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Sample records for all-solid photonic bandgap

  1. Photonic bandgap confinement in an all-solid tellurite glass photonic crystal fiber

    OpenAIRE

    Lousteau, Joris; Mura, Emanuele; Milanese, Daniel; Boetti, Nadia Giovanna; Scarpignato, Gerardo Cristian

    2012-01-01

    We report on the fabrication and optical assessment of an all-solid tellurite-glass photonic bandgap fiber. The manufacturing process via a preform drawing approach and the fiber characterization procedures are described and discussed. The fiber exhibits some minor morphological deformations that do not prevent the observation of optical confinement within the fiber by bandgap effects. The experimental fiber attenuation spectrum displays clear bandgap confinement regions whose positions are c...

  2. Polarization Maintaining Hybrid TIR/Bandgap All-Solid Photonic Crystal Fiber

    DEFF Research Database (Denmark)

    Lyngsøe, Jens Kristian; Mangan, Brian J.; Roberts, John

    2008-01-01

    We report on fabricated all-solid fibers which guide by a combination of bandgap and TIR mechanisms. The fibers show high birefringence and possess a dispersion characteristic similar to the pure bandgap guiding form....

  3. 400-W near diffraction-limited single-frequency all-solid photonic bandgap fiber amplifier.

    Science.gov (United States)

    Pulford, Benjamin; Ehrenreich, Thomas; Holten, Roger; Kong, Fanting; Hawkins, Thomas W; Dong, Liang; Dajani, Iyad

    2015-05-15

    An ytterbium-doped large-mode area photonic bandgap fiber is used to demonstrate 400 W of single-frequency output at 1064 nm with excellent beam quality and minimal stimulated Brillouin scattering. The fiber possesses all-solid microstructures embedded in the cladding and a core composed of phosphosilicate with a diameter of ∼50  μm. As the signal power is pushed beyond 450 W, there is degradation in the beam quality due to the modal instability. We briefly discuss techniques to alleviate this problem in future designs. To the best of our knowledge, the 400-W single-frequency near diffraction-limited output far exceeds the current state-of-the-art from such type of fiber amplifier. PMID:26393723

  4. Photonic Bandgap Propagation in All-Solid Chalcogenide Microstructured Optical Fibers

    Directory of Open Access Journals (Sweden)

    Celine Caillaud

    2014-08-01

    Full Text Available An original way to obtain fibers with special chromatic dispersion and single-mode behavior is to consider microstructured optical fibers (MOFs. These fibers present unique optical properties thanks to the high degree of freedom in the design of their geometrical structure. In this study, the first all-solid all-chalcogenide MOFs exhibiting photonic bandgap transmission have been achieved and optically characterized. The fibers are made of an As38Se62 matrix, with inclusions of Te20As30Se50 glass that shows a higher refractive index (n = 2.9. In those fibers, several transmission bands have been observed in mid infrared depending on the geometry. In addition, for the first time, propagation by photonic bandgap effect in an all-chalcogenide MOF has been observed at 3.39 µm, 9.3 µm, and 10.6 µm. The numerical simulations based on the optogeometric properties of the fibers agree well with the experimental characterizations.

  5. Investigation on single taper-based all-solid photonic bandgap fiber modal interferometers.

    Science.gov (United States)

    Li, Jie; Geng, Mengmei; Sun, Li-Peng; Fan, Pengcheng; Liu, Bo; Guan, Bai-Ou

    2016-04-18

    We demonstrate a single taper-based all-solid photonic bandgap (AS-PBG) fiber modal interferometer that consists of a central tapered fiber region connected to the untapered via two abrupt transitions. Modal interference is given by superimposing the bandgap-guided fundamental core mode with a lower effective index and a specific index-guided cladding supermode with a higher effective index. A series of interferometers with taper diameter of 50μm ~60μm and device length of ~3mm are fabricated and studied in contrast to the conventional counterparts. The temperature coefficient of the interferometer is closely determined by the fraction of the cladding supermode energy localized within the index-raised regions of the fiber. The refractive index (RI) responsivities associated to fiber taper sizes are investigated. The measured maximal RI sensitivity is ~3512.36nm/RIU at the taper diameter of 50μm around RI = 1.423. This research gives a deep understanding to the modal-interferometric AS-PBG structure, which we believe to be valuable for the future application of the related device. PMID:27137292

  6. Characteristics of Bragg Gratings in All-Solid Photonic Bandgap Fiber

    Institute of Scientific and Technical Information of China (English)

    Bai-Ou Guan; Zhi Wang; Yang Zhang; Da Chen

    2008-01-01

    We report on fiber Bragg gratings in all-solid photonie bandgap fiber that was composed of a triangular array of high-index Ge-doped rods in pure silica background with fluorine-doped index-depressed layer surrounding the Ge-doped rod. Fiber Bragg gratings were photowritten with 193 nm ArF excimer laser and characterized for their response to strain, temperature, bending, and torsion. These gratings couple light from the forward core mode to not only backward core mode but also backward rod modes. This results in multiple resonance peaks in the reflection spectrum. All resonance wavelengths exhibited the same temperature and strain response with coefficient similar to that of Bragg gratings in standard single-mode fiber. The strength of the resonance peaks corresponding to the backward rod modes showed high sensitivity to bending and torsion.

  7. In-line Mach-Zehnder interferometer composed of microtaper and long-period grating in all-solid photonic bandgap fiber

    International Nuclear Information System (INIS)

    We report a compact in-line Mach-Zehnder interferometer combining a microtaper with a long-period grating (LPG) in a section of all-solid photonic bandgap fiber. Theoretical and experimental investigations reveal that the interferometer works from the interference between the fundamental core mode and the LP01 cladding supermodes. The mechanism underlying the mode coupling caused by the microtaper can be attributed to a bandgap-shifting as the fiber diameter is abruptly scaled down. In addition, the interferometer designed to strengthen the coupling ratio of the long-period grating has a promising practical application in the simultaneous measurement of curvature and temperature.

  8. Photonic Bandgap Fibers

    DEFF Research Database (Denmark)

    Barkou, Stig Eigil; Broeng, Jes; Bjarklev, Anders Overgaard

    1999-01-01

    Photonic bandgap fibers are describes using a new Kagomé cladding structure. These fibers may potentially guide light in low-index regions. Such fibers offer new dispersion properties, and large design flexibility.......Photonic bandgap fibers are describes using a new Kagomé cladding structure. These fibers may potentially guide light in low-index regions. Such fibers offer new dispersion properties, and large design flexibility....

  9. Photonic Bandgap (PBG) Shielding Technology

    Science.gov (United States)

    Bastin, Gary L.

    2007-01-01

    Photonic Bandgap (PBG) shielding technology is a new approach to designing electromagnetic shielding materials for mitigating Electromagnetic Interference (EM!) with small, light-weight shielding materials. It focuses on ground planes of printed wiring boards (PWBs), rather than on components. Modem PSG materials also are emerging based on planar materials, in place of earlier, bulkier, 3-dimensional PBG structures. Planar PBG designs especially show great promise in mitigating and suppressing EMI and crosstalk for aerospace designs, such as needed for NASA's Constellation Program, for returning humans to the moon and for use by our first human visitors traveling to and from Mars. Photonic Bandgap (PBG) materials are also known as artificial dielectrics, meta-materials, and photonic crystals. General PBG materials are fundamentally periodic slow-wave structures in I, 2, or 3 dimensions. By adjusting the choice of structure periodicities in terms of size and recurring structure spacings, multiple scatterings of surface waves can be created that act as a forbidden energy gap (i.e., a range of frequencies) over which nominally-conductive metallic conductors cease to be a conductor and become dielectrics. Equivalently, PBG materials can be regarded as giving rise to forbidden energy gaps in metals without chemical doping, analogous to electron bandgap properties that previously gave rise to the modem semiconductor industry 60 years ago. Electromagnetic waves cannot propagate over bandgap regions that are created with PBG materials, that is, over frequencies for which a bandgap is artificially created through introducing periodic defects

  10. Polarization properties of photonic bandgap fibers

    DEFF Research Database (Denmark)

    Broeng, Jes; Libori, Stig E. Barkou; Bjarklev, Anders Overgaard

    2000-01-01

    We present the first analysis of polarization properties of photonic bandgap fibers. Strong birefringence may be obtained for modest non-uniformities in and around the core region, suggesting the use of photonic bandgap fibers as polarization maintaining components.......We present the first analysis of polarization properties of photonic bandgap fibers. Strong birefringence may be obtained for modest non-uniformities in and around the core region, suggesting the use of photonic bandgap fibers as polarization maintaining components....

  11. Photonic bandgap structures

    CERN Document Server

    Marco, Pisco; Antonello, Cutolo

    2012-01-01

    This E-Book covers the research and the development of a novel generation of photonic devices for sensing applications. Key features of this book include a brief review of basic PhCs related design and fabrication concepts, a selection of crossover topics for the development of novel technological platforms for physical, chemical and biological sensing and a description of the main PhCs sensors to date by representing many of the exciting sensing applications that utilize photonic crystal structures.

  12. Surface state photonic bandgap cavities

    OpenAIRE

    Rahachou, A. I.; Zozoulenko, I. V.

    2005-01-01

    We propose and analyze a new type of a resonant high-Q cavity for lasing, sensing or filtering applications, which is based on a surface states of a finite photonic crystal. We demonstrate that such the cavity can have a Q factor comparable with that one of conventional photonic band-gap defect mode cavities. At the same time, the distinguished feature of the surface mode cavity is that it is situated directly at the surface of the photonic crystal. This might open up new possibilities for de...

  13. Photonic bandgap fiber bundle spectrometer

    CERN Document Server

    Hang, Qu; Syed, Imran; Guo, Ning; Skorobogatiy, Maksim

    2010-01-01

    We experimentally demonstrate an all-fiber spectrometer consisting of a photonic bandgap fiber bundle and a black and white CCD camera. Photonic crystal fibers used in this work are the large solid core all-plastic Bragg fibers designed for operation in the visible spectral range and featuring bandgaps of 60nm - 180nm-wide. 100 Bragg fibers were chosen to have complimentary and partially overlapping bandgaps covering a 400nm-840nm spectral range. The fiber bundle used in our work is equivalent in its function to a set of 100 optical filters densely packed in the area of ~1cm2. Black and white CCD camera is then used to capture spectrally "binned" image of the incoming light at the output facet of a fiber bundle. To reconstruct the test spectrum from a single CCD image we developed an algorithm based on pseudo-inversion of the spectrometer transmission matrix. We then study resolution limit of this spectroscopic system by testing its performance using spectrally narrow test peaks (FWHM 5nm-25nm) centered at va...

  14. High sensitivity high temperature sensor based on SMS structure with large-core all-solid bandgap fiber as the multimode section

    Science.gov (United States)

    Franco, Marcos A. R.; Cruz, Alice L. S.; Serrão, Valdir A.; Barbosa, Carmem L.

    2014-05-01

    A fiber optic interferometric device based on a singlemode-multimode-singlemode (SMS) structure is proposed as a high sensitive high temperature sensor. The multimode section (MMF) consists of a large-core all-solid photonic bandgap fiber (AS-PBF) with silica as the background material and germanium-doped silica at the high index regions. The numerical analyses were carried out by beam propagation method. The numerical results indicate a constant high temperature sensitivity of ~-35 pm/°C over a large temperature range from 20oC to 930°C.

  15. Actively doped solid core Photonic Bandgap Fiber

    DEFF Research Database (Denmark)

    Broeng, Jes; Olausson, Christina Bjarnal Thulin; Lyngsøe, Jens Kristian;

    2010-01-01

    Solid photonic bandgap fibers offer distributed spectral filtering with extraordinary high suppression. This opens new possibilities of artificially tailoring the gain spectrum of fibers. We present record-performance of such fibers and outline their future applications....

  16. Air-guiding Photonic Bandgap Fibers

    DEFF Research Database (Denmark)

    Hansen, Theis Peter

    2005-01-01

    Photonic bandgap fibers that guide light in an air core have attracted much interest since their first demonstration in 1999. The prospect of low-loss guiding of light in air has importance for a multitude of applications, such as data transmission, gas sensors, dispersion compensation and guiding...

  17. Advances in photonic bandgap fiber functionality

    DEFF Research Database (Denmark)

    Lyngsøe, Jens Kristian

    In order to take advantage of the many intriguing optical properties of photonic bandgap fibers, there are some technological challenges that have to be addressed. Among other things this includes transmission loss and the fibers ability to maintain field polarization. The work presented in this ...

  18. Gaussian Filtering with Tapered Liquid Crystal Photonic Bandgap Fibers

    DEFF Research Database (Denmark)

    Scolari, Lara; Alkeskjold, Thomas Tanggaard; Bjarklev, Anders Overgaard

    2006-01-01

    We present a device based on a tapered Liquid Crystal Photonic Bandgap Fiber that allows active all-in-fiber filtering. The resulting Photonic Bandgap Fiber device provides a Gaussian filter covering the wavelength range 1200-1600 nm......We present a device based on a tapered Liquid Crystal Photonic Bandgap Fiber that allows active all-in-fiber filtering. The resulting Photonic Bandgap Fiber device provides a Gaussian filter covering the wavelength range 1200-1600 nm...

  19. A plasma photonic crystal bandgap device

    Science.gov (United States)

    Wang, B.; Cappelli, M. A.

    2016-04-01

    A fully tunable plasma photonic crystal is used to control the propagation of free space electromagnetic waves in the S to X bands of the microwave spectrum. An array of discharge plasma tubes forms a simple square crystal structure with the individual plasma dielectric constant tuned through variation in the plasma density. We show, through simulations and experiments, that transverse electric mode bandgaps exist, arising from the positive and negative dielectric constant regimes of the plasma, and that the respective bandgap frequencies can be shifted through changing the dielectric constant by varying discharge current density.

  20. Advances in Solid Core Photonic Bandgap Fiber Amplifiers

    DEFF Research Database (Denmark)

    Alkeskjold, Thomas Tanggaard; Laurila, Marko; Petersen, Sidsel Rübner;

    2012-01-01

    We present recent development of photonic crystal fiber amplifiers containing photonic bandgap structures for enhanced spectral and modal filtering functionality.......We present recent development of photonic crystal fiber amplifiers containing photonic bandgap structures for enhanced spectral and modal filtering functionality....

  1. Extending of flat normal dispersion profile in all-solid soft glass nonlinear photonic crystal fibres

    Science.gov (United States)

    Siwicki, Bartłomiej; Kasztelanic, Rafał; Klimczak, Mariusz; Cimek, Jarosław; Pysz, Dariusz; Stępień, Ryszard; Buczyński, Ryszard

    2016-06-01

    The bandwidth of coherent supercontinuum generated in optical fibres is strongly determined by the all-normal dispersion characteristic of the fibre. We investigate all-normal dispersion limitations in all-solid oxide-based soft glass photonic crystal fibres with various relative inclusion sizes and lattice constants. The influence of material dispersion on fibre dispersion characteristics for a selected pair of glasses is also examined. A relation between the material dispersion of the glasses and the fibre dispersion has been described. We determined the parameters which limit the maximum range of flattened all-normal dispersion profile achievable for the considered pair of heavy-metal-oxide soft glasses.

  2. Jacquard-woven photonic bandgap fiber displays

    CERN Document Server

    Sayed, Imran; Skorobogatiy, Maksim

    2010-01-01

    We present an overview of photonic textile displays woven on a Jacquard loom, using newly discovered polymer photonic bandgap fibers that have the ability to change color and appearance when illuminated with ambient or transmitted light. The photonic fiber can be thin (smaller than 300 microns in diameter) and highly flexible, which makes it possible to weave in the weft on a computerized Jacquard loom and develop intricate double weave structures together with a secondary weft yarn. We demonstrate how photonic crystal fibers enable a variety of color and structural patterns on the textile, and how dynamic imagery can be created by balancing the ambient and emitted radiation. Finally, a possible application in security ware for low visibility conditions is described as an example.

  3. A new photonic bandgap cover for a patch antenna with a photonic bandgap substrate

    Institute of Scientific and Technical Information of China (English)

    林青春; 朱方明; 何赛灵

    2004-01-01

    A new photonic bandgap (PBG) cover for a patch antenna with a photonic bandgap substrate is introduced. The plane wave expansion method and the FDTD method were used to calculate such an antenna system. Numerical results for the input return loss, radiation pattern, surface wave, and the directivity of the antennas are presented. A comparison between the conventional patch antenna and the new PBG antenna is given. It is shown that the new PBG cover is very efficient for improving the radiation directivity. The physical reasons for the improvement are also given.

  4. Hybrid photonic-bandgap accelerating cavities

    CERN Document Server

    Di Gennaro, E; Savo, S; Andreone, A; Masullo, M R; Castaldi, G; Gallina, I; Galdi, V

    2009-01-01

    In a recent investigation, we studied two-dimensional point-defected photonic bandgap cavities composed of dielectric rods arranged according to various representative periodic and aperiodic lattices, with special emphasis on possible applications to particle acceleration (along the longitudinal axis). In this paper, we present a new study aimed at highlighting the possible advantages of using hybrid structures based on the above dielectric configurations, but featuring metallic rods in the outermost regions, for the design of extremely-high quality factor, bandgap-based, accelerating resonators. In this framework, we consider diverse configurations, with different (periodic and aperiodic) lattice geometries, sizes, and dielectric/metal fractions. Moreover, we also explore possible improvements attainable via the use of superconducting plates to confine the electromagnetic field in the longitudinal direction. Results from our comparative studies, based on numerical full-wave simulations backed by experimental...

  5. Modeling of realistic cladding structures for photonic bandgap fibers

    DEFF Research Database (Denmark)

    Mortensen, Niels Asger; Nielsen, Martin Dybendal

    2004-01-01

    Cladding structures of photonic bandgap fibers often have airholes of noncircular shape, and, typically, close-to-hexagonal airholes with curved corners are observed. We study photonic bandgaps in such structures by aid of a two-parameter representation of the size and curvature. For the fundamen......Cladding structures of photonic bandgap fibers often have airholes of noncircular shape, and, typically, close-to-hexagonal airholes with curved corners are observed. We study photonic bandgaps in such structures by aid of a two-parameter representation of the size and curvature. For the...... fundamental bandgap we find that the bandgap edges (the intersections with the air line) shift toward shorter wavelengths when the air-filling fraction f is increased. The bandgap also broadens, and the relative bandwidth increases exponentially with f2. Compared with recent experiments [Nature 424, 657 (2003...

  6. Highly dispersive photonic band-gap prism

    International Nuclear Information System (INIS)

    We propose the concept of a photonic band-gap (PBG) prism based on two-dimensional PBG structures and realize it in the millimeter-wave spectral regime. We recognize the highly nonlinear dispersion of PBG materials near Brillouin zone edges and utilize the dispersion to achieve strong prism action. Such a PBG prism is very compact if operated in the optical regime, ∼20μm in size for λ∼700nm, and can serve as a dispersive element for building ultracompact miniature spectrometers. copyright 1996 Optical Society of America

  7. Highly dispersive photonic band-gap prism.

    Science.gov (United States)

    Lin, S Y; Hietala, V M; Wang, L; Jones, E D

    1996-11-01

    We propose the concept of a photonic band-gap (PBG) prism based on two-dimensional PBG structures and realize it in the millimeter-wave spectral regime. We recognize the highly nonlinear dispersion of PBG materials near Brillouin zone edges and utilize the dispersion to achieve strong prism action. Such a PBG prism is very compact if operated in the optical regime, ~20 mm in size for lambda ~ 700 nm, and can serve as a dispersive element for building ultracompact miniature spectrometers. PMID:19881796

  8. All-solid-state deep ultraviolet laser for single-photon ionization mass spectrometry

    Science.gov (United States)

    Yuan, Chengqian; Liu, Xianhu; Zeng, Chenghui; Zhang, Hanyu; Jia, Meiye; Wu, Yishi; Luo, Zhixun; Fu, Hongbing; Yao, Jiannian

    2016-02-01

    We report here the development of a reflectron time-of-flight mass spectrometer utilizing single-photon ionization based on an all-solid-state deep ultraviolet (DUV) laser system. The DUV laser was achieved from the second harmonic generation using a novel nonlinear optical crystal KBe2BO3F2 under the condition of high-purity N2 purging. The unique property of this laser system (177.3-nm wavelength, 15.5-ps pulse duration, and small pulse energy at ˜15 μJ) bears a transient low power density but a high single-photon energy up to 7 eV, allowing for ionization of chemicals, especially organic compounds free of fragmentation. Taking this advantage, we have designed both pulsed nanospray and thermal evaporation sources to form supersonic expansion molecular beams for DUV single-photon ionization mass spectrometry (DUV-SPI-MS). Several aromatic amine compounds have been tested revealing the fragmentation-free performance of the DUV-SPI-MS instrument, enabling applications to identify chemicals from an unknown mixture.

  9. Liquid Crystals and Photonic Bandgap Fiber Components

    DEFF Research Database (Denmark)

    Weirich, Johannes; Wei, Lei; Scolari, Lara;

    Liquid Crystal(LC)filled Photonic Crystal Fibers(PCFs) represent a promising platform for the design and the fabrication of tunable all-in fiber devices. Tunability is achieved by varying the refractive index of the LC thermally, optically or electrically. In this contribution we present important...... parts of the LC theory as well as an application of a LC infiltrated PCF subject to an external electrostatic field. The fiber is placed between two electrodes and the voltage is increased step by step leading to the reorientation of the LC in the fiber capillaries. This mechanism can be used to produce...... a swichable polarizer, and an on chip LC photonic bandgap fiber polarimeter is presented, which admits strong attenuation of one polarization direction while the other one is nearly unaffected....

  10. Electrically tunable liquid crystal photonic bandgap fiber laser

    DEFF Research Database (Denmark)

    Olausson, Christina Bjarnal Thulin; Scolari, Lara; Wei, Lei;

    2010-01-01

    We demonstrate electrical tunability of a fiber laser by using a liquid crystal photonic bandgap fiber. Tuning of the laser is achieved by combining the wavelength filtering effect of a liquid crystal photonic bandgap fiber device with an ytterbium-doped photonic crystal fiber. We fabricate an all......-spliced laser cavity based on a liquid crystal photonic bandgap fiber mounted on a silicon assembly, a pump/signal combiner with single-mode signal feed-through and an ytterbium-doped photonic crystal fiber. The laser cavity produces a single-mode output and is tuned in the range 1040-1065nm by applying...

  11. Hybrid photonic-bandgap accelerating cavities

    Energy Technology Data Exchange (ETDEWEB)

    Di Gennaro, E [CNISM and Department of Physics, University of Naples ' Federico II' , Naples (Italy); Zannini, C; Savo, S; Andreone, A [CNR-INFM ' Coherentia' and Department of Physics, University of Naples ' Federico II' , Naples (Italy); Masullo, M R [INFN-Naples Unit, Naples (Italy); Castaldi, G; Gallina, I; Galdi, V [Waves Group, Department of Engineering, University of Sannio, Benevento (Italy)], E-mail: masullo@na.infn.it

    2009-11-15

    In a recent investigation, we studied two-dimensional (2D) point-defected photonic bandgap cavities composed of dielectric rods arranged according to various representative periodic and aperiodic lattices, with special emphasis on possible applications to particle acceleration (along the longitudinal axis). In this paper, we present a new study aimed at highlighting the possible advantages of using hybrid structures based on the above dielectric configurations, but featuring metallic rods in the outermost regions, for the design of extremely high quality factor, bandgap-based, accelerating resonators. In this framework, we consider diverse configurations, with different (periodic and aperiodic) lattice geometries, sizes and dielectric/metal fractions. Moreover, we also explore possible improvements attainable via the use of superconducting plates to confine the electromagnetic field in the longitudinal direction. Results from our comparative studies, based on numerical full-wave simulations backed by experimental validations (at room and cryogenic temperatures) in the microwave region, identify the candidate parametric configurations capable of yielding the highest quality factor.

  12. Hybrid photonic-bandgap accelerating cavities

    Science.gov (United States)

    Di Gennaro, E.; Zannini, C.; Savo, S.; Andreone, A.; Masullo, M. R.; Castaldi, G.; Gallina, I.; Galdi, V.

    2009-11-01

    In a recent investigation, we studied two-dimensional (2D) point-defected photonic bandgap cavities composed of dielectric rods arranged according to various representative periodic and aperiodic lattices, with special emphasis on possible applications to particle acceleration (along the longitudinal axis). In this paper, we present a new study aimed at highlighting the possible advantages of using hybrid structures based on the above dielectric configurations, but featuring metallic rods in the outermost regions, for the design of extremely high quality factor, bandgap-based, accelerating resonators. In this framework, we consider diverse configurations, with different (periodic and aperiodic) lattice geometries, sizes and dielectric/metal fractions. Moreover, we also explore possible improvements attainable via the use of superconducting plates to confine the electromagnetic field in the longitudinal direction. Results from our comparative studies, based on numerical full-wave simulations backed by experimental validations (at room and cryogenic temperatures) in the microwave region, identify the candidate parametric configurations capable of yielding the highest quality factor.

  13. Hybrid photonic-bandgap accelerating cavities

    International Nuclear Information System (INIS)

    In a recent investigation, we studied two-dimensional (2D) point-defected photonic bandgap cavities composed of dielectric rods arranged according to various representative periodic and aperiodic lattices, with special emphasis on possible applications to particle acceleration (along the longitudinal axis). In this paper, we present a new study aimed at highlighting the possible advantages of using hybrid structures based on the above dielectric configurations, but featuring metallic rods in the outermost regions, for the design of extremely high quality factor, bandgap-based, accelerating resonators. In this framework, we consider diverse configurations, with different (periodic and aperiodic) lattice geometries, sizes and dielectric/metal fractions. Moreover, we also explore possible improvements attainable via the use of superconducting plates to confine the electromagnetic field in the longitudinal direction. Results from our comparative studies, based on numerical full-wave simulations backed by experimental validations (at room and cryogenic temperatures) in the microwave region, identify the candidate parametric configurations capable of yielding the highest quality factor.

  14. Novel 1-D Sandwich Photonic Bandgap Structure

    Institute of Scientific and Technical Information of China (English)

    庞云波; 高葆新

    2004-01-01

    A sandwich photonic bandgap (PBG) structure is a novel PBG structure whose periodic lattice is buried in the middle of a substrate. Neither drilling nor suspending the substrate is required, and the integrity of the ground plane is maintained. This paper presents several modification techniques for sandwich PBG structure fabrication. The forbidden gap can be improved by adopting the chirping technique, applying the tapering technique, enlarging the periodic elements, adjusting the location of the periodic lattice in the substrate, and using different dielectric media H-shape elements. A finite difference time domain method is applied to analyze the structures. Deep and wide stopbands can be obtained using the modified sandwich structures. Experimental measurement results agree well with the theoretical analysis.

  15. Main Factors for Affecting Photonic Bandgap of Photonic Crystals

    Institute of Scientific and Technical Information of China (English)

    LI Xia; XUE Wei; JIANG Yu-rong; YU Zhi-nong; WANG Hua-qing

    2007-01-01

    The factors affecting one dimensional (1D) and two dimensional (2D) photonic crystals (PhCs) are systemically analyzed in this paper by numerical simulation.Transfer matrix method (TMM) is employed for 1D PCs, both finite difference time domain method (FDTD) and plane wave expansion method (PWE) are employed for 2D PCs.The result shows that the photonic bandgaps (PBG) are directly affected by crystal type, crystal lattice constant, modulation of refractive index and periodicity, and it is should be useful for design of different type photonic crystals with the required PBG and functional devices.Finally, as an example, a near-IR 1D PCs narrow filter was designed.

  16. All-solid birefringent hybrid photonic crystal fiber based interferometric sensor for measurement of strain and temperature

    DEFF Research Database (Denmark)

    Gu, Bobo; Yuan, Scott Wu; Zhang, A. Ping;

    2011-01-01

    A highly sensitive fiber-optic interferometric sensor based on an all-solid birefringent hybrid photonic crystal fiber (PCF) is demonstrated for measuring strain and temperature. A strain sensitivity of similar to 23.8 pm/mu epsilon and a thermal sensitivity of similar to-1.12 nm/degrees C are...

  17. Large-area single-mode photonic bandgap vcsels

    DEFF Research Database (Denmark)

    Birkedal, Dan; Gregersen, N.; Bischoff, S.; Madsen, M.; Romstad, F.; Oestergaard, J.

    We demonstrate that the photonic bandgap effect can be used to control the modes of large area vertical cavity surface emitting lasers. We obtain more than 20 dB side mode suppression ratios in a 10-micron area device.......We demonstrate that the photonic bandgap effect can be used to control the modes of large area vertical cavity surface emitting lasers. We obtain more than 20 dB side mode suppression ratios in a 10-micron area device....

  18. Thermal tunability of photonic bandgaps in liquid crystal filled polymer photonic crystal fiber

    Science.gov (United States)

    Wang, Doudou; Chen, Guoxiang; Wang, Lili

    2016-05-01

    A highly tunable bandgap-guiding polymer photonic crystal fiber is designed by infiltrating the cladding air holes with liquid crystal 5CB. Structural parameter dependence and thermal tunability of the photonic bandgaps, mode properties and confinement losses of the designed fiber are investigated. Bandgaps red shift as the temperature goes up. Average thermal tuning sensitivity of 30.9 nm/°C and 20.6 nm/°C is achieved around room temperature for the first and second photonic bandgap, respectively. Our results provide theoretical references for applications of polymer photonic crystal fiber in sensing and tunable fiber-optic devices.

  19. High-power narrow-linewidth large mode area photonic bandgap fiber amplifier

    Science.gov (United States)

    Pulford, Benjamin; Dajani, Iyad; Ehrenreich, Thomas; Holten, Roger; Vergien, Christopher; Naderi, Nader; Mart, Cody; Gu, Guancheng; Kong, Fanting; Hawkins, Thomas; Dong, Liang

    2015-03-01

    Ytterbium-doped large mode area all-solid photonic bandgap fiber amplifiers were used to demonstrate power at 1064 nm. In an initial set of experiments, a fiber with a core diameter of ~50 μm, and a calculated effective area of 1450 μm2 in a straight fiber, was used to generate approximately 600 W. In this case, the input seed was modulated using a sinusoidal format at a frequency of 400 MHz. The output, however, was multimode as the fiber design did not allow for single-mode operation at this wavelength. A second fiber was then fabricated to operate predominantly in single mode at 1064 nm by having the seed closer to the short wavelength edge of the bandgap. This fiber was used to demonstrate 400 W of single-frequency output with excellent beam quality. As the signal power exceeded 450 W, there was significant degradation in the beam quality due to the modal instability. Nevertheless, to the best of our knowledge, the power scaling results obtained in this work far exceed results from prior state of the art all-solid photonic bandgap fiber lasers.

  20. Effect of Dielectric Constant Contrast and Filling Factor to Photonic Bandgap

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    The effect of dielectric constant contrast and the filling factor to the photonic bandgap in a 2-D square lattice photonic crystal is discussed. The location, width and number of photonic bandgap can be modulated.

  1. Properties of photonic bandgap in one-dimensional multicomponent photonic crystal

    Institute of Scientific and Technical Information of China (English)

    ZHANG Yi; WANG Qi

    2006-01-01

    Properties of photonic band gap and light propagation in one-dimensional multicomponent photonic crystal have been studied with the optical transfer matrix method.We mainly analyze the relation of photonic band-gap property with the arrangement of components,the refractive index and the geometrical thickness.In this study,the methods to change the width and the location of the existing photonic band-gaps in multicomponent photonic crystal are proposed.

  2. High-Efficiency Solar Cells Using Photonic-Bandgap Materials

    Science.gov (United States)

    Dowling, Jonathan; Lee, Hwang

    2005-01-01

    Solar photovoltaic cells would be designed to exploit photonic-bandgap (PBG) materials to enhance their energy-conversion efficiencies, according to a proposal. Whereas the energy-conversion efficiencies of currently available solar cells are typically less than 30 percent, it has been estimated that the energy-conversion efficiencies of the proposed cells could be about 50 percent or possibly even greater. The primary source of inefficiency of a currently available solar cell is the mismatch between the narrow wavelength band associated with the semiconductor energy gap (the bandgap) and the broad wavelength band of solar radiation. This mismatch results in loss of power from both (1) long-wavelength photons, defined here as photons that do not have enough energy to excite electron-hole pairs across the bandgap, and (2) short-wavelength photons, defined here as photons that excite electron- hole pairs with energies much above the bandgap. It follows that a large increase in efficiency could be obtained if a large portion of the incident solar energy could be funneled into a narrow wavelength band corresponding to the bandgap. In the proposed approach, such funneling would be effected by use of PBG materials as intermediaries between the Sun and photovoltaic cells.

  3. All-solid-state cavity QED using Anderson-localized modes in disordered photonic crystal waveguides

    DEFF Research Database (Denmark)

    Lodahl, Peter; Sapienza, Luca; Nielsen, Henri Thyrrestrup;

    2010-01-01

    We employ Anderson-localized modes in deliberately disordered photonic crystal waveguides to confine light and enhance the interaction with matter. A 15-fold enhancement of the decay rate of a single quantum dot is observed meaning that 94% of the emitted single photons are coupled to an Anderson...

  4. Large-mode-area single-mode-output Neodymium-doped silicate glass all-solid photonic crystal fiber

    OpenAIRE

    Wentao Li; Danping Chen; Zhou Qinling; Lili Hu

    2015-01-01

    We have demonstrated a 45 μm core diameter Neodymium-doped all-solid silicate glass photonic crystal fiber laser with a single mode laser output. The structure parameters and modes information of the fiber are both demonstrated by theoretical calculations using Finite Difference Time Domain (FDTD) method and experimental measurements. Maximum 0.8 W output power limited by launched pump power has been generated in 1064 nm with laser beam quality factor M2 1.18.

  5. Temperature Compensated Strain Sensor Based on Cascaded Sagnac Interferometers and All-Solid Birefringent Hybrid Photonic Crystal Fibers

    DEFF Research Database (Denmark)

    Gu, Bobo; Yuan, Wu; He, Sailing;

    2012-01-01

    We demonstrate a temperature compensated strain sensor with two cascaded Sagnac interferometers, that provide strain sensing and temperature compensation, respectively. The Sagnac interferometers use an all-solid hybrid photonic crystal fiber with stress-induced birefringence. The stress......-induced birefringent fiber is known to offer the maximum strain sensitivity, but also to suffer from temperature crosstalk. Our experimental results show that the cascaded Sagnac sensor can suppress the crosstalk to a temperature upto 0.33 με/ºC, while still providing a high strain sensitivity of ~25.6 pm}/με....

  6. Optically controlled photonic bandgap structures for microstrip circuits

    CERN Document Server

    Cadman, D A

    2003-01-01

    This thesis is concerned with the optical control of microwave photonic bandgap circuits using high resistivity silicon. Photoconducting processes that occur within silicon are investigated. The influence of excess carrier density on carrier mobility and lifetime is examined. In addition, electron-hole pair recombination mechanisms (Shockley-Read-Hall, Auger, radiative and surface) are investigated. The microwave properties of silicon are examined, in particular the variation of silicon reflectivity with excess carrier density. Filtering properties of microstrip photonic bandgap structures and how they may be controlled optically are studied. A proof-of-concept microstrip photonic bandgap structure with optical control is designed, simulated and measured. With no optical illumination incident upon the silicon, the microstrip photonic bandgap structure's filtering properties are well-defined; a 3dB stopband width of 2.6GHz, a 6dB bandwidth of 2GHz and stopband depth of -11.6dB at the centre frequency of 9.9GHz...

  7. Mode Division Multiplexing Exploring Hollow-Core Photonic Bandgap Fibers

    DEFF Research Database (Denmark)

    Xu, Jing; Lyngso, Jens Kristian; Leick, Lasse; Carpenter, Joel; Wilkinson, Timothy D.; Peucheret, Christophe

    2013-01-01

    We review our recent exploratory investigations on mode division multiplexing using hollow-core photonic bandgap fibers (HC-PBGFs). Compared with traditional multimode fibers, HC-PBGFs have several attractive features such as ultra-low nonlinearities, low-loss transmission window around 2 µm etc....

  8. Bandgap properties of low index contrast aperiodically ordered photonic quasicrystals

    CERN Document Server

    Zito, Gianluigi; Di Gennaro, Emiliano; Andreone, Antonello; Santamato, Enrico; Abbate, Giancarlo

    2009-01-01

    We numerically analyze, using Finite Difference Time Domain simulations, the bandgap properties of photonic quasicrystals with a low index contrast. We compared 8-, 10- and 12-fold symmetry aperiodically ordered lattices with different spatial tiling. Our results show that tiling design, more than symmetry, determines the transmission properties of these structures.

  9. Optically controlled photonic bandgap structures for microstrip circuits

    International Nuclear Information System (INIS)

    This thesis is concerned with the optical control of microwave photonic bandgap circuits using high resistivity silicon. Photoconducting processes that occur within silicon are investigated. The influence of excess carrier density on carrier mobility and lifetime is examined. In addition, electron-hole pair recombination mechanisms (Shockley-Read-Hall, Auger, radiative and surface) are investigated. The microwave properties of silicon are examined, in particular the variation of silicon reflectivity with excess carrier density. Filtering properties of microstrip photonic bandgap structures and how they may be controlled optically are studied. A proof-of-concept microstrip photonic bandgap structure with optical control is designed, simulated and measured. With no optical illumination incident upon the silicon, the microstrip photonic bandgap structure's filtering properties are well-defined; a 3dB stopband width of 2.6GHz, a 6dB bandwidth of 2GHz and stopband depth of -11.6dB at the centre frequency of 9.9GHz. When the silicon is illuminated, the structure's filtering properties are suppressed. Under illumination the experimental results display an increase in S21 of 6.5dB and a reduction in S11 of more than 10dB at 9.9GHz. A comparison of measured and simulated results reveal that the photogenerated excess carrier density is between 4 x 1015 cm-3 and 1.1 x 1016 cm-3. (author)

  10. Gap solitons in inhomogeneous high-index photonic bandgap fibers

    DEFF Research Database (Denmark)

    Lægsgaard, Jesper

    2011-01-01

    Microstructured optical fibers based on As2Se3 glass may be designed to have an in-plane photonic bandgap, and thereby support modes with zero propagation constant and zero group velocity [1]. It has been shown that such structures will support gap solitons which by way of Raman scattering will be...

  11. Biased liquid crystal photonic bandgap fiber

    DEFF Research Database (Denmark)

    Weirich, Johannes; Lægsgaard, Jesper; Alkeskjold, Thomas Tanggaard;

    2008-01-01

    We simulate the director structure of all capillaries in a biased photonic crystal fiber infiltrated with liquid crystals. Various mode simulations for different capillaries show the necessity to consider the entire structure.......We simulate the director structure of all capillaries in a biased photonic crystal fiber infiltrated with liquid crystals. Various mode simulations for different capillaries show the necessity to consider the entire structure....

  12. Gas sensing using air-guiding photonic bandgap fibers

    DEFF Research Database (Denmark)

    Ritar, Tuomo; Tuominen, J.; Ludvigsen, Hanne;

    2004-01-01

    We demonstrate the high sensitivity of gas sensing using a novel air-guiding photonic bandgap fiber. The bandgap fiber is spliced to a standard single-mode fiber at the input end for easy coupling and filled with gas through the other end placed in a vacuum chamber. The technique is applied to...... characterize absorption lines of acetylene and hydrogen cyanide employing a tunable laser as light source. Measurements with a LED are also performed for comparison. Detection of weakly absorbing gases such as methane and ammonia is explored....

  13. Biased liquid crystal infiltrated photonic bandgap fiber

    DEFF Research Database (Denmark)

    Weirich, Johannes; Lægsgaard, Jesper; Scolari, Lara;

    2009-01-01

    A simulation scheme for the transmission spectrum of a photonic crystal fiber infiltrated with a nematic liquid crystal and subject to an external bias is presented. The alignment of the biased liquid crystal is simulated using the finite element method to solve the relevant system of coupled...... partial differential equations. From the liquid crystal alignment the full tensorial dielectric permittivity in the capillaries is derived. The transmission spectrum for the photonic crystal fiber is obtained by solving the generalized eigenvalue problem deriving from Maxwell’s equations using a vector...... element based finite element method. We demonstrate results for a splay aligned liquid crystal infiltrated into the capillaries of a four-ring photonic crystal fiber and compare them to corresponding experiments....

  14. Compact and broadband waveguide taper based on partial bandgap photonic crystals

    Institute of Scientific and Technical Information of China (English)

    Jin Hou; Dingshan Gao; Huaming Wu; Zhiping Zhou

    2009-01-01

    Partial bandgap characteristics of parallelogram lattice photonic crystals are proposed to suppress the radiation modes in a compact dielectric waveguide taper so as to obtain high transmittance in a large wavelength range. Band structure of the photonic crystals shows that there exists a partial bandgap. The photonic crystals with partial bandgap are then used as the cladding of a waveguide taper to reduce the radiation loss efficiently. In comparison with the conventional dielectric taper and the complete bandgap photonic crystal taper, the partial bandgap photonic crystal taper has a high transmittance of above 85% with a wide band of 170 nm.

  15. Three-dimensional metallic photonic crystals with optical bandgaps.

    Science.gov (United States)

    Vasilantonakis, Nikos; Terzaki, Konstantina; Sakellari, Ioanna; Purlys, Vytautas; Gray, David; Soukoulis, Costas M; Vamvakaki, Maria; Kafesaki, Maria; Farsari, Maria

    2012-02-21

    The fabrication of fully three-dimensional photonic crystals with a bandgap at optical wavelengths is demonstrated by way of direct femtosecond laser writing of an organic-inorganic hybrid material with metal-binding moieties, and selective silver coating using electroless plating. The crystals have 600-nm intralayer periodicity and sub-100 nm features, and they exhibit well-defined diffraction patterns. PMID:22278944

  16. Advances and limitations in the modelling of fabricated photonic bandgap fibers

    OpenAIRE

    Poletti, F.; Petrovich, M.N.; Amezcua-Correa, R.; Broderick, N.G.; Monro, T.M.; Richardson, D. J.

    2006-01-01

    We model fabricated silica photonic bandgap fibers and achieve good agreement between simulated and measured properties. We identify the size of the SEM bitmap image as the ultimate limit to the accurate calculation of surfaces modes within the bandgap.

  17. Cavity quantum electrodynamics with three-dimensional photonic bandgap crystals

    CERN Document Server

    Vos, W L

    2015-01-01

    This paper gives an overview of recent work on three-dimensional (3D) photonic crystals with a "full and complete" 3D photonic band gap. We review five main aspects: 1) spontaneous emission inhibition, 2) spatial localization of light within a tiny nanoscale volume (aka "a nanobox for light"), 3) the introduction of a gain medium leading to thresholdless lasers, 4) breaking of the weak-coupling approximation of cavity QED, both in the frequency and in the time-domain, 5) decoherence, in particular the shielding of vacuum fluctuations by a 3D photonic bandgap. In addition, we list and evaluate all known photonic crystal structures with a demonstrated 3D band gap.

  18. Air-guiding photonic bandgap fiber with improved triangular air-silica photonic crystal cladding

    OpenAIRE

    Yan, M; Shum, P

    2005-01-01

    We introduce a small-core air-guiding photonic crystal fiber whose cladding is made of improved air-silica photonic crystal with non-circular air holes placed in triangular lattice. The fiber achieves un-disturbed bandgap guidance over 350nm wavelength range.

  19. One-dimensional photonic bandgap structure in abalone shell

    Institute of Scientific and Technical Information of China (English)

    LI Bo; ZHOU Ji; LI Longtu; LI Qi; HAN Shuo; HAO Zhibiao

    2005-01-01

    @@ Photonic bandgap (PBG) materials are periodic com- posites of dielectric materials in which electromagnetic waves of certain frequency range cannot propagate in any or a special direction. Recently, there has been great inter- est in synthetic PBG materials due to their ability in ma- nipulation of photons. Since 500 million years ago, the natural world has been exploiting photonic structures for specific biological purposes[1]. Different types of biologi- cal PBG materials have been discovered in recent years, such as the one-dimension PBG structure in the sea mouse Aphrodita[2], and the fruits Elaeocarpus[3,4]; two-dimension PBG structure in the male peacock Pavo muticus feathers[5], Indonesian male Papilio palinurus butterfly[6], Thaumantis diores butterfly[7] and the male Ancyluris meliboeus Fabricius butterflies[8]; and three-dimension PBG structure in the weevil Pachyrhynchus argus[9].

  20. The Second Order Guided Modes Based on Photonic Bandgap Effects in Air/Glass Photonic Crystal Fibers

    International Nuclear Information System (INIS)

    We introduce a defect site in the periodic structure of a photonic bandgap fiber, to confine and guide the second order mode by photonic bandgap effects. Based on a high air-filling fraction photonic crystal cladding structure, a simplified model with an equivalent air cladding was proposed to explore and analyze the properties of this second order guided mode

  1. Analysis of photonic band-gap structures in stratified medium

    DEFF Research Database (Denmark)

    Tong, Ming-Sze; Yinchao, Chen; Lu, Yilong;

    2005-01-01

    Purpose - To demonstrate the flexibility and advantages of a non-uniform pseudo-spectral time domain (nu-PSTD) method through studies of the wave propagation characteristics on photonic band-gap (PBG) structures in stratified medium Design/methodology/approach - A nu-PSTD method is proposed in...... the occasions where the spatial distributions contain step of up to five times larger than the original size, while simultaneously the flexibility of non-uniform sampling offers further savings on computational storage. Research limitations/implications - Research has been mainly limited to the simple...

  2. Design of photonic bandgap fibers by topology optimization

    DEFF Research Database (Denmark)

    Dühring, Maria Bayard; Sigmund, Ole; Feurer, Thomas

    2010-01-01

    A method based on topology optimization is presented to design the cross section of hollow-core photonic bandgap fibers for minimizing energy loss by material absorption. The optical problem is modeled by the timeharmonic wave equation and solved with the finite element program Comsol Multiphysics....... The optimization is based on continuous material interpolation functions between the refractive indices and is carried out by the method of moving asymptotes. An example illustrates the performance of the method where air and silica are redistributed around the core so that the overlap between the...

  3. Feasibility of detecting single atoms using photonic bandgap cavities

    CERN Document Server

    Lev, B I; Barclay, P; Painter, O J; Mabuchi, H; Lev, Benjamin; Srinivasan, Kartik; Barclay, Paul; Painter, Oskar; Mabuchi, Hideo

    2004-01-01

    We propose an atom-cavity chip that combines laser cooling and trapping of neutral atoms with magnetic microtraps and waveguides to deliver a cold atom to the mode of a fiber taper coupled photonic bandgap (PBG) cavity. The feasibility of this device for detecting single atoms is analyzed using both a semi-classical treatment and an unconditional master equation approach. Single-atom detection seems achievable in an initial experiment involving the non-deterministic delivery of weakly trapped atoms into the mode of the PBG cavity.

  4. Bandgap isotropy in photonic quasicrystals with low-index contrast

    Science.gov (United States)

    Andreone, Antonello; Abbate, Giancarlo; Di Gennaro, Emiliano; Rose Thankamani, Priya

    2012-05-01

    Formation and development of the photonic band gap in two-dimensional 8-, 10-, and 12-fold symmetry quasicrystalline lattices of low-index contrast are reported. Finite-size structures made of dielectric cylindrical rods are studied and measured in the microwave region, and their properties are compared with a conventional hexagonal crystal. Band-gap characteristics are investigated by changing the direction of propagation of the incident beam inside the crystal. Various angles of incidence are used to investigate the isotropic nature of the band gap.

  5. Liquid Crystal Photonic bandgap Fibers: Modeling and Devices

    DEFF Research Database (Denmark)

    Weirich, Johannes

    In this PhD thesis an experimental and numerical investigation of liquid crystal infiltrated photonic bandgap fibers (LCPBGs) is presented. A simulation scheme for modeling LCPBG devices including electrical tunability is presented. New experimental techniques, boundary coating and the applications...... of monomer added LCs, are investigated. Waveplates based on LCPBGs and a tunable polarization maintaining filter are developed. An on-chip tunable notch filter based on long period gratings is presented. Furthermore, the application of a LCPBG device for the electrical control of a fiber laser is...

  6. Mode Division Multiplexing Exploring Hollow-Core Photonic Bandgap Fibers

    DEFF Research Database (Denmark)

    Xu, Jing; Lyngso, Jens Kristian; Leick, Lasse;

    2013-01-01

    . After having discussed the potential and challenges of using HC-PBGFs as transmission fibers for mode multiplexing applications, we will report a number of recent proof-of-concept results obtained in our group using direct detection receivers. The first one is the transmission of two 10.7 Gbit/s non......We review our recent exploratory investigations on mode division multiplexing using hollow-core photonic bandgap fibers (HC-PBGFs). Compared with traditional multimode fibers, HC-PBGFs have several attractive features such as ultra-low nonlinearities, low-loss transmission window around 2 µm etc...

  7. True photonic band-gap mode-control in VCSEL structures

    DEFF Research Database (Denmark)

    Romstad, F.; Madsen, M.; Birkedal, Dan;

    2003-01-01

    Photonic band-gap mode confinement in novel nano-structured large area VCSEL structures is confirmed by the amplified spontaneous emission spectrum. Both guide and anti-guide VCSEL structures are experimentally characterised to verify the photonic band-gap effect.......Photonic band-gap mode confinement in novel nano-structured large area VCSEL structures is confirmed by the amplified spontaneous emission spectrum. Both guide and anti-guide VCSEL structures are experimentally characterised to verify the photonic band-gap effect....

  8. Electrically controllable liquid crystal photonic bandgap fiber with dual-frequency control

    DEFF Research Database (Denmark)

    Scolari, Lara; Alkeskjold, Thomas Tanggaard; Riishede, Jesper;

    2005-01-01

    We present an electrically tunable liquid crystal photonic bandgap fiber device based on a dual frequency liquid crystal with pre-tilted molecules that allows the bandgaps to be continuously tuned. The frequency dependent behavior of the liquid crystal enables active shifting of the bandgaps toward...

  9. Power-scalable long-wavelength Yb-doped photonic bandgap fiber sources

    DEFF Research Database (Denmark)

    Olausson, Christina Bjarnal Thulin; Shirakawa, Akira; Maurayama, Hiroki; Ken-ichi, Ueda; Lyngsøe, Jens Kristian; Broeng, Jes

    2010-01-01

    Ytterbium-doped photonic-bandgap fiber sources operationg at the long-wavelength edge of the ytterbium gain band are being investigated for high power amplification. Artificial shaping of the gain spectrum by the characteristic distributed filtering effect of the photonic bandgap enables spontane...

  10. Photonic bandgap via nonlinear modulation assisted by spontaneously generated coherence

    Energy Technology Data Exchange (ETDEWEB)

    Yao, Yin-Ping; Zhang, Tong-Yi [State Key Laboratory of Transient Optics and Photonics, Xi' an Institute of Optics and Precision Mechanics, Chinese Academy of Sciences, Xi' an 710119 (China); Kou, Jun [Quantum Engineering Center, Beijing Institute of Control Device, Beijing 100854 (China); Wan, Ren-Gang, E-mail: wrg@opt.ac.cn [State Key Laboratory of Transient Optics and Photonics, Xi' an Institute of Optics and Precision Mechanics, Chinese Academy of Sciences, Xi' an 710119 (China)

    2013-09-02

    A four-level double-ladder atomic system with two upper states coupled to the excited state by a standing-wave trigger field is explored to generate photonic bandgap (PBG) structure. With the assistance of spontaneously generated coherence (SGC) from the two decay pathways, we can obtain single or double fully developed PBG when the trigger field is far away from resonance or resonant. While in the absence of SGC, the atomic medium becomes strong absorptive to the probe field, and therefore the resulting PBGs are severely malformed or even cannot be opened up. Numerical results show that the PBG structure is originated from the third-order cross Kerr nonlinear modulation between the probe and trigger fields. This mechanism differs from the recent schemes based on linear modulation.

  11. Novel spatial solitons in light-induced photonic bandgap structures

    Institute of Scientific and Technical Information of China (English)

    Ci-bo LOU; Li-qin TANG; Dao-hong SONG; Xiao-sheng WANG; Jing-jun XU; Zhi-gang CHEN

    2008-01-01

    The study of wave propagation in periodic sys-tems is at the frontiers of physics, from fluids to condensed matter physics, and from photonic crystals to Bose-Einstein condensates. In optics, a typical example of periodic system is a closely-spaced waveguide array, in which collective behavior of wave propagation exhibits many intriguing phenomena that have no counterpart in homogeneous media. Even in a linear waveguide array, the diffraction property of a light beam changes due to evanescent coupling between nearby waveguide sites, leading to normal and anomalous discrete diffraction. In a nonlinear waveguide array, a bal-ance between diffraction and self-action gives rise to novel localized states such as spatial "discrete solitons" in the semi-infinite (or total-internal-reflection) gap or spatial "gap solitons" in the Bragg reflection gaps, Recently, in a series of experiments, we have "fabricated" closely-spaced waveguide arrays (photonic lattices) by optical induction. Such photonic structures have attracted great interest due to their novel physics, link to photonic crystals, as well as po-tential applications in optical switching and navigation. In this review article, we present a brief overview on our ex-perimental demonstrations of a number of novel spatial soliton phenomena in light-induced photonic bandgap structures, including self-trapping of fundamental discrete solitons and more sophisticated lattice gap solitons. Much of our work has direct impact on the study of similar discrete phenomena in systems beyond optics, including sound waves, water waves, and matter waves (Bose-Einstein con-densates) propagating in periodic potentials.

  12. High Thermal and Electrical Tunability of Negative Dielectric Liquid Crystal Photonic Bandgap Fibers

    DEFF Research Database (Denmark)

    Wei, Lei; Scolari, Lara; Weirich, Johannes;

    2008-01-01

    We infiltrate photonic crystal fibers with negative dielectric liquid crystals. 400nm bandgap shift is obtained in the range 22ºC-80ºC and 119nm shift of the long-wavelength bandgap edge is achieved by applying a voltage of 200V.......We infiltrate photonic crystal fibers with negative dielectric liquid crystals. 400nm bandgap shift is obtained in the range 22ºC-80ºC and 119nm shift of the long-wavelength bandgap edge is achieved by applying a voltage of 200V....

  13. Enhanced Two-Photon Absorption in a Hollow-Core Photonic Bandgap Fiber

    CERN Document Server

    Saha, Kasturi; Londero, Pablo; Gaeta, Alexander L

    2010-01-01

    We show that two-photon absorption (TPA) in Rubidium atoms can be greatly enhanced by the use of a hollow-core photonic bandgap fiber. We investigate off-resonant, degenerate Doppler-free TPA on the 5S1/2 - 5D5/2 transition and observe 1% absorption of a pump beam with a total power of only 1 mW in the fiber. These results are verified by measuring the amount of emitted blue fluorescence and are consistent with the theoretical predictions which indicate that transit time effects play an important role in determining the two-photon absorption cross-section in a confined geometry.

  14. Larger bandgap of elliptical cylinders in two-dimensional double-layer photonic crystals

    International Nuclear Information System (INIS)

    We investigate the bandgap properties of two-dimensional double-layer photonic crystals composed of elliptical cylinders in square and triangular lattices, considering cylinders formed of dielectric cores surrounded by interfacial layers of air in magnesium fluoride background. Using the plane-wave numerical expansion method, the bandgap spectrum for the cylinders covered by air rings is obtained for different structural parameters, such as the radius, orientation angle, and lattice constant. The results show that the bandgap of the two-dimensional double-layer photonic crystal is greatly improved compared with traditional two-dimensional photonic crystal and the triangular lattice presents a larger bandgap than the square lattice. The optimal structure parameters to broaden the bandgap are presented. (paper)

  15. Thermal tunability of photonic bandgaps in liquid crystal infiltrated microstructured polymer optical fibers

    DEFF Research Database (Denmark)

    Yuan, Scott Wu; Wei, Lei; Alkeskjold, Thomas Tanggaard;

    2009-01-01

    We demonstrate the photonic bandgap effect and the thermal tunability of bandgaps in microstructured polymer optical fibers infiltrated with liquid crystal. Two liquid crystals with opposite sign of the temperature gradient of the ordinary refractive index (E7 and MDA-00- 1444) are used to...

  16. Photonic bandgap fiber lasers and multicore fiber lasers for next generation high power lasers

    DEFF Research Database (Denmark)

    Shirakawa, A.; Chen, M.; Suzuki, Y.;

    2014-01-01

    Photonic bandgap fiber lasers are realizing new laser spectra and nonlinearity mitigation that a conventional fiber laser cannot. Multicore fiber lasers are a promising tool for power scaling by coherent beam combination. © 2014 OSA....

  17. Low loss liquid crystal photonic bandgap fiber in the near-infrared region

    DEFF Research Database (Denmark)

    Scolari, Lara; Wei, Lei; Gauza, S.;

    2010-01-01

    We infiltrate a photonic crystal fiber with a perdeuterated liquid crystal, which has a reduced infrared absorption. The lowest loss ever reported (about 1 dB) in the middle of the near-infrared bandgap is achieved.......We infiltrate a photonic crystal fiber with a perdeuterated liquid crystal, which has a reduced infrared absorption. The lowest loss ever reported (about 1 dB) in the middle of the near-infrared bandgap is achieved....

  18. Supercontinuum generation enhancement in all-solid all-normal dispersion soft glass photonic crystal fiber pumped at 1550 nm

    Science.gov (United States)

    Siwicki, Bartłomiej; Klimczak, Mariusz; Stępień, Ryszard; Buczyński, Ryszard

    2015-10-01

    We study supercontinuum generation enhancement in an all-normal dispersion, all-glass photonic crystal fiber made of lead-silicate glasses. Dispersion characteristics were optimized through adjustment of regular hexagonal lattice of photonic crystal fiber in case of three different, thermally matched pairs of glasses. Supercontinuum generation was simulated with split-step Fourier method using the model that takes into account frequency-dependent effective mode area and losses, Raman response of the medium and temporal shape of the input pulse. An octave-spanning coherent supercontinuum has been obtained for all-glass fiber with lattice constant Λ = 1.73 μm and filling factor d/Λ = 0.8, made of silicate SF6/F2, spanning 850-2200 nm wavelengths in 10 dB dynamic range and pumped with pulses with energy as low as 3 nJ at 1550 nm.

  19. Photonic Bandgap Properties of Atom-lattice Photonic Crystals in Polymer

    Institute of Scientific and Technical Information of China (English)

    REN Lin; WANG Dian; SUN Gui-ting; NIU Li-gang; YANG Han; SONG Jun-feng

    2011-01-01

    The present paper covers the various photonic crystals(PhCs) structures mimicking real atom-lattice structures in electronic crystals by using the femtosecond laser-induced two-photon photopolymerization of SU-8 resin. The bandgap properties were investigated by varying the crystal orientations in <111>, <110> and <100> of diamond-lattice PhCs. lhe photonic stop gaps were present at λ=3.88 μm in <111> direction, λ=4.01 μtm in <110> direction and λ=5.30 μm in <100> direction, respectively. In addition, defects were introduced in graphite-lattice PhCs and the strong localization of photons in this structure with defects at λ=5 μm was achieved. All the above work shows the powerful capability of femtosecond laser fabrication in manufacturing various complicated threedimensional photonic crystals and of controlling photons by inducing defects in the PhCs samples.

