybridization (ISH) and supporting histology, microarray, RNA sequencing, reference atlases, projection mapping and magnetic resonance imaging]. In addition, standardized and unique features in the web applications are described that enable users to search and mine the various data sets. Features include both simple and sophisticated methods for gene searches, colorimetric and fluorescent ISH image viewers, graphical displays of ISH, microarray and RNA sequencing data, Brain Explorer software for 3D navigation of anatomy and gene expression, and an interactive reference atlas viewer. In addition, cross data set searches enable users to query multiple Allen Brain Atlas data sets simultaneously. All of the Allen Brain Atlas resources can be accessed through the Allen Brain Atlas data portal.

  3. Memory and Nostalgia in Woody Allens "Midnight in Paris" (Memoria y nostalgia en "Medianoche en París" de Woody Allen

    Directory of Open Access Journals (Sweden)

    Eubanks,Peter

    2014-09-01

    Full Text Available Abstract: Woody Allen´s recent "Midnight in Paris" describes a Paris that has as many identities as there are observers to ascribe them. Indeed, there is no one, true Paris that everyone objectively shares; Paris, in Allen´s film, exists only in the phenomenology of the observers perception, a perception often marred and made unreliable by an escapist need to withdraw from the present in order to take shelter in a glorified, utopian past. Allen thus criticizes the nostalgic impulse, the "Golden-Age thinking" (as it is called in the film that forces various characters simultaneously to inhabit two worlds, that of a prelapsarian past and that of the fallen present. His protagonist´s journey back and forth between the present and the idealized Roaring Twenties is everyman´s journey, the sometimes surreal voyage between reality and imagination, between the world actually inhabited and the world artificially constructed for oneself. Yet it is when Allen´s protagonist finally discovers nostalgia within his nostalgia, a longing within his longing, that he recognizes the flawed thinking behind his almost mythologized perception of the past, reflecting everyman´s realization that the past is ultimately the expression of our present needs. Resumen: Uno de los films recientes de Woody Allen, "Midnight in Paris", describe un París que tiene tantas identidades como observadores hay a quienes atribuirlos. De hecho, no hay un París auténtico que compartan todos. París, en el film de Allen, solo existe en la fenomenología de la percepción del observador, una percepción con frecuencia dañada/arruinada y realizada poco fidedigna por una necesidad escapista a retirarse del presente para refugiarse en un pasado glorificado, utópico. Así Allen critica el impulso nostálgico, la idea del "pensamiento del siglo de oro" (tal y como viene a ser llamado en el film que obliga a que varios personajes residan en dos mundos al mismo tiempo: el de un mundo

  4. Exploring the Dynamic Radio Sky with the Allen Telescope Array

    Science.gov (United States)

    Williams, Peter Kelsey George

    The revolution in digital technology that has had so many obvious effects in recent decades has not spared the field of astronomy. It has led to an enormous improvement in astronomers' ability to study the "time domain," the expected and unexpected ways in which celestial objects change on timescales ranging from milliseconds to centuries. In the field of radio astronomy a variety of advances have led to a new breed of observatories that are orders of magnitude more efficient at surveying the sky than previous facilities. These new observatories produce data at prodigous rates, however, and require sophisticated analysis to take full advantage of their capabilities. With several major facilities coming online in the next few years, there is an urgent need to prove that terabytes of data can be reliably turned into genuine astrophysical results. This dissertation develops tools and techniques for coping with this challenge and applies them to data obtained with the Allen Telescope Array (ATA), a pioneering next-generation radio observatory located in Northern California. The ATA was built from the ground up to be a fast survey instrument, incorporating a suite of the new technologies that figure prominently in the new telescopes. I develop and describe miriad-python, a framework for the rapid development of interferometric analysis software that is used in a variety of ways in my subsequent research. I also present a robust software system for executing multiple observing campaigns cooperatively ("commensally") at the ATA. Data from the ATA are difficult to analyze due to nontraditional features such as a large instantaneous field of view; continuous coverage of a large, interference-prone frequency range; and broadband, movable feeds; I describe and implement several methods for coping with these challenges. This technical work is driven by the needs of a variety of astrophysical applications. I use broadband spectra of starforming galaxies to investigate the

  5. Replacement of two amino acids of 9R-dioxygenase-allene oxide synthase of Aspergillus niger inverts the chirality of the hydroperoxide and the allene oxide.

    Science.gov (United States)

    Sooman, Linda; Wennman, Anneli; Hamberg, Mats; Hoffmann, Inga; Oliw, Ernst H

    2016-02-01

    The genome of Aspergillus niger codes for a fusion protein (EHA25900), which can be aligned with ~50% sequence identity to 9S-dioxygenase (DOX)-allene oxide synthase (AOS) of Fusarium oxysporum, homologues of the Fusarium and Colletotrichum complexes and with over 62% sequence identity to homologues of Aspergilli, including (DOX)-9R-AOS of Aspergillus terreus. The aims were to characterize the enzymatic activities of EHA25900 and to identify crucial amino acids for the stereospecificity. Recombinant EHA25900 oxidized 18:2n-6 sequentially to 9R-hydroperoxy-10(E),12(Z)-octadecadienoic acid (9R-HPODE) and to a 9R(10)-allene oxide. 9S- and 9R-DOX-AOS catalyze abstraction of the pro-R hydrogen at C-11, but the direction of oxygen insertion differs. A comparison between twelve 9-DOX domains of 9S- and 9R-DOX-AOS revealed conserved amino acid differences, which could contribute to the chirality of products. The Gly616Ile replacement of 9R-DOX-AOS (A. niger) increased the biosynthesis of 9S-HPODE and the 9S(10)-allene oxide, whereas the Phe627Leu replacement led to biosynthesis of 9S-HPODE and the 9S(10)-allene oxide as main products. The double mutant (Gly616Ile, Phe627Leu) formed over 90% of the 9S stereoisomer of HPODE. 9S-HPODE was formed by antarafacial hydrogen abstraction and oxygen insertion, i.e., the original H-abstraction was retained but the product chirality was altered. We conclude that 9R-DOX-AOS can be altered to 9S-DOX-AOS by replacement of two amino acids (Gly616Ile, Phe627Leu) in the DOX domain.

  6. The effectiveness of the Allen Carr smoking cessation training in companies tested in a quasi-experimental design

    NARCIS (Netherlands)

    Dijkstra, Arie; Zuidema, Rixt; Vos, Diederick; van Kalken, Marike

    2014-01-01

    Background: The Allen Carr training (ACt) is a popular one-session smoking cessation group training that is provided by licensed organizations that have the permission to use the Allen Carr method. However, few data are available on the effectiveness of the training. Methods: In a quasi-experimental

  7. A Critique of Mark D. Allen's "The Preservation of Verb Subcategory Knowledge in a Spoken Language Comprehension Deficit"

    Science.gov (United States)

    Kemmerer, David

    2008-01-01

    Allen [Allen, M. (2005). "The preservation of verb subcategory knowledge in a spoken language comprehension deficit." "Brain and Language, 95", 255-264.] reports a single patient, WBN, who, during spoken language comprehension, is still able to access some of the syntactic properties of verbs despite being unable to access some of their semantic…

  8. Tim Allen, one of Hollywood's top comedy actors with Rolf Landua from CERN

    CERN Document Server

    Laurent Guiraud

    2000-01-01

    Tim Allen ('Galaxy Quest', 'For Richer and Poorer', 'The Santa Clause', Voice of 'Buzz Lightyear', in Toy Story 1 and 2), visited CERN in July 2000. He has a keen interest in modern physics. In his last book "I'm not really here" he contemplates the funny and the intriguing aspects of quantum physics in his daily life.

  9. The Alchian-Allen Effect in Higher Education: Public versus Private Enrollment.

    Science.gov (United States)

    Kroncke, Charles O., Jr.; Ressler, Rand W.

    1993-01-01

    Part of cost of participating in higher education is foregone employment. An increase in unemployment rate is expected to decrease full cost of postsecondary education, causing increase in demand. This paper reexamines this expectation, in the face of the Alchian-Allen effect (changes in fixed costs), once the public/private school distinction has…

  10. Regioselective Allene Hydrosilylation Catalyzed by NHC Complexes of Nickel and Palladium

    Science.gov (United States)

    Miller, Zachary D.; Li, Wei; Belderrain, Tomás R.; Montgomery, John

    2013-01-01

    Regioselective methods for allene hydrosilylation have been developed, with regioselectivity being governed primarily by choice of metal. Alkenylsilanes are produced via nickel catalysis with larger N-heterocyclic carbene ligands, and allylsilanes are produced via palladium catalysis with smaller N-heterocyclic carbene ligands. These complementary methods allow either regioisomeric product to be obtained with exceptional regiocontrol. PMID:24079389

  11. Well-posedness for one-dimensional anisotropic Cahn-Hilliard and Allen-Cahn systems

    Directory of Open Access Journals (Sweden)

    Ahmad Makki

    2015-01-01

    Full Text Available Our aim is to prove the existence and uniqueness of solutions for one-dimensional Cahn-Hilliard and Allen-Cahn type equations based on a modification of the Ginzburg-Landau free energy proposed in [8]. In particular, the free energy contains an additional term called Willmore regularization and takes into account strong anisotropy effects.

  12. Improving Vocational Education with Mentally Retarded Persons: A Conversation with L. Allen Phelps.

    Science.gov (United States)

    Thomas, M. Angele

    1983-01-01

    Special vocational educator L. Allen Phelps identifies major issues in vocational programing for mentally retarded students (including implementing technology and expanding integration); comments on the effects of the changing federal role; notes changes in staffing patterns; cites the need for advocacy by professional associations; and suggests…

  13. A Century after Van Allen's Birth: Conclusion of Reconnaissance of Radiation Belts in the Solar System

    Science.gov (United States)

    Krimigis, S. M.

    2014-12-01

    On May 1, 1958 in the Great Hall of the US National Academy of Sciences, James A. Van Allen, having instrumented Explorer-1 and follow-on satellites with radiation detectors, announced the discovery of intense radiation at high altitudes above Earth. The press dubbed the doughnut-shaped structures "Van Allen Belts" (VAB). Soon thereafter, the search began for VAB at nearby planets. Mariner 2 flew by Venus in 1962 at a distance of 41,000 km, but no radiation was detected. The Mariner 4 mission to Mars did not observe planet-associated increase in radiation, but scaling arguments with Earth's magnetosphere yielded an upper limit to the ratio of magnetic moments of MM/ME Jupiter by Pioneers 10, 11 in 1973 and 1974, respectively, measured a plethora of energetic particles in Jupiter's magnetosphere and established the fact that their intensities were rotationally modulated. Later flybys of Jupiter and Saturn by the two Voyagers in 1979 and 1981 revealed that those magnetospheres possessed their own internal plasma source(s) and radiation belts. Subsequent discoveries of Van Allen belts at Uranus and Neptune by Voyager 2 demonstrated that VAB are the rule rather than the exception in planetary environments. We now know from the Voyagers and through Energetic Neutral Atom images from Cassini and IBEX that an immense energetic particle population surrounds the heliosphere itself. Thus, the reconnaissance of radiation belts of our solar system has been completed, some 56 years after the discovery of the Van Allen Belts at Earth.

  14. No Radio Flaring Detected from Cygnus X-3 at 3 GHz by Allen Telescope Array

    Science.gov (United States)

    Williams, P. K. G.; Bower, G. C.; Tomsick, J. A.; Bodaghee, A.; Corbet, R. H. D.

    2011-01-01

    Following the announcement of a 98 GHz flare from the microquasar Cygnus X-3 (ATel #3130), we observed it with the Allen Telescope Array (Welch et al., 2009 Proc. IEEE 97 1438 for 2.5 hours beginning at 2011 January 28.848 UT (MJD 55589.848), about 4.0 hours after the 98 GHz observations concluded.

  15. Synthesis of 2,3-disubstituted thiophens via metalated acetylenes and allenes

    NARCIS (Netherlands)

    Jong, R.L.P. de; Brandsma, L.

    1982-01-01

    2,3-Disubstituted thiophen derivatives have been obtained in reasonable yields by treating 2-alkyne- and allene derivatives with butyllithium and potassium t-butoxide in tetrahydrofuran, adding carbon disulfide to the organometallic intermediate and then successively adding t-butyl alcohol, hexameth

  16. The Vortex and the Line: Performative Gestures in Allen Ginsberg's ‘Wichita Vortex Sutra’

    DEFF Research Database (Denmark)

    Sørensen, Bent

    and their identity politics… Queering the straight lines of Modernism, Allen Ginsberg suggests in his long poem about America and the Vietnam War, ‘Wichita Vortex Sutra’, that lying media discourses and corrupt political and military statements about the necessity of participation in the war may be cancelled out...

  17. Precipitation of relativistic electrons of the Van Allen belts into the proton aurora

    Energy Technology Data Exchange (ETDEWEB)

    Jordanova, Vania K [Los Alamos National Laboratory; Miyoshi, Y [NAGOYA UNIV; Sakaguchi, K [NAGOYA UNIV; Shiokawa, K [NAGOYA UNIV; Evans, D S [SEC/NOAA; Albert, Jay [AFRL; Connors, M [UNIV OF ATHABASCA

    2008-01-01

    The Van Allen electron belts consist of two regions encircling the earth in which relativistic electrons are trapped in the earth's magnetic field. Populations of relativistic electrons in the Van Allen belts vary greatly with geomagnetic disturbance and they are a major source of damage to space vehicles. In order to know when and by how much these populations of relativistic electrons increase, it is important to elucidate not only the cause of acceleration of relativistic electrons but also the cause of their loss from the Van Allen belts. Here we show the first evidence that left-hand polarized electromagnetic ion cyclotron (EMIC) plasma waves can cause the loss of relativistic electrons into the atmosphere, on the basis of results of an excellent set of ground and satellite observations showing coincident precipitation of ions with energies of tens of keV and of relativistic electrons into an isolated proton aurora. The proton aurora was produced by precipitation of ions with energies of tens of keV due to EMIC waves near the plasma pause, which is a manifestation of wave-particle interactions. These observations clarify that ions with energies of tens of keV affect the evolution of relativistic electrons in the Van Allen belts via parasitic resonance with EMIC waves, an effect that was first theoretically predicted in the early 1970's.

  18. The Allen Telescope Array : The First Widefield, Panchromatic, Snapshot Radio Camera

    NARCIS (Netherlands)

    Leeuwen, Joeri van

    2009-01-01

    The first 42 elements of the Allen Telescope Array (ATA-42) are beginning to deliver data at the Hat Creek Radio Observatory in Northern California. Scientists and engineers are actively exploiting all of the flexibility designed into this innovative instrument for simultaneously conducting panorami

  19. Correlation between Allen cognitive level test and CANTAB in patients with Schizophrenia

    Directory of Open Access Journals (Sweden)

    Talieh Sheikh Fendereski

    2012-07-01

    Full Text Available Background and Aim: Schizophrenia is a severe psychiatric disorder and characterized by impairments in a wide range of cognitive domains. Allen Cognitive Level Screen has been used extensively by occupational therapists as a quick screening tool to derive a view of cognitive function in people with psychiatric disabilities. Cambridge Neuropsychological Test Automated Battery (CANTAB is a computerized neuropsychological assessment battery which is commonly used to assess an executive functioning. The purpose of this study was to examine the relationship between two measures of executive function used by different disciplines (Allen cognitive level test and CANTAB when assessing persons with schizophrenia. Materials and Methods: In this cross-sectional study, the relation between Allen cognitive level test`s outcome and subtests of CANTAB (SWM, SSP & IED( were investigated in 30 patients with chronic schizophrenia (Mean age= 39 , man=80%,woman=20%. Allen cognitive level test was used to measure cognitive level and Spatial Span (SSP to measure working memory capacity, Spatial Working Memory (SWM to evaluate working memory and its strategy of usage and Intra/Extra dimensional Set Shift (IED to assess attentional set shifting. All the data was analyzed by SPSS-16.Results: No Significant correlation was found between cognition levels of Allen test and SWM subtest (rS= -0/046; P=0/811, SSP (rS=0/009; P= -0/024 and IED (rS= -0/074; P=0/699.Conclusion: The findings of this study suggest that although patients with schizophrenia might have problems in cognitive component, they may show less problem in performing goal directed activities. In addition, the approaches of evaluation based on which the tests have been planned should be considered for investigating the correlation between two tests. It seems that the results of a top-down approach may be different from those of a bottom-up approach.

  20. Quantitative mid-infrared spectra of allene and propyne from room to high temperatures

    KAUST Repository

    Es-sebbar, Et-touhami

    2014-11-01

    Allene (a-C3H4; CH2CCH2) and propyne (p-C3H4; CH3C2H) have attracted much interest because of their relevance to the photochemistry in astrophysical environments as well as in combustion processes. Both allene and propyne have strong absorption in the infrared region. In the present work, infrared spectra of a-C3H4 and p-C3H4 are measured in the gas phase at temperatures ranging from 296 to 510 K. The spectra are measured over the 580-3400 cm-1 spectral region at resolutions of 0.08 and 0.25 cm-1 using Fourier Transform Infrared spectroscopy. Absolute integrated intensities of the main infrared bands are determined at room temperature and compared with values derived from literature for both molecules. Integrated band intensities are also determined as a function of temperature in various spectral regions.

  1. Electron acceleration in the heart of the Van Allen radiation belts.

    Science.gov (United States)

    Reeves, G D; Spence, H E; Henderson, M G; Morley, S K; Friedel, R H W; Funsten, H O; Baker, D N; Kanekal, S G; Blake, J B; Fennell, J F; Claudepierre, S G; Thorne, R M; Turner, D L; Kletzing, C A; Kurth, W S; Larsen, B A; Niehof, J T

    2013-08-30

    The Van Allen radiation belts contain ultrarelativistic electrons trapped in Earth's magnetic field. Since their discovery in 1958, a fundamental unanswered question has been how electrons can be accelerated to such high energies. Two classes of processes have been proposed: transport and acceleration of electrons from a source population located outside the radiation belts (radial acceleration) or acceleration of lower-energy electrons to relativistic energies in situ in the heart of the radiation belts (local acceleration). We report measurements from NASA's Van Allen Radiation Belt Storm Probes that clearly distinguish between the two types of acceleration. The observed radial profiles of phase space density are characteristic of local acceleration in the heart of the radiation belts and are inconsistent with a predominantly radial acceleration process.

  2. Automated determination of electron density from electric field measurements on the Van Allen Probes spacecraft

    Science.gov (United States)

    Zhelavskaya, Irina; Kurth, William; Spasojevic, Maria; Shprits, Yuri

    2016-07-01

    We present the Neural-network-based Upper-hybrid Resonance Determination (NURD) algorithm for automatic inference of the electron number density from plasma wave measurements made onboard NASA's Van Allen Probes mission. A feedforward neural network is developed to determine the upper hybrid resonance frequency, f_{uhr}, from electric field measurements, which is then used to calculate the electron number density. In previous missions, the plasma resonance bands were manually identified, and there have been few attempts to do robust, routine automated detections. We describe the design and implementation of the algorithm and perform an initial analysis of the resulting electron number density distribution obtained by applying NURD to 2.5 years of data collected with the EMFISIS instrumentation suite of the Van Allen Probes mission. Densities obtained by NURD are compared to those obtained by another recently developed automated technique and also to an existing empirical plasmasphere and trough density model.

  3. A critique of Mark D. Allen's "the preservation of verb subcategory knowledge in a spoken language comprehension deficit".

    Science.gov (United States)

    Kemmerer, David

    2008-07-01

    Allen [Allen, M. (2005). The preservation of verb subcategory knowledge in a spoken language comprehension deficit. Brain and Language, 95, 255-264.] reports a single patient, WBN, who, during spoken language comprehension, is still able to access some of the syntactic properties of verbs despite being unable to access some of their semantic properties. Allen claims that these findings challenge linguistic theories which assume that much of the syntactic behavior of verbs can be predicted from their meanings. I argue, however, that this conclusion is not supported by the data for two reasons: first, Allen focuses on aspects of verb syntax that are not claimed to be influenced by verb semantics; and second, he ignores aspects of verb syntax that are claimed to be influenced by verb semantics.

  4. Enantioselective and Regiodivergent Addition of Purines to Terminal Allenes: Synthesis of Abacavir.

    Science.gov (United States)

    Thieme, Niels; Breit, Bernhard

    2017-02-01

    The rhodium-catalyzed atom-economic asymmetric N-selective intermolecular addition of purine derivatives to terminal allenes is reported. Branched allylic purines were obtained in high yields, regioselectivity and outstanding enantioselectivity utilizing a Rh/Josiphos catalyst. Conversely, linear selective allylation of purines could be realized in good to excellent regio- and E/Z-selectivity with a Pd/dppf catalyst system. Furthermore, the new methodology was applied to a straightforward asymmetric synthesis of carbocyclic nucleoside abacavir.

  5. Explaining the dynamics of the ultra-relativistic third Van Allen radiation belt

    OpenAIRE

    Mann, Ian R.; Ozeke, L. G.; Murphy, Kyle R; Clauderpierre, S. G.; Turner, D. L.; Baker, D. N.; Rae, I. J.; Kale, A; Milling, David; Boyd, A. J.; Spence, H. E.; Reeves, G. D.; H. J. Singer; Dimitrakoudis, S.; Daglis, I. A.

    2016-01-01

    Since the discovery of the Van Allen radiation belts over 50 years ago, an explanation for their complete dynamics has remained elusive. Especially challenging is understanding the recently discovered ultra-relativistic third electron radiation belt. Current theory asserts that loss in the heart of the outer belt, essential to the formation of the third belt, must be controlled by high-frequency plasma wave–particle scattering into the atmosphere, via whistler mode chorus, plasmaspheric hiss,...

  6. Allen Brain Atlas-Driven Visualizations: A Web-Based Gene Expression Energy Visualization Tool

    Directory of Open Access Journals (Sweden)

    Andrew eZaldivar

    2014-05-01

    Full Text Available The Allen Brain Atlas-Driven Visualizations (ABADV is a publicly accessible web-based tool created to retrieve and visualize expression energy data from the Allen Brain Atlas (ABA across multiple genes and brain structures. Though the ABA offers their own search engine and software for researchers to view their growing collection of online public data sets, including extensive gene expression and neuroanatomical data from human and mouse brain, many of their tools limit the amount of genes and brain structures researchers can view at once. To complement their work, ABADV generates multiple pie charts, bar charts and heat maps of expression energy values for any given set of genes and brain structures. Such a suite of free and easy-to-understand visualizations allows for easy comparison of gene expression across multiple brain areas. In addition, each visualization links back to the ABA so researchers may view a summary of the experimental detail. ABADV is currently supported on modern web browsers and is compatible with expression energy data from the Allen Mouse Brain Atlas in situ hybridization data. By creating this web application, researchers can immediately obtain and survey numerous amounts of expression energy data from the ABA, which they can then use to supplement their work or perform meta-analysis. In the future, we hope to enable ABADV across multiple data resources.

  7. Nonlinear wave-particle interactions in the outer radiation belts: Van Allen Probes results

    Science.gov (United States)

    Agapitov, Oleksiy; Mozer, Forrest; Artemyev, Anton; Drake, James; Vasko, Ivan

    2016-10-01

    Huge numbers of different nonlinear structures (double layers, electron holes, non-linear whistlers, etc. referred to as Time Domain Structures - TDS) have been observed by the electric field experiment on board the Van Allen Probes. A large part of the observed non-linear structures are associated with whistler waves and some of them can be directly driven by whistlers. Observations of electron velocity distributions and chorus waves by the Van Allen Probe B provided long-lasting signatures of electron Landau resonant interactions with oblique chorus waves in the outer radiation belt. In the inhomogeneous geomagnetic field, such resonant interactions then lead to the formation of a plateau in the parallel (with respect to the geomagnetic field) velocity distribution due to trapping of electrons into the wave effective potential. The feedback from trapped particles provides steepening of parallel electric field and development of TDS seeded from initial whistler structure (well explained in terms of Particle-In-Cell model). The decoupling of the whistler wave and the nonlinear electrostatic component is shown in PIC simulation in the inhomogeneous magnetic field system and are observed by the Van Allen Probes in the radiation belts.

  8. Unravelling the Complexities of the Earth's Radiation Belts: Findings from the Van Allen Probes mission

    Science.gov (United States)

    Mauk, Barry; Fox, Nicola; Kessel, Ramona; Sibeck, David; Kanekal, Shri

    2014-05-01

    Within the first year of Van Allen Probe operations, team members made a series of highly publicized decisive discoveries concerning the structure and evolution of the Earth's radiation belts, the processes that energize particles there, and the locations where they operate. Nevertheless, much more extensive and less publicized findings from the Van Allen Probes suggest that Earth's radiation belts regions remain a highly complex and puzzling place. Although the relation between magnetic storm and radiation belt enhancements and loss has been emphasized, dynamics during non-storm periods has occasionally been shown to be dramatic. While emphasis has been placed on new findings regarding local non-adiabatic energization mechanisms, adiabatic mechanisms have also been shown to be important. Furthermore, the interplay between, and relative importance of, these and other energization processes remain uncertain. The role of seed populations has been highlighted, with some studies pointing to localized mechanisms and others pointing to the role of substorms in transporting and injecting such populations. Here we review some of the less publicized findings and future objectives of the Van Allen Probes mission to get a broader and in-depth view of present understanding of Earth's inner magnetosphere.

  9. [A study on Horace N. Allen's medicine and recognition of Korean body].

    Science.gov (United States)

    Lee, Young Ah

    2011-12-31

    Je Jung Won was the first modern-style Government hospital built by the Korean King Ko-Jong in April 1885, and it was the medical missionary Horace Newton Allen(1858~1932) who made one of the greatest contributions to the establishment of the hospital. Allen was an American missionary. He graduated from Ohio Wesleyan University with a degree in theology in 1881, and completed one-yearcourse at Miami Medical College. In Korea and America he worked as a physician, a missionary, an American diplomatic minister to Korea and a Korean minister's secretary to America. While acting as a mediator between Korea and America, he knew and recorded the domestic and foreign situation of Korea during Gaehwagi(the civilized and enlightened age). Thus to study him is to understand Korea's Gaehwagi as well as to research American medical missionaries. During his stay in Korea(1884~1905), Allen steadily wrote diaries and letters about Korean politics, diplomacy, society, culture, and medicine. Thus his public/private record through diaries and letters(the quantity of these materials amounts to several thousands) supplements the Korean early modern era's historical record. However, until now these materials have received little scholarly attention from researchers except for a few historians of missionary work between Korea and America, or of Korean modern medicine. I intended to use these materials to suggest a new perspective on the study of Korean Gaehwagi. Allen, along with John W. Heron, who came to Seoul on June 21st 1885, treated about 10,460 Korean patients in the first year of the opening of JeJungWon. They made "the first annual report of the Korean Government Hospital". This report explained how Allen and Heron regarded and treated Korean patients. Allen's diaries, letters and other writings offer a realistic view of how the western people actually recognized the Korean people at that time. As a western doctor, Allen had an ambivalent attitude toward Korean medical concepts

  10. Rate Coefficients of the Reaction of OH with Allene and Propyne at High Temperatures

    KAUST Repository

    Es-Sebbar, Et Touhami

    2016-09-28

    Allene (H2C═C═CH2; a-C3H4) and propyne (CH3C≡CH; p-C3H4) are important species in various chemical environments. In combustion processes, the reactions of hydroxyl radicals with a-C3H4 and p-C3H4 are critical in the overall fuel oxidation system. In this work, rate coefficients of OH radicals with allene (OH + H2C═C═CH2 → products) and propyne (OH + CH3C≡CH → products) were measured behind reflected shock waves over the temperature range of 843–1352 K and pressures near 1.5 atm. Hydroxyl radicals were generated by rapid thermal decomposition of tert-butyl hydroperoxide ((CH3)3–CO–OH), and monitored by narrow line width laser absorption of the well-characterized R1(5) electronic transition of the OH A–X (0,0) electronic system near 306.7 nm. Results show that allene reacts faster with OH radicals than propyne over the temperature range of this study. Measured rate coefficients can be expressed in Arrhenius form as follows: kallene+OH(T) = 8.51(±0.03) × 10–22T3.05 exp(2215(±3)/T), T = 843–1352 K; kpropyne+OH(T) = 1.30(±0.07) × 10–21T3.01 exp(1140(±6)/T), T = 846–1335 K.

  11. The Allen Telescope Array: The First Widefield, Panchromatic, Snapshot Radio Camera for Radio Astronomy and SETI

    CERN Document Server

    Welch, Jack; Blitz, Leo; Bock, Douglas; Bower, Geoffrey C; Cheng, Calvin; Croft, Steve; Dexter, Matt; Engargiola, Greg; Fields, Ed; Forster, James; Gutierrez-Kraybill, Colby; Heiles, Carl; Helfer, Tamara; Jorgensen, Susanne; Keating, Garrett; Lugten, John; MacMahon, Dave; Milgrome, Oren; Thornton, Douglas; Urry, Lynn; van Leeuwen, Joeri; Werthimer, Dan; Williams, Peter H; Tarter, Melvin Wright Jill; Ackermann, Robert; Atkinson, Shannon; Backus, Peter; Barott, William; Bradford, Tucker; Davis, Michael; DeBoer, Dave; Dreher, John; Harp, Gerry; Jordan, Jane; Kilsdonk, Tom; Pierson, Tom; Randall, Karen; Ross, John; Fleming, Seth Shostak Matt; Cork, Chris; Wadefalk, Artyom Vitouchkine Niklas; Weinreb, Sander

    2009-01-01

    The first 42 elements of the Allen Telescope Array (ATA-42) are beginning to deliver data at the Hat Creek Radio Observatory in Northern California. Scientists and engineers are actively exploiting all of the flexibility designed into this innovative instrument for simultaneously conducting surveys of the astrophysical sky and conducting searches for distant technological civilizations. This paper summarizes the design elements of the ATA, the cost savings made possible by the use of COTS components, and the cost/performance trades that eventually enabled this first snapshot radio camera. The fundamental scientific program of this new telescope is varied and exciting; some of the first astronomical results will be discussed.

  12. Cognition About the Creative Process – Interview With Dr Andrew P. Allen

    Science.gov (United States)

    Allen, Andrew P.; Loughnane, Lynda

    2016-01-01

    What is the relationship between the creative process and cognition and perception? Lynda Loughnane, a master’s student in Art and Process in Crawford College of Art and Design, Cork, Ireland interviewed Dr Andrew P. Allen about the subject. Areas covered include mindfulness, Type 1 and Type 2 thinking, stage theories of creativity, engagement with the art process and the artwork, phenomenology and consciousness with and without self report. The interview was constructed to cover a wide range of subject matter, so as to gather as much information as possible in layman's language about the cognitive process in relation to creativity and interaction with art. PMID:27872674

  13. Charisma and Counterculture: Allen Ginsberg as a Prophet for a New Generation

    OpenAIRE

    Yaakov Ariel

    2013-01-01

    The cultural role of Allen Ginsberg does not fit a typical Weberian model of charisma. The avant-garde poet was an outstanding personality and possessed an unusual ability to affect people. He played a vital role in expanding the boundaries of personal freedom in America of the 1950s–1990s, blazing new paths for spiritual, communal and artistic expression. Serving as a father figure for the counterculture—a symbol of an alternative set of cultural norms, lifestyles and literary forms—Ginsberg...

  14. Cognition About the Creative Process – Interview With Dr Andrew P. Allen

    Directory of Open Access Journals (Sweden)

    Andrew P. Allen

    2016-11-01

    Full Text Available What is the relationship between the creative process and cognition and perception? Lynda Loughnane, a master’s student in Art and Process in Crawford College of Art and Design, Cork, Ireland interviewed Dr Andrew P. Allen about the subject. Areas covered include mindfulness, Type 1 and Type 2 thinking, stage theories of creativity, engagement with the art process and the artwork, phenomenology and consciousness with and without self report. The interview was constructed to cover a wide range of subject matter, so as to gather as much information as possible in layman's language about the cognitive process in relation to creativity and interaction with art.

  15. Allen Terhaar: Future Development of Cotton for the 21 st Century

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    The 2011 China International Cotton Conference, organized by China Cotton Association (CCA), Research Centre for Rural Economy (RCRE) of the Ministry of Agriculture (MOA) as well as the China National Cotton Exchange (CNCE), took place June 15-16 in the beautiful coastal city of Dalian this year. Allen Terhaar, Executive President of Cotton Council International (CCI), delivered a speech with the name of Cotton in the 21st Century: Sustaining Our Industry's Future. In the following part, let's share his opinions and suggestions.

  16. Accounting for Diradical Character through DFT. The Case of Vinyl Allene Oxide Rearrangement.

    Science.gov (United States)

    López, Roberto Villar; Faza, Olalla Nieto; López, Carlos Silva

    2015-11-01

    The transformation of vinyl allene oxides into cyclopentenones is key to the biosynthesis of a number of hormone-like molecules in plants. Two competitive paths are generally accepted for this transformation: a concerted SN2-like mechanism and a stepwise path with a diradical oxyallyl intermediate. Recently, a new stepwise closed-shell path has been proposed that circumvents the key oxyallyl intermediate. In this work, we conduct a thorough computational investigation, including dynamic effects, to identify the most likely mechanism for this transformation.

  17. Evaluation of effects of groundwater withdrawals at the proposed Allen combined-cycle combustion turbine plant, Shelby County, Tennessee

    Science.gov (United States)

    Haugh, Connor J.

    2016-08-10

    The Mississippi Embayment Regional Aquifer Study groundwater-flow model was used to simulate the potential effects of future groundwater withdrawals at the proposed Allen combined-cycle combustion turbine plant in Shelby County, Tennessee. The scenario used in the simulation consisted of a 30-year average withdrawal period followed by a 30-day maximum withdrawal period. Effects of withdrawals at the Allen plant site on the Mississippi embayment aquifer system were evaluated by comparing the difference in simulated water levels in the aquifers at the end of the 30-year average withdrawal period and at the end of the scenario to a base case without the Allen combined-cycle combustion turbine plant withdrawals. Simulated potentiometric surface declines in the Memphis aquifer at the Allen plant site were about 7 feet at the end of the 30-year average withdrawal period and 11 feet at the end of the scenario. The affected area of the Memphis aquifer at the Allen plant site as delineated by the 4-foot potentiometric surface-decline contour was 2,590 acres at the end of the 30-year average withdrawal period and 11,380 acres at the end of the scenario. Simulated declines in the underlying Fort Pillow aquifer and overlying shallow aquifer were both less than 1 foot at the end of the 30-year average withdrawal period and the end of the scenario.

  18. Book review: The man who saved the whooping crane: The Robert Porter Allen story

    Science.gov (United States)

    King, Sammy L.

    2013-01-01

    Kathleen Kaska has done a remarkable job of capturing the life of Robert Porter Allen, truly one of the premier biologist/conservationists of the twentieth century. Allen, born in 1905, grew up reading outdoor adventure books and playing in the woods of northern Pennsylvania with his brother. At a young age, he was encouraged to join the Junior Audubon club and his passion for ornithology soon crystallized. He attended Lafayette College to study ornithology, but he was disinterested in academics and fared poorly. He dropped out after two years and joined the Merchant Marines. Not an auspicious beginning for such a highly respected scientist and conservationist! Soon, however, he landed a librarian job with Audubon and his diligence, acumen, and communication skills allowed him to take more and more responsibilities. He became one of the youngest Audubon sanctuary directors ever appointed, and he was also able to secure a fellowship through Cornell to work on Roseate Spoonbills (Platalea ajaja). Audubon later appointed him to lead their Whooping Crane (Grus americana) studies.

  19. Automatic registration of imaging mass spectrometry data to the Allen Brain Atlas transcriptome

    Science.gov (United States)

    Abdelmoula, Walid M.; Carreira, Ricardo J.; Shyti, Reinald; Balluff, Benjamin; Tolner, Else; van den Maagdenberg, Arn M. J. M.; Lelieveldt, B. P. F.; McDonnell, Liam; Dijkstra, Jouke

    2014-03-01

    Imaging Mass Spectrometry (IMS) is an emerging molecular imaging technology that provides spatially resolved information on biomolecular structures; each image pixel effectively represents a molecular mass spectrum. By combining the histological images and IMS-images, neuroanatomical structures can be distinguished based on their biomolecular features as opposed to morphological features. The combination of IMS data with spatially resolved gene expression maps of the mouse brain, as provided by the Allen Mouse Brain atlas, would enable comparative studies of spatial metabolic and gene expression patterns in life-sciences research and biomarker discovery. As such, it would be highly desirable to spatially register IMS slices to the Allen Brain Atlas (ABA). In this paper, we propose a multi-step automatic registration pipeline to register ABA histology to IMS- images. Key novelty of the method is the selection of the best reference section from the ABA, based on pre-processed histology sections. First, we extracted a hippocampus-specific geometrical feature from the given experimental histological section to initially localize it among the ABA sections. Then, feature-based linear registration is applied to the initially localized section and its two neighbors in the ABA to select the most similar reference section. A non-rigid registration yields a one-to-one mapping of the experimental IMS slice to the ABA. The pipeline was applied on 6 coronal sections from two mouse brains, showing high anatomical correspondence, demonstrating the feasibility of complementing biomolecule distributions from individual mice with the genome-wide ABA transcriptome.

  20. Generation and effects of EMIC waves observed by the Van Allen Probes on 18 March 2013

    Science.gov (United States)

    Zhang, J.; Saikin, A.; Gamayunov, K. V.; Spence, H. E.; Larsen, B.; Geoffrey, R.; Smith, C. W.; Torbert, R. B.; Kurth, W. S.; Kletzing, C.

    2015-12-01

    Electromagnetic ion cyclotron (EMIC) waves play a crucial role in particle dynamics in the Earth's magnetosphere. The free energy for EMIC wave generation is usually provided by the temperature anisotropy of the energetic ring current ions. EMIC waves can in turn cause particle energization and losses through resonant wave-particle interactions. Using measurements from the Van Allen Probes, we perform a case study of EMIC waves and associated plasma conditions observed on 18 March 2013. From 0204 to 0211 UT, the Van Allen Probe-B detected He+-band EMIC wave activity in the post-midnight sector (MLT=4.6-4.9) at very low L-shells (L=2.6-2.9). The event occurred right outside the inward-pushed plasmapause in the early recovery phase of an intense geomagnetic storm - min. Dst = -132 nT at 2100 UT on 17 March 2013. During this event, the fluxes of energetic (> 1 keV), anisotropic O+ dominate both the H+ and He+ fluxes in this energy range. Meanwhile, O+ fluxes at low energies (coefficient (Dαα) of the EMIC wave packets by using nominal ion composition, derived total ion density from the frequencies of upper hybrid resonance, and measured ambient and wave magnetic field. EMIC wave growth rates are also calculated to evaluate the role of loss-cone distributed ring current ions in the EMIC wave generation.

  1. The effect of Hurricane Allen on the Bellairs fringing reef, Barbados

    Science.gov (United States)

    Mah, Anmarie J.; Stearn, Colin W.

    1986-01-01

    On August 4, 1980 Hurricane Allen damaged the northern fringing reef located just offshore from the Bellairs Research Institute of McGill University on the west coast of Barbados. During the summer and one winter month of 1981 a resurvey of the reef was done and the results were compared with a similar survey made in 1974. On a reefal scale the changes in the proportion of substrates before and after Hurricane Allen were statistically significant for all substrates and species with the exception of Millepora spp. Among the corals, Porites porites has been most affected by the catastrophe: its coverage was reduced by 96%. The other corals ( Siderastrea sidera, Porites astreoides, Montastrea annularis, and Agaricia agaricites) were reduced by 75 to 25%. Onshore transport is suggested by the high abundance of Acropora cervicornis (20%) and Madracis mirabilis (30%) in the rubble on the fringing reef (the former only grows seaward of the reef). Offshore transport is suggested by the relatively poor representation of Porites porites (32%) in the rubble. Shannon-Weaver diversity indices of the corals dropped from 1.61 to 1.26. The changes in diversity are best explained by the intermediate disturbance hypothesis.

  2. Genetic diversity and structure in the Endangered Allen Cays Rock Iguana, Cyclura cychlura inornata

    Directory of Open Access Journals (Sweden)

    Andrea C. Aplasca

    2016-03-01

    Full Text Available The Endangered Allen Cays Rock Iguana (Cyclura cychlura inornata is endemic to the Allen Cays, a tiny cluster of islands in the Bahamas. Naturally occurring populations exist on only two cays (<4 ha each. However, populations of unknown origin were recently discovered on four additional cays. To investigate patterns of genetic variation among these populations, we analyzed nuclear and mitochondrial markers for 268 individuals. Analysis of three mitochondrial gene regions (2,328 bp and data for eight nuclear microsatellite loci indicated low genetic diversity overall. Estimates of effective population sizes based on multilocus genotypes were also extremely low. Despite low diversity, significant population structuring and variation in genetic diversity measures were detected among cays. Genetic data confirm the source population for an experimentally translocated population while raising concerns regarding other, unauthorized, translocations. Reduced heterozygosity is consistent with a documented historical population decline due to overharvest. This study provides the first range-wide genetic analysis of this subspecies. We suggest strategies to maximize genetic diversity during ongoing recovery including additional translocations to establish assurance populations and additional protective measures for the two remaining natural populations.

  3. Rich methane premixed laminar flames doped by light unsaturated hydrocarbons - Part I : allene and propyne

    CERN Document Server

    Gueniche, Hadj-Ali; Dayma, Guillaume; Fournet, Ren{é}; Battin-Leclerc, Fr{é}d{é}rique

    2006-01-01

    The structure of three laminar premixed rich flames has been investigated: a pure methane flame and two methane flames doped by allene and propyne, respectively. The gases of the three flames contain 20.9% (molar) of methane and 33.4% of oxygen, corresponding to an equivalence ratio of 1.25 for the pure methane flame. In both doped flames, 2.49% of C3H4 was added, corresponding to a ratio C3H4/CH4 of 12% and an equivalence ratio of 1.55. The three flames have been stabilized on a burner at a pressure of 6.7 kPa using argon as dilutant, with a gas velocity at the burner of 36 cm/s at 333 K. The concentration profiles of stable species were measured by gas chromatography after sampling with a quartz microprobe. Quantified species included carbon monoxide and dioxide, methane, oxygen, hydrogen, ethane, ethylene, acetylene, propyne, allene, propene, propane, 1,2-butadiene, 1,3-butadiene, 1-butene, isobutene, 1-butyne, vinylacetylene, and benzene. The temperature was measured using a PtRh (6%)-PtRh (30%) thermocou...

  4. An impenetrable barrier to ultrarelativistic electrons in the Van Allen radiation belts.

    Science.gov (United States)

    Baker, D N; Jaynes, A N; Hoxie, V C; Thorne, R M; Foster, J C; Li, X; Fennell, J F; Wygant, J R; Kanekal, S G; Erickson, P J; Kurth, W; Li, W; Ma, Q; Schiller, Q; Blum, L; Malaspina, D M; Gerrard, A; Lanzerotti, L J

    2014-11-27

    Early observations indicated that the Earth's Van Allen radiation belts could be separated into an inner zone dominated by high-energy protons and an outer zone dominated by high-energy electrons. Subsequent studies showed that electrons of moderate energy (less than about one megaelectronvolt) often populate both zones, with a deep 'slot' region largely devoid of particles between them. There is a region of dense cold plasma around the Earth known as the plasmasphere, the outer boundary of which is called the plasmapause. The two-belt radiation structure was explained as arising from strong electron interactions with plasmaspheric hiss just inside the plasmapause boundary, with the inner edge of the outer radiation zone corresponding to the minimum plasmapause location. Recent observations have revealed unexpected radiation belt morphology, especially at ultrarelativistic kinetic energies (more than five megaelectronvolts). Here we analyse an extended data set that reveals an exceedingly sharp inner boundary for the ultrarelativistic electrons. Additional, concurrently measured data reveal that this barrier to inward electron radial transport does not arise because of a physical boundary within the Earth's intrinsic magnetic field, and that inward radial diffusion is unlikely to be inhibited by scattering by electromagnetic transmitter wave fields. Rather, we suggest that exceptionally slow natural inward radial diffusion combined with weak, but persistent, wave-particle pitch angle scattering deep inside the Earth's plasmasphere can combine to create an almost impenetrable barrier through which the most energetic Van Allen belt electrons cannot migrate.

  5. Observations of Quasi-Periodic Whistler Mode Waves by the Van Allen Probes

    Science.gov (United States)

    Hospodarsky, George; Wilkinson, Darrelle; Kurth, William; Kletzing, Craig; Santolik, Ondrej

    2016-10-01

    Observed in Earth's inner magnetosphere, quasi-periodic whistler mode emissions (QP) are electromagnetic waves in the frequency range from a few hundred Hz to a few kHz that exhibit a periodic modulation (typically a few minutes) of their wave intensity. These waves were first detected at high latitude ground stations, but more recently have been observed by a number of spacecraft, including the twin Van Allen Probes. The Electric and Magnetic Field Instrument Suite and Integrated Science (EMFISIS) instrument simultaneously measures the vector wave magnetic field and electric field, allowing wave propagation parameters, such as wave normal angle and Poynting vector, to be obtained. Almost four years of Van Allen Probes data have been examined and a statistical survey of the occurrence and properties of the QP emissions has been performed. The QP emissions were found to have periods ranging from 1 to 16 minutes with events lasting from less than 1 hour up to 6 hours. Some events were detected on successive orbits and a number of events were simultaneously detected by both spacecraft, even during large spacecraft separations, providing an opportunity to investigate the source and propagation properties of these waves.

  6. Cross-scale observations of the 2015 St. Patrick's day storm: THEMIS, Van Allen Probes, and TWINS

    Science.gov (United States)

    Goldstein, J.; Angelopoulos, V.; De Pascuale, S.; Funsten, H. O.; Kurth, W. S.; LLera, K.; McComas, D. J.; Perez, J. D.; Reeves, G. D.; Spence, H. E.; Thaller, S. A.; Valek, P. W.; Wygant, J. R.

    2017-01-01

    We present cross-scale magnetospheric observations of the 17 March 2015 (St. Patrick's Day) storm, by Time History of Events and Macroscale Interactions during Substorms (THEMIS), Van Allen Probes (Radiation Belt Storm Probes), and Two Wide-angle Imaging Neutral-atom Spectrometers (TWINS), plus upstream ACE/Wind solar wind data. THEMIS crossed the bow shock or magnetopause 22 times and observed the magnetospheric compression that initiated the storm. Empirical models reproduce these boundary locations within 0.7 RE. Van Allen Probes crossed the plasmapause 13 times; test particle simulations reproduce these encounters within 0.5 RE. Before the storm, Van Allen Probes measured quiet double-nose proton spectra in the region of corotating cold plasma. About 15 min after a 0605 UT dayside southward turning, Van Allen Probes captured the onset of inner magnetospheric convection, as a density decrease at the moving corotation-convection boundary (CCB) and a steep increase in ring current (RC) proton flux. During the first several hours of the storm, Van Allen Probes measured highly dynamic ion signatures (numerous injections and multiple spectral peaks). Sustained convection after ˜1200 UT initiated a major buildup of the midnight-sector ring current (measured by RBSP A), with much weaker duskside fluxes (measured by RBSP B, THEMIS a and THEMIS d). A close conjunction of THEMIS d, RBSP A, and TWINS 1 at 1631 UT shows good three-way agreement in the shapes of two-peak spectra from the center of the partial RC. A midstorm injection, observed by Van Allen Probes and TWINS at 1740 UT, brought in fresh ions with lower average energies (leading to globally less energetic spectra in precipitating ions) but increased the total pressure. The cross-scale measurements of 17 March 2015 contain significant spatial, spectral, and temporal structure.

  7. Crystallization and Preliminary X-ray Analysis of Allene Oxide Synthase, Cytochrome P450 CYP74A2, from Parthenium argentatum

    Science.gov (United States)

    Oxylipins are oxygenated derivatives of fatty acids and pivotal signaling molecules in plants and animals. Allene oxide synthase (AOS) is a key cytochrome P450 CYP74 enzyme involved in the biosynthesis of plant oxylipin jasmonates to convert 13(S)-hydroperoxide to allene oxide. Guayule (Parthenium a...

  8. Comparison of species-resolved energy spectra from ACE EPAM and Van Allen Probes RBSPICE

    Science.gov (United States)

    Patterson, J.; Manweiler, J. W.; Armstrong, T. P.; Lanzerotti, L. J.; Gerrard, A. J.; Gkioulidou, M.

    2013-12-01

    We present a comparison between energy spectra measured by the Advanced Composition Explorer (ACE) Electron Proton Alpha Monitor (EPAM) instrument and the Van Allen Probe Ion Composition Experiment (RBSPICE) for two significant and distinct events in early 2013. The first is an impulsive solar particle event on March 17th. While intense, this event presented no significant surprises in terms of its composition or anisotropy characteristics, thus providing a good baseline for response of the trapped radiation belts as observed by the Van Allen Probes. The second solar event occurred late May 22nd and early May 23rd. This event has a much greater concentration of medium and heavy ions than the St. Patrick's Day event, as well as having very peculiar energy spectra with evidence of two distinct populations. During the St. Patrick's Day Event, the energy spectra for helium, carbon, oxygen, neon, silicon, and iron all show the same spectral power law slope -3.1. The event shows strong anisotropy with intensities differing by a factor of four for both protons and Z>1 ions. The late May event also has strong anisotropy, and in the same directions as the St. Patrick's Day Event, but with very different composition and energy spectra. The spectra are much harder with power law spectral slopes of -0.5. Additionally, there is a significant spectral bump at 3 MeV/nuc for helium that is not present in the spectra of the heavier ions. The intensities of the heavier ions, however, show an increase that is an order of magnitude greater than the increase seen for helium. The March 17 RBSPICE observations show multiple injection events lasting for less than an hour each during the Van Allen Probes B apogees. These injections are seen in protons as well as Helium and only somewhat observed in Oxygen. Spectral slopes for the observations range from approximately -5 during quiet times to double peaked events with a spectral slope of approximately -2 at the beginning of the injection

  9. Estudo da resistência do tendão do supra-espinal com pontos simples, duplos e Mason Allen Study on the resistance of the supraspinous tendon using simple, matress and mason allen stitches

    Directory of Open Access Journals (Sweden)

    Roberto Yukio Ikemoto

    2010-01-01

    Full Text Available OBJETIVO: O objetivo do trabalho foi comparar a resistência entre os pontos simples, duplo e Mason-Allen modificado, utilizados para o reparo do manguito rotador, e verificar se há diferença significativa que justifique a utilização do ponto do tipo Mason-Allen modificado ao invés dos pontos simples ou duplo. MÉTODO: Retiramos tendões do músculo supra-espinal de 15 cadáveres humanos frescos (30 ombros, com a média de idade de 45 anos. Os testes foram realizados na máquina universal de ensaio mecânico Kratos® 500/2000 e os resultados submetidos aos testes estatísticos de t-student, análise de variância (ANOVA, comparação múltipla de Bonferroni e calculadas as correlações de Pearson. Os testes foram realizados ao nível de significância de 5%. RESULTADOS: Não houve diferença significativa com relação à idade, ao tamanho das amostras e deslocamento do tendão. A resistência variou com média de 127,50 N com o ponto simples, 163,95 N com o duplo e com o ponto de Mason-Allen modificado esta foi de 198,45 N. CONCLUSÃO: não existe diferença da resistência no tendão quanto à falha na interface sutura - tendão comparando-se o ponto duplo com o Mason-Allen modificado e os pontos simples e duplo, porém há diferença quando comparados os pontos simples e Mason-Allen modificado.OBJECTIVE: The purpose of this study was to compare the rotator cuff tendon resistance at the interface tendon-suture using three different sorts of stitches (simple, mattress and modified Mason-Allen. METHODS: To do this, 30 rotator cuffs were totally dissected from 15 specimens, which were 45 years old on average. The tests were done using a Kratos® 500/2000 machine and the statistical analyses applied were the Student t-test, ANOVA test, Multiple Bonferroni Comparison, and Pearson's correlation coefficients; all the analyses used a significance level of 5%. RESULTS: No significant difference was observed regarding the age, sample sizes and

  10. An allene-doped liquid argon ionization chamber for Ar and Ca ions at around 100 MeV/n

    CERN Document Server

    Yunoki, A; Fukuda, N; Kase, M; Kato, T; Kikuchi, J; Masuda, K; Niimura, M; Okada, H; Ozaki, K; Piao, Y; Shibamura, E; Tanaka, M; Tanihata, I; Terasawa, K

    1999-01-01

    An allene-doped liquid argon ionization chamber with 48 mmx48 mmx40 mm sensitive volume has been constructed for precise energy measurement of heavy ions at around 100 MeV/n. An energy resolution of 0.6%-0.7% (FWHM) was achieved for Ca and Ar ions both at 78 MeV/n. (author)

  11. Barbara Allen, Daniel Breslau organize 2009 annual meeting of Society for Social Studies of Science in Washington, D.C.

    OpenAIRE

    2009-01-01

    Organizing a conference with more than 1,000 attendees from around the globe is no small task. Just ask Barbara Allen, associate professor and director, Science and Technology Studies, National Capital Region; and her Blacksburg colleague, Daniel Breslau, associate professor, Science and Technology Studies, who co-chaired the 2009 annual meeting of the Society for Social Studies of Science (4S).

  12. John W. Allen 《I like to be associated with winners and China tops the list》

    Institute of Scientific and Technical Information of China (English)

    JESSY ZHANG

    2006-01-01

    @@ John Allen defines himself as a global entrepreneur, active in private and public areas. As Chairman and CEO of Greater China Corporation (GCC), a public company based in New York City,he is involved in acquiring and building businesses relating to China's economic growth.

  13. Electron dropout echoes induced by interplanetary shock: Van Allen Probes observations

    Science.gov (United States)

    Hao, Y. X.; Zong, Q.-G.; Zhou, X.-Z.; Fu, S. Y.; Rankin, R.; Yuan, C.-J.; Lui, A. T. Y.; Spence, H. E.; Blake, J. B.; Baker, D. N.; Reeves, G. D.

    2016-06-01

    On 23 November 2012, a sudden dropout of the relativistic electron flux was observed after an interplanetary shock arrival. The dropout peaks at ˜1 MeV and more than 80% of the electrons disappeared from the drift shell. Van Allen twin Probes observed a sharp electron flux dropout with clear energy dispersion signals. The repeating flux dropout and recovery signatures, or "dropout echoes", constitute a new phenomenon referred to as a "drifting electron dropout" with a limited initial spatial range. The azimuthal range of the dropout is estimated to be on the duskside, from ˜1300 to 0100 LT. We conclude that the shock-induced electron dropout is not caused by the magnetopause shadowing. The dropout and consequent echoes suggest that the radial migration of relativistic electrons is induced by the strong dusk-dawn asymmetric interplanetary shock compression on the magnetosphere.

  14. Convection Electric Field Observations by THEMIS and the Van Allen Probes

    Science.gov (United States)

    Califf, S.; Li, X.; Bonnell, J. W.; Wygant, J. R.; Malaspina, D.; Hartinger, M.; Thaller, S. A.

    2013-12-01

    We present direct electric field measurements made by THEMIS and the Van Allen Probes in the inner magnetosphere, focusing on the large-scale, near-DC convection electric field. The convection electric field drives plasma Earthward from the tail into the inner magnetosphere, playing a critical role in forming the ring current. Although it is normally shielded deep inside the magnetosphere, during storm times this large-scale electric field can penetrate to low L values (L mechanism for ~100 keV electron injection into the slot region and inner radiation belt. The relationship of the convection electric field with the plasmasphere is also important for understanding the dynamic outer radiation belt, as the plasmapause boundary has been strongly correlated with the dynamic variation of the outer radiation belt electrons.

  15. Five Years of SETI with the Allen Telescope Array: Lessons Learned

    Science.gov (United States)

    Harp, Gerald

    2016-01-01

    We discuss recent observations at the Allen Telescope Array (ATA) supporting a wide ranging Search for Extraterrestrial Intelligence (SETI). The ATA supports observations over the frequency range 1-10 GHz with three simultaneous phased array beams used in an anticoincidence detector for false positive rejection. Here we summarize observational results over the years 2011-2015 covering multiple campaigns of exoplanet stars, the galactic plane, infrared excess targets, etc. Approximately 2 x 108 signals were identified and classified over more than 5000 hours of observation. From these results we consider various approaches to the rapid identification of human generated interference in the process of the search for a signal with origins outside the radius of the Moon's orbit. We conclude that the multi-beam technique is superb tool for answering the very difficult question of the direction of origin of signals. Data-based simulations of future instruments with more than 3 beams are compared.

  16. Explaining occurrences of auroral kilometric radiation in Van Allen radiation belts

    Science.gov (United States)

    Xiao, Fuliang; Zhou, Qinghua; Su, Zhenpeng; He, Zhaoguo; Yang, Chang; Liu, Si; He, Yihua; Gao, Zhonglei

    2016-12-01

    Auroral kilometric radiation (AKR) is a strong terrestrial radio emission and dominates at higher latitudes because of reflection in vicinities of the source cavity and plasmapause. Recently, Van Allen Probes have observed occurrences of AKR emission in the equatorial region of Earth's radiation belts but its origin still remains an open question. Equatorial AKR can produce efficient acceleration of radiation belt electrons and is a risk to space weather. Here we report high-resolution observations during two small storm periods 4-6 April and 18-20 May 2013 and show, using a 3-D ray tracing simulation, that AKR can propagate downward all the way into the equatorial plane in the radiation belts under appropriate conditions. The simulated results can successfully explain the observed AKR's spatial distribution and frequency range, and the current results have a wide application to all other magnetized astrophysical objects in the universe.

