WorldWideScience

Sample records for all-carbon quaternary stereogenic

  1. Synthetic Strategies toward Natural Products Containing Contiguous Stereogenic Quaternary Carbon Atoms.

    Science.gov (United States)

    Büschleb, Martin; Dorich, Stéphane; Hanessian, Stephen; Tao, Daniel; Schenthal, Kyle B; Overman, Larry E

    2016-03-18

    Strategies for the total synthesis of complex natural products that contain two or more contiguous stereogenic quaternary carbon atoms in their intricate structures are reviewed with 12 representative examples. Emphasis has been put on methods to create quaternary carbon stereocenters, including syntheses of the same natural product by different groups, thereby showcasing the diversity of thought and individual creativity. A compendium of selected natural products containing two or more contiguous stereogenic quaternary carbon atoms and key reactions in their total or partial syntheses is provided in the Supporting Information.

  2. Toward the Enantioselective Total Synthesis of Lyngbyatoxin A: On the Stereocontrolled Introduction of the Quaternary Stereogenic Centre

    DEFF Research Database (Denmark)

    Tønder, Janne Ejrnæs; Tanner, David Ackland

    2003-01-01

    This paper deals with an approach to the enantioselective total synthesis of Lyngbyatoxin A, with focus on the stereocontrolled introduction of the quaternary stereogenic centre. The key step in the synthesis involves an enantiospecific Lewis-acid mediated rearrangement of chiral vinyl epoxides c...

  3. Ligand-enabled multiple absolute stereocontrol in metal-catalysed cycloaddition for construction of contiguous all-carbon quaternary stereocentres.

    Science.gov (United States)

    Ohmatsu, Kohsuke; Imagawa, Naomichi; Ooi, Takashi

    2014-01-01

    The development of a general catalytic method for the direct and stereoselective construction of contiguous all-carbon quaternary stereocentres remains a formidable challenge in chemical synthesis. Here, we report a highly enantio- and diastereoselective [3+2] annulation reaction of 5-vinyloxazolidinones and activated trisubstituted alkenes catalysed by a palladium complex bearing a newly devised phosphine ligand with a chiral ammonium salt component, which enables the single-step construction of three contiguous stereocentres, including vicinal all-carbon quaternary stereocentres, in a five-membered heterocyclic framework. This stereoselective cycloaddition protocol relies on the remarkable ability of the chiral ligand to rigorously control the absolute stereochemistry of each chiral centre associated with the multiple bond-forming events, and provides a reliable catalytic process for the asymmetric synthesis of densely functionalized pyrrolidines.

  4. Modular Terpenoid Construction via Catalytic Enantioselective Formation of All-Carbon Quaternary Centers: Total Synthesis of Oridamycin A, Triptoquinones B and C, and Isoiresin.

    Science.gov (United States)

    Feng, Jiajie; Noack, Florian; Krische, Michael J

    2016-09-28

    Total syntheses of oridamycin A, triptoquinones B and C, and isoiresin are accomplished from a common intermediate prepared via iridium-catalyzed alcohol C-H tert-(hydroxy)prenylation - a byproduct-free process that forms an all-carbon quaternary stereocenter with excellent control of diastereo- and enantioselectivity.

  5. Palladium-catalyzed asymmetric alkylation in the synthesis of cyclopentanoid and cycloheptanoid core structures bearing all-carbon quaternary stereocenters

    KAUST Repository

    Hong, Allen Y.

    2011-12-01

    General catalytic asymmetric routes toward cyclopentanoid and cycloheptanoid core structures embedded in numerous natural products have been developed. The central stereoselective transformation in our divergent strategies is the enantioselective decarboxylative alkylation of seven-membered β-ketoesters to form α-quaternary vinylogous esters. Recognition of the unusual reactivity of β-hydroxyketones resulting from the addition of hydride or organometallic reagents enabled divergent access to γ-quaternary acylcyclopentenes through a ring contraction pathway or γ-quaternary cycloheptenones through a carbonyl transposition pathway. Synthetic applications of these compounds were explored through the preparation of mono-, bi-, and tricyclic derivatives that can serve as valuable intermediates for the total synthesis of complex natural products. This work complements our previous work with cyclohexanoid systems.

  6. Palladium-Catalyzed Asymmetric Conjugate Addition of Arylboronic Acids to Five-, Six-, and Seven-Membered β-Substituted Cyclic Enones: Enantioselective Construction of All-Carbon Quaternary Stereocenters

    KAUST Repository

    Kikushima, Kotaro

    2011-05-11

    The first enantioselective Pd-catalyzed construction of all-carbon quaternary stereocenters via 1,4-addition of arylboronic acids to β-substituted cyclic enones is reported. Reaction of a wide range of arylboronic acids and cyclic enones using a catalyst prepared from Pd(OCOCF(3))(2) and a chiral pyridinooxazoline ligand yields enantioenriched products bearing benzylic stereocenters. Notably, this transformation is tolerant to air and moisture, providing a practical and operationally simple method of synthesizing enantioenriched all-carbon quaternary stereocenters.

  7. Stereogenicity revisited. Proposal of holantimers for comprehending the relationship between stereogenicity and chirality.

    Science.gov (United States)

    Fujita, Shinsaku

    2004-04-30

    The close relationship between stereogenicity and chirality has frequently caused serious confusion in the stereochemistry of organic molecules and inorganic complexes. To clarify the entangled relationship between them, we have proposed the concept of "holantimer". In addition, we have newly defined the concept of "stereoisogram" in order to correlate a set of stereoiomers based on holantimeric and enantiomeric relationships. These concepts have been applied to tetrahedral organic molecules as well as to square-planar inorganic complexes. The stereogenicity characterized by a stereoisogram has been called "RS-stereogenicity", which has been clarified to be a property that should be correlated to chirality. The stereoisograms of tetrahedral molecules have been examined and classified into five types, i.e., type I (chiral/RS-stereogenic), type II (chiral/RS-astereogenic), type III (chiral/RS-stereogenic), type IV (achiral/RS-astereogenic), and type V (achiral/RS-stereogenic), where RS descriptors are concluded to be specified in cases of types I, III, and V. On the other hand, the stereoisograms of square-planar complexes have been classified to two types, i.e., type II and type IV. As a result, the confusion on the RS-nomenclature has been concluded to appear within the RS-stereogenic relationships. Such a new viewpoint of stereogenicity and chirality as described in the present paper provides us with a methodology for restructuring stereochemistry.

  8. Stereocontrolled Introduction of the Quaternary Stereogenic Centre in Lyngbyatoxin A

    DEFF Research Database (Denmark)

    Tønder, Janne Ejrnæs; Tanner, David Ackland

    , a methodology developed by Jung et al(1). For model studies, the requisite vinyl epoxides were obtained by Sharpless asymmetric epoxidation of the corresponding allylic alcohols, followed by a TPAP oxidation and a Wittig reaction. It was observed that the choice of protective group on the indole nitrogen in had...... was the desired aldehyde resulting from vinyl migration. The aldehyde functionality then serves as a convenient “handle” for further elaboration. 1) Jung, M. E.; D'Amico, D. C. J. Am. Chem. Soc. 1995, 117, 7379-7388....

  9. All-carbon molecular tunnel junctions.

    Science.gov (United States)

    Yan, Haijun; Bergren, Adam Johan; McCreery, Richard L

    2011-11-30

    This Article explores the idea of using nonmetallic contacts for molecular electronics. Metal-free, all-carbon molecular electronic junctions were fabricated by orienting a layer of organic molecules between two carbon conductors with high yield (>90%) and good reproducibility (rsd of current density at 0.5 V carbon devices exhibit current density-voltage (J-V) behavior similar to those with metallic Cu top contacts. However, the all-carbon devices display enhanced stability to bias extremes and greatly improved thermal stability. Completed carbon/nitroazobenzene(NAB)/carbon junctions can sustain temperatures up to 300 °C in vacuum for 30 min and can be scanned at ±1 V for at least 1.2 × 10(9) cycles in air at 100 °C without a significant change in J-V characteristics. Furthermore, these all-carbon devices can withstand much higher voltages and current densities than can Cu-containing junctions, which fail upon oxidation and/or electromigration of the copper. The advantages of carbon contacts stem mainly from the strong covalent bonding in the disordered carbon materials, which resists electromigration or penetration into the molecular layer, and provides enhanced stability. These results highlight the significance of nonmetallic contacts for molecular electronics and the potential for integration of all-carbon molecular junctions with conventional microelectronics.

  10. The diastereoselective synthesis of octahedral cationic iridium hydride complexes with a stereogenic metal centre.

    Science.gov (United States)

    Humbert, Nicolas; Mazet, Clément

    2016-08-23

    We report herein the highly diastereoselective synthesis of octahedral cationic Ir(iii) hydride complexes with a stereogenic metal centre following various strategies. The configurational stability of these compounds has also been investigated.

  11. Stereocontrolled synthesis of 1,5-stereogenic centers through three-carbon homologation of boronic esters.

    Science.gov (United States)

    Unsworth, Phillip J; Leonori, Daniele; Aggarwal, Varinder K

    2014-09-08

    Allylic pinacol boronic esters are stable toward 1,3-borotropic rearrangement. We developed a Pd(II)-mediated isomerization process that gives di- or trisubstituted allylic boronic esters with high E selectivity. The combination of this method with lithiation-borylation enables the synthesis of carbon chains that bear 1,5-stereogenic centers. The utility of this method has been demonstrated in a formal synthesis of (+)-jasplakinolide.

  12. Determination of the absolute configurations at stereogenic centers in the presence of axial chirality.

    Science.gov (United States)

    Polavarapu, Prasad L; Jeirath, Neha; Kurtán, Tibor; Pescitelli, Gennaro; Krohn, Karsten

    2009-01-01

    Cephalochromin, a homodimeric naphthpyranone natural product, contains both axial chirality due to the hindered rotation along the biaryl axis and central chirality due to the C-2, C-2' stereogenic centers of the fused pyranone ring. For determining the absolute configurations (ACs) of central chirality elements, different chiroptical spectroscopic methods, namely vibrational circular dichroism (VCD), electronic circular dichroism (ECD), and optical rotation (OR), have been used. From these experimental data, in conjunction with corresponding quantum chemical predictions at B3LYP/6-311G* level, it is found that the ECD spectra of cephalochromin are dominated by its axial chirality and are not suitable to distinguish the (aS,2S,2'S) and (aS,2R,2'R) diastereomers and hence to determine the ACs of the central chirality elements. OR signs also did not distinguish the (aS,2S,2'S) and (aS,2R,2'R) diastereomers. On other hand, VCD spectrum of cephalochromin exhibited separate spectral features attributable to axial chirality and stereogenic centers, thereby allowing the determination of both types of chirality elements. This is the first investigation demonstrating that, because of vibrations specific to the studied stereogenic centers, VCD spectroscopy can be used to simultaneously determine the ACs of axial and central chirality elements whenever other chiroptical methods (ECD and OR) fail to report on them.

  13. Unusual High Oxygen Reduction Performance in All-Carbon Electrocatalysts

    Science.gov (United States)

    Wei, Wei; Tao, Ying; Lv, Wei; Su, Fang-Yuan; Ke, Lei; Li, Jia; Wang, Da-Wei; Li, Baohua; Kang, Feiyu; Yang, Quan-Hong

    2014-09-01

    Carbon-based electrocatalysts are more durable and cost-effective than noble materials for the oxygen reduction reaction (ORR), which is an important process in energy conversion technologies. Heteroatoms are considered responsible for the excellent ORR performance in many carbon-based electrocatalysts. But whether an all-carbon electrocatalyst can effectively reduce oxygen is unknown. We subtly engineered the interfaces between planar graphene sheets and curved carbon nanotubes (G-CNT) and gained a remarkable activity/selectivity for ORR (larger current, and n = 3.86, ~93% hydroxide + ~7% peroxide). This performance is close to that of Pt; and the durability is much better than Pt. We further demonstrate the application of this G-CNT hybrid as an all-carbon cathode catalyst for lithium oxygen batteries.We speculate that the high ORR activity of this G-CNT hybrid stems from the localized charge separation at the interface of the graphene and carbon nanotube, which results from the tunneling electron transfer due to the Fermi level mismatch on the planar and curved sp2 surfaces. Our result represents a conceptual breakthrough and pioneers the new avenues towards practical all-carbon electrocatalysis.

  14. Noncovalent Substrate-Directed Enantioselective Heck Reactions: Synthesis of S- and P-Stereogenic Heterocycles.

    Science.gov (United States)

    de Azambuja, Francisco; Carmona, Rafaela C; Chorro, Tomaz H D; Heerdt, Gabriel; Correia, Carlos Roque D

    2016-08-01

    S- and P-Stereogenic heterocycles were synthesized by a remarkably simple enantioselective Heck desymmetrization reaction based on the unprecedented noncovalent directing effect of S=O and P=O functionalities. Selected prochiral symmetric substrates were efficiently arylated using the recently disclosed chiral PyraBOx ligand under mild and open-flask reaction conditions. Several five-membered aryl- sulfones, sulfoxides, and phosphine oxides were synthesized in good to excellent yields, in good to high diastereoselectivity, and enantiomeric ratios up to 98:2. Theoretical calculations also support the noncovalent directing effect of the S=O and P=O functionalities during the arylation process.

  15. P-Stereogenic Phosphines for the Stabilisation of Metal Nanoparticles. A Surface State Study

    Directory of Open Access Journals (Sweden)

    Eva Raluy

    2016-12-01

    Full Text Available Palladium and ruthenium nanoparticles have been prepared following the organometallic precursor decomposition methodology, under dihydrogen pressure and in the presence of borane protected P-stereogenic phosphines. NMR (Nuclear Magnetic Resonance monitoring of the corresponding syntheses has permitted to determine the optimal metal/ligand ratio for leading to small and well-dispersed nanoparticles. Exchange ligand reactions of the as-prepared materials have proven the strong interaction of the phosphines with the metal surface; only oxidative treatment using hydrogen peroxide could release the phosphine-based stabiliser from the metal surface. Pd and Ru nanoparticles have been evaluated in hydrogenation reactions, confirming the robustness of the stabilisers, which selectively permitted the hydrogenation of exocyclic C=C bonds, preventing the coordination of the aromatic rings and as a result, their hydrogenation.

  16. Stereogeneous construction – fabric-formed concrete as material and process

    DEFF Research Database (Denmark)

    Manelius, Anne-Mette

    2012-01-01

    På engelsk: This paper contributes to studies of architectural potentials of fabric formwork for concrete by seeking to establish a theoretical concept that evaluates qualities of materials and principles of construction as well as aspects of the expression of concrete construction. Through...... planning and teaching workshops with students, categorizing and interpreting experimental data, and reflecting and communicating knowledge, the concept Stereogeneity developed as a response to questions about the nature of concrete cast in fabric forms and the relation between the molded and the mold....... The word describes concrete as material and process. Fabric Formwork is the pivotal formwork-tectonic topic of investigation in the experimental and analytical parts of the thesis work on which this paper is based. The youth of the architectural application of construction methods for fabric formwork...

  17. Catalytic asymmetric synthesis of enantioenriched heterocycles bearing a C-CF3 stereogenic center.

    Science.gov (United States)

    Huang, Yi-Yong; Yang, Xing; Chen, Zhuo; Verpoort, Francis; Shibata, Norio

    2015-06-08

    Given the important agricultural and medicinal application of optically pure heterocycles bearing a trifluoromethyl group at the stereogenic carbon center in the heterocyclic framework, the exploration of efficient and practical synthetic strategies to such types of molecules remains highly desirable. Catalytic enantioselective synthesis has one clear advantage that it is more cost-effective than other synthetic methods, but remains limited by challenges in achieving excellent yield and stereoselectivities with a low catalyst loading. Thus far, numerous models of organo- and organometal-catalyzed asymmetric reactions have been exploited to achieve this elusive goal over the past decade. This review article describes recent progress on this research topic, and focuses on an understanding of the catalytic asymmetric protocols exemplified in the catalytic enantioselective synthesis of a wide range of complex enantioenriched trifluoromethylated heterocycles.

  18. Carbon nanotubes functionalized by salts containing stereogenic heteroatoms as electrodes in their battery cells

    Directory of Open Access Journals (Sweden)

    Zdanowska Sandra

    2016-12-01

    Full Text Available This paper concentrates on electrochemical properties of groups of multi-walled carbon nanotubes (MWCNT functionalized with substituents containing a stereogenic heteroatom bonded covalently to the surface of the carbon nanotube. This system was tested in Swagelok-type cells. The cells comprised a system (functionalized CNT with salts containing S and P atoms with a working electrode, microfiber separators soaked with electrolyte solution, and a lithium foil counter/reference (commercial LiCoO2 electrode. The electrolyte solution was 1 M LiPF6 in propylene carbonate. Using standard techniques (cyclic voltammetry/chronopotentiometry, galvanostatic cycling was performed on the cells at room temperature with a CH Instruments Model 600E potentiostat/galvanostat electrochemical measurements. Methods of functionalization CNT were compared in terms of the electrochemical properties of the studied systems. In all systems, the process of charge/discharge was observed.

  19. Attempts to prepare an all-carbon indigoid system

    Directory of Open Access Journals (Sweden)

    Şeref Yildizhan

    2015-03-01

    Full Text Available First attempts are described to prepare a precursor for an all-carbon analog of indigo, the tetracyclic triene 4. Starting from indan-2-one (9 the α-methylene ketone 13 was prepared. Upon subjecting this compound to a McMurry coupling reaction, it dimerized to the bis-indene derivative 17, rather than providing the tetramethyl derivative of 4, the hydrocarbon 14. In a second approach, indan-1-one (18 was dimerized to the conjugated enedione 21 through the bis-1-indene dimer 19. All attempts to methylenate 21 failed, however. When 19 was treated with the Tebbe reagent, the dimer 23 was produced, presumably through a Cope reaction of the intermediately generated isomer 22. The bis-indene derivative 23 can be alkylated with 1,2-dibromoethane to produce a 1:1 mixture of the spiro compounds 24 and 25. Although 9 could be reductively dimerized to 30, the conversion of this olefin to 14 failed.

  20. Flexible all-carbon photovoltaics with improved thermal stability

    Science.gov (United States)

    Tang, Chun; Ishihara, Hidetaka; Sodhi, Jaskiranjeet; Chen, Yen-Chang; Siordia, Andrew; Martini, Ashlie; Tung, Vincent C.

    2015-04-01

    The structurally robust nature of nanocarbon allotropes, e.g., semiconducting single-walled carbon nanotubes (SWCNTs) and C60s, makes them tantalizing candidates for thermally stable and mechanically flexible photovoltaic applications. However, C60s rapidly dissociate away from the basal of SWCNTs under thermal stimuli as a result of weak intermolecular forces that "lock up" the binary assemblies. Here, we explore use of graphene nanoribbons (GNRs) as geometrically tailored protecting layers to suppress the unwanted dissociation of C60s. The underlying mechanisms are explained using a combination of molecular dynamics simulations and transition state theory, revealing the temperature dependent disassociation of C60s from the SWCNT basal plane. Our strategy provides fundamental guidelines for integrating all-carbon based nano-p/n junctions with optimized structural and thermal stability. External quantum efficiency and output current-voltage characteristics are used to experimentally quantify the effectiveness of GNR membranes under high temperature annealing. Further, the resulting C60:SWCNT:GNR ternary composites display excellent mechanical stability, even after iterative bending tests.

  1. Coaxial fiber supercapacitor using all-carbon material electrodes.

    Science.gov (United States)

    Le, Viet Thong; Kim, Heetae; Ghosh, Arunabha; Kim, Jaesu; Chang, Jian; Vu, Quoc An; Pham, Duy Tho; Lee, Ju-Hyuck; Kim, Sang-Woo; Lee, Young Hee

    2013-07-23

    We report a coaxial fiber supercapacitor, which consists of carbon microfiber bundles coated with multiwalled carbon nanotubes as a core electrode and carbon nanofiber paper as an outer electrode. The ratio of electrode volumes was determined by a half-cell test of each electrode. The capacitance reached 6.3 mF cm(-1) (86.8 mF cm(-2)) at a core electrode diameter of 230 μm and the measured energy density was 0.7 μWh cm(-1) (9.8 μWh cm(-2)) at a power density of 13.7 μW cm(-1) (189.4 μW cm(-2)), which were much higher than the previous reports. The change in the cyclic voltammetry characteristics was negligible at 180° bending, with excellent cycling performance. The high capacitance, high energy density, and power density of the coaxial fiber supercapacitor are attributed to not only high effective surface area due to its coaxial structure and bundle of the core electrode, but also all-carbon materials electrodes which have high conductivity. Our coaxial fiber supercapacitor can promote the development of textile electronics in near future.

  2. Flexible all-carbon photovoltaics with improved thermal stability

    Energy Technology Data Exchange (ETDEWEB)

    Tang, Chun; Ishihara, Hidetaka; Sodhi, Jaskiranjeet; Chen, Yen-Chang; Siordia, Andrew; Martini, Ashlie; Tung, Vincent C., E-mail: ctung@ucmerced.edu

    2015-04-15

    The structurally robust nature of nanocarbon allotropes, e.g., semiconducting single-walled carbon nanotubes (SWCNTs) and C{sub 60}s, makes them tantalizing candidates for thermally stable and mechanically flexible photovoltaic applications. However, C{sub 60}s rapidly dissociate away from the basal of SWCNTs under thermal stimuli as a result of weak intermolecular forces that “lock up” the binary assemblies. Here, we explore use of graphene nanoribbons (GNRs) as geometrically tailored protecting layers to suppress the unwanted dissociation of C{sub 60}s. The underlying mechanisms are explained using a combination of molecular dynamics simulations and transition state theory, revealing the temperature dependent disassociation of C{sub 60}s from the SWCNT basal plane. Our strategy provides fundamental guidelines for integrating all-carbon based nano-p/n junctions with optimized structural and thermal stability. External quantum efficiency and output current–voltage characteristics are used to experimentally quantify the effectiveness of GNR membranes under high temperature annealing. Further, the resulting C{sub 60}:SWCNT:GNR ternary composites display excellent mechanical stability, even after iterative bending tests. - Graphical abstract: The incorporation of solvent resistant, mechanically flexible and electrically addressable 2-D soft graphene nanoribbons facilitates the assembly of photoconductive carbon nano-p/n junctions for thermally stable and flexible photovoltaic cells.

  3. All-Carbon Electrode Consisting of Carbon Nanotubes on Graphite Foil for Flexible Electrochemical Applications

    Directory of Open Access Journals (Sweden)

    Je-Hwang Ryu

    2014-03-01

    Full Text Available We demonstrate the fabrication of an all-carbon electrode by plasma-enhanced chemical vapor deposition for use in flexible electrochemical applications. The electrode is composed of vertically aligned carbon nanotubes that are grown directly on a flexible graphite foil. Being all-carbon, the simple fabrication process and the excellent electrochemical characteristics present an approach through which high-performance, highly-stable and cost-effective electrochemical applications can be achieved.

  4. QUATERNARY GEOLOGY & GEOMORPHOLOGY

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    <正>20112526Bai Daoyuan (Hunan Institute of Geology Survey,Changsha 410011,China); Liu Bo Quaternary Tectonic-Sedimentary Characteristics and Environmental Evolution of Linli Sag,Dongting Basin (Journal of

  5. QUATERNARY GEOLOGY & GEOMORPHOLOGY

    Institute of Scientific and Technical Information of China (English)

    2011-01-01

    <正>20111129 Bai Daoyuan(Hunan Institute of Geological Survey,Changsha 410011,China);Li Chang’an Quaternary Tectonic-Sedimentary Characteristics and Environmental Evolution of Anxiang Sag in Dongting Basin and Its West Periphery(Journal of Earth Sciences and Environment,ISSN1672-6561,CN61-1423/P,32(2),2010,p.120-129,6 illus.,1 table,48 refs.)Key words:Quaternary,sedimentary environment,structural evolution,Dongtinghu Basin Detailed geologic mapping and bore data was conducted to study on the Quaternary tectonic and sedimentary characteristics and environmental evolution of Anxiang Sag and its west periphery of Dongting Basin,which provided new materials for Quaternary geology of Jianghan-Dongting Basin.The sag trends north-south direction and is surrounded by normal faults.The thickness of Quaternary deposits in the sag is commonly 100~220 m with maximun thickness of 300 m,and from lower to upper,the Quaternary strata is composed of Early Pleistocene Huatian Formation and Miluo Formation,Middle Pleistocene Dongtinghu Formation

  6. Second Quaternary dating workshop

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1999-11-01

    The second Quaternary dating methods workshop was held at Lucas Heights and sponsored by ANSTO and AINSE. Topics covered include, isotope and thermoluminescence dating, usage of accelerator and thermal ionisation mass spectrometry in environmental studies emphasizing on the methodologies used and sample preparation

  7. Ligand-Enabled γ-C–H Olefination and Carbonylation: Construction of β-Quaternary Carbon Centers

    OpenAIRE

    Li, Suhua; Chen, Gang; Feng, Chen-Guo; Gong, Wei; Yu, Jin-Quan

    2014-01-01

    Monoselective γ-C–H olefination and carbonylation of aliphatic acids has been accomplished by using a combination of a quinoline-based ligand and a weakly coordinating amide directing group. The reaction provides a new route for constructing richly functionalized all-carbon quaternary carbon centers at the β-position of aliphatic acids.

  8. Ligand-enabled γ-C-H olefination and carbonylation: construction of β-quaternary carbon centers.

    Science.gov (United States)

    Li, Suhua; Chen, Gang; Feng, Chen-Guo; Gong, Wei; Yu, Jin-Quan

    2014-04-09

    Monoselective γ-C-H olefination and carbonylation of aliphatic acids has been accomplished by using a combination of a quinoline-based ligand and a weakly coordinating amide directing group. The reaction provides a new route for constructing richly functionalized all-carbon quaternary carbon centers at the β-position of aliphatic acids.

  9. QUATERNARY GEOLOGY & GEOMORPHOLOGY

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    <正>20050939 An Chengbang (Key Lab. of Western Chinese Environment System, Ministry of Education, Lanzhou University, Lanzhou, Gansu 730000, China); Feng Zhaodong Humid Climate During 9-3. 8 KaBP in the Western Part of Chinese Loess Plateau (Marine Geology & Quaternary Geology, ISSN0256-1492, CN37-1117/P, 24 (3), 2004, p. 111-116, 3 illus. , 1 table, 40 refs. , with English abstract)

  10. Partitioning the Quaternary

    Science.gov (United States)

    Gibbard, Philip L.; Lewin, John

    2016-11-01

    We review the historical purposes and procedures for stratigraphical division and naming within the Quaternary, and summarize the current requirements for formal partitioning through the International Commission on Stratigraphy (ICS). A raft of new data and evidence has impacted traditional approaches: quasi-continuous records from ocean sediments and ice cores, new numerical dating techniques, and alternative macro-models, such as those provided through Sequence Stratigraphy and Earth-System Science. The practical usefulness of division remains, but there is now greater appreciation of complex Quaternary detail and the modelling of time continua, the latter also extending into the future. There are problems both of commission (what is done, but could be done better) and of omission (what gets left out) in partitioning the Quaternary. These include the challenge set by the use of unconformities as stage boundaries, how to deal with multiphase records in ocean and terrestrial sediments, what happened at the 'Early-Mid- (Middle) Pleistocene Transition', dealing with trends that cross phase boundaries, and the current controversial focus on how to subdivide the Holocene and formally define an 'Anthropocene'.

  11. Synthesis and properties of poly(1-phenyl-1-octyne)s containing stereogenic and chromophoric pendant groups

    Institute of Scientific and Technical Information of China (English)

    LAM; Jacky; W.Y.; JIM; Cathy; K.W.; KWOK; Hoi; Sing

    2009-01-01

    Poly(1-phenyl-1-octyne)s containing different stereogenic and chromophoric pendants {-[(C6H13)C=C(C6H4-p-CO2-R)]n-R=[(1S)-endo]-(-)-borneyl (P3), (1R,2S,5R)-(-)-menthyl (P4),―C6H4-p-(1R,2S,5R)-(-)-menthyl (P5), 2-napthyl (P6), 4-biphenylyl (P7)} have been designed and synthesized. The polymers are prepared in moderate yields by WCl6-Ph4Sn and possess high molecular weights (Mw up to 64000). The structures and properties of the polymers are characterized and evaluated by NMR, TGA, UV, CD, PL, and EL analyses. All the polymers are thermally stable and their temperatures for 5% weight loss locate in the range of 300 to 416℃ under nitrogen. The energy band gaps of all the polymers are ~3.0 eV. Polymers P4 and P5 show CD absorptions associated with the helicity of the polymer segments. Excitation of the THF solutions of P3―P7 by UV irradiation gives strong blue lights of ~485 nm with quantum yields higher than 20%. The thin films of the polymers also emit in the same spectral region, indicative of little aggregation-caused quenching of light emission. Multilayer EL devices with a configuration of ITO/Polymer:PVK/BCP/Alq3/LiF/Al are constructed, which emit blue lights of ~487 nm. The maximum luminance and external quantum efficiency vary with the pendant groups, with P6 exhibiting the highest external quantum efficiency of 0.16%. The spectra stability of the EL devices is outstanding and the EL peak maximum experiences little change with the applied voltage.

  12. Cyanines Bearing Quaternary Azaaromatic Moieties

    OpenAIRE

    Sbliwa, Wanda; Matusiak, Grazyna; Bachowska, Barbara

    2006-01-01

    Selected cyanines bearing quaternary azaaromatic moieties are presented, showing their monomers, dimers and polymers, as well as their possible applications. Cyanines having NLO properties are also briefly described.

  13. Ethylene in Organic Synthesis. A New Route to Anticholenergic Pyrrolidinoindolines, and Other Molecules with All Carbon-Quaternary Centers via Asymmetric Hydrovinylation

    Science.gov (United States)

    Lim, Hwan Jung; RajanBabu, T. V.

    2011-01-01

    The asymmetric hydrovinylation (1 mol % Ni-cat., 1 atm, ethylene, >98% ee) products from 1-methylenetetralines are readily converted into 3,3-disubstituted oxindoles, and subsequently to pyrrolidinoindolines. These hydrovinylation products are also useful for the syntheses of enantiopure benzomorphans. PMID:22103775

  14. Magnetism of quaternary sediments

    Science.gov (United States)

    Heller, Friedrich

    Magnetism of Quaternary sediments was the topic of a well-attended symposium held during the 13th INQUA (International Union of Quaternary Research) congress in Beijing, China, August 2-9. More than 40 papers were delivered by scientists from Belgium, England, France, Germany, Japan, New Zealand, Sweden, Switzerland, Taiwan, the United States, the Soviet Union, Yugoslavia, and other countries. The host country contributed to a productive session that was part of the first large scientific meeting to take place in Beijing after the June 4, 1989, upheaval.Nearly half of the studies focused on paleomagnetic and rock magnetic properties of loess in Alaska, Central Asia, China, and New Zealand. Magnetostratigraphic polarity dating was done at some sections in the western (Shaw et al.) and central Chinese loess plateau (Bai and Hus; Wang and Evans; Yue). The interpretation of the polarity pattern found in the western loess plateau still is not unambiguous. In the central part, certain polarity boundaries, such as the Brunhes/Matuyama (B/M) boundary, are found in slightly different stratigraphic positions (Hus et al.; Yue). In deep-sea sediments the lock-in depth of natural remanent magnetization (NRM) at the B/M boundary seems to be a linear function of sedimentation rate (de Menocal et al.). Although the magnetization process in the Chinese loess is not well understood, detailed records of polarity transitions have been reported for the B/M and the Jaramillo R→N transition (Ma et al.; Rolph).

  15. Two- and Three-Dimensional All-Carbon Nanomaterial Assemblies for Tissue Engineering and Regenerative Medicine.

    Science.gov (United States)

    Lalwani, Gaurav; Patel, Sunny C; Sitharaman, Balaji

    2016-06-01

    Carbon nanomaterials such as carbon nanotubes and graphene have gained significant interest in the fields of materials science, electronics and biomedicine due to their interesting physiochemical properties. Typically these carbon nanomaterials have been dispersed in polymeric matrices at low concentrations to improve the functional properties of nanocomposites employed as two-dimensional (2D) substrates or three-dimensional (3D) porous scaffolds for tissue engineering applications. There has been a growing interest in the assembly of these nanomaterials into 2D and 3D architectures without the use of polymeric matrices, surfactants or binders. In this article, we review recent advances in the development of 2D or 3D all-carbon assemblies using carbon nanotubes or graphene as nanoscale building-block biomaterials for tissue engineering and regenerative medicine applications.

  16. All-carbon nanotube diode and solar cell statistically formed from macroscopic network

    Institute of Scientific and Technical Information of China (English)

    Albert G. Nasibulin[1,2,3; Adinath M. Funde[3,4; Ilya V. Anoshkin[3; Igor A. Levitskyt[5,6

    2015-01-01

    Schottky diodes and solar cells are statistically created in the contact area between two macroscopic films of single-walled carbon nanotubes (SWNTs) at the junction of semiconducting and quasi-metallic bundles consisting of several high quality tubes. The n-doping of one of the films allows for photovoltaic action, owing to an increase in the built-in potential at the bundle-to-bundle interface. Statistical analysis demonstrates that the Schottky barrier device contributes significantly to the I-V characteristics, compared to the p-n diode. The upper limit of photovoltaic conversion efficiency has been estimated at N20%, demonstrating that the light energy conversion is very efficient for such a unique solar cell. While there have been multiple studies on rectifying SWNT diodes in the nanoscale environment, this is the first report of a macroscopic all-carbon nanotube diode and solar cell.

  17. Optical diode action from axially asymmetric nonlinearity in an all-carbon solid-state device.

    Science.gov (United States)

    Anand, Benoy; Podila, Ramakrishna; Lingam, Kiran; Krishnan, S R; Siva Sankara Sai, S; Philip, Reji; Rao, Apparao M

    2013-01-01

    Nanostructured carbons are posited to offer an alternative to silicon and lead to further miniaturization of photonic and electronic devices. Here, we report the experimental realization of the first all-carbon solid-state optical diode that is based on axially asymmetric nonlinear absorption in a thin saturable absorber (graphene) and a thin reverse saturable absorber (C60) arranged in tandem. This all-optical diode action is polarization independent and has no phase-matching constraints. The nonreciprocity factor of the device can be tuned by varying the number of graphene layers and the concentration or thickness of the C60 coating. This ultracompact graphene/C60 based optical diode is versatile with an inherently large bandwidth, chemical and thermal stability, and is poised for cost-effective large-scale integration with existing fabrication technologies.

  18. Chiral nonracemic late-transition-metal organometallics with a metal-bonded stereogenic carbon atom: development of new tools for asymmetric organic synthesis.

    Science.gov (United States)

    Malinakova, Helena C

    2004-06-07

    Transition-metal-catalyzed cross-coupling reactions and the Heck reaction have evolved into powerful tools for the construction of carbon-carbon bonds. In most cases, the reactive organometallic intermediates feature a carbon-transition-metal sigma bond between a sp(2)-hybridized carbon atom and the transition metal (Csp(2)--TM). New, and potentially more powerful approach to transition-metal-catalyzed asymmetric organic synthesis would arise if catalytic chiral nonracemic organometallic intermediates with a stereogenic sp(3)-hybridized carbon atoms directly bonded to the transition metal (C*sp(3)--TM bond) could be formed from racemic or achiral organic substrates, and subsequently participate in the formation of a new carbon-carbon bond (C*sp(3)-C) with retention of the stereochemical information. To date, only a few catalytic processes that are based on this concept, have been developed. In this account, both "classical" and recent studies on preparation and reactivity of stable chiral nonracemic organometallics with a metal-bonded stereogenic carbon, which provide the foundation for the future design of new synthetic transformations exploiting the outlined concept, are discussed, along with examples of relevant catalytic processes.

  19. Analysis of All-Carbon Brick Bottom and Ceramic Cup Synthetic Hearth Bottom

    Institute of Scientific and Technical Information of China (English)

    ZHAO Hong-bo; CHENG Shu-sen; ZHAO Min-ge

    2007-01-01

    One of the bottlenecks of the blast furnace (BF) campaign is the life length of hearth bottom. The basic reason for the erosion of hearth bottom is its direct contact with hot metal. According to the theory of heat transfer, models of BF hearth bottom are built based on the actual examples using software and VC language, and the calculated results are in good agreement with the data of BF dissection after blowing out. The temperature distribution and the capability of the resistance to erosion for different structures of hearth bottom are analyzed, especially the two prevalent kinds of hearth bottom arrangements called "the method of heat transfer" for all-carbon brick bottom and "the method of heat isolation" for ceramic synthetic hearth bottom. Features of the two kinds of hearth bottoms are analyzed. Also the different ways of protecting the hearth bottom are clarified, according to some actual examples. After that, the same essence of prolonging life, and the fact that the existence of a "protective skull" with low thermal conductivity between the hot metal and brick layers is of utmost importance are shown.

  20. All-carbon-based porous topological semimetal for Li-ion battery anode material.

    Science.gov (United States)

    Liu, Junyi; Wang, Shuo; Sun, Qiang

    2017-01-24

    Topological state of matter and lithium batteries are currently two hot topics in science and technology. Here we combine these two by exploring the possibility of using all-carbon-based porous topological semimetal for lithium battery anode material. Based on density-functional theory and the cluster-expansion method, we find that the recently identified topological semimetal bco-C16 is a promising anode material with higher specific capacity (Li-C4) than that of the commonly used graphite anode (Li-C6), and Li ions in bco-C16 exhibit a remarkable one-dimensional (1D) migration feature, and the ion diffusion channels are robust against the compressive and tensile strains during charging/discharging. Moreover, the energy barrier decreases with increasing Li insertion and can reach 0.019 eV at high Li ion concentration; the average voltage is as low as 0.23 V, and the volume change during the operation is comparable to that of graphite. These intriguing theoretical findings would stimulate experimental work on topological carbon materials.

  1. Catalytic enantioselective construction of quaternary stereocenters: assembly of key building blocks for the synthesis of biologically active molecules.

    Science.gov (United States)

    Liu, Yiyang; Han, Seo-Jung; Liu, Wen-Bo; Stoltz, Brian M

    2015-03-17

    The ever-present demand for drugs with better efficacy and fewer side effects continually motivates scientists to explore the vast chemical space. Traditionally, medicinal chemists have focused much attention on achiral or so-called "flat" molecules. More recently, attention has shifted toward molecules with stereogenic centers since their three-dimensional structures represent a much larger fraction of the chemical space and have a number of superior properties compared with flat aromatic compounds. Quaternary stereocenters, in particular, add greatly to the three-dimensionality and novelty of the molecule. Nevertheless, synthetic challenges in building quaternary stereocenters have largely prevented their implementation in drug discovery. The lack of effective and broadly general methods for enantioselective formation of quaternary stereocenters in simple molecular scaffolds has prompted us to investigate new chemistry and develop innovative tools and solutions. In this Account, we describe three approaches to constructing quaternary stereocenters: nucleophilic substitution of 3-halooxindoles, conjugate addition of boronic acids to cyclic enones, and allylic alkylation of enolates. In the first approach, malonic ester nucleophiles attack electrophilic 3-halooxindoles, mediated by a copper(II)-bisoxazoline catalyst. A variety of oxindoles containing a benzylic quaternary stereocenter can be accessed through this method. However, it is only applicable to the specialized 3,3-disubstituted oxindole system. To access benzylic quaternary stereocenters in a more general context, we turned our attention to the enantioselective conjugate addition of carbon nucleophiles to α,β-unsaturated carbonyl acceptors. We discovered that in the presence of catalytic palladium-pyridinooxazoline complex, arylboronic acids add smoothly to β-substituted cyclic enones to furnish ketones with a β-benzylic quaternary stereocenter in high yields and enantioselectivities. The reaction is

  2. Proposal to redefine the Quaternary

    Institute of Scientific and Technical Information of China (English)

    BradPillans

    2004-01-01

    The following proposal has been circulated, via the Executive of the International Union for Quaternary Research (INQUA), to all INQUA members for discussion. It also appears on the ICS web site (www.stratigraphy.org). Comments may be sent to John Clague, President of INQUA (jclague@sfu.ca), and Brad Pillans(brad.pillans@anu.edu.au).

  3. Regulated-stereoselective construction of thirteen stereogenic centers necessary for the frame of (+)-discodermolide, based on iterative Lewis acid-promoted aldol reactions.

    Science.gov (United States)

    Kiyooka, Syun-ichi; Shahid, Kazi Abdus; Goto, Fumitaka; Okazaki, Momotoshi; Shuto, Yoshihiro

    2003-10-17

    The segments C(1)-C(13) and C(15)-C(21) containing the 13 stereogenic centers required for the frame of (+)-discodermolide were synthesized in good to excellent enantio- and diastereoselectivities from a common racemic aldehyde, derived from 2-methyl-1,3-propanediol. The enantioselective aldol reactions of the racemic aldehyde with a silylketene acetal, derived from ethyl 2-bromopropionate, in the presence of chiral oxazaborolidinones, prepared in situ with N-p-toluenesulfonyl-(R)- and -(S)-valine and BH(3).THF, proceeded under kinetic control to give the stereotriads with a high degree of enantioselectivity. Enantioselective (chiral borane) and diastereoselective (BF(3).OEt(2) and TiCl(4)) aldol reactions with the silylketene acetal, coupled with diastereoselective radical debrominations (Bu(3)SnH, Et(3)B, with or without MgBr(2)), were used iteratively. This aldol reaction strategy for the construction of the polypropionate frame dramatically shortened the steps needed for the construction of the final segments.

  4. Synthesis of Chitosan Quaternary Ammonium Salts

    Institute of Scientific and Technical Information of China (English)

    2001-01-01

    A series of N-alkyl or N-aryl chitosan quaternary ammonium salts were prepared via Schiffs base intermediates. Quaternization of N-substituted chitosan derivatives was carried out using methyl iodide to produce water-soluble cationic chitosan quaternary ammonium salt. The products were characterized by IR, 1HNMR and elemental analysis. The degree of substitution of chitosan quaternary ammonium salt was calculated by elemental analysis.

  5. Synthesis of enantioenriched γ-quaternary cycloheptenones using a combined allylic alkylation/Stork–Danheiser approach: preparation of mono-, bi-, and tricyclic systems

    KAUST Repository

    Bennett, Nathan B.

    2012-01-01

    A general method for the synthesis of β-substituted and unsubstituted cycloheptenones bearing enantioenriched all-carbon γ-quaternary stereocenters is reported. Hydride or organometallic addition to a seven-membered ring vinylogous ester followed by finely tuned quenching parameters achieves elimination to the corresponding cycloheptenone. The resulting enones are elaborated to bi- and tricyclic compounds with potential for the preparation of non-natural analogs and whose structures are embedded in a number of cycloheptanoid natural products.

  6. Novel Quaternary Quantum Decoder, Multiplexer and Demultiplexer Circuits

    Science.gov (United States)

    Haghparast, Majid; Monfared, Asma Taheri

    2017-02-01

    Multiple valued logic is a promising approach to reduce the width of the reversible or quantum circuits, moreover, quaternary logic is considered as being a good choice for future quantum computing technology hence it is very suitable for the encoded realization of binary logic functions through its grouping of 2-bits together into quaternary values. The Quaternary decoder, multiplexer, and demultiplexer are essential units of quaternary digital systems. In this paper, we have initially designed a quantum realization of the quaternary decoder circuit using quaternary 1-qudit gates and quaternary Muthukrishnan-Stroud gates. Then we have presented quantum realization of quaternary multiplexer and demultiplexer circuits using the constructed quaternary decoder circuit and quaternary controlled Feynman gates. The suggested circuits in this paper have a lower quantum cost and hardware complexity than the existing designs that are currently used in quaternary digital systems. All the scales applied in this paper are based on Nanometric area.

  7. All-carbon multi-electrode array for real-time in vitro measurements of oxidizable neurotransmitters

    CERN Document Server

    Picollo, F; Bernardi, E; Plaitano, M; Franchino, C; Gosso, S; Pasquarelli, A; Carbone, E; Olivero, P; Carabelli, V

    2016-01-01

    We report on the ion beam fabrication of all-carbon multi electrode arrays (MEAs) based on 16 graphitic micro-channels embedded in single-crystal diamond (SCD) substrates. The fabricated SCD-MEAs are systematically employed for the in vitro simultaneous amperometric detection of the secretory activity from populations of chromaffin cells, demonstrating a new sensing approach with respect to standard techniques. The biochemical stability and biocompatibility of the SCD-based device combined with the parallel recording of multi-electrodes array allow: i) a significant time saving in data collection during drug screening and/or pharmacological tests over a large number of cells, ii) the possibility of comparing altered cell functionality among cell populations, and iii) the repeatition of acquisition runs over many cycles with a fully non-toxic and chemically robust bio-sensitive substrate.

  8. Ab initio study of transport properties of an all-carbon molecular switch based on C20 molecule

    Institute of Scientific and Technical Information of China (English)

    OUYANG Fang-ping; XU Hui

    2007-01-01

    Choosing closed-ended armchair (5, 5) singlewall carbon nanotubes (CCNTs) as electrodes, we have investigated the electron transport properties across a carbon molecular junction consisting of a C20 molecule sandwiched between two semi-infinite carbon nanotubes. It is shown that the Landauer conductance of this carbon hybrid system can be tuned within several orders of magnitude not only by varying the tube-C20 distance, but more importantly by changing the orientation of the C20 molecule and rotating the C20 molecule or one of the tubes around the symmetry axis of the system at fixed distances. This fact could make this all-carbon molecular system a possible candidate for a nanoelectronic switching device. Moreover, our study also reveals that molecular configuration selection and structural relaxation would play an important role in the design of such devices.

  9. Synthesis and stereochemical assignments of diastereomeric Ni(II complexes of glycine Schiff base with (R-2-(N-{2-[N-alkyl-N-(1-phenylethylamino]acetyl}aminobenzophenone; a case of configurationally stable stereogenic nitrogen

    Directory of Open Access Journals (Sweden)

    Hiroki Moriwaki

    2014-02-01

    Full Text Available A family of chiral ligands derived from α-phenylethylamine and 2-aminobenzophenone were prepared by alkylation of the nitrogen atom. Upon reaction with glycine and a Ni(II salt, these ligands were transformed into diastereomeric complexes, as a result of the configurational stability of the stereogenic nitrogen atom. Different diastereomeric ratios were observed depending on the substituent R introduced in the starting ligand, and stereochemical assignments were based on X-ray analysis, along with NMR studies and optical rotation measurements.

  10. Phosphate Tether-Mediated Ring-Closing Metathesis for the Generation of P-Stereogenic, Z-Configured Bicyclo[7.3.1]- and Bicyclo[8.3.1]phosphates.

    Science.gov (United States)

    Markley, Jana L; Maitra, Soma; Hanson, Paul R

    2016-02-05

    A phosphate tether-mediated ring-closing metathesis (RCM) study to the synthesis of Z-configured, P-stereogenic bicyclo[7.3.1]- and bicyclo[8.3.1]phosphates is reported. Investigations suggest that C3-substitution, olefin substitution, and proximity of the forming olefin to the bridgehead carbon of the bicyclic affect the efficiency and stereochemical outcome of the RCM event. This study demonstrates the utility of phosphate tether-mediated desymmetrization of C2-symmetric, 1,3-anti-diol-containing dienes in the generation of macrocyclic phosphates with potential synthetic and biological utility.

  11. Late Quaternary changes in climate

    Energy Technology Data Exchange (ETDEWEB)

    Holmgren, K.; Karlen, W. [Stockholm Univ. (Sweden). Dept. of Physical Geography

    1998-12-01

    This review concerns the Quaternary climate with an emphasis on the last 200 000 years. The present state of art in this field is described and evaluated. The review builds on a thorough examination of classic and recent literature. General as well as detailed patterns in climate are described and the forcing factors and feed-back effects are discussed. Changes in climate occur on all time-scales. During more than 90% of the Quaternary period earth has experienced vast ice sheets, i.e. glaciations have been more normal for the period than the warm interglacial conditions we face today. Major changes in climate, such as the 100 000 years glacial/interglacial cycle, are forced by the Milankovitch three astronomical cycles. Because the cycles have different length climate changes on earth do not follow a simple pattern and it is not possible to find perfect analogues of a certain period in the geological record. Recent discoveries include the observation that major changes in climate seem to occur at the same time on both hemispheres, although the astronomical theory implies a time-lag between latitudes. This probably reflects the influence of feed-back effects within the climate system. Another recent finding of importance is the rapid fluctuations that seem to be a normal process. When earth warmed after the last glaciation temperature jumps of up to 10 deg C occurred within less than a decade and precipitation more than doubled within the same time. The forcing factors behind these rapid fluctuations are not well understood but are believed to be a result of major re-organisations in the oceanic circulation. Realizing that nature, on its own, can cause rapid climate changes of this magnitude put some perspective on the anthropogenic global warming debate, where it is believed that the release of greenhouse gases will result in a global warming of a few C. To understand the forcing behind natural rapid climate changes appears as important as to understand the role

  12. Domino Michael-Michael and Aldol-Aldol Reactions: Diastereoselective Synthesis of Functionalized Cyclohexanone Derivatives Containing Quaternary Carbon Center.

    Science.gov (United States)

    Ghorai, Manas K; Halder, Sandipan; Das, Subhomoy

    2015-10-02

    A simple strategy for the synthesis of highly functionalized cyclohexanone derivatives containing an all-carbon quaternary center from α-(aryl/alkyl)methylidene-β-keto esters or β-diketones via a K-enolate mediated domino Michael-Michael reaction sequence with moderate to good yield and excellent diastereoselectivity (de > 99%) is described. Interestingly, Li-base mediated reaction of α-arylmethylidene-β-diketones affords functionalized 3,5-dihydroxy cyclohexane derivatives as the kinetically controlled products via a domino aldol-aldol reaction sequence with excellent diastereoselectivity. Li-enolates of the β-keto esters or β-diketones undergo facile domino Michael-Michael reaction with nitro-olefins to afford the corresponding nitrocyclohexane derivatives in good yields and excellent diastereoselectivity (de > 99%). The formation of the products and the observed stereoselectivity were explained by plausible mechanisms and supported by extensive computational study. An asymmetric version of the protocol was explored with (L)-menthol derived nonracemic substrates, and the corresponding nonracemic cyclohexanone derivatives containing an all-carbon quaternary center were obtained with excellent stereoselectivity (de, ee > 99%).

  13. PROGRESS IN QUATERNARY AEOLIAN ENVIRONMENT RESEARCH

    Institute of Scientific and Technical Information of China (English)

    LU Rui-jie; CHEN Yuan; HASI Eerdun; YUE Xing-ling

    2005-01-01

    Quaternary aeolian environment researches were mainly conducted by analyzing the information carri-ers, extracting valuable evidences about aeolian environment changes, so to presume and reconstruct paleoenviron-ments. This paper formulated progress in Quaternary aeolian environment research using dune-morphological records,sedimentological records and bio-fossils records, as well as advances about chronology; presented that people shouldpay more attention to further synthetic study of multi-types of records including dune morphology, size, formationtime, sediment supply, and their relations with wind regime in future, especially the research on dating method.

  14. Climate predictors of late quaternary extinctions

    DEFF Research Database (Denmark)

    Nogués-Bravo, David; Ohlemüller, Ralf; Batra, Persaram

    2010-01-01

    Between 50,000 and 3,000 years before present (BP) 65% of mammal genera weighing over 44 kg went extinct, together with a lower proportion of small mammals. Why species went extinct in such large numbers is hotly debated. One of the arguments proposes that climate changes underlie Late Quaternary...... extinctions, but global quantitative evidence for this hypothesis is still lacking. We test the potential role of global climate change on the extinction of mammals during the Late Quaternary. Our results suggest that continents with the highest climate footprint values, in other words, with climate changes...

  15. Catalytic enantioselective synthesis of quaternary carbon stereocentres

    Science.gov (United States)

    Quasdorf, Kyle W.; Overman, Larry E.

    2014-12-01

    Quaternary carbon stereocentres--carbon atoms to which four distinct carbon substituents are attached--are common features of molecules found in nature. However, before recent advances in chemical catalysis, there were few methods of constructing single stereoisomers of this important structural motif. Here we discuss the many catalytic enantioselective reactions developed during the past decade for the synthesis of single stereoisomers of such organic molecules. This progress now makes it possible to incorporate quaternary stereocentres selectively in many organic molecules that are useful in medicine, agriculture and potentially other areas such as flavouring, fragrances and materials.

  16. 21 CFR 172.165 - Quaternary ammonium chloride combination.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 3 2010-04-01 2009-04-01 true Quaternary ammonium chloride combination. 172.165... HUMAN CONSUMPTION Food Preservatives § 172.165 Quaternary ammonium chloride combination. The food additive, quaternary ammonium chloride combination, may be safely used in food in accordance with...

  17. Palladium-Catalyzed Asymmetric Quaternary Stereocenter Formation

    NARCIS (Netherlands)

    Gottumukkala, Aditya L.; Matcha, Kiran; Lutz, Martin; de Vries, Johannes G.; Minnaard, Adriaan J.

    2012-01-01

    An efficient palladium catalyst is presented for the formation of benzylic quaternary stereocenters by conjugate addition of arylboronic acids to a variety of beta,beta-disubstituted carbocyclic, heterocyclic, and acyclic enones. The catalyst is readily prepared from PdCl2, PhBOX, and AgSbF6, and pr

  18. Palladium-catalyzed asymmetric quaternary stereocenter formation

    NARCIS (Netherlands)

    Gottumukkala, A.L.; Matcha, K.; Lutz, M.; de Vries, J.G.; Minnaard, A.J.

    2012-01-01

    An efficient palladium catalyst is presented for the formation of benzylic quaternary stereocenters by conjugate addition of arylboronic acids to a variety of β,β-disubstituted carbocyclic, heterocyclic, and acyclic enones. The catalyst is readily prepared from PdCl2, PhBOX, and AgSbF6, and provides

  19. Extensive Quaternary glaciations in eastern Turkey

    Science.gov (United States)

    Yeşilyurt, Serdar; Akçar, Naki; Doǧan, Uǧur; Yavuz, Vural; Ivy-Ochs, Susan; Vockenhuber, Christof; Schlunegger, Fritz; Schlüchter, Christian

    2016-04-01

    During cold periods in the Quaternary, global ice volume increased and as a result valley glaciers advanced and the vice versa occurred during the warm periods. Quaternary glacier fluctuations had been also recorded in the Turkish mountains. Recently, the chronology of Late Quaternary advances in the northern and western Turkish mountains was reconstructed by surface exposure dating. However, these advances in the eastern Turkey are not dated yet. In this study, we investigated paleoglaciations in Kavuşşahap Mountains, which is located to the south of Lake Van in eastern Turkey. These mountains are one of the extensively glaciated areas in Turkey. Glacial activity is evidenced by more than 20 U-shaped valleys. For instance, one of the prominent and well-preserved glacial landscapes of Turkey is situated in the Narlıca valley system. Lateral and terminal moraines in the valley system indicate more than 10 glacial advances. To build their chronology, 39 erratic carbonaceous boulders were sampled for surface exposure dating with cosmogenic 36Cl. We also reconstructed the ice margin reconstruction of the Narlıca paleoglacier using the accumulation area ratio and area-altitude balance ratio approaches. We estimated an equilibrium line altitude (ELA) of ca. 2900 m above sea level based on the maximum ice extend, which implied ca. 800 m decrease in the ELA during the Late Quaternary in comparison to the lower bound of the modern ELA estimate. The first results of the surface exposure dating will be presented.

  20. Synergistically enhanced activity of graphene quantum dots/graphene hydrogel composites: a novel all-carbon hybrid electrocatalyst for metal/air batteries

    Science.gov (United States)

    Wang, Mengran; Fang, Zhao; Zhang, Kai; Fang, Jing; Qin, Furong; Zhang, Zhian; Li, Jie; Liu, Yexiang; Lai, Yanqing

    2016-06-01

    Primary zinc/air batteries could be the next generation of energy storage devices because of their high power density and high safety. Graphene quantum dots nested in the graphene hydrogel have been proposed as excellent all-carbon hybrid oxygen reduction reaction (ORR) catalysts, indicative of their great potential in primary zinc/air batteries.Primary zinc/air batteries could be the next generation of energy storage devices because of their high power density and high safety. Graphene quantum dots nested in the graphene hydrogel have been proposed as excellent all-carbon hybrid oxygen reduction reaction (ORR) catalysts, indicative of their great potential in primary zinc/air batteries. Electronic supplementary information (ESI) available. See DOI: 10.1039/c6nr02622b

  1. Contrasting H-mode behaviour with deuterium fuelling and nitrogen seeding in the all-carbon and metallic versions of JET

    CERN Document Server

    Maddison, G P; Alper, B; Arnoux, G; Balboa, I; Beurskens, M N A; Boboc, A; Brezinsek, S; Brix, M; Clever, M; Coelho, R; Coenen, J W; Coffey, I; Belo, P C da Silva Aresta; Devaux, S; Devynck, P; Eich, T; Felton, R C; Flanagan, J; Frassinetti, L; Garzotti, L; Groth, M; Jachmich, S; Järvinen, A; Joffrin, E; Kempenaars, M A H; Kruezi, U; Lawson, K D; Lehnen, M; Leyland, M J; Liu, Y; Lomas, P J; Lowry, C G; Marsen, S; Matthews, G F; McCormick, G K; Meigs, A G; Morris, A W; Neu, R; Nunes, I M; Oberkofler, M; Rimini, F G; Saarelma, S; Sieglin, B; Sips, A C C; Sirinelli, A; Stamp, M F; van Rooij, G J; Ward, D J; Wischmeier, M; contributors, JET EFDA

    2014-01-01

    The former all-carbon wall on JET has been replaced with beryllium in the main torus and tungsten in the divertor to mimic the surface materials envisaged for ITER. Comparisons are presented between Type I H-mode characteristics in each design by examining respective scans over deuterium fuelling and impurity seeding, required to ameliorate exhaust loads both in JET at full capability and in ITER.

  2. Efficient cellulose solvent: quaternary ammonium chlorides.

    Science.gov (United States)

    Kostag, Marc; Liebert, Tim; El Seoud, Omar A; Heinze, Thomas

    2013-10-01

    Pure quaternary tetraalkylammonium chlorides with one long alkyl chain dissolved in various organic solvents constitute a new class of cellulose solvents. The electrolytes are prepared in high yields and purity by Menshutkin quaternization, an inexpensive and easy synthesis route. The pure molten tetraalkylammonium chlorides dissolve up to 15 wt% of cellulose. Cosolvents, including N,N-dimethylacetamide (DMA), may be added in large excess, leading to a system of decreased viscosity. Contrary to the well-established solvent DMA/LiCl, cellulose dissolves in DMA/quaternary ammonium chlorides without any pretreatment. Thus, the use of the new solvent avoids some disadvantages of DMA/LiCl and ionic liquids, the most extensively employed solvents for homogeneous cellulose chemistry.

  3. Quaternary Tipping Points in Tropical Northern Australia

    Science.gov (United States)

    Moss, Patrick; Dunbar, Gavin; Croke, Jacky; Katunar, Rosie

    2016-04-01

    Tropical northern Queensland, particularly the volcanic Atherton Tableland, contains some of the most detailed and longest terrestrial palaeoenvironmental archives in Australia and when combined with adjacent marine sediment records provides key insight into potential environmental 'tipping points' for the entire Quaternary period and beyond. This presentation will provide an overview of some of the key tipping points (i.e. significant landscape transformation) that have occurred within the tropical northern Australian region over the Quaternary, as well as discussing potential causes and subsequent impacts of these transformation episodes. These events include the development of the Great Barrier Reef, transition from obliquity to eccentricity dominated glacial-interglacial cycles, the Mid-Brunhes event, the Oxygen Isotope Stage 6 episode, the arrival of people into the region, Last Glacial-Interglacial Transition and European settlement.

  4. [Quaternary prevention: containment as an ethical necessity].

    Science.gov (United States)

    Martínez González, C; Riaño Galán, I; Sánchez Jacob, M; González de Dios, J

    2014-12-01

    The growing capacity of medicine to generate more iatrogenic events than ever, and the risk of unsustainability of health systems have led to new prevention concept: quaternary prevention aimed at restraining medicalization. Quaternary prevention is essential in the phenomenon called disease mongering, which could be translated as commercialization of disease. Encouraging this sort of prevention and halting the consequences of disease mongering requires the development of all the institutional potential for prevention, as well as all the personal willingness for restraint; it involves separating us from the unnecessary auspices of industry, being critical of our work, not being maleficent, respecting the principle of justice as managers of the limited public resources and making ourselves feel responsible for the social cost resulting from medical decisions. From this point of view, this work analyses neonatal screening, developments in the area of neonatology and primary health care.

  5. PCA for predicting quaternary structure of protein

    Institute of Scientific and Technical Information of China (English)

    Tong WANG; Hongbin SHEN; Lixiu YAO; Jie YANG; Kuochen CHOU

    2008-01-01

    The number and arrangement of subunits that form a protein are referred to as quaternary structure. Knowing the quaternary structure of an uncharacterized protein provides clues to finding its biological function and interaction process with other molecules in a biological system. With the explosion of protein sequences generated in the Post-Genomic Age, it is vital to develop an automated method to deal with such a challenge. To explore this prob-lem, we adopted an approach based on the pseudo position-specific score matrix (Pse-PSSM) descriptor, proposed by Chou and Shen, representing a protein sample. The Pse-PSSM descriptor is advantageous in that it can combine the evolution information and sequence-correlated informa-tion. However, incorporating all these effects into a descriptor may cause 'high dimension disaster'. To over-come such a problem, the fusion approach was adopted by Chou and Shen. A completely different approach, linear dimensionality reduction algorithm principal component analysis (PCA) is introduced to extract key features from the high-dimensional Pse-PSSM space. The obtained dimension-reduced descriptor vector is a compact repre-sentation of the original high dimensional vector. The jack-knife test results indicate that the dimensionality reduction approach is efficient in coping with complicated problems in biological systems, such as predicting the quaternary struc-ture of proteins.

  6. Synthesis of novel quaternary ammonium surfactants containing adamantane

    Institute of Scientific and Technical Information of China (English)

    Jian Wei Guo; Xing Zhong; Hua Zhu; Li Juan Feng; Ying De Cui

    2012-01-01

    A series of novel quaternary ammonium surfactants containing adamantane were designed and synthesized from 1-adamantanecarboxylic acid.The structures of target surfactants were confirmed by 1H NMR,elements analysis and FTIR.Surface properties of these surfactants were investigated.Due to the lipophilicity of adamantane,the critical micelle concentration (CMC) and C20 values of the synthesized quaternary ammonium surfactants are lower than that of conventional quaternary ammonium surfactants.

  7. Ultrafast electron transfer in all-carbon-based SWCNT-C60 donor-acceptor nanoensembles connected by poly(phenylene-ethynylene) spacers

    Science.gov (United States)

    Barrejón, Myriam; Gobeze, Habtom B.; Gómez-Escalonilla, María J.; Fierro, José Luis G.; Zhang, Minfang; Yudasaka, Masako; Iijima, Sumio; D'Souza, Francis; Langa, Fernando

    2016-08-01

    Building all-carbon based functional materials for light energy harvesting applications could be a solution to tackle and reduce environmental carbon output. However, development of such all-carbon based donor-acceptor hybrids and demonstration of photoinduced charge separation in such nanohybrids is a challenge since in these hybrids part of the carbon material should act as an electron donating or accepting photosensitizer while the second part should fulfil the role of an electron acceptor or donor. In the present work, we have successfully addressed this issue by synthesizing covalently linked all-carbon-based donor-acceptor nanoensembles using single-walled carbon nanotubes (SWCNTs) as the donor and C60 as the acceptor. The donor-acceptor entities in the nanoensembles were connected by phenylene-ethynylene spacer units to achieve better electronic communication and to vary the distance between the components. These novel SWCNT-C60 nanoensembles have been characterized by a number of techniques, including TGA, FT-IR, Raman, AFM, absorbance and electrochemical methods. The moderate number of fullerene addends present on the side-walls of the nanotubes largely preserved the electronic structure of the nanotubes. The thermodynamic feasibility of charge separation in these nanoensembles was established using spectral and electrochemical data. Finally, occurrence of ultrafast electron transfer from the excited nanotubes in these donor-acceptor nanohybrids has been established by femtosecond transient absorption studies, signifying their utility in building light energy harvesting devices.Building all-carbon based functional materials for light energy harvesting applications could be a solution to tackle and reduce environmental carbon output. However, development of such all-carbon based donor-acceptor hybrids and demonstration of photoinduced charge separation in such nanohybrids is a challenge since in these hybrids part of the carbon material should act as an

  8. The possibility of chemically inert, graphene-based all-carbon electronic devices with 0.8 eV gap.

    Science.gov (United States)

    Qi, Jing Shan; Huang, Jian Yu; Feng, Ji; Shi, Da Ning; Li, Ju

    2011-05-24

    Graphene is an interesting electronic material. However, flat monolayer graphene does not have significant gap in the electronic density of states, required for a large on-off ratio in logic applications. We propose here a novel device architecture, composed of self-folded carbon nanotube-graphene hybrids, which have been recently observed experimentally in Joule-heated graphene. These experiments demonstrated the feasibility of cutting, folding, and welding few-layer graphene in situ to form all-carbon nanostructures with complex topologies. The electronic gap of self-folded nanotubes can be combined with the semimetallicity of graphene electrodes to form a "metal-semiconductor-metal" junction. By ab initio calculations we demonstrate large energy gaps in the transmission spectra of such junctions, which preserve the intrinsic transport characteristics of the semiconducting nanotubes despite topologically necessary disinclinations at the flat graphene-curved nanotube interface. These all-carbon devices are proposed to be constructed by contact probe cutting and high-temperature annealing and, if produced, would be chemically stable at room temperature under normal gas environments.

  9. THE BINARY IMAGE OF THE DUAL OF QUATERNARY GOETHALS CODE

    Institute of Scientific and Technical Information of China (English)

    崔杰

    2002-01-01

    The 2-adic representations of codewords of the dual of quaternary Goethals code are given. By the 2-adic representations, the binary image of the dual of quaternary Goethals code under the Gray map is proved to be the nonlinear code constructed by Goethals in 1976.

  10. All-carbon graphene bioelectronics.

    Science.gov (United States)

    Nam, Sungwoo; Chun, Sunggyu; Choi, Jonghyun

    2013-01-01

    We report nano field-effect transistor (nanoFET) biosensors built from the monolithic integration of graphene and graphite. The monolithic integration enables nanoscopic field-effect detection of chemical and biological signals with mechanically flexible and robust interface with biological systems in several respects. Our nanoFET biosensors exhibit superior detection sensitivity, mechanical flexibility and nanoscopic detection resolution. First, we demonstrate that electrical detection can be achieved from nanoscale electric field modulation of the graphene channel while the signal integrity is not perturbed by mechanical deflection of graphene nanoFET sensors. Such capability is introduced by the advanced design of monolithic graphene-graphite without any need for metal-graphene heterointerfaces. Second, we explore the chemical detection capability of graphene nanoFET sensors, and show that our sensors are responsive to localized chemical environmental changes/perturbations. Our nanoFET sensors not only show clear response to nanoscopic charge perturbation but also demonstrate potential 3-D sensing capability due to the advanced monolithic graphene-graphite mechanical design. These unique capabilities of our monolithic graphene-graphite bioelectronics could be exploited in chemical and biological detection and conformal interface with biological systems in the future.

  11. Late Quaternary climate change shapes island biodiversity.

    Science.gov (United States)

    Weigelt, Patrick; Steinbauer, Manuel Jonas; Cabral, Juliano Sarmento; Kreft, Holger

    2016-04-07

    Island biogeographical models consider islands either as geologically static with biodiversity resulting from ecologically neutral immigration-extinction dynamics, or as geologically dynamic with biodiversity resulting from immigration-speciation-extinction dynamics influenced by changes in island characteristics over millions of years. Present climate and spatial arrangement of islands, however, are rather exceptional compared to most of the Late Quaternary, which is characterized by recurrent cooler and drier glacial periods. These climatic oscillations over short geological timescales strongly affected sea levels and caused massive changes in island area, isolation and connectivity, orders of magnitude faster than the geological processes of island formation, subsidence and erosion considered in island theory. Consequences of these oscillations for present biodiversity remain unassessed. Here we analyse the effects of present and Last Glacial Maximum (LGM) island area, isolation, elevation and climate on key components of angiosperm diversity on islands worldwide. We find that post-LGM changes in island characteristics, especially in area, have left a strong imprint on present diversity of endemic species. Specifically, the number and proportion of endemic species today is significantly higher on islands that were larger during the LGM. Native species richness, in turn, is mostly determined by present island characteristics. We conclude that an appreciation of Late Quaternary environmental change is essential to understand patterns of island endemism and its underlying evolutionary dynamics.

  12. Quaternary ammonium compounds – New occupational hazards

    Directory of Open Access Journals (Sweden)

    Agnieszka Lipińska-Ojrzanowska

    2014-10-01

    Full Text Available Quaternary ammonium compounds (QACs, quats belong to organic ionic chemical agents which display unique properties of both surfactants and disinfectants. Their wide distribution in the work environment and also in private households brings about new occupational hazards. This paper reviews reports about the health effects of QACs. QACs could play a role of sensitizers and irritants to the skin and mucous membranes. It is suspected that particular QACs can display an immunologic crossreactivity between each other and with other chemical compounds containing ammonium ion, such as muscle relaxants widely used in anesthesia. They may promote the development of airway allergy, however, the background mechanisms are still unclear and need to be further investigated. Until now, a few cases of occupational asthma induced by QACs have been described and their involvement in contact dermatitis has been documented. The possibility of anaphylaxis due to QACs cannot be excluded as well. Med Pr 2014;65(5:675–682

  13. Biosedimentology of Quaternary stromatolites in intertropical Africa

    Science.gov (United States)

    Casanova, J.

    Mineralizations of microbial origin constitute a non-negligeable part of Quaternary limestones in intertropical Africa. Stromatolites have colonized a wide range of environments corresponding to different hydroclimatic situations: travertines in fluviatile environments, oncolites in flood plains, encrustations in sebkha areas and shorelines of deep, fresh water lakes. The developed morphologies represent a complete catalogue of the microbial carbonated mineralizations: oncolites, chemneys, pool-rim dams, biocherms, planar or cylindrical encrustations. The building organisms may be either pure bacterial colonies (hydrothermal and lacustrine environments), cyanophyte associations (fluviatile and lacustrine environments) or complex microbial biocoenoses. Stromatolites have recorded the hydrologic, climatic and sedimentologic evolution of the continental environment in intertropical Africa for the past 240 000 years.

  14. Absolute age determination of quaternary faults

    Energy Technology Data Exchange (ETDEWEB)

    Cheong, Chang Sik; Lee, Seok Hoon; Choi, Man Sik [Korea Basic Science Institute, Seoul (Korea, Republic of)] (and others)

    2000-03-15

    To constrain the age of neotectonic fault movement, Rb-Sr, K-Ar, U-series disequilibrium, C-14 and Be-10 methods were applied to the fault gouges, fracture infillings and sediments from the Malbang, Ipsil, Wonwonsa faults faults in the Ulsan fault zone, Yangsan fault in the Yeongdeog area and southeastern coastal area. Rb-Sr and K-Ar data imply that the fault movement of the Ulan fault zone initiated at around 30 Ma and preliminary dating result for the Yang san fault is around 70 Ma in the Yeongdeog area. K-Ar and U-series disequilibrium dating results for fracture infillings in the Ipsil fault are consistent with reported ESR ages. Radiocarbon ages of quaternary sediments from the Jeongjari area are discordant with stratigraphic sequence. Carbon isotope data indicate a difference of sedimentry environment for those samples. Be-10 dating results for the Suryum fault area are consistent with reported OSL results.

  15. Paleomagnetic research on Black Sea Quaternary sediments

    Science.gov (United States)

    Kalcheva, V.; Nozharov, P.; Kovacheva, M.; Shopov, V.

    1990-10-01

    The paper reports the first paleomagnetic study of a Black Sea Quaternary sediment core made by a Bulgarian research group. The experimental results show an important difference in magnetic behaviour between the samples from the Holocene part and those from the Pleistocene part of the core. Suggestions are made for the character of the remanent magnetization and the main carriers of it. The presence of greigite (Fe 3S 4) and pyrite (FeS 2) is discussed. A rough correlation is established between the variation of inclination for the Holocene part of the sediment and for the Bulgarian archeomagnetic curve. On the basis of the comparison of inclination data obtained from the Pleistocene part of the core and previously studied Black Sea core (related to the absolute time scale), it is suggested that the lower boundary of the Pleistocene part is ˜ 16000 years old (BP).

  16. Suggested terminology for Quaternary dating methods

    Science.gov (United States)

    Colman, Steven M.; Pierce, K.L.; Birkeland, P.W.

    1987-01-01

    Classification of Quaternary dating methods should be based on the level of quantitative information and the degree of confidence contained in the age estimates produced by the dating methods. We recommend the use of the terms numerical-age, calibrated-age, relative-age, and correlated-age to describe these levels. We also classify dating methods by type into sideral, isotopic, radiogenic, chemical and biological, geomorphic, and correlation methods. The use of "absolute" is inappropriate for most dating methods, and should be replaced by "numerical." The use of "date" should be minimized in favor of "age" or "age estimate." We recommend use of the abbreviations ka and Ma for most ages; calender dates can be used where appropriate and yr B.P. can be used for radiocarbon ages. ?? 1987.

  17. Hydration Structure of the Quaternary Ammonium Cations

    KAUST Repository

    Babiaczyk, Wojtek Iwo

    2010-11-25

    Two indicators of the hydropathicity of small solutes are introduced and tested by molecular dynamics simulations. These indicators are defined as probabilities of the orientation of water molecules\\' dipoles and hydrogen bond vectors, conditional on a generalized distance from the solute suitable for arbitrarily shaped molecules. Using conditional probabilities, it is possible to distinguish features of the distributions in close proximity of the solute. These regions contain the most significant information on the hydration structure but cannot be adequately represented by using, as is usually done, joint distance-angle probability densities. Our calculations show that using our indicators a relative hydropathicity scale for the interesting test set of the quaternary ammonium cations can be roughly determined. © 2010 American Chemical Society.

  18. Energy consumption maps for quaternary distillation sequences

    DEFF Research Database (Denmark)

    Gomez-Castro, F.I.; Ramírez-Vallejo, N.E.; Segovia-Hernandez, J.G.

    2016-01-01

    of the solutions space. For the separation of ternary mixtures, Tedder and Rudd (1978) presented a composition map for which thermally coupled systems allowed energy savings. However, the scenario is different for quaternary mixtures, since no similar information is available. Therefore, in this work, energy...... be generated for the separation of multicomponent mixtures. This fact is an advantage, since a wide portfolio of alternatives can be used to separate a specific mixture; however, this is also a disadvantage since a lot of alternatives must be explored in order to find the optimal one. The optimal configuration......, for a given mixture, depends on the nature of the mixture, usually quantified for ternary mixtures through the ease of separation index (ESI), and also on the feed composition. As can be noticed, the size of the design and optimization problem increases when these variables are considered in the generation...