  20. One-dimensional tunable magnetic photonic band-gap materials at microwave frequency

    International Nuclear Information System (INIS)

    The microwave transmission characteristics of one-dimensional magnetic photonic band-gap (MPBG) materials, in which a ferromagnetic composite layer is sandwiched by periodic dielectric layers, are studied. The magnetic photonic band gaps (MBPGs) are obtained related to the existence of ferromagnetic resonance (FMR) in the vicinity of the band-gap frequency. We investigate the effects of period structure and the applied magnetic field on the MPBGs as well as the ferromagnetic resonance. The photonic band gaps of the TE mode shift to lower frequencies. The MPBG effect is strongly dependent on the periodic structure of the MPBG materials. While the FMR effect is dominated by the applied magnetic field

  1. Highly tunable large core single-mode liquid crystal photonic bandgap fiber

    DEFF Research Database (Denmark)

    Alkeskjold, Thomas Tanggaard; Lægsgaard, Jesper; Bjarklev, Anders Overgaard;

    2006-01-01

    We demonstrate a highly tunable photonic bandgap fiber, which has a large-core diameter of 25 mu m and an effective mode area of 440 mu m(2). The tunability is achieved by infiltrating the air holes of a photonic crystal fiber with an optimized liquid-crystal mixture having a large temperature...... Society of America....

  2. Computational methods for the analysis and design of photonic bandgap structures

    OpenAIRE

    Qiu, Min

    2000-01-01

    In the present thesis, computational methods for theanalysis and design of photonic bandgap structure areconsidered. Many numerical methods have been used to study suchstructures. Among them, the plane wave expansion method is veryoften used. Using this method, we show that inclusions ofelliptic air holes can be used effectively to obtain a largercomplete band gap for two-dimensional (2D) photonic crystals.An optimal design of a 2D photonic crystal is also consideredin the thesis using a comb...

  3. Mode areas and field energy distribution in honeycomb photonic bandgap fibers

    CERN Document Server

    Laegsgaard, J; Bjarklev, A; Laegsgaard, Jesper; Mortensen, Niels Asger; Bjarklev, Anders

    2003-01-01

    The field energy distributions and effective mode areas of silica-based photonic bandgap fibers with a honeycomb airhole structure in the cladding and an extra airhole defining the core are investigated. We present a generalization of the common effective area definition, suitable for the problem at hand, and compare the results for the photonic bandgap fibers with those of index-guiding microstructured fibers. While the majority of the field energy in the honeycomb photonic bandgap fibers is found to reside in the silica, a substantial fraction (up to ~30%) can be located in the airholes. This property may show such fibers particularly interesting for sensor applications, especially those based on nonlinear effects or interaction with other structures (e.g. Bragg gratings) in the glass.

  4. Compact optically-fed microwave true-time delay using liquid crystal photonic bandgap fiber device

    DEFF Research Database (Denmark)

    Wei, Lei; Xue, Weiqi; Chen, Yaohui;

    2009-01-01

    Electrically tunable liquid crystal photonic bandgap fiber device based optically-fed microwave true-time delay is demonstrated. A maximum ~60° phase shift and an averaged ~7.2ps true time delay are obtained over the modulation frequency range 1GHz-19GHz.......Electrically tunable liquid crystal photonic bandgap fiber device based optically-fed microwave true-time delay is demonstrated. A maximum ~60° phase shift and an averaged ~7.2ps true time delay are obtained over the modulation frequency range 1GHz-19GHz....

  5. Tunable All-in-Fiber Waveplates Based on Negative Dielectric Liquid Crystal Photonic Bandgap Fibers

    DEFF Research Database (Denmark)

    Wei, Lei; Eskildsen, Lars; Weirich, Johannes;

    2008-01-01

    Tunable all-in-fiber waveplates based on negative dielectric liquid crystal photonic bandgap fibers are presented. The birefringence can be tuned electrically and thermally to work as a quarter-wave or a half-wave plate in the range 1520 nm-1580 nm.......Tunable all-in-fiber waveplates based on negative dielectric liquid crystal photonic bandgap fibers are presented. The birefringence can be tuned electrically and thermally to work as a quarter-wave or a half-wave plate in the range 1520 nm-1580 nm....

  6. Three-dimensional single gyroid photonic crystals with a mid-infrared bandgap

    CERN Document Server

    Peng, Siying; Chen, Valerian H; Khabiboulline, Emil T; Braun, Paul; Atwater, Harry A

    2016-01-01

    A gyroid structure is a distinct morphology that is triply periodic and consists of minimal isosurfaces containing no straight lines. We have designed and synthesized amorphous silicon (a-Si) mid-infrared gyroid photonic crystals that exhibit a complete bandgap in infrared spectroscopy measurements. Photonic crystals were synthesized by deposition of a-Si/Al2O3 coatings onto a sacrificial polymer scaffold defined by two-photon lithography. We observed a 100% reflectance at 7.5 \\mum for single gyroids with a unit cell size of 4.5 \\mum, in agreement with the photonic bandgap position predicted from full-wave electromagnetic simulations, whereas the observed reflection peak shifted to 8 um for a 5.5 \\mum unit cell size. This approach represents a simulation-fabrication-characterization platform to realize three-dimensional gyroid photonic crystals with well-defined dimensions in real space and tailored properties in momentum space.

  7. Bandgaps of the Chalcogenide Glass Hollow-Core Photonic Crystal Fiber

    International Nuclear Information System (INIS)

    Bandgaps of chalcogenide glass hollow-core photonic crystal fibers (GLS HC-PCFs) are analyzed by using the plane-wave expansion method. A mid-infrared laser can propagate in these low confinement loss fibers when the wavelength falls into the bandgaps. For enlarging the bandgap width, an improved GLS HC-PCF is put forward, the normalized frequency kΛ of the improved fiber is from 7.2 to 8.5 in its first bandgap. The improved GLS HC-PCF with pitch of 4.2 μm can transmit the lights with wavelengths ranging from 3.1 μm to 3.7 μm. (fundamental areas of phenomenology(including applications))

  8. Cavity quantum electrodynamics with three-dimensional photonic bandgap crystals

    NARCIS (Netherlands)

    Vos, W.L.; Woldering, L.A.; Ghulinyan, M.; Pavesi, L.

    2015-01-01

    This paper is Chapter 8 of the book "Light Localisation and Lasing: Random and Pseudorandom Photonic Structures", edited by Mher Ghulinyan and Lorenzo Pavesi (Cambridge University Press, Cambridge, 2015). It provides an overview of much recent work on 3D photonic crystals with a complete photonic b

  9. Low index-contrast aperiodically ordered photonic quasicrystals for the development of isotropic photonic band-gap devices

    Science.gov (United States)

    Priya Rose, T.; Di Gennaro, E.; Andreone, A.; Abbate, G.

    2010-05-01

    Photonic quasicrystals (PQCs) have neither true periodicity nor translational symmetry, however they can exhibit symmetries that are not achievable by conventional periodic structures. The arbitrarily high rotational symmetry of these materials can be practically exploited to manufacture isotropic band gap materials, which are perfectly suitable for hosting waveguides or cavities. In this work, formation and development of the photonic bandgap (PBG) in twodimensional 8-, 10- and 12-fold symmetry quasicrystalline lattices of low dielectric contrast (0.4-0.6) were measured in the microwave region and compared with the PBG properties of a conventional hexagonal crystal. Band-gap properties were also investigated by changing the direction of propagation of the incident beam inside the crystal. Various angles of incidence from 0° to 30° were used in order to investigate the isotropic nature of the band-gap.

  10. Photolithography of thick photoresist coating for electrically controlled liquid crystal photonic bandgap fibre devices

    DEFF Research Database (Denmark)

    Wei, Lei; Khomtchenko, Elena; Alkeskjold, Thomas Tanggaard;

    2009-01-01

    Thick photoresist coating for electrode patterning in an anisotropically etched V-groove is investigated for electrically controlled liquid crystal photonic bandgap fibre devices. The photoresist step coverage at the convex corners is compared with and without soft baking after photoresist spin...

  11. Controlling terahertz waves with meta-materials and photonic bandgap structures

    Energy Technology Data Exchange (ETDEWEB)

    Shchegolkov, Dmitry [Los Alamos National Laboratory; Azad, Abul [Los Alamos National Laboratory; O' Hara, John F [Los Alamos National Laboratory; Moody, Nathan A [Los Alamos National Laboratory; Simakov, Evgenya I [Los Alamos National Laboratory

    2010-12-07

    We will describe research conducted at Los Alamos National Laboratory towards developing components for controlling terahertz waves. We employ meta-materials and, particularly, meta-films, as very compact absorbers for controlling quasioptical beams. We believe that dielectric photonic bandgap structures could replace ordinary metal waveguide devices at THz, since metal structures become extremely lossy in this frequency range.

  12. Generation of Low Divergent High Power Supercontinuum Through a Large Mode Area Photonic Bandgap Fiber

    CERN Document Server

    Ghosh, S; Varshney, R K; Pal, B P

    2012-01-01

    We report generation of broadband low divergent supercontinuum over the entire wavelength window of 1.5 to 3.5 {\\mu}m from a 2.25 meter long effective single moded photonic bandgap fiber with mode area of 1100 {\\mu}m2.

  13. 10 Gbit/s transmission over air-guiding photonic bandgap fibre at 1550 nm

    DEFF Research Database (Denmark)

    Peucheret, Christophe; Zsigri, Beata; Hansen, T.P.;

    2005-01-01

    The first data transmission over air-guiding photonic bandgap (PBG) fibre is demonstrated. A 10 Gbit/s signal was successfully transmitted at 1550 nm over 150 m of singlemode PBG fibre, thus demonstrating their applicability to optical communications. Furthermore, the impact of the polarisation...

  14. Noise filtering in a multi-channel system using a tunable liquid crystal photonic bandgap fiber

    DEFF Research Database (Denmark)

    Petersen, Martin Nordal; Scolari, Lara; Tokle, Torger; Alkeskjold, Thomas Tanggaard; Gauza, S.; Wu, Shin-Ton; Bjarklev, Anders Overgaard

    2008-01-01

    This paper reports on the first application of a liquid crystal infiltrated photonic bandgap fiber used as a tunable filter in an optical transmission system. The device allows low-cost amplified spontaneous emission (ASE) noise filtering and gain equalization with low insertion loss and broad...

  15. Transmission Bandwidth Tunability of a Liquid-Filled Photonic Bandgap Fiber

    Institute of Scientific and Technical Information of China (English)

    ZOU Bing; LIU Yan-Ge; DU Jiang-Sing; WANG Zhi; HAN Ting-Ting; XU Jian-Bo; LI Yuan; LIU Bo

    2009-01-01

    @@ A temperature tunable photonic bandgap tiber (PBGF) is demonstrated by an index-guiding photonic crystal fiber filled with high-index liquid. The temperature tunable characteristics of the fiber axe experimentally and numerically investigated. Compression of transmission bandwidth of the PBGF is demonstrated by changing the temperature of part of the fiber. The tunable transmission bandwidth with a range of 250 nm is achieved by changing the temperature from 30℃ to 90℃.

  16. Study on the photonic bandgaps of hollow-core microstructured fibers

    Institute of Scientific and Technical Information of China (English)

    Zhaolun Liu; Guiyao Zhou; Lantian Hou

    2006-01-01

    A simple method is presented to measure the transmission spectrum of hollow-core microstructured fibers in the visible, near-infrared, and mid-infrared regions. The plane wave expansion method is applied to analyze the photonic bandgaps of hollow-core microstructured fibers. The experimental results indicate that there are several strong transmission bands in the near-infrared and mid-infrared region, but hardly any transmission phenomena in the visible region, which shows that there are some bandgaps in nearinfrared wavelength. The experimental results are consistent with the numerically simulative results using a plane wave expansion method.

  17. Paving the way for third harmonic generation in hollow-core photonic bandgap fibers

    CERN Document Server

    Montz, Z

    2014-01-01

    We present two novel hybrid photonic structures made of silica that possess two well-separated frequency bandgaps. The addition of interstitial air holes in a precise location and size allows these bandgaps to open up with a ratio of ${\\sim3}$ between their central frequencies at the air line ${ck_z/w=1}$, thus fulfilling the basic guidance condition for third harmonic generation in hollow-core fibers. In addition, these designs may serve as high-power laser delivery of two well-separated wavelengths, such as visible and near infrared.

  18. Manipulating the Propagation of Solitons with Solid-Core Photonic Bandgap Fibers

    Directory of Open Access Journals (Sweden)

    O. Vanvincq

    2012-01-01

    Full Text Available We review the dynamics of soliton self-frequency shift induced by Raman gain in special solid-core photonic bandgap fibers and its consequences in terms of supercontinuum generation. These photonic bandgap fibers have been designed to allow nonlinear experiments in the first bandgap without suffering from significant loss even when working close to the photonic bandgap edge. We studied experimentally, numerically, and analytically the extreme deceleration of the soliton self-frequency shift at the long-wavelength edge of the first transmission window. This phenomenon is interpreted as being due to a large variation of the group-velocity dispersion in this spectral range and has been obtained with no significant power loss. Then, we investigated experimentally and numerically the generation of supercontinuum in this kind of fibers, in both spectral and temporal domains. In particular, we demonstrated an efficient tailoring of the supercontinuum spectral extension as well as a strong noise reduction at its long-wavelength edge.

  19. Effect of photonic bandgap on upconversion emission in YbPO4:Er inverse opal photonic crystals.

    Science.gov (United States)

    Yang, Zhengwen; Zhu, Kan; Song, Zhiguo; Zhou, Dacheng; Yin, Zhaoyi; Qiu, Jianbei

    2011-01-20

    We obtained upconversion (UC) light-emitting photonic materials (YbPO(4):Er) with an inverse opal structure by the self-assembly technique in combination with a solgel method. The effect of the photonic stopband on the UC luminescence of the (2)H(11/2), (4)S(3/2)→(4)I(15/2), and (4)F(9/2)→(4)I(15/2) transitions of Er(3+) has been observed in the inverse opals of the Er(3+)-doped YbPO(4). Significant suppression of the UC emission was detected if the photonic bandgap overlapped with the Er(3+) ions emission band, while enhancement of the UC emission occurs if the emission band appears at the edge of the bandgap. PMID:21263723

  20. First Evidence of Near-Infrared Photonic Bandgap in Polymeric Rod-Connected Diamond Structure

    CERN Document Server

    Chen, Lifeng; Zheng, Xu; Lin, Jia-De; Oulton, Ruth; Lopez-Garcia, Martin; Ho, Ying-Lung D; Rarity, John G

    2015-01-01

    We present the simulation, fabrication, and optical characterization of low-index polymeric rod-connected diamond (RCD) structures. Such complex three-dimensional photonic crystal structures are created via direct laser writing by two-photon polymerization. To our knowledge, this is the first measurement at near-infrared wavelengths, showing partial photonic bandgaps. We characterize structures in transmission and reflection using angular resolved Fourier image spectroscopy to visualize the band structure. Comparison of the numerical simulations of such structures with the experimentally measured data show good agreement for both P- and S-polarizations.

  1. Gaussian Filtering with Tapered Oil-Filled Photonic Bandgap Fibers

    DEFF Research Database (Denmark)

    Brunetti, Anna Chiara; Scolari, Lara; Weirich, Johannes;

    2008-01-01

    A tunable Gaussian filter based on a tapered oil-filled photonic crystal fiber is demonstrated. The filter is centered at X=1364nm with a bandwidth (FWHM) of 237nm. Tunability is achieved by changing the temperature of the filter. A shift of 210nm of the central wavelength has been observed by...

  2. THz Photonic Band-Gap Prisms Fabricated by Fiber Drawing

    DEFF Research Database (Denmark)

    Busch, Stefan F.; Xu, Lipeng; Stecher, Matthias;

    2012-01-01

    We suggest a novel form of polymeric based 3D photonic crystal prisms for THz frequencies which could be fabricated using a standard fiber drawing technique. The structures are modeled and designed using a finite element analyzing technique. Using this simulation software we theoretically study...... their performance....

  3. Picosecond pump-probe measurement of bandgap changes in SiO2/TiO2 one-dimensional photonic bandgap structures

    Science.gov (United States)

    Hwang, Jisoo; Kim, Min Jung; Wu, J. W.; Mook Lee, Seung; Rhee, Bum Ku

    2006-02-01

    A picosecond pump-probe nonlinear optical measurement is performed in SiO2/TiO2 one-dimensional photonic bandgap structures fabricated by a solgel method. Both high and low band edges were examined by varying the probe wavelengths and angle tuning was also employed to further clarify the mechanism of a nonlinear optical response. The third-order nonlinear optical response in one-dimensional photonic bandgap structures that comprise TiO2 films is responsible for the nonlinear optical transmissions at both bandgap edges, with an 8% decrease at the low-energy edge and a 4.5% increase at the high-energy edge for a 355 nm pump intensity of 430 MW/cm2.

  4. Polarization-maintaining fiber pulse compressor by birefringent hollow-core photonic bandgap fiber.

    Science.gov (United States)

    Shirakawa, Akira; Tanisho, Motoyuki; Ueda, Ken-Ichi

    2006-12-11

    Structural birefringent properties of a hollow-core photonic-bandgap fiber were carefully investigated and applied to all-fiber chirped-pulse amplification as a compressor. The group birefringence of as high as 6.9x10(-4) and the dispersion splitting by as large as 149 ps/nm/km between the two principal polarization modes were observed at 1557 nm. By launching the amplifier output to one of the polarization modes a 17-dB polarization extinction ratio was obtained without any pulse degradation originating from polarization-mode dispersion. A hybrid fiber stretcher effectively compensates the peculiar dispersion of the photonic-bandgap fiber and pedestal-free 440-fs pulses with a 1-W average power and 21-nJ pulse energy were obtained. Polarization-maintaining fiber-pigtail output of high-power femtosecond pulses is useful for various applications. PMID:19529631

  5. Broadband orbital angular momentum transmission using a hollow-core photonic bandgap fiber.

    Science.gov (United States)

    Li, Haisu; Ren, Guobin; Lian, Yudong; Zhu, Bofeng; Tang, Min; Zhao, Yuanchu; Jian, Shuisheng

    2016-08-01

    We present the viability of exploiting a current hollow-core photonic bandgap fiber (HC-PBGF) to support orbital angular momentum (OAM) states. The photonic bandgap intrinsically provides a large refractive index spacing for guiding light, leading to OAM transmission with low crosstalk. From numerical simulations, a broad OAM±1 mode transmission window with satisfied effective index separations between vector modes (>10-4) and low confinement loss (power weight for OAM mode) is found to be affected by the modal effective area. Simulation results also show HC-PBGF based OAM transmission is immune to fabrication inaccuracies near the hollow core. This work illustrates that HC-PBGF is a competitive candidate for high-capacity communication harnessing OAM multiplexing. PMID:27472626

  6. Dipole Emission In Finite Photonic Band-Gap Structures an Exactly Solvable One-Dimensional Model

    CERN Document Server

    Dowling, J P

    1999-01-01

    I consider an exact model of atomic spontaneous dipole emission and classical dipole radiation in a finite photonic band-gap structure. The full 3D or 2D problem is reduced to a finite 1D model, and then this is solved for analytically using algebraic matrix transfer techniques. The results give insight to the electromagnetic emission process in periodic dielectrics, quantitative predictions for emission in 1D dielectric stacks, and qualitative formulas for the 2D and 3D problem.

  7. Bandgap Engineering of Double Perovskites for One- and Two-photon Water Splitting

    DEFF Research Database (Denmark)

    Castelli, Ivano Eligio; Thygesen, Kristian Sommer; Jacobsen, Karsten Wedel

    2013-01-01

    Computational screening is becoming increasingly useful in the search for new materials. We are interested in the design of new semiconductors to be used for light harvesting in a photoelectrochemical cell. In the present paper, we study the double perovskite structures obtained by combining 46...... the volume has an effect on the size of the bandgap. In addition, we suggest some new candidate materials that can be used as photocatalysts in one- and two-photon water splitting devices....

  8. Transparency and Strong Gain Without Population Inversion in Photonic Bandgap Crystals

    Institute of Scientific and Technical Information of China (English)

    杜春光; 胡正峰; 侯春风; 李师群

    2002-01-01

    Without using the weak-field approximation, we investigate the transient properties of a Λ-type atom with one transition near resonant with a photonic bandgap edge. Whatever the initial state of the atom is, the atom can become transparent to a probefield, and strong gain without population inversion is also possible if the atom has been pre-excited. The defect mode formed by atomic doping can have a strong effect on the absorption properties of the atom.

  9. Continuous generation of Rubidium vapor in hollow-core photonic band-gap fibers

    CERN Document Server

    Donvalkar, Prathamesh S; Clemmen, Stephane; Gaeta, Alexander L

    2015-01-01

    We demonstrate high optical depths (50+/-5), lasting for hours in Rubidium-filled hollow-core photonic band-gap fibers, which represents a 1000X improvement over operation times previously reported. We investigate the vapor generation mechanism using both a continuous-wave and a pulsed light source and find that the mechanism for generating the Rubidium atoms is primarily due to thermal vaporization. Continuous generation of large vapor densities should enable measurements at the single-photon level by averaging over longer time scales.

  10. Low-temperature fabrication of single-crystal ZnO nanopillar photonic bandgap structures

    International Nuclear Information System (INIS)

    We describe the fabrication of single-crystal nanopillars of ZnO in two-dimensional periodic and aperiodic arrays for photonic applications. The structures are defined by a thin polymer template created by e-beam lithography and are grown at 90 deg. C using an electrochemical process. The individual single-crystal ZnO pillars have diameters of ∼120 nm and lengths greater than 1 μm. Visible light diffraction patterns from the ordered arrays were observed, and the in-plane photonic bandgap was characterized

  11. All-optical modulation in dye-doped nematic liquid crystal photonic bandgap fibers

    DEFF Research Database (Denmark)

    Alkeskjold, Thomas Tanggaard; Lægsgaard, Jesper; Bjarklev, Anders Overgaard;

    2004-01-01

    Photonic crystal fibers (PCFs) have attracted significant attention during the last years and much research has been devoted to develop fiber designs for various applications, hereunder tunable fiber devices. Recently, thermally and electrically tunable PCF devices based on liquid crystals (LCs......) have been demonstrated. However, optical tuning of the LC PCF has until now not been demonstrated. Here we demonstrate an all-optical modulator, which utilizes a pulsed 532nm laser to modulate the spectral position of the bandgaps in a photonic crystal fiber infiltrated with a dye-doped nematic liquid...

  12. Design of mid-IR and THz quantum cascade laser cavities with complete TM photonic bandgap

    CERN Document Server

    Bahriz, Michael; Moreau, Virginie; Colombelli, Raffaele; Painter, Oskar; 10.1364/OE.15.005948

    2009-01-01

    We present the design of mid-infrared and THz quantum cascade laser cavities formed from planar photonic crystals with a complete in-plane photonic bandgap. The design is based on a honeycomb lattice, and achieves a full in-plane photonic gap for transverse-magnetic polarized light while preserving a connected pattern for efficient electrical injection. Candidate defects modes for lasing are identified. This lattice is then used as a model system to demonstrate a novel effect: under certain conditions - that are typically satisfied in the THz range - a complete photonic gap can be obtained by the sole patterning of the top metal contact. This possibility greatly reduces the required fabrication complexity and avoids potential damage of the semiconductor active region.

  13. Non-resonant below-bandgap two-photon absorption in quantum dot solar cells

    Energy Technology Data Exchange (ETDEWEB)

    Li, Tian; Dagenais, Mario, E-mail: dage@ece.umd.edu [Department of Electrical and Computer Engineering, University of Maryland, College Park, Maryland 20742 (United States)

    2015-04-27

    We study the optically nonlinear sub-bandgap photocurrent generation facilitated by an extended tailing distribution of states in an InAs/GaAs quantum dots (QDs) solar cell. The tailing states function as both the energy states for low energy photon absorption and the photocarriers extraction pathway. One of the biggest advantages of our method is that it can clearly differentiate the photocurrent due to one-photon absorption (1PA) process and two-photon absorption (2PA) process. Both 1PA and 2PA photocurrent generation efficiency in an InAs/GaAs QD device operated at 1550 nm have been quantitatively evaluated. A two-photon absorption coefficient β = 5.7 cm/GW is extracted.

  14. Stability and bandgaps of layered perovskites for one- and two-photon water splitting

    International Nuclear Information System (INIS)

    Direct production of hydrogen from water and sunlight requires stable and abundantly available semiconductors with well positioned band edges relative to the water red-ox potentials. We have used density functional theory (DFT) calculations to investigate 300 oxides and oxynitrides in the Ruddlesden–Popper phase of the layered perovskite structure. Based on screening criteria for the stability, bandgaps and band edge positions, we suggest 20 new materials for the light harvesting photo-electrode of a one-photon water splitting device and 5 anode materials for a two-photon device with silicon as photo-cathode. In addition, we explore a simple rule relating the bandgap of the perovskite to the number of octahedra in the layered structure and the B-metal ion. Finally, the quality of the GLLB-SC potential used to obtain the bandgaps, including the derivative discontinuity, is validated against G0W0@LDA gaps for 20 previously identified oxides and oxynitrides in the cubic perovskite structure. (paper)

  15. Stability and bandgaps of layered perovskites for one- and two-photon water splitting

    Science.gov (United States)

    Castelli, Ivano E.; María García-Lastra, Juan; Hüser, Falco; Thygesen, Kristian S.; Jacobsen, Karsten W.

    2013-10-01

    Direct production of hydrogen from water and sunlight requires stable and abundantly available semiconductors with well positioned band edges relative to the water red-ox potentials. We have used density functional theory (DFT) calculations to investigate 300 oxides and oxynitrides in the Ruddlesden-Popper phase of the layered perovskite structure. Based on screening criteria for the stability, bandgaps and band edge positions, we suggest 20 new materials for the light harvesting photo-electrode of a one-photon water splitting device and 5 anode materials for a two-photon device with silicon as photo-cathode. In addition, we explore a simple rule relating the bandgap of the perovskite to the number of octahedra in the layered structure and the B-metal ion. Finally, the quality of the GLLB-SC potential used to obtain the bandgaps, including the derivative discontinuity, is validated against G0W0@LDA gaps for 20 previously identified oxides and oxynitrides in the cubic perovskite structure.

  16. Broadband optically controlled switching effect in a microfluid-filled photonic bandgap fiber

    Science.gov (United States)

    Guo, Junqi; Liu, Yan-ge; Wang, Zhi; Luo, Mingming; Huang, Wei; Han, Tingting; Liu, Xiaoqi

    2016-05-01

    Broadband optically controlled switching in a microfluid-filled photonic bandgap fiber (MF-PBGF) was observed and investigated. The MF-PBGF was formed by infusing a temperature-sensitive high-index fluid into all of the cladding holes of a microstructured optical fiber (MOF). The fiber was then side pumped with a 532 nm continuous wave laser. An extinction ratio of greater than 20 dB at most of the bandgap wavelengths (more than 200 nm) was obtained with a switching power of ∼147 mW. Theoretical and experimental investigations revealed that the effect originated from changes in the temperature gradient induced by heat absorption of the fiber coating with laser illumination. These investigations offer a new and simple approach to achieve wideband and flexible all-optical fiber switching devices without using any photosensitive materials.

  17. Microstructured and Photonic Bandgap Fibers for Applications in the Resonant Bio- and Chemical Sensors

    Directory of Open Access Journals (Sweden)

    Maksim Skorobogatiy

    2009-01-01

    Full Text Available We review application of microstructured and photonic bandgap fibers for designing resonant optical sensors of changes in the value of analyte refractive index. This research subject has recently invoked much attention due to development of novel fiber types, as well as due to development of techniques for the activation of fiber microstructure with functional materials. Particularly, we consider two sensors types. The first sensor type employs hollow core photonic bandgap fibers where core guided mode is confined in the analyte filled core through resonant effect in the surrounding periodic reflector. The second sensor type employs metalized microstructured or photonic bandgap waveguides and fibers, where core guided mode is phase matched with a plasmon propagating at the fiber/analyte interface. In resonant sensors one typically employs fibers with strongly nonuniform spectral transmission characteristics that are sensitive to changes in the real part of the analyte refractive index. Moreover, if narrow absorption lines are present in the analyte transmission spectrum, due to Kramers-Kronig relation this will also result in strong variation in the real part of the refractive index in the vicinity of an absorption line. Therefore, resonant sensors allow detection of minute changes both in the real part of the analyte refractive index (10−6–10−4 RIU, as well as in the imaginary part of the analyte refractive index in the vicinity of absorption lines. In the following we detail various resonant sensor implementations, modes of operation, as well as analysis of sensitivities for some of the common transduction mechanisms for bio- and chemical sensing applications. Sensor designs considered in this review span spectral operation regions from the visible to terahertz.

  18. Millijoule Pulse Energy Second Harmonic Generation With Single-Stage Photonic Bandgap Rod Fiber Laser

    DEFF Research Database (Denmark)

    Laurila, Marko; Saby, Julien; Alkeskjold, Thomas Tanggaard; Scolari, Lara; Cocquelin, Benjamin; Salin, Francois; Broeng, Jes; Lægsgaard, Jesper

    2011-01-01

    In this paper, we demonstrate, for the first time, a single-stage Q-switched single-mode (SM) ytterbium-doped rod fiber laser delivering record breaking pulse energies at visible and UV light. We use a photonic bandgap rod fiber with a mode field diameter of 59μm based on a new distributed......-mode-filtering (DMF) fiber design, where germanium-doped high-index inclusions are added in order to enable efficient suppression of higher order modes. The rod fiber design is illustrated....

  19. Metallic Photonic Bandgap Resonant Antennas with High Directivity and High Radiation Resistance

    Institute of Scientific and Technical Information of China (English)

    林青春; 符建; 何赛灵; 章坚武

    2002-01-01

    A metallic photonic bandgap (MPBG) resonant antenna is introduced, which has novel characteristics (such as high directivity and high radiation resistance for a certain range of frequencies) as compared to conventional MPBG antennas. The linear MPBG resonant antenna is formed by infinitely long metallic rods in vacuum. The numerical results for the radiation pattern and the radiation resistance are presented. By adjusting the struct ure of the MPBG resonant antenna and its working frequency, an optimal structure is achieved. The physical reasons for the novel characteristics of the MPBG resonant antenna are also explained.

  20. X-ray spontaneous emission control by 1-dimensional photonic bandgap structure

    OpenAIRE

    André, Jean-Michel; Jonnard, Philippe

    2010-01-01

    Paper available at http://epjd.edpsciences.org/index.php?option=com_article&access=standard&Itemid=129&url=/articles/epjd/abs/2010/06/d09549/d09549.html International audience The possibility of controlling the X-ray spontaneous emission of atoms embedded in a 1-dimensional photonic bandgap structure by the so-called Purcell effect, is studied. Calculations of the spontaneously emitted power are presented from Fermi's golden rule in the framework of the Wigner-time approach extended to ...

  1. High-directivity planar antenna using controllable photonic bandgap material at microwave frequencies

    International Nuclear Information System (INIS)

    In this letter, we experimentally demonstrate the capability of a controllable photonic bandgap (CPBG) material to conform the emitted radiation of a planar antenna at 12 GHz. The CPBG material is a variable conductance lattice fabricated with high-frequency PIN diodes soldered along metallic stripes on dielectric printed boards. Depending on the diode bias, the emitted radiation of the antenna can be either transmitted or totally reflected by the material. In the transmission state, the antenna radiation is spatially filtered by the CPBG material in a sharp beam perpendicular to the surface of the material. [copyright] 2001 American Institute of Physics

  2. Compression of realistic laser pulses in hollow-core photonic bandgap fibers

    DEFF Research Database (Denmark)

    Lægsgaard, Jesper; Roberts, John

    2009-01-01

    Dispersive compression of chirped few-picosecond pulses at the microjoule level in a hollow-core photonic bandgap fiber is studied numerically. The performance of ideal parabolic input pulses is compared to pulses from a narrowband picosecond oscillator broadened by self-phase modulation during...... power, duration, and bandwidth. The same conclusion is found for the peak power and energy of solitons formed beyond the point of maximal compression. Long-pass filtering of these solitons is shown to be a promising route to clean solitonlike output pulses with peak powers of several MW....

  3. Low index-contrast photonic bandgap fiber for transmission of short pulsed light

    DEFF Research Database (Denmark)

    Riishede, Jesper; Lægsgaard, Jesper; Broeng, Jes;

    2004-01-01

    The use of low-index-contrast photonic bandgap (PBG) fiber for transmission of short pulsed light is discussed. PBG fibers have positive waveguide dispersion at long wavelengths at which conventional index-guiding fibers have negative waveguide dispersion. PBG fibers with low-index contrast can be...... used to obtain fibers with zero dispersion and a large mode area below 800 nm$+3$/. The results show that the PBG fiber is less sensitive to nonlinear effects and allows transmission of considerably larger intensities....

  4. Analysis of photonic band-gap (PBG) structures using the FDTD method

    DEFF Research Database (Denmark)

    Tong, M.S.; Cheng, M.; Lu, Y.L.;

    2004-01-01

    In this paper, a number of photonic band-gap (PBG) structures, which are formed by periodic circuit elements printed oil transmission-line circuits, are studied by using a well-known numerical method, the finite-difference time-domain (FDTD) method. The results validate the band-stop filter...... behavior of these structures, and the computed results generally match well with ones published in the literature. It is also found that the FDTD method is a robust, versatile, and powerful numerical technique to perform such numerical studies. The proposed PBG filter structures may be applied in microwave...

  5. Photonic band-gap fiber gas cell fabricated using femtosecond micromachining.

    Science.gov (United States)

    Hensley, Christopher; Broaddus, Daniel H; Schaffer, Chris B; Gaeta, Alexander L

    2007-05-28

    Femtosecond laser drilling is used to produce a variablepressure fiber gas cell. Tightly focused laser pulses are used to produce micrometer-diameter radial channels in a hollow-core photonic band-gap fiber (HC-PBGF), and through these microchannels the core of the fiber is filled with a gas. The fiber cell is formed by fusion splicing and sealing the ends of the HC-PBGF to standard step-index fiber. As a demonstration, acetylene is introduced into an evacuated fiber at multiple backing pressures and spectra are measured. PMID:19546979

  6. Scattering loss analysis and structure optimization of hollow-core photonic bandgap fiber

    Science.gov (United States)

    Song, Jingming; Wu, Rong; Sun, Kang; Xu, Xiaoliang

    2016-06-01

    Effects of core structure in 7 cell hollow-core photonic bandgap fibers (HC-PBGFs) on scattering loss are analyzed by means of investigating normalized interface field intensity. Fibers with different core wall thickness, core radius and rounding corner of air hole are simulated. Results show that with thick core wall and expanded core radius, scattering loss could be greatly reduced. The scattering loss of the HC-PBGFs in the wavelength range of 1.5-1.56 μm could be decreased by about 50 % of the present level with optimized core structure design.

  7. Bandgap characteristics of 2D plasma photonic crystal with oblique incidence: TM case

    Institute of Scientific and Technical Information of China (English)

    Xie Ying-Tao; Yang Li-Xia

    2011-01-01

    A novel periodic boundary condition (PBC), that is the constant transverse wavenumber (CTW) method, is introduced to solve the time delay in the transverse plane with oblique incidence. Based on the novel PBC, the FDTD/PBC algorithm is proposed to study periodic structure consisting of plasma and vacuum. Then the reflection coefficient for the plasma slab from the FDTD/PBC algorithm is compared with the analytic results to show the validity of our technique. Finally, the reflection coefficients for the plasma photonic crystals are calculated using the FDTD/PBC algorithm to study the variation of bandgap characteristics with the incident angle and the plasma parameters. Thus it has provided the guiding sense for the actual manufacturing plasma photonic crystal.

  8. Robust topology optimization of three-dimensional photonic-crystal band-gap structures

    CERN Document Server

    Men, Han; Freund, Robert M; Peraire, Jaime; Johnson, Steven G

    2014-01-01

    We perform full 3D topology optimization (in which "every voxel" of the unit cell is a degree of freedom) of photonic-crystal structures in order to find optimal omnidirectional band gaps for various symmetry groups, including fcc (including diamond), bcc, and simple-cubic lattices. Even without imposing the constraints of any fabrication process, the resulting optimal gaps are only slightly larger than previous hand designs, suggesting that current photonic crystals are nearly optimal in this respect. However, optimization can discover new structures, e.g. a new fcc structure with the same symmetry but slightly larger gap than the well known inverse opal, which may offer new degrees of freedom to future fabrication technologies. Furthermore, our band-gap optimization is an illustration of a computational approach to 3D dispersion engineering which is applicable to many other problems in optics, based on a novel semidefinite-program formulation for nonconvex eigenvalue optimization combined with other techniq...

  9. Slow-light effect in a silicon photonic crystal waveguide as a sub-bandgap photodiode.

    Science.gov (United States)

    Terada, Yosuke; Miyasaka, Kenji; Ito, Hiroyuki; Baba, Toshihiko

    2016-01-15

    We demonstrate a Si sub-bandgap photodiode in a photonic crystal slow-light waveguide that operates at telecom wavelengths and can be fabricated using a Ge-free, standard Si-photonics CMOS process. In photodiodes based on absorption via mid-bandgap states, the slow-light enhancement enables performance that is well balanced among high responsivity, low dark current, high speed, wide working spectrum, and CMOS-process compatibility, all of which are otherwise difficult to achieve simultaneously. Owing to the slow-light effect and supplemental gain at a high reverse bias, the photodiode shows a responsivity of 0.15  A/W with a low dark current of 40 nA, which is attributed to no particular processes such as ion implantation and excess exposure of the Si surface. The maximum responsivity was 0.36  A/W. The modest gain allows for sufficient frequency bandwidth to observe an eye opening at up to 30  Gb/s. PMID:26766696

  10. Threshold for formation of atom-photon bound states in a coherent photonic band-gap reservoir

    Science.gov (United States)

    Wu, Yunan; Wang, Jing; Zhang, Hanzhuang

    2016-05-01

    We study the threshold for the formation of atom-photon bound (APB) states from a two-level atom embedded in a coherent photonic band-gap (PBG) reservoir. It is shown that the embedded position of the atom plays an important role in the threshold. By varying the atomic embedded position, a part of formation range of APB states can be moved from inside to outside the band gap. The direct link between the steady-state entanglement and APB states is also investigated. We show that the values of entanglement between reservoir modes reflect the amount of bounded energy caused by APB states. The feasible experimental systems for verifying the above phenomena are discussed. Our results provide a clear clue on how to form and control APB states in PBG materials.

  11. Continuously tunable devices based on electrical control of dual-frequency liquid crystal filled photonic bandgap fibers

    DEFF Research Database (Denmark)

    Scolari, Lara; Alkeskjold, Thomas Tanggaard; Riishede, Jesper;

    2005-01-01

    We present an electrically controlled photonic bandgap fiber device obtained by infiltrating the air holes of a photonic crystal fiber (PCF) with a dual-frequency liquid crystal (LC) with pre-tilted molecules. Compared to previously demonstrated devices of this kind, the main new feature of this...... one is its continuous tunability due to the fact that the used LC does not exhibit reverse tilt domain defects and threshold effects. Furthermore, the dual-frequency features of the LC enables electrical control of the spectral position of the bandgaps towards both shorter and longer wavelengths in...

  12. Simulation Design for Rutile-TiO2 Nanostructures with a Large Complete-Photonic Bandgap in Electrolytes

    Directory of Open Access Journals (Sweden)

    Toshihiro Isobe

    2012-10-01

    Full Text Available The photonic bands of various TiO2 2D photonic crystals, i.e., cylindrical, square and hexagonal columns connected with/without walls and filled with acetonitrile, were investigated from the perspective of dye-sensitized solar cells. The finite-difference time-domain methods revealed that two-dimensional (2D photonic crystals with rods connected with walls composed of TiO2 and electrolytes had complete photonic band gaps under specific conditions. This optimally designed bandgap reaches a large Δω/ωmid value, 1.9%, in a triangular array of square rods connected with walls, which is the largest complete 2D bandgap thus far reported for a photochemical system. These discoveries would promote the photochemical applications of photonic crystals.

  13. Using microwave and macroscopic samples of dielectric solids to study the photonic properties of disordered photonic bandgap materials.

    Science.gov (United States)

    Hashemizad, Seyed Reza; Tsitrin, Sam; Yadak, Polin; He, Yingquan; Cuneo, Daniel; Williamson, Eric Paul; Liner, Devin; Man, Weining

    2014-01-01

    Recently, disordered photonic materials have been suggested as an alternative to periodic crystals for the formation of a complete photonic bandgap (PBG). In this article we will describe the methods for constructing and characterizing macroscopic disordered photonic structures using microwaves. The microwave regime offers the most convenient experimental sample size to build and test PBG media. Easily manipulated dielectric lattice components extend flexibility in building various 2D structures on top of pre-printed plastic templates. Once built, the structures could be quickly modified with point and line defects to make freeform waveguides and filters. Testing is done using a widely available Vector Network Analyzer and pairs of microwave horn antennas. Due to the scale invariance property of electromagnetic fields, the results we obtained in the microwave region can be directly applied to infrared and optical regions. Our approach is simple but delivers exciting new insight into the nature of light and disordered matter interaction. Our representative results include the first experimental demonstration of the existence of a complete and isotropic PBG in a two-dimensional (2D) hyperuniform disordered dielectric structure. Additionally we demonstrate experimentally the ability of this novel photonic structure to guide electromagnetic waves (EM) through freeform waveguides of arbitrary shape. PMID:25285416

  14. Transmission and Propagation of an Accelerating Mode in a Photonic Bandgap Fiber

    Energy Technology Data Exchange (ETDEWEB)

    Ng, C.-K.; England, R.J.; Lee, L.-Q.; Noble, R.; Rawat, V.; Spencer, J.; /SLAC

    2010-08-26

    A hollow core photonic bandgap (PBG) lattice in a dielectric fiber can provide high gradient acceleration in the optical regime, where the accelerating mode resulting from a defect in the PBG fiber can be excited by high-power lasers. Efficient methods of coupling laser power into the PBG fiber are an area of active research. In this paper, we develop a simulation method using the parallel finite-element electromagnetic suite ACE3P to study the propagation of the accelerating mode in the PBG fiber and determine the radiation pattern into free space at the end of the PBG fiber. The far-field radiation will be calculated and the mechanism of coupling power from an experimental laser setup will be discussed.

  15. Applied electric field to fabricate colloidal crystals with the photonic band-gap in communication waveband

    International Nuclear Information System (INIS)

    The macropore silica colloidal crystal templates were assembled orderly in a capillary glass tube by an applied electric field method to control silica deposition. In order to achieve the photonic band gap (PBG) of colloidal crystal in optical communication waveband, the diameter of silica microspheres is selected by Bragg diffraction formula. An experiment was designed to test the bandgap of the silica crystal templates. This paper discusses the formation process and the close-packed fashion of the silica colloidal crystal templates was discussed. The surface morphology of the templates was also analyzed. The results showed that the close-packed fashion of silica array templates was face-centered cubic (FCC) structure. The agreement is very good between the experimental data and the theoretical calculation

  16. Applied electric field to fabricate colloidal crystals with the photonic band-gap in communication waveband

    Institute of Scientific and Technical Information of China (English)

    Yan Hai-Tao; Wang Ming; Ge Yi-Xian; Yu Ping

    2009-01-01

    The macropore silica colloidal crystal templates were assembled orderly in a capillary glass tube by an applied electric field method to control silica deposition. In order to achieve the photonic band gap (PBG) of colloidal crystal in optical communication waveband, the diameter of silica microspheres is selected by Bragg diffraction formula. An experiment was designed to test the bandgap of the silica crystal templates. This paper discusses the formation process and the close-packed fashion of the silica colloidal crystal templates was discussed. The surface morphology of the templates was also analyzed. The results showed that the close-packed fashion of silica array templates was face-centered cubic (FCC) structure. The agreement is very good between the experimental data and the theoretical calculation.

  17. Air-Guiding Photonic Bandgap Fibers: Spectral Properties, Macrobending Loss, and Practical Handling

    DEFF Research Database (Denmark)

    Hansen, Theis Peter; Broeng, Jes; Jakobsen, Christian; Vienne, Guillaume; Simonsen, Harald R.; Nielsen, Martin Dybendal; Skovgaard, Peter M.W.; Folkenberg, Jacob Riis; Bjarklev, Anders Overgaard

    2004-01-01

    For development of hollow-core transmission fibers, the realizable fibers lengths, bandwidth, characterization, and compatibility with standard technology are important issues. We report record-length air-guiding fiber, spectral properties, splicing, and optical time domain reflectometer (OTDR) m......) measurements. Furthermore, spectral macrobending loss measurements for two different designs of air-core photonic bandgap fibers are presented. While bending loss is observed, it does not limit operation for all practical bending diameters (>tex/tex......For development of hollow-core transmission fibers, the realizable fibers lengths, bandwidth, characterization, and compatibility with standard technology are important issues. We report record-length air-guiding fiber, spectral properties, splicing, and optical time domain reflectometer (OTDR...

  18. SU-8 process optimization for high fiber coupling efficiency of liquid crystal filled photonic bandgap fiber components

    DEFF Research Database (Denmark)

    Wei, Lei; Alkeskjold, Thomas Tanggaard; Bjarklev, Anders Overgaard

    2009-01-01

    SU-8 structures are built up to increase the fiber coupling efficiency of liquid crystal photonic bandgap fiber components. The resolution reduction of UV exposure is minimized to 4%, and insertion loss is reduced to 2.7dB....

  19. Experimental high gradient testing of a 17.1 GHz photonic band-gap accelerator structure

    Science.gov (United States)

    Munroe, Brian J.; Zhang, JieXi; Xu, Haoran; Shapiro, Michael A.; Temkin, Richard J.

    2016-03-01

    We report the design, fabrication, and high gradient testing of a 17.1 GHz photonic band-gap (PBG) accelerator structure. Photonic band-gap (PBG) structures are promising candidates for electron accelerators capable of high-gradient operation because they have the inherent damping of high order modes required to avoid beam breakup instabilities. The 17.1 GHz PBG structure tested was a single cell structure composed of a triangular array of round copper rods of radius 1.45 mm spaced by 8.05 mm. The test assembly consisted of the test PBG cell located between conventional (pillbox) input and output cells, with input power of up to 4 MW from a klystron supplied via a TM01 mode launcher. Breakdown at high gradient was observed by diagnostics including reflected power, downstream and upstream current monitors and visible light emission. The testing procedure was first benchmarked with a conventional disc-loaded waveguide structure, which reached a gradient of 87 MV /m at a breakdown probability of 1.19 ×10-1 per pulse per meter. The PBG structure was tested with 100 ns pulses at gradient levels of less than 90 MV /m in order to limit the surface temperature rise to 120 K. The PBG structure reached up to 89 MV /m at a breakdown probability of 1.09 ×10-1 per pulse per meter. These test results show that a PBG structure can simultaneously operate at high gradients and low breakdown probability, while also providing wakefield damping.

  20. Continuously tunable all-in-fiber devices based on thermal and electrical control of negative dielectric anisotropy liquid crystal photonic bandgap fibers

    DEFF Research Database (Denmark)

    Wei, Lei; Eskildsen, Lars; Weirich, Johannes;

    2009-01-01

    We infiltrate photonic crystal fibers with a negative dielectric anisotropy liquid crystal. 396nm bandgap shift is obtained in the temperature range 22°C-80°C, and 67 nm shift of long-wavelength bandgap edge is achieved by applying a voltage of 200Vrms. The polarization sensitivity and correspond......We infiltrate photonic crystal fibers with a negative dielectric anisotropy liquid crystal. 396nm bandgap shift is obtained in the temperature range 22°C-80°C, and 67 nm shift of long-wavelength bandgap edge is achieved by applying a voltage of 200Vrms. The polarization sensitivity and...

  1. Hyperuniform disordered photonic bandgap materials, from microwave to infrared wavelength regime

    Science.gov (United States)

    Man, Weining

    Recently, we have introduced a new class of hyperuniform disordered (HUD) photonic bandgap (PBG) materials enabled by a novel constrained optimization method for engineering the material's Fourier transform to be continuous, isotropic and stealthy. Their structure factor S (k) is equal to zero for small kand exhibits a broad ring of maximum values around a characteristic wave-length range. Experimentally, an isotropic complete PBG (at all angles and for all polarizations) in an alumina-based HUD structure and single-polarized PBGs for plastic-based HUD structure have been demonstrated. Using measured and simulated transmission and phase delay information through these HUD structures, we also unfolded their band structures and reconstructed the effective dispersion relations of propagating electromagnetic modes in them. The intrinsic isotropy in these disordered structures is an inherent advantage associated with the lack of crystalline order, offering unprecedented freedom for functional defect design impossible to achieve in photonic crystals. In the microwave regime, we have shown the creation of freeform waveguides, which can channel photons robustly along arbitrarily curved paths and around sharp bends, and be decorated with defects to produce sharply resonant structures useful for filtering and frequency splitting. Recent simulation and experimental results for waveguides and modulators based on submicron-scale planar hyperuniform disordered PBG structures further highlight their ability to serve as highly compact, flexible and energy-efficient platforms for photonic integrated circuits. NSF DMR-1308084, EPSRC (UK) DTG Grant KD5050, EPSRC (UK) Strategic Equipment Grant EP/M008576/1, NSF SBIR-1345168, NSF MRI-1040444.

  2. Monolithic Yb-fiber femtosecond laser with intracavity all-solid PBG fiber and ex-cavity HC-PCF

    DEFF Research Database (Denmark)

    Turchinovich, Dmitry; Liu, Xiaomin; Lægsgaard, Jesper

    2010-01-01

    (PM) photonic bandgap fiber (PBG) is used in the cavity of the master oscillator for dispersion compensation and stabilization of modelocking. The final compression of an chirped-pulse-amplified laser signal is performed in a hollow PM PCF, yielding final fiber-delivered pulse energy of around 7 n......We demonstrate an all-fiber femtosecond master oscillator / power amplifier operating at the central wavelength of 1033 nm, based on Yb-doped fiber as gain medium, and two different kinds of photonic crystal fibers for dispersion control and stabilization. An all-solid (AS) polarization maintaining...

  3. Robust topology optimization of three-dimensional photonic-crystal band-gap structures.

    Science.gov (United States)

    Men, H; Lee, K Y K; Freund, R M; Peraire, J; Johnson, S G

    2014-09-22

    We perform full 3D topology optimization (in which "every voxel" of the unit cell is a degree of freedom) of photonic-crystal structures in order to find optimal omnidirectional band gaps for various symmetry groups, including fcc (including diamond), bcc, and simple-cubic lattices. Even without imposing the constraints of any fabrication process, the resulting optimal gaps are only slightly larger than previous hand designs, suggesting that current photonic crystals are nearly optimal in this respect. However, optimization can discover new structures, e.g. a new fcc structure with the same symmetry but slightly larger gap than the well known inverse opal, which may offer new degrees of freedom to future fabrication technologies. Furthermore, our band-gap optimization is an illustration of a computational approach to 3D dispersion engineering which is applicable to many other problems in optics, based on a novel semidefinite-program formulation for nonconvex eigenvalue optimization combined with other techniques such as a simple approach to impose symmetry constraints. We also demonstrate a technique for robust topology optimization, in which some uncertainty is included in each voxel and we optimize the worst-case gap, and we show that the resulting band gaps have increased robustness to systematic fabrication errors. PMID:25321732

  4. Design of a second cyclotron harmonic gyrotron oscillator with photonic band-gap cavity

    International Nuclear Information System (INIS)

    A photonic band-gap cavity (PBGC) gyrotron with a frequency of about 98 GHz is designed. Theoretical analyses and numerical calculations are made for the PBGC operating at fundamental and second cyclotron harmonic with a TE34 waveguide mode to demonstrate the beam-wave interaction. The results show that mode competition is successfully eliminated in the PBGC using mode selectivity and choosing the appropriate operating parameters. As a result, the second harmonic PBGC gyrotron operating at TE34 mode achieves a higher output efficiency than that of the fundamental. It is also demonstrated that, in the case of the chosen parameters for TE34 waveguide mode, the use of PBG structure in the second harmonic gyrotron brings about not only a lower operating B-field but also a weaker mode competition. The results show that the high-order electromagnetic mode can be developed to interact with the high cyclotron harmonic using the selectivity of the PBGC, which gives an encouraging outlook for the development of high-harmonic gyrotrons.

  5. Compact Design of an Electrically Tunable and Rotatable Polarizer Based on a Liquid Crystal Photonic Bandgap Fiber

    DEFF Research Database (Denmark)

    Wei, Lei; Alkeskjold, Thomas Tanggaard; Bjarklev, Anders Overgaard

    2009-01-01

    In this letter, a compact electrically controlled broadband liquid crystal (LC) photonic bandgap fiber polarizer is designed and fabricated. A good fiber coupling quality between two single-mode fibers and one 10-mm-long LC-filled photonic crystal fiber is obtained and protected by using SU-8 fiber...... fixing structures during the device assembly. The total insertion loss of this all-in-fiber device is 2.7 dB. An electrically tunable polarization extinction ratio of 21.3 dB is achieved with 45$^{circ}$ rotatable transmission axis as well as switched on and off in the wavelength range of 1300–1600 nm....

  6. X-Band Photonic Band-Gap Accelerator Structure Breakdown Experiment

    Energy Technology Data Exchange (ETDEWEB)

    Marsh, Roark A.; /MIT /MIT /NIFS, Gifu /JAERI, Kyoto /LLNL, Livermore; Shapiro, Michael A.; Temkin, Richard J.; /MIT; Dolgashev, Valery A.; Laurent, Lisa L.; Lewandowski, James R.; Yeremian, A.Dian; Tantawi, Sami G.; /SLAC

    2012-06-11

    In order to understand the performance of photonic band-gap (PBG) structures under realistic high gradient, high power, high repetition rate operation, a PBG accelerator structure was designed and tested at X band (11.424 GHz). The structure consisted of a single test cell with matching cells before and after the structure. The design followed principles previously established in testing a series of conventional pillbox structures. The PBG structure was tested at an accelerating gradient of 65 MV/m yielding a breakdown rate of two breakdowns per hour at 60 Hz. An accelerating gradient above 110 MV/m was demonstrated at a higher breakdown rate. Significant pulsed heating occurred on the surface of the inner rods of the PBG structure, with a temperature rise of 85 K estimated when operating in 100 ns pulses at a gradient of 100 MV/m and a surface magnetic field of 890 kA/m. A temperature rise of up to 250 K was estimated for some shots. The iris surfaces, the location of peak electric field, surprisingly had no damage, but the inner rods, the location of the peak magnetic fields and a large temperature rise, had significant damage. Breakdown in accelerator structures is generally understood in terms of electric field effects. These PBG structure results highlight the unexpected role of magnetic fields in breakdown. The hypothesis is presented that the moderate level electric field on the inner rods, about 14 MV/m, is enhanced at small tips and projections caused by pulsed heating, leading to breakdown. Future PBG structures should be built to minimize pulsed surface heating and temperature rise.

  7. A two-dimensional photonic crystal with six large bandgaps formed by a hexagonal lattice of anisotropic cylinders

    Institute of Scientific and Technical Information of China (English)

    庄飞; 吴良; 何赛灵

    2002-01-01

    The plane-wave expansion method is used to calculate the band structure of a two-dimensional photonic crystalformed by a hexagonal structure of anisotropic cylinders. Two cylindrical inclusions in the unit cell have two differentradii, R1 and R2 (Ri<R2). By reducing the symmetry of the structure and choosing appropriately parameters R2and s = R1/R2 (s<1), we obtain six large complete bandgaps, among which three are over 0.05 ωe (where ωe = 2πc/a)in the high region of the normalized frequency (however, one of these over 0.065 ωe is not stable). There are two otherstable complete bandgaps in the low-frequency region.

  8. A two—dimensional photonic crystal with six large bandgaps formed by a hexagonal lattice of anisotropic cylinders

    Institute of Scientific and Technical Information of China (English)

    庄飞; 吴良; 等

    2002-01-01

    The plane-wave expansion method is used to calculate the band structure of a two-dimensional photonic crystal formed by a hexagonal structure of anisotropic cylinders.Two cylindrical inclusions in the unit cell have two different radii,R1 and R2(R1bandgaps,among which three are over 0.05 we(where we=2πc/α)in the high region of the normalized frequency (however,one of these over 0.065 we is not stable).There are two other stable complete bandgaps in the low-frequency region.

  9. Photon absorption and photocurrent in solar cells below semiconductor bandgap due to electron photoemission from plasmonic nanoantennas

    DEFF Research Database (Denmark)

    Novitsky, Andrey; Uskov, Alexander; Gritti, Claudia; Protsenko, I. E.; Kardynal, Beata; Lavrinenko, Andrei

    2014-01-01

    continuous metal films. Optimally designed metal nanoparticles can provide an effectivemechanismfor the photon absorption in the infrared range below the semiconductor bandgap, resulting in the generation of a photocurrent in addition to the photocurrent from band-to-band absorption in a semiconductor. Such......We model the electron photoemission frommetal nanoparticles into a semiconductor in a Schottky diode with a conductive oxide electrode hosting the nanoparticles. We show that plasmonic effects in the nanoparticles lead to a substantial enhancement in photoemission compared with devices with...

  10. Enhancement of room temperature sub-bandgap light emission from silicon photonic crystal nanocavity by Purcell effect

    International Nuclear Information System (INIS)

    We report the enhancement of sub-bandgap photoluminescence from silicon via the Purcell effect. We couple the defect emission from silicon, which is believed to be due to hydrogen incorporation into the lattice, to a photonic crystal (PhC) nanocavity. We observe an up to 300-fold enhancement of the emission at room temperature at 1550 nm, as compared to an unpatterned sample, which is then comparable to the silicon band-edge emission. We discuss the possibility of enhancing this emission even further by introducing additional defects by ion implantation, or by treating the silicon PhC nanocavity with hydrogen plasma.

  11. Amplification and ASE suppression in a polarization-maintaining ytterbium-doped solid-core photonic bandgap fibre

    DEFF Research Database (Denmark)

    Olausson, Christina Bjarnal Thulin; Falk, Charlotte Ijeoma; Lyngsøe, Jens Kristian; Hansen, K.P.; Bjarklev, Anders Overgaard; Broeng, Jes

    2009-01-01

    We demonstrate suppression of amplified spontaneous emission at the conventional ytterbium gain wavelengths around 1030 nm in a cladding-pumped polarization-maintaining ytterbium-doped solid core photonic crystal fibre. The fibre works through combined index and bandgap guiding. Furthermore, we...... show that the peak of the amplified spontaneous emission can be shifted towards longer wavelengths by rescaling the fibre dimensions. Thereby one can obtain lasing or amplification at longer wavelengths (1100 nm - 1200 nm) as the amount of amplification in the fibre is shown to scale with the power of...... the amplified spontaneous emission....