  17. Van Allen Probes observations of oxygen cyclotron harmonic waves in the inner magnetosphere

    Science.gov (United States)

    Usanova, M. E.; Malaspina, D. M.; Jaynes, A. N.; Bruder, R. J.; Mann, I. R.; Wygant, J. R.; Ergun, R. E.

    2016-09-01

    Waves with frequencies in the vicinity of the oxygen cyclotron frequency and its harmonics have been regularly observed on the Van Allen Probes satellites during geomagnetic storms. We focus on properties of these waves and present events from the main phase of two storms on 1 November 2012 and 17 March 2013 and associated dropouts of a few MeV electron fluxes. They are electromagnetic, in the frequency range ~0.5 to several Hz, and amplitude ~0.1 to a few nT in magnetic and ~0.1 to a few mV/m in electric field, with both the wave velocity and the Poynting vector directed almost parallel to the background magnetic field. These properties are very similar to those of electromagnetic ion cyclotron waves, which are believed to contribute to loss of ring current ions and radiation belt electrons and therefore can be also important for inner magnetosphere dynamics.

  18. Rir Por Quê? ironia e pensamento, vida e morte em Kierkegaard e Woody Allen

    Directory of Open Access Journals (Sweden)

    ACSELRAD, Marcio

    2009-06-01

    Full Text Available The studies on humor and laughter have been growing in the past few years. Adored and divinized in ancient Greece, humor was later banished from the field of thought in Greece and, later on, with a modernity so serious and scientific. Nowadays it is being revisited strongly. The goal of the present article is to try and understand the phenomenon in recent times, mainly from the end of the nineteen century on, more specifically after Nietzsche and Kierkegaard have laid eyes upon the subject of irony. We intend to work both the philosophical and the communicational aspects, showing how they are bonded. We shall also use the cinema of Woody Allen to exemplify our main ideas.

  19. New results from the Colorado CubeSat and comparison with Van Allen Probes data

    Science.gov (United States)

    Li, X.

    2013-05-01

    The Colorado Student Space Weather Experiment (CSSWE) is a 3-unit (10cm x 10cm x 30cm) CubeSat mission funded by the NSF, launched into a highly inclined (650) low-Earth (490km x 790km) orbit on 09/13/12 as a secondary payload under NASA's Educational Launch of Nanosatellites (ELaNa) program. CSSWE contains a single science payload, the Relativistic Electron and Proton Telescope integrated little experiment (REPTile), which is a simplified and miniaturized version of the Relativistic Electron and Proton Telescope (REPT) built at the Laboratory for Atmospheric and Space Physics (LASP) of University of Colorado for NASA/Van Allen Probes mission, which consists of two identical spacecraft, launched on 08/30/12, that traverse the heart of the radiation belts in a low inclination (100) orbit. REPTile is designed to measure the directional differential flux of protons ranging from 9 to 40 MeV and electrons from 0.5 to >3.3 MeV. Three-month science mission (full success) was completed on 1/05/13. We are now into the extended mission phase, focusing on data analysis and modeling. REPTile measures a fraction of the total population that has small enough equatorial pitch angles to reach the altitude of CSSWE, thus measuring the precipitating population as well as the trapped population. These measurements are critical for understanding the loss of outer radiation belt electrons. New results from CSSWE and comparison with Van Allen Probes data will be presented. The CSSWE is also an ideal class project, involving over 65 graduate and undergraduate students and providing training for the next generation of engineers and scientists over the full life-cycle of a satellite project.

  20. Gene co-expression analysis identifies brain regions and cell types involved in migraine pathophysiology: a GWAS-based study using the Allen Human Brain Atlas.

    Science.gov (United States)

    Eising, Else; Huisman, Sjoerd M H; Mahfouz, Ahmed; Vijfhuizen, Lisanne S; Anttila, Verneri; Winsvold, Bendik S; Kurth, Tobias; Ikram, M Arfan; Freilinger, Tobias; Kaprio, Jaakko; Boomsma, Dorret I; van Duijn, Cornelia M; Järvelin, Marjo-Riitta R; Zwart, John-Anker; Quaye, Lydia; Strachan, David P; Kubisch, Christian; Dichgans, Martin; Davey Smith, George; Stefansson, Kari; Palotie, Aarno; Chasman, Daniel I; Ferrari, Michel D; Terwindt, Gisela M; de Vries, Boukje; Nyholt, Dale R; Lelieveldt, Boudewijn P F; van den Maagdenberg, Arn M J M; Reinders, Marcel J T

    2016-04-01

    Migraine is a common disabling neurovascular brain disorder typically characterised by attacks of severe headache and associated with autonomic and neurological symptoms. Migraine is caused by an interplay of genetic and environmental factors. Genome-wide association studies (GWAS) have identified over a dozen genetic loci associated with migraine. Here, we integrated migraine GWAS data with high-resolution spatial gene expression data of normal adult brains from the Allen Human Brain Atlas to identify specific brain regions and molecular pathways that are possibly involved in migraine pathophysiology. To this end, we used two complementary methods. In GWAS data from 23,285 migraine cases and 95,425 controls, we first studied modules of co-expressed genes that were calculated based on human brain expression data for enrichment of genes that showed association with migraine. Enrichment of a migraine GWAS signal was found for five modules that suggest involvement in migraine pathophysiology of: (i) neurotransmission, protein catabolism and mitochondria in the cortex; (ii) transcription regulation in the cortex and cerebellum; and (iii) oligodendrocytes and mitochondria in subcortical areas. Second, we used the high-confidence genes from the migraine GWAS as a basis to construct local migraine-related co-expression gene networks. Signatures of all brain regions and pathways that were prominent in the first method also surfaced in the second method, thus providing support that these brain regions and pathways are indeed involved in migraine pathophysiology.

  1. Molecular Cloning and Characterization of an Allene Oxide Cyclase Gene Associated with Fiber Strength in Cotton

    Institute of Scientific and Technical Information of China (English)

    WANG Li-man; ZHU You-min; TONG Xiang-chao; HU Wen-jing; CAI Cai-ping; GUO Wang-zhen

    2014-01-01

    Allene oxide cyclase (AOC) is one of the most important enzymes in the biosynthetic pathway of the plant hormone jasmonic acid (JA). AOC catalyzes the conversion of allene oxide into 12-oxo-phytodienoic acid (OPDA), a precursor of JA. Using 28K cotton genome array hybridization, an expressed sequence tag (EST;GenBank accession no. ES792958) was investigated that exhibited signiifcant expression differences between lintless-fuzzless XinWX and linted-fuzzless XinFLM isogenic lines during ifber initiation stages. The EST was used to search the Gossypium EST database (http://www.ncbi.nlm.nih.gov/) for corresponding cDNA sequences encoding full-length open reading frames (ORFs). Identiifed ORFs were conifrmed using transcriptional and genomic data. As a result, a novel gene encoding AOC in cotton (Gossypium hirsutum AOC;GenBank accession no. KF383427) was cloned and characterized. The 741-bp GhAOC gene comprises three exons and two introns and encodes a polypeptide of 246 amino acids. Two homologous copies were identiifed in the tetraploid cotton species G. hirsutum acc. TM-1 and G. barbadense cv. Hai7124, and one copy in the diploid cotton species G. herbaceum and G. raimondii. qRT-PCR showed that the GhAOC transcript was abundant in cotton ifber tissues from 8 to 23 days post anthesis (DPA), and the expression proifles were similar in the two cultivated tetraploid cotton species G. hirsutum acc. TM-1 and G. barbadense cv. Hai7124, with a higher level of transcription in the former. One copy of GhAOC in tetraploid cotton was localized to chromosome 24 (Chr. D8) using the subgenome-speciifc single nucleotide polymorphism (SNP) marker analysis, which co-localized GhAOC to within 10 cM of a ifber strength quantitative trait locus (QTL) reported previously. GhAOC was highly correlated with ifber quality and strength (P=0.014) in an association analysis, suggesting a possible role in cotton ifber development, especially in secondary cell wall thickening.

  2. Chiroptical Properties and the Racemization of Pyrene and Tetrathiafulvalene-Substituted Allene: Substitution and Solvent Effects on Racemization in Tetrathiafulvalenylallene

    Directory of Open Access Journals (Sweden)

    Masashi Hasegawa

    2014-03-01

    Full Text Available Dissymmetric 1,3-diphenylallene derivative 3 connected with 4,5-bis(methyl-thiotetrathiafulvalenyl and 1-pyrenyl substituents was prepared and characterized. The molecular structure was determined by X-ray crystallographic analysis. Optical resolution was accomplished using a recycling chiral HPLC, and its chiroptical properties were examined with optical rotation and electronic circular dichroism (ECD spectra. The title compound underwent photoracemization under daylight. This behavior was investigated in various solvents and compared with that of 1,3-bis(tetrathiafulvalenylallene (bis-TTF-allene derivative 2. The first-order rate plot of the intensity of the ECD spectra at a given time interval gave the rate of racemization. Mild racemization was observed in polar solvents, whereas a relatively fast rate was obtained in less polar solvents. In addition, the TTF groups of the allene also accelerate the racemization rate. These results suggest that the racemization mechanism occurs via a non-polar diradical structure.

  3. A comparison of flash electroretinograms recorded from Burian Allen, JET, C-glide, gold foil, DTL and skin electrodes.

    Science.gov (United States)

    Esakowitz, L; Kriss, A; Shawkat, F

    1993-01-01

    Single flash scotopic and photopic electroretinograms (ERGs) were recorded from the same subjects using six types of corneal electrode, in order to assess their relative effectiveness. In addition, the ERG from a lower eyelid skin electrode was recorded to give an indication of the degree of attenuation to be expected from a skin electrode. On average, the scotopic ERG recorded from the Burian Allen electrode measured 471 microV (100%), and relative to this the b-waves recorded using other electrodes were as follows: JET (89%), C-glide (77%), gold foil (56%), DTL (46%) and skin (12%). Under photopic conditions the order was the same and the interelectrode proportions similar. The b-wave amplitude recorded using the Burian Allen electrode was 125 microV (100%), and with other electrodes was as follows: JET (93%), C-glide (78%), gold foil (60%), DTL (60%) and skin (14%).

  4. Commensal observing with the Allen Telescope array: software command and control

    CERN Document Server

    Gutierrez-Kraybill, Colby; MacMahon, David; Williams, Peter K G; Harp, Gerald; Ackermann, Robert; Kilsdonk, Tom; Richards, Jon; Barott, William C; 10.1117/12.857860

    2010-01-01

    The Allen Telescope Array (ATA) is a Large-Number-Small-Diameter radio telescope array currently with 42 individual antennas and 5 independent back-end science systems (2 imaging FX correlators and 3 time domain beam formers) located at the Hat Creek Radio Observatory (HCRO). The goal of the ATA is to run multiple back-ends simultaneously, supporting multiple science projects commensally. The primary software control systems are based on a combination of Java, JRuby and Ruby on Rails. The primary control API is simplified to provide easy integration with new back-end systems while the lower layers of the software stack are handled by a master observing system. Scheduling observations for the ATA is based on finding a union between the science needs of multiple projects and automatically determining an efficient path to operating the various sub-components to meet those needs. When completed, the ATA is expected to be a world-class radio telescope, combining dedicated SETI projects with numerous radio astronom...

  5. Exercises in Anatomy, Connectivity, and Morphology using Neuromorpho.org and the Allen Brain Atlas.

    Science.gov (United States)

    Chu, Philip; Peck, Joshua; Brumberg, Joshua C

    2015-01-01

    Laboratory instruction of neuroscience is often limited by the lack of physical resources and supplies (e.g., brains specimens, dissection kits, physiological equipment). Online databases can serve as supplements to material labs by providing professionally collected images of brain specimens and their underlying cellular populations with resolution and quality that is extremely difficult to access for strictly pedagogical purposes. We describe a method using two online databases, the Neuromorpho.org and the Allen Brain Atlas (ABA), that freely provide access to data from working brain scientists that can be modified for laboratory instruction/exercises. Neuromorpho.org is the first neuronal morphology database that provides qualitative and quantitative data from reconstructed cells analyzed in published scientific reports. The Neuromorpho.org database contains cross species and multiple neuronal phenotype datasets which allows for comparative examinations. The ABA provides modules that allow students to study the anatomy of the rodent brain, as well as observe the different cellular phenotypes that exist using histochemical labeling. Using these tools in conjunction, advanced students can ask questions about qualitative and quantitative neuronal morphology, then examine the distribution of the same cell types across the entire brain to gain a full appreciation of the magnitude of the brain's complexity.

  6. Writing on: Context and Visual Culture in Recent Works of Allen Fisher and Ulli Freer

    Directory of Open Access Journals (Sweden)

    Juha Virtanen

    2016-05-01

    Full Text Available This article is a study of Allen Fisher’s 'Proposals' and 'SPUTTOR', and Ulli Freer’s 'Burner on the Buff'. It aims to demonstrate that these works, despite their individual differences, share certain common parallels: (1 an interest in literary and visual culture, and (2 an awareness of the bearing these aspects of culture have on questions of state and civil authority. In the case of 'Proposals', this is discussed via the context of work – particularly in relation to the marketization of Higher Education (HE – and Fisher’s poetics of ‘confidence in lack’. These analyses are extended further through an examination of the social history of the US Space Shuttle programme under the Reagan administration, and the visual practices of collage in 'SPUTTOR'. The broader claims of these arguments are subsequently paralleled with cultural and socio-legal perspectives pertaining to graffiti–especially in connection to Banksy’s recent work, 'Art Buff', which ultimately provides a crucial context for understanding key aspects of 'Burner on the Buff.'

  7. Van Allen Probes observations of EMIC events triggered by solar wind dynamic pressure enhancements

    Science.gov (United States)

    Lee, D. Y.; Cho, J.; Roh, S. J.; Shin, D. K.; Hwang, J.; Kim, K. C.; Choi, C.; Kletzing, C.; Wygant, J. R.; Thaller, S. A.; Larsen, B.; Skoug, R. M.

    2015-12-01

    Electromagnetic ion cyclotron (EMIC) waves are one of the key plasma waves that can affect charged particle dynamics in the Earth's inner magnetosphere. One of the generation mechanisms of EMIC waves has long been known to be due to magnetospheric compression due to impact by enhanced solar wind dynamic pressure Pdyn. With the Van Allen Probes observations, we have identified 4 EMIC wave events that are triggered by Pdyn enhancements under northward IMF, prolonged quiet time conditions. We find the following features of the EMIC events. (1) They are triggered immediately at the Pdyn impact and remain active during the same period as the enhanced Pdyn duration. (2) They occur in either H band or He band or both. (3) Two events occur inside the plasmasphere and the other two outside the plasmasphere. (4) The wave polarization, either R or L, are highly elliptical, being close to be linear. (5) The wave normal angles are quite large, well away from being field-aligned. (6) About 10 - 50 keV proton fluxes indicate enhanced flux state with ~90 deg-peaked anisotropy in velocity distribution after the Pdyn impact. (7) From low altitude NOAA POES satellite observations of particles we find no obvious evidence for relativistic electron precipitation due to these Pdyn-triggered EMIC events. We will discuss implications of these observations on wave generation mechanism and interaction with radiation belt electrons.

  8. Allene- d4: Analysis of the {ν 5}/{ν 2} + ν 7 bands

    Science.gov (United States)

    Plíva, J.; Rousan, K.

    1988-06-01

    The infrared absorption spectrum of allene- d4 was measured on a high-resolution Fourier transform spectrometer in the region 2200 to 2300 cm -1, and deconvolution was used to attain an efective linewidth ˜0.0025 cm -1. The two parallel bands occurring in this region, centered at 2228.442 and 2275.992 cm -1, belong to the ν5 fundamental in close Fermi resonance with the ν2 + ν7 combination. Both bands exhibit the effects of very strong anharmonic perturbations by the states 2 ν4 + ν7, 2 ν9 + 2 ν11, ν4 + ν7 + 2 ν11, and ν2 + ν10 + ν11 and of x,y-Coriolis perturbations by additional states which have not been identified. The interacting upper states {ν 5}/{ν 2} + ν 7 and 12 perturbing states were included in the Hamiltonian used for the treatment of this highly distorted spectrum. A set of spectroscopic constants is reported which reproduces all the assigned lines of the two bands with a standard deviation of 0.0045 cm -1. The analysis indicates that the Fermi resonance between ν5 and ν2 + ν7 is nearly exact, with the unperturbed origins of these states located at 2252.137 and 2252.164 cm -1, respectively, and a coupling constant of 23.64 cm -1.

  9. “A DESCENT INTO THE MAELSTRÖM”: AESTHETICS OF SUBLIME AND EDGAR ALLEN POE

    Directory of Open Access Journals (Sweden)

    TUĞBA AYAS

    2012-10-01

    Full Text Available This paper aims to interpret Edgar Allen Poe’s short story “A Descent into the Maelström” in terms of the virtues of the 18th century sublime aesthetic theoretically informed by the works of two prominent philosophers, namely Edmund Burke and Immanuel Kant. “A Descent into the Maelström” is a landscape story about a fisherman’s escape from a deadly whirlpool called Moskoe-ström off the Norwegian coast in the North Sea. The aesthetics of sublime refers to a soul elevating experience of a piece of nature that is massive or mighty enough to cause human imagination to fail. Hence, it is possible to interpret this story in terms of the notion of sublime. The paper shall claim that Poe’s short story exemplifies both a Kantian and Burkean understandings of the concept in a fashion that is peculiar to Poe’s literary style. In the tale, the fisherman’s and the narrator’s experiences correspond to two kinds of sublime. Thus, in Poe’s peculiar writing, Burkean sublime shall be traced back in the fisherman’s experience of the whirlpool, whereas Kantian sublime in that of narrator’s. Following these two philosophers and their descriptions of the sublime, the paper shall trace this notion in Poe’s tale.

  10. Statistical Features of EMIC Waves Observed on Van Allen Probes in the Inner Magnetosphere

    Science.gov (United States)

    Lee, D. Y.; Roh, S. J.; Cho, J.; Shin, D. K.; Hwang, J.; Kim, K. C.; Kurth, W. S.; Kletzing, C.; Wygant, J. R.; Thaller, S. A.

    2015-12-01

    Electromagnetic ion cyclotron (EMIC) waves are one of the key plasma waves that can affect charged particle dynamics in the Earth's inner magnetosphere. Knowledge of global distribution of the EMIC waves is critical for accurately assessing the significance of its interaction with charged particles. With the Van Allen Probes EMFISIS observations, we have surveyed EMIC events for ~2.5 years period. We have identified well-defined, banded wave activities only, as distinguished from broad band wave activities. We have obtained global distribution of occurrence of the identified waves with distinction between H- and He-bands. We compare it with previous observations such as THEMIS and CRRES. For the identified events we have drawn all the basic wave properties including wave frequency, polarization, wave normal angle. In addition, we have distinguished the EMIC events that occur inside the plasmasphere and at the plasmapause from those outside the plasmasphere. Finally, we have tested solar wind and geomagnetic dependence of the wave events. We give discussions about implications of these observations on wave generation mechanism and interaction with radiation belt electrons.

  11. Primary Beam and Dish Surface Characterization at the Allen Telescope Array by Radio Holography

    CERN Document Server

    Atkinson, Shannon; Backus, P R; Barott, William; Bauermeister, Amber; Blitz, Leo; Bock, D C -J; Bower, Geoffrey C; Bradford, Tucker; Cheng, Calvin; Croft, Steve; Dexter, Matt; Dreher, John; Engargiola, Greg; Fields, Ed; Heiles, Carl; Helfer, Tamara; Jordan, Jane; Jorgensen, Susan; Kilsdonk, Tom; Gutierrez-Kraybill, Colby; Keating, Garrett; Law, Casey; Lugten, John; MacMahon, D H E; McMahon, Peter; Milgrome, Oren; Siemion, Andrew; Smolek, Ken; Thornton, Douglas; Pierson, Tom; Randall, Karen; Ross, John; Shostak, Seth; Tarter, J C; Urry, Lynn; Werthimer, Dan; Williams, Peter K G; Whysong, David; Harp, G R; Ackermann, R F; Nadler, Z J; Blair, Samantha K; Davis, M M; Wright, M C H; Forster, J R; DeBoer, D R; Welch, W J

    2012-01-01

    The Allen Telescope Array (ATA) is a cm-wave interferometer in California, comprising 42 antenna elements with 6-m diameter dishes. We characterize the antenna optical accuracy using two-antenna interferometry and radio holography. The distortion of each telescope relative to the average is small, with RMS differences of 1 percent of beam peak value. Holography provides images of dish illumination pattern, allowing characterization of as-built mirror surfaces. The ATA dishes can experience mm-scale distortions across -2 meter lengths due to mounting stresses or solar radiation. Experimental RMS errors are 0.7 mm at night and 3 mm under worst case solar illumination. For frequencies 4, 10, and 15 GHz, the nighttime values indicate sensitivity losses of 1, 10 and 20 percent, respectively. The ATA.s exceptional wide-bandwidth permits observations over a continuous range 0.5 to 11.2 GHz, and future retrofits may increase this range to 15 GHz. Beam patterns show a slowly varying focus frequency dependence. We prob...

  12. Spectropolarimetry with the Allen Telescope Array: Faraday Rotation toward Bright Polarized Radio Galaxies

    CERN Document Server

    Law, C J; Bower, G C; Backer, D C; Bauermeister, A; Croft, S; Forster, R; Gutierrez-Kraybill, C; Harvey-Smith, L; Heiles, C; Hull, C; Keating, G; MacMahon, D; Whysong, D; Williams, P K G; Wright, M

    2010-01-01

    We have observed 37 bright, polarized radio sources with the Allen Telescope Array (ATA) to present a novel analysis of their Faraday rotation properties. Each source was observed during the commissioning phase with 2 to 4 100-MHz bands at frequencies ranging from 1 to 2 GHz. These observations demonstrate how the continuous frequency coverage of the ATA's log-periodic receiver can be applied to the study of Faraday rotation measures (RMs). We use RM synthesis to show that wide-bandwidth data can find multiple RM components toward a single source. Roughly a quarter of the sources studied have extra RM components with high confidence (brighter than ~40 mJy), when observing with a RM resolution of roughly 100 rad/m2. These extra components contribute 10%-70% of the total polarized flux. This is the first time multiple RM components have been identified in a large sample of point sources. For our observing configuration, these extra RM components bias the measurement of the peak RM by 10-15 rad/m2 ; more general...

  13. A Neural Network Approach for Identifying Relativistic Electron Pitch Angle Distributions in Van Allen Probes Data

    Science.gov (United States)

    Souza, V. M. C. E. S.; Vieira, L.; Alves, L. R.; Da Silva, L. A.; Koga, D.; Sibeck, D. G.; Walsh, B.; Kanekal, S. G.; Silveira, M. D.; Medeiros, C.; Mendes, O., Jr.; Marchezi, J.; Rockenbach, M.; Jauer, P. R.; Gonzalez, W.; Baker, D. N.

    2015-12-01

    A myriad of physical phenomena occur in the inner magnetosphere, in particular at the Earth's radiation belts, which can be a result of the combination of both internal and external processes. However, the connection between physical processes occurring deep within the magnetosphere and external interplanetary drivers it is not yet well understood. In this work we investigate whether a selected set of interplanetary structures affect the local time distribution of three different classes of high energy electron pitch angle distributions (PADs), namely normal, isotropic, and butterfly. We split this work into two parts: initially we focus on the methodology used which employs a Self-Organized Feature Map (SOFM) neural network for identifying different classes of electron PAD shapes in the Van Allen Probes' Relativistic Electron Proton Telescope (REPT) data. The algorithm can categorize the input data into an arbitrary number of classes from which three of them appears the most: normal, isotropic and butterfly. Other classes which are related with these three also emerge and deserve to be addressed in detail in future works. We also discuss the uncertainties of the algorithm. Then, we move to the second part where we describe in details the criteria used for selecting the interplanetary events, and also try to investigate the relation between key parameters characterizing such interplanetary structures and the local time distributions of electron PAD shapes.

  14. ACE EPAM and Van Allen Probes RBSPICE measurements of interplanetary oxygen injection to the inner magnetosphere

    Science.gov (United States)

    Patterson, J. D.; Manweiler, J. W.; Gerrard, A. J.; Lanzerotti, L. J.

    2015-12-01

    On March 17, 2015, a significant oxygen-rich interplanetary event was measure by the Advanced Composition Explorer (ACE) Electron Proton Alpha Monitor (EPAM) instrument. At the same time the Van Allen Probes Radiation Belt Storm Probes Ion Composition Experiment (RBSPICE) instrument recorded significant enhancements of oxygen in the inner magnetosphere. We present a detailed analysis of this event utilizing a new method of exploiting the EPAM Pulse Height Analyzer (PHA) data to precisely resolve helium and oxygen spectra within the 0.5 to 5 MeV/nuc range. We also present the flux, partial particle pressures, and pitch angle distributions of the ion measurements from RBSPICE. During this event, both EPAM and RBSPICE measured O:He ratios greater than 10:1. The pitch angle distributions from RBSPICE-B show a strong beam of oxygen at an L ~ 5.8 early on March 17th during orbit. The timing between the observations of the oxygen peak at ACE and the beam observed at RBSPICE-B is consistent with the travel-time required for energetic particle transport from L1 to Earth and access to the magnetosphere. We assert that the oxygen seen by RBSPICE during the initial phase of this event is the result of direct injection from the interplanetary medium of energetic ions. This poster contains the observations and detailed calculations to support this assertion.

  15. Suppression of allene oxide synthase 3 in potato increases degree of arbuscular mycorrhizal fungal colonization.

    Science.gov (United States)

    Morcillo, Rafael Jorge León; Navarrete, María Isabel Tamayo; Bote, Juan Antonio Ocampo; Monguio, Salomé Prat; García-Garrido, José Manuel

    2016-01-15

    Arbuscular mycorrhizal (AM) is a mutually beneficial interaction among higher plants and soil fungi of the phylum Glomeromycota. Numerous studies have pointed that jasmonic acid plays an important role in the development of the intraradical fungus. This compound belongs to a group of biologically active compounds known as oxylipins which are derived from the oxidative metabolism of polyunsaturated fatty acids. Studies of the regulatory role played by oxylipins in AM colonization have generally focused on jasmonates, while few studies exist on the 9-LOX pathway of oxylipins during AM formation. Here, the cDNA of Allene oxide synthase 3 (AOS3), a key enzyme in the 9-LOX pathway, was used in the RNA interference (RNAi) system to transform potato plants in order to suppress its expression. Results show increases in AOS3 gene expression and 9-LOX products in roots of wild type potato mycorrhizal plants. The suppression of AOS3 gene expression increases the percentage of root with mycorrhizal colonization at early stages of AM formation. AOS3 RNA interference lead to an induction of LOXA and 13-LOX genes, a reduction in AOS3 derived 9-LOX oxylipin compounds and an increase in jasmonic acid content, suggesting compensation between 9 and 13-LOX pathways. The results in a whole support the hypothesis of a regulatory role for the 9-LOX oxylipin pathway during mycorrhization.

  16. Estimates of trapped radiation encountered on low-thrust trajectories through the Van Allen belts

    Science.gov (United States)

    Karp, I. M.

    1973-01-01

    Estimates were made of the number of trapped protons and electrons encountered by vehicles on low-thrust trajectories through the Van Allen belts. The estimates serve as a first step in assessing whether these radiations present a problem to on-board sensitive components and payload. The integrated proton spectra and electron spectra are presented for the case of a trajectory described by a vehicle with a constant-thrust acceleration A sub c equal to 0.001 meter/sq sec. This value of acceleration corresponds to a trip time of about 54 days from low earth orbit to synchronous orbit. It is shown that the time spent in the belts and hence the radiation encountered vary nearly inversely with the value of thrust acceleration. Thus, the integrated spectral values presented for the case of A sub c = 0.001 meter/sq sec can be generalized for any other value of thrust acceleration by multiplying them by the factor 0.001/A sub c.

  17. Improved lattice Boltzmann modeling of binary flow based on the conservative Allen-Cahn equation

    Science.gov (United States)

    Ren, Feng; Song, Baowei; Sukop, Michael C.; Hu, Haibao

    2016-08-01

    The primary and key task of binary fluid flow modeling is to track the interface with good accuracy, which is usually challenging due to the sharp-interface limit and numerical dispersion. This article concentrates on further development of the conservative Allen-Cahn equation (ACE) [Geier et al., Phys. Rev. E 91, 063309 (2015), 10.1103/PhysRevE.91.063309] under the framework of the lattice Boltzmann method (LBM), with incorporation of the incompressible hydrodynamic equations [Liang et al., Phys. Rev. E 89, 053320 (2014), 10.1103/PhysRevE.89.053320]. Utilizing a modified equilibrium distribution function and an additional source term, this model is capable of correctly recovering the conservative ACE through the Chapman-Enskog analysis. We also simulate four phase-tracking benchmark cases, including one three-dimensional case; all show good accuracy as well as low numerical dispersion. By coupling the incompressible hydrodynamic equations, we also simulate layered Poiseuille flow and the Rayleigh-Taylor instability, illustrating satisfying performance in dealing with complex flow problems, e.g., high viscosity ratio, high density ratio, and high Reynolds number situations. The present work provides a reliable and efficient solution for binary flow modeling.

  18. Understanding Earth's radiation belt electron dynamics: Van Allen Probes observations and simulations

    Science.gov (United States)

    Li, Wen; Ma, Qianli; Thorne, Richard; Bortnik, Jacob; Zhang, Xiaojia

    2016-10-01

    Various physical processes are known to cause acceleration, loss, and transport of energetic electrons in the Earth's radiation belts, but their quantitative roles in different time and space need further investigation. In the present paper, we evaluate the relative roles of various physical processes during geomagnetic storms using a 3D diffusion simulation. By quantitatively comparing the electron evolution observed by Van Allen Probes and simulation, we found that whistler-mode chorus waves play a critical role in accelerating electrons up to several MeV through efficient energy diffusion. By only including radial diffusion driven by ultra-low-frequency waves, the simulation underestimates the observed electron acceleration, while radial diffusion plays an important role in redistributing electrons. Although an additional loss process is required to fully explain the overestimated electron fluxes at multi-MeV, the combined physical processes of radial diffusion and scattering by whistler-mode waves reproduce the observed electron dynamics remarkably well, suggesting that quasi-linear diffusion theory is reasonable to evaluate radiation belt electron dynamics, and the importance of nonlinear wave-particle interaction may still remain as an open question. We would like to acknowledge AFOSR Award FA9550-15-1-0158, NASA Grants NNX15AI96G, NNX15AF61G, and the NSF Grant AGS 1564510 for supporting this research.

  19. Explaining the dynamics of the ultra-relativistic third Van Allen radiation belt

    Science.gov (United States)

    Mann, I. R.; Ozeke, L. G.; Murphy, K. R.; Claudepierre, S. G.; Turner, D. L.; Baker, D. N.; Rae, I. J.; Kale, A.; Milling, D. K.; Boyd, A. J.; Spence, H. E.; Reeves, G. D.; Singer, H. J.; Dimitrakoudis, S.; Daglis, I. A.; Honary, F.

    2016-10-01

    Since the discovery of the Van Allen radiation belts over 50 years ago, an explanation for their complete dynamics has remained elusive. Especially challenging is understanding the recently discovered ultra-relativistic third electron radiation belt. Current theory asserts that loss in the heart of the outer belt, essential to the formation of the third belt, must be controlled by high-frequency plasma wave-particle scattering into the atmosphere, via whistler mode chorus, plasmaspheric hiss, or electromagnetic ion cyclotron waves. However, this has failed to accurately reproduce the third belt. Using a data-driven, time-dependent specification of ultra-low-frequency (ULF) waves we show for the first time how the third radiation belt is established as a simple, elegant consequence of storm-time extremely fast outward ULF wave transport. High-frequency wave-particle scattering loss into the atmosphere is not needed in this case. When rapid ULF wave transport coupled to a dynamic boundary is accurately specified, the sensitive dynamics controlling the enigmatic ultra-relativistic third radiation belt are naturally explained.

  20. Charisma and Counterculture: Allen Ginsberg as a Prophet for a New Generation

    Directory of Open Access Journals (Sweden)

    Yaakov Ariel

    2013-01-01

    Full Text Available The cultural role of Allen Ginsberg does not fit a typical Weberian model of charisma. The avant-garde poet was an outstanding personality and possessed an unusual ability to affect people. He played a vital role in expanding the boundaries of personal freedom in America of the 1950s–1990s, blazing new paths for spiritual, communal and artistic expression. Serving as a father figure for the counterculture—a symbol of an alternative set of cultural norms, lifestyles and literary forms—Ginsberg was a charismatic counter-leader, with no clearly defined followers or movement. As a leader in a more liberated era, he offered energy, ideas, inspiration, and color, but no structure or authority. Instead he was a prophet of freedom, calling on people to express themselves openly, to expand and experiment. This role demanded charisma but of a different kind—one that was more spiritual and less organizational or hierarchical. This article follows Gary Dickson’s essay “Charisma, Medieval and Modern,” in offering a suggestive analysis of and supplement to Weber’s understanding of charisma. The article grapples with the concept of charisma in relation to a generation that resented rigid structures and authorities.

  1. Evolution of chorus emissions into plasmaspheric hiss observed by Van Allen Probes

    Science.gov (United States)

    Zhou, Qinghua; Xiao, Fuliang; Yang, Chang; Liu, Si; He, Yihua; Wygant, J. R.; Baker, D. N.; Spence, H. E.; Reeves, G. D.; Funsten, H. O.

    2016-05-01

    The two classes of whistler mode waves (chorus and hiss) play different roles in the dynamics of radiation belt energetic electrons. Chorus can efficiently accelerate energetic electrons, and hiss is responsible for the loss of energetic electrons. Previous studies have proposed that chorus is the source of plasmaspheric hiss, but this still requires an observational confirmation because the previously observed chorus and hiss emissions were not in the same frequency range in the same time. Here we report simultaneous observations form Van Allen Probes that chorus and hiss emissions occurred in the same range ˜300-1500 Hz with the peak wave power density about 10-5 nT2/Hz during a weak storm on 3 July 2014. Chorus emissions propagate in a broad region outside the plasmapause. Meanwhile, hiss emissions are confined inside the plasmasphere, with a higher intensity and a broader area at a lower frequency. A sum of bi-Maxwellian distribution is used to model the observed anisotropic electron distributions and to evaluate the instability of waves. A three-dimensional ray tracing simulation shows that a portion of chorus emission outside the plasmasphere can propagate into the plasmasphere and evolve into plasmaspheric hiss. Moreover, hiss waves below 1 kHz are more intense and propagate over a broader area than those above 1 kHz, consistent with the observation. The current results can explain distributions of the observed hiss emission and provide a further support for the mechanism of evolution of chorus into hiss emissions.

  2. SYNTHESIS OF FUNCTIONAL POLYETHYLENE via COPOLYMERIZATION OF ETHYLENE AND SUBSTITUTED ALLENE USING BIS(β-ENAMINOKETONATO)TITANIUM CATALYSTS

    Institute of Scientific and Technical Information of China (English)

    Miao Hong; Bai-xiang Li; Yue-sheng Li

    2011-01-01

    Novel copolymerization of ethylene with substituted allenes (CH2=C=CH-R,1:R =n-butyl,2:R =n-octyl)using bis(β-enaminoketonato)titanium catalysts [PhN=C(R2)CHC(R1)O]2TiCl2 (1a:R1 =CF3,R2 =CH3; 1b:R1 =Ph,R2 =CF3) has been investigated.In the presence of modified methylaluminoxane,these catalysts can copolymerize ethylene with substituted allenes,affording copolymers with unimodal molecular weight distributions and homogeneous compositions.By varying the reaction conditions,the comonomer incorporation can be tuned in the range of 0-3.6 mol%.1H-NMR spectra reveal that the copolymerization proceeds through 1,2-insertion fashion of allene comonomer exclusively,and the regioselective nature maintains under various reaction conditions.The retained intra-chain double bond can be converted into the epoxy group under mild conditions.

  3. Observation of chorus waves by the Van Allen Probes: Dependence on solar wind parameters and scale size

    Science.gov (United States)

    Aryan, Homayon; Sibeck, David; Balikhin, Michael; Agapitov, Oleksiy; Kletzing, Craig

    2016-08-01

    Highly energetic electrons in the Earth's Van Allen radiation belts can cause serious damage to spacecraft electronic systems and affect the atmospheric composition if they precipitate into the upper atmosphere. Whistler mode chorus waves have attracted significant attention in recent decades for their crucial role in the acceleration and loss of energetic electrons that ultimately change the dynamics of the radiation belts. The distribution of these waves in the inner magnetosphere is commonly presented as a function of geomagnetic activity. However, geomagnetic indices are nonspecific parameters that are compiled from imperfectly covered ground based measurements. The present study uses wave data from the two Van Allen Probes to present the distribution of lower band chorus waves not only as functions of single geomagnetic index and solar wind parameters but also as functions of combined parameters. Also the current study takes advantage of the unique equatorial orbit of the Van Allen Probes to estimate the average scale size of chorus wave packets, during close separations between the two spacecraft, as a function of radial distance, magnetic latitude, and geomagnetic activity, respectively. Results show that the average scale size of chorus wave packets is approximately 1300-2300 km. The results also show that the inclusion of combined parameters can provide better representation of the chorus wave distributions in the inner magnetosphere and therefore can further improve our knowledge of the acceleration and loss of radiation belt electrons.

  4. Allen's rule revisited: temperature influences bone elongation during a critical period of postnatal development.

    Science.gov (United States)

    Serrat, Maria A

    2013-10-01

    Limbs of animals raised at warm ambient temperature are significantly and permanently longer than those of siblings housed in the cold. These highly reproducible lab results closely parallel the ecogeographical tenet described by Allen's extremity size rule, which states that appendage length correlates with temperature and latitude. It is unclear what mechanisms underlie these differences and in what pattern they emerge, since the morphology is traditionally thought to reflect naturally selected genomic adaptations for thermoregulation. This study tests the a posteriori hypothesis that adult extremity length is subject to substantial modification by temperature during a brief but critical period of early postnatal development. Weanling mice (N = 28) were divided into three groups and housed at 7°C, 21°C, or 27°C for eight weeks. Tail lengths and body mass were measured weekly. Mass did not differ at any age. Analysis of tail elongation curves revealed two distinct phases: an initial period of rapid temperature-sensitive growth in which elongation rate was directly impacted by temperature; and a second phase of continued growth in which rates were identical among groups. Comparable growth reactions occur in response to other environmental variables such as exercise, suggesting that the skeleton is most responsive to external stimuli during a window of heightened sensitivity when growth occurs most rapidly. Knowledge of the timing and degree to which growth plasticity permits mammals to immediately adjust to novel temperature conditions will be important for analyzing skeletal variation in fluctuating climates, particularly for assessing factors that may accelerate skeletal evolution at temperature extremes.

  5. The perpendicular CD stretching band ν8 of allene- d4

    Science.gov (United States)

    Plíva, J.; Rousan, K.; Merchan, A.; Polo, S. R.

    1983-05-01

    The perpendicular infrared band of the degenerate CD stretching vibration ν8 (species E) in allene- d4 with band origin at 2321.2473 cm -1 was measured on a high resolution Fourier transform spectrometer and deconvolved to a linewidth of ˜0.0028 cm -1. A total of 23 subbands with KΔ K ranging from -10 to +12 have been assigned. An improved set of ground state constants B0, DJ0, DJK0, and HJK0 was obtained using ˜1300 combination differences from this band and from the parallel bands ν5 and ν6 measured on the same instrument. The ν8 band exhibits many perturbations caused by interactions with various combinations of lower lying vibrations. The nature of the perturbing states is discussed and three of the strongest perturbations are quantitatively accounted for by constructing a Hamiltonian matrix which includes three different perturbing states and their Coriolis interactions with the upper state of ν8. The ν2 + ν7 parallel band, strongly enhanced by Fermi resonance with ν5, is observed just below the ν8 band. Its upper state was also included in the H matrix, but its J xy-Coriolis interaction with ν8 could not satisfactorily account for the perturbations seen in the KΔ K = -8 to -10 subbands of ν8. Using data for the subbands from KΔ K = -7 to +10, a set of spectroscopic constants was obtained for the ν8 state (and for the three perturbing states) with the aid of our computer program system SYMTOP designed for the treatment of symmetric top bands whose upper states are involved in arbitrary interactions. The standard deviation of the fit, 0.0031 cm -1, far exceeds the precision of the measurements (˜0.0004 cm -1) and is evidence for the presence of additional high-order perturbations.

  6. Lipoxygenase-allene oxide synthase pathway in octocoral thermal stress response

    Science.gov (United States)

    Lõhelaid, H.; Teder, T.; Samel, N.

    2015-03-01

    Marine ecosystems are sensitive to elevated seawater temperature, with stony corals serving as model organisms for temperature-imposed declines in population viability and diversity. Several stress markers, including heat shock proteins, have been used for the detection and prediction of stress responses in stony corals. However, the stress indicators in soft corals remain elusive. In higher animals and plants, oxylipins synthesized by fatty acid di- and monooxygenases contribute to stress-induced signaling; however, the role of eicosanoid pathways in corals remains unclear. The eicosanoid gene specific to corals encodes for a natural fusion protein of allene oxide synthase and lipoxygenase ( AOS- LOX). In this work, using the easily cultivated soft coral Capnella imbricata as the stress response model, we monitored the expression of the AOS-LOX and the formation of arachidonic acid metabolites in response to an acute rise in water temperature. Gene expression profiles of two 70 kDa heat shock proteins ( Hsps: Hsp70 and Grp78) were used as a positive control for the stress response. In comparison with normal seawater temperature (23 °C), AOS- LOXa and Hsps were all up-regulated after modest (28 °C) and severe (31 °C) temperature elevation. While the up-regulation of AOS- LOXa and Grp78 was more sensitive to moderate temperature changes, Hsp70s were more responsive to severe heat shock. Concurrently, endogenous and exogenous AOS-LOXa-derived eicosanoids were up-regulated. Thus, together with the up-regulation of AOS- LOX by other abiotic and biotic stress stimuli, these data implicate AOS-LOX as part of the general stress response pathway in corals.

  7. Innermost Van Allen Radiation Belt for High Energy Protons at Saturn

    Science.gov (United States)

    Cooper, John F.

    2008-01-01

    The high energy proton radiation belts of Saturn are energetically dominated by the source from cosmic ray albedo neutron decay (CRAND), trapping of protons from beta decay of neutrons emitted from galactic cosmic ray nuclear interactions with the main rings. These belts were originally discovered in wide gaps between the A-ring, Janus/Epimetheus, Mimas, and Enceladus. The narrow F and G rings significant affected the CRAND protons but did not produce total depletion. Voyager 2 measurements subsequently revealed an outermost CRAND proton belt beyond Enceladus. Although the source rate is small, the trapping times limited by radial magnetospheric diffusion are very long, about ten years at peak measured flux inwards of the G ring, so large fluxes can accumulate unless otherwise limited in the trapping region by neutral gas, dust, and ring body interactions. One proposed final extension of the Cassini Orbiter mission would place perikrone in a 3000-km gap between the inner D ring and the upper atmosphere of Saturn. Experience with CRAND in the Earth's inner Van Allen proton belt suggests that a similar innermost belt might be found in this comparably wide region at Saturn. Radial dependence of magnetospheric diffusion, proximity to the ring neutron source, and northward magnetic offset of Saturn's magnetic equator from the ring plane could potentially produce peak fluxes several orders of magnitude higher than previously measured outside the main rings. Even brief passes through such an intense environment of highly penetrating protons would be a significant concern for spacecraft operations and science observations. Actual fluxes are limited by losses in Saturn's exospheric gas and in a dust environment likely comparable to that of the known CRAND proton belts. The first numerical model of this unexplored radiation belt is presented to determine limits on peak magnitude and radial profile of the proton flux distribution.

  8. Photofragment imaging study of the CH2CCH2OH radical intermediate of the OH +allene reaction

    Science.gov (United States)

    Raman, Arjun S.; Justine Bell, M.; Lau, Kai-Chung; Butler, Laurie J.

    2007-10-01

    These velocity map imaging experiments characterize the photolytic generation of one of the two radical intermediates formed when OH reacts via an addition mechanism with allene. The CH2CCH2OH radical intermediate is generated photolytically from the photodissociation of 2-chloro-2-propen-1-ol at 193nm. Detecting the Cl atoms using [2+1] resonance-enhanced multiphoton ionization evidences an isotropic angular distribution for the Cl +CH2CCH2OH photofragments, a spin-orbit branching ratio for Cl(P1/22):Cl(P3/22) of 0.28, and a bimodal recoil kinetic energy distribution. Conservation of momentum and energy allows us to determine from this data the internal energy distribution of the nascent CH2CCH2OH radical cofragment. To assess the possible subsequent decomposition pathways of this highly vibrationally excited radical intermediate, we include electronic structure calculations at the G3//B3LYP level of theory. They predict the isomerization and dissociation transition states en route from the initial CH2CCH2OH radical intermediate to the three most important product channels for the OH +allene reaction expected from this radical intermediate: formaldehyde+C2H3, H +acrolein, and ethene+CHO. We also calculate the intermediates and transition states en route from the other radical adduct, formed by addition of the OH to the center carbon of allene, to the ketene+CH3 product channel. We compare our results to a previous theoretical study of the O +allyl reaction conducted at the CBS-QB3 level of theory, as the two reactions include several common intermediates.

  9. Wounding stimulates ALLENE OXIDE SYNTHASE gene and increases the level of jasmonic acid in Ipomoea nil cotyledons

    Directory of Open Access Journals (Sweden)

    Emilia Wilmowicz

    2016-03-01

    Full Text Available Allene oxide synthase (AOS encodes the first enzyme in the lipoxygenase pathway, which is responsible for jasmonic acid (JA formation. In this study we report the molecular cloning and characterization of InAOS from Ipomoea nil. The full-length gene is composed of 1662 bp and encodes for 519 amino acids. The predicted InAOS contains PLN02648 motif, which is evolutionarily conserved and characteristic for functional enzymatic proteins. We have shown that wounding led to a strong stimulation of the examined gene activity in cotyledons and an increase in JA level, which suggest that this compound may be a modulator of stress responses in I. nil.

  10. Colour image segmentation by the vector-valued Allen-Cahn phase-field model: a multigrid solution

    CERN Document Server

    Kay, David A

    2007-01-01

    We propose a new method for the numerical solution of a PDE-driven model for colour image segmentation and give numerical examples of the results. The method combines the vector-valued Allen-Cahn phase field equation with initial data fitting terms. This method is known to be closely related to the Mumford-Shah problem and the level set segmentation by Chan and Vese. Our numerical solution is performed using a multigrid splitting of a finite element space, thereby producing an efficient and robust method for the segmentation of large images.

  11. Multi-Spacecraft Data Assimilation and Reanalysis During the THEMIS and Van Allen Probes Era

    Science.gov (United States)

    Kellerman, A. C.; Shprits, Y.; Kondrashov, D. A.; Podladchikova, T.; Drozdov, A.; Subbotin, D.

    2013-12-01

    consideration of the innovation vector may lead to a new physical understanding of the radiation belt system, which can later be used to improve our model forecasts. In the current study, we explore the radiation belt dynamics of the current era including data from the THEMIS, Van Allen Probes, GPS satellites, Akebono, NOAA and Cluster spacecraft. Intercalibration is performed between spacecraft on an individual energy channel basis, and in invariant coordinates. The global reanalysis allows an unprecedented analysis of the source-acceleration-transport-loss relationship in Earth's radiation belts. This analysis is used to refine our model capabilities, and to prepare the 3-D reanalysis for real-time data. The global 3-D reanalysis is an important step towards full-scale modeling and operational forecasting of this dynamic region of space.

  12. Van Allen Probes observations of dipolarization and its associated O+ flux variations in the inner magnetosphere

    Science.gov (United States)

    Nose, M.; Keika, K.; Kletzing, C.; Smith, C. W.; MacDowall, R. J.; Reeves, G. D.; Spence, H. E.

    2015-12-01

    Recent study employing the MDS-1 satellite reveals that magnetic field dipolarization in the deep inner magnetosphere is not unusual. When the MDS-1 satellite was located at L=3.5-5.0 near the auroral onset longitude (MLT difference of ≤2.5 h), the occurrence probability of local dipolarization was about 16%. Surprisingly, an event was found at L~3.6, far inside the geosynchronous altitude. It was also shown that after the dipolarization, the oxygen ENA flux in the nightside ring current region measured by the IMAGE satellite was predominantly enhanced by a factor of 2-5 and stayed at an enhanced level for more than 1 h, while clear enhancement was scarcely seen in the hydrogen ENA flux. To better understand mechanisms of the selective acceleration of O+ ions during dipolarization, an in-situ measurement of ion fluxes is needed. However, there are few studies investigating H+ and O+ flux variations during dipolarization in the deep inner magnetosphere. In this study we investigate magnetic field dipolarization and its associated ion flux variations in the deep inner magnetosphere, using magnetic field and ion flux data obtained by the Van Allen Probes. From the magnetic field data recorded on the nightside (1800-0600 MLT) in the inner magnetosphere (L=3.0-6.6) in VDH coordinates, we select substorm-related dipolarization events in which the H component increases by more than 20 nT and the absolute value of the V component decreases by more than 8 nT in 5 minutes. About 150 dipolarization events are identified from 1 October 2012 to 30 June 2015. We find that the dipolarization mostly occurs at L=4.5-6.5 in the premidnight sector (2100-0000 MLT). No events are found at Levents are accompanied by O+ flux enhancements in the energy range higher than a few keV, which have the pitch angle distribution peaked around 45 or 135 degrees. We also find that low energy O+ ions often appear after dipolarization with an energy dispersion starting from around keV down to a few

  13. Since Yesterday: The Nineteen Thirties in America. By Frederick Allen Lewis. New York: Bantam Books, 1939. 292pp. Since Yesterday: The Nineteen Thirties in America. By Frederick Allen Lewis. New York: Bantam Books, 1939. 292pp.

    Directory of Open Access Journals (Sweden)

    Eileen Klink

    2008-04-01

    Full Text Available Material Covered: A compendium of events, people, places, and settings of the Thirties, this book offers information on: 1.chronology and impact of events on national and international levels–from the prelude to the Panic, September 3, 1929, through the outbreak of the war with Germany, September 3, 1939. 2.major political and business figures plus celebrities of the era–Hoover, Roosevelt, Hitler, Charles Lindbergh, Fred & Gracie Allen, etc. 3.influential organizations and unions. 4.statistical information and analysis. 5. day–to–day life—e.g., the books, magazines, and newspapers; films and radio programs; automobiles; fashions; the weather. Material Covered: A compendium of events, people, places, and settings of the Thirties, this book offers information on: 1.chronology and impact of events on national and international levels–from the prelude to the Panic, September 3, 1929, through the outbreak of the war with Germany, September 3, 1939. 2.major political and business figures plus celebrities of the era–Hoover, Roosevelt, Hitler, Charles Lindbergh, Fred & Gracie Allen, etc. 3.influential organizations and unions. 4.statistical information and analysis. 5. day–to–day life—e.g., the books, magazines, and newspapers; films and radio programs; automobiles; fashions; the weather.

  14. When Harry met Zuckerman: self-reflexivity and metafiction in Philip Roth and Woody Allen When Harry met Zuckerman:self-reflexivity and metafiction in Philip Roth and Woody Allen

    Directory of Open Access Journals (Sweden)

    Thomás Creus

    2008-04-01

    Full Text Available The objective of this essay is to compare the works of novelist Philip Roth and film-maker Woody Allen in what regards their treatment of the highly complex theme of the interrelations between fiction and reality. A comparative analysis of selected Roth’s novels and Allen’s films evinces their recurrent preoccupation with the creation of art and its implications, be it through the choice of writers or artists as main characters, be it through plots that mix real facts with invented ones and imaginary characters with real ones, be it through the use of autobiographical elements in a fictional discourse—all metafictional devices that call attention to the artist’s own process of creation. The objective of this essay is to compare the works of novelist Philip Roth and film-maker Woody Allen in what regards their treatment of the highly complex theme of the interrelations between fiction and reality. A comparative analysis of selected Roth’s novels and Allen’s films evinces their recurrent preoccupation with the creation of art and its implications, be it through the choice of writers or artists as main characters, be it through plots that mix real facts with invented ones and imaginary characters with real ones, be it through the use of autobiographical elements in a fictional discourse—all metafictional devices that call attention to the artist’s own process of creation.

  15. Comparison of Van Allen Probes radiation belt proton data with test particle simulation for the 17 March 2015 storm

    Science.gov (United States)

    Engel, M. A.; Kress, B. T.; Hudson, M. K.; Selesnick, R. S.

    2016-11-01

    The loss of protons in the outer part of the inner radiation belt (L = 2 to 3) during the 17 March 2015 geomagnetic storm was investigated using test particle simulations that follow full Lorentz trajectories with both magnetic and electric fields calculated from an empirical model. The simulation results presented here are compared with proton pitch angle measurements from the Van Allen Probe satellites Relativistic Electron Proton Telescope (REPT) instrument before and after the coronal mass ejection-shock-driven storm of 17-18 March 2015, with minimum Dst =- 223 nT, the strongest storm of Solar Cycle 24, for four different energy ranges with 30, 38, 50, and 66 MeV mean energies. Two simulations have been run, one with an inductive electric field and one without. All four energy channels show good agreement with the Van Allen Probes REPT measurements for low L (L 2.4. A previous study using the Highly Elliptical Orbiter 3 spacecraft also showed improved agreement when including the inductive electric field but was unable to compare effects on the pitch angle distributions.

  16. Avaliação de pacientes submetidos à sutura do manguito rotador com a técnica de mason-allen modificada

    OpenAIRE

    Porto,Fernanda de Marchi Bosi; Alves,Marcelo Wiltemburg; Andrade,André Luis Lugnani de

    2013-01-01

    OBJETIVO: Avaliar clinicamente pacientes que foram submetidos a reparo artroscópico do manguito rotador (MR), pela técnica de sutura Mason-Allen modificada. MÉTODOS: Foram avaliados 79 pacientes submetidos à artroscopia de ombro. As lesões foram reparadas com a sutura Mason-Allen modificada entre os anos de 2003 e 2009, divididos pela classificação de Cofield e avaliados clinicamente pelo Sistema de Pontuação da Universidade de Los Angeles (UCLA) no pré e pós-operatório. RESULTADOS: A avaliaç...

  17. Modes of Heme-Binding and Substrate Access for Cytochrome P450 CYP74A Revealed by Crystal Structures of Allene Oxide Synthase

    Science.gov (United States)

    Cytochrome P450s exist ubiquitously in all organisms and are involved in many biological processes. Allene oxide synthase (AOS) is a P450 enzyme that plays a key role in the biosynthesis of oxylipin jasmonates which are involved in signal and defense reactions in higher plants. The crystal structure...

  18. Isomerization of Internal Alkynes to Iridium(III Allene Complexes via C–H Bond Activation: Expanded Substrate Scope, and Progress towards a Catalytic Methodology

    Directory of Open Access Journals (Sweden)

    Neha Phadke

    2015-11-01

    Full Text Available The synthesis of a series of allene complexes (POCOPIr(η2-RC=.=CR’ 1b–4b (POCOP = 2,6-bis(di-tert-butylphosphonitobenzene via isomerization of internal alkynes is reported. We have demonstrated that the application of this methodology is viable for the isomerization of a wide variety of alkyne substrates. Deuterium labeling experiments support our proposed mechanism. The structures of the allene complexes 1b–4b were determined using spectroscopic data analysis. Additionally, the solid-state molecular structure of complex 2b was determined using single crystal X-ray diffraction studies and it confirmed the assignment of an iridium-bound allene isomerization product. The rates of isomerization were measured using NMR techniques over a range of temperatures to allow determination of thermodynamic parameters. Finally, we report a preliminary step towards developing a catalytic methodology; the allene may be liberated from the metal center by exposure of the complex to an atmosphere of carbon monoxide.

  19. Broad and Visionary. Commentary on Allen Kent (1977) Information Science. (Journal of Education for Librarianship, 17(3), 131-139)

    Science.gov (United States)

    Bates, Marcia J.

    2015-01-01

    Allen Kent was a pioneer in many aspects of library and information science (LIS), and yet, as this author reads Kent's 1977 article, there is not much in it that has become ancient, irrelevant history. The questions he discusses are still alive in the discipline in 2014, whether it is called LIS (library and information science), information…

  20. Typical values of the electric drift E × B/B2 in the inner radiation belt and slot region as determined from Van Allen Probe measurements

    Science.gov (United States)

    Lejosne, Solène; Mozer, F. S.

    2016-12-01

    The electric drift E × B/B2 plays a fundamental role for the description of plasma flow and particle acceleration. Yet it is not well-known in the inner belt and slot region because of a lack of reliable in situ measurements. In this article, we present an analysis of the electric drifts measured below L 3 by both Van Allen Probes A and B from September 2012 to December 2014. The objective is to determine the typical components of the equatorial electric drift in both radial and azimuthal directions. The dependences of the components on radial distance, magnetic local time, and geographic longitude are examined. The results from Van Allen Probe A agree with Van Allen Probe B. They show, among other things, a typical corotation lag of the order of 5 to 10% below L 2.6, as well as a slight radial transport of the order of 20 m s-1. The magnetic local time dependence of the electric drift is consistent with that of the ionosphere wind dynamo below L 2 and with that of a solar wind-driven convection electric field above L 2. A secondary longitudinal dependence of the electric field is also found. Therefore, this work also demonstrates that the instruments on board Van Allen Probes are able to perform accurate measurements of the electric drift below L 3.