  19. Antimicrobial Polymeric Materials with Quaternary Ammonium and Phosphonium Salts

    Directory of Open Access Journals (Sweden)

    Yan Xue

    2015-02-01

    Full Text Available Polymeric materials containing quaternary ammonium and/or phosphonium salts have been extensively studied and applied to a variety of antimicrobial-relevant areas. With various architectures, polymeric quaternary ammonium/phosphonium salts were prepared using different approaches, exhibiting different antimicrobial activities and potential applications. This review focuses on the state of the art of antimicrobial polymers with quaternary ammonium/phosphonium salts. In particular, it discusses the structure and synthesis method, mechanisms of antimicrobial action, and the comparison of antimicrobial performance between these two kinds of polymers.

  20. Quaternary Logic and Applications Using Multiple Quantum Well Based SWSFETs

    Directory of Open Access Journals (Sweden)

    P. Gogna

    2012-11-01

    Full Text Available This paper presents Spatial Wavefunction-Switched Field-Effect Transistors (SWSFET to implement efficient quaternary logic and arithmetic functions. Various quaternary logic gates and digital building blocks are presented using SWSFETs. In addition, arithmetic operation with full adder using novel logic algebra is also presented. The SWSFET based implementation of digital logic, cache and arithmetic block results in up to 75% reduction in transistor count and up to 50% reduction in data interconnect densities. Simulations of quaternary logic gates using the BSIM equivalent models for SWSFET channels are also described.

  1. Quaternary Fault and Fold Database of the United States

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — The Quaternary Fault and Fold Database contains the results of thousands of scientific assessments of faults and associated folds in the United States that...

  2. Quaternary alluvial stratigraphy and palaeoclimatic reconstruction at the Thar margin

    DEFF Research Database (Denmark)

    Jain, M.; Tandon, S.K.

    2003-01-01

    Quaternary alluvial record at the Thar desert margin has been examined using the exposed succession along Mahudi, Sabarmati river, Western India. Different alluvial facies, their associations and granulometry have been studied for palaeoenvironmental reconstruction. Clay mineral indices smectite...

  3. A Quaternary Geomagnetic Instability Time Scale

    Science.gov (United States)

    Singer, B. S.

    2013-12-01

    Reversals and excursions of Earth's geomagnetic field create marker horizons that are readily detected in sedimentary and volcanic rocks worldwide. An accurate and precise chronology of these geomagnetic field instabilities is fundamental to understanding several aspects of Quaternary climate, dynamo processes, and surface processes. For example, stratigraphic correlation between marine sediment and polar ice records of climate change across the cryospheres benefits from a highly resolved record of reversals and excursions. The temporal patterns of dynamo behavior may reflect physical interactions between the molten outer core and the solid inner core or lowermost mantle. These interactions may control reversal frequency and shape the weak magnetic fields that arise during successive dynamo instabilities. Moreover, weakening of the axial dipole during reversals and excursions enhances the production of cosmogenic isotopes that are used in sediment and ice core stratigraphy and surface exposure dating. The Geomagnetic Instability Time Scale (GITS) is based on the direct dating of transitional polarity states recorded by lava flows using the 40Ar/39Ar method, in parallel with astrochronologic age models of marine sediments in which O isotope and magnetic records have been obtained. A review of data from Quaternary lava flows and sediments yields a GITS comprising 10 polarity reversals and 27 excursions during the past 2.6 million years. Nine of the ten reversals bounding chrons and subchrons are associated with 40Ar/39Ar ages of transitionally-magnetized lava flows. The tenth, the Guass-Matuyama chron boundary, is tightly bracketed by 40Ar/39Ar dated ash deposits. Of the 27 well-documented excursions, 14 occurred during the Matuyama chron and 13 during the Brunhes chron; 19 have been dated directly using the 40Ar/39Ar method on transitionally-magnetized volcanic rocks and form the backbone of the GITS. Excursions are clearly not the rare phenomena once thought

  4. Known and suggested quaternary faulting in the midcontinent United States

    Science.gov (United States)

    Wheeler, R.L.; Crone, A.J.

    2001-01-01

    The midcontinent United States between the Appalachian and Rocky Mountains contains 40 known faults or other potentially tectonic features for which published geologic information shows or suggests Quaternary tectonic faulting. We report results of a systematic evaluation of published and other publicly available geologic evidence of Quaternary faulting. These results benefit seismic-hazard assessments by (1) providing some constraints on the recurrence intervals and magnitudes of large, prehistoric earthquakes, and (2) identifying features that warrant additional study. For some features, suggested Quaternary tectonic faulting has been disproved, whereas, for others, the suggested faulting remains questionable. Of the 40 features, nine have clear geologic evidence of Quaternary tectonic faulting associated with prehistoric earthquakes, and another six features have evidence of nontectonic origins. An additional 12 faults, uplifts, or historical seismic zones lack reported paleoseismological evidence of large. Quaternary earthquakes. The remaining 13 features require further paleoseismological study to determine if they have had Quaternary earthquakes that were larger than any known from local historical records; seven of these 13 features are in or near urbanized areas where their study could affect urban hazard estimates. These seven are: (1) the belt of normal faults that rings the Gulf of Mexico from Florida to Texas. (2) the Northeast Ohio seismic zone, (3) the Valmont and (4) Goodpasture faults of Colorado. (5) the Champlain lowlands normal faults of New York State and Vermont, and (6) the Lexington and (7) Kentucky River fault systems of eastern Kentucky. Published by Elsevier Science B.V.

  5. Mutagenicity of quaternary ammonium salts containing carbohydrate moieties

    Energy Technology Data Exchange (ETDEWEB)

    Dmochowska, Barbara [Department of Carbohydrate Chemistry, University of Gdansk, Sobieskiego 18, 80-952 Gdansk (Poland); Piosik, Jacek; Woziwodzka, Anna [Intercollegiate Faculty of Biotechnology, University of Gdansk and Medical University of Gdansk, Kladki 24, 80-822 Gdansk (Poland); Sikora, Karol; Wisniewski, Andrzej [Department of Carbohydrate Chemistry, University of Gdansk, Sobieskiego 18, 80-952 Gdansk (Poland); Wegrzyn, Grzegorz, E-mail: wegrzyn@biotech.univ.gda.pl [Department of Molecular Biology, University of Gdansk, Kladki 24, 80-822 Gdansk (Poland)

    2011-10-15

    Highlights: {yields} A series of quaternary ammonium salts containing carbohydrate moieties, with configuration D-galacto, D-gluco and D-manno, was synthesized and characterized. {yields} The quaternary ammonium salts containing carbohydrate moieties revealed potent mutagenic activities, as assessed by using the Vibrio harveyi bioluminescence mutagenicity test. {yields} The N-[2-(D-glycopyranosyloxy)ethyl]-N,N,N-trimethylaminium salts were of the highest activity in the mutagenicity assay. {yields} We suggest that quaternary ammonium salts may be more hazardous than previously supposed. - Abstract: Quaternary ammonium salts are widely used in industrial, agricultural, healthcare and domestic applications. They are believed to be safe compounds, with little or no health hazard to humans. However, in this report, we demonstrate that a series of newly synthesized quaternary ammonium salts containing carbohydrate moieties reveal potent mutagenic activities, as assessed by using the Vibrio harveyi bioluminescence mutagenicity test. D-Gluco- and D-galacto-derivatives were found to have a higher mutagenic potential than D-manno-derivatives. Among the former groups of compounds, the N-[2-(D-glycopyranosyloxy)ethyl]-N,N,N-trimethylaminium salts were of the highest activity in the mutagenicity assay. These results suggest that the safety of quaternary ammonium salts may be lower than previously supposed, indicating a need for testing such compounds for their mutagenicity.

  6. A Quaternary fault database for central Asia

    Science.gov (United States)

    Mohadjer, Solmaz; Ehlers, Todd Alan; Bendick, Rebecca; Stübner, Konstanze; Strube, Timo

    2016-02-01

    Earthquakes represent the highest risk in terms of potential loss of lives and economic damage for central Asian countries. Knowledge of fault location and behavior is essential in calculating and mapping seismic hazard. Previous efforts in compiling fault information for central Asia have generated a large amount of data that are published in limited-access journals with no digital maps publicly available, or are limited in their description of important fault parameters such as slip rates. This study builds on previous work by improving access to fault information through a web-based interactive map and an online database with search capabilities that allow users to organize data by different fields. The data presented in this compilation include fault location, its geographic, seismic, and structural characteristics, short descriptions, narrative comments, and references to peer-reviewed publications. The interactive map displays 1196 fault traces and 34 000 earthquake locations on a shaded-relief map. The online database contains attributes for 123 faults mentioned in the literature, with Quaternary and geodetic slip rates reported for 38 and 26 faults respectively, and earthquake history reported for 39 faults. All data are accessible for viewing and download via http://www.geo.uni-tuebingen.de/faults/. This work has implications for seismic hazard studies in central Asia as it summarizes important fault parameters, and can reduce earthquake risk by enhancing public access to information. It also allows scientists and hazard assessment teams to identify structures and regions where data gaps exist and future investigations are needed.

  7. A Quaternary Fault Database for Central Asia

    Science.gov (United States)

    Mohadjer, S.; Ehlers, T. A.; Bendick, R.; Stübner, K.; Strube, T.

    2015-09-01

    Earthquakes represent the highest risk in terms of potential loss of lives and economic damage for Central Asian countries. Knowledge of fault location and behavior is essential in calculating and mapping seismic hazard. Previous efforts in compiling fault information for Central Asia have generated a large amount of data that are published in limited-access journals with no digital maps publicly available, or are limited in their description of important fault parameters such as slip rates. This study builds on previous work by improving access to fault information through a web-based interactive map and an online database with search capabilities that allow users to organize data by different fields. The data presented in this compilation include fault location, its geographic, seismic and structural characteristics, short descriptions, narrative comments and references to peer-reviewed publications. The interactive map displays 1196 fault segments and 34 000 earthquake locations on a shaded-relief map. The online database contains attributes for 122 faults mentioned in the literature, with Quaternary and geodetic slip rates reported for 38 and 26 faults respectively, and earthquake history reported for 39 faults. This work has implications for seismic hazard studies in Central Asia as it summarizes important fault parameters, and can reduce earthquake risk by enhancing public access to information. It also allows scientists and hazard assessment teams to identify structures and regions where data gaps exist and future investigations are needed.

  8. Quaternary stratigraphy and palaeogeography of Poland

    Science.gov (United States)

    Marks, Leszek; Dzierżek, Jan; Janiszewski, Robert; Kaczorowski, Jarosław; Lindner, Leszek; Majecka, Aleksandra; Makos, Michał; Szymanek, Marcin; Tołoczko-Pasek, Anna; Woronko, Barbara

    2016-09-01

    Though the stratigraphical and palaeogeographical framework of the Quaternary in Poland is still to be completed, several crucial points have been confirmed recently. The preglacial series, accepted for years as belonging to the Lower Pleistocene, is undoubtedly of Early Pliocene age, with a huge hiatus above almost until the uppermost Lower Pleistocene. The earliest glaciation in Poland (Nidanian) occurred at about 900 ka BP when the ice sheet reached the mid-southern part of the country. The following Podlasian Interglacial embraced the Brunhes/Matuyama boundary in the middle, in a similar fashion to the corresponding Cromerian Complex in Western Europe. The late Early and early Middle Pleistocene interglacials in Poland comprised 2-3 optima each, whereas every one of the younger interglacials was characterised by a single optimum only. The Late Vistulian ice sheet was most extensive in the western part of Poland (Leszno Phase) whereas the younger Poznań Phase was more extensive in the central and eastern part of the country. This was due to the varied distance from the glaciation center in Scandinavia, making the ice sheet margin reach a terminal position in different times. Palaeoclimatological research in the Tatra Mountains has provided new evidence for the atmospheric circulation over Europe. During cold phases of the Pleistocene in Poland a continental climate extended further westwards, quite the opposite that occurring during warmer intervals.

  9. A Quaternary Fault Database for Central Asia

    Directory of Open Access Journals (Sweden)

    S. Mohadjer

    2015-09-01

    Full Text Available Earthquakes represent the highest risk in terms of potential loss of lives and economic damage for Central Asian countries. Knowledge of fault location and behavior is essential in calculating and mapping seismic hazard. Previous efforts in compiling fault information for Central Asia have generated a large amount of data that are published in limited-access journals with no digital maps publicly available, or are limited in their description of important fault parameters such as slip rates. This study builds on previous work by improving access to fault information through a web-based interactive map and an online database with search capabilities that allow users to organize data by different fields. The data presented in this compilation include fault location, its geographic, seismic and structural characteristics, short descriptions, narrative comments and references to peer-reviewed publications. The interactive map displays 1196 fault segments and 34 000 earthquake locations on a shaded-relief map. The online database contains attributes for 122 faults mentioned in the literature, with Quaternary and geodetic slip rates reported for 38 and 26 faults respectively, and earthquake history reported for 39 faults. This work has implications for seismic hazard studies in Central Asia as it summarizes important fault parameters, and can reduce earthquake risk by enhancing public access to information. It also allows scientists and hazard assessment teams to identify structures and regions where data gaps exist and future investigations are needed.

  10. Quaternary Evolution of Karliova Triple Junction

    Science.gov (United States)

    Sançar, Taylan; Zabcı, Cengiz; Akyüz, H. Serdar

    2013-04-01

    The arguments to explain Quaternary evolution of Karlıova Triple Junction (KTJ) depends upon two different analogue models. The compressional type of Prandtl Cell Model (PCM) and 60 km wide shear zone with concomitant counter clockwise block rotation used to modelled for west and east of the KTJ respectively. The data for the model of west of the KTJ acquired by extensive field studies, and quantified geomorphic features. Compressional PCM put forward that behavior of slip lines controlled by boundary faults. But the model is not enough to explain slip distribution, age relation of them. At west of the KTJ boundary faults presented by eastern most segments of the North Anatolian Fault Zone (NAFZ) and the East Anatolian Fault Zone (EAFZ). Slip lines, however, presented by Bahçeli and Toklular faults. Both field studies and morphometric analyses undisputedly set forth that there are two different fault types between the NAFZ and EAFZ. The most strain loaded fault type, which are positioned near the NAFZ, start as a strike-slip fault and when it turn to SE its sense of motion change to oblique normal due to changing orientation of principal stress axes. The new orientation of stress axes exposed in the field as a special kind of caprock -cuesta-. The younger slip lines formed very close to junction point and accommodate less slip. Even though slip trajectories started from the boundary faults in compressional PCM, at the west of KTJ, right lateral trajectories more clearly formed close the NAFZ and left lateral trajectories, relatively less strain loaded fault type, are poorly formed close the EAFZ . We think that, this differences between KTJ and compressional PCM result from the distinction of velocity of boundary faults. East of the KTJ governed by completely different mechanism. The region controlled two main fault systems. The Varto Fault Zone (VFZ), the eastern branch of the KTJ, and Murat Fault (MF) delimited the region from north and south respectively. The

  11. Quaternary Magmatism in the Cascades - Geologic Perspectives

    Science.gov (United States)

    Hildreth, Wes

    2007-01-01

    Foreward The Cascade magmatic arc is a belt of Quaternary volcanoes that extends 1,250 km from Lassen Peak in northern California to Meager Mountain in Canada, above the subduction zone where the Juan de Fuca Plate plunges beneath the North American Plate. This Professional Paper presents a synthesis of the entire volcanic arc, addressing all 2,300 known Quaternary volcanoes, not just the 30 or so visually prominent peaks that comprise the volcanic skyline. Study of Cascade volcanoes goes back to the geological explorers of the late 19th century and the seminal investigations of Howel Williams in the 1920s and 1930s. However, major progress and application of modern scientific methods and instrumentation began only in the 1970s with the advent of systematic geological, geophysical, and geochemical studies of the entire arc. Initial stimulus from the USGS Geothermal Research Program was enhanced by the USGS Volcano Hazards Program following the 1980 eruption of Mount St. Helens. Together, these two USGS Programs have provided more than three decades of stable funding, staffing, and analytical support. This Professional Paper summarizes the resultant USGS data sets and integrates them with the parallel contributions of other investigators. The product is based upon an all-encompassing and definitive geological database, including chemical and isotopic analyses to characterize the rocks and geochronology to provide the critical time constraints. Until now, this massive amount of data has not been summarized, and a systematic and uniform interpretation firmly grounded in geological fact has been lacking. Herein lies the primary utility of this Cascade volume. It not only will be the mandatory starting point for new workers, but also will provide essential geological context to broaden the perspectives of current investigators of specific Cascade volcanoes. Wes Hildreth's insightful understanding of volcanic processes and his uncompromising scientific integrity make him

  12. The isotope hydrology of Quaternary climate change.

    Science.gov (United States)

    Darling, W G

    2011-04-01

    Understanding the links between climate change and human migration and culture is an important theme in Quaternary archaeology. While oxygen and hydrogen stable isotopes in high-latitude ice cores provide the ultimate detailed record of palaeoclimate extending back to the Middle Pleistocene, groundwater can act as a climate archive for areas at lower latitudes, permitting a degree of calibration for proxy records such as lake sediments, bones, and organic matter. Not only can oxygen and hydrogen stable isotopes be measured on waters, but the temperature of recharge can be calculated from the amount of the atmospheric noble gases neon, argon, krypton, and xenon in solution, while residence time can be estimated from the decay of the radioisotopes carbon-14, chlorine-36, and krypton-81 over timescales comparable to the ice core record. The Pleistocene-Holocene transition is well characterised in aquifers worldwide, and it is apparent that isotope-temperature relationships of the present day are not necessarily transferable to past climatic regimes, with important implications for the interpretation of proxy isotope data. Groundwaters dating back to one million years, i.e., to beyond the Middle Pleistocene, are only found in major aquifer basins and information is relatively sparse and of low resolution. Speleothem fluid inclusions offer a way of considerably increasing this resolution, but both speleothem formation and large-scale groundwater recharge requires humid conditions, which may be relatively infrequent for areas currently experiencing arid climates. Both types of record therefore require caution in their interpretation when considering a particular archaeological context.

  13. The biological activity of quaternary ammonium salts (QASs

    Directory of Open Access Journals (Sweden)

    Ewa Obłąk

    2010-04-01

    Full Text Available Quaternary ammonium salts (QASs, especially those of cationic surfactant character, are applied as antibacterial and antifungal disinfectants. QASs affect lipid-enveloped viruses, including human immunodeficiency virus (HIV and hepatitis B virus (HBV, but not non-enveloped viruses. These compounds are extensively used in domestic (as ingredients of shampoos, hair conditioners, agricultural (as fungicides, pesticides, insecticides, healthcare (as medications, and industrial applications (as biocides, fabric softeners, corrosion inhibitors. The extensive use of quaternary ammonium disinfectants in recent years has led to the development of resistance in microorganisms to these drugs. Thus [i]Staphylococcus[/i] [i]aureus[/i] strains contain the plasmid-carrying genes [i]qacA[/i] and [i]qacB [/i]encoding resistance to quaternary ammonium compounds and acriflavine. The membrane proteins QacA and QacB confer multidrug resistance by exporting the compound by the proton motive force which is generated by the transmembrane electrochemical proton gradient.

  14. [The biological activity of quaternary ammonium salts (QASs)].

    Science.gov (United States)

    Obłak, Ewa; Gamian, Andrzej

    2010-04-19

    Quaternary ammonium salts (QASs), especially those of cationic surfactant character, are applied as antibacterial and antifungal disinfectants. QASs affect lipid-enveloped viruses, including human immunodeficiency virus (HIV) and hepatitis B virus (HBV), but not non-enveloped viruses. These compounds are extensively used in domestic (as ingredients of shampoos, hair conditioners), agricultural (as fungicides, pesticides, insecticides), healthcare (as medications), and industrial applications (as biocides, fabric softeners, corrosion inhibitors). The extensive use of quaternary ammonium disinfectants in recent years has led to the development of resistance in microorganisms to these drugs. Thus Staphylococcus aureus strains contain the plasmid-carrying genes qacA and qacB encoding resistance to quaternary ammonium compounds and acriflavine. The membrane proteins QacA and QacB confer multidrug resistance by exporting the compound by the proton motive force which is generated by the transmembrane electrochemical proton gradient.

  15. Quaternary naltrexone reverses radiogenic and morphine-induced locomotor hyperactivity

    Energy Technology Data Exchange (ETDEWEB)

    Mickley, G.A.; Stevens, K.E.; Galbraith, J.A.; White, G.A.; Gibbs, G.L.

    1984-04-01

    The present study attempted to determine the relative role of the peripheral and central nervous system in the production of morphine-induced or radiation-induced locomotor hyperactivity of the mouse. Toward this end, we used a quaternary derivative of an opiate antagonist (naltrexone methobromide), which presumably does not cross the blood-brain barrier. Quaternary naltrexone was used to challenge the stereotypic locomotor response observed in these mice after either an i.p. injection of morphine or exposure to 1500 rads /sup 60/Co. The quaternary derivative of naltrexone reversed the locomotor hyperactivity normally observed in the C57BL/6J mouse after an injection of morphine. It also significantly attenuated radiation-induced locomotion. The data reported here support the hypothesis of endorphin involvement in radiation-induced and radiogenic behaviors. However, these conclusions are contingent upon further research which more fully evaluates naltrexone methobromide's capacity to cross the blood-brain barrier.

  16. Absolute age determination of quaternary fault and formation

    Energy Technology Data Exchange (ETDEWEB)

    Cheong, Chang Sik; Lee, Kwang Sik; Choi, Man Sik [Korea Basic Science Institute, Seoul (Korea, Republic of)] (and others)

    2002-04-15

    The annual ('01-'01) objective of this project is to data the fault activity for the presumed quaternary fault zones to the western part of the Ulsam fault system and southeastern coastal area near the Wolseong Nuclear Power Plant. Rb-Sr, K-Ar, OSL, C-14 and U-series disequilibrium methods were applied to the fault rocks, organic matter and quaternary formations collected from the Pyeonghae, Bogyeongsa, Yugyeri, Byegkye, Gacheon-1 and Joil outcrops of the Yangsan fault system, the Baenaegol outcrop of the Moryang fault system, the Susyongji(Madong-2), Singye, Hwalseongri, Ipsil and Wonwonsa outcrops of the Ulsan fault system and from quaternary marine terraces (Oryoo and Kwangseong sites) in the southeastern coastal area. The experimental procedure of the OSL SAR protocol was reexamined to get more reliable dating results.

  17. Atmospheric effects on Quaternary polarization encoding for free space communication

    Science.gov (United States)

    Soorat, Ram; Vudayagiri, Ashok

    2016-10-01

    We have simulated atmospheric effects such as fog and smoke in laboratory environment to simulate depolarisation due to atmospheric effects during a free space optical communi- cation. This has been used to study noise in two components of quaternary encoding for polarization shift keying. Individual components of a Quaternary encoding, such as vertical and horizontal as well as 45$^\\circ$ and 135$^\\circ$ , are tested separately and indicates that the depo- larization effects are different for these two situation. However, due to a differential method used to extract information bits, the protocol shows extremely low bit error rates. The information obtained is useful during deployment of a fully functional Quaternary encoded PolSK scheme in free space.

  18. Origin of Quaternary Red Clay of Southern Anhui Province

    Institute of Scientific and Technical Information of China (English)

    HUXUEFENG; YUANGUODONG; 等

    1998-01-01

    The particle-size distribution,heavy mineral constituents and rare earth elements(REE) characteristics of the Quaternary red clay of southern Anhui Province were studied to explore the origin of the clay.The results showed that the clay had some properties of areolian deposits,which could be compared with,those of the loess in North China ;and its chondrite-normalized curves of REE were similar to those of the Xiashu loess implying tha they shared the same orighin.It was concluded in combination with the results rported by other researchers that the Quaternary red clay of southern Anhui Province originated from aolian deposts, and this could reveal the cycles of warm and cold climates in the area during the Quaternary period.

  19. Electrochemical oxidation of quaternary ammonium electrolytes : Unexpected side reactions in organic electrochemistry

    NARCIS (Netherlands)

    Nouri Nigjeh, Eslam; de Vries, Marcel; Bruins, Andries P.; Bischoff, Rainer; Permentier, Hjalmar P.

    2012-01-01

    Quaternary ammonium salts are among the most widely used electrolytes in organic electrochemistry, but there is little known about their unwanted side oxidation reactions. We have, therefore, studied the constant potential oxidation products of quaternary ammonium electrolytes using mass spectrometr

  20. Antibacterial activity of reactive quaternary ammonium compounds in solution and in nonleachable coatings

    NARCIS (Netherlands)

    Gozzelino, G.; Romero Tobar, D.E.; Chaitiemwong, N.; Hazeleger, W.C.; Beumer, R.R.

    2011-01-01

    Antibacterial polymers suitable for coating applications without leaching of the biocidal component have been obtained by UV copolymerization of acrylic resins with acrylic monomers containing quaternary ammonium moieties. Suitable reactive biocides, based on quaternary ammonium monomers (QAMs), end

  1. Quaternary Structure Analyses of an Essential Oligomeric Enzyme.

    Science.gov (United States)

    Soares da Costa, Tatiana P; Christensen, Janni B; Desbois, Sebastien; Gordon, Shane E; Gupta, Ruchi; Hogan, Campbell J; Nelson, Tao G; Downton, Matthew T; Gardhi, Chamodi K; Abbott, Belinda M; Wagner, John; Panjikar, Santosh; Perugini, Matthew A

    2015-01-01

    Here, we review recent studies aimed at defining the importance of quaternary structure to a model oligomeric enzyme, dihydrodipicolinate synthase. This will illustrate the complementary and synergistic outcomes of coupling the techniques of analytical ultracentrifugation with enzyme kinetics, in vitro mutagenesis, macromolecular crystallography, small angle X-ray scattering, and molecular dynamics simulations, to demonstrate the role of subunit self-association in facilitating protein dynamics and enzyme function. This multitechnique approach has yielded new insights into the molecular evolution of protein quaternary structure.

  2. Kinetic Study of MOCVD Ⅲ-Ⅴ Quaternary Antimonides

    Institute of Scientific and Technical Information of China (English)

    1999-01-01

    The kinetics of MOCVD GaInAsSb and AlGaAsSb was studied by the growth rate as a function of growth temperature and partial pressure of Ⅲ and Ⅴ MO species. The diffusion theory was used to explain the mass transport processes in MOCVD Ⅲ-Ⅴ quaternary antimonides. On the basis of the discussion about their growth kinetics and epilayer properties, the good quality multi-epilayers of these two quaternary antimonides and their photodetectors and arrays with wavelength of 1.8~2.3 μm and detectivities of D*>109 cm Hz1/2 W-1 were obtained.

  3. Session Introduction: Global correlation on late Quaternary paleovalley systems

    NARCIS (Netherlands)

    Cohen, K.M.; Amorosi, A.; Busschers, F.S.; Hori, K.; Tanabe, S.

    2015-01-01

    All around the world, paleovalley systems have trapped great amounts of deposits and hold a quite complete Late Quaternary record. Uniquely, these records directly interlink the shelf marine with the hinterland fluvial realms. In the vicinity of ice sheets, in similar ways, paleovalleys interlink th

  4. Significant differences in late Quaternary bedrock erosion and transport

    DEFF Research Database (Denmark)

    Andrews, John; Bjørk, Anders Anker; Eberl, Dennis;

    2015-01-01

    We use quantitative X-ray diffraction to determine the mineralogy of late Quaternary marine sediments from the West and East Greenland shelves offshore from early Tertiary basalt outcrops. Despite the similar basalt outcrop area (60 000–70 000 km2), there are significant differences between East ...

  5. Application of Analytic Geometry to Ternary and Quaternary Diagrams.

    Science.gov (United States)

    MacCarthy, Patrick

    1986-01-01

    Advantages of representing ternary and quaternary composition diagrams by means of rectangular coordinates were pointed out in a previous paper (EJ 288 693). A further advantage of that approach is that analytic geometry, based on rectangular coordinates, is directly applicable as demonstrated by the examples presented. (JN)

  6. A revision of the Pliocene and Quaternary Lutrinae from Europe

    NARCIS (Netherlands)

    Willemsen, G.F.

    1992-01-01

    In this paper, a revision of the Pliocene and Quaternary Lutrinae from Europe is presented. Such a revision, including fossil material, has not been published since the work of Pohle (1919). Three tribes within the Lutrinae are recognized: the Lutrini, the Aonyxini and the Enhydrini. The latter comp

  7. Comparative analyses of quaternary arrangements in homo-oligomeric proteins in superfamilies: Functional implications.

    Science.gov (United States)

    Sudha, Govindarajan; Srinivasan, Narayanaswamy

    2016-09-01

    A comprehensive analysis of the quaternary features of distantly related homo-oligomeric proteins is the focus of the current study. This study has been performed at the levels of quaternary state, symmetry, and quaternary structure. Quaternary state and quaternary structure refers to the number of subunits and spatial arrangements of subunits, respectively. Using a large dataset of available 3D structures of biologically relevant assemblies, we show that only 53% of the distantly related homo-oligomeric proteins have the same quaternary state. Considering these homologous homo-oligomers with the same quaternary state, conservation of quaternary structures is observed only in 38% of the pairs. In 36% of the pairs of distantly related homo-oligomers with different quaternary states the larger assembly in a pair shows high structural similarity with the entire quaternary structure of the related protein with lower quaternary state and it is referred as "Russian doll effect." The differences in quaternary state and structure have been suggested to contribute to the functional diversity. Detailed investigations show that even though the gross functions of many distantly related homo-oligomers are the same, finer level differences in molecular functions are manifested by differences in quaternary states and structures. Comparison of structures of biological assemblies in distantly and closely related homo-oligomeric proteins throughout the study differentiates the effects of sequence divergence on the quaternary structures and function. Knowledge inferred from this study can provide insights for improved protein structure classification and function prediction of homo-oligomers. Proteins 2016; 84:1190-1202. © 2016 Wiley Periodicals, Inc.

  8. Distribution of acidic groundwater around quaternary volcanoes in Japan

    Energy Technology Data Exchange (ETDEWEB)

    Asamori, Koichi; Ishimaru, Tsuneari; Iwatsuki, Teruki [Japan Nuclear Cycle Development Inst., Toki, Gifu (Japan). Tono Geoscience Center

    2002-06-01

    One important key issue in the understanding of the long-term stability of the geological environment is the influence of magmatism. In this study, we examined the general spatial distribution of acidic groundwater around Quaternary volcanoes in Japan using a database of groundwater geochemistry. The results may be summarized as follows: Acidic groundwater with pH < 4.8 mainly occur in present volcanic regions and are distributed from several kilometers to about 20 km from Quaternary volcanoes. The pH value of groundwater tends to decrease with increasing distance from a volcano. However, these results may be affected by inhomogeneity of groundwater data distribution and the characteristic activity of each volcano. In order to assess a specific volcanic region, a detailed analysis that considers volcanic activity, using a data set with high spatial density is necessary. (author)

  9. Studies on a Cationically Modified Quaternary Ammonium Salt of Lignin

    Institute of Scientific and Technical Information of China (English)

    YANG Ai-li; JIANG Wen-ju

    2007-01-01

    A new quaternary ammonium salt monomer was synthesized and a quaternary amination of lignin( noted as QL),with the monomer was carried out by grafting copolymerization. The products were characterized by Fourier Transform Infrared spectroscopy(FTIR). The experimental results indicate that the yield of the monomer was 99.06%, and the conversion of the monomer and the grafting yield of QL were 93.69% and 185.78%, respectively. The feasibility of QL as the fiocculant to be applied in color removal of five artificial dyes, eriochrome black T( dye A), gongo red( dye B), direct fast black G (dye C), cuprofix blue green B (dye D), and acid black ATT (dye E) was examined.Results show that QL exhibits the favorable flocculation performance and high stability.

  10. Synthesis and Antibacterial Activity of Novel Quaternary Ammonium Pyridoxine Derivatives.

    Science.gov (United States)

    Shtyrlin, Nikita V; Sapozhnikov, Sergey V; Koshkin, Sergey A; Iksanova, Alfiya G; Sabirov, Arthur H; Kayumov, Airat R; Nureeva, Aliya A; Zeldi, Marina I; Shtyrlin, Yurii G

    2015-01-01

    A series of 26 quaternary ammonium pyridoxine derivatives were synthesized and their cytotoxicity and antibacterial activities against clinically relevant bacterial strains were tested in vitro. The antibacterial activity of mono-ammonium salts increased with the rise of the lipophilicity and compound 3,3,5-trimethyl-8,8-dioctyl-1,7,8,9-tetrahydro-[1,3]dioxino[5,4-d]pyrrolo[3,4-b]pyridin-8-ium chloride (2d) reaches a maximum among them. Bis-ammonium salt of pyridoxine 4 with two dimethyloctylamine groups also demonstrated high antibacterial activity despite lower lipophilicity. The results of MTT assay indicated that HEK 293 cells were more sensitive than HSF to quaternary ammonium pyridoxine derivatives. Compounds 2d and 4 did not induce the damage of the DNA and might be of interest in the development of new antimicrobials.

  11. Active tectonics of the Oran (Algeria) Quaternary plain

    Science.gov (United States)

    youcef, Bouhadad; rabah, Bensalem; e-hadi, oubaiche

    2016-04-01

    The Oran region, in north-western Algeria, has been hit several times in the past by destructive moderate-sized and strong earthquakes. The Oran October 9th , 1790 (I0= X) was among the strongest seismic events in the western Mediterranean area comparable, if we consider the described effects, to the El- Asnam (1980, Ms=7.3) and Zemmouri (2003, Mw=6.8) earthquakes. Such strong seismic events requires the presence of major active geological structures that are re-activated several times in the past. In this work we present results of a multi- disciplinary study combining geomorphic analysis, field earthquake geological investigations and geophysical methods, undertaken to study the southern border of the Oran Quaternary plain. A 50 km long, SW-dipping and NE-SW trending active fault has been identified that showing clear quaternary deformation. Keywords: earthquake geology, active fault, geomorphic, geophysics, Algeria.

  12. New quantum codes constructed from quaternary BCH codes

    Science.gov (United States)

    Xu, Gen; Li, Ruihu; Guo, Luobin; Ma, Yuena

    2016-10-01

    In this paper, we firstly study construction of new quantum error-correcting codes (QECCs) from three classes of quaternary imprimitive BCH codes. As a result, the improved maximal designed distance of these narrow-sense imprimitive Hermitian dual-containing quaternary BCH codes are determined to be much larger than the result given according to Aly et al. (IEEE Trans Inf Theory 53:1183-1188, 2007) for each different code length. Thus, families of new QECCs are newly obtained, and the constructed QECCs have larger distance than those in the previous literature. Secondly, we apply a combinatorial construction to the imprimitive BCH codes with their corresponding primitive counterpart and construct many new linear quantum codes with good parameters, some of which have parameters exceeding the finite Gilbert-Varshamov bound for linear quantum codes.

  13. A Synthetic Route to Quaternary Pyridinium Salt-Functionalized Silsesquioxanes

    Directory of Open Access Journals (Sweden)

    Nataliya Kostenko

    2012-01-01

    Full Text Available A synthetic route to potentially biocidal silsesquioxanes functionalized by quaternary pyridinium functionalities has been developed. N-Alkylation reactions of the precursor compounds 4-(2-(trimethoxysilylethyl-pyridine (5 and 4-(2-trichloro-silylethylpyridine (6 with iodomethane, n-hexylbromide, and n-hexadecylbromide cleanly afforded the corresponding N-alkylpyridinium salts (7–10. The synthesis of a 4-(2-ethylpyridine POSS derivative (2 was achieved by capping of the silsesquioxane trisilanol Cy7Si7O9(OH3 (1 via two different preparative routes. Attempts to use compound 2 as precursor for quaternary pyridinium salt-functionalized POSS derivatives were met with only partial success. Only the reaction with iodomethane cleanly afforded the new N-methylpyridinium salt 12 in high yield, whereas n-hexylbromide and n-hexadecylbromide failed to react with 2 even under forcing conditions.

  14. Geological provenance of Quaternary deposits from the southeastern Brazilian coast

    Energy Technology Data Exchange (ETDEWEB)

    Anjos, R.M. [Instituto de Fisica, Universidade Federal Fluminense, Av. Gal. Milton Tavares de Souza s/n, Gragoata, Campus da Praia Vermelha, 24210-346, Niteroi, R.J. (Brazil)]. E-mail: meigikos@if.uff.br; Veiga, R. [Instituto de Fisica, Universidade Federal Fluminense, Av. Gal. Milton Tavares de Souza s/n, Gragoata, Campus da Praia Vermelha, 24210-346, Niteroi, R.J. (Brazil); Carvalho, C. [Instituto de Fisica, Universidade Federal Fluminense, Av. Gal. Milton Tavares de Souza s/n, Gragoata, Campus da Praia Vermelha, 24210-346, Niteroi, R.J. (Brazil); Macario, K.D. [Instituto de Fisica, Universidade Federal Fluminense, Av. Gal. Milton Tavares de Souza s/n, Gragoata, Campus da Praia Vermelha, 24210-346, Niteroi, R.J. (Brazil); Gomes, P.R.S. [Instituto de Fisica, Universidade Federal Fluminense, Av. Gal. Milton Tavares de Souza s/n, Gragoata, Campus da Praia Vermelha, 24210-346, Niteroi, R.J. (Brazil)

    2007-05-01

    Natural gamma radiation measurements of beach sand deposits were performed with the aim of understanding the provenance and transport processes of sediments along the coastal zone of three Brazilian States. The method employs thorium, uranium and potassium as tracers of the mineralogical properties of beach sand minerals, which reflect the geological history of transport and sorting processes. A considerable positive correlation with the geological evolution of these Quaternary coastal deposits was observed.

  15. The impact of Quaternary Ice Ages on mammalian evolution.

    Science.gov (United States)

    Lister, Adrian M

    2004-02-29

    The Quaternary was a time of extensive evolution among mammals. Most living species arose at this time, and many of them show adaptations to peculiarly Quaternary environments. The latter include continental northern steppe and tundra, and the formation of lakes and offshore islands. Although some species evolved fixed adaptations to specialist habitats, others developed flexible adaptations enabling them to inhabit broad niches and to survive major environmental changes. Adaptation to short-term (migratory and seasonal) habitat change probably played a part in pre-adapting mammal species to the longer-term cyclical changes of the Quaternary. Fossil evidence indicates that environmental changes of the order of thousands of years have been sufficient to produce subspeciation, but speciation has typically required one hundred thousand to a few hundred thousand years, although there are both shorter and longer exceptions. The persistence of taxa in environments imposing strong selective regimes may have been important in forcing major adaptive change. Individual Milankovitch cycles are not necessarily implicated in this process, but nor did they generally inhibit evolutionary change among mammals: many evolutionary divergences built over multiple climatic cycles. Deduction of speciation timing requires input from fossils and modern phenotypic and breeding data, to complement and constrain mitochondrial DNA coalescence dates which appear commonly to overestimate taxic divergence dates and durations of speciation. Migrational and evolutionary responses to climate change are not mutually exclusive but, on the contrary, may be synergistic. Finally, preliminary analysis suggests that faunal turnover, including an important element of speciation, was elevated in the Quaternary compared with the Neogene, at least in some biomes. Macroevolutionary species selection or sorting has apparently resulted in a modern mammalian fauna enriched with fast-reproducing and/or adaptively

  16. Microstructure development in Al-Cu-Ag-Mg quaternary alloy

    Science.gov (United States)

    Zhou, Bin; Froyen, L.

    2012-01-01

    The solidification behaviour of multi-component and multi-phase systems has been largely investigated in binary and ternary alloys. In the present study, a quaternary model system is proposed based on the well known Al-Cu-Ag and Al-Cu-Mg ternary eutectic alloys. The quaternary eutectic composition and temperature were determined by EDS (Energy Dispersive Spectrometry) and DSC (Differential Scanning Calorimetry) analysis, respectively. The microstructure was then characterised by SEM (Scanning Electron Microscope). In the DSC experiments, two types of quaternary eutectics were determined according to their phase composition. For each type of eutectic, various microstructures were observed, which result in different eutectic compositions. Only one of the determined eutectic compositions was further studied by the controlled growth technique in a vertical Bridgeman type furnace. In the initial part of the directionally solidified sample, competing growth between two-phase dendrites and three-phase eutectics was obtained, which was later transformed to competing growth between three-phase and four-phase eutectics. Moreover, silver enrichment was measured at the solidification front, which is possibly caused by Ag sedimentation due to gravity and Ag rejection from dendritic and three-phase eutectic growth, and its accumulation at the solidification front.

  17. Quaternary tectonic faulting in the Eastern United States

    Science.gov (United States)

    Wheeler, R.L.

    2006-01-01

    Paleoseismological study of geologic features thought to result from Quaternary tectonic faulting can characterize the frequencies and sizes of large prehistoric and historical earthquakes, thereby improving the accuracy and precision of seismic-hazard assessments. Greater accuracy and precision can reduce the likelihood of both underprotection and unnecessary design and construction costs. Published studies proposed Quaternary tectonic faulting at 31 faults, folds, seismic zones, and fields of earthquake-induced liquefaction phenomena in the Appalachian Mountains and Coastal Plain. Of the 31 features, seven are of known origin. Four of the seven have nontectonic origins and the other three features are liquefaction fields caused by moderate to large historical and Holocene earthquakes in coastal South Carolina, including Charleston; the Central Virginia Seismic Zone; and the Newbury, Massachusetts, area. However, the causal faults of the three liquefaction fields remain unclear. Charleston has the highest hazard because of large Holocene earthquakes in that area, but the hazard is highly uncertain because the earthquakes are uncertainly located. Of the 31 features, the remaining 24 are of uncertain origin. They require additional work before they can be clearly attributed either to Quaternary tectonic faulting or to nontectonic causes. Of these 24, 14 features, most of them faults, have little or no published geologic evidence of Quaternary tectonic faulting that could indicate the likely occurrence of earthquakes larger than those observed historically. Three more features of the 24 were suggested to have had Quaternary tectonic faulting, but paleoseismological and other studies of them found no evidence of large prehistoric earthquakes. The final seven features of uncertain origin require further examination because all seven are in or near urban areas. They are the Moodus Seismic Zone (Hartford, Connecticut), Dobbs Ferry fault zone and Mosholu fault (New York

  18. Quaternary basaltic volcanism in the Payenia volcanic province, Argentina

    DEFF Research Database (Denmark)

    Søager, Nina

    The extensive Quaternary volcanism in the Payenia volcanic province, Mendoza, Argentina, is investigated in this study by major and trace element analyses, Sr, Nd, Hf and Pb-isotopic analyses and Zr-Hf isotope dilution data on samples from almost the entire province. The samples are mainly...... in basalts from all the studied volcanic fields in Payenia is signs of lower crustal contamination indicating assimilation of, in some cases, large amounts of trace element depleted, mafic, plagioclase-bearing rocks. The northern Payenia is dominated by backarc basalts erupted between late Pliocene to late...

  19. Mutagenic activity of quaternary ammonium salt derivatives of carbohydrates

    Science.gov (United States)

    Sikora, Karol; Woziwodzka, Anna; Piosik, Jacek; Podgórska, Beata

    2016-01-01

    Summary This paper presents a study on a series of quaternary ammonium salt (QAS) derivatives of glucopyranosides with an elongated hydrophobic hydrocarbon chain. The new N-[6-(β-D-glucopyranosyloxy)hexyl]ammonium bromides and their O-acetyl derivatives were analyzed via 1H and 13C NMR spectroscopy. The mutagenic activity of the newly synthesized QAS was investigated using two different techniques: The Vibrio harveyi luminescence assay and the Ames test. The obtained results support previous findings contesting QAS safety and indicate that QAS, specifically pyridinium derivatives, might be mutagenic. PMID:27559394

  20. Quaternary geology of the Channeled Scabland and adjacent areas

    Science.gov (United States)

    Baker, V. R.

    1978-01-01

    The quaternary history of the channeled scabland is characterized by discrete episodes of catastrophic flooding and prolonged periods of loess accumulation and soil formation. The loess sequence was correlated with Richmond's Rocky Mountain glacial chronology. At least five major catastrophic flood events occurred in the general vicinity of the channeled scabland. The earliest episode occurred prior to the extensive deposition of the Palouse formation. The last major episode of flooding occurred between about 18,000 and 13,000 years ago. It probably consisted of two outbursts from glacial Lake Missoula.

  1. A Quaternary Decision Diagram Machine: Optimization of Its Code

    Science.gov (United States)

    2010-08-01

    2026 IEICE TRANS. INF. & SYST., VOL.E93–D, NO.8 AUGUST 2010 INVITED PAPER Special Section on Multiple-Valued Logic and VLSI Computing A Quaternary...sequentially. A straightforward method to increase the speed is to increase the clock frequency. However, this is 2028 IEICE TRANS. INF. & SYST...reduce the 2030 IEICE TRANS. INF. & SYST., VOL.E93–D, NO.8 AUGUST 2010 Fig. 9 4-address QDD machine. Fig. 10 Branch instruction for 4-address QDD

  2. 40 CFR 721.10154 - Quaternary ammonium compounds, dicoco alkyldimethyl, chlorides, reaction products with silica.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 30 2010-07-01 2010-07-01 false Quaternary ammonium compounds, dicoco alkyldimethyl, chlorides, reaction products with silica. 721.10154 Section 721.10154 Protection of Environment... SUBSTANCES Significant New Uses for Specific Chemical Substances § 721.10154 Quaternary ammonium...

  3. European quaternary refugia: a factor in large carnivore extinction?

    Science.gov (United States)

    O'Regan, Hannah J.; Turner, Alan; Wilkinson, David M.

    2002-12-01

    The extinction of large carnivores in Europe during the Quaternary is reviewed and the potential role of glacial refugia in these extinctions is investigated using the VORTEX model for population viability analysis. A model was built for a medium sized big cat similar to the extinct Panthera gombaszoegensis utilising life history data from the modern jaguar Panthera onca. This approach highlighted the potential importance of glacial refugia in the extinction process. Even model refugia the size of the Italian peninsula did not guarantee persistence of a population over a 1000 yr time span, illustrating the role of chance in survival in such a refugium. An area the size of the largest Mediterranean island was unable to support a big cat population for a period of 1000 yr. The models also demonstrated the importance of inbreeding as a mechanism for extinction in refugia. It is suggested that repeated genetic bottlenecks during successive glaciations would tend to remove lethal recessive alleles from the population, increasing the probability of survival in refugia in subsequent glaciations. The history of extinction of large carnivores in the European Quaternary is interpreted in the light of these results.

  4. Quaternary evolution of the Southern Apennines coastal plains: a review

    Science.gov (United States)

    Santangelo, Nicoletta; Romano, Paola; Ascione, Alessandra; Russo Ermolli, Elda

    2017-02-01

    The Quaternary evolution of the main coastal basins located along the southwestern margin of the Southern Apennines has been reconstructed by integrating the huge amount of existing stratigraphical and geomorphological data. The information produced in the last twenty years has shed new light on the recent (late Middle Pleistocene to Present) history of the Campanian and Sele plains or basins. During the early Quaternary, the analysed coastal basins originated as half-grabens in response to opening processes active since the late Tortonian in the southern Tyrrhenian back-arc basin. In some of these basins (e.g. the Campanian Plain), volcanism has also played an important role. In the inner sectors of the coastal basins, the complex interplay between block faulting, sedimentary inputs and glacioeustatic fluctuations gave rise to relative sea-level change and related coastline migrations, leading to the formation of the present-day coastal plains. In the Sele Plain basin, the construction of the present-day landscape mainly resulted from the substantial ceasing of subsidence in the final part of the Middle Pleistocene. Conversely, a strong contribution to the recent evolution of the Campanian Plain has been provided by abundant volcaniclastic aggradation, able to hinder the effect of the vertical motions that occurred in the last 100 ka.

  5. Quaternary evolution of the Southern Apennines coastal plains: a review

    Directory of Open Access Journals (Sweden)

    Santangelo Nicoletta

    2017-02-01

    Full Text Available The Quaternary evolution of the main coastal basins located along the southwestern margin of the Southern Apennines has been reconstructed by integrating the huge amount of existing stratigraphical and geomorphological data. The information produced in the last twenty years has shed new light on the recent (late Middle Pleistocene to Present history of the Campanian and Sele plains or basins. During the early Quaternary, the analysed coastal basins originated as half-grabens in response to opening processes active since the late Tortonian in the southern Tyrrhenian back-arc basin. In some of these basins (e.g. the Campanian Plain, volcanism has also played an important role. In the inner sectors of the coastal basins, the complex interplay between block faulting, sedimentary inputs and glacioeustatic fluctuations gave rise to relative sea-level change and related coastline migrations, leading to the formation of the present-day coastal plains. In the Sele Plain basin, the construction of the present-day landscape mainly resulted from the substantial ceasing of subsidence in the final part of the Middle Pleistocene. Conversely, a strong contribution to the recent evolution of the Campanian Plain has been provided by abundant volcaniclastic aggradation, able to hinder the effect of the vertical motions that occurred in the last 100 ka.

  6. Mineralogical and geological study of quaternary deposits and weathering profiles

    Energy Technology Data Exchange (ETDEWEB)

    Jeong, Gi Young; Lee, Bong Ho [Andong National Univ., Andong (Korea, Republic of)

    2004-01-15

    Movement history of a quaternary reverse fault cutting marine terrace deposit and tertiary bentonite in the Yangnammyon, Gyoungju city was studied by the mineralogical and microtextural analysis of the fault clays and weathered terrace deposits. Two types of fault clays were identified as greenish gray before the deposition of the marine terrace deposits and reddish brown after deposition. Greenish gray fault clay is composed mostly of smectite probably powdered from bentonite showing at least two events of movement from microtextures. After the bentonite was covered by quaternary marine gravel deposits, the reverse fault was reactivated cutting marine gravel deposits to form open spaces along the fault plane which allowed the hydrological infiltration of soil particles and deposition of clays in deep subsurface. The reddish brown 'fault' clays enclosed the fragments of dark brown ultrafine varved clay, proving two events of faulting, and slicken sides bisecting reddish brown clays suggest another faulting event in the final stage. Mineralogical and microtextural analysis of the fault clay show total five events of faulting, which had not been recognized even by thorough conventional paleoseismological investigation using trench, highlighting the importance of microtextural and mineralogical analysis in paleoseismology.

  7. Quaternary climate - Terrestrial Biosphere Interaction: amplifying or stabilizing?

    Science.gov (United States)

    Claussen, Martin

    2016-04-01

    According to the Gaia hypothesis, interaction between climate and biological processes tend to homeostatically maintain, on a global scale, conditions favourable for life. Does the idea of homeostatic interaction between terrestrial biosphere and climate hold for the Quaternary glacial - interglacial changes? Interpretation of palaeoclimate and palaeobotanic evidence by using climate and Earth system models yields an interesting picture. The synergy between the sea-ice albedo - climate feedback and the taiga-tundra - climate feedback is suggested to amplify the orbitally forced climatic precession. This effect seems to be strong at regional scale, but small at global scale. Various simulations indicate that biogeophysical processes amplify the difference of some 4 to 6 K in global mean temperature between glacial and interglacial climate by some 10 percent. The combined effect of biogeophysical and biogeochemical processes, i.e. processes with involve carbon stored in biomass and soil, is less clear. Theoretical studies suggest that in pre-industrial, interglacial climate, a reduction in boreal and extratropical forests tend to cool the climate and a reduction in tropical forest, to warm the climate. Recent estimates in changes in organic carbon stored under ice sheets and in permafrost point at the possibility that the sum of all terrestrial biogeochemical processes might almost "carbon neutral" to the climate system. If corroborated, this observation would favour the assumption of a dominance of biogeophysical processes amplifying orbitally forced Quaternary climate variations.

  8. Geomorphology and Quaternary geology of the Dakhla Oasis Region, Egypt

    Science.gov (United States)

    Brookes, Ian A.

    Dakhla Oasis (25.5°N, 29°E) occupies a structurally localized depression at 90-140 m above sea level, ˜1200 km 2 in area, below a 300 m escarpment bordering the Libyan Plateau, Western Desert of Egypt. Semi-arid intervals of the Quaternary period generated eight sedimentary formations, separated by erosion during hyper-arid intervals. Sediments comprise three generations of colluvial/fluvial fanglomerates, two generations of tabular spring-laid clastic and chemical sediments, two generations of mound springs and basinal sediments. of fluvio-lacustrine, evaporitic, pluvio-aeolian and aeolian origins. Discussion of these sediments is organized according to geomorphic region, from north to south, plateau, scarp and piedmont, lowland and cuesta plain. Chronological evidence is restricted to many radiocarbon dates of Holocene cultural material associated with playa sediments (9-4.5 ka), a {Th}/{U} isochron age of ˜62.0 ±7.6 ka for basinal evaporites, and two {Th}/{U} ages of ˜176 and ˜170 ka for a boulder of derived travertine. The regional Quaternary sequence is reconstructed from stratigraphic and geomorphic relationships of the sediments and erosion surfaces. It is broadly similar to sequences earlier reconstructed in the topographically similar Kharga Oasis region 150 km to the east, and Kurkur Oasis, 400 km to the south-southeast. Speculations on chronology and driving mechanism are offered in conclusion.

  9. Quaternary history and contemporary patterns in a currently expanding species

    Science.gov (United States)

    Kerdelhué, Carole; Zane, Lorenzo; Simonato, Mauro; Salvato, Paola; Rousselet, Jérôme; Roques, Alain; Battisti, Andrea

    2009-01-01

    Background Quaternary climatic oscillations had dramatic effects on species evolution. In northern latitudes, populations had to survive the coldest periods in refugial areas and recurrently colonized northern regions during interglacials. Such a history usually results in a loss of genetic diversity. Populations that did not experience glaciations, in contrast, probably maintained most of their ancestral genetic diversity. These characteristics dramatically affected the present-day distribution of genetic diversity and may influence the ability of species to cope with the current global changes. We conducted a range-wide study of mitochondrial genetic diversity in the pine processionary moth (Thaumetopoea pityocampa/T. wilkinsoni complex, Notodontidae), a forest pest occurring around the Mediterranean Basin and in southern Europe. This species is responding to the current climate change by rapid natural range expansion and can also be accidentally transported by humans. Our aim was to assess if Quaternary climatic oscillations had a different effect across the species' range and to determine if genetic footprints of contemporary processes can be identified in areas of recent introduction. Results We identified three main clades that were spatially structured. In most of Europe, the genetic diversity pattern was typical for species that experienced marked glaciation cycles. Except in refugia, European populations were characterized by the occurrence of one main haplotype and by a strong reduction in genetic diversity, which is expected in regions that were rapidly re-colonized when climatic conditions improved. In contrast, all other sub-clades around the Mediterranean Basin occurred in limited parts of the range and were strongly structured in space, as is expected in regions in which the impact of glaciations was limited. In such places, genetic diversity was retained in most populations, and almost all haplotypes were endemic. This pattern was extreme on remote

  10. Quaternary history and contemporary patterns in a currently expanding species

    Directory of Open Access Journals (Sweden)

    Rousselet Jérôme

    2009-09-01

    Full Text Available Abstract Background Quaternary climatic oscillations had dramatic effects on species evolution. In northern latitudes, populations had to survive the coldest periods in refugial areas and recurrently colonized northern regions during interglacials. Such a history usually results in a loss of genetic diversity. Populations that did not experience glaciations, in contrast, probably maintained most of their ancestral genetic diversity. These characteristics dramatically affected the present-day distribution of genetic diversity and may influence the ability of species to cope with the current global changes. We conducted a range-wide study of mitochondrial genetic diversity in the pine processionary moth (Thaumetopoea pityocampa/T. wilkinsoni complex, Notodontidae, a forest pest occurring around the Mediterranean Basin and in southern Europe. This species is responding to the current climate change by rapid natural range expansion and can also be accidentally transported by humans. Our aim was to assess if Quaternary climatic oscillations had a different effect across the species' range and to determine if genetic footprints of contemporary processes can be identified in areas of recent introduction. Results We identified three main clades that were spatially structured. In most of Europe, the genetic diversity pattern was typical for species that experienced marked glaciation cycles. Except in refugia, European populations were characterized by the occurrence of one main haplotype and by a strong reduction in genetic diversity, which is expected in regions that were rapidly re-colonized when climatic conditions improved. In contrast, all other sub-clades around the Mediterranean Basin occurred in limited parts of the range and were strongly structured in space, as is expected in regions in which the impact of glaciations was limited. In such places, genetic diversity was retained in most populations, and almost all haplotypes were endemic. This

  11. Rapid dendrite growth in quaternary Ni-based alloys

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    The high undercooling and rapid solidification of Ni-10%Cu-10%Fe-10%Co quaternary alloy were achieved by electromagnetic levitation and glass fluxing techniques. The maximum undercooling of 276 K (0.16TL) was obtained in the experiments. All the solidified samples are determined to be α-Ni single-phase solid solutions by DSC thermal analysis and X-ray diffraction analysis. The microstructure of the α-Ni solid solution phase transfers from dendrite to equiaxed grain with an increase in undercooling, accompanied by the grain refinement effect. When the undercooling is very large, the solute trapping effect becomes quite significant and the microsegregation is suppressed. The experimental measurement of α-Ni dendrite growth velocity indicates that it increases with undercooling according to the relation, V=8×10-2×△T1.2.

  12. QUATERNARY DELSARTE-GOETHALS AND GOETHALS-DELSARTE CODES

    Institute of Scientific and Technical Information of China (English)

    CUI Jie; WAN Zhexian

    2002-01-01

    In this paper, the quaternary Delsarte-Goethals code DG(m,δ) and its dual code GD(m, δ) are discussed. The type and the trace representation are given for DG(m, δ),while the type and the minimum Lee weight are determined for GD(m, δ). The shortened codes of DG(m, δ) and GD(m, δ) are proved to be Z4-cyclic. The binary image of DG(m, δ)is proved to be the binary Delsarte-Goethals code DG(m+1, δ), and the essential difference between the binary image of GD(m, δ) and the binary Goethals-Delsarte code GD(m +1, δ)is exhibited. Finally, the decoding algorithms of DG(m, δ) and GD(m, δ) are discussed.

  13. QUATERNARY DELSARTE—GOETHALS AND GOETHALS—DELSARTE CODES

    Institute of Scientific and Technical Information of China (English)

    CUIJie; WANZhexian

    2002-01-01

    In this paper,the quaternary Delsarte-Goethals code DG(m,δ)and its dual code GD(m,δ)are discussed.The type and the trace representation are given for DG\\(m,δ),while the type and the minimum Lee weight are determined for GD(m,δ),The shortened codes of DG(m,δ)and GD(m,δ),are proved to be ZZ4-cyclic.The binary image of DG(m,δ) is proved to be the binary Delsarte-Goethals code DG((m+1,δ),and the essential difference between the binary image of GD(m,δ)and the binary Goethals-Delsarte code GD((m+1,δ)is exhibited.Finally,the decoding algorithms of DG(m,δ)and GD(m,δ)are discussed.

  14. Evolution of Quaternary groundwater system in North China Plain

    Institute of Scientific and Technical Information of China (English)

    张宗祜; 施德鸿; 任福弘; 殷正宙; 孙继朝; 张翠云

    1997-01-01

    The Quaternary groundwater system in the North China Plain is formed mainly through the terrestrial water flow action on the united geological and tectonic backgrounds. The analysis of groundwater dynamic field, simulation of groundwater geochemistry, and the 14C dating and extraction of isotope information have provided more evidence for recognizing and assessing the evolution of groundwater circulation system and studying the past global changes. The exploitation and utilization of groundwater on a large scale and overexploitation have given rise to the decline of regional groundwater level, change of flow field, decrease of water resources and downward movement of saline water body. The water environment has entered a new evolution stage in which it is intensely disturbed by the mankind’s activities.

  15. Expansion and contraction of Chinese deserts during the Quaternary

    Institute of Scientific and Technical Information of China (English)

    刘东生; 孙继敏

    2002-01-01

    Episodic dune formations during the Quaternary are found in many deserts of China.The causes of desert expansions on different time scales are not the same. Desert extension atabout 1.1 and 0.9 Ma ago were the response to the active tectonic movements, whereas the de-sert evolutions on the ten-thousand years time scale were the response to the orbital scale climaticchanges. Spatial scale studies on desert evolution indicate that desert margins shifted greatly dur-ing the last glacial maximum (LGM) and the Holocene optimum, its changing from 125°E of theLGM to 105°E of the climatic optimum. Historical desertification in the semiarid China is not a re-sponse to climate drought but largely associated with the human impacts (mainly over-cultivation)since about 2300 years ago, which leads to the reworking of the underlying LGM sands.

  16. Antibacterial effect of composite resins containing quaternary ammonium polyethyleneimine nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Yudovin-Farber, Ira [Hebrew University of Jerusalem, Department of Medicinal Chemistry and Natural Products, School of Pharmacy, Faculty of Medicine (Israel); Beyth, Nurit; Weiss, Ervin I. [Hebrew University of Jerusalem, Department of Prosthodontics, Faculty of Dentistry (Israel); Domb, Abraham J., E-mail: avid@ekmd.huji.ac.i [Hebrew University of Jerusalem, Department of Medicinal Chemistry and Natural Products, School of Pharmacy, Faculty of Medicine (Israel)

    2010-02-15

    Quaternary ammonium polyethyleneimine (QA-PEI)-based nanoparticles were synthesized by crosslinking with dibromopentane followed by N-alkylation with various alkyl halides and further N-methylation with methyl iodide. Insoluble pyridinium-type particles were prepared by suspension polymerization of 4-vinyl pyridine followed by N-alkylation with alkyl halides. Polyamine-based nanoparticles embedded in restorative composite resin at 1% w/w were tested for antibacterial activity against Streptococcus mutans using direct contact test. Activity analysis revealed that the alkyl chain length of the QA-PEI nanoparticles plays a significant role in antibacterial activity of the reagent. The most potent compound was octyl-alkylated QA-PEI embedded in restorative composite resin at 1% w/w that totally inhibited S. mutans growth in 3-month-aged samples. This data indicates that restorative composite resin with antibacterial properties can be produced by the incorporation of QA-PEI nanoparticles.

  17. Control of Quaternary sea-level changes on gas seeps

    Science.gov (United States)

    Riboulot, Vincent; Thomas, Yannick; Berné, Serge; Jouet, Gwénaël.; Cattaneo, Antonio

    2014-07-01

    Gas seeping to the seafloor through structures such as pockmarks may contribute significantly to the enrichment of atmospheric greenhouse gases and global warming. Gas seeps in the Gulf of Lions, Western Mediterranean, are cyclical, and pockmark "life" is governed both by sediment accumulation on the continental margin and Quaternary climate changes. Three-dimensional seismic data, correlated to multi-proxy analysis of a deep borehole, have shown that these pockmarks are associated with oblique chimneys. The prograding chimney geometry demonstrates the syn-sedimentary and long-lasting functioning of the gas seeps. Gas chimneys have reworked chronologically constrained stratigraphic units and have functioned episodically, with maximum activity around sea level lowstands. Therefore, we argue that one of the main driving mechanisms responsible for their formation is the variation in hydrostatic pressure driven by relative sea level changes.

  18. Quaternary Prevention, an Answer of Family Doctors to Overmedicalization

    Directory of Open Access Journals (Sweden)

    Marc Jamoulle

    2015-02-01

    Full Text Available In response to the questioning of Health Policy and Management (HPAM by colleagues on the role of rank and file family physicians in the same journal, the author, a family physician in Belgium, is trying to highlight the complexity and depth of the work of his colleagues and their contribution to the understanding of the organization and economy of healthcare. It addresses, in particular, the management of health elements throughout the ongoing relationship of the family doctor with his/her patients. It shows how the three dimensions of prevention, clearly included in the daily work, are complemented with the fourth dimension, quaternary prevention or prevention of medicine itself, whose understanding could help to control the economic and human costs of healthcare.

  19. A Quaternary ZnCdSeTe Nanotip Photodetector

    Directory of Open Access Journals (Sweden)

    Cheng YC

    2009-01-01

    Full Text Available Abstract The authors report the growth of needle-like high density quaternary Zn0.87Cd0.13Se0.98Te0.02nanotips on oxidized Si(100 substrate. It was found that average length and average diameter of the nanotips were 1.3 μm and 91 nm, respectively. It was also found that the as-grown ZnCdSeTe nanotips exhibit mixture of cubic zinc-blende and hexagonal wurtzite structures. Furthermore, it was found that the operation speeds of the fabricated ZnCdSeTe nanotip photodetector were fast with turn-on and turn-off time constants both less than 2 s.

  20. The geological characteristics during the quaternary period around Japan island

    Energy Technology Data Exchange (ETDEWEB)

    Hagiwara, Shigeru [Chuo Kaihatsu Corp., Enterprises Promotion Bureau, Tokyo (Japan); Sakamoto, Yoshiaki; Ogawa, Hiromichi; Nakayama, Shinichi [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment

    2002-11-01

    Radioactive wastes arising from radioisotope facilities and nuclear research facilities should be disposed of in the surface of the earth, the shallow underground, the adequate depth and the deep underground according to radioactivity concentrations, and should be managed during several hundreds years. The earth scientific phenomena observed in Japan island at present occurred continuously from the past, and the same phenomena at the future should occur in the similar factor. Therefore, for the purpose to get the fundamental data for the selection of disposal site, this report reviewed on the genesis and classification of the sediments, earth scientific phenomena observed in Japan island and the feature of each place (10 districts) concerning to the Quaternary period in the newest geological time unit. (author)

  1. Antibacterial effect of composite resins containing quaternary ammonium polyethyleneimine nanoparticles

    Science.gov (United States)

    Yudovin-Farber, Ira; Beyth, Nurit; Weiss, Ervin I.; Domb, Abraham J.

    2010-02-01

    Quaternary ammonium polyethyleneimine (QA-PEI)-based nanoparticles were synthesized by crosslinking with dibromopentane followed by N-alkylation with various alkyl halides and further N-methylation with methyl iodide. Insoluble pyridinium-type particles were prepared by suspension polymerization of 4-vinyl pyridine followed by N-alkylation with alkyl halides. Polyamine-based nanoparticles embedded in restorative composite resin at 1% w/w were tested for antibacterial activity against Streptococcus mutans using direct contact test. Activity analysis revealed that the alkyl chain length of the QA-PEI nanoparticles plays a significant role in antibacterial activity of the reagent. The most potent compound was octyl-alkylated QA-PEI embedded in restorative composite resin at 1% w/w that totally inhibited S. mutans growth in 3-month-aged samples. This data indicates that restorative composite resin with antibacterial properties can be produced by the incorporation of QA-PEI nanoparticles.

  2. Book Review: The history of the Quaternary Research Association

    Science.gov (United States)

    Bowen, D. Q.

    2016-06-01

    This is a book that should be in the library of every member of the QRA as well as their institutions. This volume is a celebration of 50 years of the Quaternary Studies Field Group (1964), which was renamed the Quaternary Research Association (QRA) in 1969. What follows is a combination of a review with some further information based on the recollection of someone who was there. In examining the origins of the QSFG due credit is paid to Richard Hey and Richard West, but an inexplicable omission is the earlier discussion between Hey, Allan Straw and others during the field meeting of the Yorkshire Geological Society in September 1962 (Worsley, 2014). It is said that history is always written by the victors, or in modern parlance by those who write the minutes! But, in the writing of history there are only degrees of unsuccess. In Chapter 2 John Catt comments on the less than perfect early archival records of the QRA. So it is to his credit that 50 years of archival material has been diligently sifted and edited. In this he was assisted by memories of some named QRA members who are thanked. Wider consultation may have filled some of the gaps. At earlier meetings it was always a pleasure to greet long retired colleagues, such as Archie Lamont at the Carlops glacial drainage system when being demonstrated by Brian Sissons in 1966, or Tony Farringdon at Ballycotton Bay in 1968, or Hallam Movius in 1971 at a London discussion meeting. Similarly, who can forget the field meeting at Canterbury in 1967 when Alec Skempton demonstrated the Sevenoaks by-pass late-glacial slope failures, and John Hutchinson's use of Pomatias elegans for dating the Folkestone Warren landslips? Jan Mangerud's first QRA meeting on the Isle of Man (1971) was notable for his prescient recognition of glaciomarine deposits.

  3. Occurrence of volcanic ash in the Quaternary alluvial deposits, lower Narmada basin, western India

    Indian Academy of Sciences (India)

    Rachna Raj

    2008-02-01

    This communication reports the occurrence of an ash layer intercalated within the late Quaternary alluvial succession of the Madhumati River, a tributary of the lower Narmada River. Petrographic, morphological and chemical details of glass shards and pumice fragments have formed the basis of this study. The ash has been correlated with the Youngest Toba Tuff. The finding of ash layer interbedded in Quaternary alluvial sequences of western Indian continental margin is significant, as ash being datable material, a near precise time-controlled stratigraphy can be interpreted for the Quaternary sediments of western India. The distant volcanic source of this ash requires a fresh re-assessment of ash volume and palaeoclimatic interpretations.

  4. Novel approach for prediction of ultrasonic velocity in quaternary liquid mixtures

    Indian Academy of Sciences (India)

    J D Pandey; A K Singh; Ranjan Dey

    2005-01-01

    A modified Flory theory along with the Auerbach and Altenberg relations has been employed for the computation of ultrasonic velocity of three quaternary liquid mixtures and a comparative study of all the three relations has then been carried out.

  5. Evaluation of chitosan quaternary ammonium salt-modified resin denture base material.

    Science.gov (United States)

    Song, Rong; Zhong, Zhaohua; Lin, Lexun

    2016-04-01

    Chitosan quaternary ammonium salt displays good antioxidant and antibacterial characteristics and it shows appreciable solubility in water. When added to the traditional denture material to form a resin base, it could promote good oral health by improving the oral environment. In this study, chitosan quaternary ammonium salt was added to the denture material following two different methods. After three months of immersion in artificial saliva, the specimens were tested for tensile strength and were scanned by electron microscope. The murine fibroblast cytotoxicity and antibacterial properties were also tested. The result showed no significant differences in the tensile strength and in the proliferation of murine L929 fibroblast cells. The two structures of chitosan quaternary ammonium salt-modified denture material had different degrees of corrosion resistance and antimicrobial properties. These results indicate that chitosan quaternary ammonium salt-modified resin denture base material has the potential to become a new generation oral denture composite material.

  6. Estimated Thickness of Quaternary Sediment in the Wood River Valley aquifer system, South-Central Idaho

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This dataset is the estimated thickness of Quaternary sediment of the Wood River Valley aquifer system. This isopach map was constructed by subtracting the estimated...

  7. Effects of quaternary ammonium silane coatings on mixed fungal and bacterial biofilms on tracheoesophageal shunt prostheses

    NARCIS (Netherlands)

    Oosterhof, JJH; Buijssen, KJDA; Busscher, HJ; van der Laan, BFAM; van der Mei, HC

    2006-01-01

    Two quaternary ammonium silanes (QAS) were used to coat silicone rubber tracheoesophageal shunt prostheses, yielding a positively charged surface. One QAS coating [(trimethoxysilyl)-propyidimethylocta-decylammonium chloride] was applied through chemical bonding, while the other coating, Biocidal ZF,

  8. Quaternary epitopes of α345(IV) collagen initiate Alport post-transplant anti-GBM nephritis

    DEFF Research Database (Denmark)

    Olaru, Florina; Luo, Wentian; Wang, Xu-Ping

    2013-01-01

    Alport post-transplant nephritis (APTN) is an aggressive form of anti-glomerular basement membrane disease that targets the allograft in transplanted patients with X-linked Alport syndrome. Alloantibodies develop against the NC1 domain of α5(IV) collagen, which occurs in normal kidneys, including...... of alloantibodies against allogeneic collagen IV. Some alloantibodies targeted alloepitopes within α5NC1 monomers, shared by α345NC1 and α1256NC1 hexamers. Other alloantibodies specifically targeted alloepitopes that depended on the quaternary structure of α345NC1 hexamers. In Col4a5-null mice, immunization...... with native forms of allogeneic collagen IV exclusively elicited antibodies to quaternary α345NC1 alloepitopes, whereas alloimmunogens lacking native quaternary structure elicited antibodies to shared α5NC1 alloepitopes. These results imply that quaternary epitopes within α345NC1 hexamers may initiate...

  9. Synthesis of Main-Chain Chiral Quaternary Ammonium Polymers for Asymmetric Catalysis Using Quaternization Polymerization

    Directory of Open Access Journals (Sweden)

    Md. Masud Parvez

    2012-06-01

    Full Text Available Main-chain chiral quaternary ammonium polymers were successfully synthesized by the quaternization polymerization of cinchonidine dimer with dihalides. The polymerization occurred smoothly under optimized conditions to give novel type of main-chain chiral quaternary ammonium polymers. The catalytic activity of the polymeric chiral organocatalysts was investigated on the asymmetric benzylation of N-(diphenylmethylideneglycine tert-butyl ester.

  10. Quaternary Organic Amines Inhibit Na,K Pump Current in a Voltage-dependent Manner

    OpenAIRE

    2004-01-01

    The effects of organic quaternary amines, tetraethylammonium (TEA) chloride and benzyltriethylammonium (BTEA) chloride, on Na,K pump current were examined in rat cardiac myocytes superfused in extracellular Na+-free solutions and whole-cell voltage-clamped with patch electrodes containing a high Na+-salt solution. Extracellular application of these quaternary amines competitively inhibited extracellular K+ (K+ o) activation of Na,K pump current; however, the concentration for half maximal inh...

  11. Progress report. Task 1 - quaternary tectonics, 1 October 1991--30 September 1992

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1992-09-30

    Progress is reported on a study concerned with the quaternary tectonics of Yucca Mountain, the proposed site for an underground disposal facility for high-level radioactive wastes. Refinement and revision of crater Flat Quaternary stratigraphy continued and consisted of several activities: revision of rock varnish cation leaching curve; sample comparison of RV manganese;,iron microlaminations;and correlation of Crater Flat allostratigraphic units with regional chronologies.

  12. Quaternary Alkylammonium Conjugates of Steroids: Synthesis, Molecular Structure, and Biological Studies.

    Science.gov (United States)

    Brycki, Bogumił; Koenig, Hanna; Pospieszny, Tomasz

    2015-11-23

    The methods of synthesis as well as physical, spectroscopic (¹H-NMR, 13C-NMR, and FT-IR, ESI-MS), and biological properties of quaternary and dimeric quaternary alkylammonium conjugates of steroids are presented. The results were contrasted with theoretical calculations (PM5 methods) and potential pharmacological properties (PASS). Alkylammonium sterols exhibit a broad spectrum of antimicrobial activity comparable to squalamine.