  12. Monolithic femtosecond Yb-fiber laser with photonic crystal fibers

    DEFF Research Database (Denmark)

    Liu, Xiaomin; Lægsgaard, Jesper; Turchinovich, Dmitry

    We demonstrate a monolithic stable SESAM-modelocked self-starting Yb-fiber laser. A novel PM all-solid photonic bandgap fiber is used for intra-cavity of dispersion management. The ex-cavity final pulse compression is performed in a spliced-on PM hollow-core photonic crystal fiber. The laser...

  13. Stability and bandgaps of layered perovskites for one- and two-photon water splitting

    OpenAIRE

    Castelli, Ivano Eligio; García Lastra, Juan Maria; Hüser, Falco; Thygesen, Kristian Sommer; Jacobsen, Karsten Wedel

    2013-01-01

    Direct production of hydrogen from water and sunlight requires stable and abundantly available semiconductors with well positioned band edges relative to the water red-ox potentials. We have used density functional theory (DFT) calculations to investigate 300 oxides and oxynitrides in the Ruddlesden–Popper phase of the layered perovskite structure. Based on screening criteria for the stability, bandgaps and band edge positions, we suggest 20 new materials for the light harvesting photo-electr...

  14. Enhanced chemiluminescent detection scheme for trace vapor sensing in pneumatically-tuned hollow core photonic bandgap fibers.

    Science.gov (United States)

    Stolyarov, Alexander M; Gumennik, Alexander; McDaniel, William; Shapira, Ofer; Schell, Brent; Sorin, Fabien; Kuriki, Ken; Benoit, Gilles; Rose, Aimee; Joannopoulos, John D; Fink, Yoel

    2012-05-21

    We demonstrate an in-fiber gas phase chemical detection architecture in which a chemiluminescent (CL) reaction is spatially and spectrally matched to the core modes of hollow photonic bandgap (PBG) fibers in order to enhance detection efficiency. A peroxide-sensitive CL material is annularly shaped and centered within the fiber's hollow core, thereby increasing the overlap between the emission intensity and the intensity distribution of the low-loss fiber modes. This configuration improves the sensitivity by 0.9 dB/cm compared to coating the material directly on the inner fiber surface, where coupling to both higher loss core modes and cladding modes is enhanced. By integrating the former configuration with a custom-built optofluidic system designed for concomitant controlled vapor delivery and emission measurement, we achieve a limit-of-detection of 100 parts per billion (ppb) for hydrogen peroxide vapor. The PBG fibers are produced by a new fabrication method whereby external gas pressure is used as a control knob to actively tune the transmission bandgaps through the entire visible range during the thermal drawing process. PMID:22714227

  15. Measurement and suppression of secondary waves caused by high-order modes in a photonic bandgap fiber-optic gyroscope.

    Science.gov (United States)

    Xu, Xiaobin; Gao, Fuyu; Song, Ningfang; Jin, Jing

    2016-05-16

    Air-core photonic bandgap fiber (PBF) is a good choice for fiber-optic gyroscopes (FOGs) owing to the fact that it can be adapted to a wide variety of environments. However, its multimode properties are disadvantageous for the application to FOGs. An interference-based method is proposed to precisely determine the secondary waves caused by the high-order modes and their coupling. Based on the method, two groups of secondary waves have been found, having optical path differences (OPDs) of ~1.859 m and ~0.85 m, respectively, relative to the primary waves in a PBFOG that consists of a 7-cell PBF coil, approximately 180 m in length. Multi-turn bends of the PBF at both ends of the PBF coil after the fusion splicing points are shown to suppress the intensity of these secondary waves by approximately 10 dB. PMID:27409849

  16. Simultaneous coupling of surface plasmon resonance and photonic bandgap to InGaAs quantum well emission

    Energy Technology Data Exchange (ETDEWEB)

    Gao, Hongwei [Engineering Product Development, Singapore University of Technology and Design, Singapore 487372 (Singapore); Teng, Jinghua [Institute of Materials Research and Engineering, Singapore 117602 (Singapore); Chua, Soo Jin, E-mail: elecsj@nus.edu.sg [Institute of Materials Research and Engineering, Singapore 117602 (Singapore); Department of Electrical and Computer Engineering, National University of Singapore, Singapore 117576 (Singapore)

    2016-01-07

    A photonic bandgap structure was created on the 100 nm thick GaAs barrier layer with Au nanodisks deposited inside the holes. To mitigate the nonradiative surface recombination of GaAs, the Au nanodisks were formed on top of a 15 nm SiO{sub 2} deposited in the holes. A maximum 7.6-fold increase in photoluminescence intensity was obtained at the etch depth of 80 nm. In this configuration, the Au nanodisk is separated from the quantum well by 20 nm of GaAs and 15 nm of SiO{sub 2}. The experimental result was verified by the simulation based on this structure. There was a good agreement between experiments with simulation results.

  17. Simultaneous coupling of surface plasmon resonance and photonic bandgap to InGaAs quantum well emission

    International Nuclear Information System (INIS)

    A photonic bandgap structure was created on the 100 nm thick GaAs barrier layer with Au nanodisks deposited inside the holes. To mitigate the nonradiative surface recombination of GaAs, the Au nanodisks were formed on top of a 15 nm SiO2 deposited in the holes. A maximum 7.6-fold increase in photoluminescence intensity was obtained at the etch depth of 80 nm. In this configuration, the Au nanodisk is separated from the quantum well by 20 nm of GaAs and 15 nm of SiO2. The experimental result was verified by the simulation based on this structure. There was a good agreement between experiments with simulation results

  18. A 158 fs 5.3 nJ fiber-laser system at 1 mu m using photonic bandgap fibers for dispersion control and pulse compression

    DEFF Research Database (Denmark)

    Nielsen, C.K.; Jespersen, Kim Giessmann; Keiding, S.R.

    2006-01-01

    We demonstrate a 158 fs 5.3 nJ mode-locked laser system based on a fiber oscillator, fiber amplifier and fiber compressor. Dispersion compensation in the fiber oscillator was obtained with a solid-core photonic bandgap (SC-PBG) fiber spliced to standard fibers, and external compression is obtained...

  19. Wide bandgap semiconductors. Fundamental properties and modern photonic and electronic devices

    Energy Technology Data Exchange (ETDEWEB)

    Takahashi, K. [Nippon EMC Ltd. (Japan). R and D Center; Yoshikawa, A. [Chiba Univ. (Japan); Sandhu, A. (eds.) [Tokyo Institute of Technology (Japan)

    2007-07-01

    This book offers a comprehensive overview of the development, current state and future prospects of wide bandgap semiconductor materials and related optoelectronics devices. It includes an overview of recent developments in III-V nitride semiconductors, SiC, diamond, ZnO, II-VI materials and related devices including AIGaN/GaN FET, UV LDs, white light LEDs, and cold electron emitters. With 901 references, 333 figures and 21 tables, this book will serve as a one-stop source of knowledge on wide bandgap semiconductors and related optoelectronics devices. After review of the basic physics of WBGS and the relevance of the physical properties to the development of commercial devices, the book addresses the applications of WBGS devices for solid-state white-light illumination, medicine and gigahertz-high power telecommunications. In addition, description of recent development in the growth and applications of nitride semiconductors are complemented by chapters on the properties and device applications of SiC, diamond thin films, doping of ZnO, II-IVs and the novel BeZnSeTe/BAlGaAs material systems. Practical issues and problems such as the effect of defects on device performance are highlighted and solutions proposed based on recent studies. (orig.)

  20. In vivo imaging of the morphology and changes in pH along the gastrointestinal tract of Japanese medaka by photonic band-gap hydrogel microspheres

    Energy Technology Data Exchange (ETDEWEB)

    Du, Xuemin [Advanced Laboratory for Environmental Research and Technology, USTC-CityU, Suzhou 215123 (China); Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei, Anhui 230026 (China); Centre for Functional Photonics, Department of Biology and Chemistry, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong (China); Lei, Ngai-Yu; Hu, Peng [Centre for Functional Photonics, Department of Biology and Chemistry, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong (China); Lei, Zhang; Ong, Daniel Hock-Chun [Department of Physics, The Chinese University of Hong Kong, Shatin, Hong Kong (China); Ge, Xuewu [Advanced Laboratory for Environmental Research and Technology, USTC-CityU, Suzhou 215123 (China); Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei, Anhui 230026 (China); Zhang, Zhicheng, E-mail: zczhang@ustc.edu.cn [Advanced Laboratory for Environmental Research and Technology, USTC-CityU, Suzhou 215123 (China); Department of Polymer Science and Engineering, University of Science and Technology of China, Hefei, Anhui 230026 (China); Lam, Michael Hon-Wah, E-mail: bhmhwlam@cityu.edu.hk [Advanced Laboratory for Environmental Research and Technology, USTC-CityU, Suzhou 215123 (China); Centre for Functional Photonics, Department of Biology and Chemistry, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong (China)

    2013-07-17

    Graphical abstract: -- Highlights: •Fabrication of pH-responsive photonic colloidal crystalline microspheres. •Specific photonic band-gap responses occurred in the pH range of 4–5. •Remarkably low in vivo toxicity to Japanese medaka (Oryzia latipes). •In vivo imaging of the morphology and pH along GI tract of Japanese medaka. •Demonstrates bio-imaging potentials of stimuli-responsive photonic materials. -- Abstract: Colloidal crystalline microspheres with photonic band-gap properties responsive to media pH have been developed for in vivo imaging purposes. These colloidal crystalline microspheres were constructed from monodispersed core–shell nano-size particles with poly(styrene-co-acrylic acid) (PS-co-PAA) cores and poly(acrylic acid-co-N-isopropylacrylamide) (PAA-co-PNIPAM) hydrogel shells cross-linked by N,N′-methylenebisacrylamide. A significant shift in the photonic band-gap properties of these colloidal crystalline microspheres was observed in the pH range of 4–5. This was caused by the discontinuous volume phase transition of the hydrogel coating, due to the protonation/deprotonation of its acrylic acid moieties, on the core–shell nano-sized particles within the microspheres. The in vivo imaging capability of these pH-responsive photonic microspheres was demonstrated on a test organism – Japanese medaka, Oryzia latipes – in which the morphology and change in pH along their gastrointestinal (GI) tracts were revealed under an ordinary optical microscope. This work illustrates the potential of stimuli-responsive photonic band-gap materials in tissue-/organ-level in vivo bio-imaging.

  1. In vivo imaging of the morphology and changes in pH along the gastrointestinal tract of Japanese medaka by photonic band-gap hydrogel microspheres

    International Nuclear Information System (INIS)

    Graphical abstract: -- Highlights: •Fabrication of pH-responsive photonic colloidal crystalline microspheres. •Specific photonic band-gap responses occurred in the pH range of 4–5. •Remarkably low in vivo toxicity to Japanese medaka (Oryzia latipes). •In vivo imaging of the morphology and pH along GI tract of Japanese medaka. •Demonstrates bio-imaging potentials of stimuli-responsive photonic materials. -- Abstract: Colloidal crystalline microspheres with photonic band-gap properties responsive to media pH have been developed for in vivo imaging purposes. These colloidal crystalline microspheres were constructed from monodispersed core–shell nano-size particles with poly(styrene-co-acrylic acid) (PS-co-PAA) cores and poly(acrylic acid-co-N-isopropylacrylamide) (PAA-co-PNIPAM) hydrogel shells cross-linked by N,N′-methylenebisacrylamide. A significant shift in the photonic band-gap properties of these colloidal crystalline microspheres was observed in the pH range of 4–5. This was caused by the discontinuous volume phase transition of the hydrogel coating, due to the protonation/deprotonation of its acrylic acid moieties, on the core–shell nano-sized particles within the microspheres. The in vivo imaging capability of these pH-responsive photonic microspheres was demonstrated on a test organism – Japanese medaka, Oryzia latipes – in which the morphology and change in pH along their gastrointestinal (GI) tracts were revealed under an ordinary optical microscope. This work illustrates the potential of stimuli-responsive photonic band-gap materials in tissue-/organ-level in vivo bio-imaging

  2. Compact nanocavity with elliptical slot inside photonic wire bandgap materials including sidewalls gratings for biosensing

    Science.gov (United States)

    Daraei, Ahmadreza; Daraei, Mohammad Esmaeil

    2016-07-01

    In this paper, we introduce and propose a compact and multipurpose one-dimensional photonic crystal silicon wire nanocavity (NC) sensor in silicon-on-insulator wafers. A slot with elliptical cross section (SECS) in the center of the NC together with tapered sidewalls grating of photonic wire (PhWr) provides strongly confined photonic modes for the sensing purposes. We have examined and optimized several geometrical parameters of the PhWr and SECS NC theoretically and computationally. Using finite element method, we have operated our computational validation for the variety of designs. Our results have shown strongly confined photonic mode with high quality ( Q) factor ~1.6 × 104, small modal volume, V mod ~ 0.005( λ/ n)3, as well as high sensitivity as 530 nm/RIU simultaneously operating nearly at the telecom window. These results are promising for refractive index-based sensing, e.g., nanobiomaterials.

  3. Robust topology optimization of three-dimensional photonic-crystal band-gap structures

    OpenAIRE

    Men, Han; Lee, Karen Y. K.; Freund, Robert M.; Peraire, Jaime; Johnson, Steven G.

    2014-01-01

    We perform full 3D topology optimization (in which "every voxel" of the unit cell is a degree of freedom) of photonic-crystal structures in order to find optimal omnidirectional band gaps for various symmetry groups, including fcc (including diamond), bcc, and simple-cubic lattices. Even without imposing the constraints of any fabrication process, the resulting optimal gaps are only slightly larger than previous hand designs, suggesting that current photonic crystals are nearly optimal in thi...

  4. Conversion of above- and below-bandgap photons via InAs quantum dot media embedded into GaAs solar cell

    International Nuclear Information System (INIS)

    Quantum dots (QDs) provide photovoltaic conversion of below-bandgap photons due to multistep electron transitions. QDs also increase conversion efficiency of the above-bandgap photons due to extraction of electrons from QDs via Coulomb interaction with hot electrons excited by high-energy photons. Nanoscale potential profile (potential barriers) and nanoscale band engineering (AlGaAs atomically thin barriers) allow for suppression of photoelectron capture to QDs. To study these kinetic effects and to distinguish them from the absorption enhancement due to light scattering on QDs, we investigate long, 3-μm base GaAs devices with various InAs QD media with 20 and 40 QD layers. Quantum efficiency measurements show that, at least at low doping, the multistep processes in QD media are strongly affected by the wetting layer (WL). The QD media with WLs provide substantial conversion of below-bandgap photons and for devices with 40 QD layers the short circuit current reaches 29.2 mA/cm2. The QD media with band-engineered AlGaAs barriers and reduced wetting layers (RWL) enhance conversion of high-energy photons and decrease the relaxation (thermal) losses.

  5. Wide-Band Spatially Tunable Photonic Bandgap in Visible Spectral Range and Laser based on a Polymer Stabilized Blue Phase

    Science.gov (United States)

    Lin, Jia-De; Wang, Tsai-Yen; Mo, Ting-Shan; Huang, Shuan-Yu; Lee, Chia-Rong

    2016-07-01

    This work successfully develops a largely-gradient-pitched polymer-stabilized blue phase (PSBP) photonic bandgap (PBG) device with a wide-band spatial tunability in nearly entire visible region within a wide blue phase (BP) temperature range including room temperature. The device is fabricated based on the reverse diffusion of two injected BP-monomer mixtures with a low and a high chiral concentrations and afterwards through UV-curing. This gradient-pitched PSBP can show a rainbow-like reflection appearance in which the peak wavelength of the PBG can be spatially tuned from the blue to the red regions at room temperature. The total tuning spectral range for the cell is as broad as 165 nm and covers almost the entire visible region. Based on the gradient-pitched PSBP, a spatially tunable laser is also demonstrated in this work. The temperature sensitivity of the lasing wavelength for the laser is negatively linear and approximately ‑0.26 nm/°C. The two devices have a great potential for use in applications of photonic devices and displays because of their multiple advantages, such as wide-band tunability, wide operated temperature range, high stability and reliability, no issue of hysteresis, no need of external controlling sources, and not slow tuning speed (mechanically).

  6. Nonlinear optical sub-bandgap excitation of ZnO-based photonic resonators

    Science.gov (United States)

    Bader, Christina A.; Zeuner, Franziska; Bader, Manuel H. W.; Zentgraf, Thomas; Meier, Cedrik

    2015-12-01

    Zinc oxide (ZnO) is a versatile candidate for photonic devices due to its highly efficient optical emission. However, for pumping of ZnO photonic devices UV-sources are required. Here, we investigate the alternative usage of widely available pulsed near-infrared (NIR)-sources and compare the efficiency of linear and nonlinear excitation processes. We found that bulk ZnO, ZnO thin films grown by molecular beam epitaxy, and ZnO/SiO2 microdisk devices exhibit strong nonlinear response when excited with NIR pulses (λ ≈ 1060 nm). In addition, we show that the ZnO/SiO2 microdisks exhibit sharp whispering gallery modes over the blue-yellow part of the visible spectrum for both excitation conditions and high Q-factors up to Q = 4700. The results demonstrate that nonlinear excitation is an efficient way to pump ZnO photonic devices.

  7. Nonlinear optical sub-bandgap excitation of ZnO-based photonic resonators

    International Nuclear Information System (INIS)

    Zinc oxide (ZnO) is a versatile candidate for photonic devices due to its highly efficient optical emission. However, for pumping of ZnO photonic devices UV-sources are required. Here, we investigate the alternative usage of widely available pulsed near-infrared (NIR)-sources and compare the efficiency of linear and nonlinear excitation processes. We found that bulk ZnO, ZnO thin films grown by molecular beam epitaxy, and ZnO/SiO2 microdisk devices exhibit strong nonlinear response when excited with NIR pulses (λ ≈ 1060 nm). In addition, we show that the ZnO/SiO2 microdisks exhibit sharp whispering gallery modes over the blue-yellow part of the visible spectrum for both excitation conditions and high Q-factors up to Q = 4700. The results demonstrate that nonlinear excitation is an efficient way to pump ZnO photonic devices

  8. Two-Dimensional Photonic Band-Gap Defect Modes with Deformed Lattice

    Institute of Scientific and Technical Information of China (English)

    CAI Xiang-Hua; ZHENG Wan-Hua; MA Xiao-Tao; REN Gang; XIA Jian-Bai

    2005-01-01

    @@ A numerical study of the defect modes in two-dimensional photonic crystals with deformed triangular lattice is presented by using the supercell method and the finite-difference time-domain method We find the stretch or shrink of the lattice can bring the change not only on the frequencies of the defect modes but also on their magnetic field distributions. We obtain the separation of the doubly degenerate dipole modes with the change of the lattice and find that both the stretch and the shrink of the lattice can make the dipole modes separate large enough to realize the single-mode emission. These results may be advantageous to the manufacture of photonic crystal lasers and provide a new way to realize the single-mode operation in photonic crystal lasers.

  9. Coherence effects in propagation through one-dimensional photonic bandgap structures with a rough glass interface

    NARCIS (Netherlands)

    Mandatori, Antonio; Bertolotti, Mario; Sibilia, Concita; Hoenders, Bert J.; Scalora, Michael

    2007-01-01

    The effect of the coherence of a beam traveling through a photonic ID structure coupled with a rough glass is studied. The analysis is made for the case of spatial coherence showing the possibility to determine the coherence characteristics of the beam by an examination of the output field. We have

  10. Preconditioning bandgap eigenvalue problems in three-dimensional photonic crystals simulations

    International Nuclear Information System (INIS)

    To explore band structures of three-dimensional photonic crystals numerically, we need to solve the eigenvalue problems derived from the governing Maxwell equations. The solutions of these eigenvalue problems cannot be computed effectively unless a suitable combination of eigenvalue solver and preconditioner is chosen. Taking eigenvalue problems due to Yee's scheme as examples, we propose using Krylov-Schur method and Jacobi-Davidson method to solve the resulting eigenvalue problems. For preconditioning, we derive several novel preconditioning schemes based on various preconditioners, including a preconditioner that can be solved by Fast Fourier Transform efficiently. We then conduct intensive numerical experiments for various combinations of eigenvalue solvers and preconditioning schemes. We find that the Krylov-Schur method associated with the Fast Fourier Transform based preconditioner is very efficient. It remarkably outperforms all other eigenvalue solvers with common preconditioners like Jacobi, Symmetric Successive Over Relaxation, and incomplete factorizations. This promising solver can benefit applications like photonic crystal structure optimization.

  11. Polarization Properties of Elliptical-Hole Liquid Crystal Photonic Bandgap Fibers

    DEFF Research Database (Denmark)

    Tartarini, Giovanni; Pansera, Marco; Alkeskjold, Thomas Tanggaard;

    2007-01-01

    ellipticity allow some phenomena that are not predicted yet, such as polarization-dependent losses and birefringence sign change in the wavelength range used for standard telecom fibers. Control of these features allows the design of new devices for sensing or telecommunication applications......The characteristics of triangular photonic crystal fibers (PCFs) with elliptical holes filled with a nematic liquid crystal (LC) are investigated theoretically. The analysis that is carried out using the finite-element method, including material dispersion effects, shows that LC anisotropy and hole...

  12. Effect of Fresnel reflections in a hybrid air-core photonic-bandgap fiber ring-resonator gyro.

    Science.gov (United States)

    Yan, Yuchao; Ma, Huilian; Wang, Linglan; Li, Hanzhao; Jin, Zhonghe

    2015-11-30

    A novel hybrid polarization-maintaining (PM) air-core photonic bandgap fiber (PBF) ring resonator is firstly demonstrated by using a conventional solid-core PM fiber optical coupler formed by splicing a section of PM air-core PBF into the resonator. Due to Fresnel reflections exist at the two junctions between the air-core PBF and the solid-core fiber, the forward output signal of this hybrid ring resonator is the normal resonant curve with the superposition of the lightwaves that experienced even numbers of Fresnel reflections and the backward output signal is composed of lightwaves that experienced odd numbers of Fresnel reflections. Rigorous derivations of the forward and backward output signals are given out. The biggest resonant depth and finesse of the hybrid air-core PBF ring resonator predicted are 0.352 and 6.3 respectively by assuming a splice loss of 1.8 dB per junction. These predictions are finally confirmed by testing both the forward and backward output signals of the hybrid ring resonator. With the countermeasures against the influences of the odd numbers of Fresnel reflections, a bias stability of 0.007°/s is successfully demonstrated in a hybrid PM air-core PBF ring-resonator gyro. PMID:26698764

  13. Coherent all-optical switching by resonant quantum-dot distributions in photonic band-gap waveguides

    International Nuclear Information System (INIS)

    We study the detailed propagative characteristics of optical pulses in photonic band-gap (PBG) waveguides, coupled near resonantly to inhomogeneously broadened distributions of quantum dots. The line centers of the quantum-dot (QD) distributions are placed near a sharp discontinuity in the local electromagnetic density of states. Using finite-difference time-domain (FDTD) simulations of optical pulse dynamics and independent QD susceptibilities associated with resonance fluorescence, we demonstrate subpicosecond switching from pulse absorption to pulse amplification using steady-state optical holding and gate fields with power levels on the order of 1 milliwatt. In the case of collective response of QDs within the periodic dielectric microstructure, the gate power level is reduced to 200 microwatt for room temperature operation. In principle, this enables 200 Gbits per second optical information processing at wavelengths near 1.5 microns in various wavelength channels. The allowed pulse bandwidth in a given waveguide channel exceeds 0.5 THz allowing switching of subpicosecond laser pulses without pulse distortion. The switching contrast from absorption to gain is governed by the QD oscillator strength and dipole dephasing time scale. We consider dephasing time scales ranging from nanoseconds (low-temperature operation) to one picosecond (room-temperature operation). This all-optical transistor action is based on simple Markovian models of single-dot and collective-dot inversion and switching by coherent resonant pumping near the photon density of states discontinuity. The structured electromagnetic vacuum is provided by two-mode waveguide architectures in which one waveguide mode has a cutoff that occurs, with very large Purcell factor, near the QDs resonance, while the other waveguide mode exhibits nearly linear dispersion for fast optical propagation and modulation. Unlike optical switching based on Kerr nonlinearities in an optical cavity resonator, switching

  14. 光子带隙结构在微带带通滤波器中的应用%Application of Photonic Bandgap Structure in Microstrip Bandpass Filters

    Institute of Scientific and Technical Information of China (English)

    高强; 闫敦豹; 袁乃昌; 付云起

    2004-01-01

    介绍了两种带有一维光子带隙(Photonic Bandgap,简称PBG)结构的微带带通滤波器.它们具有良好的慢波、带阻特性,同时在结构上又无须腐蚀接地板,而仅仅修改微带线的形状.计算仿真与测量结果基本相符合.

  15. Photonic band-gap engineering for volume plasmon polaritons in multiscale multilayer hyperbolic metamaterials

    CERN Document Server

    Zhukovsky, Sergei V; Babicheva, Viktoriia E; Lavrinenko, Andrei V; Sipe, J E

    2013-01-01

    We theoretically study the propagation of large-wavevector waves (volume plasmon polaritons) in multilayer hyperbolic metamaterials with two levels of structuring. We show that when the parameters of a subwavelength metal-dielectric multilayer ("substructure") are modulated ("superstructured") on a larger, wavelength scale, the propagation of volume plasmon polaritons in the resulting multiscale hyperbolic metamaterials is subject to photonic band gap phenomena. A great degree of control over such plasmons can be exerted by varying the superstructure geometry. When this geometry is periodic, stop bands due to Bragg reflection are shown to form within the volume plasmonic band. When a cavity layer is introduced in an otherwise periodic superstructure, resonance peaks of the Fabry-P\\'erot nature are shown to be present within the stop bands. More complicated superstructure geometries are also considered. For example, fractal Cantor-like multiscale metamaterials are found to exhibit characteristic self-similar s...

  16. A Multifrequency Notch Filter for Millimeter Wave Plasma Diagnostics based on Photonic Bandgaps in Corrugated Circular Waveguides

    Directory of Open Access Journals (Sweden)

    Wagner D.

    2015-01-01

    Full Text Available Sensitive millimeter wave diagnostics need often to be protected against unwanted radiation like, for example, stray radiation from high power Electron Cyclotron Heating applied in nuclear fusion plasmas. A notch filter based on a waveguide Bragg reflector (photonic band-gap may provide several stop bands of defined width within up to two standard waveguide frequency bands. A Bragg reflector that reflects an incident fundamental TE11 into a TM1n mode close to cutoff is combined with two waveguide tapers to fundamental waveguide diameter. Here the fundamental TE11 mode is the only propagating mode at both ends of the reflector. The incident TE11 mode couples through the taper and is converted to the high order TM1n mode by the Bragg structure at the specific Bragg resonances. The TM1n mode is trapped in the oversized waveguide section by the tapers. Once reflected at the input taper it will be converted back into the TE11 mode which then can pass through the taper. Therefore at higher order Bragg resonances, the filter acts as a reflector for the incoming TE11 mode. Outside of the Bragg resonances the TE11 mode can propagate through the oversized waveguide structure with only very small Ohmic attenuation compared to propagating in a fundamental waveguide. Coupling to other modes is negligible in the non-resonant case due to the small corrugation amplitude (typically 0.05·λ0, where λ0 is the free space wavelength. A Bragg reflector for 105 and 140 GHz was optimized by mode matching (scattering matrix simulations and manufactured by SWISSto12 SA, where the required mechanical accuracy of ± 5 μm could be achieved by stacking stainless steel rings, manufactured by micro-machining, in a high precision guiding pipe. The two smooth-wall tapers were fabricated by electroforming. Several measurements were performed using vector network analyzers from Agilent (E8362B, ABmm (MVNA 8-350 and Rohde&Schwarz (ZVA24 together with frequency multipliers. The

  17. Competitive behavior of photons contributing to junction voltage jump in narrow band-gap semiconductor multi-quantum-well laser diodes at lasing threshold

    International Nuclear Information System (INIS)

    The junction behavior of different narrow band-gap multi-quantum-well (MQW) laser diodes (LDs) confirmed that the jump in the junction voltage in the threshold region is a general characteristic of narrow band-gap LDs. The relative change in the 1310 nm LD is the most obvious. To analyze this sudden voltage change, the threshold region is divided into three stages by Ithl and Ithu, as shown in Fig. 2; Ithl is the conventional threshold, and as long as the current is higher than this threshold, lasing exists and the IdV/dI-I plot drops suddenly; Ithu is the steady lasing point, at which the separation of the quasi-Fermi levels of electron and holes across the active region (Vj) is suddenly pinned. Based on the evolutionary model of dissipative structure theory, the rate equations of the photons in a single-mode LD were deduced in detail at Ithl and Ithu. The results proved that the observed behavior of stimulated emission suddenly substituting for spontaneous emission, in a manner similar to biological evolution, must lead to a sudden increase in the injection carriers in the threshold region, which then causes the sudden increase in the junction voltage in this region

  18. Competitive behavior of photons contributing to junction voltage jump in narrow band-gap semiconductor multi-quantum-well laser diodes at lasing threshold

    Energy Technology Data Exchange (ETDEWEB)

    Feng, Liefeng, E-mail: fengliefeng@tju.edu.cn, E-mail: lihongru@nankai.edu.cn; Yang, Xiufang; Wang, Cunda; Yao, Dongsheng [Tianjin Key Laboratory of Low Dimensional Materials Physics and Preparing Technology, Faculty of Science, Tianjin University, Tianjin 300072 (China); Li, Yang [Business and Vocational College of Hainan, Haikou 570203 (China); Li, Ding; Hu, Xiaodong [Research Center for Wide Band Gap Semiconductors, State Key Laboratory for Artificial Microstructure and Mesoscopic Physics, School of Physics, Peking University, Beijing 100871 (China); Li, Hongru, E-mail: fengliefeng@tju.edu.cn, E-mail: lihongru@nankai.edu.cn [State Key Laboratory for Medicinal Chemistry and Biology, College of Pharmacy, Nankai University, Tianjin 300071 (China)

    2015-04-15

    The junction behavior of different narrow band-gap multi-quantum-well (MQW) laser diodes (LDs) confirmed that the jump in the junction voltage in the threshold region is a general characteristic of narrow band-gap LDs. The relative change in the 1310 nm LD is the most obvious. To analyze this sudden voltage change, the threshold region is divided into three stages by I{sub th}{sup l} and I{sub th}{sup u}, as shown in Fig. 2; I{sub th}{sup l} is the conventional threshold, and as long as the current is higher than this threshold, lasing exists and the IdV/dI-I plot drops suddenly; I{sub th}{sup u} is the steady lasing point, at which the separation of the quasi-Fermi levels of electron and holes across the active region (V{sub j}) is suddenly pinned. Based on the evolutionary model of dissipative structure theory, the rate equations of the photons in a single-mode LD were deduced in detail at I{sub th}{sup l} and I{sub th}{sup u}. The results proved that the observed behavior of stimulated emission suddenly substituting for spontaneous emission, in a manner similar to biological evolution, must lead to a sudden increase in the injection carriers in the threshold region, which then causes the sudden increase in the junction voltage in this region.

  19. Facile construction of dual bandgap optical encoding materials with PS@P(HEMA-co-AA)/SiO2-TMPTA colloidal photonic crystals

    Science.gov (United States)

    Tian, Yu; Zhang, Jing; Liu, Si-Si; Yang, Shengyang; Yin, Su-Na; Wang, Cai-Feng; Chen, Li; Chen, Su

    2016-07-01

    An operable strategy for the construction of dual-reflex optical code materials from bilayer or Janus-structure colloidal photonic crystals (CPCs) has been established in this work. In this process, monodispersed submicrometer polystryene@poly(2-hydroxyethyl methacrylate-co-acrylic acid) hydrogel microspheres with soft-shell/hard-core structure and monodispersed colloidal silica spheres were fabricated. These two kinds of colloidal units can be facilely integrated into a single material without optical signal interference because they are well isolated for the immiscibility between water and ethoxylated trimethylolpropane triacrylate (TMPTA) and the upper layer of SiO2-TMPTA is a kind of transparent. Moreover, diverse optical code series with different dual photonic bandgaps can be obtained via tuning the colloid sizes. Compared to the conventional single-reflex CPCs, the as-prepared dual-reflex optical code materials represented high information capacity in encoding process. More interesting, delicate code pattern has been also achieved on the optical film via the silk-screen printing technique, which will greatly extend the dual-reflex optical code materials to practical uses in areas containing bio-encoding, anti-counterfeiting, and flexible displays.

  20. Interactions of low-power photons with natural opals—PBG materials, photonic control, natural metamaterials, spontaneous laser emissions, and band-gap boundary responses

    International Nuclear Information System (INIS)

    Four views of each of the opal research specimens in white light (for in-article or cover), in the same order as the specimens depicted in Fig. 3 of the main manuscript. A.On the left: 1.5 carat oval cabochon precious fire opal. B.In the center: 2.5 carats faceted fancy shield precious fire contra luz with mild adularescence. C.On the right: 5.0 carats round cabochon precious crystal opal with blue adularescence. Highlights: ► Emission of micro-lasers from microspheroid cluster boundary zones (quantum dots). ► Lasers illuminated or fluoresced the intra-opal structures of microspheroid photonic glass clusters. ► Microspheroid boundaries are durable to low power light sources. ► Display of previously unknown low power photonic optic properties. ► The research specimens are natural metamaterials. - Abstract: One overall goal of this research was to examine types of naturally-occurring opals that exhibit photonic control to learn about previously-unknown properties of naturally occurring photonic control that may be developed for broader applications. Three different photon sources were applied consecutively to three different types of natural, flawless, gem-quality precious opals. Two photon sources were lasers (green and red) and one was simulated daylight tungsten white. As each type of precious opal was exposed to each of the photon sources, the respective refractions, reflections, and transmissions were studied. This research is the first to show that applying various pleochroic and laser photon sources to these types of opals revealed significant information regarding naturally occurring photonic control, metamaterials, spontaneous laser emissions, and microspheroid cluster (inter-PBG zone) boundary effects. Plus, minimizing ambient light and the use of low power photon sources were critical to observing the properties regarding this photonic materials research. This research yielded information applicable to the development of materials to advance

  1. Low-loss transmission band in photonic crystal waveguides with sharp cutoff at a frequency below the bandgap

    DEFF Research Database (Denmark)

    Krüger, Asger Christian; Zhang, Min; Groothoff, Nathaniel; Malureanu, Radu; Kristensen, Martin

    2011-01-01

    We present TE transmission measurements of photonic crystal waveguides with high hole radius to period ratio r/Λ=0.388. This geometry introduces a unique low loss transmission band in addition to the traditional PhC guiding band and very sharp transmission edges for devices with a length of 50 μm...... or longer. Finite difference time domain and plane wave expansion simulations confirm the results and show that the sharpness of the cutoffs can be explained by the spectral shape of the guiding mode in the band diagram....

  2. Precise Balancing of Viscous and Radiation Forces on a Particle in Liquid-Filled Photonic Bandgap Fiber

    OpenAIRE

    Euser, T.G.; Garbos, M. K.; Chen, J. S. Y.; Russell, P. St. J.

    2009-01-01

    It is shown that, in the liquid-filled hollow core of a single-mode photonic crystal fiber, a micron-sized particle can be held stably against a fluidic counter-flow using radiation pressure, and moved to and fro (over 10s of cm) by ramping the laser power up and down. The results represent a major advance over previous work on particle transport in optically multimode liquid-filled fibers, in which the fluctuating transverse field pattern renders the radiation and trapping forces unpredictab...

  3. 1178 nm all Yb-fiber laser source power-scaled by solid-core photonic bandgap fiber for 589nm generation

    DEFF Research Database (Denmark)

    Maruyama, H.; Shirakawa, A.; Ueda, K.I.;

    2009-01-01

    Here we report an 1178 nm all Yb-fiber laser source power-scaled by solid-core photonic bandgap fiber (SC-PBGF) for 589 nm generation. A 1.4 W output at 589 nm with an input power of 9 W at 1178 nm were obtained. One important advantage of PBGF is distributed filtering. Hence the gain spectrum can...... be designed artificially in an active-ion-doped SC-PBGF, desirable for long-wavelength Yb fiber laser operation. At first, 1178 nm amplification seeded with a non-polarized and linearly-polarized FRL was carried out with the core launched powers of 4 W and 2 W, respectively. As a result, an output...... power of 30 W at 1178 nm with was obtained with the slope efficiency of 58% and ASE free. A 25 W linearly-polarized output with dimensions. Thereby one can obtain lasing or amplification at longer avelengths (1100 nm - 1200 nm) as the amount of amplification in the fibre is shown to scale with the power...

  4. Precise Balancing of Viscous and Radiation Forces on a Particle in Liquid-Filled Photonic Bandgap Fiber

    CERN Document Server

    Euser, T G; Chen, J S Y; Russell, P St J

    2009-01-01

    It is shown that, in the liquid-filled hollow core of a single-mode photonic crystal fiber, a micron-sized particle can be held stably against a fluidic counter-flow using radiation pressure, and moved to and fro (over 10s of cm) by ramping the laser power up and down. The results represent a major advance over previous work on particle transport in optically multimode liquid-filled fibers, in which the fluctuating transverse field pattern renders the radiation and trapping forces unpredictable. The counter-flowing liquid can be loaded with sequences of chemicals in precisely controlled concentrations and doses, making possible studies of single particles, vesicles or cells.

  5. 太赫兹双芯光子带隙光纤定向耦合器%Terahertz dual-core photonic band-gap fiber directional coupler

    Institute of Scientific and Technical Information of China (English)

    白晋军; 王昌辉; 侯宇; 范飞; 常胜江

    2012-01-01

    提出了一种低损耗、宽频段太赫兹双芯光子带隙光纤定向耦合器,光纤的包层由亚波长尺度呈三角晶格排列的空气孔组成,两个纤芯分别由去掉7个空气孔构成.利用全矢量有限元法对光纤的色散、耦合特性以及损耗特性进行了理论分析.研究表明,这种耦合器的损耗系数小于0.021cm^-1更重要的是可以实现0.14THz范围内的宽频定向耦合.这种定向耦合器在太赫兹通信系统中滤波、波分复用、偏振分离和开关等技术中有潜在的应用价值.%A low-loss and broadband terahertz twin-core photonic band-gap fiber directional coupler is proposed, which consists of a cladding with a triangular lattice array of sub-wavelength air rods and two cores formed respectively by omitting seven nearby air rods. The group veIocity dispersion, the coupling and the loss of the fibers are investigated by using a full-vector finite element method. The numerical simulations show that the loss coefficient of the coupler is less than 0.021 cm^-1, and the coupling broadband of 0.14 THz can be realized. The directional coupler has potential applications in terahertz communication systems, such as filtering, wavelength-division multiplexing, polarization isolation, switching and so on.

  6. Tunable Fabry-Perot filter using hollow-core photonic bandgap fiber and micro-fiber for a narrow-linewidth laser.

    Science.gov (United States)

    Wang, Xiaozhen; Zhu, Tao; Chen, Liang; Bao, Xiaoyi

    2011-05-01

    A novel tunable fiber Fabry-Perot (FP) filter is proposed and demonstrated by using a hollow-core photonic bandgap fiber (HC-PBF) and a micro-fiber. The interference cavity is a hollow core of HC-PBF. One of the reflection mirrors is the splicing point between a section of HC-PBF and a single mode fiber. The other reflection mirror is a gold-coated end of micro-fiber that uses chemical etching process to obtain the similar diameter as the core of HC-PBF. Hence the movable mirror can be adjusted with long distance inside the hollow core of HC-PBF. Tunable FP filter is used as a mode selecting component in the reflection mode to implement stable single longitudinal mode (SLM) operation in a ring laser. With FP cavity length of 0.25 ± 0.14 mm, the wavelength of SLM laser can be tuned over 1554-1562 nm with a tuning step of 0.2-0.3 nm, a side-mode suppression ratio (SMSR) of 32-36 dB and a linewidth of 3.0-5.1 kHz. With FP cavity length of 2.37 ± 0.37 mm, the SLM laser can be tuned over 1557.3-1560.2 nm with a tuning step of 0.06-0.1 nm, a SMSR of 44-51 dB and a linewidth of 1.8-3.0 kHz. PMID:21643220

  7. Novel All Solid-state Polymer Electrolytes for Lithium Battery

    Institute of Scientific and Technical Information of China (English)

    Hui Jiang; Shibi Fang

    2005-01-01

    @@ 1Introduction All solid-state polymer electrolytes for lithium battery was proved to be an attractive direction. Compared with prevenient polymer electrolytes all solid-state polymer electrolytes were superiority in more broad electrochemical window, more stable/low interfacial resistance especially when situ-polymerization utilized, excellent mechanical properties and dissepiment free. A lithium secondary battery using all solid-state polymer electrolyte meet the challenge of energy source for both portable electronic devices and electric vehicles (EV) or engine/battery hybrid vehicles (HEV). All solid-state comb-like network polymer electrolytes (CNPE) based on polysiloxane with internal plasticizing chain (IPC) has been designed and synthesized. See Fig. 1.

  8. A study of potential high band-gap photovoltaic materials for a two step photon intermediate technique in fission energy conversion. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Prelas, M.A.

    1996-01-24

    This report describes progress made to develop a high bandgap photovoltaic materials for direct conversion to electricity of excimer radiation produced by fission energy pumped laser. This report summarizes the major achievements in sections. The first section covers n-type diamond. The second section covers forced diffusion. The third section covers radiation effects. The fourth section covers progress in Schottky barrier and heterojunction photovoltaic cells. The fifth section covers cell and reactor development.

  9. All solid state pulsed power system for water discharge

    OpenAIRE

    Sakugawa, Takashi; Yamaguchi, Takahiro; Yamamoto, Kunihiro; Kiyan, Tsuyoshi; Namihira, Takao; Katsuki, Sunao; Akiyama, Hidenori; サクガワ, タカシ; ヤマグチ, タカヒロ; ヤマモト, クニヒロ; キヤン, ツヨシ; ナミヒラ, タカオ; カツキ, スナオ; アキヤマ, ヒデノリ; 佐久川, 貴志

    2005-01-01

    Pulsed power has been used to produce non-thermal plasmas in gases that generate a high electric field at the tip of streamer discharges, where high energy electrons, free radicals, and ozone are produced. Recently, all solid state pulsed power generators, which are operated with high repetition rate, long lifetime and high reliability, have been developed for industrial applications, such as high repetition rate pulsed gas lasers, high energy density plasma (EUV sources) and water discharges...

  10. Interface investigations on all solid state thin film batteries

    Energy Technology Data Exchange (ETDEWEB)

    Jacke, S.; Song, J.; Cherkashinin, G.; Jaegermann, W. [Technische Univ. Darmstadt (Germany). Fachbereich Materialwissenschaft

    2010-07-01

    An All-Solid-State battery consisting of LiCoO{sub 2} as cathode, Lithium phosphorous oxynitride (LiPON) as solid electrolyte and LiAl as anode was fabricated. The thickness of the battery was 1.3{mu}m. An investigation of the structural composition of the materials relevant for the conductivity was carried out on the LiPON material by XPS core level analysis under UHV transfer. These analyses were then compared to the properties of the cathode-electrolyte interface using the same experimental methods. (orig.)

  11. Diode-pumped all-solid-state lasers and applications

    CERN Document Server

    Parsons-Karavassilis, D

    2002-01-01

    This thesis describes research carried out by the within the Physics Department at Imperial College that was aimed at developing novel all-solid-state laser sources and investigating potential applications of this technology. A description of the development, characterisation and application of a microjoule energy level, diode-pumped all-solid-state Cr:LiSGAF femtosecond oscillator and regenerative amplifier system is presented. The femtosecond oscillator was pumped by two commercially available laser diodes and produced an approx 80 MHz pulse train of variable pulse duration with approx 30 mW average output power and a tuning range of over approx 60 nm. This laser oscillator was used to seed a regenerative amplifier, resulting in adjustable repetition rate (single pulse to 20 kHz) approx 1 mu J picosecond pulses. These pulses were compressed to approx 150 fs using a double-pass twin-grating compressor. The amplifier's performance was investigated with respect to two different laser crystals and different pul...

  12. 飞秒激光与宽禁带物质相互作用过程中光子-电子-声子之间的微能量传导Ⅰ:光子吸收过程%Microscopic energy transport through photon-electron-phonon interactions during ultrashort laser ablation of wide bandgap materials Part Ⅰ:photon absorption

    Institute of Scientific and Technical Information of China (English)

    姜澜; 李丽珊; 王素梅

    2009-01-01

    The new phenomena induced by femtosecond lasers lead to the new area of ultrafast science.It is a significant challenge to explain the phenomena associated with complex non-equilibrium and non-linear processes.Although there is a growing body of experimental observation,a comprehensive model remains undeveloped.We review the challenges in understanding the photon absorption stage mainly for the femtosecond ablation of wide bandgap materials at the intensities of 1013~1014 W/cm2.Major opinions and challenges in ionization mechanisms are presented by primarily considering multiphoton ionization and avalanche ionization.

  13. A New All Solid State Approach to Gaseous Pollutant Detection

    Science.gov (United States)

    Brown, V.; Tamstorf, K.

    1971-01-01

    Recent efforts in our laboratories have concentrated on the development of an all solid state gas sensor, by combining solid electrolyte (ion exchange membrane) technology with advanced thin film deposition processes. With the proper bias magnitude and polarity these miniature electro-chemical,cells show remarkable current responses for many common pollution gases. Current activity is now focused on complementing a multiple array (matrix) of these solid state sensors, with a digital electronic scanner device possessing "scan-compare-identify-alarm: capability. This innovative approach to multi-component pollutant gas analysis may indeed be the advanced prototype for the "third generation" class of pollution analysis instrumentation so urgently needed in the decade ahead.

  14. Diffuse-light all-solid-state invisibility cloak.

    Science.gov (United States)

    Schittny, Robert; Niemeyer, Andreas; Kadic, Muamer; Bückmann, Tiemo; Naber, Andreas; Wegener, Martin

    2015-09-15

    An ideal invisibility cloak makes arbitrary macroscopic objects within the cloak indistinguishable from its surrounding—for all directions, illumination patterns, polarizations, and colors of visible light. Recently, we have approached such an ideal cloak for the diffusive regime of light propagation using a core-shell geometry and a mixture of water and white wall paint as the surrounding. Here, we present an all-solid-state version based on polydimethylsiloxane doped with titania nanoparticles for the surrounding/shell and on a high-reflectivity microporous ceramic for the core. By virtue of reduced effects of absorption, especially from the core, the cloaking performance and the overall light throughput are improved significantly. PMID:26371896

  15. Fabrication of FCC Structure Colloidal Photonic Crystals and Characteration of Band-Gap Measured%FCC结构胶体光子晶体的制备及其带隙特性测量

    Institute of Scientific and Technical Information of China (English)

    闫海涛; 王鸣; 葛益娴; 喻平; 刘青

    2009-01-01

    基于对光纤传输特性和胶体光子晶体制备方法的研究,提出了用外加电场控制的方法制备光子带隙位于通讯波段的FCC结构的胶体光子晶体,并用光纤系统测试胶体光子晶体的带隙特性.采用RSOFT模拟了胶体光子晶体的带隙,分析了带隙位于通讯波段时所需的胶体微球的基本参量(微球折射率和直径).采用自组装的方法,用步进电机控制玻璃基片向上的拉升速率.速率为5 μm/s,同时外加一电场.用扫描电镜观测胶体晶体的表面形貌,并设计了单模光纤系统测量胶体光子晶体的带隙特性.测试的透射谱线表明胶体光子晶体的带隙中心波长为1552 nm.测试结果和模拟结果具有很好的一致性,误差只有2 nm.%Based on the transmission characteration of optical fiber and the methods of fabrication colloidal photonic crystals, electric field-controlled method is used to fabricate colloidal photonic crystals with the photonic band-gap (PBG) in communications wavelength. RSOFT is used to simulate PBG characteration of colloidal photonic crystals and the parameters of colloidal microsphere are obtained. By the self-assembled method, the stepping motor is used to control the glass substrate, with the rate of 5 μm/s. At the same time an electric field is applied in the process of the colloidal crystals growth. The scanning electron microscopy is used to observe the surface of colloidal photonic crystals. An optical fiber system is designed to test PBG center wavelength of colloidal photonic crystals. Transmission spectrum shows the PBG of this colloidal crystals at 1552 nm. The agreement is very good between the experimental results and the simulation results, with the error of only 2 nm.

  16. All-Solid-State Laser Amplifiers for Intense Lyman-α Generation

    Science.gov (United States)

    Oishi, Yu; Okamura, Kotaro; Miyazaki, Koji; Saito, Norihito; Iwasaki, Masahiko; Wada, Satoshi

    We have developed an all-solid-state high energy 1062.78 nm pulse amplifier system toward efficient Lyman-α generation using two-photon resonance four-wave mixing in Kr gas. Nd:YSAG and Nd:YGAG crystals were applied to regenerative amplifier in order to investigate whether suitable for amplification of 1062.78 nm light. The higher gain was obtained by use of Nd:YGAG crystal. Moreover, we have developed Nd:YGAG ceramic for subsequent power amplifiers to overcome an inhomogeneity in large aperture Nd:YGAG single crystal. 100 mJ level 1062.78 nm pulses have been obtained using Nd:YGAG ceramic amplifier.

  17. Electrical characterization of all-solid-state thin film batteries

    Science.gov (United States)

    Nagasubramanian, G.; Doughty, D. H.

    All-solid-state thin film micro-batteries comprised of a lithium anode, lithium phosphorus oxy-nitride (LiPON) solid electrolyte and Li xCoO 2 cathode were evaluated at different temperatures from -50 to 80 °C for electrical behavior and impedance raise. The cell dimensions were ˜2 cm long, ˜1.5 cm wide and ˜15 μm thick. The rated capacity of the cells was about 400 μAh. The cells were cycled (charge/discharge) at room temperature over 100 times at a 0.25 C rate. The charge and discharge cut-off voltages were 4.2 and 3.0 V, respectively. The cells did not show any capacity decay over 100 cycles. The measured capacity was 400 μAh. The coulombic efficiency was 1, which suggests that the cell reaction is free from any parasitic side reactions and the lithium intercalation and de-intercalation reaction is completely and totally reversible. These cells also have good high-rate performance at room temperature. For example, these cells discharged at a 2.5 C rate delivered ˜90% of the capacity at a 0.25 C rate. However, the delivered capacities even at a 0.25 C rate at 80 and -50 °C were much lower than the room temperature capacity. Cells soaked at -50 °C were not damaged permanently as seen by the near normal behavior when returned to room temperature. However, cells heated to 80 °C were permanently damaged as seen by the lack of normal performance back at room temperature. Cell impedance was measured before and after cycling at different temperatures. The high-frequency resistance (generally ascribed to the electrolyte and other resistances in series with the electrolyte resistance) decreased with decreasing temperature. However, the interfacial resistance increased significantly with decreasing temperature. Further, the electrolyte resistance accounted for ˜2% of the total cell resistance. The cycled cells showed higher impedance than the uncycled cells.

  18. Photonics

    CERN Document Server

    Andrews, David L

    2015-01-01

    Discusses the basic physical principles underlying Biomedical Photonics, spectroscopy and microscopy This volume discusses biomedical photonics, spectroscopy and microscopy, the basic physical principles underlying the technology and its applications. The topics discussed in this volume are: Biophotonics; Fluorescence and Phosphorescence; Medical Photonics; Microscopy; Nonlinear Optics; Ophthalmic Technology; Optical Tomography; Optofluidics; Photodynamic Therapy; Image Processing; Imaging Systems; Sensors; Single Molecule Detection; Futurology in Photonics. Comprehensive and accessible cov

  19. Photonics

    CERN Document Server

    Andrews, David L

    2015-01-01

    This book covers modern photonics accessibly and discusses the basic physical principles underlying all the applications and technology of photonicsThis volume covers the basic physical principles underlying the technology and all applications of photonics from statistical optics to quantum optics. The topics discussed in this volume are: Photons in perspective; Coherence and Statistical Optics; Complex Light and Singular Optics; Electrodynamics of Dielectric Media; Fast and slow Light; Holography; Multiphoton Processes; Optical Angular Momentum; Optical Forces, Trapping and Manipulation; Pol

  20. Photonics

    CERN Document Server

    Andrews, David L

    2015-01-01

    Discusses the basic physical principles underlying the technology instrumentation of photonics This volume discusses photonics technology and instrumentation. The topics discussed in this volume are: Communication Networks; Data Buffers; Defense and Security Applications; Detectors; Fiber Optics and Amplifiers; Green Photonics; Instrumentation and Metrology; Interferometers; Light-Harvesting Materials; Logic Devices; Optical Communications; Remote Sensing; Solar Energy; Solid-State Lighting; Wavelength Conversion Comprehensive and accessible coverage of the whole of modern photonics Emphas

  1. Photonics

    CERN Document Server

    Andrews, David L

    2015-01-01

    Discusses the basic physical principles underlying thescience and technology of nanophotonics, its materials andstructures This volume presents nanophotonic structures and Materials.Nanophotonics is photonic science and technology that utilizeslight/matter interactions on the nanoscale where researchers arediscovering new phenomena and developing techniques that go wellbeyond what is possible with conventional photonics andelectronics.The topics discussed in this volume are: CavityPhotonics; Cold Atoms and Bose-Einstein Condensates; Displays;E-paper; Graphene; Integrated Photonics; Liquid Cry

  2. Photonic crystal fibers -

    DEFF Research Database (Denmark)

    Libori, Stig E. Barkou

    2002-01-01

    possibilities, the thesis will attempot to offer a proof of concept, rather than an in-depth analysis, thus reflecting the present state of the art within the area of micro-structured fibers. Another important sub-class of micro-structured fibers is photonic bandgap fibers. Photonic bandgap fibers are far more......-structured fibers that guide light by simple index effects. However, photonic bandgap fibers offer more radical possibilities, such as core regions with an effective index that is lower than the surrounding effective cladding index one may guide light in air- and dispersion qualities that differ from both those of...

  3. Ultrafast photonic crystal optical switching

    Institute of Scientific and Technical Information of China (English)

    GONG Qi-huang; HU Xiao-yong

    2006-01-01

    Photonic crystal,a novel and artificial photonic material with periodic dielectric distribution,possesses photonic bandgap and can control the propagation states of photons.Photonic crystal has been considered to be a promising candidate for the future integrated photonic devices.The properties and the fabrication method of photonic crystal are expounded.The progresses of the study of ultrafast photonic crystal optical switching are discussed in detail.

  4. Photonic bandgap fibers: theory and experiments

    DEFF Research Database (Denmark)

    Bjarklev, Anders Overgaard; Broeng, Jes; Libori, Stig E. Barkou

    2000-01-01

    We will in this presentation address, show how the fiber cladding structure influences the resulting waveguiding properties. The core may be introduced by breaking the periodicity of the air holes at the center of the fiber. It has been demonstrated experimentally that this makes it possible to...

  5. Liquid Crystal photonic Bandgap Fiber Devices

    DEFF Research Database (Denmark)

    Wei, Lei

    polarizer with electrically tunable polarization extinction ratio is obtained. An on-chip tunable notch filter based on long-period gratings is presented, exhibiting high polarization sensitivity. A tunable polarization controller using negative dielectric LCs is developed, which can be thermally and...... electrically controlled to work both as a quarter-wave plate or half-wave plate. An electrically tunable bandpass filter based on two solid-core PCFs filled with different LCs is fabricated, and the tunability of the bandwidth is achieved by individually or simultaneously controlling the driving voltage of...

  6. Photonic crystal fibers

    DEFF Research Database (Denmark)

    Lægsgaard, Jesper; Hansen, K P; Nielsen, M D;

    2003-01-01

    Photonic crystal fibers having a complex microstructure in the transverse plane constitute a new and promising class of optical fibers. Such fibers can either guide light through total internal reflection or the photonic bandgap effect, In this paper, we review the different types and applications...... of photonic crystal fibers with particular emphasis on recent advances in the field....

  7. Wide Bandgap Extrinsic Photoconductive Switches

    Science.gov (United States)

    Sullivan, James Stephen

    Wide Bandgap Extrinsic Photoconductive Switches Semi-insulating Gallium Nitride, 4H and 6H Silicon Carbide are attractive materials for compact, high voltage, extrinsic, photoconductive switches due to their wide bandgap, high dark resistance, high critical electric field strength and high electron saturation velocity. These wide bandgap semiconductors are made semi-insulating by the addition of vanadium (4H and 6H-SiC) and iron (2H-GaN) impurities that form deep acceptors. These deep acceptors trap electrons donated from shallow donor impurities. The electrons can be optically excited from these deep acceptor levels into the conduction band to transition the wide bandgap semiconductor materials from a semi-insulating to a conducting state. Extrinsic photoconductive switches with opposing electrodes have been constructed using vanadium compensated 6H-SiC and iron compensated 2H-GaN. These extrinsic photoconductive switches were tested at high voltage and high power to determine if they could be successfully used as the closing switch in compact medical accelerators. The successful development of a vanadium compensated, 6H-SiC extrinsic photoconductive switch for use as a closing switch for compact accelerator applications was realized by improvements made to the vanadium, nitrogen and boron impurity densities. The changes made to the impurity densities were based on the physical intuition outlined and simple rate equation models. The final 6H-SiC impurity 'recipe' calls for vanadium, nitrogen and boron densities of 2.5 e17 cm-3, 1.25e17 cm-3 and ≤ 1e16 cm-3, respectively. This recipe was originally developed to maximize the quantum efficiency of the vanadium compensated 6H-SiC, while maintaining a thermally stable semi-insulating material. The rate equation models indicate that, besides increasing the quantum efficiency, the impurity recipe should be expected to also increase the carrier recombination time. Three generations of 6H-SiC materials were tested. The

  8. [The design of all solid-state tunable pulsed Ti:sapphire laser system].

    Science.gov (United States)

    Chen, Zhe; Ku, Geng; Wan, Junchao; Wang, Wei; Zhou, Chuanqing

    2013-05-01

    This paper presented a design of broadly all solid-state tunable pulsed Ti:sapphire laser with high power and stable performance. The laser was pumped by custom-made Nd:YAG laser which had water cooling system and amplified by two stage amplifier. The method accomplished tunable output of all solid-state tunable pulsed Ti:sapphire laser by modifying the reflection angle of the back mirror. We investigated the relationship between the power of the pumping laser and the all solid-state tunable pulsed Ti: sapphire laser by changing the power of the pumping source. PMID:24015611

  9. Optical Fiber Lasers and All Solid-State Passively Modulated Microchip Lasers

    Institute of Scientific and Technical Information of China (English)

    Junewen; Chen; Pie-Yau; Chien; Yu-Ting; Lee

    2003-01-01

    Erbium fiber lasers of continuous mode outputs and of pulsed picosecond and sub-picosecond pulses train are reported. Compact all solid state passively modulated microchip lasers are also developed to the same degree.

  10. Development of an All Solid High Energy Density Space Rated Battery Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Quallion's intends to develop an all-solid 600 Wh/kg, flexible form-factor lithium rechargeable energy device for advanced space power applications. Quallion's...