  1. Gold coordination during homogeneous alkyne and allene cyclisation catalysis: Coordination to substrates, to ancillary ligands and in intermediates

    Directory of Open Access Journals (Sweden)

    Hubert Schmidbaur

    2011-03-01

    Full Text Available The ever-increasing role of homogeneous gold catalysis in organic synthesis and the consequent need to be able to rationally control the rate and outcome of such reactions has emphasised the importance of each successive metal–carbon coordination step. Concentrating on alkyne and allene cyclisation and upon reaction mechanisms postulated on the basis of empirical and theoretical results, we have examined the coordination of gold fragments to triple bonds, the modification of gold(I precatalysts to effect specific reaction pathways or enantioselectivity and the isolation of coordinated intermediates or model compounds thereof. Some of the recent advances that have been made in various laboratories are described in this compact review.

  2. Exact Mass Measurements for a-Allenic Alcohol by Atmospheric Pressure Chemical Ionization/Time-of-flight Mass Spectrometry

    Institute of Scientific and Technical Information of China (English)

    何萍; 郭寅龙; 陈国强; 徐代旺; 麻生明

    2003-01-01

    The atmospheric pressure chemical ionization/time,of-flight mass speetrmtry (APEI/TOF-MS) was applied to determine the mass of five a.aIIenic alcohols via their vrotonated molecu.lar ions nslna Imsifive ion mode. Polyethylene Idycol (PEG) was used as the hlternal reference. All results were obtained under the resolution of about 5000 FWHM (full width at the half maximum). Solvent effects were studied and the satired results were obtained in acetonitrile. Comvared with the theoreflcal values, nun absolute errors were less thRn 1.0 mmu. The efTeets Of nozzle pote.Jldal, push pulse potential, pug pulse potentlai, puO bias potential and ic(lulsltion rate on exact mass determina/lon were also discussed. APCI/TOF.MS is proven to be a very semi/ire analytical technique and an alternative ionizafion mode in analytical technique lablle compounds with relatively weak polarity, such as a-allenic alcohol.

  3. Van Allen Probes observations of prompt MeV radiation belt electron acceleration in nonlinear interactions with VLF chorus

    Science.gov (United States)

    Foster, J. C.; Erickson, P. J.; Omura, Y.; Baker, D. N.; Kletzing, C. A.; Claudepierre, S. G.

    2017-01-01

    Prompt recovery of MeV (millions of electron Volts) electron populations in the poststorm core of the outer terrestrial radiation belt involves local acceleration of a seed population of energetic electrons in interactions with VLF chorus waves. Electron interactions during the generation of VLF rising tones are strongly nonlinear, such that a fraction of the relativistic electrons at resonant energies are trapped by waves, leading to significant nonadiabatic energy exchange. Through detailed examination of VLF chorus and electron fluxes observed by Van Allen Probes, we investigate the efficiency of nonlinear processes for acceleration of electrons to MeV energies. We find through subpacket analysis of chorus waveforms that electrons with initial energy of hundreds of keV to 3 MeV can be accelerated by 50 keV-200 keV in resonant interactions with a single VLF rising tone on a time scale of 10-100 ms.

  4. A new species of Trichuris Roederer, 1761 (Nematoda: Trichuridae) from Heteromys gaumeri Allen & Chapman (Rodentia: Heteromyidae) in Yucatan, Mexico.

    Science.gov (United States)

    Panti-May, Jesús Alonso; Robles, María Del Rosario

    2016-09-01

    In Mexico, four species of Trichuris Roederer, 1761 have been recorded in wild rodents belonging to the family Heteromyidae. In the present paper, we describe a new species based on specimens collected from Heteromys gaumeri Allen & Chapman (Heteromyidae: Heteromyinae) in the tropical forests of the Yucatan Peninsula, Mexico. Trichuris silviae n. sp. can be differentiated from the congeners described in North and South American rodents by morphological and morphometric features, such as the possession of a wide spicular tube, a thicker proximal cloacal tube, a shorter distal cloacal tube and a cylindrical spicular sheath. This is the first description of a Trichuris spp. from heteromyid rodents in Mexico and the fourth in North America. Despite the broad distribution of Heteromys spp., few cases of Trichuris infection have been reported. Further studies are necessary to verify if the new species is present in other heteromyid rodents in order to increase our knowledge about its geographical and host distribution.

  5. Distributed and boundary optimal control of the Allen-Cahn equation with regular potential and dynamic boundary conditions

    Science.gov (United States)

    Benincasa, T.; Donado Escobar, L. D.; Moroşanu, C.

    2016-08-01

    This paper is concerned with an optimal control problem (P) (both distributed control as well as boundary control) for the nonlinear phase-field (Allen-Cahn) equation, involving a regular potential and dynamic boundary condition. A family of approximate optimal control problems (Pɛ) is introduced and results for the existence of an optimal control for problems (P) and (Pɛ) are proven. Furthermore, the convergence result of the optimal solution of problem (Pɛ) to the optimal solution of problem (P) is proved. Besides the existence of an optimal control in problem (Pɛ), necessary optimality conditions (Pontryagin's principle) as well as a conceptual gradient-type algorithm to approximate the optimal control, were established in the end.

  6. Computational neuroanatomy: mapping cell-type densities in the mouse brain, simulations from the Allen Brain Atlas

    Science.gov (United States)

    Grange, Pascal

    2015-09-01

    The Allen Brain Atlas of the adult mouse (ABA) consists of digitized expression profiles of thousands of genes in the mouse brain, co-registered to a common three-dimensional template (the Allen Reference Atlas).This brain-wide, genome-wide data set has triggered a renaissance in neuroanatomy. Its voxelized version (with cubic voxels of side 200 microns) is available for desktop computation in MATLAB. On the other hand, brain cells exhibit a great phenotypic diversity (in terms of size, shape and electrophysiological activity), which has inspired the names of some well-studied cell types, such as granule cells and medium spiny neurons. However, no exhaustive taxonomy of brain cell is available. A genetic classification of brain cells is being undertaken, and some cell types have been chraracterized by their transcriptome profiles. However, given a cell type characterized by its transcriptome, it is not clear where else in the brain similar cells can be found. The ABA can been used to solve this region-specificity problem in a data-driven way: rewriting the brain-wide expression profiles of all genes in the atlas as a sum of cell-type-specific transcriptome profiles is equivalent to solving a quadratic optimization problem at each voxel in the brain. However, the estimated brain-wide densities of 64 cell types published recently were based on one series of co-registered coronal in situ hybridization (ISH) images per gene, whereas the online ABA contains several image series per gene, including sagittal ones. In the presented work, we simulate the variability of cell-type densities in a Monte Carlo way by repeatedly drawing a random image series for each gene and solving the optimization problem. This yields error bars on the region-specificity of cell types.

  7. Deterministic methods for the relativistic Vlasov-Maxwell equations and the Van Allen belts dynamics; Methodes deterministes de resolution des equations de Vlasov-Maxwell relativistes en vue du calcul de la dynamique des ceintures de Van Allen

    Energy Technology Data Exchange (ETDEWEB)

    Le Bourdiec, S

    2007-03-15

    Artificial satellites operate in an hostile radiation environment, the Van Allen radiation belts, which partly condition their reliability and their lifespan. In order to protect them, it is necessary to characterize the dynamics of the energetic electrons trapped in these radiation belts. This dynamics is essentially determined by the interactions between the energetic electrons and the existing electromagnetic waves. This work consisted in designing a numerical scheme to solve the equations modelling these interactions: the relativistic Vlasov-Maxwell system of equations. Our choice was directed towards methods of direct integration. We propose three new spectral methods for the momentum discretization: a Galerkin method and two collocation methods. All of them are based on scaled Hermite functions. The scaling factor is chosen in order to obtain the proper velocity resolution. We present in this thesis the discretization of the one-dimensional Vlasov-Poisson system and the numerical results obtained. Then we study the possible extensions of the methods to the complete relativistic problem. In order to reduce the computing time, parallelization and optimization of the algorithms were carried out. Finally, we present 1Dx-3Dv (mono-dimensional for x and three-dimensional for velocity) computations of Weibel and whistler instabilities with one or two electrons species. (author)

  8. A thermally stable gold(III) hydride: synthesis, reactivity, and reductive condensation as a route to gold(II) complexes.

    Science.gov (United States)

    Roşca, Dragoş-Adrian; Smith, Dan A; Hughes, David L; Bochmann, Manfred

    2012-10-15

    Going for gold: The first thermally stable gold(III) hydride [(C N C)*AuH] is presented. It undergoes regioselective insertions with allenes to give gold(III) vinyl complexes, and reductive condensation with [(C N C)*AuOH] to the air-stable Au(II) product, [(C N C)*(2)Au(2)], with a short nonbridged gold-gold bond.

  9. Quantification of Brain Access of Exendin-4 in the C57BL Mouse Model by SPIM Fluorescence Imaging and the Allen Mouse Brain Reference Model

    DEFF Research Database (Denmark)

    Jensen, Casper Bo; Secher, Anna; Hecksher-Sørensen, Jacob;

    2015-01-01

    With the recent advance in 3D microscopy such as Single Plane Illumination Microscopy (SPIM) it is possible to obtain high resolution image volumes of the entire mouse brain. These data can be used to study the access of several peptides such as the glucagon-like peptide-1 (GLP-1) analogue Exendin...... construct a SPIM brain atlas based on the Allen mouse brain 3D reference model and use it to analyze the access of peripherally injected Exendin-4 into the brain compared to a negative control group. The constructed atlas consists of an average SPIM volume obtained from eight C57BL mouse brains using group......-wise registration. A cross-modality registration is performed between the constructed average volume and the Allen mouse brain reference model to allow propagation of annotations to the SPIM average brain. Finally, manual corrections of the annotations are performed and validated by visual inspection. The study...

  10. Synthesis of 1,2-allenic ketones through oxidation of homopropargyl alcohols with CrO3(cat.)/TBHP under MWI

    Institute of Scientific and Technical Information of China (English)

    Xin Ying Zhang; Ying Ying Qu; Yang Yang Wang; Xue Sen Fan

    2011-01-01

    A Cr3 catalyzed oxidation of homopropargyl alcohols with tert-butyl hydroperoxide under microwave irradiation was found to be an efficient and rapid alternative for the preparation of 1,2-allenic ketones. The advantages of this procedure include short reaction time, less adverse impact on the environment and reasonably high efficiency. (c) 2010 Published by Elsevier B.V. on behalf of Chinese Chemical Society.

  11. Empirical modeling of the storm time innermost magnetosphere using Van Allen Probes and THEMIS data: Eastward and banana currents

    Science.gov (United States)

    Stephens, G. K.; Sitnov, M. I.; Ukhorskiy, A. Y.; Roelof, E. C.; Tsyganenko, N. A.; Le, G.

    2016-01-01

    The structure of storm time currents in the inner magnetosphere, including its innermost region inside 4RE, is studied for the first time using a modification of the empirical geomagnetic field model TS07D and new data from Van Allen Probes and Time History of Events and Macroscale Interactions during Substorms missions. It is shown that the model, which uses basis-function expansions instead of ad hoc current modules to approximate the magnetic field, consistently improves its resolution and magnetic field reconstruction with the increase of the number of basis functions and resolves the spatial structure and evolution of the innermost eastward current. This includes a connection between the westward ring current flowing largely at and the eastward ring current concentrated at resulting in a vortex current pattern. A similar pattern coined `banana current' was previously inferred from the pressure distributions based on the energetic neutral atom imaging and first-principles ring current simulations. The morphology of the equatorial currents is dependent on storm phase. During the main phase, it is complex, with several asymmetries forming banana currents. Near SYM-H minimum, the banana current is strongest, is localized in the evening-midnight sector, and is more structured compared to the main phase. It then weakens during the recovery phase resulting in the equatorial currents to become mostly azimuthally symmetric.

  12. Three Neoclassicisms. Exploring the Possibilities of a Comparative Average Shot Length Through Clint Eastwood, Brian De Palma and Woody Allen

    Directory of Open Access Journals (Sweden)

    Agustín Rubio Alcover

    2013-07-01

    Full Text Available This study is intended to compare the complete filmographies of the three American directors whose works are analyzed. They are Clint Eastwood, Brian De Palma and Woody Allen. We define the approach as a trampoline for leaping over the wall of a difficult conceptual and methodological blind alley—an understanding of movie editors and their task, but above all their contribution. Their work is disguised as something merely technical and obvious but, even in the best of cases, this attitude never anything other than lazy. It is the analysis route upheld and cultivated by the David Bordwell and Barry Salt that we are prepared to travel along. If we want to abjure an unsustainably radical anti-empiricism without precipitating ourselves into neo-empiricist infantilism or regressing to a chaotic teratology—that is: to try to remain focused on both the wood and the trees—a statistical-type study, aided by the latest-generation digital and computer tools and, more specifically, an Average Shot Length study (which we will refer to from now on with the acronym ASL appears to us an objective and, consequently, literally unobjectionable criterion. It is probably as reductionist as it is stimulating when it comes to reaching conclusions that are non-definitive but undoubtedly worthy of interest, because, faced with the subjectivity of the analysis and at the general macroscopic level of the movie, the normative and the standard blends with the deviant, or exceptional.   

  13. Combined convective and diffusive simulations: VERB-4D comparison with 17 March 2013 Van Allen Probes observations

    Science.gov (United States)

    Shprits, Yuri Y.; Kellerman, Adam C.; Drozdov, Alexander Y.; Spence, Harlan E.; Reeves, Geoffrey D.; Baker, Daniel N.

    2015-11-01

    This study is focused on understanding the coupling between different electron populations in the inner magnetosphere and the various physical processes that determine evolution of electron fluxes at different energies. Observations during the 17 March 2013 storm and simulations with a newly developed Versatile Electron Radiation Belt-4D (VERB-4D) are presented. Analysis of the drift trajectories of the energetic and relativistic electrons shows that electron trajectories at transitional energies with a first invariant on the scale of ~100 MeV/G may resemble ring current or relativistic electron trajectories depending on the level of geomagnetic activity. Simulations with the VERB-4D code including convection, radial diffusion, and energy diffusion are presented. Sensitivity simulations including various physical processes show how different acceleration mechanisms contribute to the energization of energetic electrons at transitional energies. In particular, the range of energies where inward transport is strongly influenced by both convection and radial diffusion are studied. The results of the 4-D simulations are compared to Van Allen Probes observations at a range of energies including source, seed, and core populations of the energetic and relativistic electrons in the inner magnetosphere.

  14. Kalman Filtering and Smoothing of the Van Allen Probes Observations to Estimate the Radial, Energy and Pitch Angle Diffusion Rates

    Science.gov (United States)

    Podladchikova, T.; Shprits, Y.; Kellerman, A. C.

    2015-12-01

    The Kalman filter technique combines the strengths of new physical models of the Earth's radiation belts with long-term spacecraft observations of electron fluxes and therefore provide an extremely useful method for the analysis of the state and evolution of the electron radiation belts. However, to get the reliable data assimilation output, the Kalman filter application is confronted with a set of fundamental problems. E.g., satellite measurements are usually limited to a single location in space, which confines the reconstruction of the global evolution of the radiation environment. The uncertainties arise from the imperfect description of the process dynamics and the presence of observation errors, which may cause the failure of data assimilation solution. The development of adaptive Kalman filter that combines the Van Allen Probes data and 3-D VERB code, its accurate customizations in the reconstruction of model describing the phase space density (PSD) evolution, extension of the possibilities to use measurement information, and the model adjustment by developing the identification techniques of model and measurement errors allowed us to reveal hidden and implicit regularities of the PSD dynamics and obtain quantitative and qualitative estimates of radial, energy and pitch angle diffusion characteristics from satellite observations. In this study we propose an approach to estimate radial, energy and pitch angle diffusion rates, as well as the direction of their propagation.

  15. Whistler anisotropy instabilities as the source of banded chorus: Van Allen Probes observations and particle-in-cell simulations.

    Science.gov (United States)

    Fu, Xiangrong; Cowee, Misa M; Friedel, Reinhard H; Funsten, Herbert O; Gary, S Peter; Hospodarsky, George B; Kletzing, Craig; Kurth, William; Larsen, Brian A; Liu, Kaijun; MacDonald, Elizabeth A; Min, Kyungguk; Reeves, Geoffrey D; Skoug, Ruth M; Winske, Dan

    2014-10-01

    Magnetospheric banded chorus is enhanced whistler waves with frequencies ωr particle-in-cell simulations in a magnetized, homogeneous, collisionless plasma to test the hypothesis that banded chorus is due to local linear growth of two branches of the whistler anisotropy instability excited by two distinct, anisotropic electron components of significantly different temperatures. The electron densities and temperatures are derived from Helium, Oxygen, Proton, and Electron instrument measurements on the Van Allen Probes A satellite during a banded chorus event on 1 November 2012. The observations are consistent with a three-component electron model consisting of a cold (a few tens of eV) population, a warm (a few hundred eV) anisotropic population, and a hot (a few keV) anisotropic population. The simulations use plasma and field parameters as measured from the satellite during this event except for two numbers: the anisotropies of the warm and the hot electron components are enhanced over the measured values in order to obtain relatively rapid instability growth. The simulations show that the warm component drives the quasi-electrostatic upper band chorus and that the hot component drives the electromagnetic lower band chorus; the gap at ∼Ω e /2 is a natural consequence of the growth of two whistler modes with different properties.

  16. 'Confessing out the soul to conform to the rhythm of thought': a reading of Allen Ginsberg’s Beat poetry

    Directory of Open Access Journals (Sweden)

    H. Kruger

    2007-07-01

    Full Text Available Much critical writing about the Beat Movement has focused on the strong interrelationship between the literary and social discourses within and around the movement. However, the study of Beat literature also necessitates an awareness of its position within the literary discourse of the twentieth century. Beat writing may be seen as standing in the unstable, shifting territory between two equally unstable, shifting literary movements: modernism and postmodernism. Beat poetry pits itself against high modernism and the New Critical tradition, draws upon some aspects of early avant-garde modernism, and simultaneously remoulds these aspects into what may be regarded as the beginnings of postmodernism in the USA. This article presents a reading of Allen Ginsberg’s Beat poetry against this literary-historical background. A brief general overview of some of the key characteristics of Beat poetry is given, followed by a discussion of a number of Beat poems, organised around some salient features of Ginsberg’s Beat poetry that may be linked to Beat poetry’s position in the transition from modernism to postmodernism.

  17. Whistler anisotropy instabilities as the source of banded chorus: Van Allen Probes observations and particle-in-cell simulations

    Science.gov (United States)

    Fu, Xiangrong; Cowee, Misa M.; Friedel, Reinhard H.; Funsten, Herbert O.; Gary, S. Peter; Hospodarsky, George B.; Kletzing, Craig; Kurth, William; Larsen, Brian A.; Liu, Kaijun; MacDonald, Elizabeth A.; Min, Kyungguk; Reeves, Geoffrey D.; Skoug, Ruth M.; Winske, Dan

    2014-10-01

    Magnetospheric banded chorus is enhanced whistler waves with frequencies ωrcell simulations in a magnetized, homogeneous, collisionless plasma to test the hypothesis that banded chorus is due to local linear growth of two branches of the whistler anisotropy instability excited by two distinct, anisotropic electron components of significantly different temperatures. The electron densities and temperatures are derived from Helium, Oxygen, Proton, and Electron instrument measurements on the Van Allen Probes A satellite during a banded chorus event on 1 November 2012. The observations are consistent with a three-component electron model consisting of a cold (a few tens of eV) population, a warm (a few hundred eV) anisotropic population, and a hot (a few keV) anisotropic population. The simulations use plasma and field parameters as measured from the satellite during this event except for two numbers: the anisotropies of the warm and the hot electron components are enhanced over the measured values in order to obtain relatively rapid instability growth. The simulations show that the warm component drives the quasi-electrostatic upper band chorus and that the hot component drives the electromagnetic lower band chorus; the gap at ˜Ωe/2 is a natural consequence of the growth of two whistler modes with different properties.

  18. The Allen Telescope Array Pi GHz Sky Survey I. Survey Description and Static Catalog Results for the Bootes Field

    CERN Document Server

    Bower, Geoffrey C; Keating, Garrett; Whysong, David; Ackermann, Rob; Atkinson, Shannon; Backer, Don; Backus, Peter; Barott, Billy; Bauermeister, Amber; Blitz, Leo; Bock, Douglas; Bradford, Tucker; Cheng, Calvin; Cork, Chris; Davis, Mike; DeBoer, Dave; Dexter, Matt; Dreher, John; Engargiola, Greg; Fields, Ed; Fleming, Matt; Forster, R James; Gutierrez-Kraybill, Colby; Harp, G R; Heiles, Carl; Helfer, Tamara; Hull, Chat; Jordan, Jane; Jorgensen, Susanne; Kilsdonk, Tom; Law, Casey; van Leeuwen, Joeri; Lugten, John; MacMahon, Dave; McMahon, Peter; Milgrome, Oren; Pierson, Tom; Randall, Karen; Ross, John; Shostak, Seth; Siemion, Andrew; Smolek, Ken; Tarter, Jill; Thornton, Douglas; Urry, Lynn; Vitouchkine, Artyom; Wadefalk, Niklas; Weinreb, Sandy; Welch, Jack; Werthimer, Dan; Williams, Peter K G; Wright, Melvyn

    2010-01-01

    The Pi GHz Sky Survey (PiGSS) is a key project of the Allen Telescope Array. PiGSS is a 3.1 GHz survey of radio continuum emission in the extragalactic sky with an emphasis on synoptic observations that measure the static and time-variable properties of the sky. During the 2.5-year campaign, PiGSS will twice observe ~250,000 radio sources in the 10,000 deg^2 region of the sky with b > 30 deg to an rms sensitivity of ~1 mJy. Additionally, sub-regions of the sky will be observed multiple times to characterize variability on time scales of days to years. We present here observations of a 10 deg^2 region in the Bootes constellation overlapping the NOAO Deep Wide Field Survey field. The PiGSS image was constructed from 75 daily observations distributed over a 4-month period and has an rms flux density between 200 and 250 microJy. This represents a deeper image by a factor of 4 to 8 than we will achieve over the entire 10,000 deg^2. We provide flux densities, source sizes, and spectral indices for the 425 sources d...

  19. Occurrence characteristics of outer zone relativistic electron butterfly distribution: A survey of Van Allen Probes REPT measurements

    Science.gov (United States)

    Ni, Binbin; Zou, Zhengyang; Li, Xinlin; Bortnik, Jacob; Xie, Lun; Gu, Xudong

    2016-06-01

    Using Van Allen Probes Relativistic Electron Proton Telescope (REPT) pitch angle resolved electron flux data from September 2012 to March 2015, we investigate in detail the global occurrence pattern of equatorial (|λ| ≤ 3°) butterfly distribution of outer zone relativistic electrons and its potential correlation with the solar wind dynamic pressure. The statistical results demonstrate that these butterfly distributions occur with the highest occurrence rate ~ 80% at ~ 20-04 magnetic local time (MLT) and L > ~ 5.5 and with the second peak (> ~ 50%) at ~ 11-15 MLT of lower L shells ~ 4.0. They can also extend to L = 3.5 and to other MLT intervals but with the occurrence rates predominantly butterfly distributions are likely to peak between 58° and 79° for L = 4.0 and 5.0 and between 37° and 58° for L = 6.0, regardless of the level of solar wind dynamic pressure. Relativistic electron butterfly distributions at L = 4.0 also exhibit a pronounced day-night asymmetry in response to the Pdyn variations. Compared to the significant L shell and MLT dependence of the global occurrence pattern, outer zone relativistic electron butterfly distributions show much less but still discernable sensitivity to Pdyn, geomagnetic activity level, and electron energy, the full understanding of which requires future attempts of detailed simulations that combine and differentiate underlying physical mechanisms of the geomagnetic field asymmetry and scattering by various magnetospheric waves.

  20. A Self-Study Tutorial using the Allen Brain Explorer and Brain Atlas to Teach Concepts of Mammalian Neuroanatomy and Brain Function.

    Science.gov (United States)

    Jenks, Bruce G

    2009-01-01

    The Allen Brain Atlas is a repository of neuroanatomical data concerning the mouse brain. The core of the database is a Nissl-stained reference atlas of the brain accompanied by in situ hybridization data for essentially the entire mouse genome. This database is freely available at the Allen Institute for Brain Science website, as is an innovative tool to explore the database, the Brain Explorer. This tool is downloaded and installed on your own computer. I have developed a self-study tutorial, "Explorations with the Allen Brain Explorer", which uses the Brain Explorer and the Brain Atlas to teach fundamentals of mammalian neuroanatomy and brain function. In this tutorial background information and step-by-step exercises on the use of the Brain Explorer are given using PowerPoint as a platform. To do the tutorial both the PowerPoint and the Brain Explorer are opened on the computer and the students switch from one program to the other as they go, in a step-wise fashion, through the various exercises. There are two main groups of exercises, titled "The Basics" and "Explorations", with both groups accessed from a PowerPoint "Start Menu" by clicking on dynamic links to the appropriate exercises. Most exercises have a number of dynamic links to PowerPoint slides where background information for the exercises is given or the neuroanatomical data collected from the Brain Atlas is discussed.

  1. MENGA: A New Comprehensive Tool for the Integration of Neuroimaging Data and the Allen Human Brain Transcriptome Atlas.

    Directory of Open Access Journals (Sweden)

    Gaia Rizzo

    Full Text Available Brain-wide mRNA mappings offer a great potential for neuroscience research as they can provide information about system proteomics. In a previous work we have correlated mRNA maps with the binding patterns of radioligands targeting specific molecular systems and imaged with positron emission tomography (PET in unrelated control groups. This approach is potentially applicable to any imaging modality as long as an efficient procedure of imaging-genomic matching is provided. In the original work we considered mRNA brain maps of the whole human genome derived from the Allen human brain database (ABA and we performed the analysis with a specific region-based segmentation with a resolution that was limited by the PET data parcellation. There we identified the need for a platform for imaging-genomic integration that should be usable with any imaging modalities and fully exploit the high resolution mapping of ABA dataset.In this work we present MENGA (Multimodal Environment for Neuroimaging and Genomic Analysis, a software platform that allows the investigation of the correlation patterns between neuroimaging data of any sort (both functional and structural with mRNA gene expression profiles derived from the ABA database at high resolution.We applied MENGA to six different imaging datasets from three modalities (PET, single photon emission tomography and magnetic resonance imaging targeting the dopamine and serotonin receptor systems and the myelin molecular structure. We further investigated imaging-genomic correlations in the case of mismatch between selected proteins and imaging targets.

  2. Combined Experimental and Theoretical Study on the Formation of the Elusive 2-Methyl-1-silacycloprop-2-enylidene Molecule under Single Collision Conditions via Reactions of the Silylidyne Radical (SiH; X(2)Π) with Allene (H2CCCH2; X(1)A1) and D4-Allene (D2CCCD2; X(1)A1).

    Science.gov (United States)

    Yang, Tao; Dangi, Beni B; Maksyutenko, Pavlo; Kaiser, Ralf I; Bertels, Luke W; Head-Gordon, Martin

    2015-12-17

    The crossed molecular beam reactions of the ground-state silylidyne radical (SiH; X(2)Π) with allene (H2CCCH2; X(1)A1) and D4-allene (D2CCCD2; X(1)A1) were carried out at collision energies of 30 kJ mol(-1). Electronic structure calculations propose that the reaction of silylidyne with allene has no entrance barrier and is initiated by silylidyne addition to the π electron density of allene either to one carbon atom (C1/C2) or to both carbon atoms simultaneously via indirect (complex forming) reaction dynamics. The initially formed addition complexes isomerize via two distinct reaction pathways, both leading eventually to a cyclic SiC3H5 intermediate. The latter decomposes through a loose exit transition state via an atomic hydrogen loss perpendicularly to the plane of the decomposing complex (sideways scattering) in an overall exoergic reaction (experimentally: -19 ± 13 kJ mol(-1); computationally: -5 ± 3 kJ mol(-1)). This hydrogen loss yields the hitherto elusive 2-methyl-1-silacycloprop-2-enylidene molecule (c-SiC3H4), which can be derived from the closed-shell cyclopropenylidene molecule (c-C3H2) by replacing a hydrogen atom with a methyl group and the carbene carbon atom by the isovalent silicon atom. The synthesis of the 2-methyl-1-silacycloprop-2-enylidene molecule in the bimolecular gas-phase reaction of silylidyne with allene enriches our understanding toward the formation of organosilicon species in the gas phase of the interstellar medium in particular via exoergic reactions of no entrance barrier. This facile route to 2-methyl-1-silacycloprop-2-enylidene via a silylidyne radical reaction with allene opens up a versatile approach to form hitherto poorly characterized silicon-bearing species in extraterrestrial environments; this reaction class might represent the missing link, leading from silicon-bearing radicals via organosilicon chemistry eventually to silicon-carbon-rich interstellar grains even in cold molecular clouds where temperatures are as

  3. A Nano-satellite Mission to Study Charged Particle Precipitation from the Van Allen Radiation Belts caused due to Seismo-Electromagnetic Emissions

    CERN Document Server

    Sivadas, Nithin; Kannapan, Deepti; Yalamarthy, Ananth Saran; Dhiman, Ankit; Bhagoji, Arjun; Shankar, Athreya; Prasad, Nitin; Ramachandran, Harishankar; Koilpillai, R David

    2014-01-01

    In the past decade, several attempts have been made to study the effects of seismo-electromagnetic emissions - an earthquake precursor, on the ionosphere and the radiation belts. The IIT Madras nano-satellite (IITMSAT) mission is designed to make sensitive measurements of charged particle fluxes in a Low Earth Orbit to study the nature of charged particle precipitation from the Van Allen radiation belts caused due to such emissions. With the Space-based Proton Electron Energy Detector on-board a single nano-satellite, the mission will attempt to gather statistically significant data to verify possible correlations with seismo-electromagnetic emissions before major earthquakes.

  4. 艾伦·卡尔松的科学认知主义理论%Allen Carlson's Scientific Cognition Theory

    Institute of Scientific and Technical Information of China (English)

    薛富兴

    2009-01-01

    @@ 艾伦·卡尔松(Allen Carlson)的自然美学理论在当代西方美学中独树一帜.这一理论因强调科学知识在自然审美欣赏中的重要作用而被同行称之为"科学认知主义"(scientific cognitivism).认真分析这一理论的基本内容,对当代自然、环境美学的基础理论建构很有参考价值.

  5. 認知症高齢者に対するAllen Cognitive Level Screen の有用性

    OpenAIRE

    阿部, 勇太; 藤田, 尚子; 久米, 裕; 石井, 奈智子; 石井, 良和; Abe, Yuta; Fujita, Naoko; KUME, Yu; ISHII, Nachiko; Ishii, Yoshikazu

    2011-01-01

    本研究では, 65歳以上の統合失調症群, 認知症群に対して革細工という作業活動を用いた評価であるAllenCognitive Level Screen (以下ACLS)を, 期間をあけて2回実施し, 認知レベルを測定し再テスト信頼性を検討した. また, HDS-R, NM スケール, REHAB を基準として両群の結果を比較検討した. その結果, 統合失調症群と認知症群の両群においてACLS の再テスト信頼性が確認でき, 基準関連妥当性があることが示唆された. また, 統合失調症群においては年齢が高くなるごとに認知レベルが低下しているが, 認知症群では年齢に関係なく, 疾患に起因して認知レベルが低下していることが明らかになった. 本研究にて, ACLS は統合失調症高齢者においてはもちろんのこと, 認知症高齢者においても言語・行動観察・作業活動の要素を含む多角的側面からの評価が可能であり,信頼性, 妥当性のある認知機能評価であると示唆された. よって認知症高齢者においても, ACLS により得られた評価結果にて, 作業活動導入場面や日常生活の課題遂行場面において対象者の認知レベル...

  6. BASEMAP, ALLEN COUNTY, OHIO

    Data.gov (United States)

    Federal Emergency Management Agency, Department of Homeland Security — FEMA Framework Basemap datasets comprise six of the seven FGDC themes of geospatial data that are used by most GIS applications (Note: the seventh framework theme,...

  7. Biomechanical evaluation between the modified Mason-Allen stitch and the locked double-tie stitch on the infraspinatus of sheep,

    Directory of Open Access Journals (Sweden)

    Alberto Naoki Miyazaki

    2014-12-01

    Full Text Available Objectives:To evaluate and compare the in vitro biomechanical results from two stitches: the Mason-Allen stitch, as modified by Habermeyer; and the locked double-tie stitch developed at our service, on tendons of the infraspinatus muscle of sheep.Methods:Twenty tendons from the infraspinatus muscle of sheep were randomly divided into two groups: LDT, on which the locked double-tie stitch was performed; and MA, with the modified Mason-Allen stitch. The evaluation was performed in the mechanics laboratory, using a standard test machine with unidirectional traction, constant velocity of 20 mm per second and a 500 N load cell, without force cycling.Results:We observed that LDT was superior to MA, for the force needed to form spaces of both 5 mm (p = 0.01 and 10 mm (p = 0.002 and also for the maximum traction resistance (p = 0.003.Conclusion:We confirmed our hypothesis that LDT stitches are superior to MA stitches from a biomechanical point of view. This is a further stitching option for surgeons, when fragile and poorly vascularized tendons need to be sutured, and it improves the quality of fixation without increasing the "strangulation" and, consequently, the ischemic area.

  8. Characteristics of ring current protons and oxygen ions during the 7 January 2015 and 17 March 2015 storms: Van Allen Probes/RBSPICE observations

    Science.gov (United States)

    Keika, K.; Seki, K.; Nose, M.; Machida, S.; Miyoshi, Y.; Lanzerotti, L. J.; Mitchell, D. G.; Gkioulidou, M.; Gerrard, A. J.; Manweiler, J. W.

    2015-12-01

    We investigate enhancements and losses of energetic (~50-~500 keV) protons and oxygen ions during two intense storms on January 7 and March 17 in 2015. We use proton and oxygen ion data from RBSPICE onboard Van Allen Probes. During the January 7 storm (Dstmin = -99 nT), Van Allen Probes explored the inner magnetosphere on the night side, with both spacecraft located around midnight at apogee. Their orbits were in opposite phase. RBSPICE data are available from both spacecraft during the rapid recovery of the storm. We analyze energy spectra of both species to identify whether the ring current is symmetric or not, and determine the dominant loss process. During the March 17 storm (Dstmin = -223 nT), Van Allen Probes traveled in the pre-midnight sector during the outbound paths and around midnight during the inbound path. The orbits of the two spacecraft were in opposite phase. The Dst index during the storm showed a two-step decrease with the first minimum at 9 UT and the second at 22 UT. Enhancements of ring current ions began at RBSPICE-B at ~7 UT, and RBSPICE-A entered the ring current region at ~9 UT. The RBSPICE data show penetration of energetic protons (μ~0.1 keV/nT) down to L~4 during the first storm development. Protons penetrated more deeply (as low as L~3) during the second enhancement. The protons, which we confirmed made a dominant contribution to energy density at L = 3-4, are more enhanced in flux around the storm maximum. The flux of 200-400 keV oxygen ions was enhanced and localized around midnight near the end of the first storm development. Oxygen ion enhancements during the second development were seen in a wide range of MLT (pre-midnight to midnight). We examine the evolution of ion energy spectra to identify whether each phase of the multi-step storm development was due to deep penetration of transport/injections, density enhancements, or/and non-adiabatic acceleration of protons and oxygen ions.

  9. The Arabidopsis male-sterile mutant dde2-2 is defective in the ALLENE OXIDE SYNTHASE gene encoding one of the key enzymes of the jasmonic acid biosynthesis pathway

    DEFF Research Database (Denmark)

    von Malek, Bernadette; van der Graaff, Eric; Schneitz, Kay;

    2002-01-01

    exhibits a male-sterile phenotype. The dde2-2 phenotype can be rescued by application of methyl jasmonate, indicating that the mutant is affected in jasmonic acid biosynthesis. The combination of genetic mapping and a candidate-gene approach identified a frameshift mutation in the ALLENE OXIDE SYNTHASE...

  10. 9 July 2008 - Microsoft Co-Founder P. Allen visiting ATLAS control room and underground experimental area with Adviser J. Ellis and IT Department Head W. von Rüden.

    CERN Multimedia

    Maximilien Brice

    2008-01-01

    9 July 2008 - Microsoft Co-Founder P. Allen visiting ATLAS control room and underground experimental area with Adviser J. Ellis and IT Department Head W. von Rüden and guided by ATLAS Collaboration Users S. Goldfarb, P. Nevski and L. Price.

  11. Reaction of allene esters with Selectfluor/TMSX (X = I, Br, Cl and Selectfluor/NH4SCN: Competing oxidative/electrophilic dihalogenation and nucleophilic/conjugate addition

    Directory of Open Access Journals (Sweden)

    A. Srinivas Reddy

    2015-09-01

    Full Text Available Reaction of benzyl and ethyl allenoates with TMSX (X = I, Br, Cl and with NH4SCN were investigated in MeCN, DMF, and in imidazolium ionic liquids [BMIM][NTf2] and [BMIM][PF6] as solvent, in the presence and absence of Selectfluor. Comparative product analysis studies demonstrate that the ability of Selectflour to promote oxidative/electrophilic dihalogenation/dithiocyanation with TMSX/NH4SCN (as observed previously for 1-arylallenes is diminished in allenoates, most significantly in reactions with TMSCl, and essentially disappearing in reactions with NH4SCN, in favor of nucleophilic/conjugate addition. The study underscores the contrasting reactivity patterns in 1-arylallenes and allenoates toward electrophilic and nucleophilic additions in halofunctionalization with TMSX/Selectfluor and thiocyanation reactions with NH4SCN/Selectfluor. These competing pathways are influenced by the nature of the anion, allene structure, and the choice of solvent.

  12. Computing transition rates for the 1-D stochastic Ginzburg--Landau--Allen--Cahn equation for finite-amplitude noise with a rare event algorithm

    CERN Document Server

    Rolland, J; Simonnet, E

    2015-01-01

    In this paper we compute and analyse the transition rates and duration of reactive trajectories of the stochastic 1-D Allen-Cahn equations for both the Freidlin-Wentzell regime (weak noise or temperature limit) and finite-amplitude white noise, as well as for small and large domain. We demonstrate that extremely rare reactive trajectories corresponding to direct transitions between two metastable states are efficiently computed using an algorithm called adaptive multilevel splitting. This algorithm is dedicated to the computation of rare events and is able to provide ensembles of reactive trajectories in a very efficient way. In the small noise limit, our numerical results are in agreement with large-deviation predictions such as instanton-like solutions, mean first passages and escape probabilities. We show that the duration of reactive trajectories follows a Gumbel distribution like for one degree of freedom systems. Moreover, the mean duration growths logarithmically with the inverse temperature. The prefa...

  13. Hydrogeologic framework and water quality of the Vermont Army National Guard Ethan Allen Firing Range, northern Vermont, October 2002 through December 2003

    Science.gov (United States)

    Clark, Stewart F.; Chalmers, Ann; Mack, Thomas J.; Denner, Jon C.

    2005-01-01

    The Ethan Allen Firing Range of the Vermont Army National Guard is a weapons-testing and training facility in a mountainous region of Vermont that has been in operation for about 80 years. The hydrologic framework and water quality of the facility were assessed between October 2002 and December 2003. As part of the study, streamflow was continuously measured in the Lee River and 24 observation wells were installed at 19 locations in the stratified drift and bedrock aquifers to examine the hydrogeology. Chemical analyses of surface water, ground water, streambed sediment, and fish tissue were collected to assess major ions, trace elements, nutrients, and volatile and semivolatile compounds. Sampling included 5 surface-water sites sampled during moderate and low-flow conditions; streambed-sediment samples collected at the 5 surface-water sites; fish-tissue samples collected at 3 of the 5 surface-water sites; macroinvertebrates collected at 4 of the 5 surface-water sites; and ground-water samples collected from 10 observation wells, and samples collected at all surface- and ground-water sites. The hydrogeologic framework at the Ethan Allen Firing Range is dominated by the upland mountain and valley setting of the site. Bedrock wells yield low to moderate amounts of water (0 to 23 liters per minute). In the narrow river valleys, layered stratified-drift deposits of sand and gravel of up to 18 meters thick fill the Lee River and Mill Brook Valleys. In these deposits, the water table is generally within 3 meters below the land surface and overall ground-water flow is from east to west. Streamflow in the Lee River averaged 0.72 cubic meters per second (25.4 cubic feet per second) between December 2002 and December 2003. Streams are highly responsive to precipitation events in this mountainous environment and a comparison with other nearby watersheds shows that Lee River maintains relatively high streamflow during dry periods. Concentrations of trace elements and nutrients

  14. Relativistic electron microbursts and variations in trapped MeV electron fluxes during the 8-9 October 2012 storm: SAMPEX and Van Allen Probes observations

    Science.gov (United States)

    Kurita, Satoshi; Miyoshi, Yoshizumi; Blake, J. Bernard; Reeves, Geoffery D.; Kletzing, Craig A.

    2016-04-01

    It has been suggested that whistler mode chorus is responsible for both acceleration of MeV electrons and relativistic electron microbursts through resonant wave-particle interactions. Relativistic electron microbursts have been considered as an important loss mechanism of radiation belt electrons. Here we report on the observations of relativistic electron microbursts and flux variations of trapped MeV electrons during the 8-9 October 2012 storm, using the SAMPEX and Van Allen Probes satellites. Observations by the satellites show that relativistic electron microbursts correlate well with the rapid enhancement of trapped MeV electron fluxes by chorus wave-particle interactions, indicating that acceleration by chorus is much more efficient than losses by microbursts during the storm. It is also revealed that the strong chorus wave activity without relativistic electron microbursts does not lead to significant flux variations of relativistic electrons. Thus, effective acceleration of relativistic electrons is caused by chorus that can cause relativistic electron microbursts.

  15. Enrico Fermi Awards Ceremony for Dr. Allen J. Bard and Dr. Andrew Sessler, February 2014 (Presentations, including remarks by Energy Secretary, Dr. Ernest Moniz)

    Energy Technology Data Exchange (ETDEWEB)

    Moniz, Ernest [U.S. Energy Secretary

    2014-02-03

    The Fermi Award is a Presidential award and is one of the oldest and most prestigious science and technology honors bestowed by the U.S. Government. On February 3, 2014 it was conferred upon two exceptional scientists. The first to be recognized is Dr. Allen J. Bard, 'for international leadership in electrochemical science and technology, for advances in photoelectrochemistry and photocatalytic materials, processes, and devices, and for discovery and development of electrochemical methods including electrogenerated chemiluminescence and scanning electrochemical microscopy.' The other honoree is Dr. Andrew Sessler, 'for advancing accelerators as powerful tools of scientific discovery, for visionary direction of the research enterprise focused on challenges in energy and the environment, and for championing outreach and freedom of scientific inquiry worldwide.' Dr. Patricia Dehmer opened the ceremony, and Dr. Ernest Moniz presented the awards.

  16. Container II

    OpenAIRE

    Baraklianou, Stella

    2016-01-01

    Container II, self-published artists book.\\ud The book was made on the occasion of the artists residency at the Banff Arts Centre, in Alberta Canada. \\ud \\ud Container II is a performative piece, it worked in conjunction with the photographic installation "Stage Set: Cool Tone" . (photographic floor installation, Reclaimed wood, frames, 130x145cm, 2016) \\ud The photographic installation was also part of the artists residency titled "New Materiality" at the Banff Arts Centre. \\ud \\ud Limited E...

  17. A Comparison of Van Allen Belt Radiation Environment Modeling Programs: AE8/AP8 Legacy, AE9/AP9, and SPENVIS

    Science.gov (United States)

    Reed, Evan; Pellish, Jonathan

    2016-01-01

    In the space surrounding Earth there exists an active radiation environment consisting mostly of electrons and protons that have been trapped by Earths magnetic field. This radiation, also known as the Van Allen Belts, has the potential to damage man-made satellites in orbit; thus, proper precautions must be taken to shield NASA assets from this phenomenon. Data on the Van Allen Belts has been collected continuously by a multitude of space-based instruments since the beginning of space exploration. Subsequently, using theory to fill in the gaps in the collected data, computer models have been developed that take in the orbital information of a hypothetical mission and output the expected particle fluence and flux for that orbit. However, as new versions of the modeling system are released, users are left wondering how the new version differs from the old. Therefore, we performed a comparison of three different editions of the modeling system: AE8/AP8 (legacy), which is included in the model 9 graphical user interface as an option for ones calculations, AE9/AP9, and the Space Environment Information System (SPENVIS), which is an online-based form of AE8/AP8 developed by NASA and the European Space Agency that changed the code to allow the program to extrapolate data to predict fluence and flux at higher energies. Although this evaluation is still ongoing, it is predicted that the model 8 (legacy) and SPENVIS version will have identical outputs with the exception of the extended energy levels from SPENVIS, while model 9 will provide different fluences than model 8 based on additional magnetic field descriptions and on-orbit data.

  18. TBscore II

    DEFF Research Database (Denmark)

    Rudolf, Frauke; Lemvik, Grethe; Abate, Ebba;

    2013-01-01

    Abstract Background: The TBscore, based on simple signs and symptoms, was introduced to predict unsuccessful outcome in tuberculosis patients on treatment. A recent inter-observer variation study showed profound variation in some variables. Further, some variables depend on a physician assessing...... them, making the score less applicable. The aim of the present study was to simplify the TBscore. Methods: Inter-observer variation assessment and exploratory factor analysis were combined to develop a simplified score, the TBscore II. To validate TBscore II we assessed the association between start...

  19. Facile, regioselective [4 + 2] cycloaddition involving 1-aryl-4-phenyl-1-azadienes and allenic esters: an efficient route to novel substituted 1-aryl-4-phenyl-1,4-dihydropyridines.

    Science.gov (United States)

    Ishar, M P; Kumar, K; Kaur, S; Kumar, S; Girdhar, N K; Sachar, S; Marwaha, A; Kapoor, A

    2001-07-12

    [reaction: see text]1-Aryl-4-phenyl-1-azadienes undergo facile, regioselective [4 + 2] cycloaddition to the C2,C3 pi-bond of allenic esters in refluxing benzene, and the formed adducts undergo a 1,3-H shift to afford novel 2-alkyl-1-aryl-3-ethoxycarbonyl-4-phenyl-1,4-dihydropyridines (78-97%). However, when the reaction is carried at room temperature, besides the [4 + 2] addition, the [2 + 2] mode of addition involving C=N of azadiene and C3,C4 pi-bond of allenic esters also intervenes. The resulting N-aryl-2-ethoxy-carbonyl-methylidene-4-styrylazetidines (17-28%) undergo reorganization on silica gel to afford 2-cyclohexen-1-ones.

  20. Suppression of Allene Oxide Cyclase in Hairy Roots of Medicago truncatula Reduces Jasmonate Levels and the Degree of Mycorrhization with Glomus intraradices1[w

    Science.gov (United States)

    Isayenkov, Stanislav; Mrosk, Cornelia; Stenzel, Irene; Strack, Dieter; Hause, Bettina

    2005-01-01

    During the symbiotic interaction between Medicago truncatula and the arbuscular mycorrhizal (AM) fungus Glomus intraradices, an endogenous increase in jasmonic acid (JA) occurs. Two full-length cDNAs coding for the JA-biosynthetic enzyme allene oxide cyclase (AOC) from M. truncatula, designated as MtAOC1 and MtAOC2, were cloned and characterized. The AOC protein was localized in plastids and found to occur constitutively in all vascular tissues of M. truncatula. In leaves and roots, MtAOCs are expressed upon JA application. Enhanced expression was also observed during mycorrhization with G. intraradices. A partial suppression of MtAOC expression was achieved in roots following transformation with Agrobacterium rhizogenes harboring the MtAOC1 cDNA in the antisense direction under control of the cauliflower mosaic virus 35S promoter. In comparison to samples transformed with 35S∷uidA, roots with suppressed MtAOC1 expression exhibited lower JA levels and a remarkable delay in the process of colonization with G. intraradices. Both the mycorrhization rate, quantified by fungal rRNA, and the arbuscule formation, analyzed by the expression level of the AM-specific gene MtPT4, were affected. Staining of fungal material in roots with suppressed MtAOC1 revealed a decreased number of arbuscules, but these did not exhibit an altered structure. Our results indicate a crucial role for JA in the establishment of AM symbiosis. PMID:16244141

  1. Suppression of allene oxide cyclase in hairy roots of Medicago truncatula reduces jasmonate levels and the degree of mycorrhization with Glomus intraradices.

    Science.gov (United States)

    Isayenkov, Stanislav; Mrosk, Cornelia; Stenzel, Irene; Strack, Dieter; Hause, Bettina

    2005-11-01

    During the symbiotic interaction between Medicago truncatula and the arbuscular mycorrhizal (AM) fungus Glomus intraradices, an endogenous increase in jasmonic acid (JA) occurs. Two full-length cDNAs coding for the JA-biosynthetic enzyme allene oxide cyclase (AOC) from M. truncatula, designated as MtAOC1 and MtAOC2, were cloned and characterized. The AOC protein was localized in plastids and found to occur constitutively in all vascular tissues of M. truncatula. In leaves and roots, MtAOCs are expressed upon JA application. Enhanced expression was also observed during mycorrhization with G. intraradices. A partial suppression of MtAOC expression was achieved in roots following transformation with Agrobacterium rhizogenes harboring the MtAOC1 cDNA in the antisense direction under control of the cauliflower mosaic virus 35S promoter. In comparison to samples transformed with 35SuidA, roots with suppressed MtAOC1 expression exhibited lower JA levels and a remarkable delay in the process of colonization with G. intraradices. Both the mycorrhization rate, quantified by fungal rRNA, and the arbuscule formation, analyzed by the expression level of the AM-specific gene MtPT4, were affected. Staining of fungal material in roots with suppressed MtAOC1 revealed a decreased number of arbuscules, but these did not exhibit an altered structure. Our results indicate a crucial role for JA in the establishment of AM symbiosis.

  2. Simulation of a hump structure in the optical scattering rate within a generalized Allen formalism and its application to copper oxide systems.

    Science.gov (United States)

    Hwang, Jungseek

    2013-07-24

    We propose a possible way to simulate a hump structure in the optical scattering rate. The optical scattering rate of correlated charge carriers can be defined within an extended Drude model formalism. When some electron- and hole-doped copper oxide systems are in spin density or charge density wave phases they show hump structures in their optical scattering rates. The hump structures have not yet been simulated or clearly understood. We are able to simulate the hump structure by using a peak followed by a dip feature in the normalized density of states within a generalized Allen formalism. We observe that reversing the order of the dip and peak gives completely different features in the optical scattering rate; a peak-dip (dip-peak) results in a hump (a valley) in the scattering rate. We also obtain the real parts of the optical conductivity and reflectance spectra from the simulated optical scattering rate and compare them with published experimental spectra. From these comparisons we conclude that the peak-dip order can give the hump structure that is observed experimentally in copper oxide systems. Finally we fit two published optical spectra with our new model and discuss our results and the possible origin of the dip or peak features in the normalized density of states.

  3. MIDL: A Demonstration of Multi-Mission Analysis of Charged Particle Data From Van Allen Probes and the Juno Earth Flyby

    Science.gov (United States)

    Brown, L. E.; Mitchell, D. G.; Paranicas, C.; Mauk, B.; Lanzerotti, L. J.; Vandegriff, J. D.

    2013-12-01

    At the present time, a fleet of heliosphere spacecraft is producing an unprecedented number of measurements of charged particles and magnetic fields throughout the solar system - from Mercury to the local interstellar medium. It is vital to have a flexible and efficient data browsing, discovery, and analysis environment to navigate this wealth of information. We present a multi-mission tool for quick look data viewing and analysis. In addition to a rich tool and feature set, MIDL3 (Mission Independent Data Layer - 3rd version) provides environments to cater to different user classes from instrument team engineers, to team scientists, to the general science community. Furthermore, MIDL3 adds a new, highly interactive, end-user visualization environment for rapid browsing and exploration of science and engineering data. Like AMDA and MAPSVIEW, MIDL has functioned for Cassini plasma and particle data as a highly successful platform for inter-comparing different instruments/sensors with minimal preparation work on the part of the user. We present a demonstration of simultaneous analysis of the JUNO Earth flyby (October 9, 2013) data from the JEDI instruments and Van Allen Probes data from the RBSPICE instruments. Since these two instrument sets share a very similar design (see presentations by C Paranicas, et al. and J Manwiler, et al. at this conference for details) we anticipate important results from this unique opportunity to compare measurements of energetic electrons and ions made by six telescopes each for the five similar instruments on three spacecraft within Earth's magnetosphere.

  4. Lower hybrid frequency range waves generated by ion polarization drift due to electromagnetic ion cyclotron waves: Analysis of an event observed by the Van Allen Probe B

    Science.gov (United States)

    Khazanov, G. V.; Boardsen, S.; Krivorutsky, E. N.; Engebretson, M. J.; Sibeck, D.; Chen, S.; Breneman, A.

    2017-01-01

    We analyze a wave event that occurred near noon between 07:03 and 07:08 UT on 23 February 2014 detected by the Van Allen Probes B spacecraft, where waves in the lower hybrid frequency range (LHFR) and electromagnetic ion cyclotron (EMIC) waves are observed to be highly correlated, with Pearson correlation coefficient of 0.86. We assume that the correlation is the result of LHFR wave generation by the ions' polarization drift in the electric field of the EMIC waves. To check this assumption the drift velocities of electrons and H+, He+, and O+ ions in the measured EMIC wave electric field were modeled. Then the LHFR wave linear instantaneous growth rates for plasma with these changing drift velocities and different plasma compositions were calculated. The time distribution of these growth rates, their frequency distribution, and the frequency dependence of the ratio of the LHFR wave power spectral density (PSD) parallel and perpendicular to the ambient magnetic field to the total PSD were found. These characteristics of the growth rates were compared with the corresponding characteristics of the observed LHFR activity. Reasonable agreement between these features and the strong correlation between EMIC and LHFR energy densities support the assumption that the LHFR wave generation can be caused by the ions' polarization drift in the electric field of an EMIC wave.

  5. Improvement of copper tolerance of Arabidopsis by transgenic expression of an allene oxide cyclase gene, GhAOC1, in upland cotton (Gossypium hirsutum L.)

    Institute of Scientific and Technical Information of China (English)

    Yuange Wang; Huaihua Liu; Qingguo Xin

    2015-01-01

    Allene oxide cyclase (AOC, E 5.3.99.6) is an essential enzyme in the jasmonic acid (JA) biosynthetic pathway and mediates a wide range of adaptive responses. In this report, five AOC genes (GhAOC1–GhAOC5) were cloned from upland cotton (Gossypium hirsutum L.), sequenced, and characterized. Real-time PCR analysis indicated that the transcripts of GhAOCs were abundantly expressed in roots and less in fibers, and regulated in cotton plants under methyl jasmonate (MeJA) and CuCl2 stresses. To investigate the role of GhAOC under copper stress, transgenic Arabidopsis plants overexpressing cotton GhAOC1 under control of the Cauliflower mosaic virus 35S (CaMV 35S) promoter were generated. Compared to untransformed plants, GhAOC1-overexpressing Arabidopsis thaliana plants exhibited markedly higher survival rate, shoot fresh weight, shoot dry weight, and photosynthetic efficiency, and reduced cell membrane damage and lipid peroxidation under copper stress. This study provides the first evidence that GhAOC1 plays an important role in copper stress tolerance.

  6. Improvement of copper tolerance of Arabidopsis by transgenic expression of an allene oxide cyclase gene, GhAOC1, in upland cotton (Gossypium hirsutum L.

    Directory of Open Access Journals (Sweden)

    Yuange Wang

    2015-08-01

    Full Text Available Allene oxide cyclase (AOC, E 5.3.99.6 is an essential enzyme in the jasmonic acid (JA biosynthetic pathway and mediates a wide range of adaptive responses. In this report, five AOC genes (GhAOC1–GhAOC5 were cloned from upland cotton (Gossypium hirsutum L., sequenced, and characterized. Real-time PCR analysis indicated that the transcripts of GhAOCs were abundantly expressed in roots and less in fibers, and regulated in cotton plants under methyl jasmonate (MeJA and CuCl2 stresses. To investigate the role of GhAOC under copper stress, transgenic Arabidopsis plants overexpressing cotton GhAOC1 under control of the Cauliflower mosaic virus 35S (CaMV 35S promoter were generated. Compared to untransformed plants, GhAOC1-overexpressing Arabidopsis thaliana plants exhibited markedly higher survival rate, shoot fresh weight, shoot dry weight, and photosynthetic efficiency, and reduced cell membrane damage and lipid peroxidation under copper stress. This study provides the first evidence that GhAOC1 plays an important role in copper stress tolerance.