  13. Sustainable groundwater development and management in the Quaternary Hang-Jia-Hu Plain, China

    Institute of Scientific and Technical Information of China (English)

    朱琰

    2002-01-01

    Based on the results of study on regional water supply system, water quality assessments, Quaternary aquifers investigation, and correlation analysis of groundwater depression resulting from land subsidence in the Hang-Jia-Hu Quaternary Plain, this paper presents the groundwater resources policy and sustainable management methods suitable for this area. Suggestions for controlling land subsidence by implementation of wise groundwater policy and management measures are also given.

  14. From Morphostratigraphy to Chronostratigraphy – Modern Quaternary Geomorphology as a Basic for Climatic Research

    OpenAIRE

    Böse, Margot

    2015-01-01

    In preparation for the Congress of the International Association of Geomorphologists (IAG) in Paris 2013, our French colleagues discussed session proposals with their colleagues from other countries. Hanna Bremer, the internationally renowned geomorphologist from Germany, was informally involved in the discussion – and she proposed a session with Quaternary aspects; I got involved as geomorphologist and president of the German Quaternary Association (DEUQUA) at that time. We were still develo...

  15. Quaternary Alkylammonium Conjugates of Steroids: Synthesis, Molecular Structure, and Biological Studies

    Directory of Open Access Journals (Sweden)

    Bogumił Brycki

    2015-11-01

    Full Text Available The methods of synthesis as well as physical, spectroscopic (1H-NMR, 13C-NMR, and FT-IR, ESI-MS, and biological properties of quaternary and dimeric quaternary alkylammonium conjugates of steroids are presented. The results were contrasted with theoretical calculations (PM5 methods and potential pharmacological properties (PASS. Alkylammonium sterols exhibit a broad spectrum of antimicrobial activity comparable to squalamine.

  16. The pragmatic roots of American Quaternary geology and geomorphology

    Science.gov (United States)

    Baker, Victor R.

    1996-07-01

    H.L. Fairchild's words from the 1904 Geological Society of America Bulletin remain appropriate today: "Geologists have been too generous in allowing other people to make their philosophy for them". Geologists have quietly followed a methodological trinity involving (1) inspiration by analogy, (2) impartial and critical assessment of hypotheses, and (3) skepticism of authority (prevailing theoretical constraints or paradigms). These methods are described in classical papers by Quaternary geologists and geomorphologists, mostly written a century ago. In recent years these papers have all been criticized in modern philosophical terms with little appreciation for the late 19th century American philosophical tradition from which they arose. Recent scholarly research, however, has revealed some important aspects of that tradition, giving it a coherence that has largely been underappreciated as 20th century philosophy of science pursued its successive fads of logical positivism, critical rationalism, relativism, and deconstructivism — for all of which "science" is synonymous with "physics". Nearly all this ideology is geologically irrelevant. As philosophy of science in the late 20th century has come to be identical with philosophy of analytical physics, focused on explanations via ideal truths, much of geology has remained true to its classical doctrines of commonsensism, fallibilism, and realism. In contrast to the conceptualism and the reductionism of the analytical sciences, geology has emphasized synthetic thinking: the continuous activity of comparing, connecting, and putting together thoughts and perceptions. The classical methodological studies of geological reasoning all concern the formulation and testing of hypotheses. Analysis does not serve to provide the ultimate answers for intellectual puzzles predefined by limiting assumptions imposed on the real world. Rather, analysis in geology allows the investigator to consider the consequential effects of

  17. Large-scale and patternable graphene: direct transformation of amorphous carbon film into graphene/graphite on insulators via Cu mediation engineering and its application to all-carbon based devices.

    Science.gov (United States)

    Chen, Yu-Ze; Medina, Henry; Lin, Hung-Chiao; Tsai, Hung-Wei; Su, Teng-Yu; Chueh, Yu-Lun

    2015-02-07

    Chemical vapour deposition of graphene was the preferred way to synthesize graphene for multiple applications. However, several problems related to transfer processes, such as wrinkles, cleanness and scratches, have limited its application at the industrial scale. Intense research was triggered into developing alternative synthesis methods to directly deposit graphene on insulators at low cost with high uniformity and large area. In this work, we demonstrate a new concept to directly achieve growth of graphene on non-metal substrates. By exposing an amorphous carbon (a-C) film in Cu gaseous molecules after annealing at 850 °C, the carbon (a-C) film surprisingly undergoes a noticeable transformation to crystalline graphene. Furthermore, the thickness of graphene could be controlled, depending on the thickness of the pre-deposited a-C film. The transformation mechanism was investigated and explained in detail. This approach enables development of a one-step process to fabricate electrical devices made of all carbon material, highlighting the uniqueness of the novel approach for developing graphene electronic devices. Interestingly, the carbon electrodes made directly on the graphene layer by our approach offer a good ohmic contact compared with the Schottky barriers usually observed on graphene devices using metals as electrodes.

  18. Quaternary continetal back-arc evolution from southern Mendoza, Argentina

    Science.gov (United States)

    Espanon, Venera; Chivas, Allan; Dosseto, Anthony; Honda, Masahiko; Phillips, David; Matchan, Erin; Price, David

    2016-04-01

    The Quaternary evolution of the Payenia Basaltic Province (PBP) in southern Mendoza, Argentina has been investigated using a multi-dating approach in combination with pre-exiting geochemical data. This basaltic province covers an area of approximately 40000 km2 and is mainly characterised by backarc volcanism. In the current investigation nine new radiometric ages obtained using surface exposure, 40Ar/39Ar and thermoluminescence dating are presented. Six ages correspond to the late Pleistocene and three to the Holocene. The surface exposure ages obtained using cosmogenic 3He and 21Ne are in good agreement with previous publications and confidently suggest that part of this basaltic province was active at least 4000 years ago (taking a conservative approach). In addition, we combined the available geochronological and geochemical data to reconstruct the Quaternary evolution of this basaltic province. This approach was used to create maps of geospatial distribution of trace-element ratios to determine geochemical changes during the Pleistocene. Employing this method it is evident that two geochemical distinct types of magma were erupting at the same time interval within the PBP. In the north eastern part (Nevado volcanic field) of the PBP an arc-like signature is evident, while in the southern part (Río Colorado volcanic field) of the same basaltic province an Ocean Island Basalt (OIB) signature is evident. The arc-like signature in the north eastern part of the PBP, decreased during the Pleistocene in a north-west direction indicated by a reduction in Ba/La and La/Ta in the Nevado and Llancanelo volcanic field. The Holocene volcanism is restricted to the western side of the Payún Matrú volcanic field and is dominated by OIB-like signatures such as high Ta/Hf and low Ba/La and La/Ta. This contribution presents new geochronology for the PBP and confirms that two different types of volcanism occurred simultaneously during the Pleistocene, while the Holocene

  19. A model of the Quaternary geological deposits of Bucharest City

    Science.gov (United States)

    Serpescu, Irina; Radu, Emil; Radu Gogu, Constantin; Amine Boukhemacha, Mohamed; Gaitanaru, Dragos; Bica, Ioan

    2013-04-01

    Bucharest city is located in the central part of the Moesic Platform, in the Romanian Plain with micro-relief resulting from erosion and sedimentary processes which extended along the valleys of the Dambovita River to the south and the Colentina River to the north. The city is located in the axial area of a syncline where the thickness of the sedimentary deposits is up to 1000 m. The area lies on a rigid base is made of metamorphites, and various igneous intrusions (granodiorite, granite). The sedimentary deposits covering this rigid base are made by different phases of erosion and sedimentary processes of marine, lacustrian or continental sediments ending with Quaternary sediments. As a result, different alluvial deposits (such as piedmont, deltaic, alluvial cones, terrace, waterside and lacustrine deposits) can be met. Furthermore one also can find loess deposits which in turn cover totally the older deposits where rivers dug the present relief. To highlight the spatial extent of these geological structures, a geological model of Bucharest city is developed. A set of information coming from different sources as geological and geotechnical boreholes showing a detailed geological and lithological description, geological and topographical maps, geological and hydrogeological reports have been used to develop the 3D geological model of this region. 33 geological cross sections were defined and interpreted by using lithological and sedimentological criteria. Using these geological cross sections and prior geological knowledge, the Quaternary deposits have been described and classified into 6 structural units given from top to down as follows: (1) Superficial deposits represented by loess and anthropogenic materials. The geological model indicates that these deposits show a sporadic development becoming more concentrated in the central west part of the city. (2) Colentina Formations composed by of poorly sorted, cross-stratified sand and gravel with clayey lens

  20. Quaternary Deformation of Sumba, Indonesia: Evidence from Carbonate Terraces

    Science.gov (United States)

    Dahlquist, M. P.; West, A. J.; Dolan, J. F.

    2014-12-01

    The Banda Arc of Indonesia remains one of the least understood tectonic domains on the modern Earth. The island of Sumba, located approximately 50 km south of Flores and 120 km north of the Java Trench, northwest of where it transitions into the Timor Trough, lies in a region of tectonic transition and potentially offers insights into regional dynamics. The Banda Arc is volcanically active, but Sumba itself is not volcanic. The northern coast of Sumba is covered in Quaternary coral terraces, with the rest of the island's surface geology composed of Mio-pliocene carbonates and uplifted Late Cretaceous-Oligocene forearc basin and volcanic rocks. The purpose of this study is to remotely map the topographic expression of the coral terraces and use the information gained to better understand deformation on Sumba since their deposition. The ages of the coral terraces, of which many platforms are exposed over significant areas of the island, have been constrained at Cape Luandi in north central Sumba, but uplift rates calculated from those ages may not be representative of the island as a whole. The lateral continuity of these dated terraces can help constrain the extent to which uplift of Sumba is spatially variable. Analysis of the terraces using SRTM digital elevation data with ArcGIS software makes it possible to trace the same terrace platforms over large distances, and shows that the north central part of the island has experienced the most uplift since the deposition of the terraces, forming an anticline with the east limb dipping more steeply than the west. The terraces are not well preserved on the southern half of the island. Exposure of older rocks and lack of terrace preservation, as well as a south-skewed drainage divide suggests the southern half of the island experiences greater exhumation, but this could be driven by climate or other factors and does not necessarily indicate more rapid uplift. Study of Quaternary deformation of Sumba can offer greater

  1. Late Quaternary environments, vegetation and agriculture in northern New Zealand

    Science.gov (United States)

    Horrocks, M.; Nichol, S. L.; Augustinus, P. C.; Barber, I. G.

    2007-03-01

    A sedimentological and plant microfossil history of the Late Quaternary is preserved in two sediment cores from early Polynesian ditch systems on southern Aupouri Peninsula. The study places human activities into a geomorphological and ecological context and allows comparison of natural and anthropogenic effects on two different geological settings: a floodplain and a relatively closed peat swamp. The data fill part of the current gap in the environmental record from northern New Zealand, namely MIS 3 (57k-26k yr BP). There is evidence for an increase in fire frequency in the region after 40k 14C yr BP, suggesting a shift to drier (and cooler) conditions. Pollen records show that conifer-hardwood forest dominated by podocarps (especially Dacrydium) prevailed prior to Polynesian arrival and deforestation within the last millennium, with Fuscopsora insignificant throughout. Both cores show sections with gaps in deposition or preservation, possible flood-stripping of peat during the pre-Holocene and mechanical disturbance by early Polynesians. The identification of prehistoric starch grains and other microremains of introduced Colocasia esculenta (taro) in both cores supports indirect evidence that the ditch systems of far northern New Zealand were used for the extensive cultivation of this crop. Copyright

  2. Summary of Quaternary geology of the Municipality of Anchorage, Alaska

    Science.gov (United States)

    Schmoll, H.R.; Yehle, L.A.; Updike, R.G.

    1999-01-01

    Quaternary geology of the Upper Cook Inlet region is dominated by deposits of glacier retreats that followed repeated advances from both adjacent and more distant mountains. At several levels high on the mountains, there are remnant glacial deposits and other features of middle or older Pleistocene age. Late Pleistocene lateral moraines along the Chugach Mountain front represent successively younger positions of ice retreat from the last glacial maximum. As the trunk glacier retreated northeastward up the Anchorage lowland, Cook Inlet transgressed the area, depositing the Bootlegger Cove Formation and Tudor Road deposits. The glacier then readvanced to form the latest Pleistocene Elmendorf Moraine, a prominent feature that trends across the Anchorage lowland. Extensive alluvium was deposited both concurrently and somewhat later as Cook Inlet regressed. Mountain valleys contain (1) locally preserved moraines possibly of early Holocene age; (2) poorly preserved moraine remnants of older late Holocene age; and (3) well-preserved moraines formed mainly during the Little Ice Age. Glaciers still occupy large parts of the mountains, the upper ends of some mountain valleys, and small cirques. Holocene landslide deposits, including those formed during the great Alaska earthquake of 1964, occur throughout the area, especially along bluffs containing the Bootlegger Cove Formation.

  3. Interaction of ochratoxin A with quaternary ammonium beta-cyclodextrin.

    Science.gov (United States)

    Poór, Miklós; Kunsági-Máté, Sándor; Szente, Lajos; Matisz, Gergely; Secenji, Györgyi; Czibulya, Zsuzsanna; Kőszegi, Tamás

    2015-04-01

    Ochratoxin A (OTA) is a widely spread nephrotoxic food contaminant mycotoxin. Unfortunately, attenuation or prevention of the toxic effects of OTA is still an unresolved problem. Molecular inclusion of OTA by cyclodextrins (CDs) results in complexes with low stability. In the human organism, OTA exists mostly in the dianionic state (OTA(2-)). Therefore, our major goal was to develop a chemically modified cyclodextrin which gives a more stable complex with OTA than the previously published derivatives and which shows stronger preference towards OTA(2-). In our fluorescence spectroscopic study we demonstrate that quaternary ammonium beta-cyclodextrin (QABCD) fulfils both of these requirements. The calculated stability constant of the QABCD-OTA(2-) complex was 28,840 M(-1) (about 200-fold higher than that of the β-CD-OTA(2-) complex). We hypothesize, that QABCD may be a suitable tool for the decontamination of different OTA-contaminated drinks; furthermore, for alleviation of the toxic effects of OTA, such complex formation may reduce its absorption from the intestine.

  4. Responses of Quaternary rainforest vertebrates to climate change in Australia

    Science.gov (United States)

    Hocknull, Scott A.; Zhao, Jian-xin; Feng, Yue-xing; Webb, Gregory E.

    2007-12-01

    A new middle Pleistocene vertebrate fossil record from eastern Australia, dated by U disequilibrium series, records the first Quaternary record of an Australian tropical rainforest fauna. This exceptionally rich fauna underwent extinction after a long period of relative faunal stability, spanning several glacial cycles, and persisted probably until 280 000 years ago. Some time between 280 000 and 205 000 years ago the rainforest fauna was replaced by a xeric-adapted fauna. Since that time, the xeric-adapted fauna was replaced by a mesic-adapted fauna which was established by the Holocene. This is the first vertebrate faunal evidence in Australia of the middle Pleistocene Mid-Brunhes Climatic Event (MBE), a major climatic reorganisation that led to increased aridity in northern Australia from around 300 000 years ago. Several independent palaeoclimate proxies suggest that the climatic shift to aridity was due to increased climatic variability and weakened northern monsoons, which may be manifested in the extinction of the aseasonal rainforest fauna and its replacement by an arid-adapted fauna. We extend the temporal ranges of several taxa from the Pliocene into the middle Pleistocene. We also reveal a longer palaeobiogeographic connection of rainforest taxa and lineages shared between New Guinea and Australia than was previously thought and show that their extinction on mainland Australia occurred sometime after 280 000 years ago.

  5. Late Quaternary carbonate accumulation along eastern South Atlantic Ocean

    Science.gov (United States)

    Crabill, K.; Slowey, N. C.; Foreman, A. D.; Charles, C. D.

    2015-12-01

    Water masses originating from both the North Atlantic Ocean and the Southern Ocean intersect the Walvis Ridge and Namibian margin of southwest Africa. Changes in the distribution and properties of these water masses through time are reflected by variations in the nature of the sediments accumulating along this margin. As part of our ongoing studies, we are investigating the interrelationships between oceanographic/climatic change and the accumulation of carbonate minerals during the late Quaternary. A suite of cores that possess sediment records corresponding to the most recent glacial-interglacial cycles was collected from the water depth range of 500 to 3000 meters. Cores that preserve records of key water masses were selected for detailed analyses. Sediment bulk density, the concentration of calcium carbonate, and the relative proportions of carbonate minerals were precisely determined at regular depth intervals in these cores. Foraminiferal d18O and C-14 dates provide chronologic control. Results will be used to calculate how the accumulation rates of carbonate minerals on the seafloor vary through time, and the correspondence of such variation to changes in ocean circulation and climate will be assessed.

  6. Late Quaternary deformation, Saddle Mountains anticline, south-central Washington

    Science.gov (United States)

    West, M. W.; Ashland, F. X.; Busacca, A. J.; Berger, G. W.; Shaffer, M. E.

    1996-12-01

    Grabens and beheaded streams above a subjacent thrust fault illuminate late Quaternary deformation on the north limb of the Saddle Mountains anticline, Yakima fold belt, Washington. Geologic mapping and trenches excavated across a scarp on the north flank of a 13-km-long graben and a ± 5-m-high scarp north of the graben, confirm that deformation is related to coseismic slip on the underlying Saddle Mountains fault. Graben development began ca. 100 ka and continued into the Holocene. At least 6.5 m of vertical displacement in a ca. 20 40 ka paleosol yields minimum normal fault slip rates of 0.16 0.33 mm/yr. Assuming that normal slip in the hanging wall above the daylighting fault tip is related to primary reverse slip on the fault, resolution of throw on the 30°-dipping Saddle Mountains fault yields minimum slip of 13 m and minimum slip rates of 0.33 0.65 mm/yr, 2.3 9.4 times greater than slip rates used in a recent seismic hazard analysis for the Hanford Reservation.

  7. Antibacterial Activity of Dental Cements Containing Quaternary Ammonium Polyethylenimine Nanoparticles

    Directory of Open Access Journals (Sweden)

    Nurit Beyth

    2012-01-01

    Full Text Available Glass ionomer cements (GICs are commonly used for cementing full cast crown restorations. Regrettably, although the dental cements fill the gap between the tooth and the crown, bacterial microleakage may occur, resulting in secondary caries. As microleakage cannot be completely prevented, GICs possessing antibacterial properties are in demand. In the present study the antibacterial activity of insoluble, cross-linked quaternary ammonium polyethylenimine (QPEI nanoparticles incorporated at 1% w/w in two clinically available GICs were studied. The antibacterial activity was tested against Streptococcus mutans and Lactobacillus casei using the direct contact test (DCT and the agar diffusion test (ADT. Using the direct contact test, antibacterial activity (<0.05 was found in both tested GICs with incorporated QPEI nanoparticles, the effect lasting for at least one month. However, the ADT showed no inhibition halo in the test bacteria, indicating that the antimicrobial nanoparticles do not diffuse into the agar. The results show that the incorporation of QPEI nanoparticles in glass ionomer cements has a long-lasting antibacterial effect against Streptococcus mutans and Lactobacillus casei. Changing the antibacterial properties of glass ionomer cements by incorporating QPEI antibacterial nanoparticles may prolong the clinical performance of dental crowns.

  8. Enhanced adsorption of quaternary amine using modified activated carbon.

    Science.gov (United States)

    Prahas, Devarly; Wang, M J; Ismadji, Suryadi; Liu, J C

    2014-01-01

    This study examined different methodologies to modify activated carbon (AC) for the removal of quaternary amine, tetramethylammonium hydroxide (TMAH), from water. Commercial carbon (WAC) was treated by nitric acid oxidation (NA-WAC), silica impregnation (SM-WAC0.5), and oxygen plasma (P10-WAC), and their characteristics and adsorption capacity were compared. The Langmuir model fitted the equilibrium adsorption data well under different pH. The maximum adsorption capacity of WAC was 27.77 mg/g, while those of NA-WAC, SM-WAC 0.5, and P10-WAC were 37.46, 32.83 and 29.03 mg/g, respectively. Nitric acid oxidation was the most effective method for enhancing the adsorption capacity of TMAH. Higher pH was favorable for TMAH adsorption. Desorption study revealed that NA-WAC had no considerable reduction in performance even after five cycles of regeneration by 0.1 N hydrochloric acid. It was proposed that electrostatic interaction was the main mechanism of TMAH adsorption on activated carbon.

  9. Ligand exchange in quaternary alloyed nanocrystals--a spectroscopic study.

    Science.gov (United States)

    Gabka, Grzegorz; Bujak, Piotr; Giedyk, Kamila; Kotwica, Kamil; Ostrowski, Andrzej; Malinowska, Karolina; Lisowski, Wojciech; Sobczak, Janusz W; Pron, Adam

    2014-11-14

    Exchange of initial, predominantly stearate ligands for pyridine in the first step and butylamine (BA) or 11-mercaptoundecanoic acid (MUA) in the second one was studied for alloyed quaternary Cu-In-Zn-S nanocrystals. The NMR results enabled us to demonstrate, for the first time, direct binding of the pyridine labile ligand to the nanocrystal surface as evidenced by paramagnetic shifts of the three signals attributed to its protons to 7.58, 7.95 and 8.75 ppm. XPS investigations indicated, in turn, a significant change in the composition of the nanocrystal surface upon the exchange of initial ligands for pyridine, which being enriched in indium in the 'as prepared' form became enriched in zinc after pyridine binding. This finding indicated that the first step of ligand exchange had to involve the removal of the surface layer enriched in indium with simultaneous exposure of a new, zinc-enriched layer. In the second ligand exchange step (replacement of pyridine with BA or MUA) the changes in the nanocrystal surface compositions were much less significant. The presence of zinc in the nanocrystal surface layer turned out necessary for effective binding of pyridine as shown by a comparative study of ligand exchange in Cu-In-Zn-S, Ag-In-Zn-S and CuInS2, carried out by complementary XPS and NMR investigations.

  10. Possible Late Quaternary faulting in the Benton Hills, southeastern Missouri

    Energy Technology Data Exchange (ETDEWEB)

    Palmer, J.R.; Hoffman, D. (Missouri Geological Survey Program, Rolla, MO (United States). Dept. of Natural Resources)

    1993-03-01

    Geologic mapping in the 1930's by Dan Stewart and Lyle McManamy identified numerous faults in the Thebes Gap area of the Benton Hills, including two post-late Quaternary faults (max. of 10 m displacement) along the southeastern escarpment. Recent geologic mapping (Richard Harrison, pers. comm.) suggests dextral strike-slip displacement on most of these faults; some deformation post-dates the Pliocene-Pleistocene Mounds gravel. Small historical earthquake epicenters have been recorded in the Benton Hills area. Review of these data and analysis of the geologic and structural relationships to small- and large-scale drainage and alluvial features suggest tectonic control of the southeastern escarpment of the Benton Hills. The authors propose the coincidence of geologic structures and landforms resembles tectonically active alluvial basin margins, with the Benton Hills southeastern margin representing a fault block uplift escarpment. Future seismic reflection, drilling and trenching studies are planned to determine if the escarpment is fault controlled and of recent origin.

  11. Catalytic enantioselective synthesis of indanes by a cation-directed 5-endo-trig cyclization

    Science.gov (United States)

    Johnston, Craig P.; Kothari, Abhishek; Sergeieva, Tetiana; Okovytyy, Sergiy I.; Jackson, Kelvin E.; Paton, Robert S.; Smith, Martin D.

    2015-02-01

    5-Endo-trig cyclizations are generally considered to be kinetically unfavourable, as described by Baldwin's rules. Consequently, observation of this mode of reaction under kinetic control is rare. This is usually ascribed to challenges in achieving appropriate approach trajectories for orbital overlap in the transition state. Here, we describe a highly enantio- and diastereoselective route to complex indanes bearing all-carbon quaternary stereogenic centres via a 5-endo-trig cyclization catalysed by a chiral ammonium salt. Through computation, the preference for the formally disfavoured 5-endo-trig Michael reaction over the formally favoured 5-exo-trig Dieckmann reaction is shown to result from thermodynamic contributions to the innate selectivity of the nucleophilic group, which outweigh the importance of the approach trajectory as embodied by Baldwin's rules. Our experimental and theoretical findings demonstrate that geometric and stereoelectronic constraints may not be decisive in the observed outcome of irreversible ring-closing reactions.

  12. Equiatomic quaternary Heusler alloys: A material perspective for spintronic applications

    Science.gov (United States)

    Bainsla, Lakhan; Suresh, K. G.

    2016-09-01

    Half-metallic ferromagnetic (HMF) materials show high spin polarization and are therefore interesting to researchers due to their possible applications in spintronic devices. In these materials, while one spin sub band has a finite density of states at the Fermi level, the other sub band has a gap. Because of their high Curie temperature (TC) and tunable electronic structure, HMF Heusler alloys have a special importance among the HMF materials. Full Heusler alloys with the stoichiometric composition X2YZ (where X and Y are the transition metals and Z is a sp element) have the cubic L21 structure with four interpenetrating fcc sublattices. When each of these four fcc sublattices is occupied by different atoms (XX'YZ), a quaternary Heusler structure with different structural symmetries (space group F-43m, #216) is obtained. Recently, these equiatomic quaternary Heusler alloys (EQHAs) with 1:1:1:1 stoichiometry have attracted a lot of attention due to their superior magnetic and transport properties. A special class of HMF materials identified recently is known as spin gapless semiconductors (SGS). The difference in this case, compared with HMFs, is that the density of states for one spin band is just zero at the Fermi level, while the other has a gap as in the case of HMFs. Some of the reported SGS materials belong to EQHAs family. This review is dedicated to almost all reported materials belonging to EQHAs family. The electronic structure and hence the physical properties of Heusler alloys strongly depend on the degree of structural order and distribution of the atoms in the crystal lattice. A variety of experimental techniques has been used to probe the structural parameters and degree of order in these alloys. Their magnetic properties have been investigated using the conventional methods, while the spin polarization has been probed by point contact Andreev reflection technique. The experimentally obtained values of saturation magnetization are found to be in

  13. Mapping the late Quaternary evolution of the lower Mississippi Valley

    Science.gov (United States)

    Haugerud, R. A.; Simon, K. M.; James, T. S.

    2013-12-01

    The lower Mississippi Valley (LMV) extends from Cape Girardeau to Natchez and from Little Rock to Memphis. Extensive Quaternary terraces within the LMV have been considered to reflect downstream changes in base level (global sea level) and (or) upstream changes in water and sediment input because of glaciation. We suggest that the first-order control on terrace development was glacial-isostatic adjustment (GIA). Observed variation in heights of Quaternary alluvial surfaces at Memphis is 50 m (Rittenour et al., 2007). GIA modeling by Clark et al. (1994) predicted vertical displacement of as much as 130 m at Memphis over the last 18,000 years. ICE-5G models predict smaller displacement and reinforce the viability of GIA as the primary cause of LMV aggradation and incision. Existing analyses of LMV terraces are built on geomorphic maps by Saucier and colleagues (1974, 1994; Autin et al., 1991) that were interpreted from aerial photographs and inch-to-the-mile contour maps. Geomorphic mapping from high-resolution DEMs is more accurate, more rapid, and more reproducible than mapping from aerial photography and intermediate-resolution contours. Working from lidar DEMs (1-5 m XY resolution) and the 10 m National Elevation Dataset (NED) DEM largely derived from 1:24,000 scale contours, Haugerud is mapping the geomorphology of the LMV at ~1:500,000 scale. Goals are to explore the GIA-terrace hypothesis and improve the geomorphic and stratigraphic context for studies of New Madrid seismicity. Mapping leads to several observations: 1. The Holocene floodplain of the Mississippi River onlaps older surfaces. The river appears to be filling a hole created by collapse of the Laurentide forebulge. Continued filling of this accommodation space will, barring human intervention, enable the river to abandon its course through Thebes Gap in favor of a lower-elevation route through Oran Gap. 2. Within Holocene meander belts, younger levee crests are higher than older levee crests. The

  14. Europe's Neogene and Quaternary lake gastropod diversity - a statistical approach

    Science.gov (United States)

    Neubauer, Thomas A.; Georgopoulou, Elisavet; Harzhauser, Mathias; Mandic, Oleg; Kroh, Andreas

    2014-05-01

    During the Neogene Europe's geodynamic history gave rise to several long-lived lakes with conspicuous endemic radiations. However, such lacustrine systems are rare today as well as in the past compared to the enormous numbers of "normal" lakes. Most extant European lakes are mainly results of the Ice Ages and are due to their (geologically) temporary nature largely confined to the Pleistocene-Holocene. As glacial lakes are also geographically restricted to glacial regions (and their catchment areas) their preservation potential is fairly low. Also deposits of streams, springs, and groundwater, which today are inhabited by species-rich gastropod assemblages, are rarely preserved. Thus, the pre-Quaternary lacustrine record is biased towards long-lived systems, such as the Late Miocene Lake Pannon, the Early to Middle Miocene Dinaride Lake System, the Middle Miocene Lake Steinheim and several others. All these systems have been studied for more than 150 years concerning their mollusk inventories and the taxonomic literature is formidable. However, apart from few general overviews precise studies on the γ-diversities of the post-Oligocene European lake systems and the shifting biodiversity in European freshwater systems through space and time are entirely missing. Even for the modern faunas, literature on large-scale freshwater gastropod diversity in extant lakes is scarce and lacks a statistical approach. Our preliminary data suggest fundamental differences between modern and pre-Pleistocene freshwater biogeography in central Europe. A rather homogenous central European Pleistocene and Holocene lake fauna is contrasted by considerable provincialism during the early Middle Miocene. Aside from the ancient Dessaretes lakes of the Balkan Peninsula, Holocene lake faunas are dominated by planorbids and lymnaeids in species numbers. This composition differs considerably from many Miocene and Pliocene lake faunas, which comprise pyrgulid-, hydrobiid-, viviparid-, melanopsid

  15. Quaternary Tectonism in a Collision Zone, Northwest Washington

    Science.gov (United States)

    McCrory, P. A.; Wolf, S. C.; Intelmann, S. S.; Danforth, W. W.; Weldon, R. J.; Blair, J. L.

    2004-12-01

    Kinematic, geodetic, and geologic observations define a region with 6-8 mm/y of north-south contraction between the Columbia River and Vancouver Island. We attribute this contraction to differential forearc-block motion within the Cascadia subduction system where the Oregon Coast Range block is moving northward relative to Vancouver Island. The contraction is accommodated by a combination of distributed uplift in the Olympic Mountains, and faulting along the margins of the Coast Range and Vancouver Island blocks. The tide gauge at Neah Bay, which records one of the highest rates of uplift anywhere along the Cascadia subduction margin, suggests that a significant portion of this north-south contraction occurs between the northern Olympic Peninsula and Vancouver Island. The northwest-trending Calawah fault, extending from Makah Bay eastward to near Lake Crescent, appears to mark the modern boundary between the Olympic Mountains block and the Vancouver Island block in northwestern Washington. Onshore, the 80+ km-long Calawah fault displaces late Quaternary glacial sediments and geodetic uplift rates increase abruptly across the fault zone. Offshore in Makah Bay, new multibeam, sidescan-sonar, and high-resolution seismic reflection data image a complex, multi-strand fault zone that offsets the seafloor and moves Cape Flattery rocks seaward. Two parallel, northwest-trending fault strands bound a down-dropped block that in turn terminates along a northward-trending anticlinal fold and thrust fault. These data suggest that the Calawah fault zone currently accommodates contraction both by uplift and by seaward translation of rocks north of the forearc-block boundary. Our geologic mapping in the Cape Flattery area indicates that differential block motion is accommodated by a combination of crustal uplift, folding, and left-lateral, strike-slip faulting.

  16. Late Quaternary geology of the Lower Central Plain, Thailand

    Science.gov (United States)

    Sinsakul, Sin

    2000-08-01

    The Lower Central Plain or Chao Phraya Plain, located in the upper Gulf of Thailand, has an average elevation of 2 m above the present mean sea level. It is a fault bounded basin developed in the Plio-Pleistocene epoch. Consequently, the basin has been filled with Quaternary sediment reaching a thickness of almost 2000 m, of which only the upper 300 m is known. The Pleistocene deposits of the Lower Central Plain represent a complex interplay of alluvial, fluvial and deltaic environments of the Chao Phraya River and its tributaries. The upper sequence of sand and stiff clay with iron-oxide concretions on the surface was deposited in a fluviatile environment subjected to a regressive period in the late Pleistocene. The term "Chao Phraya delta" is used to define the landform where the Chao Phraya River interacted with marine processes as the sea level changed during the Holocene transgression. These strata indicated that the Holocene sea reached its maximum height of 4 m above the present mean sea level around 6000 years B.P.; from then on sea level fluctuated until it reached its present level around 1500 years B.P. This complex sea level history has caused the progradation of tidal flat, and tide-dominated delta deposits, consisting of soft marine clay, that covered the Lower Central Plain to an average depth of 15 m in the Bangkok area. The soft marine clay or Bangkok clay is the most important unit in the stratigraphic sequence in terms of land subsidence in the Lower Central Plain. Evidence of coastal erosion is also considerable in the low tidal flat area on the west bank of the Chao Phraya River mouth and adjacent coast.

  17. Quaternary deformation around the Palo Negro area, Pampa Norte, Argentina

    Science.gov (United States)

    Brunetto, E.; Iriondo, M.; Zamboni, L.; Gottardi, G.

    2010-04-01

    The Pampa Norte region is a great plain characterized by low slopes and accumulation of hundreds of meters of thick loose sediments. A high morphostructure denominated San Guillermo block stands out in the central plain, the Tostado-Selva scarp forming its western boundary. It is located in an intraplate setting characterized by low tectonic activity. However recent uplift can be inferred by means of terrain analysis and the sedimentology of the Palo Negro Fm. Pond deposits (Palo Negro Fm.) observed in the scarp suggest topographic inversion during the Late Quaternary in the Palo Negro area. The morphology indicates that the deformation was widely distributed, forming a gentle (ca. 5 m amplitude and 13 km wavelength) asymmetric fold. Low sinuosity lineaments located in the base of the scarp, coincident with knick points in the topographic profile, can be interpreted as the projection of tip-lines by high-angle fault-propagation. This geometry is compatible with reverse kinematics on blind faults. A deformation style with reactivation of pre-existing faults is consistent with structural observations. Seismic reflectors suggest the presence of Cretaceous high-angle normal faults, and the orientation of lineaments is similar to the orientation of the graben systems and transverse accommodation zones originated during the opening of the South Atlantic Ocean. One OSL dating of 67.4 ± 5.1 kyr B.P (from Palo Negro Fm. supposed as deposited on a flat plain floor) and a height difference of 9.5 m measured in the Tostado-Selva scarp account for an averaged uplift rate of 0.14 mm/year.

  18. An Atlas of Submarine Glacial Landforms: Modern, Quaternary and Ancient

    Science.gov (United States)

    Jakobsson, M.; Dowdeswell, J. A.; Canals, M.; Todd, B. J.; Dowdeswell, E. K.; Hogan, K. A.

    2014-12-01

    In the past two decades there have been several advances that make the production of an atlas of submarine glacial landforms timely. First is the development of high-resolution imaging technologies; multi-beam echo-sounding or swath bathymetry that allows the detailed mapping of the sea floor at water depths of tens to thousands of metres across continental margins, and 3-D seismic methods that enable the visualisation of palaeo-continental shelves in Quaternary sediments and ancient palaeo-glacial rocks (e.g. Late Ordovician of Northern Africa). A second technological development is that of ice-breaking or ice-strengthened ships that can penetrate deep into the ice-infested waters of the Arctic and Antarctic, to deploy the multibeam systems. A third component is that of relevance - through both the recognition that the polar regions, and especially the Arctic, are particularly sensitive parts of the global environmental system and that these high-latitude margins (both modern and ancient) are likely to contain significant hydrocarbon resources. An enhanced understanding of the sediments and landforms of these fjord-shelf-slope systems is, therefore, of increasing importance to both academics and industry. We are editing an Atlas of Submarine Glacial Landforms that presents a series of individual contributions that describe, discuss and illustrate features on the high-latitude, glacier-influenced sea floor. Contributions are organised in two ways: first, by position on a continental margin - from fjords, through continental shelves to the continental slope and rise; secondly, by scale - as individual landforms and assemblages of landforms. A final section provides discussion of integrated fjord-shelf-slope systems. Over 100 contributions by scientists from many countries contain descriptions and interpretation of swath-bathymetric data from both Arctic and Antarctic margins and use 3D seismic data to investigate ancient glacial landforms. The Atlas will be

  19. Late Quaternary sackungen in the highest mountains of the Carpathians

    Science.gov (United States)

    Pánek, Tomáš; Mentlík, Pavel; Engel, Zbyněk; Braucher, Règis; Zondervan, Albert

    2017-03-01

    Sackungen represents a common mode of deep-seated rock-slope failures in alpine landscapes, but proof of their temporal and causal relationship to extrinsic factors such as climatic changes, glacier retreat or seismic activity remains elusive. Based on the terrestrial cosmogenic nuclide (TCN) dating of 18 sackung scarps supported by one radiocarbon-dated scarp, we reconstructed the post-glacial chronology of sackungen in the Tatra Mts. (central Europe, Slovakia and Poland), the highest part of the Carpathians. The obtained ages (∼15.7-4.3 ka) indicate that sackungen post-date the regional LGM and some of them originated soon after the glacier withdrawal from adjacent valleys. Furthermore, systematic decrease of scarp ages with their increasing altitude suggests a direct link between sackung origin and post-LGM glacier thinning. However, substantial lag (>5 ka) of some sackungen in respect to glacier retreat implies complex relationships between sackung onset and deglaciation where retreat of glaciers acted predominantly as a preparatory, not a triggering factor during the genesis of these slope deformations. They originated either as a consequence of stress relaxation within the rock mass lasting several ka or alternatively could be triggered by climatic processes or seismicity. Indeed, a significant part of sackung activity took place during predominantly warmer and more humid periods, with some dates coinciding with the Bølling-Allerød chronozone, but especially with the onset of the Holocene and the Holocene Climatic Optimum. Earthquake triggering is less probable, as the Tatra Mts. lack significant modern and historic seismic activity and there is no geomorphic evidence of fault offsets on the Late Quaternary landforms. In concert with other recent studies, we propose that large rock slope failures in high mountains seldom react immediately to glacier withdrawal, but could display temporal delay lasting up to several millennia.

  20. Effect of quaternary ammonium salts on flotation behavior of aluminosilicate minerals

    Institute of Scientific and Technical Information of China (English)

    ZHAO Sheng-gui; ZHONG Hong; LIU Guang-yi

    2007-01-01

    The electrokinetic properties and flotation of diaspore, kaolinite, pyrophyllite and illite with quaternary ammonium salts collectors were studied. The results of flotation tests show that the collecting ability of quaternary ammonium salts for the four minerals is in the order(from strong to weak) of octadecyl dimethyl benzyl ammonium chloride(ODBA), cetyl trimethyl ammonium bromide(CTAB), dodecyl trimethyl ammonium chloride(DTAC). Under the condition of alkalescence, it is possible to separate the diaspore from the silicate minerals such as kaolinite, illite and pyrophyllite using quaternary ammonium salts as collector. Isoelectric points (IEP) of diaspore, kaolinite, pyrophyllite and illite are pH=6.0, 3.4, 2.3 and 3.2, respectively. Quaternary ammonium salts can change ζ-potential of the aluminosilicate minerals obviously. The flotation mechanisms were explained by ζ-potential and Fourier transform infrared spectrum (FT-IR) measurements. The results demonstrate that only electrostatic interaction takes place between aluminosilicate minerals (diaspore, kaolinite, pyrophyllite and illite) and quaternary ammonium salts.

  1. Ultra-low-power carbon nanotube FET-based quaternary logic gates

    Science.gov (United States)

    Sharifi, Fazel; Moaiyeri, Mohammad Hossein; Navi, Keivan; Bagherzadeh, Nader

    2016-09-01

    This paper presents low-power carbon nanotube field-effect transistor (CNTFET)-based quaternary logic circuits. The proposed quaternary circuits are designed based on the CNTFET unique properties, such as the same carrier mobility for N- and P-type devices and also providing desirable threshold voltages by adopting proper diameters for the nanotubes. In addition, no paths exist between supply and ground rails in the steady states of the proposed designs, which eliminates the ON state static current and also the stacking technique is utilised in order to significantly reduce the leakage currents. The results of the simulations, conducted using Synopsys HSPICE with the standard 32 nm CNTFET technology, confirm the significantly lower power consumption, higher energy efficiency and lower sensitivity to process variation of the proposed designs compared to the state-of-the-art quaternary logic circuits. The proposed quaternary logic circuits have on average 92, 99 and 91% less total power, static power and PDP, respectively, compared with the most low-power and energy-efficient CNTFET-based quaternary logic circuits, recently presented in the literature.

  2. The ichthyofauna of limnic systems in Quaternary deposits of extreme southern Brazil

    Directory of Open Access Journals (Sweden)

    Cindy Marques

    2016-12-01

    Full Text Available The Quaternary in the state of Rio Grande do Sul (RS, southern Brazil, is geologically represented by the coastal plain and was originated by successive events of Pleistocene-Holocene marine transgressions and the occurrence of alluvial deposits. This paper aimed to characterize the fish assemblage occurring in a swampy Quaternary area adjacent to Lagoa Pequena, a lacustrine system connected to the west margin of the Laguna dos Patos estuary. A checklist is also provided of the ichthyofauna so far recorded in limnic systems of Quaternary deposits in the state of Rio Grande do Sul. A total of 42 species was recorded, distributed in nine orders, 18 families and 31 genera. Characidae and Cichlidae were the most representative families, comprising 15 and 4 species respectively. A bibliographic revision associated to our sample data revealed the occurrence of 156 species in limnic systems inserted in RS Quaternary deposits (114 limnic, 15 marine/estuarine/limnic, ten marine/estuarine, nine estuarine/limnic and eight marine. Characiformes and Siluriformes are the most diverse orders, corroborating the Neotropical pattern. Seven species can be considered endemic to RS Quaternary deposits.

  3. Book Review: Quaternary Environmental Change in Southern Africa: Physical and Human Dimensions

    Science.gov (United States)

    Murray-Wallace, Colin V.

    2017-02-01

    This attractively presented book examines the legacy of a diverse range of Quaternary environmental processes in the fashioning of Southern African landscapes and their ultimate interconnection with human evolution, technological developments and subsistence in dynamically changing environments. In its 25 chapters the book reviews different elements of Southern African landscapes and emphasizes their diversity, from classical desert dune environments to glacial, periglacial, fluvial, karst, wetlands, estuaries and sandy coastal landscapes. In addition, the soils and duricrusts that are so distinctive to these landscapes (Runge) and colluvial deposits and slope instability (Botha et al.) are also reviewed. Evidence for Quaternary environmental change is also examined in terms of pollen, charcoal and plant macrofossil records (Bamford et al.), minerogenic microfossil records (Fitchett et al.) and terrestrial ecosystem changes in the late Quaternary (Meadows and Quick). The archaeological records of the Earlier Stone Age (Kuman), Middle Stone Age, and Later Stone Age (Mitchell) are also comprehensively reviewed.

  4. Synthesis and characterization of chitosan based dye containing quaternary ammonium group.

    Science.gov (United States)

    Tang, Ruilin; Zhang, Ying; Zhang, Yang; Yu, Zhiming

    2016-03-30

    A new antimicrobial biopolymer dye was synthesized by reaction of quaternary ammonium salt of chitosan and reactive red x-3b. And quaternary ammonium salt of chitosan was produced by grafting glycidyltrimethylammonium chloride on chitosan. The synthesized materials were characterized by Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), solubility test and antimicrobial test. Results show that the antimicrobial biopolymer dye was combined by N(+)(CH3)3 of quaternary ammonium salt of chitosan and sulfonic group of reactive red x-3b. Water solubility of chitosan biopolymer dye was increased as well as pH value. In addition, antibacterial property of new synthesized dye was excellent, whose antibacterial rates of Staphylococcus and Escherichia coli were both bigger than 99%. These results may provide new perspectives on improving the decorative properties and antimicrobial properties in wood industry.

  5. The nonmarine environment of Quaternary foraminifers in Yanshuzhuang, China: Evidence from boron and strontium isotopes

    Institute of Scientific and Technical Information of China (English)

    XIAO YingKai; XIAO Jun; ZHAO ZhiQi; HE MaoYong; LI ShiZhen

    2008-01-01

    The concentrations and isotopic compositions of boron and strontium of Quaternary foraminifers and bivalve fossils collected in the Yanghuzhuang section of Yanqing, Beijing and of modern gastropods living in the Guishui River and of river water were measured. The concentrations and isotopic compo-sitions of Quaternary foraminifers and bivalve fossils differed from those of modern marine fo-raminifers and were similar to those of modern terrestrial gastropods from the Guishui River. These results indicate that early Quaternary foraminifers in the Yanghuzhuang section inhabited a nonmarine environment and that these foraminifers were not the result of a transgression or sea flooding. The foraminifers were not special halobios and can survive in the terrestrial condition that resembled those of the ocean.

  6. Atmospheric effects on Quaternary polarization encoding for free space communication, laboratory simulation

    CERN Document Server

    Soorat, Ram

    2015-01-01

    We have simulated atmospheric effects such as fog and smoke in laboratory environment to simulate depolarisation due to atmospheric effects during a free space optical communi- cation. This has been used to study noise in two components of quaternary encoding for polarization shift keying. Individual components of a Quaternary encoding, such as vertical and horizontal as well as 45$^\\circ$ and 135$^\\circ$ , are tested separately and indicates that the depo- larization effects are different for these two situation. However, due to a differential method used to extract information bits, the protocol shows extremely low bit error rates. The information obtained is useful during deployment of a fully functional Quaternary encoded PolSK scheme in free space.

  7. Evidence of seismites in coastal Quaternary deposits of western Oranie (northwestern Algeria)

    Science.gov (United States)

    Boukhedimi, Mohamed Amine; Louni-Hacini, Amina; Bouhadad, Youcef; Ritz, Jean-François; Machane, Djamel; Benhamouche, Azzeddine; Bourenane, Hamid

    2016-10-01

    Coastal Quaternary deposits of western Oranie show typical soft-sediment deformations including sedimentary dykes, sand volcanoes, sismoslumps, thixotropic bowls, thixotropic wedges, diapir-like structures, and faults grading. Field observations indicate that these deformations exist at several levels of the studied deposits along the west Oranian coast. This study demonstrated that these structures are earthquakes-related, by analysis of potential trigger sources. Several arguments demonstrate the seismic origin: the depositional environment rich in water that located in an active tectonic region, the thixotropic nature of deformations and their large vertical and horizontal diffusion in the Quaternary series consistent with a seismic recurrence. This allows characterizing these Quaternary soft-sediment deformations as seismites that were triggered by earthquakes.

  8. Quaternary Evolution of North Core Sound Sound, North Carolina

    Science.gov (United States)

    Dietsche, Andrew

    Northern Core Sound is a shallow lagoonal estuary located behind the Outer Banks barrier islands of eastern North Carolina. Thirty-two vibracores and 155 km of chirp and boomer seismic data have been used to define the geologic framework and establish the Holocene evolution of this back-barrier lagoon. Vibracores have been logged for lithology, and sampled to establish the distribution and abundance of foraminifera. The lithostratigraphy and biofacies could not be directly correlated but when related to the seismic data, apparent patterns could be recognized. The Quaternary stratigraphic framework of North Core Sound consists of five depositional sequences, comprising transgressive, highstand, and falling stage systems tracts. Seismic reflections are prominent and are correlated to the sequence stratigraphic surfaces within Pamlico Sound defined by Mallinson et al. (2010). The late Pleistocene paleotopographic surface dips slightly seaward and is characterized by two or three fluvial channels correlating to modern embayments. These channels are separated by a paleotopographic high that extends from Cedar Island seaward. The channels run northeast in the north and southwest in the south creating two different paleo-environments. The paleotopographic high may have contributed to differing foraminiferal assemblages found within Holocene unit. The Holocene unit is characterized by high salinity estuarine deposits dominated by the foraminifera Elphidium excavatum and Ammonia parkinsoniana. Three very similar biofacies were defined with more abundant Ammonia parkinsoniana where salinities may have been slightly lower. Only a salt marsh facies was significantly different. The biofacies may also represent the two paleo-environments illustrated in the seismic data as one is mainly found to the north of the paleotopographic high and the other to the south. Two seismic reflections, H30 and H60, are interpreted as tidal ravinement surfaces and divide the Holocene into three

  9. Late Quaternary rates of stream incision in Northeast Peloponnese, Greece

    Science.gov (United States)

    Karymbalis, Efthimios; Papanastassiou, Dimitrios; Gaki-Papanastassiou, Kalliopi; Ferentinou, Maria; Chalkias, Christos

    2016-09-01

    This study focuses on defining rates of fluvial incision for the last 580±5 kyr along valley systems of eight streams that drain the eastern part of the northern Peloponnese. The streams are developed on the uplifted block of the offshore-running Xylokastro normal fault, one of the main faults bounding the southern edge of the Gulf of Corinth half-graben, and have incised a set of ten uplifted marine terraces having an amphitheatric shape. These terraces range in age from 60±5 kyr to 580±5 kyr and have been mapped in detail and correlated with late Pleistocene oxygen-isotope stages of high sea-level stands by previous studies. The terraces were used in this paper as reference surfaces in order to define fluvial incision rates at the lower reaches of the studied streams. To evaluate incision rates, thirty-three topographic valley cross-sections were drawn using fieldwork measurements as well as using a highly accurate (2×2 cell size) Digital Elevation Model (DEM) at specific locations where streams cut down the inner edges of the marine terraces. For each cross-section the ratio of valley floor width to valley height (Vf) and long-term mean stream incision rates were estimated for the last 580±5 kyr, while rock uplift rates were estimated for the last 330±5 kyr. The geomorphic evolution of the valleys on the uplifted block of the Xylokastro fault has been mainly driven by the lithology of the bedrock, sea level fluctuations during the late Quaternary, and incision of the channels due to the tectonic uplift. Stream incision rates range from 0.10±0.1 mm/yr for the last 123±7 kyr to 1.14±0.1 mm/yr for the last 310±5 kyr and are gradually greater from east to west depending on the distance from the trace of the fault. Downcutting rates are comparable with the rock uplift rates, which range from 0.4±0.02 mm/yr to 1.49±0.12 mm/yr, over the last 330±5 kyr.

  10. Synthesis and antibacterial activity screening of quaternary ammonium derivatives of triazolyl pyranochromenones

    Indian Academy of Sciences (India)

    PREETI YADAV; BIPUL KUMAR; HEMANT K GAUTAM; SUNIL K SHARMA

    2017-02-01

    A series of quaternary ammonium derivatives of triazolyl pyranochromen-2-ones have been synthesized and characterized; their antibacterial potential were investigated against two gram negative (Pseudomonas aeruginosa and Escherichia coli) and two gram positive bacterial strains (Bacillus cereus and Staphylococcus aureus). In order to develop structure-activity relationship (SAR), the effect of varying the substituent (R) at the C-10 position of pyranochromen-2-one as well as the length of the spacer (n) between the triazolyl pyranochromen-2-ones and quaternary ammonium group, on the antibacterial activity of compoundshas been evaluated. Some of the screened compounds exhibited antibacterial potential against the studied strains in the microgram range.

  11. Geomorphological effects of plate movemen during Quaternary in China's tropics

    Institute of Scientific and Technical Information of China (English)

    ZHANGWeiqiang; HUANGZhenguo

    2004-01-01

    The eastern and western fronts of plate movement in Taiwan Island and Tibetan Plateau respectively are the two major sources of tectonic force for the morphogensis during Quaternary in China's tropics. Seven examples of geomorphological effects of plate movement are enumerated to discuss the differentiation of tectonic landforms in space and time during Quaternary. The tectonic movement tends to be more active since middle Pleistocene. Some phenomena such as the arc-shape mountain systems, volcanism and crustal deformation imply that the juncture zone of eastern and western tectonic forces is located at about 110°E.

  12. Towards dating Quaternary sediments using the quartz Violet Stimulated Luminescence (VSL) signal

    DEFF Research Database (Denmark)

    Ankjærgaard, C.; Jain, Mayank; Wallinga, J.

    2013-01-01

    Quartz optically stimulated luminescence (OSL) dating is widely used to determine the time of deposition and burial of Late Quaternary sediments. Application of the method is usually limited to the past 150,000 years due to early saturation of the OSL signal. Here we explore the potential to date...... Quaternary sediments using the violet (402 nm) stimulated luminescence (VSL) signal of quartz.We develop and test a new post-blue VSL single aliquot regenerative dose dating protocol, and demonstrate that the VSL signal originates from a deep trap at about 1.9 eV with a thermal lifetime of 1011 years at 10...

  13. A study of 36Cl age in Quaternary groundwater of Hebei plain, China

    Institute of Scientific and Technical Information of China (English)

    周炼; 刘存富; 姜山; 高山

    2001-01-01

    Chlorine-36 has various advantages as a dating tool for old groundwater. In this paper, 36CI of Quaternary groundwater in the Hebei plain of North China has been measured using accelerator mass spectrometry (AMS). Ages calculated from the 36CI/CI ratio show that ion filtration, which is responsible for the CI- concentration increasing with depth and along flow paths in Hebei plain groundwater. It is concluded that 36CI age of the groundwater in the 3rd Group of the Quaternary (Q2) in the Cangzhou area is 250ka, and that of the 4th Group(Q1) is 300ka.

  14. A New Quaternary Strand of the Karakoram Fault System, Ladakh Himalayas

    Science.gov (United States)

    Bohon, W.; Hodges, K.; Arrowsmith, R.; Tripathy, A.

    2009-12-01

    The NW-SE striking, dextral Karakoram fault system stretches for more than 1200 km from the Pamirs of Central Asia at least as far southeast as the Kailas area of Tibet. Estimates for the total lateral displacement along the fault system range from 150-1000 km, and estimated Quaternary rates of slip range from 1 to 30 mm/yr. In the Ladakh region of NW India (~ 33°28’N, 78°45’E), the fault system expresses as northern and southern strands bounding the Pangong Range. Studies of ductile deformation fabrics along these strands suggest that slip began in the Miocene, and Brown et al. (2002) documented Quaternary right-lateral slip along the northern strand at ~4 mm/yr on the basis of offset geomorphic features. The lack of documented Quaternary offset along the southern strand has led most researchers to assume that Quaternary slip on the Karakoram fault system in this region was partitioned exclusively to the northern strand. Our summer 2009 field work in the Pangong Range and adjacent Nubra Valley provides the first documentation of significant Quaternary activity along the southern strand. In the valley between the villages of Tangste (34°01’ N, 78°10’ E) and Durbuk (34°06’ N, 78°07’), the fault is visible high on the northeastern mountain side as a break in slope with offset Quaternary paleosurfaces and beheaded and offset stream channels, the largest of which have been displaced by as much as 250 m. Field mapping north of Durbuk, near the town of Tangyar (34°15’N, 77°52’E), shows that the southern strand continues northwest and cuts across the landscape as a sinuous, continuous trace with shutter ridges, offset alluvial fan surfaces, and sag ponds developed along its length. In this region, the northern and southern strands are linked by a Quaternary, E-directed thrust fault that places high-grade metamorphic rocks over poorly consolidated Quaternary alluvium. The partitioning of dextral slip between two strands of the Karakoram system

  15. Design and Stereoselective Preparation of a New Class of Chiral Olefin Metathesis Catalysts and Application to Enantioselective Synthesis of Quebrachamine: Catalyst Development Inspired by Natural Product Synthesis

    Science.gov (United States)

    Sattely, Elizabeth S.; Meek, Simon J.; Malcolmson, Steven J.; Schrock, Richard R.; Hoveyda, Amir H.

    2010-01-01

    A total synthesis of the Aspidosperma alkaloid quebrachamine in racemic form is first described. A key catalytic ring-closing metathesis of an achiral triene is used to establish the all-carbon quaternary stereogenic center and the tetracyclic structure of the natural product; the catalytic transformation proceeds with reasonable efficiency through the use of existing achiral Ru or Mo catalysts. Ru- or Mo-based chiral olefin metathesis catalysts have proven to be inefficient and entirely nonselective in cases where the desired product is observed. In the present study, the synthesis route thus serves as a platform for the discovery of new olefin metathesis catalysts that allow for efficient completion of an enantioselective synthesis of quebrachamine. Accordingly, on the basis of mechanistic principles, stereogenic-at-Mo complexes bearing only monodentate ligands have been designed. The new catalysts provide significantly higher levels of activity than observed with the previously reported Ru- or Mo-based complexes. Enantiomerically enriched chiral alkylidenes are generated through diastereoselective reactions involving achiral Mo-based bispyrrolides and enantiomerically pure silyl-protected binaphthols. Such chiral catalysts initiate the key enantioselective ring-closing metathesis step in the total synthesis of quebrachamine efficiently (1 mol % loading, 22 °C, 1 h, >98% conversion, 84% yield) and with high selectivity (98:2 er, 96% ee). PMID:19113867

  16. A Shape-Adaptive, Antibacterial-Coating of Immobilized Quaternary-Ammonium-Compounds Tethered on Hyperbranched Polyurea and its Mechanism of Action

    NARCIS (Netherlands)

    Asri, Lia; Crismaru, Mihaela; Roest, Steven; Chen, Yun; Ivashenko, Oleksii; Rudolf, Petra; Tiller, Joerg C.; van der Mei, Henny C.; Loontjens, Ton J.A.; Busscher, Henk J. Busscher

    2014-01-01

    Quaternary-ammonium-compounds are potent cationic antimicrobials used in everyday consumer products. Surface-immobilized, quaternary-ammonium-compounds create an antimicrobial contact-killing coating. We describe the preparation of a shape-adaptive, contact-killing coating by tethering quaternary-am

  17. Late Quaternary Megafaunal Extinctions in Northern Eurasia: Latest Results

    Science.gov (United States)

    Stuart, Anthony

    2010-05-01

    Anthony J. Stuart1 & Adrian M. Lister2 1 Biological and Biomedical Sciences, Durham University, South Road, Durham DH1 3LE, UK. Email: tony.s@megafauna.org.uk 2 Department of Palaeontology, The Natural History Museum, Cromwell Road, London SW7 5BD, UK. Email: a.lister@nhm.ac.uk. The global extinction of many spectacular species of megafauna (large terrestrial mammals, together with a few large reptiles and birds) within the last c. 50,000 years (Late Quaternary) has been attributed on the one hand to ‘overkill' by human hunters and on the other to environmental change. However, in spite of more than half a century of active interest and research the issue remains unresolved, largely because there are insufficient dated records of megafaunal species for most parts of the world. Northern Eurasia is an especially fruitful region in which to research megafaunal extinctions as it has a wealth of megafaunal material and crucially most extinctions occurred well within the range of radiocarbon dating. Our approach, in a series of projects over the last decade funded by the UK Natural Environment Research Council (NERC), involves amassing radiocarbon dates made directly on megafaunal material from across the entire region: a) by submitting a substantial number of samples (so far c. 500 dates) for AMS dating at Oxford (ORAU); b) obtaining AMS dates from colleagues working on aDNA projects; and c) carefully screening (‘auditing') dates from the literature. The dates (calibrated using OxCal) are plotted as time-sliced maps and as chronological/geographical charts. In our previous work we targeted a range of extinct species from Northern Eurasia: woolly mammoth, woolly rhinoceros, giant deer, cave bear (in collaboration with Martina Pacher), cave lion, and spotted hyaena (which survives today only in Sub-Saharan Africa). By this means we have established a reliable chronology for these extinctions which we are able to compare with the climatic, vegetational and

  18. QuaBingo: A Prediction System for Protein Quaternary Structure Attributes Using Block Composition

    Directory of Open Access Journals (Sweden)

    Chi-Hua Tung

    2016-01-01

    Full Text Available Background. Quaternary structures of proteins are closely relevant to gene regulation, signal transduction, and many other biological functions of proteins. In the current study, a new method based on protein-conserved motif composition in block format for feature extraction is proposed, which is termed block composition. Results. The protein quaternary assembly states prediction system which combines blocks with functional domain composition, called QuaBingo, is constructed by three layers of classifiers that can categorize quaternary structural attributes of monomer, homooligomer, and heterooligomer. The building of the first layer classifier uses support vector machines (SVM based on blocks and functional domains of proteins, and the second layer SVM was utilized to process the outputs of the first layer. Finally, the result is determined by the Random Forest of the third layer. We compared the effectiveness of the combination of block composition, functional domain composition, and pseudoamino acid composition of the model. In the 11 kinds of functional protein families, QuaBingo is 23% of Matthews Correlation Coefficient (MCC higher than the existing prediction system. The results also revealed the biological characterization of the top five block compositions. Conclusions. QuaBingo provides better predictive ability for predicting the quaternary structural attributes of proteins.

  19. Quaternary rhyolite from the Mineral Mountains, Utah, USA. Final report, Volume 77-10

    Energy Technology Data Exchange (ETDEWEB)

    Evans, S.H. Jr.; Nash, W.P.

    1978-03-01

    A suite of silicic volcanic rocks is associated with the Roosevelt Hot Springs geothermal area in southwestern Utah. The volcanic sequence includes Tertiary rhyolite 8 My old and obsidian, ash and rhyolite of Quaternary age. The Quaternary lavas are characterized by high silica content (76.5% Si0/sub 2/) and total alkalies in excess of 9 percent. Obsidians commonly contain greater amounts of fluorine than water. Two older flows (0.8 My) can be distinguished from younger dome and pyroclastic material (approximately 0.5 My) by subtle differences in their chemistry. The mineralogy of the rhyolites consists of alkali feldspar, plagioclase, and small amounts of Fe-Ti oxides, biotite, hornblende and rare allanite. Fe-Ti oxide temperatures are 740 to 785/sup 0/C for the flows and 635 to 665/sup 0/C for the domes; two feldspar temperatures give similar results. The phase relationships of bulk rock, glass and feldspar compositions demonstrate that the younger Quaternary rhyolites could have been derived from the earlier magma type, represented by the obsidian flows, by a process of crystal fractionation. The major phases which must fractionate are alkali feldspar, plagioclase and quartz with minor amounts of biotite, magnetite and ilmenite participating also. Trace element patterns support this scheme as well. The Tertiary lavas cannot be related to the Quaternary rhyolites and are thought to represent a separate event.

  20. Synthesis, EPR and Fluorescence Properties of Quaternary Lanthanide Complexes with Chloroacetate and Phenanthroline Ligands

    Institute of Scientific and Technical Information of China (English)

    朱龙观; 肖洪平

    2002-01-01

    A series of novel quaternary mixed anion complexes of lanthanide containing 1,10-phenanthroline (phen) and chloroacetate ligands were synthesized from the water/ethanol solution with slightly acidic solution and characterized by elemental analysis, IR, UV and thermal analysis. The EPR and fluorescence properties also were studied.

  1. A New Method to Identify Quaternary Moraine:Acoustic Emission Stress Measurement

    Institute of Scientific and Technical Information of China (English)

    ZHAO Zhizhong; QIAO Yansong; TIAN Jiaorong; WANG Min; LI Mingze; HE Peiyuan; QIAN Fang

    2006-01-01

    How to effectively identify glacial sediments, especially Quaternary moraine, has been in dispute for decades. The traditional methods, e.g., sedimentary and geomorphologic ones, are facing challenge in eastern China where controversial moraine deposits are dominatingly distributed. Here,for the first time, we introduce the acoustic emission (AE) stress measurement, a kind of historical stress measurement, to identify Quaternary moraine. The results demonstrate that it can be employed to reconstruct stress information of glaciation remaining in gravels, and may shed light on the identification of Quaternary moraine in eastern China. First, we measured the AE stress of gravels of glacial origin that are underlying the Xidatan Glacier, eastern Kunlun Mountains in western China.Second, we calculated the stress according to the actual thickness of the glacier. The almost identical stress values suggest that the glacial gravels can memorize and preserve the overlying glacier-derived aplomb stress. And then we introduce this new approach to the controversial moraine in Mount Lushan, eastern China. The results indicate that the stress is attributed to the Quaternary glacier, and the muddy gravels in the controversial moraine in Mount Lushan are moraine deposits but not others.

  2. Blockfields in Reinheimen Nationalpark, Norway – Neogene weathering remnants or Quaternary periglacial origin?

    DEFF Research Database (Denmark)

    Andersen, Jane Lund; Egholm, David Lundbek; Knudsen, Mads Faurschou;

    rates of landscape evolution of the mountain summit. References Goodfellow B W, 2012. A granulometry and secondary mineral fingerprint of chemical weathering in periglacial landscapes and its application to blockfield origins. Quaternary Science Reviews, 57, 121- 135. Strømsøe J R, Paasche Ø, 2011....... Weathering patterns in high-latitude regolith. Journal of Geophysical Research: Earth Surface, 116 (F3)...

  3. Epoxidation of Alkenes with Aqueous Hydrogen Peroxide and Quaternary Ammonium Bicarbonate Catalysts

    DEFF Research Database (Denmark)

    Mielby, Jerrik Jørgen; Kegnæs, Søren

    2013-01-01

    A range of solid and liquid catalysts containing bicarbonate anions were synthesised and tested for the epoxidation of alkenes with aqueous hydrogen peroxide. The combination of bicarbonate anions and quaternary ammonium cations opens up for new catalytic systems that can help to overcome challen...

  4. Different virucidal activities of hyperbranched quaternary ammonium coatings on poliovirus and influenza virus

    NARCIS (Netherlands)

    Tuladhar, E.; Koning, M.C. de; Fundeanu, I.; Beumer, R.; Duizer, E.

    2012-01-01

    Virucidal activity of immobilized quaternary ammonium compounds (IQACs) coated onto glass and plastic surfaces was tested against nveloped influenza A (H1N1) virus and nonenveloped poliovirus Sabin1. The IQACs tested were virucidal against the influenza virus within 2 min, but no virucidal effect ag

  5. Long alkyl chain bis-quaternary ammonium-based ionic liquids as biologically active xanthene dyes

    Energy Technology Data Exchange (ETDEWEB)

    Pernak, Juliusz; Swierczynska, Anna; Walkiewicz, Filip [Poznan Univ. of Technology, Poznan (Poland). Faculty of Chemical Technology; Krystkowiak, Ewa [A. Mickiewicz University, Poznan, (Poland). Faculty of Chemistry; Maciejewski, Andrzej [A. Mickiewicz University, Poznan (Poland). Centre of Ultrafast Laser Spectroscopy

    2009-07-01

    New examples of air- and moisture-stable, hydrophobic and hydrophilic bis-quaternary ammonium derived ionic liquids have been prepared. These ionic liquids have been proposed to act as biological active dyes with characteristic unique physicochemical properties, providing alternatives to some conventional anionic xanthene dyes such as eosine Y, fluorescein and erythrosine. (author)

  6. High order quaternary arrangement confers increased structural stability to Brucella Spp. lumazine synthase

    Energy Technology Data Exchange (ETDEWEB)

    Zylberman, V.; Craig, P.O.; Klinke, S.; Cauerhff, A.; Goldbaum, F.A. [Instituto Leloir, Buenos Aires (Argentina); Braden, B.C. [Bowie State Univ., Maryland (United States)

    2004-07-01

    The penultimate step in the pathway of riboflavin biosynthesis is catalyzed by the enzyme lumazine synthase (LS). One of the most distinctive characteristics of this enzyme is the structural quaternary divergence found in different species. The protein exists as pentameric and icosahedral forms, built from practically the same structural monomeric unit. The pentameric structure is formed by five 18 kDa monomers, each extensively contacting neighboring monomers. The icosahedral structure consists of 60 LS monomers arranged as twelve pentamers giving rise to a capsid exhibiting icosahedral 532 symmetry. In all lumazine synthases studied, the topologically equivalent active sites are located at the interfaces between adjacent subunits in the pentameric modules. The Brucella spp. lumazine synthase (BLS) sequence clearly diverges from pentameric and icosahedral enzymes. This unusual divergence prompted to further investigate on its quaternary arrangement. In the present work, we demonstrate by means of solution Light Scattering and X-ray structural analyses that BLS assembles as a very stable dimer of pentamers representing a third category of quaternary assembly for lumazine synthases. We also describe by spectroscopic studies the thermodynamic stability of this oligomeric protein, and postulate a mechanism for dissociation/unfolding of this macromolecular assembly. The higher molecular order of BLS increases its stability 20 deg C compared to pentameric lumazine synthases. The decameric arrangement described in this work highlights the importance of quaternary interactions in the stabilization of proteins. (author)

  7. Synthesis and Spectroscopic Characterisation of N-Alkyl Quaternary Ammonium Salts Typical Precursors of Cyanines

    OpenAIRE

    Almeida, P; Reis, L. V.; SANTOS, P.F.; Ramos, S. S.; Pardal, A. C.

    2002-01-01

    The synthesis and spectroscopic characterisation of some representative N-alkylsubstituted quaternary ammonium salts derived from benzothiazole, benzoxazole, benzoselenazole, indole and quinoline are described. These heterocyclic salts, bearing an activated methyl group in the 2-position in relation to the nitrogen atom and N-methyl, -pentyl, -hexyl and -decyl chains, are typical precursors of cyanine dyes.

  8. Synthesis and Spectroscopic Characterisation of N-Alkyl Quaternary Ammonium Salts Typical Precursors of Cyanines

    Directory of Open Access Journals (Sweden)

    P. Almeida

    2002-03-01

    Full Text Available The synthesis and spectroscopic characterisation of some representative N-alkylsubstituted quaternary ammonium salts derived from benzothiazole, benzoxazole, benzoselenazole, indole and quinoline are described. These heterocyclic salts, bearing an activated methyl group in the 2-position in relation to the nitrogen atom and N-methyl, -pentyl, -hexyl and -decyl chains, are typical precursors of cyanine dyes.

  9. Modular, Catalytic Enantioselective Construction of Quaternary Carbon Stereocenters by Sequential Cross-Coupling Reactions.

    Science.gov (United States)

    Potter, Bowman; Edelstein, Emma K; Morken, James P

    2016-07-01

    The catalytic Suzuki-Miyaura cross-coupling with chiral γ,γ-disubstituted allylboronates in the presence of RuPhos ligand occurs with high regioselectivity and enantiospecificity, furnishing nonracemic compounds with quaternary centers. Mechanistic experiments suggest that the reaction occurs by transmetalation with allyl migration, followed by rapid reductive elimination.

  10. A chronology of alluvial fan response to Late Quaternary sea level and climate change, Crete

    Science.gov (United States)

    Pope, Richard J. J.; Candy, Ian; Skourtsos, Emmanuel

    2016-09-01

    To better understand how fluvial systems respond to late Quaternary climatic forcing OSL and U-series dating was applied to stratigraphically significant sedimentary units within a small (aggradation to occur except during major climatic driven transitions i.e. major sea level fall and postglacial vegetation development.

  11. Quaternary Volcanic Activities in Shandong Peninsula and Northern Parts of Jiangsu and Anhui Provinces

    Institute of Scientific and Technical Information of China (English)

    郑洪汉; 高维明; 等

    1990-01-01

    Quaternary volcanic rocks often coexist with loess,as observed in the same geologic sections in the Shandong Peninsula and northern parts of Jiangsu and Anhui provinces.The development age of Shandong loess in close to that in the middle reaches of the Yellow River.Loess strata are of synchronous implication in the loess belt of North China.So the ages of volcanic activities can be es-timated approximately from the stratigraphic relations between loess layers and volcanic rocks.The re-sults of dating of the Quaternary volcanic rocks,baked layers and the TL dates of loess samples sug-gest that the Quaternary volcanic activity can be divided into 4 stages in the region studied,with the ages being 1.15-1.03,0.86-0.72,0.55-0.33 and 0.02 Ma B.P.respectively .The occurrence of tephra in the Shandong loess sections is possible due to multiple episodes of volcanism during the Quaternary time.

  12. The influence of climate on species distribution over time and space during the late Quaternary

    Science.gov (United States)

    Carotenuto, F.; Di Febbraro, M.; Melchionna, M.; Castiglione, S.; Saggese, F.; Serio, C.; Mondanaro, A.; Passaro, F.; Loy, A.; Raia, P.

    2016-10-01

    Understanding the effect of climate on the composition of communities and its change over time and space is one of the major aims in ecology and paleoecology. Herein, we tackled on this issue by studying late Quaternary large mammal paleocommunities of Eurasia. The late Quaternary was a period of strong environmental instability, especially characterized by the occurrence of the last glacial maximum (LGM). We used community phylogenetics and joint species distribution models in order to understand the factors determining paleocommunity composition in the late Quaternary. Our results support the existence of strong climatic selection operating on the LGM fauna, both through the disappearance of warm-adapted species such as Elephas antiquus, Hippopothamus amphibious, and Stephanorhinus hemitoechus, and by setting the stage for the existence of a community characterized by cold-adapted large mammals. Patterns of abundance in the fossil record, co-occurrence between species pairs, and the extent of climatic forcing on faunal composition, differ between paleocommunities, but not between extinct and extant species, which is consistent with the idea that climate change, rather than the presence of humans, exerted a major effect on the survival of the late Quaternary megafauna.

  13. Synthesis of hierarchical zeolites using an inexpensive mono-quaternary ammonium surfactant as mesoporogen.

    Science.gov (United States)

    Zhu, Xiaochun; Rohling, Roderigh; Filonenko, Georgy; Mezari, Brahim; Hofmann, Jan P; Asahina, Shunsuke; Hensen, Emiel J M

    2014-12-04

    A simple amphiphilic surfactant containing a mono-quaternary ammonium head group (N-methylpiperidine) is effective in imparting substantial mesoporosity during synthesis of SSZ-13 and ZSM-5 zeolites. Highly mesoporous SSZ-13 prepared in this manner shows greatly improved catalytic performance in the methanol-to-olefins reaction compared to bulk SSZ-13.

  14. A glimpse of the Quaternary monsoon history from India and adjoining seas

    Digital Repository Service at National Institute of Oceanography (India)

    Saraswat, R.; Nigam, R.; Correge, T.

    , it seems clear that a major intensification of the summer monsoon occurred at ~ 8.2 Ma. A seasonal monsoon circulation with distinct summer and winter monsoon phases was established at ~ 2.8 Ma. In the Late Quaternary, the summer monsoon weakens during...

  15. Species-specific responses of Late Quaternary megafauna to climate and humans

    DEFF Research Database (Denmark)

    Lorenzen, Eline D; Nogués-Bravo, David; Orlando, Ludovic

    2011-01-01

    Despite decades of research, the roles of climate and humans in driving the dramatic extinctions of large-bodied mammals during the Late Quaternary period remain contentious. Here we use ancient DNA, species distribution models and the human fossil record to elucidate how climate and humans shape...