  11. Recent progress in all-solid-state quantum dot-sensitized TiO2 nanotube array solar cells

    International Nuclear Information System (INIS)

    All-solid-state quantum dot-sensitized TiO2 nanotube array solar cells have been drawing great attention to solar energy conversion, which break through restrictions in traditional solar cells, such as the high recombination at interfaces of porous TiO2 films/sensitizers/hole conductors/counter electrodes, instability of dyes, and leakage of solution electrolyte, and so the novel solar cells exhibit promising applications in the future. In this Minireview article, the assembling of solar cells including the preparation of TiO2 nanotube array photoanodes, quantum dot preparation and sensitization on photoanodes, filling of hole conductors in TiO2 nanotubes, and selection of counter electrodes are overviewed, and the development course of all-solid-state quantum dot-sensitized TiO2 nanotube array solar cells in recent years are summarized in detail. Moreover, the influences of TiO2 nanotube array photoanodes, quantum dots, solid electrolyte, and counter electrodes on photon-to-current efficiencies of solar cells are summarized. In addition, current problems of solid-state quantum dot-sensitized TiO2 nanotube array solar cells are analyzed, and the corresponding improvements, such as multisensitizers and passivation layers, are proposed to improve the photoelectric conversion efficiency. Finally, this Minireview provides a perspective for the future development of this novel solar cell

  12. Recent progress in all-solid-state quantum dot-sensitized TiO{sub 2} nanotube array solar cells

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Qingyao, E-mail: wangqingyao0532@163.com [Ludong University, School of Chemistry and Materials Science (China); Chen, Chao; Liu, Wei [Tongji University, School of Materials Science and Engineering (China); Gao, Shanmin [Ludong University, School of Chemistry and Materials Science (China); Yang, Xiuchun, E-mail: yangxc@tongji.edu.cn [Tongji University, School of Materials Science and Engineering (China)

    2016-01-15

    All-solid-state quantum dot-sensitized TiO{sub 2} nanotube array solar cells have been drawing great attention to solar energy conversion, which break through restrictions in traditional solar cells, such as the high recombination at interfaces of porous TiO{sub 2} films/sensitizers/hole conductors/counter electrodes, instability of dyes, and leakage of solution electrolyte, and so the novel solar cells exhibit promising applications in the future. In this Minireview article, the assembling of solar cells including the preparation of TiO{sub 2} nanotube array photoanodes, quantum dot preparation and sensitization on photoanodes, filling of hole conductors in TiO{sub 2} nanotubes, and selection of counter electrodes are overviewed, and the development course of all-solid-state quantum dot-sensitized TiO{sub 2} nanotube array solar cells in recent years are summarized in detail. Moreover, the influences of TiO{sub 2} nanotube array photoanodes, quantum dots, solid electrolyte, and counter electrodes on photon-to-current efficiencies of solar cells are summarized. In addition, current problems of solid-state quantum dot-sensitized TiO{sub 2} nanotube array solar cells are analyzed, and the corresponding improvements, such as multisensitizers and passivation layers, are proposed to improve the photoelectric conversion efficiency. Finally, this Minireview provides a perspective for the future development of this novel solar cell.

  13. Efficient all solid-state UV source for satellite-based lidar applications

    International Nuclear Information System (INIS)

    A satellite-based UV-DIAL measurement system would allow continuous global monitoring of ozone concentration in the upper atmosphere. However such systems remain difficult to implement because aerosol-scattering return signals for satellite-based lidars are very weak. A suitable system must produce high-energy UV pulses at multiple wavelengths with very high efficiency. For example, a nanosecond system operating at 10 Hz must generate approximately 1 J per pulse at 308-320 nm. An efficient space-qualified wavelength-agile system based on a single UV source that can meet this requirement is probably not available using current laser technology. As an alternative, we're pursuing a multi-source approach employing all-solid-state modules that individually generate 300-320 nm light with pulse energies in the range of 50-200 mJ, with transform-limited bandwidths and good beam quality. Pulses from the individual sources can be incoherently summed to obtain the required single-pulse energy. These sources use sum-frequency mixing of the 532 nm second harmonic of an Nd:YAG pump laser with 731-803 nm light derived from a recently-developed, state-of-the-art, nanosecond optical parametric oscillator. Two source configurations are under development, one using extra-cavity sum-frequency mixing, and the other intra-cavity sum-frequency mixing. In either configuration, we hope to obtain sum-frequency mixing efficiency approaching 60% by carefully matching the spatial and temporal properties of the laser and OPO pulses. This ideal balance of green and near-IR photons requires an injection-seeded Nd:YAG pump-laser with very high beam quality, and an OPO exhibiting unusually high conversion efficiency and exceptional signal beam quality. The OPO employs a singly-resonant high-Fresnel-number image-rotating self-injection-seeded nonplanar-ring cavity that achieves pump depletion > 65% and produces signal beams with M2 ∼ 3 at pulse energies exceeding 50 mJ. Pump beam requirements can

  14. All-solid-state blue laser pumped Pr:KY3F10-BBO ultraviolet laser at 305 nm All-solid-state blue laser

    Science.gov (United States)

    Dong, Y.; Li, S. T.; Zhang, X. H.

    2012-02-01

    An all-solid-state blue laser pumped Pr:KY3F10 (Pr:KYF) laser at 610 nm has been demonstrated. With an incident pump power of 2.6 W, the maximum output power was 213 mW. Moreover, intracavity second-harmonic generation (SHG) has also been achieved with a maximum ultraviolet power of 11 mW by using a β-BaB2O4 (BBO) nonlinear crystal. To the best of our knowledge, this is the first report on continuous-wave ultraviolet generation by intracavity frequency doubling Pr:KYF laser.

  15. Wide-Bandgap Semiconductors

    Energy Technology Data Exchange (ETDEWEB)

    Chinthavali, M.S.

    2005-11-22

    With the increase in demand for more efficient, higher-power, and higher-temperature operation of power converters, design engineers face the challenge of increasing the efficiency and power density of converters [1, 2]. Development in power semiconductors is vital for achieving the design goals set by the industry. Silicon (Si) power devices have reached their theoretical limits in terms of higher-temperature and higher-power operation by virtue of the physical properties of the material. To overcome these limitations, research has focused on wide-bandgap materials such as silicon carbide (SiC), gallium nitride (GaN), and diamond because of their superior material advantages such as large bandgap, high thermal conductivity, and high critical breakdown field strength. Diamond is the ultimate material for power devices because of its greater than tenfold improvement in electrical properties compared with silicon; however, it is more suited for higher-voltage (grid level) higher-power applications based on the intrinsic properties of the material [3]. GaN and SiC power devices have similar performance improvements over Si power devices. GaN performs only slightly better than SiC. Both SiC and GaN have processing issues that need to be resolved before they can seriously challenge Si power devices; however, SiC is at a more technically advanced stage than GaN. SiC is considered to be the best transition material for future power devices before high-power diamond device technology matures. Since SiC power devices have lower losses than Si devices, SiC-based power converters are more efficient. With the high-temperature operation capability of SiC, thermal management requirements are reduced; therefore, a smaller heat sink would be sufficient. In addition, since SiC power devices can be switched at higher frequencies, smaller passive components are required in power converters. Smaller heat sinks and passive components result in higher-power-density power converters

  16. Photonic Crystal Fibres

    DEFF Research Database (Denmark)

    Bjarklev, Anders Overgaard; Broeng, Jes; Sanchez Bjarklev, Araceli

    bandgap structures and thoughts of inspiration from microstructures in nature, as well as classification of the various photonic crystal fibres, theoretical tools for analysing the fibres and methods of their production. Finally, the book points toward some of the many future applications, where photonic...

  17. Compressed lead-based perovskites reaching optimal Shockley-Queisser bandgap with prolonged carrier lifetime

    CERN Document Server

    Liu, Gang; Gong, Jue; Yang, Wenge; Mao, Ho-kwang; Liu, Zhenxian; Schaller, Richard D; Zhang, Dongzhou; Xu, Tao

    2016-01-01

    Atomic structure of materials plays a decisive role in the light-matter interaction. Yet, despite its unprecedented progress, further efficiency boost of Lead-based organic-inorganic perovskite solar cells is hampered by its greater bandgap than the optimum value according to Shockley-Queisser limit. Here, we report the experimental achievement of bandgap narrowing in formamidinium lead triiodide from 1.489 to 1.337 eV by modulating the lattice constants under hydraulic compression, reaching the optimized bandgap for single-junction solar cells. Strikingly, such bandgap narrowing is accomplished with improved, instead of sacrificed carrier lifetime. More attractively, the narrowed bandgap is partially retainable after the release of pressure. This work opens a new dimension in basic science understanding of structural photonics and paves an alternative pathway towards more efficient photovoltaic materials.

  18. Low-bandgap, monolithic, multi-bandgap, optoelectronic devices

    Energy Technology Data Exchange (ETDEWEB)

    Wanlass, Mark W.; Carapella, Jeffrey J.

    2016-01-05

    Low bandgap, monolithic, multi-bandgap, optoelectronic devices (10), including PV converters, photodetectors, and LED's, have lattice-matched (LM), double-heterostructure (DH), low-bandgap GaInAs(P) subcells (22, 24) including those that are lattice-mismatched (LMM) to InP, grown on an InP substrate (26) by use of at least one graded lattice constant transition layer (20) of InAsP positioned somewhere between the InP substrate (26) and the LMM subcell(s) (22, 24). These devices are monofacial (10) or bifacial (80) and include monolithic, integrated, modules (MIMs) (190) with a plurality of voltage-matched subcell circuits (262, 264, 266, 270, 272) as well as other variations and embodiments.

  19. Low-bandgap, monolithic, multi-bandgap, optoelectronic devices

    Energy Technology Data Exchange (ETDEWEB)

    Wanlass, Mark W.; Carapella, Jeffrey J.

    2016-03-22

    Low bandgap, monolithic, multi-bandgap, optoelectronic devices (10), including PV converters, photodetectors, and LED's, have lattice-matched (LM), double-heterostructure (DH), low-bandgap GaInAs(P) subcells (22, 24) including those that are lattice-mismatched (LMM) to InP, grown on an InP substrate (26) by use of at least one graded lattice constant transition layer (20) of InAsP positioned somewhere between the InP substrate (26) and the LMM subcell(s) (22, 24). These devices are monofacial (10) or bifacial (80) and include monolithic, integrated, modules (MIMs) (190) with a plurality of voltage-matched subcell circuits (262, 264, 266, 270, 272) as well as other variations and embodiments.

  20. Efficient all solid-state continuous-wave yellow-orange light source

    DEFF Research Database (Denmark)

    Janousek, Jiri; Johansson, Sandra; Tidemand-Lichtenberg, Peter; Wang, Shunhua; Mortensen, Jesper Liltorp; Buchhave, Preben; Laurell, Fredrik

    2005-01-01

    We present highly efficient sum-frequency generation between two CW IR lasers using periodically poled KTP. The system is based on the 1064 and 1342 nm laser-lines of two Nd:YVO4 lasers. This is an all solid-state light source in the yellow-orange spectral range. The system is optimized in terms ...

  1. Nitrogen dissociation during RF sputtering of Lipon electrolyte for all-solid-states batteries

    DEFF Research Database (Denmark)

    Stamate, Eugen; Christiansen, Ane Sælland; Holtappels, Peter

    2013-01-01

    phosphorus oxynitride (Lipon), that can be compacted with the anode and cathode electrodes in an all-solid-states structure where the nitrogen incorporation is considered one of the key parameters for controlling the ionic conductivity. In this work the nitrogen dissociation during RF sputtering of Lipon...

  2. Efficient all solid-state continuous-wave yellow-orange light source

    DEFF Research Database (Denmark)

    Janousek, Jiri; Johansson, Sandra; Tidemand-Lichtenberg, Peter;

    2005-01-01

    We present highly efficient sum-frequency generation between two CW IR lasers using periodically poled KTP. The system is based on the 1064 and 1342 nm laser-lines of two Nd:YVO4 lasers. This is an all solid-state light source in the yellow-orange spectral range. The system is optimized in terms of...

  3. 光导在折射率引导光纤、多孔光纤、光子带隙光纤和纳米线中的简要定性解释%Simple qualitative explanations for light guidance in index-guiding fibres, holey fibres, photonic band-gap fibres and nanowires

    Institute of Scientific and Technical Information of China (English)

    LOVE John

    2014-01-01

    本文是一篇教学论文,旨在通过对具体实例中不同物理过程的分析来定性解释光导拓宽固体材料折射率引导光纤光谱、多孔光纤光谱、光子带隙光纤光谱和纳米线光谱的原理。%This is a tutorial-style paper in which simple explanations are presented to provide qualitative in-sight into the different physical processes that account for the guidance of light in the broadening spectrum of fibre types.These types include solid-material index-guiding fibres, holey fibres, photonic band-gap fibres and nano-wires.

  4. High Reversibility of Soft Electrode Materials in All-solid-state Batteries

    Directory of Open Access Journals (Sweden)

    Atsushi eSakuda

    2016-05-01

    Full Text Available All-solid-state batteries using inorganic solid electrolytes (SEs are considered to be ideal batteries for electric vehicles (EVs and plug-in hybrid electric vehicles (PHEVs because they are potentially safer than conventional lithium-ion batteries (LIBs. In addition, all-solid-state batteries are expected to have long battery lives owing to the inhibition of chemical side reactions because only lithium ions move through the typically used inorganic SEs. The development of high-energy (more than 300 Wh kg-1 secondary batteries has been eagerly anticipated for years. The application of high-capacity electrode active materials is essential for fabricating such batteries. Recently, we proposed metal polysulfides as new electrode materials. These materials show higher conductivity and density than sulfur, which is advantageous for fabricating batteries with relatively higher energy density. Lithium niobium sulfides, such as Li3NbS4, have relatively high density, conductivity, and rate capability among metal polysulfide materials, and batteries with these materials have capacities high enough to potentially exceed the gravimetric energy density of conventional LIBs.Favorable solid-solid contact between the electrode and electrolyte particles is a key factor for fabricating high performance all-solid-state batteries. Conventional oxide-based positive electrode materials tend to be given rise to cracks during fabrication and/or charge-discharge processes. Here we report all-solid-state cells using lithium niobium sulfide as a positive electrode material, where favorable solid-solid contact was established by using lithium sulfide electrode materials because of their high processability. Cracks were barely observed in the electrode particles in the all-solid-state cells before or after charging and discharging with a high capacity of approx. 400 mAh g-1, suggesting that the lithium niobium sulfide electrode charged and discharged without experiencing

  5. All-solid-state narrow-linewidth 455-nm blue laser based on Ti: sapphire crystal

    Institute of Scientific and Technical Information of China (English)

    Shankui Rong; Xiaolei Zhu; Weibiao Chen

    2009-01-01

    A compact, all-solid-state, narrow-linewidth, pulsed 455-nm blue laser based on Ti:sapphire crystal is developed. Pumped by a 10-Hz, frequency-doubled all-solid-state Nd:YAG laser and injection-seeded by an external cavity laser diode, the narrow-linewidth 910-nm laser with pulse width of 20 ns is obtained from a Tirsapphire laser. 3.43-mJ blue laser can be obtained from the laser system by frequency-doubling with BBO crystal. This research is very useful to determine the roadmap of developing the practical, high power blue laser. This kind of laser will have potential application for underwater communication.

  6. Fluorine-Doped Antiperovskite Electrolyte for All-Solid-State Lithium-Ion Batteries.

    Science.gov (United States)

    Li, Yutao; Zhou, Weidong; Xin, Sen; Li, Shuai; Zhu, Jinlong; Lü, Xujie; Cui, Zhiming; Jia, Quanxi; Zhou, Jianshi; Zhao, Yusheng; Goodenough, John B

    2016-08-16

    A fluorine-doped antiperovskite Li-ion conductor Li2 (OH)X (X=Cl, Br) is shown to be a promising candidate for a solid electrolyte in an all-solid-state Li-ion rechargeable battery. Substitution of F(-) for OH(-) transforms orthorhombic Li2 OHCl to a room-temperature cubic phase, which shows electrochemical stability to 9 V versus Li(+) /Li and two orders of magnitude higher Li-ion conductivity than that of orthorhombic Li2 OHCl. An all-solid-state Li/LiFePO4 with F-doped Li2 OHCl as the solid electrolyte showed good cyclability and a high coulombic efficiency over 40 charge/discharge cycles. PMID:27356953

  7. Oxide-ceramic electrolyte layers for all-solid-state lithium batteries

    OpenAIRE

    Reppert, Thorsten; Tsai, Chih-Long; Finsterbusch, Martin; Uhlenbruck, Sven; Guillon, Olivier; Bram, Martin

    2015-01-01

    In the past decade, electricity generated from renewable energy sources, as well as electro mobility have gained much importance in our society. With this readiness to change the current system, an increase of requirements for electric grid and safety aspects of energy storage systems appear. All-solid-state lithium batteries (ASB) have better safety properties due to the non-flammable solid electrolyte than common lithium ion batteries (LIB), which use flammable organic liquid as electrolyte...

  8. Mechanical and electrochemical response of all-solid-state lithium-ion batteries

    OpenAIRE

    Bucci, Giovanna; Carter, W. Craig; Chiang, Yet-Ming

    2014-01-01

    All-solid-state rechargeable lithium-ion batteries have attracted much interest because they have features particularly favorable for large-scale application to automotive applications and to stationary load-leveling for intermittent power generation from solar or wind energy. The replacement of an organic liquid electrolyte with a nonflammable and more reliable inorganic solid electrolyte (SE) simplifies the battery design and improves safety and durability of the system [1]. However, the me...

  9. Sub-micrometer-thick all-solid-state supercapacitors with high power and energy densities

    Energy Technology Data Exchange (ETDEWEB)

    Meng, Fanhui [Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials, Ministry of Education, and School of Chemistry and Chemical Engineering, Shandong University, Jinan 250061 (China); Ding, Yi [Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials, Ministry of Education, and School of Chemistry and Chemical Engineering, Shandong University, Jinan 250061 (China); Shandong Applied Research Center for Gold Technology (Au-SDARC), Yantai 264005 (China)

    2011-09-15

    A sub-micrometer-thick, flexible, all-solid-state supercapacitor is fabricated. Through simultaneous realization of high dispersity of pseudocapacitance materials and quick electrode response, the hybrid nanostructures show enhanced volumetric capacitance and excellent stability, as well as very high power and energy densities. This suggests their potential as next-generation, high-performance energy conversion and storage devices for wearable electronics. (Copyright copyright 2011 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  10. Super Soft All-Ethylene Oxide Polymer Electrolyte for Safe All-Solid Lithium Batteries

    OpenAIRE

    Luca Porcarelli; Claudio Gerbaldi; Federico Bella; Jijeesh Ravi Nair

    2016-01-01

    Here we demonstrate that by regulating the mobility of classic −EO− based backbones, an innovative polymer electrolyte system can be architectured. This polymer electrolyte allows the construction of all solid lithium-based polymer cells having outstanding cycling behaviour in terms of rate capability and stability over a wide range of operating temperatures. Polymer electrolytes are obtained by UV-induced (co)polymerization, which promotes an effective interlinking between the polyethylene o...

  11. High repetition rate, compact micro-pulse all-solid-state laser

    Institute of Scientific and Technical Information of China (English)

    Yutong Feng; Junqing Meng; Weibiao Chen

    2007-01-01

    A high repetition rate, compact micro-pulse all-solid-state laser is designed. The diffusion bonded crystal of YAG, Nd:YAG, and Cr4+:YAG is taken as a monolithic cavity. The optimized initial transmission,output coupling, and pumping size of Cr4+:YAG are calculated. The experimental results show that the laser satisfies the requirement of a spaceborne laser range finder.

  12. High-power all-solid-state batteries using sulfide superionic conductors

    Science.gov (United States)

    Kato, Yuki; Hori, Satoshi; Saito, Toshiya; Suzuki, Kota; Hirayama, Masaaki; Mitsui, Akio; Yonemura, Masao; Iba, Hideki; Kanno, Ryoji

    2016-04-01

    Compared with lithium-ion batteries with liquid electrolytes, all-solid-state batteries offer an attractive option owing to their potential in improving the safety and achieving both high power and high energy densities. Despite extensive research efforts, the development of all-solid-state batteries still falls short of expectation largely because of the lack of suitable candidate materials for the electrolyte required for practical applications. Here we report lithium superionic conductors with an exceptionally high conductivity (25 mS cm‑1 for Li9.54Si1.74P1.44S11.7Cl0.3), as well as high stability ( ∼0 V versus Li metal for Li9.6P3S12). A fabricated all-solid-state cell based on this lithium conductor is found to have very small internal resistance, especially at 100 ∘C. The cell possesses high specific power that is superior to that of conventional cells with liquid electrolytes. Stable cycling with a high current density of 18 C (charging/discharging in just three minutes; where C is the C-rate) is also demonstrated.

  13. Comprehensive characterization of all-solid-state thin films commercial microbatteries by Electrochemical Impedance Spectroscopy

    Science.gov (United States)

    Larfaillou, S.; Guy-Bouyssou, D.; le Cras, F.; Franger, S.

    2016-07-01

    Constant miniaturization of electronic devices opens the way to the development of thin film microbatteries (TFB). For this type of devices, the use of an all-solid-state thin film technology has many advantages over conventional lithium cells. These microbatteries are thin, bendable and can be produced with a customizable shape for integration in microelectronic devices. Moreover, without liquid electrolyte, they are safer. With the aim to support the industrial production of these TFBs, adequate tools for understanding the electrochemical behavior of the complete microbattery and the identification of their possible failures that can occur have to be developed. In this context, the Electrochemical Impedance Spectroscopy seems to be a good compromise for cells characterization. Widely used for the characterization of liquid electrolyte-based batteries, this technique has been less applied to all solid state batteries, mainly because of the difficulty to work with a two-electrode system. There has been no comprehensive study deeply explaining the impedance evolution during the entire life of a microbattery. In this paper, physical characterizations of individual active materials and aging experiments have been performed in order to undoubtedly assign each EIS contributions, and to propose a more comprehensive electrical model for this family of commercial all-solid-state microbatteries.

  14. Two-Dimentional Photonic Crystal Waveguides

    DEFF Research Database (Denmark)

    Søndergaard, Thomas; Dridi, Kim

    1999-01-01

    In the recent years a new class of periodic high-index contrast dielectric structures, known as photonic bandgap structures, has been discovered. In these structures frequency intervals, known as photonic bandgaps, where propagation of electromagnetic waves is not allowed, exist due to the periodic...... dielectric function. This is analogous to semiconductors, where electronic bandgaps exist due to the periodic arrangement of atoms. As is also the case for semiconductor structures, photonic bandgap structures may become of even greater value when defects are introduced. In particular, point defects make...... possible a novel class of optical microcavities, whereas line defects make possible a novel class of waveguides. In this paper we will analyze two-dimensional photonic crystal waveguides based on photonic crystals with rods arranged on a triangular and a square lattice using a plane-wave expansion method...

  15. Fabrication and Performance of All-Solid-State Chloride Sensors in Synthetic Concrete Pore Solutions

    OpenAIRE

    Gao, Xiaojian; Zhang, Jian; Yang, Yingzi; Deng, Hongwei

    2010-01-01

    One type of all-solid-state chloride sensor was fabricated using a MnO2 electrode and a Ag/AgCl electrode. The potentiometric response of the sensor to chloride in synthetic concrete pore solutions was systematically studied, and the polarization performance was also evaluated. The results show a good linear relationship between the potential reading of the sensor and the logarithm of chloride activity (concentration ranges from 0.05 to 5.0 M), and the potential value remains stable with incr...

  16. High Energy, Single-Mode, All-Solid-State Nd:YAG Laser

    Science.gov (United States)

    Prasad, Narasimha S.; Singh, Upendra N.; Hovis, Floyd

    2006-01-01

    In this paper, recent progress made in the design and development of an all-solid-state, single longitudinal mode, conductively cooled Nd:YAG laser operating at 1064 nm wavelength for UV lidar for ozone sensing applications is presented. Currently, this pump laser provides an output pulse energy of greater than 1.1 J/pulse at 50 Hz PRF and a pulsewidth of 22 ns. The spatial profile of the output beam is a rectangular super Gaussian. Electrical-to-optical system efficiency of greater than 7% and a minimum M(sup 2) value of less than 2 have been achieved.

  17. High power, broadly tunable all-solid-state synchronously-pumped lithium triborate optical parametric oscillator

    OpenAIRE

    Butterworth, S.D.; Girard, S; Hanna, D.C.

    1995-01-01

    The performance of a high-power all-solid-state synchronously-pumped optical parametric oscillator (OPO) based on a Brewster-angled lithium triborate (LBO) crystal is reported. The pump scheme includes a diode-pumped amplifier stage to boost the mean output power from an additive-pulse mode-locked Nd:YLF laser by a factor of two. Improvements in the efficiency of an external resonant frequency-doubler have produced a useful output power of 660mW at 523.5µm for pumping the OPO. Temperature-tun...

  18. All-solid-state lithium batteries with inorganic solid electrolytes: Review of fundamental science

    Science.gov (United States)

    Xiayin, Yao; Bingxin, Huang; Jingyun, Yin; Gang, Peng; Zhen, Huang; Chao, Gao; Deng, Liu; Xiaoxiong, Xu

    2016-01-01

    The scientific basis of all-solid-state lithium batteries with inorganic solid electrolytes is reviewed briefly, touching upon solid electrolytes, electrode materials, electrolyte/electrode interface phenomena, fabrication, and evaluation. The challenges and prospects are outlined as well. Project supported by the National High Technology Research and Development Program of China (Grant No. 2013AA050906), the National Natural Science Foundation of China (Grant Nos. 51172250 and 51202265), the Strategic Priority Research Program of the Chinese Academy of Sciences (Grant No. XDA09010201), and Zhejiang Province Key Science and Technology Innovation Team, China (Grant No. 2013PT16).

  19. An all-solid-state laser source at 671 nm for cold atom experiments with lithium

    OpenAIRE

    Eismann, U.; Gerbier, F.; Canalias, C.; Zukauskas, A.; Trénec, G.; Vigué, J.; Chevy, F.; Salomon, C.

    2012-01-01

    International audience We present an all solid-state narrow line\\-width laser source emitting $670\\,\\mathrm{mW}$ output power at $671\\,\\mathrm{nm}$ delivered in a diffraction-limited beam. The \\linebreak source is based on a fre\\-quency-doubled diode-end-\\linebreak pumped ring laser operating on the ${^4F}_{3/2} \\rightarrow {^4I}_{13/2}$ transition in Nd:YVO$_4$. By using periodically-poled po\\-tassium titanyl phosphate (ppKTP) in an external build\\-up cavity, doubling efficiencies of up t...

  20. Wide Bandgap Extrinsic Photoconductive Switches

    Energy Technology Data Exchange (ETDEWEB)

    Sullivan, James S. [State Univ. of New York (SUNY), Plattsburgh, NY (United States); Univ. of California, Davis, CA (United States)

    2012-01-20

    Photoconductive semiconductor switches (PCSS) have been investigated since the late 1970s. Some devices have been developed that withstand tens of kilovolts and others that switch hundreds of amperes. However, no single device has been developed that can reliably withstand both high voltage and switch high current. Yet, photoconductive switches still hold the promise of reliable high voltage and high current operation with subnanosecond risetimes. Particularly since good quality, bulk, single crystal, wide bandgap semiconductor materials have recently become available. In this chapter we will review the basic operation of PCSS devices, status of PCSS devices and properties of the wide bandgap semiconductors 4H-SiC, 6H-SiC and 2H-GaN.

  1. Electronic structure characterization and bandgap engineering of solar hydrogen materials

    International Nuclear Information System (INIS)

    Bandgap, band edge positions as well as the overall band structure of semiconductors are of crucial importance in photoelectrochemical and photocatalytic applications. The energy position of the band edge level can be controlled by the electronegativity of the dopants, the pH of the solution (flatband potential variation of 60 mV per pH unit), as well as by quantum confinement effects. Accordingly, band edges and bandgap can be tailored to achieve specific electronic, optical or photocatalytic properties. Synchrotron radiation with photon energy at or below 1 keV is giving new insight into such areas as condensed matter physics and extreme ultraviolet optics technology. In the soft x-ray region, the question tends to be, what are the electrons doing as they migrated between the atoms. In this paper, I will present a number of soft x-ray spectroscopic study of nanostructured 3d metal compounds Fe2O3 and ZnO

  2. Wide Bandgap Extrinsic Photoconductive Switches

    Energy Technology Data Exchange (ETDEWEB)

    Sullivan, James S. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

    2013-07-03

    Semi-insulating Gallium Nitride, 4H and 6H Silicon Carbide are attractive materials for compact, high voltage, extrinsic, photoconductive switches due to their wide bandgap, high dark resistance, high critical electric field strength and high electron saturation velocity. These wide bandgap semiconductors are made semi-insulating by the addition of vanadium (4H and 6HSiC) and iron (2H-GaN) impurities that form deep acceptors. These deep acceptors trap electrons donated from shallow donor impurities. The electrons can be optically excited from these deep acceptor levels into the conduction band to transition the wide bandgap semiconductor materials from a semi-insulating to a conducting state. Extrinsic photoconductive switches with opposing electrodes have been constructed using vanadium compensated 6H-SiC and iron compensated 2H-GaN. These extrinsic photoconductive switches were tested at high voltage and high power to determine if they could be successfully used as the closing switch in compact medical accelerators.

  3. New Light-Harvesting Materials Using Accurate and Efficient Bandgap Calculations

    DEFF Research Database (Denmark)

    Castelli, Ivano Eligio; Hüser, Falco; Pandey, Mohnish;

    2014-01-01

    materials for different applications where the bandgaps are used as descriptors for the efficiency of a photoelectrochemical device. Here, new light harvesting materials are proposed to be used in a one-photon photoelectrochemical device for water splitting by combining the estimation of the bandgaps with......Electronic bandgap calculations are presented for 2400 experimentally known materials from the Materials Project database and the bandgaps, obtained with different types of functionals within density functional theory and (partial) self-consistent GW approximation, are compared for 20 randomly...... chosen compounds forming an unconventional set of ternary and quaternary materials. It is shown that the computationally cheap GLLB-SC potential gives results in good agreement (around 15%) with the more advanced and demanding eigenvalue-self-consistent GW. This allows for a high-throughput screening of...

  4. Resonant add-drop filter based on a photonic quasicrystal

    DEFF Research Database (Denmark)

    Romero-Vivas, J.; Chigrin, D. N.; Lavrinenko, Andrei;

    2005-01-01

    We present a numerical study of optical properties of an octagonal quasi-periodic lattice of dielectric rods. We report on a complete photonic bandgap in TM polarization up to extremely low dielectric constants of rods. The first photonic bandgap remains open down to dielectric constant as small ...

  5. Room-temperature single-photon sources based on nanocrystal fluorescence in photonic/plasmonic nanostructures

    Science.gov (United States)

    Lukishova, S. G.; Winkler, J. M.; Bissell, L. J.; Mihaylova, D.; Liapis, Andreas C.; Shi, Z.; Goldberg, D.; Menon, V. M.; Boyd, R. W.; Chen, G.; Prasad, P.

    2014-10-01

    Results are presented here towards robust room-temperature SPSs based on fluorescence in nanocrystals: colloidal quantum dots, color-center diamonds and doped with trivalent rare-earth ions (TR3+). We used cholesteric chiral photonic bandgap and Bragg-reflector microcavities for single emitter fluorescence enhancement. We also developed plasmonic bowtie nanoantennas and 2D-Si-photonic bandgap microcavities. The paper also provides short outlines of other technologies for room-temperature single-photon sources.

  6. All-Solid-State UV Transmitter Development for Ozone Sensing Applications

    Science.gov (United States)

    Prasad, Narasimha S.; Singh, Upendra N.; Armstrong, Darrell Jr.

    2009-01-01

    In this paper, recent progress made in the development of an all-solid-state UV transmitter suitable for ozone sensing applications from space based platforms is discussed. A nonlinear optics based UV setup based on Rotated Image Singly Resonant Twisted Rectangle (RISTRA) optical parametric oscillator (OPO) module was effectively coupled to a diode pumped, single longitudinal mode, conductively cooled, short-pulsed, high-energy Nd:YAG laser operating at 1064 nm with 50 Hz PRF. An estimated 10 mJ/pulse with 10% conversion efficiency at 320 nm has been demonstrated limited only by the pump pulse spatial profile. The current arrangement has the potential for obtaining greater than 200 mJ/pulse. Previously, using a flash-lamp pumped Nd:YAG laser with round, top-hat profile, up to 24% IR-UV conversion efficiency was achieved with the same UV module. Efforts are underway to increase the IR-UV conversion efficiency of the all solid-state setup by modifying the pump laser spatial profile along with incorporating improved OPO crystals.

  7. Characterization of All Solid State Hydrogen Ion Selective Electrode Based on PVC-SR Hybrid Membranes

    Directory of Open Access Journals (Sweden)

    Yoon-Bo Shim

    2003-06-01

    Full Text Available Hydrogen ion selective membranes formulated with 3140 RTV silicone rubber (SR in PVC were studied to extend the life time of solid state ion sensors through improved membrane adhesion. All solid state hydrogen ion selective electrodes were prepared by incorporation of tridodecyl amine (TDDA as an ionophore, potassium tetrakis[3.5-bis(p-chlorophenylborate (KTpClPB as a lipophilic additive, bis(2-ethylhexyladipate (DOA as a plasticizer. Their linear dynamic range was pH 2.0-11.0 and showed the near Nernstian slope of 55.1±0.2 mV/pH (r=0.999. The ifluences from alkali and alkaline earth metal ions were studied for the response of the final ISE membrane composition. Impedance spectroscopic data showed that the resistance was increased by increasing SR content in PVC. Brewster Angle Microscopy (BAM image showed clear differences according to the SR compositions in PVC. Life time of the all solid state membrane electrode was extended to about 2 months by preparing the membrane with PVC and SR. The standard reference material from NIST (2181 HEPES Free acid and 2182 NaHEPESate was tested for the ISE and it gave good result.

  8. 1047-nm all-solid-state laser based on Nd: LuLF

    Institute of Scientific and Technical Information of China (English)

    Rui Li; Ting Yu; Lianhan Zhang; Weibiao Chen; Yin Hang

    2011-01-01

    @@ A compact all-solid-state continuous-wave (CW) laser at 1047 nm is developed based on Nd:LuLF, which is grown through the Czochralski technique. From the laser system, 1.3-W laser can be obtained, which corresponds to the slope efficiencies of 20.1% and 49.5% with respect to the incident and absorbed pump powers, respectively. To the best of our knowledge, this is the highest power level achieved at 1047 nm based on the Nd:LuLF crystal.%A compact all-solid-state continuous-wave (CW) laser at 1047 nm is developed based on Nd:LuLF, which is grown through the Czochralski technique. From the laser system, 1.3-W laser can be obtained, which corresponds to the slope efficiencies of 20.1% and 49.5% with respect to the incident and absorbed pump powers, respectively. To the best of our knowledge, this is the highest power level achieved at 1047 nm based on the Nd:LuLF crystal.

  9. All Solid-State Lithium Metal Batteries Using Cross-linked Polymer Electrolytes

    Science.gov (United States)

    Pan, Qiwei; Li, Christopher; Soft Materials Team

    Nowadays, to prepare all solid-state lithium metal batteries with high rate capability and stability using solid polymer electrolytes (SPEs) is still a grand challenge because of the interfaces between the SPE and the electrodes. In this presentation, we report a series of hybrid SPEs with controlled network structures by using POSS as cross-linker. These hybrid network SPEs show promising ionic conductivity, mechanical properties, and lithium dendrite growth resistance. All solid-state LiFePO4/Li batteries were also prepared using these SPEs as the electrolytes to study the effect of conductivity and mechanical properties of the SPEs on the performance of the batteries. At 90 °C, the prepared cells show high rate capability and stability. Capacity up to 160 mAh/g can be obtained at a C/2 rate during the galvanostatic cycling. Capacity retention of the cells is higher than 80% after 250 cycles. Battery performance at 60 °C and decay mechanism of the batteries will also be discussed.

  10. All-solid state flexible supercapacitors based on graphene/polymer composites

    International Nuclear Information System (INIS)

    Recent advances in lightweight, flexible, and wearable electronic equipment has led to advancements in the development of sufficiently compact and flexible energy storage. A challenge remains to integrate the storage elements as closely as possible within a fully flexible device. Here, we demonstrate the fabrication of all-solid state flexible supercapacitors with the integration of two electrodes that consist of graphene/polymer composites. Robust conductive free-standing thin graphene/polymer composite electrodes were prepared through a simple “physical grinding” process. As-prepared composite electrodes store energy up to a reversible gravimetric capacitance of 90.6 F/g, at a constant current density of 0.5 A/g while also delivering long-term durability (90% retention) for excess of five-thousands of cycles. Notably, the enhancement of mechanical properties of supercapacitors enables them to maintain their electrochemical performance even when twisted or folded. This straightforward approach to the fabrication of fully flexible supercapacitors provides new design opportunities within wearable electronics and electrochemical applications. - Highlights: • All solid-sate supercapacitors were fabricated using graphene/polymer composite electrodes. • Supercapacitor devices show an excellent mechanical flexibility. • High electrochemical performances were demonstrated

  11. In Situ STEM-EELS Observation of Nanoscale Interfacial Phenomena in All-Solid-State Batteries.

    Science.gov (United States)

    Wang, Ziying; Santhanagopalan, Dhamodaran; Zhang, Wei; Wang, Feng; Xin, Huolin L; He, Kai; Li, Juchuan; Dudney, Nancy; Meng, Ying Shirley

    2016-06-01

    Behaviors of functional interfaces are crucial factors in the performance and safety of energy storage and conversion devices. Indeed, solid electrode-solid electrolyte interfacial impedance is now considered the main limiting factor in all-solid-state batteries rather than low ionic conductivity of the solid electrolyte. Here, we present a new approach to conducting in situ scanning transmission electron microscopy (STEM) coupled with electron energy loss spectroscopy (EELS) in order to uncover the unique interfacial phenomena related to lithium ion transport and its corresponding charge transfer. Our approach allowed quantitative spectroscopic characterization of a galvanostatically biased electrochemical system under in situ conditions. Using a LiCoO2/LiPON/Si thin film battery, an unexpected structurally disordered interfacial layer between LiCoO2 cathode and LiPON electrolyte was discovered to be inherent to this interface without cycling. During in situ charging, spectroscopic characterization revealed that this interfacial layer evolved to form highly oxidized Co ions species along with lithium oxide and lithium peroxide species. These findings suggest that the mechanism of interfacial impedance at the LiCoO2/LiPON interface is caused by chemical changes rather than space charge effects. Insights gained from this technique will shed light on important challenges of interfaces in all-solid-state energy storage and conversion systems and facilitate improved engineering of devices operated far from equilibrium. PMID:27140196

  12. Super Soft All-Ethylene Oxide Polymer Electrolyte for Safe All-Solid Lithium Batteries

    Science.gov (United States)

    Porcarelli, Luca; Gerbaldi, Claudio; Bella, Federico; Nair, Jijeesh Ravi

    2016-01-01

    Here we demonstrate that by regulating the mobility of classic -EO- based backbones, an innovative polymer electrolyte system can be architectured. This polymer electrolyte allows the construction of all solid lithium-based polymer cells having outstanding cycling behaviour in terms of rate capability and stability over a wide range of operating temperatures. Polymer electrolytes are obtained by UV-induced (co)polymerization, which promotes an effective interlinking between the polyethylene oxide (PEO) chains plasticized by tetraglyme at various lithium salt concentrations. The polymer networks exhibit sterling mechanical robustness, high flexibility, homogeneous and highly amorphous characteristics. Ambient temperature ionic conductivity values exceeding 0.1 mS cm-1 are obtained, along with a wide electrochemical stability window (>5 V vs. Li/Li+), excellent lithium ion transference number (>0.6) as well as interfacial stability. Moreover, the efficacious resistance to lithium dendrite nucleation and growth postulates the implementation of these polymer electrolytes in next generation of all-solid Li-metal batteries working at ambient conditions.

  13. All-solid-state supercapacitors on silicon using graphene from silicon carbide

    Science.gov (United States)

    Wang, Bei; Ahmed, Mohsin; Wood, Barry; Iacopi, Francesca

    2016-05-01

    Carbon-based supercapacitors are lightweight devices with high energy storage performance, allowing for faster charge-discharge rates than batteries. Here, we present an example of all-solid-state supercapacitors on silicon for on-chip applications, paving the way towards energy supply systems embedded in miniaturized electronics with fast access and high safety of operation. We present a nickel-assisted graphitization method from epitaxial silicon carbide on a silicon substrate to demonstrate graphene as a binder-free electrode material for all-solid-state supercapacitors. We obtain graphene electrodes with a strongly enhanced surface area, assisted by the irregular intrusion of nickel into the carbide layer, delivering a typical double-layer capacitance behavior with a specific area capacitance of up to 174 μF cm-2 with about 88% capacitance retention over 10 000 cycles. The fabrication technique illustrated in this work provides a strategic approach to fabricate micro-scale energy storage devices compatible with silicon electronics and offering ultimate miniaturization capabilities.

  14. All-solid state flexible supercapacitors based on graphene/polymer composites

    Energy Technology Data Exchange (ETDEWEB)

    Kim, Jung Won; Choi, Bong Gill, E-mail: bgchoi@kangwon.ac.kr

    2015-06-01

    Recent advances in lightweight, flexible, and wearable electronic equipment has led to advancements in the development of sufficiently compact and flexible energy storage. A challenge remains to integrate the storage elements as closely as possible within a fully flexible device. Here, we demonstrate the fabrication of all-solid state flexible supercapacitors with the integration of two electrodes that consist of graphene/polymer composites. Robust conductive free-standing thin graphene/polymer composite electrodes were prepared through a simple “physical grinding” process. As-prepared composite electrodes store energy up to a reversible gravimetric capacitance of 90.6 F/g, at a constant current density of 0.5 A/g while also delivering long-term durability (90% retention) for excess of five-thousands of cycles. Notably, the enhancement of mechanical properties of supercapacitors enables them to maintain their electrochemical performance even when twisted or folded. This straightforward approach to the fabrication of fully flexible supercapacitors provides new design opportunities within wearable electronics and electrochemical applications. - Highlights: • All solid-sate supercapacitors were fabricated using graphene/polymer composite electrodes. • Supercapacitor devices show an excellent mechanical flexibility. • High electrochemical performances were demonstrated.

  15. Ultrahigh photoconductivity of bandgap-graded CdSxSe1‑x nanowires probed by terahertz spectroscopy

    Science.gov (United States)

    Liu, Hongwei; Lu, Junpeng; Yang, Zongyin; Teng, Jinghua; Ke, Lin; Zhang, Xinhai; Tong, Limin; Sow, Chorng Haur

    2016-06-01

    Superiorly high photoconductivity is desirable in optoelectronic materials and devices for information transmission and processing. Achieving high photoconductivity via bandgap engineering in a bandgap-graded semiconductor nanowire has been proposed as a potential strategy. In this work, we report the ultrahigh photoconductivity of bandgap-graded CdSxSe1‑x nanowires and its detailed analysis by means of ultrafast optical-pump terahertz-probe (OPTP) spectroscopy. The recombination rates and carrier mobility are quantitatively obtained via investigation of the transient carrier dynamics in the nanowires. By analysis of the terahertz (THz) spectra, we obtain an insight into the bandgap gradient and band alignment to carrier transport along the nanowires. The demonstration of the ultrahigh photoconductivity makes bandgap-graded CdSxSe1‑x nanowires a promising candidate as building blocks for nanoscale electronic and photonic devices.

  16. High Energy, Single-Mode, All-Solid-State and Tunable UV Laser Transmitter

    Science.gov (United States)

    Prasad, Narasimha S.; Singh, Upendra N.; Hovis, FLoyd

    2007-01-01

    A high energy, single mode, all solid-state Nd:YAG laser primarily for pumping an UV converter is developed. Greater than 1 J/pulse at 50 HZ PRF and pulse widths around 22 ns have been demonstrated. Higher energy, greater efficiency may be possible. Refinements are known and practical to implement. Technology Demonstration of a highly efficient, high-pulse-energy, single mode UV wavelength generation using flash lamp pumped laser has been achieved. Greater than 90% pump depletion is observed. 190 mJ extra-cavity SFG; IR to UV efficiency > 21% (> 27% for 1 mJ seed). 160 mJ intra-cavity SFG; IR to UV efficiency up to 24% Fluence laser is being refined to match or exceed the above UV converter results. Currently the Nd:YAG pump laser development is a technology demonstration. System can be engineered for compact packaging.

  17. All-Solid-State Multi-wavelength Laser System from 208 to 830 nm

    Institute of Scientific and Technical Information of China (English)

    ZHAO Shang-Hong; CHEN Guo-Fu; ZHAO Wei; WANG Yi-Shan; YU Lian-Jun

    2001-01-01

    Four-wavelength lasers from the near-infrared to deep-ultraviolet range, 532, 830, 415 and 208nm, have been developed in one all-solid-state laser system. The laser system is pumped by a diode-Q-YLF laser at 532nm,a Ti:sapphire laser, and the nonlinear second-harmonic-generation crystals LBO and BBO are used to generate different wavelengths. Maximum average powers (repetition rate 1 kHz) of 1.1 W at 830nm, 380m W at 415nm and 39mW at 208nm are obtained when the pumping power is 3.6 W. The main characteristics of this system are presented.

  18. High efficiency single frequency 355 nm all-solid-state UV laser

    Science.gov (United States)

    Xie, Xiaobing; Wei, Daikang; Ma, Xiuhua; Li, Shiguang; Liu, Jiqiao; Zhu, Xiaolei; Chen, Weibiao

    2016-05-01

    A novel conductively cooled high energy single-frequency 355 nm all-solid-state UV laser is presented based on sum-frequency mixing technique. In this system, a pulsed seeder laser at 1064 nm wavelength, modulated by an AOM, is directly amplified by the cascaded multi-stage hybrid laser amplifiers, and two LBO crystals are used for the SHG and SFG, finally a maximum UV pulse energy of 226 mJ at 355 nm wavelength is achieved with frequency-tripled conversion efficiency as high as 55%, the pulse width is around 12.2 ns at the repetition frequency of 30 Hz. The beam quality factor M 2 of the output UV laser is measured to be 2.54 and 2.98 respectively in two orthogonal directions.

  19. Design and Characterisation of Solid Electrolytes for All-Solid-State Lithium Batteries

    DEFF Research Database (Denmark)

    Sveinbjörnsson, Dadi Þorsteinn

    The development of all-solid-state lithium batteries, in which the currently used liquid electrolytes are substituted for solid electrolyte materials, could lead to safer batteries offering higher energy densities and longer cycle lifetimes. Designing suitable solid electrolytes with sufficient...... chemical and electrochemical stability, high lithium ion conduction and negligible electronic conduction remains a challenge. The highly lithium ion conducting LiBH4-LiI solid solution is a promising solid electrolyte material. Solid solutions with a LiI content of 6.25%-50% were synthesised by planetary......-rich microstructures during ball milling is found to significantly influence the conductivity of the samples. The long-range diffusion of lithium ions was measured using quasi-elastic neutron scattering. The solid solutions are found to exhibit two-dimensional conduction in the hexagonal plane of the crystal structure...

  20. The research on the micro-processing-used all-solid-state picosecond laser

    Science.gov (United States)

    Bai, Zhen-xu; Ai, Qing-kang; Duan, Jin-peng; Chen, Meng; Li, Gang

    2012-04-01

    A micro processing used LD end-pumped Nd:YVO4 all solid-state picosecond pulse laser was demonstrated under the semiconductor saturable absorption mirror(SESAM) mode-locking technology and regeneration amplifier technology, by using BBO crystal as electro-optic crystal and diode-side-pumped Nd:YAG. 1064nm laser was obtained with 1.47mJ single pulse energy, 15ps pulse width at 1 kHz repetition rate and the pulse energy fluctuation was less than 0.6% in 3 hours operation. Finally, through the galvanometric we got the beam focused, realizing the steel plate processing which thickness was 0.5mm and the aperture radius was 25.5μm.

  1. An all-solid-state laser source at 671 nm for cold atom experiments with lithium

    CERN Document Server

    Eismann, Ulrich; Canalias, Carlota; Zukauskas, Andrius; Trénec, Gérard; Vigué, Jacques; Chevy, Frédéric; Salomon, Christophe

    2011-01-01

    We present an all solid-state narrow line-width laser source emitting $670\\,\\mathrm{mW}$ output power at $671\\,\\mathrm{nm}$ delivered in a diffraction-limited beam. The source is based on a frequency-doubled diode-end-pumped ring laser operating on the ${^4F}_{3/2} \\rightarrow {^4I}_{13/2}$ transition in Nd:YVO$_4$. By using periodically-poled potassium titanyl phosphate (ppKTP) in an external build-up cavity, doubling efficiencies of up to 86% are obtained. Tunability of the source over $100\\,\\rm GHz$ is accomplished. We demonstrate the suitability of this robust frequency-stabilized light source for laser cooling of lithium atoms. Finally a simplified design based on intra-cavity doubling is described and first results are presented.

  2. An All Solid-State Pulsed Power Generator for Plasma Immersion Ion Implantation (PⅢ)

    Institute of Scientific and Technical Information of China (English)

    LIU Kefu; QIU Jian; WU Yifan

    2009-01-01

    An all solid-state pulsed power generator for plasma immersion ion implantation (PⅢ) is described. The pulsed power system is based on a Marx circuit configuration and semi-conductor switches, which have many advantages in adjustable repetition frequency, pulse width modulation and long serving life compared with the conventional circuit category, tube-based technologies such as gridded vacuum tubes, thyratrons, pulse forming networks and transformers.The operation of PⅢ with pulse repetition frequencies up to 500 Hz has been achieved at a pulse voltage amplitude from 2 kV to 60 kV, with an adjustable pulse duration from 1 μs to 100 μs.The proposed system and its performance, as used to drive a plasma ion implantation chamber,axe described in detail on the basis of the experimental results.

  3. Two-dimensional tin selenide nanostructures for flexible all-solid-state supercapacitors.

    Science.gov (United States)

    Zhang, Chunli; Yin, Huanhuan; Han, Min; Dai, Zhihui; Pang, Huan; Zheng, Yulin; Lan, Ya-Qian; Bao, Jianchun; Zhu, Jianmin

    2014-04-22

    Due to their unique electronic and optoelectronic properties, tin selenide nanostructures show great promise for applications in energy storage and photovoltaic devices. Despite the great progress that has been achieved, the phase-controlled synthesis of two-dimensional (2D) tin selenide nanostructures remains a challenge, and their use in supercapacitors has not been explored. In this paper, 2D tin selenide nanostructures, including pure SnSe2 nanodisks (NDs), mixed-phase SnSe-SnSe2 NDs, and pure SnSe nanosheets (NSs), have been synthesized by reacting SnCl2 and trioctylphosphine (TOP)-Se with borane-tert-butylamine complex (BTBC) and 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone. Utilizing the interplay of TOP and BTBC and changing only the amount of BTBC, the phase-controlled synthesis of 2D tin selenide nanostructures is realized for the first time. Phase-dependent pseudocapacitive behavior is observed for the resulting 2D nanostructures. The specific capacitances of pure SnSe2 NDs (168 F g(-1)) and SnSe NSs (228 F g(-1)) are much higher than those of other reported materials (e.g., graphene-Mn3O4 nanorods and TiN mesoporous spheres); thus, these tin selenide materials were used to fabricate flexible, all-solid-state supercapacitors. Devices fabricated with these two tin selenide materials exhibited high areal capacitances, good cycling stabilities, excellent flexibilities, and desirable mechanical stabilities, which were comparable to or better than those reported recently for other solid-state devices based on graphene and 3D GeSe2 nanostructures. Additionally, the rate capability of the SnSe2 NDs device was much better than that of the SnSe NS device, indicating that SnSe2 NDs are promising active materials for use in high-performance, flexible, all-solid-state supercapacitors. PMID:24601530

  4. Development of Spintronic Bandgap Materials

    Energy Technology Data Exchange (ETDEWEB)

    Levy, Jeremy; Awschalom, David; Floro, Jerrold

    2014-02-16

    The development of Ge/Si quantum dots with high spatial precision has been pursued, with the goal of developing a platform for “spintronics bandgap materials”. Quantum dots assemblies were grown by molecular beam epitaxy on carbon-templated silicon substrates. These structures were characterized by atomic force microscopy. Vertically gated structures were created on systems with up to six well-defined quantum dots with a controlled geometric arrangement, and low-temperature (mK) transport experiments were performed. These experiments showed evidence for a crossover from diamagnetic to Zeeman energy shifts in resonant tunneling of electrons through electronic states in the quantum dots.

  5. Photonic band gap of 2D complex lattice photonic crystal

    Institute of Scientific and Technical Information of China (English)

    GUAN Chun-ying; YUAN Li-bo

    2009-01-01

    It is of great significance to present a photonic crystal lattice structure with a wide photonic bandgap. A two-dimension complex lattice photonic crystal is proposed. The photonic crystal is composed of complex lattices with triangular structure, and each single cell is surrounded by six scatterers in an hexagon. The photonic band gaps are calculated based on the plane wave expansion (PWE) method. The results indicate that the photonic crystal has tunable large TM polarization band gap, and a gap-midgap ratio of up to 45.6%.

  6. Photonic crystals in epitaxial semiconductors

    CERN Document Server

    La Rue, R M de

    1998-01-01

    The title of the paper uses the expression "photonic crystals". By photonic crystals, we mean regular periodic structures with a substantial refractive index variation in one-, two- or three- dimensional space. Such crystals can $9 exist naturally, for example natural opal, but are more typically fabricated by people. Under sufficiently strong conditions, i.e., sufficiently large refractive index modulation, correct size of structural components, and $9 appropriate rotational and translational symmetry, these crystals exhibit the characteristics of a photonic bandgap (PBG) structure. In a full photonic bandgap structure there is a spectral stop band for electromagnetic waves $9 propagating in any direction through the structure and with an arbitrary state of polarization. This behavior is of interest both from a fundamental viewpoint and from the point of view of novel applications in photonic devices. The $9 paper gives an outline review of work on photonic crystals carried out by the Optoelectronics Researc...

  7. One-step spray processing of high power all-solid-state supercapacitors

    Science.gov (United States)

    Huang, Chun; Grant, Patrick S.

    2013-08-01

    Aqueous suspensions of multi-wall carbon nanotubes (MWNTs) in dilute H2SO4 were sprayed onto both sides of a Nafion membrane and dried to fabricate flexible solid-state supercapacitors. A single cell with MWNT-only electrodes had a capacitance of 57 F g-1 per electrode at 2 mV s-1 and 44 F g-1 at 150 mV s-1 but with low H+ mobility. Cells with MWNT + ionomer hybrid electrodes showed higher H+ mobility, and the electric double layer (EDL) capacitance increased to 145 F g-1 at 2 mV s-1 and 91 F g-1 at 150 mV s-1. The energy and power densities of one electrode charged to 1 V at 1 A g-1 were 12.9 Wh kg-1 and 3.3 kW kg-1 respectively. Three solid-state supercapacitor cells connected in series charged to 3 V at 1 and 2 A g-1 provided a device power density of 8.9 kW kg-1 at 1 A g-1 and 9.4 kW kg-1 at 2 A g-1, the highest for all-solid-state EDL supercapacitors.

  8. Fabrication and Performance of All-Solid-State Chloride Sensors in Synthetic Concrete Pore Solutions

    Directory of Open Access Journals (Sweden)

    Hongwei Deng

    2010-11-01

    Full Text Available One type of all-solid-state chloride sensor was fabricated using a MnO2 electrode and a Ag/AgCl electrode. The potentiometric response of the sensor to chloride in synthetic concrete pore solutions was systematically studied, and the polarization performance was also evaluated. The results show a good linear relationship between the potential reading of the sensor and the logarithm of chloride activity (concentration ranges from 0.05 to 5.0 M, and the potential value remains stable with increasing immersion time. The existence of K+, Ca2+, Na+ and SO42− ions have little influence on the potentiometric response of the sensor to chloride, but the pH has a significant influence on the potential value of the sensor at low chloride concentration. The potential reading of the sensor increases linearly with the solution temperature over the range from 5 to 45 °C. Meanwhile, an excellent polarization behavior is proven by galvanostatic and potentiodynamic tests. All of the results reveal that the developed sensor has a great potential for monitoring chloride ions in concrete environments.

  9. Research progress in all-solid-state high power green laser

    International Nuclear Information System (INIS)

    The paper reports the research progress in all-solid-state high power green laser. The intracavity frequency-doubled green laser adopts the two-rod L-shaped cavity. When the pumping power is 1 174 W, the 532 nm output power is 186 W and the optical-optical efficiency is 15.8% with LBO frequency-doubling crystal. A diode pumped master oscillator power amplifier laser with output pulse energy of 1.2 J at 400 Hz repetition rate is demonstrated. With a type II phase matched KTP crystal, 525 mJ green light pulse energy at 400 Hz repetition rate is obtained. The frequency conversion efficiency is about 43.7%. The laser energy of the double beam laser is more than 1 J with the technique of polarization synthesis. Moreover, a 90 degree quartz rotator is placed between the two laser modules to fulfill thermal-induced birefringence compensation of laser media, and a specially designed large aperture tapered fiber as a solid state phase conjugation mirror is used in the power amplifier to improve beam quality. (authors)

  10. Fabrication and performance of all-solid-state chloride sensors in synthetic concrete pore solutions.

    Science.gov (United States)

    Gao, Xiaojian; Zhang, Jian; Yang, Yingzi; Deng, Hongwei

    2010-01-01

    One type of all-solid-state chloride sensor was fabricated using a MnO(2) electrode and a Ag/AgCl electrode. The potentiometric response of the sensor to chloride in synthetic concrete pore solutions was systematically studied, and the polarization performance was also evaluated. The results show a good linear relationship between the potential reading of the sensor and the logarithm of chloride activity (concentration ranges from 0.05 to 5.0 M), and the potential value remains stable with increasing immersion time. The existence of K(+), Ca(2+), Na(+) and SO(4) (2-) ions have little influence on the potentiometric response of the sensor to chloride, but the pH has a significant influence on the potential value of the sensor at low chloride concentration. The potential reading of the sensor increases linearly with the solution temperature over the range from 5 to 45 °C. Meanwhile, an excellent polarization behavior is proven by galvanostatic and potentiodynamic tests. All of the results reveal that the developed sensor has a great potential for monitoring chloride ions in concrete environments. PMID:22163467

  11. All-Solid-State Electrochromic Variable Emittance Coatings for Thermal Management in Space

    Science.gov (United States)

    Kislov, Nikolai; Groger, Howard; Ponnappan, Rengasamy

    2003-01-01

    The results presented in this article demonstrate the feasibility of ``all-solid-state'' inorganic electrochromic (EC) variable emittance coatings (VEC) for thermal management in space. VECs were built on glass substrates, flexible polyimide (Kapton™) films, and on high resistance silicon wafers. The best VECs were found to modulate mid-infrared emittance from 0.15 to 0.46 on a Kapton film and from 0.24 to 0.48 on a silicon wafer that performs the dual role as both infrared window and substrate. The results of thermal estimations for a two-dimensional plate showed that EC systems with emittance modulation ratio ɛhigh/Vegr low = 3 can be practically used to advantage in providing enhanced thermal control for lightweight structures in space. In addition, EC variable solar reflectance coatings (VSRCs) were built on polyethylene terephthalate (PET) film. The average reflection of the VSRC in a visual spectral range was 63% in the bleached condition and 20% in the colored condition. Thermal analysis shows that a combination of VECs and VSRCs described in this work provides an enhanced range of thermal control for satellites and small space vehicles in the space environment.