  7. Non-Linear Model for the Disturbance of Electronics in by High Energy Electron Plasmas in the Van Allen Radiation Belts

    Science.gov (United States)

    Atkinson, William

    2009-11-01

    A model is presented that models the disturbance of electrical components by high energy electrons trapped in the Van Allen radiation belts; the model components consists of module computing the electron fluence rate given the altitude, the time of the year, and the sunspot number, a module that transports the electrons through the materials of the electrical component, and a module that computes the charge and electrical fields of the insulating materials as a function of time. A non-linear relationship (the Adameic-Calderwood equation) for the variation of the electrical conductivity with the electrical field strength is used as the field intensities can be quite high due to the small size of the electrical components and the high fluence rate of the electrons. The results show that the electric fields can often be as high as 10 MV/m in materials commonly used in cables such as Teflon and that the field can stay at high levels as long as an hour after the irradiation ends.

  8. Inferring electromagnetic ion cyclotron wave intensity from low altitude POES proton flux measurements: A detailed case study with conjugate Van Allen Probes observations

    Science.gov (United States)

    Zhang, Yang; Shi, Run; Ni, Binbin; Gu, Xudong; Zhang, Xianguo; Zuo, Pingbing; Fu, Song; Xiang, Zheng; Wang, Qi; Cao, Xing; Zou, Zhengyang

    2017-03-01

    Electromagnetic ion cyclotron (EMIC) waves play an important role in the magnetospheric particle dynamics and can lead to resonant pitch-angle scattering and ultimate precipitation of ring current protons. Commonly, the statistics of in situ EMIC wave measurements is adopted for quantitative investigation of wave-particle interaction processes, which however becomes questionable for detailed case studies especially during geomagnetic storms and substorms. Here we establish a novel technique to infer EMIC wave amplitudes from low-altitude proton measurements onboard the Polar Operational Environmental Satellites (POES). The detailed procedure is elaborated regarding how to infer the EMIC wave intensity for one specific time point. We then test the technique with a case study comparing the inferred root-mean-square (RMS) EMIC wave amplitude with the conjugate Van Allen Probes EMFISIS wave measurements. Our results suggest that the developed technique can reasonably estimate EMIC wave intensities from low-altitude POES proton flux data, thereby providing a useful tool to construct a data-based, near-real-time, dynamic model of the global distribution of EMIC waves once the proton flux measurements from multiple POES satellites are available for any specific time period.

  9. The Allen Telescope Array Twenty-centimeter Survey - A 690-Square-Degree, 12-Epoch Radio Dataset - I: Catalog and Long-Duration Transient Statistics

    CERN Document Server

    Croft, Steve; Ackermann, Rob; Atkinson, Shannon; Backer, Don; Backus, Peter; Barott, William C; Bauermeister, Amber; Blitz, Leo; Bock, Douglas; Bradford, Tucker; Cheng, Calvin; Cork, Chris; Davis, Mike; DeBoer, Dave; Dexter, Matt; Dreher, John; Engargiola, Greg; Fields, Ed; Fleming, Matt; Forster, James R; Gutierrez-Kraybill, Colby; Harp, Gerry; Helfer, Tamara; Hull, Chat; Jordan, Jane; Jorgensen, Susanne; Keating, Garrett; Kilsdonk, Tom; Law, Casey; van Leeuwen, Joeri; Lugten, John; MacMahon, Dave; McMahon, Peter; Milgrome, Oren; Pierson, Tom; Randall, Karen; Ross, John; Shostak, Seth; Siemion, Andrew; Smolek, Ken; Tarter, Jill; Thornton, Douglas; Urry, Lynn; Vitouchkine, Artyom; Wadefalk, Niklas; Welch, Jack; Werthimer, Dan; Whysong, David; Williams, Peter K G; Wright, Melvyn

    2010-01-01

    We present the Allen Telescope Array Twenty-centimeter Survey (ATATS), a multi-epoch (12 visits), 690 square degree radio image and catalog at 1.4GHz. The survey is designed to detect rare, very bright transients as well as to verify the capabilities of the ATA to form large mosaics. The combined image using data from all 12 ATATS epochs has RMS noise sigma = 3.94mJy / beam and dynamic range 180, with a circular beam of 150 arcsec FWHM. It contains 4408 sources to a limiting sensitivity of S = 20 mJy / beam. We compare the catalog generated from this 12-epoch combined image to the NRAO VLA Sky Survey (NVSS), a legacy survey at the same frequency, and find that we can measure source positions to better than ~20 arcsec. For sources above the ATATS completeness limit, the median flux density is 97% of the median value for matched NVSS sources, indicative of an accurate overall flux calibration. We examine the effects of source confusion due to the effects of differing resolution between ATATS and NVSS on our abi...

  10. Improvement of copper tolerance of Arabidopsis by transgenic expression of an allene oxide cyclase gene,GhA OC1, in upland cotton(Gossypium hirsutum L.)

    Institute of Scientific and Technical Information of China (English)

    Yuange; Wang; Huaihua; Liu; Qingguo; Xin

    2015-01-01

    Allene oxide cyclase(AOC, E 5.3.99.6) is an essential enzyme in the jasmonic acid(JA)biosynthetic pathway and mediates a wide range of adaptive responses. In this report, five AOC genes(Gh AOC1–Gh AOC5) were cloned from upland cotton(Gossypium hirsutum L.),sequenced, and characterized. Real-time PCR analysis indicated that the transcripts of Gh AOCs were abundantly expressed in roots and less in fibers, and regulated in cotton plants under methyl jasmonate(Me JA) and Cu Cl2 stresses. To investigate the role of Gh AOC under copper stress, transgenic Arabidopsis plants overexpressing cotton Gh AOC1 under control of the Cauliflower mosaic virus 35S(Ca MV 35S) promoter were generated. Compared to untransformed plants, Gh AOC1-overexpressing Arabidopsis thaliana plants exhibited markedly higher survival rate, shoot fresh weight, shoot dry weight, and photosynthetic efficiency, and reduced cell membrane damage and lipid peroxidation under copper stress.This study provides the first evidence that Gh AOC1 plays an important role in copper stress tolerance.

  11. Carotenoid composition of the flowers of Mimulus lewisii and related species: Implications regarding the prevalence and origin of two unique, allenic pigments.

    Science.gov (United States)

    LaFountain, Amy M; Frank, Harry A; Yuan, Yao-Wu

    2015-05-01

    The genus Mimulus has been used as a model system in a wide range of ecological and evolutionary studies and contains many species with carotenoid pigmented flowers. However, the detailed carotenoid composition of these flowers has never been reported. In this paper the floral carotenoid composition of 11 Mimulus species are characterized using high-performance liquid chromatography, mass spectrometry and chemical methods with a particular focus on the genetic model species, Mimulus lewisii. M. lewisii flowers have five major carotenoids: antheraxanthin, violaxanthin, neoxanthin, and the unique allenic carotenoids, deepoxyneoxanthin and mimulaxanthin. This carotenoid profile is consistent with the expression levels of putative carotenoid biosynthetic genes in the M. lewisii flower. The other 10 species possess the same five carotenoids or a subset of these. Comparison of the carotenoid profiles among species in a phylogenetic context provides new insights into the biosynthesis and evolution of deepoxyneoxanthin and mimulaxanthin. This work also lays the foundation for future studies regarding transcriptional control of the carotenoid biosynthesis pathway in Mimulus flowers.

  12. Using the cold plasma dispersion relation and whistler mode waves to quantify the antenna sheath impedance of the Van Allen Probes EFW instrument

    Science.gov (United States)

    Hartley, D. P.; Kletzing, C. A.; Kurth, W. S.; Bounds, S. R.; Averkamp, T. F.; Hospodarsky, G. B.; Wygant, J. R.; Bonnell, J. W.; Santolík, O.; Watt, C. E. J.

    2016-05-01

    Cold plasma theory and parallel wave propagation are often assumed when approximating the whistler mode magnetic field wave power from electric field observations. The current study is the first to include the wave normal angle from the Electric and Magnetic Field Instrument Suite and Integrated Science package on board the Van Allen Probes in the conversion factor, thus allowing for the accuracy of these assumptions to be quantified. Results indicate that removing the assumption of parallel propagation does not significantly affect calculated plasmaspheric hiss wave powers. Hence, the assumption of parallel propagation is valid. For chorus waves, inclusion of the wave normal angle in the conversion factor leads to significant alterations in the distribution of wave power ratios (observed/ calculated); the percentage of overestimates decreases, the percentage of underestimates increases, and the spread of values is significantly reduced. Calculated plasmaspheric hiss wave powers are, on average, a good estimate of those observed, whereas calculated chorus wave powers are persistently and systematically underestimated. Investigation of wave power ratios (observed/calculated), as a function of frequency and plasma density, reveals a structure consistent with signal attenuation via the formation of a plasma sheath around the Electric Field and Waves spherical double probes instrument. A simple, density-dependent model is developed in order to quantify this effect of variable impedance between the electric field antenna and the plasma interface. This sheath impedance model is then demonstrated to be successful in significantly improving agreement between calculated and observed power spectra and wave powers.

  13. Felipe II

    Directory of Open Access Journals (Sweden)

    Carlos Restrepo Canal

    1962-04-01

    Full Text Available Como parte de la monumental Historia de España que bajo la prestante y acertadísima dirección de don Ramón Menéndez Pidal se comenzó a dar a la prensa desde 1954 por la Editorial Espasa Calpe S. A., aparecieron en 1958 dos tomos dedicados al reinado de Felipe II; aquella época en que el imperio español alcanzó su unidad peninsular juntamente con el dilatado poderío que le constituyó en la primera potencia de Europa.

  14. Wirkungen des SGB II auf Personen mit Migrationshintergrund: Projekt IIa1 - 04/06 ; Jahresbericht zum 31.12.2008 - Hauptband

    OpenAIRE

    2009-01-01

    Auf Grundlage von Geschäftsdaten, von repräsentativen telefonischen Befragungen und von qualitativen Interviews mit Betroffenen und Fallmanagern wurden die Wirkungen der "Grundsicherung für Arbeitsuchende" auf Migrant/innen untersucht. Ihr Anteil an allen ALG-II Beziehenden beträgt im bundesweiten Durchschnitt 28 Prozent. Im Vergleich zu denjenigen ohne Migrationshintergrund sind sie im Durchschnitt jünger und haben häufiger keinen, aber auch häufiger höhere (Aus-)Bildungsabschlüsse. Die häuf...

  15. Rapid enhancement of low-energy (shocks based on two Van Allen Probes case studies: Implications for source regions and heating mechanisms

    Science.gov (United States)

    Yue, Chao; Li, Wen; Nishimura, Yukitoshi; Zong, Qiugang; Ma, Qianli; Bortnik, Jacob; Thorne, Richard M.; Reeves, Geoffrey D.; Spence, Harlan E.; Kletzing, Craig A.; Wygant, John R.; Nicolls, Michael J.

    2016-07-01

    Interactions between interplanetary (IP) shocks and the Earth's magnetosphere manifest many important space physics phenomena including low-energy ion flux enhancements and particle acceleration. In order to investigate the mechanisms driving shock-induced enhancement of low-energy ion flux, we have examined two IP shock events that occurred when the Van Allen Probes were located near the equator while ionospheric and ground observations were available around the spacecraft footprints. We have found that, associated with the shock arrival, electromagnetic fields intensified, and low-energy ion fluxes, including H+, He+, and O+, were enhanced dramatically in both the parallel and perpendicular directions. During the 2 October 2013 shock event, both parallel and perpendicular flux enhancements lasted more than 20 min with larger fluxes observed in the perpendicular direction. In contrast, for the 15 March 2013 shock event, the low-energy perpendicular ion fluxes increased only in the first 5 min during an impulse of electric field, while the parallel flux enhancement lasted more than 30 min. In addition, ionospheric outflows were observed after shock arrivals. From a simple particle motion calculation, we found that the rapid response of low-energy ions is due to drifts of plasmaspheric population by the enhanced electric field. However, the fast acceleration in the perpendicular direction cannot solely be explained by E × B drift but betatron acceleration also plays a role. Adiabatic acceleration may also explain the fast response of the enhanced parallel ion fluxes, while ion outflows may contribute to the enhanced parallel fluxes that last longer than the perpendicular fluxes.

  16. Computing Transition Rates for the 1-D Stochastic Ginzburg-Landau-Allen-Cahn Equation for Finite-Amplitude Noise with a Rare Event Algorithm

    Science.gov (United States)

    Rolland, Joran; Bouchet, Freddy; Simonnet, Eric

    2016-01-01

    In this article we compute and analyse the transition rates and duration of reactive trajectories of the stochastic 1-D Allen-Cahn equations for both the Freidlin-Wentzell regime (weak noise or temperature limit) and finite-amplitude white noise, as well as for small and large domain. We demonstrate that extremely rare reactive trajectories corresponding to direct transitions between two metastable states are efficiently computed using an algorithm called adaptive multilevel splitting. This algorithm is dedicated to the computation of rare events and is able to provide ensembles of reactive trajectories in a very efficient way. In the small noise limit, our numerical results are in agreement with large-deviation predictions such as instanton-like solutions, mean first passages and escape probabilities. We show that the duration of reactive trajectories follows a Gumbel distribution like for one degree of freedom systems. Moreover, the mean duration growths logarithmically with the inverse temperature. The prefactor given by the potential curvature grows exponentially with size. The main novelty of our work is that we also perform an analysis of reactive trajectories for large noises and large domains. In this case, we show that the position of the reactive front is essentially a random walk. This time, the mean duration grows linearly with the inverse temperature and quadratically with the size. Using a phenomenological description of the system, we are able to calculate the transition rate, although the dynamics is described by neither Freidlin-Wentzell or Eyring-Kramers type of results. Numerical results confirm our analysis.

  17. Reactions of Cg10062, a cis-3-Chloroacrylic Acid Dehalogenase Homologue, with Acetylene and Allene Substrates: Evidence for a Hydration-Dependent Decarboxylation.

    Science.gov (United States)

    Huddleston, Jamison P; Johnson, William H; Schroeder, Gottfried K; Whitman, Christian P

    2015-05-19

    Cg10062 is a cis-3-chloroacrylic acid dehalogenase (cis-CaaD) homologue from Corynebacterium glutamicum with an unknown function and an uninformative genomic context. It shares 53% pairwise sequence similarity with cis-CaaD including the six active site amino acids (Pro-1, His-28, Arg-70, Arg-73, Tyr-103, and Glu-114) that are critical for cis-CaaD activity. However, Cg10062 is a poor cis-CaaD: it lacks catalytic efficiency and isomer specificity. Two acetylene compounds (propiolate and 2-butynoate) and an allene compound, 2,3-butadienoate, were investigated as potential substrates. Cg10062 functions as a hydratase/decarboxylase using propiolate as well as the cis-3-chloro- and 3-bromoacrylates, generating mixtures of malonate semialdehyde and acetaldehyde. The two activities occur sequentially at the active site using the initial substrate. With 2,3-butadienoate and 2-butynoate, Cg10062 functions as a hydratase and converts both to acetoacetate. Mutations of the proposed water-activating residues (E114Q, E114D, and Y103F) have a range of consequences from a reduction in wild type activity to a switch of activities (i.e., hydratase into a hydratase/decarboxylase or vice versa). The intermediates for the hydration and decarboxylation products can be trapped as covalent adducts to Pro-1 when NaCNBH3 is incubated with the E114D mutant and 2,3-butadienoate or 2-butynoate, and the Y103F mutant and 2-butynoate. Three mechanisms are presented to explain these findings. One mechanism involves the direct attack of water on the substrate, whereas the other two mechanisms use covalent catalysis in which a covalent bond forms between Pro-1 and the hydration product or the substrate. The strengths and weaknesses of the mechanisms and the implications for Cg10062 function are discussed.

  18. Synthesis of unsymmetrical substituted 1,4-dihydropyridines through thermal and microwave assisted [4+2] cycloadditions of 1-azadienes and allenic esters.

    Science.gov (United States)

    Singh, Lakhwinder; Ishar, M P Singh; Elango, Munusamy; Subramanian, Venkatesan; Gupta, Vivek; Kanwal, Priyanka

    2008-03-21

    Thermal and microwave assisted [4+2] cycloadditions of 1,4-diaryl-1-aza-1,3-butadienes with allenic esters lead to cycloadducts, which after a 1,3-H shift afford variedly substituted unsymmetrical 2-alkyl-1,4-diaryl-3-ethoxycarbonyl-1,4-dihydropyridines in high yields. Reactions carried out under microwave irradiation are cleaner and give higher yields with much shortened reaction times. Density functional theory (DFT) at the B3LYP/6-31G* level has been used to calculate geometric features of the reactants, barrier for s-trans to s-cis and reverse isomerization of azadienes (5a-d, 10a-e), dihedral angles between N(1), C(2), C(3), and C(4) atoms of azadienes along with various indices such as chemical hardness (eta), chemical potential (micro), global electrophilicity (omega), and the difference in global electrophilicity (Deltaomega) between the reacting pairs and Fukui functions (f (+) and f(-)). The results revealed that s-trans is the predominant conformation of azadienes at ambient temperature and the barrier for conversion of the s-trans rotamer of 1-azadienes to s-cis may be the major factor influencing the chemoselectivity, i.e., [4+2] verses [2+2] cycloaddition. The regiochemistry of the observed cycloadditions is collated with the obtained local electrophilicity indices (Fukui functions). Transition states for the formation of both [4+2] and [2+2] cycloadducts as located at the PM3 level indicate that the transition state for the formation of [4+2] cycloadducts has lower energy, again supporting the earlier conclusion that preferred formation of [4+2] cycloaaducts at higher temperature may be a consequence of barrier for s-trans to s-cis transformation of 1-azadienes.

  19. ALLEN COUNTY, KANSAS, USA, REDELINEATION, Allen County, KANSAS

    Data.gov (United States)

    Federal Emergency Management Agency, Department of Homeland Security — The Floodplain Mapping/Redelineation study deliverables depict and quantify the flood risks for the study area. The primary risk classifications used are the...

  20. Small Diameter Bomb Increment II (SDB II)

    Science.gov (United States)

    2015-12-01

    Bomb Increment II (SDB II) DoD Component Air Force Joint Participants Department of the Navy Responsible Office References SAR Baseline ( Production ...Selected Acquisition Report (SAR) RCS: DD-A&T(Q&A)823-439 Small Diameter Bomb Increment II (SDB II) As of FY 2017 President’s Budget Defense...Funding 19 Low Rate Initial Production 31 Foreign Military Sales 32 Nuclear Costs 32 Unit Cost 33 Cost Variance 36 Contracts

  1. Enantioselective Cyclopropanation of a Wide Variety of Olefins Catalyzed by Ru(II)-Pheox Complexes.

    Science.gov (United States)

    Chanthamath, Soda; Iwasa, Seiji

    2016-10-18

    The transition-metal-catalyzed asymmetric cyclopropanation of olefins with diazoacetates has become one of the most important methods for the synthesis of optically active cyclopropane derivatives, which are key pharmaceutical building blocks and present in a large number of natural products. To date, significant progress has been made in this area of research, and efficient stereocontrolled synthetic approaches to cyclopropane derivatives have been developed using rhodium, ruthenium, copper, and cobalt catalysts. However, the vast majority of these strategies are limited to electron-rich olefins, such as styrene derivatives, due to the electrophilicity of the metal-carbene intermediates generated from the reaction of the metal with the diazo compound. Recently, the D2-symmetric Co(II)-phophyrin complexes developed by Zhang et al. were shown to be the most efficient catalysts for the asymmetric cyclopropanation of electron-deficient olefins. This catalytic system is mechanistically distinct from the previous rhodium and copper catalytic systems, proceeding via radical intermediates. However, the asymmetric cyclopropanation of vinyl carbamates, allenes, and α,β-unsaturated carbonyl compounds has rarely been reported. Therefore, the development of new powerful catalysts for the asymmetric cyclopropanation of a wide range of olefinic substrates is the next challenge in this field. In this Account, we summarize our recent studies on the Ru(II)-Pheox-catalyzed asymmetric cyclopropanation of various olefins, including vinyl carbamates, allenes, and α,β-unsaturated carbonyl compounds. We demonstrate that the developed catalytic system effectively promotes the asymmetric cyclopropanation of a wide variety of olefins to produce the desired cyclopropane products in high yields with excellent stereocontrol. The use of succinimidyl-, ketone-, and ester-functionalized diazoacetates as carbene sources was found to be crucial for the high stereoselectivity of the

  2. Elizabeth II uus kunstigalerii

    Index Scriptorium Estoniae

    1999-01-01

    Tähistamaks oma troonile asumise 50. aastapäeva, avab Elizabeth II 6. II 2002 Buckinghami palees uue kunstigalerii, mis ehitatakse palee tiibhoonena. Arhitekt John Simpson. Elizabeth II kunstikogust

  3. Synthesis of 5-(2-methoxy-1-naphthyl- and 5-[2-(methoxymethyl-1-naphthyl]-11H-benzo[b]fluorene as 2,2'-disubstituted 1,1'-binaphthyls via benzannulated enyne–allenes

    Directory of Open Access Journals (Sweden)

    Kung K. Wang

    2011-04-01

    Full Text Available 5-(2-Methoxy-1-naphthyl- and 5-[2-(methoxymethyl-1-naphthyl]-11H-benzo[b]fluorene were synthesized by treatment of the corresponding benzannulated enediynes with potassium tert-butoxide in refluxing toluene to give benzannulated enyne–allenes for the subsequent Schmittel cascade cyclization reactions. The structures of these two 5-(1-naphthyl-11H-benzo[b]fluorenes could be regarded as 2,2'-disubstituted 1,1'-binaphthyls with the newly constructed benzofluorenyl group serving as a naphthyl moiety.

  4. FLOODPLAIN, Allen COUNTY, KENTUCKY USA

    Data.gov (United States)

    Federal Emergency Management Agency, Department of Homeland Security — The Floodplain Mapping/Redelineation study deliverables depict and quantify the flood risks for the study area. The primary risk classifications used are the...

  5. HYDROLOGY, ALLEN COUNTY, KENTUCKY USA

    Data.gov (United States)

    Federal Emergency Management Agency, Department of Homeland Security — Hydrology data include spatial datasets and data tables necessary for documenting the hydrologic procedures for estimating flood discharges for a flood insurance...

  6. Floodplain, Allen County, OHIO, USA

    Data.gov (United States)

    Federal Emergency Management Agency, Department of Homeland Security — The Floodplain Mapping study deliverables depict and quantify the flood risks for the study area. The primary risk classifications used are the...

  7. floodzones_allen_FEMA_1999

    Data.gov (United States)

    Louisiana Geographic Information Center — The Q3 Flood Data are derived from the Flood Insurance Rate Maps (FIRMS) published by the Federal Emergency Management Agency (FEMA). The file is georeferenced to...

  8. Small Diameter Bomb Increment II (SDB II)

    Science.gov (United States)

    2013-12-01

    been further delays to the F-35 System Development and Demonstration ( SDD ) program. As a result, the SDB II integration will be accomplished as a...follow-on integration to the F-35 SDD . SDB II OT&E on the F-35 will not be completed by the FRP threshold of October 2019, thus delaying the FRP decision

  9. Factor II deficiency

    Science.gov (United States)

    ... if one or more of these factors are missing or are not functioning like they should. Factor II is one such coagulation factor. Factor II deficiency runs in families (inherited) and is very rare. Both parents must ...

  10. Space Earthquake Perturbation Simulation (SEPS) an application based on Geant4 tools to model and simulate the interaction between the Earthquake and the particle trapped on the Van Allen belt

    Science.gov (United States)

    Ambroglini, Filippo; Jerome Burger, William; Battiston, Roberto; Vitale, Vincenzo; Zhang, Yu

    2014-05-01

    During last decades, few space experiments revealed anomalous bursts of charged particles, mainly electrons with energy larger than few MeV. A possible source of these bursts are the low-frequency seismo-electromagnetic emissions, which can cause the precipitation of the electrons from the lower boundary of their inner belt. Studies of these bursts reported also a short-term pre-seismic excess. Starting from simulation tools traditionally used on high energy physics we developed a dedicated application SEPS (Space Perturbation Earthquake Simulation), based on the Geant4 tool and PLANETOCOSMICS program, able to model and simulate the electromagnetic interaction between the earthquake and the particles trapped in the inner Van Allen belt. With SEPS one can study the transport of particles trapped in the Van Allen belts through the Earth's magnetic field also taking into account possible interactions with the Earth's atmosphere. SEPS provides the possibility of: testing different models of interaction between electromagnetic waves and trapped particles, defining the mechanism of interaction as also shaping the area in which this takes place,assessing the effects of perturbations in the magnetic field on the particles path, performing back-tracking analysis and also modelling the interaction with electric fields. SEPS is in advanced development stage, so that it could be already exploited to test in details the results of correlation analysis between particle bursts and earthquakes based on NOAA and SAMPEX data. The test was performed both with a full simulation analysis, (tracing from the position of the earthquake and going to see if there were paths compatible with the burst revealed) and with a back-tracking analysis (tracing from the burst detection point and checking the compatibility with the position of associated earthquake).

  11. Crossed-beam reaction of carbon atoms with hydrocarbon molecules. V. Chemical dynamics of n-C4H3 formation from reaction of C(3Pj) with allene, H2CCCH2(X 1A1)

    Science.gov (United States)

    Kaiser, R. I.; Mebel, A. M.; Chang, A. H. H.; Lin, S. H.; Lee, Y. T.

    1999-06-01

    The crossed molecular beams technique was employed to investigate the reaction between ground state carbon atoms, C(3Pj), and allene, H2CCCH2(X 1A1), at two averaged collision energies of 19.6 and 38.8 kJ mol-1. Product angular distributions and time-of-flight spectra of C4H3 were recorded. Forward-convolution fitting of the data yields weakly polarized center-of-mass angular flux distributions isotropic at lower, but forward scattered with respect to the carbon beam at a higher collision energy. The maximum translational energy release and the angular distributions combined with ab initio and RRKM calculations are consistent with the formation of the n-C4H3 radical in its electronic ground state. The channel to the i-C4H3 isomer contributes less than 1.5%. Reaction dynamics inferred from the experimental data indicate that the carbon atom attacks the π-orbitals of the allenic carbon-carbon double bond barrierless via a loose, reactant-like transition state located at the centrifugal barrier. The initially formed cyclopropylidene derivative rotates in a plane almost perpendicular to the total angular momentum vector around its C-axis and undergoes ring opening to triplet butatriene. At higher collision energy, the butatriene complex decomposes within 0.6 ps via hydrogen emission to form the n-C4H3 isomer and atomic hydrogen through an exit transition state located 9.2 kJ mol-1 above the products. The explicit identification of the n-C4H3 radical under single collision represents a further example of a carbon-hydrogen exchange in reactions of ground state carbon atoms with unsaturated hydrocarbons. This channel opens a barrierless route to synthesize extremely reactive hydrocarbon radicals in combustion processes, interstellar chemistry, and hydrocarbon-rich atmospheres of Jupiter, Saturn, Titan, as well as Triton.

  12. Quininium tetrachloridozinc(II

    Directory of Open Access Journals (Sweden)

    Li-Zhuang Chen

    2009-10-01

    Full Text Available The asymmetric unit of the title compound {systematic name: 2-[hydroxy(6-methoxyquinolin-1-ium-4-ylmethyl]-8-vinylquinuclidin-1-ium tetrachloridozinc(II}, (C20H26N2O2[ZnCl4], consists of a double protonated quininium cation and a tetrachloridozinc(II anion. The ZnII ion is in a slightly distorted tetrahedral coordination environment. The crystal structure is stabilized by intermolecular N—H...Cl and O—H...Cl hydrogen bonds.

  13. Hydrosol II Project; El Proyecto Hydrosol II

    Energy Technology Data Exchange (ETDEWEB)

    Lopez Martinez, A.

    2008-07-01

    At present energy production is based on the combustion of fossil fuels and is the main cause of greenhouse gas emissions, which is to say it is the main cause of the climate change that is affecting the planet. On a worldwide scale, the use of solar concentration systems with systems capable of dissociating water is considered, from both an energy and an economic standpoint, as the most important long-term goal in the production of solar fuels to reduce the costs of hydrogen and to ensure practically zero carbon dioxide emissions. The Hydrosol II project has the largest pilot plant of its kind, and the Hydrosol II reactors will be capable of breaking up the water molecule on the basis of thermochemical cycles at moderate temperatures. The Hydrosol II project pilot plant is now a reality, located in the SSPS heliostats field of the Almeria Solar Platform. (Author)

  14. Burkina Faso - BRIGHT II

    Data.gov (United States)

    Millennium Challenge Corporation — Millennium Challenge Corporation hired Mathematica Policy Research to conduct an independent evaluation of the BRIGHT II program. The three main research questions...

  15. Rom II-forordningen

    DEFF Research Database (Denmark)

    Pii, Tine; Nielsen, Peter Arnt

    2008-01-01

    Artiklen redegør for de vigtigste regler i Europaparlamentets og Rådets forordning om lovvalgsregler for forpligtelser uden for kontraktforhold (Rom II) og sammenligner dem med dansk ret.......Artiklen redegør for de vigtigste regler i Europaparlamentets og Rådets forordning om lovvalgsregler for forpligtelser uden for kontraktforhold (Rom II) og sammenligner dem med dansk ret....

  16. Ovarian Cancer Stage II

    Science.gov (United States)

    ... hyphen, e.g. -historical Searches are case-insensitive Ovarian Cancer Stage II Add to My Pictures View /Download : ... 1650x675 View Download Large: 3300x1350 View Download Title: Ovarian Cancer Stage II Description: Three-panel drawing of stage ...

  17. An in vivo comparison of the modified Mason-Allen suture technique versus an inclined horizontal mattress suture technique with regard to tendon-to-bone healing: a biomechanical and histologic study in sheep.

    Science.gov (United States)

    Schlegel, Theodore F; Hawkins, Richard J; Lewis, Chad W; Turner, A Simon

    2007-01-01

    The purpose of this study is to examine long-term tendon-to-bone healing, by use of a sheep animal model, after rotator cuff repairs performed with 2 different suture techniques: an inclined horizontal mattress suture pattern placed with special arthroscopic instrumentation (HMS) and the modified Mason-Allen pattern (MMA). After a pre hoc power analysis, 18 skeletally mature sheep were randomly assigned to either the HMS or MMA repair technique, with contralateral limbs used for the control group. At 26 weeks, the animals were euthanized. Six sheep from each group underwent biomechanical testing. Load-to-failure and stiffness results indicated no statistically significant difference between the 2 groups. Avulsion of the tuberosity was the primary mode of failure for both groups. In the remaining 6 sheep, histologic evaluation demonstrated that, regardless of treatment, the tendon appeared completely healed in the bony trough. Because the long-term biomechanical and histologic properties of healed tendons repaired with an HMA technique are equal to those obtained with an MMA technique, the inclined horizontal mattress suture may be appropriate for arthroscopic rotator cuff repair. Short-term studies are necessary to determine whether these findings are true early after tendon repair, when failure may be most common.

  18. Leo II PC

    Data.gov (United States)

    Kansas Data Access and Support Center — LEO II is a second-generation software system developed for use on the PC, which is designed to convert location references accurately between legal descriptions and...

  19. NNDSS - Table II. Vibriosis

    Data.gov (United States)

    U.S. Department of Health & Human Services — NNDSS - Table II. Vibriosis - 2017. In this Table, provisional cases of selected notifiable diseases (≥1,000 cases reported during the preceding year), and...

  20. Gamble II Facility

    Data.gov (United States)

    Federal Laboratory Consortium — FUNCTION: Gamble II produces a high-voltage (2 MV), high-current (1 MA), short (100 ns) pulse of energy of either positive or negative polarity. This terawatt power...

  1. Strongly luminescing ruthenium(II)/ruthenium(II) and ruthenium(II)/platinum(II) binuclear complexes

    Energy Technology Data Exchange (ETDEWEB)

    Sahai, R.; Baucom, D.A.; Rillema, D.P.

    1986-10-08

    Two strongly luminescing complexes, ruthenium(II)/ruthenium(II) homobinuclear complex and ruthenium(II)/platinum(II) heterobinuclear complex, have been prepared and characterized. The organic part of the complex is 4,4'-dimethyl-2,2' bipyridine dimer. The luminescence behavior of the homobinuclear and heterobinculear complexes was found to be comparable to that of Ru(bpy)/sub 3//sup 2 +/, although the luminescence maxima were shifted from 615 to 620 nm. These complexes exhibit good stability due to the bidentate chelating capability of the bridging ligand. These new complexes can provide the opportunity for detailed photophysical studies related to donor-acceptor interactions and to the possibility of two simultaneous single-electron transfer events. 17 references, 2 figures.

  2. Ecuaciones Diferenciales II

    OpenAIRE

    Mañas Baena, Manuel; Martínez Alonso, Luis

    2015-01-01

    En este manual se revisan diferentes aspectos sobre las ecuaciones diferenciales en derivadas parciales de utilidad para los físicos. Se elaboraron como notas de clase de la asignatura Ecuaciones II, del plan 1993 de la Licenciatura de Física de la UCM. Actualmente cubre un 75% de la asignatura Métodos Matemáticos II del Grado de Física de la UCM.

  3. DUMAND II status report

    Energy Technology Data Exchange (ETDEWEB)

    Aoki, T. (ICRR, University of Tokyo, Japan (JP)); Becker-Szendy, R.; Bosetti, P.; Boynton, P.E.; Bradner, H.; Camerini, U.; Clem, J.; Commichau, V.; Dau, D.; Dye, S.; Grieder, P.K.F.; Hayashino, T.; Hazen, E.; Jaworski, M.; Kitamura, T.; Kobayakawa, K.; Koske, P.; Learned, J.G.; Ley, C.; Lord, J.J.; March, R.; Matsuno, S.; Minkowski, P.; Mitsui, K.; O' Connor, D.; Ohashi, Y.; Okada, A.; Peterson, V.Z.; Rathlev, J.; Roberts, A.; Roos, C.E.; Sakuda, M.; Samm, D.; Stenger, V.J.; Tanaka, S.; Uehara, S.; Webster, M.; Wilkins, G.; Wilkes, R.J.; Yamaguchi, A.; Yamamoto, I.; Young, K.K. (University of Bern, Switzerland (CH) Boston University, (USA) University of Hawaii, (USA) University of Kiel, Germany (DE) Kobe University, Japan (JP) Kinki University, Japan (JP) Okayama Science University, Japan (JP) Scripps Institute of Oceanography, (USA) Tohoku University, Japan (JP) ICRR, University of tokyo, Japan (JP) NLHEP Tsukuba, Japan (JP) Vanderbilt University, (USA) University of Washington, (US

    1991-04-05

    The scientific goals, design, capabilities, and status of the DUMAND II detector system are described. In June, 1989, the High Energy Physics Advisory Panel recommended support for construction of DUMAND II to the U.S. Department of Energy. Funding began in 1990, and prototype development for various detector subsystems is under way. Current plans include deployment of the shore cable, junction box and three strings of optical detector modules in 1992, and expansion to the full 9-string configuration in 1993.

  4. DUMAND II status report

    Science.gov (United States)

    Aoki, T.; Becker-Szendy, R.; Bosetti, P.; Boynton, P. E.; Bradner, H.; Camerini, U.; Clem, J.; Commichau, V.; Dau, D.; Dye, S.; Grieder, P. K. F.; Hayashino, T.; Hazen, E.; Jaworski, M.; Kitamura, T.; Kobayakawa, K.; Koske, P.; Learned, J. G.; Ley, C.; Lord, J. J.; March, R.; Matsuno, S.; Minkowski, P.; Mitsui, K.; O'Connor, D.; Ohashi, Y.; Okada, A.; Peterson, V. Z.; Rathlev, J.; Roberts, A.; Roos, C. E.; Sakuda, M.; Samm, D.; Stenger, V. J.; Tanaka, S.; Uehara, S.; Webster, M.; Wilkins, G.; Wilkes, R. J.; Yamaguchi, A.; Yamamoto, I.; Young, K. K.

    1991-04-01

    The scientific goals, design, capabilities, and status of the DUMAND II detector system are described. In June, 1989, the High Energy Physics Advisory Panel recommended support for construction of DUMAND II to the U.S. Department of Energy. Funding began in 1990, and prototype development for various detector subsystems is under way. Current plans include deployment of the shore cable, junction box and three strings of optical detector modules in 1992, and expansion to the full 9-string configuration in 1993.

  5. II-VI semiconductor compounds

    CERN Document Server

    1993-01-01

    For condensed matter physicists and electronic engineers, this volume deals with aspects of II-VI semiconductor compounds. Areas covered include devices and applications of II-VI compounds; Co-based II-IV semi-magnetic semiconductors; and electronic structure of strained II-VI superlattices.

  6. SYNTHESIS AND CHARACTERIZATION OF SALICYLALDAZINE AND ITS METAL (II) COMPLEXES DERIVED FROM METAL (II) CHLORIDES

    OpenAIRE

    Jamila wazir

    2016-01-01

    The salicylaldazine (ligand) and its metal (II) complexes like copper (II), nickel (II), zinc (II), cobalt (II) and manganese (II) complexes has been synthesized and characterized by different techniques using FTIR, UV-VIS spectroscopy. The ligand (salicylaldazine) is synthesized by the condensation reaction of salicylaldehyde and hydrazine sulfate. The salicylaldazine metal (II) complexes like Cu (II) , Ni(II), Zn (II), Co(II), Mn(II) were prepared by using metal (II) chloride in dioxane. Th...

  7. About APPLE II Operation

    Science.gov (United States)

    Schmidt, T.; Zimoch, D.

    2007-01-01

    The operation of an APPLE II based undulator beamline with all its polarization states (linear horizontal and vertical, circular and elliptical, and continous variation of the linear vector) requires an effective description allowing an automated calculation of gap and shift parameter as function of energy and operation mode. The extension of the linear polarization range from 0 to 180° requires 4 shiftable magnet arrrays, permitting use of the APU (adjustable phase undulator) concept. Studies for a pure fixed gap APPLE II for the SLS revealed surprising symmetries between circular and linear polarization modes allowing for simplified operation. A semi-analytical model covering all types of APPLE II and its implementation will be presented.

  8. Calculus II For Dummies

    CERN Document Server

    Zegarelli, Mark

    2012-01-01

    An easy-to-understand primer on advanced calculus topics Calculus II is a prerequisite for many popular college majors, including pre-med, engineering, and physics. Calculus II For Dummies offers expert instruction, advice, and tips to help second semester calculus students get a handle on the subject and ace their exams. It covers intermediate calculus topics in plain English, featuring in-depth coverage of integration, including substitution, integration techniques and when to use them, approximate integration, and improper integrals. This hands-on guide also covers sequences and series, wit

  9. Galaxy S II

    CERN Document Server

    Gralla, Preston

    2011-01-01

    Unlock the potential of Samsung's outstanding smartphone with this jargon-free guide from technology guru Preston Gralla. You'll quickly learn how to shoot high-res photos and HD video, keep your schedule, stay in touch, and enjoy your favorite media. Every page is packed with illustrations and valuable advice to help you get the most from the smartest phone in town. The important stuff you need to know: Get dialed in. Learn your way around the Galaxy S II's calling and texting features.Go online. Browse the Web, manage email, and download apps with Galaxy S II's 3G/4G network (or create you

  10. Type-II Leptogenesis

    CERN Document Server

    Kim, Jihn E

    2016-01-01

    I will talk on our new theory on baryogenesis through type-II leptogenesis which is different from the well-known type-I leptogenesis. I will comment on the Jarlskog phases, $\\delta_{\\rm CKM}$ and $\\delta_{\\rm PMNS}$, in the CKM and PMNS matrices. In the type-II leptogenesis, the PMNS phase is used for Sakharov's condition on the global quantum number generation in the Universe. For this to be effective, the SU(2)$\\times$U(1) gauge symmetry must be broken during the leptogenesis epoch.

  11. Class II Microcins

    Science.gov (United States)

    Vassiliadis, Gaëlle; Destoumieux-Garzón, Delphine; Peduzzi, Jean

    Class II microcins are 4.9- to 8.9-kDa polypeptides produced by and active against enterobacteria. They are classified into two subfamilies according to their structure and their gene cluster arrangement. While class IIa microcins undergo no posttranslational modification, class IIb microcins show a conserved C-terminal sequence that carries a salmochelin-like siderophore motif as a posttranslational modification. Aside from this C-terminal end, which is the signature of class IIb microcins, some sequence similarities can be observed within and between class II subclasses, suggesting the existence of common ancestors. Their mechanisms of action are still under investigation, but several class II microcins use inner membrane proteins as cellular targets, and some of them are membrane-active. Like group B colicins, many, if not all, class II microcins are TonB- and energy-dependent and use catecholate siderophore receptors for recognition/­translocation across the outer membrane. In that context, class IIb microcins are considered to have developed molecular mimicry to increase their affinity for their outer membrane receptors through their salmochelin-like posttranslational modification.

  12. MARC II and COBOL

    Directory of Open Access Journals (Sweden)

    Henriette D. Avram

    1968-12-01

    Full Text Available A description of the machine processing of MARC II records using COBOL for an application on the Library of Congress System 360/30. Emphasis is on the manipulation by COBOL of highly complex variable length MARC records containing variable length fields.

  13. Periodontics II: Course Proposal.

    Science.gov (United States)

    Dordick, Bruce

    A proposal is presented for Periodontics II, a course offered at the Community College of Philadelphia to give the dental hygiene/assisting student an understanding of the disease states of the periodontium and their treatment. A standardized course proposal cover form is given, followed by a statement of purpose for the course, a list of major…

  14. Dark Blue II

    OpenAIRE

    2013-01-01

    Dark Blue II, high fired porcelain, decorated with cobalt chloride, woodfired with salt. 10,5 x 10,5 x 19 cm. Ferdigstilt: 2012. Innkjøpt til Collection of The American Museum of Ceramic Art, Pomona, California, USA.

  15. Dianilinedichloridozinc(II

    Directory of Open Access Journals (Sweden)

    Islam Ullah Khan

    2010-05-01

    Full Text Available In the title compound, [ZnCl2(C6H7N2], the ZnII ion (site symmetry 2 adopts a near-regular tetrahedral ZnN2Cl2 coordination geometry. In the crystal, molecules are linked by N—H...Cl hydrogen bonds, generating (100 sheets containing R22(8 loops.

  16. Inhibitory role of peroxiredoxin II (Prx II) on cellular senescence.

    Science.gov (United States)

    Han, Ying-Hao; Kim, Hyun-Sun; Kim, Jin-Man; Kim, Sang-Keun; Yu, Dae-Yeul; Moon, Eun-Yi

    2005-08-29

    Reactive oxygen species (ROS) were generated in all oxygen-utilizing organisms. Peroxiredoxin II (Prx II) as one of antioxidant enzymes may play a protective role against the oxidative damage caused by ROS. In order to define the role of Prx II in organismal aging, we evaluated cellular senescence in Prx II(-/-) mouse embryonic fibroblast (MEF). As compared to wild type MEF, cellular senescence was accelerated in Prx II(-/-) MEF. Senescence-associated (SA)-beta-galactosidase (Gal)-positive cell formation was about 30% higher in Prx II(-/-) MEF. N-Acetyl-l-cysteine (NAC) treatment attenuated SA-beta-Gal-positive cell formation. Prx II(-/-) MEF exhibited the higher G2/M (41%) and lower S (1.6%) phase cells as compared to 24% and 7.3% [corrected] in wild type MEF, respectively. A high increase in the p16 and a slight increase in the p21 and p53 levels were detected in PrxII(-/-) MEF cells. The cellular senescence of Prx II(-/-) MEF was correlated with the organismal aging of Prx II(-/-) mouse skin. While extracellular signal-regulated kinase (ERK) and p38 activation was detected in Prx II(-/-) MEF, ERK and c-Jun N-terminal kinase (JNK) activation was detected in Prx II(-/-) skin. These results suggest that Prx II may function as an enzymatic antioxidant to prevent cellular senescence and skin aging.

  17. RADTRAN II user guide

    Energy Technology Data Exchange (ETDEWEB)

    Madsen, M M; Wilmot, E L; Taylor, J M

    1983-02-01

    RADTRAN II is a flexible analytical tool for calculating both the incident-free and accident impacts of transporting radioactive materials. The consequences from incident-free shipments are apportioned among eight population subgroups and can be calculated for several transport modes. The radiological accident risk (probability times consequence summed over all postulated accidents) is calculated in terms of early fatalities, early morbidities, latent cancer fatalities, genetic effects, and economic impacts. Groundshine, inhalation, direct exposure, resuspension, and cloudshine dose pathways are modeled to calculate the radiological health risks from accidents. Economic impacts are evaluated based on costs for emergency response, cleanup, evacuation, income loss, and land use. RADTRAN II can be applied to specific scenario evaluations (individual transport modes or specified combinations), to compare alternative modes or to evaluate generic radioactive material shipments. Unit-risk factors can easily be evaluated to aid in performing generic analyses when several options must be compared with the amount of travel as the only variable.

  18. Transport phenomena II essentials

    CERN Document Server

    REA, The Editors of

    2012-01-01

    REA's Essentials provide quick and easy access to critical information in a variety of different fields, ranging from the most basic to the most advanced. As its name implies, these concise, comprehensive study guides summarize the essentials of the field covered. Essentials are helpful when preparing for exams, doing homework and will remain a lasting reference source for students, teachers, and professionals. Transport Phenomena II covers forced convention, temperature distribution, free convection, diffusitivity and the mechanism of mass transfer, convective mass transfer, concentration

  19. Algebra & trigonometry II essentials

    CERN Document Server

    REA, Editors of

    2012-01-01

    REA's Essentials provide quick and easy access to critical information in a variety of different fields, ranging from the most basic to the most advanced. As its name implies, these concise, comprehensive study guides summarize the essentials of the field covered. Essentials are helpful when preparing for exams, doing homework and will remain a lasting reference source for students, teachers, and professionals. Algebra & Trigonometry II includes logarithms, sequences and series, permutations, combinations and probability, vectors, matrices, determinants and systems of equations, mathematica

  20. Cervantes y Felipe II

    Directory of Open Access Journals (Sweden)

    Ludovik Osterc

    1999-12-01

    Full Text Available Como es sabido, el 13 de septiembre de 1598, a las cinco de la mañana, falleció en el Escorial el Rey Felipe II. Sevilla que según sus historiadores siempre se distinguió entre todas las ciudades de España por el fausto y suntuosidad de los sucesos solemnes, ya sea cuando los monarcas se dignaban visitarla, ya sea cuando se trataba de honrar su memoria con ocasión de su muerte, se habia excedido a si misma en el reinado de Felipe II. La pública y señorial entrada de su padre, el emperador Carlos V cuando en 1526 vino a esta ciudad para realizar sus bodas con la Infanta Isabel de Portugal, que por su magnificencia consignan sus anales, como superior a cuantas hubo antes en análogas circunstancias, no puede compararse con el recibimiento dispensado a Felipe II, el año de 1570, que por encargo de su Cabildo describió la docta pluma de Mal Lara.

  1. What is LAMPF II

    Energy Technology Data Exchange (ETDEWEB)

    Thiessen, H.A.

    1982-08-01

    The present conception of LAMPF II is a high-intensity 16-GeV synchrotron injected by the LAMPF 800-MeV H/sup -/ beam. The proton beam will be used to make secondary beams of neutrinos, muons, pions, kaons, antiprotons, and hyperons more intense than those of any existing or proposed accelerator. For example, by taking maximum advantage of a thick target, modern beam optics, and the LAMPF II proton beam, it will be possible to make a negative muon beam with nearly 100% duty factor and nearly 100 times the flux of the existing Stopped Muon Channel (SMC). Because the unique features of the proposed machine are most applicable to beams of the same momentum as LAMPF (that is, < 2 GeV/c), it may be possible to use most of the experimental areas and some of the auxiliary equipment, including spectrometers, with the new accelerator. The complete facility will provide improved technology for many areas of physics already available at LAMPF and will allow expansion of medium-energy physics to include kaons, antiprotons, and hyperons. When LAMPF II comes on line in 1990 LAMPF will have been operational for 18 years and a major upgrade such as this proposal will be reasonable and prudent.

  2. Teil II: Umgang mit natürlichen Ressourcen

    OpenAIRE

    2009-01-01

    Der 2008 in Johannesburg (Republik Südafrika) verabschiedete Weltagrarbericht (International Assessment of Agricultural Knowledge, Science and Technology for Development [IAASTD]) ist Resultat einer bislang einmaligen kooperativen Anstrengung von UN- und anderen internationalen Organisationen, 60 Regierungen und mehr als 400 Wissenschaftlerinnen und Wissenschaftlern aus allen Erdregionen. Ein Globaler Bericht und fünf Regionale Berichte stellen die wesentlichen heutigen ...

  3. 艾伦·卡尔松科学认知主义的困境及其出路%Dilemma and the Outlet:Allen Carlson’s Scientific Cognitivism

    Institute of Scientific and Technical Information of China (English)

    张春燕

    2015-01-01

    在环境美学的发展中,艾伦·卡尔松的科学认知主义独树一帜,它可以有效地批判自然审美的对象模式和景观模式,并在一定程度上有助于揭示自然环境的审美价值,维护自然审美的客观性。然而,这一学说存在严重的缺陷,因为它剔除了自然审美中个体经验的意义,狭隘地理解了审美经验的客观性,最终违背了审美的基本原则。这一缺陷的深层原因还在于卡尔松仍然没有摆脱对象化的思维模式,将自然环境看作是外在于人的实际生活之外的对象。相反,杜威的经验论和海德格尔的存在论指出了理解人与自然的关系的有效途径,可为自然审美提供正确路径,即自然的审美价值存在于人的实际生活和积极创造的过程中。%In the development of environmental aesthetics, Allen Carlson’s scientific cognitivism is very special, it can critique effectually object mode and landscape mode in aesthetic appreciation of nature, and to some extent, it is conducive to reveal the aesthetical value of natural environment, and preserve the objectivity of aesthetic appreciation of nature. However, this theory has serious defects, because it rejects the sense of individual experience, and gives a narrow understanding of objectivity of aesthetic experience, finally, it violates the basic principles of Aesthetics. The deep reason of these defects lies in the objectified thought that Carlson doesn’t get rid of, which means he looks natural environment as objects existing out of the real life of human. On the contrary, Dewey’s empiricism and Heidegger’s ontology indicate the efficient path of understanding the relationship between human and nature, which can provide correct way for aesthetic appreciation of nature, that is, the aesthetic values lie in the process of real life and positive creation.

  4. Obituary: John Allen Eddy (1931-2009)

    Science.gov (United States)

    Gingerich, Owen

    2011-12-01

    Jack Eddy, who was born 25 March 1931 in Pawnee City in southeastern Nebraska, died after a long battle with cancer in Tucson, Arizona, on 10 June 2009. Best known for his work on the long-term instability of the sun, described in a landmark paper in Science titled "The Maunder Minimum," he also deserves recognition as one of the triumvirate who founded the Historical Astronomy Division of the AAS. His father ran a cooperative farm store where Jack worked as a teenager; his parents were of modest means and there were concerns whether he could afford college, but one of the state senators, also from Pawnee City, nominated him for the U.S. Naval Academy. A course in celestial navigation gave him a love of the sky. After graduation in 1953, he served four years on aircraft carriers in the Pacific during the Korean War and then as a navigator and operations officer on a destroyer in the Persian Gulf. In 1957, he left the Navy and entered graduate school at the University of Colorado in Boulder, where in 1962 he received a Ph.D. in astro-geophysics. His thesis, supervised by Gordon Newkirk, dealt with light scattering in the upper atmosphere, based on data from stratospheric balloon flights. He then worked as teacher and researcher at the High Altitude Observatory in Boulder. Always adventuresome and willing to explore new frontiers, on his own time Eddy examined an Amerindian stone circle in the Big Horn mountains of Wyoming, a so-called medicine wheel, concluding that there were alignments with both the solstitial sun and Aldebaran. His conjectures became a cover story on Science magazine in June of 1974. In 1971 Jack privately reproduced for his friends a small collection of his own hilarious cartoons titled "Job Opportunities for Out-of-work Astronomers," with an abstract beginning, "Contrary to popular belief, a PhD in Astronomy/Astrophysics need not be a drawback in locating work in this decade." For example, under merchandising, a used car salesman advertises, "This Mercury is Hot! Red Shift, Black Body, and a Perfect Radiator." Ironically, within a few years he was laid off from his HAO position as a result of budget cuts at its parent organization, the National Center for Atmospheric Research (NCAR). In an interview a quarter of a century later Eddy remarked, "I found out how hard it is for a person with a Ph.D. to get another job at that time, and often wished I didn't have one, for I was often told, true or not, that I was overqualified for the few jobs that turned up." Eddy found a temporary job writing a book for NASA as part of a series on the Skylab spacecraft; the book, The New Sun, was published in 1979. Again, working on his own time, he revived an earlier finding, namely, that between 1645 and 1715 the sun was almost devoid of spots, and he greatly extended the previous work of Gustav Spörer and Walter Maunder by showing during that period a dearth of aurorae and atmospheric carbon-14, a diminution of the solar corona during eclipses, and probably a correlation with cooling of the earth. For onomatopoiec reasons, the rhythm of the m's, Eddy chose the title "the Maunder Minimum" for the phenomenon, and for his unusually long cover story in the 18 June 1976 issue of Science. The paper was well received, and for a while Eddy was an invited speaker fifty times a year. In 1977, Eddy scored yet again, with his third cover story in Science, a jointly authored paper on solar rotation in the early 17th century. In 1977-78 Eddy had a fellowship at the Harvard-Smithsonian Center for Astrophysics in Cambridge, and during that time Ken Brecher and I had a series of conversations with Jack in which we worked out a proposal for a historical astronomy division within the AAS; since I had just been an AAS Councilor, I negotiated with the Society for its actualization, and Eddy became the first HAD president, in 1981-83. He introduced the logo, Dürer's ancient astronomer, and at the end of his term, the plaque with the motto "Ich bin HAD," which has been passed on to every subsequent division president. At the IAU meeting in New Delhi, Eddy became president of the IAU Commission 41 on the history of astronomy (1985-88). While at the CfA Eddy received a tenure offer from the director, George Field. But Eddy's wife, Marjorie Bratt Eddy, and four children had remained behind, and Jack felt obliged to return to Colorado. With the offer from the Smithsonian Observatory and his considerable fame, HAO and NCAR were eager to rehire him. Eddy soon became increasingly interested in interdisciplinary sciences, turning away from his earlier enthusiasm for the history of astronomy. He became the first chairman of a National Academy of Sciences committee for an International Geosphere-Biosphere Program, which later became the U.S. Global Change Program. Early in 1986, UCAR (the University Corporation for Atmospheric research, which managed NCAR) formalized its response to the challenge of global change with a new Office for Interdisciplinary Earth Studies, which Eddy founded and directed. The office focused efforts to bring the atmospheric sciences and other relevant disciplines together to study the earth's living and inanimate elements as a single system. In 1987 Eddy received the Arctowski medal from the National Academy of Science, an honor awarded triennially for studies in solar physics and solar terrestrial relationships. In 1992 Eddy found a new opportunity as chief scientist and vice president of the Center for International Earth Science Information Network, which he described as a federally funded pork barrel project in Michigan. Meanwhile Eddy had divorced; he remarried in 1992 to a fellow worker at UCAR, and he and his new wife, Barbara, relocated to Saginaw, Michigan. After two years he was "extremely frustrated" by the bureaucracy, so he and Barbara struck out on their own, founding the newsletter Consequences (with support from five federal agencies) to explain in popular terms the nature and eventual impacts of environmental changes of all kinds. In 2004 they moved to Tucson, where Eddy worked for NASA at the National Solar Observatory until the time of his death. Author's Note: A principal source of information is the interview with John A. Eddy by Spencer Weart on 21 April 1999, Niels Bohr Library & Archives, American Institute of Physics, College Park, MD USA, www.aip.org/history/ohilist/22910.html. See also the obituary by Peter Foukal in Physics Today, January 2010, pp. 60-61.

  5. Algebra II workbook for dummies

    CERN Document Server

    Sterling, Mary Jane

    2014-01-01

    To succeed in Algebra II, start practicing now Algebra II builds on your Algebra I skills to prepare you for trigonometry, calculus, and a of myriad STEM topics. Working through practice problems helps students better ingest and retain lesson content, creating a solid foundation to build on for future success. Algebra II Workbook For Dummies, 2nd Edition helps you learn Algebra II by doing Algebra II. Author and math professor Mary Jane Sterling walks you through the entire course, showing you how to approach and solve the problems you encounter in class. You'll begin by refreshing your Algebr

  6. Thermodynamics II essentials

    CERN Document Server

    REA, The Editors of

    2013-01-01

    REA's Essentials provide quick and easy access to critical information in a variety of different fields, ranging from the most basic to the most advanced. As its name implies, these concise, comprehensive study guides summarize the essentials of the field covered. Essentials are helpful when preparing for exams, doing homework and will remain a lasting reference source for students, teachers, and professionals. Thermodynamics II includes review of thermodynamic relations, power and refrigeration cycles, mixtures and solutions, chemical reactions, chemical equilibrium, and flow through nozzl

  7. Engineering mathematics-II

    CERN Document Server

    Ganesh, A

    2009-01-01

    About the Book: This book Engineering Mathematics-II is designed as a self-contained, comprehensive classroom text for the second semester B.E. Classes of Visveswaraiah Technological University as per the Revised new Syllabus. The topics included are Differential Calculus, Integral Calculus and Vector Integration, Differential Equations and Laplace Transforms. The book is written in a simple way and is accompanied with explanatory figures. All this make the students enjoy the subject while they learn. Inclusion of selected exercises and problems make the book educational in nature. It shou

  8. Complex variables II essentials

    CERN Document Server

    Solomon, Alan D

    2013-01-01

    REA's Essentials provide quick and easy access to critical information in a variety of different fields, ranging from the most basic to the most advanced. As its name implies, these concise, comprehensive study guides summarize the essentials of the field covered. Essentials are helpful when preparing for exams, doing homework and will remain a lasting reference source for students, teachers, and professionals. Complex Variables II includes elementary mappings and Mobius transformation, mappings by general functions, conformal mappings and harmonic functions, applying complex functions to a

  9. Amorphous iron (II) carbonate

    DEFF Research Database (Denmark)

    Sel, Ozlem; Radha, A.V.; Dideriksen, Knud;

    2012-01-01

    exothermic than that of amorphous calcium carbonate (ACC). This suggests that enthalpy of crystallization in carbonate systems is ionic-size controlled, which may have significant implications in a wide variety of conditions, including geological sequestration of anthropogenic carbon dioxide.......Abstract The synthesis, characterization and crystallization energetics of amorphous iron (II) carbonate (AFC) are reported. AFC may form as a precursor for siderite (FeCO3). The enthalpy of crystallization (DHcrys) of AFC is similar to that of amorphous magnesium carbonate (AMC) and more...