  16. Characteristics of Quaternary deposits near Songjianghe Town on west slope of Changbai Mountain

    Institute of Scientific and Technical Information of China (English)

    WANG Xi-kui; LI Jun-min; ZHANG Hong-yan

    2004-01-01

    On the basis of field survey, microscope sighting, TL dating and scanning electron microscope analysis, the characteristics of Quaternary deposits near Songjianghe Town on the west slope of Changbai Mountain are analyzed and described. There were two phases of volcanism during Mid-Late Quaternary. One occurred before 15.22 × 104 aB.P. and the other happened between 14.27 × 104 aB.P. and 1.41 × 104 aB.P. Volcanism is a landform-making process which makes the rough relief in the studied area become higher and higher. Flow water is a main erosion agency and it cuts into the basalts making river valleys. The Quaternary fluvial deposits distributed on terraces first come from the weathered debris of basement rocks, then they are transported and deposited by flow water. After 1.41 × 104 aB.P, the river water quickly cuts into the newly formed basalts making a deep valley. Volcanism in the studied area is a main landform-making event in Mid-Late Quaternary.

  17. Late Quaternary vegetation and glacial history in the St. Lawrence Lowlands, Canada

    NARCIS (Netherlands)

    Lasalle, Pierre

    1966-01-01

    This paper presents data of various kinds concerning the Quaternary geology of the St. Lawrence Lowlands: pollen diagrams, C14 dates, and diatom floras. These data show that the highest parts of the St. Lawrence Lowlands were already deglaciated more than 12,000 years ago, as appears from the existe

  18. Systematic paleontology of Quaternary ostracode assemblages from the Gulf of Alaska; Part 3, Family Cytheruridae

    Science.gov (United States)

    Brouwers, E.M.

    1994-01-01

    Forty-six species of podocopid ostracodes, most belonging to the Family Cytheruridae, are reported from Quaternary continental-shelf sediments of the Gulf of Alaska. Descriptions and illustrations are provided for 27 new species, 11 previously described species, and 8 species retained in open nomenclature. This report is based on 198 bottom grab samples collected during 1975, 1979, and 1980.

  19. 40 CFR 721.9075 - Quaternary ammonium salt of fluorinated alkylaryl amide.

    Science.gov (United States)

    2010-07-01

    ... fluorinated alkylaryl amide. 721.9075 Section 721.9075 Protection of Environment ENVIRONMENTAL PROTECTION... amide. (a) Chemical substance and significant new uses subject to reporting. (1) The chemical substance identified generically as quaternary ammonium salt of fluorinated alkylaryl amide (PMN No. P-92-688)...

  20. Superoxide Anion Radical Scavenging Ability of Quaternary Ammonium Salt of Chitosan

    Institute of Scientific and Technical Information of China (English)

    Xiao Yan ZHU; Jian Min WU; Zhi Shen JIA

    2004-01-01

    A series of N-alkyl or N-aryl chitosan quaternary ammonium salt were prepared using 96% deacetylated chitosan. Their scavenging activities against superoxide anion radical were investigated by chemiluminescence. The IC50 values of these compounds range from 280 to 880 μg/mL, which should be attributed to their different substitutes.

  1. Gravity field separation and mapping of buried quaternary valleys in Lolland, Denmark using old geophysical data

    DEFF Research Database (Denmark)

    Møller, M.J.; Olsen, Henrik; Ploug, C.;

    2007-01-01

    In this paper we utilise the old industrial data for planning new surveys. The overall purpose is a detailed mapping of possible aquifers for the island of Lolland, Denmark. This is done through detection and modelling of the buried quaternary valleys, which either can serve as potential aquifers...

  2. Kinetics of Hydrolysis of Cationic Reactive Disperse Dyes Containing Quaternary Group

    Institute of Scientific and Technical Information of China (English)

    XIE Kong-liang; HOU Ai-qin

    2006-01-01

    The kinetics of hydrolysis of cationic reactive disperse dyes containing quaternary group and chemical shift(13CNMR) of the adjacent carbon atoms with pyridine-acetylamino were discussed. The results show pyridine-acetylamino reactive group had higher reactivity than chloroacetylamino and chemical shift(13CNMR) of the adjacent carbon atoms with pyridine-acetylamino moved 18.77 ppm.

  3. Quaternary tectonic movements in the Argentine Puna, 24/sup 0/ to 27/sup 0/ s latitude

    Energy Technology Data Exchange (ETDEWEB)

    Strecker, M.R.; Alonso, R.; Rivelli, F.; Mon, R.

    1985-01-01

    The Puna of NW Argentina, one of the highest plateaus in the world, is the southern continuation of the Andean Altiplano geomorphic province of Peru and Bolivia. The region is not seismically active and reports of neotectonic movements are scarce. However, the areas of Salar de los Pastos Grandes, Salar del Hombre Muerto and Sierra Calalaste clearly have experienced Quaternary tectonic movements. At Salar de los Pastos Grandes, early Pleistocene lake sediments are offset by reverse faulting. At Salar del Hombre Muerto, Quaternary pyroclastic and debris-flow deposits are unconformable over sediments 5.86 m.y. old that were folded during the Pliocene-Pleistocene Diaguita deformation. Within the Quaternary sediments two separate deformational phases with reverse faulting and shallow thrusting are recognized. The timing of movement is well defined since the deformed strata are covered by a basalt flow 0.75 m.y. old. The flow in turn is affected by normal faulting. Similar normal faults associated with basalt flows were found at Sierra Calalaste. These observations are in accord with pronounced extensional movements and basaltic volcanism at the Calama-Olacapato-Toro Lineament (0.2 m.y. old flows) and might document the Quaternary transition from a compressive to an extensional tectonic regime in the southern Puna.

  4. Synthesis and biological activity of quaternary ammonium salt-type agents containing cholesterol and terpenes.

    Science.gov (United States)

    Novotná, Eva; Waisser, Karel; Kuneš, Jiří; Palát, Karel; Buchta, Vladimír; Stolaříková, Jiřina; Beckert, Rainer; Wsól, Vladimír

    2014-06-01

    New quaternary ammonium salt-type compounds with lipophilic cholesterol and terpene moieties were synthesized. The compounds showed promising antibacterial and antimycobacterial activities. Those compounds containing the cholesterol moiety showed significant activity against Staphylococcus aureus, Staphylococcus epidermidis, and Enterococcus faecium. On the contrary, the antimycobacterial activity increased with the presence of the terpene unit in the molecule.

  5. Late Quaternary faulting and historic seismicity in the western Lake Mead area, Nevada, Arizona and California

    Energy Technology Data Exchange (ETDEWEB)

    Anderson, L.W.; O' Connel, D.R. (Bureau of Reclamation, Denver, CO (United States))

    1993-04-01

    As part of a regional seismic hazard study for Reclamation dams on the northern lower Colorado River, the age and distribution of known and suspected late Quaternary faults were investigated and historic seismicity was analyzed for the western Lake Mead area. Late Quaternary faults in the area consist of the Mead Slope, Black Hills, Frenchman Mountain, and California Wash faults. Geologic mapping and scarp profiles indicate that of these late Quaternary faults, the Black Hills fault displays evidence for the youngest (probably mid-Holocene) surface faulting. No information about the ages of older events was obtained for any of the faults; however, the ages of the most recent surface-rupturing events for individual faults suggest recurrence intervals of tens of thousands of years for specific faults and regional recurrence rates of several thousand years for M[sub 3] [>=] 6 1/2 events. Since 1936 when Hoover Dam was completed and the initial filling of Lake Mead began, the Boulder Basin area, the largest and deepest part of Lake Mead, has experienced abundant seismic activity that includes some of the largest historic earthquakes in southern Nevada (at least 21 M 4 events and one M 5). Based on earthquake locations from early networks (1937--1950) and those from temporary networks operating in 1975--1976 and 1988, earthquakes are clearly associated with the northeast-striking Mead Slope and Black Hills faults; one of the few associations of seismicity with late Quaternary faults in the Basin and Range. However, earthquakes also appear to be associated with the Fortification fault, a north-striking fault with no evidence of Quaternary surface faulting. Focal mechanisms for some of the 1975--1976 and 1988 events (all events M [<=] 3) suggest active strike-slip/oblique-slip motion on north-striking faults and normal/oblique-slip motion on northeast-striking structures.

  6. The quaternary lidocaine derivative, QX-314, exerts biphasic effects on transient receptor potential vanilloid subtype 1 channels in vitro

    DEFF Research Database (Denmark)

    Rivera-Acevedo, Ricardo E; Pless, Stephan Alexander; Ahern, Christopher A;

    2011-01-01

    BACKGROUND: Transient receptor potential vanilloid subfamily member 1 (TRPV1) channels are important integrators of noxious stimuli with pronounced expression in nociceptive neurons. The experimental local anesthetic, QX-314, a quaternary (i.e., permanently charged) lidocaine derivative, recently...

  7. Radiocarbon chronologies and extinction dynamics of the Late Quaternary mammalian megafauna of the Taimyr Peninsula, Russian Federation

    NARCIS (Netherlands)

    MacPhee, RDE; Tikhonov, AN; Mol, D; Maliave, CD; Van der Plicht, H; Greenwood, AD; Flemming, C; Agenbroad, L; MacPhee, Ross D.E.; Tikhonov, Alexei N.; Marliave, Christian de; Greenwood, Alex D.

    2002-01-01

    This paper presents 75 new radiocarbon dates based on late Quaternary mammal remains recovered from eastern Taimyr Peninsula and adjacent parts of the northern Siberian lowlands, Russian Federation, including specimens of woolly mammoth (Mammuthus primigenius), steppe bison (Bison priscus), muskox (

  8. Clay minerals as palaeomonsoon proxies: Evaluation and relevance to the late Quaternary records from SE Arabian Sea

    Digital Repository Service at National Institute of Oceanography (India)

    Thamban, M.; Rao, V.P.

    as palaeoclimatic proxies are evaluated and discussed. Systematic investigations using several sediment cores from the SE Arabian Sea reveal that despite the influence of several complicating factors, variations in clay mineral composition during the late Quaternary...

  9. Cretaceous to Quaternary Siliciclastic Sediments of the Tarfaya Basin, Marginal Atlantic, SW Morocco Petrography, Geochemistry, Provenance, Climate and Weathering

    OpenAIRE

    Ali, Sajid

    2012-01-01

    This dissertation is prepared to attain the doctorate under the title "Cretaceous to Quaternary Siliciclastic Sediments of the Tarfaya Basin, Marginal Atlantic, SW Morocco Petrography, Geochemistry, Provenance, Climate and Weathering".

  10. Ground-water quality in quaternary deposits of the central high plains aquifer, south-central Kansas, 1999

    Data.gov (United States)

    US Fish and Wildlife Service, Department of the Interior — Water samples from 20 randomly selected domestic water-supply wells completed in the Quaternary deposits of south-central Kansas were collected as part of the High...

  11. SN2-type ring opening of substituted--tosylaziridines with zinc (II) halides: Control of racemization by quaternary ammonium salt

    Indian Academy of Sciences (India)

    Manas K Ghorai; Deo Prakash Tiwari; Amit Kumar; Kalpataru Das

    2011-11-01

    Quaternary ammonium salt mediated highly regioselective ring opening of aziridines with zinc(II) halides to racemic and non-racemic -halo amines in excellent yield and selectivity is described. The reaction proceeds via an SN2-type pathway and the partial racemization of the starting substrate and the product was effectively controlled by using quaternary ammonium salts to afford the enantioenriched products (er up to 95:5).

  12. Microstructure and mechanical properties of Al3Ti-based alloys in Al-Ti-Mo-X quaternary systems

    Institute of Scientific and Technical Information of China (English)

    Seiji Miura; Tetsuo Mohri

    2003-01-01

    A part of Al -Ti-Mo-Cr quaternary phase diagram is constructed for the microstructure control of D022-Al3Ti or its derivative, LI2-(Al,Cr)3Ti, -based alloys. It was found that quaternary bce phase equilibrates with either DO222-A13Ti or L12-(Al,Cr)3Ti, orboth, exist in large compositional areas. The mechanical properties is strongly affected by precipitates appearing, and presumablyalloy microstructures.

  13. Effective electron mass in quantum wires of III-V, ternary and quaternary materials.

    Science.gov (United States)

    Paitya, N; Ghatak, K P

    2012-12-01

    In this paper, an attempt is made to study the effective electron mass (EEM) in Quantum wires (QWs) of III-V, ternary and quaternary materials on the basis of three and two band models of Kane within the framework of k x p formalism. It has been found, taking QWs of InAs, InSb, GaAs, Hg(1-x)Cd(x)Te and In(1-x)Ga(x)As(1-y)P(t) that the 1D EEM increases with electron concentration per unit length and decreases with increasing film thickness respectively. For ternary and quaternary materials the EEM increases with increase in alloy composition. Under certain special conditions all the results for all the 1-D materials get simplified into the well known parabolic energy bands and thus confirming the compatibility test. The results of this paper find two applications in the fields of nanoscience and technology.

  14. Growth of ternary and quaternary cubic III-nitrides on 3C-SiC substrates

    Science.gov (United States)

    Schörmann, J.; Potthast, S.; Schnietz, M.; Li, S. F.; As, D. J.; Lischka, K.

    2006-06-01

    Cubic GaN, AlxGa1-xN/GaN multiple quantum wells and quaternary AlxGayIn1-x-yN layers were grown by plasma assisted molecular beam epitaxy on 3C-SiC substrates. Using the intensity of a reflected high energy electron beam as a probe optimum growth conditions of c-III nitrides were found, when a 1 monolayer Ga coverage is formed at the growing surface. Clear RHEED oscillations during the initial growth of AlxGa1-xN/GaN quantum wells were observed. X-ray diffraction measurements of these quantum well structures show clear satellite peaks indicating smooth interfaces. Growth of quaternary AlxGayIn1-x-yN lattice matched to GaN were demonstrated.

  15. Synthesis and surface-active property of bis-quaternary ammonium-sodium sulfate Gemini surfactant

    Institute of Scientific and Technical Information of China (English)

    Zhao Qiuling; Gao Zhinong

    2006-01-01

    N,N-dimethyldodecylamine,hydrochloride and epichlorohydrin (molar ration is 2:1:1) were used to synthesize bis-quaternary ammonium Gemini surfactant with a hydroxyl in its spacer group by the one-pot method.This hydroxyl was sulfonated by chlorosulfonic acid and then neutralized to bis-quaternary ammonium-sodium sulfate zwitterionic Gemini surfactant.The yield of the final product was 78%,and the melting point was 231-233℃.Its structure was characterized by IR,1H-NMR,MS,and elemental analyses.The critical micelle concentration (cmc)and surface tension of the novel zwitterionic Gemini surfactant in aqueous solution at 15℃ are 7.2×10-5 mol/L and 34.5 mN/m,respectively.

  16. Paleomagnetic dating of tectonically influenced Plio-Quaternary fan-system deposits from the Apennines (Italy

    Directory of Open Access Journals (Sweden)

    Michele Saroli

    2015-03-01

    Full Text Available The Roveto Valley is a narrow, elongated, NW-trending depression filled with continental Plio-Quaternary deposits that outcrop at different topographic elevations. A morpho-lithostratigraphic succession of the continental deposits has been defined in order to reconstruct the geological Quaternary evolution of the area. These deposits do not contain materials suitable for biostratigraphic dating; therefore, in order to determine their chronology, three different units were sampled for magnetostratigraphic investigations. Paleomagnetic results demonstrated that standard demagnetization techniques are effective in removing secondary remanence components and in isolating the characteristic remanent magnetization, allowing us to determine, for each cycle, whether it was deposited before or after the Brunhes-Matuyama geomagnetic reversal at 781 ka. Preliminary rock magnetic analyses indicated that magnetite is the main magnetic carrier and that hematite, which gives the pink colour to the matrix, is in the superparamagnetic grain-size range and thus does not retain any paleomagnetic remanence.

  17. EVALUATION OF THE ANTIMICROBIAL EFFECTS OF NEW HETEROCYCLIC BIS-QUATERNARY AMMONIUM COMPOUNDS ON BIOFILMS

    Directory of Open Access Journals (Sweden)

    OANA E. CONSTANTIN

    2016-07-01

    Full Text Available Considering the well-known mechanism of adaptable resistance of microorganisms to chemical compounds through biofilms formation and the widespread use of N-heterocyclic quaternary ammonium salts (QAC as disinfectants, in this study we have evaluate the effect of 8 newly synthesized symmetrical and unsymmetrical diquaternary ammonium salts of 1,2-bis-(4-pyridil-ethane on bacterial biofilms produced by three different bacterial strains. The effect of the exposure to quaternary ammonium salts on biofilm communities was investigated within biofilms obtained in a conventional testing system, on stainless steel and glass surfaces. Differential plate counts were used to characterize the developed communities and the effects of QAC exposure and the results were correlated with epifluorescence microphotographs. The data obtained revealed a significant reduction of bacterial cells in the biofilms tested with 4-7 log CFU for all the QAC.

  18. Ion Mobility-Mass Spectrometry Differentiates Protein Quaternary Structures Formed in Solution and in Electrospray Droplets.

    Science.gov (United States)

    Han, Linjie; Ruotolo, Brandon T

    2015-07-01

    Electrospray ionization coupled to mass spectrometry is a key technology for determining the stoichiometries of multiprotein complexes. Despite highly accurate results for many assemblies, challenging samples can generate signals for artifact protein-protein binding born of the crowding forces present within drying electrospray droplets. Here, for the first time, we study the formation of preferred protein quaternary structures within such rapidly evaporating nanodroplets. We use ion mobility and tandem mass spectrometry to investigate glutamate dehydrogenase dodecamers and serum amyloid P decamers as a function of protein concentration, along with control experiments using carefully chosen protein analogues, to both establish the formation of operative mechanisms and assign the bimodal conformer populations observed. Further, we identify an unprecedented symmetric collision-induced dissociation pathway that we link directly to the quaternary structures of the precursor ions selected.

  19. New insights into the earliest Quaternary environments in the Central North Sea from 3D seismic

    Science.gov (United States)

    Lamb, Rachel; Huuse, Mads; Stewart, Margaret; Brocklehurst, Simon H.

    2014-05-01

    In the past the transition between an unconformable surface in the south to a conformable horizon towards the north has made identification and mapping the base-Quaternary in the central North Sea difficult (Sejrup et al 1991; Gatliff et al 1994). However recent integration of biostratigraphy, pollen analysis, paleomagnetism and amino acid analysis in the Dutch and Danish sectors (Rasmussen et al 2005; Kuhlmann et al 2006) has allowed greater confidence in the correlation to the region 3D seismic datasets and thus has allowed the base-Quaternary to be mapped across the entire basin. The base-Quaternary has been mapped using the PGS MegaSurvey dataset from wells in the Danish Sector along the initially unconformable horizon and down the delta front into the more conformable basin giving a high degree of confidence in the horizon pick. The revised base-Quaternary surface reaches a depth of 1248 ms TWT with an elongate basin shape which is significantly deeper than the traditionally mapped surface. Using RMS amplitudes and other seismic attributes the revised base-Quaternary has been investigated along the horizon and in time slice to interpret the environments of the earliest Quaternary prior to the onset of glaciation. Combined with analysis of aligned elongate furrows over 10 km long, 100 m wide and 100 m deep suggest a deep marine environment in an almost enclosed basin with persistent strong NW-SE bottom currents in the deepest parts. Pockmarks were formed by the escape of shallow gas on the sides of a small delta in the eastern part of the basin. The progradation of large deltas from both the north and south into the basin make up the majority of the deposition of sediment into the basin. Key Words: base-Quaternary; seismic interpretation; paleoenvironments References: Gatliff, R.W, Richards, P.C, Smith, K, Graham, C.C, McCormac, M, Smith, N.J.P, Long, D, Cameron, T.D.J, Evans, D, Stevenson, A.G, Bulat, J, Ritchie, J.D, (1994) 'United Kingdom offshore regional

  20. Quaternary geologic map of the Boston 4 degrees x 6 degrees quadrangle, United States and Canada

    Science.gov (United States)

    State compilations by Hartshorn, Joseph H.; Thompson, W.B.; Chapman, W.F.; Black, R.F.; Richmond, Gerald Martin; Grant, D.R.; Fullerton, David S.; edited and integrated by Richmond, Gerald Martin

    1991-01-01

    The Quaternary Geologic Map of the Boston 4 deg x 6 deg Quadrangle was mapped as part of the Quaternary Geologic Atlas of the United States. The atlas was begun as an effort to depict the areal distribution of surficial geologic deposits and other materials that accumulated or formed during the past 2+ million years, the period that includes all activities of the human species. These materials are at the surface of the earth. They make up the 'ground' on which we walk, the 'dirt' in which we dig foundations, and the 'soil' in which we grow crops. Most of our human activity is related in one way or another to these surface materials that are referred to collectively by many geologists as regolith, the mantle of fragmental and generally unconsolidated material that overlies the bedrock foundation of the continent. The maps were compiled at 1:1,000,000 scale.

  1. A Quaternary-Stage User Interest Model Based on User Browsing Behavior and Web Page Classification

    Institute of Scientific and Technical Information of China (English)

    Zongli Jiang; Hang Su

    2012-01-01

    The key to personalized search engine lies in user model. Traditional personalized model results in that the search results of secondary search are partial to the long-term interests, besides, forgetting to the long-term interests disenables effective recollection of user interests. This paper presents a quaternary-stage user interest model based on user browsing behavior and web page classification, which consults the principles of cache and recycle bin in operating system, by setting up an illuminating text-stage and a recycle bin interest-stage in front and rear of the traditional interest model respectively to constitute the quaternary-stage user interest model. The model can better reflect the user interests, by using an adaptive natural weight and its calculation method, and by efficiently integrating user browsing behavior and web document content.

  2. Design and analysis of carbon nanotube FET based quaternary full adders

    Institute of Scientific and Technical Information of China (English)

    Mohammad Hossein MOAIYERI; Shima SEDIGHIANI; Fazel SHARIFI; Keivan NAVI

    2016-01-01

    CMOS binary logic is limited by short channel effects, power density, and interconnection restrictions. The effective solution is non-silicon multiple-valued logic (MVL) computing. This study presents two high-performance quaternary full adder cells based on carbon nanotube field effect transistors (CNTFETs). The proposed designs use the unique properties of CNTFETs such as achieving a desired threshold voltage by adjusting the carbon nanotube diameters and having the same mobility as p-type and n-type devices. The proposed circuits were simulated under various test conditions using the Synopsys HSPICE simulator with the 32 nm Stanford comprehensive CNTFET model. The proposed designs have on average 32% lower delay, 68% average power, 83% energy consumption, and 77% static power compared to current state-of-the-art quaternary full adders. Simulation results indicated that the proposed designs are robust against process, voltage, and temperature variations, and are noise tolerant.

  3. Hydrolysed ginseng-saponin quaternary: a novel conditioning agent for hair care products.

    Science.gov (United States)

    Young-Dae, K; Chang-Kew, K; Chung-Nam, L; Byung-Jo, H

    1989-10-01

    Synopsis A new quaternary ammonium compound, hydrolysed ginseng-saponin quaternary (HGSQ), from Korean ginseng saponin and 2,3-epoxypropyltrimethyl ammonium chloride, has been developed as a conditioning agent for hair care products. This structure has a hydrophobic group from the aglycone of ginseng saponin which is biologically active and considered as the most important component of Korean ginseng. Its properties of surface tension, conductivity, critical micelle concentration (CMC), eye irritation, sorption onto hair, tensile strength for 20% extension and moisture retention effect were studied. Its cationic character allows the molecule to be more substantive than ginseng saponin. HGSQ had good physical properties and was safe enough as a cosmetic raw material. Also half-head tests of HGSQ-containing shampoo were carried out to evaluate the conditioning effects in shampoos. HGSQ showed good conditioning properties in a shampoo.

  4. Loess in China: A Good Archive of Climatic and Environmental Changes during the Quaternary

    Institute of Scientific and Technical Information of China (English)

    Wang Limeng; Lu Huayu

    2005-01-01

    @@ Quaternary scientists in China have significantly improved our knowledge of loess deposition as well as our understanding of paleoclimatic and paleoenvironmental changes over the past 2.5 million years. It is recognized that loess is of aeolian origin with loess forming dust continuously deposited. It is also believed that grain-size, magnetic susceptibility, carbon isotopes and fossil assemblages in loess deposits are good proxy indicators of paleomonsoon climate and paleovegetation changes over the past 2.5 million years. Chinese loess is regarded as one of the best terrestrial archives of climatic and environmental changes during the Quaternary.Further investigation of loess deposits and their records of climatic and environmental change aids understanding of climate change and gives scientific backing for the project of ecological and environmental restoration in northwest China.

  5. PREPARATION AND PHOTOSENSITIVITY OF WATER SOLUBLE PHENOLIC RESINS CONTAINING ACRYLOYL AND QUATERNARY AMMONIUM CHLORIDE GROUPS

    Institute of Scientific and Technical Information of China (English)

    Xiao-ming Tan; Hong-quan Xie; Nai-yu Huang

    2002-01-01

    New water soluble and photocrosslinkable prepolymers containing acrylate and quaternary ammonium salt groups were synthesized from epoxy phenolic resin via ring-opening reaction with acrylic acid and with aqueous solution of triethylamine hydrochloride successively. The second reaction needs no phase transfer catalyst to accelerate, since the product formed can act as a phase transfer catalyst. The prepolymer obtained contains both photocrosslinkable acrylate groups and hydrophilic quaternary ammonium salt groups. Optimum conditions for these reactions were studied. The photosensitivity of the prepolymer was also investigated. The effects of different photoinitiators, different crosslinkable diluent monomers and amine accelerator on the photosensitivity of the prepolymer were compared. The photoinitiator of hydrogen abstraction type is still effective without using amine or alcohol as accelerator, because the prepolymer contains α H beside the OH groups formed in the ring-opening reactions.

  6. Two Classes of Bacterial IMPDHs according to Their Quaternary Structures and Catalytic Properties

    Science.gov (United States)

    Alexandre, Thomas; Rayna, Bertrand; Munier-Lehmann, Hélène

    2015-01-01

    Inosine-5′-monophosphate dehydrogenase (IMPDH) occupies a key position in purine nucleotide metabolism. In this study, we have performed the biochemical and physico-chemical characterization of eight bacterial IMPDHs, among which six were totally unexplored. This study led to a classification of bacterial IMPDHs according to the regulation of their catalytic properties and their quaternary structures. Class I IMPDHs are cooperative enzymes for IMP, which are activated by MgATP and are octameric in all tested conditions. On the other hand, class II IMPDHs behave as Michaelis-Menten enzymes for both substrates and are tetramers in their apo state or in the presence of IMP, which are shifted to octamers in the presence of NAD or MgATP. Our work provides new insights into the IMPDH functional regulation and a model for the quaternary structure modulation is proposed. PMID:25706619

  7. Enantioselective construction of quaternary N-heterocycles by palladium-catalysed decarboxylative allylic alkylation of lactams

    KAUST Repository

    Behenna, Douglas C.

    2011-12-18

    The enantioselective synthesis of nitrogen-containing heterocycles (N-heterocycles) represents a substantial chemical research effort and resonates across numerous disciplines, including the total synthesis of natural products and medicinal chemistry. In this Article, we describe the highly enantioselective palladium-catalysed decarboxylative allylic alkylation of readily available lactams to form 3,3-disubstituted pyrrolidinones, piperidinones, caprolactams and structurally related lactams. Given the prevalence of quaternary N-heterocycles in biologically active alkaloids and pharmaceutical agents, we envisage that our method will provide a synthetic entry into the de novo asymmetric synthesis of such structures. As an entry for these investigations we demonstrate how the described catalysis affords enantiopure quaternary lactams that intercept synthetic intermediates previously used in the synthesis of the Aspidosperma alkaloids quebrachamine and rhazinilam, but that were previously only available by chiral auxiliary approaches or as racemic mixtures. © 2012 Macmillan Publishers Limited. All rights reserved.

  8. β-CD assisted dissolution of quaternary ammonium permanganates in aqueous medium.

    Science.gov (United States)

    Bank, Suraj Prakash; Guru, Partha Sarathi; Dash, Sukalyan

    2014-10-13

    The non-polar internal cavity of β-cyclodextrin (β-CD) has been exploited for the entrapment of the hydrophobic tails of two water insoluble quaternary ammonium permanganates (QAPs): cetyltrimethylammonium permanganate (CTAP) and tetrabutylammonium permanganate (TBAP), for solubilization in aqueous medium. The solubilization and organizational behavior of the QAPs in aqueous β-CD solution have been determined from the comparison of their rates of self-oxidation in presence and in absence of β-CD. Effect of QAP concentration on their observed rate constants (k(obs)) at a fixed β-CD concentration, phase solubility analysis in varying β-CD concentration, impact of quaternary ammonium bromides (QABs) on the kobs values of CTAP and TBAP at fixed QAP and β-CD concentrations, and the temperature effect have been reported. A scheme to explain the solvation of QAPs in aqueous β-CD has been proposed based on dynamic light scattering (DLS) analysis of the samples.

  9. Mechanisms of flotation separation of diaspore and kaolinite by quaternary ammonium salt DTAL

    Institute of Scientific and Technical Information of China (English)

    陈湘清; 胡岳华; 王毓华

    2004-01-01

    The FTIR spectroscopy indicates that the adsorption of quaternary ammonium salt DTAL on the diaspore and kaolinite is physical adsorption. The adsorption of cationic surfactants measured by two-phase titration shows that the adsorption on the kaolinite is notably more than that on diaspore. The adsorption isotherm on kaolinte is linear while that of DTAL on diaspore is two-step flat form. The analysis on the cationic ions of kaolinite supernatants shows that kaolinite releases plenty of crystalloid structure ions which countervail the crystalloid charge because of the adsorption of the cationic surfactant. The mechanisms of the quaternary ammonium salt DTAL on flotation separation of diaspore and kaolinite include ion exchange interaction as well as electrostatic force.

  10. Thermoelectric properties of quaternary (Bi,Sb){sub 2}(Te,Se){sub 3} compound

    Energy Technology Data Exchange (ETDEWEB)

    Lu, Pengfei, E-mail: photon.bupt@gmail.com [State Key Laboratory of Information Photonics and Optical Communications, Ministry of Education, Beijing University of Posts and Telecommunications, P.O. Box 72, Beijing 100876 (China); Li, Yiluan; Wu, Chengjie; Yu, Zhongyuan; Cao, Huawei; Zhang, Xianlong; Cai, Ningning; Zhong, Xuxia [State Key Laboratory of Information Photonics and Optical Communications, Ministry of Education, Beijing University of Posts and Telecommunications, P.O. Box 72, Beijing 100876 (China); Wang, Shumin [State Key Laboratory of Functional Materials for Informatics, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200050 (China); Photonics Laboratory, Department of Microtechnology and Nanoscience, Chalmers University of Technology, 41296 Gothenburg (Sweden)

    2014-01-25

    Highlights: • Sb and Se spin–orbit coupling play a key role in the band structure. • Substituted Bi/Sb and Te/Se have a limited impact on the transport coefficients. • n-Type doping will be preferred for quaternary (Bi,Sb){sub 2}(Te,Se){sub 3} compound. -- Abstract: The quaternary (Bi,Sb){sub 2}(Te,Se){sub 3} compounds are investigated using first-principles study and Boltzmann transport theory. The energy band structure and density of states are studied in detail. The electronic transport coefficients are then calculated as a function of chemical potential. The figure of merit ZT is obtained assuming a constant relaxation time and an averaged thermal conductivity. Our theoretical result agrees well with previous experimental data.

  11. Late Quaternary transgressive large dunes on the sediment-starved Adriatic shelf

    Science.gov (United States)

    Correggiari, A.; Field, M.E.; Trincardi, F.

    1996-01-01

    The Adriatic epicontinental basin is a low-gradient shelf where the late-Quaternary transgressive systems tract (TST) is composed of thin parasequences of backbarrier, shoreface and offshore deposits. The facies and internal architecture of the late-Quaternary TST in the Adriatic epicontinental basin changed consistently from early transgression to late transgression reflecting: (1) fluctuations in the balance between sediment supply and accommodation increase, and (2) a progressive intensification of the oceanographic regime, driven by the transgressive widening of the basin to as much as seven times its lowstand extent. One of the consequences of this trend is that high-energy marine bedforms such as sand ridges and sand waves characterize only areas that were flooded close to the end of the late-Quaternary sea-level rise, when the wind fetch was maximum and bigger waves and stronger storm currents could form. We studied the morphology, sediment composition and sequence-stratigraphical setting of a field of asymmetric bedforms (typically 3 m high and 600 m in wavelength) in 20-24 m water depth offshore the Venice Lagoon in the sediment-starved North Adriatic shelf. The sand that forms these large dunes derived from a drowned transgressive coastal deposit reworked by marine processes. Early cementation took place over most of the dune crests limiting their activity and preventing their destruction. Both the formation and deactivation of this field of sand dunes occurred over a short time interval close to the turn-around point that separates the late-Quaternary sea-level rise and the following highstand and reflect rapid changes in the oceanographic regime of the basin.

  12. Synthesis and Characterization of Novel Ternary and Quaternary Alkali Metal Thiophosphates

    KAUST Repository

    Alahmary, Fatimah S.

    2014-05-01

    The ongoing development of nonlinear optical (NLO) crystals such as coherent mid-IR sources focuses on various classes of materials such as ternary and quaternary metal chalcophosphates. In case of thiophosphates, the connection between PS4-tetrahedral building blocks and metals gives rise to a broad structural variety where approximately one third of all known ternary (A/P/S) and quaternary (A/M/P/S) (A = alkali metal, M = metal) structures are acentric and potential nonlinear optical materials. The molten alkali metal polychalcophosphate fluxes are a well-established method for the synthesis of new ternary and quaternary thiophosphate and selenophosphate compounds. It has been a wide field of study and investigation through the last two decades. Here, the flux method is used for the synthesis of new quaternary phases containing Rb, Ag, P and S. Four new alkali metal thiophosphates, Rb4P2S10, RbAg5(PS4), Rb2AgPS4 and Rb3Ag9(PS4)4, have been synthesized successfully from high purity elements and binary starting materials. The new compounds were characterized by single crystal and powder X-ray diffraction, scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), ultraviolet-visible (UV-VIS), Raman spectroscopy, thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). These compounds show interesting structural variety and physical properties. The crystal structures feature 3D anionic framework built up of PS4 tetrahedral units and charge balanced by Ag and alkali metal cations. All prepared compounds are semiconductors with band gap between 2.3 eV to 2.6 eV and most of them are thermally stable up to 600ºC.

  13. Effect of quaternary ammonium salts in the process of extracting oil filled rubber from latex

    Directory of Open Access Journals (Sweden)

    N. S. Nikulina

    2016-01-01

    Full Text Available Currently, much attention is paid to the improvement of production technology of synthetic rubber. Much attention is given to rubber is produced by emulsion polymerization. This is due to the fact that rubbers produced by emulsion polymerization have a number of positive characteristics, and are widely used in the tire and rubber industry, in composite formulations for various purposes. In recent years, the technology of production of synthetic rubbers are widely used quaternary ammonium salts which are produced on an industrial scale. Application low and high molecular weight quaternary ammonium salts to reduce pollution of environ-mental protection, exclude the use of mineral salts without significant changes in the process flowsheet. It is found that quaternary ammonium salts react with the components of the emulsion system to form insoluble complexes, which are captured produced rubber crumb. However, Applications, quaternary salts in the manufacture of oil-filled rubber in the literature sources have not been given due attention. The study presents the results of research on the effect of the concentration of a coagulating agent, tempera tours and concentration of the dispersed phase in the process of coagulation of latex in the preparation of oil-filled rubber stamps SCS-30 ARKM-15. The concentration of the coagulating agent does not significantly affect the process of separation of the rubber from the latex. The process of isolation rubber latex is advantageously carried out at a reduced temperature. The concentration of the dispersed phase also provides material effect on the coagulation process. The lead researches mouthestablished that produced rubber, rubber compounds and vulcanizates based on these indicators correspond to their requirements.

  14. Late Quaternary glaciation of the Upper Soca River Region (Southern Julian Alps, NW Slovenia)

    Science.gov (United States)

    Bavec, Milos; Tulaczyk, Slawek M.; Mahan, Shannon; Stock, Gregory M.

    2004-01-01

    Extent of Late Quaternary glaciers in the Upper Soc??a River Region (Southern Julian Alps, SE Europe) has been analyzed using a combination of geological mapping, glaciological modeling, and sediment dating (radiocarbon, U/Th series and Infrared Stimulated Luminescence-IRSL). Field investigations focused mainly on relatively well preserved Quaternary sequences in the Bovec Basin, an intramontane basin located SW of the Mediterranean/Black Sea divide and surrounded by mountain peaks reaching from approximately 2100 up to 2587 m a.s.l. Within the Basin we recognized two Late Quaternary sedimentary assemblages, which consist of the same facies association of diamictons, laminated lacustrine deposits and sorted fluvial sediments. Radiocarbon dating of the upper part of the lake sediments sequence (between 12790??85 and 5885??60 14C years b.p.) indicates that the younger sedimentary assemblage was deposited during the last glacial maximum and through early Holocene (Marine Isotope Stage 21, MIS 2-1). Sediment ages obtained for the older assemblage with U/Th and IRSL techniques (between 154.74??22.88 and 129.93??7.90 ka b.p. for selected samples) have large errors but both methods yield results consistent with deposition during the penultimate glacial-interglacial transition (MIS 6-5). Based on analyses of field data combined with glaciological modeling, we argue that both sediment complexes formed due to high sediment productivity spurred by paraglacial conditions with glaciers present in the uplands around the Bovec Basin but not extending down to the basin floor. Our study shows that the extent and intensity of direct glacial sedimentation by Late Quaternary glaciers in the region was previously significantly overestimated. ?? 2004 Elsevier B.V. All rights reserved.

  15. Geological and geomorphological evolution of a sedimentary periglacial landscape in Northeast Siberia during the Late Quaternary

    OpenAIRE

    2007-01-01

    A wide variety of environmental records is necessary for analysing and understanding the complex Late Quaternary dynamics of permafrost-dominated Arctic landscapes. A NE Siberian periglacial key region was studied in detail using sediment records, remote sensing data, and terrain modelling, all incorporated in a geographical information system (GIS). The study area consists of the Bykovsky Peninsula and the adjacent Khorogor Valley in the Kharaulakh Ridge situated a few kilometres southeast o...

  16. InGaAsP Quaternary Materials for Near Infrared Detector and Laser Applications

    Science.gov (United States)

    1980-06-01

    Japanese Journal of Applied Physics , vol. 19, pp. L17-L20, January 1980. 52. H. Kaube, Y. Yamaucbi and N. Susa...Sugiyama, H. Kojima, H. Enda, and M. Shibata, "Vapor Phase Epitaxial Growth and Characterization of Gal-ylnyAsl-xPx Quaternary Alloys," Japanese Journal of Applied Physics , vol...34 Japanese Journal of Applied Physics , vol. 18, pp. 2167-2168, 1979. 59. G. H. Olsen and T. J. Zamerowski, *Crystal Growth

  17. Polyamide 6 Nanocomposites with Inorganic Particles Modified with Three Quaternary Ammonium Salts

    Directory of Open Access Journals (Sweden)

    Hélio de Lucena Lira

    2011-11-01

    Full Text Available The purpose of this study was to obtain polyamide 6 nanocomposites with national organically modified clay with three quaternary ammonium salts. The obtained results confirm the intercalation of molecules of salt in the clay layers, and a good interaction with the polymer, showing the formation of intercalated and/or partially exfoliated structures. The nanocomposites showed similar thermal stability compared to pure polymer, and the mechanical properties presented interesting and promising results.

  18. The grain-size characteristics of Quaternary deposits at Xingshan near Siping in Jilin province, China

    Institute of Scientific and Technical Information of China (English)

    Maxwell A Boateng; Xikui Wang

    2006-01-01

    This research paper analyses the grain-size characteristics of the Quaternary deposits at Xingshan near Siping, Jilin province in China by employing graphic measures to study the grain size distribution and its mode of transport and deposition. The Quaternary deposits at Xingshan lie unconformable on Cretaceous rocks made of siltstone, mudstone and sandstone. The average grain size is between 8.06 to 8.55Φ (0.002 6 ~0.003 7 mm). The Quaternary deposits at Xingshan mainly compose of very fine silt to clay. The compositions of the grade are clay 63% and silt 37%. The clay size components are weathered debris transported and deposited by flowing water from the SE highlands or hills to the low lying NW Xingshan plains whereas the silty components accumulated by aoelian process. The Quaternary deposits at Xingshan accumulated in the middle and late Pleistocene interglacial periods from (459.12~39.03) ka to (88.92~7.56) ka. The standard deviation ranged from 0.96 to 1.36Φ, indicating that the sediments are moderately to poorly sorted, Coefficient of skewness ranged from 0.16~0.31 with an average skewness of 0.218, (Positively skewed towards fine). Kurtosis values (0.84~1.05) from the grain size distribution and visual inspection of the frequency curves indicate platykurtic to mesokurtic curves and unimodal to bimodal grain-size distribution. The type of deposit formation is sand dune and the source is at a distal from its provenance.

  19. Quantitative analysis of deuterium using the isotopic effect on quaternary {sup 13}C NMR chemical shifts

    Energy Technology Data Exchange (ETDEWEB)

    Darwish, Tamim A., E-mail: tamim.darwish@ansto.gov.au [National Deuteration Facility, Australian Nuclear Science and Technology Organisation, Locked Bag 21, Kirrawee DC, NSW 2232 (Australia); Yepuri, Nageshwar Rao; Holden, Peter J. [National Deuteration Facility, Australian Nuclear Science and Technology Organisation, Locked Bag 21, Kirrawee DC, NSW 2232 (Australia); James, Michael [Australian Synchrotron, 800 Blackburn Road, Clayton, Victoria 3168 (Australia)

    2016-07-13

    Quantitative analysis of specifically deuterated compounds can be achieved by a number of conventional methods, such as mass spectroscopy, or by quantifying the residual {sup 1}H NMR signals compared to signals from internal standards. However, site specific quantification using these methods becomes challenging when dealing with non-specifically or randomly deuterated compounds that are produced by metal catalyzed hydrothermal reactions in D{sub 2}O, one of the most convenient deuteration methods. In this study, deuterium-induced NMR isotope shifts of quaternary {sup 13}C resonances neighboring deuterated sites have been utilized to quantify the degree of isotope labeling of molecular sites in non-specifically deuterated molecules. By probing {sup 13}C NMR signals while decoupling both proton and deuterium nuclei, it is possible to resolve {sup 13}C resonances of the different isotopologues based on the isotopic shifts and the degree of deuteration of the carbon atoms. We demonstrate that in different isotopologues, the same quaternary carbon, neighboring partially deuterated carbon atoms, are affected to an equal extent by relaxation. Decoupling both nuclei ({sup 1}H, {sup 2}H) resolves closely separated quaternary {sup 13}C signals of the different isotopologues, and allows their accurate integration and quantification under short relaxation delays (D1 = 1 s) and hence fast accumulative spectral acquisition. We have performed a number of approaches to quantify the deuterium content at different specific sites to demonstrate a convenient and generic analysis method for use in randomly deuterated molecules, or in cases of specifically deuterated molecules where back-exchange processes may take place during work up. - Graphical abstract: The relative intensities of quaternary {sup 13}C {"1H,"2H} resonances are equal despite the different relaxation delays, allowing the relative abundance of the different deuterated isotopologues to be calculated using NMR fast

  20. Late Quaternary stratigraphic development in the lower Luni, Mahi and Sabarmati river basins, western India

    Indian Academy of Sciences (India)

    M Jain; S K Tandon; S C Bhatt

    2004-09-01

    This study reviews the Quaternary alluvial stratigraphy in three semi-arid river basins of western India i.e., lower Luni (Rajasthan), and Mahi and Sabarmati (Gujarat alluvial plains). On the basis of OSL chronologies, it is shown that the existing intra-valley lithostratigraphic correlations require a revision. The sand, gravel and mud facies are present during various times in the three basins, however, the fluvial response to climate change, and the resulting facies associations, was different in the Thar desert as compared to that at the desert margin; this makes purely lithostratigraphic correlations unviable. It is further shown that the rivers in the Thar desert were more sensitive to climate change and had small response times and geomorphic thresholds as compared to the desert-margin rivers. This is illustrated during the early OIS 1, when the Luni river in the Thar desert was dynamic and showed frequent variations in fluvial styles such as gravel bedload braided streams, sand-bed ephemeral streams and meandering streams, all followed by incision during the early Holocene. The coeval deposits in Sabarmati, however, only show a meandering, floodplain-dominated river. Late Quaternary alluvial deposits in these basins unconformably overlie some older deposits that lack any absolute chronology. Based on the facies types and their associations, and the composition and architecture of the multistoried gravel sheets in the studied sections, it is suggested that older deposits are of pre-Quaternary age. This hypothesis implies the presence of a large hiatus incorporating much of the Quaternary period in the exposed sections.

  1. Extraction of metals from metal ion-catechol-quaternary base systems.

    Science.gov (United States)

    Vrchlabský, M; Sommer, L

    1968-09-01

    Methods are given for the extraction of iron(III), molybdenum(VI), titanium(IV), niobium(V), vanadium(IV), uranium(VI) and tungsten(VI) as ternary complexes with catechol and a quaternary cation such as n-butyltriphenylphosphonium, n-propyltriphenylphosphonium, tetraphenylarsonium, cetylpyridinium, cetyltrimethylammonium and 2,3,5-triphenyltetrazolium, the solvent being chloroform. By use of masking agents and pH control, some of these elements can be separated from each other by this means.

  2. Human Dispersals Along the African Rift Valley in the Late Quaternary

    Science.gov (United States)

    Tryon, C. A.; Faith, J. T.; Peppe, D. J.

    2014-12-01

    Climate- and tectonic-driven environmental dynamics of the East African Rift System (EARS) during the Quaternary played an important role in the demographic history of early Homo sapiens, including expansions of modern humans across and out of Africa. Human forager population size, geographic range, and behaviors such as hunting strategies and residential mobility likely varied in response to changes in the local and regional environment. Throughout the Quaternary, floral and faunal change was linked at least in part to variations in moisture availability, temperature, and atmospheric CO2, which in addition to uplift and faulting, contributed to the expansion and contraction of a number of large lakes that served as biogeographic barriers to many taxa. This is particularly clear for the Lake Victoria basin, where biogeographic, geological, and paleontological evidence documents repeated expansion and contraction of the ranges of species in response to lake level and vegetation change. Across much of eastern Africa, the topography of the rift facilitated north-south dispersals, the timing of which may have depended in part on the expansion and contraction of the equatorial forest belt. Dispersal potential likely increased during the more arid periods of the late Quaternary, when the roles of lakes and forests as dispersal barriers was reduced and the extent of low net primary productivity dry grasslands increased, the latter requiring large home ranges for human foragers, conditions suitable for range expansions within H. sapiens.

  3. Flotation and adsorption of quaternary ammonium salts collectors on kaolinite of different particle size

    Institute of Scientific and Technical Information of China (English)

    Jiang Hao; Liu Guorong; Hu Yuehua; Xu Longhua; Yu Yawen; Xie Zhen; Chen Haochuan

    2013-01-01

    The flotation behaviors of decyltrimethylammonium (103C),dodecyltrimethylammonium chloride (DTAC),tetradecyltrimethylammonium chloride (TTAC) and cetyltrimethylammonium chloride (CTAC) on kaolinite of different particle size fraction were studied.The adsorbed amount and adsorption isotherms of collectors on kaolinite were determined for painstaking investigation into the adsorption of quaternary amines at kaolinite-water interface by ultraviolet spectrophotometer methods.The flotation results show that the flotation recovery of kaolinite of different particle fraction increases with an increase in pH when 103C,DTAC,TrAC and CTAC are used as collectors.As the concentration of collectors increases,the flotation recovery increases.Particle size of kaolinite has a strong effect on flotation.The flotation recovery of fine kaolinite decreases with the carbon chain of quaternary ammonium salts collectors increasing,while coarse kaolinite is on the contrary.The adsorbed amount tests and adsorption isotherms show that adsorbed amount increases when the particle size of kaolinite increases or when the carbon chain length of quaternary ammonium salts increases.Within the range of flotation collector concentration,the longer the hydrocarbon chain,the more probable to be absolutely adsorbed by fine kaolinite particles and then the lower the collector concentration in the bulk,which leds to lower flotation recovery.

  4. Primary solidification phases of the Sn-rich Sn-Ag-Cu-Ni quaternary system

    Science.gov (United States)

    Chang, Cheng-An; Chen, Sinn-Wen; Chiu, Chen-Nan; Huang, Yu-Chih

    2005-08-01

    The eutectic and near-eutectic Sn-Ag-Cu solders are the most promising lead-free solders, and nickel is frequently used as the barrier layer material. Nickel dissolves into the molten Sn-Ag-Ni alloy during the soldering process, and the ternary solder becomes a Sn-Ag-Cu-Ni quaternary melt near the nickel substrate. Liquidus projection is the projection of the liquidus trough and it delineates the boundaries of various primary solidification phases. Information of liquidus projection is helpful for understanding the alloys’ solidification behavior. This study prepared the Sn-Ag-Cu-Ni alloys of various compositions at the Sn-rich corner. The alloys were melted at higher temperatures and solidified in air. The solidified alloys were metallographically examined to determine the phases formed, especially the primary solidification phases. No ternary or quaternary compounds were found. The knowledge of the primary solidification phases, phase formation sequences, and reaction temperatures determined in this study were put together with all of the available liquidus projections of the constituent ternary systems to determine the primary solidification phases of the quaternary Sn-Ag-Cu-Ni system at the Sn-rich corner.

  5. Quaternary Geology and Geomorphology of Terna River Basin in West Central India

    Directory of Open Access Journals (Sweden)

    Mohammad Babar

    2012-12-01

    Full Text Available This paper presents the morphostratigraphy, lithostratigraphy and sedimentary structures of Terna River basin in the Deccan Basaltic Province (DBP of West Central India. These Quaternary deposits have been divided into three informal formations (i dark grey silt formation – Late Holocene, (ii Light grey silt formations – Early Holocene, (iii Dark grayish brown silt formation – Late Pleistocene with the older Quaternary Alluvial deposits of Upper Pleistocene age. The fine clay and silt formations in the lower reaches reflect that the streams are of low gradient and more sinuous. The river shows evidences of channel movement by avulsion, largely controlled by lineaments. Palaeo-levees, in the form 4–5 m high ridges exist along the Terna River floodplain, specifically in the Ter, Killari, Sastur, Dhuta and Makni villages. Several lineaments occur along NE-SW, NW-SE, E-W and WNW-ESE directions, which control the basement structure in the study area. The values of the Topographic Sinuosity Index (TSI indicate rejuvenation of the area leading to the dominance of topography on the sinuosity of the river channels. The break in slope in the long profile is also indication of the Quaternary tectonic uplift of the area. Radiocarbon dating of some charcoal fragments collected from folded beddings indicates that paleoseismic activity might have taken place along the basin between AD 120 and AD 1671.

  6. Quaternary fluvial response to climate change in glacially influenced river systems

    Science.gov (United States)

    Cordier, Stéphane; Adamson, Kathryn; Delmas, Magali; Calvet, Marc; Harmand, Dominique

    2016-04-01

    Over the last few decades, many studies in Europe and other continents have focused on the fluvial response to climate forcing in unglaciated basins. However, glacial activity may have a profound impact on the behaviour of the fluvial systems located downstream. In comparison to ice-free basins, these systems are characterised by distinctive hydrological and sediment supply regimes. Over Quaternary timescales, the fluvial records are influenced by periglacial (in non-glaciated areas), proglacial, and paraglacial processes. Understanding the impacts of these processes on the formation and preservation of the Quaternary geomorphological and sedimentary archives is key for our understanding of glacial-fluvial interactions. We investigate the impact of Quaternary glacial activity on fluvial sediment transfer, deposition, and preservation. Using existing studies from across Europe, we create a database of glaciofluvial geomorphology, sedimentology, and geochronology. This is used to examine how glacial forcing of fluvial systems varies spatially in different basin settings, and temporally over successive Milankovitch cycles. In particular, we focus on the ways in which the primary glacial-fluvial depositional signal could be distinguished from periglacial and paraglacial reworking and redeposition.

  7. Hydrolysis of cellulose catalyzed by quaternary ammonium perrhenates in 1-allyl-3-methylimidazolium chloride.

    Science.gov (United States)

    Wang, Jingyun; Zhou, Mingdong; Yuan, Yuguo; Zhang, Quan; Fang, Xiangchen; Zang, Shuliang

    2015-12-01

    Quaternary ammonium perrhenates were applied as catalyst to promote the hydrolysis of cellulose in 1-allyl-3-methylimidazolium chloride ([Amim]Cl). The quaternary ammonium perrhenates displayed good catalytic performance for cellulose hydrolysis. Water was also proven to be effective to promote cellulose hydrolysis. Accordingly, 97% of total reduced sugar (TRS) and 42% of glucose yields could be obtained under the condition of using 5mol% of tetramethyl ammonium perrhenate as catalyst, 70μL of water, ca. 0.6mmol of microcrystalline cellulose (MCC) and 2.0g of [Amim]Cl as solvent under microwave irradiation for 30min at 150°C (optimal conditions). The influence of quaternary ammonium cation on the efficiency of cellulose hydrolysis was examined based on different cation structures of perrhenates. The mechanism on perrhenate catalyzed cellulose hydrolysis is also discussed, whereas hydrogen bonding between ReO4 anion and hydroxyl groups of cellulose is assumed to be the key step for depolymerization of cellulose.

  8. Quaternary polymethacrylate-magnesium aluminum silicate films: molecular interactions, mechanical properties and tackiness.

    Science.gov (United States)

    Rongthong, Thitiphorn; Sungthongjeen, Srisagul; Siepmann, Juergen; Pongjanyakul, Thaned

    2013-12-15

    The aim of this study was to investigate the impact of the addition of magnesium aluminum silicate (MAS), a natural clay, on the properties of polymeric films based on quaternary polymethacrylates (QPMs). Two commercially available aqueous QPM dispersions were studied: Eudragit(®) RS 30D and Eudragit(®) RL 30D (the dry copolymers containing 5 and 10% quaternary ammonium groups, respectively). The composite QPM-MAS films were prepared by casting. Importantly, QPM interacted with MAS and formed small flocculates prior to film formation. Continuous films were obtained up to MAS contents of 19% (referred to the QPM dry mass). ATR-FTIR and PXRD revealed that the positively charged quaternary ammonium groups of QPM interacted with negatively charged SiO(-) groups of MAS, creating nanocomposite materials. This interaction led to improved thermal stability of the composite films. The puncture strength and elongation at break of dry systems decreased with increasing MAS content. In contrast, the puncture strength of the wet QPM-MAS films (upon exposure to acidic or neutral media) increased with increasing MAS content. Furthermore, incorporation of MAS into QPM films significantly decreased the latter's tackiness in the dry and wet state. These findings suggest that nanocomposite formation between QPM and MAS in the systems can enhance the strength of wet films and decrease their tackiness. Thus, MAS offers an interesting potential as novel anti-tacking agent for QPM coatings.

  9. A study of the formation constants of ternary and quaternary complexes of some bivalent transition metals

    Directory of Open Access Journals (Sweden)

    MADHURJYA NEOG

    2010-01-01

    Full Text Available The formation of hetero-ligand 1:1:1, M(II-Opda-Sal/Gly ternary and 1:1:1:1, M(II-Opda-Sal-Gly quaternary complexes, where M(II = Ni, Cu, Zn and Cd; Opda = o‑phenylenediamine, Sal = salicylic acid, Gly = glycine, was studied pH-metrically in aqueous medium. The formation constants for the resulting ternary and quaternary complexes were evaluated at a constant ionic strength, μ = 0.20 mol dm-3 and temperature, 30±0.1 °C. The order of the formation constants in terms of the metal ion for both type of complexes was found to be Cu(II > Ni(II > Zn(II > Cd(II. This order was explained based on the increasing number of fused rings, the coordination number of the metal ions, the Irving – William order and the stability of various species. The expected species formed in solution were pruned with the Fortran IV program SPEPLOT and the stability of the ternary and quaternary complexes is explained.

  10. Paleoenvironmental changes during the late Quaternary as inferred from foraminifera assemblages in the Laizhou Bay

    Institute of Scientific and Technical Information of China (English)

    YAO Jing; YU Hongjun; XU Xingyong; YI Liang; CHEN Guangquan; SU Qiao

    2014-01-01

    Controlled by climate changes, there were three large-scale transgressions and regressions around the Bohai Sea during the late Quaternary, which were accepted by most geologists. However, a big controversy still exists about the time when the transgressions occurred separately. In order to find out the process of the paleoenvironmental changes around the Bohai Sea in the late Quaternary, the foraminifera assemblages from a new borehole Lz908 in the southern coast of the Laizhou Bay were studied, and then the transgressive strata were indentified. Combined with accelerator mass spectrometry radiocarbon 14C (AMS14C) and opti-cally stimulated luminescence (OSL) ages, the occurrence time of these transgressions were re-determined. The result showed that three major large-scale transgressions occurred separately at the beginning of ma-rine isotopic stage 7 (MIS7), the last interglacial period (MIS5) and the Holocene. In addition, a small-scale transgression occurred in the mid-MIS6, and the corresponding transgressive stratum was deposited. The transgressive deposition of MIS3 was also discovered in this study. However, the characteristics of the fora-minifera indicated the environment during this period was colder than that in the MIS5. By comparison with the global sea-level changes, the paleoenvironmental changes around the Bohai Sea in the late Quaternary can be consistent with the global climate changes.

  11. Characterisation of quaternary polymethacrylate films containing tartaric acid, metoprolol free base or metoprolol tartrate.

    Science.gov (United States)

    Glaessl, B; Siepmann, F; Tucker, I; Siepmann, J; Rades, T

    2009-11-01

    The aim of this study was to better understand the interactions between metoprolol tartrate and quaternary polymethacrylate (Eudragit RL and Eudragit RS) films. For reasons of comparison, polymeric films containing the free base metoprolol or free tartaric acid were also prepared. Systems containing various amounts of the free base, free acid and the salt were characterised using polarising light microscopy, X-ray powder diffraction, differential scanning calorimetry and mechanical analysis (puncture test). The free base is the most efficient plasticiser of the three species for Eudragit RL and Eudragit RS, but with limited solubility in the polymers. Due to its hydrophobicity, it can interact with the hydrophobic polymer backbones. In contrast, in salt containing films, ionic interactions between the positively charged quaternary ammonium groups and the negatively charged tartrate anions apparently occur, this being suggested by the different effects on Eudragit RL versus RS, which have different contents of quaternary ammonium groups. Importantly, the combination of acid and base as a salt avoids drug precipitation at higher metoprolol contents. The obtained new insight into the occurring drug-polymer interactions can help to facilitate the development/optimisation of this type of dosage forms.

  12. Monsoon triggered formation of Quaternary alluvial megafans in the interior of Oman

    Science.gov (United States)

    Blechschmidt, Ingo; Matter, Albert; Preusser, Frank; Rieke-Zapp, Dirk

    2009-09-01

    A vast bajada consisting of coalescing low-gradient (veneer of weakly cemented Quaternary gravels. A combination of remote sensing, lithological analyses and luminescence dating is used to interpret the complex aggradation history of the Quaternary alluvial fans from the interior of Oman in the context of independent regional climate records. From satellite imagery and clast analysis four fans can be discerned in the study area. While two early periods of fan formation are tentatively correlated to the Miocene-Pliocene and the Early Pleistocene, luminescence dating allows the distinction of five phases of fan aggradation during the Middle-Late Pleistocene. These phases are correlated with pluvial periods from Marine Isotope Stage (MIS) 11 through 3, when southern Arabia was affected by monsoonal precipitation. It is concluded that the aggradation of the alluvial fans was triggered by the interplay of increased sediment production during arid periods and high rainfall with enhanced erosion of hillslopes and transport rates during strong monsoon phases. However, the lack of fine-grained sediments, bioturbation and organic material implies that although the Quaternary fans are sourced by monsoonal rains they formed in a semi-arid environment. Thus, it appears that, in contrast to the Oman Mountains, the interior was not directly affected by monsoonal precipitation.

  13. Spontaneous quaternary and tertiary T-R transitions of human hemoglobin in molecular dynamics simulation.

    Directory of Open Access Journals (Sweden)

    Jochen S Hub

    2010-05-01

    Full Text Available We present molecular dynamics simulations of unliganded human hemoglobin (Hb A under physiological conditions, starting from the R, R2, and T state. The simulations were carried out with protonated and deprotonated HC3 histidines His(beta146, and they sum up to a total length of 5.6 micros. We observe spontaneous and reproducible T-->R quaternary transitions of the Hb tetramer and tertiary transitions of the alpha and beta subunits, as detected from principal component projections, from an RMSD measure, and from rigid body rotation analysis. The simulations reveal a marked asymmetry between the alpha and beta subunits. Using the mutual information as correlation measure, we find that the beta subunits are substantially more strongly linked to the quaternary transition than the alpha subunits. In addition, the tertiary populations of the alpha and beta subunits differ substantially, with the beta subunits showing a tendency towards R, and the alpha subunits showing a tendency towards T. Based on the simulation results, we present a transition pathway for coupled quaternary and tertiary transitions between the R and T conformations of Hb.

  14. Quaternary transgressive and regressive depositional sequences in the East China Sea

    Institute of Scientific and Technical Information of China (English)

    2003-01-01

    Based on the interpretation more than 4000 km sparker single channel seismic profiles and the comparison with Borehole DZQ4 on the outer shelf of the East China Sea (ECS), the seismic sequences, sedimentary facies and paleo-sedimentary environment are studied to establish the chronology framework and discuss the Quaternary transgressive and regressive sequences of the ECS shelf as well as their response to glacio-eustatic sea-level changes. The sea level of the ECS fluctuated with global climate changes in the Quaternary. During the sea level rise, the Pacific tidal wave impacted actively on the ECS continental shelf and the reciprocating tidal currents in NW-SE direction formed tidal sand ridges, which represent large transgressive deposits visible on the seismic profiles. In response to sea level fall, the Yangtze River deltas prograded seaward and built massive subaqueous deltas to form regressive sequences on the seismic profiles. Alternative transgression and regression sequences were vertically distributed on the ECS shelf with the frequent eustacy in the Quaternary. The gentle slope of the ECS shelf makes it possible for the coastline to migrate hundreds of kilometers forth and back on the shelf because of tens of meters sea level changes, in the meanwhile, the Yangtze River discharged large amounts of sediments into the ECS resulting in large-scale subaqueous deltas and tidal sand ridges. There have developed 3 stages of tidal sand ridges and 4 stages of deltas on the ECS shelf since oxygen isotope stage 8.

  15. Partial phase diagram of Pd-Ag-Ru-Gd quaternary system

    Institute of Scientific and Technical Information of China (English)

    2005-01-01

    On the basis of the Ag-Pd-Gd, Ag-Ru-Gd and Pd-Ru-Gd ternary systems, the partial phase diagram of Pd-Ag-Ru-Gd(Gd<25% atom fraction) quaternary system has been studied by means of X-ray diffraction analysis, differential thermal analysis, electron probe microanalysis and optical microscopy.The 700℃ isothermal sections of the Ag-Pd-5Ru-Gd, Ag-Pd-20Ru-Gd and Ag-Pd-50Ru-Gd (Gd≤25%atom fraction) phase diagrams were determined respectively. And the 700℃ isothermal section of the PdAg-Ru-Gd (Gd≤25% atom fraction) quaternary system phase diagram was finally irferred. The section consists of four single-phase regions: solid solution Pd(Ag), (Ru), Pd3Gd and Ag51 Gd14; five two-phase regions: Pd(Ag) + (Ru), Pd(Ag) + Ag51 Gd14 , (Ru) + Ag51 Gd14 , Pd(Ag) + Pd3Gd and (Ru) +Pd3Gd; three three-phase regions: Pd(Ag) + Pd3Gd+ (Ru), Pd(Ag) + Ag51Gd14 + (Ru) and (Ru) +Ag51Gd14 + Pd3Gd; one four-phase region Pd(Ag) + (Ru) + Ag51Gd14 + Pd3Gd. No new quaternary intermetallic phase is found.

  16. Quaternary nanofossils on the Brazilian continental shelf; Nanofosseis calcarios do quaternario da margem continental brasileira

    Energy Technology Data Exchange (ETDEWEB)

    Antunes, Rogerio Loureiro [PETROBRAS S.A., Rio de Janeiro, RJ (Brazil). Centro de Pesquisas (CENPES). Gerencia de Bioestratigrafia e Paleoecologia], E-mail: rlantunes@petrobras.com.br

    2007-07-01

    The study of calcareous nanofossils occurring in the deposits on the Brazilian continental margin began in the late 1960s, undertaken solely by PETROBRAS. Instead of presenting an academic outlook, the purpose of these investigations is first to formulate a biostratigraphic framework to apply to oil well samples. The initial result was the first zoning for the Brazilian continental margin, which considered the deposits formed between the Aptian and Miocene series. Since the 1960s to date, many papers have been written either with details of that original zoning or applying nanofossil biostratigraphy to solve stratigraphic problems. Regardless of all the papers and studies undertaken, little attention has been paid to the Quaternary, since these deposits are normally of no interest to petroleum geology stricto sensu, especially in a large part of the Brazilian margin. On the other hand, there are a few articles and some Master's dissertations and PhD theses that were written and/or are in progress in Brazilian universities. On the other hand, elsewhere in the world, Quaternary nanofossils have been thoroughly investigated in terms of biostratigraphy and paleoceanography. It is, therefore, very clear that there is a gap between what is being done elsewhere in the world and what has been done in Brazil. In fact, this gap is not larger simply because of a few researchers in Brazilian universities who are studying this topic. The intention of this paper is to contribute toward a richer study of Quaternary nanofossils. It, therefore, contains illustrations and taxonomic descriptions of many species observed in the younger strata of the Brazilian margin basins. This article not only aspires to portray and disseminate the potential of nanofossils for the marine Quaternary study but is also an invitation to students (under and post-graduates) and university researchers - an invitation to learn a little more about the subject and spend some time studying these real gems

  17. Map and Data for Quaternary Faults and Fault Systems on the Island of Hawai`i

    Science.gov (United States)

    Cannon, Eric C.; Burgmann, Roland; Crone, Anthony J.; Machette, Michael N.; Dart, Richard L.

    2007-01-01

    Introduction This report and digitally prepared, GIS-based map is one of a series of similar products covering individual states or regions of United States that show the locations, ages, and activity rates of major earthquake-related features such as faults and fault-related folds. It is part of a continuing the effort to compile a comprehensive Quaternary fault and fold map and database for the United States, which is supported by the U.S. Geological Survey's (USGS) Earthquake Hazards Program. Guidelines for the compilation of the Quaternary fault and fold maps for the United States were published by Haller and others (1993) at the onset of this project. This compilation of Quaternary surface faulting and folding in Hawai`i is one of several similar state and regional compilations that were planned for the United States. Reports published to date include West Texas (Collins and others, 1996), New Mexico (Machette and others, 1998), Arizona (Pearthree, 1998), Colorado (Widmann and others, 1998), Montana (Stickney and others, 2000), Idaho (Haller and others, 2005), and Washington (Lidke and others, 2003). Reports for other states such as California and Alaska are still in preparation. The primary intention of this compilation is to aid in seismic-hazard evaluations. The report contains detailed information on the location and style of faulting, the time of most recent movement, and assigns each feature to a slip-rate category (as a proxy for fault activity). It also contains the name and affiliation of the compiler, date of compilation, geographic and other paleoseismologic parameters, as well as an extensive set of references for each feature. The map (plate 1) shows faults, volcanic rift zones, and lineaments that show evidence of Quaternary surface movement related to faulting, including data on the time of most recent movement, sense of movement, slip rate, and continuity of surface expression. This compilation is presented as a digitally prepared map product

  18. The New ILP Database of Quaternary Faults and Folds in South America

    Science.gov (United States)

    Costa, C. H.; Cisneros, H. A.; Machette, M. N.; Dart, R. L.

    2003-12-01

    As part of the International Lithosphere Program's Task Group II-2, we have completed the compilation of Quaternary faults and folds in South America and have established an Internet website for this data. The underpinning maps and reports have been released as electronic U.S. Geological Survey Open-File Reports (pdfs, see poster). The maps show the location, time, sense of slip, and activity rate of major earthquake-related features such as faults and fault-related folds. The maps are accompanied by descriptions of their Quaternary activity. The primary elements of the 10-year project are supervision and interpretation of geologic/tectonic information (Costa and Machette), data compilation (project participants), database design and management (Cisneros), and GIS input and management (Dart). A dozen experts in Quaternary faulting, neotectonics, paleoseismology, and seismology compiled the data: questions about individual faults or additions to the database should be directed to them. Prior to this project, digital maps of Quaternary faults did not exist for any of the South America countries, even though understanding the extent and character of active and older Quaternary faults are critical elements of seismic-hazards analysis. These new data will help extend the relatively short record of instrumental and felt seismicity that is the primary parameter for current seismic-hazard assessments in South American countries. Although some fault data were available for most of the countries (i.e., Venezuela), the degree of completeness varies as a function of the remoteness and vegetation cover (i.e., Brazil). A few faults such as the Bocono have had detailed investigations involving modern paleoseismic techniques. Other faults have been studied in some detail, usually in association with concerns about hazards to urban areas or the safety of critical facilities such as mining operations, oil-and-gas pipelines, or power-generating facilities. However, the general state

  19. Quaternary geologic map of the Winnipeg 4 degrees x 6 degrees quadrangle, United States and Canada

    Science.gov (United States)

    Fullerton, D. S.; Ringrose, S.M.; Clayton, Lee; Schreiner, B.T.; Goebel, J.E.

    2000-01-01

    The Quaternary Geologic Map of the Winnipeg 4? ? 6? Quadrangle, United States and Canada, is a component of the U.S. Geological Survey Quaternary Geologic Atlas of the United States map series (Miscellaneous Investigations Series I-1420), an effort to produce 4? ? 6? Quaternary geologic maps, at 1:1 million scale, of the entire conterminous United States and adjacent Canada. The map and the accompanying text and supplemental illustrations provide a regional overview of the areal distributions and characteristics of surficial deposits and materials of Quaternary age (~1.8 Ma to present) in parts of North Dakota, Minnesota, Manitoba, and Saskatchewan. The map is not a map of soils as soils are recognized in agriculture. Rather, it is a map of soils as recognized in engineering geology, or of substrata or parent materials in which agricultural soils are formed. The map units are distinguished chiefly on the basis of (1)genesis (processes of origin) or environments of deposition: for example, sediments deposited primarily by glacial ice (glacial deposits or till), sediments deposited in lakes (lacustrine deposits), or sediments deposited by wind (eolian deposits); (2) age: for example, how long ago the deposits accumulated; (3) texture (grain size)of the deposits or materials; (4) composition (particle lithology) of the deposits or materials; (5) thickness; and (6) other physical, chemical, and engineering properties. Supplemental illustrations show (1) temporal correlation of the map units, (2) the areal relationships of late Wisconsin glacial ice lobes and sublobes, (3) temporal and spatial correlation of late Wisconsin glacial phases, readvance limits, and ice margin stillstands, (4) temporal and stratigraphic correlation of surface and subsurface glacial deposits in the Winnipeg quadrangle and in adjacent 4? ? 6? quadrangles, and (5) responsibility for state and province compilations. The database provides information related to geologic hazards (for example

  20. Origin, Extent, and Thickness of Quaternary Geologic Units in the Willamette Valley, Oregon

    Science.gov (United States)

    O'Connor, Jim E.; Sarna-Wojcicki, Andrei M.; Wozniak, Karl C.; Polette, Danial J.; Fleck, Robert J.

    2001-01-01

    Stratigraphic and chronologic information collected for Quaternary deposits in the Willamette Valley, Oregon, provides a revised stratigraphic framework that serves as a basis for a 1:250,000-scale map, as well as for thickness estimates of widespread Quaternary geologic units. We have mapped 11 separate Quaternary units that are differentiated on the basis of stratigraphic, topographic, pedogenic, and hydrogeologic properties. In summation, these units reflect four distinct episodes in the Quaternary geologic development of the Willamette Valley: 1) Fluvial sands and gravels that underlie terraces flanking lowland margins and tributary valleys were probably deposited between 2.5 and 0.5 million years ago. They are the oldest widespread surficial Quaternary deposits in the valley. Their present positions and preservation are undoubtedly due to postdepositional tectonic deformation - either by direct tectonic uplift of valley margins, or by regional tectonic controls on local base level. 2) Tertiary and Quaternary excavation or tectonic lowering of the Willamette Valley accommodated as much as 500 m (meters) of lacustrine and fluvial fill. Beneath the lowland floor, much of the upper 10 to 50 m of fill is Quaternary sand and gravel deposited by braided channel systems in subhorizontal sheets 2 to 10 m thick. These deposits grade to gravel fans 40 to 100 m thick where major Cascade Range rivers enter the valley and are traced farther upstream as much thinner valley trains of coarse gravel. The sand and gravel deposits have ages that range from greater than 420,000 to about 12,000 years old. A widely distributed layer of sand and gravel deposited at about 12 ka (kiloannum, thousands of years before the present) is looser and probably more permeable than older sand and gravel. Stratigraphic exposures and drillers' logs indicate that this late Pleistocene unit is mostly between 5 and 20 m thick where it has not been subsequently eroded by the Willamette River and its

  1. Significance of Quaternary and Experimental Fluvial Systems to Interpretation of the Stratigraphic Record

    Science.gov (United States)

    Blum, M. D.; Martin, J. M.

    2012-12-01

    Studies of Quaternary and experimental fluvial systems provide significant insight for interpretation of fluvial deposits in the stratigraphic record, ranging from measurement of processes and relevant scales of key architectural elements, to process-based understanding of fluvial systems in sequence stratigraphic models. One key advantage for Quaternary and experimental systems is they commonly provide the ability to test, in a classical verification or falsification sense, interpretations, models and their alternatives that were developed from the stratigraphic record alone. First, scaling relationships developed from Quaternary fluvial deposits can be utilized to constrain interpretations of ancient strata, as well as predict the scale of channel fills, channel-belt sand bodies, and incised valleys. Scaling relationships are defined by power laws, with absolute dimensions that scale to drainage area, water flux, and sediment flux. Width-to-thickness ratios for channel fills range from 10-20:1, whereas channel-belt sand bodies upstream from backwater effects commonly range from 70-300:1, and 20-40:1within the backwater zone, where channel migration is limited. Quaternary incised valleys range from 25-150 m in thickness, and ~5-100 km in width, with width-to-thickness ratios of ~500-800. Scales of Quaternary channel fills and channel-belt sand bodies overlap are consistent with compilations from the ancient record. However, even the smallest Quaternary incised valleys reside in the uppermost part of the domain of published ancient valleys, with ancient examples overlapping significantly with modern channel fills and channel belts. We suggest that many ancient examples have been overinterpreted because of a lack of objective criteria for differentiating channel fills, channel belts, and incised valleys. Second, incised valleys have long played a key role in sequence-stratigraphic interpretations. For incised valleys in the stratigraphic record, either in outcrop or

  2. The Quaternary Silver Creek Fault Beneath the Santa Clara Valley, California

    Science.gov (United States)

    Wentworth, Carl M.; Williams, Robert A.; Jachens, Robert C.; Graymer, Russell W.; Stephenson, William J.