  12. Flexible all-solid-state MnO2 thin films based symmetric supercapacitors

    International Nuclear Information System (INIS)

    Flexible energy storage devices gained lot of substantial research interest in the recent decade as their special features and potential applications in different portable electronic devices such as smart sensors, actuators, mobiles, flexible touch screens and electronic newspapers, etc. Therefore, to develop such devices, the flexible electrode and electrolytes with desired mechanical and electrochemical properties are required. In present article, porous nanostructured MnO2 thin films are prepared directly on flexible stainless steel substrate through chemical bath deposition (CBD) method. Further, flexible all-solid-state thin film symmetric supercapacitors (FASSTF-SSCs) have been fabricated using identical MnO2 electrodes with carboxymethyl cellulose- Na2SO4 (CMC-Na2SO4) gel electrolyte. Our results, demonstrate that 0.7 μm thick FASSTF cell exhibits specific capacitance of 145 F g−1 with specific energy of 16 Wh kg−1 and excellent cycling stability after 2500 cycles. In addition, we have presented demonstration of lighting of two light emitting diodes (LEDs) for 135 s which finally confirms the potential applicability of MnO2 based solid-state symmetric cells for high-performance flexible energy storage devices

  13. All solid state lithium batteries based on lamellar garnet-type ceramic electrolytes

    Science.gov (United States)

    Du, Fuming; Zhao, Ning; Li, Yiqiu; Chen, Cheng; Liu, Ziwei; Guo, Xiangxin

    2015-12-01

    All solid-state lithium batteries are constructed by using highly conducting Ta-doped Li7La3Zr2O12 (LLZTO) as the solid electrolytes as well as the supports, coated with composite cathodes consisting of poly(vinylidene fluoride) (PVdF):LiTFSI, Ketjen Black, and carbon-coated LiFePO4 on one side and attached with Li anode on the other side. At 60 °C, the batteries show the first discharge capacity of 150 mAh g-1 at 0.05 C and 93% capacity retention after 100 cycles. As the current density increases from 0.05 C to 1 C, the specific capacity decreases from 150 mAh g-1 to 100 mAh g-1. Further elevated temperature up to 100 °C leads to further improved performance, i.e. 126 mAh g-1 at 1 C and 99% capacity retention after 100 cycles. This good performance can be attributed to the highly conducting ceramic electrolytes, the optimum electronic and ionic conducting networks in the composite cathodes, and closely contacted cathode/LLZTO interface. These results indicate that the present strategy is promising for development of high-performance solid-state Li-ion batteries operated at medium temperature.

  14. Highly flexible, all solid-state micro-supercapacitors from vertically aligned carbon nanotubes

    International Nuclear Information System (INIS)

    We report a highly flexible planar micro-supercapacitor with interdigitated finger electrodes of vertically aligned carbon nanotubes (VACNTs). The planar electrode structures are patterned on a thin polycarbonate substrate with a facile, maskless laser-assisted dry transfer method. Sputtered Ni is used to reduce the in-plane resistance of the VACNT electrodes. An ionogel, an ionic liquid in a semi-solid matrix, is used as an electrolyte to form a fully solid-state device. We measure a specific capacitance of 430 μF cm−2 for a scan rate of 0.1 V s−1 and achieve rectangular cyclic voltammograms at high scan rates of up to 100 V s−1. Minimal change in capacitance is observed under bending. Mechanical fatigue tests with more than 1000 cycles confirm the high flexibility and durability of the novel material combination chosen for this device. Our results indicate that this scalable and facile fabrication technique shows promise for application in integrated energy storage for all solid-state flexible microdevices. (paper)

  15. Solid polymer electrolytes: materials designing and all-solid-state battery applications: an overview

    International Nuclear Information System (INIS)

    Polymer electrolytes are promising materials for electrochemical device applications, namely, high energy density rechargeable batteries, fuel cells, supercapacitors, electrochromic displays, etc. The area of polymer electrolytes has gone through various developmental stages, i.e. from dry solid polymer electrolyte (SPE) systems to plasticized, gels, rubbery to micro/nano-composite polymer electrolytes. The polymer gel electrolytes, incorporating organic solvents, exhibit room temperature conductivity as high as ∼10-3 S cm-1, while dry SPEs still suffer from poor ionic conductivity lower than 10-5 S cm-1. Several approaches have been adopted to enhance the room temperature conductivity in the vicinity of 10-4 S cm-1 as well as to improve the mechanical stability and interfacial activity of SPEs. In this review, the criteria of an ideal polymer electrolyte for electrochemical device applications have been discussed in brief along with presenting an overall glimpse of the progress made in polymer electrolyte materials designing, their broad classification and the recent advancements made in this branch of materials science. The characteristic advantages of employing polymer electrolyte membranes in all-solid-state battery applications have also been discussed. (topical review)

  16. Diffusion and Interface Effects during Preparation of All-Solid Microstructured Fibers

    Directory of Open Access Journals (Sweden)

    Kobelke Jens

    2014-09-01

    Full Text Available All-solid microstructured optical fibers (MOF allow the realization of very flexible optical waveguide designs. They are prepared by stacking of doped silica rods or canes in complex arrangements. Typical dopants in silica matrices are germanium and phosphorus to increase the refractive index (RI, or boron and fluorine to decrease the RI. However, the direct interface contact of stacking elements often causes interrelated chemical reactions or evaporation during thermal processing. The obtained fiber structures after the final drawing step thus tend to deviate from the targeted structure risking degrading their favored optical functionality. Dopant profiles and design parameters (e.g., the RI homogeneity of the cladding are controlled by the combination of diffusion and equilibrium conditions of evaporation reactions. We show simulation results of diffusion and thermal dissociation in germanium and fluorine doped silica rod arrangements according to the monitored geometrical disturbances in stretched canes or drawn fibers. The paper indicates geometrical limits of dopant structures in sub-µm-level depending on the dopant concentration and the thermal conditions during the drawing process. The presented results thus enable an optimized planning of the preform parameters avoiding unwanted alterations in dopant concentration profiles or in design parameters encountered during the drawing process.

  17. Superior Electrical Conductivity in Hydrogenated Layered Ternary Chalcogenide Nanosheets for Flexible All-Solid-State Supercapacitors.

    Science.gov (United States)

    Hu, Xin; Shao, Wei; Hang, Xudong; Zhang, Xiaodong; Zhu, Wenguang; Xie, Yi

    2016-05-01

    As the properties of ultrathin two-dimensional (2D) crystals are strongly related to their electronic structures, more and more attempts were carried out to tune their electronic structures to meet the high standards for the construction of next-generation smart electronics. Herein, for the first time, we show that the conductive nature of layered ternary chalcogenide with formula of Cu2 WS4 can be switched from semiconducting to metallic by hydrogen incorporation, accompanied by a high increase in electrical conductivity. In detail, the room-temperature electrical conductivity of hydrogenated-Cu2 WS4 nanosheet film was almost 10(10) times higher than that of pristine bulk sample with a value of about 2.9×10(4)  S m(-1) , which is among the best values for conductive 2D nanosheets. In addition, the metallicity in the hydrogenated-Cu2 WS4 is robust and can be retained under high-temperature treatment. The fabricated all-solid-state flexible supercapacitor based on the hydrogenated-Cu2 WS4 nanosheet film shows promising electrochemical performances with capacitance of 583.3 F cm(-3) at a current density of 0.31 A cm(-3) . This work not only offers a prototype material for the study of electronic structure regulation in 2D crystals, but also paves the way in searching for highly conductive electrodes. PMID:27060363

  18. Properties of All-Solid Lithium-Ion Rechargeable Batteries Deposited by RF Magnetron Sputtering

    Science.gov (United States)

    Zhu, R. J.; Ren, Y.; Geng, L. Q.; Chen, T.; Li, L. X.; Yuan, C. R.

    2013-08-01

    Amorphous V2O5, LiPON and Li2Mn2O4 thin films were fabricated by RF magnetron sputtering methods and the morphology of thin films were characterized by scanning electron microscopy. Then with these three materials deposited as the anode, solid electrolyte, cathode, and vanadium as current collector, a rocking-chair type of all-solid-state thin-film-type Lithium-ion rechargeable battery was prepared by using the same sputtering parameters on stainless steel substrates. Electrochemical studies show that the thin film battery has a good charge-discharge characteristic in the voltage range of 0.3-3.5 V, and after 30 cycles the cell performance turned to become stabilized with the charge capacity of 9 μAh/cm2, and capacity loss of single-cycle of about 0.2%. At the same time, due to electronic conductivity of the electrolyte film, self-discharge may exist, resulting in approximately 96.6% Coulombic efficiency.

  19. Developments of high-voltage all-solid-state thin-film lithium ion batteries

    Science.gov (United States)

    Schwenzel, J.; Thangadurai, V.; Weppner, W.

    Powders of Li 2MMn 3O 8 (M = Fe, Co) were prepared by glycine nitrate combustion from the corresponding metal nitrates. The reaction products were pressed into pellets with the addition of 20 wt.% excess LiNO 3, which were used as targets for e-beam evaporation. A high-voltage all-solid-state thin-film lithium ion battery was demonstrated by the sequential deposition of spinel structured Li 2MMn 3O 8 (M = Co, Fe) as positive electrode by e-beam evaporation, LiPON as electrolyte, and metallic Al as negative electrode by sputtering in N 2 and Ar gas mixtures with specific power and gas flow rates. A lithium ion conductivity of ˜10 -6 S cm -1 was observed for the optimized thin-film LiPON electrolyte prepared under the condition of a chamber pressure of 2.6 × 10 -2 mbar and a power of 60-100 W. The chemical diffusion coefficient (D˜) was found to be in the range 10 -13 to 10 -12 cm 2 s -1 for any composition x of Li 2- xMMn 3O 8 (M = Fe, Co) in the range from 0.1 to 1.6 by employing the galvanostatic intermittent titration technique (GITT). AC impedance studies revealed a charge transfer resistance of 260-290 Ω, a double layer capacity of ˜45-70 μF for an electrode area of 6.7 cm 2.

  20. All solid supercapacitor based on polyaniline and crosslinked sulfonated poly[ether ether ketone

    International Nuclear Information System (INIS)

    All solid supercapacitor based on polyaniline (PANI) and crosslinked sulfonated poly[ether ether ketone] (XSPEEK,) is reported in this paper. The crosslinker used for sulfonated poly[ether ether ketone] (SPEEK) is 1,4-bis(hydroxymethyl) benzene. The XSPEEK is used as both solid electrolyte and separator membrane. Supercapacitors are fabricated using various PANI/XSPEEK weight ratios. These are characterized by cyclic voltammetry and galvanostatic charge-discharge studies. The supercapacitor with PANI/XSPEEK weight ratio 1:0.5, exhibit a specific capacitance of 480 F g-1 of PANI. To the best of authors' knowledge, the value reported here is the highest for a supercapacitor based on a proton conducting solid polymer electrolyte and PANI. Detailed electrochemical impedance spectroscopy analysis is carried out. The analysis shows that the complex capacitance of the supercapacitor depends on the XSPEEK content. The time constant (t0), derived from the imaginary part of complex capacitance decreases with increase in the XSPEEK content in the supercapacitor. Cycle life characteristics of the supercapacitor show a decrease in specific capacitance during initial cycles and get stabilized during later cycles.

  1. All-solid-state nitrate-selective electrode and its application in drinking water

    International Nuclear Information System (INIS)

    An all-solid-state nitrate-selective electrode with the implementation of graphene as the ion-to-electron transducer was reported. The charge-transfer process was examined by electrochemical impedance spectroscope and the hydrophobic nature of the graphene film was characterized via the potentiometric water layer test. The analytical performance of the nitrate-selective electrode was investigated by the determination of nitrate in drinking water. The obtained results showed that graphene can significantly facilitate the ion-to-electron transducer and prevent the formation of water layer between the ion-selective membrane and the graphene layer. The fabricated nitrate-selective electrode displayed a Nernstian slope of 57.9 mV per decade of nitrate concentration, a low detection limit of 3 × 10−5 M and a rapid response time (within 10 s) for concentration upon 10−4 M. The determination of real samples indicated that the constructed nitrate-selective electrode was capable of monitoring nitrate in drinking water, providing a handy alternative for routine analysis.

  2. Photonics: practically there?

    Directory of Open Access Journals (Sweden)

    Paula Gould

    2002-09-01

    Strange things happen to light when it passes through photonic crystals. A significant variation in refractive index between the material’s periodic lattice structure and its substrate traps transmitted photons in either one area or the other, creating distinct ‘allowed’ and ‘forbidden’ energy regions. Light with wavelengths equivalent to the forbidden region, the so-called photonic bandgap, is stopped from passing further. Wavelengths from the rest of the electromagnetic spectrum, on the other hand, are free to continue their passage through the material unhindered. In effect, the material is able to halt the passage of light just as the periodic potential of semiconductors, such as silicon, bars electrons from occupying the forbidden energy bandgap.

  3. A miniature all-solid-state calcium electrode applied to in situ seawater measurement

    Science.gov (United States)

    Xu, Hui; Wang, You; Luo, Zhiyuan; Pan, Yiwen

    2013-12-01

    An all-solid-state miniature calcium ion selective electrode (ISE) based on poly(3,4-ethylenedioxythiophene) doped with poly(styrene sulfonate) (PEDOT(PSS)) for continuous in situ measurement in seawater was studied. The electrode substrate was a platinum (Pt) wire of 0.5 mm diameter and PEDOT(PSS) was electropolymerized on one end of the Pt wire to act as the solid contact of this calcium ISE. The PEDOT(PSS) layer was covered with a calcium-selective poly(vinyl chloride) membrane, which contained ETH129 as calcium ionophore, potassium tetrakis-(p-chlorophenyl)borate as lipophilic anion and bis(2-ethylhexyl) sebacate as the plasticizer. Experiments using electrochemical impedance spectroscopy and reversed chronopotentiometry illustrated that electropolymerized PEDOT(PSS) decreased the resistance and improved the stability of the electrode. The sensors can work stably in the calcium ion concentration range of 10-6-10-1 mol L-1 with the slope of 27.7 mV/decade. Also Na+, K+ and Mg2+ can hardly interfere with the performance of the electrode. This electrode was applied to measure the calcium ion concentration of seawater samples. The experimental data showed that the electrode can resist the corrosion of seawater and its reproducibility was good (SD < 0.1 mM kg-1). The lifetime of such an electrode was at least six months. Because of the wire-shape and the small size of such a liquid junction free calcium electrode, it is pressure-resistant and easy to package and seal, therefore it is suitable for use in underwater equipment for in situ seawater measurement.

  4. A miniature all-solid-state calcium electrode applied to in situ seawater measurement

    International Nuclear Information System (INIS)

    An all-solid-state miniature calcium ion selective electrode (ISE) based on poly(3,4-ethylenedioxythiophene) doped with poly(styrene sulfonate) (PEDOT(PSS)) for continuous in situ measurement in seawater was studied. The electrode substrate was a platinum (Pt) wire of 0.5 mm diameter and PEDOT(PSS) was electropolymerized on one end of the Pt wire to act as the solid contact of this calcium ISE. The PEDOT(PSS) layer was covered with a calcium-selective poly(vinyl chloride) membrane, which contained ETH129 as calcium ionophore, potassium tetrakis-(p-chlorophenyl)borate as lipophilic anion and bis(2-ethylhexyl) sebacate as the plasticizer. Experiments using electrochemical impedance spectroscopy and reversed chronopotentiometry illustrated that electropolymerized PEDOT(PSS) decreased the resistance and improved the stability of the electrode. The sensors can work stably in the calcium ion concentration range of 10−6–10−1 mol L−1 with the slope of 27.7 mV/decade. Also Na+, K+ and Mg2+ can hardly interfere with the performance of the electrode. This electrode was applied to measure the calcium ion concentration of seawater samples. The experimental data showed that the electrode can resist the corrosion of seawater and its reproducibility was good (SD < 0.1 mM kg−1). The lifetime of such an electrode was at least six months. Because of the wire-shape and the small size of such a liquid junction free calcium electrode, it is pressure-resistant and easy to package and seal, therefore it is suitable for use in underwater equipment for in situ seawater measurement. (paper)

  5. All solid-state tunable KTP optical parametric oscillator amplifier system

    International Nuclear Information System (INIS)

    We present the performance characteristics of a low energy all-solid-state nea- infrared optical parametric oscillator amplifier (OPOA). The pump source is a laser diode (LD) pumped frequency-doubled Nd: YAG laser with a single mode energy of 4 mJ in 8ns, 50 Hz pulse. The OPOA system, based on potassium titanyl photophate (KTP) crystal, features a low pump energy threshold at 532 nm of less than 0.4 mJ, broad tunability from 750 to 1040 nm for the signal and a conversion efficiency of 27% at 920 nm. The bandwidth at 960 nm was reduced from the free running mode (>100 GHz) to less than 150 MHz by the simultaneous injection seeding of the pump laser and the OPOA, which is close to the Fourier transform limit of the 4ns output pulses. The OPOA has a potential tunability of over 60 nm from 915-975 nm determined by its external cavity grating tuned diode seed laser. External cavity second harmonic conversion of the idler to visible green-red light in a type II KTP crystal and of the signal to visible blue-green light in a type I BBO crystal was performed with efficiencies up to 10%. We have used the near-infrared output for wavelength-dependent fluorescence lifetime studies in ytterbium-doped laser materials. We have also used the second harmonic wavelengths between 565-600 nm to measure the transmission of Nd: YAG in a preliminary experiment to demonstrate the utility of the system. As a pump source, a novel laser-diode pumped eight pass Nd: YAG zig-zag slab amplifier was developed aiming to achieve high energy extraction efficiency. High energy extraction efficiency of upto 73% for the laser mode volume has been achieved in this amplifier operating at an initial small signal gain of 3.36. The compensation of the thermal birefringence in this amplifier was successfully performed.

  6. Developments of high-voltage all-solid-state thin-film lithium ion batteries

    Energy Technology Data Exchange (ETDEWEB)

    Schwenzel, J.; Thangadurai, V.; Weppner, W. [Chair for Sensors and Solid State Ionics, Faculty of Engineering, University of Kiel, Kaiserstrasse 2, D-24143 Kiel (Germany)

    2006-03-09

    Powders of Li{sub 2}MMn{sub 3}O{sub 8} (M=Fe, Co) were prepared by glycine nitrate combustion from the corresponding metal nitrates. The reaction products were pressed into pellets with the addition of 20wt.% excess LiNO{sub 3}, which were used as targets for e-beam evaporation. A high-voltage all-solid-state thin-film lithium ion battery was demonstrated by the sequential deposition of spinel structured Li{sub 2}MMn{sub 3}O{sub 8} (M=Co, Fe) as positive electrode by e-beam evaporation, LiPON as electrolyte, and metallic Al as negative electrode by sputtering in N{sub 2} and Ar gas mixtures with specific power and gas flow rates. A lithium ion conductivity of {approx}10{sup -6} S cm{sup -1} was observed for the optimized thin-film LiPON electrolyte prepared under the condition of a chamber pressure of 2.6x10{sup -2} mbar and a power of 60-100W. The chemical diffusion coefficient (D-bar) was found to be in the range 10{sup -13} to 10{sup -12} cm{sup 2}s{sup -1} for any composition x of Li{sub 2-x} MMn{sub 3}O{sub 8} (M=Fe, Co) in the range from 0.1 to 1.6 by employing the galvanostatic intermittent titration technique (GITT). AC impedance studies revealed a charge transfer resistance of 260-290{omega}, a double layer capacity of {approx}45-70{mu}F for an electrode area of 6.7cm{sup 2}. (author)

  7. Modelling of photonic crystal fibres

    DEFF Research Database (Denmark)

    Knudsen, Erik

    2003-01-01

    In the presenta ph.d. work a theoretical study of aspects of modelling photonic crystal fibres was carried out. Photonic crystal fibres form a class of optical waveguides where guidance is no longer provided by a difference in refractive index between core and cladding. Instead, guidance is...... provided by an arrangement of air-holes running along the length of the fibre. Depending on the geometry of the fibre, the guiding mechanism may be either arising from the formation of a photonic bandgap in the cladding structure (photonic bandgap fibre), or by an effect resembling total internal...... modes in contiguous fibre segments curved at different radii. Overall microbend loss is expressed as a statistical mean of mismatch losses. Extending a well proven, established formula for macrobending losses in stop index fibres, we provide an estimate of macrobend losses in an air-guiding photonic...

  8. Monolayer MoS2 Bandgap Modulation by Dielectric Environments and Tunable Bandgap Transistors

    Science.gov (United States)

    Ryou, Junga; Kim, Yong-Sung; KC, Santosh; Cho, Kyeongjae

    2016-01-01

    Semiconductors with a moderate bandgap have enabled modern electronic device technology, and the current scaling trends down to nanometer scale have introduced two-dimensional (2D) semiconductors. The bandgap of a semiconductor has been an intrinsic property independent of the environments and determined fundamental semiconductor device characteristics. In contrast to bulk semiconductors, we demonstrate that an atomically thin two-dimensional semiconductor has a bandgap with strong dependence on dielectric environments. Specifically, monolayer MoS2 bandgap is shown to change from 2.8 eV to 1.9 eV by dielectric environment. Utilizing the bandgap modulation property, a tunable bandgap transistor, which can be in general made of a two-dimensional semiconductor, is proposed. PMID:27378032

  9. Monolayer MoS2 Bandgap Modulation by Dielectric Environments and Tunable Bandgap Transistors.

    Science.gov (United States)

    Ryou, Junga; Kim, Yong-Sung; Kc, Santosh; Cho, Kyeongjae

    2016-01-01

    Semiconductors with a moderate bandgap have enabled modern electronic device technology, and the current scaling trends down to nanometer scale have introduced two-dimensional (2D) semiconductors. The bandgap of a semiconductor has been an intrinsic property independent of the environments and determined fundamental semiconductor device characteristics. In contrast to bulk semiconductors, we demonstrate that an atomically thin two-dimensional semiconductor has a bandgap with strong dependence on dielectric environments. Specifically, monolayer MoS2 bandgap is shown to change from 2.8 eV to 1.9 eV by dielectric environment. Utilizing the bandgap modulation property, a tunable bandgap transistor, which can be in general made of a two-dimensional semiconductor, is proposed. PMID:27378032

  10. Development of an all-solid-state exciter for a high average-power TEA CO2 laser

    International Nuclear Information System (INIS)

    An all-solid-state exciter with a three-stage magnetic pulse compressor has been designed and constructed for a high repetition-rate transversely excited atmospheric CO2 laser. An average laser power of 1.5 kW was obtained at a repetition rate of 200 pps, with an overall efficiency of 7.3%. This is the first time that the average CO2 laser power of more than 1 kW has been demonstrated by an all-solid-state exciter. (author)

  11. Colloidal Bandpass and Bandgap Filters

    Science.gov (United States)

    Yellen, Benjamin; Tahir, Mukarram; Ouyang, Yuyu; Nori, Franco

    2013-03-01

    Thermally or deterministically-driven transport of objects through asymmetric potential energy landscapes (ratchet-based motion) is of considerable interest as models for biological transport and as methods for controlling the flow of information, material, and energy. Here, we provide a general framework for implementing a colloidal bandpass filter, in which particles of a specific size range can be selectively transported through a periodic lattice, whereas larger or smaller particles are dynamically trapped in closed-orbits. Our approach is based on quasi-static (adiabatic) transition in a tunable potential energy landscape composed of a multi-frequency magnetic field input signal with the static field of a spatially-periodic magnetization. By tuning the phase shifts between the input signal and the relative forcing coefficients, large-sized particles may experience no local energy barriers, medium-sized particles experience only one local energy barrier, and small-sized particles experience two local energy barriers. The odd symmetry present in this system can be used to nudge the medium-sized particles along an open pathway, whereas the large or small beads remain trapped in a closed-orbit, leading to a bandpass filter, and vice versa for a bandgap filter. NSF CMMI - 0800173, Youth 100 Scholars Fund

  12. Wide Bandgap Nanostructured Space Photovoltaics Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Firefly, in collaboration with Rochester Institute of Technology, proposes an STTR program for the development of a wide-bandgap GaP-based space solar cell capable...

  13. Distributed optical fibre devices based on liquid crystal infiltrated photonic crystal fibers

    OpenAIRE

    Alkeskjold, Thomas Tanggaard; Broeng, Jes; Hermann, D.S.; Bjarklev, Anders Overgaard

    2004-01-01

    We describe a new class of hybrid photonic crystal fibers, which are liquid crystal infiltrated fibers. Using these fibers, we demonstrate 'distributed' tunable filter and switching functionalities operating by the photonic bandgap effect.

  14. Tuning the Bandgap of a Ternary Semiconductor

    OpenAIRE

    2005-01-01

    This interactive tutorial covers the following: The relationship between bandgap energy and the long wavelength cut-off of a detector response., The changes expected in long wavelength cut-off in response to changes in alloy composition and operating temperature.The interactions in this tutorial involve students using sliding scales to change the values of alloy composition, bandgap energy, cut-off wavelength, temperature, and intrinsic carrier concentration, and make observations of correspo...

  15. Engineering photonic density of states using metamaterials

    DEFF Research Database (Denmark)

    Jacob, Z.; Kim, J.Y.; Naik, G.V.;

    2010-01-01

    The photonic density of states (PDOS), like its electronic counterpart, is one of the key physical quantities governing a variety of phenomena and hence PDOS manipulation is the route to new photonic devices. The PDOS is conventionally altered by exploiting the resonance within a device such as a...... microcavity or a bandgap structure like a photonic crystal. Here we show that nanostructured metamaterials with hyperbolic dispersion can dramatically enhance the photonic density of states paving the way for metamaterial-based PDOS engineering....

  16. Modulated electron-multiplied fluorescence lifetime imaging microscope: all-solid-state camera for fluorescence lifetime imaging

    NARCIS (Netherlands)

    Zhao, Q.; Schelen, B.; Schouten, R., et al.

    2012-01-01

    We have built an all-solid-state camera that is directly modulated at the pixel level for frequency-domain fluorescence lifetime imaging microscopy (FLIM) measurements. This novel camera eliminates the need for an image intensifier through the use of an application-specific charge coupled device des

  17. Enhancement of Cycling Performance by Li2O-Sn Anode for All-Solid-State Batteries

    Science.gov (United States)

    Jee, Seung Hyun; Lee, Seok Hee; Kim, Dong-Joo; Kwak, Ji-Yeon; Nam, Sang-Cheol; Yoon, Young Soo

    2012-08-01

    A solid-state half-cell structure with a Sn-Li2O composite (SLC) anode/LiPON/Li was prepared to improve upon the cycling stability at the second discharging cycle of the non-Li anode thin films for all-solid-state batteries. Based on the cycling behaviors of the all-solid half cell with SLC and pure Sn thin film electrodes at first and second discharging cycles, cycling stability at the initial charging-discharging cycle of the all-solid-state battery system was improved. The high retention value of SLC thin film electrodes with LiPON solid electrolyte might originate from (1) the structural stability of the SLC thin film, and (2) suppression of crack formation at the SLC surface owing to an increasing surface mechanical strength of the SLC thin film by the LiPON deposition on it. These results indicate that the SLC thin film has a high possibility as the stable solid anode material for use as an all-solid-state battery.

  18. Nonlinear spatial mode imaging of hybrid photonic crystal fibers

    DEFF Research Database (Denmark)

    Petersen, Sidsel Rübner; Alkeskjold, Thomas Tanggaard; Laurila, Marko; Andersen, T. V.; Lægsgaard, Jesper

    2013-01-01

    Degenerate spontaneous four wave mixing is studied for the rst time in a large mode area hybrid photonic crystal ber, where light con nement is achieved by combined index- and bandgap guiding. Four wave mixing products are generated on the edges of the bandgaps, which is veri ed by numerical and...

  19. Magneto-tunable one-dimensional graphene-based photonic crystal

    Energy Technology Data Exchange (ETDEWEB)

    Jahani, D., E-mail: dariush110@gmail.com; Soltani-Vala, A., E-mail: asoltani@tabrizu.ac.ir; Barvestani, J.; Hajian, H. [Department of Solid State Physics, Faculty of Physics, University of Tabriz, Tabriz (Iran, Islamic Republic of)

    2014-04-21

    We investigate the effect of a perpendicular static magnetic field on the optical bandgap of a one-dimensional (1D) graphene-dielectric photonic crystal in order to examine the possibility of reaching a rich tunable photonic bandgap. The solution of the wave equation in the presence of the anisotropic Hall situation suggests two decoupled circularly polarized wave each exhibiting different degrees of bandgap tunability. It is also numerically demonstrated that applying different values of field intensity lead to perceptible changes in photonic bandgap of such a structure. Finally, the effect of opening a finite electronic gap in the spectrum of graphene on the optical dispersion solution of such a 1D photonic crystal is reported. It is shown that increasing the value of the electronic gap results in the shrinkage of the associated photonic bandgaps.

  20. Photonic mesophases from cut rod rotators

    Energy Technology Data Exchange (ETDEWEB)

    Stelson, Angela C.; Liddell Watson, Chekesha M., E-mail: cml66@cornell.edu [Materials Science and Engineering, Cornell University, Ithaca, New York 14853 (United States); Avendano, Carlos [Chemical Engineering and Analytical Science, The University of Manchester, Manchester M13 9PL (United Kingdom)

    2016-01-14

    The photonic band properties of random rotator mesophases are calculated using supercell methods applied to cut rods on a hexagonal lattice. Inspired by the thermodynamic mesophase for anisotropic building blocks, we vary the shape factor of cut fraction for the randomly oriented basis. We find large, stable bandgaps with high gap isotropy in the inverted and direct structures as a function of cut fraction, dielectric contrast, and filling fraction. Bandgap sizes up to 34.5% are maximized at high dielectric contrast for rods separated in a matrix. The bandgaps open at dielectric contrasts as low as 2.0 for the transverse magnetic polarization and 2.25 for the transverse electric polarization. Additionally, the type of scattering that promotes the bandgap is correlated with the effect of disorder on bandgap size. Slow light properties are investigated in waveguide geometry and slowdown factors up to 5 × 10{sup 4} are found.

  1. Petahertz optical drive with wide-bandgap semiconductor

    Science.gov (United States)

    Mashiko, Hiroki; Oguri, Katsuya; Yamaguchi, Tomohiko; Suda, Akira; Gotoh, Hideki

    2016-08-01

    High-speed photonic and electronic devices at present rely on radiofrequency electric fields to control the physical properties of a semiconductor, which limits their operating speed to terahertz frequencies (1012 Hz ref. ). Using the electric field from intense light pulses, however, could extend the operating frequency into the petahertz regime (1015 Hz ref. ). Here we demonstrate optical driving at a petahertz frequency in the wide-bandgap semiconductor gallium nitride. Few-cycle near-infrared pulses are shown to induce electric interband polarization though a multiphoton process. Dipole oscillations with a periodicity of 860 as are revealed in the gallium nitride electron and hole system by using the quantum interference between the two transitions from the valence and conduction band states, which are probed by an extremely short isolated attosecond pulse with a coherent broadband spectrum. In principle, this shows that the conductivity of the semiconductor can be manipulated on attosecond timescales, which corresponds to instantaneous light-induced switching from insulator to conductor. The resultant dipole frequency reaches 1.16 PHz, showing the potential for future high-speed signal processing technologies based on wide-bandgap semiconductors.

  2. Photonic bandgap structures for long-range surface plasmon polaritons

    DEFF Research Database (Denmark)

    Bozhevolnyi, Sergey I.; Boltasseva, Alexandra; Søndergaard, Thomas;

    2005-01-01

    Propagation of long-range surface plasmon polaritons (LR-SPPs) along periodically thickness-modulated metal stripes embedded in dielectric is studied both theoretically and experimentally for light wavelengths in the telecom range. We demonstrate that symmetric (with respect to the film surface) ...

  3. Optical devices based on liquid crystal photonic bandgap fibers

    DEFF Research Database (Denmark)

    Alkeskjold, Thomas Tanggaard

    2005-01-01

    features directly caused by LC anisotropy has been identified. The main sources of loss is discussed and investigated through simulations and experimental verification. The thesis begins with an introduction to LCs and PCFs, with emphasis on the basic properties, which are useful for describing the...

  4. Tunable photonic bandgap fiber based devices for optical networks

    DEFF Research Database (Denmark)

    Alkeskjold, Thomas Tanggaard; Scolari, Lara; Rottwitt, Karsten;

    2005-01-01

    In future all optical networks one of the enabling technologies is tunable elements including reconfigurable routers, switches etc. Thus, the development of a technology platform that allows construction of tuning components is critical. Lately, microstructured optical fibers, filled with liquid...... crystals, have proven to be a candidate for such a platform. Microstructured optical fibers offer unique wave-guiding properties that are strongly related to the design of the air holes in the cladding of the fiber. These wave-guiding properties may be altered by filling the air holes with a material, for...... example a liquid crystal that changes optical properties when subjected to, for example, an optical or an electrical field. The utilization of these two basic properties allows design of tunable optical devices for optical networks. In this work, we focus on applications of such devices and discuss recent...

  5. Hollow core photonic bandgap fibers for medical applications

    OpenAIRE

    Vural, Mert

    2009-01-01

    Ankara : The Department of Materials Science and Nanotechnology and the Institute of Engineering and Sciences of Bilkent University, 2009. Thesis (Master's) -- Bilkent University, 2009. Includes bibliographical references leaves 87-95. Vural, Mert Master's

  6. Graphene Photonics and Optoelectronics

    OpenAIRE

    Bonaccorso, F.; Sun, Z.; Hasan, T.; Ferrari, A. C.

    2010-01-01

    The richness of optical and electronic properties of graphene attracts enormous interest. Graphene has high mobility and optical transparency, in addition to flexibility, robustness and environmental stability. So far, the main focus has been on fundamental physics and electronic devices. However, we believe its true potential to be in photonics and optoelectronics, where the combination of its unique optical and electronic properties can be fully exploited, even in the absence of a bandgap, ...

  7. Anisotropic nanostructures directly written by fs pulses in wide-bandgap materials

    OpenAIRE

    Baumberg, J. J.; Mills, J. D.; Kazansky, P. G.; Bricchi, E.

    2003-01-01

    The use of lasers to directly pattern optoelectronic devices primarily utilizes direct irradiation by UV light. We present here an alternative route using multi-photon absorption within a spherical focus in 3D space, thus allowing complex embedded structures to be directly written. In wide-bandgap materials such as chalcogenide, fluoride and silica glasses, our observations suggest free electrons are produced within the focus of a high-power infrared ultrashort pulse. The anisotropic interact...

  8. Tunable bandgaps and excitons in doped semiconducting carbon nanotubes made possible by acoustic plasmons

    OpenAIRE

    Spataru, Catalin D.; Léonard, François

    2010-01-01

    Doping of semiconductors is essential in modern electronic and photonic devices. While doping is well understood in bulk semiconductors, the advent of carbon nanotubes and nanowires for nanoelectronic and nanophotonic applications raises some key questions about the role and impact of doping at low dimensionality. Here we show that for semiconducting carbon nanotubes, bandgaps and exciton binding energies can be dramatically reduced upon experimentally relevant doping, and can be tuned gradua...

  9. Optically fed microwave true-time delay based on a compact liquid-crystal hotonic-bandgap-fiber device

    DEFF Research Database (Denmark)

    Wei, Lei; Xue, Weiqi; Chen, Yaohui; Alkeskjold, Thomas Tanggaard; Bjarklev, Anders Overgaard

    2009-01-01

    An electrically tunable liquid-crystal, photonic-bandgap-fiber-device-based, optically fed microwave true-time delay is demonstrated with the response time in the millisecond range. A maximum electrically controlled phase shift of around 70° at 15GHz and an averaged 12.9ps true time delay over the...

  10. Quasi-Fermi level splitting and sub-bandgap absorptivity from semiconductor photoluminescence

    Energy Technology Data Exchange (ETDEWEB)

    Katahara, John K.; Hillhouse, Hugh W., E-mail: h2@uw.edu [Department of Chemical Engineering, University of Washington, Seattle, Washington 98105 (United States)

    2014-11-07

    A unified model for the direct gap absorption coefficient (band-edge and sub-bandgap) is developed that encompasses the functional forms of the Urbach, Thomas-Fermi, screened Thomas-Fermi, and Franz-Keldysh models of sub-bandgap absorption as specific cases. We combine this model of absorption with an occupation-corrected non-equilibrium Planck law for the spontaneous emission of photons to yield a model of photoluminescence (PL) with broad applicability to band-band photoluminescence from intrinsic, heavily doped, and strongly compensated semiconductors. The utility of the model is that it is amenable to full-spectrum fitting of absolute intensity PL data and yields: (1) the quasi-Fermi level splitting, (2) the local lattice temperature, (3) the direct bandgap, (4) the functional form of the sub-bandgap absorption, and (5) the energy broadening parameter (Urbach energy, magnitude of potential fluctuations, etc.). The accuracy of the model is demonstrated by fitting the room temperature PL spectrum of GaAs. It is then applied to Cu(In,Ga)(S,Se){sub 2} (CIGSSe) and Cu{sub 2}ZnSn(S,Se){sub 4} (CZTSSe) to reveal the nature of their tail states. For GaAs, the model fit is excellent, and fitted parameters match literature values for the bandgap (1.42 eV), functional form of the sub-bandgap states (purely Urbach in nature), and energy broadening parameter (Urbach energy of 9.4 meV). For CIGSSe and CZTSSe, the model fits yield quasi-Fermi leveling splittings that match well with the open circuit voltages measured on devices made from the same materials and bandgaps that match well with those extracted from EQE measurements on the devices. The power of the exponential decay of the absorption coefficient into the bandgap is found to be in the range of 1.2 to 1.6, suggesting that tunneling in the presence of local electrostatic potential fluctuations is a dominant factor contributing to the sub-bandgap absorption by either purely electrostatic (screened Thomas-Fermi) or

  11. Ultra-wide bandwidth wavelength selective couplers based on the all solid multi-core Ge-doped fibre

    Science.gov (United States)

    Li, X.; Sun, B.; Yu, Y.

    2014-09-01

    A novel wavelength selective coupler based on the all solid nine-core Ge-doped fibre has been proposed. The wavelength selective coupler is based on the phenomenon of a multi-core coupling. All the cores are made of Ge-doped silica and the index of central core is larger than the outer core. At the fixed fibre length, the different wavelength can be selected. The performances of coupling and propagation characteristics have been numerically investigated by using a full beam propagation method (BPM). Simulation results show that the all solid nine-core Ge-doped fibre can achieve simultaneous shorter coupler length and wideband filtering characteristics. The 0.763 mm and 0.745 mm wavelength selective coupler are proposed to achieve different wavelength division and the bandwidth is up to the 400 nm, and 300 nm, respectively.

  12. In situ TEM studies of micron-sized all-solid-state fluoride ion batteries: Preparation, prospects, and challenges.

    Science.gov (United States)

    Hammad Fawey, Mohammed; Chakravadhanula, Venkata Sai Kiran; Reddy, Munnangi Anji; Rongeat, Carine; Scherer, Torsten; Hahn, Horst; Fichtner, Maximilian; Kübel, Christian

    2016-07-01

    Trustworthy preparation and contacting of micron-sized batteries is an essential task to enable reliable in situ TEM studies during electrochemical biasing. Some of the challenges and solutions for the preparation of all-solid-state batteries for in situ TEM electrochemical studies are discussed using an optimized focused ion beam (FIB) approach. In particular redeposition, resistivity, porosity of the electrodes/electrolyte and leakage current are addressed. Overcoming these challenges, an all-solid-state fluoride ion battery has been prepared as a model system for in situ TEM electrochemical biasing studies and first results on a Bi/La0.9 Ba0.1 F2.9 half-cell are presented. Microsc. Res. Tech. 79:615-624, 2016. © 2016 Wiley Periodicals, Inc. PMID:27145192

  13. Machine learning bandgaps of double perovskites

    Science.gov (United States)

    Pilania, G.; Mannodi-Kanakkithodi, A.; Uberuaga, B. P.; Ramprasad, R.; Gubernatis, J. E.; Lookman, T.

    2016-01-01

    The ability to make rapid and accurate predictions on bandgaps of double perovskites is of much practical interest for a range of applications. While quantum mechanical computations for high-fidelity bandgaps are enormously computation-time intensive and thus impractical in high throughput studies, informatics-based statistical learning approaches can be a promising alternative. Here we demonstrate a systematic feature-engineering approach and a robust learning framework for efficient and accurate predictions of electronic bandgaps of double perovskites. After evaluating a set of more than 1.2 million features, we identify lowest occupied Kohn-Sham levels and elemental electronegativities of the constituent atomic species as the most crucial and relevant predictors. The developed models are validated and tested using the best practices of data science and further analyzed to rationalize their prediction performance.

  14. Porous silicon bandgap broadening at natural oxidation

    International Nuclear Information System (INIS)

    Emission and excitation photoluminescence spectra of porous silicon thin layers have been investigated at natural oxidation. The shift of both types of spectra to high-energy region with time has been shown. Analysis of excitation spectra points out the indirect behavior of electron transitions responsible for visible photoluminescence, which remains unaltered at natural oxidation. The value of optical bandgap is estimated in each case. It is shown that the optical bandgap broadens during oxidation due to size reduction of silicon nanocrystallites. - Highlights: → Porous silicon emission and excitation spectra blue shifted at natural oxidation. → Excitation spectra points out the indirect behavior of electron transitions. → Optical bandgap broadens during oxidation due to Si nanoparticles size reduction.

  15. Radiation risk models for all solid cancers other than those types of cancer requiring individual assessments after a nuclear accident.

    Science.gov (United States)

    Walsh, Linda; Zhang, Wei

    2016-03-01

    In the assessment of health risks after nuclear accidents, some health consequences require special attention. For example, in their 2013 report on health risk assessment after the Fukushima nuclear accident, the World Health Organisation (WHO) panel of experts considered risks of breast cancer, thyroid cancer and leukaemia. For these specific cancer types, use was made of already published excess relative risk (ERR) and excess absolute risk (EAR) models for radiation-related cancer incidence fitted to the epidemiological data from the Japanese A-bomb Life Span Study (LSS). However, it was also considered important to assess all other types of solid cancer together and the WHO, in their above-mentioned report, stated "No model to calculate the risk for all other solid cancer excluding breast and thyroid cancer risks is available from the LSS data". Applying the LSS models for all solid cancers along with the models for the specific sites means that some cancers have an overlap in the risk evaluations. Thus, calculating the total solid cancer risk plus the breast cancer risk plus the thyroid cancer risk can overestimate the total risk by several per cent. Therefore, the purpose of this paper was to publish the required models for all other solid cancers, i.e. all solid cancers other than those types of cancer requiring special attention after a nuclear accident. The new models presented here have been fitted to the same LSS data set from which the risks provided by the WHO were derived. Although it is known already that the EAR and ERR effect modifications by sex are statistically significant for the outcome "all solid cancer", it is shown here that sex modification is not statistically significant for the outcome "all solid cancer other than thyroid and breast cancer". It is also shown here that the sex-averaged solid cancer risks with and without the sex modification are very similar once breast and thyroid cancers are factored out. Some other notable model

  16. Light and gas confinement in hollow-core photonic crystal fibre based photonic microcells

    DEFF Research Database (Denmark)

    Benabid, F.; Roberts, John; Couny, F.; Light, P. S.

    2009-01-01

    optical waveguide guidance. For the second type of fibre, which can guide over a broad wavelength range, we examine the nature of the inhibited coupling. We describe a technique for the fabrication of photonic microcells that can accommodate vacuum pressures, and we finish by showing the latest results on...... guides via a photonic bandgap and the other guides by virtue of an inhibited coupling between core and cladding mode constituents. For the former fibre type, we explore how the bandgap is formed using a photonic analogue of the tight-binding model and how it is related to the anti-resonant reflection...

  17. Mid-Infrared nonlinear silicon photonics

    OpenAIRE

    Liu, Xiaoping; Kuyken, Bart; Green, William M. J.; Osgood, Richard M.; Baets, Roel; Roelkens, Günther

    2014-01-01

    Recently there has been a growing interest in mid-infrared (mid-IR) photonic technology with a wavelength of operation approximately from 2-14 mu m. Among several established mid-IR photonic platforms, silicon nanophotonic platform could potentially offer ultra-compact, and monolithically integrated mid-IR photonic devices and device arrays, which could have board impact in the mid-IR technology, such as molecular spectroscopy, and imaging. At room temperature, silicon has a bandgap similar t...

  18. Using Protection Layers for a 2-Photon Water Splitting Device

    DEFF Research Database (Denmark)

    Seger, Brian; Mei, Bastian Timo; Frydendal, Rasmus;

    2015-01-01

    optimized to absorb low energy photons (small bandgap). To a large degree this approach has been hindered by corrosion issues. In this talk I will first discuss how our computational screening of 2,400 materials showed that very few materials can efficiently absorb light without corroding in water splitting......The 2-photon tandem device for photocatalytic water splitting has been theoretically shown to provide a higher efficiency than a single photon device(1). This increased efficiency can be achieved by having one material optimized to absorb high energy photons (large bandgap) and another material...

  19. Effect of dissolved CO2 on the potential stability of all-solid-state ion-selective electrodes.

    Science.gov (United States)

    Han, J H; Cui, G; Kim, S J; Han, S H; Cha, G S; Nam, H

    2001-11-01

    The influence of dissolved CO2 on the potentiometric responses of all-solid-state ion-selective electrodes (ISEs) was systematically examined with four different types of electrodes fabricated by pairing pH-sensitive and pH-insensitive metal electrodes (Pt and Ag/AgCl, respectively) with pH-sensitive and pH-insensitive ion-selective membranes (H+-selective membrane based on tridodecylamine and Na+-selective membrane based on tetraethyl calix[4]arenetetraacetate, respectively). The experimental results clearly showed that the carbonic acid formed by the diffused CO2 and water vapor at the membrane/metal electrode interface varies the phase boundary potentials both at the inner side of the H+-selective membrane (deltaE(in)mem) and at the metal electrode surface (deltaEelec). The potential changes, deltaE(in)mem and deltaEelec, occurring at the facing boundaries, are opposite in their sign and result in a canceling effect if both the membrane and metal surface are pH-sensitive. Consequently, the H+-selective membrane coated on a pH-sensitive electrode (Pt) tends to exhibit a smaller CO2 interference than that on a pH-insensitive electrode (Ag/AgCl). When the all-solid-state Na+ and K+ ISEs were fabricated with both pH-insensitive metal electrode and ion-selective membrane, they did not suffer from CO2 interference. It was also confirmed that plasticization of the PVC leads to increased CO2 permeation. Various types of intermediate layers were examined to reduce the CO2 interference problem in the fabrication of H+-selective all-solid-state ISEs. The results indicated that the H+-selective electrode needs an intermediate layer that maintains a constant pH unless the carbonic acid formation at the interfacial area is effectively quenched. PMID:11763089

  20. Investigations of a high power all-solid-state synchronously-pumped lithium triborate optical parametric oscillator

    OpenAIRE

    Butterworth, Stuart David

    1997-01-01

    The work presented in this thesis describes the operation of a high power all-solid-state synchronously pumped optical parametric oscillator based on a Brewster-angled lithium triborate crystal. The OPO is pumped by a resonant frequency doubled, amplified, diode-pumped mode-locked laser. Performance characteristics of the individual "modules" in the overall system are presented. The work describes the production of 2.0 psec pulses from a diode-pumped Nd:YLF laser using the passive mode-lo...

  1. All-solid-state blue laser pumped Pr:KY3F10-BBO ultraviolet laser at 305 nm

    International Nuclear Information System (INIS)

    An all-solid-state blue laser pumped Pr:KY3F10 (Pr:KYF) laser at 610 nm has been demonstrated. With an incident pump power of 2.6 W, the maximum output power was 213 mW. Moreover, intracavity second-harmonic generation (SHG) has also been achieved with a maximum ultraviolet power of 11 mW by using a β-BaB2O4 (BBO) nonlinear crystal. To the best of our knowledge, this is the first report on continuous-wave ultraviolet generation by intracavity frequency doubling Pr:KYF laser

  2. All-Solid-State Textile Batteries Made from Nano-Emulsion Conducting Polymer Inks for Wearable Electronics

    OpenAIRE

    Tapani Ryhänen; Darryl Cotton; Di Wei

    2012-01-01

    A rollable and all-solid-state textile lithium battery based on fabric matrix and polymer electrolyte that allows flexibility and fast-charging capability is reported. When immerged into poly(3,4-ethylenedioxythiophene) (PEDOT) nano-emulsion inks, an insulating fabric is converted into a conductive battery electrode for a fully solid state lithium battery with the highest specific energy capacity of 68 mAh/g. This is superior to most of the solid-state conducting polymer primary and/or second...

  3. Coherent mid-infrared supercontinuum generation in all-solid chalcogenide microstructured fibers with all-normal dispersion.

    Science.gov (United States)

    Liu, Lai; Cheng, Tonglei; Nagasaka, Kenshiro; Tong, Hoangtuan; Qin, Guanshi; Suzuki, Takenobu; Ohishi, Yasutake

    2016-01-15

    We report the coherent mid-infrared supercontinuum generation in an all-solid chalcogenide microstructured fiber with all-normal dispersion. The chalcogenide microstructured fiber is a four-hole structure with core material of AsSe2 and air holes that are replaced by As2S5 glass rods. Coherent mid-infrared supercontinuum light extended to 3.3 μm is generated in a 2 cm long chalcogenide microstructured fiber pumped by a 2.7 μm laser. PMID:26766722

  4. Defect solitons in photonic lattices.

    Science.gov (United States)

    Yang, Jianke; Chen, Zhigang

    2006-02-01

    Nonlinear defect modes (defect solitons) and their stability in one-dimensional photonic lattices with focusing saturable nonlinearity are investigated. It is shown that defect solitons bifurcate out from every infinitesimal linear defect mode. Low-power defect solitons are linearly stable in lower bandgaps but unstable in higher bandgaps. At higher powers, defect solitons become unstable in attractive defects, but can remain stable in repulsive defects. Furthermore, for high-power solitons in attractive defects, we found a type of Vakhitov-Kolokolov (VK) instability which is different from the usual VK instability based on the sign of the slope in the power curve. Lastly, we demonstrate that in each bandgap, in addition to defect solitons which bifurcate from linear defect modes, there is also an infinite family of other defect solitons which can be stable in certain parameter regimes. PMID:16605473

  5. Manufacturing method of photonic crystal

    Science.gov (United States)

    Park, In Sung; Lee, Tae Ho; Ahn, Jin Ho; Biswas, Rana; Constant, Kristen P.; Ho, Kai-Ming; Lee, Jae-Hwang

    2013-01-29

    A manufacturing method of a photonic crystal is provided. In the method, a high-refractive-index material is conformally deposited on an exposed portion of a periodic template composed of a low-refractive-index material by an atomic layer deposition process so that a difference in refractive indices or dielectric constants between the template and adjacent air becomes greater, which makes it possible to form a three-dimensional photonic crystal having a superior photonic bandgap. Herein, the three-dimensional structure may be prepared by a layer-by-layer method.

  6. Atomic layer deposition of lithium phosphates as solid-state electrolytes for all-solid-state microbatteries

    International Nuclear Information System (INIS)

    Atomic layer deposition (ALD) has been shown as a powerful technique to build three-dimensional (3D) all-solid-state microbattery, because of its unique advantages in fabricating uniform and pinhole-free thin films in 3D structures. The development of solid-state electrolyte by ALD is a crucial step to achieve the fabrication of 3D all-solid-state microbattery by ALD. In this work, lithium phosphate solid-state electrolytes were grown by ALD at four different temperatures (250, 275, 300, and 325 °C) using two precursors (lithium tert-butoxide and trimethylphosphate). A linear dependence of film thickness on ALD cycle number was observed and uniform growth was achieved at all four temperatures. The growth rate was 0.57, 0.66, 0.69, and 0.72 Å/cycle at deposition temperatures of 250, 275, 300, and 325 °C, respectively. Furthermore, x-ray photoelectron spectroscopy confirmed the compositions and chemical structures of lithium phosphates deposited by ALD. Moreover, the lithium phosphate thin films deposited at 300 °C presented the highest ionic conductivity of 1.73 × 10−8 S cm−1 at 323 K with ∼0.51 eV activation energy based on the electrochemical impedance spectroscopy. The ionic conductivity was calculated to be 3.3 × 10−8 S cm−1 at 26 °C (299 K). (paper)

  7. High-energy all-solid-state sodium beacon laser with line width of 0.6 GHz

    Science.gov (United States)

    Lu, Yan-Hua; Xie, Gang; Zhang, Lei; Fan, Guo-Bin; Pang, Yu; Li, Nan; Wei, Bin; Gao, Song-Xin; Zhang, Wei; Tang, Chun

    2015-02-01

    A high-energy all-solid-state sodium beacon laser at 589 nm with a repetition rate of 50 Hz is introduced, which is based on sum frequency mixing between a 1,064 nm laser and a 1,319 nm laser. The 1,064 nm laser, which features an external modulated CW seed laser and several stages of amplifiers, can provide pulse energy of 740 mJ with ultra-narrow line width (~17 kHz) and superior stability. The 1,319 nm laser can deliver pulse energy of 580 mJ with a narrow line width of 0.6 GHz. By sum frequency mixing in a LBO crystal, pulse energy of 380 mJ is achieved at 589 nm with a conversion efficiency of 29 %. By controlling the center wavelength of 1,064 nm laser, the target beam's central wavelength is locked to be 589.1592 nm with a line width of 0.6 GHz, which is dominated mainly by the 1,319 nm laser. The beam quality factor is measured to be M 2 = 1.6. The pulse duration is measured to be 140 μs in full-width at half-maximum (FWHM). To the best of our knowledge, this represents the highest pulse energy for all-solid-state sodium beacon laser ever reported.

  8. All-solid-state high performance asymmetric supercapacitors based on novel MnS nanocrystal and activated carbon materials

    Science.gov (United States)

    Chen, Teng; Tang, Yongfu; Qiao, Yuqing; Liu, Zhangyu; Guo, Wenfeng; Song, Jianzheng; Mu, Shichun; Yu, Shengxue; Zhao, Yufeng; Gao, Faming

    2016-03-01

    All-solid-state high-performance asymmetric supercapacitors (ASCs) are fabricated using γ-MnS as positive electrode and porous eggplant derived activated carbon (EDAC) as negative electrode with saturated potassium hydroxide agar gel as the solid electrolyte. The laminar wurtzite nanostructure of γ-MnS facilitates the insertion of hydroxyl ions into the interlayer space, and the manganese sulfide nanowire offers electronic transportation channels. The size-uniform porous nanostructure of EDAC provides a continuous electron pathway as well as facilitates short ionic transportation pathways. Due to these special nanostructures of both the MnS and the EDAC, they exhibited a specific capacitance of 573.9 and 396 F g‑1 at 0.5 A g‑1, respectively. The optimized MnS//EDAC asymmetric supercapacitor shows a superior performance with specific capacitance of 110.4 F g‑1 and 89.87% capacitance retention after 5000 cycles, a high energy density of 37.6 Wh kg‑1 at a power density of 181.2 W kg‑1 and remains 24.9 Wh kg‑1 even at 5976 W kg‑1. Impressively, such two assembled all-solid-state cells in series can light up a red LED indicator for 15 minutes after fully charged. These impressive results make these pollution-free materials promising for practical applications in solid aqueous electrolyte-based ASCs.

  9. Inkjet-printed all solid-state electrochromic devices based on NiO/WO3 nanoparticle complementary electrodes.

    Science.gov (United States)

    Cai, Guofa; Darmawan, Peter; Cui, Mengqi; Chen, Jingwei; Wang, Xu; Eh, Alice Lee-Sie; Magdassi, Shlomo; Lee, Pooi See

    2016-01-01

    Nanostructured thin films are important in the fields of energy conversion and storage. In particular, multi-layered nanostructured films play an important role as a part of the energy system for energy saving applications in buildings. Inkjet printing is a low-cost and attractive technology for patterning and deposition of multi-layered nanostructured materials on various substrates. However, it requires the development of a suitable ink formulation with optimum viscosity, surface tension and evaporation rate for various materials. In this study, a versatile ink formulation was successfully developed to prepare NiO and WO3 nanostructured films with strong adhesion to ITO coated glass using inkjet printing for energy saving electrochromic applications. We achieved a high performance electrochromic electrode, producing porous and continuous electrochromic films without aggregation. The NiO film with 9 printed layers exhibits an optical modulation of 64.2% at 550 nm and a coloration efficiency (CE) of 136.7 cm(2) C(-1). An inkjet-printed complementary all solid-state device was assembled, delivering a larger optical modulation of 75.4% at 633 nm and a higher CE of 131.9 cm(2) C(-1) among all solid-state devices. The enhanced contrast is due to the printed NiO film that not only performs as an ion storage layer, but also as a complementary electrochromic layer. PMID:26610811

  10. Orthogonal optimization for room temperature magnetron sputtering of ZnO:Al films for all-solid electrochromic devices

    International Nuclear Information System (INIS)

    In order to obtain competent and quality (high transparency, conductivity and stability) aluminium-doped zinc oxide (ZnO:Al, ZAO) films for all solid electrochromic devices, ZAO films were prepared by direct current (D.C.) reactive magnetron sputtering at room temperature based on orthogonal design. Optical and electrical property dependences of the films on the four dominant sputtering parameters: sputtering time, target-substrate distance, sputtering power and O2 flow ratio were simultaneously investigated with measured results using mathematical and statistical method. Optimal Parameters to fabricate ZAO films with optimum comprehensive performances were obtained ultimately. Resistivity and carrier concentration of ZAO film deposited with optimized parameters were 3.89 x 10-4 Ω cm and 1.09 x 1021 cm-3, respectively. ZAO films with these superior properties were employed as transparent electrodes eventually in a WO3 based all-solid electrochromic device which displayed good electrochromic performance. The regulation range for transmittance in the visible region of the device was more than 50%, which was comparable to that of the device adopting indium tin oxide (ITO) films as electrodes.