  10. Thin film processes II

    CERN Document Server

    Kern, Werner

    1991-01-01

    This sequel to the 1978 classic, Thin Film Processes, gives a clear, practical exposition of important thin film deposition and etching processes that have not yet been adequately reviewed. It discusses selected processes in tutorial overviews with implementation guide lines and an introduction to the literature. Though edited to stand alone, when taken together, Thin Film Processes II and its predecessor present a thorough grounding in modern thin film techniques.Key Features* Provides an all-new sequel to the 1978 classic, Thin Film Processes* Introduces new topics, and sever

  11. Skin and bones. II.

    Science.gov (United States)

    Orlow, S J; Watsky, K L; Bolognia, J L

    1991-09-01

    Skin disorders in which a radiograph may detect associated bony changes or abnormalities of calcification are discussed. They are grouped into eight categories: (1) inherited diseases (e.g., alkaptonuria, neurofibromatosis); (2) congenital disorders (e.g., Sturge-Weber and Proteus syndromes); (3) inflammatory conditions (e.g., dermatomyositis, sarcoidosis); (4) infections (e.g., dental sinus, syphilis); (5) neoplasias (e.g., histiocytosis, mastocytosis); (6) drug- and environment-induced (e.g., acroosteolysis, retinoid toxicity); (7) calcinosis cutis; and (8) osteoma cutis. The first part of this review, published in the August 1991 issue of this JOURNAL, dealt with the first two categories; part II discusses categories 3 through 8.

  12. PIVKA-II

    Institute of Scientific and Technical Information of China (English)

    建石良介

    2005-01-01

    @@ PIVKA-II是通过维生素K缺乏或拮抗剂II诱导的蛋白质 (protein induced by vitamine K absence or antagonist-II),又称为右旋-γ-羧基-凝血酶原(des-γ-carboxy prothrombin),它是肝脏合成的无凝血活性的异常凝血酶原.自从Liebman等(1984年)报道以来,PIVKA-II作为肝细胞癌的特异性肿瘤标志物,是临床上不可缺少的检查.

  13. Electronics II essentials

    CERN Document Server

    REA, The Editors of

    2012-01-01

    REA's Essentials provide quick and easy access to critical information in a variety of different fields, ranging from the most basic to the most advanced. As its name implies, these concise, comprehensive study guides summarize the essentials of the field covered. Essentials are helpful when preparing for exams, doing homework and will remain a lasting reference source for students, teachers, and professionals. Electronics II covers operational amplifiers, feedback and frequency compensation of OP amps, multivibrators, logic gates and families, Boolean algebra, registers, counters, arithmet

  14. Diaquabis(benzyloxyacetatocopper(II

    Directory of Open Access Journals (Sweden)

    Xiao-Min Hao

    2008-05-01

    Full Text Available In the title mononuclear complex, [Cu(C9H9O32(H2O2], the CuII ion, located on an inversion center, is hexacoordinated by four O atoms from two benzyloxyacetate ligands [Cu—O = 1.9420 (14 and 2.2922 (14 Å] and two water molecules [Cu—O = 2.0157 (15 Å] in a distorted octahedral geometry. In the crystal structure, intermolecular O—H...O hydrogen bonds link the molecules into layers parallel to the bc plane.

  15. Physics II for dummies

    CERN Document Server

    Holzner, Steven

    2010-01-01

    A plain-English guide to advanced physics. Does just thinking about the laws of motion make your head spin? Does studying electricity short your circuits? Physics II For Dummies walks you through the essentials and gives you easy-to-understand and digestible guidance on this often intimidating course. Thanks to this book, you don?t have to be Einstein to understand physics. As you learn about mechanical waves and sound, forces and fields, electric potential and electric energy, and much more, you?ll appreciate the For Dummies law: The easier we make it, the faster you'll understand it!

  16. Graphics gems II

    CERN Document Server

    Arvo, James

    1991-01-01

    Graphics Gems II is a collection of articles shared by a diverse group of people that reflect ideas and approaches in graphics programming which can benefit other computer graphics programmers.This volume presents techniques for doing well-known graphics operations faster or easier. The book contains chapters devoted to topics on two-dimensional and three-dimensional geometry and algorithms, image processing, frame buffer techniques, and ray tracing techniques. The radiosity approach, matrix techniques, and numerical and programming techniques are likewise discussed.Graphics artists and comput

  17. Statistics II essentials

    CERN Document Server

    Milewski, Emil G

    2012-01-01

    REA's Essentials provide quick and easy access to critical information in a variety of different fields, ranging from the most basic to the most advanced. As its name implies, these concise, comprehensive study guides summarize the essentials of the field covered. Essentials are helpful when preparing for exams, doing homework and will remain a lasting reference source for students, teachers, and professionals. Statistics II discusses sampling theory, statistical inference, independent and dependent variables, correlation theory, experimental design, count data, chi-square test, and time se

  18. Computer science II essentials

    CERN Document Server

    Raus, Randall

    2012-01-01

    REA's Essentials provide quick and easy access to critical information in a variety of different fields, ranging from the most basic to the most advanced. As its name implies, these concise, comprehensive study guides summarize the essentials of the field covered. Essentials are helpful when preparing for exams, doing homework and will remain a lasting reference source for students, teachers, and professionals. Computer Science II includes organization of a computer, memory and input/output, coding, data structures, and program development. Also included is an overview of the most commonly

  19. Data structures II essentials

    CERN Document Server

    Smolarski, Dennis C

    2012-01-01

    REA's Essentials provide quick and easy access to critical information in a variety of different fields, ranging from the most basic to the most advanced. As its name implies, these concise, comprehensive study guides summarize the essentials of the field covered. Essentials are helpful when preparing for exams, doing homework and will remain a lasting reference source for students, teachers, and professionals. Data Structures II includes sets, trees, advanced sorting, elementary graph theory, hashing, memory management and garbage collection, and appendices on recursion vs. iteration, alge

  20. Effect of Cu(II), Cd(II) and Zn(II) on Pb(II) biosorption by algae Gelidium-derived materials.

    Science.gov (United States)

    Vilar, Vítor J P; Botelho, Cidália M S; Boaventura, Rui A R

    2008-06-15

    Biosorption of Pb(II), Cu(II), Cd(II) and Zn(II) from binary metal solutions onto the algae Gelidium sesquipedale, an algal industrial waste and a waste-based composite material was investigated at pH 5.3, in a batch system. Binary Pb(II)/Cu(II), Pb(II)/Cd(II) and Pb(II)/Zn(II) solutions have been tested. For the same equilibrium concentrations of both metal ions (1 mmol l(-1)), approximately 66, 85 and 86% of the total uptake capacity of the biosorbents is taken by lead ions in the systems Pb(II)/Cu(II), Pb(II)/Cd(II) and Pb(II)/Zn(II), respectively. Two-metal results were fitted to a discrete and a continuous model, showing the inhibition of the primary metal biosorption by the co-cation. The model parameters suggest that Cd(II) and Zn(II) have the same decreasing effect on the Pb(II) uptake capacity. The uptake of Pb(II) was highly sensitive to the presence of Cu(II). From the discrete model it was possible to obtain the Langmuir affinity constant for Pb(II) biosorption. The presence of the co-cations decreases the apparent affinity of Pb(II). The experimental results were successfully fitted by the continuous model, at different pH values, for each biosorbent. The following sequence for the equilibrium affinity constants was found: Pb>Cu>Cd approximately Zn.

  1. Inside ISIS II

    CERN Multimedia

    1981-01-01

    ISIS stands for Identification of Secondaries by Ionization Sampling. It was a drift chamber with an active volume of about 40 m3 built by Oxford University as a particle identifier for the European Hybrid Spectrometer (EHS). The photo shows the electrostatic grading structure and the central anode-wire plane, with Roger Giles standing just under it (Annual Report 1981 p. 57, Fig. 4). ISIS-II differed from the prototype ISIS-I only in the depth of the track (4 m instead of 1 m) thus extending the momentum range for particle identification to 50 GeV/c. See Nucl. Instr. and Meth. 224 (1984) 396, and Nucl. Instr. and Meth. 258 (1987) 26.

  2. Phase II Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Schuknecht, Nate [Project Manager; White, David [Principle Investigator; Hoste, Graeme [Research Engineer

    2014-09-11

    The SkyTrough DSP will advance the state-of-the-art in parabolic troughs for utility applications, with a larger aperture, higher operating temperature, and lower cost. The goal of this project was to develop a parabolic trough collector that enables solar electricity generation in the 2020 marketplace for a 216MWe nameplate baseload power plant. This plant requires an LCOE of 9¢/kWhe, given a capacity factor of 75%, a fossil fuel limit of 15%, a fossil fuel cost of $6.75/MMBtu, $25.00/kWht thermal storage cost, and a domestic installation corresponding to Daggett, CA. The result of our optimization was a trough design of larger aperture and operating temperature than has been fielded in large, utility scale parabolic trough applications: 7.6m width x 150m SCA length (1,118m2 aperture), with four 90mm diameter × 4.7m receivers per mirror module and an operating temperature of 500°C. The results from physical modeling in the System Advisory Model indicate that, for a capacity factor of 75%: The LCOE will be 8.87¢/kWhe. SkyFuel examined the design of almost every parabolic trough component from a perspective of load and performance at aperture areas from 500 to 2,900m2. Aperture-dependent design was combined with fixed quotations for similar parts from the commercialized SkyTrough product, and established an installed cost of $130/m2 in 2020. This project was conducted in two phases. Phase I was a preliminary design, culminating in an optimum trough size and further improvement of an advanced polymeric reflective material. This phase was completed in October of 2011. Phase II has been the detailed engineering design and component testing, which culminated in the fabrication and testing of a single mirror module. Phase II is complete, and this document presents a summary of the comprehensive work.

  3. Annex II technical documentation assessed.

    Science.gov (United States)

    van Drongelen, A W; Roszek, B; van Tienhoven, E A E; Geertsma, R E; Boumans, R T; Kraus, J J A M

    2005-12-01

    Annex II of the Medical Device Directive (MDD) is used frequently by manufacturers to obtain CE-marking. This procedure relies on a full quality assurance system and does not require an assessment of the individual medical device by a Notified Body. An investigation into the availability and the quality of technical documentation for Annex II devices revealed severe shortcomings, which are reported here.

  4. RTNS-II operations guidebook

    Energy Technology Data Exchange (ETDEWEB)

    Heikkinen, D.W.

    1985-04-01

    This guidebook is intended to provide training criteria, procedures and guidelines for operation of the RTNS-II neutron sources and ancilliary equipment. Use of this document requires full knowledge of the RTNS-II Facility Safety Procedure (FSP) and any Operational Safety Procedures (OSP) in effect. The RTNS-II FSP defines the hazards which may be encountered at RTNS-II and defines the procedures which must be followed in performing any task including operations. The purpose of this document is to provide a central source of detailed information concerning systems and equipment used in operating the RTNS-II neutron sources on a day-to-day basis. All members of the Operations Group are expected to be familiar with its contents. It is also intended to be used in training new members of the Operations Group.

  5. Organizing MHC Class II Presentation

    Directory of Open Access Journals (Sweden)

    David R Fooksman

    2014-04-01

    Full Text Available Major histocompatibility complex (MHC class II molecules are ligands for CD4+ T cells and are critical for initiating the adaptive immune response. This review is focused on what is currently known about MHC class II organization at the plasma membrane of antigen presenting cells and how this affects antigen presentation to T cells. The organization and diffusion of class II molecules have been measured by a variety of biochemical and microscopic techniques. Membrane lipids and other proteins have been implicated in MHC class II organization and function. However, when compared with the organization of MHC class I or TCR complexes, much less is known about MHC class II. Since clustering of T cell receptors occurs during activation, the organization of MHC molecules prior to recognition and during synapse formation may be critical for antigen presentation.

  6. Neurofibromatosis Type II

    Directory of Open Access Journals (Sweden)

    Akram Kasiri Ghahi

    2003-08-01

    Full Text Available Neurofibromatosis type 2 (NF2 is an inherited disease which is mainly characterized by the development of multiple schwannomas and meningiomas.  Incidence of the disease is about 1 in 60,000. Affected individuals inevitably develop schwannomas, typically affecting both auditory-vestibular nerve which lead in hearing loss and deafness. The majority of patients present with hearing loss, which is usually unilateral at onset and may be accompanied or preceded by tinnitus. Vestibular schwannomas may also cause dizziness or imbalance as a first symptom. Nausea, vomiting or true vertigo are rare symptoms, except in late-stage disease. NF II is caused by a defect in the gene that normally gives rise to a product called Merlin or Schwannomin, located on chromosome 22. Diagnosis is based on clinical and neuroimaging studies. Presymptomatic genetic testing is an integral part of the management of NF2 families. Prenatal diagnosis and pre-implantation genetic diagnosis is possible.

  7. Selective separation of Cu (II), Zn (II), and Cd (II) by solvent extraction

    Institute of Scientific and Technical Information of China (English)

    XIE Keng; WEN Jiankang; HUA Yixin; RUAN Renman

    2008-01-01

    An experimental investigation was presented on the separation of Cu (II), Zn (II), and Cd (II) from a rich sulfate leachate of zinc slag by solvent extraction. The results of orthogonal experiments indicate that LIX 984N is highly selective and very efficient in the extraction of Cu (II), and the analysis of variance indicates that the sequence of parameters according to their influence on the separation efficiency is phase ratio>LIX 984N concentration>pH value>extraction time. The optimal condition for copper extraction is obtained as 25% of LIX 984N concentration, 7 min of extraction time, 3:2 of phase ratio O/A, and pH=1.7. The separation of Zn (II) and Cd (II) was performed after the copper extraction from the raffinate. Comparative analysis of the separation with di-2-ethylhexyl phosphoric acid (D2EHPA), D2EHPA-tributyl-phosophate (TBP) synergistic extracting system, and 2-ethylhexyl phosphonic acid mono 2-ethylhexyl ester (HEHEHP) was made at pH=2.0. It is demonstrated that the extraction efficiency with D2EHPA is improved after being saponified by sodium hydroxide, and D2EHPA-TBP synergistic extracting, as well as HEHEHP, has a superior selectivity to Zn (II) over Cd (II).

  8. Can Co(II) or Cd(II) substitute for Zn(II) in zinc fingers?

    Indian Academy of Sciences (India)

    P Rabindra Reddy; M Radhika

    2001-02-01

    Zinc finger domains consist of sequences of amino acids containing cysteine and histidine residues tetrahedrally coordinated to a zinc ion. The role of zinc in a DNA binding finger was considered purely structural due to the absence of redox chemistry in zinc. However, whether other metals e.g. Co(II) or Cd(II) can substitute Zn(II) is not settled. For an answer the detailed interaction of Co(II) and Cd(II) with cysteine methylester and histidine methylester has been investigated as a model for the zinc core in zinc fingers. The study was extended to different temperatures to evaluate the thermodynamic parameters associated with these interactions. The results suggest that zinc has a unique role.

  9. Options Study - Phase II

    Energy Technology Data Exchange (ETDEWEB)

    R. Wigeland; T. Taiwo; M. Todosow; W. Halsey; J. Gehin

    2010-09-01

    The Options Study has been conducted for the purpose of evaluating the potential of alternative integrated nuclear fuel cycle options to favorably address the issues associated with a continuing or expanding use of nuclear power in the United States. The study produced information that can be used to inform decisions identifying potential directions for research and development on such fuel cycle options. An integrated nuclear fuel cycle option is defined in this study as including all aspects of the entire nuclear fuel cycle, from obtaining natural resources for fuel to the ultimate disposal of used nuclear fuel (UNF) or radioactive wastes. Issues such as nuclear waste management, especially the increasing inventory of used nuclear fuel, the current uncertainty about used fuel disposal, and the risk of nuclear weapons proliferation have contributed to the reluctance to expand the use of nuclear power, even though it is recognized that nuclear power is a safe and reliable method of producing electricity. In this Options Study, current, evolutionary, and revolutionary nuclear energy options were all considered, including the use of uranium and thorium, and both once-through and recycle approaches. Available information has been collected and reviewed in order to evaluate the ability of an option to clearly address the challenges associated with the current implementation and potential expansion of commercial nuclear power in the United States. This Options Study is a comprehensive consideration and review of fuel cycle and technology options, including those for disposal, and is not constrained by any limitations that may be imposed by economics, technical maturity, past policy, or speculated future conditions. This Phase II report is intended to be used in conjunction with the Phase I report, and much information in that report is not repeated here, although some information has been updated to reflect recent developments. The focus in this Options Study was to

  10. Stiffnites. Part II

    Directory of Open Access Journals (Sweden)

    Maria Teresa Pareschi

    2011-06-01

    Full Text Available

    The dynamics of a stiffnite are here inferred. A stiffnite is a sheet-shaped, gravity-driven submarine sediment flow, with a fabric made up of marine ooze. To infer stiffnite dynamics, order of magnitude estimations are used. Field deposits and experiments on materials taken from the literature are also used. Stiffnites can be tens or hundreds of kilometers wide, and a few centimeters/ meters thick. They move on the sea slopes over hundreds of kilometers, reaching submarine velocities as high as 100 m/s. Hard grain friction favors grain fragmentation and formation of triboelectrically electrified particles and triboplasma (i.e., ions + electrons. Marine lipids favor isolation of electrical charges. At first, two basic assumptions are introduced, and checked a posteriori: (a in a flowing stiffnite, magnetic dipole moments develop, with the magnetization proportional to the shear rate. I have named those dipoles as Ambigua. (b Ambigua are ‘vertically frozen’ along stiffnite streamlines. From (a and (b, it follows that: (i Ambigua create a magnetic field (at peak, >1 T. (ii Lorentz forces sort stiffnite particles into two superimposed sheets. The lower sheet, L+, has a sandy granulometry and a net positive electrical charge density. The upper sheet, L–, has a silty muddy granulometry and a net negative electrical charge density; the grains of sheet L– become finer upwards. (iii Faraday forces push ferromagnetic grains towards the base of a stiffnite, so that a peak of magnetic susceptibility characterizes a stiffnite deposit. (iv Stiffnites harden considerably during their motion, due to magnetic confinement. Stiffnite deposits and inferred stiffnite characteristics are compatible with a stable flow behavior against bending, pinch, or other macro instabilities. In the present report, a consistent hypothesis about the nature of Ambigua is provided.

  11. Delta II commercial space transportation

    Science.gov (United States)

    Meyers, J. F.

    1988-07-01

    Delta II is an upgraded variant of the Delta family of launch vehicles that has been in use by NASA since 1960. Among the design improvements incorporated by Delta II is a cryogenic-propellant second stage, a 2.89-m diameter satellite-protecting nose fairing, graphite/epoxy solid rocket motor cases, and 12:1 main engine expansion nozzle. The manufacturer/operator offers Delta II customers a dedicated, single satellite launch capability fully tailored to the given spacecraft's unique mission requirements.

  12. Quininium tetra-chloridozinc(II).

    Science.gov (United States)

    Chen, Li-Zhuang

    2009-09-05

    The asymmetric unit of the title compound {systematic name: 2-[hydr-oxy(6-meth-oxy-quinolin-1-ium-4-yl)meth-yl]-8-vinyl-quinuclidin-1-ium tetra-chlorido-zinc(II)}, (C(20)H(26)N(2)O(2))[ZnCl(4)], consists of a double proton-ated quininium cation and a tetra-chloridozinc(II) anion. The Zn(II) ion is in a slightly distorted tetra-hedral coordination environment. The crystal structure is stabilized by inter-molecular N-H⋯Cl and O-H⋯Cl hydrogen bonds.

  13. Tier II Chemical Storage Facilities

    Data.gov (United States)

    Iowa State University GIS Support and Research Facility — Facilities that store hazardous chemicals above certain quantities must submit an annual emergency and hazardous chemical inventory on a Tier II form. This is a...

  14. Examination of the e{sup +} and e{sup +}e{sup -} pair emission from heavy ion collisions at the EPoS II spectrometer; Untersuchung der e{sup +}- und e{sup +}e{sup -}-Paaremission aus Schwerionenkollisionen mit dem EPoS II Spektrometer

    Energy Technology Data Exchange (ETDEWEB)

    Baumann, J.

    1996-12-01

    In the course of examination of the positron and positron-electron pair emission from heavy ion collisions at the Coulomb barrier, the research groups EPOS I and ORANGE have found a number of line structures in the measured positron energy and cumulative pair energy spectra which up to present could not be fully explained, as theoretical interpretations so far remain inconsistent in some respects. For clarification, further measurements have been made at the completely new designed EPoS II spectrometer. Reproducibility of the lines is possible at a high level of statistical significance. (orig./CB) [Deutsch] Bei Untersuchungen der Positron- und Positron- Elektron- Paaremissionaus Schwerionenkollisionen an der Coulombbarriere wurde von den Gruppen EPOS I und ORANGE eine Reihe von Linienstrukturen in den gemessenen Positronenenergie- und Paarsummenenergiespektren beobachtet, fuer die bislang keine in allen Punkten konsistente, theoretische Erklaerunggefunden werden konnte. Um ihre Ursachen zu klaeren, wurden mit dem voellig neu aufgebauten EPoS II Spektrometer weitere Messreihen durgefuehrt. Die Reproduzierbarkeit der Linien ist auf einem hohen statistischen Signifikanzniveau moeglich.

  15. Insulin-like growth factor II (IGF-II).

    Science.gov (United States)

    O'Dell, S D; Day, I N

    1998-07-01

    Insulin-like growth factor II (IGF-II) plays a key role in mammalian growth, influencing foetal cell division and differentiation and possibly metabolic regulation. The mature 67 amino acid peptide shares sequence homology with both insulin and IGF-I. The liver is the main endocrine source of IGFs, but autocrine/paracrine activity is found in most tissues. The type 1 receptor mediates most of the biological effects of IGF-I and IGF-II; the type 2 receptor is involved with IGF-II degradation. Binding proteins may both localise IGFs to the receptors and regulate their activities. The IGF2 gene is maternally imprinted in mouse and human. Relaxation of IGF2 imprinting occurs in the Beckwith-Wiedemann syndrome of somatic overgrowth, sporadic Wilms' tumour and a number of other cancers. In the general adult population, the IGF2-INS gene cluster may also influence body weight, in which case IGF-II function could become a target for therapeutic intervention in obesity.

  16. Cr(III,Mn(II,Fe(III,Co(II,Ni(II,Cu(II and Zn(II Complexes with Diisobutyldithiocarbamato Ligand

    Directory of Open Access Journals (Sweden)

    Mohammad Tarique

    2011-01-01

    Full Text Available The synthesis of sulphur and nitrogen containing dithiocarbamato ligand derived from diisobutylamine as well as its coordination compounds with 3d series transition metals is presented. These synthesized compounds were characterized on the basis of elemental analysis, conductometric measurements and IR spectral studies. The analytical data showed the stoichiometry 1:2 and 1:3 for the compounds of the types ML2 {M=Mn(II, Co(II, Ni(II, Cu(II and Zn(II} and M'L3{M'=Cr(III and Fe(III} respectively. The conductometric measurements proved the non-electrolytic behaviour of all the compounds. The bidentate nature of dithiocarbamato moiety was confirmed on the basis of IR spectral data.

  17. EBR-II Data Digitization

    Energy Technology Data Exchange (ETDEWEB)

    Yoon, Su-Jong [Idaho National Lab. (INL), Idaho Falls, ID (United States); Rabiti, Cristian [Idaho National Lab. (INL), Idaho Falls, ID (United States); Sackett, John [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2014-08-01

    1. Objectives To produce a validation database out of those recorded signals it will be necessary also to identify the documents need to reconstruct the status of reactor at the time of the beginning of the recordings. This should comprehends the core loading specification (assemblies type and location and burn-up) along with this data the assemblies drawings and the core drawings will be identified. The first task of the project will be identify the location of the sensors, with respect the reactor plant layout, and the physical quantities recorded by the Experimental Breeder Reactor-II (EBR-II) data acquisition system. This first task will allow guiding and prioritizing the selection of drawings needed to numerically reproduce those signals. 1.1 Scopes and Deliverables The deliverables of this project are the list of sensors in EBR-II system, the identification of storing location of those sensors, identification of a core isotopic composition at the moment of the start of system recording. Information of the sensors in EBR-II reactor system was summarized from the EBR-II system design descriptions listed in Section 1.2.

  18. II National Environment Congress; II Congreso Nacional de Medio Ambiente

    Energy Technology Data Exchange (ETDEWEB)

    Camacho Serna, F.

    1994-12-31

    The paper summarizes the most relevant opinions expressed during the opening act of the II Natural Environment Congress, which took place in Madrid from the 21 ``st to the 25``st of November 1994. The objective of the Congress was the analysis of the environmental situation in Spain. (Author)

  19. Administrative Plans. STIP II (Skill Training Improvement Programs Round II).

    Science.gov (United States)

    Los Angeles Community Coll. District, CA.

    Personnel policies, job responsibilities, and accounting procedures are summarized for the Los Angeles Community College District's Skill Training Improvement Programs (STIP II). This report first cites references to the established personnel and affirmative action procedures governing the program and then presents an organizational chart for the…

  20. GRID Computing at Belle II

    CERN Document Server

    Bansal, Vikas

    2015-01-01

    The Belle II experiment at the SuperKEKB collider in Tsukuba, Japan, will start physics data taking in 2018 and will accumulate 50 ab$^{-1}$ of e$^{+}$e$^{-}$ collision data, about 50 times larger than the data set of the earlier Belle experiment. The computing requirements of Belle II are comparable to those of a run I high-p$_T$ LHC experiment. Computing will make full use of such grids in North America, Asia, Europe, and Australia, and high speed networking. Results of an initial MC simulation campaign with 3 ab$^{-1}$ equivalent luminosity will be described

  1. Helium II level measurement techniques

    Science.gov (United States)

    Celik, D.; Hilton, D. K.; Zhang, T.; Van Sciver, S. W.

    2001-05-01

    In this paper, a survey of cryogenic liquid level measurement techniques applicable to superfluid helium (He II) is given. The survey includes both continuous and discrete measurement techniques. A number of different probes and controlling circuits for this purpose have been described in the literature. They fall into one of the following categories: capacitive liquid level gauges, superconducting wire liquid level gauges, thermodynamic (heat transfer-based) liquid level gauges, resistive gauges, ultrasound and transmission line-based level detectors. The present paper reviews these techniques and their suitability for He II service. In addition to these methods, techniques for measuring the total liquid volume and mass gauging are also discussed.

  2. Efficiency of Chitosan for the Removal of Pb (II), Fe (II) and Cu (II) Ions from Aqueous Solutions

    OpenAIRE

    Soheil Sobhanardakani; Raziyeh Zandipak; Hassan Parvizimosaed; Arash Javanshir Khoei; Mehran Moslemi; Mahsa Tahergorabi; Seyed Mehdi Hosseini; Parisa Delfieh

    2014-01-01

    Background: Heavy metals have been recognized as harmful environmental pollutant known to produce highly toxic effects on different organs and systems of both humans and animals. The aim of this paper is to evaluate the adsorption potential of chitosan for the removal of Pb(II), Fe(II) and Cu(II) ions from aqueous solutions. Methods: This study was conducted in laboratory scale. In this paper chitosan has been used as an adsorbent for the removal of Pb(II), Fe(II) and Cu(II) from aqueous s...

  3. Solar Ca II K Observations

    Science.gov (United States)

    Bertello, Luca; Pevtsov, Alexei A.; Tlatov, Andrey; Singh, Jagdev

    2016-07-01

    Some of the most important archives of past and current long-term solar synoptic observations in the resonance line of Ca II K are described here. These observations are very important for understanding the state of the solar magnetism on time scales up to several decades. The first observations of this kind began in 1904 at the Kodaikanal Observatory (India), followed by similar programs at different other locations. Regular full-disk Ca II K monitoring programs started in 1915 at the Mount Wilson Observatory (USA) and in 1917 at the National Solar Observatory of Japan. Beginning in 1919 and in 1926 regular observations were taken also at the Paris-Meudon Observatory (France) and at the "Donati solar tower telescope of the Arcetri Astrophysical Observatory in Italy, respectively. In 1926 the the Astronomical Observatory of the Coimbra University in Portugal started its own program of Ca II K observations. Although some of these programs have been terminated over the years, their data archives constitute a unique resource for studies of solar variability. In the early 1970s, the National Solar Observatory (NSO) at Sacramento Peak (USA) started a new program of daily Sun-as-a-star observations in the Ca II K line. Today the NSO is continuing these observations through its Synoptic Optical Long-term Investigations of the Sun (SOLIS) facility.

  4. DUMAND-II progress report

    Energy Technology Data Exchange (ETDEWEB)

    Wilkes, R.J.; Alexander, C.M. (University of Hawaii (United States)); Aoki, T. (ICRR, University of Tokyo (Japan)); Berson, U.; Bosetti, P. (Technische Hochschule Aachen (Germany)); Bolesta, J. (University of Hawaii (United States)); Boynton, P.E. (University of Washington (United States)); Bradner, H. (Scripps Institution of Oceanography (United States)); Camerini, U. (University of Wisconsin (United States)); Dye, S.T.; Gergin, E. (Boston University (United States)); Gorham, P.W. (University of Hawaii (United States)); Grieder, P.K.F. (University of Bern (Switzerland)); Grogan, W. (University of Wisconsin (United States)); Hanada, H. (Tohoku University of Japan (Japan)); Harris, D. (University of Hawaii (United States)); Hayashino, T. (Tohoku University of Japan (Japan)); Hazen, E. (Boston University (United States)); Ito, M. (Tohoku University (Japan)); Jaworski, M. (ICRR, University of Tokyo (Japan)); Jenko, M. (Boston University (United States)); Kawamoto, H. (To; The DUMAND Collaboration:

    1993-06-15

    The design, scientific goals, and capabilities of the DUMAND II detector system are described. Construction was authorized by DOE in 1990, and construction of various detector subsystems is under way. Current plans include deployment of the shore cable, junction box and three strings of optical detector modules in 1993, with expansion to the full 9-string configuration about one year later.

  5. DUMAND-II progress report

    Science.gov (United States)

    Wilkes, R. J.; Alexander, C. M.; Aoki, T.; Berson, U.; Bosetti, P.; Bolesta, J.; Boynton, P. E.; Bradner, H.; Camerini, U.; Dye, S. T.; Gergin, E.; Gorham, P. W.; Grieder, P. K. F.; Grogan, W.; Hanada, H.; Harris, D.; Hayashino, T.; Hazen, E.; Ito, M.; Jaworski, M.; Jenko, M.; Kawamoto, H.; Kitamura, T.; Kobayakawa, K.; Kondo, S.; Koske, P.; Learned, J. G.; Ley, C.; Lord, J. J.; Lord, R.; Lozic, T.; March, R.; Matsumoto, T.; Matsuno, S.; Mavretic, A.; McCourry, L.; Mignard, M.; Miller, K.; Minkowski, P.; Mitiguy, R.; Mitsui, K.; Narita, S.; Nicklaus, D.; Ohashi, Y.; Okada, A.; Orlov, D.; Peterson, V. Z.; Roberts, A.; Sakuda, M.; Stenger, V. J.; Suzuki, H.; Tanaka, S.; Uehara, S.; Wiebusch, C.; Wilkins, G.; Webster, M.; Wilkes, R. J.; Wurm, G.; Yamaguchi, A.; Yamamoto, I.; Young, K. K.

    1993-06-01

    The design, scientific goals, and capabilities of the DUMAND II detector system are described. Construction was authorized by DOE in 1990, and construction of various detector subsystems is under way. Current plans include deployment of the shore cable, junction box and three strings of optical detector modules in 1993, with expansion to the full 9-string configuration about one year later.

  6. Light harvesting in photosystem II

    NARCIS (Netherlands)

    Amerongen, van H.; Croce, R.

    2013-01-01

    Water oxidation in photosynthesis takes place in photosystem II (PSII). This photosystem is built around a reaction center (RC) where sunlight-induced charge separation occurs. This RC consists of various polypeptides that bind only a few chromophores or pigments, next to several other cofactors. It

  7. NSLS-II RF SYSTEMS

    Energy Technology Data Exchange (ETDEWEB)

    Rose, J.; Gash, W.; Holub, B.; Kawashima, Y.; Ma, H.; Towne, N.; Yeddulla, M.

    2011-03-28

    The NSLS-II is a new third generation light source being constructed at Brookhaven Lab. The storage ring is optimized for low emittance by use of damping wigglers to reduce the emittance to below 1 nm-rad. The RF systems are designed to provide stable beam through tight RF phase and amplitude stability requirements.

  8. Elizabeth II / Fagira D. Morti

    Index Scriptorium Estoniae

    Fagira D. Morti, pseud., 1974-

    2006-01-01

    Järjejutt Elizabeth II elust. Järgneb nr. 80, lk. 30-33, nr. 81, lk. 30-32, nr. 82, lk. 34-36, nr. 83, lk. 34-37, nr. 84, lk. 42-45, nr. 85, lk. 36-38, 86, lk. 44-47, nr. 87, lk. 32-35. Nr. 86 ja 87 autor: Helene Wait

  9. DECOVALEX II PROJECT Executive Summary

    Energy Technology Data Exchange (ETDEWEB)

    Jing, L.; Stephansson, O. [Royal Inst. of Tech., Stockholm (Sweden). Dept. of Civil and Environmental Engineering; Tsang, C.F. [Lawrence Berkeley National Laboratory, Berkeley, CA (United States). Earth Science Div.; Knight, L.J. [United Kingdom Nirex Ltd., Harwell (United Kingdom); Kautsky, F. [Swedish Nuclear Power Inspectorate (SKI), Stockholm (Sweden)

    1999-11-01

    DECOVALEX II project started in November 1995 as a continuation of the DECOVALEX I project, which was completed at the end of 1994. The project was initiated by recognising the fact that a proper evaluation of the current capacities of numerical modelling of the coupled T-H-M processes in fractured media is needed not only for small scale, well controlled laboratory test cases such as those studied in DECOVALEX I, but also for less characterised, more complex and realistic in-situ experiments. This executive summary presents the motivation, structure, objectives, approaches, and highlights of the main tasks and main achievements of the DECOVALEX II project from 1995-1999. The main source of the materials came from four technical reports the project prepared by the project Secretariat, which, in turn, were based on numerous progress reports produced by a large number of international research teams over the three and half year period. The editors of this summary, together with the Steering Committee of the DECOVALEX II project, feel very encouraged by the progresses which have been made during the project time and very positive about the usefulness of the achievements reached by the project to the larger international community of scientific research and management of radioactive wastes in different countries. We sincerely hope that continued efforts be made to forward the research carried out in both DECOVALEX I and DECOVALEX II projects so that the disposal of radioactive waste could be managed on a more reliable scientific basis.

  10. Type-II Weyl semimetals.

    Science.gov (United States)

    Soluyanov, Alexey A; Gresch, Dominik; Wang, Zhijun; Wu, QuanSheng; Troyer, Matthias; Dai, Xi; Bernevig, B Andrei

    2015-11-26

    Fermions--elementary particles such as electrons--are classified as Dirac, Majorana or Weyl. Majorana and Weyl fermions had not been observed experimentally until the recent discovery of condensed matter systems such as topological superconductors and semimetals, in which they arise as low-energy excitations. Here we propose the existence of a previously overlooked type of Weyl fermion that emerges at the boundary between electron and hole pockets in a new phase of matter. This particle was missed by Weyl because it breaks the stringent Lorentz symmetry in high-energy physics. Lorentz invariance, however, is not present in condensed matter physics, and by generalizing the Dirac equation, we find the new type of Weyl fermion. In particular, whereas Weyl semimetals--materials hosting Weyl fermions--were previously thought to have standard Weyl points with a point-like Fermi surface (which we refer to as type-I), we discover a type-II Weyl point, which is still a protected crossing, but appears at the contact of electron and hole pockets in type-II Weyl semimetals. We predict that WTe2 is an example of a topological semimetal hosting the new particle as a low-energy excitation around such a type-II Weyl point. The existence of type-II Weyl points in WTe2 means that many of its physical properties are very different to those of standard Weyl semimetals with point-like Fermi surfaces.

  11. Tech Area II: A history

    Energy Technology Data Exchange (ETDEWEB)

    Ullrich, R. [Ktech Corp., Albuquerque, NM (United States)

    1998-07-01

    This report documents the history of the major buildings in Sandia National Laboratories` Technical Area II. It was prepared in support of the Department of Energy`s compliance with Section 106 of the National Historic Preservation Act. Technical Area II was designed and constructed in 1948 specifically for the final assembly of the non-nuclear components of nuclear weapons, and was the primary site conducting such assembly until 1952. Both the architecture and location of the oldest buildings in the area reflect their original purpose. Assembly activities continued in Area II from 1952 to 1957, but the major responsibility for this work shifted to other sites in the Atomic Energy Commission`s integrated contractor complex. Gradually, additional buildings were constructed and the original buildings were modified. After 1960, the Area`s primary purpose was the research and testing of high-explosive components for nuclear weapons. In 1994, Sandia constructed new facilities for work on high-explosive components outside of the original Area II diamond-shaped parcel. Most of the buildings in the area are vacant and Sandia has no plans to use them. They are proposed for decontamination and demolition as funding becomes available.

  12. Rahvusvaheline "Scripta manent II" Tallinnas

    Index Scriptorium Estoniae

    2000-01-01

    Eduard Taska 110. sünniaastapäevale pühendatud rahvusvaheline köitekunsti- ja kalligraafianäitus "Scripta manent II" Tallinna Kunstihoones. Köitekunsti osas pälvis "kuldraamatu" Marielle Liivat, ergutusauhinnad: Marje Kask, Kadi Kiipus, Urve Kolde

  13. Pol II CTD Code Light.

    Science.gov (United States)

    Corden, Jeffry L

    2016-01-21

    In this issue of Molecular Cell, Schüller et al. (2016) and Suh et al. (2016) describe genetic and mass spectrometry methodologies for mapping phosphorylation sites on the tandem repeats of the RNA polymerase II CTD. The results suggest that the CTD Code may be simpler than expected.

  14. Progress at Tis Abay II

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    The construction of the Tis Abay II hydro power project in Ethiopia, which is considered to be a key element in Ethiopia's power development programme, is nearing completion. It is hoped that the US$63M project, which is funded by the Ethiopian government, will help the country meet its 10-12% annual growth in electricity demand and support the expanding economy.

  15. Synthesis and spectral studies of Cu(II, Ni(II, Co(II, Mn(II, Zn(II and Cd(II complexes of a new macroacyclic ligand N,N’-bis(2-benzothiazolyl-2,6-pyridinedicarboxamide

    Directory of Open Access Journals (Sweden)

    KALAGOUDA B. GUDASI

    2006-05-01

    Full Text Available A new macroacyclic amide ligand N,N’-bis(2-benzothiazolyl-2,6-pyridinedicarboxamide (BPD, formed by the condensation of 2,6-pyridinedicarbonyldichloride with 2-aminobenzothiazole, and its Cu(II, Ni(II, Co(II, Mn(II, Zn(II and Cd(II complexes were synthesized. Their structures were elucidated on the basis of elemental analyses, conductance measurements, magnetic moments, spectral (IR, NMR, UV-Visible, EPR and FAB and thermal studies. The complexes exhibit an octahedral geometry around the metal center. Conductance data of the complexes suggested them to be 1:1 electrolytes. The pentadentate behavior of the ligand was proposed on the basis of spectral studies. The X-band EPR spectra of the Cu(II and Mn(II complexes in the polycrystalline state at room (300 K and liquid nitrogen temperature (77 K were recorded and their salient features are reported.

  16. Synthesis, spectroscopic, antimicrobial and DNA cleavage studies of new Co(II), Ni(II), Cu(II), Cd(II), Zn(II) and Hg(II) complexes with naphthofuran-2-carbohydrazide Schiff base

    Science.gov (United States)

    Halli, Madappa B.; Sumathi, R. B.

    2012-08-01

    A series of Co(II), Ni(II), Cu(II), Cd(II), Zn(II) and Hg(II) complexes have been synthesized with newly synthesized Schiff base derived from naphthofuran-2-carbohydrazide and cinnamaldehyde. The elemental analyses of the complexes are confined to the stoichiometry of the type MLCl2 [M = Co(II) and Cu(II)], ML2Cl2 [M = Ni(II), Cd(II), Zn(II) and Hg(II)] respectively, where L is Schiff base ligand. Structures have been proposed from elemental analyses, IR, electronic, mass, 1H NMR, ESR spectral data, magnetic, and thermal studies. The measured low molar conductance values in DMF indicate that the complexes are non-electrolytes. Spectroscopic studies suggest coordination occurs through azomethine nitrogen and carbonyl oxygen of the ligand with the metal ions. The Schiff base and its complexes have been screened for their antibacterial (Escherichia coli, Staphylococcus aureus, Bacillus subtilis and Salmonella typhi) and antifungal (Aspergillus niger, Aspergillus flavus, Cladosporium and Candida albicans) activities by minimum inhibitory concentration (MIC) method. The DNA cleavage studies by agarose gel electrophoresis method was studied for all the complexes.

  17. Selective chelation of Cd(II) and Pb(II) versus Ca(II) and Zn(II) by using octadentate ligands containing pyridinecarboxylate and pyridyl pendants.

    Science.gov (United States)

    Ferreirós-Martínez, Raquel; Esteban-Gómez, David; Platas-Iglesias, Carlos; de Blas, Andrés; Rodríguez-Blas, Teresa

    2009-12-07

    Herein we report the coordination properties toward Cd(II), Pb(II), Ca(II), and Zn(II) of a new octadentate ligand (py-H(2)bcpe) based on a ethane-1,2-diamine unit containing two picolinate and two pyridyl pendants, which is structurally derived from the previous reported ligand bcpe. Potentiometric studies have been carried out to determine the protonation constants of the ligand and the stability constants of the complexes with these cations. The introduction of the pyridyl pendants in bcpe provokes a very important increase of the logK(ML) values obtained for the Pb(II) and Cd(II) complexes, while this effect is less important in the case of the Zn(II) analogue. As a result, py-bcpe shows a certain selectivity for Cd(II) and Pb(II) over Zn(II) while keeping good Pb(II)/Ca(II) and Cd(II)/Ca(II) selectivities, and the new receptor py-bcpe can be considered as a new structural framework for the design of novel Cd(II) and Pb(II) extracting agents. Likewise, the stabilities of the Cd(II) and Pb(II) complexes are higher than those of the corresponding EDTA analogues. The X-ray crystal structure of [Zn(py-bcpe)] shows hexadentate binding of the ligand to the metal ion, the coordination polyhedron being best described as a severely distorted octahedron. However, the X-ray crystal structure of the Pb(II) analogue shows octadentate binding of the ligand to the metal ion. A detailed investigation of the structure in aqueous solution of the complexes by using nuclear magnetic resonance (NMR) techniques and density functional theory (DFT) calculations (B3LYP) shows that while in the Zn(II) complex the metal ion is six-coordinated, in the Pb(II) and Ca(II) analogues the metal ions are eight-coordinated. For the Cd(II) complex, our results suggest that in solution the complex exists as a mixture of seven- and eight-coordinated species. DFT calculations performed both in the gas phase and in aqueous solution have been also used to investigate the role of the Pb(II) lone pair in

  18. Information on Asse II; Informationen ueber die Schachtanlage Asse II

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2015-02-15

    The information brochure on Asse II describes the situation in the repository for radioactive wastes that was closed by law due to the violations of safety standards. The discussed topics include the necessity of waste retrieval, the problems with public anxiety and public information, the hazard of an uncontrolled water ingress (worst case scenario), the work sites in the cavern, man-machine interactions and the cost of the project.

  19. Physicochemical properties of 3,4,5-trimethoxybenzoates of Mn(II, Co(II, Ni(II and Zn(II

    Directory of Open Access Journals (Sweden)

    W. FERENC

    2005-09-01

    Full Text Available The complexes of Mn(II, Co(II, Ni(II, Cu(II and Zn(II with 3,4,5-trimethoxybenzoic acid anion of the formula: M(C10H11O52·nH2O, where n = 6 for Ni(II, n = 1 for Mn(II, Co(II, Cu(II, and n = 0 for Zn, have been synthesized and characterized by elemental analysis, IR spectroscopy, X–ray diffraction measurements, thermogravimetry and magnetic studies. They are crystalline compounds characterized by various symmetry. They decompose in various ways when heated in air to 1273 K. At first, they dehydrate in one step and form anhydrous salts. The final products of decomposition are oxides of the respective metals (Mn2O3, Co3O4, NiO, CuO, ZnO. The solubilities of the analysed complexes in water at 293 K are in the orders of 10-2 – 10-4 mol dm-3. The magnetic susceptibilities of the Mn(II, Co(II, Ni(II and Cu(II complexes were measured over the range of 76–303 K and the magnetic moments were calculated. The results show that the 3,4,5-trimethoxybenzoates of Mn(II, Co(II and Ni(II are high-spin complexes but that of Cu(II forms a dimer [Cu2(C10H11O54(H2O2]. The carboxylate groups bind as monodentate or bidentate chelating or bridging ligands.

  20. Cytotoxic copper(II), cobalt(II), zinc(II), and nickel(II) coordination compounds of clotrimazole.

    Science.gov (United States)

    Betanzos-Lara, Soledad; Gómez-Ruiz, Celedonio; Barrón-Sosa, Lidia R; Gracia-Mora, Isabel; Flores-Álamo, Marcos; Barba-Behrens, Noráh

    2012-09-01

    Sixteen novel mononuclear Cu(II), Co(II), Zn(II), and Ni(II) complexes of the biologically active ligand clotrimazole (clotri) of the forms [M(clotri)(2)Cl(2)]·nH(2)O (1-4), [M(clotri)(2)Br(2)]·nH(2)O (5-7), [M(clotri)(3)Br(2)] (8), [M(clotri)(3)NO(3)]NO(3)·nH(2)O (9, 11), [M(clotri)(3)(NO(3))(2)]·nH(2)O (10), and [M(clotri)(3)(OH(2))(2)NO(3)]NO(3)·nH(2)O (12) were synthesized and fully characterized. Dinuclear [Cu(2)(clotri)(4)μ(2)-Cl(4)]·2H(2)O (1a) and [Cu(2)(clotri)(4)μ(2)-Br(2)]·2H(2)O (5b) as well as tetranuclear [Cu(4)(clotri)(4)μ(4)-Br(6)μ(4)-O] (5a) complexes were also isolated. Complexes 1-7, 9, and 11 present a tetrahedral geometry; complex 8 exhibits a pentacoordinated structure; complexes 1a, 10 and 12 an octahedral geometry. X-ray crystal structures of [Cu(clotri)(2)Cl(2)](1), [Cu(clotri)(2)(EtOH)Cl(2)](1·EtOH), [Zn(clotri)(2)Cl(2)] (3), [Zn(clotri)(2)Br(2)] (7), and [Cu(4)(clotri)(4)μ(4)-Br(6)μ(4)-O] (5a) were obtained. Complexes 1-12 were tested for cytotoxic activity against the human carcinoma cell lines HeLa (cervix-uterine), PC3 (prostate), and HCT-15 (colon) displaying IC(50) values <30 μM. Confocal microscopy and nuclear dying (DAPI) for complex 1 showed condensation of cromatin and nuclear membrane fragmentation. Immunocytochemical detection/expression of biomarkers suggests that complexes 1 and 9 induce cell death via apoptosis. TUNEL assay detected DNA fragmentation in HeLa cells, resulting from apoptotic signaling cascades induced by Cu(II) complexes 1 and 9. (1)H NMR studies of the Zn(II) complexes showed that they can bind to nucleotides.

  1. World War II Weather Record Transmittances

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — World War II Weather Record Transmittances are a record of the weather and meteorological data observed during World War II and transferred to the archive. It...

  2. Unusual route for preparation of manganese(II), cobalt(II), zinc(II) and cadmium(II) carbonate compounds: synthesis and spectroscopic characterizations

    Indian Academy of Sciences (India)

    Moamen S Refat; Mohsen M Al-Qahtani

    2011-07-01

    The manganese(II) carbonate, MnCO3.H2O, cobalt(II) carbonate, CoCO3.4H2O, zinc(II) carbonate, ZnCO3 and cadmium(II) carbonate, CdCO3, respectively, were synthesis by a new simple unusual route during the reaction of aqueous solutions of MnX2, CoX2, ZnX2 and CdX2, where (X = Br- and ClO$^{-}_{4}$) with urea at high temperature within ∼ 90°C for 6 h. The infrared spectra of the reaction products clearly indicate the absence of the bands of urea, but show the characteristic bands of ionic carbonate, CO$^{2-}_{3}$. A general mechanism describing the preparation of manganese(II), cobalt(II), zinc(II) and cadmium(II) carbonate compounds are discussed.

  3. The synthesis and characterization of complexes of zinc(II, cadmium(II, platinum(II and palladium(II with potassium 3-dithiocarboxy-3-aza-5-aminopentanoate

    Directory of Open Access Journals (Sweden)

    SRECKO TRIFUNOVIC

    2004-02-01

    Full Text Available Complexes of zinc(II, cadmium(II, platinum(II and palladium(II with a new polydentate dithiocarbamate ligand, 3-dithiocarboxy-3-aza-5-aminopentanoate (daap-, of the type M(daap2·nH2O (M = Zn(II, Cd(II, n = 2, or M = Pt(II, Pd(II, n = 0, have been prepared and characterized by elemental analysis, IR and UV/VIS spectroscopy, as well as magnetic measurements. The spectra of the complexes suggest a bidentate coordination of the daap- ligand to the metal ions via the sulfur atoms of the deprotonated dithiocarbamato group. The fact that under the same experimental conditions its S-methyl ester does not form complexes could be taken as proof of the suggested coordination mode.

  4. Belle II silicon vertex detector

    Science.gov (United States)

    Adamczyk, K.; Aihara, H.; Angelini, C.; Aziz, T.; Babu, V.; Bacher, S.; Bahinipati, S.; Barberio, E.; Baroncelli, Ti.; Baroncelli, To.; Basith, A. K.; Batignani, G.; Bauer, A.; Behera, P. K.; Bergauer, T.; Bettarini, S.; Bhuyan, B.; Bilka, T.; Bosi, F.; Bosisio, L.; Bozek, A.; Buchsteiner, F.; Casarosa, G.; Ceccanti, M.; Červenkov, D.; Chendvankar, S. R.; Dash, N.; Divekar, S. T.; Doležal, Z.; Dutta, D.; Enami, K.; Forti, F.; Friedl, M.; Hara, K.; Higuchi, T.; Horiguchi, T.; Irmler, C.; Ishikawa, A.; Jeon, H. B.; Joo, C. W.; Kandra, J.; Kang, K. H.; Kato, E.; Kawasaki, T.; Kodyš, P.; Kohriki, T.; Koike, S.; Kolwalkar, M. M.; Kvasnička, P.; Lanceri, L.; Lettenbicher, J.; Maki, M.; Mammini, P.; Mayekar, S. N.; Mohanty, G. B.; Mohanty, S.; Morii, T.; Nakamura, K. R.; Natkaniec, Z.; Negishi, K.; Nisar, N. K.; Onuki, Y.; Ostrowicz, W.; Paladino, A.; Paoloni, E.; Park, H.; Pilo, F.; Profeti, A.; Rashevskaya, I.; Rao, K. K.; Rizzo, G.; Rozanska, M.; Sandilya, S.; Sasaki, J.; Sato, N.; Schultschik, S.; Schwanda, C.; Seino, Y.; Shimizu, N.; Stypula, J.; Suzuki, J.; Tanaka, S.; Tanida, K.; Taylor, G. N.; Thalmeier, R.; Thomas, R.; Tsuboyama, T.; Uozumi, S.; Urquijo, P.; Vitale, L.; Volpi, M.; Watanuki, S.; Watson, I. J.; Webb, J.; Wiechczynski, J.; Williams, S.; Würkner, B.; Yamamoto, H.; Yin, H.; Yoshinobu, T.

    2016-09-01

    The Belle II experiment at the SuperKEKB collider in Japan is designed to indirectly probe new physics using approximately 50 times the data recorded by its predecessor. An accurate determination of the decay-point position of subatomic particles such as beauty and charm hadrons as well as a precise measurement of low-momentum charged particles will play a key role in this pursuit. These will be accomplished by an inner tracking device comprising two layers of pixelated silicon detector and four layers of silicon vertex detector based on double-sided microstrip sensors. We describe herein the design, prototyping and construction efforts of the Belle-II silicon vertex detector.

  5. Belle II Silicon Vertex Detector

    CERN Document Server

    Mohanty, Gagan B

    2015-01-01

    The Belle II experiment at the SuperKEKB collider in Japan is designed to indirectly probe new physics using approximately 50 times the data recorded by its predecessor. An accurate determination of the decay-point position of subatomic particles such as beauty and charm hadrons as well as a precise measurement of low-momentum charged particles will play a key role in this pursuit. These will be accomplished by a vertex detector, which comprises two layers of pixelated silicon detector and four layers of silicon vertex detector. We describe herein the design, prototyping and construction efforts of the Belle-II silicon vertex detector that is aimed to be commissioned towards the middle of 2017.

  6. [Tyrosinemia type II. Case report].

    Science.gov (United States)

    Benatiya, A I; Bouayed, M A; Touiza, E; Daoudi, K; Bhalil, S; Elmesbahi, I; Tahri, H

    2005-01-01

    Tyrosinemia type II or Richner-Hanhart syndrome is a rare hereditary disease characterized by the association of pseudoherpetiform corneal ulcerations and palmoplantar hyperkeratosis. We report the case of a 12 year-old young man presenting a superficial punctate keratitis and a corneal dystrophy in both eyes, associated with a palmoplantar hyperkeratosis. The dosage of the serum level of tyrosine is meaningfully raised to 1236 micromol/l. A dietary treatment restraining tyrosine and phenylalanine is started with favorable results after an evolution of 6 months. Tyrosinemia type II is an autosomal recessive disease, due to an enzymatic deficit in tyrosine aminotransferase. The diagnosis is based on the clinic and high level of serum and urinary tyrosine as well as of its urinary metabolites. This disease must be suspected in all cases of dentritic keratitis not reacting on the antiviral treatment, and more especially if it is associated with cutaneous lesions such as palmo-plantar keratosis.

  7. Belle II silicon vertex detector

    Energy Technology Data Exchange (ETDEWEB)

    Adamczyk, K. [H. Niewodniczanski Institute of Nuclear Physics, Krakow 31-342 (Poland); Aihara, H. [Department of Physics, University of Tokyo, Tokyo 113-0033 (Japan); Angelini, C. [Dipartimento di Fisica, Università di Pisa, I-56127 Pisa (Italy); INFN Sezione di Pisa, I-56127 Pisa (Italy); Aziz, T.; Babu, V. [Tata Institute of Fundamental Research, Mumbai 400005 (India); Bacher, S. [H. Niewodniczanski Institute of Nuclear Physics, Krakow 31-342 (Poland); Bahinipati, S. [Indian Institute of Technology Bhubaneswar, Satya Nagar (India); Barberio, E.; Baroncelli, Ti.; Baroncelli, To. [School of Physics, University of Melbourne, Melbourne, Victoria 3010 (Australia); Basith, A.K. [Indian Institute of Technology Madras, Chennai 600036 (India); Batignani, G. [Dipartimento di Fisica, Università di Pisa, I-56127 Pisa (Italy); INFN Sezione di Pisa, I-56127 Pisa (Italy); Bauer, A. [Institute of High Energy Physics, Austrian Academy of Sciences, 1050 Vienna (Austria); Behera, P.K. [Indian Institute of Technology Madras, Chennai 600036 (India); Bergauer, T. [Institute of High Energy Physics, Austrian Academy of Sciences, 1050 Vienna (Austria); Bettarini, S. [Dipartimento di Fisica, Università di Pisa, I-56127 Pisa (Italy); INFN Sezione di Pisa, I-56127 Pisa (Italy); Bhuyan, B. [Indian Institute of Technology Guwahati, Assam 781039 (India); Bilka, T. [Faculty of Mathematics and Physics, Charles University, 121 16 Prague (Czech Republic); Bosi, F. [INFN Sezione di Pisa, I-56127 Pisa (Italy); Bosisio, L. [Dipartimento di Fisica, Università di Trieste, I-34127 Trieste (Italy); INFN Sezione di Trieste, I-34127 Trieste (Italy); and others

    2016-09-21

    The Belle II experiment at the SuperKEKB collider in Japan is designed to indirectly probe new physics using approximately 50 times the data recorded by its predecessor. An accurate determination of the decay-point position of subatomic particles such as beauty and charm hadrons as well as a precise measurement of low-momentum charged particles will play a key role in this pursuit. These will be accomplished by an inner tracking device comprising two layers of pixelated silicon detector and four layers of silicon vertex detector based on double-sided microstrip sensors. We describe herein the design, prototyping and construction efforts of the Belle-II silicon vertex detector.