    2010-01-01

    The northwest-trending Silver Creek Fault is a 40-km-long strike-slip fault in the eastern Santa Clara Valley, California, that has exhibited different behaviors within a changing San Andreas Fault system over the past 10-15 Ma. Quaternary alluvium several hundred meters thick that buries the northern half of the Silver Creek Fault, and that has been sampled by drilling and imaged in a detailed seismic reflection profile, provides a record of the Quaternary history of the fault. We assemble evidence from areal geology, stratigraphy, paleomagnetics, ground-water hydrology, potential-field geophysics, and reflection and earthquake seismology to determine the long history of the fault in order to evaluate its current behavior. The fault formed in the Miocene more than 100 km to the southeast, as the southwestern fault in a 5-km-wide right step to the Hayward Fault, within which the 40-km-long Evergreen pull-apart basin formed. Later, this basin was obliquely cut by the newly recognized Mt. Misery Fault to form a more direct connection to the Hayward Fault, although continued growth of the basin was sufficient to accommodate at least some late Pliocene alluvium. Large offset along the San Andreas-Calaveras-Mt Misery-Hayward Faults carried the basin northwestward almost to its present position when, about 2 Ma, the fault system was reorganized. This led to near abandonment of the faults bounding the pull-apart basin in favor of right slip extending the Calaveras Fault farther north before stepping west to the Hayward Fault, as it does today. Despite these changes, the Silver Creek Fault experienced a further 200 m of dip slip in the early Quaternary, from which we infer an associated 1.6 km or so of right slip, based on the ratio of the 40-km length of the strike-slip fault to a 5-km depth of the Evergreen Basin. This dip slip ends at a mid-Quaternary unconformity, above which the upper 300 m of alluvial cover exhibits a structural sag at the fault that we interpret as

  3. Mapping the North Sea base-Quaternary: using 3D seismic to fill a gap in the geological record

    Science.gov (United States)

    Lamb, Rachel; Huuse, Mads; Stewart, Margaret; Brocklehurst, Simon H.

    2014-05-01

    The identification and mapping of the base-Quaternary boundary in the central parts of the North Sea is problematic due to the change from an unconformable transition between Pliocene and Pleistocene deltaic deposits in the southern North Sea to a conformable one further north (Sejrup et al 1991; Gatliff et al 1994). The best estimates of the transition use seismic reflection data to identify a 'crenulated reflector' (Buckley 2012), or rely on correlating sparse biostratigraphy (Cameron et al 1987). Recent integration of biostratigraphy, pollen analysis, paleomagnetism and amino acid analysis in the Dutch and Danish sectors (Rasmussen et al 2005; Kuhlmann et al 2006) allows greater confidence in the correlation to a regional 3D seismic dataset and show that the base-Quaternary can be mapped across the entire basin. The base-Quaternary has been mapped using the PGS MegaSurvey dataset from wells in the Danish Sector along the initially unconformable horizon and down the delta front into the more conformable basin giving a high degree of confidence in the horizon pick. The mapped horizon is presented here alongside the difference between this new interpretation and the previously interpreted base-Quaternary (Buckley 2012). The revised base-Quaternary surface reaches a depth of 1248 ms TWT or approximately 1120 m (assuming average velocity of 1800 m/s) showing an elongate basin shape that follows the underlying structure of the Central Graben. The difference between the revised base-Quaternary and the traditional base-Quaternary reaches a maximum of over 600 ms TWT or approximately 540 m in the south-west with over 300 ms TWT or approximately 270 m at the Josephine well (56° 36.11'N, 2° 27.09'E) in the centre of the basin. Mapping this new base-Quaternary allows for the interpretation of the paleo-envionrment during the earliest Quaternary. Seismic attribute analysis indicates a deep water basin with sediment deposition from multiple deltas and redistribution by deep

  4. Sex allocation and functional bias of quaternary and quinary flowers on same inflorescence in the hermaphrodite Ruta graveolens

    Science.gov (United States)

    Tang, Jing-Yu; Ren, Ming-Xun

    2011-09-01

    Intra-inflorescence variation in floral traits is important to understand the pollination function of an inflorescence and the real reproductive outputs of a plant. Ruta graveolens (Rutaceae) produce both quaternary (four petals and eight stamens) and quinary (five petals and ten stamens) flowers on the same cymes, while their pollination roles and the effects on the reproductive success remained unexplored. We experimentally examined the biomass of female versus male organs and pollen viability and stigma receptivity to explore the sex allocation patterns between the flowers. The breeding systems and reproductive outputs through either female function (seed set) or male function (pollen dispersal) were also studied for quinary and quaternary flowers to determine whether there was functional bias. The results showed that R. graveolens was protandrous, with a mixed mating system. Its stamens could slowly move one by one and only dehisce when positioning at the flower center, which could greatly enhance pollen dispersal. The first-opened quinary flower allocated significantly higher resources (dry biomass) in female organs while quaternary flowers allocated more resource in male organs. The quaternary flowers experienced higher pollen limitation in seed production but were more successful in pollen dispersal and the quinary flowers reproduced both through female and male functions. Our data suggested that quinary and quaternary flower on same inflorescence in R. graveolens functioned mainly as the sex role that most resources were allocated, which probably reflect an adaptation for floral phenology and pollination process in this plant.

  5. Versatile methods for synthesizing organic acid salts of quaternary berberine-type alkaloids as anti-ulcerative colitis agents.

    Science.gov (United States)

    Zhang, Zhi-Hui; Li, Jing; Zhang, Hai-Jing; Deng, An-Jun; Wu, Lian-Qiu; Li, Zhi-Hong; Song, Hong-Rui; Wang, Wen-Jie; Qin, Hai-Lin

    2016-06-01

    Two versatile methods to synthesize kinds of organic acid salts of quaternary berberine-type alkaloids were investigated in order to determine which is more efficient to improve the liposolubility of the target compounds and to explore the efficacy of the target compounds as anti-ulcerative colitis (UC) agents. Overall evaluation according to the reaction results and yields of the final products indicated that the synthetic method using tertiary (±)-8-acylmethyldihydroberberine-type alkaloids as key intermediates is superior to that of using tertiary dihydroberberine-type alkaloids as intermediates. Ten target compounds were synthesized using quaternary berberine chloride and quaternary coptisine chloride as starting materials, respectively, and the anti-UC activity of some target compounds was evaluated in an in vitro x-box-binding protein 1 (XBP1) transcriptional activity assay using dual luciferase reporter detection. At 10 μM, the tested compounds were found to activate the transcription of XBP1 target at almost the same level as that of quaternary coptisine chloride. The synthesized target compounds were also found to share higher liposolubility than the inorganic acid salts of quaternary berberine-type alkaloid.

  6. The offshore Yangsan fault activity in the Quaternary, SE Korea: Analysis of high-resolution seismic profiles

    Science.gov (United States)

    Kim, Han-Joon; Moon, Seonghoon; Jou, Hyeong-Tae; Lee, Gwang Hoon; Yoo, Dong Geun; Lee, Sang Hoon; Kim, Kwang Hee

    2016-12-01

    The NNE-trending dextral Yangsan fault is a > 190-km-long structure in the Korean Peninsula traced to the southeastern coast. The scarcity of Quaternary deposits onland precludes any detailed investigation of the Quaternary activity and structure of the Yangsan fault using seismic reflection profiling. We acquired offshore high-resolution seismic profiles to investigate the extension of the Yangsan fault and constrain its Quaternary activity using stratigraphic markers. The seismic profiles reveal a NNE-trending fault system consisting of a main fault and an array of subsidiary faults that displaced Quaternary sequences. Stratigraphic analysis of seismic profiles indicates that the offshore faults were activated repeatedly in the Quaternary. The up-to-the-east sense of throw on the main fault and plan-view pattern of the fault system are explained by dextral strike-slip faulting. The main fault, when projected toward the Korean Peninsula along its strike, aligns well with the Yangsan fault. We suggest that the offshore fault system is a continuation of the Yangsan fault and has spatial correlation with weak but ongoing seismicity.

  7. Late Quaternary Faulting along the San Juan de los Planes Fault Zone, Baja California Sur, Mexico

    Science.gov (United States)

    Busch, M. M.; Coyan, J. A.; Arrowsmith, J.; Maloney, S. J.; Gutierrez, G.; Umhoefer, P. J.

    2007-12-01

    As a result of continued distributed deformation in the Gulf Extensional Province along an oblique-divergent plate margin, active normal faulting is well manifest in southeastern Baja California. By characterizing normal-fault related deformation along the San Juan de los Planes fault zone (SJPFZ) southwest of La Paz, Baja California Sur we contribute to understanding the patterns and rates of faulting along the southwest gulf-margin fault system. The geometry, history, and rate of faulting provide constraints on the relative significance of gulf-margin deformation as compared to axial system deformation. The SJPFZ is a major north-trending structure in the southern Baja margin along which we focused our field efforts. These investigations included: a detailed strip map of the active fault zone, including delineation of active scarp traces and geomorphic surfaces on the hanging wall and footwall; fault scarp profiles; analysis of bedrock structures to better understand how the pattern and rate of strain varied during the development of this fault zone; and a gravity survey across the San Juan de los Planes basin to determine basin geometry and fault behavior. The map covers a N-S swath from the Gulf of California in the north to San Antonio in the south, an area ~45km long and ~1-4km wide. Bedrock along the SJPFZ varies from Cretaceous Las Cruces Granite in the north to Cretaceous Buena Mujer Tonalite in the south and is scarred by shear zones and brittle faults. The active scarp-forming fault juxtaposes bedrock in the footwall against Late Quaternary sandstone-conglomerate. This ~20m wide zone is highly fractured bedrock infused with carbonate. The northern ~12km of the SJPFZ, trending 200°, preserves discontinuous scarps 1-2km long and 1-3m high in Quaternary units. The scarps are separated by stretches of bedrock embayed by hundreds of meters-wide tongues of Quaternary sandstone-conglomerate, implying low Quaternary slip rate. Further south, ~2 km north of the

  8. Tectonic control on the Late Quaternary hydrography of the Upper Tiber Basin (Northern Apennines, Italy)

    Science.gov (United States)

    Benvenuti, Marco; Bonini, Marco; Moroni, Adriana

    2016-09-01

    We examine the intramontane Upper Tiber Basin in the Northern Apennines (central Italy), where sub-orthogonal fault systems forced river deviation and the abandonment of alluvial fans since the late Middle Pleistocene. Archaeological material, spanning the Middle Palaeolithic-Iron Age, was collected mostly from the surface of the Late Quaternary alluvial landforms and related deposits (MUP and HOL units). This information contributed to the partial dating of seven major stages of drainage development. Normal faults parallel and transverse to the basin trend were active at different times and conditioned the valley pattern of the Middle (MUP1-2)-Late (MUP3) Pleistocene Tiber, Singerna, Sovara and Tignana rivers, which still flow today into the basin. The MUP1 and the MUP3 fans were beheaded by the displacement of their feeder valleys along the basin-transverse Carmine and Montedoglio faults. In some cases, the former feeder rivers underwent stream piracy but their courses mostly deviated in response of the topographic gradient created by faulting, as well as through the incision of new valleys that exploited the lithological contrast along the fault lines. The MUP3 Tignana fan was abandoned mostly due to the activity of the basin-parallel, dip-slip Sansepolcro fault. Subsidence driven by the basin-parallel Anghiari and Sansepolcro fault systems also provided the accommodation space for the MUP3 and HOl1-2 Afra fans between Late Pleistocene and early-mid Holocene. This study exemplifies the interplay between longitudinal and transverse fault systems, and the Late Quaternary hydrographic evolution of an extensional basin settled in the axial zone of an active fold-and-thrust belt. Although the faulting has interacted with the forcing exerted by the Late Quaternary climate fluctuations on the basin drainage systems, the tectonic rates are sufficiently high to represent the prime controller on base-level change and drainage routing patterns.

  9. Quaternary ammonium biocides as antimicrobial agents protecting historical wood and brick.

    Science.gov (United States)

    Rajkowska, Katarzyna; Koziróg, Anna; Otlewska, Anna; Piotrowska, Małgorzata; Nowicka-Krawczyk, Paulina; Brycki, Bogumił; Kunicka-Styczyńska, Alina; Gutarowska, Beata

    2016-01-01

    Quaternary ammonium compounds (QACs) are widely used in disinfection of water, surfaces and instruments as well as in textile, leather and food industries because of their relatively low toxicity, broad antimicrobial spectrum, non-volatility and chemical stability. Due to these advantages, QACs are also used in restoration and can be applied on historical material. The aim of this study was to determine the usefulness of biocides based on quaternary ammonium salts and containing various excipients in the protection of historical materials against microbial growth. The study determined the antimicrobial activity of three biocides against bacteria: Pseudomonas fluorescens, Staphylococcus equorum, Bacillus cereus, Bacillus muralis, Sporosarcina aquimarina and Rhodococcus fascians, and moulds: Chaetomium globosum, Penicillium citreonigrum, Cladosporium cladosporioides I, Acremonium strictum, Aspergillus fumigatus and Cladosporium cladosporioides II, all isolated from historical wood and brick. Staphylococcus equorum, Bacillus cereus, Sporosarcina aquimarina and Rhodococcus fascians bacteria, and Cladosporium cladosporioides I and Acremonium strictum moulds showed high sensitivity to quaternary ammonium biocides. Historical wood can be effectively disinfected by three applications of biocide A (30% v/v) containing dodecyl dimethyl ammonium chloride (DDAC), citric acid, propiconazole and propanol. Disinfection of historical brick can be carried out by three applications of 6% v/v solutions of biocide B (based on DDAC and ethylenediaminetetraacetic acid - EDTA) or biocide C (containing a non-ionic surfactant, DDAC and EDTA). Effective protection of historical building materials against microbial growth for a period of seven days can be achieved by the application of biocide A (30% v/v) on the wood surface and biocide B (6% v/v) on the brick surface.

  10. Quaternary geologic map of the White Lake 4° x 6° quadrangle, United States

    Science.gov (United States)

    State compilations by Pope, David E.; Gilliland, William A.; Wermund, E.G.; edited and integrated by Richmond, Gerald Martin; Weide, David L.; Moore, David W.; Digital edition by Bush, Charles A.

    1990-01-01

    This map is part of the Quaternary Geologic Atlas of the United States (I-1420). It was first published as a printed edition in 1990. The geologic data have now been captured digitally and are presented here along with images of the printed map sheet and component parts as PDF files. The Quaternary Geologic Map of the White Lake 4° x 6° Quadrangle was mapped as part of the Quaternary Geologic Atlas of the United States. The atlas was begun as an effort to depict the areal distribution of surficial geologic deposits and other materials that accumulated or formed during the past 2+ million years, the period that includes all activities of the human species. These materials are at the surface of the Earth. They make up the ground on which we walk, the dirt in which we dig foundations, and the soil in which we grow crops. Most of our human activity is related in one way or another to these surface materials that are referred to collectively by many geologists as regolith, the mantle of fragmental and generally unconsolidated material that overlies the bedrock foundation of the continent. The maps were compiled at 1:1,000,000 scale. In recent years, surficial deposits and materials have become the focus of much interest by scientists, environmentalists, governmental agencies, and the general public. They are the foundations of ecosystems, the materials that support plant growth and animal habitat, and the materials through which travels much of the water required for our agriculture, our industry, and our general well being. They also are materials that easily can become contaminated by pesticides, fertilizers, and toxic wastes. In this context, the value of the surficial geologic map is evident.

  11. Beyond BLASTing: tertiary and quaternary structure analysis helps identify major vault proteins.

    Science.gov (United States)

    Daly, Toni K; Sutherland-Smith, Andrew J; Penny, David

    2013-01-01

    We examine the advantages of going beyond sequence similarity and use both protein three-dimensional (3D) structure prediction and then quaternary structure (docking) of inferred 3D structures to help evaluate whether comparable sequences can fold into homologous structures with sufficient lateral associations for quaternary structure formation. Our test case is the major vault protein (MVP) that oligomerizes in multiple copies to form barrel-like vault particles and is relatively widespread among eukaryotes. We used the iterative threading assembly refinement server (I-TASSER) to predict whether putative MVP sequences identified by BLASTp and PSI Basic Local Alignment Search Tool are structurally similar to the experimentally determined rodent MVP tertiary structures. Then two identical predicted quaternary structures from I-TASSER are analyzed by RosettaDock to test whether a pair-wise association occurs, and hence whether the oligomeric vault complex is likely to form for a given MVP sequence. Positive controls for the method are the experimentally determined rat (Rattus norvegicus) vault X-ray crystal structure and the purple sea urchin (Strongylocentrotus purpuratus) MVP sequence that forms experimentally observed vaults. These and two kinetoplast MVP structural homologs were predicted with high confidence value, and RosettaDock predicted that these MVP sequences would dock laterally and therefore could form oligomeric vaults. As the negative control, I-TASSER did not predict an MVP-like structure from a randomized rat MVP sequence, even when constrained to the rat MVP crystal structure (PDB:2ZUO), thus further validating the method. The protocol identified six putative homologous MVP sequences in the heterobolosean Naegleria gruberi within the excavate kingdom. Two of these sequences are predicted to be structurally similar to rat MVP, despite being in excess of 300 residues shorter. The method can be used generally to help test predictions of homology via

  12. Geothermal prospecting by geochemical methods in the Quaternary volcanic province of Dhamar (central Yemen)

    Science.gov (United States)

    Minissale, Angelo; Vaselli, Orlando; Mattash, Mohamed; Montegrossi, Giordano; Tassi, Franco; Ad-Dukhain, Abdulsalam; Kalberkamp, Ulrich; Al-Sabri, Ali; Al-Kohlani, Taha

    2013-01-01

    This paper deals with geothermal prospecting carried out in the Quaternary volcanic field of Dhamar, which is located almost in the centre of the main Oligo-Miocene basaltic trap plateau of Yemen. By applying geochemical and thermometric techniques in domestic wells producing water from the shallow unconfined aquifer in the area, which is prevalently hosted inside the Quaternary volcano-clastic material, a closed thermal anomaly associated with the Quaternary volcanic activity was well delineated. Although the aquifer(s) has a Ca-Na-HCO3 composition, that is typical of shallow groundwater, there are several chemical anomalies in the hotter central area compared to typical aquifers: i) the pH is lower and, consequently, the calculated partial pressure of CO2 in solution is higher, ii) the electrical conductivity is higher, iii) the total salinity is higher and iv) the fluoride ion concentration is higher. Such chemical anomalies in the hotter part of the aquifer do not seem to be generated by the rising and/or mixing of deep hydrothermal components rising into the shallow aquifer, but rather produced by enhanced water-rock interaction processes resulting from the higher temperature of the aquifer and its greater acidity. By applying some speculative calculations, based on the likely temperature of rainfall in the area and the depth and temperature of individual wells, the local thermal gradients in the area have been calculated. The thermal gradient varies from less than the average Earth gradient at the periphery of the delimitated thermal anomaly, to more than 250 °C/km, within an extensive area (exceeding 200 km2) where the gradient is greater than 100/120 °C/km.

  13. Enhanced water-solubility, antibacterial activity and biocompatibility upon introducing sulfobetaine and quaternary ammonium to chitosan.

    Science.gov (United States)

    Chen, Yuxiang; Li, Jianna; Li, Qingqing; Shen, Yuanyuan; Ge, Zaochuan; Zhang, Wenwen; Chen, Shiguo

    2016-06-05

    Chitosan (CS) has attracted much attention due to its good antibacterial activity and biocompatibility. However, CS is insoluble in neutral and alkaline aqueous solution, limiting its biomedical application to some extent. To circumvent this drawback, we have synthesized a novel N-quaternary ammonium-O-sulfobetaine-chitosan (Q3BCS) by introducing quaternary ammonium compound (QAC) and sulfobetaine, and its water-solubility, antibacterial activity and biocompatibility were evaluated compare to N-quaternary ammonium chitosan and native CS. The results showed that by introducing QAC, antibacterial activities and water-solubilities increase with degrees of substitution. The largest diameter zone of inhibition (DIZ) was improved from 0 (CS) to 15mm (N-Q3CS). And the water solution became completely transparent from pH 6.5 to pH 11; the maximal waters-solubility was improved from almost 0% (CS) to 113% at pH 7 (N-Q3CS). More importantly, by further introducing sulfobetaine, cell survival rate of Q3BCS increased from 30% (N-Q3CS) to 85% at 2000μg/ml, which is even greater than that of native CS. Furthermore, hemolysis of Q3BCS was dropped sharply from 4.07% (N-Q3CS) to 0.06%, while the water-solution and antibacterial activity were further improved significantly. This work proposes an efficient strategy to prepare CS derivatives with enhanced antibacterial activity, biocompatibility and water-solubility. Additionally, these properties can be finely tailored by changing the feed ratio of CS, glycidyl trimethylammonium chloride and NCO-sulfobetaine.

  14. A“Yellow Cap” on Quaternary Red Clay in Jiujiang,Jiangxi Province

    Institute of Scientific and Technical Information of China (English)

    1999-01-01

    A thin layer of yellow-brown-colored earth was generally found on Quaternary red clay in Jiujing,Jiangxi Province,A typical profile was established.Both particle size distribution and REE(rare earth elements)characteristics of the yellow-brown-colored earth of the profile fully suggested its aeolian origin and close similarity of Nanjing Xiashu Loess.The study also implied aeolian origin of the underlying Quaternary red clay,Compared with the red clay,the yellow-brown-colored earth was less weathered because of its lower content of free iron and higher mole ratios of SiO2/Al2O3 and SiO2(Fe2O3+Al2O3) as well as its less developed chemical microtextures of quartz grains.In order to study the ages of the two deposits comparatively,the thermoluminescent dating method was used.As a result,the bottom of the yellow-brown-colored earth was dated to 60±5 ka B.P.and the upper part of the red clay 388±54 ka B.P.It was suggested that the yellow-brown-colored earth earth was formed in the Late Pleistocene and was probably the aeolian deposit of the Last Glacial,which corresponded with the Malan Loess in the Loess Plateau of the northwestern part of China,while the underlying red clay was formed in the Middle Pleistocene.A“yellow cap” on Quaternary red clay in Jiujiang implied a great climatic and environmental variation in the beginning of the Late Pleistocene in the southern part of China,especially in the middle and lower reaches of the Yangtze River,The event not only halted the rubification,once dominating the region but also produced a widespread covering of aeolian deposit,as only occurred in the cold and dry environment.

  15. Quaternary transgressive and regressive depositional sequences in the East China Sea

    Institute of Scientific and Technical Information of China (English)

    LIUZhenxia; YINPing; XIONGYingqian; S.Beme; A.Trentesaux; LIChaoxin

    2003-01-01

    Based on the interpretation more than 4000 km sparker single channel seismic profiles and the comparison with Borehole DZQ4 on the outer shelf of the East China Sea (ECS),the seismic sequences,sedimentary facies and paleo-sedimentary environment are studied to establish the chronology framework and discuss the Quaternary transgressive and regressive sequences of the ECS shelf as well as their response to glacio-eustatic sea-level changes.The sea level of the ECS fluctuated with global climate changes in the Quaternary.During the sea level rise,the pacific tidal wave impacted actively on the ECS continental shelf and the reciprocating tidal currents in NW-SE direction formed tidal sand ridges,which represent large transgressive deposits visible on the seismic profiles.In response to sea level fall,the Yangtze River deltas prograded seaward and built massive subaqueous deltas to form regressive sequences on the seismic profiles.Alternative transgression and regression sequences were vertically distributed on the ECS shelf with the frequent eustacy in the Quaternary.The gentle slope of the ECS shelf makes it possible for the coastline to migrate hundreds of kilometers forth and back on the shelf because of tens of meters sea level changes,in the meanwhile,the Yangtze River discharged large amounts of sediments into the ECS resulting in large-scale subaqueous deltas and tidal sand ridges.There have developed 3 stages of tidal sand ridges and 4 stages of deltas on the ECS shelf since oxygen isotope stage 8.

  16. Fluvial responses to late Quaternary climate change in the Shiyang River drainage system, western China

    Science.gov (United States)

    Gao, Hongshan; Li, Zongmeng; Pan, Baotian; Liu, Fenliang; Liu, Xiaopeng

    2016-04-01

    As a drainage system located in arid western China, the Shiyang River, combined with considerable fluvial strata and landform information, provides an environmental context within which to investigate fluvial responses to late Quaternary climate change. Sedimentological analysis and optically stimulated luminescence (OSL) dating enabled us to reconstruct the processes and fluvial styles of three sedimentary sequences of the Shagou and Hongshui rivers in the Shiyang drainage system. Our results present a variety of river behaviors during the late Quaternary in these areas. In the upstream Shiyang River, Zhangjiadazhuang (ZJDZ) profile of the Shagou was dominated by aggradation and a meandering channel pattern at 10.6-4.2 ka, while a noticeable channel incision occurred at ~ 4.2 ka followed by lateral channel migration. In the downstream Shiyang River, Datugou (DTG) profile of the Hongshui was an aggrading meandering river from 39.7 to 7.2 ka while channel incision occurred at 7.2 ka. Another downstream profile, Wudunwan (WDW) of the Hongshui was also characterized by aggradation from 22.4 to 4.8 ka; however, its channel pattern shifted from braided to meandering at ~ 13 ka. A discernable downcutting event occurred at ~ 4.8 ka, followed by three channel aggradation and incision episodes prior to 1.8 ka. The last 1.8 ka has been characterized by modern channel and floodplain development. The fluvial processes and styles investigated have a close correlation with late Quaternary climate change in the Shiyang River drainage. During cold phases, the WDW reach was dominated by aggradation with a braided channel pattern. During warm phases, the rivers that we investigated were also characterized by aggradation but with meandering channel patterns. Channel incision events and changes of fluvial style occurred mainly during climate transitions.

  17. Quaternary volcanism, tectonics, and sedimentation in the Idaho National Engineering Laboratory area

    Energy Technology Data Exchange (ETDEWEB)

    Hackett, W.R.; Smith, R.P.

    1992-09-01

    In this article, we discuss the regional context and describe localities for a two-day field excursion in the vicinity of the Idaho National Engineering Laboratory (INEL). We address several geologic themes: (1) Late Cenozoic, bimodal volcanism of the Eastern Snake River Plain (ESRP), (2) the regional tectonics and structural geology of the Basin and Range province to the northwest of the ESRP, (3) fluvial, lacustrine, and aeolian sedimentation in the INEL area, and (4) the influence of Quaternary volcanism and tectonics on sedimentation near the INEL.

  18. Quaternary volcanism, tectonics, and sedimentation in the Idaho National Engineering Laboratory area

    Energy Technology Data Exchange (ETDEWEB)

    Hackett, W.R.; Smith, R.P.

    1992-01-01

    In this article, we discuss the regional context and describe localities for a two-day field excursion in the vicinity of the Idaho National Engineering Laboratory (INEL). We address several geologic themes: (1) Late Cenozoic, bimodal volcanism of the Eastern Snake River Plain (ESRP), (2) the regional tectonics and structural geology of the Basin and Range province to the northwest of the ESRP, (3) fluvial, lacustrine, and aeolian sedimentation in the INEL area, and (4) the influence of Quaternary volcanism and tectonics on sedimentation near the INEL.

  19. A Quaternary Polybenzimidazole Membrane for Intermediate Temperature Polymer Electrolyte Membrane Fuel Cells

    DEFF Research Database (Denmark)

    Xu, C.; Scott, K.; Li, Qingfeng

    2013-01-01

    A quaternary ammonium polybenzimidazole (QPBI) membrane was synthesized for applications in intermediate temperature (100–200 °C) hydrogen fuel cells. The QPBI membrane was imbibed with phosphoric acid to provide suitable proton conductivity. The proton conductivity of the membrane was 0.051 S cm–1...... at 150 °C with the PA acid loading level of 3.5 PRU (amount of H3PO4 per repeat unit of polymer QPBI). The QPBI membrane was characterized in terms of composition, structure and morphology by NMR, FTIR, SEM, and EDX. The fuel cell performance with the membrane gave peak power densities of 440 and 240 m...

  20. The electronic and magnetic properties of quaternary Heusler alloy CoFeMnGe

    Science.gov (United States)

    Seema, K.

    2016-05-01

    We present study of quaternary Heusler alloy CoFeMnGe using density functional theory. The compound is half-metallic with half-metallic gap of 0.13 eV. The total magnetic moment of this compound is 3.96 μB which is in close agreement with Slater-Pauling rule. The effect of lattice compression and expansion shows the robustness of half-metallicity. A large value of half-metallic gap and 100% spin-polarization makes this material interesting for spin dependent applications.

  1. On the Design and Analysis of Quaternary Serial and Parallel Adders

    CERN Document Server

    Das, Anindya; Hasan, Masud

    2010-01-01

    Optimization techniques for decreasing the time and area of adder circuits have been extensively studied for years mostly in binary logic system. In this paper, we provide the necessary equations required to design a full adder in quaternary logic system. We develop the equations for single-stage parallel adder which works as a carry look-ahead adder. We also provide the design of a logarithmic stage parallel adder which can compute the carries within log2(n) time delay for n qudits. At last, we compare the designs and finally propose a hybrid adder which combines the advantages of serial and parallel adder.

  2. Quaternary alloy semiconductor nanobelts with bandgap spanning the entire visible spectrum.

    Science.gov (United States)

    Pan, Anlian; Liu, Ruibin; Sun, Minghua; Ning, Cun-Zheng

    2009-07-15

    We used an improved cothermal evaporation route for the first time to achieve quaternary semiconductor nanostructured alloys, using an example of Zn(x)Cd(1-x)S(y)Se(1-y) nanobelts. The PL (bandgap) of these as-grown nanostructured alloys can be continuously tunable across the entire visible spectrum through experimentally controlling their compositions. Such widely controlled alloy nanostructures via composition/light emission provide a new material platform for applications in wavelength-tunable lasers, multicolor detectors, full-spectrum solar cells, LEDs, and color displays.

  3. Bio- and aminostratigraphy of some Quaternary marine deposits in West Greenland

    DEFF Research Database (Denmark)

    Funder, Svend Visby; Simonarson, Leifur A.

    1984-01-01

    age. The mollusc faunas at the sites are distinctly different, although all reflect influx of some subarctic water into Baffin Bay. The fauna from Patorffk is the most diverse subfossil Quaternary fauna known from Baffin Bay. Such species as Panopea Ilorvegica and Balanus hameri indicate conditions...... warmer than the present, although no identical faunal assemblages are known. The fauna at Laksebugt is similar to modem faunas, but the dominating Portlandia arctica and Macoma moesta indicate a climate somewhat colder than the present, and Mytilus edulis suggests the presence of subarctic water...

  4. Quaternary Oxide of Cerium, Terbium, Praseodymium and Zirconium for Three-Way Catalysts

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    Oxygen storagecapacity (OSC), oxygen buffer capacity (OBC), X-ray diffraction and electron diffraction pattern, high resolution electron microscopy were used to study the quaternary oxides, i.e., of Ce, Tb, Pr and Zr. (Ce0.6Tb0.2Zr0.2O2-δ and Ce0.6Pr0.2Zr0.2O2-δ). OSC and OBC data indicate that these oxides have very good oxygen transfer capacity (OTC) and their pseudo-solid solutions exhibit fluorite-type structure. These oxides may act as a good candidate for three-way catalysts (TWC).

  5. Dimethyl carbonate synthesis via transesterification catalyzed by quaternary ammonium salt functionalized chitosan

    Institute of Scientific and Technical Information of China (English)

    Yuan Zhao; Liang Nian He; Yuan Yi Zhuang; Jin Quan Wang

    2008-01-01

    A quaternary ammonium salt covalently linked to chitosan was first used as a catalyst for dimethyl carbonate (DMC) synthesis by the transesterification of propylene carbonate (PC) with methanol. The effects of various reaction variables like reaction time, temperature and pressure on the catalytic performance were also investigated. 54% DMC yield and 71% PC conversion were obtained under the optimal reaction conditions. Notably, the catalyst was able to be reused with retention of high catalytic activity and selectivity. Consequently, the process presented here has great potential for industrial application due to its advantages such as stability, easy preparation from renewable biopolymer, and simple separation from products.

  6. Phase Equilibria of Ternary and Quaternary Systems Containing Diethyl Carbonate with Water.

    Science.gov (United States)

    Chen, Yao; Wen, Caiyu; Zhou, Xiaoming; Zeng, Jun

    2014-01-01

    In this study liquid phase equilibrium compositions were measured at 298.15 K under atmospheric pressure for (water + propan-1-ol + diethyl carbonate (DEC) + benzene or cyclohexane or heptane) quaternary systems and (water + DEC + propan-1-ol or benzene or cyclohexane) ternary systems. Good correlation of the experimental LLE data was seen for the measured systems by both modified and extended UNIQUAC models. The solubility of DEC in aqueous and organic phases is shown by equilibrium distribution coefficients calculated from the LLE data.

  7. Micropaleontologic record of Quaternary paleoenvironments in the Central Albemarle Embayment, North Carolina, U.S.A.

    Science.gov (United States)

    Culver, Stephen J.; Farrell, Kathleen M.; Mallinson, David J.; Willard, Debra A.; Horton, Benjamin P.; Riggs, Stanley R.; Thieler, E. Robert; Wehmiller, John F.; Parham, Peter; Snyder, Scott W.; Hillier, Caroline

    2011-01-01

    To understand the temporal and spatial variation of eustatic sea-level fluctuations, glacio-hydro-isostacy, tectonics, subsidence, geologic environments and sedimentation patterns for the Quaternary of a passive continental margin, a nearly complete stratigraphic record that is fully integrated with a three dimensional chronostratigraphic framework, and paleoenvironmental information are necessary. The Albemarle Embayment, a Cenozoic regional depositional basin in eastern North Carolina located on the southeast Atlantic coast of the USA, is an ideal setting to unravel these dynamic, interrelated processes.Micropaleontological data, coupled with sedimentologic, chronostratigraphic and seismic data provide the bases for detailed interpretations of paleoenvironmental evolution and paleoclimates in the 90. m thick Quaternary record of the Albemarle Embayment. The data presented here come from a transect of cores drilled through a barrier island complex in the central Albemarle Embayment. This area sits in a ramp-like setting between late Pleistocene incised valleys.The data document the episodic infilling of the Albemarle Embayment throughout the Quaternary as a series of transgressive-regressive (T-R) cycles, characterized by inner shelf, midshelf, and shoreface assemblages, that overlie remnants of fluvial to estuarine valley-fill. Barrier island and marginal marine deposits have a low preservation potential. Inner to mid-shelf deposits of the early Pleistocene are overlain by similar middle Pleistocene shelf sediments in the south of the study area but entirely by inner shelf deposits in the north. Late Pleistocene marine sediments are of inner shelf origin and Holocene deposits are marginal marine in nature. Pleistocene marine sediments are incised, particularly in the northern half of the embayment by lowstand paleovalleys, partly filled by fluvial/floodplain deposits and in some cases, overlain by remnants of transgressive estuarine sediments. The shallowing

  8. Geomorphic evidence for enhanced Pliocene-Quaternary faulting in the northwestern Basin and Range

    Science.gov (United States)

    Ellis, Magdalena A; Barnes Jason B,; Colgan, Joseph P.

    2014-01-01

    Mountains in the U.S. Basin and Range Province are similar in form, yet they have different histories of deformation and uplift. Unfortunately, chronicling fault slip with techniques like thermochronology and geodetics can still leave sizable, yet potentially important gaps at Pliocene–Quaternary (∼105–106 yr) time scales. Here, we combine existing geochronology with new geomorphic observations and approaches to investigate the Miocene to Quaternary slip history of active normal faults that are exhuming three footwall ranges in northwestern Nevada: the Pine Forest Range, the Jackson Mountains, and the Santa Rosa Range. We use the National Elevation Dataset (10 m) digital elevation model (DEM) to measure bedrock river profiles and hillslope gradients from these ranges. We observe a prominent suite of channel convexities (knickpoints) that segment the channels into upper reaches with low steepness (mean ksn = ∼182; θref = 0.51) and lower, fault-proximal reaches with high steepness (mean ksn = ∼361), with a concomitant increase in hillslope angles of ∼6°–9°. Geologic maps and field-based proxies for rock strength allow us to rule out static causes for the knickpoints and interpret them as transient features triggered by a drop in base level that created ∼20% of the existing relief (∼220 m of ∼1050 m total). We then constrain the timing of base-level change using paleochannel profile reconstructions, catchment-scale volumetric erosion fluxes, and a stream-power–based knickpoint celerity (migration) model. Low-temperature thermochronology data show that faulting began at ca. 11–12 Ma, yet our results estimate knickpoint initiation began in the last 5 Ma and possibly as recently as 0.1 Ma with reasonable migration rates of 0.5–2 mm/yr. We interpret the collective results to be evidence for enhanced Pliocene–Quaternary fault slip that may be related to tectonic reorganization in the American West, although we cannot rule out climate as a

  9. Critical Coalescence Concetration (CCC as a parameter for evaluation of selected quaternary ammonium compounds

    Directory of Open Access Journals (Sweden)

    Danuta Szyszka

    2013-10-01

    Full Text Available The objective of this paper was to determine the Critical Coalescence Concentration (CCC of surfactants such as N(dodecyloxycarboxymethyl N,N,N-(trimethylammonium bromide (DMGM- 12, N-[2-(dodecyoxycarboxyethyl] N,N,N-(trimethylammonium bromide (DMALM-12 and N-[3- (dodecanoyloxycarboxyprophyl] N,N,N-(trimethylammonium bromide (DMPM-11. The surfactants used represent quaternary ammonium compounds containing a hydrophobic moiety with an ester group (commonly known as “esterquats”. The CCC value was determined by analysis of the relationship between concentration of surfactant and average air bubble diameter. The values of the critical coalescence concentration (CCC were estimated using a graphical method.

  10. PALEOSEISMICITY OF QUATERNARY FAULTS NEAR ALBUQUERQUE, NEW MEXICO: The Zia Fault

    OpenAIRE

    McCalpin, James P.

    2001-01-01

    This study continues USGS-funded efforts to assess the activity and earthquake hazard potential of Quaternary faults in the Albuquerque metropolitan region. Our target in 2000 was the Zia fault, a 37 km-long normal fault that trends N-S in northern Llano de Albuquerque (LdA). The Zia fault is one of three major east-dipping normal faults that define the western margin of the Rio Grande rift in the northern Albuquerque basin, the other faults being the Calabacillas fault (to the west of the Zi...

  11. Fabrication and properties of HDPE/CF/CaCO3/PE-g-MAH quaternary composites

    Science.gov (United States)

    Wang, X.-L.; Ming, H.; Yin, H.

    2015-07-01

    In this research, carbon fiber (CF) was taken as reinforcing filler, nano calcium carbonate (CaCO3) was taken as toughener, maleic anhydride grafted polyethylene (PE-g-MAH) was taken as compatibilizer for high density polyethylene (HDPE) modification. Through orthogonal test, the influence of different amount of ingredient CF, CaCO3 and PE-g-MAH on the mechanical properties of the HDPE composites was researched. The optimal composition of the quaternary composites with the good toughness and high strength was obtained.

  12. Asymmetric synthesis of quaternary aryl amino acid derivatives via a three-component aryne coupling reaction

    Directory of Open Access Journals (Sweden)

    Elizabeth P. Jones

    2011-11-01

    Full Text Available A method was developed for the synthesis of α-alkyl, α-aryl-bislactim ethers in good to excellent yields and high diastereoselectivities, consisting of a facile one-pot procedure in which the aryl group is introduced by means of a nucleophilic addition to benzyne and the alkyl group by alkylation of a resultant benzylic anion. Hydrolysis of the sterically less hindered adducts gave the corresponding quaternary amino acids with no racemization, whereas hydrolytic ring opening gave the corresponding valine dipeptides from bulkier bislactims.

  13. Bio-based ionic liquid crystalline quaternary ammonium salts: properties and applications.

    Science.gov (United States)

    Sasi, Renjith; Rao, Talasila P; Devaki, Sudha J

    2014-03-26

    In the present work, we describe the preparation, properties, and applications of novel ionic liquid crystalline quaternary ammonium salts (QSs) of 3-pentadecylphenol, a bio-based low-cost material derived from cashew nut shell liquid. Amphotropic liquid crystalline phase formation in QSs was characterized using a combination of techniques, such as DSC, PLM, XRD, SEM, and rheology, which revealed the formation of one, two, and three dimensionally ordered mesophases in different length scales. On the basis of these results, a plausible mechanism for the formation of specific modes of packing in various mesophases was proposed. Observation of anisotropic ionic conductivity and electrochemical stability suggests their application as a solid electrolyte.

  14. Interionic pair potentials and partial structure factors of compound-forming quaternary NaSn liquid alloy: First principle approach

    Indian Academy of Sciences (India)

    Anil Thakur; P K Ahluwalia

    2007-10-01

    In this paper formulae for partial structure factors have been used to study partial structure factors of compound-forming quaternary liquid alloys by considering Hoshino's m-component hard-sphere mixture, which is based on Percus-Yevic equation of Hiroike. Formulae are applied to NaSn (Na, Sn, NaSn, Na3Sn) which is considered as a quaternary liquid mixture with the formation of two compounds simultaneously. We have compared the total structure factors for ternary and quaternary alloys with experimental total structure factors which are found to be in good agreement. This suggests that, for suitable stoichiometric composition, two compounds are formed simultaneously. The hard-sphere diameters needed have been calculated using Troullier and Martins ab-initio pseudopotentials.

  15. Role of quaternary additions on dislocated martensite, retain austenite and mechanical properties of Fe/Cr/C structural steels

    Energy Technology Data Exchange (ETDEWEB)

    Rao, B.V.N.

    1978-02-01

    The influence of quaternary alloy additions of Mn and Ni to Fe/Cr/C steels which have been designed to provide superior mechanical properties has been investigated. Transmission electron microscopy and x-ray analysis revealed increasing amounts of retained austenite with Mn up to 2 w/o and with 5 w/o Ni additions after quenching from 1100/sup 0/C. This is accompanied by a corresponding improvement in toughness properties of the quaternary alloys. In addition, the generally attractive combinations of strength and toughness in these quaternary alloys is attributed to the production of dislocated lath martensite from a homogeneous austenite phase free from undissolved alloy carbides. Grain-refining resulted in a further increase in the amount of retained austenite.

  16. Nickel-catalyzed enantioselective hydrovinylation of silyl-protected allylic alcohols:An efficient access to homoallylic alcohols with a chiral quaternary center

    Institute of Scientific and Technical Information of China (English)

    2010-01-01

    Asymmetric hydrovinylation of silyl-protected allylic alcohols catalyzed by nickel complexes of chiral spiro phosphoramidite ligands was developed.A series of homoallylic alcohols with a chiral quaternary center were produced in high yields(up to 97%) and high enantioselectivities(up to 95% ee).The reaction provides an efficient method for preparing bifunctional compounds with a chiral quaternary carbon center.

  17. Porous polymers bearing functional quaternary ammonium salts as efficient solid catalysts for the fixation of CO2 into cyclic carbonates

    Science.gov (United States)

    Cai, Sheng; Zhu, Dongliang; Zou, Yan; Zhao, Jing

    2016-07-01

    A series of porous polymers bearing functional quaternary ammonium salts were solvothermally synthesized through the free radical copolymerization of divinylbenzene (DVB) and functionalized quaternary ammonium salts. The obtained polymers feature highly cross-linked matrices, large surface areas, and abundant halogen anions. These polymers were evaluated as heterogeneous catalysts for the synthesis of cyclic carbonates from epoxides and CO2 in the absence of co-catalysts and solvents. The results revealed that the synergistic effect between the functional hydroxyl groups and the halide anion Br- afforded excellent catalytic activity to cyclic carbonates. In addition, the catalyst can be easily recovered and reused for at least five cycles without significant loss in activity.

  18. Electronic properties and chemical bonding in quaternary arsenide oxides LaZnAsO and YZnAsO

    Energy Technology Data Exchange (ETDEWEB)

    Bannikov, V.V.; Shein, I.R. [Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences, Pervomaiskaya, 91, 620041, Ekaterinburg (Russian Federation); Ivanovskii, A.L., E-mail: ivanovskii@ihim.uran.ru [Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences, Pervomaiskaya, 91, 620041, Ekaterinburg (Russian Federation)

    2009-07-15

    First principles FLAPW-GGA band structure calculations are employed to obtain the structural, electronic properties and chemical bonding picture for two related phases, namely, quaternary arsenide oxides LaZnAsO and YZnAsO. These compounds are found to be direct-transition type semiconductors with the GGA gaps of about 0.65-1.30 eV. The peculiarities of chemical bonding in these phases are investigated and discussed in comparison with quaternary arsenide oxide LaFeAsO-a basic phase for the newly discovered 26-55 K superconductors.

  19. Active Faulting and Quaternary Landforms Deformation Related to the Nain Fault

    Directory of Open Access Journals (Sweden)

    Abolghasem Gourabi

    2011-01-01

    Full Text Available Problem statement: Landforms developed across terrain defining boundary the Nain fault have imprints of recent tectonic activity in the west region of Central Iran. Depositional landforms such as alluvial fans bear signatures of later phases of tectonic activity in the form of faulting of alluvial fan deposits and development of fault traces and scarps within 100 km long and a NW-SE-trending zone, 1000-2000 m wide. Approach: We are addressing the neotectonic landforms based on detailed field work carried out in the Nain exposed active fault segments which brought forward some outstanding morphtectonic evidence of quaternary tectonically activities. Tectonic geomorphology applied to the Nain fault suggests recent subsurface activity along the Nain fault and an interconnecting faulting network of roughly NW-SE-trending, right-lateral, strike-slip segments and mostly NW-SE-oriented, transtensional to normal faults. Results: Evidence for recent activity is provided by faulted Pleistocene-Holocene deposits, fresh scarps in Late Quaternary deposits, 8-15 m lateral offsets locally affecting the drainage pattern of the area, ground creeping, aligning of series of spring faults, deflected streams and fault trace over recent alluvial fans. The existences of strike-slip faults system in the Nain area can be implications for seismic hazard. Conclusion: Motion along these structures suggests, in fact, that cumulative displacements include normal, transtensional and strike-slip components. Based on all evidence of active tectonics, earthquake risk and occurrence area is significant.

  20. Partial delignification of wood and membrane preparation using a quaternary ammonium ionic liquid

    Science.gov (United States)

    Miao, Jiaojiao; Yu, Yongqi; Jiang, Zeming; Tang, Lan; Zhang, Liping

    2017-01-01

    This work determined that southern yellow pine wood can almost be completely dissolved in the quaternary ammonium ionic liquid tetrabutylammonium acetate with dimethyl sulfoxide (in a 2:8 mass ratio), after minimal grinding, upon heating at 85 °C for three dissolution/reconstitution cycles, each 1.5 h. Approximately 34.6% of the native lignin and 67.4% of the native carbohydrates present in the original wood can subsequently be extracted, respectively, and were assessed. A gradual decrease in lignin with increased extraction cycles resulted in increased crystallinity index of the cellulose II in the cellulose-rich residue, as confirmed by X-ray diffraction. An increasingly homogeneous macrostructure in the cellulose-rich residue was also evident from scanning electron microscopy images. Membranes cast directly from either wood or cellulose-rich residue solutions in the same tetrabutylammonium acetate/dimethyl sulfoxide system, were prepared using a papermaking-like process. Morphological and mechanical studies indicated that lignin extraction made the membranes more uniform and flexible. Systematic increases in the fibril lengths and orientations of the recovered materials were also found with decreasing lignin contents on the basis of atomic force microscopy analysis. This work demonstrates that relatively efficient partial separation of pine wood and subsequent membrane preparation are possible using a quaternary ammonium ionic liquid. PMID:28266507

  1. Polydimethylsiloxane-polymethacrylate block copolymers tethering quaternary ammonium salt groups for antimicrobial coating

    Energy Technology Data Exchange (ETDEWEB)

    Qin, Xiaoshuai; Li, Yancai; Zhou, Fang; Ren, Lixia; Zhao, Yunhui, E-mail: zhaoyunhui@tju.edu.cn; Yuan, Xiaoyan

    2015-02-15

    Highlights: • A series of PDMS-b-QPDMAEMA block copolymers were synthesized via RAFT polymerization. • The composition and morphology of the copolymer films strongly depended on the content of QPDMAEMA. • Migration of QPDMAEMA blocks toward surface was promoted when contacting with water. • Heterogeneous film surfaces with higher N{sup +} content exhibited more obvious antimicrobial activity. - Abstract: Block copolymers PDMS-b-PDMAEMA were synthesized via reversible addition-fragmentation chain transfer (RAFT) polymerization involving N,N-dimethylaminoethyl methacrylate (DMAEMA) by using poly(dimethylsiloxane) (PDMS) macro-chain transfer agent. And, the tertiary amino groups in PDMAEMA were quaternized with n-octyliodide to provide quaternary ammonium salts (QPDMAEMA). The well-defined copolymers generated composition variation and morphology evolvement on film surfaces, which were characterized by X-ray photoelectron spectroscopy, atomic force microscopy, and contact angle measurements. The results indicated that the enrichment of QPDMAEMA brought about lower elemental ratios of Si/N on the film surfaces. The surface morphologies evolved with the variations of QPDMAEMA content, and the variation trend of film roughness was exactly opposite to that of water contact angle hysteresis. With regard to structure-antimicrobial relationships, the copolymer films had more evident antimicrobial activity against Gram-positive, Bacillus subtilis, and the surfaces with heterogeneous morphology and higher N{sup +} content presented better antimicrobial activity. The functionalized copolymers based PDMS and quaternary ammonium salts materials have the potential applications as antimicrobial coatings.

  2. Growth of ternary and quaternary cubic III-nitrides on 3C-SiC substrates

    Energy Technology Data Exchange (ETDEWEB)

    Schoermann, J.; Potthast, S.; Schnietz, M.; Li, S.F.; As, D.J.; Lischka, K. [Department of Physics, University of Paderborn, Warburger Str. 100, 33095 Paderborn (Germany)

    2006-06-15

    Cubic GaN, Al{sub x}Ga{sub 1-x}N/GaN multiple quantum wells and quaternary Al{sub x}Ga{sub y}In{sub 1-x-y}N layers were grown by plasma assisted molecular beam epitaxy on 3C-SiC substrates. Using the intensity of a reflected high energy electron beam as a probe optimum growth conditions of c-III nitrides were found, when a 1 monolayer Ga coverage is formed at the growing surface. Clear RHEED oscillations during the initial growth of Al{sub x}Ga{sub 1-x}N/GaN quantum wells were observed. X-ray diffraction measurements of these quantum well structures show clear satellite peaks indicating smooth interfaces. Growth of quaternary Al{sub x}Ga{sub y}In{sub 1-x-y}N lattice matched to GaN were demonstrated. (copyright 2006 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  3. Calcium Nodules as a Proxy for Quaternary Paleoclimate Change on China's Loess Plateau.

    Science.gov (United States)

    He, Wenming; He, Hongming; Zhu, Mingyong

    2015-01-01

    Different proxies have been used to investigate Quaternary paleoclimate change. Here, we used weathering of calcium nodules in paleosols on China's Loess Plateau as a proxy for Quaternary paleoclimate changes to provide an alternative indicator of these changes. Paleosol and carbonate nodules were collected from Luochuan and Lantian counties in Shaanxi Province, China. We found that this approach allowed quantitative reconstruction of temperature, rainfall, soil mineral composition, and the effects of weathering and leaching. The changes in carbonate content in the loess and paleosol sequences were controlled by alternating dry and wet climatic conditions. Nodule formation conditions were directly affected by the leaching and migration of elements. The loess and paleosol sequences developed calcium nodules, and their formation was closely related to the rainfall and leaching characteristics of the paleoclimate. The paleoclimate and soil minerals affected the vegetation types and directly influenced changes in the soil. During formation of the calcium nodules, the surface vegetation evolved slowly, and the number of species and quantity of vegetation both decreased.

  4. Research of the Late Quaternary Recent Activity of the Middle Segment of Kouquan Fault

    Institute of Scientific and Technical Information of China (English)

    Xu Wei; Liu Xudong; Zhang Shimin

    2012-01-01

    Systematic research of the characteristics of late Quaternary activity of the middle part of Kouquan fault has been done through conducting 1:50000 geologic mapping combining with remote sensing interpretation of spot imaging, field validating and chronology research of the research area. Studies suggest that the middle part of Kouquan fault has had strong activity since the late Quaternary which controls the tectonic evolvement of the nearby mountains and Datong basin. The recent activity of this fault has faulted the sandy gravel layers of T1 terrace and the lower part of dark loessial soils over the terrace on the north of Chanfang village. The maximum vertical displacement is over 3m in the area between Xiaoyukou village and Louzikou village, and to the south of Dayukou village and the north of Emaokou village, the displacement decreases to 0. 5m and 0. 25m respectively. Based on the recent faulted landforms and combined with dating, we determined the age of recent activity of the fault in the research area to be between 7. 71ka B.P. to 3. 00 ka B.P. Discussions are made on this in combination with previous research.

  5. Energy-dependent relaxation time in quaternary amorphous oxide semiconductors probed by gated Hall effect measurements

    Science.gov (United States)

    Socratous, Josephine; Watanabe, Shun; Banger, Kulbinder K.; Warwick, Christopher N.; Branquinho, Rita; Barquinha, Pedro; Martins, Rodrigo; Fortunato, Elvira; Sirringhaus, Henning

    2017-01-01

    Despite the success of exploiting the properties of amorphous oxide semiconductors for device applications, the charge transport in these materials is still not clearly understood. The observation of a definite Hall voltage suggests that electron transport in the conduction band is free-electron-like. However, the temperature dependence of the Hall and field-effect mobilities cannot be explained using a simple bandlike model. Here, we perform gated Hall effect measurements in field-effect transistors, which allow us to make two independent estimates of the charge carrier concentration and determine the Hall factor providing information on the energy dependence of the relaxation time. We demonstrate that the Hall factor in a range of sputtered and solution-processed quaternary amorphous oxides, such as a-InGaZnO, is close to two, while in ternary oxides, such as InZnO, it is near unity. This suggests that quaternary elements like Ga act as strong ionized impurity scattering centers in these materials.

  6. Enrichment of arsenic in the Quaternary sediments from Ankaleshwar industrial area, Gujarat, India: an anthropogenic influence.

    Science.gov (United States)

    Shirke, K D; Pawar, N J

    2015-09-01

    Arsenic (As) contamination of sediments and waters is known from Bengal and other parts of eastern and central India. However, there is paucity of reports that document occurrence of As in Quaternary sediments from western India. In this paper, we report the enrichment of As in the Quaternary sediments of Ankaleshwar area in the western Indian state of Gujarat. Twenty-five surface and five profile samples were analyzed that indicated spatial and vertical distribution of As in the sediments. The As content of fine size fractions (63 μm) compared with upper continental crust (UCC) and standard shale indicates anomalous As enrichment that is supported by moderate to high geo-accumulation index (Igeo) as well as pollution index (Pi). Enrichment of As is seen in surface sediments from the industrial and urban land use regions, followed by oil field and agricultural land suggesting strong influence of anthropogenic factors. Although the arsenic concentration decreases with depth, the relatively higher values of As coupled with Igeo and Pi index values suggest downward migration of metal that is likely to contaminate groundwater. This calls for urgent remediation so that the ill effects of As contamination can be minimized.

  7. Surface Induced Dissociation Yields Quaternary Substructure of Refractory Noncovalent Phosphorylase B and Glutamate Dehydrogenase Complexes

    Science.gov (United States)

    Ma, Xin; Zhou, Mowei; Wysocki, Vicki H.

    2014-03-01

    Ion mobility (IM) and tandem mass spectrometry (MS/MS) coupled with native MS are useful for studying noncovalent protein complexes. Collision induced dissociation (CID) is the most common MS/MS dissociation method. However, some protein complexes, including glycogen phosphorylase B kinase (PHB) and L-glutamate dehydrogenase (GDH) examined in this study, are resistant to dissociation by CID at the maximum collision energy available in the instrument. Surface induced dissociation (SID) was applied to dissociate the two refractory protein complexes. Different charge state precursor ions of the two complexes were examined by CID and SID. The PHB dimer was successfully dissociated to monomers and the GDH hexamer formed trimeric subcomplexes that are informative of its quaternary structure. The unfolding of the precursor and the percentages of the distinct products suggest that the dissociation pathways vary for different charge states. The precursors at lower charge states (+21 for PHB dimer and +27 for GDH hexamer) produce a higher percentage of folded fragments and dissociate more symmetrically than the precusors at higher charge states (+29 for PHB dimer and +39 for GDH hexamer). The precursors at lower charge state may be more native-like than the higher charge state because a higher percentage of folded fragments and a lower percentage of highly charged unfolded fragments are detected. The combination of SID and charge reduction is shown to be a powerful tool for quaternary structure analysis of refractory noncovalent protein complexes, as illustrated by the data for PHB dimer and GDH hexamer.

  8. Composition dependences of thermodynamical properties associated with Pb-free ternary, quaternary, and quinary solder systems

    Science.gov (United States)

    Dogan, A.; Arslan, H.

    2016-05-01

    In the present study, Chou's General Solution Model (GSM) has been used to predict the enthalpy and partial enthalpies of mixing of the liquid Ag-In-Sn ternary, Ag-In-Sn-Zn quaternary, and Ag-Au-In-Sn-Zn quinary systems. These are of technical importance to optimize lead-free solder alloys, in selected cross-sections: x In/ x Sn = 0.5/0.5 (ternary), Au-In0.1-Sn0.8-Zn0.1, Ag-In0.1-Sn0.8-Zn0.1 (quaternary), and t = x Au/ x In = 1, x In = x Sn = x Zn (quinary) at 1173, 773, and 773 K, respectively. Moreover, the activity of In content in the ternary alloy system Ag-In-Sn has been calculated and its result is compared with that determined from the experiment, while the activities of Ag contents associated with the alloys mentioned above have been calculated. The other traditional models such as of Colinet, Kohler, Muggianu, Toop, and Hillert are also included in calculations. Comparing those calculated from the proposed GSM with those determined from experimental measurements, it is seen that this model becomes considerably realistic in computerization for estimating thermodynamic properties in multicomponent systems.

  9. Quaternary deposits and weathered bedrock material as a source of dangerous radon emissions in Estonia

    Directory of Open Access Journals (Sweden)

    Petersell Valter

    2015-06-01

    Full Text Available The risk of dangerous radon emissions in Estonia is high, being among the highest in Europe. In almost 33 per cent of Estonian land area, the content of radon in soil-contained air exceeds the safe limit for unrestricted construction (50 kBq/m3. In such high radon-risk areas the concentration of radon in soil-contained air ranges from 50 to 400 kBq/m3, in a few cases reaching up to 2,100 kBq/m3 exceeding the permitted level for residential areas. The situation is particularly serious in the northernmost part of the country, where uranium-rich graptolite argillite (Dictyonema shale and the Obolus phosphorite are close to ground surface and their particles are constituent parts of Quaternary deposits. Radon emissions from bedrock have been investigated in detail, but to date Quaternary strata as a source of radon emissions are poorly studied. According to our measurements the highest concentrations of radon are related to tills containing clasts and fines of graptolite argillite and phosphorite. Glacial deposits include also granitoidal material, containing U, Th and K, which have been transported by glaciers from the outcrop areas of crystalline basement rocks in Finland and the Gulf of Finland. Due to weathering, outwash and repeated redeposition other genetic types are poorer in radioactive elements and they are weaker sources of radon.

  10. Shaping quaternary assemblies of water-soluble non-peptide helical foldamers by sequence manipulation

    Science.gov (United States)

    Collie, Gavin W.; Pulka-Ziach, Karolina; Lombardo, Caterina M.; Fremaux, Juliette; Rosu, Frédéric; Decossas, Marion; Mauran, Laura; Lambert, Olivier; Gabelica, Valérie; Mackereth, Cameron D.; Guichard, Gilles

    2015-11-01

    The design and construction of biomimetic self-assembling systems is a challenging yet potentially highly rewarding endeavour that contributes to the development of new biomaterials, catalysts, drug-delivery systems and tools for the manipulation of biological processes. Significant progress has been achieved by engineering self-assembling DNA-, protein- and peptide-based building units. However, the design of entirely new, completely non-natural folded architectures that resemble biopolymers (‘foldamers’) and have the ability to self-assemble into atomically precise nanostructures in aqueous conditions has proved exceptionally challenging. Here we report the modular design, formation and structural elucidation at the atomic level of a series of diverse quaternary arrangements formed by the self-assembly of short amphiphilic α-helicomimetic foldamers that bear proteinaceous side chains. We show that the final quaternary assembly can be controlled at the sequence level, which permits the programmed formation of either discrete helical bundles that contain isolated cavities or pH-responsive water-filled channels with controllable pore diameters.

  11. Paragenesia of Quaternary pediments and river terraces on the north piedmont of Wutai Mountains

    Institute of Scientific and Technical Information of China (English)

    ZHANG ShiMin; REN JunJie; NIE GaoZhong

    2007-01-01

    A study has been made of the paragenetic relations of the pediments and river terraces on the northern piedmont of Wutai Mountains via geomorphologic mapping of 1:10000 scale, and an analysis on the role of tectonic, climatic, and drainage factors in the parageneses. The Quaternary pediments and river terraces on the north piedmont of Wutai Mountains united to constitute six steps of geomorphic surfaces. The episodic uplifting of fault blocks was the dominant factor in the formation of the unified surfaces, however climatic change and drainage diversities led to undulation of the surfaces. The second terrace of Yangyan River (T2) was formed in the last glacial maximum, when the river was in aggradational state. The third to fifth terraces were formed in interglacial stages, when the river was in equilibrium or degradational state. It is inferred that climate had no insignificant effect on the river incision caused by tectonic uplifting. In light of terraces dating, since the Quaternary the Wutai fault-block mountains experienced six rapid uplifting events, and the starting time of the last four events was respectively 1.2, 0.6, 0.13, and 0.02 Ma B.P.

  12. Aqueous two-phase system based on natural quaternary ammonium compounds for the extraction of proteins.

    Science.gov (United States)

    Zeng, Chao-Xi; Xin, Rui-Pu; Qi, Sui-Jian; Yang, Bo; Wang, Yong-Hua

    2016-02-01

    Aqueous two-phase systems, based on the use of natural quaternary ammonium compounds, were developed to establish a benign biotechnological route for efficient protein separation. In this study, aqueous two-phase systems of two natural resources betaine and choline with polyethyleneglycol (PEG400/600) or inorganic salts (K2 HPO4 /K3 PO4 ) were formed. It was shown that in the K2 HPO4 -containing aqueous two-phase system, hydrophobic interactions were an important driving force of protein partitioning, while protein size played a vital role in aqueous two-phase systems that contained polyethylene glycol. An extraction efficiency of more than 90% for bovine serum albumin in the betaine/K2 HPO4 aqueous two-phase system can be obtained, and this betaine-based aqueous two-phase system provided a gentle and stable environment for the protein. In addition, after investigation of the cluster phenomenon in the betaine/K2 HPO4 aqueous two-phase systems, it was suggested that this phenomenon also played a significant role for protein extraction in this system. The development of aqueous two-phase systems based on natural quaternary ammonium compounds not only provided an effective and greener method of aqueous two-phase system to meet the requirements of green chemistry but also may help to solve the mystery of the compartmentalization of biomolecules in cells.

  13. Nature and Timing of Quaternary glaciation in the Himalaya: Review and Speculation

    Science.gov (United States)

    Owen, L. A.

    2012-12-01

    Reconstructions of the extent and defining the timing of Quaternary glaciation across the Himalaya is an important step towards understanding the nature of long-term (centennial-millennial scale) climate-glacier dynamics in the high mountains of Central Asia. Recent efforts, aided by extensive programs of mapping and numerical dating, are beginning to more accurately define the extent and timing of Quaternary glaciation throughout the Himalayan-Tibetan orogen. The picture that is emerging is one of complex variation in the timing and extent of glaciation within and between regions. This variation is likely controlled by regional differences in the role of the major climatic systems that influence the region over time and topographic factors. A transect across the western end of the Himalayan-Tibetan orogen, including detailed studies in the Lahul Himalaya, Zanskar, Ladakh, Hunza and the Pamir, illustrates this complexity. This transect has the potential, when examined in more detail using newly developing numerical dating, and geomorphic and sedimentologic methods, to derive high-resolution records of glaciation that will help in understanding the complex relationship between climate-glacier dynamics and topography.

  14. Pre-Wisconsinan mammals from Jamaica and models of late Quaternary extinction in the greater Antilles

    Science.gov (United States)

    MacPhee, R. D. E.; Ford, Derek C.; McFarlane, Donald A.

    1989-01-01

    The vertebrate fauna recovered from indurated conglomerates at Wallingford Roadside Cave (central Jamaica) is shown to be in excess of 100,000 yr old according to uranium series and electron spin resonance dating. The Wallingford local fauna is therefore pre-Wisconsinan in age, and Roadside Cave is now the oldest radiometrically dated locality in the West Indies containing identifiable species of land mammals. In the absence of a good radiometric record for Quaternary paleontological sites in the Caribbean, there is no satisfactory basis for determining whether most extinct Antillean mammals died out in a "blitzkrieg"-like event immediately following initial human colonization in the mid-Holocene. Fossils of Clidomys (Heptaxodontidae, Caviomorpha), the giant Wallingford rodent, have never been found in situ in sediments of demonstrably Holocene age, and its extinction may antedate the middle Holocene. This is also a possibility for the primate Xenothrix mcgregori, although its remains have been found in loose cave earth. A major, climate-driven bout of terrestrial vertebrate extinction at about 14,000-12,000 yr B.P. has been hypothesized for the West Indies by G. Pregill and S. L. Olson ( Annual Review of Ecology and Systematics12, 75-98, 1981), but at present there is nothing to connect the disappearance of Clidomys with this event either. Quaternary extinctions in the Caribbean may prove to be of critical significance for evaluating the reality of New World blitzkrieg, but not until an effort is mounted to constrain them rigorously using modern radiometric approaches.

  15. Zero-flux planes, flux reversals and diffusion paths in ternary and quaternary diffusion

    Energy Technology Data Exchange (ETDEWEB)

    Dayananda, M.A.

    1986-05-23

    During isothermal multicomponent diffusion, interdiffusion fluxes of individual components can go to zero at zero-flux planes (ZFP) and exhibit flux reversals from one side to the other of such planes. Interdiffusion fluxes as well as the locations and compositions of ZFPs for components are determined directly from the concentration profiles of diffusion couples without the need for prior knowledge of interdiffusion coefficients. The development and identification of ZFPs is reviewed with the aid of single phase and two-phase diffusion couples investigated in the Cu-Ni-Zn system at 775/sup 0/C. ZFP locations in the diffusion zone nearly correspond to sections where the activity of a component is the same as its activity in either of the terminal alloys of a couple. Path slopes at ZFPs are uniquely dictated by the atomic mobility and thermodynamic data for the components. Discontinuous flux reversals for the components can also occur at interfaces in multiphase couples. Identification of ZFPs is also presented for diffusion in the Cu-Ni-Zn-Mn quaternary system. Analytical representation of diffusion paths for both ternary and quaternary diffusion couples is presented with the aid of characteristic path parameters.

  16. Reversible hemostatic properties of sulfabetaine/quaternary ammonium modified hyperbranched polyglycerol.

    Science.gov (United States)

    Wen, Jiying; Weinhart, Marie; Lai, Benjamin; Kizhakkedathu, Jayachandran; Brooks, Donald E

    2016-04-01

    A library of hyperbranched polyglycerols (HPGs) functionalized with different mole fractions of zwitterionic sulfabetaine and cationic quaternary ammonium ligands was synthesized and characterized. A post-polymerization method was employed that utilized double bond moieties on the dendritic HPG for the coupling of thiol-terminated ligands via UV initiated thiol-ene "click" chemistry. The proportions of different ligands were precisely controlled by varying the ligand concentration during the irradiation process. The effect of the polymer library on hemostasis was investigated using whole human blood. It was found that polymer with ≥40% of alkenes converted to positive charges and the remainder to sulfabetaines caused hemagglutination at ≥1 mg/mL, without causing red blood cell lysis. The quaternary ammonium groups can interact with the negative charged sites on the membranes of erythrocytes, which provides the bioadhesion. The zwitterionic sulfabetaine evidently provides a hydration layer to partially mask the adverse effects that are likely to be caused by cationic moieties. The polymer was also found able to enhance platelet aggregation and activation in a concentration and positive charge density-dependent manner, which would contribute to initiating hemostasis. In a variety of other assays the material was found to be largely biocompatible. The polymer-induced hemostasis is obtained by a process independent of the normal blood clotting cascade but dependent on red blood cell agglutination, where the polymers promote hemostasis by linking erythrocytes together to form a lattice to entrap the cells.

  17. Paleoclimatic, paleovegetational and provenance change in the Ganga Plain during the late Quaternary

    Indian Academy of Sciences (India)

    Shailesh Agrawal; Prasanta Sanyal; Melinda K Bera; Jitendra K Dash; Srinivasan Balakrishnan

    2013-08-01

    Present study aims at reconstructing the paleomonsoonal rainfall, paleovegetation and provenance change during the late Quaternary. Towards this, Bhognipur core, collected from the southern Ganga Plain, have been sampled for soil carbonate (SC) and soil. The 18O values of SC (18OSC) range from −7.6 to −4.9‰. The variations in 18OSC values suggest that during the late Quaternary, the monsoon intensified during MIS 3 and MIS 1 and the maximum lowering of rainfall intensity is observed during MIS 2. The 13C value of SC (13CSC), organic matter dispersed in the soil (13CSOM) and occluded in the carbonate nodules (13CNOM) ranges from −4.1 to +1.4‰, −25.6 to −16.3‰, and −27.7 to −25.0‰, respectively, implies mixed C3–C4 vegetation over the Ganga Plain. Variations in 13CSOM and 13CNOM values at same depth imply preservation problem of pristine organic matter signature. Therefore, it is important to assess the preservation of residual organic matter before using it for paleovegetational reconstruction. The monsoon-vegetation relationship indicates that relative abundances of C3–C4 vegetation were mainly driven by variations in monsoonal rainfall intensity. Using 87Sr/86Sr in SC, we show that the Himalayan river was supplying sediments in the southern part of the Ganga Plain during MIS 3.

  18. Eolian sediment responses to late Quaternary climate changes: Temporal and spatial patterns in the Sahara

    Science.gov (United States)

    Swezey, C.

    2001-01-01

    This paper presents a compilation of eolian-based records of late Quaternary climate changes in the Sahara. Although the data are relatively sparse, when viewed as a whole, they reveal a general pattern of widespread eolian sediment mobilization prior to 11,000 cal. years BP, eolian sediment stabilization from 11,000 to 5000 cal. years BP, and a return to widespread eolian sediment mobilization after 5000 cal. years BP. Furthermore, an eolian-based record from southern Tunisia reveals the existence of millennial-scale changes in eolian sediment behavior. These millennial-scale variations provide examples of eolian sediment responses to climate changes at a scale intermediate between seasonal and orbital ('Milankovitch') changes, and they are also coincident with abrupt atmospheric and oceanic changes. The general synchroneity of the eolian stratigraphic records and their coincidence with various oceanic and atmospheric changes suggest that global forcing mechanisms have influenced late Quaternary eolian sediment behavior in the Sahara. ?? 2001 Elsevier Science B.V.

  19. Enhanced water-solubility and antibacterial activity of novel chitosan derivatives modified with quaternary phosphonium salt.

    Science.gov (United States)

    Zhu, Dan; Cheng, Honghao; Li, Jianna; Zhang, Wenwen; Shen, Yuanyuan; Chen, Shaojun; Ge, Zaochuan; Chen, Shiguo

    2016-04-01

    Chitosan (CS) has been widely recognized as an important biomaterial due to its good antimicrobial activity, biocompatibility and biodegradability. However, CS is insoluble in water in neutral and alkaline aqueous solution due to the linear aggregation of chain molecules and the formation of crystallinity. This is one of the key factors that limit its practical applications. Therefore, improving the solubility of CS in neutral and alkaline aqueous solution is a primary research direction for biomedical applications. In this paper, a reactive antibacterial compound (4-(2,5-Dioxo-pyrrolidin-1-yloxycarbonyl)-benzyl)-triphenyl-phosphonium bromide (NHS-QPS) was synthesized for chemical modification of CS, and a series of novel polymeric antimicrobial agents, N-quaternary phosphonium chitosan derivatives (N-QPCSxy, x=1-2,y=1-4) were obtained. The water solubilities and antibacterial activities of N-QPCSxy against Escherichia coli and Staphylococcus aureus were evaluated compare to CS. The water solubility of N-QPCSxy was all better than that of CS at neutral pH aqueous solution, particularly, N-QPCS14 can be soluble in water over the pH range of 3 to 12. The antibacterial activities of CS derivatives were improved by introducing quaternary phosphonium salt, and antibacterial activity of N-QPCSxy increases with degree of substitution. Overall, N-QPCS14 represents a novel antibacterial polymer material with good antibacterial activity, waters solubility and low cytotoxicity.

  20. Estimates of late Quaternary mode and intermediate water silicic acid concentration in the Pacific Southern Ocean

    Science.gov (United States)

    Rousseau, Jonathon; Ellwood, Michael J.; Bostock, Helen; Neil, Helen

    2016-04-01

    The Southern Ocean plays a critical role in the exchange of carbon between the ocean and atmosphere over glacial-interglacial timescales. Hypotheses used to explain late Quaternary variations in atmospheric carbon dioxide (CO2) implicate changes in the nutrient dynamics and circulation of the Southern Ocean. Here we present silicon isotope (δ30Si) records of late Quaternary sponges and diatoms from the NZ-sector of the Southern Ocean. Analysis of our sponge δ30Si records strongly suggests that the silicic acid concentration at mode and intermediate depths was higher during the LGM and the deglacial period compared to the present day. Our diatom δ30Si record suggests biological productivity near of the Polar Front was greater during the deglacial period, but not significantly different during the LGM compared to the present day. Taking our dataset in context with other regional paleoceanographic records, we interpret the predicted elevation in LGM and deglacial silicic acid concentration to reflect a shoaling of water masses during the LGM and 'leakage' of excess Southern Ocean dissolved silicon during the deglacial period.