  11. Simultaneous Band-Gap Narrowing and Carrier-Lifetime Prolongation of Organic-Inorganic Trihalide Perovskites

    Energy Technology Data Exchange (ETDEWEB)

    Kong, Lingping; Liu, Gang; Gong, Jue; Hu, Qingyang; Schaller, Richard D.; Dera, Przemyslaw; Zhang, Dongzhou; Liu, Zhenxian; Yang, Wenge; Zhu, Kai; Tang, Yuzhao; Wang, Chuanyi; Wei, Su-Huai; Xu, Tao; Mao, Ho-kwang

    2016-08-09

    The organic-inorganic hybrid lead trihalide perovskites have been emerging as the most attractive photovoltaic materials. As regulated by Shockley-Queisser theory, a formidable materials science challenge for improvement to the next level requires further band-gap narrowing for broader absorption in solar spectrum, while retaining or even synergistically prolonging the carrier lifetime, a critical factor responsible for attaining the near-band-gap photovoltage. Herein, by applying controllable hydrostatic pressure, we have achieved unprecedented simultaneous enhancement in both band-gap narrowing and carrier-lifetime prolongation (up to 70% to -100% increase) under mild pressures at -0.3 GPa. The pressure-induced modulation on pure hybrid perovskites without introducing any adverse chemical or thermal effect clearly demonstrates the importance of band edges on the photon-electron interaction and maps a pioneering route toward a further increase in their photovoltaic performance.

  12. Simultaneous band-gap narrowing and carrier-lifetime prolongation of organic-inorganic trihalide perovskites.

    Science.gov (United States)

    Kong, Lingping; Liu, Gang; Gong, Jue; Hu, Qingyang; Schaller, Richard D; Dera, Przemyslaw; Zhang, Dongzhou; Liu, Zhenxian; Yang, Wenge; Zhu, Kai; Tang, Yuzhao; Wang, Chuanyi; Wei, Su-Huai; Xu, Tao; Mao, Ho-Kwang

    2016-08-01

    The organic-inorganic hybrid lead trihalide perovskites have been emerging as the most attractive photovoltaic materials. As regulated by Shockley-Queisser theory, a formidable materials science challenge for improvement to the next level requires further band-gap narrowing for broader absorption in solar spectrum, while retaining or even synergistically prolonging the carrier lifetime, a critical factor responsible for attaining the near-band-gap photovoltage. Herein, by applying controllable hydrostatic pressure, we have achieved unprecedented simultaneous enhancement in both band-gap narrowing and carrier-lifetime prolongation (up to 70% to ∼100% increase) under mild pressures at ∼0.3 GPa. The pressure-induced modulation on pure hybrid perovskites without introducing any adverse chemical or thermal effect clearly demonstrates the importance of band edges on the photon-electron interaction and maps a pioneering route toward a further increase in their photovoltaic performance. PMID:27444014

  13. Wide bandgap matrix switcher, amplifier and oscillator

    Energy Technology Data Exchange (ETDEWEB)

    Sampayan, Stephen

    2016-08-16

    An electronic device comprising an optical gate, an electrical input an electrical output and a wide bandgap material positioned between the electrical input and the electrical output to control an amount of current flowing between the electrical input and the electrical output in response to a stimulus received at the optical gate can be used in wideband telecommunication applications in transmission of multi-channel signals.

  14. Large Bandgap Semiconductors for Solar Water Splitting

    DEFF Research Database (Denmark)

    Malizia, Mauro

    Photoelectrochemical water splitting represents an eco-friendly technology that could enable the production of hydrogen using water as reactant and solar energy as primary energy source. The exploitation of solar energy for the production of hydrogen would help modern society to reduce the relian...... on fossil fuels as primary feedstock for hydrogen production and diminish the emission of greenhouse gases in the atmosphere, weakening the global warming phenomenon.The dissertation reports the development of GaP (gallium phosphide) photocathodes as a large bandgap semiconductor for...... photoelectrochemical water splitting devices having tandem design. The increase of the photovoltage produced by GaP under illumination was the main goal of this work. GaP has a bandgap of 2.25 eV and could in theory produce a photovoltage of approximately 1.7 V. Instead, the photovoltage produced by the semiconductor...... of BiVO4 (bismuth vanadate) was investigated in view of combining this 2.4 eV large bandgap semiconductor with a Si back-illuminated photocathode. A device obtained by mechanical stacking of BiVO4 photoanode and standard Si photocathode performs non-assisted water splitting under illumination with...

  15. High rate bias sputtered LiCoO2 thinfilms as positive electrode for all-solid-state lithium microbatteries

    International Nuclear Information System (INIS)

    Highlights: • High performance all-solid-state Li microbatteries using bias sputtered LiCoO2 films. • High specific capacity of 50 μAh cm−2 μm−1 • Significant decrease in the annealing treatment of deposits from 700°C to 400-500°C. • High rate capability: only 12% capacity decrease in the C/2.5 to 30 C range • Excellent cycle life over 900 cycles (84% capacity retention at C/2.5). - Abstract: A LiCoO2 thin film with a crystalline structure and free of the cubic phase is obtained by adopting a two-step treatment with a combination of bias substrate during RF sputtering and a post-annealing treatment at moderate temperature of 500 °C or 400 °C. All-solid-state Li/LiPON/LiCoO2 lithium batteries are fabricated using such crystalline bias LiCoO2 thin films. The crack-free surface of the cathode thin film and the nanosized LiCoO2 particles ensure an efficient electrochemical behavior and high performance of the battery. The rate capability and the influence of the voltage range on the rechargeable capacity delivered by the battery are investigated as well as cycling properties. A high capacity close to 50 μAh cm−2 μm−1 is demonstrated at 10 μA. cm−2 with an excellent rate capability since 86% of this value is recovered at 30 C without any further damage of the cathode thin film. An excellent cycling behavior of the biased film is demonstrated since after a capacity decay of 12% over the first 100 cycles, the specific capacity practically does not decline over 800 additional cycles at 0.4 C rate. These results compare very well with the best all-solid-state Li microbatteries built with LiCoO2 heat-treated at 700 °C or more. It exemplifies the relevance of using biased LiCoO2 thin films heat-treated at moderate temperature (400 °C-500 °C)

  16. A quantum photonic dissipative transport theory

    Science.gov (United States)

    Lei, Chan U.; Zhang, Wei-Min

    2012-05-01

    In this paper, a quantum transport theory for describing photonic dissipative transport dynamics in nanophotonics is developed. The nanophotonic devices concerned in this paper consist of on-chip all-optical integrated circuits incorporating photonic bandgap waveguides and driven resonators embedded in nanostructured photonic crystals. The photonic transport through waveguides is entirely determined from the exact master equation of the driven resonators, which is obtained by explicitly eliminating all the degrees of freedom of the waveguides (treated as reservoirs). Back-reactions from the reservoirs are fully taken into account. The relation between the driven photonic dynamics and photocurrents is obtained explicitly. The non-Markovian memory structure and quantum decoherence dynamics in photonic transport can then be fully addressed. As an illustration, the theory is utilized to study the transport dynamics of a photonic transistor consisting of a nanocavity coupled to two waveguides in photonic crystals. The controllability of photonic transport through the external driven field is demonstrated.

  17. Coherent mid-infrared supercontinuum generation in all-solid chalcogenide microstructured fibers with all-normal dispersion

    Science.gov (United States)

    Liu, Lai; Cheng, Tonglei; Nagasaka, Kenshiro; Tong, Hoang Tuan; Suzuki, Takenobu; Ohishi, Yasutake

    2016-02-01

    We report the coherent mid-infrared supercontinuum generation in an all-solid chalcogenide microstructured fiber with all-normal dispersion. The chalcogenide microstructured fiber is four-hole structure with core material of AsSe2 and air holes are replaced by As2S5 glass rods. Coherent mid-infrared supercontinuum light is generated in a 2-cm-long chalcogenide microstructured fiber pumped by a 2.7 μm laser. The simulated and experimental results have a good match and the coherence property of supercontinuum light in the chalcogenide microstructured fiber has been studied by using the complex degree of coherence theory. Coherent mid-infrared supercontinuum generation is extended to 3.3 μm in this work.

  18. Effects of cathode electrolyte interfacial (CEI) layer on long term cycling of all-solid-state thin-film batteries

    Science.gov (United States)

    Wang, Ziying; Lee, Jungwoo Z.; Xin, Huolin L.; Han, Lili; Grillon, Nathanael; Guy-Bouyssou, Delphine; Bouyssou, Emilien; Proust, Marina; Meng, Ying Shirley

    2016-08-01

    All-solid-state lithium-ion batteries have the potential to not only push the current limits of energy density by utilizing Li metal, but also improve safety by avoiding flammable organic electrolyte. However, understanding the role of solid electrolyte - electrode interfaces will be critical to improve performance. In this study, we conducted long term cycling on commercially available lithium cobalt oxide (LCO)/lithium phosphorus oxynitride (LiPON)/lithium (Li) cells at elevated temperature to investigate the interfacial phenomena that lead to capacity decay. STEM-EELS analysis of samples revealed a previously unreported disordered layer between the LCO cathode and LiPON electrolyte. This electrochemically inactive layer grew in thickness leading to loss of capacity and increase of interfacial resistance when cycled at 80 °C. The stabilization of this layer through interfacial engineering is crucial to improve the long term performance of thin-film batteries especially under thermal stress.

  19. An All-Solid-State Fiber-Shaped Aluminum-Air Battery with Flexibility, Stretchability, and High Electrochemical Performance.

    Science.gov (United States)

    Xu, Yifan; Zhao, Yang; Ren, Jing; Zhang, Ye; Peng, Huisheng

    2016-07-01

    Owing to the high theoretical energy density of metal-air batteries, the aluminum-air battery has been proposed as a promising long-term power supply for electronics. However, the available energy density from the aluminum-air battery is far from that anticipated and is limited by current electrode materials. Herein we described the creation of a new family of all-solid-state fiber-shaped aluminum-air batteries with a specific capacity of 935 mAh g(-1) and an energy density of 1168 Wh kg(-1) . The synthesis of an electrode composed of cross-stacked aligned carbon-nanotube/silver-nanoparticle sheets contributes to the remarkable electrochemical performance. The fiber shape also provides the aluminum-air batteries with unique advantages; for example, they are flexible and stretchable and can be woven into a variety of textiles for large-scale applications. PMID:27193636

  20. Modulation of superconducting critical temperature in niobium film by using all-solid-state electric-double-layer transistor

    International Nuclear Information System (INIS)

    An all-solid-state electric-double-layer transistor (EDLT) was fabricated for electrical modulation of the superconducting critical temperature (Tc) of Nb film epitaxially grown on α-Al2O3 (0001) single crystal. In an experiment, Tc was modulated from 8.33 to 8.39 K while the gate voltage (VG) was varied from 2.5 to −2.5 V. The specific difference of Tc for the applied VG was 12 mK/V, which is larger than that of an EDLT composed of ionic liquid. A Tc enhancement of 300 mK was found at the Li4SiO4/Nb film interface and is attributed to an increase in density of states near the Fermi level due to lattice constant modulation. This solid electrolyte gating method should enable development of practical superconducting devices highly compatible with other electronic devices

  1. A sequential thin-film deposition equipment for in-situ fabricating all-solid-state thin film lithium batteries

    Energy Technology Data Exchange (ETDEWEB)

    Liu Wenyuan [Laser Chemistry Institute, Department of Chemistry, Fudan University, Shanghai, 200433 (China); Fu Zhengwen [Laser Chemistry Institute, Department of Chemistry, Fudan University, Shanghai, 200433 (China); Qin Qizong [Laser Chemistry Institute, Department of Chemistry, Fudan University, Shanghai, 200433 (China)]. E-mail: qzqin@fudan.ac.cn

    2007-02-26

    To improve the interfacial quality and electrochemical performance of all-solid-state thin film lithium batteries (TFLBs), a sequential thin film deposition equipment has been developed. This equipment consists of a dry glove box for packing TFLB and four vacuum chambers, one chamber of them for deposition lithium film anode by flash thermal evaporation, and the other three vacuum chambers for deposition of current collectors, cathode and solid electrolyte by magnetron sputtering, respectively. This equipment has been used to sequentially deposited Au current collector, TiO{sub 2} cathode, LiPON (lithium phosphorus oxynitride) solid electrolyte and metallic Li anode thin films, and to prepare a TFLB with a structural configuration of Li/LiPON/TiO{sub 2}/Au via an in-situ process without breaking vacuum. The results showed that the TFLB exhibited lower interface resistance and better electrochemical performance than that fabricated via an ex-situ process.

  2. A sequential thin-film deposition equipment for in-situ fabricating all-solid-state thin film lithium batteries

    International Nuclear Information System (INIS)

    To improve the interfacial quality and electrochemical performance of all-solid-state thin film lithium batteries (TFLBs), a sequential thin film deposition equipment has been developed. This equipment consists of a dry glove box for packing TFLB and four vacuum chambers, one chamber of them for deposition lithium film anode by flash thermal evaporation, and the other three vacuum chambers for deposition of current collectors, cathode and solid electrolyte by magnetron sputtering, respectively. This equipment has been used to sequentially deposited Au current collector, TiO2 cathode, LiPON (lithium phosphorus oxynitride) solid electrolyte and metallic Li anode thin films, and to prepare a TFLB with a structural configuration of Li/LiPON/TiO2/Au via an in-situ process without breaking vacuum. The results showed that the TFLB exhibited lower interface resistance and better electrochemical performance than that fabricated via an ex-situ process

  3. Inkjet-printed all solid-state electrochromic devices based on NiO/WO3 nanoparticle complementary electrodes

    Science.gov (United States)

    Cai, Guofa; Darmawan, Peter; Cui, Mengqi; Chen, Jingwei; Wang, Xu; Eh, Alice Lee-Sie; Magdassi, Shlomo; Lee, Pooi See

    2015-12-01

    Nanostructured thin films are important in the fields of energy conversion and storage. In particular, multi-layered nanostructured films play an important role as a part of the energy system for energy saving applications in buildings. Inkjet printing is a low-cost and attractive technology for patterning and deposition of multi-layered nanostructured materials on various substrates. However, it requires the development of a suitable ink formulation with optimum viscosity, surface tension and evaporation rate for various materials. In this study, a versatile ink formulation was successfully developed to prepare NiO and WO3 nanostructured films with strong adhesion to ITO coated glass using inkjet printing for energy saving electrochromic applications. We achieved a high performance electrochromic electrode, producing porous and continuous electrochromic films without aggregation. The NiO film with 9 printed layers exhibits an optical modulation of 64.2% at 550 nm and a coloration efficiency (CE) of 136.7 cm2 C-1. An inkjet-printed complementary all solid-state device was assembled, delivering a larger optical modulation of 75.4% at 633 nm and a higher CE of 131.9 cm2 C-1 among all solid-state devices. The enhanced contrast is due to the printed NiO film that not only performs as an ion storage layer, but also as a complementary electrochromic layer.Nanostructured thin films are important in the fields of energy conversion and storage. In particular, multi-layered nanostructured films play an important role as a part of the energy system for energy saving applications in buildings. Inkjet printing is a low-cost and attractive technology for patterning and deposition of multi-layered nanostructured materials on various substrates. However, it requires the development of a suitable ink formulation with optimum viscosity, surface tension and evaporation rate for various materials. In this study, a versatile ink formulation was successfully developed to prepare NiO and

  4. An all-solid-state laser source at 671 nm for cold-atom experiments with lithium

    Science.gov (United States)

    Eismann, U.; Gerbier, F.; Canalias, C.; Zukauskas, A.; Trénec, G.; Vigué, J.; Chevy, F.; Salomon, C.

    2012-01-01

    We present an all-solid-state narrow-linewidth laser source emitting 670 mW output power at 671 nm delivered in a diffraction-limited beam. The source is based on a frequency-doubled diode-end-pumped ring laser operating on the 4 F 3/2→4 I 13/2 transition in Nd:YVO4. By using periodically poled potassium titanyl phosphate (ppKTP) in an external buildup cavity, doubling efficiencies of up to 86% are obtained. Tunability of the source over 100 GHz is accomplished. We demonstrate the suitability of this robust frequency-stabilized light source for laser cooling of lithium atoms. Finally, a simplified design based on intra-cavity doubling is described and first results are presented.

  5. Flexible all solid state supercapacitor with high energy density employing black titania nanoparticles as a conductive agent

    Science.gov (United States)

    Zhi, Jian; Yang, Chongyin; Lin, Tianquan; Cui, Houlei; Wang, Zhou; Zhang, Hui; Huang, Fuqiang

    2016-02-01

    Increasing the electrical conductivity of pseudocapacitive materials without changing their morphology is an ideal structural solution to realize both high electrochemical performance and superior flexibility for an all solid state supercapacitor (ASSSC). Herein, we fabricate a flexible ASSSC device employing black titania (TiO2-x:N) decorated two-dimensional (2D) NiO nanosheets as the positive electrode and mesoporous graphene as the negative electrode. In this unique design, NiO nanosheets are used as pseudocapacitive materials and TiO2-x:N nanoparticles serve as the conductive agent. Owing to the excellent electrical conductivity of TiO2-x:N and well defined ``particle on sheet'' planar structure of NiO/TiO2-x:N composites, the 2D morphology of the decorated NiO nanosheets is completely retained, which efficiently reinforces the pseudocapacitive activity and flexibility of the whole all solid state device. The maximum specific capacitance of fabricated the NiO/TiO2-x:N//mesoporous graphene supercapacitor can reach 133 F g-1, which is 2 and 4 times larger than the values of the NiO based ASSSC employing graphene and carbon black as the conductive agent, respectively. In addition, the optimized ASSSC displays intriguing performances with an energy density of 47 W h kg-1 in a voltage region of 0-1.6 V, which is, to the best of our knowledge, the highest value for flexible ASSSC devices. The impressive results presented here may pave the way for promising applications of black titania in high energy density flexible storage systems.Increasing the electrical conductivity of pseudocapacitive materials without changing their morphology is an ideal structural solution to realize both high electrochemical performance and superior flexibility for an all solid state supercapacitor (ASSSC). Herein, we fabricate a flexible ASSSC device employing black titania (TiO2-x:N) decorated two-dimensional (2D) NiO nanosheets as the positive electrode and mesoporous graphene as the

  6. Ab initio study of the bandgap engineering of Al1−xGaxN for optoelectronic applications

    KAUST Repository

    Amin, B.

    2011-01-19

    A theoretical study of Al1−xGaxN, based on the full-potential linearized augmented plane wave method, is used to investigate the variations in the bandgap,optical properties, and nonlinear behavior of the compound with the change in the Ga concentration. It is found that the bandgap decreases with the increase in Ga. A maximum value of 5.50 eV is determined for the bandgap of pure AlN, which reaches a minimum value of 3.0 eV when Al is completely replaced by Ga. The static index of refraction and dielectric constant decreases with the increase in the bandgap of the material, assigning a high index of refraction to pure GaN when compared to pure AlN. The refractive index drops below 1 for higher energy photons, larger than 14 eV. The group velocity of these photons is larger than the vacuum velocity of light. This astonishing result shows that at higher energies the optical properties of the material shifts from linear to nonlinear. Furthermore, frequency dependent reflectivity and absorption coefficients show that peak values of the absorption coefficient and reflectivity shift toward lower energy in the ultraviolet (UV) spectrum with the increase in Ga concentration. This comprehensive theoretical study of the optoelectronic properties predicts that the material can be effectively used in the optical devices working in the visible and UV spectrum.

  7. Three-dimensional photonic crystals created by single-step multi-directional plasma etching.

    Science.gov (United States)

    Suzuki, Katsuyoshi; Kitano, Keisuke; Ishizaki, Kenji; Noda, Susumu

    2014-07-14

    We fabricate 3D photonic nanostructures by simultaneous multi-directional plasma etching. This simple and flexible method is enabled by controlling the ion-sheath in reactive-ion-etching equipment. We realize 3D photonic crystals on single-crystalline silicon wafers and show high reflectance (>95%) and low transmittance (<-15dB) at optical communication wavelengths, suggesting the formation of a complete photonic bandgap. Moreover, our method simply demonstrates Si-based 3D photonic crystals that show the photonic bandgap effect in a shorter wavelength range around 0.6 μm, where further fine structures are required. PMID:25090524

  8. Quantum Transport Theory for Photonic Networks

    CERN Document Server

    Lei, Chan U

    2010-01-01

    In this paper, we develop a quantum transport theory to describe photonic transport in photonic networks. The photonic networks concerned in the paper consist of all-optical circuits incorporating photonic bandgap waveguides and driven resonators. The photoncurrents flowing through waveguides are entirely determined from the exact master equation of the driven resonators. The master equation of the driven resonators is obtained by explicitly eliminating all the waveguide degrees of freedom while the back-reactions between resonators and waveguides are fully taken into account. The relations between the driven photonic dynamics and photoncurrents are obtained. The quantum dissipation and quantum noise effects in photonic transport are also fully addressed. As an illustration, the theory is applied to the transport phenomena of a driven nanocavity coupled to two waveguides in photonic crystals. The controllability of photonic transport through the driven resonator is demonstrated.

  9. Photonics based on carbon nanotubes

    OpenAIRE

    Gu, Qingyuan; Gicquel-Guézo, Maud; Loualiche, Slimane; Pouliquen, Julie Le; Batte, Thomas; Folliot, Hervé; Dehaese, Olivier; Grillot, Frederic; Battie, Yann; Loiseau, Annick; Liang, Baolai; Huffaker, Diana

    2013-01-01

    Among direct-bandgap semiconducting nanomaterials, single-walled carbon nanotubes (SWCNT) exhibit strong quasi-one-dimensional excitonic optical properties, which confer them a great potential for their integration in future photonics devices as an alternative solution to conventional inorganic semiconductors. In this paper, we will highlight SWCNT optical properties for passive as well as active applications in future optical networking. For passive applications, we directly compare the effi...

  10. Intermediate Bandgap Solar Cells From Nanostructured Silicon

    Energy Technology Data Exchange (ETDEWEB)

    Black, Marcie [Bandgap Engineering, Lincoln, MA (United States)

    2014-10-30

    This project aimed to demonstrate increased electronic coupling in silicon nanostructures relative to bulk silicon for the purpose of making high efficiency intermediate bandgap solar cells using silicon. To this end, we formed nanowires with controlled crystallographic orientation, small diameter, <111> sidewall faceting, and passivated surfaces to modify the electronic band structure in silicon by breaking down the symmetry of the crystal lattice. We grew and tested these silicon nanowires with <110>-growth axes, which is an orientation that should produce the coupling enhancement.

  11. Switchable Electromagnetic Bandgap Surface Wave Antenna

    Directory of Open Access Journals (Sweden)

    Qiang Bai

    2014-01-01

    Full Text Available This paper presents a novel switchable electromagnetic bandgap surface wave antenna that can support both a surface wave and normal mode radiation for communications at 2.45 GHz. In the surface wave mode, the antenna has a monopole-like radiation pattern with a measured gain of 4.4 dBi at ±49° and a null on boresight. In the normal mode, the antenna operates like a back-fed microstrip patch antenna.

  12. Monolithic photonic crystal quantum-cascade laser

    Energy Technology Data Exchange (ETDEWEB)

    Benz, A; Deutsch, C H; Fasching, G; Unterrainer, K [Photonics Institute and Center for Micro- and Nanostructures, Vienna University of Technology, Gusshausstrasse 29/387, A-1040 Vienna (Austria); Andrews, A M; Klang, P; Schrenk, W; Strasser, G, E-mail: alexander.benz@tuwien.ac.a [Institute of Solid-State Electronics and Center for Micro- and Nanostructures, Vienna University of Technology, Floragasse 7/362, A-1040 Vienna (Austria)

    2009-11-15

    We present the design and realization of active photonic crystal (PhC) terahertz quantum-cascade lasers. The devices consist of sub-wavelength isolated pillars which are embedded in a double-metal waveguide. The lasing is observed at flat-band regions not in the bandgap itself. A stable single-mode emission under all driving conditions is achieved.

  13. Silicon nanostructures for photonics and photovoltaics

    NARCIS (Netherlands)

    F. Priolo; T. Gregorkiewicz; M. Galli; T.F. Krauss

    2014-01-01

    Silicon has long been established as the material of choice for the microelectronics industry. This is not yet true in photonics, where the limited degrees of freedom in material design combined with the indirect bandgap are a major constraint. Recent developments, especially those enabled by nanosc

  14. Research on micro-sized acoustic bandgap structures.

    Energy Technology Data Exchange (ETDEWEB)

    Fleming, James Grant; McCormick, Frederick Bossert; Su, Mehmet F.; El-Kady, Ihab Fathy; Olsson, Roy H., III; Tuck, Melanie R.

    2010-01-01

    Phononic crystals (or acoustic crystals) are the acoustic wave analogue of photonic crystals. Here a periodic array of scattering inclusions located in a homogeneous host material forbids certain ranges of acoustic frequencies from existence within the crystal, thus creating what are known as acoustic (or phononic) bandgaps. The vast majority of phononic crystal devices reported prior to this LDRD were constructed by hand assembling scattering inclusions in a lossy viscoelastic medium, predominantly air, water or epoxy, resulting in large structures limited to frequencies below 1 MHz. Under this LDRD, phononic crystals and devices were scaled to very (VHF: 30-300 MHz) and ultra (UHF: 300-3000 MHz) high frequencies utilizing finite difference time domain (FDTD) modeling, microfabrication and micromachining technologies. This LDRD developed key breakthroughs in the areas of micro-phononic crystals including physical origins of phononic crystals, advanced FDTD modeling and design techniques, material considerations, microfabrication processes, characterization methods and device structures. Micro-phononic crystal devices realized in low-loss solid materials were emphasized in this work due to their potential applications in radio frequency communications and acoustic imaging for medical ultrasound and nondestructive testing. The results of the advanced modeling, fabrication and integrated transducer designs were that this LDRD produced the 1st measured phononic crystals and phononic crystal devices (waveguides) operating in the VHF (67 MHz) and UHF (937 MHz) frequency bands and established Sandia as a world leader in the area of micro-phononic crystals.

  15. Two-dimensional heterogeneous photonic bandedge laser

    OpenAIRE

    Kwon, Soon-Hong; Kim, Se-Heon; Kim, Sun-Kyung; Lee, Yong-Hee; Kim, Sung-Bock

    2004-01-01

    We proposed and realized a two-dimensional (2D) photonic bandedge laser surrounded by the photonic bandgap. The heterogeneous photonic crystal structure consists of two triangular lattices of the same lattice constant with different air hole radii. The photonic crystal laser was realized by room-temperature optical pumping of air-bridge slabs of InGaAsP quantum wells emitting at 1.55 micrometer. The lasing mode was identified from its spectral positions and polarization directions. A low thre...

  16. Regrowth-Free Processing for GaAs and InP Photonic Integrated Circuits

    Institute of Scientific and Technical Information of China (English)

    John; H.; Marsh

    2003-01-01

    Technologies are described for integrating multiple bandgaps and photonic crystal structures monolithically in a semiconductor chip. Practical devices examples include high power 980 nm pumps, 2×2 crosspoint switches and lasers modelocked at THz frequencies.

  17. A leap over Dirac cones in one-dimensional graphene-based photonic crystal

    Science.gov (United States)

    Jahani, D.; Abaspour, L.; Soltani-Vala, A.; Barvestani, J.

    2016-06-01

    The existence of a photonic bandgap in the visible range of light spectrum corresponding to a 1D graphene-based photonic crystal which recently has been proposed and is formed by embedding alternatively graphene layers into a dielectric background is investigated in this paper. By the use of the complete form of optical conductivity for the full expression of the tight-binding Hamiltonian of graphene layer, we numerically demonstrate an appeared bandgap in the visible region of the spectrum which can open up new route for further high-frequency applications of graphene-based photonic devices. It is revealed that the associated bandgap could be altered by changing the hopping energy and the amount of chemical potential leading to broadening the forbidden frequency regions with further increasing. Finally, it is also shown that the tunability feature of the photonic bandgap could be affected by changing the hopping energy.

  18. Oxygen-activated growth and bandgap tunability of large single-crystal bilayer graphene

    Science.gov (United States)

    Hao, Yufeng; Wang, Lei; Liu, Yuanyue; Chen, Hua; Wang, Xiaohan; Tan, Cheng; Nie, Shu; Suk, Ji Won; Jiang, Tengfei; Liang, Tengfei; Xiao, Junfeng; Ye, Wenjing; Dean, Cory R.; Yakobson, Boris I.; McCarty, Kevin F.; Kim, Philip; Hone, James; Colombo, Luigi; Ruoff, Rodney S.

    2016-05-01

    Bernal (AB)-stacked bilayer graphene (BLG) is a semiconductor whose bandgap can be tuned by a transverse electric field, making it a unique material for a number of electronic and photonic devices. A scalable approach to synthesize high-quality BLG is therefore critical, which requires minimal crystalline defects in both graphene layers and maximal area of Bernal stacking, which is necessary for bandgap tunability. Here we demonstrate that in an oxygen-activated chemical vapour deposition (CVD) process, half-millimetre size, Bernal-stacked BLG single crystals can be synthesized on Cu. Besides the traditional ‘surface-limited’ growth mechanism for SLG (1st layer), we discovered new microscopic steps governing the growth of the 2nd graphene layer below the 1st layer as the diffusion of carbon atoms through the Cu bulk after complete dehydrogenation of hydrocarbon molecules on the Cu surface, which does not occur in the absence of oxygen. Moreover, we found that the efficient diffusion of the carbon atoms present at the interface between Cu and the 1st graphene layer further facilitates growth of large domains of the 2nd layer. The CVD BLG has superior electrical quality, with a device on/off ratio greater than 104, and a tunable bandgap up to ∼100 meV at a displacement field of 0.9 V nm‑1.

  19. Oxygen-activated growth and bandgap tunability of large single-crystal bilayer graphene

    Energy Technology Data Exchange (ETDEWEB)

    Hao, Yufeng; Wang, Lei; Liu, Yuanyue; Chen, Hua; Wang, Xiaohan; Tan, Cheng; Nie, Shu; Suk, Ji Won; Jiang, Tengfei; Liang, Tengfei; Xiao, Junfeng; Ye, Wenjing; Dean, Cory R.; Yakobson, Boris I.; McCarty, Kevin F.; Kim, Philip; Hone, James; Colombo, Luigi; Ruoff, Rodney S.

    2016-02-01

    Bernal (AB)-stacked bilayer graphene (BLG) is a semiconductor whose bandgap can be tuned by a transverse electric field, making it a unique material for a number of electronic and photonic devices. A scalable approach to synthesize high-quality BLG is therefore critical, which requires minimal crystalline defects in both graphene layers and maximal area of Bernal stacking, which is necessary for bandgap tunability. Here we demonstrate that in an oxygen-activated chemical vapour deposition (CVD) process, half-millimetre size, Bernal-stacked BLG single crystals can be synthesized on Cu. Besides the traditional 'surface-limited' growth mechanism for SLG (1st layer), we discovered new microscopic steps governing the growth of the 2nd graphene layer below the 1st layer as the diffusion of carbon atoms through the Cu bulk after complete dehydrogenation of hydrocarbon molecules on the Cu surface, which does not occur in the absence of oxygen. Moreover, we found that the efficient diffusion of the carbon atoms present at the interface between Cu and the 1st graphene layer further facilitates growth of large domains of the 2nd layer. The CVD BLG has superior electrical quality, with a device on/off ratio greater than 104, and a tunable bandgap up to -100 meV at a displacement field of 0.9 V nm-1.

  20. Oxygen-activated growth and bandgap tunability of large single-crystal bilayer graphene.

    Science.gov (United States)

    Hao, Yufeng; Wang, Lei; Liu, Yuanyue; Chen, Hua; Wang, Xiaohan; Tan, Cheng; Nie, Shu; Suk, Ji Won; Jiang, Tengfei; Liang, Tengfei; Xiao, Junfeng; Ye, Wenjing; Dean, Cory R; Yakobson, Boris I; McCarty, Kevin F; Kim, Philip; Hone, James; Colombo, Luigi; Ruoff, Rodney S

    2016-05-01

    Bernal (AB)-stacked bilayer graphene (BLG) is a semiconductor whose bandgap can be tuned by a transverse electric field, making it a unique material for a number of electronic and photonic devices. A scalable approach to synthesize high-quality BLG is therefore critical, which requires minimal crystalline defects in both graphene layers and maximal area of Bernal stacking, which is necessary for bandgap tunability. Here we demonstrate that in an oxygen-activated chemical vapour deposition (CVD) process, half-millimetre size, Bernal-stacked BLG single crystals can be synthesized on Cu. Besides the traditional 'surface-limited' growth mechanism for SLG (1st layer), we discovered new microscopic steps governing the growth of the 2nd graphene layer below the 1st layer as the diffusion of carbon atoms through the Cu bulk after complete dehydrogenation of hydrocarbon molecules on the Cu surface, which does not occur in the absence of oxygen. Moreover, we found that the efficient diffusion of the carbon atoms present at the interface between Cu and the 1st graphene layer further facilitates growth of large domains of the 2nd layer. The CVD BLG has superior electrical quality, with a device on/off ratio greater than 10(4), and a tunable bandgap up to ∼100 meV at a displacement field of 0.9 V nm(-1). PMID:26828845

  1. Compound semiconductor alloys: From atomic-scale structure to bandgap bowing

    International Nuclear Information System (INIS)

    Compound semiconductor alloys such as InxGa1−xAs, GaAsxP1−x, or CuInxGa1−xSe2 are increasingly employed in numerous electronic, optoelectronic, and photonic devices due to the possibility of tuning their properties over a wide parameter range simply by adjusting the alloy composition. Interestingly, the material properties are also determined by the atomic-scale structure of the alloys on the subnanometer scale. These local atomic arrangements exhibit a striking deviation from the average crystallographic structure featuring different element-specific bond lengths, pronounced bond angle relaxation and severe atomic displacements. The latter, in particular, have a strong influence on the bandgap energy and give rise to a significant contribution to the experimentally observed bandgap bowing. This article therefore reviews experimental and theoretical studies of the atomic-scale structure of III-V and II-VI zincblende alloys and I-III-VI2 chalcopyrite alloys and explains the characteristic findings in terms of bond length and bond angle relaxation. Different approaches to describe and predict the bandgap bowing are presented and the correlation with local structural parameters is discussed in detail. The article further highlights both similarities and differences between the cubic zincblende alloys and the more complex chalcopyrite alloys and demonstrates that similar effects can also be expected for other tetrahedrally coordinated semiconductors of the adamantine structural family

  2. Bottom-Up Fabrication of Activated Carbon Fiber for All-Solid-State Supercapacitor with Excellent Electrochemical Performance.

    Science.gov (United States)

    Ma, Wujun; Chen, Shaohua; Yang, Shengyuan; Chen, Wenping; Weng, Wei; Zhu, Meifang

    2016-06-15

    Activated carbon (AC) is the most extensively used electrode material for commercial electric double layer capacitors (EDLC) given its high specific surface area (SSA) and moderate cost. However, AC is primarily used in the forms of powders, which remains a big challenge in developing AC powders into continuous fibers. If AC powders can be processed into fiber, then they may be scaled up for practical applications to supercapacitors (SCs) and satisfy the rapid development of flexible electronics. Herein, we report a bottom-up method to fabricate AC fiber employing graphene oxide (GO) as both dispersant and binder. After chemical reduction, the fiber has high electrical conductivity (185 S m(-1)), high specific surface area (1476.5 m(2) g(-1)), and good mechanical flexibility. An all solid-state flexible SC was constructed using the prepared fiber as electrode, which is free of binder, conducting additive, and additional current collector. The fiber-shaped SC shows high capacitance (27.6 F cm(-3) or 43.8 F g(-1), normalized to the two-electrode volume), superior cyclability (90.4% retention after 10 000 cycles), and good bendability (96.8% retention after bending 1000 times). PMID:27239680

  3. Proton conductive tantalum oxide thin film deposited by reactive DC magnetron sputtering for all-solid-state switchable mirror

    Science.gov (United States)

    Tajima, K.; Yamada, Y.; Bao, S.; Okada, M.; Yoshimura, K.

    2008-03-01

    Our developed all-solid-state switchable mirror as a smart window is consisted in multi-layer of Mg4Ni/Pd/Ta2O5/WO3/ITO/glass and can switch reversibly from the reflective state to the transparent one. The development of high performance solid electrolyte thin film of Ta2O5 is important for fast speed switching and high durability of the device. In this work, we have investigated the electrochemical property of Ta2O5 thin film deposited by reactive DC magnetron sputtering. The effect of thickness on electrochemical and proton conductivities of Ta2O5 thin film was investigated. The Ta2O5 thin film with a thickness of 400 nm had better proton conductivity of 1.5×10-9 S/cm measured by AC impedance method. The transmittance at wavelength of 670 nm of the device with 400 nm thick Ta2O5 thin film was changed from 0.1% (reflective state) to 51% (transparent state) within 10 s by applying voltage of 5 V. The device showed high durability up to two-thousand switching cycles.

  4. Densely-packed graphene/conducting polymer nanoparticle papers for high-volumetric-performance flexible all-solid-state supercapacitors

    Science.gov (United States)

    Yang, Chao; Zhang, Liling; Hu, Nantao; Yang, Zhi; Wei, Hao; Xu, Zhichuan J.; Wang, Yanyan; Zhang, Yafei

    2016-08-01

    Graphene-based all-solid-state supercapacitors (ASSSCs) are one of the most ideal candidates for high-performance flexible power sources. The achievement of high volumetric energy density is highly desired for practical application of this type of ASSSCs. Here, we present a facile method to boost volumetric performances of graphene-based flexible ASSSCs through incorporation of ultrafine polyaniline-poly(4-styrenesulfonate) (PANI-PSS) nanoparticles in reduced graphene oxide (rGO) papers. A compact structure is obtained via intimate contact and π-π interaction between PANI-PSS nanoparticles and rGO sheets. The hybrid paper electrode with the film thickness of 13.5 μm, shows an extremely high volumetric specific capacitance of 272 F/cm3 (0.37 A/cm3 in a three-electrode cell). The assembled ASSSCs show a large volumetric specific capacitance of 217 F/cm3 (0.37 A/cm3 in a two-electrode cell), high volumetric energy and power density, excellent capacitance stability, small leakage current as well as low self-discharge characteristics, revealing the usefulness of this robust hybrid paper for high-performance flexible energy storage devices.

  5. Solid Polymer Electrolytes Based on Functionalized Tannic Acids from Natural Resources for All-Solid-State Lithium-Ion Batteries.

    Science.gov (United States)

    Shim, Jimin; Bae, Ki Yoon; Kim, Hee Joong; Lee, Jin Hong; Kim, Dong-Gyun; Yoon, Woo Young; Lee, Jong-Chan

    2015-12-21

    Solid polymer electrolytes (SPEs) for all-solid-state lithium-ion batteries are prepared by simple one-pot polymerization induced by ultraviolet (UV) light using poly(ethylene glycol) methyl ether methacrylate (PEGMA) as an ion-conducting monomeric unit and tannic acid (TA)-based crosslinking agent and plasticizer. The crosslinking agent and plasticizer based on natural resources are obtained from the reaction of TA with glycidyl methacrylate and glycidyl poly(ethylene glycol), respectively. Dimensionally stable free-standing SPE having a large ionic conductivity of 5.6×10(-4)  Scm(-1) at room temperature can be obtained by the polymerization of PEGMA into P(PEGMA) with a very small amount (0.1 wt %) of the crosslinking agent and 2.0 wt % of the plasticizer. The ionic conductivity value of SPE with a crosslinked structure is one order of magnitude larger than that of linear P(PEGMA) in the waxy state. PMID:26609912

  6. Modulation of superconducting critical temperature in niobium film by using all-solid-state electric-double-layer transistor

    Energy Technology Data Exchange (ETDEWEB)

    Tsuchiya, Takashi, E-mail: TSUCHIYA.Takashi@nims.go.jp, E-mail: TERABE.Kazuya@nims.go.jp; Moriyama, Satoshi; Terabe, Kazuya, E-mail: TSUCHIYA.Takashi@nims.go.jp, E-mail: TERABE.Kazuya@nims.go.jp; Aono, Masakazu [International Center for Materials Nanoarchitechtonics (WPI-MANA), National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan)

    2015-07-06

    An all-solid-state electric-double-layer transistor (EDLT) was fabricated for electrical modulation of the superconducting critical temperature (T{sub c}) of Nb film epitaxially grown on α-Al{sub 2}O{sub 3} (0001) single crystal. In an experiment, T{sub c} was modulated from 8.33 to 8.39 K while the gate voltage (V{sub G}) was varied from 2.5 to −2.5 V. The specific difference of T{sub c} for the applied V{sub G} was 12 mK/V, which is larger than that of an EDLT composed of ionic liquid. A T{sub c} enhancement of 300 mK was found at the Li{sub 4}SiO{sub 4}/Nb film interface and is attributed to an increase in density of states near the Fermi level due to lattice constant modulation. This solid electrolyte gating method should enable development of practical superconducting devices highly compatible with other electronic devices.

  7. Effects of type of nanosized carbon black on the performance of an all-solid-state potentiometric electrode for nitrate

    International Nuclear Information System (INIS)

    The potentiometric properties of all-solid-state nitrate-selective electrodes based on plasticised PVC and containing different types of nanosized carbon black were investigated. The use of a carbon black interlayer is shown to significantly improve the potentiometric response. The electrodes display a close-to-Nernstian slope in the range from 10−1 to 10−6 M, highly stable potentials and low membrane resistance. However, different analytical features were found depending on the type of carbon black used. The best long-term potential stability was observed for the electrode with Printex XE2-B carbon black that has a relatively high BET surface area (1000 m2 · g−1) and an average particle size of 30 nm. Nevertheless, the electrodes with the Vulcan XC-72 (BET surface: 240 m2 · g−1; average size: 55 nm) showed the most repeatable and reproducible standard potential. The lowest detection limit for nitrate (2.5·10−7 M) is observed for an electrode containing Vulcan XC-72. (author)

  8. All-solid-state flexible supercapacitors based on papers coated with carbon nanotubes and ionic-liquid-based gel electrolytes

    International Nuclear Information System (INIS)

    All-solid-state flexible supercapacitors were fabricated using carbon nanotubes (CNTs), regular office papers, and ionic-liquid-based gel electrolytes. Flexible electrodes were made by coating CNTs on office papers by a drop-dry method. The gel electrolyte was prepared by mixing fumed silica nanopowders with ionic liquid, 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ([EMIM][NTf2]). This supercapacitor showed high power and energy performance as a solid-state flexible supercapacitor. The specific capacitance of the CNT electrodes was 135 F g−1 at a current density of 2 A g−1, when considering the mass of active materials only. The maximum power and energy density of the supercapacitors were 164 kW kg−1 and 41 Wh kg−1, respectively. Interestingly, the solid-state supercapacitor with the gel electrolyte showed comparable performance to the supercapacitors with ionic-liquid electrolyte. Moreover, the supercapacitor showed excellent stability and flexibility. The CNT/paper- and gel-based supercapacitors may hold great potential for low-cost and high-performance flexible energy storage applications. (paper)

  9. Effect of Molecular Weight on Mechanical and Electrochemical Performance of All Solid-State Polymer Electrolyte Membranes

    Science.gov (United States)

    He, Ruixuan; Ward, Daniel; Echeverri, Mauricio; Kyu, Thein

    2015-03-01

    Guided by ternary phase diagrams of polyethylene glycol diacrylate (PEGDA), succinonitrile plasticizer, and LiTFSI salt, completely amorphous solid-state transparent polymer electrolyte membranes (ss-PEM) were fabricated by UV irradiation in the isotropic melt state. Effects of PEGDA molecular weight (700 vs 6000 g/mol) on ss-PEM performance were investigated. These amorphous PEMs have superionic room temperature ionic conductivity of ~10-3 S/cm, whereby PEGDA6000-PEM outperforms its PEGDA700 counterpart, which may be ascribed to lower crosslinking density and greater segmental mobility. The longer chain between crosslinked points of PEGDA6000-PEM is responsible for greater extensibility of ~80% versus ~7% of PEGDA700-PEM. Besides, both PEMs exhibited thermal stability up to 120 °C and electrochemical stability versus Li+/Li up to 4.7V. LiFePO4/PEM/Li and Li4Ti5O12 /PEM/Li half-cells exhibited stable cyclic behavior up to 50 cycles tested with a capacity of ~140mAh/g, suggesting that LiFePO4/PEM/Li4Ti5O12 may be a promising full-cell for all solid-state lithium battery. We thank NSF-DMR 1161070 for providing funding of this project.

  10. Optical rogue waves in an all-solid-state laser with a saturable absorber: importance of the spatial effects

    International Nuclear Information System (INIS)

    We study the features of the optical rogue waves (ORWs) observed in an all-solid-state (Cr:YAG+Nd:YVO4) passively-Q-switched laser, which is a system of wide practical interest. The extreme events appear as isolated pulses of extraordinary intensity during the chaotic regime of this laser. The standard theoretical description (three-level rate equations for a single mode of the field and a two-level system for the absorber) does predict the existence of many of the observed dynamical features, including chaos, but it fails to predict the existence of ORWs. Faced with the problem of improving the theoretical description, we find that ORWs are observed only when the Fresnel number of the laser cavity and the embedding dimension of the attractor reconstructed from the experimental time series are high, and the laser spot profile has a spatially complex structure. These results suggest that spatial effects are an essential ingredient in the formation of ORWs in this type of laser. (paper)

  11. Search for chameleon particles via photon regeneration

    Energy Technology Data Exchange (ETDEWEB)

    Chou, Aaron S.; /CCPP, New York U.

    2008-09-01

    We report the first results from the GammeV search for chameleon particles, which may be created via photon-photon interactions within a strong magnetic field. The chameleons are assumed to have matter effects sufficiently strong that they reflect from all solid surfaces of the apparatus, thus evading detection in our previous search for weakly-interacting axion-like particles. We implement a novel technique to create and trap the reflective particles within a jar and to detect them later via their afterglow as they slowly convert back into photons. These measurements provide the first experimental constraints on the couplings of chameleons to photons.

  12. An All-Solid-State, Room-Temperature, Heterodyne Receiver for Atmospheric Spectroscopy at 1.2 THz

    Science.gov (United States)

    Siles, Jose V.; Mehdi, Imran; Schlecht, Erich T.; Gulkis, Samuel; Chattopadhyay, Goutam; Lin, Robert H.; Lee, Choonsup; Gill, John J.; Thomas, Bertrand; Maestrini, Alain E.

    2013-01-01

    Heterodyne receivers at submillimeter wavelengths have played a major role in astrophysics as well as Earth and planetary remote sensing. All-solid-state heterodyne receivers using both MMIC (monolithic microwave integrated circuit) Schottky-diode-based LO (local oscillator) sources and mixers are uniquely suited for long-term planetary missions or Earth climate monitoring missions as they can operate for decades without the need for any active cryogenic cooling. However, the main concern in using Schottky-diode-based mixers at frequencies beyond 1 THz has been the lack of enough LO power to drive the devices because 1 to 3 mW are required to properly pump Schottky diode mixers. Recent progress in HEMT- (high-electron-mobility- transistor) based power amplifier technology, with output power levels in excess of 1 W recently demonstrated at W-band, as well as advances in MMIC Schottky diode circuit technology, have led to measured output powers up to 1.4 mW at 0.9 THz. Here the first room-temperature tunable, all-planar, Schottky-diode-based receiver is reported that is operating at 1.2 THz over a wide (˜20%) bandwidth. The receiver front-end (see figure) consists of a Schottky-diode-based 540 to 640 GHz multiplied LO chain (featuring a cascade of W-band power amplifiers providing around 120 to 180 mW at W-band), a 200-GHz MMIC frequency doubler, and a 600-GHz MMIC frequency tripler, plus a biasable 1.2-THz MMIC sub-harmonic Schottky-diode mixer. The LO chain has been designed, fabricated, and tested at JPL and provides around 1 to 1.5 mW at 540 o 640 GHz. The sub-harmonic mixer consists of two Schottky diodes on a thin GaAs membrane in an anti-parallel configuration. An integrated metal insulator metal (MIM) capacitor has been included on-chip to allow dc bias for the Schottky diodes. A bias voltage of around 0.5 V/diode is necessary to reduce the LO power required down to the 1 to 1.5 mW available from the LO chain. The epilayer thickness and doping profiles have

  13. All-solid-state potentiometric sensors for ascorbic acid by using a screen-printed compatible solid contact

    Energy Technology Data Exchange (ETDEWEB)

    Veltsistas, Panayotis G.; Prodromidis, Mamas I.; Efstathiou, Constantinos

    2004-01-23

    The development of all-solid-state potentiometric ion selective electrodes for monitoring of ascorbic acid, by using a screen-printed compatible solid contact is described. The applied methodology is based on the use of PVC membrane modified with some firstly-tested ionophores (triphenyltin(IV)chloride, triphenyltin(IV)hydroxide and palmitoyl-L-ascorbic acid) and a novel one synthesized in our laboratory (dibutyltin(IV) diascorbate). Synthesis protocol and some preliminary identification studies are given. A conductive graphite-based polymer thick film ink was used as an internal solid contact between the graphite electrode and the PVC membrane. The presence and the nature of the solid contact (plain or doped with lanthanum 2,6-dichlorophenolindophenol (DCPI)) seem to enhance the analytical performance of the electrodes in terms of sensitivity, dynamic range, and response time. The analytical performance of the constructed electrodes was evaluated with potentiometry, constant-current chronopotentiometry and electrochemical impedance spectroscopy (EIS). The interference effect of various compounds was also tested. The potential response of the optimized Ph{sub 3}SnCl-based electrode was linear against ascorbic acid concentration range 0.005-5.0 mM. The applicability of the proposed sensors in real samples was also tested. The detection limit was 0.002 mM ascorbic acid (50 mM phosphate, pH 5 in 50 mM KCl). The slope of the electrodes was super-Nernstian and pH dependent, indicating a mechanism involving a combination of charge transfer and ion exchange processes. Fabrication of screen-printed ascorbate ISEs has also been demonstrated.

  14. All-solid-state potentiometric sensors for ascorbic acid by using a screen-printed compatible solid contact

    International Nuclear Information System (INIS)

    The development of all-solid-state potentiometric ion selective electrodes for monitoring of ascorbic acid, by using a screen-printed compatible solid contact is described. The applied methodology is based on the use of PVC membrane modified with some firstly-tested ionophores (triphenyltin(IV)chloride, triphenyltin(IV)hydroxide and palmitoyl-L-ascorbic acid) and a novel one synthesized in our laboratory (dibutyltin(IV) diascorbate). Synthesis protocol and some preliminary identification studies are given. A conductive graphite-based polymer thick film ink was used as an internal solid contact between the graphite electrode and the PVC membrane. The presence and the nature of the solid contact (plain or doped with lanthanum 2,6-dichlorophenolindophenol (DCPI)) seem to enhance the analytical performance of the electrodes in terms of sensitivity, dynamic range, and response time. The analytical performance of the constructed electrodes was evaluated with potentiometry, constant-current chronopotentiometry and electrochemical impedance spectroscopy (EIS). The interference effect of various compounds was also tested. The potential response of the optimized Ph3SnCl-based electrode was linear against ascorbic acid concentration range 0.005-5.0 mM. The applicability of the proposed sensors in real samples was also tested. The detection limit was 0.002 mM ascorbic acid (50 mM phosphate, pH 5 in 50 mM KCl). The slope of the electrodes was super-Nernstian and pH dependent, indicating a mechanism involving a combination of charge transfer and ion exchange processes. Fabrication of screen-printed ascorbate ISEs has also been demonstrated

  15. Electrically Tunable Bandgaps in Bilayer MoS₂.

    Science.gov (United States)

    Chu, Tao; Ilatikhameneh, Hesameddin; Klimeck, Gerhard; Rahman, Rajib; Chen, Zhihong

    2015-12-01

    Artificial semiconductors with manufactured band structures have opened up many new applications in the field of optoelectronics. The emerging two-dimensional (2D) semiconductor materials, transition metal dichalcogenides (TMDs), cover a large range of bandgaps and have shown potential in high performance device applications. Interestingly, the ultrathin body and anisotropic material properties of the layered TMDs allow a wide range modification of their band structures by electric field, which is obviously desirable for many nanoelectronic and nanophotonic applications. Here, we demonstrate a continuous bandgap tuning in bilayer MoS2 using a dual-gated field-effect transistor (FET) and photoluminescence (PL) spectroscopy. Density functional theory (DFT) is employed to calculate the field dependent band structures, attributing the widely tunable bandgap to an interlayer direct bandgap transition. This unique electric field controlled spontaneous bandgap modulation approaching the limit of semiconductor-to-metal transition can open up a new field of not yet existing applications. PMID:26560813

  16. Low-temperature cross-talk magnetic-field sensor based on tapered all-solid waveguide-array fiber and magnetic fluids.

    Science.gov (United States)

    Miao, Yinping; Ma, Xixi; Wu, Jixuan; Song, Binbin; Zhang, Hao; Zhang, Kailiang; Liu, Bo; Yao, Jianquan

    2015-08-15

    A compact fiber-optic magnetic-field sensor based on tapered all-solid waveguide-array fiber (WAF) and magnetic fluid (MF) has been proposed and experimentally demonstrated. The tapered all-solid WAF is fabricated by using a fusion splicer, and the sensor is formed by immersing the tapered all-solid WAF into the MF. The transmission spectra have been measured and analyzed under different magnetic-field intensities. Experimental results show that the acquired magnetic-field sensitivity is 44.57 pm/Oe for a linear magnetic-field intensity range from 50 to 200 Oe. All-solid WAF has very similar thermal expansion coefficient for high- and low-refractive-index glasses, so mode profile is not affected by thermal drifts. Also, magnetically induced refractive-index changes into the ferrofluid are of the order of ∼5×10(-2), while the corresponding thermally induced refractive-index changes into the ferrofluid are expected to be lower. The temperature response has also been detected, and the temperature-induced wavelength shift perturbation is less than 0.3 nm from temperature of 26.9°C-44°C. The proposed magnetic-field sensor has such advantages as low temperature sensitivity, simple structure, and ease of fabrication. It also indicates that the magnetic-field sensor based on tapered all-solid WAF and MF is helpful to reduce temperature cross-sensitivity for the measurement of magnetic field. PMID:26274690

  17. Photonic band structure of two-dimensional metal/dielectric photonic crystals

    International Nuclear Information System (INIS)

    An improved plane wave expansion method for the numerical calculation of photonic bands of metal/dielectric photonic crystal (PC) are presented. This method is applied to two-dimensional PCs with frequency-dependent dielectric constants. We obtained the photonic band structure of three kinds of structures: sawtooth, cylinder and hole PCs. The results show that the lowest band-1 is relatively flat, and does not approach zero. Also, there is no complete band-gap that extends throughout the first Brillouin zone for these three structures. However, there are partial band-gaps in different directions in the first Brillouin zone. For the complementary cylinder and hole PCs, their photonic bands are similar except for the lowest three bands; the hole PC’s lowest frequency of band-1 is larger than that of cylinder PC for the configuration R/d  =  0.2. (paper)

  18. Bandgap engineering of GaN nanowires

    Science.gov (United States)

    Ming, Bang-Ming; Wang, Ru-Zhi; Yam, Chi-Yung; Xu, Li-Chun; Lau, Woon-Ming; Yan, Hui

    2016-05-01

    Bandgap engineering has been a powerful technique for manipulating the electronic and optical properties of semiconductors. In this work, a systematic investigation of the electronic properties of [0001] GaN nanowires was carried out using the density functional based tight-binding method (DFTB). We studied the effects of geometric structure and uniaxial strain on the electronic properties of GaN nanowires with diameters ranging from 0.8 to 10 nm. Our results show that the band gap of GaN nanowires depends linearly on both the surface to volume ratio (S/V) and tensile strain. The band gap of GaN nanowires increases linearly with S/V, while it decreases linearly with increasing tensile strain. These linear relationships provide an effect way in designing GaN nanowires for their applications in novel nano-devices.

  19. Wide bandgap materials in future electronic applications

    International Nuclear Information System (INIS)

    A brief overview of the impact that wide bandgap materials have, and will have in the future, on the development of (micro)electronic devices, circuits, and systems is presented. It is held that electronic control systems and thus their applications fall into three temperature domains, delineated by the maximum use temperature of the semiconductor systems with which they are equipped: the current low temperature (- 100 to 200 oC) domain dominated by silicon; a medium temperature range (200 - ∼600oC), in which GaN and AlN provide the transition to SiC; and a high temperature domain (600-1300 oC) not yet covered by any one material system and in which research and development of c-BN based composites can at first, as passives, enhance performance in all three temperature/application ranges. Current developments in most application areas are cost-not performance-driven. (author)

  20. 2-Photon tandem device for water splitting

    DEFF Research Database (Denmark)

    Seger, Brian; Castelli, Ivano Eligio; Vesborg, Peter Christian Kjærgaard;

    2014-01-01

    Within the field Of photocatalytic water splitting there are several strategies to achieve the goal of efficient and cheap photocatalytic water splitting. This work examines one particular strategy by focusing on monolithically stacked, two-photon photoelectrochemical cells. The overall aim of the...... properties. These results show that without protective layers there are scarcely any materials which seem viable as photoabsorbers whereas with protection layers there are significantly more candidates. Since the protection layer (and redox catalysts) on the light facing side should not interfere with light...... photocatalytic water splitting by using a large bandgap photocathode and a low bandgap photoanode with attached protection layers....

  1. Near-Infrared Sub-Bandgap All-Silicon Photodetectors: State of the Art and Perspectives

    Directory of Open Access Journals (Sweden)

    Luigi Sirleto

    2010-11-01

    Full Text Available Due to recent breakthroughs, silicon photonics is now the most active discipline within the field of integrated optics and, at the same time, a present reality with commercial products available on the market. Silicon photodiodes are excellent detectors at visible wavelengths, but the development of high-performance photodetectors on silicon CMOS platforms at wavelengths of interest for telecommunications has remained an imperative but unaccomplished task so far. In recent years, however, a number of near-infrared all-silicon photodetectors have been proposed and demonstrated for optical interconnect and power-monitoring applications. In this paper, a review of the state of the art is presented. Devices based on mid-bandgap absorption, surface-state absorption, internal photoemission absorption and two-photon absorption are reported, their working principles elucidated and their performance discussed and compared.

  2. Tunable fluorescence enhancement based on bandgap-adjustable 3D Fe3O4 nanoparticles

    Science.gov (United States)

    Hu, Fei; Gao, Suning; Zhu, Lili; Liao, Fan; Yang, Lulu; Shao, Mingwang

    2016-06-01

    Great progress has been made in fluorescence-based detection utilizing solid state enhanced substrates in recent years. However, it is still difficult to achieve reliable substrates with tunable enhancement factors. The present work shows liquid fluorescence enhanced substrates consisting of suspensions of Fe3O4 nanoparticles (NPs), which can assemble 3D photonic crystal under the external magnetic field. The photonic bandgap induced by the equilibrium of attractive magnetic force and repulsive electrostatic force between adjacent Fe3O4 NPs is utilized to enhance fluorescence intensity of dye molecules (including R6G, RB, Cy5, DMTPS-DCV) in a reversible and controllable manner. The results show that a maximum of 12.3-fold fluorescence enhancement is realized in the 3D Fe3O4 NP substrates without the utilization of metal particles for PCs/DMTPS-DCV (1.0 × 10‑7 M, water fraction (f w) = 90%).