  8. Roget's II the new thesaurus

    CERN Document Server

    2003-01-01

    Roget’s II: The New Thesaurus, Third Edition, allows the user to find the right synonym with a minimum of effort. Unlike many thesauruses, this easy-to-use reference lists main entry words alphabetically, as in a dictionary, for quick lookup. Each entry is divided into senses, with brief definitions and a full list of synonyms for each sense, to ensure that the selected usage is the most appropriate one. All special usages, such as slang terms, are labeled and grouped together at the end of each synonym list. Following each list is a cross-reference to a related entry in the thesaurus’s unique Category Index. This index leads the reader from the starting word to dozens of others that have related or opposite meanings. All these features make Roget’s II the best resource for finding the right word every time.

  9. Particle Identification at Belle II

    CERN Document Server

    Sandilya, S

    2016-01-01

    We report on the charged particle identification (PID) systems for the upcoming Belle II experiment. The time of propagation counter in the central region and the proximity focusing ring imaging Cherenkov counters with aerogel radiator in the forward region will be used as the PID devices. They are expected to provide a kaon identification efficiency of more than 94% at a low pion misidentification probability of 4%. The motivation for the upgrade, method, and status of both systems are discussed.

  10. Fe II emission in AGN

    Directory of Open Access Journals (Sweden)

    M. Joly

    2008-01-01

    Full Text Available El espectro óptico de las galaxias Seyfert 1 muestra una gran variedad de líneas de emisión producidas por FeII. Damos tres ejemplos e investigamos la formación de estas líneas con el fin de determinar las condiciones físicas de las regiones en donde se emiten.

  11. MPS II drift chamber system

    Energy Technology Data Exchange (ETDEWEB)

    Platner, E.D.

    1982-01-01

    The MPS II detectors are narrow drift space chambers designed for high position resolution in a magnetic field and in a very high particle flux environment. Central to this implementation was the development of 3 multi-channel custom IC's and one multi-channel hybrid. The system is deadtimeless and requires no corrections on an anode-to-anode basis. Operational experience and relevance to ISABELLE detectors is discussed.

  12. Synthetic, spectral and solution studies on imidazolate-bridged copper(II)-copper(II) and copper(II)-zinc(II) complexes

    Indian Academy of Sciences (India)

    Subodh Kumar; R N Patel; P V Khadikar; K B Pandeya

    2001-02-01

    Synthesis, spectral and solution studies on 2-ethyl imidazolate-bridged (2-EtIm) homo-binuclear copper(II)-copper(II) and hetero-binuclear copper(II)-zinc(II) homologue are described. Magnetic moment values of homo-binuclear complexes indicate that the imidazolate group can mediate antiferromagnetic interactions. Optical spectra of hetero-binuclear complex at varying H values suggest that the imidazolate-bridged complex is stable over the H-range 7 15-10 0.

  13. Copper(II), cobalt(II), nickel(II) and zinc(II) complexes of Schiff base derived from benzil-2,4-dinitrophenylhydrazone with aniline

    Indian Academy of Sciences (India)

    N Raman; S Ravichandran; C Thangaraja

    2004-06-01

    New Schiff base chelates of Cu(II), Co(II), Ni(II) and Zn(II) derived from benzil-2,4-dinitrophenylhydrazone with aniline have been synthesised. Microanalytical data, molar conductance, and magnetic susceptibility values have been obtained, and IR, 1H NMR, 13C NMR, UV-Vis, CV and EPR spectral studies have been carried out to suggest tentative structures for the complexes.

  14. Potentiometric study of atenolol as hypertension drug with Co(II, Ni(II, Cu(II and Zn(II transition metal ions in aqueous solution

    Directory of Open Access Journals (Sweden)

    Abdulbaset A. Zaid

    2015-01-01

    Full Text Available Binary and ternary complexes of Co(II, Ni(II, Cu(II and Zn(II with atenolol as hypertension drug and glycine have been determined pH metrically at room temperature and 0.01 M ionic strength (NaClO4 in aqueous solution. The formation of various possible species has been evaluated by computer program and discussed in terms of various relative stability parameters.

  15. Efficiency of Chitosan for the Removal of Pb (II, Fe (II and Cu (II Ions from Aqueous Solutions

    Directory of Open Access Journals (Sweden)

    Soheil Sobhanardakani

    2014-09-01

    Full Text Available Background: Heavy metals have been recognized as harmful environmental pollutant known to produce highly toxic effects on different organs and systems of both humans and animals. The aim of this paper is to evaluate the adsorption potential of chitosan for the removal of Pb(II, Fe(II and Cu(II ions from aqueous solutions. Methods: This study was conducted in laboratory scale. In this paper chitosan has been used as an adsorbent for the removal of Pb(II, Fe(II and Cu(II from aqueous solution. In batch tests, the effects of parameters like pH solution (1.0-8.0, initial metal concentrations (100-1000 mgL-1, contact time (5.0-150 min and adsorbent dose (1.0-7.0 g on the adsorption process were studied. Results: The results showed that the adsorption of Pb(II, Fe(II and Cu(II ions on chitosan strongly depends on pH. The experimental isothermal data were analyzed using the Langmuir and Freundlich equations and it was found that the removal process followed the Langmuir isotherm and maximum adsorption capacity for the adsorption of Pb(II, Fe(II and Cu(II ions by the chitosan were 55.5mg g−1, 71.4 mg g−1 and 59 mg g−1, respectively, under equilibrium conditions at 25±1 ºC. The adsorption process was found to be well described by the pseudo-second-order rate model. Conclusion: The obtained results showed that chitosan is a readily, available, economic adsorbent and was found suitable for removing Pb(II, Fe(II and Cu(II ions from aqueous solution.

  16. PEP-II Operations Report

    Energy Technology Data Exchange (ETDEWEB)

    Zisman, Michael S.

    2000-11-01

    PEP-II is a two-ring asymmetric B factory operating at the Upsilon(4S) resonance. It was constructed by a SLAC-LBNL-LLNL collaboration. The collider comprises two rings, a High-Energy Ring (HER) storing 9 GeV electrons, and a Low-Energy Ring (LER) storing 3.1 GeV positrons. Commissioning of the HER began in mid-1997 and commissioning of the LER began in mid-1998. First evidence for collisions was obtained on July 23, 1998. The BaBar detector was installed in early 1999, and commissioning with the detector commenced in May 1999. By September 1999, PEP-II had reached a peak luminosity of 1.35 x 10{sup 33} cm{sup {minus}2} s{sup {minus}1}. In the present run, which began in October 1999, the peak luminosity has reached 3.1 x 10{sup 33} cm{sup {minus}2} s{sup {minus}1} and the integrated luminosity delivered is 25 fb{sup {minus}1}. At present, PEP-II is the world's highest luminosity collider. In this paper we describe the startup experience and summarize the operational experience during fiscal year 2000 (from October 1999 through September 2000). Plan s for luminosity upgrades are briefly described.

  17. Urotensin II in cardiovascular regulation

    Directory of Open Access Journals (Sweden)

    Fraser D Russell

    2008-08-01

    Full Text Available Fraser D RussellSchool of Health and Sport Sciences, Faculty of Science, Health and Education, University of the Sunshine Coast, Sippy Downs, Queensland, AustraliaAbstract: Cardiovascular function is modulated by neuronal transmitters, circulating hormones, and factors that are released locally from tissues. Urotensin II (UII is an 11 amino acid peptide that stimulates its’ obligatory G protein coupled urotensin II receptors (UT to modulate cardiovascular function in humans and in other animal species, and has been implicated in both vasculoprotective and vasculopathic effects. For example, tissue and circulating concentrations of UII have been reported to increase in some studies involving patients with atherosclerosis, heart failure, hypertension, preeclampsia, diabetes, renal disease and liver disease, raising the possibility that the UT receptor system is involved in the development and/or progression of these conditions. Consistent with this hypothesis, administration of UT receptor antagonists to animal models of cardiovascular disease have revealed improvements in cardiovascular remodelling and hemodynamics. However, recent studies have questioned this contributory role of UII in disease, and have instead postulated a protective effect on the cardiovascular system. For example, high concentrations of circulating UII correlated with improved clinical outcomes in patients with renal disease or myocardial infarction. The purpose of this review is to consider the regulation of the cardiovascular system by UII, giving consideration to methodologies for measurement of plasma concentrations, sites of synthesis and triggers for release.Keywords: urotensin II, cardiovascular disease, heart failure, hypertension

  18. Topaz II preliminary safety assessment

    Science.gov (United States)

    Marshall, Albert C.; Standley, Vaughn; Voss, Susan S.; Haskin, Eric

    1993-01-01

    The Strategic Defense Initiative Organization (SDIO) decided to investigate the possibility of launching a Russian Topaz II space nuclear power system. A preliminary safety assessment was conducted to determine whether or not a space mission could be conducted safely and within budget constraints. As part of this assessment, a safety policy and safety functional requirements were developed to guide both the safety assessment and future Topaz II activities. A review of the Russian flight safety program was conducted and documented. Our preliminary safety assessment included a top level event tree, neutronic analysis of normal and accident configurations, an evaluation of temperature coefficients of reactivity, a reentry and disposal analysis, and analysis of postulated launch abort impact accidents, and an analysis of postulated propellant fire and explosion accidents. Based on the assessment, it appears that it will be possible to safely launch the Topaz II system in the U.S. with some possible system modifications. The principal system modifications will probably include design changes to preclude water flooded criticality and to assure intact reentry.

  19. Levels of Cd (II, Mn (II, Pb (II, Cu (II, and Zn (II in Common Buzzard (Buteo buteo from Sicily (Italy by Derivative Stripping Potentiometry

    Directory of Open Access Journals (Sweden)

    P. Licata

    2010-01-01

    Full Text Available The purpose of this study was to determine the concentrations of heavy metals (Cd, Pb, Cu, Mn, and Zn in different organs (liver, kidney, muscle, lung, skin, and feathers of buzzards (Buteo buteo, utilized as a “biological indicator” for environmental contamination, from different areas of Sicily and to investigate the relationships between birds sex, age, and weight and metal levels in these samples. All samples of common buzzards were collected at the “Recovery Center of Wild Fauna” of Palermo, through the Zooprophilactic Institute. Potentiometric stripping analysis (PSA was used to determine the content of Cd(II, Cu(II, Mn(II, Pb(II, and Zn(II in bird tissues. For toxic metals, the highest levels of Pb were in liver and those of Cd in lung; Zn levels were higher than Cu and Mn in all tissues analyzed. The concentrations in liver, lung, kidney, and muscle could be considered as an indicative of chronic exposure to metals while the presence of metals in skin could be consequential to storing and elimination processes. The found concentrations of metals in the studied matrices required a highly sensitive method for their determination and a simple sample preparation procedure, and the proposed method was well suited for this purpose.

  20. The McClellan-Kerr Waterway and Regional Economic Development - Phase II Study.

    Science.gov (United States)

    1985-11-01

    by Walras in the ... late ninteenth century (1954). Recently, Liew (1980), Hudson and Jorgenson (1974, 1976) introduced prices into the computation of...Review of Economics and Statistics, August, 1957. 37. Walras , L., Elements of Pure Economics, (English Edition), George Allen and * Urwin, London, 1954

  1. Neurofibromatosis type II presenting as vertical diplopia.

    Science.gov (United States)

    Sokwala, Ahmed; Knapp, Christopher; Gottlob, Irene

    2004-09-01

    Neurofibromatosis type II (NF II) is rare and most commonly presents with hearing loss, tinnitus and/or vestibular disturbance in the third decade of life. The authors describe a rare case presenting with NF II with vertical diplopia due to IV(th) nerve palsy. The patient was otherwise asymptomatic despite multiple extensive lesions on MRI.

  2. Competition from Cu(II), Zn(II) and Cd(II) in Pb(II) binding to Suwannee River Fulvic Acid

    NARCIS (Netherlands)

    Chakraborty, P.; Chakrabarti, C.L.

    2008-01-01

    This is a study of trace metal competition in the complexation of Pb(II) by well-characterized humic substances, namely Suwannee River Fulvic Acid (SRFA) in model solutions. It was found that Cu(II) seems to compete with Pb(II) for strong binding sites of SRFA when present at the same concentration

  3. Argus II retinal prosthesis system: An update.

    Science.gov (United States)

    Rachitskaya, Aleksandra V; Yuan, Alex

    2016-09-01

    This review focuses on a description of the Argus II retinal prosthesis system (Argus II; Second Sight Medical Products, Sylmar, CA) that was approved for humanitarian use by the FDA in 2013 in patients with retinitis pigmentosa with bare or no light perception vision. The article describes the components of Argus II, the studies on the implant, and future directions.

  4. Macrocyclic receptor showing extremely high Sr(II)/Ca(II) and Pb(II)/Ca(II) selectivities with potential application in chelation treatment of metal intoxication.

    Science.gov (United States)

    Ferreirós-Martínez, Raquel; Esteban-Gómez, David; Tóth, Éva; de Blas, Andrés; Platas-Iglesias, Carlos; Rodríguez-Blas, Teresa

    2011-04-18

    Herein we report a detailed investigation of the complexation properties of the macrocyclic decadentate receptor N,N'-Bis[(6-carboxy-2-pyridil)methyl]-4,13-diaza-18-crown-6 (H(2)bp18c6) toward different divalent metal ions [Zn(II), Cd(II), Pb(II), Sr(II), and Ca(II)] in aqueous solution. We have found that this ligand is especially suited for the complexation of large metal ions such as Sr(II) and Pb(II), which results in very high Pb(II)/Ca(II) and Pb(II)/Zn(II) selectivities (in fact, higher than those found for ligands widely used for the treatment of lead poisoning such as ethylenediaminetetraacetic acid (edta)), as well as in the highest Sr(II)/Ca(II) selectivity reported so far. These results have been rationalized on the basis of the structure of the complexes. X-ray crystal diffraction, (1)H and (13)C NMR spectroscopy, as well as theoretical calculations at the density functional theory (B3LYP) level have been performed. Our results indicate that for large metal ions such as Pb(II) and Sr(II) the most stable conformation is Δ(δλδ)(δλδ), while for Ca(II) our calculations predict the Δ(λδλ)(λδλ) form being the most stable one. The selectivity that bp18c6(2-) shows for Sr(II) over Ca(II) can be attributed to a better fit between the large Sr(II) ions and the relatively large crown fragment of the ligand. The X-ray crystal structure of the Pb(II) complex shows that the Δ(δλδ)(δλδ) conformation observed in solution is also maintained in the solid state. The Pb(II) ion is endocyclically coordinated, being directly bound to the 10 donor atoms of the ligand. The bond distances to the donor atoms of the pendant arms (2.55-2.60 Å) are substantially shorter than those between the metal ion and the donor atoms of the crown moiety (2.92-3.04 Å). This is a typical situation observed for the so-called hemidirected compounds, in which the Pb(II) lone pair is stereochemically active. The X-ray structures of the Zn(II) and Cd(II) complexes show that

  5. Co(II)-detection does not follow Kco(II) gradient : channelling in Co(II)-sensing.

    OpenAIRE

    Patterson, C J; Pernil, R.; Dainty, S.J.; Chakrabarti, B; Henry, C. E.; Money, V.A.; Foster, A.W.; N. J. Robinson

    2013-01-01

    The MerR-like transcriptional activator CoaR detects surplus Co(II) to regulate Co(II) efflux in a cyanobacterium. This organism also has cytosolic metal-sensors from three further families represented by Zn(II)-sensors ZiaR and Zur plus Ni(II)-sensor InrS. Here we discover by competition with Fura-2 that CoaR has KCo(II) weaker than 7 × 10−8 M, which is weaker than ZiaR, Zur and InrS (KCo(II) = 6.94 ± 1.3 × 10−10 M; 4.56 ± 0.16 × 10−10 M; and 7.69 ± 1.1 × 10−9 M respectively). KCo(II) for Co...

  6. The bovine class II major histocompatibility complex: Serological definition and further characterization of class II haplotypes.

    NARCIS (Netherlands)

    Nilsson, Ph.R.

    1994-01-01

    In this thesis an analysis of the major histocompatibility complex (MHC) class II in cattle is reported, with emphasis on the development of class II serology. First, the production of class II alloantisera, and the serological definition of bovine MHC class II polymorphism is described. Subsequentl

  7. Mixed metal copper(II)-nickel(II) and copper(II)-zinc(II) complexes of multihistidine peptide fragments of human prion protein.

    Science.gov (United States)

    Jószai, Viktória; Turi, Ildikó; Kállay, Csilla; Pappalardo, Giuseppe; Di Natale, Giuseppe; Rizzarelli, Enrico; Sóvágó, Imre

    2012-07-01

    Mixed metal copper(II)-nickel(II) and copper(II)-zinc(II) complexes of four peptide fragments of human prion protein have been studied by potentiometric, UV-vis and circular dichroism spectroscopic techniques. One peptide contained three histidyl residues: HuPrP(84-114) with H85 inside and H96, H111 outside the octarepeat domain. The other three peptides contained two histidyl residues; H96 and H111 for HuPrP(91-115) and HuPrP(84-114)H85A while HuPrP(84-114)H96A contained the histidyl residues at positions 85 and 111. It was found that both histidines of the latter peptides can simultaneously bind copper(II) and nickel(II) ions and dinuclear mixed metal complexes can exist in slightly alkaline solution. One molecule of the peptide with three histidyl residues can bind two copper(II) and one nickel(II) ions. H85 and H111 were identified as the major copper(II) and H96 as the preferred nickel(II) binding sites in mixed metal species. The studies on the zinc(II)-PrP peptide binary systems revealed that zinc(II) ions can coordinate to the 31-mer PrP peptide fragments in the form of macrochelates with two or three coordinated imidazol-nitrogens but the low stability of these complexes cannot prevent the hydrolysis of the metal ion in slightly alkaline solution. These data provide further support for the outstanding affinity of copper(II) ions towards the peptide fragments of prion protein but the binding of nickel(II) can significantly modify the distribution of copper(II) among the available metal binding sites.

  8. Synthesis, spectral characterization and biological evaluation of Mn(II), Co(II), Ni(II), Cu(II), Zn(II) and Cd(II) complexes with thiosemicarbazone ending by pyrazole and pyridyl rings

    Science.gov (United States)

    Yousef, T. A.; Abu El-Reash, G. M.; Al-Jahdali, M.; El-Rakhawy, El-Bastawesy R.

    2014-08-01

    Here we present the synthesis of the new Mn(II), Co(II), Ni(II), Cu(II), Zn(II) and Cd(II) complexes with chelating ligand (Z)-(2-((1,3-diphenyl-1H-pyrazol-4-yl)methylene) hydrazinyl)(pyridin-2-ylamino)methanethiol. All the complexes were characterized by elemental analysis, IR, 1H NMR, UV-vis, magnetic susceptibility measurements and EPR spectral studies. IR spectra of complexes showed that the ligand behaves as NN neutral bidentate, NSN mononegative tridentate and NSNN mononegative tetradentate. The electronic spectra and the magnetic measurements suggested the octahedral geometry for all complexes as well as the EPR confirmed the tetragonal distorted octahedral for Cu(II) complex. Cd(II) complex showed the highest inhibitory antioxidant activity either using ABTS method. The SOD-like activity exhibited those Cd(II) and Zn(II) complexes have strong antioxidative properties. We tested the synthesized compounds for antitumor activity and showed that the ability to kill liver (HePG2) and breast (MCF-7) cancer cells definitely.

  9. Ambiguity in Edward II Ambiguity in Edward II

    Directory of Open Access Journals (Sweden)

    Carmen Gago Alvarez

    2008-04-01

    Full Text Available This paper examines the ambiguity of characterization in Christopher Marlowe’s Edward II, probably written in 1591. Marlowe’s characters belong to the History of England in the fourteenth century and are portrayed as vividly interesting, contradicting, unpredictable human beings who sometimes surprise us, even astonish us with their sudden change of attitude and mind. The appraisal that follows is meant to demonstrate how these features are both a result of the appropriation of History and of its dramaturgical transformation. This paper examines the ambiguity of characterization in Christopher Marlowe’s Edward II, probably written in 1591. Marlowe’s characters belong to the History of England in the fourteenth century and are portrayed as vividly interesting, contradicting, unpredictable human beings who sometimes surprise us, even astonish us with their sudden change of attitude and mind. The appraisal that follows is meant to demonstrate how these features are both a result of the appropriation of History and of its dramaturgical transformation.

  10. 2-line ferrihydrite: synthesis, characterization and its adsorption behaviour for removal of Pb(II), Cd(II), Cu(II) and Zn(II) from aqueous solutions.

    Science.gov (United States)

    Rout, K; Mohapatra, M; Anand, S

    2012-03-21

    Nano-structured 2-line ferrihydrite was synthesized by a pH-controlled precipitation technique at 90 °C. Chemical, X-ray diffraction (XRD), Fourier transform infrared (FTIR) and Raman analyses confirmed the sample to be 2-line ferrihydrite. The nano nature of the prepared sample was studied by transmission electron microscopy (TEM). The surface area obtained by the Brunauer-Emmett-Teller (BET) method was 175.8 m(2) g(-1). The nanopowder so obtained was used to study its behaviour for the removal of Pb(II), Cd(II), Cu(II) and Zn(II) from aqueous solutions. The relative importance of experimental parameters such as solution pH, contact time and concentration of adsorbate on the uptake of various cations was evaluated. By increasing the pH from 2.0 to 5.5, adsorption of the four cations increased. The kinetics parameters were compared by fitting the contact time data to both linear as well as non-linear forms of pseudo-second-order models. Linear forms of both Langmuir and Freundlich models fitted the equilibrium data of all the cations except for Pb(II) which was also fitted to the non-linear forms of both the models as it gave a low R(2) value of 0.85 for the Langmuir model. High Langmuir monolayer capacities of 366, 250, 62.5 and 500 mg g(-1) were obtained for Pb(II), Cd(II), Cu(II) and Zn(II), respectively. Presence of chloride or sulfate had an adverse effect on cation adsorption. The interactive effects on adsorption from solutions containing two, three or four cations were studied. Surprisingly no Cd(II) adsorption was observed in Pb(II)-Cd(II), Pb(II)-Cd(II)-Zn(II) and Pb(II)-Cd(II)-Cu(II)-Zn(II) systems under the studied concentration range. The overall loading capacity of the adsorbent decreased in mixed cation systems. Metal ion loaded adsorbents were characterized by XRD, FTIR and Raman techniques. The high adsorption capability of the 2-lines ferrihydrite makes it a potentially attractive adsorbent for the removal of cations from aqueous solutions.

  11. Commissioning of NSLS-II

    Energy Technology Data Exchange (ETDEWEB)

    Willeke, F.

    2015-05-03

    NSLS-II, the new 3rd generation light source at BNL was designed for a brightness of 1022 photons s-1mm-2mrad-2 (0.1%BW)-1. It was constructed between 2009 and 2014. The storage ring was commissioned in April 2014 which was followed by insertion device and beamline commissioning in the fall of 2014. All ambitious design parameters of the facility have already been achieved except for commissioning the full beam intensity of 500mA which requires more RF installation. This paper reports on the results of commissioning.

  12. Tetraquabis(5-fluorosaccharinatonickel(II

    Directory of Open Access Journals (Sweden)

    Larnelle Peterson

    2009-04-01

    Full Text Available In the centrosymmetric title complex, [Ni(C7H3FNO3S2(H2O4], the NiII atom exhibits a slightly distorted trans-NiN2O4 octahedral coordination. The nitrogen donors are provided by two 5-fluorosaccharinate ligands and the oxygen donors are provided by four water molecules. The crystal structure features O—H...O and bifurcated O—H...(F,O hydrogen bonds, the latter involving the F atom of the 5-fluorosaccharinate ligand.

  13. Belle II and Hadron spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Križan, Peter, E-mail: peter.krizan@ijs.si [J. Stefan Institute and University of Ljubljana (Slovenia)

    2015-08-15

    Asymmetric B factories, PEP-II with BaBar and KEKB with Belle, made a decisive contribution to flavour physics. In addition, they also observed a long list of new hadrons, some of which do not fit into the standard meson and baryon schemes. The next generation of B factories, the so called Super B factory will search for departures from the Standard model. For this task, a 50 times larger data sample is needed, corresponding to an integrated luminosity of 50 ab{sup −1}. With such a large data sample there are many more topics to explore, including searches for new and exotic hadrons, and investigation of their properties.

  14. Chiari II malformation. Pt. 4

    Energy Technology Data Exchange (ETDEWEB)

    Naidich, T.P.; McLone, D.G.; Fulling, K.H.

    1983-08-01

    Computed tomography successfully delineates the multiple components of the Chiari II malformation at the craniocervical junction, the hindbrain, and the cervical spinal cord. These include wide foramen magnum and upper cervical spinal canal; incomplete fusions of the posterior arches of C1 and lower cervical vertebrae; cascading protrusions of vermis, fourth ventricle, medulla, and cervical cord into the spinal canal; cervicomedullary ''kinking''; anterior displacement and sequential sagittal compression of each protrusion by the protrusions posterior to it; compression of all protrusions by the posterior lip of foramen magnum and the posterior arch of C1; and associated cervical hydromyelia, cervical diastematomyelia, and cervical arachnoid cysts.

  15. Materiales II, 2010-11

    OpenAIRE

    2010-01-01

    I. Materiales de clase: 1.Hormigón; 2.Materiales metálicos: ( metales 1, metales 2); 3.Plásticos. II. Bibliografía * Generales * Conocer los materiales empleados en la construcción, sus variedades y las características físicas, mecánicas y químicas que los definen. * Plantear y resolver problemas relativos a las propiedades físicas, mecánicas y químicas de los materiales de construcción. * Conocer los procedimientos industriales de localización, extracción, obtención,...

  16. Tris(ethylenediaminezinc(II hexafluoridosilicate

    Directory of Open Access Journals (Sweden)

    Jinxiang Dong

    2009-12-01

    Full Text Available The title compound, [Zn(C2H8N23](SiF6, was synthesized ionothermally using choline chloride–imidazolidone as solvent and template provider. In the crystal structure, the anions and cations are located on special positions of site symmetry 3.2 and show a typical octahedral geometry. The ZnII ion is coordinated by six N atoms from three ethylenediamine molecules. The crystal structure displays weak hydrogen bonding between [SiF6]2− anions and the ethylenediamine NH hydrogen atoms.

  17. Belle II Technical Design Report

    CERN Document Server

    Abe, T; Adamczyk, K; Ahn, S; Aihara, H; Akai, K; Aloi, M; Andricek, L; Aoki, K; Arai, Y; Arefiev, A; Arinstein, K; Arita, Y; Asner, D M; Aulchenko, V; Aushev, T; Aziz, T; Bakich, A M; Balagura, V; Ban, Y; Barberio, E; Barvich, T; Belous, K; Bergauer, T; Bhardwaj, V; Bhuyan, B; Blyth, S; Bondar, A; Bonvicini, G; Bozek, A; Bracko, M; Brodzicka, J; Brovchenko, O; Browder, T E; Cao, G; Chang, M -C; Chang, P; Chao, Y; Chekelian, V; Chen, A; Chen, K -F; Chen, P; Cheon, B G; Chiang, C -C; Chistov, R; Cho, K; Choi, S -K; Chung, K; Comerma, A; Cooney, M; Cowley, D E; Critchlow, T; Dalseno, J; Danilov, M; Dieguez, A; Dierlamm, A; Dillon, M; Dingfelder, J; Dolenec, R; Dolezal, Z; Drasal, Z; Drutskoy, A; Dungel, W; Dutta, D; Eidelman, S; Enomoto, A; Epifanov, D; Esen, S; Fast, J E; Feindt, M; Garcia, M Fernandez; Fifield, T; Fischer, P; Flanagan, J; Fourletov, S; Fourletova, J; Freixas, L; Frey, A; Friedl, M; Fruehwirth, R; Fujii, H; Fujikawa, M; Fukuma, Y; Funakoshi, Y; Furukawa, K; Fuster, J; Gabyshev, N; Cueto, A Gaspar de Valenzuela; Garmash, A; Garrido, L; Geisler, Ch; Gfall, I; Goh, Y M; Golob, B; Gorton, I; Grzymkowski, R; Guo, H; Ha, H; Haba, J; Hara, K; Hara, T; Haruyama, T; Hayasaka, K; Hayashi, K; Hayashii, H; Heck, M; Heindl, S; Heller, C; Hemperek, T; Higuchi, T; Horii, Y; Hou, W -S; Hsiung, Y B; Huang, C -H; Hwang, S; Hyun, H J; Igarashi, Y; Iglesias, C; Iida, Y; Iijima, T; Imamura, M; Inami, K; Irmler, C; Ishizuka, M; Itagaki, K; Itoh, R; Iwabuchi, M; Iwai, G; Iwai, M; Iwasaki, M; Iwasaki, M; Iwasaki, Y; Iwashita, T; Iwata, S; Jang, H; Ji, X; Jinno, T; Jones, M; Julius, T; Kageyama, T; Kah, D H; Kakuno, H; Kamitani, T; Kanazawa, K; Kapusta, P; Kataoka, S U; Katayama, N; Kawai, M; Kawai, Y; Kawasaki, T; Kennedy, J; Kichimi, H; Kikuchi, M; Kiesling, C; Kim, B K; Kim, G N; Kim, H J; Kim, H O; Kim, J -B; Kim, J H; Kim, M J; Kim, S K; Kim, K T; Kim, T Y; Kinoshita, K; Kishi, K; Kisielewski, B; van Dam, K Kleese; Knopf, J; Ko, B R; Koch, M; Kodys, P; Koffmane, C; Koga, Y; Kohriki, T; Koike, S; Koiso, H; Kondo, Y; Korpar, S; Kouzes, R T; Kreidl, Ch; Kreps, M; Krizan, P; Krokovny, P; Krueger, H; Kruth, A; Kuhn, W; Kuhr, T; Kumar, R; Kumita, T; Kupper, S; Kuzmin, A; Kvasnicka, P; Kwon, Y -J; Lacasta, C; Lange, J S; Lee, I -S; Lee, M J; Lee, M W; Lee, S -H; Lemarenko, M; Li, J; Li, W D; Li, Y; Libby, J; Limosani, A; Liu, C; Liu, H; Liu, Y; Liu, Z; Liventsev, D; Virto, A Lopez; Makida, Y; Mao, Z P; Marinas, C; Masuzawa, M; Matvienko, D; Mitaroff, W; Miyabayashi, K; Miyata, H; Miyazaki, Y; Miyoshi, T; Mizuk, R; Mohanty, G B; Mohapatra, D; Moll, A; Mori, T; Morita, A; Morita, Y; Moser, H -G; Martin, D Moya; Mueller, T; Muenchow, D; Murakami, J; Myung, S S; Nagamine, T; Nakamura, I; Nakamura, T T; Nakano, E; Nakano, H; Nakao, M; Nakazawa, H; Nam, S -H; Natkaniec, Z; Nedelkovska, E; Negishi, K; Neubauer, S; Ng, C; Ninkovic, J; Nishida, S; Nishimura, K; Novikov, E; Nozaki, T; Ogawa, S; Ohmi, K; Ohnishi, Y; Ohshima, T; Ohuchi, N; Oide, K; Olsen, S L; Ono, M; Ono, Y; Onuki, Y; Ostrowicz, W; Ozaki, H; Pakhlov, P; Pakhlova, G; Palka, H; Park, H; Park, H K; Peak, L S; Peng, T; Peric, I; Pernicka, M; Pestotnik, R; Petric, M; Piilonen, L E; Poluektov, A; Prim, M; Prothmann, K; Regimbal, K; Reisert, B; Richter, R H; Riera-Babures, J; Ritter, A; Ritter, A; Ritter, M; Roehrken, M; Rorie, J; Rosen, M; Rozanska, M; Ruckman, L; Rummel, S; Rusinov, V; Russell, R M; Ryu, S; Sahoo, H; Sakai, K; Sakai, Y; Santelj, L; Sasaki, T; Sato, N; Sato, Y; Scheirich, J; Schieck, J; Schwanda, C; Schwartz, A J; Schwenker, B; Seljak, A; Senyo, K; Seon, O -S; Sevior, M E; Shapkin, M; Shebalin, V; Shen, C P; Shibuya, H; Shiizuka, S; Shiu, J -G; Shwartz, B; Simon, F; Simonis, H J; Singh, J B; Sinha, R; Sitarz, M; Smerkol, P; Sokolov, A; Solovieva, E; Stanic, S; Staric, M; Stypula, J; Suetsugu, Y; Sugihara, S; Sugimura, T; Sumisawa, K; Sumiyoshi, T; Suzuki, K; Suzuki, S Y; Takagaki, H; Takasaki, F; Takeichi, H; Takubo, Y; Tanaka, M; Tanaka, S; Taniguchi, N; Tarkovsky, E; Tatishvili, G; Tawada, M; Taylor, G N; Teramoto, Y; Tikhomirov, I; Trabelsi, K; Tsuboyama, T; Tsunada, K; Tu, Y -C; Uchida, T; Uehara, S; Ueno, K; Uglov, T; Unno, Y; Uno, S; Urquijo, P; Ushiroda, Y; Usov, Y; Vahsen, S; Valentan, M; Vanhoefer, P; Varner, G; Varvell, K E; Vazquez, P; Vila, I; Vilella, E; Vinokurova, A; Visniakov, J; Vos, M; Wang, C H; Wang, J; Wang, M -Z; Wang, P; Wassatch, A; Watanabe, M; Watase, Y; Weiler, T; Wermes, N; Wescott, R E; White, E; Wicht, J; Widhalm, L; Williams, K M; Won, E; Xu, H; Yabsley, B D; Yamamoto, H; Yamaoka, H; Yamaoka, Y; Yamauchi, M; Yin, Y; Yoon, H; Yu, J; Yuan, C Z; Yusa, Y; Zander, D; Zdybal, M; Zhang, Z P; Zhao, J; Zhao, L; Zhao, Z; Zhilich, V; Zhou, P; Zhulanov, V; Zivko, T; Zupanc, A; Zyukova, O

    2010-01-01

    The Belle detector at the KEKB electron-positron collider has collected almost 1 billion Y(4S) events in its decade of operation. Super-KEKB, an upgrade of KEKB is under construction, to increase the luminosity by two orders of magnitude during a three-year shutdown, with an ultimate goal of 8E35 /cm^2 /s luminosity. To exploit the increased luminosity, an upgrade of the Belle detector has been proposed. A new international collaboration Belle-II, is being formed. The Technical Design Report presents physics motivation, basic methods of the accelerator upgrade, as well as key improvements of the detector.

  18. Bis(hexamethylenetetraminebis(trichloroacetatocopper(II

    Directory of Open Access Journals (Sweden)

    Li-Min Li

    2009-11-01

    Full Text Available In the title compound, [Cu(C2Cl3O22(C6H12N42], the CuII ion (site symmetry 2 is coordinated by two trichloroacetate anions and two hexamethylenetetramine molecules, resulting in a distorted CuN2O2 geometry that is intermediate between tetrahedral and square planar. The Cl atoms are disordered over two sets of sites, with relative occupancies of 0.749 (7 and 0.251 (7. In the crystal, the packing is consolidated by intermolecular C—H...O interactions.

  19. Theory of function spaces II

    CERN Document Server

    Triebel, Hans

    1992-01-01

    Theory of Function Spaces II deals with the theory of function spaces of type Bspq and Fspq as it stands at the present. These two scales of spaces cover many well-known function spaces such as Hölder-Zygmund spaces, (fractional) Sobolev spaces, Besov spaces, inhomogeneous Hardy spaces, spaces of BMO-type and local approximation spaces which are closely connected with Morrey-Campanato spaces. Theory of Function Spaces II is self-contained, although it may be considered an update of the author’s earlier book of the same title. The book’s 7 chapters start with a historical survey of the subject, and then analyze the theory of function spaces in Rn and in domains, applications to (exotic) pseudo-differential operators, and function spaces on Riemannian manifolds. ------ Reviews The first chapter deserves special attention. This chapter is both an outstanding historical survey of function spaces treated in the book and a remarkable survey of rather different techniques developed in the last 50 years. It is s...

  20. BNL ATF II beamlines design

    Energy Technology Data Exchange (ETDEWEB)

    Fedurin, M. [Brookhaven National Lab. (BNL), Upton, NY (United States); Jing, Y. [Brookhaven National Lab. (BNL), Upton, NY (United States); Stratakis, D. [Brookhaven National Lab. (BNL), Upton, NY (United States); Swinson, C. [Brookhaven National Lab. (BNL), Upton, NY (United States)

    2015-05-03

    The Brookhaven National Laboratory. Accelerator Test Facility (BNL ATF) is currently undergoing a major upgrade (ATF-II). Together with a new location and much improved facilities, the ATF will see an upgrade in its major capabilities: electron beam energy and quality and CO2 laser power. The electron beam energy will be increased in stages, first to 100-150 MeV followed by a further increase to 500 MeV. Combined with the planned increase in CO2 laser power (from 1-100 TW), the ATF-II will be a powerful tool for Advanced Accelerator research. A high-brightness electron beam, produced by a photocathode gun, will be accelerated and optionally delivered to multiple beamlines. Besides the energy range (up to a possible 500 MeV in the final stage) the electron beam can be tailored to each experiment with options such as: small transverse beam size (<10 um), short bunch length (<100 fsec) and, combined short and small bunch options. This report gives a detailed overview of the ATFII capabilities and beamlines configuration.

  1. The spectrum of Fe II

    CERN Document Server

    Nave, Gillian

    2012-01-01

    The spectrum of singly-ionized iron (Fe II) has been recorded using high-resolution Fourier transform and grating spectroscopy over the wavelength range 900 {\\AA} to 5.5 {\\mu}m. The spectra were observed in high-current continuous and pulsed hollow cathode discharges using Fourier transform (FT) spectrometers at the Kitt Peak National Observatory, Tucson, AZ and Imperial College, London and with the 10.7 m Normal Incidence Spectrograph at the National Institute of Standards and Technology. Roughly 12 900 lines were classified using 1027 energy levels of Fe II that were optimized to measured wavenumbers. The wavenumber uncertainties of lines in the FT spectra range from 10-4 cm-1 for strong lines around 4 {\\mu}m to 0.05 cm-1 for weaker lines around 1500 {\\AA}. The wavelength uncertainty of lines in the grating spectra is 0.005 {\\AA}. The ionization energy of (130 655.4+-0.4) cm-1 was estimated from the 3d6(5D)5g and 3d6(5D)6h levels.

  2. The SRC-II process

    Science.gov (United States)

    Schmid, B. K.; Jackson, D. M.

    1981-03-01

    The Solvent Refined Coal (SRC-II) process which produces low-sulfur distillate fuel oil from coal is discussed. The process dissolves coal in a process-derived solvent at elevated temperature and pressure in the presence of hydrogen, separates the undissolved mineral residue, then recovers the original solvent by vacuum distillation. The distillate fuel oil produced is for use largely as a nonpolluting fuel for generating electrical power and steam and is expected to be competitive with petroleum fuels during the 1980s. During this period, the SRC-II fuel oil is expected to be attractive compared with combustion of coal with flue gas desulfurization in U.S. East Coast oil-burning power plants, as well as in small and medium-sized industrial boilers. The substantial quantities of methane, light hydrocarbons and naphtha produced by the process have value as feedstocks for preparation of pipeline gas, ethylene and high-octane unleaded gasoline, and can replace petroleum fractions in many applications. The liquid and gas products from a future large-scale plant, such as the 6000 t/day plant planned for Morgantown, West Virginia, are expected to have an overall selling price of $4.25 to $4.75/GJ.

  3. Mass spectrometry and potentiometry studies of Pb(II)-, Cd(II)- and Zn(II)-cystine complexes.

    Science.gov (United States)

    Furia, Emilia; Aiello, Donatella; Di Donna, Leonardo; Mazzotti, Fabio; Tagarelli, Antonio; Thangavel, Hariprasad; Napoli, Anna; Sindona, Giovanni

    2014-01-21

    Cd(II)-, Pb(II)- and Zn(II)-cystine complexes were investigated by potentiometric and different mass spectrometric (MS) methodologies. Laser desorption mass spectrometry has provided both the composition and structure of metal-cystine complexes according to the speciation models proposed on the basis of the potentiometric data. Detection of neutral complexes was achieved by protonation or electrochemical reduction during mass spectrometric experiments. The redox activity of metal-cystine complexes was confirmed by laser desorption and charge transfer matrix assisted laser assisted MS experiments, which allowed us to observe the formation of complexes with a reduction of cystine. The stoichiometry of Cd(II)-, Pb(II)- and Zn(II)-cystine complexes was defined by observing the isotopic pattern of the investigated compound. The results suggest that interaction occurs through the carboxylate group of the ligand.

  4. U ltracompact H II regions: new challenges

    Directory of Open Access Journals (Sweden)

    S. E. Kurtz

    2000-01-01

    Full Text Available El nombre de \\regi on H II ultracompacta" (UC H II apareci o por primera vez en la literatura hace mas de 30 a~nos. Desde entonces se han identi cado del orden de 103 regiones o candidatos a UC H II y se han propuesto al menos siete modelos para explicarlas. Las evidencias observacionales recientes indican que la clasi caci on usual de UC H II puede ser inadecuada para todas las nebulosas densas y peque~nas que rodean a las estrellas masivas j ovenes. En particular, algunas UC H II parecen ser las regiones densas de estructuras m as grandes a las que llamamos \\UC H II con emisi on extendida". Otras regiones H II parecen ser un orden de magnitud m as peque~nas y dos ordenes de magnitud m as densas que las UC H II tradicionales. Ellas merecen una nueva clasi caci on y las llamamos \\regiones H II super-ultracompactas". Damos un resumen hist orico y cient co de las UC H II, presentamos los nuevos datos observacionales que dan origen a las nuevas clasi caciones y discutimos brevemente las implicaciones para los modelos te oricos.

  5. Chelation of Cu(II, Zn(II, and Fe(II by Tannin Constituents of Selected Edible Nuts

    Directory of Open Access Journals (Sweden)

    Magdalena Karamać

    2009-12-01

    Full Text Available The tannin fractions isolated from hazelnuts, walnuts and almonds were characterised by colorimetric assays and by an SE-HPLC technique. The complexation of Cu(II and Zn(II was determined by the reaction with tetramethylmurexide, whereas for Fe(II, ferrozine was employed. The walnut tannins exhibited a significantly weaker reaction with the vanillin/HCl reagent than hazelnut and almond tannins, but the protein precipitation capacity of the walnut fraction was high. The SE-HPLC chromatogram of the tannin fraction from hazelnuts revealed the presence of oligomers with higher molecular weights compared to that of almonds. Copper ions were most effectively chelated by the constituents of the tannin fractions of hazelnuts, walnuts and almonds. At a 0.2 mg/assay addition level, the walnut tannins complexed almost 100% Cu(II. The Fe(II complexation capacities of the tannin fractions of walnuts and hazelnuts were weaker in comparison to that of the almond tannin fraction, which at a 2.5 mg/assay addition level, bound Fe(II by ~90%. The capacity to chelate Zn(II was quite varied for the different nut tannin fractions: almond tannins bound as much as 84% Zn(II, whereas the value for walnut tannins was only 8.7%; and for hazelnut tannins, no Zn(II chelation took place at the levels tested.

  6. Removal of Pb(II), Cd(II), Cu(II) and trichloroethylene from water by Nanofer ZVI.

    Science.gov (United States)

    Eglal, Mahmoud M; Ramamurthy, Amruthur S

    2015-01-01

    Zero-valent iron nanoparticle (Nanofer ZVI) is a new reagent due to its unique structure and properties. Images of scanning electron microscopy/electron dispersive spectroscopy (SEM/EDS), transmission electron microscopy and X-ray diffraction revealed that Nanofer ZVI is stable, reactive and has a unique structure. The particles exhibited a spherical shape, a chain-like structure with a particle size of 20 to 100 nm and a surface area between 25-30 m2g(-1). The time interval for particles to agglomerate and settle was between 4-6 h. SEM/EDS Images showed that particle size increased to 2 µm due to agglomeration. Investigation of adsorption and oxidation behavior of Nanofer ZVI used for the removal of Cu(II), Pb(II), Cd(II) ions and trichloroethylene (TCE) from aqueous solutions showed that the optimal pH for Pb(II), Cu(II), Cd(II) and TCE removal were 4.5 and 4.8, 5.0 and 6.5, respectively. Test data were used to form Langmuir and Freundlich isotherms. The maximum contaminant loading was estimated as 270, 170, 110, 130 mg per gram of Nanofer ZVI for Cu(II), Pb(II), Cd(II) and TCE respectively. Removal of metal ions is interpreted in terms of their hydrated ionic radii and their electronegativity. TCE oxidation followed the dechlorination pathway resulting in nonhazardous by-products.

  7. Preparation and thermal decomposition of copper(II, zinc(II and cadmium(II chelates with 8-hydroxyquinoline

    Directory of Open Access Journals (Sweden)

    Crespi Marisa S.

    1999-01-01

    Full Text Available When the compounds are heated in an inert atmosphere it can be verified the consecutive partial sublimation, fusion, partial volatilization and partial thermal decomposition of the anhydrous complexes. When in an oxidating atmosphere the above process is only verified to Cu(II chelates. Anhydrous copper(II complexes present a monoclinic structure in the b form and the volatilized compound in a a form. Zinc(II and cadmium(II hydrated complexes are isomorphous and they present different cell dimensions from those reported previously.

  8. Solid phase extraction of Cu(II), Ni(II), Pb(II), Cd(II) and Mn(II) ions with 1-(2-thiazolylazo)-2-naphthol loaded Amberlite XAD-1180.

    Science.gov (United States)

    Tokalioğlu, Serife; Yilmaz, Vedat; Kartal, Senol

    2009-05-01

    A new method for separation and preconcentration of trace amounts of Cu(II), Ni(II), Pb(II), Cd(II) and Mn(II) ions in various matrices was proposed. The method is based on the adsorption and chelation of the metal ions on a column containing Amberlite XAD-1180 resin impregnated with 1-(2-thiazolylazo)-2-naphthol (TAN) reagent prior to their determination by flame atomic absorption spectrometry (FAAS). The effect of pH, type, concentration and volume of eluent, sample volume, flow rates of sample and elution solutions, and interfering ions have been investigated. The optimum pH for simultaneous retention of all the metal ions was 9. Eluent for quantitative elution was 20 ml of 2 mol l(-1) HNO(3). The optimum sample and eluent flow rates were found as 4 ml min(-1), and also sample volume was 500 ml, except for Mn (87% recovery). The sorption capacity of the resin was found to be 0.77, 0.41, 0.57, and 0.30 mg g(-1) for Cu(II), Ni(II), Cd(II), and Mn(II), respectively. The preconcentration factor of the method was 200 for Cu(II), 150 for Pb(II), 100 for Cd(II) and Ni(II), and 50 for Mn(II). The recovery values for all of the metal ions were > or = 95% and relative standard deviations (RSDs) were < or = 5.1%. The detection limit values were in the range of 0.03 and 1.19 microg l(-1). The accuracy of the method was confirmed by analysing the certified reference materials (TMDA 54.4 fortified lake water and GBW 07605 tea samples) and the recovery studies. This procedure was applied to the determination of Cu(II), Ni(II), Pb(II), Cd(II) and Mn(II) in waste water and lake water samples.

  9. [Biosorption of Cd(II), Cu(II), Pb(II) and Zn(II) in aqueous solutions by fruiting bodies of macrofungi (Auricularia polytricha and Tremella fuciformis)].

    Science.gov (United States)

    Mo, Yu; Pan, Rong; Huang, Hai-wei; Cao, Li-xiang; Zhang, Ren-duo

    2010-07-01

    Batch experiments were conducted to study the ability of fruiting bodies of Auricularia polytricha and Tremella fuciformis to adsorb Cd(II), Cu(II), Pb(II) and Zn(II) from aqueous solutions, including biosorption ability of the biomass to remove heavy metals from solutions with different concentrations, kinetics of adsorption, influence of co-cations, and biosorption affinity in multi-metalsystem. Results showed that in the solutions with individual metal, the maximum biosorption amounts of Cd(II), Cu(II), Pb(II), Zn(II) by A. polytricha were 18.91, 18.69, 20.33, 12.42 mg x g(-1), respectively, and the highest removal rates for all cases were more than 85%. The maximum biosorption amounts of Cd(II), Cu(II), Pb(II), Zn(II) by T. fuciformis were 19.98, 20.15, 19.16, 16.41 mg x g(-1), respectively, and highest removal rates for all cases were more than 75%. In the solutions with initial concentrations of 10, 50 and 100 mg x L(-1), the biosorption amounts increased but the removal rates decreased as the initial concentrations increasing. The pseudo-second-order reaction model described adsorption kinetics of heavy metal ions by fruiting bodies of A. polytricha and T. fuciformis better than the pseudo-first-order reaction model. In the solutions with multi metals, the biosorption amounts of heavy metals by two biosorbent were in the order of Ph(II) > Cd(II) > Cu(II) > Zn(II). The ions with more negative charges were preferential to be sorbed. The biosorption ability of A. polytricha was inhibited in multi-metal solutions. In multi-metal solutions, T. fuciformis sorbed a higher amount of Pb(II) but lower amounts of other three ions than that in the individual metal solutions. The results indicated that both fruiting bodies of A. polytricha and T. fuciformis were potential biosorbents.

  10. Dimethylammonium tetraaqua(hydrogensulfatosulfatocuprate(II

    Directory of Open Access Journals (Sweden)

    Peter Held

    2014-04-01

    Full Text Available In the title salt, [(CH32NH2][Cu(HSO4(SO4(H2O4], one type of cation and anion is present in the asymmetric unit. The CuII atom in the complex anion, [Cu(HSO4(SO4(H2O4]−, has a tetragonal bipyramidal [4 + 2] coordination caused by a Jahn–Teller distortion, with the aqua ligands in equatorial and two O atoms of tetrahedral HSO4 and SO4 units in apical positions. Both types of ions form sheets parallel to (010. The interconnection within and between the sheets is reinforced by O—H...O and N—H...O hydrogen bonds, respectively, involving the water molecules, the two types of sulfate anions and the ammonium groups.

  11. Quantum mechanics II advanced topics

    CERN Document Server

    Rajasekar, S

    2015-01-01

    Quantum Mechanics II: Advanced Topics uses more than a decade of research and the authors’ own teaching experience to expound on some of the more advanced topics and current research in quantum mechanics. A follow-up to the authors introductory book Quantum Mechanics I: The Fundamentals, this book begins with a chapter on quantum field theory, and goes on to present basic principles, key features, and applications. It outlines recent quantum technologies and phenomena, and introduces growing topics of interest in quantum mechanics. The authors describe promising applications that include ghost imaging, detection of weak amplitude objects, entangled two-photon microscopy, detection of small displacements, lithography, metrology, and teleportation of optical images. They also present worked-out examples and provide numerous problems at the end of each chapter.

  12. Tris(ethylenediaminecobalt(II sulfate

    Directory of Open Access Journals (Sweden)

    Bunlawee Yotnoi

    2010-06-01

    Full Text Available The structure of the title compound, [CoII(C2H8N23]SO4, the cobalt example of [M(C2H8N23]SO4, is reported. The Co and S atoms are located at the 2d and 2c Wyckoff sites (point symmetry 32, respectively. The Co atom is coordinated by six N atoms of three chelating ethylenediamine molecules generated from half of the ethylenediamine molecule in the asymmetric unit. The O atoms of the sulfate anion are disordered mostly over two crystallographic sites. The third disorder site of O (site symmetry 3 has a site occupancy approaching zero. The H atoms of the ethylenediamine molecules interact with the sulfate anions via intermolecular N—H...O hydrogen-bonding interactions.

  13. CONGENITAL SENSORY NEUROPATHY (HSAN II

    Directory of Open Access Journals (Sweden)

    Venkata Chalam

    2015-08-01

    Full Text Available A 5 year old girl having hereditary sensory neuropathy, type II manifesting as congenital absence of pain sensation and trophic changes in the skin is reported. This child presented with presented with multiple ulcers over hands and feet since 2 years of age. The ulcers were non - healing type with serosanguineous discharge. There is abnormal gait and weakness in upper and lower limbs. On examination there are deep ulcers measuring 5x7x2cms over left feet. Fingers of both hands and feet were mutilated with loss of phalanges, sensations to fine touch, pain and temperature are decreased bilaterally below the mid arm and feet, vibration sensations were normal, proprioception could not be tested due to deformities. Sensory and motor nerve conduction studies showed evidence of sensorimotor axonal neuropathy.

  14. Neurosurgical notes: World War II.

    Science.gov (United States)

    Pool, J L

    2000-03-01

    This concerns my activities as a neurosurgeon in the European Theater of Operations and the North African, Tunisian campaign, during World War II. Action during the Battle of the Bulge came later. Our mobile tent hospital, the 9th Evacuation Hospital, was similar to that depicted in the television show M*A*S*H. To lend flavor to these comments, I have referred to medical and surgical matters in other units as well as our own, mentioned global aspects of the war, and included vignettes of life off-duty. The story begins after induction into the Army Medical Corps as a volunteer in July 1942 and ends with honorable discharge in April 1946.

  15. Optimization of simultaneous electrochemical determination of Cd(II), Pb(II), Cu(II) and Hg(II) at carbon nanotube-modified graphite electrodes.

    Science.gov (United States)

    Pikna, L'ubomír; Heželová, Mária; Kováčová, Zuzana

    2015-01-01

    The health of the environment is worsening every day. Monitoring of potentially toxic elements and remediation of environmental pollution are necessary. Therefore, the research and development of simple, inexpensive, portable and effective sensors is important. Electrochemistry is a useful component of the field of environment monitoring. The present study focuses on evaluating and comparing three types of electrodes (PIGE, PIGE/MWCNT/HNO3 and PIGE/MWCNT/EDTA/HNO3) employed for the simultaneous electrochemical determination of four potentially toxic elements: Cd(II), Pb(II), Cu(II) and Hg(II). Cyclic voltammograms were measured in an acetate buffer. The LOD, LOQ, the standard and relative precisions of the method and a prediction intervals were calculated (according to the technical procedure DIN 32 645) for the three electrodes and for each measured element. The LOD for PIGE/CNT/HNO3 (the electrode with narrowest calculated prediction intervals) was 2.98 × 10(-7) mol L(-1) for Cd(II), 4.83 × 10(-7) mol L(-1) for Pb(II), 3.81 × 10(-7) mol L(-1) for Cu(II), 6.79 × 10(-7) mol L(-1) for Hg(II). One of the benefits of this study was the determination of the amount of Hg(II) in the mixture of other elements.

  16. Cu(II) and Zn(II) ions alter the dynamics and distribution of Mn(II) in cultured chick glial cells

    Energy Technology Data Exchange (ETDEWEB)

    Wedler, F.C.; Ley, B.W. (Dept. of Molecular Cell Biology, Pennsylvania State University, University Park (USA))

    1990-12-01

    Previous studies revealed that Mn(II) is accumulated in cultured glial cells to concentrations far above those present in whole brain or in culture medium. The data indicated that Mn(II) moves across the plasma membrane into the cytoplasm by facilitated diffusion or counter-ion transport with Ca(II), then into mitochondria by active transport. The fact that 1-10 microM Mn(II) ions activate brain glutamine synthetase makes important the regulation of Mn(II) transport in the CNS. Since Cu(II) and Zn(II) caused significant changes in the accumulation of Mn(II) by glia, the mechanisms by which these ions alter the uptake and efflux of Mn(II) ions has been investigated systematically under chemically defined conditions. The kinetics of (54MN)-Mn(II) uptake and efflux were determined and compared under four different sets of conditions: no adducts, Cu(II) or Zn(II) added externally, and with cells preloaded with Cu(II) or Zn(II) in the presence and absence of external added metal ions. Zn(II) ions inhibit the initial velocity of Mn(II) uptake, increase total Mn(II) accumulated, but do not alter the rate or extent Mn(II) efflux. Cu(II) ions increase both the initial velocity and the net Mn(II) accumulated by glia, with little effect on rate or extent of Mn(II) efflux. These results predict that increases in Cu(II) or Zn(II) levels may also increase the steady-state levels of Mn(II) in the cytoplasmic fraction of glial cells, which may in turn alter the activity of Mn(II)-sensitive enzymes in this cell compartment.

  17. Kinetics of Formation of Cobalt(II)- and Nickel(II) Carbonic Anhydrase.

    Science.gov (United States)

    McQuate, Robert S.; Reardon, John E.

    1978-01-01

    Discusses the kinetic behavior associated with the interaction of metal ions with apocarbonic anhydrase, focusing on the formation of two metallocarbonic anhydrase--the biochemically active Co(II) and the inactive Ni(II)derivatives. (GA)

  18. Molecular cloning, sequencing, and expression analysis of cDNA encoding metalloprotein II (MP II) induced by single and combined metals (Cu(II), Cd(II)) in polychaeta Perinereis aibuhitensis.