  1. Albedo changes, Milankovitch forcing, and late quaternary climate changes in the central Andes

    Energy Technology Data Exchange (ETDEWEB)

    Kull, C.; Grosjean, M. [Swiss Federal Inst. of Tech., Zurich (Switzerland). Dept. of Geography

    1998-11-01

    Late quaternary humidity changes resulted in substantial modifications of the land surface characteristics in the Altiplano of the Atacama desert, central Andes. Reconstructions of surface albedo, top-of-atmosphere (TOA) albedo, and shortwave net radiation in the Andes of northern Chile for 20,14,10,7 and 0 ka suggest that surface and TOA albedo increased substantially during periods of relatively humid environmental conditions (i.e., with large palaeolakes, glaciers and dense vegetation). The decrease of summer shortwave net radiation and seasonality during the late-glacial/early Holocene humid phase (14 to 10 ka) due to Earth`s surface and atmospheric characteristics added to the effect of orbitally driven negative deviations of southern Hemisphere austral summer insolation and minimum seasonality at 20 S. Therefore, in situ radiative forcing is, in contrast to the Northern Hemisphere tropics, not a suitable explanation for enhanced convective precipitation and, ultimately, humid climatic conditions. Our results suggest that late Quaternary humidity changes on the Altiplano reflect a collective response to (1) environmental changes in the source area of the moisture (e.g., reexpansion of the rain forest and increased release of latent heat over Amazonia and the Chaco, warm sea surface temperatures in the E Pacific) and, (2) large-scale circulation patterns and wave structures in the upper troposphere (strength and position of the Bolivian high, divergent flow stimulating convection over the Altiplano), or that they even reflect a response to (3) interhemispherical teleconnections. (orig.) With 5 figs., 2 tabs., 45 refs.

  2. Effect of the N-terminal residues on the quaternary dynamics of human adult hemoglobin

    Science.gov (United States)

    Chang, Shanyan; Mizuno, Misao; Ishikawa, Haruto; Mizutani, Yasuhisa

    2016-05-01

    The protein dynamics of human hemoglobin following ligand photolysis was studied by time-resolved resonance Raman spectroscopy. The time-resolved spectra of two kinds of recombinant hemoglobin expressed in Escherichia coli, normal recombinant hemoglobin and the α(V1M)/β(V1M) double mutant, were compared with those of human adult hemoglobin (HbA) purified from blood. A frequency shift of the iron-histidine stretching [ν(Fe-His)] band was observed in the time-resolved spectra of all three hemoglobin samples, indicative of tertiary and quaternary changes in the protein following photolysis. The spectral changes of the α(V1M)/β(V1M) double mutant were distinct from those of HbA in the tens of microseconds region, whereas the spectral changes of normal recombinant hemoglobin were similar to those of HbA isolated from blood. These results demonstrated that a structural change in the N-termini is involved in the second step of the quaternary structure change of hemoglobin. We discuss the implications of these results for understanding the allosteric pathway of HbA.

  3. Polydimethylsiloxane-polymethacrylate block copolymers tethering quaternary ammonium salt groups for antimicrobial coating

    Science.gov (United States)

    Qin, Xiaoshuai; Li, Yancai; Zhou, Fang; Ren, Lixia; Zhao, Yunhui; Yuan, Xiaoyan

    2015-02-01

    Block copolymers PDMS-b-PDMAEMA were synthesized via reversible addition-fragmentation chain transfer (RAFT) polymerization involving N,N-dimethylaminoethyl methacrylate (DMAEMA) by using poly(dimethylsiloxane) (PDMS) macro-chain transfer agent. And, the tertiary amino groups in PDMAEMA were quaternized with n-octyliodide to provide quaternary ammonium salts (QPDMAEMA). The well-defined copolymers generated composition variation and morphology evolvement on film surfaces, which were characterized by X-ray photoelectron spectroscopy, atomic force microscopy, and contact angle measurements. The results indicated that the enrichment of QPDMAEMA brought about lower elemental ratios of Si/N on the film surfaces. The surface morphologies evolved with the variations of QPDMAEMA content, and the variation trend of film roughness was exactly opposite to that of water contact angle hysteresis. With regard to structure-antimicrobial relationships, the copolymer films had more evident antimicrobial activity against Gram-positive, Bacillus subtilis, and the surfaces with heterogeneous morphology and higher N+ content presented better antimicrobial activity. The functionalized copolymers based PDMS and quaternary ammonium salts materials have the potential applications as antimicrobial coatings.

  4. C.A.D. representation of ternary and quaternary phase diagrams

    Science.gov (United States)

    Delao, James D.

    1986-01-01

    This work is concerned with the utilization of C.A.D. solid-modeling software for the computer representation of three-dimensional phase diagrams. The work was undertaken in two parts. First, the C.A.D. software (I-DEAS, by Structural Dynamics Research Corp.) was integrated with a variety of auxiliary Fortran 77 and I-DEAS language programs which were written specifically for the purpose of phase diagram representation. The capabilities of the resulting suite of software for three-dimensional phase diagram representation were developed and illustrated by the construction, display and manipulation of solid-model phase diagrams for a hypothetical quaternary eutectic system. The results of this work are discussed in some detail in the attached publication ('Solid-modeling: a C.A.D. Alternative for Three-dimensional Phase Diagram Representation'). Such a technique is of general applicability, having utility in both research and education. Secondly, using the C.A.D. technique, data from the literature (gleaned from some 70 separate publications), which represent experimentally determined phase boundaries, were combined to form solid-model representations of the CMS2-M2S-S ternary space diagram and the CMS2-CAS2-M2S-S quaternary liquidus projection (where C=CaO, M=MgO, A=Al2O3, and S=SiO2). These diagrams were utilized in a concurrent study of solidification in the CMAS system.

  5. Late Quaternary relative sea level in Southern California and Monterey Bay

    Science.gov (United States)

    Reynolds, Laura C.; Simms, Alexander R.

    2015-10-01

    Few records of late Quaternary relative sea level (RSL) are available for the Pacific coast of North America south of San Francisco Bay, a region where RSL data would be particularly useful for constraining vertical rates of tectonic motion. This paper provides the first regional, uplift-corrected late Quaternary RSL history for southern California derived from a compilation of 132 previously published and unpublished radiocarbon ages from nearshore, estuarine, and freshwater deposits in sediment cores from coastal southern California. We also provide a local, uplift-corrected RSL history for Monterey Bay, central California, generated from 48 radiocarbon ages from Elkhorn Slough and surrounding environments. Our resulting compilations show rapid sea-level rise from 15 ka which begins to decelerate to present mean sea level (PMSL) between 6 and 8 ka. Late Holocene (Bay in central California. Both rates of late Holocene RSL rise calculated are lower than recent RSL rates from southern California (˜1.61 ± 0.34 to 2.4 ± 1.04 mm a-1) and Monterey Bay (1.49 ± 0.95 mm a-1), derived from uplift-corrected, 20th century tide gauge data. This new RSL data fills geographical gaps in relative sea-level histories, as well as provides important datums for local tectonic processes.

  6. Formation and shape-control of hierarchical cobalt nanostructures using quaternary ammonium salts in aqueous media

    Science.gov (United States)

    Deshmukh, Ruchi; Mehra, Anurag

    2017-01-01

    Aggregation and self-assembly are influenced by molecular interactions. With precise control of molecular interactions, in this study, a wide range of nanostructures ranging from zero-dimensional nanospheres to hierarchical nanoplates and spindles have been successfully synthesized at ambient temperature in aqueous solution. The nanostructures reported here are formed by aggregation of spherical seed particles (monomers) in presence of quaternary ammonium salts. Hydroxide ions and a magnetic moment of the monomers are essential to induce shape anisotropy in the nanostructures. The cobalt nanoplates are studied in detail, and a growth mechanism based on collision, aggregation, and crystal consolidation is proposed based on a electron microscopy studies. The growth mechanism is generalized for rods, spindles, and nearly spherical nanostructures, obtained by varying the cation group in the quaternary ammonium hydroxides. Electron diffraction shows different predominant lattice planes on the edge and on the surface of a nanoplate. The study explains, hereto unaddressed, the temporal evolution of complex magnetic nanostructures. These ferromagnetic nanostructures represent an interesting combination of shape anisotropy and magnetic characteristics.

  7. Scalable Generalization of Hydraulic Conductivity in Quaternary Strata for Use in a Regional Groundwater Model

    Science.gov (United States)

    Jatnieks, J.; Popovs, K.; Klints, I.; Timuhins, A.; Kalvans, A.; Delina, A.; Saks, T.

    2012-04-01

    The cover of Quaternary sediments especially in formerly glaciated territories usually is the most complex part of the sedimentary sequences. In regional hydro-geological models it is often assumed as a single layer with uniform or calibrated properties (Valner 2003). However, the properties and structure of Quaternary sediments control the groundwater recharge: it can either direct the groundwater flow horizontally towards discharge in topographic lows or vertically, recharging groundwater in the bedrock. This work aims to present calibration results and detail our experience while integrating a scalable generalization of hydraulic conductivity for Quaternary strata in the regional groundwater modelling system for the Baltic artesian basin - MOSYS V1. We also present a method for solving boundary transitions between spatial clusters of lithologically similar structure. In this study the main unit of generalization is the spatial cluster. Clusters are obtained from distance calculations combining the Normalized Compression Distance (NCD) metric, calculated by the CompLearn parameter-free machine learning toolkit, with normalized Euclidean distance measures for coordinates of the borehole log data. A hierarchical clustering solution is used for obtaining cluster membership identifier for each borehole. Using boreholes as generator points for Voronoi tessellation and dissolving resulting polygons according to their cluster membership attribute, allows us to obtain spatial regions representing a certain degree of similarity in lithological structure. This degree of similarity and the spatial heterogeneity of the cluster polygons can be varied by different flattening of the hierarchical cluster model into variable number of clusters. This provides a scalable generalization solution which can be adapted according to model calibration performance. Using the dissimilarity matrix of the NCD metric, a borehole most similar to all the others from the lithological structure

  8. Reconnaissance study of late quaternary faulting along cerro GoDen fault zone, western Puerto Rico

    Science.gov (United States)

    Mann, P.; Prentice, C.S.; Hippolyte, J.-C.; Grindlay, N.R.; Abrams, L.J.; Lao-Davila, D.

    2005-01-01

    The Cerro GoDen fault zone is associated with a curvilinear, continuous, and prominent topographic lineament in western Puerto Rico. The fault varies in strike from northwest to west. In its westernmost section, the fault is ???500 m south of an abrupt, curvilinear mountain front separating the 270- to 361-m-high La CaDena De San Francisco range from the Rio A??asco alluvial valley. The Quaternary fault of the A??asco Valley is in alignment with the bedrock fault mapped by D. McIntyre (1971) in the Central La Plata quadrangle sheet east of A??asco Valley. Previous workers have postulated that the Cerro GoDen fault zone continues southeast from the A??asco Valley and merges with the Great Southern Puerto Rico fault zone of south-central Puerto Rico. West of the A??asco Valley, the fault continues offshore into the Mona Passage (Caribbean Sea) where it is characterized by offsets of seafloor sediments estimated to be of late Quaternary age. Using both 1:18,500 scale air photographs taken in 1936 and 1:40,000 scale photographs taken by the U.S. Department of Agriculture in 1986, we iDentified geomorphic features suggestive of Quaternary fault movement in the A??asco Valley, including aligned and Deflected drainages, apparently offset terrace risers, and mountain-facing scarps. Many of these features suggest right-lateral displacement. Mapping of Paleogene bedrock units in the uplifted La CaDena range adjacent to the Cerro GoDen fault zone reveals the main tectonic events that have culminated in late Quaternary normal-oblique displacement across the Cerro GoDen fault. Cretaceous to Eocene rocks of the La CaDena range exhibit large folds with wavelengths of several kms. The orientation of folds and analysis of fault striations within the folds indicate that the folds formed by northeast-southwest shorTening in present-day geographic coordinates. The age of Deformation is well constrained as late Eocene-early Oligocene by an angular unconformity separating folDed, Deep

  9. Specialization in Plant-Hummingbird Networks Is Associated with Species Richness, Contemporary Precipitation and Quaternary Climate-Change Velocity

    Science.gov (United States)

    Dalsgaard, Bo; Magård, Else; Fjeldså, Jon; Martín González, Ana M.; Rahbek, Carsten; Olesen, Jens M.; Ollerton, Jeff; Alarcón, Ruben; Cardoso Araujo, Andrea; Cotton, Peter A.; Lara, Carlos; Machado, Caio Graco; Sazima, Ivan; Sazima, Marlies; Timmermann, Allan; Watts, Stella; Sandel, Brody; Sutherland, William J.; Svenning, Jens-Christian

    2011-01-01

    Large-scale geographical patterns of biotic specialization and the underlying drivers are poorly understood, but it is widely believed that climate plays an important role in determining specialization. As climate-driven range dynamics should diminish local adaptations and favor generalization, one hypothesis is that contemporary biotic specialization is determined by the degree of past climatic instability, primarily Quaternary climate-change velocity. Other prominent hypotheses predict that either contemporary climate or species richness affect biotic specialization. To gain insight into geographical patterns of contemporary biotic specialization and its drivers, we use network analysis to determine the degree of specialization in plant-hummingbird mutualistic networks sampled at 31 localities, spanning a wide range of climate regimes across the Americas. We found greater biotic specialization at lower latitudes, with latitude explaining 20–22% of the spatial variation in plant-hummingbird specialization. Potential drivers of specialization - contemporary climate, Quaternary climate-change velocity, and species richness - had superior explanatory power, together explaining 53–64% of the variation in specialization. Notably, our data provides empirical evidence for the hypothesized roles of species richness, contemporary precipitation and Quaternary climate-change velocity as key predictors of biotic specialization, whereas contemporary temperature and seasonality seem unimportant in determining specialization. These results suggest that both ecological and evolutionary processes at Quaternary time scales can be important in driving large-scale geographical patterns of contemporary biotic specialization, at least for co-evolved systems such as plant-hummingbird networks. PMID:21998716

  10. Severnaya Zemlya, Arctic Russia: a nucleation area for Kara Sea ice sheets during the Middle to Late Quaternary

    NARCIS (Netherlands)

    Moller, P.; Lubinski, D.J.; Ingolfsson, O.; Forman, S.L.; Seidenkrantz, M.S.; Bolshiyanov, D.Y.; Lokrantz, H.; Antonov, O.; Pavlov, M.; Ljung, K.; Zeeberg, J.J.; Andreev, A.

    2006-01-01

    Quaternary glacial stratigraphy and relative sea-level changes reveal at least four expansions of the Kara Sea ice sheet over the Severnaya Zemlya Archipelago at 79°N in the Russian Arctic, as indicated from tills interbedded with marine sediments, exposed in stratigraphic superposition, and from ra

  11. C-H hydroxylation of phosphonates with oxygen in [bmIm]OH To produce quaternary α-hydroxy phosphonates.

    Science.gov (United States)

    Li, Xiangguang; Jin, Cheng; Gu, Lijun

    2015-02-20

    A highly efficient and mild [bmIm]OH-catalyzed α-hydroxylation of phosphonates using O2 as the oxygen source is described. The employment of ionic liquid under mild reaction conditions makes this transformation green and practical. Especially, this reaction provided a novel and convenient methodology for the construction of quaternary α-hydroxy phosphonates.

  12. Stable isotopes reflect the ecological stability of two high-elevation mammals from the late Quaternary of Colorado

    Science.gov (United States)

    McLean, Bryan S.; Emslie, Steven D.

    2012-05-01

    The vertebrate fossil record of Cement Creek Cave, Colorado, spans from > 45,000 yr ago to the present and represents the richest stratified series of high-elevation (> 2900 m) mammal remains known from the late Quaternary of North America. Stable carbon and oxygen isotope analyses of tooth enamel were used to assess potential ecological responses of two species found commonly throughout the cave, Yellow-bellied marmots (Marmota flaviventris) and Bushy-tailed woodrats (Neotoma cinerea), to late Quaternary climate and environmental changes of the Southern Rocky Mountains. Results indicate that despite such perturbations, the dietary ecologies of both species were maintained across this period. Neither taxon shifted to consuming C4 taxa or different C3 functional groups; similarly, no significant shifts in surface water use were detected. Variations in enamel δ13C were observed, however, that represent the physiological responses of high-elevation plants to changing levels of late Quaternary atmospheric CO2. While our findings extend both the geographic and elevational record of this plant CO2 response, they simultaneously highlight the ecological stability of high-elevation M. flaviventris and N. cinerea during climate changes of late Quaternary magnitude.

  13. Microstructural aspects of manganese metal during its electrodeposition from sulphate solutions in the presence of quaternary amines

    Energy Technology Data Exchange (ETDEWEB)

    Padhy, Subrat Kumar [CSIR – Institute of Minerals and Materials Technology, Council of Scientific and Industrial Research, Bhubaneswar 751013 (India); Academy of Scientific and Innovative Research, CSIR Campus, CSIR Road, Taramani, Chennai 600 113 (India); Patnaik, P. [CSIR – Institute of Minerals and Materials Technology, Council of Scientific and Industrial Research, Bhubaneswar 751013 (India); Tripathy, B.C., E-mail: bankim@immt.res.in [CSIR – Institute of Minerals and Materials Technology, Council of Scientific and Industrial Research, Bhubaneswar 751013 (India); Academy of Scientific and Innovative Research, CSIR Campus, CSIR Road, Taramani, Chennai 600 113 (India); Bhattacharya, I.N. [CSIR – Institute of Minerals and Materials Technology, Council of Scientific and Industrial Research, Bhubaneswar 751013 (India)

    2015-03-15

    Graphical abstract: - Highlights: • Quaternary amines produced smooth and bright manganese electrodeposits. • TEABr produced smooth and bright deposits with euhedral shaped crystals. • TBABr produced dendritic deposits with elongated poly-nodular crystals. • All the quaternary amines behaved as cathode polarisers. • TEABr was found to be the most efficient organic additive. - Abstract: In the present study investigation was made on the electrodeposition of manganese from sulphate solutions in the presence of quaternary amines TEABr, TPABr and TBABr. The concentrations of these additives were varied over a relatively broad range to evaluate their effect on the deposit morphology and preferred crystal orientations of the electrodeposited metal. TEABr resulted in bright and smooth manganese electrodeposits giving euhedral shape to the crystals with distinct triple junction points. TPABr also showed similar results at lower concentrations. However, TBABr resulted in the formation of dendritic growths with elongated poly-nodular crystals similar to that of Paragorgia corals having uniform multistep growths. The presence of these quaternary amines in the electrolyte causes polarisation of the cathode. TBABr being the strongest cathode polariser adsorbs strongly on the cathode resulting in poor deposit quality. TEABr was found to be the most efficient additive producing the desired quality manganese electrodeposit.

  14. Tectonic and climatic controls on late quaternary sedimentary processes in a neotectonic intramontane basin. (The Pitalito Basin, South Colombia).

    NARCIS (Netherlands)

    Bakker, J.

    1990-01-01

    The present study deals with the influence of tectonics and climatic changes on sedimentation patterns in the Quaternary Pitalito Basin (lat. 1°52'N, long. 76°02'W). This intramontane sedimentary basin is 15 km in width and 20 kin in length and is located in the Eastern Cordillera of the southern Co

  15. Survival of adhering staphylococci during exposure to a quaternary ammonium compound evaluated by using atomic force microscopy imaging

    NARCIS (Netherlands)

    Crismaru, Mihaela; Asri, Lia ATW; Loontjens, Jacobus; Krom, Bastiaan P; de Vries, Jacob; van der Mei, Henderina; Busscher, Hendrik

    2011-01-01

    Effects of a quaternary ammonium compound (QAC) on the survival of adhering staphylococci on a surface were investigated using atomic force microscopy (AFM). Four strains with different minimal inhibitory concentrations (MIC) and minimal bactericidal concentrations (MBC) for the QAC were exposed to

  16. The impact of the Quaternary glaciations on the Durmitor mountains (Montenegro) as understood from detailed geomorphological mapping

    Science.gov (United States)

    Frankl, Amaury; Annys, Klaas; Spalević, Velibor; Čurović, Milic; Borota, Dragan; Nyssen, Jan

    2014-05-01

    In the Balkans, few studies exist that highlight the impact of the Quaternary glaciations on the landscape. However, the impact of the Quaternary glaciations was important and the glacial imprint remains well preserved in the limestone massifs where karst hydrology prevails. This study presents a detailed geomorphological map at scale 1:10,000 that was prepared of the northeastern Durmitor mountains (2523 m a.s.l.) and the plateau Jezerska Površ (47 km², Dinaric Alps, Montenegro). Mapping occurred from an intensive fieldwork campaign and remote sensing analysis, and was finalized in a GIS environment. The basic components of the legend are (i) processes/genesis, (ii) materials, (iii) morphometry/morphography, (iv) hydrography, (v) vegetation and (vi) anthropogenic features, that are organized as a box-of-bricks type of legend (AGRG-system). The geomorphological setting of the area consists of Mesozoic limestones which were eroded physically by Quaternary glacial and periglacial activity and chemically during interglacials. Glacial deposits of three Middle to Late Pleistocene glacial phases exist on the plateau, only scarcely dissected by meltwater channels. In the mountains, Holocene glacier retreat left behind a series of well-preserved recessional moraines and a static glacier remains in the cirque head. The presented map serves as a valuable tool for Quaternary research in the Durmitor Mountains, and serves as an example on the interaction between glacial and karst processes. Keywords: Debeli Namet glacier, Dinaric Alps, Geographic Information System (GIS), Glacial landforms, Karst.

  17. Discovery and Significance of Quaternary Glacial Vestiges in the Hexigten Area of the Southern Da Hinggan Mountains, Inner Mongolia

    Institute of Scientific and Technical Information of China (English)

    SUN Hongyan; TIAN Mingzhong; WU Fadong; ZHANG Jianping

    2005-01-01

    The question whether there have been Quaternary glaciations in the Da Hinggan area has puzzled glacial geologists for many years because no sufficient glacial evidence has been found in this area. The study of Quaternary glaciers in the Da Hinggan area is also a key issue of the glaciology in China because of the special location of this area. In the past two years,a large number of complete and typical glacial vestiges have been found in Hexigten in the southern Da Hinggan Mountains,such as fossil cirque groups,horns,knife-edge crests,terminal moraines,glacial stepped stones.These landforms are located at a watershed,which are thus impossible to be formed due to tectonic processes,water or weathering,but can only be formed by glaciation. The calculated flat indexes of the fossil cirques in the Hexigten are 1.7-4.5,4-5 and 1.3-5,which are within the range of 1.7-5 that is the flat index of real cirques. The typical and complete moraines have also been found in this area. All these glacial vestiges prove that the Quaternary glaciers did exist in the Da Hinggan Mountains of eastern China. Thus,it is of important scientific significance for the research on Chinese,even the global climatic and environmental evolution since the Quaternary.

  18. Poly(amido amine)s as Gene Delivery Vectors: Effects of Quaternary Nicotinamide Moieties in the Side Chains

    NARCIS (Netherlands)

    Mateos Timoneda, Miguel A.; Lok, Martin C.; Hennink, Wim E.; Feijen, Jan; Engbersen, Johan F.J.

    2008-01-01

    To evaluate the effect of quaternary nicotinamide pendant groups on gene delivery properties, a series of poly(amido amine) (co)polymers were synthesized by Michael addition polymerization of N, N-cystaminebisacrylamide with variable ratios of 1-(4-aminobutyl)-3-carbamoylpyridinium (Nic-BuNH2), and

  19. Dual catalysis for the redox annulation of nitroalkynes with indoles: enantioselective construction of indolin-3-ones bearing quaternary stereocenters.

    Science.gov (United States)

    Liu, Ren-Rong; Ye, Shi-Chun; Lu, Chuan-Jun; Zhuang, Gui-Lin; Gao, Jian-Rong; Jia, Yi-Xia

    2015-09-14

    The enantioselective redox annulation of nitroalkynes with indoles is enabled by gold/chiral phosphoric acid dual catalysis. A range of indolin-3-one derivatives bearing quaternary stereocenters at the C2 position were afforded in good yields and excellent enantioselectivities (up to 96 % ee) from readily available starting materials.

  20. separation of strontium and cesium from ternary and quaternary lithium chloride-potassium chloride salts via melt crystallization

    Directory of Open Access Journals (Sweden)

    Ammon N. Williams

    2015-12-01

    Full Text Available Separation of cesium chloride (CsCl and strontium chloride (SrCl2 from the lithium chloride-potassium chloride (LiCl-KCl salt was studied using a melt crystallization process similar to the reverse vertical Bridgeman growth technique. A ternary SrCl2-LiCl-KCl salt was explored at similar growth rates (1.8–5 mm/h and compared with CsCl ternary results to identify similarities. Quaternary experiments were also conducted and compared with the ternary cases to identify trends and possible limitations to the separations process. In the ternary case, as much as 68% of the total salt could be recycled per batch process. In the quaternary experiments, separation of Cs and Sr was nearly identical at the slower rates; however, as the growth rate increased, SrCl2 separated more easily than CsCl. The quaternary results show less separation and rate dependence than in both ternary cases. As an estimated result, only 51% of the total salt could be recycled per batch. Furthermore, two models have been explored to further understand the growth process and separation. A comparison of the experimental and modeling results reveals that the nonmixed model fits reasonably well with the ternary and quaternary data sets. A dimensional analysis was performed and a correlation was identified to semipredict the segregation coefficient.

  1. Geochemistry and petrogenesis of Quaternary volcanism from the islets in the eastern Beibu Gulf:evidence for Hainan plume

    Institute of Scientific and Technical Information of China (English)

    LI Naisheng; YAN Quanshu; CHEN Zhihua; SHI Xuefa

    2013-01-01

    Some of the islets in the eastern Beibu Gulf are covered by Quaternary volcano strata. The rock samples from these islets mainly consist of quartz tholeiites (at Shenjiandao), olivine tholeiites (at Linshidao and Xieyang-dao) and alkali basalts (at Yangpubi and Jianshidao), and basically represent four periods of the Quaternary volcanism of Hainan Island and its adjacent regions. Except for the samples from Shenjiandao, most of the Quaternary volcanics of these islets belong to alkali magma series. The trace element characteristics of all of these samples show they are OIB (oceanic island basalt)-like, which implies that their deep geodynamic setting may be related to a mantle plume. The Sr-Nd-Pb isotopic compositions show that the mantle source beneath the Quaternary strata can be regarded as a result of binary mixing between a depleted, DMM (de-pleted MORB mantle)-like source and an enriched mantle type 2 (EM2). The EM2 may be originated from the Hainan mantle plume, and has been metasomatized by carbonaceous fluids released from ancient re-cycled oceanic crust at an asthenospheric mantle level. These features, together with typical trace element ratios, reflect that the parent magma was not subjected to crustal contamination during its ascent to the surface. This study provides further petrological and geochemical evidence for the existence of the Hainan mantle plume.

  2. Phase equilibria in the palladium-rich part of the Pd-Au-Cu-Sn quaternary system

    Science.gov (United States)

    Kareva, M. A.; Kabanova, E. G.; Zhmurko, G. P.; Kuznetsov, V. N.

    2017-02-01

    The solubility of tin in the phases of Pd-Au-Sn and Pd-Cu-Sn ternary systems and a Pd-Au-Cu-Sn quaternary system with a fixed Pd: Au: Cu ratio of 11.1: 1: 4.6 is studied via microstructural, X-ray diffraction, and energy dispersive analysis. It is found that a quaternary alloy in equilibrium with a solid solution based on Pd, Au, and Sn contains a τ1 compound with structure which is derivative of the In type. It contains 15 at % Sn and is a solid solution of the same compounds identified earlier in Pd-Au-Sn and Pd-Cu-Sn ternary systems. In addition, a quaternary alloy with a content of 20 at % Sn also contains a τ2 compound with the Pd2CuSn own type and can barely dissolve gold. The obtained data are used to construct a three-dimensional model of the Pd-rich part of the isothermal tetrahedron of the Pd-Au-Cu-Sn system and diagrams of the tin solubility isolines in palladium-rich alloys of the quaternary system at 500°C.

  3. Specialization in plant-hummingbird networks is associated with species richness, contemporary precipitation and quaternary climate-change velocity.

    Science.gov (United States)

    Dalsgaard, Bo; Magård, Else; Fjeldså, Jon; Martín González, Ana M; Rahbek, Carsten; Olesen, Jens M; Ollerton, Jeff; Alarcón, Ruben; Cardoso Araujo, Andrea; Cotton, Peter A; Lara, Carlos; Machado, Caio Graco; Sazima, Ivan; Sazima, Marlies; Timmermann, Allan; Watts, Stella; Sandel, Brody; Sutherland, William J; Svenning, Jens-Christian

    2011-01-01

    Large-scale geographical patterns of biotic specialization and the underlying drivers are poorly understood, but it is widely believed that climate plays an important role in determining specialization. As climate-driven range dynamics should diminish local adaptations and favor generalization, one hypothesis is that contemporary biotic specialization is determined by the degree of past climatic instability, primarily Quaternary climate-change velocity. Other prominent hypotheses predict that either contemporary climate or species richness affect biotic specialization. To gain insight into geographical patterns of contemporary biotic specialization and its drivers, we use network analysis to determine the degree of specialization in plant-hummingbird mutualistic networks sampled at 31 localities, spanning a wide range of climate regimes across the Americas. We found greater biotic specialization at lower latitudes, with latitude explaining 20-22% of the spatial variation in plant-hummingbird specialization. Potential drivers of specialization--contemporary climate, Quaternary climate-change velocity, and species richness--had superior explanatory power, together explaining 53-64% of the variation in specialization. Notably, our data provides empirical evidence for the hypothesized roles of species richness, contemporary precipitation and Quaternary climate-change velocity as key predictors of biotic specialization, whereas contemporary temperature and seasonality seem unimportant in determining specialization. These results suggest that both ecological and evolutionary processes at Quaternary time scales can be important in driving large-scale geographical patterns of contemporary biotic specialization, at least for co-evolved systems such as plant-hummingbird networks.

  4. Age determination and development of experimental methods for quaternary fault and formation

    Energy Technology Data Exchange (ETDEWEB)

    Cheong, Chang Sik; Kim, Jeong Min; Lee, S. H.; Han, J. H.; Shin, H. S.; Cheong, Y. J. [Korea Basic Science Institute, Daejeon (Korea, Republic of); Lee, H. S. [Pukyong National Univ., Busan (Korea, Republic of); Hong, D. G. [Kangwon National Univ., Gangneung (Korea, Republic of)

    2006-02-15

    Correlation of palaeo-shoreline elevations indicates that the MQt{sub 4} terrace in Suryum site has formed during MIS 5e, which is supported by stratigraphically concordant OSL ages for NQt{sub 3} terrace sediments in Yonghan area. Sedimentological features of the trench site of the Eupcheon fault suggest multiple fault movements during the Late Quaternary. All of these observations imply that uplift rate in the middle part of the coast has been much larger than that in the northern part during 125 ka {approx} 80 ka, requiring the revision of conventional view that the Korean peninsula is tectonically very stable. The ESR data suggest that the Ilkwang fault zone has been formed by the initial surface fault activity at 2-3 Ma and reactivated at least 4 times at 1.2-1.3 Ma, 1 Ma, 0.6 Ma and 0.5 Ma, with part of adjacent NNE and NE trending faults. The Eupcheon fault has been reactivated along the boundary between fault breccia originated from Cretaceous sedimentary rocks and Tertiary lithic tuff at around 2 Ma, 1.3 Ma, and 1 Ma. It has been reactivation again along the boundary between Cretaceous sandstone and fault breccia at 0.8 Ma, and between fault breccia and Tertiary lithic tuff at 0.6 Ma. During the late Quaternary after MIS 5e, the Eupcheon fault reactivated along the boundary between fault gouges, cutting Quaternary marine terrace deposits. The ESR data for the Eupcheon fault, however, should be carefully reexamined because it is probable that the samples contain clay components of weathering, not cataclastic origin. A weathering profile developed in the Suryum site was disturbed by tectonic movement that appears to be a simple one-time reverse faulting event based on field observations. A comparative analysis of the mineralogy, micromorphology, and chemistry of the weathering profile and fault gouge, however, reveals that both the microfissures in the deformed weathering profile and larger void spaces along the fault plane were filled with multi

  5. Ion-pair hollow-fiber liquid-phase microextraction of the quaternary ammonium surfactant dicocodimethylammonium chloride.

    Science.gov (United States)

    Hultgren, Sofie; Larsson, Niklas; Nilsson, Bo F; Jönsson, Jan Ake

    2009-02-01

    A two-phase hollow-fiber (HF) liquid-phase microextraction (LPME) method was developed for determination of a quaternary ammonium compound surfactant, dicocodimethylammonium chloride, in aqueous samples. The porous HF was fixed on a metal rod support and was impregnated with approximately 6.6 microL of organic extractant, which was immobilized in the HF pores. Surfactant extraction was facilitated by addition of carboxylic acid to the sample forming neutral ion pairs with the quaternary ammonium compound. After extraction, the analyte was transferred from the organic extractant in the fiber pores by dissolving the 1-octanol into 100 microL methanol. The methanol extract was analyzed by liquid chromatography-mass spectrometry. The method was optimized (with optimized parameters in brackets) with regard to type of organic extractant (1-octanol), fiber length (2 cm), choice and concentration of anionic carrier (600 microg L(-1) octanoate), procedure of transfer to methanol (15-min sonication), sample volume (250 mL), extraction time (17 h), pH (10), and ionic strength (50 mM carbonate). Aspects influencing repeatability in LPME of (quaternary ammonium) surfactants are discussed. The enrichment factor achieved in 250-mL carbonate buffer was around 400. Due to matrix effects, the enrichment factors achieved when industrial process water was analyzed were 120 or about 30% of that in carbonate buffer. Detection limits of 0.3 microg L(-1) in carbonate buffer and 0.9 microg L(-1) in industrial process water were obtained. If the studied compound is seen as a model substance representing quaternary dialkylated dimethylated ammonium surfactants in general, the developed method may be applied to other quaternary ammonium surfactants.

  6. 13C NMR and XPS characterization of anion adsorbent with quaternary ammonium groups prepared from rice straw, corn stalk and sugarcane bagasse

    Science.gov (United States)

    Cao, Wei; Wang, Zhenqian; Zeng, Qingling; Shen, Chunhua

    2016-12-01

    Despite amino groups modified crop straw has been intensively studied as new and low-cost adsorbent for removal of anionic species from water, there is still a lack of clear characterization for amino groups, especially quaternary ammonium groups in the surface of crop straw. In this study, we used 13C NMR and XPS technologies to characterize adsorbents with quaternary ammonium groups prepared from rice straw, corn stalk and sugarcane bagasse. 13C NMR spectra clearly showed the presence of quaternary ammonium groups in lignocelluloses structure of modified crop straw. The increase of nitrogen observed in XPS survey spectra also indicated the existence of quaternary ammonium group in the surface of the adsorbents. The curve fitting of high-resolution XPS N1s and C1s spectra were conducted to probe the composition of nitrogen and carbon contained groups, respectively. The results showed the proportion of quaternary ammonium group significantly increased in the prepared adsorbent's surface that was dominated by methyl/methylene, hydroxyl, quaternary ammonium, ether and carbonyl groups. This study proved that 13C NMR and XPS could be successfully utilized for characterization of quaternary ammonium modified crop straw adsorbents.

  7. Geomorphic expression of late Quaternary sea level changes along the southern Saurashtra coast, western India

    Indian Academy of Sciences (India)

    Nilesh Bhatt; Uday Bhonde

    2006-08-01

    Geomorphic expression of land-sea interaction is preserved in the form of abandoned cliffs, marine terraces,shore platforms and marine notches along the southern Saurashtra coast. These features have been used to ascertain the magnitude of sea level changes during late Quaternary.Notch morphology and associated biological encrustation have been used to estimate the magnitude and duration of palaeo-sea strands.Marine notches and other erosive features occurring between 12 and 15 m above the present Biological Mean Sea Level (BMSL) are attributed to the last interglacial corresponding to the Marine Isotopic Stage 5 (MIS-5). However,6 to 9 m upliftment of the coastal fringe is attributed to this sea level.The second major high sea strand was identified during the mid-Holocene when the sea rose 2 m above the present level.Notches corresponding to this high sea level are recorded 4 to 5 m above the present BMSL.

  8. The late Quaternary tephrostratigraphical record of the San Gregorio Magno basin (southern Italy)

    Science.gov (United States)

    Munno, R.; Petrosino, P.

    2007-03-01

    Twenty-one primary pyroclastic layers were found embedded in the lacustrine sediments of the San Gregorio Magno basin (Southern Apennines). These sand-sized layers were characterised by a noticeable juvenile fragments content and by a sharp basal contact with the underlying clay and silt sediments. The tephra layers have been correlated with terrestrial counterparts from well-known eruptive events of the Campanian volcanic area, or with reference layers from deep sea sediment cores and from the Monticchio maar sequence. The investigation of the San Gregorio Magno tephra layers made it possible to deduce that lacustrine sedimentation at San Gregorio Magno basin began before 170k yr BP and lasted at least until the emplacement of the Neapolitan Yellow Tuff, which occurred about 15k yr BP. The tephrochronology allowed determination of the varying sedimentation rate that occurred in the basin. Correlation of the lacustrine record with marine sequences has allowed development of a late Quaternary tephrostratotype for southern Italy. Copyright

  9. A Preliminary Paleomagnetic Rsult of Quaternary Drilling Core form Southern Leizhou Peninsula,Guangdong Province

    Institute of Scientific and Technical Information of China (English)

    王俊达; 梁池生; 等

    1999-01-01

    313 orientated samples were collected from Drilling Core ZK1 in southern Leizhou Peninsula for the study of Quaternary paleomagnetic strato-chronology.Te polarity measurement results indicate that the core recorded paleomagnetic information in three main parts:the upper one of the core,from the ground surface to the depth of 39m ,is normally magnetized in polarity,the middle one,from 39m 59 210m in depth,mainly shows reversed polarity and the lower one recorded normal polarity again.They correspond to the Brunhes normal chron,the Matuyama reversed chron and the Guass normal chron in the geomagnetic polarity time scale,respectively.The age of he core could be over 3.4Ma.Meanwhile,the magnetic susceptibility was measured and its result is significant for stratigraphic division and paleoclimatic research.

  10. Neo-tectonic fracturing after emplacement of quaternary granitic pluton in the Kakkonda geothermal field, Japan

    Energy Technology Data Exchange (ETDEWEB)

    Doi, N.; Kato, O. [JMC Goethermal Eng. Co., Ltd., Iwate-ken (Japan); Kanisawa, S.; Ishikawa, K. [Tohoku Univ., Sendai (Japan)

    1995-12-31

    The fracture which occurs in the Kakkonda geothermal system was formed by neo-tectonic stress after the emplacement of the neo-granite (Quaternary Kakkonda Granite) at middle Pleistocene to recent. The characteristic contrast in permeability at ca.1.5 km is strongly controlled by the contact metamorphic zone, especially cordierite and higher grade metamorphic zones, in which the high temperature (320{degrees}C<) and low permeable deep reservoir was created. The five geothermal wells 2.5-3.0 km deep have clarified that a microearthquake zone below -1.0 km shows high permeability especially at the margin of the Kakkonda Granite, and low permeability outside of a microearthquake zone. The Kakkonda Granite is a composite pluton which has very few fractures inside of it. Thus, neo-tectonic fracturing has developed in the non-metamorphosed Tertiary formations and the margin of the Kakkonda Granite.

  11. Magnetic properties and magnetocaloric effect in quaternary boroncarbides compound ErNiBC

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Yikun, E-mail: zhangyk@epm.neu.edu.cn [Department of Material Science and Engineering, Shanghai University, Shanghai 200072 (China); Institute of Materials Physics, University of Münster, Wilhelm-Klemm-Straße 10, D-48149 Münster (Germany); Wilde, Gerhard [Institute of Materials Physics, University of Münster, Wilhelm-Klemm-Straße 10, D-48149 Münster (Germany)

    2015-09-01

    The magnetocaloric effect (MCE) of quaternary intermetallic compound ErNiBC has been investigated by magnetization and heat capacity measurements. The compound undergoes a paramagnetic (PM) to ferromagnetic (FM) transition at T{sub C}~5 K and the ground state of Er ion forms a Kramer's doublet state. The magnetic transition is found to be second order in nature. The maximum magnetic entropy change (−ΔS{sub M}{sup max}) and adiabatic temperature change (ΔT{sub ad}{sup max}) of ErNiBC are 24.8 J/kg K and 8.6 K, respectively, for a magnetic field change of 0–50 kOe, and the corresponding refrigerant capacity (RC) is 312 J/kg.

  12. Ferromagnetism in half-metallic quaternary FeVTiAl Heusler compound

    Science.gov (United States)

    Bhat, Tahir Mohiuddin; Bhat, Idris Hamid; Yousuf, Saleem; Gupta, Dinesh C.

    2016-05-01

    The electronic structure and magnetic properties of FeVTiAl quaternary Heusler alloy have been investigated within the density functional theory framework. The material was found completely spin-polarized half-metallic Ferromagnet in the ground state with F-43m structure. The structural stability was further confirmed by calculating different elastic constants in the cubic phase. Present study predicts an energy band gap of 0.72 eV calculated in localized minority spin channel at an equilibrium lattice parameter of 6.0Å. The calculated total spin magnetic moment of 2 µB/f.u. is in agreement with the Slater-Pauling rule for full Heusler alloys.

  13. High spin polarization in CoFeMnGe equiatomic quaternary Heusler alloy

    Energy Technology Data Exchange (ETDEWEB)

    Bainsla, Lakhan [Department of Physics, Indian Institute of Technology Bombay, Mumbai 400076 (India); Magnetic Materials Unit, National Institute for Materials Science, Tsukuba 305-0047 (Japan); Suresh, K. G., E-mail: suresh@phy.iitb.ac.in [Department of Physics, Indian Institute of Technology Bombay, Mumbai 400076 (India); Nigam, A. K. [Department of Condensed Matter and Materials Science, Tata Institute of Fundamental Research, Mumbai 400005 (India); Manivel Raja, M. [Defence Metallurgical Research Laboratory, Hyderabad 500058 (India); Varaprasad, B. S. D. Ch. S.; Takahashi, Y. K.; Hono, K. [Magnetic Materials Unit, National Institute for Materials Science, Tsukuba 305-0047 (Japan)

    2014-11-28

    We report the structure, magnetic property, and spin polarization of CoFeMnGe equiatomic quaternary Heusler alloy. The alloy was found to crystallize in the cubic Heusler structure (prototype LiMgPdSn) with considerable amount of DO{sub 3} disorder. Thermal analysis result indicated the Curie temperature is about 750 K without any other phase transformation up to melting temperature. The magnetization value was close to that predicted by the Slater-Pauling curve. Current spin polarization of P = 0.70 ± 0.01 was deduced using point contact andreev reflection measurements. The temperature dependence of electrical resistivity has been fitted in the temperature range of 5–300 K in order to check for the half metallic behavior. Considering the high spin polarization and Curie temperature, this material appears to be promising for spintronic applications.

  14. Synthesis and evaluation of ageing effect on Cu–Al–Be–Mn quaternary Shape Memory Alloys

    Directory of Open Access Journals (Sweden)

    A.G. Shivasiddaramiah

    2016-09-01

    Full Text Available Copper based shape memory alloy exhibits high transformation temperature and ability to differ the achieved properties through alloying additions. A quaternary Cu–Al–Be–Mn shape memory alloys of 0.2–0.4 wt% of manganese, 0.4–0.5 wt% of Beryllium and 10–14 wt% of aluminium with remaining copper, showing β-phase at higher temperature and show shape memory effect when quenching to lower temperatures, SMA's were prepared by induction melting. The objective is to study the effect of thermal ageing at different temperatures Af (above austenitic phase finish temperature and at different time on shape memory effect and transformation temperatures. The aged specimens or SMA's were studied by DSC, OM and hardness measurements. The results from this study help to find the applications in different thermal conditions.

  15. Synthesis of Tertiary and Quaternary Amine Derivatives from Wood Resin as Chiral NMR Solvating Agents

    Directory of Open Access Journals (Sweden)

    Tiina Laaksonen

    2015-11-01

    Full Text Available Chiral tertiary and quaternary amine solvating agents for NMR spectroscopy were synthesized from the wood resin derivative (+-dehydroabietylamine (2. The resolution of enantiomers of model compounds [Mosher’s acid (3 and its n-Bu4N salt (4] (guests by (+-dehydroabietyl-N,N-dimethylmethanamine (5 and its ten different ammonium salts (hosts was studied. The best results with 3 were obtained using 5 while with 4 the best enantiomeric resolution was obtained using (+-dehydroabietyl-N,N-dimethylmethanaminium bis(trifluoromethane-sulfonimide (6. The compounds 5 and 6 showed a 1:1 complexation behaviour between the host and guest. The capability of 5 and 6 to recognize the enantiomers of various α-substituted carboxylic acids and their n-Bu4N salts in enantiomeric excess (ee determinations was demonstrated. A modification of the RES-TOCSY NMR pulse sequence is described, allowing the enhancement of enantiomeric discrimination when the resolution of multiplets is insufficient.

  16. Late Quaternary fine silt deposits of Jammu, NW Himalaya: Genesis and climatic significance

    Indian Academy of Sciences (India)

    Rajinder K Ganjoo; Vinod Kumar

    2012-02-01

    The fine silt deposits of Jammu (J & K State, India) stretch all along the Siwalik foothills from Jammu to the Potwar Plateau in Pakistan. The post-Siwalik deposits, first discussed by de Terra and Paterson (1939), are attributed to wind action. The deposits termed as ‘Potwar loessic silt’ comprising sandy silt are essentially of late Quaternary age (75–18 ka) and are re-looked herein from the point of view of genesis and climatic significance. The sorting, skewness and kurtosis parameters of fine silts of Jammu suggest fluvial environment of the deposits wherein the water budget fluctuated. The weak pedogenesis of fine silts at certain intervals corroborate to periods of less or no sedimentation. The bivariant plot studies further suggest fluvial environment of deposition for the fine silt at Jammu, with regular fluctuations in the budget of river water that was perhaps in consonance with oscillations in the climate of the region.

  17. Design of Multi-Valued Quaternary Based Analog-to-Digital Converter

    Directory of Open Access Journals (Sweden)

    A. H.M.Z. Alam

    2009-01-01

    Full Text Available Problem statement: The design of multi-valued quaternary based Analog-to-Digital Converter (ADC circuit was presented. The ADC generates multi-valued logic outputs rather than the conventional binary output system to overall reduction in circuit complexity and size. Approach: Design was implemented using pipeline ADC architecture and was simulated using model parameters based on standard 0.13 µm CMOS process. Results: Performance analysis of the design showed desirable performance parameters in terms of response, low power consumption, and a sampling rate of 10 MHz at a supply voltage of 1.3V was achieved. Conclusion/Recommendations: The ADC design was suitable for the needs of mixed-signal integrated circuit design and can be implemented as a conversion circuit for systems based on multiple-valued logic design.

  18. Maps of Quaternary Deposits and Liquefaction Susceptibility in the Central San Francisco Bay Region, California

    Science.gov (United States)

    Witter, Robert C.; Knudsen, Keith L.; Sowers, Janet M.; Wentworth, Carl M.; Koehler, Richard D.; Randolph, Carolyn E.; Brooks, Suzanna K.; Gans, Kathleen D.

    2006-01-01

    This report presents a map and database of Quaternary deposits and liquefaction susceptibility for the urban core of the San Francisco Bay region. It supercedes the equivalent area of U.S. Geological Survey Open-File Report 00-444 (Knudsen and others, 2000), which covers the larger 9-county San Francisco Bay region. The report consists of (1) a spatial database, (2) two small-scale colored maps (Quaternary deposits and liquefaction susceptibility), (3) a text describing the Quaternary map and liquefaction interpretation (part 3), and (4) a text introducing the report and describing the database (part 1). All parts of the report are digital; part 1 describes the database and digital files and how to obtain them by downloading across the internet. The nine counties surrounding San Francisco Bay straddle the San Andreas fault system, which exposes the region to serious earthquake hazard (Working Group on California Earthquake Probabilities, 1999). Much of the land adjacent to the Bay and the major rivers and streams is underlain by unconsolidated deposits that are particularly vulnerable to earthquake shaking and liquefaction of water-saturated granular sediment. This new map provides a consistent detailed treatment of the central part of the 9-county region in which much of the mapping of Open-File Report 00-444 was either at smaller (less detailed) scale or represented only preliminary revision of earlier work. Like Open-File Report 00-444, the current mapping uses geomorphic expression, pedogenic soils, inferred depositional environments, and geologic age to define and distinguish the map units. Further scrutiny of the factors controlling liquefaction susceptibility has led to some changes relative to Open-File Report 00-444: particularly the reclassification of San Francisco Bay mud (Qhbm) to have only MODERATE susceptibility and the rating of artificial fills according to the Quaternary map units inferred to underlie them (other than dams - adf). The two colored

  19. Magnetic properties and magnetocaloric effect in quaternary boroncarbides compound ErNiBC

    Science.gov (United States)

    Zhang, Yikun; Wilde, Gerhard

    2015-09-01

    The magnetocaloric effect (MCE) of quaternary intermetallic compound ErNiBC has been investigated by magnetization and heat capacity measurements. The compound undergoes a paramagnetic (PM) to ferromagnetic (FM) transition at TC~5 K and the ground state of Er ion forms a Kramer's doublet state. The magnetic transition is found to be second order in nature. The maximum magnetic entropy change (-ΔSMmax) and adiabatic temperature change (ΔTadmax) of ErNiBC are 24.8 J/kg K and 8.6 K, respectively, for a magnetic field change of 0-50 kOe, and the corresponding refrigerant capacity (RC) is 312 J/kg.

  20. Agulhas leakage as a key process in the modes of Quaternary climate changes.

    Science.gov (United States)

    Caley, Thibaut; Giraudeau, Jacques; Malaizé, Bruno; Rossignol, Linda; Pierre, Catherine

    2012-05-01

    Heat and salt transfer from the Indian Ocean to the Atlantic Ocean (Agulhas leakage) has an important effect on the global thermohaline circulation and climate. The lack of long transfer record prevents elucidation of its role on climate changes throughout the Quaternary. Here, we present a 1,350-ka accumulation rate record of the planktic foraminiferal species Globorotalia menardii. We demonstrate that, according to previous assumptions, the presence and reseeding of this fauna in the subtropical southeast Atlantic was driven by interocean exchange south of Africa. The Agulhas transfer strengthened at glacial ice-volume maxima for every glacial-interglacial transition, with maximum reinforcements organized according to a 400-ka periodicity. The long-term dynamics of Agulhas leakage may have played a crucial role in regulating meridional overturning circulation and global climate changes during the Mid-Brunhes event and the Mid-Pleistocene transition, and could also play an important role in the near future.

  1. Analysis of electrostatic stability and ordering in quaternary perovskite solid solutions

    Science.gov (United States)

    Caetano, Clovis; Butler, Keith T.; Walsh, Aron

    2016-04-01

    There are three distinct classes of perovskite structured metal oxides, defined by the charge states of the cations: AIBVO3,AIIBIVO3 , and AIIIBIIIO3 . We investigated the stability of cubic quaternary solid solutions A B O3-A'B'O3 using a model of point-charge lattices. The mixing enthalpies were calculated and compared for the three possible types of combinations of the compounds, both for the random alloys and the ground-state-ordered configurations. The mixing enthalpy of the (I,V)O3-(III,III)O3 alloy is always larger than the other alloys. We found that, different from homovalent alloys, for these heterovalent alloys a lattice constant mismatch between the constituent compounds could contribute to stabilize the alloy. At low temperatures, the alloys present a tendency to spontaneous ordering, forming superlattices consisting of alternated layers of AB O 3 and A'B'O3 along the [110 ] direction.

  2. Application of DOI index to analysis of selected examples of resistivity imaging models in Quaternary sediments

    Directory of Open Access Journals (Sweden)

    Glazer Michał

    2014-12-01

    Full Text Available Interpretation of resistivity cross sections may be in many cases unreliable due to the presence of artifacts left by the inversion process. One way to avoid erroneous conclusions about geological structure is creation of Depth of Investigation (DOI index maps, which describe durability of prepared model with respect to variable parameters of inversion. To assess the usefulness of this interpretation methodology in resistivity imaging method over quaternary sediments, it has been used to one synthetic data set and three investigation sites. Two of the study areas were placed in the Upper Silesian Industrial District region: Bytom - Karb, Chorzów - Chorzow Stary; and one in the Southern Pomeranian Lake District across Piława River Valley. Basing on the available geological information the results show high utility of DOI index in analysis of received resistivity models, on which areas poorly constrained by data has been designated.

  3. Differentiating clinical care from disease prevention: a prerequisite for practicing quaternary prevention

    Directory of Open Access Journals (Sweden)

    Charles Dalcanale Tesser

    Full Text Available Abstract: This article contends that the distinction between clinical care (illness and prevention of future disease is essential to the practice of quaternary prevention. The authors argue that the ongoing entanglement of clinical care and prevention transforms healthy into "sick" people through changes in disease classification criteria and/or cut-off points for defining high-risk states. This diverts health care resources away from those in need of care and increases the risk of iatrogenic harm in healthy people. The distinction in focus is based on: (a management of uncertainty (more flexible when caring for ill persons; (b guarantee of benefit (required only in prevention; (c harm tolerance (nil or minimal in prevention. This implies attitudinal differences in the decision-making process: greater skepticism, scientism and resistance towards preventive action. These should be based on high-quality scientific evidence of end-outcomes that displays a net positive harm/benefit ratio.

  4. Influence of alkyl group of imidazolinyl-quaternary-ammonium-salt on corrosion inhibition efficiency

    Institute of Scientific and Technical Information of China (English)

    SHI Shun-cun; WANG Xue-ye; YI Ping-gui; CAO Chen-zhong; DENG Tong-tong; SU Jie-shu

    2006-01-01

    The action between imidazolinyl-quaternary-ammonium-salt(IQAS) molecule and Fe atom was studied,and the influence of the alkyl group connected with N atom of imidazoline ring on corrosion inhibition efficiency was explored. Quantum chemical methods, HF/6- 31 G and HF/Lan L2 dz, were applied successively to calculate the parameters such as front molecular orbit energy of IQAS Ⅰ-Ⅳ and chemical adsorption for IQAS Ⅰ-Ⅳ and Fe atom.The corrosion inhibition efficiency was measured with the weight loss method of carbon steel samples in acidic solution and oil field sewage. Based on the theoretical analyses and experimental results, it is concluded that N-Fe coordination bond is formed between IQAS molecule and Fe atom, corrosion inhibition efficiency is decreased in the following order(from large to small): IQAS Ⅳ, IQAS Ⅲ, IQAS Ⅱ , IQAS Ⅰ.

  5. Organometallics and quaternary ammonium salts affect calcium ion desorption from lecithin liposome membranes.

    Science.gov (United States)

    Kral, T E; Kuczera, J; Przestalski, S

    2001-01-01

    The objective of the present work was to compare the effects of groups of tin and lead organometallic compounds and their mixtures with amphiphilic quaternary ammonium salts (QAS) on the process of calcium ion desorption from lecithin liposome membranes, as dependent on the properties of the hydrophilic and hydrophobic parts of QAS. In the investigations the method of radioactive labels was applied. Synergism and antagonism in the action of both groups of compounds were found. The effectiveness of the cooperation depended more on chain length of QAS compounds than on the size and polarity of their hydrophobic parts. The most effective of all compounds studied was a the mixture of benzyldimethylammonium chloride in a mixture with tripropyltin. Since the rate of calcium desorption proved to be a good measure of efficacy of biologically active surfactants, it seems that the conclusions reached in this paper may be useful for choosing compounds which are able to decontaminate the environment polluted with heavy metals.

  6. Climate change not to blame for late Quaternary megafauna extinctions in Australia.

    Science.gov (United States)

    Saltré, Frédérik; Rodríguez-Rey, Marta; Brook, Barry W; Johnson, Christopher N; Turney, Chris S M; Alroy, John; Cooper, Alan; Beeton, Nicholas; Bird, Michael I; Fordham, Damien A; Gillespie, Richard; Herrando-Pérez, Salvador; Jacobs, Zenobia; Miller, Gifford H; Nogués-Bravo, David; Prideaux, Gavin J; Roberts, Richard G; Bradshaw, Corey J A

    2016-01-29

    Late Quaternary megafauna extinctions impoverished mammalian diversity worldwide. The causes of these extinctions in Australia are most controversial but essential to resolve, because this continent-wide event presaged similar losses that occurred thousands of years later on other continents. Here we apply a rigorous metadata analysis and new ensemble-hindcasting approach to 659 Australian megafauna fossil ages. When coupled with analysis of several high-resolution climate records, we show that megafaunal extinctions were broadly synchronous among genera and independent of climate aridity and variability in Australia over the last 120,000 years. Our results reject climate change as the primary driver of megafauna extinctions in the world's most controversial context, and instead estimate that the megafauna disappeared Australia-wide ∼13,500 years after human arrival, with shorter periods of coexistence in some regions. This is the first comprehensive approach to incorporate uncertainty in fossil ages, extinction timing and climatology, to quantify mechanisms of prehistorical extinctions.

  7. Effect of Mineral Admixtures on Resistance to Sulfuric Acid Solution of Mortars with Quaternary Binders

    Science.gov (United States)

    Makhloufi, Zoubir; Bederina, Madani; Bouhicha, Mohamed; Kadri, El-Hadj

    This research consists to study the synergistic action of three mineral additions simultaneously added to the cement. This synergistic effect has a positive effect on the sustainability of limestone mortars. Tests were performed on mortars based on crushed limestone sand and manufactured by five quaternary binders (ordinary Portland cement and CPO mixed simultaneously with filler limestone, blast-furnace and natural pozzolan). The purpose of this research was to identify the resistance of five different mortars to the solution of sulfuric acid. Changes in weight loss and compressive strength measured at 30, 60, 90, 120 and 180 days for each acid solution were studied. We followed up on the change in pH of the sulfuric acid solution at the end of each month up to 180 days.

  8. Testing MODFLOW-LGR for simulating flow around Buried Quaternary valleys - synthetic test cases

    DEFF Research Database (Denmark)

    Vilhelmsen, Troels Norvin; Christensen, Steen

    In Denmark the water supply is entirely based on ground water. In some parts of the country these resources are found in buried quaternary tunnel valleys. Intensive mapping has shown that the valleys typically have a complex internal hydrogeology with multiple cut and ­fill structures. The admini...... on the results we will evaluate how to use the method to re­fine a regional scale model covering an area north of the town of Aarhus, Denmark. The area, which contains several buried valleys, is marked with a red square on the map.......­finement (LGR) method developed for MODFLOW-2005 for simulation of groundwater flow in areas containing buried valleys. The tests are conducted as comparative analysis between simulations made with a globally refi­ned model, a locally re­fined model, and a globally coarse model, respectively. Based...

  9. Quaternary glacial records in mountain regions:A formal stratigraphical approach

    Institute of Scientific and Technical Information of China (English)

    P.D.Hughes; P.L.Gibbard; J.C.Woodward

    2005-01-01

    Glacial deposits in locally-glaciated mountain regions are often expressed through their surface form and the study of these deposits constitutes a major branch of geomorphology. Studies of glacial depositional records in mountain areas have often neglected formal stratigraphical procedure resulting in an ad hoc development of quasi-stratigraphical nomenclature. Here, a formal stratigraphical procedure is recommended, since this enables a systematic approach to the subdivision of glacial deposits in mountain regions. Moreover, such an approach facilitates, in some instances, the development of a formal chronostratigraphy that can be compared to regional and global geological time scales. This is important in locally-glaciated mountain regions where glacial deposits represent one of the most important records of cold stage environments. Given that glacial landforms represent a key component of the Quaternary record, maintaining a formal link between geomorphological and geological stratigraphical procedure is a fundamental requirement of a consistent and comparable stratigraphical framework.

  10. Biotreatment on cellulose fluff pulp: quaternary ammonium salts finish and grafting with beta-cyclodextrin.

    Science.gov (United States)

    Ghemati, Djamila; Oudia, Atika; Aliouche, Djamel; Lamouri, Saad

    2009-11-01

    For its potential performances to be expanded, cellulose needs to be processed in different ways. Therefore, an object of the present work was to provide a chemical modification of cellulose through: a specific finish with two quaternary ammonium salts (namely Aliquat 336 and Aliquat 1529, respectively). Chemical grafting of beta-cyclodextrin derivative (beta-CD) onto fibers followed by the inclusion of benzoic acid in the grafted CD cavities as a probe chemical. Physicochemical properties and performances of the untreated and treated fibers have been determined with infrared spectra, microscopy, swelling measurements, antimicrobial finishing tests, and dye adsorption. Our results show that cellulose fibers can be efficiently modified with no significant changes in its structural and surface properties; the treated fibers show an attractive behavior in swelling, dye adsorption and antibacterial activity.

  11. Crystal structure of the quaternary alloy CuTaInSe{sub 3}

    Energy Technology Data Exchange (ETDEWEB)

    Mora, A.J. [Laboratorio de Cristalografia, Departamento de Quimica, Facultad de Ciencias, Universidad de Los Andes, Merida 5101 (Venezuela); Grima-Gallardo, P.; Duran, S.; Munoz, M.; Quintero, M. [Centro de Estudios de Semiconductores, Departamento de Fisica, Facultad de Ciencias, Universidad de Los Andes, Merida 5101 (Venezuela); Delgado, G.E.

    2008-07-15

    The crystal structure of the quaternary compound CuTaInSe{sub 3} belonging to the system (CuInSe{sub 2}){sub 1-x}(TaSe){sub x} with x=0.5, was analyzed using X-ray powder diffraction data. This material is isostructural with the CuFeInSe{sub 3} compound, and crystallize in the tetragonal space group P42c (N 112), Z=1, with unit cell parameters a=5.7831(1) A, c=11.6227(4) A, V=388.71(2) A{sup 3}. The Rietveld refinement of 18 instrumental and structural variables led to R{sub p}=8.0%, R{sub wp}=9.5%, R{sub exp}=6.3% and {chi}{sup 2}=1.5 for 4501 step intensities and 144 independent reflections. (copyright 2008 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

  12. High durability and low toxicity antimicrobial coatings fabricated by quaternary ammonium silane copolymers.

    Science.gov (United States)

    Li, Hairui; Bao, Hongqian; Bok, Ke Xin; Lee, Chi-Ying; Li, Bo; Zin, Melvin T; Kang, Lifeng

    2016-02-01

    Adhesion and subsequent growth of microorganisms on material surfaces are a major concern in many biomedical applications. Currently, various polymers are immobilized on material surfaces to prevent microbial colonization. However, there are several challenges with regard to the coating materials, including their inability to kill microorganisms, complexity of surface grafting, limited durability and toxicity towards humans. To address these challenges, we synthesize a novel quaternary ammonium silane (QAS) antimicrobial copolymer to confer the antimicrobial effect via a simple thermal-curing coating process. The QAS copolymers were less toxic to 3 human cell lines than a commercial antimicrobial QAS monomeric agent, namely, dimethyloctadecyl[3-(trimethoxysilyl) propyl]ammonium chloride (DTPAC). Moreover, the QAS coatings demonstrated superior antimicrobial efficacy and durability than those of the DTPAC coatings. In conclusion, the novel QAS copolymers are useful to prevent substrates from microbial infections, yet with low toxicity to humans and long durability. In addition, the synthetic process is potentially scalable for industrial applications.

  13. Perfluorinated quaternary ammonium salts of polyoxometalate anions: Fluorous biphasic oxidation catalysis with and without fluorous solvents

    Energy Technology Data Exchange (ETDEWEB)

    Maayan, Galia; Fish, Richard H.; Neumann, Ronny

    2003-05-28

    Perfluorinated quaternary ammonium cations, [CF{sub 3}(CF{sub 2}){sub 7}(CH{sub 2}){sub 3}]{sub 3}CH{sub 3}N{sup +} (RFN{sup +}), were synthesized and used as counter cations for the [WZnM{sub 2}(H{sub 2}O){sub 2}(ZnW{sub 9}O{sub 34}){sub 2}]{sup 12-} (M = Mn(II), Zn(II)), polyoxometalate. The (RFN{sup +}){sub 12}[WZnM{sub 2}(H{sub 2}O){sub 2}(ZnW9O{sub 34}){sub 2}] compounds were fluorous biphasic catalysts for alcohol and alkenol oxidation, and alkene epoxidation with aqueous hydrogen peroxide. Reaction protocols with or without a fluorous solvent were tested. The catalytic activity and selectivity was affected both by the hydrophobicity of the solvent and the substrate.

  14. Paleoenvironmental imprint on subseafloor microbial communities in Western Mediterranean Sea Quaternary sediments

    Directory of Open Access Journals (Sweden)

    M.-C. Ciobanu

    2012-01-01

    Full Text Available An interdisciplinary study was conducted to evaluate the relationship between geological and paleontological parameters and the bacterial and archaeal community structure of two contrasted subseafloor sites in the Western Mediterranean Sea (Ligurian Sea and Gulf of Lions. Since both depositional environments were well-documented in this area, large data-sets were available and allowed to calibrate the investigated cores with several reference and dated cores previously collected in the same area, and notably correlated to Quaternary climate variations. Molecular-based fingerprints showed that the Ligurian Sea sediments, characterized by an heterolithic facies with numerous turbidites from a deep-sea levee, were unexpectedly dominated by Betaproteobacteria (more than 70 %, at the base of the core mainly below five meters in the sediment. Analysis of relative betaproteobacterial abundances and turbidites frequency indicated that the microbial diversity was controlled by the important climatic changes occurring during the last 20 ka. This result was supported by statistical direct multivariate canonical correspondence analyses (CCA. In contrast, the Gulf of Lions core, characterized by a homogeneous lithology of upper-slope environment, was dominated by the Bacteroidetes group and in a lesser extent, by the Betaproteobacteria group. At both sites, the dominance of Betaproteobacteria coincided with increased terrestrial inputs, as confirmed by the geochemical measurements (Si, Sr, Ti and Ca. In the Gulf of Lions, geochemical parameters were also found to drive microbial community composition. Taken together, our data suggest that the palaeoenvironmental history of erosion and deposition recorded in the Western-Mediterranean Sea sediments has left its imprint on the structure/composition of the microbial communities during the late Quaternary.

  15. Environmental Magnetic Signature Of Late Quaternary Climate and Paleoceanography in the Bering Sea

    Science.gov (United States)

    Platzman, E. S.; Lund, S.; Kirby, M. E.

    2014-12-01

    High latitude drilling during IODP expedition 323 in the Bering Sea provides a unique opportunity to study in detail the evolution of Quaternary paleoceanography, climate and glacial history of the Bering Sea gateway to the Arctic Ocean. Our study focuses on a 400 ky interval of Quaternary marine sediments cored along the Bering Slope. Samples for magnetic analysis were obtained from sites U1339, U1343, U1344, U1345, at depths of 1008-3484 m. Sediments in these cores are a mixture of siliclastic material, derived primarily from terrigeneous sources, and biogenic material. Detailed measurements of the variation in bulk magnetic properties including natural remanent magnetization (NRM), susceptibility, ARM, and IRM, have been used to monitor changes in concentration, composition and grainsize of the magnetic components. In addition, sediment grain size analysis was preformed on biogenic free aliquots at selected intervals. Our results indicate that the dramatic bimodal magnetic intensity signal that alternates between a strong and weak NRM and magnetic susceptibility is associated with relatively course and fine grain sizes repectively. This is the opposite to the pattern estimated by our initial IODP Ex. 323 reports. Current models propose that, as has been observed in the North Atlantic, high intensities are likely to be related to high contributions of terrigenous and glaciomarine sediments deposited during glacial periods and low intensities are likely to occur during interglacials when continental sediments become trapped on the on the shelf. Contrary to this hypothesis, however, we find compelling evidence for a substantial increase in terrigenous input during the interglacial periods and what appears to be a predominantly pelagic signal during the glacial periods. Comparison of our data with other proxy data including oxygen isotopes, NGR, GRA allows us to investigate the possible causal links between these changes and the environmental history of the North

  16. Effect of double quaternary ammonium groups on micelle formation of partially fluorinated surfactant.

    Science.gov (United States)

    Matsuoka, Keisuke; Chiba, Nagisa; Yoshimura, Tomokazu; Takeuchi, Emi

    2011-04-15

    To investigate the effect of divalency on the micelle properties, we synthesized divalent cationic surfactants composed of fluorocarbons and double quaternary ammonium groups N,N-dimethyl-N-[2-(N'-trimethylammonium)ethyl]-1-(3-perfluoroalkyl-2-hydroxypropyl) ammonium bromide [C(n)(F)C(3)-2Am; where n (=8 or 10) represents the number of carbon atoms in the fluorocarbon chain]. The double quaternary ammonium groups are continuously combined by the ethylene spacer in the surfactant head group, which clearly distinguishes the molecular design of the surfactant from those of the other typical divalent surfactants, bolaform and gemini types. The presence of the divalent head group results in an advantageous increase in their solubility [i.e., rise in the critical micelle concentration (cmc)]; however, the extra electrostatic repulsion between divalent cations decreases the surface activity in comparison with monovalent homologous fluorinated surfactants. The cmc, surface tension at cmc, and area occupied by a surfactant molecule in aqueous solution at 298.2K are 4.32 mM, 30.6 mN m(-1), and 0.648 nm(2 )molecule(-1), respectively, for C(8)(F)C(3)-2Am, and 1.51 mM, 30.4 mN m(-1), and 0.817 nm(2) molecule(-1), respectively, for C(10)(F)C(3)-2Am. The micellar size and shape were investigated by dynamic light scattering and freeze-fracture transmission electron microscopy (TEM). The TEM micrographs show that C(n)(F)C(3)-2Am (n=8 and 10) mainly forms ellipsoidal micelles approximately 10-100 nm in size for n=8 and approximately 10-20 nm in size for n=10. The degree of counterion binding to micelle was determined by selective electrode potential measurements, and the results of 0.7-0.8 agree with the average values for conventional monovalent ionic surfactants.

  17. Use-dependent block of cardiac sodium channels by quaternary derivatives of lidocaine.

    Science.gov (United States)

    Gintant, G A; Hoffman, B F

    1984-02-01

    Modulation of the reduction of fast inward sodium current by local anesthetics due to changes in electrical activity has been termed use-dependent block ( Courtney 1975). To determine the mechanisms responsible for use-dependent block of cardiac sodium channels and to compare use-dependent block in cardiac and nerve preparations, we investigated use-dependent block of cardiac sodium channels by the quaternary lidocaine analogues QX -314 and QX -222 (two agents previously studied in nerve). We used canine cardiac Purkinje fibers, and assessed changes in the fast inward sodium current using changes in the maximum rate of rise of the action potential upstroke (Vmax). Two microelectrode voltage clamp and current clamp techniques were used to control membrane potential prior to stimulated upstrokes . Use-dependent block was not affected by shortening the action potential duration during rapid stimulation. Partial recovery from use-dependent block was observed during rapid stimulation with brief depolarizing prepulses terminating immediately prior to the upstroke. Similar prepulses also prevented the development of use-dependent block following an abrupt increase in the stimulation rate. Hyperpolarizing prepulses during rapid stimulation caused recovery from use-dependent block; recovery was greater and more rapid with increasingly negative prepulses . Hyperpolarization during periods of electrical quiescence also caused greater recovery. These results, interpreted using the modulated receptor hypothesis ( Hille 1977; Hondeghem and Katzung 1977), suggest that use-dependent block of cardiac sodium channels by quaternary local anesthetics is due to drug association with the inactivated sodium channel receptor which occurs only after these drugs gain access to the receptor site through open sodium channels.

  18. Micromorphological investigations of the Late Quaternary loess-paleosol sequences of the Kashmir Valley, India

    Science.gov (United States)

    Dar, Reyaz Ahmad; Chandra, Rakesh; Romshoo, Shakil Ahmad; Kowser, Nazia

    2015-11-01

    The loess-paleosol sequences of the Karewa Group preserve a valuable repository of the Late Quaternary climatic changes and the landscape evolution history of the Karewa Basin of Kashmir Valley in their lithological and pedogenic records. Three representative loess-paleosol sections at Shankerpora (SP), Khan Sahib (KS) and Pattan (PT) localities were chosen for detailed lithostratigraphic fieldwork and micromorphological observations of thin sections. Lithostratigraphic analysis revealed lateral and vertical variation in thickness and number of paleosol profiles from south-west to north-west of the Karewa Basin suggesting the availability of land-surface for periodic loess deposition. The SP section is marked by 6 (SP-S6, S7, S8, S9, S10, S12), KS section by 3 (KS-S2, S4, S5) and PT section by 2 (PT-S1, S3) thick mature paleosol profiles. Theses paleosols have well developed 'Ah' and 'Btk' horizons representing prolonged land-surface stability when pedogenic processes outpace loess deposition. On the other hand comparatively thin to thick paleosol profiles represent weak to moderate pedogenic maturity indicating short stratigraphic breaks with rapid loess deposition. Micromorphological observations of thin sections suggested that clay illuviation and CaCO3 accumulation have operated within the paleosol profiles. CaCO3 features are often associated with clay coatings suggesting decalcification of carbonates followed by clay illuviation. Pedogenic CaCO3 probably resulted from the precipitation of the soil solution near the average depth of wetting front. The pedogenic CaCO3, illuvial clay, mottles, iron manganese features, pedal microstructure and blocky aggregates reveal variation in the pedogenic maturity among and within the loess-paleosol sections. The morphological (both micro- and macro-morphological) attributes of loess-paleosols suggest variation of climatic conditions during the Late Quaternary period in the Karewa Basin of Kashmir Valley, India.

  19. Gela submarine slide: gigantic basin-wide event in the Plio-Quaternary foredeep of Sicily

    Energy Technology Data Exchange (ETDEWEB)

    Argnani, A.; Trincardi, F.

    1988-08-01

    The Gela basin is a Pliocene-Quaternary foredeep basin located at the front of the Maghrebian fold-thrust belt of Sicily, filled with 2,500 m-thick shallowing-upward marine sediments. An important contribution to the basin fill comes from a huge, basin-wide submarine slide which extends for 3,500 km/sup 2/ and thickens as much as 450 m; the estimated sediment volume involved in the slide is close to 1,000 km/sup 3/. The authors investigation used more than 3,000 km of multichannel and single-channel seismic reflection profiles. The slide depositional geometries and facies relationships have been reconstructed from seismic interpretation to provide insight into transport and emplacement mechanisms. Apparently, the slide was not simply deposited via mass transfer from the slope into the basin. Indeed, the bulk of the slide is composed of basin sediments plastically deformed under the gravitational force driven by the correspondent slope sediments. Such a deformation occurred above an extremely effective decollement surface which controlled the slide distribution throughout the basin. More localized decollement planes are, however, present within the slide body and contributed to its complex deformation. The slide can thus be considered the result of a generalized gravitational collapse which affected the sediments lying above a peculiar decollement horizon. A general uplift characterized the late Quaternary evolution of the area, and volcanic activity was quite widespread and documented in the historical record. A punctuated episode of energy release (volcanic related ), superimposed to the uplift trend, may have triggered the slide in conjunction with potentially easy detachment of a decollement.