  3. Feasibility of tunable MEMS photonic crystal devices

    International Nuclear Information System (INIS)

    Periodic photonic crystal structures channel electromagnetic waves much as semiconductors (quantum) wells channel electrons. Photonic bandgap crystals (PBC) are fabricated by arranging sub-wavelength alternating materials with high and low dielectric constants to produce a desired effective bandgap. Photons with energy within this bandgap cannot propagate through the structure. This property has made these structures useful for microwave applications such as frequency-selective surfaces, narrowband filters, and antenna substrates when the dimensions are on the order of millimeters. They are also potentially very useful, albeit much more difficult to fabricate, in the visible-near-infrared region for various applications when the smallest dimensions are at the edge of current micro-lithography fabrication tools. We micro-fabricated suspended free standing micro-structure bridge waveguides to serve as substrates for PBC features. These micro-bridges were fabricated onto commercial silicon-on-insulator wafers. Nanoscale periodic features were fabricated onto these micro-structure bridges to form a tunable system. When this combined structure is perturbed, such as mechanical deflection of the suspended composite structure at resonance, there can be a realtime shift in the material effective bandgap due to slight geometric alterations due to the induced mechanical stress. Extremely high resonance frequencies device speeds are possible with these very small dimension MEMS

  4. Bandgap engineering of InGaAsP/InP laser structure by photo-absorption-induced point defects

    Science.gov (United States)

    Kaleem, Mohammad; Nazir, Sajid; Saqib, Nazar Abbas

    2016-03-01

    Integration of photonic components on the same photonic wafer permits future optical communication systems to be dense and advanced performance. This enables very fast information handling between photonic active components interconnected through passive optical low loss channels. We demonstrate the UV-Laser based Quantum Well Intermixing (QWI) procedure to engineer the band-gap of compressively strained InGaAsP/InP Quantum Well (QW) laser material. We achieved around 135nm of blue-shift by simply applying excimer laser (λ= 248nm). The under observation laser processed material also exhibits higher photoluminescence (PL) intensity. Encouraging experimental results indicate that this simple technique has the potential to produce photonic integrated devices and circuits.

  5. Design for maximum band-gaps in beam structures

    DEFF Research Database (Denmark)

    Olhoff, Niels; Niu, Bin; Cheng, Gengdong

    2012-01-01

    This paper aims to extend earlier optimum design results for transversely vibrating Bernoulli-Euler beams by determining new optimum band-gap beam structures for (i) different combinations of classical boundary conditions, (ii) much larger values of the orders n and n-1 of adjacent upper and lower...... eigenfrequencies of maximized band-gaps, and (iii) different values of a minimum cross-sectional area constraint. The periodicity of the optimum beams and the attenuation of their band-gaps are also discussed....

  6. First Principles Study of Electrochemical and Chemical Stability of the Solid Electrolyte-Electrode Interfaces in All-Solid-State Li-Ion Batteries

    Science.gov (United States)

    Zhu, Yizhou; He, Xingfeng; Mo, Yifei

    All-solid-state Li-ion battery is a promising next-generation energy-storage technology. Using novel ceramic solid electrolyte materials, all-solid-state battery has advantages of intrinsic safety and high energy density compared to current Li-ion batteries based on organic liquid electrolyte. However, the power density achieved in all-solid-state battery is still unsatisfactory. The high interfacial resistance at electrode-electrolyte interface is one of the major limiting factors. Here we demonstrated a computational approach based on first principles calculation to systematically investigate the chemical and electrochemical stability of solid electrolyte materials, and provide insightful understanding of the degradation and passivation mechanisms at the interface. Our calculation revealed that the intrinsic stability of solid electrolyte materials and solid electrolyte-electrode interfaces is limited and the formation of interphase layers are thermodynamically favorable. Our study demonstrated a computational scheme to evaluate the electrochemical and chemical stability of the solid interfaces. Our newly gained understanding provided principles for developing solid electrolyte materials with enhanced stability and for engineering interfaces in all-solid-state Li-ion batteries. This work was supported by Office of Energy Efficiency and Renewable Energy (DE-EE0006860).

  7. PHOTON-PHOTON COLLISIONS

    OpenAIRE

    Burke, D.

    1982-01-01

    Studies of photon-photon collisions are reviewed with particular emphasis on new results reported to this conference. These include results on light meson spectroscopy and deep inelastic eγ scattering. Considerable work has now been accumulated on resonance production by γγ collisions. Preliminary high statistics studies of the photon structure function Fγ2(x,Q2) are given and comments are made on the problems that remain to be solved.

  8. Photon-photon colliders

    Energy Technology Data Exchange (ETDEWEB)

    Sessler, A.M.

    1995-04-01

    Since the seminal work by Ginsburg, et at., the subject of giving the Next Linear Collider photon-photon capability, as well as electron-positron capability, has drawn much attention. A 1990 article by V.I. Teinov describes the situation at that time. In March 1994, the first workshop on this subject was held. This report briefly reviews the physics that can be achieved through the photon-photon channel and then focuses on the means of achieving such a collider. Also reviewed is the spectrum of backscattered Compton photons -- the best way of obtaining photons. We emphasize the spectrum actually obtained in a collider with both polarized electrons and photons (peaked at high energy and very different from a Compton spectrum). Luminosity is estimated for the presently considered colliders, and interaction and conversion-point geometries are described. Also specified are laser requirements (such as wavelength, peak power, and average power) and the lasers that might be employed. These include conventional and free-electron lasers. Finally, we describe the R&D necessary to make either of these approaches viable and explore the use of the SLC as a test bed for a photon-photon collider of very high energy.

  9. Photon-photon colliders

    International Nuclear Information System (INIS)

    Since the seminal work by Ginsburg, et at., the subject of giving the Next Linear Collider photon-photon capability, as well as electron-positron capability, has drawn much attention. A 1990 article by V.I. Teinov describes the situation at that time. In March 1994, the first workshop on this subject was held. This report briefly reviews the physics that can be achieved through the photon-photon channel and then focuses on the means of achieving such a collider. Also reviewed is the spectrum of backscattered Compton photons -- the best way of obtaining photons. We emphasize the spectrum actually obtained in a collider with both polarized electrons and photons (peaked at high energy and very different from a Compton spectrum). Luminosity is estimated for the presently considered colliders, and interaction and conversion-point geometries are described. Also specified are laser requirements (such as wavelength, peak power, and average power) and the lasers that might be employed. These include conventional and free-electron lasers. Finally, we describe the R ampersand D necessary to make either of these approaches viable and explore the use of the SLC as a test bed for a photon-photon collider of very high energy

  10. Towards self-similar propagation in a dispersion tailored and highly nonlinear segmented bandgap fiber at 2.8 micron

    CERN Document Server

    Biswas, Piyali; Biswas, Abhijit; Pal, Bishnu P

    2016-01-01

    We numerically demonstrate self-similar propagation of parabolic optical pulses through a highly nonlinear and passive specialty photonic bandgap fiber at 2.8 micron. In this context, we have proposed a scheme endowed with a rapidly varying, but of nearly-mean-zero longitudinal dispersion and modulated nonlinear profile in order to achieve self-similarity of the formed parabolic pulse propagating over longer distances. To implement the proposed scheme, we have designed a segmented bandgap fiber with suitably tapered counterparts to realize such customized dispersion with chalchogenide glass materials. A self-similar parabolic pulse with full-width-at-half-maxima of 4.12 ps and energy of ~ 39 pJ as been achieved at the output. Along with a linear chirp spanning over the entire pulse duration, 3dB spectral broadening of about 38 nm at the output has been reported.

  11. High Power Wide Bandgap Engineered MMW MMIC Transceiver Project

    Data.gov (United States)

    National Aeronautics and Space Administration — During this phase I SBIR effort unique proven lattice and bandgap engineering techniques will be utilized to epitaxially grow InAlAs / InGaAs on GaN substrate for...

  12. Bandgap tuning in armchair MoS2 nanoribbon

    Science.gov (United States)

    Yue, Qu; Chang, Shengli; Kang, Jun; Zhang, Xueao; Shao, Zhengzheng; Qin, Shiqiao; Li, Jingbo

    2012-08-01

    We report on the first-principles calculations of bandgap modulation in armchair MoS2 nanoribbon (AMoS2NR) by transverse and perpendicular electric fields respectively. In the monolayer AMoS2NR case, it is shown that the bandgap can be significantly reduced and be closed by transverse field, whereas the bandgap modulation is absent under perpendicular field. The critical strength of transverse field for gap closure decreases as ribbon width increases. In the multilayer AMoS2NR case, in contrast, it is shown that the bandgap can be effectively reduced by both transverse and perpendicular fields. Nevertheless, it seems that the two fields exhibit different modulation effects on the gap. The critical strength of perpendicular field for gap closure decreases with increasing number of layers, while the critical strength of transverse field is almost independent of it.

  13. CMOS bandgap references and temperature sensors and their applications

    OpenAIRE

    Wang, G.

    2005-01-01

    Two main parts have been presented in this thesis: device characterization and circuit. In integrated bandgap references and temperature sensors, the IC(VBE, characteristics of bipolar transistors are used to generate the basic signals with high accuracy. To investigate the possibilities to fabricate high-precision bandgap references and temperature sensors in low-cost CMOS technology, the electrical characteristics of substrate bipolar pnp transistors have been investigated over a wide tempe...

  14. Local resonance bandgaps in periodic media: theory and experiment.

    Science.gov (United States)

    Raghavan, L; Phani, A Srikantha

    2013-09-01

    Periodic composites such as acoustic metamaterials use local resonance phenomenon in designing low frequency sub-Bragg bandgaps. These bandgaps emerge from a resonant scattering interaction between a propagating wave and periodically arranged resonators. This paper develops a receptance coupling technique to combine the dynamics of the resonator with the unit cell dynamics of the background medium to analyze flexural wave transmission in a periodic structure, involving a single degree of freedom coupling between the medium and the resonator. Receptance techniques allow for a straightforward extension to higher dimensional systems with multiple degrees of freedom coupling and for easier experimental measurements. Closed-form expressions for the location and width of sub-Bragg bandgaps are obtained. Rigid body modes of the unit cell of the background medium are shown to set the bounding frequencies for local resonance bandgaps. Results from the receptance analysis compare well with Bloch wave analysis and experiments performed on a finite structural beam with periodic masses and resonators. Stronger coupling and inertia of the resonator increase the local resonance bandgap width. Two-fold periodicity widens the Bragg bandgap, narrowed by local resonators, thus expanding the design space and highlighting the advantages of hierarchical periodicity. PMID:23967928

  15. Multi-analyte biochip (MAB) based on all-solid-state ion-selective electrodes (ASSISE) for physiological research.

    Science.gov (United States)

    Wan Salim, Wan W Amani; Zeitchek, Michael A; Hermann, Andrew C; Ricco, Antonio J; Tan, Ming; Selch, Florian; Fleming, Erich; Bebout, Brad M; Bader, Mamoun M; Ul Haque, Aeraj; Porterfield, D Marshall

    2013-01-01

    Lab-on-a-chip (LOC) applications in environmental, biomedical, agricultural, biological, and spaceflight research require an ion-selective electrode (ISE) that can withstand prolonged storage in complex biological media (1-4). An all-solid-state ion-selective-electrode (ASSISE) is especially attractive for the aforementioned applications. The electrode should have the following favorable characteristics: easy construction, low maintenance, and (potential for) miniaturization, allowing for batch processing. A microfabricated ASSISE intended for quantifying H(+), Ca(2+), and CO3(2-) ions was constructed. It consists of a noble-metal electrode layer (i.e. Pt), a transduction layer, and an ion-selective membrane (ISM) layer. The transduction layer functions to transduce the concentration-dependent chemical potential of the ion-selective membrane into a measurable electrical signal. The lifetime of an ASSISE is found to depend on maintaining the potential at the conductive layer/membrane interface (5-7). To extend the ASSISE working lifetime and thereby maintain stable potentials at the interfacial layers, we utilized the conductive polymer (CP) poly(3,4-ethylenedioxythiophene) (PEDOT) (7-9) in place of silver/silver chloride (Ag/AgCl) as the transducer layer. We constructed the ASSISE in a lab-on-a-chip format, which we called the multi-analyte biochip (MAB) (Figure 1). Calibrations in test solutions demonstrated that the MAB can monitor pH (operational range pH 4-9), CO3(2-) (measured range 0.01 mM - 1 mM), and Ca(2+) (log-linear range 0.01 mM to 1 mM). The MAB for pH provides a near-Nernstian slope response after almost one month storage in algal medium. The carbonate biochips show a potentiometric profile similar to that of a conventional ion-selective electrode. Physiological measurements were employed to monitor biological activity of the model system, the microalga Chlorella vulgaris. The MAB conveys an advantage in size, versatility, and multiplexed analyte

  16. Nonlocal hyperconcentration on entangled photons using photonic module system

    Science.gov (United States)

    Cao, Cong; Wang, Tie-Jun; Mi, Si-Chen; Zhang, Ru; Wang, Chuan

    2016-06-01

    Entanglement distribution will inevitably be affected by the channel and environment noise. Thus distillation of maximal entanglement nonlocally becomes a crucial goal in quantum information. Here we illustrate that maximal hyperentanglement on nonlocal photons could be distilled using the photonic module and cavity quantum electrodynamics, where the photons are simultaneously entangled in polarization and spatial-mode degrees of freedom. The construction of the photonic module in a photonic band-gap structure is presented, and the operation of the module is utilized to implement the photonic nondestructive parity checks on the two degrees of freedom. We first propose a hyperconcentration protocol using two identical partially hyperentangled initial states with unknown coefficients to distill a maximally hyperentangled state probabilistically, and further propose a protocol by the assistance of an ancillary single photon prepared according to the known coefficients of the initial state. In the two protocols, the total success probability can be improved greatly by introducing the iteration mechanism, and only one of the remote parties is required to perform the parity checks in each round of iteration. Estimates on the system requirements and recent experimental results indicate that our proposal is realizable with existing or near-further technologies.

  17. Photon-photon collisions

    International Nuclear Information System (INIS)

    Highlights of the VIIIth International Workshop on Photon-Photon Collisions are reviewed. New experimental and theoretical results were reported in virtually every area of γγ physics, particularly in exotic resonance production and tests of quantum chromodynamics where asymptotic freedom and factorization theorems provide predictions for both inclusive and exclusive γγ reactions at high momentum transfer. 73 refs., 12 figs

  18. Photon-photon colliders

    Energy Technology Data Exchange (ETDEWEB)

    Sessler, Andrew M.

    1996-01-01

    Since the seminal work by Ginsburg, et al., the subject of giving the Next Linear Collider photon-photon capability, as well as electron-positron capability, has drawn much attention [1]. A 1990 article by V.I. Telnov describes the situation at that time [2]. In March 1994, the first workshop on this subject was held [3]. This report briefly reviews the physics that can be achieved through the photon-photon channel and then focuses on the means of achieving such a collider. Also reviewed is the spectrum of backscattered Compton photons—the best way of obtaining photons. We emphasize the spectrum actually obtained in a collider with both polarized electrons and photons (peaked at high energy and very different from a Compton spectrum). Luminosity is estimated for the presently considered colliders, and interaction and conversion-point geometries are described. Also specified are laser requirements (such as wavelength, peak power, and average power) and the lasers that might be employed. These include conventional and free-electron lasers. Finally, we describe the R&D necessary to make either of these approaches viable and explore the use of the SLC as a test bed for a photon-photon collider of very high energy.

  19. On the Suppression Band and Bandgap of Planar Electromagnetic Bandgap Structures

    Directory of Open Access Journals (Sweden)

    Baharak Mohajer-Iravani

    2014-01-01

    Full Text Available Electromagnetic bandgap structures are considered a viable solution for the problem of switching noise in printed circuit boards and packages. Less attention, however, has been given to whether or not the introduction of EBGs affects the EMI potential of the circuit to couple unwanted energy to neighboring layers or interconnects. In this paper, we show that the bandgap of EBG structures, as generated using the Brillouin diagram, does not necessarily correspond to the suppression bandwidth typically generated using S-parameters. We show that the reactive near fields radiating from openings within the EBG layers can be substantial and are present in the entire frequency band including propagating and nonpropagating mode regions. These fields decay fast with distance; however, they can couple significant energy to adjacent layers and to signal lines. The findings are validated using full-wave three-dimensional numerical simulation. Based on this work, design guidelines for EBG structures can be drawn to insure not only suppression of switching noise but also minimization of EMI and insuring signal integrity.

  20. Next Generation Solar Cells Based on Graded Bandgap Device Structures Utilising Rod-Type Nano-Materials

    Directory of Open Access Journals (Sweden)

    Imyhamy M. Dharmadasa

    2015-06-01

    Full Text Available Current solar cells under research and development utilise mainly one absorber layer limiting the photon harvesting capabilities. In order to develop next generation solar cells, research should move towards effective photon harvesting methods utilising low-cost solar energy materials. This will lead to reduce the $W−1 figure for direct solar energy conversion to electrical energy. In this work, a graded bandgap solar cell has been designed to absorb all photons from the UV, visible and IR regions. In addition, impurity PV effect and impact ionisation have been incorporated to enhance charge carrier creation within the same device. This new design has been experimentally tested using the most researched MOCVD grown GaAs/AlGaAs system, in order to confirm its validity. Devices with high Voc ~ 1175 mV and the highest possible FF ~ (0.85–0.87 have been produced, increasing the conversion efficiency to ~20% within only two growth runs. These devices were also experimentally tested for the existence of impurity PV effect and impact ionisation. The devices are PV active in complete darkness producing over 800 mV, Voc indicating the harvesting of IR radiation from the surroundings through impurity PV effect. The quantum efficiency measurements show over 140% signal confirming the contribution to PV action from impact ionisation. Since the concept is successfully proven, the low-cost and scalable electrodeposited semiconducting layers are used to produce graded bandgap solar cell structures. The utilisation of nano- and micro-rod type materials in graded bandgap devices are also presented and discussed in this paper. Preliminary work on glass/FTO/n-ZnS/n-CdS/n-CdTe/Au graded bandgap devices show 10%–12% efficient devices indicating extremely high Jsc values ~48 mA·cm−2, showing the high potential of these devices in achieving higher efficiencies. The detailed results on these low-cost and novel graded bandgap devices are presented in a separate

  1. All-Solid-Thin Film Electrochromic Devices Consisting of Layers ITO / NiO / ZrO2 / WO3 / ITO

    Directory of Open Access Journals (Sweden)

    K.J. Patel

    2013-05-01

    Full Text Available We have prepared an all-solid-thin film electrochromic device (ECD, consisting of layers ITO / NiO / ZrO2 / WO3 / ITO using the PVD method. The WO3 is used as an electrochromic layer, NiO as an ion-storage layer, and ZrO2 as a solid electrolyte layer in the all-solid-thin film ECD. The optical transmittance varied between 3-59 %. The device shows the coloration and bleaching time of 120 s and 2 s, respectively, with a good memory effect and desirable cycle-life.

  2. Characteristics of rapid-thermal-annealed LiNi1-xCoxO2 cathode films for all-solid-state rechargeable thin film microbatteries

    International Nuclear Information System (INIS)

    We report on the characteristics of rapid-thermal-annealed LiNi1-xCoxO2 cathode films for all-solid-state thin film microbatteries (TFBs). Scanning electron microscopy, atomic force microscopy, X-ray photoelectron spectroscopy and Auger electron spectroscopy results show that the surface oxide layer formed on the as-deposited LiNi1-xCoxO2 film is completely removed by a rapid thermal annealing process. All-solid-state TFBs consisting of Li/LiPON/LiNi1-xCoxO2/Pt/MgO/Si exhibit stable cyclibility and a high specific discharge capacity of 60.2 μAh/cm2 μm. It is concluded that the LiyNi1-xCoxO2 cathode could represent a promising candidate for a cathode film in TFBs

  3. Toward ambient temperature operation with all-solid-state lithium metal batteries with a sp3 boron-based solid single ion conducting polymer electrolyte

    Science.gov (United States)

    Zhang, Yunfeng; Cai, Weiwei; Rohan, Rupesh; Pan, Meize; Liu, Yuan; Liu, Xupo; Li, Cuicui; Sun, Yubao; Cheng, Hansong

    2016-02-01

    The ionic conductivity decay problem of poly(ethylene oxide) (PEO)-based solid polymer electrolytes (SPEs) when increase the lithium salt of the SPEs up to high concentration is here functionally overcome by the incorporation of a charge delocalized sp3 boron based single ion conducting polymer electrolyte (SIPE) with poly(ethylene oxide) to fabricate solid-state sp3 boron based SIPE membranes (S-BSMs). By characterizations, particularly differential scanning calorimeter (DSC) and ionic conductivity studies, the fabricated S-BSMs showed decreased melting points and increased ionic conductivity as steadily increase the content of sp3 boron based SIPE, which significantly improved the low temperature performance of the all-solid-state lithium batteries. The fabricated Li | S-BSMs | LiFePO4 cells exhibit highly electrochemical stability and excellent cycling at temperature below melting point of PEO, which has never been reported so far for SIPEs based all-solid-state lithium batteries.

  4. Preparation of hydroxide ion conductive KOH–layered double hydroxide electrolytes for an all-solid-state iron–air secondary battery

    Directory of Open Access Journals (Sweden)

    Taku Tsuneishi

    2014-06-01

    Full Text Available Anion conductive solid electrolytes based on Mg–Al layered double hydroxide (LDH were prepared for application in an all-solid-state Fe–air battery. The ionic conductivity and the conducting ion species were evaluated from impedance and electromotive force measurements. The ion conductivity of LDH was markedly enhanced upon addition of KOH. The electromotive force in a water vapor concentration cell was similar to that of an anion-conducting polymer membrane. The KOH–LDH obtained was used as a hydroxide ion conductive electrolyte for all-solid-state Fe–air batteries. The cell performance of the Fe–air batteries was examined using a mixture of KOH–LDH and iron-oxide-supported carbon as the negative electrode.

  5. An Integrated Glucose Sensor with an All-Solid-State Sodium Ion-Selective Electrode for a Minimally Invasive Glucose Monitoring System

    OpenAIRE

    Junko Kojima; Samiko Hosoya; Chihiro Suminaka; Nobuyasu Hori; Toshiyuki Sato

    2015-01-01

    We developed a minimally invasive glucose monitoring system that uses a microneedle to permeate the skin surface and a small hydrogel to accumulate interstitial fluid glucose. The measurement of glucose and sodium ion levels in the hydrogel is required for estimating glucose levels in blood; therefore, we developed a small, enzyme-fixed glucose sensor with a high-selectivity, all-solid-state, sodium ion-selective electrode (ISE) integrated into its design. The glucose sensor immobilized gluco...

  6. NiCo2O4@TiN Core-shell Electrodes through Conformal Atomic Layer Deposition for All-solid-state Supercapacitors

    KAUST Repository

    Wang, Ruiqi

    2016-03-04

    Ternary transition metal oxides such as NiCo2O4 show great promise as supercapacitor electrode materials. However, the unsatisfactory rate performance of NiCo2O4 may prove to be a major hurdle to its commercial usage. Herein, we report the development of NiCo2O4@TiN core–shell nanostructures for all-solid-state supercapacitors with significantly enhanced rate capability. We demonstrate that a thin layer of TiN conformally grown by atomic layer deposition (ALD) on NiCo2O4 nanofiber arrays plays a key role in improving their electrical conductivity, mechanical stability, and rate performance. Fabricated using the hybrid NiCo2O4@TiN electrodes, the symmetric all-solid-state supercapacitor exhibited an impressive stack power density of 58.205 mW cm−3 at a stack energy density of 0.061 mWh cm−3. To the best of our knowledge, these values are the highest of any NiCo2O4-based all-solid-state supercapacitor reported. Additionally, the resulting NiCo2O4@TiN all-solid-state device displayed outstanding cycling stability by retaining 70% of its original capacitance after 20,000 cycles at a high current density of 10 mA cm−2. These results illustrate the promise of ALD-assisted hybrid NiCo2O4@TiN electrodes for sustainable and integrated energy storage applications.

  7. Preparation of hydroxide ion conductive KOH–layered double hydroxide electrolytes for an all-solid-state iron–air secondary battery

    OpenAIRE

    Taku Tsuneishi; Hisatoshi Sakamoto; Kazushi Hayashi; Go Kawamura; Hiroyuki Muto; Atsunori Matsuda

    2014-01-01

    Anion conductive solid electrolytes based on Mg–Al layered double hydroxide (LDH) were prepared for application in an all-solid-state Fe–air battery. The ionic conductivity and the conducting ion species were evaluated from impedance and electromotive force measurements. The ion conductivity of LDH was markedly enhanced upon addition of KOH. The electromotive force in a water vapor concentration cell was similar to that of an anion-conducting polymer membrane. The KOH–LDH obtained was used as...

  8. Electronic band-gap modified passive silicon optical modulator at telecommunications wavelengths.

    Science.gov (United States)

    Zhang, Rui; Yu, Haohai; Zhang, Huaijin; Liu, Xiangdong; Lu, Qingming; Wang, Jiyang

    2015-01-01

    The silicon optical modulator is considered to be the workhorse of a revolution in communications. In recent years, the capabilities of externally driven active silicon optical modulators have dramatically improved. Self-driven passive modulators, especially passive silicon modulators, possess advantages in compactness, integration, low-cost, etc. Constrained by a large indirect band-gap and sensitivity-related loss, the passive silicon optical modulator is scarce and has been not advancing, especially at telecommunications wavelengths. Here, a passive silicon optical modulator is fabricated by introducing an impurity band in the electronic band-gap, and its nonlinear optics and applications in the telecommunications-wavelength lasers are investigated. The saturable absorption properties at the wavelength of 1.55 μm was measured and indicates that the sample is quite sensitive to light intensity and has negligible absorption loss. With a passive silicon modulator, pulsed lasers were constructed at wavelengths at 1.34 and 1.42 μm. It is concluded that the sensitive self-driven passive silicon optical modulator is a viable candidate for photonics applications out to 2.5 μm. PMID:26563679

  9. All-solid, flexible solar textiles based on dye-sensitized solar cells with ZnO nanorod arrays on stainless steel wires

    International Nuclear Information System (INIS)

    Highlights: • All-solid, flexible solar textile fabricated with DSSCs is demonstrated. • DSSCs woven into a satin structure and transparent PET film are used. • Solar textile showed a high efficiency of 2.57%. -- Abstract: An all-solid, flexible solar textile fabricated with dye-sensitized solar cells (DSSCs) woven into a satin structure and transparent poly(ethylene terephthalate) (PET) film was demonstrated. A ZnO nanorod (NR) vertically grown from fiber-type conductive stainless steel (SS) wire was utilized as a photoelectrode, and a Pt-coated SS wire was used as a counter electrode. A graft copolymer, i.e. poly(vinyl chloride)-graft-poly(oxyethylene methacrylate) (PVC-g-POEM) was synthesized via atom transfer radical polymerization (ATRP) and used as a solid electrolyte. The conditions for the growth of ZnO NR and sufficient dye loading were investigated to improve cell performance. The adhesion of PET films to DSSCs resulted in physical stability improvements without cell performance loss. The solar textile with 10 × 10 wires exhibited an energy conversion efficiency of 2.57% with a short circuit current density of 20.2 mA/cm2 at 100 mW/cm2 illumination, which is the greatest account of an all-solid, ZnO-based flexible solar textile. DSSC textiles with woven structures are applicable to large-area, roll-to-roll processes

  10. All-solid-state electrochemical capacitors using MnO2 electrode/SiO2-Nafion electrolyte composite prepared by the sol-gel process

    Science.gov (United States)

    Shimamoto, Kazushi; Tadanaga, Kiyoharu; Tatsumisago, Masahiro

    2014-02-01

    Electrode-electrolyte composites of MnO2 active material, acetylene black (AB), and SiO2-Nafion solid electrolyte were prepared using the sol-gel process to form good solid-solid interfaces. The composites were obtained by the addition of MnO2 and AB into a sol of hydrolyzed tetraethoxysilane with Nafion, and successive solidification of the precursor sol. Scanning electron microscope and energy dispersive X-ray spectroscopy measurements show that good solid-solid interface is formed between electrodes and solid electrolytes in the composites. All-solid-state hybrid capacitors were fabricated using the composites or the hand-grinding mixture of MnO2, AB and SiO2-Nafion powder as positive electrodes, activated carbon powder as a negative electrode, and phosphosilicate gel as a solid electrolyte. The all-solid-state hybrid capacitors using the composites exhibit larger capacitances and better rate performance than the capacitors using the electrode prepared by hand-mixing of powders. Specific discharge capacitances of the capacitor with the composite are 85 F g-1 for the one with the composite electrode and 48 F g-1 for the one with the hand-mixed electrode, at 1 mA cm-2. Moreover, the all-solid-state capacitors using the composite electrode can be operated at temperatures between -30 °C and 60 °C.

  11. Large-bandwidth planar photonic crystal waveguides

    DEFF Research Database (Denmark)

    Søndergaard, Thomas; Lavrinenko, Andrei

    defect has appropriate dispersion properties relative to the photonic crystal slab material surrounding the line defect. A three-dimensional theoretical analysis is given for large-bandwidth waveguide designs based on a silicon-air photonic crystal slab suspended in air. In one example, the leakage......A general design principle is presented for making finite-height photonic crystal waveguides that support leakage-free guidance of light over large frequency intervals. The large bandwidth waveguides are designed by introducing line defects in photonic crystal slabs, where the material in the line......-free single-mode guidance is found for a large frequency interval covering 60% of the photonic band-gap....

  12. Integrated photonic crystal selective emitter for thermophotovoltaics

    Science.gov (United States)

    Zhou, Zhiguang; Yehia, Omar; Bermel, Peter

    2016-01-01

    Converting blackbody thermal radiation to electricity via thermophotovoltaics (TPV) is inherently inefficient. Photon recycling using cold-side filters offers potentially improved performance but requires extremely close spacing between the thermal emitter and the receiver, namely a high view factor. Here, we propose an alternative approach for thermal energy conversion, the use of an integrated photonic crystal selective emitter (IPSE), which combines two-dimensional photonic crystal selective emitters and filters into a single device. Finite difference time domain and current transport simulations show that IPSEs can significantly suppress sub-bandgap photons. This increases heat-to-electricity conversion for photonic crystal based emitters from 35.2 up to 41.8% at 1573 K for a GaSb photovoltaic (PV) diode with matched bandgaps of 0.7 eV. The physical basis of this enhancement is a shift from a perturbative to a nonperturbative regime, which maximized photon recycling. Furthermore, combining IPSEs with nonconductive optical waveguides eliminates a key difficulty associated with TPV: the need for precise alignment between the hot selective emitter and cool PV diode. The physical effects of both the IPSE and waveguide can be quantified in terms of an extension of the concept of an effective view factor.

  13. Photon management with index-near-zero materials

    Science.gov (United States)

    Wang, Zhu; Wang, Ziyu; Yu, Zongfu

    2016-08-01

    Index-near-zero materials can be used for effective photon management. They help to restrict the angle of acceptance, resulting in greatly enhanced light trapping limit. In addition, these materials also decrease the radiative recombination, leading to enhanced open circuit voltage and energy efficiency in direct bandgap solar cells.

  14. Phosphorene nanoribbons: Passivation effect on bandgap and effective mass

    International Nuclear Information System (INIS)

    Highlights: • Hydrogenation and fluorination can passivate the metallic edge states of zPNRs. • The bandgap of each type of zPNRs decreases as the ribbon's width increases duo to the quantum confinement effect. • Two local configurations of passivated atoms can coexist in nanoribbons and affect the bandgap of narrow nanoribbons. • New passivation configuration can effectively reduce the effective mass of electrons. - Abstract: The edge passivation effect of phosphorene nanoribbons is systematically investigated using density functional theory. Hydrogen and fluorine atoms passivate the metallic edge states of nanoribbons and can open a bandgap up to 2.25 eV. The two configurations of passivated atoms can exist at two edges and affect the bandgap of narrow nanoribbons. The bandgap of each type of zPNRs decreases as the ribbon's width increases, which can be attributed to the quantum confinement effect. The new configuration, named Cb, can effectively reduce the effective mass of electrons, which benefits the future design of phosphorene-based electronic devices

  15. Quantum well effect based on hybridization bandgap in deep subwavelength coupled meta-atoms

    Science.gov (United States)

    Chen, Yongqiang; Li, Yunhui; Wu, Qian; Jiang, Haitao; Zhang, Yewen; Chen, Hong

    2015-09-01

    In this paper, quantum well (QW) effect in a hybridization bandgap (HBG) structure via hiring deep subwavelength coupled meta-atoms is investigated. Subwavelength zero-index-metamaterial-based resonators acting as meta-atoms are side-coupled to a microstrip, forming the HBG structure. Both numerical and microwave experimental results confirm that, through properly hiring another set of meta-atoms, band mismatch between two HBGs can be introduced resulting in the HBG QW effect. Compared with the conventional QW structure based on Bragg interferences in photonic crystal, the device length of the proposed HBG QW structure can be reduced to only 1/4, demonstrating well the deep subwavelength property. Therefore, the above features make our design of HBG QW structures suitable to be utilized as multi-channel filters or multiplexers in microwave and optical communication system.

  16. Three-dimensional photonic crystals fabricated by simultaneous multidirectional etching

    Science.gov (United States)

    Kitano, Keisuke; Suzuki, Katsuyoshi; Ishizaki, Kenji; Noda, Susumu

    2015-04-01

    We discuss three-dimensional (3D) photonic crystals fabricated by simultaneous multidirectional plasma etching. First, we investigate a method for controlling the ion sheath used in reactive ion etching for obtaining multidirectional etching. We then discuss the fabrication tolerance from an analytical perspective. Based on our results, we demonstrate the fabrication of 3D photonic crystals with thicknesses of 1, 1.5, and 2 lattice periods in the surface-normal direction on single-crystalline silicon wafers, which show high reflectance (˜100 %) and low transmittance (-17 dB ) at optical communication wavelengths, suggesting the formation of a complete photonic band gap. We reveal that the shape of the etched holes limits the performance of 3D photonic crystals and suggest possible ways to improve the band-gap effect. Moreover, we show that 3D photonic crystals with short lattice constants show high reflectance (˜80 %) at visible to near-infrared wavelengths. By investigating the influence of absorption on the characteristics of 3D photonic crystals, we reveal that the reflectance remains as high as 94% in the photonic band-gap range even when the absorption of silicon is taken into account. We find that a unique increase of absorption occurs at several discrete wavelengths below the photonic band gap, suggesting the possibility of manipulating light absorption. These results not only simplify the fabrication of 3D photonic crystals, but also provide a basis for realizing 3D photonic nanostructures that include other materials.

  17. Low temperature insertion of energy levels into the ZnO nanorod's bandgap by nanotube conversion

    International Nuclear Information System (INIS)

    Finding a material for complete absorption and emission of the visible range of the electromagnetic spectrum has been always a challenge for optoelectronic research groups. One dimensional zinc oxide (ZnO) nanostructures with wide bandgaps have been proposed as candidates to solve this problem. We have developed, characterized and optimized an approach to create a very high level of intentional defects or surface states to fill ZnO nanorods bandgap energy diagram. This process was performed systematically at a low temperature with high throughput on the hexagonal ZnO nanorods. These nanorods were 2.5 μm in length and grown with chemical bath deposition. The best conversion process occurred in a 2 M KCl solution at 90 °C for 5 h. ZnO nanotubes have presented a reasonably high performance photon collection and emission. - Highlights: • Large arrays of highly oriented ZnO nanotubes have been fabricated and characterized. • Very high intentional level of defects was introduced to the nanorods. • The conversion of nanorods to nanotubes must be monitored all the way to the end. • Long conversion decreased the number of surface levels in the ZnO's bandgap

  18. Linear and Nonlinear Wave Dynamics in Amorphous Photonic Lattices

    Science.gov (United States)

    Rechtsman, Mikael; Szameit, Alexander; Segev, Mordechai

    Conventional intuition in solid-state physics holds that in order for a solid to have an electronic band-gap, it must be periodic, allowing the use of Bloch's theorem. Indeed, the free-electron approximation seems to imply that Bragg scattering in periodic potentials is a necessary condition for the formation of a band-gap. But this is obviously untrue: looking through a window reveals that glassy silica (SiO2), although possessing no order at all, still displays a band-gap spanning the entire photon energy range of visible light, without absorption. Several experimental studies have probed the properties of the band-gap in such "amorphous" electronic systems using spectroscopic techniques [1], time-of-flight measurements [2], and others. With the major progress in photonic crystals [3, 4], it is natural to explore amorphous photonic structures with band-gaps, where the actual wavefunction can be observed directly, and hence, many physical issues can be studied at an unprecedented level. Indeed, amorphous photonic media have been studied theoretically in several pioneering papers (e.g., [5, 6]), and experiments in the microwave regime have demonstrated the existence of a band-gap [5]. However, amorphous band-gap media have never been studied experimentally in the optical regime. Particularly in optics, the full beauty of disorder can be revealed: optics offers the possibility to precisely engineer the potential strength and period, as well as the unique opportunity to employ nonlinearity under controlled conditions, which could unravel unknown features that are much harder to access experimentally in other systems. Here, we present the first experimental study of amorphous photonic lattices: a two-dimensional array of randomly organized evanescently coupled waveguides. We demonstrate that the bands in this medium, comprising inherently localized Anderson states, are separated by gaps, despite the total lack of Bragg scattering. We find that amorphous photonic

  19. The role of spin exchange in charge transfer in low-bandgap polymer: Fullerene bulk heterojunctions

    International Nuclear Information System (INIS)

    Formation, relaxation and dynamics of polarons and methanofullerene anion radicals photoinitiated in poly[N-9″-hepta-decanyl-2,7-carbazole-alt-5,5-(4′,7′-di-2-thienyl-2′,1′, 3′-benzothiadiazole)]:-[6,6]-phenyl-C61-butyric acid methyl ester (PCDTBT:PC61BM) bulk heterojunctions were studied mainly by light-induced EPR (LEPR) spectroscopy in wide photon energy and temperature ranges. Some polarons are pinned by spin traps whose number and depth are governed by the composite morphology and photon energy. The proximity of the photon energy and the polymer bandgap reduces the number of such traps, inhibits recombination of mobile charge carriers, and facilitates their mobility in polymer network. Spin relaxation and charge carrier dynamics were studied by the steady-state saturation method at wide range of temperature and photon energy. These processes were shown to be governed by spin exchange as well as by the photon energy. Charge transfer in the composite is governed by the polaron scattering on the lattice phonons of crystalline domains embedded into amorphous polymer matrix and its activation hopping between polymer layers. The energy barrier required for polaron interchain hopping exceeds that of its intrachain diffusion. Anisotropy of polaron dynamics in the PCDTBT:PC61BM composite is less than that of poly(3-alkylthiophenes)-based systems that evidences for better ordering of the former. Lorentzian shape of LEPR lines of both charge carriers, lower concentration of spin traps as well as behaviours of the main magnetic resonance parameters were explained by layer ordered morphology of polymer matrix

  20. Optimum design of band-gap beam structures

    DEFF Research Database (Denmark)

    Olhoff, Niels; Niu, Bin; Cheng, Gengdong

    2012-01-01

    of a single, linearly elastic material without damping. Numerical results are presented for different combinations of classical boundary conditions, prescribed orders of the upper and lower natural frequencies of maximized natural frequency gaps, and a given minimum constraint value for the beam......The design of band-gap structures receives increasing attention for many applications in mitigation of undesirable vibration and noise emission levels. A band-gap structure usually consists of a periodic distribution of elastic materials or segments, where the propagation of waves is impeded or...... significantly suppressed for a range of external excitation frequencies. Maximization of the band-gap is therefore an obvious objective for optimum design. This problem is sometimes formulated by optimizing a parameterized design model which assumes multiple periodicity in the design. However, it is shown in...

  1. Photon-photon collisions

    Energy Technology Data Exchange (ETDEWEB)

    Brodsky, S.J.

    1985-01-01

    The study of photon-photon collisions has progressed enormously, stimulated by new data and new calculational tools for QCD. In the future we can expect precise determinations of ..cap alpha../sub s/ and ..lambda../sup ms/ from the ..gamma..*..gamma.. ..-->.. ..pi../sup 0/ form factor and the photon structure function, as well as detailed checks of QCD, determination of the shape of the hadron distribution amplitudes from ..gamma gamma.. ..-->.. H anti H, reconstruction of sigma/sub ..gamma gamma../ from exclusive channels at low W/sub ..gamma gamma../, definitive studies of high p/sub T/ hadron and jet production, and studies of threshold production of charmed systems. Photon-photon collisions, along with radiative decays of the psi and UPSILON, are ideal for the study of multiquark and gluonic resonances. We have emphasized the potential for resonance formation near threshold in virtually every hadronic exclusive channel, including heavy quark states c anti c c anti c, c anti c u anti u, etc. At higher energies SLC, LEP, ...) parity-violating electroweak effects and Higgs production due to equivalent Z/sup 0/ and W/sup + -/ beams from e ..-->.. eZ/sup 0/ and e ..-->.. nu W will become important. 44 references.

  2. Photon-photon collisions

    International Nuclear Information System (INIS)

    The current status, both theoretical and experimental, of two photon collision physics is reviewed with special emphasis on recent experimental results from e+e- storage rings. After a complete presentation of the helicity amplitude formalism for the general process e+e- → Xe+e-, various approximations (transverse photon, Weisaecker Williams) are discussed. Beam polarisation effects and radiative corrections are also briefly considered. A number of specific processes, for which experimental results are now available, are then described. In each case existing theoretical prediction are confronted with experimental results. The processes described include single resonance production, lepton and hadron pair production, the structure functions of the photon, the production of high Psub(T) jets and the total photon photon cross section. In the last part of the review the current status of the subject is summarised and some comments are made on future prospects. These include both extrapolations of current research to higher energy machines (LEP, HERA) as well as a brief mention of both the technical realisation and the physics interest of the real γγ and eγ collisions which may be possible using linear electron colliders in the 1 TeV energy range

  3. Study on the propagation mechanism of evanescent waves in one-dimensional periodic photonic crystal

    International Nuclear Information System (INIS)

    Based on the evanescent waves theory, the formation condition and propagation mechanism of evanescent waves in one-dimensional periodic photonic crystal are studied. When the incident light travels through the periodic photonic crystal at a certain angle, the optical resonance will occur in the optically denser medium, and a unique photonic local feature will occur in photonic bandgap. Furthermore, the influences on transmission performance by the photonic crystal parameters are discussed respectively. The simulation results show that the structure mentioned above can achieve the performance of high transmission and high Q value, which can provide theoretical references for photonic crystal multi-channel filters

  4. Study on the propagation mechanism of evanescent waves in one-dimensional periodic photonic crystal

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Ying, E-mail: chenying@ysu.edu.cn [Hebei Province Key Laboratory of Test/Measurement Technology and Instrument, School of Electrical Engineering, Yanshan University, Qinhuangdao 066004 (China); Shi, Jia; Liu, Teng; Dong, Jing [Hebei Province Key Laboratory of Test/Measurement Technology and Instrument, School of Electrical Engineering, Yanshan University, Qinhuangdao 066004 (China); Zhu, Qiguang; Chen, Weidong [Key Laboratory of Special Fiber and Fiber Sensor of Hebei Province, School of Information Science and Engineering, Yanshan University, Qinhuangdao 066004 (China)

    2015-10-02

    Based on the evanescent waves theory, the formation condition and propagation mechanism of evanescent waves in one-dimensional periodic photonic crystal are studied. When the incident light travels through the periodic photonic crystal at a certain angle, the optical resonance will occur in the optically denser medium, and a unique photonic local feature will occur in photonic bandgap. Furthermore, the influences on transmission performance by the photonic crystal parameters are discussed respectively. The simulation results show that the structure mentioned above can achieve the performance of high transmission and high Q value, which can provide theoretical references for photonic crystal multi-channel filters.

  5. Dispersion-shifted all-solid high index-contrast microstructured optical fiber for nonlinear applications at 1.55µm

    OpenAIRE

    Feng, Xian; Poletti, Francesco; Camerlingo, Angela; Parmigiani, Francesca; Horak, Peter; Petropoulos, Periklis; Loh, Wei H.; Richardson, David J

    2009-01-01

    We report the fabrication of an all-solid highly nonlinear microstructured optical fiber. The structured preform was made by glass extrusion using two types of commercial lead silicate glasses that provide high index-contrast. Effectively single-moded guidance was observed in the fiber at 1.55µm. The effective nonlinearity and the propagation loss at this wavelength were measured to be 120W/km respectively at 1.55µm. These predictions are consistent with the experimentally determined dispersi...

  6. Effect of Poly(Ether Urethane) Introduction on the Performance of Polymer Electrolyte for All-Solid-State Dye-Sensitized Solar Cells

    International Nuclear Information System (INIS)

    The introduction of poly(ether urethane) (PEUR) into polymer electrolyte based on poly(ethylene oxide), LiI and I2, has significantly increased the ionic conductivity by nearly two orders of magnitudes. An increment of I−3 diffusion coefficient is also observed. All-solid-state dye-sensitized solar cells are constructed using the polymer electrolytes. It was found that PEUR incorporation has a beneficial effect on the enhancement of open circuit voltage Voc by shifting the band edge of TiO2 to a negative value. Scanning electron microscope images indicate the perfect interfacial contact between the TiO2 electrode and the blend electrolyte

  7. An all-solid state laser system for the laser ion source RILIS and in-source laser spectroscopy of astatine at ISOLDE,CERN

    OpenAIRE

    Rothe, Sebastian

    2012-01-01

    This doctoral thesis describes the extension of the resonance ionization laser ion source RILIS at CERN/ISOLDE by the addition of an all-solid state tunable titanium:sapphire (Ti:Sa) laser system to complement the well-established system of dye lasers. Synchronous operation of the so called Dual RILIS system of Ti:Sa and dye lasers was investigated and the potential for increased ion beam intensity, reliability, and reduced setup time has been demonstrated. In-source resonance ionization spec...

  8. Facile template-free synthesis of vertically aligned polypyrrole nanosheets on nickel foams for flexible all-solid-state asymmetric supercapacitors

    Science.gov (United States)

    Yang, Xiangwen; Lin, Zhixing; Zheng, Jingxu; Huang, Yingjuan; Chen, Bin; Mai, Yiyong; Feng, Xinliang

    2016-04-01

    This paper reports a novel and remarkably facile approach towards vertically aligned nanosheets on three-dimensional (3D) Ni foams. Conducting polypyrrole (PPy) sheets were grown on Ni foam through the volatilization of the environmentally friendly solvent from an ethanol-water solution of pyrrole (Py), followed by the polymerization of the coated Py in ammonium persulfate (APS) solution. The PPy-decorated Ni foams and commercial activated carbon (AC) modified Ni foams were employed as the two electrodes for the assembly of flexible all-solid-state asymmetric supercapacitors. The sheet-like structure of PPy and the macroporous feature of the Ni foam, which render large electrode-electrolyte interfaces, resulted in good capacitive performance of the supercapacitors. Moreover, a high energy density of ca. 14 Wh kg-1 and a high power density of 6.2 kW kg-1 were achieved for the all-solid-state asymmetric supercapacitors due to the wide cell voltage window.This paper reports a novel and remarkably facile approach towards vertically aligned nanosheets on three-dimensional (3D) Ni foams. Conducting polypyrrole (PPy) sheets were grown on Ni foam through the volatilization of the environmentally friendly solvent from an ethanol-water solution of pyrrole (Py), followed by the polymerization of the coated Py in ammonium persulfate (APS) solution. The PPy-decorated Ni foams and commercial activated carbon (AC) modified Ni foams were employed as the two electrodes for the assembly of flexible all-solid-state asymmetric supercapacitors. The sheet-like structure of PPy and the macroporous feature of the Ni foam, which render large electrode-electrolyte interfaces, resulted in good capacitive performance of the supercapacitors. Moreover, a high energy density of ca. 14 Wh kg-1 and a high power density of 6.2 kW kg-1 were achieved for the all-solid-state asymmetric supercapacitors due to the wide cell voltage window. Electronic supplementary information (ESI) available: ESI

  9. High-efficiency GaAs and GaInP solar cells grown by all solid-state molecular-beam-epitaxy

    OpenAIRE

    Lu, Shulong; Ji, Lian; He, Wei; Dai, Pan; Yang, Hui; Arimochi, Masayuki; Yoshida, Hiroshi; Uchida, Shiro; Ikeda, Masao

    2011-01-01

    We report the initial results of GaAs and GaInP solar cells grown by all solid-state molecular-beam-epitaxy (MBE) technique. For GaAs single-junction solar cell, with the application of AlInP as the window layer and GaInP as the back surface field layer, the photovoltaic conversion efficiency of 26% at one sun concentration and air mass 1.5 global (AM1.5G) is realized. The efficiency of 16.4% is also reached for GaInP solar cell. Our results demonstrate that the MBE-grown phosphide-contained ...

  10. Photonic crystals with topological defects

    CERN Document Server

    Liew, Seng Fatt; Xiong, Wen; Cao, Hui

    2014-01-01

    We introduce topological defect to a square lattice of elliptical cylinders. Despite the broken translational symmetry, the long-range positional order of the cylinders leads to residual photonic bandgap in the density of optical states. However, the band-edge modes are strongly modified by the spatial variation of ellipse orientation. The $\\Gamma-X$ band-edge mode splits into four regions of high intensity and the output flux becomes asymmetric due to the formation of crystalline domains with different orientation. The $\\Gamma-M$ band-edge mode has the energy flux circulates around the topological defect center, creating an optical vortex. By removing the elliptical cylinders at the center, we create localized defect states which are dominated by either clockwise or counter-clockwise circulating waves. The flow direction can be switched by changing the ellipse orientation. The deterministic aperiodic variation of the unit cell orientation adds another dimension to the control of light in photonic crystals, e...

  11. Automating Energy Bandgap Measurements in Semiconductors Using LabVIEW

    Science.gov (United States)

    Garg, Amit; Sharma, Reena; Dhingra, Vishal

    2010-01-01

    In this paper, we report the development of an automated system for energy bandgap and resistivity measurement of a semiconductor sample using Four-Probe method for use in the undergraduate laboratory of Physics and Electronics students. The automated data acquisition and analysis system has been developed using National Instruments USB-6008 DAQ…

  12. Bandgap Opening in Graphene Induced by Patterned Hydrogen Adsorption

    DEFF Research Database (Denmark)

    Balog, Richard; Jørgensen, Bjarke; Nilsson, Louis;

    2010-01-01

    fermions, and graphene shows ballistic charge transport, turning it into an ideal material for circuit fabrication. However, graphene lacks a bandgap around the Fermi level, which is the defining concept for semiconductor materials and essential for controlling the conductivity by electronic means. Theory...

  13. Synthesis of low-bandgap alternating copolymers with thienothiadiazole units

    Czech Academy of Sciences Publication Activity Database

    Kmínek, Ivan; Výprachtický, Drahomír; Cimrová, Věra

    Istanbul : Istanbul Technical University, 2011. s. 197. [IUPAC International Conference on Advanced Polymers via Macromolecular Engineering /9./ - APME 2011. 05.09.2011-08.09.2011, Nevsehir, Cappadocia] R&D Projects: GA MŠk(CZ) 1M06031 Institutional research plan: CEZ:AV0Z40500505 Keywords : thienothiadiazole * low bandgap * copolymer Subject RIV: BM - Solid Matter Physics ; Magnetism

  14. Characterisation of polymeric rod-connected diamond photonic crystal at near-infrared range

    OpenAIRE

    Chen, L; Taverne, M.P.C.; X. Zheng; Huang, C. C.; Garcia, Y.L.; Hewak, D.W.; Rarity, J.G.

    2015-01-01

    We present a low-index polymeric three-dimensional photonic crystal, rod-connected diamond structure, created via direct laser writing, showing a partial photonic band gap at near-infrared wavelengths in both P and S polarization, measured by angular resolved Fourier image spectroscopy. We show initial tests of backfilling with high refractive index material aimed at achieving a full photonic bandgap in the near-infrared.

  15. Design of robust and efficient photonic switches using topology optimization

    DEFF Research Database (Denmark)

    Elesin, Yuriy; Lazarov, Boyan Stefanov; Jensen, Jakob Søndergaard;

    2012-01-01

    a performance which is very sensitive to geometric manufacturing errors (under- or over-etching). Such behavior is undesirable and robustness is achieved by optimizing for several design realizations. The possible geometric uncertainties are modeled by random variables. It is shown that the designs...... are insensitive with respect to variations of signal parameters, such as signal amplitudes and phase shifts. The obtained robust designs of a 1D photonic switch can substantially outperform simple bandgap designs, known from the literature, where switching takes place due to the bandgap shift produced...

  16. Effects of counter electrodes on photovoltaic performance of all-solid-state TiO2-based dye-sensitized solar cells

    Science.gov (United States)

    Shang, Mingwei; Liu, Benjamin; Dong, Zhenhua; Dong, Zhenyu; Dong, Lifeng

    2015-03-01

    In order to analyse the effects of counter electrodes on photovoltaic performance of dye-sensitized solar cells (DSSCs), different electrodes were used as the counter electrodes for all-solid-state TiO2-based DSSCs. An inorganic solid-state electrolyte, CsSnI2.95F0.05, was selected to couple with N719 dye-sensitized TiO2 nanorod arrays to fabricate the DSSCs. Fluorine doped tin oxide transparent conducting glass (FTO), platinum coated FTO (Pt/FTO), graphite coated FTO (graphite/FTO), and graphite coated common glass (graphite/glass) were investigated as the counter electrodes, and the cells composed of the corresponding electrodes above have power-conversion efficiencies of 2.17%, 9.84%, 7.62%, and 3.45%, respectively. Our findings indicate that due to its unique catalytic and conducting properties, graphite can replace both Pt and FTO as a counter electrode to reduce the fabrication cost of all-solid-state TiO2-based DSSCs.

  17. Facile fabrication of all-solid-state flexible interdigitated MnO2 supercapacitor via in-situ catalytic solution route

    Science.gov (United States)

    Long, Xiao; Zeng, Zhigang; Guo, Erjuan; Shi, Xiaobo; Zhou, Haijun; Wang, Xiaohong

    2016-09-01

    With the rapid development of wearable and portable electronics, the demand for all-solid-state flexible energy storage devices with high performance, long-term cycling stability and bending stability has been aroused. Physical and chemical method for preparing thin-film materials has enabled planar flexible supercapacitors (SCs) to be fabricated for a variety of applications. In this work, we report on the facile fabrication of an all-solid-state flexible interdigitated supercapacitor with a convenient and efficient two-step method. 3-D nanostructured α-MnO2 has been prepared on the surface of interdigitated Pt metal pattern on polyethylene terephthalate (PET) substrate as high-performance electrode material via in-situ catalytic solution route without any assistance of template or surfactant. The SCs are fabricated with PVA/H3PO4 as solid-state electrolyte, which exhibited good electrochemical performance with areal capacitance as much as 20 mF cm-2 at a scan rate of 10 mV s-1, relatively high energy density (3.6 × 10-7 Wh cm-2-1.9 × 10-6 Wh cm-2) and power density (9 × 10-5 W cm-2-1.6 × 10-4 W cm-2), and excellent long-term cycling stability with capacitance retention of 82.2% (10,000 times charge and discharge), and bending stability with capacitance retention of 89.6%.

  18. Wet-process Fabrication of Low-cost All-solid Wire-shaped Solar Cells on Manganese-plated Electrodes

    International Nuclear Information System (INIS)

    Highlights: • All-solid wire-shaped flexible solar cells are firstly assembled on low-cost Mn-plated fibers. • Energy efficiency improved by >27% after coating a layer of Mn on various substrates. • The cell is fabricated via wet process under low temperature and mild pH conditions. • Stable flexible solar cells are realized on lightweight and low-cost polymer fiber. - Abstract: All-solid wire-shaped flexible solar cells are assembled for the first time on low-cost Mn-plated wires through wet-process fabrication under low temperature and mild pH conditions. With a price cheap as the steel, metal Mn can be easily plated on almost any substrates, and evidently promote the photovoltaic efficiency of wire-shaped solar cells on various traditional metal wire substrates, such as Fe and Ti, by 27% and 65%, respectively. Flexible solar cell with much lower cost and weight is assembled on Mn-plated polymer substrate, and is still capable of giving better performance than that on Fe or Ti substrate. Both its mechanical and chemical stability are good for future weaving applications. Owing to the wire-type structure, such low-cost metals as Mn, which are traditionally regarded as unsuitable for solar cells, may provide new opportunities for highly efficient solar cells

  19. Optimization of Beam Properties with Respect to Maximum Band-Gap

    DEFF Research Database (Denmark)

    Halkjær, Søren; Sigmund, Ole

    2004-01-01

    We study numerically the frequency band-gap phenomenon for bending waves in an infinite periodic beam. The outcome of the analysis is then subjected to an optimization problem in order to maximize these band-gaps. The band-gap maximization may be performed with respect to material parameters and...

  20. Optimal design of tunable phononic bandgap plates under equibiaxial stretch

    Science.gov (United States)

    Hedayatrasa, Saeid; Abhary, Kazem; Uddin, M. S.; Guest, James K.

    2016-05-01

    Design and application of phononic crystal (PhCr) acoustic metamaterials has been a topic with tremendous growth of interest in the last decade due to their promising capabilities to manipulate acoustic and elastodynamic waves. Phononic controllability of waves through a particular PhCr is limited only to the spectrums located within its fixed bandgap frequency. Hence the ability to tune a PhCr is desired to add functionality over its variable bandgap frequency or for switchability. Deformation induced bandgap tunability of elastomeric PhCr solids and plates with prescribed topology have been studied by other researchers. Principally the internal stress state and distorted geometry of a deformed phononic crystal plate (PhP) changes its effective stiffness and leads to deformation induced tunability of resultant modal band structure. Thus the microstructural topology of a PhP can be altered so that specific tunability features are met through prescribed deformation. In the present study novel tunable PhPs of this kind with optimized bandgap efficiency-tunability of guided waves are computationally explored and evaluated. Low loss transmission of guided waves throughout thin walled structures makes them ideal for fabrication of low loss ultrasound devices and structural health monitoring purposes. Various tunability targets are defined to enhance or degrade complete bandgaps of plate waves through macroscopic tensile deformation. Elastomeric hyperelastic material is considered which enables recoverable micromechanical deformation under tuning finite stretch. Phononic tunability through stable deformation of phononic lattice is specifically required and so any topology showing buckling instability under assumed deformation is disregarded. Nondominated sorting genetic algorithm (GA) NSGA-II is adopted for evolutionary multiobjective topology optimization of hypothesized tunable PhP with square symmetric unit-cell and relevant topologies are analyzed through finite

  1. Fabrication of photonic amorphous diamonds for terahertz-wave applications

    Science.gov (United States)

    Komiyama, Yuichiro; Abe, Hiroyuki; Kamimura, Yasushi; Edagawa, Keiichi

    2016-05-01

    A recently proposed photonic bandgap material, named "photonic amorphous diamond" (PAD), was fabricated in a terahertz regime, and its terahertz-wave propagation properties were investigated. The PAD structure was fabricated from acrylic resin mixed with alumina powder, using laser lithographic, micro-additive manufacturing technique. After fabrication, the resulting structure was dewaxed and sintered. The formation of a photonic bandgap at around 0.45 THz was demonstrated by terahertz time-domain spectroscopy. Reflecting the disordered nature of the random network structure, diffusive terahertz-wave propagation was observed in the passbands; the scattering mean-free path decreased as the frequency approached the band edge. The mean-free paths evaluated at the band edges were close to the Ioffe-Regel threshold value for wave localization.