    Science.gov (United States)

    Yang, Dazuo; Zhou, Yibing; Zhao, Huan; Zhou, Xiaoxiao; Sun, Na; Wang, Bin; Yuan, Xiutang

    2012-11-01

    We amplified and analyzed the complete cDNA of metalloprotein II (MP II) from the somatic muscle of the polychaete Perinereis aibuhitensis, the full length cDNA is 904 bp encoding 119 amino acids. The MP II cDNA sequence was subjected to BLAST searching in NCBI and was found to share high homology with hemerythrin of other worms. MP II expression of P. aibuhitensis exposed to single and combined metals (Cu(II), Cd(II)) was analyzed using real time-PCR. MP II mRNA expression increased at the start of Cu(II) exposure, then decreased and finally return to the normal level. Expression pattern of MP II under Cd(II) exposure was time- and dose-dependent. MP II expression induced by a combination of Cd(II) and Cu(II) was similar to that induced by Cd(II) alone.

  19. Co(II), Ni(II), Cu(II) and Zn(II) complexes of a bipyridine bis-phenol conjugate: generation and properties of coordinated radical species.

    Science.gov (United States)

    Arora, Himanshu; Philouze, Christian; Jarjayes, Olivier; Thomas, Fabrice

    2010-11-14

    Four bis-phenolate complexes [Zn(II)L], [Ni(II)L], [Cu(II)L] and [Co(II)L] (where [H(2)L = 2,2'-[2,2']bipyridinyl-6-yl-bis-4,6-di-tert-butylphenol] have been synthesized. The copper(II) and nickel(II) complexes have been characterized by X-ray diffraction, showing a metal ion within a square planar geometry, slightly distorted towards tetrahedral. The cyclic voltametry (CV) curve of [Zn(II)L] consists of a single bi-electronic reversible wave at 0.06 V vs. Fc/Fc(+). The electrochemically generated dication is a diradical species [Zn(II)L˙˙](2+) that exhibits the typical phenoxyl π-π* band at 395 nm. It is EPR-silent due to magnetic interactions between the phenoxyl moieties. The CV curves of [Ni(II)L] and [Cu(II)L] exhibit two distinct ligand-centred one-electron oxidation waves. The first one is observed at E(1/2)(1) = 0.38 and 0.40 V for the nickel and copper complex, respectively, and corresponds to the formation of M(II)-coordinated phenoxyl radicals. Accordingly, [Ni(II)L˙](+) exhibits a strong absorption band at 960 nm and an (S = ½) EPR signal centred at g(iso) = 2.02. [Cu(II)L˙](+) is EPR-silent, in agreement with a magnetic coupling between the metal and the radical spin. In contrast with the other complexes, [Co(II)L] was found to react with dioxygen (mostly in the presence of pyridine), giving rise to a stable (S = ½) superoxo radical complex [Co(III)L(Py)(O(2)˙)]. One-electron oxidation of [Co(II)L] at -0.01 V affords a diamagnetic cobalt(III) complex [Co(III)L](+) that is inert towards O(2) binding, whereas two-electron oxidation leads to the paramagnetic phenoxyl radical species [Co(III)L˙](+) whose EPR spectrum features an (S = ½) signal at g(iso) = 2.00.

  20. Adsorption of Cd(II) and Pb(II) from aqueous solutions on activated alumina.

    Science.gov (United States)

    Naiya, Tarun Kumar; Bhattacharya, Ashim Kumar; Das, Sudip Kumar

    2009-05-01

    The ability of activated alumina as synthetic adsorbent was investigated for adsorptive removal of Cd(II) and Pb(II) ions from aqueous solutions. Various physico-chemical parameters such as pH, initial metal ion concentration, and adsorbent dosage level and equilibrium contact time were studied. The optimum solution pH for adsorption of Cd(II) and Pb(II) from aqueous solutions was found to be 5. Kinetics data were best described by pseudo-second order model. The effective particle diffusion coefficient of Cd(II) and Pb(II) are of the order of 10(-10) m(2)/s. Values of mass transfer coefficient were estimated as 4.868x10(-6) cm/s and 6.85x10(-6) cm/s for Cd(II) and Pb(II) adsorption respectively. The equilibrium adsorption data for Cd(II) and Pb(II) were better fitted to Langmuir adsorption isotherm model. The thermodynamic studies indicated that the adsorption was spontaneous and exothermic for Cd(II) adsorption and endothermic for Pb(II). The sorption energy calculated from Dubinin-Radushkevich isotherm were 11.85 kJ/mol and 11.8 kJ/mol for the adsorption of Cd(II) and Pb(II) respectively which indicated that both the adsorption processes were chemical in nature. Desorption studies were carried out using dilute mineral acids. Application studies carried out using industrial waste water samples containing Cd(II) and Pb(II) showed the suitability of activated alumina in waste water treatment plant operation.

  1. Biosorption of Cd(II) and Zn(II) by nostoc commune: isotherm and kinetics studies

    Energy Technology Data Exchange (ETDEWEB)

    Morsy, Fatthy M. [Faculty of Science, Botany Department, Assiut University, Assiut (Egypt); Hassan, Sedky H.A. [Department of Biological Environment, Kangwon National University, Kangwon-do (Korea, Republic of); Koutb, Mostafa [Faculty of Science, Botany Department, Assiut University, Assiut (Egypt); Umm Al-Qura University, Faculty of Applied Science, Biology Department, Mecca (Saudi Arabia)

    2011-07-15

    In this study, Nostoc commune (cyanobacterium) was used as an inexpensive and efficient biosorbent for Cd(II) and Zn(II) removal from aqueous solutions. The effect of various physicochemical factors on Cd(II) and Zn(II) biosorption such as pH 2.0-7.0, initial metal concentration 0.0-300 mg/L and contact time 0-120 min were studied. Optimum pH for removal of Cd(II) and Zn(II) was 6.0, while the contact time was 30 min at room temperature. The nature of biosorbent and metal ion interaction was evaluated by infrared (IR) technique. IR analysis of bacterial biomass revealed the presence of amino, carboxyl, hydroxyl, and carbonyl groups, which are responsible for biosorption of Cd(II) and Zn (II). The maximum biosorption capacities for Cd(II) and Zn(II) biosorption by N. commune calculated from Langmuir biosorption isotherm were 126.32 and 115.41 mg/g, respectively. The biosorption isotherm for two biosorbents fitted well with Freundlich isotherm than Langmuir model with correlation coefficient (r{sup 2} < 0.99). The biosorption kinetic data were fitted well with the pseudo-second-order kinetic model. Thus, this study indicated that the N. commune is an efficient biosorbent for the removal of Cd(II) and Zn(II) from aqueous solutions. (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  2. Diet History Questionnaire II & Canadian Diet History Questionnaire II: Web-based DHQ

    Science.gov (United States)

    The Web-based versions of DHQ II and C-DHQ II are identical in content to the paper forms. By automating the DHQ II and providing versions on the Web for public use, researchers have another tool to collect and analyze food frequency questionnaire data.

  3. Spectral and thermodynamic properties of Ag(I), Au(III), Cd(II), Co(II), Fe(III), Hg(II), Mn(II), Ni(II), Pb(II), U(IV), and Zn(II) binding by methanobactin from Methylosinus trichosporium OB3b.

    Science.gov (United States)

    Choi, Dong W; Do, Young S; Zea, Corbin J; McEllistrem, Marcus T; Lee, Sung-W; Semrau, Jeremy D; Pohl, Nicola L; Kisting, Clint J; Scardino, Lori L; Hartsel, Scott C; Boyd, Eric S; Geesey, Gill G; Riedel, Theran P; Shafe, Peter H; Kranski, Kim A; Tritsch, John R; Antholine, William E; DiSpirito, Alan A

    2006-12-01

    Methanobactin (mb) is a novel chromopeptide that appears to function as the extracellular component of a copper acquisition system in methanotrophic bacteria. To examine this potential physiological role, and to distinguish it from iron binding siderophores, the spectral (UV-visible absorption, circular dichroism, fluorescence, and X-ray photoelectron) and thermodynamic properties of metal binding by mb were examined. In the absence of Cu(II) or Cu(I), mb will bind Ag(I), Au(III), Co(II), Cd(II), Fe(III), Hg(II), Mn(II), Ni(II), Pb(II), U(VI), or Zn(II), but not Ba(II), Ca(II), La(II), Mg(II), and Sr(II). The results suggest metals such as Ag(I), Au(III), Hg(II), Pb(II) and possibly U(VI) are bound by a mechanism similar to Cu, whereas the coordination of Co(II), Cd(II), Fe(III), Mn(II), Ni(II) and Zn(II) by mb differs from Cu(II). Consistent with its role as a copper-binding compound or chalkophore, the binding constants of all the metals examined were less than those observed with Cu(II) and copper displaced other metals except Ag(I) and Au(III) bound to mb. However, the binding of different metals by mb suggests that methanotrophic activity also may play a role in either the solubilization or immobilization of many metals in situ.

  4. FOREWORD: HELAS II International Conference

    Science.gov (United States)

    Gizon, Laurent; Roth, Markus

    2008-07-01

    Volume 118 (2008) of Journal of Physics: Conference Series provides a written record of the talks and posters presented at the HELAS II International Conference `Helioseismology, Asteroseismology and MHD Connections'. The conference was held during the week 20-24 August 2007 in Göttingen, Germany, jointly hosted by the Max Planck Institute for Solar System Research and the Faculty of Physics of the University of Göttingen. A total of 140 scientists from all over the world attended. The Scientific Organizing Committee consisted of Conny Aerts, Annie Baglin, Jørgen Christensen-Dalsgaard, Thierry Corbard, Jadwiga Daszyńska-Daszkiewicz, Stefan Dreizler, Yvonne Elsworth, Laurent Gizon (Chairman), Wolfgang Glatzel, Frank Hill, Donald Kurtz, Oskar von der Lühe, Maria Pia Di Mauro, Mário Monteiro, Pere Pallé, Markus Roth, Philip Scherrer, Manfred Schüssler, and Michael Thompson. HELAS stands for the European Helio- and Asteroseismology Network, a Coordination Action supported by the sixth Framework Programme of the European Union. It aims to bring together researchers in the fields of solar and stellar oscillations. This volume consists of 91 articles organized into sections that reflect the scientific programme of the conference: 012001-07 Wave diagnostics in physics, geophysics and astrophysics 012008-09 Perspectives on helio- and asteroseismology 012010-17 Asteroseismology: Observations 012018-25 Asteroseismology: Theory 012026-32 Global helioseismology and solar models 012033-38 Local helioseismology and magnetic activity 012039-44 Future observational projects in helio- and asteroseismology 012045-91 Poster papers. The overwhelming majority of papers discuss the seismology of the Sun and stars. Papers in the first section provide a broader perspective on wave phenomena and techniques for probing other physical systems, from living beings to the universe as a whole. We were extremely fortunate to have particularly distinguished experts to cover these topics

  5. Adsorption of Cd(II), Cu(II) and Ni(II) ions by cross-linking chitosan/rectorite nano-hybrid composite microspheres.

    Science.gov (United States)

    Zeng, Lixuan; Chen, Yufei; Zhang, Qiuyun; Guo, Xingmei; Peng, Yanni; Xiao, Huijuan; Chen, Xiaocheng; Luo, Jiwen

    2015-10-05

    Chitosan/rectorie (CTS/REC) nano-hybrid composite microsphere was prepared by changing the proportion of CTS/REC with 2:1, 3:1 and 4:1. Compared with the pure cross-linking chitosan microsphere, the nano-hybrid composite microsphere was proved to have better sorption capacity of Cd(II), Cu(II) and Ni(II), especially 2:1(CTS/REC-1). The adsorption behavior of the microsphere of Cd(II), Cu(II) and Ni(II) was investigated in single and binary metal systems. In single system, the equilibrium studies showed that the adsorption of Cd(II), Cu(II) and Ni(II) followed the Langmuir model and the pseudo-second-order kinetic model. The negative values of (ΔG) suggested that the adsorption process was spontaneous. In binary system, the combined action of the metals was found to be antagonistic and the metal sorption followed the order of Cu(II)>Cd(II)>Ni(II). The regeneration studies indicated that EDTA desorbed Cd(II), Cu(II) and Ni(II) from cross-linking microspheres better than HCl. The FT-IR and XPS spectra showed that coordination bonds were formed between Cd(II), Cu(II) and Ni(II) and the nitrogen atoms of cross-linking CTS/REC nano-hybrid composite microspheres.

  6. Aleksius II tuleb homme Eestisse / Krista Taim

    Index Scriptorium Estoniae

    Taim, Krista

    2003-01-01

    Moskva ja kogu Venemaa õigeusu kiriku patriarh Aleksius II tuleb Eestisse visiidile, mille käigus kohtub president Arnold Rüütliga, siinsete õigeusu kogudustega, peab kolm jumalateenistust Aleksander Nevski katedraalis ning käib Kuremäe kloostris. Samas: Vene õigeusu kiriku patriarh Aleksius II

  7. World War II Memorial Learning Activities.

    Science.gov (United States)

    Tennessee State Dept. of Education, Nashville.

    These learning activities can help students get the most out of a visit to the Tennessee World War II Memorial, a group of ten pylons located in Nashville (Tennessee). Each pylon contains informational text about the events of World War II. The ten pylons are listed as: (1) "Pylon E-1--Terror: America Enters the War against Fascism, June…

  8. Metallothionein-I+II in neuroprotection

    DEFF Research Database (Denmark)

    Pedersen, Mie Ø; Jensen, Rikke; Pedersen, Dan S

    2009-01-01

    -I+II decrease inflammation and secondary tissue damage (oxidative stress, neurodegeneration, and apoptosis) and promote post-injury repair and regeneration (angiogenesis, neurogenesis, neuronal sprouting and tissue remodelling). Intracellularly the molecular MT-I+II actions involve metal ion control...

  9. Photoionization models for giant h ii regions

    Directory of Open Access Journals (Sweden)

    Gra´zyna Stasi´nska

    2000-01-01

    Full Text Available Revisamos las fuentes de incertidumbre en los modelos de fotoionizaci on de regiones H II gigantes. Tambi en discutimos el problema de la temperatura electr onica a la luz de los ajustes de modelos en tres regiones H II gigantes.

  10. TRUPACT-II procedures and maintenance instructions

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1994-01-14

    The purpose of this document is to provide the technical requirements for operation, inspection and maintenance of a TRUPACT-II Shipping Package and directly related components. This document shall supply the minimum requirements as specified in the TRUPACT-II Safety Analysis Report for Packaging (SARP) and Certificate of Compliance (C of C) 9218. In the event there is a conflict between this document and the TRUPACT-II SARP (NRC Certificate of Compliance No. 9218), the TRUPACT-II SARP shall govern. This document details the operations, maintenance, repair, replacement of components, as well as the documentation required and the procedures to be followed to maintain the integrity of the TRUPACT-II container. These procedures may be modified for site use, but as a minimum all parameters and format listed herein must be included in any site modified version. For convenience and where applicable steps may be performed out of sequence. Packaging and payload handling equipment and transport trailers have been specifically designed for use with the TRUPACT-II Packaging. This document discusses the minimum required procedures for use of the adjustable center of gravity lift fixture and the TRUPACT-II transport trailer in conjunction with the TRUPACT-II Packaging.

  11. ATLAS Phase-II trigger upgrade

    CERN Document Server

    Sankey, Dave; The ATLAS collaboration

    2016-01-01

    This talk for ACES summarises the current status of the ATLAS Phase-II trigger upgrade, describing and comparing the two architectures under consideration, namely the two hardware level system described in the Phase-II Upgrade Scoping Document and the more recent single hardware level system.

  12. DART II documentation. Volume III. Appendices

    Energy Technology Data Exchange (ETDEWEB)

    1979-10-01

    The DART II is a remote, interactive, microprocessor-based data acquistion system suitable for use with air monitors. This volume of DART II documentation contains the following appendixes: adjustment and calibration procedures; mother board signature list; schematic diagrams; device specification sheets; ROM program listing; 6800 microprocessor instruction list, octal listing; and cable lists. (RWR)

  13. Aldosterone response to angiotensin II during hypoxemia

    Energy Technology Data Exchange (ETDEWEB)

    Colice, G.L.; Ramirez, G.

    1986-07-01

    Exercise stimulates the renin-angiotensin-aldosterone system (RAAS). However, increases in plasma aldosterone concentrations (PAC) are suppressed when exercise is performed at high altitude or under hypoxemic conditions. As the angiotensin-II response to high-altitude exercise is normal, it is speculated that an inhibitor, discharged during hypoxemia, acted to suppress angiotensin-II-mediated aldosterone release. A study was conducted to test this hypothesis, taking into account the measurement of the aldosterone response to exogenous angiotensin II during normoxemia and hypoxemia. It was found that the dose-response curve of PAC to angiotensin II was not significantly inhibited by the considered model of hypoxemia. The hypoxemia-mediated release of an angiotensin II inhibitor does, therefore, not explain the previous observations of PAC suppression during hypoxemic exercise. 28 references.

  14. Radiosurgery for type II neurofibromatosis.

    Science.gov (United States)

    Rowe, Jeremy; Radatz, Matthias; Kemeny, Andras

    2008-01-01

    A summary of our radiosurgical experience treating type II neurofibromatosis (NF2) vestibular schwannomas (VSs), based on a retrospective consecutive series of 122 tumours in 92 patients, with an extended series of a further 22 patients (906 patient-years of follow-up) to investigate the risk of malignancy after radiosurgery. With current techniques, we estimate that 8 years after radiosurgery for NF2 VS, 20% of patients will have required further treatment, 50% will be well controlled, and in 30% there will have been some concern about control, but they will have been managed conservatively. Three years after treatment, approximately 40% retain their functional hearing, 40% have some deterioration, 20% becoming deaf in that ear. The risk of facial palsy was 5%. Two malignancies were recorded after radiosurgery, in one the malignant behaviour preceded treatment. This is less than the previously reported rate of spontaneously developing malignant gliomas in NF2. Whilst the clinical results are far worse than those achieved treating sporadic tumours, this applies equally to the results of surgery or observation when treating NF2 tumours. It is important therefore that these patients are given advice specific for NF2. Considering this, we believe that radiosurgery remains a valuable minimally invasive treatment option for selected NF2 patients.

  15. Tris(ethylenediaminecobalt(II dichloride

    Directory of Open Access Journals (Sweden)

    Kristin Cooke

    2013-06-01

    Full Text Available The title compound, [CoII(C2H8N23]Cl2, was obtained unexpectedly as the product of an attempted solvothermal synthesis of cobalt selenide from the elements in the presence of NH4Cl in ethylenediamine solvent. The three chelate rings of the distorted octahedral [Co(C2H8N23]2+ complex cation adopt twisted conformations about their C—C bonds. The spread of cis-N—Co—N bond angles [80.17 (6–98.10 (6°] in the title compound is considerably greater than the equivalent data for [CoIII(C2H8N23]Cl3 [Takamizawa et al. (2008. Angew. Chem. Int. Ed. 47, 1689–1692]. In the crystal, the components are linked by numerous N—H...Cl hydrogen bonds, generating a three-dimensional network in which the cationic complexes are stacked in columns along [010] and separated by columns of chloride anions.

  16. Type II-P Supernovae as Standard Candles: The SDSS-II Sample Revisited

    OpenAIRE

    Poznanski, Dovi; Nugent, Peter E.; Filippenko, Alexei V.

    2010-01-01

    We revisit the observed correlation between Hbeta and FeII velocities for Type II-P supernovae (SNe~II-P) using 28 optical spectra of 13 SNe II-P and demonstrate that it is well modeled by a linear relation with a dispersion of about 300 km/s. Using this correlation, we reanalyze the publicly available sample of SNe II-P compiled by D'Andrea et al. and find a Hubble diagram with an intrinsic scatter of 11% in distance, which is nearly as tight as that measured before their sample is added to ...

  17. Early failure of Class II resin composite versus Class II amalgam restorations placed by dental students.

    Science.gov (United States)

    Overton, J D; Sullivan, Diane J

    2012-03-01

    Using the information from remake request slips in a dental school's predoctoral clinic, we examined the short-term survival of Class II resin composite restorations versus Class II dental amalgam restorations. In the student clinic, resin composite is used in approximately 58 percent of Class II restorations placed, and dental amalgam is used in the remaining 42 percent. In the period examined, Class II resin composite restorations were ten times more likely to be replaced at no cost to the patient than Class II dental amalgam restorations. A total of eighty-four resin composite restorations and six amalgam restorations were replaced due to an identified failure.

  18. Poly[tetra­aqua-di-μ4-malonato-barium(II)cadmium(II)

    OpenAIRE

    2010-01-01

    In the title complex, [BaCd(C3H2O4)2(H2O)4]n, the BaII atoms, located on crystallographic twofold axes, adopt slightly distorted square-antiprismatic coordination geometries, while the CdII atoms, which lie on crystallographic centres of symmetry, have a distorted octahedral coordination. Each malonate dianion binds two different CdII atoms and two different BaII atoms. This connectivity generates alternating layers along [100] in the structure, with one type containing CdII cations and malon...

  19. Equilibrium and kinetic studies of Pb(II, Cd(II and Zn(II sorption by Lagenaria vulgaris shell

    Directory of Open Access Journals (Sweden)

    Mitić-Stojanović Dragana-Linda

    2012-01-01

    Full Text Available The sorption of lead, cadmium and zinc ions from aqueous solution by Lagenaria vulgaris shell biosorbent (LVB in batch system was investigated. The effect of relevant parameters such as contact time, biosorbent dosage and initial metal ions concentration was evaluated. The Pb(II, Cd(II and Zn(II sorption equilibrium (when 98% of initial metal ions were sorbed was attained within 15, 20 and 25 min, respectively. The pseudo first, pseudo-second order, Chrastil’s and intra-particle diffusion models were used to describe the kinetic data. The experimental data fitted the pseudo-second order kinetic model and intra-particle diffusion model. Removal efficiency of lead(II, cadmium(II and zinc(II ions rapidly increased with increasing biosorbent dose from 0.5 to 8.0 g dm-3. Optimal biosorbent dose was set to 4.0 g dm-3. An increase in the initial metal concentration increases the sorption capacity. The sorption data of investigated metal ions are fitted to Langmuir, Freundlich and Temkin isotherm models. Langmuir model best fitted the equilibrium data (r2 > 0.99. Maximal sorption capacities of LVB for Pb(II, Cd(II and Zn(II at 25.0±0.5°C were 0.130, 0.103 and 0.098 mM g-1, respectively. The desorption experiments showed that the LVB could be reused for six cycles with a minimum loss of the initial sorption capacity.

  20. Revisited abundance diagnostics in quasars: Fe II/Mg II ratios

    CERN Document Server

    Verner, E M; Verner, D A; Johansson, S; Gull, T R

    2003-01-01

    Both the Fe II UV emission in the 2000- 3000 A region [Fe II (UV)] and resonance emission line complex of Mg II at 2800 A are prominent features in quasar spectra. The observed Fe II UV/ Mg II emission ratios have been proposed as means to measure the buildup of the Fe abundance relative to that of the alpha-elements C, N, O, Ne and Mg as a function of redshift. The current observed ratios show large scatter and no obvious dependence on redshift. Thus, it remains unresolved whether a dependence on redshift exists and whether the observed Fe II UV/ Mg II ratios represent a real nucleosynthesis diagnostic. We have used our new 830-level model atom for Fe+ in photoionization calculations, reproducing the physical conditions in the broad line regions of quasars. This modeling reveals that interpretations of high values of Fe II UV/ Mg II are sensitive not only to Fe and Mg abundance, but also to other factors such as microturbulence, density, and properties of the radiation field. We find that the Fe II UV/ Mg II...

  1. Adsorption of Cu(II), Hg(II), and Ni(II) ions by modified natural wool chelating fibers

    Energy Technology Data Exchange (ETDEWEB)

    Monier, M., E-mail: monierchem@yahoo.com [Chemistry Department, Drexel University, Philadelphia, PA (United States); Chemistry Department, Faculty of Science, Mansoura University, Mansoura (Egypt); Ayad, D.M.; Sarhan, A.A. [Chemistry Department, Faculty of Science, Mansoura University, Mansoura (Egypt)

    2010-04-15

    The graft copolymerization of ethyl acrylate (EA) onto natural wool fibers initiated by potassium persulphate and Mohr's salt redox initiator system in limited aqueous medium was carried out in heterogeneous media. Ester groups of the grafted copolymers were partially converted into hydrazide function groups followed by hydrazone formation through reaction with isatin. Also the application of the modified fibers for metal ion uptake was studied using Cu(II), Hg(II) and Ni(II). The modified chelating fibers were characterized using FTIR spectroscopy, SEM and X-ray diffraction.

  2. Structural and Spectroscopic Aspects of Schiff Base Metal Complexes of Cobalt(II, Nickel(II and Copper(II

    Directory of Open Access Journals (Sweden)

    B.K. Rai

    2014-09-01

    Full Text Available The complexes of Co(II, Ni(II and Cu(II with Schiff base 2-butyl thioquinazoline 4(3H thiosemicarbazone were synthesized. The general formulae of the complexes are of the type {M(L2X2], L=2 – butyl thioquinazoline 4(3H thiosemicarbazone; x = Cl-, Br-, I- and NO3-. Elemental analyses and spectral (IR, electronic studies of the synthesized complexes suggest the presence of octahedral, environment around the central metal ion. These complexes were also subjected to study their antimicrobial screening against, Gram positive bacteria Candida albicans and gram negative bacteria Escherichia coli by disc diffusion technique.

  3. Adsorption of Cu(II), Hg(II), and Ni(II) ions by modified natural wool chelating fibers.

    Science.gov (United States)

    Monier, M; Ayad, D M; Sarhan, A A

    2010-04-15

    The graft copolymerization of ethyl acrylate (EA) onto natural wool fibers initiated by potassium persulphate and Mohr's salt redox initiator system in limited aqueous medium was carried out in heterogeneous media. Ester groups of the grafted copolymers were partially converted into hydrazide function groups followed by hydrazone formation through reaction with isatin. Also the application of the modified fibers for metal ion uptake was studied using Cu(II), Hg(II) and Ni(II). The modified chelating fibers were characterized using FTIR spectroscopy, SEM and X-ray diffraction.

  4. Unsaturated b-ketoesters and their Ni(II, Cu(II and Zn(II complexes

    Directory of Open Access Journals (Sweden)

    MUHAMMED BASHEER UMMATHUR

    2009-03-01

    Full Text Available A new series of b-ketoesters in which the keto group is attached to the olefinic linkage were synthesized by the reaction of methyl acetoacetate and aromatic aldehydes under specified conditions. The existence of these compounds predominantly in the intramolecularly hydrogen bonded enol form was well demonstrated from their IR, 1H-NMR and mass spectral data. Details on the formation of their [ML2] complexes with Ni(II, Cu(II and Zn(II and the nature of the bonding are discussed on the basis of analytical and spectral data.

  5. Structural Properties of MHC Class II Ligands, Implications for the Prediction of MHC Class II Epitopes

    DEFF Research Database (Denmark)

    Jørgensen, Kasper Winther; Buus, Søren; Nielsen, Morten

    2010-01-01

    properties of MHC class II ligands. Here, we perform one such large-scale analysis. A large set of SYFPEITHI MHC class II ligands covering more than 20 different HLA-DR molecules was analyzed in terms of their secondary structure and surface exposure characteristics in the context of the native structure......Major Histocompatibility class II (MHC-II) molecules sample peptides from the extracellular space allowing the immune system to detect the presence of foreign microbes from this compartment. Prediction of MHC class II ligands is complicated by the open binding cleft of the MHC class II molecule...... of the corresponding source protein. We demonstrated that MHC class II ligands are significantly more exposed and have significantly more coil content than other peptides in the same protein with similar predicted binding affinity. We next exploited this observation to derive an improved prediction method for MHC...

  6. Use of APACHE II and SAPS II to predict mortality for hemorrhagic and ischemic stroke patients.

    Science.gov (United States)

    Moon, Byeong Hoo; Park, Sang Kyu; Jang, Dong Kyu; Jang, Kyoung Sool; Kim, Jong Tae; Han, Yong Min

    2015-01-01

    We studied the applicability of the Acute Physiology and Chronic Health Evaluation II (APACHE II) and Simplified Acute Physiology Score II (SAPS II) in patients admitted to the intensive care unit (ICU) with acute stroke and compared the results with the Glasgow Coma Scale (GCS) and National Institutes of Health Stroke Scale (NIHSS). We also conducted a comparative study of accuracy for predicting hemorrhagic and ischemic stroke mortality. Between January 2011 and December 2012, ischemic or hemorrhagic stroke patients admitted to the ICU were included in the study. APACHE II and SAPS II-predicted mortalities were compared using a calibration curve, the Hosmer-Lemeshow goodness-of-fit test, and the receiver operating characteristic (ROC) curve, and the results were compared with the GCS and NIHSS. Overall 498 patients were included in this study. The observed mortality was 26.3%, whereas APACHE II and SAPS II-predicted mortalities were 35.12% and 35.34%, respectively. The mean GCS and NIHSS scores were 9.43 and 21.63, respectively. The calibration curve was close to the line of perfect prediction. The ROC curve showed a slightly better prediction of mortality for APACHE II in hemorrhagic stroke patients and SAPS II in ischemic stroke patients. The GCS and NIHSS were inferior in predicting mortality in both patient groups. Although both the APACHE II and SAPS II systems can be used to measure performance in the neurosurgical ICU setting, the accuracy of APACHE II in hemorrhagic stroke patients and SAPS II in ischemic stroke patients was superior.

  7. Synthesis, Spectral Characterization, Molecular Modeling, and Antimicrobial Studies of Cu(II, Ni(II, Co(II, Mn(II, and Zn(II Complexes of ONO Schiff Base

    Directory of Open Access Journals (Sweden)

    Padmaja Mendu

    2012-01-01

    Full Text Available A series of Cu(II, Ni(II, Co(II, Mn(II, and Zn(II complexes have been synthesized from the schiff base ligand L. The schiff base ligand [(4-oxo-4H-chromen-3-yl methylene] benzohydrazide (L has been synthesized by the reaction between chromone-3-carbaldehyde and benzoyl hydrazine. The nature of bonding and geometry of the transition metal complexes as well as schiff base ligand L have been deduced from elemental analysis, FT-IR, UV-Vis, 1HNMR, ESR spectral studies, mass, thermal (TGA and DTA analysis, magnetic susceptibility, and molar conductance measurements. Cu(II, Ni(II, Co(II, and Mn(II metal ions are forming 1:2 (M:L complexes, Zn(II is forming 1:1 (M:L complex. Based on elemental, conductance and spectral studies, six-coordinated geometry was assigned for Cu(II, Ni(II, Co(II, Mn(II, and Zn(II complexes. The complexes are 1:2 electrolytes in DMSO except zinc complex, which is neutral in DMSO. The ligand L acts as tridentate and coordinates through nitrogen atom of azomethine group, oxygen atom of keto group of γ-pyrone ring and oxygen atom of hydrazoic group of benzoyl hydrazine. The 3D molecular modeling and energies of all the compounds are furnished. The biological activity of the ligand and its complexes have been studied on the four bacteria E. coli, Edwardella, Pseudomonas, and B. subtilis and two fungi pencillium and tricoderma by well disc and fusion method and found that the metal chelates are more active than the free schiff base ligand.

  8. Solid-phase extraction of Mn(II), Co(II), Ni(II), Cu(II), Cd(II) and Pb(II) ions from environmental samples by flame atomic absorption spectrometry (FAAS)

    Energy Technology Data Exchange (ETDEWEB)

    Duran, Celal [Department of Chemistry, Faculty of Art and Science, Karadeniz Technical University, 61080 Trabzon (Turkey); Gundogdu, Ali [Department of Chemistry, Faculty of Art and Science, Karadeniz Technical University, 61080 Trabzon (Turkey); Bulut, Volkan Numan [Department of Chemistry, Giresun Faculty of Art and Science, Karadeniz Technical University, 28049 Giresun (Turkey); Soylak, Mustafa [Department of Chemistry, Faculty of Art and Science, Erciyes University, 38039 Kayseri (Turkey)]. E-mail: soylak@erciyes.edu.tr; Elci, Latif [Department of Chemistry, Faculty of Art and Science, Pamukkale University, 20020 Denizli (Turkey); Sentuerk, Hasan Basri [Department of Chemistry, Faculty of Art and Science, Karadeniz Technical University, 61080 Trabzon (Turkey); Tuefekci, Mehmet [Department of Chemistry, Faculty of Art and Science, Karadeniz Technical University, 61080 Trabzon (Turkey)

    2007-07-19

    A new method using a column packed with Amberlite XAD-2010 resin as a solid-phase extractant has been developed for the multi-element preconcentration of Mn(II), Co(II), Ni(II), Cu(II), Cd(II), and Pb(II) ions based on their complex formation with the sodium diethyldithiocarbamate (Na-DDTC) prior to flame atomic absorption spectrometric (FAAS) determinations. Metal complexes sorbed on the resin were eluted by 1 mol L{sup -1} HNO{sub 3} in acetone. Effects of the analytical conditions over the preconcentration yields of the metal ions, such as pH, quantity of Na-DDTC, eluent type, sample volume and flow rate, foreign ions etc. have been investigated. The limits of detection (LOD) of the analytes were found in the range 0.08-0.26 {mu}g L{sup -1}. The method was validated by analyzing three certified reference materials. The method has been applied for the determination of trace elements in some environmental samples.

  9. Chitosan film loaded with silver nanoparticles-sorbent for solid phase extraction of Al(III), Cd(II), Cu(II), Co(II), Fe(III), Ni(II), Pb(II) and Zn(II).

    Science.gov (United States)

    Djerahov, Lubomir; Vasileva, Penka; Karadjova, Irina; Kurakalva, Rama Mohan; Aradhi, Keshav Krishna

    2016-08-20

    The present study describes the ecofriendly method for the preparation of chitosan film loaded with silver nanoparticles (CS-AgNPs) and application of this film as efficient sorbent for separation and enrichment of Al(III), Cd(II), Cu(II), Co(II), Fe(III), Ni(II), Pb(II) and Zn(II). The stable CS-AgNPs colloid was prepared by dispersing the AgNPs sol in chitosan solution at appropriate ratio and further used to obtain a cast film with very good stability under storage and good mechanical strength for easy handling in aqueous medium. The incorporation of AgNPs in the structure of CS film and interaction between the polymer matrix and nanoparticles were confirmed by UV-vis and FTIR spectroscopy. The homogeneously embedded AgNPs (average diameter 29nm, TEM analysis) were clearly observed throughout the film by SEM. The CS-AgNPs nanocomposite film shows high sorption activity toward trace metals under optimized chemical conditions. The results suggest that the CS-AgNPs nanocomposite film can be feasibly used as a novel sorbent material for solid-phase extraction of metal pollutants from surface waters.

  10. Dinuclear Metallacycles with Single M-X-M Bridges (X = Cl(-), Br(-); M = Fe(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II)): Strong Antiferromagnetic Superexchange Interactions.

    Science.gov (United States)

    Reger, Daniel L; Pascui, Andrea E; Foley, Elizabeth A; Smith, Mark D; Jezierska, Julia; Wojciechowska, Agnieszka; Stoian, Sebastian A; Ozarowski, Andrew

    2017-03-06

    A series of monochloride-bridged, dinuclear metallacycles of the general formula [M2(μ-Cl)(μ-L)2](ClO4)3 have been prepared using the third-generation, ditopic bis(pyrazolyl)methane ligands L = m-bis[bis(1-pyrazolyl)methyl]benzene (Lm), M = Cu(II), Zn(II), and L = m-bis[bis(3,5-dimethyl-1-pyrazolyl)methyl]benzene (Lm*), M = Fe(II), Co(II), Ni(II), Cu(II), Zn(II), Cd(II). These complexes were synthesized from the direct reactions of M(ClO4)2·6H2O, MCl2, and the ligand, Lm or Lm*, in the appropriate stoichiometric amounts. Three analogous complexes of the formula [M2(μ-Cl)(μ-L)2](BF4)3, L = Lm, M = Cu(II), and L = Lm*, M = Co(II), Cu(II), were prepared from the reaction of [M2(μ-F)(μ-L)2](BF4)3 and (CH3)3SiCl. The bromide-bridged complex [Cu2(μ-Br)(μ-Lm*)2](ClO4)3 was prepared by the first method. Three acyclic complexes, [Co2(μ-Lm)μ-Cl4], [Co2(μ-Lm*)Cl4], and [Co2(μ-Lm*)Br4], were also prepared. The structures of all [M2(μ-X)(μ-L)2](3+) (X = Cl(-), Br(-)) complexes have two ditopic bis(pyrazolyl)methane ligands bridging two metals in a metallacyclic arrangement. The fifth coordination site of the distorted trigonal bipyramidal metal centers is filled by a bridging halide ligand that has an unusual linear or nearly linear M-X-M angle. The NMR spectra of [Zn2(μ-Cl)(μ-Lm*)2](ClO4)3 and especially [Cd2(μ-Cl)(μ-Lm*)2](ClO4)3 demonstrate that the metallacycle structure is maintained in solution. Solid state magnetic susceptibility data for the copper(II) compounds show very strong antiferromagnetic exchange interactions, with -J values of 536 cm(-1) for [Cu2(μ-Cl)(μ-Lm)2](ClO4)3·xCH3CN, 720 cm(-1) for [Cu2(μ-Cl)(μ-Lm*)2](ClO4)3, and 945 cm(-1) for [Cu2(μ-Br)(μ-Lm*)2](ClO4)3·2CH3CN. Smaller but still substantial antiferromagnetic interactions are observed with other first row transition metals, with -J values of 98 cm(-1) for [Ni2(μ-Cl)(μ-Lm*)2](ClO4)3, 55 cm(-1) for [Co2(μ-Cl)(μ-Lm*)2](ClO4)3, and 34 cm(-1) for [Fe2(μ-Cl)(μ-Lm*)2](ClO4

  11. Angiotensin II receptors in testes

    Energy Technology Data Exchange (ETDEWEB)

    Millan, M.A.; Aguilera, G.

    1988-05-01

    Receptors for angiotensin II (AII) were identified and characterized in testes of rats and several primate species. Autoradiographic analysis of the binding of 125I-labeled (Sar1,Ile8)AII to rat, rhesus monkey, cebus monkey, and human testicular slide-mounted frozen sections indicated specific binding to Leydig cells in the interstitium. In rat collagenase-dispersed interstitial cells fractionated by Percoll gradient, AII receptor content was parallel to that of hCG receptors, confirming that the AII receptors are in the Leydig cells. In rat dispersed Leydig cells, binding was specific for AII and its analogs and of high affinity (Kd, 4.8 nM), with a receptor concentration of 15 fmol/10(6) cells. Studies of AII receptors in rat testes during development reveals the presence of high receptor density in newborn rats which decreases toward the adult age (4934 +/- 309, 1460 +/- 228, 772 +/- 169, and 82 +/- 12 fmol/mg protein at 5, 15, 20, and 30 days of age, respectively) with no change in affinity. At all ages receptors were located in the interstitium, and the decrease in binding was parallel to the decrease in the interstitial to tubular ratio observed with age. AII receptor properties in membrane-rich fractions from prepuberal testes were similar in the rat and rhesus monkey. Binding was time and temperature dependent, reaching a plateau at 60 min at 37 C, and was increased by divalent cations, EGTA, and dithiothreitol up to 0.5 mM. In membranes from prepuberal monkey testes, AII receptors were specific for AII analogs and of high affinity (Kd, 4.2 nM) with a receptor concentration of 7599 +/- 1342 fmol/mg protein. The presence of AII receptors in Leydig cells in rat and primate testes in conjunction with reports of the presence of other components of the renin-angiotensin system in the testes suggests that the peptide has a physiological role in testicular function.

  12. Carlos II: el centenario olvidado

    Directory of Open Access Journals (Sweden)

    Luis Antonio RIBOT GARCÍA

    2009-12-01

    Full Text Available RESUMEN: A partir de una reflexión inicial sobre el fenómeno de las conmemoraciones, el autor se plantea las causas por las que el tercer centenario de la muerte de Carlos II no dará lugar a ninguna conmemoración. Con independencia de las valoraciones de todo tipo que puedan hacerse de dichas celebraciones, lo cierto es que, en este caso, tal vez hubieran permitido acercar al gran público a uno de los monarcas peor conocidos y menos valorados de la historia de España. Lo más grave, sin embargo, es que la sombra del desconocimiento y el juicio peyorativo se extienden también sobre todo su reinado. Las investigaciones sobre aquel periodo, sin embargo, a pesar de que no abundan, muestran una realidad bastante distinta, en la que la decadencia y la pérdida de la hegemonía internacional convivieron con importantes iniciativas y realizaciones políticas, tanto en el ámbito interno de la Monarquía, como en las relaciones internacionales.ABSTRACT: Parting from an initial reflection about the phenomenon of commemorations, the author ponders the causes for which the third centenary of Charles IFs death will not be the subjet of any celebrations. Besides any evaluations which might be made of these events, the truth is that, perhaps, in this case, a commemoration would have brought the general public closer to one of the least known and worst valued monarchs in the history of Spain. What is more serious, however, is the fact that the shadow of ignorance and pejorative judgement extend also over the entirety of his reign. Though scarce, research about this period shows a very different reality, in wich decadence and the loss of international hegemony cohabitated with important political initiatives and achievements, both in the monarchy's internal domain and in the international arena.

  13. Investigation of Spray-Applied Polyurethane Foam Roofing Systems-II

    Science.gov (United States)

    1990-09-01

    CA MARCOR BASE / PWO, Camp Pendleton, CA ELASTPORT INTI., INC / Jil Osborn, Mgr, Ventura , CA MARCORBASE / PWO, Camp Lejeune, NC ED)WARD) K NODA...Code 1121 (EA Silva ), Arlington, VA SAN DIEGO STATE UNIV /CE Dept (Noorany), San Diego, CA OCNR / Code 1234, Arlington, VA SCIENCE APPS INTL CORP...VAN ALLEN, B / Kingston, NY VENTURA COUNTY / Deputy PW Dir, Ventura , CA VENTURA COUNTY I PWA (Brownie), Ventura , CA VERNON KUEHN / Lakewood, CO VULCAN

  14. LHC II system sensitivity to magnetic fluids

    CERN Document Server

    Cotae, Vlad

    2005-01-01

    Experiments have been designed to reveal the influences of ferrofluid treatment and static magnetic field exposure on the photosynthetic system II, where the light harvesting complex (LHC II) controls the ratio chlorophyll a/ chlorophyll b (revealing, indirectly, the photosynthesis rate). Spectrophotometric measurement of chlorophyll content revealed different influences for relatively low ferrofluid concentrations (10-30 mul/l) in comparison to higher concentrations (70-100 mul/l). The overlapped effect of the static magnetic field shaped better the stimulatory ferrofluid action on LHC II system in young poppy plantlets.

  15. Level II Ergonomic Analyses, Dover AFB, DE

    Science.gov (United States)

    1999-02-01

    IERA-RS-BR-TR-1999-0002 UNITED STATES AIR FORCE IERA Level II Ergonomie Analyses, Dover AFB, DE Andrew Marcotte Marilyn Joyce The Joyce...Project (070401881, Washington, DC 20503. 1. AGENCY USE ONLY (Leave blank) 2. REPORT DATE 4. TITLE AND SUBTITLE Level II Ergonomie Analyses, Dover...1.0 INTRODUCTION 1-1 1.1 Purpose Of The Level II Ergonomie Analyses : 1-1 1.2 Approach 1-1 1.2.1 Initial Shop Selection and Administration of the

  16. Belle II Physics Prospects, Status and Schedule

    Science.gov (United States)

    Bennett, J.

    2016-11-01

    The second generation B-factory at the SuperKEKB facility in Tsukuba, Japan is beginning to take shape. The highly anticipated Belle II experiment will have a rich physics program at the intensity frontier, in complement to existing experiments in the energy frontier. Accelerator commissioning has been making good progress, as has the construction and installation of the Belle II detector. An overview of the physics prospects at Belle II, as well as the status and schedule of the experiment, is presented.

  17. Angiotensin II and Renal Tubular Ion Transport

    Directory of Open Access Journals (Sweden)

    Patricia Valles

    2005-01-01

    Evidence for the regulation of H+-ATPase activity in vivo and in vitro by trafficking/exocytosis has been provided. An additional level of H+-ATPase regulation via protein synthesis may be important as well. Recently, we have shown that both aldosterone and angiotensin II provide such a mechanism of regulation in vivo at the level of the medullary collecting tubule. Interestingly, in this part of the nephron, the effects of aldosterone and angiotensin II are not sodium dependent, whereas in the cortical collecting duct, both aldosterone and angiotensin II, by contrast, affect H+ secretion by sodium-dependent mechanisms.

  18. A note on Type II covolutional codes

    OpenAIRE

    Johannesson, Rolf; Ståhl, Per; Wittenmark, Emma

    2000-01-01

    The result of a search for the world's second type II (doubly-even and self-dual) convolutional code is reported. A rate R=4/8, 16-state, time-invariant, convolutional code with free distance dfree=8 was found to be type II. The initial part of its weight spectrum is better than that of the Golay convolutional code (GCC). Generator matrices and path weight enumerators for some other type II convolutional codes are given. By the “wrap-around” technique tail-biting versions of (32, 18, 8) T...

  19. ALPS II technical overview and status report

    CERN Document Server

    Spector, Aaron

    2016-01-01

    The Any Light Particle Search II (ALPS II) is an experiment that utilizes the concept of resonant enhancement to improve on the sensitivity of traditional light shining through a wall style experiments. These experiments attempt to detect photons passing through an opaque wall by converting to relativistic weakly interacting sub-eV particles and then reconverting back to photons. ALPS II at DESY in Hamburg, Germany will use dually resonant optical cavities before and after the wall to increase the probability of this interaction occurring. This paper gives a technical overview and status report of the experiment.

  20. Synthesis, spectral characterization thermal stability, antimicrobial studies and biodegradation of starch–thiourea based biodegradable polymeric ligand and its coordination complexes with [Mn(II, Co(II, Ni(II, Cu(II, and Zn(II] metals

    Directory of Open Access Journals (Sweden)

    Nahid Nishat

    2016-09-01

    Full Text Available A biodegradable polymer was synthesized by the modification reaction of polymeric starch with thiourea which is further modified by transition metals, Mn(II, Co(II, Ni(II, Cu(II and Zn(II. All the polymeric compounds were characterized by (FT-IR spectroscopy, 1H NMR spectroscopy, 13C NMR spectroscopy, UV–visible spectra, magnetic moment measurements, thermogravimetric analysis (TGA and antibacterial activities. Polymer complexes of Mn(II, Co(II and Ni(II show octahedral geometry, while polymer complexes of Cu(II and Zn(II show square planar and tetrahedral geometry, respectively. The TGA revealed that all the polymer metal complexes are more thermally stable than their parental ligand. In addition, biodegradable studies of all the polymeric compounds were also carried out through ASTM-D-5338-93 standards of biodegradable polymers by CO2 evolution method which says that coordination decreases biodegradability. The antibacterial activity was screened with the agar well diffusion method against some selected microorganisms. Among all the complexes, the antibacterial activity of the Cu(II polymer–metal complex showed the highest zone of inhibition because of its higher stability constant.

  1. Template Synthesis, Characterization and Biological Activity of Cu(II, Ni(II, Co(II, Zn(IIComplexes with Isonicotinoylhydrazone--2-aldehydefluorene Ligand

    Directory of Open Access Journals (Sweden)

    2010-01-01

    Full Text Available This is about synthesizing new complex combinations of Cu(II, Ni(II,Co(II, Zn(II with aroylhydrazone ligand isonicotinoylhydrazone-2-aldehydefluorene (INHAF made by condensation of isonicotinoylhydrazine with 2-aldehydefluorene. The complexes have been characterized by analytical data, IR, UV-Vis, NMR spectra, magnetic susceptibility values, thermal analysis and for the Cu(II complex the ESR spectrum has been registered. For all complexes the biological activity against the Staphylo-coccus aureus, Escherichia coli, Klebssiella pneumoniae bacteria has been investigated. The experimental data sustain stoichiometry of 1:2 (metal/ligand for the Cu(II, Ni(II, Zn(II complexes and of 1:1 for the complex with Co(II. The electronic spectra and the magnetic moments suggest octahedral stereochemistry at the complexes with Cu(II, Ni(II and the tetrahedral geometry for the Co(II complex. The INHAF ligand is coordinated bidentate by the O=C amide oxygen and the azomethine nitrogen in the complexes of Cu(II, Ni(II, Co(II and monodentate by the azomethine nitrogen in the complex of Zn(II.

  2. The type II collagen fragments Helix-II and CTX-II reveal different enzymatic pathways of human cartilage collagen degradation

    DEFF Research Database (Denmark)

    Charni-Ben Tabassi, N; Desmarais, S; Jensen, Anne-Christine Bay

    2008-01-01

    sections were then incubated for up to 84h in the presence or absence of E-64 and GM6001, inhibitors of cysteine proteases and MMPs, respectively. RESULTS: In vitro, Cats K, L and S generated large amount of Helix-II, but not CTX-II. Cat B generated CTX-II fragment, but destroyed Helix-II immunoreactivity...

  3. Synthesis and characterisation of Cu(II), Ni(II), Mn(II), Zn(II) and VO(II) Schiff base complexes derived from o-phenylenediamine and acetoacetanilide

    Indian Academy of Sciences (India)

    N Raman; Y Pitchaikani Raja; A Kulandaisamy

    2001-06-01

    Neutral tetradentate N2O2 type complexes of Cu(II), Ni(II), Mn(II), Zn(II) and VO(II) have been synthesised using a Schiff base formed by the condensation of -phenylenediamine with acetoacetanilide in alcohol medium. All the complexes were characterised on the basis of their microanalytical data, molar conductance, magnetic susceptibility, IR, UV-Vis 1H NMR and ESR spectra. IR and UV-Vis spectral data suggest that all the complexes are square-planar except the Mn(II) and VO(II) chelates, which are of octahedral and square pyramidal geometry respectively. The monomeric and neutral nature of the complexes was confirmed by their magnetic susceptibility data and low conductance values. The ESR spectra of copper and vanadyl complexes in DMSO solution at 300 K and 77 K were recorded and their salient features are reported.

  4. Selected methods for dissolved iron (II, III) and dissolved sulfide (-II) determinations in geothermal waters

    Science.gov (United States)

    Vivit, D.V.; Jenne, E.A.

    1985-01-01

    Dissolved sulfide (-II) and dissolved iron (II, III) were determined in geothermal well water samples collected at Cerro Prieto, Mexico. Most samples consisted of liquid and gas (two phases) at the instant of collection; and a subset of samples, referred to as ' flashed ' samples, consisted of pressurized steam samples which were allowed to condense. Sulfide was determined by sulfide specific ion electrode; Fe(II) and Fe(III) plus Fe(II) were determined spectrophotometrically. The precision and accuracy of the methods were evaluated for these high-silica waters with replicate analyses, spike recoveries, and an alternate method. Direct current (d.c.) argon plasma emission spectrometry was the alternate method used for Fe(III)-plus-Fe(II) analyses. Mean dissolved iron concentrations ranged from 20.2 to 834 micrograms/L (ug/L) as Fe(II) and 26.8 to 904 ug/L as Fe(III) plus Fe(II). Mean sulfide concentrations ranged from about 0.01 to 5.3 mg/L (S-II) Generally, higher S(-II) values and larger Fe(II)/Fe(III) ratios were found in the two-phase samples. These findings suggest that the ' flashed ' samples are at a less reduced state than the two-phase samples. (Author 's abstract)

  5. T lymphocytes and dendritic cells are activated by the deletion of peroxiredoxin II (Prx II) gene.

    Science.gov (United States)

    Moon, Eun-Yi; Noh, Young-Wook; Han, Ying-Hao; Kim, Sun-Uk; Kim, Jin-Man; Yu, Dae-Yeul; Lim, Jong-Seok

    2006-02-15

    Peroxiredoxin II (Prx II) is a member of antioxidant enzyme family and it plays a protective role against oxidative damage. Constitutive production of endogenous reactive oxygen species was detected in spleen and bone marrow cells lacking Prx II. Here, we investigated the role of Prx II in immune responses. The total number of splenocytes (especially, the population of S-phase cells and CD3(+) T cells) was significantly higher in Prx II(-/-) mice than in wild type. Number of peripheral blood mononuclear cells (PBMCs) in Prx II(-/-) mice was also higher than wild type. Differentiation of Prx II(-/-) mouse bone marrow cells into CD11c-positive dendritic cells was greater than that of wild type. Transplantation of Prx II(-/-) bone marrow cells into wild type mice increased PBMCs in blood and bone marrow-derived dendritic cells. Prx II deletion enhances concanavalin A (ConA)-induced splenocyte proliferation and mixed lymphocyte reaction (MLR) activity of bone marrow-derived CD11c-positive dendritic cells to stimulate recipient splenocytes. Collectively, these data suggest that Prx II inhibits the immune cell responsiveness, which may be regulated by scavenging the low amount of reactive oxygen species (ROS).

  6. Synthesis and studies on Cu(II), Co(II), Ni(II) complexes of Knoevenagel β-diketone ligands

    Science.gov (United States)

    Sumathi, S.; Tharmaraj, P.; Sheela, C. D.; Anitha, C.

    2012-11-01

    Transition metal complexes of various acetylacetone based ligands of the type ML [where M = Cu(II), Ni(II), Co(II); L = 3-(aryl)-pentane-2,4-dione] have been synthesized. The structural features have been derived from their elemental analysis, magnetic susceptibility, molar conductance, IR, UV-Vis, 1H NMR, Mass and ESR spectral studies. Conductivity measurements reveal that all the complexes are non-electrolytic in nature. Spectroscopic and other analytical data of the complexes suggest octahedral geometry for other metal(II) complexes. The redox behavior of the copper(II) complexes have been studied by cyclic voltammetry. The free ligands and their metal complexes have been screened for their in vitro biological activities against the bacteria Pseudomonas aeruginosa, Escherichia coli and Staphylococcus aureus as well as the fungus Candida albicans by well diffusion method. The zone of inhibition value indicates that the most of the metal(II) complexes are found to possess increased activities compared to those of the free ligands. All synthesized compounds may serve as potential photoactive materials as indicated from their characteristic fluorescence properties. The second harmonic generation (SHG) efficiency of the ligands (L1-L3) was found to be considerable effect than that of urea and KDP (potassium dihydrogen phosphate).

  7. Adsorption of copper (II), chromium (III), nickel (II) and lead (II) ions from aqueous solutions by meranti sawdust.

    Science.gov (United States)

    Rafatullah, M; Sulaiman, O; Hashim, R; Ahmad, A

    2009-10-30

    The present study proposed the use of meranti sawdust in the removal of Cu(II), Cr(III), Ni(II) and Pb(II) ions from synthetic aqueous solutions. Batch adsorption studies showed that meranti sawdust was able to adsorb Cu(II), Cr(III), Ni(II) and Pb(II) ions from aqueous solutions in the concentration range 1-200mg/L. The adsorption was favoured with maximum adsorption at pH 6, whereas the adsorption starts at pH 1 for all metal ions. The effects of contact time, initial concentration of metal ions, adsorbent dosage and temperature have been reported. The applicability of Langmuir, Freundlich, and Dubinin-Radushkevich (D-R) isotherm was tried for the system to completely understand the adsorption isotherm processes. The adsorption kinetics tested with pseudo-first-order and pseudo-second-order models yielded high R(2) values from 0.850 to 0.932 and from 0.991 to 0.999, respectively. The meranti sawdust was found to be cost effective and has good efficiency to remove these toxic metal ions from aqueous solution.

  8. Antiviral Activity of Substituted Chalcones and their Respective Cu(ii, Ni(ii and Zn(ii Complexes

    Directory of Open Access Journals (Sweden)

    K. G. Mallikarjun

    2005-01-01

    Full Text Available Complexes of Cu(II, Ni(II and Zn(II with of 3-(phenyl-1-(2’-hydroxynaphthyl – 2 – propen – 1 – one (PHPO , 3 - (4-chlorophenyl - 1- (2’-hydroxynaphthyl–2–propen – 1 – one (CPHPO, 3 - (4 -methoxyphenyl -1-(2’-hydroxynapthyl-2-propen-1-one(MPHPO,3 - (3,4-dimethoxyphenyl –1-(2’-hydroxynaphthyl – 2 - propen– 1 – one (DMPHPO have been prepared and the purity of the samples were checked by elemental analysis. The ligands and their Cu(II, Ni(II and Zn(II complexes were tested on the infectivity of tobacco ring spot virus(TRSV using cowpea (Vigna Sinensis as a local lesions assay host. All the compounds were tested at different concentrations (250 ppm to 1500 ppmon the infectivity of the virus by applying them either with virus inoculum or 24 h before of after virus inoculation to the test plants. The compounds were found to have varied effects on virus infectivity depending on compounds concentration and method of application. The statistical significance of the data was determined by using analysis of variance.

  9. Sorption recovery of platinum (II, IV in presence of copper (II and zinc (II from chloride solutions

    Directory of Open Access Journals (Sweden)

    Kononova Olga N.

    2015-01-01

    Full Text Available The sorption preconcentration of platinum (II, IV ions was investigated in presence of accompanying copper (II and zinc (II ions from chloride solutions on the new ion exchangers CYBBER (Russia, previously unexplored. The initial concentrations of platinum and accompanying ions were 0.25 mmol L-1 and 2.0 mmol L-1, respectively, and the acidity of medium was 0.001 - 4.0 mol L-1. It was shown that the resins investigated - strong and weak basic anion exchangers as well as chelate ion exchangers - possess good sorption and kinetic properties. The simultaneous sorption of investigated ions results in the complete recovery of platinum, while the non-ferrous metal ions are sorbed at less than 20%. Followed by the selective elution of platinum by thiourea (80 g L-1 solution in 0.3 M H2SO4, the quantitative isolation of platinum was achieved (more than 90%. Therefore, the studied ion exchangers can be recommended for recovery and separation of Pt(II,IV, Cu(II and Zn(II ions.