  20. Latest Quaternary palaeoceanographic change in the eastern North Atlantic based upon a dinoflagellate cyst event ecostratigraphy

    Directory of Open Access Journals (Sweden)

    Rex Harland

    2016-05-01

    Full Text Available The analyses of dinoflagellate cyst records, from the latest Quaternary sediments recovered from DSDP Core 610A taken on the Feni Ridge in the southern Rockall Trough, and part of core MD01-2461 on the continental margin of the Porcupine Seabight in the eastern North Atlantic Ocean, has provided evidence for significant oceanographic change encompassing the Last Glacial Maximum (LGM and part of the Holocene. This together with other published records has led to a regional evaluation of oceanographic change in the eastern North Atlantic over the past 68 ka, based upon a distinctive dinoflagellate event ecostratigraphy. These changes reflect changes in the surface waters of the North Atlantic Current (NAC, and perhaps the deeper thermohaline Atlantic Meridional Overturning Circulation (AMOC, driving fundamental regime changes within the phytoplanktonic communities. Three distinctive dinoflagellate cyst associations based upon both factor and cluster analyses have been recognised. Associations characterised by Bitectatodinium tepikiense (between 61.1 ± 6.2 to 13.4 ± 1.1 ka BP, Nematosphaeropsis labyrinthus (between 10.5 ± 0.3 and 11.45 ± 0.8 ka. BP, and the cyst of Protoceratium reticulatum (between 8.5 ± 0.9 and 5.2 ± 1.3 ka. BP indicate major change within the eastern North Atlantic oceanography. The transitions between these changes occur over a relatively short time span (c.1.5 ka, given our sampling resolution, and have the potential to be incorporated into an event stratigraphy through the latest Quaternary as recommended by the INTIMATE (INTegrating Ice core, MArine and TErrestrial records group. The inclusion of a dinoflagellate cyst event stratigraphy would highlight changes within the phytoplankton of the North Atlantic Ocean as a fully glacial world changed to our present interglacial.

  1. Quaternary Geology and Surface Faulting Hazard: Active and Capable Faults in Central Apennines, Italy

    Science.gov (United States)

    Falcucci, E.; Gori, S.

    2015-12-01

    The 2009 L'Aquila earthquake (Mw 6.1), in central Italy, raised the issue of surface faulting hazard in Italy, since large urban areas were affected by surface displacement along the causative structure, the Paganica fault. Since then, guidelines for microzonation were drew up that take into consideration the problem of surface faulting in Italy, and laying the bases for future regulations about related hazard, similarly to other countries (e.g. USA). More specific guidelines on the management of areas affected by active and capable faults (i.e. able to produce surface faulting) are going to be released by National Department of Civil Protection; these would define zonation of areas affected by active and capable faults, with prescriptions for land use planning. As such, the guidelines arise the problem of the time interval and general operational criteria to asses fault capability for the Italian territory. As for the chronology, the review of the international literature and regulatory allowed Galadini et al. (2012) to propose different time intervals depending on the ongoing tectonic regime - compressive or extensional - which encompass the Quaternary. As for the operational criteria, the detailed analysis of the large amount of works dealing with active faulting in Italy shows that investigations exclusively based on surface morphological features (e.g. fault planes exposition) or on indirect investigations (geophysical data), are not sufficient or even unreliable to define the presence of an active and capable fault; instead, more accurate geological information on the Quaternary space-time evolution of the areas affected by such tectonic structures is needed. A test area for which active and capable faults can be first mapped based on such a classical but still effective methodological approach can be the central Apennines. Reference Galadini F., Falcucci E., Galli P., Giaccio B., Gori S., Messina P., Moro M., Saroli M., Scardia G., Sposato A. (2012). Time

  2. Quaternary paleoceanographic reconstruction of Eastern Equatorial Pacific:planktic foraminiferal evidence

    Science.gov (United States)

    Mallick, Kirtiranjan; Sinha, Devesh K.; Singh, Ashutosh K.

    2016-04-01

    The Eastern Equatorial Pacific (EEP) is quite unique in its oceanographic set up and exhibits considerable variations on shorter to longer time scales. The region encounters intense upwelling caused by the Peru Current. The EEP show a strong ocean-atmosphere coupling, which is manifested in form of events like (El Nino Southern Oscillations (ENSO) that affects the global climate. The present work is based on planktic foraminiferal census data from the ODP Hole 846B, situated at 3°S latitude near the Galapagos spreading centre in the EEP, for paleoceanographic reconstructions for the Quaternary Period. Four species which show significant fluctuations in the relative abundance are Globigerinoides ruber (mixed layer and oligotrophic species), Neogloboquadrina dutertrei (fertility indicator and thermocline dweller),Globigerina bulloides (upwelling indicator) and Globorotalia inflata (temperate species). Results of the analyses of the census count of the planktic foraminifera indicate the overall dominance of the shallow water thermocline species N. dutertrei, suggesting the prevalence of the robust EEP Cold tongue during the Quaternary. The increase in the relative abundance of Gs.ruber marks seven planktic foraminiferal events (2.52Ma to 0.5Ma) of reduced strength of the cold tongue along the EEP. These intervals are concomitant with spreading and encroachment of warm water from the Western Pacific suggesting El Nino like conditions due to reduced strength of trade winds. Seven planktic foraminiferal events (2.42Ma to 0.20Ma) show prominent increase in the relative abundance of Gg.bulloides indicating advection of nutrient rich waters due to enhanced coastal upwelling. Invasion of the temperate species Globorotalia inflata is indicated by its abundance reaching up to 20 percent of the total assemblage at 3°S occur during ~ 2.07 Ma, 1.32 Ma and 1.05 Ma. The unusual occurrence of the cold water temperate species indicates the expansion of southern polar front which

  3. Agricultural contaminants in Quaternary aquitards: A review of occurrence and fate in North America

    Science.gov (United States)

    Rodvang, S. J.; Simpkins, W. W.

    2001-01-01

    The intensity of agriculture has increased significantly during the past 30 years, resulting in increased detection of agricultural contaminants (nutrients, pesticides, salts, trace elements, and pathogens) in groundwater. Till, glaciolacustrine, and loess deposits of Quaternary age compose the most common surficial deposits underlying agricultural areas in North America. Quaternary aquitards generally contain higher concentrations of solid organic carbon (SOC, as much as 1.4%), dissolved organic carbon (DOC, as much as 205 mg/L), and reduced sulfur (as much as 0.9%) than do aquifers. Their potential to sorb pesticides increases with the percent of older SOC, because diagenesis increases Koc. Denitrification consistently reduces nitrate to non-detectable levels in unweathered Quaternary aquitards. Organic carbon of Quaternary age is a more labile electron donor than carbon from shale clasts. Pyrite is a more labile electron donor than carbon in many instances. Unweathered Quaternary aquitards provide a high degree of protection for underlying aquifers, due to their large reserves of SOC and reduced sulfur for sorption and denitrification, combined with their typically low hydraulic conductivity. In contrast, agricultural contaminants are common in weathered Quaternary aquitards. Lower reserves of reduced sulfur and sorptive/labile organic carbon, and a higher bulk K due to fractures, limit their ability to attenuate nitrate and pesticides. Subsurface drainage, which is common in Quaternary aquitards because of high water tables, bypasses the attenuation capacity of Quaternary aquitards and facilitates the transport of agricultural contaminants to surface water. Résumé. L'agriculture s'est significativement accrue au cours des dernières 30 années, provoquant une détection plus fréquente dans les eaux souterraines de contaminants agricoles (engrais, pesticides, sels, éléments en traces et germes pathogènes). Les moraines, les formations glacio-lacustres et

  4. Quaternary Geochronology, Paleontology, and Archaeology of the Upper San Pedro River Valley, Sonora, Mexico

    Science.gov (United States)

    Gaines, E. P.

    2013-12-01

    This poster presents the results of multi-disciplinary investigations of the preservation and extent of Quaternary fossil-bearing strata in the San Pedro River Valley in Sonora, Mexico. Geologic deposits in the portions of the San Pedro Valley in southern Arizona contain one of the best late Cenozoic fossil records known in North America and the best record of early humans and extinct mammals on the continent. The basin in the U.S. is one of the type locations for the Blancan Land Mammal Age. Hemiphilian and Irvingtonian fossils are common. Rancholabrean remains are widespread. Strata in the valley adjacent to the international border with Mexico have yielded the densest concentration of archaeological mammoth-kill sites known in the western hemisphere. Despite more than 60 years of research in the U.S., however, and the fact that over one third of the San Pedro River lies south of the international boundary, little has been known about the late Cenozoic geology of the valley in Mexico. The study reported here utilized extensive field survey, archaeological documentation, paleontological excavations, stratigraphic mapping and alluvial geochronology to determine the nature and extent of Quaternary fossil-bearing deposits in the portions of the San Pedro Valley in Sonora, Mexico. The results demonstrate that the Plio-Pleistocene fossil -bearing formations known from the valley in Arizona extend into the uppermost reaches of the valley in Mexico. Several new fossil sites were discovered that yielded the remains of Camelids, Equus, Mammuthus, and other Proboscidean species. Late Pleistocene archaeological remains were found on the surface of the surrounding uplands. AMS radiocarbon dating demonstrates the widespread preservation of middle- to late- Holocene deposits. However, the late Pleistocene deposits that contain the archaeological mammoth-kill sites in Arizona are absent in the valley in Mexico, and are now known to be restricted to relatively small portions of

  5. Latest Quaternary palaeoceanographic change in the eastern North Atlantic based upon a dinoflagellate cyst event ecostratigraphy.

    Science.gov (United States)

    Harland, Rex; Polovodova Asteman, Irina; Morley, Audrey; Morris, Angela; Harris, Anthony; Howe, John A

    2016-05-01

    The analyses of dinoflagellate cyst records, from the latest Quaternary sediments recovered from DSDP Core 610A taken on the Feni Ridge in the southern Rockall Trough, and part of core MD01-2461 on the continental margin of the Porcupine Seabight in the eastern North Atlantic Ocean, has provided evidence for significant oceanographic change encompassing the Last Glacial Maximum (LGM) and part of the Holocene. This together with other published records has led to a regional evaluation of oceanographic change in the eastern North Atlantic over the past 68 ka, based upon a distinctive dinoflagellate event ecostratigraphy. These changes reflect changes in the surface waters of the North Atlantic Current (NAC), and perhaps the deeper thermohaline Atlantic Meridional Overturning Circulation (AMOC), driving fundamental regime changes within the phytoplanktonic communities. Three distinctive dinoflagellate cyst associations based upon both factor and cluster analyses have been recognised. Associations characterised by Bitectatodinium tepikiense (between 61.1 ± 6.2 to 13.4 ± 1.1 ka BP), Nematosphaeropsis labyrinthus (between 10.5 ± 0.3 and 11.45 ± 0.8 ka. BP), and the cyst of Protoceratium reticulatum (between 8.5 ± 0.9 and 5.2 ± 1.3 ka. BP) indicate major change within the eastern North Atlantic oceanography. The transitions between these changes occur over a relatively short time span (c.1.5 ka), given our sampling resolution, and have the potential to be incorporated into an event stratigraphy through the latest Quaternary as recommended by the INTIMATE (INTegrating Ice core, MArine and TErrestrial records) group. The inclusion of a dinoflagellate cyst event stratigraphy would highlight changes within the phytoplankton of the North Atlantic Ocean as a fully glacial world changed to our present interglacial.

  6. Cationic nanoparticles with quaternary ammonium-functionalized PLGA–PEG-based copolymers for potent gene transfection

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Yan-Hsung [Kaohsiung Medical University, School of Dentistry, College of Dental Medicine (China); Fu, Yin-Chih [Kaohsiung Medical University, Graduate Institute of Medicine, College of Medicine (China); Chiu, Hui-Chi [Kaohsiung Medical University, Department of Medicinal and Applied Chemistry, College of Life Science (China); Wang, Chau-Zen [Kaohsiung Medical University, Department of Physiology, College of Medicine (China); Lo, Shao-Ping [Kaohsiung Medical University, Department of Medicinal and Applied Chemistry, College of Life Science (China); Ho, Mei-Ling [Kaohsiung Medical University, Department of Physiology, College of Medicine (China); Liu, Po-Len [Kaohsiung Medical University, Department of Respiratory Therapy, College of Medicine (China); Wang, Chih-Kuang, E-mail: ckwang@kmu.edu.tw [Kaohsiung Medical University, Department of Medicinal and Applied Chemistry, College of Life Science (China)

    2013-11-15

    The objective of the present work was to develop new cationic nanoparticles (cNPs) with amphiphilic cationic copolymers for the delivery of plasmid DNA (pDNA). Cationic copolymers were built on the synthesis of quaternary ammonium salt compounds from diethylenetriamine (DETA) to include the positively charged head group and amphiphilic multi-grafts. PLGA-phe-PEG-qDETA (PPD), phe-PEG-qDETA-PLGA (PDP), and PLGA-phe-PEG-qDETA-PLGA (PPDP) cationic copolymers were created by this moiety of DETA quaternary ammonium, heterobifunctional polyethylene glycol (COOH-PEG-NH{sub 2}), phenylalanine (phe), and poly(lactic-co-glycolic acid) (PLGA). These new cNPs were prepared by the water miscible solvent displacement method. They exhibit good pDNA binding ability, as shown in a retardation assay that occurred at a particle size of ∼217 nm. The zeta potential was approximately +21 mV when the cNP concentration was 25 mg/ml. The new cNPs also have a better buffering capacity than PLGA NPs. However, the pDNA binding ability was demonstrated starting at a weight ratio of approximately 6.25 cNPs/pDNA. Gene transfection results showed that these cNPs had transfection effects similar to those of Lipofectamine 2000 in 293T cells. Furthermore, cNPs can also transfect human adipose-derived stem cells. The results indicate that the newly developed cNP is a promising candidate for a novel gene delivery vehicle.

  7. Preliminary results of paleoseismic investigations of Quaternary faults on eastern Yucca Mountain, Nye County, Nevada

    Energy Technology Data Exchange (ETDEWEB)

    Menges, C.M.; Oswald, J.A.; Coe, J.A. [and others

    1995-12-31

    Site characterization of the potential nuclear waste repository at Yucca Mountain, Nevada, requires detailed knowledge of the displacement histories of nearby Quaternary faults. Ongoing paleoseismic studies provide data on the amount and rates of Quaternary activity on the Paintbrush Canyon, Bow Ridge, and Stagecoach Road faults along the eastern margin of the mountain over varying time spans of 0-700 ka to perhaps 0-30 ka, depending on the site. Preliminary stratigraphic interpretations of deposits and deformation at many logged trenches and natural exposures indicate that each of these faults have experienced from 3 to 8 surface-rupturing earthquakes associated with variable dip-slip displacements per event ranging from 5 to 115 cm, and commonly in the range of 20 to 85 cm. Cumulative dip-slip offsets of units with broadly assigned ages of 100-200 ka are typically less than 200 cm, although accounting for the effects of possible left normal-oblique slip could increase these displacements by factors of 1.1 to 1.7. Current age constraints indicate recurrence intervals of 10{sup 4} to 10{sup 5} years (commonly between 30 and 80 k.y.) and slip rates of 0.001 to 0.08 mm/yr (typically 0.01-0.02 mm/yr). Based on available timing data, the ages of the most recent ruptures varies among the faults; they appear younger on the Stagecoach Road Fault ({approximately}5-20 ka) relative to the southern Paintbrush Canyon and Bow Ridge faults ({approximately}30-100 ka).

  8. Tribological performance evidence on ternary and quaternary nitride coatings applied for industrial steel

    Energy Technology Data Exchange (ETDEWEB)

    Caicedo, J. C.; Aguilar, Y. [Universidad del Valle, School of Materials Engineering, Ciudad Universitaria Melendez, Calle 13 No. 100-00, Edif. 320, A. A. 25360 Cali (Colombia); Aperador, W., E-mail: jcaicedoangulo1@gmail.com [Universidad Militar Nueva Granada, Department of Engineering, Carrera 11 No. 101-80, 6343200 Bogota D. C. (Colombia)

    2013-08-01

    A diagnostic of mechanical and tribological behavior in ternary Ti-C-N and quaternary Ti-Nb-C-N films deposited onto Si (100) and 4140 steel substrates by r.f. magnetron sputtering process varying negative bias voltage from 0 to 100 V, was done in this work. Growth parameters as power density, Ar/N{sub 2} flow rate, and substrate temperature were kept constant at the moment of the deposition. Introduction of Nb in the ternary Ti-C-N film was evaluated by X-ray diffraction analysis. Quantitative elemental concentration depth profile by glow discharge optical emission spectroscopy and the morphology via scanning electron microscopy were observed for the layers before the tests. Mechanical and tribological properties for both coatings were obtained by mean of nano indentation measurements through load versus displacement method, and scratch test using the critical load criterion, respectively. The failure modes from scratch test were observed via optical microscopy. X-ray diffraction results show as the amount of Nb is increased into the quaternary phase, the preferred orientation change in the film dur to the modification in the strain and lattice parameter. Energy dispersive X-ray results from previous work show the Ti CN and TiNbCN layers were stoichiometric. Nano indentation results reaching the elastic-plastic behavior of the Ti CN and Ti CN films with inclusion of Nb (TiNbCN), indicate not only the hardness and elastic modulus but also the critical load for the adhesive failure increase when increasing r.f negative bias voltage. An improvement of hardness and critical load around 60% and 28% for Ti CN as well as 26% and 31% for TiNbCN, respectively, was associated to an increasing in the r.f negative bias voltage from 0 to - 100 V. (Author)

  9. Phylogeography of Rhodiola kirilowii (Crassulaceae: a story of Miocene divergence and quaternary expansion.

    Directory of Open Access Journals (Sweden)

    Jian-Qiang Zhang

    Full Text Available The evolution and current distribution of the Sino-Tibetan flora have been greatly affected by historical geological events, such as the uplift of the Qinghai-Tibetan Plateau (QTP, and Quaternary climatic oscillations. Rhodiola kirilowii, a perennial herb with its distribution ranging from the southeastern QTP and the Hengduan Mountains (HM to adjacent northern China and central Asia, provides an excellent model to examine and disentangle the effect of both geological orogeny and climatic oscillation on the evolutionary history of species with such distribution patterns. We here conducted a phylogeographic study using sequences of two chloroplast fragments (trnL-F and trnS-G and internal transcribed spacers in 29 populations of R. kirilowii. A total of 25 plastid haplotypes and 12 ITS ribotypes were found. Molecular clock estimation revealed deep divergence between the central Asian populations and other populations from the HM and northern China; this split occurred ca. 2.84 million year ago. The majority of populations from the mountains of northern China were dominated by a single haplotype or ribotype, while populations of the HM harbored both high genetic diversity and high haplotype diversity. This distribution pattern indicates that HM was either a diversification center or a refugium for R. kirilowii during the Quaternary climatic oscillations. The present distribution of this species on mountains in northern China may have resulted from a rapid glacial population expansion from the HM. This expansion was confirmed by the mismatch distribution analysis and negative Tajima's D and Fu's FS values, and was dated to ca. 168 thousand years ago. High genetic diversity and population differentiation in both plastid and ITS sequences were revealed; these imply restricted gene flow between populations. A distinct isolation-by-distance pattern was suggested by the Mantel test. Our results show that in old lineages, populations may harbour

  10. Human Antibodies that Recognize Novel Immunodominant Quaternary Epitopes on the HIV-1 Env Protein

    Science.gov (United States)

    Hicar, Mark D.; Chen, Xuemin; Sulli, Chidananda; Barnes, Trevor; Goodman, Jason; Sojar, Hakimuddin; Briney, Bryan; Willis, Jordan; Chukwuma, Valentine U.; Kalams, Spyros A.; Doranz, Benjamin J.; Spearman, Paul; Crowe, James E.

    2016-01-01

    Numerous broadly neutralizing antibodies (Abs) target epitopes that are formed or enhanced during mature HIV envelope formation (i.e. quaternary epitopes). Generally, it is thought that Env epitopes that induce broadly neutralizing Abs are difficult to access and poorly immunogenic because of the characteristic oligomerization, conformational flexibility, sequence diversity and extensive glycosylation of Env protein. To enhance for isolation of quaternary epitope-targeting Abs (QtAbs), we previously used HIV virus-like particles (VLPs) to bind B cells from long-term non-progressor subjects to identify a panel of monoclonal Abs. When expressed as recombinant full-length Abs, a subset of these novel Abs exhibited the binding profiles of QtAbs, as they either failed to bind to monomeric Env protein or showed much higher affinity for Env trimers and VLPs. These QtAbs represented a significant proportion of the B-cell response identified with VLPs. The Ab genes of these clones were highly mutated, but they did not neutralize common HIV strains. We sought to further define the epitopes targeted by these QtAbs. Competition-binding and mapping studies revealed these Abs targeted four separate epitopes; they also failed to compete for binding by Abs to known major neutralizing epitopes. Detailed epitope mapping studies revealed that two of the four epitopes were located in the gp41 subunit of Env. These QtAbs bound pre-fusion forms of antigen and showed differential binding kinetics depending on whether oligomers were produced as recombinant gp140 trimers or as full-length Env incorporated into VLPs. Antigenic regions within gp41 present unexpectedly diverse structural epitopes, including these QtAb epitopes, which may be targeted by the naturally occurring Ab response to HIV infection. PMID:27411063

  11. Human Antibodies that Recognize Novel Immunodominant Quaternary Epitopes on the HIV-1 Env Protein.

    Directory of Open Access Journals (Sweden)

    Mark D Hicar

    Full Text Available Numerous broadly neutralizing antibodies (Abs target epitopes that are formed or enhanced during mature HIV envelope formation (i.e. quaternary epitopes. Generally, it is thought that Env epitopes that induce broadly neutralizing Abs are difficult to access and poorly immunogenic because of the characteristic oligomerization, conformational flexibility, sequence diversity and extensive glycosylation of Env protein. To enhance for isolation of quaternary epitope-targeting Abs (QtAbs, we previously used HIV virus-like particles (VLPs to bind B cells from long-term non-progressor subjects to identify a panel of monoclonal Abs. When expressed as recombinant full-length Abs, a subset of these novel Abs exhibited the binding profiles of QtAbs, as they either failed to bind to monomeric Env protein or showed much higher affinity for Env trimers and VLPs. These QtAbs represented a significant proportion of the B-cell response identified with VLPs. The Ab genes of these clones were highly mutated, but they did not neutralize common HIV strains. We sought to further define the epitopes targeted by these QtAbs. Competition-binding and mapping studies revealed these Abs targeted four separate epitopes; they also failed to compete for binding by Abs to known major neutralizing epitopes. Detailed epitope mapping studies revealed that two of the four epitopes were located in the gp41 subunit of Env. These QtAbs bound pre-fusion forms of antigen and showed differential binding kinetics depending on whether oligomers were produced as recombinant gp140 trimers or as full-length Env incorporated into VLPs. Antigenic regions within gp41 present unexpectedly diverse structural epitopes, including these QtAb epitopes, which may be targeted by the naturally occurring Ab response to HIV infection.

  12. Synthesis and Spectroscopic Characterisation of 2,3-Epoxy/3-Chloro-2-hydroxy Propyl Derivatives of Quaternary Ammonium Salts: Useful Cationic Fixing Agents

    Institute of Scientific and Technical Information of China (English)

    SHARIF Saima; AHMAD Saeed; IZHAR-UL-HAQ Mian Muhammad

    2008-01-01

    Eight mono-reactive and four bis-reactive 2,3-epoxy/3-chloro-2-hydroxy propyl derivatives of quaternary ammonium salts have been synthesised by reacting epichlorohydrin with suitable tertiary amines and diamines.Mono-reactive derivatives also contain cyano and carboxylic groups in addition to 2,3-epoxy/3-chloro-2-hydroxy propyl groups. The structures of these quaternary ammonium salts have been characterised using IR and 1H NMR spectroscopic techniques. These quaternary ammonium chlorides have been applied to the cotton fabrics as pretreatments and aftertreatments and promising results have been obtained.

  13. Estimated Altitude of the Consolidated Rock Surface Underlying Quaternary Sediments of the Wood River Valley aquifer system, South-Central Idaho

    Data.gov (United States)

    U.S. Geological Survey, Department of the Interior — This dataset is the estimated altitude of the consolidated rock surface underlying Quaternary sediment of the Wood River Valley aquifer system. This surface is...

  14. Trapping of carbolithiation-derived tertiary benzylic α-lithio piperidines with carbon electrophiles: Controlling the formation of α-amino quaternary and vicinal stereocenters.

    Science.gov (United States)

    Beng, Timothy K; Fox, Nathan; Bassler, Daniel P; Alwali, Amir; Sincavage, Kayla; Silaire, Ann Wens V

    2015-08-28

    The interception of carbolithiation-derived tertiary benzylic α-lithio piperidines with carbon electrophiles, under HMPA-mediated conditions, has led to the diastereoselective synthesis of vicinally functionalized piperidines bearing α-amino quaternary stereocenters.

  15. Late Quaternary paleoceanographic features as deduced from calcium carbonate and faunal changes of planktonic foraminifers in core samples from northeastern Arabian Sea

    Digital Repository Service at National Institute of Oceanography (India)

    Rao, K.K.; Jayalakshmy, K.V.; Singh, A.D.

    carbonate and planktonic foraminifers, with implications on paleoceanography of the Arabian Sea during late Quaternary. Paleoclimatic curve based on per cent variations of carbonate is substantiated by the faunal characteristics. Low value of cold...

  16. The Unseen Founders Of Quaternary Science - The Men Of Glasgow, Scotland (Invited)

    Science.gov (United States)

    Rose, J.

    2010-12-01

    Louis Agassiz (1807-1873) and Charles Lyell (1797-1875) are widely regarded as the founders of Quaternary Science, and there is no doubt that they played their part: Agassiz in 1840 presented and promoted his case for the wide-scale fluctuations of glaciers, and Lyell, through his books and contacts, did much to introduce the subject which we now know as climate change. However there are a number of individuals who contributed to the founding of Quaternary Science who are not so readily recognised and a remarkable fact is that a significant proportion were men without academic training or background who come from, or worked in Glasgow or the adjacent region of central Scotland. First amongst the Glaswegians was James Smith (1782-1867) who, in 1836 presented a paper to the Geological Society of London (where it was duly ignored) in which he suggested, on the basis of fossils dredged from the bed of the Clyde and experience of sailing around Iceland, that the climate of Scotland had been as cold as that of Iceland in the recent past. In 1841, Charles Maclaren (1782-1866) a journalist from Edinburgh, but using information based on raised shorelines near Glasgow proposed what we now know as the glacio-eustatic theory in which the variations in glacier extent control the level of the sea. Perhaps the most important of all was James Croll (1821- 1890) who worked on the theory of ice ages, based on orbital forcing, while janitor at the Andersonian Institute and Museum in Glasgow between 1859-1867. This work was the true precursor to the Milankovitch theory which provides the explanation for the major predictable elements of climate change. Robert Jack (1845-1921) from Irvine, southwest of Glasgow, while doing fieldwork for the British Geological Survey near Loch Lomond close to Glasgow, described in 1874 evidence for non-glacial conditions between tills and clearly recognised that climate could change from glacial to temperate and then glacial climate, before returning to

  17. Quaternary shorelines of the broader area of Cape Maleas - Neapolis - Elafonissos Isl. (SE Peloponnese)

    Science.gov (United States)

    Karymbalis, Efthimios; Gaki-Papanastassiou, Kalliopi; Papanastassiou, Dimitris; Tsodoulos, Ioannis; Tsivgoulis, Nikolaos; Tsanakas, Konstantinos; Valkanou, Kanella

    2015-04-01

    The aim of this study is to provide information about the landscape evolution of the broader area of Cape Maleas - Neapolis - Elafonissos Isl. during the Quaternary. In order to investigate the geomorphic evolution of the study area the uplifted coastal landforms, such as shore platforms, notches and remnants of marine terraces, were studied in detail through extensive field-work using topographic diagrams at a scale of 1:5,000, obtained from the Hellenic Military Geographical Service. Additionally, a spatial database was constructed derived from analogue topographic maps at various scales (1:50,000 and 1:5,000), geological maps (1:50,000 maps of IGME), aerial photographs and Google earth images using GIS techniques. The study area is located in SE Peloponnese in a particularly tectonically active area. Geodynamic processes in the region, which is part of the Hellenic island arc, are related to the active subduction of the African lithosphere beneath the Eurasian plate. The Paleozoic basement of the study area consists of geological formations of the geotectonic units of Arna, Tripolis, and Pindus. The Alpine basement is overlain by extensive outcrops of Pliocene and Pleistocene deposits. Upper Pliocene to Lower Pleistocene formations are composed of marine - lacustrine deposits which are mainly pelites, sandstones, conglomerates, calcarenites and carbonate rocks with red algae whereas Pleistocene formations consist of fluvioterrential deposits (clay, sands, loams and angular rock fragments). The Holocene deposits consist of talus cones, scree, and unconsolidated alluvial deposit, eluvial mantle materials and coastal sand dunes along the N, NE and S shoreline of Elafonissos Isl. as well as at Cape Punta. The general trend of the faults in the study area is mainly NW-SE with some secondary ones having NE-SW direction. Along the coast between Cape Koulendi and Cape Maleas, uplifted geomorphological features were mapped, including marine terraces, shore platforms and

  18. Highly luminescent water-soluble quaternary Zn-Ag-In-S quantum dots for tumor cell-targeted imaging.

    Science.gov (United States)

    Deng, Dawei; Cao, Jie; Qu, Lingzhi; Achilefu, Samuel; Gu, Yueqing

    2013-04-14

    Exploring the synthesis and biomedical applications of biocompatible quantum dots (QDs) is currently one of the fastest growing fields of nanotechnology. Hence, in this work, we present a facile approach to produce water-soluble (cadmium-free) quaternary Zn-Ag-In-S (ZAIS) QDs. Their efficient photoluminescence (PL) emissions can be tuned widely in the range of 525-625 nm by controlling the size and composition of the QDs with the PL quantum yields (QYs) of 15-30%. These highly luminescent ZAIS QDs are less toxic due to the absence of highly toxic cadmium, and can be versatilely modified by a DHLA-PEG-based ligand. Importantly, after being modified by tumor cell-specific targeting ligands (e.g., folate and RGD peptide), the PEGylated quaternary QDs show potential applications in tumor cell imaging as a promising alternative for Cd-based QDs.

  19. Optical analysis of lens-like Cu{sub 2}CdSnS{sub 4} quaternary alloy nanostructures

    Energy Technology Data Exchange (ETDEWEB)

    Odeh, Ali Abu; Ayub, R.M. [University Malaysia Perlis, Institute of Nano Electronic Engineering, Kangar, Perlis (Malaysia); Al-Douri, Y. [University Malaysia Perlis, Institute of Nano Electronic Engineering, Kangar, Perlis (Malaysia); University of Sidi-Bel-Abbes, Physics Department, Faculty of Science, Sidi-Bel-Abbes (Algeria); Ameri, M. [Universite Djilali Liabes de Sidi Bel- Abbes, Laboratoire Physico-Chimie des Materiaux Avances (LPCMA), Sidi-Bel-Abbes (Algeria); Bouhemadou, A. [University of Setif 1, Laboratory for Developing New Materials and Their Characterization, Setif (Algeria); Prakash, Deo [SMVD University, Faculty of Engineering, School of Computer Science and Engineering, Kakryal, Katra, J and K (India); Verma, K.D. [S.V. College, Material Science Research Laboratory, Department of Physics, Aligarh, U.P. (India)

    2016-10-15

    Cu{sub 2}CdSnS{sub 4} quaternary alloy nanostructures with different copper concentrations (0.2, 0.4, 0.6, 0.8 and 1.0 M) were successfully synthesized on n-type silicon substrates using spin coating technique with annealing temperature at 300 C. Optical properties were analyzed through UV-Vis and Photoluminescence spectroscopies, and thus, there is a change in energy band gap with increasing Cu concentration from 0.2 to 1.0 M. The structural properties of Cu{sub 2}CdSnS{sub 4} quaternary alloy nanostructures were investigated by X-ray diffraction. The particles size and shape have a direct relationship with copper concentration. Morphological and topographical studies were carried out by using scanning electron microscopy and atomic force microscopy. The obtained results are investigated to be available in the literature for future studies. (orig.)

  20. Superhydrophobic cotton fabric coating based on a complex layer of silica nanoparticles and perfluorooctylated quaternary ammonium silane coupling agent

    Science.gov (United States)

    Yu, Minghua; Gu, Guotuan; Meng, Wei-Dong; Qing, Feng-Ling

    2007-01-01

    A superhydrophobic complex coating for cotton fabrics based on silica nanoparticles and perfluorooctylated quaternary ammonium silane coupling agent (PFSC) was reported in this article. The complex thin film was prepared through a sol-gel process using cotton fabrics as a substrate. Silica nanoparticles in the coating made the textile surface much rougher, and perfluorooctylated quaternary ammonium silane coupling agent on the top layer of the surface lowered the surface free energy. Textiles coated with this coating showed excellent water repellent property, and water contact angle (CA) increased from 133° on cotton fabrics treated with pure PFSC without silica sol pretreatment up to 145°. The oil repellency was also improved and the contact angle of CH 2I 2 droplet on the fabric surface reached to 131°. In contrast, the contact angle of CH 2I 2 on the fabric surface treated with pure PFSC was only 125°.

  1. Glacial meltwater impounding: Evidence from the late Quaternary glaciogenic sediments in the Sangla valley, district Kinnaur, Himachal Pradesh, India

    Indian Academy of Sciences (India)

    R K Ganjoo; M N Koul

    2005-08-01

    Sangla valley is situated at an altitude of ∼3500m above mean sea level and lies in the Kinnaur district of Himachal Pradesh. It is fed by river Baspa, a tributary of river Sutlej, that entrenches through the Quaternary glaciogenic deposits before emerging out of the valley and joining the river Sutlej at Karcham. The unstratified to stratified glaciogenic deposits consist of large boulders to fine silt and are classified into four major depositional facies on the basis of sedimentary texture and depositional environment. The facies — basal conglomerates, debris flow, water/sheet flow and laminites — represents the change in the environment of deposition from glaciofluvial to lacustrine and also the extent of the glacier to the valley floor during late Quaternary.

  2. Synthesis and crystal structure of the quaternary compound AgFe{sub 2}GaTe{sub 4}

    Energy Technology Data Exchange (ETDEWEB)

    Delgado, Gerzon E., E-mail: gerzon@ula.ve [Laboratorio de Cristalografía, Departamento de Química, Facultad de Ciencias, Universidad de Los Andes, Mérida 5101 (Venezuela, Bolivarian Republic of); Quintero, Eugenio; Tovar, Rafael; Grima-Gallardo, Pedro; Quintero, Miguel [Centro de Estudio de Semiconductores, Departamento de Física, Facultad de Ciencias, Universidad de Los Andes, Mérida 5101 (Venezuela, Bolivarian Republic of)

    2014-11-15

    Highlights: • New quaternary compound. • Synthesis from solid state reaction. • Crystal structure. • Rietveld refinement. - Abstract: The crystal structure of the quaternary compound AgFe{sub 2}GaTe{sub 4}, belonging to the system I–II{sub 2}–III–VI{sub 4}, was characterized by Rietveld refinement using X-ray powder diffraction data. The powder pattern was composed by 84.5% of the principal phase AgFe{sub 2}GaTe{sub 4} and 15.5% of the secondary phase FeTe. This material crystallizes with stannite structure in the tetragonal space group I-42m (N° 121), Z = 2, unit cell parameters a = 6.3409(2) Å, c = 12.0233(4) Å, V = 483.42(3) Å{sup 3}, and is isostructural with CuFe{sub 2}InSe{sub 4}.

  3. Radiocarbon dating late Quaternary loess deposits using small terrestrial gastropod shells

    Science.gov (United States)

    Pigati, Jeff S.; McGeehin, John P.; Muhs, Daniel R.; Bettis, E. Arthur

    2013-01-01

    Constraining the ages and mass accumulation rates of late Quaternary loess deposits is often difficult because of the paucity of organic material typically available for 14C dating and the inherent limitations of luminescence techniques. Radiocarbon dating of small terrestrial gastropod shells may provide an alternative to these methods as fossil shells are common in loess and contain ∼12% carbon by weight. Terrestrial gastropod assemblages in loess have been used extensively to reconstruct past environmental conditions but have been largely ignored for dating purposes. Here, we present the results of a multi-faceted approach to understanding the potential for using small terrestrial gastropod shells to date loess deposits in North America. First, we compare highly resolved 14C ages of well-preserved wood and gastropod shells (Succineidae) recovered from a Holocene loess section in Alaska. Radiocarbon ages derived from the shells are nearly identical to wood and plant macrofossil ages throughout the section, which suggests that the shells behaved as closed systems with respect to carbon for at least the last 10 ka (thousands of calibrated 14C years before present). Second, we apply 14C dating of gastropod shells to late Pleistocene loess deposits in the Great Plains using stratigraphy and independent chronologies for comparison. The new shell ages require less interpretation than humic acid radiocarbon ages that are commonly used in loess studies, provide additional stratigraphic coverage to previous dating efforts, and are in correct stratigraphic order more often than their luminescence counterparts. Third, we show that Succineidae shells recovered from historic loess in the Matanuska River Valley, Alaska captured the 20th century 14C bomb spike, which suggests that the shells can be used to date late Holocene and historic-aged loess. Finally, results from Nebraska and western Iowa suggest that, similar to other materials, shell ages approaching ∼40 ka should

  4. Evidence for alternative quaternary structure in a bacterial Type III secretion system chaperone

    Directory of Open Access Journals (Sweden)

    Picking Wendy L

    2010-07-01

    Full Text Available Abstract Background Type III secretion systems are a common virulence mechanism in many Gram-negative bacterial pathogens. These systems use a nanomachine resembling a molecular needle and syringe to provide an energized conduit for the translocation of effector proteins from the bacterial cytoplasm to the host cell cytoplasm for the benefit of the pathogen. Prior to translocation specialized chaperones maintain proper effector protein conformation. The class II chaperone, Invasion plasmid gene (Ipg C, stabilizes two pore forming translocator proteins. IpgC exists as a functional dimer to facilitate the mutually exclusive binding of both translocators. Results In this study, we present the 3.3 Å crystal structure of an amino-terminally truncated form (residues 10-155, denoted IpgC10-155 of the class II chaperone IpgC from Shigella flexneri. Our structure demonstrates an alternative quaternary arrangement to that previously described for a carboxy-terminally truncated variant of IpgC (IpgC1-151. Specifically, we observe a rotationally-symmetric "head-to- head" dimerization interface that is far more similar to that previously described for SycD from Yersinia enterocolitica than to IpgC1-151. The IpgC structure presented here displays major differences in the amino terminal region, where extended coil-like structures are seen, as opposed to the short, ordered alpha helices and asymmetric dimerization interface seen within IpgC1-151. Despite these differences, however, both modes of dimerization support chaperone activity, as judged by a copurification assay with a recombinant form of the translocator protein, IpaB. Conclusions From primary to quaternary structure, these results presented here suggest that a symmetric dimerization interface is conserved across bacterial class II chaperones. In light of previous data which have described the structure and function of asymmetric dimerization, our results raise the possibility that class II

  5. Sedimentological imprint on subseafloor microbial communities in Western Mediterranean Sea Quaternary sediments

    Directory of Open Access Journals (Sweden)

    M.-C. Ciobanu

    2012-09-01

    Full Text Available An interdisciplinary study was conducted to evaluate the relationship between geological and paleoenvironmental parameters and the bacterial and archaeal community structure of two contrasting subseafloor sites in the Western Mediterranean Sea (Ligurian Sea and Gulf of Lion. Both depositional environments in this area are well-documented from paleoclimatic and paleooceanographic point of views. Available data sets allowed us to calibrate the investigated cores with reference and dated cores previously collected in the same area, and notably correlated to Quaternary climate variations. DNA-based fingerprints showed that the archaeal diversity was composed by one group, Miscellaneous Crenarchaeotic Group (MCG, within the Gulf of Lion sediments and of nine different lineages (dominated by MCG, South African Gold Mine Euryarchaeotal Group (SAGMEG and Halobacteria within the Ligurian Sea sediments. Bacterial molecular diversity at both sites revealed mostly the presence of the classes Alphaproteobacteria, Betaproteobacteria and Gammaproteobacteria within Proteobacteria phylum, and also members of Bacteroidetes phylum. The second most abundant lineages were Actinobacteria and Firmicutes at the Gulf of Lion site and Chloroflexi at the Ligurian Sea site. Various substrates and cultivation conditions allowed us to isolate 75 strains belonging to four lineages: Alpha-, Gammaproteobacteria, Firmicutes and Actinobacteria. In molecular surveys, the Betaproteobacteria group was consistently detected in the Ligurian Sea sediments, characterized by a heterolithic facies with numerous turbidites from a deep-sea levee. Analysis of relative betaproteobacterial abundances and turbidite frequency suggested that the microbial diversity was a result of main climatic changes occurring during the last 20 ka. Statistical direct multivariate canonical correspondence

  6. Southern East Siberia PlioceneeQuaternary faults:Database, analysis and inference

    Institute of Scientific and Technical Information of China (English)

    Oksana V. Lunina; Riccardo Caputo; Anton A. Gladkov; Andrey S. Gladkov

    2014-01-01

    This paper presents the first release of an Informational System (IS) devoted to the systematic collection of all available data relating to PlioceneeQuaternary faults in southern East Siberia, their critical analysis and their seismotectonic parameterization. The final goal of this project is to form a new base for improving the assessment of seismic hazard and other natural processes associated with crustal defor-mation. The presented IS has been exploited to create a relational database of active and conditionally active faults in southern East Siberia (between 100º-114º E and 50º-57ºN) whose central sector is characterized by the highly seismic Baikal rift zone. The information within the database for each fault segment is organized as distinct but intercorrelated sections (tables, texts and pictures, etc.) and can be easily visualized as HTML pages in offline browsing. The preliminary version of the database distributed free on disk already highlights the general fault pattern showing that the Holocene and historical activity is quite uniform and dominated by NEeSW and nearly EeW trending faults;the former with a prevailing dip-slip normal kinematics, while the latter structures are left-lateral strike-slip and oblique-slip (with different proportion of left-lateral and normal fault slip components). These faults are mainly concen-trated along the borders of the rift basins and are the main sources of moderate-to-strong (M≧5.5) earthquakes on the southern sectors of East Siberia in recent times. As a whole, based on analyzing the diverse fault kinematics and their variable spatial distribution with respect to the overall pattern of the tectonic structures formed and/or activated during the late PlioceneeQuaternary, we conclude they were generated under a regional stress field mainly characterized by a relatively uniform NWeSE tension, but strongly influenced by the irregular hard boundary of the old Siberian craton. The obtained inferences are in an

  7. Quaternary vegetation and climate changes on Banks Peninsula, South Island, New Zealand

    Science.gov (United States)

    Soons, J. M.; Moar, N. T.; Shulmeister, J.; Wilson, H. D.; Carter, J. A.

    2002-07-01

    Late Quaternary terrestrial and marine pollen records from the Canterbury Plains and Banks Peninsula suggest that climates during the peak of Marine Isotope Stage 7 (MIS 7) were similar to those prevailing during stage 5e and the Holocene. Podocarp forest (notably Prumnopitys taxifolia—matai) characterises each interglaciation. In contrast, marine records from DSDP 594 cores, off the east coast of Canterbury, indicate that stage 7 was dominated by montane forest ( Libocedrus sp. and Phyllocladus). This suggests temperatures as much as 3 °C colder than indicated by the Banks Peninsula assemblage. Age control from both sites appears to be robust. Some of the differences may be related to the taphonomy of the pollen at both sites. DSDP 594 may reflect a more southerly catchment of fluvially and aeolian-derived pollen than does the Banks Peninsula site. Banks Peninsula was alternately separated from, and joined to, the mainland as Quaternary sea levels fell and rose. Assuming modern ocean current patterns, during interglacials the south-north Southland Current would have swept through the seaway separating the island from the mainland, diverting the flow of rivers embouching on the Canterbury coast, and moving sediments and fluvially transported pollen northwards. Little of this material would have reached DSDP 594, nor, if wind patterns were similar to those of today, would wind-borne pollen from Banks Peninsula have reached the site. It is probable that vegetation on the Peninsula was consistently distinct from that recorded at DSDP 594, which has a more southerly derivation. In contrast to the high mountain areas of the South Island, the low levels of grass pollen in the available record suggest that the Peninsula retained a woody vegetation over much of its area during glacial periods. This was favoured by the physiography of the area, with a variety of micro-climates, and by the extensive areas available for colonisation at times of low sea level. The podocarp

  8. Evidence for alternative quaternary structure in a bacterial Type III secretion system chaperone

    Energy Technology Data Exchange (ETDEWEB)

    Barta, Michael L.; Zhang, Lingling; Picking, Wendy L.; Geisbrecht, Brian V. (UMKC); (OKLU)

    2010-10-05

    Type III secretion systems are a common virulence mechanism in many Gram-negative bacterial pathogens. These systems use a nanomachine resembling a molecular needle and syringe to provide an energized conduit for the translocation of effector proteins from the bacterial cytoplasm to the host cell cytoplasm for the benefit of the pathogen. Prior to translocation specialized chaperones maintain proper effector protein conformation. The class II chaperone, Invasion plasmid gene (Ipg) C, stabilizes two pore forming translocator proteins. IpgC exists as a functional dimer to facilitate the mutually exclusive binding of both translocators. In this study, we present the 3.3 {angstrom} crystal structure of an amino-terminally truncated form (residues 10-155, denoted IpgC10-155) of the class II chaperone IpgC from Shigella flexneri. Our structure demonstrates an alternative quaternary arrangement to that previously described for a carboxy-terminally truncated variant of IpgC (IpgC{sup 1-151}). Specifically, we observe a rotationally-symmetric 'head-to-head' dimerization interface that is far more similar to that previously described for SycD from Yersinia enterocolitica than to IpgC1-151. The IpgC structure presented here displays major differences in the amino terminal region, where extended coil-like structures are seen, as opposed to the short, ordered alpha helices and asymmetric dimerization interface seen within IpgC{sup 1-151}. Despite these differences, however, both modes of dimerization support chaperone activity, as judged by a copurification assay with a recombinant form of the translocator protein, IpaB. Conclusions: From primary to quaternary structure, these results presented here suggest that a symmetric dimerization interface is conserved across bacterial class II chaperones. In light of previous data which have described the structure and function of asymmetric dimerization, our results raise the possibility that class II chaperones may

  9. Influence of fluvial processes on the quaternary geologic framework of the continental shelf, North Carolina, USA

    Science.gov (United States)

    Boss, S.K.; Hoffman, C.W.; Cooper, B.

    2002-01-01

    Digital, single-channel, high-resolution seismic reflection profiles were acquired from the insular continental shelf of North Carolina, USA along a data grid extending from Oregon Inlet northward 48 km to Duck, North Carolina and from the nearshore zone seaward approximately 28 km (total surveyed area= 1334 km2). These data were processed and interpreted to delineate principal reflecting horizons and develop a three-dimensional seismic stratigraphic framework for the continental shelf that was compared to stratigraphic data from the shoreward back-barrier (estuarine) and barrier island system. Six principal reflecting horizons (designated R0 through R5) were present within the upper 60 m of the shelf stratigraphic succession. Three-dimensional mapping of reflector R1 demonstrated its origin from fluvial incision of the continental shelf during an episode (or episodes) of lowered sea-level. Fluvial processes during development of reflector R1 were responsible for extensive reworking and re-deposition of sediment throughout most of the northern half of the study area. Five seismic stratigraphic units (designated S1 through S5) were tentatively correlated with depositional sequences previously identified from the North Carolina back-barrier (estuarine) and barrier island system. These five stratigraphic units span the Quaternary Period (S1 = early Holocene; S2 = 51-78 ka; S3 = 330-530 ka; S4 = 1.1-1.8 Ma; S5 = earliest Pleistocene). Unit S1 is composed of fine-grained fluvial/estuarine sediment that back-filled incised streams during early Holocene sea-level rise. The four other stratigraphic units (S2-S5) display tabular depositional geometries, low total relief, and thicken toward the east-southeast as their basal reflectors dip gently between 0.41 m km-1 (0.02??) and 0.54 m km-1 (0.03??). Knowledge of the three-dimensional subsurface stratigraphic architecture of the continental shelf enhances understanding of the development of shelf depositional successions and

  10. The Quaternary Pan-lake (Overflow) Period and Paleoclimate on the Qinghai-Tibet Plateau

    Institute of Scientific and Technical Information of China (English)

    ZHENG Mianping; YUAN Heran; ZHAO Xitao; LIU Xifang

    2005-01-01

    Lake geomorphology and high-level lacustrine deposits since the mid-late Pleistocene are well preserved in lakes of the Qinghai-Tibet Plateau. According to geological surveys of 17 lake districts in different locations of the plateau,combined with interpretations of satellite images and topographic maps, the authors studied the timing of formation and scopes of the pan-lake areas of the plateau and their paleoclimate. The latest two high lake levels (overflow surfaces) on the Qinghai-Tibet Plateau in the Quaternary occurred at ~40 to 30/35 ka and ~65 to 53 ka respectively. In these time intervals, the plateau was covered by huge interconnected pan-lake systems with a total area of ~36 km2 and a total volume of lake water of >530 million km2, which are about 38 times and 659 times larger than those of the modem lakes respectively. Before this pan-lake period in the late Pleistocene, there had been three high lake levels that occurred at ~132-112 ka, 110-95 ka and 91-72/~83-75 ka respectively, suggesting that the late Quaternary climate on the plateau was unstable and changed rapidly. The ~40-30 ka high lake level also appeared in the Tengger desert north of the plateau,suggesting that there existed very strong summer monsoons from South Asia then; the variation in solar radiation with a 20,000 precessional period has special importance for the high-altitude Qinghai-Tibet Plateau in the low-latitude zone of the Earth. Around 30 ka, the pan-lakes at the peripheries of the Qinghai-Tibet Plateau drained out suddenly with rapid uplift of the plateau and cooling. In a short time the huge amount of cold lake water emptied into the Indian Ocean and Western Pacific. The draining event of the pan-lakes brought about the environmental changes of rivers and lakes at peripheries of the plateau.

  11. Quaternary IPM (integrated pest management)--concept for the control of powdery mildew in sugar beets.

    Science.gov (United States)

    Wolf, P F J; Verreet, A

    2008-01-01

    Powdery mildew, caused by Erysiphe betae (Vanha) Weltzien, may be assumed as an important leaf disease in sugar beet growing areas of central Europe. Although the causal agent is mainly adapted to arid climatic zones, the disease is appearing every year, where the extent of infection is mainly dependent on weather conditions and susceptibility of cultivar. The losses caused by powdery mildew seldom exceed 10% of sugar yield; moreover, losses are likely only under the condition that the epidemic onset occurs before end-August. Nevertheless, the epidemic onset varies in a wide range, as there are years with high incidence followed by growing periods without severe infection. Therefore, in order to have a flexible control of the disease, where the use of fungicides could be minimised to an essential amount, a quaternary IPM (Integrated Pest Management) -concept was developed. The development is based on epidemiological field studies (Germany, 1993-2004, n = 76) of sugar beet leaf diseases under variation of year, site and cultivar. Efficacy of fungicide treatment timing was assessed in relation to the epidemic development. Comparison of treatments comprised fungicide sprays carried out from disease initiation till later stages of the epidemic. Additionally, the assessments were performed in relation to an untreated and a healthy control--the latter was three times treated according to a treatment regime with three to four week intervals. The effect of different application timings was measured by the potential of disease and yield loss control. The quaternary concept combines the advantages of four elements in order to compensate the constraints of the single tools: The period without disease risk is determined by a so-called negative-prognosis (i). First symptoms appear in the period from mid-July till the beginning of September. If disease initiation cannot be excluded, field observations by a sample of 100 leaves are advised. The disease scores enable the appliance

  12. Late Quaternary river channel migrations of the Kura River in Transcaucasia - tectonic versus climatic causes

    Science.gov (United States)

    von Suchodoletz, Hans; Gärtner, Andreas; Hoth, Silvan; Umlauft, Josefine; Godoladze, Tea; Faust, Dominik

    2015-04-01

    Large-scale river channel migrations either in the form of avulsions or combing, i.e. progressive lateral migrations, are global phenomena during the Late Quaternary. Such channel migrations were triggered by tectonics, climate change, human activity or a combination of those factors. River channel migrations have the potential to cause significant human and economic losses. Thus, a more thorough knowledge about underlying causes and process rates is essential. Furthermore, such studies will elucidate the sensitivity or robustness of rivers to different external and internal forcing-agents, i.e. they help to identify the dominant drivers of regional landscape evolution. The Caucasus region is part of the active collision zone between the Africa-Arabian and the Eurasian plates, and is characterized by high current tectonic activity. Furthermore, significant environmental changes took place during the Late Quaternary, i.e. the shrinking or even disappearance of glaciers in the Greater and Lesser Caucasus or fundamental changes of the vegetation cover varying between woodland and grassland-dominated vegetation. The Kura River is the main gaining stream of the Transcaucasian Depression located between the Greater Caucasus Mountains in the north and the Lesser Caucasus Mountains in the south, and receives several tributaries from both mountain ranges. This study focusses on the middle course of the Kura River in eastern Georgia, SE of the city of Tbilisi. Integration of fluvial geomorphology, geochronology, heavy mineral analyses and seismo-tectonic analyses demonstrates that this part of the Kura River underwent large-scale channel migrations up to >10 km during Late Pleistocene and Holocene. It is interpreted that these movements followed both tectonic and climatic triggers: Whereas SW-ward migrations were caused by tectonic uplift in and SW-directed advance of the Kura fold and thrust belt as part of the Greater Caucasus, NE-ward migrations occurred during cold

  13. Late Quaternary landscape evolution in the Great Karoo, South Africa: Processes and drivers.

    Science.gov (United States)

    Oldknow, Chris; Hooke, Janet; Lang, Andreas

    2016-04-01

    The Great Karoo spans the north-central part of South Africa at a major climatic boundary. The characteristics, sequences, spatial patterns and drivers of river response to Late Quaternary climate changes in this region remain unclear due to the fragmentary alluvial/colluvial stratigraphic record and the lack of dated palaeoclimatic archives. Dendritic gully networks incised into deep deposits (up to 6 m) of colluvium and alluvium in the upper Sundays River catchment expose a legacy of "cut and fill" features. In 1st order tributaries, these are predominantly discontinuous palaeochannels and flood-outs with localised palaeosols, whereas in 2nd & 3rd order tributaries there are: 1) incised palaeo-geomorphic surfaces, 2) semi-continuous inset terrace sequences, 3) buried palaeo-gully topography. Using a combination of field mapping, logging of sediment outcrops, soil micromorphological and grain size analysis, mineral magnetic measurements and radiometric dating (OSL & 14C), we derive a stratigraphic evolution model which demonstrates a) the number of phases of incision, aggradation and pedogenesis, b) the spatial and temporal extent of each phase and c) the drivers of alluviation and associated feedbacks. Our reconstruction of regional valley alluviation indicates four distinct terrace units of contrasting depositional age. The base of the succession reflects slow aggradation under periglacial conditions associated with the Last Glacial Maximum. Subsequent channel entrenchment, causing terrace abandonment (T1) occurred in the deglacial period when vegetation and rainfall were in anti-phase. Re-instatement of connectivity with deep upland colluvial stores resulted in the injection of a pulse of sediment to valley floors, triggering compartmentalised backfilling (aggradation of T2) which propagated upstream as far as the second order drainage lines. This backfilling restructured the local hydrology, which, in concert with enhanced summer-rainfall, contributed to a

  14. QuatIdent: a web server for identifying protein quaternary structural attribute by fusing functional domain and sequential evolution information.

    Science.gov (United States)

    Shen, Hong-Bin; Chou, Kuo-Chen

    2009-03-01

    Many proteins exist in vivo as oligomers with various different quaternary structural attributes rather than as single individual chains. They are the structural bases of various marvelous biological functions such as cooperative effects, allosteric mechanism, and ion-channel gating. Therefore, with the avalanche of protein sequences generated in the postgenomic era, it is very important for both basic research and drug discovery to identify their quaternary structural attributes in a timely manner. In view of this, a powerful ensemble identifier, called QuatIdent, is developed by fusing the functional domain and sequential evolution information. QuatIdent is a 2-layer predictor. The 1st layer is for identifying a query protein as belonging to which one of the following 10 main quaternary structural attributes: (1) monomer, (2) dimer, (3) trimer, (4) tetramer, (5) pentamer, (6) hexamer, (7) heptamer, (8) octamer, (9) decamer, and (10) dodecamer. If the result thus obtained turns out to be anything but monomer, the process will be automatically continued to further identify it as belonging to a homo-oligomer or hetero-oligomer. The overall success rate by QuatIdent for the 1st layer identification was 71.1% and that for the 2nd layer ranged from 84 to 96%. These rates were derived by the jackknife cross-validation tests on the stringent benchmark data sets where none of proteins has > or =60% pairwise sequence identity to any other in a same subset. QuatIdent is freely accessible to the public as a web server via the site at http://www.csbio.sjtu.edu.cn/bioinf/Quaternary/ , by which one can get the desired 2-level results for a query protein sequence in around 25 seconds. The longer the sequence is, the more time that is needed.

  15. Bandgap Tunability in Sb-Alloyed BiVO₄ Quaternary Oxides as Visible Light Absorbers for Solar Fuel Applications.

    Science.gov (United States)

    Loiudice, Anna; Ma, Jie; Drisdell, Walter S; Mattox, Tracy M; Cooper, Jason K; Thao, Timothy; Giannini, Cinzia; Yano, Junko; Wang, Lin-Wang; Sharp, Ian D; Buonsanti, Raffaella

    2015-11-01

    The challenge of fine compositional tuning and microstructure control in complex oxides is overcome by developing a general two-step synthetic approach. Antimony-alloyed bismuth vanadate, which is identified as a novel light absorber for solar fuel applications, is prepared in a wide compositional range. The bandgap of this quaternary oxide linearly decreases with the Sb content, in agreement with first-principles calculations.

  16. Th/U dating of marine and continental mollusk shell, and travertine samples in quaternary deposits in Morocco

    Science.gov (United States)

    Semghouli, S.; Choukri, A.; Cherkaoui El Moursli, R.; Jahjouh, E.; Chouak, A.; Ben Mohammadi, A.; Latiris, M.; Reyss, J.-L.; Plaziat, J. L.

    2001-06-01

    Th/U measurements by alpha spectrometry have been carried out on samples of quaternary deposits in Morocco Ages yielded by marine samples allow identification of two high sea levels: (1) Last Interglacial ˜133 ka (ii) Harounien sea level ˜266 ka. The scatter of ages around 133 and 266 ka has been discussed and corrected. For continental samples, the ages allowed identification of humid episodes during which these samples have been deposited.

  17. Ring-Contraction Strategy for the Practical, Scalable, Catalytic Asymmetric Synthesis of Versatile γ-Quaternary Acylcyclopentenes

    KAUST Repository

    Hong, Allen Y.

    2011-02-24

    Contraction action! A simple protocol for the catalytic asymmetric synthesis of highly functionalized γ-quaternary acylcyclopentenes (see schematic) in up to 91 % overall yield and 92 % ee has been developed. The reaction sequence employs a palladium-catalyzed enantioselective alkylation reaction and exploits the unusual stability of β-hydroxy cycloheptanones to achieve a general and robust method for performing two-carbon ring contractions.

  18. Studies of Quaternary deformation zones through geomorphic and geophysical evidence: A case in the Precordillera Sur, Central Andes of Argentina

    Science.gov (United States)

    Terrizzano, Carla M.; Fazzito, Sabrina Y.; Cortés, José M.; Rapalini, Augusto E.

    2010-07-01

    At the northern sector of the Precordillera Sur (31° 50'-32° 40' SL/68° 45'-69° 20' WL), Central Andes of Argentina, NW-trending sinistral transpressive shear zones at different scales, product of the Late Cenozoic Andean deformation, are recognized. The most significant of them is the 120 km long Barreal-Las Peñas Belt and within it, a small-scale (7 km long) Quaternary sinistral transpressive shear zone, called Los Avestruces, has been detected from geomorphological and geophysical analysis (32° SL/69° 21 WL). Geophysical techniques were applied to better characterize the shallow structure and kinematics of some representative structures in this shear zone. In particular, the use of tomography of electrical resistivity methods allowed characterizing the subsurface geometry of some areas of interest, enabling the recognition of Quaternary layers against their original slope, the geometry of the reverse fault which uplifted the Pleistocene deposits of one of the highs, the geometry of a likely previous extensional fault reactivated and inverted during the Quaternary as well as the presence of a reverse blind fault, which has uplifted the Quaternary deposits of the Los Avestruces bog. The location of the above mentioned shear zones coincides with the northern branch of the NW-trending extensional Triassic Cuyana basin. Thus, their presence appears to be related to Andean reactivation of older (Triassic), mainly NW-trending, structures. In the northern area of the Precordillera Sur, as well as in other places of the world here discussed, these kinds of paleotectonic oblique features play a major role in defining the geometry and kinematics of Late Cenozoic deformation.

  19. Pliocene-Quaternary contourites along the northern Gulf of Cadiz margin: sedimentary stacking pattern and regional distribution

    Science.gov (United States)

    Llave, Estefanía; Matias, Hugo; Hernández-Molina, F. Javier; Ercilla, Gemma; Stow, Dorrik A. V.; Medialdea, Teresa

    2011-12-01

    This study reports novel findings on the Pliocene-Quaternary history of the northern Gulf of Cadiz margin and the spatiotemporal evolution of the associated contourite depositional system. Four major seismic units (P1, P2, QI and QII) were identified in the Pliocene-Quaternary sedimentary record based on multichannel seismic profiles. These are bounded by five major discontinuities which, from older to younger, are the M (Messinian), LPR (lower Pliocene revolution), BQD (base Quaternary discontinuity), MPR (mid-Pleistocene revolution) and the actual seafloor. Unit P1 represents pre-contourite hemipelagic/pelagic deposition along the northern Gulf of Cadiz margin. Unit P2 reflects a significant change in margin sedimentation when contourite deposition started after the Early Pliocene. Mounded elongated and separated drifts were generated during unit QI deposition, accompanied by a general upslope progradation of drifts and the migration of main depocentres towards the north and northwest during both the Pliocene and Quaternary. This progradation became particularly marked during QII deposition after the mid-Pleistocene (MPR). Based on the spatial distribution of the main contourite depocentres and their thickness, three structural zones have been identified: (1) an eastern zone, where NE-SW diapiric ridges have controlled the development of two internal sedimentary basins; (2) a central zone, which shows important direct control by the Guadalquivir Bank in the south and an E-W Miocene palaeorelief structure in the north, both of which have significantly conditioned the basin-infill geometry; and (3) a western zone, affected in the north by the Miocene palaeorelief which favours deposition in the southern part of the basin. Pliocene tectonic activity has been an important factor in controlling slope morphology and, hence, influencing Mediterranean Outflow Water pathways. Since the mid-Pleistocene (MPR), the sedimentary stacking pattern of contourite drifts has been

  20. Synthesis, Crystal and Electronic Structure of the Quaternary Magnetic EuTAl4Si2 (T = Rh and Ir) Compounds

    Energy Technology Data Exchange (ETDEWEB)

    Maurya, Arvind [Tata Institute of Fundamental Research; Thamizhavel, Arumugam [Tata Institute of Fundamental Research; Provino, Alessia [University of Genova; Pani, Marcella [University of Genova; Manfrinetti, Pietro [University of Genova; Paudyal, Durga [Ames Laboratory; Dhar, Sudesh Kumar [Tata Institute of Fundamental Research

    2014-01-22

    Single crystals of the quaternary europium compounds EuRhAl4Si2 and EuIrAl4Si2 were synthesized by using the Al–Si binary eutectic as a flux. The structure of the two quaternary compounds has been refined by single crystal X-ray diffraction. Both compounds are stoichiometric and adopt an ordered derivative of the ternary KCu4S3 structure type (tetragonal tP8, P4/mmm). The two compounds reported here represent the first example of a quaternary and truly stoichiometric 1:1:4:2 phase crystallizing with this structure type. In light of our present results, the structure of the BaMg4Si3 compound given in literature as representing a new prototype is actually isotypic with the KCu4S3 structure. Local spin density approximation including the Hubbard U parameter (LSDA + U) calculations show that Eu ions are in the divalent state, with a significant hybridization between the Eu 5d, Rh (Ir) 4d (5d), Si 3p and Al 3p states. Magnetic susceptibility measured along the [001] direction confirms the divalent nature of the Eu ions in EuRhAl4Si2 and EuIrAl4Si2, which order magnetically near 11 and 15 K, respectively.

  1. LATE QUATERNARY SEISMIC SEQUENCES AND SEDIMENTATION ALONG THE COAST OFF TAISHAN,GUANGDONG,AS REVEALED BY HIGH RESOLUTION SEISMIC DATA

    Institute of Scientific and Technical Information of China (English)

    吴时国; 黄孝健

    2002-01-01

    Seismic stratigraphic analysis of 150 km of high-resolution seismic profiles (G E OPULSE and 3.5 kHz) obtained along the muddy coast off Taishan, Guangdong pr ovided valuable information on the offshore Quaternary stratigraphy, tectonics, sedimentary evol ution, and environmental and engineering geology of this area.The following late Quaternary stratigraphic sequences were mapped. (1) Pleistoce ne alluvial silty sand and shallow marine clay; (2) coarse fluvial channel sand; (3 ) nearshore and bay clayey sediments. The incision of fluvial channels occurred in two stages: duri ng the Late Pleistocene and at the beginning of the Holocene. The Pleistocene fluvial channe ls have been filled by coarse sand overlain by more than 10 m of late Pleistocene clay and 20-30 m o f Holocene clay.The coastal area is dissected by two major fault systems: the first group strike s ENE-WSW and controls the evolution of the adjacent Quaternary basin, while the second one tr ends NNE-SSW. These fault systems must be taken into account in any coastal engineering consid erations. In addition, both granitic and metamorphic basements were recognized.

  2. In situ cosmogenic 10Be dating of the Quaternary glaciations in the southern Shaluli Mountain on the Southeastern Tibetan Plateau

    Institute of Scientific and Technical Information of China (English)

    WANG; Jian; Raisbeck; Grand; XU; Xiaobin; Yiou; Francios; BAI; Shibiao

    2006-01-01

    It is generally considered that four-times ice age happened during the Quaternary epoch on the Tibetan Plateau.However,the research on the chronology of the four-times ice age is far from enough.The Shaluli Mountain on the Southeastern Tibetan Plateau is an ideal place for plaeo-glacier study,because there are abundant Quaternary glacial remains there.This paper discusses the ages of the Quaternary glaciations,based on the exposure dating of roche moutonnée,moraines and glacial erosion surfaces using in situ cosmogenic isotopes 10Be.It is found that the exposure age of the roche moutonnée at Tuershan is 15 ka,corresponding to Stage 2 of the deep-sea oxygen isotope,suggesting that the roche moutonnée at Tuershan is formed in the last glacial maximum.The exposure age of glacial erosion surface at Laolinkou is 130-160 ka,corresponding to Stage 6 of the deep-sea oxygen isotope.The oldest end moraine at Kuzhaori may form at 421-766 kaBP,corresponding to Stages 12-18 of the deep-sea oxygen isotope.In accordance with the climate characteristic of stages 12,14,16 and 18 reflected by the deep-sea oxygen isotope,polar ice cores and loess sequence,the oldest end moraine at Kuzhaori may form at stage 12 or stage 16,the latter is more possible.

  3. An evaluation of deep thin coal seams and water-beating/resisting layers in the quaternary system using seismic inversion

    Institute of Scientific and Technical Information of China (English)

    XU Yong-zhong; HUANG Wei-chuan; CHEN Tong-jun; CUI Ruo-fei; CHEN Shi-zhong

    2009-01-01

    Non-liner wave equation inversion, wavelet analysis and artificial neural networks were used to obtain stratum parame-ters and the distribution of thin coal seams. The lithology of the water-bearing/resisting layer in the Quaternary system was also predicted. The implementation process included calculating the well log parameters, stratum contrasting the seismic data and the well logs, and extracting, studying and predicting seismic attributes. Seismic inversion parameters, including the layer velocity and wave impedance, were calculated and effectively used for prediction and analysis. Prior knowledge and seismic interpretation were used to remedy a dearth of seismic data during the inversion procedure. This enhanced the stability of the inversion method. Non-linear seismic inversion and artificial neural networks were used to interpret coal seismic lithology and to study the wa-ter-bearing/resisting layer in the Quaternary system. Interpretation of the 1-2 m thin coal seams, and also of the wa-ter-bearing/resisting layer in the Quaternary system, is provided. The upper mining limit can be lifted from 60 m to 45 m. The pre-dictions show that this method can provide reliable data useful for thin coal seam exploitation and for lifting the upper mining limit, which is one of the principles of green mining.

  4. Electronic structure, magnetism and robust half-metallicity of new quaternary Heusler alloy FeCrMnSb

    Energy Technology Data Exchange (ETDEWEB)

    Singh, Mukhtiyar [Department of Physics, Kurukshetra University, Kurukshetra 136 119, Haryana (India); Saini, Hardev S. [Department of Physics, National Institute of Technology, Kurukshetra 136 119, Haryana (India); Thakur, Jyoti [Department of Physics, Kurukshetra University, Kurukshetra 136 119, Haryana (India); Reshak, Ali H. [Institute of Complex Systems, FFPW, CENAKVA, University of South Bohemia in CB, Nove Hrady 37333 (Czech Republic); Center of Excellence Geopolymer and Green Technology, School of Material Engineering, University Malaysia Perlis, 01007 Kangar, Perlis (Malaysia); Kashyap, Manish K., E-mail: manishdft@gmail.com [Department of Physics, Kurukshetra University, Kurukshetra 136 119, Haryana (India)

    2013-12-15

    Highlights: •A new quaternary Heusler alloy FeCrMnSb is identified with robust half metallicity. •The stability of FeCrMnSb has been examined using elastic constants. •Effect of uniform and tetragonal strains on half metallicity has been studied. -- Abstract: A new quaternary Heusler alloy FeCrMnSb is identified by employing ab initio electronic structure calculations. It is stable in Y-structure which is also verified by various conditions governed by elastic constants c{sub ij}. It is a true half-metallic (HM) ferromagnet with integer magnetic moment of 2.00 μ{sub B} per formula unit. The values of minority band gap and HM gap are found to be 0.65 eV and 0.1 eV, respectively. The HM character of FeCrMnSb sustains for −6% to 9% of uniform strain and −9% to 12% of tetragonal strain. This new quaternary Heusler alloy can be proved as an ideal candidate for spin valves and magnetic tunnel junction applications (MTJs)

  5. Nano-sized quaternary CuGa2In3S8 as an efficient photocatalyst for solar hydrogen production

    KAUST Repository

    Kandiel, Tarek

    2014-09-03

    The synthesis of quaternary metal sulfide (QMS) nanocrystals is challenging because of the difficulty to control their stoichiometry and phase structure. Herein, quaternary CuGa2In3S8 photocatalysts with a primary particle size of ≈4nm are synthesized using a facile hot-injection method by fine-tuning the sulfur source injection temperature and aging time. Characterization of the samples reveals that quaternary CuGa2In3S8 nanocrystals exhibit n-type semiconductor characteristics with a transition band gap of ≈1.8eV. Their flatband potential is located at -0.56V versus the standard hydrogen electrode at pH6.0 and is shifted cathodically by 0.75V in solutions with pH values greater than 12.0. Under optimized conditions, the 1.0wt% Ru-loaded CuGa2In3S8 photocatalyst exhibits a photocatalytic H2 evolution response up to 700nm and an apparent quantum efficiency of (6.9±0.5)% at 560nm. These results indicate clearly that QMS nanocrystals have great potential as nano-photocatalysts for solar H2 production. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  6. Theoretical prediction of structural, electronic and optical properties of quaternary alloy Zn1-xBexSySe1-y

    Institute of Scientific and Technical Information of China (English)

    Hacini K; Meradji H; Ghemid S; El Haj Hassan F

    2012-01-01

    Within density functional theory based on the full potential-linearized augmented plane wave method,we carry out the first-principles calculation of the structural,electronic,and optical properties of the zinc blende quaternary alloy Zn1-xBexSySe1-y.The Perdew-Burke-Ernzerhof generalized gradient approximation based on the optimization of total energy and the Engel-Vosko generalized gradient approximation based on the optimization of the corresponding potential are used.Our investigation on the effect of the composition on lattice constants,bulk modulus,band gap,optical dielectric constant,and refractive index shows a non-linear dependence.The energy gap Eg(x,y) has been determined over the entire compositions x and y.In addition,the energy band gap of the technologically important quaternary alloy Zn1-xBexSySe1-y in conditions of being lattice matched to ZnS substrate has been investigated.It is noteworthy that the present work is the first theoretical study of the quaternary alloy of interest.

  7. Quaternary chronostratigraphy and stable isotope paleoecology of Big Bone Lick, Kentucky, USA

    Science.gov (United States)

    Tankersley, Kenneth Barnett; Murari, Madhav Krishna; Crowley, Brooke E.; Owen, Lewis A.; Storrs, Glenn W.; Mortensen, Litsa

    2015-05-01

    Big Bone Lick (BBL) in northern Kentucky, USA has been a critical geologic site in the historical development of North American Quaternary vertebrate paleontology since the 1700s. Sedimentology, geoarcheology, paleontology, accelerator mass spectrometry radiocarbon and optically stimulated luminescence dating, and stable carbon and nitrogen isotope analyses were undertaken to develop a chronostratigraphy and history of erosion and deposition for the site to provide a foundation for understanding taphonomy, and species extinction and adaptation to periods of climatic and environmental change. Three geomorphic surfaces are recognized at BBL representing significant periods of floodplain aggradation since the last glacial maximum (26.5-19 ka) dating to the Oldest Dryas (Tazewell, 25-19 ka), the Older Dryas (Cary, 14-12 ka), and late Holocene (5 ka to the present). Unconformities suggest significant periods of degradation during the transitions from cold and dry to warm and moist climates from the Oldest Dryas (Tazewell) to Bølling Oscillation, from the Older Dryas (Cary) to the Allerød, and from the Younger Dryas (Valders) to the Holocene Climatic Optimum. Increased anthropogenic activities since 5 ka may have increased soil upland erosion and floodplain aggradation. Stable isotopes demonstrate that the landscape has been dominated by C3 vegetation since the last glacial maximum.