  2. Decay dynamics of quantum dots influenced by the local density of optical states of two-dimensional photonic crystal membranes

    DEFF Research Database (Denmark)

    Julsgaard, Brian; Johansen, Jeppe; Stobbe, Søren; Stolberg-Rohr, T.; Sünner, T.; Kamp, M.; Forchel, A.; Lodahl, Peter

    2008-01-01

    We have performed time-resolved spectroscopy on InAs quantum dot ensembles in photonic crystal membranes. The influence of the photonic crystal is investigated by varying the lattice constant systematically. We observe a strong slow down of the quantum dots’ spontaneous emission rates as the two...... bandgap in good agreement with local density of states calculations....

  3. Photon technology. Hard photon technology; Photon technology. Hard photon gijutsu

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-03-01

    Research results of hard photon technology have been summarized as a part of novel technology development highly utilizing the quantum nature of photon. Hard photon technology refers to photon beam technologies which use photon in the 0.1 to 200 nm wavelength region. Hard photon has not been used in industry due to the lack of suitable photon sources and optical devices. However, hard photon in this wavelength region is expected to bring about innovations in such areas as ultrafine processing and material synthesis due to its atom selective reaction, inner shell excitation reaction, and spatially high resolution. Then, technological themes and possibility have been surveyed. Although there are principle proposes and their verification of individual technologies for the technologies of hard photon generation, regulation and utilization, they are still far from the practical applications. For the photon source technology, the laser diode pumped driver laser technology, laser plasma photon source technology, synchrotron radiation photon source technology, and vacuum ultraviolet photon source technology are presented. For the optical device technology, the multi-layer film technology for beam mirrors and the non-spherical lens processing technology are introduced. Also are described the reduction lithography technology, hard photon excitation process, and methods of analysis and measurement. 430 refs., 165 figs., 23 tabs.

  4. III-V/Si photonics by die-to-wafer bonding

    Directory of Open Access Journals (Sweden)

    G. Roelkens

    2007-07-01

    Full Text Available Photonic integrated circuits offer the potential of realizing low-cost, compact optical functions. Silicon-on-insulator (SOI is a promising material platform for this photonic integration, as one can rely on the massive electronics processing infrastructure to process the optical components. However, the integration of a Si laser is hampered by its indirect bandgap. Here, we present the integration of a direct bandgap III-V epitaxial layer on top of the SOI waveguide layer by means of a die-to-wafer bonding process in order to realize near-infrared laser emission on and coupled to SOI.

  5. Photonics and optoelectronics of 2D semiconductor transition metal dichalcogenides

    Science.gov (United States)

    Mak, Kin Fai; Shan, Jie

    2016-04-01

    Recent advances in the development of atomically thin layers of van der Waals bonded solids have opened up new possibilities for the exploration of 2D physics as well as for materials for applications. Among them, semiconductor transition metal dichalcogenides, MX2 (M = Mo, W; X = S, Se), have bandgaps in the near-infrared to the visible region, in contrast to the zero bandgap of graphene. In the monolayer limit, these materials have been shown to possess direct bandgaps, a property well suited for photonics and optoelectronics applications. Here, we review the electronic and optical properties and the recent progress in applications of 2D semiconductor transition metal dichalcogenides with emphasis on strong excitonic effects, and spin- and valley-dependent properties.

  6. Fabrication of a Two-Dimensional Organic Photonic Crystal

    Institute of Scientific and Technical Information of China (English)

    HU Xiao-Yong; LI Yan; GONG Qi-Huang; CHENG Bing-Ying; ZHANG Dao-Zhong

    2005-01-01

    @@ A high-quality two-dimensional polystyrene photonic crystal is fabricated by the method of focused ion beam etching. The scanning electron microscopy (SEM) and the transmittance spectrum are used to characterize the properties of the photonic crystal. The measured transmittance spectrum is in agreement with the theoretical one. The influences of the disorders caused by the random perturbations in the diameter or the position of the air holes on the photonic band structure are analysed. It is found that the phtonic bandgap can tolerate less than 10% degree of disorder.

  7. High-Beam-Quality All-Solid-State 355 nm Ultraviolet Pulsed Laser Based on a Master-Oscillator Power-Amplifier System Pumped at 888 nm

    Science.gov (United States)

    Hong, Hailong; Liu, Qiang; Huang, Lei; Gong, Mali

    2012-09-01

    An efficient all-solid-state 355 nm ultraviolet laser based on an 888 nm pumped master-oscillator power-amplifier (MOPA) system is presented. Due to the high beam quality of the fundamental wave being superior to 1.15 (M2) under all pump powers and pulse repetition frequencies (PRFs), the UV laser has the advantage of being able to operate continuously from zero to maximum power. The maximum green and UV output powers were 45.9 W at 50 kHz and 24.3 W at 65 kHz with the corresponding conversion efficiencies from IR-to-green and IR-to-UV of 66.0% and 34.1%, respectively.

  8. A Compact All-Solid-State 630-ps 9.43-kHz High Power Nd:YAG/Nd:YVO4 Hybrid Laser System

    International Nuclear Information System (INIS)

    We present a simple and compact design for an all-solid-state laser amplifier system which can output 9.43-kHz 630-ps, 3.5-Wpulse trains under 20 W absorbed pumping power. The excellent matching between the repetition of its seed source and the fluorescence lifetime of the amplifying medium makes it quiet efficient for the four-pass amplifier to be pumped in cw mode without need of any synchronization device between the oscillator and the amplifier. The entire setup just covers an area of 55 × 25 cm2. The output average power fluctuation is less than ±1.5% within 10min and 3% within 6h. (fundamental areas of phenomenology (including applications))

  9. An all-solid state laser system for the laser ion source RILIS and in-source laser spectroscopy of astatine at ISOLDE, CERN

    CERN Document Server

    Rothe, Sebastian; Nörtershäuser, W

    This doctoral thesis describes the extension of the resonance ionization laser ion source RILIS at ISOLDE, CERN, by the addition of an all-solid state tuneable titanium: sapphire (Ti:Sa) laser system to complement the well-established system of dye lasers. Synchronous operation of the so called Dual RILIS system of Ti:Sa and dye lasers was investigated and the potential for increased ion beam intensity, reliability, and reduced setup time has been demonstrated. In-source resonance ionization spectroscopy was performed at ISOLDE, CERN, and at ISAC, TRIUMF, radioactive ion beam facilities to develop an efficient and selective three-colour ionization scheme for the purely radioactive element astatine. A LabVIEW based monitoring, control and measurement system was conceived which enabled, in conjunction with Dual RILIS operation, the spectroscopy of high lying Rydberg states, from which the ionization potential of the astatine atom was determined for the first time experimentally.

  10. Controllable light filters using an all-solid-state switchable mirror with a Mg-Ir thin film for preterm infant incubators

    Science.gov (United States)

    Tajima, Kazuki; Shimoike, Mika; Li, Heng; Inagaki, Masumi; Izumi, Hitomi; Akiyama, Misaki; Matsushima, Yukiko; Ohta, Hidenobu

    2013-04-01

    We have fabricated a controllable light filter using an all-solid-state switchable mirror incorporating a Mg-Ir thin film for use in preterm infant incubators. The solid-state switchable mirror device was fabricated by depositing a multilayer on a glass substrate. The mixed hydride of MgH2 and Mg6Ir2H11 created from the Mg-Ir thin film is red in the transparent state. The optical switching speeds between the reflective and transparent red states depended on applied voltage. The device showed three states, namely, reflective, black, and transparent red, due to the properties of the switchable mirror material. These results suggest that the material could be used as a controllable light filter for preterm infant incubators, since it eliminates the light wavelength that disturbs regular sleep-wake cycles of preterm infants.

  11. An all-solid state laser system for the laser ion sources RILIS and in-source laser spectroscopy of astatine at ISOLDE/CERN

    Energy Technology Data Exchange (ETDEWEB)

    Rothe, Sebastian

    2012-09-24

    This doctoral thesis describes the extension of the resonance ionization laser ion source RILIS at CERN/ISOLDE by the addition of an all-solid state tunable titanium:sapphire (Ti:Sa) laser system to complement the well-established system of dye lasers. Synchronous operation of the so called Dual RILIS system of Ti:Sa and dye lasers was investigated and the potential for increased ion beam intensity, reliability, and reduced setup time has been demonstrated. In-source resonance ionization spectroscopy was performed at ISOLDE/CERN and at ISAC/TRIUMF radioactive ion beam facilities to develop an efficient and selective three-colour ionization scheme for the purely radioactive element astatine. A LabVIEW based monitoring, control and measurement system was conceived which enabled, in conjunction with Dual RILIS operation, the spectroscopy of high lying Rydberg states, from which the ionization potential of the astatine atom was determined for the first time experimentally.

  12. Facile fabrication of all-solid-state SnO2/NiCo2O4 biosensor for self-powered glucose detection

    Science.gov (United States)

    Cai, Bin; Mao, Weiwei; Ye, Zhizhen; Huang, Jingyun

    2016-09-01

    With increasing attention on daily diabetes management, we develop an all-solid-state self-powered glucose biosensor, with simultaneous solar energy conversion, electrochemical energy storage and glucose sensing. The SnO2 nanosheet arrays are used to obtain photogenerated electron-hole pairs, and rhombus-shaped NiCo2O4 nanorod arrays are developed for solar energy storage. A stable open circuit voltage ~0.58 V is obtained after being fully charged, which is a suitable voltage for the oxidation of glucose. The biosensor can work under two different modes without any external bias voltage, and both show large linear range and excellent selectivity. Under the sunlight, photocurrent shows a sensitive decrease upon different glucose additions. Meanwhile, in the dark condition, the open circuit voltage of the charged biosensor also exhibits a corresponding response to glucose.

  13. An all-solid state laser system for the laser ion sources RILIS and in-source laser spectroscopy of astatine at ISOLDE/CERN

    International Nuclear Information System (INIS)

    This doctoral thesis describes the extension of the resonance ionization laser ion source RILIS at CERN/ISOLDE by the addition of an all-solid state tunable titanium:sapphire (Ti:Sa) laser system to complement the well-established system of dye lasers. Synchronous operation of the so called Dual RILIS system of Ti:Sa and dye lasers was investigated and the potential for increased ion beam intensity, reliability, and reduced setup time has been demonstrated. In-source resonance ionization spectroscopy was performed at ISOLDE/CERN and at ISAC/TRIUMF radioactive ion beam facilities to develop an efficient and selective three-colour ionization scheme for the purely radioactive element astatine. A LabVIEW based monitoring, control and measurement system was conceived which enabled, in conjunction with Dual RILIS operation, the spectroscopy of high lying Rydberg states, from which the ionization potential of the astatine atom was determined for the first time experimentally.

  14. 1,2,4-Triazolium perfluorobutanesulfonate as an archetypal pure protic organic ionic plastic crystal electrolyte for all-solid-state fuel cells

    DEFF Research Database (Denmark)

    Luo, Jiangshui; Jensen, Annemette Hindhede; Brooks, Neil R.;

    2015-01-01

    1,2,4-Triazolium perfluorobutanesulfonate (1), a novel, pure protic organic ionic plastic crystal (POIPC) with a wide plastic crystalline phase, has been explored as a proof-of-principle anhydrous proton conductor for all-solid-state high temperature hydrogen/air fuel cells. Its physicochemical...... properties, including thermal, mechanical, structural, morphological, crystallographic, spectral, and ion-conducting properties, as well as fuel cell performances, have been studied comprehensively in both fundamental and device-oriented aspects. With superior thermal stability, 1 exhibits crystal (phase III......), plastic crystalline (phase II and I) and melt phases successively from 173 C to 200 C. Differential scanning calorimetry and temperature dependent powder X-ray diffraction (XRD) measurements together with polarized optical microscopy and thermomechanical analysis reveal the two solid–solid phase...

  15. A Compact All-Solid-State 630-ps 9.43-kHz High Power Nd: YAG/ Nd: YVO4 Hybrid Laser System

    Institute of Scientific and Technical Information of China (English)

    XU Shi-Xiang; WEI Xiao-Yu; DU Ke-Ming; LI Jing-Zhen

    2008-01-01

    We present a simple and compact design for an all-solid-state laser amplifier system which can output 9.43-kHz 630-ps, 3.5-W pulse trains under 20W absorbed pumping power. The excellent matching between the repetition of its seed source and the fluorescence lifetime of the amplifying medium makes it quiet efficient for the four-pass amplifier to be pumped in cw mode without need of any synchronization device between the oscillator and the amplifier. The entire setup just covers an area of 55×25cm2. The output average power fluctuation is less than ±1.5% within 10min and 3% within 6h.

  16. High-Performance All-Solid-State Lithium-Sulfur Battery Enabled by a Mixed-Conductive Li2S Nanocomposite.

    Science.gov (United States)

    Han, Fudong; Yue, Jie; Fan, Xiulin; Gao, Tao; Luo, Chao; Ma, Zhaohui; Suo, Liumin; Wang, Chunsheng

    2016-07-13

    All-solid-state lithium-sulfur batteries (ASSLSBs) using highly conductive sulfide-based solid electrolytes suffer from low sulfur utilization, poor cycle life, and low rate performance due to the huge volume change of the electrode and the poor electronic and ionic conductivities of S and Li2S. The most promising approach to mitigate these challenges lies in the fabrication of a sulfur nanocomposite electrode consisting of a homogeneous distribution of nanosized active material, solid electrolyte, and carbon. Here, we reported a novel bottom-up method to synthesize such a nanocomposite by dissolving Li2S as the active material, polyvinylpyrrolidone (PVP) as the carbon precursor, and Li6PS5Cl as the solid electrolyte in ethanol, followed by a coprecipitation and high-temperature carbonization process. Li2S active material and Li6PS5Cl solid electrolyte with a particle size of ∼4 nm were uniformly confined in a nanoscale carbon matrix. The homogeneous nanocomposite electrode consisting of different nanoparticles with distinct properties of lithium storage capability, mechanical reinforcement, and ionic and electronic conductivities enabled a mechanical robust and mixed conductive (ionic and electronic conductive) sulfur electrode for ASSLSB. A large reversible capacity of 830 mAh/g (71% utilization of Li2S) at 50 mA/g for 60 cycles with a high rate performance was achieved at room temperature even at a high loading of Li2S (∼3.6 mg/cm(2)). This work provides a new strategy to design a mechanically robust, mixed conductive nanocomposite electrode for high-performance all-solid-state lithium sulfur batteries. PMID:27322663

  17. Microwave Photonics

    OpenAIRE

    A J Seeds; Liu, C. P.; Ismail, T; Fice, M. J.; Pozzi, F.; Steed, R. J.; Rouvalis, E.; Renaud, C.C.

    2010-01-01

    Microwave photonics is the use of photonic techniques for the generation, transmission, processing and reception of signals having spectral components at microwave frequencies. This tutorial reviews the technologies used and gives applications examples.

  18. Polychromatic photons

    DEFF Research Database (Denmark)

    Keller, Ole

    2002-01-01

    A review is given of the space-time wave mechanics of single photons, a subject with an almost century long history. The Landau-Peierls photon wave function, which is related nonlocally to the electromagnetic field is first described, and thereafter the so-called energy wave function, based on the...... positive-frequency Riemann-Silberstein vectors, is discussed. Recent attempts to understand the birth process of a photon emerging from a single atom are summarized. The polychromatic photon concept is introduced, and it is indicated how the wave mechanics of polychromatic photons can be upgraded to wave...... train quantum electrodynamics. A brief description of particle (photon) position operators is given, and it is shown that photons usually are only algebraically confined in an emission process. Finally, it is demonstrated that the profile of the birth domain of a radio-frequency photon emitted in a...

  19. Photon Structure

    OpenAIRE

    Grindhammer, Guenter

    2001-01-01

    Large pT processes at HERA, initiated by almost real and by virtual photons, provide information on the structure of the photon. We report on the latest measurements of dijets and large pT particle production with the H1 detector. This includes a leading order determination of an effective virtual photon parton density, of the gluon density of the photon, and comparisons with models.

  20. Phonon Bandgap Engineering of Strained Monolayer MoS2

    OpenAIRE

    Jiang, Jin-Wu

    2014-01-01

    The phonon band structure of monolayer MoS2 is characteristic for a large energy gap between acoustic and optical branches, which protects the vibration of acoustic modes from being scattered by optical phonon modes. Therefore, the phonon bandgap engineering is of practical significance for the manipulation of phonon-related mechanical or thermal properties in monolayer MoS2. We perform both phonon analysis and molecular dynamics simulations to investigate the tension effect on the phonon ban...

  1. Direct bandgap silicon: tensile-strained silicon nanocrystals

    Czech Academy of Sciences Publication Activity Database

    Kůsová, Kateřina; Hapala, Prokop; Valenta, J.; Jelínek, Pavel; Cibulka, Ondřej; Ondič, Lukáš; Pelant, Ivan

    2014-01-01

    Roč. 1, č. 2 (2014), "1300042-1"-"1300042-9". ISSN 2196-7350 R&D Projects: GA ČR(CZ) GBP108/12/G108; GA ČR GPP204/12/P235; GA ČR GAP204/10/0952 Institutional support: RVO:68378271 Keywords : silicon nanocrystals * badstructure * light emission * direct bandgap * surface capping Subject RIV: BM - Solid Matter Physics ; Magnetism

  2. Bandgap tunability at single-layer molybdenum disulphide grain boundaries

    KAUST Repository

    Huang, Yu Li

    2015-02-17

    Two-dimensional transition metal dichalcogenides have emerged as a new class of semiconductor materials with novel electronic and optical properties of interest to future nanoelectronics technology. Single-layer molybdenum disulphide, which represents a prototype two-dimensional transition metal dichalcogenide, has an electronic bandgap that increases with decreasing layer thickness. Using high-resolution scanning tunnelling microscopy and spectroscopy, we measure the apparent quasiparticle energy gap to be 2.40±0.05 eV for single-layer, 2.10±0.05 eV for bilayer and 1.75±0.05 eV for trilayer molybdenum disulphide, which were directly grown on a graphite substrate by chemical vapour deposition method. More interestingly, we report an unexpected bandgap tunability (as large as 0.85±0.05 eV) with distance from the grain boundary in single-layer molybdenum disulphide, which also depends on the grain misorientation angle. This work opens up new possibilities for flexible electronic and optoelectronic devices with tunable bandgaps that utilize both the control of two-dimensional layer thickness and the grain boundary engineering.

  3. Extended-Range Ultrarefractive 1D Photonic Crystal Prisms

    Science.gov (United States)

    Ting, David Z.

    2007-01-01

    A proposal has been made to exploit the special wavelength-dispersive characteristics of devices of the type described in One-Dimensional Photonic Crystal Superprisms (NPO-30232) NASA Tech Briefs, Vol. 29, No. 4 (April 2005), page 10a. A photonic crystal is an optical component that has a periodic structure comprising two dielectric materials with high dielectric contrast (e.g., a semiconductor and air), with geometrical feature sizes comparable to or smaller than light wavelengths of interest. Experimental superprisms have been realized as photonic crystals having three-dimensional (3D) structures comprising regions of amorphous Si alternating with regions of SiO2, fabricated in a complex process that included sputtering. A photonic crystal of the type to be exploited according to the present proposal is said to be one-dimensional (1D) because its contrasting dielectric materials would be stacked in parallel planar layers; in other words, there would be spatial periodicity in one dimension only. The processes of designing and fabricating 1D photonic crystal superprisms would be simpler and, hence, would cost less than do those for 3D photonic crystal superprisms. As in 3D structures, 1D photonic crystals may be used in applications such as wavelength-division multiplexing. In the extended-range configuration, it is also suitable for spectrometry applications. As an engineered structure or artificially engineered material, a photonic crystal can exhibit optical properties not commonly found in natural substances. Prior research had revealed several classes of photonic crystal structures for which the propagation of electromagnetic radiation is forbidden in certain frequency ranges, denoted photonic bandgaps. It had also been found that in narrow frequency bands just outside the photonic bandgaps, the angular wavelength dispersion of electromagnetic waves propagating in photonic crystal superprisms is much stronger than is the angular wavelength dispersion obtained

  4. Characterization of all-solid-state secondary batteries with LiCoO{sub 2} thin films prepared by ECR sputtering as positive electrodes

    Energy Technology Data Exchange (ETDEWEB)

    Takahashi, Masaya; Hayashi, Masahiko; Shodai, Takahisa [NTT Energy and Environment Systems Laboratories, Nippon Telegraph and Telephone Corporation, 3-1 Morinosato Wakamiya, Atsugi, Kanagawa 243-0198 (Japan)

    2009-04-01

    We fabricated all-solid-state lithium secondary batteries consisting of LiCoO{sub 2} thin films prepared by electron cyclotron resonance (ECR) sputtering LiPON and metallic lithium films, and investigated the influence of the sputtering target composition on the performance of the batteries and LiCoO{sub 2} films. We found that the LiCoO{sub 2} film sputtered with a stoichiometric LiCoO{sub 2} target included many impurities (mainly Co{sub 3}O{sub 4}) and these impurities were eliminated by adding an excess of Li source to the sputtering target to achieve a Li/Co atomic ratio of 2.0 elsewhere. The LiCoO{sub 2} film sputtered with a Li2.0 target exhibited a larger discharge capacity and a high performance level for large current operation. However, the capacity of a battery employing LiCoO{sub 2} film sputtered with a Li2.0 target decreased more rapidly than that with a Li1.0 or Li1.7 target in a charge-discharge cycle test. We also investigated the cycle performance of LiCoO{sub 2} films in an ordinary liquid electrolyte by using beaker type cells. We found that the decrease in capacity during the cycle tests was caused by the deterioration of the LiCoO{sub 2} film, because the dependence of the target composition on the cycle performance in the beaker type cells was similar to that in the all-solid-state cells. We consider the capacity decrease to be caused by the deterioration in the crystallinity of the LiCoO{sub 2} film when using the Li2.0 target and caused by the formation of a Co{sub 3}O{sub 4} layer on the surface of the LiCoO{sub 2} film when using a Li1.7 target on basis of the results of X-ray diffraction analysis and Raman spectroscopy. (author)

  5. All-Solid-State Nd:YAG Laser Operating at 1064 nm and 1319 nm under 885 nm Thermally Boosted Pumping

    International Nuclear Information System (INIS)

    We report a high-efficiency Nd:YAG laser operating at 1064 nm and 1319 nm, respectively, thermally boosted pumped by an all-solid-state Q-switched Ti:sapphire laser at 885 nm. The maximum outputs of 825.4 mW and 459.4 mW, at 1064 nm and 1319 nm respectively, are obtained in a 8-mm-thick 1.1 at. % Nd:YAG crystal with 2.1 W of incident pump power at 885 nm, leading to a high slope efficiency with respect to the absorbed pump power of 68.5% and 42.0%. Comparative results obtained by the traditional pumping at 808 nm are presented, showing that the slope efficiency and the threshold with respect to the absorbed pump power at 1064 nm under the 885 nm pumping are 12.2% higher and 7.3% lower than those of 808 nm pumping. At 1319 nm, the slope efficiency and the threshold with respect to the absorbed pump power under 885 nm pumping are 9.9% higher and 3.5% lower than those of 808 nm pumping. The heat generation operating at 1064 nm and 1319 nm is reduced by 19.8% and 11.1%, respectively

  6. All-solid-state doubly resonant intracavity frequency sum mixing orange yellow laser with 3.2 W output power at 593.5 nm

    Science.gov (United States)

    Zhu, P. F.; Li, B.; Liu, W. Q.; Liu, T. H.; Fang, C. X.; Zhano, Y.; Yao, Y.; Zheng, Q.

    2013-01-01

    A compact and efficient 593.5 nm orange-yellow laser is realized using doubly resonant intracavity sum frequency mixing. Two Nd: YVO4 crystals are employed as the gain crystals. In two sub-cavities, 1064 nm radiation from one Nd: YVO4 and 1342 nm radiation from the other Nd: YVO4 are mixed to generate 593.5 nm orange-yellow laser. In the overlapping of the two cavities, sum frequency mixing is achieved in a type I critical phase matching (CPM) LBO crystal. An output power of 3.2 W at the wavelength of 593.5 nm is obtained with total incident pump power of 38 W. The optical to optical conversion efficiency is up to 8.4% and the stability of the output power is better than 2.48% in 8 h. To the best knowledge, this it the highest watt-level laser at 593.5 nm generated by diode end pump all-solid-state technology.

  7. An Integrated Glucose Sensor with an All-Solid-State Sodium Ion-Selective Electrode for a Minimally Invasive Glucose Monitoring System

    Directory of Open Access Journals (Sweden)

    Junko Kojima

    2015-06-01

    Full Text Available We developed a minimally invasive glucose monitoring system that uses a microneedle to permeate the skin surface and a small hydrogel to accumulate interstitial fluid glucose. The measurement of glucose and sodium ion levels in the hydrogel is required for estimating glucose levels in blood; therefore, we developed a small, enzyme-fixed glucose sensor with a high-selectivity, all-solid-state, sodium ion-selective electrode (ISE integrated into its design. The glucose sensor immobilized glucose oxidase showed a good correlation between the glucose levels in the hydrogels and the reference glucose levels (r > 0.99, and exhibited a good precision (coefficient of variation = 2.9%, 0.6 mg/dL. In the design of the sodium ISEs, we used the insertion material Na0.33MnO2 as the inner contact layer and DD16C5 exhibiting high Na+/K+ selectivity as the ionophore. The developed sodium ISE exhibited high selectivity (\\( \\log \\,k^{pot}_{Na,K} = -2.8\\ and good potential stability. The sodium ISE could measure 0.4 mM (10−3.4 M sodium ion levels in the hydrogels containing 268 mM (10−0.57 M KCl. The small integrated sensor (ϕ < 10 mm detected glucose and sodium ions in hydrogels simultaneously within 1 min, and it exhibited sufficient performance for use as a minimally invasive glucose monitoring system.

  8. 2.1-watts intracavity-frequency-doubled all-solid-state light source at 671 nm for laser cooling of lithium

    CERN Document Server

    Eismann, Ulrich; Salomon, Christophe; Chevy, Frédéric

    2013-01-01

    We present an all-solid-state laser source emitting up to 2.1 W of single-frequency light at 671 nm developed for laser cooling of lithium atoms. It is based on a diode-pumped, neodymium-doped orthovanadate (Nd:YVO$_4$) ring laser operating at 1342 nm. Optimization of the thermal management in the gain medium results in a maximum multi-frequency output power of 2.5 W at the fundamental wavelength. We develop a simple theory for the efficient implementation of intracavity second harmonic generation, and its application to our system allows us to obtain nonlinear conversion efficiencies of up to 88%. Single-mode operation and tuning is established by adding an etalon to the resonator. The second-harmonic wavelength can be tuned over 0.5 nm, and mode-hop-free scanning over more than 6 GHz is demonstrated, corresponding to around ten times the laser cavity free spectral range. The output frequency can be locked with respect to the lithium $D$-line transitions for atomic physics applications. Furthermore, we obser...

  9. A new solid polymer electrolyte incorporating Li10GeP2S12 into a polyethylene oxide matrix for all-solid-state lithium batteries

    Science.gov (United States)

    Zhao, Yanran; Wu, Chuan; Peng, Gang; Chen, Xiaotian; Yao, Xiayin; Bai, Ying; Wu, Feng; Chen, Shaojie; Xu, Xiaoxiong

    2016-01-01

    Li10GeP2S12 (LGPS) is incorporated into polyethylene oxide (PEO) matrix to fabricate composite solid polymer electrolyte (SPE) membranes. The lithium ion conductivities of as-prepared composite membranes are evaluated, and the optimal composite membrane exhibits a maximum ionic conductivity of 1.21 × 10-3 S cm-1 at 80 °C and an electrochemical window of 0-5.7 V. The phase transition behaviors for electrolytes are characterized by DSC, and the possible reasons for their enhanced ionic conductivities are discussed. The LGPS microparticles, acting as active fillers incorporation into the PEO matrix, have a positive effect on the ionic conductivity, lithium ion transference number and electrochemical stabilities. In addition, two kinds of all-solid-state lithium batteries (LiFeO4/SPE/Li and LiCoO2/SPE/Li) are fabricated to demonstrate the good compatibility between this new SPE membrane and different electrodes. And the LiFePO4/Li battery exhibits fascinating electrochemical performance with high capacity retention (92.5% after 50 cycles at 60 °C) and attractive capacities of 158, 148, 138 and 99 mAh g-1 at current rates of 0.1 C, 0.2 C, 0.5 C and 1 C at 60 °C, respectively. It is demonstrated that this new composite SPE should be a promising electrolyte applied in solid state batteries based on lithium metal electrode.

  10. An all-solid-state screen-printed carbon paste reference electrode based on poly(3,4-ethylenedioxythiophene) as solid contact transducer

    International Nuclear Information System (INIS)

    The paper presents the design of an all-solid-state portable reference electrode based on a screen-printed carbon paste electrode suitable for rapid human serum testing. The electrode was covered by electropolymerized poly(3,4-ethylenedioxythiophene) (PEDOT) doped with poly(styrenesulfonate) (PSS) as an internal solid contact layer and polyvinyl chloride (PVC) membrane containing lipophilic anion and cation additives. The electrochemical properties of PEDOT(PSS) and PEDOT(PSS)/PVC film on a carbon paste electrode were studied by electrochemical impedance spectroscopy and cyclic voltammetry methods. The reference electrode exhibited good potential stability (for H+, Na+, K+, Ca2+, Cl− and CO2−3/HCO−3), good reproducibility and long-term stability. The structure is applied as reference electrodes in human serum pH analysis with pH ion selective planar electrodes, forming a serum pH sensor. The response time of such a pH sensor was 15 s and the sensitivity was −52.2 ± 1.0 mV per decade. Other properties, such as repeatability, reproducibility and stability, were also evaluated. Clinical trials were carried out and compared with the results obtained from the routine hospital electrolyte analyzer, which demonstrated that their analytical performance was closely matched. (paper)

  11. High Energy Density All Solid State Asymmetric Pseudocapacitors Based on Free Standing Reduced Graphene Oxide-Co3O4 Composite Aerogel Electrodes.

    Science.gov (United States)

    Ghosh, Debasis; Lim, Joonwon; Narayan, Rekha; Kim, Sang Ouk

    2016-08-31

    Modern flexible consumer electronics require efficient energy storage devices with flexible free-standing electrodes. We report a simple and cost-effective route to a graphene-based composite aerogel encapsulating metal oxide nanoparticles for high energy density, free-standing, binder-free flexible pseudocapacitive electrodes. Hydrothermally synthesized Co3O4 nanoparticles are successfully housed inside the microporous graphene aerogel network during the room temperature interfacial gelation at the Zn surface. The resultant three-dimensional (3D) rGO-Co3O4 composite aerogel shows mesoporous quasiparallel layer stack morphology with a high loading of Co3O4, which offers numerous channels for ion transport and a 3D interconnected network for high electrical conductivity. All solid state asymmetric pseudocapacitors employing the composite aerogel electrodes have demonstrated high areal energy density of 35.92 μWh/cm(2) and power density of 17.79 mW/cm(2) accompanied by excellent cycle life. PMID:27494271

  12. Generation of 3.5W high efficiency blue-violet laser by intracavity frequency-doubling of an all-solid-state tunable Ti:sapphire laser.

    Science.gov (United States)

    Ding, X; Wang, R; Zhang, H; Wen, W Q; Huang, L; Wang, P; Yao, J Q; Yu, X Y; Li, Z

    2008-03-31

    In this paper, we report a high power, high efficiency blue-violet laser obtained by intracavity frequency-doubling of an all-solid-state Q-switched tunable Ti:sapphire laser, which was pumped by a 532 nm intracavity frequency-doubled Nd:YAG laser. A beta-BaB2O4 (BBO) crystal was used for frequency-doubling of the Ti:sapphire laser and a V-shape folded three-mirror cavity was optimized to obtain high power high efficiency second harmonic generation (SHG). At an incident pump power of 22 W, the tunable output from 355 nm to 475 nm was achieved, involving the maximum average output of 3.5 W at 400 nm with an optical conversion efficiency of 16% from the 532 nm pump laser to the blue-violet output. The beam quality factor M(2) was measured to be Mx(2)=2.15, My(2)=2.38 for characterizing the tunable blue laser. PMID:18542555

  13. AC impedance analysis of ionic and electronic conductivities in electrode mixture layers for an all-solid-state lithium-ion battery

    Science.gov (United States)

    Siroma, Zyun; Sato, Tomohiro; Takeuchi, Tomonari; Nagai, Ryo; Ota, Akira; Ioroi, Tsutomu

    2016-06-01

    The ionic and electronic effective conductivities of an electrode mixture layers for all-solid-state lithium-ion batteries containing Li2Ssbnd P2S5 as a solid electrolyte were investigated by AC impedance measurements and analysis using a transmission-line model (TLM). Samples containing graphite (graphite electrodes) or LiNi0.5Co0.2Mn0.3O2 (NCM electrodes) as the active material were measured under a "substrate | sample | bulk electrolyte | sample | substrate" configuration (ion-electron connection) and a "substrate | sample | substrate" configuration (electron-electron connection). Theoretically, if the electronic resistance is negligibly small, which is the case with our graphite electrodes, measurement with the ion-electron connection should be effective for evaluating ionic conductivity. However, if the electronic resistance is comparable to the ionic resistance, which is the case with our NCM electrodes, the results with the ion-electron connection may contain some inherent inaccuracy. In this report, we theoretically and practically demonstrate the advantage of analyzing the results with the electron-electron connection, which gives both the ionic and electronic conductivities. The similarity of the behavior of ionic conductivity with the graphite and NCM electrodes confirms the reliability of this analysis.

  14. Electrochemical properties of an all-solid-state lithium-ion battery with an in-situ formed electrode material grown from a lithium conductive glass ceramics sheet

    Science.gov (United States)

    Amiki, Yuichi; Sagane, Fumihiro; Yamamoto, Kazuo; Hirayama, Tsukasa; Sudoh, Masao; Motoyama, Munekazu; Iriyama, Yasutoshi

    2013-11-01

    A lithium insertion reaction in a Li+ conductive glass ceramics solid electrolyte (lithium aluminum titanium phosphate: LATP) sheet produces an in-situ formed electrode active material, which operates at 2.35 V vs. Li/Li+ in the vicinity of the LATP-sheet/current-collector interface. Electron energy loss spectroscopy clarifies that titanium in the LATP sheet in the vicinity of the current collector/LATP-sheet interface is preferentially reduced by this lithium insertion reaction. Charge transfer resistance between the in-situ-formed-electrode and the LATP-sheet is less than 100 Ω cm2, which is smaller than that of the common LiPON/LiCoO2 interface. A thin film of LiCoO2 is deposited on one side of the LATP-sheet as a Li+ source for developing the in-situ formed electrode material. Eventually, a Pt/LATP-sheet/LiCoO2/Au multilayer is fabricated. The multilayer structure successfully works as an all-solid-state lithium-ion battery operating at 1.5 V. A redox peak of the battery is observed even at 100 mV s-1 in the potential sweep curve. Additionally, charge-discharge reactions are repeated stably even after 25 cycles.

  15. All-Solid-State High-Energy Asymmetric Supercapacitors Enabled by Three-Dimensional Mixed-Valent MnOx Nanospike and Graphene Electrodes.

    Science.gov (United States)

    Yang, Jie; Li, Guizhu; Pan, Zhenghui; Liu, Meinan; Hou, Yuan; Xu, Yijun; Deng, Hong; Sheng, Leimei; Zhao, Xinluo; Qiu, Yongcai; Zhang, Yuegang

    2015-10-14

    Three-dimensional (3D) nanostructures enable high-energy storage devices. Here we report a 3D manganese oxide nanospike (NSP) array electrode fabricated by anodization and subsequent electrodeposition. All-solid-state asymmetric supercapacitors were assembled with the 3D Al@Ni@MnOx NSP as the positive electrode, chemically converted graphene (CCG) as the negative electrode, and Na2SO4/poly(vinyl alcohol) (PVA) as the polymer gel electrolyte. Taking advantage of the different potential windows of Al@Ni@MnOx NSP and CCG electrodes, the asymmetric supercapacitor showed an ideal capacitive behavior with a cell voltage up to 1.8 V, capable of lighting up a red LED indicator (nominal voltage of 1.8 V). The device could deliver an energy density of 23.02 W h kg(-1) at a current density of 1 A g(-1). It could also preserve 96.3% of its initial capacitance at a current density of 2 A g(-1) after 10000 charging/discharging cycles. The remarkable performance is attributed to the unique 3D NSP array structure that could play an important role in increasing the effective electrode surface area, facilitating electrolyte permeation, and shortening the electron pathway in the active materials. PMID:26393403

  16. Disposable all-solid-state pH and glucose sensors based on conductive polymer covered hierarchical AuZn oxide.

    Science.gov (United States)

    Kim, Dong-Min; Cho, Seong Je; Cho, Chul-Ho; Kim, Kwang Bok; Kim, Min-Yeong; Shim, Yoon-Bo

    2016-05-15

    Poly(terthiophene benzoic acid) (pTBA) layered-AuZn alloy oxide (AuZnOx) deposited on the screen printed carbon electrode (pTBA/AuZnOx/SPCE) was prepared to create a disposable all-solid-state pH sensor at first. Further, FAD-glucose oxidase (GOx) was immobilized onto the pTBA/AuZnOx/SPCE to fabricate a glucose sensor. The characterizations of the sensor probe reveal that AuZnOx forms a homogeneous hierarchical structure, and that the polymerized pTBA layer on the alloy oxide surface captures GOx covalently. The benzoic acid group of pTBA coated on the probe layer synergetically improved the pH response of the alloy oxide and provide chemical binding sites to enzyme, which resulted in a Nernstian behavior (59.2 ± 0.5 mV/pH) in the pH range of 2-13. The experimental parameters affecting the glucose analysis were studied in terms of pH, temperature, humidity, and interferences. The sensor exhibited a fast response time <1s and a dynamic range between 30 and 500 mg/dL glucose with a detection limit of 17.23 ± 0.32 mg/dL. The reliabilities of the disposable pH and glucose sensors were examined for biological samples. PMID:26703994

  17. Wide bandgap engineering of (AlGa)2O3 films

    International Nuclear Information System (INIS)

    Bandgap tunable (AlGa)2O3 films were deposited on sapphire substrates by pulsed laser deposition (PLD). The deposited films are of high transmittance as measured by spectrophotometer. The Al content in films is almost the same as that in targets. The measurement of bandgap energies by examining the onset of inelastic energy loss in core-level atomic spectra using X-ray photoelectron spectroscopy is proved to be valid for determining the bandgap of (AlGa)2O3 films as it is in good agreement with the bandgap values from transmittance spectra. The measured bandgap of (AlGa)2O3 films increases continuously with the Al content covering the whole Al content range from about 5 to 7 eV, indicating PLD is a promising growth technology for growing bandgap tunable (AlGa)2O3 films.

  18. Energy Bandgap and Edge States in an Epitaxially Grown Graphene/h-BN Heterostructure

    Science.gov (United States)

    Hwang, Beomyong; Hwang, Jeongwoon; Yoon, Jong Keon; Lim, Sungjun; Kim, Sungmin; Lee, Minjun; Kwon, Jeong Hoon; Baek, Hongwoo; Sung, Dongchul; Kim, Gunn; Hong, Suklyun; Ihm, Jisoon; Stroscio, Joseph A.; Kuk, Young

    2016-08-01

    Securing a semiconducting bandgap is essential for applying graphene layers in switching devices. Theoretical studies have suggested a created bulk bandgap in a graphene layer by introducing an asymmetry between the A and B sub-lattice sites. A recent transport measurement demonstrated the presence of a bandgap in a graphene layer where the asymmetry was introduced by placing a graphene layer on a hexagonal boron nitride (h-BN) substrate. Similar bandgap has been observed in graphene layers on metal substrates by local probe measurements; however, this phenomenon has not been observed in graphene layers on a near-insulating substrate. Here, we present bulk bandgap-like features in a graphene layer epitaxially grown on an h-BN substrate using scanning tunneling spectroscopy. We observed edge states at zigzag edges, edge resonances at armchair edges, and bandgap-like features in the bulk.

  19. Energy Bandgap and Edge States in an Epitaxially Grown Graphene/h-BN Heterostructure

    Science.gov (United States)

    Hwang, Beomyong; Hwang, Jeongwoon; Yoon, Jong Keon; Lim, Sungjun; Kim, Sungmin; Lee, Minjun; Kwon, Jeong Hoon; Baek, Hongwoo; Sung, Dongchul; Kim, Gunn; Hong, Suklyun; Ihm, Jisoon; Stroscio, Joseph A.; Kuk, Young

    2016-01-01

    Securing a semiconducting bandgap is essential for applying graphene layers in switching devices. Theoretical studies have suggested a created bulk bandgap in a graphene layer by introducing an asymmetry between the A and B sub-lattice sites. A recent transport measurement demonstrated the presence of a bandgap in a graphene layer where the asymmetry was introduced by placing a graphene layer on a hexagonal boron nitride (h-BN) substrate. Similar bandgap has been observed in graphene layers on metal substrates by local probe measurements; however, this phenomenon has not been observed in graphene layers on a near-insulating substrate. Here, we present bulk bandgap-like features in a graphene layer epitaxially grown on an h-BN substrate using scanning tunneling spectroscopy. We observed edge states at zigzag edges, edge resonances at armchair edges, and bandgap-like features in the bulk. PMID:27503427

  20. Experimental realization of microwave photonic topological insulators

    Science.gov (United States)

    Dong, Jianwen

    2015-03-01

    Topological properties play a fundamental role in many physical phenomena. While topology focus on electronic systems, there has been a recent emergence of interest in exploring topological orders with photons. Recent experiments have demonstrated substantial progress towards the implementation of Hamiltonians with topological robustness, from microwave to visible frequency domains. Here, we will show the demonstration on nontrivial photonic bandgaps, as well as the topologically protected edge states. We designed and fabricated a metacrystal comprising non-resonant meta-atoms sandwiched between two metallic plates. Spin Chern number of photonic crystals is calculated based on group theory and accurately predicts topological characters of edge states in different gaps. Topologically nontrivial gaps are achieved by mode exchange at high symmetric k-points. Nontrivial bandgap was confirmed by experimentally measured transmission spectra and calculated nonzero spin Chern number. Gapless spin-filtered edge states were demonstrated experimentally by measuring Ez fields and Hz fields, as well as their phase differences. Robustness of the edge states were also observed when an obstacle is introduced near the edge.

  1. High dno/dT liquid crystals and their applications in a thermally tunable liquid crystal photonic crystal fiber

    DEFF Research Database (Denmark)

    Li, J.; Gauza, S.; Wu, S.-T.;

    2006-01-01

    crystal mixtures, designated as UCF-1 and UCF-2. The dn(o)/dT of UCF-1 is similar to 4x higher than that of 5CB at room temperature. By infiltrating UCF-1 into the air holes of a three-rod core photonic crystal fiber, we demonstrate a thermally tunable photonic bandgap fiber with tuning sensitivity of 27...

  2. Photonic Lantern

    CERN Document Server

    Leon-Saval, Sergio; Bland-Hawthorn, Joss

    2015-01-01

    Photonic lanterns allow for a low-loss transformation of a multimode waveguide into a discrete number of single-mode waveguides and vice versa, thus, enabling the use of single-mode photonic technologies in multimode systems. In this review, we will discuss the theory and function of the photonic lantern, along with several different variants of the technology. We will also discuss some of its applications in more detail.

  3. High-efficiency, monolithic, multi-bandgap, tandem photovoltaic energy converters

    Science.gov (United States)

    Wanlass, Mark W.

    2011-11-29

    A monolithic, multi-bandgap, tandem solar photovoltaic converter has at least one, and preferably at least two, subcells grown lattice-matched on a substrate with a bandgap in medium to high energy portions of the solar spectrum and at least one subcell grown lattice-mismatched to the substrate with a bandgap in the low energy portion of the solar spectrum, for example, about 1 eV.

  4. Microwave photonics

    CERN Document Server

    Lee, Chi H

    2006-01-01

    Wireless, optical, and electronic networks continue to converge, prompting heavy research into the interface between microwave electronics, ultrafast optics, and photonic technologies. New developments arrive nearly as fast as the photons under investigation, and their commercial impact depends on the ability to stay abreast of new findings, techniques, and technologies. Presenting a broad yet in-depth survey, Microwave Photonics examines the major advances that are affecting new applications in this rapidly expanding field.This book reviews important achievements made in microwave photonics o

  5. Photonic glasses

    CERN Document Server

    Gan, Fuxi

    2006-01-01

    This book introduces the fundamental mechanism of photonic glasses - the linear and nonlinear optical effects in glass under intense light irradiation: phot-induced absorption, refraction, polarization, frequency, coherence and monochromaticity changes. Emphasis is placed on new developments in the structure, spectroscopy and physics of new glassy materials for photonics applications, such as optical communication, optical data storage, new lasers and new photonic components and devices. The book presents the research results of the authors in new glasses for photonics over the last decade. Sa

  6. Controlling spontaneous emission of light by photonic crystals

    DEFF Research Database (Denmark)

    Lodahl, Peter

    2005-01-01

    Photonic bandgap crystals were proposed almost two decades ago as a unique tool for controlling propagation and emission of light. Since then the research field of photonic crystals has exploded and many beautiful demonstrations of the use of photonic crystals and fibers for molding light...... propagation have appeared that hold great promises for integrated optics. These major achievements solidly demonstrate the ability to control propagation of light. In contrast, an experimental demonstration of the use of photonic crystals for timing the emission of light has so far lacked. In a recent...... publication in Nature, we have demonstrated experimentally that both the direction and time of spontaneous emission can be controlled, thereby confirming the original proposal by Eli Yablonovich that founded the field of photonic crystals. We believe that this work opens new opportunities for solid...

  7. Photonic bandgap amorphous chalcogenide thin films with multilayered structure grown by pulsed laser deposition method

    Science.gov (United States)

    Zhang, Shao-qian; Němec, Petre; Nazabal, Virginie; Jin, Yu-qi

    2016-05-01

    Amorphous chalcogenide thin films were fabricated by the pulsed laser deposition technique. Thereafter, the stacks of multilayered thin films for reflectors and microcavity were designed for telecommunication wavelength. The prepared multilayered thin films for reflectors show good compatibility. The microcavity structure consists of Ge25Ga5Sb10S65 (doped with Er3+) spacer layer surrounded by two 5-layer As40Se60/Ge25Sb5S70 reflectors. Scanning/transmission electron microscopy results show good periodicity, great adherence and smooth interfaces between the alternating dielectric layers, which confirms a suitable compatibility between different materials. The results demonstrate that the chalcogenides can be used for preparing vertical Bragg reflectors and microcavity with high quality.

  8. Stability and bandgaps of layered perovskites for one- and two-photon water splitting

    DEFF Research Database (Denmark)

    Castelli, Ivano Eligio; García Lastra, Juan Maria; Hüser, Falco;

    2013-01-01

    Direct production of hydrogen from water and sunlight requires stable and abundantly available semiconductors with well positioned band edges relative to the water red-ox potentials. We have used density functional theory (DFT) calculations to investigate 300 oxides and oxynitrides in the Ruddles...... against G0W0@LDA gaps for 20 previously identified oxides and oxynitrides in the cubic perovskite structure....

  9. Progress towards photonic crystal quantum cascade laser

    OpenAIRE

    Walker, C L; Farmer, C. D.; Stanley, C. R.; Ironside, C. N.

    2004-01-01

    The work describes recent progress in the design, simulation, implementation and characterisation of photonic crystal (PhC) GaAs-based quantum cascade lasers (QCLs). The benefits of applying active PhC confinement around a QCL cavity are explained, highlighting a route to reduced threshold current operation. Design of a suitable PhC has been performed using published bandgap maps; simulation results of this PhC show a wide, high reflectivity stopband. Implementation of the PhC for the device ...

  10. Photonic crystal fibres - a variety of applications

    DEFF Research Database (Denmark)

    Bjarklev, Anders Overgaard; Riishede, Jesper

    2002-01-01

    bandgap fibers. These fibers have today reached a level of maturity where they may be used as building blocks for a variety of new applications. Today's research is focusing increasingly on applications of the fibres, thus redirecting earlier focus on crystal fibers themselves and their unique guiding...... mechanisms. Some of the new applications that are receiving a significant amount of attention are based on nonlinear effects-super continuum generation and applications of such being highly studied examples. In this presentation, we will discuss the basic properties of photonic crystal fibers and highlight...

  11. Advances in wide bandgap SiC for optoelectronics

    DEFF Research Database (Denmark)

    Ou, Haiyan; Ou, Yiyu; Argyraki, Aikaterini;

    2014-01-01

    Silicon carbide (SiC) has played a key role in power electronics thanks to its unique physical properties like wide bandgap, high breakdown field, etc. During the past decade, SiC is also becoming more and more active in optoelectronics thanks to the progress in materials growth and nanofabrication....... This paper will review the advances in fluorescent SiC for white light-emitting diodes, covering the poly-crystalline doped SiC source material growth, single crystalline epitaxy growth of fluorescent SiC, and nanofabrication of SiC to enhance the extraction efficiency for fluorescent SiC based white...

  12. New Curvature-Compensated CMOS Bandgap Voltage Reference

    Institute of Scientific and Technical Information of China (English)

    Lu Shen; Ning Ning; Qi Yu; Yan Luo; Chun-Sheng Li

    2007-01-01

    A novel curvaturecompensated CMOS bandgap voltage reference is presented. The reference utilizes two first order temperature compensations generated from the nonlinearity of the finite current gain β of vertical pnp bipolar transistor. The proposed circuit,designed in a standard 0.18 μm CMOS process, achieves a good temperature coefficient of 2.44 ppm/℃ with temperature range from 40 ℃ to 85 ℃, and about 4 mV supply voltage variation in the range from 1.4 V to 2.4 V. With a 1.8 V supply voltage, the power supply rejection ratio is 56 dB at 10 MHz.

  13. Properties of the slab modes in photonic crystal optical waveguides

    OpenAIRE

    Adibi, Ali; Xu, Yong; Lee, Reginald K.; Yariv, Amnon; Scherer, Axel

    2000-01-01

    We show that by placing a slab of semiconductor material between two photonic bandgap (PBG) mirrors, waveguide modes at frequencies out of the PBC; can he obtained. These modes are similar to the modes of a conventional dielectric slab waveguide. Using these modes, we can obtain very good coupling between a PEG waveguide and a dielectric slab waveguide with similar slab properties. We discuss the properties of these slab modes and outline the guideline for the optimization elf the PRC wavegui...

  14. Overcoming the Cut-Off Charge Transfer Bandgaps at the PbS Quantum Dot Interface

    KAUST Repository

    El-Ballouli, Ala'a O.

    2015-11-17

    Light harvesting from large size of semiconductor PbS quantum dots (QDs) with a bandgap of less than 1 eV is one of the greatest challenges precluding the development of PbS QD-based solar cells because the interfacial charge transfer (CT) from such QDs to the most commonly used electron acceptor materials is very inefficient, if it occurs at all. Thus, an alternative electron-accepting unit with a new driving force for CT is urgently needed to harvest the light from large-sized PbS QDs. Here, a cationic porphyrin is utilized as a new electron acceptor unit with unique features that bring the donor–acceptor components into close molecular proximity, allowing ultrafast and efficient electron transfer for QDs of all sizes, as inferred from the drastic photoluminescence quenching and the ultrafast formation of the porphyrin anionic species. The time-resolved results clearly demonstrate the possibility of modulating the electron transfer process between PbS QDs and porphyrin moieties not only by the size quantization effect but also by the interfacial electrostatic interaction between the positively charged porphyrin and the negatively charged QDs. This approach provides a new pathway for engineering QD-based solar cells that make the best use of the diverse photons making up the Sun\\'s broad irradiance spectrum.

  15. Interface induce growth of intermediate layer for bandgap engineering insights into photoelectrochemical water splitting

    Science.gov (United States)

    Zhang, Jian; Zhang, Qiaoxia; Wang, Lianhui; Li, Xing’Ao; Huang, Wei

    2016-06-01

    A model of interface induction for interlayer growing is proposed for bandgap engineering insights into photocatalysis. In the interface of CdS/ZnS core/shell nanorods, a lamellar solid solution intermediate with uniform thickness and high crystallinity was formed under interface induction process. Merged the novel charge carrier transfer layer, the photocurrent of the core/shell/shell nanorod (css-NR) array was significantly improved to 14.0 mA cm‑2 at 0.0 V vs. SCE, nearly 8 times higher than that of the perfect CdS counterpart and incident photon to electron conversion efficiency (IPCE) values above 50% under AM 1.5G irradiation. In addition, this array photoelectrode showed excellent photocatalytic stability over 6000 s. These results suggest that the CdS/Zn1‑xCdxS/ZnS css-NR array photoelectrode provides a scalable charge carrier transfer channel, as well as durability, and therefore is promising to be a large-area nanostructured CdS-based photoanodes in photoelectrochemical (PEC) water splitting system.

  16. Interface induce growth of intermediate layer for bandgap engineering insights into photoelectrochemical water splitting.

    Science.gov (United States)

    Zhang, Jian; Zhang, Qiaoxia; Wang, Lianhui; Li, Xing'ao; Huang, Wei

    2016-01-01

    A model of interface induction for interlayer growing is proposed for bandgap engineering insights into photocatalysis. In the interface of CdS/ZnS core/shell nanorods, a lamellar solid solution intermediate with uniform thickness and high crystallinity was formed under interface induction process. Merged the novel charge carrier transfer layer, the photocurrent of the core/shell/shell nanorod (css-NR) array was significantly improved to 14.0 mA cm(-2) at 0.0 V vs. SCE, nearly 8 times higher than that of the perfect CdS counterpart and incident photon to electron conversion efficiency (IPCE) values above 50% under AM 1.5G irradiation. In addition, this array photoelectrode showed excellent photocatalytic stability over 6000 s. These results suggest that the CdS/Zn1-xCdxS/ZnS css-NR array photoelectrode provides a scalable charge carrier transfer channel, as well as durability, and therefore is promising to be a large-area nanostructured CdS-based photoanodes in photoelectrochemical (PEC) water splitting system. PMID:27250648

  17. Extreme group index measured and calculated in 2D SOI-based photonic crystal waveguides

    DEFF Research Database (Denmark)

    Lavrinenko, Andrei; Jacobsen, Rune Shim; Fage-Pedersen, Jacob; Frandsen, Lars Hagedorn; Zsigri, Beata; Peucheret, Christophe; Borel, Peter Ingo

    2005-01-01

    lattice of air-holes in the 216-nm thick silicon layer in an SOI material. Experimental transmission spectra show a mode cut-off around 1562.5 nm for the fundamental photonic bandgap mode. In order to measure and model the group index of modes in the PCW, a time-of-flight (ToF) method is applied....

  18. Photo-Induced Bandgap Renormalization Governs the Ultrafast Response of Single-Layer MoS2.

    Science.gov (United States)

    Pogna, Eva A A; Marsili, Margherita; De Fazio, Domenico; Dal Conte, Stefano; Manzoni, Cristian; Sangalli, Davide; Yoon, Duhee; Lombardo, Antonio; Ferrari, Andrea C; Marini, Andrea; Cerullo, Giulio; Prezzi, Deborah

    2016-01-26

    Transition metal dichalcogenides (TMDs) are emerging as promising two-dimensional (2D) semiconductors for optoelectronic and flexible devices. However, a microscopic explanation of their photophysics, of pivotal importance for the understanding and optimization of device operation, is still lacking. Here, we use femtosecond transient absorption spectroscopy, with pump pulse tunability and broadband probing, to monitor the relaxation dynamics of single-layer MoS2 over the entire visible range, upon photoexcitation of different excitonic transitions. We find that, irrespective of excitation photon energy, the transient absorption spectrum shows the simultaneous bleaching of all excitonic transitions and corresponding red-shifted photoinduced absorption bands. First-principle modeling of the ultrafast optical response reveals that a transient bandgap renormalization, caused by the presence of photoexcited carriers, is primarily responsible for the observed features. Our results demonstrate the strong impact of many-body effects in the transient optical response of TMDs even in the low-excitation-density regime. PMID:26691058

  19. Observation of excited-state excitons and band-gap renormalization in hole-doped carbon nanotubes using photoluminescence excitation spectroscopy

    OpenAIRE

    Kimoto, Yoshio; Okano, Makoto; Kanemitsu, Yoshihiko

    2013-01-01

    The higher Rydberg states of the E11 exciton in undoped and hole-doped single-walled carbon nanotubes (SWCNTs) were studied using one- and two-photon photoluminescence excitation spectroscopy. Increasing the hole-dopant concentration resulted in a redshift of the first excited state (2g) and a blueshift of the ground state (1u) of the E11 exciton. From the redshift of higher Rydberg states, we found that a reduction of the band-gap energy occurs in hole-doped SWCNTs. These findings show that ...

  20. Miniature all-solid-state heterostructure nanowire Li-ion batteries as a tool for engineering and structural diagnostics of nanoscale electrochemical processes

    Science.gov (United States)

    Oleshko, Vladimir P.; Lam, Thomas; Ruzmetov, Dmitry; Haney, Paul; Lezec, Henri J.; Davydov, Albert V.; Krylyuk, Sergiy; Cumings, John; Talin, A. Alec

    2014-09-01

    Complex interfacial phenomena and phase transformations that govern the operation of Li-ion batteries require detailed nanoscale 3D structural and compositional characterization that can be directly related to their capacity and electrical transport properties. For this purpose, we have designed model miniature all solid-state radial heterostructure Li-ion batteries composed of LiCoO2 cathode, LiPON electrolyte and amorphous Si anode shells, which were deposited around metallized high-aspect-ratio Si nanowires as a scaffolding core. Such diagnostic batteries, the smallest, complete secondary Li-ion batteries realized to date, were specifically designed for in situ electrical testing in a field-emission scanning electron microscope and/or transmission electron microscope. The results of electrochemical testing were described in detail in a previous publication (Nano Lett., 2012, 12, 505-511). The model Li-ion batteries allow analysis of the correlations between electrochemical properties and their structural evolution during cycling in various imaging, diffraction and spectroscopic modes down to the atomic level. Employing multimode analytical scanning/transmission electron microscopy imaging coupled with correlative multivariate statistical analysis and tomography, we have analyzed and quantified the 3D morphological and structural arrangement of the batteries, including textured platelet-like LiCoO2 nanocrystallites, buried electrode-electrolyte interfaces and hidden internal defects to clarify effects of scaling on a battery's electrochemical performance. Characterization of the nanoscale interfacial processes using model heterostructure nanowire-based Li-ion batteries provides useful guidelines for engineering of prospective nano-sized building blocks in future electrochemical energy storage systems.Complex interfacial phenomena and phase transformations that govern the operation of Li-ion batteries require detailed nanoscale 3D structural and compositional