  10. Pecan nutshell as biosorbent to remove Cu(II), Mn(II) and Pb(II) from aqueous solutions.

    Science.gov (United States)

    Vaghetti, Julio C P; Lima, Eder C; Royer, Betina; da Cunha, Bruna M; Cardoso, Natali F; Brasil, Jorge L; Dias, Silvio L P

    2009-02-15

    In the present study we reported for the first time the feasibility of pecan nutshell (PNS, Carya illinoensis) as an alternative biosorbent to remove Cu(II), Mn(II) and Pb(II) metallic ions from aqueous solutions. The ability of PNS to remove the metallic ions was investigated by using batch biosorption procedure. The effects such as, pH, biosorbent dosage on the adsorption capacities of PNS were studied. Four kinetic models were tested, being the adsorption kinetics better fitted to fractionary-order kinetic model. Besides that, the kinetic data were also fitted to intra-particle diffusion model, presenting three linear regions, indicating that the kinetics of adsorption should follow multiple sorption rates. The equilibrium data were fitted to Langmuir, Freundlich, Sips and Redlich-Peterson isotherm models. Taking into account a statistical error function, the data were best fitted to Sips isotherm model. The maximum biosorption capacities of PNS were 1.35, 1.78 and 0.946mmolg(-1) for Cu(II), Mn(II) and Pb(II), respectively.

  11. Copper(II) and lead(II) removal from aqueous solution by water treatment residues.

    Science.gov (United States)

    Castaldi, Paola; Silvetti, Margherita; Garau, Giovanni; Demurtas, Daniela; Deiana, Salvatore

    2015-01-01

    In this study, we investigated the ability of Fe- and Al-based water treatment residues (Fe- and Al-WTR) to accumulate Pb(II) and Cu(II) at pH 4.5. The role of the inorganic and organic fractions of WTRs in metals sorption was also assessed. Sorption isotherms showed a higher sorption of Pb(II) by both WTRs with respect to Cu(II) (e.g. 0.105 and 0.089 mmol g(-1) of Pb(II) and Cu(II) respectively sorbed by Fe-WTR). Fe-WTR revealed a stronger sorbent for both metals than Al-WTR. The amount of Pb(II) and Cu(II) sorbed by Fe-WTR was about the 69% and 63% higher than that sorbed by the Al-WTR. The organic matter of Fe- and Al-WTR contributed to about 26% and 8.5% respectively in the sorption of both metals. The sequential extraction procedure showed that the greatest amount of metals sorbed by both WTRs were tightly bound and not extractable, and this was particularly apparent for Cu(II). The FT-IR spectra indicated the formation of inner-sphere complexes between the Fe(Al)-O nucleus and Pb(II) and Cu(II). Moreover, the FT-IR spectra also suggested that the humic fraction of WTRs interacted, through the carboxylate groups, with Cu(II) and Pb(II) by forming mainly monodentate and bidentate complexes, respectively.

  12. Kinetics of homogeneous and surface-catalyzed mercury(II) reduction by iron(II)

    Science.gov (United States)

    Amirbahman, Aria; Kent, Douglas B.; Curtis, Gary P.; Marvin-DiPasquale, Mark C.

    2013-01-01

    Production of elemental mercury, Hg(0), via Hg(II) reduction is an important pathway that should be considered when studying Hg fate in environment. We conducted a kinetic study of abiotic homogeneous and surface-catalyzed Hg(0) production by Fe(II) under dark anoxic conditions. Hg(0) production rate, from initial 50 pM Hg(II) concentration, increased with increasing pH (5.5–8.1) and aqueous Fe(II) concentration (0.1–1 mM). The homogeneous rate was best described by the expression, rhom = khom [FeOH+] [Hg(OH)2]; khom = 7.19 × 10+3 L (mol min)−1. Compared to the homogeneous case, goethite (α-FeOOH) and hematite (α-Fe2O3) increased and γ-alumina (γ-Al2O3) decreased the Hg(0) production rate. Heterogeneous Hg(0) production rates were well described by a model incorporating equilibrium Fe(II) adsorption, rate-limited Hg(II) reduction by dissolved and adsorbed Fe(II), and rate-limited Hg(II) adsorption. Equilibrium Fe(II) adsorption was described using a surface complexation model calibrated with previously published experimental data. The Hg(0) production rate was well described by the expression rhet = khet [>SOFe(II)] [Hg(OH)2], where >SOFe(II) is the total adsorbed Fe(II) concentration; khet values were 5.36 × 10+3, 4.69 × 10+3, and 1.08 × 10+2 L (mol min)−1 for hematite, goethite, and γ-alumina, respectively. Hg(0) production coupled to reduction by Fe(II) may be an important process to consider in ecosystem Hg studies.

  13. Investigation of the oxygen affinity of manganese(II, cobalt(II and nickel(II complexes with some tetradentate Schiff bases

    Directory of Open Access Journals (Sweden)

    Adel A.A. Emara

    2014-12-01

    Full Text Available Oxygen absorption–desorption processes for square planar Mn(II, Co(II and Mn(II complexes of tetradentate Schiff base ligands in DMF and chloroform solvents were investigated. The tetradentate Schiff base ligands were obtained by condensation reaction of ethylenediamine with salcyldehyde, o-hydroxyacetophenone or acetylacetone in the molar ratio 1:2. The square planar complexes were prepared by the reaction of the Schiff base ligands with Mn(II acetate, Co(II nitrate and Ni(II nitrate in dry ethanol under nitrogen atmosphere. The sorption processes were undertaken in the presence and absence of (pyridine axial-base in 1:1 M ratio of (pyridine:metal(II complexes. Complexes in DMF indicate significant oxygen affinity than in chloroform solvent. Cobalt(II complexes showed significant sorption processes compared to Mn(II and Ni(II complexes. The presence of pyridine axial base clearly increases oxygen affinity.

  14. 禅悟人生,回归本真--论艾伦·金斯伯格的诗禅佛韵%Enlightening Life and Returning to the True Self:Allen Ginsberg ’s Zen in His Poetry

    Institute of Scientific and Technical Information of China (English)

    李寒

    2013-01-01

    Allen Ginsburg's affinity with Zen Buddhism is the inevitable of contingency, which is related to his own life experience, social environment, literary and cultural contexts. He begins to learn about Zen Buddhism at Columbia University. His belief in it deepens as he is in more contact with his friends on the east and west coasts of America. As a result, he goes to such Buddhist countries as India and China to learn Buddhism and practise meditation. He finally converts to Buddhism, piously believing in it until his death. In his Zen affinity, William Blake's voice across space and time initiates his spiritual enlightenment; In his happy life of meditation, he is absolutely at ease with everything, and his spontaneous writing integrating Zen with poetry exposes his poetry-Zen aesthetics in perceiving the real life; In his lightening life, he has compassion for the interests of the worldly, and transcends life and death, ultimately returns to his true Self.%艾伦·金斯伯格与佛禅的因缘是偶然中的必然。这与其自身的生活经历、社会环境、文学和文化背景相关联。大学时初结佛缘,后在与东西海岸的师友交往中佛缘渐深,以至亲自到印度、中国学佛参禅,最终皈依佛门,信奉持受一直到生命的最后。在佛禅的因缘中,威廉·布莱克的声音穿越时空开启他灵性的顿悟;在禅悦的人生中,他随缘任运,融通诗禅的自发写作表现出感悟生活真实的诗禅美学;在禅悟的人生中,他慈悲为怀利益众生,超越生死而最终回归生命的真实性。

  15. DIGITAL FLOOD INSURANCE RATE MAP DATABASE, ALLEN COUNTY, OHIO

    Data.gov (United States)

    Federal Emergency Management Agency, Department of Homeland Security — The Digital Flood Insurance Rate Map (DFIRM) Database depicts flood risk information and supporting data used to develop the risk data. The primary risk...

  16. DIGITAL FLOOD INSURANCE RATE MAP DATABASE, ALLEN COUNTY, INDIANA, USA

    Data.gov (United States)

    Federal Emergency Management Agency, Department of Homeland Security — The Digital Flood Insurance Rate Map (DFIRM) Database depicts flood risk Information And supporting data used to develop the risk data. The primary risk;...

  17. DIGITAL FLOOD INSURANCE RATE MAP DATABASE, ALLEN COUNTY, USA

    Data.gov (United States)

    Federal Emergency Management Agency, Department of Homeland Security — The Digital Flood Insurance Rate Map (DFIRM) Database depicts flood risk information and supporting data used to develop the risk data. The primary risk...

  18. DIGITAL FLOOD INSURANCE RATE MAP DATABASE, ALLEN COUNTY, KY

    Data.gov (United States)

    Federal Emergency Management Agency, Department of Homeland Security — The Digital Flood Insurance Rate Map (DFIRM) Database depicts flood risk information and supporting data used to develop the risk data. The primary risk...

  19. DIGITAL FLOOD INSURANCE RATE MAP DATABASE, ALLEN COUNTY, KANSAS, USA

    Data.gov (United States)

    Federal Emergency Management Agency, Department of Homeland Security — The Digital Flood Insurance Rate Map (DFIRM) Database depicts flood risk Information And supporting data used to develop the risk data. The primary risk;...

  20. BASEMAP, Basemap Framework Submission for ALLEN COUNTY, OHIO

    Data.gov (United States)

    Federal Emergency Management Agency, Department of Homeland Security — FEMA Framework Basemap datasets comprise six of the seven FGDC themes of geospatial data that are used by most GIS applications (Note: the seventh framework theme,...

  1. Farce: A History from Aristophanes to Woody Allen.

    Science.gov (United States)

    Bermel, Albert

    In a celebration of the expansiveness and inclusiveness of farce, this book describes the art form rather than defines it. Part 1 illustrates the nature of farce and its relationship to tragedy, comedy, and melodrama. Part 2 is a cumulative biography of farce, beginning with Greek and Roman writers and continuing through Shakespeare, Moliere, and…

  2. Semiotic Text - discovering perspective accidentally / Daniel Edward Allen

    Index Scriptorium Estoniae

    Allen, Daniel Edward, 1966-

    2014-01-01

    Läti fotolaagrist, kus autor tutvus esmakordsest Eesti esimese fotograafi Johannes Pääsukese sajandivanuste töödega, mis andsid talle inspiratsiooni oma kunstiprojekti läbiviimiseks. Pildistamisest minevikus ja tänapäeval

  3. Basemap Framework Submission for Allen Parish, LA, USA

    Data.gov (United States)

    Federal Emergency Management Agency, Department of Homeland Security — FEMA Framework Basemap datasets comprise six of the seven FGDC themes of geospatial data that are used by most GIS applications (Note: the seventh framework theme,...

  4. K\\"allen-Lehman Representation and the Gluon Propagator

    CERN Document Server

    Frasca, Marco

    2007-01-01

    We exploit the Kallen-Lehman representation of the two-point Wightman function to prove that the gluon propagator cannot go to zero in the infrared limit. We are able to derive also the functional form of it. This means that current results on the lattice can be used to derive the scalar glueball spectrum to be compared both with experiments and different aimed lattice computations.

  5. Designed for a better life. Interview by Daniel Allen.

    Science.gov (United States)

    Cunningham, Colm

    2009-04-01

    A new design audit tool contains a series of resources for carrying out an assessment of environments used by people with dementia. It is suitable for refurbishment projects or new buildings and can be used across a range of settings, including day centres, hospital wards, care homes and GP surgeries.

  6. Distsiplineeri end! : elustiili kureerimine Sejima ja Nishizawa loomingus / Matthew Allen

    Index Scriptorium Estoniae

    Allen, Matthew

    2011-01-01

    Kazuyo Sejima ja Ryue Nishizawa (AB SANAA, Jaapan) loomingust. Autor kirjutab, et Sejima ja Nishizawa ühisbüroos SANAA valminud projektid loovad spetsiifilise arhitektuurse subjekti. Arhitektide looming ärgitab asukaid omaenda elustiili estetiseerima ja kureerima, ruum juhib ja distsiplineerib kasutajat

  7. NNDSS - Table II. Hepatitis (viral, acute) C

    Data.gov (United States)

    U.S. Department of Health & Human Services — NNDSS - Table II. Hepatitis (viral, acute) C - 2017. In this Table, provisional cases of selected notifiable diseases (≥1,000 cases reported during the preceding...

  8. NNDSS - Table II. Hepatitis (viral, acute)

    Data.gov (United States)

    U.S. Department of Health & Human Services — NNDSS - Table II. Hepatitis (viral, acute) - 2014.In this Table, all conditions with a 5-year average annual national total of more than or equals 1,000 cases but...

  9. NNDSS - Table II. Hepatitis (viral, acute)

    Data.gov (United States)

    U.S. Department of Health & Human Services — NNDSS - Table II. Hepatitis (viral, acute) - 2016. In this Table, provisional* cases of selected†notifiable diseases (≥1,000 cases reported during the preceding...

  10. NNDSS - Table II. Hepatitis (viral, acute)

    Data.gov (United States)

    U.S. Department of Health & Human Services — NNDSS - Table II. Hepatitis (viral, acute) - 2015.In this Table, provisional cases of selected notifiable diseases (≥1,000 cases reported during the preceding...

  11. Courseware Review: Vernier Software: Precision Timer II.

    Science.gov (United States)

    Park, John C.

    1988-01-01

    Reviews "Vernier Software: Precision Timer II" for high school through college mechanics. Introduces 14 different modes including pulse time, pendulum timer, bouncer timer, gate timer, collision timers, and stroke calibration. Provides two typical displays and ratings of the software. (YP)

  12. Aleksi II kritikujet "Kod da Vintshi"

    Index Scriptorium Estoniae

    2006-01-01

    Dan Browni samanimelise romaani järgi valminud põnevusfilm "Da Vinci kood" : režissöör Ron Howard : Ameerika Ühendriigid 2006. Venemaa patriarh Aleksius II nimetas filmi linastamist lugupidamatuseks moraalinormide vastu

  13. NNDSS - Table II. Tetanus to Vibriosis

    Data.gov (United States)

    U.S. Department of Health & Human Services — NNDSS - Table II. Tetanus to Vibriosis - 2016. In this Table, provisional* cases of selected†notifiable diseases (≥1,000 cases reported during the preceding...

  14. NNDSS - Table II. Tetanus to Vibriosis

    Data.gov (United States)

    U.S. Department of Health & Human Services — NNDSS - Table II. Tetanus to Vibriosis - 2015.In this Table, provisional cases of selected notifiable diseases (≥1,000 cases reported during the preceding year),...

  15. GRACE-II Small Satellite Study Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Quantify the science benefits of GRACE-II mission comprised of multiple pairs of smallsats using realistic expected performance of smallsats and a miniaturized...

  16. Quest II produce quality research overview

    NARCIS (Netherlands)

    Lukasse, L.J.S.; Harkema, H.; Otma, E.C.; Paillart, M.J.M.

    2013-01-01

    The Quest II control algorithm (patent pending), developed by Wageningen UR Food & Biobased Research together with Maersk Line and Carrier Transicold, reduces the energy consumption of reefer containers by approx. 65% without impairing produce quality.

  17. Input data to run Landis-II

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The data are input data files to run the forest simulation model Landis-II for Isle Royale National Park. Files include: a) Initial_Comm, which includes the location...

  18. Training experience at Experimental Breeder Reactor II

    Energy Technology Data Exchange (ETDEWEB)

    Driscoll, J.W.; McCormick, R.P.; McCreery, H.I.

    1978-01-01

    The EBR-II Training Group develops, maintains,and oversees training programs and activities associated with the EBR-II Project. The group originally spent all its time on EBR-II plant-operations training, but has gradually spread its work into other areas. These other areas of training now include mechanical maintenance, fuel manufacturing facility, instrumentation and control, fissile fuel handling, and emergency activities. This report describes each of the programs and gives a statistical breakdown of the time spent by the Training Group for each program. The major training programs for the EBR-II Project are presented by multimedia methods at a pace controlled by the student. The Training Group has much experience in the use of audio-visual techniques and equipment, including video-tapes, 35 mm slides, Super 8 and 16 mm film, models, and filmstrips. The effectiveness of these techniques is evaluated in this report.

  19. NNDSS - Table II. Legionellosis to Malaria

    Data.gov (United States)

    U.S. Department of Health & Human Services — NNDSS - Table II. Legionellosis to Malaria - 2017. In this Table, provisional cases of selected notifiable diseases (≥1,000 cases reported during the preceding...

  20. NNDSS - Table II. Meningococcal to Pertussis

    Data.gov (United States)

    U.S. Department of Health & Human Services — NNDSS - Table II. Meningococcal to Pertussis - 2017. In this Table, provisional cases of selected notifiable diseases (≥1,000 cases reported during the preceding...

  1. NNDSS - Table II. Salmonellosis to Shigellosis

    Data.gov (United States)

    U.S. Department of Health & Human Services — NNDSS - Table II. Salmonellosis to Shigellosis - 2017. In this Table, provisional cases of selected notifiable diseases (≥1,000 cases reported during the preceding...

  2. NNDSS - Table II. Ehrlichiosis and Anaplasmosis

    Data.gov (United States)

    U.S. Department of Health & Human Services — NNDSS - Table II. Ehrlichiosis and Anaplasmosis - 2017. In this Table, provisional cases of selected notifiable diseases (≥1,000 cases reported during the...

  3. NNDSS - Table II. Tetanus to Varicella

    Data.gov (United States)

    U.S. Department of Health & Human Services — NNDSS - Table II. Tetanus to Varicella - 2017. In this Table, provisional cases of selected notifiable diseases (≥1,000 cases reported during the preceding year),...

  4. NNDSS - Table II. Cryptosporidiosis to Dengue

    Data.gov (United States)

    U.S. Department of Health & Human Services — NNDSS - Table II. Cryptosporidiosis to Dengue - 2017. In this Table, provisional cases of selected notifiable diseases (≥1,000 cases reported during the preceding...

  5. NNDSS - Table II. West Nile virus disease

    Data.gov (United States)

    U.S. Department of Health & Human Services — NNDSS - Table II. West Nile virus disease - 2015.In this Table, provisional cases of selected notifiable diseases (≥1,000 cases reported during the preceding...

  6. NNDSS - Table II. Salmonellosis to Shigellosis

    Data.gov (United States)

    U.S. Department of Health & Human Services — NNDSS - Table II. Salmonellosis to Shigellosis - 2014. In this Table, all conditions with a 5-year average annual national total of more than or equals 1,000 cases...

  7. NNDSS - Table II. Invasive Pneumococcal to Legionellosis

    Data.gov (United States)

    U.S. Department of Health & Human Services — NNDSS - Table II. Invasive Pneumococcal to Legionellosis - 2014.In this Table, all conditions with a 5-year average annual national total of more than or equals...

  8. NNDSS - Table II. Invasive Pneumococcal to Legionellosis

    Data.gov (United States)

    U.S. Department of Health & Human Services — NNDSS - Table II. Invasive Pneumococcal to Legionellosis - 2015.In this Table, provisional cases of selected notifiable diseases (≥1,000 cases reported during the...

  9. NNDSS - Table II. Invasive Pneumococcal to Legionellosis

    Data.gov (United States)

    U.S. Department of Health & Human Services — NNDSS - Table II. Invasive Pneumococcal to Legionellosis - 2016. In this Table, provisional* cases of selected†notifiable diseases (≥1,000 cases reported during...

  10. NNDSS - Table II. Lyme disease to Meningococcal

    Data.gov (United States)

    U.S. Department of Health & Human Services — NNDSS - Table II. Lyme disease to Meningococcal - 2016. In this Table, provisional* cases of selected†notifiable diseases (≥1,000 cases reported during the...

  11. NNDSS - Table II. Rubella to Salmonellosis

    Data.gov (United States)

    U.S. Department of Health & Human Services — NNDSS - Table II. Rubella to Salmonellosis - 2016. In this Table, provisional* cases of selected†notifiable diseases (≥1,000 cases reported during the preceding...

  12. NNDSS - Table II. Cryptosporidiosis to Dengue

    Data.gov (United States)

    U.S. Department of Health & Human Services — NNDSS - Table II. Cryptosporidiosis to Dengue - 2016. In this Table, provisional* cases of selected†notifiable diseases (≥1,000 cases reported during the...

  13. NNDSS - Table II. Giardiasis to Haemophilus influenza

    Data.gov (United States)

    U.S. Department of Health & Human Services — NNDSS - Table II. Giardiasis to Haemophilus influenza - 2016. In this Table, provisional* cases of selected†notifiable diseases (≥1,000 cases reported during the...

  14. NNDSS - Table II. Ehrlichiosis/Anaplasmosis

    Data.gov (United States)

    U.S. Department of Health & Human Services — NNDSS - Table II. Ehrlichiosis/Anaplasmosis - 2016. In this Table, provisional* cases of selected†notifiable diseases (≥1,000 cases reported during the preceding...

  15. NNDSS - Table II. Chlamydia to Coccidioidomycosis

    Data.gov (United States)

    U.S. Department of Health & Human Services — NNDSS - Table II. Chlamydia to Coccidioidomycosis - 2016. In this Table, provisional* cases of selected†notifiable diseases (≥1,000 cases reported during the...

  16. NNDSS - Table II. West Nile virus disease

    Data.gov (United States)

    U.S. Department of Health & Human Services — NNDSS - Table II. West Nile virus disease - 2017. In this Table, provisional cases of selected notifiable diseases (≥1,000 cases reported during the preceding...

  17. NNDSS - Table II. Lyme disease to Meningococcal

    Data.gov (United States)

    U.S. Department of Health & Human Services — NNDSS - Table II. Lyme disease to Meningococcal - 2014In this Table, all conditions with a 5-year average annual national total of more than or equals 1,000 cases...

  18. NNDSS - Table II. Babesiosis to Campylobacteriosis

    Data.gov (United States)

    U.S. Department of Health & Human Services — NNDSS - Table II. Babesiosis to Campylobacteriosis - 2017. In this Table, provisional cases of selected notifiable diseases (≥1,000 cases reported during the...

  19. NNDSS - Table II. Chlamydia to Coccidioidomycosis

    Data.gov (United States)

    U.S. Department of Health & Human Services — NNDSS - Table II. Chlamydia to Coccidioidomycosis - 2017. In this Table, provisional cases of selected notifiable diseases (≥1,000 cases reported during the...

  20. NNDSS - Table II. Shiga toxin to Shigellosis

    Data.gov (United States)

    U.S. Department of Health & Human Services — NNDSS - Table II. Shiga toxin to Shigellosis - 2015. In this Table, provisional cases of selected notifiable diseases (≥1,000 cases reported during the preceding...

  1. NNDSS - Table II. Shiga toxin to Shigellosis

    Data.gov (United States)

    U.S. Department of Health & Human Services — NNDSS - Table II. Shiga toxin to Shigellosis - 2016. In this Table, provisional* cases of selected†notifiable diseases (≥1,000 cases reported during the...

  2. NNDSS - Table II. Giardiasis to Haemophilus influenza

    Data.gov (United States)

    U.S. Department of Health & Human Services — NNDSS - Table II. Giardiasis to Haemophilus influenza - 2017. In this Table, provisional cases of selected notifiable diseases (≥1,000 cases reported during the...

  3. NNDSS - Table II. Babesiosis to Campylobacteriosis

    Data.gov (United States)

    U.S. Department of Health & Human Services — NNDSS - Table II. Babesiosis to Campylobacteriosis - 2016. In this Table, provisional* cases of selected†notifiable diseases (≥1,000 cases reported during the...

  4. NNDSS - Table II. Mumps to Rabies, animal

    Data.gov (United States)

    U.S. Department of Health & Human Services — NNDSS - Table II. Mumps to Rabies, animal - 2015.In this Table, provisional cases of selected notifiable diseases (≥1,000 cases reported during the preceding...

  5. NNDSS - Table II. Mumps to Rabies, animal

    Data.gov (United States)

    U.S. Department of Health & Human Services — NNDSS - Table II. Mumps to Rabies, animal - 2014.In this Table, all conditions with a 5-year average annual national total of more than or equals 1,000 cases but...

  6. NNDSS - Table II. Chlamydia to Coccidioidomycosis

    Data.gov (United States)

    U.S. Department of Health & Human Services — NNDSS - Table II. Chlamydia to Coccidioidomycosis - 2015.In this Table, provisional cases of selected notifiable diseases (≥1,000 cases reported during the...

  7. NNDSS - Table II. Rubella to Salmonellosis

    Data.gov (United States)

    U.S. Department of Health & Human Services — NNDSS - Table II. Rubella to Salmonellosis - 2015.In this Table, provisional cases of selected notifiable diseases (≥1,000 cases reported during the preceding...

  8. NNDSS - Table II. Giardiasis to Haemophilus influenza

    Data.gov (United States)

    U.S. Department of Health & Human Services — NNDSS - Table II. Giardiasis to Haemophilus influenza - 2014. In this Table, all conditions with a 5-year average annual national total of more than or equals 1,000...

  9. NNDSS - Table II. Babesiosis to Coccidioidomycosis

    Data.gov (United States)

    U.S. Department of Health & Human Services — NNDSS - Table II. Babesiosis to Coccidioidomycosis - 2014.In this Table, provisional cases of selected notifiable diseases (≥1,000 cases reported during the...

  10. NNDSS - Table II. Babesiosis to Campylobacteriosis

    Data.gov (United States)

    U.S. Department of Health & Human Services — NNDSS - Table II. Babesiosis to Campylobacteriosis - 2015.In this Table, provisional cases of selected notifiable diseases (≥1,000 cases reported during the...

  11. NNDSS - Table II. Lyme disease to Meningococcal

    Data.gov (United States)

    U.S. Department of Health & Human Services — NNDSS - Table II. Lyme disease to Meningococcal - 2015.In this Table, provisional cases of selected notifiable diseases (≥1,000 cases reported during the preceding...

  12. NNDSS - Table II. Ehrlichiosis/Anaplasmosis

    Data.gov (United States)

    U.S. Department of Health & Human Services — NNDSS - Table II. Ehrlichiosis/Anaplasmosis - 2014.In this Table, all conditions with a 5-year average annual national total of more than or equals 1,000 cases but...

  13. NNDSS - Table II. Cryptosporidiosis to Dengue

    Data.gov (United States)

    U.S. Department of Health & Human Services — NNDSS - Table II. Cryptosporidiosis to Dengue - 2015.In this Table, provisional cases of selected notifiable diseases (≥1,000 cases reported during the preceding...

  14. NNDSS - Table II. Giardiasis to Haemophilus influenza

    Data.gov (United States)

    U.S. Department of Health & Human Services — NNDSS - Table II. Giardiasis to Haemophilus influenza - 2015.In this Table, provisional cases of selected notifiable diseases (≥1,000 cases reported during the...

  15. NNDSS - Table II. Ehrlichiosis/Anaplasmosis

    Data.gov (United States)

    U.S. Department of Health & Human Services — NNDSS - Table II. Ehrlichiosis/Anaplasmosis - 2015.In this Table, provisional cases of selected notifiable diseases (≥1,000 cases reported during the preceding...

  16. Fe ii fluorescence in symbiotic stars

    Directory of Open Access Journals (Sweden)

    M. Eriksson

    2004-01-01

    Full Text Available Se ha investigado la uorescencia por PAR del ion Fe II en ocho estrellas simbi oticas con muy diversos valores de la temperatura de la componente caliente y del per odo orbital. Los datos empleados son espectros de archivo del IUE. Todas las l neas de bombeo estudiadas se encuentran en la regi on (1200-2000 A del IUE, excepto He II 1084.942 y O VI 1032.041. Las l neas de uorescencia del Fe II est an principalmente en la regi on Fe II, pero algunas caen en la regi on de las l neas de bombeo. Nuestro objetivo es entender las condiciones optimas para la formaci on de l neas de uorescencia por PAR del Fe II. Tres de los sistemas estudiados, RR Tel, AG Peg and V1016 Cyg, presentan 10-30 canales activos del Fe II. Dos condiciones relacionan a estos sistemas. La componente caliente es una enana blanca de temperatura extrema (80 103-150 103 K, y los tres sistemas son novas simbi oticas, que han tenido erupciones en los ultimos 150 a~nos. Los sistemas AG Dra, RW Hya and R Aqr tienen s olo 2-3 canales activos del Fe II. Los dos sistemas restantes, CI Cyg and T CrB, no mostraron l neas de uorescencia del Fe II. Estos sistemas tienen en com un que la intensidad de emisi on de los elementos altamente ionizados es menor que en la mayor a de los sistemas simbi oticos, y que la componente caliente puede ser una estrella de secuencia principal con acreci on, en vez de una enana blanca.

  17. NSLS-II Radio Frequency Systems

    Energy Technology Data Exchange (ETDEWEB)

    Rose J.; Gao F.; Goel, A.; Holub, B.; Kulpin, J.; Marques, C.; Yeddulla, M.

    2015-05-03

    The National Synchrotron Light Source II is a 3 GeV X-ray user facility commissioned in 2014. The NSLS-II RF system consists of the master oscillator, digital low level RF controllers, linac, booster and storage ring RF sub-systems, as well as a supporting cryogenic system. Here we will report on RF commissioning and early operation experience of the system.

  18. EXODUS II: A finite element data model

    Energy Technology Data Exchange (ETDEWEB)

    Schoof, L.A.; Yarberry, V.R.

    1994-09-01

    EXODUS II is a model developed to store and retrieve data for finite element analyses. It is used for preprocessing (problem definition), postprocessing (results visualization), as well as code to code data transfer. An EXODUS II data file is a random access, machine independent, binary file that is written and read via C, C++, or Fortran library routines which comprise the Application Programming Interface (API).

  19. NSLS-II Beam Diagnostics Overview

    Energy Technology Data Exchange (ETDEWEB)

    Singh,O.; Alforque, R.; Bacha, B.; Blednykh, A.; Cameron, P.; Cheng, W.; Dalesio, L. B.; Della Penna, A. J.; doom, L.; Fliller, R. P.; Ganetis, G.; Heese, R.; Hseuh, H-C.; Johnson, E. D.; Kosciuk, b. N.; Kramer, S. L.; Krinsky, S.; Mead, J.; Ozaki, S.; Padrazo, D.; Pinayev, I.; Ravindranath, R. V.; Rose, J.; Shaftan, T.; Sharma, S.; Skaritka, J.; Tanabe, T.; Tian, Y.; Willeke, F. J.; Yu, L-H.

    2009-05-04

    A new 3rd generation light source (NSLS-II) is in the early stages of construction at Brookhaven National Laboratory. The NSLS-II facility will provide ultra high brightness and flux with exceptional beam stability. It presents several challenges for diagnostics and instrumentation, related to the extremely small emittance. In this paper, we present an overview of all planned instrumentation systems, results from research and development activities; and then focus on other challenging aspects.

  20. Development of Low Cost Adsorbent from Cow Horn for the Biosorption of Mn (II, Ni (II and Cd (II Ion from Aqueous Solution

    Directory of Open Access Journals (Sweden)

    Jimoh. O. Tijani

    2014-01-01

    Full Text Available Development of low cost adsorbent from cow horn for the biosorption of Mn (II, Ni (II and Cd (II ion aqueous solution was carried out by batch adsorption experiment at 32°C. Parameters such as pH, contact time, metal ion concentrations as well as temperature were monitored. The residual concentration of Mn (II, Ni (II and Cd (II were determined using Atomic Absorption Spectrophotometer. The results revealed that maximum Ni (II and Cd (II ion removal occurred at pH of 6 while Mn (II ion occurred at pH of 7 respectively. Langmuir and Temkin adsorption isotherm were used to describe the equilibrium data. The equilibrium data fitted well to Langmuir isotherm than Temkin isotherm. Thermodynamic investigation showed that standard Gibbs free energy (∆G˚ was positive indicating the feasibility and non-spontaneous of the process. The positive value of standard Enthalpy (∆H˚ implies that the reaction was endothermic and the negative standard Entropy (∆S˚ signifies decrease in the randomness at the solid/solution interface of the adsorbent during the adsorption process. The kinetic study revealed that adsorption of Mn (II, Ni (II and Cd (II could be best described by pseudo-second model. This study demonstrated that adsorbent developed from cow horn could be used as an alternative to commercial activated carbon in the removal of Mn (II, Ni (II and Cd (II ions from aqueous solution.

  1. Synthesis and characterization of hydroxyapatite nanoparticles impregnated on apple pomace to enhanced adsorption of Pb(II), Cd(II), and Ni(II) ions from aqueous solution.

    Science.gov (United States)

    Chand, Piar; Pakade, Yogesh B

    2015-07-01

    Hydroxyapatite nanoparticles were synthesized, characterized, and impregnated onto apple pomace surface (HANP@AP) for efficient removal of Pb(II), Cd(II), and Ni(II) ions from water. HANP@AP was characterized by Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), energy-dispersive spectroscopy (EDS), transmission electron microscope (TEM), X-ray diffraction (XRD), and surface area analysis. Batch sorption studies were carried out to investigate the influence of different parameters as amount of dose (g), pH, time (min), and initial concentration (mg L(-1)) on adsorption process. Experimental kinetic data followed pseudo-second-order model and equilibrium data well fitted to Langmuir adsorption model with maximum adsorption capacities of 303, 250, and 100 mg g(-1) for Pb(II), Cd(II), and Ni(II) ions, respectively. Competitive adsorption of Pb(II), Cd(II), and Ni(II) ions in presences of each other was studied to evaluate the removal efficiency of HANP@AP against multi metal-loaded water. HANP@AP was successfully applied to real industrial wastewater with 100 % removal of all three metal ions even at high concentration. HANP@AP could be recycled for four, four, and three cycles in case of Pb(II), Cd(II) and Ni(II), respectively. The study showed that HANP@AP is fast, cost effective, and environmental friendly adsorbent for removal of Pb(II), Cd(II), and Ni(II) ions from real industrial wastewater.

  2. Pb(II) and Cd(II) removal from aqueous solutions by olive cake

    Energy Technology Data Exchange (ETDEWEB)

    Doyurum, Sabriye [Department of Chemistry, Faculty of Arts and Sciences, Celal Bayar University, Manisa 45140 (Turkey)]. E-mail: sabriyedoyurum@yahoo.com; Celik, Ali [Department of Chemistry, Faculty of Arts and Sciences, Celal Bayar University, Manisa 45140 (Turkey)

    2006-11-02

    The removal of heavy metals from wastewater using olive cake as an adsorbent was investigated. The effect of the contact time, pH, temperature, and concentration of adsorbate on adsorption performance of olive cake for Pb(II) and Cd(II) ions were examined by batch method. Adsorption of Pb(II) and Cd(II) in aqueous solution onto olive cake was studied in single component. After establishing the optimum conditions, elution of these ions from the adsorbent surface was also examined. The optimum sorption conditions were determined for two elements. Maximum desorption of the Pb(II) and Cd(II) ions were found to be 95.92 and 53.97% by 0.5 M HNO{sub 3} and 0.2 M HCl, respectively. The morphological analysis of the olive cake was performed by the scanning electron microscopy (SEM)

  3. Pb(II) and Cd(II) removal from aqueous solutions by olive cake.

    Science.gov (United States)

    Doyurum, Sabriye; Celik, Ali

    2006-11-02

    The removal of heavy metals from wastewater using olive cake as an adsorbent was investigated. The effect of the contact time, pH, temperature, and concentration of adsorbate on adsorption performance of olive cake for Pb(II) and Cd(II) ions were examined by batch method. Adsorption of Pb(II) and Cd(II) in aqueous solution onto olive cake was studied in single component. After establishing the optimum conditions, elution of these ions from the adsorbent surface was also examined. The optimum sorption conditions were determined for two elements. Maximum desorption of the Pb(II) and Cd(II) ions were found to be 95.92 and 53.97% by 0.5M HNO(3) and 0.2M HCl, respectively. The morphological analysis of the olive cake was performed by the scanning electron microscopy (SEM).

  4. Poly[tetraaquadi-mu4-malonato-barium(II)zinc(II)].

    Science.gov (United States)

    Guo, Ming Lin; Guo, Chen Hu

    2006-01-01

    The title complex, [BaZn(C3H2O4)2(H2O)4]n, is polymeric, due to the connectivity brought about by each malonate dianion bonding to two different Zn(II) cations and two different Ba(II) cations. The Ba(II) cations, on crystallographic twofold axes, have slightly distorted square-antiprismic coordination, with Ba-O distances ranging from 2.795 (2) to 2.848 (2) A. The Zn(II) cations, which lie on crystallographic centres of symmetry, have distorted octahedral coordination, with Zn-O bonds in the range 2.0364 (19)-2.3248 (18) A. The water molecules participate in extensive O-H...O hydrogen bonding. The structure comprises alternating layers along [100], with one type containing Zn(II) cations and malonate dianions, while the other is primarily composed of Ba(II) cations and water molecules.

  5. Poly[tetra­aqua-di-μ4-malonato-barium(II)cadmium(II)

    Science.gov (United States)

    Guo, Ming-Lin; Gao, Wen-Jun; Luo, Cong-Cong; Liu, Long

    2011-01-01

    In the title complex, [BaCd(C3H2O4)2(H2O)4]n, the BaII atoms, located on crystallographic twofold axes, adopt slightly distorted square-anti­prismatic coordination geometries, while the CdII atoms, which lie on crystallographic centres of symmetry, have a distorted octa­hedral coordination. Each malonate dianion binds two different CdII atoms and two different BaII atoms. This connectivity generates alternating layers along [100] in the structure, with one type containing CdII cations and malonate dianions, while the other is primarily composed of BaII ions and coordinated water mol­ecules. The water mol­ecules also participate in extensive O—H⋯O hydrogen bonding. PMID:21522548

  6. Poly[tetra-aqua-di-μ(4)-malonato-barium(II)cadmium(II)].

    Science.gov (United States)

    Guo, Ming-Lin; Gao, Wen-Jun; Luo, Cong-Cong; Liu, Long

    2010-12-04

    In the title complex, [BaCd(C(3)H(2)O(4))(2)(H(2)O)(4)](n), the Ba(II) atoms, located on crystallographic twofold axes, adopt slightly distorted square-anti-prismatic coordination geometries, while the Cd(II) atoms, which lie on crystallographic centres of symmetry, have a distorted octa-hedral coordination. Each malonate dianion binds two different Cd(II) atoms and two different Ba(II) atoms. This connectivity generates alternating layers along [100] in the structure, with one type containing Cd(II) cations and malonate dianions, while the other is primarily composed of Ba(II) ions and coordinated water mol-ecules. The water mol-ecules also participate in extensive O-H⋯O hydrogen bonding.

  7. Preferred crystallographic orientation in the ice I ← II transformation and the flow of ice II

    Science.gov (United States)

    Bennett, K.; Wenk, H.-R.; Durham, W.B.; Stern, L.A.; Kirby, S.H.

    1997-01-01

    The preferred crystallographic orientation developed during the ice I ← II transformation and during the plastic flow of ice II was measured in polycrystalline deuterium oxide (D2O) specimens using low-temperature neutron diffraction. Samples partially transformed from ice I to II under a non-hydrostatic stress developed a preferred crystallographic orientation in the ice II. Samples of pure ice II transformed from ice I under a hydrostatic stress and then when compressed axially, developed a strong preferred orientation of compression axes parallel to (1010). A match to the observed preferred orientation using the viscoplastic self-consistent theory was obtained only when (1010) [0001] was taken as the predominant slip system in ice II.

  8. Differential Effect of Solution Conditions on the Conformation of the Actinoporins Sticholysin II and Equinatoxin II

    Directory of Open Access Journals (Sweden)

    EDSON V.F. FAUTH

    2014-12-01

    Full Text Available Actinoporins are a family of pore-forming proteins with hemolytic activity. The structural basis for such activity appears to depend on their correct folding. Such folding encompasses a phosphocholine binding site, a tryptophan-rich region and the activity-related N-terminus segment. Additionally, different solution conditions are known to be able to influence the pore formation by actinoporins, as for Sticholysin II (StnII and Equinatoxin II (EqtxII. In this context, the current work intends to characterize the influence of distinct solution conditions in the conformational behavior of these proteins through molecular dynamics (MD simulations. The obtained data offer structural insights into actinoporins dynamics in solution, characterizing its conformational behavior at the atomic level, in accordance with previous experimental data on StnII and EqtxII hemolytic activities.

  9. PIVKA-II-producing advanced gastric cancer.

    Science.gov (United States)

    Takano, Shigetsugu; Honda, Ichiro; Watanabe, Satoshi; Soda, Hiroaki; Nagata, Matsuo; Hoshino, Isamu; Takenouchi, Toshinao; Miyazaki, Masaru

    2004-08-01

    We describe the case of a 68-year-old man with primary advanced adenocarcinoma of the stomach, who displayed extremely high plasma levels of protein induced by vitamin K antagonist (PIVKA)-II (15 600 mAU/ml) and normal levels of alphafetoprotein (AFP) (4 ng/ml). Ultrasonography and dynamic computed tomography ruled out hepatocellular carcinoma (HCC) or liver metastasis. After preoperative chemotherapy, pancreatico-spleno total gastrectomy with D2 lymphadenectomy was performed. Postoperatively, plasma levels of PIVKA-II returned to within the normal range (29 mAU/ml). Microscopic examination revealed stomach adenocarcinoma showing various histological types, such as moderately to poorly differentiated mucinous adenocarcinoma, but hepatoid differentiation of gastric adenocarcinoma was not detected. Localization of PIVKA-II and AFP within tumor cells was demonstrated by immunohistochemical staining using monoclonal antibodies. These results indicate that tumor cells from gastric cancer may produce PIVKA-II. Some cases of PIVKA-II- and AFP-producing advanced gastric cancer with liver metastasis have been reported, but this is the first report of gastric cancer without liver metastasis producing PIVKA-II alone.

  10. AUGO II: A Comprehensive Subauroral Zone Observatory

    Science.gov (United States)

    Schofield, I. S.; Connors, M. G.

    2012-12-01

    Athabasca University Geophysical Observatory II (AUGO II) is a comprehensive subauroral zone observatory designed for routine automated optical and magnetic observation of the aurora. Becoming operational in February 2012, AUGO II has six temperature/humidity controlled observation rooms, each equipped with a 1.5 meter diameter acrylic dome custom fabricated for wide spectral transparency. AUGO II is located approximately 25 km southwest of the town of Athabasca, in Alberta, Canada, on the southern edge of the auroral zone (Geodetic coordinates: latitude 54 36' 10", longitude 113 38' 40" west. CGM coordinates: latitude 61.7, longitude 306.8, L-value 4.5). AUGO II is sufficiently isolated from urban development that skies are dark enough during winter months to allow optical studies of faint phenomena, such as H-beta studies of proton precipitation aurora, currently underway. The observatory's modest residence can accommodate six persons, allowing groups to live and work with their instruments for the duration of their research campaign without leaving the site. AUGO II's inaugural guest research campaign was reported successful, and resulted in a permanent VLF/LF radio experiment being deployed at the observatory's expansive site. We are hopeful more research groups will take advantage of this unique facility and help realize its full potential.

  11. Coordination Modes of a Schiff Base Derived from Substituted 2-Aminothiazole with Chromium(III, Manganese(II, Iron(II, Cobalt(II, Nickel(II and Copper(II Metal Ions: Synthesis, Spectroscopic and Antimicrobial Studies

    Directory of Open Access Journals (Sweden)

    Ambit Thakar

    2011-01-01

    Full Text Available Transition metal complexes of Cr(III, Mn(II, Fe(II, Co(II, Ni(II and Cu(II metal ions with general stoichiometry [ML2.2H2O] and [ML3], where M= Mn(II, Cr(III, Fe(II, Co(II, Ni(II and Cu(II, L= Schiff base derived from the condensation of 2-amino-4(4’-phenyl/methylphenyl-5-methyl-thiazole with 4-acetyl-1(3-chloro phenyl-3-methyl-2-pyrazoline-5-ones, have been synthesized and structurally characterized by elemental analysis, molar conductance measurements, magnetic susceptibility measurements and spectral techniques like IR, UV, 1H NMR, 13C NMR and Mass Spectra. All the complexes were found to be octahedral geometry. The ligand and its complexes have been screened for their antifungal and antibacterial activities against three fungi, i.e. Alternaria brassicae, Aspergillus niger and Fesarium oxysporum and two bacteria, i.e. Xanthomonas compestris and Pseudomonas aeruginosa.

  12. Application of mesoporous SBA-15 silica functionalized with 4-amino-2-mercaptopyrimidine for the adsorption of Cu(II), Zn(II), Cd(II), Ni(II), and Pb(II) from water.

    Science.gov (United States)

    Jorgetto, Alexandre de Oliveira; Pereira, Silvana Pontes; Silva, Rafael Innocenti Vieira da; Saeki, Margarida Juri; Martines, Marco Antonio Utrera; Pedrosa, Valber de Albuquerque; Castro, Gustavo Rocha de

    2015-01-01

    This work reports the sol-gel synthesis of a SBA-15 silica, and its functionalization with 4-amino-2-mercaptopyrimidine to perform adsorption of metal species from aqueous media. The functionalization of the material was confirmed by FTIR and superficial area measurements. The final material was tested through batch experiments to uncover its adsorptive properties towards the adsorption of Cu(II), Cd(II), Zn(II), Pb(II) and Ni(II). Contact time and pH conditions were investigated, and the material presented slow adsorption kinetics, which was best described by the pseudo-second order model. In addition, at pH 5 - 6, the adsorption of the metal ions was favored. Under optimized conditions, the material had its maximum adsorption capacities determined for all metal species studied, and the obtained values were 13.0 µmol g(-1) for Zn(II), 12.3 µmol g(-1) for Cu(II), 3.45 µmol g(-1) for Ni(II), 2.45 µmol g(-1) for Pb(II) and 0.60 µmol g(-1) for Cd(II). The capacity differences between each metal ion were discussed in terms of their ionic radii and Person's soft/hard acids/bases concept.

  13. Mutation and biochemical analysis in carnitine palmitoyltransferase type II (CPT II) deficiency

    DEFF Research Database (Denmark)

    Olpin, S E; Afifi, A; Clark, S

    2003-01-01

    Carnitine palmitoyltransferase type II (CPT II) deficiency has three basic phenotypes, late-onset muscular (mild), infantile/juvenile hepatic (intermediate) and severe neonatal. We have measured fatty acid oxidation and CPT II activity and performed mutation studies in 24 symptomatic patients......, the implication being that they may significantly influence the manifestation of clinical disease and could therefore potentially be considered as a susceptibility variants. Among myopathic individuals, males comprised 88% of patients, suggesting increased susceptibility to clinical disease. A small number...

  14. Development of Canonical Marine Aviation Logistics Support Program II (MALSP II) Deployment

    Science.gov (United States)

    2015-06-01

    logistics supply chain. A supply chain is a complex dynamic network involving the flow of information, material , and funds (Ahn, Lee, & Park, 2003, p...CANONICAL MARINE AVIATION LOGISTICS SUPPORT PROGRAM II (MALSP II) DEPLOYMENT by Brian M. Bagley June 2015 Thesis Advisor: Chad W. Seagren...3. REPORT TYPE AND DATES COVERED Master’s Thesis 4. TITLE AND SUBTITLE DEVELOPMENT OF CANONICAL MARINE AVIATION LOGISTICS SUPPORT PROGRAM II

  15. STELLAR POPULATIONS AND THE STAR FORMATION HISTORIES OF LOW SURFACE BRIGHTNESS GALAXIES. II. H II REGIONS

    Energy Technology Data Exchange (ETDEWEB)

    Schombert, James [Department of Physics, University of Oregon, Eugene, OR 97403 (United States); McGaugh, Stacy [Department of Astronomy, Case Western Reserve University, Cleveland, OH 44106 (United States); Maciel, Tamela, E-mail: jschombe@uoregon.edu, E-mail: stacy.mcgaugh@case.edu, E-mail: tm419@cam.ac.uk [Department of Physics, Cambridge University, Cambridge (United Kingdom)

    2013-08-01

    The luminosities, colors, and H{alpha} emission for 429 H II regions in 54 low surface brightness (LSB) galaxies are presented. While the number of H II regions per galaxy is lower in LSB galaxies compared to star-forming irregulars and spirals, there is no indication that the size or luminosity function of H II regions differs from other galaxy types. The lower number of H II regions per galaxy is consistent with their lower total star formation rates. The fraction of the total L{sub H{alpha}} contributed by H II regions varies from 10% to 90% in LSB galaxies (the rest of the H{alpha} emission being associated with a diffuse component) with no correlation with galaxy stellar or gas mass. Bright H II regions have bluer colors, similar to the trend in spirals; their number and luminosities are consistent with the hypothesis that they are produced by the same H II luminosity function as spirals. Comparison with stellar population models indicates that the brightest H II regions in LSB galaxies range in cluster mass from a few 10{sup 3} M{sub Sun} (e.g., {rho} Oph) to globular-cluster-sized systems (e.g., 30 Dor) and that their ages are consistent with clusters from 2 to 15 Myr old. The faintest H II regions are comparable to those in the LMC powered by a single O or B star. Thus, star formation in LSB galaxies covers the full range of stellar cluster mass.

  16. [C II] and [N II] from dense ionized regions in the Galaxy

    CERN Document Server

    Langer, W D; Pineda, J L

    2016-01-01

    The interstellar medium (ISM) consists of highly ionized and neutral atomic, as well as molecular, components. Knowledge of their distribution is important for tracing the structure and lifecycle of the ISM. Here we determine the properties of the highly ionized and neutral weakly ionized gas in the Galaxy traced by the fine-structure lines of ionized nitrogen, [N II], and ionized carbon, [C II]. To analyze the ionized ISM we utilize [C II] 158 micron and [N II] 205 micron lines taken with the high spectral resolution Heterodyne Instrument in the Far-Infrared (HIFI) on the Herschel Space Observatory along ten lines of sight towards the inner Galaxy. [N II] emission can be used to estimate the contribution of the highly ionized gas to the [C II] emission and separate the highly ionized and weakly ionized neutral gas. We find that [N II] has strong emission in distinct spectral features along all lines of sight associated with strong [C II] emission. The [N II] arises from moderate density extended HII regions ...

  17. Part I: Sound color in the music of Gyorgy Kurtag, Part II: "Leopard's Path," thirteen visions for chamber ensemble

    Science.gov (United States)

    Iachimciuc, Igor

    The dissertation is in two parts, a theoretical study and a musical composition. In Part I the music of Gyorgy Kurtag is analyzed from the point of view of sound color. A brief description of what is understood by the term sound color, and various ways of achieving specific coloristic effects, are presented in the Introduction. An examination of Kurtag's approaches to the domain of sound color occupies the chapters that follow. The musical examples that are analyzed are selected from Kurtag's different compositional periods, showing a certain consistency in sound color techniques, the most important of which are already present in the String Quartet, Op. 1. The compositions selected for analysis are written for different ensembles, but regardless of the instrumentation, certain principles of the formation and organization of sound color remain the same. Rather than relying on extended instrumental techniques, Kurtag creates a large variety of sound colors using traditional means such as pitch material, register, density, rhythm, timbral combinations, dynamics, texture, spatial displacement of the instruments, and the overall musical context. Each sound color unit in Kurtag's music is a separate entity, conceived as a complete microcosm. Sound color units can either be juxtaposed as contrasting elements, forming sound color variations, or superimposed, often resulting in a Klangfarbenmelodie effect. Some of the same gestural figures (objets trouves) appear in different compositions, but with significant coloristic modifications. Thus, the principle of sound color variations is not only a strong organizational tool, but also a characteristic stylistic feature of the music of Gyorgy Kurtag. Part II, Leopard's Path (2010), for flute, clarinet, violin, cello, cimbalom, and piano, is an original composition inspired by the painting of Jesse Allen, a San Francisco based artist. The composition is conceived as a cycle of thirteen short movements. Ten of these movements are

  18. Electrochemical studies of DNA interaction and antimicrobial activities of MnII, FeIII, CoII and NiII Schiff base tetraazamacrocyclic complexes

    Science.gov (United States)

    Kumar, Anuj; Vashistha, Vinod Kumar; Tevatia, Prashant; Singh, Randhir

    2017-04-01

    Tetraazamacrocyclic complexes of MnII, FeIII, CoII and NiII have been synthesized by template method. These tetraazamacrocycles have been analyzed with various techniques like molar conductance, IR, UV-vis, mass spectral and cyclic voltammetric studies. On the basis of all these studies, octahedral geometry has been assigned to these tetraazamacrocyclic complexes. The DNA binding properties of these macrocyclic complexes have been investigated by electronic absorption spectra, fluorescence spectra, cyclic voltammetric and differential pulse voltammetric studies. The cyclic voltammetric data showed that ipc and ipa were effectively decreased in the presence of calf thymus DNA, which is a strong evidence for the interaction of these macrocyclic complexes with the calf thymus DNA (ct-DNA). The heterogeneous electron transfer rate constant found in the order: KCoII > KNiII > KMnII which indicates that CoII macrocyclic complex has formed a strong intercalated intermediate. The Stern-Volmer quenching constant (KSV) and voltammetric binding constant were found in the order KSV(CoII) > KSV(NiII) > KSV(MnII) and K+(CoII) > K+(NiII) > K+(MnII) which shows that CoII macrocyclic complex exhibits the high interaction affinity towards ct-DNA by the intercalation binding. Biological studies of the macrocyclic complexes compared with the standard drug like Gentamycin, have shown antibacterial activities against E. coli, P. aeruginosa, B. cereus, S. aureus and antifungal activity against C. albicans.

  19. Relativistic Hotspots in FR II Radio Sources

    Science.gov (United States)

    Chartrand, Alex M.; Miller, B. P.; Brandt, W. N.; Gawronski, M. P.; Cederbloom, S. E.

    2011-01-01

    We present a list of six FR II radio sources that are candidates to possess hotspots with modestly relativistic (v/c > 0.2) bulk velocities, in contrast to the vast majority of FR II radio sources that possess non-relativistic hotspot bulk velocities (e.g., v/c = 0.03+/- 0.02 from Scheuer 1995). These objects display arm- length and flux-ratio asymmetries between lobes that self-consistently indicate relativistic motion. The candidates are selected from the FIRST 1.4 GHz survey (including but not limited to the catalog of FR II quasars of de Vries et al. 2006) with the requirement that the radio core have a spectroscopic SDSS counterpart. We find no significant difference in the number of neighboring sources within 300 projected kpc of the candidate sources and randomly selected nearby regions. The deprojected and light travel-time corrected lobe distances are not abnormal for FR II sources, and neither are the core-to-lobe flux ratios after correcting for lobe beaming. We briefly consider four possibilities for these type of objects: (i) environmental interactions randomly mimicking relativistic effects, (ii) a restarted jet causing the near hotspot to brighten while the far hotspot still appears faint, (iii) observation during a short interval common to FR II lifetimes during which the hotspot decelerates from relativistic to non-relativistic velocities, and (iv) innately unusual characteristics (e.g., a mass-loaded jet) driving relativistic bulk velocities in the hotspots of a small fraction (< 1%) of FR II objects. We favor the last interpretation but cannot rule out the alternatives. We also comment on the useful external constraints such objects provide to the evaluation of hotspot X-ray emission mechanisms.

  20. Selective Hg(II) adsorption from aqueous solutions of Hg(II) and Pb(II) by hydrolyzed acrylamide-grafted PET films.

    Science.gov (United States)

    Rahman, Nazia; Sato, Nobuhiro; Sugiyama, Masaaki; Hidaka, Yoshiki; Okabe, Hirotaka; Hara, Kazuhiro

    2014-01-01

    Selective Hg(II) adsorption from aqueous solutions of Hg(II) and Pb(II) using hydrolyzed acrylamide (AAm)-grafted polyethylene terephthalate (PET) films was examined to explore the potential reuse of waste PET materials. Selective recovery of Hg(II) from a mixture of soft acids with similar structure, such as Hg(II) and Pb(II), is important to allow the reuse of recovered Hg(II). An adsorbent for selective Hg(II) adsorption was prepared by γ-ray-induced grafting of AAm onto PET films followed by partial hydrolysis through KOH treatment. The adsorption capacity of the AAm-grafted PET films for Hg(II) ions increased from 15 to 70 mg/g after partial hydrolysis because of the reduction of hydrogen bonding between -CONH2 groups and the corresponding improved access of metal ions to the amide groups. The prepared adsorbent was characterized by Fourier transform infrared spectroscopy and scanning electron microscopy. The absorbent film showed high selectivity for the adsorption of Hg(II) over Pb(II) throughout the entire initial metal concentration range (100-500 mg/L) and pH range (2.2-5.6) studied. The high selectivity is attributed to the ability of Hg(II) ions to form covalent bonds with the amide groups. The calculated selectivity coefficient for the adsorbent binding Hg(II) over Pb(II) was 19.2 at pH 4.5 with an initial metal concentration of 100 mg/L. Selective Hg(II) adsorption equilibrium data followed the Langmuir model and kinetic data were well fitted by a pseudo-second-order equation. The adsorbed Hg(II) and Pb(II) ions were effectively desorbed from the adsorbent film by acid treatment, and the regenerated film showed no marked loss of adsorption capacity upon reuse for selective Hg(II) adsorption.