  8. A Mid-Late Quaternary loess-paleosol record in Simmons Farm in southern Illinois, USA

    Science.gov (United States)

    Wang, Hongfang; Lundstrom, C.C.; Zhang, Z.; Grimley, D.A.; Balsam, W.L.

    2009-01-01

    In unglaciated areas of the Mississippi Valley region, the typical full loess-paleosol succession contains the Modern Soil developed in Peoria Silt, weakly developed Farmdale Geosol developed in Roxana Silt, Sangamon Geosol developed in Loveland Silt, and Yarmouth Geosol developed in Crowley's Ridge Silt. Although a fifth loess called the Marianna Silt is reported at one area, the paleosol that separates the Crowley Ridge and Marianna Silts is not well defined. Previous thermoluminescence (TL) and optical stimulated luminescence (OSL) age chronology has suggested multiple phases of Sangamon Geosol developed in Loveland Silt, but clear morphological evidence of polygenetic Sangamon Geosol profiles have not been found. Recently, a thick loess-paleosol sequence has been studied in the middle Mississippi Valley in unglaciated southern Illinois, USA. Soil morphology and analytical results revealed five loesses and associated paleosol units. Two Sangamon Bt horizons were found separated by a thick ACtk horizon, interpreted to indicate two phases of Sangamon Geosol development. This well-preserved loess-paleosol succession provides one of the most complete mid-late Quaternary loess records in the middle Mississippi Valley to date, and is important for studying the stratigraphic framework and paleoclimate and environment changes. ?? 2008 Elsevier Ltd. All rights reserved.

  9. Late Quaternary Tephrostratigraphy of South-Central Chile (~ 38 - 40 °S)

    Science.gov (United States)

    Fontijn, K.; Rawson, H. L.; Van Daele, M. E.; Moernaut, J.; Abarzúa, A. M.; Pyle, D. M.; Mather, T. A.; De Batist, M. A. O.; Moreno-Roa, H.; Naranjo, J. A.

    2014-12-01

    The volcanoes of the Siete Lagos region ("Lake District") in South-Central Chile form part of the Southern Volcanic Zone of the Andes and include some of the most active volcanoes in South America, i.e. Villarrica and Llaima. The Late Quaternary (~ last 15 ka) regional tephrostratigraphic record for this region is however still poorly developed. We combine detailed stratigraphic logging of terrestrial sections in the vicinity of Llaima, Sollipulli, Villarrica, Quetrupillan, Mocho-Choshuenco and Puyehue-Cordón Caulle volcanoes with petrological, whole-rock and glass geochemical data, and 14C dating on charcoal entrained in volcanic deposits, and correlate the on-land sequences with tephra layers in existing 14C-dated lacustrine records of Laguna Las Ranas and Lagos Villarrica, Calafquén and Riñihue. The combined record includes previously described major eruptions, e.g. Llaima Pumice (Llaima) and Alpehue Pumice (Sollipulli), which help to constrain the relative timing of events. These correlations suggest that several widespread volcanic units are several hundreds to thousands of years older than previously thought. The record also includes newly described pumice-producing events, e.g. for the poorly studied Quetrupillan volcano, and provides new insights into the post-glacial eruptive frequency in the Southern Volcanic Zone. The newly updated stratigraphy with high-quality geochemical data also contributes to the regional tephrochronological framework which helps to significantly improve age models for lacustrine palaeoseismological and palaeoenvironmental archives.

  10. Shift in detrital sedimentation in the eastern Bay of Bengal during the late Quaternary

    Indian Academy of Sciences (India)

    C Prakash Babu; J N Pattan; K Dutta; N Basavaiah; G V Ravi Prasad; D K Ray; P Govil

    2010-06-01

    Down-core variations of granulometric, geochemical and mineral magnetism of a 70-cm long sediment core retrieved from the eastern Bay of Bengal abyssal region were studied to understand sedimentation pattern and sediment provenance during the last ∼12 kyr BP. Based on down-core physical and elemental variations, three units were identified: unit 3 (70–43 cm) is a ∼30 cm thick clayey silt organic carbon-rich (0.5–0.92%) turbidite probably delivered by the Brahmaputra River during the late Quaternary period. Units 2 (43–24 cm) and 1 (24–0 cm) represent enhanced and reduced supply of coarse-grained detrital sediments from the Ganges River during early and late Holocene period, respectively. Increased terrigenous supply dilutes calcium carbonate (CaCO3) and biogenic elements (P, Ba and Cu) in units 3 and 2. On the contrary, a reduction in detrital input enhances CaCO3 and biogenic elements in unit 1. Lithogenic elements (Ti, Al, K and Rb) and shale-normalized REE patterns in all three units suggest terrigenous source. The shift in provenance from the Brahmaputra to the Ganges derived sediments is evident by a sharp increase in sediment grain size, increased concentration and grain size assemblages of magnetic minerals, lithogenic elements concentration and Lan/Ybn ratio. This study highlights terrigenous dilution on biogenic sedimentation in the eastern Bay of Bengal sediments.

  11. Novel Amino-Pyridine Functionalized Chitosan Quaternary Ammonium Derivatives: Design, Synthesis, and Antioxidant Activity

    Directory of Open Access Journals (Sweden)

    Qing Li

    2017-01-01

    Full Text Available Chemical modification of chitosan is increasingly studied for its potential of providing new applications of chitosan. Here, a group of novel chitosan quaternary ammonium derivatives containing pyridine or amino-pyridine were designed and successfully synthesized through chemical modification of chitosan. Pyridine and amino-pyridine were used as functional groups to improve the antifungal activity of chitosan derivatives. The chitosan derivatives’ antioxidant activity against hydroxyl-radical and 1,1-Diphenyl-2-picrylhydrazyl (DPPH-radical was tested in vitro. The results showed that chitosan derivatives had better water solubility and stronger antioxidant activity compared with chitosan in all assays. Especially, compounds 3C and 3E (with 3-amino pyridine and 2,3-diamino pyridine as substitute respectively exhibited stronger hydroxyl-radical and DPPH-radical scavenging ability than other synthesized compounds. These data demonstrated that the synergistic effect of the amino group and pyridine would improve the antioxidant activity of chitosan derivatives, and the position of the amino group on pyridine could influence the antioxidant property of chitosan derivatives.

  12. Plasma-enhanced synthesis of bactericidal quaternary ammonium thin layers on stainless steel and cellulose surfaces.

    Science.gov (United States)

    Jampala, Soujanya N; Sarmadi, M; Somers, E B; Wong, A C L; Denes, F S

    2008-08-19

    We have investigated bottom-up chemical synthesis of quaternary ammonium (QA) groups exhibiting antibacterial properties on stainless steel (SS) and filter paper surfaces via nonequilibrium, low-pressure plasma-enhanced functionalization. Ethylenediamine (ED) plasma under suitable conditions generated films rich in secondary and tertiary amines. These functional structures were covalently attached to the SS surface by treating SS with O 2 and hexamethyldisiloxane plasma prior to ED plasma treatment. QA structures were formed by reaction of the plasma-deposited amines with hexyl bromide and subsequently with methyl iodide. Structural compositions were examined by electron spectroscopy for chemical analysis and Fourier transform infrared spectroscopy, and surface topography was investigated with atomic force microscopy and water contact angle measurements. Modified SS surfaces exhibited greater than a 99.9% decrease in Staphylococcus aureus counts and 98% in the case of Klebsiella pneumoniae. The porous filter paper surfaces with immobilized QA groups inactivated 98.7% and 96.8% of S. aureus and K. pneumoniae, respectively. This technique will open up a novel way for the synthesis of stable and very efficient bactericidal surfaces with potential applications in development of advanced medical devices and implants with antimicrobial surfaces.

  13. Inhibition of biofouling by modification of forward osmosis membrane using quaternary ammonium cation.

    Science.gov (United States)

    Park, Kang-Hee; Yu, Sang-Hyun; Kim, Han-Shin; Park, Hee-Deung

    2015-01-01

    In the operation of the forward osmosis (FO) process, biofouling of the membrane is a potentially serious problem. Development of an FO membrane with antibacterial properties could contribute to a reduction in biofouling. In this study, quaternary ammonium cation (QAC), a widely used biocidal material, was conjugated with a silane coupling agent (3-(trimethoxysilyl)-propyldimethyloctadecyl ammonium chloride) and used to modify an FO membrane to confer antibacterial properties. Fourier transform infrared spectroscopy (FT-IR) demonstrated that the conjugated QAC was successfully immobilized on the FO membrane via covalent bonding. Bacterial viability on the QAC-modified membrane was confirmed via colony count method and visualized via bacterial viability assay. The QAC membrane decreased the viability of Escherichia coli to 62% and Staphylococcus aureus to 77% versus the control membrane. Inhibition of biofilm formation on the QAC modified membrane was confirmed via anti-biofilm tests using the drip-flow reactor and FO unit, resulting in 64% and 68% inhibition in the QAC-modified membrane against the control membrane, respectively. The results demonstrate the effectiveness of the modified membrane in reducing bacterial viability and inhibiting biofilm formation, indicating the potential of QAC-modified membranes to decrease operation costs incurred by biofouling.

  14. Alkaline stability of quaternary ammonium cations for alkaline fuel cell membranes and ionic liquids.

    Science.gov (United States)

    Marino, M G; Kreuer, K D

    2015-02-01

    The alkaline stability of 26 different quaternary ammonium groups (QA) is investigated for temperatures up to 160 °C and NaOH concentrations up to 10 mol L(-1) with the aim to provide a basis for the selection of functional groups for hydroxide exchange membranes in alkaline fuel cells and of ionic-liquid cations stable in basic conditions. Most QAs exhibit unexpectedly high alkaline stability with the exception of aromatic cations. β-Protons are found to be far less susceptible to nucleophilic attack than previously suggested, whereas the presence of benzyl groups, nearby hetero-atoms, or other electron-withdrawing species promote degradation reactions significantly. Cyclic QAs proved to be exceptionally stable, with the piperidine-based 6-azonia-spiro[5.5]undecane featuring the highest half-life at the chosen conditions. Absolute and relative stabilities presented herein stand in contrast to literature data, the differences being ascribed to solvent effects on degradation.

  15. Predicting a quaternary tungsten oxide for sustainable photovoltaic application by density functional theory

    Energy Technology Data Exchange (ETDEWEB)

    Sarker, Pranab; Huda, Muhammad N., E-mail: huda@uta.edu [Department of Physics, University of Texas at Arlington, Arlington, Texas 76019 (United States); Al-Jassim, Mowafak M. [National Renewable Energy Laboratory, Golden, Colorado 80401 (United States)

    2015-12-07

    A quaternary oxide, CuSnW{sub 2}O{sub 8} (CTTO), has been predicted by density functional theory (DFT) to be a suitable material for sustainable photovoltaic applications. CTTO possesses band gaps of 1.25 eV (indirect) and 1.37 eV (direct), which were evaluated using the hybrid functional (HSE06) as a post-DFT method. The hole mobility of CTTO was higher than that of silicon. Further, optical absorption calculations demonstrate that CTTO is a better absorber of sunlight than Cu{sub 2}ZnSnS{sub 4} and CuIn{sub x}Ga{sub 1−x}Se{sub 2} (x = 0.5). In addition, CTTO exhibits rigorous thermodynamic stability comparable to WO{sub 3}, as investigated by different thermodynamic approaches such as bonding cohesion, fragmentation tendency, and chemical potential analysis. Chemical potential analysis further revealed that CTTO can be synthesized at flexible experimental growth conditions, although the co-existence of at least one secondary phase is likely. Finally, like other Cu-based compounds, the formation of Cu vacancies is highly probable, even at Cu-rich growth condition, which could introduce p-type activity in CTTO.

  16. Sinorhizobium meliloti chemotaxis to quaternary ammonium compounds is mediated by the chemoreceptor McpX.

    Science.gov (United States)

    Webb, Benjamin A; Karl Compton, K; Castañeda Saldaña, Rafael; Arapov, Timofey D; Keith Ray, W; Helm, Richard F; Scharf, Birgit E

    2017-01-01

    The bacterium Sinorhizobium meliloti is attracted to seed exudates of its host plant alfalfa (Medicago sativa). Since quaternary ammonium compounds (QACs) are exuded by germinating seeds, we assayed chemotaxis of S. meliloti towards betonicine, choline, glycine betaine, stachydrine and trigonelline. The wild type displayed a positive response to all QACs. Using LC-MS, we determined that each germinating alfalfa seed exuded QACs in the nanogram range. Compared to the closely related nonhost species, spotted medic (Medicago arabica), unique profiles were released. Further assessments of single chemoreceptor deletion strains revealed that an mcpX deletion strain displayed little to no response to these compounds. Differential scanning fluorimetry showed interaction of the isolated periplasmic region of McpX (McpX(PR) and McpX34-306 ) with QACs. Isothermal titration calorimetry experiments revealed tight binding to McpX(PR) with dissociation constants (Kd ) in the nanomolar range for choline and glycine betaine, micromolar Kd for stachydrine and trigonelline and a Kd in the millimolar range for betonicine. Our discovery of S. meliloti chemotaxis to plant-derived QACs adds another role to this group of compounds, which are known to serve as nutrient sources, osmoprotectants and cell-to-cell signalling molecules. This is the first report of a chemoreceptor that mediates QACs taxis through direct binding.

  17. Payenia Quaternary flood basalts (southern Mendoza, Argentina: Geophysical constraints on their volume

    Directory of Open Access Journals (Sweden)

    Mauro G. Spagnuolo

    2016-09-01

    Full Text Available The Quaternary volcanic province of Payenia is located in southern Mendoza and northern Neuquén provinces of Argentina and is characterized by a dominant basaltic composition. The volcanic province covers an area larger than 40,000 km2 and its origin and evolution has been the center of several studies. In this study we analyzed gravity data together with more accurate volcanic volumes calculations in order to investigate the subsurface structure of the Payenia volcanic province. The volume of material was calculated using digital elevation models and geographic information system (GIS techniques to estimate the volume of material erupted and then, with those values, make an estimation of the intrusive material that could be located within the crust. The results of the calculations were compared with different 2D-sections constructed to model the gravity data and compare with the observed satellite gravity. After evaluating different models which have been generated to match both: the observed gravity data and the subsurface material calculated, we discuss those that best fit with observation. The results clearly indicate that the lithosphere is attenuated below the region.

  18. Payenia Quaternary flood basalts (southern Mendoza, Argentina):Geophysical constraints on their volume

    Institute of Scientific and Technical Information of China (English)

    Mauro G. Spagnuolo; Darío L. Orts; Mario Gimenez; Andres Folguera; Victor A. Ramos

    2016-01-01

    The Quaternary volcanic province of Payenia is located in southern Mendoza and northern Neuquén provinces of Argentina and is characterized by a dominant basaltic composition. The volcanic province covers an area larger than 40,000 km2 and its origin and evolution has been the center of several studies. In this study we analyzed gravity data together with more accurate volcanic volumes calculations in order to investigate the subsurface structure of the Payenia volcanic province. The volume of material was calculated using digital elevation models and geographic information system (GIS) techniques to estimate the volume of material erupted and then, with those values, make an estimation of the intrusive material that could be located within the crust. The results of the calculations were compared with different 2D-sections constructed to model the gravity data and compare with the observed satellite gravity. After evaluating different models which have been generated to match both: the observed gravity data and the subsurface material calculated, we discuss those that best fit with observation. The results clearly indicate that the lithosphere is attenuated below the region.

  19. Chronostratigraphy of uplifted Quaternary hemipelagic deposits from the Dodecanese island of Rhodes (Greece)

    Science.gov (United States)

    Quillévéré, Frédéric; Cornée, Jean-Jacques; Moissette, Pierre; López-Otálvaro, Gatsby Emperatriz; van Baak, Christiaan; Münch, Philippe; Melinte-Dobrinescu, Mihaela Carmen; Krijgsman, Wout

    2016-07-01

    An integrated magneto-biostratigraphic study, based on calcareous nannofossils and foraminifers, together with the radiometric dating of a volcaniclastic layer found in several outcrops, was carried out on the hemipelagic deposits of the Lindos Bay Formation (LBF) at six localities on the island of Rhodes (Greece). Our highly refined chronostratigraphic framework indicates that the lower and upper lithostratigraphic boundaries of the LBF are diachronous. Associated with the 40Ar/39Ar age determination of 1.85 ± 0.08 Ma for the volcaniclastic layer, our data show that among the investigated outcrops, the Lindos Bay type locality section provides the longest record (1.1 Ma) of the LBF. Hemipelagic deposition occurred continuously from the late Gelasian (∼1.9 Ma) to the late Calabrian (∼0.8 Ma), i.e., from Chrons C2n (Olduvai) to C1r.1r (Matuyama) and from nannofossil Zones CNPL7 to CNPL10. This long record, together with the hemipelagic nature of the deposits, make the Lindos Bay type locality section a unique element in the eastern Mediterranean region, allowing future comparisons with other early Quaternary deep-sea sections available in the central and western Mediterranean regions.

  20. Modern and late Quaternary clay mineral distribution in the area of the SE Mediterranean Sea

    Science.gov (United States)

    Hamann, Yvonne; Ehrmann, Werner; Schmiedl, Gerhard; Kuhnt, Tanja

    2009-05-01

    The present-day clay mineral distribution in the southeastern Levantine Sea and its borderlands reveals a complex pattern of different sources and distribution paths. Smectite dominates the suspended load of the Nile River and of rivers in the Near East. Illite sources are dust-bearing winds from the Sahara and southwestern Europe. Kaolinite is prevalent in rivers of the Sinai, in Egyptian wadis, and in Saharan dust. A high-resolution sediment core from the southeastern Levantine Sea spanning the last 27 ka shows that all these sources contributed during the late Quaternary and that the Nile River played a very important role in the supply of clay. Nile influence was reduced during the glacial period but was higher during the African Humid Period. In contrast to the sharp beginning and end of the African Humid Period recorded in West African records (15 and 5.5 ka), our data show a more transitional pattern and slightly lower Nile River discharge rates not starting until 4 ka. The similarity of the smectite concentrations with fluctuations in sea-surface temperatures of the tropical western Indian Ocean indicates a close relationship between the Indian Ocean climate system and the discharge of the Nile River.

  1. Status of correlation of Quaternary stratigraphic units in the western conterminous United States

    Science.gov (United States)

    Birkeland, P.W.; Crandell, D.R.; Richmond, G.M.

    1971-01-01

    Deposits of Quaternary age from the Rocky Mountains to the Pacific Coast in the western conterminous United States represent a great variety of environments. The deposits include those of continental and alpine glaciers, glacial meltwater streams, nonglacial streams, pluvial lakes, marine environments, eolian environments, and masswasting environments. On two charts we have attempted to correlate representative sequences of deposits of many of these environments, based on published sources and recent unpublished investigations. Evidence for correlation is based mainly on stratigraphic sequence, soil characteristics, the amount of subsequent erosion and interlayered volcanic ash beds identifiable as to source. Chronologic control is based on numerous radiocarbon dates, U-series dates on marine fossils, and K-Ar dates on volcanic rocks. The Bishop volcanic ash bed and one of the Pearlette-like volcanic ash beds appear to represent significant regional key horizons, respectively about 700,000 and 600,000 years old. Rock magnetism is shown to suggest the paleomagnetic polarity at the time of rock deposition. Assigned land-mammal ages of included fossils help to put limits on the age of some units. ?? 1971.

  2. Lithostratigraphy, volcanism, paleomagnetism and palynology of Quaternary lacustrine deposits from Barombi Mbo (West Cameroon): Preliminary results

    Science.gov (United States)

    Maley, J.; Livingstone, D. A.; Giresse, P.; Thouveny, N.; Brenac, P.; Kelts, K.; Kling, G.; Stager, C.; Haag, M.; Fournier, M.; Bandet, Y.; Williamson, D.; Zogning, A.

    1990-08-01

    We present preliminary results from the study of 23.50-m core from Lake Barombi Mbo, representing the last 25,000 years. The lake is in an explosion crater formed during Quaternary time. The very laminated sediment is composed mostly of clay containing 5-10% organic carbon. Each couplet is commonly composed of a basal lamina rich in quartz, plant debris, muscovite and sponge spicules, and of a more clayey upper lamina often with siderite. A perturbed section near the base of the core, before ca. 21,000 yr B.P., could be the result of a violent release of gas, such CO 2, comparable to the recent Nyos gas eruption. The paleomagnetic studies exhibit high-frequency oscillations interpreted as paleosecular variations of the local geomagnetic field. This first record obtained on the African continent can be closely compared to the type record obtained in Western Europe. The pollen results demonstrate the presence of a forest refuge in West Cameroon during the last great arid period, ca. 18,000 yr B.P. When equatorial forest was broken up, elements of montane vegetation spread to the lowlands. These phenomena resulted from a drying and cooling climate.

  3. Geomorphologic evolution and environmental changes in the Shaluli Mountain region during the Quaternary

    Institute of Scientific and Technical Information of China (English)

    ZHOU Shangzhe; XU Liubing; CUI Jianxin; ZHANG Xiaowei; ZHAO Jingdong

    2005-01-01

    Geologic and geomorphologic evidence from the Shaluli Mountain indicates that the planation surface that formed in the Late Tertiary disintegrated during the Late Pliocene-Early Quaternary. At the same time, rift basins appeared on some parts of the planation surface, and began to accumulate fluvial-lacustrine sediment. These are interpreted as being the response of this region to Phase-A of the Qingzang Tectonic Movement. After this, the Shaluli Mountain continued to rise in several pulses. Faulting and incision by some large tributaries of the Jinsha and Yalong Rivers resulted in several rift river valleys and the earliest terraces. Generally, the planation surface in this region had been uplifted to about 3500-3700 m a.s.l. no later than 550-600 ka BP, after the Kunlun-Huanghe Tectonic Movement, and coupled with global glacial climate, and resulted in the earliest glaciation recognized so far in the Hengduan Mountains. At the same time, loess was deposited in the Ganzi area of the northern Shaluli Mountain. During the last glacial period, the Shaluli Mountain approached its present altitude and developed several large ice caps, such as the Daocheng Ice Cap and Xinlong Ice Cap, as well as several huge valley glaciers. These paleoglaciers produced some of the most spectacular glacial topography on the Tibetan Plateau.

  4. Adsorption of Pb(II on Mentha piperita carbon (MTC in single and quaternary systems

    Directory of Open Access Journals (Sweden)

    Rais Ahmad

    2017-02-01

    Full Text Available In the present study mentha treated carbon (MTC has been utilized as a novel adsorbent for the removal of Pb(II in single and quaternary systems from aqueous solution. The effects of various parameters like pH, contact time and ionic strength have been studied. The adsorbent was characterized by FTIR in order to find the functional groups present on the adsorbent. The equilibrium was attained in 180 min. The maximum adsorption of Pb(II was observed at pH 6. The adsorption isotherm studies show that data are fitted well with Freundlich and Temkin isotherms model. The kinetics data show that boundary layer diffusion is the rate controlling step for the adsorption process and it is dominant when Pb(II ion concentration is higher. The adsorption of Pb(II increases with the increase in the ionic strength of the solution. The positive value of ΔH0 indicates the reaction to be endothermic in nature. The activation energy was found to be 20.60 kJ/mol K indicating physiosorption.

  5. Taxonomy of quaternary deep-sea ostracods from the Western North Atlantic ocean

    Science.gov (United States)

    Yasuhara, Moriaki; Okahashi, H.; Cronin, T. M.

    2009-01-01

    Late Quaternary sediments from Ocean Drilling Program (ODP) Hole 1055B, Carolina Slope, western North Atlantic (32??47.041??? N, 76??17.179??? W; 1798m water depth) were examined for deep-sea ostracod taxonomy. A total of 13933 specimens were picked from 207 samples and c. 120 species were identified. Among them, 87 species were included and illustrated in this paper. Twenty-eight new species are described. The new species are: Ambocythere sturgio, Argilloecia abba, Argilloecia caju, Argilloecia keigwini, Argilloecia robinwhatleyi, Aversovalva carolinensis, Bythoceratina willemvandenboldi, Bythocythere eugeneschornikovi, Chejudocythere tenuis, Cytheropteron aielloi, Cytheropteron demenocali, Cytheropteron didieae, Cytheropteron richarddinglei, Cytheropteron fugu, Cytheropteron guerneti, Cytheropteron richardbensoni, Eucytherura hazeli, Eucytherura mayressi, Eucytherura namericana, Eucytherura spinicorona, Posacythere hunti, Paracytherois bondi, Pedicythere atroposopetasi, Pedicythere kennettopetasi, Pedicythere klothopetasi, Pedicythere lachesisopetasi, Ruggieriella mcmanusi and Xestoleberis oppoae. Taxonomic revisions of several common species were made to reduce taxonomic uncertainty in the literature. This study provides a robust taxonomic baseline for application to palaeoceanographical reconstruction and biodiversity analyses in the deep and intermediate-depth environments of the North Atlantic Ocean. ?? The Palaeontological Association, 2009.

  6. The association effect of quaternary ammonium salt on carboxymethyl cellulose and its analytical applications.

    Science.gov (United States)

    Wang, Yanhua; Gao, Chanjuan; Yang, Shengke

    2015-01-01

    Sodium carboxymethyl cellulose (CMC) has been extensively used in petroleum, geology, common household chemicals, food, medicine and other industries, owing to its excellent water-soluble, emulsifying, water retention and film forming properties. It is known as 'industrial monosodium glutamate'. However, the research of the test method on CMC is far behind the research of its actual application value. This study showed that, weak acid or weak basic medium, the carboxyl groups dissociated from CMC, existing as a big negative ion, which can form ion-association complexes with some quaternary ammonium cations through electrostatic and hydrophobic interactions. The absorption spectrum changes and Triton-X100 can increase the sensitivity of the system. The maximum absorption wavelengths are, respectively, about 256 nm for dodecyl trimethyl ammonium bromide (LTAB), 244 nm for tetradecyltrimethyl ammonium bromide (TTAB) and 240 nm for cetyltrimethyl ammonium bromide (CTAB) with CMC. The reactions show very high sensitivities and the maximum molar absorption coefficients are 1.10 × 10(4) L/(mol·cm) for LTAB system, 1.24 × 10(6) L/(mol·cm) for TTAB system and 1.78 × 10(6) L/(mol·cm) for CTAB system. This method is simple and rapid, and can be applied for the spectrophotometric determination of trace CMC in the supernatant of centrifuged drilling mud.

  7. The quaternary structure of the eukaryotic DNA replication proteins Sld7 and Sld3.

    Science.gov (United States)

    Itou, Hiroshi; Shirakihara, Yasuo; Araki, Hiroyuki

    2015-08-01

    The initiation of eukaryotic chromosomal DNA replication requires the formation of an active replicative helicase at the replication origins of chromosomes. Yeast Sld3 and its metazoan counterpart treslin are the hub proteins mediating protein associations critical for formation of the helicase. The Sld7 protein interacts with Sld3, and the complex formed is thought to regulate the function of Sld3. Although Sld7 is a non-essential DNA replication protein that is found in only a limited range of yeasts, its depletion slowed the growth of cells and caused a delay in the S phase. Recently, the Mdm2-binding protein was found to bind to treslin in humans, and its depletion causes defects in cells similar to the depletion of Sld7 in yeast, suggesting their functional relatedness and importance during the initiation step of DNA replication. Here, the crystal structure of Sld7 in complex with Sld3 is presented. Sld7 comprises two structural domains. The N-terminal domain of Sld7 binds to Sld3, and the C-terminal domains connect two Sld7 molecules in an antiparallel manner. The quaternary structure of the Sld3-Sld7 complex shown from the crystal structures appears to be suitable to activate two helicase molecules loaded onto replication origins in a head-to-head manner.

  8. Cycloaddition Reaction of Carbon Dioxide to Epoxides Catalyzed by Polymer-Supported Quaternary Phosphonium Salts

    Directory of Open Access Journals (Sweden)

    Yubing Xiong

    2013-01-01

    Full Text Available Polymer-supported quaternary phosphonium salt (PS-QPS was explored as effective catalyst for the coupling reaction of carbon dioxide with epoxides. The results indicated that cyclic carbonates with high yields (98.6% and excellent selectivity (100% could be prepared at the conditions of 5 MPa CO2, 150°C, and 6 h without the addition of organic solvents or cocatalysts. The effects of various reaction conditions on the catalytic performance were investigated in detail. The catalyst is applicable to a variety of epoxides, producing the corresponding cyclic carbonates in good yields. Furthermore, the catalyst could be recovered easily and reused for five times without loss of catalytic activity obviously. A proposed mechanism for synthesis of cyclic carbonate in the presence of PS-QPS was discussed. The catalyst was characterized by thermogravimetric analysis (TGA, scanning electron microscopy (SEM, and Fourier transform infrared (FT-IR spectrum. It is believed that PS-QPS is of great potential for CO2 fixation applications due to its unusual advantages, such as easy preparation, high activity and selectivity, stability, low cost, and reusability.

  9. The late Quaternary decline and extinction of palms on oceanic Pacific islands

    Science.gov (United States)

    Prebble, M.; Dowe, J. L.

    2008-12-01

    Late Quaternary palaeoecological records of palm decline, extirpation and extinction are explored from the oceanic islands of the Pacific Ocean. Despite the severe reduction of faunal diversity coincidental with human colonisation of these previously uninhabited oceanic islands, relatively few plant extinctions have been recorded. At low taxonomic levels, recent faunal extinctions on oceanic islands are concentrated in larger bodied representatives of certain genera and families. Fossil and historic records of plant extinction show a similar trend with high representation of the palm family, Arecaceae. Late Holocene decline of palm pollen types is demonstrated from most islands where there are palaeoecological records including the Cook Islands, Fiji, French Polynesia, the Hawaiian Islands, the Juan Fernandez Islands and Rapanui. A strong correspondence between human impact and palm decline is measured from palynological proxies including increased concentrations of charcoal particles and pollen from cultivated plants and invasive weeds. Late Holocene extinctions or extirpations are recorded across all five of the Arecaceae subfamilies of the oceanic Pacific islands. These are most common for the genus Pritchardia but also many sedis fossil palm types were recorded representing groups lacking diagnostic morphological characters.

  10. Tropical Rain Forest and Climate Dynamics of the Atlantic Lowland, Southern Brazil, during the Late Quaternary

    Science.gov (United States)

    Behling, Hermann; Negrelle, Raquel R. B.

    2001-11-01

    Palynological analysis of a core from the Atlantic rain forest region in Brazil provides unprecedented insight into late Quaternary vegetational and climate dynamics within this southern tropical lowland. The 576-cm-long sediment core is from a former beach-ridge "valley," located 3 km inland from the Atlantic Ocean. Radio-carbon dates suggest that sediment deposition began prior to 35,000 14C yr B.P. Between ca. 37,500 and ca. 27,500 14C yr B.P. and during the last glacial maximum (LGM; ca. 27,500 to ca. 14,500 14C yr B.P.), the coastal rain forest was replaced by grassland and patches of cold-adapted forest. Tropical trees, such as Alchornea, Moraceae/Urticaceae, and Arecaceae, were almost completely absent during the LGM. Furthermore, their distributions were shifted at least 750 km further north, suggesting a cooling between 3°C and 7°C and a strengthening of Antarctic cold fronts during full-glacial times. A depauperate tropical rain forest developed as part of a successional sequence after ca. 12,300 14C yr B.P. There is no evidence that Araucaria trees occurred in the Atlantic lowland during glacial times. The rain forest was disturbed by marine incursions during the early Holocene period until ca. 6100 14C yr B.P., as indicated by the presence of microforaminifera. A closed Atlantic rain forest then developed at the study site.

  11. Long-term efficient organic photovoltaics based on quaternary bulk heterojunctions

    Science.gov (United States)

    Nam, Minwoo; Cha, Minjeong; Lee, Hyun Hwi; Hur, Kahyun; Lee, Kyu-Tae; Yoo, Jaehong; Han, Il Ki; Kwon, S. Joon; Ko, Doo-Hyun

    2017-01-01

    A major impediment to the commercialization of organic photovoltaics (OPVs) is attaining long-term morphological stability of the bulk heterojunction (BHJ) layer. To secure the stability while pursuing optimized performance, multi-component BHJ-based OPVs have been strategically explored. Here we demonstrate the use of quaternary BHJs (q-BHJs) composed of two conjugated polymer donors and two fullerene acceptors as a novel platform to produce high-efficiency and long-term durable OPVs. A q-BHJ OPV (q-OPV) with an experimentally optimized composition exhibits an enhanced efficiency and extended operational lifetime than does the binary reference OPV. The q-OPV would retain more than 72% of its initial efficiency (for example, 8.42-6.06%) after a 1-year operation at an elevated temperature of 65 °C. This is superior to those of the state-of-the-art BHJ-based OPVs. We attribute the enhanced stability to the significant suppression of domain growth and phase separation between the components via kinetic trapping effect.

  12. Quaternary structural evolution of Terracina and Gaeta basins (Eastern Tyrrhenian margin, Italy)

    Energy Technology Data Exchange (ETDEWEB)

    Aiello, G.; Marsella, E.; Sacchi, M. [Consiglio Nazionale delle Ricerche, Naples (Italy). Ist. di Ricerca Geomare Sud

    2000-07-01

    In the Terracina and Gaeta basins (Italy) quaternary sediments are displaced by normal faults, which affect also Meso-Cenozoic tectonic units of the acoustic basement. The extensional tectonics is characterized by normal faults systems trending NE-SW and E-W. In the Terracina basin, roughly N-S oriented, half-graben structures are down thrown seaward through normal faults; the Gaeta extensional basin, E-W oriented, has two main depo centers and is bounded to the north and to the south by E-W trending normal faults and to the east by a NW-SE trending normal faults. [Italian] I bacini di Terracina e Gaeta mostrano un significativo controllo tettonico sulla sedimentazione quaternaria, causato dalla presenza di faglie normali: esse dislocano le unita' tettoniche meso-cenozoiche che rappresentano il basamento acustico. Sistemi di faglie normali ad andamento NE-SW e E-W determinano nel bacino di Terracina una struttura di tipo semi-graben orientata N-S- e ribassata verso mare da faglie dirette. Il bacino di Gaeta rappresenta un bacino estensionale ad andamento E-W, articolato in due principali depocentri e delimitato verso nord e verso sud da faglie normali ad andamento E-W e verso est da una faglia diretta ad andamento NW-SE.

  13. Shifting sources and transport paths for the late Quaternary Escanaba Trough sediment fill (northeast Pacific)

    Science.gov (United States)

    Zuffa, G.G.; De Rosa, R.; Normark, W.R.

    1997-01-01

    Escanaba Trough, which forms the southernmost part of the axial valley of the actively spreading Gorda Ridge, is filled with several hundred meters of sediment of presumed late Quaternary age. Surficial sediment samples from gravity cores, deeper samples (as much as 390 m) from Site 35 of the Deep Sea Drilling Program (Leg 5), and the acoustic character of the sediment fill observed on seismic-reflection profiles indicate that much of the sediment fill is of turbidite origin. Gross composition and heavy- mineral analyses of sand samples show that two distinct petrofacies comprise the sediment fill. The lower part of the fill was derived primarily from the Klamath River source of northern California while the younger fill, including the surficial sand beds, are from the Columbia River drainage much farther north. The Escanaba Trough sediment provides an opportunity to evaluate concepts for paleogeographic and paleotectonic reconstructions that are based on facies analysis and compositional and textural data for the volcanic components because both intrabasinal and extrabasinal sources are present as well as coeval (neovolcanic) and non coeval (paleovolcanic) sourcre This study of a modern basin shows, that although the sediment sources could be identified, it was useful to have some knowledge of the sediment pathway(s), the effects of diagenesis, and the possible effects of sediment sorting as a result of long transport distances from the source area for some components. Application of these same techniques to ancient deposits without benefit of the additional parameters will face limitations.

  14. Computation of Galois field expressions for quaternary logic functions on GPUs

    Directory of Open Access Journals (Sweden)

    Gajić Dušan B.

    2014-01-01

    Full Text Available Galois field (GF expressions are polynomials used as representations of multiple-valued logic (MVL functions. For this purpose, MVL functions are considered as functions defined over a finite (Galois field of order p - GF(p. The problem of computing these functional expressions has an important role in areas such as digital signal processing and logic design. Time needed for computing GF-expressions increases exponentially with the number of variables in MVL functions and, as a result, it often represents a limiting factor in applications. This paper proposes a method for an accelerated computation of GF(4-expressions for quaternary (four-valued logic functions using graphics processing units (GPUs. The method is based on the spectral interpretation of GF-expressions, permitting the use of fast Fourier transform (FFT-like algorithms for their computation. These algorithms are then adapted for highly parallel processing on GPUs. The performance of the proposed solutions is compared with referent C/C++ implementations of the same algorithms processed on central processing units (CPUs. Experimental results confirm that the presented approach leads to significant reduction in processing times (up to 10.86 times when compared to CPU processing. Therefore, the proposed approach widens the set of problem instances which can be efficiently handled in practice. [Projekat Ministarstva nauke Republike Srbije, br. ON174026 i br. III44006

  15. Sputtered tungsten-based ternary and quaternary layers for nanocrystalline diamond deposition.

    Science.gov (United States)

    Walock, Michael J; Rahil, Issam; Zou, Yujiao; Imhoff, Luc; Catledge, Shane A; Nouveau, Corinne; Stanishevsky, Andrei V

    2012-06-01

    Many of today's demanding applications require thin-film coatings with high hardness, toughness, and thermal stability. In many cases, coating thickness in the range 2-20 microm and low surface roughness are required. Diamond films meet many of the stated requirements, but their crystalline nature leads to a high surface roughness. Nanocrystalline diamond offers a smoother surface, but significant surface modification of the substrate is necessary for successful nanocrystalline diamond deposition and adhesion. A hybrid hard and tough material may be required for either the desired applications, or as a basis for nanocrystalline diamond film growth. One possibility is a composite system based on carbides or nitrides. Many binary carbides and nitrides offer one or more mentioned properties. By combining these binary compounds in a ternary or quaternary nanocrystalline system, we can tailor the material for a desired combination of properties. Here, we describe the results on the structural and mechanical properties of the coating systems composed of tungsten-chromium-carbide and/or nitride. These WC-Cr-(N) coatings are deposited using magnetron sputtering. The growth of adherent nanocrystalline diamond films by microwave plasma chemical vapor deposition has been demonstrated on these coatings. The WC-Cr-(N) and WC-Cr-(N)-NCD coatings are characterized with atomic force microscopy and SEM, X-ray diffraction, X-ray photoelectron spectroscopy, Raman spectroscopy, and nanoindentation.

  16. The structural, electronic and magnetic properties of quaternary Heusler alloy TiZrCoIn

    Science.gov (United States)

    Yan, Peng-Li; Zhang, Jian-Min; Xu, Ke-Wei

    2016-04-01

    Employing the first-principles calculations, we have investigated the structural, electronic and magnetic properties of quaternary Heusler alloy TiZrCoIn. The TiZrCoIn alloy with type (I) configuration is predicted to be half-metallic ferromagnet at its equilibrium lattice constant 6.525 Å with an indirect band gap of 0.930 eV in minority spin channel. The total magnetic moment is 2 μB/f.u., following the Slater-Pauling rule μt=Zt-18. Moreover, the negative formation energy indicates the thermodynamical stability of this alloy. The band gap of minority spin channel is determined by the bonding (t2g) and antibonding (t1u) states created from the hybridizations of the d states of transition metal atoms Ti, Zr and Co. In addition, the HM, character is kept as hydrostatic strain ranged from -10% to 7.6% and tetragonal strain ranged from -19% to 27%.

  17. Neuraminidase inhibitory activities of quaternary isoquinoline alkaloids from Corydalis turtschaninovii rhizome.

    Science.gov (United States)

    Kim, Jang Hoon; Ryu, Young Bae; Lee, Woo Song; Kim, Young Ho

    2014-11-01

    Clostridium perfringens is a Gram-positive spore-forming bacterium that causes food poisoning. The neuraminidase (NA) protein of C. perfringens plays a pivotal role in bacterial proliferation and is considered a novel antibacterial drug target. Based on screens for novel NA inhibitors, a 95% EtOH extract of Corydalis turtschaninovii rhizome showed NA inhibitory activity (68% at 30 μg/ml), which resulted in the isolation of 10 isoquinoline alkaloids; namely, palmatine (1), berberine (2), coptisine (3), pseudodehydrocorydaline (4), jatrorrhizine (5), dehydrocorybulbine (6), pseudocoptisine (7), glaucine (8), corydaline (9) and tetrahydrocoptisine (10). Interestingly, seven quaternary isoquinoline alkaloids 1-7 (IC50 = 12.8 ± 1.5 to 65.2 ± 4.5 μM) showed stronger NA inhibitory activity than the tertiary alkaloids 8-10. In addition, highly active compounds 1 and 2 showed reversible non-competitive behavior based on a kinetic study. Molecular docking simulations using the Autodock 4.2 software increased our understanding of receptor-ligand binding of these compounds. In addition, we demonstrated that compounds 1 and 2 suppressed bacterial growth.

  18. A mild solvothermal route to kesterite quaternary Cu2ZnSnS4 nanoparticles

    Science.gov (United States)

    Cao, M.; Shen, Y.

    2011-03-01

    Quaternary kesterite-type Cu2ZnSnS4 (CZTS) nanoparticles for low-cost thin film solar cell were successfully synthesised using a relatively simple and convenient solvothermal route. Nanoparticles with diameters of about 5-10 nm were obtained at the temperature of 180 °C, analyzed by transmission electron microscopy (TEM). The morphologies of the continuous CZTS films with satisfactory stoichiometry were characterized by scanning electron microscopy (SEM) and energy dispersive X-ray analysis (EDXA). The crystallinity of CZTS nanoparticles was greatly improved by annealing in H2S (5%)/Ar mixed gases analyzed by X-ray diffraction (XRD). High-resolution X-ray photo-emission spectroscopy (XPS) analysis of the four constituent elements confirmed the purity and composition of CZTS nanoparticles. UV-vis absorption spectra measurement indicated that the band gap of as-synthesised CZTS nanoparticles was about 1.5 eV, which was near the optimum value for photovoltaic solar conversion in a single-band-gap device.

  19. Late Quaternary tectonic landforms and fluvial aggradation in the Saryu River valley: Central Kumaun Himalaya

    Science.gov (United States)

    Kothyari, Girish Ch.; Luirei, Khayingshing

    2016-09-01

    The present study has been carried out with special emphasis on the aggradational landforms to explain the spatial and temporal variability in phases of aggradation/incision in response to tectonic activity during the late Quaternary in the Saryu River valley in central Kumaun Himalaya. The valley has preserved cut-and-fill terraces with thick alluvial cover, debris flow terraces, and bedrock strath terraces that provide signatures of tectonic activity and climate. Morphostratigraphy of the terraces reveals that the oldest landforms preserved south of the Main Central Thrust, the fluvial modified debris flow terraces, were developed between 30 and 45 ka. The major phase of valley fill is dated between 14 and 22 ka. The youngest phase of aggradation is dated at early and mid-Holocene (9-3 ka). Following this, several phases of accelerated incision/erosion owing to an increase in uplift rate occurred, as evident from the strath terraces. Seven major phases of bedrock incision/uplift have been estimated during 44 ka (3.34 mm/year), 35 ka (1.84 mm/year), 15 ka (0.91 mm/year), 14 ka (0.83 mm/year), 9 ka (1.75 mm/year), 7 ka (5.38 mm/year), and around 3 ka (4.4 mm/year) from the strath terraces near major thrusts. We postulate that between 9 and 3 ka the terrain witnessed relatively enhanced surface uplift (2-5 mm/year).

  20. Transition of Quaternary glacial cyclicity in deep-sea records at Nansha, the South China Sea

    Institute of Scientific and Technical Information of China (English)

    WANG; Pinxian

    2001-01-01

    [1]Shackleton. N. J., Opdyke, N. D., Oxygen isotope and paleomagnetic stratigraphy of Pacific core V28-239: Late Plio cene to Latest Pleistocene, Mem. Geol. Soc. Am., 1976, 145: 449-464.[2]Ding, Z., Liu, D., New Development of China Loess Research (1) Loess Stratigraphy, Quaternary Research (in Chinese),1989, 1: 24-35.[3]Raymo, M. E., Oppo, D. W., Curry. W., The mid-Pleistocene climate transition: A deep sea carbon isotopic perspective,Paleoceanography, 1997, 12(4): 546-559.[4]PrellW. L., Oxygen and carbon isotope stratigraphy for the Quaternary of Hole 502B: Evidence for two modes of isotopic variability, in Init. Repts. DSDP (eds. Prell and W. L., Gardner, J. V.), 1982, 68: 455-464.[5]Shackleton. N. J., The 100,000-year ice-age cycle identified and found to lag temperature, carbon dioxide, and orbital eccentricity, Science, 2000, 289: 1897-1902.[6]Rutherford, S., D'Hondt, S., Early onset and tropical forcing of 100,000-year Pleistocene glacial cycles, Nature, 2000, 408:72-75.[7]Berger, W. H., Bickert, T., Jansen, E. et al., The central mystery of the Quaternary Ice Age, Oceanus, 1993, 36(4): 53-56.[8]Raymo, M. E., The timing of major climate terminations, Paleoceanography, 1997, 12(4): 577-585.[9]Berger, W. H., Jansen, E., Mid-Pleistocene climate shift: The Nansen connection, Geophysical Monograph, 1994, 84:295-311.[10]Clark, P. C., Pollanrd, D., Origin of the middle Pleistocene transition by ice sheet erosion of regolith, Paleoceanography,1998, 13: 1-19.[11]Wang, P., Prell, W., Blum, P. et al. Initial Reports 184, Ocean Drilling Program in Proceedings of the ODP [CD-ROM].Texas: Texas A&M University, College Station, 2000, 1-103.[12]Zhao, Q., Jian, Z., Liang, J. et al., Neogene Oxygen Isotopic Stratigraphy, ODP Site 1148, northern South China Sea, Sci ence in China, Ser. D,2001, 44(10): 934-942.[13]Zhao, Q., Jian, Z., Li, B. et al., Microtektites in the Middle Pleistocene deep-sea sediments of the South China

  1. Late Quaternary dietary shifts of the Cape grysbok ( Raphicerus melanotis) in southern Africa

    Science.gov (United States)

    Faith, J. Tyler

    2011-01-01

    The Cape grysbok is endemic to southern Africa's Cape Floral Region where it selectively browses various species of dicotyledonous vegetation. Fossil evidence indicates that the grysbok persisted under glacial and interglacial conditions throughout the late Quaternary and inhabited a range of environments. This study employs mesowear analysis to reconstruct grysbok diets over time and in response to changing environments at Nelson Bay Cave, Die Kelders Cave 1, Klasies River Mouth, and Swartklip 1. Results indicate that the amount of grasses (monocots) versus leafy vegetation (dicots) included in the diet fluctuated over time and largely in agreement with changes in faunal community structure. The case for dietary flexibility is particularly clear at Nelson Bay Cave, where there is a significant trend from mixed feeding towards increased browsing from the late Pleistocene (~ 18,500 14C yr BP) through the Holocene. Dietary shifts at Nelson Bay Cave are consistent with the hypothesis that declining grassland productivity is responsible for the terminal Pleistocene extinction of several large ungulates in southern Africa. Furthermore, the short-term dietary shifts demonstrated here (100s to 1000s of years) provide an important caution against relying on taxonomic uniformitarianism when reconstructing the dietary preferences of fossil ungulates, both extant and extinct.

  2. Multifunctional properties related to magnetostructural transitions in ternary and quaternary Heusler alloys

    Energy Technology Data Exchange (ETDEWEB)

    Dubenko, Igor, E-mail: igor_doubenko@yahoo.com [Department of Physics, Southern Illinois University, Carbondale, IL 62901 (United States); Quetz, Abdiel; Pandey, Sudip; Aryal, Anil; Eubank, Michael [Department of Physics, Southern Illinois University, Carbondale, IL 62901 (United States); Rodionov, Igor; Prudnikov, Valerii; Granovsky, Alexander [Faculty of Physics, Moscow State University, Vorob' evy Gory, 11999I Moscow (Russian Federation); Lahderanta, Erkki [Lappeenranta University of Technology, 53851 (Finland); Samanta, Tapas; Saleheen, Ahmad; Stadler, Shane [Department of Physics & Astronomy, Louisiana State University, Baton Rouge, LA 70803 (United States); Ali, Naushad [Department of Physics, Southern Illinois University, Carbondale, IL 62901 (United States)

    2015-06-01

    In this report, the results of a study on the effects of compositional variations induced by the small changes in concentrations of the parent components and/or by the substitution of Ni, Mn, or In by an extra element Z, on the phase transitions, and phenomena related to the magnetostructural transitions in off-stoichiometric Ni–Mn–In based Heusler alloys are summarized. The crystal structures, phase transitions temperatures, and magnetic and magnetocaloric properties were analyzed for representative samples of the following systems (all near 15 at% indium concentration): Ni–Mn–In, Ni–Mn–In–Si, Ni–Mn–In–B, Ni–Mn–In–Cu, Ni–Mn–In–Cu–B, Ni–Mn–In–Fe, Ni–Mn–In–Ag, and Ni–Mn–In–Al. - Highlights: • The experimental results on phase transitions temperatures, adiabatic temperature changes, magnetoresistance and heat flow for the ternary and quaternary Heusler alloys based on Ni{sub 50}Mn{sub 35}In{sub 15} demonstrate high sensitivity of magnetic properties to the small changes in concentrations of the parent components and/or by the substitution of Ni, Mn, or In by an additional element Z. • The phenomena related to the magnetostructural transitions strongly depend on the weighted average radius of constituent ions.

  3. Quaternary folding in the south piedmont of central segment of Tianshan Mountains

    Institute of Scientific and Technical Information of China (English)

    2002-01-01

    The Tianshan Mountains are an important active structural belt in the interior of Eurasia. By integrated methods of surface geology survey and interpretation of seismic profiles, we distinguish fold scarps located at the south limb of the Kuqatawu anticline and the north limb of the Dongqiulitag anticline in the Kuqa rejuvenation foreland thrust belt, south piedmont of central segment of the Tianshan Mountains. Fold scarp is a newly found structural phenomenon. Because of the bend of thrust plane and the movement of hanging wall above the thrust plane, the original horizontal deposits of hanging wall and their surface become a monocline structure, resulting from the separating and migration of the active and fixed axial surfaces. Measuring the geometry of fold scarp and using the data of age of the deformed deposits, the crustal shortening rate resulting from the deeply seated subsurface thrust is calculated. The crustal shortening rate reflected by the fold scarp located at the north limb of the Dngqiulitag anticline is (1±0.1) mm/a. The fold scarps of the Dongqiulitag anticline and the Kuqatawu anticline identify that the deformation process of the crustal compressive structures in the Kuqa area extends into the Late Quaternary.

  4. Environmental and Archaeological Implications of a Late Quaternary Palynological Sequence, Poyang Lake, Southern China

    Science.gov (United States)

    Jiang, Qinhua; Piperno, Dolores R.

    1999-09-01

    Paleoecological data from Poyang Lake, southern China, indicate that significant natural and human-induced vegetational changes have occurred during the Late Quaternary in the Middle Yangtze River valley, the likely location of rice (Oryza sativa L.) domestication. During the late Pleistocene (from ca. 12,830 to ca. 10,500 yr B.P.), the climate was cooler and drier than today's. The subtropical, mixed deciduous-evergreen broad-leaved forest which constitutes the modern, potential vegetation was reduced and herbaceous vegetative cover expanded. A hiatus in sedimentation occurred in Poyang Lake, beginning sometime after ca. 10,500 yr B.P. and lasting until the middle Holocene (ca. 4000 yr B.P.). At ca. 4000 yr B.P., the regional vegetation was a diverse, broad-leaved forest dominated by many of the same arboreal elements (e.g., Quercus, Castanopsis, Liquidambar) that grow in the area today. A significant reduction of arboreal pollen and an increase of herbaceous pollen at ca. 2000 yr B.P. probably reflect human influence on the vegetation and the expansion of intensive rice agriculture into the dryland forests near the river valleys.

  5. A Preliminary Report of Changing Quaternary Mammal Faunas in Subalpine New Guinea

    Science.gov (United States)

    Hope, Geoffrey; Flannery, Tim; Boeardi

    1993-07-01

    The faunas found in the mountains of central Irian Jaya have experienced dramatic changes through the late Quaternary. Remains of two previously unknown species of large marsupial, Maokopia ronaldi and Protemnodon hopei, have been recovered from unrelated cave and fluvial deposits which today occur in dense upper montane forest. Direct dating of the finds has not as yet been possible, but stratigraphic, sedimentologic, and palynologic evidence indicates that these species lived near a climatic treeline in subalpine grassland in the late Pleistocene. At higher altitudes a rockshelter provided the second known mid-Holocene record of Thylogale christenseni and Thylogale sp. cf. brunii, apparently extinct grassland wallabies. The two largest remaining subalpine mammal species are being locally exterminated by hunting, leaving only a large murid, Mallomys gunung, which weighs less than 2.0 kg. The area thus records the disappearance of a grassland-adapted fauna. The possum Pseudocheirops cupreus dominates in modem hunting returns, although this species is totally absent from the local fossil records. It may thus be in the process of invading a vacated and disturbed niche from the upper montane forest.

  6. Palaeoenvironmental dynamics inferred from late Quaternary permafrost deposits on Kurungnakh Island, Lena Delta, Northeast Siberia, Russia

    Science.gov (United States)

    Wetterich, Sebastian; Kuzmina, Svetlana; Andreev, Andrei A.; Kienast, Frank; Meyer, Hanno; Schirrmeister, Lutz; Kuznetsova, Tatyana; Sierralta, Melanie

    2008-08-01

    Late Quaternary palaeoenvironments of the Siberian Arctic were reconstructed by combining data from several fossil bioindicators (pollen, plant macro-fossils, ostracods, insects, and mammal bones) with sedimentological and cryolithological data from permafrost deposits. The record mirrors the environmental history of Beringia and covers glacial/interglacial and stadial/interstadial climate variations with a focus on the Middle Weichselian interstadial (50-32 kyr BP). The late Pleistocene to Holocene sequence on Kurungnakh Island reflects the development of periglacial landscapes under changing sedimentation regimes which were meandering fluvial during the Early Weichselian, colluvial or proluvial on gently inclined plaines during the Middle and Late Weichselian, and thermokarst-affected during the Holocene. Palaeoecological records indicate the existence of tundra-steppe vegetation under cold continental climate conditions during the Middle Weichselian interstadial. Due to sedimentation gaps in the sequence between 32 and 17 kyr BP and 17 and 8 kyr BP, the Late Weichselian stadial is incompletely represented in the studied outcrops. Nevertheless, by several palaeoecological indications arctic tundra-steppe vegetation under extremely cold-arid conditions prevailed during the late Pleistocene. The tundra-steppe disappeared completely due to lasting paludification during the Holocene. Initially subarctic shrub tundra formed, which later retreated in course of the late Holocene cooling.

  7. Imaging Quaternary glacial deposits and basement topography using the transient electromagnetic method for modeling aquifer environments

    Science.gov (United States)

    Simard, Patrick Tremblay; Chesnaux, Romain; Rouleau, Alain; Daigneault, Réal; Cousineau, Pierre A.; Roy, Denis W.; Lambert, Mélanie; Poirier, Brigitte; Poignant-Molina, Léo

    2015-08-01

    Aquifer formations along the northern shore of the Saint-Lawrence River in Quebec (Canada) mainly consist of glacial and coastal deposits of variable thickness overlying Precambrian bedrock. These deposits are important because they provide the main water supply for many communities. As part of a continuing project aimed at developing an inventory of the groundwater resources in the Charlevoix and Haute-Côte-Nord (CHCN) regions of the province of Quebec in Canada, the central loop transient electromagnetic (TEM) method was used to map the principal hydrogeological environments in these regions. One-dimensional smooth inversion models of the TEM soundings have been used to construct two-dimensional electrical resistivity sections, which provided images for hydrogeological validation. Electrical contour lines of aquifer environments were compared against available well logs and Quaternary surface maps in order to interpret TEM soundings. A calibration table was achieved to represent common deposits and basements. The calibration table was then exported throughout the CHCN region. This paper presents three case studies; one in the Forestville site, another in the Les Escoumins site and the other in the Saint-Urbain site. These sites were selected as targets for geophysical surveys because of the general lack of local direct hydrogeological data related to them.

  8. Antimicrobial activity of a quaternary ammonium methacryloxy silicate-containing acrylic resin: a randomised clinical trial

    Science.gov (United States)

    Liu, Si-ying; Tonggu, Lige; Niu, Li-na; Gong, Shi-qiang; Fan, Bing; Wang, Liguo; Zhao, Ji-hong; Huang, Cui; Pashley, David H.; Tay, Franklin R.

    2016-01-01

    Quaternary ammonium methacryloxy silicate (QAMS)-containing acrylic resin demonstrated contact-killing antimicrobial ability in vitro after three months of water storage. The objective of the present double-blind randomised clinical trial was to determine the in vivo antimicrobial efficacy of QAMS-containing orthodontic acrylic by using custom-made removable retainers that were worn intraorally by 32 human subjects to create 48-hour multi-species plaque biofilms, using a split-mouth study design. Two control QAMS-free acrylic disks were inserted into the wells on one side of an orthodontic retainer, and two experimental QAMS-containing acrylic disks were inserted into the wells on the other side of the same retainer. After 48 hours, the disks were retrieved and examined for microbial vitality using confocal laser scanning microscopy. No harm to the oral mucosa or systemic health occurred. In the absence of carry-across effect and allocation bias (disks inserted in the left or right side of retainer), significant difference was identified between the percentage kill in the biovolume of QAMS-free control disks (3.73 ± 2.11%) and QAMS-containing experimental disks (33.94 ± 23.88%) retrieved from the subjects (P ≤ 0.001). The results validated that the QAMS-containing acrylic exhibits favourable antimicrobial activity against plaque biofilms in vivo. The QAMS-containing acrylic may also be used for fabricating removable acrylic dentures. PMID:26903314

  9. SWISS-MODEL: modelling protein tertiary and quaternary structure using evolutionary information.

    Science.gov (United States)

    Biasini, Marco; Bienert, Stefan; Waterhouse, Andrew; Arnold, Konstantin; Studer, Gabriel; Schmidt, Tobias; Kiefer, Florian; Gallo Cassarino, Tiziano; Bertoni, Martino; Bordoli, Lorenza; Schwede, Torsten

    2014-07-01

    Protein structure homology modelling has become a routine technique to generate 3D models for proteins when experimental structures are not available. Fully automated servers such as SWISS-MODEL with user-friendly web interfaces generate reliable models without the need for complex software packages or downloading large databases. Here, we describe the latest version of the SWISS-MODEL expert system for protein structure modelling. The SWISS-MODEL template library provides annotation of quaternary structure and essential ligands and co-factors to allow for building of complete structural models, including their oligomeric structure. The improved SWISS-MODEL pipeline makes extensive use of model quality estimation for selection of the most suitable templates and provides estimates of the expected accuracy of the resulting models. The accuracy of the models generated by SWISS-MODEL is continuously evaluated by the CAMEO system. The new web site allows users to interactively search for templates, cluster them by sequence similarity, structurally compare alternative templates and select the ones to be used for model building. In cases where multiple alternative template structures are available for a protein of interest, a user-guided template selection step allows building models in different functional states. SWISS-MODEL is available at http://swissmodel.expasy.org/.

  10. The Quaternary Structure of NADPH Thioredoxin Reductase C Is Redox-Sensitive

    Institute of Scientific and Technical Information of China (English)

    Juan Manuel Pérez-Ruiz; Maricruz González; Maria Cristina Spinola; Luisa Maria Sandali; Francisco Javier Cejudo

    2009-01-01

    NADPH thioredoxin reductase C (NTRC) is a chloroplast enzyme able to conjugate NADPH thioredoxin reduc-tase (NTR) and thioredoxin (TRX) activities for the efficient reduction of 2-Cys peroxiredoxin (2-Cys PRX).Because NADPH can be produced in chloroplasts during darkness,NTRC plays a key role for plant peroxide detoxification during the night.Here,it is shown that the quaternary structure of NTRC is highly dependent on its redox status.In vitro,most of the enzyme adopted an oligomeric state that disaggregated in dimers upon addition of NADPH,NADH,or DTr.Gel filtration and West-ern blot analysis of protein extracts from Arabidopsis chloroplast stroma showed that native NTRC forms aggregates,which are sensitive to NADPH and DTT,suggesting that the aggregation state might be a significant aspect of NTRC activity in vivo.Moreover,the enzyme is localized in clusters in Arabidopsis chloroplasts.NTRC triple and double mutants,A164G-V182E-R183F and A164G-R183F,replacing key residues of NADPH binding site,showed reduced activity but were still able to dimerize though with an increase in intermediary forms.Based on these results,we propose that the catalytically active form of NTRC is the dimer,which formation is induced by NADPH.

  11. A comprehensive database of quality-rated fossil ages for Sahul’s Quaternary vertebrates

    Science.gov (United States)

    Rodríguez-Rey, Marta; Herrando-Pérez, Salvador; Brook, Barry W.; Saltré, Frédérik; Alroy, John; Beeton, Nicholas; Bird, Michael I.; Cooper, Alan; Gillespie, Richard; Jacobs, Zenobia; Johnson, Christopher N.; Miller, Gifford H.; Prideaux, Gavin J.; Roberts, Richard G.; Turney, Chris S. M.; Bradshaw, Corey J. A.

    2016-07-01

    The study of palaeo-chronologies using fossil data provides evidence for past ecological and evolutionary processes, and is therefore useful for predicting patterns and impacts of future environmental change. However, the robustness of inferences made from fossil ages relies heavily on both the quantity and quality of available data. We compiled Quaternary non-human vertebrate fossil ages from Sahul published up to 2013. This, the FosSahul database, includes 9,302 fossil records from 363 deposits, for a total of 478 species within 215 genera, of which 27 are from extinct and extant megafaunal species (2,559 records). We also provide a rating of reliability of individual absolute age based on the dating protocols and association between the dated materials and the fossil remains. Our proposed rating system identified 2,422 records with high-quality ages (i.e., a reduction of 74%). There are many applications of the database, including disentangling the confounding influences of hypothetical extinction drivers, better spatial distribution estimates of species relative to palaeo-climates, and potentially identifying new areas for fossil discovery.

  12. Antibacterial Activity, in Vitro Cytotoxicity, and Cell Cycle Arrest of Gemini Quaternary Ammonium Surfactants.

    Science.gov (United States)

    Zhang, Shanshan; Ding, Shiping; Yu, Jing; Chen, Xuerui; Lei, Qunfang; Fang, Wenjun

    2015-11-10

    Twelve gemini quaternary ammonium surfactants have been employed to evaluate the antibacterial activity and in vitro cytotoxicity. The antibacterial effects of the gemini surfactants are performed on Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus) with minimum inhibitory concentrations (MIC) ranging from 2.8 to 167.7 μM. Scanning electron microscopy (SEM) analysis results show that these surfactants interact with the bacterial cell membrane, disrupt the integrity of the membrane, and consequently kill the bacteria. The data recorded on C6 glioma and HEK293 human kidney cell lines using an MTT assay exhibit low half inhibitory concentrations (IC50). The influences of the gemini surfactants on the cell morphology, the cell migration ability, and the cell cycle are observed through hematoxylin-eosin (HE) staining, cell wound healing assay, and flow cytometric analyses, respectively. Both the values of MIC and IC50 decrease against the growth of the alkyl chain length of the gemini surfactants with the same spacer group. In the case of surfactants 12-s-12, the MICs and IC50s are found to decrease slightly with the spacer chain length changing from 2 to 8 and again to increase at higher spacer length (s = 10-12). All of the gemini surfactants show great antibacterial activity and cytotoxicity, and they might exhibit potential applications in medical fields.

  13. Responses of landform development to tectonic movements and climate change during Quaternary in Fenhe drainage basin

    Institute of Scientific and Technical Information of China (English)

    HUXiaomeng; LIYouli; FUJianli

    2003-01-01

    Tectonic movements and climate changes are two main controllers on the development of landfrorm.In order to reconstruct the history of the evolution of the landform in the Fenhe drainage basin during middle-late Quaternary comprehensively,this paper has provided a variety of geomorphological and geologic evidences to discuss how tetonic movements and climate changes worked together to influence the landform processes,According to the features of the lacustrine and alluvial terraces in this drainage basin,it is deduced that it was the three tectonic uplifts that resulted in the three great lake-regressions with an extent of about 40-60 m and the formation of the three lacustrine terraces.The times when the tectonic uplifts took place are 0.76 MaBP,0.55 MaBP and 0.13 MaBP respectively,synchronous with the formation of paleosol units S8,S5 and S1 respectively.During the intervals between two tectonic uplifts when tectonic movement was very weak ,climate changes played a major role in the evolution of the paleolakes and caused frequent fluctuations of lake levels.The changes of the features of lacustrine sediment in the grabens show the extent of such fluctuations of lake level is about 2-3m.

  14. Late Quaternary climate variability in the Sahel: inferences from marine dust records offshore Senegal

    Science.gov (United States)

    Stuut, J. W.; Meyer, I.; Fischer, H.; Mollenhauer, G.; Mulitza, S.; Pittauerova, D.; Zabel, M.; Schulz, M.

    2008-12-01

    Societies and ecosystems in northern Africa are strongly affected by the availability of water. As a consequence, long-term absence of rainfall has very dear effects on the ecosystems, as was dramatically shown in the 70'ies and 80'ies of the 20th century. Recent high-resolution reconstructions of Sahel palaeoclimate allow for new insights into these drastic climate variations and to disentangle the effects of the different components of the climate system on African climate change. In this study we extend the instrumental record of climate variability using marine sediment cores that were retrieved off the coast of Senegal, northwest Africa. The sediment records contain continuous high-resolution records of dust sedimentation ranging from about 4,000 to about 57,000 years. A 210Pb age model for the youngest sediments allows for a matching of the proxy rainfall record with instrumental precipitation data. Specifically, variations in the grain-size distributions of the terrigenous sediment fraction, deconvolved with an end-member modelling algorithm (Weltje, 1997) are used to reconstruct rainfall variability on land throughout the late Quaternary.

  15. Biostratigraphy of the Quaternary nannofossils from Campos Basin; Bioestratigrafia dos nanofosseis quaternarios da Bacia de Campos

    Energy Technology Data Exchange (ETDEWEB)

    Antunes, Rogerio L. [PETROBRAS, Rio de Janeiro, RJ (Brazil). Centro de Pesquisas

    1994-04-01

    Seven biostratigraphic intervals have been identified through biostratigraphic studies based on calcareous nannofossils from samples of the Quaternary section of Campos and Santos basins. These intervals (named A to G) are based mainly on biological events such as extinction, first appearance, and prevalence (acme zone) of cosmopolitan taxa. In view of this, almost all recognized sections have an identity with colval biozones that have been described in the bibliography, making easier their correlation with magneto stratigraphic units and the inference of absolute ages. Nevertheless, interval D has not been consistently identified. According to what was observed it is possible to further divide the section. Such detailing would be based mainly on the appearance of Helicosphaera inversa (in interval C) and form B of H. carteri. var. wallichii (at the base of interval F), and on the abundance of H. carteri s.l. (in interval G). It is possible that other subdivisions will be delineated through quantitative investigation. However, these would be based on `anomalous` concentrations of some species with strong environmental connotation. This is the case, for example, of sharp variations in the absolute frequency of Coccolithus pelagicus which, for the time being, have been detected in intervals F and G. According to the bibliography, this species attains maximum proliferation during glacial epochs. (author). 5 figs., 1 tab.

  16. Petrography and petrology of Quaternary volcanic rocks from Ghezel Ghaleh, northwest Qorveh

    Directory of Open Access Journals (Sweden)

    Alireza Bajelan

    2014-10-01

    Full Text Available Introduction In the east and northeast of Sanandaj in the Qorveh-Bijar-Takab axis, there are series of basaltic composition volcanoes with Quaternary age. The study area is part of the Sanandaj-Sirjan zone and is located between 47°52' and 47°57' E longitudes and 35°26 and '35°30' N latitudes. Due to the location of the volcanic cone on Pliocene clastic sediments and Quaternary travertine, the age of these volcanoes is considered to be Quaternary. The cones mostly consist of low scoria, ash, volcanic bombs, lapilli deposits and basaltic lava (Moein Vaziri and Aminsobhani, 1985. Petrological and geochemical studies have been carried out to evaluate Quaternary magmatism in the area and to determine the nature of the lithological characteristics, such as the evaluation of source rocks and magma type, degree of partial melting and the tectonic setting of Ghezel Ghaleh rocks (Moein Vaziri, 1997. Simplified geological map of the study area is characterized by ER-Mapper software. Materials and methods In the course of field studies in the region, 40 samples were taken, 30 thin sections were prepared and polished. XRD analyses were performed on some whole rock samples. All major, minor and trace elements were assessed by ICP-MS at Lab Weft Laboratory in Australia. Results Based on the classification of structural zones, the area is located in the Sanandaj-Sirjan zone, hundred kilometers away from the main Zagros thrust along the NW-SE direction. After early Cimmerian orogeny, andesitic volcanic activity took place (Moein Vaziri and Aminsobhani, 1985. A major secondary mineral in these rocks is iddingsite, formed by hydration and oxidation of the olivine (Shelley, 1993. According to SiO2 against Na2O + K2O (TAS diagram (Irvine and Baragar , 1971 and cationic R1 and R2 diagram (De La Roche et el., 1980, volcanic rocks of the area indicate alkaline series. Discussion To obtain more information on the tectonic setting of these rocks, the Zr/Y-Zr diagram

  17. Optical absorption analysis of quaternary molybdate- and tungstate-ordered double perovskites

    Energy Technology Data Exchange (ETDEWEB)

    Tablero, C., E-mail: ctablero@etsit.upm.es

    2015-08-05

    Highlights: • These compounds present a high optical absorption. • The absorption coefficients using different DFT + U alternatives have been compared. • The absorption coefficients have been split into different contributions. • The maximum efficiency is near the maximum efficiency for multiple-gap solar cells. - Abstract: Quaternary-ordered double perovskite A{sub 2}MM′O{sub 6} (M = Mo,W) semiconductors are a group of materials with a variety of photocatalytic and optoelectronic applications. An analysis focused on the optoelectronic properties is carried out using first-principles density-functional theory with several U orbital-dependent one-electron potentials applied to different orbital subspaces. The structural non-equivalence of the atoms resulting from the symmetry has been taken in account. In order to analyze optical absorption in these materials deeply, the absorption coefficients have been split into inter- and intra-non-equivalent species contributions. The results indicate that the effect of the A and M′ atoms on the optical properties are minimal whereas the largest contribution comes from the non-equivalent O atoms to M transitions.

  18. Episodic Late Quaternary slopewash deposition as recorded in colluvial aprons, Southeastern Wyoming

    Science.gov (United States)

    Hanson, Paul R.; Mason, Joseph A.; Goble, Ronald J.

    2004-09-01

    Colluvial aprons found along fluvial terraces of the Laramie River and Sybille Creek in southeastern Wyoming are interpreted as late Quaternary slopewash deposits. Each apron studied contained multiple buried soils, interpreted to indicate that slopewash activity was episodic and short-lived, and was followed by relatively long periods of landscape stability and soil development. Apron deposits were described and subsequently correlated based on their internal stratigraphy and their relative degree of soil development. Optical dating was used to chronologically constrain periods of slopewash deposition, and based on 17 optical ages taken from five aprons, aggradation occurred at ˜65-56, 16.0, 12.9, 11.8, 8.1, 7.3, 5.0, and 1.7 ka. Several of these events correspond with climatic transitions such as the termination of Heinrich Event 1, the onset and termination of the Younger Dryas, and the 8.2 ka event, suggesting that apron aggradation was driven by changes in climatic regime. Although either increased aridity or a change in precipitation regime could result in increased erosion of terrace scarps, apron aggradation events do not correlate with regional records of aridity. Instead, periods of increased precipitation intensity and/or frequency that occur during climatic transitions most likely drive apron aggradation events.

  19. CO2 capture from simulated fuel gas mixtures using semiclathrate hydrates formed by quaternary ammonium salts.

    Science.gov (United States)

    Park, Sungwon; Lee, Seungmin; Lee, Youngjun; Seo, Yongwon

    2013-07-02

    In order to investigate the feasibility of semiclathrate hydrate-based precombustion CO2 capture, thermodynamic, kinetic, and spectroscopic studies were undertaken on the semiclathrate hydrates formed from a fuel gas mixture of H2 (60%) + CO2 (40%) in the presence of quaternary ammonium salts (QASs) such as tetra-n-butylammonium bromide (TBAB) and fluoride (TBAF). The inclusion of QASs demonstrated significantly stabilized hydrate dissociation conditions. This effect was greater for TBAF than TBAB. However, due to the presence of dodecahedral cages that are partially filled with water molecules, TBAF showed a relatively lower gas uptake than TBAB. From the stability condition measurements and compositional analyses, it was found that with only one step of semiclathrate hydrate formation with the fuel gas mixture from the IGCC plants, 95% CO2 can be enriched in the semiclathrate hydrate phase at room temperature. The enclathration of both CO2 and H2 in the cages of the QAS semiclathrate hydrates and the structural transition that results from the inclusion of QASs were confirmed through Raman and (1)H NMR measurements. The experimental results obtained in this study provide the physicochemical background required for understanding selective partitioning and distributions of guest gases in the QAS semiclathrate hydrates and for investigating the feasibility of a semiclathrate hydrate-based precombustion CO2 capture process.

  20. Ages of subsurface stratigraphic intervals in the Quaternary of Enewetak Atoll, Marshall Islands

    Science.gov (United States)

    Szabo, B. J.; Tracey, J. I.; Goter, E. R.

    1985-01-01

    Drill cores of Enewetak Atoll, Marshall Islands, reveal six stratigraphic intervals, numbered in downward sequence, which represent vertical coral growth during Quaternary interglaciations. Radiocarbon dates indicate that the Holocene sea transgressed the emergent reef platform by about 8000 yr B.P. The reef grew rapidly upward (about 5 to 10 mm/yr) until about 6500 yr B.P. Afterward vertical growth slowed to about 0.5 mm/yr, then lateral development became dominant during the last several thousand years. The second interval is dated at 131,000 ± 3000 yr B.P. by uranium series. This unit correlates with oxygen-isotope substage 5e and with terrace VIIa of Huon Peninsula, New Guinea, and of Main Reef-2 terrace at Atauro Island. The third interval is not dated because corals were recrystallized and it is tentatively correlated with either oxygen-isotope stages 7 or 9. The age of the fourth interval is estimated at 454,000 ± 100,000 yr B.P. from measured {234U }/{238U } activity ratios. This unit is correlated with either oxygen-isotope stage 9, 11, or 13.